#DEFINITION	Reference Metabolome for Vigna radiata
#IDENTTFIER	RefMeta-Vigna radiata.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Vigna radiata
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Vigna radiata was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1672
Annotation	Galactotriose
Peak:m/z	Relative Intensity
206.9741821	0.29
209.1181793	0.10
220.1226044	0.03
223.1845093	0.12
224.6988220	0.02
255.7073975	0.04
267.1310730	0.08
339.1324463	0.05
358.1896362	0.02
369.1434326	0.02
373.9771118	0.04
379.1195068	0.05
380.1726685	0.06
398.1823120	0.10
403.1107788	0.04
410.9455566	0.23
411.9745483	0.33
413.9635620	0.24
415.9143066	0.12
417.1840820	0.05
420.0244751	0.08
423.0622559	0.02
459.9749756	0.03
465.0248413	0.05
485.0550537	0.09
486.4740601	0.07
503.1672974	100.00
504.3150024	0.15
529.9769897	0.07
531.0109253	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1097.5157
Annotation	AzII
Peak:m/z	Relative Intensity
320.1726685	0.03
336.2036133	0.04
359.2554626	0.08
377.1028442	0.15
422.9783325	0.12
451.5106812	0.19
465.1931763	0.48
467.2157898	0.11
469.4474487	4.46
470.5235596	1.74
483.2145691	0.28
484.0311279	0.14
485.4029541	1.15
487.3949890	4.44
488.4265137	1.56
509.5064392	0.11
511.5800171	0.07
529.3037109	0.23
537.4415283	0.55
538.6837158	0.55
555.5095825	1.03
556.5433350	0.29
557.1712646	0.24
558.4924316	0.20
569.3613281	1.97
570.3229370	0.79
583.6954346	0.08
595.0518799	0.06
599.9757080	0.07
601.4326172	2.22
602.5303955	0.77
609.3150635	0.61
610.5246582	0.10
613.0421753	0.34
619.5449219	0.60
627.5556641	0.60
628.4718018	0.05
643.4840088	0.23
645.3565674	31.12
646.4119873	12.49
647.0309448	0.12
674.4575806	0.09
681.0643311	0.27
681.6796265	0.33
682.2954102	0.16
697.3776245	0.14
727.5313110	0.18
745.6594238	0.40
746.3836670	0.15
753.3338623	0.71
754.4150391	0.16
763.4125977	1.64
764.3974609	0.85
771.3391113	1.46
772.3921509	0.24
773.2822266	0.10
774.4372559	0.06
775.5394287	0.30
781.4688110	0.37
789.2729492	0.41
790.7189331	0.20
807.3986816	0.65
808.1076660	0.08
815.2087402	0.10
825.3640137	0.15
826.3769531	0.29
881.2036133	0.15
886.5002441	0.14
887.3376465	0.18
891.5067139	1.78
892.4681396	1.15
909.4594727	22.49
910.5007324	12.25
920.4897461	0.13
927.5322266	3.45
928.4750977	1.21
935.3381348	3.61
936.2122803	0.94
936.8702393	0.04
951.3398438	0.97
953.4427490	56.90
954.5357666	24.66
957.2755127	0.17
969.6977539	0.60
971.4324951	100.00
972.4686279	57.13
973.1865234	0.24
976.9979248	0.09
979.6284180	0.11
997.4482422	1.90
998.5483398	1.31
1004.4111330	0.10
1010.3049320	0.08
1027.5659180	0.30
1028.8441160	0.06
1034.0495610	0.08
1035.3508300	2.73
1036.5454100	1.15
1051.7355960	0.09
1053.1955570	0.11
1069.6325680	0.07
1078.8503420	0.78
1079.4610600	10.51
1080.4650880	6.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	652.2274
Annotation	Unknow
Peak:m/z	Relative Intensity
194.3734436	2.74
195.0061951	17.82
195.9337921	0.54
217.0994873	0.06
230.7144470	0.38
236.9570618	0.20
249.0368195	0.49
252.5962219	0.28
271.0450439	2.68
273.2349854	0.83
278.8650818	0.20
288.4505615	2.20
289.0781860	1.86
305.1384888	0.14
306.1639404	1.15
306.9234009	1.20
309.5802002	0.38
310.2208862	1.94
319.9072266	1.26
320.8648682	2.94
324.8305664	65.79
338.7615356	2.38
339.8091431	0.85
341.4022827	1.98
342.2491455	5.40
342.9111938	31.04
355.7823486	4.24
356.8937378	96.41
357.9227295	1.66
397.1067505	0.31
434.5052490	0.76
458.0331421	0.11
468.6456909	0.54
485.4545898	0.40
486.7485352	6.17
489.7277222	10.54
490.3533325	0.82
504.5207520	1.15
505.1509399	0.30
518.7349243	100.00
519.9551392	1.26
632.6463623	0.68
634.0311890	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2763
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
141.1365814	0.05
141.8716736	0.02
158.9797363	0.01
161.0937805	0.01
174.9415894	0.04
198.0332642	0.15
211.2846375	0.03
216.1985168	0.07
242.9804230	0.04
261.0960693	0.07
291.1148071	0.03
293.3809204	0.09
304.3134155	0.17
317.3558350	0.06
321.8525391	0.05
322.4755249	0.01
335.2412720	100.00
336.0984497	0.02
360.3855591	0.01
414.8201599	0.03
415.4709778	0.14
420.1817017	0.02
433.1752930	0.12
440.0321960	0.05
458.1517334	4.25
458.8312073	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
85.0403748	0.04
86.0959930	0.04
87.8819199	0.07
97.0465393	0.02
106.9398880	1.22
112.9355011	0.09
120.9593506	0.07
124.8859100	0.03
126.8950577	0.27
143.9580994	0.07
144.8518372	0.23
147.1630859	0.05
148.9700317	0.60
150.7426605	0.16
152.9240723	38.32
154.9977264	0.08
156.8707886	0.02
157.8496246	0.03
162.9159393	0.32
166.9427795	0.33
169.0821228	0.04
170.9045105	0.42
172.8744507	0.11
174.9601746	0.12
177.2839203	0.10
178.8853455	0.03
186.6175842	0.08
188.1214905	0.31
193.0704651	0.24
195.0131226	6.88
199.1759949	0.14
201.0719604	0.09
202.9410706	0.15
207.1303711	0.11
208.0109863	0.07
210.8782043	0.04
215.1723328	0.38
215.9694824	0.04
217.0138550	1.15
225.0718994	0.32
227.0299072	0.12
228.0846252	0.04
229.1201477	0.41
230.2089539	0.29
231.1166077	0.02
233.1473694	0.09
235.0448914	0.32
243.0147705	32.13
243.6759033	0.38
244.9309692	0.03
245.9569702	0.30
247.0759888	0.02
248.0234680	0.33
253.0114441	7.98
257.0419312	0.15
258.7850647	0.12
261.1170654	1.15
268.6193237	0.19
269.3128967	0.07
270.9554443	100.00
272.0129395	0.12
274.1717529	0.08
274.8432922	0.07
279.8576660	0.78
289.2988892	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5067
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
255.219101	34.24
271.3102722	0.86
279.2263794	100.00
295.6067505	1.03
305.4431763	1.69
327.1859741	0.42
358.4558716	0.37
372.5906372	0.42
422.2297363	1.28
431.1270142	1.57
434.3268433	2.39
445.0435181	0.24
452.3510132	14.02
458.1368408	0.94
463.8424072	1.31
471.5684204	0.53
472.3458862	1.29
476.3428345	0.63
487.604248	0.76
520.4273071	0.65
530.9812622	0.90
534.0427856	0.46
546.0255127	2.82
566.2296143	1.10
568.4699097	1.29
569.4875488	0.80
577.7235718	1.00
593.8565674	0.56
595.0842285	0.36
614.7767334	0.29
624.5509033	0.37
630.6054077	1.35
636.3864136	0.44
642.9400635	1.87
652.6558228	0.20
654.7279053	0.58
655.5437012	0.84
660.1916504	1.58
666.8143921	0.22
668.2185669	4.09
670.227356	0.63
671.3215332	1.93
678.2382202	3.21
695.828064	2.25
696.8852539	9.10
697.5187378	12.24
705.5029297	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1
Annotation	Vitexin
Peak:m/z	Relative Intensity
125.1761627	0.05
150.9230957	0.05
155.1172638	0.14
161.1419525	0.18
163.1427307	0.11
179.2671509	0.03
181.0914001	0.14
188.092041	0.08
205.1015167	0.12
206.9718323	0.11
209.1382751	0.11
223.0949097	0.26
223.7169189	0.04
227.1957855	0.72
231.019043	0.07
232.9887085	0.08
239.394104	0.09
249.1196289	0.87
251.1901855	0.17
263.4068298	0.14
264.8031921	0.11
269.1335449	1.17
278.8735962	0.07
281.2033081	0.05
283.0917969	0.51
285.0444336	0.33
286.1471252	0.38
287.0889893	0.51
291.0435791	0.05
293.0639038	0.06
297.961731	0.12
309.1130676	0.22
311.0570068	100.00
311.6786499	0.13
312.3222046	0.03
323.0527649	0.57
325.2357788	0.43
326.1025085	0.25
327.1455078	0.61
328.1659546	0.50
329.3165894	0.10
337.120636	0.42
338.065033	0.04
338.9902344	0.07
341.1975708	17.10
342.1767578	0.07
351.1213989	0.05
352.9975281	1.25
354.0009155	0.05
355.1170959	0.56
365.2132568	0.13
367.1567078	0.24
368.0495605	0.09
369.3547058	0.19
370.0491943	0.95
371.2497559	8.63
374.8819275	0.04
377.1893005	0.27
382.2956543	0.12
383.1752625	0.39
384.4190063	0.67
385.1777344	1.30
386.2338867	0.59
387.1481323	0.70
388.2090759	0.94
389.3070984	0.54
393.5694885	0.12
394.259491	0.15
395.3301697	0.55
395.9837341	0.04
399.4511108	0.20
400.2138367	1.51
401.1413574	0.64
402.396698	0.04
403.1352539	0.15
409.2599182	0.06
412.2348633	1.61
413.1631165	4.08
414.0782471	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	264.0711
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
83.7940750	0.07
106.9851074	0.08
110.0148163	0.05
111.0880585	0.03
116.0759583	0.25
128.0104675	0.44
128.9132385	0.17
131.9886322	0.12
134.0039520	0.05
137.8906860	0.31
138.9015045	0.23
143.9852142	0.11
144.6867065	0.06
146.0807037	0.52
147.1007538	0.08
156.1979065	0.13
157.8823700	0.51
162.8114624	0.09
171.7885895	0.09
173.9511566	2.93
179.0346069	0.07
183.2949066	0.41
197.9953156	0.59
198.9817505	0.19
200.0571594	10.69
202.1147461	0.18
204.1216583	0.17
209.8950348	1.86
215.8647003	0.12
218.0760345	3.41
220.2435455	1.29
223.0238037	0.03
227.9669189	21.88
229.0295105	0.19
234.2850952	0.19
235.3180695	0.49
236.8494110	0.11
241.0254517	0.03
243.6662750	0.22
245.9527435	100.00
247.1842194	0.06
255.0978546	0.42
257.1624451	0.05
263.8906555	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1241
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
136.8956909	75.82
137.6790314	0.18
145.0054932	1.35
150.9934387	0.60
161.0279388	0.55
165.0032196	0.17
166.8892365	0.38
179.0267029	2.23
183.8361816	0.27
184.9973755	0.62
198.9267273	1.20
201.3019257	0.16
202.8861084	0.40
204.9284363	0.81
212.9849854	0.44
227.1678467	2.48
229.0761108	0.88
229.8086090	0.09
245.0287170	1.52
253.0757751	4.86
266.8705750	0.13
270.9659729	100.00
271.6409302	0.11
289.0957642	43.67
308.9680176	0.10
313.0399170	7.46
320.0705872	0.46
321.3533020	0.19
325.4501038	0.34
329.1441345	3.59
331.3346252	0.14
341.2753906	0.19
355.2121582	0.15
387.8583069	0.14
391.1867371	0.23
405.1148376	22.36
406.9946594	0.85
433.1654358	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1313
Annotation	CMP-8-amino-3,8-dideoxy-beta-D-manno-octulosonate
Peak:m/z	Relative Intensity
200.8929291	0.56
362.9146118	0.25
381.1533813	100.00
382.1649780	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.015
Annotation	Unknow
Peak:m/z	Relative Intensity
121.3529663	0.01
139.0874329	0.02
145.1021881	0.01
163.0557861	0.04
182.3925476	0.01
189.2248993	0.05
194.9679108	0.01
208.9767914	0.06
218.3179932	0.02
220.9278107	0.04
223.8488312	100.00
234.5721436	0.07
235.2479401	0.01
241.6406250	10.62
242.3364258	0.02
248.0744629	0.01
251.4876251	0.01
264.7850952	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	404.3158
Annotation	N-palmitoyl phenylalanine
Peak:m/z	Relative Intensity
117.2277298	0.03
118.1039429	0.27
119.9631348	23.71
120.8672485	0.03
131.0813293	0.35
133.0405731	0.14
134.8021393	0.20
136.9551392	0.13
141.2035065	0.03
147.3380127	0.04
148.9308014	0.82
154.0239105	0.03
161.1672974	0.04
165.9186707	100.00
169.2524109	0.08
174.9752808	0.03
177.1856842	0.21
179.2401123	0.06
180.9448547	0.06
189.2623138	0.15
190.1941071	0.08
191.3474731	0.27
195.1944427	0.05
207.0955353	0.37
208.1298218	0.06
209.2917480	0.05
211.1484985	0.17
212.7671509	0.17
218.2068787	0.15
221.2507172	0.18
222.0206909	0.08
223.0936737	0.09
225.4283142	0.15
227.0955811	0.18
237.1673889	0.26
238.0727844	0.10
241.2999878	0.05
243.0838013	0.11
250.6009521	0.19
251.6523132	0.13
260.0805359	0.04
263.3987122	0.22
265.2532959	0.03
271.1641846	0.07
277.9960938	0.21
283.2405396	0.25
284.5898743	0.16
286.8998108	0.09
288.3185425	0.16
291.1308899	0.03
292.4371643	0.09
293.3179932	0.06
295.0929565	0.04
301.3204956	0.16
302.4167480	0.10
306.4312134	0.03
308.1929932	0.09
311.9074707	0.03
314.1675415	0.04
317.3355713	0.18
319.2569580	0.15
320.3250732	0.07
323.4475403	0.35
326.5167236	0.08
327.4514160	0.15
336.6187744	0.06
337.3349915	1.13
341.3353577	0.36
343.3756714	0.10
344.2350464	0.10
346.4255371	0.04
347.2958984	0.16
351.3321228	0.10
355.0364990	1.48
355.6802979	0.01
357.3997498	0.22
358.1656799	5.09
359.3777771	0.21
360.3495178	0.24
362.4042664	0.24
363.5368652	0.10
367.1004028	0.02
367.7019958	0.16
372.0805969	0.02
373.0667419	0.05
375.2728577	0.07
377.3748169	0.13
385.6810913	1.11
386.2975159	9.34
387.2448425	0.26
390.3537292	0.02
404.1194153	0.42
405.2140198	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1091.3445
Annotation	Unknow
Peak:m/z	Relative Intensity
382.8323669	0.09
442.8591003	0.70
484.9998474	0.18
503.0049438	1.55
504.0939331	0.02
545.0684814	0.70
574.9212646	0.07
604.9027100	0.63
647.4447632	0.28
664.7946777	0.26
827.2255859	100.00
828.2994385	6.75
829.0755615	0.33
928.9128418	0.06
956.2404785	3.80
957.2175293	0.58
1073.1760250	8.12
1074.2081300	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.303
Annotation	Neobonaspectin B
Peak:m/z	Relative Intensity
171.2129669	0.26
175.1691589	0.20
179.1833649	0.13
181.2619476	0.05
182.1322784	0.07
182.9482574	0.10
183.8843842	0.19
184.6470642	0.08
189.4682465	0.07
193.1409302	0.10
199.3686981	0.06
202.7299957	0.15
206.5989380	0.02
217.0427551	0.03
221.0908203	0.10
227.0587616	0.02
242.6642761	0.06
243.4661102	0.05
245.2218323	1.30
259.1780701	0.02
261.0427246	1.10
263.3073730	0.63
271.0034790	0.06
273.6676025	0.07
275.1030273	0.08
279.2601318	0.09
281.1740112	0.23
282.9278870	0.06
290.3750610	0.03
291.3952026	0.04
293.2745361	0.04
297.1723328	0.15
299.0331421	0.09
301.2306519	0.15
305.3315430	0.07
307.1836548	0.04
309.3099976	0.03
315.2631836	0.24
317.0684814	1.63
318.1262817	0.02
319.2122803	0.32
327.2397461	0.05
335.1268921	4.05
337.3182983	100.00
339.5839233	0.08
355.6992798	0.23
367.5653076	0.04
389.5129395	0.10
397.9895630	0.01
400.5240479	0.04
407.5135498	0.04
417.2337036	0.29
424.5661621	0.03
425.3817749	0.15
431.5709229	0.02
432.7836304	0.12
435.0916748	0.27
437.5434570	0.04
441.1173706	0.03
443.2950439	0.12
455.5802612	0.61
456.3540649	0.04
459.5891724	0.03
498.3632202	0.09
505.3430176	0.65
509.3484497	0.07
530.5758667	0.03
537.1328125	0.24
539.7622070	0.04
542.4093018	0.12
543.6848145	0.08
551.5299683	0.09
554.1005859	0.22
555.3550415	0.03
561.2022705	11.43
569.2849731	0.18
578.5331421	3.88
579.2224731	20.21
580.5868530	0.16
581.2011108	0.05
596.4665527	0.22
597.4390869	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	307.1397
Annotation	Unknow
Peak:m/z	Relative Intensity
88.9598846	0.39
96.9077606	0.73
98.9582367	6.23
100.9347916	3.17
106.8480148	0.20
110.8703003	0.08
113.0375977	2.63
118.9001846	2.29
125.1406403	0.23
127.0077515	2.93
129.0380554	0.87
130.8992004	0.57
141.0545959	1.17
142.9406738	1.88
145.0592499	100.00
149.0095215	0.14
158.8584290	0.77
161.0145874	1.29
162.9914551	0.10
164.8482971	0.04
178.4847412	0.69
179.2313690	0.28
183.2387390	0.08
187.0823212	7.24
188.0666656	0.08
197.2226257	0.20
199.1321716	0.66
200.5078735	0.17
204.9757080	0.09
208.9815063	0.16
213.3666992	0.05
216.9617615	0.29
223.1624756	0.06
227.1669312	0.07
229.1721191	0.40
235.1833496	0.12
242.1302795	0.06
250.8956299	0.07
253.3786011	0.06
261.0666504	0.47
262.8852539	0.27
263.9201355	0.11
271.0744629	0.22
277.1533813	0.21
287.9949341	0.44
289.2364502	0.49
291.9442139	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.08
Annotation	5,6,4'-Trihydroxy-7,3'-dimethoxyIsoflavone
Peak:m/z	Relative Intensity
97.1082001	0.03
111.1497040	0.03
120.8760071	0.32
131.0564270	0.07
133.9025879	0.01
147.1124878	0.02
149.0646362	0.04
151.0545044	0.15
158.1586609	0.02
162.8834229	2.65
164.1815796	0.09
165.1301270	0.03
165.7336578	0.05
169.0194855	2.03
172.9871674	0.09
177.0395203	0.31
180.8938293	0.11
195.0465698	1.66
199.2163849	0.05
208.9547424	0.03
210.2138977	0.11
213.0214233	0.13
214.2468872	0.03
218.7850647	0.02
230.2581177	0.02
236.3726196	0.03
237.0050354	0.16
238.3826904	0.01
239.1661987	0.10
241.9390259	0.17
249.3186035	0.05
252.8856812	0.19
254.8550415	0.05
255.8615112	0.08
263.2214966	0.02
268.8722229	0.10
273.9462585	0.07
277.3197327	0.04
281.2394409	0.03
285.1007690	0.09
287.2033691	0.03
288.2121582	0.02
290.1830444	0.04
294.0817871	0.14
295.2421570	0.04
299.2282104	0.03
301.0302124	0.03
302.1439209	0.13
303.4632568	0.05
310.0116577	0.08
313.0655823	100.00
313.9765015	0.04
315.2670288	0.03
319.0441284	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.26
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
179.1391754	0.10
182.9438324	0.02
198.9245911	0.10
205.1989746	0.06
211.0341034	0.15
212.2080688	0.10
213.1926117	0.18
215.0412292	0.03
220.1204529	0.15
223.1333313	0.06
224.8771973	0.15
227.1762085	0.14
237.0706177	0.27
250.1924744	0.09
252.0708771	0.07
254.8149109	0.06
259.1535645	0.14
262.4855957	0.06
272.2013550	0.09
275.2337646	0.26
277.2611389	0.02
279.2035522	0.09
293.1701050	0.26
294.2392578	0.06
295.1617432	0.14
301.2883301	0.10
305.0815430	0.13
310.5010986	0.02
313.2792358	0.05
314.2043152	0.20
323.0576782	0.04
326.4468384	0.06
332.3999023	0.03
334.8436279	0.02
336.2426758	0.09
350.1107178	0.21
351.1277466	0.11
356.2003174	0.05
356.8922119	0.03
361.0977173	0.04
363.1724854	0.10
367.3746948	0.03
377.3824463	0.07
390.2565308	0.07
397.2897949	0.07
401.4547119	0.06
409.1026001	0.24
414.5120239	0.04
419.5415039	0.06
421.2100830	0.05
425.2698364	0.03
433.5137939	0.07
436.0235596	0.12
442.5629272	0.04
446.4711914	0.06
449.6539917	0.22
459.5202637	0.35
461.5190430	0.06
463.2152100	0.03
464.5147705	0.03
466.8751831	0.15
469.5105591	0.11
470.4389648	0.03
473.2270508	0.11
474.0985718	0.41
475.5350342	0.73
476.2662354	0.20
477.5502319	0.04
480.5462036	0.11
485.3707886	0.13
487.3658447	0.17
489.2164307	0.12
489.8505859	0.10
492.5575562	0.17
495.3911133	0.20
497.5084229	0.07
498.1185913	0.06
501.1942749	0.36
502.3435059	0.70
503.2108765	0.58
504.2990723	0.45
506.5203857	0.07
507.3295288	0.05
508.5408325	0.04
509.5993042	0.07
511.8712158	0.02
513.7348022	0.16
516.0971069	0.06
517.3694458	0.19
519.3644409	0.70
520.3839722	0.55
521.2294312	0.13
529.3193970	1.36
530.5785522	1.02
531.4950562	1.64
532.1547852	0.09
532.7598267	0.30
534.1326294	3.61
535.3816528	2.41
536.3452759	0.48
538.4752808	0.32
539.3534546	0.60
540.2688599	0.13
542.8293457	0.07
545.2159424	0.14
546.0429077	0.51
547.3021851	100.00
548.3076782	25.97
549.4142456	2.53
551.3198853	1.03
552.3391113	0.09
554.0808716	0.06
557.2304077	0.43
558.7763672	0.20
561.3383789	1.92
562.3198242	0.08
563.3593140	1.09
564.2294312	0.69
565.3433228	0.22
566.3431396	0.15
572.0216064	0.60
574.3996582	0.29
575.1480103	3.24
576.3082275	0.90
578.1552124	0.69
579.3272705	6.60
580.2127075	1.86
588.3323364	0.98
589.1652222	3.68
590.0451660	1.45
590.7210083	0.10
592.0634155	0.40
593.1355591	0.10
606.4513550	0.69
607.1447144	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Isovitexin
Peak:m/z	Relative Intensity
143.0226288	0.03
149.8233643	0.01
161.094696	0.02
161.9586792	0.01
179.2111816	0.03
191.0852051	0.07
203.1235046	0.01
216.9985352	0.10
251.1240234	0.02
267.1221619	0.01
268.0692444	0.01
269.2094727	0.13
270.2799683	0.07
281.1497803	0.04
283.1435547	0.50
284.1929932	0.20
293.0808105	0.06
294.2272339	0.09
295.2592163	0.07
296.3728333	0.01
309.2704773	0.02
311.0534058	100.00
312.0850525	59.90
321.3035889	0.02
322.981781	0.11
324.0423889	0.20
325.0982666	0.08
336.0411682	0.03
336.9150391	0.01
341.0750732	8.16
342.1940308	5.43
350.1038208	0.01
351.4217529	0.07
352.1877136	0.02
353.0956421	0.58
354.1103516	0.30
355.1130371	0.06
356.1261292	0.06
362.0639954	0.02
365.1094666	0.03
366.072937	0.05
367.1898193	0.04
368.0974731	0.03
371.2792053	0.47
372.2529602	0.13
377.2775269	0.23
378.059967	0.02
383.0909119	0.11
384.2082825	0.18
386.3509827	0.01
386.9582214	0.11
388.2845764	0.05
389.2937317	0.09
390.2680054	0.01
395.1637268	0.17
395.9851379	0.08
413.1352234	0.47
414.0349731	0.36
414.9657288	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.507
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
235.2786865	0.27
252.0939026	0.25
255.273819	38.68
256.3452148	8.61
257.7175903	0.64
261.2047119	0.74
269.4811401	0.06
279.2241211	100.00
280.295105	20.64
294.4497681	0.39
306.2147217	0.18
327.1654663	0.13
354.3682251	0.37
399.2739258	0.61
403.048645	0.52
430.9498901	1.00
434.3339233	1.87
435.3334961	0.06
451.2032471	0.26
452.3556519	16.39
453.248291	3.69
457.6742554	0.09
458.5153809	0.53
459.4490967	1.45
469.6369629	0.32
476.4077148	1.07
477.6092529	1.64
485.3169556	0.60
487.0204468	0.23
517.2420654	0.43
527.2199097	0.22
551.4711914	0.42
552.4541016	2.05
553.5227661	3.32
554.4061279	0.89
556.3479614	0.20
567.2202148	1.29
568.1918945	0.24
595.3270874	0.88
620.0529175	0.66
621.7655029	0.19
630.5933228	0.26
642.4802246	0.20
652.0598755	0.17
656.8278198	0.69
665.4047241	1.47
668.1472778	0.12
669.2420654	0.35
671.5464478	0.33
673.4802856	0.17
675.651062	0.20
679.2994995	1.47
685.2268677	0.37
696.687561	0.08
697.3530273	2.70
698.7437134	1.02
715.2184448	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1755
Annotation	Bis-gamma-glutamylcysteinylbis-beta-alanine
Peak:m/z	Relative Intensity
178.0760193	0.11
178.8968658	0.24
184.9827118	0.12
189.0583496	0.18
191.2524414	0.40
195.9904938	0.91
196.9338989	0.23
203.0137177	0.09
223.9470978	0.63
228.0752869	0.13
240.1344910	0.15
242.1264954	0.11
247.8955994	0.15
249.9677429	0.33
256.1621704	0.13
268.0839539	5.41
286.2018738	20.31
299.8713989	0.36
301.9920044	5.64
303.9771729	0.07
318.1520996	16.50
320.1331177	100.00
333.7288513	0.25
352.0281372	35.19
355.7578125	0.14
356.9404297	0.09
374.9466553	0.07
381.1279907	0.37
389.0352783	0.15
492.2035522	3.36
510.1760864	68.33
526.3395996	0.14
531.1231079	0.34
547.1206665	0.11
567.0039062	0.06
592.9816284	0.18
603.2129517	1.22
621.1311035	33.54
621.7816162	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.192
Annotation	Sachaloside VII
Peak:m/z	Relative Intensity
161.0278931	0.36
165.0504303	0.08
178.8678894	0.32
187.1776428	0.12
248.9328003	0.09
250.8102112	0.05
267.9758911	0.13
272.9436340	0.04
277.3654175	0.03
284.9066772	0.02
288.2079773	0.11
306.7914124	0.08
322.9607544	0.06
331.2907104	0.03
333.2332764	0.22
338.4146118	0.12
349.1369934	100.00
351.0473938	0.47
359.2780151	0.05
376.3764343	0.34
377.3962708	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9191
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0091705	0.06
158.9531860	2.03
159.9391479	0.82
160.9379272	0.05
199.0028687	0.78
200.0614014	0.21
217.0682678	0.22
217.8734741	0.19
228.8954926	0.80
229.8602600	0.73
272.9233704	43.82
273.9723511	28.42
354.2344360	0.12
384.5976562	0.13
385.2754211	0.16
386.8881226	67.39
387.8510132	100.00
388.5285339	0.17
420.1716614	0.08
427.2637329	0.04
427.9073181	0.23
434.9693604	0.04
439.7630005	0.06
443.2020264	0.10
445.7362671	0.07
455.2510071	0.10
456.1809387	0.66
457.0326843	0.08
457.8927307	0.09
458.9058533	0.03
460.8003235	0.06
472.1166382	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.166
Annotation	Fibraurinoside
Peak:m/z	Relative Intensity
181.2132263	0.02
185.1336060	0.02
191.1052551	0.02
204.8886414	0.01
211.3352966	0.03
281.1000977	0.04
282.0879517	0.05
283.1578979	0.01
294.3995056	0.04
297.5216675	0.02
299.3098755	0.04
309.1428833	0.29
322.0881958	0.04
323.1268921	0.14
327.3341675	0.09
335.0899658	0.01
338.1560059	0.08
341.1455078	36.20
341.7839966	0.04
353.1417236	100.00
353.7552490	0.19
363.1879883	0.01
365.1508179	0.10
366.0325928	0.04
369.1276855	0.13
370.3099365	4.80
370.9298096	27.66
371.5906982	0.08
375.4733276	0.04
377.1931152	0.05
389.1260376	0.44
395.1672363	0.02
406.2280884	0.10
407.2968140	0.09
412.2692871	0.24
413.0899658	0.16
417.4860840	0.02
426.0943604	0.04
426.9523926	0.02
428.7540283	0.04
431.2436523	0.08
432.3469238	0.25
433.0891724	0.02
437.0569458	0.02
442.9005737	0.21
445.2040405	0.17
446.0476685	0.08
448.4360962	0.04
450.1593628	0.05
452.2258911	0.21
453.2287598	0.08
456.9027710	0.03
458.1591797	0.03
459.1663818	0.07
467.1493530	0.07
469.2114868	0.16
471.3269653	0.13
472.2668457	0.03
472.9312134	0.01
478.7083130	0.05
486.0159302	0.33
487.0386963	1.67
488.0790405	0.24
489.1609497	2.00
490.4340210	0.01
491.4605103	0.04
493.1958618	0.07
495.2192993	0.02
503.0697632	0.22
503.6844482	0.01
504.5490112	0.02
514.2167358	0.14
515.1472778	0.09
516.4964600	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Herbacetin 8-(2'',3''-diacetylxyloside)
Peak:m/z	Relative Intensity
174.7947693	0.04
192.1854553	0.15
217.2947693	0.14
227.8886108	0.08
244.0908203	0.06
269.1745605	0.03
271.1116333	9.65
278.9344482	0.04
297.1695557	0.25
305.8843994	0.40
307.2599487	0.18
312.2127075	0.06
313.1315308	0.38
314.1428833	0.04
321.2247925	0.04
330.1887817	0.09
332.1166992	0.04
337.4896851	0.05
349.3995361	0.04
361.7333374	0.11
367.1843872	0.07
377.1492920	0.10
379.2044678	0.06
381.3304443	0.36
387.1316528	0.12
393.3856201	0.04
397.5794678	0.07
399.0651855	0.40
403.2229614	0.15
414.5780029	0.18
415.1825562	1.56
416.0046387	0.14
417.1834717	1.45
427.1323242	0.23
431.0806885	0.19
433.0517578	100.00
433.6846313	0.50
434.6163940	0.04
440.1846313	0.25
445.7539673	0.04
448.4700317	0.02
456.9949951	0.20
458.9844971	0.05
459.8967896	0.14
462.0683594	0.03
462.9346924	0.21
464.1928711	0.18
465.3335571	0.06
473.0940552	0.22
475.5273438	0.05
478.4487915	0.15
483.0876465	0.06
485.4368896	0.21
489.2758789	0.02
495.0664062	0.41
496.1223755	0.02
499.6332397	0.13
501.3767700	0.19
507.1606445	0.45
510.0887451	0.27
513.6119995	0.17
514.6599731	0.05
515.4077759	0.35
517.4225464	0.07
519.2075195	0.04
525.6535034	0.05
533.1454468	0.23
534.3574829	0.03
535.6001587	0.26
540.3884277	0.03
542.5953369	0.10
543.4779663	0.12
546.2133789	0.09
546.8762207	0.17
547.9678955	0.19
548.7648315	0.25
552.5233765	0.62
560.3010254	0.56
561.1185913	2.00
562.2032471	0.07
570.1789551	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1702
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
190.9302521	0.11
202.017807	0.05
240.9052734	0.09
243.2226257	0.12
250.2449646	0.03
254.7633209	0.04
255.7823792	0.09
269.4056396	0.02
270.1075439	0.11
271.0275269	1.86
272.2384644	0.04
277.1047974	0.08
282.9691772	0.23
285.1748047	0.94
288.7236328	0.08
291.2021484	0.56
295.0400391	0.10
313.1691895	5.37
320.4782715	0.05
327.196167	0.05
331.1219482	0.16
337.1154785	0.16
341.3756714	0.23
343.1170654	0.05
345.1453857	0.03
355.1551514	0.05
355.894043	0.07
367.0738525	0.55
373.1291504	0.03
375.2738037	0.03
379.2825317	0.05
385.1793213	0.04
387.3184204	0.06
388.9492188	0.11
397.2037964	0.86
398.4391479	0.12
399.1335449	0.15
400.9226685	0.08
405.1155396	0.07
409.105957	0.42
410.7192383	0.04
415.1878662	12.24
416.1912231	0.80
417.1005249	1.85
418.2879639	0.04
419.208374	0.09
423.0540161	0.17
427.3654175	0.15
430.5297852	0.03
431.5122681	0.22
433.1078491	100.00
433.928894	0.49
435.0683594	0.05
441.4898071	0.10
447.1592407	0.03
449.3797607	0.10
450.1934814	0.02
453.1466675	0.60
454.5390625	0.20
457.3901367	0.32
458.2318115	0.06
459.2366333	0.52
464.8873291	0.05
471.9650879	0.10
475.3386841	0.05
476.9862671	0.14
482.8835449	0.09
486.9351196	0.09
488.079895	0.13
488.8676147	0.06
492.3240967	0.05
493.1348267	0.02
495.3902588	0.10
499.2387695	0.31
512.9993286	0.50
515.9605103	0.09
525.2006226	0.63
530.1065063	0.21
531.1056519	0.08
532.3706665	0.04
533.0566406	0.12
534.7166138	0.11
535.4137573	0.03
538.0077515	0.39
542.3143311	0.31
543.1517334	0.42
547.1195679	0.09
549.4923706	0.46
552.0891724	0.50
560.190918	2.40
561.1387329	5.62
561.7617798	0.05
563.8602905	0.17
579.3535156	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1188
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
107.8130035	0.03
112.8653488	0.10
119.1093903	0.06
122.9658356	0.66
131.2613525	0.03
135.0733643	0.01
135.9401245	0.60
136.9657593	0.03
142.9986267	0.03
147.1114197	0.02
149.0701294	0.02
150.9138031	0.46
151.5210419	0.03
153.0504150	2.87
159.0264893	0.04
161.0347290	0.05
177.0730743	0.18
192.3825684	0.08
193.0235291	0.15
194.9759369	100.00
195.5899048	0.13
206.9212341	0.01
209.1131287	0.10
219.1936340	0.08
234.9627991	0.03
236.9947815	1.50
249.0389404	0.23
266.9180908	0.20
279.0726624	0.01
281.2450867	0.02
296.7937012	0.24
297.4288330	0.01
310.7182007	0.02
314.3212891	0.02
315.3650513	0.02
327.0436401	0.02
339.2209167	0.09
342.0686951	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.2069
Annotation	7S,8S-DiHOTrE
Peak:m/z	Relative Intensity
95.0268784	0.11
96.6556854	0.05
109.1145020	0.17
110.9502106	0.12
113.1889191	0.21
122.1740112	0.08
123.0083389	0.25
126.9964676	0.16
129.0337830	0.43
134.8849030	0.12
137.3272705	0.07
141.0411224	0.29
149.1906738	0.07
154.9911194	0.34
159.2531586	0.03
161.2972412	0.02
163.1927185	0.11
167.1942444	0.68
171.1223297	0.04
177.1855316	0.50
179.1641846	0.14
181.0041656	0.25
193.0414429	0.14
195.1279297	13.49
197.2256470	0.09
203.2878418	0.08
205.1564636	0.16
207.1018066	0.20
209.3345032	0.04
211.1030884	0.13
217.3597107	0.05
221.0993958	0.03
223.0549622	0.14
226.9260254	0.04
228.8533325	0.05
231.2652283	0.08
233.1887817	0.69
235.3881836	0.17
236.6045837	0.03
238.1180115	0.09
241.2592773	0.12
243.0075989	0.11
245.3576050	0.12
247.1583252	1.30
247.7909546	0.10
251.1145630	2.63
253.2713928	0.08
263.1984253	0.18
265.1152954	0.88
273.2065125	0.65
279.5414734	0.07
281.2379150	0.39
283.1906128	0.12
287.2138367	0.03
289.2914124	0.74
291.2152710	100.00
291.8509827	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1119.5558
Annotation	Camellioside D
Peak:m/z	Relative Intensity
337.1266479	0.14
437.4756470	0.96
438.6057739	0.15
457.3486023	1.58
536.3863525	0.32
571.7706299	0.09
601.5053711	0.38
619.4968262	1.78
671.4461060	0.12
687.3913574	0.23
689.0285645	0.13
713.4199829	1.42
716.3117676	0.55
719.2935791	0.70
720.3925781	0.26
730.6355591	0.22
733.4434814	14.94
734.5767822	3.14
735.6024780	1.53
751.0583496	1.05
752.0859375	2.03
752.6861572	0.21
753.4697876	0.09
759.5288086	0.65
760.4448853	0.12
761.2484131	0.10
767.4573975	0.15
775.3996582	0.15
777.6766357	2.51
778.5019531	0.64
779.3984375	1.63
781.5295410	1.30
783.5236206	0.52
795.6134033	1.73
796.6136475	1.46
811.5581055	0.35
813.5914307	0.48
829.4505615	0.24
830.7418213	0.24
863.2550049	1.06
863.8991699	0.39
875.3732910	0.69
877.4829102	1.59
878.6264648	0.46
879.6025391	0.13
882.8215332	0.17
884.9730225	0.21
892.5042725	0.19
895.5021973	11.78
896.5141602	4.66
898.6024170	0.89
903.5180664	10.32
904.5373535	3.42
913.2580566	2.29
914.3913574	0.83
921.4106445	3.60
922.6218262	0.65
937.2797852	0.70
939.4974365	13.27
940.6071777	4.39
941.5096436	0.38
944.4008789	0.30
957.4676514	56.15
958.5529785	33.18
959.6052246	1.07
965.8168945	0.27
971.4085693	0.19
999.6054688	0.66
1000.7319340	0.25
1011.5023190	0.17
1040.0639650	0.13
1057.6330570	7.69
1058.6448970	3.02
1066.8791500	0.80
1075.4345700	0.32
1083.5183110	5.67
1084.3889160	1.93
1087.8715820	0.38
1089.6868900	0.71
1090.3652340	0.32
1101.4851070	100.00
1102.5214840	51.49
1103.5023190	3.62
1104.5571290	0.12
1105.8752440	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1117
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
138.7717133	0.04
271.0272827	0.04
283.1096191	1.66
295.1229858	2.74
307.1108398	0.05
310.9324036	0.09
313.0733643	16.18
314.0790405	0.01
325.3267212	0.03
333.0015259	0.04
337.1257324	7.61
338.2072144	0.04
343.1318359	1.56
348.9745483	0.14
351.0837097	0.54
361.0353699	0.13
367.0602112	20.71
367.9273376	0.10
379.1759338	5.84
397.1360168	24.51
398.3284302	0.04
415.1452637	100.00
416.1839600	0.72
416.8850098	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1036
Annotation	Zidovudine
Peak:m/z	Relative Intensity
91.8965149	0.02
118.8936768	0.10
120.7666779	0.46
121.9069519	0.45
133.1471558	0.01
135.9263763	100.00
136.7957458	0.10
137.9619598	0.40
138.9089508	0.42
149.8608856	0.17
151.0723572	0.25
152.2009125	0.03
177.8243256	0.06
222.0368042	0.06
227.0582733	0.05
231.9560089	0.01
250.1658173	0.17
251.1041107	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2491
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
175.1409302	0.13
198.9374695	0.06
217.2684479	0.10
221.1093140	0.15
245.3492584	0.06
251.2911377	0.17
259.2540283	0.11
267.5502625	0.12
273.0836487	0.17
275.1793213	0.26
277.1642456	0.13
279.0525513	0.06
285.2807312	0.40
287.1469727	0.34
293.2154541	0.11
295.2419434	0.09
303.3027039	0.83
304.7759399	0.08
319.2528687	0.11
321.2897339	7.60
322.3084717	0.14
332.0939331	0.04
337.5061646	0.04
341.0253296	0.06
345.3087158	0.07
347.2957153	8.76
348.0086670	0.46
351.4861450	0.07
363.3500366	0.31
364.2799683	0.12
365.2028198	2.65
366.2708740	0.06
367.2537231	0.14
369.5095825	0.03
391.1392212	0.13
394.4796143	0.62
398.3325806	0.06
401.5420532	0.02
403.0747681	0.08
404.2266235	0.04
407.0852661	1.03
419.2066650	0.12
422.1317749	0.19
423.0084839	0.06
425.3248901	0.42
435.4708252	0.03
437.0912476	0.25
438.4697266	0.16
441.1176758	0.24
447.2058105	0.37
448.7318726	0.16
453.1240845	0.05
455.3301392	0.54
461.0093384	0.11
463.2985840	0.23
465.3613892	0.30
467.1871948	0.06
479.2974243	0.07
480.8104248	1.33
481.5017700	1.22
483.2606201	100.00
484.3141479	6.00
485.3167114	0.08
491.1525269	0.13
492.1178589	0.04
497.4404907	0.13
498.9562378	0.18
508.7606201	0.77
509.3979492	4.67
510.4267578	0.38
518.5833130	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	669.2761
Annotation	Unknow
Peak:m/z	Relative Intensity
255.2072906	0.39
257.1513367	0.11
277.0944824	0.10
287.2966309	0.21
291.3244629	0.49
305.0686646	0.79
313.2623596	0.03
315.3805542	0.05
317.2144470	0.04
321.1492920	0.12
327.1030884	0.13
341.3129272	0.10
348.9399414	0.05
361.2842407	0.90
363.1680908	100.00
376.3970947	0.11
377.2692261	4.19
387.0287476	0.54
391.2766724	0.44
400.9854736	0.07
403.3271484	0.13
405.2362671	5.33
409.3699341	0.18
416.9002686	0.20
419.3599854	0.09
431.3396606	0.07
432.4570923	0.09
433.3387451	0.13
434.9813232	0.31
441.5545654	0.07
445.2311401	0.70
447.3536377	0.52
448.4677124	0.03
451.4188232	0.18
465.2251587	0.14
477.4602661	0.14
479.6520386	0.19
487.3705444	0.23
489.1077271	0.59
491.2666016	0.09
497.4020996	0.08
506.0629272	0.24
507.2163696	9.22
513.3612671	0.18
524.4486694	0.63
525.0929565	9.54
539.1089478	0.06
549.2968140	0.48
552.1346436	0.08
555.5545044	0.15
565.5944214	0.10
566.9469604	0.60
568.5172729	0.07
577.3455200	0.30
579.0748291	0.42
581.5361938	0.13
583.3104248	0.16
587.4865112	0.07
591.5063477	0.05
594.5539551	0.12
597.4121094	0.17
606.2567139	0.23
607.0382080	0.07
608.7148438	0.17
609.3994141	0.08
618.9226074	0.24
623.0687256	0.53
624.5297241	1.40
625.2249756	5.92
626.2015381	0.98
627.6925659	0.13
631.2627563	0.07
644.5900269	0.40
651.3288574	0.86
652.3647461	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.18
Annotation	Estramustine
Peak:m/z	Relative Intensity
146.8572693	0.11
154.8864441	0.12
156.9348755	0.66
174.9494629	0.68
189.0010986	0.24
191.0421448	0.32
195.0263367	0.28
201.7931061	0.09
222.9712219	0.08
228.1292114	0.15
244.9537354	0.21
247.3338013	0.83
248.1277161	0.62
256.8043213	0.06
258.9553833	0.29
269.0024109	1.72
270.7246094	0.11
272.1849060	0.30
275.1027222	0.23
277.0941162	0.94
278.0182800	0.09
280.2434387	0.16
280.8715515	0.27
286.4120483	1.12
287.0481567	1.87
290.1253052	0.28
293.1850586	1.28
293.9572754	0.67
304.9534302	4.98
305.9347534	0.77
307.3019104	0.18
311.0737915	6.06
315.0049438	0.37
315.8451843	0.55
321.7167969	0.20
322.7860413	2.08
332.9494019	1.42
334.0462341	3.82
335.6962280	0.97
336.4600525	0.15
337.1057434	0.20
338.0883789	0.36
344.0258789	0.92
347.7745361	0.73
349.8685303	0.73
350.9449768	0.16
360.2290039	0.65
361.1103821	0.28
366.2641602	0.33
373.2188110	0.07
377.4065552	1.58
378.1265259	1.09
378.7461853	0.57
380.1870117	1.11
381.0395203	0.15
383.9690247	0.08
394.0148010	10.17
395.1904602	10.51
396.0466003	100.00
396.8294373	0.26
399.4188232	0.15
400.3628235	0.24
403.0179749	0.71
404.0313110	4.78
405.1718445	0.10
407.9557190	0.24
408.8403931	1.10
417.6195374	0.77
418.6428223	0.93
420.1282043	0.76
421.8977356	60.91
422.7763367	1.21
424.9409485	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	648.3863
Annotation	1-Palmitoyl-2-(5-keto-8-oxo-6-octenoyl)-sn-glycero-3-phosphatidylcholine
Peak:m/z	Relative Intensity
213.8332214	0.23
226.9248199	0.76
227.6822968	0.25
238.1208191	0.07
239.0450134	0.06
248.2396393	0.07
262.5808105	0.22
263.2822571	0.09
302.3695984	0.04
303.1835327	0.12
305.2677917	0.05
307.3743286	0.08
319.6979370	0.05
334.5892334	0.14
337.3760986	0.23
368.2368774	0.34
373.5692139	0.13
381.0598145	0.10
386.3564453	0.19
393.4978638	0.26
396.6295776	0.09
418.2666016	0.04
425.4643555	0.21
451.3100586	0.23
460.2455444	0.29
464.7647705	0.12
468.2691040	0.53
475.7255249	0.70
478.2255249	0.14
483.2059326	0.07
487.2910156	0.07
489.3269653	0.05
504.8720093	0.16
507.3374634	100.00
528.1118774	0.07
532.6976929	0.09
542.6574097	0.19
548.3159790	0.12
550.4331665	0.14
557.8312988	0.17
562.8836060	0.04
564.4302979	0.38
571.1301270	0.04
573.8167725	0.05
578.2212524	0.13
587.1662598	0.14
588.6868286	0.11
598.7536011	0.11
605.1552734	0.62
612.4174194	0.13
630.3246460	3.28
631.0422974	0.17
647.8523560	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.3228
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9580383	1.37
195.0773315	0.33
201.3721008	0.05
203.0012665	0.20
215.0320740	0.19
233.0624084	0.11
239.2108765	0.09
244.4877777	0.16
245.1810608	0.17
255.2599182	0.14
259.0760803	0.05
269.2229004	0.18
273.4299011	0.27
277.2692871	30.41
280.8493347	0.19
283.6011353	0.09
284.3057251	0.12
285.2810669	0.10
287.3676758	0.19
291.1598511	2.59
293.2999878	0.26
295.2576294	0.12
298.3578491	0.10
301.0264893	0.18
308.1923523	0.13
310.3804321	0.11
318.4473267	0.20
319.1491699	2.13
323.0365601	24.37
323.6576538	0.16
324.8665771	0.04
327.1748657	0.12
331.2139282	0.14
341.1665039	100.00
349.1964722	0.23
353.2355957	0.14
361.3812866	0.11
373.2120361	0.20
379.1066284	0.58
420.3024292	0.14
421.2020264	0.09
429.2451782	0.10
439.1812744	0.57
462.1737671	0.16
480.9364014	0.35
493.2927856	0.17
497.2312012	0.08
503.3679199	0.19
512.3166504	0.09
523.0766602	0.07
537.2963257	0.09
541.1107788	0.30
554.3165283	0.09
555.4487915	0.17
557.7592163	0.16
566.3947144	0.32
567.2377930	0.45
582.7465820	0.24
583.4574585	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2609
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
217.0854645	0.02
233.3536072	0.06
251.1046906	0.07
255.3217010	0.14
256.1388245	0.07
263.5702515	0.08
274.5255127	0.04
279.3515015	0.27
280.2933960	0.13
283.2443542	0.14
291.1903687	0.17
292.4248962	0.25
293.3138428	0.07
294.2498169	0.12
295.3289185	0.21
297.3829956	0.04
309.1998901	0.53
310.1920776	0.66
311.3244019	0.28
312.4766235	0.22
313.4625854	0.10
314.4011230	0.12
327.4486084	0.07
329.2262573	0.09
336.3383789	0.09
342.9860229	0.02
348.5911255	0.02
369.2007446	0.13
375.0803223	0.05
390.7005005	0.10
410.4783325	0.08
425.4427490	0.07
428.2708740	0.05
446.2624512	0.03
460.4166260	0.07
463.1967163	0.05
467.2684937	0.07
471.8935547	0.02
484.5587158	0.02
489.2468262	0.03
493.3478394	0.03
501.1734009	0.07
503.6961060	0.13
509.3743286	0.03
513.4163208	0.09
515.2820435	82.40
515.9284058	0.26
518.3044434	0.20
519.4805298	0.24
527.4338989	0.08
529.3897705	0.16
530.3201294	0.03
532.3759766	0.35
533.1803589	0.14
537.5357666	0.52
545.2886353	0.12
546.2653198	1.44
547.4131470	2.50
549.3987427	0.07
555.6116333	0.11
559.1298218	100.00
559.8452148	0.27
562.5443726	0.06
563.5567017	0.08
571.1527710	0.04
572.2130737	0.51
573.4771118	1.58
574.7911987	0.05
575.6189575	0.14
576.7941895	0.04
604.5245361	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	334.1078
Annotation	gamma-Glutamyl-S-methylcysteinyl-beta-alanine
Peak:m/z	Relative Intensity
108.9271851	0.07
112.9309692	0.36
127.9657593	21.10
140.1510315	0.12
152.0332336	0.30
153.0892944	0.52
157.0046539	11.83
158.3025208	0.10
159.0627747	0.44
169.0712433	0.12
170.9652863	0.21
178.0418701	1.75
179.0469818	6.06
183.3607178	0.33
183.9884338	3.38
184.9981384	4.98
196.0826111	10.93
197.0853882	2.35
197.9305115	0.13
199.0064697	0.15
204.9888611	9.07
214.0363464	0.57
217.1266174	0.21
218.0617371	0.28
219.2052612	0.41
224.0744934	5.18
225.3505859	0.16
226.1418762	1.02
227.1258240	1.30
242.1190796	3.12
244.1555481	2.44
250.0573730	0.82
251.1191406	0.06
256.2353210	0.46
262.1579590	2.02
268.0118713	91.58
268.6412659	0.78
270.7463379	0.12
273.3925781	0.11
282.0714111	0.36
286.1675110	100.00
288.2471619	0.09
291.4142456	0.10
292.1372986	0.14
300.1079102	0.41
305.9535522	0.19
316.0305481	90.08
317.1665344	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2198
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
162.9869843	0.38
201.1653137	0.03
205.0601959	0.02
210.9437714	0.04
213.4131775	0.03
234.7348633	0.14
241.1433868	0.24
243.1286163	0.03
249.1748657	0.03
264.6816406	0.34
271.0221558	0.02
285.0724487	0.13
299.1793213	0.03
307.0607910	0.09
314.9736938	0.02
320.1264038	0.01
322.3498535	0.03
323.9680786	0.01
324.8914185	0.49
328.8569336	0.14
330.2650146	0.06
331.6683960	0.01
343.2328491	0.14
344.9666748	0.02
347.3019409	0.01
359.1409912	0.09
361.1540527	100.00
361.7634277	0.43
365.2095337	0.04
377.3662109	0.06
379.1759033	0.01
385.1751099	0.01
386.1002808	0.02
393.0151978	0.02
396.1328125	0.02
402.2072754	0.07
403.2293701	0.52
421.3903809	0.03
433.1761475	0.27
459.0316162	0.02
463.2583618	0.13
466.9905396	0.07
470.4314575	0.06
477.1176758	8.58
478.1710815	0.04
478.9020386	0.01
487.4639282	0.07
490.2025757	0.05
495.4801025	0.03
504.9626465	0.23
506.6368408	0.04
507.3547974	0.02
507.9983521	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.2837
Annotation	Ceriporic acid B
Peak:m/z	Relative Intensity
104.9092102	0.13
107.0002747	0.14
109.0765991	1.32
110.8845825	0.08
112.8663177	0.11
114.9127274	0.08
116.8305664	0.18
118.9577179	0.17
120.9426880	0.42
122.9901810	0.59
124.8984680	0.36
126.9295273	0.26
128.9453125	0.21
130.8199768	0.22
132.9918213	0.46
135.0895538	1.55
136.9720001	0.71
138.9674988	0.26
140.9528198	0.24
143.0588074	0.36
145.0762024	0.08
146.9846344	0.71
149.0827026	1.69
151.0441895	1.05
152.7936096	0.61
155.0954285	0.15
156.9345093	0.40
158.9908142	0.43
160.9952698	0.82
161.8838501	0.03
163.0782013	0.77
164.9611206	1.81
166.9785614	0.20
169.0900574	0.16
171.0793457	0.92
173.0914459	0.19
175.1421509	1.03
177.0479431	0.89
178.3257751	0.09
179.0080414	1.06
179.7196655	0.07
181.1893768	0.21
182.2148743	0.14
183.0154419	0.15
184.2100525	0.21
185.1063843	0.80
187.0257568	0.39
189.0439453	1.13
191.1380005	0.11
192.9441223	1.27
195.0242920	0.07
197.1877899	0.43
198.1197815	0.09
199.1483154	0.30
200.3004761	0.06
200.9840393	0.30
203.0896606	0.59
204.9340820	0.14
207.0916748	1.38
207.9542694	0.10
209.2468872	0.16
210.9852600	0.84
213.1899109	0.55
214.9784851	0.13
217.2349243	0.35
219.2648926	0.22
221.1228027	0.50
223.2433472	0.74
225.1363525	2.05
227.0942993	0.21
228.8806458	0.24
233.2683411	0.21
237.5840454	0.33
239.1425171	0.93
240.9343567	0.68
243.1891479	0.60
245.2269897	22.99
247.2114868	3.89
249.1034851	0.08
251.5366211	0.03
253.1295776	0.28
255.2449951	0.51
259.2839966	0.64
261.2160645	1.41
263.1477966	51.81
263.7734375	0.30
265.2024231	10.95
267.0735474	0.86
268.2053833	0.13
269.2462158	0.15
270.9506531	0.31
272.9968872	0.31
277.9321289	0.31
280.5737000	0.96
281.2212524	7.60
283.2048950	1.66
285.1846313	0.26
287.1900024	0.07
291.2378235	0.05
293.2285767	0.16
295.2573242	0.63
296.2684326	0.31
297.1075134	0.03
298.1379089	0.07
299.0925903	1.46
300.1804504	0.04
301.1883545	0.40
303.3004150	0.03
308.3974609	0.06
309.1791077	0.83
311.3819580	0.38
313.0303955	0.27
313.7512207	4.66
319.3345032	2.73
320.2530823	0.07
323.1823120	0.04
327.3832397	0.48
329.8975220	0.06
331.2224121	0.60
331.9409180	0.20
332.9250488	0.02
337.2291260	100.00
338.0269165	0.54
345.7998047	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1726
Annotation	Unknow
Peak:m/z	Relative Intensity
171.9583893	0.25
174.0461273	0.08
184.3049927	0.04
187.9547729	0.12
199.9696655	0.62
202.0517731	6.28
217.9999237	0.99
218.9838715	0.60
244.0307770	1.10
256.7617798	0.08
260.7859497	0.30
261.9729919	100.00
320.1817017	0.04
341.1929932	0.13
383.0905151	0.09
384.3648682	0.13
387.3784180	0.10
388.0911255	0.15
411.1396484	0.13
439.2578735	0.05
466.6547241	0.06
471.0642090	0.12
504.3930054	0.08
505.3455200	0.09
543.3489990	0.42
560.1666870	0.06
586.1847534	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1039.6691
Annotation	Unknow
Peak:m/z	Relative Intensity
337.3750916	0.74
443.2517090	1.10
444.3460693	0.26
502.3520508	34.39
503.4208984	10.25
520.3430176	100.00
521.3240967	25.90
522.0072632	0.04
534.3862305	6.62
535.3026123	1.80
605.4986572	0.04
623.2077026	10.03
624.3156128	2.78
626.6911621	0.15
643.8382568	0.16
644.5567627	0.07
703.4378052	0.19
704.3094482	0.06
857.2078857	0.28
899.2652588	0.06
979.8364258	0.26
980.6578369	1.36
981.6555176	0.27
1021.4453120	0.82
1022.2945560	0.07
1039.8040770	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9706879	0.11
100.8958588	4.18
102.9858398	0.58
106.7424927	0.31
112.9089432	14.17
114.9417114	0.62
116.9346542	0.14
118.9382553	13.18
124.8931274	2.88
129.8094635	0.09
130.8600922	5.66
142.9628906	17.95
148.9711609	3.56
160.8818054	20.52
176.7860870	0.15
178.9010468	100.00
250.9558105	0.18
263.0205688	0.43
280.9132690	2.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0929
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
133.1189423	0.02
138.7869568	0.04
150.8908691	0.09
161.0950928	0.08
165.0611572	0.14
183.1089935	0.04
224.2198792	0.04
243.0521851	0.05
249.2216187	0.09
263.1520996	0.03
266.9735413	0.04
275.1379089	0.03
278.9942017	0.02
285.0408936	100.00
286.1455688	2.06
299.1075134	0.07
300.7739868	0.04
307.6075745	0.02
327.0505676	17.64
327.9877625	0.12
339.0174561	0.05
345.3677368	0.08
348.5090332	0.02
355.2975769	0.05
357.1168213	2.07
369.1666565	0.45
371.3226013	0.06
373.348053	0.03
379.1682129	0.02
380.1447144	0.04
380.9030151	0.09
385.3211365	0.06
387.2419739	0.64
393.1481628	0.10
399.3049316	0.16
400.9767761	0.02
403.3152771	0.29
405.20224	0.04
411.0874329	0.32
419.2740784	0.03
429.2678528	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1657
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.7582092	1.74
118.9458771	1.19
124.9511719	0.39
130.7908325	1.93
135.2267761	0.15
142.0423584	0.09
143.1092682	1.84
145.1048584	1.11
147.0868225	0.15
148.9270325	0.62
149.9145050	0.24
153.0863037	0.45
160.6571655	0.68
163.0239563	41.12
179.1487579	0.20
189.2037201	0.27
207.0870819	100.00
209.0831909	1.27
224.9380188	3.18
249.1206055	0.13
287.2796326	0.27
369.2019348	21.62
370.2304382	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.13
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
64.9155579	0.02
66.8598557	0.60
69.0905151	0.02
70.9803162	0.14
77.0949860	0.04
79.0897446	0.03
80.9914856	0.08
83.0285721	0.04
84.9226837	8.97
90.9934235	0.11
92.9821472	0.03
94.9250336	0.10
96.8735199	0.08
98.9804840	0.70
100.6802673	0.01
105.3903198	0.03
107.1065369	0.07
109.0101776	0.28
110.8297882	0.47
112.9284973	0.12
114.9020538	0.03
119.1001282	0.59
120.9582367	0.45
123.0211792	0.01
124.8570709	0.29
127.0121460	0.20
128.8937988	0.48
130.9587402	0.78
133.0295715	0.18
135.0826111	0.19
137.0110168	0.02
139.0206757	0.24
140.9792633	0.15
143.0526276	1.12
145.0810852	2.60
147.0580139	0.32
148.9347076	1.42
151.0951691	0.02
155.2016144	0.13
157.1027374	0.06
158.3491974	0.04
159.2335663	0.06
160.8000641	0.03
162.9066315	2.25
165.1442566	0.32
167.0360413	5.18
169.0709076	0.62
173.0142670	0.11
176.0291595	0.02
179.0655975	0.44
180.9900055	0.22
182.2048492	0.04
182.9731445	0.15
184.0940399	0.03
185.0951385	0.26
185.9612579	0.01
190.9987946	39.42
195.0446320	0.10
197.0693665	0.41
199.0221558	0.11
201.1797943	0.05
206.0648041	0.22
206.8002319	0.20
209.0764771	100.00
211.9937286	0.09
214.8195801	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.2184
Annotation	Saframycin B
Peak:m/z	Relative Intensity
157.0443420	0.20
166.1931305	0.86
177.3501282	0.06
183.9130249	0.11
186.9575195	0.09
189.7872314	0.09
191.9105530	0.06
204.1651764	0.29
206.2521362	0.05
210.2658539	0.11
215.3421021	0.07
222.0279083	0.16
245.3690338	0.08
247.1571198	2.23
250.1117249	0.03
257.1396179	0.19
259.9719543	0.60
263.9756470	0.17
267.1157837	0.07
270.1431885	0.04
273.2281799	1.96
277.2633667	0.04
278.0223389	0.03
283.0674133	0.04
291.9522095	1.60
293.2319336	0.13
311.0408936	0.04
312.1802368	0.06
315.3169556	0.06
323.2899170	0.12
325.0913696	2.05
329.1776123	0.10
330.9715576	0.07
338.8454590	0.27
341.1602783	2.32
342.7294922	0.07
347.1432495	0.10
350.5263062	0.08
352.9118042	0.29
355.4240112	0.09
357.0661011	1.90
364.1173096	0.33
365.4140625	0.06
373.0436401	11.08
377.2843018	0.15
379.3164062	0.19
380.2058105	0.18
382.3482056	0.06
383.2917480	0.09
384.1993408	0.13
385.1381226	2.48
397.2982788	0.26
407.1491699	1.80
409.0398560	0.04
414.7276611	0.04
421.6179810	0.13
424.2069702	0.08
425.3521729	0.07
426.3001709	0.06
429.1948242	0.10
434.0859375	0.03
437.3469849	0.12
438.5664673	0.05
442.3188477	0.08
444.4527588	0.20
447.0986328	0.05
450.1083374	0.12
450.8216553	0.26
453.3513794	0.14
455.9036255	0.11
457.2095947	0.43
458.9191284	0.10
462.4260864	0.31
464.2016602	0.34
465.3153687	6.47
466.5155029	0.15
476.4605103	0.27
478.2297363	0.95
485.2426147	0.11
486.2623901	0.09
488.0827026	1.42
489.3446045	0.13
490.0671997	0.12
491.8859253	0.25
492.5258179	0.06
493.4063110	0.22
496.4878540	0.24
499.4431763	0.28
500.7757568	0.08
506.1433716	100.00
506.8544312	0.31
507.9979248	0.19
510.2719116	3.38
510.9484253	0.38
519.4125366	0.17
520.3031616	5.62
521.2039185	0.21
528.8246460	0.23
529.7424927	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.25
Annotation	Unknow
Peak:m/z	Relative Intensity
184.0080872	0.17
185.1391754	0.06
191.0959320	0.21
196.1163483	0.68
196.9152069	0.05
204.7918701	0.06
211.1951141	0.04
212.1063385	0.06
212.9404449	0.07
217.0162659	0.03
219.1555939	0.25
221.0111084	0.08
223.4750061	0.01
224.1139221	0.24
229.0817261	0.05
229.8116455	0.03
231.1019287	0.22
233.2895355	0.02
234.3013916	0.30
235.0099640	0.03
242.2776337	0.24
242.9333496	0.01
246.9757690	0.12
248.0416565	0.12
248.8256073	0.25
256.1392212	0.06
260.2264404	0.08
261.3025818	0.01
264.6862183	0.17
265.3543701	0.01
268.1265564	2.49
268.9890442	0.65
275.2602234	0.17
277.2000732	0.23
278.5275879	0.10
286.1649780	3.18
287.2585144	0.88
289.0275574	0.19
293.0978699	1.89
302.0959473	2.77
303.1859436	0.71
306.9952393	1.91
308.9949951	0.05
316.8944702	0.27
317.6094971	0.01
320.0938721	100.00
321.1414795	20.34
324.9541626	1.24
325.8585815	0.06
327.4497070	0.03
329.4844360	0.04
331.0825500	0.05
333.1199951	0.07
335.0709839	0.18
347.1669312	0.13
349.1543579	0.04
359.1391602	0.02
365.1141968	0.06
376.6068115	0.02
387.3923340	0.03
401.2794189	0.07
405.4931030	0.03
407.3669434	0.17
438.6257935	0.51
439.3919067	0.05
444.8779907	0.02
449.4341431	0.12
453.8737183	0.02
461.1708984	0.03
467.4042969	0.07
473.2211914	0.08
478.1174927	0.02
479.1911011	0.02
480.7570801	0.23
485.0723267	0.09
503.0739136	0.09
509.1786499	0.15
510.0371704	0.11
511.2149048	0.15
512.4852905	0.03
513.3735962	0.04
517.1633911	0.66
518.2057495	0.04
523.2255249	0.56
540.0400391	0.05
541.2986450	0.75
551.2681274	0.26
553.1074219	0.08
557.3757324	0.05
558.3118286	0.11
563.2136841	0.03
567.4008179	0.13
569.3352051	0.06
570.2066040	0.05
571.2139282	0.08
583.2424927	2.65
585.7261963	0.19
587.2218628	0.10
592.9515991	0.03
600.4258423	0.97
601.1110229	10.69
603.4075928	0.05
610.8728638	0.03
615.1369019	0.10
616.4868774	0.11
623.0415039	0.14
628.1002808	0.17
628.9254761	0.11
629.6060181	0.10
638.0549927	0.13
638.6700439	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.2185
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0494537	0.09
162.9971008	5.23
183.0612488	8.42
196.8877869	0.08
205.0897827	1.53
207.0462036	0.95
212.3756561	0.04
225.3042145	0.13
229.0550385	0.12
233.5514832	0.06
234.3289185	1.12
235.0199280	1.17
237.1492920	0.13
247.0474091	0.09
248.7167206	0.10
249.3357391	0.51
255.0567322	0.35
263.7189941	0.31
264.7534180	1.67
267.2102051	0.22
268.8447266	0.07
276.1692200	0.27
280.9920654	0.30
289.1229858	0.68
293.0326538	0.28
307.1602173	10.74
321.5070190	0.12
324.9561768	7.40
327.2468262	0.25
328.8237915	0.43
332.2523804	0.16
334.1904297	0.13
345.0060425	0.11
347.2147217	0.44
349.1261597	0.51
353.1201172	7.29
353.9927368	0.10
356.1901855	0.10
357.2694092	0.55
361.2239990	0.18
371.1074829	0.85
373.7624512	0.35
375.4040527	0.72
387.1840820	0.24
391.2277832	0.03
403.0584106	0.12
413.0435791	0.25
416.1489868	0.17
417.1332397	0.92
418.3428345	0.30
419.2241211	0.55
431.0453491	0.46
436.4101562	0.05
446.9097900	1.11
448.2239990	0.21
450.1407471	0.08
453.1692505	0.14
454.9286499	0.27
455.7149658	0.18
465.0971069	0.08
473.0541992	0.09
474.2852783	0.43
477.2410278	0.28
483.0166626	0.05
491.0577393	100.00
492.1365356	3.05
493.1047974	2.88
501.0711060	0.34
503.3480835	0.10
504.2593994	0.45
505.1405640	0.42
507.1484985	0.13
517.2066040	0.26
517.9324341	0.08
519.2741089	0.93
522.0680542	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1808
Annotation	Neocalycopterone methyl ether
Peak:m/z	Relative Intensity
192.1686249	0.05
213.1080170	0.04
220.3295593	0.03
221.1277161	0.02
246.1618958	0.01
280.7864075	0.02
284.1141052	0.04
286.1851807	0.02
286.8295898	0.05
290.9140625	0.03
330.1094360	0.60
332.1681213	0.01
341.1627808	0.06
344.9962769	0.01
346.3206787	0.02
348.0039062	0.04
352.9557495	0.06
369.3223267	0.02
375.0067139	0.02
383.1915894	0.32
397.0384521	0.03
404.5217285	0.07
405.2758179	0.03
414.3364868	0.02
439.0393677	0.04
442.5558472	0.06
443.3058472	0.01
446.3943481	0.06
449.4066162	0.02
451.3419189	0.08
456.6319580	0.05
459.3977661	0.51
461.0820312	100.00
462.1779175	1.47
463.1066284	1.86
463.8460693	0.02
478.5066528	0.02
485.2203979	0.10
503.0772705	0.09
512.8508301	0.02
535.8698730	0.01
562.6383667	0.11
575.5569458	0.06
578.9677734	0.03
580.2755127	0.03
592.4925537	0.05
593.2564087	0.03
618.3601074	0.04
619.5963745	0.43
620.8048096	0.83
622.1925659	0.26
626.4891968	0.03
646.4509888	1.30
647.4196167	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	596.31
Annotation	Kni 102
Peak:m/z	Relative Intensity
171.0218048	0.32
173.0634155	0.13
174.1524353	0.07
175.1651611	0.15
177.9447021	0.07
178.9234924	0.21
181.0425720	0.05
183.2056274	0.20
185.2044830	0.04
186.2323608	0.08
188.0653076	0.06
189.3270721	0.04
192.1298523	0.08
192.8448181	0.14
194.0608063	0.23
195.0837402	0.07
197.1017151	0.50
198.2932281	0.30
199.1077576	0.29
201.9426575	0.17
204.2586365	0.30
206.2240753	0.26
208.0434875	0.06
209.1660461	0.08
211.2410736	0.18
212.1550293	0.11
213.8424988	0.06
216.9621124	0.04
218.1943359	0.04
220.1816254	0.13
221.9050598	0.41
223.3603363	0.56
225.1965942	0.18
227.1101532	0.11
230.1539612	0.06
231.4907837	0.05
234.0574188	0.06
237.2066193	0.35
237.9831238	0.28
239.2030487	0.24
241.3527527	0.57
242.5549622	0.06
243.2075043	0.19
244.1957550	0.16
247.8807526	0.41
250.0733032	0.49
251.1767426	0.85
252.3536072	0.32
253.4020996	0.31
255.3123627	0.07
256.2042236	0.07
257.1490479	0.09
259.2678833	0.70
260.3393555	0.10
264.2084351	0.23
266.2175293	0.56
266.9944763	0.21
268.1911011	1.54
269.2868958	0.91
270.2586975	0.04
271.2223511	1.71
272.0984802	0.73
273.4375305	0.08
279.6079407	0.16
280.6953735	0.29
283.0932922	3.58
284.1054688	5.06
285.0250244	0.40
286.3020935	0.72
287.0090942	0.03
288.1089783	0.66
290.3348083	0.04
292.2765503	0.24
293.2526245	0.18
295.0069580	4.14
296.1033936	4.50
297.1687622	0.56
298.3200073	0.39
299.1898804	0.23
302.4072876	0.15
303.6010132	0.21
304.4300537	0.03
307.3167419	0.23
308.5532837	0.29
311.3369141	0.06
313.0802612	47.34
314.1206665	66.85
315.7640381	0.87
316.5423584	0.38
320.0202637	0.27
322.1909180	0.05
326.3887329	0.58
327.9047241	0.06
328.5471802	0.29
329.3629150	0.10
330.4717407	0.14
332.0054321	0.05
337.0296021	6.07
338.1632690	10.31
339.1423950	0.16
340.4508667	0.04
342.2235718	0.13
343.3790894	0.21
344.3585815	1.16
345.4244385	0.73
346.3583984	0.18
347.4212646	0.07
348.2563477	0.57
349.1577759	1.21
350.0945435	2.33
352.1049805	0.36
353.3319702	0.09
354.2044067	0.11
355.0808105	0.08
356.4884644	0.07
358.3510742	0.03
360.3480225	0.24
360.9999390	0.20
362.0928955	0.95
363.1846313	0.10
367.0258179	21.50
368.1493530	41.66
370.0641479	1.09
371.1352539	0.03
372.3119507	0.70
375.2433472	0.19
379.2027588	5.51
380.1732788	11.58
388.2352905	3.04
389.4085693	0.92
390.3258667	4.53
391.1097412	0.61
395.0328369	0.07
397.0903931	10.21
398.1384888	26.79
399.1156616	0.33
400.2238770	0.14
402.4174194	0.08
404.2196045	0.05
406.3139038	1.41
407.4802856	0.19
409.2605591	0.05
410.0830688	0.09
415.0939941	39.79
416.0906982	100.00
417.3096924	0.91
418.0817261	0.58
419.1653442	0.12
421.4402466	0.06
430.2074585	0.29
432.4888306	2.54
433.2487183	28.42
434.1736450	94.63
435.2286987	5.49
440.2323608	0.33
449.2166748	1.36
450.1331177	4.47
451.8723145	0.12
453.9359741	0.25
456.3215332	5.16
457.3827515	0.20
464.0701904	0.07
471.8305664	0.11
475.3430786	0.24
476.2574463	0.25
477.2761841	0.30
478.4071655	0.74
480.1938477	0.35
482.2819214	0.25
483.4368286	0.14
490.2366943	0.23
494.2937622	0.13
496.4931641	0.17
497.1482544	0.06
499.1854858	0.02
500.3452148	0.45
504.2363892	0.03
509.4685669	0.10
510.5998535	0.19
514.7178955	0.24
516.7112427	0.30
518.5367432	0.28
521.2851562	0.12
522.9326172	0.21
523.8063354	0.59
527.3831177	0.14
530.2915649	0.28
534.3693848	0.21
535.4039917	0.21
542.3533325	0.10
550.3857422	5.79
551.3546753	1.71
552.3093872	2.44
553.3452148	0.08
558.8358154	0.36
560.1190796	4.45
561.4155884	0.23
564.2892456	0.23
568.3067627	2.00
569.3347778	0.59
573.4024658	0.27
578.0708008	84.10
579.2935181	0.62
585.8287964	0.16
597.1159058	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1281.6089
Annotation	Balanitesin
Peak:m/z	Relative Intensity
406.4504700	0.20
438.5138550	0.12
456.4285889	0.23
457.8824158	0.40
469.3576050	0.38
500.0857544	0.11
535.3555908	0.05
573.0689697	0.10
619.4537354	0.31
620.5733643	0.24
637.6561279	0.12
662.3703613	0.08
699.5505371	0.08
716.6072998	0.56
733.4792480	2.25
734.4928589	8.40
735.3291626	1.55
736.2337646	0.13
746.5998535	0.35
750.3257446	0.15
751.3547363	1.33
752.6116943	1.47
753.2723389	0.20
763.6401367	0.35
765.4539185	0.48
781.2009277	0.20
782.3631592	0.81
783.5407104	0.07
784.5362549	0.09
820.6334229	0.10
831.5585938	0.36
832.4614258	0.15
837.3737793	0.06
849.9893188	0.10
851.2072144	0.10
864.5332031	0.35
876.1890869	0.11
877.1168213	0.17
878.5678711	0.83
879.3629150	0.10
895.5567627	2.91
896.4923096	10.93
897.4354248	2.72
898.4041748	0.21
903.6422119	0.15
904.3421631	0.18
908.2518311	0.25
913.6202393	0.61
914.4879150	2.63
921.0297852	0.15
922.4451904	0.46
925.3979492	0.09
932.4645996	0.09
940.5908203	0.08
943.9276123	0.69
944.5864258	2.05
945.4587402	0.40
951.3498535	0.08
957.8508301	0.43
958.6029053	0.78
959.6556396	0.20
981.5461426	0.21
984.6219482	0.13
994.3422852	0.25
995.7171631	0.36
996.4450684	0.13
1011.8063960	0.13
1013.6767580	0.10
1023.7249760	0.10
1024.4936520	0.25
1026.7413330	0.48
1027.5284420	0.06
1038.3928220	0.26
1039.5004880	0.55
1040.5854490	0.33
1041.3769530	1.47
1042.0129390	0.04
1043.6055910	0.25
1048.7248540	0.07
1057.4041750	1.24
1058.4405520	9.46
1059.3889160	1.70
1065.6196290	0.25
1066.5578610	5.47
1067.6124270	1.67
1076.5834960	0.45
1077.5021970	0.87
1083.5173340	0.60
1084.6364750	3.40
1085.3767090	0.89
1101.8845210	2.80
1102.5144040	10.18
1103.5776370	3.61
1104.9522710	0.17
1119.4138180	3.16
1120.5244140	27.77
1121.5782470	7.42
1122.6416020	0.59
1148.8698730	0.15
1162.6103520	0.28
1163.9863280	0.24
1172.4259030	0.39
1202.5457760	1.30
1203.7718510	0.13
1220.4902340	10.52
1221.5324710	3.39
1228.6781010	0.28
1229.3656010	0.24
1238.5438230	0.60
1246.5064700	12.98
1247.5667720	6.22
1264.4470210	100.00
1265.6562500	36.06
1266.6730960	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.2681
Annotation	PS(17:1(9Z)/0:0)
Peak:m/z	Relative Intensity
153.0009918	0.05
167.3931885	0.18
171.1728668	0.04
178.8574982	0.13
185.1687927	0.85
196.0397644	3.05
211.0498505	0.07
214.0309448	2.56
249.0591888	0.02
256.1834106	0.11
275.2805786	0.04
279.2648010	0.04
279.8869019	0.06
281.1804199	0.05
283.3923645	0.31
293.1994019	100.00
293.8699646	0.29
295.1188965	0.41
309.0414429	0.15
309.7542725	0.08
311.2502441	1.96
312.2828369	0.37
318.8663635	0.07
333.0171204	0.09
368.0339355	0.07
391.2227173	0.05
392.3240051	0.45
406.1059875	0.04
421.5044861	0.12
429.3328552	0.31
447.2538147	0.25
462.2147827	0.10
469.2983093	0.07
470.2654114	0.14
472.1696472	0.38
478.3657532	0.06
488.6637573	0.21
490.2599182	60.07
491.3871155	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1485
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0563660	0.63
171.1521149	0.34
179.0314636	0.68
196.9109802	0.30
214.9285889	0.69
226.9167786	0.58
241.1521149	0.09
242.9303131	0.04
245.0790863	4.49
263.0350647	100.00
270.8925171	0.06
284.8572998	0.28
301.1262817	0.09
322.9638672	0.21
334.8308716	0.49
366.6026001	0.03
372.6812134	0.12
374.8815308	0.04
388.1054077	0.05
412.6712036	0.12
415.2192383	0.03
418.5866699	0.03
439.0721436	0.11
461.2850952	0.20
462.0907593	0.03
463.2979126	0.08
480.9376221	0.06
508.4273071	0.12
509.3777466	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1649
Annotation	Safflomin A
Peak:m/z	Relative Intensity
169.9368286	0.11
174.9956207	0.06
188.0826721	0.82
205.0716705	1.22
206.2175140	0.02
209.2276611	0.03
217.0657654	0.07
226.0521545	0.17
228.9216461	0.06
243.1382904	0.04
253.1749878	0.03
255.1296234	0.03
267.1069946	0.26
271.0643005	4.04
271.6771851	0.04
283.1434937	4.05
284.2465820	0.04
285.3375854	0.09
287.0171509	0.02
295.1552734	13.19
296.9024048	0.06
298.2340393	0.07
307.1485596	0.12
308.8214722	0.17
311.0230713	0.50
313.0925293	57.23
321.0488281	0.12
322.1350708	0.03
323.4041138	0.13
325.2568970	0.11
328.3067017	0.10
337.1233521	14.05
339.1542969	0.16
343.2362671	0.16
349.0948486	0.75
351.1781006	0.69
352.9242554	0.03
355.2133179	0.08
361.2807617	0.19
363.0240479	0.09
365.2689209	0.11
367.1242065	10.83
369.6177368	0.15
370.9417725	0.06
372.6778564	0.15
379.1248169	5.81
391.3883057	0.21
397.0711060	19.76
397.7675171	0.08
399.3620605	0.16
400.1898804	0.04
401.2184448	0.04
404.2687378	0.04
415.2130737	100.00
416.2169800	0.24
416.9562988	0.24
418.2801514	0.12
421.1223755	0.31
428.8820190	0.26
429.4893188	0.08
433.1102295	87.37
434.0407104	0.40
442.0756226	0.13
447.1149902	0.03
448.9863892	0.11
454.9293823	0.14
457.2216187	0.54
462.9028931	0.07
464.9061890	0.19
465.5839233	0.06
468.2985229	0.08
469.5435181	0.19
471.0610962	0.03
474.2698975	0.10
475.2402954	1.17
481.2301636	0.48
484.1072388	0.08
490.3201294	0.14
499.1091309	1.47
507.0255127	0.21
508.3803101	0.14
511.1017456	0.25
513.9365845	0.36
516.0046997	0.08
522.3871460	0.08
523.3855591	0.27
529.2001343	0.38
534.1249390	0.07
541.2605591	0.55
549.0178833	0.40
549.6797485	0.02
551.3298340	0.09
559.2018433	1.75
574.7299805	0.04
575.4560547	0.13
577.1204224	25.80
577.7690430	0.51
585.9474487	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3391
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0121765	0.45
183.9616089	100.00
258.2180786	0.47
337.5584106	0.08
502.3517456	58.12
503.0785522	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5067
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
241.0935516	0.16
243.1011047	0.56
255.1953888	39.93
260.8270569	0.70
265.2670593	0.28
277.4300232	0.25
279.2260742	100.00
284.5172729	0.27
323.4892578	0.28
326.2965698	0.45
383.1628418	0.42
388.4973755	0.40
392.6195068	0.24
433.9763794	1.23
434.6500854	1.22
452.3485718	20.62
464.5162964	0.56
476.1088257	1.22
481.3292236	0.28
486.0411987	0.63
508.149353	0.31
516.0167847	0.65
545.2450562	0.19
567.4636841	0.72
597.5473633	1.13
616.4556885	0.42
626.4138794	0.69
636.2177734	1.00
652.4830933	0.78
666.4608765	0.16
668.1990967	1.75
678.2484131	0.41
685.0737915	1.85
685.71875	0.60
686.437439	0.23
690.7576294	0.35
696.2299805	1.46
697.3809814	2.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1507
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
167.1416016	0.03
168.9293671	0.03
171.1384430	0.03
171.8707275	0.02
173.0788269	0.03
179.0760040	0.11
180.9729614	0.02
181.8855743	0.14
183.0797424	0.11
184.8864746	0.25
185.9518890	0.08
187.0448303	0.42
189.0784912	0.09
191.8681030	0.05
193.2691650	0.02
195.0734406	0.41
196.1015625	0.11
196.9391937	0.44
197.9765625	0.17
199.0242462	0.28
200.1466522	0.02
201.1928711	0.02
202.8785400	0.01
204.8754730	0.05
206.8681488	0.02
208.9504852	0.04
210.0886078	0.01
210.9620056	0.71
212.4363098	0.32
213.0957642	0.52
214.0603027	0.12
215.1867065	0.12
217.0613708	0.05
219.1166229	0.02
223.2550354	0.18
223.9324341	0.15
225.1978455	0.02
226.0781555	0.05
227.1519012	0.34
227.9063568	0.10
229.1127777	2.04
230.1184692	0.28
239.0085602	0.84
240.1451263	0.27
241.0421600	0.96
242.0179443	0.17
243.0375824	0.13
244.1582947	0.01
250.2160339	0.02
255.0200500	1.50
255.9410400	0.55
257.1351929	3.29
258.1106567	0.39
259.0368958	0.03
267.1053467	1.21
268.0852051	0.27
269.1263733	0.11
270.0773315	0.04
277.0270691	0.01
280.9977417	0.03
282.2487183	0.01
283.1737671	0.77
285.0036316	100.00
286.0234985	13.51
287.0521240	0.06
287.8912354	0.02
298.9374390	0.32
300.0007019	0.03
307.3878479	0.02
309.0162354	0.03
311.0757446	0.95
312.0421753	0.17
313.2128296	0.02
313.8256226	0.02
316.0557861	0.04
321.0100708	0.02
323.3248901	0.07
323.9340820	0.02
325.2576904	0.06
327.0939331	2.82
328.0513306	0.66
334.9042969	0.07
336.2678833	0.01
338.9668579	0.02
340.1221313	0.02
341.3513184	0.01
342.0401611	0.02
349.2499390	0.02
351.1209717	0.05
352.3958130	0.02
353.1788940	0.01
353.9617920	0.01
355.2163696	0.01
357.1253052	0.46
358.0855713	0.20
365.3134766	0.03
367.2037964	0.02
369.3755493	0.03
370.3421631	0.05
371.1362305	0.02
377.1885376	0.06
381.3057861	0.01
393.3065796	0.03
395.4442139	0.03
408.8425293	0.03
409.5230713	0.01
411.2483521	0.04
413.1221313	0.08
428.9618530	0.03
430.9712524	0.14
432.3772583	0.02
447.1751099	0.16
448.1516113	0.09
452.3128052	0.02
455.3810425	0.03
457.0166016	0.03
461.3860474	0.02
466.0022583	0.01
472.3421631	0.01
473.2369385	0.20
475.3847656	0.03
499.2458496	0.02
517.4057007	0.04
519.3203735	0.01
521.1738892	0.01
525.0971069	0.02
531.3364258	0.04
531.9814453	0.01
533.1124878	0.14
538.9845581	0.02
548.2460327	0.03
549.2190552	0.02
550.1482544	0.04
558.0255127	0.06
561.2366333	0.02
565.1431274	0.23
566.2777710	0.08
575.2866821	0.33
576.1025391	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	608.239
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1356506	0.02
176.9773712	2.86
194.9503174	21.56
204.1787415	0.11
215.7052002	0.05
231.0502319	0.04
241.1116333	0.12
245.2510223	0.18
246.3569489	0.15
248.5260925	0.10
249.1330414	0.65
271.0811157	0.24
273.0070190	0.10
278.3320618	0.03
284.8850708	0.06
288.6039734	0.06
302.4729004	0.20
303.1730957	0.37
306.2482300	0.12
307.1032410	0.36
319.3073730	0.06
320.7142334	4.76
323.3126831	0.33
324.9104614	14.87
338.8259277	3.55
345.3267212	0.04
355.0179443	0.12
356.7857666	100.00
357.5848999	0.05
406.7760620	0.13
445.1927490	1.07
446.4420776	0.28
469.1157227	0.03
483.1709595	0.05
486.8798828	0.30
515.1168823	0.06
518.1926270	16.63
518.8237915	82.81
519.5214233	0.65
526.2901001	0.30
572.0442505	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.23
Annotation	Hydroxypropyl methyl cellulose
Peak:m/z	Relative Intensity
192.9619904	0.91
221.0580292	17.16
250.8859253	1.00
263.0266113	1.11
269.0108032	0.51
280.7225037	3.19
305.0359497	1.01
311.1534424	0.83
319.2050476	0.79
321.0830688	0.26
323.0393066	4.04
337.1491699	27.52
341.0534058	20.61
355.1266479	2.93
383.1823730	100.00
425.2111816	3.76
442.7405396	9.16
443.3560791	0.47
449.0803833	1.77
465.3608398	0.29
485.3057251	4.29
499.2359619	41.86
503.2247314	0.81
517.2109375	0.40
572.9728394	0.10
647.1265259	0.33
661.2489624	19.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.09
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
159.0481415	0.08
197.359375	0.06
201.2827454	0.05
217.0549011	0.08
241.0419922	0.23
249.1342773	0.10
267.1477661	0.50
285.0449219	100.00
286.1540833	0.21
297.7490845	0.39
298.8448486	0.33
301.0576172	0.05
303.3617554	0.20
309.1862183	0.08
310.9187622	0.21
313.2246399	0.03
314.234436	0.26
317.2202148	0.12
320.1513977	0.08
321.2574768	0.05
323.3534546	0.07
325.0557861	0.18
327.1340942	99.61
327.9248047	0.15
331.338623	0.10
336.9791565	0.10
339.048584	0.77
341.1230469	0.09
353.2915344	0.02
357.131897	21.41
357.8821411	0.02
359.4618835	0.11
365.3297119	0.09
366.130249	0.14
369.2712708	0.93
371.134613	0.29
375.8633118	0.08
379.1053772	0.07
381.1659546	0.12
383.1624451	0.08
387.2119141	1.37
393.171814	0.41
398.9335022	0.12
403.0031738	0.30
404.2339478	0.17
405.0854187	0.02
411.1816711	0.71
412.0965881	0.06
419.0730591	0.02
429.2211304	4.11
430.7652893	0.08
436.6814575	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.21
Annotation	9(S)-HpOTrE
Peak:m/z	Relative Intensity
94.70127869	0.07
96.81018066	0.03
108.8357239	0.24
112.9627991	0.28
122.9961548	0.14
129.0619507	1.17
135.2510376	0.21
136.9742432	0.02
140.7859802	0.20
146.8779297	0.13
149.2549286	0.03
151.3295746	0.04
154.9202423	0.37
158.9177551	0.04
163.0401611	0.16
167.1032715	0.41
171.2377014	0.12
175.1186523	0.28
177.0835266	0.51
179.0986633	0.79
180.9572449	0.39
185.1823425	0.04
189.421936	0.04
193.109314	0.19
195.0771942	15.16
196.3329468	0.07
201.0577393	0.05
207.2375183	0.39
211.1803284	0.09
213.1683044	0.03
215.2616577	0.13
217.3679199	0.03
219.1238098	0.13
220.9509888	0.12
222.0906372	0.02
223.1938782	0.23
225.3034058	0.04
229.2139282	0.03
233.2485962	0.56
235.0769348	0.08
237.2424622	0.11
239.2299194	0.07
240.2427368	0.02
243.02005	0.04
245.2126465	0.17
247.1843872	0.95
249.4651489	0.11
251.2418213	3.20
252.0311584	0.16
253.4482117	0.03
263.1990662	0.15
264.5947876	0.33
265.2140198	0.37
273.2063904	0.85
281.0751953	0.11
287.2172852	0.06
289.3032837	0.96
291.1880493	100.00
293.2480469	0.14
309.1905823	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.23
Annotation	Integrifoside C
Peak:m/z	Relative Intensity
124.8437805	0.06
160.9252319	0.12
162.8343506	0.10
164.6798401	0.04
176.9418640	0.06
179.1007996	0.15
181.0413818	0.13
191.3777161	0.02
205.1709595	0.03
209.0690002	0.05
219.2884674	0.06
221.0353851	0.11
222.9791565	0.08
226.0982666	0.04
227.1352539	1.08
230.8595886	0.06
232.9893188	0.38
247.1769104	0.06
249.1524963	0.64
251.2976990	0.08
267.2532349	0.14
269.0790100	2.37
273.0325928	0.04
283.0190125	0.25
286.2306519	0.02
287.2785645	0.03
290.0400391	0.09
293.1448975	0.04
297.9733276	0.12
299.1869202	0.17
311.0844421	100.00
312.1708374	0.94
313.0819702	0.06
314.3790894	0.01
315.3185730	0.07
323.1016235	0.48
325.0195618	0.04
328.2040405	0.06
335.1497803	0.03
337.2177734	0.27
341.1588745	15.04
342.1961975	0.09
351.0082092	0.06
353.2205811	0.82
355.0311890	0.27
365.2814636	0.06
366.3808899	0.20
367.0992126	0.23
369.0321960	0.04
370.3159485	0.80
371.1965027	9.34
372.6517639	0.13
373.3005371	0.14
377.0762939	0.08
383.1808167	0.61
385.1862183	1.39
386.9559937	0.63
387.5974426	0.02
388.4005432	0.14
389.2042542	0.80
394.9816589	0.46
398.1667480	0.04
400.0543518	0.37
401.1839905	0.66
403.1800842	0.07
411.1507263	0.19
412.0039673	0.24
413.0955811	3.32
413.9936829	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2652
Annotation	Salviadienol B
Peak:m/z	Relative Intensity
160.8433685	0.06
167.0145264	0.22
183.5377808	0.16
184.3450623	0.25
200.9823456	0.26
211.2042847	0.76
212.3217163	0.15
213.2137604	0.09
223.1921234	0.09
223.9869232	0.04
242.2728119	0.19
257.0537720	0.06
259.3684692	0.09
270.2011108	0.09
271.2074585	0.41
284.3280640	0.06
291.5061035	0.80
296.9398193	0.16
300.4733276	0.28
301.1083984	1.61
305.0913086	0.09
309.1220703	0.17
317.2766113	0.09
323.3850098	0.13
325.2240601	0.13
327.1932983	14.39
328.2770996	2.30
331.4109497	0.43
337.0634155	0.09
349.1854248	1.05
352.1904907	0.09
364.2064819	0.09
372.1531982	0.14
373.0907593	0.64
376.5397949	0.11
377.3709717	0.13
380.1833496	0.11
384.8571167	0.15
387.4974365	0.36
389.5148315	0.28
390.6553345	0.48
405.3092041	0.28
407.2987671	0.21
415.0301514	0.48
431.3546753	0.09
433.1685181	0.25
442.6694946	0.16
444.9957275	0.53
447.9020386	0.25
455.4709473	0.13
456.6436768	0.13
457.5658569	0.08
461.2107544	0.08
463.3836670	0.39
467.1337280	0.04
468.1456909	0.11
472.7016602	0.32
475.3197021	1.16
489.5140381	0.16
493.2598877	100.00
495.0715942	0.07
497.1126709	0.08
502.2597046	0.09
505.0391235	0.10
507.3562622	2.57
508.8510132	0.46
509.6513062	0.21
510.3179321	0.34
511.1158447	1.34
517.1636963	0.11
521.4965820	0.12
523.3298950	0.59
535.3728638	1.69
543.7996216	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1265.6173
Annotation	Unknow
Peak:m/z	Relative Intensity
368.1371460	0.05
421.3727417	0.09
437.6355591	0.08
438.4728394	0.07
453.7170410	0.22
465.2464600	0.26
483.2893677	0.61
484.3458862	0.16
513.8594360	0.15
571.1742554	0.16
614.3043213	0.07
619.3754883	0.27
633.4395752	0.06
637.2430420	0.08
647.5159302	0.06
659.6182251	0.04
661.4787598	0.28
685.4694824	0.14
687.6251831	0.05
697.5767212	0.27
713.2978516	0.28
715.4228516	0.32
729.2360840	0.21
730.7200928	0.24
733.4938354	9.05
734.4649658	3.12
735.2462158	0.03
751.4448853	1.58
752.3620605	0.23
752.9985352	0.15
759.4197998	0.50
760.5079346	0.05
761.5797729	0.42
764.8196411	0.04
768.1647339	0.04
769.5623779	0.19
777.5509033	0.70
781.5694580	0.23
782.6875610	0.22
783.6794434	0.13
784.6550293	0.04
793.8787842	0.12
795.6209717	0.08
796.7350464	0.14
829.6390381	0.05
830.7928467	0.07
831.4799805	0.10
832.4817505	0.05
841.6617432	0.16
847.5019531	0.08
848.8142090	0.05
857.7264404	0.14
859.9755859	0.13
863.2913818	0.21
874.3942871	0.12
875.5737305	0.43
876.6737061	0.77
877.5679932	0.54
878.6345215	0.28
879.4105225	0.47
880.2048340	0.74
885.7600098	0.03
889.6966553	0.22
894.8829346	0.61
895.5241699	8.72
896.4722900	6.07
897.1793213	0.06
903.5474854	6.78
904.4498291	3.21
913.4602051	1.12
914.5527344	1.04
919.3142090	0.23
921.4945068	2.79
922.4538574	0.86
923.4937744	0.06
926.0849609	0.53
938.9581299	0.62
939.6169434	5.01
940.4833984	3.50
941.5439453	0.46
949.9016113	0.11
957.4530029	5.29
958.5314941	1.73
959.1813965	0.17
969.6229248	0.05
1006.0861820	0.14
1010.3793950	0.04
1023.5090330	0.18
1024.1451420	0.04
1024.8511960	0.07
1039.6794430	0.05
1040.5311280	0.46
1041.4885250	11.06
1042.6051030	6.32
1043.3984380	0.10
1054.8254390	0.09
1057.4565430	6.60
1058.4455570	3.46
1059.7973630	0.18
1067.6125490	0.56
1075.5559080	0.16
1076.5970460	0.37
1083.7021480	0.20
1085.4873050	2.96
1086.5916750	1.10
1087.4929200	0.02
1101.3673100	1.52
1102.4865720	1.28
1103.4895020	12.72
1104.5219730	10.77
1105.9427490	3.08
1119.5523680	6.83
1120.5625000	3.22
1121.5765380	0.13
1127.7043460	0.05
1131.4143070	0.08
1132.2182620	0.06
1157.6220700	0.04
1159.4960940	0.06
1185.6275630	0.58
1186.6481930	0.07
1203.5014650	11.36
1204.6103520	7.35
1205.3862300	0.14
1221.5423580	0.55
1222.3536380	0.13
1223.1494140	0.09
1229.4432370	4.43
1230.5563960	3.68
1247.5362550	100.00
1248.4755860	63.14
1249.5618900	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	648.3867
Annotation	1-Palmitoyl-2-(5-keto-8-oxo-6-octenoyl)-sn-glycero-3-phosphatidylcholine
Peak:m/z	Relative Intensity
227.0946503	1.87
242.1129303	0.11
243.1828461	0.09
245.2242737	0.66
270.6265564	0.15
288.2756958	0.10
306.9050903	0.16
312.9743652	0.04
319.2210693	0.07
329.3528442	0.06
333.4929810	0.10
335.0726929	0.08
336.1058960	0.15
337.2351685	0.04
339.1779785	0.03
348.3562012	0.05
353.0742798	0.08
355.9520874	0.12
368.4244995	0.05
382.3543701	0.19
383.4631958	0.10
386.7251587	0.19
392.3386841	0.30
394.3339844	0.16
399.4255371	0.07
411.2482300	0.08
415.4613037	0.14
423.2644043	0.11
425.4229126	0.21
428.3480225	0.10
451.0676270	0.14
454.2790527	0.03
460.1439819	0.14
486.4019165	0.08
487.3645630	0.19
489.5164795	0.14
494.1437988	0.04
503.6979370	0.26
507.3362427	100.00
515.4105835	0.09
519.9801636	0.08
546.0327759	0.09
550.6358643	0.36
552.7586060	0.10
555.3242798	0.02
580.5496826	0.08
581.2770386	0.10
584.5140991	0.06
588.5419312	0.17
589.5708618	0.17
592.5679932	0.11
606.1660767	0.06
607.3082275	0.04
612.3573608	0.02
615.4895630	0.17
621.3859253	0.05
630.2927856	1.42
647.8021851	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.0101
Annotation	Unknow
Peak:m/z	Relative Intensity
127.8546753	0.13
144.1761322	0.11
145.9371643	0.04
153.1541443	0.06
153.9463806	0.28
155.9119110	4.30
163.0736084	0.04
167.1065063	0.13
171.9808807	0.08
183.9192047	0.04
195.9159546	0.23
196.9317627	0.07
198.4975433	0.33
199.8645782	72.02
200.5479736	0.28
213.0782013	0.04
215.1376038	0.11
217.2622986	0.08
229.0492859	26.28
231.1469421	0.05
240.0609436	0.21
243.6947632	0.08
254.9144592	10.75
256.5244446	0.48
257.1443481	0.20
270.9180603	0.40
272.7803040	56.17
273.5164795	0.09
289.1823120	0.17
294.1518860	0.19
297.0963440	0.06
300.1050415	0.05
301.2859802	0.27
301.9197998	0.07
302.8109436	0.54
316.9092712	100.00
318.1237488	0.04
342.0711975	0.10
343.1083374	2.76
351.9386292	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2819
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
249.4095154	0.09
279.5379639	0.07
282.1297607	0.10
287.2862244	0.09
288.0715027	0.04
335.2678833	0.08
336.2962646	0.09
348.9464722	0.03
355.3046875	0.25
356.2642822	0.10
357.1913452	0.05
389.5245972	0.05
390.2506714	0.04
402.3754883	2.40
403.3511353	0.70
404.1125488	0.02
405.3347778	0.16
422.3565674	0.09
432.3498535	0.02
444.1367798	1.37
445.2883301	1.25
446.2639160	0.12
447.1585083	0.07
448.2805786	0.74
449.3742065	0.77
453.1416016	0.03
471.2819824	0.03
474.3267212	0.18
476.4954224	0.26
477.3735962	0.30
485.9499512	0.27
488.1893921	1.54
489.1290283	1.28
490.2796631	0.22
493.1955566	0.35
497.1416016	0.06
498.1817627	0.08
499.2056274	0.48
500.3326416	0.22
504.2074585	0.11
505.2758179	0.05
506.0703125	0.09
507.1852417	0.11
508.2557373	1.08
509.3487549	0.81
516.4115601	0.02
520.2131958	13.29
521.1941528	7.49
522.2667847	0.09
529.8467407	0.06
532.7084351	0.07
541.3091431	0.85
542.2249146	0.96
543.0978394	0.04
544.2393188	0.15
545.1843872	0.07
557.3972778	0.10
558.3847046	0.17
559.3709106	1.12
560.2612305	0.55
560.9181519	0.10
564.3566895	0.10
565.5936890	0.02
573.3508911	0.53
574.3925171	0.28
579.3501587	0.10
580.3380737	0.08
583.2507324	0.56
584.2355957	0.65
585.2019653	3.48
586.3016968	4.75
587.2588501	0.03
589.1963501	0.05
589.8368530	0.05
590.7416382	0.03
591.6873169	0.14
599.4517822	0.35
601.0284424	1.23
602.1666870	0.34
603.2275391	0.28
604.1351318	0.06
606.6561890	0.08
615.4562378	0.43
617.2910767	100.00
618.2723999	71.46
619.0877075	0.02
627.2740479	3.45
628.2738647	6.08
631.8769531	0.51
632.6926880	0.21
633.3991089	0.08
634.4450073	0.67
641.4229126	0.12
642.3010254	0.01
645.2200317	15.28
646.3689575	12.32
647.1859131	0.11
648.1567993	0.06
649.0569458	0.33
650.2562866	0.12
654.8190308	0.18
656.4632568	0.19
659.2630005	64.72
660.2455444	49.92
660.9496460	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.8544846	0.61
108.9816895	0.02
118.7698898	0.09
122.9549637	1.62
124.8796692	0.14
143.1097412	0.15
152.0383759	2.78
166.9514160	100.00
172.9596252	0.02
183.0742798	0.04
190.8738098	0.10
197.1213989	0.03
199.0733948	0.05
206.9606934	0.13
208.2640076	0.04
209.1494141	0.09
214.8569336	0.08
217.4330444	0.03
219.8290405	0.18
226.0742493	0.05
232.9772034	0.06
235.2316589	0.05
238.8036804	0.13
242.8597412	0.07
244.8809509	0.22
254.6499939	0.17
257.0678406	0.24
257.8825073	0.04
261.1049805	0.10
273.0607300	0.05
282.9864502	0.20
285.1453247	0.25
286.1454468	0.05
293.2580566	0.31
299.1915283	0.11
301.1585388	0.56
310.7647705	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.3383
Annotation	Mezzettiaside 9
Peak:m/z	Relative Intensity
178.7875366	0.85
185.0785217	0.21
192.9892883	0.15
202.8030701	0.10
208.9497986	0.16
219.0184631	0.24
233.0139618	0.15
244.8821716	0.49
248.6672211	0.09
249.4052734	0.31
261.4154053	0.04
270.1459351	0.05
271.3307190	0.12
274.9001465	0.10
279.2309570	41.99
279.8499146	0.16
281.1773071	0.35
287.4607544	0.15
291.3965454	0.22
293.2291260	1.72
295.9157715	0.25
303.3567505	0.69
307.0625610	0.23
315.1046753	0.23
321.1162720	3.10
323.0279541	27.41
333.1653442	1.00
341.0781250	100.00
341.6784668	0.35
350.4606934	0.61
351.1655273	0.26
375.1766357	0.33
376.9132080	0.22
381.2510376	0.72
387.2703857	0.54
403.0688477	0.25
409.0981445	0.07
423.0554199	0.21
433.6065674	0.22
438.7684937	0.09
440.6754761	0.14
441.3347778	0.35
445.5480957	0.14
446.5622559	0.16
449.4008179	0.35
458.4797363	0.10
471.5834961	0.34
487.5661621	0.07
503.0311890	0.07
559.2796021	0.09
573.1551514	0.09
581.1140137	0.06
583.1167603	0.05
584.6437378	0.13
585.4403687	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1123
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
84.9196396	0.05
96.9785461	1.87
98.9965668	0.15
109.0116196	1.18
111.1559296	0.05
113.0648804	0.02
115.1716766	0.04
116.8953857	0.06
126.9772797	11.91
129.0207520	0.14
144.8860168	18.66
145.7394409	0.04
157.8328247	0.05
160.4208679	0.03
162.3762970	4.47
162.9906464	26.46
165.0722809	0.29
169.0848846	0.02
170.9478607	0.02
180.9089661	0.14
183.0582123	0.08
187.0560913	0.29
189.0838013	0.14
191.5801086	0.04
192.7694397	1.14
195.1182709	0.06
198.8989258	1.54
203.7953491	0.14
205.0682068	0.69
207.2146606	0.43
210.4035950	0.06
211.0429688	0.49
212.0682678	0.07
213.2208557	0.17
216.7877502	3.00
219.0586243	0.09
222.9375610	2.17
224.8891602	0.68
228.9283752	0.93
230.8983765	0.02
232.5879517	0.03
234.9248657	0.97
235.7833557	0.07
240.2526855	0.46
241.0449219	1.01
242.6186523	0.26
243.2289124	0.08
246.9797058	3.53
250.5894165	0.13
252.9204102	9.80
256.4500122	0.09
257.1574402	0.37
257.9854736	1.58
258.8580627	15.42
261.0095215	0.34
268.1454468	8.80
269.1572876	2.55
270.4368591	2.64
271.0603333	28.04
275.7567749	0.08
277.0023499	0.09
278.0652466	0.03
279.1608887	0.54
282.9963684	0.22
283.8816528	0.08
285.8849182	0.09
287.1683960	1.32
288.2815552	23.72
288.9667053	100.00
296.5601196	0.05
304.9606628	0.12
306.9663696	10.14
307.5973511	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
131.0886993	0.02
133.0936584	0.01
150.8805084	0.02
152.1264038	0.01
156.960022	0.02
160.8512878	0.01
161.9178162	0.01
167.0926514	0.08
175.0257263	0.01
191.0345459	0.01
191.9426575	0.03
199.2546082	0.01
201.051178	0.01
211.2157288	0.01
215.033432	0.02
217.1650696	0.01
223.0603943	0.01
226.4559631	0.01
231.2292328	0.01
241.1189575	0.06
242.8081665	0.01
249.2388916	0.11
250.1860352	0.02
258.2277832	0.01
267.2517395	0.07
268.9294434	0.08
270.1379395	0.02
281.0422058	0.01
285.0355225	100.00
286.0601196	28.70
286.9772339	0.04
297.0153809	0.01
298.230957	0.07
299.0157166	0.06
300.4095459	0.01
302.1883545	0.01
303.2542725	0.03
306.6260376	0.04
309.2363892	0.07
310.1363525	0.07
313.972168	0.06
322.7728882	0.02
325.2163086	0.02
327.0491638	13.12
328.0967102	4.80
339.1365662	0.05
341.1130371	0.01
343.232666	0.03
345.9373474	0.02
351.1320801	0.02
357.1412659	2.21
358.1672974	1.14
369.1205444	0.24
370.1394348	0.04
371.4639893	0.05
380.9232788	0.03
387.1576538	0.24
388.1118774	0.10
390.1235657	0.03
392.9573669	0.06
394.3382263	0.05
400.5340881	0.03
403.1833191	0.11
404.038208	0.03
411.101532	0.06
412.0185547	0.05
417.2199402	0.04
418.0228577	0.04
429.1076965	0.65
430.1408386	0.26
439.3287659	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.2158
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
108.9031525	0.44
110.9844818	0.07
113.9192963	0.03
119.0296021	0.14
120.7159424	0.43
121.3519669	0.07
122.8782654	0.16
124.0730362	0.02
126.9401855	0.23
129.1173553	0.02
129.8727722	0.05
133.1221924	0.07
135.0824890	1.09
136.9357605	0.08
139.0495300	0.27
141.0801697	0.07
142.2818909	0.04
144.9847870	0.17
148.8802795	0.21
150.7616425	0.16
153.1243896	0.21
153.8616943	0.02
155.2918396	0.03
157.3056946	0.19
159.1163330	0.13
161.1219788	0.38
163.1028442	0.04
165.0893860	0.12
165.8900452	0.05
167.1637573	0.16
171.8519287	0.05
173.1387329	0.04
174.8671417	0.12
178.1853790	0.04
179.0282898	0.31
180.9498291	0.14
183.0163269	0.57
185.1489258	0.29
187.1105499	0.07
189.0745697	0.03
193.0040131	0.05
195.0677795	1.74
197.0322723	0.13
199.1653137	0.33
201.0631409	0.41
203.0528259	0.06
205.1359711	0.10
208.9951477	1.54
210.4985657	0.06
211.1170959	0.34
212.9052582	0.06
213.8655396	0.11
217.4803772	0.17
218.9984436	0.06
221.1761475	0.04
222.1234436	0.02
223.0157776	0.22
225.1340942	0.22
227.0781555	0.30
229.2218628	0.10
230.9656982	0.07
232.1938782	0.02
233.0878906	0.02
235.3254089	0.07
237.3670044	0.16
239.0605774	0.29
241.2719116	1.44
242.4949341	0.20
243.2954407	0.67
245.0822144	0.47
247.1590881	0.69
249.1644592	0.19
251.1277771	1.50
253.1474304	0.28
254.2788086	0.12
255.2263184	0.33
257.1278687	0.08
259.1492310	2.26
261.2005005	0.51
263.2267456	1.12
265.1119080	0.19
267.0389099	0.02
269.1433411	6.19
271.2480469	0.68
273.1807861	0.16
275.3481445	0.19
279.1380005	0.50
283.2080078	0.23
285.3068237	0.97
287.1405334	7.69
289.0891724	2.16
289.6899109	0.09
291.4485168	0.06
293.1807556	0.08
294.7961426	0.05
295.8820190	0.14
297.2114258	3.46
299.1138306	0.04
302.9815674	0.72
303.5935669	0.06
305.1952209	4.58
306.0397034	0.30
307.1415405	0.03
308.2093506	0.10
308.8863220	0.29
309.9754944	0.17
311.4191589	0.02
315.1380615	25.15
315.7874756	0.17
318.0036316	0.12
319.1320190	0.98
321.4976501	0.15
323.1618652	0.87
324.2088013	0.24
333.1439514	100.00
333.8316650	0.52
335.6114197	0.18
337.0544434	0.06
342.4255676	0.32
350.5222473	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5174
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
241.0464630	8.01
243.1828156	0.18
259.2962952	0.22
261.2853394	1.12
279.2156982	70.63
280.0994568	0.47
281.3525391	0.79
297.0443726	9.91
315.1017456	4.03
391.1095886	0.10
412.9393311	0.27
413.5879517	0.17
415.2985229	64.76
417.5213013	1.10
433.2233887	2.00
502.9437256	0.12
521.4215088	2.38
575.3044434	0.22
577.2973633	100.00
578.1972046	0.68
579.2967529	1.34
595.3240967	19.41
597.7147217	0.09
686.2987061	0.14
695.5480347	0.37
778.4757690	1.30
796.4297485	0.96
797.2516479	0.20
839.7095947	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	443.3265
Annotation	N-palmitoyl tryptophan
Peak:m/z	Relative Intensity
126.9616165	0.10
129.8455658	1.30
132.0451965	0.07
141.9696198	0.61
143.9245911	1.45
144.5393219	0.21
145.9850311	12.20
159.0465393	10.16
159.9078827	0.33
160.8396912	0.34
169.3513489	0.64
170.0162506	0.92
185.4192505	0.06
187.9323120	67.40
188.9710846	0.20
190.8473511	0.10
203.1667023	0.60
204.9720154	100.00
206.1181946	0.34
214.9332581	0.17
225.0776978	0.24
239.1003723	0.25
256.1836853	0.30
259.9668274	0.30
263.4127197	0.31
280.6856079	0.18
284.9935608	0.45
290.9418945	0.18
292.9701538	0.11
301.4901428	0.45
303.4263306	0.08
307.2412109	0.57
308.0341797	0.20
308.9116516	0.12
314.7874146	0.16
315.4547424	0.30
326.2448730	1.11
333.4693909	0.46
340.4035645	0.67
341.5915527	0.12
343.3825073	0.63
349.3045044	0.11
350.6996460	0.19
355.6040649	0.40
365.3450928	0.25
368.9836121	0.76
370.6018372	0.09
374.8503723	0.21
378.4534302	0.23
381.2707214	0.26
387.3650208	0.53
389.3597412	0.11
397.3684387	11.85
398.5885925	0.54
399.3681335	0.08
411.3339233	0.14
415.0719299	0.17
425.2608337	37.60
426.2855530	1.10
443.5280151	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1068
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
164.9149780	0.03
168.0575104	0.08
192.9954376	0.13
195.0388947	0.10
212.5097961	0.16
224.3748474	0.03
239.2469177	0.07
242.9594727	0.23
246.1500854	0.18
250.9962463	0.15
257.0723267	0.02
259.0472717	0.66
269.1643677	0.04
270.9922791	0.09
278.9710083	0.23
281.3824158	0.11
283.1163635	1.22
285.4299011	0.18
287.0581360	2.61
291.5211487	0.23
293.1346436	0.05
295.1636963	0.03
297.2072144	0.31
298.9562378	3.94
299.5769653	0.19
301.0240479	0.90
301.9748535	0.21
307.3205261	0.04
311.1171875	11.24
318.0829163	0.16
318.9371948	0.09
320.1010742	0.33
321.2178955	0.08
323.1881714	0.91
325.1884155	0.63
326.9812622	0.16
329.0662231	25.44
329.7952881	0.12
330.9172668	0.09
337.3622437	0.08
339.1690674	0.12
341.0075073	0.05
343.0606079	0.09
349.0263367	0.26
351.0785522	0.17
353.0906067	17.52
354.2625122	0.12
355.1261902	0.32
357.0576172	0.04
359.1143188	1.01
365.2396851	0.60
367.0858765	0.41
370.7967224	0.18
371.4595642	0.06
373.4399719	0.12
377.1329346	0.12
383.1401672	14.21
385.0271912	2.96
386.3089294	0.15
388.0485229	0.02
395.1342163	5.86
402.8266907	0.63
404.7656860	0.07
411.2254944	0.04
413.1878967	23.36
420.9136658	0.15
425.6602478	0.11
429.0313110	0.14
431.1246033	100.00
432.2221069	0.71
434.1147766	0.03
435.1771545	0.07
439.9494934	0.13
441.5713806	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	546.1588
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9991913	0.10
193.1337585	0.12
208.9114990	0.16
216.0327148	0.13
222.1953125	0.16
233.9741364	0.09
236.1952057	0.06
237.9877319	0.20
240.1389771	0.21
250.3984985	0.07
265.8593750	0.04
269.2422485	0.09
279.2943726	0.13
279.9647827	0.14
287.9866943	0.41
290.8497925	0.02
291.9711914	0.07
297.3072205	0.16
298.0715332	0.28
302.0890198	0.16
303.9823608	0.10
307.1013794	0.14
308.0166016	0.31
309.9701538	0.34
316.8630981	0.12
321.9887695	0.55
323.9804688	0.04
327.1081543	0.05
336.1485596	0.09
338.0902100	0.54
339.8704834	0.08
343.8865356	0.26
357.3751221	0.06
362.0715332	0.54
365.4342651	0.57
366.2243652	0.31
367.2025146	0.15
369.6440430	0.16
370.3734741	0.04
374.9153442	0.22
379.3371582	0.11
380.1066284	0.33
380.9518433	0.10
382.0648193	0.52
383.1893311	0.19
384.0988770	0.62
385.0892944	0.28
387.8322144	0.04
393.0890503	0.11
396.9351196	0.09
399.5134277	0.68
400.1439209	6.44
401.1876831	0.08
403.0231323	0.04
406.3306885	0.16
408.0705566	0.29
414.2359619	0.07
415.1878662	0.24
417.1320801	0.26
420.7028809	0.12
426.1440430	3.68
427.0426636	0.07
432.9644775	0.27
435.3741455	0.17
440.4498901	0.08
441.5073242	0.33
442.1099854	0.04
443.8117676	0.06
444.8485107	0.13
450.0261841	1.03
450.7344360	0.35
456.2519531	0.20
457.6797485	0.05
459.1417236	0.07
460.3703613	0.04
464.7062378	0.30
472.0678101	0.04
474.0048828	0.14
480.2385864	0.81
483.2230835	0.19
484.1852417	0.20
486.4738159	0.11
487.1170044	0.09
492.1026611	0.07
494.5154419	0.19
500.0353394	1.11
502.1333618	0.10
504.4321899	0.09
505.0639038	0.19
509.0967407	0.44
510.1211548	4.72
510.8853149	0.17
516.0087280	0.21
517.3855591	0.08
523.2512817	0.08
525.4208374	0.03
528.1646729	100.00
529.1726074	0.23
532.2590332	0.14
535.0609741	0.04
537.0946655	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1508
Annotation	Ethyl gallate
Peak:m/z	Relative Intensity
205.1104736	0.06
232.9898376	0.07
238.2083740	0.15
239.2163086	0.04
244.8161469	0.14
268.0666809	0.05
268.9838867	0.57
270.8978882	0.05
272.8852234	0.06
281.9574585	1.86
283.1098633	4.16
284.9954834	0.12
293.2500610	0.22
295.3775635	0.10
297.1467285	3.26
298.2385864	0.54
298.9955444	0.04
309.2663574	0.41
311.0391846	58.33
312.1881714	2.57
320.1101685	0.18
321.0912476	0.29
322.8699341	1.50
324.4530029	0.29
325.2799683	0.67
325.9708862	0.14
327.0821533	3.07
335.0733032	0.23
336.0340576	0.08
337.1419678	0.29
339.1031494	0.13
341.1032104	11.76
341.9392700	0.36
349.0722046	0.09
351.2321777	0.57
353.1878052	2.41
357.3008423	1.48
367.1871338	0.06
369.3034058	0.06
376.9663086	0.18
378.3162231	0.05
383.0849609	2.20
384.1965942	0.17
390.2633667	0.10
393.1096802	0.71
394.9556274	0.81
411.0092163	0.02
413.1961670	2.30
414.3305664	0.17
423.1199951	0.09
425.3790283	0.18
427.1185303	0.04
429.4500732	0.03
431.1162109	100.00
432.0382080	2.23
437.2612915	0.07
438.9719238	0.11
443.2719116	0.05
445.2647705	0.49
454.9655762	0.29
456.3204346	0.14
466.1028442	0.05
467.0563354	0.06
471.3379517	0.09
473.1396484	29.34
474.1043091	1.66
485.2997437	0.08
486.9960938	0.20
488.3178101	0.06
503.2334595	3.98
504.3882446	0.11
505.1728516	0.19
515.3474731	0.30
517.4583130	0.05
529.0756226	0.10
531.0368042	0.06
532.8380127	0.46
533.4541626	0.04
545.3167725	0.03
546.2734985	0.07
547.1141968	0.35
548.1547241	0.03
557.0067139	0.10
557.6520996	0.09
575.1887817	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	931.2129
Annotation	Unknow
Peak:m/z	Relative Intensity
285.0286865	9.28
301.9114380	0.02
303.1202698	0.75
313.2074585	0.05
321.3118286	0.08
339.1420898	2.28
343.2118530	0.10
405.2814941	0.02
447.2153931	0.73
462.2009277	0.06
465.1704102	100.00
519.9307251	0.02
525.4624634	0.04
576.8706665	0.02
625.0896606	0.09
721.7881470	0.11
735.1640015	0.04
782.5024414	0.02
800.6714478	0.03
895.4891968	0.05
912.2722168	0.09
913.1748047	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8600998	4.34
115.9579468	4.08
131.9993896	0.17
155.2762451	0.09
156.6037903	0.11
158.8961487	100.00
159.9283752	98.27
198.8388977	0.06
199.9701538	3.53
217.9286194	1.52
227.9034729	0.53
228.9894409	2.63
229.9501648	46.17
245.8912964	0.41
256.0375977	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	999.4635
Annotation	Mukurozioside Ib
Peak:m/z	Relative Intensity
304.5397644	0.08
320.9617310	0.16
323.1001892	1.18
340.9883423	0.37
352.2138977	0.32
353.2070312	0.17
364.8969727	0.39
373.0786438	0.16
378.9689331	0.11
383.2367859	0.42
397.0665588	1.89
415.2110596	7.81
425.4726562	0.07
427.1656799	0.11
439.1560669	0.41
449.2110291	0.10
456.8992920	0.31
457.5263062	0.30
467.5640259	0.13
485.1669617	1.68
486.2927246	0.09
505.1545410	0.14
527.2042847	0.30
541.2205811	1.15
545.1666260	0.14
559.2355957	10.02
577.2174072	8.53
597.2745361	0.13
599.0913696	0.22
601.4381104	0.26
619.1930542	0.65
629.0819702	0.28
637.1000366	0.08
645.5311279	0.10
647.0916748	0.40
651.4562988	0.19
667.6658936	0.08
675.3232422	0.23
685.2785645	1.11
689.8290405	0.26
703.0839233	1.26
721.2457275	100.00
721.8539429	0.64
735.4502563	0.22
739.2411499	56.59
739.8438721	0.33
745.3283691	0.16
746.5133667	0.17
747.2720947	0.45
771.0445557	0.11
805.4367676	0.15
811.2205811	0.20
817.4724121	0.60
837.1458740	2.09
837.7626953	0.07
839.0314941	0.08
845.3991699	0.36
869.5375977	0.28
879.3859863	0.19
911.5792236	0.12
919.4853516	0.25
926.6184082	0.29
941.4334717	0.96
945.5377197	1.11
952.5351562	0.15
963.3458252	0.51
981.5335693	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.88
Annotation	Unknow
Peak:m/z	Relative Intensity
104.9436569	0.04
114.1366425	0.15
132.8358154	0.11
148.8877563	0.04
163.0629272	0.06
165.0247498	0.07
174.9137573	0.02
177.2182922	0.03
178.1454468	0.09
180.7398682	0.09
189.1276550	0.06
195.2539520	0.22
207.2303772	0.11
215.8975525	0.11
218.9236755	3.69
220.0729675	0.06
236.8983459	0.06
239.4598083	0.08
240.1435242	0.08
243.4492798	0.14
244.1852417	0.13
245.2783203	0.29
246.2701721	0.58
247.1760254	0.18
248.9869385	0.10
256.8220825	0.12
257.9621582	0.71
259.1252747	0.05
260.8890991	0.05
262.7703552	100.00
267.3103638	0.11
274.7261047	0.11
275.9459839	0.13
280.6663513	15.83
281.2849121	0.06
281.8859253	0.21
283.2608643	8.55
285.1047974	0.44
285.8402710	0.45
286.6460266	0.16
288.4233704	0.11
291.2046204	0.30
292.1407471	3.33
293.0156250	0.15
303.5779114	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.1274
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
67.0213165	0.31
70.9700851	0.22
84.8823318	8.82
85.5436020	0.02
86.9620514	0.01
91.0708618	0.03
95.0779114	0.03
98.9860382	0.45
105.0783386	0.04
110.9475098	0.30
119.0350952	0.47
121.0464630	0.19
123.0478516	0.03
124.6627350	0.18
126.8830261	0.08
130.9031830	0.82
134.7960358	0.17
138.9492798	0.05
141.1453705	0.02
142.9513092	1.40
145.0148010	1.74
147.1003876	0.09
148.9492950	1.19
152.6630402	0.01
155.0759125	0.05
163.0315247	1.94
165.0713806	0.10
166.9732361	4.84
169.0625763	0.03
173.0666809	0.08
179.0140381	0.29
180.9996185	0.33
182.8648376	0.01
191.0362854	43.57
197.0450287	0.50
209.0076599	100.00
210.3692474	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1612
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
182.0523224	0.14
183.1233063	0.27
184.0816040	0.08
185.2599792	0.29
187.2293549	0.11
192.8425446	0.07
198.9916687	0.11
205.0417480	0.37
208.2616577	0.05
214.2179718	0.08
215.1819153	0.05
216.2590179	0.07
219.0198669	0.06
221.0578613	0.22
222.2634125	0.19
223.0913086	0.29
223.8439026	0.10
225.1130066	0.36
225.8745422	0.45
227.0223389	1.50
228.1642456	0.14
229.0956726	0.07
243.0045624	0.39
243.9146271	0.24
252.2857361	0.07
254.2955627	0.80
255.0884399	18.45
256.0420532	0.10
267.2479858	0.11
268.2592773	0.04
269.0751343	0.85
270.9743958	15.91
272.0609131	5.55
281.0526733	0.08
282.1268616	0.16
284.0599976	0.11
284.8375854	0.23
285.5195618	0.08
286.9858398	0.11
291.0237732	0.07
297.0577393	0.45
297.8870239	0.80
299.1350708	5.78
300.0167542	51.77
301.0927734	0.34
313.2617188	1.14
314.9887085	100.00
316.1145630	0.77
317.2401733	0.19
328.0189819	0.11
329.0225220	0.30
340.8227539	0.11
342.1217651	0.81
343.1486816	0.65
354.1231689	0.24
357.0050659	2.55
358.0593262	0.12
366.9860840	0.25
370.6035156	0.10
372.4666138	0.13
387.2918701	0.58
399.2692871	0.40
415.1665039	0.23
418.9155884	0.97
423.1871338	0.09
431.3204346	0.60
442.2186890	0.06
443.2796631	0.08
447.1557617	0.06
449.0908813	0.08
460.8352661	0.39
467.3648682	0.14
469.2554932	0.07
477.0812378	0.26
478.5224609	0.04
483.9608154	0.11
485.1914062	0.84
486.0091553	0.07
488.2145386	0.26
491.4436035	0.10
493.0331421	0.06
503.2054443	0.29
518.8786621	0.11
525.8510742	0.16
530.2944946	0.09
531.0073853	0.16
532.2097778	0.32
532.8794556	0.36
533.5567017	0.09
541.0787964	0.42
548.2327271	0.15
549.2708130	0.25
551.2323608	0.22
563.1383667	0.15
567.6092529	0.15
576.2083130	0.58
577.0958252	2.73
578.1655884	0.35
579.7621460	0.20
591.3652344	0.38
592.1950073	0.17
592.8452759	0.15
595.2243042	0.21
604.9401245	0.84
608.2427368	12.02
609.1255493	0.29
623.3593140	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	715.37
Annotation	Eclalbasaponin V
Peak:m/z	Relative Intensity
202.3402405	0.19
207.1492767	0.17
210.9474487	0.39
211.8142853	0.39
213.0981445	0.27
215.0596161	0.22
218.0375061	0.30
222.9698181	0.44
224.4821014	0.14
226.2699280	0.18
228.9860535	0.46
237.3167725	0.55
238.0773163	0.26
238.7872620	0.23
241.0703888	0.90
242.0067902	1.54
243.0616913	0.51
244.1110992	0.43
250.1294861	0.47
264.0507812	0.23
267.2218018	0.47
267.8735352	0.06
269.0291138	18.91
270.1082458	24.59
271.0519104	38.52
272.0501709	19.48
272.9712830	0.46
275.2180176	0.30
278.0514526	0.36
280.4016418	0.13
281.8528137	0.06
286.1640320	0.54
292.9479675	0.07
297.2017822	0.43
298.1826782	0.67
310.4311523	0.50
311.2478027	0.27
319.1439819	0.28
321.1239319	0.23
327.3864136	0.19
328.2869873	1.29
329.2199097	2.14
330.8817444	0.18
332.0667725	0.20
346.9898071	0.41
348.2176514	1.19
349.1757202	2.50
350.6379089	1.74
351.2578430	1.32
364.1273804	0.26
366.3825073	0.28
367.1096802	2.43
368.2987061	0.81
369.0814209	0.76
383.1179810	4.34
385.0648804	46.37
386.1530762	59.07
387.1310425	100.00
387.8953247	0.25
390.8728638	0.14
399.1534424	0.29
410.2512817	0.15
424.7769165	1.23
426.2863159	0.16
442.3150024	0.16
470.7521973	0.26
486.4943237	0.20
489.4715576	0.23
494.0892944	0.28
515.0601196	0.07
521.7526245	0.36
531.7861328	0.26
543.8088989	0.28
553.6272583	0.18
555.2177734	0.19
568.3098145	0.13
573.4692383	0.44
580.2502441	0.77
596.8172607	0.52
597.8612061	0.51
599.3494263	0.29
600.5374756	0.36
616.4664307	0.67
630.5480347	0.41
632.0912476	0.50
637.4758911	0.26
649.1891479	0.36
653.4469604	0.35
657.1736450	0.50
661.0381470	0.15
662.4487305	0.90
671.6897583	0.29
677.1786499	0.17
678.0382690	0.52
678.9343262	0.26
683.2109375	0.15
694.9204712	0.05
696.0357056	1.36
697.0607300	3.89
697.7303467	0.86
705.7667236	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.2
Annotation	Karachine
Peak:m/z	Relative Intensity
125.8004608	0.16
143.9474335	0.30
162.2451477	0.08
169.9606323	0.33
175.8124084	0.36
184.0786438	0.13
192.9919128	0.85
198.1807709	0.13
204.1846008	0.15
207.1761932	0.07
208.8454132	0.14
224.1030121	0.55
229.2034607	0.28
230.2201538	0.07
244.0616455	0.08
253.2298889	0.19
255.2023621	0.40
257.2867737	0.12
270.9533386	0.41
272.1616211	1.11
284.0285950	0.59
285.3283997	0.19
287.1271973	100.00
288.1290894	0.32
289.0510559	0.25
295.1423035	0.39
296.1944885	0.40
299.1259460	0.74
305.0521240	6.67
308.1369629	0.03
313.0108032	2.38
314.0941772	8.34
314.8564758	0.04
320.7805176	0.12
322.1188049	1.11
327.1925049	0.90
337.1697083	0.39
338.1624146	5.34
339.2941895	0.13
343.8581543	0.18
344.5863342	0.08
345.1975403	0.31
346.4329529	0.23
351.3483582	0.04
352.3427124	0.04
353.0598145	0.79
353.9740601	0.34
357.4142456	0.21
361.3716431	0.12
367.5382996	2.23
368.2291565	13.57
369.0886536	0.19
371.1362000	0.29
374.4740906	0.19
380.1172791	4.85
388.5040894	0.59
389.8651428	0.54
398.2002258	15.01
403.2963867	0.28
405.3558350	0.16
406.4643555	0.09
415.0370483	1.57
416.1174927	72.40
417.0626526	0.76
425.2236633	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
279.1934814	1.65
391.2859497	0.05
433.4614868	0.09
459.4095459	0.11
504.2576294	100.00
505.1347046	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2531
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
143.0713654	0.04
145.0701752	0.16
147.0418243	0.09
149.1438599	0.10
152.9172211	0.05
155.1412354	0.19
156.9724884	0.13
158.9532166	0.18
161.2340088	0.05
163.0268250	0.07
164.8483124	0.08
167.0976868	0.22
168.1260986	0.02
169.0869293	0.33
171.0623169	0.27
173.0214233	0.05
174.1832275	0.09
175.0998077	0.24
177.1627808	0.24
178.4513245	0.01
179.0935669	0.09
181.0733490	0.02
181.8609009	0.07
183.0806885	0.24
185.1751404	0.20
187.1346436	0.04
189.0177002	0.05
190.7740326	0.15
193.1593781	0.09
195.1098175	0.75
197.0848083	0.12
199.2569122	0.27
201.2842712	0.12
203.0457001	0.02
204.9514008	0.07
207.1608276	0.78
209.0202026	0.09
210.9942627	0.33
213.2739868	0.06
214.9909363	0.35
217.1582336	0.22
218.9899902	0.03
221.0014648	0.23
223.2290955	0.22
225.2221680	0.28
227.1737518	0.30
229.1562805	0.26
230.7803345	0.01
233.3442841	0.06
237.2245483	0.11
239.1496582	1.49
241.2725525	1.38
243.0401764	0.15
245.1901245	0.31
247.1262817	0.60
249.2968903	1.70
251.2257538	0.06
253.1379700	0.03
255.3395691	0.11
257.1393738	1.56
257.8828125	0.02
259.1367798	0.16
261.0146484	0.30
263.2479248	0.13
264.0178833	0.07
265.2738953	0.05
267.1530151	6.80
269.2514038	0.99
271.1382446	0.22
273.1444092	0.38
275.0213013	0.23
281.2129517	0.22
283.2194214	0.22
285.1331177	16.33
287.1379395	0.97
291.1922913	0.11
294.5587769	0.13
295.2163696	3.37
297.0452271	0.25
299.2617798	0.04
300.9633179	0.26
303.2211914	2.15
304.9670410	0.10
307.0441284	0.06
311.3476562	0.13
313.1376343	25.60
313.7660522	0.07
315.2047729	1.70
319.3000488	0.07
321.2078247	0.19
323.7145996	0.03
329.2265625	0.16
331.1196289	100.00
331.7608032	0.06
333.2279663	1.23
333.8451538	0.02
337.1094971	0.30
339.3087769	0.06
341.1694336	0.05
346.3273926	0.08
347.0699463	0.09
349.1397095	41.04
349.7532959	0.05
351.3599854	0.31
353.3101196	0.10
355.2983398	0.07
357.1461182	0.13
359.2221069	0.05
361.3475342	0.06
365.2094727	0.12
367.0150146	0.32
369.0952759	0.28
371.0108643	0.04
373.3237305	0.25
377.4699707	0.06
378.3171997	0.04
379.3401489	0.04
383.1107788	0.06
385.1605225	0.13
387.0654907	0.05
389.3874512	0.16
390.2565918	0.04
393.4285889	0.28
397.0032959	0.54
401.2789307	0.08
403.3823242	0.08
409.1049194	0.05
411.2295532	0.24
415.2634888	0.33
417.1203003	0.05
419.5214844	0.01
421.3535767	0.10
423.0750732	0.06
427.0663452	0.25
429.1957397	0.33
430.5041504	0.06
431.6816406	0.11
433.3291626	0.15
435.1595459	0.06
436.3636475	0.03
439.2488403	0.16
445.4926758	0.15
447.0725708	0.40
448.3915405	0.05
449.5271606	0.02
450.2415161	0.03
451.5287476	0.07
457.2789917	1.39
458.8608398	0.05
459.7794189	0.04
463.7262573	0.02
465.1618652	0.96
467.5286865	0.25
475.1862183	3.15
479.3936157	0.02
482.7459717	0.10
483.7887573	0.06
490.8181763	0.04
493.2183228	22.47
493.8387451	0.11
494.4591675	0.04
502.1868286	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.2137
Annotation	Unknow
Peak:m/z	Relative Intensity
192.7662201	0.10
194.9764404	4.12
206.9486084	0.07
211.0451508	0.22
220.0437317	0.26
223.0167542	0.22
228.9254761	0.14
241.0780334	0.09
246.8209839	1.04
248.9966125	0.52
253.0684509	0.12
258.7529907	0.45
261.1498108	0.76
270.2609253	0.76
271.0155029	5.42
276.8608398	0.27
286.9600830	0.15
288.3149719	1.02
288.9949951	5.51
289.9089355	0.38
294.7713623	0.17
295.9465332	2.33
303.0600586	0.20
305.9194336	0.99
306.8780823	5.92
307.8335571	0.32
319.9495239	0.20
324.8009949	100.00
325.9449463	2.59
339.7072754	0.15
340.7913208	0.48
342.1335449	9.76
342.7700195	64.89
343.7188110	0.58
356.9081421	27.48
366.7806396	0.42
396.6010742	0.38
414.7160034	0.06
420.7413330	0.35
432.8127441	0.72
450.4813232	1.98
451.4047241	0.08
468.4715576	0.38
474.9004517	2.99
476.0733643	27.42
486.6818848	11.77
487.3439331	0.24
504.0703125	2.53
504.8146973	4.96
516.3881836	0.31
518.2187500	3.34
518.8694458	12.74
601.8674316	0.18
619.6957397	0.77
620.3650513	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1059.5699
Annotation	Unknow
Peak:m/z	Relative Intensity
345.2151489	0.05
346.9396667	0.16
351.0805359	0.43
352.7012329	0.10
363.4387512	0.35
365.3460693	0.03
405.1614380	0.43
407.1641541	0.25
425.3569946	0.08
439.2461853	2.08
440.0262451	0.04
479.0443115	0.24
479.6786499	0.11
530.8229980	0.11
537.4174805	0.20
540.1025391	0.85
551.3835449	0.32
569.2904663	7.80
570.2960205	0.89
587.3111572	1.11
588.4976807	0.20
591.4799805	0.16
615.4001465	0.80
619.6844482	0.16
633.6790771	0.25
664.0233154	0.12
671.6051025	0.04
673.4280396	0.60
683.4067383	0.03
713.3329468	0.22
717.5296631	0.32
729.5008545	0.05
731.3583984	100.00
732.4718628	6.93
735.6011963	0.18
747.3731689	0.09
753.2167969	0.38
753.9122925	0.11
803.7884521	0.15
815.6702881	0.14
876.7813721	0.08
897.4816895	7.31
898.5850830	0.66
899.2176514	0.05
915.5483398	3.31
916.8304443	0.34
940.3308105	0.11
943.5650635	1.77
944.6047363	0.30
955.8349609	0.03
965.1741943	0.13
1001.5280760	0.75
1013.1053470	0.06
1023.0708010	0.24
1027.1173100	0.09
1041.1943360	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.188
Annotation	Ciceritol
Peak:m/z	Relative Intensity
204.8919678	0.07
207.1588898	0.11
222.9082794	0.12
230.8028107	0.08
249.1501312	1.18
262.0892944	0.03
267.0164795	100.00
268.1828003	0.07
284.0095215	0.06
346.0349731	0.30
350.2833252	0.05
385.9971924	0.01
388.0980835	0.24
404.1260376	0.03
417.0581055	0.03
563.0631714	0.17
571.1342773	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2809
Annotation	Unknow
Peak:m/z	Relative Intensity
181.2932739	0.14
182.9508209	0.08
189.0449982	0.41
201.2524414	0.11
203.0482788	3.65
206.8885345	0.13
209.0053558	0.09
217.0021057	0.09
218.5109863	0.07
219.1429138	0.06
231.2757111	0.13
237.1436462	6.45
241.1517334	0.04
243.2632751	0.34
245.1558533	0.43
259.1554565	0.54
267.1338501	0.08
268.1924133	0.12
273.1392822	0.05
274.9997864	0.23
279.1821289	0.27
281.0786133	100.00
295.2820435	1.12
305.1441956	9.50
307.1909790	0.33
313.1052246	0.16
319.1395874	0.08
321.9908447	0.10
322.9841919	4.33
335.1431885	0.31
343.2008667	0.18
347.1939087	0.28
352.6120605	2.47
353.2761841	2.93
364.4546509	0.25
365.2055054	1.68
370.7264404	0.23
376.9750977	0.14
382.6530151	2.43
383.2745361	0.64
404.1491089	0.09
405.4293213	0.50
407.0101318	0.19
413.0589600	0.59
425.2271729	0.41
432.1360474	0.16
442.2491455	2.75
442.9763794	21.56
467.3768921	0.61
469.1158447	0.37
485.0709229	0.10
490.5211182	0.37
526.8163452	0.11
532.0313110	0.27
553.1354370	0.14
557.1620483	0.22
587.3405151	0.05
601.0895386	0.08
603.4731445	0.12
610.9701538	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	770.7455
Annotation	Unknow
Peak:m/z	Relative Intensity
222.0943756	0.38
245.0049744	0.89
275.1541443	0.19
284.5997925	0.41
285.7223206	0.54
304.9887085	1.26
306.0249939	0.55
315.0725708	0.52
324.9282837	0.67
326.4982910	0.46
333.9647217	0.20
337.4645996	0.42
338.8393555	0.40
346.2002563	0.42
347.3374634	0.24
356.7153931	0.82
357.5579834	0.16
365.6012573	8.44
366.5010376	0.60
384.0149536	1.35
396.1315308	0.77
403.7458496	0.69
407.0552368	1.00
407.9044800	0.36
417.1982422	3.63
426.2604370	1.52
431.1529541	0.64
437.1042480	2.03
437.9084473	3.64
446.7777710	9.36
447.8181763	2.16
449.1972656	0.60
467.0507202	1.19
467.8392334	0.42
468.6962280	0.10
477.2294922	1.70
486.4550781	0.09
489.2468872	0.93
491.1036377	0.84
492.2747803	0.68
493.2841797	0.39
496.0770264	0.54
496.8469849	0.36
498.2562256	3.93
499.0561523	0.16
507.4566040	4.97
509.0490112	2.65
510.1560059	1.18
511.6077271	0.32
518.9027710	6.17
519.7893066	0.92
521.1029663	0.40
524.9953003	0.24
526.8489990	1.50
527.8836670	37.54
528.8605347	4.90
529.5087891	0.43
530.1370850	0.19
539.7896118	0.26
549.7221069	1.03
551.1912231	1.23
552.0869751	0.64
558.1795044	1.50
565.1393433	0.45
569.1808472	3.77
570.1431274	0.56
571.1068726	0.44
579.1560669	1.97
579.8404541	0.88
581.0880127	0.96
586.3295288	0.27
588.4525757	3.65
589.3313599	0.70
593.2125244	0.34
594.2427368	0.16
599.5059814	9.86
600.3341675	8.36
608.8926392	42.34
609.8012085	4.85
622.4484253	0.56
629.4132080	0.06
630.8917847	0.19
639.4505005	2.76
644.0321655	0.26
651.5941772	1.05
653.1278687	0.28
660.5421143	12.32
661.4338989	0.81
669.3794556	43.16
670.3118286	6.93
671.2549438	6.22
672.1864014	2.42
673.3497314	0.77
681.0667114	25.76
683.7102661	0.14
685.2307739	0.59
689.9492188	100.00
690.8991089	7.45
691.5727539	0.36
693.9169312	0.16
694.8589478	0.57
697.8590698	2.62
710.8300781	1.66
713.4364014	0.27
720.3547974	4.23
721.2586670	4.53
731.1287231	9.68
732.0195923	3.94
743.2473755	0.35
752.7794189	1.08
753.5923462	0.65
758.8498535	0.25
760.9896240	1.39
761.6731567	10.16
762.3601685	4.15
775.0603638	0.47
791.0820923	1.24
792.0125122	0.61
803.0285034	1.29
804.6737061	0.56
814.7516479	0.88
815.3610229	1.09
816.2277832	0.16
817.4151611	0.33
820.8961792	0.50
833.1732788	1.97
834.2738647	0.36
835.4497070	0.42
845.3231201	0.43
851.3540039	0.44
852.2919312	0.29
853.2356567	0.11
856.0639038	0.14
857.1316528	0.18
863.9950562	0.37
875.1666870	0.33
876.2056885	1.48
877.4768677	0.60
892.5642090	1.08
893.2258301	18.26
894.2595215	6.11
895.3581543	0.27
896.5884399	0.54
923.0933228	0.23
933.8298950	0.30
952.6834106	0.34
977.1149292	0.59
993.0487671	0.22
993.9609375	0.23
995.2173462	1.75
996.8213501	0.43
1012.8941040	3.83
1014.1162110	1.03
1036.6759030	2.12
1037.5478520	0.27
1039.0594480	0.55
1055.1701660	16.36
1056.4044190	8.67
1057.3581540	0.47
1067.4442140	1.16
1085.5330810	0.16
1097.4060060	0.27
1114.4016110	0.53
1116.2556150	0.60
1147.4770510	0.33
1157.2834470	0.42
1157.9262700	0.47
1159.3190920	0.52
1175.1914060	0.76
1177.2550050	0.19
1180.3798830	0.39
1198.1168210	1.23
1199.1141360	1.25
1200.5567630	1.07
1217.1254880	2.66
1218.3349610	1.38
1219.4715580	0.34
1229.1395260	0.29
1248.4019780	0.43
1277.2526860	1.16
1319.3302000	0.15
1337.4417720	1.25
1338.2108150	0.26
1339.0750730	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
185.1454163	0.01
191.0371094	0.03
192.9672394	0.02
206.357193	0.01
229.0732422	0.02
254.3823853	0.01
258.223999	0.03
266.0545044	0.03
271.0939026	1.88
272.0990906	0.53
278.0975952	0.03
283.0713501	0.22
283.914856	0.05
291.1046143	0.01
295.1426392	0.69
295.9161377	0.11
297.3442993	0.01
303.1378174	0.03
307.9508667	0.02
313.0828857	4.28
314.2003784	1.07
332.2525635	0.17
333.2613525	0.01
337.2178345	0.32
338.1182251	0.04
343.2780151	0.02
349.1824341	0.02
355.4384155	0.04
356.2114258	0.02
357.1368408	0.03
361.3787842	0.02
367.1228638	0.35
368.192688	0.18
374.2108154	0.03
379.1027222	0.18
380.3310547	0.06
386.3860474	0.05
387.2327881	0.01
393.4840698	0.02
394.2026367	0.02
396.2197266	0.09
397.1218872	1.00
398.1695557	0.30
399.0661011	0.02
403.4302368	0.01
414.0499878	0.08
415.1290283	9.34
416.1447144	2.60
417.1955566	0.30
418.0970459	0.15
423.1032715	0.09
427.1639404	0.04
428.2252808	0.03
430.3622437	0.05
433.116333	100.00
434.1434937	25.51
434.8511963	0.03
436.187561	0.03
441.1578369	0.22
442.1827393	0.05
443.5373535	0.01
447.0159302	0.01
448.2418213	0.01
449.1991577	0.01
451.057373	0.03
454.2485962	0.04
457.1500854	0.12
459.0198975	0.22
459.9539185	0.05
462.3190308	0.01
463.0774536	0.01
467.2675171	0.03
475.2866211	0.10
476.5174561	0.03
481.1728516	0.02
482.2269897	0.06
482.8673706	0.02
484.248291	0.04
486.7797241	0.06
500.2163696	0.03
507.3774414	0.01
508.2493286	0.01
512.8655396	0.03
516.0603638	0.00
520.1768188	0.01
521.1760864	0.01
525.1434937	0.33
526.3074341	0.17
529.2859497	0.03
531.2556763	0.01
536.343689	0.03
538.9675293	0.02
543.1643677	0.11
544.2338257	0.06
545.0672607	0.01
546.9896851	0.01
548.3224487	0.04
549.2924805	0.07
552.281311	0.00
561.0908203	0.51
562.0564575	0.20
562.6824341	0.03
570.8171997	0.03
580.5557251	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.1563
Annotation	Chitobiose
Peak:m/z	Relative Intensity
126.9339066	0.04
128.8928528	0.12
130.1540527	0.12
150.0193939	3.75
156.0941315	0.06
159.0434265	0.11
185.0679932	0.52
188.0357513	0.18
199.3901367	0.04
202.8266754	0.23
213.0282288	0.23
215.2749481	0.29
218.9754639	0.28
223.1933289	0.19
230.3221283	0.04
246.8754883	0.11
253.2169189	0.17
264.0072937	0.06
268.9958191	0.17
271.0497742	0.03
273.9089966	0.02
280.0760193	0.04
282.0446777	7.31
283.9792480	0.06
285.1394043	0.07
287.1649780	0.08
295.1430054	100.00
296.5260925	0.05
298.4189453	0.14
301.1610413	0.19
306.0562744	0.07
307.2183838	0.45
310.1938477	0.06
315.1006470	0.56
318.2049561	0.06
325.5072327	0.04
327.4607849	0.15
330.8408813	0.03
333.3253784	0.13
338.2480164	0.18
345.6371460	0.71
346.2542419	0.14
349.2269287	0.11
350.8985901	0.07
352.2712097	0.18
365.0113831	0.18
366.9029846	0.80
368.3864441	0.07
381.2561646	1.97
383.2784424	0.24
385.4192200	0.28
391.3707886	0.10
393.6426697	0.16
396.7366638	0.25
406.2292786	0.12
408.2877197	0.24
409.1602478	2.01
410.2729492	0.18
418.0518188	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.1758
Annotation	Unknow
Peak:m/z	Relative Intensity
145.7947083	0.14
147.9161987	100.00
162.8866577	0.14
183.9888458	0.04
194.9943542	0.55
291.8845215	0.14
309.7125549	0.81
310.3525696	0.07
324.4176331	0.07
327.0952759	0.15
327.8522034	0.04
342.9095764	0.65
357.3338013	0.25
377.5185242	0.12
379.2807922	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.4119
Annotation	Unknow
Peak:m/z	Relative Intensity
252.9107208	0.26
259.1479492	0.39
263.3745422	0.09
265.1687317	0.11
277.3391113	0.36
289.2726440	0.16
