#DEFINITION	Reference Metabolome for Vaccinium uliginosum
#IDENTTFIER	RefMeta-Vaccinium uliginosum.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Vaccinium uliginosum
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Vaccinium uliginosum was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	204.0862
Annotation	7a-Epialexaflorine
Peak:m/z	Relative Intensity
59.9111176	1.03
67.9858093	1.51
69.9710159	2.31
71.9600906	0.32
74.0368424	0.20
81.8275528	0.08
83.8842468	3.91
84.9058075	1.23
86.0700226	0.97
93.9126129	0.15
95.8719482	17.11
96.9724731	2.64
98.0451508	0.54
98.9517059	0.41
99.9534149	0.24
102.0074310	1.97
102.9716797	0.72
107.9828796	0.56
108.9025726	0.65
110.0118256	2.63
112.0608521	0.14
113.9190521	95.38
115.9376984	0.21
117.9911041	0.14
122.0231628	0.59
124.0231476	0.47
124.7119293	0.26
125.9276123	35.59
126.9090271	5.62
128.1325378	0.12
132.1139679	0.09
137.9544220	22.99
140.3085938	0.18
143.9738007	12.85
145.0102386	2.28
148.3195190	0.08
150.0516052	6.10
156.0895386	24.97
157.9772034	100.00
159.0935516	0.24
162.0356903	4.25
162.9200592	0.12
167.9613037	87.33
168.8597260	0.08
173.9368591	0.92
175.0765076	0.09
176.0491943	0.29
185.9985504	55.11
187.0056610	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.1173
Annotation	Pedaliin
Peak:m/z	Relative Intensity
189.3833008	0.06
197.1796265	0.18
200.2265320	0.12
267.1481323	0.11
271.1940308	0.14
276.8786621	0.50
297.0699158	0.31
301.3086548	0.05
303.1846924	0.37
315.3034058	0.32
317.1284485	100.00
317.7591858	0.26
325.4087219	0.22
347.3175049	0.48
355.2159119	0.17
356.2056274	0.09
359.4105530	1.01
389.8159790	0.14
395.2920532	0.35
397.2198792	0.31
397.9190063	0.43
399.2238464	0.17
403.3432312	0.19
410.4900208	0.10
411.1430054	0.07
413.1036072	0.50
421.3681030	0.26
424.5562439	0.13
429.3918762	0.05
433.4184875	0.13
443.1247559	0.18
447.3195496	0.17
451.3393250	0.14
461.2003479	1.46
464.5066833	0.32
469.8460999	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.25
Annotation	Ligurobustoside A
Peak:m/z	Relative Intensity
192.0702515	0.25
196.9953003	0.02
199.1555176	0.15
209.2056122	1.54
225.1452179	0.13
227.1084595	0.53
236.5267334	0.05
237.2603302	0.05
255.2705688	0.06
259.0519104	0.08
282.2099304	0.03
289.4747620	0.06
299.7805176	0.03
301.0768433	0.63
305.1923218	2.45
315.3089905	0.04
322.3059387	5.18
331.1907349	10.06
337.3013916	0.06
343.3623352	0.04
347.2350159	0.08
350.1870117	1.66
374.4317932	0.07
385.6725159	0.05
400.1183167	0.42
402.1713562	0.45
417.3525696	1.76
418.3239136	22.85
419.3636169	9.37
421.3281555	0.04
428.3234558	2.41
435.2340393	4.77
435.8383484	0.02
446.2098083	100.00
446.9320679	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.1303
Annotation	Apholate
Peak:m/z	Relative Intensity
111.9548569	0.02
119.0439682	0.12
131.0494080	0.03
141.9419403	0.08
145.2294006	0.02
153.8528442	0.05
159.9998474	1.88
161.1152039	1.19
173.1172028	0.25
177.3882294	0.24
178.0638123	1.54
179.1654510	0.07
211.1833344	0.59
212.0317078	0.07
230.2596436	0.05
231.9302979	0.06
239.0649719	0.09
240.0039062	0.04
241.1269226	0.20
256.5171509	0.06
266.2697754	0.06
274.3822021	0.12
281.0858459	0.76
290.2617798	0.05
293.3600159	0.07
294.3255005	0.10
301.0184326	0.07
321.5963440	0.32
322.2044983	1.32
329.0249329	0.21
336.8703003	0.04
340.1707764	100.00
342.2127075	0.21
343.2314758	0.10
348.2224731	0.09
350.3334656	0.09
358.2198181	0.11
367.3720398	0.23
368.2266541	0.47
369.4989929	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1614
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9668579	0.03
154.9807892	0.09
160.7988281	0.05
171.1354065	0.34
173.0148163	0.43
178.8557129	0.06
189.1596527	0.06
191.0274963	100.00
221.2036743	0.01
293.2669373	0.06
300.2694702	0.03
311.2015991	0.67
312.3806763	0.02
323.2954102	0.01
324.8796387	0.01
327.1612549	0.01
340.6334839	0.05
341.3281250	0.04
370.2163696	0.05
438.9111633	0.01
441.2511292	0.02
473.0650940	0.03
483.4800110	0.02
504.4497681	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1714
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0261841	0.08
217.0208435	0.75
235.0059967	0.09
296.6903076	0.06
303.0777588	10.33
304.1987915	1.47
321.1235352	7.60
322.1597900	0.56
337.0678101	0.04
350.9497681	0.08
355.4758911	0.04
362.4754639	0.05
363.0985107	0.13
381.2692871	0.17
382.1317749	0.04
409.0657349	0.27
419.0222168	0.23
437.3336792	1.53
444.3357544	0.17
453.3765869	0.04
462.8424683	0.68
463.6070557	0.41
464.2705078	0.03
473.4804077	0.15
479.1882324	20.79
480.2662354	5.81
482.1979370	0.04
495.5670776	0.13
497.2421875	10.70
498.3507690	4.02
517.0526123	0.16
524.6220703	0.08
533.5481567	0.18
539.2222290	27.58
540.3523560	7.76
561.3956299	0.31
562.0717773	0.10
571.3007812	0.40
581.1500854	0.26
600.5072021	0.16
605.6331177	0.11
607.1947632	0.06
625.2269287	100.00
626.2151489	24.75
626.8385620	0.05
634.5452881	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1402
Annotation	Sinocrassoside A1
Peak:m/z	Relative Intensity
148.2914276	0.09
148.9887848	0.24
158.0811615	0.04
159.0391388	0.14
160.0991211	0.18
161.0866394	1.57
163.0025787	0.40
172.0825806	0.03
173.1299438	0.04
175.1006775	0.38
177.0371094	3.04
178.9540558	3.23
189.0881042	0.02
191.2407532	0.07
192.1977234	0.11
193.0419159	0.74
195.1940460	0.08
197.2244873	0.04
199.0984344	0.05
200.9837341	0.09
202.1686859	0.13
203.1029968	0.95
205.1234436	0.03
213.0485535	0.07
214.8562927	0.01
217.1300507	0.16
219.0214233	0.25
220.0848236	0.05
221.0490112	4.45
226.8674316	0.04
227.8826294	0.03
229.2072449	0.10
233.2313843	0.29
244.9611969	0.10
251.3237152	0.46
259.1367493	0.02
261.1442566	0.10
263.1583252	1.96
273.3981628	0.08
275.2132874	0.13
277.1671143	0.32
279.0701904	0.19
280.0838623	0.39
288.4027405	0.11
297.2545471	0.05
300.9534302	0.11
302.2966309	0.05
305.0083008	0.22
309.2289429	0.06
317.5949402	0.07
321.6949463	0.07
323.2075806	100.00
331.8967285	0.04
337.2624512	14.30
339.4660645	0.07
345.8767090	0.16
354.6088257	0.05
367.2530518	0.08
368.2298584	0.08
370.3583679	0.04
373.0559692	0.02
401.3477173	0.06
405.2843628	0.12
413.3355408	0.04
414.1723938	0.04
426.1117249	0.03
429.2585754	0.35
432.3209839	0.06
441.7635803	0.09
443.4230957	0.06
454.6072693	0.02
455.2231140	0.03
456.3916321	0.21
457.4056091	0.52
465.2326050	0.03
468.0192261	0.15
469.1946411	4.17
473.6034851	0.04
481.2080383	0.05
482.3451233	0.49
483.4538269	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.0162
Annotation	Unknow
Peak:m/z	Relative Intensity
130.2401428	0.02
146.9626465	0.15
163.7408752	0.07
169.3682709	0.15
172.4067383	0.09
176.0227661	0.08
177.2996521	0.06
197.1137695	0.09
217.0615692	0.08
219.2140198	0.10
229.3490295	0.09
230.1285095	0.23
231.0762634	0.15
235.0336914	0.60
243.9181824	0.20
246.1919250	0.08
250.2239990	0.05
252.9805298	0.19
261.0984192	0.12
264.0436707	0.12
264.9523010	0.41
269.2925415	0.08
274.3254700	0.17
278.7377930	0.03
281.0190430	0.52
289.1085205	0.16
290.3323975	0.12
293.1783447	0.93
294.1070251	0.16
295.0281372	0.27
295.9318237	0.06
301.0962524	0.36
303.2031860	0.14
304.1593933	0.14
305.1217041	0.14
307.0413818	32.37
308.1104736	0.25
310.1676025	0.65
311.0376587	0.25
319.0289917	49.83
321.0437622	1.82
323.2881470	0.47
328.9928589	0.06
330.0247498	0.48
331.1456299	1.73
335.0628052	0.19
336.9042053	62.78
337.8065186	0.04
339.3461914	0.17
342.8906555	0.11
346.2384338	0.18
347.1095581	0.28
349.0251465	1.68
351.1097717	0.06
352.2530823	0.37
353.2691040	0.15
354.2067871	0.06
355.1201172	0.25
360.9701538	0.30
362.1920166	0.04
364.2236328	0.35
365.0915527	1.81
367.0075989	29.66
373.2027283	0.56
378.7636414	0.46
381.0365601	0.10
382.0722351	0.29
383.0948486	0.70
387.4393005	0.03
391.1199036	14.25
393.3673706	0.14
397.2256775	0.22
400.4442139	0.09
409.0928650	100.00
418.1972046	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.02
Annotation	Unknow
Peak:m/z	Relative Intensity
161.2270203	0.45
162.8717346	0.06
199.3573303	0.11
200.0002136	0.24
210.2095947	0.12
213.1813507	0.12
217.9295654	0.45
222.7490540	0.09
229.9850769	1.02
231.1293640	0.96
233.0653381	0.08
234.8150024	0.10
246.6472473	0.08
248.2145996	0.09
250.1170959	0.22
254.0524902	0.14
255.0559082	0.05
256.2026367	0.30
256.8856812	0.13
258.1098328	0.76
258.9693909	0.10
265.0481567	0.30
277.2987366	0.08
280.0874634	0.13
285.0870361	0.33
292.5866699	0.55
293.3320312	0.19
295.1279297	0.31
297.3470764	0.42
298.1682739	0.08
301.9022522	0.49
303.2180176	0.37
305.0614624	0.18
306.9595947	48.44
307.5889282	0.09
309.1743774	0.05
311.0562439	0.31
317.2532043	0.26
319.1063843	57.00
320.9750977	2.65
323.0036011	0.56
327.2141113	0.10
331.0907593	0.86
334.9645386	1.29
336.2006531	20.51
337.0599365	75.79
349.0613708	0.97
360.9499512	0.42
365.0329895	2.70
367.0395508	59.32
368.0179443	0.28
373.0554810	0.70
377.3309631	0.13
379.2324524	0.39
380.2512512	0.32
382.1119995	100.00
383.1589050	33.13
389.7963562	0.39
391.0608826	6.52
396.6335754	0.45
397.3839722	0.18
409.0758972	56.13
409.6942139	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1017
Annotation	Melicitrin
Peak:m/z	Relative Intensity
303.1007996	100.00
304.0936890	0.05
330.9517212	0.04
331.6240845	0.05
333.1701965	0.02
345.2832642	0.64
357.1404419	0.04
365.3873291	0.02
369.2318726	0.52
384.3081055	0.04
399.2209167	0.62
411.2554016	0.14
429.2476196	0.21
447.1628723	1.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0474
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
163.8977051	0.01
177.0710754	0.04
192.9489441	0.18
211.0557251	2.78
216.2141724	0.01
241.0786438	1.02
258.9894714	0.03
273.0911865	0.07
280.1687622	1.02
305.2473145	0.11
315.1674805	0.04
321.2061157	0.50
323.1154785	100.00
385.1321411	2.00
397.0184326	0.01
403.1130371	2.36
467.1887817	0.40
478.9110718	0.17
480.8912964	0.09
520.5480347	0.02
546.7543335	0.08
547.3621216	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.23
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0503387	0.07
205.0096893	0.07
207.1296997	0.04
223.3985596	0.34
231.2029266	0.92
247.3300934	0.06
249.1221008	11.88
267.2014771	16.09
283.1958618	0.42
293.1466675	0.09
297.2772217	2.05
299.0964966	0.07
304.2771912	0.18
307.2130737	0.03
315.1948242	0.76
317.2425537	0.06
323.2851562	0.25
331.5640869	0.09
347.3963623	0.07
360.9659424	0.16
369.4256592	0.13
370.3500977	0.11
374.2175903	0.50
375.3173828	0.08
379.3175659	0.04
393.4270630	0.07
411.3524170	2.99
429.3919678	43.12
431.1905518	0.35
434.2974854	0.05
435.1896362	0.09
437.4389648	0.06
441.3624268	0.08
447.0315552	0.32
455.2935181	5.97
461.3443604	0.37
463.4671021	0.05
469.1142578	0.03
473.2866821	100.00
473.9194946	0.21
477.4173584	0.07
479.0894165	0.15
485.3635864	0.39
489.6025391	0.18
491.3032227	85.90
491.9540405	0.43
497.7006836	0.05
504.2583618	0.06
513.2481079	0.12
515.3724976	0.17
521.1361084	0.10
526.3679810	0.06
533.1797485	2.20
539.3977051	0.10
545.0878296	0.06
547.4180908	0.20
553.7662964	0.04
554.4169922	0.16
558.7988892	0.27
561.1111450	0.44
563.3214722	0.88
565.6433105	0.31
570.2526245	0.06
572.3831177	0.08
577.0901489	0.09
586.3706665	0.14
590.9858398	0.14
593.3608398	4.84
606.7534790	0.23
607.3963013	0.27
609.2375488	0.18
617.3718872	0.87
621.6355591	0.05
623.3781738	0.14
625.3579712	0.04
627.9003296	0.20
630.8472290	0.26
633.3422241	0.32
635.3873901	7.44
643.6991577	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.1279
Annotation	Luteolin 7-(2''-glucosyllactate)
Peak:m/z	Relative Intensity
302.0576172	0.07
315.3112183	0.01
317.1444702	100.00
318.1715088	18.93
319.0124512	0.00
328.4525757	0.02
379.1843872	0.01
438.4940186	0.02
498.4938354	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1347
Annotation	Syringin
Peak:m/z	Relative Intensity
145.0876007	0.10
149.0818024	9.03
159.1333618	0.09
161.0640411	0.33
162.9031677	0.09
164.1443176	0.05
178.8655090	0.14
180.8261719	0.25
191.0851898	0.63
192.1286926	0.13
207.0139923	0.08
209.0798035	100.00
233.3438721	0.12
239.1124573	0.05
249.2009888	0.03
251.2752075	0.36
285.2427979	0.04
298.9313354	0.07
308.0846558	0.08
310.9801331	0.04
324.6408081	0.09
326.1718140	10.72
327.2900085	1.74
353.3358765	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0927
Annotation	5-Hydroxy-6-methoxy-3',4'-methylenedioxyfurano[2'',3'':7,8]flavanone
Peak:m/z	Relative Intensity
127.9276276	0.02
143.2233734	0.04
165.1592407	0.01
173.0352478	0.01
191.4874573	0.03
193.6410370	0.05
197.0232391	0.11
207.8209076	0.03
209.2658539	0.11
210.1680603	0.02
219.2012329	0.05
229.3546448	0.04
231.1473083	0.04
233.2935486	0.01
235.3447571	0.01
239.0550537	0.02
244.4415283	0.03
246.0566406	0.02
247.2981567	0.03
256.3992920	0.02
258.1288757	0.01
273.0360718	0.04
274.7847900	0.01
275.4275513	0.03
276.3858643	0.01
281.3010254	0.05
285.1901855	0.02
289.0846558	0.02
290.5847168	0.01
293.6225586	0.04
294.4569702	0.04
295.5205383	0.02
297.4410400	0.04
299.3878174	0.05
301.5755005	0.02
303.3493652	0.02
308.1036987	0.03
309.2210693	0.10
315.3754578	0.00
321.6125488	0.02
323.2792969	0.07
324.1823425	0.03
325.3396301	0.05
328.4766846	0.01
338.3117676	0.10
339.2154846	0.17
340.2654724	0.13
341.2141418	0.24
342.1085815	0.02
343.2287598	0.01
349.3350525	0.11
349.9409790	0.01
353.1770630	100.00
354.2561340	0.05
355.6763611	0.17
357.3222046	0.07
367.1613464	0.64
367.8586121	0.01
369.1490784	0.07
370.2102661	0.31
386.0944519	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1191
Annotation	3,4,5-Trimethoxyphenyl glucoside
Peak:m/z	Relative Intensity
111.0462265	0.04
124.9017029	0.06
128.9590454	0.07
137.1654663	0.06
138.1862335	0.23
138.9801025	0.23
141.0072327	0.04
142.8858337	0.06
150.3806305	0.05
152.1753235	0.11
152.9862061	0.09
154.1236572	0.12
160.1108398	0.03
161.1224060	0.33
162.4403992	0.24
163.0528564	0.57
163.7665100	0.09
164.9962769	0.97
166.9574280	0.04
173.0910797	0.22
179.0522461	0.98
180.0186768	0.46
181.1482849	0.74
182.0496216	0.68
183.0519562	0.96
184.0429382	0.68
185.1691742	0.04
191.1205750	2.55
193.1312561	0.28
193.9915161	0.07
195.0707703	0.18
203.1967010	0.14
204.9408264	0.12
205.9932098	0.29
207.1768646	0.42
208.1926270	0.32
209.3090668	0.09
211.0034637	0.15
217.2537231	0.06
219.2977600	0.05
223.1021423	0.11
223.8798218	0.13
225.2845154	0.22
233.1850586	0.30
235.2541199	0.17
236.1614380	0.15
237.0084534	0.09
239.0656128	0.04
241.3953247	0.11
243.1137695	0.13
255.1786194	0.20
256.0936890	0.04
259.3514404	0.30
262.3302002	0.05
274.1928101	0.06
280.1412354	0.39
280.8980103	0.26
281.9750061	0.14
283.0998535	0.12
285.1671753	0.13
286.9303284	0.09
298.0166626	1.31
299.2120361	100.00
300.0315857	0.33
301.2233276	0.73
302.0975647	0.09
309.1345215	0.06
313.0508423	0.10
315.3417969	0.28
316.3618469	0.17
317.3398438	0.10
322.5932922	0.06
326.7290039	0.51
327.3965759	0.22
328.1307983	0.06
330.2017517	2.51
335.9744873	0.23
337.2162476	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1038
Annotation	Castamollissin
Peak:m/z	Relative Intensity
139.1278229	0.06
149.2812805	0.01
151.0450287	0.90
152.2007751	0.04
153.0744629	0.39
161.9331970	0.06
163.0511169	0.11
164.1471405	0.03
165.2150574	0.10
167.0380554	0.01
169.1410828	0.25
177.2848053	0.04
179.0610046	0.52
179.8775482	0.10
181.0347748	0.13
187.2187195	0.04
191.1209564	0.17
192.0267944	0.03
193.0993347	0.08
196.9754333	0.03
203.1240540	0.02
204.1003113	0.05
205.1383972	0.07
206.2246552	0.03
207.1479340	0.16
208.1706543	0.04
219.1549072	0.34
219.8709869	0.03
221.1691895	0.02
221.9078674	0.01
231.1034393	0.12
232.2616577	0.01
234.1241608	0.83
235.1952515	0.20
237.3580475	0.05
238.1426392	0.02
241.2748871	0.04
243.2275085	0.03
244.2885437	0.04
246.1153564	0.11
247.1322327	0.27
249.1806335	0.03
254.1993103	0.02
255.3596497	0.02
256.1535034	0.06
257.1260986	0.01
258.3226624	0.07
259.1795654	0.09
260.0007019	0.05
260.9205017	0.03
263.1298828	0.03
264.1229858	0.07
265.0940857	0.06
267.2252197	0.02
269.1221924	0.11
270.4394836	0.05
271.1827698	0.03
272.0932922	0.02
273.1593933	1.74
275.3601685	0.06
277.3092346	0.12
279.1477966	0.05
280.2320251	0.02
281.2338257	0.07
283.0110168	0.05
284.0570068	0.04
285.2145081	0.03
286.9036560	0.23
287.7023315	0.01
289.3234558	0.05
290.5661926	0.02
291.2171631	0.14
292.2492371	0.01
295.4130554	0.10
296.4467163	0.02
297.6944580	0.08
299.0780029	0.27
301.1467285	2.65
303.2133484	1.29
304.2270203	0.04
305.1436157	0.05
307.9423523	0.01
309.6163330	0.05
310.2587891	0.03
313.5047302	0.32
314.3567200	0.20
315.2026978	1.51
316.2817993	2.62
317.2559204	0.49
318.2869873	0.03
319.2557373	0.21
325.3141479	0.10
326.1877441	0.04
327.4158325	0.04
328.3128662	0.27
329.1837463	3.58
330.2290344	0.76
331.2681274	0.20
333.1291504	0.08
335.3829956	0.02
338.3104248	0.07
341.3169556	0.27
344.1563721	100.00
345.1695557	20.35
346.2175293	0.04
348.9282837	0.02
351.4418640	0.09
352.1553955	0.05
352.9682617	0.01
354.2223816	0.04
355.2977295	0.09
356.4067993	0.05
357.3958130	0.18
358.2067261	0.25
359.1587219	1.81
359.7668457	0.02
361.4042664	0.05
367.2208252	0.01
369.1346436	0.21
371.3696289	0.16
372.3031006	0.28
373.4146729	0.05
374.2098389	0.15
380.9270020	0.02
383.2685852	0.04
384.3163452	0.09
385.2082520	0.08
387.2109680	12.27
388.3914795	0.08
389.5440063	0.02
391.3413086	0.05
397.2032776	0.04
399.2981567	0.11
400.4804993	0.04
401.4634094	0.03
409.1536560	0.06
411.0515747	0.06
411.6784363	0.01
413.5098877	0.03
417.3206482	2.21
431.3269653	0.04
432.9247437	0.07
433.6277771	0.01
441.0765991	0.12
445.2006531	0.06
447.5254211	0.03
449.2527161	1.14
457.6300964	0.05
459.3190002	0.26
462.2558899	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1611
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
178.9199677	0.24
182.2734222	0.04
183.2028351	0.13
185.7455139	0.05
187.9717865	0.02
189.8428955	0.02
191.0975189	0.04
192.1626892	0.03
197.3192749	0.01
198.2155151	0.02
199.2329559	0.16
199.9691925	0.05
202.9754333	0.08
204.2233276	0.25
205.3537598	0.04
207.2021790	0.07
208.0794067	0.05
211.0122681	0.17
211.9926453	0.03
213.1628418	0.04
214.2478027	0.13
215.1345978	0.05
215.9794464	0.11
217.1594391	0.07
218.9811401	0.07
220.1557770	0.02
221.1426392	0.04
223.0146179	0.02
224.0109711	0.12
225.1488800	0.04
226.1624146	0.06
227.1688995	0.29
228.1766663	0.14
229.1875916	0.06
231.1065979	0.02
233.1303864	0.02
234.1454010	0.02
234.9736481	0.05
237.1224518	0.03
239.1313934	0.03
240.2025757	0.08
241.1496735	0.12
242.9717712	0.97
244.2314758	0.39
245.2807007	0.01
247.1531372	0.37
249.0944824	0.02
250.9858551	0.02
252.3025818	0.15
253.3121948	0.02
254.1408691	0.83
255.1733246	4.44
256.1015625	0.70
257.2909546	0.11
259.2621460	0.39
261.3474731	0.08
267.0939941	0.05
268.2063599	0.12
269.2623901	0.14
270.1574097	0.88
271.1430054	7.54
272.1953735	4.04
273.1790161	0.51
280.0543213	0.03
283.2429810	0.10
284.2271118	0.30
285.1959229	1.09
286.3672485	0.18
287.2586975	2.22
288.2141113	0.35
289.1713867	0.06
290.4710083	0.03
293.4336548	0.06
297.1195068	0.21
298.2513428	0.35
299.1757812	7.05
300.1452942	20.81
301.1358643	3.71
302.1915283	0.07
303.2182617	0.05
307.3314209	0.01
309.1206970	0.05
310.1206665	0.11
311.3772583	0.09
313.2476196	3.12
314.3595581	23.72
315.1599731	100.00
316.1496887	16.87
322.1855164	0.02
324.3334351	0.03
325.3110352	0.19
326.2387085	0.08
327.2435913	0.43
328.0904541	0.43
329.2725830	1.04
330.3276978	0.17
331.0997925	0.02
333.2635498	0.05
335.2203979	0.03
336.1466675	0.06
338.5234985	0.03
339.2556152	0.11
340.1250610	0.01
341.1818848	0.08
342.2192993	0.58
343.1981812	0.30
344.1287842	0.06
353.3219604	0.06
354.2481079	0.02
355.2676392	0.11
357.1460571	7.75
358.2283936	1.61
367.1450806	0.19
368.3730469	0.16
369.2267456	0.21
373.1031494	0.03
375.3508911	0.03
381.4288940	0.07
382.2982788	0.09
385.2992554	0.02
387.1478882	1.31
388.1257324	0.42
395.1847534	0.02
399.1456909	0.12
400.2349854	0.13
406.3289185	0.06
409.2805176	0.02
413.3856201	0.03
415.5489502	0.11
417.5200806	0.04
419.4115601	0.25
423.1926880	0.05
427.5502319	0.05
431.2415771	0.03
441.2355347	0.16
442.3032837	0.05
443.1494751	0.03
447.1627808	0.10
455.0933228	0.03
459.4393921	0.09
460.5374756	0.02
461.5336914	0.05
463.2714233	0.38
464.3322754	0.03
471.1769409	0.05
472.4238281	0.04
477.2233276	0.69
478.2343140	0.15
479.3450317	0.04
491.2814941	0.02
494.0352783	0.02
498.4717407	0.04
501.2409058	0.28
502.4666748	0.10
513.4119263	0.05
527.3314819	0.02
534.1885376	0.08
537.3705444	0.08
547.5183105	0.04
555.3435059	0.13
563.4959106	0.10
567.6007080	0.08
573.4188843	0.06
574.2715454	0.01
577.2407837	0.15
578.2281494	0.03
579.8062134	0.02
587.5403442	0.02
588.3383179	0.07
591.3306274	1.30
592.3818970	0.56
593.4765015	0.25
595.3597412	2.06
596.3899536	0.64
604.7012329	0.05
605.4143677	0.13
606.5183716	0.14
608.3319702	0.63
609.1713257	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.2865
Annotation	Shimofuridin A
Peak:m/z	Relative Intensity
209.2030792	0.22
244.1731262	0.05
249.1758118	0.08
267.1279907	0.14
275.0719604	0.05
281.2167358	0.07
295.4431763	0.17
297.1155090	0.09
301.2189636	0.02
309.2280884	0.11
311.1652527	0.05
312.1495361	0.36
313.3294067	0.75
322.9729309	0.05
327.3018188	27.23
329.1694031	0.03
338.2883606	0.21
341.3238525	2.22
343.4677124	0.22
354.8163452	0.02
357.5997314	0.03
363.0735474	0.03
379.2493896	0.02
391.7428589	0.11
397.7003784	0.07
405.1881714	0.08
409.3156128	0.11
420.3950806	0.06
429.3498535	0.09
433.5430908	0.04
435.1397095	0.02
440.8685913	0.04
447.3132324	0.03
452.3224487	0.03
461.2276001	0.03
473.1929932	0.03
474.3690186	0.31
475.1757202	0.06
478.5231934	0.04
489.3972168	100.00
491.4617920	0.07
493.6708374	0.03
495.3176880	2.11
498.7415771	0.04
501.2214966	0.02
503.3369751	7.78
503.9529419	0.02
505.2036133	0.11
507.2039795	0.22
509.3837280	0.05
517.3681030	0.07
519.2841187	0.21
520.7054443	0.05
522.2841797	0.04
523.4763794	0.07
525.4359131	0.08
531.5095215	0.09
537.3661499	11.14
541.3224487	0.10
543.7064209	0.06
547.3388062	0.08
549.4718628	0.07
551.5288696	0.05
558.2700806	0.03
567.2184448	0.13
573.3690186	0.02
581.1090698	0.03
596.3487549	0.12
609.5725098	0.07
613.2993774	0.16
617.7003784	0.02
623.6445923	0.09
628.2561646	0.22
639.0664062	0.12
646.5460815	0.15
648.4658813	0.05
653.2031250	0.76
654.5997314	0.23
655.3705444	0.44
660.3126831	0.12
662.3928833	0.14
663.8267212	0.03
666.4249878	0.04
667.6447754	0.12
668.5510864	0.06
669.4523315	0.04
677.3548584	0.33
679.3075562	0.16
680.6788330	0.23
681.2994385	0.41
682.0617676	0.14
683.4506836	0.24
684.4074097	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.2386
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
185.0494995	0.14
192.1369934	0.14
209.1177216	1.71
211.0233002	0.09
213.0747986	0.40
220.1676025	0.03
234.1908875	0.08
260.8924561	0.04
272.0350342	0.04
281.0335999	0.02
287.2185059	1.44
290.1732788	0.05
291.2889099	0.09
305.1968994	2.24
306.2097168	0.04
308.2725830	6.49
317.1742554	4.51
322.3204346	0.05
332.9969482	0.06
336.1528931	0.10
349.0377502	0.03
350.2889404	1.01
357.9580078	0.05
360.6436157	0.04
365.1357117	0.02
371.4463806	0.04
386.0075684	1.11
387.3361511	0.04
388.3586731	0.70
399.3277283	0.02
404.3065796	22.81
405.4291382	7.24
414.1734314	2.26
414.9926147	0.09
421.2964172	5.40
422.0075684	0.01
432.2634583	100.00
434.5275574	0.10
450.0981750	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2286
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
152.9801483	0.01
167.1262207	0.01
173.0428009	0.04
178.9943848	0.06
179.9322205	0.01
219.2106628	0.01
223.3009491	0.02
225.3467560	0.02
227.1214294	0.01
229.1976471	0.04
235.4072571	0.02
241.2543793	0.02
243.3192749	0.03
256.3668213	0.01
259.2257996	0.01
261.4334106	0.02
271.1162720	0.13
281.1246643	0.03
283.3594055	0.01
286.2652283	0.01
289.4361877	0.02
290.1449280	0.01
291.3066406	0.01
293.3578491	0.00
295.1813049	0.01
299.2447205	0.01
311.3831482	0.01
315.1853333	0.47
316.3899536	0.03
325.0967407	0.01
329.3807678	0.01
330.5010376	0.01
331.1534119	0.20
332.2617188	0.19
333.4211426	0.02
337.3223267	0.03
341.2003174	0.05
346.1353760	0.01
347.0997925	0.01
355.2418823	0.02
369.3199463	0.14
377.5268555	0.07
399.4354248	0.09
404.0448303	0.02
405.9279785	0.04
407.3557434	0.05
414.3849487	0.04
423.3348999	0.01
431.4522400	0.04
436.2227478	0.01
448.2731628	100.00
449.4017334	3.19
450.5940857	0.07
451.3796082	0.08
458.8818054	0.01
462.1776733	0.01
464.2229919	0.04
468.0520630	0.01
473.4019165	0.01
474.4215393	0.03
475.5940552	0.05
476.3146057	0.12
477.4152527	0.22
479.1862488	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.03569794	0.03
94.82326508	0.03
102.67659	0.23
104.1632538	0.22
104.8732452	0.09
107.0603485	0.07
108.0578003	0.12
122.8735504	0.20
123.9650879	0.14
127.0947113	0.04
128.9347992	1.43
130.0045624	0.48
134.1464233	0.04
135.1214752	0.05
138.0264893	0.11
141.1778412	0.10
142.0529022	0.29
143.0588531	0.12
148.0928955	0.09
149.1212921	0.05
150.9568939	10.08
152.0310211	3.86
152.9510956	0.14
155.9712372	0.04
157.160965	0.08
158.2136688	0.04
160.8950653	0.03
162.1388397	0.04
163.0511627	0.05
165.0756989	0.08
166.0988007	0.24
166.9984436	0.16
168.2773438	0.11
169.0576324	0.07
170.0600891	0.04
171.2403259	0.04
172.0762634	0.27
175.8661652	0.06
179.1094971	1.20
180.2272034	0.19
182.1838074	0.06
183.9650574	0.18
185.0228729	0.41
186.2065735	0.25
187.1513824	0.04
195.1835175	0.25
196.2892914	0.05
196.9517059	0.31
198.1146545	0.93
199.1823273	0.03
200.0679169	0.03
206.1542816	0.18
206.8758545	0.06
208.1072693	0.26
209.2796326	0.10
210.0961151	0.21
211.0750275	0.08
212.050705	0.23
217.5490417	0.31
218.2957001	0.06
219.0888062	0.03
225.0566254	0.27
226.1321411	1.40
234.1104736	0.08
235.6889191	0.47
236.3554077	0.44
237.5352325	0.16
238.2283173	1.38
239.169754	1.18
240.161438	0.17
251.2093506	0.38
253.0808563	100.00
254.1075439	6.74
254.7257538	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2711
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1520844	0.02
160.6376953	0.07
161.2511749	0.05
164.1236115	0.10
165.0399170	0.22
167.3077545	0.04
191.1415100	0.40
192.0419312	0.15
193.1203918	1.10
194.0300903	0.10
195.2961731	0.04
197.0353394	0.09
205.3605042	0.06
206.9743042	0.07
217.2373505	0.05
218.2948456	0.02
219.8853760	0.09
220.6573334	0.05
235.1606903	0.03
236.2894897	0.02
239.2634888	0.15
245.3086548	0.04
246.4100800	0.07
247.0663452	0.15
251.2504730	0.11
255.1201477	0.07
259.1398315	0.44
261.2370605	1.10
262.1325073	0.07
263.2834778	0.02
267.0750122	0.07
268.2095337	0.05
272.2868652	0.03
288.2599792	0.02
293.2368164	0.39
295.0496521	0.15
297.3853149	0.06
299.2943726	0.06
301.1407471	0.25
303.2494507	0.68
304.0716553	0.11
311.0697021	0.98
313.1646118	0.17
314.2019653	1.27
315.2689819	0.30
319.2219238	0.10
321.1364136	0.02
327.6365967	0.03
329.2109985	21.26
330.2205811	3.78
331.2179565	0.08
333.5810547	0.05
345.4223022	0.05
347.1608276	29.66
348.2686768	4.25
353.4656982	0.10
355.3430786	0.13
356.4779663	0.04
357.3806763	0.02
359.3381348	0.02
363.3045044	0.04
365.3656006	0.06
369.2512207	0.08
371.2413940	1.97
372.3654175	0.26
373.3392334	2.32
374.4102783	0.51
377.1423340	0.04
389.2573242	0.34
390.8731689	0.02
397.2083130	15.85
398.2993164	2.34
401.2140503	0.57
402.2024536	0.13
404.3195801	0.04
405.0356445	0.13
419.1235962	0.16
420.4132690	0.16
432.4340820	0.03
437.3510742	0.10
445.3353882	0.05
447.4317017	0.06
450.4931641	0.04
457.3572998	0.05
461.6359863	0.02
465.4232788	0.10
491.1390381	0.17
503.1677246	0.03
505.2907104	100.00
506.3713379	8.37
507.1831665	0.08
508.4052124	0.10
516.3546753	0.05
533.1742554	1.16
534.4437256	0.43
536.5122681	0.06
542.3932495	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.0909
Annotation	Methysticin
Peak:m/z	Relative Intensity
78.8267822	0.16
98.7739105	0.08
106.9162903	100.00
108.7159882	0.05
113.1175003	0.09
118.3994141	0.08
120.8729095	0.83
126.9361725	22.26
129.2034302	0.09
142.1492920	0.10
142.9862366	0.16
146.8190613	0.14
148.8647766	41.29
151.0524597	0.10
154.9167786	0.34
159.2014465	0.14
162.4539032	0.03
165.0190735	0.21
168.9690247	35.21
170.9784851	0.26
172.1652527	0.09
175.1253357	0.10
176.1763153	0.04
177.1112061	0.05
178.8147888	0.05
181.0977173	0.37
183.4233093	0.05
184.9656982	0.20
187.1288452	0.08
188.9609222	0.07
193.1755676	0.13
194.1322021	0.44
197.0288696	0.27
198.9819031	0.03
202.2810059	0.05
203.2045593	0.22
204.0771179	0.21
209.1439514	0.02
215.1007385	0.22
217.2396851	0.23
228.0208740	0.09
229.2607727	0.19
230.1679382	0.17
233.0419006	0.52
233.9246216	0.32
239.3114319	0.16
243.7819214	0.07
245.4425354	0.18
246.9545288	0.15
251.6474609	0.05
256.4628601	0.98
257.1636963	3.52
258.1891479	0.29
260.2865601	0.10
265.1447754	0.04
266.6428223	0.04
273.7872314	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.1868
Annotation	Cypellogin A
Peak:m/z	Relative Intensity
179.0278931	0.40
179.7943420	0.05
183.2312164	0.10
187.1336670	0.05
189.0968933	0.06
189.9866180	0.08
191.8955536	0.06
192.9719543	0.09
195.1270447	0.05
198.9769897	0.10
201.0368652	0.10
203.1907654	0.04
205.1170349	0.08
206.9148865	0.10
209.1376038	0.04
210.1764526	0.05
211.1696930	0.05
212.9647369	0.16
214.9647675	0.17
217.0438080	0.28
221.1738586	0.02
225.9557343	0.18
227.2115631	0.54
228.2089081	0.11
229.2449188	0.13
232.9265747	0.09
233.9057465	0.08
237.2660217	0.08
239.5083160	0.06
240.1824036	0.07
241.4266052	0.04
242.1252899	0.08
243.3773804	0.21
244.1532898	0.07
245.1568909	0.12
247.2497253	0.09
249.0844116	0.03
250.9734802	0.11
253.2232666	0.06
255.1587219	4.36
256.1853027	0.94
257.1799927	0.12
264.2678223	0.14
266.3016968	0.08
268.9496765	0.03
271.1759338	7.05
272.1784363	0.94
273.1452026	1.03
274.2047119	0.21
275.0879517	0.04
279.1950073	0.08
281.0873413	0.19
283.2386475	0.26
285.1797485	0.18
293.2490540	0.11
295.0427246	0.24
296.6092529	0.12
297.3444824	0.13
299.0590820	2.27
300.1375732	39.90
301.1463623	68.99
302.2166138	8.51
311.2388306	0.13
313.1444702	0.20
314.2773438	0.09
319.1363525	0.06
319.9489136	0.12
322.1902466	0.11
325.1907349	0.47
326.1991272	0.13
327.1047668	0.41
329.1120911	0.09
337.4250488	0.05
339.0848389	0.13
343.0928345	3.21
344.2372437	0.53
349.1954346	0.03
355.1869507	0.29
356.4246216	0.21
367.2745361	0.07
370.9969482	0.07
372.9104614	0.26
373.7002563	0.24
379.1212158	0.05
380.5842896	0.06
382.4309692	0.06
385.2726440	0.16
397.0977783	0.19
399.0616455	0.02
401.2962646	0.03
402.2905273	0.11
402.9686279	0.04
409.0890503	0.06
415.3792114	0.10
420.4605713	0.06
427.1145630	0.28
428.4176025	0.02
432.3439941	0.24
433.3500366	0.59
437.1430664	0.03
445.2403564	4.44
446.2762451	0.96
449.2377319	0.07
449.9872437	0.22
455.5689697	0.03
460.3573608	0.02
461.5113525	0.04
463.2049561	100.00
464.2187500	19.88
464.8643188	0.09
465.7212524	0.02
467.4669189	0.35
468.6467285	0.09
469.5585938	0.04
474.9861450	0.07
476.3555298	0.06
485.2730103	0.20
493.3563843	0.17
495.3346558	0.02
497.3667603	0.08
498.4896240	0.04
503.4082642	0.39
504.4786987	0.03
509.5189819	0.09
510.2802124	0.06
519.2037964	0.15
530.1879272	0.02
533.5054321	0.36
539.2611694	0.06
543.0079346	0.06
553.4234009	0.30
554.3618774	0.03
558.3087769	0.36
559.0787354	0.24
571.1546021	0.10
583.3243408	0.21
584.4634399	0.10
585.3413086	0.30
586.4400635	0.16
590.9718018	0.02
593.9647827	0.13
597.5297241	0.30
598.7503052	0.14
600.2127075	0.02
602.4371338	0.07
611.4975586	1.01
612.4307251	0.87
613.2442017	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1304
Annotation	Kaempferol-3-Glucoside-2''-p-coumaroyl
Peak:m/z	Relative Intensity
171.2206879	0.43
187.1614227	0.22
196.8634338	0.11
198.8182983	0.26
201.1330261	0.27
223.2789001	0.21
224.1116943	1.45
227.3251953	0.46
229.1603699	0.91
255.1430664	0.67
257.1194153	0.85
268.1861267	0.24
285.039093	100.00
285.8601074	0.96
298.9168091	0.18
307.2283936	5.93
310.947998	0.26
327.0615845	0.41
330.2774048	0.18
341.6157837	0.37
345.1625366	0.37
357.0528564	0.23
366.4674683	0.21
367.3725586	0.72
371.3116455	0.15
375.3430176	0.09
380.4625854	0.58
389.4490356	0.18
393.2457886	0.77
398.0637207	0.91
411.2232056	0.25
414.6756592	0.14
421.3643188	0.35
422.2675781	0.18
425.3787231	0.17
428.4606323	0.46
429.347168	1.27
431.3768921	1.37
441.2003784	0.58
442.2002563	0.32
445.0783081	0.69
447.1434937	12.39
451.4193726	0.35
459.901062	0.17
471.3571167	0.34
479.5232544	0.95
500.8105469	0.15
501.9594727	0.52
503.3899536	1.11
504.8331299	0.45
508.9846802	0.68
530.3579712	0.12
546.3046265	3.12
547.2595825	8.52
547.9280396	0.23
548.6616211	0.28
549.6531982	0.49
551.3928833	0.40
555.2362671	0.42
556.8847046	1.34
557.6282349	0.62
565.2331543	0.17
574.4415283	0.21
575.4492188	2.32
576.2022705	0.18
578.1335449	1.09
583.6790161	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0643921	0.02
149.2777710	0.03
161.0545959	0.13
163.0800171	0.38
165.1683960	0.04
177.1582642	0.37
189.1617737	0.10
191.0310669	0.22
192.9533386	0.05
200.9626007	0.11
204.1207886	0.08
205.1626587	0.30
207.1083374	0.38
216.9394226	0.51
219.1587219	0.16
220.2406769	0.03
221.1339722	0.08
227.0131836	0.06
231.1290283	0.30
233.1328583	0.10
234.2175751	0.10
243.8462524	0.04
246.8794861	0.03
248.3616638	0.03
253.4883118	0.10
256.1149292	0.18
257.1831055	0.12
259.4294739	0.03
261.2200012	0.18
263.1858521	0.03
264.9956055	0.03
267.2515259	0.08
269.0975037	0.12
271.1924438	0.88
272.1216736	0.04
273.2554932	0.55
275.0908203	0.20
277.3328857	0.02
281.3168945	0.12
283.1708984	1.44
284.4165039	0.58
285.2125244	1.18
286.3661194	0.08
289.1215820	0.10
295.2473145	0.29
297.1414795	0.52
298.2338867	0.16
299.3282776	0.48
300.2714539	0.22
301.2197571	0.55
303.2093811	0.40
306.1997681	0.28
307.3250122	0.12
309.2037964	0.17
311.2397766	0.12
313.0975952	1.48
314.1395264	100.00
315.1412354	43.13
317.2527466	0.19
321.1789551	4.80
325.2357788	0.38
326.5324097	0.32
327.2537842	4.31
329.2138977	15.90
337.2778931	0.20
339.1408081	0.51
342.2087097	0.04
343.3441162	0.19
344.1200867	0.06
345.1292114	0.27
352.3575439	0.14
354.3866272	0.11
355.1250916	0.15
357.1454773	6.05
358.6774902	0.14
359.3929443	0.09
361.2763062	0.19
365.8768311	0.05
367.3688049	0.11
369.2063599	2.94
370.4344177	0.09
371.3741455	0.10
379.1255798	0.15
381.3106995	0.08
383.2996826	0.21
387.2836609	3.20
388.3365173	0.06
397.2237244	0.10
399.2310486	0.26
401.2528992	3.54
403.0859375	0.13
411.2113037	0.65
413.9641418	0.04
415.2131653	1.87
429.1627502	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	662.8325
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1634979	0.03
249.2730408	0.06
273.0920715	0.33
275.0948486	0.04
275.8006897	0.05
276.9031372	0.06
289.0837097	2.65
304.9808960	4.34
311.3292236	0.03
363.0812378	0.05
386.7485962	0.07
403.0362549	2.61
403.9600830	0.08
418.9631348	13.98
419.5958862	0.02
434.9909058	4.83
459.0604248	0.02
486.2127075	0.03
501.8319092	0.15
504.0894165	0.03
507.1700439	0.04
508.9090576	0.07
514.9766235	0.04
516.9417114	8.86
517.9315796	1.10
518.6105347	0.04
530.9208374	0.11
532.9042358	9.60
546.9478149	0.36
548.8663940	100.00
549.5421753	0.20
564.9486694	0.08
571.8704224	0.10
573.0253296	0.22
574.2073364	0.04
579.1817017	0.05
585.9543457	0.04
587.2512817	0.16
588.1681519	0.37
589.0207520	0.40
591.7148438	0.02
606.2042847	0.22
607.0370483	0.04
614.9021606	0.07
615.8294067	0.94
616.8779297	1.37
618.7481079	0.33
619.4494019	0.09
621.4262085	0.10
634.1065063	0.06
639.0516357	0.02
643.9032593	0.06
645.1305542	0.09
653.1410522	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1666
Annotation	Fibraurinoside
Peak:m/z	Relative Intensity
158.1056824	0.16
161.0775909	0.56
163.0857086	3.30
165.0094604	1.42
170.9103241	0.15
173.0603333	0.10
175.2069550	0.35
187.0724030	1.29
189.3362579	0.21
192.0463562	0.07
201.1112061	0.13
202.9244385	0.51
204.0682678	0.11
205.1713409	0.29
207.0769348	0.39
211.2847748	0.21
219.0328369	0.52
222.9693756	0.05
225.1409607	25.42
229.1754761	0.61
231.1014404	0.17
233.2982483	0.14
235.0977173	0.06
246.9618530	0.56
249.0304260	0.26
252.0299225	0.18
255.2324982	0.24
259.2868652	0.37
265.3164368	0.31
267.0881958	0.15
267.7229614	0.10
270.3280640	0.25
271.2833252	0.23
273.1371460	0.09
275.1087646	0.06
276.2512207	0.11
281.3110046	0.18
285.2429199	0.93
287.3068237	0.34
289.3086548	0.19
298.9200439	0.20
301.2168579	0.19
307.1784668	100.00
309.1196899	0.15
311.2476807	0.43
313.4125366	0.61
314.2709351	1.16
325.6547241	0.09
327.2744751	1.68
328.1725464	4.10
329.1625977	47.63
331.1054077	0.79
337.2809448	0.19
343.3796997	0.36
351.1823120	0.41
353.3575439	0.59
359.7164917	0.74
362.8231812	0.10
367.4572144	0.12
369.3088379	5.31
370.1237793	0.24
371.3302612	2.02
373.1750488	0.18
379.2988892	0.26
383.1394653	0.98
384.3127441	0.07
387.3317871	65.84
389.3169556	0.07
397.2894897	0.08
400.1514893	0.49
401.1745605	2.90
402.0968018	0.21
411.2172852	0.10
417.7001953	0.05
431.2128906	0.14
433.3820190	0.11
437.3189697	0.37
443.5834961	1.12
445.2500000	0.05
447.3834229	0.06
449.2114868	0.39
455.1795044	1.03
457.2196655	0.15
459.0071411	0.22
469.1536255	0.12
471.3111572	1.05
473.2670288	18.12
475.2145386	0.13
487.1052246	21.79
489.2500610	1.79
491.1898804	0.61
497.2971802	0.97
500.3002319	0.24
501.2569580	0.12
512.9995728	0.83
515.3247681	28.47
516.6414795	0.13
518.5223999	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1067
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
247.1678467	0.04
267.3974304	0.03
287.1300659	100.00
305.3851624	0.02
317.0082092	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1324
Annotation	Melicitrin
Peak:m/z	Relative Intensity
331.1519775	100.00
331.9305420	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.0335083	0.47
93.09195709	0.46
96.98017883	0.74
98.90084839	1.25
107.2138214	0.60
107.8446808	0.21
108.9661407	0.41
110.8452911	1.61
112.7244492	0.56
120.985321	1.67
123.1100464	0.82
124.9265366	0.86
127.0141907	0.19
129.1019287	0.69
135.1021118	2.24
139.0424194	0.98
141.0257568	0.77
143.1272583	1.55
145.1243896	0.97
147.2440643	0.48
149.2533875	0.43
153.0543213	0.81
154.9795532	0.55
157.1516418	0.24
163.144928	2.08
164.9803467	0.76
165.890152	0.26
167.1663818	0.81
169.0830536	1.37
176.9948273	1.82
179.1299133	0.60
181.0394592	2.12
183.0817566	2.29
184.9648743	1.03
187.1785889	0.26
189.3227234	0.39
191.1584015	0.92
192.4562378	0.94
193.1568298	0.33
193.9564667	0.60
195.124054	3.21
197.0263519	1.84
199.3601379	1.35
202.9833374	0.53
205.3833008	0.71
207.1584473	1.06
209.1141663	1.84
211.1987	5.31
213.2242432	1.45
215.4100037	1.47
217.201416	0.69
219.0655212	0.63
221.2302551	1.34
223.1412048	1.60
223.9948425	0.55
225.1134033	1.43
226.4718628	0.99
227.1156616	2.59
229.2214966	0.54
230.9498291	0.36
235.3608704	0.75
236.1977539	0.26
237.2226562	1.09
239.0830383	0.86
241.0649414	0.46
245.3252869	0.24
247.2084961	1.74
248.1278381	0.60
250.1268616	0.40
251.2831421	2.80
253.2394104	6.19
255.1833496	1.35
257.2473145	2.02
260.817627	0.25
264.4616699	0.60
265.3887329	1.23
266.2546692	0.22
267.2214355	1.66
269.272583	0.91
270.2002258	0.72
273.104187	0.33
275.3369141	11.23
277.1079102	0.39
280.7869568	0.41
281.4784851	0.34
283.3589478	4.34
284.2438354	0.44
293.210022	100.00
294.2415771	1.25
296.4340515	1.46
297.4794006	1.47
302.1394348	2.84
310.453064	0.65
311.3558655	0.35
319.1714478	0.19
321.1321411	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.21
Annotation	Unknow
Peak:m/z	Relative Intensity
143.1793365	0.07
148.4113922	0.04
149.0839996	0.15
153.0967712	0.66
159.9470215	0.03
161.0480652	0.06
173.0440674	0.04
175.0532837	0.81
175.8003845	0.09
183.1803741	0.05
187.3957062	0.07
193.0958557	0.47
194.9635315	0.02
201.3717346	0.05
217.1584778	0.48
218.2031555	0.12
220.8022919	0.08
234.9855957	0.08
238.7135925	0.10
243.3666534	0.02
249.2125854	0.27
250.7917786	0.05
255.3477478	0.04
256.5775452	0.14
261.3327026	0.04
263.3489075	0.07
265.1356812	0.05
268.2151794	0.09
277.1185913	0.04
282.0230408	0.13
285.1536865	0.50
286.0289917	0.18
287.3745117	0.24
293.4550476	0.09
297.1931152	0.12
299.1439819	0.05
308.3234863	0.24
310.7492371	0.02
311.3782959	0.19
313.2044678	0.50
314.2439575	0.57
315.3004456	0.27
316.2775574	0.07
319.2203369	0.04
323.1857300	0.29
327.2417297	0.09
328.2832642	1.13
329.3046265	8.56
330.3412476	0.29
337.1600037	100.00
340.7673340	0.05
343.2581787	0.58
344.2286377	0.18
345.0027466	0.03
356.6104126	0.05
363.2269287	0.05
370.1924133	0.27
371.1558228	0.39
383.2017212	0.26
385.4699402	0.02
388.1958923	0.04
401.3598022	0.03
432.2895813	0.15
443.7378235	0.12
445.3519592	51.47
447.3447266	0.14
455.0584717	0.04
459.5885315	0.05
471.3606567	0.04
473.0305786	0.22
476.2173157	12.08
477.3533020	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.13
Annotation	Castamollissin
Peak:m/z	Relative Intensity
148.9523773	2.07
151.2032318	0.08
153.0182190	0.06
157.0217896	0.11
160.1208496	0.08
162.9121246	0.05
164.4221802	0.40
165.1686554	0.57
166.3050079	0.14
167.3724518	0.05
169.1463928	0.07
174.0402527	0.03
174.9367371	0.05
176.9907990	0.10
190.0130920	0.04
191.2852631	0.24
192.1277771	0.24
193.0806885	2.80
197.0758362	0.08
200.2046051	0.07
201.0604553	0.05
205.0212860	0.24
206.0631714	0.05
207.1443481	0.16
208.9460144	0.04
211.2998657	0.02
215.1091309	0.03
217.1754303	0.12
219.1681671	0.21
220.3007355	0.42
220.9831238	0.12
229.4186707	0.06
234.8840027	0.23
237.2426300	0.09
239.0785828	0.30
241.0927887	0.63
242.1815491	1.06
243.2056274	0.15
246.1816101	0.04
247.1018219	0.29
248.2425690	0.09
251.3593750	0.04
259.6763306	0.24
261.1925659	0.77
265.2036133	0.37
268.2834473	0.03
268.8854370	0.05
270.1389771	0.09
272.6073608	0.14
273.4848328	0.22
275.1843872	0.07
278.7769165	0.07
282.4335938	0.09
285.1146240	4.09
286.1826782	4.74
287.1241455	1.76
289.3045044	0.02
292.4627075	0.16
293.3610229	0.20
297.1188354	0.25
299.0243530	0.26
301.4160156	0.05
302.2150269	0.12
303.2869873	1.64
304.1579590	0.29
305.2030640	0.12
311.1575317	0.83
312.9989014	0.11
314.2730103	1.51
315.2492676	0.19
319.1654663	0.96
325.2792358	0.21
327.1362915	0.22
329.1735229	100.00
330.7119141	0.07
331.3345337	0.35
333.5488892	0.25
341.2396240	0.40
343.3163452	0.04
345.2210083	0.70
346.1600342	2.92
347.2363281	29.57
349.3677368	0.04
355.1602173	26.09
359.2965088	0.85
369.1717529	0.07
371.2600098	0.28
373.3364868	0.13
381.1323242	0.47
382.1922607	0.30
383.1826782	0.44
389.3047485	0.21
397.2119141	0.11
398.2913208	0.05
399.3186646	0.20
401.1784058	0.05
403.2055664	0.04
405.5408325	0.04
419.2012939	0.12
422.4026489	0.06
423.2770996	0.22
425.1825562	0.24
431.3770142	0.06
447.0528564	0.07
449.0057983	0.12
463.2819214	26.06
464.4960327	0.35
465.2892456	1.44
491.3083496	3.51
493.3259888	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.213
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9822388	0.53
145.0788879	0.14
145.7840881	0.09
148.9451447	14.06
160.9622498	4.14
163.2842712	0.14
184.8389740	0.26
191.0591278	5.86
203.0227509	0.41
220.5161438	3.84
221.2403107	0.40
234.3267822	0.23
238.9561462	0.99
250.9630432	1.59
259.0466309	0.12
263.0152893	0.16
269.3599243	0.24
275.1228638	0.58
280.9792480	1.52
287.0865479	0.32
293.1807861	5.11
308.2063599	0.19
310.9960938	20.66
311.5973206	0.05
313.2771301	0.43
315.2085266	0.39
327.1737061	0.25
328.1357117	0.46
329.1418152	4.08
336.8874207	0.12
341.2657776	0.15
343.1589355	0.49
345.0205383	0.09
369.0735168	0.12
371.4365540	0.59
372.6527100	0.20
443.3716431	0.31
445.3316345	100.00
459.2791748	0.20
462.2627258	0.22
463.2719421	0.11
471.4794617	0.30
476.3625183	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1395
Annotation	Kadsurenin B
Peak:m/z	Relative Intensity
113.0692291	0.02
120.9505463	0.01
125.1963501	0.02
141.0627899	0.01
149.0829163	0.01
153.1142731	0.03
158.7827148	0.01
166.0782166	0.34
177.6416626	0.01
179.1248322	0.03
181.0976562	0.66
203.7020416	0.01
217.1017761	0.06
219.1759644	0.04
221.3486328	0.01
223.2893677	0.01
229.2158813	0.03
231.0451660	0.04
242.1223145	0.03
247.2697144	0.02
267.1297607	0.01
279.1025696	0.05
282.4513245	0.03
284.2511597	0.02
287.2592773	0.00
294.2317810	0.28
295.1233826	0.02
296.2809143	0.34
297.1972046	0.08
298.3664551	0.19
299.2608948	0.06
309.1981201	3.26
310.2448730	1.51
311.3046875	4.53
313.2509460	0.02
323.6395264	0.02
324.2635803	0.04
326.1533508	100.00
326.7616577	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0929
Annotation	Meliternin
Peak:m/z	Relative Intensity
114.9948578	0.03
133.0873413	0.04
134.0965271	0.16
145.0577698	0.03
161.0509033	0.48
173.0237732	0.17
178.1552734	0.14
183.2334595	0.04
186.8902740	0.05
193.0503540	100.00
204.0511475	0.16
205.2212372	0.03
217.2811432	0.02
222.9884186	0.09
226.8012390	0.06
228.1224365	0.08
229.2982788	0.03
238.2223816	0.03
247.3053284	0.04
249.2649841	0.09
257.2926941	0.04
269.2332764	0.09
273.1374512	0.08
283.3153992	0.18
284.2133484	0.06
291.3050537	0.03
293.5604858	0.02
294.5877075	0.02
295.4001160	0.03
299.1819763	0.09
301.0495911	0.10
307.5576172	0.03
311.0513916	0.10
311.6836243	0.04
313.4398193	0.05
325.4100952	0.24
327.5748291	0.16
328.9607544	0.02
338.0753784	0.09
339.2219238	0.14
340.5386658	0.18
341.2711182	0.75
344.2019043	0.11
345.0384521	0.14
348.3040161	0.07
349.1384277	0.24
353.2005005	0.13
354.9043884	0.05
355.6076965	0.03
357.1007385	0.02
366.4372864	0.07
367.4280090	2.20
369.2840271	0.49
370.2952576	0.94
371.2215271	0.17
375.4636536	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.3539
Annotation	Unknow
Peak:m/z	Relative Intensity
188.9002838	0.15
193.1519928	0.08
211.1387482	5.26
235.0009766	0.05
253.2441254	0.50
256.2506409	0.04
263.5240173	0.04
273.2233276	0.02
279.3481750	0.14
311.3512573	0.05
321.5339355	0.06
335.3635864	0.04
359.4201050	0.05
377.4090576	0.62
380.3275757	0.04
381.6080933	0.03
387.4813232	5.08
405.4820557	1.79
411.2965698	0.05
413.1199951	0.17
419.1196289	0.20
421.0671387	0.10
424.0859985	0.05
425.1734009	0.25
429.4937134	1.65
438.6540527	0.08
443.5366821	0.06
446.5880127	0.08
447.2737427	3.63
448.0042114	0.01
461.3887329	0.25
466.6196289	0.07
471.4416504	0.07
473.5565186	0.03
475.3421631	0.13
476.2745361	0.11
477.8529053	0.12
479.4946289	0.24
481.5614014	0.14
487.6530151	0.04
489.5056763	0.05
493.3854980	0.04
501.2045898	0.14
531.3347778	0.22
533.5249634	0.05
535.1925659	0.25
536.1257935	0.15
551.3969116	0.14
557.3666992	0.06
559.1704712	0.04
562.2712402	0.04
568.2258301	0.20
569.9423218	0.05
573.2101440	0.02
575.7335815	0.04
578.8937988	0.06
581.5347290	0.11
595.1055298	0.43
595.7877808	0.16
597.5344849	2.15
604.8220825	0.03
605.5097046	0.25
623.4749756	100.00
624.0983887	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1066
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
287.1271362	100.00
287.7799683	0.17
289.3510132	0.02
305.2093506	0.04
317.2329712	0.03
329.4351807	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
130.9919434	0.02
161.1875305	0.02
178.8538208	0.04
206.9347839	0.01
250.9413452	0.11
258.0795288	0.02
341.2101440	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.15
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1101074	0.23
151.0962524	0.04
160.9180145	0.13
162.9008484	0.15
165.1454468	0.24
167.0979309	0.52
172.7814636	0.05
177.1484070	0.87
178.0158386	0.23
179.2739868	0.22
188.0888214	0.07
189.1016846	0.12
190.9974365	0.53
193.0699158	0.25
195.1458435	3.67
208.1677551	0.21
209.1515961	0.03
210.8583221	0.30
213.1332092	0.10
217.1642609	0.06
219.0998230	5.28
221.1544800	0.23
223.2324982	0.90
230.9739075	0.13
237.1208191	0.11
238.9159851	0.04
245.2510986	0.30
249.2067261	1.06
255.0157776	0.32
256.7441711	0.05
257.3773499	0.22
261.1744385	0.27
263.2911377	0.08
265.3834229	0.16
266.9003296	0.09
269.3074341	0.07
270.2593384	0.10
271.1356201	0.26
272.2854614	0.15
273.3947144	0.44
279.1593628	0.42
281.0269165	0.16
283.2122192	0.03
284.1586914	0.11
287.4216919	0.41
291.0601807	0.07
293.4464111	0.25
295.3109131	0.14
297.0932007	0.06
299.2070312	10.51
301.2946777	0.04
303.1817017	1.40
305.4184570	0.25
309.2951050	0.06
313.1237183	0.37
316.2273560	0.16
321.2517090	0.09
329.3285522	0.39
331.1674194	100.00
339.1134033	0.41
341.3958740	0.11
345.2805786	0.20
348.7212524	1.96
349.3296509	26.28
355.2741699	2.35
357.1820679	37.60
358.1729126	0.18
359.1422729	0.08
371.2328491	0.08
373.1643066	7.64
379.3490601	0.19
382.1226807	0.09
385.1580811	0.33
387.4803467	0.06
391.2181396	0.31
394.2425537	0.07
403.2532349	0.87
405.3869629	0.05
414.4832764	0.11
415.2593994	0.80
417.4453735	0.09
420.9161987	0.14
423.5142822	0.04
430.3630371	0.04
437.2002563	0.15
439.1928101	0.05
445.4041748	0.24
447.3522949	0.04
449.0697021	0.39
451.4265747	0.12
452.1932983	0.04
453.4263916	0.05
457.2091064	0.40
461.2691650	10.69
464.4726562	0.06
465.4314575	0.14
466.2573242	0.35
467.5440674	0.25
475.4816284	0.07
480.6445312	0.11
481.5774536	0.14
493.2477417	14.67
495.2359009	0.10
501.9219360	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Unknow
Peak:m/z	Relative Intensity
132.0676880	0.03
133.1378479	0.02
134.7483368	0.05
136.8868561	0.06
143.1595612	0.08
144.1805420	0.02
145.2570953	0.03
145.8785400	0.04
151.0419159	2.33
152.1650391	0.16
153.0668945	0.35
158.9597931	0.07
161.2175140	0.12
162.9308777	0.32
163.9800110	0.08
165.1908417	0.30
167.2568665	0.03
169.0794525	0.22
171.0339203	0.03
173.1620636	0.16
174.2717285	0.26
175.2014160	0.28
177.0624390	0.20
179.0716553	1.07
180.0083923	0.09
181.0212097	0.23
183.0545959	0.13
184.9571533	0.14
187.1392212	0.13
189.0722961	0.18
190.1755066	0.10
191.1699829	0.18
192.0290222	0.05
193.0825806	0.31
196.2151184	0.03
197.2125397	0.06
199.2186279	0.10
201.2929535	0.13
203.2498474	0.16
205.1087189	0.26
207.0929413	0.19
208.1335449	0.13
209.1292725	0.09
211.1571350	0.29
212.1527405	0.13
212.9918060	0.13
215.4262085	0.03
216.0740662	0.06
217.1031494	0.42
219.0771484	0.21
219.8997192	0.05
221.0270996	0.04
222.9722748	0.10
225.1939087	0.22
227.1183777	1.53
229.2383423	0.18
231.1940308	0.08
233.2399445	0.09
236.9374084	0.20
239.1459351	0.29
240.4446106	0.11
241.2235413	0.43
242.3107910	0.37
243.2374878	0.90
245.2770996	0.01
249.0159302	0.08
251.2575378	0.10
253.1976013	0.12
255.1354980	9.06
256.1770630	1.75
257.0963745	3.55
259.3015747	0.12
261.4148865	0.04
265.3176575	0.12
266.1279602	0.14
267.2170105	0.38
269.2017822	1.17
271.1556396	0.19
273.2549744	0.10
279.2312927	0.10
280.4567261	0.03
281.1368408	0.29
282.2675171	0.04
283.4437256	7.12
284.1325073	100.00
285.1150818	74.47
286.0245361	0.04
287.1740112	0.03
289.3310242	0.03
295.2459717	0.30
296.1773987	0.11
297.2893677	0.58
298.0895386	0.14
299.2271729	2.56
300.9713135	0.02
307.1658325	0.33
309.2390747	0.22
313.2586670	0.08
314.1741943	0.54
315.2734375	0.12
321.3641357	0.07
323.2615356	0.07
325.1531372	0.02
327.2211304	18.31
328.9838257	0.17
329.5988159	0.04
338.4490662	0.07
339.2434082	0.55
340.2005005	0.05
341.0850525	0.05
350.5985718	0.11
351.2889404	0.07
353.2514038	0.12
354.3092041	0.08
355.2294922	0.10
356.2510986	0.03
357.1999207	2.39
358.2631836	0.02
359.3711548	0.08
361.1467896	0.06
363.0895996	0.09
367.3591614	0.03
369.1436768	0.29
371.3833313	0.15
373.0536194	0.03
375.2224731	0.09
379.2340393	0.13
381.1908569	0.08
383.0575256	0.04
385.3860779	0.04
386.3550110	0.05
387.2544861	0.22
391.1336670	0.04
393.4682007	0.08
401.4331360	0.03
402.7360229	0.03
403.3569641	0.81
405.2739868	0.04
413.4884338	0.05
415.9614868	0.03
419.3601379	3.01
420.6608887	0.03
428.3289185	0.07