290.6924744	0.07
295.3099670	0.07
305.0971375	0.27
321.2227173	0.06
323.0286865	0.99
327.7700806	0.15
329.2559814	0.31
340.6645813	0.13
361.1571045	0.15
365.1608582	0.08
370.3559570	0.05
379.1196899	2.17
383.1649170	0.52
393.3873901	0.06
395.3320312	0.24
397.1570435	6.54
406.3329468	0.58
415.2073975	4.19
421.3245850	0.06
425.2996826	0.63
429.4736938	0.11
439.1803589	1.50
442.9263916	0.28
449.0876465	0.88
450.4926758	0.40
463.4912109	0.12
466.3245850	0.04
467.2977295	1.18
471.7902832	0.17
481.5150757	0.09
482.5546875	0.46
485.3031616	0.78
495.5819092	0.17
499.2897339	0.07
504.9088745	0.26
506.1494141	0.17
511.4002686	0.20
513.3901978	0.49
517.0795288	0.28
518.3635254	0.12
523.3043213	0.25
525.2577515	0.16
541.4571533	0.07
556.0671997	0.11
557.7467041	0.07
559.2705688	100.00
577.1519165	44.19
577.8406982	0.08
580.3801880	0.27
614.3101196	0.17
621.3782349	0.04
630.0269775	0.14
657.3101196	0.38
659.6365356	0.08
662.3461304	0.08
669.4006348	0.07
674.6780396	0.06
675.4297485	0.25
684.8202515	0.06
687.3881226	0.21
688.5452271	0.16
691.6076660	0.12
699.3646851	0.10
700.6979980	0.23
704.4225464	0.06
705.3186646	0.11
706.1028442	0.17
712.8865356	0.05
714.4176025	0.09
720.4426270	0.20
732.8662720	0.14
740.5072021	0.07
744.5673218	0.09
745.4979858	0.10
749.4172974	0.79
758.3047485	1.32
759.3246460	0.29
760.9110718	0.17
772.1063843	0.35
773.7739258	0.19
774.4246826	0.42
776.4235229	4.77
777.4130249	0.36
791.5041504	0.16
792.5114136	0.48
793.7333374	0.76
800.5380249	0.41
801.5825806	0.13
809.2482300	0.08
818.4028320	2.89
819.4382324	3.22
820.4555054	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2029
Annotation	Kunzeaphlogin F
Peak:m/z	Relative Intensity
160.9677887	6.16
167.0862122	0.19
178.9260254	6.79
188.9976196	0.24
203.0779266	0.44
221.1305847	0.14
223.0787964	36.69
232.9938507	1.04
241.2712402	0.32
243.0216980	0.26
249.0900726	0.37
261.9716187	0.16
263.1364441	6.72
267.0401001	0.09
278.8989563	0.23
285.3453369	0.17
293.0787354	0.20
309.4212646	0.09
310.9875488	0.10
320.1937866	0.24
323.1207275	24.13
324.5362549	0.97
325.3519287	0.71
342.7833252	0.19
343.5066528	0.06
359.0951538	1.00
367.0580444	0.12
384.6970825	1.45
385.6101074	0.94
401.2192383	0.66
403.1892090	100.00
413.4089966	0.08
415.2424927	0.37
422.4710693	0.22
426.0618896	0.49
426.6964722	0.14
431.3687134	0.62
432.7255859	0.16
441.2916260	0.86
445.0668945	19.89
445.6802979	0.10
447.3869019	0.69
456.4625854	0.30
457.2677612	0.66
460.4464722	0.48
470.7732544	0.18
472.2069702	0.21
485.1682129	5.76
486.8844604	0.39
487.7033081	0.09
490.5313110	0.57
501.1394653	3.51
502.0262451	0.31
503.1666870	0.57
504.3171387	0.16
505.1887207	0.82
511.0011597	0.76
514.9838257	0.56
528.4849854	0.99
529.2910767	0.43
530.3936768	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	530.2949
Annotation	Cuniloside
Peak:m/z	Relative Intensity
159.0867004	0.15
178.7314606	0.17
184.9487305	0.07
194.9792786	0.20
219.3276215	0.18
241.0639496	0.23
259.1785583	8.30
269.2058716	0.69
271.1882935	2.58
271.8812866	0.23
276.4710693	0.23
282.4058533	0.18
286.3485718	0.41
287.1004333	1.12
287.7526855	0.21
290.8701172	0.11
296.9389648	0.49
302.3587646	0.19
305.2187805	1.42
315.1260986	4.92
322.3344116	0.19
324.8120117	0.07
329.6043091	0.33
331.5993652	0.39
333.1051636	16.34
349.3281250	0.45
351.1509399	33.62
351.7935791	0.46
354.2911987	0.31
360.0289307	0.27
367.2033691	0.25
368.1187744	0.13
371.2398682	0.29
372.0668335	0.08
374.0845337	0.24
375.1937256	0.18
378.1856689	0.08
379.1873169	0.04
389.2713623	0.09
391.3558350	0.15
401.2937012	0.17
409.6503906	0.40
421.1254883	2.23
434.4269409	0.67
435.1454468	0.23
438.3037720	0.30
448.7970581	1.99
462.8853149	0.19
468.1303711	0.78
470.1654663	0.39
475.9880371	0.11
476.6231079	0.08
480.4532471	0.08
483.2702026	0.12
484.2680054	0.27
486.3927002	0.15
487.3646851	0.36
488.2602539	0.63
494.3445435	3.02
495.2006226	2.30
496.3153076	0.26
498.3184204	0.08
499.1979980	0.07
500.3140259	0.33
505.6051636	0.37
511.9280396	3.53
513.1558838	100.00
513.8659668	0.15
516.2909546	0.09
521.3297119	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
149.0725708	0.04
189.0706177	0.09
191.0229492	0.06
192.8117981	0.04
207.1204987	0.05
233.1625977	0.04
242.025116	0.01
246.1739502	0.03
247.1696472	0.13
251.2035522	0.89
253.0327454	0.07
255.0913696	0.17
259.1056824	0.04
268.170105	2.20
269.0611572	16.25
270.1471863	0.62
281.2503052	0.08
283.035614	0.52
287.3589478	0.05
291.0299377	0.12
292.9309082	0.15
311.0476074	100.00
312.0692139	0.27
318.9307251	0.03
323.2192993	0.48
325.3157349	0.09
333.2379456	0.03
334.9869385	0.04
337.1410522	0.60
339.3357544	0.04
341.1639709	17.45
341.963562	0.06
343.4873047	0.02
347.2503662	0.06
351.2455139	0.03
352.9415894	0.59
355.0465088	0.26
365.304718	0.07
371.1260681	0.58
373.455658	0.04
377.150238	0.36
377.8194275	0.09
383.0582581	0.30
385.0990295	0.08
395.0704651	0.45
413.0911865	2.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1696
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
189.2367706	0.06
206.8722534	0.05
220.947876	0.06
270.9946594	2.28
272.1789551	0.03
283.3222656	0.07
289.1247253	0.07
294.9276733	0.38
301.3911133	0.08
313.0825195	2.91
321.0632324	0.05
322.1043701	0.07
337.0430908	0.21
343.3200684	0.05
367.0464478	1.50
368.8203125	0.06
379.2689209	0.49
389.7271729	0.04
397.1356812	1.87
398.2827148	0.03
399.2798462	0.05
415.0998535	9.99
417.109375	0.31
427.1294556	0.08
433.1136475	100.00
434.0829468	0.15
435.0581665	0.14
441.2451782	0.19
442.6470337	0.13
445.1430664	0.43
450.2584229	0.10
458.0419312	0.09
459.1431885	0.04
462.286499	0.14
463.0075684	1.57
464.1147461	0.76
475.3817139	0.03
481.368103	0.14
482.4361572	0.10
488.4330444	0.15
492.0964355	0.04
497.8394775	0.24
498.5233765	0.14
507.3501587	0.11
509.3248901	0.04
513.0112915	0.04
517.1583862	0.03
520.0057373	0.08
523.861145	0.08
524.9713745	0.16
531.3168335	0.02
534.689209	0.38
542.2313232	0.21
543.2077026	0.88
549.0024414	0.15
552.3217163	0.01
553.5266724	0.06
560.2019653	5.23
561.1690063	3.88
562.1123047	0.18
569.770813	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1975
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
162.8988037	0.07
178.4002228	0.05
195.0602875	0.06
204.9894409	0.11
205.9652405	0.06
210.1015930	0.26
225.1964722	0.13
255.1782532	0.15
257.0897217	0.07
267.2558594	0.03
279.0225220	0.02
280.2464294	0.16
280.8858032	0.09
293.1022339	0.15
296.5331116	0.07
297.1953125	1.92
315.1656494	1.28
318.2261963	0.10
322.7528687	0.04
323.6324463	0.04
327.1425171	52.70
328.0666504	0.18
330.8692627	0.23
334.2328491	0.10
339.1402588	0.13
340.1554565	0.06
345.1094971	11.50
352.1824341	0.04
354.4150391	0.06
357.0610962	43.54
363.1102905	0.09
371.9672241	0.11
373.3781738	0.07
375.0059814	100.00
375.6708374	0.22
376.3850708	0.04
380.1334229	0.18
381.1647949	0.22
386.9750366	0.03
389.2479858	0.32
390.1478271	0.21
391.5440674	0.09
394.0455933	0.04
405.2589111	0.03
417.2317505	0.17
418.3076172	0.14
440.0769653	0.53
441.1588135	1.41
442.1681519	0.88
470.0289307	0.02
475.4025879	0.06
476.7365112	0.05
489.2775879	0.20
491.0385132	0.66
491.7645874	0.06
493.3330078	0.51
504.1701050	0.04
507.0122681	0.89
509.1795654	0.05
518.4162598	1.93
519.2910156	2.11
520.1037598	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1829
Annotation	Unknow
Peak:m/z	Relative Intensity
236.1672974	0.04
343.9824829	0.03
349.0579224	0.08
361.0221558	0.03
362.2645264	0.22
414.2680664	0.18
421.6051636	0.04
423.1252441	0.05
443.5014038	0.06
451.6268921	0.03
476.3596191	0.06
482.3418579	0.09
510.9934692	0.20
524.0805054	0.06
525.2537231	0.80
532.8289185	0.44
533.8601074	0.85
541.2672729	0.09
543.2153931	100.00
544.3760376	0.42
560.9702759	0.11
566.0202637	0.10
571.2286987	0.04
576.1249390	0.04
578.7697144	0.07
606.2918091	0.27
615.2598267	0.16
620.0344238	0.22
623.6080322	0.23
637.8905640	0.45
664.1458740	0.20
683.0035400	0.05
687.4074097	0.28
713.6897583	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.2666
Annotation	PS(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
147.2182770	0.20
149.0788422	0.14
154.9024963	0.88
158.9884338	0.26
161.0104370	0.24
163.1144409	0.44
165.1839447	0.11
167.1024628	0.16
173.1739960	0.10
175.0958099	0.16
177.0804443	0.09
179.1276703	0.04
184.1176300	0.06
185.1990356	0.06
186.1079712	0.07
187.0602112	0.02
188.6614227	0.13
189.3764648	0.14
195.8831024	0.06
200.9728394	0.12
202.9561310	0.17
215.3846283	0.26
223.0635986	0.09
227.0776367	0.09
229.2090759	0.03
231.1565704	0.20
237.1536560	0.22
239.5381012	0.08
242.0427094	0.63
243.1730957	4.84
245.3721008	0.11
257.2421875	0.06
260.2565918	0.67
261.1897583	11.14
264.7624512	0.05
269.3759460	0.07
285.3873596	0.09
291.0406494	0.08
292.8264771	0.05
305.3319092	0.14
306.0803223	0.03
312.9855347	0.07
317.2932739	0.95
319.1339111	0.08
323.1226196	0.11
325.2847290	0.11
326.9782715	0.06
329.4154053	0.05
330.5151978	0.29
331.1935425	0.02
335.2442017	29.09
335.8684692	0.19
336.8781738	0.17
339.1842041	0.10
344.3798218	0.17
345.4237671	0.03
348.2867432	2.29
359.3308105	0.08
364.5146484	0.07
365.8051758	0.08
377.9270020	0.12
378.9594727	0.14
389.3975220	0.12
390.2040405	0.20
392.1217651	0.08
393.3161011	0.08
394.4320679	0.04
397.1929321	0.04
401.1928711	0.06
406.1390991	0.02
407.8568115	0.10
413.5493164	0.53
415.1692505	22.39
418.1115112	0.08
422.4849243	0.45
423.4794312	0.05
426.9348755	0.20
430.2422485	0.18
432.6389160	0.05
433.2550049	2.50
446.1763916	0.27
448.0527954	0.05
451.3162842	0.18
452.9155273	0.23
454.3161621	0.08
455.3627319	0.27
467.2443237	0.37
471.2218018	0.40
473.7025757	0.54
476.1504517	0.42
480.0520630	0.06
484.9064941	0.26
487.0731812	0.10
487.9893799	0.14
502.1268921	100.00
502.8969727	0.14
511.8548584	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	340.2129
Annotation	Unknow
Peak:m/z	Relative Intensity
116.9905319	0.13
127.0819321	0.08
127.9946442	0.48
129.9595642	29.71
143.1826935	0.37
147.2183838	0.21
151.3113251	0.09
161.0590515	0.28
164.0319519	0.13
165.1427917	0.52
166.9022522	0.08
177.1458130	0.13
178.9983673	0.45
191.7281952	0.05
200.2967834	0.13
203.0500031	0.28
211.0165100	0.56
216.8963318	0.18
219.1203918	0.06
221.2718811	0.15
225.3652954	0.08
226.9593201	0.24
229.1348877	0.18
230.0876465	0.05
239.8677368	0.05
242.1202393	0.22
247.0908508	0.11
248.1265259	0.41
256.1059570	0.06
260.2695007	1.12
265.2992554	0.04
266.0703125	0.18
267.0677490	0.45
269.1402893	13.96
276.0652466	0.09
278.5058594	1.15
279.2700195	1.71
281.0196228	7.37
281.9990234	6.36
283.0951233	16.41
284.0775452	0.29
285.1500549	0.22
293.1265259	2.50
295.1206055	11.12
296.0569763	0.94
297.0527954	0.43
297.9542847	0.24
304.2705994	0.25
306.3621826	0.07
308.1110229	0.80
309.0632019	0.25
311.0327759	7.39
311.8738708	0.18
313.0341797	0.45
321.1403503	0.73
323.0985413	100.00
324.4710693	0.07
325.0797729	1.11
340.2000427	0.07
341.1220398	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
113.0545044	0.04
131.1203003	0.05
143.0183563	0.11
149.0747986	0.02
151.0222168	0.03
160.9397888	0.04
161.7031555	0.08
178.9825745	0.48
180.0308228	0.06
196.9414368	0.28
198.1010437	0.04
199.0788574	0.57
215.0380554	1.79
216.2042542	1.52
217.0996094	9.41
341.1289978	100.00
342.1426392	19.72
343.1059875	10.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.5006
Annotation	PI(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
233.0705414	0.22
241.0572968	29.13
242.1308594	1.00
253.2530823	0.31
255.1527405	49.16
256.2661743	8.62
259.0618591	1.74
259.8937378	0.22
275.3037109	0.35
277.3095093	16.42
278.2751465	3.51
279.1910706	1.74
297.0064087	16.67
298.1679382	1.75
315.0315552	4.43
368.5982666	0.14
389.2415161	0.37
391.2250366	62.45
392.3432007	11.96
409.2124023	3.51
410.1539307	0.34
413.2222290	7.77
414.3041992	2.17
415.4230347	0.71
431.1606445	0.12
461.3562622	0.19
479.4915771	0.27
497.5310059	0.35
498.3020630	0.66
551.5638428	0.51
553.3038330	100.00
554.3948364	25.37
558.0327759	0.24
569.4682007	0.67
571.2592163	20.34
572.3984985	8.51
575.3026733	25.70
576.2658081	5.18
577.3129272	1.02
588.1076050	0.15
593.4590454	2.73
594.4352417	0.90
595.6401978	0.68
669.3386230	0.33
670.2273560	0.25
671.3150024	0.40
700.0650024	0.25
735.2979126	0.18
772.2920532	0.32
779.9032593	0.10
813.9523315	0.39
814.7280273	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0978
Annotation	Vitexin
Peak:m/z	Relative Intensity
283.1102295	0.20
293.5150452	0.14
309.0547485	0.06
311.0544128	100.00
312.1364136	0.33
320.8892822	0.04
323.0687561	0.74
333.2801514	0.08
337.3594971	0.14
341.1698608	27.07
349.0260925	0.02
351.0974731	0.04
353.1063843	1.25
355.3047485	0.40
365.1980286	0.08
367.1503906	0.28
371.0375671	1.05
372.22995	0.05
377.0855103	0.60
383.1782532	1.07
385.5211487	0.03
395.2013855	0.77
413.1159973	6.89
413.7583008	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1089.4967
Annotation	Unknow
Peak:m/z	Relative Intensity
304.8214111	0.04
322.8066101	0.20
333.2425842	0.03
340.4673157	0.36
341.1040649	0.86
342.0810852	0.20
349.0891724	0.02
359.1701660	0.10
365.2204895	0.36
366.2037964	0.05
367.0437012	0.02
379.0971680	0.22
381.8937378	0.08
383.1373901	4.16
384.2073059	0.20
388.7639160	0.09
394.8765259	0.06
413.0098572	0.30
423.4207153	0.06
424.9186096	0.16
425.6994934	0.16
439.6203613	0.04
440.8905029	0.06
442.8222046	1.60
444.0159912	0.21
449.0213013	0.55
450.0497742	0.10
453.1198730	0.06
455.2251587	0.08
461.2691650	0.17
466.9056396	0.77
468.0671692	0.21
483.2994995	0.19
485.1235657	2.06
486.2653198	0.22
491.4364014	0.05
493.0079346	0.07
503.0230103	2.10
503.9842834	0.05
505.5090942	0.05
509.0217285	0.19
510.2176514	0.07
527.2665405	3.34
528.2304688	0.61
545.1770630	7.21
546.3084717	0.75
556.8846436	0.03
559.2589722	1.36
560.3909912	0.22
569.0513916	0.18
570.1982422	0.06
571.2766113	0.05
574.9250488	0.14
585.2544556	0.06
587.1432495	1.25
588.1846924	0.10
599.1813965	0.09
602.6704102	0.28
603.3695068	0.30
604.3823853	0.07
605.2412109	0.25
611.2862549	0.68
612.2893066	0.18
627.3098145	0.02
629.0361938	1.23
630.6021118	0.16
636.1232910	0.16
641.6248779	0.14
645.1290283	1.29
646.9610596	1.69
648.1102295	0.33
658.8779297	0.29
665.1241455	0.40
665.9805908	0.08
689.3308105	0.68
690.4248047	0.27
704.8221436	0.31
707.3093872	0.03
719.9285889	0.04
731.9309082	0.06
738.5314941	0.02
741.4871216	0.03
747.1546631	0.16
748.4649048	0.04
752.8417358	0.07
762.4955444	0.07
765.4884033	0.28
766.2120361	0.05
791.3387451	0.14
807.1345215	3.94
807.7540283	0.59
809.2093506	100.00
810.1807861	20.43
811.2155762	0.11
827.1776123	33.36
828.2969971	6.82
831.2331543	0.16
831.8925781	0.08
849.3736572	0.13
866.7907715	0.03
891.3288574	0.10
909.2457275	0.38
910.3254395	0.07
926.6248779	0.18
970.5452881	0.04
1043.6259770	0.29
1071.0533450	0.10
1072.3026120	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.09
Annotation	Homoorientin
Peak:m/z	Relative Intensity
138.1434631	0.07
144.9906921	0.07
165.0570068	0.14
175.0258484	0.04
187.1387482	0.03
200.8536224	0.04
214.8540039	0.16
219.219986	0.09
222.6795197	0.03
231.1794434	0.11
239.351593	0.12
240.0700073	0.11
240.9211731	0.46
265.0948181	0.20
267.0596313	3.44
269.2107544	0.13
283.0221863	0.94
284.4220886	0.14
285.2599487	1.23
297.0725098	0.26
298.0733948	0.16
303.2538757	0.56
309.3223877	0.07
313.4432068	0.14
315.389801	0.10
321.3114624	0.38
325.1884766	0.16
327.0532532	100.00
337.0888367	0.16
339.0797729	2.22
341.1989746	0.59
351.0736084	0.12
353.1763916	0.67
357.0674438	80.07
357.6864624	0.41
360.1932068	0.05
361.2836914	0.06
365.2660828	0.24
367.2072449	0.14
369.1044617	2.07
371.181366	2.04
381.2963562	0.18
387.2023621	4.06
393.1057434	0.38
399.0611267	1.00
400.1259766	0.09
401.4700623	0.12
403.1834717	0.65
411.1568298	3.67
417.1516418	0.15
419.2173462	0.14
425.3574524	0.14
429.0936279	22.95
429.940033	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
118.3486557	0.14
118.9642639	0.82
125.0094833	0.25
130.9764557	0.79
135.0095825	1.17
142.8665161	1.50
149.0745544	0.23
160.3694763	0.18
160.9996948	2.58
164.0727997	0.14
179.0086060	25.85
193.2206116	0.17
197.1234131	0.44
204.9751587	0.25
223.0258179	100.00
240.9935608	1.47
249.2823486	0.09
264.7774048	0.04
271.2689819	0.07
283.0865479	0.33
304.3339233	0.05
313.4071350	0.15
315.3125000	0.05
343.4700012	0.20
355.3129272	0.12
357.0296021	0.17
359.1918030	2.75
373.3204956	0.22
375.2190552	0.05
384.9116516	0.58
403.0298157	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	830.2626
Annotation	Aromatized deshydroxy-C-1027 chromophore
Peak:m/z	Relative Intensity
232.0374451	0.42
235.8306580	0.08
238.0489655	0.08
242.9585571	0.15
243.9491730	0.08
248.2991180	0.04
249.2514038	0.22
250.0086975	0.99
250.9169922	0.10
251.9441528	0.49
256.1317749	0.26
259.9154663	0.09
261.1388855	0.17
262.1502075	0.22
262.9879150	0.09
264.1796875	0.04
264.9953003	0.01
265.9778137	0.08
267.8831482	0.10
271.9895020	0.05
276.2190552	0.03
276.9953613	0.08
278.0646057	0.08
279.0325317	0.65
279.9673462	5.95
281.0737305	0.44
281.9223633	0.84
289.1436768	0.04
294.0775146	0.10
301.9668274	0.03
302.9427795	0.03
306.0980835	0.18
308.0576477	0.24
310.0762329	0.60
321.1302490	0.07
322.0192261	0.65
323.3836365	0.06
324.0551453	0.10
326.9915161	0.06
334.4778137	0.08
335.9060669	0.46
337.3956909	0.03
338.1427307	0.12
340.0659180	3.54
351.8487549	1.85
353.0817871	0.61
358.0276489	0.14
362.1107178	0.09
364.1015625	0.16
365.1204834	0.05
368.0567627	0.15
368.7641296	0.03
375.2159424	0.05
376.0175781	0.26
378.1240234	0.20
380.1651001	0.18
381.9657593	2.56
383.0848694	0.75
392.1041260	0.05
394.1974487	0.27
398.0979614	0.06
405.9963379	0.18
411.9066162	3.41
412.6213379	0.11
417.4998779	0.03
422.4783936	0.13
424.0987549	1.00
427.0537720	0.02
439.9926758	1.37
441.9761353	100.00
443.0610352	2.12
444.1441040	0.98
459.1630249	0.05
475.0168457	0.06
476.1964111	0.30
484.4266357	0.12
487.8995361	0.04
502.0195312	0.56
504.4733887	0.27
506.0609131	8.88
506.6875000	0.09
507.7745972	0.06
542.7019043	0.06
544.0490112	0.05
548.0222168	0.08
568.0264893	0.03
571.9983521	0.03
580.4741821	0.05
584.1769409	0.08
601.7115479	0.04
603.4642334	5.24
604.1087036	19.62
629.3455811	0.05
638.1682129	0.03
639.7958984	0.08
642.4805908	0.02
648.5432739	0.03
649.9319458	0.82
654.3736572	0.03
666.1885986	0.16
667.3457031	2.70
667.9999390	21.35
669.0474854	0.77
670.0225220	0.24
682.3049927	0.07
740.2949829	0.08
770.0175781	0.15
771.1106567	1.75
781.7705078	0.01
785.4373169	0.04
793.3033447	0.11
812.1791382	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
179.222702	0.07
269.1398315	0.17
283.2174683	0.53
292.9923096	0.12
308.9558716	0.03
311.0481567	100.00
312.0762024	0.35
318.9542847	0.06
322.9258118	0.07
336.965271	0.08
341.1467896	5.28
353.0841675	0.29
355.1072998	0.07
367.1534119	0.02
370.9886169	0.06
377.1822205	0.16
383.1123962	0.21
395.1654358	0.42
412.9690857	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1769
Annotation	Lactucaside
Peak:m/z	Relative Intensity
164.9931030	2.83
173.0078583	0.03
176.8565369	0.11
177.9944153	2.47
180.9705048	0.10
192.9637451	55.04
195.0149689	8.94
207.2607574	0.23
217.0649719	0.31
235.0532990	0.63
265.1636963	0.11
269.2803345	0.20
270.2481079	0.13
285.2385864	0.52
320.5037842	0.28
327.3901367	0.04
329.6313477	0.10
341.0783081	6.23
345.3098145	0.39
354.3140869	0.06
355.2001953	0.51
371.3000488	0.27
382.5896606	0.04
385.0283813	0.07
389.0236206	100.00
389.7061157	0.35
397.3714600	0.13
409.0920410	0.18
413.1882324	0.50
427.0908203	0.09
430.1235352	0.18
431.2746582	1.61
442.0006714	0.09
442.9545288	0.15
443.6340942	0.17
450.0860596	0.25
451.4177856	0.20
466.4095459	0.25
471.7284546	0.37
489.0297241	0.07
490.8789673	0.69
502.9735718	0.66
504.1196899	2.11
505.0457153	3.11
506.2534790	0.32
507.1101074	0.07
514.7041626	0.42
533.1415405	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	694.96
Annotation	Unknow
Peak:m/z	Relative Intensity
255.1620178	0.04
261.1407471	0.04
267.1733398	0.15
277.2247314	2.76
278.3269958	1.88
279.2324524	9.47
280.3212280	1.61
281.2147827	0.16
306.5233154	0.12
308.8933411	0.07
314.0657349	0.09
326.0669556	0.04
339.6392822	0.04
345.4019165	0.05
351.0428467	0.10
354.2885132	0.03
355.3419189	0.04
358.1701050	0.12
363.2355347	0.06
365.3777466	0.28
377.1463623	0.04
381.5562744	0.03
395.9656372	0.13
397.6809692	0.18
413.2792969	1.54
414.1918335	2.24
415.1733398	7.59
416.2380371	3.23
417.3843384	0.37
418.6287842	0.17
424.0476685	0.31
431.1848145	0.42
432.1868896	0.13
433.2479248	2.64
434.2366333	0.94
435.4479980	0.11
437.6683960	0.12
438.9608154	0.19
452.4044189	0.06
453.5585938	0.10
455.2389526	0.14
462.7540894	0.14
499.6808472	0.11
517.1907349	0.28
520.4784546	0.07
525.4447021	0.15
534.3830566	0.19
540.1583252	0.38
541.8505859	0.07
550.8983765	0.14
566.4882202	0.09
576.4264526	0.16
578.4302368	0.06
579.9551392	0.23
581.5499268	0.06
586.6500854	0.12
589.8583984	0.05
601.6093750	0.05
602.2608032	0.16
609.3006592	0.15
614.7120972	0.19
615.3459473	0.10
631.0520630	100.00
632.7017212	0.14
634.0305786	0.14
634.6325073	0.84
635.5706177	0.09
636.6967163	0.28
648.3899536	0.35
650.5531616	0.64
651.4110718	0.12
657.0613403	0.33
658.7743530	0.21
660.8302002	0.06
665.4255371	0.03
667.3978271	0.28
674.9198608	0.51
676.6847534	0.91
677.6470337	1.32
694.8826294	0.41
695.7226562	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	522.2823
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
146.8893433	0.15
149.0754852	0.10
152.0356140	0.03
154.9100647	1.13
159.0696411	0.13
165.1067047	0.12
167.1164703	0.13
171.0367737	0.04
172.6561432	0.16
177.3254089	0.02
179.2874756	0.13
182.9321289	0.02
184.2482300	0.14
185.1379089	0.17
189.1249084	0.08
193.2645416	0.10
195.0463562	0.04
201.2006073	0.03
203.3814392	0.03
208.9543915	0.08
216.9619141	0.07
223.2109680	0.02
242.2199097	0.20
244.1576538	0.15
245.1205444	2.99
253.0008392	0.10
259.8701782	0.42
261.2236938	0.13
263.1929932	7.58
269.9002686	0.11
275.0780029	0.11
277.1749268	0.10
283.4633179	0.12
292.2321777	0.08
293.2599487	0.08
309.1846313	0.04
312.1991577	0.09
319.2993774	0.22
321.1463013	0.17
322.0125122	0.08
335.2023315	0.36
337.2332153	31.07
337.8439331	0.17
342.5510864	0.06
347.2247925	0.14
350.3091431	1.49
353.0395508	0.06
363.5852051	0.08
382.3411865	0.04
395.1899414	0.03
406.3604126	0.07
417.1055298	7.37
424.3822632	1.05
435.0845947	0.08
436.2265625	0.03
437.1101685	0.21
445.0040283	0.02
448.0617676	0.29
450.7811890	0.19
454.1873169	0.13
455.3679810	0.06
458.4929199	0.19
463.1591797	0.03
464.5584717	0.02
473.4402466	0.15
475.3128662	0.03
477.1723633	0.02
478.1376343	0.05
487.2879639	0.05
491.2767334	0.13
496.2165527	0.02
504.1600952	100.00
504.8419800	0.28
512.3777466	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
66.8504791	0.05
84.9013977	0.06
86.8898392	0.71
87.5111694	0.01
100.9576721	0.01
110.9490356	100.00
111.8071289	0.03
128.9215698	2.04
130.9114380	1.09
142.9969025	0.01
146.9286346	0.23
154.9745636	0.13
157.3247681	0.04
159.0067291	0.04
161.0460205	0.03
164.1772919	0.02
171.4714813	0.08
172.9684906	21.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1224
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
162.8123779	0.08
195.0974579	0.02
222.9094238	0.03
261.0453796	0.01
265.2474976	0.02
271.0895386	0.41
283.0059204	0.10
289.2066345	0.38
295.1563721	0.42
297.1324768	0.27
311.3227539	0.02
313.1654358	2.03
315.0513611	0.13
331.0940247	2.45
337.1053162	0.99
341.9938965	0.03
355.0751953	0.42
367.1643066	0.43
378.9906921	0.12
384.2507629	0.06
385.0797119	0.02
393.9295959	0.01
397.0413513	2.53
398.0117798	0.01
407.0713806	0.02
415.1274109	16.30
415.7674255	0.06
433.0895691	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.3383
Annotation	Unknow
Peak:m/z	Relative Intensity
225.1990356	0.07
244.3102875	0.04
249.1259766	0.03
280.3083496	0.06
282.2427368	0.04
319.0710449	0.04
326.7360229	0.03
328.1701050	0.06
332.6964722	0.07
369.1185303	0.25
370.2876587	0.32
373.5558472	0.11
387.1895752	100.00
388.2012939	12.61
388.9244385	0.01
415.3986816	0.03
441.2937622	0.19
443.2087402	0.07
479.0946655	0.04
530.9709473	0.02
578.8252563	0.12
587.2837524	0.15
595.6028442	0.07
656.1779175	0.05
667.1343384	0.02
674.7025146	0.04
684.9520874	0.06
711.7643433	0.03
731.2435303	0.07
739.1453857	0.04
745.4641724	0.03
758.2783813	0.16
766.4453125	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1039.67
Annotation	Unknow
Peak:m/z	Relative Intensity
308.1281433	0.30
337.4723511	0.11
338.4121094	0.16
349.1050720	0.05
361.2725525	0.05
367.1232300	0.06
443.3078613	0.47
502.3572693	35.00
503.4374695	8.24
520.2509766	100.00
521.2013550	21.49
521.8445435	0.17
534.2243652	5.30
535.2360840	1.64
604.9319458	0.45
605.5382080	0.10
606.2740479	0.12
620.5543213	0.13
623.1221313	0.19
624.3554688	0.13
644.1538086	0.71
645.3391113	0.05
685.4063721	0.21
703.2844238	13.75
704.3771973	4.12
856.2736816	0.07
857.1367188	0.21
980.3596191	3.02
981.4194336	0.66
1021.3879390	0.22
1022.3601070	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.056
Annotation	Wairol
Peak:m/z	Relative Intensity
117.0363312	0.10
119.1590042	0.02
134.9547424	0.10
143.1333313	0.01
145.1787720	0.03
147.0797729	0.15
148.9530945	0.05
161.0326233	0.13
162.9821014	0.03
163.9894104	0.03
173.1518860	0.09
183.0839233	0.03
185.2924652	0.05
188.9620056	0.03
191.0367279	0.30
193.1628571	0.06
196.1647797	0.01
197.1480713	0.02
198.9025879	0.02
201.1375427	0.12
203.0140381	0.14
216.9346619	0.09
223.2287598	0.06
225.1945496	0.06
227.1170654	0.14
233.3376465	0.02
237.1938171	0.05
237.9457703	0.01
239.1043091	0.51
240.0150146	0.01
240.9780579	0.05
243.1337280	0.32
251.1322632	0.03
252.1216431	0.03
253.3748779	0.01
254.0538940	0.02
255.4003601	0.02
263.8817749	0.02
265.0715332	0.13
267.0650024	0.45
268.0633545	0.69
269.2989502	0.12
270.0681458	0.01
281.1255188	0.79
283.0567017	100.00
284.0721436	5.51
293.1455688	0.98
294.0981750	0.03
295.0914917	0.02
309.2378540	0.19
311.2515259	0.31
312.0492249	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1087.4786
Annotation	Unknow
Peak:m/z	Relative Intensity
323.1314392	0.35
341.0275269	1.33
365.2434692	0.28
366.7605286	0.09
378.9566040	0.19
379.6243896	0.11
383.2401733	2.07
394.4919434	0.04
397.0947266	0.07
406.7349548	0.19
412.3896484	0.10
424.6947021	0.28
442.8864136	2.65
448.9945068	0.99
466.8938293	0.35
480.9414062	0.10
483.3049927	0.14
484.9659424	1.74
491.1967773	0.04
502.9425049	1.79
503.5437317	0.78
527.2615967	3.79
539.2115479	0.18
540.1756592	0.30
545.1921387	7.39
551.2362061	0.07
557.3137207	0.16
559.1597900	1.26
569.2470703	0.57
582.9411621	0.06
583.5703125	0.11
587.0291748	2.38
587.7562256	0.08
593.1474609	0.03
601.0344238	0.30
604.9600830	0.53
611.3355713	0.71
629.2385864	1.39
643.0692139	0.78
645.0551758	0.13
646.6777954	0.38
647.3093872	1.69
665.2270508	0.14
689.2644043	0.54
691.2615967	0.14
702.7987061	0.54
742.3264160	0.11
745.1853638	0.22
749.4368286	0.25
779.9905396	0.07
790.9443970	0.34
805.0936279	4.92
809.2011719	100.00
809.8852539	0.33
827.2808838	30.77
847.3515625	0.05
871.4169922	0.10
907.3179932	0.55
925.7901611	0.07
941.7048340	0.16
944.5090332	0.12
953.1179199	0.13
955.8710938	0.04
968.1953125	0.08
969.5522461	0.35
980.6812744	0.16
1008.8022460	0.12
1023.7680660	0.05
1024.8756100	0.11
1037.6555180	0.37
1053.5510250	0.06
1054.2443850	0.06
1054.9936520	0.06
1068.5965580	0.54
1069.5705570	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1023.4448
Annotation	Unknow
Peak:m/z	Relative Intensity
391.1434937	0.03
407.4825439	0.07
409.2369690	0.12
426.2247314	0.01
436.2137451	0.03
469.1061096	0.14
470.5770264	0.05
483.0132141	0.20
487.3651123	0.18
488.5747070	0.09
491.3923645	0.08
493.4392090	0.07
507.2922668	0.21
511.3485413	0.50
512.2197876	0.04
520.6315918	0.04
523.3618774	0.05
537.3569336	0.10
538.2648315	0.15
549.6197510	0.14
553.5690918	0.03
557.8525391	0.02
567.3883057	4.65
568.4523926	2.42
569.4541016	0.30
583.3672485	0.68
584.4367676	0.24
585.4125977	0.18
596.4318848	0.23
597.7274170	0.02
598.3377686	0.06
599.8090820	0.13
601.4196777	6.55
602.5228271	3.19
603.5254517	0.81
615.2557373	0.61
616.3599854	0.07
619.4154663	3.49
620.5284424	1.14
621.7036133	0.25
623.4367676	0.14
625.4820557	0.03
633.1774902	0.12
643.5998535	0.34
644.4181519	0.14
649.3707275	0.08
650.4090576	0.03
657.6556396	0.06
661.6141968	0.14
663.1889648	0.12
667.4089355	0.30
668.5173340	0.07
671.5081787	0.10
673.4281006	0.06
683.6288452	0.02
699.4119873	4.52
700.3466187	1.74
701.3323975	0.42
713.5708008	0.24
718.5133667	0.08
736.6863403	0.04
745.4154663	1.15
746.4063110	0.33
747.0350342	0.07
747.7172852	0.03
748.4645386	0.06
763.4602661	10.38
764.4909668	5.93
765.5621338	0.97
777.5015869	0.03
778.7384644	0.02
781.5151978	5.81
782.6435547	2.88
783.7399902	0.53
796.0961914	0.19
800.2368164	0.09
805.4367676	0.03
806.2574463	0.31
807.6807861	0.03
818.6539307	0.04
823.5479736	0.14
824.6408691	0.13
829.4112549	0.23
830.3510742	0.25
835.2208252	0.03
845.4282227	0.60
846.4294434	0.13
847.3781738	0.06
853.0361328	0.04
859.6091309	0.11
861.4442139	14.59
862.4562988	7.52
863.5269775	2.34
868.3211670	0.09
895.5703125	0.16
903.4481201	0.23
904.4880371	0.06
907.5346680	0.46
908.5228271	0.55
909.6875000	0.02
913.2207031	0.03
925.5174561	100.00
926.4768066	65.79
927.4683838	10.83
928.1715088	0.04
934.4227295	0.08
938.6732178	0.09
941.8551025	0.16
943.4884033	62.01
944.4884033	44.07
945.6024170	5.84
950.4197998	0.13
963.6962891	0.37
964.6585693	0.08
979.5800781	1.99
980.4257812	0.87
981.7409668	0.03
993.3225098	1.47
994.5181885	1.18
995.6060791	0.08
1005.4700930	0.56
1006.5805660	0.18
1007.2602540	0.11
1023.6308590	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.2423
Annotation	Sorbitan laurate
Peak:m/z	Relative Intensity
108.9967194	0.51
110.9796219	0.06
113.1012039	0.05
114.8443069	0.10
116.7593994	0.08
118.9564209	0.17
121.1354675	0.34
122.9652481	0.23
126.9195557	0.06
129.0397644	0.17
130.9656677	0.13
132.8978271	0.08
134.7629395	0.22
137.1566010	0.24
138.8059082	0.33
141.1859283	0.03
142.8755188	0.09
145.0890503	0.14
148.9673767	0.33
151.2320251	0.16
153.0487061	0.30
154.8773193	0.11
156.8735962	0.13
159.3491211	0.37
161.1681824	0.17
163.1027527	0.40
165.2009277	0.14
166.2146912	0.07
167.0607300	0.18
170.9191742	2.14
173.0732574	0.06
176.9653320	0.18
179.2430573	0.06
183.0572968	0.34
185.0189209	13.95
187.1044922	0.63
189.2674255	0.39
191.1045990	0.08
193.4401550	0.14
195.0617981	0.14
196.1037903	0.03
196.9130402	0.06
198.8484192	0.11
199.9228668	0.14
201.1263733	1.64
202.7554932	0.61
205.0826721	1.00
207.1156616	0.18
209.1790466	0.08
211.0709076	1.01
213.0794373	0.08
217.1921997	0.30
218.5508423	0.41
219.1725464	2.15
221.3131104	0.14
223.1437378	3.98
225.1097717	0.92
226.7848816	0.81
229.0212402	0.23
230.6628113	0.04
233.0837402	0.08
233.9570923	0.02
235.1914978	0.58
237.0524292	0.60
239.0213928	0.93
241.2416992	0.34
243.0745544	0.28
245.3165283	0.03
247.1842346	0.38
249.3725281	0.03
251.2747498	0.03
251.9530029	0.03
253.2506714	0.97
256.1742249	0.06
257.2458496	2.72
258.1590881	0.15
259.0931091	0.18
261.2775269	0.13
265.2315979	0.94
267.2855530	0.10
268.7514343	0.04
269.4104004	0.31
271.2734680	0.05
275.2127686	32.09
275.9593506	0.04
276.8079834	0.04
283.0584412	0.17
293.1263428	100.00
294.0381165	0.36
299.3243408	0.03
301.1960449	2.95
304.1383362	0.06
306.1423035	0.03
311.1704712	91.94
317.3765869	0.06
319.1236572	0.26
324.9660339	0.07
328.6091309	1.83
329.2094727	19.78
329.9210815	0.14
337.9124756	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.15
Annotation	Unknow
Peak:m/z	Relative Intensity
123.3226318	0.71
126.9028015	4.36
144.8773499	2.51
162.7526550	2.19
179.9424896	4.84
183.1175842	0.56
198.1012268	6.20
246.8598938	0.25
249.5238342	1.26
255.1535645	0.47
258.9048462	3.81
270.8237305	1.19
274.6364136	0.70
276.3128052	0.60
277.0655518	2.86
288.8396301	7.12
306.3355713	5.46
306.9957886	12.82
318.8775024	0.60
320.8697510	0.60
321.8606262	1.05
323.0192261	1.06
324.1041565	12.38
324.7628174	100.00
325.4487000	0.80
336.1488037	0.66
342.2355957	24.81
342.9167175	73.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.3267
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8786926	0.10
131.9687958	0.58
136.7833099	0.08
141.9364014	0.62
143.0119324	0.35
144.0372467	1.36
144.8767395	0.10
146.0398407	6.85
147.1023865	0.09
150.9743042	0.19
154.2000275	0.18
156.0942383	0.12
158.3388062	0.86
159.0260162	4.33
160.0053101	0.08
160.9780731	0.52
163.1484222	0.28
166.0958557	0.12
166.8708954	0.15
167.9068909	0.17
169.2039032	0.12
170.0101166	2.13
175.1212769	0.62
177.1035767	0.09
178.7862549	0.33
181.0344543	0.05
182.0502930	0.38
184.1110840	0.59
185.9528198	0.08
187.1057129	1.41
188.0720215	38.58
193.8766174	0.37
196.0090332	0.38
198.1190186	0.15
200.2435608	0.32
202.0516968	0.13
203.0436096	0.38
205.0112457	48.77
207.0322876	0.15
210.0724182	0.51
212.2140198	0.34
212.9876709	0.12
214.1760864	0.41
216.0656738	0.03
217.2182770	0.04
219.9334717	0.08
221.6702271	0.05
224.1362152	0.28
226.1682739	0.60
228.0727539	0.10
229.1803894	0.10
231.1236267	0.27
233.7387085	0.32
236.4416199	0.42
238.1493378	0.44
239.0733032	0.14
240.2308960	0.29
241.0405426	0.10
242.3560791	0.33
243.1423645	0.77
245.1598511	1.19
248.3078613	0.12
250.1872559	0.62
251.1818848	0.10
252.1195984	0.15
254.0239868	0.55
255.2417603	0.07
256.2348633	0.26
259.3847656	0.04
261.0802307	0.12
263.1215820	0.86
264.9101868	0.12
266.2478027	0.37
267.3107910	0.07
268.3258362	1.02
268.9931030	0.25
270.3539124	0.19
270.9689636	0.09
273.1883240	0.05
277.1206970	0.16
278.8272095	0.20
280.2887268	1.67
281.1257324	0.09
282.2453613	0.39
283.3881836	0.12
285.3479004	0.04
287.3292236	0.23
290.3240051	1.35
292.3406982	0.59
294.2017822	0.47
296.2614136	0.48
297.0674133	0.13
298.5345764	0.32
301.1564941	0.28
304.1733093	0.92
306.1708374	0.24
307.2275391	0.06
308.3213806	0.32
309.4459839	0.23
311.2990723	0.16
313.0316467	0.09
314.2269287	0.51
315.1500244	0.29
316.7070923	0.24
320.1127319	0.35
322.2182617	0.23
323.1010132	0.10
325.2800293	0.25
326.4400024	0.15
327.2634888	0.18
329.1806030	0.24
332.3720703	0.12
335.2295227	0.04
336.7731323	0.50
337.4541931	0.34
338.4580078	0.24
341.2134705	1.57
343.1845703	0.12
350.2265320	1.60
351.2445068	0.78
355.2282104	1.86
357.3624268	0.07
359.2587585	0.12
362.4793701	0.13
364.3751221	4.27
365.1911926	0.61
366.2443542	0.69
367.3718262	0.29
369.1537476	3.59
371.4354553	0.15
374.4169006	1.07
376.4431152	0.18
378.4463806	0.07
379.0574341	0.11
380.2964172	3.87
383.3046570	4.57
384.4168091	0.26
385.3973389	0.06
386.5525208	0.07
390.1899414	0.23
392.3265076	35.39
393.3805847	1.70
394.5092163	1.07
396.4004211	1.95
397.1963501	1.08
403.1898804	0.77
404.3580627	24.15
405.7011414	0.37
406.4443359	0.89
407.3188782	0.70
409.9243774	0.11
410.5316772	1.36
411.2672424	0.43
413.3563538	0.74
414.2865601	0.16
415.3280029	0.06
421.3392334	100.00
422.4125671	9.82
423.4025574	24.03
425.5790710	0.22
426.2876892	0.53
430.3934937	0.16
431.8341064	6.68
432.4416504	6.22
433.4144592	0.58
434.4090576	0.11
435.3930359	0.14
437.2263489	0.05
439.4069214	31.31
449.2734375	80.40
450.3125305	5.93
451.6558533	0.06
467.6432800	0.15
476.1118469	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	566.0206
Annotation	Unknow
Peak:m/z	Relative Intensity
165.7909546	0.05
172.0157013	0.07
183.7368774	1.60
184.3719635	0.04
185.7892761	0.05
191.0426941	0.17
196.0516052	0.10
197.9859009	0.68
199.9219055	0.05
210.2580414	0.07
211.9426270	0.09
213.7147522	0.27
215.8773804	0.05
218.0755157	0.08
223.9919434	0.76
225.8945618	0.45
227.0602722	2.32
227.8773804	44.77
234.0236969	0.23
238.0671692	0.10
239.9597015	1.04
242.0918274	0.04
243.2019653	0.05
243.9218445	0.10
245.5267944	0.07
251.9575806	0.21
253.9492645	2.41
254.7690277	0.03
257.7269897	0.15
258.3562012	0.17
261.8052979	0.32
267.9870605	0.48
269.9653931	22.53
270.7063904	0.22
271.9733582	0.46
276.0771484	0.10
283.8674316	0.43
285.6182251	0.44
286.8887329	0.03
288.0051880	0.03
296.0040283	2.15
297.6752930	1.32
298.2770996	0.15
301.8880005	0.05
303.3595581	0.06
304.0753784	0.45
311.8659668	1.01
312.8635254	0.30
313.9536133	15.97
315.8687744	1.09
316.7936401	0.09
318.1147461	0.20
320.9835815	0.05
323.2822876	0.05
326.1977539	0.07
327.9969482	1.08
329.9138184	100.00
331.7863770	0.10
340.0740967	0.79
341.7827759	0.33
345.9655151	0.17
356.1361084	0.05
357.8769531	6.70
358.9808350	0.10
359.9003906	1.15
373.9572754	3.47
375.8621826	3.92
388.6817627	0.42
398.0506592	0.83
402.1441650	0.20
405.9036255	0.06
408.0510254	0.23
416.0379028	0.96
417.0249023	0.14
417.8041382	0.05
418.5899658	0.07
420.9651489	0.11
424.1605835	0.21
425.9937134	0.05
431.1668091	0.07
432.2354736	0.53
432.9395142	0.29
434.0585938	0.15
435.8241577	4.56
436.9880981	0.52
441.9000244	0.90
442.8780518	0.16
444.1043701	0.04
447.9309082	0.33
448.9218750	0.22
450.0679932	0.79
457.5437012	0.09
459.1925049	0.08
461.9966431	35.64
467.0419312	0.05
469.9013672	0.62
470.9959717	0.10
475.0023193	0.19
476.0145264	1.96
477.8250122	3.04
503.1154785	0.19
504.1205444	1.04
505.7946777	0.24
507.1265259	0.13
519.5520020	0.17
521.4098511	0.91
522.0800171	1.62
522.6823730	0.15
527.9402466	0.16
528.9580078	0.08
529.5907593	0.05
538.9494019	0.14
542.7931519	0.06
547.4583130	2.13
548.1108398	7.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	558.1614
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0026245	0.17
180.9299011	0.06
213.9722900	0.03
217.0470734	0.03
220.1281433	0.02
232.2040405	0.05
234.0821381	0.04
242.9523468	0.05
244.1258698	0.05
245.1115112	0.03
246.0895691	0.04
251.8914032	0.03
258.1235962	0.05
262.3892212	0.02
269.0757446	0.13
272.0001831	0.12
273.0615234	0.04
273.8259277	0.03
277.2863770	0.02
282.5564575	0.02
283.1892700	0.09
287.1007080	0.03
298.3723145	0.05
306.2199097	0.11
311.1507568	2.69
312.4047852	0.03
321.2984009	0.04
334.4352417	0.05
335.2860107	0.03
337.0805054	0.08
338.3999634	0.11
341.1187134	0.18
347.4599609	0.06
349.1755981	0.42
350.1842651	0.11
351.0253296	0.31
352.2658081	0.05
355.1593628	0.02
357.8419189	0.13
361.4476318	0.07
364.4498901	0.05
365.3697510	0.11
366.2204590	0.16
375.2046509	0.09
376.3865356	1.11
377.1803589	3.95
378.1832275	0.37
381.1822510	0.03
387.9863892	0.07
389.3410034	0.02
391.2522583	0.66
392.2548828	0.12
394.1670532	24.49
395.2745972	1.00
396.2258911	0.09
406.3047485	0.24
407.1772461	0.36
408.2125244	0.03
415.2573853	0.05
418.5118408	0.05
419.2574463	0.16
420.3073730	0.40
421.1737061	1.05
422.2705078	0.02
424.2026978	2.17
425.1232300	0.18
427.1237793	0.04
431.2372437	3.86
432.1213989	0.11
436.1549683	0.23
438.1246338	100.00
439.2437134	2.14
443.0263062	0.06
448.1789551	0.04
450.2386475	0.38
451.2066040	0.09
451.8698730	0.16
454.3563843	0.02
457.0953369	0.15
459.4365234	0.11
460.4122925	0.02
464.1396484	0.15
466.3439331	0.09
468.1331787	10.49
469.1868896	0.27
470.8255005	0.06
478.3493042	0.06
480.1544800	0.39
480.7826538	0.03
482.4002075	0.07
493.2290649	0.09
495.3337402	0.07
496.0537720	0.04
497.1427612	1.08
498.3063354	0.65
502.0608521	0.04
504.2442627	0.24
510.3458862	0.20
511.3802490	0.52
512.4033813	0.17
513.1976318	0.83
514.1986694	10.48
515.2048950	0.30
520.0307617	0.04
520.8143921	0.13
522.1408081	0.34
539.0681763	0.34
540.1819458	0.67
541.1618652	1.90
542.2351685	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.308
Annotation	PC(14:0/0:0)
Peak:m/z	Relative Intensity
158.9445801	0.14
166.1132812	0.23
181.1216736	0.35
184.0032501	37.94
190.7373047	0.13
191.3723450	0.18
229.1724854	0.24
232.0893860	0.08
233.0615997	0.25
235.9477692	0.16
238.3322296	0.17
240.0960388	0.45
258.1322632	0.21
278.8734131	0.65
282.1847839	0.32
287.7102661	0.59
333.1333923	0.42
335.4644775	0.26
383.5559998	0.06
391.3645935	0.19
393.8771362	0.39
401.1461182	0.10
412.4059753	0.46
417.3305969	0.15
419.0528259	0.07
422.2991028	0.86
425.3603210	0.18
432.6802673	0.28
435.1940002	0.24
440.1508484	0.18
448.3178711	0.13
450.3057556	100.00
451.3046570	0.85
458.8945618	0.47
467.4201965	0.16
468.2746887	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
224.0255737	0.05
279.2233887	0.25
391.0957031	0.04
392.4418335	0.01
415.1377563	0.11
433.2434082	0.03
459.3657837	0.06
504.2955322	100.00
505.3426514	0.19
518.1262207	0.06
544.2802124	0.03
546.5701294	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3389
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0546417	0.12
183.9697266	29.22
195.7121277	0.03
199.1545105	0.03
240.0093384	0.21
258.0692139	0.31
337.4041138	0.20
443.3090210	0.43
502.3738403	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.2734
Annotation	2-oxo-nonadecanoic acid
Peak:m/z	Relative Intensity
89.0679321	0.38
90.9362640	2.96
92.9748383	7.17
94.8944321	100.00
97.0004425	31.80
99.0768738	2.97
101.0357971	1.40
103.0200958	10.32
105.2891312	0.95
107.0118256	3.00
108.9155884	81.22
110.9427109	14.87
112.9592285	1.58
115.1692352	0.82
116.9476166	12.03
119.1051788	0.32
120.9650574	11.98
123.0367203	41.56
124.9427643	12.50
125.6950378	1.27
127.0708542	1.44
134.9880981	11.23
137.0393677	33.42
138.9127197	6.34
141.3782654	0.26
144.8904724	6.45
147.1743317	1.54
149.0033264	4.23
151.0208740	9.78
153.1136017	2.13
155.0244446	0.48
155.8217163	0.57
157.1936035	0.84
158.4704590	1.19
159.0985413	4.12
161.0232391	2.55
163.0208130	5.40
165.0982361	16.10
167.1433258	0.43
168.9768066	1.00
173.0511169	5.99
177.1885834	3.98
179.2394409	1.15
181.0416870	0.38
183.0987244	1.37
187.0742798	4.26
191.3124695	1.72
197.9734344	0.96
199.2500763	1.68
201.3825989	3.24
210.9774780	0.86
215.3514099	1.12
219.3340759	8.53
221.1040039	9.59
233.0868225	2.03
235.2902222	0.40
237.1523438	5.74
239.0964355	33.18
254.2007751	0.62
257.1634216	56.65
257.7698975	0.69
266.9063416	0.80
269.3554077	0.63
272.0902100	3.96
273.8724060	0.95
274.6692810	0.47
277.4736328	1.14
278.2521973	0.35
284.0750732	1.69
285.2731323	2.10
293.1022034	0.59
295.1442566	7.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	338.1972
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0317535	0.12
123.0479355	0.12
125.9542770	0.07
128.0650024	2.44
129.9664154	100.00
130.9110718	0.18
134.9457092	0.07
138.0988770	0.10
146.7646179	0.09
148.0704956	0.19
154.1202393	0.08
155.9404602	0.05
163.0419006	0.14
164.7086792	0.18
171.9917145	23.17
181.1503296	0.71
181.8865204	0.12
189.1749268	0.30
192.9133911	0.09
201.1015472	0.10
204.9467468	0.09
206.9832153	1.46
210.8697205	0.15
215.1427612	0.16
243.1898804	0.10
246.2058716	0.18
266.2658081	0.14
276.2824097	0.36
277.1307983	0.19
289.2554321	0.19
292.0397034	0.56
294.1057129	0.75
295.1304626	0.26
300.1261597	0.14
309.9784851	0.49
311.2587891	0.23
318.5473022	0.41
319.4638672	0.84
320.2405090	4.34
321.0804443	0.46
323.1121216	0.09
324.0055542	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	993.5939
Annotation	Unknow
Peak:m/z	Relative Intensity
279.2085571	5.93
279.8144226	0.10
280.4231262	0.07
333.3890686	0.05
415.3249512	0.07
476.2414551	100.00
477.2457275	1.65
502.1875000	0.06
577.0006104	0.04
686.8880615	0.07
689.5594482	0.02
758.3515625	0.02
933.0026855	0.07
949.7698975	0.06
976.4998779	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.23
Annotation	Unknow
Peak:m/z	Relative Intensity
107.1340332	0.12
109.9992142	0.14
113.8618622	0.07
115.9251709	0.06
120.8653717	0.24
121.9869537	0.03
123.2720184	0.03
128.9714966	0.05
131.0374451	0.06
132.6864319	0.17
134.7910156	0.12
135.7111969	0.08
150.9860535	0.31
155.9326477	0.06
163.1302490	0.06
164.7387695	0.02
175.3705292	0.04
176.9629517	0.03
181.1659393	0.02
188.2696228	0.04
193.1712646	0.39
194.1624146	0.05
204.1458435	0.02
209.2495728	0.06
210.3264465	0.03
211.0532227	0.03
211.9028931	0.04
214.3115234	0.07
224.9089050	0.04
229.6320496	0.11
232.1557007	0.24
242.1196289	0.11
243.0954895	0.11
244.1609802	0.06
248.0162048	0.09
250.2089539	0.13
254.2000427	0.72
257.3449707	0.09
264.7026978	0.07
266.0882568	0.08
270.8104858	0.11
273.0904541	0.09
277.8420410	0.07
278.9820862	0.03
281.7885742	0.04
283.2480164	0.17
286.3753967	0.05
289.3983459	0.07
293.0765076	0.40
294.1890259	0.06
296.1907349	0.58
297.2254639	0.17
300.1204834	0.03
300.8504028	0.40
306.1844482	1.05
307.0580444	0.31
307.8711853	0.14
310.2844849	0.10
311.9300232	0.31
313.4700928	0.14
314.7172241	0.19
315.3676758	0.09
318.7527466	0.27
320.9130249	0.14
324.1898499	100.00
325.2142944	0.59
326.5648499	0.16
327.3443604	0.17
332.3555603	0.12
333.2227478	0.06
342.0172424	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1294
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
136.1313019	0.03
150.9911957	0.04
151.8745575	0.17
152.9605560	0.71
154.1258240	0.05
155.0955811	0.03
165.0596771	0.06
167.0595398	0.31
177.8947754	0.05
189.1576233	0.04
192.5140076	0.02
208.8379211	0.02
210.0975647	0.01
216.8008270	0.02
221.1357117	0.03
227.0498047	0.04
230.0505219	0.04
231.0795288	0.01
271.8840942	0.08
272.9299011	0.29
281.1006470	0.40
287.0967102	0.11
297.1757202	0.06
297.9067993	0.03
311.1900024	0.07
312.0795898	0.50
313.1797180	0.45
315.0687256	100.00
316.0656738	0.02
327.2004395	0.42
329.2458801	0.02
331.2864990	0.02
341.2583618	0.03
342.2473450	0.10
343.2426147	0.03
345.0763550	13.22
345.6833801	0.11
348.9500427	0.04
353.3085938	0.04
357.0233154	0.55
358.2819214	0.05
375.1724854	0.18
380.8844604	0.12
386.4000854	0.10
387.2591553	0.18
391.1989136	0.30
392.4810791	0.07
399.0869141	0.39
416.0722351	0.32
417.1695251	3.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
143.1473541	0.02
149.1038513	0.04
150.7093353	0.02
160.7858429	0.02
162.2128143	0.03
180.2340088	0.04
251.2062378	0.07
267.8779907	0.19
269.1085815	2.38
270.1182251	0.13
283.1157227	0.31
286.3479004	0.03
287.1984253	0.08
293.1160889	0.05
294.3754883	0.02
296.9739685	0.04
298.3594971	0.01
311.0544434	100.00
312.0646667	0.31
320.9308472	0.10
323.0433044	0.50
324.1584167	0.01
325.1056519	0.11
327.1789551	0.09
329.3996277	0.03
331.2198486	0.04
335.0994568	0.04
337.0476685	0.07
341.1794434	19.64
342.0697021	0.09
343.2674866	0.11
349.2488403	0.02
351.1002197	0.13
353.0983276	0.79
355.1289978	0.22
365.0670471	0.07
366.9971008	0.19
371.1711731	0.79
377.263092	0.26
383.1852112	0.42
385.2341003	0.04
387.0453491	0.02
389.0971375	0.02
395.2538757	0.32
411.156311	0.08
413.0845947	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.5016
Annotation	PI(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
240.8992615	20.20
241.9582977	6.82
242.8100891	0.09
255.1729736	39.77
256.2633972	23.53
257.2113647	1.24
259.0376892	1.43
277.1591797	19.89
278.2660217	10.88
279.3365479	1.52
296.9922180	15.83
298.0715942	5.65
299.1147461	0.74
315.1060791	3.31
316.0674133	0.56
391.2354126	57.07
392.2326660	39.34
393.1825562	8.04
409.2805176	2.63
410.4194336	1.53
413.2210083	7.24
414.1420898	7.27
415.1688232	1.69
430.9630127	0.44
432.2510986	0.56
461.0523071	0.16
462.1780396	0.67
463.2683716	0.46
480.5787354	0.57
497.2127075	0.11
498.4452515	0.18
504.2711182	0.26
553.2963257	62.79
554.3548584	100.00
555.4020386	17.23
571.3222656	13.20
572.3778687	22.79
573.4046021	1.85
575.2424927	9.69
576.3745728	28.43
577.4889526	3.93
593.4116211	1.65
594.4177856	3.01
669.5713501	0.10
670.5392456	0.13
671.7227783	0.39
745.2893066	0.17
753.4339600	0.59
767.9783325	0.15
812.2520142	0.13
814.2482300	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1032
Annotation	Toringin
Peak:m/z	Relative Intensity
130.8650208	0.07
142.8444366	0.04
144.1827698	0.03
148.8215790	0.05
160.8796692	0.04
163.0698395	0.05
192.0973358	0.02
193.1916809	0.03
215.1648254	0.09
245.9445801	0.02
253.1405640	0.09
267.0351868	0.28
268.1862488	0.02
269.1164856	0.07
274.6468506	0.06
277.0940247	0.13
279.3651733	0.38
280.2339172	0.05
282.2890625	0.02
283.2935486	0.02
289.1894836	0.12
291.0450439	0.04
293.0175781	0.10
295.0433350	100.00
296.2237549	0.15
304.8729858	0.07
307.1019897	1.28
309.2846375	0.07
310.1961060	0.02
310.9197693	0.39
312.1188354	0.07
317.0740356	0.03
321.0082703	0.09
323.3200684	0.05
325.0940247	18.20
327.1812134	0.10
329.1000366	0.04
331.1332703	0.09
332.2929688	0.04
335.3686829	0.13
336.0376587	0.07
337.0943604	1.56
338.9470825	0.79
341.1078491	0.19
349.1431580	0.31
351.1779175	0.24
352.4666138	0.08
353.2049561	0.05
354.2505798	0.06
355.1307373	1.07
356.1786194	0.05
357.0787659	0.03
359.1304626	0.02
361.1240234	0.21
367.0670166	1.04
369.1733704	0.12
370.5561218	0.01
371.2167664	0.05
373.3056641	0.43
377.1297302	0.06
379.1848450	0.91
383.1275940	0.05
384.2075500	0.11
385.2575989	0.29
395.9666748	0.23
397.2263794	2.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
143.0438538	0.03
205.8662109	0.04
251.0816345	0.04
269.0428467	0.57
269.9262695	0.08
279.2749023	0.03
281.1403809	0.13
283.1062927	1.14
293.1542664	0.29
295.1654358	0.25
296.9880371	0.07
298.9931030	0.03
299.8341980	0.03
309.2655334	0.06
311.0178833	100.00
312.0949097	1.43
320.8186646	0.05
321.8198242	0.02
323.1383057	1.83
324.2424927	0.07
325.1458130	0.23
337.0443115	0.10
339.2410278	0.05
341.1528320	25.28
342.2484436	0.35
349.1934204	0.13
351.3866882	0.02
353.0488281	1.99
355.1174011	0.76
356.3243408	0.04
365.2353210	0.12
367.2583313	0.10
371.1679993	0.49
377.1881409	0.51
383.1147156	1.72
385.0486755	0.08
388.4197083	0.07
395.0693359	0.56
401.1421814	0.06
413.0894470	2.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0154114	0.02
229.0175781	0.12
272.9247437	6.19
274.0064697	1.29
274.8388672	0.06
291.9569702	0.01
385.1098633	0.02
386.9039307	19.48
387.8704834	6.69
390.2829590	0.02
428.1569214	0.02
474.6985474	0.15
498.0574341	0.04
499.0032349	0.27
500.7927246	100.00
501.8247681	54.95
502.4603882	0.23
513.2677002	0.10
525.1846313	0.07
527.8273315	0.04
540.8861084	0.17
541.8303223	0.44
542.8701172	0.44
543.6564331	0.03
548.2797241	0.04
552.2570801	0.06
558.7590942	0.23
559.5770874	0.08
560.3994141	0.08
566.7472534	0.05
568.9214478	0.76
569.8035889	0.68
570.7750854	0.67
571.6250000	0.14
573.8660278	0.09
579.0204468	0.03
582.8869019	0.25
583.9000854	0.17
587.0443726	0.02
587.7407837	0.11
596.8508911	0.05
597.9443970	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2603
Annotation	Taxumairol V
Peak:m/z	Relative Intensity
160.9543610	0.11
172.0086670	0.13
174.8587646	0.37
179.2170258	0.10
184.3161316	0.31
186.8820190	0.06
195.1794891	0.06
223.1761780	0.04
231.4789429	0.08
238.1283264	0.17
250.9480133	0.12
257.3884888	0.05
265.1025391	0.10
270.8120117	0.22
273.2197876	0.19
275.3147583	0.56
287.1943359	0.24
301.0478516	0.48
303.2514954	1.48
312.4337769	0.17
315.3632202	0.56
316.0218506	0.07
327.0017090	0.08
333.2529297	0.09
341.1019897	0.18
343.4142456	0.16
347.2556152	1.61
357.1947021	0.08
359.2957153	0.10
361.4584351	0.13
362.7783813	0.08
363.4093628	0.13
365.2396240	1.27
366.4732056	0.08
367.5360107	0.11
369.1299438	0.71
370.3777466	0.16
383.7684326	0.11
385.6151123	0.31
389.2198486	1.04
390.3963623	0.04
397.9921265	0.14
399.1331787	0.41
402.2070923	0.20
407.1577759	0.30
415.0281372	0.05
417.3016357	0.22
418.9510498	0.09
429.2241821	0.23
432.2096558	0.34
432.9943848	0.50
437.2169189	0.68
443.2545776	0.16
447.3533325	3.60
449.0227661	0.52
463.2509766	0.06
465.2125244	3.43
466.7021484	0.13
479.2751465	1.65
481.2308350	2.52
482.2996216	0.18
483.2214355	0.43
485.3261108	0.29
490.4714355	0.17
497.2351685	0.14
505.4443970	0.06
509.2332153	100.00
509.8482666	0.93
510.5679321	0.40
521.0597534	0.04
522.4312134	0.72
523.2865601	0.76
524.3600464	0.07
525.2034302	0.39
527.2522583	56.12
527.9102173	0.18
531.3067017	0.12
532.2841187	0.12
533.1678467	0.07
539.1026001	2.60
541.2674561	2.52
549.4881592	0.13
550.4547729	0.05
551.1973267	0.95
552.2406616	0.29
554.5606689	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0849
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
76.7876587	0.12
84.0238266	0.21
89.9565277	0.36
91.2355804	0.05
118.9291077	87.81
130.0533142	1.70
135.9704590	100.00
147.9759674	0.59
202.0605316	1.79
216.7716522	0.16
218.2688293	0.09
222.9479218	0.07
229.1122284	0.44
247.0508575	1.85
248.0130157	9.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Lactulose
Peak:m/z	Relative Intensity
179.1905518	0.35
203.0475922	0.41
221.0917664	7.28
232.7492981	0.33
244.9263916	0.23
250.9096222	1.42
262.4459534	0.20
265.6493835	0.28
268.7774048	0.16
280.8892212	3.14
305.1121216	0.96
311.0557861	0.34
318.3951416	0.22
323.0806885	3.79
340.9399414	34.67
341.5947876	0.15
346.1695557	0.29
383.2109985	100.00
391.1909180	0.17
407.1478882	0.44
412.4482422	1.15
413.1770630	0.04
425.2736206	3.30
440.8545532	0.09
442.9449463	21.23
456.9445801	0.42
466.9393311	1.67
485.2126465	34.17
503.0554199	3.94
510.2904663	0.46
527.0351562	0.33
527.9627686	0.85
530.1918335	0.75
542.1893921	1.97
545.0264893	2.22
545.6792603	0.06
645.4757080	0.45
647.2663574	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.3293
Annotation	PS(20:1(11Z)/0:0)
Peak:m/z	Relative Intensity
167.0520630	0.04
176.8590088	0.06
183.9791260	35.64
197.0640259	0.03
204.2675171	0.07
219.0647583	0.05
223.1329956	0.10
241.2217560	0.39
248.1398926	0.04
251.4505005	0.07
258.1351624	0.44
263.3968506	0.26
268.2036743	0.07
268.9910278	0.06
271.0314331	0.06
272.7192383	0.04
277.1486206	0.15
307.3436279	0.04
308.2757568	0.09
313.4891357	0.12
314.3668213	0.05
324.9227295	0.06
328.2910156	0.04
335.1878052	0.11
337.1475220	0.07
339.5068359	0.07
340.5634766	0.18
348.4758301	0.17
351.5282593	0.15
361.0463257	0.07
363.0643921	0.29
365.3151245	0.11
367.2185059	0.09
369.2369995	0.23
371.3016968	0.24
372.0347900	0.03
377.2730713	0.05
380.2507935	0.33
382.8757935	0.04
383.6597900	0.11
389.2283325	0.07
390.2573242	0.18
394.3786011	0.87
398.3984375	0.03
406.2229614	0.10
407.3928833	0.06
412.2131958	1.02
417.0236206	0.04
420.7330933	0.04
422.8203125	0.14
424.1722412	0.19
431.8359375	0.04
433.0549927	0.04
434.2811890	29.55
436.0691528	0.21
438.3059082	0.17
443.0532837	0.05
446.1965942	0.15
447.4411621	0.02
452.2525635	3.16
453.5669556	0.16
457.3712158	0.05
462.4131470	0.14
463.3341675	0.31
464.4441528	0.02
470.0421143	0.04
473.7202148	0.20
477.1668701	0.09
478.0417480	0.04
478.7645874	0.21
479.5520020	0.17
481.2418823	0.41
481.8568726	0.85
487.2400513	0.31
489.4042358	0.05
490.1558838	0.05
493.5657349	0.07
494.3829956	0.18
498.2539673	2.74
500.3765259	1.17
503.2562866	0.19
505.6477051	0.27
507.4299927	0.18
508.4384155	0.05
511.4190063	0.17
516.2959595	22.71
518.3728638	43.94
520.1281128	0.05
523.3014526	0.03
528.1746216	0.10
534.2853394	100.00
535.2294312	1.09
538.4487915	0.03
543.4504395	0.53
552.0794067	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1614
Annotation	Safflomin A
Peak:m/z	Relative Intensity
171.0744629	0.21
175.0105896	3.07
176.9966278	3.91
178.9951324	0.48
185.1320801	0.25
188.0674286	0.15
196.2449188	0.11
197.2055054	0.99
198.3322144	0.47
199.0139008	0.71
201.1066284	0.15
202.9477234	0.26
204.1107941	0.27
209.0678101	0.66
213.0602722	0.53
215.2100983	0.27
216.0457306	0.21
217.1054077	1.91
219.0658264	0.15
222.9148560	0.16
225.3665771	0.11
239.0821075	1.18
240.0821228	0.10
241.0870819	6.04
243.0763702	2.47
244.8433533	0.34
256.9329834	1.70
259.0947876	0.44
260.1635437	0.14
265.1555786	0.11
266.9854126	0.73
269.2916870	0.49
275.1737671	1.69
277.0917969	0.10
283.4109497	0.25
285.0180054	100.00
286.9653931	0.10
292.2583008	0.19
299.1054077	0.17
303.0569458	92.60
307.1021729	0.42
309.0749512	0.16
311.2084656	2.33
322.9493408	0.46
327.1032104	0.68
329.1176147	2.23
336.9517212	0.11
341.1932983	0.14
351.0609131	0.17
355.0380249	0.09
359.1249390	0.73
363.3040771	0.29
365.3104858	0.28
371.0648193	8.90
383.2418823	0.35
387.4275513	0.27
392.1384888	0.10
397.2728882	0.16
401.0206299	4.32
404.2271729	0.12
406.0989990	0.92
406.9887695	1.17
411.1932373	0.67
413.3056030	0.34
431.2062988	5.83
443.0893555	0.43
449.1405640	3.89
453.0521240	0.26
455.4017334	0.08
459.1812134	0.15
460.8767700	0.52
469.1940308	0.10
471.4891357	0.52
473.1411743	2.52
475.2819214	0.09
481.0541382	0.10
485.0752563	0.05
487.1444702	3.23
488.1565552	2.49
489.5324097	0.57
491.1151733	23.02
495.0844116	0.10
503.0984497	1.45
515.9075317	0.45
517.2546997	1.76
521.1227417	3.09
524.6927490	0.05
527.2245483	1.01
535.4289551	0.14
543.5972290	0.40
548.6384277	0.34
557.2556763	0.06
564.6871948	0.51
565.4242554	1.80
567.2277832	2.15
575.2319946	0.39
581.0437012	0.16
583.2993774	2.44
592.0866699	0.34
593.1858521	14.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.22
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
106.9730988	0.06
108.9982605	0.03
112.0461502	0.06
117.0285797	0.01
119.3625641	0.07
120.9346313	0.08
123.0532684	0.04
125.1601791	0.02
126.0155106	0.05
128.8825378	0.10
130.8654633	0.04
134.9701233	0.02
136.8236694	0.02
138.8685455	0.02
141.2112427	0.04
143.0065155	0.15
147.1001892	0.23
148.0607605	0.04
149.2721863	0.02
151.1765900	0.05
154.8402100	0.04
156.9744263	0.13
158.9168701	0.08
161.1100616	0.09
163.0303040	0.03
164.0410767	0.09
164.9776917	0.04
170.9157410	0.13
173.0982361	0.07
174.9698792	0.11
177.2672729	0.02
181.0605774	0.06
182.9711761	0.04
184.1099548	0.05
184.9610291	0.23
187.2257080	0.09
189.1695557	0.25
191.1869354	0.02
193.0548706	0.04
194.9483948	0.13
195.9068604	0.02
196.9792938	0.03
198.8048706	0.11
201.2329102	0.04
203.1284943	0.05
205.1399231	0.08
207.0081024	0.10
209.1805573	0.03
211.2059021	0.04
212.1497803	0.05
213.1170044	0.20
213.9942627	0.05
215.3476257	0.02
217.0671997	0.04
219.1281128	0.20
220.0121460	0.09
221.1502380	0.07
223.1326904	0.24
225.1487427	0.12
227.9833679	0.25
229.0744019	0.09
231.0269470	0.13
235.1264954	0.20
236.1052856	0.06
237.1755981	0.22
239.2426147	0.24
241.1287537	0.17
243.3636780	0.07
245.0212097	0.29
249.1810303	0.45
251.4802551	0.12
253.1855469	0.37
254.3227844	0.03
257.0037231	0.26
259.3216858	0.09
262.1253662	0.02
263.2564392	0.40
265.1582336	0.11
267.2030945	0.12
269.0465088	0.20
274.1826782	0.05
275.0894165	0.02
277.2617188	0.21
279.1099854	0.28
280.8925781	0.19
281.8120117	0.03
284.1565552	0.09
287.1796570	0.29
288.6027832	0.14
289.2926331	0.02
289.9586182	0.01
291.2735291	0.43
293.2095947	0.67
295.3375854	0.02
305.1248779	0.55
307.2016907	0.03
308.4409180	0.11
309.1019897	0.24
310.3235779	0.25
313.2402039	0.22
314.0620728	0.02
315.0922241	1.60
315.9300537	0.12
319.2445068	0.11
320.0990295	0.03
321.3001709	0.03
322.2261353	0.06
323.0652466	0.45
328.0974426	0.02
329.1984253	0.03
330.6283569	0.10
333.1706848	100.00
334.2538452	0.05
335.1971741	0.04
341.9613342	0.15
343.2187195	0.03
350.4238586	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	832.6234
Annotation	Unknow
Peak:m/z	Relative Intensity
244.0382690	0.18
246.7521362	0.04
261.2451782	0.11
277.1445007	0.07
278.8801270	0.03
301.5158997	0.08
319.1650085	0.07
321.1498413	0.05
337.2974243	5.66
338.3708496	1.32
356.1294250	0.03
360.3634644	0.08
373.3400574	0.01
401.1600342	0.09
403.1056519	0.56
404.2095947	0.16
416.5758667	0.38
417.6143799	0.04
419.3040161	13.66
420.4381714	5.09
422.4339600	0.05
437.1546631	1.25
438.2348022	0.13
440.4279785	0.02
449.5365601	0.04
467.4272461	0.04
478.4154053	1.66
479.4498291	0.85
480.6589966	0.09
496.3634644	100.00
497.3480225	28.43
498.0087891	0.12
502.3944092	0.31
507.5446167	0.05
509.2877197	0.03
537.3919678	0.11
582.4948730	0.11
602.0222778	0.01
675.4165649	0.17
814.6764526	0.80
815.6325684	0.91
833.4367065	0.58
834.2713623	0.13
834.8734131	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
135.1168518	0.02
137.0738525	0.00
142.853653	0.01
149.0988922	0.05
151.2229004	0.00
161.0237427	0.07
161.8541107	0.01
162.9728241	0.01
164.1577454	0.01
172.0058899	0.01
178.2437134	0.01
182.972229	0.01
189.1899719	0.11
190.324707	0.04
192.3381195	0.02
202.0374451	0.01
204.9385529	0.01
207.1718903	0.34
208.2268372	0.05
217.9896393	0.01
224.7915192	0.01
232.277832	0.01
233.0448456	0.10
234.0430908	0.02
239.5154724	0.00
240.9847717	0.01
247.0114746	0.02
249.0544128	0.01
251.1486816	4.77
252.1630554	0.66
254.1863403	0.01
257.3601074	0.01
259.2507935	0.03
262.6586304	0.01
267.3200378	0.05
268.383728	0.61
269.117218	7.48
270.1257324	1.46
281.0998535	0.05
282.0957336	0.07
283.096283	0.36
284.2255859	0.17
285.5322876	0.01
287.3012695	0.19
288.2947388	0.01
291.2144165	0.02
292.4205933	0.00
293.2319031	0.06
294.1737671	0.01
295.2370605	0.05
296.4809265	0.01
297.9378662	0.01
299.4198608	0.06
306.3138428	0.00
307.1994019	0.01
309.2391968	0.08
311.0542603	100.00
312.0579224	23.61
312.6865234	0.05
313.4663696	0.02
315.2307129	0.03
321.1111145	0.05
322.4606018	0.05
323.1228943	0.55
324.114563	0.18
325.0594788	0.08
326.0544434	0.02
329.1550598	0.02
330.6102295	0.02
331.2623291	0.01
333.1286621	0.01
333.9735413	0.01
335.0762024	0.05
337.1295776	0.14
338.2352295	0.03
341.1141663	27.36
342.1066895	7.53
344.2040405	0.03
345.3704224	0.01
347.9817505	0.01
349.2705383	0.06
351.1760864	0.06
352.4120789	0.04
353.1988831	0.59
354.1430054	0.25
355.213623	0.63
356.2270508	0.22
357.9179382	0.00
365.1890259	0.11
366.169342	0.03
367.1456604	0.10
367.9446411	0.02
369.3493042	0.03
371.0892944	1.04
372.1023254	0.41
376.1988525	0.04
377.1702271	0.28
378.2917786	0.07
383.0219421	0.32
384.1938782	0.13
385.995575	0.01
387.1875916	0.05
388.0945129	0.01
394.0675964	0.06
395.15979	0.92
396.2079163	0.32
401.3796997	0.05
402.1781616	0.08
403.1119385	0.01
404.1048889	0.02
413.122345	3.79
414.1591492	0.92
415.3786011	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5065
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
205.1408081	0.14
208.9820862	0.20
223.1732788	0.73
233.3711853	0.36
240.9976807	0.22
251.1446381	0.15
255.2153625	35.31
256.2492371	0.08
259.3140564	0.10
261.4043884	0.18
279.2271118	100.00
283.4026489	0.25
284.1756897	0.13
293.2032471	0.72
295.1433716	0.09
296.4821167	0.08
377.2415161	0.28
391.3265381	0.38
392.2888794	0.18
408.3828735	0.23
419.6049805	0.59
420.3361206	0.15
434.3851929	2.31
437.3267822	0.40
452.2229004	16.42
452.8730469	0.09
458.2124634	1.62
476.2773438	2.09
480.475647	0.32
490.3985596	0.25
491.2753296	0.13
523.371582	0.18
553.2409058	0.18
554.2974243	0.13
571.4706421	0.12
574.3102417	0.60
579.3980103	0.20
614.2935181	0.13
651.1259155	0.12
653.090271	0.24
670.3880615	0.12
695.3578491	0.34
696.4116821	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9592896	0.12
217.0691071	0.04
229.0233002	0.04
232.9384766	0.09
272.9229736	7.01
273.8683472	0.04
290.1441040	0.06
384.7430420	0.03
386.4049683	1.93
387.0123291	13.42
388.5364380	0.18
429.1891479	0.07
458.0904541	0.05
466.6383057	0.05
472.1555176	0.18
498.9609375	0.74
500.7891235	100.00
501.4421387	0.60
509.9669800	0.10
512.2178345	0.07
513.0183716	0.11
513.9204102	0.20
522.3746338	0.05
528.6109619	0.15
539.9490356	0.11
540.8608398	0.80
541.9000244	0.66
544.6392212	0.12
546.8674316	0.04
557.7825928	0.20
559.7990112	0.03
566.1083984	0.05
566.8444824	0.24
567.8707886	0.85
568.8533936	0.88
570.0338745	0.43
570.8600464	0.58
571.8023071	0.23
572.6483154	0.07
583.7850342	0.09
585.4819946	0.15
586.7298584	0.19
590.8875122	0.13
596.0287476	0.14
615.3038330	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2392
Annotation	Radiatoside
Peak:m/z	Relative Intensity
200.2082214	0.05
200.8559418	0.25
203.3811798	0.14
208.9848480	0.15
210.9134827	0.49
211.8638000	0.34
213.0608673	0.32
214.0086365	0.42
215.0751648	2.57
215.9239044	1.10
217.2416077	1.84
219.0659790	0.18
221.0831146	1.48
222.0375671	0.26
225.2202454	0.35
227.0659180	4.20
228.2238159	1.18
229.1925201	0.87
230.5410919	0.50
231.2635498	0.35
233.1490479	0.10
241.0046082	0.26
243.1703949	1.47
244.1094360	0.17
245.2771301	0.99
246.0993805	0.09
251.3426514	0.12
253.1699524	3.98
254.2500305	1.04
255.0091858	0.15
257.3237000	0.28
259.1273193	0.47
260.7139893	0.83
262.7656250	0.82
263.3738098	0.07
271.0820312	18.69
272.1784058	2.59
283.2378540	0.12
285.0176392	0.16
286.9976196	0.33
289.1663513	17.48
290.2181702	2.24
295.5543213	0.24
297.2293396	0.48
305.3539429	0.14
306.5039062	0.22
307.2170715	0.22
308.0255127	0.20
313.3829346	0.31
315.0527344	13.54
316.2467041	1.63
317.0653076	0.10
317.7985229	0.20
326.7552490	0.07
331.3305054	0.16
333.2083130	4.57
334.1554565	0.77
341.0527954	0.54
342.9629211	0.17
359.1378174	8.05
360.0754395	0.76
361.1898193	0.12
369.8413086	0.54
377.1528931	100.00
378.2474976	20.18
379.3481445	0.54
386.0996704	0.11
394.9172363	0.08
403.3810425	0.18
415.3036499	0.25
420.1856689	0.12
451.3395996	0.53
452.1074219	0.17
456.9392090	0.24
469.3027954	6.85
470.2456055	2.44
475.5527344	0.11
495.1694336	0.59
496.3324585	0.26
498.2817383	0.05
513.3407593	0.72
521.2691650	0.09
537.6019897	0.24
539.0068359	0.75
540.2524414	0.19
554.3292847	0.52
555.7064819	0.40
557.2540894	6.21
558.2808838	1.64
582.5682983	0.06
585.3578491	0.11
595.1417236	0.18
599.2235107	0.47
602.2920532	0.42
611.5303955	0.19
613.2619019	15.94
614.4481812	6.01
627.6252441	0.10
629.5911255	0.09
631.3101196	36.96
632.2919312	11.10
632.9186401	0.11
639.0286255	0.25
645.2932129	0.62
646.4877930	0.39
657.2541504	15.05
658.3006592	3.12
660.3855591	0.63
673.4554443	0.75
675.2585449	44.12
676.3246460	13.26
676.9442749	0.16
678.4418335	0.11
683.3733521	0.44
689.4995728	0.47
690.4063721	0.41
701.2186890	14.79
702.3253784	5.45
703.5010376	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.2637
Annotation	Unknow
Peak:m/z	Relative Intensity
170.0751343	0.06
183.0677643	0.07
187.9587097	48.46
189.1133118	0.61
204.9823608	100.00
205.8789825	0.11
207.0534210	2.52
221.1123047	0.08
224.2038269	0.24
224.9873047	1.65
242.4127960	0.38
243.0947418	0.37
244.8852234	0.09
246.8691406	0.04
260.8439331	0.03
297.9497070	0.54
309.2242126	0.10
311.0882263	0.04
313.1484375	0.07
355.8766479	0.13
366.3453369	0.03
367.0999756	0.15
369.3885498	0.05
386.5899658	0.88
387.3640747	0.05
404.3828735	0.02
405.0155640	0.06
410.9234619	0.11
419.1053467	0.03
428.9223022	0.10
441.1967163	0.04
447.1752930	0.47
462.2540894	0.17
471.3385010	0.03
478.1301880	0.21
530.9869995	0.05
534.5075684	0.03
547.3200073	0.10
549.4756470	0.02
562.1242676	0.08
563.2112427	0.10
567.1533813	0.13
577.3045044	0.19
585.5778809	0.05
588.7490845	0.06
591.0974731	1.11
592.3672485	0.39
611.2957764	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.22
Annotation	Crepenynic acid
Peak:m/z	Relative Intensity
83.0291138	1.76
87.2059174	0.20
96.9969253	0.29
106.7963715	0.50
123.0641251	0.27
135.1824646	0.21
137.2803955	0.18
142.9920807	0.24
144.9634705	0.45
160.9988708	0.58
163.0438843	0.67
166.1702728	0.35
175.3345642	0.27
176.9873657	1.79
179.1056519	4.88
191.1026001	3.76
203.0911560	0.32
205.2508850	4.48
211.2321472	0.30
219.1830139	1.67
221.1622925	0.64
231.2735901	0.93
233.2231750	100.00
235.1394043	0.49
241.2734985	1.37
247.1795044	0.61
257.2171326	5.93
259.1813354	46.34
259.8345642	0.08
261.2914429	3.69
275.1609497	1.11
277.2334900	1.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2445
Annotation	ID14326
Peak:m/z	Relative Intensity
163.0140076	1.21
178.3532715	0.06
207.1839905	0.11
211.2273254	0.07
231.4026031	0.07
234.1553497	0.29
235.0216980	0.17
264.6316528	0.54
265.2671814	0.05
279.5177002	0.06
281.1385803	0.06
288.9575195	0.09
291.5004578	0.14
302.9873047	0.04
307.0261841	0.29
310.2283020	0.10
314.0248413	0.12
314.8669128	0.11
324.7504883	0.93
327.3638306	0.21
331.0922241	0.07
335.3695679	0.13
342.8508301	0.05
343.5839233	0.11
345.2595215	0.05
363.1177063	0.48
374.1065674	0.22
378.8272095	0.03
387.2990723	0.10
391.0016785	0.24
395.1554260	0.07
396.0636597	0.04
410.1234131	0.07
428.0042419	0.03
429.2030945	0.05
435.0671997	0.03
443.3038025	0.15
445.4950867	0.02
447.4343872	0.22
449.2373657	0.05
461.1609192	100.00
461.9520264	0.90
463.1590881	0.72
464.7342224	0.12
465.4276123	0.51
466.9549866	0.11
468.0453186	0.05
469.1007690	0.03
471.1163635	0.03
471.8843384	0.15
475.2519836	0.05
477.3794556	0.13
478.5210266	0.16
479.3932190	0.06
488.2451477	0.29
489.3768921	0.74
490.4770203	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
143.0632935	0.05
160.7735596	0.14
191.151947	0.05
230.907135	0.03
249.0070496	0.01
269.1903687	0.33
281.1129456	0.08
283.1973877	0.35
293.3910828	0.04
295.1604004	0.05
297.3250732	0.01
309.2423096	0.10
311.0576782	100.00
312.107666	0.19
323.1003723	0.35
337.3129272	0.04
341.1043701	14.24
342.0386047	0.13
345.1706238	0.03
351.1449585	0.07
353.0476685	0.52
355.1598511	0.25
359.2269287	0.01
364.7089233	0.08
365.3164673	0.04
369.7529602	0.05
371.191925	1.32
372.3502197	0.02
377.1107178	0.26
383.1677551	0.44
384.1257019	0.03
385.330719	0.11
386.789856	0.05
388.2975464	0.20
389.0384827	0.06
395.1840515	0.55
399.2541199	0.12
412.0943298	0.05
413.2610779	1.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.3592
Annotation	Unknow
Peak:m/z	Relative Intensity
217.3227997	0.22
223.2867126	0.44
233.2400360	0.23
237.0119781	0.06
238.2677917	0.27
248.1399841	0.16
249.0849152	0.13
260.0378113	0.09
265.0793762	0.87
266.9902954	1.47
277.2034302	0.08
283.1528320	3.38
284.0376587	0.71
296.8141785	0.43
297.4515686	0.42
304.1484375	0.11
305.2132263	0.69
306.0760193	0.09
306.6869507	0.22
309.2852478	0.10
318.9584961	0.05
321.1721191	0.06
322.0179443	0.31
323.1456299	5.58
324.0698242	0.12
327.3177795	0.60
334.5126343	0.16
336.0319214	0.47
337.3131714	0.12
341.2841187	0.22
342.9629517	0.17
348.9722290	0.57
349.7309570	0.10
351.0378418	0.26
353.1982422	0.47
361.2559204	0.42
363.0843506	27.20
364.1388550	6.13
365.0728760	0.84
378.2732544	0.28
379.1998291	3.25
380.3209839	9.65
381.1807861	100.00
382.1383667	6.28
395.4698486	0.07
397.2722168	0.22
398.3625488	0.78
407.4500122	0.41
420.3896484	0.26
421.0690308	0.06
433.5613403	0.10
458.0661011	0.13
459.1796265	0.26
473.4281616	0.16
478.0338135	12.94
479.1824341	2.91
483.1557617	0.09
487.3344727	0.22
490.8330078	0.16
496.1999512	0.17
502.5099487	0.06
512.2822876	0.12
517.3511963	0.86
518.4090576	0.51
519.1061401	0.71
520.1910400	0.07
535.3513184	0.24
536.7037964	0.23
547.2052612	0.16
549.1620483	0.28
555.1103516	0.27
556.3566895	0.14
558.3545532	0.40
559.6259766	0.44
564.2616577	0.11
576.2407837	2.58
577.2192993	1.25
578.5381470	0.04
581.2406616	0.05
586.4469604	0.29
589.3264771	0.24
592.6318970	6.98
593.2406616	33.61
594.1842651	8.92
594.9415283	0.11
621.4601440	0.07
625.6403198	0.24
632.2375488	4.99
633.3709717	1.43
634.3162231	0.08
635.4034424	0.13
637.4596558	0.09
645.2745972	0.24
650.1319580	0.25
664.4830933	0.37
667.3689575	0.31
671.8325806	0.39
673.4816284	0.66
676.2286987	0.10
677.2208862	0.53
681.7064819	0.08
690.3585205	1.31
691.3111572	1.27
692.4425659	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1013.6022
Annotation	trans,octacis-Decaprenylphospho-beta-D-ribofuranose 5-phosphate
Peak:m/z	Relative Intensity
347.1732483	1.61
351.1387329	0.32
363.2376709	0.06
405.2968445	1.85
406.4430542	0.23
407.6875000	0.11
414.4027405	0.16
421.2210999	0.14
425.2597046	0.35
439.2698364	1.79
440.4056091	0.34
507.4198303	0.33
508.2883911	0.81
523.4237061	3.90
524.3975830	0.49
535.5765381	0.29
567.4671631	0.14
569.4700928	6.41
570.4035645	0.40
587.3902588	1.61
591.1578369	0.12
601.5120850	0.05
616.4891357	0.18
629.4680786	0.16
631.5503540	0.31
633.3875732	0.47
634.6191406	0.25
671.7172241	0.18
673.5364990	0.23
683.5722046	0.07
685.3917236	41.51
686.1250610	1.08
686.7450562	3.28
695.4384155	0.14
703.2294922	0.07
719.7392578	0.13
731.3646240	100.00
732.4010010	9.56
747.3948975	0.29
769.2814941	0.07
791.0325928	0.24
815.3797607	0.16
833.7187500	0.22
851.5257568	12.09
852.6877441	2.64
853.3272705	0.79
868.6579590	0.08
869.6223145	0.80
870.5808105	0.06
896.3244629	0.14
897.5308838	0.98
906.7827148	0.22
914.3734131	1.01
915.5650635	0.27
935.4707031	0.06
956.7196045	0.13
978.5184326	0.11
994.6616211	0.10
995.3378906	0.09
1013.4177250	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.508
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
211.2416687	0.06
222.901001	0.06
241.1477814	0.25
245.2882996	0.17
251.0473633	0.15
255.2964783	32.82
261.1448975	0.85
279.234375	100.00
279.8610229	0.19
281.2550659	0.15
291.3404541	0.20
293.4059143	1.10
306.9461365	0.26
309.3484192	0.25
327.2688599	0.07
418.6474609	0.17
419.4963379	0.23
420.4703979	0.07
434.3295898	1.04
452.2513428	17.46
453.222229	0.29
458.19104	0.06
476.2459717	0.87
480.4169312	0.08
484.279541	0.39
506.1933594	0.17
555.4471436	0.18
584.3042603	0.21
650.2776489	0.22
680.5769043	0.14
695.3428345	0.18
696.4396973	0.85
713.8927002	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2247
Annotation	Lactulose
Peak:m/z	Relative Intensity
338.6072998	0.02
339.3979492	0.03
341.0656128	100.00
341.9720459	0.03
636.7841187	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.264
Annotation	Unknow
Peak:m/z	Relative Intensity
170.4424896	0.85
171.1179199	0.11
179.1191864	1.05
183.1270752	0.26
188.0513153	45.92
189.0809021	2.93
190.4080505	0.18
205.0705719	100.00
206.0945435	2.60
207.1147614	26.34
224.9763184	15.07
228.1790619	0.33
236.2467957	0.06
241.1646423	0.14
243.0085602	1.03
244.1400299	0.09
260.9746094	0.39
262.2727051	0.25
285.2929688	0.69
298.3034058	0.43
313.0609131	0.06
328.0572510	0.22
333.1354370	0.17
349.2326050	0.44
369.3404541	0.27
372.1565552	0.25
386.4550781	3.42
387.0922852	6.21
388.1233521	0.44
401.1737671	0.50
403.3946533	0.24
404.2687378	1.15
405.0419312	3.31
405.7618408	0.12
407.2800903	0.54
411.0584106	0.44
412.0990601	0.19
417.9832764	0.08
445.3720703	0.38
447.0433350	0.54
449.1694946	0.16
453.1152954	0.10
455.0118408	0.39
463.0082397	0.42
480.0255737	0.81
490.3998413	0.45
518.4193726	0.47
547.6948853	0.17
552.5584717	0.48
563.1177368	0.53
565.1073608	0.34
575.2313843	0.19
582.5441284	0.30
589.5097656	0.83
591.1176147	17.99
592.3341675	5.08
600.3053589	0.28
601.8051147	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	657.3118
Annotation	Alpindenoside C
Peak:m/z	Relative Intensity
225.3465271	0.72
228.6634064	0.40
233.1220703	0.60
246.9956970	0.88
261.3740234	0.16
275.3068848	0.79
287.4046021	0.21
302.9248962	0.40
303.6292114	0.17
305.4089355	0.18
317.1599731	1.24
329.1672363	0.62
331.3028564	1.37
335.3395386	0.60
345.5489502	0.32
349.2031860	36.83
350.3270874	2.41
357.4448853	0.23
373.1085205	0.99
389.3491821	0.29
401.3404541	0.47
409.5290527	0.53
413.2039795	0.27
419.3022461	2.64
421.3023071	17.84
431.3689575	1.10
433.2354126	1.08
437.3992920	1.54
439.2733154	0.36
449.2613525	52.24
461.4002686	0.20
465.6223755	0.53
467.2891235	16.28
483.6881104	1.78
493.4071045	11.80
494.2366333	0.45
495.3659058	6.20
499.4771729	0.43
504.9879761	0.15
509.4030151	0.84
511.2725830	100.00
512.3257446	5.87
535.0607300	0.68
537.3098755	0.36
563.2076416	1.59
567.3118286	10.35
577.3214111	0.32
581.2984619	0.57
595.3255005	42.13
596.1943970	0.43
597.2421265	2.03
611.3976440	2.87
612.3025513	0.88
613.2847290	13.22
620.7501831	2.02
627.3079834	54.01
629.4216919	38.87
639.3904419	11.30
647.1587524	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	583.4146
Annotation	Pectenol B
Peak:m/z	Relative Intensity
162.8760529	0.06
165.0081329	1.41
169.0514679	0.21
171.1210022	0.21
173.0412750	0.58
175.1248474	0.89
176.1534119	0.32
178.2369385	0.42
179.0274658	0.70
180.0823212	0.09
181.1727295	0.86
182.1366577	0.23
182.9761047	0.79
185.0206146	0.60
187.1315613	0.87
190.1181030	0.09
191.2164764	0.96
191.8166504	0.09
193.0793457	0.36
194.2594910	0.11
195.1294556	0.93
197.3867798	1.19
199.1722107	0.60
201.9887085	0.07
203.1405029	1.18
205.0873566	1.07
206.1991882	0.53
207.1278534	2.19
209.1136475	3.91
211.0428162	1.31
213.1278687	0.55
214.9970093	0.44
217.1535645	0.11
219.2509003	0.36
221.1928711	10.58
222.4034729	0.23
223.1249695	1.23
225.1745911	0.58
227.1119995	0.15
228.8493195	0.33
233.0785217	1.23
235.1994171	2.33
237.2247620	0.66
239.4788513	0.24
240.9499207	0.32
243.0683441	0.13
245.2792969	0.60
246.3496094	0.31
247.2261658	1.59
249.2716980	0.95
250.6661072	0.18
253.1468811	0.57
255.2013397	0.10
257.2405396	0.46
258.1887207	0.57
259.1722412	0.58
260.3069763	0.42
261.1430664	1.09
263.1731262	2.25
265.0548706	1.90
267.1148682	0.26
269.2802429	0.70
271.3957520	0.28
273.1984253	1.77
274.1765442	0.22
275.2296753	1.72
277.1201172	0.44
279.2005005	0.78
281.2269287	0.15
283.0313110	1.23
285.1082764	1.08
286.1884766	0.07
287.0701294	1.39
289.0117798	1.08
289.6658325	0.18
291.1909790	0.56
293.0940552	0.85
298.1574707	0.38
299.3754272	0.95
300.8794861	1.30
301.5234985	0.42
303.1121826	0.72
305.3677673	1.38
307.3145752	0.81
309.3019409	0.41
311.4026489	0.20
312.4259033	0.62
313.2214355	0.83
315.2681885	0.49
317.2813416	1.01
319.2022705	0.80
321.1924438	1.09
323.3258057	0.35
325.6489868	0.36
326.4554443	0.32
327.3810425	0.19
329.4155884	0.39
331.3868408	1.04
333.3681030	0.70
335.1387329	0.85
336.3426514	0.27
337.3632812	0.36
338.3381958	0.16
339.4086914	0.27
341.4060669	0.15
342.2808228	0.43
343.2530518	1.64
345.3531494	0.43
347.3151245	0.55
349.2379761	0.27
351.2431030	0.72
353.3182373	0.53
355.1367798	0.39
356.0870972	0.15
357.3712769	1.58
359.2423096	2.21
361.0043945	0.22
362.1892700	0.04
363.2547607	0.11
364.3334351	3.82
365.3867188	0.44
367.3627930	0.26
369.0429688	0.35
371.0314941	0.34
373.3869629	0.70
375.2656860	1.94
377.4052124	4.95
378.1659546	0.14
379.4110107	0.13
381.3275146	0.50
383.2068481	0.55
385.4142456	2.74
386.5946655	0.26
387.5288086	0.96
388.2510986	0.16
389.3621216	1.29
390.2938843	2.47
391.1520386	1.02
393.2747803	0.21
394.4694214	0.12
396.2354126	0.18
399.3581543	3.89
401.3025513	0.30
403.3944702	1.41
405.7769775	0.17
407.2900391	0.48
409.3367920	0.96
411.3937988	0.07
413.3234863	0.35
417.2509155	0.23
419.3069458	0.15
421.0856934	0.51
423.5043335	0.24
425.3946533	6.88
427.3192139	2.06
429.2103882	0.31
430.2457886	0.63
431.4325562	0.16
433.3743286	0.36
435.4730835	0.23
438.2147217	1.50
439.4595947	0.34
443.3283081	1.41
445.4511108	1.18
449.2540283	0.06
450.0670776	0.30
453.5303345	0.14
455.3638306	1.08
457.6722412	0.17
459.4501343	0.21
461.1807861	0.41
463.6134033	0.63
464.4871826	0.13
465.3035889	0.82
469.6270752	0.36
471.6553345	0.66
473.6217041	0.63
477.3479614	3.43
478.4501953	0.38
481.5312500	0.29
485.2922974	0.20
487.8475952	0.27
491.4080200	100.00
493.4781494	0.16
494.2675781	0.16
497.5022583	0.20
499.5303345	0.19
502.7683716	0.13
504.4716187	0.99
505.2937622	0.09
507.4167480	0.21
509.4224243	1.04
521.4539795	0.24
523.4837646	0.53
527.3410645	0.93
532.3064575	0.18
539.4675903	0.38
541.3481445	0.14
547.4824829	2.48
548.4296265	0.11
549.1577759	0.06
550.4713135	0.11
555.5078125	0.18
565.3761597	20.18
565.9963989	0.14
574.3049927	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.4523
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
236.1805725	0.11
240.8805237	0.12
256.3159790	0.05
265.3208008	0.15
279.5853271	0.08
298.1166382	0.10
302.4351196	0.11
309.3416748	0.07
322.9626770	0.11
329.3666382	0.39
378.2629395	0.10
392.6568604	0.10
412.7911987	0.05
425.3969116	0.08
426.4158325	0.08
446.2687988	0.06
449.8897705	0.10
451.3576050	0.05
465.0281982	0.22
471.4086304	6.44
472.2352295	0.77
485.3207397	0.10
487.2803345	0.04
513.2897339	0.08
525.4693604	0.15
527.3278809	0.06
535.7379761	0.08
546.1177979	0.05
551.6884766	0.09
555.5465698	0.06
568.5815430	0.20
571.2221680	0.37
585.3082886	0.17
586.6445923	0.08
588.8661499	0.14
615.4688110	11.18
616.5811157	1.48
625.3164673	0.22
633.4039307	100.00
634.4049683	16.76
635.1337280	0.20
648.5709839	0.04
649.5115967	0.13
654.4694214	0.14
675.4751587	0.41
676.5654907	0.05
679.4970093	0.04
705.6870728	0.07
707.1251831	0.17
717.1182251	0.05
731.2694702	0.05
733.7062378	0.14
734.7147827	0.56
735.5010376	0.21
737.3967896	0.12
749.2549438	0.62
759.7941284	0.13
763.2864990	0.16
765.6340942	0.19
766.7376709	0.10
776.2651978	0.10
777.3269043	3.27
778.3849487	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.21
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.0845795	0.35
221.123291	5.76
226.9481659	0.25
250.3823395	0.08
251.0058136	0.19
262.9653625	0.22
280.6577148	1.67
281.2709656	0.37
290.7685852	0.31
305.1282349	1.85
310.5332336	0.15
321.406311	0.20
323.0124512	4.82
330.145813	0.14
336.102417	0.32
340.9800415	31.62
383.1253662	100.00
385.206543	0.33
397.0521851	0.36
398.2362061	0.28
408.2529297	0.67
412.7625732	3.98
424.456665	0.56
425.310791	0.69
431.0745239	0.23
439.1729126	0.36
442.3783569	2.92
443.0450439	21.20
467.1862793	1.16
472.9367065	0.36
475.2357178	0.12
485.1330566	32.63
485.7724609	0.35
502.9313354	3.16
517.2192993	0.15
545.3478394	0.89
546.90625	0.23
575.1278076	0.07
601.2247925	0.18
647.1757812	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	861.3932
Annotation	Holothurin B2
Peak:m/z	Relative Intensity
303.0655518	0.07
357.7945862	0.04
371.2974243	0.04
376.6366577	0.06
380.2211304	0.03
392.1376953	0.03
423.6906738	0.24
424.3976440	0.13
439.2019043	0.22
441.5392456	0.22
447.3270874	0.18
451.3164062	0.06
451.9378662	0.03
453.6797485	0.02
454.3787231	0.02
467.1187134	0.07
469.4108887	1.35
470.3329468	1.01
471.5597534	0.12
482.2819824	0.04
483.4128418	0.10
487.3743896	0.29
488.4041748	0.17
491.4437866	0.11
494.4105225	0.13
495.1843872	0.18
502.6802368	0.04
507.4731445	0.20
509.1592407	0.12
511.2799683	0.11
521.5894775	0.38
523.2233887	0.18
529.4688721	0.06
536.4721680	0.05
552.4730835	0.03
553.6178589	0.11
555.1094360	0.10
558.4567871	0.06
564.4755249	0.12
565.3182373	0.09
567.3527222	12.57
568.4077759	4.26
569.3372192	1.36
570.5097046	0.30
575.6218872	0.05
576.6126709	0.03
579.0249634	0.04
579.6378784	0.15
583.3967896	2.63
584.4951782	0.84
585.5403442	0.31
599.5565186	0.03
601.4146729	23.12
602.5439453	9.30
603.4935303	1.81
606.2814331	0.06
609.1336060	0.02
616.2987671	0.07
617.4873047	0.13
619.4680176	7.36
620.4590454	3.11
621.3662720	0.32
623.4771118	0.13
627.4793701	0.04
633.3742065	0.05
643.3944092	0.26
644.3209839	0.13
650.3342896	0.04
655.5397949	0.15
656.2688599	0.04
667.4844971	0.64
668.4522095	0.19
680.4320068	0.05
681.5706177	0.04
683.6778564	0.16
686.2430420	0.08
699.3904419	14.52
700.4171753	5.99
701.4400024	1.13
713.4028931	0.07
719.8288574	0.03
733.4387817	0.08
741.4246216	0.06
742.4316406	0.05
745.6355591	0.60
746.4193726	0.14
747.7921753	0.02
749.4142456	0.12
755.2578735	0.27
756.2592163	0.06
763.4518433	100.00
764.4531860	48.04
765.4793091	7.25
766.1002197	0.04
767.3638306	0.02
768.8201294	0.05
771.3020020	0.04
775.3087769	0.01
778.9307861	0.04
781.4454346	49.07
782.4304199	23.97
783.5470581	3.76
797.3519897	0.09
801.5388184	0.06
802.4592285	0.33
816.2128296	0.02
817.3591919	3.51
818.3746338	2.03
819.4536743	0.95
825.6537476	0.06
826.4417114	0.07
829.0757446	0.11
831.1356201	1.21
832.3367310	1.21
833.1984253	0.37
843.2557373	0.17
844.2678223	0.28
845.4680786	0.07
847.5076294	0.02
861.2255249	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.2894
Annotation	3b,4b,7a,12a-Tetrahydroxy-5b-cholanoic acid
Peak:m/z	Relative Intensity
120.0975189	0.07
121.1734467	0.27
122.9748993	0.51
124.9530640	0.52
127.0042877	0.40
128.9190826	1.05
130.9864044	1.15
132.0266571	0.24
133.3209991	0.12
134.8710632	1.12
136.9907379	0.28
138.1701202	0.22
140.0900726	0.25
141.1312866	0.30
143.0592041	1.34
145.0507507	2.81
147.1073303	1.85
149.1100159	2.20
151.0754242	1.28
155.0395660	0.70
156.9707642	2.27
158.0478363	0.66
158.9786377	1.41
160.9828491	2.17
163.1139832	1.12
164.6416321	0.87
165.2756958	0.67
166.1420898	0.09
167.0399933	0.48
169.0829010	1.71
170.0521851	0.27
171.1371613	1.10
173.1394653	1.40
174.0075684	0.10
174.9794312	2.74
176.0595703	0.29
177.2138062	1.88
178.2731934	0.43
179.1773071	1.02
181.0480042	1.14
183.0712891	0.57
183.8503723	0.21
184.9043427	1.34
187.0327454	1.70
189.0563049	1.19
189.6802063	0.05
191.1946411	0.17
193.1818542	0.39
195.1785278	1.18
197.0358124	1.53
199.1127625	2.43
201.0614624	2.11
202.5430908	0.25
203.3114929	1.46
205.0998383	1.17
205.8921509	0.10
207.4698486	0.54
209.0984039	0.89
211.2186584	2.14
213.2432556	1.07
215.1353455	4.05
217.0442200	1.67
219.1724854	0.41
220.4940186	0.09
221.1553345	0.97
223.0034027	0.83
225.2388000	0.87
227.1254730	1.26
229.2118835	3.83
231.1135864	1.18
233.0891724	0.85
235.1490784	1.74
236.9537964	1.02
237.9790344	0.07
239.0135498	2.48
241.4548645	0.64
242.5400085	0.79
243.1894836	11.05
245.1670227	4.91
247.1309204	1.33
249.1010437	0.71
251.2483215	0.50
253.1081543	0.84
255.1970215	1.00
257.2339172	1.96
259.0726013	1.46
261.1561279	24.99
263.1502075	17.03
265.2368164	1.29
266.6613159	0.14
267.2820435	0.57
268.1986389	0.21
269.1485901	0.59
271.1734924	2.76
273.2277832	2.26
275.0351868	1.56
276.1260681	0.21
277.1732178	4.15
279.3322449	6.11
281.2355652	0.84
283.4039917	0.52
285.0759277	2.66
287.3270569	1.95
289.1766968	3.91
289.8605652	0.23
291.2451782	8.93
293.2718201	5.85
295.1471863	1.73
297.3356323	1.21
299.2771606	1.06
300.2773438	0.19
301.2073975	1.12
303.2162476	3.70
305.2605896	7.00
306.9484253	1.23
309.2579956	1.04
310.0837402	0.20
311.2539062	2.20
313.2566833	2.50
315.1983337	4.44
317.2744141	5.38
317.9076538	0.64
319.2864990	0.62
321.1748047	1.10
323.2617188	6.12
325.2471924	1.89
327.3224182	0.48
329.2988586	5.90
331.3159180	17.85
333.1849670	2.19
335.1635132	3.62
337.0152893	0.31
339.3142090	1.56
341.3254089	27.54
343.2667847	3.67
344.2186890	0.34
345.3025818	1.31
347.2617493	14.42
348.4082336	0.25
349.2363281	0.06
353.3182983	15.18
354.2176208	0.14
355.5133057	0.06
359.2516785	100.00
361.1686707	1.57
365.1397400	1.35
369.2492981	0.59
371.3108826	46.75
376.5873718	0.23
377.2509460	3.14
379.2376404	0.47
380.2304993	0.07
381.4890747	0.74
382.3452148	0.14
383.9170227	0.09
389.2283020	57.44
395.0751648	0.27
397.1207275	0.16
403.2367249	0.06
407.2571106	83.66
408.3999329	0.93
409.1184692	0.12
413.3511353	0.40
415.2166443	0.75
416.4781494	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1451
Annotation	Rutine
Peak:m/z	Relative Intensity
173.2051697	0.01
176.0154724	0.03
177.0918884	0.02
178.9949646	2.04
179.9283905	0.16
181.1137848	0.04
182.1156921	0.09
182.9098358	0.10
183.8759003	0.04
185.0736694	0.01
187.052887	0.19
188.9835052	0.19
189.9400482	0.02
191.0471649	0.26
192.2698822	0.16
192.9511719	0.15
197.0578918	0.10
198.0799103	0.11
198.8286743	0.04
201.1265564	0.10
202.9698334	0.15
205.0585327	0.01
206.9790802	0.11
210.9188385	0.17
212.0679932	0.11
213.0569153	0.21
214.5298462	0.15
215.2198181	0.10
217.0328369	0.31
218.1867828	0.07
219.1509399	0.05
221.1406708	0.11
222.086853	0.01
225.9979401	0.15
227.1417542	0.25
228.0848541	0.16
228.9754486	0.46
230.0624695	0.11
232.2640533	0.03
232.9521942	0.06
237.2185669	0.03
239.1984406	0.26
240.245575	0.14
242.0909424	0.05
243.1413422	0.40
245.1863708	0.05
246.2637177	0.09
247.1957092	0.22
249.0957489	0.02
252.1207886	0.04
253.0730286	0.16
254.2115021	0.32
255.0619659	2.57
256.0194702	1.02
257.0551453	0.78
258.0039978	0.28
259.8120728	0.01
266.415863	0.05
267.0872192	0.03
269.2820435	0.23
271.0795898	4.47
271.9929199	0.45
273.0826111	1.05
274.1489868	0.13
276.1338501	0.02
277.4145813	0.03
279.9168701	0.02
281.1879883	0.07
282.0102539	0.04
283.0657959	0.61
284.0741577	0.08
285.0837402	0.41
287.4190674	0.02
295.9830322	0.24
297.0699463	0.66
298.3591919	0.20
299.4055786	2.16
300.0234375	26.25
301.0283203	100.00
302.1340942	15.46
303.0728149	0.04
306.1086426	0.03
311.178894	0.14
312.9806213	0.79
314.1396484	0.04
314.9325867	0.30
316.3026733	0.02
323.9577942	0.10
325.1690369	0.22
326.2774048	0.08
327.2437744	0.22
328.020874	0.04
329.1137085	0.05
330.3471069	0.02
332.15979	0.05
337.2976685	0.11
338.100647	0.04
343.0910034	6.38
344.1213379	1.66
353.1726074	0.05
355.1444092	0.36
367.0400391	0.02
369.1870117	0.11
371.0150757	0.04
373.0723267	0.62
381.3551025	0.12
383.1392212	0.02
386.2424927	0.04
405.9644775	0.08
409.2647705	0.13
409.9233398	0.03
411.2896729	0.05
418.9974976	0.02
427.0856323	0.29
429.4083252	0.21
430.4146118	0.01
431.0513916	0.03
437.3068237	0.02
439.0195312	0.01
440.218689	0.02
444.805542	0.46
446.2155762	0.05
447.2267456	0.24
457.4293823	0.27
458.3411865	0.09
461.8969116	0.04
463.1287842	0.34
464.0906982	0.11
465.12146	0.70
466.0853882	0.03
467.0530396	0.04
469.2401733	0.03
471.1454468	0.08
473.4043579	0.03
475.0159302	0.11
481.1647339	0.03
483.3163452	0.01
484.2590332	0.05
487.3345947	0.03
488.2796021	0.09
489.1098022	0.08
490.1401978	0.07
496.109375	0.02
499.12146	0.12
500.0532837	0.09
505.4769287	0.04
518.9921265	0.13
525.1791992	0.07
530.9716187	0.06
538.0545044	0.03
542.3890381	0.09
548.1886597	0.30
549.2141724	0.17
551.1355591	0.02
563.1727905	0.08
564.0806274	0.40
565.2544556	0.07
566.3210449	0.13
568.5366211	0.07
574.2893066	0.09
577.6035156	0.06
580.413147	0.13
581.3200073	0.06
582.1417847	0.05
587.1193237	0.15
591.1846313	2.06
592.2030029	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.3125
Annotation	Pipeloside A
Peak:m/z	Relative Intensity
194.8420410	0.18
224.9615936	0.09
228.1638641	0.07
233.5180511	0.07
236.3772583	0.13
240.9275818	0.07
249.2372437	0.12
259.1508179	0.06
278.1907654	0.65
279.3880615	2.18
280.1640015	0.09
283.4487915	0.34
305.4203186	0.15
307.1153564	0.61
307.9002686	0.09
316.8770142	0.19
318.0585327	0.13
339.2098999	0.15
343.3441162	0.09
357.3070679	0.23
369.0703735	0.46
391.4067993	0.09
394.9012451	0.10
413.2700806	0.50
414.1190186	0.37
415.2637329	0.93
416.1638794	0.41
431.4580688	0.11
432.4543457	0.48
433.2679443	0.48
440.1788940	0.17
468.8491821	0.05
476.6265869	0.16
511.3165283	0.15
519.4822388	0.83
532.5732422	0.07
538.4244995	0.12
541.5865479	0.16
549.3892212	0.10
550.5010986	0.11
553.2898560	0.33
579.3930054	0.07
597.1473999	0.14
606.1613159	0.12
609.3198242	0.34
617.5437012	0.09
619.6390991	0.20
623.6232300	0.10
631.2954712	0.38
632.0217285	0.17
634.6072388	0.99
635.4057007	0.63
644.7880249	0.24
649.1053467	0.79
651.3356323	100.00
652.0064697	0.32
663.0414429	0.10
664.3737183	0.42
666.9448242	0.15
671.8353882	0.44
675.7548218	0.08
677.3966675	0.63
686.5248413	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.14
Annotation	N6-Carbamoyl-L-threonyladenosine
Peak:m/z	Relative Intensity
119.8117371	0.08
121.5404816	0.05
126.9360199	0.11
135.8146362	0.35
146.1929016	0.13
149.1438599	0.03
149.8959045	0.21
162.0293884	0.87
163.0285950	0.05
188.2642670	0.11
189.2331543	0.03
199.2751770	0.04
204.9646149	0.49
205.9586182	0.21
213.2728882	0.03
214.9972687	0.05
233.3489990	0.07
237.7368469	0.05
251.0052185	0.27
251.9913940	0.19
266.4447327	0.03
268.1005859	2.94
270.1418762	0.15
281.0345459	100.00
289.4866333	0.04
293.9567261	0.69
297.1248474	0.06
298.0778809	0.15
299.8964233	0.13
300.9465027	0.12
309.0498352	0.14
325.0623169	0.06
326.1055908	0.21
334.2446594	0.15
334.9666748	0.16
337.4791260	0.06
338.2756348	0.08
339.7659912	0.10
343.1038818	0.13
346.2867126	0.12
349.0875244	0.05
350.4100647	0.15
367.0843201	0.74
372.0515747	0.13
377.2196960	0.34
381.3997498	0.04
391.2845154	0.05
394.1280518	0.53
395.0369568	0.73
396.0957947	0.47
404.5475464	0.14
413.9786072	0.04
422.9130554	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1032
Annotation	Toringin
Peak:m/z	Relative Intensity
131.1480103	0.01
136.9236145	0.02
145.3302917	0.03
148.9733734	0.05
162.8671722	0.03
179.1778564	0.04
186.7205658	0.04
204.0938721	0.01
231.7446899	0.03
233.2031555	0.02
235.1175232	0.15
247.2683411	0.03
253.3507996	0.13
267.0688477	0.80
271.0509338	0.02
272.9087524	0.03
275.3309326	0.03
277.3557129	0.18
279.3316040	0.04
281.1600952	0.02
295.0521851	100.00
296.0571289	0.21
297.1359863	0.02
299.2771912	0.02
301.2190552	0.05
302.6041870	0.04
307.2621765	0.05
309.0109558	0.02
310.1516724	0.01
312.1784058	0.04
313.2152710	0.03
319.0044556	0.03
321.4009399	0.02
323.0816650	0.02
325.0992432	2.37
337.1303406	0.28
339.2968750	0.03
340.2195740	0.09
341.1289673	0.06
349.4004517	0.03
354.3226929	0.20
355.1517334	0.12
356.3197021	0.02
361.2582092	0.04
367.2901917	0.07
368.9911194	0.07
370.1565857	0.04
371.2258606	0.18
373.2193298	0.13
377.9956360	0.03
378.9866943	0.03
383.2987976	0.02
385.1431274	0.04
386.3838196	0.10
387.2778320	0.03
394.8777466	0.03
396.2550354	0.09
397.2139282	0.39
398.4212036	0.03
400.3966370	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	945.292
Annotation	Unknow
Peak:m/z	Relative Intensity
502.9539795	0.19
545.0246582	0.04
647.8805542	0.20
787.6469727	0.19
808.1683960	0.06
827.2084351	100.00
828.3895874	0.18
829.6481323	0.08
881.5059204	0.07
926.9744263	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5169
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
240.9421082	7.59
259.0592041	0.85
261.5484619	0.36
277.4213562	0.26
279.2994080	63.71
281.3896790	2.33
297.0299683	13.30
311.1273804	0.41
315.1455688	2.07
349.4335022	0.42
415.2373657	53.84
417.3988037	1.32
433.2251587	0.86
435.1674805	0.24
485.4456177	0.32
501.2178955	0.22
518.3400879	0.47
521.0026855	0.19
575.2708740	0.49
577.2374268	100.00
577.8770752	0.85
578.6228027	0.46
579.3992310	0.66
595.3877563	17.80
597.3067017	0.49
689.8571167	0.29
700.7355957	0.33
713.3412476	0.19
725.1362915	0.15
733.6299438	0.42
765.4512329	0.37
778.6817017	0.22
785.5009155	0.26
797.4735718	0.35
810.5803833	0.40
811.5339355	0.16
825.1036377	0.20
836.7687988	0.57
839.2239990	0.21
857.2142944	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.29
Annotation	Assamsaponin I
Peak:m/z	Relative Intensity
175.9667969	0.12
176.9902039	0.09
182.2436676	0.10
187.0639954	0.39
188.1806793	0.07
192.9541931	15.12
194.0621033	2.63
195.1173706	0.23
196.2364960	0.08
200.1141205	0.05
212.9171448	0.26
213.8948975	0.17
215.0426636	1.33
216.1905212	0.52
233.0592651	2.66
234.0350342	0.66
241.1122131	0.04
242.1136475	0.18
251.2793579	0.05
259.0990906	0.17
269.1270142	0.07
273.1125488	0.06
274.1288452	0.30
285.9088135	0.14
287.1082458	0.05
291.1826782	1.23
292.3173828	0.49
304.0043640	1.40
305.2846069	0.45
305.9434814	0.03
309.1438599	0.56
309.8877258	0.04
322.0647583	100.00
323.0901184	32.91
337.1901245	0.05
383.4940796	0.04
384.1900024	0.10
394.4511719	0.07
395.1799316	0.06
398.0281982	0.11
401.2503052	0.09
409.0288696	0.07
413.1068115	0.02
418.9574585	0.01
438.2312622	0.05
442.3932495	0.03
444.8972168	0.03
449.0870361	0.10
459.4148560	0.04
465.1348267	0.15
466.1877441	0.10
469.3588867	0.25
477.1082153	0.41
483.1506348	0.35
484.3634644	0.32
501.0581055	1.74
502.1558228	0.66
514.8606567	0.14
515.4708252	0.06
516.1169434	0.02
517.3143311	0.12
526.7145386	0.22
535.3222656	0.11
550.0686646	0.35
557.7981567	0.13
558.4801025	0.09
559.2383423	0.04
571.0767822	0.17
572.1615601	0.09
573.0639038	0.07
577.5025635	0.07
581.3138428	0.09
584.7268677	0.07
587.4917603	0.27
593.0654297	0.01
594.3238525	0.04
597.1792603	0.11
599.2870483	0.15
612.2669067	0.06
613.3154907	0.28
631.0523071	0.02
713.5230103	0.06
755.3604126	0.16
790.9282837	0.04
891.9404297	0.04
953.1084595	0.08
1077.6491700	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.17
Annotation	Secologanin dimethyl acetal
Peak:m/z	Relative Intensity
127.3207550	0.03
130.9541931	0.15
135.0708923	0.07
138.9617920	0.22
142.8506012	0.06
146.9132385	0.02
153.2456207	0.03
156.9918518	0.05
159.0427246	0.02
160.9522552	0.19
174.9127502	0.15
178.6187134	0.12
179.2741699	0.02
183.0710144	1.49
189.2547913	0.07
192.3437500	0.03
205.1454468	0.12
219.4024353	0.03
223.1188049	0.04
225.1512909	0.08
227.0922394	0.34
229.1785889	0.03
230.0833588	0.02
230.9755554	0.61
235.1085205	0.14
241.2581787	0.06
243.6834106	0.03
249.0255432	11.48
253.2280579	0.46
255.3264160	0.06
259.0920410	0.02
267.0350952	10.00
271.1050110	3.22
285.3121948	0.04
286.9656372	0.05
289.3216248	0.01
296.9906616	0.04
309.3023071	0.02
310.9866333	2.81
312.1576538	8.47
313.1066895	100.00
320.1975098	0.26
321.1484985	0.19
323.9773560	0.05
325.1487732	0.17
328.8049316	0.03
341.1033936	0.41
343.0892029	19.30
343.9327393	0.06
353.0156860	0.02
353.7487183	0.08
355.1204834	0.63
356.2541504	0.08
357.0130005	0.22
360.8746338	0.04
371.3576965	0.07
372.3239746	0.56
373.1889954	1.19
379.2409668	0.12
384.5000610	0.16
385.1614685	0.85
385.7677307	0.03
387.1822815	1.52
389.3647156	0.07
390.2755432	0.37
391.3291931	0.11
396.9910889	0.95
397.5957336	0.02
403.1493530	0.30
413.2407837	0.05
414.1567688	0.34
415.1877747	7.06
418.1764221	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.08
Annotation	gamma-Glutamyl-S-methylcysteine sulfoxide
Peak:m/z	Relative Intensity
83.6962433	0.04
87.9611282	0.90
90.8373947	0.06
106.0923767	0.01
127.0999527	0.05
129.9138184	0.42
132.9161072	0.02
137.8963318	0.02
143.0690308	0.01
144.9286041	0.07
147.0743713	0.03
152.0253296	3.69
176.7107849	0.08
192.8386841	0.03
199.0365906	0.20
200.0290222	0.13
206.9732361	0.05
210.2678528	0.02
211.2083130	0.05
216.9932861	100.00
220.9299622	0.09
234.8941345	0.45
237.1945496	0.03
240.0008850	0.24
245.2719421	0.04
250.8595276	0.02
254.1612244	0.02
263.0150452	1.00
263.9617615	0.14
264.7142944	0.12
272.1341858	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.7286
Annotation	Unknow
Peak:m/z	Relative Intensity
136.0525513	1.48
137.0304260	0.56
146.0583038	0.16
147.0944519	2.44
163.1329956	0.06
164.2669220	0.60
164.9083252	7.74
165.9257202	0.16
174.2685394	0.22
175.0102234	0.35
181.9715271	41.65
182.9226379	0.66
191.1777039	0.86
203.0601501	0.15
207.0472107	0.30
211.1806641	0.49
215.5098572	0.19
220.8904724	0.38
225.2346497	0.13
229.2041931	0.38
233.0558777	0.21
236.0529938	4.79
239.0688171	0.99
245.2476196	0.54
249.0109863	0.20
254.7044067	1.17
256.2486877	0.07
258.8835144	0.38
262.9343872	0.89
265.2240295	0.29
265.8849792	0.09
271.0150757	0.12
272.8736267	1.92
277.0613708	0.23
281.0784912	3.22
282.3269958	0.88
283.0774536	0.12
291.1046143	0.63
294.0192566	0.55
296.9897156	0.40
299.3029785	0.88
305.2946472	0.64
308.0050049	0.27
309.1349487	1.81
315.0398560	0.29
319.3122559	0.18
325.2631836	0.21
330.3237305	0.41
340.5584106	0.46
347.3879700	0.44
356.1824341	1.08
357.4615173	0.10
359.9511414	0.14
361.9065857	0.17
364.1444702	0.11
367.3516541	0.20
372.1607666	0.20
375.5162964	0.69
378.3410950	2.58
379.2175598	0.59
379.9004211	0.14
381.0767822	0.10
384.9255676	1.27
389.0018921	0.72
389.9970703	0.42
395.3836670	0.15
401.3127747	0.14
402.4505310	0.10
403.0823059	0.17
404.2116394	0.76
407.0324707	0.37
410.2496643	1.91
413.0553894	0.14
418.3125305	0.20
418.9169922	0.32
419.7072754	0.47
420.4507446	0.09
423.9498596	2.48
425.0269470	0.37
426.9570007	0.15
433.1133728	0.22
435.2297058	0.08
435.8378906	0.58
436.6453247	0.33
438.7544861	0.36
444.2746887	1.86
445.0540161	0.53
449.0082092	0.44
457.6946106	8.46
458.6015320	2.96
460.2231750	0.19
462.1181335	1.15
463.1858215	0.75
464.7508240	0.34
466.7737122	25.07
467.4404602	4.63
468.5504456	0.16
470.2317200	3.83
471.3982849	1.64
472.0546265	1.99
473.2084045	0.15
487.0667114	0.19
491.2844543	4.79
492.3577271	0.08
498.9775085	0.28
517.3604736	0.96
537.0052490	1.36
538.0458984	0.74
569.4708252	0.35
586.8758545	0.22
604.8601074	0.07
608.9883423	0.48
609.6815796	0.38
618.2392578	0.66
630.7428589	0.26
636.3099365	0.33
644.3917847	0.22
645.2645264	0.58
663.1295776	0.82
664.1882935	0.93
668.0875854	0.27
680.2622681	9.20
681.2510376	2.67
681.9809570	0.64
689.5342407	0.14
697.3265991	6.48
698.4069214	0.99
733.2601929	0.52
750.2288818	1.13
751.2788696	6.15
752.3133545	2.80
761.3608398	1.13
762.2360229	0.49
763.3803711	0.40
765.4758301	0.12
779.3305664	100.00
780.3086548	26.35
798.6480103	0.49
799.5347290	0.99
800.4406128	0.73
825.5474243	0.96
847.3803711	1.22
861.2890625	8.92
862.2392578	4.71
862.9484253	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.507
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
214.0495605	0.73
251.375	0.43
255.245636	43.21
256.3419495	12.14
261.2195129	1.30
279.226532	100.00
280.2958679	23.19
327.4783936	0.44
341.35495	0.53
412.7403564	1.13
430.9889526	0.56
434.3562012	0.60
452.3154297	15.30
453.3245239	2.89
458.3721313	1.79
461.2058105	1.69
464.0375366	0.44
470.6168823	0.79
476.2622681	1.02
477.1205444	0.91
477.7719727	1.04
487.4906616	0.84
514.2266846	1.08
551.1998291	0.60
569.7094116	0.84
580.2529297	1.46
588.2584839	0.75
609.1289673	0.94
617.6772461	1.18
623.7904663	1.04
625.4616089	0.84
645.0307007	0.78
651.5336304	1.09
655.2479248	0.94
657.3208008	0.70
669.3610229	1.25
670.1636353	1.42
671.4104004	2.69
679.4840088	4.45
685.571228	2.66
697.4197388	25.06
698.390686	5.38
705.8205566	2.20
712.3136597	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
215.1231232	0.24
228.3709412	0.46
255.1608124	39.28
256.2713013	13.75
261.348114	0.80
264.0669556	0.29
268.9522705	0.31
279.2385254	100.00
280.2064819	21.67
303.0263672	0.58
309.2231445	0.18
311.3467712	0.14
354.9550171	0.49
359.3674316	0.09
378.2988892	0.25
386.2352905	0.31
395.3155518	0.10
419.2874146	0.21
434.2796021	1.21
435.3255005	0.18
452.3415527	15.13
453.2714844	3.41
457.8392944	0.74
476.3893433	2.28
477.3962402	1.30
485.1264038	0.63
489.3143921	0.15
513.3909302	0.18
517.0526123	0.80
551.6378784	0.44
553.3595581	5.43
567.479126	0.92
595.3737793	1.07
596.3432007	0.44
608.5490112	0.61
613.0778198	0.27
618.2175293	0.22
621.4785767	0.20
654.5275269	0.82
655.348877	0.43
666.5823975	0.74
669.1010132	0.43
670.6389771	0.55
679.3079834	0.62
680.7139893	0.31
685.2178345	0.33
697.3897095	3.94
698.7142334	0.77
701.5009766	0.15
706.4603882	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2237
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8773956	4.31
163.4900208	0.18
165.7409058	0.07
167.0681000	0.65
168.0556946	0.15
168.9903259	0.42
179.1011963	0.08
182.1433411	0.16
184.6588898	0.09
193.1011810	0.05
194.2171478	0.24
199.2422180	0.20
204.9822083	0.48
207.0866547	0.04
209.1429596	0.10
217.0616150	0.21
233.3656616	0.17
234.1488953	0.10
235.0686646	0.36
239.2609863	0.03
243.3556213	0.06
247.0025635	0.61
251.1981659	0.07
252.8647766	0.12
259.2131958	0.17
263.3406982	0.23
264.8812256	1.04
280.8727722	0.08
287.4445801	0.07
289.1183472	1.26
293.0260010	0.27
307.0705566	16.87
312.8253174	0.73
313.5969849	0.07
315.4415283	0.12
320.1436768	0.50
324.8936157	0.88
330.9631958	0.09
333.1892090	0.06
337.2799072	0.14
338.1365967	0.17
341.7223511	0.08
353.1578369	8.74
361.3540649	0.29
363.0196533	0.16
370.9861450	0.68
375.2651978	0.10
379.2520142	0.05
382.4713135	0.05
384.3062744	0.15
397.1978760	0.54
400.8439941	0.22
402.7758789	0.52
409.2777710	0.24
412.9921265	0.20
414.9620972	0.55
421.5739136	0.09
431.1576538	0.18
432.1838379	0.17
433.4581299	0.07
435.3064575	0.08
444.7348633	0.27
445.4689941	0.07
447.3253784	0.06
458.6393433	0.10
460.2461548	0.40
461.1366577	0.29
475.1134644	100.00
476.2375488	0.56
477.2116699	0.15
478.3500977	0.04
483.4296265	0.09
484.1088867	0.18
484.9510498	0.25
488.2620239	0.15
489.3245239	0.19
490.4742432	0.13
491.1254272	0.10
493.6584473	0.15
498.5651245	0.14
502.4050293	1.69
503.2276611	1.61
504.3023682	0.27
506.5042114	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	695.4025
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1296539	0.05
204.8526306	0.02
207.1155853	0.03
208.2485657	0.05
216.7911835	0.02
218.7745972	0.01
220.9832153	0.14
223.1152802	4.27
223.9323730	0.02
233.0455627	0.13
240.9709167	0.18
249.0139465	0.15
251.0345459	2.79
263.2291870	0.05
265.2322083	0.04
267.8759460	0.08
268.7398682	0.08
270.8891602	0.01
273.0779724	0.15
279.0967407	0.03
280.0753174	0.04
281.2457581	0.04
283.3586121	0.06
287.1837769	0.03
289.2318115	0.14
291.3049927	0.08
293.0879517	0.02
293.9756775	0.01
295.1846619	0.02
301.2717285	0.03
303.1524658	0.01
305.3839111	0.04
306.5608215	0.13
307.1886292	0.03
313.2074585	0.20
319.3796387	0.01
331.2523804	3.34
335.7384033	0.04
349.1769409	1.88
351.1430664	0.07
365.7374878	0.03
367.1767578	100.00
371.1954956	0.02
379.1108398	0.03
383.0134888	0.01
384.4554443	0.06
385.1312866	0.06
404.2065430	0.04
407.0082397	0.03
407.7713013	0.04
421.2094727	0.04
508.9960938	0.01
531.4641113	0.04
533.6422729	0.20
535.1683960	0.02
570.5564575	0.04
579.2439575	0.09
589.2175293	0.05
619.1147461	0.01
636.8756714	0.08
643.2993164	0.03
658.1819458	0.02
659.2578735	0.17
660.5459595	0.02
662.0933228	0.01
676.5796509	0.20
677.2880249	0.66
678.2615356	0.03
689.5991821	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.17
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9251404	0.63
119.0497208	1.55
123.9238739	0.17
125.1560364	0.18
130.9826355	1.10
142.9752197	1.57
144.9496765	0.96
147.1695557	0.39
148.7495422	1.01
160.9779510	0.88
163.0964661	100.00
164.2966003	0.21
178.7294312	0.81
181.2948456	0.21
183.0668030	0.46
189.0453796	0.68
191.0178223	0.16
200.8361511	0.36
207.0991058	7.04
209.1362305	2.96
221.3274384	0.12
223.1318665	0.13
225.1789246	2.63
239.0968628	0.36
243.3197327	0.28
245.2168274	0.14
249.1786194	0.61
267.0254822	0.07
275.8649902	0.24
281.2313843	0.11
286.9778442	0.39
297.3289185	0.34
307.3209229	0.17
316.4914551	0.23
339.1682129	0.49
341.0708008	1.90
343.1689453	2.17
357.1326904	0.10
357.9039001	0.12
359.3596497	0.18
366.9348755	0.40
369.2368469	25.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5069
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
227.3262634	0.24
255.1842804	39.73
256.263092	5.15
265.2442627	0.32
271.6817017	0.21
279.2336426	100.00
280.2525635	13.80
284.2090454	0.19
329.095459	0.53
337.9649048	0.60
345.2172852	0.13
347.2922974	0.51
352.9412231	0.39
390.8414307	0.10
405.3629761	0.26
409.1389771	0.29
419.2781982	0.17
434.336792	0.44
435.2232666	0.18
452.2428589	16.57
453.302063	4.92
458.4945679	0.69
470.3939209	0.49
476.3725586	1.98
477.2141724	0.47
487.4382324	0.11
526.2950439	0.36
537.5480347	0.27
540.4649048	0.43
551.4225464	0.34
553.5061035	0.54
571.6082764	0.17
595.2650757	1.03
597.9365845	0.44
634.0306396	0.40
641.7508545	0.61
647.1300659	0.27
651.7162476	0.30
656.5618896	0.38
669.2477417	0.83
671.3479004	0.53
679.2329102	1.27
684.9104614	1.58
696.8198853	1.89
697.4487915	4.64
698.6876831	0.17
699.3133545	0.62
699.9532471	0.24
703.4423218	0.14
705.9963989	0.36
716.534668	0.10
725.442627	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.2337
Annotation	Taxumairol Y
Peak:m/z	Relative Intensity
161.0967407	0.04
178.8814697	0.02
180.0218201	0.02
191.1829224	0.02
199.1389465	0.02
218.1627502	0.03
229.0304871	0.03
271.0273132	0.01
281.0821533	0.02
285.1149292	0.02
292.0444031	0.01
301.5974121	0.05
315.0979614	0.05
316.3129883	0.38
318.3517456	0.04
319.2722168	0.28
320.4515381	0.11
323.0841064	0.02
327.4560547	0.05
328.3203125	0.05
343.3013916	0.04
345.1035156	0.52
346.1512451	0.37
363.2397461	100.00
364.2651367	67.00
369.9689941	0.04
377.1036987	0.09
377.9859009	0.04
380.4298706	0.04
405.1990967	12.69
406.2205200	8.37
406.9883423	0.03
416.9705811	0.05
430.0162964	0.04
432.9265747	0.07
435.3826904	0.04
436.2821045	0.04
441.6522217	0.02
448.5244141	0.04
450.0822144	0.04
450.7883911	0.04
452.2175903	0.04
454.1574097	0.09
455.1278687	0.06
461.2834473	0.01
462.1647339	0.10
463.5083008	0.02
465.2855835	0.15
466.0283203	0.24
472.3207397	0.02
477.6920776	0.09
479.2278442	0.07
480.1548462	0.10
481.9441528	0.41
489.9987183	0.07
493.2439575	0.12
494.2648315	0.30
499.0623169	0.07
507.2999268	0.19
508.1755981	0.17
511.6240845	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	Galactotriose
Peak:m/z	Relative Intensity
160.9714050	0.15
179.0103455	1.16
221.1312866	0.44
250.7171783	0.03
280.8997803	0.14
305.0668030	0.05
311.0214844	0.07
323.1279907	0.33
341.0234985	2.02
359.3331909	0.02
377.1189575	11.03
441.3391724	0.08
485.2494507	0.20
503.1729736	100.00
541.2310791	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	827.2665
Annotation	Lantanose A
Peak:m/z	Relative Intensity
250.9030609	0.04
262.2811279	0.10
280.9398193	0.34
287.2036133	0.14
303.5181274	0.03
305.0635376	0.09
309.3172302	0.06
310.9407654	0.29
312.2233276	0.05
320.7113342	0.03
323.1389465	1.72
324.0371704	0.40
340.9349976	16.45
342.0901489	1.70
365.1034546	1.23
366.3085938	0.18
383.1399536	19.69
384.0462646	3.12
384.6705933	0.01
406.9456177	0.03
412.1123047	0.15
412.7813721	2.95
414.1226807	0.22
424.6508789	0.16
425.6284790	0.02
426.5045166	0.03
442.8942871	18.63
443.9193726	3.38
449.4047241	0.08
450.5498657	0.08
452.9482422	0.13
454.2230225	0.03
455.2640991	0.05
456.0555420	0.10
467.2876587	0.13
467.9899902	0.05
473.0886230	0.36
474.2174072	0.12
483.3492432	0.06
485.1463623	4.60
486.2614136	0.88
502.9735718	18.84
504.0808105	2.85
509.7705688	0.17
527.1879272	0.13
545.1621704	100.00
546.2230225	24.69
569.0542603	0.33
569.9371338	0.64
573.4179077	0.22
574.9650879	0.15
587.1168823	2.64
588.1300659	0.54
599.2525635	0.06
604.9125366	2.44
606.0540161	0.16
611.3627319	0.14
629.1883545	0.54
647.1657104	6.12
648.2116089	2.10
664.9804077	0.51
666.1720581	0.19
707.2033081	2.11
708.2573853	0.26
809.2045288	0.29
810.1384888	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.3123
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0337677	0.15
248.8857117	0.17
262.0740967	0.21
265.4890137	0.23
270.3416748	0.33
339.4456787	0.10
343.3550415	0.37
367.2693481	0.38
373.3695068	0.10
374.2850952	0.49
375.3320923	0.08
384.8305664	0.26
386.2713013	0.35
387.1080933	0.17
401.5424194	0.16
403.3321533	0.20
409.2807617	0.13
423.3024902	0.32
426.9389038	0.10
428.1574097	0.47
430.0679932	0.09
447.4463501	0.21
454.9217529	0.06
458.2331543	0.12
465.5434570	0.16
470.0675049	0.19
482.9888306	0.21
487.1912231	0.43
501.2892456	100.00
502.1077881	0.11
503.2678833	1.13
504.2706909	0.70
509.3913574	0.39
511.2271118	83.83
511.8400269	0.20
525.3214722	0.56
529.0373535	1.23
529.6914673	0.07
532.2876587	0.09
537.6209717	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	584.3361
Annotation	Shearinine F
Peak:m/z	Relative Intensity
169.1603394	0.05
172.3023682	0.14
175.0378418	0.03
175.9973602	0.16
177.2522125	0.05
182.1659088	0.13
184.0943604	0.54
190.9663086	0.05
191.9939728	0.11
192.8578796	0.35
195.0864868	0.06
199.3304291	0.08
206.2115021	0.05
214.8322296	0.64
223.1274719	0.05
233.4171753	0.10
238.8536682	0.06
249.4638367	0.04
259.2845459	0.29
271.2555542	0.03
275.3787231	0.03
276.2064209	0.06
286.0032959	0.03
290.9180908	0.25
304.1245728	0.79
311.3137207	0.08
312.3778687	0.10
321.1809692	0.27
322.2387695	0.77
323.1717529	0.08
324.2606812	0.04
327.2974854	0.10
330.5906982	0.32
331.3796997	0.29
336.5440674	0.06
338.2164307	3.96
342.3899536	0.03
348.4801025	0.06
356.3344727	0.12
360.3026733	0.08
366.3157959	5.03
385.9760742	0.19
394.5519409	0.31
396.1489868	0.86
403.4218140	0.32
404.4775391	0.27
407.1630249	0.07
414.2327881	0.06
415.1986084	0.10
419.1528931	0.36
420.3731689	0.31
420.9943237	0.09
426.4218140	0.24
433.1934814	0.04
437.3255005	100.00
437.9329834	0.14
439.3890381	0.05
441.3536377	0.10
443.2188110	0.06
449.3219604	0.16
451.3150635	0.30
455.2166138	69.68
456.6480713	0.06
460.4852905	0.07
464.7854614	0.09
467.1435547	0.09
470.9847412	0.08
477.3859863	0.07
485.1911011	0.20
492.3167114	0.10
495.2493896	3.27
499.2091675	0.07
501.2681274	0.17
505.3727417	0.16
509.7532349	1.38
510.4515381	0.05
511.1761475	0.06
518.4732666	0.42
519.7407227	0.24
523.6721191	0.35
527.5742798	0.11
529.0687866	0.21
537.9929810	0.17
546.2799683	0.19
547.2294312	0.28
548.3247070	0.46
561.1529541	0.11
564.0115356	0.17
565.3840942	1.03
566.2877808	5.15
567.4535522	0.60
574.7911987	1.10
584.4680786	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Isovitexin
Peak:m/z	Relative Intensity
190.9184265	0.02
215.0501556	0.03
217.1931763	0.04
238.9626465	0.01
243.1433411	0.01
262.9908752	0.01
269.0527039	0.24
283.0540466	0.44
286.8244629	0.01
293.051178	0.05
295.0004883	0.05
299.2237549	0.02
309.0548706	0.06
311.0558167	100.00
312.1352234	0.24
321.1294861	0.10
323.1357422	0.36
325.4124146	0.03
329.0377197	0.03
337.2043152	0.10
339.045929	0.02
341.0619507	13.08
342.3156128	0.06
349.0971069	0.03
351.0906067	0.11
353.0577698	0.60
355.0800476	0.44
365.2454834	0.10
367.1456909	0.05
369.3266296	0.02
371.1139221	0.35
377.0989075	0.25
383.0584412	0.20
383.6789856	0.05
385.1765747	0.05
395.2099915	0.41
413.1960449	1.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5163
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
241.0212402	11.65
242.1414185	0.19
258.9855957	0.69
261.4373169	0.52
277.2591248	0.48
279.2378235	56.13
291.2042542	0.22
296.9883728	10.74
315.1121826	1.68
415.2589722	53.13
431.1374512	0.16
433.3066406	2.54
480.9677734	0.22
485.6007690	0.62
503.4231567	0.84
520.8653564	0.27
521.5854492	0.14
561.3350830	0.27
577.3306274	100.00
579.2422485	1.53
595.3981323	18.02
597.7924194	0.19
603.3897095	0.35
607.3154907	0.34
695.2814331	1.81
697.6235962	0.19
707.3444214	0.38
778.6515503	0.12
792.5022583	1.27
796.4827271	2.36
797.3064575	0.52
801.0419312	0.10
839.2756348	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.1859
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
117.8919525	0.28
130.1789246	0.01
131.9090576	0.04
144.0352783	0.23
146.0497742	2.25
159.0117493	0.10
165.8773193	0.03
170.0895691	0.17
187.9783630	28.43
204.9769592	100.00
205.5915527	0.16
245.1396484	0.01
251.8067322	0.06
262.0277100	0.01
267.2843018	0.06
272.9976196	0.02
287.3024292	0.01
319.1365967	0.01
329.9624634	0.11
346.3107910	0.06
348.6918945	0.01
355.3676758	0.08
363.7805481	0.09
364.9105835	0.09
366.4299011	0.02
373.3028259	0.01
374.1241760	0.01
376.4684753	0.04
380.1991577	0.02
383.5114746	0.05
391.1336060	0.15
392.3149109	0.13
400.2780457	0.04
409.2420959	0.22
410.1435242	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.9244
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9033813	0.11
272.9763489	0.01
357.9854736	0.11
358.8160400	0.34
370.7160645	0.05
376.0132141	0.04
382.8244324	0.04
386.0964966	0.05
389.0824890	0.09
399.0492249	0.17
399.9809875	0.07
400.6969910	0.04
401.9114990	0.06
405.0816956	0.03
414.8780823	0.19
425.1192017	0.08
426.9241028	100.00
428.8416138	2.17
429.8277893	0.03
443.0776367	0.04
445.0025330	0.26
454.9986572	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.13
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
71.9669189	13.51
72.6770554	0.02
79.1222382	0.02
80.9415588	0.03
90.1207504	0.10
92.9632568	0.06
98.9357910	0.02
115.1314087	0.15
117.8994293	100.00
118.7217560	0.10
120.0516052	0.04
120.8093109	0.06
126.5262604	0.07
130.0533752	1.41
131.0629883	0.16
132.9604797	0.04
147.9976044	1.44
152.7760162	0.08
155.9946899	0.14
157.2356873	0.03
158.8450012	0.13
160.5924225	0.08
163.0168915	0.05
164.0961761	0.03
170.3684235	0.11
171.0464935	0.08
173.9886627	0.12
180.8361206	0.14
184.0762787	5.52
187.3553009	0.03
191.1756439	0.03
198.8458252	0.18
200.8613739	1.63
201.9635773	0.11
205.7320251	0.45
210.3258362	0.06
210.9340363	0.57
214.9210968	0.14
219.2631989	0.10
226.5368652	0.06
229.0928345	9.41
230.0540161	32.00
230.8848267	0.42
234.7450562	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	680.8962
Annotation	Unknow
Peak:m/z	Relative Intensity
220.9761658	0.08
221.9783478	0.07
269.1372986	0.09
270.8938599	0.32
272.9544373	0.35
303.1651611	0.09
311.6190796	0.07
312.8561707	1.16
313.8916626	0.05
314.8036194	0.45
316.9772949	0.04
321.2823486	0.07
337.1871643	0.30
338.8904114	0.11
341.7473145	0.17
347.2626953	0.05
351.8302612	0.05
356.8629150	16.82
358.2880859	0.59
370.0223999	0.07
371.1357422	0.08
376.3330078	0.17
383.5234375	0.22
384.4234619	0.35
385.5014038	0.05
387.0031128	0.22
389.0767822	0.14
398.5916138	0.14
400.3824463	2.54
400.9841309	14.12
413.0526123	0.07
443.8653564	0.67
444.5339355	0.12
447.0031738	0.05
450.9006348	0.11
454.0248413	0.06
457.0388794	0.14
457.9321289	0.03
470.8330688	0.25
472.5255127	0.23
473.2144775	0.31
475.0523682	0.07
477.6227417	0.05
485.9968872	0.11
486.8745117	0.52
488.1868896	11.25
488.7946777	100.00
489.6752319	0.41
490.9710693	8.25
499.2494507	0.08
504.3830566	0.14
506.3141479	0.08
517.7371216	0.18
527.9579468	0.15
529.7793579	0.06
531.2199707	0.05
534.5783081	0.07
541.6080933	0.03
543.8599243	0.45
548.6679077	0.34
549.9225464	0.06
551.7837524	0.19
562.9266968	0.60
563.7537231	0.15
575.7395630	0.19
577.0057983	1.07
581.7998657	0.19
582.9562988	0.11
583.9733887	0.58
585.4451294	0.88
591.1702271	0.19
592.9247437	2.44
594.6166992	0.07
610.3280640	0.04
612.3506470	0.03
619.2069092	0.10
631.9730835	0.54
634.9988403	0.21
635.8851929	0.49
636.9188843	0.39
645.0664673	0.02
657.1030884	0.08
661.1746216	0.46
662.1508179	1.11
662.8097534	2.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1081.5231
Annotation	AzIII
Peak:m/z	Relative Intensity
321.0112610	4.84
322.0486145	0.89
339.0546265	7.18
340.1789856	0.64
345.2447205	0.09
350.9656982	0.16
379.9565735	0.11
380.8775940	0.10
382.3900757	0.25
392.9913940	0.05
405.1632080	0.87
406.0833130	0.17
407.1298218	2.30
408.2213440	0.35
409.2412109	0.91
410.1180725	0.34
416.9226379	0.22
417.7770996	0.04
421.2940369	0.14
423.0888672	0.10
435.2420044	7.85
436.1026917	0.55
450.9329529	0.02
453.4252930	1.23
461.2113647	0.14
479.1195984	1.54
480.1009521	0.36
497.0970459	100.00
498.1293335	12.21
498.7588806	0.09
660.2823486	0.18
667.5045776	0.18
679.3945312	0.10
725.4782715	0.07
741.3850708	0.11
742.3452759	0.04
746.5913086	0.04
755.7324829	0.25
758.6862183	0.10
759.4471436	3.28
760.5197754	1.61
761.1579590	0.41
778.2987061	0.03
799.3157959	0.20
825.4570312	0.15
874.9232178	0.07
879.9447021	0.07
893.6369629	0.09
897.1024170	0.08
906.8955078	0.14
917.4370117	0.53
918.6385498	0.06
919.7111816	0.24
935.4534912	0.08
941.6684570	0.23
943.0356445	0.34
947.6478271	0.28
948.4801025	0.57
961.2800293	0.11
973.5418701	0.08
975.4429932	0.11
976.4670410	0.30
981.5029297	2.98
982.6997070	2.05
987.3187256	0.04
990.9573975	0.09
1002.3781740	0.07
1005.2675780	0.10
1007.3947750	0.14
1010.7127690	0.17
1017.4018550	0.07
1019.4925540	2.04
1020.5651860	1.56
1037.4545900	0.55
1038.6906740	0.52
1039.4216310	0.23
1040.5095210	0.10
1046.5125730	0.14
1063.4230960	10.77
1064.4333500	6.67
1065.1243900	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1189
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
112.8558502	0.08
118.8668289	0.01
123.0127106	0.89
129.1455078	0.03
136.0156860	0.39
150.8262634	0.31
153.0550842	5.46
158.9147644	0.02
161.0122070	0.34
177.0138092	0.17
178.9718933	0.02
186.0998535	0.05
191.0650940	0.01
193.1968536	0.15
195.0053406	100.00
209.0173340	0.03
219.1249695	0.11
237.0744629	2.19
242.9709167	0.07
266.0741577	0.06
267.1566467	0.15
269.4992676	0.06
281.1020813	0.03
293.2018433	0.03
294.3661194	0.17
296.2987061	0.12
296.9326477	0.45
308.1005249	0.02
309.2512207	0.08
311.0308228	0.19
313.2403564	0.19
327.3824158	0.15
337.8799438	0.03
339.2945557	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.2958
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
204.0270081	0.53
217.9954834	0.04
235.9870300	0.09
251.1795959	0.12
262.4629517	0.11
265.3413086	0.08
269.1114502	0.23
273.1934814	0.23
275.9673462	0.21
287.0971069	1.78
297.4879150	0.15
299.1136475	0.86
305.1344604	0.22
311.5981750	0.09
313.1684570	0.28
315.1898804	2.14
321.3516235	0.17
322.1635132	0.06
323.2315674	0.39
325.2293396	0.32
327.1549988	0.11
337.2011719	1.66
339.3607788	0.08
341.1343994	0.21
343.0380859	0.11
345.2781982	0.10
352.1804810	0.05
355.1118164	0.98
357.2696533	0.95
358.4358521	0.06
359.2254639	0.13
361.9902954	0.10
369.2853394	0.79
370.3925171	0.18
371.2328491	1.54
373.1853027	1.92
383.2474365	0.78
387.3220825	0.20
397.1965942	0.10
401.1255493	7.25
404.0003662	0.09
413.3047485	0.29
414.9715576	0.24
423.0147095	0.64
431.1106567	0.18
431.8947144	0.10
433.4153442	0.84
434.2350464	0.06
436.4746094	0.09
438.0404053	0.16
445.2322388	0.12
449.8325806	0.05
450.5084229	0.32
462.1168823	0.23
464.3493042	15.91
466.1524658	0.08
467.0855103	0.08
472.3778076	0.31
476.1157227	0.64
478.1441650	0.25
480.1213379	0.10
482.3110352	0.89
484.2682495	0.42
490.1003418	12.13
490.7155762	0.06
492.1807251	0.15
494.2131348	1.99
496.3535767	0.10
497.0980835	0.20
504.0507812	0.26
508.1217041	10.78
510.2579956	1.10
514.1119385	2.03
516.3345337	0.15
519.1769409	0.07
520.2856445	0.52
522.2343140	95.64
523.4205933	1.11
524.2134399	3.18
526.2139282	4.30
538.1719360	0.23
540.0426025	0.80
542.2000122	0.35
543.7589722	0.06
551.3128052	0.20
553.8570557	0.15
583.3512573	0.63
585.5835571	0.32
587.2202759	2.70
593.7479858	0.10
598.3012695	0.43
600.8081665	0.33
603.1994019	4.67
611.1998901	8.15
615.2338867	0.79
616.9503174	0.39
619.2901001	5.76
625.1859131	0.14
629.1967163	13.18
630.2172241	0.37
633.0209961	0.09
635.2875366	0.08
641.0990601	0.05
643.1521606	65.48
643.8872070	0.39
647.2744751	100.00
656.1239624	0.18
661.1674194	18.17
662.2401123	1.22
663.6207275	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	846.1494
Annotation	Unknow
Peak:m/z	Relative Intensity
255.9178467	0.03
256.9088745	0.01
259.0377502	0.07
265.1999512	0.25
268.1483765	0.06
273.9672852	0.20
275.0783997	0.13
299.2647095	0.01
303.1608887	0.05
307.9830933	0.02
309.8894958	0.03
312.0307007	0.01
314.1687012	0.05
315.6965027	0.10
318.0204163	0.12
319.0656433	0.13
320.0045776	0.47
322.0120239	0.17
324.9863281	0.02
330.6817017	0.04
335.3373108	0.01
339.1890869	0.05
341.9078064	0.01
344.3253174	0.01
355.1696167	0.10
357.3098755	0.04
358.2261353	0.02
358.9127808	0.12
359.9537964	0.45
362.4200134	0.08
365.9729309	0.15
373.0026855	0.02
373.7382812	0.01
374.9342041	0.17
377.1021729	0.01
382.9837036	0.01
384.2349548	0.02
385.0543823	0.03
401.1422729	0.14
402.9813843	0.29
406.7647705	0.10
409.0151367	0.23
410.1555786	0.25
413.1962280	0.02
421.4804077	0.01
427.8332520	0.08
428.8763428	0.02
433.2705688	0.02
435.8425293	0.04
439.1088257	0.06
443.9343872	0.05
445.0473022	0.16
447.3830566	0.10
449.7679443	0.01
451.0399780	0.73
452.9933472	0.33
453.8932495	0.30
471.6016846	0.03
474.9476929	0.02
489.9714966	0.20
491.4764404	0.04
494.0121460	0.10
494.9104614	1.18
502.8136597	0.02
508.0642700	0.10
519.5269165	0.06
520.2844238	0.03
521.2587891	0.01
533.9175415	0.43
535.1441040	0.15
537.3433838	0.18
538.1005859	4.03
541.2049561	0.02
562.0980225	0.03
563.3928833	0.07
564.0983276	0.13
565.7174683	0.06
580.0189209	1.58
581.9420776	100.00
582.6126099	0.77
583.6433105	0.01
632.5832520	0.01
655.4696655	0.05
672.0399780	0.03
684.0300903	0.02
717.2390137	0.05
719.0498657	0.02
741.2739868	0.07
819.0110474	0.02
827.9218140	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	502.17
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0970001	0.05
197.0194092	0.02
252.3933563	0.01
264.1907349	0.02
272.2532043	0.03
282.0567017	0.06
287.7505493	0.02
299.3106689	0.19
299.9763794	0.03
308.3597412	0.02
313.1634521	0.04
317.0347900	0.05
322.1403503	0.06
334.1882935	0.04
340.3242798	0.06
347.1871338	0.01
349.1725464	0.05
350.1017456	0.08
352.2237549	0.10
355.0575562	0.04
356.1582947	0.03
358.4687805	0.08
370.8697815	0.03
376.0424194	0.09
378.0067749	0.01
379.2639771	0.02
382.1682739	1.91
393.8815918	0.06
397.3771973	0.08
398.5131531	0.01
402.0999451	0.02
406.2704773	1.64
412.2466125	0.33
415.1883240	0.02
424.0899658	0.06
426.2554016	0.05
427.3949890	0.02
430.0020142	0.09
431.4451599	0.03
436.2558289	1.72
437.2866211	0.14
441.0950012	0.01
448.3321228	0.31
448.9529114	0.01
455.2201843	0.01
456.1768494	0.04
457.2702332	0.07
458.0589600	0.09
466.2073669	3.43
467.0903931	0.05
470.1658325	0.09
470.8578186	0.10
471.8771667	0.04
475.8507690	0.05
484.1632690	100.00
485.1677551	0.04
488.5536194	0.10
492.7304382	0.15
493.4194031	0.07
497.1612244	0.07
514.1402588	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1427.668
Annotation	Unknow
Peak:m/z	Relative Intensity
457.3768311	0.31
525.1710205	0.07
620.5621948	0.60
621.5274658	0.08
638.8359985	0.08
687.4089966	0.22
688.3952637	0.05
696.4009399	0.20
697.6427002	0.07
715.5524902	0.08
730.7435913	0.08
733.4505615	2.48
734.3897095	3.99
735.3981323	1.39
747.0333252	0.16
751.5245361	0.41
752.6349487	0.84
753.6918945	0.05
763.5852661	0.24
764.7595215	0.62
781.6140137	0.03
782.7204590	0.24
783.6199951	0.09
784.5485840	0.29
812.7785645	0.09
831.1600952	0.13
833.4232788	0.19
849.6804199	0.10
859.3682251	0.10
863.2738037	0.04
864.7230225	0.19
877.5603638	0.15
878.7352295	0.43
879.4954834	0.22
882.3481445	0.04
888.7247314	0.26
895.5197754	3.40
896.5523682	5.99
897.5773926	1.14
909.7093506	0.03
914.3394775	2.08
915.5174561	0.33
925.5841064	0.05
926.4638672	0.68
932.8599854	0.12
939.5407715	0.04
940.5446777	0.05
943.5660400	0.18
944.5093994	0.16
945.5709229	0.06
959.3693848	0.05
967.5407715	0.13
979.4622803	0.06
984.7839355	0.06
994.4871826	0.14
995.6760254	0.11
1003.7734380	0.12
1007.7385250	0.14
1008.7047120	0.17
1010.3796390	0.11
1012.5720210	0.06
1024.8437500	0.28
1025.6485600	0.15
1026.5671390	0.86
1037.5117190	0.32
1038.5019530	0.08
1039.7868650	0.61
1040.5837400	0.83
1041.7286380	0.54
1042.5667720	3.43
1043.4975590	0.83
1057.4527590	1.28
1058.4946290	5.98
1059.5991210	1.43
1060.7689210	0.05
1061.4757080	0.17
1065.4599610	1.40
1066.4973140	2.71
1067.6887210	1.51
1076.4167480	0.65
1077.7497560	0.44
1083.0932620	0.09
1083.7818600	0.32
1084.4539790	0.65
1085.6291500	0.56
1086.6806640	0.06
1094.6301270	0.16
1101.9255370	0.96
1102.6547850	1.95
1103.5957030	1.24
1104.8673100	0.11
1105.7735600	0.07
1113.5985110	0.26
1119.2475590	0.11
1119.8518070	0.05
1120.6884770	2.32
1121.8022460	2.01
1131.2718510	0.07
1133.3306880	0.10
1154.6932370	0.06
1155.3249510	0.22
1167.5974120	0.05
1186.4670410	0.87
1187.5043950	0.25
1203.3991700	0.71
1204.5317380	7.45
1205.5233150	2.76
1219.4405520	0.86
1220.5075680	5.09
1221.6346440	1.73
1222.3579100	0.28
1223.2927250	0.14
1229.0959470	0.07
1230.2431640	0.15
1238.6481930	0.42
1239.5205080	0.52
1248.5561520	2.74
1249.6428220	1.25
1264.6171880	1.76
1265.6402590	2.39
1266.6328120	7.97
1267.5623780	2.59
1281.5368650	0.29
1282.5410160	4.57
1283.7294920	2.69
1290.5839840	0.10
1294.7121580	1.03
1295.7578120	0.36
1348.5017090	0.57
1349.3188480	0.22
1363.5766600	0.09
1366.5281980	10.67
1367.5765380	6.34
1368.1851810	0.11
1374.3693850	0.05
1380.8173830	0.09
1384.6887210	1.01
1392.5932620	13.06
1393.7050780	6.27
1398.4144290	0.22
1399.6132810	0.10
1410.5421140	100.00
1411.6357420	37.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1484
Annotation	Unknow
Peak:m/z	Relative Intensity
151.1548615	0.06
152.9880524	0.98
171.1206665	0.26
179.1429443	0.75
190.9782104	0.06
196.9675598	0.26
199.9408569	0.17
207.0971069	0.04
215.1553955	0.30
226.9619141	0.89
241.2299957	0.03
243.0067444	0.03
244.9480438	4.33
260.0684204	0.04
261.0976868	0.10
263.1207581	100.00
281.9994812	0.20
283.4372559	0.48
284.1936646	0.07
315.8297119	0.17
316.8608398	0.15
319.3759155	0.10
320.0990601	0.03
324.0870972	0.03
336.8651733	0.28
364.2863770	0.20
376.0568848	0.08
379.1615601	0.06
380.3591309	0.04
392.9632568	0.38
397.2692261	0.04
398.0651855	0.02
406.1005249	0.12
415.2639160	0.25
421.1544189	0.49
423.2820435	0.03
436.1984863	0.06
438.9155884	1.75
452.1659546	0.04
452.8492432	0.09
461.1367188	0.16
480.0955200	0.03
480.9863281	0.05
483.0105591	0.87
494.4605103	0.07
506.9624634	0.07
508.2747192	0.07
509.1515503	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.0509
Annotation	Iriflogenin
Peak:m/z	Relative Intensity
105.0886688	0.02
108.6210709	0.05
109.8997650	0.05
123.1626205	0.07
124.7749176	0.05
132.9716644	2.05
136.9561462	0.06
146.9375000	0.84
148.0039825	0.08
148.9572144	0.38
151.0405579	0.25
157.2058411	0.04
160.9456787	0.12
162.9299316	0.40
164.9717255	0.32
167.1851349	0.03
169.0354462	0.12
171.1075592	0.07
172.8853302	1.18
174.9004211	1.90
175.9667053	0.30
176.9092407	0.46
182.0308838	0.02
185.4399109	0.03
186.8012848	0.05
188.8979492	0.25
189.8277588	0.06
190.9323425	2.79
192.0590363	0.08
192.9441528	0.39
194.1442871	0.05
195.0840759	0.15
196.2382812	0.06
196.9140472	0.02
198.1605682	0.02
199.0940857	0.68
199.9496918	0.02
201.0418701	0.73
202.9932251	0.06
204.9288483	0.08
209.2619934	0.05
211.1697693	0.50
212.0912170	0.28
213.0574036	0.51
214.9443054	0.07
217.1226196	0.69
218.0892944	0.09
218.9744873	0.09
220.9469604	0.08
222.0011902	0.04
223.1687012	0.03
224.5123596	0.10
225.9139709	0.10
227.1311646	0.35
229.1796265	0.11
230.4890137	0.13
231.2250671	0.24
237.0257874	0.18
238.2485352	0.31
239.2222290	0.46
240.0603027	1.05
241.0730286	0.72
242.1578369	0.38
243.0007935	0.77
244.1859436	0.09
252.9116821	0.03
255.0301208	3.07
256.1770935	0.26
257.0319824	0.43
258.9757080	1.14
264.3441162	0.16
265.2024536	0.10
266.1865234	0.10
267.4490356	0.08
268.1352234	0.17
269.0312805	0.06
270.8953857	0.77
271.8566895	0.04
277.2785645	0.02
280.0844421	0.06
281.0482178	0.65
282.9516296	2.12
284.0255737	17.28
285.1156006	1.34
297.0250244	1.52
298.9909668	100.00
300.1007996	8.44
309.1100464	2.12
310.0700073	0.19
312.1105347	0.03
327.0880737	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1007.3308
Annotation	Lactulose
Peak:m/z	Relative Intensity
323.0557556	0.17
341.0407715	0.53
365.4700623	0.15
484.9315186	0.08
503.2235107	100.00
986.9426270	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.144
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
80.6245193	0.04
83.9269257	0.18
85.9186401	22.58
106.9908447	0.05
129.9981384	0.95
131.9516296	100.00
146.9226379	0.02
148.0616760	0.86
177.2333069	0.07
179.0976257	0.04
198.0875397	4.90
205.2139130	0.05
206.1459656	0.04
214.9595947	0.75
217.0839996	0.03
218.2890778	0.02
218.9442444	0.09
219.8631287	0.18
225.0489044	0.91
226.1447754	0.05
240.8674774	0.06
243.0609741	5.05
244.0656738	23.17
252.2657471	0.03
260.0036316	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1972
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9986115	0.11
113.0490036	0.79
118.9647980	0.35
121.0502014	0.05
122.9275665	0.04
124.9682770	0.10
139.2281036	0.07
142.9547882	0.38
146.9681244	0.12
149.0144958	0.14
152.9849243	0.05
155.2772980	0.10
159.1086121	0.08
161.0105286	0.38
163.1226501	0.18
164.0536499	0.29
165.1611633	0.10
167.2150879	0.97
175.2250061	0.11
179.0529938	0.48
183.2269592	0.46
185.0397644	0.08
189.0390930	0.22
191.2716980	0.05
193.2042542	0.14
195.2850647	0.11
197.1519470	0.08
203.1652832	0.17
207.0958557	0.13
207.9965363	0.54
209.0672150	0.96
210.0153046	0.63
211.1276550	4.44
216.1385498	0.34
225.1630249	0.13
227.2995605	0.36
229.0556641	51.15
230.1376953	1.37
235.2792053	0.04
236.9140625	0.05
239.2310181	0.40
241.1161499	0.37
243.1802368	1.01
243.9333191	0.06
245.1727600	0.08
249.0310669	0.38
251.0523682	0.09
253.0973511	1.15
256.0224915	0.13
257.2070007	0.32
259.1724243	0.06
262.1060486	0.05
269.1157227	0.47
271.2825928	3.68
281.2764893	0.10
282.1575623	0.06
283.1860352	2.26
284.0209045	0.11
285.0944824	0.36
293.2828369	0.28
295.3184814	0.29
297.2003479	0.08
301.3273926	0.16
303.1201782	0.13
311.1937561	3.81
312.7306213	0.10
314.9674377	0.11
319.1508789	0.19
325.0396729	0.29
327.6120605	0.03
329.0840454	0.94
331.0500488	2.73
337.0269165	0.26
340.8837891	0.24
343.4287415	0.46
347.0574951	0.42
349.3806763	0.73
355.2333984	1.69
356.1872253	0.06
359.2118835	0.83
361.0210876	0.35
363.1744385	0.14
371.1782532	0.09
373.1837463	100.00
374.3380432	4.70
377.3753967	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.0706
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
85.8379974	0.35
128.0044556	100.00
133.9139099	1.40
153.1015167	1.97
170.9872589	2.21
197.1170807	1.70
203.2489166	0.08
215.0814209	6.92
227.0708618	3.07
244.9470978	38.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	310.1156
Annotation	1,7-Dimethylguanosine
Peak:m/z	Relative Intensity
121.1366119	0.09
132.9251404	2.56
144.0401917	0.06
148.1677094	0.05
161.8774109	0.06
163.1643677	0.09
178.0090637	100.00
179.5150604	0.17
180.2646179	0.12
190.0629578	0.18
192.1760559	0.58
197.0717163	0.08
213.9971313	0.07
220.0830994	1.89
252.2207642	0.05
261.8743896	0.09
263.9168701	0.10
265.8870850	0.63
268.3301697	0.08
274.0054932	0.15
276.2213135	0.08
280.0395813	0.09
281.2902832	0.05
292.1209717	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	887.1844
Annotation	Unknow
Peak:m/z	Relative Intensity
307.0522766	0.03
325.0438843	0.04
335.0193787	0.03
347.1713867	0.06
365.3034058	0.72
370.9415894	0.08
377.2391968	0.24
395.2297668	0.25
401.4539795	0.40
407.2472534	0.06
412.1067505	0.21
419.1203613	0.13
424.7493896	0.08
425.3715210	0.04
437.2900391	0.30
449.0983887	0.05
455.0709229	4.96
455.7614136	0.04
470.4753418	0.13
472.4755249	0.13
473.1823730	0.07
495.9827881	0.15
497.0110474	0.35
509.1618652	0.13
514.6956177	0.27
527.0585938	0.39
563.5563965	0.08
589.0757446	0.27
605.2230835	1.02
616.9379883	0.99
617.6463013	0.31
622.5302124	0.02
629.1939087	1.52
635.0986328	0.06
647.1033936	23.27
647.7519531	0.04
659.1162720	0.29
671.2150879	4.02
673.2243652	0.15
677.0920410	3.11
680.9730835	0.06
683.2011719	0.64
688.9734497	0.03
695.1614990	0.78
698.9817505	0.12
701.0371704	4.66
706.0662231	0.10
713.1992798	4.67
718.9342041	0.60
722.8288574	0.08
725.1948853	1.63
731.2313232	2.91
737.2501831	0.91
743.2523804	0.90
749.0385132	22.64
749.6802368	0.14
754.9901733	0.43
757.2059937	0.36
761.0641479	0.33
767.0221558	100.00
767.6668091	0.18
769.0657959	0.13
773.0964966	0.76
779.1148071	5.44
784.2910767	0.13
785.3203735	0.13
786.9695435	0.18
791.1020508	2.38
792.8440552	0.40
793.5264282	0.14
797.1660767	6.52
803.1782227	3.87
809.3516846	0.10
815.1281738	1.96
821.1685181	7.13
833.1376343	4.75
851.0100708	7.83
851.6415405	0.47
869.1094360	32.69
870.4038086	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1738
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
253.1370239	0.11
264.2158813	0.11
268.0114746	0.09
285.7409668	0.35
294.2935486	0.34
299.6343384	0.16
301.914978	0.79
303.1462708	0.39
317.060791	100.00
317.7277832	0.84
323.4581909	0.08
331.1400146	0.23
337.2529297	0.16
357.0491943	0.28
359.0748901	0.88
362.4135132	0.70
376.675354	0.81
383.3383179	0.40
409.0518188	0.49
416.2623901	0.45
417.1276245	0.08
418.9255371	0.11
425.2608032	0.70
427.3239136	0.58
434.369812	0.09
447.2814331	0.40
459.2359619	0.27
460.9265137	0.80
462.1878662	1.46
462.9434814	4.09
463.5951538	0.15
475.1880493	0.30
476.1740723	0.16
478.8980713	23.70
493.2803955	0.27
495.1607666	0.97
496.0663452	0.23
508.3456421	0.12
521.2010498	1.16
526.5587769	0.54
528.9373779	0.20
535.0426636	0.38
564.9234009	0.40
570.9616089	0.29
579.3088379	1.05
580.6315918	0.24
602.7855835	0.32
606.5690308	0.55
607.444397	1.17
608.3578491	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1663
Annotation	Butrin
Peak:m/z	Relative Intensity
167.0194855	4.46
178.9738464	0.05
186.9127655	0.05
192.6759338	0.16
193.2905731	0.31
193.9503937	0.12
196.9771423	7.11
207.1002808	0.09
209.0650635	0.34
215.1478882	0.07
221.0018158	0.16
235.0807953	5.43
239.0317841	0.08
240.0134277	0.09
243.0423889	0.14
247.0603638	0.03
251.0050964	0.20
259.0092773	0.23
264.9630737	1.61
267.0025635	0.47
268.8261414	0.25
282.9125977	0.53
284.0366211	0.24
285.1442261	0.05
287.1205444	1.70
297.0568848	0.19
298.1594849	0.14
301.1967773	0.13
309.1619873	0.05
311.2302856	2.90
312.1686401	5.09
313.1986694	0.43
315.0608215	0.06
315.9369507	0.11
319.1608887	0.04
323.3258057	0.16
324.0882568	0.13
325.1482544	0.24
329.0615234	100.00
337.0386353	0.32
338.2803345	0.19
339.0900879	0.06
341.1903687	2.50
342.0646362	1.15
343.0222168	0.10
345.5026855	0.06
353.4211426	0.48
354.2529907	0.71
359.1337891	34.50
371.2827759	0.13
372.0836792	0.18
377.0268555	0.30
378.2017212	0.09
383.2968140	0.06
384.3107910	0.52
385.0918579	0.26
389.1270142	0.51
391.1967163	0.09
395.1674194	0.30
396.0630493	0.27
397.0590820	0.06
413.1419678	9.07
415.2566528	1.46
417.2734375	0.17
426.1580200	0.14
428.3937378	0.05
429.0036011	0.11
431.1807251	0.27
433.0924072	23.63
442.0370483	0.13
443.2030640	0.05
447.0219116	0.04
449.3511963	0.11
455.9991455	0.09
457.2942505	0.10
459.0557861	0.09
461.1162109	0.04
465.2288818	0.04
468.2333374	0.10
469.2261963	0.06
473.1610718	1.16
474.2902222	2.46
475.0753174	1.45
476.1088257	0.07
483.2213135	0.92
484.8934937	0.04
486.0995483	0.34
491.2657471	0.07
493.7250366	0.06
501.0753784	5.37
503.1695557	0.70
504.3891602	0.54
505.2723999	0.21
506.0534058	0.17
506.8890991	0.03
508.2042236	0.21
510.2435913	0.14
511.3641968	0.09
515.3500366	0.04
516.2329712	0.16
533.2490234	0.25
535.3955688	0.81
537.1901245	0.03
547.9548950	1.15
549.0694580	2.76
550.3112183	1.01
551.0743408	0.35
558.0646362	0.08
559.0756226	0.51
567.0015259	0.22
575.1543579	0.19
576.5279541	1.33
577.2141724	11.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	612.31
Annotation	Oleficin
Peak:m/z	Relative Intensity
195.4150391	0.03
198.1753082	0.14
259.2767029	0.09
281.0227051	0.13
311.0908508	0.10
311.9598999	0.03
323.2413025	0.07
347.3799438	0.05
368.2781982	0.12
371.3127441	0.06
387.3305664	0.05
387.9790649	0.06
397.1889038	0.07
403.5892334	0.10
406.0952759	0.11
411.2355957	0.04
432.9158325	0.10
435.3144531	0.44
436.3285522	0.20
443.7195435	0.05
460.3148193	0.09
463.3581543	0.19
474.3161621	0.17
481.2410278	9.91
486.3264771	0.08
490.6106567	0.13
493.3733521	0.10
495.5489502	0.31
498.1959839	0.04
505.9287720	0.09
507.1127319	0.41
509.4199829	0.03
516.1185913	0.21
518.1704102	0.16
524.2637939	0.03
525.2805786	0.27
537.6233521	0.37
547.2932739	0.09
547.9356079	0.06
550.3483276	0.05
551.0913696	0.06
552.3265381	100.00
553.2422485	0.47
560.4595337	0.10
565.3111572	0.44
566.3912964	1.73
567.4345703	0.13
568.1116943	0.19
569.1806641	0.13
576.0363770	0.13
580.1030884	0.09
582.5410156	0.04
584.5213623	0.10
592.4797363	0.11
593.3400269	0.25
594.2661133	0.82
595.1820679	0.05
597.2819824	0.55
603.9716187	0.18
612.8327026	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0881
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
145.0680389	0.03
148.4946899	0.04
150.9837952	0.36
152.9916382	0.06
160.9184265	0.03
162.9940491	0.07
168.8291168	0.04
172.8731384	0.07
178.9915771	0.95
182.9567261	0.02
188.9560547	0.08
189.9948273	0.06
190.8858643	0.10
193.2089996	0.02
207.0550537	0.08
208.9806824	0.08
211.1566467	0.02
213.086792	0.04
217.1600494	0.07
220.8218536	0.08
227.1179657	0.13
228.140686	0.07
228.9936829	0.09
233.0177307	0.08
236.8864441	0.07
238.9167786	0.04
240.1964417	0.10
246.5652771	0.03
253.9695435	0.03
254.9986572	0.10
257.1116333	0.03
258.9622803	0.07
271.0119019	0.39
272.9535217	0.21
279.4735107	0.04
281.1695862	0.18
282.3599548	0.08
284.1846008	0.05
285.1493835	0.14
297.2473755	0.11
300.0091248	21.87
301.0402832	100.00
302.8993835	0.04
309.3153076	0.04
311.2089233	0.12
313.196228	0.26
314.8813782	0.20
317.0911255	0.02
319.2684021	0.06
325.0866699	0.05
326.0540466	0.04
327.1817322	0.09
330.7751465	0.02
337.0481262	0.12
341.1118164	0.55
342.1532593	1.58
343.1641846	3.64
347.1629944	0.02
348.3118896	0.03
350.8427124	0.12
353.04245	0.05
355.0726318	0.18
361.349884	0.10
371.0986023	0.16
372.4065247	0.52
373.1464539	0.54
383.2288513	0.02
385.0662537	0.04
391.0063171	0.08
396.3521729	0.03
399.0969238	0.04
400.825531	0.04
403.1375427	0.05
408.0571899	0.05
409.1156006	0.07
414.4154053	0.07
416.7859802	0.08
419.0212097	0.20
426.0708313	0.04
427.3659363	0.07
431.1758118	1.16
437.9982605	0.04
445.0311279	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	941.5098
Annotation	23-Hydroxyursolic acid 28-O-alpha-L-rhamnopyranosyl-(1->4)-beta-D-glucopyranosyl-(1->6)-beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
290.4177856	0.52
307.1947937	0.72
324.9565430	0.49
375.3299255	1.27
377.1239929	0.43
395.1983337	1.24
403.1019287	0.58
409.4624634	3.10
421.1826782	1.17
424.9949341	1.87
425.6150513	1.09
436.7737427	1.86
437.4389038	9.26
438.2806396	0.20
454.9407349	0.46
457.3756104	21.82
458.0021362	0.12
464.8407593	0.28
467.3519287	0.78
479.6486206	0.42
497.0833740	1.43
501.3554688	0.36
507.5391846	2.18
525.4312744	31.23
527.6807861	3.37
553.4960327	0.89
568.6106567	0.36
571.3178101	4.90
589.6489258	2.24
597.4417114	11.85
615.4843140	45.27
633.5504150	2.99
733.5525513	30.84
751.4564819	6.26
777.0018311	0.24
777.7417603	2.02
795.5197144	22.43
823.3989258	0.80
879.4334106	61.47
880.3933716	1.19
894.3303833	0.54
897.4210815	4.25
905.6740112	1.18
923.4240112	100.00
924.6311646	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.1906
Annotation	Limonexic acid
Peak:m/z	Relative Intensity
146.2229767	0.28
147.0722504	0.93
150.7686157	0.28
156.0020447	0.27
156.7338409	0.10
158.9676819	0.18
161.0506897	7.22
163.0649567	0.67
175.0749359	8.07
177.1497040	0.10
179.0418701	4.28
181.2794342	0.23
184.6821899	1.68
185.3477478	0.08
186.9564056	2.05
188.9480286	0.32
195.0694275	0.26
198.8535461	0.69
201.0214386	0.05
212.0844879	0.14
216.9725037	2.23
232.7714539	0.14
242.8329926	0.31
263.1231079	0.27
265.2780457	0.08
274.1044006	0.20
277.1334229	0.18
279.1337891	2.11
283.1909180	0.26
291.0530090	6.79
291.9898682	0.92
295.1317749	1.45
299.1391602	0.10
301.1957397	0.15
309.0582886	0.16
311.1084900	40.68
311.7947083	0.07
313.0787354	0.12
315.2557983	0.61
317.1557007	0.23
323.1346130	100.00
325.0587769	0.87
334.9420166	0.90
337.1783142	0.32
340.9894409	25.12
341.6153564	0.18
347.2118835	0.41
349.2508850	0.17
349.9351196	0.23
351.0980835	0.10
352.9792175	0.93
353.7496338	0.38
355.2718506	0.13
359.1051941	0.29
365.2324219	0.77
366.8404541	0.09
369.4153137	0.45
373.2161255	0.32
373.8841858	0.52
379.3317566	0.05
383.1040649	0.45
389.1806946	0.32
393.6953125	0.19
397.2687988	2.24
398.7669373	0.31
406.7946777	0.14
407.3995056	0.26
410.4077454	0.25
411.9584351	0.09
413.2067871	0.06
415.2944336	0.06
420.7901001	0.46
422.1333008	0.50
423.8973694	0.50
425.0491943	0.17
426.9273987	0.98
431.3546753	0.06
436.4778442	0.24
437.2525330	0.34
438.1415405	0.19
438.9664001	0.32
442.8829956	1.16
454.9609070	0.87
456.3854370	0.81
457.2171936	5.54
458.0735779	0.13
467.2043762	1.67
470.4018250	0.08
472.3645325	0.65
473.2186890	1.04
474.9975891	0.38
479.7348022	0.18
482.1378479	0.44
483.3670349	0.37
485.0242615	9.27
485.7616272	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
124.8180771	0.29
153.1985474	0.03
160.805542	0.40
164.2229309	0.02
165.0536957	0.07
175.2757721	0.11
179.0066223	0.79
180.9481201	0.03
186.774292	0.06
196.848877	0.06
205.0883179	0.93
207.0464783	0.02
208.9980621	0.07
215.2174835	0.03
222.0854797	0.02
223.0902405	0.19
225.0831909	0.03
227.4101105	0.08
233.1457214	0.34
239.2046814	0.43
249.077301	0.05
251.2206116	0.77
263.2659607	0.07
265.036377	0.06
266.9752197	0.10
269.0411377	12.04
269.6433105	0.22
272.056427	0.06
275.0283203	0.17
277.2330017	0.07
279.285553	0.18
281.2445679	0.08
282.9433594	0.06
287.0209351	1.05
293.2975769	0.09
297.2860413	0.08
299.0407104	0.22
304.1470337	0.04
306.6160583	0.15
307.2290039	0.17
309.4247437	0.10
311.0529175	100.00
311.704834	0.32
312.3128052	0.05
315.1955261	0.08
319.3731995	0.05
320.3896179	0.03
321.5110474	0.02
323.3901062	0.04
327.0180664	0.05
335.1674194	0.05
337.0419312	1.86
339.1555176	0.04
341.1983643	15.08
342.1115417	0.11
344.8633728	0.08
353.2158813	0.46
355.2312317	0.36
359.1596069	0.06
365.3539124	0.04
366.8677673	1.49
370.0275879	0.05
371.2268982	0.73
377.0584106	0.27
383.1118469	0.55
385.1460876	0.84
387.2602844	0.34
388.2817078	0.67
389.2817078	0.24
390.0093079	0.08
393.1705017	0.31
394.7655334	0.18
395.4364014	0.12
399.4017639	0.06
401.1169739	0.85
412.4458923	0.29
413.1544189	4.17
416.0680542	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2811
Annotation	Assamsaponin I
Peak:m/z	Relative Intensity
199.1436462	0.04
204.8473511	0.03
209.1279602	0.07
235.1419067	1.44
235.9674683	0.03
241.7380829	0.08
243.1692047	0.18
245.1396179	0.09
246.9776611	0.18
252.8021240	0.08
261.0710144	0.03
263.0430298	0.07
263.9745178	0.04
268.3775940	0.21
269.1914368	0.03
277.3027954	0.47
283.2756348	0.16
286.1707764	0.28
287.0967407	0.74
296.0234985	0.06
301.9878540	0.16
302.8370972	0.04
305.1246948	3.30
306.1771851	0.53
309.1325684	0.02
313.5451660	0.02
317.3637085	0.06
327.0313110	0.03
328.6405029	0.05
329.2529907	0.07
341.2135010	0.11
345.1060181	0.04
346.2056274	0.09
353.1763916	0.05
373.1759644	0.06
378.0307007	0.11
381.6430054	0.41
383.2483521	0.08
387.4184570	0.15
401.1856689	0.11
403.2913818	0.15
405.1095581	0.14
412.4633789	0.40
421.4002075	3.15
422.2671509	0.30
423.1913452	0.05
435.5025024	0.05
445.3620605	0.06
447.0566406	0.05
454.5558472	0.51
455.3384399	0.11
457.2040405	2.54
458.2847900	0.16
462.5609741	0.06
465.1248169	0.17
466.3781738	1.01
467.1843262	0.68
469.4404297	0.04
470.2816162	0.17
471.4872437	0.14
473.3809204	0.17
474.4169922	0.12
476.3801270	2.76
477.1646118	0.53
479.2285156	0.07
482.8366699	0.16
485.4440918	100.00
486.3569336	4.39
487.3642578	0.31
488.5488281	0.25
495.4631348	0.04
499.1378784	0.05
500.1877441	0.27
501.5090942	0.10
502.2434692	0.05
506.4087524	0.04
508.9627075	0.04
509.8994141	0.08
511.2235107	0.06
513.2823486	0.04
520.3250732	0.03
522.8131714	0.12
525.3773804	1.61
533.8449097	0.09
534.8276367	0.20
537.2141113	0.10
538.4875488	0.06
539.4310303	0.29
542.7656860	0.06
545.3242798	0.05
547.5335083	0.50
549.3181152	0.27
552.2894897	0.07
553.1904907	0.07
555.5179443	0.25
556.2138672	0.43
556.9419556	0.19
565.5626221	0.08
566.3853149	0.13
567.1891479	0.17
568.7055054	0.10
569.4556274	0.38
570.2991943	0.38
571.6659546	0.16
581.2701416	0.05
583.0838013	0.64
584.3627319	0.14
585.1461792	0.35
589.4419556	0.09
590.2390747	0.32
593.0323486	0.24
594.8806152	0.23
596.7733765	0.05
597.6491089	0.11
598.2922974	3.06
598.8979492	2.33
599.5661011	0.68
600.5679932	0.11
601.7504272	0.17
602.3829956	0.02
608.2632446	0.30
609.1738892	0.39
609.8559570	0.06
611.3847046	1.20
612.3650513	1.17
620.4384155	8.46
621.3682251	0.76
643.7019653	0.05
645.5161743	1.59
646.6761475	0.18
647.3812256	0.08
670.6369019	0.06
697.0253296	0.02
715.3615112	0.18
721.2404175	0.05
734.2409058	0.04
745.3990479	0.33
746.3929443	0.09
757.3652954	1.74
758.5008545	0.78
763.4667969	0.19
765.6169434	0.10
775.3701782	0.86
776.3376465	0.84
777.5075073	0.07
781.3993530	0.04
817.6132202	0.09
825.1338501	0.16
826.1552124	0.08
857.4611206	0.77
858.5244141	0.29
864.9677734	0.13
871.4869995	0.19
872.8142700	0.22
873.5244141	0.04
889.5501099	0.21
890.6171265	0.09
891.6777954	0.46
892.9159546	0.18
909.5044556	0.05
915.4084473	0.56
916.4434204	0.11
917.0700073	0.03
933.3341675	1.93
934.2971191	1.18
935.0853882	0.82
935.8546753	0.12
936.5995483	0.20
953.4568481	15.80
954.4750977	8.78
955.4237671	2.14
971.3766479	11.14
972.4648438	3.79
973.4456177	0.88
998.6804810	0.08
1033.3620610	0.04
1034.5809330	0.19
1035.5098880	0.04
1126.2419430	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	430.1936
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8662415	0.06
158.9997406	0.03
161.0589142	0.06
169.0844421	0.05
269.0331116	0.17
274.1164551	0.08
283.2832642	2.36
284.3443604	0.06
290.2352905	0.19
291.2879944	0.08
297.0010986	0.09
298.2454834	0.07
304.0492554	0.19
304.8803406	0.07
309.4353943	0.02
311.1598206	5.64
323.3091431	0.03
326.1743164	0.06
331.2806396	0.05
331.9847107	0.06
340.2482910	0.30
341.0515137	0.60
343.1706238	0.14
346.0250854	0.02
348.1035767	0.02
349.3143005	100.00
350.2593994	1.00
356.0221252	0.33
356.8514709	0.03
370.3137817	0.14
386.3322144	0.10
388.3011475	0.04
394.1210327	0.02
395.0348816	0.07
407.7123108	0.01
412.0597839	0.05
413.1650085	0.08
421.6846924	0.34
487.6626282	0.09
488.7054138	0.01
491.3584290	0.05
505.7993469	0.09
519.2874146	0.07
521.6098022	0.05
537.1519775	0.01
549.3027954	1.01
550.2439575	0.47
551.5510864	0.06
567.3720093	0.90
568.5556030	0.23
581.4075317	0.51
582.3820190	0.24
609.5339966	0.15
621.2439575	0.01
641.3315430	0.03
654.5007935	0.09
681.3229370	1.83
682.3788452	0.59
683.3383179	0.03
699.3836060	2.05
700.4169312	0.93
701.1160278	0.03
741.3023071	0.46
742.3178101	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
150.09552	0.01
151.1558838	0.01
152.9684448	0.03
157.2354736	0.06
159.084259	0.03
163.0894165	0.01
179.0561829	0.07
180.269928	0.01
186.2808838	0.05
191.0674744	0.02
192.3013	0.01
201.1757507	0.01
201.9813538	0.02
203.0453644	0.01
207.2277527	0.01
207.9344788	0.01
208.894989	0.01
221.1241455	0.03
226.1729584	0.04
241.1759033	0.01
243.2184143	0.01
247.21521	0.02
251.1729431	0.07
252.4400635	0.03
253.2027588	0.01
258.9670715	0.03
265.3666382	0.01
268.0719299	2.53
269.0752563	32.90
270.0684814	10.29
271.1429443	0.04
281.3725891	0.05
283.070282	0.57
284.1958618	0.39
287.1078491	0.09
291.1246643	0.07
292.4357605	0.05
293.1744385	0.09
294.3422546	0.02
295.3200684	0.05
297.2844238	0.02
307.0236206	0.07
309.2918396	0.02
311.0571899	100.00
312.0249939	48.59
319.2528687	0.01
320.1321411	0.02
321.1003723	0.02
323.2097168	0.38
324.2243042	0.27
325.0224915	0.01
326.1877136	0.05
336.0305481	0.02
337.0901184	0.09
338.1235962	0.07
341.0964355	13.56
342.1170959	6.31
345.3911133	0.13
349.1804199	0.01
350.1625366	0.02
351.2541504	0.08
352.4888306	0.07
353.1832581	0.76
354.1011963	0.46
355.1630249	0.30
356.170105	0.14
359.9756775	0.04
365.256012	0.06
366.1854248	0.01
367.6944885	0.07
368.3382568	0.03
369.6575623	0.04
371.177002	0.47
372.2286072	0.08
377.0257263	0.29
378.3059998	0.11
383.1453857	0.45
384.1022949	0.22
384.7450867	0.04
386.2999878	0.01
388.2120972	0.03
389.5810242	0.02
393.269928	0.01
394.0486755	0.03
395.10495	0.28
396.1124573	0.27
398.282196	0.01
400.7333679	0.03
402.3474731	0.04
403.9217224	0.04
413.1343689	1.63
414.1230774	1.27
416.2689819	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0928
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
142.190567	0.03
160.8778687	0.11
180.9912109	0.05
182.911499	0.04
200.8139801	0.05
231.287384	0.07
254.960968	0.12
257.3044128	0.05
266.3078308	0.17
267.1990662	0.05
268.917572	0.07
280.9385986	0.05
281.9188843	0.02
283.3725891	0.22
285.0444336	100.00
286.0758362	0.31
288.9680786	0.12
294.9472961	0.05
297.1513672	0.17
301.1332092	0.11
303.3849487	0.04
313.1299438	0.14
314.1061401	0.15
315.2288818	0.03
325.0289612	0.55
327.0050049	19.71
328.0063782	0.15
339.0726013	0.16
341.0157166	0.09
343.3919678	0.12
344.0114441	0.14
347.1878052	0.05
353.367157	0.03
354.1531372	0.05
355.2544861	0.08
357.1084595	6.82
359.2175598	0.05
362.9151306	0.06
369.1993713	0.68
371.0698853	0.15
373.1546021	0.13
375.1272888	0.11
381.2814026	0.04
385.3688965	0.14
386.4062805	0.16
387.2470093	0.43
388.4885864	0.13
389.4926758	0.07
390.2761536	0.13
393.1184387	0.14
399.042511	0.24
400.3952332	0.07
401.2218018	0.09
409.3551941	0.17
410.360321	0.30
411.2721252	0.53
416.3908386	0.41
428.5774841	0.22
429.2618713	0.60
432.7502136	0.05
447.2048645	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.229
Annotation	Dihydrofoliamenthin
Peak:m/z	Relative Intensity
191.1327515	0.07
202.1720734	0.06
211.1795654	0.02
230.2614441	0.06
233.1756592	0.17
241.0533600	0.06
271.1436157	0.02
273.1062317	0.08
317.2123413	0.19
331.1853638	0.57
335.1379395	0.10
342.9599609	0.12
361.2276611	1.32
363.5953369	0.05
377.3109741	0.11
379.1998901	100.00
380.1642456	0.04
393.2455444	0.18
403.1880493	0.10
405.1893311	0.12
413.1028442	0.03
415.2223511	0.03
421.2177124	16.48
421.8408813	0.05
434.9088135	0.04
441.1951294	0.08
445.0693970	0.10
451.5338135	0.03
452.2274780	0.08
454.0895386	0.14
454.7349854	0.13
457.0447388	0.09
464.9638062	0.10
478.1705322	0.09
480.4319458	0.05
481.2424927	0.16
493.3265381	0.20
495.1223755	3.18
495.7534790	0.01
497.2412720	0.14
498.1212769	0.03
502.8118286	0.12
505.3075562	0.05
507.3909302	0.07
522.3047485	0.46
523.2634277	0.76
525.4552612	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.1436
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
126.9412689	0.08
135.0317535	0.16
135.8837280	0.03
143.9084778	0.04
148.8057556	0.02
151.1021423	0.53
166.9091492	0.08
169.0409698	0.03
175.0113831	0.12
185.1709595	0.03
189.1181641	0.05
191.2482147	0.05
203.0021057	0.03
208.2946472	0.12
209.2633820	0.03
211.0539703	0.12
215.2148438	0.02
216.9855804	0.35
235.0557098	0.70
240.7348938	0.02
243.2046509	0.05
247.0195312	0.02
251.2014465	0.23
253.0470886	0.20
261.9087830	0.03
269.7601624	0.04
275.0836487	4.26
280.0678101	0.04
284.1652832	0.15
284.9912720	0.07
287.1663513	0.26
293.3228455	0.04
297.7608643	0.06
299.1030273	2.82
311.0392456	0.02
313.3095398	0.07
313.9650269	0.05
314.9664001	0.02
317.1252747	22.44
322.1840515	0.09
322.9102173	0.14
329.1016541	0.02
331.5265503	0.06
336.2476196	0.02
338.2184753	0.03
341.1121216	12.40
346.3034058	0.05
352.0175171	0.23
353.2268066	4.31
356.2739563	0.21
365.2359619	0.95
368.1426086	0.14
368.9811707	0.02
370.4454041	1.31
371.0996399	3.74
377.2359924	0.07
383.0480652	16.23
383.6980591	0.12
388.2954102	0.03
391.5877991	0.06
398.1800232	0.11
400.3984985	1.54
401.1398926	8.62
402.2065735	0.06
409.3948669	0.04
416.3851013	0.18
419.0239563	100.00
419.6912537	0.39
427.8540344	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0967
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
117.3022461	0.06
132.1132507	0.05
159.0621796	0.17
177.2064667	0.04
188.0028839	100.00
188.7729340	0.00
189.8610077	0.01
196.0827484	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	596.3199
Annotation	1-Epicrassicaudine
Peak:m/z	Relative Intensity
170.7980347	0.10
179.9844513	0.22
194.1421814	0.06
209.8386230	0.06
211.3266144	0.08
215.1632233	0.05
223.0509491	2.54
224.1820526	0.60
239.1693420	0.04
241.0570374	6.68
242.1185608	0.80
259.0520325	0.38
260.0903015	0.27
260.9814453	0.07
267.0906677	0.09
269.0906067	0.05
271.0599365	0.06
273.3833008	0.04
279.1939697	7.88
280.3180542	0.92
293.1903381	15.27
293.8787231	0.19
295.3052368	0.53
307.3352661	2.92
311.3472900	0.10
315.0567017	11.37
316.0518799	1.15
317.1424561	0.04
324.1499023	0.36
333.0947266	1.82
336.0993042	0.15
339.3127441	0.09
377.0565186	0.09
379.0694580	0.17
389.0806885	0.18
391.4558716	0.03
394.3748779	0.06
404.3017578	0.32
410.0815430	0.12
413.3662720	0.08
415.1793213	1.82
416.0786133	0.57
429.1722412	0.45
431.0706787	0.27
433.4009399	0.04
437.4198608	0.18
438.2586060	0.04
446.3568726	0.53
447.2659302	4.46
449.3488159	0.86
465.4227295	0.06
473.2517700	4.89
474.2883911	1.98
489.1456299	0.08
490.8850708	0.09
502.1607056	0.19
517.2206421	1.03
518.2739868	40.57
518.9270630	0.05
520.3253174	0.59
532.2570190	15.12
533.2328491	0.11
536.1953735	100.00
537.2468262	0.45
549.9688721	0.97
551.2330933	0.08
578.3901978	0.34
579.4102173	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1456
Annotation	Rutine
Peak:m/z	Relative Intensity
171.1168213	0.12
172.8847351	0.05
174.0992737	0.24
178.9674072	2.04
182.0294037	0.20
183.0737915	0.11
187.097168	0.03
188.9671783	0.11
191.1355896	0.08
193.0132446	1.28
195.0836487	0.10
197.1352539	0.07
198.137207	0.24
199.3546448	0.06
201.2050323	0.10
205.1105804	0.25
210.0567627	0.12
211.0127716	0.30
212.3237915	0.15
214.9351807	0.22
217.1000061	0.45
219.2262573	0.39
226.903656	0.60
229.1410217	1.14
235.0112305	0.04
239.1392059	0.60
240.2049408	0.17
244.1682587	0.10
246.9425659	0.36
251.3095398	0.23
254.5363464	0.41
255.1855469	1.86
256.8619385	0.78
259.1245728	0.22
263.2568054	0.17
266.0348511	0.11
271.063324	5.40
272.0220947	0.07
273.0831909	0.89
283.1555176	0.81
285.0736084	0.31
286.4211426	0.11
287.3156128	0.23
295.0359497	0.29
297.2564087	0.82
299.003418	1.49
300.0369263	29.44
301.041748	100.00
302.1427307	1.18
312.072937	0.09
312.9320679	0.66
313.8857727	0.69
315.2006226	0.08
325.0244141	0.54
326.9344482	1.21
329.1030273	0.13
337.1036377	0.34
341.2230835	0.23
341.8431396	0.07
343.1218262	8.30
343.9024048	0.04
354.9607544	0.27
356.1950073	0.09
367.0627441	0.08
369.2888794	0.43
373.0996704	1.03
374.3834839	0.14
379.9716797	0.06
384.2304688	0.10
393.0860596	0.06
396.9713135	0.05
401.4088135	0.18
403.149353	0.24
406.0931396	0.32
411.444397	0.24
428.4415894	0.07
429.4431152	0.11
439.1628418	0.07
446.0140991	0.05
447.4526367	0.19
449.2325439	0.06
455.2006226	0.11
456.1830444	0.12
457.2853394	0.12
459.1118774	0.20
463.1174316	0.55
464.1104736	0.05
465.2466431	0.50
469.7752686	0.24
472.1236572	0.06
472.7418213	0.19
473.4053955	0.09
480.6676636	0.05
483.5505981	0.06
487.8011475	0.11
489.3082275	0.28
491.2922974	0.20
495.0606079	0.04
499.1971436	0.48
500.0685425	0.12
507.2541504	0.37
514.1334839	0.13
519.4445801	0.18
520.7866821	0.24
521.4899902	0.62
522.9552002	0.08
537.1160889	0.09
546.4381714	0.24
547.3945923	0.09
549.1251221	0.19
562.1914062	0.25
563.1819458	0.16
563.9174194	0.08
565.0001831	1.29
565.7739868	0.05
579.8305664	0.08
581.192688	0.12
584.1641235	0.08
589.585144	0.25
591.0884399	3.73
594.2772217	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.51
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
219.3357697	0.24
237.3153992	0.08
240.894989	0.26
255.2779694	36.61
256.2513428	0.21
260.8866577	0.17
273.271698	0.22
277.4186707	0.20
279.2273865	100.00
281.175415	0.08
283.2592468	0.43
284.5409851	0.11
293.424469	0.39
297.046814	0.11
299.1125793	0.21
309.173584	0.12
327.2971191	0.28
328.4605713	0.07
343.3066711	0.18
360.6734619	0.60
378.4921875	0.36
389.2788086	0.36
391.0515137	0.34
392.2400513	0.10
403.5248413	0.37
419.1358032	0.14
419.9337158	0.06
429.1830444	0.27
433.7507324	0.13
434.492981	1.86
438.2557983	0.38
445.3495483	0.24
452.3174438	17.46
453.3677979	0.18
455.067749	0.48
458.1884766	1.50
462.3186035	0.59
464.2264404	0.10
475.1808472	0.24
476.4130859	0.81
482.2077026	0.12
490.2328491	0.12
504.1752319	0.11
552.3701782	0.17
553.1416016	0.10
554.170105	0.32
623.3482056	0.27
635.5829468	0.26
636.5650024	0.15
639.6069946	0.19
643.331665	0.24
650.4951172	0.08
655.1260376	0.61
656.3873901	0.11
665.5203247	0.13
669.694519	0.28
670.3770142	0.14
684.3920288	0.17
694.2911987	0.11
695.2418823	0.15
696.4550781	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	445.12
Annotation	Unknow
Peak:m/z	Relative Intensity
144.1040039	0.12
151.0973206	0.32
157.1248016	0.10
179.0148621	0.66
189.1183777	0.16
192.8522339	0.08
194.9999390	0.08
197.0824432	2.15
199.3717346	0.10
201.2000580	0.18
202.9267120	0.08
204.8847351	0.09
209.1808167	0.07
220.9550781	0.36
223.2287750	0.50
224.0471802	0.19
227.4456482	0.18
229.1345062	0.17
232.1233826	0.25
234.0333099	0.96
235.0561371	3.22
242.1401367	0.19
247.0562134	1.79
250.9667358	0.16
253.0148621	0.80
261.3057251	0.26
261.9277954	0.06
263.3070374	0.34
265.0027466	16.02
267.1767578	0.10
269.1462097	0.12
270.2165527	0.27
273.1056519	0.34
277.6979370	0.21
281.1705017	0.54
283.0351562	100.00
284.3363342	0.38
286.8853455	0.09
293.7519836	0.46
298.3073120	0.12
300.2149963	0.88
300.8672485	3.55
307.2090454	1.41
309.2518921	0.25
312.1299438	0.26
313.3494263	0.07
316.1199951	0.15
325.0511780	45.06
330.4613037	0.21
332.1401367	0.08
335.1579590	0.52
337.2072754	1.68
338.7926025	0.56
342.3981934	2.20
343.0445862	9.01
347.1922607	0.18
349.0253906	0.85
351.9100037	0.31
353.1437378	1.05
354.9334717	6.31
355.9780273	1.57
356.8267822	0.36
361.0220337	3.46
361.9002686	0.19
363.4270325	0.58
364.2647705	0.35
365.6403809	0.83
366.6743469	1.85
367.3118286	1.05
371.6364441	0.10
379.0323792	4.84
381.1203613	0.09
382.6261597	0.24
383.3318787	0.14
384.3390198	3.69
385.0922546	3.92
385.8439026	0.10
387.2494507	0.49
391.2061768	0.53
395.9897461	2.99
397.0541077	7.35
398.4723511	0.34
399.3031921	0.56
400.2023621	0.10
401.2555542	5.95
404.1976624	0.22
408.1830750	0.88
409.0898438	0.94
412.8647461	0.28
414.1163940	3.84
415.1055908	12.46
421.5747375	0.27
426.1274719	1.75
427.1361389	13.79
431.1092529	1.04
435.6697083	0.59
444.5904236	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.79
Annotation	Liothyronine
Peak:m/z	Relative Intensity
209.0696716	0.03
231.9467468	0.08
292.8825989	0.44
316.0192871	0.30
374.9125977	0.07
399.6671143	0.78
420.3109131	0.14
437.7734375	0.52
443.8646851	0.06
444.8280640	0.05
456.1604614	0.12
458.1747437	0.04
476.9965820	0.14
480.7760010	0.04
481.8992920	0.18
483.7153320	3.34
489.1211548	0.02
495.8275146	0.02
497.9991455	0.07
499.7847290	0.10
521.5590820	3.50
522.1720581	0.01
557.9679565	0.09
566.9609985	1.67
567.6655884	11.97
589.9375610	0.13
603.8302002	0.02
605.5727539	100.00
606.2593384	0.60
607.9080200	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
967.4165039	32.56
969.4155884	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.1061
Annotation	S-Methyl GSH
Peak:m/z	Relative Intensity
100.0009842	0.06
111.8600159	0.02
116.0708008	0.01
129.9245300	1.67
146.9813232	0.07
157.8728333	3.38
159.0616760	0.11
175.1385345	2.40
175.9940491	9.53
189.7916718	0.11
192.9351807	100.00
215.0104065	0.42
228.8612976	0.04
232.9888916	4.69
247.1777954	0.10
258.9777527	0.04
273.6092529	0.02
275.7806702	0.04
278.0637817	0.05
286.1751709	0.49
294.1173706	0.01
304.0331421	5.77
305.0651550	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2138
Annotation	Lactulose
Peak:m/z	Relative Intensity
178.8930206	0.14
202.8857422	0.31
221.0412140	6.17
249.5018616	0.48
250.7974854	0.47
262.9115601	0.15
268.5104065	0.35
280.9005127	1.68
305.2077026	1.32
310.7327881	0.74
321.1232300	0.32
323.0040894	5.84
341.0311890	34.50
383.1815796	100.00
407.0225220	0.23
411.3918457	0.09
412.8512573	2.73
425.2017212	1.17
441.5496216	0.16
442.7907104	21.34
443.5233154	0.48
455.4088135	0.07
466.9446411	0.47
473.1605225	0.45
485.2168579	28.04
502.9004517	3.63
545.1363525	1.12
618.9389038	0.15
647.3554077	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1918
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
170.9041138	0.02
175.0387878	0.04
176.9748688	1.28
184.9952240	0.04
198.1096802	0.02
202.8160858	0.02
218.7262573	0.14
233.1601868	0.03
247.2155457	0.07
251.2201538	0.03
254.2621765	0.10
261.2216187	0.04
269.1734009	0.09
272.9684448	0.06
275.1542358	0.37
285.0587463	0.02
289.4371948	0.17
291.1871033	0.27
293.2741394	0.16
300.9982910	0.19
306.9221191	0.03
307.5591431	0.03
313.3876953	0.01
317.1985168	0.30
319.2378235	1.28
320.9973755	0.11
322.5317383	0.02
324.1500549	0.15
325.0706177	0.08
326.1748657	0.04
326.9714966	0.03
333.0377197	0.17
335.2222900	31.07
337.1719360	1.30
338.1102905	0.09
339.1587219	0.06
345.1813965	0.18
351.0265198	0.03
353.0316467	0.13
354.1134338	0.15
360.0732727	0.02
363.1784363	100.00
363.7979736	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.2002
Annotation	7S,8S-DiHOTrE
Peak:m/z	Relative Intensity
79.0071335	1.54
80.9772186	1.87
83.0091782	1.33
84.8701477	0.17
91.0103302	7.68
91.9075546	0.13
93.0128861	4.49
94.9476624	3.20
96.9470749	1.93
98.8408508	0.80
103.0567627	0.27
104.8869629	16.42
106.9011993	4.38
107.5526657	0.06
108.9911499	1.70
109.9094162	0.24
110.9650955	1.76
113.2580414	0.77
115.2432938	0.17
116.9559097	2.58
119.0058975	15.43
121.0097122	6.80
122.9873886	2.28
125.0457382	1.18
126.8703156	0.71
129.0530396	3.00
131.0283356	9.67
133.0669861	30.26
135.0967712	7.19
137.0599670	1.24
139.1321411	0.17
140.9835205	1.63
142.9751282	2.19
145.0187988	22.36
147.0039368	32.20
149.0830994	8.57
151.1000366	0.75
153.0211487	0.27
155.0583344	2.35
157.0166931	9.27
159.0451660	34.21
161.0791321	16.85
163.0393372	8.81
165.0301971	4.83
166.9274902	0.64
168.9829407	5.49
171.0899048	10.27
173.0918884	26.27
175.0434570	11.23
177.0505371	2.90
178.9779816	3.65
181.1522064	1.63
183.0965729	11.47
185.1257324	4.52
187.0851288	7.55
189.1595306	6.26
191.1100159	3.20
193.0643921	4.55
195.0513306	0.88
197.0689087	11.14
199.0928345	2.79
201.0690613	7.84
203.2254639	1.70
205.2070312	2.91
207.2062683	1.11
207.9481506	0.18
209.0203857	0.78
210.1337280	0.41
211.1518250	4.78
213.1085205	4.71
215.1351929	13.09
217.2278137	0.37
219.1249084	8.26
227.2481995	0.57
229.1145020	18.10
231.2252197	0.75
233.1597290	9.71
234.1295471	0.18
236.9740601	0.09
239.1440430	37.10
239.7700806	0.14
245.2662964	0.07
247.2453918	25.61
248.9829102	0.21
257.1660461	100.00
266.2299500	0.38
275.0820923	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.96
Annotation	Unknow
Peak:m/z	Relative Intensity
141.8097076	0.07
155.9140472	0.57
170.0419312	0.33
183.9532166	0.53
199.9387665	11.80
200.8622131	0.58
213.9509888	3.20
215.0364685	0.13
218.1008606	0.19
225.9226532	0.27
227.7379150	0.50
242.0974121	0.12
243.9399414	3.41
245.7586060	1.21
251.2149963	0.27
255.7822876	0.05
257.9000244	50.15
258.5052490	0.10
260.1550903	0.12
261.9615479	1.77
266.0444336	0.05
268.0101624	0.17
271.6691589	0.61
274.0239563	0.07
284.0211182	0.83
285.9625854	3.32
287.9227905	5.88
289.8145142	2.72
300.2373352	0.24
301.7964478	39.12
303.9364624	3.47
314.0314331	1.54
320.2326965	0.15
321.6721802	0.18
327.8088684	1.82
329.0024109	2.48
329.8180847	9.71
331.9339905	100.00
342.8722534	0.12
345.2244263	2.82
345.8772583	17.60
347.8296509	2.21
357.6784363	0.36
358.8337097	0.35
371.3670044	0.17
372.1650696	0.31
373.6578674	3.53
374.3834839	0.07
375.9534607	0.15
389.0449219	0.43
391.7918396	37.99
392.5256348	0.49
395.0199280	0.14
399.8630676	2.15
403.2510071	0.12
417.9073792	72.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Isovitexin
Peak:m/z	Relative Intensity
137.034668	0.02
243.1700134	0.02
255.1229248	0.02
269.1830444	0.25
280.9627686	0.09
283.116272	0.34
287.2860107	0.02
293.1282959	0.06
309.2635498	0.17
311.0532837	100.00
312.0483704	0.35
321.0992432	0.08
323.0692139	0.17
325.1651001	0.02
337.3167114	0.13
341.0767517	12.57
341.7537842	0.01
353.067627	0.85
355.1696167	0.26
365.3687439	0.08
367.1795959	0.02
371.0221558	0.17
377.0978088	0.24
383.0571594	0.32
385.3174438	0.03
395.2303162	0.39
413.106781	2.30
414.2575684	0.02
421.7744751	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.211
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
104.8935699	0.20
109.0201416	0.04
119.2924271	0.17
121.1560669	0.18
122.9472351	0.27
124.8648987	0.09
131.2093506	0.13
133.0159912	1.39
136.7363586	0.19
139.1563721	0.13
141.1782532	0.09
143.1790466	0.23
144.2218933	0.08
147.2472382	0.11
149.1123352	0.20
150.9871216	0.16
154.9559326	0.24
156.9049377	0.15
159.0166016	0.12
161.1372681	0.07
164.9997253	0.57
167.2090454	0.07
169.0684967	0.07
170.8090820	0.05
173.2186890	0.18
174.0080261	0.15
177.2664032	0.12
179.9907837	0.09
180.8734131	0.35
182.9024658	0.26
186.9556580	0.07
189.2252808	0.15
191.1702576	0.05
192.8867340	0.32
195.1112061	1.87
197.1668701	0.03
199.0565033	0.25
203.9088440	0.07
204.8404388	0.84
207.0457916	0.24
209.0999146	0.11
210.2306213	0.10
213.0102234	0.10
215.2829590	0.32
217.0909271	0.04
219.0058289	0.07
223.1095581	1.20
225.0693359	0.27
226.2198486	0.07
227.0211182	0.13
229.3594666	0.46
230.9991150	0.43
232.6157837	0.03
235.0990295	0.04
236.9687805	0.59
238.0622864	0.25
239.1577148	1.00
241.2371216	1.55
245.1256409	2.15
247.2104797	0.36
248.9689941	0.68
251.0133972	0.18
254.3871765	0.05
255.0953064	0.03
257.2814026	1.06
259.2625122	0.15
261.1861572	3.45
263.2069397	4.89
265.0621033	0.19
267.1677856	8.72
267.7897949	0.12
269.2315369	0.14
269.9509888	0.07
271.1087646	1.28
273.0867310	1.19
275.2814941	0.71
275.9370728	0.27
276.8481750	0.33
279.1662598	0.26
279.8734131	0.08
283.1592102	16.24
285.2060547	15.02
287.2038269	1.40
289.2967224	0.32
291.6790771	0.20
293.1305542	0.15
294.5358582	0.25
295.2701111	1.78
297.1611938	0.20
299.0814819	0.16
301.1298828	3.58
303.1555786	3.31
305.1840210	1.05
307.1204224	0.21
311.0986633	0.34
313.1254272	28.24
313.7600403	0.10
319.2821960	0.28
321.1383972	1.28
323.1333923	0.39
324.5892029	0.19
325.3566895	0.05
331.1505127	24.74
331.7579651	0.08
332.4541016	0.15
337.4884033	0.22
338.9957886	0.39
340.2331543	0.25
345.2481079	0.39
347.0310364	0.22
347.7959290	0.06
349.1433411	100.00
350.2418518	0.55
351.1096802	0.05
351.9001770	0.19
357.9837952	0.72
367.0973511	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0666
Annotation	Maximaisoflavone F
Peak:m/z	Relative Intensity
108.9920654	0.01
116.9896317	0.10
134.9591217	0.01
149.2507324	0.12
151.1835632	0.07
161.0428467	0.22
164.1080627	0.15
177.1625366	0.10
179.0660400	1.08
180.0804138	0.02
187.9727783	0.07
191.1699219	0.02
195.2037506	0.04
200.9651489	0.01
203.1233368	0.25
204.2209015	0.13
205.3222656	0.02
218.1975708	0.05
218.9385986	0.01
221.1055908	0.51
224.9769287	0.20
226.9016113	0.01
228.9334717	0.07
235.0270996	0.12
240.2339478	0.08
247.0245361	0.47
253.2598877	0.04
261.4143677	0.02
267.2010193	0.38
269.0430603	17.84
270.1642456	0.82
273.2582703	0.02
279.1675720	1.59
281.0616760	11.27
282.0544434	6.08
283.0764160	15.10
284.1051025	1.26
293.1546326	2.20
295.0590515	12.66
296.1051331	0.59
297.0545959	0.16
304.7885742	0.05
308.1409302	0.61
309.3107605	0.26
311.0628357	6.06
312.2307129	0.47
313.2661743	0.08
321.0696411	1.11
323.0919189	100.00
324.1062012	6.45
339.3811035	0.04
341.1390076	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7278748	1.03
296.7503357	10.77
379.9779663	3.21
380.6165161	55.98
433.9072266	0.25
461.6348267	0.17
464.4273071	100.00
465.2595825	0.13
487.9194336	0.08
501.7478638	0.72
521.3834839	0.16
531.0623779	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1815
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.9436798	2.76
117.0858536	0.23
119.0707855	2.38
125.0434570	0.04
130.9471436	0.89
135.0593872	0.09
142.9939270	3.38
147.0141907	3.36
147.9940796	0.17
148.9868774	1.28
160.5720825	0.91
161.1805725	0.05
161.9024658	0.28
162.9479065	4.60
164.1441040	7.00
165.0945129	2.54
169.1174927	0.26
178.8153381	1.43
181.2206573	0.14
191.0503540	5.05
193.1814575	0.17
199.0953064	0.08
203.1582336	0.18
206.9643860	0.32
209.0478516	100.00
209.8354034	0.04
211.1577606	0.77
227.0696411	7.60
228.1087646	0.24
232.9361877	0.07
247.2706909	0.55
249.2429504	0.26
249.9457397	0.18
252.9767456	0.15
259.2261658	0.21
269.2694092	0.11
283.2362976	0.44
288.1695557	0.32
299.3188171	0.59
305.2813110	0.18
327.4837341	0.22
343.1579590	0.10
353.3374023	0.73
369.2957153	0.28
371.1536255	37.75
372.3486023	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.4404
Annotation	Unknow
Peak:m/z	Relative Intensity
279.3615417	0.49
283.6406250	0.08
287.1079712	0.13
297.2703552	0.05
305.0267944	0.65
311.1509399	0.05
321.2050781	0.37
322.8305054	1.31
323.4307556	0.04
327.6329041	0.05
333.2551880	0.07
337.3612671	0.17
340.8407593	1.79
343.1594238	0.13
347.3912048	0.08
356.9006958	0.06
365.1439514	0.81
377.0399780	0.07
382.1204529	0.18
383.2038574	6.57
391.3721313	0.08
394.3629150	0.22
395.2347412	0.06
397.2111206	1.89
407.1466675	0.18
409.2917480	0.05
412.7174072	0.42
421.3384399	0.35
423.1961670	0.21
425.0724487	1.21
440.9107056	0.31
442.9799805	0.96
446.5056152	0.17
449.3386841	0.35
451.1788330	0.27
455.4521484	0.07
467.0607300	5.00
471.3934326	0.07
475.3385010	0.03
485.1505127	2.61
490.0097656	0.08
503.1373901	0.83
509.4107666	0.15
525.2042847	0.02
526.5076904	0.11
527.1885376	0.18
535.5504150	0.20
539.2222290	0.09
541.2884521	0.36
553.0615845	0.31
563.3574219	0.06
565.6197510	0.06
571.5291138	0.10
572.2843018	0.15
583.5882568	0.09
602.9711304	0.08
605.5138550	0.06
629.3215332	0.27
630.7689209	0.09
641.9466553	0.16
644.5487061	0.32
645.2968140	2.30
647.2481079	100.00
649.2655640	0.09
653.3612671	0.33
662.9664307	0.05
665.2734985	31.72
666.5911255	0.05
670.1808472	0.03
674.3705444	0.08
687.0578003	0.08
691.0552368	0.13
693.1687012	0.12
705.0018311	0.20
709.4973755	0.06
723.4039917	0.08
725.6680298	0.68
729.3179321	0.12
731.2479858	0.07
736.5311890	0.22
745.2100220	0.05
746.6204224	0.04
747.4083252	0.19
749.6019897	0.07
751.5599365	0.28
753.5346680	0.35
754.7639771	0.13
755.5285034	0.18
759.4037476	0.08
762.3978882	0.07
763.4038696	0.16
764.8705444	0.33
765.4714966	0.17
767.3850708	0.27
769.2969360	1.93
769.9003906	0.20
773.4786377	0.08
777.5418091	0.08
779.1707764	0.04
781.6657104	0.30
791.6994019	0.13
792.3053589	0.37
795.6101685	0.15
796.4539185	0.18
797.4781494	0.14
803.7174072	0.05
807.1781616	0.31
809.5446167	0.53
811.7617798	0.18
816.4951172	0.22
821.4136963	0.27
822.5079956	1.01
823.3614502	0.45
824.6907349	0.05
831.4716187	0.10
836.1453857	0.08
839.0184937	0.03
839.8036499	0.24
845.9723511	0.21
847.6549683	0.31
852.4519043	0.18
855.4494019	0.07
856.4055176	0.04
858.4097290	1.91
859.5277710	0.70
866.7313232	0.25
867.5411377	0.09
872.6693726	0.15
873.5333862	0.25
877.2559204	0.03
880.6894531	0.85
881.4159546	0.30
891.4114380	6.60
892.2763672	0.06
893.4143677	0.15
894.3148804	0.13
909.3360596	6.29
910.3162842	2.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2305
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9584656	0.70
178.9871521	0.03
183.1634064	0.15
189.2337036	0.04
193.1626587	0.03
199.0443115	0.02
201.1207275	0.33
209.2107849	0.10
234.2972412	0.42
235.1893005	0.03
240.6492615	0.05
251.7588806	0.03
253.1901245	0.08
263.7009888	0.15
264.3684082	0.09
264.9780884	0.43
269.2475586	0.06
271.0363464	0.08
275.1357422	0.12
279.3374634	0.02
281.2904053	0.03
288.8954773	0.06
295.0769043	0.04
298.6426392	0.09
299.2838135	0.06
301.1450195	0.02
306.6373901	0.06
307.3056641	0.07
309.1151123	0.11
313.2426758	0.05
314.1751099	0.03
317.1198730	0.02
321.3614502	0.06
324.9821167	0.91
330.3627319	0.13
331.3941040	0.13
343.4251099	0.74
345.3030396	0.63
346.5204468	0.03
354.0833130	0.12
355.1104736	0.02
357.0905151	0.06
361.2094116	100.00
370.9753418	0.03
379.0142822	0.22
390.4028320	0.02
391.2279663	0.05
403.2606201	0.32
404.2994995	0.06
421.2844849	0.02
426.2628174	0.10
438.1275635	0.04
445.4328003	0.05
447.0046387	0.15
451.3016968	0.15
455.2256470	0.08
461.1024170	0.23
462.3741455	0.14
463.3806152	0.12
467.7529907	0.05
469.5490723	0.02
472.3012085	0.01
475.1002808	0.14
477.1502075	26.33
477.7612915	0.13
478.9375000	0.44
481.1675415	0.23
490.4341431	0.03
493.0715332	0.17
496.9808350	0.03
504.1818237	0.11
505.1934814	0.78
508.2339478	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.1807
Annotation	Gravacridonetriol glucoside
Peak:m/z	Relative Intensity
147.1575470	0.13
165.7511292	0.04
175.1946106	0.27
180.8088379	0.06
193.3021240	0.05
199.1699066	0.03
210.1776581	0.03
216.0314331	0.02
217.2716370	0.06
223.1889954	0.03
251.8288116	0.09
254.1872559	0.06
269.3033447	0.01
274.3828735	0.03
281.4649353	0.04
283.1686401	0.04
289.1524048	0.02
299.1293335	0.20
304.5201416	0.02
315.2043457	0.03
322.2055664	0.23
328.1217041	0.05
331.2316284	0.02
335.4384155	0.04
340.0548096	0.42
355.1912842	0.03
358.0380859	0.22
360.1715698	0.08
364.1349487	0.09
365.2803955	0.02
366.1422729	0.41
370.0920410	0.04
372.2156982	0.02
373.1093140	0.06
374.3757935	0.08
382.1868896	0.52
384.0639038	0.16
387.8309326	0.06
389.8916626	0.07
391.0957031	0.12
397.0999146	0.07
399.5817871	0.09
400.1968994	1.35
406.4202271	0.18
411.9698486	0.04
415.2722168	0.04
417.1127930	0.05
418.0399780	0.02
422.1865234	0.04
424.2240601	1.42
427.3983154	0.07
430.6382446	0.24
433.3784790	0.19
436.0590210	0.11
443.5021362	0.03
445.2900391	0.04
447.6998901	0.19
449.1928101	0.04
451.0444946	0.03
453.9975586	0.14
457.2445068	0.04
459.3844604	0.09
466.1580200	0.46
471.1475830	0.07
479.0692749	0.06
484.1787109	5.02
484.7978516	0.03
488.3984375	0.06
489.3314819	0.03
497.6027222	0.02
502.1818848	100.00
502.8475342	0.20
504.1726685	0.02
511.3220825	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	354.192
Annotation	2'-Acetylheliotrine
Peak:m/z	Relative Intensity
108.8100281	0.10
122.8031616	0.08
129.9659882	8.44
136.8768921	0.06
139.9569244	0.80
140.8041229	0.07
142.9585114	0.07
145.2496643	0.07
149.1148987	0.39
153.0194702	0.18
155.8938904	0.15
157.2146912	0.04
160.9757385	0.87
162.9495087	0.11
165.0275879	0.70
168.1780396	0.05
169.9021759	0.12
177.0609131	0.96
179.1628113	1.44
180.5356598	0.06
186.7914886	0.07
192.0394440	0.74
194.0360870	0.34
198.0313873	0.05
203.1150360	0.17
205.3322906	0.12
210.1741180	0.05
218.3075256	0.49
221.8795166	0.04
223.1234436	2.94
225.0393677	0.13
227.1060486	0.11
230.1394958	0.95
232.1703491	0.08
241.0667114	0.06
246.2772827	0.31
248.2123718	4.95
252.8499146	0.10
254.8773804	0.09
258.1341858	0.04
259.0826111	0.09
262.3467102	0.09
265.3044739	0.14
269.9873657	0.31
274.2061768	10.31
284.1864929	0.13
292.1677856	37.48
293.3550415	0.04
295.2575073	0.07
298.2877808	0.07
308.1365356	0.12
310.1872253	100.00
315.7592468	0.07
318.1855469	13.60
325.4621887	0.14
326.0700073	0.17
335.5483704	3.94
336.1564941	52.44
336.8141479	0.26
337.4654846	0.11
339.2415161	0.06
339.9823914	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	907.5754
Annotation	Unknow
Peak:m/z	Relative Intensity
282.4788208	1.15
313.3589478	21.62
393.1009521	1.60
436.1094971	16.20
436.7592773	0.08
454.1245728	100.00
454.7551270	0.27
647.4288940	0.03
663.3170776	0.21
748.7988281	0.17
783.7085571	0.11
844.1574097	0.04
845.5270996	0.69
846.2711792	0.23
888.7009277	1.59
889.3925171	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.939
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0627441	0.01
158.9371796	0.19
199.0469666	0.02
203.1557007	0.02
216.8404694	0.09
229.0851746	0.13
245.1582336	0.08
246.2291870	0.04
247.2540894	0.05
269.7380371	0.04
271.2030640	0.29
272.9328613	100.00
277.2590637	0.05
294.6019897	0.08
296.0801697	0.01
311.9823303	0.03
312.9408264	0.07
315.2288818	0.02
325.0297241	0.05
329.0433960	0.02
331.1180420	0.02
340.2829590	0.03
341.1178284	0.40
342.2156982	0.07
343.0000000	0.30
354.7385864	0.04
356.9159851	0.06
358.0936584	0.01
358.7228699	0.03
368.1533508	0.03
368.8393555	0.22
377.1681519	0.11
386.9444275	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
140.0398865	0.05
152.7315063	0.05
195.9729919	0.23
214.0193176	1.73
224.2082520	0.02
227.2845154	0.12
255.1978455	100.00
348.4512329	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
69.9883423	0.07
70.9314423	0.89
72.9688263	0.07
73.9097748	0.07
78.7505188	0.08
79.9371796	0.12
82.0722656	0.11
83.0545502	0.28
83.8844223	0.28
84.9637756	0.87
87.9142456	1.88
92.9449616	0.39
94.1900787	0.10
94.8829803	0.43
95.8161621	0.67
96.8080750	0.17
97.8454437	0.33
99.5412750	0.27
100.8756256	0.46
101.8652802	2.18
103.9808350	0.12
106.0256348	0.05
106.9680634	0.30
107.9534454	0.38
108.8831329	0.21
109.9063568	0.15
110.6454468	0.08
111.9636230	0.27
114.9796600	0.14
118.8614655	0.14
121.1700745	0.35
122.1663208	0.38
123.7694855	0.07
125.2944641	0.07
125.9833832	0.15
127.1897888	0.10
128.0442657	0.27
128.8910828	0.39
129.9909058	16.74
133.1172485	0.11
134.8625641	0.08
136.1361237	0.04
137.0574036	0.09
137.9306183	0.07
138.7958221	0.10
139.9768982	0.15
140.5873871	0.11
142.1964874	0.41
143.5205994	0.06
146.0506744	0.13
152.9693451	0.74
154.0546112	0.54
156.1312714	0.36
156.9018707	0.35
158.8050385	100.00
160.9259796	0.08
161.9074249	0.14
163.1790924	0.19
164.1069183	1.04
164.7488251	0.09
169.5594940	0.12
171.0292053	0.23
172.1124420	3.91
176.8111115	1.05
179.0011139	0.65
179.9784088	0.10
181.1461639	1.55
182.0853271	3.39
182.9529572	0.28
184.0963745	0.08
194.6833954	0.08
199.9724274	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	545.0604
Annotation	Quercetin 3-(3''-sulfatoglucoside)
Peak:m/z	Relative Intensity
208.1203766	0.20
229.1413269	0.16
322.3668213	0.13
327.1610107	0.34
342.8839722	0.23
369.0774536	0.17
377.0789185	0.15
378.3212891	0.09
384.0170898	0.97
388.1435547	0.20
393.3357544	0.08
396.1402588	0.05
398.9864502	0.10
414.1851196	0.31
415.1736450	0.36
416.0320435	0.33
424.1073608	0.10
425.1970825	0.48
426.3264771	0.45
428.0069580	0.04
433.2426147	0.37
443.9039307	5.82
449.3621826	0.07
455.8329468	0.73
457.1118774	0.14
462.0122681	0.13
468.0301514	0.23
470.6676025	0.20
474.1273804	0.50
475.6025391	0.37
478.4028931	0.25
484.9647827	0.11
485.9950562	1.84
490.5740356	0.04
498.2363892	0.05
499.0440063	0.07
503.8939819	100.00
504.5149536	0.77
509.3682251	0.51
515.1267700	0.52
516.9927368	0.14
520.9398804	1.72
521.7778320	17.06
522.9279785	0.37
526.4530029	0.73
527.1461792	1.04
544.4830933	0.26
545.1470337	0.14
546.2784424	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	636.3865
Annotation	Unknow
Peak:m/z	Relative Intensity
183.9276276	0.22
198.8819275	0.16
208.0115204	0.14
233.3608856	0.11
239.1308594	0.19
242.0005646	0.29
262.9843445	0.25
268.2263794	0.04
275.3515930	0.26
282.3436584	0.12
285.0935669	0.15
301.2681885	0.30
306.1456909	0.37
310.6462402	0.21
313.0388184	0.29
323.4808960	0.23
337.3980103	1.46
362.1245728	0.71
372.1596680	0.23
380.1096802	0.72
402.1990356	0.20
407.2668457	0.06
417.3112183	0.17
424.2962646	0.51
433.3292236	0.16
436.2926636	0.13
447.5158691	0.72
452.2812500	0.09
472.1288452	0.13
477.3957520	10.26
480.5925903	0.16
493.5341187	0.06
495.3125610	100.00
495.9265747	0.38
496.6267700	0.53
501.4714355	0.34
520.5277710	0.25
529.7446289	0.21
531.1782227	0.09
533.4601440	0.28
556.9516602	0.32
558.4249268	0.39
576.2463989	0.10
577.4786987	0.08
580.4195557	0.34
591.4116821	0.29
593.2760620	0.67
595.5202026	0.37
600.3020630	0.22
605.2162476	0.56
615.8877563	0.47
618.3690186	42.41
620.3953857	0.52
627.6882935	0.37
635.5667725	1.07
637.6227417	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1071.5377
Annotation	Hoodigoside O
Peak:m/z	Relative Intensity
481.3180237	0.01
551.7542725	0.09
578.9846191	0.06
597.7102051	0.04
623.4011230	0.12
641.4506836	0.23
648.4310303	0.04
655.4597168	0.06
685.4263916	0.05
701.2020264	0.08
702.4255371	0.10
720.4544678	0.07
739.4359741	0.08
741.7695923	0.04
745.3491821	0.02
759.4462891	0.16
770.4638672	0.03
793.3983765	0.03
801.1047363	0.19
821.3083496	0.02
863.5122070	0.03
873.8865967	0.04
896.8442383	0.04
897.5731201	0.14
905.5960693	0.16
910.0516357	0.06
912.6589355	0.03
925.5583496	0.02
932.5064697	0.03
941.4266357	0.02
949.4038086	2.20
954.6342773	0.07
955.8320312	0.18
967.4818115	100.00
968.1236572	0.24
973.7802734	0.05
977.7658691	0.08
984.5854492	0.05
993.4285889	0.03
1011.4609380	6.46
1012.1767580	0.02
1027.3308110	0.04
1034.3338620	0.10
1039.4091800	0.36
1043.7326660	0.05
1053.3995360	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.2174
Annotation	Saframycin B
Peak:m/z	Relative Intensity
159.9532318	0.20
165.8982697	1.10
176.7792358	0.04
194.9242859	0.15
203.9546967	0.89
206.0104370	0.23
210.0817719	0.10
215.1871643	0.23
227.1416931	0.21
228.8304138	0.14
234.4091644	0.11
242.9682617	0.04
245.0467529	0.11
247.0916595	2.46
253.0683899	0.12
260.0740967	1.65
261.2578125	0.04
264.3267822	0.06
270.2547607	0.19
273.0413208	1.74
275.3490601	0.17
287.4546204	0.12
288.8474121	0.16
290.2670288	0.08
292.1237488	0.41
294.8938599	0.20
299.1314697	0.14
300.3250732	0.52
302.2567139	0.08
309.1934204	0.08
311.1418457	0.16
313.0005493	0.83
313.7236328	0.30
321.2521973	0.05
325.1752319	1.79
327.1838989	0.13
329.0761719	0.20
333.0808105	0.04
339.1878052	0.08
341.1455078	2.94
347.1093140	1.34
353.0736694	0.22
353.9335327	0.13
355.1471558	0.11
356.9673462	1.71
357.7522583	0.08
360.4730225	0.20
367.2149658	0.10
368.2828979	0.05
369.1545410	0.33
373.0643921	9.28
374.2817993	0.09
375.2743530	0.46
376.1884155	0.70
377.2368164	0.35
379.2502441	0.07
385.2612915	1.47
390.4196167	0.34
391.2512207	0.07
405.6410522	0.08
408.9810181	0.22
413.5180664	0.20
416.1343384	0.04
422.3065186	0.13
433.5564575	0.08
436.2044678	0.05
437.1163330	0.17
440.5848389	0.37
444.4512329	0.41
460.2136230	0.29
462.1202393	0.10
465.2560425	4.66
473.4401245	0.21
475.4935303	0.65
478.0223389	2.04
481.2797241	0.08
488.3034058	0.96
490.2344360	0.76
492.1636353	1.38
494.1276245	0.07
502.3501587	0.32
503.3958130	0.28
506.1611328	100.00
506.8337402	0.12
510.1535645	3.82
519.2609253	1.07
520.1609497	8.27
521.1928101	0.07
528.6610718	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0967
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
118.0612335	0.01
132.0224915	0.01
159.1944885	0.19
187.9602509	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	699.3542
Annotation	Denin
Peak:m/z	Relative Intensity
211.1834564	0.14
226.4205933	0.10
230.2800598	0.18
239.0646515	0.07
245.0262299	0.11
246.3668213	0.03
259.3992310	0.09
266.0537109	0.04
287.3706055	0.05
300.6987000	0.11
305.1261597	0.15
311.1479492	0.08
319.0767212	0.25
325.4014282	0.04
327.2843018	0.03
337.6915283	0.09
339.5225220	0.13
342.7521973	0.20
345.2819519	0.11
347.2304688	2.59
348.0023193	0.16
355.1034546	0.03
365.2493286	0.24
368.0872803	0.12
372.9733887	0.06
375.4264526	0.22
376.2960205	0.04
393.2422485	0.14
394.1080322	0.11
405.1729126	0.10
407.2262573	0.23
412.3302002	0.09
421.1862183	1.07
446.7863770	0.09
447.8328857	0.06
455.2595215	0.17
469.0703125	0.02
509.5756836	0.09
512.4959717	0.07
513.2080688	0.19
519.3964844	0.25
520.6718750	0.06
525.6100464	0.07
537.3383179	100.00
538.3959351	22.39
540.5128784	0.20
557.3822632	0.36
571.2669678	0.19
577.4221802	0.23
579.3682251	0.14
588.9703369	0.08
591.4913940	0.21
592.2288208	0.04
608.3992310	0.04
609.2546997	0.16
617.4042358	0.81
618.0102539	0.13
625.8153687	0.05
626.9550171	0.11
628.3133545	0.10
629.1104736	0.04
636.4500732	0.12
643.3778687	0.21
644.2570190	0.02
646.2033691	0.22
655.4423828	0.09
661.9772949	0.29
663.8444824	0.28
678.1798706	0.08
680.2071533	0.48
681.2780151	0.88
699.1284790	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	941.4734
Annotation	Cynarasaponin D
Peak:m/z	Relative Intensity
271.0598145	0.11
273.1985779	0.12
288.9629211	0.07
307.0879517	4.39
308.0124512	0.02
325.1623535	4.07
326.0842590	0.41
329.3199463	0.09
332.9445190	0.28
351.2524414	0.10
364.9555054	0.04
367.0316772	0.29
367.9268188	0.27
377.4338379	0.11
379.0413818	0.05
391.1910400	0.66
392.3598328	0.24
393.1665649	1.97
394.1177368	0.04
394.9065247	0.37
396.0344849	0.08
403.3456421	0.06
407.0231934	0.18
409.0616455	0.08
421.0715332	3.91
422.1810913	0.48
437.4415283	0.38
438.4469604	0.16
439.1078491	0.48
440.2415161	0.09
441.0256348	0.07
457.1193848	0.06
458.5468750	0.15
465.2756958	2.37
466.3349609	0.50
467.6892090	0.03
468.7794800	0.20
483.1066284	100.00
484.1278687	16.74
493.1559448	0.04
495.2716675	0.10
506.4275513	0.22
525.2783203	0.21
528.5653687	0.12
570.1831665	0.09
595.4562378	0.04
597.4464111	0.37
598.5030518	0.12
613.4116821	0.15
614.4428101	0.06
615.2258911	0.13
633.4622803	6.97
634.5573120	2.65
640.4566040	0.10
659.2023315	0.06
675.5824585	0.05
693.7025146	0.15
719.5158691	0.11
725.3356323	0.09
733.3159790	0.31
748.5885620	0.09
751.7246704	0.02
761.3815308	0.11
765.3929443	0.18
769.6433716	0.06
773.7804565	0.11
779.1947021	0.07
791.5195923	2.65
792.2543335	0.23
795.9885254	0.22
796.6005249	0.11
807.4057007	0.33
808.4381104	0.21
809.6091919	0.11
810.5143433	0.52
811.2722778	0.17
818.4313965	0.03
822.8035278	0.07
824.1326904	0.05
826.4527588	0.13
835.2872925	0.39
835.9412842	0.09
836.6375732	0.17
837.5965576	0.02
848.6853027	0.05
850.6281738	0.11
857.3623657	0.04
864.4320068	0.11
879.5262451	1.87
880.5278931	0.72
884.2006836	0.15
889.4801636	0.17
890.5559692	0.13
891.3455200	0.04
895.6043091	0.04
896.4095459	0.38
897.5459595	1.09
898.5267334	0.36
905.3078613	0.44
906.6560669	0.10
923.4153442	11.53
924.4659424	5.34
925.2130737	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2443
Annotation	Ligurobustoside A
Peak:m/z	Relative Intensity
144.9077911	0.13
161.0708771	0.09
163.0127716	3.31
163.9572754	0.78
205.0031738	0.62
234.5110779	1.07
235.3813171	1.24
236.1832581	0.10
264.9589233	1.73
265.9125977	1.11
283.1720581	0.17
289.1994934	0.30
295.0953979	1.01
301.3026123	0.08
307.2243958	0.54
308.2536011	0.11
311.0630493	0.47
312.1493225	0.10
323.3162537	0.08
324.8740845	0.84
325.9469910	1.45
344.2659302	0.05
346.3927307	0.32
359.0505371	0.09
363.2697754	0.11
364.0495300	0.23
365.0968018	0.08
366.2446899	0.61
388.3841553	0.18
396.3646545	0.25
416.7225647	0.16
434.3636169	0.15
448.3696594	0.06
461.1711121	12.34
462.1947327	100.00
463.4421082	0.20
464.3468323	0.60
466.1659546	0.11
472.6430054	0.07
480.1670532	0.08
490.3357849	0.34
506.3562622	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
149.0793915	0.00
161.1442719	0.01
173.1491699	0.01
179.0745087	0.03
189.0368347	0.02
227.5473633	0.01
243.1793823	0.01
252.2133484	0.01
269.1612244	0.17
270.1123657	0.04
280.9927368	0.06
282.5247192	0.02
283.1608887	0.33
284.1998291	0.06
287.1424255	0.01
293.1327515	0.06
295.2236938	0.02
307.3603516	0.01
308.9840698	0.03
311.0598145	100.00
312.0732422	28.47
312.6763306	0.07
317.3734436	0.02
319.4262695	0.02
321.0405273	0.06
322.2020874	0.00
323.2494507	0.23
324.111145	0.13
325.1645813	0.01
326.1838989	0.01
328.0622253	0.02
330.1916504	0.01
335.1451721	0.02
337.1386719	0.07
337.8778076	0.02
339.3382874	0.02
341.1099854	12.21
342.2058105	3.86
347.9545288	0.02
349.3464355	0.02
350.1364746	0.01
351.0492859	0.03
353.1268616	0.79
354.0726318	0.21
355.149292	0.27
356.228241	0.07
365.0845032	0.12
366.1093445	0.02
367.0304565	0.02
368.3037415	0.06
369.3822327	0.01
371.0362244	0.22
372.1075745	0.11
377.2226562	0.12
378.2385864	0.06
383.1845398	0.25
384.2036438	0.15
385.3683777	0.01
387.7367554	0.04
395.113739	0.22
396.2319946	0.09
401.495575	0.02
413.131958	1.28
414.2148132	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.4863
Annotation	Acankoreoside E
Peak:m/z	Relative Intensity
310.1285400	0.11
344.2665405	0.07
407.4422607	0.10
421.3582458	0.08
422.5093994	0.10
423.4863281	0.11
424.9488525	0.08
439.4512329	1.62
440.4284668	0.50
441.8314209	0.11
465.1757202	0.59
467.5444946	0.35
468.3081665	0.21
469.3655396	16.33
470.4631348	7.26
483.2701416	0.30
483.9572754	0.07
485.3673706	1.56
486.4108276	1.10
487.3890381	5.85
488.4579468	2.44
489.8042603	0.09
495.6503296	0.30
497.2313843	0.65
498.5491333	0.26
513.4312134	0.08
516.3553467	0.25
523.4996338	0.22
525.3437500	0.52
529.6428833	0.41
530.4183350	0.35
544.2716064	0.15
555.4491577	8.39
556.4171143	4.14
557.5929565	0.43
565.5975952	0.19
567.4159546	0.05
569.3855591	2.41
570.3015137	2.54
583.3306885	0.98
584.4429932	0.61
599.5394287	0.10
601.4148560	8.93
602.5347290	5.60
610.3433838	0.13
619.5483398	0.83
620.4895630	0.39
627.3298950	5.06
628.2819824	2.54
630.2393188	0.19
641.5031128	0.07
643.5281372	0.31
645.4001465	56.55
646.3876953	34.30
647.0239258	0.29
655.6054688	0.07
663.5014038	0.51
666.1318970	0.53
688.4755249	0.22
728.3956299	0.16
745.4612427	3.43
746.4856567	0.88
748.2896729	0.05
763.4298706	12.48
764.5326538	10.23
765.5579224	0.04
774.2764282	0.17
781.4718628	3.17
782.4304199	1.21
791.6652832	0.26
793.4227905	0.37
807.3637695	0.11
808.6647949	0.59
809.4125366	0.08
810.2237549	0.26
811.3633423	0.18
825.7192993	1.93
826.5710449	1.37
828.7142944	0.23
837.7206421	0.23
838.6150513	0.53
843.3564453	0.09
851.2936401	0.13
866.0944824	0.23
867.4729614	0.41
883.3636475	0.27
899.2289429	0.08
900.3666382	0.12
909.4898071	100.00
910.5352173	79.93
911.6300049	0.14
912.5260010	0.05
927.4548950	6.99
928.4613647	8.62
936.6412964	0.22
942.4377441	0.17
953.3894043	19.66
954.4982910	15.12
956.9277954	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	310.093
Annotation	Zierin
Peak:m/z	Relative Intensity
88.9512482	0.12
96.9257202	0.16
98.9673691	0.09
101.0172882	2.02
104.9617462	0.35
110.8268280	0.09
112.9572144	3.13
114.8268585	0.12
115.8405151	0.48
116.9072723	0.09
117.9666138	0.35
118.9972839	2.39
119.9190369	0.05
125.1303101	0.17
127.9616852	0.30
130.2552643	0.47
130.9664154	2.12
131.9865112	7.82
134.0620422	0.16
135.0431976	0.53
141.9323425	0.10
142.9427490	1.21
144.0773315	2.20
145.9773865	9.77
147.0836945	0.99
148.0021820	7.24
148.8759003	0.45
150.0276489	0.39
151.9252319	0.10
154.1586151	0.15
157.2068481	0.10
158.0008850	1.72
158.6110077	0.11
159.9602661	100.00
160.9830933	0.45
161.8207092	0.17
164.0139771	0.53
165.9341125	0.78
170.0522766	0.87
172.0209351	10.05
174.0717316	15.24
175.9106140	1.65
178.0838623	1.52
178.8803864	2.69
180.1489563	0.04
181.9522095	0.14
183.9252472	0.83
185.4058533	0.33
186.0893250	6.03
188.0739441	0.46
189.9954987	1.61
196.0885010	1.34
197.1696167	0.06
198.1497192	0.78
199.9561615	1.92
202.0594940	50.86
204.0422668	7.70
208.5791931	0.09
212.1910095	0.47
214.0756836	15.89
216.1173096	1.45
218.0242615	0.39
220.1618042	0.56
222.0652771	0.70
225.9718628	1.63
227.9593201	0.59
231.9801025	11.44
238.1784973	0.14
244.0500793	0.45
245.9817505	0.22
248.0829468	0.13
256.1825562	0.18
264.0052490	2.67
267.8403625	0.06
273.9255066	0.07
280.2966309	0.06
291.0494080	0.15
292.0425415	0.35
295.1531372	0.21
310.9751587	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5074
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
222.1136169	0.16
255.1704102	35.47
256.1289673	0.27
261.2035828	0.36
277.2185974	0.37
279.2322388	100.00
279.837616	0.19
281.3683472	0.16
286.2553101	0.11
294.9960022	0.25
310.3963013	0.14
327.1280823	0.07
335.1005859	0.48
340.1679077	0.07
371.3694458	0.22
378.0567017	0.38
413.3153687	0.16
415.1914673	0.05
419.171936	0.18
420.2141724	0.05
432.1571045	0.21
433.7927246	0.07
434.4124756	0.68
450.1340332	0.25
452.3383789	14.02
458.1883545	1.54
459.1845703	0.22
462.3467407	0.16
476.2038574	1.88
492.3538208	0.28
552.5448608	0.33
568.125061	0.11
579.4249268	0.26
594.8447266	0.09
603.7451172	0.14
607.3241577	0.11
628.9702148	0.31
639.331604	0.11
640.2610474	0.08
655.354248	0.49
667.72052	0.24
670.1325073	0.13
671.6239624	0.11
678.5932007	0.37
695.1350708	0.14
696.0661621	0.82
696.8103027	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1664
Annotation	Diosmin 
Peak:m/z	Relative Intensity
202.1557617	0.03
210.8790894	0.04
219.8651123	0.03
234.6446838	0.08
256.0862122	0.08
259.3353882	0.02
263.1010437	0.06
265.3338013	0.04
282.270813	0.19
284.006958	12.80
284.84375	0.06
297.2732544	0.15
299.0519104	100.00
302.0458374	0.06
312.2067261	0.04
321.1727295	0.03
325.0429077	0.04
327.1958008	0.08
328.0501709	0.02
329.0390625	0.06
338.1681519	0.13
341.196167	0.10
343.9996948	0.10
352.3378296	0.08
355.2752075	0.29
356.7131958	0.27
364.9719238	0.03
372.194519	0.03
385.9879761	0.11
391.2781372	0.06
402.1818848	0.05
403.1395264	0.09
408.2947998	0.13
409.8562622	0.10
412.5834961	0.03
425.0687256	0.12
427.3416138	0.54
431.2791138	0.12
441.151062	0.16
443.1954956	0.03
445.4242554	0.05
457.3886108	0.02
458.4380493	0.04
459.3259277	0.11
460.21521	0.06
463.3082275	0.09
468.1494751	0.03
469.3082275	0.01
473.2841797	0.05
481.4247437	0.04
482.0580444	0.03
487.0509033	0.55
488.2125244	0.27
502.1065674	0.04
511.5557251	0.06
517.1517944	0.43
518.0541992	0.05
519.1696777	0.06
520.3452759	0.03
521.3702393	0.06
523.2602539	0.05
529.3079224	0.35
532.0189209	0.10
539.4710693	0.05
542.3685913	0.06
542.9887085	0.02
547.4408569	0.13
559.1411743	0.20
560.0805054	0.05
561.3123169	0.66
562.1841431	1.74
562.8874512	0.18
563.4877319	0.17
571.3169556	0.26
577.5982666	0.02
583.2241821	0.19
588.2228394	0.11
589.2059937	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	918.1246
Annotation	Unknow
Peak:m/z	Relative Intensity
272.4482727	0.02
285.9556274	0.02
307.0846863	0.02
313.5812683	0.10
353.1279602	0.10
370.1237793	0.13
379.0465698	0.02
380.0457764	0.06
382.0639038	0.06
384.0628662	0.05
392.1938477	0.04
395.9561462	0.19
398.1211548	0.12
398.9708557	0.05
408.2283936	0.14
423.0794678	0.07
426.0346680	0.18
433.1423340	0.14
437.4165039	0.06
438.1110229	0.37
438.8150635	0.02
449.9973145	0.02
451.0427246	0.15
460.9154663	0.06
466.3831177	0.13
467.8927612	0.21
469.0443115	0.03
470.2731323	0.05
485.0691528	0.25
485.9357910	0.16
487.2063599	0.11
492.0819092	0.06
503.7487183	0.09
528.2313232	0.11
530.1598511	0.13
540.0927124	0.08
546.0687256	0.26
549.2328491	0.06
558.0194092	0.14
606.8794556	0.14
607.9937134	0.05
612.8181763	0.07
613.7053223	0.16
617.7873535	0.02
622.3421021	0.06
627.2244263	0.02
636.0596924	0.40
644.5156860	0.06
648.3202515	0.29
649.2262573	0.20
649.9640503	0.10
659.9199829	0.09
666.0454712	0.34
669.4678955	0.09
674.2898560	0.04
677.1303101	0.78
678.0736694	14.88
679.1870728	0.08
680.1358032	0.14
684.1679077	0.04
690.0003052	0.48
694.5009766	0.08
695.2994995	0.08
700.8978882	0.08
702.0910034	0.79
708.0168457	6.38
709.3105469	0.16
714.0775146	0.30
719.4257202	0.23
720.0994873	0.07
726.1889038	0.25
730.9906006	0.12
732.0996704	1.38
733.2625122	0.03
738.2573242	1.01
739.1373901	0.06
744.0692749	1.33
750.1875000	0.24
751.8534546	0.35
752.5361938	0.04
754.8317871	0.09
756.1602783	0.98
757.0736694	0.02
761.0753174	0.06
762.2128906	1.37
767.9813843	0.61
769.1218872	0.39
773.8749390	0.25
778.9465332	0.43
780.0624390	9.29
780.8482666	0.32
783.1768188	0.05
792.1130981	0.51
796.2552490	0.69
798.0390015	100.00
798.7518311	0.72
804.0444946	0.75
808.0526733	0.08
810.0599365	2.82
810.6846313	0.07
815.8696289	0.02
816.4978027	0.06
820.8651733	0.10
822.1643066	1.12
826.5881348	0.42
828.0746460	14.62
829.0101318	0.59
829.9909058	0.28
830.8382568	0.45
832.0314331	0.06
834.1918335	0.63
838.1235352	0.02
839.9738770	0.52
841.0797729	0.21
845.9357300	0.80
851.7530518	1.30
852.4931641	0.45
854.4631348	0.05
857.3417969	0.14
862.8920288	0.18
864.1284790	3.61
869.1696167	0.03
873.7640381	0.06
881.2203979	0.52
882.1088257	6.89
899.5917969	6.04
900.2372437	19.92
918.4476929	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	666.24
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
194.9414978	17.74
248.8299561	1.29
303.2567749	0.34
306.8736572	0.25
309.7603149	0.30
320.6630859	1.72
324.9860229	15.12
338.8042603	4.34
339.4876099	0.70
355.2632446	1.52
356.1318359	6.80
356.8772583	100.00
445.3847046	0.14
462.9260254	0.12
472.4726562	0.17
481.7578735	0.68
504.1135254	1.09
518.2180176	9.88
518.9066772	51.93
609.2256470	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	622.1897
Annotation	Unknow
Peak:m/z	Relative Intensity
184.0916443	0.36
189.9559784	1.86
252.0863190	0.20
265.0757751	0.14
270.2541199	0.20
287.3645630	0.19
295.3013306	0.39
311.3651428	0.22
314.9729004	0.15
322.0935364	0.05
331.9937744	0.13
337.0866699	0.27
343.1389771	0.19
345.1284790	0.08
361.2489624	0.74
365.3547363	0.15
367.1417236	0.42
370.9078369	0.07
374.5207520	0.40
380.1406860	0.66
385.0699463	4.36
394.2586670	0.19
406.2330322	0.15
415.0837402	0.19
423.6377563	0.11
433.1099854	11.00
439.2621460	0.29
445.2440796	0.24
450.9760132	0.59
456.0361938	0.24
457.3132324	1.26
460.2619019	0.22
461.0507202	0.09
461.8515015	0.10
464.1661377	1.31
465.3009644	0.19
466.3001099	0.30
468.8958740	0.51
472.1485596	0.23
475.0824585	0.36
476.1200562	0.22
481.5657959	0.36
483.2336426	0.54
483.8812256	0.63
487.2720947	11.44
489.5345459	0.16
493.1983032	0.14
500.5550537	0.36
501.4700317	0.22
502.1128540	0.77
505.1566772	100.00
509.0366821	0.45
513.7257080	0.55
514.6454468	0.38
519.5713501	0.22
524.2236938	0.50
526.2116089	0.06
531.2382202	0.17
550.3576050	0.19
557.3397827	0.15
558.2731323	0.21
559.5198975	0.57
568.1513062	1.19
568.8755493	0.20
574.2477417	0.15
578.6278687	0.67
586.2570190	9.59
589.0258789	0.09
590.3679810	0.22
593.5959473	1.59
594.3491821	0.08
603.2719727	0.93
604.1578979	6.91
605.4716187	0.23
613.5452881	1.43
615.4379272	0.84
622.9709473	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
213.9375	0.24
224.8342285	0.03
234.8025818	0.04
237.0682678	0.30
241.1853027	0.23
251.3838501	0.03
255.2543488	35.29
257.4684753	0.13
258.2473755	0.09
261.2358093	0.20
275.526123	0.09
279.2297974	100.00
279.8415527	0.47
289.2306824	0.06
293.1338501	0.73
294.3359985	0.33
295.2296143	0.05
305.0390625	0.26
305.9613647	0.28
306.5924072	0.08
309.197876	0.05
311.0178833	0.11
340.8161621	0.04
373.6694946	0.13
391.2055054	1.39
392.3198242	0.13
397.1092529	1.34
398.2421875	0.03
402.3518066	0.25
415.2634277	0.14
417.055603	0.07
420.4576416	0.13
433.8133545	0.07
434.4180298	1.92
437.729126	0.08
449.3880005	0.14
452.2697144	16.31
457.2512207	0.30
458.1724854	1.34
462.3790894	0.19
476.2549438	1.71
505.079834	0.07
508.2194214	0.21
518.8237305	0.29
554.4306641	0.23
555.6298218	0.08
564.1199951	0.06
578.6881714	0.14
595.3250122	0.13
608.9911499	0.08
611.8312988	0.12
614.1812134	0.22
618.47052	0.09
627.7133789	0.13
628.3300781	0.07
634.500061	0.25
646.3762207	0.08
648.2055054	0.33
655.2105103	1.12
663.4396362	0.05
664.2467651	0.18
668.3311768	0.06
677.3396606	0.07
678.3137817	0.28
691.2411499	0.28
695.447937	0.25
696.375	0.68
697.0484009	0.33
699.5341187	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
148.887207	0.01
161.1000214	0.05
178.958313	0.07
188.9356384	0.05
192.1038971	0.10
203.2504425	0.02
205.3927612	0.03
206.2731323	0.03
208.3253632	0.02
209.3996887	0.06
218.904129	0.04
221.388382	0.01
233.2759399	0.02
246.0690308	0.02
247.0819092	0.01
248.3600464	0.05
249.2549438	0.01
251.2266541	0.62
252.2258911	0.11
269.1434326	0.45
270.0658875	0.16
278.9877319	0.06
282.4129639	0.04
283.18927	0.36
284.0662231	0.14
287.3688354	0.05
288.494812	0.03
293.2471313	0.01
294.0546265	0.05
296.9914551	0.02
298.2875977	0.03
301.1671143	0.03
309.3522034	0.04
311.0619507	100.00
312.0658569	51.98
312.7252808	0.12
319.3007812	0.05
321.3473816	0.01
322.0641174	0.02
323.163208	0.35
324.2157288	0.06
325.2536621	0.06
327.1254272	0.04
328.2526245	0.02
329.287262	0.02
332.8926392	0.03
335.630249	0.05
337.1964111	0.08
338.1282959	0.09
341.105896	11.80
342.2009888	6.59
343.1706543	0.04
344.2189941	0.01
345.1793823	0.03
348.1333313	0.01
348.9858704	0.04
351.3840027	0.11
352.191925	0.07
353.1063843	0.36
354.2001038	0.44
355.0678101	0.22
356.207428	0.11
365.2805481	0.07
366.3414001	0.06
367.1800232	0.24
368.1720886	0.04
369.301178	0.01
371.2319336	0.37
372.2059631	0.09
376.4745483	0.07
377.1552734	0.07
378.247467	0.09
383.1221313	0.32
384.1663513	0.11
385.1078796	0.08
387.1512146	0.10
388.0294189	0.11
389.2341919	0.03
390.3733215	0.07
395.2643127	0.22
396.2036743	0.46
402.471344	0.01
413.1542664	1.70
414.0838318	1.13
415.9513855	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.22
Annotation	Crepenynic acid
Peak:m/z	Relative Intensity
95.1677780	0.92
96.9808960	1.42
115.0313644	0.73
135.1683502	1.98
141.2262268	0.82
147.1558838	0.31
149.2556152	0.31
153.1788330	0.43
162.9268341	0.99
167.9645538	0.27
171.3092957	0.35
172.9372864	0.63
177.0345764	1.05
179.1599426	0.97
190.9485779	1.70
205.1723633	2.35
208.0750122	0.34
219.1692505	1.42
233.2489014	100.00
247.3769531	0.51
249.4373474	0.68
257.2220154	4.71
259.2180176	31.07
261.3195801	2.73
275.0827637	0.34
277.4445801	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5074
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
208.6544037	0.10
213.0136108	0.08
227.2044983	0.17
235.0378113	0.14
238.9575043	0.15
247.0514679	0.42
255.1982727	36.12
277.2138062	0.24
279.2317505	100.00
281.0859985	0.18
283.3032837	0.34
293.2159119	0.19
294.3250732	0.33
295.4541016	0.08
296.6183472	0.20
302.0544434	0.19
312.0982056	0.15
324.8175659	0.06
329.3273315	0.78
347.1393433	0.37
353.3756714	0.09
370.9989014	0.15
388.5471191	0.13
391.2385864	1.25
406.6303711	0.06
408.7159424	0.10
416.1942139	0.19
421.4580078	0.10
434.3181763	0.44
436.4894409	0.06
452.3480225	16.76
458.2637939	0.91
466.0684814	0.26
475.7475586	0.53
476.4903564	1.94
564.477356	0.18
591.1841431	0.07
629.2474365	0.08
636.3739624	0.09
639.6390991	0.06
641.9837036	0.11
652.6248169	0.20
655.2924805	0.74
668.2209473	0.77
678.0683594	0.21
679.8406982	0.05
686.3053589	0.20
691.7504272	0.13
695.3388062	0.21
696.475769	0.64
697.9569702	0.20
705.333313	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	528.0999
Annotation	Unknow
Peak:m/z	Relative Intensity
173.1773987	0.07
179.8400269	0.06
228.0900574	0.06
241.0668488	0.12
243.1127472	0.04
276.1823730	0.04
285.2670898	0.06
291.0764771	0.03
297.6848755	0.08
303.0126038	0.15
315.9827881	0.11
331.3229370	0.04
333.0148315	0.16
337.9356689	0.07
347.1990967	0.49
348.1711426	0.04
350.3306885	0.10
363.2904663	0.21
365.2859497	0.23
366.0542603	0.43
369.3091431	0.08
399.2183838	0.08
408.0709839	0.18
412.1617432	0.12
422.0618896	0.08
423.0709229	0.08
425.1710815	0.05
438.1884766	0.04
441.3206787	0.06
441.9906006	0.13
453.4355469	0.04
462.2794800	0.08
465.2026367	100.00
467.6078491	0.47
468.3126831	0.10
479.6742554	0.58
481.1371460	0.08
483.1682739	0.37
499.2351074	0.23
509.9865723	1.85
511.3494873	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	708.3534
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9109802	0.26
239.0962067	0.09
245.3038635	0.11
249.5531311	0.07
253.9379120	0.35
258.1239624	0.14
263.1229858	0.25
265.0001221	1.48
265.9620667	0.39
266.8701172	0.61
283.1965942	1.37
284.0809937	0.30
295.1136169	0.11
296.2692261	0.17
297.1565857	0.29
303.0512390	0.28
305.1860046	0.95
306.9544067	0.18
309.2815552	0.37
310.9444580	0.31
320.0366516	0.06
321.1278687	0.33
322.1005249	0.24
323.1582642	5.08
324.1529236	0.54
332.8908081	0.47
334.1909790	0.46
335.2865906	0.09
336.2392578	0.25
343.4827881	0.18
349.4053345	0.28
351.2111816	2.15
352.2131653	0.06
359.0859375	0.09
361.3671875	0.40
362.3254395	1.87
363.2026367	22.27
364.2301025	4.22
365.0446167	1.37
365.6619263	0.29
379.1507568	1.45
380.0921021	5.49
381.1358032	100.00
382.1738281	10.05
398.0784302	0.34
399.4656372	0.49
419.9149780	0.31
457.5523682	0.11
458.7063599	0.17
465.4901123	0.22
478.0633545	9.34
479.1083984	1.84
508.3372192	0.29
517.2941895	0.69
518.0783691	0.15
521.0874023	0.07
539.5189819	0.38
554.5526733	0.11
557.5775757	0.32
558.2377930	0.76
559.2002563	0.06
565.4529419	0.27
576.3637695	0.77
577.3048706	0.96
579.5184937	0.10
593.1676636	30.91
594.2383423	11.77
595.0563354	0.38
609.1495972	0.07
619.2931519	0.54
632.1520996	3.36
633.1574097	0.78
637.6073608	0.10
644.4175415	0.13
649.3256836	0.09
650.9933472	0.22
659.5210571	0.43
662.7709961	0.48
664.3069458	0.27
673.1869507	0.16
676.4479980	0.27
690.4441528	2.10
691.3474731	1.98
699.2249146	0.20
700.2409058	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	663.4125
Annotation	Unknow
Peak:m/z	Relative Intensity
223.0315552	0.33
238.9266052	0.19
240.9757996	2.02
263.0624084	11.14
280.8670044	0.09
293.0285950	0.18
323.3244629	0.29
333.2228394	0.92
351.1859131	100.00
362.9109497	0.19
522.4714966	0.72
534.1677856	0.15
539.3447876	0.32
543.5974731	0.38
551.5568237	0.81
563.7374878	0.74
607.6179199	0.54
620.9662476	0.41
626.6707153	0.18
636.1394653	0.69
643.6071167	0.61
645.3672485	3.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1311
Annotation	CMP-8-amino-3,8-dideoxy-beta-D-manno-octulosonate
Peak:m/z	Relative Intensity
183.0217438	0.11
199.8858337	0.33
201.3638916	0.14
219.0805969	0.27
290.0074463	0.56
290.9723816	0.21
317.3604126	0.51
325.1434937	0.07
342.9871216	0.10
358.0919189	1.33
359.3062134	0.09
363.0661621	26.31
371.4237061	4.35
372.2312012	1.69
381.0722656	100.00
381.6775513	0.36
382.3762817	0.08
453.3617554	0.37
470.9391479	0.09
483.0582275	0.34
488.7346802	0.15
524.4100952	0.08
525.2716064	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1971
Annotation	Carolenalin 4-O-beta-D-glucoside
Peak:m/z	Relative Intensity
141.2441101	0.05
142.8823395	0.04
153.0480347	4.19
161.0487671	0.16
179.1659088	0.19
187.3835449	0.17
205.1404419	7.17
207.1652069	0.11
215.0284119	0.28
219.0846405	0.23
221.0710297	0.04
223.0293121	1.89
225.0011902	0.04
246.2398376	0.14
247.1265869	0.52
249.0088196	0.04
261.3855591	0.02
264.8601379	0.16
271.2325134	0.12
306.2052612	0.16
312.1350098	0.04
329.3386230	0.08
331.3991089	0.08
339.3241577	0.07
345.0506897	0.11
349.1069946	0.04
364.2917480	0.03
367.1101990	100.00
367.7633667	0.19
369.0855408	0.08
369.9527283	0.05
373.2268982	0.13
381.0338440	0.10
383.4817505	0.08
385.3048401	0.59
391.4769897	0.07
392.1892395	0.13
395.0644226	0.05
398.8901978	0.03
400.2184448	0.09
408.3116760	0.05
409.1841125	1.30
409.9601135	0.06
418.2621460	0.14
426.7274170	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
179.0580292	0.27
221.0710449	8.05
234.5594788	0.43
250.5664978	1.09
280.9026184	1.39
305.4108887	0.56
310.9676514	0.51
322.6669617	1.66
323.2783508	2.81
337.084137	0.14
340.9874878	35.18
383.1239624	100.00
397.0147095	0.23
407.2741089	1.00
412.6031494	3.54
425.2832642	1.57
442.9692383	29.03
467.1836548	0.19
485.1119995	32.78
485.8001099	0.24
500.2905273	0.39
503.0759888	6.90
545.0714722	4.29
575.9939575	0.72
593.3687744	0.58
619.1079712	0.82
621.3128662	0.61
645.2097778	0.51
646.9359741	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	620.3634
Annotation	Unknow
Peak:m/z	Relative Intensity
183.0267792	0.07
184.1301422	0.61
185.0546570	0.18
187.1882019	0.21
189.3614502	0.10
191.1332550	0.32
193.1375275	0.24
198.7044983	0.18
215.2893982	0.07
222.4533691	0.53
225.2663269	0.22
227.1609039	0.37
231.0132294	0.14
235.0704041	0.26
237.2192841	0.33
239.1623230	0.70
241.1647339	0.38
247.1262512	0.32
249.5027924	0.58
250.2622833	0.36
253.3046417	0.19
257.1238098	0.23
259.1052246	1.01
261.2017212	0.35
265.3057861	0.17
270.8169556	0.44
273.2916260	0.37
275.1834717	0.52
277.3571472	0.64
279.3559265	0.48
283.3421631	0.34
285.0858459	0.38
287.0466003	0.32
289.1882324	0.59
291.2076416	0.63
293.4218140	0.19
296.9708862	0.27
299.0988770	0.33
301.1165466	0.07
303.0911865	1.36
304.3016968	0.13
305.3045044	0.59
309.4766846	0.73
311.2117310	0.12
313.1956177	0.31
315.3208618	0.41
317.3259277	0.79
321.4443970	0.28
323.3491821	0.15
328.9702148	0.28
333.2507324	0.39
335.4929199	0.08
337.4110718	0.14
339.2017212	1.15
341.1921997	1.18
343.0701904	0.09
345.2360840	1.10
347.2699585	0.24
351.3557129	0.63
353.2769775	0.45
357.2972412	2.96
359.3461304	0.86
361.1611938	0.33
365.5162964	0.41
369.3756104	4.39
375.1316528	0.62
377.3070068	0.24
383.2788696	0.05
387.2449951	5.41
400.4432373	0.20
405.1445923	4.68
409.5015259	0.10
417.5909424	0.11
423.1376343	100.00
433.2428589	0.31
434.0248413	0.45
435.1023560	0.10
440.0392456	1.57
440.8629761	1.08
443.2378540	0.95
448.1525879	0.16
457.9008179	0.57
463.4763184	0.60
466.8070679	0.14
477.0533447	0.27
478.2166138	0.15
479.3715820	0.13
480.2611694	0.51
495.3334351	0.37
503.9953003	0.15
507.6036377	0.07
513.5233765	0.08
519.2299194	0.50
522.2064209	0.32
531.3851318	0.17
534.2205200	0.05
535.7391968	0.52
545.1049194	0.54
549.1917725	0.82
554.5704956	0.60
567.4951782	0.67
571.2271729	0.11
574.2377319	0.44
575.3604126	0.09
583.8469849	0.42
585.0288696	1.20
601.3399048	2.14
602.4963379	2.82
603.7075806	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.2157
Annotation	Stephalonine C
Peak:m/z	Relative Intensity
141.9475403	0.49
142.9035645	0.12
153.9235229	0.08
154.9570770	0.05
157.0022430	0.77
158.2226562	0.39
159.0060730	0.24
167.0015411	0.07
168.7695007	0.24
169.9436951	0.18
172.8888855	0.22
174.0090485	0.14
176.0659790	0.60
177.1423187	0.10
178.3183289	0.16
179.2968445	0.10
181.0690002	0.20
183.9324951	0.93
184.9376526	4.83
186.0382385	0.19
189.0917358	0.56
191.0097351	7.06
191.8822937	0.23
193.0216980	0.66
193.9559021	0.23
195.9669495	0.32
197.9252625	0.05
198.8782959	0.06
203.0086060	29.30
207.0109558	0.23
209.2046204	0.25
210.0848541	0.09
210.8403931	0.80
212.1197357	0.74
214.1525269	0.14
215.9259186	0.11
219.0266418	1.87
224.0402374	0.23
225.1956787	0.13
228.9800568	14.27
229.8157043	0.52
231.1479492	0.41
237.0400543	0.15
239.2760315	0.16
240.2609406	1.30
241.1445007	0.35
242.1054993	0.14
247.0383453	4.04
248.9776917	0.10
251.7540436	0.18
257.3245239	0.08
259.1481934	0.32
267.2321472	0.10
268.2350464	0.88
269.1094055	0.67
270.2659912	0.05
287.0710144	1.01
288.1675415	0.27
293.3536377	0.06
294.2384644	0.05
295.0592957	0.05
296.2238770	0.12
301.1295776	0.07
302.1116943	1.55
304.9334412	0.23
311.2161865	1.44
312.3152466	1.05
313.2076111	4.13
319.6223755	0.20
320.3396301	0.11
322.1667480	1.67
324.3777161	0.23
327.5223389	0.36
329.1239929	3.14
330.0724182	0.09
331.3905029	0.16
332.0414429	0.32
337.2741089	0.05
340.1319885	0.88
345.2893982	0.09
347.0978088	100.00
348.0742188	0.59
354.9895630	0.14
358.1094360	0.50
359.1166992	0.66
361.2164612	0.16
363.3311462	0.29
364.4027405	0.62
365.0749512	8.52
369.2527466	0.11
373.1864014	0.12
374.2962036	0.32
375.0423584	0.22
376.0714722	7.62
384.3553772	0.17
387.1294250	1.43
395.1308899	0.70
398.2034607	0.65
399.0632935	0.15
404.1996765	0.37
405.0014954	1.80
405.8091125	0.09
413.2351990	0.41
415.2637634	0.33
417.1199646	0.63
420.1343689	0.28
421.1623535	0.16
431.9682617	0.16
433.0830383	0.05
434.2455139	0.56
444.2835388	0.47
446.2587585	0.10
449.3946228	0.20
450.6622314	0.07
452.8015442	0.18
453.5870667	0.04
458.0958557	0.56
465.8392944	0.40
471.5318909	0.17
475.5569763	1.57
476.1930237	8.52
477.3292847	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	392.3168
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9581680	0.70
130.0128021	100.00
152.9661560	0.59
153.9400940	0.78
189.2740173	0.24
213.0339203	0.22
231.1554260	0.56
235.3890686	0.50
238.2701416	0.29
242.9226379	2.97
244.1442871	0.68
255.2453003	1.47
256.3239746	5.05
278.0322876	0.30
287.2534485	0.30
293.1537476	0.35
320.4235840	0.19
324.1499634	0.47
332.1195068	0.13
346.6019287	0.43
348.4050293	18.50
364.3008423	0.17
372.5589294	0.08
373.5249023	0.16
374.4176331	3.29
375.1194763	0.67
393.0528870	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.4059
Annotation	Beesioside D
Peak:m/z	Relative Intensity
202.1919250	0.19
206.9215393	0.15
213.2385559	0.07
215.2043610	0.04
225.1000977	0.04
255.2988892	0.13
256.0141907	0.03
268.3141785	0.04
283.2741089	0.08
309.8315125	0.13
319.1705627	0.05
327.1936646	0.08
336.9563599	0.12
340.0566406	0.03
341.0750732	0.08
366.2775879	0.05
368.3088379	0.04
376.3294678	0.03
383.0761108	0.21
399.0599365	0.04
408.4010010	0.04
413.2932129	0.07
417.0761108	0.09
455.3792725	0.05
460.1466064	0.17
462.7143555	0.07
466.6066895	0.10
471.4767456	100.00
485.3129883	0.23
494.6875000	0.07
499.0027466	0.23
500.7370605	0.08
550.3910522	1.13
561.5975342	0.11
565.2902222	0.17
572.7174683	0.13
573.5832520	0.11
577.3109741	0.13
579.9982300	0.07
592.1182251	0.32
593.0917358	0.11
606.8023071	0.47
617.6554565	0.09
619.2207031	0.21
620.1334839	0.08
623.3098755	0.10
627.3006592	0.03
633.2098999	15.64
635.4784546	0.32
649.1445923	0.20
651.0844116	0.07
657.2058105	0.15
660.7266235	0.39
661.8057861	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1644
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
203.3352661	0.08
209.7501526	0.12
210.8319702	0.43
216.9172058	0.42
228.3765717	0.14
236.9049072	0.18
258.1960144	0.34
271.1332092	0.42
273.0305786	0.52
275.1781616	0.24
276.2819214	0.49
283.0266724	0.92
287.0559692	87.94
288.0290527	100.00
288.6904297	0.15
295.0996399	1.54
296.472229	0.17
298.9516602	0.28
306.4431763	0.60
307.1846924	0.25
308.2478638	0.11
311.8884888	0.14
313.1511536	4.17
314.1046753	2.39
327.9296875	0.27
329.2098389	1.56
330.4401245	0.46
337.2120972	0.98
343.2460938	0.43
347.1828003	0.20
348.8447876	0.54
362.0521851	0.19
367.2396851	1.06
379.2122192	1.27
380.0510254	0.65
381.9539185	0.09
383.3607178	0.57
397.0567627	1.95
398.2755127	0.23
401.4165649	0.24
415.1427612	10.04
416.1826782	5.86
421.953186	0.68
431.0454102	0.95
432.0823975	2.90
433.1552734	10.63
434.0541992	8.22
434.6858521	0.28
446.0722046	0.09
449.041687	17.48
449.9675903	29.55
458.3865967	0.66
459.050354	0.12
466.3155518	0.26
472.9952393	0.24
474.2303467	0.25
476.0447998	0.64
477.2034912	0.14
479.6716919	0.39
486.2630005	0.68
493.1184082	0.11
495.2528076	0.61
499.2311401	1.04
502.2775879	0.51
504.9729004	0.09
516.0726929	0.49
519.2438965	0.37
524.2324829	0.31
530.2782593	0.19
532.4960327	0.72
535.5960083	1.14
549.4298706	0.93
550.3204956	0.12
551.6303101	0.25
558.6078491	0.37
559.3903198	0.16
560.4988403	0.25
564.1365356	0.11
565.2207031	0.24
569.8705444	0.29
577.0842896	2.01
578.1414185	4.21
586.6920776	0.12
596.0401611	0.29
601.3830566	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	304.96
Annotation	Unknow
Peak:m/z	Relative Intensity
110.0863800	0.05
120.7557297	0.05
122.8110733	0.07
123.8933258	0.26
142.0524292	0.96
151.1496582	0.17
163.7154846	0.07
173.2664948	0.07
182.8703918	0.11
183.9174194	0.28
187.0467529	0.18
193.0238037	0.06
195.1991272	0.11
207.2059021	0.09
215.0892944	0.28
220.1499634	0.15
221.2937012	0.03
230.8590698	0.09
241.5579834	0.18
245.1862793	0.10
245.7993774	0.05
247.2310181	0.24
249.1859741	0.23
255.1645203	0.19
258.3478394	0.41
259.1220703	1.66
260.1104736	0.06
260.8688660	0.10
263.8078308	100.00
267.9859619	0.57
269.0559692	0.32
274.8631287	0.04
276.6999207	1.05
277.3970642	0.34
281.0147400	0.77
281.6779175	2.62
284.0113525	2.70
285.3027344	0.34
286.3197021	0.99
287.1651306	0.98
288.0275269	0.18
289.3311157	0.14
290.1567993	0.14
291.6874084	0.10
292.6158142	0.56
295.1974487	0.05
295.8477173	0.34
301.0881958	0.17
303.1904297	0.03
304.3985901	0.16
305.4188538	0.43
313.6471863	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
270.9855652	0.05
283.1815796	0.85
295.0396729	0.57
313.1793213	25.57
337.1979370	19.26
343.0086670	0.03
349.0686035	0.25
355.1291199	0.12
361.0731201	0.02
367.0622864	39.16
367.6927185	0.24
379.0830994	12.65
379.7077026	0.07
397.1509399	17.75
397.8969421	0.07
415.0691833	100.00
415.6749268	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Isovitexin
Peak:m/z	Relative Intensity
161.1422272	0.03
179.2936401	0.03
190.9923706	0.08
214.9582672	0.02
225.1279602	0.03
267.1928101	0.03
269.1645813	0.24
283.1539917	0.29
293.1914978	0.03
309.3580017	0.09
311.0653076	100.00
312.012146	0.16
321.2515259	0.11
323.1555176	0.34
325.3681946	0.06
327.3114624	0.06
335.0867004	0.02
337.3479614	0.10
341.1287537	13.61
342.2478027	0.06
349.1708374	0.03
351.1547241	0.11
353.0119934	0.82
355.1398621	0.37
365.1447144	0.13
367.2488098	0.06
371.0219421	0.46
377.0801086	0.28
383.2396545	0.38
395.1289062	0.30
413.1543274	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5069
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
224.8159027	0.13
227.2254028	0.17
241.3060303	0.11
255.2050018	39.74
261.0969543	0.20
267.0493774	0.08
275.250946	0.07
277.5899658	0.29
279.2332458	100.00
279.878479	0.42
283.5140381	0.09
284.3826294	0.23
291.1609192	0.15
293.1762085	0.08
294.4009399	0.09
295.3577271	0.24
305.1059265	0.14
321.1941528	0.08
327.3867798	0.08
385.220459	0.18
391.3625488	0.35
392.1710815	0.61
402.427002	0.32
404.5083008	0.04
419.274292	0.08
429.0610962	0.30
430.9469604	0.20
434.1846313	1.64
441.9083862	0.08
450.5525513	0.09
452.3015747	19.48
453.3937378	0.13
458.366333	1.11
476.4492798	0.70
492.3449707	0.05
518.2565918	0.07
553.5509644	1.15
578.4096069	0.05
600.5814209	0.15
610.4347534	0.05
619.5160522	0.17
621.4194946	0.38
639.3920288	0.06
640.6253052	0.08
642.2645874	0.30
655.3764038	0.15
668.2316284	0.23
669.3474731	0.22
678.5809937	0.50
695.2252808	0.25
696.1878052	1.44
711.3036499	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2997
Annotation	Adouetine Y
Peak:m/z	Relative Intensity
199.0839233	0.04
233.9647217	0.05
235.1067505	0.65
242.7281036	0.02
246.9703217	0.09
249.1021729	1.91
250.0903931	0.12
251.0973663	0.10
260.9966431	0.28
275.1972656	0.02
277.4017334	0.05
287.0391235	0.02
289.0230103	0.44
290.4365845	0.03
303.1894531	2.53
304.1895142	0.30
315.1997070	0.28
316.0990601	0.17
317.2274780	0.32
323.2121582	0.07
329.1931152	0.06
339.3545532	0.05
340.9447632	0.03
344.9671631	0.07
351.4816895	0.05
354.9692993	0.10
369.3936768	0.12
380.0909424	0.11
381.4594116	0.07
395.2720337	0.13
396.2151489	0.11
397.3040161	1.75
398.2996826	0.20
407.4174805	0.09
409.3093872	0.52
410.2644653	0.20
411.5557251	0.09
421.4248047	0.20
422.3220215	0.12
423.3136597	0.16
424.1895752	0.11
434.9946899	0.37
436.3358765	0.15
438.0017700	0.27
439.3992310	0.07
440.3018799	0.07
447.4213257	0.06
449.9564819	0.09
451.1712646	0.25
452.6786499	0.06
453.3589478	0.81
454.2106323	0.05
457.5463257	0.43
458.5852051	0.06
463.3325195	1.28
464.3515015	0.17
465.2941895	0.34
466.4053955	0.03
467.3845215	0.44
469.5540161	0.06
470.3826294	0.08
472.7077026	0.03
477.2688599	1.35
478.3100586	0.97
479.4157715	0.09
480.2517090	0.27
480.9048462	0.02
485.5500488	0.22
487.3672485	0.44
488.2777710	0.09
491.0906982	0.41
493.2916870	3.16
494.3632202	1.45
495.3257446	0.05
503.3038940	0.11
505.2416382	0.50
507.3529053	10.00
508.4539185	2.56
509.4161987	0.05
519.3735962	0.04
521.3755493	4.85
522.6583862	2.27
523.3782349	11.93
524.4910278	4.38
531.2600098	0.04
535.5544434	0.05
537.3632202	100.00
538.4020386	25.70
539.1279907	0.09
548.6440430	0.15
549.2649536	2.30
550.7304077	0.90
551.4288940	2.03
552.3917847	2.70
553.4656372	0.74
557.1382446	0.03
567.2884521	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1815
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
109.7134552	0.16
112.9515305	2.12
115.1766739	0.13
119.0122299	2.56
125.0505524	0.20
130.8345947	1.26
135.0989075	0.10
142.9847260	3.11
147.0785522	3.90
147.8817139	0.32
149.0270691	0.26
150.9027100	0.19
160.8280029	0.30
163.1402588	0.96
164.1069489	2.38
165.0864868	2.16
173.2035217	0.56
177.1036835	0.19
179.0881958	1.31
181.0271606	0.23
190.0152893	0.20
191.0579529	4.86
209.0746155	100.00
210.1127625	1.74
211.2702332	1.18
227.1694031	9.86
248.8397827	0.11
251.1531372	1.26
287.2120667	0.31
301.2463684	0.24
311.1716003	0.23
325.4349060	0.16
329.2356873	0.10
330.3859253	0.15
339.1226501	0.23
341.8848267	0.65
343.0297546	0.20
353.2894592	0.79
353.9927673	0.27
371.0793762	42.54
371.9045105	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.1869
Annotation	Gnetifolin K
Peak:m/z	Relative Intensity
163.1318359	0.06
165.0797272	0.47
175.0794067	0.09
176.9138947	0.05
179.0154114	0.39
187.7901154	0.10
191.0973816	0.28
193.1237183	0.32
195.0870361	3.70
203.1338959	0.07
204.9078064	0.10
206.1708069	0.04
207.9429016	2.92
213.1858215	0.09
218.7956848	0.05
223.0434723	30.05
230.9268951	0.11
232.1677094	0.35
255.2453613	0.09
259.8918762	0.13
265.0321655	0.57
268.6045532	0.08
269.9509277	0.03
270.9872437	0.59
272.0745239	0.73
273.2807617	0.10
280.4819336	0.12
282.0980835	0.09
282.9838562	0.46
283.8922729	0.12
284.9536743	0.61
286.2650146	0.17
289.1197510	0.84
295.4774170	0.09
298.9819336	0.04
300.0811157	0.08
311.0270691	1.80
311.9880676	5.23
313.0642700	4.81
314.2051697	2.62
315.0665894	0.34
319.0619507	0.25
324.9340210	0.14
326.2720337	0.08
327.0789795	0.12
328.1772461	0.12
331.2700195	0.11
339.2326660	0.16
340.1721191	0.14
341.1182861	0.41
342.1288452	0.99
343.0358887	0.76
344.1448975	1.40
345.1141968	0.45
349.1724243	0.10
354.5483398	0.06
355.2731934	0.20
355.8914795	0.19
358.2732544	0.12
361.3359375	0.43
370.0355835	0.10
371.1016235	3.89
372.4264526	0.07
373.0582275	2.97
375.3668213	0.04
376.1174927	0.69
378.2753296	0.34
379.0132446	0.11
380.1020508	0.12
382.4622192	0.09
388.6850586	0.31
389.3296509	0.11
390.3441162	0.23
391.2256470	0.25
396.1172485	0.40
397.1304321	0.65
398.4799194	0.16
400.5526123	0.79
401.1630859	0.56
419.0048218	100.00
419.7385254	0.28
422.2545776	0.05
428.2766724	0.14
431.4475098	0.10
434.3088379	0.04
435.2941284	0.07
435.9382324	0.11
437.3035889	0.07
443.0799561	0.15
444.9978638	0.08
449.4725342	0.11
452.2805786	0.08
454.9544678	0.18
459.0204468	0.06
460.3773193	0.16
461.1660767	0.71
472.9343872	0.07
478.3303223	0.12
486.0568237	0.26
488.1997070	0.20
491.0691528	0.27
494.3377075	0.19
495.3044434	0.11
505.2764282	0.34
509.3181763	0.17
512.2614746	0.07
520.9757690	0.34
532.1249390	0.14
533.1893311	0.06
534.2106323	2.02
535.1479492	2.89
536.3153687	0.07
537.1637573	0.71
538.3733521	0.07
543.3273315	0.22
544.1585693	0.10
545.1104126	0.26
549.3265991	0.15
562.0303345	0.89
563.0677490	1.01
563.6913452	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.3026
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.1606140	0.20
180.1623840	0.12
182.4070587	0.28
183.2053833	0.08
184.1022339	0.44
185.0057373	4.88
187.0157776	0.07
187.9995728	0.14
192.9994659	0.12
194.8236237	0.16
202.4459229	0.33
203.0569763	1.76
212.3186035	0.11
224.8853455	0.08
237.1771545	0.09
244.0536346	5.63
260.0220642	0.07
262.0098877	100.00
263.3361511	0.10
264.2152405	0.21
272.4509277	0.12
274.0856934	0.09
278.2152710	0.14
279.4476013	0.12
301.0972290	0.24
304.8693848	0.11
322.7620239	0.24
335.2032471	0.15
337.2260132	2.65
338.3477173	1.57
347.0932007	0.05
357.5079346	0.13
369.9455566	0.30
381.2958374	0.32
398.6773682	0.25
400.1667480	0.05
402.1237183	0.21
410.6906128	0.41
411.4842529	0.17
425.9127197	0.36
431.9972534	0.07
435.3300171	0.25
454.7277832	0.26
470.2054443	0.09
471.5964355	0.08
473.7257690	0.10
475.1151733	0.24
482.2188721	0.14
504.5932007	0.10
505.4875488	0.07
511.2105103	0.09
517.2484741	0.35
531.3632202	0.18
539.1909180	0.05
541.4188843	0.05
547.4436646	0.07
549.4400024	0.10
553.1184692	0.13
561.1611328	0.37
562.2116089	1.06
566.9834595	0.28
569.5307617	0.14
570.1835327	0.04
579.4550171	2.51
580.3300781	3.22
581.0538940	0.10
582.2163696	0.13
583.2019043	0.25
597.5782471	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.28
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9631042	0.22
162.0532074	0.26
163.0430756	0.11
178.7857513	4.53
179.4229736	0.21
190.7919312	0.04
205.3301849	0.04
224.7150879	0.67
235.1384888	0.07
249.1575623	0.11
251.3909607	0.16
285.0371094	0.13
301.2297974	0.05
311.1360474	0.06
327.1856689	0.13
331.4327393	0.26
332.2045898	0.18
334.7598877	0.16
342.0242920	0.13
344.1820679	0.05
349.1365356	0.68
351.2702637	58.94
352.8493652	0.05
355.3441772	0.11
373.4251709	0.05
374.1510010	0.10
377.1671143	0.08
379.4683838	0.38
381.3884277	0.07
389.7178345	0.09
391.4443970	0.11
393.0678711	0.32
394.2431641	0.32
397.0582275	0.46
401.4270630	0.27
405.8005981	0.08
409.0828857	0.14
413.2708740	0.10
431.2847290	0.25
432.1533203	0.07
432.8344727	0.42
438.0258179	0.86
439.2377930	0.47
443.2825317	0.12
444.0582275	0.19
450.3356323	0.20
452.7753906	0.09
455.0655518	0.10
458.1856689	0.06
460.4501953	0.13
467.0040894	0.14
469.4060669	0.08
476.1138306	0.07
495.4334106	0.36
496.3985596	0.20
497.4675903	0.15
498.1874390	0.14
499.2977905	2.38
503.4426880	0.10
510.6253662	0.43
512.1912842	100.00
513.1716919	24.67
513.7805786	0.41
514.4744263	0.16
515.5336304	0.20
523.1600342	0.45
527.0521851	0.10
528.4011230	0.30
531.3530884	0.11
540.4005737	0.11
541.3288574	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1646
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
181.0136261	0.04
247.1582642	0.07
257.0433044	0.10
269.0778198	0.07
270.9528198	0.33
272.9623413	0.10
275.5006409	0.30
279.114502	0.16
283.9470825	0.05
285.1536865	0.06
287.050293	100.00
289.3093872	0.21
293.0907898	0.32
294.9141235	1.73
311.1723633	0.24
313.0574951	6.64
313.6967163	0.23
323.0786133	0.15
326.5852661	0.04
327.2432251	0.13
329.1258545	0.97
332.0878296	0.20
333.0917969	0.09
337.2330933	0.98
343.083313	0.28
346.949707	0.24
348.7852783	0.14
356.2553711	0.48
359.4363403	0.34
365.4252319	0.13
367.0061646	2.70
378.7078857	0.24
379.3326416	0.48
383.2329712	0.13
390.3007202	0.10
397.1201782	2.68
405.7495728	0.43
406.5030518	0.09
413.2009277	0.17
414.4227295	0.73
415.2153931	11.31
415.8342896	0.15
422.0053711	0.28
429.8250122	0.13
431.1567993	1.09
432.227356	16.75
433.2890625	12.01
435.0595093	0.10
438.9465332	0.60
444.098938	0.07
445.3288574	0.08
448.21698	1.23
449.05896	27.50
458.9591675	0.17
465.1175537	0.13
473.1018066	0.11
474.1512451	0.34
477.9336548	0.18
479.0687256	0.32
488.9438477	0.34
490.3063965	0.04
491.2132568	0.05
499.1013184	0.14
506.5895386	0.10
509.1339722	0.18
512.713562	0.15
515.4551392	0.13
517.3713989	0.31
530.5377197	0.11
540.2377319	0.27
548.916687	0.13
550.3570557	0.26
552.1886597	0.17
558.0463257	0.07
559.3017578	0.24
576.0184326	1.76
577.2091064	5.57
578.7300415	0.12
585.8788452	0.51
586.5490723	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	596.3196
Annotation	1-Epicrassicaudine
Peak:m/z	Relative Intensity
222.9291077	3.69
224.0035553	0.85
225.1666260	0.32
241.0633392	7.25
242.0859985	1.55
258.2210083	0.12
258.9625549	0.18
271.7829285	0.51
277.0003662	0.08
279.2545776	6.15
280.2790527	1.67
293.2792664	19.23
294.0988159	0.07
295.0183716	0.19
307.2769165	7.91
315.1237793	11.92
316.1217651	2.18
321.8084717	0.10
333.0697632	1.64
334.0751953	0.44
352.5903931	0.24
361.0664673	0.33
375.2879639	2.21
394.2052612	0.18
398.3992920	0.08
404.3328247	1.53
412.0601807	0.17
415.4067383	0.98
416.1787109	0.15
417.0889893	0.09
418.2929688	0.31
422.6750488	0.42
431.3709106	0.14
433.3113403	0.26
433.9642334	0.53
443.2078857	0.12
445.9878540	0.70
447.2962646	9.20
449.3004761	1.46
461.5859375	0.17
465.2229614	0.53
473.3712158	5.54
474.2445679	2.69
475.1520386	0.11
476.2609253	0.12
477.5029297	0.24
485.3824463	0.17
491.3736572	0.15
502.2153931	0.37
504.0835571	0.15
518.2310181	50.55
519.2921753	0.42
520.0567017	0.25
526.3876953	0.34
532.2929077	25.54
533.0606689	0.23
536.2739258	100.00
537.3183594	0.77
538.5097656	0.08
549.9821777	0.86
551.3139038	0.15
560.7487793	0.16
577.0958862	0.11
578.2868042	0.53
579.2124023	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.2745972	0.03
206.9570465	0.43
290.8333130	8.07
347.2429810	0.11
349.1679077	0.07
374.6724243	5.26
380.1351318	0.02
380.8845825	0.01
456.2021484	0.20
458.4916382	100.00
459.1851196	0.40
523.6083984	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	910.1523