429.2630005	0.41
430.5846558	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1487
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9752045	0.32
165.0718842	0.95
166.0111694	0.15
169.0193481	0.15
173.1395721	0.27
175.1936493	0.05
177.0461426	0.02
178.8774872	0.09
182.0209198	0.05
182.8680725	0.14
184.8426514	0.06
187.1047974	0.30
188.3202820	0.11
189.2767792	0.03
191.1088715	0.11
193.1444702	0.18
193.8550262	0.12
197.4950409	0.15
201.1412659	0.74
203.0552063	0.03
205.0659027	0.17
207.5478668	0.04
213.0545807	0.05
217.1370850	0.08
219.0816803	0.09
225.2225037	0.32
226.0996094	0.13
228.7006836	0.18
229.3243103	1.36
230.0330505	0.03
231.1798248	0.21
233.1419830	0.37
241.2392578	0.07
243.1688690	1.02
247.0813904	21.66
248.1085510	2.67
249.2872314	0.07
253.0037231	0.20
255.1679993	0.04
257.1071777	0.37
259.1958618	4.09
260.3024902	0.61
261.2539062	0.38
269.3450623	0.21
271.0955505	8.44
272.1685791	0.81
273.1133423	1.38
275.0583496	5.41
276.1165161	1.14
283.1086731	1.39
284.4557495	0.58
285.2333069	0.39
287.1361694	2.04
289.0915833	23.74
290.0635376	2.15
291.1540222	55.68
292.2399292	4.86
295.1128540	0.09
299.1593018	0.78
301.0930176	14.19
302.2048340	3.40
303.2193604	7.44
304.2625122	1.44
309.1541748	0.05
311.0285339	0.10
313.1298218	0.84
315.2559204	0.30
316.3330078	0.35
317.1943970	0.07
324.9960938	0.05
330.1456909	0.04
331.5043945	0.23
333.1108398	1.89
334.3276978	0.14
349.1237793	0.15
381.1876221	0.12
386.3327637	0.04
389.2412720	0.13
393.0908203	0.09
394.3048706	0.10
405.5766602	0.10
407.1366577	0.18
409.1886597	53.61
410.1882324	12.18
411.2450562	11.29
412.1815186	1.74
417.8152466	0.10
418.4366455	0.06
420.4946899	0.08
421.0949707	2.40
421.8162231	0.25
422.4197998	0.45
423.2415161	0.47
425.6055908	0.06
427.1296997	100.00
428.2254028	19.72
433.4368896	0.07
435.2422485	3.10
435.8847656	0.13
436.5131226	0.34
439.1692505	4.70
440.0184937	0.43
451.4677124	0.52
453.1079712	5.03
454.1970825	0.98
469.0819092	0.08
517.0302124	0.06
525.5546265	0.09
533.1679077	0.27
543.1686401	1.62
544.2803955	0.27
561.1672363	5.43
562.2428589	1.62
585.8363647	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0824
Annotation	Methyl gallate 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
101.0172501	0.12
113.0956192	0.05
118.9739380	0.16
120.9864960	0.42
122.2634583	0.08
124.7810822	0.15
129.1362610	0.04
135.1175995	0.07
137.0015869	2.60
138.9194031	58.63
140.0317993	5.53
143.1819153	0.07
151.0701599	0.06
152.9266663	0.28
158.9984131	0.24
161.0882874	0.98
163.0776672	5.33
164.9481201	100.00
166.0740662	14.15
173.2724304	0.29
178.9477081	0.05
181.1464539	1.38
182.9422913	24.78
184.0252686	2.09
186.1790161	0.06
189.0901794	0.04
193.1274414	1.16
194.1614380	0.20
196.0498962	0.10
197.1549683	0.22
205.1630554	0.62
207.0092468	11.00
208.0350647	0.61
219.1660461	0.08
221.3768311	0.08
224.3818665	0.29
225.2101440	0.67
226.2658997	0.09
235.0735474	0.14
237.2086792	1.11
240.3117371	0.08
249.1111755	0.19
256.3119812	0.12
259.8894653	0.05
262.0520325	0.05
265.1919556	0.84
267.2346802	0.08
268.2718506	0.08
274.3027649	0.06
275.1517334	0.07
283.5850220	0.31
284.2482605	0.93
285.2185669	0.14
299.2423096	0.26
300.1980286	0.12
301.1129761	0.34
302.2359009	0.24
327.1398315	9.47
328.1204834	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1719
Annotation	Lepidimoic acid
Peak:m/z	Relative Intensity
216.0985107	0.02
217.1992493	0.79
218.0083313	0.01
238.9627686	0.01
258.6599121	0.01
279.3134766	0.03
303.2119141	11.77
304.2290039	0.37
319.3956909	0.04
321.1881714	8.30
322.2436523	0.35
339.1957397	0.07
367.1169434	0.02
381.3135986	0.27
382.3452148	0.02
392.2365112	0.01
406.1939087	0.13
409.2652588	0.02
419.3756714	0.10
420.3926392	0.04
433.4201660	0.01
435.2472534	0.06
437.1831055	1.70
438.3563232	0.14
449.1069946	0.01
450.4294434	0.03
451.3435059	0.01
453.6591187	0.03
464.1550293	0.04
467.2260742	0.19
468.3518066	0.01
477.1537476	0.04
479.2384033	20.86
480.2498779	2.07
485.1693115	0.38
486.3215942	0.04
495.4415894	0.23
497.2719116	11.72
498.3440552	1.13
509.5284424	0.04
521.4138794	0.02
527.1201782	0.03
539.2717285	30.49
540.4172363	3.91
579.5953979	0.02
581.2930298	0.23
582.2194214	0.03
584.1041260	0.02
589.1304321	0.05
607.5737305	0.02
608.5531616	0.15
625.2204590	100.00
626.2140503	12.47
626.8408813	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.28
Annotation	Tupichigenin C
Peak:m/z	Relative Intensity
140.9964447	0.05
145.2144470	0.13
147.4177551	0.08
149.1445007	0.06
153.1081085	0.17
157.0977173	0.12
161.0443726	0.03
163.1611786	0.83
165.2550964	0.05
173.0556641	0.10
175.1619873	0.29
181.0023346	0.09
193.1669006	2.58
203.4953613	0.17
209.1779785	0.45
211.2126160	3.74
229.0595856	0.06
231.0146637	0.16
237.1774139	0.13
241.2714844	0.07
249.1666260	0.31
250.1943970	0.16
259.6098328	0.07
260.2538147	0.13
265.3487244	0.06
267.3044128	1.31
269.1905518	0.17
274.8982849	0.36
277.2805786	0.09
283.2263489	0.90
285.2823792	0.22
287.1782532	0.31
288.3079834	0.26
289.2242432	0.62
303.2298584	0.12
309.1988220	0.19
311.1439819	0.04
313.2945557	0.20
314.2534180	0.13
314.8823853	0.09
317.5574951	0.09
319.2381897	0.30
321.6480103	0.25
325.1774902	0.21
327.0583801	0.12
328.9444580	0.05
331.1644897	100.00
332.7846375	0.18
336.1254578	0.08
339.5841370	0.20
348.9189453	0.11
355.4464111	0.08
357.2291870	0.15
358.0335999	0.06
364.1271973	0.12
367.1662598	0.11
369.5708923	0.12
371.4180298	0.05
372.9987183	0.03
383.4039001	0.34
385.2426147	0.12
391.2664795	0.20
395.2734070	0.06
401.5735168	0.55
402.9082031	0.06
405.3606262	0.07
406.0961914	0.07
407.0530090	0.06
417.2856445	0.04
419.3305969	0.10
421.1331787	0.09
429.6622314	0.10
433.3540344	0.17
439.6027527	0.10
445.0300598	0.13
447.2870483	0.37
448.4278870	0.05
449.6577148	0.06
457.2361145	0.86
461.1794739	0.20
465.5997009	0.08
474.0941772	0.21
474.9192200	0.54
475.5325623	4.56
478.4010315	0.16
492.9470825	0.07
494.5784302	0.11
1027.4877930	0.11
1292.0943600	2.81
1437.3245850	0.38
1454.4689940	0.12
1676.9324950	0.03
1763.8863530	0.09
1791.2335210	0.08
1818.9307860	4.91
1823.4158940	0.32
1834.5780030	0.83
1905.0919190	0.10
1916.2369380	0.09
1921.5809330	0.30
1943.3741460	0.10
1944.4060060	0.56
1947.3864750	0.07
1952.6007080	0.03
1960.9932860	0.11
1963.3092040	0.06
1990.6368410	0.06
1993.6872560	23.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	378.1768
Annotation	Unknow
Peak:m/z	Relative Intensity
104.4094391	0.08
109.9422226	0.51
111.1912384	0.20
112.9729538	1.09
118.8362885	0.97
128.8891296	0.88
140.1950989	0.46
142.0763245	4.53
143.0772400	1.33
146.9202576	0.12
150.0616913	0.10
152.0295410	0.24
154.1101379	2.34
154.9910278	0.11
159.0139923	1.40
161.0559998	3.00
163.9464417	0.07
168.0510864	4.03
170.1307373	28.33
172.1871185	1.35
175.1975708	0.08
180.1296539	10.70
181.3599854	0.10
184.1159363	0.35
190.0917358	0.10
194.1782837	0.06
198.1140594	86.14
200.1102448	0.44
202.3888550	0.14
210.1176453	0.25
212.2204285	0.15
214.6015015	0.08
216.1187744	100.00
222.1814880	0.13
224.1980286	0.26
240.2940979	1.27
242.4161377	0.62
252.0612183	0.05
253.3837891	0.07
258.2572327	1.64
259.3767700	0.07
262.2607422	0.09
265.4184265	0.11
270.0653687	3.86
270.7357483	0.09
278.2096252	0.06
281.4781799	0.10
285.3804321	0.07
290.1893311	0.14
293.3831177	0.08
305.9212646	0.15
315.1496277	0.20
316.3163452	0.13
317.4363708	0.29
318.4060669	0.12
332.2546387	0.05
333.2289124	0.22
334.4774780	0.08
335.5126953	0.32
345.3834229	0.20
347.8249512	0.26
349.1746521	0.14
350.3230591	0.30
359.1298523	0.23
360.0680237	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Scopolin
Peak:m/z	Relative Intensity
132.9153748	0.02
135.1088257	0.57
142.9253845	0.11
161.1003113	0.42
173.0279846	0.35
179.0179749	3.82
191.0385132	100.00
215.9873657	0.03
304.4262085	0.01
309.3738403	0.05
334.9730835	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1772
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
191.1060486	0.03
237.0771484	100.00
238.1773682	0.68
267.2832642	0.13
323.1212158	0.02
324.9902954	0.05
342.2451172	0.04
365.3558350	0.03
403.2712402	0.08
417.0432739	0.05
535.3865356	0.01
559.4248047	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1246
Annotation	Unknow
Peak:m/z	Relative Intensity
157.1048889	0.03
162.9142761	0.08
165.0825043	0.10
168.9968872	0.24
170.2786255	0.07
172.9094238	0.04
177.1373138	0.10
177.9526978	0.02
179.1018066	0.35
180.1044312	0.03
181.1666260	0.12
190.0860138	0.01
190.9752197	0.17
192.0140228	0.21
193.0399780	0.28
194.2112579	0.08
195.2929840	0.01
203.1327209	0.24
204.2593689	0.07
205.1316681	0.15
206.1469116	0.05
207.2045288	0.11
208.0932617	0.02
209.1373291	0.15
211.1352081	0.04
213.4316864	0.05
216.3049011	0.02
217.1125488	0.05
219.2162476	0.93
220.1583252	0.42
222.1171722	0.03
224.1942902	0.04
225.1712494	0.06
229.1259460	0.08
231.1293945	0.21
232.1522827	0.05
233.1957092	0.02
234.1900177	1.64
235.1528931	0.68
236.1867981	0.07
237.0746765	0.11
239.0151978	0.04
240.0348816	0.02
241.2696838	0.85
242.1612244	0.96
243.1546326	0.62
244.2482910	0.07
245.0225830	0.09
245.9403381	0.06
247.0731812	0.48
248.2348480	0.06
249.1826935	0.12
254.2472839	0.04
256.1399231	0.08
257.2268677	0.12
258.0952759	1.16
259.2207642	0.38
261.1985779	0.07
263.0015259	0.35
264.0728760	0.14
265.4837952	0.02
268.1721802	0.11
269.0631104	1.36
270.2403564	0.98
271.1493530	0.47
272.5332642	0.99
273.2152710	5.57
274.1834106	0.57
275.1903076	0.28
276.2405396	0.07
277.1613770	0.42
278.4549561	0.06
279.3882446	0.08
281.1443481	0.08
282.1077576	0.08
283.1336975	0.15
283.9746094	0.06
285.2319336	0.23
286.1818237	0.75
287.2438354	1.23
288.1734009	0.11
289.1302490	0.08
291.2667847	0.30
293.5330200	0.06
296.3444214	0.02
297.3473511	0.14
299.1962891	0.25
300.1661377	0.56
301.1460571	7.21
302.2446289	1.44
303.2906494	1.99
304.3836670	0.13
305.2396240	0.05
308.3770447	0.06
309.6979980	0.02
310.5565796	0.05
311.2924194	0.07
313.1115723	0.31
314.1880493	0.75
315.1626587	4.27
316.1488037	5.39
317.1615601	1.26
318.3244629	0.14
319.2742920	0.25
321.1834717	0.11
323.3062134	0.06
326.2762451	0.03
327.2519531	0.16
328.3827515	0.86
329.2534790	7.69
330.1653442	4.38
331.1989136	1.12
331.8875732	0.03
335.5301514	0.02
336.3716431	0.06
337.2336426	0.08
338.2252197	0.03
339.1979980	0.04
341.0689697	0.94
342.3675537	0.39
344.1397095	100.00
345.1716919	51.52
346.2161255	5.53
346.9270630	0.06
349.3999023	0.18
352.4015503	0.14
354.0552368	0.21
355.2836914	0.22
356.6550903	0.23
357.4026489	0.74
359.1433105	4.51
360.2236328	0.45
361.0334473	0.12
363.4442749	0.05
364.4576416	0.10
367.2092896	0.29
368.1622925	0.09
369.1338501	0.47
370.3448486	0.06
371.3015747	0.29
372.2603149	0.72
373.2682495	0.40
374.2086792	0.15
375.2440186	0.14
376.3162842	0.04
377.2716675	0.05
378.8115845	0.03
381.3209229	0.17
382.3081665	0.09
383.2506714	0.20
383.9414062	0.02
385.4604492	0.04
387.2280884	24.57
388.1887817	3.63
389.1417847	0.13
391.1522827	0.02
394.1351929	0.03
395.3107910	0.11
397.1788330	0.13
397.9216919	0.04
399.2213135	0.22
401.3611450	0.16
402.0941772	0.11
403.3782959	0.04
405.1329956	0.17
406.1239624	0.07
410.1375732	0.02
411.1910400	0.13
413.4032593	0.09
415.2168579	0.10
417.2487183	3.46
418.3773804	0.42
419.1285400	0.02
423.3135986	0.03
425.2924805	0.02
429.2147827	0.29
431.1009521	0.10
433.2075806	0.08
435.5632324	0.07
439.5543823	0.07
445.5407104	0.04
452.2261963	0.09
453.5142212	0.12
456.1378174	0.04
459.4226074	0.02
461.2235107	0.04
463.2030029	0.02
464.3132324	0.03
465.1320801	0.04
471.2114868	0.13
473.3541260	0.03
475.4676514	0.06
477.6224976	0.02
478.6818237	0.05
479.3522339	0.10
481.3649292	0.06
482.2158203	0.05
487.4220581	0.03
489.2302856	6.55
490.3015747	1.64
499.2133179	0.03
503.2254639	1.16
504.4719849	0.07
505.3483887	0.41
506.0486450	0.06
507.3303223	1.68
508.2960815	0.46
511.4454346	0.02
514.3456421	0.08
515.6736450	0.05
517.2834473	0.39
518.2757568	0.12
521.2979126	3.88
522.3794556	1.36
523.1501465	0.06
527.3210449	0.09
529.0367432	0.02
530.4580078	0.02
531.2331543	0.28
532.4920654	0.10
533.5101929	0.07
534.3054199	0.53
535.3140869	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.8661194	5.48
130.9772644	0.25
143.0718079	0.06
158.9305115	100.00
199.0163269	1.15
199.9766541	0.02
200.9111938	0.04
216.9084167	1.02
228.9301453	25.33
245.0276489	0.50
253.8798523	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.1613
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
267.0675049	0.13
269.4087524	0.02
277.3099976	0.02
278.1931763	0.10
279.3205261	0.05
293.2973022	0.03
299.2546997	0.04
301.1329041	0.02
313.0440674	0.03
328.2233276	0.04
345.0931702	0.02
351.3793030	0.03
352.2655029	0.07
352.8812256	0.02
361.1998901	0.04
363.2979126	0.03
369.0883179	0.06
379.1234131	0.02
385.4201050	0.14
392.2410889	0.01
396.3842163	0.02
402.3750610	0.03
408.2397461	0.03
421.2249146	0.03
423.3367920	0.56
427.4216309	0.05
448.3795166	0.03
453.1693726	0.05
457.1949463	0.11
458.5060425	0.02
465.4100952	0.04
467.0497437	0.04
468.3969116	0.01
479.3718262	0.02
481.5440063	0.03
483.2289429	0.06
485.5504761	0.03
489.1004639	0.08
500.4309692	0.03
501.1997070	0.11
503.4669189	0.06
509.4556274	0.06
510.3521729	0.03
511.4685059	0.02
514.2708130	0.04
515.2188110	0.02
528.3331909	0.10
529.3722534	0.30
533.3499146	0.03
534.2924805	0.10
541.2918701	0.12
545.5052490	0.09
546.2467651	0.22
547.4032593	0.27
548.3512573	0.03
556.4561768	0.07
564.4226685	0.04
568.5372925	0.02
579.5449829	0.03
583.5933228	0.02
585.4399414	0.10
589.4236450	0.09
595.3864136	0.13
607.5245972	0.02
615.4971924	0.05
619.0398560	0.14
622.1419067	0.03
623.3390503	0.05
625.2161255	0.14
627.5729370	0.12
628.5991211	0.04
631.5700684	0.02
633.3882446	0.03
634.2855835	0.01
637.2987671	0.10
639.3570557	0.03
640.3627930	0.04
646.4871216	0.04
649.7058105	0.05
659.3856201	0.23
662.5310059	0.08
663.5239868	0.29
665.3258667	100.00
665.9448853	0.83
671.9240112	0.09
676.2526245	0.08
677.2881470	0.66
688.1066284	0.03
689.5441284	0.12
691.3859863	0.65
693.6763306	0.07
694.3939209	0.12
699.5592651	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.23
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
135.1510315	0.04
145.1394653	0.10
153.2912140	0.19
165.0738220	0.02
166.7835083	0.07
170.2903442	0.10
170.9334717	0.30
181.2697144	0.05
216.8372498	0.14
223.0631561	0.17
236.4177704	0.08
244.9425049	0.15
247.0200806	0.08
249.0879517	0.25
257.1055908	0.04
276.9220581	0.04
284.9274292	0.12
287.0313110	0.03
295.2136536	0.11
296.2583923	0.05
301.1590576	3.04
302.4237671	4.52
303.2198792	57.00
309.0987244	0.09
310.5458374	0.04
313.0325012	0.06
315.2884521	0.44
316.2900391	0.03
317.1605225	0.13
318.5098572	0.04
324.2360229	0.03
325.2911987	0.07
331.1741638	32.05
332.1824646	47.30
333.2189941	100.00
334.0081177	0.04
338.1509399	0.16
338.9966431	0.60
343.6063232	0.10
345.5641479	0.05
349.6102905	0.20
356.2132568	0.06
373.4251404	0.04
375.5629272	0.11
377.3512268	0.04
379.2306519	0.11
395.1539001	0.05
397.3218384	0.06
399.2696228	0.12
405.1632996	0.11
411.3109436	0.04
412.7942810	0.07
418.4317322	0.03
419.2019043	0.36
421.0065613	0.09
422.2544250	0.05
424.4745789	0.04
428.4758606	0.11
429.0871277	0.09
441.1763611	0.04
446.4095764	0.21
447.2452698	0.47
448.3403015	0.54
449.6587219	0.06
456.3829651	0.08
464.8510437	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.2479
Annotation	3-Oxo-alpha-ionol 9-[apiosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
180.9748993	0.40
191.1225281	0.23
203.1786804	0.09
204.2972412	0.11
207.2609558	0.18
249.1690369	0.09
257.3796387	0.19
263.2662048	0.11
285.1531067	0.15
286.2500305	0.24
301.1119690	100.00
301.9957886	0.10
303.2752991	0.85
309.4056396	0.20
313.3508911	0.57
319.3032837	0.42
325.1653137	0.17
330.6094055	0.65
331.2498169	2.09
341.2779846	0.10
343.1928101	0.35
344.1601257	0.22
369.3240356	0.18
394.8996277	0.40
415.2462769	0.50
419.7629700	0.15
439.3005981	0.67
441.4367371	0.29
445.4919128	1.07
446.8300781	0.36
469.4270325	1.42
473.3196716	0.45
477.5894165	0.18
487.2312927	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.2
Annotation	Serruloside
Peak:m/z	Relative Intensity
130.5758667	0.49
137.2859039	0.22
143.0218201	4.03
148.9179382	1.11
151.0565643	8.01
152.3618317	0.45
155.9290619	0.37
158.3202209	0.26
159.0416107	0.53
161.0124207	5.54
167.0344849	1.49
171.0143890	0.45
172.9946136	1.02
174.1621094	0.71
175.1076660	0.86
177.2053528	2.66
179.0680237	14.26
180.2346191	0.78
180.9454498	0.64
183.8934937	2.99
187.2393799	6.92
189.1202698	8.74
191.1856995	0.32
197.2924957	0.85
199.1179504	7.66
200.1499634	0.57
201.2249451	2.97
202.3576965	1.75
203.0811005	0.23
205.0838928	3.99
207.1206970	0.55
215.1923523	3.39
217.1531677	100.00
219.2199707	1.09
227.9316101	0.29
233.4787750	0.21
234.1077728	0.22
235.1668396	12.35
236.1963806	0.68
237.2563019	0.22
241.3705444	0.39
243.1899414	1.81
245.5049133	0.51
249.3505249	0.35
259.3413391	0.22
261.1239014	20.20
263.1181946	0.33
273.2087402	0.53
275.0323486	0.22
279.1446533	8.56
283.4837646	0.95
299.2800903	0.52
330.1670227	3.50
344.9530334	0.65
353.4562378	0.18
395.2894287	51.64
397.1287842	0.84
399.2642212	0.72
423.3750305	2.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2913
Annotation	Taxusabietane E
Peak:m/z	Relative Intensity
226.1690674	0.05
307.1894531	0.12
313.1895447	100.00
314.2920532	9.36
328.3469238	0.16
343.3341064	1.58
344.3243408	0.74
429.8457031	0.03
449.2962646	0.06
472.5159912	0.03
491.1954956	0.02
493.3095703	0.16
495.4517822	0.03
496.4721069	0.08
507.5881348	0.02
517.2766113	0.05
522.2213135	0.17
523.4222412	0.60
524.1737671	0.15
525.2636719	0.05
529.4915161	0.14
537.4982300	0.03
539.7661133	0.07
540.5447998	0.04
545.4429321	0.03
548.4130859	0.10
557.3020630	0.04
564.2870483	0.03
565.3476562	0.16
566.6082153	0.08
579.6555176	0.08
595.4448853	0.25
596.5908203	0.05
609.4520264	0.05
611.2058716	0.11
617.4974976	0.03
619.6196899	0.07
625.4596558	0.04
627.3770142	0.03
633.4790649	0.08
634.7387695	0.08
643.5680542	0.10
661.6767578	0.05
665.3492432	0.08
668.6719360	0.02
669.5342407	0.09
671.4973145	1.36
672.4967651	0.41
673.4421997	0.18
674.2530518	0.11
675.4593506	0.03
683.6503906	0.10
687.5002441	0.29
688.8911133	0.02
699.9937134	0.03
701.2527466	0.62
705.4779053	0.06
710.2195435	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9276886	0.53
86.9718781	0.72
99.0824585	0.02
100.9782257	0.02
110.9730530	100.00
126.8660431	0.02
128.9379730	2.37
130.9167023	1.36
146.9420471	0.18
153.1629944	0.06
154.9852142	0.77
170.8996735	0.06
172.9758301	27.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.1693
Annotation	Isoscoparin 2''-O-ferulate
Peak:m/z	Relative Intensity
212.9538269	0.07
216.8746948	0.10
241.7376709	0.09
243.3430328	0.30
255.2415466	0.07
270.0433960	0.25
285.8484497	0.06
287.1954956	0.78
299.1241760	1.25
301.2062988	0.07
303.5789795	0.30
315.1925659	1.50
316.2270508	0.25
331.1611633	100.00
373.0043945	0.27
471.2648315	0.31
476.8775024	0.25
493.0876465	0.12
505.6733398	0.14
507.2697754	0.12
513.5610962	0.34
537.1604614	0.05
539.3485107	0.11
593.4463501	0.56
603.6018677	0.12
607.3023071	0.26
609.5935669	0.06
623.0121460	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.04541779	0.19
96.01935577	0.72
98.9983902	0.52
103.81604	0.40
115.0646057	0.32
123.1571503	0.23
124.9441833	1.13
126.9932404	0.34
127.9925919	0.79
131.0350647	0.28
132.8022308	0.82
135.0697021	1.02
139.1295166	0.34
141.0756531	0.49
142.7640381	1.47
149.0722656	1.96
150.9941864	1.45
152.9508972	1.70
153.5686035	0.34
155.031311	2.03
157.2610474	0.36
158.9724121	1.33
161.0409241	0.30
163.0839233	1.78
167.0847931	0.53
169.0953369	1.69
172.3232117	0.61
177.130249	1.94
179.0543365	0.24
180.9032745	1.95
183.0806427	0.53
184.9387512	0.66
187.2382507	1.74
189.4279175	0.26
191.2898712	0.32
193.0472412	0.43
195.2642822	1.95
197.1282654	2.34
198.9226379	0.36
201.0627136	0.88
203.2156982	0.24
207.1369324	1.67
208.6411743	0.80
209.327179	1.33
210.2149048	1.91
211.2893677	2.18
213.056427	1.51
214.0315857	0.24
215.0935059	0.42
215.987854	0.43
217.1767883	0.47
221.0906372	0.55
223.2095947	1.13
225.26651	1.19
227.29599	0.68
228.2523499	0.26
229.1699524	1.14
231.0957642	0.28
233.4473572	0.95
234.9326782	1.23
237.1333313	0.81
238.1585999	0.30
239.2563477	0.34
241.0131226	1.71
247.3782349	0.72
249.2850952	1.43
249.9423828	0.28
251.0628357	1.40
253.1829529	7.14
254.9554138	0.47
257.2053223	3.00
258.1099854	1.33
261.3093262	0.87
264.6408997	1.34
265.3520508	4.83
267.3045349	2.23
268.4734497	1.05
269.2962341	2.16
270.1177063	3.39
274.7349243	0.90
275.3390198	9.32
279.9526672	1.25
281.1950073	1.72
282.1798096	0.42
283.2218628	0.85
284.6638184	0.53
291.1853638	0.59
293.2088623	100.00
293.943634	0.53
295.2675781	0.59
302.1293335	3.80
310.5799561	0.19
311.5630493	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0032120	4.90
115.9963531	1.61
130.9954529	0.32
131.8977051	0.03
143.0376892	0.02
158.9563751	100.00
159.9469910	34.41
173.9545898	0.02
192.2191162	0.04
198.9734497	1.25
200.0090027	0.94
201.0605469	0.12
201.9451599	0.02
217.0366821	0.35
218.1363525	0.72
228.9429016	17.69
229.9324036	17.30
244.9616699	0.27
245.9982910	0.43
247.3514709	0.08
255.5125732	0.12
256.2312622	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.11
Annotation	Unknow
Peak:m/z	Relative Intensity
142.5938568	0.09
148.9606018	0.34
161.0903015	0.22
175.1208801	0.66
181.1676636	0.13
193.0162354	0.19
195.0112915	0.06
196.9389648	0.12
198.0909882	0.24
199.1283875	2.02
201.1533813	0.50
211.9103088	0.05
212.8744507	0.63
213.5657043	0.09
217.0751343	1.31
223.1606293	0.20
226.2143707	0.10
231.1815186	0.06
241.0981140	15.30
241.7508392	0.59
242.9882202	1.21
245.1017303	0.04
246.1539764	0.09
257.0833435	0.44
259.1422424	0.05
263.0886230	0.25
267.1030579	0.64
285.0863342	100.00
285.7110596	0.17
291.2980347	0.14
301.4692993	0.27
302.2960510	0.10
303.2064514	2.23
327.0142212	0.26
333.1441345	0.27
341.3917847	0.14
343.1270752	0.09
345.2640381	0.10
353.0794067	0.16
371.2453003	2.09
381.2538757	6.64
397.2861023	1.08
411.2209778	0.08
447.2190247	0.08
449.1237488	0.05
461.2172546	0.09
463.2799377	0.64
474.2317505	0.11
487.3739319	0.25
489.6503296	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1193
Annotation	Unknow
Peak:m/z	Relative Intensity
137.0961914	0.05
149.0296173	2.95
151.0712585	0.22
152.9854584	0.04
163.1882172	0.09
164.0997925	0.09
164.9624939	0.12
166.2754211	0.34
167.1336365	0.06
168.9330139	0.05
175.1228485	0.08
176.9491577	0.24
178.9490814	1.46
189.0823975	0.39
190.9280090	0.22
191.9952087	1.69
192.9521790	1.19
203.0296631	0.05
204.7552795	0.05
206.1428223	0.40
207.0941467	0.28
208.9011230	0.15
219.0513306	0.05
224.2401123	0.10
227.2265472	0.04
229.1599731	0.05
232.8392181	0.06
235.0294495	0.70
237.3457336	0.04
239.2094269	0.09
243.1806488	0.07
245.1958008	0.33
259.1808472	0.62
260.1119385	0.12
260.8260803	0.23
261.5361633	0.09
263.0397644	0.09
265.0925293	0.04
271.1898804	0.78
272.1598816	0.13
279.4684753	0.06
281.3222046	0.21
283.0111084	0.05
285.3739014	0.04
287.1778870	0.41
287.9019470	0.20
289.1598816	0.24
293.1666870	0.29
297.1216125	0.15
299.1398926	9.22
300.8476257	0.19
301.4789124	0.09
302.3678284	0.04
303.3435669	0.71
309.3158569	0.14
313.2669067	0.29
314.2325134	1.42
316.1434937	70.87
317.1128540	48.91
318.2288513	0.06
319.1630249	0.52
325.1289062	47.51
327.1038513	0.34
329.2311401	100.00
335.1379089	0.06
341.0501709	0.89
343.6400757	0.14
345.2542114	0.28
346.1022339	4.41
347.2054749	13.05
353.1753235	0.87
359.2772217	1.84
369.4386902	0.05
371.0333862	0.17
375.1152344	0.17
389.1656799	0.94
392.3622742	0.06
395.0588074	0.07
401.1773071	0.17
413.0705261	0.25
417.4797058	0.12
419.2551575	0.48
432.3223572	0.10
433.4570007	0.58
435.3808289	0.95
437.0424194	0.05
461.1746521	6.70
464.5304565	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9578
Annotation	Unknow
Peak:m/z	Relative Intensity
127.8172607	0.10
130.1470032	0.35
142.0126801	0.09
156.0170593	0.71
170.1780853	0.43
172.0266418	0.07
183.9727020	0.64
190.8471375	0.05
199.9541321	15.62
200.9689026	0.22
214.0078430	3.62
218.0047302	0.53
227.9509430	0.35
239.9661560	0.24
242.0693970	0.13
243.9732361	5.97
246.0041809	1.22
255.7323303	0.06
257.9234619	73.63
262.0029297	1.44
268.0372620	0.33
284.0988159	1.34
285.8438721	4.04
288.0153809	9.79
289.8845825	2.46
301.8702698	38.66
302.6058350	0.37
304.0681152	3.23
305.0068970	0.23
312.0657959	0.37
312.9872742	0.35
314.0183411	0.54
328.0979004	2.04
329.7281189	8.96
331.9165039	100.00
338.0946655	0.57
342.9237671	0.15
344.4893799	0.11
345.8570862	18.61
347.3784790	0.53
348.0423584	2.88
357.8060913	0.17
363.3802795	0.10
372.5694275	0.21
373.8474731	3.29
375.4834290	0.88
376.2189636	0.28
392.0425720	35.89
400.0002136	3.68
407.4585876	0.07
417.9236145	71.13
418.5960388	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1379
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
184.7312469	0.39
189.1712952	0.11
203.2553864	0.20
221.9923401	0.12
227.6090698	0.16
229.2527466	0.69
231.0287476	0.78
245.4269714	0.25
247.1062622	0.14
249.0740967	0.14
257.1454773	0.13
265.1935425	0.17
267.1484375	0.18
268.7688293	0.16
273.3039856	0.41
281.2112427	0.10
287.2239990	0.11
291.1842957	2.22
299.2465210	0.21
300.9495239	0.34
303.1085510	100.00
307.0158081	0.14
309.1000061	91.33
314.6509399	0.19
317.3949890	0.60
327.1447754	0.99
345.1514282	34.14
345.7639771	0.12
347.1256104	0.14
357.3722534	0.11
362.9673462	0.16
369.2174683	1.17
369.9725342	0.10
381.0152588	3.17
381.9878540	0.81
387.3690186	0.68
393.2314453	0.63
394.8656616	0.36
399.1992798	1.53
411.2407227	8.47
413.3270874	0.11
415.4353027	0.36
421.0103149	0.32
422.9658813	0.29
429.3251953	2.30
435.3464355	0.30
445.5029907	0.31
447.1579590	4.68
448.4220581	0.45
449.3533325	0.43
451.3767700	0.12
459.4091797	0.10
465.1601562	2.90
466.9321289	0.56
469.3894653	0.42
473.2155762	2.04
474.2951050	0.25
479.2318726	0.22
484.3345337	0.30
485.8617554	0.07
487.3345337	0.17
490.2780762	0.18
491.2854614	0.59
499.1087036	0.18
515.3397217	0.43
517.0859375	0.74
519.3139038	0.36
519.9342041	0.34
525.5806274	0.64
529.8980103	0.62
533.3966064	0.10
535.2514038	0.13
542.5170898	1.30
545.7277222	0.12
557.3534546	3.26
566.9855957	0.69
572.8464966	0.35
574.0364380	0.21
575.1588745	1.81
580.4364624	0.16
581.4537354	0.61
583.7311401	0.41
593.1511841	23.59
593.8767700	0.11
594.7868042	0.59
596.0888062	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.22
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
150.0810242	0.25
151.0348206	0.41
161.9454041	0.12
164.1623993	0.08
165.1579590	0.08
178.9472656	0.72
180.2157745	0.21
181.0763397	0.09
186.8971863	0.06
195.1862640	0.79
204.6271210	0.08
206.1420441	0.04
207.3768921	0.05
214.2705536	0.05
216.1257019	0.04
217.2810669	0.06
218.9863892	0.10
227.3205109	0.12
233.0654907	0.17
234.1308899	0.06
243.5003052	0.08
255.0912170	0.05
258.2144775	0.10
259.1316528	0.15
261.1909790	0.21
266.3116455	0.08
267.2863770	0.10
268.2608643	0.10
271.1611938	0.93
272.0666199	0.32
273.1709595	0.37
275.3141785	0.04
276.3376465	0.48
277.2758789	0.14
285.1342773	0.05
287.1950684	0.11
288.2870483	0.22
289.1692505	0.20
291.0390015	0.20
300.9202271	0.97
301.5281372	0.17
302.3690796	0.04
309.1381226	0.05
311.5184326	0.06
313.2606812	0.29
316.1128540	17.78
317.1026001	27.92
318.1245728	23.03
319.1771851	2.99
320.2449951	0.04
323.1119385	0.06
325.3348999	0.09
327.1988525	5.36
328.1624146	0.05
329.2985840	0.25
330.2190552	0.74
331.0194702	0.10
332.0082397	0.07
337.2301025	0.19
339.3268433	0.10
341.1619873	0.08
342.6826782	0.23
343.2927856	0.77
345.8684082	0.10
347.2963257	0.20
349.4591064	0.12
355.2876587	0.08
357.4146729	0.12
358.2283936	0.44
359.4741821	0.16
360.2371216	0.67
361.3113403	5.92
362.5662231	0.13
363.2062378	0.08
367.2626953	0.15
368.3500977	0.11
369.5020142	0.25
370.4158325	0.04
371.5693359	0.05
372.3920288	0.06
373.4152222	0.48
376.2675171	0.06
377.0770874	0.09
381.2845459	1.37
390.4600220	0.12
391.3668213	7.18
393.2575073	0.18
396.3400269	0.15
397.1756592	0.73
401.0651245	0.06
412.5089722	0.07
427.3100586	0.13
433.2939453	0.15
438.1425171	0.14
445.3717651	0.21
460.9619751	0.03
462.2134399	0.64
463.2901001	0.05
468.3934326	0.04
475.3183594	100.00
477.2014160	1.80
479.1809082	1.39
480.2817993	7.41
481.3357544	5.14
485.4885864	0.20
487.1521606	2.73
491.0106201	0.33
493.2077026	0.26
495.4061890	0.38
496.6366577	0.11
502.9771118	0.05
504.1973877	0.40
505.3679810	5.46
508.2819824	0.47
509.2729492	0.28
525.0565796	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.1184
Annotation	Unknow
Peak:m/z	Relative Intensity
59.8693886	45.28
69.9083710	7.21
71.9006043	1.51
84.1567535	0.06
97.0203552	0.41
98.0056000	0.19
112.0729065	5.57
113.0225830	0.81
114.0886536	4.99
114.9527435	1.63
115.9347076	60.24
130.0522461	40.09
130.8829193	0.21
133.0711365	1.19
140.0421600	3.13
140.9895782	0.22
151.7446442	0.20
157.0772247	87.52
158.0179596	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	797.1896
Annotation	Unknow
Peak:m/z	Relative Intensity
245.3780060	0.02
255.8574829	0.04
263.2159729	0.07
288.9547729	0.05
303.2165833	0.06
305.3612061	0.01
331.1563110	0.06
373.2175293	0.83
410.9308472	0.07
447.0988159	0.08
452.2644043	0.06
467.2529297	1.14
483.3184814	0.04
489.1744995	0.05
493.3572388	0.16
506.4937744	0.02
509.0875244	0.10
535.0379639	0.04
554.2566528	0.09
591.6864014	0.38
592.3647461	0.56
593.1365356	0.19
599.2332153	0.02
617.3134155	0.73
629.2095337	0.16
632.3075562	0.03
633.5497437	0.17
635.2570190	100.00
647.2672729	0.03
665.1922607	0.10
731.6596069	0.03
735.5494995	0.02
751.0514526	0.05
769.3253784	0.04
778.2952271	0.07
779.0827026	0.03
797.6565552	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.1744
Annotation	Unknow
Peak:m/z	Relative Intensity
317.1603088	0.21
318.4324036	0.02
359.0899658	0.30
370.2856445	0.08
373.2506714	0.04
374.4279175	0.04
451.4012451	0.07
453.3697510	1.37
465.3648071	0.03
467.1017456	0.07
468.4116211	0.10
469.5334473	0.07
479.1963501	0.06
495.2971191	0.14
513.3226929	0.08
517.3614502	0.07
521.2722778	0.11
536.3857422	0.08
539.4229126	0.08
559.6139526	0.03
584.7896118	0.08
593.2099609	0.13
602.5545044	0.23
603.2794189	0.42
615.3421631	0.07
619.3973389	0.69
621.1892090	100.00
621.9285278	0.27
632.0551147	0.16
635.3677368	0.10
637.1214600	0.03
650.2130737	0.06
651.2307739	0.40
657.2973022	0.07
690.3718872	0.09
701.9207153	0.22
717.2265015	0.27
723.4389038	0.08
738.1356812	0.07
739.2749023	0.20
750.4149780	0.14
753.2730103	0.12
756.3048096	0.13
764.5936890	0.32
765.4122925	0.14
768.1838989	0.16
769.2020874	0.29
783.1985474	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.15
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
95.0005188	0.17
107.0432129	0.03
110.9575195	0.03
113.1895065	0.02
114.7936020	0.05
116.3148270	0.04
119.0107727	1.12
121.0553436	0.09
121.9693527	0.13
123.0543442	0.03
126.9462280	0.46
130.9342651	0.03
132.9759827	0.09
133.9547729	0.06
135.1367950	0.07
136.1387939	0.09
136.9691315	1.22
137.9102478	0.08
139.1727600	0.08
143.0571594	0.05
147.2622833	0.07
149.0704956	1.63
151.0243530	24.28
152.1582336	0.03
155.0582886	0.06
156.9569092	0.22
158.0608063	0.07
158.8943787	0.06
161.0637207	0.49
163.0124817	1.63
163.8235931	0.04
164.9723816	0.53
165.9362335	0.07
168.1472626	0.17
168.9022980	0.02
174.4664001	0.11
175.1753540	0.40
176.2995911	0.13
177.0112305	0.82
177.8994751	0.45
178.9955139	1.09
179.9703979	0.15
181.1281586	0.11
182.9587250	0.05
187.2473907	0.06
189.0994873	15.19
190.0355682	0.12
191.3367920	0.23
193.0596313	0.11
194.2246552	0.07
196.9822845	0.02
198.0502319	0.07
199.2991638	0.03
201.1814270	0.12
203.0832825	0.08
204.0434113	0.08
205.2451477	0.15
207.1254425	4.71
209.1433716	0.04
210.0967102	0.05
211.0495300	0.17
213.0935669	0.09
215.0527039	0.81
215.7898865	0.07
216.5125732	0.03
221.1207581	0.07
223.3600159	0.10
225.1911011	0.50
227.2318726	0.22
228.3333435	0.08
229.1347961	0.40
231.2371826	0.19
232.8957825	0.04
233.8748779	0.08
237.2015991	0.04
238.3296509	0.06
239.1314087	0.05
240.9057007	0.46
242.1147766	1.82
243.0730591	2.54
244.3158875	0.19
245.2240295	0.17
248.2064209	0.50
249.3196411	0.92
250.2645569	0.23
253.1286011	1.65
254.2939148	0.43
255.1935425	2.05
256.0251465	0.05
256.9858093	0.20
259.2724609	0.08
260.0989990	0.15
261.1654663	0.15
263.0662231	0.26
265.8782959	0.11
267.2067261	0.53
268.1016541	0.09
269.0902100	0.96
270.1698914	6.08
271.2341919	5.36
272.1875610	0.32
273.2479553	0.23
275.2336731	2.42
277.2880249	0.22
281.2007446	5.45
282.2799072	0.03
284.0519104	0.27
285.1744385	13.84
287.2334290	62.26
288.1890259	1.14
289.3130493	0.21
294.2245483	0.18
295.2533569	1.11
296.1149597	0.09
297.3528442	0.03
298.2155151	4.28
299.1883545	20.45
300.1590576	1.49
301.2216187	1.86
303.1843872	3.14
304.1302185	0.16
305.5016174	0.02
313.2008667	100.00
314.0804138	0.05
315.1050110	7.56
316.1923218	10.34
317.1585388	1.14
321.3744507	0.14
322.1346436	0.13
331.2034302	3.36
344.9884644	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.0879
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0817871	0.06
147.0018616	0.84
149.1171112	0.10
163.0243988	0.03
164.1185913	0.03
165.0441895	0.07
167.0344238	0.23
174.9839172	7.44
192.1181335	0.08
193.0660095	0.64
203.1581116	0.06
204.9417725	0.03
207.0879517	0.07
213.1888580	0.26
215.1216736	0.76
219.0130310	0.11
223.1844177	0.03
231.5194092	0.03
233.0613708	0.25
239.0416260	0.30
242.2130737	0.03
243.1620178	0.02
246.9181213	0.04
257.1546936	5.41
258.1930542	0.08
259.0880127	0.10
273.3800659	0.08
275.4844971	0.02
283.1422119	2.07
286.3903809	0.03
289.0957336	0.14
299.2222900	7.13
301.0965576	100.00
317.0672913	0.03
319.1483154	8.55
325.1123047	17.79
331.0811768	0.18
343.2774658	0.05
361.1632996	0.03
365.2926025	0.02
374.9122620	0.08
379.3563232	0.03
383.0869141	0.14
405.2369080	0.71
407.2501221	0.60
422.2552795	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.7953491	0.02
164.1576233	0.01
167.0597229	0.06
172.0304108	0.02
173.1998901	0.02
175.1997681	0.02
176.3127747	0.01
177.2136688	0.02
179.0742798	0.07
185.2744751	0.02
186.1264038	0.02
187.2065735	0.07
199.2177277	0.02
203.1743164	0.33
204.3453064	0.05
205.0704956	0.11
206.1697235	0.02
212.0669250	0.02
213.1558228	0.02
216.9977570	0.07
225.3887634	0.03
227.3976135	0.03
228.1801453	0.05
229.3651733	0.04
231.3258972	0.06
235.0532532	0.01
243.2243500	0.24
243.9447327	0.05
245.1694946	2.21
246.1976166	0.17
247.2117615	0.07
250.9610291	0.01
252.2513123	0.03
255.1479645	0.33
257.1778564	0.09
259.4010620	0.01
261.3215942	0.02
269.2060242	0.29
270.1743774	0.02
271.1638184	0.09
273.1622925	1.38
274.1317749	0.25
275.2243652	0.04
283.1424561	0.05
285.2557983	0.03
287.2446899	5.80
288.2113037	0.66
289.1769714	14.56
290.2344360	1.86
291.6301270	0.06
295.2244873	0.01
297.2659912	0.02
299.1808472	4.21
300.1926575	0.34
301.3041382	0.14
311.2809448	0.03
312.1995850	0.03
325.2581177	0.05
329.1163330	0.47
330.2128296	0.06
331.3131714	0.39
332.2547607	0.12
335.2437134	0.04
339.0942383	0.09
340.5310669	0.07
341.2147827	0.07
342.3828735	0.08
347.3504639	0.04
351.4432373	0.05
355.2128906	0.02
357.3396606	0.33
358.2778931	0.10
363.0379639	0.04
365.5236816	0.04
373.1658325	0.05
375.4460449	0.06
379.4343262	0.02
381.2169800	1.02
382.3870239	0.17
389.3571777	0.01
390.3242798	0.02
393.4612427	0.03
398.1854858	0.04
405.2039795	0.02
407.2593384	39.24
408.2396240	5.15
409.1910400	0.48
410.3179321	0.22
411.2368774	0.18
412.4248657	0.05
413.2643433	0.04
414.1909790	0.03
415.2486572	0.07
416.3624878	0.04
421.0469971	0.03
423.3986816	0.18
425.2164917	100.00
426.2083740	11.39
427.4463501	0.01
430.5988159	0.05
433.2159424	0.52
434.3010864	0.07
435.2437744	0.04
437.6570435	0.02
441.1905518	0.02
446.3681641	0.01
449.1928711	0.76
451.2185059	20.64
452.3252563	4.73
453.2542725	0.05
454.4805298	0.04
455.0908813	0.04
457.1711426	0.01
458.2854004	0.10
463.1620483	0.01
465.1991577	0.02
467.2828369	0.50
468.1847534	0.30
472.4752197	0.08
473.5341797	0.02
474.1860352	0.01
479.2984619	0.01
485.4253540	0.02
489.3479004	0.01
491.3415527	0.07
492.3431396	0.05
493.4799805	0.14
494.3736572	0.03
497.1713257	0.14
498.2467651	0.09
501.1317749	0.11
502.3661499	0.02
503.3218384	0.02
511.4396362	0.01
515.3762817	0.16
516.2979126	0.04
531.2613525	0.24
532.2764893	0.04
533.3710327	0.76
534.4083862	0.24
541.1252441	0.02
542.3332520	0.06
559.2845459	8.02
560.3417358	1.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.22
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
136.1349182	0.02
143.0457153	0.07
144.9037476	0.07
147.1143188	0.04
149.1352844	0.13
151.1880798	0.04
152.3307648	0.02
161.0544434	0.10
163.0710144	0.09
164.1779022	0.07
164.9858398	0.14
169.1363678	0.09
172.8000946	0.02
173.4403076	0.05
174.1014099	0.02
175.0516357	0.27
175.9961700	0.05
177.1040649	0.59
178.9935608	0.94
186.9972534	0.05
189.1228638	0.49
189.8435974	0.03
190.9643860	0.79
193.1232910	0.47
195.1325684	0.22
198.9328003	0.02
199.8728333	0.11
203.1844177	0.10
205.1412506	0.30
206.9200592	0.24
211.0383759	0.12
213.0906525	0.07
214.9526062	0.20
215.9882202	0.15
217.0893097	1.93
219.0314331	0.18
221.2165527	0.06
227.5583344	0.08
229.6216431	0.10
233.0097656	0.13
234.7572632	0.02
239.1595154	0.09
240.2780762	0.03
240.9574432	0.13
243.0816956	0.12
245.2003174	0.07
247.1275940	1.31
248.9509583	0.04
254.9675903	0.26
257.1395569	0.93
258.9678345	0.22
261.0549316	0.06
263.1535034	0.04
265.1650696	0.05
269.1340027	0.19
271.1888428	0.44
272.0649109	0.39
273.0893555	0.19
277.2449951	0.25
281.1887512	0.18
283.3119507	0.99
285.1871643	0.72
287.1591492	0.39
291.1846313	0.03
293.4488831	0.02
295.3214722	0.24
296.2718201	0.02
297.2303162	0.17
300.0812378	100.00
301.0759277	47.57
302.3138123	0.08
305.0504761	0.04
307.2617493	0.11
309.6535950	0.07
311.0989075	0.45
313.1665649	4.92
315.1469116	35.10
317.1216736	0.05
319.2159424	0.16
321.3169556	0.07
323.4339905	0.10
324.0726929	0.03
325.2416382	1.20
327.1807556	0.65
329.0814819	0.16
330.2320251	0.02
331.4694214	0.11
335.2147217	0.16
337.1475525	41.47
342.0491943	0.43
343.1477051	13.82
344.1818848	0.06
345.2676392	0.17
351.3661194	0.02
353.4446106	0.05
355.1901245	5.09
357.2772827	0.24
359.3674622	0.09
367.1828918	1.57
369.3626404	0.06
370.2189636	0.03
371.2236023	0.03
373.2150574	4.67
375.1520081	0.02
377.4255066	0.01
381.4246826	0.27
383.2537231	0.04
385.2967224	0.90
389.4124756	0.07
391.2319641	0.09
394.2182922	0.12
395.1595154	0.10
399.1589661	0.22
401.2318420	0.02
403.1515808	0.03
409.1460266	0.23
415.2531433	0.24
417.2653503	1.33
419.3848877	0.30
427.0060730	0.30
435.4425659	0.21
445.3029175	2.25
447.6720581	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	939.3839
Annotation	Unknow
Peak:m/z	Relative Intensity
290.2044067	0.03
320.3808594	0.03
347.2351685	0.03
370.4231873	0.02
379.2098389	0.07
387.1188354	0.06
398.1066284	0.02
403.4733276	0.04
425.3164062	0.06
434.5812988	0.02
435.4318237	0.05
439.3007812	0.04
443.4522705	0.04
451.4161377	0.08
458.2438354	0.06
459.3077393	0.04
462.2630005	0.07
465.1245117	0.03
477.4255981	0.05
478.2127075	0.10
479.3167725	0.06
484.1304932	0.05
493.3853760	0.17
494.4667969	0.03
515.3753052	0.08
544.2800903	0.03
554.2903442	0.05
558.2145386	0.05
563.0652466	0.04
568.4135132	0.05
586.2360229	0.30
586.8536987	0.03
592.8713989	0.11
597.5247192	0.02
601.2323608	0.07
604.5545654	0.36
605.3428345	0.21
610.2369995	0.11
612.5719604	0.05
622.3152466	0.08
624.5630493	0.02
632.2460327	0.14
633.4148560	0.03
639.0493774	0.14
639.7240601	0.03
643.5154419	0.25
654.4799194	0.42
655.3748169	0.07
684.2521973	0.03
691.5283813	0.04
692.5084839	0.14
709.4058838	0.98
710.4172363	0.09
713.4318848	0.02
716.1284790	0.05
722.5656738	0.05
727.3717651	0.82
728.1807861	0.32
730.5595093	0.10
731.4951782	0.10
735.6921997	0.06
740.0229492	0.12
741.4644775	0.36
743.6741333	0.33
744.5757446	0.80
745.4895630	2.72
746.4389648	1.67
747.0983276	0.02
748.4126587	0.17
749.4439697	0.05
753.5028076	0.09
754.3975220	0.04
759.3718872	0.25
763.7137451	0.07
766.5863647	0.11
769.6441040	0.04
770.5205688	0.13
771.6740112	0.17
772.7125244	0.05
773.4863892	0.07
777.4838257	2.64
778.5881958	0.43
780.4628296	0.10
781.5575562	0.12
784.4616699	11.19
785.4306030	2.32
786.6281738	0.16
787.5239258	0.02
799.0672607	0.22
804.8554688	0.22
805.6927490	0.04
808.2916870	0.04
816.3956909	18.56
817.4790039	3.29
824.8176880	0.04
828.8142090	0.03
830.1906738	0.09
835.5346069	0.02
837.2376099	0.06
839.4526367	0.11
842.2828979	0.08
845.4244995	0.43
848.4243774	0.35
853.8450928	0.32
854.6942749	0.10
859.9501343	0.04
866.3403931	0.07
871.4678345	3.00
872.5958252	0.83
878.0504761	0.04
885.7232056	0.08
889.4416504	2.24
890.5631714	1.01
903.4718628	1.19
904.5603638	0.18
907.4948120	100.00
908.5816040	20.72
921.5582275	2.20
922.5752563	1.12
923.8172607	0.08
940.1721802	0.04
941.1172485	0.09
954.3760376	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9716
Annotation	Unknow
Peak:m/z	Relative Intensity
201.9467316	0.06
211.9749908	0.06
212.8687592	0.04
253.0314636	0.02
265.3722229	0.09
271.5491333	0.02
279.2751160	0.04
301.4647827	0.05
303.8495789	0.05
312.9992065	0.11
318.2920227	0.04
327.4304199	0.06
328.2841187	0.02
329.9862366	0.07
332.0119019	0.35
334.1375427	0.15
335.4277954	0.05
348.0933838	1.60
349.7283936	0.02
361.6852417	0.04
367.4078674	0.04
375.3442993	0.04
375.9502258	0.02
392.0407715	0.04
394.0210876	100.00
401.2765808	0.03
402.0715027	0.26
408.2624817	0.04
409.1336365	0.07
419.0339355	0.43
420.0115356	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.2391
Annotation	Unknow
Peak:m/z	Relative Intensity
188.1792755	0.08
195.8818207	0.14
228.0095367	0.10
242.2127380	0.51
245.2426147	1.15
257.2083130	0.17
259.1832581	1.69
269.8798828	0.07
274.0602417	0.47
288.2151489	0.53
328.2386475	0.12
356.2746582	0.40
371.5838013	0.28
374.1979980	0.78
385.4066162	3.37
386.3082275	0.53
400.2500000	0.33
403.3115234	6.91
410.4105225	0.27
413.9799805	0.29
434.0687256	0.12
435.4786987	0.06
442.4790039	0.19
443.3438721	0.11
450.6583862	0.26
453.8029175	0.43
459.4591064	0.18
470.1887207	0.15
471.2173462	0.49
475.4150391	0.13
479.2798462	1.03
485.7166748	0.28
486.3767700	0.40
487.3070068	9.78
488.5382690	2.50
496.3640747	1.38
497.4315186	12.30
500.0087280	0.05
504.3493042	5.57
514.3743896	16.94
515.2967529	100.00
516.0926514	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.0828
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
147.0869751	0.85
148.8671570	0.38
167.2357635	0.08
175.0191803	11.91
176.8961029	0.21
191.9748230	0.27
193.0529327	3.59
195.0327148	0.07
201.3648376	0.07
206.9862213	0.08
212.9897461	0.39
215.1330566	1.10
229.0565948	0.13
231.1753235	0.07
233.2290649	0.41
237.3795624	0.09
239.0940247	0.86
243.1647034	0.06
247.3724060	0.06
255.1015320	0.06
257.1264343	7.68
259.1457214	0.95
265.3775940	0.10
270.9857788	0.24
273.1341858	0.73
275.2489929	0.21
275.9849548	0.12
283.1697083	2.81
290.0484619	0.09
301.1791992	100.00
302.7234802	0.12
304.0510864	0.06
305.3243103	0.18
313.3278809	0.06
315.0354309	0.18
317.0598755	0.43
317.8361206	0.06
319.1705017	15.56
323.0921021	0.29
324.0726929	0.16
327.2342529	0.31
329.2879333	5.52
331.2360229	0.03
341.1478271	0.74
342.3917847	0.08
343.2310791	0.31
344.4705505	0.07
349.4678040	0.26
355.2398682	25.24
357.2891235	0.20
359.4005737	0.13
362.2669373	0.50
363.3419189	0.32
370.1496277	0.22
371.0844116	0.15
373.1798706	0.17
378.4789429	0.14
381.3578491	0.19
382.5121155	0.09
390.9378662	0.30
391.6341248	0.09
393.2236938	0.16
394.1846008	0.15
396.1429138	0.28
397.2296143	0.41
412.2868652	0.31
413.4540100	0.29
421.1686707	0.07
427.1370239	0.14
435.4185486	0.41
436.2318420	0.73
437.2445679	2.93
439.1196289	0.14
448.0712585	0.25
453.0757141	0.31
454.2882385	0.24
461.4472046	0.10
463.1478577	3.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.2445
Annotation	Cineracipadesin B
Peak:m/z	Relative Intensity
176.8400574	0.08
180.1546631	0.26
181.0890045	0.15
191.9582214	0.45
193.3267365	0.07
195.1380005	12.03
207.0810394	0.09
211.2280273	0.19
213.1454163	0.04
221.2993774	0.09
225.2048950	2.84
227.2076569	0.10
254.9103394	0.06
256.0759277	0.09
266.1315308	0.05
271.3027649	0.09
272.1719055	0.21
275.3339844	0.11
276.3784485	0.31
293.2812500	0.06
297.1752014	0.07
301.3019104	1.39
302.2378540	1.19
311.0337524	0.09
313.2114868	0.25
315.4907227	0.10
325.3746338	0.14
327.2557373	0.09
329.1777344	0.18
331.0460205	0.14
337.5136108	0.20
341.1298828	0.30
343.2780762	0.47
344.2745361	0.48
345.0573120	0.08
346.4650879	0.04
353.3068848	0.21
355.3679810	0.24
356.1613770	0.06
359.2390137	71.50
359.8409424	0.28
361.4245605	0.17
363.2320557	0.07
373.2658691	61.39
376.4390869	0.38
379.2747192	0.44
388.3440552	0.15
389.1978760	1.42
399.2531738	0.07
403.1566772	4.01
407.1871948	47.72
407.8380127	0.10
413.4378052	0.03
417.0839233	0.05
419.4512939	0.05
421.1820068	70.78
422.1041260	0.14
423.1869507	0.49
426.2913818	0.14
433.5166626	0.14
435.1373291	0.11
439.2584839	0.10
441.3560791	0.63
445.4871826	0.04
451.3424683	0.10
453.4255371	0.15
463.2913208	0.44
466.7055664	0.24
467.4135742	0.11
471.2551270	0.10
473.3723145	0.04
474.4014893	0.05
477.0413818	0.04
479.0993652	0.07
481.4617920	0.03
483.6110840	0.08
501.4391479	0.06
505.2730103	0.22
507.2500000	0.27
509.2124634	0.14
510.0775146	0.10
515.3501587	0.50
517.1589966	0.80
517.9282837	0.02
519.0050659	0.04
520.2948608	0.11
528.6270752	0.04
530.5413818	0.08
540.2589111	0.04
541.4639893	0.19
542.1931763	0.10
543.3425293	0.05
544.4546509	0.07
549.2307739	0.11
553.2377930	0.03
555.3478394	100.00
556.0487671	0.43
557.3333130	0.98
559.1424561	1.80
560.5419922	0.06
561.5032349	0.06
567.4175415	0.04
573.5449829	0.04
575.4129028	0.04
581.1760864	0.33
585.1099854	1.70
585.9389648	0.48
588.3410034	0.08
593.4304810	0.09
595.1520386	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2082
Annotation	Amritoside C
Peak:m/z	Relative Intensity
179.1380920	0.07
207.0624390	1.71
208.7708130	0.06
223.3509521	0.12
243.2632751	0.17
245.2181396	0.07
247.4192810	0.07
249.1878357	0.47
259.2083130	0.34
263.2084351	0.05
267.3013916	0.11
271.6950073	0.09
277.3599854	0.04
278.8009644	0.12
283.0136108	0.34
284.2724609	0.09
301.3001709	0.36
315.2672729	0.11
317.1311646	0.06
318.3856201	0.16
325.2737427	0.06
326.2571411	0.39
329.2418823	89.08
330.3058472	2.38
331.3025513	0.26
339.2489014	0.07
341.2310181	100.00
342.3432617	2.17
343.1493530	0.18
345.1677246	0.70
353.1187744	0.07
358.9426270	56.67
359.9995728	0.40
363.1619263	0.23
369.0693359	0.06
373.1776733	0.08
375.3350220	0.05
381.4819336	0.29
386.5814819	0.30
387.4342651	0.22
391.3906860	0.12
401.3473511	0.51
405.4470825	0.04
407.2863770	0.10
409.4074097	0.25
417.3536377	0.24
422.4852905	0.06
429.3393555	0.03
433.0509644	0.34
435.2911987	0.14
436.3970947	0.13
438.4312744	0.07
443.3731689	0.27
446.9780273	0.09
452.1278687	0.09
455.3765869	0.10
468.2916260	0.07
471.2795410	0.45
472.3728027	0.21
480.3280640	0.08
481.3052979	0.23
486.2873535	0.18
491.1535645	0.85
501.2844238	0.06
503.3759155	0.09
507.3963623	2.53
520.1124268	3.45
521.0331421	44.60
522.1403198	0.69
523.1771851	2.88
523.9213867	0.10
524.9573364	0.17
528.4141235	0.15
531.5538940	0.43
536.2398071	0.07
537.2727661	0.11
540.4766846	0.05
547.0348511	0.04
548.5951538	0.46
549.4544067	1.13
550.4512939	0.46
558.2733765	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.1122
Annotation	Melicitrin
Peak:m/z	Relative Intensity
143.1293793	1.08
167.0969086	1.91
276.1015930	6.17
291.0274963	0.95
321.1186218	100.00
345.0664673	1.47
363.0818481	3.93
387.4970703	4.47
447.4435730	4.33
465.3409729	4.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0078
Annotation	Unknow
Peak:m/z	Relative Intensity
147.0204773	0.07
164.9881439	0.11
167.2104340	0.03
168.9508362	0.10
172.9461670	0.06
186.2577820	0.07
193.8240356	0.09
194.6002197	0.16
200.0225677	0.20
202.9576263	0.02
205.0853577	0.11
213.9209442	0.05
215.0677643	0.06
216.0368500	0.25
217.2430420	0.11
218.0579376	0.69
222.0974426	0.05
224.0043335	0.07
228.2441101	0.05
230.0848541	1.16
231.4707947	0.08
234.0168152	0.11
235.9414368	0.04
242.0235596	0.08
245.3761597	0.04
254.0010376	0.23
254.6109009	0.06
255.9763489	0.06
257.6772461	0.24
258.3486328	0.15
258.9640503	0.07
264.2735901	0.13
265.2282104	0.04
274.8414307	0.05
275.8573608	0.21
277.1044922	0.04
278.1602173	0.08
279.2055664	0.09
281.2100525	0.10
287.0811157	0.03
290.1697693	0.27
292.0144043	0.20
295.4051514	0.07
297.9696655	0.05
299.8884888	0.15
301.7065430	0.24
302.4499512	0.21
304.2012939	0.79
306.1312866	2.20
310.0585327	0.50
316.0338745	0.14
317.3272095	0.04
318.1368103	0.26
328.0837097	0.14
329.1718140	0.04
333.3709106	0.07
334.9047241	0.21
336.0394897	10.24
338.0628662	0.04
347.1014099	0.11
349.2888184	0.17
350.0899963	0.30
351.0140381	0.12
357.9324341	0.07
359.8716431	0.09
362.8186340	0.09
363.9279175	0.26
365.2850647	0.43
366.0776978	0.23
377.9127502	0.06
379.9298706	0.08
382.0764465	100.00
382.6907349	0.18
383.5101929	0.05
385.2971497	0.09
389.6768494	0.05
395.8030701	0.12
407.2422791	0.96
408.2571411	0.61
425.4375610	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.19
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
112.9351044	1.26
125.1022034	0.31
129.1032562	0.20
138.1156616	0.46
143.1084900	1.48
148.9263153	0.40
150.9797058	0.85
153.0030823	29.02
159.0098267	1.48
161.0468292	8.97
162.9823608	0.16
164.0441284	2.10
165.0594177	0.29
177.1087494	0.25
179.0277100	2.66
180.2322845	0.35
180.9295197	0.91
183.0639496	0.67
187.1693115	0.90
188.9903259	0.51
190.0246887	4.46
191.1518555	0.06
192.0584717	0.25
203.2156372	0.63
205.1248474	67.77
207.1062012	0.24
208.1518707	1.48
221.1949463	0.46
223.0665741	100.00
225.0881653	0.09
230.9752197	0.25
232.0045776	0.16
233.0694275	0.28
234.2846985	0.25
236.9848633	0.81
247.0619507	39.62
247.6786194	0.23
249.1646729	0.07
250.1584473	0.14
252.1669922	0.16
262.9804993	0.32
265.1958008	8.44
276.9813538	1.76
277.6094360	0.45
278.4630127	0.54
279.3132629	0.31
280.9128418	0.13
289.1591797	0.77
294.2720337	0.22
295.1275024	2.31
305.3955383	0.27
322.6809082	0.17
325.1831665	4.79
339.2651062	0.10
341.2009583	1.80
343.4166870	0.34
351.3646545	0.09
357.1618652	0.12
367.3014221	1.28
370.3006897	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1041
Annotation	Castamollissin
Peak:m/z	Relative Intensity
141.0618744	0.07
149.2275848	0.08
151.0165253	1.66
153.1010132	0.31
158.9434509	0.02
161.2675781	0.06
162.8932800	0.18
165.1984863	0.15
169.0525513	0.47
174.9553070	0.02
175.9675598	0.19
177.3124847	0.02
179.1026154	0.98
180.0755005	0.09
181.0074158	0.30
186.0863037	0.14
187.1724548	0.06
188.1467743	0.08
189.0928345	0.22
190.0393677	0.07
190.9335327	0.05
192.0376282	0.39
193.0406647	0.08
198.2594910	0.06
199.0546875	0.02
200.9996338	0.04
202.1655579	0.03
203.1955261	0.24
204.1456299	1.05
205.0122986	0.30
207.3361969	0.15
209.2102051	0.15
211.1989746	0.15
212.9959412	0.05
215.2348022	0.05
217.0594025	0.08
218.1437988	0.03
220.0089569	0.08
221.0885010	0.03
223.1326141	0.03
227.2423401	0.05
229.2881470	0.10
231.1713257	0.21
232.0505066	0.10
233.1386871	0.37
235.0413055	0.07
236.9108429	0.18
239.2273865	0.29
239.8782654	0.07
240.9483032	0.04