Annotation	3-hydroxyadipyl-CoA
Peak:m/z	Relative Intensity
261.6998291	0.02
285.8320618	0.14
303.8846436	0.72
334.1683350	0.48
350.2417908	0.04
394.0662231	0.29
406.0494995	0.21
436.0819092	0.25
437.3078613	0.39
452.4249268	0.02
454.2696533	0.04
468.0852661	0.06
484.0188599	0.05
494.9328613	0.24
496.1177979	2.30
497.0034790	0.49
498.0200195	0.02
513.9947510	0.09
522.0975342	0.38
538.3836060	0.03
540.2653809	0.03
554.2642212	0.11
556.0747070	6.21
557.2530518	0.33
558.1142578	0.44
566.5975952	0.02
567.9859009	0.03
571.0601196	0.03
574.1838379	0.04
582.8551636	0.09
594.1375122	0.02
598.2282104	0.02
603.6944580	0.05
610.4992676	0.02
613.9990845	0.06
626.9365845	0.03
628.0317993	1.89
642.1075439	0.08
657.1997070	0.07
657.9960327	1.82
658.9323120	0.05
663.2512817	0.03
669.8260498	0.05
679.2861938	0.05
684.0802612	0.05
688.0801392	5.32
688.9619751	0.04
702.1745605	0.12
716.3420410	0.56
718.1061401	100.00
719.2202759	4.68
720.1782837	2.88
730.0531616	0.51
745.2814331	0.02
746.1966553	0.03
747.6004639	0.20
748.3050537	0.58
759.1144409	0.02
776.1231689	0.09
777.9994507	0.08
805.5708618	0.02
820.1934204	0.05
820.9041748	0.04
822.0601196	2.08
829.7128296	0.01
864.0404053	0.08
866.0119019	2.07
874.3261108	0.02
891.3567505	0.15
892.1405029	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2767
Annotation	Unknow
Peak:m/z	Relative Intensity
217.3216858	0.07
229.4703369	0.06
230.0953827	0.38
231.3220825	0.08
241.0200653	0.47
246.9604187	0.14
273.0735474	0.55
274.1653748	0.36
275.0329895	0.10
276.6716614	0.03
277.3233337	0.24
279.3084717	0.13
297.1789551	0.03
308.9266357	0.06
317.7078247	0.22
318.3482056	0.24
335.1838379	1.72
336.2329102	1.99
337.0502625	1.01
356.2756958	0.06
357.4232178	0.12
367.0053711	0.07
413.2188110	0.44
415.3410645	0.51
429.4577637	0.05
431.2146606	0.48
433.2431641	0.13
459.2844238	0.11
460.2299805	0.75
470.4319458	0.07
478.3745728	0.09
483.2913818	0.03
485.1975098	0.22
487.3875732	0.11
488.2198486	0.13
490.5018311	0.16
492.1835938	0.18
494.9309692	0.17
504.1563721	6.92
513.5666504	0.16
520.4321899	0.25
525.8065796	0.08
527.4454956	0.51
530.7251587	0.28
531.5132446	0.21
533.4268188	0.06
535.0845337	0.40
536.1563110	100.00
536.7701416	0.87
547.1497803	0.11
557.3428345	0.12
559.1652222	0.08
559.8507690	0.10
573.3744507	0.15
577.1677856	0.06
583.6301880	0.04
588.2896118	0.08
589.2783813	0.23
598.2439575	0.15
598.9755249	0.07
600.1316528	0.17
600.8319702	0.19
604.7451172	0.13
605.5681152	0.04
608.3933105	0.06
612.4250488	0.03
615.1773682	0.21
616.1317749	0.30
619.0743408	0.39
620.1909180	0.10
621.3848267	0.14
629.0095825	0.17
630.9336548	0.34
632.1833496	2.31
633.3329468	2.24
642.2660522	0.15
643.4439697	0.43
646.2532349	0.66
647.3709106	0.37
648.2348022	0.16
649.3541870	0.27
656.3375244	0.18
657.4359131	0.17
659.0396729	0.07
660.5176392	0.72
661.2655640	1.86
662.3063354	0.05
665.0387573	0.18
674.2993774	0.83
675.2726440	3.42
684.4412842	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.3715
Annotation	PC(16:0/5:0(COOH))
Peak:m/z	Relative Intensity
179.9650726	0.04
185.2027588	0.03
186.9586029	0.04
190.7598114	0.10
200.3415070	0.32
204.7953491	0.12
210.0147552	0.02
213.0760651	0.66
219.1523132	0.08
221.2345734	0.09
222.9970093	0.03
231.1289062	0.23
241.3146667	0.06
258.2108765	0.10
266.9125366	0.04
275.0601501	0.16
276.2475586	0.03
279.2261353	0.05
289.0204468	0.03
293.1989746	0.13
301.5291138	0.09
309.3063354	0.13
311.2874756	0.09
313.2387695	0.18
314.9719543	0.10
317.5322266	0.12
327.4711914	0.30
331.3443604	0.02
336.2687378	0.10
341.1362305	0.03
342.5092163	0.08
352.0054321	0.07
354.2938843	0.32
357.4785767	0.05
359.3589478	0.22
365.1926880	0.04
371.7471924	0.18
372.4768677	0.14
381.4417725	0.08
387.8435669	0.04
391.2977295	0.04
393.1942749	0.16
409.5943604	0.01
418.3212280	0.24
420.3341064	0.01
422.0006714	0.05
425.0540161	0.02
436.2492065	0.11
451.4542847	0.08
454.2028809	0.21
457.4297485	0.05
459.5590210	0.02
466.2709961	0.04
467.3325806	0.02
469.3378906	100.00
470.0033569	0.19
481.7516479	0.05
483.5538330	0.06
494.0664062	0.02
500.9292603	0.07
511.6171265	0.03
512.6696777	0.15
513.4842529	0.05
515.2631226	0.03
518.6541138	0.02
524.0869751	0.03
540.5241699	0.05
542.3944702	0.12
543.2270508	0.10
546.5558472	0.01
548.9896240	0.23
550.2729492	0.14
551.8772583	0.08
553.0167236	0.11
555.3939819	0.10
556.2448120	0.03
561.4020386	0.04
563.8191528	0.21
564.5199585	0.02
567.2708130	0.18
573.6654663	0.31
575.3366089	0.27
576.1437378	0.02
578.3949585	0.16
581.2641602	0.06
582.3729248	0.06
591.4077759	0.56
592.4201050	1.22
593.4082642	0.11
609.5939941	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1662
Annotation	Butrin
Peak:m/z	Relative Intensity
170.9305115	0.11
172.1667938	0.36
173.0550690	0.48
174.1944580	0.09
175.9954224	0.77
177.0328979	0.13
177.9715729	0.18
178.8995209	0.32
179.9917755	0.41
181.1180420	0.48
181.9112549	0.27
183.1531372	0.11
187.1694336	0.07
192.0121460	0.07
192.9921265	0.04
195.1704102	0.10
196.1085358	0.12
197.0899353	0.39
198.1102600	0.19
199.0825195	0.66
200.3930054	0.35
201.1537476	0.76
202.1862335	0.14
203.1208954	0.06
205.1566162	0.03
207.0291138	0.18
208.0397339	0.03
211.2648010	0.07
213.0727234	0.09
214.0187683	0.03
215.1100464	1.15
216.1286469	0.26
218.0655975	0.03
221.0639496	0.11
222.9609070	0.16
224.9426727	0.72
225.9717712	0.07
240.1059570	0.15
241.0897980	1.25
241.9593353	0.17
243.1015930	2.75
244.2565765	0.83
251.0979462	0.04
256.8621826	0.13
259.0392456	45.56
260.1298828	5.92
266.1063538	0.06
267.0163574	0.11
269.0387268	100.00
270.1289062	13.97
271.0644531	0.04
283.0228271	0.74
283.9887085	0.16
285.0886841	0.05
287.0441895	61.33
288.1287231	10.58
293.0677490	0.10
294.0084229	0.11
297.2514038	0.17
307.3130493	0.04
311.1359253	2.03
312.3876953	0.23
329.1567993	0.13
336.0535278	0.20
342.2867432	0.05
343.2681274	0.04
353.1148071	0.19
354.2322998	0.18
355.1889648	0.26
383.1574097	0.07
384.1439209	0.05
384.9076538	0.08
394.4696655	0.06
397.0465088	0.07
409.2065430	0.05
411.1268311	0.04
415.1273804	0.61
416.2517090	0.08
427.0963135	0.02
428.9601440	0.06
431.3825684	0.36
432.3925781	0.27
433.2421875	0.39
434.3128662	0.09
439.9991455	0.16
441.3145752	0.07
446.1621704	0.07
447.5390015	0.09
449.3266602	0.06
456.3365479	0.05
457.3811035	0.03
458.1020508	0.16
460.9459839	0.09
473.1638184	0.38
474.5821533	0.87
475.2511597	1.62
476.1130981	0.27
484.2242432	0.03
488.2028809	1.80
489.0957642	0.12
490.3491821	0.20
504.2769775	0.22
505.1762085	0.50
506.2224731	0.02
514.6566772	0.12
520.3034668	0.12
523.2009888	0.05
533.4105835	0.05
534.1754761	0.19
535.0930786	0.07
536.8599854	0.08
548.9672241	0.47
549.9766846	0.37
551.1403198	0.42
551.9465942	0.04
560.0524902	0.15
564.2300415	0.04
567.1779175	16.59
568.3286133	5.22
574.0355835	0.31
577.1567993	24.35
578.2585449	6.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	895.1923
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
253.1109619	0.38
254.7641296	0.13
256.2095947	0.19
267.9643860	0.06
269.0347595	0.11
282.9378662	0.30
284.0704346	1.52
284.9835815	1.26
287.4862366	0.15
297.0896606	2.58
297.9095459	0.25
299.0998535	2.88
305.0330200	0.09
308.6012573	0.18
311.2360840	0.24
312.6006165	0.10
323.8702087	0.07
325.2164917	0.68
327.1109314	34.40
329.2850342	0.13
337.3941040	0.05
338.1897583	0.26
339.0852051	0.91
341.2907715	0.41
351.0903015	0.39
357.2342224	12.67
365.2534790	0.27
369.1909790	2.72
390.9671631	0.21
393.0330811	1.42
399.1411133	0.11
401.3349609	0.20
407.9542236	0.29
411.1802979	0.40
415.9367676	0.06
422.2957764	0.13
427.0516968	0.10
429.1157837	0.20
443.6826782	0.07
445.0292358	0.48
447.1030884	100.00
455.2898560	0.18
461.1679688	0.17
463.2893066	0.10
467.8813477	0.41
475.2310791	0.09
489.0454712	0.12
493.2311401	0.14
513.4082642	0.15
529.1625366	0.25
531.9975586	0.45
548.7584839	0.12
565.4288940	0.15
567.5529785	0.08
571.5991821	0.19
582.2833862	0.44
595.1867065	0.31
607.0723267	0.28
624.9735718	0.38
628.3973999	0.13
637.2814941	0.04
638.7529907	0.34
642.8134766	0.16
643.5054321	0.06
649.5947876	0.88
655.1539307	0.06
661.1290894	0.38
669.1018066	0.11
678.9574585	0.11
685.2804565	0.12
688.3816528	0.19
696.8704224	0.39
711.2141724	0.16
713.7760620	0.34
714.3963013	0.14
715.2256470	1.10
722.4306030	0.10
733.2088623	1.02
735.4401245	0.25
738.9205322	0.18
743.3092651	0.05
748.4135742	0.07
757.3242188	0.16
763.6252441	0.27
765.3589478	0.15
769.2416382	0.05
773.8932495	0.39
775.2141113	3.14
780.2954102	0.04
787.1237183	0.32
801.4591675	0.12
805.2055664	2.21
806.5216064	0.09
816.5274658	0.24
820.6757812	0.06
823.6431885	0.16
828.4512329	0.71
831.6171265	0.16
850.1063232	0.25
851.1039429	0.44
856.5059204	0.06
859.3512573	0.85
876.4714966	0.47
877.2718506	3.03
877.9292603	0.05
894.9440308	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1087.4817
Annotation	Unknow
Peak:m/z	Relative Intensity
305.1604004	0.11
318.5853882	0.17
323.2553101	0.21
341.0901489	0.44
365.0902405	1.01
379.1243286	0.04
383.2175598	3.77
385.4146118	0.14
394.9663086	0.07
412.9975281	0.16
417.7915955	0.04
439.0784912	0.27
442.9084473	1.06
449.2738953	0.42
455.1990356	0.09
467.2034302	0.94
481.2448730	0.06
483.2913818	0.05
485.0677490	2.38
496.8275452	0.03
503.0101929	1.88
509.5344238	0.10
527.1124268	3.66
539.0289917	0.24
541.2411499	0.13
545.2429199	8.35
557.0128784	0.57
559.1501465	2.17
569.2004395	0.06
571.3089600	0.16
575.0352783	0.15
587.1784058	0.70
593.2145996	0.17
604.5347290	0.07
605.1940918	0.12
611.1937256	0.39
615.3392334	0.12
629.1148071	0.92
643.3045044	0.85
647.2155762	1.96
659.2183228	0.06
665.1278687	0.66
670.9682007	0.41
689.0885620	1.62
702.7595215	0.39
703.3889771	0.08
707.0327759	0.39
726.9553223	0.06
735.2928467	0.14
742.1435547	0.05
745.4918213	0.15
762.5098267	0.13
797.3931885	0.10
805.3067627	5.33
809.2258301	100.00
809.8839111	0.24
827.1741943	34.71
828.0109863	0.08
835.5451660	0.20
887.6656494	0.03
907.6026611	0.11
914.3310547	0.04
924.9134521	0.17
946.4650879	0.13
967.0839844	0.09
982.7500000	0.19
1010.5477290	0.04
1014.6101070	0.10
1068.4045410	1.05
1069.6125490	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.1
Annotation	N-Malonyltryptophan
Peak:m/z	Relative Intensity
83.5784302	0.03
87.7679901	0.02
103.9883575	0.02
104.9771423	0.05
109.0345230	0.08
110.1443024	0.01
110.9159088	0.04
117.9506989	0.55
119.0584412	0.02
120.8257828	0.01
122.9475021	0.06
126.7191010	0.02
128.5592651	0.01
130.0079041	3.24
131.0545502	0.16
133.1236725	0.08
138.8321838	0.07
143.9737244	0.10
146.9716492	0.21
149.0645752	0.04
155.9456177	0.13
157.0667419	0.11
158.9672241	1.11
162.7210083	0.05
165.1121826	0.16
168.9842377	0.07
169.9472504	0.09
173.9352722	1.21
175.1947327	0.04
175.9327240	0.07
180.9929199	0.05
184.0276489	0.06
186.3113861	0.02
187.1488190	0.33
187.9952087	4.12
188.6624756	0.09
192.2985992	0.06
197.1068420	0.02
201.0952454	0.55
202.9094238	0.06
204.9975891	1.06
210.9692078	0.07
212.9071655	0.01
216.5835571	0.06
219.9797974	0.12
229.0518494	2.87
230.0108337	0.05
231.1086426	0.14
232.2521973	0.05
233.2591248	0.11
235.0323181	0.14
237.2156982	0.04
242.0964966	0.05
243.0690308	0.08
245.0701599	23.09
247.0575256	5.83
248.1768188	0.13
249.0825500	0.15
250.1024475	0.17
252.8918457	0.01
255.0541992	1.31
257.8042297	0.09
259.1223755	0.53
260.1222534	0.58
261.0515137	0.05
263.1618958	0.48
266.9989014	0.04
270.2141113	0.13
271.4694824	0.03
273.0337830	100.00
274.2564392	0.07
276.1808472	0.53
277.1420288	0.08
278.7128296	0.09
281.4625244	0.13
282.4779053	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.2444
Annotation	Zizyvoside I
Peak:m/z	Relative Intensity
152.1314240	0.15
153.0564575	1.15
154.0404663	0.16
157.3085785	0.12
158.0964813	0.04
159.0518036	0.12
162.9597473	10.53
164.0010681	0.88
169.2475281	0.20
172.0239716	0.25
173.0042877	0.05
175.0203094	0.80
185.9888458	0.41
187.1073914	1.15
188.2262268	0.46
189.1103516	3.57
190.0995636	2.90
191.1616364	0.55
195.9725037	0.20
202.0122986	0.18
202.9190826	0.11
205.0730743	100.00
206.1026611	13.18
207.0051880	0.25
222.9399719	0.43
224.2326202	0.05
225.2183990	0.08
228.5014954	0.37
234.4953918	0.75
245.2496338	0.12
247.1134644	3.05
248.2572937	0.37
264.8489380	1.67
265.8525391	0.16
266.9132080	0.06
274.0028076	0.23
277.9551392	0.16
279.0422974	0.09
288.2698059	0.38
288.8955383	0.42
289.8491211	0.15
295.0544739	0.15
305.3991089	0.29
307.0838013	6.99
308.1817627	1.02
318.2531738	0.06
320.2208252	0.06
322.2033691	0.47
324.6342773	0.24
325.2657471	0.18
340.3068848	0.10
370.2632446	0.17
374.1071167	0.16
379.2058716	1.84
385.1260376	2.96
386.1342773	0.91
387.2366333	0.73
388.4580078	0.23
412.0904541	0.13
426.3746338	0.34
437.8657837	0.16
439.7938843	0.44
440.4019165	0.20
442.0909424	0.19
444.1244507	0.12
448.4506226	0.49
449.0559082	0.32
450.0892944	0.29
451.1817627	0.12
452.2647705	0.31
468.5065918	0.09
470.0897217	0.17
471.2501831	0.26
485.4674072	0.47
486.3126831	0.75
486.9837036	0.45
488.1755981	0.33
490.5734253	0.13
493.2024536	0.19
496.0795288	0.08
500.2295532	0.16
502.8457031	0.10
513.1046753	1.48
514.3186646	0.67
515.1608276	0.11
516.1278076	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3392
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
184.0263367	29.45
240.1813049	0.18
245.3828583	0.07
258.2322388	0.29
337.1938477	0.03
443.2263794	0.13
502.3240356	100.00
503.0131226	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3589
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1719666	0.37
212.0406952	0.27
221.1562500	0.17
235.1678314	0.75
247.3784180	0.05
251.0718231	0.09
253.0906372	3.04
254.1128082	0.07
269.0595703	0.28
273.1423035	0.21
281.3829346	0.02
285.3693542	0.05
287.0916138	0.14
289.1384583	0.09
291.2444763	0.59
292.5134277	0.34
293.3215332	0.02
297.1719971	0.03
305.1526794	0.39
306.9619446	0.16
309.3844910	1.09
310.1306152	0.07
323.1817017	0.05
327.2250366	40.21
328.2209473	5.26
350.3628540	0.05
351.2456665	0.08
368.1788940	0.03
391.2442017	0.16
397.2047119	0.74
398.3585815	0.04
401.5973511	0.03
409.3029175	0.03
415.1523438	100.00
416.1332397	10.37
416.7507935	0.02
424.0417480	0.18
433.5900879	0.06
453.3462524	0.04
469.4955444	0.18
474.2286377	0.11
480.3547974	0.04
487.3895874	0.14
501.2219849	0.09
503.3814697	0.24
516.4502563	0.04
517.2198486	0.03
545.1675415	0.15
546.7172241	0.20
553.3262939	0.08
554.1851196	0.05
563.3991089	0.04
571.4221191	0.03
574.2311401	0.06
581.4684448	0.11
582.5659180	0.11
591.2822876	0.06
596.9433594	0.06
604.5640259	0.04
606.2211304	0.40
610.5484009	0.06
626.1506348	0.03
631.5103149	0.04
634.4235229	0.05
636.4144287	0.03
643.4817505	0.02
647.1870728	0.05
657.5897827	0.13
658.2361450	0.06
665.0050659	0.04
667.1232910	0.04
679.2975464	0.18
680.2787476	0.09
681.3466797	0.18
682.6338501	0.10
689.0388794	0.17
693.3314819	0.09
696.4006958	0.16
698.8444824	0.03
707.6330566	0.37
708.4921265	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.2053
Annotation	Blumiolide A
Peak:m/z	Relative Intensity
100.8451080	0.06
105.0207214	0.10
106.9626236	0.05
108.8320160	0.15
116.9444427	0.28
121.0296783	0.30
123.0207443	0.49
131.0667725	0.21
134.9985046	0.36
135.9563293	0.06
138.2590637	0.04
141.0163879	0.06
144.9661255	0.07
147.0481110	0.36
148.8367920	0.20
151.2041779	0.46
152.9779358	0.28
154.8357239	0.07
156.9225159	0.15
158.2242432	0.07
160.3791809	0.07
161.0314941	0.12
163.1401062	0.05
164.9773712	0.20
167.0167694	0.13
168.9554138	0.12
170.0872498	0.10
171.1437378	0.16
174.0958099	0.05
175.0975647	0.17
177.1730347	0.34
178.9552002	2.76
181.2221375	0.22
183.0065918	0.08
184.1625061	0.08
189.0931244	0.29
191.1233673	0.69
192.8266907	0.54
194.0336304	0.06
195.0987549	0.24
197.2451477	0.33
204.0453186	0.05
205.0047913	0.49
207.2375793	0.66
209.3281250	0.26
211.1824036	0.09
212.9963074	0.37
215.0860901	0.63
217.2711487	0.36
218.8954163	0.12
220.8884277	0.66
223.1903076	0.38
225.0589294	0.35
227.0845032	0.99
231.1320190	0.25
233.3439331	0.59
237.2042236	0.38
239.1710510	0.92
241.1167603	0.99
242.2201233	0.13
243.1226196	0.15
244.9683228	0.65
248.8619385	0.25
251.1879272	2.23
253.3687744	0.36
254.8109131	0.13
256.9063721	0.34
259.1806641	2.13
261.4695129	0.29
266.0129395	0.07
269.1699524	16.28
271.2743530	1.14
272.9377136	1.02
275.4153442	0.40
279.5139771	0.19
283.1683960	0.18
284.0401306	0.12
284.9064941	0.12
287.1227417	100.00
289.2908020	0.68
291.0151978	0.06
292.0145264	0.54
297.2026367	5.81
298.0378418	0.19
303.2019653	0.49
305.2436218	1.90
312.4294434	0.31
313.1351318	0.16
315.1054993	40.60
316.2624512	0.07
323.4534607	0.74
333.1782837	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2817
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
225.2112732	0.06
259.2834167	0.04
287.2647400	0.01
296.5036316	0.07
301.1571350	0.04
321.3118896	0.02
329.3251648	0.04
341.3514404	0.02
349.9657593	0.04
356.0355835	0.03
371.5283813	0.06
378.4156494	0.10
387.0144043	0.03
390.2007446	0.03
395.5330811	0.08
402.3753662	0.17
411.4393311	0.01
444.1461792	0.37
445.0723877	0.17
452.2998047	0.06
462.3435669	0.31
463.2713623	0.02
466.3654785	0.09
471.3354492	0.03
476.3949585	0.05
477.2159424	0.04
488.3477173	1.68
489.2274780	0.60
492.2547607	0.05
498.6227417	0.02
508.2216797	0.21
509.3116455	0.16
511.2243652	0.03
520.2371216	23.68
521.2142944	9.04
521.8532715	0.08
530.0995483	0.06
541.3449097	0.72
542.4133911	0.57
549.2943726	0.02
558.3490601	0.04
559.2039185	0.08
560.3869629	0.04
565.9187622	0.02
578.2072144	0.03
582.0839233	0.10
583.3855591	0.78
584.6300659	1.05
585.2587891	12.97
586.2905884	7.42
587.2015991	0.05
590.4841919	0.09
596.6533203	0.02
599.2954102	0.07
600.1824341	0.07
601.3881226	1.91
602.4563599	1.29
603.4261475	0.14
617.2522583	99.48
618.2374878	39.17
618.9234009	0.08
627.2978516	16.24
628.4041138	8.82
629.2590942	0.36
630.1249390	0.05
631.1591187	0.08
632.1917114	0.09
633.5891113	0.15
643.4427490	0.06
645.2667236	100.00
646.2331543	47.58
646.8717041	0.27
648.3056641	0.02
651.7400513	0.12
654.4151001	1.70
655.4523926	0.23
657.3500977	0.06
659.2191772	53.95
660.2147827	24.41
660.8495483	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
174.9864807	0.01
227.2565002	0.02
231.1558838	0.02
241.0472412	0.02
246.8594513	0.01
271.0211792	1.62
277.2731934	0.07
283.156311	0.26
284.5101318	0.02
289.0733948	0.01
292.0240479	0.02
295.0057068	0.48
301.1744385	0.01
310.8344116	0.00
313.1099854	3.44
314.1395874	0.09
332.927124	0.03
336.1134033	0.01
337.1707764	0.35
338.0841675	0.02
340.7661133	0.01
343.213623	0.06
349.3009644	0.00
350.397522	0.02
351.1172485	0.06
361.0698853	0.02
367.1077271	0.38
368.2276611	0.01
379.1268311	0.20
383.46698	0.02
384.9754639	0.01
391.2001343	0.01
397.0829468	1.31
398.1164551	0.03
399.4331055	0.05
405.6209717	0.03
408.3937988	0.01
409.1873779	0.02
411.0395508	0.04
415.1693726	11.19
416.3483887	0.52
417.1116333	0.70
421.6867676	0.02
422.9031372	0.15
428.1716309	0.02
433.1034546	100.00
434.0940552	0.09
441.3028564	0.24
447.065918	0.02
449.4688721	0.02
456.2679443	0.01
457.1084595	0.11
457.8781128	0.04
459.2353516	0.28
461.0836792	0.03
462.8324585	0.10
464.0974731	0.05
475.2451782	0.08
476.2498779	0.06
481.5279541	0.04
483.5690308	0.01
489.3538818	0.05
490.2924194	0.02
497.3429565	0.04
498.3104858	0.04
499.0470581	0.02
502.295105	0.04
504.3612061	0.02
506.9879761	0.05
512.1530762	0.03
513.2930298	0.02
516.8340454	0.04
521.2857666	0.03
525.1400757	0.30
532.5490112	0.03
541.8897705	0.01
542.9899292	0.24
547.2141724	0.01
549.5476074	0.03
554.6332397	0.02
558.291626	0.05
559.3543091	0.04
560.2079468	0.47
561.1636353	0.35
569.6828003	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.37
Annotation	Unknow
Peak:m/z	Relative Intensity
201.1349182	0.13
206.2158661	0.04
207.0095520	0.05
210.0680389	0.39
221.0827026	0.10
221.9543762	0.24
223.1714783	0.26
226.9723053	0.07
228.0995178	0.09
236.1163635	0.21
236.9499207	0.04
237.9587402	1.83
238.9591522	0.39
245.2191925	0.04
246.0448761	0.09
247.1347504	0.36
248.0098572	0.12
248.9369507	0.10
252.1887817	0.35
253.7955017	0.06
258.2030640	0.11
265.0382996	4.16
266.1712646	3.01
267.0610657	4.88
268.1410828	0.33
272.1733704	0.29
274.9974060	0.06
279.1006165	0.18
280.0808105	0.43
281.0619812	0.32
282.2272339	0.08
283.1151733	0.06
288.1439819	0.24
289.0333252	0.08
293.2229919	0.13
294.3186340	0.30
295.1934204	0.11
295.9453125	0.19
305.1273193	0.20
306.2005005	0.19
307.2038879	0.60
307.9068298	0.32
313.1571655	0.12
316.1674805	0.08
317.1874390	0.05
318.5859375	0.11
319.3877563	0.12
320.4712524	0.03
322.4349670	0.06
328.0909119	0.71
330.2049561	1.54
331.2122192	0.03
332.5844727	0.09
335.9256592	0.03
336.9577026	0.09
344.2808228	0.28
345.2141113	3.97
346.1615601	5.36
347.1234131	3.82
348.0839844	1.79
351.5080261	0.10
360.6643066	0.05
361.9871216	0.19
363.1391602	3.56
364.1270752	4.29
365.0779419	7.21
365.8734741	0.36
367.0888672	0.26
368.3547974	0.06
377.2396851	0.06
378.1065674	0.14
379.8474121	0.14
381.1391602	21.96
382.1898804	41.11
383.1174927	76.49
384.1373901	0.07
391.4806519	0.06
397.4331665	0.04
398.8106079	0.14
410.0267944	0.06
420.1531982	0.11
421.5323486	0.05
422.3558350	0.08
423.3629761	0.07
424.6545410	0.08
426.1637573	0.46
427.3194580	0.15
431.2438354	0.09
432.4370728	0.38
438.1648560	0.11
443.5286865	0.12
444.3074341	0.07
450.3559570	0.22
452.4832153	0.56
453.2901611	0.85
460.3480225	0.05
461.8075562	0.21
462.5924072	0.18
466.2623291	0.11
476.4088745	0.11
478.1538086	1.17
479.0317993	3.48
480.0977783	0.38
483.3720703	0.14
488.1759644	0.28
490.9110107	0.11
492.1154175	0.69
493.1273804	0.32
502.5121460	0.02
505.2645874	0.08
508.8134155	0.51
509.4178467	0.24
512.3319702	0.28
514.5164185	0.09
515.5010376	0.04
517.9941406	1.18
519.1544189	0.96
520.0402832	0.30
521.3546753	0.13
522.3439331	0.04
524.2019043	0.86
526.7228394	0.05
530.0994263	0.19
532.0739136	0.64
535.3681030	0.21
540.2116089	0.13
542.0437622	7.62
542.6871948	0.16
544.4409180	0.05
545.5646973	0.62
546.4257812	0.13
547.2362671	0.47
547.9973145	0.29
549.5457153	0.42
550.1803589	1.05
551.8592529	0.45
554.3703613	0.11
558.1019287	2.61
559.0875854	5.33
560.0126343	1.07
562.1803589	0.05
565.9924316	0.52
568.0178833	3.76
569.3715210	0.31
572.0503540	0.28
574.0435791	0.06
574.7418823	0.07
576.1040039	6.66
577.1251221	7.78
578.3813477	0.13
579.8160400	0.28
580.6137085	0.19
582.5744019	0.05
584.0225220	0.09
588.9420166	0.23
590.1079102	0.33
592.5497437	0.66
593.3421631	1.75
594.2166138	37.33
594.9605103	100.00
596.2153931	0.11
598.4498901	0.10
605.1550903	0.10
607.1975708	0.22
608.0073242	0.49
615.0734253	0.29
616.3362427	1.18
618.6879272	0.13
620.4319458	0.24
623.2279663	0.03
625.1854858	1.73
629.2913208	0.06
634.0191650	6.18
634.6232300	0.33
638.4163208	0.80
646.7235718	0.02
649.1787109	0.03
651.1757202	0.29
656.1527100	5.27
658.0025024	0.31
660.4960327	0.16
663.5715942	0.14
665.3617554	0.09
667.5438232	0.11
673.3763428	2.29
674.2102661	15.93
676.2828369	0.16
692.1035767	43.87
693.0042114	0.05
693.7398071	0.12
711.3086548	0.05
723.6271362	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9563293	4.54
159.9416199	1.17
160.8807831	1.34
161.9622650	0.10
198.9928589	0.08
200.0029907	0.16
201.0692139	0.09
202.0977783	0.11
219.0818481	0.05
220.2378998	0.05
228.8565826	0.43
230.9649811	0.42
231.9490051	0.07
265.8587646	0.12
272.9435425	13.12
273.9221802	26.81
274.9191284	25.00
275.9175720	15.61
387.8003235	42.80
388.8583679	50.94
389.8681335	100.00
397.6196594	0.32
413.9958496	0.20
415.9226990	0.11
418.9510803	0.15
429.7889099	0.39
431.0463562	0.29
441.9962463	0.26
457.9429932	1.23
458.9601135	4.26
459.8417664	0.61
475.7857056	0.59
476.9728699	0.07
485.8950500	0.30
488.6128845	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1594
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
178.8808136	0.03
193.1057434	0.05
204.9434204	0.18
213.4084015	0.02
218.3137054	0.04
229.0579529	0.07
237.1639557	0.07
254.8829041	0.08
263.0489197	0.03
271.3092651	0.04
272.6135254	0.10
273.3535156	0.07
274.2723389	0.06
277.0872803	0.05
281.1440125	0.08
285.2377930	0.10
293.2564697	0.07
295.9188538	0.06
299.1140137	0.01
303.0287170	100.00
303.6688232	0.11
308.8880005	0.09
326.3930054	0.02
329.0576782	0.09
331.2277222	0.11
337.1336670	0.06
343.1698608	0.06
345.0331421	0.50
353.2805786	0.04
354.9279785	0.13
356.1574707	0.06
362.2180786	0.03
367.1600952	0.04
368.0338745	0.09
369.1304932	0.02
370.4365234	0.04
383.6874390	0.01
387.0077515	0.02
393.9813232	0.01
395.3143921	0.04
399.0744629	0.04
409.0893555	0.07
413.2168579	0.05
423.0505371	0.03
425.9326172	0.02
426.9896851	0.04
429.2338257	0.19
430.3745117	0.17
431.1439819	0.16
433.2710571	0.07
435.4390259	0.02
442.3813477	0.19
447.2551880	0.49
448.8373413	4.50
451.4248047	0.05
453.2553711	0.13
456.9573364	0.03
462.0000000	0.04
464.4665527	1.93
465.0788574	22.55
469.2544556	0.15
473.2490845	0.20
478.0809937	0.43
479.0523071	0.04
481.2146606	0.08
489.1272583	0.06
489.9086304	0.04
491.1971436	0.26
494.0722656	0.05
495.1025391	0.10
496.0474854	0.02
505.2046509	0.06
510.4027710	0.03
519.0851440	0.02
521.7890625	0.03
527.4163208	0.05
529.1071777	0.02
530.6156616	0.04
539.4783936	0.07
545.2066040	0.15
546.3442993	0.03
547.0216675	0.01
550.1690674	0.08
551.1018677	0.16
553.6831055	0.08
557.1057739	0.14
563.2548828	0.02
564.2711182	0.07
565.1810303	0.04
575.2171021	0.34
578.0497437	0.12
589.8081665	0.13
592.1608887	0.04
593.1568604	0.79
594.9124756	0.29
601.7752686	0.19
602.6354370	0.05
611.1193237	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.3226
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0868683	0.06
178.8516693	1.06
185.1411743	0.09
203.5534058	0.16
215.0328674	0.07
221.0008240	0.30
223.1176758	0.21
233.2847290	0.09
244.4169769	0.14
275.6282654	0.10
277.2764282	28.72
283.2375488	0.44
284.3081055	0.76
290.9756775	1.50
291.5959473	1.33
301.4057922	0.75
315.1137085	0.15
319.1038208	4.09
323.1035461	23.73
331.1677856	0.70
333.3706665	0.18
341.1782227	100.00
349.5790405	0.56
363.3109131	0.06
366.8613281	0.26
373.2567749	0.44
381.3082275	0.10
420.3723145	0.68
438.7617188	0.47
443.2091675	0.54
463.2949829	0.15
471.2802734	0.26
514.1606445	0.48
536.4968872	0.15
540.5243530	0.50
541.6933594	0.22
567.1920166	4.74
581.0558472	0.78
583.5188599	0.20
592.3640747	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1085
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
136.8256836	0.04
161.0343781	0.06
166.9930420	6.87
197.0169067	1.28
209.1139526	0.20
226.9937744	0.16
234.9728394	1.42
251.0843201	0.04
264.9559326	0.25
269.1458130	0.77
277.0210266	0.02
287.1155396	7.76
311.1664124	0.13
329.0953369	100.00
336.9331665	0.68
340.8710327	0.36
341.4957275	0.13
355.1794434	0.82
359.0405884	16.58
371.1581726	0.09
383.2245789	0.02
389.0903625	0.26
395.4344177	0.06
401.0561218	0.27
413.1373596	0.31
431.1368103	5.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	426.3013
Annotation	Tortifolisine
Peak:m/z	Relative Intensity
146.9714050	20.20
147.9999695	1.89
150.9425354	0.01
157.0599365	0.04
162.0191193	0.04
163.9678345	100.00
165.0392151	7.62
182.1631470	0.06
183.2344971	0.01
213.8879089	0.05
235.3201904	0.14
236.3575745	0.05
241.4085999	0.02
251.0429077	0.02
271.2691345	0.03
272.6112976	0.01
278.2164307	2.44
279.2530518	1.09
288.1149292	0.01
290.2313843	8.65
291.3537598	1.95
297.5628662	0.02
304.4667358	0.01
307.3638611	0.04
308.2813721	0.02
317.5399170	0.02
321.3651428	0.02
323.4820862	0.03
325.0166016	0.05
329.4733276	0.06
335.1657104	0.03
351.3759155	0.04
353.2836914	0.05
364.4723816	0.06
365.2649536	0.44
365.8731689	0.08
369.4312439	0.08
370.5709229	0.02
380.1780701	0.06
381.2521667	0.09
382.3123169	11.02
383.4035339	4.24
385.1661682	0.02
391.4279175	0.04
397.1175842	0.02
398.7062683	0.04
407.1387939	0.03
408.6050720	0.32
409.5578308	0.23
424.5436707	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.2681
Annotation	PS(17:1(9Z)/0:0)
Peak:m/z	Relative Intensity
153.0524597	0.13
167.4420776	0.05
170.7847290	0.10
179.1517029	0.09
185.2033691	0.35
195.9927368	1.79
197.0343933	0.11
209.0985718	0.08
214.0773621	2.69
249.4546204	0.20
256.2395630	0.04
261.9869385	0.05
275.2422791	0.37
279.2469788	0.04
293.1966858	100.00
295.1904602	0.03
311.2521057	1.66
339.2029114	0.03
347.3054199	0.11
364.0885925	0.04
368.7822876	0.04
391.3088074	0.03
392.4179382	0.03
394.1845398	0.18
406.6446228	0.03
420.2073669	0.23
429.1369934	0.41
447.1511536	0.04
448.4838562	0.07
452.1465149	0.04
462.2253113	0.09
463.1644287	0.04
465.1515503	0.02
468.8672180	0.15
472.1794739	0.14
490.2526550	48.59
491.1413269	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	868.2622
Annotation	Unknow
Peak:m/z	Relative Intensity
283.8119812	0.05
287.3020325	0.08
330.9192505	0.15
375.2144775	1.57
376.2084351	0.38
389.0916138	0.18
415.9707031	0.04
416.8876953	0.10
418.1771240	0.07
443.9773560	0.09
451.0343628	0.62
452.2265015	0.08
453.8551636	0.18
459.3202515	0.29
460.1013184	0.58
461.4133911	8.42
462.1209106	59.85
463.0947876	9.20
494.6101685	0.09
501.8847656	0.48
502.9785156	0.10
505.0848389	0.17
505.8577881	0.14
534.1593628	1.07
536.2250977	0.08
577.2270508	0.25
577.8887329	0.87
578.7869873	0.11
604.3334351	0.15
611.2301636	0.14
617.7729492	0.11
619.6769409	25.81
620.6953735	6.47
621.4281616	0.13
653.2271118	0.18
663.9380493	100.00
664.9736328	23.16
665.5866089	0.04
698.7489014	0.06
699.3922729	0.40
743.0077515	0.17
749.0775757	0.11
749.8565674	0.14
782.4165649	0.05
807.0892944	0.07
823.4739380	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
121.8168182	0.02
153.072052	0.01
159.1671143	0.01
160.7727814	0.01
169.0567169	0.02
179.0339661	0.01
180.9126892	0.00
191.0660706	0.01
224.904541	0.02
247.7819214	0.01
253.1585999	0.05
257.1054077	0.01
268.0916748	0.27
269.0552063	0.27
270.1291199	0.16
281.1752625	0.01
283.1802368	0.27
284.1364441	0.09
286.247345	0.00
293.2189331	0.21
293.9091187	0.01
294.5198975	0.02
295.2610474	0.00
296.1312561	0.04
297.3462219	0.01
298.2772827	0.02
309.0567322	0.07
311.0543518	100.00
312.0663147	33.10
319.2242432	0.01
321.2099609	0.03
322.4667053	0.05
323.1437683	0.11
324.1478577	0.10
326.2614136	0.04
327.2323608	0.01
327.9387207	0.02
334.9459229	0.01
336.9786987	0.25
338.1806641	0.13
339.3859253	0.00
341.11203	11.85
342.197998	4.76
347.463623	0.03
349.2527466	0.03
350.2297363	0.01
351.2024841	0.06
353.1564331	0.66
354.1738892	0.20
355.1468506	0.15
356.1479187	0.05
356.940155	0.01
365.2540894	0.02
367.2110291	0.04
368.3554382	0.01
371.0088196	0.28
372.0610962	0.10
377.1376038	0.13
377.9689941	0.13
383.1893921	0.26
384.2497864	0.19
385.2639465	0.01
387.0262756	0.02
387.9335938	0.03
395.1359558	0.25
396.0260315	0.10
401.2776794	0.03
413.0721741	1.33
414.2539978	0.94
415.1152039	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.517
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
241.0874481	6.54
259.0316772	0.89
279.2303772	63.70
280.1455383	1.27
281.3237000	0.36
291.3096924	0.18
297.1248169	11.72
304.5975952	0.38
309.1350708	0.12
315.1148682	1.52
323.5329590	0.53
413.3024902	0.14
415.1967163	49.53
433.1007080	1.97
445.1937866	0.23
502.2494507	0.51
521.1630249	0.75
561.1849976	0.89
577.2473755	100.00
577.9080811	0.57
578.6220093	0.44
595.3399048	22.64
596.4241333	0.30
638.8676758	0.16
696.4187012	0.39
708.1470947	0.27
733.3291626	0.38
734.5178223	0.13
739.5830078	0.11
746.3696899	0.07
778.5198364	0.98
779.2607422	0.62
780.5955200	0.11
792.3995972	2.57
793.6767578	0.72
794.7932739	0.83
796.4660034	3.46
797.4661865	1.80
813.1889648	0.13
839.6657715	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.1
Annotation	Dinex
Peak:m/z	Relative Intensity
83.0358810	0.03
94.0288544	0.12
94.9549408	0.08
99.9375000	0.03
105.9783936	0.11
107.0055389	0.03
108.1645203	0.01
118.1189117	0.17
119.0783081	0.25
120.3815918	0.41
120.9904633	1.24
121.9477234	0.07
123.1390991	0.01
124.1070251	0.07
128.7606506	0.01
129.9336243	0.01
135.9788666	0.36
136.9919739	0.12
137.9779510	1.83
149.9337616	100.00
151.2332611	0.04
166.8135223	0.07
176.7801971	0.01
182.9590149	0.03
185.9472046	0.05
197.1010437	0.03
202.9729156	0.02
204.0397339	0.07
204.7845764	0.01
206.9076843	0.02
208.8034210	0.06
210.9734650	0.07
212.3616638	0.01
219.1574554	0.03
221.3514557	0.02
225.1133881	0.02
231.0533447	0.05
234.7806549	0.01
239.2813263	0.05
246.1491852	0.05
246.8074188	0.02
248.9732056	0.26
250.0762177	0.24
266.9487610	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5167
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
240.9433136	5.28
259.1124268	0.86
261.1930237	0.50
279.2144470	83.05
280.6010437	0.55
293.0995178	0.50
297.0789795	10.12
314.9809570	2.55
415.2890015	50.84
433.4747925	1.31
503.0769043	0.28
560.4046631	0.51
575.0041504	0.13
577.3643188	100.00
595.2678833	18.29
596.5847168	0.14
597.3931274	0.22
792.5921021	0.29
796.4496460	1.13
838.4578247	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.3873
Annotation	PS(12:0/12:0)
Peak:m/z	Relative Intensity
181.1037445	0.03
184.0264893	0.03
194.9126434	0.04
201.2406921	0.02
214.2690430	0.20
218.9096375	0.09
224.1721191	0.02
227.2043762	1.17
236.1840820	0.06
241.8044586	0.03
242.8975220	0.06
245.1159363	0.34
254.0805817	0.09
263.0452881	0.03
265.1242065	0.06
277.2909546	0.15
282.5550842	0.04
283.5774841	0.10
295.5711670	0.09
296.2379150	0.03
299.2454834	0.03
307.1322632	0.29
313.2495422	0.19
314.2084961	0.03
315.2203979	0.04
317.3371277	0.03
325.0674438	0.12
327.6088257	0.05
328.3037109	0.05
329.4550781	0.06
331.2329102	0.02
338.4946899	0.09
340.4576416	0.12
341.7309570	0.10
344.2125244	0.08
348.1130371	0.04
350.3593750	0.07
351.4786987	0.15
354.4348145	0.03
355.1656494	0.18
357.9312134	0.06
365.2954712	0.07
367.1031494	0.09
368.1825562	0.63
369.6193237	0.12
370.3903809	0.12
371.3199463	0.05
372.2760010	0.15
375.1758423	0.03
380.1611328	0.07
386.1583862	0.09
392.6835327	0.06
393.3543701	0.31
395.7523804	0.05
398.5071411	0.11
402.3513794	0.02
403.1135254	0.05
405.1665649	0.07
415.5133667	0.04
418.3251343	0.32
421.3662109	0.09
423.5068359	0.04
427.1988525	0.03
429.6329346	0.03
433.3745728	0.05
436.1419678	0.08
453.8579712	0.08
454.5300903	0.24
459.3115234	0.03
462.3472900	0.06
463.5157471	0.12
465.6405029	0.09
466.4351196	0.07
469.4617310	0.12
477.5737915	0.15
479.3393555	0.03
480.7882690	0.07
483.3397827	100.00
484.0416870	0.36
488.4815674	0.16
491.3939819	0.04
492.3479614	0.04
493.8043213	0.04
495.6504517	0.05
497.1845703	0.14
502.2971191	0.04
509.2371826	0.23
511.4057007	0.11
513.4725952	0.03
514.5687256	0.08
519.4609985	0.06
520.7362061	0.26
523.2164307	0.12
525.3416748	0.06
529.5254517	0.02
531.6229248	0.07
532.5327759	0.03
533.4255371	0.05
535.2851562	0.09
536.1754761	0.13
537.3637695	0.10
539.4312744	0.04
540.0370483	0.07
545.8664551	0.02
547.3336792	0.11
549.5419922	0.06
551.8992920	0.22
556.3151245	0.06
557.4979858	0.02
562.6659546	0.08
563.4026489	0.12
564.3247681	0.55
565.3420410	0.71
566.1819458	0.05
578.4381104	0.09
579.2694702	0.04
580.6119995	0.48
581.3561401	0.13
582.3864136	0.05
583.4787598	0.08
587.5775757	0.04
588.3485718	0.25
589.2965088	0.39
591.4589844	0.20
592.5960083	0.28
593.5857544	0.08
594.5802612	0.03
596.5383301	0.07
597.4485474	0.01
604.1597290	0.05
605.2920532	0.34
606.3843994	1.84
607.4039307	0.33
610.0499268	0.08
623.4486084	0.75
624.7846069	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.11
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
123.8964081	6.70
145.0041962	0.34
180.0508575	6.65
197.9926453	100.00
209.1334229	0.13
255.9060974	0.12
259.0146790	0.27
282.3546448	0.18
291.3969116	0.18
293.1764221	0.43
300.1069641	0.26
302.5827942	0.51
307.6896973	0.11
333.4586182	0.29
356.1695251	0.98
356.9654236	0.11
357.7778015	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.3206
Annotation	Anandamide (20:2, n-6)
Peak:m/z	Relative Intensity
104.9992981	0.07
109.0194702	0.70
110.9797363	0.37
115.0680313	0.07
118.8210068	0.05
121.1075439	0.22
122.1983185	0.08
123.0059280	1.00
123.6123352	0.05
124.9882355	0.21
127.1575699	0.10
131.0287018	0.09
132.9182587	0.23
135.1349182	0.35
136.9921875	0.45
138.8594055	0.15
141.1707153	0.07
143.0119171	0.12
145.0878906	0.08
147.0626831	0.30
148.9548035	0.20
151.1398315	0.78
152.9058838	0.20
155.0283203	0.52
156.9550171	0.12
157.9236603	0.02
159.0961914	0.18
161.1095734	0.34
163.1585693	0.22
165.0114136	1.07
167.5383301	0.05
169.0151672	0.29
172.1119385	0.04
173.1227112	0.35
175.1315002	0.31
176.4987030	0.08
177.2097473	0.35
179.0848389	1.35
180.1363831	0.10
181.0221558	0.33
183.2084808	0.23
185.2819214	0.05
187.0430298	0.25
188.2292786	0.03
189.1644897	0.49
191.1740112	0.41
193.1899109	0.34
194.9864349	0.83
196.1435394	0.30
197.0509338	0.08
198.1397552	0.02
199.2634430	0.04
201.0717163	0.05
203.3267822	0.09
205.2529907	0.14
207.0478668	0.33
208.0600128	0.61
209.1793060	0.75
210.1603088	0.06
211.0713654	0.02
212.2268219	1.09
213.0393677	0.07
215.3179016	0.01
217.2820435	0.22
218.3685913	0.04
219.0483093	0.19
220.9626770	0.33
222.0946960	0.20
223.1151733	0.42
224.2812500	0.05
226.0178528	1.31
226.9936829	0.07
229.1418152	0.07
230.3052063	0.15
230.9994202	0.05
233.3132019	0.20
235.2227478	0.25
236.1046448	0.04
237.1393433	0.35
238.7627258	0.13
240.2120056	0.10
242.5126953	0.06
243.1466064	0.11
247.2955017	0.10
249.1021118	0.09
250.2798462	0.12
251.0799561	0.92
252.4617310	0.30
253.1733093	0.09
254.0926819	0.25
257.1403198	0.13
257.9772949	0.09
260.1437378	0.04
261.3299561	0.06
265.0391235	0.13
265.9335327	0.08
267.0664062	0.16
270.3719482	0.01
271.2330933	0.14
273.2540894	0.06
275.3640442	0.09
277.1937561	0.08
278.1682434	0.21
279.1614380	0.56
282.3781433	0.19
283.0907288	0.09
289.1225586	0.41
291.0784912	0.07
292.8928223	0.33
293.5557251	0.04
296.0911560	0.05
299.3219910	2.37
302.6628418	0.08
306.5454712	0.16
307.3407593	0.61
308.7419739	0.05
311.1608887	0.42
316.0571899	0.12
317.3028259	6.51
320.2479248	0.10
324.3578491	0.12
325.2551270	0.11
331.3231201	0.08
333.2225647	0.04
335.1873779	100.00
335.8375244	0.27
353.1891785	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1657
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
113.0241241	1.65
118.9856567	2.09
130.8684082	0.68
136.9802551	0.07
142.9427185	1.22
145.0010071	0.18
147.0938568	1.39
160.9852905	1.48
163.0316162	100.00
163.9804382	0.17
165.1435547	0.22
178.8680115	0.44
183.8720398	0.06
207.0332794	1.24
208.9721069	1.88
223.0616150	0.60
225.0414734	7.11
249.0605774	0.13
251.5007324	0.07
253.1824036	0.13
265.2091675	0.14
287.0084839	0.37
341.0060120	1.09
343.4720459	0.07
351.9916992	0.14
369.2400818	24.26
372.2463684	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1658
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
113.0775146	2.21
118.9007339	1.95
121.1644363	0.12
124.9019165	0.29
130.9924011	0.75
134.1589661	0.19
135.1537781	0.24
142.9951477	0.91
145.0824432	1.40
147.0662231	0.39
149.0961304	0.46
150.2237244	0.21
159.1018524	0.25
160.7588806	0.96
163.1082153	47.75
164.1618958	0.11
178.8911133	0.88
189.0506592	0.53
207.1049957	100.00
208.1121826	0.25
208.9103088	0.16
225.0807800	3.88
264.6970520	0.34
308.7980347	0.25
326.8900146	0.19
366.7524109	0.36
369.2791443	24.96
370.2505188	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.2701
Annotation	9-Hydroxy-10-O-D-glucuronoside-12Z-octadecenoate
Peak:m/z	Relative Intensity
151.0758362	0.09
152.8785095	0.24
161.0899353	0.24
165.0243530	0.20
167.0165253	0.08
177.0522919	0.69
179.1481323	0.47
181.1063232	0.42
183.0928040	7.71
183.9204407	0.23
191.2738647	0.28
193.2218933	0.29
195.1161499	1.52
196.0920410	0.32
203.0029907	0.11
205.3752136	0.24
207.0310516	0.49
209.3573914	0.21
211.1517334	9.15
211.9925385	0.06
213.2216187	1.27
217.1550903	0.09
219.0617828	0.12
220.9846039	0.58
222.9924469	0.70
224.1344910	0.41
225.1334534	0.15
229.4174347	0.14
231.2302094	0.40
232.9979248	0.05
235.3726959	0.25
239.1743469	0.11
241.1532898	2.70
247.0939331	0.98
249.4125977	0.78
251.3325806	0.45
253.2937622	1.20
257.2022095	0.07
263.3873901	0.10
265.0353394	0.39
267.3576050	0.43
269.2349548	0.59
271.3750000	0.45
273.1852112	1.67
275.1624756	1.45
283.1913452	0.36
285.2386475	0.27
291.2987061	32.42
292.2944336	0.83
293.2512817	11.08
294.4943237	0.10
305.1457520	0.17
307.1451111	0.62
308.5931702	0.94
309.2904358	16.51
311.1759033	100.00
312.3677979	1.62
313.3989563	0.25
315.1976929	0.77
316.9683533	0.08
319.4239197	0.10
324.5950623	0.38
325.3601990	0.06
327.3280640	43.41
328.3332825	0.92
333.2751160	1.19
351.3560181	1.31
353.4166260	0.37
358.3900146	0.15
367.3485107	0.16
368.8532715	0.33
371.1449585	0.07
373.2022095	0.22
381.1414185	0.45
381.9358826	0.20
393.2662048	0.33
400.8067932	0.09
429.2689209	0.59
431.1693420	0.37
441.1808777	0.07
444.9518738	0.19
445.9946594	0.14
447.1067810	0.18
453.2810364	0.97
457.2480164	0.22
471.3175964	33.73
472.2981873	0.47
480.4775696	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	752.4502
Annotation	Unknow
Peak:m/z	Relative Intensity
259.1219482	0.03
284.8991394	0.06
288.0641785	0.94
304.4205017	0.06
310.8887329	0.08
313.7235107	0.05
323.1554565	0.17
325.3264160	0.08
327.1755371	0.76
331.3483887	0.15
375.5004272	0.07
380.1143188	0.13
410.0744629	0.17
432.4549561	0.46
444.4871216	0.19
454.2888794	0.07
472.4580688	0.91
476.5391846	0.17
488.4686890	0.19
491.5886841	0.05
493.2794800	0.05
498.3623047	0.07
520.3700562	0.03
533.4520264	0.10
538.7170410	0.20
562.2816772	0.09
571.2966919	0.02
572.6538696	0.45
575.4965210	0.03
579.8643188	0.10
585.5349731	0.19
587.4331665	15.71
605.2800903	9.76
611.2839966	0.41
614.5299683	0.13
623.2002563	0.75
625.4295044	0.22
644.4358521	0.06
645.3825073	0.46
653.4332275	0.29
663.5859375	0.13
679.0529785	0.04
685.7077026	0.11
706.6113892	0.04
709.9462280	0.12
716.0961304	0.45
716.9480591	0.22
724.8093262	0.26
734.2850952	100.00
734.9566040	0.73
752.4537964	0.21
753.5479736	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.1622
Annotation	Unknow
Peak:m/z	Relative Intensity
156.1947327	0.02
181.9525452	0.05
201.9975281	0.40
202.9752045	0.02
204.1430664	0.09
204.8618774	0.03
218.3046417	0.01
220.2564697	0.07
234.9755249	0.02
245.2979279	0.05
247.1379700	0.26
248.0684204	1.01
261.2289124	0.03
265.0064697	100.00
283.5317383	0.04
284.4214172	0.05
291.9963379	0.02
317.2575684	0.06
318.9494019	0.06
319.9754639	0.02
321.0555420	0.12
322.1583252	0.06
337.0787964	0.18
338.8751221	0.13
348.1127930	0.03
349.0169067	0.05
353.3976440	0.04
364.8906250	0.02
366.0496216	0.10
367.3231201	0.03
369.1085815	0.07
383.1499023	0.03
393.7542725	0.03
397.4091797	0.03
399.2048340	0.14
400.1364746	0.26
425.1274414	0.04
439.1225586	0.05
443.3295898	0.04
448.2149658	0.15
457.1752319	0.02
464.0177002	0.01
475.3907471	0.04
477.9868774	0.02
479.2318726	0.01
481.1221924	0.06
485.2012329	0.10
493.5674438	0.03
498.8643799	0.06
510.2064819	0.31
511.1282349	0.58
512.1719360	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
251.307724	0.26
255.2430725	46.03
256.1300049	0.25
261.0499268	0.49
269.3490601	0.21
277.2858582	0.53
279.2355652	100.00
279.8476562	0.45
281.3086243	0.14
287.1824646	0.08
307.5800171	0.22
311.1759338	0.23
392.1956787	0.07
415.0710449	0.19
419.2822876	0.51
431.3656616	0.27
434.3204346	2.76
437.3048096	0.15
452.3070068	20.44
453.2844849	0.09
458.3602905	1.27
476.2496338	2.30
536.2858276	0.21
553.449646	0.07
578.461853	0.14
594.281189	0.49
611.5579224	0.26
619.1300659	0.18
626.5375366	0.15
639.519165	0.13
654.4902954	0.08
655.2888794	0.04
663.4273071	0.10
685.5014038	0.08
686.3588257	0.14
696.0759888	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.3044
Annotation	Aristolin
Peak:m/z	Relative Intensity
175.9402008	0.21
184.0324554	0.07
185.1930695	0.12
192.9886169	14.88
213.3583069	0.06
215.1239014	0.84
216.9206238	0.17
232.9488373	1.75
235.0027466	0.11
255.0358582	0.54
259.1616211	0.04
266.9972534	0.12
271.2198486	0.30
273.2673340	0.65
286.2092590	0.21
290.8318481	0.11
291.4423828	0.10
304.0299072	1.46
309.2904663	1.99
319.0677490	0.51
320.1448364	0.33
322.0670776	100.00
322.8563232	0.14
324.0283508	0.31
336.3695068	0.40
337.8110352	0.18
342.4087524	0.14
352.3892212	0.18
376.1466064	0.18
388.8658447	0.23
401.2940063	0.40
402.3704224	0.20
415.1683350	0.19
424.4212036	0.09
471.3002319	0.16
483.3135986	0.90
484.0839844	0.22
486.1853027	0.19
488.2313843	0.05
501.1984253	1.25
503.6932983	0.38
509.2598267	0.13
510.1058960	0.24
511.3433228	0.07
513.1552124	0.23
515.2206421	0.09
543.8078003	0.48
556.0877686	0.98
556.7302856	0.22
558.2119141	0.34
565.3844604	0.05
568.1822510	0.10
594.2205200	0.63
595.2612915	0.56
597.0589600	0.09
603.3379517	0.23
612.1085815	2.43
613.8815308	0.84
616.1425171	0.11
616.9430542	0.15
620.9309692	0.18
621.9721680	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1035
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
150.9594727	20.85
163.0633545	0.12
168.9763947	0.61
175.0690613	0.26
175.8749695	0.03
176.8928223	0.56
178.9202576	0.45
180.1689148	0.10
182.9219971	0.04
199.1463013	0.33
217.1932526	0.19
218.8913269	0.12
240.9470825	0.84
257.0742188	0.47
259.1007080	0.13
260.8259888	0.08
265.1895142	0.07
267.1900024	0.13
271.2252502	0.12
275.1122131	0.35
285.0502930	100.00
285.8427734	0.01
297.0324707	0.23
300.9248962	0.15
302.4526978	2.05
303.1595459	12.30
313.1942139	0.75
339.0488586	23.82
343.1314697	0.68
355.1503296	0.29
375.1444397	0.04
403.0748291	0.13
421.2387085	0.15
447.2304382	8.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.1964417	0.34
203.998291	0.07
220.9723816	4.95
250.3657379	0.65
262.890564	0.74
279.851593	0.38
280.893219	1.46
305.081543	0.92
310.4741211	0.07
311.1748047	0.27
314.9894409	0.18
321.2221069	0.86
323.0864868	4.71
340.9517212	31.90
341.6066284	0.25
383.1199341	100.00
399.5296021	0.05
407.2026978	0.24
411.1495972	0.12
412.8198242	1.86
424.9598999	1.04
442.388855	4.36
443.0335083	21.21
448.8318481	0.06
449.5984497	0.07
467.1255493	0.62
472.9567261	0.95
485.1902466	31.06
503.0059204	3.83
545.2901611	1.64
604.8554688	0.31
617.0487671	0.23
647.2936401	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
151.2302246	0.02
160.8830872	0.02
179.0652466	0.02
181.1030884	0.02
189.0474854	0.04
191.1116333	0.02
192.020874	0.04
193.133194	0.07
211.1387939	0.03
222.9802094	0.02
243.0595398	0.05
255.2351685	0.01
257.4820862	0.08
266.3197632	0.01
267.0678406	0.14
273.2437134	0.06
283.1372681	0.44
285.0344543	100.00
286.0540466	0.19
293.2239075	0.03
296.8823853	0.02
298.2861023	0.09
299.0910645	0.02
303.0935059	0.01
306.0415039	0.04
309.1653137	0.11
311.2100525	0.03
313.1378479	0.58
314.1286621	0.17
315.3137817	0.05
317.3828735	0.01
321.2666016	0.10
323.111908	0.03
325.039978	0.08
327.1192932	9.54
328.0597839	0.03
339.3798218	0.06
341.1747437	0.08
342.1973877	0.11
351.5468445	0.04
354.2337341	0.03
357.1790466	2.72
359.1899719	0.13
359.9628906	0.08
367.3132629	0.02
369.0989075	0.34
373.1732788	0.03
384.3602905	0.14
387.1804504	0.28
387.9129944	0.08
390.8007507	0.02
393.1472473	0.12
398.9420471	0.08
401.1605835	0.11
402.1427002	0.10
403.3139954	0.05
405.5083313	0.02
411.2038269	0.06
411.9977417	0.03
416.1950073	0.21
428.5065918	0.28
429.2895203	0.41
429.9934998	0.02
432.4056091	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0772
Annotation	Acerosin
Peak:m/z	Relative Intensity
107.0134201	0.02
108.9856796	0.19
110.9807358	0.23
117.1661606	0.08
124.9100876	7.57
135.0335541	0.09
136.7860413	0.12
139.0002136	0.03
152.9566193	0.19
161.1337280	0.07
167.1018982	0.28
179.0469360	0.29
196.9699707	100.00
203.0698090	0.04
207.1026917	0.01
220.9743347	0.21
223.0214539	0.07
226.6739807	0.03
235.0635681	0.11
239.1749268	0.32
247.0204163	0.02
253.0298462	0.09
263.3327026	0.02
265.0418396	6.02
287.2079773	0.08
296.7471924	0.10
297.3546143	0.06
314.9081421	0.27
341.1470032	3.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.2527
Annotation	8-HpOME(6E)
Peak:m/z	Relative Intensity
90.9290161	0.03
93.1006775	0.08
95.2208786	0.09
96.8796387	0.13
98.9546356	0.04
105.0937195	0.06
106.8723068	0.03
110.8854828	0.09
119.0855255	0.07
121.0324097	0.04
123.0131683	0.19
125.1661987	0.02
126.9570770	0.03
130.1330566	0.03
131.5335999	0.05
132.8488159	0.11
134.9772949	0.21
137.1745911	0.11
138.1370544	0.09
138.9842072	0.03
140.9111633	0.24
143.0513000	0.05
147.1056824	0.86
148.8233948	0.06
151.1405182	0.09
153.0505371	0.04
155.0479126	0.14
156.2449341	0.13
158.7903442	0.57
163.1708069	0.09
165.1335297	1.61
168.8200836	0.05
171.0223846	0.65
172.8937683	0.08
175.3123627	0.04
177.0880737	0.02
179.2379150	0.04
181.1054993	0.02
182.9728851	4.27
185.0594635	2.38
187.2688904	0.09
188.1222992	0.04
193.1513824	0.03
194.9490967	0.03
196.7588959	0.03
200.9753723	1.36
202.9997253	0.44
206.1314697	0.09
207.0411987	0.01
211.0035400	0.17
212.9941711	0.04
215.3084717	0.07
220.8301392	0.02
221.4857178	0.06
222.8942871	0.07
229.1995850	0.07
230.9798889	0.09
233.3200378	0.05
235.1869812	0.13
239.1755981	0.04
241.1818542	0.22
243.0453186	0.16
245.0480042	0.04
248.7717285	0.12
253.3741760	0.17
255.2741089	0.29
256.2501526	0.02
257.1580200	0.09
259.2399292	0.08
261.2013855	0.18
267.0640259	0.21
267.9141846	0.04
268.9999390	0.15
269.6071777	0.01
273.3084106	0.04
276.9990234	0.03
279.2133179	20.85
281.1105957	0.02
283.1917419	0.38
283.9295654	0.08
286.1977844	0.04
287.2445679	0.09
291.3504028	0.08
294.4608765	0.03
295.6000671	0.03
297.1572876	100.00
298.0809937	0.10
300.0794983	0.06
306.1818237	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	987.479
Annotation	Ageratoside B1
Peak:m/z	Relative Intensity
321.2120972	0.43
323.0924377	0.19
383.0512085	0.18
422.4522095	0.31
439.4518127	14.67
483.4928589	0.36
485.2105408	0.08
486.9250183	0.29
501.6297913	0.41
520.0345459	0.08
536.4793701	0.15
543.6361084	0.16
549.1834717	0.15
551.2960205	0.22
564.4766846	0.05
620.1510010	0.03
629.1385498	0.07
644.9375610	0.07
656.7974854	0.12
661.3955688	0.26
663.4728394	100.00
677.9997559	0.12
679.2171631	1.36
679.8897095	0.25
683.2718506	0.17
705.5643311	1.57
709.4359131	0.45
735.5769043	0.13
747.4813232	0.08
763.2953491	1.12
787.0744629	0.20
789.3782959	0.04
793.0312500	0.06
806.9364014	0.18
807.6040039	0.11
824.1041260	0.35
825.3233643	1.38
850.0625000	0.06
867.2841797	0.19
896.6363525	0.07
900.9471436	0.18
901.8585205	0.27
925.7292480	0.09
941.1302490	1.33
942.9370117	0.27
969.3432617	0.93
969.9888916	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1665
Annotation	Diosmin 
Peak:m/z	Relative Intensity
226.838089	0.04
235.2041016	0.12
257.0473022	0.04
284.0794678	13.59
299.0474854	100.00
299.9098511	0.26
310.2377319	0.05
311.2258301	0.03
313.0102539	0.03
315.1360474	0.02
316.0966187	0.08
325.1453857	0.18
327.2216797	0.09
339.3260498	0.21
341.2724609	0.25
345.1034546	0.09
356.3530273	0.04
358.5869751	0.02
372.2661133	0.19
378.1396484	0.02
381.0710449	0.08
383.1785278	0.10
384.1629639	0.10
385.2368774	0.08
393.3971558	0.01
397.239502	0.06
398.2616577	0.01
403.0765991	0.26
408.2214966	0.02
413.1114502	0.06
431.2202148	0.24
458.2824097	0.03
461.0022583	0.05
463.3950806	0.05
468.1968384	0.03
473.3308105	0.02
485.1051025	0.15
486.1083984	0.04
487.2052612	0.54
489.1434937	0.03
499.1566772	0.03
501.5921021	0.04
502.3510132	0.07
517.1431274	0.30
518.1400757	0.03
521.2224731	0.04
529.4161987	0.03
531.2723999	0.05
533.2651367	0.12
535.2959595	0.02
536.1585083	0.10
543.277832	0.14
544.470459	0.05
545.3156128	0.11
547.1390991	0.07
554.0712891	0.10
559.3762817	0.33
560.2236938	0.22
561.2600098	0.34
562.223938	2.00
563.3643188	0.49
564.2119751	0.05
565.3928223	0.02
568.9180298	0.04
574.2105713	0.02
579.7852783	0.06
582.9989624	0.11
583.7090454	0.04
584.9933472	0.03
587.382019	0.07
588.041626	0.03
589.2490234	0.62
590.3674927	0.14
592.4473877	0.03
597.1843262	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
178.7555695	0.03
269.01651	0.31
283.1367188	0.32
293.2112427	0.08
295.2300415	0.01
309.3938599	0.03
311.052002	100.00
311.9067383	0.35
312.6895447	0.01
323.0881348	0.47
325.1425781	0.12
327.0220947	0.02
334.9750061	0.02
337.1071167	0.04
341.1563416	15.01
341.9129028	0.08
347.3679199	0.01
349.2804565	0.03
353.0897217	0.65
355.0869751	0.22
364.9454651	0.08
367.1589355	0.04
369.1880798	0.01
371.0236511	0.27
377.0620117	0.21
383.0290833	0.33
385.2272949	0.01
395.1482239	0.27
401.3408813	0.02
413.1861267	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.2785
Annotation	Unknow
Peak:m/z	Relative Intensity
197.1468506	0.61
211.5272064	0.07
212.9833069	1.22
222.9828491	2.56
235.0533447	0.14
241.0108948	14.90
249.2137756	0.06
255.2180328	0.18
259.1588135	3.69
268.9209595	0.07
285.2088623	0.21
293.1740112	36.88
293.7918701	0.13
297.0578613	2.12
302.3418579	0.09
311.1805115	2.64
314.1026611	0.09
315.0559692	12.75
316.0695801	0.17
320.2534790	0.08
328.6452637	0.22
331.4307861	0.14
333.1586914	1.67
338.3401489	0.08
355.9232788	0.07
365.2611694	0.30
373.6239014	0.11
401.0775757	0.18
422.1528931	0.14
428.0825806	0.22
429.2070312	9.85
434.4016113	0.19
439.9468384	0.18
443.5010986	0.04
447.3269043	2.08
448.3261108	0.06
449.2423096	1.79
457.0446777	0.49
487.0211182	0.36
497.2461548	0.70
499.3992920	0.53
506.2387085	0.16
511.2777100	6.53
513.1435547	0.16
515.5358887	0.37
525.4866333	0.39
527.5877686	0.15
535.6240845	0.08
539.2089844	27.72
539.8453369	0.15
553.2423096	0.27
559.4013062	0.13
567.1147461	0.32
581.4268799	0.24
593.3229370	0.14
594.2600098	0.76
609.3208618	100.00
610.3894653	4.07
618.4225464	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	943.5237
Annotation	23-Hydroxyursolic acid 28-O-alpha-L-rhamnopyranosyl-(1->4)-beta-D-glucopyranosyl-(1->6)-beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
269.4012451	0.19
272.4336243	0.03
273.2123718	0.07
274.6915894	0.05
275.3999329	0.11
276.9772644	0.04
281.1388550	0.34
282.3936768	0.11
283.3345032	0.11
286.2359009	0.15
287.0569458	0.44
291.0745544	0.05
295.3020935	0.03
297.5590515	0.09
302.3359375	0.18
305.0309448	1.14
308.8704834	1.31
309.9447632	0.27
311.4103088	0.19
313.0322266	0.21
315.4838257	0.46
316.4019470	0.35
319.2615967	0.13
320.7427979	0.55
322.9294128	1.98
324.0782471	0.30
326.9813538	0.12
329.2898560	0.08
330.4242859	0.04
334.8582764	0.13
335.6081848	0.13
338.0869141	0.04
338.9002686	0.47
340.9525757	0.06
349.3560181	0.27
351.1663818	1.06
363.1542969	0.20
365.3764038	0.39
366.1212769	0.06
370.2970886	0.05
371.3253784	0.15
375.2093506	0.05
377.5086670	0.20
378.8577881	0.18
381.5491028	0.06
383.3173523	1.15
391.4498291	0.07
392.9290161	0.07
393.5870056	0.14
395.1394653	0.28
397.5479126	0.03
404.2878113	0.12
405.3148499	2.65
406.0450134	0.02
409.0795288	0.03
411.4443970	0.42
412.1776123	0.14
413.2785645	0.10
415.0663452	0.07
419.0983276	0.05
420.9877930	0.26
423.3021851	20.60
424.3090820	1.48
430.9656372	0.06
435.5919189	0.37
437.2549438	0.10
441.2288818	33.93
442.2503662	2.37
457.1609497	0.14
458.4640503	0.90
459.3284912	1.66
460.1572266	0.46
466.2410889	0.06
466.9166870	0.14
477.5781250	0.21
484.9458618	0.57
485.9443970	0.07
503.2665405	0.04
505.7775879	0.06
515.1524048	0.04
527.3889771	0.34
530.2963257	0.03
533.2385864	0.17
534.3013916	0.03
535.5449219	0.14
551.0479126	1.18
552.7810669	0.33
563.4326782	0.28
568.8934937	1.35
569.7753906	0.32
580.3539429	0.65
581.3377075	8.14
582.3837891	1.42
587.0650024	0.24
597.5039673	0.20
599.1765137	57.79
600.2861938	4.22
604.5437012	1.17
605.1665039	10.50
606.2113647	1.35
608.9177856	0.09
616.2729492	2.58
616.9928589	37.09
618.1022949	1.85
620.9014282	0.70
622.0741577	0.09
633.4344482	0.42
634.8789062	9.23
636.0079956	0.90
651.4054565	0.30
658.9088135	0.13
683.6760864	0.03
687.3589478	0.28
689.2977905	0.07
692.3890381	0.05
694.9450073	0.09
706.8967896	0.21
709.1163940	0.23
709.8718872	0.38
723.8997192	0.09
725.1725464	0.17
726.9896240	0.64
731.0047607	0.08
732.3053589	0.10
739.2375488	0.19
740.1276245	0.04
741.5861816	0.05
743.4747314	0.38
744.2787476	0.52
745.3995361	0.34
751.3195190	0.05
752.3862305	0.05
762.5831909	1.06
763.2084961	2.18
764.0652466	0.17
767.0383911	3.11
767.7739868	0.16
769.2274780	0.10
770.0499878	0.02
772.0098267	0.06
778.8354492	1.89
779.7127075	0.32
780.9980469	12.66
782.2504272	0.84
783.4110718	0.04
785.5609741	0.09
797.0579834	100.00
798.1126099	7.10
798.7770386	0.17
799.4859619	0.14
805.0728149	0.27
810.3543091	0.09
823.2583008	0.08
825.5654907	0.22
826.4353638	0.13
853.2702026	0.51
870.8947754	0.14
873.7936401	0.53
888.0762939	0.11
890.3938599	0.05
899.4255981	0.13
925.0164795	3.57
926.1953735	0.88
926.8464966	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.1431
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
69.9656219	0.05
70.8329697	0.27
76.8536987	0.22
81.1158447	0.12
82.7633514	0.19
90.9886704	0.08
93.0424194	0.10
94.9474029	0.19
95.9923553	0.09
97.5997772	0.13
98.8281555	0.07
99.8969421	0.16
101.3451538	0.09
105.0182037	0.24
106.8514252	0.14
107.9331970	0.54
109.0093842	0.11
111.1389008	0.08
113.0075684	0.06
114.1793060	0.07
115.4261780	0.08
118.9691162	0.16
121.2217560	0.20
125.0909729	0.12
128.9377747	1.18
132.8903046	0.38
135.0113983	0.25
140.9633484	0.34
145.0480804	0.18
146.8882904	1.14
148.9424591	0.19
151.0246124	0.42
153.0656586	0.50
154.8973999	0.24
158.9765167	0.06
161.0986328	0.17
165.2612305	0.03
166.9411621	0.10
167.9203339	0.18
169.0914764	1.07
169.8674774	0.09
171.0646362	0.23
172.9066772	0.28
174.8174286	0.06
183.0944519	1.18
184.2722168	0.35
185.1124573	0.80
187.1002350	0.35
188.0135498	0.69
189.8829651	0.11
191.1812592	0.05
193.1065979	7.54
197.0523529	0.43
199.0722504	0.10
201.1195831	0.65
208.9347534	0.54
211.0116577	100.00
211.9215851	0.15
212.7282562	0.09
214.3175507	0.30
220.2801971	0.08
224.6886749	0.09
229.0927277	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0859
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
119.9173584	100.00
120.6802826	0.03
130.9568787	0.34
138.2158508	0.03
147.7834625	0.65
148.9626465	4.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	Phosphatidylethanolamine 16:0-18:2
Peak:m/z	Relative Intensity
214.2837982	0.35
231.1293335	0.11
241.0014191	0.35
253.9701538	0.06
255.2842407	36.67
256.2030334	0.09
261.59729	0.07
269.2169189	0.12
279.1681213	100.00
279.9367676	0.18
282.9965515	0.19
283.6349182	0.07
284.2636108	0.08
291.0015564	0.48
293.1802063	0.73
297.2675781	0.10
305.9002075	0.23
307.1395264	0.35
309.2090759	0.11
363.2282715	0.10
366.2717285	0.12
377.2119141	0.22
378.3031006	0.23
391.0774536	0.05
397.9534302	0.08
408.9096069	0.26
415.2374268	0.04
434.3043213	1.32
438.1711426	0.10
448.1891479	0.06
452.3286133	14.67
453.326416	0.06
457.1453857	0.22
458.5493774	0.43
471.5194702	0.08
476.3248901	1.70
488.336731	0.34
516.4303589	0.24
532.7706909	0.17
553.4054565	0.32
567.3699341	0.09
571.4448853	0.08
590.104126	0.09
593.6500244	0.06
622.65802	0.30
632.862915	0.34
636.5067749	0.12
655.060791	0.12
668.0727539	0.12
673.7379761	0.10
694.3916016	0.18
695.2990112	0.09
696.3475952	1.79
699.6069336	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.36
Annotation	Denin
Peak:m/z	Relative Intensity
190.8304596	0.06
199.1226349	0.03
200.0086517	0.05
203.0610657	0.13
209.0184326	0.04
219.0700531	0.05
221.1775818	0.36
232.8926849	0.12
235.0476379	5.56
238.9373932	0.03
241.3226929	0.11
245.0281677	0.53
246.2246857	0.06
248.9259796	0.06
253.0990601	2.41
259.1157837	0.15
262.9467163	0.14
269.0496216	0.27
277.2537231	3.35
280.5751343	0.09
281.2808838	0.04
285.1242981	0.08
287.0632935	4.78
293.0525513	0.95
293.6724854	0.14
295.3425903	0.14
296.3890991	0.24
303.3733521	0.04
305.1087036	6.32
323.1390381	1.20
345.4467163	0.09
349.3513184	0.08
361.2125854	0.13
378.9989624	0.23
382.3399658	0.09
392.1530151	0.10
397.1221313	100.00
397.9603271	0.08
415.1294556	34.73
415.7524414	0.04
417.2153931	0.06
424.4378662	0.05
427.3583984	0.03
453.3261719	0.06
480.8014526	0.07
492.5519409	0.04
502.3659058	0.06
503.4700317	0.05
507.1966553	0.03
513.1193848	0.67
515.1892700	0.12
533.1185913	0.07
587.2983398	0.12
593.8768921	0.04
598.0543213	0.17
615.4557495	0.16
617.5277710	0.11
627.0888672	0.06
628.5462036	0.21
631.0427246	0.11
632.1843872	0.07
632.8328247	0.06
641.1971436	0.07
642.3713989	0.05
656.6227417	0.66
657.3872681	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.958
Annotation	Unknow
Peak:m/z	Relative Intensity
127.8703003	0.13
155.8410645	0.79
169.8129272	0.77
183.9771118	0.90
198.2516174	0.19
199.9304810	13.44
200.9509583	0.72
213.9168396	2.24
217.9666748	0.27
225.6257935	0.36
227.6904602	0.70
228.2949829	0.08
241.7872009	0.44
243.7434998	4.75
244.3478699	0.08
245.7875061	2.23
255.5508118	0.14
257.9552002	53.93
261.9729004	2.41
284.0233154	1.62
285.8588867	6.49
287.8962402	10.14
289.7029419	1.90
290.3510132	0.13
299.7390442	1.00
301.8689270	44.20
303.9756775	2.04
313.9682922	0.51
318.0284119	0.04
326.3742065	0.54
327.8880615	2.80
329.0767212	0.55
329.7508240	6.92
331.9240417	100.00
332.9243164	0.55
336.9057312	0.28
338.1822815	0.06
345.6871338	21.70
347.3588562	1.07
347.9634094	0.39
349.7980652	0.06
353.2180176	0.16
357.7863770	0.55
373.6152649	2.10
375.6109619	0.29
390.0774841	0.31
391.9425659	40.62
392.9876709	0.39
399.8855591	1.94
417.9026184	80.09
427.4679565	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1091.3447
Annotation	Unknow
Peak:m/z	Relative Intensity
383.2288513	0.09
412.9545898	0.07
485.0873413	0.04
502.8075867	0.90
545.1685791	0.98
574.9604492	0.16
605.0050049	0.30
665.0885620	0.27
753.0396729	0.07
809.0634766	0.15
827.2960205	100.00
956.1944580	4.08
962.3569336	0.13
987.1528320	0.18
1003.9395750	0.07
1026.9877930	0.17
1073.1533200	9.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.0598
Annotation	Isoflaccidinin
Peak:m/z	Relative Intensity
91.0160980	0.62
92.8948059	0.35
94.8903809	0.27
107.0064850	0.16
109.0208435	0.07
118.9794540	5.62
120.8039398	9.13
122.1881790	0.62
122.9203644	1.52
124.0423737	0.11
124.9621735	0.04
129.0673370	0.09
133.2523804	0.06
134.9834290	0.16
136.9437714	1.29
137.9757996	0.16
145.1198425	0.20
151.0647736	0.06
153.1214294	0.03
157.1433258	0.04
162.9246521	1.67
164.8734741	100.00
165.9870605	6.54
166.9990234	0.06
172.9734802	0.15
181.0921936	0.29
182.9510956	0.52
183.8051605	0.15
184.7685852	0.25
186.9252167	2.66
187.9991302	0.43
199.0202637	0.11
201.0779114	0.07
208.8527832	0.38
211.0544739	0.06
212.9769897	0.90
214.0652466	0.34
227.2465820	0.60
228.0824280	0.11
237.1653442	0.07
237.8549805	0.10
239.1734009	0.17
241.1090393	1.34
241.9369812	0.17
247.2178955	0.05
255.0534058	8.74
256.0438843	2.04
265.0635986	0.88
267.0967407	0.50
282.0089111	0.87
283.0397339	23.49
283.9516602	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.112
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
197.0400391	0.02
239.0143127	0.02
271.0472717	0.41
283.1301575	0.77
290.9009094	0.03
295.0825500	0.88
307.0825806	0.03
311.0166321	0.21
313.0491028	16.79
313.9443970	0.09
325.4094238	0.08
327.3998718	0.02
337.0770264	10.71
337.8494873	0.03
343.0108643	0.48
349.3095398	0.14
351.1885986	0.26
361.1634216	0.08
367.0715027	27.39
367.6725464	0.03
368.9978943	0.05
372.0842590	0.11
373.1721191	0.08
373.9857483	0.09
375.0314026	0.06
379.0735779	7.02
379.6761780	0.02
397.1221008	17.51
401.2111816	0.06
405.2186279	0.03
409.0735168	0.07
415.0946045	100.00
415.7010193	0.98
416.4298401	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.2336
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1784515	0.23
195.0148621	0.65
229.0963593	0.22
240.9540558	1.26
246.8919373	0.25
258.6644897	0.93
270.8388367	8.29
281.9528198	3.52
288.2065430	1.68
288.9896851	9.80
305.0750427	0.11
306.2561951	2.28
306.8631592	6.70
309.3678589	0.43
320.7282410	1.10
324.3780518	32.07
325.0036926	100.00
327.0667114	0.17
336.3733521	0.15
338.3150635	1.40
340.7139893	0.64
342.1686401	23.89
342.7812500	92.36
343.5092773	0.12
356.2663574	1.00
356.9478149	1.53
435.4671021	0.14
437.5048218	0.59
438.4265747	1.00
443.3856201	0.71
450.7888794	3.56
452.5393066	0.53
461.9629517	18.42
468.8406372	0.18
476.6558838	0.24
484.9395142	0.56
486.0649414	2.77
486.8910522	7.81
503.6875000	0.69
504.5381470	3.98
518.8344116	1.84
519.8771973	0.17
588.4618530	0.36
605.5786133	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1657
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9530106	2.02
118.9579620	1.65
124.9924850	0.57
130.8933563	0.32
142.9393768	0.92
145.1468811	0.61
146.9884033	0.51
148.7492065	0.81
159.1202698	0.26
160.9708557	0.32
163.1160889	100.00
164.4997864	0.12
178.8560181	0.18
181.1847687	0.46
189.2416992	0.07
197.2988586	0.08
207.0784912	14.79
208.0439606	0.15
209.1885376	2.24
220.8450317	0.17
224.0257568	0.05
225.1499634	1.45
236.8181763	0.28
249.2494812	0.41
343.0993042	0.12
369.2205505	14.35
369.8490906	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1055.5059
Annotation	Unknow
Peak:m/z	Relative Intensity
303.4831543	0.12
316.9056091	0.09
318.1459961	0.02
319.3086548	0.12
335.3032532	0.04
337.3721924	0.40
345.1309814	0.04
347.3609619	0.38
365.1429749	0.30
465.3419495	0.27
479.4346924	0.07
483.2438354	0.06
497.2697144	1.34
499.3114319	0.77
509.4223328	0.08
527.2639160	100.00
528.2561035	1.02
573.1329346	0.07
737.4697266	0.06
773.4078979	0.04
996.0910645	0.01
1009.0446780	0.08
1028.5046390	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1336
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
95.90940857	0.02
106.0175018	0.12
106.9156647	0.02
107.916748	1.84
122.8385086	0.02
123.9427338	0.04
127.0073547	0.02
134.0661926	0.46
135.9401093	2.10
152.0068054	6.87
154.0021362	0.21
169.9494934	8.96
174.3627167	0.02
195.6621704	0.02
200.9879456	0.04
201.8472595	0.10
214.1879272	0.03
215.9672241	0.02
220.0631714	0.02
231.9946289	0.02
240.2183533	0.02
244.4247742	0.01
251.1657715	0.05
260.3110352	0.01
286.0938721	0.07
288.1163025	0.04
296.12854	0.25
304.4703979	0.03
309.5125732	0.11
314.1264648	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.3044
Annotation	Unknow
Peak:m/z	Relative Intensity
175.9740906	0.10
180.8878632	0.02
184.0711670	0.01
186.9466400	0.07
187.9256592	0.02
191.2324524	0.02
193.0332642	14.23
195.0430756	0.46
199.2994995	0.04
204.4646301	0.01
207.7841949	0.02
209.0105286	0.01
212.9663391	0.45
215.0303955	1.31
216.0018005	0.02
216.9407806	0.10
233.0190430	2.00
241.0791168	0.10
255.2691650	0.11
259.1397095	0.25
267.9504395	0.04
269.0178223	0.03
273.1676636	0.09
284.1798096	0.02
286.1322937	0.34
287.0997314	0.04
291.2345581	1.92
302.1844482	0.01
304.1932678	2.04
305.0662231	0.28
309.2050171	0.23
322.0704346	100.00
329.0701599	0.08
332.9718018	0.01
357.0988770	0.02
365.1658325	0.02
366.3377075	0.05
367.2345581	0.07
376.2678223	0.03
383.3535767	0.01
387.1238403	0.03
400.4506836	0.04
403.3899536	0.01
404.9040527	0.07
411.0588379	0.11
424.1859741	0.03
448.1212769	0.03
467.0267944	0.01
468.5179443	0.07
483.0836182	0.38
483.8815308	0.03
498.4619751	0.10
501.0107422	1.71
501.6680908	0.06
504.2602539	0.03
510.0936890	0.01
520.0195923	0.03
531.2503052	0.06
541.4052734	0.11
549.4142456	0.02
551.3868408	0.02
567.4296875	0.09
585.3467407	0.03
593.4667358	0.07
594.1483154	0.08
595.0836792	0.01
597.1256714	0.02
600.4187622	0.02
612.1080322	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3146
Annotation	Unknow
Peak:m/z	Relative Intensity
242.0688477	0.11
277.1931152	1.61
431.3175659	0.06
457.3996582	0.07
476.5294800	0.02
502.2507324	100.00
503.2515259	0.38
515.1591187	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9387436	4.85
130.9691467	0.35
158.8824768	100.00
198.9816589	2.04
200.9613342	0.05
217.0259705	0.57
225.8343811	0.03
228.8878479	25.03
244.9910583	0.38
255.0335083	0.09
255.9826660	0.03
270.0193481	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.3516
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1748657	0.02
240.9014587	0.08
250.4083862	0.01
304.1512146	0.03
305.1467896	0.02
307.1755676	0.04
311.2245483	0.04
320.6428833	0.02
322.1599731	0.05
323.4041748	0.03
327.4190674	0.03
351.0158691	0.02
377.3175049	0.02
387.1231689	0.02
391.2153320	0.01
392.4773560	0.02
400.3915405	0.02
403.0236206	0.01
419.6116943	0.06
427.1002197	0.01
431.1486816	0.02
443.0654907	0.03
444.3847656	0.04
465.5313110	0.07
480.8585205	0.06
487.3634644	0.04
488.3579712	0.02
503.1110840	0.04
505.5361328	0.04
511.0100098	0.02
513.4683228	0.04
523.2096558	0.05
525.0274048	0.04
534.4569702	0.02
537.2867432	0.04
538.5376587	0.04
549.5017700	0.08
550.9461060	0.04
553.3865967	0.09
555.1749878	0.02
557.4840698	0.01
563.3692627	0.03
567.3289185	100.00
568.3064575	16.09
569.1843262	0.01
581.0272217	0.03
582.9710083	0.06
584.1358643	0.04
593.3851318	0.03
597.3646851	0.11
598.2145386	0.09
609.2527466	0.06
612.6312866	0.09
617.1058960	0.09
624.1661987	0.07
625.2886353	0.04
629.6429443	0.03
638.3193359	0.08
666.0628052	0.02
667.3238525	0.02
669.3703003	0.09
670.4013062	0.04
672.9891968	0.05
683.3267212	0.09
685.2101440	0.36
687.4803467	0.04
691.9631348	0.04
693.4917603	0.01
696.7443848	0.07
699.2633667	0.26
700.5194092	0.02
706.2901001	0.11
710.3330688	0.60
711.3485107	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
169.0197754	0.01
179.386261	0.01
205.9561462	0.06
251.1578674	0.18
268.0341492	0.02
269.1339417	0.43
281.1853638	0.08
283.0718384	0.80
293.1134949	0.15
295.019165	0.08
297.2867432	0.05
299.3999634	0.07
307.4186401	0.03
309.1633911	0.04
311.0532837	100.00
312.0442505	1.77
321.0358582	0.19
323.0988159	1.48
325.1106873	0.28
327.3826294	0.02
333.187561	0.08
335.1982422	0.02
337.1169434	0.09
339.1500854	0.01
341.0861816	24.24
342.1074829	0.18
349.1464539	0.17
351.2421875	0.15
353.1781006	1.77
354.315918	0.14
355.2175293	0.53
365.18927	0.31
367.0791321	0.25
368.4565125	0.05
371.0957642	0.65
377.1628113	0.47
378.2967529	0.19
383.1099548	1.19
384.9174805	0.02
387.1062317	0.07
395.0735779	0.35
413.0764465	2.00
413.9418335	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1
Annotation	Vitexin
Peak:m/z	Relative Intensity
124.5288696	0.06
150.9479218	0.04
161.0256042	0.03
164.4342041	0.09
189.2519226	0.07
193.1414185	0.15
205.0443878	0.11
207.2583313	0.06
207.9215393	0.06
213.9916534	0.02
227.1349335	0.52
233.0800934	0.03
246.0123291	0.04
249.0646667	0.87
251.1737671	0.23
266.9294739	0.06
269.1699524	1.60
270.3991394	0.02
276.1416626	0.05
279.0866699	0.03
283.1736755	0.34
285.1585999	0.21
286.2602234	0.02
287.1412964	0.14
293.2926025	0.05
297.1998291	0.15
298.22995	0.03
302.2154846	0.02
311.046875	100.00
312.1114807	0.32
313.0274658	0.09
315.342926	0.10
316.9534302	0.05
322.1030273	0.05
323.1112976	0.64
324.9854126	0.07
326.0749207	0.34
327.4007874	0.12
328.1234741	0.26
329.0205078	0.03
333.1893311	0.04
336.9605408	0.22
338.0418701	0.06
339.1773376	0.15
341.1873169	16.08
342.1925964	0.07
344.98349	0.06
349.2879639	0.04
351.3343201	0.17
353.2462769	0.65
355.1384277	0.40
356.0354614	0.05
365.04953	0.11
369.1060791	0.39
370.2154541	1.16
371.1188965	7.05
371.8157654	0.11
382.1754456	0.26
383.2468567	0.56
384.2941284	0.18
385.2304382	1.02
386.3516846	0.18
387.2051392	0.28
388.1498108	0.27
389.1670837	0.29
392.9585876	0.05
394.1596375	0.27
395.0440979	0.97
400.0992126	0.93
401.2608948	0.40
403.1116638	0.08
412.2603149	1.14
413.2519836	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	262.0569
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
78.0937729	0.62
93.9660034	0.19
95.9646454	20.46
97.9310913	0.83
98.8396149	0.14
100.9713898	0.40
110.0225067	0.11
111.0107422	0.41
112.0602264	0.13
113.3057404	0.14
114.9955750	0.29
115.8991241	0.44
117.0622864	0.74
118.9628143	0.47
123.9079590	0.29
126.1310272	0.67
127.9691010	8.46
128.9719543	0.60
131.9297791	0.24
134.0641785	0.06
137.9720917	4.68
138.9473267	0.33
139.9891968	1.50
141.9045563	82.82
143.9970245	0.23
146.1837006	0.23
147.0176697	0.49
155.9980316	3.42
157.9426117	94.09
159.0312958	0.72
170.0529022	0.73
172.0090637	6.52
174.0651855	1.38
181.9473724	0.79
183.0301819	1.05
183.6673584	0.08
187.8577118	1.73
197.9552765	0.17
199.9816742	11.40
201.9185791	100.00
214.1384277	1.55
217.9938812	21.58
218.9400177	4.58
226.0550079	0.80
231.9959259	0.09
243.9662476	10.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	197.05
Annotation	Ethyl gallate
Peak:m/z	Relative Intensity
58.9676437	0.22
68.7266083	0.06
80.9198456	0.34
82.9909821	0.34
92.9716797	0.44
94.9943543	0.33
96.9889679	0.05
109.1097717	0.88
111.0009155	4.29
113.0182495	1.30
122.9727631	0.64
124.8996735	100.00
126.9742432	0.04
130.9086456	0.06
134.9860840	0.53
136.8860931	3.91
138.7655487	0.93
148.9060974	0.03
151.0446930	0.13
153.0104828	2.38
154.9658051	0.84
160.9134979	0.03
166.9242401	1.67
178.9553833	4.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.0702
Annotation	Deethylatrazine
Peak:m/z	Relative Intensity
117.9747620	0.30
134.1192169	0.01
141.9498291	0.67
143.9303131	11.36
145.9464569	100.00
146.8992920	0.08
159.9997559	0.51
169.9032745	3.43
188.0688629	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1027.5095
Annotation	Pisumsaponin I
Peak:m/z	Relative Intensity
430.4099731	0.23
583.4867554	0.37
639.3082275	0.32
657.9057617	0.19
749.1607666	0.11
750.3195190	0.17
846.4908447	0.21
847.2569580	0.21
921.6741943	0.42
939.6489258	0.47
941.0655518	0.41
941.7922363	0.17
965.5108643	2.41
966.3059082	0.08
979.3726807	0.47
981.3568115	0.18
983.5261230	100.00
991.1191406	0.27
995.7141113	0.06
1009.0971680	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.2546
Annotation	Pterodontoside E
Peak:m/z	Relative Intensity
142.8178558	0.03
150.9198151	0.05
152.9509583	0.02
161.0341492	0.28
166.8505859	0.04
171.1822815	0.09
183.1166077	0.18
189.4100037	0.04
207.0471344	0.07
211.4254761	0.03
235.4444580	0.02
242.9461975	0.17
255.4050293	0.38
268.1028748	0.16
283.2715759	0.93
283.9703979	0.02
297.1474304	0.05
299.4006653	0.06
301.0789185	4.11
302.2992859	0.50
303.3628540	0.02
306.8737183	0.07
310.7634277	0.10
312.3082275	0.03
315.1112976	0.07
319.4101562	0.02
325.4223633	0.03
339.3910522	0.17
342.1419373	0.02
343.1528931	0.98
359.3770142	0.04
373.1585999	0.20
379.4955750	0.03
387.4640503	0.08
389.3109131	0.03
391.3327332	0.03
392.0627136	0.03
397.3022156	0.04
399.2070312	0.08
401.3146057	0.03
403.2822266	0.10
417.2145691	100.00
417.8619080	0.37
419.2854919	0.49
427.1913452	0.22
434.2976990	0.08
445.2943420	2.58
446.2028198	0.37
448.0509338	0.11
450.8839111	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	334.2947
Annotation	Unknow
Peak:m/z	Relative Intensity
98.9388580	0.03
101.8105927	0.05
108.8510437	0.17
111.0123367	0.04
113.1200638	0.03
119.1974335	0.27
119.9929657	0.09
123.0946655	0.24
124.6227264	0.20
128.9899292	0.06
132.9075165	0.07
135.2198792	0.13
136.8149414	0.49
139.0221863	0.39
150.9730225	0.20
152.9775085	0.06
155.1149750	0.07
161.1433411	0.10
163.0069885	0.10
164.9765472	0.13
168.9335785	0.06
175.1679230	0.22
184.1776733	0.08
189.1857910	0.03
191.0117645	0.22
192.8759613	0.03
196.3688354	0.09
197.0937958	0.19
203.1358032	0.03
204.6586761	0.05
209.0197144	0.67
216.7930298	0.24
219.1501770	0.19
221.2503967	0.30
222.3987732	0.04
225.1198730	0.26
226.1245117	0.09
227.2952881	0.04
232.9460144	0.13
235.9853821	0.13
239.0922546	1.63
242.5772400	0.37
245.0422668	0.20
250.9915466	0.28
252.5180054	0.20
256.0736694	0.03
257.2791138	0.16
261.1268921	0.06
262.2278137	0.37
263.1860657	1.51
265.3144531	0.04
267.1243896	0.04
268.2206421	0.16
269.0832520	0.06
271.1156006	0.05
273.1455383	0.07
274.3194580	0.44
276.1428223	0.13
280.2750244	3.32
281.2463989	1.10
282.4750366	0.04
285.2045593	0.06
288.1719360	0.15
291.1789551	0.18
292.5927124	0.02
295.0016479	0.12
298.2200012	15.68
299.0677795	0.26
305.4561157	0.13
306.1484375	0.27
310.7901306	0.03
311.4905701	0.15
314.5110168	0.04
316.2614746	100.00
317.0973206	0.50
343.1094971	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.303
Annotation	Unknow
Peak:m/z	Relative Intensity
168.8226318	0.03
173.1802979	0.08
177.9997253	0.04
179.2760315	0.23
182.2955627	0.09
183.8681030	0.08
184.8435669	7.62
187.2765503	0.23
197.1590576	0.05
197.9620209	0.04
201.0085297	0.10
202.9465485	1.66
208.7807312	0.19
212.2232208	0.12
225.2554779	0.03
243.9996033	5.76
246.3582764	0.19
260.0828857	0.15
261.9917603	100.00
262.7638550	0.04
289.0876465	0.11
299.9251099	0.19
311.0291748	0.35
314.2182617	0.06
317.9695435	0.19
329.5593262	0.06
331.1134033	0.09
335.1397705	0.03
337.3674927	2.49
338.3356323	2.13
355.6054077	0.04
356.5847168	0.05
365.2144165	0.07
401.4317017	0.03
417.3289185	0.27
418.3187866	0.03
425.3671265	0.05
450.2606812	0.04
455.2818604	0.05
455.9756470	0.28
456.5805664	0.05
459.2664185	0.25
468.2924805	0.25
478.3913574	0.38
486.3062744	0.14
490.4714355	0.14
496.1915894	0.05
509.0187378	0.12
526.4244995	0.16
529.8930664	0.05
533.7429199	0.25
536.1646729	0.05
539.4216919	0.16
541.3109741	0.09
549.2389526	0.20
552.2639771	0.05
556.3820801	0.07
557.5654907	0.15
562.3146362	0.70
569.4708252	0.12
570.3008423	0.16
573.5191040	0.31
575.0740967	0.06
579.0116577	0.53
579.6882935	0.74
580.3129272	2.50
581.4737549	0.06
597.2765503	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1647
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
267.7120667	0.09
269.1020508	0.02
271.1212158	0.85
277.3919067	0.06
280.8641968	0.06
283.0805359	0.44
287.1684570	0.12
295.2705078	0.33
299.1452637	0.04
300.1680298	0.07
311.0733643	0.13
313.0729980	10.04
313.7211304	0.13
314.3536987	0.06
320.9622803	0.05
327.1097412	0.01
328.3715210	0.02
329.2255249	0.06
337.0918579	4.19
338.3891602	0.02
346.2971191	0.07
348.6611938	0.05
349.2615967	0.13
355.2361450	0.08
357.1674194	0.07
361.0462646	0.05
367.0811768	6.61
368.0582275	0.03
379.2007446	2.30
387.2600708	0.07
390.3807983	0.03
397.1850586	3.07
408.8188477	0.07
415.0906372	26.99
416.3016357	0.03
417.1165161	0.11
431.1495972	0.34
433.0562134	100.00
433.6828613	0.38
439.0632935	0.11
443.1549683	0.02
445.1879883	0.02
449.1841431	4.31
450.9489746	0.03
457.0733032	0.76
463.0889893	0.22
465.3628540	0.05
475.1451416	4.37
480.4591675	0.03
481.2435303	0.02
490.0755005	0.03
491.2692871	0.10
498.9612427	3.19
499.6235352	0.02
501.8775024	0.09
503.9472046	0.01
504.9833984	0.10
511.0260620	0.29
513.1813965	0.08
523.2009277	0.13
529.0824585	4.42
530.3820190	0.04
541.1383667	1.72
550.1561279	0.06
551.5778809	0.02
554.0546875	0.13
558.4266968	0.42
559.1551514	3.08
561.9081421	0.02
567.1306763	0.04
577.0535278	32.18
577.7606201	0.09
595.4701538	0.02
597.0260620	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1067.5061
Annotation	Unknow
Peak:m/z	Relative Intensity
307.1302795	2.47
308.4009399	0.05
325.1733398	2.52
326.2326660	0.10
330.6942139	0.05
333.1183472	0.10
367.1504517	0.34
368.3311157	0.14
383.2532654	0.06
391.3233337	0.21
393.1791382	0.92
394.1523132	0.04
395.2086487	0.10
403.1639404	0.14
406.9836121	0.55
409.0312805	0.55
421.2713318	3.64
422.2000732	0.52
437.0963135	0.14
439.1151733	0.64
440.4943848	0.17
442.4880066	0.03
465.0141602	1.92
466.2743835	0.33
483.0958557	100.00
484.2192383	13.42
485.3883972	0.15
501.1236877	0.11
528.1813354	0.45
545.5249634	0.26
546.2954712	0.36
547.4050293	0.30
592.3936157	0.05
624.5766602	0.13
631.2449951	0.06
651.8155518	0.13
652.8494873	0.07
659.2866211	0.10
678.8975220	0.80
721.5174561	0.05
724.2735596	0.19
739.7608643	0.11
741.5776978	0.05
742.3737793	0.06
751.5360107	0.11
755.7630005	0.10
759.4841309	9.47
760.5059814	3.24
786.2402344	0.13
809.0944824	0.18
810.1871338	1.87
811.2225342	1.95
812.3040771	0.38
827.3773193	0.08
829.1279297	0.80
830.2365723	0.07
838.4885254	0.18
841.5539551	0.30
859.4649658	0.35
862.1159668	0.11
878.1650391	0.17
878.9592285	0.14
886.2464600	0.18
892.5697021	0.17
899.5761719	0.12
904.5666504	0.19
917.3629150	2.86
918.5017090	0.61
919.2139893	0.14
933.7023926	0.10
934.7226562	0.24
935.4226074	0.14
941.4420166	0.16
949.3592529	0.22
961.3410645	0.69
962.3886719	0.10
967.4898682	3.95
968.4173584	2.01
987.8127441	0.10
988.5476074	0.12
992.4927979	0.12
1005.5185550	1.04
1006.4974370	0.77
1021.9478760	0.20
1023.4202880	0.46
1024.5723880	0.81
1025.4401860	0.29
1026.8283690	0.46
1031.3701170	0.18
1032.3024900	0.17
1049.4310300	12.47
1050.5029300	7.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.27
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9833527	0.02
192.8453217	0.04
197.1098938	0.04
205.1024780	0.12
225.1799316	0.04
232.8845673	0.10
234.7893372	0.49
235.5889587	0.13
243.1882324	0.02
247.2088318	0.09
255.1688843	0.07
264.9380493	0.34
265.7138367	0.07
270.0606689	0.03
271.1379395	0.09
277.0094299	0.01
292.9036865	0.13
297.1471863	0.13
300.3973389	0.04
306.9746704	0.24
307.8098145	0.04
311.7758179	0.03
313.2258301	0.05
315.9631958	0.02
324.7033081	0.42
325.8471069	1.21
327.0966797	1.16
336.0097046	0.10
342.8756714	0.02
345.3534546	0.05
357.2293091	0.09
358.1485596	0.08
366.9147949	0.05
374.2703857	0.06
375.0490723	0.63
375.9434814	0.08
387.0087280	0.52
398.8460693	0.07
401.1625366	0.08
405.5117798	0.12
408.2649536	0.19
411.1250610	0.13
412.2653809	0.07
413.1187744	0.05
414.9038086	0.15
417.2260132	0.08
424.9602661	0.12
426.3501587	0.04
427.3059692	0.02
431.0581665	0.04
435.1621094	0.04
442.4149780	0.04
452.3394775	0.08
456.3302612	0.05
457.7593994	0.03
459.2151489	0.77
479.0017090	0.04
488.0348511	0.03
489.1799927	0.31
498.5841675	0.30
510.8947754	0.08
514.4851685	0.09
515.3449707	0.22
516.2881470	0.19
518.6859741	0.34
519.4746094	0.21
521.3332520	0.04
531.4670410	2.38
532.4221802	26.31
533.2107544	100.00
533.8550415	0.18
535.3181763	0.08
536.0257568	0.24
537.3405151	0.03
542.1738892	0.07
543.0496216	0.04
549.0701904	0.21
559.4705811	0.11
560.3949585	0.14
561.2827759	0.26
561.9462891	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.2697
Annotation	Unknow
Peak:m/z	Relative Intensity
160.1172180	0.27
169.9222717	1.84
183.1871033	0.16
185.1284332	1.01
187.9885101	57.76
201.1894531	0.12
205.0556030	100.00
206.2775269	0.09
210.0804138	0.21
220.8021240	0.16
227.1512146	0.32
228.0980377	0.19
236.9301910	0.15
251.0641937	0.08
265.0605469	0.04
300.1112976	0.07
303.3013916	0.19
304.8728027	0.17
320.5202637	0.12
322.1539307	0.12
322.9873657	0.10
324.8854980	0.30
341.2207642	0.11
366.8280640	0.10
372.1810913	0.12
387.1506348	0.21
390.3582764	0.24
405.3076172	0.21
406.4611816	0.36
407.0729370	0.67
415.2814941	0.07
418.3018799	0.21
418.9489746	0.07
420.5226440	0.15
422.2667847	0.26
437.1242676	0.09
439.1200562	0.94
440.1188354	0.23
462.7004395	0.13
463.3679810	0.09
491.6909180	0.43
494.9738159	0.16
499.6970215	0.72
507.2078247	0.24
514.9115601	0.04
521.2681274	0.21
523.0845337	0.19
524.6471558	0.15
533.1817017	0.14
540.0951538	0.66
550.2201538	0.15
551.2018433	1.17
552.0418091	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	875.2021
Annotation	Unknow
Peak:m/z	Relative Intensity
253.2240753	0.05
267.0565491	0.18
279.2789001	0.31
281.1798096	0.17
283.0856323	1.46
293.0436707	0.11
293.9999390	0.37
295.0791321	3.23
306.1839294	0.23
309.3766479	0.09
311.1422424	3.54
322.9704590	14.40
324.1791382	0.12
337.3909302	0.16
341.3417358	0.12
352.9869385	0.33
361.4821777	0.07
365.0015259	0.12
368.9605103	0.08
375.0172729	0.13
425.1987305	0.14
428.2281494	0.14
431.1223145	4.06
432.3069458	0.13
443.1872559	100.00
462.3625488	0.08
494.0637207	0.14
548.2224731	0.08
556.3707275	0.22
592.1011353	0.66
593.4129028	0.75
594.1101685	0.07
602.9295654	0.22
605.0859985	0.07
610.2029419	0.05
627.4358521	1.42
638.9741821	0.29
640.7589722	0.10
669.1245728	0.16
681.1502075	0.13
682.5722046	0.12
694.3848877	0.11
712.3172607	0.52
713.0934448	0.17
716.3983154	0.24
733.2803955	0.14
741.0368652	0.09
752.1007690	0.09
755.2033081	4.76
756.3399048	0.29
780.4429321	0.08
782.8268433	0.38
783.8099365	0.08
785.0890503	1.01
790.2576294	0.28
795.4105835	0.42
799.1366577	0.09
802.5651245	0.23
803.6279907	0.21
814.2850952	0.16
830.8127441	0.58
831.4350586	1.39
835.9769897	0.22
838.2369995	0.75
839.7115479	0.09
856.6246338	0.46
857.3435669	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
148.9960327	0.02
153.1462097	0.01
165.1790314	0.01
179.0141602	0.01
190.9266968	0.01
215.0526886	0.01
247.3406067	0.02
248.0352783	0.02
267.2911377	0.04
269.0083313	0.29
270.1143799	0.12
276.2248535	0.02
281.2642212	0.07
282.2791138	0.03
283.1388855	0.39
284.1156616	0.15
293.1402893	0.09
297.0331421	0.02
299.2039795	0.03
309.1953735	0.11
311.0509033	100.00
312.0616455	40.19
312.6828308	0.14
313.6460266	0.01
321.3500366	0.01
322.2276001	0.04
323.1824951	0.30
324.1186523	0.07
325.3032227	0.02
326.0942078	0.01
328.7928162	0.02
329.8291016	0.01
335.3593445	0.01
336.3157349	0.01
337.1650391	0.02
338.0549927	0.05
341.079895	12.63
342.1751709	5.74
343.2108459	0.03
350.9670105	0.02
353.1164856	0.65
354.1749878	0.27
355.0828857	0.24
356.1679993	0.07
365.3012085	0.04
366.1212463	0.02
367.1534119	0.08
368.2503967	0.02
369.3916626	0.02
371.142395	0.30
372.1261902	0.11
377.0617981	0.25
378.2036743	0.13
383.0854797	0.28
384.1455688	0.20
385.219574	0.04
387.0070496	0.05
390.2694397	0.01
395.1243286	0.26
396.0696716	0.02
402.2501831	0.03
413.1202393	1.93
414.2120667	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	834.55
Annotation	Aurilide B
Peak:m/z	Relative Intensity
252.5919189	0.06
267.8151855	0.09
278.9407654	0.17
281.0368347	0.18
301.2425537	0.18
302.5659790	0.06
319.1903076	0.14
320.3975830	0.06
331.1828003	0.05
334.2463379	0.18
337.2992554	6.71
338.3479919	3.54
339.3645630	1.29
355.1793823	0.43
379.3045654	0.21
403.3251343	0.39
405.2604370	0.07
406.1375122	0.11
416.3140259	0.49
417.7805176	0.67
419.2137451	9.29
420.3270264	12.79
421.3377075	4.67
437.1666870	0.86
438.2774048	1.46
439.4476929	0.77
442.0707397	0.05
450.0300293	0.49
451.1637573	0.09
453.7909546	0.07
478.3109741	0.40
479.4880371	1.44
480.4550781	0.31
491.3903198	0.20
496.3961792	68.36
497.3840942	100.00
498.3614502	26.46
502.4134521	0.41
503.2958374	0.46
506.2735596	0.11
517.6337280	0.08
522.3282471	0.06
541.3884277	0.10
546.0875854	0.14
600.1328735	0.15
619.4207153	0.08
622.0322266	0.28
627.6379395	0.12
630.4713745	0.14
635.5645142	0.08
639.1825562	0.10
646.5734253	0.15
668.4581909	0.07
677.8180542	0.11
679.4979858	0.25
680.2535400	0.12
692.3864746	0.07
693.6793823	0.21
695.6726685	0.10
697.6600342	0.18
703.6427612	0.06
718.5856934	0.36
732.3883057	0.20
756.1259766	0.17
766.6268921	0.03
770.1843872	0.10
773.1244507	0.08
773.8753662	0.08
775.6690063	0.35
777.5891113	0.13
781.3626709	0.47
784.5490723	0.08
787.6387329	0.22
788.6837769	0.08
789.6079102	0.19
790.5469360	0.09
798.9113770	0.51
799.7846069	0.31
800.5140991	0.55
815.6325684	1.83
816.5139160	1.13
817.3224487	0.33
833.7571411	4.77
834.7615356	2.21
835.6851196	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1072.2054
Annotation	Unknow
Peak:m/z	Relative Intensity
452.3006592	0.02
556.0880127	0.02
598.0464478	1.12
599.2235107	0.19
624.1793213	0.02
642.2927246	0.04
655.9749756	0.03
657.0206299	0.03
658.1810303	0.90
659.1976318	0.02
684.3227539	0.07
700.2810669	0.04
702.2957764	0.03
718.0929565	3.00
719.1508179	0.02
720.2548828	0.02
742.8531494	0.02
760.5115356	0.05
790.0627441	1.98
790.8562012	0.04
819.6777344	0.39
820.2808838	0.79
821.2028809	0.05
827.3863525	0.05
831.9514160	0.08
834.2337646	0.01
837.9514160	0.10
850.0845947	2.31
864.2521973	0.08
878.5029297	0.70
879.5594482	7.89
880.1630859	100.00
881.2464600	1.00
882.2244873	0.29
892.1040039	0.10
910.0693359	0.59
976.4343262	0.03
983.9562988	0.27
1028.0704350	1.38
1054.2412110	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9864349	0.37
86.9559174	0.92
100.9782257	0.06
110.9344940	100.00
111.6893158	0.10
118.9021454	0.03
128.8964996	1.57
130.8556671	0.92
147.0133514	0.30
154.8250580	0.08
172.9697418	21.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3079
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
138.8633728	0.05
155.0251160	0.12
173.2201080	0.12
197.9561768	0.21
199.3627014	0.11
203.0405731	0.04
215.7712555	0.17
222.8978577	0.22
247.3700562	0.22
250.4581299	0.09
262.7602539	0.11
264.4319763	0.04
265.4419861	1.08
308.3753662	1.94
325.1307983	0.22
335.2822876	0.12
337.2107849	0.10
339.3206177	68.94
346.1513672	0.10
363.2537842	0.23
382.3264465	0.19
387.1408997	0.27
387.8042297	0.03
397.1857300	0.09
406.8465271	0.09
419.2102356	8.17
420.4385681	0.04
429.2463379	0.06
431.0466309	0.05
433.1541443	0.25
434.2649536	0.04
437.0413818	0.68
439.9267273	0.06
448.6712952	0.23
462.1586609	100.00
462.8438110	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.31
Annotation	BQ 123
Peak:m/z	Relative Intensity
172.8945007	1.35
179.1210480	0.29
182.1637421	0.08
187.9809570	41.52
189.0481720	7.64
189.9866180	3.95
191.1679993	2.83
197.2460632	0.06
204.9491425	100.00
205.9980469	16.72
207.0805969	6.29
208.1538391	0.82
209.0871887	10.24
210.5789490	0.32
224.9541626	0.24
227.0128784	18.72
243.6820374	0.05
244.7236938	0.11
301.1130371	0.14
303.1489258	0.06
353.1318359	0.36
355.7240601	0.05
358.5739746	0.40
366.4462891	0.55
368.8916016	0.29
369.7040405	0.26
370.8367310	2.74
387.3690796	0.23
388.6124878	3.42
389.2608032	2.05
390.1998901	0.24
395.4248047	0.22
406.7767334	4.11
407.5069580	0.04
412.9480591	0.13
422.1973877	0.24
427.0911255	0.16
435.0588989	0.14
449.1159058	0.28
454.8333740	0.13
464.3135986	0.05
465.2711792	0.84
479.2360840	0.28
481.1944580	0.28
482.0971680	0.14
491.1067505	0.36
508.6299438	0.24
521.0678101	0.08
522.4062500	0.47
532.4747925	0.42
537.0773926	0.15
548.3245239	0.35
551.6425171	0.41
558.2788696	0.46
570.2089233	0.21
572.1383057	0.17
575.0324097	0.29
592.0636597	0.33
592.7256470	0.45
593.3367310	3.30
594.1648560	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.31
Annotation	Dendronobiloside A
Peak:m/z	Relative Intensity
161.0293732	1.15
178.9336395	0.23
183.2844849	0.24
186.6694794	0.18
211.2605438	0.23
225.0027161	0.06
241.3796082	0.09
247.1882935	0.18
253.0838013	100.00
255.9235840	0.19
259.3001099	0.10
267.1121216	0.26
269.4496765	0.09
284.8568115	0.11
287.3771973	0.06
291.3699646	0.40
305.5148621	0.10
306.9085083	0.18
309.1154175	2.13
327.2036743	69.64
329.2147217	0.36
339.1880493	0.24
343.2309570	0.20
344.1998901	0.32
345.6445923	0.19
347.2299194	0.15
350.3543091	0.84
351.3564453	0.20
363.2020264	0.23
365.2648315	1.92
381.2921143	0.14
387.1431274	0.43
400.9375000	0.63
402.2280273	0.13
403.1466064	0.46
426.1866455	0.08
434.5117798	0.41
441.9793701	0.20
443.2947998	0.08
447.7604980	0.10
457.2155762	0.10
459.2325439	0.06
467.1732788	0.35
471.6176758	0.08
473.4623413	0.22
480.2643433	0.30
484.0689697	0.11
491.3298950	0.15
499.5979614	0.25
501.5737305	0.14
503.0249634	0.28
503.6254272	0.53
505.3060913	0.07
517.1876831	3.12
519.0976562	0.38
521.4942017	0.37
523.7266846	0.08
527.2151489	0.92
530.9442139	0.06
533.4184570	0.71
542.9193726	0.17
545.0440063	0.36
545.6582642	0.10
550.5399170	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutine
Peak:m/z	Relative Intensity
237.9418793	0.41
239.0247803	0.46
244.0650635	0.17
253.1600342	0.52
256.9486694	0.22
285.3465881	0.29
287.2644043	0.31
303.0566711	100.00
303.6958923	0.30
309.0510254	0.84
317.0905151	1.65
326.4275513	0.68
329.1245728	1.57
345.2191772	0.21
350.9884033	0.76
355.1928101	0.89
358.3434448	0.54
360.9852905	1.02
383.5722656	0.56
385.9518433	0.30
404.2971191	0.29
406.1898804	0.43
413.2381592	0.51
423.3129272	0.67
424.4321289	0.78
431.1038818	1.28
432.173645	1.14
447.2003784	0.99
448.4467163	2.40
449.1553955	4.10
456.0578003	0.51
460.4047852	0.60
464.9580688	25.51
469.2174072	0.15
477.6091309	1.42
480.3579712	0.46
489.0462036	0.29
491.1141968	3.07
497.1044312	0.35
509.8791504	0.22
520.4552612	1.00
525.1984253	0.22
539.1074829	0.47
544.4804077	0.47
545.1942749	0.40
547.2185669	0.21
551.3377686	0.20
552.774231	3.02
556.5525513	0.20
561.3065186	0.96
566.9850464	0.77
575.1064453	0.61
583.3256226	0.95
592.5077515	3.77
593.1490479	5.76
593.9470825	2.81
601.6520996	0.43
602.2678833	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2765
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
141.9921112	0.12
147.1358337	0.20
149.0137329	0.23
151.1239166	0.11
154.8319702	0.39
159.1469727	0.05
163.1449432	0.20
173.1490173	0.25
175.1900177	0.46
184.9633179	0.04
187.2138062	0.03
193.0096436	0.20
197.9585876	0.22
201.1745605	0.25
211.0323639	0.28
216.0758667	0.39
219.3741455	0.14
221.1646729	0.04
225.2678223	0.08
233.2063141	0.03
241.2116241	0.45
243.1405640	2.18
251.0676575	0.27
253.0445862	0.04
261.2572021	4.28
277.2487488	0.19
293.2420654	0.16
304.2841797	2.10
306.9671326	0.09
317.3294067	0.89
319.0928345	0.05
322.3383484	0.17
331.1145020	0.31
335.2354126	77.87
335.9219971	0.05
344.9390564	0.15
349.3922729	0.09
359.2479858	0.14
378.1492920	0.33
415.2319641	9.10
433.1883545	1.95
440.0627747	0.21
458.1856995	100.00
458.8382263	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1033
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.9355469	0.62
87.8970337	100.00
125.8859711	0.09
130.1609650	0.08
131.8509827	0.10
146.0455170	11.07
149.8474579	0.06
158.8281097	0.04
169.8942871	0.28
173.8908997	0.29
190.0533600	0.31
191.0430756	0.12
191.8050537	0.16
199.2170868	0.04
200.2165985	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.3171
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0951996	0.11
170.9140778	0.20
172.0442352	0.24
201.2437744	0.18
202.8822327	0.09
209.1952057	0.11
213.7271729	0.21
219.2030029	0.08
221.3648682	0.03
239.2393646	0.09
274.2545776	0.05
282.0525513	0.88
289.2991333	0.06
303.1231079	0.04
308.0515137	0.12
309.2098389	0.46
310.2873535	0.43
311.0733032	0.09
320.7233276	0.12
323.4630127	0.17
325.3222656	0.12
327.5355225	0.92
328.3207397	0.32
335.4254150	1.57
345.7678833	0.09
347.1690063	0.30
351.2528076	0.19
353.6627197	0.07
356.0001831	0.08
362.9796143	0.06
363.6150513	0.12
365.2663574	0.07
368.2495117	2.04
369.3442383	0.16
378.1685791	0.20
383.2727051	1.73
388.8801270	0.07
393.4237061	0.29
401.3082886	6.61
407.1002197	0.05
413.0928345	0.34
423.2272339	0.63
435.1023560	0.14
447.2358398	0.64
447.8666992	0.43
449.2097168	0.06
454.0478516	0.42
455.1356201	0.11
459.1584473	0.29
465.3156738	0.88
467.3037109	0.21
468.7337646	0.13
471.3358765	0.17
477.2348022	0.16
483.2106323	100.00
483.8414917	0.30
485.2074585	0.15
497.0682373	0.56
499.4455566	0.54
501.3833008	4.19
505.2438354	0.09
507.3921509	0.48
513.5296631	0.09
523.6101685	0.70
524.3815308	3.34
525.3618164	1.34
526.1409302	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2081
Annotation	Unknow
Peak:m/z	Relative Intensity
185.2022705	0.07
187.3032227	0.28
194.8150177	0.17
204.9848633	0.32
213.0221558	0.26
231.0686340	2.50
245.3732910	0.08
247.1536865	0.17
257.2213745	0.08
264.9523621	0.08
273.1894531	0.14
279.0314941	0.07
285.2817383	0.35
286.8854370	0.07
299.1071167	0.11
307.0751343	1.71
310.9882202	0.21
315.2107239	0.15
329.2075195	0.09
341.2246094	0.16
343.4879761	0.16
346.3106689	0.18
347.2846680	0.58
364.1575317	0.16
371.1692505	0.35
379.0823975	0.20
387.3483276	0.13
402.6300659	0.13
415.3288574	0.22
421.0452881	0.10
431.4452515	0.32
444.2858276	0.20
448.8972778	0.80
449.5226440	0.02
452.4007568	0.12
466.1059570	0.09
467.0628662	0.60
473.1947021	0.71
475.5299072	0.14
492.2828979	0.13
494.0164795	0.04
497.2224731	0.40
507.2365112	0.12
509.1349487	5.16
511.6061401	0.06
513.2767334	0.15
523.4727173	0.36
531.7686157	0.14
533.0878296	0.12
535.0979614	0.37
539.2752075	33.20
540.5670166	0.06
543.1734009	0.19
544.2884521	0.12
545.1276245	0.29
551.4871216	0.06
565.4251099	0.09
566.5532837	0.49
568.3948364	2.66
569.3483276	0.98
583.1361694	100.00
584.3675537	0.45
585.1315308	1.71
585.7891235	0.24
593.2421265	8.27
599.4944458	0.24
609.3767090	0.32
610.3258057	0.70
611.1697388	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.0472
Annotation	Unknow
Peak:m/z	Relative Intensity
172.0054779	0.35
179.1728363	0.33
191.0259552	3.87
191.8230743	0.21
197.8294525	1.06
199.8918457	32.11
200.8045044	0.26
201.8096313	0.24
213.7674103	0.62
217.0927582	0.05
229.1484833	1.19
231.9171143	0.52
241.0697632	0.13
243.8137665	2.80
250.0999451	0.32
257.9540100	0.10
260.1789856	0.22
261.9013672	1.01
273.6313477	0.89
285.9475708	3.76
288.3334351	0.89
290.1044922	1.20
300.0780029	0.31
301.9711304	0.77
303.8823853	100.00
306.1328735	0.89
315.9679565	5.28
316.7470703	0.11
319.9641724	0.20
322.2838745	0.24
333.9415283	11.21
337.2438965	0.06
345.7741089	0.28
352.0257568	0.28
362.0216064	0.45
362.6921387	0.15
364.0957642	0.85
377.9593506	1.44
378.7847900	0.44
379.7396240	0.18
387.2855835	0.49
387.9264526	0.48
392.0784912	0.29
393.3549805	0.74
394.1262817	1.09
395.3008423	7.03
396.0540771	54.84
401.2261353	0.25
406.0114746	35.85
412.1466675	4.79
421.7841187	0.55
423.9544678	47.06
424.5574341	0.43
431.6174316	0.44
435.2077637	0.25
448.8104858	0.43
452.0646973	85.49
452.8450317	0.27
454.0177002	1.38
466.0198364	1.30
478.1226196	0.28
478.8468628	0.12
480.4151611	1.53
482.0079346	64.94
483.1522217	0.26
486.8447266	0.28
489.2774658	3.11
495.1197510	0.81
496.1163330	6.35
497.9967041	24.66
505.9806519	0.75
524.2474976	0.81
525.7322998	0.68
527.1572876	0.27
534.3722534	1.09
539.9360962	0.75
540.7063599	0.19
542.0654907	17.81
543.0874634	0.34
550.3428955	0.72
567.9835815	46.11
568.5866089	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1191.3424
Annotation	Unknow
Peak:m/z	Relative Intensity
705.3120728	0.19
849.2211914	0.17
867.2667236	0.82
909.4536133	0.06
959.3217773	0.03
969.3751221	0.11
996.0520020	0.05
1011.3574220	1.64
1014.4287110	0.04
1029.2625730	100.00
1029.9377440	0.48
1105.4001460	0.04
1148.6230470	0.04
1191.0019530	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.2053
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
95.0080643	0.12
104.9660873	0.43
107.0809326	0.38
108.9943237	0.23
109.7424622	0.10
111.0649033	0.29
112.9721909	0.11
119.0851135	0.20
120.8640671	2.33
123.1270828	0.56
124.9388885	0.14
129.1127930	0.25
130.2873840	0.11
130.9988098	0.11
132.9718018	0.33
134.9452209	0.77
137.0655518	1.59
138.8977356	0.75
140.9042664	0.38
141.8412476	0.06
143.1072540	0.09
145.0319824	0.53
147.0127563	0.22
149.0832825	2.42
151.1263733	0.49
153.0691223	0.03
155.0207520	0.26
155.9073486	0.03
157.0134125	0.32
158.9621277	0.40
161.0824280	0.80
163.0123138	0.66
164.9454651	2.98
167.0692444	0.97
169.0648499	0.37
171.0066833	0.43
173.0607605	0.61
175.1640015	0.60
176.9907990	0.22
181.0227203	0.20
183.0046997	0.68
185.1292114	0.60
187.1193085	0.25
188.8768005	0.39
191.0750427	0.15
192.8745270	1.56
194.0029602	0.22
195.0841064	5.81
196.3580933	0.03
197.1625061	0.27
199.3662872	0.82
200.9851379	0.10
203.0488281	0.17
205.1194153	0.20
207.0278931	0.94
209.2154541	0.50
211.0043030	1.06
213.1062317	0.45
214.7491760	0.51
215.3644104	0.06
216.9828796	0.68
219.1284180	1.29
221.0105896	1.16
222.2146301	0.08
222.9643860	0.45
225.1042480	0.41
225.9303894	0.11
227.1861267	3.52
228.9886169	0.76
231.3940735	0.92
235.1540527	0.13
237.2825928	0.17
238.9979553	0.60
239.7075806	0.10
241.1717834	2.47
243.2087708	0.82
245.1271057	2.03
246.2041321	0.05
247.1533813	0.34
248.0881042	0.18
250.0738831	0.20
251.1769104	4.25
253.1446228	1.72
255.1768799	0.30
257.2316284	1.85
259.2308044	6.18
261.1715393	1.25
265.1873779	0.05
267.2261353	0.11
269.2175293	18.48
271.1394653	5.66
273.0626221	0.93
274.2321777	0.44
275.2269897	0.39
276.7359924	0.31
279.1322632	0.58
280.1536865	0.11
283.1911926	0.06
285.2554016	1.31
287.2153320	100.00
289.1588135	5.23
292.2400513	0.25
297.1181641	11.07
298.0809631	0.20
302.2416687	0.03
303.3348389	2.83
305.2154236	5.94
315.0825195	83.15
315.6901855	0.72
316.5196533	0.15
318.1629333	0.14
324.1981201	0.33
332.1776733	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2841
Annotation	Dehydrophytosphingosine
Peak:m/z	Relative Intensity
90.8454895	0.38
92.9251328	0.46
95.0362015	1.90
96.9474869	0.46
97.9766693	0.07
101.8473206	0.19
105.0669861	0.36
107.0061035	0.62
108.9453888	1.13
109.8533173	0.14
110.9704208	0.34
115.8071365	0.02
119.0472412	1.37
121.0086823	1.17
122.8562546	0.84
123.8464127	0.23
124.8804169	0.50
127.2618637	0.02
130.9237823	0.06
133.0462494	1.51
134.9087219	1.51
136.4087219	0.31
137.0631409	1.43
138.8074951	0.10
140.0133057	0.08
140.9781189	0.10
142.3023682	0.12
143.0981445	0.08
146.9658051	0.57
149.0645142	1.23
151.0430603	0.78
153.0605469	0.17
155.2445374	0.11
156.0962219	0.17
161.1154175	0.76
163.1359711	0.98
164.8547516	0.10
167.0180817	0.14
168.9819336	0.12
170.1057281	0.07
175.2131042	0.28
177.1405792	0.15
177.9385376	0.03
179.1223755	0.11
181.0552673	0.04
189.0677643	0.37
198.3461304	0.04
203.1943970	0.22
205.2539673	0.10
207.1363525	0.55
211.8866272	0.04
218.0660706	0.15
219.2436523	0.49
221.2302246	0.84
222.8556824	0.06
225.1375122	0.54
227.2253113	0.12
227.9451599	0.08
230.1901245	0.02
233.2162476	1.35
234.1392212	0.19
235.2448120	0.09
237.1625061	1.61
239.1238708	2.14
242.2608337	1.80
245.2334595	2.48
249.5295410	0.20
250.2588196	0.88
251.1997681	3.53
256.0209045	0.04
256.9059448	0.06
262.3343201	3.55
263.3463135	4.76
268.2523193	1.67
269.2622986	0.10
274.2027588	0.09
280.2546387	63.20
281.4622803	0.33
298.2349854	100.00
299.1708069	0.17
302.2514343	0.17
306.8414307	0.20
316.2299805	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.15
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
187.8409119	0.14
190.9630280	0.09
193.0579376	0.10
221.1397705	0.07
235.2618561	0.04
243.3724823	0.03
250.9946289	0.04
255.3856964	0.05
257.1685486	0.03
259.0480652	0.03
281.1454468	0.07
283.1371765	0.30
285.2651367	0.07
297.1523438	0.04
298.6262817	0.08
301.1377563	0.03
302.9888916	0.17
304.9320679	0.05
305.5853271	0.02
307.0719604	0.04
307.7757568	0.04
311.0305176	4.18
315.0674438	0.11
323.1217041	0.05
325.1481934	0.03
335.1676025	0.06
338.8722534	0.03
341.3118896	0.32
346.1059570	0.05
349.2818604	0.14
351.2957764	0.03
353.0937500	25.58
354.2651978	0.61
355.3026733	0.06
358.9699707	0.05
361.0823364	0.11
365.1937256	0.48
367.3209229	0.09
370.9784546	0.30
376.8206177	0.10
379.2013550	0.14
381.5549927	0.09
383.0769043	14.18
383.9537354	0.18
393.2943115	0.05
395.2063599	1.29
396.2677612	0.10
397.2108765	0.85
406.3461914	0.08
407.2502441	0.08
409.2579956	0.09
411.9244385	0.05
413.1448975	3.06
414.0971680	0.06
419.3567505	0.69
423.7104492	0.11
425.2473755	0.77
427.1976318	0.37
429.2621460	0.07
429.9607544	0.10
431.2109375	4.86
437.1856689	1.11
441.2390137	0.24
443.0814819	0.16
449.1614380	0.26
451.0731812	0.02
455.1980591	3.14
464.5098877	0.54
465.1699219	0.33
466.1191406	0.75
467.4501953	0.21
471.1268311	0.20
473.1510010	100.00
473.9836426	1.33
477.2897339	0.04
481.2911377	0.11
483.3983154	0.05
485.2290039	2.29
485.9610596	0.09
487.1073608	0.29
489.2257690	0.18
490.1713867	0.10
493.5825806	0.11
497.0591431	0.04
499.1506348	0.06
503.1316528	28.99
504.0938110	0.68
505.1243286	0.04
513.2832642	0.06
515.1873169	1.67
517.2356567	1.64
517.9021606	0.08
527.2075195	0.10
531.1447144	0.38
533.1048584	3.87
534.3631592	0.29
539.0755005	0.24
544.5637207	0.36
545.2335815	1.32
547.0468750	0.29
548.4951782	0.38
549.1554565	0.43
557.3436890	1.19
558.2929077	0.02
574.4174194	1.08
575.1604614	12.72
576.2158813	0.52
591.8154907	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.09
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
162.7989502	0.03
183.0421143	0.04
205.0595245	0.05
223.1417694	0.02
227.9515686	0.05
243.0618896	0.08
247.1463623	0.04
249.2280884	0.04
253.1389771	0.07
267.0647583	0.49
269.1181641	0.04
285.0444336	100.00
286.1955566	0.64
297.4632874	0.10
298.1322632	0.04
298.8760071	0.03
309.0704651	0.05
313.007843	0.30
313.9961853	0.13
319.2452087	0.03
320.329834	0.05
322.7623901	0.09
327.0389404	58.73
327.8427124	0.01
339.0668335	0.29
340.4094238	0.04
345.1971741	0.04
353.1599426	0.19
355.8258972	0.15
357.1488342	12.46
360.0644531	0.03
369.1569519	0.51
371.1952209	0.22
381.2053833	0.13
383.2588806	0.10
384.7670593	0.05
386.019989	0.03
387.1855774	0.58
393.1847534	0.46
399.1253052	0.35
401.1607361	0.26
402.1469116	0.03
403.1174927	0.08
411.1496887	0.50
417.1221008	0.25
419.1033325	0.08
420.1977234	0.02
429.1229553	3.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1611
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0071716	0.04
179.1659241	0.13
194.1016846	0.04
197.6942291	0.09
203.1144714	0.13
209.0692291	0.19
220.8339539	0.14
239.1962280	0.17
240.9729462	0.08
244.3063660	0.14
256.3919678	0.19
267.9429626	0.35
275.2041016	0.05
286.0822754	0.21
286.7413330	0.22
288.1294556	0.19
293.1787109	0.33
306.2066650	0.05
307.2602539	0.31
315.1203918	0.12
320.2156372	5.11
321.0338135	0.68
323.1483765	0.05
328.1518555	0.09
336.1390991	0.14
341.4047852	0.30
345.1976318	0.06
346.9282227	0.05
348.9970093	0.16
352.3755493	0.10
364.5781860	0.09
372.1938477	0.04
380.0214233	0.07
380.9454346	0.03
382.1304321	0.03
383.3610840	0.16
391.4089966	0.14
393.2875366	0.10
398.8427124	0.08
401.0578613	0.72
402.1228638	0.09
405.0759888	0.07
409.5778809	0.15
411.1218262	0.09
419.1239014	100.00
425.0150146	0.09
430.0802002	0.12
433.2896729	0.09
435.3644409	0.40
436.1384888	0.10
456.3869019	0.17
457.3372803	0.09
461.0975952	30.61
461.7573853	0.08
465.0132446	0.53
472.3762207	0.17
473.5746460	0.07
487.8203735	0.07
499.2461548	0.02
501.0608521	7.59
501.6710815	0.03
503.0996094	0.21
516.5253296	1.06
517.2219849	1.11
519.1991577	0.54
535.2817993	0.08
539.7587280	0.17
541.6486206	0.06
544.5814819	0.35
545.4183960	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.9991
Annotation	Unknow
Peak:m/z	Relative Intensity
94.8796387	0.11
97.0217743	0.07
98.9728241	0.04
109.1226959	0.25
109.7675629	0.18
124.9024963	0.13
135.0671234	0.29
141.0508728	0.11
144.0763702	0.04
155.9331360	0.15
159.1729889	0.05
162.8896637	0.08
170.5568085	0.19
182.8883820	13.93
184.2274780	0.13
195.9762421	6.87
197.5937500	0.27
198.6145630	0.05
199.8664246	0.60
200.9902802	5.03
205.0242310	0.20
211.9658203	0.09
213.4194031	0.30
214.0252533	0.93
218.9558411	1.06
221.0291290	0.77
223.9243622	100.00
225.0661163	0.13
229.9594269	0.24
231.6480865	0.07
241.1752777	1.27
241.8571930	5.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1351
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.9008179	0.04
176.9326630	0.32
179.1730652	0.30
187.1144257	0.13
188.0917969	0.13
202.6646729	0.19
204.6413269	0.22
205.4067383	0.07
215.0898590	0.14
227.1893463	0.33
242.9203186	0.65
243.7933502	0.14
245.0441895	3.21
247.1703644	0.25
250.0680084	0.11
257.3096924	0.51
259.2027283	0.28
260.0617676	0.08
269.0525208	1.02
272.9260254	1.78
275.1867065	0.19
279.2416687	0.18
284.6373901	0.10
287.0379028	6.20
289.0714111	21.69
299.1047363	6.61
309.1490173	0.21
311.0454712	0.44
318.0690308	0.08
329.1482544	0.35
338.9620972	0.18
340.8485107	0.32
346.9746704	0.23
353.2554932	0.50
357.1126099	0.56
360.7095947	0.35
364.3909912	0.07
368.0967407	0.31
369.0308228	0.09
371.1436157	0.39
373.2293091	0.27
374.1621704	0.19
381.2208862	1.44
397.2080078	0.24
397.9219360	0.61
399.1126099	0.31
402.3015137	0.17
407.1743774	47.67
409.1920776	0.60
411.1193848	0.27
412.3000488	0.14
413.2426147	0.11
414.2354736	0.77
415.0479736	0.56
416.1491699	0.18
420.1510620	0.16
423.2933350	0.40
425.1990967	100.00
430.1999512	0.21
433.1075439	0.78
437.2586060	0.24
437.9899292	0.47
445.3767700	0.39
449.2808228	0.81
450.1043701	0.52
451.0992432	35.41
454.9920654	0.13
466.5289917	0.13
467.1763916	1.49
473.2013550	0.44
475.4796753	0.19
479.1586304	0.12
484.2265625	0.19
489.1223755	0.28
490.9561768	0.27
492.7778931	0.21
493.4241333	0.15
494.8797607	0.12
500.9855347	0.59
514.2228394	0.53
514.9855347	0.22
528.9906006	0.10
531.0089111	0.80
532.6826172	0.69
533.4951782	1.39
536.0321655	0.30
541.1951904	0.33
546.1467896	0.26
559.1951294	12.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	245.0763
Annotation	Pseudouridine
Peak:m/z	Relative Intensity
83.9985428	0.03
84.9940491	0.07
86.2170410	0.01
95.9724121	0.05
96.9236603	0.49
100.0243378	0.10
112.8842773	100.00
114.9706573	0.18
116.0743103	0.41
120.8683624	0.05
128.1127014	0.02
129.9889374	0.10
132.1154175	0.19
133.0009766	0.71
134.0265350	0.10
140.0979767	0.05
141.6751862	0.03
155.8304596	0.03
157.0480957	0.06
158.0785522	0.05
159.2159271	0.03
163.7987061	0.10
169.0035400	0.01
169.8141022	0.03
173.1056976	0.01
176.0066071	0.01
181.0309601	0.07
181.9760284	0.09
182.9018402	0.02
184.1429749	0.11
185.3164215	0.01
186.1271362	0.05
187.0402069	0.07
198.8077545	0.07
200.0952606	0.02
201.1024780	0.04
203.9234924	0.10
207.0554504	0.02
207.7687836	0.01
209.1031952	0.09
221.3509979	0.05
224.5721283	0.01
226.9450684	4.35
227.7401276	0.10
230.9527588	0.02
236.7913971	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2728
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
172.0466766	0.11
191.2125397	0.09
204.2214203	0.08
205.0238037	0.04
223.0282288	4.11
223.9168701	0.14
233.3661499	0.68
234.1098328	0.06
238.9498749	0.12
240.9698639	47.63
242.0597382	1.39
259.1854248	0.51
259.9950562	0.05
275.2242432	0.73
277.1919556	100.00
278.1769714	15.68
278.7900391	0.03
315.0960083	52.83
316.1880188	3.16
333.1539917	1.78
334.1533813	0.19
413.1773071	62.57
414.2090454	12.45
431.2762451	0.99
432.4215088	0.37
485.2387085	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2009
Annotation	Unknow
Peak:m/z	Relative Intensity
134.6499329	0.37
137.0145264	0.43
139.1496582	0.08
141.1109619	0.15
144.8778992	0.57
147.0524597	1.34
149.0833435	12.58
151.1795654	0.39
155.8657684	0.58
158.1210938	0.23
161.0888519	3.11
163.0717163	1.03
165.1346283	2.67
167.1363525	0.08
168.8148956	0.06
170.9870300	1.76
174.2775269	0.20
178.4181976	0.47
179.2301331	0.54
185.8862610	0.40
186.9252319	0.06
189.0382996	11.76
189.6782227	0.17
192.9296265	0.34
202.9512634	0.04
205.0893250	0.24
207.0853882	100.00
212.8373871	0.96
219.3633728	0.47
223.2025757	0.11
224.8775024	9.52
230.9411163	6.07
246.1679230	0.56
247.0522919	0.25
248.8997803	16.79
249.7973633	0.15
250.9110413	0.19
260.8842468	0.08
267.2154846	0.40
273.2927246	0.26
280.1622925	0.07
289.3196716	0.17
291.0910034	0.67
292.8049316	0.06
295.5576782	0.06
301.0730286	0.13
311.1781006	2.23
315.2667236	0.15
319.0848999	0.19
320.0523376	0.14
320.9509277	0.76
322.8034668	0.10
325.0249939	0.30
328.3195190	0.04
332.7814636	0.65
338.8252563	0.15
340.1630859	0.18
341.3416138	0.22
353.1469727	0.86
354.1813354	0.38
365.1366577	0.44
367.0841064	0.04
368.0158691	0.15
369.2104492	0.08
375.4851379	0.61
387.4324036	0.16
389.1698608	0.20
393.1500854	0.29
399.4289246	0.53
400.2878113	0.83
401.1750183	0.21
410.1949768	0.94
411.1254578	0.78
415.0153198	0.08
416.3138733	0.50
416.9716187	0.10
418.9657288	1.26
426.6307678	1.02
427.4826050	0.11
428.9334412	2.50
431.2602234	0.13
436.3419495	4.30
437.0704651	7.58
438.7306824	0.24
440.8872070	0.06
442.0451660	0.25
442.6584473	0.06
445.2586670	0.31
451.9476624	0.56
453.3109436	2.44
454.4335022	28.98
455.1537781	34.23
456.2320862	0.63
458.1018982	0.14
460.8138123	0.93
463.9690552	0.24
472.4424438	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.1862
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
118.0053711	0.20
129.8219910	0.14
144.0095978	1.14
144.9985657	0.05
146.0219116	1.85
157.0990448	0.15
159.1014404	0.28
160.9492188	0.18
166.0898743	0.16
173.5243683	0.19
176.8930969	0.21
187.9257965	26.95
189.2095032	0.56
201.0169983	0.08
204.9640503	100.00
206.0340118	0.04
207.1097717	0.10
229.0433655	0.22
229.8842163	0.12
233.0279236	0.20
237.2027588	0.08
244.1862488	0.06
245.7538147	0.12
247.0816956	2.65
250.8552246	0.14
261.1623230	0.18
262.0306396	0.58
263.1953735	1.05
265.1746216	0.05
266.8366089	0.20
279.0917969	1.58
280.0481873	5.44
287.0421448	0.08
295.3416138	0.13
297.2077332	0.07
309.9495850	0.20
311.2941895	0.15
319.9823303	0.24
320.8451538	0.14
325.2046509	0.06
328.3062744	0.06
334.1900024	0.14
339.6307983	0.41
345.2886353	0.06
346.8796692	0.08
349.2171631	0.11
350.2561951	0.19
355.2528687	0.07
363.0187378	0.33
365.1872864	0.34
367.8700256	0.12
373.3088074	0.41
381.6997986	0.60
386.1594543	0.03
391.1369019	1.88
392.2171631	0.39
393.1876526	0.12
403.4851685	0.14
409.1044617	0.90
410.3395386	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5072
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
255.1583557	31.52
256.1842651	6.83
279.2293091	100.00
280.2623596	27.40
292.027832	0.61
305.3305664	0.20
309.4352417	0.43
311.3096924	0.22
329.2695312	0.26
342.677002	0.24
374.121582	0.84
391.2570801	0.15
395.3423462	0.65
410.1677856	0.52
434.2463989	1.44
435.4415283	0.33
447.979126	0.16
452.2827148	9.99
453.27948	5.85
458.0690308	0.12
460.4515991	0.20
469.293335	0.69
476.3648071	0.10
477.1167603	0.47
487.4484253	0.51
497.354248	0.10
501.1885376	0.70
502.8356323	0.18
523.3796387	0.36
562.8852539	0.28
569.3093872	0.23
583.7046509	0.40
584.6610718	0.24
586.3824463	0.50
617.7516479	1.03
628.380249	0.51
635.0460205	0.32
650.0880737	0.64
651.2349243	0.15
656.6369019	0.19
672.6069946	0.24
674.2476196	0.38
679.1539917	0.70
680.2507935	0.61
683.2097778	0.68
685.215332	1.99
686.1248169	0.47
693.3133545	0.30
697.0941772	3.69
697.9107056	2.15
698.5148315	2.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.5015
Annotation	PI(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
233.3719635	0.06
238.9944000	0.15
240.9571991	18.06
241.9387207	0.48
255.2368469	55.21
256.2837830	9.64
258.7549744	1.12
260.0736694	0.05
269.4484863	0.09
277.1709595	20.52
278.2428894	3.08
279.4030762	0.10
297.0578003	17.62
298.0706787	0.30
315.1790161	2.27
316.2363281	0.68
391.1987305	54.10
392.2335815	11.90
409.1332397	1.08
410.3319092	0.30
413.1864014	10.32
414.1485596	2.01
431.3292236	0.90
502.3725586	0.09
551.5582886	0.54
553.2676392	100.00
554.3641968	23.89
557.4082642	0.19
571.3683472	23.16
572.3539429	6.58
575.2780762	25.05
576.2753906	6.10
593.2856445	2.17
669.6106567	0.92
701.6293945	0.21
710.6240845	0.15
753.0130615	0.18
772.6840210	0.09
814.3792114	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	167.03
Annotation	2-Hydroxy-6-oxoocta-2,4,7-trienoate
Peak:m/z	Relative Intensity
68.9989014	1.17
77.1029053	0.12
78.8934784	0.84
80.9796066	77.45
82.8995361	1.67
84.8269043	0.57
95.0116425	16.67
96.8853149	5.59
98.9430237	3.60
105.1541595	0.29
108.0882568	0.75
110.8540344	0.10
120.9230652	1.71
122.9102173	100.00
123.9136810	0.18
124.9146423	21.55
136.8798981	0.15
138.8990479	18.94
148.9412842	5.06
152.0306396	0.10
166.9644928	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1707
Annotation	Sculponeatin D
Peak:m/z	Relative Intensity
117.2612305	0.09
121.0269470	0.17
122.8160248	0.09
131.0066528	0.20
140.9871979	0.05
147.0897217	0.20
148.1898956	0.08
149.3740234	0.22
153.0088654	0.07
154.7989502	0.08
157.0357971	0.14
158.9504852	0.31
161.0627594	0.57
162.0302124	0.03
164.9837646	0.18
171.3425293	0.10
173.0757751	0.08
174.9797058	0.32
176.0939941	0.07
177.0700531	0.98
187.2042847	0.17
189.0206909	1.22
191.2735596	0.12
199.1852264	0.18
201.1306610	1.31
203.1553040	0.76
205.0559540	0.11
207.1158142	0.09
213.3044434	0.25
215.1735992	0.36
217.2116241	0.16
219.1393585	2.35
223.3574219	0.36
227.2885437	0.42
229.2116699	0.55
231.0885620	10.98
233.0707703	1.30
235.0876770	0.10
239.3087463	0.10
241.1368713	1.22
242.3873291	0.10
243.1107483	0.21
244.8842163	1.20
247.1574097	3.37
249.1976929	1.45
251.0040894	0.48
253.2034607	0.75
254.9685669	0.08
257.2236023	1.26
259.2694702	6.01
260.3331909	0.27
261.1634827	0.31
263.1990967	2.44
267.1977234	0.10
269.0881042	0.74
271.2179565	8.12
273.2311096	0.44
275.2765198	0.14
277.1650085	6.30
279.1200562	0.04
285.2075806	0.76
287.1760864	2.99
289.2215271	7.48
292.0483704	0.06
293.1709595	0.61
297.1510010	0.62
303.2011108	0.97
305.2592773	3.11
307.2604065	9.89
308.3724976	0.12
309.4027405	0.15
313.1819458	0.16
315.2428284	2.65
317.3064575	0.16
320.9678650	0.88
323.2770081	7.52
324.2979736	0.20
331.2529297	0.62
333.2043152	27.20
334.1868286	0.31
341.2682495	0.04
347.0883789	0.51
349.2279358	1.21
351.2079468	100.00
352.1832275	0.22
358.0780334	0.15
359.1903076	6.62
365.2850037	0.52
367.2752075	0.52
375.3371277	0.29
377.1315613	61.10
377.7657166	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.312
Annotation	Unknow
Peak:m/z	Relative Intensity
241.1531677	0.48
267.0499268	0.03
268.1472168	0.14
269.1078491	0.31
275.0378418	0.11
277.1490479	0.08
279.3805847	0.66
280.2235718	0.17
281.2425537	0.54
282.3038330	0.71
283.1179504	0.75
284.4614563	0.02
293.4855347	0.16
295.2423706	0.23
296.8447266	0.06
308.2196045	0.02
309.0967407	0.13
311.0513306	8.97
320.9502869	0.09
323.2453613	0.31
325.1951599	0.25
327.4458923	0.99
341.0820923	3.39
353.1723022	0.06
355.3997192	0.15
369.3290405	0.11
377.0548096	0.05
381.1387939	0.04
391.0351562	0.13
395.3453979	0.46
397.3474121	0.05
409.2136230	0.44
413.0957642	1.45
421.1584473	0.12
423.0596313	0.24
429.3632812	0.06
430.3140869	0.34
431.1958618	3.13
439.0474854	0.04
443.6169434	0.04
459.2155151	0.03
463.5919800	0.05
467.4014893	0.05
475.5020752	0.15
476.1240234	0.03
478.4436646	0.03
480.5772095	0.08
484.2983398	0.05
485.5877686	0.11
489.4450073	0.06
519.3380737	0.04
529.2012329	0.64
535.5854492	0.18
540.0955811	0.05
545.0447388	0.03
551.2122803	0.13
563.3788452	0.08
573.2145386	0.05
579.3775024	0.16
581.2061157	0.10
592.1381836	0.24
593.4497070	0.28
603.2540894	0.46
605.3424683	0.12
619.3471680	0.83
621.3377075	100.00
621.9464111	0.81
631.2291260	0.26
632.7285767	0.40
633.4190674	1.37
635.2334595	0.33
647.0531616	0.29
648.6546021	0.06
651.2849731	42.35
652.0393677	0.34
657.2281494	0.05
659.0346680	0.05
659.6658325	0.06
663.3082886	1.34
665.4720459	0.55
667.1139526	0.11
673.3158569	0.08
675.1929932	0.12
677.4612427	0.23
681.3890381	1.82
682.5478516	0.10
687.4707642	0.20
695.2590942	0.08
705.3765869	0.29
711.0914917	0.12
712.7341919	0.04
713.5585327	0.04
714.8821411	0.07
723.2396851	5.55
723.8630371	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.2263
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0505676	32.49
188.9442596	0.79
190.0316925	0.14
200.7365417	0.04
203.1050568	0.34
204.9907990	100.00
206.0849304	1.09
207.0661011	0.28
213.1290894	0.13
217.1915283	0.08
219.0246735	0.17
228.8940735	0.14
234.8566742	0.75
235.9157410	0.04
237.3739624	0.13
247.0112152	0.66
249.2372437	0.12
253.0267944	0.10
255.0868530	0.05
265.0780640	0.92
272.3933716	0.89
273.1494446	7.17
277.1081238	0.22
283.1490479	2.59
285.1864014	0.23
291.0737915	51.24
295.0039062	0.39
297.0838623	0.47
301.0420532	35.63
311.1532593	0.05
312.9252625	0.48
315.2014771	0.67
332.9818726	0.69
338.8715210	0.07
342.2448120	0.24
357.0074463	1.19
357.6083374	0.03
369.4361572	0.31
380.8228149	0.08
381.4807739	0.21
393.0367432	0.22
398.6805420	0.21
399.3346558	0.07
408.3653564	0.13
417.1110840	1.76
421.0354614	0.21
434.6723633	0.27
435.2794800	1.09
436.0781250	0.15
452.8869019	86.79
453.6879883	0.30
466.0994263	0.85
470.9766846	0.59
477.8802490	0.40
493.6378174	0.73
495.0557251	0.29
510.6698608	0.13
514.2982178	0.09
520.0075684	0.07
535.3465576	0.09
542.4454346	0.15
559.2869873	0.15
582.4616699	0.20
583.0944214	0.09
594.3475342	0.07
611.7733154	0.66
613.4480591	0.43
637.1026001	0.98
638.2412720	0.10
639.4350586	0.16
648.1593628	0.11
657.2200317	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	999.4658
Annotation	Mukurozioside Ib
Peak:m/z	Relative Intensity
319.3857422	0.13
323.3265686	0.77
340.8176270	0.14
365.2635193	0.56
379.3240356	0.07
382.2493286	0.44
383.2565308	1.49
397.2384033	1.24
406.7348633	0.10
408.4751587	0.31
415.2940979	1.97
425.0780945	0.12
443.4639893	0.07
445.1034546	0.35
449.2485962	0.54
452.8708496	0.18
455.1221924	0.05
467.2531433	0.17
485.1000366	0.15
502.7598572	0.45
523.1933594	0.25
527.3345337	0.34
541.3211670	0.46
545.3020020	0.12
559.3011475	6.95
569.2778320	0.25
577.2885742	8.50
587.3967285	0.11
601.3999023	1.11
611.1599121	0.11
619.4919434	0.09
629.1437988	0.68
643.3768921	0.31
647.4777832	0.22
685.3360596	0.39
690.6166382	0.16
691.4476318	0.08
699.4354248	0.06
721.2327881	100.00
721.9058838	0.78
734.2958984	0.08
737.3109741	0.07
739.2303467	62.70
739.8483887	0.09
777.2729492	0.16
792.8533936	0.13
794.2939453	0.26
817.5587158	0.13
836.6962891	0.13
837.3085938	0.68
851.6562500	0.18
870.2531738	0.10
871.1801758	0.20
875.8333740	0.46
889.4156494	0.36
893.0100098	0.54
895.4118652	0.08
907.3137207	0.20
913.2509766	0.11
923.3690186	0.40
953.0600586	0.06
963.0833740	0.64
965.3428955	0.05
981.3750000	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	560.3371
Annotation	Unknow
Peak:m/z	Relative Intensity
168.1309814	0.13
168.8489990	0.23
187.1824341	0.33
187.9320526	0.24
193.0703735	0.68
214.9799500	0.43
233.3138580	0.35
241.1235046	0.09
249.9462891	0.23
263.3072815	0.11
276.9928589	0.29
283.1250610	0.17
286.9074707	0.04
300.4197693	0.35
304.0561523	0.78
314.2073364	2.78
322.1524658	0.64
324.0962524	0.08
339.1849365	0.06
342.0798950	1.84
365.3481445	0.10
377.2788086	0.14
379.3497314	0.24
407.8486328	0.16
413.2843628	100.00
431.1775513	60.15
431.8412476	0.11
433.3706665	0.08
443.1306763	0.36
453.6599731	0.10
455.5391235	0.12
462.8195190	0.22
467.5548096	0.14
471.3400879	3.71
489.1356812	0.17
497.5991821	0.34
500.0361328	0.48
501.0017090	0.29
514.3709106	0.05
515.1777954	0.20
516.3120728	0.31
518.3869019	0.08
524.2936401	1.04
524.9914551	0.55
531.7133789	0.19
541.1834106	0.34
542.3181152	5.62
543.4254761	0.48
551.5360718	0.68
559.5919189	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2626
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0091705	0.06
179.2411804	0.05
226.7446594	0.08
235.0624084	1.37
235.9158630	0.05
246.6635895	0.06
259.0506287	0.07
263.0381470	0.10
268.1539612	0.28
268.8841248	0.06
277.0948792	0.66
278.3424377	0.13
286.2424011	0.33
287.1064148	0.12
294.1600342	0.06
304.9878540	2.52
306.1506958	0.55
307.1308594	2.02
308.1017456	0.15
311.1307678	0.08
325.1791687	1.06
327.1837463	0.18
331.4728394	0.57
333.0453491	0.15
349.3709717	0.06
359.3437500	0.02
367.0883789	0.04
376.1861572	0.05
391.7089233	0.16
393.1128540	0.98
394.1780396	0.07
395.3424683	0.18
410.3577271	0.44
411.8309326	0.17
416.3320923	0.16
420.2479248	0.41
421.1498413	1.11
422.0129395	0.07
426.5342407	0.16
427.3333740	0.10
428.2963257	0.18
439.1120605	0.27
440.0886841	0.10
449.0853271	0.16
450.4598389	0.14
453.8715210	1.04
454.7322998	0.55
456.8079224	0.53
457.8060303	0.11
465.1244507	1.01
465.9985352	0.66
467.3034058	0.07
468.3853760	0.14
469.6701050	0.03
475.4500732	3.75
476.2497559	1.68
476.8814087	1.69
477.5067749	0.20
483.1264038	31.52
484.1688843	9.70
485.3718262	100.00
486.4340210	1.67
487.4367676	7.60
488.4349365	2.10
489.6749268	0.22
490.7860718	0.09
498.2289429	0.17
499.5150146	0.10
500.1312866	0.28
501.3336792	0.08
502.2749634	0.06
503.5380249	0.04
508.9962158	0.29
509.9687500	0.21
513.2352905	0.09
524.9264526	0.11
525.6098022	0.09
528.1620483	0.16
530.3725586	0.16
537.4738770	0.08
539.2196655	0.19
543.3747559	0.09
551.8316040	0.23
553.1091919	0.17
554.4320068	0.77
555.3939819	0.38
556.3574219	0.33
563.0352173	0.31
565.5422363	0.18
568.3483276	0.54
569.5102539	0.21
576.5973511	0.26
582.9479370	0.36
585.3124390	0.05
587.4696655	0.17
593.2742920	0.36
597.5219727	0.65
598.7514038	1.51
599.5223999	0.05
607.3158569	0.47
608.6416626	0.18
609.6345215	0.09
611.2062988	1.40
611.9812622	1.03
620.1626587	4.23
620.7863159	3.77
621.4451904	1.39
643.5015259	0.12
645.2986450	0.88
646.2988281	0.24
646.9578857	0.17
647.7255249	0.26
663.4276733	0.16
664.4767456	0.05
715.4193115	0.14
728.2311401	0.17
729.4650879	0.05
744.3558350	0.06
758.4851685	0.03
773.3377075	0.08
775.3855591	16.64
776.3576660	7.89
777.4309692	1.76
785.3532715	0.09
805.6898193	0.09
816.6080933	0.33
843.5994263	0.07
848.3256836	0.04
849.3847656	0.17
871.1818848	0.17
890.0057983	0.05
891.3674927	0.11
892.3057251	0.07
907.4340210	0.12
908.4514160	0.25
915.4912109	0.05
916.5223999	0.09
933.2995605	1.85
934.3904419	0.91
935.7570190	0.95
936.5348511	0.27
937.4921265	0.11
951.3685913	0.78
952.5455933	2.56
953.4323730	12.59
954.3534546	5.67
955.5761108	1.45
969.5817261	0.48
971.2980347	8.17
972.5707397	2.83
973.5093384	0.43
1034.6885990	0.16
1125.5983890	0.06
1138.5438230	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1765
Annotation	Sarracine N-oxide
Peak:m/z	Relative Intensity
100.2163544	0.08
109.1883240	0.20
110.1033478	0.09
122.9339905	0.11
127.9918518	0.93
129.9651794	14.43
132.6515808	0.24
135.0259094	1.07
137.2135162	0.14
139.9605255	0.07
149.0703888	0.10
152.0292358	0.64
154.0948639	1.48
156.0393829	2.19
158.8452454	0.13
159.9315948	0.18
161.0014038	0.17
164.1152649	0.16
166.1056519	0.11
172.0115967	2.46
177.0260925	3.38
179.1121674	2.83
179.9268646	1.05
181.0745850	23.78
186.9910583	0.07
189.0747986	0.24
190.8650208	0.08
192.1862793	0.08
192.9905853	0.19
195.2187958	0.07
196.0198822	0.11
203.4168396	0.07
204.9508667	0.25
205.8869019	0.16
207.0374146	0.22
208.1057892	1.04
210.9954529	0.13
219.3551331	0.07
220.2251282	1.24
221.0442505	1.92
228.1868286	0.25
229.9234924	0.18
235.0969849	0.23
236.4142761	0.33
237.8656921	0.14
239.4654541	0.11
244.2309570	0.17
246.2606201	9.72
248.2003174	0.61
251.9725952	0.08
254.1023865	1.02
258.2306519	0.38
262.6830444	0.17
264.3671570	0.09
266.1590271	0.13
269.1497803	0.67
271.2965393	0.06
272.1315308	0.83
274.0994263	0.95
279.1061401	0.09
288.6554260	0.68
290.1479492	55.41
290.7614136	0.20
291.5620728	0.12
308.2616272	100.00
309.1150513	0.51
311.0940552	0.28
313.8949585	0.11
316.2402954	0.33
317.5367432	0.11
322.1181030	0.07
325.1961060	0.37
334.1911926	54.89
335.0348511	0.16
338.2551270	0.23
352.1602478	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1703
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
192.994339	0.02
217.050766	0.08
233.0932159	0.10
243.0483704	0.09
266.3192139	0.15
271.1276855	1.90
272.0991211	0.63
276.1834106	0.14
282.9254761	0.03
284.0426331	0.11
294.6937866	0.14
295.2957764	0.23
296.3635254	0.15
298.1551514	0.06
302.168457	0.03
313.0449219	4.20
314.1550598	1.64
320.3713379	0.03
322.1083374	0.02
332.3218994	1.01
334.1591797	0.05
337.0738525	0.49
338.1658325	0.04
343.1600342	0.10
345.7980957	0.02
347.1604614	0.14
363.9174194	0.08
367.2158203	0.52
368.1234131	0.20
373.2791138	0.02
378.9598999	0.03
382.7209473	0.02
384.2816772	0.05
387.2568359	0.09
390.3146973	0.08
391.9078979	0.03
393.2198486	0.04
397.1655884	0.90
398.09198	1.17
399.1309814	0.11
400.2479248	0.09
404.1819458	0.10
406.1126099	0.03
409.1773682	0.02
410.3446655	0.04
413.4706421	0.09
415.0918579	9.62
416.09729	5.42
417.1733398	0.56
418.0276489	0.56
422.2803955	0.14
427.144043	0.32
430.2311401	0.03
431.3533325	0.13
433.1067505	100.00
434.2107544	50.49
435.0737915	0.04
439.1644287	0.02
440.9107666	0.06
444.368042	0.05
445.1862793	0.07
449.2220459	0.05
457.3568115	0.33
459.1040039	0.18
460.1020508	0.07
461.0545044	0.07
462.4914551	0.07
464.2664795	0.21
465.149353	0.05
471.7717896	0.04
477.8515625	0.11
481.229187	0.02
490.3569336	0.13
493.9238892	0.03
494.8870239	0.14
499.0821533	0.18
499.9817505	0.08
508.1558838	0.03
517.2217407	0.08
518.4475708	0.15
520.9447021	0.15
525.25177	0.31
526.2434692	0.18
536.2213745	0.32
537.3502808	0.03
538.7149048	0.17
543.1677856	0.25
544.2206421	0.21
551.1349487	0.09
552.0308838	0.04
557.2788086	0.17
559.3433228	0.05
561.2964478	0.72
562.2405396	1.00
563.0674438	0.16
564.649292	0.20
571.1990356	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1668
Annotation	Unknow
Peak:m/z	Relative Intensity
142.8809814	0.09
150.7466736	0.04
152.0967865	0.11
153.0600586	0.07
160.9435120	0.09
161.9888000	0.05
163.0723572	0.03
167.0776062	0.06
177.0645142	0.05
189.0949249	0.69
203.0446777	0.68
205.1954803	0.06
243.2730103	0.05
251.1234741	0.05
285.3617859	0.10
286.0832520	0.06
287.1110229	0.41
303.3578491	0.43
305.1888428	6.82
323.1201172	100.00
329.1416016	0.04
333.0294495	0.07
334.0527954	0.11
346.3672180	0.05
348.3483276	0.06
363.0144043	0.03
365.1414185	10.21
377.2266235	0.05
381.1330872	0.02
393.0292053	0.06
395.2779236	0.13
404.9382019	1.68
406.9820251	0.15
409.2946167	0.08
420.7563171	0.18
423.3789368	0.23
431.2069397	0.27
435.2997131	0.08
447.1755981	0.04
448.2962341	0.08
449.1534729	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.08
Annotation	gamma-Glutamyl-S-methylcysteine sulfoxide
Peak:m/z	Relative Intensity
84.8458557	0.06
87.9345169	0.68
93.0006714	0.03
97.1589508	0.02
106.7547073	0.01
110.8334808	0.02
112.5719452	0.03
121.9046249	0.05
123.1646271	0.08
124.8416443	0.07
126.8789062	0.01
128.9361877	0.04
130.0143433	0.35
133.0354004	0.05
133.8228149	0.04
145.0886841	0.06
152.0342712	4.88
153.1585846	0.04
163.1648712	0.01
164.9024353	0.07
165.8728333	0.12
186.9420166	0.02
188.8116455	0.02
190.9831238	0.07
198.9892578	0.05
200.1606750	0.05
205.0211182	0.02
208.8722839	0.07
212.9003296	0.06
216.9954224	100.00
218.9744568	0.07
220.3641663	0.04
221.0045166	0.04
221.8972168	0.01
222.9383545	0.03
224.1160278	0.04
225.0676575	0.01
234.8908691	0.25
237.3404236	0.06
238.1427612	0.02
239.8587646	0.05
244.9401245	0.21
249.7482910	0.04
251.1159973	0.03
252.3682556	0.03
253.1653137	0.03
258.7757568	0.03
262.9263916	0.39
265.2514648	0.12
266.1286011	0.03
272.1323242	0.08
280.8329468	0.10
289.3810425	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	211.1326
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
66.8675613	0.05
70.8669357	1.32
77.8146362	0.01
83.0702515	0.04
84.8673096	0.12
87.0299072	0.06
91.0757904	0.14
92.9359589	0.09
94.8539124	0.05
97.2466278	0.02
98.9115143	0.05
104.9890747	0.03
107.0134430	0.30
109.0427856	0.07
110.7864075	0.02
114.8006287	0.02
121.0252228	0.03
123.0480042	0.16
124.9666748	0.08
127.1144562	0.10
131.0236969	2.22
132.9761658	11.54
135.2899475	0.03
136.9743652	0.16
141.0043793	0.51
142.0311432	0.01
142.7741241	0.02
146.9875031	1.46
147.5888519	0.01
148.9842682	1.62
151.0711060	14.06
152.0223846	0.03
153.0148621	0.16
154.9551849	0.98
157.2397614	0.16
162.8971252	0.07
165.1187439	0.62
167.0756989	0.15
167.8358002	0.02
169.1929474	0.15
169.9090729	0.07
174.8974457	8.43
175.5051117	0.02
180.6940765	0.03
181.3193512	0.09
182.8808136	0.19
185.2127838	0.01
190.0225372	0.04
192.9667816	100.00
193.9385376	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	790.5597
Annotation	PS(16:0/20:0)
Peak:m/z	Relative Intensity
223.0606537	0.38
225.2293701	4.63
241.1516571	0.15
241.9400177	0.14
253.5761108	0.10
271.2616577	83.49
279.2091370	14.05
280.2210083	0.24
281.1746216	0.13
293.0711975	0.42
306.2315979	0.10
330.4190674	0.29
414.7565918	0.11
415.4060059	0.31
433.3510132	0.33
447.4671631	0.07
448.4758911	0.22
485.4376831	0.14
504.2656250	100.00
504.9238892	0.29
527.2025757	0.60
595.3370361	0.47
606.3056641	0.10
685.1849365	0.27
702.2991943	0.11
726.4351196	0.15
731.3593140	0.21
738.5863647	0.23
754.6013794	0.15
755.8847656	0.26
770.3389282	0.22
771.8488159	0.21
772.4635620	0.68
773.3421021	0.66
775.0653076	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	492.2714
Annotation	PS(17:1(9Z)/0:0)
Peak:m/z	Relative Intensity
143.9970093	0.68
149.2171478	0.35
152.9555054	0.35
154.7884827	0.30
159.0146332	0.47
161.1920013	0.58
163.2348328	0.60
163.8896790	0.09
166.0191040	0.31
175.1184998	0.60
177.0831604	0.51
179.1619720	0.87
180.0455933	0.09
187.0904846	0.08
193.3279419	0.21
195.0557251	0.34
215.1514435	0.04
216.1160736	0.17
224.1420593	1.11
227.2545166	0.04
229.1408691	0.69
238.2459564	0.13
251.2465363	0.10
255.1643066	0.05
259.1539001	0.82
264.2070007	4.69
267.9847107	0.03
269.1903076	7.32
277.2547302	4.62
279.2983398	0.46
291.2306213	0.04
293.0569763	1.25
294.1673889	0.10
295.2474976	0.18
297.9948730	0.19
300.1789551	0.07
303.6513367	0.22
307.1745605	0.38
311.1186523	0.02
312.7783813	0.13
313.3839722	0.07
318.2070007	0.18
320.3281860	0.21
327.8786011	0.18
330.3774719	0.12
333.0722656	1.35
336.2141418	0.24
338.3332214	0.50
349.0346680	0.79
351.2354431	39.43
352.0564575	0.33
357.2268066	0.39
360.2257080	0.12
361.7385559	0.04
367.3397827	0.29
368.1364136	0.10
370.0067139	0.10
370.8686829	0.07
374.2841187	4.08
378.3318481	0.36
379.1867371	0.07
392.1712341	17.98
392.8724670	0.34
394.3559875	0.65
395.0588074	0.33
400.2642517	0.15
402.2946472	0.10
408.2488708	0.08
411.2755127	0.73
413.1995239	2.65
417.8677063	0.14
419.9206848	0.05
431.1370544	57.50
431.8059082	0.17
442.7761536	0.08
443.4129333	0.05
447.0072021	0.41
449.0556946	5.48
450.0369263	0.24
456.3801270	2.82
457.3809509	0.31
462.5301819	0.13
463.3237000	0.21
474.1862183	100.00
475.0827942	0.44
478.9722290	0.13
482.7678528	1.47
483.5867615	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2938
Annotation	Phosphatidylethanolamine lyso 18:1
Peak:m/z	Relative Intensity
139.9954987	0.03
153.0247803	0.04
196.0739136	1.60
214.0597992	1.41
242.3076782	0.08
253.1991272	0.79
281.2238159	100.00
282.0005798	0.02
417.3685608	0.19
432.4777527	0.08
435.2312927	0.11
436.3674011	0.03
460.3241272	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.1808
Annotation	Unknow
Peak:m/z	Relative Intensity
184.1751099	0.05
301.1933289	0.08
307.0645142	0.66
325.1631775	5.58
331.2801514	0.12
341.8151245	0.03
349.1115112	8.86
353.2060547	0.03
367.1858215	0.03
389.2017212	0.32
391.2206726	0.17
407.1576843	0.65
409.2754211	0.19
415.2023926	6.22
423.2775879	0.27
425.6152649	0.04
429.6897583	0.08
433.1590271	33.16
439.2057190	0.07
451.1546631	100.00
454.3716125	0.06
460.0123596	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
125.0461884	0.01
146.0344391	0.03
160.9334412	0.08
178.9404755	0.01
215.3731995	0.02
215.9984436	0.03
216.9899597	0.08
269.0405273	0.23
270.2793274	0.05
281.2608643	0.08
283.1068115	0.13
284.2295227	0.28
290.0927429	0.02
291.0500183	0.09
293.0969849	0.17
294.152832	0.12
309.2243042	0.01
311.057251	100.00
312.0655518	69.62
312.669281	0.08
321.0709534	0.04
323.1312866	0.30
324.1528015	0.22
326.2466125	0.01
333.1035767	0.01
336.016449	0.01
337.2382812	0.03
338.0578918	0.25
339.2345581	0.02
341.0795288	11.54
342.1046143	9.23
349.1367798	0.02
350.4135742	0.06
351.2823792	0.02
352.9568176	0.68
354.0710144	0.77
355.1248474	0.31
356.1228638	0.24
364.8684387	0.05
366.0522461	0.04
366.9989624	0.06
368.1526489	0.07
369.9794617	0.04
371.1144409	0.27
372.1246338	0.20
377.0614319	0.09
378.2705994	0.10
383.0964355	0.26
384.1322021	0.29
386.2395935	0.01
386.8976135	0.02
387.6299744	0.05
390.3224487	0.02
395.1181335	0.11
396.1153564	0.31
402.5057373	0.06
413.1598816	1.19
414.2243042	1.18
431.9284668	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5068
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
226.9444427	0.05
249.2940979	0.11
251.2734985	0.11
255.2108612	39.12
256.3181152	6.43
261.1638794	0.24
262.5491333	0.28
269.3756714	0.15
279.227417	100.00
280.2789001	16.83
294.2319946	0.39
295.2524109	0.30
308.3146057	0.10
392.2588501	0.10
405.4454346	0.09
434.3821411	0.92
452.2418823	17.65
453.3394165	2.81
458.1972046	1.60
459.265686	0.12
476.2647095	2.53
477.5307007	0.39
485.0529785	0.43
507.4719849	0.93
511.9514771	0.39
579.8309937	0.11
612.0831299	0.07
644.2633667	0.15
655.59198	0.09
656.2509155	0.33
668.9562988	0.09
670.7993774	0.23
676.0679321	0.08
679.3952026	1.32
681.2248535	0.58
696.8294678	0.30
697.585144	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1608
Annotation	Glabraoside A
Peak:m/z	Relative Intensity
178.9476929	0.29
183.0002441	0.54
185.0957031	0.11
199.0302124	0.20
203.2611084	0.35
205.0213623	1.30
208.1754456	0.11
210.9296570	0.10
212.9600067	0.19
216.8569946	0.42
227.0128784	2.24
235.0513458	3.39
235.9079285	0.08
238.5644073	0.17
245.0726929	1.40
246.8487396	0.42
253.0420380	0.53
257.1654663	0.24
265.0563660	5.48
271.0567017	7.71
273.0584717	0.06
280.1516724	0.17
282.9354858	0.29
287.1827393	0.54
288.0957947	0.65
289.2265625	3.17
297.1144409	0.31
307.0909729	1.34
312.1827698	0.10
313.0786743	0.36
315.1848755	0.09
325.1681519	3.75
330.1204224	0.30
341.2331543	0.15
346.5232544	0.41
362.2769775	0.18
373.0298462	0.09
389.0993042	0.83
395.9266968	0.16
399.2193604	0.49
404.2418823	0.11
412.9783325	0.49
416.4437256	0.05
417.3145752	1.03
421.7724609	0.18
429.3616333	0.61
431.2192383	0.15
432.1301270	0.10
433.2318726	0.97
434.5559692	0.04
435.1762085	1.36
442.2034912	0.13
449.6606445	0.49
450.5962524	1.75
451.2552490	13.77
452.3377686	0.32
453.1389771	0.16
455.3081665	0.16
459.1387329	100.00
464.3637085	0.37
468.7949219	0.19
471.2119141	3.71
475.0620728	0.25
477.1895752	0.98
487.2529907	0.23
491.0578003	0.06
496.4585571	0.12
503.2257690	0.32
506.5150757	0.24
520.0747681	0.31
525.1434937	0.10
528.2738647	2.46
529.3471069	0.14
531.5765991	0.06
534.0479736	0.24
535.0311890	0.06
536.0763550	0.27
537.1441040	0.84
549.2848511	0.81
550.2572632	10.80
551.3380127	5.77
552.2080078	1.87
553.4104004	1.47
554.4436035	0.56
560.8772583	0.11
565.1424561	1.26
565.8488159	0.10
569.1715698	0.13
579.1211548	1.21
579.7582397	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1506
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
183.9021301	0.04
196.1897736	0.09
210.1033783	0.02
211.1717072	0.03
214.9097137	0.01
223.3557892	0.01
224.0060577	0.02
226.2305603	0.01
237.0375519	0.08
239.1169128	0.10
241.2423248	0.02
251.3626556	0.02
255.3610229	0.01
266.8742371	0.03
269.1182861	0.05
279.0460205	0.10
281.1800537	0.09
283.0886841	10.37
284.2025757	1.51
293.0406494	0.21
295.7689209	0.02
296.9926147	0.03
301.4089355	0.04
305.4147644	0.03
307.5043335	0.01
308.2319336	0.03
309.1081848	0.22
311.0649414	100.00
312.0738525	17.36
312.7437744	0.03
323.0137329	0.71
324.0341797	0.20
325.1965942	0.33
326.0166016	0.20
327.3728638	0.05
327.9980469	0.05
333.2034302	0.09
335.0199585	1.24
335.9508667	0.19
337.3601685	0.01
338.2528076	0.02
341.2804565	0.06
342.0784912	0.02
343.3187866	0.02
349.1940308	0.33
350.2003784	0.02
351.3670044	0.10
353.0991821	14.67
354.1111450	3.82
354.9779663	0.02
356.9257202	0.05
360.1562500	0.02
365.1342773	0.14
367.1995850	0.05
368.6322021	0.03
369.3062744	0.04
370.6925049	0.02
377.1520996	2.45
378.2044678	0.75
383.0258179	0.02
384.4293213	0.03
385.2073364	0.10
386.2706299	0.01
391.2619629	0.05
393.1317749	0.08
395.0837402	6.63
396.1626587	1.74
410.1660767	0.07
413.0996094	17.19
414.2019653	3.89
417.1973877	0.02
431.1090088	0.27
432.2200317	0.02
449.0175781	0.01
470.2512207	0.01
503.2254028	0.57
504.2648315	0.16
515.1231079	1.15
516.0916748	0.58
529.2114868	0.01
533.2675171	0.03
548.5413208	0.12
549.1901245	0.04
557.2750854	0.07
558.3200684	0.04
575.1865845	1.70
576.1774292	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.29
Annotation	Alpindenoside C
Peak:m/z	Relative Intensity
229.3721466	0.08
241.4178162	0.11
247.0564270	0.06
257.3312073	0.13
273.2300110	0.20
277.2983398	1.02
278.9422607	0.64
314.1261597	0.06
317.0729675	0.30
318.2067261	0.11
333.6015015	0.19
334.9674683	0.84
336.2219238	1.22
337.2770386	0.21
343.2327271	0.08
347.2902222	0.06
357.0701294	0.13
369.1487427	0.12
375.6171265	0.22
385.7643433	0.27
390.7552490	0.08
413.1977539	0.86
415.2992554	1.08
429.2541504	0.05
431.1489258	0.41
433.3780518	0.25
474.9089355	0.12
479.2386475	0.10
479.9651489	0.10
482.8355103	0.14
495.6938477	0.11
503.5061646	0.24
504.1669312	0.41
506.5299072	0.11
507.1570435	0.08
509.1382446	0.17
511.2965088	0.13
513.5707397	0.05
518.3743896	0.09
520.0118408	0.15
522.3999634	0.04
531.4451294	0.07
536.1386108	3.68
539.4155884	0.05
543.4898071	0.16
545.1091919	0.08
559.0769043	0.13
573.4700317	0.16
582.9581909	0.16
586.9813843	0.11
589.0095215	0.32
589.6127930	0.08
599.3537598	0.13
600.5847778	0.44
601.4499512	0.06
608.2296753	0.15
613.5937500	0.07
615.6647949	0.22
616.4832764	0.14
617.4329224	0.41
619.2185669	8.65
620.0172119	0.14
631.2299194	0.14
632.3215942	0.69
633.0628052	1.34
634.0560913	0.49
643.0139771	0.80
646.5022583	0.09
647.2760620	0.70
648.2438965	0.18
649.2600708	1.41
657.3875732	100.00
660.1110840	1.58
661.1754761	1.49
664.4572754	0.05
665.4656372	0.40
673.1173706	0.05
674.1560669	1.16
675.2566528	3.92
676.0154419	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	713.38
Annotation	digitalin
Peak:m/z	Relative Intensity
201.1766510	0.17
213.2114868	0.09
214.0004578	0.14
215.2995300	0.96
223.0910950	0.14
225.2260742	0.26
227.0879822	0.14
234.0543213	0.38
234.9958649	0.36
235.9972534	0.91
236.8778687	0.34
238.8587036	1.37
240.8867798	0.47
242.0945129	2.09
247.1821899	0.98
249.4303589	0.35
250.1005096	0.52
250.9398499	0.42
252.0930939	0.29
264.9761658	0.53
267.1193237	6.64
268.0776062	5.57
269.0478516	28.04
270.1758423	20.33
271.2787476	0.26
272.9692383	0.48
276.0389709	0.20
279.1827393	1.61
280.3049622	0.54
281.1579895	1.31
281.8192749	0.27
287.1954041	0.28
288.1799011	0.54
289.0534363	0.65
290.1403809	0.45
291.2230835	1.22
292.9281006	1.05
296.0909119	0.22
297.2035522	0.15
299.2224121	0.34
305.0081787	0.94
307.1645508	2.12
308.1500244	3.25
309.0955505	1.42
311.3126831	0.34
316.8547058	0.30
318.5504761	0.41
321.3142700	0.61
327.0398560	1.69
330.2064209	1.21
339.7274780	0.51
347.2497559	4.75
348.2246704	3.82
349.1013794	2.79
353.2844849	0.13
365.0984497	2.88
366.2098389	3.91
367.1866455	8.54
368.0806274	0.10
381.2753296	0.40
383.1715088	28.18
384.2509155	37.69
385.1917114	100.00
386.3526611	0.45
388.1032715	0.50
389.3446045	0.14
394.9534302	0.28
397.4594116	2.11
398.9931641	0.14
453.3170166	0.55
456.1860962	0.17
519.5559692	0.27
521.4115601	0.40
527.5558472	0.47
533.3410645	0.37
538.4921875	0.56
549.2287598	0.31
551.2399292	0.54
562.1273193	0.34
569.3919067	0.13
571.1609497	0.28
577.2661743	0.28
579.3482666	0.15
587.7250366	0.58
594.5169678	0.17
595.6807861	2.17
596.8217163	4.25
597.9704590	2.81
618.4713745	0.45
619.2545776	0.64
633.5483398	0.43
635.2108765	0.32
637.0582275	1.32
644.1962891	0.56
647.3436279	1.16
648.4042358	1.12
659.2035522	0.62
669.1488647	0.30
675.2907104	0.22
676.2459106	0.49
677.1760254	0.15
678.7737427	0.55
694.1522827	3.29
694.7993774	3.32
695.4225464	1.58
696.6179810	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.2926
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
172.8857269	0.43
175.2513733	0.04
184.0006104	0.20
187.4231873	0.10
190.2382050	0.10
191.1540070	0.02
201.2782288	0.13
203.1465912	0.19
205.2869568	0.10
207.2527466	0.10
209.2072754	0.07
215.3508453	0.19
221.0572205	0.13
224.9695282	0.74
227.3858032	0.03
229.1592407	0.10
236.9774933	0.20
243.1383057	0.64
245.1944275	4.61
255.3976440	0.05
256.9726562	0.04
261.0340271	1.42
263.2695923	1.28
268.8903503	0.03
273.1567993	0.14
277.3684692	0.08
279.4198608	0.50
280.9140930	0.08
287.2117310	0.08
289.2733765	0.15
291.1820679	0.06
297.1630859	0.12
298.9293823	0.24
301.1588135	0.15
312.1002808	0.04
313.4324646	0.05
315.1143799	0.24
317.1163330	13.82
318.4417114	0.24
319.2821655	0.33
320.1713257	0.10
322.0205078	0.17
331.5601196	0.15
332.8460083	0.20
335.0532227	10.38
337.3100586	48.07
339.3219604	0.05
343.3347778	0.14
347.0565796	0.18
349.3473511	0.09
352.9242554	0.11
355.5230103	0.13
367.1951904	0.06
375.4891357	0.06
381.0226440	0.15
391.6546021	0.29
397.1008301	0.05
407.1571655	0.25
408.9463501	0.04
414.9620972	0.17
417.0659180	0.24
419.4129639	0.12
425.2718506	1.12
427.6195068	0.30
431.0280762	0.04
433.1180420	0.13
437.5065308	0.08
439.1157837	0.08
445.5958862	0.02
449.1279297	0.50
450.6045532	0.53
451.4293213	0.15
463.0753784	0.14
477.1737061	0.33
487.2930298	0.05
491.8281860	0.07
504.7932129	0.20
505.5787964	0.08
506.4063110	0.13
508.7020874	0.19
511.3901978	0.30
513.7817993	0.07
514.9835815	0.14
515.6578979	0.06
516.4509888	0.09
517.4578247	0.12
519.1914062	0.23
522.9225464	0.13
524.8884888	0.16
525.7398071	0.13
529.1995850	0.34
533.9231567	0.30
537.4407349	0.08
542.8489380	0.41
561.2301025	100.00
562.5402222	0.15
569.7457275	0.19
578.3455200	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	578.1862
Annotation	Unknow
Peak:m/z	Relative Intensity
172.0144043	0.03
189.0352020	0.04
193.1423187	0.04
202.2051849	0.02
204.0508881	0.02
224.9723053	0.01
227.1573792	0.04
246.7668762	0.03
268.9487610	0.01
298.9901123	0.03
300.8936768	0.10
312.0000000	0.02
324.0106201	0.03
325.2130737	0.03
342.9284058	0.08
364.2385864	0.03
367.1567383	0.09
374.3941040	0.03
378.2243042	0.03
379.3026123	0.01
384.9642334	0.01
386.3265381	0.02
389.5634766	0.02
397.0158081	0.05
399.3236694	0.02
400.2277832	0.05
409.1078491	0.05
411.4898682	0.03
414.0581665	0.03
416.3569336	0.01
419.8921509	0.03
425.2158203	0.14
426.1707764	0.04
427.0081177	0.33
428.2438354	0.01
431.1914673	0.04
442.2338867	0.03
443.1651611	0.32
445.1278076	4.99
446.1828613	0.12
452.5154419	0.01
455.0609741	0.03
457.2331543	0.15
457.8488770	0.03
463.0133057	100.00
464.0020752	0.07
470.2261353	0.01
473.6068726	0.09
476.9285278	0.09
478.3311157	0.05
482.1104126	0.05
490.3866577	0.02
498.1841431	0.19
511.0700073	0.02
512.3628540	0.05
516.2174072	0.01
517.4590454	0.08
524.5277710	0.01
529.3813477	0.04
534.0054932	0.05
542.1927490	0.23
545.8959351	0.01
556.8314209	0.02
559.4504395	0.68
560.2313232	3.49
568.7341309	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2626
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
150.8857574	2.28
152.9026794	100.00
170.9457550	16.67
196.2269287	0.25
205.2228394	0.51
213.9843750	1.10
243.1914062	0.30
263.1208801	0.47
277.1256714	0.14
311.5362244	0.38
327.3928833	0.50
382.3404846	5.37
400.2279663	80.29
401.1293030	1.49
405.1935730	0.26
417.3106384	0.44
418.1004944	0.65
428.3352051	0.33
455.1273804	1.20
458.2907410	1.18
459.1003723	0.55
473.1094055	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.3908
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0584259	0.38
222.7613831	0.13
233.1166992	0.21
235.1417694	0.18
241.2331390	0.55
245.0383759	0.12
250.6068420	0.16
255.3140259	1.28
262.8791809	0.42
277.0528564	0.11
278.3521423	0.24
279.4520874	0.59
280.2398071	0.10
283.5492249	0.18
287.1037598	0.07
291.2230530	0.10
293.2831421	0.21
294.3812561	0.08
295.4890137	0.07
297.2716370	0.40
298.0545349	0.35
305.1714478	0.13
307.2224121	0.27
320.8508911	0.27
321.4518127	0.17
323.1039429	1.74
329.2882690	0.37
332.2091064	0.08
340.9547119	1.11
341.5589600	0.09
355.1162720	0.20
368.9749756	0.39
377.2006226	0.37
391.2932739	0.29
395.3713989	0.04
396.9595947	0.16
402.3933716	0.12
409.0796509	0.29
414.4409180	0.25
415.3079834	0.12
429.5211182	0.23
434.0560913	0.37
450.3602905	0.36
471.2928467	0.20
478.9326172	0.60
483.2683716	0.35
485.1530151	100.00
487.3701172	0.10
503.2530518	51.14
508.2378540	0.44
508.8938599	0.18
514.2946167	0.13
521.1498413	0.31
524.8257446	0.28
526.2805786	0.28
553.0299683	0.22
553.6643677	0.54
562.2939453	0.20
565.3076782	0.05
570.8710327	0.26
571.5317993	0.17
591.0823364	0.27
593.4338989	0.53
607.1970825	0.31
610.2470093	0.16
611.4124756	0.16
624.6231079	0.15
629.2341919	0.18
634.1051025	0.28
636.4968872	0.07
638.0501099	0.34
641.4547729	0.33
653.4585571	0.08
658.1536865	0.13
661.1611938	0.12
675.2797241	1.17
683.0553589	0.19
686.5364990	0.32
687.4492798	0.42
689.7073975	0.29
693.5321655	0.39
700.1953735	0.38
701.1511230	0.91
702.3842163	0.19
703.0697632	0.10
704.8258667	2.13
705.9127808	0.74
718.2962036	0.18
719.3944092	0.55
728.3621216	0.45
729.3007812	0.20
738.5863647	0.32
746.6684570	0.75
747.4954224	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.4172
Annotation	Unknow
Peak:m/z	Relative Intensity
168.8136902	0.48
169.9713745	0.71
171.1711884	0.72
172.0261993	0.16
173.1312256	1.58
173.9097900	1.15
175.1219482	4.51
176.0247803	0.69
177.0824432	0.46
178.1572876	0.92
179.2393188	0.89
180.1911316	0.75
180.9235535	1.33
182.2016144	2.24
184.1159515	2.21
185.0691528	2.86
186.7945099	0.73
188.8686523	2.47
190.2437592	1.76
191.1784363	0.50
192.2554016	0.97
193.1699829	1.22
194.2180786	0.41
195.3265686	1.02
196.1051331	0.26
197.0936127	5.30
199.3061371	2.56
200.9790497	0.64
203.0361023	6.07
204.1792908	0.17
207.2214966	6.66
208.0474854	2.71
209.0747070	2.81
210.1362000	6.83
211.1490173	0.78
212.0256958	0.60
212.9735413	2.57
214.8761597	0.40
216.0422211	0.35
217.0252075	0.80
218.1108093	2.66
218.9983673	1.40
221.0864563	29.23
222.0682983	2.06
222.8861694	0.89
224.3447571	0.62
225.2414093	2.10
227.1004639	2.81
229.2527771	0.25
230.2087708	0.52
231.1916809	0.21
232.9658966	7.24
234.1328735	7.82
235.1682892	4.03
237.0868073	26.44
238.0517273	1.63
239.2950134	1.29
240.0511169	0.67
241.3272247	0.98
243.0197754	0.48
245.2583618	1.44
246.1606445	1.65
247.1685791	3.10
248.0842590	6.84
249.0818634	3.37
250.1542816	5.31
251.1502686	4.00
253.1930847	0.55
255.2482452	4.77
257.3510742	0.78
259.1469116	5.53
260.1438599	1.11
261.1978455	2.07
262.0987549	2.05
263.1383362	4.76
265.0421143	2.80
266.9987183	1.03
269.3666687	2.38
270.2239990	2.97
271.1380920	4.08
271.8587952	0.91
273.2229309	3.32
274.3175964	9.48
275.4962158	1.34
276.2066040	0.78
277.2644653	1.50
279.2306519	2.84
280.9627991	2.57
282.2174072	0.55
283.3432617	0.37
284.2138062	0.62
285.4111328	0.97
286.3147278	13.79
287.2670898	9.46
288.6176147	1.72
289.3853760	1.01
290.6748047	0.16
293.3089600	0.50
294.1336365	0.99
295.1460571	0.96
296.3199158	0.49
297.1903992	0.79
298.0977478	1.18
299.2789307	10.24
300.4305420	6.14
301.2838745	3.22
301.9625244	0.20
303.1355591	10.61
307.1471863	2.18
310.2604370	1.15
311.3332520	2.97
312.1293945	3.89
313.1722412	11.32
315.1439209	4.78
317.1945190	1.45
319.1981812	1.71
320.1478882	0.81
321.0184021	2.85
322.2175293	1.52
323.2651062	2.24
325.1872559	28.18
326.0002441	0.79
327.2617188	1.16
328.4254761	0.99
329.5070190	0.14
331.2711792	2.22
335.3867188	2.29
336.1572876	0.32
337.2045898	2.78
338.3164673	0.38
339.1845093	0.46
341.2481079	2.01
342.2767334	0.92
343.3096924	0.47
345.4058228	0.90
346.3162842	0.72
347.3876953	2.47
348.4107056	2.11
349.1333008	3.01
350.4588013	1.23
352.2966919	48.72
353.2878418	0.46
354.5466309	0.62
355.2537842	0.42
356.3065186	0.88
359.0558472	5.08
362.3114014	1.53
363.4764404	1.32
364.2020874	2.67
365.2765503	8.62
366.3483887	3.25
367.3381958	1.48
368.4281616	1.85
369.2981567	1.44
371.1455688	1.58
372.2203369	0.57
373.1462402	2.42
374.2435303	4.46
375.4944458	2.23
376.9765015	2.36
377.7214355	2.56
378.3391113	3.64
379.5748291	0.56
380.1857300	0.33
381.4147339	0.36
383.2330933	1.28
384.9892578	0.65
387.4706421	1.62
388.2925415	4.28
389.2565918	1.74
390.2624512	0.69
391.4017334	10.17
392.2880859	1.57
393.0289307	1.48
395.4740601	0.53
396.4470215	0.46
400.4239502	0.30
401.2357178	3.04
402.4440918	0.69
403.2855225	0.62
404.8632812	1.61
406.4657593	0.35
408.7000122	0.48
409.4099121	0.63
410.4449463	0.72
411.1143188	0.73
412.1723022	0.56
413.6518555	1.08
414.4537964	1.35
415.1968994	0.60
416.4020996	0.85
417.8064575	2.23
419.3716431	3.84
420.2090454	1.08
423.0385132	1.07
424.4204712	1.34
425.4911499	1.57
427.2508545	2.24
428.1898804	0.59
429.4625244	1.26
433.2724609	0.80
434.0576782	0.45
435.8944702	1.04
437.3838501	2.12
438.9931641	0.61
440.5147095	0.64
441.4204102	3.99
442.2922363	0.77
443.2327271	1.47
444.5246582	0.52
445.5303955	0.62
447.4609375	0.43
449.6060791	0.88
450.2233887	1.01
453.8038940	2.03
454.4376831	9.36
455.4685669	2.31
456.8775635	0.48
457.5690308	1.64
459.6582031	0.79
460.4385376	2.95
461.2061157	1.61
462.1485596	1.11
463.4423218	8.61
465.2744751	0.53
466.4059448	1.27
468.7716064	1.17
470.0979004	0.44
473.3532715	0.96
474.3596802	2.59
475.3025513	0.69
476.5114746	0.83
477.2438965	0.58
480.5723267	1.29
481.5886841	1.80
484.5238647	0.37
488.5897827	1.69
489.2383423	0.46
490.3064575	7.37
492.2812500	5.08
493.4584961	0.65
494.5570679	1.73
496.7269897	0.75
497.4295044	0.50
498.2753296	0.97
499.3136597	0.23
502.3851318	7.03
503.6579590	2.32
505.5704956	1.86
507.3832397	35.22
508.2315063	12.89
508.8735962	0.60
511.0543823	0.23
511.7324829	1.43
514.6773071	1.35
517.5190430	0.62
520.2984619	100.00
521.2496948	0.94
525.3200684	1.81
526.4738159	0.76
528.1582031	0.45
531.5183716	0.75
532.3875122	2.02
533.5108643	1.10
539.3280640	0.30
541.2745972	1.45
542.4944458	0.16
545.2219238	0.28
546.4899292	0.34
549.1643066	2.38
551.6377563	1.40
553.7549438	1.34
557.4214478	2.31
561.7146606	0.88
563.4851074	2.80
564.4188232	6.61
567.3365479	8.54
572.1883545	2.03
581.2640991	25.05
582.4323120	45.51
583.3106079	5.73
585.2501831	6.41
599.4834595	3.33
600.5020142	1.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2779
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.9373169	0.11
153.0240326	0.05
196.0319824	1.72
214.0413971	0.99
255.1838074	100.00
256.0098877	0.01
391.3629456	0.43
409.0944519	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	863.7
Annotation	Unknow
Peak:m/z	Relative Intensity
250.8804932	0.10
255.0879517	0.13
283.0534363	4.35
283.8731079	0.08
291.3586731	0.12
309.3892212	0.21
311.0169067	14.49
311.6924438	0.16
323.0534363	0.63
341.1665039	1.97
352.7887878	0.11
355.1463013	0.09
365.2398376	0.09
424.1657104	0.19
431.1907349	100.00
517.1921387	0.18
527.2265015	0.68
553.0280762	0.11
585.2693481	0.17
589.3501587	0.06
592.9953613	0.21
612.3203735	0.23
725.3068237	0.23
742.0762329	0.26
743.3005981	1.10
744.2581177	0.97
755.1878052	0.17
770.2388306	0.09
771.3129883	0.09
772.7445679	0.16
777.4331665	0.17
786.2206421	0.30
803.5350342	0.34
805.9673462	0.15
845.1928711	0.87
846.0914307	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1826
Annotation	Lactulose
Peak:m/z	Relative Intensity
281.1873474	0.12
290.5525208	0.11
305.4146118	0.08
359.0429688	0.04
362.3183594	2.14
363.0701294	4.83
381.0914307	10.71
381.8074951	0.32
452.7011719	0.11
483.1082764	0.09
525.1420288	25.30
526.2281494	0.06
533.2414551	6.97
534.2268677	1.11
543.1460571	100.00
544.1536255	0.44
585.3755493	0.05
615.1890869	0.63
645.2412720	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	415.1015
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
120.9517975	0.24
162.8924713	0.15
165.0791931	0.23
173.2183533	0.06
175.0152740	0.14
187.1447449	0.30
189.0928650	0.15
191.1034546	0.12
193.2220154	0.25
202.8216400	0.15
203.9199677	0.14
204.8629456	0.20
207.2779236	0.36
216.9623718	0.20
218.9972534	0.11
224.9843140	0.07
231.0665894	0.12
232.9455872	0.19
234.9897461	1.14
243.3464966	0.14
249.2332764	0.19
252.5368042	0.61
253.1993103	2.09
261.0425110	0.94
270.0574646	0.09
271.0814209	1.43
272.7957153	0.06
279.1057129	6.07
283.1101379	17.67
284.1237793	0.51
285.2156982	0.26
286.1937866	0.04
289.0830688	0.34
295.0313110	100.00
296.4209595	2.18
297.2607422	1.10
302.1824951	0.08
306.9339905	1.56
309.0293884	0.51
311.1221924	3.18
313.1111450	3.96
315.1947937	0.05
320.7830505	0.15
321.5563049	0.09
323.1394653	1.15
325.1114502	3.20
326.1655579	0.17
327.0627136	0.71
329.1791382	0.15
333.1007080	0.11
335.2485962	0.21
337.0708008	91.42
338.0286255	0.64
339.0261536	0.24
340.9820557	0.27
342.0003662	0.21
345.0343018	0.08
349.1862793	3.77
351.3053894	1.18
355.1653748	10.22
356.1155701	0.33
357.2479858	0.26
361.0901794	1.27
367.0979919	60.47
368.1766968	0.40
368.8999939	0.35
371.2830200	0.11
379.0929871	22.83
380.1521912	0.18
382.9754028	0.11
385.2465515	1.71
387.4413757	0.40
396.0056458	0.54
397.1006775	83.37
398.2767639	0.33
400.7062988	0.26
405.5523682	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5066
Annotation	L-alpha-Phosphatidylethanolamine (Soy)
Peak:m/z	Relative Intensity
214.1783905	0.28
228.2875824	1.06
247.9726562	0.30
255.240448	51.26
256.3332825	3.10
276.1932983	0.72
279.2288208	100.00
280.2136841	20.41
287.3375854	0.17
289.2216492	0.17
293.3853455	0.92
297.0750122	0.41
345.3885803	0.19
362.2659912	0.84
391.5007324	0.40
409.1456909	0.30
413.3518677	0.28
415.3070679	0.21
426.2694702	0.54
434.3104858	1.26
438.4719849	0.26
452.2990723	18.81
453.227356	5.39
458.3307495	0.46
459.3434448	0.59
461.0515137	0.23
476.2140503	2.00
489.4188232	0.18
535.246521	0.57
553.6387329	0.56
555.4772339	0.24
567.4979858	0.21
570.102356	0.34
571.5093384	0.17
580.6260376	0.61
583.5197144	0.84
610.5384521	0.92
617.4790039	0.39
643.7238159	0.30
655.5532227	1.37
667.7387695	0.22
669.2820435	2.24
671.6195679	0.75
672.4537964	0.25
676.9445801	0.43
679.0717163	0.31
679.8722534	0.49
685.4439087	0.62
697.4226685	6.99
698.2559204	1.53
705.8928223	1.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.2227
Annotation	13(S)-HpODE
Peak:m/z	Relative Intensity
97.27878571	0.12
101.0284119	0.14
109.1278381	0.03
120.976181	0.09
138.9034424	0.04
149.0635376	0.06
151.1279755	0.15
153.0739746	0.17
155.0497284	0.04
157.1882629	0.08
161.1766968	0.11
165.0154419	0.21
168.7305298	0.16
171.0049744	2.22
177.00354	0.26
180.9790955	0.28
183.210022	0.57
183.9152832	0.03
184.9980164	0.09
191.0666504	0.36
195.2471161	0.09
197.2401428	0.16
199.1114349	0.60
200.0516663	0.09
201.1586456	11.06
203.1711426	0.12
205.1030579	0.26
207.2685242	0.24
209.1437378	0.89
213.1517944	0.12
217.0937195	0.36
219.4629822	0.42
221.1808472	0.33
223.1233215	81.03
224.2099915	0.10
225.0678101	0.38
229.5144043	0.21
231.3474426	3.08
233.2044983	0.51
235.1578369	26.03
236.2678223	0.13
237.198761	1.41
239.1322327	0.31
247.5600891	0.56
249.1548462	0.98
251.3355103	0.26
253.222168	9.10
255.2984314	0.03
257.0782166	0.65
263.3900757	0.21
265.1197815	0.73
266.0643921	0.06
267.1646729	0.11
271.0083008	0.06
273.2473755	1.06
275.19104	36.97
281.4820862	0.14
282.1184082	0.15
283.1150208	2.36
284.098114	0.63
291.2174988	3.68
293.2086792	100.00
294.2325439	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.4836
Annotation	Acankoreoside E
Peak:m/z	Relative Intensity
323.1480713	0.50
324.3624268	0.20
325.2260132	0.07
351.4122009	0.03
352.3204956	0.05
355.6057129	0.02
423.3955078	8.49
424.3754578	14.09
425.3917847	2.57
467.5869751	0.15
469.3098755	0.02
486.4158325	0.04
496.5219727	0.03
503.2712402	0.08
508.7738037	0.02
556.2915039	0.05
601.8847046	0.04
615.5462036	0.17
627.2156372	0.02
647.4075317	37.15
648.3933716	100.00
649.4376831	32.39
650.5321655	0.23
690.2257690	2.22
691.3705444	0.64
720.3131714	0.05
720.9439087	0.11
731.0792236	0.06
731.8352051	0.08
732.4895630	0.20
747.3363647	0.91
748.2510376	2.40
749.2104492	1.04
756.3311157	0.03
778.4273682	0.13
793.5665283	0.06
795.1660767	0.15
796.2351685	0.09
805.0806274	0.05
810.1779175	0.05
811.1821289	0.25
819.3268433	0.04
852.4489136	0.06
853.2880249	0.12
858.9425049	0.03
882.1242065	0.07
882.9215698	0.05
912.2631226	0.16
913.5150757	0.18
925.3397217	0.05
936.0120239	0.03
943.3830566	0.04
952.6453247	0.02
954.2653198	0.33
955.5794067	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.1122
Annotation	Herbacetin 8-(2'',3''-diacetylxyloside)
Peak:m/z	Relative Intensity
151.1678009	0.04
159.9073334	0.06
168.6926880	0.11
198.7833405	0.11
201.7124023	0.03
210.0049591	0.09
217.2049103	0.03
219.1557922	0.07
221.0109711	0.03
236.0859375	0.05
243.0250549	0.09
244.2713623	0.06
271.1056824	0.57
274.2740479	0.03
282.9926147	0.48
295.0729980	2.29
295.6894531	0.06
303.3532104	0.15
309.3471680	0.10
311.1514893	0.13
313.1538696	34.08
318.2457886	0.05
321.2473145	0.11
322.2670288	0.03
324.1029663	0.08
324.8092041	0.04
327.2092285	0.21
329.4226685	0.06
333.2155151	0.18
335.2421265	0.06
337.0960083	13.83
341.1200562	0.04
343.1882324	0.05
348.9669800	0.18
353.0178223	0.13
354.1903076	0.17
355.2185669	0.04
357.2801514	0.23
358.3408813	0.05
361.1788330	0.21
362.8801880	0.10
365.2277222	0.07
365.9888916	0.21
367.0134277	1.01
369.0809937	0.17
371.0610352	0.73
371.9531860	0.06
377.0943604	0.19
379.1048584	8.95
380.3322754	0.06
387.3838501	0.02
392.9033203	0.03
395.2976074	0.26
397.2153931	1.98
398.3934937	0.24
403.0479126	0.07
409.3284302	0.21
415.1477661	5.26
417.7060547	0.15
421.1135254	0.22
423.0115967	0.12
425.1589966	0.14
428.8890991	0.24
433.1140747	3.65
433.9833374	0.02
435.1646729	0.20
437.6771851	0.05
439.1865234	1.59
440.3482666	0.23
440.9975586	0.05
449.2649536	0.15
451.1515503	0.06
453.1056519	0.38
455.1696167	0.04
457.0851440	2.87
458.7619019	0.14
462.7929077	0.11
465.1475220	0.39
469.3350220	0.07
471.9668579	0.12
473.2138062	0.28
475.1349487	1.32
481.4758911	0.08
483.1538086	43.00
484.3970947	0.10
487.8352661	0.10
489.1868896	0.36
501.0792847	100.00
501.7608032	0.21
502.5285034	0.05
504.1789551	0.04
509.4072266	0.37
510.2509766	0.44
512.2855225	0.02
520.2325439	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	442.2443
Annotation	Unknow
Peak:m/z	Relative Intensity
132.0507660	0.15
135.0881500	0.04
151.2168884	0.02
154.1730042	0.06
161.3715210	0.08
168.3057709	0.07
177.9527893	0.02
182.0939941	0.22
183.2938538	0.12
184.4667664	0.13
192.3081970	0.05
194.1591797	0.30
195.1198120	0.16
198.0046692	0.09
199.0874329	0.06
210.1653137	1.20
211.2035522	0.40
212.1615906	0.02
213.2946472	0.09
217.1947021	0.13
218.1678772	0.02
220.1258698	0.03
226.1902161	0.07
228.2045288	0.40
238.1585388	0.29
239.1641541	0.05
242.1555176	0.03
250.3630676	0.30
251.4231873	0.02
254.4040833	0.05
267.2577209	0.04
268.0361023	0.53
269.1416626	0.05
272.2955627	0.07
273.2185669	0.11
282.3581238	0.31
284.2790527	0.18
290.2520752	10.13
291.2832031	0.44
292.9083252	0.03
298.0820923	0.07
306.2654724	0.08
308.2433167	2.32
309.3420105	0.51
311.9981079	0.02
323.2434082	0.03
326.1818237	12.34
327.1690063	100.00
327.7733154	0.50
345.8850098	0.07
357.2619934	0.02
380.1386719	0.13
382.2399902	0.02
396.3125610	0.17
398.3482666	9.32
400.5752258	0.03
404.2185364	0.04
405.9212341	0.55
406.5639343	0.05
409.4048157	0.08
423.1730042	0.03
424.2784119	5.56
428.0966797	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1065.494
Annotation	Unknow
Peak:m/z	Relative Intensity
306.9413757	0.17
322.9022522	0.36
340.9436340	1.71
365.2034607	0.24
367.0055847	0.24
383.1720581	3.92
393.2233276	0.48
395.1474304	0.13
397.2962952	0.19
399.3169556	0.18
412.8521118	0.07
421.1702271	0.32
424.8408203	0.60
425.6409302	0.37
439.1150818	0.20
442.9899902	0.85
449.2472229	1.42
451.2181396	0.13
453.2886963	0.22
455.1026001	0.15
464.9217529	0.34
467.2139282	0.75
483.1881714	8.39
485.0918884	2.12
503.0135193	1.63
509.3497925	0.37
527.0900879	2.53
543.4822998	0.06
545.2586670	5.34
559.1697998	1.75
569.2304688	0.40
574.1311035	0.29
578.7118530	0.36
579.3793945	0.20
587.1953735	2.03
604.9187012	0.76
611.2589111	0.38
613.3952637	0.35
617.3416748	0.36
621.1507568	1.55
629.2695312	2.69
641.6961670	0.12
646.7117920	0.79
647.4049072	1.00
658.7294922	0.48
659.5926514	0.23
665.2010498	1.36
670.8059692	0.06
680.8579102	0.36
689.2474976	1.21
702.4638672	0.07
707.4180908	0.31
723.4749146	0.08
729.1303711	0.36
740.9520264	0.32
757.2702637	0.24
761.1397705	0.07
783.2761230	6.01
790.8930664	0.25
807.4328613	0.06
809.2109375	100.00
809.9307861	0.30
813.4194336	0.08
822.4560547	0.16
825.5007324	0.15
827.3087158	36.42
836.9262695	0.10
837.5808105	0.14
851.6188965	0.39
868.5129395	0.29
885.3745117	0.32
912.1633301	0.25
928.2703857	0.48
935.2891846	0.55
944.2178955	0.54
945.1920166	1.58
965.0725098	0.18
971.0422363	0.27
974.4653320	0.07
975.2849121	0.11
1002.2773440	0.12
1003.4338380	1.52
1004.1923830	0.08
1006.1979980	0.39
1035.2241210	0.08
1046.5957030	0.13
1047.4211430	1.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	397.091
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
152.8929901	0.32
235.2270813	0.10
261.3459778	0.08
271.1060791	2.48
283.0578613	56.95
283.9033203	0.44
285.2738647	0.06
295.1461182	1.35
296.1836853	0.32
297.0272827	0.89
298.8991699	0.10
301.0782471	0.07
307.0917358	0.94
309.1606750	6.45
310.2108154	0.05
311.1452637	3.68
312.0413513	0.03
313.1670532	0.50
321.1687012	0.19
323.1570129	2.25
324.4475708	0.40
325.1726990	0.58
331.0156860	0.11
333.0273132	1.37
335.1001892	0.88
337.0373535	13.20
337.6783752	0.07
341.0942993	1.51
349.0609436	81.96
351.1370544	9.22
353.1301270	1.07
361.1813660	11.19
367.1424255	66.58
369.2788391	0.88
379.1625061	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	794.2568
Annotation	Unknow
Peak:m/z	Relative Intensity
280.6900024	0.04
341.0191650	0.66
383.1275024	0.49
412.7871094	0.07
443.0236816	0.54
467.2964478	0.05
470.3902588	0.06
471.3950195	0.10
485.2299805	0.48
503.0449829	1.28
544.8760986	0.04
576.1209106	0.03
605.3571777	0.02
632.0914917	0.19
646.7926636	0.03
656.8759155	0.01
665.2258911	100.00
665.8417358	0.37
670.0858765	0.07
689.5531006	0.10
762.1572266	0.03
776.1423950	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2133
Annotation	Briaexcavatin S
Peak:m/z	Relative Intensity
159.9648590	0.06
175.2826691	0.25
176.0961304	0.23
184.0332031	0.11
185.1554871	0.07
186.9992676	0.13
188.1709290	0.13
199.1844025	0.14
220.5589600	0.04
222.6383972	0.03
230.3655701	0.09
231.1801605	0.10
245.1396179	0.09
253.1558228	0.12
258.9726868	0.03
263.0687256	0.08
267.0624390	0.11
271.1394043	1.29
285.1820679	0.32
289.3125610	0.80
295.9630737	0.07
301.3293457	0.27
305.2128906	0.18
313.2452393	0.58
315.1384888	4.47
321.0731201	0.04
323.0565796	0.05
329.2219849	1.72
331.3207397	0.15
333.1443481	10.71
333.7636108	0.09
334.3845215	0.43
341.2355957	0.07
347.1791382	0.36
349.1641846	0.07
357.0862427	0.22
359.1570435	100.00
360.2150269	0.54
366.3192749	0.24
373.2313843	18.33
374.2265015	1.29
375.2671509	5.43
377.1141968	7.70
377.7534180	0.03
381.2338867	0.10
386.2153320	0.52
387.3857422	0.09
394.0408325	0.03
401.1704712	7.93
404.4025269	0.20
405.1921387	0.04
406.1968384	0.06
407.0076904	0.10
417.1786499	0.11
419.2089844	6.08
419.9219360	0.02
421.1842041	0.11
425.1305542	0.06
431.1246338	0.03
435.1154785	0.12
439.2602539	0.05
441.3951416	0.08
443.0895996	0.36
449.1633301	0.20
450.1470337	0.07
458.1713257	0.06
459.3789062	0.07
461.2532959	0.26
462.1449585	0.08
463.4143677	0.05
465.3681641	0.24
467.2100220	0.07
476.2279663	0.16
477.1620483	0.09
478.0953979	0.18
479.2111206	1.08
480.0566406	0.03
487.0856934	0.04
492.3198242	0.20
493.0930786	0.82
495.2813110	0.96
495.9620361	0.21
502.1651001	0.08
503.2297974	0.20
504.2157593	0.05
506.1766968	0.54
507.1979370	0.22
508.2116699	0.04
510.8298340	0.47
512.1166992	0.22
520.5196533	0.65
521.3439941	1.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.3751
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
203.0748444	0.06
217.0794373	0.03
219.0482635	0.17
221.0259094	0.50
226.9988403	0.19
229.0133667	0.04
235.0393372	4.92
236.8695526	0.22
245.1599731	0.25
253.2204285	0.90
258.8953552	0.15
263.0538330	0.15
271.6232605	0.12
275.0841370	0.04
277.0595398	0.34
279.2548218	4.66
283.4686890	0.09
287.0588684	3.22
290.9586182	0.09
293.2539673	0.02
294.9810791	0.09
296.4336243	0.25
303.1773682	0.29
305.0497131	5.99
307.0823364	0.21
308.0532837	0.09
319.1959839	0.03
323.1394043	1.63
323.8031006	0.05
343.0833740	0.08
344.9737244	0.04
347.1563721	0.06
361.1896973	0.06
369.0184937	0.18
379.1336670	0.76
397.1356201	100.00
399.1511230	1.04
407.1470947	0.06
415.2272949	31.15
416.9810791	1.77
423.2827759	0.05
429.1170044	0.07
446.8701782	0.14
464.2216797	0.06
480.6899414	0.11
483.2907104	0.05
505.3596191	0.15
537.2320557	0.10
539.2308960	0.16
551.8573608	0.08
587.4791260	0.03
589.4918823	0.13
593.3521729	0.56
595.2484131	0.20
601.9076538	0.14
612.9442139	0.47
616.9729614	0.32
618.1373901	0.25
626.7982178	0.19
630.5177612	0.33
631.2617798	0.87
644.1585083	0.09
646.5702515	0.10
657.3715210	0.09
658.6293335	0.36
659.5300293	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.0771
Annotation	Dianthoside
Peak:m/z	Relative Intensity
94.8198090	0.25
98.8212051	0.30
101.0458374	0.04
122.9034882	0.62
124.9858932	12.97
125.6401062	0.03
133.9295654	0.09
136.9162292	1.73
142.7510529	0.13
147.0811462	0.30
153.0874023	0.69
164.9023132	0.50
167.0066833	100.00
175.2966766	0.18
178.9866638	1.67
180.8028870	0.08
183.1286316	0.09
185.0971680	0.10
190.8927917	0.11
192.9770050	2.00
196.9930420	91.65
201.2406311	0.29
203.0775757	0.08
205.0390320	0.12
207.0558472	0.24
208.9552612	1.61
211.0104370	0.33
226.9503174	5.75
233.1264648	0.46
239.1109009	0.43
243.2180176	1.89
251.0561523	2.25
256.9644470	0.78
259.1179810	2.37
269.0899963	9.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	952.132
Annotation	1,4-Dihydroxy-2-naphthoyl-CoA
Peak:m/z	Relative Intensity
283.7973022	0.17
298.0829163	0.40
298.8349915	0.09
308.8819580	0.05
309.9102173	0.05
315.8994751	0.14
325.9626770	0.11
336.9260254	0.13
337.8843384	0.06
354.6173096	0.13
355.4153748	0.31
356.0731812	0.33
359.8950500	0.09
370.3244019	0.07
381.2541504	0.08
382.0465088	0.14
383.0095520	0.91
384.1785278	0.11
388.1742554	0.09
394.0554810	0.09
396.1838074	0.04
400.3809204	0.07
411.9841919	1.70
413.2340698	0.18
413.9117737	0.08
423.8150024	0.11
425.8399658	0.06
441.9841309	5.64
454.0466309	0.38
472.1818237	0.44
478.6742554	0.11
484.0309448	0.66
486.3555908	0.21
500.0601807	0.07
502.0007935	12.55
514.4030151	0.12
530.5076294	0.05
543.7365112	0.14
561.9429932	1.52
576.1054688	0.10
592.1475830	0.42
610.5551758	0.11
621.0894165	0.05
621.8579712	0.18
635.2786255	0.14
643.2710571	0.04
653.5827637	0.02
670.1624146	0.21
682.4885254	0.05
694.1072388	4.43
695.9089355	0.14
700.0242310	0.34
710.1360474	0.55
712.0331421	38.01
712.6781616	0.13
717.9432983	0.05
724.0559082	1.05
736.3881226	0.10
741.4280396	1.30
742.1679077	12.50
743.0448608	0.15
747.7710571	0.26
754.0688477	0.27
762.3159790	0.03
765.9228516	0.15
772.0300903	1.50
776.2530518	0.25
786.0657349	0.05
789.9682617	0.97
796.2467651	0.15
801.2575073	0.10
806.3493652	0.15
811.9518433	0.04
812.9227905	0.58
814.0703735	11.21
816.1765747	0.14
829.9979858	0.14
832.0313110	100.00
843.9888916	1.26
856.2239990	0.06
860.3515625	0.10
861.9668579	14.30
862.5964355	0.08
871.4758911	0.04
874.3154297	0.22
880.2715454	0.22
886.0552979	0.43
894.5746460	0.17
905.0447388	0.06
908.1653442	0.04
916.1120605	0.46
930.4080200	0.10
933.9191895	3.04
934.6755981	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.16
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
187.8137817	0.34
189.0729980	0.80
200.1271667	0.06
203.1498260	0.04
205.0739441	1.93
205.9908142	1.45
223.1295166	0.13
234.1138458	0.11
248.7718658	0.23
261.1482544	0.36
264.2117310	0.08
271.0666504	0.40
274.9766846	0.13
283.1182251	0.50
287.4711914	0.07
288.7014160	0.12
291.1121826	0.11
294.9104614	1.05
311.2369385	0.24
313.0465088	3.02
320.1549683	0.33
337.1815796	0.48
346.4087524	0.39
351.4763184	0.05
353.7498169	0.78
355.6350708	0.28
357.0578613	0.07
367.0867310	1.33
383.2149048	0.07
389.3200684	0.39
392.9350586	0.36
396.1620483	0.24
397.2340088	2.12
403.2960815	0.89
405.1857300	0.13
409.1652222	1.45
415.1956177	10.45
421.1178589	0.15
423.2927246	0.60
425.2171021	0.10
427.0743408	0.14
428.1729126	0.26
430.9914551	0.26
432.4522095	3.76
433.0955811	35.36
437.3316650	0.20
439.2994385	0.86
441.4346313	0.10
444.0824585	0.20
445.2403564	0.27
447.7763672	0.20
449.0987549	0.41
451.3143921	0.24
457.1780396	22.07
463.3585815	0.05
464.1393433	0.22
465.1011353	0.23
466.1262207	0.51
468.1680908	0.28
475.2108154	9.70
476.9952393	0.09
479.2167969	0.28
480.3214722	0.35
481.2625122	3.35
482.4270630	0.35
499.2293091	4.35
505.1428833	0.63
505.8359985	0.36
511.1183472	9.35
514.2639771	1.49
515.2991943	0.18
523.1799927	2.46
524.8171997	0.37
529.1304932	15.87
532.2534790	0.24
534.6106567	0.20
535.7014771	0.04
541.1229858	4.83
547.6344604	0.32
548.8334351	0.96
549.7143555	0.19
551.3047485	0.09
553.4961548	0.25
559.1067505	25.49
559.7479858	0.54
563.1944580	0.37
565.1080322	0.84
571.2318726	0.06
577.0830688	100.00
577.7521362	0.12
595.3023682	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2137
Annotation	Lactulose
Peak:m/z	Relative Intensity
202.8696289	0.31
210.9166718	0.40
220.9029999	5.55
247.5533447	0.10
250.8359680	0.84
262.9350586	0.17
280.1714478	0.44
280.8757935	2.04
293.0512695	0.17
305.1435547	2.25
317.1046143	0.13
323.0149231	58.99
323.6200562	0.95
328.8673096	0.19
340.9786377	31.33
341.5902100	0.17
347.4185791	0.29
383.1400146	100.00
406.9899292	0.32
410.1476440	0.26
411.2017822	0.18
412.8888550	1.31
425.1085205	0.98
440.7346802	0.09
442.7814331	19.85
443.5966797	0.15
449.4219360	0.39
459.9101562	0.22
467.0855713	0.90
472.9781494	1.28
485.1426392	36.71
502.9522705	7.08
504.0629272	0.34
527.5365601	0.13
528.4249878	0.63
541.3499146	0.21
545.0977173	1.19
547.9946899	0.09
620.9868774	0.22
647.2942505	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
125.1530228	0.03
178.9078522	0.05
246.8144226	0.03
264.3946533	0.01
269.0498962	0.11
283.0276489	0.15
293.068512	0.02
311.0568848	100.00
312.0268555	0.15
322.4154358	0.11
323.1458435	0.70
325.20224	0.03
327.2912903	0.09
337.082428	0.21
341.180603	13.18
349.1547852	0.14
351.167572	0.07
353.1070862	0.82
355.1598511	0.23
365.1997375	0.01
367.0291443	0.06
371.1256714	0.30
377.0219421	0.12
382.9810486	0.35
395.0393066	0.26
413.1054382	2.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1336
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
95.98923492	0.03
97.24179077	0.02
105.8544159	0.06
107.9162827	2.32
110.5293198	0.04
121.9070663	0.01
122.9981384	0.01
123.9499664	0.14
133.9279785	0.76
135.9466553	1.88
139.928894	0.01
151.9911194	6.31
154.1846466	0.13
164.0732422	0.02
170.0383606	8.80
174.9443054	0.01
178.7961578	0.01
183.9332581	0.01
193.9429474	0.03
200.9827728	0.10
202.0517426	0.03
209.1481628	0.05
217.7579346	0.01
219.9766235	0.04
221.1183472	0.05
229.8424683	0.02
236.0049438	0.07
243.7715149	0.04
247.7086792	0.02
249.9754028	0.07
251.1740723	0.12
263.9768982	0.01
268.1253967	0.02
278.1329041	0.05
285.8188171	0.02
287.2052612	0.02
288.138916	0.03
289.9454041	0.01
296.1951904	0.17
299.3662109	0.02
309.4946899	0.07
312.3387756	0.03
314.1219177	100.00
316.9881897	0.01
322.985199	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1089.4922
Annotation	Unknow
Peak:m/z	Relative Intensity
323.0278625	0.09
340.9692383	0.61
341.8285522	0.08
365.0982361	0.48
379.3499756	0.15
380.3292847	0.07
383.1512756	2.56
384.1485291	0.12
389.8500366	0.02
397.0775452	0.11
412.2533569	0.02
412.9295349	0.14
423.0746460	0.27
424.9839478	0.13
431.1948242	0.05
439.3140869	0.05
441.2948608	0.39
442.3267212	0.09
442.9794922	1.47
443.8547363	0.18
449.1829834	0.83
450.3533325	0.07
465.1441956	0.05
467.1337585	1.01
468.1616516	0.07
483.1235962	0.10
485.1078796	1.44
486.3536987	0.03
502.9928894	1.06
503.8862915	0.08
527.1683350	4.07
528.2747803	0.38
540.5062256	0.10
545.1868896	6.95
546.1722412	0.86
557.5121460	0.10
559.1776123	1.68
560.2685547	0.35
569.5323486	0.09
572.4075317	0.07
587.1269531	2.24
588.0126953	0.04
598.9342041	0.02
603.1121216	0.12
604.4904785	0.16
605.1174316	0.46
605.9696655	0.03
611.1537476	0.88
627.5019531	0.08
629.0541382	0.98
630.2302246	0.12
640.8543701	0.03
645.1253662	0.54
647.1121216	0.85
648.2402344	0.13
653.2449951	0.10
658.3505249	0.04
665.1659546	0.37
671.2183838	0.31
689.1081543	1.01
690.0249634	0.18
692.9975586	0.03
705.0589600	0.37
705.8551636	0.05
708.2415771	0.06
713.2164917	0.04
736.2784424	0.03
746.8659668	0.19
764.9107666	0.33
766.3718262	0.12
791.2764893	0.18
807.2000732	4.69
809.1669922	100.00
810.2875977	19.33
811.1879883	0.04
827.2017822	31.73
828.1931152	5.43
828.8461914	0.02
848.9613037	0.10
850.6240234	0.06
874.7727051	0.04
910.1352539	0.04
926.7888184	0.14
927.4991455	0.06
1027.2580570	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.2291
Annotation	Unknow
Peak:m/z	Relative Intensity
186.0454102	0.05
205.0803070	0.08
207.1942596	0.32
223.0946045	0.25
231.0448151	0.16
245.3082581	0.07
249.0962830	7.44
267.0870667	13.79
285.1656494	0.32
297.2200928	1.74
323.3430786	0.10
329.1160889	0.09
348.5662231	0.27
374.0781860	0.26
403.3619995	0.15
411.1254272	2.04
411.7555542	0.01
429.2676392	34.10
430.3188477	0.33
431.3095093	0.15
449.2421875	0.07
455.2207031	4.75
455.8272705	0.13
459.3225098	0.05
471.3037720	0.23
473.1724243	100.00
474.5557861	0.29
477.2376709	0.13
483.1912231	0.04
491.2384644	7.12
515.1268921	0.14
533.1624146	0.38
555.0109253	0.04
557.3521729	0.10
562.2908325	0.03
563.1232300	0.24
575.3856812	0.08
577.1580200	0.13
591.3255005	0.05
593.3021851	0.16
594.6635132	0.05
600.6076660	0.07
606.5701294	0.12
607.2157593	0.32
608.0473633	0.16
609.2316284	0.53
609.9357300	0.21
617.0764771	0.38
633.2047729	0.03
635.1781616	4.51
635.8547974	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1039.6705
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
337.1860046	0.28
355.2361145	0.07
443.4353027	0.79
496.7215271	0.07
498.5487671	0.03
501.2649536	0.10
502.3441467	37.36
503.0264282	0.08
520.3515015	100.00
520.9763794	0.60
534.3100586	7.52
535.0068970	0.02
604.6840820	0.35
605.4284668	0.40
623.2160645	8.55
644.3481445	0.15
672.2006226	0.12
703.4320068	0.32
813.3348389	0.02
831.2729492	0.18
856.4626465	0.07
897.9951172	0.13
903.3564453	0.25
926.6978760	0.05
951.7255859	0.13
953.9620361	0.08
980.6892090	1.59
1021.2746580	1.44
1038.7910160	0.30
1039.7239990	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1067.5439
Annotation	Soyasaponin bg
Peak:m/z	Relative Intensity
307.0918274	0.56
377.2398682	1.02
394.3256531	2.75
395.1784668	0.63
407.5740051	1.31
409.4457397	0.77
420.9739990	0.89
422.0871277	2.10
425.2768250	3.41
437.8412170	3.15
447.1642456	1.88
457.4943237	14.44
458.3262329	1.34
465.4580688	2.41
466.0754089	0.68
483.2795410	7.20
485.2857056	2.20
499.7608643	1.06
518.2413330	0.57
527.4400635	1.15
535.5397339	0.46
536.4593506	1.07
551.4858398	0.74
552.4293213	0.92
553.2175293	0.81
563.4422607	7.94
580.5427246	1.71
581.7445068	0.68
583.4382935	19.86
584.3477783	2.46
615.1686401	2.17
619.4099121	2.60
623.3885498	2.87
642.5468750	1.60
651.4384155	51.39
652.3960571	24.38
653.5834351	2.50
661.4227905	1.03
667.2142334	1.22
679.5252686	2.52
680.7153320	0.70
697.4589233	13.90
698.4437866	5.02
707.3231812	2.00
723.3823242	17.48
724.4494629	3.32
733.4611816	46.27
734.5233154	19.64
741.2971802	42.90
742.4830322	24.24
751.5594482	5.45
752.3970947	4.37
759.5476074	4.12
760.4915771	1.64
807.3894043	0.50
817.0026855	1.58
818.0758057	1.96
859.4392090	4.25
878.1363525	3.94
879.3889160	83.23
880.4454346	37.20
885.0729980	4.11
897.5766602	1.37
898.2263184	2.13
903.5239258	7.23
904.7739258	2.35
921.5629883	26.56
922.4372559	10.30
941.6157227	21.00
942.6076660	4.12
949.7153320	1.09
950.4633789	2.22
967.5358887	85.43
968.5261230	49.99
1005.2469480	9.49
1006.2607420	2.62
1007.8468020	0.74
1025.2426760	3.07
1026.6433110	3.23
1031.5723880	4.13
1049.3610840	100.00
1050.4914550	36.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.3
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
94.9105377	0.31
97.0213776	0.22
105.0085754	0.02
106.0861206	0.04
108.9107666	0.24
110.9176712	0.16
121.0471344	0.08
122.8649521	0.27
125.0033493	0.08
132.9036713	0.03
135.2378845	0.09
137.1149292	0.19
147.2603760	0.03
149.1446228	0.13
151.1315002	0.09
153.3717346	0.06
154.7363586	0.05
163.0079651	0.09
165.0180969	0.09
168.9479980	0.07
175.7621460	0.03
177.1114807	0.03
183.1512756	0.11
185.9338531	0.05
201.1336365	0.06
210.9140930	0.22
221.2290649	0.38
223.3144226	0.06
225.2654114	0.13
226.2072754	0.06
229.9700012	0.02
233.4246521	0.04
235.2659607	0.28
237.9976196	0.13
239.1209717	0.14
240.4676514	0.02
241.3369751	0.05
245.1060486	0.02
247.0608826	0.52
252.2747192	0.61
253.3117676	0.34
254.4259644	0.05
256.0885010	0.28
256.7139893	0.04
260.0777893	0.05
262.0616150	0.22
264.5275269	1.37
265.3109741	3.13
268.9782410	0.13
270.3039551	1.84
271.1466980	0.15
272.3023071	0.17
277.0856018	0.09
282.2301636	41.03
283.2682495	0.26
286.9278259	0.10
294.8309937	0.13
300.2370605	100.00
301.1407776	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	921.14
Annotation	Unknow
Peak:m/z	Relative Intensity
277.0309448	0.08
293.1819763	0.08
295.0297546	0.33
308.9382935	0.05
323.7141724	0.19
325.2930298	0.12
336.2042847	0.45
340.3838501	1.15
341.2003174	0.38
352.2599792	0.42
356.0231018	0.09
356.9584045	0.24
364.0373230	0.17
367.0465088	0.33
368.2408447	0.30
368.9823608	0.12
381.9490356	0.10
383.1635742	0.21
396.2714233	0.14
397.9410400	0.59
399.1145020	0.87
410.9828491	0.45
426.7942505	0.24
428.1174316	0.26
429.0982056	0.64
434.4468994	0.53
435.2612305	1.25
442.3235474	0.23
450.8316040	0.63
452.9848633	0.28
463.0790405	0.54
469.0011597	0.91
470.0791626	1.16
471.0296631	5.24
486.4180908	0.67
487.3124390	0.42
488.0650024	1.73
489.0578003	2.88
493.7294312	0.19
529.7264404	0.25
531.1542358	0.43
541.9290161	0.26
546.8474121	0.17
548.1939697	0.69
548.8033447	0.84
558.0330811	0.08
558.7335815	0.43
596.1344604	0.49
597.5549316	0.32
609.2367554	0.07
615.3622437	0.07
636.4824829	0.20
638.2611694	1.11
639.2482300	0.61
650.9761963	6.26
661.1369019	0.10
663.2708130	0.80
668.2459106	0.25
675.1130981	0.07
678.1076050	1.63
679.1278076	4.68
680.1414185	12.94
681.1348267	24.35
685.1076050	0.42
687.2458496	0.82
689.0722046	0.16
694.0438843	0.24
699.1755371	0.12
703.3220215	1.21
704.0923462	1.87
705.0861816	10.80
705.6926880	0.11
708.1060181	0.35
708.9711914	0.71
710.1455078	3.03
711.1754150	2.04
716.1736450	0.88
717.1017456	2.59
722.1155396	0.15
723.1884766	0.44
727.1036987	0.32
728.2053833	1.01
729.1568604	3.04
732.9664307	0.59
734.5993042	3.40
735.2188110	4.59
739.1868286	0.43
740.0971680	0.55
741.1358643	0.21
744.9378052	0.13
746.1293335	2.95
747.0408325	9.44
751.8915405	0.09
753.3478394	1.40
757.0380249	0.39
758.0646362	0.60
758.7924805	0.30
761.7367554	0.16
763.1086426	0.06
763.8140259	1.21
764.9513550	7.71
770.1730957	0.17
771.1492310	2.05
773.9661255	0.41
776.8535767	0.33
780.2045288	0.18
781.3084106	5.56
782.0953369	8.80
783.0219116	25.27
783.6866455	0.11
787.5580444	0.43
788.8711548	1.53
789.4929810	0.28
792.3035889	0.59
793.8954468	0.38
795.0165405	1.51
798.2313843	5.31
799.2345581	14.45
800.0715942	52.95
801.0474243	100.00
804.9907837	0.55
806.1345825	1.14
807.0462036	2.62
809.5952148	0.21
810.9830933	0.62
812.2565308	2.37
813.1630249	4.56
816.9351196	0.12
817.7267456	0.12
818.9608765	1.33
822.5059204	0.81
823.6394653	0.84
825.0170288	9.92
825.9387817	0.21
827.1515503	0.80
830.0608521	5.83
831.1724243	4.64
836.6380005	2.35
837.3490601	0.11
842.0437012	0.33
846.8691406	0.44
848.5765991	2.44
849.2572632	5.50
853.0158081	0.56
853.8649902	2.84
855.0697632	9.50
860.0577393	0.86
863.8100586	0.13
866.0050659	5.30
866.9470825	14.06
867.6001587	0.13
872.5788574	0.18
873.2471924	0.18
875.1958008	0.69
883.8151245	4.74
884.4364624	1.85
885.0809937	21.07
900.0800781	0.17
902.0333862	25.97
903.0984497	44.80
920.8844604	0.05
922.1755371	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	659.2697
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
185.2017059	0.04
189.9433746	0.02
197.2891541	0.01
198.2173462	0.02
199.2387390	0.03
204.1047668	0.48
213.9969482	0.01
215.1030121	0.05
231.8979492	0.08
235.4246063	0.02
241.4380188	0.05
242.3876648	0.02
243.1865540	0.45
265.9273682	0.03
271.1383057	0.01
273.2635803	0.11
275.2357178	0.03
279.0292969	0.02
285.2671204	0.54
286.0902710	0.02
297.1147766	0.08
299.1630859	0.49
301.4838257	0.09
303.2296753	4.01
307.0822449	0.08
309.3723145	0.02
312.3950806	0.03
313.3628540	0.04
315.4722290	0.05
323.7296753	0.02
325.1449585	1.82
329.1729126	0.03
335.2202148	0.03
338.1838379	0.01
339.1472168	0.03
343.1275635	0.02
356.9833984	1.20
369.3569336	0.06
375.9317627	0.04
379.0212402	0.06
381.5552368	0.04
386.1434326	0.04
393.2125854	0.10
395.3895874	0.06
413.1245728	0.09
425.1201782	0.04
427.2778931	0.04
430.0161743	0.08
434.2335815	0.10
449.1074219	0.02
456.9749146	0.05
462.2826538	0.41
468.1732178	0.02
474.2562866	0.87
476.3224487	0.08
478.1375122	0.02
485.4221802	0.02
487.2031250	0.04
488.4039917	0.07
492.5189209	0.01
494.2105103	1.36
502.7607422	0.04
506.1669312	3.59
507.0097656	0.03
513.3956909	0.07
516.1549072	0.02
520.1899414	0.07
522.3278198	0.26
538.1994629	0.06
539.4081421	0.07
541.1317749	0.15
555.4140625	0.03
557.3305664	0.01
559.2310181	0.01
564.9649048	0.01
566.2092896	0.02
568.3423462	0.04
570.2673950	0.01
577.7883301	0.03
581.5224609	0.05
583.3482056	0.26
585.3480835	0.04
599.2630615	0.20
600.6912231	0.02
608.8523560	0.15
609.4609985	0.52
613.3624878	0.04
616.4223633	0.03
618.0743408	0.08
622.3375244	0.03
623.3779297	0.15
627.2230835	100.00
627.9197388	0.10
631.2558594	0.72
635.9038696	0.12
640.4165649	0.15
641.2039795	0.24
641.8525391	0.03
644.9439697	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	799.281
Annotation	Menisporopsin A
Peak:m/z	Relative Intensity
213.7469482	0.16
258.8145447	0.43
260.1643982	0.36
270.9258118	1.86
287.7430115	0.17
288.9007568	3.66
295.1012878	3.80
304.4132385	0.29
305.2469177	1.78
306.6880798	1.22
324.9283752	70.71
332.3600159	0.45
341.3207092	0.38
342.3442383	5.13
343.0158691	10.17
371.9524536	0.14
395.4401855	1.46
433.2158203	0.34
439.1920166	1.97
450.2092285	1.33
451.1375732	0.58
457.3626709	0.43
468.8325195	0.26
474.9273071	0.37
484.9341431	0.61
486.3381958	17.65
486.9559937	96.47
504.7691040	39.75
601.3781128	0.62
619.0227661	4.49
636.9464111	100.00
637.7577515	0.17
647.8101196	0.42
648.8822632	2.23
780.6412354	1.55
781.2421875	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	916.1153
Annotation	Unknow
Peak:m/z	Relative Intensity
268.8717346	0.20
282.6832581	0.05
295.0894470	0.10
304.0909729	0.05
309.1570435	0.05
310.3287354	0.32
311.0989380	0.69
312.1987000	0.10
325.1267700	0.20
326.0991821	0.07
332.1481323	0.04
335.8276978	0.24
337.9500122	1.77
341.1039734	0.18
348.0751343	0.05
349.0868225	0.28
349.9312744	0.05
352.0911560	0.14
354.2005920	0.14
355.2742004	0.16
364.9430237	0.07
366.0416565	0.23
366.7617188	0.08
371.9756470	0.07
382.0652466	0.26
392.2246094	0.08
393.8106384	0.04
396.0248413	0.52
407.4105530	0.18
408.0714722	0.53
410.0990601	0.52
410.9635620	0.45
422.1009521	0.41
423.0371704	0.61
424.0989990	12.11
424.9910889	0.39
431.1629028	0.42
436.0782471	0.06
437.9269409	0.49
448.1956177	0.11
449.3643799	0.10
453.9184570	4.45
454.9223022	0.14
455.6348267	0.26
466.0429077	0.40
468.0081177	0.17
483.1015015	1.03
483.9395752	2.32
484.5510864	0.10
485.1865234	2.65
486.2383423	0.19
495.1300049	0.14
496.1301880	0.04
502.1340332	0.27
511.8845215	0.09
514.2435913	0.10
525.9893799	0.20
527.7967529	0.10
544.0323486	23.92
556.0497437	0.43
569.8952026	0.15
573.3655396	0.05
574.0757446	0.48
586.0125732	0.08
593.3334961	0.14
604.1910400	1.72
611.5625610	0.12
612.6398315	0.09
621.0465698	0.19
621.8043823	0.12
622.4876099	0.12
628.2783203	0.05
633.8179321	0.20
648.1286011	0.69
650.2726440	0.39
662.0783081	0.03
663.0637817	0.24
664.0313110	0.43
676.1074219	3.73
680.0141602	0.16
688.0083618	0.26
689.9306030	0.86
702.1406860	0.24
703.2380981	0.16
706.1185913	12.07
707.1605835	0.22
708.3447876	0.06
717.5100708	0.97
718.2487183	0.58
722.2568970	0.21
729.4804688	0.06
730.3067017	0.22
734.3984985	0.08
736.1290894	9.78
737.2496338	0.17
748.0742188	0.99
753.1406860	0.51
753.8998413	0.46
760.0789185	0.48
766.1240234	0.06
768.1973877	0.44
771.9154663	0.08
782.9403687	0.80
784.2111816	0.04
789.9823608	0.26
794.2313843	0.19
795.9843140	68.95
796.8665161	0.39
797.8404541	0.34
808.0075684	0.91
819.0747681	0.09
820.2341309	0.25
823.8959961	0.26
825.9929199	100.00
826.6801147	0.82
827.4194336	0.10
830.4567261	0.14
835.8512573	0.11
836.9273071	0.06
838.0836182	4.56
856.1929321	0.05
867.5384521	0.08
868.2609253	0.09
871.4963989	0.08
872.9210205	0.07
874.3477173	0.07
880.0499878	0.71
897.7281494	2.19
898.4362183	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1558
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
162.7858734	0.01
178.9606934	0.08
180.0423889	0.09
184.7238770	0.04
189.0463104	0.03
191.0926514	0.17
197.0298920	0.08
203.0770569	0.10
205.0404968	0.03
209.2228851	0.05
210.1212311	0.09
215.1830750	0.03
228.8262634	0.03
237.1300659	0.07
240.1572266	0.07
242.9191284	0.04
244.9604645	0.12
247.2752686	0.23
248.2579651	0.04
257.0646362	0.14
259.0636902	0.07
268.2223816	0.12
269.1037598	1.11
281.0924683	0.32
283.0354309	11.64
284.1738892	0.02
293.1964111	0.19
294.9940796	0.32
307.4035034	0.06
308.9965820	0.05
311.0268555	100.00
312.0342407	0.54
321.2319336	0.35
322.2795410	0.03
323.0971069	1.52
323.9949341	0.07
325.2440796	0.16
332.8193359	0.05
335.1788940	0.13
337.2910767	0.14
339.2914429	0.08
341.1769409	28.76
342.2180786	0.03
351.2918701	0.68
353.1501465	1.35
367.1854858	0.45
368.2783813	0.50
369.1362305	0.18
370.2718506	0.07
371.2688599	0.08
377.1508179	3.76
378.2197266	0.06
393.1737061	0.04
395.1342163	2.89
397.3782349	0.03
415.1076660	0.09
424.9825439	0.21
431.2830200	0.03
433.0405273	0.03
439.0522461	0.08
449.0218506	0.04
451.2740479	0.05
454.9977417	0.06
456.1442261	0.05
457.4097290	0.17
486.9808960	0.07
490.8795776	0.18
513.3616333	0.07
528.5961914	0.03
530.1354370	0.57
530.9691772	0.18
533.5518799	0.15
541.2091675	0.06
558.1793213	0.13
559.2346191	0.30
562.0529175	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.2262
Annotation	11-HpODE
Peak:m/z	Relative Intensity
93.1846008	0.02
95.0131226	0.60
96.9548340	0.57
99.0001755	0.65
102.1031494	0.05
103.2618866	0.05
104.9071960	0.08
107.0475235	0.52
109.0310211	0.57
110.9499512	0.40
113.0285339	0.20
114.9822617	0.19
116.9930878	0.04
119.0905991	0.15
121.0350494	1.69
122.9199524	2.00
124.9565659	0.41
130.0876160	0.04
131.0043793	0.22
133.0227509	1.15
135.0853882	1.63
136.9935303	0.18
139.0658722	0.43
141.0767975	0.16
144.9652405	0.53
147.1358337	0.72
149.0593567	1.87
150.9658813	0.86
153.1385651	0.11
155.0648804	0.29
156.9705811	0.63
158.9259338	1.25
160.8898010	0.51
163.0924988	0.56
165.0921326	1.19
167.0483704	1.38
168.8971558	0.31
171.0561676	1.46
173.1113129	1.85
175.0612488	0.72
177.0840759	0.24
179.0256348	0.78
181.0113831	0.59
183.0381470	0.52
185.0799866	3.01
187.1939392	1.11
189.0500488	1.35
191.0672455	0.73
192.3936768	0.34
193.1000671	0.88
195.0199280	0.68
196.9700317	0.15
199.0315552	0.77
201.0401306	1.04
203.1536560	0.47
205.1506042	0.41
207.1131592	2.30
209.1546021	0.51
211.0738220	0.78
213.0726929	1.15
215.3138733	0.08
217.1854858	0.38
219.1636353	0.16
221.1808167	1.33
223.0886841	0.27
225.0686340	1.07
227.2119751	0.49
231.0763855	1.09
234.1201782	0.02
235.2231445	0.51
236.1228333	0.42
237.1795349	1.89
238.7228088	0.21
241.1304321	6.00
241.7579346	0.04
242.9944763	0.07
244.4345398	0.07
245.6618652	0.22
248.0785522	0.14
249.1784973	0.42
249.9769287	0.09
250.8786011	0.20
253.2849426	1.16
254.0081177	0.20
255.2780762	0.16
259.1110229	12.11
266.4421997	0.15
267.1824951	0.75
268.4073486	0.05
274.9075317	0.08
277.1305542	100.00
278.0091248	0.03
286.2542419	0.19
294.4335938	0.05
295.0503540	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1608
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
119.0235596	1.70
123.0561523	1.52
125.2342682	0.19
130.9119110	2.04
133.0212860	1.14
135.0014191	0.34
138.1282959	0.05
142.9996948	4.22
145.0384521	0.42
146.1484833	0.27
147.0281219	0.19
147.7501678	0.10
149.0452576	14.72
152.9344482	0.06
156.7601471	0.11
158.1931610	0.17
159.0014191	0.38
161.0650330	33.36
162.0179749	0.11
163.1125488	1.18
164.1381378	0.12
167.0056458	0.76
173.1635132	0.11
179.0432129	100.00
180.9968567	0.14
197.2907104	0.98
200.8836975	0.08
201.7666016	0.11
203.1090698	0.14
205.3065491	0.91
209.1699066	0.09
215.2609406	0.12
220.8174744	0.62
223.0286255	4.91
225.1416473	1.35
237.4320984	0.11
241.0186157	7.41
242.0392151	0.07
251.8613281	0.13
265.2218018	0.31
267.4405518	0.37
282.9180298	0.41
293.0998535	0.08
298.7178040	0.07
309.0240479	0.07
328.9238892	0.11
341.5415039	0.09
343.2224426	1.53
357.2641907	0.97
359.1636658	0.28
361.0599060	0.15
385.1853333	11.19
386.2437744	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5074
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
237.0843201	0.16
241.0880127	0.09
243.190033	0.21
255.2348633	37.17
256.2655945	5.45
259.2956543	0.32
261.3110352	0.22
262.460022	0.09
265.3009338	0.10
279.2371826	100.00
280.2219238	20.27
293.0093994	0.17
295.2631226	0.11
305.2728882	0.62
307.0131836	0.10
320.0496826	0.37
325.1885986	0.43
378.3079834	0.16
391.4916992	0.57
392.1125488	0.04
409.1029663	0.08
420.5515137	0.07
434.3528442	1.36
443.2503662	0.44
452.3031616	19.75
453.3306274	3.23
454.0515747	0.10
458.2860718	1.12
465.3658447	0.23
475.3392944	0.51
476.3339233	3.92
477.3032227	0.41
500.2736206	0.32
504.2476196	0.14
505.2293701	0.22
521.6853027	0.16
548.418396	0.47
550.3554688	0.11
563.5623169	0.08
573.1207886	0.12
595.0293579	0.08
603.208374	0.36
611.2232056	0.06
613.8001709	0.20
618.3179932	0.11
653.6362305	0.14
657.30896	0.09
659.0757446	0.10
670.3765869	0.09
671.5258179	0.06
677.3048706	0.29
679.2591553	0.23
681.4905396	0.45
691.3966064	0.12
697.4125366	1.31
698.4717407	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	822.5281
Annotation	PS(17:1(9Z)/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
231.2347107	0.05
241.2116394	0.05
255.5111084	0.12
277.3175049	1.87
279.6198730	0.03
283.4304504	0.04
292.2524109	0.07
307.5414124	0.03
311.5180969	0.02
328.4457703	0.03
341.5093994	0.01
352.0640869	0.02
363.3106995	0.01
431.5142212	0.01
464.3126831	0.13
469.6602173	0.03
471.5246582	0.02
495.4232788	0.08
502.3225708	0.07
523.2706299	0.06
533.7165527	0.04
539.2064819	0.79
540.9264526	0.11
546.1065063	0.03
560.6494751	0.07
563.7146606	0.16
564.5535278	0.49
565.4533081	0.95
566.3787231	0.38
579.3756714	0.03
587.9311523	0.03
618.6629028	0.12
637.6478882	0.05
650.9523315	0.04
669.0443115	0.07
690.8393555	0.08
691.5859375	0.18
715.6637573	0.01
719.6310425	0.02
745.2287598	0.03
748.6837769	0.03
755.0164185	0.04
759.4871216	0.10
762.3499756	100.00
763.0788574	1.00
764.7142944	0.02
776.5202026	0.17
778.6007690	0.20
779.2730713	0.02
783.0945435	0.08
787.1716309	0.06
802.1668091	0.04
803.5216064	0.60
804.4475098	0.26
821.7346191	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1511
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
171.0134583	0.05
174.8705902	0.16
181.9429169	0.06
182.9037323	0.05
184.0066376	0.05
184.9980621	0.24
186.9582214	0.23
189.0375061	0.24
193.088501	0.09
194.8647919	0.61
195.4969177	0.15
196.9612122	0.51
199.0713501	0.06
201.0871887	0.11
211.1690826	0.56
212.0256805	0.15
212.8727722	0.54
214.9940491	0.07
222.8160706	0.30
227.0196686	1.22
229.0552521	2.46
239.1078339	0.15
240.0401764	0.33
241.1656342	0.60
242.9602356	0.09
249.2212677	0.16
253.2292938	0.04
255.192688	1.71
256.1428223	0.28
257.1164551	3.25
267.0563965	1.24
268.1287231	0.10
272.1140747	0.05
282.9829102	1.70
284.0860291	4.72
285.0433044	100.00
286.0281982	1.30
297.2841797	0.31
299.1531372	0.44
309.2633362	0.12
311.1454163	7.10
315.2228394	0.40
323.2249756	0.27
327.0852661	3.75
328.9660645	0.08
339.2163696	0.12
341.1586914	0.11
343.3917236	0.22
353.0686646	1.31
357.09021	0.73
366.1306763	0.18
369.2830811	0.22
377.0682373	0.03
383.2073364	0.08
388.2940674	0.09
388.9512329	0.06
393.1604614	0.25
395.0220337	0.57
411.2589111	0.52
413.2481689	1.06
415.1253662	0.12
417.2737427	0.28
419.1914062	0.04
421.2860718	0.19
424.138916	0.03
427.3887939	0.22
429.2279053	0.32
431.2936401	0.87
441.0043945	0.14
446.3129272	0.21
447.4520874	0.22
448.2996826	0.05
448.9973755	0.13
455.1338501	0.10
461.2009277	0.08
463.3481445	0.05
465.135498	0.22
471.0178833	0.08
471.9158936	0.33
473.1530762	0.85
473.8549805	0.05
475.3011475	0.16
482.9336548	0.18
484.1223145	0.09
491.2145996	0.18
493.305603	0.12
499.0805054	0.08
502.1140747	0.13
503.2034912	0.39
506.2034302	0.10
513.7084351	0.14
519.3046265	0.11
524.3132935	0.24
531.513916	0.07
533.3548584	0.09
534.2897949	0.06
547.3262329	0.42
548.5008545	1.14
549.4524536	0.31
557.2290649	0.60
563.354248	0.05
565.5552368	0.67
573.048645	0.10
574.9555054	1.36
575.9993896	0.14
577.2512817	0.02
584.0485229	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1119
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
120.9342804	0.02
162.9366608	0.06
175.0020752	0.08
181.0570374	0.01
189.1774750	0.04
216.9308472	0.03
218.7411346	0.07
223.0403137	0.14
235.0874634	0.23
243.1612244	0.03
253.1542969	0.08
265.0792236	0.05
271.1150208	0.83
276.9352417	0.06
279.0769958	0.11
283.1901245	2.37
295.1442261	3.57
297.1359558	0.61
299.0288696	0.05
307.3038025	0.13
310.9787903	0.16
313.0321655	24.72
313.9429932	0.09
325.1785889	0.11
337.0799561	11.40
343.1347656	0.78
349.1046753	0.09
351.0412598	0.55
355.0027161	0.85
361.1610413	0.13
367.1505127	23.70
368.3112488	0.02
379.1224976	6.47
397.1398010	20.68
398.1705933	0.03
415.1434021	100.00
415.9507751	0.63
433.1332703	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	910.152
Annotation	3-hydroxyadipyl-CoA
Peak:m/z	Relative Intensity
303.8553772	0.47
316.0366211	0.08
334.0734863	0.08
393.9546509	0.22
406.0698853	0.24
437.1549072	0.36
461.9153442	0.07
480.1029663	0.04
496.0861206	2.09
497.0099487	0.84
522.0661011	0.57
527.0168457	0.03
538.2789307	0.27
539.9730225	0.11
554.1630859	0.22
554.8389282	0.04
556.0748901	4.25
556.9464722	0.65
558.0626831	0.13
573.7687378	0.38
616.0881958	0.12
627.1170044	0.22
628.1384888	1.39
628.8129272	0.12
658.0166626	2.69
684.0862427	0.18
687.4863892	0.86
688.1593628	3.84
689.1179810	0.03
700.3063354	0.26
716.1318970	0.44
718.0820923	100.00
719.1181030	6.52
720.1203613	2.61
730.2376099	0.88
748.1299438	1.89
820.0957642	0.08
821.9739990	1.43
850.1227417	0.12
852.5208130	0.28
865.9956055	1.66
892.1719360	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.3159
Annotation	Alpindenoside C
Peak:m/z	Relative Intensity
182.9625092	0.28
183.9303741	0.09
185.2628784	0.04
187.1419220	0.29
188.1797333	0.10
191.2947998	0.09
194.1803284	0.03
195.1642914	1.09
197.1784058	0.19
199.4270935	0.03
205.2199097	0.22
207.1945496	0.05
209.2632751	0.23
211.0826569	0.15
213.3078003	0.17
215.1850586	0.03
219.1387482	0.14
220.3254852	0.10
222.8766479	0.04
224.0713806	0.08
225.1726685	0.59
227.0095520	0.23
229.2260742	0.18
231.2343445	0.07
236.9855042	0.96
239.3567505	0.16
241.2311554	1.41
242.6426086	0.08
243.2791901	0.14
245.2365265	0.15
247.1020203	0.15
248.8279877	0.08
251.1427765	1.76
253.4059906	0.45
254.4118195	0.12
255.1439819	0.94
257.0496826	0.32
259.1652222	7.14
261.1351013	0.38
263.1487732	0.05
269.1915588	3.21
271.1524658	1.85
272.4099121	0.10
273.0884399	2.00
275.1253357	0.19
279.2320557	0.13
283.1622925	0.19
285.3557129	0.44
287.2467957	8.69
289.1459656	0.60
291.0130005	0.15
297.2723999	1.68
299.2499390	0.24
301.0987549	0.26
303.1158752	0.36
305.1651001	1.12
307.5087280	0.16
308.9912720	2.14
310.9912109	0.08
313.1880493	0.20
315.1875610	14.17
317.1934204	0.95
319.2796021	0.08
321.3507080	0.04
325.3447876	0.07
327.4210510	0.03
329.2523193	0.10
330.2298584	0.09
331.1477051	1.36
333.1623535	100.00
335.3109131	8.94
338.2753296	0.21
343.4001465	0.03
349.2197876	1.27
351.2495117	3.00
353.0674438	0.25
354.8889771	0.08
357.2246094	0.04
361.4855347	0.16
365.3500977	0.11
367.3044434	0.19
369.3809814	0.46
370.9727173	0.30
372.3415527	0.10
373.0346069	0.06
376.3044434	0.05
377.3016357	0.07
379.3661499	0.04
381.4907227	0.08
383.4600220	0.17
385.1976929	0.04
387.0072632	0.30
388.0849609	0.10
393.1814575	0.28
395.1019287	0.04
397.4716797	0.65
398.9672852	0.72
401.2436523	0.06
405.1470337	0.72
407.4149170	0.35
413.1818237	0.08
414.1802368	0.06
415.2888794	0.38
417.1817017	3.28
421.1472168	1.00
421.7590942	0.02
425.0941772	0.87
425.7780762	0.33
430.0792847	0.06
433.2073975	1.28
437.8364258	0.10
443.2201538	10.24
447.2973022	0.05
449.3148804	0.20
456.3541870	0.45
458.1531982	0.27
458.9562988	0.12
461.3258667	2.73
465.3203125	0.10
467.6345825	0.16
475.6640015	0.34
476.3726196	0.83
477.1206665	0.60
479.1302490	27.48
479.8389282	0.05
483.4310913	0.14
485.5567627	0.21
487.3859253	0.12
488.0205078	0.13
489.1123657	0.06
491.4683228	0.05
493.2816772	0.23
495.1968384	21.72
495.9206543	0.30
497.2849731	7.44
504.1469727	0.22
506.1505737	0.28
506.8433228	0.08
513.2520142	2.09
519.3708496	0.25
521.2379150	0.87
523.2387085	0.16
525.3454590	4.92
531.2590942	0.44
532.9464722	0.14
535.6285400	0.02
537.3201294	0.34
543.4536743	0.03
548.0924683	0.11
555.1533203	0.03
559.4237671	0.19
562.6873779	0.03
565.3414307	0.09
567.6114502	0.16
568.2844238	0.02
568.9778442	0.13
577.3629761	0.31
578.9341431	0.08
587.4978638	1.08
593.8435059	0.05
595.2319946	1.85
596.5011597	0.25
597.4001465	0.14
603.3666382	0.13
605.1237183	17.12
605.9288940	0.03
609.3598022	0.44
611.4749756	0.04
613.2515869	0.16
623.1929321	5.43
623.8458862	0.11
632.4092407	0.57
640.9691772	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
131.8707428	0.03
139.0730591	0.07
143.0877686	0.06
150.8511353	0.04
161.002594	0.17
162.9287872	0.07
174.2105103	0.05
176.8003845	0.03
186.0726318	0.03
189.3555603	0.11
197.0024719	0.10
206.7219696	0.04
221.4749756	0.03
223.1322632	0.13
226.9385071	0.05
238.911377	0.08
241.0881042	0.04
243.0626526	0.21
249.1450806	0.05
254.9466553	1.06
255.9841309	0.36
257.0481567	0.13
267.1471252	0.14
268.2552795	0.05
269.1131592	0.11
284.0351257	4.74
285.0352173	100.00
286.1271362	0.51
287.1255798	0.08
289.2363281	0.19
297.1582031	0.08
298.147644	0.11
299.12854	0.06
299.8414001	0.05
303.2581787	0.11
314.1874084	0.10
323.1102295	0.31
327.0452881	40.32
328.1487732	0.46
330.3164673	0.04
332.2766113	0.09
339.3488159	0.37
340.3141174	0.08
343.0835266	0.06
351.1812744	0.05
353.3058777	0.06
355.0325317	0.22
357.1029968	17.35
359.2892761	0.16
360.1624756	0.35
360.8728638	0.09
365.1687012	0.13
369.014679	0.56
369.6184998	0.03
371.3067017	0.34
373.9886169	0.04
378.7529602	0.06
381.0605774	0.12
383.3184204	0.37
384.8665466	0.20
387.0409851	1.11
389.2131653	0.42
391.2930908	0.10
393.195282	0.49
399.0816956	0.35
400.2921143	0.06
401.0787048	0.47
402.1731262	0.36
403.2080688	0.61
404.1173096	0.06
405.1678162	0.15
409.771759	0.18
411.1516724	1.04
417.1199341	0.06
429.1411438	3.94
432.1542664	0.22
447.3344727	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1814
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.9145584	2.62
118.9699554	7.23
125.1269455	0.18
130.9760132	3.84
133.9638977	0.30
140.9742279	0.44
143.0175018	5.19
145.2615662	1.01
147.0618134	5.41
148.9935913	3.34
153.2635498	0.20
159.0970001	0.54
160.9413757	5.70
163.3575134	0.41
165.0997314	0.70
177.1748657	0.19
178.6618042	0.52
191.1117401	1.57
192.9642029	0.19
209.0336151	94.55
210.2224884	0.31
210.9677734	4.31
211.5813293	0.29
213.3002625	0.28
227.0788574	12.08
239.1658936	0.92
240.9822998	0.66
251.1455994	0.33
268.6023865	0.26
289.1098022	0.27
311.2626953	0.60
329.1749878	4.62
341.2444763	2.07
353.1753540	1.47
371.2348938	100.00
372.3347473	3.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0929
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
153.786911	0.01
161.010025	0.06
166.963089	0.01
175.1743774	0.03
191.9083252	0.02
197.1860962	0.05
199.3261566	0.01
200.2268677	0.01
213.1032715	0.01
217.1365509	0.02
223.1023407	0.05
231.1416473	0.06
241.7585144	0.04
249.0877075	0.02
252.2662964	0.02
259.190094	0.00
267.3236694	0.03
268.2231445	0.01
269.0234375	0.01
274.2676086	0.01
285.0443115	100.00
286.087677	29.62
287.3182678	0.03
289.2437134	0.01
297.1729431	0.01
298.0010071	0.01
299.134613	0.09
301.1257935	0.01
303.4190063	0.01
309.2055969	0.02
309.9878235	0.01
315.1367798	0.03
323.0159302	0.01
325.1433716	0.01
327.0339355	10.17
328.0928345	4.14
329.0572205	0.01
330.322998	0.01
332.3075867	0.01
337.1844482	0.01
337.9801025	0.01
339.3464661	0.01
340.1002808	0.01
342.2690125	0.03
345.3594971	0.01
351.1644592	0.05
353.1112061	0.02
354.1191406	0.04
354.8939209	0.02
357.0184631	1.34
358.0600586	0.95
361.3851318	0.03
365.3588257	0.01
368.938385	0.13
370.1307068	0.12
371.4108582	0.07
372.285614	0.04
381.0261536	0.02
385.0178528	0.03
386.9924316	0.20
388.2032776	0.07
390.1601868	0.01
393.2245178	0.06
394.0182495	0.06
399.022644	0.01
400.0429382	0.06
402.0027161	0.01
403.1301575	0.11
404.1280823	0.09
406.236908	0.02
411.1660156	0.06
416.1135864	0.03
417.478302	0.02
418.9972229	0.05
429.1731262	0.54
430.183136	0.35
447.4930725	0.01
448.3976135	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1829
Annotation	Lactulose
Peak:m/z	Relative Intensity
216.9983826	0.05
219.8486176	0.03
334.8641968	0.05
348.1489868	0.08
362.0518799	0.48
362.8740845	0.08
366.2669067	0.02
380.9959106	0.24
423.1779785	0.10
430.6567993	0.05
438.9736328	0.12
440.9890747	0.15
452.0128174	0.20
453.5701904	0.17
469.4330444	0.06
470.9650879	0.04
493.0278320	0.02
506.7573853	0.04
525.2196655	1.16
532.2683716	0.25
533.0274658	1.86
533.6940308	0.86
541.3034058	0.23
543.1395874	100.00
543.8482056	0.25
560.1292114	0.02
575.1345825	0.02
587.9642944	0.02
624.1437988	0.05
644.6262207	0.02
662.0974731	0.04
668.2520142	0.04
686.5341187	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.4119
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1288910	0.07
245.1903534	0.02
250.8628540	0.06
253.0178986	0.39
255.3481445	0.17
256.5133667	0.03
258.6377258	0.12
262.9838257	0.14
268.7308044	0.06
277.0646667	0.38
282.8533630	0.04
286.8803406	0.36
291.3516235	0.03
293.0316772	0.11
295.3647461	0.07
305.0209656	0.25
309.1725769	0.02
312.3106384	0.03
321.2206421	0.02
323.0313110	0.54
327.1378174	0.12
329.4988708	0.04
340.9758301	0.07
347.1399536	0.10
363.0915527	0.04
365.1645813	0.74
379.2039185	1.41
383.1588135	0.58
392.2124634	0.07
393.3829956	0.05
393.9876099	0.11
397.2409668	7.06
406.8773193	0.18
412.6105957	0.16
415.2197876	4.76
416.3482666	0.13
420.8755493	0.07
425.2911377	0.36
437.1836548	0.02
439.0478516	0.92
440.2233276	0.03
442.7348633	0.02
449.2036743	0.93
450.4752808	0.05
455.5713501	0.02
457.3302612	0.05
467.1624756	0.50
467.9245605	0.15
481.5070190	0.08
483.6942749	0.05
485.2059937	0.88
491.4827881	0.02
499.2927856	0.04
511.2648315	0.07
513.3720093	0.02
517.1371460	0.04
523.1890259	0.60
525.1793823	0.06
541.1803589	0.11
550.2554321	0.05
553.3394165	0.06
559.2129517	100.00
559.8480225	0.21
560.5531006	0.05
567.4204102	0.12
571.3770142	0.03
575.2954712	0.12
577.1460571	43.45
577.7742310	0.29
584.9978638	0.20
589.3624878	0.02
591.1139526	0.08
592.4641113	0.13
609.5416870	0.02
616.8153076	0.04
643.3137207	0.03
646.4587402	0.17
647.3338013	0.09
655.2532349	0.08
659.3912964	0.07
675.1873779	0.14
676.4163208	0.08
677.7162476	0.04
687.4954224	0.23
688.3342896	0.09
690.2015991	0.02
692.5889893	0.06
693.2711182	0.02
705.2787476	0.15
706.2130127	0.07
712.4950562	0.13
713.1184082	0.07
714.2634888	0.09
717.9999390	0.08
720.3672485	0.06
730.1140137	0.02
731.0123901	0.11
733.5277710	0.11
744.4216919	0.11
749.4780273	0.08
754.4616699	0.02
756.2506714	0.03
758.4147339	0.32
759.2516479	0.15
768.1482544	0.11
770.7678833	0.04
772.5093994	0.33
775.8554077	0.23
776.4929810	1.95
777.2135010	0.22
778.1436157	0.07
784.5937500	0.07
789.8186035	0.06
790.5316772	0.13
792.2081909	0.03
800.5329590	0.17
818.3466187	0.47
819.4678345	0.83
821.2955933	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	305.0651
Annotation	Pratenol B
Peak:m/z	Relative Intensity
110.9031982	0.12
123.0181274	0.99
126.9984436	0.70
136.8935547	0.01
139.1541748	0.09
148.9706879	1.49
151.1005554	0.01
152.9004517	61.03
154.7843628	0.07
161.0244446	0.69
166.8850861	0.28
179.0175781	1.77
183.0519104	0.01
185.8688354	0.03
195.0047607	20.56
210.0792236	0.03
220.9221191	0.07
226.0848389	0.04
228.7453003	0.02
231.1051941	0.92
237.5824585	0.01
245.0739136	0.05
259.0087891	52.68
269.0906677	0.06
273.0349731	0.10
274.3453369	0.05
275.9505005	0.01
277.0598755	0.08
286.9388428	100.00
305.2066345	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.3284
Annotation	Unknow
Peak:m/z	Relative Intensity
190.0635529	0.35
199.1616211	0.05
211.0999756	0.28
255.2924194	0.18
277.2902527	3.52
293.2598267	0.10
295.0364380	1.01
314.4752808	0.16
323.1387939	6.85
341.1161499	35.44
350.1843872	0.10
351.1873779	0.11
357.3789062	0.08
360.4679565	0.12
362.5090942	0.11
365.1897583	0.10
368.0218506	0.07
383.1077271	0.98
390.4910889	0.29
401.1000977	0.07
421.3849487	0.39
431.4318848	0.52
438.5104370	0.60
439.2781982	0.33
443.0950317	0.10
449.5734863	0.10
452.2167358	0.42
466.8739014	0.80
467.5447388	0.29
477.7119751	0.15
484.8263550	1.00
491.8153076	0.21
508.9879761	0.27
510.4645386	0.85
511.3573608	0.26
575.3167725	0.21
585.2122192	0.18
588.4634399	0.23
601.0973511	100.00
601.7612305	0.40
602.3729858	0.09
603.1801147	0.04
611.3174438	0.14
615.5366821	0.20
624.5167847	0.15
627.0130615	0.38
628.3804932	0.43
629.2866821	0.50
638.1262207	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2548
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
347.3825073	0.02
377.3355713	0.02
397.4662476	0.03
408.6409302	0.01
422.8215332	0.02
451.9661255	0.01
452.8518677	0.01
473.1679688	0.01
481.1104736	0.01
483.2283325	0.01
493.3892822	0.03
499.5830688	0.04
500.2217407	0.01
527.2803955	100.00
528.2183228	0.05
529.1370850	0.01
555.1249390	0.11
573.2992554	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	273.08
Annotation	Alternariol monomethyl ether
Peak:m/z	Relative Intensity
78.8964157	0.08
81.0259323	0.11
90.8867798	0.83
94.9721909	0.37
104.8699188	0.04
106.7897797	0.26
109.1097870	0.07
110.8155975	0.94
118.9529419	2.49
119.9868317	0.11
121.0167923	1.87
122.8519287	0.46
126.2165527	0.06
130.8780518	0.11
133.1696777	0.17
137.3390808	0.04
138.8744507	0.23
142.9533386	0.24
144.9969940	0.51
146.9037170	79.16
149.0848389	0.47
150.9259644	2.79
152.8667450	100.00
153.7823181	0.17
154.7622986	0.07
156.9440918	0.12
158.1804352	0.07
158.9938507	0.24
159.9495544	0.15
161.1525116	0.28
162.8483734	0.78
165.2215271	0.15
167.0371552	0.07
168.9817047	0.07
170.7468872	0.03
172.9402466	0.82
174.9601135	0.10
177.3438721	0.05
178.9341736	4.32
179.9010925	0.04
181.1209106	0.30
182.9459534	0.16
183.8721161	0.03
184.8919373	0.17
189.0210876	4.96
191.3093414	0.12
192.9818726	0.21
195.2690430	0.05
196.0932922	0.07
197.2827148	0.22
200.1838379	0.07
200.9739685	0.16
203.0379944	0.07
207.2269592	0.09
209.2717285	0.04
210.2706909	0.10
211.0425110	0.32
212.9607544	0.26
214.0832520	0.05
215.2523499	0.36
225.1642761	0.32
226.5643616	0.54
227.1919861	0.67
229.2592468	0.15
231.0867004	5.00
232.0033875	0.20
237.1210327	0.51
240.8485107	0.23
241.6956787	0.09
244.3294067	0.13
244.9327393	0.48
252.9596558	0.26
254.1620789	0.42
255.1218872	7.81
259.2260742	0.17
270.2337036	0.07
273.2354126	0.68
281.9041443	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
190.7885132	0.02
257.8047791	0.05
269.0423889	0.15
270.2528076	0.08
281.2477417	0.08
283.1907349	0.16
284.0906677	0.05
293.1701965	0.08
294.2518311	0.08
309.0810547	0.13
311.0552673	100.00
312.1461792	68.74
320.9762573	0.16
321.6690674	0.03
322.3851318	0.02
323.1507874	0.76
324.1885376	0.41
325.1156616	0.06
326.2565308	0.02
337.1473694	0.14
338.1495361	0.08
341.0818176	20.50
342.0906982	19.43
342.7077026	0.17
351.0240784	0.20
352.1769714	0.07
353.1705322	0.92
354.1561584	0.86
355.2481384	0.56
356.1617737	0.43
365.0168762	0.22
366.2730408	0.07
367.1450195	0.14
368.1801147	0.04
371.2928467	0.55
372.3034973	0.42
377.1161194	0.30
378.0923767	0.27
383.1769104	0.95
384.0969543	0.66
395.0982971	0.81
396.0954895	0.53
402.2661133	0.03
413.1770935	4.67
414.1914978	4.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.3441
Annotation	Mezzettiaside 9
Peak:m/z	Relative Intensity
241.2171326	0.13
255.2177582	0.11
269.5477295	0.15
271.1501465	0.20
275.3784485	0.06
279.3063354	2.10
287.2000732	0.12
293.3700562	0.27
295.1950073	0.06
296.2860718	0.12
298.3983765	0.09
303.0599976	0.20
309.3006287	0.05
320.9537964	0.11
323.1444702	7.03
341.0973511	36.45
354.5483398	0.07
368.4826050	0.05
388.9604492	0.14
393.2308960	0.09
440.9489746	1.05
448.6497192	0.06
464.0747070	0.18
464.9829712	0.07
487.2296143	0.79
489.1428223	0.39
493.1407471	0.17
505.5475464	0.08
512.2775879	0.06
577.5029907	0.05
593.1819458	0.07
602.6437988	8.66
603.2575073	100.00
630.4049683	1.31
631.3554077	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.18
Annotation	Marikarin
Peak:m/z	Relative Intensity
157.9586792	1.24
170.9132690	0.09
171.9501953	0.41
174.9675140	0.09
175.9684448	0.43
187.9799042	0.43
190.1120300	1.65
193.0041199	6.89
208.7802582	0.18
210.0101624	0.10
213.2473450	0.34
214.9193115	0.39
258.9414673	0.12
271.1610107	0.13
286.1397095	0.08
288.9360352	0.71
304.2103271	0.60
306.8743286	0.16
312.0396729	0.13
322.0382690	100.00
325.1691284	0.23
330.9780273	0.12
337.1877441	0.27
379.8333740	0.14
381.1529541	0.08
382.1406860	0.46
389.6453857	0.23
391.4068604	0.12
409.1936646	0.08
419.1008911	0.10
422.1618652	0.20
427.1364746	0.14
433.0099487	0.33
453.6526489	0.63
457.0250244	0.20
457.7835693	0.45
465.2940063	0.59
467.4902344	0.12
468.2001343	0.21
472.2962036	0.15
475.5086060	0.17
483.1362305	0.05
490.9180908	0.30
492.9389038	1.45
493.6083984	0.12
497.9965820	0.26
499.9158936	1.08
502.3010254	0.30
505.1305542	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.2281
Annotation	Sorbitan laurate
Peak:m/z	Relative Intensity
107.0198288	0.41
115.2705307	0.08
116.9968872	0.08
123.1209412	0.32
125.1486740	0.62
127.1347046	0.39
129.1295166	0.10
137.0554352	2.20
139.0728760	0.46
142.2035217	0.06
154.9740601	0.82
157.2291412	0.74
163.2801514	0.13
165.0565491	2.13
171.1008759	29.54
171.9771881	0.07
173.0361938	0.12
177.2050171	0.79
183.0322723	0.64
185.1161194	0.92
189.2905579	0.23
191.1279602	0.08
197.1171417	0.13
198.4948578	0.67
199.1556396	0.26
201.0724487	100.00
202.1577759	0.47
205.7554626	0.23
207.2938232	0.14
209.0938568	0.36
213.1448059	0.35
217.3305054	0.07
219.0525208	1.15
221.1477661	8.70
223.1255798	0.05
224.1932068	0.30
225.2623291	0.16
226.1752014	0.07
226.9124451	0.24
228.2155151	0.08
229.1233521	0.44
233.1249695	0.98
234.9869385	0.10
236.3960876	0.29
237.2410278	1.48
239.1377258	25.68
240.0868225	0.18
241.1351624	0.21
241.9337769	0.28
243.1044617	0.13
244.4152527	0.10
245.1013184	0.62
246.1467590	0.09
247.0733643	0.29
251.2259521	14.61
253.2709351	0.14
255.2286072	0.74
257.1863708	60.76
258.2493286	0.12
261.0917969	0.11
265.2004700	0.35
267.4289551	0.14
268.0399170	0.17
269.2495117	5.05
271.2304382	0.15
273.1561279	2.80
280.9914246	0.97
283.1273193	0.32
285.3085938	0.09
287.2349243	2.56
291.1914062	42.08
292.3045654	0.43
299.2067871	1.17
300.3108521	0.06
301.2470093	1.03
307.2081299	0.18
309.2918701	36.89
317.2225342	0.17
325.4160156	0.69
327.1583252	60.24
328.1586914	0.31
329.9281006	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	273.08
Annotation	Alternariol monomethyl ether
Peak:m/z	Relative Intensity
85.2580795	0.03
91.0278778	0.27
92.9136810	0.04
95.0333023	0.32
97.1270599	0.08
102.6301727	0.04
106.9663544	0.83
110.8347931	0.52
117.1759491	0.05
118.8949738	1.10
120.9332581	2.60
123.0001068	0.68
124.9274750	0.18
128.7416687	0.07
130.9031372	0.35
131.8638458	0.07
133.3833313	0.15
137.1439972	0.06
138.1878662	0.07
139.1946564	0.03
145.0585938	0.18
147.0145874	69.22
148.1304016	0.12
149.1356506	0.65
150.9710388	2.12
152.9160004	100.00
153.9060822	0.21
155.0420227	0.05
157.3536987	0.37
157.9846191	0.12
158.9604034	0.72
160.2848511	0.15
161.1773071	0.57
163.0493927	1.36
164.8402405	0.07
166.9704132	0.48
169.1638184	0.22
171.0540314	0.75
173.1423340	0.42
174.1012115	0.08
175.2509613	0.20
177.1501770	0.03
179.0040894	7.46
180.1822968	0.12
181.0550232	0.08
183.1513367	0.21
185.1666565	0.12
185.9724884	0.07
189.0481567	3.33
192.2056274	0.09
193.0250854	0.12
194.2635498	0.11
195.1388245	0.18
197.0187988	0.18
199.1767578	0.17
200.1295471	0.26
201.2113342	0.18
202.3036804	0.34
203.2623901	0.03
205.1511841	0.16
209.1654053	0.72
212.9743347	0.37
215.2262573	0.14
217.1888428	0.12
222.9260254	0.29
225.1617737	0.10
227.1055908	1.71
229.2323914	0.10
231.0155029	5.05
231.9987183	0.65
237.0280457	0.84
241.0485229	1.26
243.0384216	0.14
244.0563354	0.13
245.2802124	1.04
249.8558960	0.08
252.3113708	0.05
253.3443604	0.08
255.1143188	6.74
256.0618286	0.70
258.0812988	0.25
259.4448853	0.17
269.1131897	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1662
Annotation	Butrin
Peak:m/z	Relative Intensity
167.8753662	0.05
169.1302948	0.09
171.0388641	0.05
172.1654816	0.53
173.0552521	0.27
175.9320221	0.40
177.0613556	0.08
178.9869080	0.31
179.8869629	0.37
181.0614166	0.20
182.1394653	0.18
183.0728912	0.07
183.9473572	0.30
187.0382690	0.04
191.0781403	0.12
192.7318726	0.08
196.1070862	0.05
197.1447144	0.42
198.3296509	0.22
199.1314087	0.80
200.0729523	0.04
201.0851440	1.43
202.1242065	0.11
203.9799500	0.14
205.0902100	0.06
213.1448059	0.08
214.2206116	0.08
215.0089874	1.00
216.1632233	0.67
219.0678864	0.21
221.0768127	0.08
224.4141388	0.46
225.1863098	0.47
225.9835968	0.09
235.0409546	0.07
238.9397278	0.11
239.8818054	0.10
241.1035156	1.55
242.2223816	0.34
243.1190948	2.07
244.0571289	0.34
251.0140839	0.09
259.0208435	44.88
260.1514587	6.83
267.2434082	0.15
269.0454407	100.00
270.1172485	18.61
283.0661011	0.60
287.0455322	63.50
288.1275330	12.02
289.2751465	0.26
293.0327454	0.20
294.8655396	0.08
297.1647949	0.05
298.2413940	0.02
300.9683838	0.06
302.1460571	0.07
311.1849976	0.65
312.2404175	0.35
313.3538818	0.09
314.3508911	0.04
330.0819092	0.04
340.9629517	0.10
352.6878662	0.17
353.3275757	0.11
354.2131348	0.27
355.1525879	0.16
356.3024902	0.16
360.6419067	0.05
371.6027222	0.06
375.5341797	0.07
381.2261963	0.09
383.2658691	0.04
384.2438354	0.04
385.2301636	0.34
413.3518066	0.04
415.1239014	0.72
416.3071899	0.10
432.0667725	0.15
433.2811890	0.20
434.0277710	0.16
439.4574585	0.07
441.2025146	0.39
447.2071533	0.07
454.9891357	0.21
461.1536255	0.11
466.4067993	0.07
469.2598877	0.07
472.3632202	0.05
473.2348633	0.32
474.0430298	1.41
475.1693115	2.28
476.1548462	0.29
486.4591064	0.06
488.0189819	2.28
489.1295776	1.19
493.3662720	0.04
504.0140381	0.04
505.2509155	0.55
506.1554565	0.16
510.7131958	0.07
511.4426270	0.13
516.6575317	0.26
517.2855835	0.09
519.9890137	0.06
536.1776733	0.09
542.3157349	0.19
549.6052856	0.60
550.3790283	0.06
551.1071167	0.23
552.2224731	0.36
559.3588257	0.21
567.2767334	12.98
568.2748413	5.95
577.1367798	22.42
578.1693115	8.43
578.8647461	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
150.9515839	2.11
152.8565521	0.13
160.9672546	0.38
162.973877	0.43
163.9075775	0.08
164.9226379	0.51
168.9439545	0.45
171.0857239	0.10
172.9645081	0.17
174.1740417	0.25
175.034668	0.20
177.0347748	0.15
179.0267334	1.67
179.7857056	0.12
181.1124573	0.09
184.6646423	0.15
187.0148315	0.15
189.2183533	0.25
190.9141541	0.33
192.0310669	0.10
193.0286255	0.02
197.0407257	0.05
202.9771271	0.39
205.455368	0.06
207.1271057	0.16
213.1173859	0.13
217.1139679	0.06
220.848938	0.13
223.1087341	0.59
225.1991272	0.14
227.0651093	1.54
229.09375	0.39
231.1021423	0.08
233.1594238	0.05
237.1577148	0.22
238.8728333	0.39
240.2404785	0.09
241.0744324	0.44
241.6959229	0.10
242.9000854	1.30
245.100769	0.31
249.0655212	0.03
252.9682312	0.05
255.0229797	8.16
256.1215515	2.12
257.0289001	0.87
259.0128479	0.24
265.1951599	0.35
266.1162109	0.09
267.2424927	0.49
269.0637512	1.50
269.9274597	0.47
271.1183777	0.22
273.0410461	0.09
275.278717	0.03
279.1383667	0.15
281.1292114	0.47
282.2273865	0.16
284.0505371	73.72
285.0440063	100.00
286.0321045	1.20
287.1352844	0.15
289.2047729	0.05
291.2330322	0.07
295.1752319	0.27
296.9856567	0.30
299.0126038	2.93
301.1928711	0.22
302.1579285	0.31
303.1290894	0.81
309.1222534	0.21
311.2144165	0.34
312.8703003	0.06
314.3460693	0.17
315.0804443	0.10
317.199585	0.08
320.0734863	21.17
321.1328735	2.51
323.1040649	0.15
327.1178894	52.02
328.1450806	0.67
329.2123413	0.12
330.1716003	0.10
331.6885681	0.07
337.4717407	0.35
339.4194641	0.08
340.4388428	0.04
342.0815735	0.36
351.1201477	0.05
357.1290283	9.63
359.0699158	0.23
360.9111938	0.05
362.1760559	0.04
366.3152161	0.13
369.0531921	0.35
383.3055725	0.19
385.1556091	0.13
387.2868347	0.38
393.0292358	0.32
399.1742249	0.12
400.9519348	0.21
402.460022	0.08
403.118927	0.44
404.3865662	0.31
410.3360291	0.10
411.1687927	1.14
417.00354	0.12
419.0889587	0.68
428.0906372	0.43
429.200592	1.33
432.1556091	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0978
Annotation	5,6-Dihydroxy-7,8,4'-trimethoxyflavanone
Peak:m/z	Relative Intensity
98.9286957	0.04
106.9590225	0.02
108.9381409	0.28
111.0896072	0.32
122.9023819	0.53
124.9584274	8.48
125.7419586	0.06
133.0037994	0.04
136.9833679	1.14
138.6676331	0.10
145.1316528	0.10
149.2857666	0.09
151.0505981	0.12
152.9028931	0.42
154.9455566	1.91
162.9252014	0.06
165.0767212	0.05
167.0150757	9.19
177.0712280	1.48
177.9772339	0.15
179.0144653	2.39
180.1925964	0.05
181.1236267	0.13
189.1008301	0.39
190.7498932	0.10
193.0710907	0.45
194.9937592	0.24
197.0518188	30.97
198.1118164	0.15
198.9280090	0.02
200.4131012	0.21
201.0551758	0.10
203.0265198	0.17
205.0938416	0.35
209.1550903	0.44
210.3656158	0.17
221.0160828	2.08
229.1731567	0.21
231.1593018	0.76
232.9559631	0.06
234.8296204	0.16
239.1358337	15.94
241.1338806	0.04
243.1190491	0.10
244.9328003	0.11
246.8492737	0.03
249.0204163	0.04
251.0056152	0.33
252.3015747	0.12
255.0668945	0.07
257.0571289	0.16
259.1543274	0.33
271.0188904	0.46
273.0340576	100.00
274.0768127	0.46
275.6831665	0.07
281.1323547	0.03
283.0590210	1.31
285.1282349	15.65
286.0677490	0.09
287.0279541	1.31
287.7770386	0.03
291.4131470	0.10
299.1990662	0.54
301.1047974	1.67
301.9444580	0.03
302.9513550	0.07
309.1013489	0.77
312.2013550	0.05
315.1048889	6.76
317.0090332	0.21
326.0917969	0.13
327.0824585	17.90
328.0245361	0.09
329.0510864	0.06
330.0682983	0.17
330.6903687	0.03
345.0082092	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.2771
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
163.0863037	0.30
169.1238251	0.05
171.0736542	0.10
172.9458923	1.08
175.0670929	0.21
177.0067444	0.08
183.2120667	0.16
184.9317627	0.18
186.3564148	0.09
186.9692993	0.57
189.1718750	0.25
190.9472809	0.11
194.2567444	0.10
195.1319885	0.03
197.0307770	0.10
199.1682892	0.60
201.1384888	0.12
205.0566711	0.19
211.0010376	0.19
213.0203857	0.47
215.1363831	0.56
219.3011169	0.14
225.0712585	0.29
227.3493195	0.17
229.1163483	0.14
231.0736694	0.03
233.2455444	0.28
235.1092529	0.22
236.1527710	0.03
239.0761871	0.35
240.6383057	0.08
241.3802795	0.15
242.6266174	1.40
243.2376556	13.48
245.2325592	0.62
249.1597900	0.19
251.2940369	0.09
253.4330597	0.05
255.4104156	0.18
256.1895752	0.09
257.2904663	0.40
259.0052795	0.31
261.2066650	13.23
263.2202148	0.25
265.1923218	0.10
271.5210876	0.17
273.1361084	0.25
275.0681152	0.23
277.2590942	0.75
279.1394653	0.62
281.2491150	0.88
291.1779175	0.51
295.1696167	0.06
297.2966309	0.15
299.1863403	3.30
305.3299561	0.59
307.1780396	0.07
310.6927490	0.10
311.4844360	0.04
315.0003662	0.50
317.2651367	22.21
318.7274170	0.03
319.4618530	0.05
323.9781494	0.08
331.0197144	0.05
332.9642944	0.11
335.3019409	100.00
337.3185425	1.18
347.1076660	0.06
353.3381958	0.70
359.1975098	0.27
369.5949707	0.08
373.3122559	0.09
397.0934448	0.07
405.1529541	0.44
407.7225952	0.24
408.3759766	0.11
409.1670532	0.19
413.4231567	0.25
415.2224121	9.33
417.3505859	0.09
419.4393921	0.09
423.2433472	3.00
426.2030640	0.05
426.9302979	0.16
433.0618896	0.25
436.9330444	0.56
439.0029907	0.07
440.9031982	0.03
445.3838501	0.24
451.3253784	0.03
454.0017090	0.14
457.9210815	0.22
461.0274048	0.43
463.3711548	0.29
465.2326050	0.14
467.4962769	0.09
468.8289185	0.24
470.2038574	0.46
473.0777588	0.06
477.0995483	0.23
478.9753418	0.26
482.6001587	0.07
485.3795166	0.39
487.0734253	0.41
487.9368286	0.21
493.3999023	0.36
494.9135132	0.88
503.2382812	0.17
505.0958862	0.16
507.1786499	0.31
512.4379272	0.77
513.2316895	0.37
519.3660278	0.18
523.4872437	0.09
530.1659546	0.34
531.0485229	4.93
532.5161133	0.06
534.0588989	0.10
535.3796997	0.07
549.2061157	0.20
559.1889648	65.05
559.8698120	0.35
577.2901001	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.2733
Annotation	2-oxo-nonadecanoic acid
Peak:m/z	Relative Intensity
89.0317841	0.71
90.7388840	0.94
92.8808746	1.38
94.9576569	35.40
97.0015717	11.98
98.8624268	2.71
100.9678192	0.83
102.9924927	4.13
106.8478699	0.31
108.9639740	42.42
110.9339676	7.22
113.0486526	0.46
116.9790649	4.08
119.1213379	0.37
120.9051056	0.78
123.0785751	29.75
124.8482513	3.85
126.7761612	1.90
128.7769470	0.61
131.1550140	0.81
132.8619995	0.96
134.9178162	1.66
136.9649811	14.84
138.9562073	3.01
142.8815613	1.96
145.1265259	1.68
147.0261841	0.80
148.0258484	0.18
149.0345306	1.48
151.0682678	7.04
153.1261444	0.51
155.1353149	0.43
157.0731201	0.56
159.0817566	2.10
163.1908569	2.19
165.0468140	7.00
167.1269836	0.62
172.3945770	0.26
173.0762634	1.95
175.1838989	0.75
177.0794830	0.87
179.1757507	1.53
181.0957642	1.56
182.9101257	0.68
184.8322754	1.25
187.0124054	4.27
191.1825562	0.37
193.1797638	0.13
194.5928955	0.09
195.2052002	1.66
197.1480408	0.70
201.2051086	2.73
208.9400330	0.22
211.0235596	1.63
215.1094360	0.90
217.0616455	0.14
219.2823181	0.43
221.0989075	7.36
231.1225281	0.15
235.2895508	0.60
237.2751770	0.82
239.1050720	25.32
241.3096619	0.17
242.8908997	0.15
249.2377319	1.04
253.2176208	0.18
254.0571899	0.14
257.2492371	100.00
259.1381836	0.13
263.2421265	0.58
267.2991333	4.26
268.0763550	1.14
269.0756226	1.39
270.1064453	0.13
270.9130554	0.67
271.9112549	1.44
277.1333008	1.40
284.1655579	0.84
290.0674744	0.79
293.1210938	0.61
295.1580200	7.95
298.0397949	0.97
313.6694641	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1613
Annotation	Safflomin A
Peak:m/z	Relative Intensity
177.1089935	0.11
189.0466156	0.25
193.1083679	0.05
199.1489563	0.90
203.2776642	0.08
207.1443634	0.17
209.0756531	2.37
214.7923584	0.09
217.1828308	0.04
229.1262512	0.28
233.1571808	0.17
234.9864349	5.14
239.0258789	0.10
241.1234741	1.19
251.1366577	1.14
256.9136963	0.34
259.0701294	0.26
263.3494568	0.05
269.1287231	10.44
270.8330078	0.05
276.9925842	0.22
279.3846130	0.11
280.4820557	0.12
285.0936279	16.83
300.3283691	0.24
301.1566162	0.15
303.0313721	0.74
311.1782837	0.12
329.0966187	100.00
337.1832886	0.92
342.1228027	0.14
347.1480713	0.28
353.3497314	0.48
357.4680176	0.11
359.3504639	0.63
366.7453003	0.06
371.0826416	4.62
382.9104614	0.13
391.0741577	0.23
393.9793701	0.09
395.2181396	0.88
411.4555664	0.12
413.0612793	7.21
427.1262817	0.26
431.0856323	38.84
434.1044922	0.07
447.1770630	0.10
448.3362427	0.92
449.2621460	8.69
459.1304932	1.95
462.1393433	0.11
485.1928711	4.07
487.2283936	0.04
489.0561523	0.38
491.0470581	0.51
492.1176758	0.48
501.1008301	1.08
503.2212524	0.37
506.0267334	0.28
517.0603638	1.05
519.8099365	0.11
521.0614624	5.69
521.7584839	0.05
530.4165039	0.26
534.1748657	0.23
537.5054321	0.13
539.0787964	0.09
549.8281860	0.10
550.9678345	0.10
557.8764038	0.12
562.7478638	0.20
565.6229248	0.39
566.4717407	0.38
567.4035645	0.64
573.9048462	0.11
575.1925659	0.05
593.1528320	7.65
594.1582031	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1089
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
151.0471191	0.04
161.0862885	0.03
163.7934875	0.02
177.0823975	0.03
192.1461487	0.07
193.2823792	0.02
203.8971100	0.02
209.1709595	0.02
222.0629578	0.03
231.1168976	0.09
241.1346436	0.03
247.3072205	0.03
255.0360413	0.09
263.1589661	0.03
267.9360046	0.05
269.1921997	0.18
271.0958862	0.03
273.4814758	0.02
277.4479980	0.02
281.2622986	0.03
283.0572510	1.66
284.0578003	7.62
285.1335449	0.93
286.1218262	0.07
294.7286377	0.05
297.1279297	1.15
298.1887817	13.65
299.0489502	100.00
300.0696411	4.65
301.1734314	0.10
306.1604919	0.02
308.1148682	0.12
309.0624390	0.03
311.1492004	0.12
312.0545959	0.06
313.0595703	3.10
314.2037354	0.34
315.1568298	0.03
321.0464783	0.36
323.1596680	0.16
326.1124268	0.37
327.2174072	0.26
328.0046387	0.13
332.1578979	0.03
337.3270874	0.04
338.8508301	0.21
340.0497131	0.05
341.0588379	4.76
342.0616455	0.09
343.1453247	0.09
344.4031067	0.12
345.1221313	0.15
353.3086853	0.16
355.5803833	0.11
356.2229919	0.25
365.1923828	0.57
366.1890259	0.03
371.1785889	0.59
372.1241455	0.08
373.8151550	0.07
382.2268982	0.07
395.1971741	0.03
398.3893738	0.08
399.2672119	0.08
400.1113586	0.18
401.2654419	0.13
413.1735229	0.14
414.3256531	0.05
415.2275085	0.45
416.3320923	0.03
417.3505554	0.09
418.5648499	0.05
419.2565308	0.13
425.8858948	0.03
428.1382141	0.07
429.3182678	0.18
432.3049011	0.02
433.0873718	0.23
441.2836609	0.01
442.3536682	0.17
443.2419434	0.21
446.1263428	73.12
447.0881348	4.79
447.7596741	0.03
451.5440063	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1614
Annotation	Galactotriose
Peak:m/z	Relative Intensity
142.9983063	4.11
149.0692749	0.36
154.9837952	0.67
160.9916382	13.12
166.9692230	0.48
177.0064850	0.39
178.9901733	100.00
184.9221191	0.53
212.0563049	0.29
221.0225220	64.56
233.0783844	0.59
247.3957062	0.13
250.6739197	5.34
263.1147766	1.35
278.1962891	0.42
280.7289124	8.23
281.3972168	0.16
305.0591431	1.87
310.5417480	1.23
311.1723938	3.57