242.1299438	0.02
243.1905060	1.80
244.5006561	0.10
245.1977539	0.25
246.8235016	0.23
247.4293823	0.02
249.1018066	0.06
252.2522888	0.04
254.1799622	0.32
255.1269226	0.16
256.0953064	0.07
257.1130676	0.46
259.3242493	0.20
261.3232422	0.10
268.3327026	0.13
269.2861938	0.07
270.1823425	0.43
271.2245178	3.90
272.1852417	0.56
273.2413025	0.56
275.2276306	0.05
280.9292297	0.19
283.2296143	0.30
284.1733704	0.35
285.1264038	5.12
286.1247864	3.15
287.1644897	1.16
289.1008606	0.33
295.3600464	0.10
296.0553894	0.05
297.0923462	0.21
298.2852173	0.48
299.1347656	4.99
300.2050781	5.44
301.0389404	0.25
302.1223145	0.08
303.3161316	0.16
307.2702637	0.26
308.1814880	0.08
310.7632141	0.23
311.4015808	0.18
314.1478882	100.00
315.1303711	67.59
316.0491333	0.90
317.2416687	0.11
319.3604736	0.12
321.9860840	0.05
323.0097656	0.03
324.4839783	0.15
325.1267395	0.14
327.3241882	0.25
329.2226257	2.57
330.1320496	0.02
331.2700806	0.57
337.2514038	0.11
339.0398254	0.27
341.0451355	0.23
342.1967163	0.50
343.2423096	0.07
344.5314331	0.18
350.2460938	0.04
352.9842224	0.08
354.1050415	0.07
355.1452026	0.12
357.1694946	20.92
358.6674805	0.13
367.0665283	0.14
369.3421631	0.33
370.1015930	0.09
372.4272766	0.04
373.1741943	0.04
381.4096069	0.16
385.4693909	0.03
387.1881104	3.25
393.4433594	0.07
398.9001770	0.07
400.3251343	0.05
401.4679871	0.02
409.1230774	0.27
413.0210266	0.05
417.4366760	0.05
429.3936768	0.03
430.4607849	0.09
433.4285583	0.30
435.2378845	0.06
441.3547974	0.03
445.3595886	0.23
447.4646301	0.05
449.2950745	6.76
450.3007202	0.14
459.1311951	0.35
462.3197937	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.98
Annotation	Unknow
Peak:m/z	Relative Intensity
67.0691452	0.07
73.0941391	0.08
81.3711548	0.04
85.0273895	0.02
87.0654602	0.04
95.0018005	0.16
98.9190521	0.06
109.1896973	0.11
112.9880981	0.19
114.1277924	0.02
116.1103973	0.06
120.1715240	0.09
121.0503082	0.09
124.7613831	0.02
126.2074585	0.03
127.2525787	0.03
135.2459106	0.11
137.0801544	0.06
140.3374176	0.07
142.2874298	0.02
143.3634796	0.07
151.9180450	0.10
156.0127411	0.06
157.4001007	0.07
158.1818085	0.02
167.1743774	0.04
169.1696167	0.32
169.8340454	0.04
171.2415924	0.05
176.7194672	0.17
178.7848358	0.12
179.8319244	0.04
182.0780640	0.28
184.0925140	0.06
185.2548676	0.30
186.8840942	100.00
188.0841217	0.14
191.2086945	0.42
192.0130768	0.20
196.4925842	0.09
197.1841278	0.05
198.0306854	0.04
198.9051208	0.17
200.0651245	0.45
203.0606842	0.02
203.9096375	0.11
204.6556549	0.92
205.6019897	0.15
207.4665070	0.32
209.1062164	1.46
210.0919342	1.22
211.0859528	0.18
213.5064545	0.16
216.1693726	0.36
218.2787323	0.21
219.7503662	0.25
223.1426392	0.08
226.9947662	0.03
227.6384125	0.04
228.5890503	0.06
239.8839722	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.0222
Annotation	Unknow
Peak:m/z	Relative Intensity
179.2856598	0.05
185.1539764	0.05
191.1380005	0.12
213.1348877	0.32
254.8595581	0.09
273.1976929	0.92
289.2290039	0.10
298.9099426	0.22
306.2183228	0.56
307.0504150	0.23
308.2216797	0.08
317.0914917	1.82
340.1553345	0.07
358.9932251	0.44
385.1361694	0.04
403.1192017	6.11
421.0650635	100.00
421.6779175	0.24
451.3266602	0.05
459.8796387	0.07
464.4919434	0.24
479.3851929	0.06
482.1414795	0.06
483.2568970	0.19
484.3101807	0.04
487.5488281	0.06
497.1956177	0.07
509.0586548	0.04
576.3596802	0.12
594.4242554	0.25
595.2964478	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.22
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9401245	0.38
161.0516663	0.26
165.1201477	0.05
180.1786804	0.16
185.0725250	1.71
191.1134338	0.69
193.0726013	0.05
199.3698120	0.06
209.3341064	0.23
218.0483093	0.07
220.8638458	0.50
227.3583069	0.10
233.2336273	0.08
234.1660461	0.04
235.2127380	0.08
239.1723022	0.23
243.4521179	0.07
251.2228088	0.17
257.0116882	0.32
258.4106445	0.13
259.2166138	0.05
263.1073608	0.15
265.2865906	0.13
273.2963867	0.05
275.1965027	1.11
277.1004639	0.38
279.0816650	0.07
281.2218628	0.10
284.0681152	0.05
289.2110596	0.14
293.2280273	20.80
295.1148071	0.06
297.1324463	0.09
298.4180298	0.10
299.6067810	0.19
301.1295776	0.68
302.1903687	0.16
303.3558350	0.47
309.0836182	0.06
311.1693726	1.89
313.3978271	0.11
317.0424805	0.22
319.2731934	0.23
328.1099243	0.08
331.3716431	0.31
334.4152222	0.04
335.1618042	0.07
339.0647583	2.69
343.3533936	0.57
344.2567749	0.08
345.2078857	2.01
347.3570557	0.14
348.2424927	0.05
350.1964111	0.29
352.1355591	0.04
355.4052734	0.14
357.3750610	0.16
359.4492188	0.25
362.2990723	0.15
363.3497925	0.44
371.3530884	0.09
373.4167480	0.43
374.1257935	0.08
375.0603027	0.07
379.3594971	0.03
381.4211426	0.03
388.4694824	0.12
389.6026001	0.06
395.1882324	0.36
397.2188721	0.24
398.0928955	0.24
399.6996460	0.25
404.3065186	0.18
406.9903564	0.18
419.3986816	0.24
422.8652344	0.09
437.2962646	0.10
438.8388672	0.07
439.4656982	0.55
443.2418213	0.08
446.3005981	0.35
447.3865967	0.06
448.9622192	0.11
452.0704956	0.04
460.9682617	0.08
462.4929810	0.26
477.3080444	0.04
479.2376099	100.00
481.4992676	0.75
489.2843018	0.16
493.2445679	0.73
496.0434570	0.04
497.2017212	0.11
504.2041626	0.04
506.6041260	0.47
507.3024902	0.91
510.2160645	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.11
Annotation	Unknow
Peak:m/z	Relative Intensity
135.0011292	0.03
137.1427307	0.08
143.3085022	0.03
147.0418091	0.06
149.1495209	0.06
153.1996765	0.02
161.2898560	0.03
163.8754578	0.06
164.7283936	0.07
181.0292969	0.17
189.0120544	0.11
217.1003723	0.11
218.0593872	0.02
219.2703857	0.04
221.1445770	0.04
225.3911438	0.02
227.2141113	0.05
228.7593384	0.07
229.3906403	0.08
233.0362396	0.05
235.3854675	0.20
237.2100525	0.02
241.1279907	0.08
245.2049561	0.12
247.3334656	0.05
253.1104736	0.04
257.2037048	0.03
259.0598145	0.06
261.1790771	0.03
263.2032471	0.11
264.2160034	0.04
265.3392944	0.05
267.0398865	0.06
269.0376282	0.05
270.1715393	0.15
271.1095276	0.05
272.0033569	0.16
273.0314636	0.03
279.4605408	0.07
280.5963440	0.08
281.4088135	0.16
283.3270264	0.09
284.1629639	0.11
285.2322998	0.60
286.2742615	0.14
287.2974548	0.38
288.2030945	0.03
289.4004517	0.04
293.1883545	0.02
294.0828552	0.08
297.2120361	0.29
298.1690369	0.02
299.1946411	0.77
301.0401611	0.06
303.3133850	0.06
305.2309875	0.02
307.0939026	0.17
308.1526489	0.07
309.0421143	0.02
311.1794434	0.11
312.3132324	0.13
313.2861328	0.19
314.2864075	0.69
315.1173706	0.11
317.1424255	0.42
325.4734497	0.07
327.1837158	5.97
328.1791992	46.06
329.1686096	100.00
330.1808167	1.12
331.2516479	4.10
333.3968201	0.03
337.1245117	0.03
339.1956177	0.15
341.0949402	2.74
343.1190186	6.45
345.4932861	0.02
347.1513062	0.16
350.2427673	0.04
353.3118286	0.71
355.3439331	0.28
357.2135925	0.37
358.1627197	0.03
359.1620789	0.11
365.5234985	0.02
366.3592224	0.10
367.0083008	0.02
368.1248779	0.08
369.2136230	0.43
370.0037842	0.04
371.1571655	3.07
372.5835266	0.14
373.3628540	0.19
375.3818054	0.06
381.1109924	0.18
383.2158203	2.04
385.3666687	0.10
386.0475159	0.05
386.9109192	0.03
389.7898560	0.05
395.3651123	0.08
397.4001160	0.17
399.2026367	0.16
400.1716614	0.09
401.1810913	4.00
403.0655823	0.07
407.1561584	0.15
413.1616821	0.15
414.1919250	0.02
415.3951111	1.51
416.7238770	0.07
417.4202881	0.18
418.5263367	0.06
420.3897400	0.09
424.1294861	0.03
425.2314758	0.28
429.2743225	1.47
432.1243286	0.03
433.5430298	0.03
434.3498230	0.26
443.2545471	0.69
446.2062683	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
131.2367554	0.23
148.8774109	0.09
161.1885376	0.05
179.0482025	0.08
195.9451294	0.05
207.0901337	0.05
236.9437561	0.11
249.1498413	0.27
256.1020203	0.06
266.9404907	0.20
290.8646851	0.11
297.6256104	0.31
298.9336548	0.13
300.4042053	0.12
304.2793579	0.17
322.8565674	0.12
325.4488525	0.11
326.3795776	0.12
341.2063293	100.00
342.9642334	0.16
354.3341064	0.06
369.0124207	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	496.14
Annotation	Unknow
Peak:m/z	Relative Intensity
243.2543793	0.01
303.5934753	0.01
331.2054138	38.99
332.2128296	48.06
333.1932068	100.00
334.2084351	17.48
363.0715942	0.02
367.4793396	0.03
369.3562012	0.06
396.3528442	0.02
415.4527283	0.01
419.5270081	0.02
441.0767212	0.02
449.9971313	0.07
467.9003601	0.01
478.5396423	0.03
479.2619934	0.04
484.9408569	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.0911
Annotation	Avicularin
Peak:m/z	Relative Intensity
259.1314087	0.01
273.1200867	0.04
287.3545532	0.01
303.1263428	100.00
303.9913330	0.02
309.0565491	0.04
315.0328369	0.02
322.5870667	0.01
381.3352356	0.01
399.6166992	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.14
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1999969	0.12
163.6887360	0.04
166.3036652	0.02
173.0477905	0.06
175.1088867	0.12
177.1702271	0.12
179.1531982	0.18
186.3297882	0.06
186.9486084	0.17
188.0070496	0.06
191.1330414	0.12
199.0005341	0.03
201.2398376	0.03
203.2199707	0.42
205.1832428	0.23
212.3931732	0.05
215.0173950	0.11
217.3359375	0.05
219.2837067	0.06
221.2560120	0.03
225.2032166	0.07
227.3677673	0.11
228.1248627	0.03
229.0385284	0.27
231.3243866	0.07
241.3127747	0.05
243.2459869	0.49
245.2128754	3.12
247.1865845	3.35
255.1904449	0.17
257.4543762	0.06
259.2904663	0.02
261.3334351	0.09
266.8922729	0.05
269.1579895	0.29
271.1130066	0.22
273.2196045	1.98
275.1279907	0.04
277.4072876	0.04
281.0856934	0.22
285.2724609	0.07
287.1980591	11.61
288.1167603	0.10
289.1290283	17.04
290.2937012	0.08
293.4510498	0.02
299.1489563	4.20
301.2233887	0.07
311.3617554	0.11
319.4937134	0.02
323.2057495	0.17
324.3485718	0.04
327.3029785	0.19
329.0912476	0.55
330.3980103	0.13
331.2094727	0.47
337.0789185	0.10
339.2115479	0.18
341.1661987	0.19
343.2928467	0.09
347.4531250	0.03
351.1341553	0.04
355.2652588	0.12
357.4091187	0.14
361.3925171	0.02
369.3414917	0.05
375.3746338	0.03
381.3472900	1.54
383.2515259	0.11
389.2869873	0.08
397.1937256	0.04
403.4378052	0.04
405.1701050	0.04
407.2479858	47.94
409.2751465	0.58
411.1945190	0.09
412.3599243	0.03
413.2568970	0.21
414.3919678	0.28
415.2723389	0.33
416.0576172	0.15
417.4145508	0.16
419.3296509	0.05
423.2709351	0.22
425.2130127	100.00
426.2736816	0.08
430.6015015	0.02
431.6210327	0.27
433.0797119	0.54
433.9083252	0.10
436.2353516	0.10
437.2365112	0.07
439.0166626	0.03
445.2320557	0.03
449.3328247	0.90
451.3208008	25.17
453.5571289	0.02
461.2971191	0.07
463.2573853	0.14
465.4730835	0.03
467.1719360	0.93
469.7695923	0.02
473.5067749	0.10
477.2990723	0.08
478.5043335	0.07
483.3134766	0.13
487.4130859	0.27
491.3513794	1.72
492.2158813	0.39
495.3644409	0.25
497.2152100	0.07
499.1411743	0.07
500.3375854	1.57
501.2809448	0.35
503.4602661	0.12
509.1629639	0.03
510.5249023	0.02
512.6055908	0.03
513.3073730	0.04
514.2732544	0.02
515.3410645	0.18
516.2774658	0.04
517.3187256	0.17
529.1890259	0.21
530.7239990	0.71
531.3392944	1.59
533.2033081	0.88
534.8545532	0.08
535.6156006	0.01
540.2466431	0.04
541.2307739	0.16
554.5021362	0.15
555.7697144	0.02
556.4193726	0.01
559.2649536	9.51
559.8699951	0.26
561.2669678	0.13
562.2595825	0.08
567.2202148	0.26
567.9472046	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.14
Annotation	Luteolin 7-(2''-glucosyllactate)
Peak:m/z	Relative Intensity
298.2609253	0.01
331.1436157	100.00
332.0066528	0.00
355.3552856	0.01
447.2595215	0.01
453.8524780	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	845.215
Annotation	Unknow
Peak:m/z	Relative Intensity
238.9465942	0.02
241.0114899	0.14
243.1467438	0.10
254.1948547	0.22
255.0676575	0.50
257.1428223	0.03
269.9432373	0.52
271.1425781	0.24
272.3134155	0.10
276.8735962	0.10
280.0892029	0.02
280.8937988	0.07
282.1216125	0.28
283.3440857	0.10
284.1918945	0.33
285.1538696	0.55
287.1515198	0.09
296.4285889	0.08
297.2317505	0.11
298.0364380	0.27
299.1995544	0.25
300.2807617	0.02
302.3606873	0.10
303.1209106	0.05
313.2171936	2.32
314.2185059	0.83
315.3454895	0.16
322.8700867	0.07
327.3397827	1.45
328.2508850	7.05
329.1321716	5.10
330.3477173	0.13
331.2826538	0.84
341.3845520	0.04
343.2413330	0.49
353.1287231	69.49
353.7545471	0.13
357.1118164	0.22
369.6266479	0.07
371.2553711	0.52
381.5165405	0.05
383.0455933	0.25
395.1298828	0.27
401.0537720	0.09
413.1721191	0.05
425.2037964	0.08
455.2894897	0.03
459.3710327	0.19
473.1205444	0.14
477.3475952	0.03
491.2752075	100.00
515.2300415	0.43
543.2150269	0.27
653.1746216	1.50
654.4559937	0.10
683.0635376	0.67
684.4575806	0.10
785.5060425	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
131.0379639	0.28
179.3414154	0.37
181.2843781	0.17
201.3210907	0.27
256.0576782	0.11
270.1650085	0.27
283.098175	0.25
287.0476074	75.00
288.1088867	0.09
293.497406	0.40
298.3687439	0.37
302.2600708	0.46
303.2835083	0.62
314.3809204	2.02
317.1829224	100.00
327.3144836	0.11
328.1900024	0.24
332.5740356	0.17
335.6786194	0.21
342.1643372	0.17
350.361969	0.41
351.3144531	0.36
362.8702087	0.20
365.4380188	0.18
367.3225098	0.85
380.9416809	0.31
385.0389709	0.99
386.1153259	0.70
389.1482239	0.37
390.3403015	0.34
390.9572754	0.54
394.6072693	0.40
399.3594971	0.40
401.2365112	0.36
404.2782593	0.20
413.0339661	0.99
417.1789246	0.79
421.5005798	0.71
428.8076477	0.61
430.1771851	0.67
431.1690063	0.59
432.0420532	1.08
434.3480835	0.27
440.222168	0.77
449.2133484	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8944
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1054993	0.02
146.9833832	0.13
159.0577850	0.24
160.1682587	0.02
174.9712982	1.07
230.1201172	0.02
245.1973877	0.09
261.1524048	0.05
273.1348572	6.96
274.0535278	0.34
275.1726379	0.04
285.1823425	0.05
289.0158691	26.40
289.8602905	0.01
291.0146484	0.02
301.8430176	0.01
302.9774170	0.01
304.9486084	100.00
305.7543945	0.01
328.8552246	0.07
330.1360779	0.01
343.9729614	0.01
345.0508728	0.24
347.0607300	0.13
347.8716431	0.05
363.0379333	0.30
365.1333923	0.01
373.1327209	0.05
374.1033325	0.29
375.0757141	0.21
390.9258728	0.02
399.4909363	0.02
400.9067688	0.04
404.6392212	0.06
408.1170349	0.03
409.3556824	0.01
418.9615784	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2133
Annotation	S-Furanopetasitin
Peak:m/z	Relative Intensity
142.9887085	0.32
145.3624725	0.32
149.0000458	2.81
152.8334961	0.22
160.2783661	0.13
161.0764160	0.34
164.2920532	0.06
166.9923401	1.03
178.9596863	0.15
191.1109924	1.07
193.1221008	0.08
219.2021484	0.09
220.1091309	0.12
220.7505188	0.34
232.7214050	0.09
238.2538452	0.17
239.1386414	0.42
251.1581116	0.12
262.6808472	0.12
269.0720215	0.21
275.3016968	0.59
280.6964417	0.12
281.3402405	0.07
284.1415100	0.40
285.3022156	0.46
287.0871887	0.70
293.1061707	0.50
297.1811829	1.47
307.1156006	1.04
308.2210693	0.62
309.3491211	0.68
311.0024109	2.57
313.2176514	4.82
314.0947876	0.30
315.1585083	2.27
316.4152222	0.12
321.6250610	0.12
323.1545410	0.96
328.2947083	0.24
329.1650085	3.81
331.4745178	0.25
337.1687012	0.25
339.1057739	0.11
355.1863708	0.21
359.5146484	0.14
367.1046753	0.14
369.3673401	0.42
371.4910583	0.30
381.3995056	0.09
385.0888672	0.17
401.0860291	0.19
403.4126892	0.56
405.6252136	0.20
417.1348877	0.09
429.5216370	0.12
431.6658325	0.06
445.2821350	100.00
447.1569824	0.14
448.9929810	0.33
459.0679626	0.85
470.3204651	0.47
473.1335144	2.04
473.9880981	0.27
476.4338684	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.0773
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1431274	0.02
151.0756683	0.98
152.0368500	0.13
153.1664734	0.05
161.1255493	0.03
163.1795959	0.09
169.1545410	0.19
175.0754089	0.01
179.0965424	1.50
180.0544434	0.23
181.0923462	0.03
185.3782349	0.02
187.1476440	0.02
189.0191040	0.11
189.9186249	0.03
191.1603851	0.12
192.5022583	0.01
193.2238159	0.05
193.9828186	0.04
197.0729065	0.17
198.2905426	0.01
201.2372894	0.03
205.2330780	0.03
207.1293335	0.01
209.2454834	0.03
210.1434174	0.02
213.1463623	0.02
217.2063599	0.17
219.2139130	0.02
221.1823425	0.19
222.3488770	0.05
227.2331696	0.09
229.1149292	0.40
230.4887543	0.01
231.3074646	0.05
232.3501129	0.01
233.2671509	0.05
237.4268188	0.02
239.0216980	0.01
241.2790833	0.04
242.1688843	0.01
245.4779968	0.01
246.2561951	0.03
247.2238464	0.07
248.3407593	0.02
249.4586487	0.01
251.2167358	0.12
254.0216675	0.08
255.2424622	0.29
256.1551819	0.07
257.2996826	0.06
257.9692078	0.01
258.6064758	0.01
259.3437805	0.12
260.2413635	0.01
261.2272034	0.02
264.0996704	0.01
265.3965149	0.03
267.4420776	0.02
269.3631897	0.05
271.0878601	0.28
272.2969666	0.15
273.1649475	0.41
274.2645874	0.06
274.8868408	0.01
275.4886169	0.02
276.2907104	0.02
277.1768188	0.01
279.0571289	0.02
280.2384644	0.03
281.0203552	0.05
283.1306458	0.03
284.5868225	0.05
285.1992493	0.10
287.1473694	0.04
289.4526672	0.17
290.3455811	0.01
297.2574768	0.28
300.1430054	85.69
301.1098938	100.00
302.1376038	14.63
303.1220093	0.04
307.1537476	0.49
308.3235168	0.08
310.4365540	0.01
311.1705322	0.02
312.0988159	0.09
313.2588501	0.31
314.3046265	0.14
315.0251465	0.05
323.1629639	0.10
324.3114624	0.04
325.3190308	0.37
326.0319519	0.04
327.2277832	0.05
329.3229065	0.01
337.1638184	0.05
341.3428955	0.02
343.1630249	4.14
344.1188354	0.85
345.4557495	0.02
347.5125732	0.01
351.1595764	0.02
355.1029968	0.22
356.4171143	0.03
358.1851501	0.01
361.4981689	0.04
365.1635437	0.04
367.3261719	0.01
373.1547852	0.38
374.2633057	0.13
379.1940002	0.11
385.1039734	0.01
389.3518982	0.16
391.0675964	0.05
397.0627136	0.07
398.2109680	0.06
403.2138977	0.02
415.1710205	0.72
416.2821655	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.9254456	0.02
125.1603546	0.01
127.1946564	0.11
134.0235596	0.02
135.129837	0.48
155.1852112	0.02
161.1473694	0.43
171.1420288	0.00
172.9921112	0.30
179.0279236	3.71
191.0541687	100.00
191.8496399	0.01
217.236908	0.02
262.1372681	0.02
292.1986084	0.02
293.5486755	0.02
309.0140686	0.01
317.2449341	0.04
338.2738647	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	811.1681
Annotation	Unknow
Peak:m/z	Relative Intensity
259.2009888	0.01
263.0190735	0.02
270.0830383	0.01
277.4064941	0.02
299.1341858	0.02
301.2289429	0.10
303.3277588	0.02
317.3783569	0.02
319.2957153	0.01
320.2393188	0.01
331.4086304	0.09
338.4675903	0.02
343.2292480	0.06
357.3937683	0.03
371.3574829	0.02
400.1691284	0.01
403.3198853	0.02
411.3533325	0.02
430.2481079	0.02
437.1842651	0.01
463.6234741	0.01
465.2439575	0.06
469.2929077	0.01
479.3329468	0.05
481.8614502	0.02
483.3989868	0.02
497.2736816	0.05
507.3547363	0.04
523.2926636	0.02
540.5159302	0.01
567.3523560	0.01
585.3720093	0.04
589.4970093	0.03
605.2148438	0.10
606.3771973	0.65
607.3767700	0.20
610.6843262	0.03
613.4243774	0.02
617.4200439	0.03
631.3947144	1.76
644.9848022	0.01
647.5096436	0.13
649.2508545	100.00
649.9641113	0.26
652.1271973	0.06
659.4135132	0.03
661.3667603	0.03
673.3241577	0.05
678.6254272	0.04
679.2604370	0.12
684.5653687	0.02
688.1697998	0.02
689.3071899	0.02
745.1339722	0.07
747.4497681	0.01
792.6896362	0.14
793.4931030	0.38
796.1050415	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.01
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9709167	0.10
175.0767822	0.04
191.2612915	0.04
200.0302124	0.05
204.7841187	0.08
210.2479858	0.06
213.1891479	0.08
216.0967255	0.13
217.7952118	0.13
229.9831543	0.64
233.0229340	0.15
234.3586426	0.10
241.9302063	0.12
244.9748840	0.07
246.0813904	0.09
253.9491882	0.27
258.0165710	0.73
275.4472351	0.03
276.2002869	0.03
277.2975464	0.13
279.4104309	0.07
292.1528320	0.09
297.9226685	0.04
301.9667969	0.80
304.4508362	0.38
305.0939331	0.85
306.0728455	1.54
310.3471680	0.07
317.0890198	1.50
318.1139221	1.18
322.0863647	0.33
327.8886108	0.06
330.0655518	0.17
332.1725464	0.09
335.0955811	2.34
335.9882812	12.11
337.9580688	0.05
341.3681335	0.04
343.0476685	0.06
345.1595154	0.42
345.9819946	0.10
348.8944092	0.06
351.2456360	0.11
355.0489502	0.16
363.1333923	0.16
364.2802429	0.45
365.1716003	1.06
366.0678406	1.12
366.7942200	0.06
373.0798645	0.05
379.4374084	0.07
382.0965576	100.00
385.1961365	0.35
389.0892334	0.31
390.1769104	0.37
391.1698303	0.07
405.3376160	0.06
407.1197510	1.43
408.1246033	2.04
417.1262207	0.25
426.0830078	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.3303
Annotation	Unknow
Peak:m/z	Relative Intensity
261.1004944	0.02
265.2119141	0.01
282.3816223	0.01
283.3388062	0.02
287.2780151	0.07
293.1084595	0.03
295.3556824	0.04
300.2408142	0.01
302.1470947	0.02
311.1164551	0.03
318.2689819	0.08
319.3139954	0.02
323.1988220	0.02
325.3121948	0.07
329.2576904	0.01
335.2866211	0.38
336.4639282	0.05
337.8785400	0.01
343.3925171	0.02
344.2654419	0.02
346.3853149	0.04
351.2861938	0.02
359.5854492	0.02
360.3899536	0.01
366.5395508	0.04
370.1519775	0.03
371.4564209	0.02
372.3844299	0.13
400.3555298	0.01
407.4485474	0.02
414.3367920	0.56
415.2939453	0.10
418.2941895	0.08
419.3311157	0.09
442.4847412	0.05
444.5627441	0.04
445.3621216	0.01
446.1796875	0.36
451.1312256	0.01
453.2788696	0.02
458.2982788	1.14
459.3043823	0.07
460.4597168	0.02
462.2344360	0.08
464.2263794	0.03
465.3562622	0.03
469.7461548	0.03
477.3738403	0.11
478.4240723	0.11
479.1737671	0.02
483.3681030	0.04
490.3914795	7.39
491.5433350	0.06
493.3325806	0.17
495.4272461	0.25
496.5276489	0.02
509.7380981	0.06
510.5175171	0.05
521.4367065	0.03
531.4480591	0.02
536.2568359	0.02
537.4446411	6.24
539.3547974	0.03
540.5286865	0.07
541.4298706	0.03
545.0771484	0.02
547.9797974	0.03
549.8132935	0.02
551.0683594	0.02
553.1356201	0.02
555.3183594	0.03
563.2734985	0.08
568.1069946	0.05
569.4873047	0.02
570.3810425	0.02
571.2434082	0.04
574.4627075	0.02
581.4404907	19.69
582.5008545	0.04
585.2856445	0.19
587.4954224	0.04
588.5439453	0.04
589.3534546	0.08
594.4756470	0.14
595.4288940	0.05
597.1116333	0.02
598.3221436	0.05
599.2688599	0.05
600.7777710	0.04
609.3263550	0.01
613.3656616	35.19
614.0105591	0.09
617.0598755	0.02
618.7142944	0.01
619.6625366	0.01
621.5438843	0.02
623.6101685	0.08
624.7459106	0.04
625.5444946	0.02
626.4004517	0.05
627.4291382	0.05
628.3481445	0.05
630.3209839	0.43
631.4792480	0.38
632.3587646	0.04
633.3849487	0.08
638.4439087	1.52
639.4965820	0.50
640.1956787	0.02
641.4250488	0.03
643.5124512	0.06
648.4310303	0.01
652.4805298	0.15
653.6158447	0.06
655.5666504	0.08
660.3212891	0.09
661.2601929	0.01
665.9106445	0.02
666.7042847	0.12
668.9777222	0.04
670.3621826	4.73
671.4929810	0.26
672.1849365	0.03
673.3757324	0.04
675.5432739	0.01
687.0247192	0.02
693.6608887	0.04
695.5442505	0.04
697.2171631	0.02
702.0348511	0.07
702.8369141	0.05
705.5001221	0.04
707.9014282	0.02
711.5205688	0.14
716.7046509	0.03
717.5142212	0.19
718.5900879	0.02
719.4448853	0.12
720.4649658	0.05
721.6411743	0.02
725.1314697	0.01
728.8640137	0.02
733.3952026	0.04
743.3291626	0.66
744.9299316	0.07
745.9914551	0.05
747.3928223	0.06
748.4705200	0.24
749.4611206	0.01
757.0348511	0.14
759.2076416	0.04
761.4127808	100.00
762.0458374	0.28
763.3724976	0.07
770.8278198	0.07
773.2592773	0.02
774.2074585	0.29
775.6215210	0.75
776.5252075	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2031
Annotation	Diospyrososide
Peak:m/z	Relative Intensity
161.1886139	0.25
164.8542480	0.30
173.1016998	0.09
173.9297180	0.10
175.0769196	0.09
178.9995422	0.62
183.2924194	0.07
193.0183716	0.07
215.0909576	0.06
217.1711731	0.05
218.0274963	0.11
221.1241455	0.22
230.3626251	0.09
233.0736389	0.06
244.3670654	0.04
257.1665039	0.96
258.2623901	0.38
259.0065308	0.63
262.1906128	0.13
266.8231812	0.05
273.3318176	0.10
274.3983765	0.18
277.1045532	0.46
283.1674805	0.13
293.1821899	0.53
294.3015137	0.20
301.1328735	2.55
302.1801758	2.08
303.2604980	0.62
311.1494751	0.20
312.1659546	0.11
315.3861694	0.26
319.3118286	0.16
320.2290649	0.12
321.2360229	0.11
327.2353516	3.65
329.4138184	0.07
331.1704712	0.18
334.0349731	0.04
338.2207031	0.04
341.3034668	0.11
343.0378418	0.03
344.5222778	0.77
345.1980591	2.03
347.2112427	0.50
348.2937622	0.11
351.2944336	0.04
355.2933350	0.04
359.0306396	0.34
360.4147949	0.03
361.4649048	0.04
362.3582153	0.29
363.3075562	0.21
371.1860352	0.15
372.7869263	0.05
373.4171143	0.16
374.3119507	0.24
375.1953125	0.09
378.3248291	0.07
381.5338745	0.28
383.3847046	1.05
393.0854492	0.20
395.2900391	0.04
397.0982056	0.34
398.1206665	0.87
399.3187866	0.53
401.7492676	0.29
403.3419189	0.14
405.7049561	0.09
409.5686035	0.13
415.1353149	0.10
416.2500000	0.15
425.2004395	0.23
429.3930664	0.09
431.2832031	0.10
434.8031616	0.37
437.1388550	0.04
441.4271851	0.07
445.3284302	0.05
453.2724609	0.08
457.2130737	0.15
462.2362061	0.30
463.4456787	0.06
476.2993164	0.36
477.4612427	0.66
479.2541504	100.00
479.9172974	0.12
481.5144653	0.14
482.4287720	0.08
483.2241821	0.10
486.0185547	0.06
489.1941528	2.02
492.2952881	0.08
493.9817505	0.06
495.3630371	0.08
496.4111938	0.13
497.4032593	0.19
498.2795410	0.06
505.1951294	0.46
506.3724976	0.26
507.3276978	1.41
510.2162476	0.18
515.9583740	0.22
526.4404907	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1591
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
209.1498413	0.01
214.9709778	0.02
225.0899353	0.07
229.1059570	0.18
247.3432159	0.05
254.1489868	0.03
255.0944824	0.03
257.1329346	0.24
260.2109680	0.03
272.7769775	0.07
285.1726685	0.20
291.1618652	0.01
303.1052246	100.00
304.1007690	0.05
308.9033508	0.05
312.7872314	0.03
315.3078613	0.02
317.2285767	0.06
327.4200439	0.05
333.0353394	0.01
344.6032715	0.04
345.2333374	0.30
367.2176514	0.02
369.3721924	0.06
399.4031372	0.04
411.2861328	0.03
417.1532593	0.02
425.2087402	0.02
429.1596680	0.16
430.4122314	0.02
431.1370239	0.02
437.2988281	0.01
447.1824951	0.79
448.4592896	0.26
449.1530762	2.62
455.1181030	0.01
456.6267700	0.02
465.0687866	22.44
465.9289551	0.01
471.3682861	0.03
473.2197266	0.27
478.5118408	0.03
479.3113403	0.06
489.2717896	0.06
491.2330322	0.12
497.4351807	0.02
513.1468506	0.02
520.6792603	0.02
527.1369019	0.02
527.7467651	0.03
529.2382202	0.04
530.2120972	0.08
535.0925903	0.03
537.2637329	0.03
542.3101807	0.01
545.0962524	0.06
548.8015747	0.02
557.3481445	0.27
575.2242432	0.18
580.0250244	0.01
583.3233032	0.01
591.1260376	0.02
593.0832520	0.20
612.2865601	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1551
Annotation	2''-O-Feruloylorientin
Peak:m/z	Relative Intensity
191.3379822	0.02
201.1533203	0.04
212.2183685	0.02
217.3229675	0.02
218.1896973	0.05
227.2673340	0.04
228.1466675	0.08
245.2581787	0.10
246.1264343	0.02
255.1240234	0.01
257.2401428	0.03
258.0402832	0.02
274.0421448	0.31
279.1993713	0.07
285.2169189	0.02
287.1477051	0.17
302.0757446	2.63
303.2191162	0.06
311.3744507	0.05
315.0275879	0.05
317.1296692	100.00
331.1604004	0.06
355.2157593	0.05
401.2005615	0.02
453.3187256	0.03
463.0904541	0.20
465.9055176	0.02
472.3480225	0.20
483.3553467	0.04
492.2940674	0.02
493.2819214	0.14
498.3515625	0.02
506.9129028	0.02
520.4255371	0.13
534.9282837	0.09
547.0011597	0.08
571.0601807	0.06
579.0285034	0.06
580.7106323	0.02
582.4728394	0.04
583.6600952	0.07
587.9067383	0.04
588.6951904	0.07
589.5253296	0.07
590.9473267	0.05
593.2579956	0.03
606.4954224	0.11
607.2755737	0.15
608.0557861	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1022
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
165.2677612	0.02
169.1340485	0.03
173.0810089	0.03
180.8692169	0.07
184.4111633	0.03
203.1365051	0.19
210.4551392	0.04
217.2250061	0.04
218.0179138	0.02
221.2057037	0.12
222.0212097	0.08
227.2524414	0.02
231.1303406	0.19
238.1560974	0.06
239.5095825	0.12
249.0241394	0.03
255.1599274	0.12
255.9435730	0.08
275.3537598	0.06
280.1439819	0.03
290.1542358	0.11
295.1390381	0.14
297.1617126	0.09
303.1030273	100.00
306.5343933	0.04
309.4467468	0.17
313.1217651	0.10
315.1809692	0.55
327.3945923	0.05
335.2227173	0.03
343.3076782	0.04
345.2824707	0.12
347.1766357	0.25
351.3304443	0.22
353.5022583	0.02
355.1804810	0.09
356.1649170	0.04
356.9838257	0.05
359.3012085	0.05
365.3358765	0.06
366.9872437	0.09
369.2048950	1.29
371.0695801	0.31
375.3774414	0.07
381.1990967	3.73
382.7390137	0.06
383.3480835	0.02
385.2763062	0.55
387.2631226	0.67
388.4771118	0.50
389.3637085	0.07
393.3555908	0.02
394.2301636	0.04
397.3358765	0.27
399.0850830	0.14
400.4089355	0.03
401.1555786	0.03
402.4286499	0.03
409.3970337	0.12
411.2453613	1.37
415.1783447	0.11
418.1926880	0.08
419.7974243	0.02
425.8171997	0.08
426.9610596	0.03
429.2669067	0.50
431.2246704	0.09
432.2365723	0.06
434.1588745	0.01
443.2217407	0.03
447.3325195	0.23
454.2324829	0.04
460.3291626	0.04
461.3472290	0.18
470.0880127	0.24
471.2247925	0.98
473.1828613	0.25
477.0147705	0.12
480.3959351	0.03
485.0999756	0.68
489.2599487	0.51
493.1489868	0.05
497.1672363	0.04
501.3576050	0.03
505.0348511	0.26
506.4408569	0.23
507.4047241	0.09
512.2003174	0.03
515.2250366	0.84
517.8439331	0.08
519.1870728	0.13
521.1845093	0.26
523.4014282	0.10
524.5312500	0.04
531.8900757	0.09
533.2042236	3.86
541.5045166	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.224
Annotation	Rourinoside
Peak:m/z	Relative Intensity
182.1857605	0.03
183.0574951	0.19
190.9624939	0.12
197.2072754	0.17
201.2536163	0.06
203.2004700	0.06
211.9559479	0.08
219.2414551	0.06
227.1969604	0.14
236.9830017	0.17
249.4729156	0.03
261.4844666	0.10
265.1484985	0.05
279.3494263	0.14
282.8874207	0.06
305.2628784	0.07
319.1331787	0.69
327.4571533	0.07
329.1080933	0.27
333.2637939	0.04
334.1552124	0.05
341.2825317	0.22
342.2752686	0.51
343.5618896	0.04
361.2528687	1.53
370.6179810	0.17
373.2911987	0.14
377.1997681	0.08
382.8395386	0.10
387.6442871	0.03
388.2628784	0.07
391.2472534	0.07
395.3247070	0.12
395.9281006	0.15
405.0886230	0.82
406.2717285	1.29
407.3026123	0.47
408.4843750	0.03
413.3684692	0.03
415.5842285	0.09
417.1979370	0.51
418.9483643	0.06
420.2013550	0.17
430.3989258	0.03
431.2105713	0.13
432.1381836	0.22
433.2714233	0.18
436.3867188	0.07
443.3007812	0.13
446.3638306	0.19
447.2369995	0.14
448.4957886	0.04
449.2523804	0.06
459.3621216	0.46
461.6318359	0.21
462.2922363	0.07
463.3008423	0.14
464.4542236	0.06
473.3528442	0.12
475.3994751	0.06
476.2817993	0.03
477.0820923	0.08
481.2990723	1.64
487.5311890	0.24
488.3623657	0.15
495.1515503	0.07
497.4442749	0.16
503.5287476	0.09
505.1786499	0.22
507.4187622	0.14
509.2803345	0.08
521.4431763	0.49
523.3560181	100.00
524.3130493	0.71
525.1657715	0.54
531.4506226	0.04
533.0795288	0.25
537.2589111	0.52
538.3560181	0.03
540.2199097	0.08
541.2899170	0.09
548.4319458	0.21
549.2119751	0.30
550.3948364	0.36
551.3997192	2.43
552.5515747	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.234
Annotation	Ixerin N
Peak:m/z	Relative Intensity
151.1085510	0.08
160.9834595	0.21
162.2013245	0.07
164.9370728	0.03
166.0005951	0.43
167.1211548	0.22
168.2275085	0.04
170.8896027	0.02
176.0672760	0.23
178.9864502	0.97
180.0789948	0.17
181.1540833	1.93
182.2029114	0.17
191.1163177	0.11
194.0687256	1.30
195.0626526	0.24
205.0167542	0.02
209.0869751	3.64
210.2010040	0.75
230.0784302	0.01
239.1386719	0.02
243.0836792	0.08
256.1604614	0.02
267.2203979	0.01
281.4920044	0.02
291.2720642	0.01
296.5090942	0.03
297.3635559	0.02
300.2836304	0.01
301.2515259	0.03
308.0637207	0.07
312.2073975	1.13
313.3242798	0.13
316.2672729	0.03
325.4656372	0.04
327.2252197	100.00
328.2087402	24.10
331.2857666	0.01
341.2416992	4.65
342.3183594	1.41
361.3010254	0.10
365.3161621	0.12
411.3745117	0.04
417.3035889	0.11
421.2347412	0.03
447.5509644	0.03
452.2827759	0.02
466.0968628	0.02
472.3931274	0.03
477.4953003	0.03
483.7733154	0.03
491.5012207	0.11
492.4495239	0.17
502.0177002	0.05
506.0220337	0.03
507.5057983	0.05
517.8706055	0.02
519.5089722	0.21
522.3566895	0.54
523.3938599	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.1857
Annotation	L-Arginine
Peak:m/z	Relative Intensity
115.8793716	0.04
152.9781189	0.03
153.9339600	0.01
195.0623627	1.23
196.0137634	9.05
213.0543213	100.00
280.9415588	0.03
284.6853943	0.02
285.3329468	0.02
313.2281494	0.02
327.4049683	0.39
368.2227478	0.05
369.3389587	1.08
370.3544922	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1616
Annotation	Isorhamnetin-3-Glucoside-4'-Glucoside
Peak:m/z	Relative Intensity
175.1891785	0.07
189.013092	0.09
190.7606201	0.08
195.1535339	0.06
198.2782288	0.01
199.1096954	0.07
200.1116028	0.11
202.4537048	0.14
203.1130066	0.13
204.0197296	0.08
205.2054749	0.11
209.0658569	0.04
212.230896	0.05
213.1733246	0.03
214.2405396	0.08
215.0410767	0.01
218.8056946	0.12
226.1710205	0.11
227.0406647	0.16
228.0102997	0.15
229.2545013	0.02
235.1903992	0.03
236.9626923	0.02
239.2047119	0.04
241.0563354	0.02
242.2357178	0.05
243.1173248	0.33
244.0995636	0.18
248.779541	0.06
252.7295685	0.04
254.1005554	0.35
255.1671143	3.82
256.3291626	0.06
259.2149353	0.20
267.1914368	0.04
268.3318481	0.03
269.031311	0.28
269.8670959	0.01
271.1708069	6.42
272.1092529	1.41
273.1976624	0.23
282.4938965	0.04
283.1827393	0.27
284.1846924	0.15
285.1835938	0.36
286.0178223	0.08
287.2128296	1.40
289.4258423	0.10
290.2826538	0.11
295.8104248	0.03
297.2720337	0.35
298.6324463	0.19
300.0819092	22.15
300.9077148	0.06
303.2976685	0.02
309.2991638	0.03
311.3977051	0.08
313.1586304	1.44
315.0523682	100.00
315.7739868	0.30
325.472168	0.06
327.2807617	0.05
328.3188477	0.03
329.2462158	0.36
337.2163696	0.09
339.1799927	0.10
342.2089233	0.19
343.2150879	0.05
345.1846313	0.02
351.2694702	0.04
357.2313232	3.04
358.2207642	0.04
359.0956421	0.10
369.2116089	0.14
372.2202759	0.06
373.6364746	0.02
381.2352295	0.02
387.168335	0.31
399.4483032	0.05
408.4295654	0.04
409.4324341	0.03
414.4081421	0.04
417.3834229	0.09
418.3635254	0.21
419.6969604	0.04
422.1933594	0.13
423.3010254	0.03
424.531189	0.02
431.1820679	0.05
441.3495483	0.15
447.5809326	0.03
451.9732666	0.03
453.4049683	0.08
455.2025146	0.02
459.258728	0.09
460.3720093	0.05
461.6106567	0.07
463.2832642	0.11
465.3972778	0.08
470.5651245	0.03
471.3874512	0.04
473.7805786	0.04
477.3121948	0.32
488.3084106	0.14
490.1815186	0.05
491.354248	0.05
493.1202393	0.05
496.265564	0.05
501.1732788	0.19
526.5137329	0.10
527.4055176	0.09
529.3143921	0.03
533.1790161	0.12
536.1791382	0.42
537.1277466	0.22
541.7789917	0.14
562.3733521	0.32
563.1914673	0.14
573.3284912	0.04
575.1454468	0.05
576.3673706	0.52
577.3560181	1.07
579.3656006	0.23
580.4642334	0.22
587.1724243	0.02
591.3717041	0.73
592.3800049	0.32
593.6359863	0.09
595.347229	1.14
602.5320435	0.02
603.4140625	0.23
604.241394	0.11
605.3389282	0.41
607.7776489	0.11
608.5322876	0.15
614.9625854	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.056
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.9927521	3.14
70.9667816	9.25
75.0193481	1.64
82.8082886	0.19
84.6752167	0.88
86.9983368	14.22
88.9948578	87.84
96.9996033	1.56
98.9598541	0.21
101.0031281	7.00
105.1253052	0.61
106.3784790	3.07
107.0240631	5.22
113.0141449	21.88
114.9748383	0.61
116.9673920	0.67
118.9780731	43.26
125.0341492	4.36
130.9223785	24.77
132.8743744	0.49
135.0083466	0.80
135.9585114	0.12
137.0203705	0.48
141.0420074	0.09
143.0093689	83.19
148.9786835	13.24
159.1322632	0.26
161.0365753	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1143
Annotation	Castamollissin
Peak:m/z	Relative Intensity
147.9560089	0.04
149.0358582	0.06
151.0787354	1.31
152.0958252	0.05
153.0729980	0.27
156.9860229	0.05
159.9251709	0.03
160.9492493	0.05
162.0427399	0.07
163.1251068	0.11
164.2100983	0.05
165.0381470	0.17
167.2275696	0.04
169.0470123	0.10
172.9131927	0.06
173.9104919	0.03
176.0522766	0.11
177.0690308	0.11
179.1327515	0.61
181.1460419	0.10
184.0859833	0.05
185.1764984	0.03
189.0823975	0.34
189.8605957	0.07
190.9065399	0.10
192.0102234	0.19
193.2075500	0.15
198.8961487	0.09
200.1759949	0.25
201.0933990	0.08
202.6855469	0.10
204.0643616	0.99
205.1098480	0.94
206.3945923	0.22
207.1708679	0.09
209.0736847	0.06
210.2012329	0.02
211.2483826	0.02
214.5285492	0.14
215.2785339	0.15
217.0660858	0.24
218.3925171	0.06
219.0024414	0.09
219.8728943	0.07
221.0691681	0.05
225.2503357	0.16
226.1492004	0.04
227.1493225	0.15
228.2179565	0.23
229.2029724	0.07
231.2289124	0.04
232.3288879	0.07
233.0326843	0.11
235.0608063	0.05
241.2751312	0.32
242.2515564	0.44
243.1316376	3.85
244.1766510	0.06
245.1754761	0.43
247.1419983	0.17
254.1659393	0.27
255.1422119	0.08
257.0275879	1.55
258.2266541	0.04
259.2344971	0.11
260.1029663	0.03
261.0494385	0.07
262.0173645	0.04
264.1243286	0.08
267.0857239	0.12
268.1059570	0.24
269.5191650	0.41
270.1821289	0.98
271.1130981	8.40
272.3495178	0.80
273.1315002	1.41
275.1489258	0.05
277.4007568	0.04
279.2554932	0.12
280.0645142	0.11
281.4934082	0.03
283.2175903	0.32
284.1359558	0.58
285.1319580	11.49
286.1113892	4.27
287.1540527	0.89
288.1914062	0.22
289.1871643	0.36
291.2475586	0.09
293.0854492	0.03
294.2416382	0.02
295.0873413	0.22
296.2066040	0.06
297.8433228	0.94
299.0936584	5.82
300.1309204	4.36
301.1645508	0.37
302.3359985	0.03
308.7935791	0.16
311.2973022	0.36
314.1166382	100.00
315.1298828	30.65
316.0954590	0.29
317.4856567	0.03
319.5652466	0.15
323.1315308	0.13
324.2581787	0.06
325.4051514	0.21
327.2249146	0.37
328.2634277	0.29
329.2941284	3.03
330.6857910	0.06
337.2583008	0.20
338.1548462	0.14
339.3103638	0.40
341.5405884	0.20
342.2003784	1.16
343.2128906	0.14
344.1455688	0.14
347.3300781	0.12
348.3897095	0.18
351.2289429	0.15
354.2567139	0.11
355.1714478	0.07
355.9436035	0.03
357.1857300	22.42
358.3296509	0.26
359.2905273	0.14
361.5535889	0.03
363.0478516	0.04
365.1976318	0.08
367.0040283	0.09
367.8580933	0.03
369.2227173	0.67
370.1931152	0.02
371.3637695	0.18
372.4028320	0.10
373.2255249	0.02
374.5263672	0.08
375.1853027	0.06
377.5719604	0.09
378.7879639	0.09
381.2852173	0.17
382.4027100	0.03
385.3896484	0.08
387.2413330	4.64
388.2314453	0.16
389.3837280	0.10
391.0316162	0.05
393.3694458	0.19
395.2573853	0.06
399.3504639	0.14
414.9442749	0.08
417.5460205	0.02
421.0454712	0.08
423.2876587	0.36
429.3578491	0.02
431.2523804	0.33
435.6458130	0.02
440.2534180	0.06
443.2818604	0.20
444.5441284	0.10
445.3598022	0.09
446.1417236	0.12
447.3209229	0.09
449.3593750	0.35
451.4806519	0.16
457.6268921	0.04
459.2871094	5.40
460.5745850	0.03
472.3192749	0.19
473.3857422	0.30
475.7068481	0.24
477.1668091	1.13
482.6093750	0.14
487.3162231	0.08
488.7382812	0.03
489.7020874	0.06
491.2241821	6.06
492.3555298	0.14
498.3377075	0.09
499.3493652	0.14
500.5111084	0.20
501.4244995	0.71
504.2532349	1.30
519.0419312	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.1
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
169.2197571	0.39
195.2245483	0.13
255.4138794	0.50
272.5771179	0.31
283.3353271	0.68
292.3026123	0.55
293.4668274	0.21
298.0329590	0.69
300.8489075	0.70
303.2239990	7.47
304.0475464	0.16
305.1301270	0.63
309.2804871	1.11
310.1722412	0.54
317.0973511	6.32
318.3287354	13.37
319.1574402	100.00
319.7793579	1.13
329.4046631	0.49
331.8961487	0.51
348.2791748	1.79
360.2559204	0.26
363.1369629	0.52
369.2912598	0.24
378.2157288	0.42
385.4585571	0.26
387.2887573	0.57
397.3634949	0.54
400.1087952	1.24
404.1935730	0.29
415.3472900	0.31
422.9905701	0.23
435.3902283	0.77
437.3055725	0.36
438.4721069	0.33
453.3838806	0.20
462.2333374	0.51
463.1516418	6.66
464.3288269	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.01
Annotation	Unknow
Peak:m/z	Relative Intensity
133.9586182	0.04
174.9845581	0.09
188.9731750	0.06
191.3605652	0.04
192.9509277	0.07
199.9825287	0.43
209.9861145	0.06
218.0875702	0.66
229.1213074	0.15
230.0422821	0.89
232.7931824	0.05
242.0497131	0.08
245.2833862	0.05
246.1661682	0.05
249.1924133	0.05
253.8386230	0.07
256.0674744	0.12
257.9969788	0.48
266.1594849	0.12
273.9043884	0.07
275.7685547	0.12
281.8326416	0.06
293.5068970	0.12
301.4167175	0.21
302.1446533	0.05
304.1593018	0.43
305.1432495	0.66
305.9985962	1.82
317.1696167	0.37
318.1773682	0.29
319.8782959	0.40
321.8760986	0.27
324.2183838	0.07
327.9655151	0.10
329.0266113	0.17
330.2029724	0.05
335.0671692	1.79
336.1067505	11.94
338.5099487	0.08
346.0122681	0.13
350.1654663	0.22
351.4541931	0.10
360.1602173	0.09
363.2071838	0.15
364.2799988	0.46
365.1944275	0.63
366.1799622	0.66
367.1275024	0.14
377.0559387	0.21
377.8795776	0.29
382.1707764	100.00
383.3077698	0.17
384.1265869	0.19
388.8403015	0.29
407.0132141	1.30
408.1856079	1.42
408.9923401	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.22
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0519562	1.23
153.0282288	0.23
162.9385071	0.03
164.6373444	0.57
165.2588196	0.18
165.9514313	0.05
167.1129913	0.19
168.9492950	0.02
175.2581024	0.03
177.0437317	0.02
177.9032288	0.02
179.4532166	0.04
181.1445312	0.05
185.1598206	0.01
189.1174316	0.10
191.1546326	0.21
191.9681091	0.46
193.0763855	2.69
197.2535706	0.31
204.1201324	0.03
206.2214355	0.05
207.1156311	0.40
209.1993866	0.05
210.9199677	0.01
217.4324951	0.05
219.1696014	0.04
219.9876251	0.14
221.1809540	0.07
222.9253693	0.02
230.0833588	0.06
232.9349365	0.23
234.9538269	0.19
237.3055420	0.05
239.1383057	0.16
243.9147644	0.01
246.9014282	0.04
251.3010712	0.02
255.2063751	0.06
256.2749329	0.03
257.1230469	0.02
258.1146545	0.10
259.2498169	0.27
260.6298218	0.37
261.2966919	0.73
265.0638428	0.07
269.1796875	0.04
273.2640381	0.12
275.3449097	0.08
279.1632080	0.04
283.1064453	0.03
285.0065308	0.25
286.3062134	0.10
287.3317871	0.21
288.4148560	0.08
289.1981201	0.02
291.2352905	0.04
293.2097168	0.22
297.0149536	0.06
300.3732605	0.09
301.2361450	0.14
302.2557983	0.19
303.2421875	2.85
305.1072998	0.14
309.4272461	0.02
311.2922974	0.27
313.2983398	0.12
314.2738037	1.21
315.2116089	0.28
317.1773682	0.05
319.2847900	0.67
326.6848755	0.13
327.4355469	0.25
329.1803589	100.00
330.3279419	0.08
331.1951904	0.26
333.3984985	0.07
337.3060303	0.01
341.3211060	0.29
343.4433594	0.05
345.2034302	0.50
346.1948242	2.87
347.1708984	31.97
355.2562866	29.95
357.1867065	0.13
359.2291260	0.76
369.1532593	0.10
370.9603271	0.20
371.6234131	0.17
373.2892456	0.12
375.4055786	0.10
381.4374390	0.05
383.3261108	0.14
389.2785034	1.03
399.3693237	0.13
401.4835205	0.10
417.2962646	0.01
419.3593750	0.19
422.3979492	0.25
423.3157349	0.18
425.5205078	0.03
428.4399414	0.04
431.3312988	0.01
453.4746704	0.06
461.3664551	0.03
463.2938843	9.65
465.1796265	1.79
473.3101807	0.11
477.4362183	0.05
482.3174438	0.02
491.2858276	3.10
494.1889648	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.9926
Annotation	Unknow
Peak:m/z	Relative Intensity
82.8410187	0.19
96.5050201	0.63
108.0025940	0.33
109.0715179	0.35
121.0074692	0.46
123.7569885	0.92
148.9992371	0.25
180.2907715	1.55
191.2285461	0.94
213.9275513	0.62
229.3468018	0.99
239.0366516	0.39
241.8236389	100.00
247.1213989	2.12
252.9382935	0.44
259.4202271	11.15
260.2686157	0.12
264.9273682	2.54
265.5935059	1.03
271.2248230	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.104
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0445862	0.20
161.2995605	0.07
165.0197144	0.04
191.0657501	0.11
193.0561829	0.13
199.1487732	0.04
214.0711975	0.03
219.2936401	0.04
223.2425232	0.03
229.1501770	0.08
241.2005310	0.73
243.1097717	0.05
247.2174683	0.27
255.2424927	0.03
256.2378540	0.29
258.0097656	0.06
265.2409363	0.04
271.1499634	4.61
272.9659424	0.10
282.2378235	0.04
283.1534424	0.31
285.1144714	4.24
287.1489868	0.13
297.1263428	0.14
299.1759338	0.85
300.1398926	1.73
301.2222900	0.13
303.1777039	2.52
303.8133545	0.03
305.3352051	0.03
307.1408691	0.05
315.1475220	100.00
324.1267395	0.05
325.2056580	0.40
327.3067627	0.08
329.3382568	0.16
333.2135620	0.28
339.1837769	9.03
345.3012085	0.02
355.4306946	0.34
381.3544006	0.03
397.0928040	0.15
406.6911621	0.03
418.2117920	0.19
419.5687866	0.02
420.1976013	0.13
421.2406616	0.38
433.4345398	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.3436
Annotation	Unknow
Peak:m/z	Relative Intensity
241.0844727	0.54
242.0424805	0.03
255.3800659	1.59
256.3787231	0.22
264.5864258	0.17
275.3396912	0.07
277.2955322	0.88
278.4234619	0.14
293.4067993	0.09
297.1484985	0.82
298.0427551	0.11
315.1760254	0.05
329.4948120	0.16
346.0537109	0.04
357.5664673	0.04
389.5689697	0.04
391.3499146	1.69
392.4741211	0.42
409.2053833	0.07
411.3201904	0.05
413.2360840	0.23
429.3374023	1.71
430.4645386	0.15
431.4423828	0.03
441.2644653	0.77
442.6025391	0.05
443.2971191	0.07
445.2792358	0.11
454.2524414	0.08
455.4096069	0.32
459.3382568	0.50
460.5088501	0.06
461.3488770	0.04
477.1905518	0.06
483.3495483	0.29
484.4363403	0.03
497.3444824	0.12
504.3671875	0.09
552.8739014	0.19
553.5261841	3.80
554.3768921	1.06
560.5303955	0.06
565.4113159	0.06
566.6785889	0.06
571.4987183	1.36
572.5574341	0.15
575.3558350	0.86
585.2946167	0.38
592.4896851	0.03
593.6470337	0.05
594.3616333	0.05
596.7790527	0.10
603.4697266	0.30
604.2897339	0.15
619.4497681	0.05
621.3986206	0.46
625.3671875	0.09
626.5994263	0.12
627.4376221	0.09
640.4187622	0.05
651.3073120	0.61
652.3132935	0.30
664.4157104	0.15
669.2949829	100.00
670.3599243	8.27
671.2274170	0.07
681.5392456	0.03
711.2880249	0.90
712.4356079	0.69
729.5486450	0.13
735.5379639	0.03
753.5391235	0.09
770.7214966	0.10
785.7441406	0.04
795.0847168	0.03
797.4949341	0.03
801.4191284	0.51
802.5053101	0.27
803.6183472	0.07
813.6193848	0.21
814.5612183	0.24
816.9351196	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1564
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
161.0039673	0.03
177.1448212	0.02
191.1345825	0.02
207.1632996	1.06
311.1671753	0.12
339.5515137	0.12
341.4155884	0.04
382.3588867	0.03
394.3138428	0.05
443.0599365	0.04
473.2428589	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1614
Annotation	b-D-Xylopyranosyl-(1->4)-a-L-rhamnopyranosyl-(1->2)-D-fucose
Peak:m/z	Relative Intensity
125.0980225	0.14
131.0109863	0.35
139.1977081	0.02
149.0960693	1.04
153.0892487	0.02
161.0329895	0.02
167.0747681	0.01
172.3664551	0.02
191.0754395	0.13
192.3050232	0.04
194.6100159	0.06
204.9592896	0.04
215.3087463	0.04
218.8307343	0.05
220.7854614	0.16
227.3388062	0.02
233.0400848	0.05
235.3273621	0.02
247.2215271	0.03
249.0487061	0.01
250.4150696	0.02
258.9746399	0.03
275.3830566	0.16
293.1502991	21.30
293.8521729	0.03
297.4813232	0.06
301.3611755	0.06
306.2958069	0.02
315.1543274	0.03
323.3031921	0.12
339.2366943	1.66
347.2134705	0.03
351.3086243	0.03
353.4703674	0.04
360.0619812	0.08
370.2018127	0.03
375.4525452	0.10
376.9612122	0.04
377.7858276	0.05
383.2246399	0.03
395.1119995	100.00
395.7667542	0.35
397.3995056	0.03
409.2622070	0.02
413.1579590	0.02
423.1102905	0.18
426.2211609	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	336.95
Annotation	Unknow
Peak:m/z	Relative Intensity
99.0222321	0.03
109.1709747	0.04
122.8847046	0.28
133.0488586	0.05
150.1062927	0.09
156.7878113	8.83
168.7969208	0.03
173.1674194	0.15
174.9303589	55.37
196.0001221	0.10
198.3350067	0.04
203.9847107	0.24
206.9284668	0.07
213.1301575	0.07
216.8859253	2.51
226.9972229	0.12
229.0690002	0.52
230.8441772	0.18
241.0178528	0.16
246.9897156	1.82
249.0768127	0.52
251.1054077	2.04
252.0847168	0.75
252.9884644	4.30
259.0106201	0.83
261.1213074	0.08
262.3356628	0.06
263.0021057	0.10
265.6529541	0.05
276.9671936	7.05
278.1941528	0.04
283.2527161	0.19
289.2184448	0.03
294.1832886	0.04
300.0863953	0.06
300.9999084	0.99
306.1049500	0.08
318.9672852	100.00
319.6035767	0.22
326.8948364	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.2234
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
124.9038010	0.08
128.9934540	0.10
130.9312744	3.98
133.2055511	0.17
137.1236725	0.30
143.0075378	0.31
148.9908142	5.21
154.8953094	0.38
158.9088745	0.51
161.0078888	14.43
162.0789337	0.18
167.0061951	0.51
173.0518951	0.13
179.0370636	0.41
181.3082581	0.28
185.0724182	0.10
187.0871277	0.35
191.0071411	3.88
205.2908020	0.42
209.0444946	0.09
210.8250427	0.17
215.1150970	1.48
219.1300049	0.33
224.9951172	0.21
233.1312561	3.18
237.3164062	0.31
267.3475342	0.16
273.0193481	0.27
279.3900146	0.39
284.1246948	1.04
285.0781860	0.43
290.7060852	0.21
293.1600342	3.54
297.3320007	1.51
300.0677795	0.08
300.9587402	0.35
305.2433167	0.22
310.3382263	0.14
314.1629639	2.13
315.2924194	100.00
318.3564453	0.17
321.5541992	0.14
339.2798767	0.50
347.5837708	0.17
357.4247437	0.31
361.4249878	0.11
385.4429016	0.24
401.3369751	0.20
429.3483582	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	397.0546
Annotation	Unknow
Peak:m/z	Relative Intensity
129.5447693	0.13
132.0185852	0.18
133.1338654	0.06
146.2022552	0.08
157.2553101	0.16
160.9064941	0.25
163.2346497	0.11
170.1589966	0.07
174.5860901	0.09
195.0780640	0.25
198.9721985	0.18
199.9201660	0.14
204.0228424	0.17
205.1910400	0.11
213.0175781	0.10
223.2114563	0.13
226.9208374	0.07
233.1794128	0.08
234.2096558	0.08
235.1325684	0.33
239.1667480	0.28
245.0337830	0.20
246.0970764	0.14
263.2208862	0.12
269.3872070	0.34
270.9610901	0.37
275.4982605	0.48
276.9954834	3.63
279.1291809	0.41
282.9843140	0.16
288.9737244	11.19
305.0097351	0.93
306.4990234	10.53
307.1151123	48.92
309.4672852	0.08
313.2076111	0.50
318.9775085	3.29
323.4313660	0.09
331.0723877	2.52
334.9589233	0.24
336.9038696	24.24
337.6119080	0.27
338.4264832	0.12
343.0550537	0.55
348.2719116	0.43
349.1263733	1.12
360.2809448	1.47
361.1102905	3.77
367.0308838	0.49
368.5838318	0.06
379.0806885	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
156.0701294	0.11
159.0193939	3.90
159.8403015	0.32
199.0461426	0.06
200.1111755	0.21
217.2166748	0.13
217.8400879	0.12
228.9236450	0.32
229.8325195	0.20
238.0830994	0.27
257.2374878	0.11
272.9946899	59.03
274.0246887	23.81
275.1291809	0.10
371.2584839	0.67
384.8251038	0.27
387.0016785	100.00
388.0625916	60.71
414.2765198	0.08
427.0408630	0.34
428.1612244	0.30
455.1818237	0.39
456.8553772	0.27
458.0496521	0.59
459.9635925	0.08
471.1264343	0.17
474.1832886	0.29
475.0115051	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.26
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9493256	0.16
161.0496216	0.89
161.9731750	0.42
163.2798004	0.10
179.1079712	0.70
191.0822296	1.39
192.0750122	0.41
193.1543579	0.30
207.1243896	0.08
219.0676575	0.08
220.8565674	2.39
221.7639160	0.22
223.1107178	0.27
223.8345184	0.05
225.0027008	0.04
239.0206146	0.06
247.1398773	0.14
249.2283936	0.19
250.7164612	0.75
251.4152222	0.89
252.2276917	0.09
253.2777863	0.05
257.3043518	0.09
263.0219727	0.21
271.2854614	0.04
276.1036377	0.22
281.0812378	0.28
281.9923096	0.07
283.2374268	0.27
288.7919922	0.15
292.2107544	0.05
293.1667175	1.98
294.1041870	0.34
299.2684326	0.05
311.0577393	10.82
312.0521851	8.80
313.1882324	0.91
315.1090698	0.20
326.7631226	0.15
342.2474365	0.09
343.3063354	0.18
345.3297119	0.11
358.4512329	0.16
369.3659668	0.52
370.2037354	0.16
371.1853027	0.47
373.0689697	0.11
379.3161011	0.08
381.4153442	0.03
385.1649780	1.23
386.2222900	0.56
387.1351929	0.90
396.9489746	0.05
416.3005981	0.28
417.5715332	0.12
427.4491577	0.32
428.6820068	0.16
440.4487915	0.07
445.3867798	0.03
447.1733398	0.04
453.3596802	0.14
456.6701660	0.25
459.6012573	0.11
461.0457764	0.14
463.0746460	0.33
464.2554932	0.43
465.4578247	0.34
470.5177002	0.04
471.3150635	0.17
485.1955566	0.32
489.3619385	0.36
491.3738403	0.47
500.1741333	0.11
501.8007812	1.60
503.3115845	100.00
505.0925903	0.82
506.6904907	0.19
522.1613770	0.16
526.3223267	0.41
529.9251099	0.16
530.8408203	1.03
531.7103271	0.56
532.3549194	0.14
534.3075562	0.09
555.2750854	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.2173
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0535736	0.14
180.9062195	1.82
199.0818787	0.23
203.9782715	0.20
207.2001648	0.10
211.1130676	0.45