322.0325012	0.23
323.0423584	20.26
340.9739380	27.83
359.0042725	0.23
383.0291443	0.92
441.3631592	0.21
443.1133423	0.82
484.9983215	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.0861
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0928040	0.60
126.9277954	1.05
132.9472656	1.65
135.0300598	0.62
145.0747223	0.29
146.9173889	0.30
150.8298950	0.88
159.1820984	0.12
172.9192810	0.06
178.9375153	100.00
180.0433350	0.15
183.0086060	0.09
212.9232483	0.22
230.8645477	2.66
234.2854004	0.04
237.0409241	0.16
242.7887573	0.15
247.0683899	0.14
255.3146057	0.13
263.1330566	0.42
265.0871887	0.48
269.2641602	0.13
280.0400391	0.08
281.9909363	0.08
287.1464233	0.08
301.1417542	0.07
307.1190186	0.07
313.1831055	0.07
315.2062683	0.21
319.2586060	0.06
320.9556885	0.12
327.3395081	0.22
331.1787720	0.17
332.9542542	0.09
338.1381226	0.07
339.0982666	0.05
341.0249023	0.83
344.6437073	0.35
345.7924194	0.89
349.2747192	0.50
353.2043762	0.26
355.1828613	0.26
358.6825867	0.09
362.3437195	0.38
363.2592468	0.09
364.2655945	0.10
364.9742737	0.10
367.1278992	0.24
367.9220886	0.23
368.8221130	0.37
372.4859314	0.13
374.4991455	0.10
379.0062561	0.34
379.9230042	0.09
383.0359802	0.10
385.0208130	0.23
386.0968933	0.53
390.3235474	0.16
398.0511169	0.53
403.8374939	0.29
408.8522339	2.55
409.4998169	0.56
410.2934265	0.19
412.1114502	0.04
417.6229858	0.42
427.5056152	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1639
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
190.2261963	0.03
215.1876831	0.09
239.2551575	0.08
243.0989532	0.04
248.8769836	0.05
251.0916443	0.03
267.1882935	0.19
271.0454407	1.99
283.0564575	7.01
284.0781555	0.10
295.1969604	4.46
303.0324097	0.08
304.0429077	0.06
306.8201294	0.15
309.0378418	0.08
310.9952698	0.31
313.0871887	91.03
314.2003174	0.05
323.0234375	0.14
337.0861206	14.09
337.7221069	0.13
339.3289795	0.27
343.2862549	0.19
349.0681763	2.84
351.0811157	0.19
355.1356812	0.06
361.2620850	1.53
367.1334839	55.22
379.1714478	13.69
393.4316406	0.07
394.2005615	0.10
397.1394653	26.46
399.0376587	0.23
409.2827148	0.12
415.1170044	100.00
415.9303589	0.12
417.2101440	0.42
433.0617065	55.04
433.6722412	0.08
439.4841919	0.05
441.4208374	0.26
448.2589111	0.06
449.2621460	0.26
457.2189941	0.24
462.9954224	0.16
467.1471558	0.10
468.5609741	0.13
475.1852417	0.09
481.4017944	0.23
514.0031128	0.23
541.1325073	0.09
548.1992798	0.07
548.9746704	0.05
550.9157715	0.23
558.9862671	2.84
559.6205444	0.13
572.3801880	0.11
577.1311646	58.14
577.7601929	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.0614
Annotation	Linderoflavone A
Peak:m/z	Relative Intensity
120.9977341	0.04
131.9646912	0.03
133.0429382	0.47
137.0508881	0.09
143.1657104	0.04
146.0988159	0.14
148.7273102	0.05
152.8132019	0.16
158.9720764	0.11
161.0624084	0.07
163.1822815	0.04
169.0300903	0.17
170.8172302	0.11
174.9871521	0.26
176.9067688	0.27
179.2136230	0.10
181.0742188	0.09
181.9133301	0.13
195.1751556	0.12
203.0679169	0.63
205.1611023	0.14
207.1505432	0.51
213.1489258	0.09
221.0455017	0.17
224.3470154	0.04
227.0399475	0.15
229.0851440	1.33
229.9306641	0.04
231.1496582	0.13
235.0746155	0.09
240.5037842	0.08
241.2650146	0.17
242.1151123	0.12
247.0534058	0.15
253.0670166	0.05
256.2837524	0.09
261.1442566	0.19
266.2022705	0.31
267.2552185	0.15
271.5267334	0.02
272.9016724	0.02
273.5563354	0.10
277.0470886	0.06
280.1444092	0.05
282.2666016	0.03
283.1257019	0.40
285.0419006	68.49
286.0639954	2.94
293.0806274	0.12
295.2438660	0.43
296.0341492	0.07
297.0320435	100.00
298.0886841	17.00
299.0157471	6.53
300.2155762	0.28
309.1320801	1.40
311.0940247	11.17
312.1317749	1.74
313.1864014	0.68
314.1705322	0.14
321.1656494	0.29
324.1089783	1.65
325.1031494	0.92
327.0580750	12.09
328.1325378	1.24
329.1891174	0.21
337.1428833	0.26
339.0546875	79.92
340.1640320	6.79
341.2285156	0.04
342.2390442	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.0875
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1525803	0.08
109.0481567	0.07
110.0184250	0.04
118.0496826	0.12
135.9136353	0.98
137.0118103	2.73
154.0206299	100.00
164.8159180	0.07
172.9807129	0.53
194.6764526	0.06
209.9835205	0.65
254.2709045	0.05
260.9321899	0.06
262.9173584	0.38
297.3237000	0.03
300.8866272	0.22
302.2365723	0.06
302.8405457	0.18
303.6635742	0.07
309.1034546	0.21
312.1288452	0.06
329.1036072	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9539
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9471283	0.55
184.0218811	0.12
235.3704834	0.10
265.3472595	0.08
267.0656738	0.07
270.8984985	0.31
272.0641174	0.19
300.0283203	0.56
309.0646362	1.63
309.9525452	0.42
310.9949951	6.61
311.9670410	1.44
326.1831970	0.04
326.9448853	0.19
328.8715820	0.49
330.0687256	0.17
350.9554443	0.59
351.8274536	0.59
353.8191528	0.05
361.2056580	0.05
364.8739014	0.14
368.8252258	0.78
369.8788452	0.33
378.9789734	3.06
379.7651367	0.25
380.8673706	1.92
381.9214172	0.27
383.1914673	10.83
383.8790588	100.00
384.9726562	0.13
388.3125000	0.34
397.0038757	1.17
398.1338806	0.08
399.4602661	0.04
400.3287659	1.28
401.2776489	16.64
402.1834412	0.11
404.4647522	0.26
406.7063904	0.24
407.3436584	0.11
411.0364075	0.25
412.3667603	0.54
423.8786011	0.15
425.0163879	0.27
432.6919250	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	560.1754
Annotation	Unknow
Peak:m/z	Relative Intensity
173.9495850	0.05
208.5953369	0.01
222.9616241	0.04
226.9765320	0.03
257.8178711	0.03
273.1328735	0.04
306.3846130	0.05
308.1922607	0.03
309.2212524	0.01
311.9046631	0.09
322.1522217	0.07
334.2479248	0.03
336.3884277	0.01
338.4328003	0.03
339.4035034	0.03
342.2219849	0.04
344.4213257	0.03
348.2644653	0.02
354.6372070	0.02
362.8826904	0.25
366.1956177	0.10
367.1160889	0.07
371.1409912	0.06
378.0689697	0.27
379.2830200	0.04
380.2102661	0.19
381.3997192	0.02
389.2778931	0.06
393.4525757	0.16
395.3842163	0.04
396.5933838	0.23
397.5015869	0.09
398.1694336	0.20
408.2498169	0.08
410.1040039	0.07
411.1580811	0.02
412.3175049	0.02
414.1094360	0.16
415.0847168	0.32
418.0124512	0.05
420.3007202	0.80
421.6040649	0.05
422.2400513	0.16
425.1730957	0.05
425.9146729	0.04
427.1902466	0.12
428.0980225	0.03
429.3949585	0.08
430.0266113	0.10
431.9362183	0.03
434.1352539	0.19
438.1529541	0.02
440.1363525	2.64
441.1113892	0.07
442.1645508	0.04
445.0942993	0.77
446.1390991	0.04
447.5759888	0.05
450.1605225	0.74
451.1626587	0.05
454.2036133	0.10
457.1417236	0.08
457.9367065	0.06
459.5546265	0.06
460.5183716	0.14
462.2585449	0.86
463.0941162	0.14
464.2382812	2.29
466.3314819	0.15
468.1765137	0.07
470.2291870	0.29
473.9193115	0.06
478.2640991	0.11
480.2052002	2.76
481.4132080	0.31
484.2351685	0.04
485.2820435	0.02
486.1729736	0.04
487.8999023	0.15
490.7299194	0.11
493.7211914	0.48
494.3630981	0.40
497.0034790	0.32
498.2239380	23.58
499.0086060	0.09
500.0846558	0.11
501.0065308	0.14
501.7177124	0.12
504.1405640	0.02
506.3076782	0.02
507.1436157	0.07
510.2532349	0.02
511.0836792	0.10
511.8824463	0.01
512.8875122	0.06
514.0591431	0.14
515.1319580	0.04
516.2992554	0.68
519.1403198	0.02
520.9402466	0.10
523.0023804	0.02
524.1402588	2.78
524.7683105	0.03
526.1749268	0.04
528.1956177	0.04
542.1911011	100.00
543.2645264	0.09
559.0161743	0.06
573.0640869	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.21
Annotation	Carnosic acid
Peak:m/z	Relative Intensity
97.0623703	0.29
98.78691864	0.18
109.9354782	0.28
110.9335251	0.79
115.7734299	0.43
118.92659	0.18
121.8782654	0.09
123.0605087	0.32
124.9335175	0.25
128.0320435	0.68
132.8625488	0.90
134.9675446	0.25
136.9080505	0.77
148.7129211	0.13
153.212616	0.26
154.9094543	0.71
162.8040161	0.37
165.0835876	0.19
170.9769287	0.66
175.2185822	0.18
176.7970734	0.53
179.0015869	0.09
182.9090271	0.70
185.2412109	0.51
188.9948273	0.17
191.2924042	0.16
192.9240417	0.65
195.153717	0.20
198.7641754	0.24
199.8046417	0.57
207.3521118	0.23
208.7501831	0.94
209.8417969	0.32
211.1818542	0.38
212.9729614	0.20
217.3366699	0.83
219.0750427	0.19
221.1016235	0.35
223.2070923	0.36
224.8147278	0.68
227.0274658	0.89
233.1864624	0.24
234.9926147	0.14
239.1327209	1.03
240.2288818	0.18
241.1171265	1.37
243.3148193	0.78
245.0397339	0.54
247.0937195	0.88
249.1539001	0.59
251.1315308	0.68
254.683075	0.79
255.9979248	0.62
257.206543	2.01
259.0489502	1.99
261.1503601	0.31
262.149353	0.71
263.2738647	0.17
269.1329956	9.47
271.2384949	7.36
273.2338562	0.72
275.1483154	0.89
277.0047913	1.52
279.2303162	0.28
281.0932312	0.33
282.9128418	0.31
284.6714478	0.29
287.1932373	100.00
288.1899109	1.12
289.243042	0.87
291.2877808	1.72
292.1573486	2.74
297.1251526	7.45
298.5057983	0.40
300.9769592	2.45
303.5393982	1.37
305.1401062	2.86
310.7103577	0.64
312.4139404	2.78
315.0154114	45.38
315.8683777	3.03
316.5970764	0.96
318.5483093	0.63
324.0278931	2.82
332.3737488	0.36
333.1797485	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.4645
Annotation	PA(16:0/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
189.2117004	0.08
241.2198181	0.41
255.2478333	95.86
256.2280884	1.72
257.2729492	0.22
261.4833679	0.42
263.2987061	0.06
277.3676147	0.67
278.2445068	1.07
279.3171082	41.31
297.0933838	0.09
313.4396362	0.16
322.3003540	0.15
327.0437622	0.36
329.5213013	0.11
330.2055969	0.53
331.3141479	0.21
339.2244568	0.71
339.9961548	0.58
340.6019287	0.19
356.4535522	0.11
357.2570801	0.08
359.4708862	0.16
367.7501831	0.04
371.2463379	0.06
381.4830933	0.17
385.1163330	0.30
387.3544922	0.60
388.2350464	0.13
389.9810181	1.48
391.1871338	100.00
392.2009277	1.58
393.1408691	0.39
395.2015991	0.13
397.1757202	0.26
406.3439331	0.17
407.5819702	0.25
409.2343750	45.10
410.2897949	0.72
411.4401855	0.33
412.7326050	0.30
415.1503296	29.10
416.4926147	0.21
417.3818970	0.21
419.5513306	0.29
421.5294189	0.23
431.1177979	0.27
433.0003662	3.46
433.6547852	0.63
435.2723999	0.08
459.4699097	0.33
460.8526611	0.19
479.0577393	0.14
485.6752930	0.42
495.8243408	0.13
504.2414551	0.22
513.5416870	0.18
517.5391235	0.15
524.0609741	0.23
541.4132690	0.06
551.2974243	0.14
552.7013550	0.11
566.7911987	0.61
567.6204224	0.07
568.2597046	0.06
579.6822510	0.35
581.2598267	0.08
604.7343140	0.06
608.2856445	0.19
615.3621216	0.09
625.2537231	0.06
626.9602661	0.75
627.7092896	0.15
632.9587402	0.14
635.8057251	0.78
652.4306030	0.87
653.4284058	1.56
654.4530029	0.13
655.9733276	0.11
657.4801636	0.36
670.7080078	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	237.0404
Annotation	6,8-Dihydroxy-5,7-dimethoxycoumarin
Peak:m/z	Relative Intensity
70.9249268	0.24
74.8850174	0.06
76.9520874	0.19
89.0733032	0.02
114.9976501	3.63
117.1098328	0.04
120.9055786	100.00
121.9629211	0.03
134.8645477	0.08
159.0815277	0.02
175.1239929	0.02
181.4559784	0.01
182.3514862	0.05
183.1684723	0.06
191.1766205	0.03
191.8860016	0.02
192.9802856	0.05
196.0964966	0.09
204.9783325	0.04
208.4141693	0.10
215.0936432	0.06
217.4211273	0.40
218.4612579	1.51
219.1639557	0.33
221.0329132	0.11
221.6850739	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1663
Annotation	Spinosin
Peak:m/z	Relative Intensity
193.0723877	0.04
226.9410706	0.02
247.1409149	0.02
249.0343170	0.01
255.9096069	0.06
273.2620239	0.01
284.0222778	15.93
285.1680298	0.08
299.0254517	100.00
300.0315552	0.03
313.2843018	0.04
320.3134766	0.02
321.3067017	0.02
323.0633545	0.03
326.3889771	0.04
327.9054565	0.01
329.3120117	0.02
333.2979736	0.03
339.5422363	0.09
340.1773682	0.01
341.0909424	0.12
343.4636230	0.02
353.1941528	0.01
354.0898438	0.02
355.0157471	0.05
357.1926880	0.01
358.2316284	0.01
359.4257812	0.04
360.1538086	0.02
365.2274170	0.01
372.0419312	0.01
384.0636597	0.08
400.0736084	0.03
402.0573120	0.08
403.1441040	0.15
411.1834717	0.06
417.3638306	0.01
426.7903442	0.07
437.3836060	0.04
445.1939087	0.02
446.3251953	0.03
447.7687378	0.02
452.3978271	0.01
469.3051147	0.06
472.0475464	0.07
485.4614868	0.06
486.1723022	0.25
487.0980835	0.30
488.2228394	0.03
507.2440796	0.01
509.4891357	0.02
513.2474365	0.02
516.1255493	0.08
517.4134521	0.13
525.3166504	0.06
532.0556030	0.04
533.2251587	0.03
543.3195190	0.12
547.0215454	0.04
552.1579590	0.01
560.3808594	0.04
561.1953125	0.38
562.1360474	0.05
562.9772339	0.24
575.0650024	0.09
577.2171021	0.06
588.4436035	0.21
589.2997437	0.17
590.3146973	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.239
Annotation	Cichorioside L
Peak:m/z	Relative Intensity
159.0617065	0.03
160.9770203	0.21
178.9726105	0.21
186.0970764	0.09
204.0461273	0.05
214.9306946	0.02
229.2927399	0.07
255.2244873	0.10
256.2062378	0.02
271.2639771	0.07
273.1600952	0.01
289.1054077	0.36
290.2802124	0.19
291.2212524	0.41
292.0167847	0.26
298.9179382	0.20
307.3723755	0.28
308.2391968	0.06
315.3899536	0.02
317.3642578	0.49
318.1703491	0.09
333.1744995	37.27
334.1943359	8.16
335.2454224	1.65
336.3496704	0.76
342.0076294	0.18
342.9620972	0.04
345.2145386	0.03
351.2304688	22.13
352.3247070	4.77
359.0647583	0.04
361.2336426	2.88
362.1716309	0.37
375.2493286	0.04
376.9586792	0.07
379.1860962	7.30
380.2959595	1.64
392.3599243	0.05
395.1275635	0.14
397.0190430	0.18
398.5099487	0.02
406.4163818	0.11
412.1557007	0.09
415.6791382	0.04
420.7993774	0.05
423.3748779	0.07
439.2570801	0.04
440.3255005	0.08
445.3812256	0.08
449.4660645	0.13
450.3031006	0.11
451.2479248	0.19
452.3883667	0.12
462.2243652	0.02
463.1978760	0.04
466.7343140	0.03
478.1918945	0.07
479.4176025	1.03
480.1240234	0.78
488.3828735	0.03
492.1943970	0.03
495.3190308	2.68
496.4100952	1.16
497.2871704	3.84
498.3611450	0.51
511.1320801	0.18
513.2788696	48.26
514.2893066	12.94
515.3013916	3.62
516.2443237	0.90
517.1188354	0.06
523.2948608	0.49
524.3955688	0.18
530.1448364	0.05
532.3930054	0.02
541.2344360	100.00
542.3301392	32.36
551.2160034	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.2088
Annotation	Aerucyclamide C
Peak:m/z	Relative Intensity
155.1733093	0.26
160.9816284	0.23
172.9896545	100.00
178.8633423	0.43
236.2639160	0.05
292.7696533	0.09
323.2467041	0.06
334.8637695	0.08
341.1428833	41.97
342.3558960	0.13
349.1708374	0.07
377.0921631	2.49
378.1823730	3.26
397.9308472	0.06
401.1311035	0.06
426.9873047	0.13
430.8963623	0.04
454.9968872	0.18
468.9366455	0.15
496.2080688	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.8691
Annotation	Unknow
Peak:m/z	Relative Intensity
143.8264313	0.05
171.8913879	0.05
201.1060486	0.17
240.9389191	0.06
272.8406982	0.43
291.1240234	0.11
298.1281738	0.16
298.9600220	0.07
302.0171509	0.08
305.9664917	0.19
312.8484497	3.42
314.9184265	2.81
317.0588684	0.15
324.0625305	0.03
328.0079346	0.04
330.8084106	0.17
334.1458130	0.09
339.1697998	0.20
340.1118164	0.16
341.1088257	0.38
341.8289185	0.17
342.9063416	0.97
343.9505615	0.41
349.9263306	12.05
354.2943115	0.12
354.9125977	0.09
356.8445435	100.00
357.4456787	0.37
358.1578979	0.07
368.9716187	0.08
371.4504089	0.65
372.9543152	0.18
382.0640564	0.05
382.9438171	0.15
385.1463318	0.32
391.1774597	0.06
393.6665344	24.43
394.3785095	0.25
398.5373230	0.37
400.8294983	81.03
410.9792786	0.04
417.0252075	0.13
417.8079529	0.06
422.3467712	0.18
425.9255371	0.19
427.0912170	0.08
427.8890076	0.06
435.7634583	0.74
436.3742065	0.30
442.5087280	0.27
443.1405945	0.19
444.3733215	2.53
444.9863281	1.60
456.9695435	0.06
460.5932922	0.39
461.3476562	0.04
466.2097778	0.10
467.3483276	0.12
469.9021301	0.57
470.9875183	0.83
479.6659241	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.3072
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9346466	0.03
255.0461731	0.08
279.0021362	0.23
287.3146362	0.14
311.1728516	0.02
336.1483154	0.04
343.0983582	0.08
387.0810547	0.04
418.2009888	0.03
424.0852051	0.05
431.1153564	0.64
445.2348022	0.07
454.8803711	0.03
462.3352051	0.07
475.3101196	0.08
483.5465088	0.09
491.2021484	0.05
503.1906738	0.25
506.6261597	0.11
508.3513794	0.09
522.3244019	0.03
523.1311035	0.07
527.2539673	0.29
531.3517456	0.23
535.9559326	0.03
537.3937378	0.03
538.2224731	0.10
542.3543701	0.06
548.8787231	0.02
550.2430420	0.21
553.2175903	0.21
555.4418945	0.02
565.1726685	0.02
567.2221680	0.08
573.3388062	0.09
579.0571289	0.05
581.2905884	0.02
591.4387207	0.05
598.1785278	0.03
600.1535645	0.03
615.2545166	0.02
620.0671997	0.14
621.4955444	0.05
625.4097290	0.33
627.1205444	0.02
633.1920166	0.09
646.3425903	0.07
647.7766724	0.04
648.9999390	0.03
650.6206665	0.07
651.4026489	0.04
655.3889771	0.12
660.4201050	0.03
661.4757080	0.09
665.3286743	1.52
667.3074341	100.00
668.0219116	0.12
673.3275757	0.19
674.1935425	0.12
675.2559204	0.15
676.2582397	0.10
679.3934937	0.08
688.3162842	0.26
691.5686035	0.06
692.3622437	0.18
693.3126221	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	881.2527
Annotation	Unknow
Peak:m/z	Relative Intensity
292.7120361	0.19
376.3985291	1.21
391.9685059	0.50
435.7642822	1.49
458.6811523	7.20
460.5787354	8.38
542.4138794	17.60
543.9224243	2.18
544.6015015	30.20
557.2291870	1.09
626.4895020	9.38
628.2322998	11.62
628.8462524	0.41
667.4144287	0.16
687.2499390	11.46
706.1242065	0.90
710.4523315	8.20
712.1474609	36.70
713.2615356	1.42
719.4033813	10.93
794.1235962	5.47
795.5694580	8.04
796.2865601	100.00
834.1075439	0.79
838.4541016	1.09
839.2471924	0.19
866.8317871	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
101.0205231	0.44
148.7737274	0.46
164.8372955	0.34
169.0279236	0.35
172.9625092	1.67
174.0999908	0.63
178.1067047	0.70
181.8504791	0.19
182.8359985	0.38
189.1720886	0.40
195.3184509	0.29
207.0212555	8.39
207.9983063	5.44
209.1867523	3.30
210.3611603	0.48
214.993927	0.40
215.9721832	0.58
222.1217651	3.18
222.9994354	11.93
224.1276245	2.31
230.9893646	0.93
233.1600342	5.21
251.064743	100.00
252.0792389	12.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1508
Annotation	Datiscin
Peak:m/z	Relative Intensity
166.9477234	0.01
169.1791992	0.05
170.8691101	0.05
175.0406799	0.06
178.8557587	0.06
182.1009216	0.19
183.1113586	0.10
184.0756378	0.02
185.1387634	0.16
186.0514679	0.03
187.1340942	0.47
188.0877075	0.01
189.0793152	0.03
191.0208588	0.05
193.2608795	0.03
195.0536194	0.34
196.0233154	0.02
197.2479858	0.24
198.0411072	0.06
199.0057983	0.17
200.0675354	0.10
201.0426025	0.02
206.901001	0.21
208.0264893	0.06
208.8552856	0.02
211.0686035	0.38
212.2362823	0.25
213.12146	0.62
214.121994	0.09
215.0507965	0.13
217.0796661	0.13
219.0853729	0.03
223.0243225	0.27
224.1537323	0.06
227.0076447	0.75
229.0079346	2.60
230.2110443	0.35
231.2117462	0.02
239.0887756	0.68
240.0707703	0.38
241.0760803	0.61
242.3321075	0.14
242.9894257	0.17
243.6030579	0.05
245.0253601	0.03
251.1724091	0.04
253.2209473	0.02
255.0930176	1.78
256.2319031	0.46
257.0770874	3.54
258.0444031	0.48
258.8460083	0.03
267.1088867	0.99
268.0868225	0.15
269.2936707	0.05
270.0495605	0.04
272.1009521	0.04
275.068573	0.02
279.2734985	0.02
281.3350525	0.01
283.8887939	4.15
285.051178	100.00
286.0391846	13.52
286.9923706	0.06
297.0267944	0.04
298.2400208	0.13
299.0487671	0.24
300.0170593	0.06
300.8201904	0.01
307.2185059	0.02
309.1460571	0.07
311.0131226	1.18
311.9524536	0.10
313.1906128	0.03
314.9702759	0.07
323.1442261	0.09
324.140625	0.03
325.0390015	0.06
327.081604	2.42
328.1567993	0.54
334.9881592	0.18
336.2151489	0.01
336.9039307	0.09
337.9879761	0.03
339.1331177	0.01
341.2408447	0.04
353.0848389	0.14
355.1784668	0.01
357.041687	0.40
358.2404175	0.10
368.6431885	0.09
383.2492676	0.01
388.1646118	0.06
393.3432617	0.08
394.270813	0.02
395.0667114	0.03
409.2602539	0.04
413.1708984	0.05
414.4754639	0.01
417.1292114	0.03
431.4030762	0.02
432.0113525	0.02
439.2675171	0.06
440.1824951	0.03
447.1903076	0.13
448.1467896	0.17
455.0424194	0.12
473.4094849	0.12
489.3743896	0.04
500.1161499	0.02
503.1891479	0.01
509.9896851	0.01
513.1831665	0.03
519.4971313	0.02
533.1810913	0.13
534.2802124	0.09
547.0541992	0.04
548.2446289	0.21
549.1938477	0.17
555.1946411	0.02
556.7862549	0.08
558.4614868	0.03
565.3217773	0.18
566.2853394	0.09
575.1896362	0.17
576.052124	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Isovitexin
Peak:m/z	Relative Intensity
148.886322	0.01
161.17659	0.02
162.0680847	0.01
175.0692444	0.01
176.9551849	0.01
179.0965271	0.03
180.3594666	0.02
192.905426	0.01
214.8547211	0.02
217.8248291	0.01
226.8711243	0.02
235.3315735	0.02
243.2387085	0.01
247.0871582	0.00
249.1378174	0.01
251.1607971	0.13
252.1753235	0.04
253.2226257	0.15
254.0453186	0.01
258.2489929	0.01
269.0455627	4.43
270.0172729	0.77
282.112854	0.04
283.19104	0.27
284.0272217	0.02
285.0498657	0.09
287.3390808	0.10
293.2685242	0.03
295.1300659	0.02
296.0180054	0.01
297.0740356	0.01
298.3574829	0.07
308.7608032	0.05
309.4005432	0.03
311.057312	100.00
312.0841064	23.23
323.1203613	0.31
324.2003174	0.06
325.1132812	0.04
335.0038452	0.03
335.8892212	0.01
337.1866455	0.19
338.2179565	0.04
339.1815796	0.01
341.076355	14.46
342.1778259	4.40
344.4602051	0.00
350.2498779	0.01
351.3771362	0.02
353.0891113	0.70
354.1071167	0.18
355.1945496	0.34
356.186615	0.05
364.0137634	0.13
365.2125854	0.08
366.03479	0.04
367.160553	0.11
369.211792	0.02
369.9012451	0.03
371.1316223	0.41
372.1385803	0.12
377.1662903	0.23
378.1622925	0.01
382.5461426	0.03
383.231842	0.51
384.2864685	0.12
385.1298523	0.01
386.2498779	0.02
387.108429	0.03
388.1674805	0.02
395.1316223	0.32
396.1595764	0.24
400.2185059	0.01
401.1243286	0.06
404.0665588	0.02
413.0768127	1.83
414.188324	0.81
427.2954407	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.114
Annotation	Robustaside B
Peak:m/z	Relative Intensity
123.7036591	0.03
138.4585419	0.09
139.1110687	0.21
143.2862244	0.02
147.1139069	0.06
153.0167542	0.06
157.0245667	0.03
158.9251709	0.04
161.0802002	0.09
167.2892456	0.05
175.0096588	0.17
179.1331787	0.11
181.8087463	0.02
183.0573730	0.78
185.0356445	0.02
189.2223511	0.12
190.8844147	0.03
193.1551208	0.06
194.0710754	0.07
195.2383270	0.03
205.0023346	0.10
206.6686096	0.02
209.9684906	0.03
219.1332092	0.02
225.2923584	0.20
227.0102539	0.55
228.1425323	0.09
229.1140137	0.02
231.0384064	0.73
235.3276367	0.28
243.0867615	0.02
249.1037903	8.47
253.1217041	0.44
256.1266785	0.05
267.0523071	6.91
267.7091370	0.06
269.1035461	0.04
269.9763794	0.12
271.1425781	4.61
278.8300781	0.04
283.9679565	0.02
287.2996826	0.06
294.0965576	0.03
295.1165771	0.07
301.8244019	0.03
309.2013245	0.03
311.0993042	4.13
312.0881958	17.60
313.1123657	100.00
320.2283020	0.45
320.9895020	0.16
323.1500854	0.12
324.2845154	0.02
325.1143494	0.31
337.0941162	0.08
338.9000244	0.01
341.1706238	0.67
342.1719666	2.94
343.1812134	16.19
351.1730652	0.03
353.0742493	0.09
354.0482788	0.03
355.1777954	0.95
356.6874695	0.37
357.3544312	0.29
359.1734009	0.02
362.1565857	0.02
363.5245667	0.03
366.0846252	0.05
369.0222778	0.09
369.9048462	0.04
371.5046387	0.13
372.1823730	0.72
373.1932068	1.61
377.9541321	0.09
379.2125549	0.17
383.8789062	0.06
385.1239014	0.58
386.6358643	0.31
387.3049011	0.92
389.4999084	0.28
390.3200378	0.66
391.2157593	0.04
395.1465454	0.03
397.1221924	0.57
402.6603088	0.08
403.2721252	0.21
414.4480896	1.10
415.2494507	6.69
416.1851196	0.01
418.7445068	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
269.0873413	0.49
281.2268982	0.03
283.0767822	0.27
287.0927734	0.03
293.1339722	0.10
295.1989441	0.02
311.0477905	100.00
312.1044922	0.10
321.0196838	0.04
323.060791	0.21
335.0783386	0.09
337.2052307	0.11
341.1629333	12.91
342.3577271	0.02
348.9359436	0.05
351.368927	0.02
353.1410522	0.81
355.0291138	0.27
367.2295837	0.12
371.1233215	0.23
376.9233704	0.19
383.1743164	0.61
385.3634338	0.04
387.069458	0.02
390.8717041	0.01
395.1341248	0.41
401.4129333	0.01
413.1924744	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2664
Annotation	Menisporopsin A
Peak:m/z	Relative Intensity
340.8992920	0.08
382.9402466	0.30
412.8515625	0.03
442.7722168	0.15
473.1040039	0.14
485.2123413	0.30
503.0716553	0.85
504.2315063	0.06
665.2169800	100.00
665.9362183	0.07
666.8444214	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2883
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
170.9330444	0.61
176.9683380	0.27
222.9627380	24.33
224.0419617	1.89
241.0225372	61.07
242.0482635	2.03
243.4130554	0.10
258.9457703	1.40
261.3248901	0.42
279.2688599	31.92
280.4006958	5.10
315.0467529	100.00
316.0806274	7.93
333.1468506	9.79
334.1152344	0.63
415.1281738	2.30
416.4586792	0.32
433.1266479	1.26
434.3271484	0.05
503.4042969	0.50
549.6831665	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9338837	0.27
296.7592773	4.74
376.5954590	0.06
380.5612793	20.29
381.2602539	0.08
439.0488892	0.30
461.8339233	0.32
462.5973511	0.11
463.8514404	4.18
464.4624634	41.76
465.2859497	0.04
548.3671265	100.00
549.0978394	0.35
586.7032471	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0881
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
151.0528259	0.61
151.8479919	0.06
152.8357697	0.04
161.577301	0.06
163.0010223	0.06
165.0449219	0.06
168.7751465	0.06
176.9375916	0.07
178.9156189	1.16
189.1221924	0.11
190.0819092	0.03
190.9592438	0.13
193.0181885	0.04
197.0619812	0.04
204.8695526	0.07
211.995575	0.02
214.8731995	0.03
221.0862122	0.10
227.0125427	0.13
233.2187958	0.15
239.0056458	0.16
239.8989258	0.07
244.2814941	0.04
254.9655457	0.05
257.1921387	0.11
261.2196045	0.04
269.0639954	0.11
271.0696716	0.50
271.9623413	0.07
273.0469666	0.38
280.6474915	0.06
281.2850952	0.11
282.9569702	0.19
284.9768066	0.17
297.1902466	0.20
300.0107422	20.96
301.0378113	100.00
308.9442139	0.05
313.0149536	0.09
315.1966248	0.06
317.4225769	0.08
319.1246948	0.02
323.1439209	0.06
325.0162354	0.37
326.9589844	0.12
330.0202026	0.03
331.1755981	0.15
336.8334045	0.03
341.1518555	0.74
342.1707153	1.98
343.1898193	3.76
346.2852783	0.06
353.1817322	0.07
355.1167603	0.19
359.3153076	0.13
371.1531067	0.28
372.1317139	0.72
373.1351013	0.48
381.2394714	0.10
384.9729919	0.12
389.1697083	0.07
392.2894287	0.05
402.3431702	0.07
414.2635193	0.09
417.9176941	0.09
419.1820679	0.25
431.2011414	1.48
434.8574524	0.08
443.0912476	0.10
444.3421021	0.14
445.1519165	0.35
448.3858948	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
137.9516754	0.01
160.9981079	0.05
179.111908	0.01
180.2834015	0.02
191.1629181	0.02
218.1570129	0.07
248.1813049	0.02
268.1336975	0.02
268.9699707	0.19
270.0254822	0.12
282.02005	0.03
283.1896057	0.21
284.1967773	0.18
285.2416992	0.03
293.2941895	0.07
293.9799194	0.03
311.0608521	100.00
312.055603	61.53
313.3812866	0.08
318.8146973	0.02
322.5113525	0.19
323.1223755	0.26
324.0495605	0.19
325.1530151	0.04
326.1384277	0.02
335.1809998	0.02
338.1153564	0.05
341.0879211	10.26
342.1740112	9.60
343.9750671	0.02
352.192688	0.03
352.9786987	0.29
354.0717773	0.82
355.1130066	0.27
356.1397095	0.01
365.3683777	0.12
366.2952881	0.14
367.0173645	0.02
368.1679382	0.04
371.0644226	0.30
372.0910339	0.02
377.0723267	0.22
378.0715637	0.16
383.0716248	0.22
383.9936523	0.27
385.2181396	0.01
387.8460388	0.04
389.3258667	0.02
395.1773987	0.24
396.0679932	0.21
401.1499023	0.06
402.3148499	0.11
413.1404114	1.81
414.076355	1.18
414.6802979	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	814.5597
Annotation	PS(16:1(9Z)/22:1(11Z))
Peak:m/z	Relative Intensity
242.2629242	0.12
247.2655487	0.10
249.3161926	1.03
255.2723846	0.14
277.2147217	0.09
279.2553101	14.04
287.3619080	0.45
293.5616150	0.55
295.2795105	100.00
312.2958984	0.16
369.3577271	0.07
386.3566895	0.08
410.3670654	0.07
433.4553833	0.63
459.5350342	0.11
504.3499756	57.03
558.2434692	0.59
582.3248901	0.07
629.3967896	0.18
697.4274902	0.10
755.4241943	0.31
762.3248901	0.55
764.5216064	0.72
768.2048950	0.21
770.6386108	0.16
773.9165649	0.20
777.5138550	0.08
793.9957275	0.13
796.4183960	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2611
Annotation	PC(11:0/0:0)
Peak:m/z	Relative Intensity
145.2449036	0.19
147.0949554	0.05
148.4236603	0.08
152.8156128	0.04
157.0894775	0.08
162.1851501	0.15
173.2133942	0.04
181.0723419	0.13
183.9771729	0.24
185.2622681	0.09
186.7562561	0.09
189.3401489	0.13
191.1024780	0.60
192.9117737	0.09
195.1563110	0.04
197.8814392	0.29
200.9735413	0.09
209.3078613	0.05
209.9732666	0.11
211.1955261	0.25
213.0770264	0.27
215.9770203	0.16
217.1517029	0.15
219.0134888	0.09
220.1385345	0.13
220.7867584	0.13
225.2454834	0.14
245.5605469	0.05
247.9757080	0.17
249.1462708	0.13
252.0852661	0.08
252.9457092	0.12
254.2794800	1.11
259.2200623	0.09
265.0255737	0.12
278.3901062	0.22
279.0982666	0.06
280.9230347	0.13
281.9884949	0.23
283.1733093	0.04
285.2285767	56.91
287.1953735	0.21
288.6436768	0.57
291.3092651	0.26
291.9128418	0.16
293.9120178	0.03
303.1339111	0.05
309.2898254	0.07
311.4250183	0.14
312.3244629	0.09
317.2405090	0.09
323.3745728	0.07
326.1734619	0.10
330.2272949	0.07
332.2659302	0.33
334.2087708	0.10
338.7791443	0.25
339.6377258	0.10
341.9190063	0.96
347.1806030	0.36
348.5086975	0.06
354.4473877	0.27
356.6861267	0.04
362.2181091	0.29
364.0170593	0.05
365.1335449	4.12
366.0644836	0.06
368.1420288	0.26
370.0262146	0.16
371.3995667	0.08
372.3865356	0.28
378.9332581	0.41
380.1857605	0.28
383.5350342	0.08
385.0635071	0.16
389.0190125	0.39
390.1637878	0.66
392.1931458	0.14
398.4296265	0.15
405.3595886	0.29
406.0600891	0.07
408.0755920	100.00
408.7922363	0.69
409.4703674	0.06
420.0692444	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	735.463
Annotation	Mubenin B
Peak:m/z	Relative Intensity
235.0261383	0.40
242.0246887	0.09
252.9430389	0.17
263.1732788	0.19
274.9797058	0.24
280.0240173	0.36
281.1946106	0.29
291.3629150	0.10
294.9429321	0.16
299.3652344	0.14
304.5206909	0.24
315.1355591	0.10
323.0404053	0.38
333.2342529	0.66
336.2812500	0.16
349.3335571	0.50
351.1883545	42.95
352.2642822	7.91
356.9453125	0.29
361.1204834	0.20
371.4530029	0.33
377.3799438	0.18
378.8517456	0.19
381.1112671	0.16
391.4153442	0.63
392.4091797	0.55
400.2706299	0.15
403.3977051	0.14
405.4816284	0.20
407.3294678	36.28
408.2842407	6.11
409.4422607	2.52
410.3553467	0.49
419.4009399	0.07
423.3082275	5.78
424.9434204	3.94
425.7418823	1.03
426.5637207	0.64
430.9331665	0.26
431.5376587	0.27
437.2871704	0.58
445.0682983	0.42
447.1996460	0.82
448.4254761	0.87
475.4179688	3.35
476.0698242	0.06
477.4379883	0.24
479.3981934	2.28
480.1643677	0.16
483.0821533	0.68
487.5667725	0.19
493.3450317	0.36
494.1810913	0.13
501.2347412	0.50
503.4361572	0.69
506.5189209	0.76
514.4047241	0.48
515.2575684	0.11
522.5130005	0.76
530.2619629	0.11
531.3200073	0.50
534.2340698	0.14
535.6000977	1.37
536.3184204	0.09
543.3518677	0.63
548.1659546	0.30
549.6329346	0.14
551.2603149	1.35
552.9169312	0.47
555.3908081	0.48
561.7579956	0.10
568.1613159	0.71
570.2806396	0.27
573.4304810	0.89
574.2455444	1.12
576.7396851	0.30
591.4377441	100.00
592.4314575	24.11
593.1805420	0.21
594.3344727	0.58
596.3551636	0.09
602.1749268	0.18
604.9185181	0.27
615.4636841	0.11
619.4252319	51.80
620.5128784	9.82
621.6691895	0.08
647.4747314	0.45
649.5974731	0.43
658.3588867	0.23
659.4461670	0.64
660.2463989	0.20
661.4705200	0.66
665.0868530	0.42
674.8009644	0.28
677.5039673	5.40
678.5767212	2.09
681.4795532	0.40
682.5726929	0.25
689.6303101	0.65
699.4390869	2.16
700.5098877	0.11
702.5968628	0.24
717.4788208	21.91
718.4851074	7.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	536.2036
Annotation	Saframycin B
Peak:m/z	Relative Intensity
154.1477661	0.02
164.0635376	0.06
178.2079163	0.09
189.1665344	0.03
194.2070160	0.03
217.1527405	0.02
225.1634521	0.15
247.1986389	0.07
256.1550903	0.08
267.0554199	0.05
269.1134644	0.06
278.5083008	0.04
293.1537781	0.18
295.1389160	0.18
297.2625122	0.08
303.1154175	0.04
311.0718384	0.06
312.2862549	0.06
322.0392456	0.07
323.1802368	0.92
324.2181396	0.46
327.7100830	0.17
328.3591309	0.08
335.4907227	0.03
337.1194458	0.57
338.3034668	0.49
338.9351196	0.11
343.3186646	0.21
353.0426636	0.20
354.0597534	0.04
355.2556152	0.13
356.0158691	0.24
360.3519897	0.10
361.3628540	0.19
373.6113892	0.31
374.2789917	0.10
375.1482544	0.06
382.2699585	0.04
386.9741821	0.17
388.2473145	0.09
389.3972778	0.02
400.1752319	0.08
405.2780762	0.08
413.4693604	0.08
415.9483032	0.18
417.3385010	0.75
418.2595825	0.04
436.2724609	0.05
443.2354126	0.04
447.4410400	0.27
448.2005615	0.03
452.1306763	0.15
460.3466797	11.08
461.3253784	0.08
464.2615967	0.02
473.5597534	0.07
475.4851074	0.07
476.5163574	0.17
489.1287842	0.15
490.3339844	0.20
491.4252930	0.66
492.2692261	0.64
493.2088013	0.08
495.5290527	0.05
500.3657227	0.08
504.2715454	100.00
508.0483398	0.27
517.5772705	0.61
518.4857788	0.58
519.1289062	0.07
526.6936646	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0882
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
145.0909119	0.02
150.9152222	0.69
152.8482208	0.03
163.0593872	0.10
169.0274811	0.06
172.7698975	0.06
178.9848022	0.72
187.1514893	0.05
189.0139618	0.14
190.0581970	0.17
192.8967743	0.05
198.0320435	0.02
203.2878265	0.03
205.0681763	0.04
207.2281494	0.04
213.4516449	0.02
217.0410919	0.07
221.1114197	0.05
227.0365295	0.06
229.1217651	0.06
232.9229431	0.08
233.9611664	0.02
236.9855347	0.04
241.1870575	0.06
245.0131836	0.03
246.7674866	0.12
247.3843689	0.01
251.1213684	0.03
254.1490479	0.11
255.1431274	0.41
256.0589600	0.03
257.1692505	0.06
261.2623291	0.04
269.2352905	0.03
270.0935669	0.03
271.1467590	0.50
273.0160522	0.14
279.3123169	0.02
281.3115234	0.15
282.9249878	0.10
285.1057739	0.04
287.2335815	0.05
297.2257080	0.19
299.9992676	19.64
300.9820557	100.00
301.6004333	0.20
303.1516418	0.02
309.0772705	0.06
310.8919373	0.03
312.9939575	0.07
314.2441101	0.04
319.1269226	0.04
322.7599487	0.04
325.0634460	0.13
327.0731201	0.06
331.2234497	0.05
335.1144409	0.09
336.4403381	0.07
337.2049255	0.13
341.0667114	2.13
342.0818481	9.10
343.1599731	4.77
346.2478027	0.02
347.3341064	0.13
353.3013306	0.06
354.3343506	0.08
355.0718384	0.10
357.3748474	0.06
365.4516602	0.02
371.3237000	0.38
372.1280518	1.52
373.1075134	0.64
383.1108704	0.05
384.2649841	0.02
394.6539001	0.03
398.9632263	0.14
400.3973083	0.08
402.2558289	0.07
403.0614929	0.20
407.7259216	0.01
408.3515625	0.01
416.0269470	0.01
417.0366516	0.04
418.3287964	0.05
419.0448914	0.12
426.1015625	0.17
426.7886658	0.02
427.5107422	0.03
429.1921082	0.03
431.1682129	0.73
444.1846619	0.49
445.2081604	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	158.98
Annotation	Unknow
Peak:m/z	Relative Intensity
70.9634247	0.25
86.9371185	0.07
114.8474121	100.00
130.9206390	5.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	846.1497
Annotation	Unknow
Peak:m/z	Relative Intensity
271.8515625	0.07
273.0559387	0.21
273.8196411	0.23
275.0700989	0.12
281.9939880	0.04
316.7088928	0.25
317.6655273	0.29
318.9296875	0.13
319.9707642	0.27
321.9839478	0.58
345.9591064	0.22
356.4660034	0.11
360.0601807	0.32
366.0036621	0.33
381.9978638	0.23
383.3115234	0.21
403.0208740	0.48
408.9595947	0.16
444.0487061	0.30
445.1023560	0.16
451.0496826	0.90
452.9391479	1.13
454.2479248	0.27
490.0162964	0.92
491.3620605	0.30
494.7838745	1.90
501.1958008	0.09
508.5474243	0.14
519.8972778	0.07
534.0472412	0.24
537.0030518	0.20
538.0444336	4.79
563.9426880	0.39
579.5136719	0.95
580.1810913	0.61
582.0183716	100.00
632.0816040	0.09
652.2764282	0.11
664.0884399	0.23
665.4013062	0.09
714.7763062	0.30
801.9290771	0.51
828.0178833	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0615
Annotation	5,7,2',3'-Tetrahydroxy-8,6'-dimethoxyflavone
Peak:m/z	Relative Intensity
109.0029373	0.28
122.9664154	1.13
123.5963135	0.02
124.8712311	0.16
132.9176788	0.42
138.8477173	0.55
146.9724274	0.21
148.8567657	0.16
150.9172058	0.08
166.9532776	100.00
167.8689880	0.10
168.9165955	0.39
176.9594727	5.78
182.3549652	0.15
183.0233459	1.68
192.9886475	0.11
195.2345734	0.12
197.8627930	0.10
205.1925812	0.14
209.0488892	0.31
211.1492920	0.07
214.6213379	0.45
225.0484314	0.14
226.1457214	0.10
229.0888062	0.08
234.9578552	79.66
252.3947144	0.04
257.1395874	0.06
261.2683716	0.24
265.2626953	0.07
270.8594971	0.23
272.1950684	0.08
278.1764526	0.12
281.0278931	0.11
281.9353027	0.05
283.2488098	0.35
285.2211304	0.14
287.1856079	0.27
297.1696777	0.26
299.1567993	0.15
301.1928101	0.33
301.9162598	0.15
309.0281067	0.14
310.1556091	0.04
313.1236572	4.73
315.1727905	0.14
325.3198853	0.33
327.0282288	18.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.2137
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
110.1623688	0.68
112.7112885	0.41
117.0680695	0.50
119.0397415	0.73
121.0006714	0.66
123.0227966	0.40
127.0473022	0.67
128.8797607	0.63
130.9342651	2.27
135.1969147	0.58
137.1137085	1.11
140.1329651	0.46
141.1431732	1.05
142.1064911	0.58
142.9819336	0.75
144.9415436	0.70
146.8913879	0.59
148.7360229	0.45
149.8926086	1.04
157.0270996	0.40
158.7833557	0.19
162.9500122	1.29
166.9909058	22.68
168.2069702	0.38
169.0991516	0.38
171.0108337	0.89
172.9341125	0.85
178.9935455	0.26
183.0161896	0.72
185.4201813	0.34
187.2154541	0.46
192.7963867	1.02
194.7985382	1.52
196.5367737	0.95
197.1488953	1.93
201.6662750	1.29
206.7731934	1.01
208.8511505	0.37
210.6623535	0.31
211.3177490	0.33
213.0968628	2.86
215.2285461	1.85
216.0681458	0.76
221.2018738	0.85
223.4945679	1.22
224.9145813	1.27
227.1133118	0.26
228.9534912	1.65
232.8536072	0.71
235.0895691	34.07
237.1428528	2.08
239.0125122	2.14
241.1546936	1.53
248.7265320	1.47
251.1741943	0.24
253.1434937	2.36
257.1449585	2.70
259.4154053	1.08
262.9691162	1.05
265.0759888	0.85
267.2855225	1.65
275.2906494	0.97
276.2701416	0.80
277.3034058	4.13
279.2997131	1.71
285.1357422	0.40
291.0725098	3.64
292.3552246	1.03
293.2492676	1.12
295.3785400	0.60
297.1676636	0.65
303.4774475	0.26
304.9600220	0.82
310.1783447	0.23
315.2648315	9.42
316.5188293	0.73
321.1914062	0.43
322.1609497	1.15
323.2797546	3.20
323.9793091	0.31
333.2025757	100.00
334.2123108	1.25
341.2762451	0.50
342.5357971	1.10
349.1208191	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	320.092
Annotation	S-Methyl GSH
Peak:m/z	Relative Intensity
101.9639053	0.05
112.9507599	0.07
118.9939346	0.38
126.8106995	0.27
127.9971085	19.59
143.1186829	0.09
143.8481903	0.12
145.0163574	0.05
152.0639954	0.25
153.0434265	0.36
157.0380249	6.37
159.0610352	1.54
166.0442505	0.12
166.9802551	0.57
168.9978638	0.29
170.1215210	0.14
171.1140442	0.12
172.9051208	0.11
174.0205078	14.31
178.8926544	4.90
179.5248260	0.08
184.1074524	0.51
185.0919342	1.27
186.0846863	0.19
190.9843292	11.35
196.0275116	6.07
197.0412750	1.85
198.6071320	0.14
199.2366638	0.09
199.8896332	0.07
211.9619751	1.49
212.9631653	2.84
214.0440674	0.67
217.1704712	0.06
224.1339722	3.63
225.0523987	0.14
229.8717346	0.97
231.0664673	1.23
232.8383179	0.07
242.0791931	3.30
248.1015930	0.92
249.1023865	0.07
250.1172791	0.43
251.0629883	0.03
254.1693420	0.26
256.1730957	0.88
258.1882019	0.09
261.1206055	0.04
268.0426636	55.59
269.0697021	0.12
274.1441650	0.03
276.2477112	0.08
277.0433960	0.08
284.0090027	0.40
286.0943909	100.00
289.8215942	0.08
302.0697021	47.13
302.8922729	0.18
303.5782776	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	703.2443
Annotation	Argylioside
Peak:m/z	Relative Intensity
199.1063080	1.35
200.9544067	0.11
207.2728271	0.23
208.1508484	0.09
209.1056061	0.35
210.9993286	0.20
212.1530762	0.17
217.1128845	5.13
218.1504822	0.25
221.1233063	0.96
222.1567688	0.16
225.1354218	0.20
227.1889343	0.33
229.1806335	6.01
230.0480652	1.27
237.3042145	0.11
239.2402344	0.17
243.0658722	3.56
244.1047363	0.58
245.1066895	0.16
253.1201477	0.41
255.1457214	12.52
256.1286011	3.21
257.0951538	0.11
262.9440918	1.11
268.9737244	0.67
270.0477295	0.11
271.0578003	1.91
273.1385193	25.97
274.1602783	3.95
281.0569153	0.67
287.0523071	0.83
289.2088623	1.10
290.0519409	0.16
291.2437744	8.88
292.2525024	3.14
299.0679016	6.83
300.0905151	0.68
301.4088440	0.18
305.1100159	0.39
307.2514954	0.11
309.0623169	0.08
311.0732727	0.14
313.3803101	0.10
317.2500000	8.52
318.2240601	1.36
322.9346008	0.13
329.3486328	0.14
333.2161865	0.20
334.7149658	0.51
335.4107056	0.44
336.4506836	0.07
339.5093994	0.16
343.1552124	12.98
344.0701904	2.54
345.1419678	1.32
353.3192749	0.11
357.5842285	0.35
361.1192017	100.00
362.1168823	28.32
377.3870239	0.18
379.2069092	0.92
380.1905518	0.09
383.0897827	0.27
389.2952271	0.31
394.6470337	0.15
397.1323242	0.26
405.0877686	0.33
416.2695923	0.17
417.5993652	0.12
419.3082886	0.07
435.3088989	15.51
436.3054810	4.98
449.2322998	0.25
450.8929443	0.07
453.2678833	17.40
454.2593384	5.69
455.0202026	0.14
455.9668579	0.20
461.1231689	0.48
463.3101196	0.46
477.4412842	0.13
479.4075317	0.10
497.2247314	0.61
498.2380981	0.04
502.1524658	0.29
503.0084229	0.08
505.1400757	0.53
523.2672729	2.12
537.4663696	0.16
541.2033081	9.95
542.3217163	2.56
544.2657471	0.17
565.0663452	0.11
576.7186890	0.07
578.6576538	0.67
579.4137573	0.11
583.3255005	0.40
584.2584229	0.20
584.9546509	0.13
593.8408813	0.11
597.2932739	3.80
598.3019409	1.16
614.0424194	0.09
615.2911987	8.47
616.3279419	1.92
630.1554565	0.41
640.1972046	0.27
641.4360352	0.64
642.4474487	0.50
657.5175781	0.82
659.2373047	62.27
660.3094482	24.27
667.4818726	0.31
685.2341919	11.87
686.3309937	6.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.2664
Annotation	AT 2433B1
Peak:m/z	Relative Intensity
238.0873413	0.04
241.3100586	0.04
272.9038696	0.04
285.0299683	0.03
306.9317322	0.02
313.1654053	0.05
319.1419067	0.31
323.1766968	0.18
325.1557007	0.08
327.3090820	0.03
355.3462524	0.37
379.0227051	0.05
392.2018433	0.02
403.2763672	0.08
416.3743896	0.02
430.3789062	0.02
431.2838135	0.01
434.2776489	0.19
438.0977173	0.04
444.2218628	0.02
446.3652344	0.07
462.3084717	0.03
476.0266113	0.06
504.3690186	0.04
507.9916992	0.01
512.4845581	0.04
517.3766479	0.08
522.0745239	0.03
529.4713745	0.04
531.2463989	0.03
539.2182007	0.21
542.7460938	0.02
551.6111450	0.13
553.5833130	0.05
555.2322388	0.04
557.1929932	1.63
558.4089966	0.11
565.7082520	0.06
570.5698853	0.11
571.4807739	0.09
581.4100952	0.39
583.1260376	0.37
585.0410767	0.04
599.2673950	47.73
599.9262695	0.11
601.3112793	0.48
602.4310913	0.24
603.3106689	0.10
607.3958130	0.06
613.2725830	0.15
615.2434692	0.43
625.1721802	0.31
629.6589966	0.16
631.1337891	0.43
643.2057495	100.00
643.8480225	0.66
647.2262573	0.02
657.3554077	0.15
659.8659058	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.1622
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
199.9929504	0.01
202.0110779	0.18
217.0136871	0.04
218.1920929	0.05
219.0313263	0.02
247.4403381	0.55
248.0970001	0.99
264.9973145	100.00
265.6090698	0.32
306.9132690	0.04
336.3378906	0.10
337.1425781	0.01
348.6614990	0.14
367.1505127	0.08
373.1431885	0.02
393.2203369	0.06
397.0224609	0.01
400.0994873	0.02
445.0684814	0.01
450.4445190	0.03
451.1802368	0.03
456.8936157	0.04
463.1361084	0.07
463.9311523	0.02
465.0885620	0.22
478.5610962	0.01
510.9531250	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.2922
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1673737	0.04
176.7984314	0.07
181.0781708	0.05
184.7850647	0.06
185.9880676	0.08
203.0376740	0.64
222.1627960	0.10
225.0397034	0.82
229.2161713	0.04
235.1079559	0.07
243.0439911	0.90
245.2408447	3.56
261.0277100	1.78
263.2910156	1.73
279.4699402	0.15
280.0794983	0.05
281.0625610	0.49
283.4887085	0.32
289.5913086	0.03
299.0470581	0.92
301.3978882	0.67
307.2445068	0.07
314.9205933	0.14
315.5460815	0.15
317.0514526	14.45
317.9654541	0.22
319.3995972	0.78
333.0484619	0.37
335.0427246	10.80
337.2731934	42.47
339.1923218	0.14
343.3329468	0.07
355.3666382	0.09
361.0987549	0.07
377.2116699	0.05
383.1469727	0.07
395.8175659	0.06
407.2803345	0.80
411.3450317	0.23
415.1694336	0.13
416.9194336	0.13
418.6464233	0.18
425.2851562	1.07
432.4656982	0.11
433.2871704	0.26
435.4518433	0.31
437.4857178	0.16
453.6849976	0.15
457.4110718	0.14
458.1453857	0.08
464.3903809	0.11
467.1635132	0.28
487.2952271	0.33
488.3283081	0.96
489.4271851	0.17
504.6760254	0.13
508.4181519	0.10
514.7382812	0.14
519.6399536	0.10
521.2881470	0.20
522.1148071	0.09
525.9426270	0.07
543.6051025	0.25
552.2839966	0.05
561.1394043	100.00
562.0679932	0.06
569.6333618	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1072.2059
Annotation	Unknow
Peak:m/z	Relative Intensity
405.9475708	0.12
555.9496460	0.09
557.3597412	0.04
598.1810303	0.62
599.3049316	0.04
638.5368652	0.11
658.0468140	1.35
700.1959839	0.09
718.0729980	2.51
730.3225098	0.03
749.4617920	0.05
770.0387573	0.21
788.3050537	0.09
790.0540161	1.57
801.1300049	0.10
817.1051025	0.06
820.0645752	0.59
827.3795166	0.06
832.1590576	0.04
850.0465088	1.64
863.8604736	0.05
878.2371826	0.44
880.1140137	100.00
881.0787354	0.38
882.2183838	0.34
891.9121094	0.16
910.0119629	0.49
921.3695068	0.05
943.5029297	0.07
984.1533203	0.83
1028.0378420	1.46
1053.3237300	0.11
1054.0407710	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	578.1858
Annotation	Unknow
Peak:m/z	Relative Intensity
191.5082550	0.02
205.0973206	0.04
209.2175751	0.09
230.8877106	0.03
259.1411743	0.10
294.9597778	0.02
303.3334351	0.10
310.0997009	0.21
325.3025513	0.02
330.3060303	0.09
350.2667847	0.12
358.5250854	0.03
367.2871704	0.09
372.3034058	0.15
376.9677734	0.02
384.2157593	0.06
386.2479858	0.08
396.9954834	0.28
398.0998535	0.04
399.3139648	0.09
402.0877075	0.18
404.2477417	0.05
409.0533447	0.11
414.2288818	0.03
416.0916748	0.37
420.9445801	0.10
426.0548706	0.09
427.2183838	0.44
432.4139404	0.02
435.1029663	0.05
437.2913208	0.14
439.0125122	0.02
441.1917725	0.06
441.8181152	0.05
442.8596191	0.03
445.1187134	4.86
445.9621582	0.02
447.8285522	0.07
448.4735107	0.13
449.8964233	0.25
452.0957031	0.14
457.2777710	0.59
458.8269043	0.08
463.0331421	100.00
463.6878052	0.40
469.1920166	0.05
480.1861572	0.03
481.4316406	0.09
491.1759644	0.06
491.9313354	0.07
503.0957031	0.07
505.3537598	0.03
509.1625977	0.05
511.1196899	0.06
512.2178345	0.20
515.2296753	0.02
516.0368042	0.06
516.8591919	0.03
524.9414673	0.04
530.4851685	0.04
536.7528076	0.02
541.1744995	0.33
542.1420288	0.28
549.6499634	0.11
557.1960449	0.17
559.1511841	0.63
560.1807251	2.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3234
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
155.1798859	0.06
166.0752563	0.32
166.9346466	0.14
171.9376984	0.03
184.0088043	41.11
185.0350189	3.00
235.1205750	0.06
243.1981964	0.04
258.0828247	0.63
259.0820618	0.04
335.2746582	0.06
408.5234375	0.03
441.2557373	0.07
442.3909302	0.11
500.3611450	100.00
501.3298950	46.83
501.9310913	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.2821
Annotation	Vomifoliol 9-[glucosyl-(1->4)-xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
221.2317810	0.37
226.8862915	0.05
255.1735229	0.15
335.2257996	0.67
383.3004761	0.45
386.8134766	0.13
452.0648804	0.14
454.8704834	0.05
457.0451050	0.49
499.1557007	0.22
503.0532837	0.08
504.1113892	0.11
511.8947754	0.13
517.4501343	0.95
519.5496826	0.40
526.8386841	0.09
529.0084839	0.15
535.8346558	0.07
548.5968018	0.10
551.5405273	0.05
559.2047729	0.41
582.4685669	0.05
585.2149658	0.41
593.4667969	0.04
595.3755493	0.18
601.7179565	0.10
602.3266602	0.08
603.0223999	0.32
608.4794312	0.20
617.4137573	0.55
618.3182983	0.50
619.4261475	0.07
633.0973511	0.78
635.3158569	100.00
635.9255981	0.41
647.2482910	3.04
655.7015991	0.24
659.8193970	0.46
661.4091187	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1642
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
225.2771606	0.07
227.0478363	0.07
242.0247803	0.21
244.1365051	0.13
252.6266937	0.09
255.2114105	0.07
258.9834595	0.13
267.050354	0.10
270.239563	0.06
271.1096191	0.28
283.2311401	0.72
287.0539551	100.00
288.0524292	72.51
290.3902588	0.14
295.1400146	0.97
297.3307495	0.14
307.2633667	0.07
313.0510254	2.90
314.3262939	0.61
315.0661621	0.36
326.1549683	0.14
329.0911865	0.47
337.211792	0.62
338.4065552	0.25
348.1022339	0.58
350.6027222	0.06
361.2306519	0.26
362.0200195	0.14
367.1776123	1.85
367.9981079	0.44
370.0778809	0.30
371.2328491	0.47
373.2875366	0.10
374.4453125	0.08
375.3218384	0.17
376.1550293	0.41
378.2114258	0.19
379.1873779	0.65
383.7895508	0.69
388.2756958	0.27
390.421814	0.90
395.0903931	0.17
397.0529175	2.47
398.4918213	0.62
404.3902588	0.39
415.1921997	9.49
416.1392822	2.19
417.5009766	0.04
418.3776855	0.10
419.4260864	0.17
422.3811646	0.07
427.8931885	0.66
430.9475098	0.42
432.0484619	1.76
433.0477295	9.59
434.1176147	5.60
446.1925659	0.40
447.3447266	0.11
449.0618286	19.27
449.9835815	20.90
450.7373047	0.12
457.1446533	0.08
467.2815552	0.05
473.0526733	0.08
475.3520508	1.11
478.0825195	0.19
497.694519	0.16
514.7997437	0.16
516.447937	0.15
529.1691284	0.27
531.5265503	0.25
534.0668335	0.37
541.223938	0.49
549.3748169	0.25
549.9923096	0.35
552.7248535	0.36
553.3886108	0.06
558.9053345	0.08
560.0621948	1.17
565.012085	0.85
566.2750244	0.68
570.3561401	0.12
571.02948	0.34
575.4573975	0.10
577.217041	5.36
578.1365967	2.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.37
Annotation	Unknow
Peak:m/z	Relative Intensity
200.8722229	0.11
202.1452484	0.06
204.8309631	0.05
206.8953705	0.13
208.9345398	0.16
210.1260529	0.10
211.2185364	0.25
213.1658630	0.08
217.1403198	0.02
219.0224152	0.04
222.0343781	0.02
223.1827240	0.13
225.3476562	0.03
227.1676483	0.07
227.9808960	0.06
229.0594635	0.08
232.9148712	0.01
234.1649628	0.01
235.1450348	0.06
236.9262390	0.86
238.0212097	0.64
239.1000824	2.06
241.0159454	0.04
245.0852356	0.02
247.1278839	0.06
249.0776672	0.45
251.3105927	0.16
252.0843658	0.06
253.3048553	0.02
255.1897430	0.06
255.8803101	0.02
256.9636841	0.09
259.1169434	0.07
263.0913391	0.07
265.1702271	0.88
267.0700073	23.06
268.1679382	0.46
269.1328735	0.11
269.9751587	0.03
271.1285400	0.10
272.1254272	0.07
275.1245422	0.06
277.1929932	0.19
277.9246216	0.15
279.0605469	0.68
279.9188538	0.09
281.0673218	1.10
282.3334351	0.06
283.1885376	0.09
283.8068237	0.16
284.5410767	0.10
285.2630310	0.03
287.0704651	0.47
289.1966858	0.26
291.2892761	0.05
292.4093323	0.02
295.0817261	0.28
296.2575073	0.05
297.1288452	0.26
299.2379761	0.02
301.3049927	0.03
302.3338623	0.13
303.0983887	0.09
305.0110779	0.04
306.2360229	0.12
307.1554565	1.16
308.1365356	0.03
309.2954407	0.21
310.1245422	0.03
315.0087280	0.11
317.2084351	0.02
319.3809814	0.25
320.0380859	0.05
322.1884766	0.26
323.0307922	0.07
323.7313843	0.04
325.2359619	0.21
327.2628174	0.22
329.3948364	0.72
330.1292419	0.32
331.0689392	0.02
333.2357178	0.02
334.1225586	0.15
335.3189087	0.11
337.5419617	0.04
340.8241577	0.05
341.9730225	0.02
343.3308105	0.08
345.1974792	0.57
346.2800903	1.96
347.1369324	22.02
348.1563110	0.62
349.1240540	0.13
354.2749023	0.03
358.0953369	0.05
361.7762451	0.05
363.4038086	0.49
364.3423462	3.33
365.1267700	15.38
366.2868042	0.54
367.1361084	0.15
368.0997314	0.02
369.5106201	0.09
378.4140015	0.06
382.0635986	14.91
383.1041260	100.00
384.1193237	3.55
385.5424194	0.13
387.5964966	0.08
393.1475220	0.05
395.1953125	0.06
400.3101196	0.02
413.5918579	0.04
414.3742065	0.05
419.2374878	0.09
422.7954102	0.05
427.1040039	0.02
432.2550659	0.10
436.3756104	0.02
437.1475220	0.02
444.3567505	0.01
445.3719482	0.06
449.1131592	0.05
453.2972412	0.14
454.4344482	0.06
459.1871948	0.05
461.3583984	0.16
462.0972900	0.07
462.9942627	0.03
469.0125732	0.05
473.4426270	0.04
478.2279053	0.13
479.2890625	0.50
479.9743652	0.22
480.8637085	0.02
484.1713257	0.03
486.7305908	0.04
491.0383301	0.03
492.0441895	0.05
497.3042603	0.03
509.2250366	0.05
512.1545410	0.05
513.1247559	0.02
514.1352539	0.10
515.5026245	0.17
518.1605835	0.13
519.1995850	0.16
520.3114624	0.05
524.3650513	0.46
525.2895508	0.08
529.0838013	0.10
530.1134644	0.07
532.1211548	0.04
537.4507446	0.15
539.0256958	0.13
540.1708374	0.15
542.1023560	2.35
543.1728516	0.62
546.6486816	1.01
547.8185425	0.06
549.1348877	0.04
550.1038208	0.36
551.1483154	0.08
552.6256714	0.10
554.6441040	0.04
558.5332642	0.77
559.1907349	1.02
560.0375366	0.67
560.7183228	0.11
562.8109741	0.11
564.2001343	0.13
565.0912476	0.06
566.7266235	0.02
568.1645508	1.18
569.1491089	0.31
570.3505859	0.01
573.3516846	0.02
574.2102661	0.03
576.1145020	1.14
577.0614624	1.99
578.0691528	0.74
579.2929688	0.03
580.2063599	0.10
586.2916870	0.02
587.2189331	0.06
589.6602783	0.29
590.4019165	0.02
592.7048340	0.12
594.3271484	15.25
595.0311890	33.58
596.0567017	7.72
597.1655273	0.04
598.2520752	0.02
602.1021729	0.10
607.6440430	0.22
615.6276245	0.12
616.3272095	0.30
617.0535278	0.14
620.0812988	0.02
622.8668823	0.02
625.1312866	0.49
626.0384521	0.52
631.5219116	0.05
634.0823364	1.63
635.0628052	0.22
638.3563843	0.20
639.4553833	0.05
648.1472168	0.02
651.0382690	0.09
652.2615967	0.15
656.0508423	0.90
657.1403809	0.36
657.7499390	0.02
658.9391479	0.06
666.3409424	0.02
669.1965942	0.10
673.5584717	0.45
674.1702881	4.44
675.1582031	1.60
692.1332397	11.45
693.1066284	5.01
693.7069702	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1035.6392
Annotation	Unknow
Peak:m/z	Relative Intensity
301.7959595	0.10
317.2278137	0.09
335.5043945	0.14
441.3342285	0.87
500.3045959	32.69
500.9633789	0.22
516.8380127	0.03
518.3583984	100.00
532.3436279	7.02
561.9356689	0.04
585.6811523	0.04
603.4013672	0.03
621.1723022	8.05
621.9878540	0.11
655.8983154	0.15
701.2977905	0.29
757.1577148	0.19
852.7192383	0.11
894.3319092	0.11
956.2750244	0.08
976.4128418	1.95
977.0180664	0.07
999.4755859	0.07
1016.9653320	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3394
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0735474	0.11
183.9529419	30.58
208.9987335	0.02
223.4330597	0.03
240.2170715	0.11
258.1581421	0.29
293.1027527	0.23
319.0439453	0.07
337.2749634	0.13
352.1209106	0.05
383.2883301	0.06
443.4326172	0.46
489.1168823	0.95
502.4158936	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2598
Annotation	Cuniloside
Peak:m/z	Relative Intensity
179.1217957	0.01
244.0082703	0.01
268.2874756	0.02
275.3373413	0.03
333.1010132	0.02
339.2542725	0.02
341.1367798	0.01
349.4586792	0.04
374.3180542	0.02
379.3516235	0.04
387.3013916	0.03
392.6181641	0.02
404.1353760	0.04
421.3249512	0.02
424.3622437	0.01
427.4547119	0.02
428.3165894	0.07
437.3804932	0.03
463.4863892	0.02
465.1899414	0.01
469.2618408	0.05
470.3112793	0.14
471.3156738	0.29
495.3857422	0.11
496.4606323	0.02
497.0874023	0.03
511.2396851	100.00
513.2883911	0.20
514.7181396	0.03
528.1868286	0.04
538.2404785	0.06
538.9496460	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	891.4023
Annotation	Unknow
Peak:m/z	Relative Intensity
295.0857544	0.04
329.3090210	0.02
341.2468262	0.02
361.5185547	0.03
367.2486572	0.02
391.1305847	0.03
395.6237183	0.10
415.3141479	0.05
443.3528442	0.07
447.3302002	0.05
453.2858887	0.03
458.5566406	0.06
459.2369995	0.05
469.4190063	0.59
478.2348022	0.03
487.3366089	0.71
488.5107422	0.04
493.2816772	0.04
507.2164917	0.15
521.5593262	0.15
537.3928833	0.74
538.5507202	0.18
549.3520508	0.25
550.2258911	0.10
552.3824463	0.08
567.3165283	100.00
568.2959595	14.41
568.9340210	0.12
571.3581543	0.09
578.5086060	0.05
609.3042603	0.17
610.4530640	0.02
611.3639526	0.09
625.3723145	0.02
632.5405884	0.05
711.3001099	0.05
727.1911011	0.08
729.2654419	0.20
730.0179443	0.04
731.0855103	0.05
739.2975464	0.02
772.6567993	0.10
784.7185059	0.02
788.6647339	0.05
790.3958130	0.08
801.4921875	0.03
802.3690796	0.04
811.5158691	0.03
830.4835205	0.04
831.4992065	0.16
832.4948120	0.05
837.0275269	0.01
840.5066528	0.02
847.5062866	0.19
848.1187134	0.06
861.2675781	0.02
873.7838745	0.03
876.4667969	0.13
891.2229614	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2603
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2127380	0.05
237.2662659	0.08
238.9395294	0.10
269.3762207	0.12
287.2546387	0.07
293.1417847	0.16
306.3750000	0.19
307.0875244	0.22
312.1194763	0.17
313.2811279	0.28
323.2700806	0.04
329.0180664	0.14
330.3068848	0.52
331.3464966	0.09
341.1831665	0.08
343.1932373	0.13
375.3813477	0.10
385.1194458	0.21
387.3254395	0.27
390.4128418	0.28
392.2296753	0.10
401.3278198	0.17
403.1766357	0.12
414.1729126	0.07
415.2347412	0.93
424.1250000	0.03
425.3864136	0.14
431.3728638	0.23
432.3380737	0.14
433.2373657	0.75
437.2253418	0.05
449.1610718	0.24
456.9035034	0.05
468.1470337	0.06
469.2367554	0.17
473.1538696	0.19
474.5499268	1.66
475.4159546	0.71
476.2324829	0.05
485.3807373	0.04
487.1484375	0.24
488.9818726	0.13
492.7468262	0.17
505.1138306	0.60
516.1083374	0.34
517.2533569	0.08
518.2778931	0.22
531.3062744	0.17
547.1247559	0.86
549.2443237	100.00
551.1729736	0.35
557.1688843	0.26
559.4678955	0.07
563.6599121	0.24
576.9976807	0.66
577.6867676	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
130.2154083	0.02
134.8457947	0.08
145.1489258	0.06
146.8942719	0.10
147.8570557	0.04
149.0634613	0.46
150.9434814	1.69
152.0658264	0.06
152.9490662	0.55
158.0489044	0.04
159.2407837	0.15
161.0035095	0.15
162.8916626	0.37
164.9198761	0.12
169.0021057	0.33
171.0193481	0.21
173.1522217	0.29
174.2207336	0.25
174.9735413	0.25
177.2570190	0.15
179.0074158	1.25
179.7546234	0.04
182.0067291	0.10
187.0503235	0.44
188.8481140	0.03
190.9116974	0.17
192.9848633	0.44
197.2474976	0.27
198.9757843	0.15
203.1623230	0.48
204.9118958	0.05
206.9496307	0.05
208.0340576	0.06
209.0020294	0.02
211.0580750	0.12
211.9316101	0.04
213.1120758	0.04
213.9156799	0.03
215.0361328	0.27
216.0654602	0.25
217.2749939	0.07
219.2507935	0.07
220.0815277	0.34
221.9219818	0.07
223.1173401	0.08
225.1723022	0.19
227.0636597	2.01
228.2439423	0.07
231.1001892	0.24
233.2532349	0.03
233.9685211	0.08
235.0303345	0.08
237.1382599	0.20
238.5458069	0.18
239.1637878	0.31
240.9796448	0.48
243.0513611	1.67
244.8518677	0.24
253.2408142	0.63
255.0323792	10.07
256.0416565	2.94
256.9845886	0.59
259.0915833	0.50
265.0933838	0.31
267.1696777	0.22
269.1482544	2.25
270.1709290	0.15
271.1822815	0.52
273.2125549	0.29
275.1943665	0.20
275.9210815	0.07
277.2327271	0.04
281.2055054	0.03
283.9870605	79.59
285.0514526	100.00
286.0951233	0.84
288.2271729	0.03
291.2634888	0.19
295.1376038	0.35
297.2831421	0.45
298.6225586	0.59
299.2324829	1.29
301.5101929	0.16
302.2225342	0.38
302.9662476	0.26
307.1365356	0.07
309.3085022	0.15
311.0366211	0.12
313.3329163	0.08
314.1045227	0.09
315.1041870	0.17
316.1235962	0.03
320.0708313	12.24
321.1447144	1.61
323.4320984	0.06
324.8623657	0.30
327.0722961	44.49
328.0637512	0.44
328.9340210	0.09
339.1412964	0.26
340.2010803	0.12
341.2101746	0.12
343.3060303	0.13
345.3232117	0.03
351.2962341	0.54
357.0571899	7.24
363.0416260	0.10
365.1405029	0.08
367.3610535	0.06
369.1954041	0.41
371.1514587	0.08
372.9949646	0.04
384.0837708	0.09
384.7197876	0.12
386.2463989	0.02
387.1858521	0.50
388.2051697	0.07
392.9515076	0.94
399.4473267	0.11
401.0696716	0.17
402.7188721	0.17
403.3800964	0.07
410.0413513	0.04
410.8950500	0.30
411.5846558	0.14
416.1179504	0.04
419.1074524	0.83
420.3114929	0.11
427.3845520	0.06
428.0694275	0.28
429.0797424	2.14
430.1540222	0.33
431.8548279	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1556
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
177.1813354	0.07
182.8998108	0.01
197.0865173	0.03
209.2938385	0.02
210.0717163	0.01
221.1276093	0.01
224.1189880	0.01
238.2195435	0.02
239.1679993	0.08
254.1747131	0.02
267.1109924	0.06
268.0330505	0.01
269.0583191	0.09
270.1079407	0.06
279.2083130	0.02
281.0014648	0.09
283.1391602	5.38
284.0295410	1.25
293.1414490	0.07
294.1635742	0.09
295.1922913	0.12
296.1308289	0.06
305.2438354	0.02
307.3066406	0.04
308.2020264	0.01
309.1260681	0.34
311.0572510	100.00
312.0588074	16.13
321.1911011	0.71
322.4651489	0.25
323.1388550	0.62
324.2813110	0.16
335.4096069	0.05
337.1136475	0.02
339.0868530	0.26
341.0689087	16.79
342.1390381	3.39
348.9951172	0.04
351.1142578	0.21
353.1278076	0.49
354.2369995	0.14
358.8375244	0.01
367.1676636	0.21
368.3577271	0.08
368.9927979	0.01
371.1157837	0.82
372.2848511	0.21
377.1928711	0.54
378.0988770	0.19
395.0620117	5.38
396.1466675	1.41
396.9720459	0.02
413.1480103	0.34
414.0931396	0.02
421.9885254	0.01
431.0789795	0.01
433.4561768	0.01
438.9556885	0.00
485.0625610	0.01
531.0770874	0.02
531.8920288	0.09
541.3940430	0.10
559.1620483	1.34
560.1875000	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0982
Annotation	Isovitexin
Peak:m/z	Relative Intensity
139.2603607	0.03
143.0942993	0.01
163.0606995	0.01
169.1329346	0.01
172.9467163	0.01
179.0101013	0.01
182.8557129	0.01
207.0267334	0.01
209.3089905	0.01
227.1896057	0.06
231.0716705	0.02
248.766571	0.01
251.1959839	0.03
264.9407043	0.01
267.2998962	0.04
269.0205078	0.34
281.9104614	0.04
283.1640015	0.45
287.2142944	0.01
292.9495239	0.06
297.0450439	0.02
300.9942627	0.02
309.2191162	0.03
311.055542	100.00
312.0133057	0.09
321.229126	0.07
322.5557251	0.03
323.1800537	0.27
326.6808472	0.02
327.3053589	0.04
334.3530273	0.01
335.3223877	0.03
338.9511108	0.02
341.0784912	14.65
341.6946716	0.06
347.0805664	0.02
349.1315918	0.02
350.7634583	0.06
353.144043	0.76
353.9937744	0.01
355.1365356	0.24
365.3569031	0.03
367.3052368	0.06
368.6917419	0.03
370.2554321	0.33
371.2704163	1.20
377.1637878	0.12
382.4951477	0.05
383.1804199	0.43
385.1078186	0.16
387.1362	0.12
388.2330322	0.20
389.1803589	0.12
392.0908203	0.04
393.0852966	0.02
395.0704651	0.34
399.8306885	0.02
401.2111206	0.06
413.1625061	2.35
414.2507019	0.07
433.5878906	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.2591
Annotation	11Z-heptadecen-1-ol
Peak:m/z	Relative Intensity
169.2497406	0.01
225.2284851	0.04
237.2464294	0.09
251.2964478	0.32
253.2426453	100.00
254.3278809	0.80
255.3906860	0.02
256.2263184	0.03
269.5841675	0.10
272.9838867	0.03
281.2639771	3.20
282.3468628	0.03
298.9759521	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Isovitexin
Peak:m/z	Relative Intensity
129.0028534	0.02
140.470932	0.02
143.232666	0.02
148.9594116	0.02
159.1221619	0.03
161.1307526	0.05
163.173233	0.01
169.2005615	0.02
171.1797485	0.01
179.048584	0.01
180.0137634	0.02
186.3921509	0.03
187.9324188	0.02
189.1586609	0.12
190.23703	0.01
191.2880249	0.02
207.2758789	0.23
208.3120117	0.09
211.2901001	0.01
215.1952209	0.01
217.1269379	0.03
233.1051636	0.07
234.1655273	0.01
241.3837891	0.00
246.945282	0.04
248.0892639	0.01
249.2731628	0.02
251.2070923	3.99
252.1791992	0.43
253.0752258	0.01
254.2232971	0.02
263.4919739	0.01
267.1748352	0.03
268.3139954	0.83
269.0616455	7.42
270.0393982	1.67
275.2724609	0.01
283.1593933	0.37
284.1088562	0.04
285.5955811	0.02
287.3131409	0.29
288.1635437	0.01
291.2233276	0.05
292.2732239	0.01
293.2342224	0.12
296.2746277	0.01
301.5218201	0.02
302.503418	0.02
303.9501648	0.01
309.3093567	0.07
311.0642395	100.00
312.0750732	23.53
315.1903381	0.04
316.0606689	0.01
319.0969849	0.01
321.0730286	0.02
323.1530762	0.47
324.1875	0.15
325.2157593	0.08
326.1385498	0.00
327.1905518	0.05
327.8941345	0.01
329.1388855	0.02
333.4182739	0.01
335.1999207	0.12
337.2012939	0.22
338.2349548	0.04
339.18396	0.01
341.0658569	23.54
342.0673218	8.16
342.675415	0.04
344.7581787	0.02
349.0625305	0.01
350.1051636	0.03
351.0160522	0.05
353.0999756	0.68
354.1052246	0.26
355.1416016	0.36
356.1536255	0.16
365.1980896	0.08
366.1463318	0.01
367.0389709	0.04
368.6207581	0.03
370.9922791	1.04
372.0179138	0.24
376.0469055	0.02
377.0167542	0.10
378.1206055	0.11
383.0591431	0.39
384.1717834	0.14
386.1947327	0.01
387.6114197	0.01
389.2795105	0.01
390.3722839	0.03
395.1002808	0.91
396.0973511	0.26
401.3055725	0.09
402.4854736	0.02
411.2133484	0.01
413.0666809	3.00
414.1132812	1.15
414.8293762	0.05
415.6929626	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.3597
Annotation	Denin
Peak:m/z	Relative Intensity
199.0381317	0.22
203.1284027	0.24
209.1694641	0.10
211.1511230	0.24
217.2953491	0.17
219.0486145	0.17
221.1284943	0.10
235.0933685	5.73
245.1465454	0.07
253.0909119	2.22
262.9934082	0.20
268.9682007	0.17
277.2218018	3.69
286.1005249	0.10
287.1061707	3.65
293.2554016	0.68
295.0621643	0.35
303.1559448	0.11
305.1253052	3.62
318.4440002	0.08
322.9854431	0.53
335.1845703	0.06
349.2791748	0.07
361.2229004	0.03
363.3527222	0.04
379.0426025	1.01
392.5112305	0.10
393.4738770	0.06
397.2236938	100.00
403.1066284	0.15
411.2322998	0.19
415.1175537	38.76
415.7618408	0.06
419.2203369	0.09
423.4918213	0.17
461.4691162	0.06
467.4068604	0.09
471.5384521	0.52
477.2421875	0.07
495.2906494	0.29
504.3740845	0.25
506.8235474	0.16
509.3095093	0.11
512.7270508	0.25
561.2998047	0.12
568.4943237	0.39
575.5908813	0.07
579.2973022	0.07
599.3394165	0.39
601.5291748	0.04
602.7893066	0.17
610.4097290	0.10
615.0962524	0.87
615.7766113	1.52
625.4329224	0.08
629.4622803	0.15
631.5238647	0.55
632.2077026	0.09
633.5078735	4.53
641.7551270	0.08
642.6845703	0.09
647.7172241	0.13
656.4303589	0.78
657.3882446	0.35
658.9588013	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.31
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
154.1958618	0.02
170.9530334	0.09
176.9590912	0.03
197.9394379	0.16
216.4873810	0.15
260.8761292	0.03
290.7242737	0.04
296.2103271	0.08
303.6973572	0.02
308.3937073	0.31
313.2158203	0.15
333.2400513	0.09
337.5137329	0.05
339.2589111	100.00
406.7713928	0.03
409.7832947	0.22
419.0182190	0.04
424.6230164	0.07
433.2148132	0.06
434.4568481	0.08
436.5947266	0.10
437.5101013	0.06
448.5922546	0.09
462.2196655	4.37
470.8308716	0.05
473.1250305	0.06
480.3859253	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.23
Annotation	punaglandin 2
Peak:m/z	Relative Intensity
180.1260834	0.10
188.1234436	0.43
204.9482727	2.24
217.2344360	0.29
225.0772705	0.18
265.0848999	0.39
271.3383179	0.14
310.8579712	0.98
322.1616211	0.37
331.0267334	0.52
335.2363281	0.15
342.8377075	0.21
343.9924316	0.17
350.3389893	0.27
357.0361328	0.08
360.0746460	0.08
361.2393799	0.20
361.8800659	0.41
379.1927490	0.39
393.0563354	0.26
395.1491089	0.38
396.5217285	0.13
411.1541138	0.39
414.2784424	0.16
424.2420044	0.12
439.1600952	3.49
450.5842285	0.42
463.3662720	0.14
469.9691162	0.22
478.4319458	0.69
481.1932373	0.12
495.1327515	0.12
497.3684692	0.10
498.2125244	0.65
499.1581421	0.34
501.2539673	0.51
505.4177246	0.29
515.0199585	0.76
522.1606445	0.13
523.2182007	1.47
526.2526245	0.56
527.4356079	0.22
541.3313599	100.00
542.2030640	0.33
549.7250366	0.32
569.4255371	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.2056
Annotation	Carnosic acid
Peak:m/z	Relative Intensity
95.04895782	0.33
96.97709656	0.15
105.0354309	0.15
107.1559372	0.09
109.1010666	0.08
112.9519348	0.24
116.8112488	1.28
119.0440979	1.18
121.0098419	3.32
123.1395569	0.48
124.8996735	0.09
128.7289124	0.11
130.1368408	0.24
131.015625	0.13
133.2643127	0.19
135.1911621	0.17
136.9401093	1.66
138.9490051	1.00
141.0233612	0.30
145.1772614	0.18
147.1777039	0.69
149.0318146	1.31
150.9860535	0.28
155.1339111	0.55
157.0027466	1.12
158.9561768	1.12
160.8782043	0.12
163.0847778	0.16
164.8964844	2.01
166.8774719	2.77
168.9841003	0.59
170.7707214	0.14
173.0365906	0.81
175.1539001	1.20
176.9799347	0.40
179.276001	0.34
181.1019287	0.95
182.8781738	0.68
185.7677155	0.33
186.9224548	0.44
189.0191803	0.69
192.9267578	0.82
194.9578247	5.28
197.1991882	0.77
199.0371704	0.74
203.1021118	0.23
204.7938538	0.64
207.0337219	0.63
209.1610413	0.59
211.2367249	0.48
213.1170349	1.24
215.085907	0.78
215.8821106	0.10
217.1289368	0.56
219.1918945	0.98
221.1481934	1.17
223.1295166	0.67
225.2597961	0.71
227.0794373	1.02
229.1176147	0.91
231.2000427	0.06
232.9673462	0.32
236.6507874	0.73
239.0319519	1.39
241.2133789	4.17
242.1691284	0.14
243.3063354	1.15
245.1653442	2.63
247.291748	0.27
248.0862122	0.12
251.1860352	5.93
253.289978	0.27
253.9890747	0.85
255.0756226	1.22
257.2928467	1.75
259.1911011	6.54
261.2549438	0.90
269.2366943	21.74
270.4973145	0.24
271.2736511	5.86
272.7555847	0.60
275.2618408	0.64
276.3272095	0.60
279.2151489	0.79
280.4932861	0.08
285.1890564	1.90
287.1935425	100.00
289.1832275	3.33
291.5535583	0.23
293.2271729	0.26
297.2605591	14.09
299.300415	0.16
303.0717468	1.38
305.2347412	5.62
305.8968506	0.11
309.6963501	0.75
311.9375	0.06
312.7518921	0.49
315.1044922	89.52
315.9024048	0.31
317.2974854	0.42
333.53125	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.2545
Annotation	Cuniloside
Peak:m/z	Relative Intensity
158.9294586	1.26
160.9574432	7.48
161.8410034	0.23
164.0567627	0.15
165.0131378	0.32
179.0926361	3.21
206.2175293	0.09
216.9657593	0.02
233.3841248	0.06
234.1833801	0.04
235.2040405	0.18
245.2813721	0.46
246.2179413	0.05
261.3214111	0.48
262.2619019	0.09
275.3341675	0.64
276.2864990	0.17
277.2977295	0.32
285.0157776	0.16
287.3160400	0.72
288.2122192	0.39
301.5413208	0.05
303.4341431	0.06
304.3195801	0.33
305.2517090	1.44
306.3386230	1.09
310.2429199	0.07
313.1643066	0.07
315.2963257	0.16
321.3669434	0.27
326.9918213	0.03
329.1838379	1.85
330.2443848	1.06
331.3257446	3.61
332.2191772	0.52
343.1667480	0.05
345.3667603	0.12
347.3328247	0.78
349.2015991	100.00
350.2205811	21.24
350.8582153	0.18
355.4648438	0.02
358.2203369	0.18
365.0943604	0.35
373.3895874	0.61
374.4492798	0.05
377.1623535	0.29
384.3443604	0.09
389.1865845	0.05
391.3330688	0.25
392.3671875	0.19
397.6135864	0.12
398.8205566	0.07
401.0115356	0.11
407.1431885	0.56
408.2990723	0.19
419.4970093	0.40
420.7207642	0.10
431.1882935	0.03
437.3983154	0.42
438.3425903	0.16
439.3048096	0.19
440.5494995	0.19
448.3207397	0.08
449.2981567	2.68
450.2705078	0.10
465.5079346	0.08
467.3669434	2.73
468.4467163	1.15
476.3892212	0.06
479.1764526	0.14
481.2607422	7.14
482.4105225	4.29
483.3292847	16.26
484.3676147	7.61
493.3003540	3.81
494.3087158	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	706.4285
Annotation	Unknow
Peak:m/z	Relative Intensity
222.1812134	0.10
234.4620972	0.15
296.9640808	0.11
301.7433167	0.08
309.3503723	0.13
337.5027771	0.25
347.1862793	0.38
373.0609131	0.22
381.1349487	0.11
383.4749146	0.28
393.9863281	0.25
425.4718018	0.36
444.9920654	0.84
449.6181641	0.11
452.5750122	0.34
454.4756470	0.17
464.6659546	0.33
469.9907837	0.35
495.1103516	0.07
502.5319824	0.20
509.0668945	1.08
516.7209473	0.29
534.5280151	0.08
535.9351807	0.13
537.2765503	0.11
541.3287964	0.28
546.7853394	0.46
547.4540405	0.23
564.3082275	0.06
566.3408203	3.58
567.5667725	0.09
577.9053345	0.30
578.5366821	0.16
582.5436401	0.12
597.5242920	0.06
606.3812866	1.46
607.2304688	0.43
608.5101929	0.50
628.3385010	1.82
646.6162720	0.11
649.0324097	0.19
659.1041870	0.23
670.3049927	12.56
672.2632446	44.21
672.9287720	0.26
688.3196411	100.00
689.1005249	2.63
689.8239136	0.45
705.7922974	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Gelomulide X
Peak:m/z	Relative Intensity
107.2803650	0.07
112.8450317	0.20
117.0552063	0.07
121.0211182	0.08
123.0323944	0.41
132.9824982	0.18
134.9309387	0.20
136.6283722	0.14
143.9970551	0.16
147.1335602	0.06
150.6322937	0.16
153.0864258	0.11
157.0382385	0.04
159.0643921	0.50
163.0857544	0.08
168.8475342	1.04
173.0445557	0.05
175.0368958	0.29
175.6479187	0.09
178.9408875	0.07
181.0159302	0.14
182.0990448	0.34
183.1511688	0.37
185.1200562	0.07
186.3344727	0.23
187.0087738	0.08
188.8226929	0.14
196.9288635	0.45
200.9673309	0.18
203.0987701	0.87
205.1500549	0.33
207.1568604	0.45
208.9674072	0.26
211.2766876	0.22
213.0567322	0.44
219.3299561	0.30
222.9076538	0.61
225.2201233	2.68
226.1755676	0.16
226.9684448	0.29
229.0506287	1.50
231.0395203	0.42
231.7978821	0.32
235.0912476	0.75
236.2976685	0.05
237.2919617	0.72
239.2921143	1.00
240.0795288	0.22
241.1858826	0.10
243.3966675	0.90
244.9099426	0.18
246.8914185	0.31
249.1796265	0.93
250.3837585	0.51
253.0290527	0.12
254.9589233	0.40
257.1290283	2.73
259.0519104	0.18
261.0350952	0.27
267.2034912	4.07
268.0122375	0.08
269.2283630	0.16
270.4765625	0.16
271.0886230	0.09
273.2827148	0.47
275.1684570	1.21
276.0682068	4.64
276.7451172	1.75
278.0477295	0.24
282.2350159	0.09
285.1426086	22.21
285.9909973	0.53
287.0617065	1.20
289.3105164	0.61
291.0893555	0.13
293.1921692	0.61
294.5910645	0.77
295.2691040	1.35
296.1583557	0.17
300.2593689	0.27
301.2638550	0.76
303.0855408	27.37
304.8905640	1.22
306.0481567	0.06
307.7176514	0.20
308.3635864	0.03
313.0218506	5.11
313.9916992	0.11
317.3827515	0.42
318.1510620	0.19
319.0847168	0.57
321.0903015	4.56
322.3410034	0.11
323.8800659	1.13
326.3691406	0.50
327.3277588	0.07
328.1665039	2.35
331.0144958	100.00
331.9074402	1.22
332.5081177	0.03
333.2822571	0.35
334.2417297	0.43
335.2633667	0.09
336.6204224	0.78
339.2160339	0.08
340.5783081	1.64
341.3089294	0.08
347.0267029	0.25
348.5948181	0.65
349.2091370	2.53
350.3502502	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.1059
Annotation	S-Methyl GSH
Peak:m/z	Relative Intensity
100.2054138	0.02
115.7802582	0.06
117.9579315	0.01
126.0527115	0.03
129.8966522	0.90
130.8628845	0.04
132.0293121	0.02
136.1453857	0.04
141.3016968	0.01
142.1466827	0.01
144.2546997	0.04
146.0371857	0.04
146.9066772	0.05
157.9141235	4.06
158.8025818	0.11
159.9480896	0.64
162.7707520	0.05
174.9960632	1.68
176.0590210	8.97
187.8984222	0.08
191.0103607	0.10
192.9696960	100.00
204.7569885	0.01
215.0685120	0.48
226.8724060	0.03
231.1137695	0.02
232.9841614	4.38
239.1072388	0.14
239.9558105	0.03
242.5419312	0.05
247.3465576	0.02
248.7593689	0.02
257.5085144	0.99
259.0450439	0.22
267.5380554	0.01
268.2410583	0.02
275.9553833	0.01
277.2789917	0.03
277.9309998	0.19
280.3186646	0.07
281.3676758	0.11
286.1658020	0.52
289.9772644	0.34
290.7439270	0.06
304.1884460	5.82
305.1730347	0.20
312.4466858	0.16
313.0991821	0.40
313.7890930	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1259.5693
Annotation	Assamsaponin I
Peak:m/z	Relative Intensity
363.3023071	0.28
378.0813599	0.14
393.1448059	0.56
403.3273621	0.16
425.2341614	0.10
435.5009766	0.09
449.5752258	1.78
450.5444031	0.05
467.2744751	0.08
468.5744019	0.32
469.3913879	3.50
470.1750183	0.67
483.2737122	0.36
484.1352539	0.41
485.4718628	1.05
487.3748169	10.33
488.3055725	1.98
512.2679443	0.21
521.2366943	0.39
537.5360718	2.71
538.2825317	0.36
555.3646240	1.45
556.3696289	0.64
569.4303589	0.32
570.4517822	1.21
583.3657227	0.29
601.4562988	3.69
602.4884644	1.29
609.0786133	0.60
610.4154053	0.59
619.4849854	0.55
620.4387817	0.61
627.4281006	3.30
628.4500122	1.18
643.9120483	0.74
645.3784180	10.06
646.3541870	4.32
663.1204224	0.05
745.4188843	2.31
746.5622559	0.14
763.5029297	3.45
764.6909180	1.63
775.4563599	17.76
776.5363770	3.68
777.4898071	0.11
781.9287109	0.63
782.5439453	0.46
789.4766846	0.41
790.3812866	0.37
807.2922363	0.49
808.2171021	0.19
815.4539795	0.44
819.5771484	0.38
826.2611084	1.77
843.1593018	0.15
868.0770264	0.30
891.5156250	2.60
892.5230713	1.55
897.2604980	0.69
909.4560547	21.31
910.5500488	11.10
916.4060059	0.88
927.4831543	1.95
933.4003906	3.37
934.3645020	1.44
935.3623047	4.54
936.5236816	2.17
953.4083252	100.00
954.5201416	45.36
955.5141602	0.41
971.4276123	95.77
972.4586182	35.55
973.3800049	0.31
995.0911865	0.32
997.4049072	0.58
998.7459717	0.92
1025.3068850	0.62
1069.4528810	0.11
1079.4597170	0.42
1080.3111570	0.60
1097.4472660	3.36
1098.5429690	0.42
1100.3183590	0.05
1113.4021000	0.33
1114.6948240	0.06
1115.9223630	1.86
1116.7569580	0.49
1118.0349120	0.62
1145.1062010	0.44
1189.5086670	0.26
1197.6578370	0.71
1198.5842290	0.46
1217.5219730	0.28
1223.5021970	0.73
1224.4426270	1.02
1241.4266360	21.63
1242.5061040	18.72
1243.6042480	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	217.1543
Annotation	Valyl-Valine
Peak:m/z	Relative Intensity
70.8541412	1.57
71.4890747	0.09
81.0193329	0.06
83.0690155	0.14
87.9517822	42.96
94.7319183	0.10
97.1424255	0.02
100.8966827	0.05
102.9134064	0.05
106.9434509	0.08
108.8707886	0.13
111.1103363	0.09
114.9884949	0.17
120.9464569	0.04
123.0327301	0.41
124.8148804	0.06
126.7277679	0.11
129.0409088	0.42
129.9072876	0.68
130.8718109	0.24
132.8975067	0.02
134.9162292	0.12
135.9109039	0.02
139.0661926	0.02
143.0213165	0.10
144.0664520	2.55
145.0182495	0.29
147.1540375	0.04
154.9665070	0.76
157.1037445	0.74
157.7465973	0.05
158.9853668	0.14
162.9832916	0.03
171.0922089	10.15
172.3550873	0.03
173.0950623	0.85
174.1465454	0.05
175.0365753	0.29
175.8187561	0.23
176.9112854	0.55
177.9678497	0.05
181.0047150	0.30
184.1190033	0.04
187.0517426	0.10
188.1213837	0.13
189.0953217	1.47
190.0503387	0.12
194.8740692	0.04
196.2294464	0.57
197.0601654	0.12
197.8050690	0.03
199.0565338	6.24
200.0453033	100.00
207.6714783	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.2228
Annotation	4,12-dihydroxy-hexadecanoic acid
Peak:m/z	Relative Intensity
93.1441345	0.07
97.0789871	0.19
99.0189896	0.49
108.6351318	0.06
110.9447250	0.47
112.9576874	0.28
125.0852585	0.11
127.0065002	0.89
129.0972595	0.58
137.1525574	0.05
138.3832092	0.08
139.0272522	1.07
141.0624390	3.40
142.0721741	0.23
142.8796692	0.09
149.1088562	0.08
155.1673737	4.33
157.2024231	0.11
167.1374359	0.17
169.0727234	1.05
171.2090607	0.06
174.1934967	0.04
181.2785950	0.19
183.1069336	1.10
185.2495270	0.29
190.0811157	0.05
194.9988403	0.32
196.2045288	0.04
207.2997437	0.27
209.1844482	0.23
211.2991943	3.19
212.2577820	0.14
213.1597595	0.19
216.2192383	0.06
219.3296509	0.04
221.2019348	2.80
223.1222839	2.82
225.3801575	0.05
227.0744629	0.28
229.3121643	0.24
230.9465637	0.11
233.3717346	0.20
237.3776245	0.46
239.1516113	6.88
239.7922974	0.13
241.2640991	20.53
242.1679688	0.52
243.0574951	0.25
243.9090576	0.23
249.3746948	0.35
250.1295776	0.07
251.2471313	4.17
252.6037292	0.37
259.2077637	0.12
265.2606812	3.95
266.4432983	1.11
267.1920166	12.91
269.2093811	100.00
270.3149109	1.26
271.4707642	0.22
283.3957520	0.20
285.0137024	0.13
287.3110962	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1001.48
Annotation	Mukurozioside Ia
Peak:m/z	Relative Intensity
279.2284241	0.13
286.8395996	0.39
323.0380859	0.74
329.0805359	0.14
339.2070312	0.17
340.5024719	0.19
365.0673828	0.41
383.0680542	1.03
384.1793213	0.13
397.1236572	2.01
407.1004639	0.04
410.3753967	0.05
415.1200562	8.02
425.5223694	0.26
439.3681030	0.05
442.8078918	0.19
449.1071167	0.34
457.3209534	0.69
467.1963806	0.68
481.0640869	0.07
485.2821655	1.05
503.5124817	0.11
523.2583008	0.12
527.1269531	0.28
541.2549438	1.41
545.2285156	0.18
559.2598877	9.75
577.2786865	5.54
584.7687988	0.04
601.4399414	0.10
610.9782715	0.28
619.1298828	0.15
622.2912598	0.24
629.1778564	0.09
645.2465820	0.10
647.1399536	0.63
661.4338379	0.06
673.4685669	0.21
677.5543213	0.14
685.5712891	0.20
691.4489136	0.15
693.0485840	0.35
703.2476196	0.58
711.0317383	0.04
717.1813965	0.18
721.2208862	100.00
721.9670410	0.36
739.2269287	49.88
739.9655762	0.42
747.2345581	0.13
754.4549561	0.24
781.2260742	0.14
795.4038086	0.10
797.2194824	0.10
805.5118408	0.05
807.7326660	0.32
839.3038330	3.65
858.5144043	0.15
867.4272461	0.28
876.8734131	0.09
881.2109375	0.12
901.4964600	0.09
909.5638428	0.26
911.6308594	0.28
937.7927246	0.04
949.5085449	0.03
951.2890625	0.05
965.6462402	0.08
967.4602051	0.11
968.7238770	0.07
970.4796143	0.10
982.4838867	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.08
Annotation	Daphnoretin methyl ether
Peak:m/z	Relative Intensity
181.1136627	0.04
204.8674469	0.01
219.1295471	0.02
223.5043030	0.03
231.1252441	0.12
243.0628662	0.04
248.9682922	0.03
251.4758606	0.04
260.1407166	0.02
268.2383423	0.04
271.0139771	4.22
271.6488037	0.03
274.9846191	0.01
279.7441406	0.04
283.0612183	100.00
284.0272827	0.13
294.9753418	0.16
297.1451721	0.09
298.1418152	0.11
303.3330688	0.08
305.0145874	0.03
307.0755920	0.25
308.0167542	0.35
309.0938721	0.21
310.9194336	0.20
321.1724854	0.59
323.2052307	0.09
325.2315063	0.30
331.0381775	0.03
336.9631653	0.06
338.2514038	0.06
339.0750122	0.33
339.9081421	0.02
349.0343933	6.18
350.1896057	0.38
367.0129089	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.22
Annotation	Lobetyolinin
Peak:m/z	Relative Intensity
161.0517731	0.02
185.3109741	0.03
188.8627777	0.02
201.9586792	0.02
209.5288086	0.02
229.0560913	0.03
233.5396576	0.07
253.8324432	0.02
255.4607544	0.05
271.0311890	0.24
273.3624878	0.03
285.2065430	0.03
289.2100830	0.80
303.1589355	0.16
305.3500061	0.10
307.2791748	0.81
315.2058105	0.26
318.0881958	0.07
319.1175537	0.73
330.9675903	0.08
333.2062988	7.18
335.4552612	0.10
336.2254639	0.07
345.5259399	0.04
347.1950073	1.61
349.1002197	0.05
351.1915894	9.15
352.1112061	0.09
355.1495972	0.05
357.2855225	0.03
365.2651367	1.26
370.1296387	0.03
371.2145996	0.14
373.0817261	0.05
375.2792358	0.45
377.1260986	100.00
377.7786255	0.27
383.1445312	0.03
384.5438232	0.03
387.3864136	0.11
389.0584106	0.16
391.1583862	27.61
392.5640869	0.29
393.3242798	4.07
395.1403198	1.76
395.7599487	0.01
403.2203369	0.28
408.0938721	0.11
419.1535645	3.81
422.5334473	0.07
423.3280029	0.08
424.2265015	0.14
431.1658325	0.57
432.1152344	0.09
435.1743164	0.07
437.1685791	8.24
438.1903076	0.17
443.2797241	0.13
449.1776123	0.31
453.4548340	0.10
461.3843384	0.04
467.2270508	0.63
473.1508179	0.17
478.2181396	0.01
479.2373657	0.08
480.3297119	0.03
482.7321777	0.17
485.1396484	0.11
489.1069946	0.02
495.3991089	0.29
496.0356445	0.10
497.2395630	3.75
498.2741699	0.11
509.3776855	0.02
511.8218994	0.03
513.2594604	3.17
514.2034302	0.19
515.0029297	0.08
521.0065308	0.48
522.2515869	0.02
529.2313232	0.24
539.2454834	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.1578
Annotation	(+)-duocarmycin SA
Peak:m/z	Relative Intensity
135.9531403	100.00
144.9053650	4.92
147.2084198	0.45
162.8528900	8.10
211.1322021	0.25
246.2779236	0.24
246.9508057	0.91
253.0831299	0.53
257.1675415	0.31
258.7518005	6.85
267.9572144	0.40
269.0174561	0.51
270.9968872	4.06
276.6571960	1.57
280.0061646	0.71
287.2903442	0.28
288.2308044	5.41
289.0127869	15.29
297.2282104	9.43
297.9981079	64.93
305.9590149	1.56
306.9397888	6.74
315.0295410	9.56
315.8517761	77.31
320.9122009	0.11
322.7922668	0.15
324.1336365	5.93
324.9379578	40.57
327.0548401	0.94
339.1339722	1.05
342.4268188	6.70
343.1114807	2.99
345.2366333	1.32
346.1615601	0.40
347.2322083	0.57
349.5153809	0.38
378.0169983	0.32
379.7071838	0.37
387.2144165	0.45
388.2345276	0.94
396.6417542	0.76
417.8404236	0.25
441.1887512	0.75
441.9836121	1.13
458.9886780	0.46
460.0524597	4.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.03
Annotation	Unknow
Peak:m/z	Relative Intensity
65.7847366	0.03
89.1259155	0.01
109.8493042	100.00
110.6502380	0.03
123.0882874	0.01
127.8114319	2.94
130.3286743	2.38
132.7901611	0.04
133.4731598	0.03
139.2952423	0.77
140.2264404	0.01
146.0036621	0.02
150.8865204	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
147.1924744	0.02
151.9343719	0.02
179.1992188	0.04
191.228363	0.02
217.9367371	0.01
230.0665436	0.03
242.0791626	0.01
243.2224121	0.01
244.2315063	0.06
249.1408386	0.02
252.2671509	0.03
255.5209961	0.02
266.9773865	0.09
269.1486206	0.20
270.3178101	0.06
283.1102295	0.40
284.2085571	0.13
293.1426392	0.06
294.2034912	0.02
297.2582092	0.02
301.4248047	0.03
309.2058716	0.02
311.059845	100.00
312.0329285	49.28
312.736084	0.08
321.0252686	0.03
322.1314087	0.02
323.0367432	0.27
324.13974	0.17
325.3535156	0.02
328.2857666	0.01
335.0698853	0.02
337.2171631	0.06
338.1166992	0.03
339.0116272	0.03
341.1162415	14.39
342.1100464	6.83
349.2114563	0.03
350.0846863	0.02
352.0041809	0.03
353.2291565	0.92
354.2250977	0.35
355.1861572	0.23
356.1300659	0.12
365.0997009	0.07
366.1863708	0.03
366.9825745	0.02
368.2452087	0.05
371.1979065	0.48
372.1229553	0.26
377.1476135	0.26
378.112915	0.18
383.1614685	0.40
384.0531311	0.26
395.1547241	0.34
396.0621338	0.40
413.1017761	2.25
414.1438293	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1173
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
135.6673889	0.10
160.1331024	0.22
161.1437225	0.05
162.6026611	0.10
165.9309082	0.20
167.2258606	0.17
191.3103790	0.12
194.9208679	0.06
196.8080139	0.17
208.9778748	0.13
212.8432617	0.29
223.1121521	0.13
223.9223022	0.37
233.1736450	0.21
246.1793213	0.16
246.8245239	0.10
248.2216187	0.16
251.1051636	0.12
263.0785522	0.15
271.1211548	0.43
282.9843140	1.24
287.1301575	1.27
293.3321228	0.12
297.1904297	1.93
299.2156982	0.25
300.2675476	0.12
301.0584717	0.04
305.2429199	1.53
310.1215210	0.08
311.0656738	1.29
315.0389099	9.21
317.9258423	0.19
321.0309753	0.16
323.3563232	0.09
325.2076721	0.32
327.0117798	0.16
329.0262146	12.24
331.2767944	0.22
336.6609802	0.05
337.3424072	0.15
338.2151489	0.24
346.8037415	1.02
351.6156006	0.15
353.0901489	2.35
361.5468140	0.08
367.0643005	0.22
369.1667480	0.24
370.9039307	0.21
375.1351624	0.23
379.8470154	0.20
382.9488220	0.85
385.2107239	2.65
391.1887817	0.33
395.2264709	0.68
397.7763062	0.17
403.4532166	0.28
404.4139709	0.08
413.1061096	2.30
420.8759155	1.30
426.0928345	0.55
431.0377502	12.93
439.1925049	0.15
449.0240784	100.00
457.5820923	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	863.202
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
241.1581573	0.00
242.1219177	0.00
244.0508881	0.02
248.2748413	0.01
249.3064423	0.01
249.9511108	0.00
254.1994171	0.02
255.2098389	0.04
256.2908630	0.01
258.3472900	0.00
263.8697205	0.01
265.0795898	0.03
267.5288086	0.04
268.1940918	0.18
269.1107788	0.13
270.0684204	0.03
271.2888489	0.01
281.2044067	0.04
282.2477417	0.20
283.1362915	4.67
284.1300964	2.14
285.1946411	0.01
291.2360229	0.00
293.0096130	0.13
294.1399536	0.09
295.1959534	0.04
296.3055725	0.02
307.4278259	0.02
309.1752319	0.06
311.1174927	17.14
312.2084656	8.33
313.1380615	0.06
323.1864014	0.32
324.0902710	0.16
325.2734375	0.02
326.3370056	0.00
335.0468750	0.02
337.1753235	0.01
338.0923462	0.01
339.1181641	0.03
340.0983582	0.01
341.1563721	1.46
342.1468506	0.68
342.7565002	0.00
349.3055115	0.01
350.5874023	0.01
353.1591797	0.05
354.1597290	0.07
355.2868652	0.02
356.3284912	0.03
365.1455078	0.01
365.9721680	0.01
377.3224487	0.01
378.2361450	0.01
383.3180542	0.02
384.4152222	0.01
395.2578125	0.01
413.2218628	0.01
414.2716675	0.01
431.2283936	100.00
432.1334839	45.23
433.1922607	0.71
553.3856812	0.00
696.3741455	0.01
725.1323853	0.02
741.3742676	0.00
741.9918213	0.01
743.3690796	0.03
744.0983276	0.02
771.4271851	0.01
772.1472778	0.02
773.2039185	0.02
774.1292114	0.00
815.1903687	0.00
817.4244995	0.01
828.2678833	0.02
845.4981689	0.03
847.6730957	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.18
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
130.9285889	1.09
134.9305878	0.17
136.6330719	0.18
142.9597931	4.05
148.8425598	0.67
161.0568237	12.15
163.1828461	0.19
167.1172791	0.41
175.0116577	0.31
178.9796906	13.41
187.0172119	1.55
205.1184845	39.54
223.4016113	0.76
226.1675262	0.44
231.1796570	0.21
247.1236267	0.16
249.1343689	100.00
262.8976746	0.17
267.2296143	1.36
268.1859741	0.51
273.4073181	0.22
291.3352356	0.07
297.0159912	1.14
309.1444702	0.78
311.0316162	0.44
313.5199280	0.19
339.0927124	1.91
341.0933533	0.14
345.1475220	0.47
349.0974731	0.16
357.1000366	0.31
362.3634644	0.14
367.1550598	0.38
368.9384155	1.05
381.2670898	0.24
383.2523193	0.36
385.1656189	12.73
387.1203918	0.16
393.1003723	0.89
399.5314331	0.12
401.1386108	0.29
409.2276306	0.32
411.1359863	9.38
413.4126892	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
209.0652161	0.08
223.3126221	0.10
242.0949707	0.03
255.2180634	36.77
261.4099731	0.19
279.235321	100.00
279.8430481	0.50
281.2952881	0.15
283.4199219	0.30
293.2942505	0.37
295.2354126	0.05
307.4580078	0.11
309.3121033	0.12
311.5239868	0.19
328.3764954	0.10
349.4136353	0.03
380.2486572	0.11
391.2440796	0.37
407.1161499	0.09
422.2210693	0.06
434.3413086	1.46
437.9331055	0.04
452.3331299	18.16
458.352478	1.04
476.2138672	1.22
499.3903198	0.08
500.4476318	0.29
503.067749	0.10
518.3967896	0.42
522.3209229	0.12
534.7922974	0.38
541.0089111	0.16
553.21875	0.18
554.3390503	0.21
555.4403687	0.12
572.7358398	0.05
585.492981	0.20
590.0963135	0.06
608.2553101	0.08
621.6456909	0.27
622.4608765	0.08
625.1293945	0.06
627.8034058	0.06
654.5516968	0.44
655.3764038	0.06
686.593689	0.23
695.0952759	0.16
696.2970581	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.17
Annotation	(+)-Jurinelloide
Peak:m/z	Relative Intensity
107.0009537	0.17
114.9624481	0.09
118.7878876	0.20
125.0507050	0.28
126.8003998	0.09
133.0684814	0.62
137.0132751	4.80
140.9958191	0.18
149.0784912	0.75
153.1952667	0.17
157.1510315	0.08
158.9883728	0.40
160.1008301	0.09
162.9529114	0.19
169.2172852	0.53
175.1784058	0.19
177.1622162	0.11
181.0126648	0.07
183.0558777	0.49
183.8538513	0.27
185.3489685	0.08
189.0807495	0.80
190.2649536	0.08
194.9939575	0.12
195.8876038	0.07
200.6665344	0.32
205.0743561	0.19
207.0835876	0.53
209.3566589	0.08
211.0781860	0.66
212.8866730	0.21
214.3081360	0.27
221.0573120	0.31
222.2665405	0.82
223.2299805	0.08
225.0174561	0.21
227.0853882	0.22
228.1470032	0.08
232.9440308	1.95
234.5166931	0.22
238.8241577	0.20
240.8527527	0.26
243.0506897	0.40
245.6048584	0.12
249.1722107	0.30
252.6339111	0.26
253.7700195	0.21
256.9609375	0.48
258.2615356	0.27
259.0340576	0.29
261.2365723	0.14
264.0693359	2.18
264.7500610	0.63
265.3960266	0.50
266.1765137	0.36
267.4482727	0.09
269.5310059	0.50
270.7347412	0.60
273.2462769	0.20
274.1730347	0.24
276.7438049	0.21
281.0407410	0.70
282.1147461	0.57
285.3541870	0.14
286.5036621	0.41
287.1250305	0.08
291.1928101	0.37
295.1321411	8.52
296.3147583	0.17
299.1513062	0.42
300.9529114	0.97
303.9491882	2.61
305.7272644	0.60
309.0816345	0.88
312.9678650	0.33
315.0784912	0.15
317.0894775	0.23
324.3283691	0.92
327.0753784	100.00
328.1437073	0.81
330.3059692	0.39
331.0236816	0.25
332.7806396	0.86
336.1846619	1.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.2755
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
206.1718903	0.03
207.0365601	0.02
224.1649170	0.01
225.3301544	0.02
253.2659302	0.02
265.3401489	0.04
280.1912537	0.03
282.0842896	0.01
289.4075928	0.05
290.4495544	0.01
301.2117920	0.02
326.1304932	0.01
331.4239502	0.01
336.3404541	0.06
340.1837158	0.06
368.2002563	0.02
372.2925415	0.01
374.3328247	0.02
375.2900391	0.01
376.4094238	0.06
386.2567139	0.01
388.3000488	0.04
388.9588623	0.02
390.2528687	0.03
398.0069580	0.02
410.0292969	0.05
412.4432983	0.02
421.3125000	0.03
431.1557007	0.03
433.3146973	0.02
434.3677979	0.16
435.3715820	0.06
441.9736328	0.02
446.3334351	0.01
447.3193359	0.20
448.4815063	0.13
459.1974487	0.57
460.4492188	0.89
461.3495483	1.52
462.3989258	0.34
463.7915039	0.07
471.1017456	0.03
473.2765503	1.95
474.3257446	0.58
476.4472046	0.06
477.2962036	0.33
478.2930908	0.07
487.4633789	0.74
488.5100098	0.18
489.3212891	0.33
490.3213501	0.01
491.3526611	0.70
492.2767334	0.97
493.3512573	0.29
494.4152832	0.01
499.3184204	0.09
500.5126343	0.03
501.5039673	0.04
502.5029907	0.08
503.6066284	0.32
504.3978882	0.34
505.3080444	0.41
506.3781128	0.22
507.1695557	0.07
515.1875610	1.16
516.3234253	0.45
517.4512329	0.21
519.1752930	0.80
520.3444824	0.65
521.4386597	0.14
529.7440186	0.02
531.2625122	0.20
533.2859497	100.00
534.3796997	30.29
535.4717407	0.04
537.4412231	0.10
543.2600708	0.15
544.4060669	0.10
547.2743530	1.42
548.3827515	0.42
549.3541260	0.13
550.2820435	0.15
551.3543091	0.27
552.3587646	0.10
557.5435791	0.03
560.6759033	0.43
561.3805542	1.54
562.1846313	0.30
563.2656250	0.05
564.3621826	1.94
565.3482666	3.16
566.2926025	1.13
575.3178101	2.55
576.3484497	0.82
577.2488403	0.10
578.3401489	0.19
579.2355347	0.01
592.4102173	0.42
593.6026001	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.43488312	0.29
80.7612915	1.89
93.05030823	0.70
95.15953064	1.12
96.92021942	1.04
103.0266113	3.03
104.8913116	0.29
106.253067	1.60
109.0784454	0.48
110.9800262	1.04
120.8379211	0.79
123.1558838	0.23
124.7426147	1.23
127.0723419	0.50
128.9911346	11.41
129.8462372	0.73
132.9623566	0.62
135.0057678	3.31
140.5407867	1.51
143.1375122	1.70
144.7337799	0.92
147.323349	0.56
148.1054535	1.14
150.9677582	100.00
151.9395294	9.65
152.8925171	0.49
154.9676056	0.75
160.9292603	1.61
165.4800262	1.47
166.4660645	1.44
167.0678864	4.73
175.0424347	1.94
179.0744171	1.90
182.0328827	0.80
182.741806	0.37
185.0150299	3.44
191.3446503	0.29
193.1062469	0.89
194.0776672	4.79
197.0641174	3.28
198.5214081	1.00
200.9530487	0.23
210.0368652	1.21
211.1068268	1.29
211.8730011	0.80
217.191925	1.75
223.2577515	0.48
225.1681061	7.47
226.0942383	2.28
235.0625153	19.56
238.1091461	16.35
239.0336761	3.38
253.0894165	94.96
254.1103973	11.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0856
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
81.12754059	0.98
82.92478943	0.71
94.87174988	0.95
102.7256317	4.06
105.0644531	0.83
106.9243469	0.40
109.037323	0.74
117.2258148	2.05
122.9567566	1.96
128.8687744	9.78
129.9633789	2.16
130.9665375	0.32
132.8393707	1.06
134.2648315	0.65
141.1838531	0.62
144.9402161	1.64
146.8690491	3.44
150.8763428	100.00
151.8626556	4.92
165.112854	0.80
166.2119293	0.32
167.0667419	3.74
169.0075378	2.49
171.1525574	1.28
174.7127075	0.34
176.0642853	0.27
177.0493164	0.52
179.1442108	3.43
180.1546173	2.00
180.9852295	2.31
181.7509918	3.93
183.2873383	0.79
184.0504913	0.40
184.9814301	3.27
189.2841187	0.95
194.0774231	1.54
195.3145599	0.24
197.033371	5.73
197.7954254	0.52
199.3970642	0.44
207.0175171	1.78
211.3043365	2.44
217.2109528	3.46
225.0942688	7.59
226.2524261	0.57
235.1496735	17.09
238.1553497	18.94
238.9754639	5.16
243.7069855	2.28
251.1052246	0.27
253.077713	98.85
254.0294189	7.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.1499
Annotation	Crispine C
Peak:m/z	Relative Intensity
84.9410400	0.77
86.9631348	0.61
92.9043350	0.63
95.0220337	5.82
95.8202057	0.17
97.0267716	4.91
99.1257172	0.21
102.8655701	0.30
105.0066376	0.14
105.9972076	0.12
106.9631195	9.15
108.8881226	8.52
110.2191620	2.04
111.0338364	4.73
112.9509277	6.43
114.8930359	7.50
118.8695755	0.71
121.1145935	0.39
121.8316727	0.33
123.0156555	7.50
124.9398193	100.00
126.8954468	1.23
129.0749512	0.08
130.9262390	0.26
133.0613708	10.36
135.0335388	3.98
136.9812622	16.43
139.1390686	0.35
141.0174561	0.57
142.0114288	0.40
143.0242310	0.99
145.0673828	0.90
146.9984436	1.58
148.0626221	1.05
149.0459595	3.89
151.0674438	29.97
153.1282654	2.35
154.9726868	4.15
156.7818298	0.29
158.8233337	0.38
160.9014130	0.82
163.0268555	5.47
164.9857941	1.58
166.9779358	4.92
168.9837799	0.19
170.9976196	6.34
173.0312653	1.80
175.9397583	0.24
176.9898529	0.16
178.1750336	0.12
179.0847168	2.45
180.2054138	0.19
181.1114197	8.66
183.0026550	0.10
185.1174011	0.45
189.1569977	9.53
191.1319427	67.78
197.0760193	3.52
198.8097839	0.10
201.0412598	0.27
207.1107483	5.09
209.1787109	18.22
210.8881531	0.29
223.4201660	0.35
224.8688354	0.35
227.1292725	5.98
232.7930908	0.17
240.9171143	0.36
243.0380554	2.14
244.4153442	0.55
245.3980103	0.59
259.1225586	7.25
267.1103210	0.32
269.0851746	33.02
271.0691528	0.31
271.7377014	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.2119
Annotation	Unknow
Peak:m/z	Relative Intensity
204.9691467	0.20
226.1509857	0.19
235.0148773	0.15
282.9419250	0.08
285.9302979	0.13
295.0617676	0.76
313.0335693	0.58
313.8950195	0.16
320.2950439	0.14
322.0351868	0.23
324.1384277	0.10
325.2594604	0.50
337.0034180	0.05
342.3052979	0.19
343.1922607	0.38
349.2261353	0.45
355.2009888	0.12
367.1473389	0.71
373.1276855	0.21
379.0551758	0.98
397.0714722	0.72
398.4837646	0.15
409.0770874	1.29
415.3583374	1.54
427.1203003	3.80
433.0752563	4.45
433.9534302	0.34
445.0632324	20.24
447.3776245	0.15
451.4008179	0.40
454.9466553	0.12
463.0285034	100.00
463.6945801	0.65
466.3263550	0.85
486.1621704	0.18
486.8629761	0.21
502.7880249	0.33
503.7832031	0.17
505.1157227	0.52
510.4122925	0.21
512.4881592	2.28
513.2902222	0.10
519.4973755	0.21
520.2958984	0.13
521.2014160	0.62
529.0170898	0.40
546.2273560	0.20
558.7863159	0.14
561.1097412	0.19
571.0944214	0.21
576.6944580	0.08
579.5492554	2.22
580.1764526	0.43
581.6270752	0.24
583.7512817	0.20
586.1008301	0.43
588.8236084	0.26
601.0350342	0.56
603.2265625	0.28
605.1051636	0.19
614.0468750	0.63
623.4216919	1.71
631.2063599	2.59
632.2835083	0.83
640.3640137	0.32
645.0767822	0.07
649.1982422	36.96
650.3136597	0.43
658.8591919	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5063
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
211.3405304	0.18
214.2160187	0.29
223.0772858	0.10
241.0188446	0.05
249.0566254	0.18
255.1950378	36.30
256.4931946	0.09
259.0977783	0.18
261.2617493	0.30
272.9067078	0.07
277.4590149	0.18
279.229126	100.00
279.8582458	0.44
281.4825134	0.09
293.2298584	0.34
297.5450134	0.04
307.4790344	0.10
311.135376	0.09
323.0264282	0.07
326.2246704	0.10
327.1997986	0.38
328.2602844	0.11
329.5280762	0.11
347.9605103	0.08
363.1137085	0.10
375.045105	0.10
377.3666992	0.39
378.161499	0.13
380.3410645	0.12
389.2601318	0.12
391.1526489	0.42
397.0123901	0.18
398.2228394	0.08
402.2750244	0.33
403.3582153	0.57
404.3041382	0.22
426.2567749	0.10
429.4171143	0.08
434.2453613	1.85
443.9315796	0.11
445.0890503	0.17
446.9298706	0.27
452.3261719	20.29
453.5274048	0.15
458.2128296	1.13
458.8830566	0.07
462.2473145	0.36
465.4638062	0.11
476.3897095	1.46
480.7172852	0.10
488.2822266	0.22
496.3665161	0.13
516.0725098	0.17
518.6584473	0.25
527.4743042	0.27
532.6748657	0.17
554.2249756	0.11
556.5248413	0.08
583.0300903	0.06
597.4041138	0.19
619.9840088	0.28
621.5132446	1.14
622.3835449	0.23
629.2700195	0.13
637.4040527	0.62
638.3831177	0.63
639.4406128	3.47
640.4293823	0.79
646.1931763	0.13
654.3484497	0.04
655.4046631	0.25
657.491394	0.09
662.6216431	0.37
667.7688599	0.23
669.6424561	0.05
670.4197998	0.12
671.5309448	0.43
677.984314	0.28
679.8395386	0.18
694.4159546	0.09
695.6119995	0.67
696.4144897	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	283.0683
Annotation	Oxoformycin
Peak:m/z	Relative Intensity
108.0612793	0.20
112.9699173	0.05
150.9252472	100.00
195.0882874	0.11
195.8711853	0.03
198.0927734	0.03
224.7362061	0.06
236.1935730	0.07
236.8596802	0.20
239.1542358	0.13
244.7860107	0.04
262.9830627	0.05
265.1168823	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2142
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.9160767	0.21
203.074173	0.31
214.8514404	0.12
221.0075073	6.22
235.5303192	0.10
250.807312	1.66
262.769165	0.36
268.475647	0.13
280.8243408	1.16
292.5745544	0.09
305.0543213	0.93
311.1526489	0.73
322.8363647	5.06
323.5041504	0.09
341.0220337	25.92
383.1289062	100.00
394.8273926	0.13
397.1206055	0.21
407.3023071	0.75
410.6236572	0.05
411.2896118	0.38
412.7783203	1.95
413.4307861	0.11
421.1725464	0.20
425.1797485	1.79
442.2808228	2.68
442.8996582	14.09
443.5876465	0.03
467.2538452	1.31
468.2208862	0.15
472.8875122	1.32
485.1115112	29.21
502.9682617	3.41
543.8953247	0.06
545.2345581	1.58
621.9265747	0.32
647.0654907	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
166.94664	0.08
181.2343445	0.02
211.1879425	0.01
233.1387939	0.03
255.271286	0.09
268.8822632	0.03
270.9904785	1.31
278.7177734	0.11
283.0135193	0.34
288.057312	0.08
295.229126	0.43
297.7151489	0.02
307.2056885	0.06
309.3114624	0.04
310.1259766	0.05
313.0842896	4.14
325.3098145	0.03
327.017334	0.07
331.1357422	0.04
333.3411255	0.19
337.0653687	0.61
343.2553101	0.02
350.029541	0.11
351.2171021	0.12
352.8575439	0.06
358.9590454	0.03
363.2973022	0.10
367.0842285	0.87
368.0994263	0.23
369.2346802	0.04
375.2677002	0.01
376.147522	0.03
377.1715088	0.12
379.137146	0.39
384.0597534	0.03
386.067627	0.07
387.2409668	0.08
397.1258545	1.27
398.2001953	0.14
399.3400269	0.07
403.2714233	0.04
407.3261108	0.05
409.2037964	0.05
415.1324463	12.77
416.208374	0.78
417.2023926	0.63
421.0830078	0.04
423.2509766	0.07
427.1192017	0.07
433.1148071	100.00
433.7609863	0.24
435.1948242	0.03
443.37854	0.08
446.0789185	0.03
448.7084351	0.08
449.4255981	0.11
454.7659912	0.02
457.2582397	0.04
458.4376221	0.11
459.2324219	0.15
462.9347534	0.07
463.8317261	0.06
474.9785156	0.01
481.0794678	0.11
483.0154419	0.04
487.6591797	0.03
497.3248901	0.09
500.1286621	0.07
504.3745728	0.06
512.4794312	0.04
513.0946655	0.02
517.3733521	0.12
525.0517578	0.28
533.2263794	0.02
538.4046631	0.02
542.5958252	0.09
543.3364258	0.24
548.3899536	0.03
550.7456055	0.10
557.7379761	0.06
559.6473999	0.08
560.4189453	0.85
561.1224976	0.76
569.5939941	0.32
570.3303223	0.08
573.2650757	0.05
579.317688	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	352.1036
Annotation	Sambucus nigra Degraded cyanogenic glycosides (2'-Epimer)
Peak:m/z	Relative Intensity
100.8724823	1.68
111.0212708	0.78
112.9906921	2.98
116.9525681	0.20
117.9579468	0.51
120.0788116	0.66
124.8585052	0.19
128.1690063	0.29
128.8759155	0.11
129.9032745	0.17
131.0078888	1.99
131.9490356	9.29
134.0442505	0.21
141.9187927	0.73
142.9955444	1.26
143.9741211	6.66
145.9607239	11.83
147.0065460	1.79
147.9297791	6.52
148.8317413	0.57
149.9809570	1.70
154.8949890	0.08
157.9589539	0.57
159.9669647	100.00
160.9437866	1.92
162.1287689	0.16
164.1221924	0.33
166.0325623	0.23
168.1791687	0.16
169.9304199	1.90
171.9626160	28.38
174.0774841	19.75
175.7250214	0.70
177.9016113	0.79
183.9842529	0.78
186.0313721	13.66
186.9060059	0.13
187.9808350	1.15
189.8895569	0.75
194.2009277	0.35
196.0834808	2.21
197.0503082	0.15
198.3154297	1.21
199.0059052	0.09
200.0384064	3.30
202.0662994	30.89
202.7553253	0.22
204.0747681	4.02
206.1275940	0.13
210.2093201	0.38
212.1687164	2.05
213.9463501	33.01
216.0674438	0.71
218.0886841	0.86
220.2982178	0.23
221.0182800	0.41
226.0074463	1.29
227.9489746	4.59
230.0205994	0.33
232.0331726	3.79
234.0225830	0.31
235.9111633	0.10
238.0928040	0.54
244.1564331	0.84
246.0806885	1.47
248.1005554	0.27
256.0843201	1.70
258.0118408	0.14
264.1080322	1.36
269.1401367	0.44
270.8387756	0.68
273.8088989	0.67
280.0603638	0.28
288.1350708	0.24
289.2978210	0.39
290.1833191	0.25
292.1433716	50.43
297.2707214	0.54
298.0941467	0.63
305.4289551	0.36
306.1244812	0.34
307.1935730	0.97
310.1463318	26.34
313.9810181	0.16
315.4758301	0.23
316.3329468	0.42
325.2839661	0.41
334.0516968	0.49
336.9486389	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	282.0844
Annotation	Crotonoside
Peak:m/z	Relative Intensity
106.9397278	0.16
114.9527130	0.02
132.9757843	3.84
133.8718872	0.03
138.9313354	0.03
149.9267578	100.00
150.7888794	0.03
191.9475555	0.05
222.5193481	0.04
235.9190674	0.07
237.9210205	0.06
240.2112732	0.08
263.8102112	0.14
265.0869141	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1712
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
165.2079773	0.05
167.0761719	0.02
176.9028473	0.80
185.0378876	0.05
223.0369415	0.14
227.2526245	0.06
237.1389465	0.03
249.3059235	0.07
253.0534821	0.29
257.0721130	0.11
260.9115906	0.04
263.2071533	0.07
271.0065613	100.00
271.6071167	0.43
282.8348999	0.04
283.8993530	0.06
285.0754395	0.03
285.9526978	0.06
290.0254517	0.16
295.1978760	0.56
296.2967529	0.05
311.1571655	1.03
312.0669556	1.18
313.1611328	0.59
315.1915283	0.93
319.2018433	0.06
320.2173462	0.02
323.1165771	0.05
324.7103882	0.03
327.2060547	0.09
337.3656616	0.02
340.4688721	0.04
342.1672363	0.31
343.0816040	0.08
355.3712769	0.06
357.1409912	0.09
367.5025024	0.03
371.1400757	0.03
371.7561035	0.07
373.1100464	0.08
374.0955811	0.13
376.8861084	0.04
378.5256348	0.05
381.3217773	0.12
387.1782837	0.02
397.9287720	0.21
399.3750000	0.16
403.2089233	0.10
404.9379883	0.15
407.2674561	0.08
409.0352783	0.02
412.0526733	0.03
414.9669800	0.26
417.1583862	3.01
424.0736694	0.19
426.9722290	0.13
430.8475342	0.05
432.4752808	0.08
435.3038940	0.03
440.5077515	0.14
444.2222900	0.09
447.1999512	0.16
448.1812744	0.15
450.6276855	0.12
457.9985352	0.20
459.1817627	1.11
471.1221924	0.09
473.0986938	0.15
473.8658447	0.03
475.2105103	0.09
485.1071167	0.17
485.8874512	0.04
488.8882446	0.03
490.8215942	0.02
491.4577026	0.03
500.0848999	0.04
505.1799927	0.14
506.1507568	0.13
508.0632935	0.09
515.9919434	0.09
517.9625854	0.13
526.3380737	0.02
530.0946655	0.04
532.0680542	0.58
533.0892334	1.42
534.8115845	0.33
535.5712280	0.02
543.1787720	0.19
547.0888062	0.09
551.2633667	0.18
555.6016235	0.05
560.1424561	0.22
561.2153320	0.33
562.4436035	0.05
564.1860962	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	654.3037
Annotation	Unknow
Peak:m/z	Relative Intensity
250.5455322	0.13
265.3915405	0.17
278.2625122	0.25
289.1670837	0.16
296.1137085	0.10
305.8858643	0.09
342.0618896	0.05
371.2268066	0.25
374.1366577	0.15
394.8595581	0.44
410.3276978	0.32
428.8468018	0.18
432.9853516	0.18
441.2088013	0.07
446.4201660	0.10
454.5411377	0.15
466.1575317	0.11
483.4841309	0.31
488.2462769	0.17
489.1572266	0.64
490.1589966	0.74
507.2698364	55.92
508.3486328	0.12
525.1244507	10.64
533.9570923	0.25
536.2465210	0.70
538.4743652	0.61
546.8709106	1.49
547.5072632	1.06
552.0424194	0.48
554.5731201	0.45
561.5297852	0.11
565.5076294	0.15
567.0652466	0.24
597.3030396	0.26
600.2509766	0.18
608.0049438	0.07
618.1057129	1.86
622.5453491	0.72
627.6632690	0.18
630.3883057	0.57
636.2526245	100.00
636.9396973	0.26
653.6192017	0.12
654.2357178	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.2279
Annotation	2-Pentadecanone
Peak:m/z	Relative Intensity
114.9774323	0.01
193.2669830	0.08
196.9989471	0.01
223.2429810	0.61
225.1695709	100.00
227.2216797	0.12
230.8654633	0.02
241.2287598	0.04
253.2409210	3.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1609
Annotation	Isorhamnetin-3-Glucoside-4'-Glucoside
Peak:m/z	Relative Intensity
180.7162018	0.06
181.3446198	0.07
183.9836578	0.28
191.0552368	0.08
196.9275818	0.15
198.6829834	0.35
202.9085083	0.37
205.0437775	0.30
207.2849121	0.15
208.8758545	0.13
213.0275116	0.08
217.0118713	0.09
219.1171875	0.18
223.555603	0.23
227.0357056	2.35
227.9361267	0.06
229.1774139	0.13
230.2248993	0.08
231.3254089	0.14
233.2968292	0.21
243.0572205	0.24
253.257782	0.14
254.0462646	0.41
255.0686798	25.46
256.135376	0.28
266.7017517	0.35
268.578186	0.13
269.2004089	1.44
271.0444946	16.51
272.1109619	8.75
274.1998291	0.17
284.4144287	0.30
285.2404785	0.74
287.0537109	1.01
295.2825317	0.17
297.1829224	0.09
298.0940552	0.42
299.0387573	8.12
299.9971924	62.18
301.1642456	0.97
309.9221802	0.19
313.0971069	0.86
314.2536926	11.16
315.0481567	100.00
316.1045532	1.66
325.0903931	0.34
327.3683472	0.11
329.0379028	0.34
339.1340332	0.66
341.3039551	0.18
342.2349243	0.17
343.2539062	0.14
357.1957397	3.76
358.0455933	0.24
366.6831055	0.14
371.9313354	0.53
373.534729	0.34
379.3092651	0.11
381.9317627	0.18
384.5212402	0.18
387.0513916	1.36
399.2059937	0.24
408.8005371	0.83
414.2891235	0.17
418.9782715	0.14
429.8861694	0.09
440.1515503	0.31
442.3606567	0.09
454.263916	0.34
457.2241211	0.10
459.0789795	0.32
460.2390137	0.82
461.0430298	0.13
463.2460327	0.23
467.0789185	0.10
477.272583	0.55
484.9439087	0.12
487.111084	0.09
490.3676758	0.05
501.1588135	0.26
502.1958618	0.19
503.1477051	0.92
520.3012085	0.22
523.6661987	0.21
530.9989014	0.27
533.1254272	0.42
539.0608521	0.27
557.048645	0.07
564.5419922	0.08
576.2818604	2.47
577.140686	2.65
578.4086914	0.95
592.1987915	0.34
594.4906616	0.72
595.3492432	0.32
596.0427246	0.05
603.5576782	0.30
604.2941895	0.55
605.3091431	1.44
608.2525635	15.43
609.2171021	0.32
613.1222534	0.25
622.9678345	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1263.6006
Annotation	Lablaboside C
Peak:m/z	Relative Intensity
539.6037598	0.12
620.3671875	0.15
621.3818359	0.07
728.6237183	0.05
781.3221436	0.49
782.2011108	0.25
782.8421631	0.18
783.7659912	0.36
817.3632812	0.03
824.4103394	0.42
851.5249023	0.08
863.1893311	0.15
876.5109863	0.04
877.3697510	0.05
896.7875977	0.03
903.7066650	0.12
904.4505615	0.05
922.3725586	0.08
923.3461914	0.10
925.1137695	0.05
939.5056152	0.09
947.5617676	0.14
957.9573975	0.29
982.5040283	0.04
1000.4222410	0.03
1001.6655270	0.10
1013.2673340	0.05
1040.6116940	0.19
1041.4916990	0.19
1057.5833740	0.10
1058.6359860	0.06
1066.2133790	0.05
1077.5800780	0.09
1084.5682370	0.61
1101.5028080	0.59
1102.5004880	2.34
1103.4888920	0.62
1119.6428220	17.71
1120.5349120	100.00
1121.4885250	48.91
1122.1765140	0.08
1126.3049320	0.06
1144.5158690	0.94
1145.4874270	0.13
1161.8709720	16.17
1162.5847170	93.73
1163.6395260	39.71
1167.2993160	0.10
1184.3500980	0.54
1185.8476560	0.20
1202.4890140	55.13
1203.4954830	23.55
1204.5168460	0.38
1205.4300540	0.57
1227.6433110	0.07
1229.4946290	0.30
1246.4396970	1.86
1247.4453120	1.23
1248.1107180	0.06
1249.5385740	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Lactulose
Peak:m/z	Relative Intensity
99.1996460	0.22
100.9813080	8.58
106.9363785	0.15
112.8911972	15.87
115.1119461	1.22
118.8659210	13.35
124.9126511	2.19
130.9944000	5.33
143.0178528	19.45
148.8995972	3.49
159.5140381	0.19
160.9059753	21.28
176.5328064	0.14
178.9858856	100.00
191.1359863	0.72
203.1499176	0.34
204.2221985	0.43
220.6710205	0.09
237.2370605	1.05
254.0060425	0.09
280.8879700	2.28
298.3330994	0.13
299.4287720	0.41
309.9315491	0.31
323.0302734	0.30
324.1709595	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	955.5759
Annotation	Unknow
Peak:m/z	Relative Intensity
306.2911377	0.51
337.2421265	52.13
338.0056152	0.02
380.5022278	0.03
442.3237915	0.15
460.2265015	1.67
478.0846558	100.00
478.7567139	0.35
576.4517212	0.03
590.3668823	0.04
597.3626099	0.02
610.2083130	0.02
614.6102905	0.12
694.1543579	0.03
713.3047485	0.17
753.6821899	0.13
781.3098755	0.04
808.6552734	0.06
837.3323975	0.10
865.3749390	0.02
883.4830933	0.10
894.5491333	0.21
916.6556396	0.11
919.6157837	0.02
922.3988647	0.20
936.1514282	0.07
937.3219604	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
214.1725159	0.15
225.2610168	0.12
236.9442291	0.27
251.3659973	0.13
255.1948547	29.44
277.1426392	0.69
279.2349548	100.00
279.8669434	0.25
292.8086548	0.22
293.436615	0.28
320.5719299	0.15
322.3039551	0.30
391.3765869	0.11
397.1480103	0.30
403.6794434	0.33
421.6646118	0.25
434.27948	2.18
438.0646973	0.23
452.3325195	20.19
458.2507324	0.51
476.1469116	1.94
492.4849854	0.27
504.3740234	0.31
526.2919922	0.06
539.1121216	0.19
541.2871094	0.37
562.2682495	0.27
594.2619019	0.22
636.9208984	0.10
644.9561768	0.09
655.4789429	0.08
668.3591919	0.38
670.6994629	0.17
677.9282227	0.33
696.1974487	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1816
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
218.1189575	0.17
222.7526703	0.05
227.1584625	0.05
241.1102448	0.14
251.3632050	0.13
252.3441315	0.02
255.1087646	0.63
269.1713867	0.06
270.1793213	0.06
272.3046570	0.06
273.1464233	0.26
275.1114807	0.05
281.1346741	0.08
283.7852783	0.03
285.1530151	0.52
286.1372681	0.28
287.0888062	0.29
288.1769409	0.32
293.0964966	0.21
295.9638672	0.09
297.1965942	0.10
298.1571045	0.05
311.0993042	0.19
311.9959106	0.50
313.1961975	0.06
315.1766052	17.80
325.2208862	0.04
327.2327271	0.03
331.2352905	0.04
339.2392578	2.48
343.3671875	0.04
345.3913574	0.45
348.1392822	0.03
349.5729980	0.03
355.1999512	0.16
356.8734741	0.14
357.4938354	0.05
360.9458008	0.03
368.1696167	0.11
368.9900513	0.10
373.9686890	0.04
374.6104736	0.24
375.2296753	1.42
376.3260498	0.31
379.1307983	0.01
381.4328613	0.10
383.7027588	0.02
387.0267944	0.25
389.1741943	0.11
393.2006226	0.12
397.4998779	0.11
399.2896729	0.13
400.3842163	0.05
404.0698242	0.21
405.4484253	0.02
407.8971558	0.05
409.0111084	0.03
412.3999023	0.02
413.0078735	0.06
414.0719604	0.11
416.2135620	0.11
417.1790161	1.00
429.3097534	0.06
431.1893311	0.04
433.2815552	1.48
434.2641602	4.42
435.1873169	3.43
446.1978760	0.03
447.3436890	0.11
451.5887451	0.04
457.9990845	0.03
459.2150269	0.11
462.3654175	0.03
463.3012695	0.12
465.2221680	0.02
466.3178101	0.08
468.4768677	0.14
473.2530518	0.06
477.1334839	100.00
477.8048096	0.39
507.1989136	3.54
508.4835205	0.02
513.1425781	0.08
518.4350586	0.08
519.1158447	0.11
521.4221802	0.04
529.4870605	0.08
530.7783203	0.07
533.1912231	0.04
534.5168457	0.20
537.3987427	0.35
550.1008301	0.03
551.1213379	0.25
553.2268677	1.34
554.4450684	0.10
559.2968750	0.03
568.3784790	0.16
576.3101196	0.17
577.2453613	0.06
578.4075928	0.56
579.3394165	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.3013
Annotation	N-palmitoyl phenylalanine
Peak:m/z	Relative Intensity
118.1488953	0.07
146.0059204	0.04
146.9829254	22.54
164.0722046	100.00
165.1409912	0.35
223.2035370	0.10
237.1749573	0.09
254.1826782	17.66
266.2896729	12.23
267.9827881	0.19
329.6213684	0.33
358.3267517	4.01
359.1160583	0.09
360.2486877	0.26
371.4284668	0.36
384.3621521	0.65
400.7657166	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0929
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
133.9201965	0.02
142.9910431	0.04
150.7438965	0.01
193.036499	0.11
199.0391083	0.01
205.9029541	0.05
211.2665405	0.02
223.3875275	0.03
228.2032166	0.04
234.3349609	0.01
236.8611603	0.02
239.2153625	0.07
252.9658508	0.03
255.1031189	0.11
255.8992615	0.08
263.0042419	0.02
267.1118469	0.21
267.885437	0.01
273.265564	0.04
281.180481	0.06
283.0757446	0.71
285.0487061	100.00
286.0272827	0.18
297.2710266	0.07
298.4715271	0.06
299.25177	0.09
301.3631287	0.08
303.0539246	0.02
304.230896	0.05
307.0770874	0.02
308.1100464	0.03
308.8548889	0.03
310.463562	0.03
311.1469727	0.03
312.2425842	0.02
313.147522	0.58
314.1429443	0.18
327.0173645	10.86
328.1982422	0.13
328.8614197	0.06
331.0046692	0.02
339.2344971	0.04
342.08078	0.04
343.1206055	0.03
349.9938354	0.09
350.90979	0.04
353.1462402	0.05
354.3127747	0.02
357.1907349	3.16
359.0256958	0.01
360.3526611	0.09
361.5210876	0.02
363.064209	0.04
369.1191711	0.49
371.0329895	0.12
371.8725586	0.06
373.1217651	0.04
381.1655273	0.01
387.2519836	0.10
393.1781616	0.17
399.0141907	0.07
400.2796631	0.03
401.319519	0.06
402.4497375	0.14
403.3010254	0.11
409.0612793	0.08
411.0776672	0.17
415.2639771	0.08
416.1560974	0.16
429.1129456	0.55
438.4586182	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.51
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
217.2792358	0.05
222.8485413	0.21
225.357666	0.19
232.9698029	0.06
242.9766235	0.08
253.1109619	0.33
255.2664185	39.48
256.2717896	0.12
257.2619629	0.08
261.0436096	0.85
277.9448242	0.72
279.228302	100.00
279.8439941	0.26
283.2913208	0.07
291.4505005	0.11
292.9941711	0.15
297.0602112	0.15
350.9914856	0.11
365.2251587	0.14
391.2630615	0.44
397.1714478	0.47
407.2262573	0.06
408.291626	0.09
428.9481201	0.18
434.3133545	0.83
451.7288208	2.55
452.3540039	14.13
458.331543	0.38
459.269104	0.20
460.1610107	0.27
476.4240112	2.98
491.8305664	0.27
518.4231567	0.10
526.3789673	0.11
530.2717896	0.23
567.4865112	0.22
595.7757568	0.15
614.7480469	0.07
621.8103638	0.19
639.6326294	0.11
640.3203735	0.28
650.9356689	0.19
655.6343994	0.09
670.2952271	0.15
674.874939	0.11
677.5542603	0.11
695.5760498	0.18
696.3087769	0.60
698.618103	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2622
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0336456	0.05
153.0845032	0.09
179.2265015	0.02
182.0019836	0.02
196.0588989	2.07
214.0950623	1.55
233.2861938	0.42
259.0931091	0.15
261.1712341	0.03
275.3248291	0.36
277.1998291	100.00
277.9747620	0.06
304.9915771	0.04
413.1734924	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5081
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
223.12117	0.37
227.0714111	0.21
235.3568726	0.66
238.0197906	0.15
240.9968262	0.24
249.247467	0.05
251.3467712	0.16
255.3049011	38.21
256.3058777	0.39
277.3372192	0.12
279.2250366	100.00
279.8466797	0.34
284.644104	0.22
293.2165833	0.65
294.1036377	0.29
299.4262695	0.09
389.1525269	0.10
391.2579346	0.41
434.3095093	2.17
435.2348633	0.33
437.3667603	0.35
452.347168	20.76
458.2143555	1.23
476.307312	2.61
490.0385132	0.19
573.7560425	0.11
653.4338989	0.48
654.3106689	0.13
671.3042603	0.08
696.3658447	3.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2806
Annotation	Assamsaponin I
Peak:m/z	Relative Intensity
205.0157471	0.34
206.0737762	0.07
217.0694580	0.19
231.1778107	0.05
235.0429993	1.68
236.1810913	0.31
245.2656555	0.02
246.3650665	0.11
263.0016479	0.06
268.0959473	0.01
269.2734985	0.15
277.1695557	0.90
286.9717712	0.66
305.0205994	4.63
306.0373230	0.46
307.0983276	0.07
313.6251221	0.04
322.3515015	0.12
330.2918091	0.05
377.1900635	0.18
381.1502075	0.14
381.7807617	0.38
387.2705078	0.52
387.8830566	0.18
390.8554077	0.17
404.1439209	0.02
412.6543579	0.02
421.3712769	3.20
422.2963257	0.38
435.7083740	0.02
444.9078979	0.03
454.2471924	0.89
455.1381836	0.28
457.2993164	2.53
458.2748413	0.61
459.0925903	0.17
465.1333008	0.10
466.4143677	1.73
467.4001465	0.27
469.4023438	0.82
470.3430786	0.26
471.6015015	0.07
476.5198975	2.89
477.3885498	0.35
478.0305176	0.02
483.2932129	0.02
485.4816895	100.00
486.3169556	7.26
487.4305420	0.49
488.6361084	0.22
489.6333618	0.03
492.1561279	0.02
492.9995728	0.22
499.2531738	0.03
500.1309814	0.09
503.2189941	0.04
508.2628174	0.05
525.5397339	2.06
526.6567383	0.32
528.1870728	0.07
534.2656250	0.41
535.0058594	0.17
537.6857300	0.17
538.7118530	0.07
539.4307251	0.12
547.3820801	0.05
548.3364868	0.03
551.4638672	0.02
555.5512085	0.25
556.7006226	0.90
557.4441528	0.21
565.7167358	0.06
598.4417725	3.00
599.5220337	0.70
601.2426147	0.10
602.5495605	0.07
607.3027954	0.09
608.1549683	0.16
609.2788086	0.09
609.9886475	0.08
611.3249512	0.11
611.9489746	0.27
620.4945679	12.00
621.5685425	1.36
624.5189209	0.03
645.4318237	1.90
646.4628296	0.31
714.3421021	0.09
727.1786499	0.03
739.3812866	0.03
746.0948486	0.19
747.6253052	0.03
755.4818115	0.01
757.3790894	2.11
758.4523926	0.64
759.4328003	0.54
763.5665894	0.10
773.5835571	0.07
775.4620361	2.52
776.3358765	0.79
777.3903198	0.30
790.5252075	0.06
807.1091309	0.05
809.6540527	0.03
818.4390259	0.08
820.3900146	0.04
842.4922485	0.06
843.3864136	0.08
844.5683594	0.04
857.5700073	0.63
858.4081421	0.54
859.5014648	0.05
871.4019165	0.27
872.4805298	0.12
873.4641724	0.11
887.4590454	0.03
889.5110474	0.41
890.6347046	0.23
891.6729126	0.28
892.6570435	0.03
907.4934082	0.05
909.7449341	0.16
910.4689941	0.04
915.1812134	0.72
916.1891479	0.36
933.4739380	2.74
934.4331055	1.45
935.4082642	0.89
936.5615845	0.66
937.7579956	0.12
938.5263672	0.07
953.4692383	21.10
954.4533691	8.91
955.4768677	3.30
956.4515991	0.23
971.4647827	9.01
972.4478149	5.06
973.5060425	0.88
974.5573730	0.12
997.2809448	0.03
1033.5275880	0.13
1034.3359380	0.06
1035.4744870	0.06
1183.8460690	0.06
1184.7846680	0.06
1185.5286870	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3232
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
165.8693237	0.16
183.9667358	100.00
184.7825317	0.04
258.3681335	0.08
335.4481201	0.24
377.1303101	0.03
389.3917236	0.12
412.0371094	0.04
441.3515015	0.08
469.1211548	0.11
487.5512695	0.26
500.3624878	59.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2174
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
96.8919220	0.96
107.0389709	0.28
107.9112015	0.04
108.9253235	0.46
109.8806305	0.16
110.9198761	0.21
114.9344177	0.73
123.0701141	0.33
124.9691162	2.19
126.8802795	0.04
129.0942688	0.59
135.1719360	0.05
137.1808472	0.19
144.2041016	0.14
144.9171753	0.10
151.1566772	0.13
153.2357788	0.30
165.1552429	0.10
166.0215149	0.11
167.1094360	0.94
169.2196350	0.04
175.2706757	0.04
177.1296692	0.14
178.8952942	0.25
181.2210236	0.85
183.0324707	40.82
189.2366791	0.09
191.1239624	0.25
193.1294556	1.32
195.1325684	9.72
195.8030853	0.16
197.1291962	0.23
203.2312164	0.20
203.8703766	0.07
205.0969696	0.11
207.2197418	0.73
208.9432678	0.34
211.0574036	84.68
213.1914673	2.95
215.1101379	0.08
217.1666260	0.96
219.1584167	0.45
221.2276306	0.81
223.0931091	1.89
225.1838989	0.67
229.1587524	0.30
231.2894287	0.34
233.1395874	3.26
235.0965881	0.91
237.1323242	0.45
239.1018982	0.63
240.1572571	0.20
241.1605530	1.28
242.1071472	0.07
243.1437378	1.78
245.2756958	0.51
247.2131653	1.66
249.2939453	0.70
251.1408691	12.58
253.5097046	0.21
255.1355591	0.90
259.2158203	0.05
263.0651855	0.48
265.4232788	0.43
267.1392822	0.39
269.2479248	20.46
273.2442017	4.13
279.1083679	0.15
281.3694458	0.52
283.2978821	0.23
289.1245117	1.27
291.1854553	100.00
292.2575684	0.18
297.1891479	0.17
299.2289429	0.79
307.2586670	2.25
309.2821655	52.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.2176
Annotation	PGI2
Peak:m/z	Relative Intensity
131.9750366	0.09
139.1140442	0.11
143.2087250	0.22
145.1639709	0.06
150.0788269	0.11
167.0449066	0.08
170.8368530	0.11
179.1257782	0.04
183.2249908	0.27
188.9756012	0.41
191.2512207	1.15
194.1005554	0.14
201.2520142	0.04
205.3206482	0.08
206.1974182	0.10
207.2520447	0.29
213.1822815	0.44
216.8513489	0.32
219.1564636	1.00
220.1230164	0.16
224.9324036	0.08
227.1511841	0.24
231.2285156	4.72
231.9608765	0.14
240.0777893	0.13
245.1764526	1.65
249.5129089	0.11
250.8088684	0.13
253.2152405	0.12
255.2037964	0.30
256.6484375	0.12
257.2695007	5.23
259.1806946	2.66
261.1465454	0.73
265.3182373	0.36
269.2571106	2.79
270.3454590	0.06
271.3738708	1.13
273.2776184	4.28
274.1436768	0.07
275.2183533	13.20
276.1789551	2.18
283.9516296	0.53
285.2030029	7.23
287.1906128	81.18
288.2260742	8.16
289.2675171	10.66
290.2366333	0.61
292.0390320	0.16
295.3294373	0.20
297.5700684	0.35
301.1083069	0.94
302.1976013	0.19
303.2315063	5.04
305.2204590	100.00
306.2984314	6.14
307.2665100	26.59
308.3368835	0.39
309.3190308	0.15
313.1500244	1.73
314.0774231	0.40
315.2683716	1.24
315.9919434	0.66
319.3175964	0.37
320.8019714	0.06
321.4147339	1.17
322.3991089	0.25
325.9750061	0.16
331.2226562	8.94
333.2015381	65.59
334.2774658	4.93
335.1687622	0.24
336.1541443	0.15
337.0281067	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.0435791	0.82
94.93769836	0.76
102.9530334	1.77
103.5883942	0.41
104.8961639	1.00
106.7802582	0.84
108.9045715	1.07
122.8457642	3.35
128.93013	10.78
130.1017914	0.53
141.2136688	0.43
150.9080963	100.00
151.9173126	8.25
154.1241913	1.40
154.9886322	1.25
157.7121582	0.55
166.061554	0.98
167.1576385	0.99
168.036499	0.21
169.124939	0.70
169.9193573	0.72
179.0686493	5.40
180.1730804	0.52
181.9933014	4.90
183.0361481	0.59
185.1539917	6.16
186.3807526	0.53
193.9037628	0.22
194.7811432	0.70
197.1614532	2.78
198.0982513	1.78
207.103714	0.27
210.0962219	0.43
211.0467224	0.32
225.0787201	5.33
226.1364136	0.69
235.1310577	0.20
238.1285248	21.78
239.1741333	2.22
251.9320068	0.38
253.0924683	68.22
254.1008759	3.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.2866
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
169.0339813	0.02
171.1342468	0.18
173.1326599	0.25
175.1445465	0.15
177.1347046	0.02
183.0457153	0.01
183.9324036	0.07
187.0963593	0.51
188.9322815	0.16
191.1103516	0.26
193.2203674	0.15
197.0560760	0.10
199.0865631	0.02
201.0876770	0.03
204.7929840	0.06
206.6313019	0.05
207.4155121	0.01
208.9603882	0.11
210.9340057	0.09
215.0561523	0.10
217.1951904	0.40
219.2952118	0.09
225.2117004	0.09
233.2913361	0.16
235.0672455	0.03
239.2196655	0.12
241.1210785	0.06
243.1868896	3.35
245.3171692	0.02
247.2762299	0.10
249.9686737	0.07
250.7752075	0.04
253.3350372	0.06
257.2402954	0.03
259.4148254	0.22
261.0604858	3.06
261.7015381	0.07
263.2863770	0.10
272.9496765	0.05
275.1889343	0.24
277.3838501	0.35
278.5750122	0.03
279.2642212	0.15
286.2688599	0.04
287.0902100	0.13
291.3081055	0.12
299.2483215	0.39
305.3659058	0.22
313.1306152	0.03
317.2685547	5.53
320.3454895	0.02
331.8366699	0.02
335.2388306	100.00
337.2783203	0.02
350.1669922	0.02
353.3386230	0.43
359.0888672	0.02
366.3988647	0.12
367.0026855	0.07
368.1864624	0.02
382.3984985	0.03
383.6177368	0.01
387.3630981	0.03
393.4663086	0.05
396.9456177	0.04
415.3670654	0.59
421.3839722	0.05
423.2439575	0.69
425.2111816	0.02
429.0405273	0.04
430.5040283	0.07
433.0682983	0.52
435.2502441	0.09
441.3548584	0.02
451.2550659	0.01
453.0795288	0.05
455.4411011	0.04
456.2539062	0.04
456.9497070	0.11
465.2968750	0.05
466.0955200	0.03
466.7836914	0.19
476.3268433	0.11
477.0805664	0.04
478.4923096	0.05
479.5812988	0.03
485.2044067	0.05
491.3083496	0.14
497.2378540	0.11
503.3272705	0.39
510.6077271	0.06
516.2943726	0.10
521.4738159	0.45
524.2357788	0.02
531.6090698	0.12
535.9108887	0.05
541.4371948	0.04
559.2966919	6.88
560.5646362	0.02
565.5195923	0.02
577.1290894	21.90
577.9293823	0.04
579.2670288	0.06
585.4112549	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.2894
Annotation	Anandamide (18:2, n-6)
Peak:m/z	Relative Intensity
92.9656830	0.35
94.9948273	2.76
99.0049515	1.58
99.8661728	0.41
104.0337143	0.53
104.9419708	0.14
106.8388214	1.16
108.9117584	3.64
111.1358337	0.74
119.0900116	2.52
121.0099030	1.53
122.9846802	3.06
124.0459900	1.54
126.7765579	0.31
127.9351959	1.05
130.0960693	1.70
133.0299072	1.46
135.1712036	1.30
137.0219574	1.85
138.9302521	2.24
140.9186401	0.52
142.0223999	1.09
144.0016785	3.43
147.1157379	1.49
148.9104919	3.41
151.0658417	2.32
154.0440369	0.29
155.1200867	1.19
158.0333557	3.57
159.0370178	0.68
161.1229248	5.53
163.0866089	4.05
164.9517365	2.44
167.2244110	0.49
169.0019836	0.45
170.2244415	1.10
172.0651245	3.51
175.0772705	6.94
177.2068176	1.43
178.9631500	3.28
182.1444702	0.15
184.0039673	0.59
185.9970551	3.36
189.0504456	1.87
191.1528931	0.72
193.2612000	0.50
195.2229767	0.28
196.1125183	0.94
198.1954651	1.03
200.0761108	5.59
201.1026764	0.51
203.2159119	0.20
205.0935059	1.46
207.0527649	0.28
211.6086426	1.90
212.3110657	2.12
214.1834106	2.37
215.2338257	0.29
217.2496643	0.82
218.7240601	0.56
219.5081177	1.00
221.2154846	1.94
226.1455383	4.48
227.1995544	0.21
228.1535034	5.63
240.3620605	8.76
242.1678162	4.69
245.2403259	43.65
247.1108398	0.45
251.2340393	0.99
254.1524658	4.88
263.1635132	24.45
264.7977905	0.28
266.2640381	0.75
268.2032166	64.28
271.3665161	0.93
280.2832031	0.36
282.2155457	2.68
282.9075928	1.36
306.2976685	90.66
307.2626038	100.00
325.4644775	1.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.5017
Annotation	PI(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
240.9972687	25.13
242.0075378	5.10
242.8900299	0.79
250.8786011	0.28
255.2163696	41.91
256.2485352	25.49
257.2601318	4.43
259.0744019	1.78
260.1664734	0.58
276.2166748	0.21
277.1896973	16.04
278.3439941	10.69
279.2312012	0.48
297.0880127	13.13
297.9892578	4.97
299.0301514	0.66
315.0936890	1.26
316.1374512	0.35
391.2111206	46.05
392.2114258	41.91
393.1884766	4.05
409.2999878	5.70
410.2349243	0.73
411.3588257	0.09
413.1570435	8.85
414.1933594	8.66
415.3198242	2.73
426.6007690	0.43
431.2410889	0.10
432.3983154	0.20
462.5419312	0.28
480.4621582	0.15
481.5330200	0.28
498.5658569	0.29
503.1560669	0.41
553.3146362	58.27
554.3153076	100.00
555.2493286	18.26
555.8704834	0.47
571.2482910	18.59
572.3527832	26.91
573.2489624	4.65
575.2312012	10.76
576.2763062	21.46
577.3639526	4.86
593.4302368	1.69
594.3671875	1.10
595.3135986	0.96
629.1630859	0.21
670.5653687	0.39
671.7025146	0.56
672.3346558	0.69
745.4412231	0.38
814.7533569	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
237.1631165	0.18
255.2646484	33.56
256.632019	0.82
279.2337036	100.00
291.286377	1.13
391.1282349	4.14
395.2366943	0.36
401.3820801	1.27
422.0582275	0.63
434.3552246	1.76
443.4381104	0.93
448.6615601	0.85
452.4506836	16.33
454.2546387	0.77
458.6363525	1.85
476.3891602	3.02
492.227356	0.47
540.5527954	0.60
547.232605	0.24
554.4891968	1.75
556.2108765	0.48
568.3797607	0.61
578.1715088	0.69
583.5374756	0.35
593.2232056	1.19
594.3535767	1.90
605.5309448	0.29
612.0200195	0.36
624.0067139	0.47
627.2546997	0.90
629.2225342	0.51
635.723877	1.12
638.7520142	0.66
654.9795532	0.18
655.6798706	0.73
667.0716553	0.52
667.9855347	1.12
670.5687256	3.31
671.1693115	0.94
672.4989624	0.22
678.3284912	1.60
679.243042	1.43
691.2634888	1.14
695.9835205	3.53
697.2956543	14.60
704.8867188	5.23
706.1281128	0.72
714.4767456	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0929
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
139.1983643	0.17
151.1305695	0.03
152.9065247	0.07
161.2041321	0.07
165.2987671	0.08
167.0992737	0.16
176.9253845	0.06
179.0949097	0.03
183.1063843	1.33
195.9468689	0.03
197.1893311	0.06
205.1253662	0.08
212.0097809	0.06
222.5899353	0.04
230.9575958	0.10
241.9271545	0.08
248.888916	0.07
263.089386	2.03
267.2870178	0.14
269.2773132	0.08
270.0931091	0.15
281.1137695	0.65
283.149353	0.04
285.0457153	100.00
286.1276855	0.81
294.9250183	0.20
298.4020996	0.09
299.1643066	0.12
308.4150696	0.02
309.3831787	0.05
310.808136	0.02
311.9851074	0.09
313.1851501	0.14
321.2236938	0.11
324.9813843	0.06
327.0381775	64.54
328.1377258	0.45
329.2244873	0.04
339.1598511	0.40
343.5436096	0.03
344.3862305	0.30
345.4752808	0.10
351.9969788	0.12
353.3267212	0.09
355.0986938	0.14
357.129425	13.19
358.0477295	0.08
359.3985901	0.13
362.236084	0.23
363.0250854	0.02
366.2888489	0.55
367.3379822	0.17
369.1819763	1.74
371.3899841	0.22
381.1589661	0.04
383.313446	0.08
384.960144	0.07
387.0065613	0.92
393.0661011	0.85
397.2666626	0.05
398.9176941	0.17
401.5553894	0.14
402.4385376	0.58
403.2008057	0.46
410.4350281	0.08
411.2860413	0.60
412.22995	0.05
415.1233826	0.22
417.2737122	0.38
419.1832581	0.37
425.0498962	0.02
425.697113	0.24
427.1430664	0.02
429.1609802	2.44
429.7904968	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.2347
Annotation	Lantanose A
Peak:m/z	Relative Intensity
381.3544312	0.06
543.1877441	0.14
687.1795044	1.10
688.2977295	0.37
705.2272339	100.00
706.1952515	29.54
707.3544922	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1349
Annotation	2'-(E)-Feruloyl-3-(arabinosylxylose)
Peak:m/z	Relative Intensity
132.0774841	0.17
132.8762360	1.83
141.1835022	0.22
143.0458984	0.64
145.0918274	1.03
146.0783539	0.27
147.0742493	0.52
154.9723053	0.35
160.9931641	4.40
163.0118713	100.00
163.8838043	1.33
171.0167999	0.31
173.2656860	0.11
175.9620667	0.44
178.8708191	0.14
186.0036163	0.11
186.9896240	1.69
191.0614929	1.75
199.1759949	0.21
203.1451569	0.21
204.9731903	14.55
206.9570923	0.35
213.9884338	0.16
215.0825195	0.40
217.1068115	0.28
219.2817535	0.39
222.3220673	0.11
227.3656311	0.11
229.0285339	0.11
229.7848969	0.06
231.1777496	0.05
235.0787659	1.70
237.2911072	0.33
246.9590454	0.28
249.0878601	1.42
250.9732361	0.13
259.3387146	0.47
271.1351318	0.06
274.9282837	0.06
276.0932922	0.53
277.0238953	0.41
279.3096313	0.26
280.9996338	2.78
291.5219116	0.17
293.1281128	1.98
294.1049194	0.24
295.0370789	1.13
300.0536499	0.32
305.2473755	0.48
307.0833130	0.51
308.2564392	0.14
308.9981079	0.05
315.2366638	0.21
325.1010742	12.12
326.1320190	0.65
336.4121094	0.12
337.1472778	2.14
339.2222900	0.16
343.9852600	0.30
347.3133545	0.10
366.1667786	0.24
369.2060547	0.92
373.1576538	0.27
376.1593018	0.10
384.7407532	0.15
389.2318420	0.80
395.0600891	0.09
399.2500916	0.07
410.2526855	1.36
411.2241211	13.34
412.0618591	0.17
413.1387634	4.69
413.9966431	0.32
415.2602844	0.12
418.0299683	0.11
420.2878418	0.21
422.4031372	0.37
430.1933899	0.20
437.8776245	0.25
439.0730286	2.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	582.18
Annotation	Unknow
Peak:m/z	Relative Intensity
256.8161011	0.12
274.3623962	0.07
283.1409302	0.81
284.9569702	0.08
293.9474487	0.31
296.2072754	0.24
298.0549927	0.06
311.0989990	0.31
313.1481934	2.13
314.1505737	2.40
315.1649780	1.43
316.2520752	1.40
326.1398926	0.32
334.4332886	1.79
337.2690430	0.63
338.0455933	2.15
339.3250122	0.66
340.2936401	0.21
356.1015625	0.87
367.2208862	0.25
368.0058594	0.72
369.1504517	0.86
370.2432251	2.03
376.5242920	0.25
378.2054443	0.52
380.0457153	0.56
381.1409302	0.22
384.1402588	0.12
386.8881226	0.19
387.8737793	0.36
397.7167358	1.89
398.4011230	0.42
399.0723267	0.38
400.1685181	1.57
400.9910889	0.36
415.0612183	5.74
416.0393066	8.89
417.0559692	11.41
418.1857300	8.22
419.2059937	3.56
420.4036255	0.69
427.3519287	0.08
430.0718994	0.40
433.1448364	23.46
434.0875244	44.54
435.1092529	100.00
436.1243896	62.52
436.7573853	0.15
437.5562134	0.45
439.0014648	0.69
441.1435547	0.38
445.0006714	0.46
446.2006226	0.53
447.0764160	0.09
450.0951538	0.45
452.1312256	0.22
460.0571899	0.40
465.4883423	0.19
479.2045288	0.35
487.4431763	0.26
494.2386475	0.46
498.0725708	0.17
505.7052002	0.38
525.4252930	0.36
535.9573975	0.42
545.1368408	0.57
549.7652588	1.81
550.5851440	0.48
559.6931152	0.20
562.1007690	0.22
563.1823730	5.00
564.1472168	4.53
565.1915894	0.22
573.3267212	1.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1068
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
164.0874329	0.01
242.7378845	0.03
255.2330627	0.02
259.3483276	0.01
287.0660400	0.45
299.0641479	1.63
311.0881042	1.88
323.1930542	0.27
327.0281372	0.13
329.0891418	14.98
329.9378662	0.07
341.2493286	0.03
347.1345825	0.01
347.7692261	0.06
353.0790100	7.30
353.7938232	0.03
359.2010193	1.20
360.5026855	0.04
364.2055664	0.04
365.1317749	0.19
367.1578064	0.23
371.3934021	0.05
377.0698853	0.21
383.0757141	19.31
385.0786438	0.05
388.8286743	0.05
395.1369324	4.12
413.1846008	24.38
414.2196655	0.03
431.1421814	100.00
432.2078552	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1071
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
127.1566162	0.02
153.0827332	0.03
178.9214325	0.03
180.8970337	0.16
184.2274017	0.10
186.8180237	0.08
188.267334	0.04
204.9335022	0.07
206.8090515	0.05
219.0716858	0.14
225.0431519	0.52
230.23526	0.05
237.2852783	0.03
256.29599	0.05
257.0361023	0.06
259.1118774	0.08
267.2189026	0.06
275.3888855	0.11
277.0213318	0.07
280.9677124	0.03
287.0632935	100.00
287.6668701	0.06
291.0106812	0.03
293.0335693	0.10
296.8502197	0.12
299.083252	1.23
301.1370544	0.28
302.1171265	0.34
302.9628906	0.02
305.1183472	0.39
307.3133545	0.05
309.272644	0.11
311.0753784	2.41
315.0100708	0.02
316.4196472	0.07
317.8257751	0.10
323.0569763	0.48
327.1941833	0.09
329.1531067	8.36
332.2662354	0.03
339.2776489	0.06
341.0190735	0.13
350.2214355	0.13
350.9823608	0.04
353.175354	3.67
355.1856384	0.14
356.4701843	0.04
359.2582397	0.24
362.2544556	0.11
365.0069885	0.34
367.3034668	0.58
369.0110779	0.03
371.2237549	0.04
374.3134766	0.03
377.2012939	0.03
378.8143311	0.06
381.4217834	0.03
383.1475525	8.25
384.2799377	0.06
385.4269409	0.15
387.5364685	0.05
388.6879578	0.05
390.32547	0.12
395.1313171	2.88
395.7956848	0.20
398.4766235	0.08
399.2402039	0.21
400.610199	0.10
401.3908997	0.21
402.4062195	0.05
403.1939392	0.07
405.2687378	0.18
408.0305481	0.06
413.1260071	8.87
414.2273254	0.07
415.9925232	0.07
417.1646729	0.22
421.349884	0.09
424.2021179	0.14
426.0041199	0.03
431.1951294	39.69
432.1624756	0.30
439.5577698	0.39
440.3615723	0.24
450.0752258	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.09
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
73.7490158	0.07
82.8535767	0.04
84.9019318	0.05
86.2094650	0.10
87.9288788	3.77
88.8065796	0.05
90.8608398	0.17
92.9211731	0.02
95.1743469	0.19
101.1404724	0.08
103.8346710	0.45
105.1495056	0.14
106.1081848	0.04
107.0677490	0.07
115.3790588	0.60
115.9874268	4.34
117.0451202	0.11
119.1082764	0.04
121.1769714	0.07
123.0460815	0.08
128.8114014	0.03
129.9316254	0.24
130.8962402	0.10
133.8998566	100.00
135.0589905	0.23
136.0224457	0.22
137.1085358	0.21
138.7206116	0.05
144.9674835	0.08
145.9624023	0.11
150.9810791	0.22
154.1226654	0.05
156.1276093	0.11
157.9437866	0.03
165.1372833	0.17
172.6930847	0.03
175.2738800	0.19
176.9649506	0.15
180.0619354	0.07
182.4743500	0.05
189.0726471	0.40
192.0264893	0.11
195.2007599	0.14
195.8207092	0.16
196.9319611	0.04
205.8876038	2.65
207.0320587	0.36
207.9540863	0.05
209.0426331	0.07
211.0921936	0.74
212.0799408	0.10
213.0642853	0.03
215.2466278	0.25
216.2245483	0.29
216.8845673	0.10
220.2252197	0.41
223.1395721	0.07
224.1787720	0.98
225.3412476	0.22
228.8368378	0.20
233.9611206	96.96
235.1986694	0.05
240.9535370	0.08
242.9682465	0.68
243.7572021	0.04
250.3096771	0.20
251.7102661	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1507
Annotation	Kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
167.0967102	0.09
171.0966339	0.14
173.0643158	0.04
174.9251251	0.05
175.8905182	0.17
179.0986023	0.05
180.2834778	0.12
182.9342346	0.35
183.9810181	0.24
185.1255798	0.22
186.4376831	0.31
187.1136475	0.28
188.046814	0.03
189.1743774	0.21
190.2089844	0.05
191.0418091	0.09
192.0213623	0.06
195.102829	0.23
196.0370636	1.20
197.0989075	0.48
198.1994019	0.79
199.1151276	0.77
200.0234375	0.26
201.36026	0.11
202.178894	0.06
204.7320862	0.10
207.0130463	0.03
208.411377	0.27
209.1624756	0.06
210.2879486	0.04
211.0908508	1.26
212.1156769	0.58
213.0640869	0.64
214.1513672	0.78
215.1252136	0.15
218.026825	0.14
219.2125244	0.04
220.6242065	0.04
223.201889	0.47
224.1839905	0.25
226.0475922	0.07
227.1238403	0.36
228.2051697	0.73
229.0975952	2.62
230.0687866	1.73
232.1697388	0.09
235.0528107	0.04
238.9428253	0.88
240.0400696	0.75
241.1132202	1.24
242.1064758	0.91
242.9817505	0.09
243.994873	0.35
253.0595398	0.06
255.0844116	1.59
256.2387695	2.08
257.1777954	4.24
258.1714478	2.91
259.0753784	0.68
264.2099609	0.17
265.135498	0.03
267.0148926	1.09
267.9560547	0.94
268.93927	0.65
270.1005859	0.34
271.0611877	0.08
272.2115784	0.04
279.2871399	0.22
281.0276184	0.05
282.1720581	0.24
283.3280029	1.01
285.0412598	100.00
286.0531616	92.94
287.0975952	16.83
288.2025452	0.15
298.0618286	0.19
299.0700073	0.25
300.1953735	0.05
301.1553955	0.51
305.1938171	0.10
306.8585815	0.09
311.1660156	0.65
312.1864624	1.28
313.233551	0.07
315.2155151	0.07
325.9140625	0.09
327.0073853	2.09
328.0570068	3.59
329.1951904	1.07
340.2996216	0.22
341.1212769	0.03
342.2133789	0.20
345.2034302	0.09
353.1499023	0.17
354.0872803	0.16
357.1515503	0.59
358.1986694	1.08
359.1846313	0.52
365.0822754	0.17
369.2462769	0.04
369.9108276	0.08
379.1456909	0.07
385.2112427	0.35
386.3846436	0.09
394.4085083	0.32
396.1216431	0.21
400.0252075	0.04
412.164856	0.38
413.100647	0.04
414.0731201	0.44
415.2141113	0.18
416.8892822	0.10
418.4594727	0.04
429.2982788	0.04
430.2175903	0.06
431.1744995	0.22
432.0168457	0.02
433.102478	0.37
440.9987793	0.15
445.5332031	0.20
447.3500366	0.02
448.1538696	0.25
449.3187256	1.33
462.2830811	0.06
463.2719116	0.04
469.0625	0.03
474.2766113	0.10
475.3006592	0.19
478.9399414	0.05
507.4202881	0.13
522.7355347	0.04
527.2164917	0.10
531.6919556	0.10
532.3001709	0.04
533.1205444	0.07
533.9373169	0.15
535.3312988	0.05
546.6008301	0.13
548.2579956	0.16
550.2815552	0.11
551.34198	0.15
552.1275024	0.15
558.3065796	0.31
559.4310913	0.22
563.2151489	0.22
566.2860718	0.35
576.3863525	0.87
577.2539062	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
269.2344971	0.04
283.0877686	0.16
293.3119507	0.19
311.0446167	100.00
312.2259521	0.25
323.1375122	0.98
337.0767212	0.07
339.1833496	0.09
341.1435547	26.06
342.1347046	0.15
353.1256104	1.23
355.0114136	0.42
365.4207458	0.14
367.3021240	0.23
371.0138550	0.65
377.1636658	0.50
383.0769958	1.10
383.6793213	0.02
385.4186096	0.20
395.1421509	0.56
413.1489563	5.97
414.4529114	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.214
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.0752411	0.79
221.0230408	5.97
232.6710205	0.28
234.9311829	0.38
245.2463684	0.47
248.8590393	0.13
250.1122742	1.21
262.9305725	0.46
278.467926	0.11
280.881958	1.27
282.4176941	0.44
302.8374329	2.25
303.9783936	0.32
305.0201416	0.94
311.1314697	0.42
320.9454346	2.44
321.8809204	2.93
323.0552368	5.66
329.1300049	0.36
331.9625244	0.09
341.0635986	30.15
342.9916382	0.26
344.883606	0.11
352.0360107	0.23
356.9262695	0.22
365.1522217	0.27
383.1086426	100.00
398.1669312	0.20
407.2908936	0.14
409.0570679	0.39
412.7911377	3.42
423.9519043	0.23
425.1425171	0.67
426.0184326	0.43
430.1641846	0.41
436.37146	0.73
442.9359741	18.19
454.9935303	0.82
457.3855591	0.35
460.2663574	0.16
467.0390015	0.70
471.9302368	0.11
472.8814697	2.52
474.0844116	1.26
475.0028687	0.11
485.1073608	30.68
485.7578735	0.07
488.6959839	0.32
490.8934326	0.53
494.9765625	0.13
503.1181641	4.39
505.5497437	0.23
514.6418457	0.43
517.2857666	1.07
519.8903809	0.16
522.774292	0.34
525.1013794	0.92
526.807312	0.17
527.7229614	0.82
529.6638794	0.28
535.90448	0.37
543.4707642	0.32
545.1638794	2.01
547.9750366	0.10
551.6273804	0.10
560.3954468	0.14
561.0360718	0.41
565.9684448	0.08
566.97052	3.30
570.4225464	0.50
576.8782959	0.79
578.0537109	0.25
591.5548706	0.32
593.2224121	1.26
598.7780151	0.51
605.0748901	0.47
606.2460938	1.65
611.3873901	0.16
619.7796631	0.14
621.0088501	3.21
622.7747192	0.32
627.6032104	0.17
635.0338745	0.18
646.8789062	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	439.3569
Annotation	Dymacrin D
Peak:m/z	Relative Intensity
125.0909042	0.26
126.9612579	0.12
130.8408508	0.62
132.9121552	2.09
134.9880524	2.89
137.1197205	1.25
145.0171661	0.26
147.0456543	3.76
148.8968201	2.67
150.8071594	0.25
159.2135925	0.67
161.0316315	2.28
163.1629944	2.28
165.0990906	0.34
167.2372742	0.33
170.0953674	0.23
172.6981506	0.15
175.1995239	3.78
177.0711365	3.15
179.1208496	0.24
184.3004150	0.19
185.0722961	0.06
186.3192139	0.17
187.1218262	0.95
189.0667419	6.52
191.0914612	100.00
193.0692139	1.37
194.9259491	0.52
196.9908447	0.20
199.2945404	0.43
201.1538239	7.64
203.1700897	30.68
205.0904236	8.43
209.0306091	0.38
213.0935669	0.80
215.1920319	1.11
217.1508942	17.99
219.3583984	0.86
221.1351318	1.10
222.9846191	1.04
226.9739838	0.61
229.1593781	2.77
231.0968475	6.98
233.1877899	0.39
235.0982666	1.66
239.4481812	1.51
241.1980286	0.94
242.9953613	1.22
245.2116089	6.45
247.1083374	7.95
249.1642761	12.28
250.9219055	0.16
253.0436096	0.69
255.2339783	0.47
257.1552734	0.79
259.0787659	1.10
261.0937805	4.66
261.7089844	0.28
263.0034180	0.38
265.2038879	0.11
267.3340759	0.10
269.3280640	1.16
270.3544312	0.26
271.3359680	0.31
273.0248718	2.46
275.1779480	2.99
277.3313599	0.73
278.0205688	0.08
281.3218994	0.84
283.2929688	1.54
284.2098694	0.13
287.1689453	1.61
289.3049011	0.93
291.4592590	0.09
295.2199402	0.30
297.4142151	0.51
298.3260193	0.16
301.2196045	1.64
303.1250610	0.54
307.3093262	0.18
309.3882446	0.43
315.1777344	3.44
323.1500244	0.33
329.3563843	2.42
335.3838196	0.12
337.2402954	0.29
340.9919434	0.08
343.2375488	0.52
350.9357910	1.16
355.2275696	1.79
357.7136230	0.49
369.3775024	2.27
378.6461487	0.28
379.3121033	0.54
380.4003296	0.24
381.2895508	0.48
383.1435242	0.89
385.2196655	0.20
386.0211182	0.18
388.8368835	0.31
389.5978699	0.39
390.5875854	0.62
393.3537598	25.02
395.3592834	2.60
397.4212036	0.38
399.4636536	0.33
403.6238708	0.19
407.4318237	0.52
408.5288086	0.10
411.5693665	0.18
415.7924194	0.12
419.1188049	0.27
421.3182373	10.70
422.0099182	0.08
424.2676697	0.61
438.3259888	0.09
439.4907532	0.42
440.3691406	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.04
Annotation	Unknow
Peak:m/z	Relative Intensity
190.0084229	0.17
197.0480499	0.18
204.8868256	0.07
206.7880859	0.03
208.8984680	0.04
225.3133240	0.17
294.5536499	0.05
302.3771362	0.03
340.1849976	0.06
343.1925049	0.08
355.3613281	0.05
359.2288208	0.09
362.2605591	0.08
369.2366333	0.10
375.3228760	0.14
383.9104614	1.41
386.9739380	0.20
387.9210205	0.18
392.2224121	0.06
395.9788208	0.06
401.9270630	0.29
409.2053833	0.11
411.5591431	0.03
414.2432861	0.28
416.4252930	0.02
420.2548218	0.08
426.2192993	1.28
429.1210327	0.28
430.3388672	0.04
433.1254883	0.13
434.1319580	0.64
438.0360718	0.11
443.9981079	9.65
446.1137695	0.18
453.1736450	0.07
456.0766602	0.21
459.3812256	0.02
462.2257080	0.07
467.8604736	0.38
473.7380981	0.76
480.6508789	0.05
481.8106689	0.04
483.0864868	0.19
485.9762573	2.04
489.0223999	0.46
496.1456299	0.15
501.9091797	0.05
503.9124756	100.00
504.5494995	0.13
505.1958008	0.05
505.8854370	0.14
507.9503784	0.12
509.1601562	0.14
513.3047485	0.07
514.1912842	0.24
515.0559692	0.04
517.2260742	0.10
518.8114624	0.18
519.8154907	0.05
521.5327148	1.10
523.1945190	0.08
529.4483032	0.36
531.1442871	2.33
532.1989136	1.68
533.3389893	0.02
535.5685425	0.23
541.5627441	0.10
550.4862671	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
164.1317139	0.04
179.1988068	0.03
208.9576111	0.01
217.2610779	0.04
224.9926147	0.11
283.1839905	0.18
311.061676	100.00
311.8757019	0.10
323.1390991	0.06
324.8586426	0.04
341.1797485	8.72
342.0891113	0.09
353.1142273	0.51
354.9302673	0.04
365.1321106	0.08
367.1811218	0.13
370.9988098	0.14
377.27005	0.11
383.0114441	0.22
395.1784058	0.14
413.2298889	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	956.3091
Annotation	Unknow
Peak:m/z	Relative Intensity
270.9821777	0.06
341.0396118	0.03
414.1686707	0.11
494.0939331	0.08
502.7849731	0.43
512.0375366	0.02
545.1044922	0.19
549.1111450	0.07
569.3228760	0.07
569.9555664	0.07
604.9373169	0.22
614.1096802	0.02
629.1259155	0.03
647.1076050	0.02
665.3473511	0.21
679.1929932	0.02
692.1269531	0.02
718.4509888	0.08
726.0013428	0.03
732.4127808	0.02
773.7997437	0.05
782.1486206	0.13
819.2808228	0.01
823.3798218	0.07
827.2265625	100.00
827.9181519	0.04
842.1076050	0.02
851.9660034	0.02
873.1583862	0.11
880.2297363	0.06
910.3344116	0.03
912.4640503	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1506
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
173.0195160	0.01
182.1373444	0.03
190.0228577	0.06
191.0785980	0.16
193.2174683	0.02
195.9392700	0.06
202.9327545	0.07
216.9570618	0.02
225.0390167	0.06
227.1320648	0.02
233.0852966	0.18
239.0955505	0.19
241.1674042	0.08
243.0989380	0.08
251.3791351	0.03
255.2968597	0.01
257.0021362	0.03
261.0027161	0.01
264.8193970	0.02
267.3420715	0.07
268.1162415	0.06
269.1061401	0.09
279.0959473	0.05
281.4108887	0.04
283.0494995	11.58
283.9837952	0.02
284.8306580	0.03
293.0384521	0.34
297.0320435	0.03
297.8862915	0.04
299.2332764	0.02
301.3763428	0.01
305.2587891	0.03
307.1390381	0.02
309.2232666	0.44
311.0202026	100.00
312.0901489	0.05
321.0042725	0.02
321.9304199	0.02
323.1838379	0.61
325.1929321	0.40
327.0161743	0.12
333.0150757	0.03
335.0265503	0.64
339.1618652	0.02
341.2005005	0.01
343.3436890	0.02
347.5089111	0.02
349.1491089	0.36
353.0895386	8.93
354.1071777	0.03
355.1265869	0.01
356.0799561	0.03
357.4025269	0.03
365.1235962	0.19
367.1732788	0.16
369.0717773	0.12
377.1560669	1.72
378.1690063	0.01
387.1338501	0.02
395.1069336	2.90
396.2169189	0.05
408.3466187	0.02
409.0118408	0.03
413.0910645	8.77
413.7541504	0.01
415.0557251	0.01
425.2932129	0.03
431.1263428	1.05
436.2398071	0.02
440.0133667	0.01
444.8300781	0.07
447.1348267	0.01
451.1945190	0.02
454.7850952	0.07
465.3209229	0.01
466.1041870	0.02
473.0186157	0.05
503.2460327	0.60
515.1658936	0.90
532.4203491	0.04
545.7145996	0.04
546.9072266	0.23
547.7248535	0.01
549.5183716	0.08
556.5587769	0.09
557.4179077	0.02
561.0271606	0.11
564.8220825	0.02
575.0040894	0.86
575.7070312	0.05
583.8200073	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1069
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
150.9900208	0.08
242.7648010	0.03
287.1596680	0.58
299.0207520	0.97
299.6802368	0.02
311.1603394	0.44
323.1137695	0.12
327.1244507	0.07
329.1659546	22.38
353.0898743	17.50
359.0651245	0.23
365.1810913	0.23
367.2627258	0.10
372.2699890	0.09
377.1643982	0.41
383.0623474	40.17
395.1557922	11.12
413.0504761	20.42
413.6858826	0.07
416.4853210	0.02
431.0820007	100.00
431.8410339	0.15
433.2942200	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.221
Annotation	(-)-SNF 4435C
Peak:m/z	Relative Intensity
136.1707458	0.34
158.9562225	0.10
169.9878235	0.05
180.9526062	0.13
193.0667725	1.10
195.2654877	0.19
209.1210022	0.47
211.1093597	0.27
211.9971771	0.32
214.9754944	0.29
223.0794373	0.07
229.9744568	0.12
244.0429230	0.09
263.0696106	0.07
264.9384460	0.07
280.5602112	0.09
285.5185852	0.23
289.0163879	0.32
298.0760498	0.34
301.2153931	0.05
315.0565186	0.64
316.2713623	0.20
319.1700745	0.14
320.7713013	0.11
322.1463013	13.76
323.1562500	0.19
324.0258789	0.57
327.8687744	0.36
329.2181091	0.09
329.9842224	0.25
331.2816772	0.41
336.2502747	0.69
338.1448059	0.21
342.9107666	0.33
346.1413574	0.15
348.6080322	0.21
349.2489624	0.32
356.1019592	0.19
358.3136292	0.05
361.9771118	0.10
363.2700806	0.06
371.2714844	0.72
373.1192932	0.18
382.2035217	0.39
383.1269531	0.09
387.7208252	0.12
388.7594910	0.35
391.3039856	0.08
393.9759521	0.06
397.5840149	0.45
400.1535645	0.09
402.2570496	0.28
404.5673828	0.22
406.1120300	0.44
407.2718201	0.35
417.9881287	0.54
422.6909485	0.25
424.0845642	0.84
424.8281555	0.14
430.1319580	0.37
431.7072754	0.19
433.1698303	0.24
436.7449951	0.30
442.1203918	2.67
447.2056580	0.11
448.5258789	0.10
450.1221008	0.11
455.5736084	0.70
459.9577332	100.00
461.2083130	1.16
462.1302795	0.35
468.6347046	0.37
477.3059998	0.21
479.0462036	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	887.2872
Annotation	Unknow
Peak:m/z	Relative Intensity
296.7882690	0.85
376.9832153	0.11
380.5551147	3.40
382.5902100	1.95
459.0385742	0.26
464.4379272	4.58
466.4118652	5.54
548.3615723	15.47
549.9260254	3.64
550.5386963	18.27
552.6922607	0.17
632.2576904	17.58
633.6392212	5.48
634.3558960	39.24
635.0332031	0.63
656.8063354	0.08
713.2341919	0.41
715.7439575	5.92
716.4258423	16.33
717.7468262	17.78
718.3777466	69.53
756.3973999	0.24
767.3014526	0.56
795.9577637	0.41
796.5592041	0.09
800.1295776	13.59
801.5647583	20.80
802.1739502	100.00
840.1546021	0.35
841.1565552	0.17
866.2305298	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	989.3197
Annotation	Lantanose B
Peak:m/z	Relative Intensity
383.2820435	0.09
503.0227356	1.22
545.1818237	0.66
605.1745605	0.51
665.0170898	0.46
707.3612061	1.71
731.3165283	0.16
790.9509277	0.09
809.2297363	0.16
827.3415527	100.00
883.0338135	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	918.127
Annotation	Unknow
Peak:m/z	Relative Intensity
282.7543945	0.11
307.2186890	0.09
325.1857300	0.02
333.2108154	0.09
338.9902344	0.05
339.9855347	0.03
342.0670471	0.27
343.2752686	0.06
354.4952087	0.04
356.0246582	0.05
357.9472656	0.06
368.5706177	0.04
369.9620972	0.06
382.1574707	0.06
383.1969910	0.07
395.0945435	0.08
396.0619202	1.57
404.8315430	0.04
410.0401611	0.13
411.0897217	0.22
412.2555542	0.12
421.9785767	0.05
424.0091553	0.08
426.1867676	0.23
438.0500488	0.31
441.8275146	0.04
449.8625488	0.05
451.1165771	0.13
455.9282837	0.16
458.2290649	0.16
462.2049561	0.11
468.1499634	0.29
469.1596069	0.47
484.9470215	0.62
486.0190430	0.24
486.9782104	0.36
497.8599854	0.08
502.1653442	0.03
504.2155762	0.08
507.3995361	0.11
510.2494507	0.10
522.2467651	0.07
528.2483521	0.21
538.0258179	0.05
540.0567017	1.20
546.0719604	0.50
551.9813843	0.06
557.9971313	0.80
558.8882446	0.04
570.2029419	0.16
574.8477783	0.04
591.7101440	0.18
594.1276855	0.55
597.5936890	0.03
600.1183472	0.17
607.2307129	0.11
608.0371094	0.09
618.3524780	0.11
619.9312744	0.05
621.0733032	0.20
622.4207153	0.05
623.0559692	0.04
631.0259399	0.10
632.2106323	0.46
633.8748169	0.02
636.0161743	3.11
637.0780640	0.18
644.0359497	0.71
647.1015015	0.18
648.0776367	0.72
649.0805054	1.13
649.9860229	0.45
656.2143555	0.37
658.0735474	0.16
659.1656494	0.04
660.0973511	1.08
662.2673340	0.29
664.3284912	0.21
665.1917114	0.34
666.2193604	3.30
672.0802002	0.59
674.0339966	0.81
675.9296265	0.03
677.4087524	1.72
678.2140503	2.27
679.2595825	1.73
680.2886353	0.07
684.1438599	0.25
685.3623657	0.17
686.1887817	0.14
688.1420288	0.03
690.0585938	2.27
692.0352173	0.03
694.7684937	0.11
696.3405762	0.17
702.0883179	3.55
703.2396851	0.09
704.3604126	0.07
706.3203735	0.20
708.0283813	7.69
708.9799194	0.08
710.0574341	0.09
713.1762085	0.07
714.0363159	0.69
716.0110474	0.56
718.0540161	0.06
719.9876709	1.61
720.5938721	0.02
721.4108276	0.13
724.7807007	0.08
726.2785645	0.85
730.1990967	0.14
730.9395752	0.06
732.2175903	1.96
733.0129395	0.16
733.7807007	0.13
735.0976562	0.12
736.4498291	0.10
738.0816650	11.89
739.1783447	0.27
743.0270996	0.04
743.9983521	1.18
744.8220825	0.16
749.4085083	0.30
750.0745239	0.98
751.1006470	1.76
752.1925659	1.14
754.0578003	0.12
755.0178223	0.15
756.0567627	11.12
757.4767456	0.10
762.1536865	1.26
763.9404297	0.17
767.2343140	0.19
768.1362915	2.35
769.0668335	3.69
770.1109619	0.24
774.2594604	0.46
774.9135132	0.09
776.0683594	0.43
778.0642700	0.18
778.8060913	0.60
780.1125488	11.11
780.7825317	0.31
786.2044678	0.30
791.9675903	2.15
792.8978271	0.08
793.9082031	0.11
796.4381714	0.97
798.0443726	100.00
799.0124512	0.40
802.4091187	0.20
804.2067871	3.34
808.1027222	0.21
809.3211060	2.04
810.1961060	16.66
811.2247925	0.12
812.2095947	0.17
814.2346802	0.14
816.0651245	1.40
816.9767456	0.07
818.5979004	0.03
820.6433716	0.15
822.0835571	8.78
823.1918335	0.31
826.1410522	0.42
828.0599976	24.36
829.1008911	0.24
832.9130249	0.08
834.1052246	4.22
836.3197632	0.18
838.2125854	0.07
839.4928589	0.32
840.1769409	1.29
840.9923706	0.06
846.1879272	1.65
852.0668335	3.73
852.7597046	0.03
858.0823975	0.43
859.0295410	0.23
863.3604736	0.53
864.1471558	5.20
882.0866089	32.66
883.1527710	0.53
887.8840942	0.10
900.0650024	89.14
901.1312866	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.124
Annotation	L-gamma-Glutamyl-beta-phenyl-beta-L-alanine
Peak:m/z	Relative Intensity
84.9811935	0.56
88.9971161	0.91
100.8838806	3.15
112.9053955	1.39
114.8886261	0.43
118.7687531	1.33
125.0509186	0.35
126.2149506	0.12
128.0043945	100.00
130.9251709	28.17
142.6010437	0.12
143.3165131	0.18
145.0376892	0.28
147.1617126	0.17
148.7567139	0.31
159.1745911	0.18
161.0484924	0.18
163.9766846	2.01
165.2597504	0.12
167.0310974	0.17
172.9234924	0.91
178.9686127	0.35
184.9623413	0.40
203.0442200	0.18
207.0498352	0.44
216.9348450	0.19
221.2925720	0.27
249.0573730	0.52
253.0281982	0.10
257.1245728	4.62
262.6578369	0.14
273.2350464	0.05
275.1260376	87.75
276.8912048	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	255.2329
Annotation	2-Hexyldecanoic acid
Peak:m/z	Relative Intensity
208.8817596	5.65
211.3254547	14.18
236.9799652	100.00
237.6208038	25.67
255.2264404	79.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.2278
Annotation	9S,10R-Epoxy-3Z,6Z-octadecadiene
Peak:m/z	Relative Intensity
94.8027802	0.81
96.7633743	0.34
107.1396332	0.07
108.9947815	1.41
110.1075516	0.11
113.1493378	0.67
124.9967499	0.67
127.0274734	7.19
134.9859314	0.35
137.0631256	0.90
139.0824280	3.22
141.0321350	100.00
151.1203308	0.07
153.0394897	1.64
155.0299683	59.87
156.1736755	0.13
166.9234161	0.46
168.9334412	0.12
180.8040924	0.30
183.1557007	0.58
191.0444336	0.10
193.1020813	5.92
195.0154114	0.22
202.9691162	0.14
219.2131653	0.19
224.2809753	0.18
225.1904907	0.12
231.2227173	3.05
233.2593689	0.69
239.0333252	0.09
247.2729492	1.81
249.2510376	69.58
250.1439819	0.46
251.4406433	0.05
259.1037598	1.46
265.2711182	0.19
267.4961853	0.06
275.5850830	0.51
277.2084961	9.21
278.1632080	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0928
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
140.0366821	0.03
175.3289185	0.03
285.1331482	0.33
286.1268311	0.04
297.2179565	0.11
323.1900635	0.05
325.2353210	0.08
327.0807495	100.00
327.7630005	0.74
328.5130005	0.01
337.3068237	0.09
339.1124268	2.10
341.1197205	0.25
353.2618408	0.48
357.0843811	83.61
358.1254883	0.16
359.3107910	0.03
367.2892761	0.06
369.2026367	1.86
371.0780029	2.15
381.3619080	0.03
383.1091003	0.15
387.1551208	3.64
393.1284485	0.47
399.0903015	0.71
400.9784241	0.06
411.1883240	2.46
416.9148254	0.19
429.1867065	24.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.69
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7663879	0.47
296.6435547	5.29
380.0852661	3.06
380.7263184	16.57
435.1438599	0.30
464.3733521	40.35
465.1541748	0.50
501.7523804	0.05
548.3901978	100.00
549.1023560	0.26
555.2056885	0.30
626.9818726	0.28
629.5757446	0.06
630.7084351	0.10
632.2711792	99.36
633.0865479	0.80
669.7938232	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2139
Annotation	Unknow
Peak:m/z	Relative Intensity
251.1357880	0.42
280.9300537	0.24
293.8489685	1.24
308.2765503	0.39
340.8947144	1.10
341.6094971	0.65
366.5634766	0.34
382.9358521	2.47
384.1987915	0.97
412.4190674	0.24
469.3980713	1.25
503.2705688	100.00
504.3408813	8.69
517.0078735	5.94
517.9805908	0.97
552.2507324	0.26
603.9307251	0.81
631.0755005	0.90
632.0684814	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	640.2104
Annotation	Unknow
Peak:m/z	Relative Intensity
181.8908844	0.20
193.0271606	0.05
210.7583008	0.22
216.9800110	0.22
241.0187378	0.62
243.2198792	0.40
244.9812927	0.09
247.0865021	0.09
252.9480896	0.38
257.2735596	0.12
258.8161011	0.36
270.3613892	1.16
270.9888916	5.19
276.5828247	0.36
280.1977234	0.34
286.0071106	0.25
288.3462524	2.80
289.0342102	7.35
297.9230347	1.59
298.6029663	0.38
301.7050781	0.08
303.3400574	0.42
304.9509277	0.38
306.3529053	3.05
306.9559937	6.32
324.1957397	14.33
324.8648071	100.00
325.5067139	0.25
338.6540527	0.25
339.8308716	0.69
340.9062500	1.29
342.7216187	99.82
343.4221802	0.39
345.1766968	0.11
395.0395508	0.18
415.1466675	0.20
416.1763916	0.40
421.2045898	0.52
432.6878052	0.48
438.7216187	0.22
449.6752319	0.34
450.9917603	1.48
460.1439209	1.01
466.1077881	0.12
469.1699829	0.16
475.0316772	1.20
477.8739624	18.88
486.7266235	4.97
487.5350342	0.54
493.1257935	0.17
502.0706177	0.06
502.9089355	0.20
504.1642456	0.85
504.9063110	4.30
517.8843994	0.23
529.1516113	0.49
542.0493774	0.17
550.1076050	0.07
551.1563721	0.33
578.2443848	0.08
604.1820679	0.15
622.1541138	0.57
623.4219971	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	825.4639
Annotation	Trojanoside A
Peak:m/z	Relative Intensity
241.1188202	0.11
283.1797485	0.11
311.5187073	0.06
382.2216187	0.13
397.1010132	0.27
415.0537109	0.05
471.1164551	0.14
482.5025635	0.06
487.4361572	0.15
524.4204712	0.07
535.3223877	0.08
536.5323486	0.11
553.2235718	0.48
555.5252075	0.23
561.1547241	0.08
571.2712402	0.08
603.2429810	0.19
617.4889526	100.00
627.4006958	0.18
648.4571533	0.25
651.2476196	0.07
659.3644409	0.29
663.2756348	0.20
666.6007080	0.25
677.3138428	0.05
720.2540894	0.08
737.7716675	0.36
738.5809937	0.11
740.3384399	0.24
745.4404907	0.12
748.6221313	0.28
760.2604980	0.12
763.1274414	0.07
765.2431030	0.43
775.4870605	0.05
779.0695190	21.25
779.7537231	0.11
781.6735840	0.06
790.0384521	0.21
791.6907349	0.14
792.5518799	0.17
806.5246582	2.21
807.3625488	3.72
808.2717896	0.41
815.5183716	0.02
824.8624878	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0834198	0.03
152.9686127	0.03
185.1577148	0.04
196.0016174	0.19
213.9663849	1.71
233.3189392	0.26
259.2042542	0.10
261.3676758	0.04
275.3947144	0.21
277.2037354	100.00
323.7400208	0.03
411.5068359	0.02
430.2441101	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.507
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
222.065155	0.42
223.1322784	0.32
243.15271	0.51
255.3163147	41.12
261.3774719	0.42
279.2365723	100.00
283.1212158	0.86
291.2097473	0.16
295.4144287	0.19
303.3546753	0.39
305.1976929	0.34
328.2577515	0.42
346.3894043	0.34
357.24646	0.14
361.3156128	0.18
391.3496094	0.11
434.2909546	0.88
444.2290039	0.34
446.2018433	0.62
452.3748779	18.06
458.2340698	1.40
466.5140381	0.17
474.7873535	0.28
476.227417	1.85
480.3840942	0.53
487.3627319	0.89
488.2259521	0.94
501.9164429	0.51
507.0562744	0.21
508.3894043	0.40
511.3609619	0.54
520.4912109	0.61
552.3803101	1.90
553.3042603	0.34
554.1199951	0.49
567.0386353	0.14
567.7377319	0.09
572.1764526	0.26
592.3230591	0.49
594.4749146	0.16
600.5266113	0.23
617.8615112	0.16
625.3717651	0.17
632.7925415	0.59
637.4978638	0.53
643.4761963	0.33
654.7947388	0.39
655.6519165	0.16
662.8289185	0.62
668.6849976	0.31
672.1186523	0.40
683.1029663	0.75
693.7901001	0.17
696.3001709	2.65
697.4428101	4.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2919
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
141.9130554	0.03
150.9318390	0.02
161.0432739	0.06
167.0515747	0.01
172.9449463	0.05
198.1088867	0.05
216.1221313	0.08
263.1779785	0.20
306.2891235	0.23
319.4747925	0.02
324.5383911	0.01
337.2239380	100.00
337.8471069	0.36
361.0742188	0.05
380.4633789	0.04
416.9090881	0.18
435.2297363	0.06
460.1735535	4.29
460.9492798	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0872
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
94.9355774	0.24
96.9486847	0.28
99.0613403	0.13
108.0166550	0.04
118.9220123	0.45
121.0799408	0.23
121.9139557	0.09
122.9531708	3.55
125.0169754	5.19
133.2242584	0.35
135.0382233	0.16
137.0247345	1.23
139.0586090	2.48
141.1196899	0.11
146.9133759	0.19
149.1398926	0.13
151.1216278	0.50
152.1196594	0.06
164.9724121	4.47
167.0469971	100.00
168.1164093	0.21
175.0773010	0.16
177.0727844	0.11
181.1003113	1.47
185.9864502	0.08
187.0455933	0.12
188.5608215	0.12
189.1813354	0.17
191.0683594	0.59
193.2680206	0.05
200.8988037	0.13
203.2506714	0.06
205.1396179	0.09
207.1847839	0.21
209.0460815	83.39
210.0270386	0.28
221.0345154	3.59
227.2822266	0.23
229.1324158	1.25
231.1345520	1.46
237.0340576	0.16
243.0549927	0.53
245.0985107	1.71
247.2225342	0.13
253.1958313	0.41
254.9338074	0.08
257.2280884	0.25
269.1536560	0.24
271.1108398	3.05
271.9562988	0.11
272.9072876	0.21
278.9381104	0.47
284.2846985	0.05
285.4844971	0.36
286.3912964	0.65
287.1653442	1.05
294.9270020	0.13
296.1757507	0.06
297.1497498	2.40
298.3370361	0.05
299.1645508	0.70
300.1666870	0.79
300.9454956	0.12
315.4660034	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.0719
Annotation	Aesculin
Peak:m/z	Relative Intensity
108.8609772	0.01
133.0719147	0.02
165.9199524	0.01
177.0062866	100.00
178.9098663	0.02
202.9030304	0.01
205.0361328	0.06
208.9493713	0.02
213.1396790	0.01
219.2127380	0.05
230.9785156	0.05
247.1823730	0.04
255.3197632	0.01
276.2145996	0.02
293.0014038	0.13
295.1239624	0.03
299.1441650	0.02
301.8971863	0.01
321.1467285	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.2961
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
204.0436859	0.36
218.2284851	0.06
236.0782776	0.02
246.0892181	0.33
262.2029419	0.04
271.0985107	0.09
272.8565979	0.10
276.2170715	0.18
278.0517883	0.02
281.1395874	0.05
283.9969788	0.09
287.1700745	0.28
294.3494263	0.06
295.2603760	0.09
299.1802368	1.02
301.0845032	0.02
305.0393677	0.09
311.0989380	0.07
313.0142212	0.09
315.1372681	1.22
323.1800537	0.63
325.1218872	0.32
329.0126648	0.05
337.2094116	0.64
339.3449707	0.17
341.2522583	0.21
343.1422729	0.27
345.2296143	0.06
355.4150391	0.02
357.1975098	0.37
359.2460327	0.41
363.3103027	0.03
365.3731079	0.03
369.3616333	0.31
371.0656128	1.02
372.5570679	0.04
373.2705078	0.41
375.2434692	0.08
383.0508423	0.78
387.2969971	0.06
389.3876953	0.04
396.9552612	0.23
401.1411133	4.84
406.9415283	0.04
415.0584717	0.22
420.1765747	0.15
433.0340576	1.44
436.0503540	0.14
438.1649780	0.19
445.9205322	0.18
446.5765381	0.08
450.2508545	0.77
452.3369141	0.02
457.8767700	0.02
462.0910034	0.21
464.2304077	12.27
464.8431396	0.05
466.1184692	0.17
467.4777222	0.09
471.9119873	0.05
472.5298462	0.02
476.1613770	0.46
477.2772827	0.09
478.4515991	0.04
480.1196899	0.10
481.9705200	0.62
482.6848145	0.11
484.0699463	0.07
490.2231445	10.96
494.3037720	0.27
496.2593384	0.09
504.1928711	0.03
508.1126099	8.70
510.3192139	0.23
512.2611084	0.05
514.2095947	1.37
522.1119995	31.99
523.0778198	0.45
524.3930054	0.27
526.1781616	0.76
529.3485107	0.03
538.0905762	0.19
540.1102295	0.28
547.5612183	0.09
549.4244995	0.09
550.2924805	0.06
554.1828003	0.03
557.3581543	0.23
565.5561523	0.11
566.3692017	0.06
567.6687622	0.12
583.3949585	0.43
585.1804810	0.81
587.3855591	1.40
592.8028564	0.13
598.2053833	0.09
601.3340454	0.02
603.3179932	4.50
611.2257080	5.36
618.6838989	0.06
619.2988281	2.53
620.3097534	0.13
629.2036133	9.81
629.8385620	0.03
643.1861572	8.02
643.8426514	0.03
647.2205200	100.00
647.9273682	0.15
652.4122314	0.02
659.5582886	0.16
661.2033081	4.48
662.0935669	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2496
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
158.8783417	4.88
160.9096069	10.84
178.7042236	1.76
245.2988892	0.22
257.4216919	0.60
263.0148315	1.06
273.2454834	2.44
275.1856689	7.40
285.3676147	2.75
301.3455200	0.38
303.1784668	24.18
311.1595459	0.22
315.3230591	0.52
317.0787964	2.27
319.3608398	1.58
321.2453003	4.99
333.1572266	0.48
335.2220459	3.33
337.4059448	0.97
347.2917480	28.21
363.2158813	3.10
365.1376343	25.16
386.9834595	0.41
397.2250977	1.29
408.3289185	0.74
437.3386230	1.96
451.8206787	0.35
465.3577271	14.57
497.3512573	100.00
499.4003296	74.88
509.2030640	5.86
510.6812744	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2651
Annotation	Salviadienol B
Peak:m/z	Relative Intensity
158.0106354	0.02
158.9924622	0.05
160.9830170	0.37
162.9653473	0.04
163.8388214	0.03
165.3919525	0.03
170.1307678	0.02
171.0989990	0.02
178.6958008	0.04
185.0312653	0.04
195.0551453	0.09
224.1431580	0.06
236.9310760	0.08
241.1335602	0.20
257.4649048	0.04
259.3491516	0.40
260.2361450	0.06
261.3039551	0.08
262.1791992	0.02
269.2086792	0.11
270.0722656	0.04
271.1911011	0.04
275.3401184	0.06
287.0692139	0.38
289.1889648	0.06
292.8344116	0.04
297.3362427	0.03
299.5327759	0.03
305.2803955	0.28
311.5444336	0.06
312.6680298	0.01
315.0846558	0.08
324.3667603	0.10
327.1621094	0.18
329.1395264	0.42
331.2949219	0.18
332.3027954	0.03
335.2340698	0.03
339.2523193	0.81
340.1254272	0.13
343.4098511	0.07
349.2416992	1.25
350.1915894	0.32
353.2600098	0.02
353.9664917	0.04
356.7408447	0.03
371.1478271	0.03
371.9627075	0.02
372.9617920	0.08
374.3790283	0.02
383.3372192	0.13
384.3696289	0.03
387.2711792	0.15
388.3814697	0.13
389.2311401	0.23
391.4870605	0.04
392.2788086	0.04
396.0729980	0.06
399.3682251	0.06
401.3112183	0.02
403.4382935	0.23
404.3103638	0.01
407.1894531	0.02
411.9063110	0.02
419.1499023	0.22
421.1893921	0.37
422.3798828	0.07
427.3663330	0.17
428.3861084	0.11
431.2610474	0.43
432.3714600	0.18
433.4274292	0.27
434.2271118	0.06
435.1417236	0.05
439.3718262	0.03
440.2162476	0.05
443.3276978	0.08
444.3496094	0.03
445.3342285	0.38
446.2067871	0.09
449.2475586	1.51
450.3128052	0.43
458.4302368	0.03
463.2760620	0.32
465.2908325	1.98
466.2819824	0.61
467.2670898	0.39
468.0391235	0.14
475.4310913	1.27
476.3930054	0.46
481.2907104	0.09
483.3244629	0.23
484.7180786	0.02
490.4055786	0.15
491.3118896	0.23
493.2905884	100.00
494.3491821	23.09
505.2717896	0.39
506.2019653	0.03
507.0153809	0.18
507.7664185	0.05
508.5742798	0.10
509.6282959	0.24
511.2345581	40.65
512.2594604	11.44
518.3611450	0.15
521.1469116	0.03
522.1395264	0.10
523.3301392	0.50
524.4364014	0.31
525.2839355	0.80
526.3178101	0.20
535.4786987	0.47
536.2778931	0.10
538.0606079	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.0403
Annotation	Datiscetin
Peak:m/z	Relative Intensity
92.7823486	0.24
107.0654373	1.60
107.7026062	0.10
109.1304169	0.31
111.1868057	0.11
119.0452118	0.27
121.0929031	0.17
123.0319901	1.04
124.9751205	0.96
133.1340027	1.82
135.0412292	5.84
136.7926941	0.26
140.8672943	0.24
145.3405457	0.17
147.1977539	0.91
149.0094299	2.09
151.0159302	11.61
151.9601593	0.25
153.3190308	0.09
154.2097168	0.92
155.0681458	0.36
157.0073242	0.64
158.9561462	0.25
161.0003052	0.55
163.2191162	0.44
164.0852509	0.50
168.9091492	1.17
171.0244446	2.24
171.8752136	0.25
172.6199341	0.52
173.2984772	1.20
174.9594727	21.31
175.9432983	3.46
177.0360107	2.35
181.9652863	0.17
184.9185181	3.95
187.0107117	1.27
189.0902710	1.96
190.1516113	0.22
195.1835938	1.13
196.3404236	1.24
197.2086487	7.19
198.0117493	6.14
198.9747620	50.25
199.9237671	1.20
201.0464478	9.20
201.9468994	0.46
210.9375000	2.35
212.0263672	1.60
213.0982056	12.19
214.2027283	1.75
215.0929565	5.73
215.9504395	1.07
217.0880432	28.56
218.0572815	1.07
223.0508118	2.41
224.0949097	1.41
225.1708374	0.36
226.0218506	1.17
227.0794373	0.37
227.9487305	0.57
229.1263733	5.47
230.2957764	0.33
238.1072998	0.16
239.0277710	3.90
241.0128174	100.00
242.0352173	6.46
243.0440063	20.16
244.0322266	2.56
249.1545410	0.43
251.0102234	0.08
256.3192444	3.45
256.9999695	39.47
258.0043945	0.93
267.0915527	18.29
268.0391235	1.30
269.1220703	0.18
270.4682617	0.10
282.9493713	0.20
285.1084290	6.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.2329
Annotation	10E,14E-octadecadienoic acid
Peak:m/z	Relative Intensity
82.9390335	3.70
97.1987076	0.66
111.1995850	1.05
182.1694794	1.74
195.0430298	2.24
205.3415527	1.08
233.3520508	1.24
235.4129944	1.48
243.1315308	2.96
251.0086670	0.74
259.2476807	2.60
261.2787781	100.00
262.2439270	1.06
279.2483826	8.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1697
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
167.1144257	0.02
172.7467651	0.00
181.1857452	0.01
233.1622620	0.01
255.3535156	0.02
259.1841736	0.00
267.0962219	0.01
271.1983643	0.11
272.2635193	0.00
279.1549072	0.00
283.0636597	0.07
284.1990051	0.06
295.0838013	0.05
296.2125549	0.00
309.3617554	0.01
311.4038696	0.00
313.1255188	4.09
314.2115479	0.51
319.4369507	0.02
332.3496704	0.00
335.1289673	0.01
337.1231079	0.68
338.1696167	0.16
349.3037720	0.03
350.0671997	0.00
353.2746582	0.01
361.0524292	0.01
362.2487793	0.01
363.8895264	0.01
364.5115356	0.00
367.1303711	1.71
368.2419434	0.40
369.2388306	0.01
371.3073730	0.01
379.2009277	0.58
380.1021729	0.14
380.8756104	0.01
381.5715332	0.00
386.5705566	0.01
387.1842651	0.07
388.2152100	0.02
397.1536255	0.86
398.1975098	0.20
399.2816162	0.02
415.1750488	14.12
416.1751709	2.00
417.2321777	0.42
418.2896118	0.04
422.3131104	0.00
427.1501465	0.00
430.3367920	0.02
433.0399780	100.00
434.0726318	12.57
434.9323730	0.02
438.4348145	0.02
439.0485229	0.01
439.9967651	0.00
441.1215210	0.01
451.4639893	0.01
452.8007812	0.02
453.7399902	0.01
457.2017822	0.04
457.9790649	0.01
459.1152344	0.34
459.9787598	0.09
460.6940308	0.01
463.1526489	0.01
463.9174805	0.01
465.5030518	0.01
471.3082275	0.00
474.9865723	0.02
482.8528442	0.05
484.1308594	0.03
494.9142456	0.03
496.1193848	0.02
507.1574097	0.02
513.0921631	0.07
513.7288818	0.02
514.3463745	0.01
525.1532593	0.04
526.0205688	0.04
526.8059692	0.01
533.6550903	0.00
543.1537476	0.31
544.3441162	0.14
561.0751343	2.38
562.1156616	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.02
Annotation	Unknow
Peak:m/z	Relative Intensity
95.2790527	0.01
96.8692932	0.02
109.9797974	0.02
125.7337494	0.06
134.8613129	0.03
200.0017853	0.02
210.1663666	0.13
222.1153564	0.03
223.9858093	11.35
224.8695679	100.00
235.9072266	0.04
239.0232697	0.03
242.0533905	3.69
242.8448639	10.96
243.5655670	0.04
244.9216309	0.21
247.0371094	0.10
248.1036835	0.13
253.3653564	0.12
263.9678040	0.03
265.7435608	0.04
275.0909424	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.1483
Annotation	12-hydroxy-3Z,6Z-dodecadienoic acid
Peak:m/z	Relative Intensity
66.8194885	0.08
68.9763107	0.15
70.7630005	0.01
76.8176956	0.14
78.8810730	0.05
80.9303513	0.02
83.1157837	0.04
84.3966522	0.06
85.1676331	0.06
90.7802124	0.11
93.0558929	0.01
94.9586182	0.24
96.8711700	0.38
97.9282684	0.03
98.9127350	0.35
105.0545349	0.05
108.8955994	0.44
110.9908905	0.05
112.8898163	0.13
114.4497681	0.02
115.0731201	0.07
116.7190399	0.06
117.8242645	0.02
118.9747925	0.07
121.1633911	0.12
122.8881836	0.36
126.9377136	0.17
128.9496765	0.27
131.0504150	0.19
132.9653625	0.18
135.1241150	0.15
136.8533325	0.20
139.0750275	0.19
140.7864532	0.10
143.0162659	0.29
145.0911255	1.32
149.0748138	0.75
151.1409149	0.05
153.1729126	0.08
155.0071869	1.01
157.0420532	1.48
158.9804688	0.40
164.9717407	0.07
167.0729218	0.39
168.9440308	0.12
169.8726807	0.04
171.0268707	1.81
171.9798431	0.13
172.9454193	0.11
175.5943909	0.03
176.9963531	2.85
183.0577087	0.13
183.7267761	0.04
185.1954651	1.10
192.3185272	0.26
195.0046844	100.00
196.0842590	0.12
203.6594696	1.52
211.9124146	0.09
213.1301575	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2142
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.8776245	0.98
221.059845	7.81
237.0378113	0.13
250.5588684	2.10
251.3097839	0.14
262.6357422	0.74
268.9788208	0.20
280.8863831	2.94
305.1461792	1.12
308.9575195	0.12
311.0704346	0.28
321.1860352	0.53
323.024231	5.20
340.9852295	33.26
346.973877	0.94
379.7480469	0.40
383.1293945	100.00
407.0602417	0.28
411.1707153	0.68
412.0012207	0.12
413.0662842	1.57
425.0938721	1.31
442.9037476	25.94
443.590332	0.11
459.1723633	1.08
466.9155884	0.95
473.1888428	0.97
485.1956177	31.34
502.7935791	5.25
503.4030762	0.74
517.1138306	0.07
545.0818481	1.93
574.6155396	0.16
582.2372437	1.27
619.2792358	0.30
646.0585327	0.13
647.4129639	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0928
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
203.1348877	0.06
215.0681000	0.04
233.1581268	0.01
285.1411133	0.44
297.2278137	0.09
298.6203308	0.02
301.0304871	0.03
302.2915649	0.02
325.2044983	0.08
327.0613098	100.00
328.4100037	0.02
337.4247437	0.01
339.1170044	0.31
342.0938721	0.05
351.1839905	0.02
357.0804749	44.58
363.1438904	0.07
369.0715637	6.33
371.2412109	0.10
373.0297546	0.02
381.2084045	0.10
387.2278137	0.15
393.1698303	3.92
399.0191345	0.87
403.3237610	0.02
411.2172852	1.59
429.1824646	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2678
Annotation	[10]-Gingerdiol
Peak:m/z	Relative Intensity
103.0240479	0.04
104.9235306	0.28
106.9635010	0.52
108.9527893	1.25
110.8425980	0.10
112.8896637	0.20
115.3263168	0.07
117.1393890	0.12
119.0549622	0.62
121.0324478	1.36
122.9975815	2.04
124.9008789	0.08
127.0196762	0.27
129.0838165	0.09
131.0856476	1.00
132.9093628	0.70
135.0507202	2.79
136.9832153	1.45
138.0587463	0.03
139.0597382	0.53
141.0227966	0.24
143.1268921	0.24
144.9624023	1.44
146.9273682	1.69
149.0175629	3.19
150.9802246	1.09
153.0926056	0.74
155.0815887	0.09
156.9565125	0.19
159.0660400	2.15
161.1102753	1.91
163.1219177	6.00
165.1041870	1.64
166.9548645	0.12
168.9984741	0.18
171.0208588	0.13
173.0399170	3.60
175.0606537	0.92
177.1037598	3.35
178.0100403	0.04
178.9975586	1.44
180.4402161	0.14
181.1719971	0.17
183.0636749	0.68
184.0493774	0.03
185.1586151	0.16
187.0093536	2.17
189.1578979	0.65
189.8979492	0.02
191.0870056	0.92
193.2436829	0.44
195.0824280	0.42
196.9854736	0.52
199.0957642	0.20
201.0760651	0.92
203.1568146	0.75
205.1402893	1.23
207.1338196	0.20
209.2260132	0.82
210.9535522	0.17
213.0909119	0.22
215.1812439	1.52
217.1000366	0.40
219.1856384	0.70
220.9994202	0.06
222.0630798	0.02
223.0177917	0.23
225.1478882	0.27
227.0707703	0.04
228.0582581	0.11
229.0996399	0.27
231.2227783	0.37
233.2100220	1.50
235.0239563	0.01
237.2287903	0.27
239.3798523	0.11
241.2805786	0.19
243.1395874	30.70
243.7546692	0.04
245.1406555	3.20
247.3179932	0.11
249.4490967	0.03
250.2506409	0.03
251.2004700	0.17
253.1533813	0.33
255.0735474	0.08
257.2489929	0.16
259.0647583	0.86
261.1726379	100.00
263.1444702	8.01
263.8349915	0.01
265.2001648	0.19
267.2753906	0.10
268.6054077	0.12
269.2672424	0.36
271.0062256	0.26
272.1079102	0.86
273.2722473	0.26
277.3552551	0.17
279.2017822	6.75
281.2335815	0.37
283.0008240	0.43
286.9997864	0.27
289.4217529	0.10
291.2117310	0.12
292.0270691	0.03
293.2019653	0.23
294.8431396	0.09
295.4841309	0.07
297.2039185	1.37
299.3345337	0.48
305.1896362	0.30
307.1506958	0.12
309.1757202	0.89
310.8895874	0.21
311.6138306	0.15
317.2920532	2.97
325.2946777	0.08
329.8933105	0.06
335.2387695	27.61
336.0246887	0.07
344.2645569	0.08
345.3829346	0.05
353.1695862	0.16
354.0345154	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	518.25
Annotation	PS(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
152.9492798	3.83
171.2028961	0.09
186.9052582	0.06
224.5659637	0.05
239.9321899	0.05
264.1593018	0.13
271.2753296	0.07
277.2774048	0.23
279.4019165	0.12
293.3864746	0.17
382.4157104	0.04
413.2681885	2.04
431.2328491	100.00
431.8751221	0.37
446.0098877	0.70
450.1455078	0.12
472.1416626	0.15
475.8928833	0.04
499.3997803	0.23
501.5274658	0.22
503.4242554	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	536.8892
Annotation	Unknow
Peak:m/z	Relative Intensity
170.7602997	0.21
182.1600952	0.08
202.0596924	0.13
211.8727722	0.28
226.6385040	0.12
266.0244141	0.21
294.0051270	0.11
311.9887695	0.16
324.6945190	0.32
327.4356689	0.09
332.2358398	0.29
332.9909668	0.54
334.1088867	0.39
341.2088623	0.31
344.1783447	0.29
345.2496338	0.07
346.8753662	1.96
347.8338013	0.09
355.7775269	0.29
357.6641235	0.25
359.1013794	0.14
363.3386230	0.17
365.0335693	0.14
373.8469238	0.08
375.2199097	0.43
378.0096436	0.05
384.9479980	4.35
391.4412231	0.98
392.0686646	0.13
400.7982178	0.28
402.8612061	100.00
403.8101807	0.69
404.6040039	0.43
410.4429932	0.55
417.3016968	0.31
418.6485596	0.76
420.0820923	1.92
420.7666016	0.84
423.9270020	0.59
424.9135132	0.69
427.0167236	0.40
428.9539795	0.92
430.0879517	0.07
438.2820435	0.30
439.0052490	0.90
440.0643311	0.18
441.5095215	0.46
442.3277588	0.47
443.2932739	0.18
444.8821411	0.56
446.8708496	51.72
447.6315308	0.23
448.7619019	5.34
455.9493408	0.62
463.8757935	0.61
464.8710327	0.27
477.0473022	0.51
486.3466187	0.37
490.7382202	0.61
492.2482300	0.78
492.9105835	0.34
495.6300659	0.34
501.0181885	0.18
504.8101196	0.10
514.4786987	1.89
518.4561157	0.78
519.3168335	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1972
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
164.2872620	0.04
176.2158813	0.07
196.3269196	0.08
207.2160645	0.06
251.1560364	0.05
285.1027222	0.04
294.8419800	0.03
297.2171936	5.25
300.3371582	0.06
307.2031250	0.03
315.1616211	0.19
320.1212769	0.13
327.1930542	10.69
334.0880737	0.27
341.1482544	0.02
345.0440063	19.31
345.6791992	0.03
346.7647705	0.03
351.9432373	0.05
357.1252441	4.88
358.1542969	0.03
361.1785278	0.12
375.0828857	100.00
386.9914551	0.24
389.3830566	0.04
391.4130249	0.02
393.4694214	0.04
396.1106567	0.03
416.9992065	0.07
419.4844971	0.08
424.1859131	0.03
433.2460938	0.05
475.1419678	0.04
490.5728149	0.22
491.2268677	0.73
491.8688965	0.04
492.9620972	0.31
500.4039917	0.09
501.2924194	0.07
507.3063354	0.06
515.5884399	0.10
519.2589111	0.59
527.7222290	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1
Annotation	Vitexin
Peak:m/z	Relative Intensity
125.1885529	0.03
148.9049072	0.09
161.2036896	0.05
178.9922791	0.04
187.1720886	0.02
189.0126648	0.06
190.0784912	0.03
191.0233154	0.04
202.9449463	0.05
205.1305847	0.06
207.1151123	0.11
209.4142761	0.05
215.263855	0.04
217.4392548	0.02
222.7567444	0.12
225.2745972	0.03
227.0511017	0.03
233.1242371	0.04
241.3063965	0.04
251.0739441	0.22
253.3450623	0.01
267.2178345	0.01
268.108429	0.18
269.1075439	0.65
273.2200012	0.05
282.9610291	0.31
288.8226929	0.01
293.1615906	0.06
302.1774292	0.05
307.1895447	0.02
309.2066345	0.07
311.0569153	100.00
311.9302368	0.02
312.9848328	0.03
317.1390991	0.02
321.2791443	0.02
323.0969238	0.24
325.2206421	0.01
329.0841675	0.02
331.2900085	0.05
332.0205078	0.06
337.047699	0.28
338.9356384	0.04
341.0834656	16.74
341.6990662	0.17
345.4449463	0.02
351.36026	0.04
353.1532593	0.63
355.147522	0.21
359.3863525	0.07
364.9409485	0.01
367.064209	0.11
368.1984558	0.04
369.9342957	0.37
371.2528992	3.62
377.2564392	0.13
383.1112671	0.39
385.1169739	0.63
386.2149658	0.04
387.2249451	0.08
389.2558594	4.19
393.9565125	0.09
395.1850586	0.38
396.1934204	0.03
397.8709106	0.10
400.7850037	0.06
401.4829712	0.12
403.2252502	0.06
411.2387085	0.15
413.1910706	3.21
414.2744446	0.08
416.2562256	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.0702
Annotation	Wairol
Peak:m/z	Relative Intensity
92.8340836	0.57
94.9899597	0.09
107.0355835	0.18
110.7630539	0.14
119.0141983	0.96
120.8552170	12.35
121.9300919	0.14
122.9879456	0.20
125.0413361	0.15
126.1155548	0.19
131.1005554	0.25
133.0905914	0.41
134.0546875	0.19
149.0082703	0.91
150.9863586	1.60
152.9963989	0.71
162.9226685	31.49
165.0507050	0.54
166.8842163	0.36
169.2256165	0.11
170.1452179	0.08
170.8530579	0.10
176.9899902	28.75
177.9567413	0.71
187.2125397	0.13
191.3261414	0.18
193.0175934	1.49
195.0014954	55.22
196.0118561	1.08
197.2004700	0.37
198.7911377	0.84
200.2495575	0.11
201.1123352	0.19
202.1305237	0.05
203.1502991	0.16
204.1738892	0.23
207.9148254	0.15
214.9677124	0.90
217.1718750	0.10
218.7933655	0.89
225.1539917	0.20
226.9502563	1.87
227.9808044	0.17
229.0444031	0.98
231.1711731	0.12
235.1127625	0.06
239.1221619	2.75
240.0719604	0.19
241.1232300	0.86
243.0312195	8.39
244.0987244	1.12
245.4026794	0.10
253.0258789	0.41
254.8955994	0.27
257.0649719	1.25
266.9870911	37.80
268.0778809	6.28
269.0635071	0.53
270.0222778	4.81
271.0414734	3.12
272.1160889	0.21
277.0336304	1.01
283.1470947	6.39
284.0562744	100.00
285.0780640	27.18
286.0495911	1.86
289.1466675	0.32
289.9604797	0.12
295.0431213	59.22
296.1356812	6.38
313.0614014	29.42
314.0360107	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	791.4342
Annotation	Unknow
Peak:m/z	Relative Intensity
223.4967041	0.05
225.1188507	0.13
241.0713196	0.08
242.1112671	0.12
247.2041321	0.08
251.2409058	0.44
255.2760315	0.23
268.8801880	0.16
270.2867126	0.09
271.4395752	0.10
273.2190552	0.14
274.0251465	0.12
279.3820496	0.10
280.8933716	0.05
289.4343262	0.21
291.0930786	0.95
292.1572266	0.22
307.1928101	0.04
309.2568970	0.66
310.0863647	0.08
323.2187500	0.05
327.2142944	38.12
328.2324524	10.81
329.2698669	0.04
347.0731812	0.07
348.1392822	0.06
361.4954224	0.09
365.2675171	0.26
371.2022705	0.18
372.9323730	0.03
387.4323730	0.06
389.1378784	1.16
390.2882080	0.25
407.1857910	0.18
408.4837646	0.13
415.4943237	0.10
463.2733765	100.00
464.2697144	33.28
465.4116821	0.25
477.5552979	0.03
481.2210693	22.66
482.2451172	8.16
482.8660889	0.13
494.4788818	0.09
518.5429688	0.32
521.5692139	0.02
532.4107666	0.16
536.7082520	0.08
553.2168579	0.08
554.0414429	0.20
600.1850586	0.20
647.1098022	0.03
675.3452759	0.53
676.2954712	0.06
703.3522339	0.04
715.4050293	0.12
720.4995728	0.06
732.5424194	0.02
733.4185791	0.08
746.4922485	0.15
756.6307983	0.15
760.4120483	0.36
764.3106079	0.09
773.3925781	3.25
774.4213867	4.06
775.0870972	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1086
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
124.9339905	0.03
148.7268066	0.24
151.0429993	0.02
163.0677795	0.06
165.0119629	0.05
167.1301270	0.03
172.9753723	0.05
177.0557251	0.02
178.9857483	0.51
180.0014343	0.02
183.3085022	0.01
188.8866272	0.02
191.1741943	0.10
192.9996033	0.05
199.0980072	0.17
201.0981903	0.15
209.1350403	0.02
215.1143188	0.11
216.9045715	0.03
219.2161865	0.06
221.2759552	0.01
222.2258301	0.02
222.9441071	0.05
243.1095886	1.14
245.1514893	0.03
250.7393494	0.01
259.0564575	34.90
265.3797913	0.05
266.8524170	0.08
269.1334534	33.42
281.0384827	0.03
283.2051086	0.33
285.1397095	0.06
287.0536194	100.00
293.2150574	0.20
297.1886597	0.02
301.0312195	0.09
311.0491638	1.46
315.0869751	0.10
323.2115479	0.07
325.3628235	0.08
329.1936035	0.68
335.3298645	0.03
340.9724121	0.02
342.0731201	0.84
343.2350159	0.03
345.6718445	0.04
352.5231018	0.07
353.1395569	0.03
365.2811279	0.01
369.1102600	0.03
385.1366272	0.02
389.1397705	0.08
401.4338379	0.02
403.2766418	0.06
405.2820740	0.82
406.4187927	0.01
411.1643066	0.04
421.0740662	1.80
431.1560669	6.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	677.2798
Annotation	Vateamine 2'beta-N-oxide
Peak:m/z	Relative Intensity
204.1167755	0.09
259.1151428	0.14
269.0442200	0.06
272.1906128	0.01
279.1526794	0.01
305.2690430	0.03
317.2107544	0.04
318.0819702	0.08
319.0826416	0.03
323.3597412	0.07
331.1718750	0.06
333.2041626	0.36
336.0156250	0.02
336.8696594	0.12
351.4448853	0.07
352.1714478	0.08
355.3171387	0.04
357.1395264	0.42
369.2720947	1.32
404.9864502	0.05
406.9978027	0.03
421.6376953	0.04
448.2897339	0.05
460.6927490	0.01
462.5219727	0.03
463.3429565	0.04
464.3676758	0.15
474.4467773	0.04
476.4036865	0.07
477.3044434	0.05
479.3282471	0.13
480.0755615	0.21
488.1530762	0.31
490.2257080	2.80
492.3030396	3.48
494.1983032	0.48
495.4569092	0.03
497.2324219	0.05
502.6671143	0.05
504.0980225	0.11
504.9047852	0.03
506.1941528	2.34
508.3718262	0.13
512.2261353	1.05
513.3417358	0.52
513.9894409	0.28
514.7529907	0.18
520.2396851	34.12
522.2954102	100.00
524.2271729	0.74
526.1928711	0.10
530.4614868	0.07
532.2792358	0.02
534.1967163	0.06
538.1466675	6.26
538.7503052	0.02
550.3990479	0.07
556.3319702	0.06
557.2009888	0.01
577.5159302	0.04
593.3512573	0.08
596.7580566	0.03
599.1693726	0.23
601.0382690	0.32
602.1167603	0.02
608.9437256	0.03
611.8240967	0.06
613.1327515	0.12
615.6374512	0.04
617.2574463	0.41
623.1150513	0.11
624.1748657	0.13
627.2322388	1.18
631.3314819	0.07
632.2907715	0.05
633.2728271	0.17
635.9609375	0.01
641.1816406	4.44
642.1235962	0.31
642.7680054	0.01
645.2282104	18.57
647.7985840	0.02
648.9699707	0.26
650.9196167	0.09
659.0975952	8.44
659.7611694	0.05
660.3754883	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
179.2946167	0.02
190.9815979	0.01
214.7207947	0.01
267.066925	0.01
269.0720825	0.43
281.0543823	0.03
283.0757446	0.43
293.0484924	0.11
305.1278076	0.02
306.8852539	0.02
309.2182617	0.07
311.0461121	100.00
312.2294922	0.17
323.1448975	0.30
337.3650818	0.04
341.0647583	12.94
341.6755981	0.03
351.101593	0.03
353.1884155	0.98
355.2182007	0.25
367.058075	0.07
370.3106995	0.06
371.1990051	0.22
377.250946	0.09
378.1878662	0.01
383.1198425	0.46
383.8599854	0.02
395.0071106	0.29
401.4562988	0.02
413.1035461	2.21
414.2645874	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
188.6651001	0.03
211.4301453	0.02
224.9354858	0.02
259.7518311	0.01
271.1325684	1.64
273.2250671	0.03
283.1141968	0.20
284.1218872	0.03
291.1182251	0.04
295.0618896	0.55
311.0142822	0.02
313.0778809	4.37
337.1984253	0.45
342.8689575	0.05
354.1143188	0.01
363.3114014	0.01
367.0728149	0.48
379.0579224	0.27
386.1098633	0.07
391.3121948	0.02
397.119751	1.08
398.1032715	0.15
399.1774902	0.10
403.055481	0.03
407.2908325	0.01
415.1385498	10.35
416.3080444	0.39
417.2653198	0.91
423.3953857	0.12
427.1761475	0.11
433.1164551	100.00
441.055481	0.05
456.9760742	0.12
458.8662109	0.07
463.4498901	0.12
464.2263184	0.02
471.2659912	0.03
474.994812	0.06
476.1262207	0.03
477.0333862	0.06
481.3033447	0.02
497.4902344	0.07
499.0422974	0.04
507.3421021	0.07
517.4064331	0.04
525.2357788	0.38
529.1419067	0.01
533.3737793	0.01
543.2981567	0.12
553.8049316	0.06
559.2063599	0.03
560.4498291	0.08
561.3184814	0.20
563.0683594	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.18
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8123779	0.33
179.2600098	0.25
191.1100769	0.05
209.0737915	100.00
303.3746033	0.09
335.0330200	0.13
341.4360962	0.40
391.4098511	0.09
413.1589966	0.16
414.0617676	0.39
415.2309570	0.11
416.2368774	0.21
419.6759033	0.08
430.9362183	0.10
445.8772583	0.06
460.9395142	0.09
503.1581421	0.90
504.2581177	2.19
505.2333374	7.03
533.1061401	0.13
533.8114624	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
213.1210632	0.26
213.820343	0.13
242.0596466	0.27
251.3551025	0.25
255.1598358	43.79
255.7804565	0.23
279.2350769	100.00
279.8673096	0.35
289.3898926	0.14
293.4543152	0.10
295.4704285	0.07
305.5094604	0.28
378.3766479	0.08
391.2244873	0.06
392.3077393	0.34
396.3761597	0.11
418.8952026	0.17
434.3682861	1.44
451.7480469	0.95
452.390686	13.90
457.2557983	0.12
458.3193359	0.68
476.3807373	1.24
477.1379395	0.35
496.4815063	0.12
516.2769775	0.24
534.3934937	0.32
558.7382202	0.58
573.2744751	0.59
654.6482544	0.19
655.3522949	0.23
662.2595825	0.14
664.5403442	0.13
667.9972534	0.25
678.5542603	0.18
682.5335083	0.38
695.6846924	0.87
696.4030151	0.10
705.9620361	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	828.2504
Annotation	Aromatized deshydroxy-C-1027 chromophore
Peak:m/z	Relative Intensity
235.9783783	0.11
237.1056366	0.16
245.2264709	0.06
246.8857117	0.25
247.9513092	0.38
249.9276733	0.27
250.7600708	0.06
260.8525085	0.14
275.8890076	0.04
277.0371094	0.81
277.9893494	0.45
279.0692749	2.64
280.0803223	0.74
281.2286377	0.32
283.1363220	0.10
287.0573425	0.21
289.1958618	0.09
290.8229065	0.26
292.2835693	0.31
294.1264038	0.10
295.9829102	0.09
297.1651611	0.17
298.0616455	0.09
300.8772583	0.13
302.7963867	0.08
305.1567993	0.13
306.3237915	0.06
319.2009888	0.55
320.9900818	3.77
322.1807861	0.27
323.1961060	0.20
324.9490967	0.11
326.0940857	0.09
338.0021362	2.01
338.9960327	0.14
346.1677856	0.09
347.1170349	0.09
349.1259460	1.36
351.0413208	1.53
351.9440308	1.08
353.1260071	0.24
355.2208252	0.22
356.0633545	0.24
363.2268066	0.07
364.2056885	0.70
366.0256958	1.21
366.8932190	0.26
368.1263733	0.22
375.0711670	0.50
376.2031250	0.14
377.3140259	0.26
380.0456848	9.00
381.0199890	2.09
382.1146240	0.21
387.1564331	38.79
388.2433472	6.36
389.0953979	0.11
390.8024902	0.03
392.8685303	0.28
396.0892944	0.75
397.0331421	0.20
399.0762939	1.17
409.1965942	1.05
420.7952271	0.18
422.1394043	0.07
422.8817749	0.10
424.0868530	0.19
437.2974243	0.05
438.9818726	4.69
440.0929565	17.44
441.0959473	100.00
442.2360229	4.85
443.0247803	0.10
458.1308594	8.63
459.1531982	1.25
460.1156006	0.12
469.1701660	0.60
472.3671265	0.05
482.0775146	0.22
487.3819580	0.05
498.3967896	0.09
500.0251465	8.38
501.0895996	2.14
504.3316650	0.17
506.5440674	0.17
510.5584106	0.34
512.1771240	0.96
513.3801880	0.19
515.2399292	0.09
516.1645508	0.14
525.8128052	0.36
527.5683594	0.13
528.2673950	0.07
529.1937866	0.17
530.2525635	0.05
541.9096680	0.05
542.5235596	0.47
543.2817383	0.20
547.1278687	0.09
554.1138916	0.19
560.2003784	0.10
564.1911011	0.04
565.9423218	0.03
572.1891479	0.05
582.1312256	1.73
583.1367798	0.51
584.1947632	0.73
584.8348999	0.21
594.9502563	0.06
600.2748413	0.04
602.1664429	13.64
603.2416382	4.15
632.5905151	0.38
634.6808472	0.10
639.3806152	0.14
643.5494995	0.10
646.4695435	0.18
648.2691040	0.49
649.3273315	0.93
650.2702026	0.18
651.4354858	0.21
653.3483276	0.27
665.0913696	0.70
666.2169800	9.78
667.2105103	2.16
668.1687622	0.32
672.0094604	0.07
680.6438599	0.14
686.2778931	0.21
687.3187866	0.15
688.4008179	0.36
690.3021851	0.14
692.3106079	0.11
695.1969604	0.11
708.2503662	2.72
709.2511597	0.96
720.2605591	1.16
721.2747192	0.46
722.3395386	0.09
737.5720215	0.22
740.1447144	0.13
741.3380127	0.10
750.1243896	0.03
754.3406372	0.39
757.3807373	0.08
768.2133179	3.17
769.0542603	2.37
769.7601929	0.02
775.2713013	0.04
780.0875244	0.20
781.2982788	0.23
782.2985229	0.15
792.3920288	1.39
793.2808228	0.81
800.2836304	0.31
808.3740234	0.07
810.2611084	33.43
811.2096558	15.57
812.1817017	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.5011
Annotation	PI(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
233.2470856	0.19
240.9466705	17.71
241.9856567	3.82
243.1575470	2.20
255.1871185	46.31
256.2619934	31.10
257.2698975	4.65
258.9546509	2.08
275.2185669	0.13
277.2188110	18.53
278.3358459	10.37
279.3048096	0.50
296.9849548	13.82
298.1016541	8.06
299.0090027	0.88
312.1983643	0.67
315.1453247	1.25
316.1192932	0.49
391.2216187	53.47
392.2208862	44.86
393.2706909	6.76
409.6220703	1.53
410.4390869	1.40
413.0849609	10.64
414.2648315	7.54
415.2356567	0.84
431.3132324	0.20
480.4694214	0.10
483.1954956	0.19
497.3657837	0.19
498.5209961	0.21
501.3158569	0.76
501.9891357	0.56
515.4533081	0.11
529.3811035	0.16
553.3065796	71.24
554.2904663	100.00
555.3955078	14.54
571.4364014	22.55
572.3933716	27.94
573.3507690	4.23
575.3179321	8.58
576.3168945	21.55
577.3206177	4.70
593.2930298	1.14
594.3273315	3.29
670.4046631	0.34
671.3338013	0.88
672.6492920	0.26
774.6109009	0.39
782.4357910	0.22
814.5908813	0.57
815.5464478	0.62
816.3348389	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.2894
Annotation	3b,4b,7a,12a-Tetrahydroxy-5b-cholanoic acid
Peak:m/z	Relative Intensity
120.9474182	0.38
122.9682465	0.07
125.1110611	0.21
126.8987045	1.32
128.0503235	0.11
128.8313599	0.15
131.0723877	0.69
133.0594635	0.40
135.0146484	0.52
136.8585815	0.21
138.9555664	0.37
141.1517181	0.26
143.0949554	0.14
144.9206848	2.27
145.8728943	0.05
147.0784607	1.34
149.0745239	1.40
150.9712677	0.55
151.9800720	0.07
152.9843445	0.32
155.1737671	0.08
156.9530334	0.42
159.0121460	0.25
161.1063995	0.74
163.0446320	2.17
164.9599609	1.17
166.9315186	0.19
168.7400818	0.15
169.3534241	0.09
170.9714661	0.50
173.0246582	1.40
175.0578003	1.62
176.9287109	1.11
179.1428680	1.22
180.9611206	0.09
183.0841370	1.61
184.1389771	0.10
185.1029358	0.85
187.0299072	0.94
189.2282410	1.29
191.0758514	0.26
193.0615997	1.67
195.1040955	0.07
196.9285431	0.79
198.8848267	0.70
201.0738525	1.15
203.1180115	1.14
204.7712402	0.07
206.9914398	0.35
208.9913025	0.48
211.1368561	0.27
212.9984436	1.36
215.1621704	0.62
217.1782074	0.75
219.1058655	1.20
221.0953827	1.87
223.0482483	1.26
225.0503998	1.71
227.1179352	0.78
229.0370636	1.55
231.2338104	0.61
233.1518250	1.06
235.1802673	0.46
237.0256653	0.50
239.2332153	2.29
241.2965393	1.28
243.1686401	7.01
243.8390503	0.04
245.1903381	5.48
247.1869202	0.59
249.2317505	0.66
251.1683960	0.92
253.3113403	0.98
255.1315002	1.01
257.1022949	0.76
259.1124268	1.58
261.2004700	16.50
263.2424011	11.61
265.2248230	1.01
267.1874695	0.55
269.2556152	0.93
271.0894775	2.26
273.2369995	1.73
275.2322083	2.63
277.2908630	1.79
278.0519714	0.08
279.2785034	4.82
281.1958008	2.12
283.2030640	0.50
285.3160400	1.19
287.2151184	1.78
289.2735596	3.21
291.2250977	1.99
293.2261658	1.81
293.9854126	0.18
295.2674561	1.09
297.1710815	0.79
299.2007446	1.36
301.2564697	0.56
303.2433167	1.00
304.7143555	0.05
305.3845215	1.70
307.0908203	1.10
307.9399109	0.44
309.0904541	1.13
311.1467285	1.98
313.2798157	3.34
315.2708130	2.35
317.2417908	0.78
319.4636230	0.15
321.2760620	0.72
323.3374329	4.94
324.2517090	0.08
327.2743835	0.18
328.8351440	0.94
329.4580078	1.44
330.2407532	0.16
331.2701721	17.22
333.2614746	0.58
335.2000122	1.12
336.1989746	0.45
337.1393433	0.30
339.5070496	0.29
340.1110229	0.09
341.3311768	23.21
343.2855530	1.63
345.4122314	0.29
347.3069153	2.84
351.5356140	0.19
353.2432556	4.77
354.5986328	0.53
355.3010254	0.33
357.9684448	0.06
359.2388306	100.00
360.0886536	0.90
361.2194519	0.44
362.2614441	0.12
363.4587708	0.17
365.8687439	0.52
367.1895447	0.27
369.1138916	0.36
371.3169861	17.46
375.8051453	0.09
377.1293030	3.46
378.2875671	0.56
379.1972961	0.91
379.9241638	0.05
381.1123352	0.20
384.1115417	0.62
386.0581360	0.70
389.2630310	21.78
389.9336243	0.10
395.3390198	0.19
396.1696777	0.43
397.5344849	0.16
401.5572510	0.03
407.2255554	19.89
407.8738708	0.14
413.2463379	0.09
415.8730164	0.27
425.0357361	0.20
437.3989258	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.3409
Annotation	Keayanine
Peak:m/z	Relative Intensity
221.2240753	0.06
234.8983917	0.05
236.1936188	0.11
247.4149170	0.03
249.1569672	0.70
250.1520691	0.16
261.1153564	0.10
279.5501404	0.03
283.2902527	0.09
287.2937317	0.22
289.1882935	0.28
301.6204224	0.10
303.2015381	2.29
304.2864075	0.24
310.9060059	0.11
312.2095947	0.05
315.5662842	0.09
329.0739136	0.04
348.1089172	0.05
349.2568970	0.05
363.2675781	0.03
367.3686523	0.16
369.2984009	0.05
371.1914673	0.06
380.9672852	0.16
383.2627563	0.10
387.3917847	0.04
389.3280640	0.33
391.4349976	0.13
395.1397705	0.20
397.1372070	2.07
398.1688232	0.27
398.9118042	0.07
407.7260742	0.09
409.3258057	0.36
417.6731567	0.05
421.4195557	0.10
422.3489990	0.07
423.3320312	0.46
424.2064209	0.12
425.2346802	0.03
435.0904541	0.12
437.3984985	0.03
451.2428589	0.22
453.1450195	0.86
454.3485718	0.21
456.1435547	0.10
463.3443604	0.25
465.3336792	0.08
467.3815918	0.72
468.4876099	0.14
469.4573975	2.21
470.4542847	1.17
477.3479004	1.99
478.2699585	0.71
481.4063721	0.04
487.3879395	0.30
491.3801270	5.71
492.4523926	1.73
493.2744751	0.05
495.3208008	0.04
505.4290161	0.51
507.3593140	3.55
508.3147583	2.03
509.3641357	1.17
521.3627319	4.64
522.3022461	2.14
523.4021606	0.31
524.1538086	0.14
525.4369507	0.06
535.6965942	0.23
536.5740356	0.17
537.2689209	0.39
538.4119263	0.55
539.3629150	0.15
549.4567871	0.02
551.3293457	1.14
552.1146851	0.49
553.3540039	8.16
554.3814697	2.26
565.2321167	0.14
567.3434448	16.90
568.4777222	6.38
569.3709106	0.12
571.1547241	0.13
572.6880493	0.06
576.9709473	0.08
579.4849243	0.19
581.5357056	1.38
582.2012329	0.06
583.5901489	0.21
584.8810425	0.30
589.2653198	1.20
590.4801636	0.20
595.0794067	0.57
596.8637085	0.20
597.7048950	0.08
598.5391235	0.07
601.4038696	14.90
602.4530640	4.28
607.5349121	0.11
609.4773560	2.57
610.6428223	0.43
612.5554810	0.12
613.4630737	0.03
614.2516479	0.03
619.4738159	3.47
620.3866577	1.28
621.3156128	0.06
623.3442383	0.27
625.2847290	2.42
626.3264771	0.82
627.5745239	0.18
635.3970337	0.09
637.3242798	0.08
639.3037109	9.35
640.2725220	3.69
649.5342407	0.29
652.7661133	0.22
655.3933716	33.06
656.3684082	12.53
662.5814819	0.09
663.3639526	0.11
665.4411011	0.05
667.4645386	1.43
669.3574829	100.00
670.3287964	38.65
671.0041504	0.07
680.3485718	0.18
681.3478394	1.52
682.6400757	0.32
683.3915405	3.47
684.4061279	1.20
685.4208374	0.98
699.4660034	4.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1453
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
171.1022186	0.02
174.0076294	0.02
175.1015472	0.05
177.2473907	0.04
178.9206238	2.15
180.0880737	0.30
181.9145355	0.06
183.1332703	0.04
185.2089844	0.09
185.9693146	0.02
187.0338287	0.14
188.2333679	0.09
189.0102539	0.14
190.0375519	0.15
191.0584106	0.29
192.0772095	0.16
192.9066925	0.30
194.0707703	0.04
195.2339172	0.02
198.0458374	0.03
199.1569977	0.05
199.8778534	0.05
201.1234131	0.04
203.0536194	0.19
205.0956116	0.09
205.7667847	0.03
206.9070129	0.08
208.0701599	0.01
209.1241913	0.04
210.0182800	0.03
210.9903564	0.44
213.1287994	0.07
214.6109924	0.14
216.0449219	0.12
217.0405884	0.19
218.2391510	0.01
221.0867310	0.09
224.2263794	0.01
225.0863800	0.02
226.1251221	0.09
227.1169891	0.65
228.9889832	1.06
230.2629089	0.06
230.8757324	0.08
232.9726105	0.05
234.2815857	0.03
239.1558533	0.12
239.9917297	0.05
241.0720215	0.29
242.8136444	0.52
243.9861450	0.06
245.0404663	0.20
247.0782623	0.16
248.9444427	0.05
252.0852509	0.02
253.2208099	0.17
255.0410004	2.67
256.0891418	0.94
257.0895386	0.42
258.1264343	0.07
259.1103516	0.03
261.0856323	0.11
264.9214478	0.03
267.1821899	0.08
268.1365051	0.02
269.1588745	0.15
271.0558472	3.80
272.0041504	1.05
273.0928345	1.15
273.9415894	0.24
274.6205139	0.04
279.6522827	0.09
281.1032715	0.23
282.3589172	0.10
283.0085144	0.42
284.1667480	0.12
285.0475464	0.05
286.3914185	0.08
287.2304688	0.07
293.4743652	0.02
295.1128540	0.09
296.1345825	0.14
297.0971680	0.82
298.1462708	0.04
300.0153503	28.05
301.0327148	100.00
302.1166992	17.38
304.3463135	0.07
310.0054321	0.03
310.9981995	0.04
313.0803223	0.23
314.1754150	0.03
315.2047729	0.25
316.0666504	0.08
320.0892944	0.04
322.7652588	0.06
324.1751709	0.04
325.0156860	0.43
326.2356567	0.08
327.0924683	0.05
328.1018066	0.02
330.7474976	0.03
331.9531860	0.05
337.3632812	0.03
338.0466919	0.02
338.8099976	0.06
339.8703003	0.02
342.4674072	0.30
343.1273804	6.75
344.1707153	1.82
355.0870972	0.28
356.1583862	0.15
359.0780640	0.03
362.9970093	0.01
367.0038452	0.18
370.9160156	0.04
373.1713867	1.07
374.1009521	0.10
381.3047485	0.01
384.0820312	0.03
385.2507935	0.06
393.0128174	0.05
395.7629395	0.06
409.1318970	0.11
410.2638550	0.01
412.2926636	0.03
420.0924683	0.03
427.0421143	0.07
429.3942261	0.09
443.1465454	0.05
447.0076904	0.11
448.2846680	0.07
450.1777344	0.04
456.6019897	0.14
457.2847290	0.11
458.3355103	0.05
459.1788330	0.02
461.0971680	0.02
462.1412964	0.05
463.0503540	0.51
464.1268311	0.13
465.1397705	0.29
466.1983643	0.10
472.2670898	0.04
473.3141479	0.09
479.2654419	0.06
480.1065063	0.03
481.9940796	0.02
483.2150269	0.15
484.3197632	0.17
492.1174316	0.04
494.2039795	0.03
495.1041870	0.03
499.1163330	0.04
499.8966064	0.01
501.5166016	0.07
520.3263550	0.01
523.5099487	0.15
525.8898315	0.01
529.0575562	0.01
531.3372192	0.05
536.0218506	0.04
547.2720337	0.02
548.5938110	0.05
549.4600830	0.02
550.2485352	0.02
551.5078735	0.07
563.2278442	0.10
564.2450562	0.10
565.1829224	0.10
573.0602417	0.16
574.4750977	0.12
575.2056274	0.01
577.2698364	0.03
579.3039551	0.10
581.1744995	0.26
591.1365356	1.38
592.1852417	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2496
Annotation	Zizyvoside I
Peak:m/z	Relative Intensity
162.7201691	0.02
204.9737244	0.04
207.2820282	0.02
234.1172333	0.16
234.8043213	0.03
264.7175903	0.06
269.1813660	0.16
289.2721558	0.02
299.0751038	0.03
307.1500854	0.13
310.9771423	0.16
318.0382080	0.04
322.7485962	0.04
325.0021362	0.21
326.1505127	0.11
329.1860962	0.04
359.1376343	0.04
370.2116699	0.03
373.3112793	0.03
389.2703857	0.01
409.2307129	0.02
412.9990845	0.07
414.3300171	0.10
415.3690186	0.17
418.0260620	0.03
425.2745972	0.06
432.3987427	0.02
438.6256104	0.04
443.1934204	0.14
449.4020386	0.16
451.1423950	0.04
456.2574463	0.11
457.5482788	0.09
463.4632568	0.03
486.9398804	0.25
489.2039185	0.11
513.1250000	0.16
514.3637085	0.14
518.9675903	0.11
531.1930542	100.00
531.8407593	0.15
533.2673950	0.07
540.2019653	0.03
558.4686890	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.13
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
160.9560394	0.14
178.9815369	1.33
180.0479279	0.39
220.9498901	0.23
250.6550293	0.10
281.0682678	0.21
281.9390869	0.09
294.4140015	0.02
306.6020508	0.05
311.9707031	0.04
323.0570068	0.83
324.1820068	0.13
340.9238281	2.56
341.8936157	0.22
343.1815186	0.08
360.1990356	0.04
361.2253418	0.29
377.0716553	2.99
378.0960693	5.00
379.0885010	14.43
485.6079712	0.05
503.2083740	100.00
504.1980591	47.41
505.1958618	16.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1507
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
169.2373352	0.08
170.9398346	0.07
174.7642212	0.04
181.1743164	0.09
183.1038666	0.03
185.5462036	0.05
188.8618774	0.11
190.9161835	0.05
193.1411133	0.04
195.2229156	0.10
196.07547	0.19
197.0249634	0.09
197.7653198	0.20
199.0458374	0.53
199.8935852	0.04
201.2279205	0.09
204.7381592	0.03
207.017807	0.05
211.0151672	0.11
213.2882996	0.07
214.8737946	0.16
216.9257507	0.32
220.75383	0.06
222.7980652	0.11
225.7865601	0.53
228.8889923	0.11
238.0338593	0.22
238.9265747	0.02
240.242218	0.23
241.1345825	0.44
243.1189728	0.52
245.1014099	0.03
245.8022766	0.04
249.1810913	0.12
250.376358	0.03
255.8896332	0.05
257.1226807	0.42
265.1956787	0.13
267.0150146	0.24
268.8941956	0.28
271.1523438	0.03
277.3349609	0.06
279.265686	0.09
281.2670898	0.07
283.1123657	5.37
285.0335388	100.00
286.1540527	2.36
287.2299194	0.04
288.6987915	0.23
293.0171509	0.42
295.2667847	0.50
296.9796753	0.09
299.3111572	0.24
306.8406372	0.06
308.0853882	0.07
308.9649658	0.72
311.0280762	46.12
311.9989929	0.37
312.9770508	0.07
321.1171875	0.12
323.1280518	8.61
324.1417236	0.15
325.0185547	0.27
327.1793213	3.03
331.1934204	0.15
333.1867065	0.29
335.1691284	0.35
337.0762329	0.15
339.3218384	0.05
341.0428467	0.12
342.1254272	0.05
346.9352417	0.04
349.2211304	0.09
353.1431885	6.04
357.173584	0.42
359.223999	0.11
365.1438599	0.96
367.2286377	0.24
369.2265015	0.05
374.2910767	0.05
377.135376	1.53
380.4205322	0.10
383.1744385	0.27
385.4781494	0.16
387.2282104	0.02
395.2103882	2.10
408.0391846	0.11
410.9219971	0.10
413.1582642	9.63
414.1577759	0.09
415.0664062	0.09
420.9229736	0.20
427.4249878	0.09
429.8511353	0.17
431.1669922	2.31
431.8583374	0.09
440.1171875	0.10
447.1673584	1.15
448.6814575	0.07
451.2889404	0.07
465.4696045	0.13
466.1861572	0.07
467.4092407	0.07
471.197998	0.03
473.1160278	0.41
477.2200928	0.04
478.6283569	0.14
485.2068481	0.05
491.0951538	0.31
503.121582	26.66
504.4494019	0.39
513.413147	0.03
515.2745972	0.61
527.0542603	0.04
529.4397583	0.12
530.1411133	0.16
531.1237793	0.10
532.9356689	0.27
546.0045776	0.06
547.2536011	0.52
548.1779785	0.23
549.3032837	0.60
550.2111206	0.03
551.2694702	0.09
556.2583618	0.20
557.2555542	0.12
562.8032227	0.05
575.1952515	3.89
576.180603	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.18
Annotation	Lactucaside
Peak:m/z	Relative Intensity
164.4470825	0.06
165.1023865	0.42
178.0419159	0.92
180.9312286	0.05
191.1823578	0.21
193.0527954	13.99
194.9982605	3.86
206.9030457	0.07
235.2059784	0.44
264.6885376	0.05
284.8339233	0.04
319.8536987	0.05
330.0923462	0.05
341.1165161	13.16
342.5844116	0.07
345.1889648	0.06
355.1559448	0.06
359.1655273	0.11
361.1270142	0.03
371.0634766	0.64
383.1408691	0.06
385.1320801	0.03
389.0906372	100.00
399.1785278	0.13
413.3069458	0.06
417.4497681	0.06
422.0621948	0.03
431.0614624	0.98
431.7542725	0.14
445.1828613	0.07
447.0579834	0.09
461.5292969	0.11
463.0965576	0.20
465.4212646	0.05
482.0864868	0.03
490.8408203	0.09
491.4582520	0.11
502.8301392	0.13
504.1350708	0.68
505.0670166	1.22
506.5576782	0.39
507.3427124	0.24
508.3480225	0.12
531.9468994	0.24
533.0969849	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0979
Annotation	Vitexin
Peak:m/z	Relative Intensity
160.9403076	0.02
232.8280029	0.07
258.8712158	0.03
269.1004028	0.07
283.0932007	0.30
290.9984741	0.01
293.1842957	0.04
297.059082	0.05
299.1180115	0.06
308.9298401	0.01
311.0598145	100.00
312.0630493	0.05
321.2273254	0.03
323.196228	0.52
337.1307068	0.15
338.1908569	0.01
341.1384277	13.90
342.2961426	0.11
349.4307556	0.02
351.0600891	0.04
353.0518188	0.78
355.0498657	0.35
365.2869263	0.23
367.1733093	0.05
371.1847229	0.22
377.1850586	0.16
383.1583557	0.37
385.1424561	0.05
395.0184021	0.23
396.3528137	0.02
413.1657104	1.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
184.5107422	0.03
187.9147186	0.02
192.950882	0.08
209.1506348	0.04
225.3923645	0.03
271.1163025	2.22
272.1143799	0.15
273.5581665	0.04
282.9597778	0.14
284.0755005	0.04
285.4341431	0.06
289.2647095	0.04
295.1992798	0.46
296.4926758	0.15
297.2053833	0.01
307.1657104	0.02
311.2676392	0.02
313.1010132	4.92
314.075592	1.19
314.8908081	0.11
323.5012207	0.01
332.2594604	0.14
334.9787598	0.04
337.0586548	0.32
338.1209106	0.18
342.2688599	0.02
345.5547485	0.04
349.5464478	0.09
351.1383667	0.02
363.0606689	0.06
367.0557861	0.17
368.0126953	0.17
374.2694092	0.04
379.2178955	0.20
380.2227783	0.02
390.2420044	0.06
396.2554932	0.08
397.2260132	0.98
398.2125854	0.38
399.3702393	0.08
400.314209	0.02
412.2798462	0.12
413.5778198	0.04
415.1411743	10.34
416.1771851	3.12
417.0218506	0.48
418.2281494	0.34
423.1000977	0.07
424.270813	0.08
427.3079224	0.02
428.1629028	0.05
430.0690308	0.05
431.1833496	0.05
433.1005249	100.00
434.1193848	31.47
440.4963379	0.03
441.2240601	0.22
442.0026245	0.03
443.0397949	0.05
444.8991089	0.11
450.1074829	0.04
457.1240234	0.12
458.5090332	0.13
459.4594116	0.10
460.2982178	0.07
464.2752686	0.06
475.2693481	0.30
476.109375	0.10
477.1068726	0.21
477.7997437	0.02
480.135437	0.03
481.288147	0.13
481.9870605	0.06
483.2805176	0.08
489.0803833	0.05
496.1875	0.01
498.3613892	0.11
500.149292	0.11
503.0042725	0.09
507.2302246	0.11
508.0596313	0.04
513.2756958	0.11
514.3069458	0.08
516.2038574	0.05
525.2791138	0.62
526.2761841	0.33
531.2280884	0.02
535.7062378	0.09
536.5008545	0.16
538.2460327	0.03
539.5950317	0.23
543.1044312	0.35
544.1152954	0.19
547.1060791	0.03
556.5111694	0.16
561.1246338	0.59
562.2592163	0.65
571.3394775	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	987.587
Annotation	PI(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:1(11Z))
Peak:m/z	Relative Intensity
277.1999512	0.07
332.8119507	0.26
347.1227417	0.39
347.9521790	0.16
351.4198608	1.14
365.3060608	0.41
386.0369263	0.20
402.9045105	0.40
405.0235291	0.76
405.6458740	0.35
406.9641113	0.37
421.2447510	0.22
425.3931274	0.37
437.2066650	0.16
439.2218933	2.67
440.4739990	0.30
495.2716064	0.17
497.4553833	4.41
498.6137695	0.31
503.3470764	0.11
569.3604736	8.80
570.3530273	1.15
587.4473877	2.08
588.3676758	0.14
602.2780762	0.08
615.1662598	0.53
659.3553467	31.86
660.4984131	4.87
663.7556152	0.45
664.6387329	0.09
681.5852051	0.25
683.1427002	0.22
689.3861084	0.20
713.1916504	0.06
720.7821045	0.18
731.4338379	100.00
732.5142212	11.86
740.4870605	0.47
775.8640137	0.08
780.2027588	0.11
783.4984131	0.04
804.4044189	0.31
822.6302490	0.06
825.6499023	13.26
826.6400146	1.90
843.4918213	1.69
844.6300049	1.29
871.5482178	1.76
872.1921387	0.08
896.3004150	0.07
912.4205322	0.06
937.7730713	0.16
941.5410156	0.44
943.1071777	0.18
953.6195068	0.23
968.5631104	0.97
969.5975342	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
214.2272949	0.39
239.2869263	0.13
253.5335693	0.05
255.2284546	39.40
256.4711914	0.09
261.314209	0.49
277.0783386	0.04
279.2266846	100.00
282.4065857	0.24
293.2650146	0.32
320.4596558	0.18
333.2909546	0.16
391.2244873	0.24
424.1772461	0.14
429.2407227	0.14
430.4888916	0.09
432.4454346	0.08
434.3225098	1.93
438.4537354	0.25
441.3422852	0.06
452.3091431	16.24
456.7958984	0.07
458.3323975	0.16
476.2679443	2.08
500.5739136	0.32
504.4014282	0.08
518.2924805	0.56
535.5388794	0.06
553.4242554	0.28
560.2137451	0.13
573.6760864	0.12
594.3405762	0.10
655.2127075	0.12
657.5517578	0.15
666.4105835	0.07
678.1948242	0.08
694.7905273	0.06
695.5070801	0.09
696.4867554	0.39
705.7019653	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5068
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
223.0511475	0.21
241.2095337	0.24
251.0917206	0.18
255.1836853	35.95
259.1101074	0.12
265.4442139	0.17
270.2202759	0.07
277.1381836	0.55
279.2350159	100.00
283.524292	0.05
293.1166992	0.44
295.4736328	0.39
297.2178955	0.05
305.2137146	0.15
311.2819519	0.08
323.1831055	0.08
360.4108276	0.07
385.3879395	0.14
392.4202271	0.10
399.3399658	0.13
429.5968018	0.06
431.00354	0.16
434.3776855	0.85
437.223999	0.06
437.9737549	0.13
447.4069824	0.22
452.2384033	15.90
452.8486938	0.08
458.3137817	0.50
476.0584106	1.21
477.2544556	0.09
504.2511597	0.11
548.279541	0.22
574.4448853	0.06
582.3292847	0.08
614.6530151	0.13
618.1411743	0.45
621.3643188	0.07
636.0419312	0.12
654.2872314	0.24
655.5622559	0.05
670.2838745	0.57
678.4337769	0.18
686.4541626	0.13
695.5005493	0.27
696.2312012	0.56
705.5028687	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.214
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.8168488	0.47
203.054245	0.44
221.1206055	6.66
233.0963135	0.12
237.0990906	0.09
250.2927856	0.60
250.9508972	0.13
263.3092957	0.11
268.7131348	0.20
279.565918	0.11
280.8027344	2.14
292.6748962	0.11
304.3096313	0.23
305.2651367	0.43
310.946167	0.30
321.2266541	0.27
323.045105	4.98
336.9838867	0.16
340.5059204	5.38
341.107605	24.60
366.6139526	0.10
383.1223145	100.00
397.8893433	0.11
407.0713501	0.64
410.8231201	0.27
412.9049683	2.23
425.2075806	2.09
442.2227173	1.18
442.9533691	19.82
467.4367065	0.20
473.1375122	0.84
485.1040039	33.24
485.7576294	0.16
503.0273438	5.33
503.6652832	0.43
543.0508423	0.15
545.1881714	1.41
580.8449097	0.26
588.4747314	0.13
618.9112549	0.45
619.954895	0.10
629.0044556	0.26
647.4230347	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.3123
Annotation	N-palmitoyl tryptophan
Peak:m/z	Relative Intensity
130.1600494	0.19
142.0310974	1.51
157.1360779	0.04
159.0025940	5.46
159.7759399	0.07
172.7076721	0.10
174.8781128	0.20
184.1603394	0.08
185.9010925	1.13
187.8493347	0.16
197.2766571	0.20
199.9062195	0.09
203.0841827	100.00
207.1029663	0.13
254.0071411	0.60
255.3364563	0.03
255.9731445	0.04
258.9617615	0.15
268.1839600	5.14
279.3129272	0.62
280.3988647	0.69
290.3266602	0.02
294.2200623	8.96
294.9465942	0.04
297.2701111	0.27
299.4403076	0.05
300.9542542	0.09
305.1514282	0.22
312.1930847	57.76
312.8362427	0.12
323.2154541	0.11
327.3433838	0.04
335.2488098	0.15
336.8786011	0.24
337.4964600	0.13
347.3684387	0.10
352.3339539	0.09
353.2008057	0.34
354.3930359	0.14
355.0241089	0.08
366.4436951	0.11
368.2711182	0.26
371.0398865	0.11
378.1169739	0.07
379.3686218	1.12
380.2149963	0.08
381.4971619	0.51
384.4336243	0.08
385.6977844	0.10
394.2577820	0.79
395.2140198	0.19
396.2933655	0.62
397.4226685	17.12
399.5833130	0.31
403.4960632	0.07
405.3980408	0.20
407.2345276	0.25
410.2670898	0.13
413.4009399	0.15
420.4844666	0.42
421.3320007	0.12
422.6332703	0.81
423.3950500	2.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.0287
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1600037	0.02
219.8141022	0.03
222.8054962	0.02
224.0029297	0.08
225.3158569	0.01
251.0196381	0.08
260.9878540	0.06
263.0706787	0.03
271.2518921	0.04
311.1277466	0.04
316.1674805	0.08
319.1736450	0.02
322.1206665	0.03
336.9927979	0.03
341.2001953	0.06
343.0812988	0.04
350.1929321	0.04
352.5620728	0.05
354.5698242	0.28
355.2788086	0.03
356.1181030	0.09
359.1715698	0.02
362.1779175	0.09
365.2443237	0.03
368.2541504	0.02
369.1523438	0.12
370.0932007	0.08
372.1949463	0.10
375.3150024	0.02
376.4362183	0.07
377.2333984	0.05
378.9396973	0.03
381.1608887	0.08
382.1885986	0.05
382.9514160	0.15
383.6636353	0.04
384.4198608	0.05
385.2236328	0.05
386.3671875	0.01
387.5523682	0.08
391.1866455	0.02
391.9938965	0.19
394.0242920	0.07
394.7706299	0.02
396.0777588	1.07
398.0111084	0.23
403.4053955	0.03
404.2717285	0.03
408.0991821	0.03
409.3399048	0.47
410.0815430	0.24
412.1121826	0.71
418.2563477	0.04
422.1558838	0.62
423.0240479	0.04
424.2761230	0.07
425.3763428	0.47
426.2390137	2.23
430.1923828	0.13
433.1976929	0.23
435.1891479	0.02
436.0322266	0.19
437.0564575	0.03
438.0314941	0.75
439.9356079	0.22
441.8964233	0.15
444.2047119	0.09
445.1673584	0.07
450.0314941	0.20
450.7832642	0.08
453.1799316	0.05
453.9174805	0.01
455.3647461	0.33
456.1153564	0.98
461.1334229	0.02
468.1183472	0.63
469.1472778	0.02
471.9785156	0.03
474.0402222	0.03
474.7501221	0.08
483.1849976	0.20
484.4121704	0.03
486.0386353	100.00
487.3082886	0.31
488.0984497	0.65
488.8240356	0.03
489.9151001	0.09
491.0278931	1.23
493.1897583	0.05
495.0922241	0.07
495.9899902	0.06
497.0021362	0.12
502.0602417	0.28
503.5999146	12.43
504.3618774	0.03
505.8583984	0.07
508.9296265	0.34
509.5450439	0.13
511.4484253	0.38
513.0692749	0.45
514.0986938	0.85
517.7689819	0.14
520.6506958	0.06
523.0875854	0.14
526.9022217	0.25
532.4255981	0.12
533.3222656	0.08
533.9723511	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2144
Annotation	Stachyose
Peak:m/z	Relative Intensity
202.933609	0.07
220.0905914	0.13
221.0538025	3.93
250.8184967	0.64
262.7913208	0.38
268.6064453	0.10
272.9824829	0.09
280.9360046	1.00
305.1095581	1.09
311.1744995	0.63
311.9699707	0.13
321.2009888	1.09
323.0029907	5.69
336.6766357	0.11
339.4244385	0.11
340.5035706	4.31
341.1392822	27.99
346.3599243	0.13
365.2617798	0.37
383.1252441	100.00
397.3931274	0.25
407.0343628	0.09
408.0292358	0.25
409.1553345	0.49
410.3093872	0.32
411.2694092	0.14
412.3552856	0.34
413.0029297	2.69
425.1613159	0.98
442.8623657	21.09
443.6642456	0.10
467.4298096	0.07
475.1204224	0.22
485.2151489	30.34
485.8602905	0.06
502.9099731	6.30
508.7449341	0.15
513.0004272	0.06
545.2227783	2.80
560.1964111	0.07
566.53302	0.30
618.6586914	0.44
635.2892456	0.13
647.159729	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	704.3253
Annotation	Lablaboside E
Peak:m/z	Relative Intensity
255.2662506	0.19
304.2291870	0.08
332.5162354	0.10
347.3370667	0.28
362.2350464	0.28
363.3853760	0.12
411.3982544	0.13
415.0820923	0.07
432.0426025	0.07
438.3055420	0.06
483.4175415	0.13
510.1011963	0.09
532.2556763	0.19
550.4178467	0.32
551.2756958	1.23
552.1890259	0.20
583.1767578	0.17
597.0604248	0.18
610.1199341	0.08
615.2706299	0.10
623.3333740	0.29
624.0586548	0.43
632.5184937	100.00
633.5233765	0.40
634.4943237	0.56
640.5401611	0.20
642.4705200	0.45
643.8764038	0.15
645.9319458	0.27
653.4435425	8.37
654.4431152	0.13
658.2335815	0.05
659.1699829	0.31
660.5225220	0.09
664.9155273	1.00
666.6763306	0.52
668.7025757	0.08
673.5003052	90.19
674.3206787	0.19
675.8768921	0.35
685.7142334	0.16
686.6624756	0.56
687.2986450	0.18
694.8421021	0.07
939.4028320	0.10
1085.7705080	0.50
1086.5842290	0.23
1103.6594240	1.63
1104.5661620	0.98
1185.3345950	0.20
1247.5784910	1.02
1248.5958250	1.11
1254.8665770	0.06
1265.5340580	26.62
1266.5556640	18.88
1268.0000000	0.15
1307.5286870	36.83
1308.5438230	26.29
1309.4836430	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1394
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
92.8522873	0.09
111.0626831	0.33
119.1201096	0.50
120.8344574	0.03
123.0417709	5.07
124.9544754	0.08
133.1799927	0.02
134.8360443	0.03
137.0019836	0.47
138.1517029	0.12
138.9856415	0.10
142.9471283	0.06
145.0497894	0.96
147.0096436	0.23
148.2088318	0.02
151.1613312	0.08
153.0251923	0.96
158.9629211	0.22
161.2229919	0.02
169.0130920	0.25
171.1028442	8.53
175.0735626	0.30
177.3556519	0.11
186.8342133	0.03
189.0631409	4.09
191.0674591	0.03
193.0010376	0.58
201.0744934	4.17
205.2763672	0.04
207.1254272	5.33
219.0677185	8.06
235.0657349	0.07
237.0964355	100.00
237.7331543	0.37
239.0185242	0.06
261.0093384	0.05
263.0680847	0.42
274.7752380	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	830.2632
Annotation	Aromatized deshydroxy-C-1027 chromophore
Peak:m/z	Relative Intensity
233.1176605	0.28
234.0044556	0.11
236.0670929	0.09
250.9831696	0.86
251.8848572	0.28
263.0349731	1.93
264.0442200	0.46
268.4207153	0.09
277.2755432	0.34
279.1331177	0.42
279.9752502	0.97
281.0387268	17.21
282.0735779	3.61
299.1392822	0.17
310.0459290	0.28
312.3521423	0.23
322.0993042	0.11
322.9578857	1.73
324.1570435	0.26
327.4065857	0.14
329.1759033	0.51
333.2732544	0.38
341.1590576	0.98
342.0953979	0.07
353.2425537	0.16
354.1693726	0.20
355.0350952	0.25
359.3432007	0.28
365.0025024	0.32
377.1702271	0.68
382.0597534	0.12
382.9285278	0.23
394.2235718	0.05
395.5817871	0.48
398.1936035	0.17
412.0256958	0.82
413.1673584	0.52
414.0816650	0.54
425.2042236	0.72
441.0252686	0.21
443.0031128	100.00
444.0532837	52.47
444.9437256	0.41
506.3502808	0.81
507.2960205	0.59
508.8697510	0.69
541.4254150	0.09
604.5486450	0.18
605.3326416	0.73
606.0994873	0.98
614.4653931	0.12
641.9274292	0.19
667.8740845	0.88
669.0200195	1.65
670.0274048	2.40
734.6133423	0.08
736.0661011	0.41
739.4766846	0.22
751.8159180	0.12
771.1305542	0.19
773.2340698	0.31
809.7395020	0.38
812.9669800	0.22
814.3002319	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1085
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
142.9835052	0.05
148.9208527	0.03
153.0173492	0.04
161.0352173	0.03
163.2777710	0.01
177.2342834	0.01
179.0355530	0.01
186.1091614	0.03
192.8614044	0.08
233.9064636	0.03
253.2627869	0.02
279.1842651	0.03
281.2544861	0.38
287.1918945	0.06
297.4138794	0.06
298.1854248	0.19
299.1241455	0.67
300.1572876	0.03
313.4150391	0.01
314.1535950	0.09
323.2604980	0.10
325.2813721	0.01
327.2793884	0.06
329.0420532	0.03
331.3577576	0.02
339.1509399	0.26
341.0946045	100.00
342.4770813	0.01
351.4852295	0.03
353.2038269	0.83
355.0870667	0.13
363.3479004	0.02
365.1797485	0.09
367.3558044	0.01
371.1425476	21.72
372.1678772	0.02
378.0541382	0.02
381.1576843	0.15
383.2165833	1.84
385.0631409	0.78
395.1375732	0.02
397.0971069	0.24
398.9740295	0.04
401.1926270	1.00
403.3831177	0.10
407.2347412	0.29
413.2003174	0.96
414.0477295	0.08
415.2012634	0.09
417.1912537	0.31
417.9176331	0.02
423.2719727	0.07
425.1491394	0.76
428.9066467	0.11
433.2572937	0.06
443.1301880	3.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	211.1339
Annotation	12-hydroxy-3Z,6Z-dodecadienoic acid
Peak:m/z	Relative Intensity
64.7343826	0.03
68.8372116	0.63
70.9799652	0.05
78.8668137	0.15
79.5313797	0.03
80.9945679	0.23
82.9855804	0.89
84.7640762	0.09
93.0794067	0.03
94.9956207	0.06
97.1423187	0.11
99.0357361	0.17
107.0820770	0.05
109.0548706	0.59
110.9104462	0.10
115.1483612	0.08
124.9602356	0.09
128.9988098	0.06
137.0794983	0.31
139.1418610	0.15
149.1314850	1.10
151.0362549	1.19
152.9518738	0.06
155.1165771	1.53
162.9239655	0.12
165.0850830	3.21
167.1231537	12.79
173.2076874	0.07
175.1460114	1.33
181.1387787	1.85
183.0760345	100.00
183.6924896	0.24
191.0697784	0.33
193.0559235	29.39
210.9673309	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.4413
Annotation	Unknow
Peak:m/z	Relative Intensity
275.5143433	0.04
279.4012146	0.49
280.8162231	0.17
287.1069336	0.04
292.9682007	0.04
296.7973328	0.09
305.1351624	0.20
318.2112427	0.02
319.0478821	0.03
320.9640503	0.37
322.9098816	0.49
324.2651367	0.18
332.5492554	0.06
337.1764832	0.05
340.9169312	1.68
345.4025879	0.19
359.2710571	0.05
365.1398621	1.84
383.1666870	7.14
391.5005493	0.15
393.0018311	0.33
395.0664673	0.26
397.1618652	1.28
407.3728638	0.24
409.2824097	0.17
412.8598328	0.26
419.4485474	0.08
423.1174316	0.09
425.1168213	1.29
431.2105103	0.06
436.2757568	0.15
439.7052612	0.35
440.7719116	0.32
442.7341309	1.73
443.4666748	0.03
451.3416138	0.06
455.0776367	0.16
463.2589111	0.18
467.1296997	2.49
473.0502319	0.20
478.9724731	0.17
483.2901611	0.08
485.1510620	2.98
485.7646484	0.04
502.6450806	0.05
503.2557983	0.65
505.1879272	0.04
507.4507446	0.05
509.5957642	0.07
524.4975586	0.05
525.4327393	0.18
527.2684326	0.04
531.3761597	0.06
535.3123779	0.30
537.3181763	0.07
544.8573608	0.10
562.3873291	0.27
563.0584717	0.12
567.2645264	0.16
580.3782959	0.06
581.3297729	0.07
584.8960571	0.03
591.5122681	0.07
596.4443359	0.10
600.7024536	0.16
603.3265991	0.22
611.1130981	0.07
613.3032837	0.11
615.4605103	0.07
619.5750122	0.05
629.2404785	0.43
645.0051270	2.14
647.2540894	100.00
649.2330933	0.03
651.0289917	0.06
655.1192627	0.04
665.2826538	26.70
669.4506226	0.05
680.7200928	0.06
684.4207153	0.07
687.4782104	0.12
690.6809692	0.12
694.4276123	0.07
695.4680786	0.13
701.3027954	0.15
704.4827881	0.08
705.0835571	0.14
719.1690063	0.16
729.4794922	0.13
730.9738159	0.05
733.8889771	0.09
739.5390625	0.10
746.8967896	0.24
747.5523071	0.11
749.6537476	0.06
751.3670044	0.14
753.4878540	0.20
754.2672119	0.27
755.4362793	0.54
765.1666870	0.03
767.2451782	0.19
768.5003662	0.05
769.5240479	0.25
771.2791748	0.07
773.3972778	0.12
777.8110352	0.04
779.2921753	0.07
781.2412109	0.14
782.4868164	0.23
786.3427124	0.05
789.2188721	0.05
792.0875854	0.18
794.5686646	0.16
795.4877930	0.06
796.6349487	0.10
803.2088623	0.06
809.6810913	0.35
821.5240479	0.46
822.7639160	0.32
823.7796631	0.02
831.6572266	0.19
838.4223022	0.13
839.5123901	0.34
841.8489380	0.04
847.2296143	0.15
849.8145142	0.17
851.1113281	0.26
851.7266235	0.25
853.4660034	0.18
857.8684692	0.33
858.4749756	0.97
859.2076416	0.14
862.7106323	0.05
863.4788208	0.05
865.3677368	0.24
866.4536133	0.25
867.5987549	0.45
868.5839233	0.28
873.5593872	0.15
874.8693237	0.10
880.5040894	0.85
881.5055542	1.21
883.8486938	0.16
891.4138794	5.56
892.3975220	0.22
908.3294067	0.55
909.5341187	4.27
910.3703003	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0856
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.87670898	0.10
81.08490753	0.09
83.2162323	0.16
91.06611633	0.31
93.02090454	0.30
93.65518188	0.07
95.06629944	0.11
96.1605835	0.21
102.9214325	0.45
104.0209045	0.24
104.8190155	0.23
106.0391998	0.11
107.1739349	0.13
110.0570221	0.15
117.369751	0.11
118.9618378	0.03
119.9641418	0.08
121.0033264	0.10
129.0195312	2.03
129.9997101	1.74
133.0647125	0.35
136.167923	0.16
137.0399628	0.37
138.051239	0.14
140.9534454	0.14
142.0632019	0.17
147.0549469	0.17
150.8690338	17.01
151.9938507	15.20
152.944397	0.61
153.8768921	0.21
155.0786285	0.16
157.2046509	0.18
158.1763458	0.04
159.1046906	0.24
160.2276611	0.05
160.9595947	0.07
166.2656708	0.30
166.9755707	0.95
168.0810699	0.14
169.2685699	0.46
169.952774	0.40
172.0902252	0.17
178.0714264	0.17
178.9807739	0.35
180.0863037	0.66
180.9143066	0.29
181.9429474	0.38
183.117691	2.23
184.3024292	0.18
184.9917145	0.40
186.0778961	0.71
194.9181976	0.13
196.7096863	0.50
197.8619995	1.50
199.1286469	0.23
200.3452454	0.25
208.1799774	0.83
211.0142059	0.54
212.093689	0.08
212.9706268	0.13
218.3609467	0.41
219.3168182	0.23
220.2996063	0.19
225.1110077	1.26
226.1036224	1.54
226.9530792	0.64
230.6356201	0.07
235.168335	1.12
236.0621796	2.19
238.0580444	1.26
239.1006927	4.11
240.040451	0.68
241.7998657	0.06
251.1071014	0.23
253.0834198	100.00
254.0734863	31.74
255.088974	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5072
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
214.2342224	0.26
243.2052917	0.28
253.1205444	0.11
255.3076782	34.31
256.3218689	3.90
261.5460205	0.17
279.2313538	100.00
280.307373	19.17
287.1271362	0.12
297.0796509	0.62
307.2484741	0.31
321.1462097	0.08
343.1825256	0.20
363.2911987	0.13
371.2483521	0.38
379.2843018	0.36
388.1651611	0.15
390.7022095	0.11
391.3208008	0.36
434.2720337	1.34
435.3640747	1.02
439.1652222	0.29
452.2443848	20.65
453.1829224	4.29
457.5361938	0.13
458.3120728	0.49
459.366272	0.43
464.2269287	0.15
476.2770386	1.34
477.0889893	1.00
553.3468628	0.29
598.3625488	0.19
627.1743164	0.35
657.7328491	0.23
669.1710205	0.31
671.2069702	0.78
674.4933472	0.10
676.272644	0.17
678.319519	0.47
688.4786377	0.17
697.2544556	1.22
706.671936	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
191.2729645	0.01
233.0479736	0.06
283.1333618	0.41
289.3044434	0.11
293.4614868	0.04
309.2685547	0.03
311.0618286	100.00
311.9232788	0.44
323.0700684	0.42
339.2660522	0.05
341.0852356	11.04
349.2512817	0.02
351.2371216	0.05
353.0736694	0.56
353.7946167	0.04
355.1198425	0.16
369.2442322	0.14
371.0860596	0.18
371.8536682	0.09
377.1488037	0.40
383.3198547	0.11
393.1960144	0.03
394.9668274	0.39
413.1225586	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0978
Annotation	Vitexin
Peak:m/z	Relative Intensity
149.9729004	0.01
160.8562927	0.05
178.7199402	0.02
190.8954773	0.06
203.1372223	0.02
206.1723938	0.02
249.3189392	0.02
267.0150452	0.11
268.1071167	0.02
269.1301575	0.08
270.1829834	0.07
283.0516357	0.25
284.1019897	0.17
286.3028564	0.05
293.0769043	0.03
294.1673889	0.02
309.3240356	0.15
311.0458984	100.00
312.0457153	68.91
313.0917969	0.01
322.1239624	0.05
323.0271301	0.15
324.0151367	0.19
326.1184082	0.12
328.0845337	0.01
334.0674744	0.01
334.9812927	0.05
337.0041199	0.11
338.2879639	0.07
341.0672913	11.90
342.1762085	9.06
343.4863892	0.02
351.5532837	0.06
353.0419922	0.85
354.095459	0.48
355.1595459	0.14
356.086731	0.17
365.0440674	0.09
365.8594971	0.09
366.8944397	0.05
371.1757202	0.42
372.1158142	0.41
377.0509338	0.07
378.1936951	0.17
383.0540466	0.53
384.1910706	0.31
395.1334534	0.38
396.1041565	0.28
402.1332703	0.02
403.029541	0.02
413.1416321	1.85
414.1392517	2.01
422.6893616	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	701.2284
Annotation	Radiatoside C
Peak:m/z	Relative Intensity
201.3852844	0.25
206.8958130	0.14
223.0381317	0.15
232.9099579	0.19
253.1034851	0.24
255.2796021	0.17
265.3843994	0.48
269.0504150	0.11
270.9416504	0.65
296.9934692	0.38
313.2130127	0.12
315.0775757	3.35
323.1712646	0.16
359.3324585	0.25
371.2816162	0.44
385.2332764	0.09
402.2221069	0.06
409.2816162	0.66
426.4642944	0.14
429.3746338	0.13
431.2033081	0.62
447.2359619	0.49
450.0891113	0.23
459.2469482	0.80
477.1778564	51.60
478.3596191	0.67
479.3862305	0.06
489.2069092	0.82
494.2066650	0.28
495.4264526	0.22
503.1907349	3.67
505.2801514	0.13
519.1597900	0.30
521.2080078	100.00
522.1343994	0.38
527.1589966	0.09
534.5288086	0.08
539.1932983	13.09
540.4920044	0.15
545.2112427	0.48
547.1336060	0.20
552.2154541	0.07
554.2208862	0.27
557.3864746	0.07
563.3538818	0.32
581.2813110	1.26
582.5072632	0.15
607.1705933	0.10
611.1856079	0.67
612.3731079	0.16
615.2022705	0.23
621.3311157	0.06
623.2081299	0.04
640.9511108	0.19
641.5800171	0.26
647.1879272	0.13
650.3931885	0.44
655.1957397	0.66
656.6315918	0.61
657.3085327	1.33
664.9432983	0.21
668.5314331	0.11
669.9362183	0.12
671.0756836	0.06
683.2105103	4.49
684.0890503	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	839.4272
Annotation	Unknow
Peak:m/z	Relative Intensity
239.1807556	0.04
241.0095825	0.04
252.9415894	0.41
255.0766602	0.03
262.6228638	0.14
263.2551575	0.05
269.0578613	0.16
274.7477417	0.06
277.3353577	0.06
279.3226929	0.18
283.1502991	0.02
285.2415161	0.05
287.1459961	0.03
293.2850647	0.02
294.2875977	0.12
297.1355591	0.03
303.1740723	0.09
305.0250244	0.36
311.2828674	0.04
323.0355835	0.76
329.4920044	0.10
337.1545715	0.04
341.0543213	0.06
347.1231079	0.06
349.2598877	0.03
351.3597412	0.03
360.1976929	0.08
361.3438110	0.20
365.2154846	0.87
367.2594604	0.08
379.2406616	0.56
380.6062927	0.03
383.1888428	0.44
397.1840210	5.40
403.1662598	0.05
406.9890137	0.14
413.1042480	0.04
415.2175293	3.50
420.5462036	0.11
425.3460083	0.44
435.5053711	0.09
439.2032471	1.08
441.4288940	0.03
442.8265991	0.20
449.2166748	0.75
451.3037720	0.07
455.3048096	0.06
457.4476318	0.07
461.1806641	0.02
463.5429688	0.16
467.2031860	0.78
474.9808350	0.10
477.4719849	0.04
485.2478027	1.14
492.2877197	0.08
495.3049316	0.13
499.3659668	0.04
511.5632324	0.06
523.1000977	0.23
524.5321045	0.02
525.3858032	0.12
536.2447510	0.13
541.3186646	0.62
542.9325562	0.05
557.6063232	0.03
559.1821289	100.00
559.9924927	0.26
571.9606934	0.06
575.2349243	0.06
577.2074585	44.06
577.8828125	0.24
579.3315430	0.03
588.2876587	0.03
593.5713501	0.03
596.2312622	0.04
599.4109497	0.06
600.3966675	0.08
603.1543579	0.04
620.1722412	0.05
623.1738892	0.04
635.7402954	0.09
644.7164917	0.15
645.6288452	0.19
646.3556519	0.11
649.4509277	0.05
658.6516724	0.04
659.2948608	0.06
661.4319458	0.06
662.7471313	0.08
672.5062256	0.04
674.5714722	0.06
677.0849609	0.26
681.0831909	0.06
685.3364868	0.05
689.5085449	0.05
690.2040405	0.06
695.3902588	0.16
698.2617188	0.05
706.0956421	0.04
712.1690674	0.08
716.4769287	0.02
718.5010986	0.13
719.3283081	0.06
720.5555420	0.10
721.3720093	0.12
723.1378784	0.11
724.4732666	0.03
732.3352051	0.02
733.6868286	0.04
735.1248169	0.05
737.6935425	0.08
747.0509644	0.13