212.2559967	0.26
222.8515015	0.17
229.0072632	0.31
231.9031830	0.22
235.1801758	0.25
240.9278870	1.14
246.4171753	0.37
247.1675568	0.41
248.8655701	0.29
250.1363373	0.28
252.0207977	0.51
253.1151581	3.00
255.2253723	0.14
257.8754883	0.13
258.8404846	2.52
262.3620605	0.12
265.2026367	0.33
268.0725098	0.89
269.3010864	0.31
271.1517944	2.07
272.8715210	0.20
276.9835205	0.52
281.4116211	0.46
285.3804016	0.13
286.2810059	0.44
288.0296631	2.50
288.8946533	28.86
292.0192261	0.13
296.0249023	0.10
302.1129150	0.14
303.1369324	0.17
305.1547546	0.14
306.4020996	1.02
307.0953979	4.78
309.3208008	0.22
310.4279480	0.95
315.1868286	0.45
320.2794189	0.51
324.9571533	100.00
325.8151245	0.93
329.0495605	0.10
333.4881592	0.12
341.3648071	0.60
342.7060547	7.19
343.4295654	0.08
346.2928467	0.21
358.9780884	0.31
365.3378906	0.08
393.8082275	0.30
397.2116699	0.19
402.9227905	0.52
412.2541504	0.25
415.0866699	1.43
420.4430542	0.54
429.6229858	1.36
430.3085327	10.38
433.3680420	0.52
445.3785400	0.44
446.5075073	0.10
447.5099487	0.92
448.2441406	3.04
449.8332520	0.18
451.0075684	2.87
451.6453857	0.17
457.8625488	0.15
459.9479980	0.24
462.9017334	0.48
464.0978394	0.38
467.1682739	0.18
468.0264282	0.46
468.6680298	0.78
477.1015625	0.55
479.0462646	1.02
486.2579346	6.42
486.9055176	29.33
487.5968018	0.22
490.1151123	0.19
491.1998291	0.22
498.5650635	0.08
502.2987671	0.25
504.7520142	7.89
505.3560181	0.60
512.3079224	0.77
520.0875244	0.25
529.1094360	0.31
536.9934082	0.35
549.4937134	0.29
550.0988159	0.40
563.9561768	0.35
573.4909058	0.22
574.4827271	0.22
590.0089722	0.14
592.0316772	3.45
617.8329468	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.2914
Annotation	Unknow
Peak:m/z	Relative Intensity
207.2661743	0.05
209.0143890	0.05
223.1830750	0.02
236.9796143	0.04
292.2699890	0.02
299.0288086	0.03
301.2465515	0.02
307.3423462	0.08
313.3707886	0.04
325.5174561	0.05
326.2860107	0.16
327.4276733	0.09
328.3247070	0.03
333.3375244	0.06
337.3681030	0.05
338.3445435	0.02
339.2501221	0.01
341.2559509	0.33
342.3679199	0.10
342.9719238	0.02
351.1622925	0.03
352.2528076	0.02
353.3064270	0.15
354.3511963	0.88
355.3640137	1.32
356.4064026	0.29
357.4255371	0.29
359.3548889	0.02
369.3599854	4.99
370.3402710	0.75
371.4343872	0.07
372.4707031	0.02
373.2567139	0.01
375.4261475	0.08
377.3054810	0.14
382.2939453	0.09
383.3629150	0.02
386.8236694	0.01
401.3562012	0.01
403.3544922	0.05
405.2627563	0.01
412.0529785	0.02
419.4968872	0.02
435.3145142	0.04
445.2768555	0.06
456.3551025	0.03
460.5742188	0.12
461.5327148	0.03
462.6084595	0.01
471.4675903	0.43
472.4149170	0.11
473.2544556	0.05
475.4456177	0.07
476.6555176	0.02
477.3168335	0.02
483.7627563	0.02
485.5269165	0.06
486.4007568	0.05
487.3571777	0.02
488.3740845	0.70
489.3422852	0.30
491.3576660	32.87
492.4268188	8.13
493.5463867	0.80
494.5537109	0.13
503.3524170	100.00
504.3850098	26.58
505.3495483	9.86
506.3972778	2.46
507.4461060	0.87
508.4473877	0.16
514.4557495	0.04
517.3911133	17.21
518.3490601	3.86
519.4113770	0.10
521.2847900	1.03
522.3389282	0.16
523.5596313	0.08
535.4835205	0.57
536.4672852	0.05
539.5039673	0.09
549.4833374	0.02
551.3074951	0.04
557.3969727	0.10
558.3196411	0.03
563.6167603	0.01
567.4166870	0.12
568.1970825	0.01
569.3998413	0.03
570.1477661	0.09
581.4257812	0.06
598.3295898	0.01
601.3610229	0.03
606.7452393	0.06
609.4336548	0.04
622.4899292	0.05
623.3919067	0.01
626.2291870	0.03
641.3688354	0.09
659.6173706	0.05
665.4035034	0.41
666.6475220	0.22
669.5488281	0.08
671.5301514	0.11
672.3650513	0.01
673.8137817	0.09
682.7537231	0.16
683.4911499	0.35
684.4703369	0.08
686.2001343	0.02
686.9684448	0.02
695.5725098	0.02
698.6830444	0.05
699.6959839	0.12
701.3742065	2.40
702.4970093	0.98
703.5855103	0.81
704.6040649	0.22
713.3806152	45.17
714.3338623	16.23
714.9343872	0.16
716.4078979	0.27
717.4756470	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0988
Annotation	Unknow
Peak:m/z	Relative Intensity
150.9641724	0.52
151.9501801	0.07
163.0026245	0.05
165.0873108	0.04
168.8849335	0.07
179.0504150	1.06
180.0971680	0.09
180.9718933	0.03
188.8120880	0.06
192.0948181	0.02
193.1966553	0.04
197.3696289	0.03
202.9799805	0.06
208.1597290	0.05
215.3713684	0.04
216.2543030	0.08
219.8718567	0.15
220.9403229	0.04
231.1819611	0.07
232.0223999	0.04
233.0114594	0.14
242.0819092	0.10
243.1285706	0.20
246.1167755	0.02
247.1873627	0.08
255.2146912	0.04
257.2544556	0.05
259.0131531	0.02
261.1384888	0.06
263.1400757	0.17
271.2437134	0.17
274.1832581	0.05
275.0949707	0.05
277.0912781	0.11
279.0237732	0.06
281.3300171	0.03
283.0953369	0.09
284.2882690	0.11
285.1888733	0.18
286.2452698	0.10
287.2096252	0.15
287.9803772	0.12
289.1146851	0.09
296.2873230	0.08
298.0665283	0.05
299.3149414	0.06
301.0914001	0.42
302.3754272	0.06
303.1530762	0.66
304.1706543	0.23
305.3925476	0.03
306.3690796	0.11
311.3095093	0.07
311.9804382	0.07
313.8201294	0.16
315.0421143	1.13
316.1097107	2.46
317.1213379	0.48
319.1137085	0.03
324.3763123	0.03
325.3579712	0.06
325.9689941	0.05
327.3149109	0.13
328.1489868	0.06
330.1540527	55.35
331.1448669	100.00
332.1614380	20.94
340.0036621	0.04
341.0947266	0.56
342.1492004	0.26
343.0562744	0.37
344.2384033	0.08
345.1545410	0.05
346.3945923	0.06
353.3867798	0.04
355.2737122	0.18
358.1481323	0.02
359.3140869	0.13
360.3487244	0.05
367.1252441	0.21
371.3039551	0.07
373.1856689	1.73
374.1399231	0.61
383.2609558	0.02
387.3171387	0.16
397.2221375	0.07
401.1483459	0.02
403.1257935	0.32
404.3665161	0.26
415.4709778	0.02
432.4965515	0.04
448.9605408	0.06
461.1447449	1.75
462.0507202	0.35
465.4403381	0.06
475.2650757	0.59
476.2402649	0.32
478.2713318	0.66
479.3221130	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1031
Annotation	Cinchonain Ic
Peak:m/z	Relative Intensity
136.8261261	0.01
153.2514343	0.03
160.7360535	0.02
163.1492157	0.09
167.0684204	0.12
175.1751404	0.02
177.0912781	2.15
185.2546997	0.01
189.0932465	3.06
216.9950867	0.54
219.0714874	0.26
225.9845581	0.01
229.1901855	0.06
231.2091522	0.20
232.1171265	0.02
237.2752991	0.10
245.4333801	0.10
255.2591858	0.09
255.9966736	0.03
270.0933228	0.01
271.0564575	0.27
275.1989136	0.04
279.2606812	0.28
282.3573303	0.07
283.2920532	0.02
284.9537964	0.01
287.2331543	2.29
288.1890869	0.29
289.2338867	1.53
297.1876831	0.28
299.1750488	16.53
301.1367493	0.44
303.3446960	0.02
311.2145996	0.04
313.0560913	0.02
314.2896118	0.09
315.0684204	0.17
317.5223083	0.05
323.1396484	0.22
325.3945923	0.11
327.1060181	0.11
329.2764893	0.03
338.9825134	0.03
341.1651917	100.00
342.0151062	0.01
345.0446777	0.01
357.2122498	0.05
365.2127686	0.08
389.4217529	0.02
392.3151855	0.02
403.2989197	0.02
405.2978821	0.17
406.3570862	0.11
407.2607117	0.16
415.3616638	0.05
433.2261047	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	943.2104
Annotation	Unknow
Peak:m/z	Relative Intensity
317.3306580	0.07
331.2674561	0.38
338.4382935	0.31
360.1493835	0.11
370.8894653	0.41
390.5131836	0.10
423.3126831	0.15
439.1550293	0.06
465.2260132	0.20
467.0864868	0.23
475.7773438	0.23
493.3875732	0.61
494.5628662	0.15
523.1764526	0.47
601.2250366	1.63
607.4203491	0.22
613.2152100	0.05
616.6022949	0.08
617.2184448	0.11
618.6211548	1.02
619.2224731	4.25
619.8424072	0.04
625.3088989	0.06
631.3842773	3.83
635.1603394	0.11
649.2621460	18.84
655.3067627	0.20
674.6086426	0.09
679.2156982	0.22
685.1975098	0.31
699.2497559	0.23
724.3482056	0.10
727.2943726	0.23
738.4100952	0.05
739.3481445	0.19
745.2754517	0.21
749.1200562	0.27
759.8176270	0.30
762.2846069	0.31
763.1881714	1.97
775.5375977	0.10
777.9349365	0.32
779.6988525	1.94
781.2354736	100.00
781.9556885	0.70
788.2728882	0.28
793.3125610	1.49
795.7666016	0.19
797.7959595	0.08
809.2419434	0.20
811.2661743	44.07
898.7067871	0.19
907.1004028	0.16
915.3960571	0.27
925.3208008	0.75
943.5895996	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	703.296
Annotation	Unknow
Peak:m/z	Relative Intensity
210.4047394	0.03
243.1770172	0.01
251.3374329	0.05
282.3407593	0.02
292.4216309	0.02
295.3050232	0.05
311.4624634	0.02
313.2118530	100.00
314.2411499	11.08
315.2255249	0.08
327.2937012	0.29
328.3452759	0.06
333.6933594	0.02
343.1743469	0.96
343.7827454	0.03
344.4865723	0.03
346.1732788	0.02
362.2160034	0.03
367.5556641	0.03
371.5911255	0.01
374.8991699	0.06
377.2036743	0.04
417.3737183	0.03
447.5050659	0.06
456.3103638	0.03
465.4851685	0.03
478.5699463	0.03
479.3424683	0.10
483.3241577	0.02
485.2297363	0.02
493.1411133	0.02
498.3568115	0.10
499.1060791	0.02
503.8142700	0.08
504.6239014	0.02
505.5825806	0.02
508.5274658	0.03
511.5393677	0.06
519.3995972	0.07
523.3016968	0.43
524.5043945	0.04
525.2169189	0.02
531.2667236	0.07
534.4177246	0.05
537.4216309	0.12
538.2980347	0.09
553.3739624	0.03
560.6405640	0.02
571.5618286	0.02
579.4434204	0.10
582.4039917	0.03
592.7912598	0.19
607.3372192	0.01
613.4121094	0.14
622.9263306	0.04
624.6257935	0.16
627.2847290	0.04
639.5614624	0.06
641.8308716	0.02
643.6884155	0.02
644.5778198	0.02
653.6669312	0.02
657.3227539	0.13
660.0219727	0.06
665.4671631	0.06
667.3916626	0.09
670.5667114	0.02
671.3474731	0.05
674.1487427	0.03
674.7841187	0.07
675.7069702	0.11
685.6394653	0.33
686.6691284	0.07
690.2476196	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.1667
Annotation	Kandelin A-1
Peak:m/z	Relative Intensity
205.0212860	0.13
215.1650391	0.18
217.1965790	0.10
220.2164917	0.04
227.0749817	0.13
229.2194214	0.25
230.3498535	0.23
231.0144348	0.04
233.4095154	0.09
241.2817078	0.12
241.9369812	0.07
243.3684998	0.08
245.1354065	1.82
246.2966003	0.07
247.1500549	0.37
249.2112885	0.05
250.1253052	0.08
255.1279449	0.27
257.4071045	0.20
267.2899780	0.10
271.4149780	0.21
279.9028625	0.13
285.0740356	0.17
286.3858948	0.14
287.2990417	1.63
289.2382507	20.12
293.3076782	0.11
297.3559570	0.27
299.1807251	1.36
301.3752441	0.23
303.3179016	0.21
310.2034302	0.07
311.2112427	0.06
317.2522278	0.33
321.1411743	1.86
323.5055542	0.08
325.2882996	0.63
326.2246704	0.12
329.3788452	0.07
331.2129211	0.13
333.0711060	0.10
335.2462769	0.22
337.2337646	0.66
339.1322632	24.99
341.2823792	0.34
343.5089111	0.14
344.3533325	0.05
345.3453064	0.12
346.5731812	0.18
352.1833496	0.05
353.3544006	0.12
355.3089600	0.20
365.2747803	0.07
379.1714478	0.26
381.2504272	0.97
383.2658691	0.09
389.2163086	0.08
390.4218140	0.20
391.2808228	0.23
393.2128906	0.30
395.1494141	0.06
399.4027100	0.04
401.4466553	0.17
406.5828247	0.33
407.3566895	5.18
409.2860718	2.18
410.2820435	0.21
411.4047852	0.24
412.2695312	0.07
415.4014893	0.25
417.1963501	6.43
421.3705444	0.11
423.3746948	0.15
425.2400513	0.09
431.3007202	1.09
433.3780518	1.44
435.1649170	40.14
445.2678223	0.61
447.1983643	0.45
449.3051147	25.20
451.2135620	27.78
451.9385376	0.24
459.3791504	3.70
461.9811401	0.05
463.3267212	0.27
467.1954956	0.33
468.0944824	0.13
470.2974243	0.07
473.1179810	0.74
475.2996826	0.14
477.2344360	6.84
485.4888916	0.09
489.3109131	1.34
491.2573242	2.03
493.3760376	0.25
499.2520752	0.07
501.2763062	0.23
505.1898193	0.21
507.7877808	0.47
509.4708862	0.12
515.4850464	0.20
517.2058716	0.07
519.3311768	0.20
522.8383789	0.12
523.6582642	0.11
525.6485596	0.26
527.2378540	0.62
529.3937378	0.25
531.4371948	0.05
532.1207886	0.31
533.3619995	0.11
535.3742065	0.42
537.2230835	0.05
543.3078003	2.00
544.3897095	0.15
545.3851929	0.09
546.4061890	0.22
547.4066162	0.33
553.2471924	0.27
554.3930054	0.17
555.2108765	0.30
557.6583862	0.15
558.4598999	0.17
559.3983765	1.09
561.4234009	0.21
563.5228271	0.07
565.4659424	0.12
567.3583374	1.84
569.2811890	23.78
571.1415405	0.65
571.7637329	0.03
572.5225220	0.11
573.3942261	0.79
575.3207397	1.26
576.3452759	0.24
577.2833252	2.72
581.4070435	0.09
585.2760620	2.81
586.0382080	0.21
587.3350830	100.00
589.4578247	0.25
593.4990234	0.35
594.3742065	0.50
599.3807373	1.03
602.2888184	0.12
603.3226929	0.66
605.2962036	0.41
606.2329102	0.38
607.2558594	0.22
611.3426514	6.51
612.4035034	0.58
613.3253784	0.09
614.6592407	0.10
615.6283569	0.06
616.2871704	0.08
617.7249756	0.05
619.5176392	0.18
625.5281372	0.10
629.2663574	15.86
630.1024780	0.14
636.6104126	0.15
637.2980347	0.14
648.1761475	0.16
653.7493286	1.29
658.4587402	0.16
661.3737183	0.06
662.3667603	0.63
663.1495361	0.16
665.2023315	0.32
673.3565063	0.08
674.9773560	0.10
677.3989868	1.51
678.9317017	0.19
679.5650024	0.19
690.1889038	0.13
692.0424805	0.15
693.3804321	0.04
694.8236084	1.92
695.4885864	4.97
702.0232544	0.15
703.3279419	0.58
706.4908447	0.29
711.4647827	0.38
712.3074951	0.39
715.2263184	0.06
720.1912231	0.53
721.3456421	13.73
722.1141968	0.09
724.4196167	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9391632	0.15
137.2445068	0.05
147.2900085	0.02
149.1701965	0.03
150.9860840	0.02
153.0987854	0.09
155.1356506	0.02
157.2068176	0.07
158.9585266	0.04
161.0243225	0.02
162.9772797	0.28
164.0809174	0.03
165.0159607	0.17
173.0881348	0.10
175.0005188	0.33
177.1399841	0.26
178.8445435	0.06
189.0063782	0.18
191.1271057	0.07
193.1189880	0.07
195.0939026	0.09
197.3061371	0.04
201.0953522	0.82
202.2476501	0.03
203.2811432	0.10
205.1751709	0.08
212.1710663	0.04
213.1691742	0.05
215.1703949	0.11
216.2106781	0.14
217.0101013	0.57
224.1159973	0.10
225.3059998	0.05
227.1734314	0.05
229.1420898	0.44
230.2977295	0.03
231.0624695	0.36
233.1330109	0.05
236.9823914	0.05
241.2222900	1.31
243.0623474	1.12
245.2626343	0.05
247.0610962	0.02
249.0863342	0.02
252.3130798	0.05
253.1675415	0.35
255.1285706	0.17
256.2279968	0.24
257.2637329	0.53
259.2477417	0.14
264.9448853	0.24
267.2020874	0.45
269.0165100	0.51
269.9589233	0.06
271.2289734	0.79
273.0997620	0.08
277.4241028	0.03
279.2370911	0.06
281.1791992	1.15
283.2734375	2.12
284.1152039	35.97
285.1041260	100.00
287.1607056	0.20
288.4744263	0.03
291.4341431	0.03
295.2120361	0.73
297.1773682	2.15
299.1319885	8.82
301.1699219	0.08
303.2811890	0.40
307.2789917	0.08
309.2033997	3.39
311.0912170	0.06
313.2707520	0.17
313.9874878	0.05
315.1911621	0.12
317.4482727	0.12
319.2344971	0.14
321.2182617	4.80
324.2149353	0.03
325.2901001	0.37
327.1666565	6.29
329.1961670	0.13
333.3418274	0.13
335.4767761	0.02
337.2603760	0.51
339.2750244	2.59
341.1782532	0.09
343.4332275	0.07
351.1669006	1.29
357.1723022	1.74
359.4504395	0.05
361.1737061	0.34
363.1869202	0.11
365.1468506	0.05
369.1272278	0.44
375.0858459	0.06
379.0917664	0.18
385.2250366	0.08
387.1948242	0.53
388.1514893	0.02
393.3769531	0.10
399.2452698	0.13
401.0812073	0.16
403.1961365	0.59
405.2188416	0.06
411.2826233	0.77
419.4649048	0.12
429.2078552	3.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
101.0478287	0.06
105.0658875	0.08
113.0282974	0.11
116.0251007	0.03
116.9070663	0.02
119.0243378	0.09
120.9321976	6.50
121.7591095	0.02
123.0651169	0.03
125.0610733	0.23
130.6370087	0.04
135.0532837	0.06
137.1520081	0.03
137.8555145	0.02
147.0694427	0.69
147.9190979	0.22
149.0624390	4.74
149.9909973	0.03
153.0125122	0.04
161.1162415	0.28
163.1295776	0.12
165.9675751	0.06
167.0297546	0.32
169.0108643	0.04
172.3443298	0.05
174.7888794	0.03
176.0945129	0.03
179.1671295	0.32
183.0289459	0.21
189.0198212	0.07
190.2700806	0.05
193.1337433	0.04
196.2401428	0.03
197.1308289	0.16
199.2776794	0.03
205.1517639	0.06
207.1141052	3.93
209.1451721	0.13
214.1855164	0.04
217.0927429	0.02
219.0776062	0.06
223.0955200	0.07
227.7810974	0.32
237.2288208	0.07
239.0908813	0.11
241.2419434	0.15
242.0759277	0.07
243.1038818	0.09
244.9882812	0.14
251.1518555	0.03
253.2685547	0.04
254.1366577	0.09
255.1585999	0.33
257.1759033	0.06
258.3452148	0.02
261.2355957	0.13
267.2721558	0.06
268.4799805	0.07
269.3543091	0.25
270.2371521	1.16
271.0473633	0.48
272.2202759	0.05
273.1418457	0.35
281.2789917	0.11
283.0791626	16.44
284.6300964	0.21
285.2851257	1.14
286.2930908	0.62
287.1618652	0.28
293.2430420	0.05
295.2424927	0.03
296.0890198	0.11
297.1923828	0.20
298.3006592	0.73
299.2189941	2.39
300.1636353	0.08
301.1770935	0.52
310.0368652	0.09
311.1549683	0.27
313.1594238	23.75
314.1378784	100.00
329.1837769	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2184
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
147.2453003	0.01
149.1328735	0.08
157.1911621	0.02
158.9293365	0.08
161.1466370	0.11
162.1113892	0.05
162.9073486	0.13
165.0790100	0.21
173.1025391	0.03
173.9215851	0.04
175.0915527	0.07
176.2420654	0.04
178.0126953	0.05
178.9994812	0.25
187.2946014	0.06
189.3307037	0.02
190.9654999	0.48
192.0858002	0.04
193.1149445	0.07
199.2184906	0.02
207.2449951	0.05
208.9946594	0.04
221.0316772	0.06
229.8744659	0.02
259.1007385	0.03
273.1263428	0.03
279.7047119	0.01
281.1406250	0.11
281.7874146	0.01
283.5262146	0.06
284.2161255	0.06
285.4148560	0.12
287.1985474	0.03
288.9767456	0.03
295.4958191	0.01
297.1823120	0.01
298.1564331	0.23
299.3248901	1.12
301.1722412	0.81
302.2692871	0.02
303.5623169	0.02
305.3045044	0.04
311.3982544	0.06
313.3085938	1.19
314.1383057	0.68
315.3854980	0.38
316.5648193	0.12
317.3175049	0.22
318.1690674	0.03
319.2322388	0.05
327.1278076	0.12
328.1859131	0.58
329.2832031	5.78
330.2020874	0.15
331.2382812	0.23
332.1387939	0.11
333.3336182	0.33
339.3654175	0.01
343.3589478	4.40
346.5061035	0.99
347.2710571	8.45
348.2536621	0.16
355.5856934	0.03
357.5322266	0.04
359.3129272	0.03
361.2737427	100.00
362.2012939	0.07
371.2587280	0.11
374.0064697	0.06
375.3179321	0.14
375.9656982	0.03
379.3586426	0.03
385.3190308	0.09
387.6486206	0.03
389.3317261	0.12
390.1524658	0.03
396.9957886	0.01
398.3529053	0.03
403.3807983	0.14
413.3798828	0.07
417.6022949	0.13
419.6707153	0.05
427.5579224	0.03
429.2235718	0.04
431.4073486	0.03
433.5627441	0.03
443.2519531	0.02
454.1704102	0.02
455.5082397	0.02
463.3079224	0.07
475.4143677	0.06
477.3394775	0.41
478.1174316	0.05
481.1907959	0.04
487.7557983	0.10
491.2910156	0.58
493.4510498	1.30
494.3511963	0.05
495.4503784	0.08
496.3312378	0.09
503.4027100	0.04
505.3845825	0.80
506.6333008	0.02
508.2141724	0.64
508.8578491	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0928
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
108.9081802	0.02
110.7850571	0.02
119.0573044	0.31
127.0520630	0.07
135.0051880	0.13
136.0241547	0.15
142.7400360	0.05
145.0024414	0.26
155.1327209	0.05
155.9753723	0.02
157.0026245	0.04
163.0818024	4.39
173.1766357	0.76
175.3935852	0.02
179.0848083	0.76
180.0620880	0.61
181.1578522	0.14
184.1540375	0.04
187.3571167	0.03
191.0431824	100.00
192.9117126	0.09
247.0072632	0.08
254.9145203	0.06
277.1099243	0.01
278.3538818	0.04
291.2872009	0.01
292.2362366	0.07
293.0819397	0.19
307.1403809	0.03
318.9428711	0.09
319.5463257	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	147.08
Annotation	3-Ureidoisobutyrate
Peak:m/z	Relative Intensity
83.8648529	0.03
100.9241486	1.74
128.0124054	0.02
129.9284058	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0599
Annotation	Unknow
Peak:m/z	Relative Intensity
174.0480042	0.02
174.9488983	0.01
186.7890930	0.09
189.9954681	0.03
200.1559296	0.04
201.0950928	0.12
215.1683350	0.05
215.9111176	0.12
217.0434113	0.14
217.8046570	0.03
226.9654846	0.28
231.1100464	0.09
233.9941406	0.11
235.1176453	0.38
239.1359558	0.03
241.2521362	0.05
243.3369446	0.11
244.9024658	2.74
253.7778778	0.04
255.9671631	0.02
256.9778748	0.30
258.1033630	0.08
259.0830078	0.05
260.5173645	0.08
261.1351624	0.04
262.1225586	0.04
272.9876099	0.15
274.8423157	2.99
277.1209106	0.54
277.9931946	0.05
279.0518494	0.06
285.3540649	0.05
287.0664062	0.14
288.9547119	2.26
290.1357422	0.17
291.0880737	0.17
292.9321899	0.20
294.8723145	0.30
299.1574707	0.07
299.9351196	0.03
301.0112915	0.21
303.1123657	0.08
304.8344727	0.11
307.0494080	1.90
308.1095581	1.24
309.2344971	0.30
313.1008911	0.12
318.8890686	2.35
320.0424194	0.03
321.2933350	0.33
322.1748657	0.03
323.1089478	0.20
324.9793701	1.25
329.2154541	0.11
331.0188599	0.29
332.0942993	0.03
333.3535156	0.17
334.0263062	0.02
335.1126099	0.26
336.2798462	0.19
337.0232544	0.41
339.1134644	0.04
344.0022583	0.02
345.9639893	0.68
347.0946045	1.12
348.9676514	15.59
350.1174927	0.04
351.1547852	1.06
352.3273926	0.19
353.1342163	0.03
355.1616821	0.26
361.5479736	0.14
362.2086182	0.17
364.0466309	17.54
365.0435181	11.27
366.1594238	0.38
366.9961548	0.95
367.5961914	0.03
373.1403809	0.26
374.2135010	0.07
378.2326660	0.09
379.1354980	0.36
380.1029663	0.10
381.0514526	0.04
382.1573486	0.64
383.3096313	0.08
390.0759277	0.05
391.0674438	2.35
392.1417847	0.59
393.1694336	0.10
393.9916382	0.24
395.2392578	0.18
396.9744873	1.53
397.9239502	0.37
399.0506592	0.13
400.0864868	0.04
406.9417725	0.33
409.0697021	100.00
411.3295288	0.03
412.3603516	0.12
414.9989624	0.37
417.9581909	0.04
419.0499268	0.23
421.1903076	0.03
421.9354248	0.13
423.0803833	0.12
423.8249512	0.03
425.9434814	4.55
427.0546265	16.35
427.8392944	0.15
431.1089478	0.02
431.7774658	0.02
435.4934692	0.43
436.2662354	0.27
443.2303467	0.20
446.1866455	0.44
448.8065186	0.09
449.8952637	0.15
451.1640625	0.15
453.1683350	0.04
455.1336060	0.28
457.4913940	0.24
459.4111938	0.31
460.1631470	0.17
461.0925903	0.06
462.1215820	0.03
463.0742188	0.18
464.0494385	0.12
467.2222290	0.06
468.0133667	0.23
469.0404053	1.02
470.0732422	0.08
473.0220947	0.21
479.7868652	0.25
480.6613770	0.25
481.3833008	0.21
482.2913208	0.20
483.7127075	0.02
485.1789551	0.36
487.1881104	0.03
489.3399658	0.27
490.3035278	0.15
491.2802734	0.36
493.1899414	0.04
494.0838013	0.07
496.0439453	0.04
497.9584351	3.55
499.0507202	4.26
500.2194824	0.11
501.1350708	0.02
508.0364380	0.34
508.9371948	0.07
511.1447754	0.35
512.8340454	0.47
522.8558960	0.09
524.7400513	0.03
525.9701538	2.04
527.0852661	0.24
528.1078491	0.35
529.1677856	8.63
530.1206055	0.42
535.2607422	0.33
543.4447021	1.21
544.0819092	3.30
544.9729614	0.55
548.1362915	0.07
551.9348145	0.27
553.0764771	1.87
555.4678345	0.08
556.1159058	0.10
557.1373291	0.09
563.8961792	0.05
570.0067749	4.05
571.1311035	10.27
571.9518433	0.09
587.2388306	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.0877
Annotation	beta-L-Arabinofuranosyl-(1->2)-beta-L-arabinofuranose
Peak:m/z	Relative Intensity
80.9139404	0.25
83.0412903	1.33
84.9299698	9.81
86.9953156	7.32
88.8710098	0.57
90.8258209	0.97
94.9712601	11.42
96.8824844	0.76
98.9808579	1.87
100.9974670	1.47
102.9630127	15.73
105.1269760	0.06
107.0635605	2.81
108.0368042	0.25
108.9155960	1.96
110.9951019	2.08
111.8460693	1.90
112.9073334	81.21
115.0267334	0.63
119.0148621	0.79
120.9544144	0.31
122.9582214	0.28
125.0465775	1.43
127.0415039	3.93
128.9555054	9.21
130.8959961	8.25
132.5943298	0.47
138.9580994	3.94
139.6019287	0.03
142.9663696	2.33
144.4827881	0.25
145.0913239	0.46
151.1802216	0.20
156.9811707	5.72
158.9246521	0.07
161.0023499	2.64
162.2512207	0.35
163.0372772	1.90
165.3660583	0.16
169.0163269	2.00
170.4838715	0.12
171.0859985	0.26
175.2074432	0.10
187.1614685	6.05
189.0487061	4.78
190.9331360	0.09
193.3437500	0.11
205.1076355	86.24
219.0060425	0.09
231.1716309	5.29
235.1214600	0.08
237.1515808	16.97
249.1578064	100.00
250.0436707	0.09
263.1294250	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2289
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
149.1285858	0.02
161.3242188	0.01
165.0700073	0.02
171.4075775	0.01
184.9507141	0.01
185.9888916	0.02
195.3142700	0.01
222.9016113	0.03
237.2528534	0.04
247.1571045	0.01
259.6676941	0.02
273.0799561	0.05
279.1713562	0.01
285.3088684	0.02
287.4603882	0.03
293.1401367	0.04
300.6033325	0.01
310.9487915	0.04
312.5058594	0.04
313.3889160	0.05
314.3096313	0.04
315.2799683	0.27
316.1701050	0.01
317.2897949	0.03
328.9868774	0.04
330.2179260	0.11
331.2616577	0.45
332.3153076	0.04
337.2631531	0.01
342.9894714	0.02
347.1737061	0.01
351.3826599	0.01
357.1466370	0.06
361.4317017	0.02
389.5085449	0.01
391.2682800	0.01
392.5112915	0.02
395.2106628	0.01
397.2533875	0.03
403.3374939	0.05
405.2048950	0.05
407.3561096	0.02
411.1809998	0.01
419.8390198	0.01
434.0509949	0.08
434.6974792	0.01
445.3301697	0.08
447.2825012	100.00
448.4038391	3.61
450.0633850	0.18
450.8161316	0.02
455.3937073	0.02
457.3514404	0.04
462.2395935	0.02
463.0291138	0.01
467.2035217	0.03
475.2460632	0.18
476.5102844	0.01
477.8112183	0.03
478.5348206	0.01
479.3198853	0.01
480.3188171	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0615
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
113.0416183	0.02
121.0023346	0.77
122.9110031	0.03
136.9941711	3.88
143.1224060	0.04
146.1206360	0.02
152.8965454	0.05
162.9748230	0.37
164.9810181	100.00
166.1632690	0.08
183.0298920	0.13
190.0817871	0.22
190.9745178	1.67
192.1825256	0.08
197.1033020	0.03
209.0792084	0.30
218.1851501	0.02
223.4951782	0.04
225.1171570	0.02
226.8619690	0.04
228.2112427	0.04
241.1280823	0.02
242.3827515	0.02
245.2938538	0.05
254.6849976	0.02
257.1699524	0.05
259.3900452	0.06
268.1352844	0.02
271.3982544	0.02
272.1296997	0.03
277.1594849	0.37
281.3418274	0.02
283.1143799	0.03
286.0759888	0.48
289.1405334	0.07
291.4125671	0.03
298.3940430	0.08
299.1774902	0.08
301.1823730	1.79
309.0392456	0.02
312.2055359	0.27
315.0774231	1.19
316.2609863	0.06
317.1560059	0.04
324.3531494	0.04
326.0834045	0.02
327.1693420	0.16
330.1160278	46.20
331.2554626	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.2339172	0.03
173.9704742	0.06
175.0330963	0.17
177.1377716	0.02
178.1145020	0.03
179.0178986	0.10
183.1452484	0.21
184.0815887	0.04
187.1307678	0.14
188.0606384	0.23
199.2940063	0.05
200.2793732	0.01
202.0943909	0.05
203.1513214	0.50
204.5603638	0.12
205.2338409	0.10
206.1251221	0.02
215.2013702	0.04
217.2511444	0.03
227.2320862	0.08
228.1200409	0.05
230.0847321	0.05
231.0990601	0.06
232.4075012	0.02
241.2105103	0.10
243.2217102	0.38
245.0643463	3.25
246.3080139	0.16
255.0375366	0.21
257.3116455	0.04
261.1880798	0.05
266.9306641	0.11
269.2322998	0.49
270.0673828	0.06
271.1125793	0.16
273.1032104	1.57
274.1961975	0.19
287.1210327	8.17
289.1288452	20.62
290.2291260	2.87
297.3840942	0.03
299.1546631	5.89
300.2538147	0.96
301.3743896	0.04
305.0001831	0.10
311.2083740	0.04
315.3890991	0.05
327.2003174	0.14
329.2553711	0.26
330.2133179	0.13
331.2675781	0.28
332.1343994	0.07
339.2629395	0.24
341.2398682	0.27
342.2880859	0.02
347.3026733	0.02
353.2766113	0.03
357.3301392	0.50
361.4604492	0.05
363.1559448	0.03
381.2658691	1.12
382.2600708	0.18
384.4565430	0.07
389.2696533	0.07
391.3985596	0.05
397.5601196	0.02
407.2232056	43.89
408.3377075	9.23
409.3216553	0.47
410.1771240	0.10
411.2464600	0.22
415.2514038	0.10
422.3884277	0.03
423.2545166	0.50
425.2033081	100.00
426.2020874	14.06
433.1670532	0.49
434.1752319	0.05
437.2511597	0.10
449.3512573	0.76
451.2194214	30.86
452.2277222	6.23
456.2933350	0.06
467.2406006	1.15
468.1442261	0.38
471.3729248	0.02
472.3594971	0.11
473.1912231	0.02
476.2288818	0.11
484.5551147	0.05
489.3757935	0.12
491.3049316	0.17
492.2974243	0.09
493.4180298	0.03
501.0484009	0.04
507.5025635	0.04
514.8239136	0.14
515.4795532	0.38
516.4130249	0.12
517.5992432	0.05
531.2578735	0.06
533.3135986	1.37
534.2933960	0.94
535.4351196	0.02
541.1889038	0.07
559.2647705	13.45
560.3813477	3.12
561.2203369	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.17
Annotation	Lupiwighteone hydrate 7-glucoside
Peak:m/z	Relative Intensity
145.0839233	1.18
158.3502960	0.10
159.0884705	0.13
160.8471527	0.10
163.0787048	2.11
174.2198486	0.08
179.2783051	0.05
187.0125732	0.48
191.0636902	0.15
193.4595947	0.05
203.1095428	0.03
205.0640869	0.29
209.2230530	5.47
215.9942627	0.09
221.2298889	0.06
247.0480499	0.39
249.0578003	0.18
269.2839355	0.22
271.0985718	0.05
280.2571106	0.05
281.0081787	0.19
293.2570801	2.05
298.4548645	0.12
303.4619751	0.06
307.1740723	27.28
318.2784424	0.11
323.2205200	0.18
329.3170776	0.07
333.4384766	0.15
334.2089844	0.22
335.3372803	0.99
336.0848389	0.09
337.5323486	0.05
348.8063354	0.10
353.2487183	3.37
354.4133301	0.41
355.3208008	0.14
356.9392700	0.05
359.2214966	0.10
366.3635864	0.15
369.0506592	0.11
371.3116455	56.43
373.2405396	0.18
377.3598633	1.41
379.0153198	0.31
385.0283203	0.08
389.4489136	0.11
399.2017822	0.24
415.1965942	0.09
416.1072998	0.05
417.5343018	0.04
423.1614990	0.17
427.1315918	0.04
430.3865356	0.11
431.3388062	0.07
433.1603394	0.09
435.0314941	0.42
437.3922729	4.01
445.3981934	0.17
455.3796997	20.35
457.3027954	100.00
458.1607666	0.29
470.1768188	0.15
471.1433716	0.11
472.2898560	0.52
473.5439453	1.07
481.4395752	2.17
485.2885132	0.07
490.3781128	0.14
499.3008423	94.37
500.2570190	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	571.2185
Annotation	5alpha-Ethoxy-6beta-hydroxy-5,6-dihydrophysalin B
Peak:m/z	Relative Intensity
165.0634460	1.73
166.8818512	0.02
180.0770416	0.46
180.9853973	0.87
195.1192017	5.74
205.1017609	0.06
207.0828857	0.05
208.1077423	1.99
209.3724976	0.22
211.2095642	0.04
212.0637512	0.04
221.1006470	0.06
249.1404877	0.08
250.2338562	0.09
256.1896362	0.16
265.5355530	0.13
267.2351074	0.04
281.4109497	0.08
286.1285400	0.11
287.2846680	0.04
295.3126221	0.12
297.2960815	0.05
305.0171814	0.04
310.0284424	0.16
311.5812683	0.49
312.2385254	0.74
313.2183838	0.10
315.3185425	0.38
317.1687622	0.23
318.7384033	0.07
319.3659668	0.20
325.3209839	1.49
326.2926025	3.24
327.2895508	2.32
329.2338867	0.06
330.1984253	0.98
337.2083130	0.06
342.1535034	3.57
343.2935791	0.09
345.2088013	100.00
355.0670776	0.22
357.3142090	45.56
358.8767700	0.18
361.4694824	0.05
364.3945312	0.08
370.4505615	0.09
371.4281616	0.28
372.1081543	0.14
373.2388306	0.20
375.2421875	12.90
377.1397705	0.04
381.3203125	0.03
388.0186157	0.11
389.1591797	0.51
390.2368774	0.16
391.4525146	0.41
400.0164185	0.21
401.2037354	0.05
406.4631958	0.05
407.0667725	0.05
408.3521118	0.09
409.0363159	0.08
416.8214111	0.06
423.2111206	0.06
429.3557739	0.13
435.3257446	0.07
437.2932129	0.07
447.2573853	0.29
448.6989746	0.08
449.4320679	0.28
451.2066040	0.03
460.4421387	0.11
469.0169678	0.03
472.4993896	0.19
475.1697998	0.30
479.3553467	0.06
482.3871460	0.04
484.9680176	0.22
485.5773926	0.25
497.0081787	0.09
509.4818115	0.06
511.0003662	0.04
512.1724854	0.06
521.4061890	0.06
523.2609253	8.37
523.9628296	0.49
525.2773438	3.34
526.3394165	0.95
527.1040039	4.92
527.7601318	0.02
528.4681396	0.18
533.4491577	0.08
534.3701782	0.13
535.3495483	0.29
536.4512329	0.13
540.2491455	0.15
541.2539062	0.65
552.1556396	0.15
553.2965698	1.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.9829407	2.31
58.9771309	5.92
60.8303909	1.25
66.9716949	0.39
68.9126892	0.30
70.9549789	7.14
71.6242905	0.23
73.0279846	0.51
80.9336319	3.09
83.1273346	0.59
84.9573212	87.15
85.9275513	0.75
86.8264923	22.04
93.0080566	49.71
96.0409393	0.18
98.9324036	3.68
100.9249725	0.68
109.0151215	24.02
110.9524689	73.40
113.3271027	0.46
115.0144501	1.81
121.0673676	0.61
124.0195618	0.31
126.9966736	100.00
128.9594421	1.80
131.0512390	0.31
136.9469452	3.38
143.0885620	3.06
144.6956787	3.34
146.2155914	0.47
146.9010162	0.47
153.0374603	9.32
154.9953766	14.68
171.1058044	28.81
172.9627533	97.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
117.0629272	0.15
210.7645874	0.88
213.0046692	0.31
251.1043091	100.00
269.4028320	0.21
279.1462402	0.23
280.0330505	0.27
281.1442261	0.46
296.3870544	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.1141
Annotation	Castamollissin
Peak:m/z	Relative Intensity
149.0112152	0.11
166.9977417	0.08
176.1737823	0.09
191.0745239	0.17
193.1894836	0.02
205.0736084	0.03
206.0450745	0.03
207.1198730	0.02
214.0933990	0.11
227.0704956	0.05
228.3207703	0.08
229.1732025	1.20
230.0111694	0.07
232.2094727	0.30
247.1129608	0.20
249.3700256	0.03
253.1326904	0.07
256.1237793	1.93
257.1811523	0.07
271.2124329	9.97
272.2977600	0.02
273.2117004	0.18
279.3494873	0.06
283.1526489	0.82
284.3651123	0.02
285.3411255	0.06
287.1250916	0.07
297.0843811	0.31
300.0856628	3.35
315.1056824	100.00
327.1860657	0.06
329.2515564	0.69
331.3491516	0.03
333.2837830	0.29
337.1635742	0.08
355.1610413	1.38
369.1780396	22.40
379.2276306	0.03
411.1693726	0.02
427.2732849	0.20
449.3246765	0.03
450.3530579	0.19
451.3791199	0.20
463.2079468	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	772.2695
Annotation	Unknow
Peak:m/z	Relative Intensity
241.2727661	0.21
253.1633606	0.41
268.1467285	0.54
271.0330200	1.73
288.9201660	3.12
299.8303833	0.07
306.7308044	2.55
307.5270386	0.18
311.1763000	0.10
319.7197876	0.07
321.0351562	0.56
323.1542358	0.22
324.4566650	13.20
325.0787354	48.57
342.9592896	14.09
384.6976318	0.23
403.3672485	0.06
407.1834717	0.22
408.1895142	0.13
415.0424194	0.19
433.0333862	0.66
437.2931519	0.06
443.2164307	0.08
448.1119385	0.10
449.7611694	0.16
450.9545898	2.06
468.0778198	0.17
468.9255981	0.56
473.0245361	0.32
478.5271606	0.07
482.3798828	0.23
484.0089111	0.45
486.2697144	15.31
487.0312500	100.00
487.9575806	0.16
491.0466919	1.21
499.8114014	0.05
501.7359619	0.19
503.0267334	0.49
504.8049927	66.42
506.1076050	0.36
513.0314941	0.12
520.7168579	0.12
527.4552612	0.22
528.4256592	0.15
529.2219849	0.20
542.0603638	0.13
550.8057251	0.13
561.5737915	0.26
592.1006470	0.22
593.4489136	0.06
598.5615234	0.39
603.0706787	1.53
609.5955811	1.79
610.2038574	17.19
611.3164673	0.41
613.6193848	0.12
622.1209717	0.08
629.0493164	0.14
633.3077393	0.22
636.3187256	0.39
639.6766357	0.16
648.8988647	2.56
666.6535645	1.13
667.4456177	0.32
689.0764771	0.09
726.4970093	0.05
755.3245239	0.43
774.9857788	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1068
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
287.2242126	0.54
303.1091003	0.02
317.1265564	100.00
317.9267883	0.01
431.2621155	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2133
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9894562	0.21
163.0417175	0.15
191.0101013	0.21
220.7019653	0.07
225.9219971	0.03
237.3194885	0.04
240.3535461	0.04
251.1609802	0.13
266.3045654	0.03
281.8271484	0.05
293.0996399	0.09
305.0676270	0.14
310.9313049	0.16
311.6023865	0.14
313.3641052	0.29
314.3121948	0.49
315.2890015	0.68
317.4428711	0.02
323.1354675	0.03
325.2748413	0.09
328.5055542	0.03
330.3061218	0.47
331.1383667	0.65
332.0615234	0.08
342.8366699	0.04
345.3608093	0.10
350.4835815	0.07
351.1619263	0.12
358.4546204	0.05
361.3891602	0.24
373.1719360	0.06
389.2971802	0.04
403.6334839	0.11
405.2577209	0.03
441.3186340	0.06
446.2313538	14.80
447.2850647	100.00
447.9256287	0.27
449.3388062	0.15
450.5124207	0.04
457.2992249	0.10
465.2624207	0.08
473.2819519	0.10
475.2064819	0.12
476.7272644	0.04
478.6744690	0.13
479.3651428	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.29
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0292664	0.17
262.0874329	0.21
290.0028687	0.14
308.2468262	0.30
331.2346191	100.00
331.9711914	0.03
343.5439453	0.04
385.5755005	0.04
403.3491211	0.66
407.2120361	0.09
421.3756104	0.18
516.3707275	0.12
517.6322632	0.03
519.2379761	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
192.9777222	0.35
195.9754486	0.43
196.9791718	0.09
206.8734741	0.45
212.8679657	2.70
220.1391602	0.12
255.1041870	0.13
266.8411560	0.16
286.9212341	0.20
290.7614136	100.00
312.1748047	0.21
315.0462646	3.41
322.3010254	0.25
339.0336914	0.50
340.2373047	0.15
356.9458618	8.60
357.9602356	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1192
Annotation	Unknow
Peak:m/z	Relative Intensity
109.1319809	0.08
113.1310196	0.07
126.8487701	0.04
161.1289978	0.23
172.9405060	0.07
178.9188385	0.04
191.0439148	100.00
207.2379303	0.05
208.2120819	0.03
283.1883545	0.02
290.9541626	0.05
311.5749512	0.02
321.3569946	0.03
324.3063049	0.08
324.9951477	0.05
333.1121521	0.07
353.0623779	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.4659
Annotation	PA(22:4(7Z,10Z,13Z,16Z)/15:1(9Z))
Peak:m/z	Relative Intensity
233.3734436	0.20
261.3246765	0.41
275.6133728	0.20
277.2832642	55.85
278.4447937	13.37
279.3191223	100.00
280.3731079	13.22
299.3605957	1.83
312.5126343	0.09
371.1642456	0.09
373.4704590	0.12
413.4244995	0.27
427.5077515	0.99
428.6492310	0.44
429.5512695	0.80
430.5298462	0.10
445.3495483	16.07
446.3455811	3.46
447.3543701	7.90
448.4057617	1.13
645.9180298	0.08
647.6876831	0.14
649.9237671	0.06
673.7787476	0.08
689.9461060	1.85
690.9544067	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.882
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8563385	100.00
141.1392822	0.29
153.1193542	0.16
161.1324158	0.19
197.0596619	0.07
209.1365967	0.34
210.8311157	0.22
212.8436584	45.69
250.0850220	0.16
258.7271118	0.10
267.2371826	0.10
269.1535339	0.09
279.0584106	0.05
280.0272827	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	733.3072
Annotation	Unknow
Peak:m/z	Relative Intensity
209.2053528	0.75
228.1281586	0.04
245.0561218	0.04
257.2320862	0.04
266.9011230	0.06
269.0892029	0.03
272.4253235	0.05
295.2454224	0.05
297.1053162	0.07
301.3031006	0.05
311.2290039	0.03
312.2122192	0.50
313.3459778	0.85
314.4472046	0.12
325.4847412	0.07
327.2247925	22.78
328.2864685	3.82
329.0185852	0.04
330.0117798	0.04
335.4291382	0.11
341.3376160	0.31
343.2763672	0.35
344.6203613	0.04
346.1495361	0.04
352.9780884	0.08
356.2500000	0.21
357.3178101	0.46
359.3039551	0.28
360.3055115	0.09
368.9763794	0.24
371.2982788	0.24
372.3351440	0.10
387.2018433	0.17
391.3147583	0.06
404.2256470	0.06
405.0161133	0.23
421.4188232	0.09
427.5231934	0.09
431.4636841	0.05
432.4058228	0.03
449.4343262	0.03
480.9310303	0.09
487.5948486	0.04
489.4131470	0.08
491.6908569	0.03
493.5161743	0.04
495.1486206	0.08
495.7952881	0.04
503.7149048	0.03
507.5421143	0.08
509.4362183	0.15
510.3054810	0.03
513.7265625	0.32
522.4483032	0.17
525.3464355	0.12
527.4031982	0.08
537.2963867	100.00
538.3421021	23.17
541.3478394	0.06
542.2424927	0.23
553.0536499	0.14
553.7670288	0.04
563.1462402	0.06
571.2235718	0.04
581.3082886	0.10
582.1967773	0.31
584.4458618	0.09
585.8237305	0.05
592.1917725	0.05
600.4196167	0.03
602.5624390	0.05
609.5108032	0.04
613.7275391	0.03
615.4535522	0.03
632.2960205	0.05
637.2970581	0.03
639.1690674	0.08
645.0524292	0.16
646.6031494	0.10
648.4480591	0.04
652.1431274	0.14
658.0837402	0.20
671.4812012	0.15
673.6113892	0.10
675.4763794	0.05
683.3117065	0.12
685.3355103	50.40
686.3721313	16.27
687.2892456	0.04
688.2839355	0.09
689.2562866	0.03
689.9928589	0.14
691.7822876	0.08
701.6387939	0.12
703.4526367	0.18
704.2678833	0.23
711.1111450	0.18
713.5285034	0.12
715.3276978	1.53
716.2451782	0.20
723.6041870	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	739.147
Annotation	Prunin 4'',6''-di-O-gallate
Peak:m/z	Relative Intensity
273.3366089	0.07
287.3170776	0.01
291.3770142	0.01
303.2470093	0.11
309.1615906	0.03
315.1288452	0.06
345.2306519	0.09
409.5693970	0.07
423.1558838	0.06
435.2429199	0.05
439.2637939	0.41
440.1461182	0.09
477.1989136	0.09
481.4333496	0.09
482.3757324	0.05
499.0120239	0.05
535.3092041	0.02
553.6620483	0.03
560.2421265	0.02
565.2982788	0.06
571.2702026	0.09
575.0806274	0.05
576.3687134	0.09
577.3728638	0.18
578.4253540	0.08
579.4910278	0.05
587.3178101	0.07
590.2236328	0.02
593.3543091	0.01
605.4500732	0.01
607.2059937	100.00
608.2673950	31.80
642.8249512	0.12
649.0408325	0.04
658.5567017	0.03
673.6135254	0.07
681.6842651	0.01
721.3716431	0.09
722.4235229	0.07
740.8247681	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3046
Annotation	Sphinganine
Peak:m/z	Relative Intensity
92.8886261	0.03
95.02526093	0.44
97.00169373	0.34
109.0586853	0.35
110.961998	0.30
112.9234695	0.02
122.9582138	0.34
125.0958557	0.07
134.8392029	0.09
137.0744476	0.24
138.5527954	0.15
141.0266113	0.06
142.9542542	0.02
148.7939911	0.15
151.0292664	0.11
152.8840027	0.05
159.196991	0.06
162.8891144	0.02
164.1201172	0.03
165.1498108	0.16
165.8703003	0.02
166.9451599	0.03
169.3819885	0.02
171.9307251	0.01
173.2810974	0.02
174.031189	0.06
179.2008362	0.05
191.1080627	0.03
193.2136993	0.10
201.1737976	0.02
202.4298706	0.03
207.3265381	0.10
211.2727356	0.02
211.9904785	0.03
213.3896179	0.07
214.1074219	0.02
216.1746216	0.04
221.2380676	0.01
224.308075	0.07
225.2102356	0.03
229.0775146	0.31
230.9136963	0.06
233.0697632	0.03
235.4797363	0.04
238.072998	0.02
238.9906006	0.11
240.3934631	0.90
242.1835632	0.07
247.2023621	0.07
248.7110596	0.07
249.3270264	0.42
253.2426453	0.03
254.3800354	0.82
255.3109741	0.11
256.1907349	0.16
257.181427	0.59
258.1093445	0.09
259.2931213	0.04
260.2268066	0.05
266.3472595	4.78
267.3008728	0.21
270.936554	0.02
274.1421509	0.08
275.0840454	0.16
284.2991028	100.00
285.0250244	0.68
287.1854248	0.19
292.9191895	0.06
293.8506775	0.01
302.3442993	0.07
303.3136292	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	237.0616
Annotation	Quinic acid
Peak:m/z	Relative Intensity
71.0324478	2.11
72.9255447	2.19
74.8558350	100.00
82.9305115	0.73
84.9955750	1.84
86.8364105	1.53
88.8552399	4.94
94.9250794	0.80
98.8833466	0.38
100.9033508	11.50
113.0179138	7.89
116.9692841	6.04
118.9630432	4.87
125.1207275	0.17
128.9971466	2.81
131.0247498	0.83
138.1053925	1.55
140.9189301	0.46
142.9191132	2.02
147.0567474	3.69
148.9877167	0.49
158.9458923	1.23
161.0306702	2.82
170.9932556	0.27
177.1879883	0.49
178.9791565	1.56
193.0594177	0.87
219.0555267	0.80
420.7134399	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.22
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
129.0106964	0.04
136.8417206	0.07
142.8388367	0.25
151.0386353	0.60
152.1483612	0.02
153.0058899	0.54
157.7934265	0.06
159.0376892	0.40
161.0925598	2.49
162.9707489	0.07
165.1078339	0.02
169.0871124	0.25
178.9114685	0.47
179.9914246	0.05
180.9209595	0.18
190.0565491	0.05
191.0615234	0.23
201.1146545	0.18
204.0790100	0.13
205.1857910	0.02
207.1991577	0.07
216.0250549	0.03
217.0476685	0.43
218.1072693	0.06
219.2134705	0.07
221.0658569	0.05
223.2815247	0.04
228.8105011	0.03
230.2230377	0.18
233.1476440	0.05
235.2711945	0.05
240.2539062	0.05
241.2933960	0.11
243.1587830	0.22
243.9061279	0.08
245.0932312	0.11
247.1192627	0.06
252.1046753	0.04
253.3159180	0.13
255.1600037	0.30
257.1065063	0.28
260.2147522	0.09
261.2929688	0.07
262.8508301	0.13
265.1545715	0.22
267.1754761	0.03
267.9662170	0.15
269.1711121	0.11
271.1135864	2.38
273.1341553	1.54
279.4817810	0.03
284.1444092	0.14
285.1106567	3.02
286.1485291	1.91
287.0635376	0.22
289.1858215	0.06
290.2456055	0.10
292.2275391	0.09
293.2465210	0.07
295.2935181	0.06
297.1021118	0.15
298.1201782	0.17
299.0798950	2.45
300.1648865	0.79
301.1881714	0.71
303.2377014	0.41
309.2436829	0.13
314.1347961	100.00
315.2178040	41.53
316.2156067	0.41
317.0901794	0.14
323.8850098	0.11
327.1462097	0.17
328.6510315	0.53
329.3010864	1.88
330.0315552	0.05
331.1669617	0.08
337.4566650	0.07
338.9834595	0.16
342.0946655	0.30
343.2865906	0.43
344.2717590	0.03
357.2327576	11.31
358.2861023	0.20
367.2307434	0.04
369.1376038	0.08
374.1733398	0.06
379.2804260	0.16
383.2720642	0.25
385.4807434	0.05
387.1612854	1.69
388.1781921	0.12
399.1816711	0.18
400.2236023	0.05
401.3829041	0.28
403.3452148	0.14
411.4496155	0.12
419.3137512	1.43
432.4207458	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2237
Annotation	S-Furanopetasitin
Peak:m/z	Relative Intensity
148.9090118	0.19
165.8988342	0.08
179.1776581	0.07
191.2053223	0.05
193.2576599	0.07
197.1951904	0.04
221.2532654	0.06
256.4552612	0.03
260.1105957	0.03
273.1239014	0.02
293.2990723	0.03
309.1951904	0.03
311.2766113	0.09
314.1514893	0.15
329.1896362	1.64
331.1900635	0.55
346.3731689	0.06
347.2379761	0.35
354.8489380	0.06
355.5397949	0.08
373.1968994	0.08
463.3151245	100.00
463.9270020	0.29
465.0195312	0.07
467.7067871	0.13
489.4424438	0.08
491.3870239	0.28
493.2159424	0.04
494.1486206	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.2303
Annotation	Unknow
Peak:m/z	Relative Intensity
214.8435669	0.27
232.9085236	1.21
250.8852234	0.03
263.2782593	0.07
288.9543762	0.06
298.0808716	0.05
305.9364319	0.11
310.9436035	0.12
323.3203430	0.23
337.3739014	0.07
341.0884399	0.49
341.6892090	0.04
383.2526855	0.11
395.2380981	0.01
407.3860474	0.04
424.3569336	0.04
439.1306152	0.03
442.6148682	0.25
443.2962036	0.37
447.2605591	0.03
473.4422607	0.08
485.2728882	0.03
495.3820801	0.15
497.1790161	0.09
499.2874756	0.08
503.2913818	100.00
513.2133179	0.21
516.9006958	0.02
527.1571655	0.05
531.2439575	0.11
550.9377441	0.22
588.4613647	0.02
613.3163452	0.03
631.1442871	0.11
632.2362671	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.0442
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0136719	0.03
138.9761353	1.58
142.8715515	0.03
148.9301300	0.04
150.9336243	0.20
152.9522400	0.04
165.0688782	0.43
167.0655670	0.56
168.9695129	0.29
181.0324707	0.26
195.0241089	0.07
199.0187378	0.02
202.9826355	0.09
204.7449493	0.10
207.2931976	0.03
213.2008057	0.02
223.0555725	1.82
229.1231995	0.16
230.7646790	0.03
239.1884460	0.51
241.0617676	100.00
241.9978943	0.06
245.8045959	0.15
247.0806885	0.03
249.2137451	0.04
255.1809082	0.02
263.3031311	0.03
266.2241211	0.04
273.1925964	0.06
273.8254395	0.03
274.9728394	0.03
277.4729919	0.03
281.3671265	0.03
284.3388672	0.03
288.3237610	0.16
289.1403809	0.04
308.0402832	0.06
309.3767090	0.03
311.2385559	0.07
316.5595093	0.05
317.3154907	0.05
319.1681519	0.16
321.2406616	0.10
325.2510376	0.02
329.2127380	1.39
333.2312012	0.11
341.2585449	0.10
347.2621765	0.14
349.3799744	0.04
361.7162781	0.11
363.1237183	1.28
365.1544495	0.69
382.2540283	0.04
390.2503357	0.02
391.1682434	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	249.0803
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
79.9138489	6.24
81.0429306	1.57
95.6231308	1.72
96.8866882	56.47
98.8404694	0.73
110.8484192	0.49
155.0435944	0.98
159.1384277	0.46
163.1182098	1.09
164.9563141	0.80
179.0709381	0.32
180.9853821	100.00
182.0923004	1.57
202.9522095	0.92
205.0579376	0.69
221.0001678	0.87
230.1608276	0.57
231.1619720	38.13
231.7954865	0.94
249.1717987	19.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.11
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
163.1593018	0.10
167.2839966	0.08
177.4417725	0.03
191.2338104	0.05
203.1125336	0.44
206.3318634	0.10
208.2069702	0.15
211.5295258	0.11
239.2960815	0.10
240.1634369	0.44
249.3517456	0.06
266.1394043	0.15
267.3359375	0.13
287.1200562	50.75
297.9523926	0.15
302.4304810	0.11
307.1094360	0.10
311.4287720	0.57
314.2225952	0.09
315.9187622	0.31
317.3834839	0.08
323.3634033	0.24
329.2764893	1.76
331.2117920	100.00
333.1803589	0.17
336.1419678	0.07
338.1636963	0.07
339.2344360	0.23
349.3699341	0.09
351.1439819	0.14
353.2685547	0.12
354.1423950	0.28
358.4808350	0.08
360.5911865	0.10
361.5911865	0.08
365.1209717	0.47
366.5046997	0.19
368.2649536	0.11
371.4549561	0.09
379.2084351	0.24
380.3314209	0.59
383.1467896	0.34
386.2792358	0.08
387.5159302	0.06
391.1403198	0.23
393.6030273	0.16
394.4277954	0.13
395.2123413	0.72
396.6211548	0.23
403.3032227	0.27
406.4849243	0.17
407.4505615	0.24
413.3784790	0.17
418.4314575	0.06
420.3092651	0.63
421.4089966	0.15
426.2233276	0.20
436.2244263	0.07
439.4067993	0.27
447.3259888	0.07
455.1132812	0.07
457.5834351	0.26
460.5905151	0.20
471.3522949	0.07
475.2459717	0.35
490.3778687	0.35
491.3303223	0.40
503.2971191	0.05
504.1539917	1.32
507.4036255	0.18
508.4619751	0.18
513.4031372	0.23
516.3815308	2.22
517.3553467	3.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1613
Annotation	b-D-Xylopyranosyl-(1->4)-a-L-rhamnopyranosyl-(1->2)-D-fucose
Peak:m/z	Relative Intensity
125.1153717	0.06
130.8903198	0.30
142.9927216	0.06
146.0959015	0.02
149.0138092	1.02
153.2298279	0.10
166.1245728	0.05
172.9549408	0.03
179.1528015	0.01
185.1916809	0.03
190.1578979	0.14
191.1112366	0.18
193.1457520	0.02
195.0851135	0.05
215.4527893	0.03
220.9306641	0.07
223.2331848	0.02
232.5753784	0.04
233.3052521	0.04
239.2211609	0.04
245.0315247	0.03
249.3321533	0.06
250.1842651	0.05
251.2773132	0.03
267.2380371	0.06
268.4767761	0.02
274.4458618	0.01
275.2951355	0.18
279.1518860	0.09
293.2225647	19.70
298.2270813	0.03
309.1778870	0.07
311.2008362	0.01
315.1590576	0.08
323.2184143	0.09
328.9895020	0.04
339.1613770	0.98
377.3211060	0.01
379.4475098	0.05
380.1481323	0.01
385.1522827	0.01
392.1752930	0.02
395.1023865	100.00
396.1039734	0.03
397.1890564	1.06
405.2979431	0.04
411.2605286	0.05
412.4837341	0.01
422.4056091	0.07
423.1049500	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1288
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
82.9434967	0.06
100.9087372	0.04
109.2183838	0.07
111.0066986	2.49
136.2501678	0.05
137.2013855	0.14
138.1935730	0.21
139.0013275	0.19
147.2347870	0.05
151.1272736	0.22
153.0273285	100.00
158.9772034	0.08
161.1329193	1.36
162.9039154	0.07
175.3315887	0.12
176.9892731	0.10
179.2299805	0.24
185.1634979	0.03
186.4495087	0.08
190.9707489	0.12
193.0420074	0.03
201.2380371	3.67
203.1733093	0.57
204.2106476	1.41
206.0118561	0.06
211.1085052	0.05
217.2087097	0.22
219.2423859	33.38
227.1180878	0.26
235.0845184	0.10
243.2125244	0.03
244.1772003	1.37
245.1947021	1.37
246.2307587	0.07
248.3739166	0.15
262.7131958	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1716
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
155.3170166	0.10
171.0955658	0.22
173.0760193	1.11
188.8951416	0.08
191.1157227	100.00
312.3378906	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1249
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1191406	0.24
180.1224518	0.02
189.1601868	0.02
191.7232666	0.02
200.0377197	0.01
209.2062378	0.01
210.9802246	0.01
212.1373749	0.01
213.2839661	0.01
216.1392517	0.01
218.2981415	0.02
227.2766571	0.03
228.2635193	0.01
229.2168732	0.09
230.0104370	0.02
235.2463684	0.02
239.1749725	0.04
241.8738861	0.01
243.4671021	0.03
245.2758026	0.06
255.2705383	0.12
256.0840759	0.03
257.1827698	0.04
269.2296753	0.01
271.1149902	0.16
272.4295654	0.10
273.3415527	0.08
283.1830444	0.03
283.9357300	0.02
285.2222900	0.02
289.4065247	0.02
293.1292419	0.04
297.1642456	0.02
297.8970947	0.03
299.2832031	0.18
300.2754822	1.72
301.1467896	13.21
302.2153320	2.42
307.2679443	0.04
311.2238770	0.06
325.2146606	0.01
337.2048950	0.01
343.1949463	0.12
344.1639404	0.04
367.2127075	0.03
373.2611084	0.02
374.3524780	0.02
395.1395264	0.01
397.2875977	0.01
401.1740723	0.03
403.5853882	0.01
409.5009155	0.02
416.2956543	0.01
428.1938477	0.02
445.1842651	0.34
446.1603394	0.03
447.4020386	0.02
461.5948486	0.08
463.2362671	100.00
464.1996460	20.23
464.8482056	0.03
473.3678589	0.01
478.5316772	0.01
483.2600708	0.04
484.4262085	0.01
489.1450806	0.15
490.1198120	0.09
500.2417603	0.02
523.2454224	0.03
528.3729248	0.03
547.3330688	0.03
548.5997925	0.01
550.5745239	0.02
561.6879272	0.06
563.2260132	0.35
564.7767944	0.03
565.6180420	0.04
566.3609009	0.01
573.0492554	0.02
590.8997192	0.06
591.5211792	0.02
600.8718872	0.02
602.3432007	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.175
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
184.4729462	0.04
201.2921448	0.02
207.2764587	0.01
216.9778137	0.03
229.2730408	0.14
238.1016693	0.06
243.1105499	0.02
255.3223877	0.03
257.2557983	0.19
272.8604126	0.18
274.1611938	0.16
279.2241821	0.02
285.1994019	0.21
287.3422852	0.09
301.2286377	0.05
302.1648560	0.75
305.2796631	0.08
309.1426392	0.12
312.4583740	0.02
315.3811035	0.01
317.1264648	100.00
330.2147522	0.01
331.3182983	0.11
351.4697876	0.01
359.2600098	0.66
364.4452515	0.03
365.1161499	0.02
374.1964722	0.07
376.2546387	0.05
377.5508423	0.03
381.7492065	0.05
383.2706299	0.20
394.1785278	0.02
395.0495605	0.02
399.3245850	0.07