751.4207153	0.04
752.4081421	0.02
754.5684204	0.13
756.2007446	0.08
757.3109741	0.03
760.1818237	0.21
761.1514893	0.10
763.2217407	0.25
764.4179077	0.08
766.2440796	0.12
767.5137329	0.02
775.0108032	0.03
777.6596069	0.17
778.7526855	0.67
779.5512085	0.10
792.4351196	0.14
793.0858765	0.30
794.5073853	0.12
795.4221191	0.07
802.4158325	0.27
803.5400391	0.05
805.5159912	1.65
807.2620239	0.21
808.0394897	0.04
820.2017822	0.85
821.4168091	1.98
822.4039917	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.1382
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
138.9500122	2.69
147.0936890	0.27
151.0296021	1.16
162.9491272	0.04
165.0121307	1.50
174.9825439	0.11
176.6250305	0.02
177.8399658	0.03
180.9835815	0.50
186.0620728	0.13
189.0111084	0.13
192.8326263	0.11
203.1625214	0.38
205.1380310	0.49
206.0340424	0.05
209.2598267	0.03
212.2133026	0.16
223.2381744	0.09
227.2897797	0.16
228.2241058	0.06
229.1751099	0.36
234.9345703	0.23
239.2712402	0.02
245.7541504	0.06
247.2336121	0.51
248.2367554	0.12
255.1267700	0.12
259.1510010	0.14
264.9326782	1.08
271.0574341	0.11
273.0569763	15.06
277.0257568	0.85
283.0942993	7.48
285.0109253	0.52
287.3106384	0.06
291.0098267	100.00
292.5875854	0.09
294.9522095	0.03
297.1464539	0.32
299.1594849	0.12
301.0441284	68.38
301.7439575	0.21
303.1710815	0.03
305.1842651	0.15
306.1396484	0.36
307.0027771	0.02
312.3060303	0.07
313.0048828	0.57
315.1760864	2.52
320.9983521	0.05
323.1363220	0.37
324.6255798	0.07
327.1523132	0.09
331.2232361	0.19
333.1057739	2.46
338.9459229	0.13
343.0051270	0.02
346.1179810	0.04
357.1041870	1.92
364.3080444	0.05
369.3811035	0.12
376.2602844	0.03
379.9629517	0.07
380.9340515	0.95
386.9621887	0.11
391.3789978	0.05
393.7491150	0.14
399.0259094	2.49
407.1826172	0.18
411.2910461	0.28
412.1460266	0.11
415.1544189	0.05
417.1510925	10.84
422.0518799	0.03
428.8965759	0.24
433.6937561	0.18
435.0821838	10.93
436.0059509	0.02
438.0286255	0.13
453.1024780	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.07
Annotation	Ala-Asp-OH
Peak:m/z	Relative Intensity
92.99877167	0.08
104.9096756	0.03
110.710022	0.02
119.1238861	0.13
120.9296494	1.28
121.9822235	0.14
131.0549469	0.22
132.9259338	0.49
134.9393768	0.12
145.0868378	0.85
146.1671906	0.08
146.9030914	0.03
148.9327698	0.90
149.9824677	0.07
151.1606445	0.06
163.0030975	0.13
164.0947113	0.06
166.8974457	0.05
171.2671356	0.15
174.9469757	0.34
177.0015259	3.20
178.0742188	0.06
181.1250916	0.07
182.8089294	0.04
186.3772583	0.09
188.959137	0.05
194.9699554	2.41
195.9014587	0.15
196.9046173	0.03
199.0487518	0.19
200.3352814	0.09
201.2500763	0.06
203.0304718	0.15
211.1181335	0.20
214.7870178	0.04
216.2752686	0.03
220.9354248	0.35
223.3627625	0.28
224.2237549	0.09
224.9323425	0.03
227.1002502	0.42
229.0505676	1.09
230.1047363	0.20
231.1805115	0.12
239.1144409	4.44
240.082489	0.35
241.2169189	0.26
242.2420959	0.16
243.0551147	0.27
249.1895752	0.10
251.1881714	0.16
253.213623	0.33
255.0762329	0.15
257.2097168	0.04
258.4555054	0.04
267.0557556	82.32
268.0354614	8.09
269.2133789	2.48
270.0892334	5.15
271.162262	0.74
276.9303589	0.02
283.0704956	8.72
284.0375366	18.98
285.0879517	5.45
286.1179199	0.14
295.0581055	100.00
296.0993652	13.21
303.9129639	0.06
313.0638123	8.13
313.9890747	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1662
Annotation	Diosmin 
Peak:m/z	Relative Intensity
176.0284882	0.02
193.8656616	0.04
212.1347046	0.06
220.8599548	0.03
226.914093	0.07
262.9882507	0.03
280.1221924	0.01
284.048584	12.34
285.0328674	4.64
299.0630493	100.00
300.0567627	33.55
320.3241882	0.05
321.2961426	0.04
322.4420776	0.02
323.2351074	0.04
329.3030396	0.03
333.0587158	0.01
341.0656128	0.12
342.09375	0.15
350.3397827	0.04
363.2555542	0.04
366.005127	0.04
383.7458496	0.03
385.3521729	0.03
398.2113037	0.04
399.2699585	0.04
402.9761353	0.10
404.2696533	0.29
426.2446289	0.10
431.2681885	0.03
443.1830444	0.34
447.1224976	0.05
450.0467529	0.06
458.9592896	0.02
462.8540649	0.12
485.2738647	0.11
486.3747559	0.02
487.3759155	0.31
488.2407837	0.12
493.5003052	0.07
495.8623657	0.03
517.3342896	0.05
518.3302002	0.02
521.6503906	0.11
522.3988647	0.07
537.3822021	0.03
545.1471558	0.13
546.5196533	0.21
553.1837158	0.03
561.4284668	0.08
562.425354	0.10
563.5062866	0.09
564.4459839	0.04
571.8508911	0.09
589.1099243	0.32
590.3582153	0.22
608.0518188	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1757
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
184.1509705	0.35
251.1448059	0.29
269.074707	0.08
274.0342407	0.10
278.7921448	0.32
301.5307922	0.36
302.1513367	2.86
317.0742798	100.00
333.4916992	0.27
340.1131592	0.15
342.9846802	0.30
359.3025513	0.09
368.3048706	0.17
369.6858521	0.14
379.1863403	0.10
385.3455811	0.09
397.0776978	0.48
409.3149414	0.21
412.5057373	0.09
415.9829712	0.39
417.4145508	0.12
427.4891968	0.31
434.2372437	0.07
444.3171387	0.27
445.4599609	0.34
455.1158447	0.15
459.3087158	0.54
461.3905029	0.08
462.2859497	0.73
463.1062622	2.34
465.0941162	0.26
478.9638672	28.16
482.6365356	0.16
491.0749512	0.62
492.7220459	0.59
494.9488525	0.40
495.9754639	0.38
504.9682007	0.15
534.6860352	0.09
561.2837524	0.56
564.8983765	0.10
565.7942505	0.16
571.3551636	0.55
578.4066772	0.28
579.3201294	1.79
581.8552856	0.17
583.7844238	0.65
588.2646484	0.60
589.3225708	0.07
597.9689941	0.27
598.6777954	0.25
606.114624	0.20
607.3512573	1.18
609.1879272	0.13
615.9883423	0.18
625.3258667	0.94
626.0755005	0.22
634.5209351	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.4576
Annotation	Aquilegioside F
Peak:m/z	Relative Intensity
279.1357117	0.10
287.6164551	0.03
288.3461914	0.02
307.0389709	0.03
409.4285278	0.03
441.6304321	0.03
463.3089600	0.09
491.3071899	0.09
517.4043579	0.26
556.2850342	0.04
589.6150513	0.06
615.5322266	0.02
630.6472778	0.06
633.4217529	100.00
634.1770630	0.18
634.9887085	0.08
641.3234253	0.07
643.6510010	0.06
654.3826294	0.05
659.4536133	0.03
661.4324951	0.32
665.4555054	0.11
671.4091187	0.06
675.5126343	0.35
678.7294922	0.12
679.5953369	0.39
690.4722900	0.10
697.4342651	0.04
704.5794678	0.18
717.2175903	0.13
721.2284546	0.16
733.1529541	0.18
740.9146118	0.11
749.5327148	0.13
758.3540649	0.05
765.3195190	0.13
779.1691284	0.03
780.4581299	0.04
781.2739868	0.15
795.0740356	11.98
795.7656860	0.11
797.3129272	0.14
798.5839844	0.11
805.8369751	0.07
814.0782471	0.13
822.6071167	0.18
823.4133911	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
158.8470612	0.10
162.2344666	0.15
175.8676758	0.04
176.9286194	0.06
189.0016937	0.19
196.9077454	0.05
198.9732056	0.04
205.7722626	0.04
208.2290649	0.18
223.2815857	0.06
228.7939911	0.03
242.8939514	0.10
253.3233337	0.07
269.8828125	0.04
273.2705383	0.12
287.0595398	76.52
287.6697998	0.08
290.8401489	0.41
292.352478	0.04
299.0386963	1.69
301.1235352	0.63
302.331543	0.19
305.2219238	0.05
307.3529663	0.04
311.09552	4.02
318.5859375	0.18
323.2291565	0.39
325.2877502	0.17
326.0179443	0.13
329.0566101	22.17
329.8477173	0.02
332.343811	0.07
333.2737732	0.22
343.1078796	0.11
349.2259521	0.17
353.1392212	14.13
359.2336426	0.32
365.0002441	0.54
366.4344788	0.31
367.6947937	0.80
372.3983765	0.22
377.0139771	0.08
378.9725037	0.12
381.5638123	0.06
383.0289612	19.77
384.7263794	0.04
392.4529724	0.27
395.137146	9.42
403.4000854	0.07
407.872406	0.16
413.0757751	19.54
413.719574	0.45
416.2019043	0.10
417.4801331	0.27
423.2151489	0.33
429.9325256	0.64
431.098999	100.00
432.8508606	0.18
439.2468872	0.11
440.1376648	0.13
448.9465027	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0927
Annotation	Homoorientin
Peak:m/z	Relative Intensity
285.1151733	0.49
299.0292664	0.07
303.2698364	0.13
312.8379822	0.04
325.2430725	0.19
327.0626831	100.00
327.941864	0.49
336.9413757	0.16
339.146759	2.04
341.250885	0.02
352.9129028	0.31
357.0602417	80.45
358.0655518	0.18
367.2368469	0.02
369.1995544	2.53
371.0428772	1.80
381.1279907	0.17
383.1704712	0.24
387.1204224	3.43
388.4827576	0.11
393.0018616	0.65
393.6844788	0.08
399.013031	1.01
409.1464844	0.08
411.1459045	3.52
417.2641602	0.08
429.1029358	25.57
429.7632141	0.08
430.7104492	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.2938
Annotation	LysoPE(0:0/20:3(8Z,11Z,14Z))
Peak:m/z	Relative Intensity
144.9542999	0.01
152.9237976	0.10
168.1294556	0.42
179.2686157	0.08
191.2449188	0.06
219.1018677	0.02
224.1027374	2.58
233.2194824	0.46
242.1368103	1.70
257.3316345	0.02
259.2434082	0.47
261.1822815	0.03
275.3468323	0.55
277.1888428	100.00
380.1465454	0.06
386.7472839	0.03
412.2391663	0.05
413.3101807	0.10
452.4096985	0.04
483.2926941	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1332
Annotation	5'-O-beta-D-Glucosylpyridoxine
Peak:m/z	Relative Intensity
107.9772873	2.40
109.1618195	0.02
123.0033493	0.11
123.9241028	0.37
124.8791046	0.04
129.8704834	0.05
130.7499084	0.05
133.8868103	1.12
135.9718628	1.93
140.0842285	0.02
149.9788208	0.12
152.0262756	8.79
154.0680847	0.16
158.2636719	0.04
160.0729370	0.01
168.0522919	0.07
169.9539032	15.26
174.0026703	0.06
185.0557709	0.01
189.1791992	0.03
190.1774292	0.04
191.0615845	0.14
199.9015198	0.03
201.4102478	0.13
202.0207367	0.04
203.1087952	0.08
208.1754150	0.02
232.1173401	0.07
236.4744568	0.15
242.0800171	0.14
244.8874207	0.03
253.0615234	0.02
260.1257629	0.02
267.0009155	0.23
267.7288208	0.02
272.0453186	0.08
278.1506042	0.10
279.9191895	0.05
285.0611877	0.08
286.1218872	0.20
288.3208008	0.08
289.9768677	0.01
291.4515381	0.04
296.1922607	0.11
296.9209595	0.05
300.1411743	0.07
304.0557861	0.05
314.0952454	100.00
315.3177490	0.06
323.0383911	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	957.28
Annotation	Pelargonidin 3-(6''-p-coumarylsambubioside)-5-(6'''-malonylglucoside)
Peak:m/z	Relative Intensity
291.1689453	0.06
340.6540222	0.12
536.9124756	0.27
545.0933228	0.42
575.0432129	0.12
605.2285767	0.27
665.1436768	0.53
820.2540894	0.29
827.1976929	100.00
828.3949585	7.15
911.2402344	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	977.4861
Annotation	23-Hydroxyursolic acid 28-O-alpha-L-rhamnopyranosyl-(1->4)-beta-D-glucopyranosyl-(1->6)-beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
301.1719360	0.15
542.4127808	0.08
623.7296753	0.11
663.4058228	0.14
723.2503052	0.06
754.9363403	0.25
758.4078979	0.49
775.4794312	0.29
798.5110474	0.18
847.4404907	0.15
849.7114868	0.06
858.6748657	0.11
885.1583862	0.11
886.9822388	0.14
917.4343872	0.21
923.4990845	0.17
931.6182251	0.10
932.4912720	0.09
933.6854248	0.33
941.5122681	100.00
942.4962769	0.22
959.3289185	0.30
960.1394043	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0771
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.9367447	1.45
112.9496613	0.05
114.0445709	0.08
119.3158112	0.06
129.0259399	0.16
136.9358521	100.00
150.8373413	0.05
161.0861511	0.02
167.0718079	0.19
178.8879395	0.69
192.0207520	0.04
195.0563202	0.10
199.0044250	0.03
201.1619568	0.12
208.7930298	0.34
220.1586914	0.28
221.2404175	0.13
225.2439575	0.56
229.1129456	0.14
240.0555420	0.05
252.9931335	0.40
254.9671936	0.70
258.0353088	0.06
270.1892700	0.09
272.2737427	0.04
281.2490540	0.87
283.3520203	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.2268
Annotation	Unknow
Peak:m/z	Relative Intensity
97.8624725	0.01
104.2051849	0.01
106.9729309	0.03
108.8643188	0.04
114.9850006	0.02
120.0394516	0.04
120.9507370	0.06
121.8301926	0.02
127.7169495	0.02
132.0329895	0.25
137.8941040	0.03
144.1567993	0.03
146.8872375	0.05
148.9960327	0.01
150.2856293	0.02
159.1209106	0.02
161.1387329	0.04
164.9838257	0.02
172.8886871	0.02
173.8866577	0.03
175.0413666	0.12
178.1191101	0.06
179.7792664	0.04
180.8117523	0.05
186.0181885	0.06
186.7326965	0.05
189.1525879	0.04
191.1967773	0.06
193.1404419	1.17
194.0268250	0.05
197.6589050	0.05
199.3414307	0.07
201.2375183	0.07
202.2371674	0.07
210.0610352	0.08
211.2120667	0.04
213.0978394	0.04
214.9800720	0.03
217.0258789	0.03
230.2396240	0.03
236.9142761	0.02
239.9497375	0.01
254.0545959	0.87
259.8086853	0.30
264.2578735	0.06
267.3067322	0.04
269.2585144	0.02
278.2326050	0.29
281.0153198	0.10
282.2903137	0.06
283.1271973	0.06
284.4157715	0.04
285.2124634	0.06
286.4090576	0.02
292.1555176	0.05
293.2035522	0.03
294.3248291	0.23
296.1694946	0.09
297.1632690	0.31
300.2068176	0.05
301.0114136	0.10
305.6860962	0.33
306.2890015	4.72
308.4647827	0.03
312.0505676	0.12
313.1776733	0.12
314.1820068	0.08
315.3560181	0.04
324.1876221	100.00
325.2048950	0.31
326.1405029	0.02
328.3494873	0.05
333.1032104	0.54
333.9213257	0.13
335.0894470	0.05
340.7884216	0.01
343.3099060	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1866
Annotation	Lushanrubescensin G
Peak:m/z	Relative Intensity
189.0510406	0.04
207.0535889	0.05
216.2480164	0.04
219.0803833	0.09
234.2267151	0.03
235.1613770	0.24
237.0576172	0.03
245.0705872	0.04
251.3735046	0.18
253.2962341	0.04
261.1967163	0.11
263.1716003	0.02
273.1264648	0.22
274.4214478	0.02
279.1809082	0.02
289.1833191	0.79
291.2667847	1.73
299.4125977	0.07
302.9927673	0.03
307.2325745	0.12
308.2545166	0.03
309.0682068	0.05
317.1850586	0.83
323.2989197	0.10
333.2150574	0.70
335.2558899	6.24
349.1751709	0.46
351.1861877	37.17
353.2766418	1.03
361.2575989	1.04
379.1974182	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
160.8284607	0.01
163.1594696	0.03
174.8276062	0.02
179.0169983	0.02
211.2868958	0.01
227.3375549	0.02
233.5651855	0.02
267.916748	0.06
269.0878906	2.00
269.8213501	0.02
279.1938477	0.04
280.9092407	0.15
282.473938	0.02
283.2222595	0.38
285.1360779	0.04
286.5747681	0.06
287.4744263	0.03
293.2988892	0.07
295.14151	0.04
298.2661743	0.07
299.2426147	0.04
303.0365906	0.03
307.2587891	0.06
309.2532349	0.12
311.0462341	100.00
312.0979919	0.20
320.9868164	0.05
323.0554504	0.58
325.2107544	0.07
327.2138367	0.08
329.3944092	0.04
331.3286438	0.04
335.2416687	0.03
336.9918213	0.13
341.0957642	18.37
341.7132568	0.09
343.2002563	0.04
347.0860901	0.03
350.928772	0.07
353.0367737	1.32
355.2523193	0.38
356.6786499	0.03
365.2020569	0.29
367.0800476	0.10
369.2945862	0.05
371.2183533	0.29
373.4679565	0.04
376.9798584	0.19
383.1509094	0.90
386.1229248	0.02
387.1508484	0.03
389.1398621	0.04
392.085968	0.05
395.2106018	0.26
400.7775574	0.07
403.382019	0.02
413.2064514	3.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
152.9959106	0.02
170.8035126	0.01
196.0170135	0.36
214.1290436	1.52
261.3053589	0.16
279.2330017	100.00
279.8746948	0.39
324.6658325	0.01
457.7401428	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
173.1661377	0.02
181.0662689	0.09
184.9319458	0.05
211.933075	0.02
223.114502	0.07
233.2086487	0.04
239.3630981	0.08
240.7766266	0.04
249.1574554	0.01
253.2184143	0.01
266.2665405	0.01
267.1820374	0.06
268.9394226	0.07
271.0213928	1.02
272.1889343	0.03
282.9440918	0.12
283.652771	0.05
291.264679	0.06
292.4903259	0.02
295.1228027	0.47
313.066864	4.18
314.2258606	0.04
315.0068359	0.05
320.1504517	0.02
322.0631714	0.03
331.4026489	0.02
337.1009521	1.08
339.2584839	0.07
343.1697388	0.02
348.9719238	0.03
351.1091919	0.02
353.3552246	0.07
357.949585	0.04
366.0668945	0.02
367.1549683	1.06
368.1618652	0.08
379.1264648	0.10
380.2542114	0.02
387.0583496	0.06
389.9483032	0.02
392.7860718	0.02
397.0952759	1.44
399.2249756	0.10
402.3049927	0.05
405.586853	0.07
415.0817261	12.42
416.2009888	0.63
417.2258911	0.31
423.1855469	0.04
427.0900269	0.06
433.1016846	100.00
436.6051025	0.01
441.1119995	0.11
446.3598633	0.04
447.0421143	0.03
449.2337036	0.04
450.2606812	0.18
457.4488525	0.11
459.1003418	0.22
463.0511475	0.07
464.2460327	0.08
475.048584	0.04
476.3701172	0.10
477.0167236	0.01
481.1291504	0.05
483.2676392	0.07
493.4112549	0.06
498.9970093	0.02
517.1668091	0.15
519.8348999	0.06
525.2410278	0.44
527.1896362	0.02
533.3381348	0.08
534.0719604	0.07
535.3235474	0.02
537.2324829	0.03
543.2669067	0.56
545.9158325	0.07
547.2348022	0.03
548.2716675	0.02
557.9174805	0.13
560.4748535	0.78
561.2542114	0.78
562.1135864	0.01
570.1553345	0.20
570.9459839	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.255
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1081238	0.12
191.0895996	0.06
202.7283936	0.10
213.2453766	0.06
223.1542358	0.09
240.9642792	0.37
241.8582153	0.35
242.9587097	0.07
255.2053833	0.10
256.2222900	0.13
277.0252075	0.10
279.1811523	0.22
280.2943726	0.61
289.2020874	0.15
294.9755859	0.09
314.9844666	0.30
316.1145630	0.13
323.5093994	0.05
327.3790894	0.10
330.0866089	0.06
331.0518188	0.14
336.1270142	0.23
339.0945435	0.08
341.2910156	0.15
393.1780396	0.09
394.1898193	0.42
395.1470337	0.18
396.5245361	0.12
399.0153809	0.19
415.7995605	0.07
416.7592163	0.53
422.7390747	0.19
433.2639771	0.13
434.2549438	0.06
435.1475830	0.04
440.4232788	0.20
443.1221924	0.21
445.1269531	0.24
463.4816895	0.08
465.0777588	0.02
471.3427734	0.22
480.9457397	0.13
492.5046997	0.09
497.0952759	0.10
499.3411255	0.11
501.0098267	0.12
505.0068970	0.19
509.1537476	0.38
511.3582153	0.34
512.0475464	0.04
518.2507324	0.15
521.4707642	0.10
529.1633301	0.04
533.4153442	0.31
534.2495117	0.34
536.4038696	0.21
537.4260864	0.38
538.3765259	0.27
539.6495361	0.18
543.4082642	0.33
550.8900757	0.96
553.2478638	100.00
553.9329224	0.25
559.7445679	0.13
560.9691772	0.07
567.2636108	0.11
569.6168823	0.18
574.6244507	0.78
575.4188843	0.38
578.4325562	0.10
579.1261597	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2144
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.1151733	0.54
221.0560608	6.48
233.2928467	0.25
250.6303711	1.04
262.99823	0.28
280.4057617	0.91
281.0532837	0.41
305.2062378	1.34
311.0351562	0.19
321.2673035	0.15
323.0713806	5.02
340.4064636	4.13
341.0853882	26.82
383.1220703	100.00
399.0808105	0.37
407.133728	0.11
412.8178711	2.46
425.1681519	0.81
442.9573364	21.62
467.0241699	1.33
473.0039062	0.54
485.2207031	26.80
503.0023193	4.20
503.7324829	0.32
545.0241089	0.75
584.3939819	0.26
619.3442993	0.19
621.0834351	0.28
647.2003784	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.18
Annotation	Ciceritol
Peak:m/z	Relative Intensity
161.0084534	3.25
167.1368103	0.19
174.9217529	0.22
178.9989014	6.97
192.8926392	2.35
202.8945312	0.14
220.8830719	0.90
233.2931824	0.08
235.2268982	0.37
249.0691223	0.27
250.3795166	0.37
263.0590820	1.03
280.8284302	0.57
287.2214355	0.52
290.4129639	0.20
301.3058472	0.22
305.1202393	0.34
310.9671631	0.17
322.6132202	0.28
337.0638428	100.00
337.6709595	0.20
340.9168091	0.97
354.9418945	0.12
485.2836304	0.26
489.0997314	0.12
499.2412720	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.1721
Annotation	Ethotoin
Peak:m/z	Relative Intensity
115.9057693	0.17
118.8625031	0.07
120.3004761	0.02
136.1105957	0.14
142.0495300	0.22
144.0938110	0.08
144.9035950	0.05
146.2745972	0.08
156.9494324	0.06
159.0695038	1.45
160.9259491	0.34
161.7454376	0.10
162.9514313	0.08
164.1368713	0.04
165.1169128	0.19
166.2948914	0.03
173.0687408	0.12
175.0951233	0.04
178.9275818	0.08
180.9974976	0.02
182.3363647	0.18
183.2116394	0.13
186.9456940	0.03
193.1243896	0.09
203.0287170	100.00
204.1400757	0.04
209.1581116	0.27
225.4226074	0.18
226.1028595	0.24
227.1814728	0.71
228.8102112	0.08
231.1652222	0.09
233.2126465	0.10
236.1678162	0.08
238.3871155	0.03
243.1605225	0.36
244.1134338	0.37
245.1868896	1.36
249.1765747	0.32
251.2773132	0.07
252.4301453	0.11
258.1198120	0.14
267.0033264	1.62
269.1396790	0.12
272.7757568	0.07
278.2421875	0.03
287.2653809	0.13
292.2961121	0.03
295.3725281	0.06
296.5617371	0.06
306.4257507	0.03
317.2257690	0.05
329.2481079	0.06
337.3512573	0.03
344.3469238	0.04
347.3201294	0.29
361.0496521	0.50
362.1518860	0.21
363.1523132	0.27
365.3674622	0.19
371.3619385	0.07
376.9509583	0.06
378.6662598	0.09
380.3860168	0.06
387.0096436	0.06
388.2266541	1.40
389.3003845	1.97
390.1672668	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	337.2734
Annotation	Subamolide C
Peak:m/z	Relative Intensity
95.0360718	2.40
97.0348816	1.44
99.0096817	1.23
100.9988861	0.38
102.8261414	1.07
104.9987411	17.67
106.8887177	27.18
109.0035858	17.91
110.9187622	6.76
113.0454025	1.14
114.8690948	0.90
117.0156784	7.02
119.0535583	25.26
121.0065994	45.23
123.0461273	18.89
124.9617615	3.25
127.2106171	0.53
128.1014099	0.57
128.8385010	1.92
130.9929199	11.22
133.0036469	21.47
135.0492706	47.49
137.0664978	11.17
137.9229431	0.20
139.0014954	2.58
140.9973755	2.71
142.9637146	5.20
145.0417786	15.74
146.9689331	32.02
149.0971069	28.92
149.8530579	0.59
151.0112610	12.83
153.1122131	4.04
154.8942413	2.44
156.9907837	8.54
158.9522705	16.59
161.0976562	25.35
163.1352386	36.14
164.9404755	10.34
166.3029938	0.88
167.0769043	6.11
169.0269623	0.51
171.0784302	17.04
173.1164246	13.90
175.1239471	22.02
177.0462036	28.66
179.1078491	4.36
181.0586853	3.78
183.1725159	1.07
184.9861450	10.49
187.0598755	12.13
189.0899048	15.13
191.1303253	16.38
193.0769958	3.85
194.7576752	3.70
196.8961639	3.52
197.5974274	0.39
199.1376648	9.26
201.0508423	4.08
202.1014404	0.26
203.1128387	6.33
205.1364288	10.69
207.1975403	6.62
209.2014160	3.28
211.0286865	1.97
212.1423035	0.83
213.1070557	4.88
215.1417542	3.82
217.1412964	6.39
219.1557007	3.33
221.0859985	7.28
222.9911499	1.16
225.1924438	1.36
227.1705017	2.20
229.3899231	1.43
231.1337891	1.81
235.2184448	12.59
237.1971436	3.01
241.1550903	2.23
243.0765076	4.83
245.1899719	16.70
247.2202759	1.50
249.0880127	19.50
251.3176270	2.86
255.2071533	1.71
257.1578369	2.80
259.2148438	3.06
261.1896973	12.55
263.2510986	31.42
265.3747559	2.37
271.2976379	1.34
272.9235229	1.35
273.5397949	3.65
275.1356201	1.27
277.2476196	17.79
279.2842407	5.19
283.1950378	3.92
288.9543457	0.34
291.2140198	3.73
293.2584839	0.86
299.1900940	0.23
301.2717285	18.32
307.2875061	3.89
309.3176270	2.00
319.3059692	100.00
320.3122559	0.20
328.3473511	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9934387	0.16
229.0815125	0.05
230.1002197	0.03
231.0503845	0.08
273.0084229	7.87
274.0591125	4.20
275.0727539	1.98
288.8820801	0.11
384.6840820	0.06
386.2724609	0.30
386.9019165	14.41
387.9174194	12.69
388.9841919	9.75
403.1979980	0.06
428.9215088	0.06
461.1144409	0.02
472.5381470	0.16
488.0991211	0.02
498.8363037	0.07
500.8465576	38.80
501.8385010	79.75
502.8414917	100.00
503.5062256	0.12
504.9989624	0.21
509.9917603	0.05
510.8264160	0.08
513.8911743	0.09
525.9212646	0.03
530.9306030	0.18
541.9374390	0.77
542.9648438	0.83
544.0885620	0.37
559.4782715	0.07
560.5773926	0.09
569.9845581	0.31
570.8762207	0.93
571.6437988	0.05
572.6308594	0.28
573.8900757	0.03
584.8358765	0.06
586.7839966	0.08
588.2288818	0.10
588.8938599	0.14
589.6048584	0.09
598.2554932	0.04
598.8771362	0.39
617.3145142	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1646
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
180.9906311	0.08
184.0110168	0.03
185.1311951	0.07
191.0530396	0.07
197.0363617	0.26
206.9238739	0.05
210.776947	0.11
213.1410065	0.02
231.0864105	0.11
241.2424011	0.29
253.641098	0.10
254.8348999	0.37
258.1617126	0.05
270.2988892	0.01
271.0057373	0.24
271.973175	0.06
283.0504761	0.37
287.0552979	100.00
289.2248535	0.05
294.9749146	0.26
309.3079834	0.04
313.0964966	2.72
329.0764771	0.59
330.3287354	0.06
335.0892334	0.06
337.0402222	0.57
346.1295166	0.02
347.1051025	0.04
349.2607422	0.03
351.0986938	0.09
353.2542725	0.15
357.7976685	0.12
359.2399292	0.12
366.9848633	0.87
367.5933838	0.03
379.0914917	0.57
392.4884644	0.12
397.0552368	0.57
415.1752319	6.33
417.2808228	0.10
418.5545044	0.03
431.0658569	0.67
432.4980469	1.29
433.1199951	2.75
442.1715698	0.05
448.4018555	2.67
449.0056152	24.69
449.6668701	0.04
457.3863525	0.26
460.9389038	0.03
462.2492676	0.10
463.2428589	0.17
464.1068726	0.06
475.0603027	0.04
481.25354	0.05
490.1015015	0.13
502.3341675	0.13
504.6992798	0.20
507.4295654	0.03
510.3916626	0.06
514.0684814	0.10
515.4036255	0.05
516.8724976	0.20
534.5205688	0.19
540.1224365	0.14
541.3956299	0.08
546.4591675	0.09
548.3314819	0.09
549.3804932	0.21
550.2719727	0.03
557.9897461	0.04
559.2022095	0.37
563.5366821	0.12
565.1286011	0.09
576.1212158	0.50
577.2545776	2.84
578.7666626	0.10
585.453064	0.16
596.4294434	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	783.2404
Annotation	Unknow
Peak:m/z	Relative Intensity
277.3268433	0.14
279.0364685	0.13
340.8701782	0.05
357.3412476	0.03
398.2253418	0.05
412.5137939	0.06
443.0296021	0.12
485.2335205	0.05
502.9944458	0.30
605.0516968	0.06
620.9896851	0.04
627.2535400	0.03
665.2210083	100.00
665.8501587	0.21
667.2150269	0.36
739.4639282	0.43
765.2369995	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1281.6127
Annotation	Balanitesin
Peak:m/z	Relative Intensity
395.4013977	0.40
453.1577759	0.68
455.4624329	0.07
469.4460449	0.15
473.4313660	0.41
483.2227173	0.31
496.9672241	0.68
499.2848511	0.07
521.5647583	0.08
635.3704834	0.98
645.1890869	0.13
677.5717163	0.52
679.4664307	0.47
697.2386475	0.16
711.6614380	0.31
731.3371582	0.05
747.4439697	0.18
749.4211426	5.99
750.2059326	0.26
763.5536499	0.05
767.4106445	0.83
775.3648682	0.24
783.7341309	0.09
793.3854980	0.13
799.4767456	0.06
811.6560059	0.19
845.4739990	0.16
849.2841797	0.34
865.4954834	0.37
891.5028076	0.42
893.5444336	0.08
895.3660889	0.30
911.4606934	10.61
912.6075439	0.21
919.4727783	5.19
925.5744629	0.14
929.4384766	0.38
937.5231934	0.79
939.4854736	0.36
941.2020264	0.31
942.5072021	0.47
955.4914551	4.66
956.4395752	1.06
957.4887695	1.25
973.4207764	3.31
974.4108887	0.12
985.3608398	0.07
998.2333984	0.11
1019.1531980	0.15
1055.4527590	0.26
1057.6218260	10.23
1058.5919190	0.94
1073.5609130	5.67
1074.5432130	0.60
1075.5888670	0.57
1083.5280760	0.20
1091.6503910	0.89
1101.4541020	1.57
1117.2583010	1.00
1117.9982910	1.04
1119.4805910	12.18
1120.6461180	1.49
1135.5275880	5.74
1136.5621340	3.39
1137.5283200	0.88
1147.5627440	0.29
1177.4895020	0.08
1178.4780270	1.40
1179.4772950	1.62
1180.0861820	0.20
1188.5981450	0.39
1197.6179200	0.33
1201.6285400	0.12
1218.8123780	3.39
1219.6229250	12.09
1220.4090580	0.30
1227.4785160	0.21
1236.5158690	0.17
1237.1744380	0.11
1237.8172610	0.08
1245.5301510	6.87
1246.2097170	0.08
1251.4771730	0.13
1263.5020750	100.00
1264.4743650	3.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1086
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
137.0556641	0.02
146.8835297	0.03
151.0093079	0.35
152.0095520	0.08
153.1091309	0.11
157.0318451	0.12
165.0206909	0.25
166.9754028	0.17
173.3658447	0.04
174.9943848	0.08
180.0354309	0.08
180.8594055	0.13
186.1204071	0.02
187.0772705	0.04
191.9164734	0.10
197.0990906	0.01
199.1114502	0.69
200.9576721	1.78
203.0177460	0.09
207.2017975	0.35
209.1137695	0.38
215.0364227	0.25
217.1294250	0.05
221.2619324	0.02
223.0607605	0.09
225.1068726	0.31
227.1546936	0.10
231.2049255	0.06
234.9935760	0.15
241.2354126	0.49
243.0904846	4.08
245.0990906	0.01
249.0162659	0.06
251.0722351	0.50
259.0419922	67.52
260.0507507	0.07
266.8743286	0.22
269.0811768	17.23
273.2902832	0.20
283.0723572	0.61
285.8094788	0.16
287.0136719	100.00
288.4319458	0.03
289.1445618	0.02
299.1006165	0.06
301.0847168	0.05
311.0263062	0.14
313.1339111	0.12
316.8489990	0.02
320.1182251	0.03
323.3712769	0.06
327.0285339	2.27
328.0466614	6.23
329.0325317	8.59
329.6680908	0.01
339.2196350	0.04
340.1339111	0.09
340.9290161	0.04
342.0678406	0.07
343.1580200	0.04
352.1508789	0.04
353.2751465	0.07
356.9433594	0.81
358.0785522	3.90
359.1321411	2.09
361.1776123	0.13
370.0938721	0.41
371.1958923	0.05
376.7762756	0.04
384.4243469	0.13
387.3087463	0.05
389.2720032	0.14
394.1571350	0.31
395.0629578	0.11
400.1487732	0.17
401.4776917	0.02
403.1459961	0.22
404.4714661	0.05
405.0780029	0.06
411.9588013	0.14
413.1133423	0.02
414.3553162	0.06
421.1987610	0.48
430.2471924	0.60
431.2126770	4.93
432.2125549	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5164
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
240.9317017	4.44
259.2655640	0.55
261.1577148	0.22
279.3096619	51.08
280.1824951	0.07
280.9388428	0.16
297.1342163	14.30
315.0928345	1.00
415.2677002	45.16
416.3944092	0.46
417.1952515	0.11
433.3145752	2.38
575.4273682	0.23
577.3148193	100.00
579.4005737	0.30
594.7887573	0.92
595.3915405	15.65
695.5609131	0.16
733.2687378	0.21
793.7247925	0.40
796.5081177	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5071
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
223.1704407	0.06
250.9715881	0.18
255.2028656	36.67
256.2985229	8.08
261.2341309	0.64
277.2503357	0.06
279.230835	100.00
280.2268982	18.99
293.3922119	0.64
296.635437	0.12
298.1101685	0.17
305.140625	0.20
308.9449463	0.23
391.3588257	0.22
393.208252	0.17
416.2709961	0.29
421.1425171	0.07
427.1518555	0.09
434.293335	0.87
435.4436646	0.32
452.3171997	19.08
453.1576538	2.83
454.0999146	0.20
458.3919678	1.31
459.0717773	0.09
473.4911499	0.07
476.2540283	1.60
477.1679688	0.71
501.2722168	0.06
505.2085571	0.11
520.1188965	0.14
525.612854	0.11
547.4817505	0.15
595.1452026	0.11
634.0532837	0.14
656.1582642	0.10
669.0908203	0.31
671.4896851	0.17
679.4862061	0.23
681.1045532	0.24
688.6812134	0.04
697.4614868	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1384
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1359100	1.05
221.0274658	0.85
259.0723877	16.55
322.8424072	0.71
341.1260376	1.88
421.1292114	3.40
439.1285400	52.79
503.2630615	100.00
554.4295044	0.18
583.2635498	33.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	955.488
Annotation	Tuberoside A (Ullucus tuberosus)
Peak:m/z	Relative Intensity
304.2537537	0.12
321.0581665	8.31
322.1085815	1.84
333.1052551	0.11
339.0841980	9.52
340.0785217	0.90
350.6245728	0.07
363.2399597	0.12
364.8667603	0.03
370.9869690	0.13
381.2265625	0.53
382.4910889	0.13
389.2412109	0.24
392.1733398	0.05
393.1921997	0.11
404.9839478	0.67
407.1609497	2.32
408.1306152	0.69
409.1726074	0.46
410.1084595	0.24
417.2276001	0.35
422.3198242	0.21
435.1533203	5.53
436.1537476	1.00
439.2205200	0.32
450.7733765	0.28
453.1750488	1.71
479.1108398	1.42
480.2159424	0.81
497.1176758	100.00
498.1196289	18.78
564.3944092	0.05
572.4469604	0.03
615.3056030	0.16
626.2179565	0.29
630.4411011	0.21
633.4683228	2.91
634.4462891	1.56
645.5297852	0.04
647.1435547	0.26
671.9381714	0.08
676.9306030	0.23
697.5722046	0.03
714.2394409	0.21
733.4947510	0.04
734.2179565	0.14
737.6050415	0.24
767.3471680	0.06
775.8260498	0.11
791.5014648	0.15
792.4230347	0.50
793.6303101	0.06
794.2999878	0.15
794.9012451	0.37
805.8170776	0.16
809.3715820	0.29
810.6519775	0.05
818.9197388	0.09
822.4346313	0.78
831.7303467	0.11
849.8973999	1.18
850.5967407	0.09
861.9630737	0.10
867.1909790	0.09
878.3645020	0.33
882.3863525	0.18
893.7924805	2.92
894.5436401	1.31
895.2540283	0.07
906.2335815	0.09
909.4218140	0.52
910.0585327	0.17
910.6603394	0.07
911.5810547	0.51
912.5380249	0.36
919.4423828	0.12
920.5443115	0.72
928.5211792	0.09
937.4028931	10.52
938.4343262	10.65
939.0902710	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.33
Annotation	3,4-Diketo-2',3'-dihydroxy-2-nor-beta-carotene
Peak:m/z	Relative Intensity
227.2926331	0.04
242.2414551	0.04
243.0245972	0.07
279.1152344	0.93
280.2983398	0.72
392.2774048	0.09
419.3798828	0.06
434.4332275	0.06
459.4862671	0.27
463.5151367	0.06
504.3029175	100.00
505.2472534	62.45
505.9089966	0.50
506.5574341	0.16
535.4835205	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5078
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
221.1262512	0.12
242.1390839	0.10
255.2202301	36.21
256.0552063	0.40
257.4073486	0.08
261.2322998	0.16
279.2302856	100.00
279.8370361	0.21
281.2609558	0.07
283.3739624	0.58
290.1798706	0.05
293.3280945	0.50
295.4176025	0.70
297.1091614	0.18
311.4855957	0.23
336.3563843	0.33
378.3199463	0.08
391.1262207	0.46
392.0726929	0.08
404.1786499	0.08
419.3025513	0.44
430.382019	0.09
434.2879028	1.20
437.4733276	0.03
452.3226929	17.29
458.3833008	1.41
465.6132812	0.17
476.2542114	2.48
488.3063965	0.19
516.4561768	0.06
519.2915649	0.14
553.3025513	0.24
555.711853	0.09
557.4887085	0.09
587.0818481	0.21
607.5917358	0.26
609.2855225	0.08
614.8006592	0.20
621.4853516	0.08
636.2946167	0.12
654.3873901	0.28
657.1248169	0.10
660.12146	0.44
668.4505005	0.08
670.3244019	0.22
673.545105	0.09
678.291687	0.11
695.4319458	0.31
696.387146	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	989.3195
Annotation	Lantanose B
Peak:m/z	Relative Intensity
305.1849060	0.19
322.9783936	0.54
340.9913635	5.60
365.0320129	0.57
383.1439209	10.72
385.3227539	0.16
394.3366699	0.08
407.0994568	0.09
412.7871704	1.52
424.9352417	0.71
442.2140808	0.19
442.9456482	8.56
466.8915405	0.41
473.2160339	0.10
483.2981567	0.04
484.9490051	0.78
503.0012207	22.64
508.5623779	0.06
527.2301025	0.94
545.1265869	40.92
545.7672119	0.22
569.1785889	0.12
574.7178955	2.06
587.1597290	0.17
604.8405762	8.00
611.2499390	0.46
629.1539307	0.32
634.9119873	0.05
645.2875366	0.15
647.2673950	1.30
665.0474243	4.33
689.2513428	0.29
707.2005005	100.00
707.8430176	0.21
718.9550781	0.25
731.0924072	0.08
749.3177490	1.43
755.4441528	0.28
767.4555664	0.12
773.7052002	0.10
779.4517822	0.05
791.2021484	0.25
797.2529297	0.11
809.2678223	8.19
827.0295410	0.23
828.3624268	0.09
841.5167236	0.04
869.2774658	1.51
971.5401611	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8248749	5.05
115.9835052	0.57
116.9406281	4.19
131.1604919	0.04
133.0484009	0.30
158.8674622	96.53
159.8927612	19.11
160.8770905	100.00
198.9653931	0.31
200.1653442	0.23
200.9262695	4.21
203.0951233	0.32
218.3711548	0.64
219.0419922	1.21
228.9872131	1.82
230.9072266	59.09
247.0010376	1.19
255.1822815	0.20
256.8825684	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.21
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
94.90397644	0.30
107.0131683	0.25
109.9164429	0.08
110.8129578	0.13
112.8689575	0.15
116.7725754	0.26
121.012558	1.35
122.8564911	0.06
131.045517	0.19
133.0217896	1.04
134.9977417	0.81
137.050415	1.49
139.1798706	0.36
145.1182251	1.49
146.8320007	0.68
148.9360199	2.03
153.06987	0.36
157.0675659	0.50
158.7817993	1.23
161.0601196	1.40
162.7581024	1.08
165.1551971	0.38
167.067627	0.66
168.9959106	0.72
170.9901428	0.87
172.9206543	0.59
175.1697388	0.44
177.1716461	0.17
179.109375	0.34
180.8973999	0.32
183.1551514	0.53
185.236496	0.26
187.045639	0.53
189.0975952	0.11
189.8335571	0.18
190.9401855	0.09
192.9507294	1.08
197.1732178	0.88
199.1860352	0.56
201.0305481	0.79
203.0839233	0.42
204.9472351	2.05
207.094635	0.88
209.1697998	0.35
210.8634644	0.85
212.2288208	0.10
215.0142517	0.25
219.0364685	1.10
220.0041809	0.52
221.0491638	0.28
225.2649841	0.18
229.1235352	2.37
231.206604	0.38
233.2673645	0.35
235.1208496	0.88
237.2156677	0.20
239.2420044	2.34
240.2003174	0.25
247.0428772	0.75
249.2105103	0.16
250.9417725	0.15
251.6203918	0.16
257.161438	3.31
263.2158203	0.43
264.1981506	0.09
265.213623	0.64
275.1934204	100.00
284.2856445	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5074
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
224.0705414	0.11
237.0795898	0.38
241.280304	0.29
255.3055573	40.05
256.3442993	0.16
261.1990967	0.45
267.4913635	0.09
277.1986389	0.42
279.2342529	100.00
279.8406982	0.26
283.1077271	0.07
293.0481262	0.25
415.2208862	0.32
419.5644531	0.11
429.390564	0.09
431.4056396	0.21
434.2589722	1.11
437.4506836	0.12
449.616272	0.18
452.3684082	17.33
454.3513794	0.21
458.3551025	0.65
463.4371338	0.51
476.2381592	1.22
506.3875122	0.07
534.8644409	0.11
546.571106	0.07
614.6587524	0.06
651.119812	0.25
653.6695557	0.13
654.3966675	0.10
686.4551392	0.24
695.4992065	0.20
696.4135742	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.2805
Annotation	Multifidoside C
Peak:m/z	Relative Intensity
167.2404022	0.07
177.1934967	0.35
180.9816589	0.08
183.0529175	1.44
195.0935059	0.34
197.0177917	0.06
205.1686554	0.40
207.1127319	0.24
211.0894165	2.31
212.1942596	0.07
213.2066956	0.59
217.0576782	0.19
219.0470123	0.42
223.1044922	0.72
224.1346130	0.30
231.9412231	0.14
233.3527069	0.54
235.1358643	0.69
239.0935516	0.13
241.0569153	1.20
244.1891785	0.48
245.0697174	0.15
247.1099091	0.25
248.9931183	0.25
252.9212341	0.81
265.1685181	0.33
267.2069092	0.43
269.0809326	0.63
271.1120605	0.49
273.2724609	0.25
274.1304932	0.07
275.2398071	0.52
277.4362793	0.09
291.2536316	17.95
293.1575928	2.24
295.1226807	0.13
303.1007080	0.14
309.2929688	15.51
310.0682983	0.22
311.2198486	23.71
312.2186890	0.23
315.3718262	0.34
319.4904785	0.09
325.4645386	0.13
327.3242188	9.34
328.5650024	0.24
333.3146362	1.69
345.4309082	0.15
347.3654785	0.05
351.1508179	0.72
355.2281494	0.09
369.3614502	0.11
373.1983643	0.19
375.4091797	0.35
387.2025757	0.32
393.4590454	0.12
396.2923584	0.07
399.2271118	1.12
402.6912231	0.17
406.9707031	0.14
411.2097168	1.20
412.0759277	0.05
413.2108765	0.14
414.8406982	0.08
423.3406982	0.30
429.4261475	0.44
431.2391357	0.26
435.1788330	0.22
453.2929688	0.83
469.2686768	0.10
471.3485718	44.46
472.2941895	0.24
473.1403809	0.35
483.2554321	0.10
485.0650635	1.63
486.3200684	0.12
487.1706543	1.17
489.2630005	100.00
490.4517212	2.19
495.0028687	0.74
499.2009277	0.61
503.2837524	0.13
512.6959839	1.11
513.3742676	3.60
514.2900391	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5065
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
232.9068604	0.29
255.1592407	44.40
256.1645203	2.29
279.2264404	100.00
280.3055725	16.80
327.3641968	0.17
328.4359131	0.72
341.3652954	0.81
378.3294678	0.17
385.2349243	2.01
387.6010132	1.00
392.9072266	1.69
431.1347656	0.39
434.3196411	0.40
435.5370483	2.44
443.178772	1.10
447.3865356	0.35
452.305542	11.90
453.5991821	2.07
458.1643677	1.74
460.3284302	0.61
469.2119141	1.10
476.1278076	1.46
478.5758057	0.94
502.9164429	1.30
513.2381592	0.41
515.430603	0.25
516.2681274	0.61
523.4282227	0.50
528.4700928	0.23
529.2316284	0.44
553.0374756	0.78
568.6505737	1.21
569.6660767	0.82
573.3037109	1.46
578.2137451	0.97
605.9890137	0.77
610.1813354	0.64
631.3088989	0.71
637.6303101	0.26
648.1849976	1.16
651.8745728	0.62
667.2763062	0.38
671.1365356	1.24
672.461853	0.48
679.2451172	1.48
697.3913574	21.34
698.4716187	7.14
699.2824097	0.33
700.4625854	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	561.0553
Annotation	Gossypetin 8-glucoside-3-sulfate
Peak:m/z	Relative Intensity
168.7136993	0.11
204.0039368	0.28
237.3848877	0.22
246.9602509	0.04
262.2966614	0.14
263.1981812	0.28
271.0849609	0.12
281.2827759	0.07
283.3242188	0.08
307.5083008	0.15
311.0024414	0.05
318.4028931	0.23
321.0955811	0.07
327.6170044	0.33
331.1814575	0.18
332.3433838	0.12
336.5864258	0.37
360.2368164	0.25
362.9130859	0.54
367.3096924	0.35
368.6856689	0.10
371.0936279	0.04
378.6362305	0.05
381.5357056	0.06
382.2432861	0.13
391.2044678	0.08
394.0972290	0.07
399.0740967	0.39
409.1884155	0.11
413.0460205	0.09
413.9664307	0.11
415.2290039	0.06
417.1596069	0.30
418.0438843	3.52
419.2880249	0.07
429.2618408	0.23
431.2622070	0.16
432.2229614	0.25
435.2554932	0.09
439.8914795	0.06
442.0881348	0.10
443.8934937	0.19
445.0996704	1.23
446.1011963	0.67
454.3096924	0.82
455.8330688	0.35
460.0460205	0.62
461.8026123	0.12
464.1033936	0.66
466.6944580	0.05
471.1968994	0.21
472.0605469	0.57
479.3629761	0.11
481.3108521	0.47
484.0124512	7.41
490.0504761	0.11
501.9595337	8.18
506.0186768	0.15
519.8674316	100.00
520.5127563	0.54
523.1282349	0.31
524.3709717	0.64
525.1802979	0.44
529.9645996	0.06
532.7097778	0.24
533.6417236	0.26
536.9432983	2.34
537.7489624	6.48
542.1760864	1.63
543.1394653	1.67
560.8383179	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2728
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
170.9849396	0.50
205.2204895	0.23
222.9706421	31.42
233.2158356	0.21
240.9894409	51.69
258.9874878	1.73
277.2181396	29.69
315.0873413	100.00
333.1404419	12.17
381.9594727	0.08
413.2638550	3.40
431.3228149	1.41
501.3245850	0.31
514.3342896	0.50
519.1548462	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.197
Annotation	(1xi,3S)-1,2,3,4-Tetrahydro-1-methyl-beta-carboline-1,3-dicarboxylic acid
Peak:m/z	Relative Intensity
155.9943695	0.03
170.0046692	0.03
171.5903320	0.03
187.0568237	0.62
205.8168335	0.14
231.1047668	0.98
264.0101013	0.17
274.9747925	50.83
275.5941162	0.21
280.0207520	0.05
324.2390747	0.01
339.0625610	0.07
351.1557007	0.08
364.1873779	0.02
366.8742676	0.18
368.0121460	1.39
369.0293579	0.49
374.7814941	0.10
376.8100586	0.03
386.9871826	0.19
411.8312378	100.00
412.5952759	0.10
417.0735474	0.14
420.0541382	0.02
436.8787842	0.04
440.9769897	0.02
451.1458740	0.13
459.0564575	0.02
489.0836792	0.29
494.9633179	0.07
501.7025146	0.02
502.9368286	0.18
503.9949341	0.03
505.0461426	0.14
510.4780884	0.08
511.1814575	0.03
512.9542847	0.04
528.9951782	0.49
531.0397339	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	329.0649
Annotation	Iriflogenin
Peak:m/z	Relative Intensity
96.9873199	0.06
98.8105469	0.27
104.7795868	0.06
106.8033905	0.05
109.0068970	0.14
110.7929764	0.06
112.9276276	0.07
118.1427994	0.08
119.1131363	0.08
121.0107040	0.28
128.9990234	0.07
130.9621887	0.05
132.8632355	0.38
135.0277405	0.32
136.9718933	1.44
139.1917114	0.05
147.9714355	0.03
148.9664307	1.61
150.7826843	0.19
153.0653687	0.07
154.6722717	0.05
159.1301575	0.05
161.0423279	0.67
163.0580750	0.11
165.1982422	0.05
167.2059021	0.31
172.8671570	0.04
174.1521912	0.32
175.0361938	0.77
176.9302979	3.01
178.3830566	0.28
179.1184387	0.04
181.0157471	0.12
183.0579987	0.12
186.0364075	0.09
187.0267029	0.47
189.0595703	0.04
190.0547638	0.03
193.1035004	0.08
195.0365906	0.99
196.1055908	0.11
199.2537231	0.16
201.0046844	0.04
203.1040192	0.42
208.8742676	0.07
210.0982056	0.04
211.2842712	0.15
213.1304626	0.42
214.8162842	0.28
217.2634583	0.13
217.9994812	0.12
218.8815918	0.54
221.0690308	0.16
223.0289307	0.06
224.6956482	0.23
226.9630127	0.36
229.0091248	0.23
230.4677124	0.11
231.0882874	0.14
237.2027893	0.32
238.2164917	0.06
239.1806641	0.23
240.9990845	0.13
243.1589661	0.10
245.1067200	1.16
246.0094604	0.08
246.8268127	0.05
250.9931335	0.90
252.9602051	0.67
255.0771179	6.26
256.1558228	0.40
257.3433533	0.51
258.1489258	0.05
259.0359192	0.11
261.2116699	0.07
264.9514771	0.88
265.6049500	0.07
266.9595947	0.59
268.1128845	0.08
268.9533691	1.05
270.2473755	0.09
271.0581970	0.11
272.0869446	0.14
272.7512207	0.10
283.0290527	77.24
284.1305237	7.89
285.2434692	3.09
286.0712280	5.34
287.0222168	0.85
287.9923096	1.08
293.1535950	0.60
295.8244324	0.07
297.1577454	0.06
299.0830688	8.00
300.0492249	20.34
301.1263123	5.61
302.2575684	0.21
306.0692749	0.10
311.0212402	100.00
312.0374451	12.04
313.3153687	0.11
319.5450439	0.57
320.7685547	0.23
328.1449585	0.09
329.0713501	8.31
329.7904663	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0658722	0.04
223.8197021	0.02
225.0039825	0.02
244.1599731	0.02
279.3369141	0.07
293.1779175	0.01
307.1488647	0.01
327.5198364	0.01
337.5590820	0.05
367.2295532	0.02
392.0155029	0.01
415.1870117	0.02
451.0600586	0.07
460.9420776	0.06
466.0345459	0.04
475.1495972	0.02
477.5463257	0.04
485.4686890	0.08
501.3473511	0.02
504.3301392	100.00
505.4442139	0.19
520.8298950	0.06
528.4198608	0.03
529.4545898	0.22
530.7527466	0.03
535.3421631	0.04
544.1838989	0.01
546.4782715	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	455.3531
Annotation	Lucidadiol
Peak:m/z	Relative Intensity
130.8643951	0.34
164.1992950	0.43
201.7327728	0.26
202.7559967	0.44
205.1870117	0.20
277.1845093	0.67
304.9179077	0.08
355.3459473	0.20
373.4320984	0.51
374.8229980	1.00
377.1700745	0.25
386.0883484	0.47
387.5201721	0.29
389.5204163	0.14
391.4529114	0.50
392.6924744	0.36
393.6060486	2.31
394.3483887	0.09
395.3051758	1.17
397.0516663	0.36
399.6491699	0.20
407.3517151	100.00
408.3797913	17.87
409.4405518	6.71
411.3623352	3.45
412.4375305	0.26
437.4832458	2.59
439.2377930	0.17
455.8524475	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3145
Annotation	Unknow
Peak:m/z	Relative Intensity
241.6919250	0.04
277.3331909	0.40
413.3208618	0.04
487.8918457	0.04
502.2857056	100.00
503.2836914	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
206.6620483	0.05
209.2943268	0.14
214.1822205	0.06
221.0866699	0.07
224.1356201	0.15
233.0295715	0.20
240.911499	0.09
251.1716003	0.08
255.1580658	34.49
255.7581787	0.13
268.1746216	0.08
275.0680542	0.10
277.4299316	0.19
279.2391052	100.00
279.8647766	0.12
283.3353882	0.07
291.2232666	0.33
293.2405396	0.49
295.199646	0.08
297.2117615	0.17
307.487915	0.07
361.2215576	0.05
378.6011353	0.05
391.2557983	0.04
393.8963013	0.09
404.3505249	0.20
415.3150635	0.26
420.0337524	0.16
422.3603516	0.15
434.3058472	1.88
434.9473267	0.08
436.2019653	0.11
452.3015747	17.99
457.6951294	0.27
458.3838501	0.42
467.2663574	0.13
476.2629395	2.14
500.1293945	0.09
504.1290894	0.08
518.1587524	0.07
542.4668579	0.26
554.1137085	0.54
555.2609253	0.04
571.4695435	0.22
594.3847656	0.08
610.5377808	0.11
621.2149048	0.10
639.7319946	0.04
654.2866821	0.14
655.2202148	0.27
657.2842407	0.20
663.7573242	0.26
668.4423218	0.02
670.1702881	0.08
678.4328613	0.15
686.3937378	0.07
695.4310913	0.56
696.333252	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.5172
Annotation	PI(14:0/22:4(7Z,10Z,13Z,16Z))
Peak:m/z	Relative Intensity
240.9961548	12.85
241.8667755	1.92
243.1105957	0.95
259.0357056	0.55
259.8596191	0.47
277.3190002	0.19
279.2309265	53.32
280.2379150	40.25
281.2226257	5.14
297.0964355	12.96
298.0659485	4.70
298.8314819	0.88
315.0449219	3.11
316.0120850	0.79
415.2149658	53.20
416.1863403	37.90
417.2126465	5.23
433.2639160	3.81
434.1218262	1.98
435.3723145	0.81
490.4415894	0.19
503.2408447	0.17
521.1799316	0.24
522.1670532	0.62
535.3892212	0.22
561.4088135	0.18
577.2807617	64.56
578.2998047	100.00
579.3325195	16.44
580.2729492	0.27
595.3207397	8.69
596.3618774	16.07
597.3692017	1.31
696.1901245	1.02
798.0770874	1.29
831.5772095	0.24
840.4831543	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.2501
Annotation	Unknow
Peak:m/z	Relative Intensity
201.1251373	0.48
203.1573181	0.20
209.2779388	0.16
219.2881470	0.17
225.1701202	0.14
227.0437012	0.46
232.9287415	1.57
243.0361633	0.33
245.2685547	0.13
263.0325928	12.94
298.1653442	0.29
304.8117981	1.29
313.1962280	0.61
321.4162598	0.16
323.1136475	100.00
327.2132568	0.35
329.0756836	0.45
331.1431274	8.42
373.3002930	0.87
377.2029419	0.14
390.3384399	0.16
398.1841431	0.19
415.5161133	0.07
418.0894165	0.17
430.0324097	0.25
432.9913330	0.60
447.1787109	0.10
456.4254150	0.20
457.2374878	1.29
460.1632080	0.16
474.6716919	0.68
475.3351440	0.54
493.2500000	12.70
493.9572754	0.58
499.2761230	0.58
515.6315308	0.11
517.9914551	0.48
535.2150879	1.15
543.1312256	0.49
547.2086792	0.37
563.3369751	0.20
565.4985352	0.31
569.4725342	0.44
573.3346558	0.14
575.0433350	1.78
575.6959839	0.10
578.3322144	0.07
591.2327881	0.51
593.1783447	0.34
604.6822510	0.28
618.3020020	0.15
619.2339478	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
216.7118683	0.09
266.2684326	0.16
271.0957947	2.12
272.0860596	0.71
275.2282715	0.04
279.1695557	0.02
282.9562378	0.13
284.223999	0.04
287.7672119	0.04
289.0462036	0.05
292.1714478	0.04
295.0234375	0.21
296.131897	0.12
297.0932617	0.25
305.6134644	0.04
310.837616	0.12
312.2131958	0.06
313.1896973	3.71
314.1969604	1.15
327.0837402	0.02
330.0946045	0.02
332.3486938	0.36
337.1881104	0.60
338.1097412	0.11
367.0708618	0.44
368.0588379	0.38
371.4569702	0.03
372.8723755	0.10
379.197876	0.15
380.0578003	0.21
387.2563477	0.02
397.1660767	1.04
398.2452393	0.74
399.7633667	0.17
401.2123413	0.04
402.2597656	0.02
403.640625	0.05
409.1871338	0.09
413.2472534	0.09
415.1315918	9.30
416.0567017	4.95
417.1551514	1.08
418.0166626	0.35
419.4053955	0.06
424.3462524	0.05
425.3887329	0.04
426.9967041	0.08
430.2930298	0.17
433.1193848	100.00
434.1432495	44.46
435.1603394	0.03
438.1400757	0.03
439.0020142	0.19
441.1460571	0.44
444.8323975	0.05
449.2211914	0.02
451.2109985	0.02
453.2676392	0.03
457.208374	0.06
459.0332031	0.28
460.3232422	0.07
466.3440552	0.04
467.5824585	0.02
475.1166992	0.22
480.9802246	0.04
482.2156372	0.08
484.0186768	0.02
488.3792725	0.04
489.7694702	0.13
493.159668	0.01
494.4070435	0.05
499.3349609	0.04
500.4006958	0.14
507.3186646	0.02
511.4005127	0.05
512.9724731	0.07
514.4594116	0.02
515.2874756	0.07
518.2299194	0.07
520.3933716	0.05
525.5835571	0.06
526.2692261	0.22
531.3575439	0.02
535.71875	0.06
536.4486694	0.11
537.0662231	0.04
538.1970215	0.02
542.9440918	0.18
543.7201538	0.08
544.3526001	0.18
546.8870239	0.08
549.4006958	0.05
556.2546997	0.03
561.2384644	1.38
562.2949219	0.97
563.9597778	0.10
570.6612549	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.3755
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
197.1417847	0.05
213.2300720	0.13
217.0852966	0.10
225.0165710	0.17
235.0349426	4.77
241.0293579	0.36
244.9594727	0.15
253.1864166	2.32
256.8461304	0.06
258.8936157	0.11
262.4428711	0.13
263.0690002	0.09
269.1400452	0.10
271.1546326	0.08
279.1965332	4.77
287.1970825	3.31
294.0910034	0.34
305.0858765	4.57
313.3700562	0.18
319.2917480	0.24
323.1656799	0.81
336.8940430	0.18
361.0133667	0.11
369.3020020	0.08
379.1831665	0.26
397.1164551	100.00
405.3457031	0.16
407.0734253	0.06
415.2099609	35.19
417.0629272	0.07
452.1233521	0.26
467.4355469	0.04
481.7752075	0.03
515.0524292	0.52
529.0720215	0.07
532.1577148	0.20
546.4592285	0.06
574.4407349	0.13
613.2042847	0.12
617.4888306	0.14
618.4613037	0.10
619.4341431	0.26
630.3818359	0.22
633.5958862	0.22
640.2248535	0.56
646.8630981	0.21
658.6538696	0.28
659.4467163	0.68
660.5090942	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1409.6608
Annotation	Lablaboside E
Peak:m/z	Relative Intensity
465.1530151	0.02
483.6101074	0.04
619.5773926	0.04
763.6375732	0.03
781.4788818	0.56
823.3608398	0.06
863.4700317	0.11
889.4849854	0.04
903.1353760	0.19
903.7877197	0.03
913.4892578	0.09
925.3713379	0.12
944.9163818	0.02
957.7414551	0.11
963.3487549	0.03
985.5817871	0.12
1041.8543700	0.04
1083.3635250	0.02
1085.4094240	0.09
1119.3833010	0.09
1145.3575440	0.12
1173.7299800	0.08
1201.9930420	0.08
1203.1474610	0.30
1203.7912600	0.05
1229.4711910	0.07
1247.5090330	1.57
1248.1818850	0.01
1254.5505370	0.07
1265.5439450	100.00
1266.2724610	0.40
1271.5510250	0.10
1289.5644530	0.98
1307.4916990	77.46
1308.3764650	0.04
1311.2375490	0.04
1329.5328370	0.68
1347.6107180	38.92
1349.5333250	0.55
1350.6068120	0.10
1373.4617920	0.08
1391.2423100	0.79
1391.8964840	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	444.1069
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9863434	0.07
135.3076324	0.13
146.5643005	0.05
173.4051971	0.08
175.1717224	0.12
179.0225220	0.07
191.0142212	0.11
193.0371552	0.27
195.1654968	0.79
196.9053955	0.71
199.2571106	0.10
202.9037628	0.12
207.0708923	0.07
207.9852142	0.05
210.2300110	0.16
217.1439362	0.04
221.0503235	0.35
223.0072632	0.06
231.7860413	0.31
233.1267395	0.27
234.2890930	0.43
234.9624023	5.12
236.9429626	0.04
238.8772888	0.10
241.5242615	0.07
246.9680786	1.70
250.8824463	0.04
252.5428162	1.00
253.3190308	0.23
254.9241943	0.10
260.5516663	0.36
263.0782776	0.81
265.0392761	15.67
267.0158081	0.10
272.8762817	0.21
274.9898682	0.16
275.9486084	0.12
281.0451355	0.58
282.9933472	100.00
284.9407654	0.37
286.1021729	0.26
287.2753296	0.56
290.1394653	0.26
294.1795654	0.32
295.0938110	0.37
298.0910339	0.26
300.0692749	1.19
300.8480225	2.45
304.8920898	0.32
306.2697144	0.38
307.1361084	0.76
312.1600037	0.47
313.0555420	0.10
315.1850586	0.08
316.2478027	0.45
319.2901917	0.08
320.0910034	0.11
325.0394897	46.82
326.4575806	0.31
331.3163452	0.14
332.9741821	0.06
334.9618530	0.06
335.6004639	0.19
337.0113220	2.88
338.2626953	0.48
339.0976562	0.71
342.0430298	2.83
343.0459595	7.37
347.2543945	0.10
348.8150635	0.27
351.3724976	0.32
352.3750000	0.39
353.2700195	1.37
354.8795776	3.94
356.0598145	0.84
361.1730957	0.70
363.4389038	0.20
365.4817810	0.53
366.9529114	3.89
368.9004211	0.04
371.8085632	0.11
374.3985291	0.04
378.5493774	0.17
379.1726379	5.06
382.1408691	0.51
383.1103210	0.68
384.3306580	1.29
385.1104431	6.50
386.3705750	0.08
387.1781311	0.12
391.2909241	0.07
395.8942566	2.83
397.0590210	10.45
401.2875061	3.02
403.8420105	0.51
407.8185730	0.11
409.0481873	1.44
413.9286804	7.26
415.0368652	15.54
416.5327759	0.10
418.1087341	0.04
426.1246948	3.71
427.1673584	11.18
428.7436218	0.72
443.1214600	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0856
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
72.77079773	0.43
75.00003052	0.61
76.85823059	2.51
81.0415802	0.39
82.12434387	0.88
95.05059814	4.87
96.81832886	0.42
98.94880676	1.48
100.8844452	0.94
103.0228729	4.53
104.9312286	2.79
107.1480713	1.34
108.1395111	0.43
109.0667572	1.58
113.14534	0.45
114.9656525	0.31
117.0674133	0.35
118.6914368	0.39
121.116272	0.72
123.0254822	1.86
125.0494385	2.19
126.146637	0.51
128.9605713	10.23
130.0608368	1.24
132.9280243	2.40
134.8690033	0.26
136.9230042	0.31
138.9742279	4.22
141.1070404	2.43
146.9906311	2.27
150.8878937	99.10
151.9007416	5.68
153.1416779	0.73
153.7675629	0.80
154.8510895	1.81
156.7049866	0.40
159.0342255	0.75
161.0918884	0.45
165.0943756	2.56
166.0872955	1.45
167.1623383	1.07
169.157486	3.88
170.736084	1.15
175.2128754	4.85
176.3465729	6.14
177.2431488	1.67
179.1230316	3.53
180.0689545	1.56
181.1980743	0.49
182.0519714	0.45
183.0907135	1.05
183.8013763	0.62
184.8627167	3.81
189.0935211	1.26
192.9711151	1.94
195.0722504	3.12
197.1509857	5.44
198.0037537	2.10
199.2859802	2.98
206.8935547	3.13
209.5797882	1.16
210.9495697	8.30
217.1238251	12.40
224.0654297	0.37
225.1998138	16.08
226.1074677	2.74
230.019104	0.53
235.1504364	71.03
237.9956055	21.27
238.9267426	0.94
251.1843414	2.29
253.0779877	100.00
253.8937378	6.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.4409
Annotation	Unknow
Peak:m/z	Relative Intensity
267.1499634	0.05
279.4560547	0.25
283.4730530	0.10
286.6657410	0.05
290.1814270	0.09
297.0885315	0.24
305.1101990	0.36
318.9532471	0.18
321.3899536	0.24
322.8645325	1.01
327.3410034	0.07
337.3145142	0.17
340.9462280	1.49
365.1146240	1.59
383.1375122	6.48
391.2545776	0.12
394.9233398	0.23
397.2613525	0.78
407.1776733	0.14
413.0950928	0.16
419.1218262	0.06
422.7915039	0.09
425.1495972	1.23
431.3141479	0.22
441.0872192	0.19
442.9393311	0.89
447.1635742	0.12
449.1748047	0.25
451.2704468	0.10
454.7193604	0.07
467.0910645	3.87
483.4032593	0.05
485.1533813	2.32
502.8663330	0.26
510.5465088	0.09
517.3201904	0.14
525.4708862	0.16
526.7660522	0.08
527.4151611	0.13
535.5916748	0.11
550.2139282	0.12
553.1950073	0.19
571.5848389	0.17
585.4423828	0.03
588.3604126	0.11
595.6027222	0.07
602.6547852	0.28
603.2775269	0.15
607.3298950	0.10
619.2708130	0.12
620.2529907	0.17
621.2299805	0.04
623.4837646	0.18
629.0565796	0.14
632.0312500	0.23
632.7691040	0.08
635.4619751	0.14
639.1279297	0.24
642.4896851	0.13
645.2462769	2.98
647.1813354	100.00
649.2812500	0.06
653.4898071	0.14
665.2967529	25.56
667.4080200	0.09
681.3704834	0.35
692.4622803	0.06
695.4583740	0.12
703.4533081	0.04
711.4807739	0.06
713.6520386	0.06
725.3981934	0.54
734.6864624	0.23
737.7247925	0.26
739.2817993	0.14
740.6614380	0.10
741.5781860	0.08
744.6447144	0.27
746.6329346	0.35
747.4786377	0.26
749.4312134	0.08
751.4071655	0.38
754.4304810	0.17
755.6506958	0.59
756.5055542	0.08
765.4996338	0.04
766.5911255	0.15
767.4136353	0.05
769.3541870	1.54
779.3181763	0.26
782.6741333	0.38
783.8288574	0.09
787.9246826	0.07
791.0487671	0.05
792.3079834	0.12
793.3697510	0.08
795.4414673	0.40
796.2118530	0.06
797.2570190	0.28
799.4959106	0.03
803.6777344	0.19
807.5494995	0.13
809.4478149	0.39
811.5757446	0.11
821.1582031	0.48
821.7637939	0.08
823.5719604	0.37
827.0331421	0.07
833.5458374	0.09
839.3890381	1.35
843.2207642	0.02
847.1792603	0.05
849.5001831	0.05
851.1361084	0.10
853.5541382	0.18
854.5961914	0.06
855.3823242	0.08
858.5172729	2.65
859.6104736	0.10
862.4565430	0.24
863.5590820	0.21
865.5299072	0.28
867.0759888	0.85
868.6618042	0.23
873.4856567	0.75
874.3811035	0.27
880.3761597	1.15
881.5401611	1.87
882.6704712	0.24
890.7735596	1.07
891.4483032	5.45
892.4479370	0.10
893.5900269	0.08
908.3060913	1.54
909.5244751	7.26
910.4193726	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.07
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
85.9570541	0.26
127.9012756	100.00
128.8736877	0.05
133.9822998	1.05
152.9750824	1.93
171.0759735	2.81
178.9339447	0.32
196.8669281	1.40
215.0513458	6.85
227.0188599	2.21
245.0500336	35.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0282593	0.07
153.0058899	0.13
165.8251648	0.03
195.9862366	2.32
196.5926819	0.00
214.0176392	1.49
243.3576813	0.01
261.1478577	0.10
279.2080994	100.00
324.9505615	0.04
415.1975708	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1089.4973
Annotation	Unknow
Peak:m/z	Relative Intensity
321.0573120	0.03
323.1181030	0.42
324.1784973	0.02
340.9424133	0.82
342.0072021	0.08
365.0535889	0.52
377.3350830	0.02
379.2725525	0.11
380.2127686	0.10
383.2385559	2.82
384.0458984	0.15
390.7520752	0.02
392.4996033	0.01
394.8921814	0.06
412.6280518	0.23
413.2494507	0.01
425.0310974	0.08
431.4913330	0.05
436.9960632	0.03
440.0990906	0.14
441.0391541	0.04
442.7802429	1.37
444.0854492	0.19
449.2156677	0.46
450.3272400	0.05
465.2518616	0.05
467.2375183	0.66
468.0567932	0.02
471.0635681	0.02
479.1372986	0.02
483.0503235	0.10
485.0149536	2.03
486.0269775	0.28
491.1914673	0.03
495.4069824	0.04
497.3438110	0.08
503.0788879	2.51
504.1219482	0.03
508.9989929	0.12
527.2183228	3.45
528.1990967	0.19
533.2462158	0.02
541.0899658	0.07
545.2051392	6.03
546.3594971	0.82
549.6345215	0.06
550.9482422	0.13
557.0239258	0.11
559.1747437	1.52
560.3560791	0.18
568.9770508	0.45
569.7520752	0.02
571.2299805	0.29
574.9584961	0.22
587.0290527	1.07
587.9157715	0.11
599.3973389	0.01
602.9156494	0.53
603.5163574	0.04
604.9462891	0.33
611.2159424	0.66
616.8779297	0.06
629.1890869	1.22
630.2889404	0.31
636.1635742	0.04
640.9824219	0.11
645.1870117	0.94
646.0957031	0.25
647.1557617	1.17
648.3602905	0.19
653.3707275	0.06
659.5233765	0.03
665.2983398	0.72
670.9750366	0.02
683.4479980	0.03
689.2384033	1.00
690.2850342	0.18
695.1379395	0.04
701.3479004	0.03
704.4733276	0.47
705.3323975	0.24
707.2278442	0.02
708.2200928	0.02
717.3326416	0.07
747.1595459	0.22
753.5401611	0.06
763.9654541	0.04
765.0330200	0.42
773.2536621	0.07
774.2952881	0.02
778.8771973	0.07
790.9568481	0.10
807.1948242	3.42
809.1806641	100.00
810.2569580	12.90
827.2086182	30.77
828.3084717	3.93
849.6062012	0.20
866.3522949	0.02
889.6735840	0.02
891.2685547	0.07
892.1480713	0.02
909.5067139	0.10
910.3758545	0.03
952.1984863	0.04
967.6361084	0.01
969.3784180	0.22
991.7680664	0.07
994.5764160	0.07
1029.6174320	0.03
1030.3759770	0.02
1071.2462160	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.2114
Annotation	Unknow
Peak:m/z	Relative Intensity
100.9090958	0.09
107.0612946	0.14
110.8932037	0.64
115.9775848	0.15
119.0373154	0.57
121.0944748	0.39
122.2178802	0.20
126.5541077	0.13
127.8809509	0.16
129.1708527	0.05
131.0653534	1.58
132.0110931	10.43
132.9970703	0.17
134.7361755	0.09
137.2163391	0.28
137.8855591	0.04
145.0722351	0.40
148.9467773	2.19
150.1816711	0.15
154.3290710	0.07
155.9939880	0.79
158.1351624	0.07
162.9915161	1.15
163.7433472	0.31
164.8902588	0.13
167.0566864	40.52
173.0914917	0.44
179.1447754	0.15
181.0240784	0.46
184.9610596	0.05
186.8587341	0.27
189.2374115	0.14
191.0813904	11.59
192.2558136	0.16
192.9502563	0.14
196.0685730	3.65
199.0296631	0.17
202.1493835	0.20
209.0368652	95.49
210.1022949	3.11
214.2012939	0.29
216.3008728	0.05
217.1549377	0.09
224.1859131	0.15
226.9832153	0.80
228.1739197	0.05
234.3384705	0.19
238.0103760	7.19
244.0007935	0.15
245.1562805	0.31
246.0951538	0.19
249.3713989	0.16
252.0750732	2.87
252.8347473	0.04
254.3671265	0.14
256.1019897	15.79
258.4043579	0.55
259.8356018	0.36
263.3837280	0.05
265.1649475	0.04
267.1199036	0.30
270.1441040	0.10
273.0326538	0.04
276.1747437	25.81
277.9757385	0.07
280.2281494	0.08
281.1797180	0.05
283.0339050	0.07
284.1430664	0.13
287.0999756	0.50
290.5278320	0.05
294.1885986	17.08
294.8621216	0.16
296.2536621	0.23
297.0521851	0.60
299.0077515	0.68
300.3701477	0.18
302.3677979	0.06
304.1316528	34.24
310.1200562	4.14
311.0747070	0.06
312.1932373	0.68
312.9495239	0.14
316.8913269	0.40
318.8411865	1.08
319.6009827	0.34
322.0807800	100.00
323.0050049	0.60
325.0513306	0.20
326.3799133	0.19
328.1006165	0.30
331.0576477	1.59
331.6945801	0.29
340.4671326	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1642
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
177.3270264	0.06
194.9699097	0.03
211.4426270	0.02
229.0735779	0.01
235.2552795	0.04
242.9751892	0.05
243.9756927	0.06
249.2199097	0.02
255.9183197	0.03
264.9232788	0.01
268.0481567	0.01
271.0574951	1.54
272.1777954	0.28
283.0679321	4.06
284.0435791	1.13
284.9636230	0.06
295.0537720	10.31
296.0535278	3.49
307.0328979	0.43
307.9590759	0.14
309.2917480	0.20
310.2769165	0.15
311.1420898	0.53
313.0623169	63.49
314.1137085	14.60
314.9489441	0.08
322.8988647	0.13
324.9245605	0.04
330.1461792	0.01
334.3244629	0.05
335.6149292	0.04
337.1246338	11.02
338.1900024	3.17
343.2081909	0.25
344.0842896	0.12
348.5418091	0.06
349.1459351	1.20
350.2083130	0.66
351.1036377	0.21
352.3756104	0.10
355.2501221	0.22
356.1198120	0.04
361.2118530	0.41
362.4287109	0.04
367.0792847	21.34
368.1356812	6.13
373.2843628	0.02
373.9623413	0.07
379.1557617	7.09
380.1058960	1.88
381.1229248	0.06
389.2813721	0.23
390.3166504	0.05
394.8588867	0.05
397.1238403	24.18
398.0952148	5.94
399.3710327	0.11
400.0769043	0.04
404.1685181	0.05
409.0230103	0.04
413.2456055	0.10
415.1130981	100.00
416.1188965	28.37
417.3796997	0.15
418.1842041	0.09
420.8610229	0.03
426.9330444	0.03
431.3157349	0.03
433.1096191	49.35
434.1152344	15.20
434.7644653	0.07
440.3031616	0.02
443.5227661	0.02
445.3503418	0.02
449.1294556	0.37
450.0868530	0.11
455.6279907	0.03
457.1060791	0.18
463.4629517	0.04
475.1433105	0.20
476.3052368	0.01
478.9494629	0.04
481.0916748	0.17
482.4874268	0.03
493.3043823	0.03
494.3684692	0.01
496.4456787	0.07
498.4669189	0.02
499.1974487	0.39
500.1670532	0.07
507.1287231	0.08
508.4250488	0.04
509.3598022	0.02
511.0892334	0.03
512.3730469	0.04
517.0919800	0.02
522.2448120	0.06
523.2153931	0.15
524.3684082	0.13
534.2427368	0.08
537.0083008	0.06
541.2036743	0.21
550.1809692	0.02
551.3700562	0.54
552.2991333	0.04
559.0842896	0.74
560.2700806	0.62
568.5083618	0.02
577.1356812	21.49
578.2225952	10.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1177
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
156.0204010	0.02
157.9073486	0.02
165.1253967	0.01
172.2418213	0.02
175.2086792	0.01
178.9167023	0.03
184.0354004	0.01
188.9840088	0.02
192.9639893	0.02
202.8850403	0.01
208.9025574	0.03
210.2596436	0.04
212.0092621	0.02
238.9909973	0.02
253.0957336	0.05
256.1619263	0.06
257.0079346	0.06
263.5098267	0.08
269.0142517	0.03
271.1393738	0.07
274.0895081	0.39
277.4308167	0.02
281.1253662	0.04
282.9246216	0.05
287.2151489	0.20
296.9807129	0.25
298.9306030	0.04
303.0952759	0.09
305.0404663	0.38
309.4414368	0.05
311.1503296	0.39
315.2174377	0.20
316.2500305	0.01
317.2622070	0.11
318.9481506	0.15
320.1742859	0.07
321.0002441	0.01
329.1948547	1.36
332.1524353	0.01
336.1473999	0.02
338.0575256	0.40
345.2421265	0.06
347.0593872	2.61
353.1834717	0.64
371.2030945	0.30
383.0945435	0.31
385.2228699	0.12
395.1519775	0.32
400.9693298	0.06
403.2377319	0.96
404.1292725	0.02
405.5262451	0.01
407.1880798	0.03
412.9740906	1.77
418.8092346	0.02
421.2968140	0.02
422.2699890	0.11
431.1629333	14.52
435.1442871	0.04
446.4641418	0.05
449.0775452	100.00
449.6960754	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.2665
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
221.0395508	0.03
259.1853027	0.03
286.0474854	0.05
320.1748657	0.05
363.0202026	0.02
366.2141724	0.02
371.4407349	0.05
374.1408081	0.16
380.4215088	0.04
396.3776855	0.05
398.2436523	0.51
398.9871826	0.07
409.5759888	0.03
414.1452026	0.16
430.4219360	0.13
435.2907104	0.03
437.8625488	0.07
442.1223145	1.63
443.2136841	0.83
444.2349854	0.49
445.4852295	0.23
447.3693237	0.04
448.2032471	0.12
450.4164429	0.04
460.4072876	0.03
462.0643311	0.19
463.3336182	0.08
467.4331665	0.03
474.2092896	3.36
475.2918701	1.54
476.3142090	0.38
477.1541748	0.10
478.4619141	0.08
479.3032837	0.04
486.1550293	0.27
487.2947388	0.71
488.1022339	0.80
489.2695312	0.07
495.5664673	0.04
507.5739746	0.09
511.2128906	0.16
512.2919922	0.17
513.3407593	0.12
513.9998169	0.23
518.3027954	1.74
519.3572388	1.12
520.2462769	1.71
521.3202515	0.66
525.8087769	0.04
528.5149536	0.03
529.3168335	0.02
539.3433838	2.64
540.3394165	1.78
545.3754883	0.03
550.1567993	0.02
554.1416626	0.03
556.3540649	0.06
558.0494385	0.01
559.3234253	0.11
564.3871460	0.02
565.4929810	0.03
569.0995483	0.03
571.3164673	5.30
572.3724976	2.81
580.4400024	0.07
581.3004761	0.79
582.2555542	0.46
583.3148804	4.92
584.3632812	3.04
589.8969116	0.02
596.2891846	0.07
599.2911377	4.27
600.3554077	2.57
601.2258911	0.02
603.5231323	0.12
604.3286133	0.08
613.1965332	1.64
614.4701538	1.94
615.2920532	12.53
616.2611694	8.10
625.2456665	1.87
626.3874512	1.26
629.3226929	0.05
630.1895142	0.10
631.2401123	7.62
632.2509155	6.59
632.8798828	0.10
643.2691040	100.00
644.2228394	71.60
644.8411255	0.27
645.5714722	0.09
647.4509888	0.08
648.3426514	0.11
652.4122925	0.03
653.1409302	0.10
654.5430298	0.02
657.1895142	3.70
658.1760864	3.32
658.7785645	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.13
Annotation	Phloridzin
Peak:m/z	Relative Intensity
143.2349243	0.04
149.1558838	0.21
166.9788513	1.18
206.1577454	0.10
211.2657928	0.16
213.3205261	0.12
214.5086212	0.08
229.1949158	0.13
231.0601501	0.49
245.3654785	0.14
249.0282288	1.68
253.1430969	0.14
254.2616272	0.26
255.2073364	0.34
267.2005005	0.43
269.0921631	0.16
271.0569153	1.81
272.1379395	5.22
273.0737	100.00
273.6765747	0.18
275.2922058	0.04
287.0462646	0.11
289.2990112	0.16
295.8843689	0.12
297.0015564	1.34
305.2741089	0.34
307.1796265	0.06
308.9047241	0.69
311.0730896	0.39
312.100647	0.80
313.1429443	0.78
314.4623718	0.93
315.142334	2.21
326.1044617	0.09
326.8919373	0.06
327.5264282	0.19
333.1279907	0.23
340.6407471	0.18
342.1235657	0.31
343.0270996	0.14
345.0449829	10.16
347.0909424	0.09
355.3157043	0.04
357.0780029	0.08
361.0335999	0.17
369.3902283	0.18
372.1286316	0.47
388.177124	0.11
389.2339172	0.15
389.9864807	0.17
390.9433289	0.30
397.1201172	0.19
399.1488342	0.36
417.2606201	9.71
417.9746094	0.11
419.5645447	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	831.2681
Annotation	Premnoside D
Peak:m/z	Relative Intensity
232.9852142	0.13
250.2787170	0.39
251.0123749	0.91
263.1843567	0.97
269.1070862	0.49
278.9667969	0.15
279.9754028	0.87
281.0864258	13.37
292.1521301	0.10
299.0625916	0.34
322.7683716	0.91
335.8324890	0.28
337.1466064	0.23
340.8062744	2.07
351.9595337	0.28
352.9943848	0.57
354.2432861	0.10
358.1662598	0.55
364.2025757	0.31
365.2289124	0.37
377.0396729	1.10
381.9377441	0.15
383.0577087	0.45
387.2219849	0.06
395.3606567	0.33
397.1902466	0.11
412.3605347	0.99
412.9642944	0.07
425.2373657	0.38
434.4535522	0.18
442.1802368	14.34
443.0968018	100.00
444.0639038	0.38
477.3134155	0.18
502.7803955	0.13
506.0127563	1.33
507.2009277	1.35
532.5328979	0.13
582.5822144	0.22
600.8031616	0.21
604.1231079	1.44
605.1237183	1.76
633.0590820	0.23
650.4247437	0.32
668.1450806	1.66
668.9047852	3.99
669.5433960	0.11
670.1876221	0.17
680.6360474	0.05
707.6558228	0.36
747.0372314	0.47
749.3784790	0.09
772.1465454	0.35
795.5355835	0.21
812.6741943	0.20
813.3054810	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.189
Annotation	Bis-gamma-glutamylcysteinylbis-beta-alanine
Peak:m/z	Relative Intensity
191.0574341	0.27
203.9659119	0.29
223.0366974	0.17
224.6593323	0.26
231.0787811	0.30
249.1215515	0.07
270.1563721	0.16
287.0124817	0.05
287.8754883	0.15
302.2467651	0.40
354.1516113	0.29
376.2122803	0.03
383.0729370	88.38
383.7608643	0.62
423.1999512	2.78
447.4155884	0.09
449.5645752	0.19
461.0676270	0.21
466.4495850	0.08
494.1911011	5.27
505.2634277	0.19
509.8893433	0.09
512.1885376	100.00
523.1326904	0.06
534.0496826	0.30
547.8389282	0.03
552.2370605	1.59
553.7247925	0.07
557.3678589	0.06
586.4658813	0.36
593.1785278	0.04
604.7318115	0.38
605.4221191	0.09
623.1900635	16.52
623.8539429	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.543
Annotation	Hoodigoside O
Peak:m/z	Relative Intensity
294.9433899	0.56
295.5993958	0.18
307.1392822	0.37
308.0565491	0.16
353.5295715	0.18
359.3882446	0.15
367.1561279	0.05
379.3700562	0.34
380.5869141	0.41
389.1087952	0.53
390.2764893	0.16
391.2542725	0.50
401.4214478	0.52
403.4797668	0.15
405.5626831	0.26
406.5336304	0.39
407.2982178	0.85
409.3722229	1.11
417.3291626	0.50
420.2638550	0.13
421.3739624	0.60
423.0141602	0.13
424.2229919	0.40
425.1085815	0.45
426.4063721	0.79
427.7561951	0.13
434.9146729	0.22
437.1366272	0.27
439.3086853	4.78
440.2864990	0.27
443.5791321	0.15
452.5563660	0.10
455.2828674	1.34
457.5443115	1.38
458.5855103	0.82
463.5629578	0.50
465.2850952	0.68
466.2245789	0.50
483.2263794	0.90
484.0632019	0.39
506.5300598	0.17
511.5999756	0.52
521.3818970	0.28
523.6096191	0.15
525.5881348	0.18
535.0235596	0.09
537.4959717	0.49
539.5717773	0.12
541.3758545	19.05
542.5314331	5.10
551.2059326	0.38
551.8247070	0.51
554.2419434	0.17
555.6002197	0.15
557.4678955	2.22
559.3456421	13.14
560.4967651	3.34
562.7467041	0.38
566.3091431	0.10
569.3580933	0.20
571.3121948	0.93
572.5050049	1.13
582.3895874	0.38
597.6140747	0.57
598.3995361	0.18
599.3375244	0.51
602.0256348	0.15
613.4935303	0.17
615.4906006	5.18
616.5560913	2.12
617.8018799	0.23
627.4769897	10.56
628.4451904	3.42
629.4525146	1.06
632.7802734	0.10
637.7660522	0.50
641.3374023	3.59
641.9451294	0.48
642.5983276	1.65
655.6062622	0.75
656.6295166	0.35
673.3853760	9.69
674.4259033	5.70
675.8045044	0.15
681.4046021	0.08
691.4553223	1.83
692.5318604	1.23
699.2854004	10.09
700.4017944	4.12
715.4577637	0.25
717.4547119	47.32
718.5041504	18.54
719.1477051	0.14
727.3703613	0.09
733.3058472	0.45
735.1068726	0.59
735.7727661	0.30
736.6052246	0.64
751.3815308	0.26
752.6488037	0.12
759.6838379	0.36
761.6296387	0.16
778.2888794	0.30
778.9165039	0.50
787.3870850	0.35
800.5334473	0.06
817.3884277	3.41
818.4741211	2.18
822.6168213	0.25
830.3499756	0.11
835.4371338	31.79
836.5424805	17.30
853.3778076	4.76
854.4650879	2.21
862.4827881	0.10
877.0343018	0.39
879.4840088	3.90
880.4160156	2.17
897.4100342	4.17
898.5146484	1.83
905.6257324	0.94
906.4609375	0.22
909.4553223	0.12
930.6848145	0.42
941.5002441	13.81
942.4060059	7.02
943.0289307	0.46
949.4724121	0.48
950.5141602	0.64
954.7100830	0.18
967.5017090	70.03
968.4645996	41.44
969.0959473	0.17
981.4641113	100.00
982.5007324	62.77
983.3947754	0.39
999.4101562	7.58
1000.4881590	3.60
1025.3713380	44.70
1026.3724370	22.73
1026.9836430	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.2233
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9218292	0.39
179.2577972	0.07
180.6965179	0.96
186.6328278	0.07
194.8143311	0.76
198.8263092	0.05
211.1379089	0.15
228.9159393	0.08
241.0840759	0.25
252.1114197	1.07
252.8228912	0.23
258.8231812	0.37
270.8799438	3.42
278.6436157	0.07
287.3135376	0.09
288.1497192	0.67
288.8678589	7.03
303.1948242	0.04
306.6115417	8.88
307.3426514	0.06
321.1972046	0.09
323.0266724	0.73
324.7847290	100.00
325.5336304	0.59
329.9220581	0.27
331.0073242	0.10
337.2915649	0.17
338.7708130	0.39
339.9749146	0.12
342.3267822	30.81
342.9783325	67.12
356.8045044	4.95
357.5142822	0.10
385.1432495	0.19
414.1336670	0.18
420.4266357	0.12
421.4114380	0.27
432.0584717	8.24
433.0361938	0.61
438.7387085	0.05
451.0682983	2.05
468.9266357	0.42
486.8212891	10.27
503.5930786	1.19
504.8076782	4.04
518.7726440	8.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.5073
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
241.3482971	0.09
243.1089172	0.12
255.2475739	39.04
256.3908997	0.16
261.2929077	0.24
265.2206421	0.07
270.1691895	0.13
277.2532349	0.38
279.2387695	100.00
279.9981384	0.71
283.3156738	0.08
284.1549072	0.16
293.2885132	0.97
296.9842224	0.07
306.9547729	0.08
309.1133118	0.09
311.3635864	0.11
327.7049561	0.27
374.1694946	0.15
376.2781372	0.35
390.4764404	0.32
397.2130127	0.33
398.0001831	0.16
399.1289062	0.11
400.3613281	0.12
402.1380615	0.08
405.4465332	0.07
419.4088135	0.13
429.0467529	0.11
434.3221436	1.93
435.1015015	0.34
444.05896	0.07
452.3168945	17.85
458.3455811	1.91
470.1315918	0.19
475.0307007	0.17
476.305603	2.21
480.4754028	0.09
485.2757568	0.13
506.3170166	0.09
517.9743652	0.17
542.3129883	0.09
553.4685669	0.69
556.3515015	0.09
560.491394	0.04
572.4246216	0.10
614.2747192	0.12
621.7055664	0.08
639.7996216	1.22
640.7372437	0.26
642.3497925	0.13
642.9754028	0.17
650.3049927	0.21
655.1307983	0.05
667.1494751	0.14
667.7666626	0.15
670.4524536	0.11
671.4876099	0.14
676.2544556	0.07
678.4385376	0.14
695.3024292	0.80
696.357666	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1037.3412
Annotation	Unknow
Peak:m/z	Relative Intensity
341.0473022	0.18
383.1380005	0.66
442.6075439	0.06
502.9830322	1.15
545.3910522	0.70
574.8074951	0.41
604.8024292	0.77
647.2140503	0.67
665.0516357	1.07
827.2197266	100.00
827.8586426	0.56
829.4188232	0.07
993.3374023	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.07
Annotation	Wairol
Peak:m/z	Relative Intensity
92.5567856	0.03
108.8818436	0.03
119.1842346	0.03
121.0246277	1.12
122.5064240	0.10
130.9967499	0.05
133.1080017	0.36
135.1593628	0.04
144.9191284	0.83
147.1333923	0.06
148.9709930	1.17
149.9739685	0.09
153.0996552	0.05
162.7886658	0.08
167.0161743	0.22
171.1474762	0.05
172.9090271	0.10
175.0208435	0.29
176.9963989	2.44
180.8957062	0.21
182.8448486	0.10
194.9353943	1.72
195.7915802	0.04
197.2070923	0.28
198.0924377	0.19
201.0335999	0.04
202.0148621	0.07
203.0337219	0.16
211.1824341	0.24
214.9552612	0.13
221.1413574	0.09
223.3252258	0.07
224.9328918	0.12
226.9730530	0.33
229.1040344	1.99
239.0927124	4.11
240.0226135	0.51
241.1158752	0.28
242.6460266	0.04
243.2734985	0.04
249.0597229	0.03
251.1643372	0.53
253.1079712	0.21
254.7753296	0.05
256.9197998	0.08
267.0464478	85.53
268.1431885	9.65
269.1002197	0.68
270.0208130	5.83
271.0745850	0.44
276.9152222	0.40
283.0989380	8.30
284.0473633	17.04
285.1026001	4.75
286.0692139	0.25
295.0700989	100.00
296.0700073	13.94
296.8430786	0.01
311.0987244	0.15
313.0921021	9.74
314.2496033	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	516.1964
Annotation	Unknow
Peak:m/z	Relative Intensity
144.0988464	0.05
145.9867096	2.79
149.8481598	0.81
159.1705475	0.04
170.0477905	1.07
187.9526062	37.72
193.0692139	0.21
204.9577179	100.00
206.1686401	0.02
206.7861938	0.02
221.2450867	0.02
283.2196655	0.04
288.2004089	0.03
294.1844788	0.02
300.0653687	0.09
311.1284790	0.20
311.9151001	1.06
314.4443970	0.03
317.9538574	0.03
322.2044678	0.18
328.1685181	0.02
336.5605469	0.05
341.9093018	0.05
354.2130127	0.39
369.2291870	0.03
370.1442261	0.05
372.2568970	0.02
376.3347778	0.03
378.0476685	0.02
378.8722534	0.08
387.1494141	0.04
393.3164062	0.05
396.3076172	0.05
401.0418091	0.17
403.2561035	0.03
416.4708252	0.10
434.6603394	0.17
442.3219604	0.05
443.2912598	0.03
456.3144531	0.07
471.1583252	0.03
472.5283203	0.12
475.0598145	0.05
480.4281616	0.09
497.1012573	0.06
498.0912476	0.27
499.1880493	0.07
506.9373169	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.102
Annotation	3,5-Dihydroxyphenyl 1-O-(6-O-galloyl-beta-D-glucopyranoside)
Peak:m/z	Relative Intensity
126.9277802	0.26
132.9238129	2.02
133.8199310	0.02
137.0010529	0.15
138.8888245	0.09
144.8721008	0.13
149.0118561	0.25
149.9045715	0.05
154.7177734	0.04
160.9627075	0.03
165.0470886	0.61
169.3236389	0.01
172.0308990	0.01
178.0048828	0.93
182.7804871	0.15
183.7553711	0.03
192.9394836	100.00
212.8630219	0.40
215.9322510	0.01
218.0895996	0.03
230.9261780	2.20
234.9487000	0.02
249.0802307	0.01
258.2662659	0.02
265.3883972	0.02
266.1014099	0.01
269.2380981	0.14
274.8907776	0.02
278.0672607	0.03
278.9725647	0.07
280.0292969	0.05
282.4641113	0.04
287.0666809	0.01
298.0183105	0.06
299.2987061	0.02
301.0493469	0.02
307.1372681	0.03
309.2469788	0.02
320.9253540	0.06
325.2860107	0.02
332.9893188	0.04
335.1767578	0.01
337.2572632	0.04
341.2127686	0.08
342.4275513	0.02
354.7636108	0.04
359.5802917	0.02
363.0654602	0.03
367.8929749	0.03
371.2615662	0.06
377.3031006	0.01
378.2682190	0.01
379.9038696	0.20
380.7635498	0.23
381.3715515	0.05
382.1482849	0.01
383.2753601	0.02
394.3871155	0.03
395.0527039	0.13
397.5530090	0.07
399.9519958	0.07
405.2222900	0.04
407.2317200	0.05
410.0385437	0.03
422.3719788	0.30
423.1287231	0.36
424.1469421	0.12
431.2084045	0.04
432.3172913	0.05
441.3139343	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.0693
Annotation	dGMP
Peak:m/z	Relative Intensity
109.0473175	0.02
118.9484711	4.34
135.9264984	100.00
137.1077576	0.01
147.9145355	0.03
186.0265045	0.29
201.1113739	0.09
216.1370239	0.30
218.2718201	0.02
232.2332458	0.04
235.6950684	0.20
250.0572205	0.32
258.2090454	0.21
267.1913452	0.24
269.0251770	0.03
276.2097778	0.10
280.2168579	0.05
281.7579346	0.03
285.6761169	0.08
288.1162109	0.33
289.5125122	0.05
291.0311279	0.15
294.0379028	0.06
302.1018677	0.08
304.1265259	0.07
305.0988770	0.07
306.9240723	0.14
311.3954468	0.04
329.2512207	0.03
330.0524902	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	564.1704
Annotation	Unknow
Peak:m/z	Relative Intensity
174.0702820	0.05
186.0279083	0.11
188.2494202	0.02
190.2139587	0.04
194.3314972	0.06
205.1207886	0.11
211.0744019	0.04
214.9848022	0.03
222.2095642	0.03
247.2395935	0.03
255.4988098	0.02
266.2075500	0.20
279.1908875	0.09
291.1027832	0.04
302.2395020	0.16
303.3500977	0.05
304.3414917	0.02
308.0966797	0.03
313.4282837	0.02
314.2416382	0.04
314.9873047	0.06
322.2861938	0.18
345.1789551	0.07
348.2996826	0.05
353.3856812	0.10
354.4963989	0.20
356.9215698	0.04
359.2119141	0.06
361.1381226	0.23
375.2126465	0.07
381.0130615	0.07
384.1813965	0.44
391.1086426	0.05
396.2223511	0.11
402.2232056	0.06
403.1116333	0.04
404.2589111	0.02
405.2324829	0.23
406.0842896	0.08
410.1975708	0.42
411.2474976	0.13
414.2489014	0.05
415.0268555	0.13
417.5833130	0.11
418.1983643	0.10
423.3392944	0.09
426.2454224	0.75
427.1965942	0.06
428.2556763	0.15
430.2928467	0.03
433.1958008	0.08
435.4950562	0.21
436.4243164	0.03
443.3268433	0.25
444.2991943	2.21
448.3683472	0.04
450.2478027	0.96
456.4506836	0.04
466.4570923	0.03
468.2352905	0.96
475.1222534	0.06
480.1182251	0.68
492.0906372	0.13
498.3676758	0.03
510.2371216	1.42
514.0650635	0.10
515.3616333	0.09
516.1350708	0.06
518.5217896	0.04
522.8967285	0.14
525.7579956	0.11
528.1636353	11.24
528.8704834	0.08
535.2860107	0.05
543.9522095	0.20
546.1558838	100.00
547.0110474	0.03
553.4809570	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
112.9770508	0.01
124.9175186	0.03
130.6381378	0.05
143.2765961	0.03
160.9939270	0.01
178.9182434	0.67
197.0665283	0.53
214.9927368	8.29
280.7532349	0.21
341.0982361	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.2772
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
163.2753601	0.31
164.0854034	0.17
165.1915588	0.19
169.0935974	0.62
171.1918182	0.21
172.9665833	1.01
175.1702576	0.19
176.8477478	0.41
184.1657562	0.10
185.1441498	0.56
187.1114502	1.64
189.3328247	0.18
190.9920654	0.42
195.1488495	0.10
197.2617950	0.16
199.0168152	0.38
201.0246124	0.87
205.0985413	0.12
206.9750671	0.09
208.8656006	0.14
210.8884125	0.09
213.2978210	0.14
213.9322357	0.08
221.2355652	0.14
225.2419891	0.66
227.1050110	0.26
231.1474152	0.11
236.8477173	0.33
239.0492859	0.13
241.1944122	0.16
242.6515350	0.63
243.2757263	12.83
245.2376556	0.13
247.2524261	0.07
251.0603027	0.09
251.9891052	0.25
252.9466248	0.07
257.2533569	0.50
258.9064941	0.27
261.2612000	10.82
265.2642517	0.03
271.2392578	0.07
273.0820312	0.14
275.2613220	0.41
277.3532715	1.08
279.3486633	0.69
280.4077454	0.09
281.1439819	1.27
289.1345825	0.02
291.2432861	0.49
293.1542358	0.21
299.0969238	3.49
300.3718872	0.21
305.4867554	0.18
306.8083801	0.03
315.1678467	0.27
317.2607422	19.10
319.1750488	0.06
321.0492554	0.13
330.4608154	0.06
332.9378662	0.14
335.2235718	100.00
335.8550415	0.40
337.0697632	0.67
341.7435913	0.44
351.2308960	0.39
353.2471313	1.04
355.1550903	0.03
359.2988281	0.39
363.3453979	0.20
365.8936768	0.08
367.2575073	0.14
369.4652100	0.41
376.0651855	0.04
377.1567383	0.04
392.1260986	0.05
396.9781494	0.25
403.8272705	0.34
405.3054810	0.49
415.2575073	10.98
416.3952026	0.13
417.1373901	0.23
419.2043457	0.21
422.1699829	0.11
423.3246460	3.79
432.8380127	0.20
437.1417236	0.26
441.4903564	0.09
443.8516235	0.08
448.8726196	0.29
450.9927979	0.40
453.4298096	0.25
454.8460083	0.31
465.2611084	0.13
469.2744751	0.38
479.0902100	0.11
480.8393555	0.55
495.0502930	0.31
496.0764771	0.10
502.1710815	0.20
503.4663696	0.66
505.3210449	0.37
512.1305542	0.14
517.3923950	0.06
520.3456421	0.23
521.1668091	0.04
523.4033813	0.02
524.2616577	0.25
527.3552246	0.04
528.5006104	0.19
531.0678711	0.17
533.4916382	0.12
535.4819946	0.08
536.4369507	0.12
541.1666870	0.50
542.5591431	0.08
554.4197998	0.05
559.2163696	62.54
559.9982300	0.17
567.5646362	0.37
577.3190308	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.27
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
150.8142395	0.02
152.8934937	2.55
171.0099182	0.09
239.3454590	0.13
243.2491760	0.07
250.7960815	0.03
258.1256104	0.02
279.4557190	0.07
281.8931885	0.05
293.4086914	0.13
294.3869629	0.05
295.3756104	0.24
307.0043335	0.09
311.5606689	0.02
322.2588501	0.03
322.9846802	0.04
384.4524536	0.27
415.2691650	1.80
418.2734985	0.04
433.2022095	100.00
433.8426514	0.33
439.1881104	0.19
445.6290283	0.16
446.5088501	0.11
448.3893433	0.12
453.1120605	0.05
457.2904053	0.24
459.3207397	0.04
474.0771484	0.08
476.5234375	0.11
492.6030884	0.13
501.3142090	0.31
502.2936401	0.29
503.6472778	0.02
519.4104004	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2921
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
137.0875092	0.02
172.9645386	0.03
198.1201782	0.10
216.2286377	0.02
221.3270874	0.03
227.1994629	0.01
238.6694946	0.02
282.4723511	0.15
300.4319763	0.09
313.2156982	100.00
313.8548279	0.32
356.1385498	0.08
363.6819458	0.06
364.8364868	0.02
366.5817261	0.02
392.8279724	0.03
407.8737488	0.03
409.0690918	0.04
422.9989624	0.01
436.1768494	4.41
450.6466370	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	578.1866
Annotation	Unknow
Peak:m/z	Relative Intensity
189.9754333	0.06
195.0264130	0.22
200.6122437	0.02
225.2281799	0.11
246.1788940	0.05
271.3757019	0.09
272.1738281	0.06
294.8931274	0.06
323.1742554	0.05
325.3223877	0.20
326.0938721	0.04
354.1878662	0.17
366.1018677	0.02
368.0881348	0.02
378.2704468	0.11
379.1868896	0.08
389.3788452	0.08
391.5871582	0.03
396.5339355	0.16
397.8436279	0.38
398.5657959	0.12
403.3312378	0.09
410.0325317	0.12
414.0933228	0.06
416.0495605	0.50
420.1864014	0.14
423.9703369	0.47
426.3841553	0.05
433.2720337	0.25
434.2419434	0.03
439.1727905	0.10
440.1740112	0.45
441.5496216	0.11
442.2813110	0.11
444.6112061	0.26
445.2752075	0.09
447.8037720	0.03
449.4169922	0.07
450.2343140	0.35
458.1953735	2.13
459.2024536	0.05
462.1915894	1.74
463.0921021	2.09
464.3033447	0.94
470.1375732	0.03
470.7992554	0.03
474.2872314	0.08
476.1004639	0.09
480.0559082	0.75
481.2366943	1.37
482.1649780	0.82
488.4578857	0.04
494.1109009	0.78
498.2019043	8.45
499.1940308	0.09
500.5486450	0.03
503.8413086	0.04
506.1285400	0.01
512.2634888	0.11
516.2593384	0.55
522.9215088	0.04
524.1954956	0.81
529.1156006	0.10
531.8917236	0.13
533.4247437	0.05
536.4779663	0.14
542.1964722	15.06
542.8468628	0.04
544.8343506	0.05
548.2252197	0.01
560.1860352	100.00
561.1299438	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.1299
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
87.0632324	0.07
98.9098816	0.03
101.1416321	0.04
109.0871277	0.05
110.8134308	0.12
124.7971191	0.13
127.9320526	100.00
129.9729462	1.06
136.9800873	0.12
153.0288239	0.03
157.0131073	0.19
158.8051605	0.04
172.8898468	0.05
174.7591400	0.04
183.1247711	0.03
197.3148041	0.14
198.9446564	0.14
201.9861145	0.06
213.0836182	0.85
215.0397797	0.53
223.1060944	4.03
228.9842987	0.36
230.8244781	0.06
241.0773926	64.81
241.6966705	0.28
244.1750946	0.04
247.1254120	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	907.5754
Annotation	Unknow
Peak:m/z	Relative Intensity
257.2532959	0.05
274.4871521	0.30
282.3707275	0.49
283.7293701	0.18
313.2240906	56.36
314.2591248	7.17
366.3400879	0.07
433.3687134	0.10
436.2085571	1.66
437.0841064	0.15
454.0646973	100.00
455.1858521	11.76
481.9946289	0.07
484.3464966	0.22
491.3951416	0.51
497.2362061	0.14
500.2496338	0.13
517.4509277	0.87
518.4406128	0.29
528.3561401	0.13
534.8333740	0.22
537.4161987	0.17
540.7047729	0.14
545.2583008	0.05
546.4159546	0.13
548.3688965	0.49
554.0950928	0.15
556.1641235	0.18
564.1704102	0.40
566.4923706	0.18
575.4046021	0.30
580.5326538	0.19
588.5947266	0.10
595.2727661	0.27
597.1203003	0.06
604.3474121	0.07
618.2963867	0.60
624.5787964	0.17
629.4802856	0.38
632.0786743	0.21
632.8731079	0.21
636.5867920	0.07
645.7121582	0.21
658.1741943	0.23
666.7367554	0.76
671.0234375	0.13
674.1488037	0.13
676.3451538	0.12
677.2827148	0.54
678.3779907	0.08
679.4672241	0.23
681.6338501	0.12
688.3890991	0.71
691.9285278	0.07
696.5900269	0.11
699.9784546	0.26
701.3867798	0.06
703.5105591	0.22
704.7032471	0.07
708.1604614	0.11
711.1414185	0.27
713.8181763	0.29
718.4004517	0.39
719.5068359	0.34
720.6460571	0.29
725.4626465	0.07
726.6793823	0.18
735.9165649	0.25
737.4820557	0.20
738.4677124	0.40
746.3411865	0.28
747.9869995	0.48
750.4205933	0.58
760.2940063	0.09
766.4011230	0.65
774.3761597	0.91
776.5752563	0.27
778.4480591	0.37
782.2462769	0.38
788.3432007	0.16
789.3135986	0.21
790.4794922	0.48
792.4760132	0.27
793.3447876	0.20
804.2639771	0.07
806.4603882	0.60
808.3606567	0.20
812.3615723	0.07
816.4880981	0.17
819.4687500	0.31
830.5289917	0.34
845.8964233	0.35
847.6753540	0.52
848.7266235	0.43
850.8200073	0.27
861.7056885	0.34
862.8269043	0.76
871.7161255	0.10
874.2184448	1.71
887.6942139	0.13
889.3396606	1.20
890.3472290	6.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.0087
Annotation	Unknow
Peak:m/z	Relative Intensity
166.0448608	0.07
190.7217102	0.07
199.2763062	0.19
199.9094849	0.26
215.0317078	0.18
216.0167694	1.13
225.9114380	2.79
241.1380157	0.70
242.3752441	0.17
243.1341553	0.28
247.8867798	0.41
252.9931335	0.20
253.9877625	0.09
255.3166809	0.45
255.9204102	0.87
257.9984131	0.92
259.0156555	21.44
261.9219055	0.81
263.1950684	1.13
268.8526611	0.69
269.9710388	3.61
271.9910583	6.70
273.9587708	29.33
281.7849426	0.42
283.8754272	22.21
284.9015198	1.69
289.7016296	0.44
290.8908997	0.11
297.8357544	0.11
299.2056580	0.13
299.9679565	0.65
301.1359253	0.60
302.9863892	82.19
303.6101990	0.19
309.7873840	0.34
311.1204224	0.14
312.2284241	0.04
313.1896362	0.11
315.0485840	1.48
315.9154663	8.89
317.1511536	9.34
317.7965088	29.88
318.7785645	0.14
321.7894287	0.14
324.1806641	0.14
326.2852783	1.66
327.0331421	6.97
327.9370728	14.61
328.9928589	1.74
329.8791504	2.47
335.0240173	2.00
336.2416687	0.09
342.9281616	0.09
345.3515320	0.16
347.9539795	0.47
355.0817871	0.29
359.8888245	0.10
360.6866455	0.62
361.5896606	0.39
362.4285583	0.05
370.5439453	0.30
372.0145874	3.32
373.1469116	3.68
374.0191956	24.14
374.9351501	0.18
376.1647339	0.06
378.9632568	2.77
385.8147888	0.20
390.1809998	0.08
392.0366821	0.43
399.6114502	0.05
401.0141907	0.26
401.9207764	0.86
402.8022766	0.40
403.9941406	16.57
404.9562683	2.92
418.0404663	10.66
419.9833374	28.33
434.3874817	0.31
445.1560669	0.05
445.9863281	3.06
447.4235229	0.08
448.5700989	0.12
459.9914856	0.25
460.9794006	0.54
463.9273987	100.00
464.5337219	1.29
470.8876343	0.28
471.6570129	0.68
489.9277649	31.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	701.1907
Annotation	Lactulose
Peak:m/z	Relative Intensity
197.1684723	0.02
221.2821350	0.05
280.9274597	0.11
311.1247559	0.02
322.8508301	0.15
340.9627686	1.97
357.2477417	0.03
358.5316772	0.05
359.2786255	0.02
383.0522461	1.65
412.6544189	0.43
425.1988525	0.03
442.9351196	1.99
467.5126953	0.03
473.1739502	0.05
485.0558472	1.17
503.0037231	1.92
521.2623901	0.07
539.0950317	3.05
545.1571655	0.07
602.1507568	0.10
646.1716919	0.02
663.4502563	0.11
665.2079468	100.00
665.8449707	0.26
667.2363281	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1803
Annotation	Spinosin
Peak:m/z	Relative Intensity
174.1003571	0.01
185.4006500	0.05
187.2227783	0.04
188.3858032	0.01
199.0892639	0.07
214.4668579	0.01
219.1023560	0.09
221.9609680	0.02
223.1133270	0.01
229.0509033	0.04
239.3254089	0.02
241.2488098	0.15
257.2345581	0.07
258.1771851	0.08
258.9377136	0.03
264.0298767	0.04
267.3367310	0.02
283.0036621	0.02
285.4339600	0.01
286.2165527	0.02
293.1535034	0.09
294.0501709	0.03
298.0035400	0.09
301.0430603	12.91
306.2729492	0.02
309.3010864	0.09
313.0884705	0.05
323.2816772	0.03
328.2170410	0.04
332.2009277	0.01
343.0418091	0.21
345.1378174	0.05
346.6782837	0.01
348.3068237	0.10
353.2249146	0.07
367.2797241	0.07
369.3765869	0.08
373.5524902	0.03
381.3123779	0.07
384.3659668	0.10
385.1335449	0.08
389.2979736	0.08
396.9031372	0.06
400.2135620	0.12
402.2225342	0.04
404.2302856	0.02
407.3422241	0.01
411.1687012	0.24
412.2014771	0.08
414.1870117	0.01
415.3051758	0.07
417.1160278	0.04
418.3770142	0.03
429.2436523	0.49
430.2882080	0.27
431.3341675	0.02
435.6044312	0.01
443.2984009	0.03
444.9257202	0.14
447.0929565	0.90
448.4047241	1.56
456.0282593	0.02
456.9918213	0.02
458.3523560	0.05
458.9854736	0.03
461.2731934	0.13
463.0181885	100.00
464.1920776	0.04
465.2822266	0.09
467.0075684	0.04
470.0690918	0.16
476.2616577	0.06
478.9743652	0.06
479.6080933	0.04
480.4064941	0.01
486.2899170	0.01
489.1860352	0.12
494.1405640	0.02
508.3608398	0.06
509.3283081	0.11
513.2527466	0.08
514.8833618	0.04
519.3060303	0.07
520.5498657	0.06
527.0313110	0.10
543.1244507	0.03
547.4533081	0.02
555.1256714	0.12
562.2551270	0.11
563.4039307	0.02
564.3469849	0.26
565.2680664	0.25
566.2401733	0.27
567.6096802	0.01
569.5075073	0.03
572.3002319	0.10
577.0463257	0.10
583.0745239	0.01
590.5380249	0.08
591.1792603	1.17
592.2897949	0.02
609.3426514	0.05
610.3002930	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1654
Annotation	(+)-Jurinelloide
Peak:m/z	Relative Intensity
108.8191223	3.34
120.7707672	0.47
121.8785477	8.76
122.9416656	1.37
125.1861420	0.14
128.8753662	1.15
129.9868469	0.09
135.2440186	0.80
136.0177155	3.18
137.0352173	0.45
139.1969910	0.17
143.1222534	0.20
145.0439758	0.08
147.0437012	5.65
148.0982056	0.96
149.1909180	1.15
150.1603088	0.26
158.9696045	0.33
159.8538818	0.06
161.0341492	1.05
161.9528198	0.50
163.1919403	0.07
164.9591064	52.34
165.9885864	1.66
173.0737915	0.28
174.8139191	0.13
176.0114288	0.42
176.9347992	0.30
177.9635162	1.92
179.0919037	25.90
179.9218140	0.28
186.0473785	0.08
187.0218201	0.55
189.2515564	0.11
190.3124847	0.19
191.2362061	0.57
192.1334839	0.37
193.1509705	0.53
194.2539368	0.14
194.8624268	0.13
198.1373291	0.33
199.2270813	0.14
202.9823914	0.42
204.9537659	1.16
208.3148804	0.10
208.9855652	2.48
210.1952667	0.10
213.1452332	0.22
217.0205688	0.11
221.0768127	0.61
221.8269653	0.22
223.1249084	3.55
224.1360474	0.42
231.2315674	0.18
235.0605469	0.24
237.3118896	0.11
238.0524597	0.12
239.0282288	0.48
243.1334229	0.41
243.8721313	0.35
255.9884033	0.10
259.1439514	0.16
260.0901489	0.04
263.9507446	0.19
265.8095093	0.47
268.3608704	0.24
269.2917175	0.62
271.1293335	0.52
272.1388245	0.17
276.1835938	0.09
281.1353149	2.84
282.3174438	0.54
283.2484131	1.10
286.5131836	0.33
287.2921753	0.48
289.0924683	0.72
290.1432495	0.06
293.2431030	0.13
295.4118042	0.13
296.0697937	0.06
298.1184998	13.64
299.1581726	1.11
300.2445984	0.07
301.1537476	1.72
302.9583740	0.33
311.0233765	0.26
313.1330261	30.93
314.1414490	1.62
315.1936035	6.34
316.0607300	3.34
317.1467896	2.14
319.2194824	1.10
325.1211853	0.83
327.5530701	0.38
328.2286377	0.86
329.1848145	1.22
331.1613770	14.86
332.3266602	1.14
333.1874695	0.03
341.2470093	0.32
343.1655579	13.89
344.4691467	0.46
346.1995544	100.00
347.2268372	2.95
361.2346497	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.2288
Annotation	Unknow
Peak:m/z	Relative Intensity
197.3468323	0.11
205.2290039	0.03
223.1156769	0.68
230.9587097	0.25
241.2253723	0.06
249.0824280	7.63
250.0983582	0.04
264.9812622	0.03
267.0928345	11.81
297.2135620	1.13
305.0812683	0.06
315.2308960	0.24
319.3647461	0.04
323.2157288	0.48
329.1903076	0.17
337.2512817	0.10
342.0046387	0.03
359.0465698	0.05
374.1559448	0.17
375.2089233	0.09
387.2395020	0.16
400.8854980	0.05
403.3856812	0.05
411.2025757	1.91
429.2075195	28.58
430.2252808	0.13
431.2625122	0.05
433.3051147	0.05
437.1008911	0.12
445.6149902	0.06
449.2369995	0.29
455.1407471	3.95
455.7567749	0.03
456.9364624	0.12
459.2512817	0.15
470.3773193	0.05
471.0529785	0.02
473.1609497	100.00
474.2606812	0.43
477.3590698	0.20
491.2874146	7.30
515.1403198	0.04
519.9227905	0.08
521.3509521	0.03
522.5173950	0.07
533.1558838	0.24
535.2661133	0.20
567.5514526	0.10
575.2637329	0.11
593.3273315	0.12
595.1358032	0.02
607.2512817	0.46
609.3346558	0.03
617.2778931	0.22
635.2100830	3.97
651.9347534	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	580.06
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2942963	0.13
181.9858093	0.16
182.6302948	0.09
184.1210327	0.17
191.0666809	0.19
196.9622650	0.23
199.8930054	0.08
213.0632629	0.19
214.8074036	0.45
216.0910339	0.18
222.0570984	0.39
223.1687012	0.17
223.9999390	0.11
226.9899750	0.30
228.0548706	0.37
230.0181732	5.64
230.8665771	0.44
234.9093170	0.36
238.1477661	0.14
257.3563843	0.12
259.1574707	0.33
263.0726013	0.23
264.1260681	0.53
266.0099487	6.19
267.9599609	0.28
269.8380737	0.53
272.0132751	8.93
273.1532593	0.66
274.3040161	0.09
274.9913940	1.03
277.0231018	0.76
277.8601685	0.15
287.9279480	0.13
295.1394653	0.10
297.2774658	0.14
298.0738525	0.25
303.0823364	0.96
308.0640869	1.04
309.9517212	56.22
311.0147095	8.61
312.0676880	2.07
314.0421448	0.63
315.2321777	6.55
315.9735107	27.16
317.0033569	66.22
317.9911499	0.20
320.2258301	0.67
321.9227905	1.75
323.0493774	1.44
333.9249268	0.51
335.1252441	2.41
336.1471558	0.75
340.9521484	3.77
342.2054443	1.08
343.0711060	1.02
345.1585693	0.21
350.2046509	0.07
351.3896484	0.24
353.0042114	5.73
354.1483154	3.45
357.9984741	9.38
358.9503174	6.86
360.0658569	2.97
361.9966431	0.42
362.8400269	0.15
363.9775391	16.23
364.9383545	5.24
371.3259888	0.08
374.0430908	2.84
375.3444214	0.39
378.0932007	0.13
379.1326904	0.10
382.6373901	0.78
383.2645874	0.21
387.1605225	2.56
388.2743530	1.23
389.0523071	0.84
390.2111206	0.24
394.0785522	0.10
396.1253662	0.21
397.6351318	0.20
399.9562988	0.28
400.9565430	0.89
402.1676636	0.54
405.0455322	0.27
407.0135498	14.58
408.3137817	0.12
409.1381836	0.09
412.1240845	0.24
418.0502930	0.66
427.0014648	4.27
427.9622192	0.94
429.0435791	0.32
432.8620605	1.27
433.6170044	0.07
434.7677002	0.46
435.9955444	0.21
441.8474731	0.07
442.8898315	1.15
444.9313965	100.00
445.6057739	0.71
446.2284546	0.19
448.8192139	0.85
450.9824829	46.31
453.0883789	1.75
456.9257202	0.29
459.1466064	0.39
470.1734619	14.09
470.9960327	78.31
475.1882324	1.79
476.1895142	1.59
488.9154663	30.53
490.5285645	1.22
491.5318604	1.39
492.9591675	3.79
496.0181885	0.49
496.9398804	0.09
499.1963501	0.10
500.1798706	0.25
501.2538452	0.07
513.2020264	0.16
515.0197144	0.22
516.4992065	0.25
517.9453735	2.89
519.0739746	0.14
527.1229248	0.11
532.1190796	0.08
532.9304810	0.12
535.0277100	4.25
535.9024048	6.58
543.7532349	2.22
544.3615112	0.14
561.2362671	8.81
562.0479736	71.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.098
Annotation	Vitexin
Peak:m/z	Relative Intensity
142.9136963	0.02
148.7136383	0.01
152.7209167	0.02
160.5676575	0.03
165.2064514	0.01
172.7799072	0.03
179.0615692	0.05
207.0614624	0.03
246.8230591	0.03
249.002594	0.07
251.2205505	0.38
268.1699829	0.02
269.1879272	0.40
280.9970398	0.02
283.1137085	0.43
287.1165771	0.07
292.9022827	0.02
298.1975708	0.03
299.05896	0.02
301.4534302	0.01
309.1085815	0.06
311.0490723	100.00
311.8717957	0.34
319.4518433	0.02
323.1948242	0.29
325.1665039	0.07
335.0197754	0.01
337.0978394	0.34
339.0886841	0.03
341.0852661	13.38
343.2542114	0.02
349.3123779	0.01
353.1613159	0.98
355.1136475	0.27
365.2394104	0.06
367.1152649	0.04
371.2090454	0.32
377.0925598	0.29
383.1335144	0.45
385.3539124	0.03
386.1341553	0.01
387.1786804	0.11
388.9071045	0.05
395.074646	0.22
400.9883728	0.03
413.2020264	2.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.43
Annotation	Campesteryl glucoside
Peak:m/z	Relative Intensity
164.9749146	0.05
175.8593750	0.02
183.0544739	0.07
190.1528320	0.03
190.9554138	0.13
193.2672272	0.22
197.0435486	0.13
199.2056427	0.03
200.2008820	0.05
202.8064728	0.18
205.2519226	0.02
206.3781128	0.03
207.2099609	0.10
211.2395020	0.02
214.7591553	0.02
217.4855957	0.05
219.1873779	0.07
225.0432281	0.09
227.3267365	0.14
228.3870544	0.07
235.2510376	0.09
237.4264679	0.10
239.8420410	0.05
243.1947632	0.10
249.2342224	0.04
252.7678528	0.05
255.0001526	0.05
261.4131775	0.09
263.4340820	0.03
264.9900513	0.05
271.5080566	0.03
273.4550476	0.09
275.1369019	0.05
279.2432861	0.06
280.0994263	0.03
283.2181396	0.03
293.0358276	0.06
296.2612610	0.07
303.5022583	0.02
305.5330811	0.06
307.1243896	0.03
310.4159851	0.06
311.5956421	0.09
312.2979126	0.08
313.0972900	0.16
314.1737671	0.05
316.3377075	0.03
319.2501221	0.02
320.9003296	0.02
323.2594604	0.09
333.0975342	0.04
335.2364502	0.42
337.1228638	0.05
339.2169800	0.18
345.2871094	0.09
347.2105713	0.20
372.4853516	0.11
373.5885620	0.13
375.4365845	0.03
377.2950439	0.03
383.3427734	0.89
387.1389160	0.08
391.3309326	0.06
396.3834229	0.14
398.4273682	0.27
401.4113159	2.93
405.3848267	0.02
407.9379272	0.15
413.5134277	0.04
415.4797363	0.20
417.4591675	0.23
419.4685059	14.67
426.1134033	0.09
427.1145020	0.04
432.4326782	0.06
433.0463257	0.06
435.3798828	0.70
437.3952637	5.31
440.1110229	0.14
443.6029663	0.18
453.2390747	0.27
460.7868042	0.05
461.4450073	2.94
463.3906860	0.33
465.1215820	0.14
471.6430664	0.05
477.4006958	0.12
479.3662720	3.66
481.2390137	0.06
485.3313599	0.09
489.3783569	0.04
493.6030884	0.24
495.2325439	0.09
495.9454956	0.02
496.7516479	0.06
499.3693237	0.05
501.5554810	0.13
503.4375610	0.78
504.6333618	0.27
505.3477783	0.24
510.6450806	0.04
513.7202759	0.32
514.8890381	0.06
517.4107056	0.08
521.3933716	1.69
522.1765747	0.19
527.5408936	0.60
531.3441772	0.27
532.2740479	0.14
534.5725098	0.12
535.2704468	0.03
545.4005737	100.00
546.0921021	0.22
562.5216675	0.43
563.4703979	0.77
564.2649536	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.144
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
85.9095535	23.23
130.0359497	1.24
131.9338684	100.00
147.8898163	1.27
197.5432281	0.41
198.1463470	5.73
202.0574188	0.06
203.6485748	0.06
214.9899445	0.47
216.1443329	0.17
219.7869873	0.05
225.0939331	0.39
243.0194550	4.90
244.1368256	26.66
252.2431793	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1754
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
215.0466919	0.44
231.0721588	0.20
251.1530304	0.13
270.2892151	0.06
276.8754883	0.17
301.0933228	0.10
302.0361328	0.83
313.3062134	0.18
317.0722656	100.00
331.0491943	0.15
333.2527466	0.10
335.1325684	0.20
344.0248413	0.12
357.9486694	0.40
362.9995728	0.37
365.4483643	0.28
369.1217651	0.46
376.2301025	0.28
377.1102905	0.16
379.8539429	0.14
399.3601074	0.43
400.71521	0.11
404.9016113	0.23
410.1582031	0.25
416.3414917	0.26
417.2157593	0.09
428.5273438	0.26
433.0525513	0.19
441.4645996	1.40
444.2798462	0.68
445.394104	0.61
457.2225342	0.07
461.9956055	0.97
462.9942017	4.05
465.4232788	0.52
467.2702637	0.09
472.8170166	0.13
478.8859863	24.05
479.5107422	0.22
505.3393555	0.47
510.4300537	0.41
531.4283447	0.14
544.2932739	1.10
547.9169922	0.46
549.4197388	0.28
552.0441284	0.48
553.2852173	0.17
556.5499878	0.33
578.4074097	0.76
579.4524536	0.91
585.4216919	0.21
588.828064	0.24
597.1084595	0.81
603.2012329	0.13
605.571228	0.61
607.1679077	3.36
624.131897	0.21
625.1897583	2.17
627.0485229	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	714.51
Annotation	1-Palmitoyl-2-linoleoyl PE
Peak:m/z	Relative Intensity
209.0407715	0.09
244.8526154	0.22
251.0432281	0.12
255.2602081	33.16
256.1803589	0.18
257.1747742	0.07
265.2926025	0.16
279.2258911	100.00
283.441803	0.10
293.1687927	0.10
295.1117554	0.19
297.0384521	0.13
370.8867188	0.18
391.1889648	0.55
397.1981201	0.12
407.3370361	0.23
419.4849243	0.20
431.269165	0.23
434.2474976	1.30
452.3674316	16.76
458.3897095	1.20
476.1462402	2.28
490.5419922	0.11
515.1747437	0.13
552.2945557	0.22
554.2666016	0.34
563.8909302	0.07
568.0333252	0.12
571.1680298	0.06
612.4634399	0.08
654.2053223	0.08
655.4032593	0.34
669.7210693	0.21
687.2103271	0.17
696.2161255	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.155
Annotation	Unknow
Peak:m/z	Relative Intensity
83.1508102	0.11
85.0006256	3.00
87.0652542	0.26
94.1181641	0.14
95.0908585	3.10
96.9551239	11.24
98.7352371	0.27
101.1124344	0.34
106.9687195	1.43
109.0124054	1.82
111.0197906	16.73
113.0765686	3.20
115.0514221	16.39
120.9351501	0.33
122.9547577	1.63
124.9968567	4.65
127.0658722	17.78
127.9000702	0.08
128.9958649	2.35
133.1569214	0.56
135.1697845	0.32
136.9904175	21.91
138.9832001	1.76
141.0899200	3.86
142.9140167	0.51
149.0136871	1.46
151.0596771	18.79
152.9803925	0.99
154.9696655	100.00
155.8530273	0.19
157.0650177	15.60
159.0681458	0.51
161.1750031	0.21
163.0121918	0.58
165.1423340	0.46
167.0478210	2.19
169.2500458	1.10
171.0544281	0.87
173.1407318	2.58
175.2575226	0.07
176.9674835	6.36
179.1456604	1.92
180.0934906	0.12
180.9414978	0.48
182.9958496	0.26
185.1518402	0.28
187.0554047	2.53
189.1528320	0.41
191.0965118	36.40
195.1275177	25.67
199.0900574	3.68
200.8977356	0.26
202.2078247	0.16
207.1022491	1.99
209.0632935	4.30
213.1505127	15.98
215.0304108	0.41
217.1436310	8.24
222.9175568	1.10
225.1549683	0.79
226.9280090	1.25
228.2162933	0.14
228.8575439	0.39
235.1074371	48.56
241.0670319	0.23
243.3112793	1.18
251.2573242	1.51
253.1290283	27.38
255.2385101	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.294
Annotation	LysoPE(0:0/20:3(8Z,11Z,14Z))
Peak:m/z	Relative Intensity
152.8449554	0.09
168.0668488	0.36
205.1512146	0.07
213.1806183	0.17
224.0671387	0.36
231.2076111	0.04
233.1882477	0.51
242.1511841	1.73
259.2908630	0.28
261.3905640	0.07
275.3199768	0.66
277.1794434	100.00
328.3855591	0.15
331.1188965	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1594
Annotation	Puerarin xyloside
Peak:m/z	Relative Intensity
202.0294800	0.24
216.0153351	0.06
230.0254517	0.16
232.0905762	0.02
233.3061218	0.05
247.4912720	0.47
248.1195374	1.26
263.2943726	0.09
265.0486450	100.00
265.9848022	0.35
268.2666626	0.16
274.9409180	0.10
282.0504150	0.02
284.0078125	2.17
285.1038513	2.06
302.1655884	0.01
304.6970825	0.03
314.8422852	0.02
344.0393677	0.09
345.0994873	0.61
346.0072021	0.10
357.2233276	0.08
358.4580688	0.10
359.2255249	0.06
367.1040649	0.06
370.7055054	0.02
375.2084961	0.22
376.0053711	0.10
385.2899780	0.02
386.6561279	0.07
394.9656372	0.07
397.0108643	0.02
400.7431641	0.02
410.9624023	0.05
416.7523804	0.12
419.2610474	0.17
458.8735962	0.07
482.9924316	0.04
489.8203125	0.05
501.1191406	0.04
502.7951050	0.06
504.8549194	0.24
505.5477905	0.04
511.0269165	0.02
512.9360352	0.03
526.8103638	0.03
529.1469116	0.13
531.1341553	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.3752
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
189.7829742	0.07
199.0991821	0.21
219.1026001	0.11
222.2129211	0.06
235.1143188	6.28
241.0571747	0.16
245.2255096	0.23
253.1231384	1.43
255.2057800	1.36
267.1921082	0.21
269.3668518	0.04
287.1005249	3.69
293.1322021	0.19
302.9526367	0.12
305.1014404	4.86
311.4314575	0.06
321.3349609	0.12
322.8499146	0.59
325.1229553	0.26
343.4910278	0.23
353.4479370	0.38
378.8836060	0.10
379.4844360	0.07
387.3485107	0.26
397.0688477	100.00
397.6893921	0.41
408.5230103	0.12
409.2605591	0.20
411.0291138	0.20
415.2145996	32.60
417.1538696	0.14
443.0536499	0.15
445.3474731	0.12
461.0507202	0.08
479.4782104	0.27
483.2562866	0.18
493.0710449	0.06
504.9542847	0.40
508.3317261	0.13
543.4110718	0.26
548.5835571	0.11
553.7175903	0.35
556.3375854	0.29
569.0328979	0.13
579.3726196	0.32
593.4254150	0.04
608.9880981	0.32
613.0980835	0.09
635.1763306	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.214
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.0665131	0.17
221.0863495	5.32
222.9371643	0.10
244.8223877	0.23
248.3201599	0.10
249.6058655	0.08
250.6974945	0.97
263.0874939	0.19
269.2442017	0.14
273.0253906	0.11
280.9665527	3.05
310.8582764	1.35
322.927002	5.07
323.5864258	0.04
327.8337402	0.12
329.6156006	0.08
338.5712585	0.15
340.5144653	3.63
341.1212769	27.52
347.387207	0.56
365.192627	0.34
381.1838379	0.24
383.1107788	100.00
384.1830444	0.06
397.0047607	1.05
398.1151123	1.17
407.7085571	2.43
409.1966553	1.01
411.5418701	0.39
412.7473145	2.20
424.975708	1.19
442.8900146	22.93
443.5119629	0.19
467.102478	0.88
472.5672607	0.60
485.1956787	29.28
498.3716431	0.14
503.085144	3.09
527.0897827	0.20
533.9819946	0.19
545.2155151	1.50
566.2702026	0.14
567.3643188	0.16
590.9303589	0.42
592.1119995	0.41
593.1876831	0.22
599.1829224	0.09
619.3952637	0.46
647.3375854	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.47
Annotation	DG(18:3(9Z,12Z,15Z)/18:4(6Z,9Z,12Z,15Z)/0:0)
Peak:m/z	Relative Intensity
171.0177765	2.65
184.6462097	1.95
201.2628937	3.35
211.1289062	1.68
215.0888062	2.72
219.2481232	0.44
222.9764862	0.64
239.1941071	1.49
245.5409241	0.58
249.3701172	0.44
265.4058838	1.19
275.2100830	3.01
295.3001099	5.97
299.3921509	4.64
323.2816162	2.02
345.0671387	1.37
349.2509155	1.60
353.2833252	2.22
365.2689209	3.48
373.1296387	2.06
375.6289062	1.49
380.8776855	0.71
393.2608032	5.84
399.4750977	3.49
411.4383545	2.71
423.2844849	1.43
439.5238037	1.53
445.5702515	0.88
447.4077148	0.44
449.4634399	1.22
459.6826782	1.83
465.4396362	2.22
501.2783813	2.37
503.3254395	1.74
505.5838013	4.74
509.6770020	0.58
513.4030762	4.18
515.2632446	1.03
519.5234985	18.29
523.8690796	0.55
533.4082642	7.95
537.4082642	11.02
547.4130249	2.53
551.3507080	6.11
552.1842651	1.35
555.8565063	1.10
561.2333374	3.37
576.1434326	0.53
581.1931763	0.58
592.1707153	6.58
593.4182129	100.00
594.4213257	11.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	557.2599
Annotation	Valeriotriate B
Peak:m/z	Relative Intensity
161.0296478	0.12
162.0362549	0.02
179.0766907	0.12
210.0212097	0.04
227.1806488	0.02
267.9908752	0.04
326.4584351	0.03
331.4273071	0.18
332.3636475	0.17
333.3013916	0.01
335.4126587	0.02
339.0165405	0.04
340.2252197	0.02
349.3530884	2.25
350.3286743	0.48
364.1584473	0.04
372.6286011	0.02
377.0695190	0.10
379.2990723	0.05
388.0114746	0.04
391.0383911	0.11
393.2041626	0.04
394.2382812	0.11
396.2349243	0.04
399.0788574	0.02
400.0566406	0.01
409.0243530	0.04
413.1015015	0.01
425.3642578	0.06
427.0617065	0.04
431.2031860	0.14
432.3479614	0.16
436.6006470	0.08
438.1458740	1.12
454.1444092	0.02
457.4783325	0.04
458.3085938	0.03
464.3032227	0.03
467.1256104	0.08
468.3346558	0.40
472.5739136	0.04
476.4233398	0.03
479.5925293	0.03
483.3967896	0.18
485.1436157	0.05
489.3413696	0.05
490.0756226	0.05
491.2946777	0.12
493.1967163	0.17
494.4574585	0.23
495.2129517	0.06
496.4612427	0.16
497.3883667	0.10
499.4887085	0.09
500.8454590	0.02
504.2143555	0.05
509.0352173	0.04
511.2824097	100.00
512.2710571	27.00
513.4464722	0.14
514.3519897	0.16
515.0048828	0.04
515.6758423	0.04
516.6430054	0.02
521.2658691	0.19
522.2461548	0.11
526.4295044	0.04
528.1718140	0.10
538.1952515	0.01
539.4282837	0.06
540.1618042	0.28
540.7753296	0.07
548.4921265	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.093
Annotation	Erinoside
Peak:m/z	Relative Intensity
112.9944305	0.97
126.9974060	0.07
128.7746124	0.09
136.8969727	11.79
139.1920166	0.24
145.1645203	0.06
145.7985382	0.12
157.0709839	0.08
161.1863403	0.16
167.0468140	0.13
174.9893036	0.51
178.9541016	0.83
183.0681152	0.09
193.0536804	0.20
195.0800934	0.04
205.0470276	0.25
207.1078644	0.33
211.1020813	5.96
217.0678711	0.14
223.1632080	0.07
223.9750061	0.05
225.0831299	0.42
231.0695190	2.50
240.9779053	0.14
243.1062317	1.05
249.0372314	66.05
261.1651611	0.08
267.0337830	100.00
268.2379761	0.12
280.9809265	0.45
282.0627136	0.08
293.3186646	0.07
297.1847534	0.06
298.5735474	0.07
301.1046753	0.06
307.1809082	0.11
310.9823914	0.40
322.9041748	0.26
325.1300964	2.54
327.0822449	0.29
341.0555115	1.83
343.1857910	1.66
350.8908386	0.12
357.2066345	0.31
369.1178284	5.46
371.8823547	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	646.3007
Annotation	Unknow
Peak:m/z	Relative Intensity
184.4741669	0.04
191.0689392	0.19
196.0435486	0.72
196.8522034	0.04
211.1735840	0.15
212.9795380	0.05
224.2434387	0.09
225.2327271	0.03
231.0873260	0.04
237.2706604	0.03
240.0933838	0.03
241.2687683	0.04
242.0420074	0.21
250.0362091	0.04
256.2008057	0.02
268.0751953	1.91
286.1658936	4.00
289.1266174	0.03
302.1086731	2.46
307.1753540	0.10
320.0758057	100.00
325.1850281	0.61
339.0142212	0.11
353.3171997	0.04
430.3561401	0.02
432.2313232	0.02
437.2470703	0.05
471.3933105	0.03
484.5787354	0.05
490.0756836	0.09
491.9827271	0.06
502.3525391	0.10
507.9371948	0.04
517.2792358	0.41
541.2987671	0.02
543.5111694	0.02
555.9242554	0.04
568.8352661	0.04
584.5324097	0.02
587.3145752	0.07
592.9680786	0.01
600.2725830	0.10
601.3523560	0.17
602.4735718	0.30
617.3290405	0.05
622.5795288	1.00
623.3683472	0.25
626.2431641	0.13
627.3297729	0.01
628.4067993	0.21
632.3703003	0.08
637.2942505	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.1289
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
71.2557602	0.16
78.9758530	0.17
80.9106293	0.46
82.6127777	0.11
91.1680450	0.04
94.9062500	0.03
95.9763184	0.03
97.0958862	0.35
107.1336212	0.06
108.9036560	0.34
119.2533722	0.05
120.9430084	0.07
121.9959564	0.06
123.0882568	0.16
124.7775269	0.22
125.4182281	0.10
126.9600983	0.10
132.9882507	0.15
135.0921326	0.86
137.0109406	0.18
145.0068359	0.08
147.1120911	7.16
149.0054932	0.07
151.1439362	0.71
153.0343170	8.83
155.2371979	0.44
157.1270905	0.13
159.0963287	0.05
160.6842651	0.04
161.3179321	0.08
163.0734863	1.40
165.1176605	75.84
166.9689331	0.07
168.9622040	0.03
171.0885620	0.09
179.0506134	1.04
181.1407471	1.72
183.0791931	1.58
184.9579010	0.28
191.0095367	9.53
197.1178131	10.96
198.6737061	0.10
209.0392609	100.00
209.8370056	0.01
211.0424347	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	Lactulose
Peak:m/z	Relative Intensity
341.0892334	100.00
342.0288086	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2139
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.7312622	0.57
221.0468292	2.53
232.9383698	0.14
235.1148987	0.17
250.3673706	1.33
251.0025635	0.72
262.9546204	0.21
268.9660034	0.31
280.8202515	3.10
304.9351196	1.29
321.1619873	0.21
323.0582275	7.06
341.0192261	25.85
383.1107788	100.00
412.7775269	0.80
425.1939087	0.74
442.9116211	18.88
443.595459	0.49
449.2423706	0.12
451.4411011	0.13
454.9355469	0.24
467.1792603	0.20
473.0775146	1.57
485.2119751	33.13
486.0440674	0.32
499.9550781	0.07
503.071167	8.33
527.9672241	0.48
545.2014771	1.35
564.2964478	0.26
577.2432251	0.26
579.8895874	0.22
601.0822754	0.24
634.8292236	0.06
647.3237915	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0981
Annotation	Vitexin
Peak:m/z	Relative Intensity
149.0027771	0.01
152.9275513	0.10
172.6631775	0.05
178.9360352	0.01
216.8078156	0.04
243.2081604	0.02
267.2877502	0.03
269.2931824	0.11
281.161438	0.05
283.1559143	0.21
293.0237732	0.02
301.0904236	0.01
309.2081909	0.03
311.0482788	100.00
312.1069946	0.18
315.1561279	0.03
323.0129395	0.16
325.2574158	0.06
337.1793213	0.06
341.1639404	10.12
349.0444031	0.04
353.1489563	0.75
355.1255188	0.16
365.2528381	0.14
367.3139954	0.07
371.1697388	0.87
377.2998352	0.16
383.2278137	0.21
383.9143677	0.03
389.2246399	0.02
395.2574768	0.14
403.1565247	0.03
413.1601257	2.00
414.3583069	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.2329
Annotation	10E,14E-octadecadienoic acid
Peak:m/z	Relative Intensity
83.1829987	0.50
95.1360779	0.93
96.8838348	0.39
121.0416718	0.24
137.0083466	0.59
153.3424683	0.50
169.2740631	0.87
220.7827148	1.02
235.0893860	1.14
243.3725891	0.61
259.1005249	5.10
261.1877136	100.00
261.7960815	0.51
279.4585876	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.0914
Annotation	Unknow
Peak:m/z	Relative Intensity
138.1716919	0.55
139.7576599	0.16
161.3442383	0.07
172.9893799	0.09
184.1452942	0.08
187.9771881	0.06
189.9970703	1.95
192.1659851	0.47
198.2873230	0.10
204.0258484	0.06
205.2300415	0.99
207.8483887	0.67
208.8390961	0.16
210.0784760	0.19
215.9701538	0.12
217.7377777	0.31
219.7111816	2.08
231.9568939	13.39
234.2523499	0.29
235.9513397	0.55
237.9283142	1.93
249.1089783	0.13
249.9222107	2.64
252.0239868	0.76
256.0657654	0.09
261.6601868	0.65
262.2973022	0.14
275.0375671	0.08
276.2039795	0.30
278.2278748	1.12
279.9796448	100.00
280.9532166	0.64
282.1937256	0.99
285.2229614	0.25
297.5046997	0.21
298.1589966	1.15
302.1306152	0.25
304.0325012	0.60
305.9839172	1.98
310.2983704	0.29
312.2028503	0.11
320.0728455	0.12
320.8167114	0.25
322.1149292	5.44
323.9685059	0.15
327.1494446	0.25
328.3984985	0.13
333.7885742	0.37
335.0670166	1.20
336.0052490	5.26
338.1596069	0.14
339.0186157	0.54
339.9801636	12.03
341.2520752	0.44
347.7676697	0.77
350.1083374	0.28
352.0910339	4.90
352.9911499	1.30
353.9942322	0.71
356.2414246	0.39
357.5466919	0.28
358.1861877	0.22
359.2081299	0.67
360.1381836	0.77
361.2357788	0.64
362.2928467	0.26
364.0825195	1.72
365.9321289	0.09
368.0970764	0.15
370.6004333	0.39
371.5164185	0.38
375.9013367	1.71
376.7180786	0.14
379.9670105	0.98
382.0830688	30.98
383.2342224	2.58
385.8175049	0.10
391.8676758	0.47
394.0176086	1.92
397.2309265	0.42
398.1746521	0.82
403.3385010	0.15
405.9019470	3.29
411.9839172	80.92
412.6772156	0.13
414.0277405	0.52
424.1163330	17.92
427.4649963	0.33
432.9943237	0.53
END