403.3530884	0.02
406.0798340	0.05
413.2627563	0.06
415.3126831	0.02
419.4942627	0.10
420.3739624	0.03
425.3424072	0.10
426.9827881	0.03
431.6416016	0.02
433.2769775	0.02
436.3117676	0.07
441.0906982	0.17
442.9731445	0.03
444.5350342	0.04
447.5324097	0.04
448.2811279	0.02
449.2290649	0.06
456.1270142	0.04
457.1177368	0.01
461.2142334	1.12
462.3686523	0.23
463.0852661	1.62
465.2137451	0.01
469.5932617	0.04
473.0398560	0.10
474.1749268	0.03
479.0413818	20.58
481.0711060	0.02
482.5080566	0.01
483.1248779	0.01
486.0310669	0.03
487.0955200	0.21
493.0646973	0.12
503.1643677	0.10
505.0500488	0.18
522.9861450	0.06
529.6947632	0.02
533.4535522	0.01
535.4155884	0.32
541.0962524	0.09
543.3449097	0.03
544.1452026	0.10
545.9965820	0.03
548.1127319	0.02
551.2683716	0.06
555.1953735	0.05
559.1519165	0.03
561.5622559	0.02
563.2285156	0.03
564.4703979	0.03
571.0845337	0.30
576.0715942	0.03
577.1441040	0.03
578.2359009	0.17
579.2067261	0.18
580.0648193	0.02
581.2981567	0.04
583.6659546	0.03
586.0480347	0.07
589.2132568	0.39
590.3494263	0.08
591.6569214	0.03
592.3167114	0.03
593.4010620	0.05
604.8171387	0.13
606.4295044	0.41
607.3576050	0.84
608.5093384	0.09
609.1766357	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0764
Annotation	Glutathione
Peak:m/z	Relative Intensity
88.7580719	0.06
98.8962402	0.25
100.1088028	0.06
110.9570465	0.16
115.9944458	0.09
120.0673141	0.15
125.0586472	0.12
126.0231323	0.06
127.3841400	0.69
128.0939636	9.43
130.2091370	0.03
132.0839386	0.05
143.0913696	9.03
144.0050659	0.16
145.2080078	0.51
146.1060638	0.97
153.1572876	0.14
160.0439758	10.49
166.0702515	0.21
167.0051880	0.80
169.1329498	0.18
169.9790649	0.17
171.0734253	1.04
177.0766602	7.97
179.0780945	11.03
183.4400482	0.04
184.5344238	0.29
185.1822510	1.10
190.0235901	0.12
191.0932922	0.03
192.0714111	0.11
197.1246643	1.78
202.0222168	0.08
210.1789246	5.25
210.8894958	0.03
213.1121826	1.97
216.1396484	0.03
218.0843201	0.29
218.9503174	0.04
224.2533875	0.08
228.3038940	0.83
231.0936890	0.99
236.2015991	0.87
242.1985779	1.36
243.2755432	0.03
244.2394409	0.09
252.0773315	0.03
254.1313477	92.72
254.9262390	0.02
260.2213135	0.09
261.4224548	0.04
262.4819031	0.08
268.9431763	0.14
272.2207947	100.00
273.0715332	0.05
288.1599426	66.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0882
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
163.1011047	0.01
190.7914581	0.01
206.8468323	0.03
219.2256165	0.01
225.1242371	0.01
243.3957977	0.03
249.2917938	0.01
270.3080444	0.03
274.9470215	0.01
294.2485962	0.01
297.2416992	0.01
307.4119263	0.01
311.1932373	0.04
312.1020508	0.06
313.2743530	0.04
325.1320190	0.02
326.2784424	0.01
327.1234741	0.05
341.1726685	0.02
343.0767822	0.04
351.3339233	0.02
355.1646118	0.01
359.3515015	0.04
369.3267822	0.03
370.2791748	0.02
371.2958984	0.02
385.3464966	0.01
386.0987549	0.01
387.3959351	0.07
419.4006348	0.02
431.5433960	0.02
440.1781616	0.01
461.2356567	0.01
463.2655640	0.34
469.0964966	0.01
473.0849609	0.02
486.1768799	0.01
487.6403809	0.01
489.2284546	0.01
491.5321045	0.02
501.5818481	0.02
503.2977905	0.83
505.2107544	100.00
505.8556519	0.14
507.2953491	0.03
519.4116211	0.03
520.8661499	0.01
524.4017944	0.02
528.5550537	0.02
531.3639526	0.12
534.2449341	0.01
540.1447144	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1199
Annotation	Castamollissin
Peak:m/z	Relative Intensity
145.0959473	0.10
147.0963440	0.08
149.9610596	0.02
152.1844788	0.07
160.9970093	0.12
162.9776917	0.11
165.1733246	0.16
165.9085236	0.08
177.0846710	0.07
181.2919006	0.02
189.1997986	0.04
191.0696411	0.14
192.1174774	0.09
193.0162048	0.12
196.9908142	0.08
203.2916260	0.11
215.0771484	0.02
217.2589569	0.26
218.1409760	0.08
219.3019104	0.05
220.0897522	0.02
227.0463867	0.02
229.1085968	0.06
229.9964142	0.07
231.1417236	0.07
232.1330566	0.04
234.3484192	0.08
239.3844910	0.12
240.1099854	0.07
241.0500183	0.02
252.2797852	0.07
255.2631531	0.17
256.2572632	0.10
257.3646851	0.03
258.2964478	0.09
259.2494202	0.26
261.1675720	0.07
263.2843323	0.10
268.3140564	0.06
270.1607971	1.29
271.2612305	0.08
272.2169800	0.10
273.3405457	0.05
274.9899597	0.15
277.4976501	0.16
279.5152588	0.23
284.0686646	0.17
285.1658325	1.58
286.0848999	0.08
287.2766113	0.89
288.0830383	0.14
289.1737671	0.09
290.2487793	0.05
291.1317139	0.07
297.2306519	0.35
298.2202759	0.06
299.1348267	0.51
301.2099609	0.23
302.0902100	0.21
303.3129883	0.26
305.2977600	0.07
309.2857666	0.03
310.3136902	0.03
311.2971497	0.30
312.6195374	0.23
313.3072205	0.95
314.1846924	0.92
315.3130493	0.37
316.1002502	0.21
317.4832764	0.07
321.3018188	0.17
323.3380432	0.08
324.1120605	0.05
325.5466309	0.04
327.2279968	8.21
328.1821594	35.53
329.1780396	100.00
330.2399292	2.35
331.1753845	11.55
333.4651489	0.03
337.2044678	0.05
338.4496460	0.04
339.2289734	0.35
341.1805115	1.00
341.8565979	0.04
343.1997986	9.68
343.8033447	0.15
345.0945129	0.29
346.2572632	0.06
347.2417908	0.45
351.1148071	0.07
353.3234253	0.74
354.0875549	0.07
355.3582764	0.12
357.3361206	0.39
369.1846313	0.35
370.6207275	0.62
371.3031006	5.10
373.2391357	0.12
381.0848389	0.04
383.2427673	2.16
384.2612000	0.08
385.0827637	0.06
386.3315125	0.05
387.3592224	0.12
395.2815247	0.39
399.4169312	0.09
401.2550354	4.29
403.4082947	0.04
409.5703125	0.02
413.2664490	1.00
414.2337341	0.05
423.2135925	0.09
425.2798767	0.36
429.4556580	0.15
431.3050842	0.07
431.9881897	0.07
437.2710876	0.20
445.4274597	0.27
447.2401123	0.06
455.5644226	0.04
459.2547302	2.34
460.3030701	0.04
463.1415710	0.12
473.3386536	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.1984
Annotation	Sambubiose
Peak:m/z	Relative Intensity
205.0671387	0.20
206.3178253	0.11
207.1737061	0.28
221.4487915	0.30
237.0873871	0.13
305.5933838	0.15
306.2396851	0.25
307.8220825	0.27
309.1167603	0.46
325.1068115	0.08
327.9697876	0.08
339.1652832	0.15
344.2544556	0.06
362.9968262	0.05
364.5765991	0.05
369.3040161	0.11
381.2185669	0.13
382.6686401	0.07
385.0980835	0.07
387.2316895	0.19
397.0922241	0.14
400.0479736	0.05
403.1779175	0.14
408.0484619	0.09
414.9219360	0.12
427.3104248	0.12
428.9904175	0.05
430.9954834	0.12
442.9334106	1.10
444.2201538	0.22
457.1289673	0.16
459.0751343	0.51
468.4025269	0.13
475.0947266	2.88
477.0927124	0.82
480.0963745	0.11
487.2209473	0.32
488.4693604	0.05
494.2841187	0.36
500.5775757	0.23
503.0352783	0.30
511.3790283	0.11
517.5337524	0.15
522.0416870	0.08
530.6184692	0.15
533.1361694	0.06
534.2817993	0.07
544.7053833	0.69
546.9810791	0.33
553.4105835	0.09
567.2575073	0.07
573.5183105	0.13
578.2084961	0.18
589.2423706	0.15
591.0670166	0.35
596.4697876	0.10
605.3128662	100.00
605.9392700	0.35
631.6693726	0.11
633.1428833	1.36
633.8177490	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9714
Annotation	Unknow
Peak:m/z	Relative Intensity
185.0309143	0.01
186.3572998	0.02
202.0729370	0.07
212.2416077	0.01
244.9845581	0.01
257.7427673	0.01
271.1854553	0.02
275.1567078	0.03
285.7391357	0.02
303.2429199	0.04
303.9552612	0.12
307.7594910	0.02
314.2813416	0.01
316.1510315	0.05
329.0132446	0.01
330.0213623	0.20
331.2875977	0.04
332.0960693	0.18
334.1477661	0.19
335.1263733	0.02
338.9808350	0.02
346.1991577	0.03
347.9667969	1.14
348.5721130	0.03
349.3473511	0.01
357.9497986	0.11
373.3821411	0.02
376.1929016	0.10
379.2830200	0.01
391.5930786	0.10
394.0339661	100.00
395.8983459	0.02
401.3731995	0.09
402.1379700	0.10
405.0893555	0.01
414.8694153	0.04
419.0796204	0.61
420.1040955	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0329
Annotation	Unknow
Peak:m/z	Relative Intensity
78.8915863	6.65
96.9269104	100.00
148.9285889	0.15
155.1095734	0.11
187.1144562	0.08
193.0890198	0.03
205.1140442	0.06
217.1021423	0.12
229.0947571	0.07
233.1026001	0.11
238.5563660	0.04
239.2086792	0.21
259.1153259	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1718
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
172.8761902	0.44
191.0347443	100.00
192.8728333	0.22
204.9746857	0.03
221.0477905	0.21
235.2528687	0.38
237.1640930	3.49
251.2322540	0.16
295.1855469	3.82
305.1494751	0.05
323.1839600	0.47
341.2141724	0.06
353.3484497	0.42
370.1509399	0.05
395.0216064	0.06
399.4102173	0.12
402.1392212	0.08
413.3933105	0.05
416.9839478	0.19
425.3353882	0.08
443.5153198	0.06
444.8743896	0.10
447.3306274	0.20
465.3694458	0.16
487.1848755	0.09
489.1516113	0.04
514.2444458	0.15
515.2541504	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.13
Annotation	4'-Methyl-(-)-epigallocatechin 7-glucuronide
Peak:m/z	Relative Intensity
166.9818878	0.56
176.9599915	0.14
180.8123627	0.17
193.6760864	0.24
195.0320129	0.12
209.0068359	6.86
241.4573669	0.10
252.9361267	0.47
291.0928955	0.18
306.8035583	0.36
317.2597351	1.88
331.1720581	17.94
332.1712341	63.41
333.1894226	67.00
334.1701965	100.00
335.1807251	77.54
377.7029724	0.08
400.8996277	0.67
408.0154114	0.36
443.0227661	0.31
451.1750793	0.82
451.7910156	0.17
460.9599304	0.82
465.4175720	0.49
468.8715210	0.62
475.5957336	0.56
479.1709900	6.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1662
Annotation	6-Feruloylcatalpol
Peak:m/z	Relative Intensity
152.9935303	0.35
158.1851501	0.04
160.8159943	0.05
164.1073608	0.06
177.4139709	0.16
179.0335693	0.04
190.1820068	0.16
191.1426392	0.13
193.2056427	0.09
195.0612488	0.06
204.9773560	1.68
208.0096588	0.04
216.9073486	0.09
219.1535492	0.10
221.2336578	0.10
223.1884460	1.19
232.0577240	0.19
236.2529602	0.17
247.0506287	0.15
251.2279358	0.15
261.3748169	0.06
263.1769409	0.51
265.1276245	0.14
271.9766541	0.23
277.4309082	0.12
281.1837769	0.11
297.3659058	0.20
307.0160522	0.21
308.1934814	0.22
313.2354736	0.22
315.1841431	1.04
316.1888428	1.77
317.3170776	0.95
322.9802246	0.07
330.0268555	0.13
337.2929077	0.09
341.3059082	0.12
343.1601562	0.04
345.1567383	0.40
345.9905396	0.04
349.4617920	0.11
353.3303833	1.07
355.1658325	0.13
357.4010010	0.39
358.2813110	0.45
359.4250488	2.05
363.3288574	0.05
367.2085571	100.00
370.9774780	0.06
372.3746338	0.06
381.3712769	0.16
387.2534790	0.17
391.4364014	0.12
397.2781982	0.11
398.2269287	0.09
399.1803589	0.03
403.0623169	0.23
414.4617310	0.08
415.3065186	0.14
425.1724243	0.27
435.4884033	0.27
441.3027344	0.18
448.1992188	0.05
450.7525635	0.05
457.8306274	0.03
459.0187988	0.30
461.0523071	0.23
475.3508911	0.23
477.0321655	0.24
479.2510376	0.12
483.0516968	0.07
491.6548462	0.17
492.4318237	0.05
493.4121704	0.07
494.1312866	0.04
500.2655029	0.17
503.2780762	0.49
506.4627686	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.24
Annotation	Milolide H
Peak:m/z	Relative Intensity
178.9143982	0.10
181.0810394	0.12
187.2488098	0.05
191.3901367	0.12
193.0358582	0.07
194.0893555	0.04
195.3442688	0.13
196.0255280	0.17
197.1437836	0.10
199.3012390	0.09
204.9672546	0.12
209.2604828	0.47
211.0681000	0.80
213.1104126	0.12
222.9696503	0.09
249.8943176	0.16
255.5102692	0.14
265.3303223	0.08
292.3550110	0.22
307.2084351	0.04
309.4980774	0.03
311.1613464	0.07
327.6193237	0.06
333.4996338	0.04
339.2816162	0.13
342.2755737	3.34
343.3895874	0.24
346.1658325	0.16
350.3427124	0.04
353.0631104	0.25
357.3454590	100.00
363.4500732	0.07
367.9656372	0.14
371.3524780	4.66
384.4307251	0.04
387.2490845	0.58
389.5738525	0.10
397.4848022	0.15
404.2920532	0.25
405.3485718	0.08
410.2647705	0.11
415.4474487	0.10
419.4890137	0.14
421.0493774	0.18
433.2962036	0.05
434.2836304	0.20
435.3676147	0.58
436.2647705	0.36
439.1278076	0.03
449.1553955	0.03
450.3229370	0.23
460.1627808	0.11
471.3124390	0.23
475.1314697	0.08
478.0926514	0.04
481.3344116	0.51
483.1792603	0.10
493.4107056	0.05
495.2424316	0.18
513.2492065	0.04
519.4227905	0.93
520.4827271	0.79
521.5429077	0.18
522.2752686	0.35
523.3124390	0.35
528.4769897	0.08
529.4581909	0.08
530.7388916	0.37
531.3817749	0.13
535.6893311	0.14
537.3526001	0.11
549.3037720	0.34
553.4000854	0.06
567.0123901	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	481.0985
Annotation	Castamollissin
Peak:m/z	Relative Intensity
145.2472534	0.06
146.8917694	1.02
148.9399414	0.07
151.9967346	0.02
158.0578156	0.02
165.1911011	0.08
166.9742432	0.11
169.0389252	0.02
174.9756317	15.07
185.0699463	0.06
189.1751099	0.03
191.1152649	0.07
192.2490540	0.13
192.9886780	0.50
195.0742798	0.03
203.2627563	0.03
205.1863708	0.04
207.2585144	0.09
213.1016541	0.35
213.8347473	0.09
215.1512146	2.12
229.0905762	0.05
230.9224701	0.04
233.1974182	0.32
234.6253967	0.01
239.1723633	1.02
242.9337921	0.01
249.0582581	0.04
255.1234131	0.04
257.1048889	8.77
258.0375977	0.24
259.2367554	0.52
265.0046387	0.12
269.2155151	0.02
270.8986816	0.01
273.1560974	0.61
274.0437317	0.02
275.1033630	0.15
283.1180115	3.02
291.4067383	0.09
301.1189880	100.00
301.9263306	0.02
313.1616211	0.25
319.1279297	3.27
327.0352783	0.05
329.1985474	6.10
343.4577026	0.03
353.1416931	0.06
355.1710510	34.04
357.2120056	0.14
359.4917603	0.04
371.2348022	0.04
395.2544250	0.06
397.2373047	0.12
413.2081604	1.08
420.2692566	0.03
437.3495178	1.04
439.3160706	0.09
463.2957458	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	320.9438
Annotation	Unknow
Peak:m/z	Relative Intensity
111.8889618	0.44
122.8956223	0.67
130.1868744	0.21
145.0493469	0.44
146.9076843	0.35
148.9743042	0.18
156.9024048	0.39
200.9548492	2.16
207.1030273	0.51
211.1799622	0.55
214.9370422	0.59
215.8830566	0.54
223.9170532	0.25
230.8609009	8.50
236.8352051	0.39
257.9118042	0.46
261.0488892	100.00
274.2051392	0.32
275.0332336	2.28
280.1099854	5.91
284.9089661	1.08
285.9655151	0.51
290.2568970	0.56
291.4060669	1.04
302.2466431	5.09
303.2312622	16.39
304.1362305	0.63
312.1152649	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.2139
Annotation	15-Acetoxyscirpene-3,4-diol 4-O-a-D-glucopyranoside
Peak:m/z	Relative Intensity
148.8902435	0.15
152.9501953	0.12
154.0067749	0.26
160.1598816	0.09
163.1293793	0.06
167.0413361	0.47
174.9660034	0.17
181.1066742	0.11
193.1080627	0.10
198.2787476	0.17
203.1184998	3.38
205.4653168	0.13
209.1604156	0.10
213.1512604	0.07
215.2385254	0.36
219.2183990	0.19
235.0787659	0.09
245.0681610	0.83
246.1127472	0.10
247.3038330	0.25
252.3739929	0.31
253.0774536	0.08
259.0679016	0.51
261.0290527	0.16
264.1847534	0.54
265.1566162	1.30
266.2820129	0.06
268.9461670	0.25
275.2522278	6.91
276.0895996	0.80
277.1394653	0.13
283.3316345	0.10
310.8287048	0.17
317.3133240	2.84
322.1984863	0.34
325.1536865	1.13
327.2294922	0.19
330.2103271	0.12
333.1442261	0.22
335.1822205	89.26
336.1629944	5.20
337.4104004	0.08
341.5629578	0.20
343.2067871	0.24
353.3560791	0.33
355.2647095	100.00
356.3639526	13.92
358.9181824	0.08
367.3416748	0.63
371.3283997	0.14
379.6700134	0.11
380.8168030	0.13
384.7116394	0.12
385.7087097	0.24
397.3067627	0.88
401.0562439	0.21
403.4210815	0.22
405.8121643	0.25
409.6291504	0.09
412.2878113	0.43
415.4129028	0.34
419.5850830	0.26
421.1706238	0.38
426.2192383	0.14
427.2970276	0.23
428.4786682	0.87
431.9839172	0.21
440.9383545	1.09
441.5865784	0.47
443.5816040	0.10
446.1091003	0.39
450.7564392	0.51
451.4603882	0.35
457.0151672	0.19
459.0138855	1.03
467.3246155	0.30
468.3789978	0.57
469.3610535	4.93
470.3359985	0.11
478.2137756	0.65
478.9878845	0.43
486.1081238	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2911
Annotation	Taxusabietane E
Peak:m/z	Relative Intensity
207.3869171	0.05
209.1771851	0.47
224.0655212	0.08
247.1463318	0.03
248.3647156	0.06
289.0451965	0.11
295.5862732	0.09
298.8508301	0.10
308.5099792	0.07
311.1400452	0.09
313.2045898	100.00
315.2963867	0.08
327.2114563	0.71
328.2749634	0.12
329.2495422	0.10
339.1451416	0.21
343.2728271	1.66
346.2553711	0.12
357.4162598	0.21
359.2737427	0.09
367.3619385	2.29
372.1350098	0.09
399.3071289	0.06
400.0825806	0.13
405.7537842	0.13
413.3906250	0.10
414.2093506	0.15
415.9489136	0.06
424.1511230	0.08
431.5090332	0.33
445.3095093	0.10
456.5317993	0.05
461.3743286	0.09
477.6232910	0.10
491.5895996	0.09
492.3171997	0.06
495.5238037	0.11
503.5321045	0.49
505.3891602	3.77
508.3983154	0.13
515.3869019	0.11
518.3337402	0.10
519.4496460	0.05
520.1275635	0.03
521.2630005	0.82
528.1701050	0.42
531.3313599	0.06
535.3864136	0.22
536.0564575	0.03
537.3696899	0.04
539.2475586	1.76
539.9539795	0.07
544.5715332	0.09
550.9910889	0.07
551.9241333	0.52
553.3641357	0.25
556.1802368	0.52
557.5808716	0.07
564.2335815	0.10
565.2130737	0.05
571.6796265	0.03
575.5961914	0.10
576.5736694	0.08
583.2203979	0.53
587.2374878	0.44
589.3901367	0.13
599.1212158	0.04
603.3918457	0.16
612.3937988	0.11
613.3398438	0.06
621.7465210	0.54
623.3389282	0.10
627.4619751	0.05
628.0881958	0.06
629.4318237	0.15
633.4915161	0.10
634.4929810	0.19
637.5765381	0.46
638.6160889	0.18
642.6406250	0.33
651.6052246	0.14
654.5792236	0.06
656.0926514	0.04
657.4163818	0.19
659.2244873	0.21
661.5979004	0.09
662.3143921	0.22
669.2934570	0.40
670.4678345	1.00
671.4414673	0.29
673.1613159	0.56
674.4365234	1.11
675.6339722	0.03
680.4735718	0.85
681.4797974	0.11
682.7770386	0.26
688.9635620	0.12
694.3274536	0.08
700.4306030	0.50
701.4219360	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.12
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0714417	0.26
177.1197052	0.20
179.3545380	0.26
180.1421661	0.03
189.0981598	0.17
190.9772644	0.49
193.0106506	0.16
201.9288788	0.13
202.9544983	0.17
205.1573486	0.18
206.0367737	0.09
216.9688110	0.09
220.1760712	0.06
227.1847229	0.06
230.1913757	0.11
233.0377045	0.06
233.9525452	0.04
235.5357208	0.14
236.9559937	0.14
241.3635559	0.29
242.4010925	0.05
243.2025146	0.10
249.1829224	0.39
251.0386353	0.24
253.2297821	0.12
256.0934448	0.07
258.1637268	0.37
262.8913574	0.08
265.0864258	0.06
269.1732178	0.55
270.1643372	0.44
271.1877441	0.38
273.0903931	1.09
274.2120667	0.06
275.0137329	0.04
276.1862793	0.08
278.9571228	0.12
284.1883545	0.30
285.3246460	0.18
287.2012634	0.49
289.1079102	0.23
292.1407471	0.08
299.2196045	0.21
300.1871033	0.56
301.0942078	1.72
302.1742554	0.30
303.1022339	0.10
305.5262451	0.08
307.2392883	0.23
310.0243530	0.10
311.1817627	0.46
312.1547852	0.53
313.0518799	0.22
315.1405029	1.40
316.4983521	1.41
317.2565308	2.87
319.1912842	0.12
323.2976074	0.65
327.2353516	0.11
329.1412354	7.98
330.2225342	7.41
331.1211548	0.58
334.2135010	0.11
335.3421021	0.17
337.2539673	0.35
339.0267334	0.05
340.8922119	0.07
343.2561646	10.41
344.1505737	64.26
345.1797485	100.00
346.5037842	0.06
352.3803711	0.06
353.1340942	0.16
354.9938354	0.17
357.3158569	0.54
358.3087158	0.25
359.2776489	0.75
363.1758423	0.08
367.1921387	1.01
368.2481079	0.44
369.1944580	0.58
369.9053955	0.44
372.2373047	0.53
373.4064941	0.09
374.2120972	0.25
379.0213623	0.09
381.3152466	0.10
383.1497803	0.37
384.1447144	0.54
385.3363647	0.92
386.2577515	0.86
387.3341064	2.96
388.0584717	0.05
394.6381836	0.38
395.3548584	0.29
397.4563599	0.06
398.2266235	0.07
399.3341064	0.88
400.3014526	0.22
401.2852783	0.15
403.2775269	0.28
407.4749146	0.03
409.3303833	0.09
411.0854492	0.82
413.5283813	0.14
414.1551514	0.06
415.3837280	0.76
417.1144409	0.34
419.7207642	0.10
422.4773560	0.22
426.2489014	0.17
429.3983765	0.38
435.2377319	0.10
438.2012329	0.22
439.4522095	0.44
440.3037109	0.26
441.4226074	0.03
445.6592407	0.42
449.3671265	0.14
451.5963135	0.74
452.4125366	0.22
453.2675171	0.46
456.7238770	0.19
457.4422607	0.38
458.6994019	0.10
459.5180664	0.15
461.2309570	0.23
462.8922729	0.10
465.4197998	0.07
468.4609375	0.07
471.3073120	0.21
472.2000732	0.07
473.3772583	0.66
474.3720093	0.37
475.4780273	0.04
477.0427246	0.19
479.1881104	0.16
481.0047607	0.09
487.7858887	0.06
489.2515259	12.22
490.2643433	0.18
494.3153687	0.19
495.1591187	0.15
497.0784912	0.05
500.5319214	0.12
501.4559937	2.79
502.4406128	1.81
503.4343872	2.79
505.2902222	3.61
507.2120361	30.85
508.1499634	0.50
517.2703247	2.70
518.2180786	0.12
520.2171021	0.07
521.2976685	0.36
529.2017212	1.97
530.3178101	1.26
531.3391113	1.38
534.2520142	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.1089
Annotation	Unknow
Peak:m/z	Relative Intensity
151.0489044	0.18
162.9535217	0.08
169.2702332	0.07
173.2090454	0.06
178.9894409	1.12
188.9776306	0.11
190.1324158	0.04
190.9380035	0.24
193.1648407	0.17
197.2995911	0.11
203.0616150	0.14
207.2280579	0.07
209.1246033	0.10
215.2879028	0.08
216.8686829	0.04
219.1977081	0.10
220.0051575	0.83
220.9871216	0.23
225.0681152	0.04
226.8542175	0.06
233.1354065	0.14
241.3143005	0.32
242.1746216	0.13
243.2088318	0.24
244.2978058	0.06
246.2592163	0.05
247.1936646	0.12
249.1614532	0.05
251.1179962	0.04
253.3346710	0.04
256.4574585	0.20
257.1629333	0.06
259.1195679	0.22
262.1553345	0.06
267.0812378	0.04
269.0390625	0.18
270.4749146	0.32
271.2749023	0.87
272.2328491	0.09
273.4830933	0.11
277.4085693	0.25
281.0366821	0.10
282.5422668	0.07
285.1357727	0.42
286.2042236	0.09
287.1154175	1.07
289.3413086	0.08
296.0000610	0.08
301.1239014	1.66
303.1491089	1.16
305.2505493	0.07
308.2139893	0.05
309.1353149	0.10
312.0498047	0.04
313.2713623	0.80
315.1889648	7.75
316.1417236	3.18
321.1616211	0.08
323.1626587	0.28
327.2166138	0.21
328.2734985	0.34
330.0973511	100.00
331.1311646	71.83
331.7706909	0.18
332.3843384	0.12
335.3331299	0.08
341.0972290	0.99
342.0859375	0.09
343.1493530	1.19
345.1486816	0.23
353.0281982	0.28
355.3930054	0.40
356.4036255	0.06
357.3641357	0.19
358.2521973	0.04
361.5206909	0.12
367.0855103	1.14
368.1668701	0.06
369.4071655	0.79
371.3330688	0.27
373.1452026	3.98
374.3471069	0.13
376.4251099	0.06
385.5164795	0.04
386.4118652	0.05
387.4389648	0.32
389.2338257	0.15
395.3206177	0.13
403.1716919	0.19
404.1495361	0.09
409.4212646	0.39
411.1430054	0.06
411.9116211	0.04
414.3006592	0.21
415.3664551	0.06
425.3456421	0.11
431.3250122	0.11
438.5504761	0.07
443.5322876	0.09
457.1926880	0.32
458.5185547	0.14
466.4547729	0.24
472.3077393	0.05
473.2442017	0.08
475.3011475	1.37
477.8154297	0.09
486.0916138	0.14
488.6899414	0.20
489.4003906	0.20
490.7111206	0.16
491.3775635	0.29
493.2584839	32.63
503.1942749	2.70
504.3644409	0.15
505.2093506	0.21
515.2626343	0.06
517.3129272	1.52
519.6610107	0.62
520.3066406	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2287
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
149.1043701	0.05
151.1775208	0.03
251.9324951	0.01
257.1275330	0.02
261.1726379	0.02
302.9343872	0.03
304.1799011	0.04
311.0686035	0.05
313.3139648	0.42
314.7714233	0.13
315.4052124	0.08
316.2308655	0.05
317.5353394	0.02
325.4148865	0.05
327.1847229	0.01
330.1429138	0.05
331.1439514	0.24
343.0948486	0.04
357.3416138	0.03
416.2234802	0.01
431.4429626	0.09
434.2150269	0.01
442.4921570	0.06
447.3094482	100.00
447.9261780	0.39
449.2452087	0.06
452.7048340	0.04
462.6414490	0.02
474.3882446	0.03
476.6275940	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1827
Annotation	Scopolin
Peak:m/z	Relative Intensity
212.2335815	0.16
212.9967194	0.15
215.3855896	0.18
219.1032867	0.96
225.2092590	0.13
225.9147339	0.06
228.9391174	0.31
230.9355774	0.40
232.2366028	0.92
233.2685699	0.27
237.2791290	0.42
239.3256836	0.13
241.1083527	0.23
242.1222534	0.46
243.1159668	3.67
244.0438538	0.43
250.5973511	0.21
253.2476196	0.37
255.0737000	2.32
256.0298157	0.40
262.1655579	0.07
264.2204590	0.22
264.9743042	0.13
267.2953796	0.09
271.2608032	2.67
272.2541809	0.69
277.1323242	0.17
278.2020264	0.05
279.2036743	1.35
280.1761780	0.24
281.1991882	2.22
282.3445740	0.28
285.0840149	0.07
289.1805420	1.95
290.2225952	0.27
294.1698914	0.20
295.2760315	0.27
296.1481934	0.25
297.2565918	5.98
298.2223816	0.77
301.2250977	0.07
305.2647705	0.73
306.3240356	0.40
309.3679810	0.15
315.1980591	0.80
316.0780640	0.12
321.4027710	0.40
322.1025391	0.31
323.1766968	36.50
324.1977844	5.77
335.1469727	1.24
336.3082275	0.21
341.1440430	12.18
342.2289734	2.82
353.1373291	100.00
354.2283325	12.87
355.1674194	0.13
359.2433472	2.77
360.2451172	0.31
361.5709229	0.20
365.4540405	0.08
375.1170654	0.24
379.2231445	0.44
380.5584717	0.20
393.1893921	3.64
394.0613403	1.79
404.9643555	0.08
409.1519165	0.22
445.2581177	0.21
445.8724976	0.25
451.5257568	0.07
454.6121216	0.31
459.3392334	0.12
463.3025513	18.59
464.2509155	3.43
465.7002563	0.11
471.5252686	0.60
472.5427246	0.28
489.2831421	4.68
490.2356567	0.69
497.3309326	1.15
509.3003540	0.33
513.3546753	0.27
515.2149048	51.02
516.3002930	14.60
517.3288574	0.55
518.0731201	0.22
519.3835449	0.20
523.5641479	0.08
527.1862183	0.18
533.2763672	28.20
534.2971802	6.59
539.1951904	0.12
545.0736694	0.12
546.2182617	0.75
554.2058716	0.19
557.2947998	0.35
566.9823608	0.07
576.5371704	0.30
597.3144531	0.24
601.2506714	0.18
604.3622437	0.15
613.3723755	0.19
620.9077759	0.07
626.7393799	0.36
634.1599731	0.08
635.2885742	0.14
662.4068604	0.22
663.1002808	0.42
671.1851807	0.16
679.9317017	0.20
689.3146362	8.35
690.3789673	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.0615
Annotation	Amaronol B
Peak:m/z	Relative Intensity
95.0413666	0.04
96.9171524	0.04
108.0751648	0.07
109.0758591	0.04
113.2543793	0.03
120.8748398	0.27
123.0209579	0.33
137.0153351	2.84
138.3857727	0.02
139.1446228	0.20
152.0391541	0.49
152.7937012	0.11
158.8267670	0.07
165.0029602	100.00
167.1000366	10.27
171.1048584	0.06
175.0050507	0.03
178.9129028	0.02
183.0897064	9.43
196.2070923	0.02
207.0167236	0.22
209.3173523	0.04
211.3029175	0.02
217.1367493	0.03
243.2889404	0.02
245.0812988	0.03
247.3375854	0.07
261.1636047	0.08
263.0480347	0.03
269.2342224	0.06
271.4729004	0.05
273.3338928	0.08
274.2385559	0.03
275.1357422	0.07
287.1206665	1.25
289.1867676	6.98
300.3192749	0.07
301.3022461	0.68
302.3892212	0.32
303.0418701	0.13
305.2538757	0.15
314.3161011	0.15
315.3003540	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.09
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
68.7697144	0.01
75.0389633	0.01
119.9390259	100.00
120.7803192	0.00
122.8041687	0.01
130.9994354	0.33
138.0347443	0.06
146.8501129	0.01
147.9020538	1.08
148.9461060	4.43
150.9593353	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1333
Annotation	5'-O-beta-D-Glucosylpyridoxine
Peak:m/z	Relative Intensity
95.9978027	0.03
106.1164551	0.10
107.9961777	1.84
113.0810318	0.02
115.0487442	0.02
118.0318527	0.01
121.7802734	0.03
123.1031265	0.05
123.9426193	0.20
134.0239716	0.69
135.9418488	1.51
148.0732269	0.05
151.9629517	5.81
153.1382141	0.04
154.0996399	0.24
156.9531250	0.05
164.0268250	0.04
170.0126038	7.40
170.6154785	0.04
175.1514587	0.09
176.1252747	0.07
179.1290741	0.02
187.9774017	0.03
190.8397369	0.02
194.1823730	0.06
211.3306274	0.05
212.1820068	0.02
215.1084900	0.02
226.4732971	0.04
227.3723145	0.02
232.3777466	0.01
236.9662170	0.02
241.4415894	0.11
242.1678772	0.63
244.2926941	0.01
249.0440063	0.08
250.3600769	0.05
251.2523499	0.01
251.9544678	0.04
253.9171448	0.01
256.0847168	0.10
259.1437378	0.06
265.5885925	0.03
268.1943054	0.11
278.2335510	0.10
284.1807251	0.01
285.1751709	0.03
286.2385864	0.03
287.0726929	0.03
288.2054443	0.02
291.1324463	0.20
296.2194214	0.33
298.9444580	0.01
302.2892761	0.12
303.0133972	0.01
308.0451050	0.01
314.1799927	100.00
315.2624512	0.13
323.0546875	0.28
332.1233215	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0829
Annotation	N-Malonyltryptophan
Peak:m/z	Relative Intensity
87.9070129	4.07
96.6644287	0.09
109.1404572	0.11
109.9835434	0.57
114.0337524	2.65
114.9868774	7.62
130.0093689	7.86
132.0318604	93.39
143.1207275	0.16
151.0980225	0.51
156.1978760	3.58
159.0581665	0.09
167.1464844	0.48
169.1510925	0.11
170.9438171	0.17
173.0327148	27.58
174.0581512	100.00
176.9164581	0.21
179.3141785	0.20
183.1219635	0.09
187.1090393	0.52
198.9385376	0.09
201.2258911	0.07
205.2020264	0.30
205.9752197	0.26
207.0906372	0.12
211.0481567	0.16
217.2079773	0.10
227.1933594	1.25
227.9875183	0.12
229.2349243	0.10
231.0754089	0.22
239.3961182	0.10
243.1243286	0.13
245.1739197	41.66
247.1042786	0.34
251.9887085	0.17
261.1038818	0.67
271.1882324	21.99
274.2122192	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	751.1312
Annotation	Unknow
Peak:m/z	Relative Intensity
247.3440247	0.13
261.2525635	0.17
263.1999512	0.06
271.0693359	0.14
278.7669373	0.19
287.1520691	0.18
288.9818420	0.32
307.3991089	0.14
313.1027222	0.16
315.3513794	0.06
329.2242432	0.16
337.3849792	0.04
345.0792847	0.33
391.3039551	0.05
397.3317261	0.04
398.3114624	0.11
402.1939697	0.09
407.2559204	0.10
409.5291138	0.13
410.2182617	0.16
421.1647339	0.08
423.2758179	1.40
424.3821411	0.18
425.6760254	0.11
429.2672729	0.30
435.2495117	0.12
439.2389526	0.37
447.2413940	0.26
449.5366821	0.16
453.3116455	0.20
465.3962402	0.41
467.1240234	0.18
484.2799683	0.13
491.2872314	0.05
495.2351685	0.09
498.8183594	0.05
507.2426147	0.21
558.6950684	0.04
560.1595459	0.24
561.3461304	0.35
562.1189575	0.17
572.1906738	0.06
573.3006592	0.87
579.0393677	0.06
583.1501465	0.06
585.1697388	0.64
589.0088501	0.14
591.2523804	100.00
591.9271851	0.25
599.7235718	0.19
601.1159058	0.32
603.4278564	0.24
617.7081909	0.05
620.6561890	1.45
621.3587036	23.10
627.1229858	0.09
652.3349609	0.14
656.5938110	0.45
668.5968628	0.08
677.4015503	0.07
691.4593506	0.09
708.5559082	0.21
713.5587769	0.23
717.4024048	0.17
734.6024780	0.20
735.2182617	0.34
753.5859375	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.3329
Annotation	Unknow
Peak:m/z	Relative Intensity
219.3213196	0.13
226.3678131	0.07
260.3373718	0.04
283.2204590	0.11
347.1296997	0.54
374.4071655	0.08
393.1339722	0.36
398.9670410	0.07
521.1471558	100.00
521.8524170	0.44
549.6122437	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.21
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0094757	0.08
148.0613556	0.11
148.9512177	0.87
151.0760498	0.44
152.1277618	0.07
160.1032410	0.12
160.8894348	0.08
163.9030609	0.03
164.9471283	0.02
166.1771851	0.05
167.2482300	0.18
168.9319458	0.10
173.0496216	0.05
174.1075439	0.05
174.9648132	0.28
176.2454681	0.16
177.1110535	0.25
179.0512238	1.56
179.9053040	0.86
186.2529602	0.05
188.3544159	0.06
189.0864563	0.16
190.0814819	0.06
191.2583618	0.37
191.9254456	0.05
193.1043396	0.03
194.0285950	0.18
197.1556702	0.09
200.3268890	0.06
205.1442566	0.17
207.2817993	0.03
208.1394196	0.11
209.0271606	0.21
213.1983948	0.03
214.2736816	0.17
215.0323792	0.03
216.2717133	0.05
217.2238770	0.19
220.4191284	0.14
223.0752869	0.22
228.3540192	0.13
229.2501984	0.11
231.0888824	0.07
231.9510498	0.24
233.2237549	0.53
234.0368347	0.12
235.3529053	0.04
238.8145752	0.04
243.0410004	0.09
244.2188873	0.19
245.2609406	0.19
246.0135498	0.05
248.3008118	0.06
249.4128723	0.33
251.2966614	0.08
254.2275391	0.34
255.2037964	0.90
256.2084656	0.51
257.1576538	0.24
258.2655334	0.19
259.1979370	0.23
261.2736816	0.04
263.9993896	0.06
269.3313599	0.07
271.1016235	0.92
272.1302185	1.13
273.1561890	1.00
274.2346802	0.28
275.1345520	0.50
276.2705688	0.07
278.1208191	0.13
278.9515381	0.10
281.0918274	0.26
282.9682007	0.40
284.1344299	0.19
285.0851746	0.84
286.0755615	0.06
287.2171936	0.05
288.2599182	0.17
293.1184387	19.13
294.0285339	0.22
296.2631836	0.15
297.2108154	0.15
298.2190552	0.28
300.1096191	22.39
301.1500854	69.01
302.1426697	55.89
303.2109375	9.50
307.1321411	0.09
311.2106323	0.04
313.7377930	0.41
314.5752563	0.24
315.2606812	0.29
316.4611511	0.04
317.6791382	0.07
319.6452332	0.23
323.1679382	0.25
324.2160645	0.07
325.2241516	0.03
326.2108765	0.24
327.3704224	0.38
329.2539673	0.41
330.2690125	0.14
331.4544067	0.10
333.0752563	0.11
334.3054199	0.03
335.5401001	0.08
337.2286072	2.90
338.3235474	3.16
339.3269958	1.64
341.3409424	0.36
342.0494385	0.20
343.0866699	0.90
344.1858521	8.26
345.2888794	8.55
346.3344727	0.06
353.3519897	1.07
354.1516418	0.16
356.2761536	0.49
357.2971802	0.14
359.2968140	0.43
367.2532043	1.38
369.2551880	0.37
371.4378662	0.06
372.2207336	0.15
374.2069092	0.40
375.2321472	0.38
376.3632812	0.04
377.5281982	0.05
379.1707764	0.21
380.2083740	0.29
381.2984924	0.12
385.4876404	0.24
386.7988586	0.41
387.4122009	0.61
389.3618469	0.30
391.4053650	0.27
393.6585388	0.14
396.2630310	0.04
397.2775879	0.12
398.0246887	0.04
407.2575989	0.04
409.4611206	0.13
410.4521790	0.16
411.3598633	0.10
413.5040588	0.06
414.4022522	0.04
417.3841858	0.45
418.0547180	0.11
419.1750793	0.06
427.2442932	0.06
428.2669678	0.24
432.2517395	0.09
435.6174927	0.14
442.4082947	0.11
445.3930054	1.06
446.2816467	6.83
447.2763672	2.89
452.2251587	0.09
459.0090332	0.04
461.1492920	100.00
463.1838684	4.63
464.2080078	44.76
465.3041687	11.35
471.5514526	0.12
475.4194031	0.32
476.8532104	0.14
477.7232361	0.08
479.3527222	0.71
488.3059692	0.72
489.3146057	0.70
491.2912903	0.22
492.3512878	0.81
506.2268677	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1243
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
129.1437683	0.02
144.8219299	0.05
147.2296448	0.04
149.0858307	0.04
151.1348877	0.20
153.0793152	4.12
159.2780609	0.03
161.2799225	0.03
163.1028442	0.06
165.1522522	0.02
175.0635376	0.06
177.1202850	0.16
180.0223846	0.02
189.1774292	0.08
191.1077271	0.09
194.9763489	0.64
197.0548553	0.02
207.0738525	0.09
211.3491364	0.02
215.0632629	0.04
217.2090454	0.03
218.6311340	0.06
225.1957855	0.32
237.2337494	0.57
239.3064575	0.03
243.3176880	0.04
245.0021057	0.16
246.9880981	0.06
249.2572327	0.06
251.2452393	0.02
254.3551331	0.06
257.1831055	0.04
259.2566528	0.04
261.3851929	0.03
265.5810852	0.03
268.9463806	0.02
271.3515930	0.07
279.3894653	0.05
284.2972107	0.02
285.0172424	0.04
288.0779114	0.18
289.1975098	1.09
297.1352234	100.00
297.9287415	0.01
298.5773315	0.06
299.1842041	0.29
300.4055176	0.83
301.1300354	1.65
303.0419922	0.04
307.2210693	0.07
315.2253418	0.68
317.3375549	0.01
318.3593445	0.15
319.2656860	0.15
322.1378784	0.15
325.1904907	0.50
326.1224365	0.17
327.1900635	0.29
329.3101807	0.07
331.2130127	0.23
341.2822571	0.16
361.4948730	0.07
363.4355469	0.06
364.4200134	0.04
366.9992371	0.12
371.2276917	0.02
377.4808350	0.08
379.2516174	0.04
390.3501892	0.03
391.4519958	0.09
392.4577942	0.04
393.5234375	0.05
403.2900085	0.13
403.9949036	0.02
405.3577576	0.28
407.2843933	0.56
409.5513611	0.07
415.2637939	2.05
423.4571838	0.06
432.2187500	0.07
433.1874084	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9143
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9185028	0.34
130.9300537	3.45
146.9350586	1.09
158.9940033	9.02
159.8865662	0.16
161.0743103	0.13
174.9159393	100.00
189.9127045	0.11
190.9898682	0.91
215.2443237	0.09
230.9235229	3.97
247.8749084	0.10
248.9452515	1.83
260.0629883	5.81
260.8893433	34.91
277.0039673	2.48
279.2986450	0.02
287.3908691	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
109.2370148	0.02
122.8092804	100.00
123.8895721	0.02
130.9909973	0.05
133.0073853	0.03
136.2518768	0.06
150.9443665	0.03
162.7205963	0.03
188.0745239	0.03
189.1926727	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.899
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2835388	0.08
202.0676727	0.03
217.8497925	0.09
229.3597260	0.09
236.2083740	0.05
273.3064270	0.25
274.9371948	0.74
276.0454712	0.33
277.0031128	0.14
288.9687500	0.20
325.3479614	0.04
387.0070801	0.32
387.9129028	0.68
388.9427490	1.97
390.0822754	0.83
391.1430664	0.26
406.8189697	0.05
419.2155151	0.03
443.1484375	0.20
458.8803711	0.52
460.0407104	0.13
460.9077759	0.12
471.2805176	0.13
473.0616455	0.41
475.0400391	0.83
488.0235596	0.12
489.0156250	0.15
501.1757202	0.33
502.0092163	2.11
502.9935913	6.23
503.9785767	10.85
505.0151978	6.16
517.1371460	0.20
520.0149536	0.02
532.7947388	0.03
533.9767456	0.05
534.9615479	0.03
545.0016479	0.79
546.0264893	0.14
549.9628296	0.03
550.8622437	0.04
561.9821167	0.25
562.8753052	0.14
572.9354858	100.00
574.1057739	1.47
574.9766235	1.32
590.0443726	0.10
590.9730225	0.26
591.7373047	0.03
596.0420532	0.06
599.7172852	0.17
600.9487305	0.65
608.2313232	0.05
618.9559937	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	460.2088
Annotation	Unknow
Peak:m/z	Relative Intensity
131.2670746	0.08
134.2163086	0.04
136.2903748	0.12
144.0885010	0.12
147.0193176	1.10
147.8704834	0.06
155.1685486	0.23
162.1280060	0.92
162.9176025	0.05
164.2932434	0.06
164.9779358	0.10
171.2434235	0.15
173.0916748	0.22
180.2301941	0.43
188.9673157	0.24
190.1256714	1.81
191.1311646	0.42
202.3165894	0.12
205.1896362	0.02
207.0012207	2.53
208.1519775	2.01
216.9446411	0.86
223.1654205	3.39
225.3278351	0.08
227.4601746	0.04
234.1025696	1.57
239.9836731	0.29
242.3105927	0.84
243.0927429	0.12
251.1371155	34.05
253.3204651	0.08
258.2341919	0.69
260.3099670	0.45
267.9941406	0.44
269.2538452	0.07
275.0811157	0.12
277.1581726	0.33
281.2314148	0.11
282.3586121	0.13
285.4133911	0.07
286.3299255	0.09
287.3585815	0.08
291.3370056	0.17
293.3591309	0.04
303.1636963	0.29
308.3031616	0.05
310.5144653	0.03
311.5271606	0.23
312.1384583	0.11
316.0766602	0.22
319.4966431	0.57
322.3052368	0.10
329.5191956	0.05
339.3036499	0.04
344.5148926	0.38
345.3026428	0.32
355.1348877	0.34
359.2472229	0.25
360.7997742	0.07
370.2765503	0.62
372.4265442	0.78
373.3073425	0.56
374.7234192	0.06
380.3167114	0.19
381.1093140	0.21
386.5859985	0.21
388.3537292	76.23
389.1075134	0.23
396.2107239	0.14
397.1243591	0.05
398.3796082	9.24
399.4253235	0.50
401.4237366	0.05
414.4072266	0.39
416.4212036	26.27
422.3528137	0.03
423.5028381	0.18
424.5695801	0.24
432.3966980	100.00
433.4125061	0.12
435.2908936	0.13
441.4433289	0.23
442.2436523	0.40
442.9989319	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.187
Annotation	Unknow
Peak:m/z	Relative Intensity
138.1683350	0.03
143.0505219	0.17
145.0603027	0.02
147.0268097	0.02
152.1694946	0.03
153.1047821	0.28
157.3763733	0.01
161.1346130	0.25
163.2351379	0.06
175.0129089	0.02
176.1554108	0.03
178.9481812	0.01
180.9057007	0.01
186.1345520	0.09
188.0309448	0.02
188.9910583	0.07
191.1442261	0.29
192.1260681	0.01
193.2592468	0.12
195.1617737	0.04
201.1949463	0.50
203.1602783	0.07
204.1961975	0.53
205.1040802	0.07
207.1018066	0.97
215.1422119	0.03
219.2736206	3.62
227.2623138	0.03
228.3297729	0.02
229.2713318	0.05
230.8984680	0.06
243.3519592	0.04
244.4440002	0.02
245.3272095	0.11
249.1700439	0.18
257.0320435	0.02
259.2545471	0.03
261.4267578	0.02
263.1484985	100.00
263.7705078	0.16
265.2153625	0.02
267.2263794	0.13
272.9672852	0.04
277.1788940	0.21
279.3052673	0.05
287.2737427	1.46
289.3833008	0.06
290.3483887	0.02
291.0393066	0.03
293.2089233	0.03
299.3394775	0.11
301.2991943	0.09
305.0607910	4.79
305.7160645	0.09
307.3050842	0.23
309.0476990	1.38
317.2687378	0.34
319.3465576	0.03
323.3510742	0.09
327.3629761	0.06
328.3245850	0.03
329.2987061	0.01
335.3104248	0.26
339.4178772	0.09
341.2604980	0.12
344.2841492	0.05
345.2769165	0.10
347.3382263	0.06
352.8399048	0.07
355.3059998	0.18
359.3595581	0.02
363.5205383	0.07
364.9010620	1.51
367.4416199	0.02
369.1226501	0.03
375.2129822	0.06
377.3307800	0.03
387.0916443	0.03
388.1578674	0.03
395.1706238	0.29
399.0920410	0.03
402.4619446	0.01
403.3872375	0.10
406.9404297	0.12
407.5601501	0.20
409.3456726	0.06
411.3919983	0.03
412.2928162	0.04
424.9841919	26.71
425.6976013	0.27
427.3369446	0.17
429.6802368	0.02
433.4783630	0.02
435.0038452	0.03
439.3676758	0.06
443.2591248	0.10
452.1632385	0.05
453.2102051	0.90
454.2583923	0.05
456.3630676	0.04
457.4056702	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
106.9891815	0.03
135.0753479	5.94
150.9341125	0.04
161.2766418	0.02
165.1024323	0.06
175.1809387	0.02
178.9943848	100.00
180.0675659	0.07
190.9201050	0.02
191.9412689	0.06
192.9116516	0.03
197.3513947	0.01
203.2353821	0.02
206.0066986	0.02
207.8421021	0.07
251.2247925	0.02
269.1901245	0.02
280.1611633	0.11
281.2840881	0.09
295.0545349	0.02
312.2329712	0.02
313.2689514	0.02
322.3534546	0.02
325.4769287	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	823.2057
Annotation	Unknow
Peak:m/z	Relative Intensity
261.5034180	0.02
297.1497192	0.04
300.2783203	0.04
331.3270874	0.12
332.2928162	0.04
357.4176636	0.03
386.3015747	0.03
395.3690796	0.07
479.4266968	0.09
481.4949951	0.07
495.2030640	0.02
525.0943604	0.02
535.3809204	0.05
539.7285767	0.01
565.4829712	0.02
580.5310059	0.11
581.6007080	0.01
586.3209839	0.02
588.1718750	0.02
600.8654175	0.02
617.2395630	0.02
618.4829712	0.16
619.5320435	0.63
620.3653564	0.14
629.8776245	0.11
638.7394409	0.03
643.4890747	0.03
644.3176880	0.09
647.4343872	0.07
653.3208008	0.02
655.8041382	0.05
659.3960571	2.57
660.3917847	1.53
661.3501587	5.54
662.4081421	1.34
664.5947876	0.02
665.2222900	0.02
673.6534424	0.03
691.3182983	100.00
692.3828125	33.04
701.5272827	0.01
728.4251709	0.01
743.3148193	0.12
760.4306641	0.01
778.8821411	0.08
791.2990112	0.74
792.3714600	0.33
793.6964111	0.07
800.0160522	0.10
806.0720825	0.07
807.0243530	0.02
823.9406128	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.2406
Annotation	Ligurobustoside A
Peak:m/z	Relative Intensity
143.1743164	0.06
144.0599518	0.24
146.0045776	0.17
147.1716156	0.06
148.1920166	0.28
149.0427094	0.11
154.9744568	0.09
159.1116943	0.03
160.9917603	0.07
162.2675476	0.15
162.9403687	0.20
164.1276550	0.27
174.1148071	0.52
174.9900665	0.08
178.7706909	0.14
180.1447906	1.31
184.0903931	0.08
191.1502991	3.28
197.2102051	0.03
205.1170654	0.03
207.0134277	0.56
207.9709015	0.52
209.1415100	0.03
213.9568176	0.06
216.3160095	0.11
217.3163757	0.34
218.0462799	1.17
219.2159119	0.04
222.2720947	0.03
224.3743439	0.07
225.2249146	0.37
227.3776855	0.32
229.3834991	0.10
235.1540527	7.92
236.2594910	0.29
237.2974548	0.06
241.0379486	0.09
242.2791443	0.39
243.2547302	0.33
244.3691101	0.11
247.1952515	0.03
250.4277344	0.05
252.2248535	7.03
254.5339355	0.05
258.2919922	0.15
259.1578064	0.38
260.4017639	0.03
263.1980896	0.07
268.3320007	0.43
270.2703857	0.30
271.1398315	0.40
277.4162903	0.19
280.1827087	0.26
281.3328857	0.06
282.1841125	0.05
285.2081604	0.10
286.2285767	0.42
288.6505127	0.08
293.2366333	0.63
296.1526794	0.03
297.2536621	0.21
298.8051147	0.02
302.9980774	0.11
307.1536255	0.06
311.1643982	0.05
314.1157227	0.09
320.2802124	0.80
327.5009155	0.06
328.3335266	0.14
329.2502441	0.96
330.1705627	0.11
339.2619629	0.19
341.1393127	0.06
343.2617798	0.17
345.3250732	0.04
346.2027588	0.03
348.4506836	0.03
353.1643066	0.05
355.4020386	0.10
356.3170166	0.06
357.4315186	0.45
360.5857239	0.05
362.8034668	0.05
372.4183044	1.20
373.4031372	0.08
374.4120483	0.16
382.3569031	2.91
383.4303284	0.24
385.1124878	0.04
387.3535461	0.03
388.3792114	0.03
389.4761658	2.53
390.7373962	0.17
400.3175049	100.00
401.3876038	0.18
404.4230042	0.08
409.5909729	0.03
414.7952881	0.11
415.4042664	0.17
417.4242249	5.93
418.2700500	0.02
426.2088928	0.96
432.6085815	0.33
433.4919739	1.23
439.3332214	0.04
444.2401123	34.07
444.8483582	0.25
446.1190491	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.224
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1829681	0.17
191.1792145	0.09
192.9578705	0.14
197.0725250	0.16
208.1876678	0.25
218.9828491	0.10
227.2406616	0.19
243.2948303	0.09
286.1170654	0.53
298.4756470	0.09
301.1769409	0.11
305.3205566	0.22
317.1033936	0.24
329.2062378	6.96
330.0146484	0.15
331.2299194	2.24
333.1381226	0.13
341.5089722	0.14
345.4107666	0.17
346.5671997	0.98
347.2744141	12.11
355.2562256	1.31
359.0440063	0.14
363.2976685	0.30
372.3752441	0.30
389.2507935	0.48
399.1016235	0.11
408.2088013	0.38
423.1854858	0.13
437.3135376	0.10
438.1939697	0.08
447.2887573	0.20
449.5416260	0.46
463.3018799	100.00
465.2357178	0.21
490.3329468	0.11
491.3738403	0.45
492.4342041	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2675
Annotation	Menisporopsin A
Peak:m/z	Relative Intensity
243.0186768	0.77
244.4894562	0.04
245.2769165	0.02
341.3415527	0.20
378.8486938	0.12
381.1906128	0.09
383.2665405	0.25
419.0382690	0.07
421.2634277	0.06
429.1882935	0.10
442.2072144	0.03
443.1231689	0.28
454.3683472	0.19
455.2050171	0.29
485.2562866	0.04
503.0115356	1.15
503.6969604	0.09
515.4072876	0.03
525.1571655	0.54
529.3781738	0.07
530.8931274	0.09
535.2813110	0.07
543.8175659	0.05
545.0288696	0.06
548.3442383	0.05
553.0026855	0.12
554.0599976	0.10
555.2367554	0.11
565.2987061	0.13
567.0569458	0.12
570.9566040	0.03
571.6236572	0.04
575.0829468	0.37
587.1403809	0.13
587.7574463	0.08
588.3579102	0.14
591.0033569	0.19
595.0657349	0.08
605.1144409	0.74
617.3971558	0.33
622.9437256	0.23
627.2871094	0.04
639.2620239	0.20
645.2764282	0.05
646.8287354	0.24
647.4794312	0.17
650.2388916	0.03
651.2396851	0.10
661.0584106	0.49
662.6004028	0.07
663.9522095	0.07
665.3652954	100.00
666.4895020	0.18
691.2323608	0.03
692.3112183	0.07
695.1598511	0.26
698.9699097	1.37
707.2394409	0.18
723.6590576	0.27
737.0628052	0.20
745.1001587	0.62
747.6025391	0.60
749.1694336	0.29
749.9841309	0.44
752.2131348	0.06
760.9854126	0.05
777.7496948	0.06
779.0117798	0.96
782.2191772	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1769
Annotation	Diospyrososide
Peak:m/z	Relative Intensity
138.9778900	0.26
153.1261749	0.52
156.8143158	1.23
160.1040649	0.19
161.1072235	3.23
163.0321198	3.13
175.1565399	1.20
179.1591949	7.05
181.0928192	2.88
187.0129700	0.09
193.2252350	0.74
197.1604004	5.97
201.1141663	0.11
203.2190094	0.36
205.1000366	3.39
206.8728333	0.88
223.1663208	6.83
228.0747681	0.07
231.0531464	3.59
239.1894379	0.12
241.1944122	3.21
249.0939636	46.20
250.1194763	0.22
251.2659912	0.20
267.2194519	90.52
273.2417297	0.10
284.5783081	0.24
285.2648010	0.96
286.2485352	0.88
287.2616272	0.27
291.2326660	0.30
297.3224792	2.62
298.8856506	0.24
309.3365479	0.56
313.1540527	0.16
315.1770630	52.16
316.1706848	0.31
323.1747131	0.11
325.1114502	0.18
328.0782776	0.65
329.1271667	3.42
331.2791748	0.48
339.4486389	0.14
341.3287964	0.13
343.0157471	0.39
345.1331787	0.11
347.0790710	0.63
349.2464294	3.67
357.3967896	0.68
370.6939697	0.14
385.4115906	0.30
387.4146118	0.22
393.5387573	0.27
395.3320312	0.61
397.5315247	0.65
401.6401978	0.38
403.3046265	1.62
411.3504333	4.49
413.2406006	3.16
415.1688538	0.16
429.3268127	66.07
431.2188416	61.12
431.9690552	0.26
445.2960815	0.09
447.3699646	4.60
448.3423462	0.10
455.3203430	5.24
471.4016418	0.14
473.2588196	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9638367	9.02
179.0624542	0.15
211.3471680	0.02
212.9049683	4.76
218.9527283	0.53
227.1626282	0.13
268.1924744	0.66
269.4386597	0.07
270.1617432	1.20
279.1365967	0.04
281.1608276	0.10
294.2601013	0.06
295.1701660	0.24
296.7931519	100.00
297.4398193	0.52
308.8393555	0.07
321.1126709	0.05
361.4076233	0.05
363.0325012	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2455
Annotation	Unknow
Peak:m/z	Relative Intensity
191.2810059	0.05
193.1458740	0.24
196.9002533	0.05
201.2654877	0.08
203.2911377	0.04
205.2135315	0.06
207.0698090	0.20
225.1669006	0.71
228.9331055	0.11
231.0639496	0.19
237.2031860	0.02
241.5786133	0.07
243.2554779	0.12
245.1468811	0.06
246.2454071	0.08
249.1696167	2.07
251.3332825	0.14
259.1465454	0.06
261.2110596	0.19
267.1336365	0.34
271.0587463	0.10
273.4952698	0.02
277.1212769	0.05
281.4147339	0.07
285.2136536	0.14
288.1441345	0.04
293.0335693	0.07
298.6524963	0.17
299.2992554	3.29
303.1788025	0.91
304.1300659	0.07
313.5833435	0.29
314.3161621	1.46
317.2408447	0.11
319.0338745	0.08
321.3313599	0.03
327.6005249	0.02
329.2368774	8.87
331.2191162	0.11
333.3771362	0.07
337.1000366	0.08
338.1857300	0.13
339.4156494	0.04
343.3500366	0.14
345.1570435	0.09
346.3773193	0.28
347.2974243	1.25
351.9846802	0.04
355.3725586	0.05
369.4017944	0.07
371.2482300	0.05
374.9770508	0.05
379.3653564	0.03
381.4797974	0.04
382.3624878	0.03
389.3001709	0.50
390.2957764	0.12
393.9779663	0.04
397.4246826	0.19
405.4969482	0.26
413.2723389	2.57
415.3723755	0.34
419.4243164	0.02
427.0251465	0.09
429.5189209	0.29
430.7390137	0.22
431.4218140	1.59
433.2985840	0.13
434.4837036	0.09
439.1502686	0.07
446.3778687	0.09
451.3071289	0.10
455.1716919	0.09
457.3786011	5.29
461.2382202	0.16
463.3093262	0.08
474.1433105	1.79
475.3002930	100.00
475.9413452	0.27
479.3807983	0.45
487.1424561	0.04
488.8475952	0.12
491.2214966	0.08
493.2801514	13.01
493.9639282	0.12
501.3683472	5.02
503.4213257	0.03
505.1524048	0.04
507.2013550	0.02
512.3729858	0.09
516.1483765	0.04
516.9778442	0.14
523.3748169	0.24
525.3286133	0.03
528.2955933	0.07
529.4645386	0.08
533.4869995	0.13
535.2844849	0.78
537.3746948	0.07
542.9340210	0.04
544.7175903	0.07
547.4124756	0.06
551.2311401	0.10
561.5773315	0.03
562.2505493	0.25
564.3637695	0.03
565.3699341	0.31
569.2164917	0.07
570.2020264	0.02
573.4746704	0.11
576.5302124	0.03
577.4936523	0.02
579.2002563	0.03
582.5261841	0.02
593.6506958	0.18
594.7070312	0.63
595.4281006	1.21
605.2203979	0.05
609.0537720	0.14
610.6599731	0.21
611.3243408	0.54
619.2312622	0.38
620.0299683	0.14
623.4334106	0.31
625.9747925	0.12
627.5809937	0.14
632.9371338	0.03
634.9326172	0.30
636.4151001	1.78
637.3955078	5.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	733.3068
Annotation	Unknow
Peak:m/z	Relative Intensity
211.2338867	0.19
212.1001129	0.09
224.9869690	0.31
236.2574463	0.09
252.7380676	0.03
253.4628296	0.04
255.5028076	0.16
257.0269775	0.02
263.1231689	0.03
282.7878723	0.03
295.0792542	0.03
298.2696838	0.07
311.3099365	0.07
313.1513977	0.70
315.4193420	0.02
328.1892700	9.69
329.2565918	0.82
331.1694946	0.04
343.2641907	100.00
344.3079224	10.96
345.1849365	0.06
360.2291260	0.05
368.3564453	0.04
370.9651489	0.03
373.4571533	0.09
379.4003296	0.12
390.2723389	0.04
391.2558594	0.35
409.1002197	0.08
436.9970093	0.03
439.0040894	0.12
451.8149414	0.02
487.0910645	0.05
507.4977417	0.25
511.2207642	0.02
521.3450317	0.29
522.2549438	0.23
529.5587158	0.02
537.5146484	0.07
543.2890625	0.07
550.7246094	0.02
553.4932861	0.10
563.5886841	0.06
567.6010132	0.03
571.3847656	0.04
572.2864380	0.06
580.4478149	0.08
612.4526367	0.03
643.7333374	0.05
644.4691772	0.19
646.9260864	0.09
659.8917847	0.03
667.4682007	0.16
671.1077271	0.13
672.2501221	0.04
673.5703735	0.05
676.1939087	0.03
685.4277954	0.12
686.4404297	0.24
687.4133911	0.12
688.3950806	0.05
689.4432983	0.07
699.1017456	0.19
701.0617065	0.05
703.3062134	0.20
704.7596436	0.07
705.5192261	0.06
714.5005493	0.13
715.4187622	0.60
716.3877563	0.29
717.7799683	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.7503281	0.01
126.8884735	0.04
134.9975739	0.35
137.0064087	0.04
142.9712219	0.03
155.0810547	0.01
160.9497375	0.30
172.9943848	0.40
179.0093079	3.69
181.3043518	0.02
189.0101013	0.02
191.0604248	100.00
214.9796448	0.01
251.2573853	0.02
262.1054077	0.06
268.1140442	0.05
292.3445435	0.13
293.090271	0.11
307.3483887	0.02
308.8431091	0.04
309.4709167	0.02
317.1978149	0.05
334.0444031	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0079
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9677124	0.04
150.4300079	0.05
169.9210205	0.04
171.9786072	0.04
182.2019958	0.06
199.8772430	0.10
200.9414673	0.03
214.0366211	0.11
215.2722931	0.07
215.9197845	0.09
217.9663391	0.44
228.0408783	0.20
229.9650116	0.95
236.1368713	0.04
239.9996643	0.11
243.0180054	0.03
244.7387390	0.24
254.0552673	0.33
256.1197510	0.06
258.1250000	0.18
271.9381714	0.03
283.8179932	0.14
284.4188232	0.06
286.1343994	0.05
290.9797974	0.08
297.5675354	0.03
301.9493408	0.75
304.0708313	0.23
304.8370361	0.05
306.0482788	0.95
317.1547852	0.53
317.9755554	0.51
319.8434143	0.13
321.1468201	0.09
321.8770752	0.47
335.3631592	2.34
335.9729309	10.62
337.1014099	0.05
344.7990417	0.15
349.7107239	0.03
351.0723877	0.14
359.1161499	0.04
361.3360291	0.09
362.3470154	0.08
363.1049500	0.08
363.8515930	0.13
365.0868530	0.66
365.7852478	0.47
367.5506897	0.24
372.5261536	0.04
382.0450439	100.00
385.3711548	0.06
389.6678162	0.33
393.0281677	0.02
397.1925354	0.05
407.1147156	2.47
408.1084290	0.84
409.2049561	0.10
418.2364807	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8746
Annotation	Unknow
Peak:m/z	Relative Intensity
158.6804810	0.07
174.8921814	1.02
199.3391571	0.03
233.0296936	0.04
244.9424591	0.50
273.0078735	0.99
273.8912964	0.11
275.1858215	0.04
288.9976196	14.00
305.0689697	5.28
311.9514771	0.03
374.0526733	0.03
387.0859985	1.69
387.9367676	0.64
388.8103638	0.11
398.1375122	0.12
403.0384521	7.74
417.1362915	0.10
418.9266968	100.00
458.0610352	0.18
458.9614258	0.41
461.5809326	0.15
464.7345581	0.11
477.1675415	0.21
486.0545044	0.33
487.1119995	0.46
488.0370483	0.11
489.4198608	0.05
503.9854126	0.05
505.0465698	0.17
523.1072388	0.08
523.9470825	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
113.1356659	0.05
178.1356506	0.10
178.9455872	1.08
197.0525208	1.01
215.1003723	8.19
221.0023804	0.12
321.3774719	0.19
341.2161255	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	455.2135
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9563141	0.06
175.0585785	0.11
193.1954193	0.06
277.3320923	0.40
301.0633545	0.16
309.1763306	0.16
356.9552002	0.06
361.3749390	0.03
365.3287048	0.04
393.8774109	0.14
395.4590759	0.12
409.2896118	100.00
409.9413757	0.21
411.1976013	0.31
437.3237610	0.84
438.0393677	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9393
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0386047	0.51
160.0464172	0.03
228.9783936	0.08
230.0670471	0.06
257.1224365	0.05
258.2097168	0.01
269.1380615	0.02
271.0841370	0.11
272.9884644	100.00
274.0060425	24.84
300.1402283	0.01
313.2000122	0.08
314.1751404	0.04
315.1353149	0.07
315.7690430	0.02
332.9021606	0.02
341.0242920	0.12
342.0915833	0.01
343.0056152	0.15
343.8920288	0.03
345.0658569	0.03
358.8561707	0.01
363.0193787	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
67.0059204	0.02
68.1681595	0.04
68.8767853	0.15
69.9821472	0.14
71.0201111	0.13
72.0404511	0.06
73.0730743	0.07
73.9956894	0.10
78.8840713	0.04
80.0055771	0.07
80.9660797	0.14
81.7720642	0.40
82.9134216	0.16
83.9231415	0.50
84.9633484	0.10
86.0854797	0.15
88.8250885	0.12
90.9182053	0.03
92.0343247	0.20
93.1278229	0.09
93.9124756	0.19
94.9873199	0.06
95.9703827	0.26
97.0312958	0.38
98.0261536	0.56
99.9793243	0.18
101.2748566	0.04
102.9643250	0.04
107.3238068	0.07
108.0069580	0.13
111.0024109	0.11
112.0472412	0.40
114.0917206	0.16
115.0624084	0.18
116.9467621	0.07
120.0620728	0.05
121.0142975	0.21
122.0084076	0.33
123.1294861	0.09
123.8980408	0.10
124.8361359	0.07
126.0270233	0.16
128.2274780	0.20
129.1213531	0.13
129.7843628	0.24
136.0272064	0.07
139.0872650	0.18
140.1658173	0.11
141.3874207	0.03
142.0105438	0.04
143.0899811	0.19
144.0594330	0.06
146.0971680	0.03
148.9438629	0.05
154.0373535	0.26
154.8391266	0.04
155.9394379	0.44
157.2427216	0.14
158.9264679	100.00
159.7478943	0.07
162.0471649	0.06
163.0451508	0.34
164.1143799	0.43
168.9116821	0.05
170.2564850	0.05
172.0381775	0.17
176.7965240	1.76
181.1088104	0.52
181.9573212	1.66
183.1793823	0.08
185.7624359	0.03
190.9419403	0.14
199.8108673	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	305.0692
Annotation	Unknow
Peak:m/z	Relative Intensity
99.1379776	0.12
115.0905762	0.19
126.9350357	0.64
144.9048157	3.32
145.9819031	0.19
148.0980225	0.08
151.2870483	0.07
158.0765228	0.17
158.9726257	0.21
161.4217529	0.05
162.8226624	6.83
164.0057678	0.20
171.3506165	0.32
175.1393433	0.35
186.0968933	0.12
189.2066650	0.71
193.1826477	0.08
194.0367126	0.25
194.6575928	0.42
198.2017212	0.26
199.0460205	0.16
202.7100830	0.09
203.4283142	0.21
206.1107483	0.10
207.2872314	2.56
208.0012207	7.73
212.8680115	0.14
214.2245178	3.62
215.0048218	6.75
226.2311401	0.10
233.0084534	0.16
239.1587219	0.06
240.9629822	1.36
245.1388550	0.13
245.9619751	0.16
249.3064575	0.27
252.8014526	0.04
258.9438477	8.44
261.1791992	0.21
268.1233826	0.08
269.0614014	0.31
271.1329956	0.81
271.7655640	0.04
277.0809021	0.77
279.9836121	11.50
280.8489075	0.59
282.2047119	0.14
286.3546143	2.35
287.1768494	5.37
287.8654175	0.42
288.9777832	100.00
290.1976929	0.90
291.6586609	0.35
292.3115845	0.10
294.8764648	0.67
296.0586243	19.19
296.7479553	0.24
305.2932129	0.08
307.2330322	0.15
308.5428467	0.09
323.8927612	0.09
325.0346069	2.18
326.0375061	0.04
327.0741882	0.09
337.0593262	0.33
338.9818420	0.57
352.8653870	0.07
354.9602356	1.37
356.2433167	0.30
367.6509705	0.09
369.0442200	0.73
379.5126038	0.06
395.1878967	0.03
396.9659729	2.36
401.0718384	0.03
410.1541138	0.09
411.1968994	0.27
414.5245972	3.13
415.1425476	10.59
416.3329468	0.30
417.1248474	0.20
427.1728210	0.75
428.2356567	2.56
429.0559692	4.76
447.6004944	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0724
Annotation	Unknow
Peak:m/z	Relative Intensity
108.8473511	0.11
110.9209671	77.51
129.0912018	0.26
130.8755035	0.15
155.0309448	0.73
170.2204590	0.14
172.9130249	100.00
175.1437073	0.13
191.0223389	1.52
209.0650482	0.16
262.8881226	0.13
291.3032227	0.17
293.1652527	0.90
301.3752441	0.18
306.9151611	0.33
335.2497864	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2394
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9206238	1.41
155.0352173	0.27
160.9973907	3.02
167.0439911	0.24
173.0737915	0.40
191.0857239	20.50
192.1278992	0.36
201.1488342	0.25
202.9203339	0.57
207.0914001	0.09
209.1296082	0.09
211.5918884	0.13
218.0255127	0.35
218.8770294	0.22
220.7139130	22.71
221.4194489	0.05
222.3270264	0.07
232.9808960	0.13
238.7480164	3.08
245.2392426	0.28
250.9163818	12.26
263.0400085	4.91
263.7700806	0.15
267.3262939	0.07
275.1590576	2.00
280.0986023	0.30
281.0053711	5.71
288.9003296	0.17
293.0777588	14.63
294.0278320	0.49
310.4106445	11.68
311.0341187	100.00
312.0731201	1.53
321.9400635	0.34
323.1064453	0.52
326.3346558	0.27
333.0091553	0.40
334.2504883	0.33
343.0983887	0.07
355.0967407	0.24
356.9586792	0.36
367.2025146	0.53
368.1336670	0.15
369.2449951	0.34
382.0126953	0.19
385.1618042	0.21
386.0639038	0.23
399.6204224	0.09
405.2854614	0.70
415.1047363	0.10
416.5270996	0.10
423.4898682	0.64
429.6051025	0.13
445.8234253	0.07
450.3266602	0.21
464.0855713	0.51
467.3465576	0.18
470.2913818	0.53
475.2606201	0.66
476.4359741	0.37
488.2761230	0.10
501.4041748	0.46
503.3580322	0.11
508.2760010	0.24
510.2290039	0.22
528.1829224	0.19
529.3690796	0.64
530.1488647	0.64
533.5064087	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.31
Annotation	Unknow
Peak:m/z	Relative Intensity
241.1714783	0.59
241.9706726	0.28
243.1342468	1.32
245.1705322	2.85
261.4484863	0.66
264.1708984	0.12
264.9740295	0.63
271.1414185	0.50
273.0047302	1.15
281.2069702	0.41
283.3313599	0.24
285.3623657	1.11
286.1809387	0.21
287.1249084	17.68
288.3322754	1.26
289.2664795	10.24
290.0644531	1.00
291.4663086	0.21
298.2131348	0.19
299.1884766	4.96
300.1187439	1.01
301.0690308	0.09
303.4746094	0.43
305.2473145	0.20
313.3774719	0.23
315.4597778	0.78
320.9455566	0.22
325.5361633	0.41
327.2718201	0.73
329.2674561	2.23
330.4073792	0.23
331.2258301	0.77
337.1612549	1.07
341.3392639	0.56
349.0956421	0.20
353.3401489	0.15
357.0717163	1.09
363.2296143	4.69
365.2145996	0.13
367.2501831	0.32
369.2286377	1.06
371.3121338	1.34
377.3165283	0.24
379.2431641	0.45
381.2019043	2.32
383.1640930	0.48
387.2526245	0.32
389.0335693	0.38
391.1235352	1.05
393.2990723	0.67
395.2642212	6.12
396.3267822	0.18
403.3295898	0.17
405.2213745	9.37
407.2061157	30.92
408.2782593	0.65
409.1035767	0.74
411.2253418	6.59
412.2938843	6.75
413.2880249	12.37
417.0457153	1.82
423.1351318	8.33
425.2368774	25.47
426.2015381	0.12
431.1887817	0.34
433.2459717	2.34
435.3035889	3.32
437.2832642	0.30
438.4349365	0.63
447.2368164	1.22
448.3407593	1.60
449.2523804	12.32
450.0720825	0.61
451.2876587	21.45
452.3261719	5.52
453.2852173	1.98
454.3787231	1.45
464.7857666	0.45
465.3925781	1.30
467.2492065	3.78
471.4064331	0.51
473.3310547	0.49
475.4812622	0.11
479.3917236	0.15
489.2904053	0.35
493.1624146	0.91
499.7312012	0.47
501.2222900	0.62
503.5153809	0.13
507.3200684	0.45
513.0820923	0.14
514.2785034	0.31
515.3126221	1.97
517.3958740	1.29
519.4326172	0.94
525.3286133	5.37
527.3982544	0.41
531.2550659	2.04
532.2175293	1.03
533.3794556	3.00
534.1193848	0.10
535.2598877	0.94
537.3601074	0.19
541.3848877	0.13
543.2504272	21.24
545.4910889	0.52
549.2512207	0.39
557.3715210	9.21
558.2305908	0.12
559.2895508	6.80
560.1919556	2.17
561.1916504	4.57
567.2267456	0.27
569.3012695	7.74
573.5057983	3.18
574.5691528	7.50
575.3363647	28.17
577.2507935	51.93
578.2178345	0.30
583.2575073	0.34
585.1826172	0.67
586.0852661	0.92
587.2344971	27.43
587.8407593	0.11
601.1751099	1.35
603.3057251	0.72
606.1818237	0.41
613.3527222	0.48
616.1696167	1.41
617.4109497	0.91
619.3210449	5.82
629.3756714	2.89
634.9264526	0.18
637.3842163	0.60
638.8770142	0.41
643.1417236	0.14
644.4135132	0.67
648.6011353	0.35
651.4091187	1.05
652.2484131	0.19
654.4910889	0.29
656.4440308	0.14
657.5490723	0.13
661.3645020	0.12
667.0620117	0.46
669.3223267	2.81
671.4357910	0.64
672.5348511	0.28
677.2981567	7.22
679.0429077	0.22
683.4351196	0.93
688.2984009	0.60
692.1345825	0.16
693.3469849	3.90
695.1621704	100.00
696.1237793	1.24
697.2850342	1.10
701.2885132	0.13
702.5982056	1.22
703.4474487	1.60
704.3969116	0.41
707.6597290	0.31
709.3499756	0.11
711.2514648	7.50
712.3383789	36.11
713.4022217	49.51
715.5530396	1.05
719.6522827	1.34
720.9884644	1.79
721.6860962	0.29
724.9093628	0.35
725.7011108	0.25
732.5027466	0.26
733.3241577	1.84
733.9757690	0.52
737.3627319	1.24
739.2424316	61.69
740.5112305	0.40
741.3767700	1.09
742.1553345	0.53
743.5200195	0.63
747.5870972	0.29
753.3183594	0.13
754.6162109	0.77
755.2451172	0.32
756.4292603	0.37
770.4040527	0.96
771.2255249	1.66
777.5028687	0.26
779.4859009	12.12
780.0938721	0.26
781.2683716	0.28
783.4349976	0.41
788.4091797	2.57
789.2247314	1.48
792.2215576	0.46
801.3493042	2.02
802.2335815	0.18
805.4490967	0.17
807.6166992	1.16
819.5761108	0.24
821.3945923	2.35
822.1465454	0.27
828.3338013	0.13
829.3480835	0.36
845.6359253	0.61
847.2381592	23.29
848.2235107	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.2644
Annotation	Unknow
Peak:m/z	Relative Intensity
189.2402039	0.13
191.1957703	0.06
192.3004303	0.03
193.3745117	0.21
207.3204193	0.13
219.0461426	0.22
223.1834412	0.05
237.2274017	0.28
243.1391296	0.05
245.3001862	0.13
259.3482666	0.05
267.2009888	0.47
284.9729309	0.05
297.1793213	0.25
299.2038879	0.05
302.0640869	0.05
313.1948547	100.00
314.5700684	0.36
315.3319397	0.57
321.0605469	0.04
331.2194214	0.08
332.1398926	0.07
345.2129517	0.24
354.9758301	0.10
363.4005127	0.06
369.0053101	0.16
371.4213257	0.05
380.0744629	0.07
437.2886963	0.10
439.1621094	0.08
447.1453247	0.33
459.3022461	0.10
463.3316650	0.28
465.2954712	1.09
467.3237915	0.11
473.1660767	0.37
477.1901245	1.24
489.2414551	0.13
495.3969116	0.08
496.8057861	0.37
501.2201538	0.24
505.0151978	0.22
506.2575073	0.13
507.3394165	0.40
511.2515259	0.05
517.4850464	0.06
520.9475098	0.11
529.1790161	0.38
531.1921387	0.21
534.1648560	0.05
536.9164429	0.16
540.4808960	0.18
546.2660522	0.11
547.0463257	0.06
549.3883057	0.07
562.5052490	0.07
565.4509888	0.05
567.3070068	0.13
568.9240112	0.06
571.0439453	0.23
577.0857544	0.03
578.9186401	0.09
580.2984619	0.07
581.2439575	0.22
582.2855835	0.27
583.4135742	0.61
589.9072266	0.07
591.0938110	0.46
597.6154175	0.10
599.2516479	0.18
604.7532349	0.06
605.3789673	0.22
607.5067749	0.13
608.3671265	0.88
609.3746948	0.33
610.0797729	0.07
618.0396118	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0886
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
160.2501678	0.01
160.8929138	0.02
165.1739197	0.03
177.1094818	0.03
178.9922791	0.07
179.9440308	0.01
183.0610657	0.01
190.8076630	0.06
192.7363129	0.03
209.0311890	0.06
211.1811066	0.05
221.5805206	0.02
223.1083679	0.03
227.9926758	0.03
245.9813232	0.01
249.3957214	0.02
255.4458923	0.02
293.1785278	0.17
294.0530396	0.01
295.2291870	0.07
298.4092407	0.03
301.2695312	0.01
303.4021301	0.01
305.0172729	0.01
311.2711182	0.14
312.2441406	0.05
323.2506714	0.02
327.1950684	0.01
329.3114624	0.03
337.5146484	0.04
339.4213257	0.16
340.4622803	0.02
341.4253540	0.02
342.2777710	0.01
343.0262451	0.07
344.7724609	0.02
356.2677612	0.01
365.1686401	0.01
367.3767090	0.02
368.2581787	0.06
369.3270874	0.08
370.4893799	0.03
379.1850586	0.01
384.0599365	0.01
386.6652222	0.10
387.4063721	0.45
411.4410400	0.01
417.1104126	0.07
429.5081787	0.02
430.5985718	0.02
434.0454712	0.03
445.1307373	0.03
445.7365723	0.02
453.3782349	0.02
455.0127563	0.02
457.3758545	0.02
459.4338989	0.07
462.6661377	0.02
463.2865601	0.18
468.4095459	0.08
471.4727173	0.02
477.6229858	0.04
486.6489258	0.09
487.3983765	0.04
488.4189453	0.05
489.4157104	0.07
491.0279541	0.01
500.3936768	0.01
501.6081543	0.10
502.2200928	0.44
503.2935181	1.41
505.1991577	100.00
505.8403931	0.17
507.3221436	0.15
513.5385132	0.01
519.1998901	0.01
521.2964478	0.08
529.1721802	0.02
530.0551758	0.03
531.1972656	0.44
533.7568970	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.97755432	0.32
81.17207336	0.77
82.92874908	0.78
85.08712769	0.32
95.27249146	0.88
102.9844971	2.89
105.0163422	0.88
106.9903564	0.30
109.1069183	2.97
113.1164398	0.69
114.9689789	1.66
119.0459747	0.52
121.0876007	0.35
123.1473846	0.27
124.9485321	1.31
127.0452118	6.59
128.9598999	7.57
134.9835358	2.25
143.0151978	1.08
144.9642181	1.03
146.9619598	2.01
149.2548981	1.04
151.0350494	100.00
151.7832184	1.36
153.098938	0.32
155.059082	1.57
156.9754181	1.64
161.0639191	1.25
164.9662628	2.01
166.0336609	1.22
167.0429382	4.42
169.2405853	2.93
170.1490326	0.55
172.1754761	1.05
175.0921783	0.86
177.9440765	0.62
179.1229401	3.87
181.2150726	2.93
182.2838593	2.64
183.1918793	0.72
185.1732178	3.14
186.2329254	1.61
188.9663086	1.29
193.1373444	5.21
194.2312012	0.84
194.9696045	0.47
197.1672516	5.22
198.9231873	0.30
205.0007782	1.59
207.07164	3.37
209.1391296	0.80
210.9541168	4.63
213.2535248	1.24
217.2810516	8.44
222.2084503	0.47
223.0677643	0.60
225.141861	13.45
226.1648102	0.35
235.1833649	30.16
237.039505	0.60
238.1358185	17.96
239.2308502	2.70
244.1110687	1.18
251.2564697	0.92
253.0821533	59.94
254.1565094	3.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0078
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1135864	0.03
198.1097870	0.12
199.7958679	0.05
210.0474854	0.09
213.0799866	0.04
215.6823425	0.15
218.0245056	0.15
228.1678467	0.06
230.0741119	0.88
233.9253540	0.04
236.2763977	0.15
240.1279297	0.12
246.1422424	0.05
254.0919800	0.14
257.4614868	0.15
258.0645752	0.57
259.8959656	0.06
271.8404541	0.03
273.7932739	0.04
284.0219421	0.14
287.4389648	0.18
297.9577026	0.19
301.9453125	0.79
304.2099609	0.12
305.0574951	0.06
306.0682983	1.14
310.4706116	0.03
315.8914795	0.13
317.0319824	0.19
317.9205933	0.17
320.1506958	0.05
322.0727539	0.22
335.2033691	0.80
336.0065918	10.26
345.9974060	0.33
349.7607422	0.39
351.1783142	0.45
360.0425415	0.11
363.2610474	0.04
365.5419006	0.08
366.1969910	0.16
367.1046753	0.04
377.9671326	0.05
378.6633606	0.07
382.0883484	100.00
384.1351624	0.08
390.0791321	0.07
394.9993591	0.24
406.0551147	0.09
407.2038269	0.66
408.2128296	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.1544
Annotation	Luteolin 7-(2''-glucosyllactate)
Peak:m/z	Relative Intensity
195.0605469	2.74
208.0420837	0.51
221.2781677	0.18
223.1558838	28.05
234.7318726	0.28
262.9826050	1.18
331.1635132	3.26
347.3482056	0.39
349.0889893	100.00
359.1723022	0.18
361.2465210	0.79
367.2687378	0.64
369.4244995	0.27
373.2320557	1.66
386.2737427	2.79
390.0939331	0.74
391.1110229	2.72
397.0356445	0.83
397.6812134	0.57
415.2697144	2.70
439.3546143	1.80
456.9886475	0.33
463.2181396	0.39
469.3413086	0.29
472.2572021	0.26
474.9125977	0.73
476.8404541	1.30
499.0891113	1.65
517.2213135	1.32
520.4772949	0.42
529.8966675	0.63
532.2448120	0.44
534.9463501	13.68
535.5875854	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	739.1462
Annotation	Prunin 4'',6''-di-O-gallate
Peak:m/z	Relative Intensity
345.1426392	0.40
395.1555176	0.54
409.1825562	0.81
439.4517212	1.17
477.3627930	0.98
481.2228394	0.40
506.7204590	0.29
576.4071655	3.96
577.1727905	1.35
605.5248413	1.68
607.2033081	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3047
Annotation	Sphinganine
Peak:m/z	Relative Intensity
95.00583649	0.46
96.99019623	0.43
109.0110474	0.32
110.9682617	0.30
119.9647827	0.06
121.1082306	0.04
122.9845276	0.64
125.1122055	0.28
132.9847717	0.02
137.0220032	0.23
139.1437988	0.15
139.9770813	0.06
145.7148743	0.02
153.1085358	0.09
155.0302734	0.05
156.9515381	0.05
162.3806763	0.04
164.9233551	0.21
167.2008362	0.03
173.176178	0.03
177.0128784	0.02
178.9655151	0.14
182.2467346	0.04
187.1653137	0.05
189.2189484	0.03
193.1643219	0.14
194.7866821	0.11
199.967804	0.02
204.1596985	0.05
204.9877319	0.04
207.4881287	0.04
210.8506165	0.06
213.1173401	0.11
214.1729126	0.02
217.2426453	0.02
229.127655	0.16
230.4016113	0.02
236.1242981	0.10
240.4398193	0.66
242.1617432	0.05
247.1038208	0.19
249.336792	0.19
252.243042	0.09
253.0960693	0.23
254.3456726	0.32
255.0701294	0.03
256.2260742	0.10
257.2852478	0.46
261.9412842	0.02
264.3092346	0.20
266.3198242	3.48
267.348053	0.66
271.1954651	0.17
272.1109619	0.08
274.0580444	0.28
274.9718018	0.14
284.2910156	100.00
285.2946777	0.30
287.0941772	0.09
288.1968079	0.03
292.7062378	0.03
302.3604736	0.09
303.3880005	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0879
Annotation	Scopolin
Peak:m/z	Relative Intensity
126.8119431	0.04
135.0934753	0.46
155.3175049	0.01
161.0590820	0.83
171.0961914	0.02
172.9332581	0.21
179.0394897	3.49
180.0418091	0.02
189.1644745	0.05
191.0405121	100.00
218.9470520	0.01
245.1337280	0.03
306.9223022	0.03
308.4383545	0.03
309.2515564	0.05
317.3296204	0.16
322.3500061	0.02
325.1848755	0.03
335.2675171	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	531.0632
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1437531	0.04
235.0066833	1.31
246.9653320	0.18
275.1483765	0.10
277.1408081	0.03
289.1881714	0.06
291.8416748	0.06
293.0305176	39.33
301.4955444	0.09
306.7249756	0.05
310.0638428	0.03
316.4230957	0.06
318.8218994	0.06
333.6978149	0.02
334.8796997	0.64
335.4946289	0.11
337.0422974	0.08
350.3154907	0.03
351.0757446	0.07
353.2214966	0.07
365.1445923	0.62
368.8973389	14.92
369.5230713	0.10
376.9247437	0.24
378.3390503	0.46
379.1922607	4.55
382.7456055	0.13
394.9050293	2.79
395.5421753	0.11
396.9190063	0.03
410.8829346	0.07
422.2445679	0.05
424.9703369	0.58
437.1615601	3.55
441.2892456	0.13
455.0327148	100.00
455.6727295	0.34
456.8950806	0.03
471.1109009	0.71
513.0383301	4.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1307
Annotation	Galactotriose
Peak:m/z	Relative Intensity
201.0272980	0.18
219.0562134	0.07
221.0990601	0.04
243.2581329	0.05
260.9642334	0.10
363.2274170	9.48
371.3443604	0.52
378.2733765	0.09
381.1206055	100.00
381.7608032	0.20
386.8642578	0.04
395.9260254	0.30
417.4179688	0.04
421.9403076	0.09
423.0715332	0.13
435.0482178	0.07
444.7534180	0.05
452.8987427	0.39
458.8115234	0.07
464.3892212	0.10
507.1293945	0.05
524.3750000	0.04
525.4783936	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1407
Annotation	Castamollissin
Peak:m/z	Relative Intensity
163.9922028	0.09
165.1393890	0.12
167.0630646	0.04
176.9981995	0.10
179.1950836	0.04
180.0684662	0.05
189.0533142	0.05
191.1702728	0.10
192.0962372	0.15
193.0863190	0.83
194.0898743	0.03
197.1718445	0.15
205.0728912	0.11
206.9243927	0.17
208.7841797	0.05
212.0010681	0.04
213.8751831	0.11
220.1334381	0.32
223.8641510	0.04
225.1592407	0.04
229.0030518	0.20
231.3283844	0.04
233.1173096	0.06
235.1686401	0.26
239.1252289	0.02
240.1512451	0.04
245.2861328	0.08
246.0198517	0.05
247.2176819	0.02
249.1244049	0.07
251.0469971	0.04
255.1239777	0.04
257.2687683	0.16
258.7784119	0.06
260.8009949	0.17
262.8891602	0.11
265.2844238	0.07
271.3256836	0.05
273.2531738	0.15
274.8830566	0.03
278.9361572	0.02
282.1281738	0.02
285.2637939	0.16
286.2700806	0.06
287.1621094	0.20
288.3367004	0.09
293.3244324	0.15
297.4575806	0.05
298.0929565	0.14
299.1648560	0.83
300.3963013	0.07
301.3088379	0.05
302.2433472	0.11
303.2298279	1.61
305.2286377	0.07
307.2682190	0.05
311.2119751	0.10
314.1486816	7.29
315.1578979	0.64
319.3040771	0.33
323.1473999	0.15
327.3305664	0.09
329.1710205	100.00
331.3319092	0.39
337.1034546	0.48
342.0444336	0.05
345.2523193	1.09
346.2923584	1.70
347.2739258	4.63
349.3032227	0.24
353.3034668	0.19
355.2353516	1.58
357.1682739	0.13
359.2672729	0.17
367.1829834	0.06
369.2207031	0.38
371.2473755	16.21
372.9688721	0.04
374.2889404	0.03
375.2399292	0.03
377.6106567	0.11
378.9307861	0.03
380.2889404	0.03
383.4602051	0.26
385.2131348	0.24
387.2092896	0.05
388.6347656	0.39
389.3304443	3.16
397.1773682	82.22
401.1625977	1.49
401.7779541	0.07
404.4963989	0.04
405.4184570	0.06
412.2598267	0.06
413.4414673	0.06
416.0733643	0.06
419.1123657	0.22
423.2985229	0.20
428.2426758	0.08
429.5244141	0.13
430.2701416	0.08
431.3126221	0.10
432.2361450	0.04
433.3847656	0.08
447.2231445	0.36
448.9042969	0.05
450.2190552	0.03
452.4583740	0.13
455.3220215	0.12
459.3427734	0.05
460.7705688	0.10
464.5253906	0.33
465.3087769	0.22
473.2825928	0.04
474.1560669	0.12
475.0917969	0.24
475.8901367	0.23
477.5257568	0.07
478.9410400	0.04
483.1357422	0.03
487.5037231	0.34
488.4854126	0.30
489.4410400	0.19
491.2716675	0.17
501.0465088	0.03
504.3300171	1.02
505.2742310	1.04
506.1346436	0.08
507.3620605	1.31
509.3229370	0.91
510.3103027	0.05
513.5242310	0.09
517.3159790	0.15
519.2782593	0.09
520.0254517	0.13
521.5742798	0.07
522.3718872	0.02
523.0918579	0.06
524.5350342	0.18
531.4386597	0.06
533.2705688	8.51
536.3707275	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2285
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
143.1063843	0.06
149.0422974	1.40
149.9363708	0.04
152.9556122	0.02
161.1700287	0.10
165.0335083	0.03
171.5265503	0.01
179.1297760	0.46
181.2533875	0.03
191.0907898	0.35
191.9758148	0.09
203.1052856	0.05
220.7712555	0.92
221.5984192	0.03
239.0125122	0.07
240.2841797	0.02
250.0131378	0.02
251.0278015	0.21
263.0645752	0.05
275.3195190	0.05
281.0895081	0.05
287.4494934	0.01
293.1461792	0.29
310.9750061	1.75
312.0317688	0.06
313.2575684	0.05
314.1884460	0.02
315.0772705	0.35
316.2427673	0.07
317.4747314	0.01
322.3540039	0.02
330.2368164	0.04
331.0967407	0.10
332.2501831	0.06
339.7363892	0.04
357.1445618	0.02
362.3746948	0.04
375.5435181	0.04
379.4142456	0.03
386.2619629	0.04
390.4696350	0.03
431.4507141	0.05
445.3511353	0.02
447.2285767	100.00
448.2726746	3.48
449.3907776	0.02
451.1090393	0.02
458.0693970	0.08
475.3894958	0.02
476.4597473	0.03
494.0267944	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.3426
Annotation	Unknow
Peak:m/z	Relative Intensity
228.0809174	0.03
242.3968353	0.03
246.4654541	0.04
248.0576477	0.08
250.3340759	0.09
257.2463989	0.07
261.3984985	0.08
262.8725281	0.13
264.2288513	0.03
269.1410828	0.03
271.3667297	0.08
272.2615356	0.16
276.1231689	0.06
285.2535400	0.04
287.3072510	0.33
288.4759521	0.02
289.2452087	0.07
299.3326416	0.24
300.1849670	0.07
305.4219360	0.04
315.2092285	0.02
318.4149780	0.02
323.3447266	0.07
326.9725037	0.04
329.3469849	0.06
332.2162476	0.05
335.3602600	0.11
337.1516113	0.18
338.7524719	0.02
340.4750366	0.11
341.3322754	0.04
344.2653809	0.11
345.3613892	0.31
346.4689331	0.03
347.2068481	0.05
349.1441040	0.09
349.7810669	0.03
350.4241943	0.06
353.1803589	0.05
355.4763184	0.05
367.2966919	0.32
369.4213867	0.17
370.2815552	0.08
371.2823181	0.14
373.1520386	0.17
381.2870483	0.06
397.2120361	0.02
399.1777954	0.69
400.2956543	0.12
420.2158813	0.02
429.0294800	0.13
430.3151245	0.06
431.5220337	0.04
435.5875854	0.16
438.3853760	0.08
438.9960938	0.03
449.3497925	2.09
450.4660645	0.23
460.3803101	1.36
461.4788818	0.34
463.1535034	0.03
464.4591675	0.10
466.2977905	0.18
467.1737671	0.02
475.4019775	0.74
476.4822998	0.23
477.6730957	0.50
478.4019165	0.91
479.4758911	0.20
480.4865723	0.10
489.4761963	0.02
492.5320435	0.60
493.2588501	0.12
498.2963867	0.08
504.4891968	0.07
505.3381958	0.08
507.2102661	0.66
508.4042358	0.14
509.3528442	0.17
510.3717041	1.82
511.3330078	0.28
524.3026123	0.04
544.4567261	0.04
557.3884888	0.03
560.9558716	0.02
571.8898315	0.11
575.5676880	0.04
583.3693848	0.15
584.4026489	0.24
586.5812988	0.06
592.2817383	0.05
596.4024658	0.46
597.5640259	0.30
601.3457642	25.50
602.4061890	7.22
604.5299072	0.04
612.5388794	0.02
614.5786133	0.03
615.2344360	0.07
626.5367432	0.16
628.3784790	0.24
630.0622559	0.02
633.3283081	14.48
634.4558716	2.45
640.3882446	13.23
641.4301147	2.82
642.4433594	0.14
643.3707886	0.06
647.3023071	0.07
660.3630981	0.24
661.0300903	0.10
663.5194702	0.13
664.4817505	0.03
672.3748169	36.93
673.4504395	7.29
674.8926392	0.18
683.3665161	0.02
686.5269165	0.03
695.1436157	0.08
705.7389526	0.14
717.5895386	0.03
719.2420654	1.49
720.3359985	0.12
721.1918335	0.06
727.3071899	0.45
728.4752808	0.12
745.4342651	1.67
746.5525513	0.62
751.5805664	0.02
763.4309692	100.00
764.4192505	24.06
765.2630615	0.07
777.4993896	0.70
778.5079956	0.39
796.5435791	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.1291
Annotation	Viridoside
Peak:m/z	Relative Intensity
93.0185471	0.06
95.0350952	0.07
101.0009003	0.09
105.0461578	0.04
108.0508270	0.49
108.9590302	1.08
113.0536346	0.15
118.9547577	0.05
120.9685364	0.24
122.3616180	0.59
123.0162125	5.61
128.0465851	0.03
130.1089478	0.02
131.1040649	0.02
133.0543060	0.03
135.1264038	1.18
138.1328583	0.02
139.1848450	0.04
143.2788696	0.05
151.0963287	0.62
152.1475220	4.04
153.0037537	100.00
156.9897461	0.02
160.7120361	0.12
162.0468140	0.02
163.0775757	0.78
165.0902100	0.79
166.3506775	0.10
173.0384521	0.04
176.5224609	0.05
177.2005157	0.04
178.1326294	0.02
179.0712280	0.52
180.1475372	0.54
181.0786743	0.05
189.1337280	0.09
192.5347595	0.08
193.1743774	0.13
194.0252380	0.20
195.0515137	0.18
195.8871002	0.04
197.0277710	0.06
204.1540222	0.06
205.2578125	0.09
207.1329346	0.55
208.0481262	0.64
209.2610474	0.09
217.0935364	0.15
218.9586182	0.12
220.1972656	0.19
221.1096497	0.13
223.0953674	0.04
225.1174316	0.76
230.9032593	0.04
235.3633728	0.04
238.2036438	0.92
240.1701050	0.05
243.1124878	0.05
249.0920410	0.05
251.2467651	0.03
253.2899780	0.05
255.1499329	0.13
256.2000122	0.02
257.1087952	0.03
269.0347290	0.43
270.1365356	0.02
271.1336060	0.38
272.4974976	0.03
279.4161072	0.17
287.0314941	0.04
295.3487549	0.20
296.3642578	0.09
297.3955994	0.05
300.2079163	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
127.0195389	0.14
135.1192322	0.46
142.7564087	0.02
144.7127686	0.01
161.0779724	0.31
171.2690887	0.05
173.0696716	0.27
179.1293945	3.79
191.0530853	100.00
273.1540222	0.08
309.2598877	0.08
317.0853271	0.02
334.2731934	0.02
335.124939	0.02
338.0390625	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1196
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9950104	0.16
149.2868805	0.07
162.9507446	0.03
164.9587860	0.05
175.1656647	0.02
177.1299133	0.03
188.9924927	0.04
192.0469971	0.02
206.0880432	0.01
207.0591736	0.03
217.1405029	0.03
221.1853790	0.03
223.1232910	0.04
227.2162781	0.02
233.2447510	0.06
240.1460114	0.47
241.1893921	0.02
242.2591248	0.14
243.1348877	0.11
244.1949310	0.02
247.2775726	0.03
254.1208496	0.04
255.2187500	0.72
256.1978760	0.12
257.1606445	0.23
267.0674744	0.01
268.2094727	0.04
269.3008118	0.01
271.2565918	0.10
273.2960205	0.05
280.1760559	0.04
282.2151489	0.01
283.1872253	0.68
284.1169434	3.10
286.1689453	0.03
294.1684265	0.07
297.0883789	0.56
299.1142273	100.00
299.9691162	0.26
301.1560364	0.65
305.3965454	0.03
311.2763367	0.26
312.4049683	0.04
313.2968140	0.49
323.4803162	0.05
325.2707520	0.07
327.4227600	0.01
335.3931274	0.02
339.2199707	0.02
341.1894836	0.27
347.2991028	0.01
353.2106323	0.30
355.3190613	0.04
364.9481201	0.03
371.3147583	0.40
383.2813721	0.03
385.1568298	0.01
387.1069641	0.05
398.8604126	0.03
401.2902832	0.04
405.3052979	0.02
407.4779358	0.04
410.1960754	0.05
415.1714783	0.02
424.9718933	0.01
443.2278442	0.27
444.4398193	0.01
457.4559021	0.30
459.2698669	0.01
461.4068604	0.30
464.3398132	0.02
465.4324036	0.01
466.3586121	0.02
467.4351196	0.08
472.5201111	0.02
475.0744019	0.04
475.7243347	0.01
485.3633423	0.31
487.0599670	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
107.3416748	0.01
111.1940613	0.01
114.9654388	0.01
127.0104446	0.04
132.1473999	0.01
132.9874268	0.01
134.0421143	0.04
135.026001	0.91
135.9806824	0.04
142.894928	0.01
155.151474	0.00
161.0736389	0.37
162.0552063	0.01
173.1619873	0.49
179.0880432	5.70
180.1902313	0.19
191.0579681	100.00
192.0299377	1.93
198.1445923	0.02
254.1209412	0.01
265.1044922	0.01
309.0884094	0.10
309.7022095	0.01
335.2619019	0.02
336.0575867	0.01
354.1269226	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.2159
Annotation	L-Arginine
Peak:m/z	Relative Intensity
113.8763199	0.03
125.1953278	0.08
128.0433960	0.06
131.0595398	7.90
154.0110779	1.33
156.0930481	0.56
167.0702515	0.04
173.0165405	100.00
201.9456177	0.08
206.0250854	0.02
210.0833588	0.34
212.1084442	0.04
232.2207336	0.06
268.8670044	0.10
285.2807617	0.08
300.1200256	0.14
301.1583252	0.40
302.4935303	0.15
303.2773438	0.10
311.2772827	0.10
316.0890198	0.09
318.9318848	0.03
328.3171997	0.02
329.3327026	0.58
336.1537476	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2239
Annotation	S-Furanopetasitin
Peak:m/z	Relative Intensity
161.0658875	0.11
177.3070374	0.05
179.3280640	0.05
239.4824677	0.04
260.8507080	0.10
296.3521729	0.04
305.2592773	0.04
309.1858521	0.14
311.2938843	0.11
317.2785645	0.05
319.3818970	0.38
327.2278442	0.15
329.1813965	1.17
331.1871338	0.95
343.1425171	0.04
345.3048096	0.05
347.1917114	0.51
355.2402344	0.24
371.1903076	0.17
397.2297363	0.06
433.1730957	0.09
463.2944336	100.00
464.2216797	0.09
473.2573853	0.14
474.2319946	0.03
476.1227417	0.06
490.5607300	0.13
491.3074341	0.21
494.4033203	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.3411
Annotation	(20R)-3beta-hydroxy-D:C-friedoolean-7,9(11)-dien-29-oic acid
Peak:m/z	Relative Intensity
127.9831390	0.07
130.0216217	0.07
130.9903564	1.05
133.0040588	0.42
135.1504517	0.77
136.0811310	0.25
144.0726776	0.53
145.0158844	1.83
147.0926208	0.77
149.0382690	0.77
151.1154022	0.28
156.0416870	0.45
157.0328674	0.13
159.0867310	2.28
161.2185974	0.53
163.1264648	1.45
165.3235474	0.09
171.1006470	0.49
173.1669464	1.67
174.0549011	0.16
175.2055664	2.98
177.1397400	1.23
178.7930908	0.19
183.1244812	0.16
184.7485046	0.10
187.0820618	2.19
189.1092377	2.66
191.2494202	0.82
193.0180511	0.14
199.0156403	0.73
201.0861969	4.19
203.1968689	4.82
207.0521545	0.43
211.2292175	0.32
211.9375610	0.10
213.2333679	1.31
215.2223663	13.30
217.1286163	1.27
218.8617706	0.07
221.0900879	0.32
223.1287231	0.35
225.1785126	0.49
227.1766510	1.21
229.3340149	2.89
230.9894104	0.31
233.1345673	0.19
235.2835693	0.86
237.0978088	0.13
239.2850952	0.78
241.3041382	0.58
243.2634277	2.14
245.2404785	0.28
247.1820068	1.93
249.2881470	0.83
251.0867004	0.29
253.2723083	1.03
255.3222656	0.35
257.2695923	0.62
259.2383423	1.38
261.3149109	2.30
262.3994141	0.28
265.1756592	0.89
267.3808899	2.48
269.3687134	1.30
271.2265625	1.10
273.0731506	3.64
274.1885071	0.17
275.2097778	2.96
277.2882996	0.09
278.0738831	0.09
279.2945862	1.16
281.2367859	1.70
283.3190308	2.00
285.2438965	2.86
287.2883301	5.17
288.0105286	0.14
289.3434448	1.06
291.2237244	0.19
293.4275818	0.09
295.3726807	4.96
297.3007507	0.75
299.2586365	2.07
301.2188416	1.97
303.1165466	1.76
304.0894165	0.50
305.1330872	2.32
307.4936218	0.35
309.1927185	0.47
311.2584839	2.03
313.3252563	2.19
315.2633057	0.54
321.5080566	1.47
323.3930664	0.24
325.4297485	1.95
327.3418579	5.25
329.4265747	0.80
335.3122253	1.76
339.3725281	2.68
341.3172607	0.91
343.3648071	0.49
345.5184937	0.11
349.3800964	0.49
353.3709106	1.56
354.4193726	0.10
355.3476257	0.90
363.2075195	0.61
365.1380005	0.19
367.3591919	4.29
369.3555603	0.46
375.6624146	0.06
377.6688232	0.29
379.4320374	0.28
381.4534607	3.26
383.2160950	0.23
388.3003540	0.14
391.4140015	100.00
392.4093323	0.65
394.8885803	0.76
395.6000366	0.84
400.4181824	0.07
401.4627380	0.63
402.3945007	0.09
403.5775146	0.18
407.7112732	0.05
409.5221252	2.47
416.9377747	0.55
418.0929871	0.19
419.4786682	9.03
420.4802551	0.11
421.3968811	0.10
436.5166016	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.1024
Annotation	Dihydroneopterin
Peak:m/z	Relative Intensity
85.0119095	0.14
94.9703140	0.05
106.0726624	0.07
121.1018066	0.04
123.9325256	100.00
127.1332245	0.06
130.1051331	0.03
133.0998535	0.33
137.2416229	0.04
144.9929962	0.60
149.0735779	0.02
156.0714874	0.06
157.6576080	0.06
162.8158417	8.65
163.4269104	0.04
164.1944427	0.14
166.1357269	0.06
166.8971710	0.02
168.1486359	0.20
180.0982819	0.93
185.8933563	0.07
194.0053253	0.08
198.1897583	0.02
210.3688202	0.05
211.1381073	0.05
219.4939270	0.07
220.3676147	0.14
238.8451538	57.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	665.3497
Annotation	Unknow
Peak:m/z	Relative Intensity
203.1545258	0.13
235.4967346	0.12
243.3511963	0.36
269.3010864	0.28
291.3919067	0.19
292.0509033	0.36
309.5808105	0.17
311.2746582	0.27
333.5584412	0.10
363.3980103	0.11
425.3011475	0.44
450.3202515	0.29
453.3178101	100.00
454.3424683	1.39
461.7522583	0.11
469.7260132	0.23
485.1685791	0.22
510.6062012	0.15
535.4118042	0.09
537.6213379	0.15
550.8115845	0.25
561.5903931	0.11
568.3588257	0.17
577.4938354	0.12
608.6592407	0.57
611.7291260	0.07
613.2492065	0.19
619.9537354	0.14
629.5066528	0.11
632.8992920	0.10
637.5683594	0.63
638.3019409	0.35
646.6480103	0.30
647.4796753	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0879
Annotation	Castamollissin
Peak:m/z	Relative Intensity
149.2139587	0.06
150.9823456	0.73
152.9405212	0.02
163.1911774	0.03
168.2109680	0.02
168.8795776	0.04
175.4266357	0.03
179.0141907	1.20
187.0131226	0.02
189.1136017	0.22
190.0473480	0.09
191.0357361	0.12
193.3139343	0.03
196.9949493	0.04
207.1099091	0.05
215.1646729	0.05
217.1322021	0.17
218.9649353	0.02
221.0216370	0.09
228.2023621	0.05
229.0704803	0.12
231.0179291	0.07
232.0316162	0.03
233.1180420	0.09
242.2711487	0.01
243.2492676	0.05
245.1453552	0.05
246.6337585	0.03
253.3136292	0.04
254.1278076	0.04
255.0736084	0.47
256.2829590	0.18
257.2113342	0.13
258.8345337	0.02
271.1561584	0.22
271.9554749	0.02
273.2062073	0.26
281.2967529	0.03
283.0460815	0.32
285.1495056	0.02
287.1803589	0.09
295.3768311	0.02
297.2687988	0.14
300.1831665	33.39
301.1329346	100.00
302.4138184	0.02
309.2828979	0.11
311.1711731	0.03
313.1222534	0.28
319.1904297	0.18
325.2180176	0.21
327.0137634	0.09
329.0600586	0.07
331.1328735	0.07
337.1006470	0.15
343.1141357	2.67
343.8097839	0.01
344.4520874	0.02
354.3731079	0.07
355.2159424	0.16
371.2262878	0.03
373.2130737	0.47
385.3346252	0.09
394.9497986	0.04
409.3724060	0.01
415.4552307	0.04
445.2650452	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1296
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
123.0237732	0.02
125.0655670	0.16
125.7303696	0.04
145.1903992	0.04
149.3203430	0.01
151.1695862	0.05
160.7724609	0.12
165.9320068	0.01
167.0855408	1.45
177.9526367	0.01
179.0673523	0.17
180.0277252	0.18
183.2914276	0.02
185.1105652	0.10
190.9853821	0.25
197.1838684	0.06
198.3497009	0.04
205.0817261	0.06
211.1854095	0.02
213.1983185	1.72
220.9869690	0.15
227.3076172	0.08
228.1150970	0.02
230.2542114	0.02
239.3170471	0.02
241.0176086	0.05
249.2453003	0.74
251.0939331	0.23
253.0967712	0.01
255.1955566	0.15
256.5617981	0.02
257.3709412	0.07
260.8966370	0.07
269.2206116	0.07
270.5940857	0.16
271.3185425	0.29
273.0864258	100.00
277.2083740	0.09
281.4221497	0.04
282.3357544	0.04
283.1845398	0.02
285.1107788	0.37
292.1162415	0.03
297.2718506	0.66
298.1879578	0.05
300.1667480	1.36
301.0848999	3.50
302.1915588	4.55
303.2246704	0.55
304.3916931	0.04
307.2141724	0.03
308.3923035	0.03
311.5705566	0.02
314.1350708	0.14
315.2593384	0.09
316.0796509	0.15
325.2837524	0.03
328.4670715	0.05
337.3899536	0.05
339.2022095	0.23
344.2250366	0.11
345.3091736	0.16
349.2561035	0.02
350.0593872	0.04
351.3748169	0.02
363.6283264	0.04
365.3730164	0.02
370.2868652	0.02
371.5744019	0.08
375.3530579	0.10
386.6642151	0.03
388.3575745	0.07
389.3534851	0.96
390.5284729	0.11
391.2927551	0.13
392.1528015	0.02
393.4074402	0.24
399.1358643	0.05
404.2431946	0.04
406.1739197	0.04
407.1408997	0.08
415.5295105	0.17
416.2400208	0.22
417.2357178	0.43
420.2240295	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	739.147
Annotation	Prunin 4'',6''-di-O-gallate
Peak:m/z	Relative Intensity
241.1431274	0.01
263.1997681	0.10
264.1380005	0.07
269.3838501	0.02
287.2206116	0.03
288.0315552	0.02
303.2208862	0.11
304.3229370	0.01
305.2025757	0.04
307.0923462	0.01
309.2927246	0.01
314.1634521	0.03
315.3120117	0.02
328.2946167	0.03
328.9338989	0.01
330.8948364	0.01
342.1569214	0.02
345.2576294	0.60
354.9278870	0.01
357.4656982	0.03
367.4175415	0.03
372.2687378	0.01
384.3154907	0.02
392.4379272	0.02
396.1420898	0.01
409.2536011	0.03
414.8621826	0.04
423.2168579	0.03
427.4133301	0.03
435.1868286	0.12
436.5477905	0.10
437.5568848	0.03
439.2857666	1.17
449.4465332	0.01
450.0486450	0.03
466.1506348	0.01
475.4996948	0.05
477.4160156	0.18
478.2805176	0.01
481.2098389	0.09
491.5153809	0.02
499.3316040	0.01
525.4705811	0.01
535.4497070	0.03
540.3068237	0.05
541.4702759	0.02
543.1184692	0.01
546.5730591	0.11
547.2796021	0.04
558.6378174	0.06
559.5426025	0.06
564.1040649	0.03
567.0792847	0.03
571.2587280	0.21
575.1962280	0.11
576.2367554	0.12
577.1911011	0.10
579.4684448	0.01
587.3386230	0.05
588.5444336	0.17
589.3171997	0.50
592.1076050	0.02
594.4221802	0.01
600.0386353	0.04
605.4781494	0.27
607.2274170	100.00
607.8468628	0.48
609.3339844	0.02
615.3110962	0.02
616.1052246	0.01
621.0805054	0.02
636.0510864	0.06
641.4174194	0.01
648.4633789	0.03
649.1041260	0.07
653.1007690	0.04
657.4175415	0.10
663.6860962	0.01
672.5654907	0.07
684.1774292	0.02
694.1633911	0.03
695.6141357	0.01
712.5388794	0.02
720.2008057	0.03
721.3944702	0.27
738.7644653	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2186
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
150.1737518	0.02
152.9408417	0.03
165.1255188	0.02
175.0914307	0.06
177.1795959	0.07
193.1328430	0.09
195.2400970	0.30
235.1938171	0.06
236.9942017	0.09
256.8664551	0.08
261.2413940	0.02
285.4627686	0.02
289.4097595	0.06
293.5009766	0.04
296.3496399	0.02
298.1232910	0.08
301.2156982	0.58
303.5880127	0.02
307.3955078	0.05
312.4994507	0.11
317.1271362	0.02
318.4710693	0.08
323.2690430	0.04
325.1404419	0.04
327.2935791	4.54
329.2304688	0.01
334.0517578	0.02
340.8056030	0.09
343.2203369	0.94
346.3444824	0.07
349.1923218	0.02
353.2536621	0.11
357.3972778	0.02
360.2301636	0.04
361.4519043	0.92
373.7232666	0.07
375.0272827	0.03
377.3156128	0.08
381.2788086	1.27
391.2315063	0.14
397.1009521	0.47
397.7609863	0.04
404.9950562	0.04
413.5108643	0.06
431.3259277	0.02
432.2354126	0.01
433.3625488	0.04
441.8135376	0.02
445.7281494	0.02
447.2230225	0.03
448.3656006	0.02
450.3540649	0.06
455.3134766	0.06
459.3712158	0.03
472.3915405	0.18
473.4044189	0.03
475.2992554	100.00
477.4240112	0.16
478.4731445	0.02
480.5302734	0.05
487.2540894	1.27
490.4026489	0.04
491.3877563	0.29
492.4663696	0.26
496.2941284	0.05
504.3556519	0.44
505.3490601	2.05
509.1953735	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	436.22
Annotation	Unknow
Peak:m/z	Relative Intensity
132.2996521	0.10
135.1933746	0.42
147.0457458	0.25
149.2830505	0.10
152.9548645	0.08
161.1752319	0.09
171.1191864	0.31
196.9776764	0.11
207.2970123	0.10
210.8830566	0.36
213.0587921	0.08
224.9784546	0.05
229.2039185	0.12
230.9131012	0.24
233.1742249	0.07
233.9946899	0.05
251.6210327	0.20
255.1264038	0.06
256.1574707	0.08
256.9694519	0.23
259.0314026	0.12
260.3339844	0.11
261.2184753	0.07
265.1558838	0.19
272.0674438	0.20
273.3036194	0.04
279.9782104	0.09
283.9608154	0.06
291.7040710	0.06
293.1617432	0.03
295.1058044	0.22
303.0960083	33.94
304.1918335	100.00
304.9649048	0.10
306.4996948	0.04
313.1392822	0.08
321.1698914	0.36
331.0523682	0.07
335.5395508	0.07
336.4132996	0.27
337.4568481	0.13
341.3070068	0.06
345.8070068	0.31
346.9327698	0.19
347.5496216	0.05
349.8168945	0.18
351.1914368	0.06
353.8085022	0.20
355.6449280	0.14
359.1080322	0.10
365.1401367	0.57
367.5283508	0.05
369.0281677	0.23
370.2453308	0.79
371.6824646	0.14
375.1713867	0.08
375.9908447	0.03
378.1826782	0.08
381.5165710	0.10
383.2250366	0.88
387.1310120	0.24
388.0791931	0.16
389.2499084	0.08
390.3171082	0.39
391.1207275	0.20
393.0195312	0.03
398.0540466	0.20
399.1856384	0.49
400.1983337	2.55
401.1823120	0.96
405.6280518	0.06
417.5629272	0.65
418.1839294	4.31
419.1914368	0.45
421.4328613	0.27
426.9929810	0.28
437.3932190	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.0771
Annotation	alpha-(1,2-Dihydroxyethyl)-1,2,3,4-tetrahydro-7-hydroxy-9-methoxy-3,4-dioxocyclopenta[c][1]benzopyran-6-acetaldehyde
Peak:m/z	Relative Intensity
104.9512329	0.07
107.0852814	0.02
109.0200806	0.12
112.9549637	0.04
121.0535126	1.75
123.0665588	0.67
124.9270477	0.17
127.1216278	0.03
137.0632935	3.42
138.0543213	0.18
139.1555481	0.15
143.2721558	0.03
146.9832001	0.12
149.0744019	0.85
151.0899353	0.04
153.0704498	1.25
163.1051025	0.08
164.1430817	2.46
165.0055542	44.08
165.9728088	0.46
167.1030884	1.55
177.2277374	0.02
178.9714661	0.20
180.0071716	0.06
181.0962830	1.47
182.0435791	0.13
191.2190247	0.01
193.0958252	11.43
195.0570526	0.07
197.0025177	0.71
202.0984497	0.14
203.1629791	0.06
204.1429138	0.24
204.9381409	0.03
207.1694336	0.06
208.0636902	0.05
211.2712097	0.03
213.2077332	0.03
217.1615295	0.26
218.4896545	0.15
219.1544189	0.25
221.1243286	0.10
231.1305847	0.15
233.1944580	0.39
234.2630310	0.04
235.4096069	0.06
236.1623230	0.09
243.1503601	0.05
244.1129456	0.70
245.2427979	0.05
246.2524414	0.75
246.9985657	0.12
247.6154175	0.02
249.2622375	0.06
251.2178650	0.34
259.2256775	11.84
261.1295166	100.00
261.9238892	0.03
263.1264648	0.39
267.4107971	0.05
270.2841187	0.03
271.1745300	0.12
272.1989136	0.03
273.2595215	0.04
275.2849731	0.67
277.1871338	0.60
279.1785278	0.51
283.2290649	0.12
285.1218262	0.32
286.2110596	0.07
287.2296143	0.15
288.2659912	1.26
299.9427185	0.02
301.1873169	4.50
303.1307068	37.65
303.8643799	0.19
305.2404785	0.43
309.8560791	0.05
311.3207397	0.26
314.3860168	0.17
315.0946045	0.04
316.3277588	0.04
317.3228760	0.05
319.2280884	10.62
327.4271240	0.04
329.2215576	6.86
331.1567688	0.42
332.1128540	0.28
347.2884216	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.167
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0260315	1.56
191.0177612	0.09
207.0883942	100.00
207.7656250	0.09
236.3561707	0.06
237.2268372	0.88
263.9562683	0.17
267.2205811	0.11
311.4069824	0.37
323.4831543	0.24
341.3066406	0.10
356.3532715	0.08
386.2967529	0.10
421.2119141	0.21
459.0389404	0.24
473.2964478	14.74
474.4503174	0.74
475.3450928	0.37
476.3444824	0.06
503.3051147	31.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1352
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
164.3125916	0.04
171.1883240	0.07
173.2602844	0.17
174.0641174	0.02
175.0127106	0.12
177.0549927	0.12
178.6634827	0.04
179.2772369	0.03
180.3480377	0.02
183.0491791	0.03
187.1374969	0.09
187.9116211	0.04
196.3191223	0.03
201.1484985	0.05
201.8851624	0.04
203.1398010	0.58
204.2484131	0.04
205.1943054	0.46
215.4172974	0.06
217.1765442	0.05
219.1978455	0.05
221.0098877	0.12
222.2602997	0.03
226.0023346	0.04
227.1582336	0.06
229.3004761	0.04
230.2732086	0.02
231.3174438	0.10
241.0652466	0.07
243.2338715	0.21
245.0792694	2.64
246.1392059	0.35
247.2465973	0.10
256.1956177	0.14
257.1863403	0.33
259.0596924	0.03
269.2138367	0.50
271.2526245	0.11
273.1799316	2.16
274.2601318	0.08
281.0900269	0.08
285.1926880	0.09
287.1238708	8.83
288.2893677	1.04
289.1785583	19.31
290.1987915	3.29
291.1506348	0.04
297.2955322	0.06
299.1193237	6.10
300.1605835	0.96
301.1752930	0.05
302.2758179	0.08
313.2662354	0.04
325.5433960	0.05
327.4302979	0.06
328.4683838	0.15
329.2760010	0.31
330.2362671	0.30
331.3338623	0.87
332.3079224	0.11
339.2631226	0.14
340.3831177	0.09
341.2147827	0.29
347.2921753	0.04
357.2810059	0.60
363.2178955	0.01
364.2340698	0.02
365.1029663	0.08
369.2266846	0.05
371.0102539	0.04
381.3391724	1.05
382.3726807	0.20
383.3533936	0.08
389.3246460	0.04
390.2774048	0.03
393.4037476	0.22
405.3402710	0.08
407.2249146	46.87
408.3141479	8.63
409.2444458	0.64
410.3040771	0.20
411.3112183	0.27
412.2529907	0.05
413.1713867	0.03
423.3460693	0.18
425.2138672	100.00
426.1852417	15.93
429.4428711	0.02
433.3373413	0.29
434.2797241	0.02
435.3412476	0.11
437.2604980	0.22
438.3291016	0.12
449.2353516	0.74
451.2219849	29.20
452.3278809	5.33
454.3532104	0.04
456.2196655	0.01
467.3689575	1.23
468.3322754	0.24
471.2172852	0.06
474.5922241	0.07
489.2054443	0.01
491.2396851	0.07
492.0580444	0.06
493.3616333	0.10
496.3189087	0.12
515.4877319	0.33
516.3500977	0.13
519.1790771	0.03
531.1489868	0.14
532.7465210	0.13
533.3842163	1.71
534.2991333	0.40
541.4168091	0.06
542.3097534	0.05
559.3153687	10.91
560.2924194	2.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.0226
Annotation	Unknow
Peak:m/z	Relative Intensity
107.0773544	0.05
121.2067795	0.07
122.0107269	0.04
123.9632645	0.03
136.1398926	0.15
136.8980713	0.04
151.0847778	1.47
152.0573120	0.30
153.1838989	0.05
162.2143097	0.04
163.0343628	0.11
164.1759644	1.33
165.0152740	7.04
166.0514069	0.75
174.2289124	0.07
179.0283661	4.70
179.9744568	0.19
187.0778809	0.03
188.2350616	0.07
190.2372437	0.11
191.0412445	0.17
192.0514374	0.46
193.1465454	0.28
200.2999268	0.02
202.1752930	0.05
204.0828552	0.33
206.0685730	0.09
213.0164795	0.05
214.0548706	0.63
215.3294373	0.17
216.2438354	0.48
219.1119995	0.13
223.0935669	0.06
226.9444275	0.40
229.1427612	0.08
231.2187500	0.09
232.1613464	0.61
235.0341797	0.06
242.1110840	5.11
243.1493530	0.96
244.1762085	2.51
245.1457825	0.07
247.3261719	0.03
248.0524902	0.03
254.2747803	0.12
255.1799927	0.03
255.9669189	0.07
259.0676575	0.99
260.0911865	0.28
270.0830078	36.26
271.0878906	100.00
272.1965027	0.80
273.0548706	0.03
274.2101440	0.03
279.0664673	0.04
283.0364990	0.07
284.2617188	0.03
287.0845947	34.04
288.0760498	12.06
288.7491455	0.03
295.1825562	0.07
299.0147095	0.29
300.1467896	2.29
301.1943970	0.52
316.1787109	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1039
Annotation	Castamollissin
Peak:m/z	Relative Intensity
161.0675964	0.06
163.0146484	0.03
165.1589813	0.05
167.1226807	0.02
189.0957642	0.07
191.0480042	0.18
203.1157227	0.03
205.2529144	0.11
206.9091644	0.03
216.4309082	0.10
217.2609711	0.10
228.3000946	0.02
229.2978516	0.07
231.1212616	0.21
233.2275085	0.09
234.1895142	0.03
242.1293335	0.03
243.6585846	0.04
245.0996094	0.15
253.2375488	0.02
255.1638184	0.05
256.3817444	0.15
257.3447266	0.05
259.2031555	0.02
261.2650146	0.46
266.9577942	0.04
269.1556702	0.10
271.1098938	0.47
273.1818542	0.51
274.2808533	0.02
280.3288574	0.04
280.9537354	0.09
283.1794739	2.34
284.5026245	0.08
285.2123718	0.09
286.1115723	0.06
287.2179565	0.29
289.2994080	0.06
292.0042114	0.08
295.2670288	0.17
297.2167358	0.32
298.1068726	0.21
299.2178345	0.84
300.0982056	1.62
301.3448181	0.34
310.0152283	0.03
310.9844360	0.35
313.3819580	1.25
314.1550903	22.21
315.1436768	100.00
315.8881836	0.36
317.1768494	0.26
319.0535889	0.06
324.0805969	0.10
325.2726440	0.36
327.1452026	2.01
329.2284546	6.06
331.2502747	0.09
332.9864502	0.11
337.2259521	0.59
339.1553345	1.07
341.1397095	0.10
342.1629028	0.04
343.2353516	0.19
345.2940063	0.07
348.9414673	0.06
351.2042847	6.12
353.5683594	0.03
354.3318481	0.03
355.2388916	0.11
357.2256470	3.77
367.1428223	0.03
369.3109131	1.36
370.3576965	0.03
373.1285400	0.05
377.1366882	0.02
381.1976624	0.54
385.3108215	0.20
387.1431580	1.26
389.4969177	0.04
399.1795349	0.14
409.1648254	0.26
415.3633423	0.02
417.1213684	0.35
418.1062927	0.03
423.3695068	0.12
427.1582947	0.09
431.2560120	0.60
432.3794861	0.10
433.2167053	0.30
435.5922852	0.15
441.4563293	0.32
445.2088928	1.86
447.3991089	0.03
449.4242859	0.08
459.3348083	1.74
462.2742310	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1482
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.1109772	0.47
165.0738068	1.37
167.1037903	0.61
173.1973419	0.11
177.0256348	0.20
183.1045380	0.40
187.2251587	0.21
191.2174683	0.14
193.1146240	0.11
199.1535950	0.15
200.9016876	0.62
203.1763000	0.11
224.9146729	0.08
227.2434082	0.10
229.0544281	1.14
242.9493408	1.20
244.9973297	0.09
247.1165161	21.84
248.1592712	0.13
248.9915466	0.52
255.2114410	0.09
256.9169922	0.16
259.1487427	3.57
261.1060486	0.37
271.0804138	3.68
273.0762939	2.30
273.7436523	0.33
275.0754395	5.66
283.1087646	1.81
284.9166870	0.06
287.0567017	1.52
289.1525269	14.77
291.0780945	58.09
297.0637207	0.29
299.1734619	1.09
301.0797729	22.35
303.2432251	4.83
311.3656006	0.09
312.8874817	0.61
315.0483093	0.56
317.3471069	0.10
319.3840942	0.22
325.2847900	0.08
331.0498657	0.27
333.2423706	1.58
343.1835327	0.13
357.2138062	0.37
375.1727905	0.33
381.1539917	0.32
391.3681641	0.23
393.3800659	0.12
398.1361084	0.08
399.1857910	0.19
401.8316650	0.06
402.5916138	0.07
405.3759766	0.40
407.3833008	0.07
409.1507568	51.84
410.0495605	0.83
411.3099365	16.16
416.4708252	0.11
421.1508179	2.27
423.6547852	0.74
425.1298828	1.03
427.1882935	100.00
435.3327637	3.66
439.2373657	4.43
447.1864624	0.16
448.3667603	0.72
451.4965820	0.33
453.2224121	9.26
457.4640503	0.45
488.7572632	0.13
525.5491943	0.16
541.6334229	0.17
542.3980103	0.44
543.2483521	3.11
558.9221802	0.49
560.3820801	0.48
561.2723999	4.64
568.4836426	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.13
Annotation	Castamollissin
Peak:m/z	Relative Intensity
149.0360413	0.92
151.0690002	0.03
160.8834839	0.03
163.0629730	0.08
164.3183899	0.07
165.0463562	0.77
167.0526428	0.11
175.1329498	0.18
176.1250916	0.10
176.9766541	0.02
179.2298889	0.03
181.0189362	0.13
183.2429810	0.04
187.3011475	0.05
189.4039917	0.02
191.0115662	0.21
192.0885925	0.59
193.0986633	2.96
195.0293732	0.04
197.2814941	0.05
203.1621704	0.09
207.1534119	0.23
211.3308868	0.11
217.1563416	0.09
219.0625916	0.05
221.1891632	0.14
223.3766479	0.06
224.2591248	0.04
233.2413025	0.05
235.3817444	0.10
237.3361206	0.03
239.3073730	0.35
242.1434631	0.05
243.9786530	0.09
245.3693695	0.07
246.9516296	0.04
250.7080688	0.05
257.1294556	0.08
258.1738892	0.03
259.2308350	0.29
260.2218018	0.10
261.2050171	1.11
265.0799866	0.18
269.1925659	0.18
275.2418823	0.08
279.2138062	0.03
282.1400757	0.03
285.1435547	0.14
285.9973145	0.32
287.0535889	0.19
288.2389221	0.03
289.3117676	0.02
293.1026611	0.15
294.1389771	0.03
297.3986816	0.09
299.3159790	0.37
301.3215332	0.39
303.2060547	3.25
305.2218018	0.13
307.0380859	0.03
309.2801514	0.03
311.1547241	0.59
311.7633667	0.03
313.4655762	0.24
314.1345215	1.59
315.3425293	0.25
318.1948853	0.03
319.2247925	0.74
321.0089111	0.05
324.3065186	0.04
326.1882935	0.09
327.0676880	0.11
329.1759644	100.00
330.0272827	0.18
331.2705688	0.51
333.2711792	0.11
337.0501709	0.03
341.3101196	0.39
343.4176025	0.16
345.1956787	0.67
346.2176514	4.43
347.1888428	32.33
349.4315186	0.05
355.1964722	30.15
356.9495239	0.09
359.2021484	1.13
371.0836792	0.18
372.3852539	0.03
373.4132080	0.02
377.3745728	0.07
381.3524170	0.20
383.2171021	0.16
387.3525391	0.03
389.0952148	0.62
401.0479736	0.03
403.3064575	0.05
413.2856445	0.03
419.2849731	0.13
421.3040771	0.04
422.2857666	0.34
422.9751587	0.18
425.0223999	0.08
436.4277344	0.02
437.2557983	0.19
441.1231079	0.04
463.2699585	27.80
465.2979126	1.39
473.4268188	0.03
491.2839355	3.39
493.4478149	0.03
494.2108765	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0719
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
107.9229584	0.25
108.9920731	6.26
113.0069733	0.06
119.0980606	0.11
120.0372696	0.03
121.0170593	0.05
121.9117737	0.03
123.0551910	0.09
124.9509811	0.03
131.1008148	0.06
135.0611267	0.54
143.0421143	0.15
152.9548187	100.00
160.0222168	0.07
163.1217041	0.09
165.1462555	0.06
166.9291077	0.23
177.0815430	0.94
179.0497589	0.04
191.0173645	0.04
193.1453552	0.02
195.0227051	6.01
205.1835327	0.17
214.1647644	0.07
219.3516541	0.13
223.1121826	0.14
225.0900574	0.36
231.1597900	0.21
247.0945435	0.06
251.3452148	0.04
255.1312866	6.22
268.8418274	0.23
270.2536011	0.08
271.1238708	0.06
279.1715698	0.04
284.1896362	0.09
287.1213989	0.05
288.0665588	0.04
297.1995850	0.24
299.2371826	0.03
300.1553955	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.0911
Annotation	Avicularin
Peak:m/z	Relative Intensity
219.1742554	0.01
245.0848999	0.01
258.9815063	0.01
273.1546936	0.07
301.1484375	0.01
303.1323853	100.00
303.9521790	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	821.1884
Annotation	Unknow
Peak:m/z	Relative Intensity
310.3195190	0.06
311.3738403	0.02
347.2302246	0.06
362.2366333	0.12
368.5313721	0.25
431.6284180	0.09
457.3495483	0.08
461.4005737	0.21
463.1554565	0.10
479.3190918	0.33
489.7668457	0.09
491.4596558	0.16
502.9508667	0.16
505.5330811	0.05
519.4946899	0.11
545.5859985	0.05
551.1684570	0.23
563.7885132	0.17
567.5100708	0.08
573.4793701	0.02
577.1259155	0.05
590.2294312	0.19
595.3701172	0.06
597.5466309	0.14
614.4824829	0.06
615.4246216	0.17
616.3120728	0.13
617.4348755	0.39
624.3501587	0.05
631.1396484	0.09
641.2738647	0.59
643.8229370	0.31
657.2357788	0.08
659.2998047	100.00
659.9365845	0.60
671.5341187	0.06
674.4838867	0.07
683.3007202	0.13
691.6479492	0.11
695.3807983	0.06
712.2978516	0.09
714.2221069	0.05
720.2382812	0.10
731.4885864	0.06
739.3679199	0.11
751.6871948	0.15
769.0651855	0.03
774.9201050	0.09
784.8527222	0.02
785.5981445	0.16
789.4963989	0.04
802.5991211	0.39
803.5425415	0.32
804.2578735	0.08
805.3118286	0.07
806.3704224	0.06
820.8892822	0.04
821.6578979	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.3422
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1127777	0.04
238.0676270	0.04
246.3830566	0.06
250.1444855	0.03
257.0763245	0.04
258.2922974	0.02
261.1922302	0.09
270.9155273	0.06
279.4161377	0.02
287.1305542	0.13
288.0395203	0.01
289.4683228	0.02
294.9655151	0.02
297.3681946	0.03
299.4399414	0.11
305.1527405	0.01
309.1604614	0.02
317.0770874	0.05
325.0124817	0.01
326.3623352	0.03
331.1486206	0.07
332.2098083	0.02
337.4572144	0.06
341.0946960	0.04
345.4646606	0.02
347.2373962	0.05
349.1386108	0.03
359.2672729	0.03
367.0441284	0.06
368.3571777	0.02
371.3777466	0.21
372.3363342	0.09
373.3706665	0.01
385.3486938	0.03
397.4831543	0.10
398.6239624	0.03
399.2462158	0.07
407.6810303	0.02
438.5023193	0.02
442.2562866	0.01
448.0632324	0.02
449.3668213	0.67
450.3721924	0.12
460.4153442	0.61
461.4802246	0.14
464.4971924	0.03
465.3177490	0.06
466.1679688	0.06
467.5123291	0.08
471.0739136	0.02
472.1885986	0.02
475.6577148	0.03
476.7429810	0.03
477.5827026	0.02
478.3463135	0.42
479.3057861	0.16
480.7100830	0.02
482.8073730	0.02
485.5139160	0.01
486.4561157	0.03
492.1893311	0.04
493.3859863	0.15
494.2666626	0.04
495.5170898	0.01
500.5171509	0.03
505.1414795	0.01
509.2319946	0.16
510.3470459	0.17
511.3980103	0.13
542.7284546	0.05
550.3554077	0.01
557.3350220	0.04
569.3921509	0.01
572.8892212	0.19
583.3143311	0.03
587.3555298	0.03
589.2221069	0.03
596.4710693	0.19
599.2648315	0.02
601.3634644	4.89
602.4721069	1.73
610.5623169	0.03
615.2094116	0.02
616.3457642	0.03
622.4899292	0.04
627.3071899	0.04
628.2086792	0.01
633.3026123	2.01
634.3654785	0.63
640.3908691	2.77
641.4685669	0.92
642.5331421	0.11
643.3670654	0.05
651.2535400	0.04
661.8154907	0.04
663.3522339	0.07
664.4359741	0.05
672.3613892	6.04
673.4171753	1.56
674.6237183	0.07
675.5554199	0.03
692.1273804	0.02
693.5597534	0.02
703.6397095	0.02
709.0710449	0.02
714.8630981	0.02
719.2540894	0.23
720.3429565	0.07
727.4284668	0.04
728.3367310	0.02
733.4238892	0.04
745.3967896	0.49
746.4876099	0.17
747.4572754	0.03
752.4464722	0.01
753.5860596	0.02
757.6452026	0.01
759.7482910	0.06
763.4370728	100.00
764.4468384	33.51
765.1082764	0.17
768.2507935	0.03
777.4547119	0.26
778.3305664	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.09
Annotation	3,4',5,6-Tetrahydroxy-3',7-dimethoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
150.9387512	0.40
161.0221710	0.04
163.2842407	0.12
164.5371704	0.05
165.1855469	0.06
177.2156982	0.06
179.0342407	2.83
182.8345795	0.05
191.3142090	0.04
192.2819824	0.22
193.4408569	0.06
197.0874329	0.09
199.2825928	0.06
205.1297607	0.03
206.0985413	0.16
207.0643311	0.51
209.2622986	0.29
211.1209106	0.13
217.1530914	0.08
219.1883545	0.03
221.0865784	0.11
227.1605377	0.14
228.9985199	0.15
232.3073425	0.09
233.2344208	0.06
235.3251953	0.05
242.2306824	0.30
244.3580017	0.05
245.1860962	0.16
249.2112122	0.11
255.2400665	0.22
259.1569824	0.41
262.9480591	0.05
264.9339294	0.12
267.0708923	0.07
269.3758545	0.09
270.1901855	0.84
271.1643066	2.92
272.3180542	0.06
273.0567017	0.03
281.1364136	0.04
284.2676392	0.06
285.1527405	0.05
287.1917725	1.16
288.2249146	0.08
289.1754150	0.20
291.1374817	0.12
295.2272339	0.22
299.1448364	0.72
301.0866699	0.21
303.1604004	0.04
304.1595459	0.08
307.0406494	0.04
308.0819702	0.04
313.1557007	0.18
316.1029663	100.00
317.1043091	34.87
318.2916870	0.14
319.2344971	0.08
323.0864258	0.03
325.2489624	0.05
326.0969849	0.11
327.2364502	0.51
329.2374878	0.97
337.1412964	0.49
339.3581543	0.08
341.1691895	0.57
351.0986328	0.05
354.0800171	0.14
357.4873047	0.23
359.0645752	1.67
361.4490967	0.07
366.3474121	0.04
369.2144775	0.52
371.2981567	0.14
377.2465820	0.11
383.2072144	0.08
389.3034668	0.59
391.4008179	0.08
394.2669678	0.07
395.2772827	0.50
397.2761230	0.04
401.2942505	0.04
402.1560059	0.07
411.3040161	0.32
419.7279663	0.06
431.1591187	0.15
441.6283569	0.07
443.4523926	0.07
458.9359131	0.17
459.7716675	0.04
461.2058105	0.88
463.3490601	0.07
471.5315552	0.04
475.2445068	0.70
477.3284912	1.16
479.1986694	14.51
480.2731323	0.27
485.2728882	0.30
489.2663574	2.10
490.0780640	0.10
501.4520874	0.08
502.2549438	0.10
503.2413940	3.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1194
Annotation	Unknow
Peak:m/z	Relative Intensity
136.9563751	0.04
147.1107330	0.04
148.1095886	0.04
149.0132446	2.82
150.0215759	0.29
151.0211182	0.08
162.9045715	0.09
164.0594482	0.08
165.0545197	0.23
166.0045624	0.32
167.0780334	0.07
168.3607178	0.03
173.0608521	0.02
175.8410034	0.03
177.2123718	0.12
178.9748230	0.09
182.2368011	0.03
189.1217804	0.03
191.1429291	0.34
192.0202637	0.68
193.0614319	1.54
194.0412598	0.42
197.1288452	0.06
202.9180603	0.03
205.1211243	0.06
206.5746765	0.08
207.2847900	0.23
217.1879425	0.06
218.7900696	0.02
219.8633881	0.20
221.1988525	0.03
223.9213867	0.06
227.1374817	0.05
230.9879456	0.08
233.0766907	0.03
234.2284088	0.02
235.1490021	0.14
237.8705444	0.03
247.2651672	0.10
257.0334778	0.06
258.0236511	0.04
260.2254333	0.21
261.1094971	0.04
262.2887268	0.06
265.1804199	0.31
272.1962891	0.02
273.5231628	0.01
275.4816895	0.09
276.2838745	0.03
279.1486511	0.04
281.1376648	0.46
282.1154175	0.15
285.2977295	0.03
286.4336853	0.02
288.2172546	0.03
289.1714172	0.20
293.0858459	0.09
297.3544922	0.13
299.2484436	6.76
300.2213745	1.69
301.1835327	0.04
302.4383545	0.28
303.2601013	0.96
304.3848267	0.20
305.0673828	0.08
312.6665039	0.03
314.1054688	0.49
315.2672119	0.73
316.1792603	6.40
317.1375122	4.93
318.1997375	1.17
319.1405640	0.38
320.2283630	0.04
325.1630554	46.80
326.1424866	9.84
327.0970459	0.02
329.1567383	100.00
330.2264404	25.51
333.0541687	0.02
335.2599487	0.02
339.0066223	0.03
343.4210510	0.08
345.3962402	0.65
346.2691650	4.80
347.2057190	14.20
348.2677612	2.66
350.3695679	0.08
355.1779785	0.04
357.3373413	0.05
359.1559448	0.27
360.0655823	0.08
372.2121582	0.09
375.1084595	0.17
376.4547729	0.04
383.3097229	0.04
385.2713928	0.07
389.1846619	0.64
390.2010193	0.04
392.3553467	0.20
393.2842712	0.21
394.2102051	0.03
395.5397034	0.05
401.0662842	0.10
413.1033325	0.09
419.2764587	0.25
420.2313538	0.03
431.4530029	0.07
433.2263489	0.11
435.0919495	0.68
435.7724304	0.04
436.5610962	0.16
437.5258484	0.04
451.6021423	0.11
461.2202759	2.87
462.2444458	1.32
463.2733765	0.04
465.3131714	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.24
Annotation	Ethyl 3-hydroxyoctanoate O-[glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
149.0669556	1.17
149.9476013	0.62
150.9007263	0.11
152.9916077	0.05
153.6171265	0.09
157.1435089	0.02
160.9639893	0.06
163.0740814	0.14
164.1324158	0.06
165.0845642	0.51
166.0677948	0.77
167.1863708	0.42
168.0238495	0.16
169.1425018	0.05
171.0928650	0.03
176.1431274	0.04
177.0585632	0.04
178.1801147	0.05
179.1334839	0.07
180.2012024	0.05
181.2582092	0.02
191.0645599	0.33
192.1454468	0.60
193.0818481	3.71
194.0129089	1.86
195.1023560	0.35
197.0818787	0.26
197.9160461	0.08
203.9005127	0.11
206.1894684	0.25
207.1448669	0.23
208.0048523	0.18
208.9936218	0.08
211.3712769	0.04
217.1822510	0.02
218.2682190	0.04
219.3897247	0.08
220.0903625	0.17
221.1463318	0.32
222.2583160	0.03
223.3302002	0.07
229.1158447	0.03
230.2374268	0.09
233.2729187	0.06
235.1883392	0.11
236.0652771	0.05
237.2421112	0.06
239.2120361	0.14
240.0703735	0.20
240.8770905	0.04
244.3518524	0.06
245.2822876	0.17
246.2388611	0.24
247.3779297	0.05
250.0061340	0.14
251.1399536	0.14
257.0212708	0.03
258.4467773	0.03
259.3841553	0.09
260.1167603	0.29
261.1845703	0.93
262.2788696	0.79
263.3261108	0.25
265.0891724	0.14
267.3084717	0.04
270.1743469	0.04
271.2296143	0.05
273.1985779	0.15
274.1503296	0.13
275.5766907	0.09
276.2144775	0.05
278.0622559	0.04
281.3991089	0.05
282.2783813	0.19
283.5949097	0.03
284.2224731	0.03
285.1852417	0.03
286.4229126	0.28
287.3980713	0.04
288.1242676	0.08
289.2826538	0.08
290.3249512	0.08
294.2732544	0.08
296.1564941	0.08
298.2326050	0.04
299.1815186	0.12
300.6466980	0.11
301.4268799	0.28
302.4680176	0.13
303.1126099	1.40
304.2611694	2.74
305.3157959	0.42
305.9403076	0.05
311.1945190	0.63
312.3140259	0.40
313.2616577	0.02
314.2342529	0.91
315.2869873	1.42
316.3833618	0.28
317.1899414	0.08
319.3213501	0.53
320.3103638	0.63
321.4063110	0.15
322.1016235	0.04
325.2993164	0.03
327.2271118	0.21
329.2243652	45.62
330.1954346	100.00
331.2171631	17.68
332.1646118	0.43
333.6304932	0.04
334.5565796	0.04
341.1339111	0.27
342.2252808	0.30
343.1608887	0.20
344.2621460	0.10
345.2668457	0.11
346.2791138	1.92
347.2362671	26.53
348.2047729	47.52
349.2356567	7.65
350.2269287	0.04
355.2172852	17.42
356.1900635	29.27
357.1820068	6.39
358.1845093	0.31
359.2853394	0.71
360.2940674	1.66
361.3145752	0.16
363.1671753	0.05
364.4344482	0.13
367.0317383	0.07
370.3784180	0.14
371.2919312	0.12
372.2327881	0.23
373.2028809	0.25
374.1716919	0.10
375.7658081	0.07
377.2652588	0.02
378.3327637	0.14
381.1613770	0.08
382.2286987	0.09
383.2531128	0.08
384.3673706	0.14
385.4229736	0.10
389.2059937	0.11
390.3242798	1.09
391.4196777	0.32
394.2313232	0.05
397.4041748	0.02
400.8215332	0.24
402.1901855	0.45
415.0932007	0.10
418.3095703	0.03
419.4077759	0.02
420.2523193	0.15
420.9401855	0.02
422.6468506	0.20
423.4177246	0.26
424.4901123	0.24
425.3407593	0.18
426.3801880	0.02
432.0396118	0.13
436.6276245	0.05
439.1980591	0.10
442.4946899	0.02
447.4860229	0.03
448.5606079	0.04
450.3085327	0.22
451.3256226	0.03
455.4355469	0.02
461.3018799	0.06
463.2723999	0.75
464.3150635	18.42
465.3308105	8.08
466.3911133	1.61
467.4105835	0.49
469.1370850	0.15
472.9291992	0.05
474.2780151	0.26
478.3242188	0.10
479.4357910	0.13
490.4600830	0.07
492.2461548	5.67
493.2787476	1.28
495.3901978	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.1074
Annotation	3,4',5,6-Tetrahydroxy-3',7-dimethoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
168.7069397	0.25
205.0223694	1.25
280.8442993	0.20
283.6981506	0.19
290.0371704	0.36
293.3691406	0.22
297.3327637	0.54
317.2581787	3.33
318.0181274	3.52
319.1849365	100.00
329.0249634	0.77
342.4174805	0.14
343.0816650	0.60
359.0944824	0.09
360.3659058	0.10
361.2175293	1.37
378.2973633	0.12
385.1977539	1.64
388.8176880	0.20
397.1678467	0.39
401.3796997	0.26
403.4603882	0.33
409.3569946	0.14
421.1294556	0.13
427.3121948	2.22
429.1416016	0.18
437.2616577	0.22
442.2294312	0.13
445.2977905	0.33
463.4817505	0.78
468.9428101	0.93
477.3585815	0.20
480.9017334	0.12
487.1998291	3.13
499.1063843	0.30
505.2363892	24.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2288
Annotation	Patrinoside
Peak:m/z	Relative Intensity
143.2095337	0.09
149.0202332	0.35
161.1400604	0.14
171.2799683	0.10
179.3553009	0.12
190.9733276	0.12
211.1564484	0.12
213.3589783	0.04
220.0737152	0.58
220.9445953	0.16
238.6431885	0.12
275.0959473	0.07
276.1718445	0.12
279.5519409	0.04
281.1358337	0.08
288.1896973	0.16
293.0643616	0.14
297.3085327	0.10
309.6170959	0.05
310.9623718	0.47
312.0531616	0.04
313.4277344	0.75
314.5141296	0.30
315.3497009	0.67
321.4852600	0.19
329.3674622	0.06
331.2038269	4.45
332.4322510	0.64
344.9983521	0.04
346.3697510	0.27
362.3036194	0.07
364.4182129	0.09
369.4909058	0.15
385.1029358	0.05
387.4362183	0.07
390.3445435	0.07
397.4960938	0.06
406.4135437	0.09
407.2193909	0.04
418.3191528	0.09
431.6276550	0.10
432.6988831	0.09
447.2631226	100.00
448.3122253	16.52
449.7344055	0.16
450.5004883	0.09
451.2194519	0.05
457.4820251	0.06
462.3574219	0.05
467.1440125	0.05
474.0599670	0.09
475.6103821	0.73
476.5172424	0.05
477.3313293	0.04
480.3612366	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1142
Annotation	Castamollissin
Peak:m/z	Relative Intensity
152.9660034	0.05
163.1598816	0.08
177.1708984	0.05
188.2143860	0.06
189.0444336	0.12
190.1804810	0.04
191.1141968	0.19
191.8860626	0.05
193.1885376	0.03
203.1740723	0.03
207.0272217	0.06
213.1777649	0.03
213.9657440	0.04
217.1732635	0.06
227.1101685	0.05
228.2816925	0.14
229.1446838	0.24
231.1723175	0.27
232.3134918	0.03
233.1138000	0.13
234.4660950	0.02
237.1419678	0.03
239.4664612	0.07
241.2100220	0.15
246.2248077	0.04
247.2279510	0.09
253.7672119	0.10
256.1080627	0.39
259.3383179	0.09
261.3038330	0.14
265.0291748	0.03
268.1998291	0.05
269.1385498	0.11
270.1429443	0.09
271.2168579	1.02
272.2344360	0.41
273.1923828	0.42
275.2108154	0.02
282.1594543	0.28
283.1980591	2.53
284.1324463	0.03
285.2343140	0.19
286.2982788	0.08
287.3756714	0.16
296.2230225	0.09
297.1244507	0.35
298.0653076	0.10
299.4283447	1.45
300.1456299	3.76
301.3146973	0.17
303.2813110	0.05
310.0635376	0.05
311.0525513	0.12
312.1706543	0.02
313.1840820	0.52
314.2821045	18.88
315.1433716	100.00
316.3064575	0.23
317.2434082	0.11
319.4099731	0.05
324.2273560	0.06
325.3125610	0.52
327.1744385	1.44
329.1887207	3.82
335.4135742	0.04
337.1843872	0.12
339.1358032	0.53
341.1089478	0.28
341.9498291	0.06
343.1425781	0.10
351.6118164	0.03
354.0312500	0.12
355.2940063	0.23
356.6014404	0.14
357.2414551	2.39
365.3829346	0.04
367.2232056	0.02
369.2680054	0.90
369.8742065	0.02
371.3071289	0.07
373.1004639	0.03
381.2484741	0.21
386.2721558	0.02
387.2230225	0.79
388.2606201	0.02
393.2817383	5.24
399.1213989	0.12
403.5966797	0.11
409.0848389	0.02
415.3338623	0.10
423.0737305	0.10
427.4286499	0.05
433.2670898	0.02
441.4308472	0.24
444.1949463	0.02
451.3333740	0.16
457.2971802	0.05
459.2528687	0.07
461.2224121	0.05
469.1337280	0.19
472.9645996	0.10
475.2556152	0.28
477.1643677	1.06
483.2024536	0.07
486.0034790	0.04
487.3061523	1.48
488.2280884	0.14
491.2679443	0.11
501.1312866	1.34
505.3648682	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2237
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9143982	0.03
163.2027130	0.04
164.8690948	0.03
193.1058960	0.05
229.5875549	0.03
261.0808105	0.13
277.3881836	0.04
283.2564697	0.06
287.0377808	0.01
293.0992432	0.04
303.3572998	0.06
310.8874512	0.06
329.2649536	0.21
331.3073120	0.20
347.1610718	0.69
355.1793823	0.43
371.1407471	0.19
382.3740845	0.02
389.0094604	0.02
401.4890137	0.05
430.9199219	0.01
461.5541382	0.07
463.2918091	100.00
463.9348145	0.31
465.2835083	0.07
473.2734985	0.02
491.4413452	0.02
509.0174561	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.7569580	3.11
374.8674316	2.84
458.5980225	21.00
459.3004761	0.51
542.6007690	100.00
543.2787476	1.22
544.7152710	0.34
624.0913086	0.20
626.4908447	74.95
628.7555542	3.54
664.8163452	0.48
688.5780640	2.97
707.8073730	0.83
709.9697266	20.19
710.6228638	94.20
730.5304565	0.36
748.3060303	5.17
748.9388428	1.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9271393	0.02
138.1351013	0.03
143.0226593	0.16
149.3434753	0.05
151.1955872	0.02
153.0987549	1.45
154.2663269	0.04
159.1112823	0.09
161.0481720	2.59
162.1034546	0.03
165.2364960	0.03
172.0934753	0.01
178.9750671	1.18
179.7739563	0.03
187.1149292	0.01
188.9282227	0.04
205.1405640	2.01
206.2202454	0.06
223.0903931	4.98
224.0437927	0.23
225.0630798	0.54
235.5520020	0.01
268.2651672	0.02
285.3028564	0.12
298.7216797	0.16
299.3299866	0.57
300.4431763	0.16
307.3822632	0.09
309.1430054	0.01
313.4548645	0.02
344.5175171	0.05
355.3570862	0.05
366.8901978	0.03
371.6693726	0.04
385.1954041	100.00
386.2005005	7.20
387.0190735	0.05
395.5179443	0.03
413.1983337	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1039
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0655365	0.12
155.0104980	0.05
160.9614563	0.12
169.0348969	0.09
174.8643188	0.02
175.9554138	0.06
179.0772400	0.07
187.2663269	0.03
196.2008057	0.04
197.1856384	0.18
199.1811829	1.17
201.2450256	0.15
213.0819397	0.38
217.0917664	0.11
217.8513489	0.06
223.1601562	0.05
225.4293518	0.05
241.1483765	12.97
242.1534424	0.07
242.9996338	0.90
249.2223206	0.07
255.0380554	0.06
257.1860657	0.22
266.9440918	0.16
285.0977173	100.00
287.3857117	0.09
289.2786560	0.03
300.3265991	0.33
301.1584473	0.45
302.0704956	0.81
303.2196960	0.61
313.2182312	0.04
314.1611328	0.07
315.2456665	0.13
316.1798401	0.15
317.1176758	0.03
328.0899658	0.03
329.2617798	0.31
333.2541199	0.03
337.0883789	0.05
338.0906982	0.14
339.2005920	14.07
343.0696411	0.03
349.0694885	0.02
355.1606445	0.19
365.1148376	0.33
374.1111145	0.04
377.2236633	0.25
381.2370911	0.09
391.2924500	0.04
397.3496399	0.17
403.1681213	0.10
421.2898560	0.36
447.1663208	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.13
Annotation	Unknow
Peak:m/z	Relative Intensity
95.3385849	0.02
98.9720078	0.02
110.9986572	0.03
116.9950333	0.07
118.2588959	0.02
121.1693268	0.01
124.9994431	0.02
130.0681763	0.08
132.0370026	1.67
135.0918427	0.04
141.9933014	0.02
147.0158081	0.02
148.9609375	0.10
152.9852295	0.01
154.7918396	0.03
159.7123718	0.01
161.2262268	0.02
166.0106506	0.15
168.0697327	0.05
175.2124023	0.07
176.2233887	0.04
180.0122070	0.01
183.1124573	0.03
184.0015717	0.50
185.9152679	0.03
191.1018677	0.03
193.0249481	0.35
195.1006470	0.02
196.4085083	0.02
205.1974792	0.02
207.2656250	0.06
212.1393738	3.09
212.9453735	0.06
220.1485901	0.01
224.1212463	0.02
229.9262085	0.05
233.3554993	0.10
234.0478210	0.28
237.5934448	0.06
240.1335449	0.19
243.8992004	0.03
247.0080261	0.04
249.4184265	0.02
250.2414246	0.06
252.3010864	0.14
257.9866028	0.06
259.7732544	0.06
261.2277832	0.02
265.1303101	0.02
266.2383118	0.03
268.1673889	100.00
269.2109375	0.01
270.0316772	0.05
270.9920044	0.02
275.3743896	0.06
277.0527649	0.06
278.0816956	0.04
278.9968262	0.10
282.1458435	0.01
282.9635010	0.01
286.7485657	0.13
288.2286377	0.14
294.0025940	0.03
295.0940857	0.06
296.4479675	0.20
305.1369324	0.37
306.1759644	0.75
308.4187012	0.37
309.3634949	0.01
314.8056030	0.11
315.7365417	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Scopolin
Peak:m/z	Relative Intensity
109.2550049	0.02
110.9929504	0.07
127.1733246	0.04
132.8704224	0.01
135.0981140	0.60
145.0905151	0.01
152.9356384	0.05
155.2398987	0.05
161.0782623	0.33
171.1549835	0.04
173.1078796	1.02
178.9874420	4.59
179.6014404	0.02
191.0010071	100.00
192.0917969	0.01
232.2069092	0.01
291.9707947	0.01
293.3907471	0.02
299.0514526	0.01
308.2171936	0.02
309.3242798	0.02
317.0069580	0.02
335.2881470	0.06
335.9179993	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1246
Annotation	Cyanidin 3-(6''-caffeylglucoside)
Peak:m/z	Relative Intensity
179.0800323	0.32
182.3330994	0.04
190.9159851	0.03
201.1566925	0.17
202.0453491	0.07
223.0789948	0.03
231.2767029	0.09
245.2223053	0.03
254.9531860	0.35
261.2456665	0.30
270.2500610	0.08
271.1543579	0.18
273.0293274	0.09
285.3816528	0.08
293.1659546	0.14
295.2856445	0.05
299.9966431	2.34
301.0815430	13.47
307.2875366	0.08
313.1448364	0.12
325.6430664	0.08
336.4735107	0.04
341.1361694	3.43
343.3427734	0.27
351.4472046	0.06
352.7730103	0.11
365.4396362	0.07
371.6917725	0.11
375.3132935	0.03
377.2910156	0.04
383.6438599	0.08
395.6351318	0.04
401.4418945	0.07
409.4068604	0.16
413.4688110	0.06
415.1597900	0.04
420.9827271	0.05
424.1813965	0.03
428.4239502	0.09
429.0960693	0.12
439.2293091	0.12
445.4354248	0.09
446.8724976	0.74
447.5676880	0.62
459.2733765	0.25
461.4228516	0.28
463.1986084	100.00
463.8392944	0.17
477.2387085	0.17
481.3339844	0.03
487.5024414	0.37
488.6199951	0.08
489.3051758	0.19
499.3054199	0.08
501.1184692	0.08
503.2859497	1.42
517.4956055	0.08
518.6418457	0.07
519.6847534	0.09
520.4953003	0.07
522.6795044	0.10
523.4975586	0.33
536.6246948	0.08
545.3521118	0.15
548.3142700	0.07
553.2290649	0.08
561.4120483	0.03
562.3448486	0.18
563.2800903	1.37
564.4550781	0.17
565.4995728	0.08
570.1140137	0.04
572.8103638	0.10
573.4872437	0.35
578.2695312	0.07
581.4369507	0.11
582.3585815	0.03
589.4277344	0.24
590.2376099	0.05
591.3725586	0.31
608.4896851	0.05
609.7244873	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.15
Annotation	Orchioside B
Peak:m/z	Relative Intensity
144.7663727	0.03
150.0463562	0.04
151.0020599	1.63
152.0511322	0.85
152.8157654	0.10
159.1285248	0.03
160.9869385	0.05
162.3751526	0.08
163.1234436	0.21
166.0797577	0.06
168.0998535	0.12
169.0240326	0.08
173.8162231	0.10
176.1437683	0.03
176.8603516	0.07
179.0218811	2.01
180.0418091	0.97
181.1011353	0.12
184.4402466	0.06
189.2960510	0.07
190.0558472	0.12
191.0584106	0.08
192.0573730	0.10
192.9642029	0.28
194.2266846	0.07
197.2538605	0.03
198.3060608	0.08
203.1958923	0.14
205.3858643	0.04
207.3616333	0.09
208.2116547	0.07
210.0512543	0.27
212.0997009	0.08
213.2412872	0.13
214.1822510	0.03
215.1245422	0.10
218.0900269	0.06
221.1072083	0.04
222.1456299	0.10
223.2214050	0.02
224.9682312	0.02
226.0200958	0.11
227.2172852	0.06
228.3026123	0.10
229.2662964	0.09
230.1484070	0.02
231.4972076	0.07
233.6611481	0.10
235.2386475	0.07
238.1909485	0.09
240.2276306	0.13
242.1993713	0.05
243.7416077	0.24
244.4292603	0.01
248.1981506	0.09
249.2661591	0.04
252.3070526	0.06
254.1200256	0.22
255.2435913	0.80
256.2104797	1.08
257.2757874	0.08
258.2119446	0.04
266.0068970	0.02
267.7729797	0.05
269.1448669	0.14
270.1654053	0.11
271.1453857	1.96
272.1817322	1.93
273.2043457	0.87
274.1622314	0.35
275.3112793	0.16
275.9506836	0.10
277.1046143	0.03
280.4255066	0.04
281.0756531	0.13
282.1210327	0.04
283.2024231	0.31
284.1954651	0.26
285.1210022	0.52
286.2879639	0.08
287.3932495	0.06
288.2356567	0.12
289.2416382	0.02
297.2434692	0.14
298.2701416	0.16
300.1121216	25.19
301.1548462	100.00
302.1477051	96.71
303.1083374	13.93
309.0089111	0.06
310.0433044	0.03
311.2117920	0.46
313.2150879	0.22
314.3119507	0.19
315.1882629	0.35
316.1350403	0.43
317.2008667	0.13
318.3136597	0.07
322.3907776	0.03
323.2714844	0.08
326.3193359	0.13
327.1180420	0.21
329.0897217	1.28
330.2545166	1.58
331.0625305	0.10
332.3754272	0.03
337.2027588	0.12
338.5604248	0.13
339.2734985	0.11
341.3931580	0.05
343.1183472	1.71
344.2365112	22.01
345.1854858	32.69
346.1805725	0.18
346.8172607	0.07
348.2391357	0.05
351.4368286	0.10
353.2468872	0.10
354.1946411	0.40
355.1864014	0.35
356.2415771	0.38
357.2072754	0.20
358.0013123	0.33
359.2451782	0.73
359.8850098	0.11
362.6005249	0.04
365.9838867	0.01
367.2907715	0.10
368.4028015	0.09
369.5993652	0.12
370.2716064	0.10
371.9959412	0.11
373.3671570	0.15
374.2073669	0.48
375.2557678	0.22
379.0212708	0.22
380.3018188	0.24
381.3414917	0.14
383.3383789	0.16
384.5545959	0.06
387.2207642	4.31
395.2704468	0.05
397.1059265	0.03
398.3701477	0.05
399.2405396	0.04
401.5484924	0.07
403.4429016	0.06
407.3635864	0.07
410.3498840	0.16
411.3188782	0.20
417.1855164	0.39
419.4717102	0.09
427.3187561	0.02
428.3536682	0.11
429.4228516	0.08
433.2893677	0.03
442.5428772	0.08
445.3491516	0.94
446.1910706	4.82
447.1845398	1.19
453.2320557	0.03
460.1944885	0.09
463.1636353	3.59
464.2266846	27.99
465.2236328	6.66
470.3227234	0.08
475.2465210	0.66
476.2121887	0.04
477.3645630	0.04
478.3207703	0.07
479.3812866	0.74
480.2633972	0.09
487.6713562	0.07
488.2986755	0.82
489.3853149	0.98
492.1855774	1.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.9987183	0.01
111.0934753	0.02
113.0940933	0.01
115.2102356	0.03
127.2942352	0.01
132.9272919	0.01
134.0582581	0.02
135.0869751	0.53
136.9348297	0.02
143.1000671	0.02
155.2538147	0.06
161.1231995	0.42
171.0034332	0.01
173.1245422	0.73
175.0662842	0.01
179.1377258	4.11
191.0570068	100.00
191.8757019	0.01
206.1106567	0.01
220.9640198	0.01
292.3500061	0.03
307.0883179	0.01
309.3450317	0.07
317.62146	0.02
324.1020508	0.01
335.1184998	0.01
337.3898315	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	491.1172
Annotation	Isoscutellarein 8,4'-dimethyl ether 7-glucuronide
Peak:m/z	Relative Intensity
191.4983368	0.01
233.3964844	0.01
240.3334045	0.01
265.4606323	0.01
284.8779602	0.02
287.1197510	100.00
288.5464478	0.03
311.2847290	0.01
329.3480835	0.01
347.4456787	0.04
472.0805054	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.21
Annotation	Schizandriside
Peak:m/z	Relative Intensity
162.9648743	0.14
223.2346039	0.11
240.5373230	0.29
245.1316986	0.21
255.0573425	0.37
268.2393188	0.20
287.2455750	1.44
288.1700439	0.81
289.0737305	2.92
294.1885681	0.38
296.4321594	0.36
297.5830078	0.15
303.1298828	0.32
304.1752930	0.80
313.2936096	0.53
328.3031006	0.27
331.1474304	100.00
357.2905273	0.36
360.5451050	0.16
374.1373596	0.28
403.4548340	0.37
408.6380920	0.19
411.8649902	0.99
434.5769958	0.46
447.3984070	0.51
452.3945312	0.17
465.1462708	0.11
465.9906311	0.88
469.3478394	0.66
475.3327332	1.33
483.8551331	0.30
490.1053772	0.23
494.3618469	0.18
502.3152161	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3044
Annotation	Sphinganine
Peak:m/z	Relative Intensity
92.92570496	0.02
94.86117554	0.26
97.01726532	0.42
109.0439606	0.27
111.0786896	0.47
113.2198334	0.02
115.187912	0.07
116.1908035	0.02
121.0610657	0.07
123.0621796	0.61
125.1929398	0.02
133.1697998	0.03
136.9143066	0.42
139.3011627	0.10
140.1033936	0.05
145.0466919	0.03
148.5749207	0.08
149.9670105	0.05
151.2898254	0.08
153.0410767	0.10
157.0015869	0.14
163.0043945	0.03
164.869873	0.15
166.3767242	0.03
167.0794678	0.03
169.2937164	0.02
170.2992554	0.03
171.1082916	0.04
175.1251221	0.02
177.2516479	0.05
179.0924377	0.05
187.1195526	0.04
192.912323	0.03
193.9572144	0.01
195.0851746	0.05
201.2973328	0.07
202.2800598	0.10
207.4079285	0.04
215.2079468	0.04
217.4346619	0.04
221.2732544	0.01
225.0970764	0.07
226.7372742	0.06
227.4363403	0.07
229.2059631	0.41
230.3352661	0.15
231.0445251	0.02
235.0888367	0.02
238.0938721	0.03
240.4424744	0.63
242.2844849	0.05
244.213501	0.10
245.5705261	0.10
246.5559692	0.10
247.1593628	0.13
249.360321	0.15
253.199585	0.12
254.5099182	0.41
255.4740601	0.05
256.364624	0.17
257.13797	0.72
257.7710571	0.03
259.005188	0.07
260.3974304	0.03
261.0101929	0.07
266.3311768	3.98
267.181488	0.37
271.0689392	0.17
272.6280518	0.03
274.1694641	0.26
284.3016663	100.00
285.2783813	0.45
287.2781982	0.06
290.9226074	0.11
293.1571045	0.37
302.1038818	0.03
303.2358398	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2396
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9421692	1.09
158.4101715	0.19
161.0222473	5.79
163.0800629	0.23
191.0462799	17.46
203.2560883	0.17
215.7101746	0.10
217.2507629	0.11
220.1065369	4.95
220.8744354	6.94
233.0523682	0.29
238.9727173	2.40
245.2151184	0.40
246.8981018	0.40
250.9807281	5.91
262.9371033	0.61
271.6247864	0.12
275.2388306	1.65
277.3734131	0.16
281.0145874	2.26
293.1260681	15.43
310.9672852	100.00
311.6378784	0.64
323.1739502	0.31
331.0984497	0.19
336.9409790	0.31
341.1324463	0.24
367.3921509	0.80
383.0150146	0.15
384.4788208	0.61
385.2938232	1.92
394.2606812	0.08
396.8488159	0.38
403.4873047	0.24
413.2122803	0.27
415.4952393	0.11
424.2946167	0.22
425.6607056	0.28
428.6371460	0.12
429.6370239	0.09
451.1082153	0.10
458.3374023	0.15
463.0523071	0.20
484.9776001	0.14
487.2981567	0.07
500.8855591	2.80
501.5852051	1.14
503.7015991	0.28
506.2855835	0.31
509.5209351	0.72
513.4691162	0.11
528.2677612	0.18
537.4414062	0.22
538.2643433	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.13
Annotation	N2-(3-Carboxy-2-hydroxy-1-oxopropyl)arginine
Peak:m/z	Relative Intensity
96.9596863	0.02
98.2124786	0.03
112.0731659	0.71
113.2868347	0.04
114.1411743	0.29
115.0782623	0.29
116.0315323	0.91
119.2733688	0.03
121.3259048	0.02
127.2159195	0.08
127.9784546	0.06
128.9154358	0.35
130.1119537	0.74
131.0140991	0.05
133.0983124	0.08
134.0457611	0.02
135.0347900	0.04
140.0284119	0.09
143.2279663	0.03
145.2876740	0.02
145.9768372	0.11
147.9671021	0.05
149.0343018	0.04
151.0534363	0.08
157.1189575	2.32
158.0343933	2.33
159.0110168	0.04
161.0641479	0.16
161.6953430	0.20
162.9708862	0.11
163.8015289	0.04
165.1499939	0.14
175.1230164	100.00
177.0520477	0.03
177.9584961	0.06
178.8926849	0.10
182.6744385	0.09
185.1172333	0.21
186.2164612	0.03
187.2752380	0.09
189.0265503	0.07
191.4721375	1.31
192.4642792	0.28
193.1340637	0.09
195.0851440	0.39
200.3226929	28.87
201.0773926	5.00
201.6926270	0.07
207.2334595	0.03
209.6361084	0.26
210.8008728	0.05
213.2152100	0.77
214.1274109	0.20
214.9851990	0.06
217.2685547	0.18
219.0396729	0.09
220.1550903	0.11
224.1686096	0.03
225.1407776	0.12
227.1349487	0.02
228.1963806	0.12
231.0599670	2.90
232.1130676	0.91
232.9031372	0.02
235.3178406	0.09
237.1747742	0.03
238.0963440	0.97
244.1336060	0.02
245.2077026	0.41
247.0807495	0.03
249.2276001	0.41
250.3003540	0.06
252.9594116	0.04
254.4594116	0.33
255.4958801	0.14
256.1697693	2.82
257.1942749	0.31
261.1748657	0.12
263.3974609	0.19
269.0446472	0.10
271.2180176	0.06
273.1240845	4.21
274.1941528	1.95
281.5782471	2.84
282.2293701	1.02
290.9549255	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.21
Annotation	Atalanine
Peak:m/z	Relative Intensity
214.6585693	0.05
221.2389221	0.11
233.0151672	0.13
239.8590546	0.01
251.2143860	0.02
262.0733643	0.02
263.0501099	0.01
281.2536316	0.05
291.3427734	0.03
305.3993530	0.03
311.0465698	0.05
323.2764893	0.15
341.0599365	0.51
342.1002808	0.03
343.2077637	0.01
383.2042847	0.07
412.9035034	0.09
443.0634155	0.11
467.1965332	0.02
487.2694702	0.03
488.3123779	0.01
503.2865601	100.00
504.3386230	3.57
505.4138184	0.04
514.5860596	0.12
529.4556274	0.04
559.9476318	0.05
631.2899780	0.09
631.9915161	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1559
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0942383	0.31
153.0691833	0.61
154.0630798	0.18
159.9893646	0.13
160.9323578	0.10
163.8689575	0.02
175.1073303	0.71
176.0007019	0.20
176.7490540	0.02
178.3622437	0.02
191.1005859	0.12
193.0618286	1.02
194.1851807	0.03
205.0389709	0.02
215.1534119	0.04
217.2215881	0.16
218.0917053	0.05
219.1423645	0.04
220.8727722	0.03
233.2406769	0.04
233.9692993	0.03
234.8800201	0.13
236.1127777	0.10
239.3246307	0.02
245.1757812	0.03
247.4255981	0.02
251.0454254	0.03
259.0235291	0.02
260.8013611	0.02
265.3531189	0.02
273.1436157	0.04
277.2817383	0.26
278.3097534	0.03
280.4026794	0.03
281.0534058	0.02
284.8937378	0.09
287.1028442	0.02
293.3129272	0.13
294.3100891	0.04
297.3364563	0.17
298.2995911	0.02
299.2955933	0.01
309.4516907	0.03
311.0687256	0.32
311.9337158	0.20
313.2957458	0.44
314.2646484	0.32
315.3026428	0.28
316.2601624	0.07
320.1976013	0.05
323.2185669	0.46
324.2362061	0.16
327.9418030	0.15
329.2021790	2.46
330.3656616	0.60
337.1973572	100.00
338.2039795	18.98
341.2824707	0.05
343.2431641	0.17
344.2313232	0.08
354.3033142	0.02
355.8110352	0.03
357.0807800	0.07
363.3063660	0.15
371.3182068	0.12
372.2779541	0.11
386.1790466	0.02
393.5156860	0.02
401.3062134	0.11
402.7552795	0.06
415.1809998	0.02
418.1176147	0.04
422.4794006	0.05
425.4360657	0.01
429.2144470	0.03
445.2732849	18.54
446.2575684	2.91
447.3941040	0.08
449.3321838	0.06
455.6989746	0.01
456.4369202	0.02
459.6015015	0.01
461.4011536	0.26
471.4853821	0.02
473.6244202	0.05
476.1918335	3.21
477.3040466	0.72
478.2769470	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1147
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0397797	1.95
153.1651001	0.11
161.0208740	0.04
163.2990417	0.19
163.9833832	0.18
165.1312866	0.43
166.9443665	0.10
172.0544128	0.09
179.0442505	0.05
180.0591888	0.06
181.1712341	0.08
191.1186829	0.24
192.0126343	0.20
193.1049347	2.40
196.9541321	0.22
203.1712952	0.05
205.2625275	0.06
207.0374908	0.60
211.2142639	0.05
217.2666626	0.10
220.2358704	0.15
221.0929413	0.03
233.3068237	0.19
235.1207733	0.33
239.2425537	0.22
240.0845642	0.14
243.1877289	0.40
259.1257935	0.19
260.4580688	0.31
261.2221069	0.73
263.0795288	0.05
265.1099243	0.44
267.1850891	0.08
271.2009888	0.13
272.9990234	0.08
275.0099792	0.06
285.1402588	0.37
286.0639038	0.67
286.8773193	0.12
287.4885254	0.18
291.4506836	0.09
293.2559814	0.11
297.1008301	0.17
299.2139282	0.48
301.0935669	0.39
302.0840454	0.30
303.2243042	2.23
304.1175537	0.07
305.3836670	0.08
309.4290771	0.05
311.3102417	0.63
313.4900513	0.12
314.1398315	2.32
315.2668457	0.25
317.2977905	0.09
319.1962280	1.35
321.3923340	0.25
329.1655884	100.00
329.8438721	0.50
331.2850952	0.76
333.3622437	0.16
341.0858765	0.09
345.2237549	1.43
346.2951050	3.13
347.2421875	24.69
349.2651978	0.05
355.2088623	23.83
357.3937378	0.07
359.2825928	1.44
369.4238281	0.04
371.4187012	0.07
373.4989014	0.09
377.4424438	0.13
383.3293457	0.10
387.3254395	0.13
389.1737671	0.99
401.3776245	0.12
419.2530518	0.09
421.8766479	0.28
423.1808472	0.33
425.3902588	0.21
429.2920532	0.06
449.1683350	0.25
462.2505493	0.29
463.3267822	5.37
465.0490723	0.69
465.7073975	0.34
479.4122314	0.10
481.1485596	0.67
491.2686768	3.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	249.0803
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
79.8453293	10.23
93.1812897	0.37
96.9145813	100.00
98.9614868	0.12
101.0046844	0.24
109.1340332	0.21
113.0565491	0.42
142.8870087	0.41
177.4660797	0.13
189.0876007	0.07
202.8702850	1.33
205.0704498	0.43
212.0139313	0.10
231.1353912	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	853.2157
Annotation	Unknow
Peak:m/z	Relative Intensity
275.4992371	0.11
300.1089478	0.04
302.9859009	0.04
313.0412292	0.04
331.2133789	0.08
334.2807617	0.12
343.1882019	0.06
352.4822998	0.05
361.1613770	0.05
394.5203247	0.04
411.2618408	0.03
423.1215210	0.03
463.1590576	0.07
468.3419800	0.03
469.3265381	0.03
479.2546387	0.03
481.4579468	0.03
482.3110352	0.03
489.5599365	0.10
495.5316772	0.21
496.3740234	0.05
511.2872314	0.21
519.1436768	0.05
540.3371582	0.08
547.2042847	0.04
560.7909546	0.05
562.5682373	0.09
565.3917236	0.07
605.4855957	0.15
617.5369873	0.18
620.0953369	0.09
621.5299683	0.04
630.4459839	0.09
631.5379639	0.73
641.5468140	0.09
647.2719116	0.77
648.2487183	2.69
649.3552856	1.37
655.0341797	0.10
659.3984985	2.77
671.2893677	0.07
683.4578857	0.19
687.3334351	0.35
691.3069458	100.00
692.0167236	0.21
696.4071045	0.12
700.4970093	0.13
707.5016479	0.04
714.3029785	0.11
720.1137085	0.11
724.3467407	0.06
726.9052124	0.24
755.3657227	0.04
771.7828979	0.22
786.8163452	0.10
791.0364380	0.06
800.1426392	0.08
806.9601440	0.19
809.0287476	0.08
819.3328857	0.07
821.2583618	0.83
823.3556519	0.30
827.6126099	0.06
834.3433838	0.20
835.2352295	0.77
852.9749146	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2286
Annotation	Ssioriside
Peak:m/z	Relative Intensity
160.9436493	0.23
166.0611420	1.26
176.1515656	0.25
178.9028778	0.64
181.1556854	4.94
193.9770355	0.89
195.2062073	0.38
209.1670532	2.76
228.8690338	0.09
231.1150513	0.06
243.1649475	0.12
251.0970306	0.30
261.1532288	0.16
267.2340393	0.05
279.1844482	0.24
283.3305664	0.18
287.0042114	0.09
288.3977356	0.14
297.2760010	0.10
299.1399536	0.07
303.5122070	0.11
319.0013428	0.11
320.4454956	0.20
323.2935181	0.07
325.3684692	0.18
327.2919922	1.06
328.2593994	0.41
329.1416016	0.19
330.1110229	0.24
331.3950195	0.36
332.0390015	0.16
341.3784790	0.17
343.2156372	100.00
347.1223755	0.38
348.2857666	0.37
349.2747192	0.19
357.2895508	7.00
362.9881592	0.05
371.3025513	0.04
372.6837158	0.08
373.4135132	0.16
377.3204346	0.10
379.1868286	0.10
384.2807617	0.14
386.4104004	0.20
388.2851562	0.15
389.2001343	0.22
390.1534424	0.45
391.1795654	0.76
397.2228394	0.47
398.3383179	0.48
407.7015381	0.20
412.8162842	0.05
413.4166870	0.23
417.3178711	0.05
418.6350708	0.08
421.3602295	0.09
431.0539551	0.18
433.6456909	0.15
451.1453247	0.09
454.4570923	0.39
455.1213989	0.08
456.3765259	0.36
457.5843506	0.34
463.4857788	0.08
465.9027710	0.15
467.4245605	0.15
470.3762207	0.32
471.8038940	0.57
473.0258179	0.11
477.3187866	0.07
481.5045776	0.24
490.7846069	0.06
491.4736328	0.23
492.3068237	0.23
493.3345337	0.69
505.3875122	2.57
506.3180542	3.13
507.3516235	2.20
508.4280396	0.99
509.3836060	1.36
511.4352417	0.17
517.0556030	0.40
517.6931763	0.11
518.4855347	0.04
522.4443970	0.05
524.3651123	0.05
525.2222900	0.05
535.1955566	1.32
536.2388306	0.31
538.4704590	1.60
539.1630249	0.05
552.2796021	0.08
554.2761841	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.11
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
177.0890961	0.03
187.1354828	0.12
196.2502289	0.04
204.3720703	0.11
205.1139526	0.49
227.4191895	0.02
244.9390259	0.11
251.4421234	0.11
264.6826477	0.02
277.2278442	0.04
279.3151245	0.02
280.9446106	0.03
295.1835632	0.03
296.4570923	0.03
299.0730591	0.04
301.3016357	0.20
303.1228027	100.00
303.7566223	0.17
311.3211060	0.08
317.2336731	0.17
319.3685608	0.04
323.3448486	0.03
337.3409119	0.02
339.3122253	0.06
343.3854370	0.15
344.1947632	0.05
345.2317200	1.35
363.2904663	0.04
369.2298889	1.36
381.1971130	0.18
387.4703064	0.12
393.0773010	0.17
393.6784058	0.03
396.1463928	0.13
397.2716370	0.05
411.2278137	2.89
417.1467896	0.03
418.1806946	0.09
419.1949463	0.02
429.1099243	0.11
431.2924805	0.10
438.3882141	0.06
441.9739685	0.08
443.3843079	0.12
445.2406311	0.05
453.1708069	0.68
471.1664124	0.58
475.3658752	0.02
487.0228882	0.02
489.2143860	7.71
490.2113647	0.13
492.3233337	0.04
493.4131165	0.08
507.0289612	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2137
Annotation	Citbismine C
Peak:m/z	Relative Intensity
188.9177094	0.08
191.1153870	100.00
211.0634155	0.20
310.9984741	0.19
323.1477661	4.42
353.3640747	2.96
473.2258301	2.93
613.3166504	0.45
617.3059692	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1287.3527
Annotation	Unknow
Peak:m/z	Relative Intensity
409.6264648	0.03
437.4979248	0.25
479.1904602	0.74
497.3599854	0.77
539.3504639	3.91
553.1819458	0.03
577.4219971	0.06
581.2493896	0.02
607.2348633	0.06
625.2990723	9.22
643.2801514	100.00
643.9304199	0.24
681.1984253	0.17
965.5310059	0.04
1113.3066410	0.02
1126.7675780	0.24
1130.3078610	0.02
1206.0454100	0.06
1269.1409910	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.1857
Annotation	Variabiloside E
Peak:m/z	Relative Intensity
230.9720459	0.36
247.0938110	0.06
249.2003174	100.00
250.2799988	0.08
266.9880066	0.06
283.2910767	0.10
292.9307251	0.10
317.1353455	0.12
331.1799316	0.09
367.2583618	0.28
373.3028564	0.08
387.2742310	0.05
405.3848267	0.15
407.1881714	0.06
410.4654541	0.08
447.3500977	0.12
452.3582764	0.08
459.2746582	0.04
465.5424194	0.03
491.5601807	0.06
507.3532104	0.08
512.1705933	0.04
518.2659912	0.11
521.5452881	0.08
532.3856812	0.14
544.3531494	0.04
551.2575073	0.40
552.9138184	0.14
563.2783813	0.31
572.3007202	0.25
575.4260254	0.47
576.2955933	0.03
577.5961304	0.04
581.7351685	0.10
591.5181274	0.09
593.3446655	0.80
594.0661621	0.27
598.6150513	0.06
601.2016602	0.10
605.8163452	0.17
609.5599365	0.06
611.5549927	0.29
615.4658813	0.07
617.4935303	0.06
620.5313721	0.08
621.1542358	0.06
623.4961548	0.05
625.2462769	0.10
633.5567017	0.04
637.5404053	0.08
650.9275513	0.05
653.2509766	0.05
669.3053589	0.15
670.3977051	0.11
674.5897827	0.10
675.5505981	0.20
679.2811279	0.20
685.5846558	0.05
690.1244507	0.39
693.3663330	0.17
703.7861328	0.04
709.2565918	0.46
710.9960938	0.03
711.6903687	0.32
712.5730591	0.31
713.7432251	0.05
719.3856812	0.12
737.2737427	0.67
738.4485474	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	528.1506
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9374084	3.61
162.1509247	0.29
163.2054443	0.14
165.1497345	0.18
178.0504608	0.47
187.9886475	0.30
190.1274567	1.64
191.2738342	0.39
193.0738220	100.00
194.0340424	18.07
212.2492981	0.07
213.0026398	0.06
214.0000305	0.10
232.0838776	0.88
233.1901703	0.08
234.9984283	0.04
240.1359253	0.09
274.1157837	0.12
291.1121216	0.13
293.0466309	0.07
307.3483887	0.14
322.4918823	0.05
333.3722534	0.32
334.2395630	3.10
335.2073975	0.59
337.1063232	3.02
338.2088623	0.19
340.9852905	0.20
349.5781860	0.11
355.1314697	2.85
361.4251099	0.06
365.2871094	0.24
367.3451538	0.54
397.3240967	0.36
405.3916016	0.09
425.7956543	0.09
438.3684082	0.07
439.3419189	0.04
441.4906616	0.05
464.3783569	0.11
467.9094849	0.12
469.2691040	0.05
479.1594238	0.13
479.7999268	0.18
480.5032349	0.12
483.3541260	0.75
484.1112671	0.17
485.3536987	0.56
486.5634155	0.05
487.4229736	0.13
493.3613281	0.58
496.1983032	0.07
497.4857788	0.38
510.7166748	0.40
511.4998169	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1123.5557
Annotation	Hoodigoside M
Peak:m/z	Relative Intensity
331.3418274	0.19
413.3704224	0.29
451.3166809	0.20
477.2458496	0.05
509.3270874	0.12
557.5521240	0.08
575.6357422	4.84
637.5681152	0.06
661.5742188	0.10
667.5948486	0.07
724.3475342	0.08
737.6243896	6.14
755.6215820	7.14
781.7884521	0.23
786.3055420	0.04
790.7407837	0.07
799.5647583	100.00
800.1894531	0.99
807.4475098	0.13
837.5887451	0.18
841.6567383	1.07
855.3686523	0.08
867.2320557	0.16
875.0711670	0.06
893.7045898	0.09
899.5788574	0.08
921.0723877	0.11
923.7412109	0.36
925.6009521	0.13
931.1568604	0.21
943.4403076	0.19
949.7888184	0.25
950.5917969	0.05
952.6745605	0.06
954.7285156	0.09
957.7322998	0.06
961.6850586	2.45
981.1339111	0.08
982.3680420	0.20
1004.0679930	0.14
1012.0842290	0.27
1026.8017580	0.27
1045.5706790	0.07
1070.6484380	0.09
1073.1386720	0.06
1079.4237060	0.36
1087.7475590	0.21
1092.8266600	0.15
1101.2850340	0.14
1105.3698730	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	809.1907
Annotation	Unknow
Peak:m/z	Relative Intensity
246.8689575	0.02
253.1120758	0.02
267.3765564	0.03
286.2928162	0.02
287.0522766	0.03
294.2742920	0.03
301.0690308	0.08
302.1334229	0.03
315.1787109	0.02
331.2353210	0.20
332.0307007	0.04
333.3839111	0.07
364.1731567	0.05
371.1893921	0.17
388.2158813	0.02
397.0635986	0.05
407.0315552	0.05
449.3626099	0.05
461.4367676	0.01
463.2523804	0.08
464.6279907	0.10
478.2534790	0.02
479.3485107	0.13
494.2831421	0.03
495.4205322	0.10
496.2647705	0.03
497.3586426	0.07
513.9328003	0.02
518.4461060	0.02
521.1118774	0.02
535.4696655	0.08
551.2496948	0.35
558.3807983	0.09
572.2803345	0.05
585.3657227	0.02
600.3422241	0.11
603.3791504	0.35
604.2039185	0.57
605.3358765	0.24
612.2147217	0.03
615.3752441	0.29
628.1605225	0.02
629.3516235	0.25
635.6804810	0.04
638.2708740	0.02
639.2140503	0.03
641.8984985	0.01
645.3578491	0.23
646.2985840	0.63
647.2863159	6.12
647.9634399	0.09
659.2903442	3.49
661.3185425	0.03
675.3455200	0.11
677.2996216	100.00
677.9376831	0.45
683.3120117	0.16
688.6629028	0.02
691.4744873	0.02
695.4844971	0.02
701.7921143	0.06
726.9196167	0.06
746.6555786	0.02
760.6972046	0.01
762.0447998	0.01
772.4177246	0.04
776.3018799	0.07
777.1132202	0.11
784.3963013	0.10
788.3323364	0.02
790.2917480	0.14
791.2260742	0.65
791.8849487	0.02
810.2542114	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
119.1162949	0.06
120.9568863	0.06
122.9014587	0.91
143.1527252	0.12
147.1059265	0.37
149.0877686	4.91
162.8552246	0.07
165.3547974	0.08
167.0134583	42.25
167.9570618	0.05
174.9033813	0.05
175.9723206	0.15
179.2613220	0.11
181.2873993	0.15
191.0542908	100.00
192.9481812	0.04
197.2833557	0.04
209.1143188	4.87
221.0516968	9.11
223.1151123	0.07
233.2174072	0.85
239.1981812	0.86
240.1401367	0.07
247.3143616	0.07
250.9963074	1.33
255.0264893	0.14
255.7221680	0.25
261.2245483	0.44
263.1748047	0.21
269.0943604	7.91
270.0882874	0.23
272.2626343	0.09
282.3053284	0.39
283.2250977	0.60
285.1988525	1.22
286.1494751	0.40
287.1003418	0.07
293.2858887	0.29
295.3117981	0.05
297.2882690	0.23
298.8913879	2.56
301.0960999	0.24
311.1913757	3.52
313.3254395	11.78
314.1495056	83.14
315.1630249	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
81.0862198	0.01
98.0426025	0.01
100.0685730	0.03
109.9744415	0.01
113.9693604	0.03
135.9695129	23.76
138.0674133	0.02
140.6348877	0.03
149.2160339	0.01
164.9529877	100.00
181.9908905	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	207.0663
Annotation	Sinapinaldehyde
Peak:m/z	Relative Intensity
74.7728958	0.02
83.1268921	0.04
101.3666229	0.03
102.9883575	0.11
113.3316803	0.04
116.9848022	0.38
118.9057770	0.04
123.2850800	0.04
127.0648956	0.05
142.9844666	0.16
145.4290924	0.07
146.9777374	100.00
147.7563477	0.01
151.0085449	0.06
161.0648041	1.94
163.0490112	0.27
165.0913239	75.71
178.9265442	0.06
188.9906769	0.26
191.9653778	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.1292
Annotation	Viridoside
Peak:m/z	Relative Intensity
95.0866394	0.07
101.0430527	0.02
108.3097992	0.24
109.0501556	1.14
121.0811996	0.09
123.0813370	6.22
123.9666443	0.09
137.3146667	0.05
151.0741882	0.47
152.9881287	100.00
160.8822479	0.01
162.1206970	0.04
163.9687805	0.04
165.0630951	0.04
167.1633759	0.02
167.8086548	0.05
176.1795959	0.03
178.9825134	0.18
180.1329956	0.11
189.0422668	0.03
192.0434875	0.02
194.2081146	0.02
195.0375519	0.10
196.2516174	0.03
207.2417297	0.11
208.1832581	0.19
209.1860657	0.03
220.2168579	0.13
221.6440430	0.02
223.1385803	0.05
231.2083130	0.02
238.2566833	0.11
239.2851868	0.02
252.1342468	0.07
254.9874268	0.06
257.2536316	0.02
259.2539368	0.03
269.0872192	0.22
271.1811829	0.17
285.1896973	0.03
287.1996460	0.11
296.6415100	0.08
297.3875732	0.03
299.0131836	0.03
300.3244629	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.05
Annotation	Unknow
Peak:m/z	Relative Intensity
66.9035950	0.04
74.9646301	0.02
83.0286102	0.10
85.0034027	9.81
87.0037994	0.01
100.9424896	0.24
111.0065460	8.67
117.0357819	0.01
125.0253906	0.16
129.0227814	1.60
132.7695770	0.19
143.0184784	0.19
146.9498749	0.27
159.0718994	0.12
161.0603790	0.53
173.0491791	0.34
177.1596832	0.30
187.0371857	2.16
191.2079773	0.01
195.1605682	0.07
205.0070648	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0615
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
101.0074463	0.04
113.0548935	0.05
120.9898834	0.51
136.9322662	3.71
141.1302643	0.03
149.1629944	0.02
159.1510010	0.02
162.9715118	0.02
164.9907227	100.00
179.0970306	0.03
190.0155487	0.07
191.0312805	0.73
196.3224640	0.06
197.0325317	0.09
199.0406952	0.05
208.9654541	0.09
229.1180420	0.07
233.0316467	0.05
249.0852356	0.07
272.0966492	0.04
273.2377319	0.04
275.2801514	0.05
277.2098999	0.07
285.9777832	0.08
298.2731934	0.04
299.0646362	0.03
300.2212219	0.03
301.2540894	0.62
312.2898865	0.03
313.4437256	0.03
315.1395874	0.29
325.3770142	0.10
327.2673340	0.28
330.2099609	12.46
331.1035767	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.13
Annotation	Robustaside B
Peak:m/z	Relative Intensity
141.0702820	0.42
143.0340576	0.26
145.7055206	1.58
168.9790802	0.18
184.2194519	0.48
189.2135620	0.60
205.2506409	0.22
210.9853363	0.20
219.1372070	0.49
221.1936951	0.14
231.1181183	0.38
238.3603516	0.32
241.1897583	0.34
252.2279968	0.60
254.9161377	1.80
269.1506653	0.25
270.2707214	0.32
273.0306702	26.32
281.4815674	0.24
283.1530151	1.81
285.1913757	1.61
292.2441406	0.49
297.2539673	0.89
303.2083130	100.00
325.3234253	0.67
326.0566406	0.32
339.3994141	0.33
342.1248474	0.74
344.4901733	3.65
345.3571777	1.21
347.3241272	1.17
348.2658081	0.39
351.2782593	0.42
353.2877808	0.20
355.4199829	0.36
367.3200378	1.66
369.2203369	0.46
370.3110352	0.13
371.3492737	1.76
372.3700562	0.23
373.4496155	0.55
381.2317810	1.73
386.3335876	0.16
388.9735107	2.34
393.1770935	0.77
399.1767883	3.76
406.3318787	1.01
407.2204285	0.39
416.7842712	5.51
417.4059143	7.17
418.3968201	1.41
420.0681152	0.15
422.1753540	0.56
426.3902283	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0498505	4.72
160.0679169	0.34
160.9109650	0.70
171.2217102	0.21
199.1187439	0.70
199.9162903	0.18
218.1342163	0.06
219.1296387	0.10
228.9979553	0.82
230.0071259	0.55
231.1248322	0.88
273.0165405	47.79
274.0716858	35.59
275.0840454	19.70
289.0009460	0.52
373.1165161	0.24
386.9911194	51.01
387.9983215	100.00
389.0538025	68.18
417.0273132	0.21
417.8969727	0.29
428.2219543	0.12
429.0255737	0.28
429.9594421	0.15
456.1397705	0.29
456.8776855	0.34
458.0946655	0.05
459.1746826	0.23
460.0267029	0.04
475.1648254	0.12
484.6241760	0.08
492.9334412	0.24
494.3554077	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.3708
Annotation	Unknow
Peak:m/z	Relative Intensity
295.8841248	0.08
301.1977844	0.07
328.2862244	7.93
329.3535767	0.47
343.2356567	100.00
344.3906860	3.32
357.6449280	0.10
358.5428467	0.05
415.2379761	0.20
426.2668457	0.12
505.2191772	2.31
505.8729858	0.19
515.2797241	0.06
541.2534180	0.03
553.4048462	0.08
582.4420166	0.06
597.5075073	0.07
599.4441528	0.04
601.6756592	0.08
613.6456909	0.07
617.4897461	0.30
690.5932007	0.04
691.9616089	0.26
716.3106689	0.10
729.4666138	0.09
747.3030396	0.10
749.5901489	0.04
763.3273315	81.78
764.3056641	8.69
764.9205322	0.03
790.6246948	0.11
804.3142700	0.20
833.4666138	0.15
840.5307007	0.11
850.5093994	0.05
858.4299316	0.09
865.8025513	0.07
877.4636841	0.09
881.6200562	0.16
893.4628906	0.28
895.7286377	0.07
897.2642212	0.13
898.3325806	0.10
907.7357788	0.13
908.7603149	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9214630	0.39
208.8631592	0.19
290.8538818	5.58
292.8175659	6.64
333.0463257	0.04
338.9395142	0.05
340.5506592	0.02
370.1990967	0.03
374.6591187	2.55
375.7839966	0.91
376.8105469	5.13
383.1144409	0.22
399.1219482	0.04
400.4164429	0.09
401.0324707	0.13
406.7291870	0.03
407.5437622	0.23
417.2551270	0.01
424.8001709	0.32
438.0497437	0.37
438.7918091	0.65
452.9379272	0.02
453.6588745	0.04
454.6620483	0.13
458.6886597	20.54
459.9495850	19.69
460.7568970	100.00
463.0244141	0.08
468.7512207	0.15
472.7075195	0.02
478.3717041	0.02
480.3309326	0.15
480.9949951	0.11
483.2548828	0.19
484.0125122	0.91
484.9562988	2.25
496.5873413	0.02
497.6557617	0.26
498.8109741	0.40
500.2905884	0.02
514.9275513	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	482.13
Annotation	Yersiniabactin
Peak:m/z	Relative Intensity
151.7329712	0.02
167.0336151	0.02
207.1574402	0.02
237.1117554	0.01
259.3185425	0.01
293.1463928	0.01
297.2876587	0.03
302.2809448	0.01
315.2764893	0.02
317.1763306	41.84
318.1582336	52.32
319.1566162	100.00
320.2230835	23.07
330.4585571	0.01
333.0002441	0.01
348.9256287	0.04
355.2100220	0.02
361.1024170	0.02
362.5160828	0.02
368.7944031	0.06
374.3114929	0.03
414.4963989	0.05
445.6169128	0.03
448.3672180	0.02
463.3518372	0.04
464.2549438	0.05
468.2615662	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	895.3608
Annotation	Precorrin 6Y
Peak:m/z	Relative Intensity
267.4751587	0.02
277.2483521	0.06
313.2517700	87.45
314.3120117	0.91
333.1162109	0.03
343.4536743	0.03
362.9559326	0.04
433.1479492	0.04
447.2833252	0.06
461.4633789	0.03
475.3910522	1.95
476.2595825	0.14
489.5351562	0.05
504.3517456	0.03
523.3233032	0.10
530.3923340	0.03
535.2249756	0.03
537.3010254	0.13
549.4780273	0.08
551.1300049	0.16
563.4385986	0.02
565.7054443	0.05
567.5244141	0.02
577.2553101	0.03
591.6921387	0.04
596.7191772	0.05
612.5733032	0.04
669.7528076	0.06
672.2752686	0.16
675.8766479	0.05
685.3529053	0.11
689.7764282	0.10
697.1829224	0.06
704.4386597	0.05
705.5465088	0.04
706.6796265	0.03
714.2586060	0.04
715.3137817	0.44
715.9411621	0.03
733.3009644	100.00
734.3581543	2.89
739.3826294	0.06
745.0543823	0.04
746.5314331	0.22
760.1899414	0.12
775.7831421	0.08
777.3381348	0.03
789.3905640	0.04
806.3915405	0.03
814.5258789	0.02
819.3744507	0.05
827.2626343	0.20
843.9496460	0.02
845.5884399	0.02
846.4996948	0.08
848.3677368	0.02
851.4788818	0.29
863.4620972	0.24
864.5863037	0.03
877.6170044	0.15
878.5133057	0.09
880.1836548	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1229
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
208.2433777	0.01
230.3222656	0.03
258.0070190	0.01
282.1494141	0.01
283.2983398	0.01
284.9567871	0.02
286.1683350	0.52
291.0227661	0.11
297.3912354	0.02
301.1300354	100.00
301.9357300	0.04
302.9926758	0.04
309.5510254	0.02
313.5254517	0.05
318.4688721	0.01
321.0408325	0.01
327.0393066	0.02
329.3098145	0.01
339.1809692	0.01
343.0250854	0.05
351.1937256	0.04
368.6220703	0.01
369.2811279	0.05
381.1685791	0.01
383.1754761	0.04
385.9284058	0.04
387.1582642	0.17
393.5522461	0.04
404.5172119	0.02
407.4356079	0.01
411.4572144	0.03
416.2805786	0.01
417.2871094	0.02
428.1943359	0.02
429.2569580	0.01
435.6046143	0.02
442.8638306	0.09
445.3380737	0.04
446.0048828	0.02
461.5675659	0.01
463.1819458	2.48
463.9072876	0.03
467.6782837	0.02
486.3338013	0.03
489.5807495	0.03
503.2540283	0.51
505.2191772	4.80
506.1127319	0.02
517.4381714	0.01
527.1541138	0.05
530.6958008	0.13
531.3351440	0.48
532.1677856	0.01
537.9413452	0.01
538.9280396	0.05
540.4238281	0.01
548.5374146	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	660.1685
Annotation	Unknow
Peak:m/z	Relative Intensity
188.9388733	1.38
190.1728821	0.25
192.2183990	0.49
193.1197052	1.68
194.0117035	0.72
195.0230865	1.27
199.0790253	0.79
201.1260986	0.08
207.0356445	6.27
208.0486145	4.88
209.0712585	1.60
211.1008606	0.75
216.9040222	0.35
218.0201569	0.96
218.9096527	1.84
229.1826630	0.07
231.1144867	0.31
235.9764404	8.88
237.0437927	0.50
239.0182800	0.16
247.1330872	0.62
250.3366394	0.26
255.9787292	0.92
257.1535950	0.73
264.0785828	100.00
274.1134338	3.34
275.3428650	0.09
282.1375732	0.08
296.0779724	0.57
297.2226868	4.75
298.2879639	0.10
301.3294983	0.10
303.3321533	0.46
308.2220154	0.59
320.2407837	0.59
321.2224121	3.63
322.1719666	2.64
331.0818481	0.40
334.2505493	0.35
339.0299377	14.42
340.1989746	0.51
347.2874756	2.86
348.3110352	0.44
357.0783691	0.44
358.1074219	0.45
363.7655029	0.15
365.2349854	3.47
370.5358276	0.10
373.4255371	0.10
375.1611328	0.77
377.5864868	0.08
380.9366455	0.19
386.6500244	0.18
393.0941772	31.81
393.6951294	0.70
405.0891724	2.87
410.2133179	0.11
411.2968750	1.13
423.0868530	2.09
425.0180054	0.13
426.3982544	0.16
428.1790161	3.43
438.0781860	0.14
450.3002319	1.78
451.2125244	0.30
453.7178955	0.30
460.2333984	0.26
461.2204590	0.17
464.3275146	0.49
465.0889893	0.24
468.2795410	20.62
473.7333984	0.29
476.2612305	0.25
485.4113770	1.85
486.5109863	0.71
490.3044434	0.18
495.3151855	0.37
496.2587891	0.22
497.2536621	1.21
504.4508057	0.09
510.9548340	0.43
513.2187500	4.82
514.0574951	0.45
526.9226685	0.07
531.1798706	69.54
531.8258667	0.92
532.6437988	0.62
536.7085571	0.17
537.3311157	0.27
562.6224976	0.09
567.3567505	0.32
570.0242310	0.25
576.0256958	0.39
579.1598511	2.39
585.3790283	57.12
596.4873047	0.40
597.3088989	0.66
598.0648804	0.38
603.4018555	0.15
613.4229126	0.48
614.3226929	1.78
615.2208862	0.17
622.9981079	0.07
631.0958862	0.64
632.1691284	0.98
642.2042847	10.72
643.3556519	5.85
651.0662231	0.08
661.0247803	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.22
Annotation	Unknow
Peak:m/z	Relative Intensity
144.0350189	0.03
149.0982971	2.06
158.1858521	0.04
163.1448517	0.16
163.9140015	0.29
165.0577393	0.65
167.1742249	0.05
181.2669983	0.05
191.1485596	0.23
192.3473816	1.30
193.0267029	3.15
197.1340485	0.04
200.2388306	0.02
201.8615417	0.04
203.0898438	0.05
207.0937042	0.26
216.1447601	0.03
220.3045044	0.18
222.2699127	0.04
223.9741211	0.28
231.2782745	0.07
233.1966858	0.07
235.0821533	0.07
239.0752563	0.57
240.2570190	0.06
241.2287903	0.45
242.1726685	0.29
243.1392975	0.15
246.4096222	0.04
247.1666870	0.10
248.0949554	0.06
257.3867188	0.08
259.2043762	0.17
260.5859985	0.22
261.2603149	1.28
265.1413574	0.21
269.2331543	0.11
270.1645508	0.17
273.2741699	0.05
275.2464905	0.08
277.2753296	0.03
285.1355591	1.02
286.1423950	0.64
287.1237183	0.23
288.1521606	0.09
289.0720520	0.03
293.1708984	0.40
297.1273804	0.06
299.1955261	0.31
301.4185181	0.20
302.5339355	0.46
303.2507324	2.58
305.1246948	0.32
309.1611938	0.07
311.1743164	1.00
313.2079468	0.04
314.1022339	1.34
315.2810669	0.19
316.2092285	0.09
319.2796021	0.70
321.1724243	0.08
327.6276855	0.07
329.1732788	100.00
331.1428223	0.27
332.5959473	0.04
333.5140991	0.09
341.3018799	0.16
343.2269287	0.14
344.2641602	0.05
345.3615112	0.51
346.2832642	4.40
347.1757812	32.68
347.7907715	0.12
349.4639893	0.04
351.1382446	0.09
355.1874390	26.62
359.1536255	0.41
361.3130493	0.03
369.3477783	0.05
371.1568604	0.23
372.0984497	0.02
372.9896851	0.06
381.3109131	0.20
382.2351074	0.09
383.3424072	0.25
389.1710815	1.24
399.0446777	0.09
405.4067383	0.03
419.2138672	0.39
422.3220825	0.23
423.3990479	0.42
425.5415649	0.05
431.3695679	0.03
433.2611084	0.09
441.3046265	0.07
463.3786011	17.83
464.1674194	0.07
465.3248901	1.70
473.0822754	0.03
476.1217041	0.04
479.2937012	0.18
481.2706909	0.61
491.2949829	2.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	505.1332
Annotation	Peonidin 3-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
286.3264465	0.08
301.1138000	100.00
309.4515991	0.00
342.9729004	0.07
347.2469788	0.03
487.4196167	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1611
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
118.9822083	1.15
124.2727203	0.08
125.0654907	0.48
131.0074158	1.03
135.1061707	1.19
143.0108185	3.54
145.9039459	0.10
149.0275879	0.85
161.1183014	2.06
179.0574341	28.77
181.2591248	0.37
195.2013550	0.20
197.1466675	2.48
205.0761414	0.86
221.1707153	0.10
223.1341553	100.00
225.0787354	0.07
235.9274597	0.05
236.9370117	0.65
238.9335327	0.21
241.2318115	18.94
249.1405640	0.07
255.0131226	0.05
267.3086548	0.27
270.1620789	0.07
279.5709229	0.17
282.7992554	0.22
312.8472290	2.61
313.5938416	0.15
315.4046936	0.53
316.0290222	0.07
322.1092834	0.07
330.2271118	0.09
331.4083557	0.11
343.2274780	2.76
345.2282715	0.37
347.7423706	0.15
349.2795105	0.11
357.1627502	0.09
359.2525330	6.87
367.4218140	0.19
373.4632874	0.15
385.1661072	0.88
387.8999329	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	753.162
Annotation	Unknow
Peak:m/z	Relative Intensity
257.3450317	0.05
283.0001221	0.02
284.9396973	0.02
287.1607056	0.32
303.1232605	0.05
303.7720337	0.03
318.3542175	0.03
329.1513672	0.34
332.3402100	0.03
345.1552124	0.29
346.1574707	0.07
359.2240601	0.22
360.1875000	0.07
421.2600098	0.04
423.2036743	1.31
424.3699951	0.27
426.1806641	0.11
439.2825928	0.30
440.2980347	0.32
449.3704224	0.10
453.1520386	0.28
454.0877075	0.18
463.2808838	0.08
464.8281250	0.02
465.5654907	0.05
487.1715088	0.02
491.0551147	0.21
491.6704712	0.03
492.3998413	0.18
495.3941040	0.03
496.5178833	0.03
507.4298096	0.24
508.3400879	0.05
522.3200684	0.07
545.6658325	0.05
573.3001099	0.82
574.3673706	0.19
576.8474731	0.09
582.9407349	0.08
585.1876221	0.24
586.4931030	0.33
589.2908325	0.05
591.2681274	100.00
592.2725220	31.25
592.9650269	0.05
596.1476440	0.15
598.3078003	0.08
599.2376099	0.07
601.5031128	0.10
603.3384399	0.36
604.2665405	0.19
607.3641968	0.05
609.6992798	0.03
621.2476196	32.18
622.2509155	9.54
622.8598633	0.15
633.4816284	0.06
672.1290894	0.06
693.3897705	0.07
713.6912842	0.18
715.2417603	0.11
735.3923950	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	439.3563
Annotation	Lucidadiol
Peak:m/z	Relative Intensity
123.8249741	0.07
129.0382843	0.08
131.0030670	0.31
133.0106201	1.70
135.1105042	4.76
137.4447632	0.11
143.0796204	0.15
145.0775452	0.24
147.0117188	2.72
149.1291809	2.50
151.1438599	0.37
159.0594330	0.62
160.0469666	0.15
161.1029053	2.76
163.0888062	2.36
165.2026672	0.04
167.0972748	0.10
173.2343140	0.33
175.1740112	3.35
177.1427307	2.26
179.1347961	0.39
187.1420593	1.12
189.1869354	6.14
191.2055969	100.00
193.1273346	0.67
201.2185059	7.35
203.2151947	30.64
205.1605225	7.37
207.1375122	0.46
208.9067993	0.22
213.1611023	0.09
215.2211914	2.05
217.1932373	18.33
219.2091522	1.81
221.1294861	2.16
223.2133789	1.85
227.3218994	0.53
229.2869263	2.36
231.2645569	6.86
233.3134918	0.18
235.1536255	2.14
241.3251953	0.64
243.3566589	0.93
245.2570190	7.61
247.1365662	9.23
249.1819458	13.25
251.1961670	0.61
255.2639465	0.69
257.3970337	0.44
259.2872620	0.60
261.2942200	4.04
263.2045288	0.16
265.2795105	0.16
267.4668884	0.13
269.2914124	0.69
271.3110046	0.08
273.2966614	0.93
275.3159485	2.63
277.1916199	0.62
283.3027649	0.60
285.3516235	0.18
287.3220215	2.37
289.1492310	1.02
293.3338623	0.24
295.2515564	0.05
297.2651062	0.28
299.4674072	0.04
301.2807007	1.23
303.1277466	0.69
309.5990601	0.09
311.4768372	0.04
313.2072754	0.37
315.3789673	2.55
317.4821472	0.35
323.4375916	0.45
329.2914124	1.61
331.1469421	0.12
337.2189636	0.22
341.4205933	0.50
343.2532043	1.46
345.4931641	0.21
351.2907715	0.96
355.2593384	0.61
357.3413086	0.08
359.5222168	0.11
369.4208984	1.36
371.6122437	0.06
379.6629639	0.22
381.6276855	0.08
383.5683594	0.77
393.5267639	29.71
394.8135071	0.32
411.4443054	0.79
421.3901672	8.32
430.4540405	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	391.2828
Annotation	Di(ethylhexyl) phthalate
Peak:m/z	Relative Intensity
113.0683136	1.71
113.8868256	0.74
140.5390472	0.54
145.2023621	1.37
149.0274048	100.00
149.9411316	31.53
166.9984436	18.29
168.0558777	4.23
174.2909546	1.62
194.5379639	0.35
248.0480042	0.94
251.0597534	0.54
253.3228149	1.37
258.3311462	2.15
260.4186096	8.22
261.5531616	11.93
262.2893372	2.04
265.5016479	1.28
278.9876709	19.22
280.0109863	31.71
286.1528015	0.94
303.0369873	6.98
306.1550293	1.68
318.9375	0.59
320.7552795	2.98
324.2197876	1.28
327.8797913	1.41
329.5014038	0.93
338.3940125	1.83
346.0761719	7.59
347.1765137	2.49
348.2060242	1.27
350.9847412	6.82
356.5696106	0.59
360.1576538	0.64
360.8437805	4.04
361.4519348	3.52
363.8873596	0.69
369.9773865	0.60
374.1834106	8.60
375.2293091	4.05
382.6149597	0.79
383.7201538	1.57
391.4412231	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1087
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
100.9862976	11.56
112.9216156	18.69
115.0384445	0.35
117.0219193	0.73
119.0482788	19.39
124.9877548	2.64
130.9552917	7.79
143.0421143	20.98
148.8823242	2.73
159.0892029	0.11
160.9773254	19.64
179.0022278	100.00
184.1292725	0.08
185.0455017	0.14
186.0348511	0.18
199.2055054	0.11
221.2431335	0.89
281.0919189	4.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	446.1931
Annotation	Unknow
Peak:m/z	Relative Intensity
134.1377411	0.11
136.1007843	0.05
141.1284332	0.24
144.6251526	0.05
145.2483521	0.05
147.0343170	0.69
154.2699432	0.05
162.0355225	0.77
163.1023407	0.13
164.3489990	0.21
171.1246643	0.03
172.9532623	0.19
173.9683685	0.06
177.3374939	0.02
180.0872803	0.67
190.0766296	1.68
191.2068176	0.65
192.0564270	0.07
200.1771545	0.04
201.1813049	0.09
206.1525269	0.34
207.0670319	1.75
208.1678162	4.02
210.0666504	0.16
211.3900909	0.24
213.0054932	0.04
217.0075378	1.04
219.2591553	0.08
223.1954041	3.26
228.0769958	0.11
229.0435181	0.05
230.9234924	0.04
233.5820618	0.18
234.1860657	2.48
236.2322693	0.14
236.9933472	0.03
242.1621704	0.05
251.1423340	32.62
254.3676758	0.31
258.1237183	0.55
260.2892151	0.31
267.5444946	0.02
269.0746765	0.02
272.1419678	0.15
275.8394775	0.16
277.4010315	0.49
278.2633057	0.03
279.4230042	0.03
284.3366699	0.14
286.3980408	0.16
289.1397095	0.06
291.3428955	0.07
295.4286194	0.03
297.9738464	0.09
302.2532654	0.08
303.2810669	0.04
305.1721497	0.03
308.1687012	0.47
309.5458679	0.03
315.3972168	0.14
317.3859558	0.21
318.6564331	0.11
319.3881226	0.11
325.9639893	0.07
327.7162781	0.09
330.2636719	0.20
331.2073364	0.02
333.3426514	0.15
341.3368530	0.31
345.4627075	0.27
346.3237305	0.24
356.4009399	0.94
358.3836365	1.02
359.2649841	0.27
366.5051880	0.08
367.2160339	0.03
372.3818054	0.31
374.3266296	70.99
375.0321350	0.25
382.4168701	0.03
384.3872986	8.74
385.4524841	0.38
387.3616943	0.06
400.4493408	0.38
402.3324585	26.59
402.9895630	0.28
409.3658142	0.04
410.3575134	0.48
414.1892700	0.03
418.4200745	100.00
427.5126038	0.24
428.3007507	0.28
429.5122986	0.10
431.2960815	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0932
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0863953	0.05
132.8910522	0.21
137.0930481	0.21
141.0205841	0.05
149.0301208	0.05
151.0584259	2.19
152.1535645	0.11
153.1387787	0.66
156.9888306	0.05
163.0350189	0.27
165.0413208	0.28
165.9899902	0.03
169.0527496	0.35
171.0318756	0.11
173.0052795	0.12
174.0604401	0.60
175.0010681	0.31
177.2297821	0.04
179.0509644	1.25
181.1893005	0.09
185.2169495	0.20
187.0329895	0.34
189.2105713	0.03
190.0954437	0.17
191.1360016	0.19
192.1026001	0.22
192.9867859	0.69
195.1656799	0.30
199.1067352	0.16
201.1156769	0.41
202.1322479	0.12
203.0389404	0.43
205.0340729	0.11
206.2653503	0.21
207.2225800	0.09
209.1509857	0.11
211.3060760	0.23
213.0202637	0.31
214.9675598	0.26
217.0997925	0.28
218.2241669	0.04
219.1226196	0.07
221.1342316	0.11
222.1916199	0.21
223.1599274	0.12
224.1166840	0.06
227.1385651	1.56
228.1739197	0.20
229.0428467	0.35
231.1492920	0.29
232.8924561	0.09
234.0055847	0.04
235.3051453	0.14
237.2756195	0.33
239.1569519	0.26
241.1424561	0.95
243.1405334	3.08
245.0762024	0.21
247.1208191	0.09
249.0513000	0.23
253.0577393	0.41
255.1453247	14.33
256.1581116	2.19
257.1234131	0.84
259.1425781	0.71
260.4006042	0.04
261.2446289	0.05
263.3855896	0.09
265.2866821	0.29
267.2125244	0.27
269.0954590	2.08
269.6992798	0.03
271.1785889	0.10
273.3642578	0.08
275.2801819	0.08
278.4187927	0.09
279.6492310	0.31
281.2845459	0.21
282.2242126	0.03
284.0604248	99.86
285.0958557	100.00
286.3274231	0.05
289.3444519	0.11
293.0922852	0.10
295.2572632	0.20
296.0782166	0.05
297.2085571	1.54
298.1121521	0.13
299.1647034	2.97
301.8961487	0.24
303.1394653	0.18
307.2330322	0.05
309.2527161	0.35
311.2728577	0.23
313.1654053	0.05
314.2343750	2.43
315.1131897	0.78
321.3234253	0.19
323.1380920	0.25
325.4360046	0.05
327.1057739	21.05
328.1125488	0.04
329.2059326	0.54
331.3895264	0.07
336.8660583	0.11
339.1950684	0.68
341.3757324	0.16
351.2274780	0.16
355.2015991	0.05
357.2729797	3.29
358.3658142	0.09
359.3273315	0.27
361.4631653	0.05
368.9541321	0.11
373.0084839	0.19
373.7494812	0.04
374.8226624	0.07
379.2929993	0.24
381.3452759	0.06
385.3338318	0.15
386.2921448	0.34
386.9578552	0.05
389.3044739	0.11
391.2912292	0.04
399.2081604	0.04
400.2381287	0.04
401.4115295	1.36
403.3865662	2.86
405.0382385	0.03
419.3616943	0.83
420.4681702	0.08
429.1512756	0.73
430.3306274	0.20
432.5807800	0.04
446.8403931	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1485
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.0407104	0.17
164.2294159	0.04
165.1039429	1.06
169.0529785	0.03
172.7646637	0.24
175.0284271	0.08
177.2847595	0.06
179.0333710	0.14
181.0635071	0.07
182.9655762	0.02
187.1801147	0.55
188.9943542	0.15
190.8737183	0.08
193.2541351	0.03
197.1320953	0.04
201.0668640	0.23
202.0510864	0.04
205.1548920	0.04
207.2560425	0.06
211.0398407	0.08
213.0571899	0.16
215.3656616	0.07
217.2837524	0.09
219.1264343	0.12
219.9739227	0.04
225.2546844	0.18
229.1096191	1.70
230.0871735	0.14
231.2137451	0.25
233.2436066	0.08
233.9450989	0.05
243.1157532	0.37
244.8005524	0.04
247.0933990	20.93
248.1378174	1.60
249.0555878	0.08
253.1693726	0.07
254.2401428	0.15
255.2701416	0.04
257.1115723	0.18
259.1921387	2.78
260.2236938	0.46
261.3953552	0.10
266.9969177	0.11
271.1407471	6.40
272.1289978	0.55
273.1507263	0.81
275.1592102	3.91
276.1950684	1.31
283.1912842	1.38
284.0464478	0.59
285.2478638	0.64
286.0315552	0.17
287.0852661	1.74
289.1114807	15.47
291.1047363	58.29
292.2392578	4.28
295.1580811	0.26
299.1586609	0.53
301.0728760	16.50
302.1349487	1.67
303.2162476	4.96
304.2451172	0.31
311.0766907	0.17
313.1865540	0.74
314.2067871	0.05
315.2880249	0.33
316.2628784	0.13
325.0448608	0.37
331.2056885	0.31
332.1665649	0.03
333.1497803	1.14
334.2790527	0.29
343.1946411	0.04
375.0344238	0.08
389.3183594	0.07
391.3820190	0.10
399.1771851	0.04
400.2718506	0.18
405.3131714	0.04
407.3966675	0.04
409.1797485	43.27
410.1981201	7.76
411.2935791	13.52
412.2744751	2.54
414.2328491	0.11
415.1223145	0.06
416.1209717	0.03
417.2727051	0.52
418.2175293	0.27
421.1419678	3.48
422.4764404	0.61
423.2737427	0.36
424.1376953	0.07
425.3923340	0.25
427.1046143	100.00
428.1257324	16.55
428.8121338	0.17
433.0607300	0.11
435.2711792	3.40
436.3338013	0.37
439.1353149	3.23
440.1937256	0.91
447.4136963	0.12
448.3749390	0.20
451.2214966	0.08
453.1065063	8.84
454.1875610	1.67
469.4094849	0.03
481.3776245	0.04
496.2467651	0.03
498.3549805	0.15
503.4410400	0.14
507.1223145	0.04
524.6621704	0.24
533.2192383	0.07
543.2098389	1.67
544.3915405	0.45
552.2622681	0.09
556.4614868	0.11
559.1542358	0.11
561.1504517	5.04
562.2351685	1.20
563.0237427	0.05
581.5401611	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0678
Annotation	Unknow
Peak:m/z	Relative Intensity
164.5166626	0.02
174.8746033	0.13
179.0284119	0.17
183.1640015	0.11
185.1652222	0.15
187.0703430	0.56
200.9631805	0.03
204.9556274	0.07
210.9719543	0.06
217.0644684	0.39
224.1354370	0.06
226.9718170	0.37
229.0136719	0.03
230.1654358	0.19
234.9407501	1.48
244.9006042	1.58
252.9896851	0.04
257.1925659	0.32
261.2373657	0.04
264.9094543	0.20
271.1669922	0.04
272.9735107	0.09
274.8802185	0.89
277.0779724	3.84
279.2564697	0.07
283.2130737	0.05
288.9574585	5.21
291.2597046	0.05
292.9767761	0.89
294.9509888	2.65
301.0830688	0.13
302.9835205	0.18
303.6988831	0.05
305.0617065	0.25
306.3132935	0.58
307.0676270	6.13
308.9795532	0.04
313.1498413	0.13
319.0030518	3.78
323.0498657	0.03
325.0283813	4.41
328.9948120	0.13
331.1873779	0.23
334.9379272	0.10
335.5474243	0.03
336.3150024	0.24
336.9976807	3.11
337.8441162	0.07
342.8402100	0.06
346.3516235	0.02
346.9838867	0.41
349.0244751	17.06
350.0294800	0.05
351.1367188	0.71
354.8785400	1.90
355.5054321	0.02
361.1014404	0.08
362.1744385	0.19
363.1746216	0.06
364.1198120	1.41
365.0864868	3.01
365.9684448	0.06
367.1088257	4.36
367.8858032	0.04
372.2423096	0.16
373.1988525	1.19
374.2266235	0.04
375.2204590	0.10
379.1094360	0.83
380.3471069	0.34
381.0811157	0.21
382.1066284	0.21
383.2883911	0.04
384.7676392	0.03
389.1679688	0.08
391.0961304	6.99
392.1470947	0.04
395.1984253	0.12
397.0731201	9.02
398.0178223	0.04
406.9849243	0.78
408.4742432	7.43
409.1397095	100.00
411.0128784	0.20
412.2015381	1.99
412.9401855	0.70
414.2092285	0.10
415.0885010	2.93
416.3005371	0.03
418.2352295	0.23
420.7777100	0.04
421.3977661	0.11
425.9581909	1.35
427.1632690	24.87
434.2797241	0.03
435.4168091	0.07
439.1708374	0.18
446.1889648	0.03
449.1268921	0.11
449.9423218	0.23
451.1848755	0.27
452.9843750	0.04
457.2294312	0.14
459.5795288	0.04
462.9312134	0.28
464.1354370	0.05
465.2572632	0.13
467.4509888	0.32
468.5276489	0.73
469.1551514	2.01
472.9839478	0.11
481.0159912	0.26
484.3180542	0.12
486.7774658	0.05
489.7114868	0.09
492.4963989	0.06
493.6038208	0.08
494.3116455	0.10
498.0885620	1.46
499.0579224	5.26
499.8768311	0.16
500.9788208	0.11
507.8895874	0.89
508.9165649	0.24
510.9141235	0.61
512.1741333	0.03
513.1110229	0.19
514.1619263	0.06
525.2503052	0.29
525.9803467	0.12
528.4690552	0.79
529.1362305	9.79
530.0232544	0.04
533.7614746	0.05
544.1890259	1.00
545.0534058	0.10
552.0847778	0.24
553.1210327	1.19
570.6722412	4.86
571.2805176	12.79
579.1912231	0.10
579.9373169	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	797.1889
Annotation	Unknow
Peak:m/z	Relative Intensity
223.3363037	0.01
257.1578064	0.05
287.0997925	0.04
288.0299072	0.07
301.0827026	0.03
305.2254944	0.05
329.2583008	0.09
330.5725403	0.07
331.3355713	0.19
333.3114319	0.05
345.3470459	0.02
365.3238525	0.03
367.3927612	0.02
371.1838379	0.01
372.2347717	0.02
373.3046875	0.42
393.3235474	0.01
407.5705566	0.02
422.9250488	0.02
423.7481079	0.02
424.3899536	0.06
447.5070801	0.01
467.2960815	1.31
471.3179932	0.02
479.3168335	0.01
482.5906982	0.03
484.5192871	0.01
491.6165161	0.04
492.2810059	0.07
493.2909546	0.07
501.4375610	0.03
509.6179810	0.12
534.1375122	0.03
535.2175293	0.16
542.4530029	0.02
574.1670532	0.07
575.3952637	0.03
585.3908081	0.02
591.3230591	0.54
592.2902832	2.62
593.3784790	0.36
597.9812012	0.01
611.0114136	0.05
615.5901489	0.01
616.3123169	0.19
617.3936768	0.21
626.2872314	0.03
629.2346802	0.11
631.3314819	0.08
633.2025757	0.14
635.2619019	100.00
635.9438477	0.30
645.1456299	0.12
664.5017090	0.10
665.4887085	0.11
669.3040771	0.03
670.3925171	0.02
677.0130005	0.03
706.7040405	0.04
709.1822510	0.02
723.6094360	0.02
730.3010864	0.02
731.3029175	0.05
770.3967285	0.05
774.2805786	0.10
777.2491455	0.06
778.5137939	0.08
779.4582520	0.21
797.2802124	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	249.0802
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
79.9109192	8.79
81.0300598	0.16
96.9005737	55.88
109.9702301	0.51
110.8882599	0.60
116.8152008	0.31
127.1999359	0.17
131.2083130	0.38
151.0984039	0.16
154.8583679	0.70
163.0754852	0.33
167.0985107	0.12
170.9135437	0.15
181.0504456	100.00
181.8035126	0.24
203.0146790	3.34
204.9866791	1.63
206.1538849	0.40
221.1129303	0.10
230.1097260	3.20
231.1269379	30.75
232.2376099	0.34
249.0962524	17.15
250.2599030	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.1186
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.8538704	44.32
69.8803558	6.69
71.9995270	1.73
97.2514038	0.28
98.1332855	0.43
112.0047607	6.82
113.0048828	1.38
114.1589050	3.52
115.0909424	2.85
116.0166321	56.70
130.0625000	35.87
131.1643219	0.25
133.1617889	0.56
140.0552063	2.10
141.1738434	0.19
156.9971466	77.31
157.9765778	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.088
Annotation	Castamollissin
Peak:m/z	Relative Intensity
137.0383148	0.11
149.0680847	0.05
151.0284729	0.12
153.0002136	0.05
161.0737915	0.10
163.0448303	0.35
163.9707336	0.10
165.1637878	0.16
173.0181580	0.09
175.1323242	0.18
176.9716187	0.58
183.0230713	0.06
189.3456116	0.15
191.0261536	0.53
193.1597748	0.84
203.1856384	0.13
205.1393127	0.10
207.2206573	0.18
209.3206787	0.07
213.0758514	0.30
215.2081604	0.13
217.0901337	1.55
219.0937500	0.36
221.1120453	0.03
226.9687195	0.02
229.0911407	0.10
230.0933075	0.05
231.2071228	0.25
233.1739044	0.19
235.0254822	0.18
236.7693176	0.03
239.1921234	0.05
243.2539978	0.20
245.0081787	0.23
247.2282715	1.20
248.9023743	0.16
253.2623596	0.04
254.2237854	0.04
255.3609924	0.21
256.0445862	0.22
257.1860657	1.47
259.1235962	0.26
261.3824768	0.05
264.0301208	0.03
267.3835449	0.14
268.9760437	0.37
271.2932739	0.19
273.0804138	0.27
275.3139343	0.06
277.1527100	0.03
281.2544556	0.33
283.2514954	0.79
285.2777710	0.91
287.3722534	0.32
293.3891296	0.04
295.2026978	0.28
297.2696228	0.18
298.3401489	0.17
300.0567932	100.00
301.1134949	44.73
302.0527649	0.10
303.3584595	0.07
307.0076599	0.08
311.2693787	0.38
313.0886841	4.71
315.0933838	30.85
319.1710815	0.16
323.0873413	0.15
325.2280273	2.11
326.0816040	0.08
327.1297913	1.10
329.2029114	0.21
330.4246216	0.14
331.3426514	0.10
337.1557617	36.12
339.1118164	0.06
341.1103210	0.20
343.1587524	10.76
345.3250122	0.09
347.3945923	0.04
351.3061523	0.17
355.2367554	5.07
357.1086426	0.04
359.3391113	0.17
365.4427490	0.09
366.6876526	0.13
367.3768311	1.34
373.1083069	4.05
377.5281677	0.03
379.3941345	0.04
385.3020630	0.84
388.2744141	0.11
391.3807068	0.04
395.3029480	0.17
403.4790344	0.04
408.9712524	0.04
417.4569397	0.09
419.2884216	0.32
420.9163818	0.07
427.3022156	0.45
435.2208252	0.05
445.2482605	2.07
445.9266052	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.109
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1256866	0.03
147.0418396	0.06
149.2244873	0.03
153.0553589	0.01
165.0981445	0.07
167.0989227	0.22
175.9766388	0.01
177.0227051	0.11
178.0227966	0.02
179.2617798	0.05
180.9398499	0.10
187.1161194	0.05
189.1117554	0.12
202.9650879	0.03
217.0077667	0.05
227.3485718	0.03
233.1193237	0.08
247.1968994	0.05
257.4266968	0.03
262.1506653	0.02
266.2729187	0.02
269.9180603	0.04
271.6067200	0.04
274.1504822	0.04
276.7738037	0.06
278.3037720	0.11
280.3124390	0.02
282.3707886	0.06
283.2078247	0.11
285.2322693	0.27
286.8361511	0.10
287.4837952	0.07
293.1307068	0.18
294.2572937	0.03
297.1288452	0.16
298.4376221	0.24
299.2869263	0.74
301.0946350	0.07
303.3036804	0.03
307.1793518	0.15
310.3964233	0.09
313.0776978	0.55
314.0335693	0.14
315.3486328	0.04
321.2638550	0.03
325.3580627	0.03
325.9731445	0.05
327.2618713	4.34
328.1701355	32.68
329.1630554	100.00
330.2955933	0.84
331.3013916	2.76
335.2509155	0.05
339.3551636	0.08
341.2486572	4.71
343.1735229	3.41
346.9200439	0.07
351.2708130	0.06
353.2615967	0.16
355.2586060	0.17
357.2622681	0.32
365.0101624	0.03
366.3363953	0.19
368.0523682	0.06
369.4478760	0.03
371.1619873	4.11
372.4467468	0.06
373.4945374	0.04
381.1470032	0.27
383.2644348	1.56
395.3169556	0.03
397.1910095	0.06
398.8901672	0.02
401.2435608	2.17
402.5187073	0.08
406.9869080	0.04
411.4763489	0.08
413.3408508	0.16
415.3081360	0.51
417.2995300	0.10
425.3401794	0.15
429.2718811	1.11
443.2773132	0.91
446.4852295	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1325
Annotation	Melicitrin
Peak:m/z	Relative Intensity
331.1690674	100.00
367.3146362	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.151
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0806732	0.05
168.1567993	0.02
169.0985413	0.07
171.1815338	0.08
172.1160278	0.01
173.2815704	0.03
174.0102997	0.01
175.0909576	0.01
177.2100067	0.02
179.1744080	0.07
180.0720520	0.02
182.2488708	0.12
183.2277985	0.13
184.1693878	0.03
185.1693420	0.19
186.1270752	0.05
187.1944885	0.28
188.2573242	0.01
189.1278687	0.08
190.1195679	0.01
191.1754456	0.01
192.1636200	0.01
195.2288208	0.28
196.1643372	0.14
197.2491150	0.33
198.2025146	0.05
199.1252441	0.27
200.1878815	0.03
201.1858215	0.07
202.3366394	0.00
205.1647339	0.01
207.0221100	0.01
208.3191528	0.01
209.3162079	0.03
211.0932007	0.46
212.2618408	0.10
213.2166290	0.48
214.2199554	0.14
215.0916290	0.09
216.2529602	0.00
217.1927795	0.08
218.2397156	0.01
219.0822144	0.04
223.1827087	0.18
224.2020569	0.07
225.1647644	0.01
226.4391785	0.08
227.1532898	0.44
228.0742645	0.10
229.2522125	1.58
230.2134857	0.29
230.9332581	0.01
234.5429382	0.00
237.2068939	0.04
239.1425781	0.64
240.2099152	0.41
241.2043915	0.92
242.2505035	0.07
243.2471771	0.14
244.0329590	0.04
250.2076569	0.00
255.1908569	1.29
256.2037964	0.62
257.2406311	3.28
258.2688904	0.41
259.1895752	0.02
260.1951904	0.00
267.1686401	0.96
268.2456055	0.15
269.1892395	0.10
270.1097107	0.04
271.2390137	0.01
273.3435364	0.00
274.1671448	0.01
278.1267700	0.00
279.0744629	0.01
281.2486572	0.02
282.2007446	0.03
283.3552246	0.65
285.0784912	100.00
286.1292725	11.27
287.2005005	0.01
288.4338989	0.01
295.1748047	0.01
297.1458130	0.05
298.0586548	0.08
299.1832886	0.29
300.1459351	0.05
301.5905151	0.01
303.5285645	0.01
309.3079224	0.01
310.4724731	0.01
311.3068237	0.01
313.2227783	0.01
314.3134155	0.01
315.1336365	0.02
320.4958496	0.01
322.2150269	0.00
323.2930908	0.02
325.1728516	0.04
327.1054077	2.15
328.2251587	0.49
329.2816162	0.01
335.3007202	0.01
339.2148438	0.06
340.4007568	0.01
341.2801514	0.01
342.8989868	0.01
349.2291260	0.01
351.1818848	0.03
352.1036377	0.01
354.0783691	0.01
355.4473267	0.03
357.1881104	0.45
358.1717529	0.07
365.1724854	0.00
367.2991943	0.04
369.1420288	0.05
370.5422974	0.01
373.2227783	0.11
374.1079102	0.01
383.3364868	0.02
393.3411255	0.06
394.3390503	0.03
404.1433716	0.00
411.3032227	0.03
412.4530640	0.00
413.3646851	0.00
414.1864624	0.01
415.3890991	0.01
417.4639893	0.01
419.6665649	0.01
423.2893677	0.01
426.2281494	0.01
429.2366943	0.04
431.2538452	0.04
435.3251343	0.01
439.2198486	0.02
441.3795166	0.02
442.2260742	0.00
443.4505005	0.00
445.3550415	0.01
447.1331787	0.15
448.2859497	0.06
457.3990479	0.01
461.3563843	0.01
467.4561768	0.02
471.2488403	0.01
473.4715576	0.01
474.4197388	0.01
475.2736206	0.01
476.3833008	0.00
497.4647827	0.01
499.2164917	0.01
503.1679688	0.01
505.5708008	0.00
507.1770020	0.02
517.2965698	0.01
525.6203613	0.01
527.3561401	0.01
532.3188477	0.01
533.2076416	0.04
537.6589355	0.01
547.3552856	0.37
548.3125610	0.04
549.3635864	0.18
550.3283691	0.03
557.3186646	0.00
558.1062622	0.01
565.3233643	0.18
566.3186035	0.04
571.7124634	0.02
573.5576782	0.00
575.3562622	0.23
576.5581665	0.03
579.1965332	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.11
Annotation	3,4',5,6-Tetrahydroxy-3',7-dimethoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
150.9531708	0.05
163.0687256	0.17
175.1079254	0.14
176.9409180	0.25
187.1160583	0.68
196.1910400	0.28
205.5464783	0.10
208.9626312	0.06
240.9640198	0.04
242.9840393	0.07
254.9412689	0.04
266.2103577	0.05
283.5556946	0.08
298.5217285	0.12
301.3704224	0.17
317.1563721	5.78
318.3290405	12.49
319.1567383	100.00
319.7869873	0.30
329.3171387	0.28
332.5083618	0.04
343.2353516	0.37
347.1809692	0.08
354.4149780	0.23
360.0657959	0.03
361.2781982	2.24
369.4050293	0.05
370.6206665	0.09
373.3178711	0.03
385.0371094	0.32
391.2492065	0.29
409.0917358	0.14
419.1190796	0.16
420.8132935	0.03
427.3345337	0.67
432.9232788	0.26
441.8977051	0.06
444.8359375	0.20
447.4201660	0.08
448.4942017	0.22
449.7100220	0.17
457.0811157	0.07
463.0732422	0.23
464.9287109	0.11
469.1951904	0.26
487.2056274	3.29
495.4309692	0.18
500.7408447	0.16
505.1813354	7.55
508.5586548	0.29
514.7028198	0.12
522.7998657	0.05
523.6351929	0.07
534.9755859	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.2632
Annotation	Linoleamide
Peak:m/z	Relative Intensity
95.0411301	2.29
96.9270325	0.89
109.1202240	1.35
110.9256668	0.33
113.9985809	1.52
120.7489700	1.56
122.9398575	2.10
124.0639954	0.63
125.0625000	0.40
126.1174850	0.54
127.2057343	0.62
128.0841064	1.43
133.1858215	0.85
135.1198425	1.20
137.2030945	2.33
139.0206299	2.10
142.0484924	4.75
145.1116028	0.92
146.1263733	0.40
149.0913239	2.27
151.1943054	0.43
152.2975769	0.25
153.1301880	0.60
153.8760986	0.30
156.0175476	1.79
161.1811676	2.54
161.9895630	1.16
163.1967926	1.09
165.0269318	2.15
166.1912842	0.23
167.1257629	0.57
167.9842529	2.03
170.1566467	0.92
175.0296936	2.82
177.1523285	2.67
179.0677338	4.02
181.0606079	1.10
184.1444092	2.51
189.3694611	0.87
191.1007538	0.30
192.2482910	0.33
194.8666077	0.69
196.1621399	0.76
198.1118469	1.24
203.1658630	0.40
205.2760925	1.57
207.2398987	0.20
210.2141113	0.95
219.0770569	0.30
220.1028442	0.21
221.2584534	0.50
224.0043945	0.67
235.1511230	0.56
236.3001099	0.54
245.1787109	45.02
249.2277222	7.77
262.3240051	3.80
263.2351685	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3047
Annotation	Sphinganine
Peak:m/z	Relative Intensity
95.02513123	0.62
96.10675049	0.01
97.05418396	0.21
98.96536255	0.04
109.046051	0.64
110.1125412	0.10
110.9709015	0.10
111.9886017	0.10
123.0319519	0.24
125.0144501	0.14
129.9950562	0.03
133.0411072	0.02
137.1401062	0.13
140.0948792	0.06
140.9727478	0.07
147.7963715	0.03
150.3457336	0.16
151.1847229	0.05
153.0004272	0.22
157.0884552	0.03
163.5148621	0.04
165.0869751	0.38
173.1358337	0.09
175.1712036	0.04
179.006958	0.27
182.8931274	0.03
190.081955	0.05
190.9599609	0.06
192.1941223	0.10
193.2222595	0.14
199.3704224	0.05
200.883606	0.06
202.1354675	0.04
205.0973511	0.06
207.2775879	0.09
212.1207275	0.36
213.058075	0.02
215.3205566	0.07
219.2796631	0.16
220.2966919	0.02
224.1298523	0.04
226.4325562	0.03
227.218689	0.02
228.0695496	0.05
229.1157532	0.47
229.8074036	0.02
236.5150452	0.08
238.1395264	0.03
239.3276978	0.06
240.3079529	0.73
243.210083	0.03
244.164917	0.08
247.0778809	0.08
249.1834106	0.22
253.2667847	0.04
254.3013	0.27
257.0901489	0.91
258.1652222	0.08
260.4128418	0.14
261.2015381	0.14
266.3222046	5.29
267.2086792	0.59
270.2580261	0.03
271.1970215	0.25
273.2597351	0.11
274.1383057	0.07
275.2692871	0.22
278.9417725	0.03
280.3670044	0.08
284.3001709	100.00
285.118042	0.72
287.1109009	0.15
302.2778931	0.05
303.3852539	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.16
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9918213	0.33
183.0325317	2.30
186.1131287	0.08
188.1988831	0.18
188.8213806	0.05
192.0406342	0.05
193.1235809	0.30
197.3941650	0.10
203.3012085	0.34
204.0845337	0.07
205.8778687	0.07
207.2792511	0.22
209.2864990	0.05
214.2624664	0.34
215.0057983	0.08
218.8619232	0.18
219.9385834	0.14
223.8588562	0.11
226.1116180	0.14
227.0846252	0.15
231.0648193	0.23
232.0352783	0.17
241.2711792	0.09
242.1121216	0.32
243.2113647	0.32
244.2774506	0.13
247.3144531	0.07
249.2463989	0.19
251.1610413	0.33
252.0515442	0.31
255.2653198	0.24
256.1301270	0.05
257.4786072	0.21
259.1339111	0.66
260.0313721	0.04
261.1426697	0.27
262.2799072	0.05
267.4060669	0.40
268.8708801	0.11
270.1682739	0.83
271.2259216	4.52
272.1697998	0.05
277.1110229	0.14
281.3081665	0.32
285.1546936	0.74
285.7936707	0.06
287.1986084	3.14
288.1399231	0.96
289.3762817	0.15
297.2014160	0.11
298.0976868	0.34
298.9469910	0.04
300.2328186	0.73
301.2040100	0.76
302.1262207	0.08
303.2155762	0.65
304.8457031	0.07
309.0410156	0.11
310.1796875	0.15
311.1040955	0.10
312.2937622	0.12
313.2138672	0.56
315.0586548	10.24
316.1593018	16.64
319.1639404	44.94
321.1560669	0.14
325.0201416	0.15
327.2120056	0.53
328.0924072	0.29
329.1698914	3.91
330.1902466	34.39
331.1567688	100.00
333.0287476	0.12
335.1864624	0.08
337.2725830	0.22
338.9607544	0.05
340.3211670	0.19
341.1153564	0.85
343.1943970	1.85
345.0646362	0.13
347.2932129	0.06
353.0585938	0.51
355.2911377	0.28
359.4157104	0.07
367.3362427	0.08
373.2516479	2.10
385.1789551	0.19
387.3469849	0.20
389.1121216	0.05
391.3272095	0.16
397.3722534	0.08
401.3005981	0.05
403.5132446	0.34
407.2758179	0.08
411.2908936	0.08
413.4368896	0.21
417.2615967	0.18
418.2621460	0.38
431.6889648	0.08
432.3508301	0.21
434.4615479	0.13
435.2833252	0.18
441.0263672	0.20
443.2747192	0.06
447.5523682	0.20
449.2099609	0.05
451.2283325	0.05
457.2411499	0.34
458.1379395	0.32
459.4607544	0.40
463.2582397	0.40
464.2791138	0.31
465.4151001	0.18
471.5319214	0.12
472.5259399	0.24
473.4805908	0.33
474.1795654	0.04
475.2713623	0.63
476.3880615	1.69
477.3299561	1.33
478.2648926	0.21
479.2539062	0.74
480.6505737	0.19
486.5588989	0.06
487.4465332	0.50
493.1369629	0.49
495.4721069	0.06
497.6919556	0.15
500.0193481	0.20
506.2402954	0.23
507.2593994	1.45
511.2051392	0.11
513.3424072	0.05
517.5251465	0.31
519.4797363	0.11
522.3527222	0.15
533.3258667	0.16
546.3466797	0.05
548.4543457	0.14
549.4699707	0.21
567.3063965	0.13
573.5504150	0.36
575.0637207	0.07
577.5696411	0.41
578.4598999	0.35
579.6013794	0.74
593.2210693	0.59
594.5526123	0.27
595.3370361	0.49
597.1856689	0.04
603.4558716	0.13
606.1582642	0.15
607.4054565	8.44
619.4418335	0.39
620.3817749	0.29
621.4443970	2.49
624.4290161	1.90
639.3082886	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.2627
Annotation	Unknow
Peak:m/z	Relative Intensity
303.1227722	1.61
304.2423706	0.10
321.0817871	1.66
322.1692505	0.09
362.8739319	0.02
381.2179565	0.60
382.1618042	0.04
418.7803650	0.05
419.4619141	0.06
420.3507385	0.02
423.5001831	0.05
437.1611938	0.48
438.3832397	0.02
443.3524780	0.04
467.3515625	0.27
477.4040527	0.02
479.2305298	3.31
480.3822632	0.10
485.2330322	0.13
495.5629883	0.13
497.2476196	0.90
498.1910400	0.06
521.3058472	0.10
534.3253784	0.07
539.2970581	6.68
540.2561646	0.54
581.0747681	0.08
581.7042847	0.06
599.4353638	0.05
607.3923950	0.08
625.2938232	10.82
626.3970947	1.73
643.3147583	51.28
644.3651123	6.34
661.5255127	0.05
662.5321655	0.03
685.4464722	0.22
686.4810181	0.04
697.3872681	0.06
703.3892212	1.01
704.3265991	0.07
721.6253052	0.02
723.2920532	0.05
741.3587036	0.19
745.3507690	0.31
746.2569580	0.16
755.2943726	0.03
757.5464478	0.02
759.2756958	1.03
760.6156006	0.09
765.2480469	0.10
773.7289429	0.03
789.4697266	1.18
790.4072266	0.40
799.3864746	0.02
801.3151245	5.98
802.4750366	0.98
807.4472046	1.75
808.5144653	0.41
817.5174561	0.20
819.3579712	4.18
820.4263306	0.44
831.3639526	0.54
832.1564941	0.18
834.5541992	0.02
835.5678711	0.05
842.4449463	0.08
843.3853149	0.24
844.6567993	0.04
848.8019409	0.15
849.4742432	0.94
850.4564819	0.24
861.3931274	22.89
862.3539429	5.09
863.0133057	0.03
875.4735718	0.05
877.5015259	0.06
885.2234497	0.08
891.4769287	0.02
892.4381714	0.01
903.5197144	0.30
904.3650513	0.14
921.5131836	0.12
922.1881714	0.02
929.4834595	0.65
930.4341431	0.03
947.3455200	100.00
948.4094849	19.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.1449
Annotation	Unknow
Peak:m/z	Relative Intensity
127.7180939	0.62
130.0132446	2.68
132.0170898	0.55
147.0306702	100.00
171.2226257	0.26
188.2537231	0.48
218.8262939	0.59
246.9015503	0.40
257.0754395	0.85
262.9002380	2.34
272.0121460	1.59
274.9120483	0.45
275.9778137	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.12
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1622620	0.12
148.9721375	0.09
149.9056702	0.10
151.0475006	0.78
162.8125610	0.03
164.0361023	0.11
166.2265320	0.05
168.8051910	0.03
177.8769226	0.11
179.0057983	1.99
189.1825256	0.08
190.1933899	0.02
191.0618591	0.05
192.2509308	0.05
193.1024628	0.06
197.1099854	0.08
199.9329529	0.03
200.8923340	0.05
206.0002136	0.28
207.0856323	0.28
209.0567017	0.08
211.1483459	0.05
219.1410675	0.14
225.1482544	0.11
227.1977539	0.12
228.6589661	0.06
233.1685181	0.30
237.1714478	0.14
242.1747284	0.03
243.1406250	0.23
245.2642212	0.20
247.1084900	0.04
254.1430054	0.04
255.3561401	0.02
258.0968628	0.10
259.0625305	0.11
263.2204285	0.05
265.1640930	0.04
266.9030457	0.03
269.2341614	0.14
270.0654297	0.07
271.2391663	0.20
272.1932373	0.05
273.1246033	0.02
275.1710510	0.06
285.0236206	0.17
287.2842102	0.22
288.2395020	0.07
289.2131348	0.58
291.0448303	0.04
297.0603333	0.10
299.2851868	0.38
301.1996765	0.08
308.8347778	0.06
311.4516602	0.12
312.2072144	0.05
313.2803955	0.17
316.1322327	100.00
317.1149902	66.97
318.1291809	0.63
318.8515930	0.07
325.2067261	2.57
327.1411133	0.68
329.2115173	4.15
331.2282104	0.06
335.3936157	0.11
339.2180481	0.05
341.2626038	0.52
345.1107483	0.08
346.3558350	0.11
347.2091675	0.35
353.1786499	0.22
359.2352905	2.30
359.9879761	0.02
361.2486572	0.13
369.1051636	0.08
371.2241821	0.12
383.3630066	0.02
389.2622986	0.34
390.2114258	0.07
401.1279907	0.11
419.2848816	0.03
434.4228821	0.05
435.4547424	0.22
461.2272644	2.80
462.1985474	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.13
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0897522	0.08
149.9878082	0.21
160.8594360	0.19
162.9134827	0.11
165.0269470	0.11
166.9856873	0.12
172.4067230	0.06
175.2083282	0.30
177.9624786	0.12
185.1484680	1.84
191.0228577	0.49
203.2068176	0.11
209.1772766	0.19
215.0571594	0.13
220.8532867	0.69
227.2357635	0.13
233.4487305	0.36
237.3111725	0.07
239.2285767	0.23
239.9220276	0.10
249.2608948	0.07
251.2247162	0.08
257.3609009	0.42
258.2838745	0.09
263.2586670	0.10
265.1307678	0.04
275.1900940	0.43
279.4864807	0.03
281.1831055	0.10
283.9255981	0.10
287.5195618	0.04
289.3059082	0.11
291.1652832	0.05
293.1917114	21.32
297.2848511	0.51
298.0545654	0.25
301.2296753	1.09
302.1667480	0.55
303.4176025	0.25
311.1394653	2.83
313.3681030	0.17
314.0733643	0.06
316.3743896	0.23
317.0894775	0.14
319.2256470	0.04
327.2106934	0.22
330.1041870	0.08
334.6917114	0.11
339.1950073	0.60
341.2648315	0.15
342.3756104	0.34
343.4146118	0.17
344.3922119	0.57
345.2411499	1.37
347.2110596	0.59
350.8823853	0.09
357.3056030	0.04
359.6171265	0.11
362.2976685	0.18
363.2359619	0.58
372.4302979	0.04
375.3303833	0.10
377.3878784	0.08
383.3424683	0.06
387.0650635	0.08
388.5156860	0.06
389.2495728	0.10
397.0108643	0.26
398.2812500	0.36
399.5198975	0.10
405.2484131	0.19
407.2243652	0.24
415.3296509	0.05
425.3881836	0.26
429.2180176	0.13
435.1605835	0.45
439.2750244	0.85
443.9313965	0.09
446.3491821	0.84
446.9509277	0.05
451.2257690	0.11
454.2509766	0.06
461.3087158	0.11
462.2663574	0.05
463.4552612	0.25
465.5607910	0.14
467.1818237	0.04
477.0709839	0.07
479.2556152	100.00
481.3101196	0.53
482.3475952	0.17
487.4353638	0.06
488.3937378	0.07
489.2952271	0.35
493.5444946	0.19
495.3593140	0.05
505.0872803	0.08
506.3060913	1.28
507.2393799	1.21
508.8197632	0.08
510.3510742	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1305
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0094757	0.25
159.5629272	0.03
161.1694794	0.05
163.0799408	0.03
163.9873657	0.16
165.0211182	2.48
166.1050720	0.02
167.0327148	0.25
174.0736084	0.08
181.0240479	0.07
188.3682556	0.04
189.9104614	0.03
191.1952820	0.07
192.1785736	0.07
193.1213837	5.74
197.1779175	0.03
205.0464630	0.11
206.9303131	0.06
212.8776703	0.04
214.1036377	0.03
216.1219482	0.61
219.0310059	0.09
220.4290466	0.06
223.2892609	0.03
226.1397400	0.02
229.2365723	0.55
231.1708527	5.28
233.1507416	0.09
235.2084351	0.07
240.1976013	0.09
242.0818787	0.12
245.3757477	0.08
254.2115936	0.09
255.2409973	0.11
257.3114929	0.06
258.1439209	0.04
259.4689331	0.10
261.3383179	0.05
269.6439819	0.08
271.4525757	0.36
273.2291260	3.36
275.1627197	0.08
282.7611389	0.04
284.0457458	4.40
285.2053223	0.25
286.1437988	0.06
289.2250366	0.77
293.3226929	0.16
297.3703613	0.03
299.1672974	51.72
300.1520996	0.05
301.1047363	0.26
303.2518311	0.03
311.0297852	0.07
312.8546143	0.11
315.2169189	1.00
317.1326904	100.00
318.2149658	0.05
323.0937500	0.10
327.3392334	0.26
329.1609497	0.10
331.9998169	0.07
333.1501465	0.08
337.5350952	0.06
339.3354492	0.03
341.3186035	0.36
344.2411499	0.18
345.3485718	0.15
347.2485352	0.17
353.0718994	0.27
355.2293701	0.27
359.2854614	3.99
360.7562866	0.06
367.0541382	0.05
368.0261841	0.05
371.2798462	8.54
375.1728516	0.03
379.2899170	0.05
383.3740845	0.07
387.2861328	0.03
389.0537109	0.09
391.3926392	0.02
394.6023560	0.03
397.2105713	60.35
411.2478027	0.10
435.1542358	0.15
445.5726318	0.05
461.1951904	0.33
467.2224121	0.10
475.1757202	0.24
477.2886353	0.31
479.3519897	0.27
485.6926270	0.06
491.2174683	0.04
494.9496460	0.02
503.1688232	3.40
503.8170166	0.25
504.4309692	0.06
507.3142700	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0614
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
105.1589050	0.04
109.1372528	0.10
110.8398361	0.12
121.0668411	0.49
122.9722214	0.13
133.9478607	0.05
135.0829620	0.03
136.9502869	3.69
150.0853271	0.02
153.1997681	0.12
156.0513306	0.06
157.0758972	0.06
163.0910950	0.50
164.9808350	100.00
175.0487823	0.06
179.1450500	0.12
181.0606995	0.05
183.0402527	0.05
185.1182556	0.06
190.1232605	0.49
191.0930176	3.24
191.9786682	0.06
193.0747681	0.26
194.9101868	0.05
205.1507111	0.08
207.0349426	0.04
208.0098572	0.02
208.9979401	0.32
213.2733459	0.02
222.9716797	0.03
233.1259766	0.06
239.3898621	0.02
241.9591370	0.02
254.9153442	0.05
257.1517944	0.17
259.1655884	0.16
269.1561279	0.21
270.2044678	0.06
271.3218384	0.21
273.3433533	0.09
275.8369141	0.04
277.2628174	0.72
280.9133301	0.03
282.3320618	0.12
283.2211914	0.06
286.0443115	0.74
287.1992188	0.09
289.2397766	0.06
294.2976685	0.03
297.3505249	0.25
298.4465942	0.27
299.1567383	0.84
300.2781067	0.30
301.2005005	2.96
302.4205933	0.11
303.4094238	0.03
309.2294312	0.19
312.1940308	0.31
313.2974243	0.27
315.1602783	1.45
317.1843262	0.35
325.0819397	0.10
326.2434692	0.17
327.2453613	0.84
328.0210571	0.02
330.1395264	63.69
331.2707825	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
106.2179565	0.04
111.0032196	0.04
112.9331512	0.47
118.8501282	0.19
121.0285034	0.74
125.1050339	0.17
137.9483185	0.45
138.9157410	0.05
140.1069946	0.29
143.1506348	0.13
150.1598511	0.12
153.0166016	3.60
154.1117554	0.22
155.1018982	1.06
161.2512054	0.13
165.1954193	0.13
166.1724091	0.27
167.1524658	0.18
167.8941956	0.13
178.9734497	0.34
180.0601654	0.53
181.8917847	2.58
192.1162415	0.09
193.2285461	0.03
195.1209717	1.20
197.0082703	98.98
207.5120087	0.18
211.1270752	17.06
219.3193970	0.18
220.2566833	0.12
223.1472168	0.54
224.1425171	1.05
232.8426208	0.14
234.2964478	0.06
239.1763306	100.00
242.3158569	0.05
249.3202209	0.26
251.1981201	0.50
263.1119995	0.26
263.8062134	0.04
265.2344666	0.63
267.1795349	0.07
269.1638184	11.05
271.1491394	0.62
274.7655640	0.09
280.1115112	0.15
281.0643005	0.58
284.1222229	0.14
284.9128418	0.43
293.2132568	0.68
296.0680237	0.06
299.1339722	30.08
313.2727661	0.13
315.2550964	0.31
316.3976440	0.19
317.0299072	0.07
323.5379028	0.14
327.2422180	0.05
329.2293396	0.09
331.2233276	0.08
340.6900635	0.11
341.3853455	0.13
343.1321411	0.35
344.2196350	4.41
359.0697021	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.1723
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
145.1713104	0.06
151.2659302	0.02
182.1036377	0.02
183.0120850	0.04
184.9582825	0.05
193.2406311	0.53
194.2291565	0.04
199.1963196	0.03
203.0640564	0.08
208.9329834	0.02
219.2955017	0.08
221.5075073	0.01
226.9290161	0.14
228.9057312	0.03
235.1259460	0.38
245.1536255	1.11
257.1922607	0.02
265.1602173	0.14
268.1159973	0.04
271.1235352	0.32
272.2134399	0.01
278.2268372	0.10
289.1290894	1.34
295.1172791	0.03
316.6894531	0.02
319.4521484	0.07
337.3582764	0.09
349.2319946	0.05
353.2698975	0.09
355.3029175	7.86
363.1320190	0.02
367.9800110	0.08
369.1005554	0.02
370.2931213	0.06
379.3413391	0.46
381.2264709	0.09
394.9600525	0.04
397.3101196	100.00
398.1726685	0.13
422.7760010	0.14
423.4218750	0.26
442.5374756	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1978
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.1589813	0.95
245.2217560	2.39
246.3034210	0.09
247.0680847	0.06
251.1351776	0.15
256.2586670	0.20
257.2594604	0.12
261.2394714	0.87
269.2046204	0.41
271.0110779	0.14
273.0920105	0.43
277.0982666	0.24
279.2106628	0.10
283.1788940	0.43
285.0721130	0.89
287.1700745	15.52
288.0870667	0.19
289.1500854	6.56
295.0724792	0.14
297.1564331	0.25
299.2136230	3.96
301.1343384	0.06
303.3609009	0.15
310.3168945	0.16
313.3673096	0.06
315.1907959	0.20
318.0444031	0.17
323.2441406	0.09
326.2416992	0.14
327.3075562	0.56
329.2441406	1.37
331.3419800	0.19
335.4909363	0.25
337.2253723	0.31
339.3055725	0.78
341.1782837	0.96
344.9744568	0.10
351.2180176	0.58
353.1000671	0.29
357.2109375	0.05
363.2265625	5.99
364.6915894	0.31
365.3093872	0.12
367.3415527	0.07
369.2748413	0.83
371.1687012	0.07
373.1496582	0.23
377.1706543	0.06
379.0966797	0.25
379.7067261	0.10
381.2890015	1.43
383.2602844	1.46
387.1347046	0.92
389.0847168	0.86
391.2594604	1.05
393.0922241	0.03
395.2328491	7.18
396.1351929	0.05
403.3406982	0.05
405.2364502	8.25
406.0350342	0.18
407.2503662	26.68
409.3324585	0.82
413.2481689	7.37
417.2276001	1.92
421.2218018	0.78
423.2543945	6.83
425.2107544	19.25
425.8834229	0.15
431.3182983	0.33
433.2407227	0.76
433.9344482	0.25
435.2170410	1.59
437.2797241	0.78
447.4514160	0.43
449.2332153	15.41
451.2825928	16.43
452.2246704	0.26
453.4000244	0.27
454.0635986	0.11
459.2182007	0.30
464.2310181	0.07
465.3019409	0.68
467.2757568	2.19
471.2651367	0.22
474.0628052	0.16
475.3814087	0.31
477.2445068	0.09
480.9668579	0.41
489.5747681	0.75
491.5811157	0.15
493.2431641	0.64
505.4999390	0.06
510.5205078	0.06
515.3739014	1.90
517.2663574	0.96
519.1964111	0.69
525.2887573	4.41
527.2832642	0.03
531.2440796	0.41
533.3797607	6.15
534.3588867	0.10
535.2073364	1.27
538.3065186	0.05
539.3390503	0.15
543.2556763	17.02
545.3380737	1.23
549.3911133	0.29
557.2974243	6.85
559.2835693	5.03
561.2267456	3.42
569.2846069	4.61
570.6424561	0.26
575.2292480	28.47
575.9226685	1.12
577.2598267	47.34
585.0755615	0.60
587.2576904	25.36
589.4257812	0.15
595.4089355	0.15
599.3615112	0.06
601.4209595	0.33
603.2936401	0.43
609.6007690	0.13
611.3245850	0.20
616.0174561	0.07
617.1217651	1.06
618.7841187	0.72
619.4314575	3.37
625.5399780	0.09
627.3581543	0.08
629.3371582	2.08
633.7593994	0.09
635.5668335	0.51
637.4978027	0.10
643.3854980	0.62
644.4129028	0.24
649.5515747	0.11
650.7695923	0.15
651.3862915	1.85
652.2040405	0.15
658.1547241	0.05
659.4181519	0.06
667.4235229	0.19
669.3648682	1.69
675.4020996	0.08
677.2733765	6.45
681.3117676	0.36
685.1597900	0.40
695.2302246	100.00
695.8800049	0.98
696.9075317	0.43
697.6623535	0.08
701.3983765	1.00
703.6455078	1.22
704.6270142	0.08
707.4955444	0.10
708.9298096	0.09
710.1888428	0.50
711.2003174	1.26
713.2001343	34.85
713.8674927	0.13
717.5689087	0.16
719.3224487	0.47
720.9609985	1.81
721.5852051	0.64
723.4664307	0.11
727.2766724	0.40
733.1916504	1.26
735.1647339	0.10
737.3442383	1.01
739.2515259	48.26
739.9179077	0.08
755.2698364	1.22
756.2194214	0.15
770.4206543	0.39
775.3779297	0.15
777.3426514	0.07
779.4274292	2.89
781.0217896	0.16
788.4367065	2.21
789.4132690	0.52
792.8920288	0.07
794.6308594	0.16
797.0360718	0.28
801.8218384	1.02
802.6338501	0.10
803.5610352	0.92
821.3701172	1.76
823.6881714	0.21
829.5159302	0.44
842.3115234	0.19
845.3358765	0.13
847.3222046	18.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2554
Annotation	Unknow
Peak:m/z	Relative Intensity
289.2988281	0.11
293.1215210	0.03
306.4021606	0.05
335.3322144	0.86
339.3378296	0.08
340.2949829	0.08
346.0398560	0.04
417.6549683	0.06
437.8158569	0.04
448.2569580	0.14
449.2946167	0.07
451.5189209	0.18
458.7911377	0.03
462.6795044	0.08
467.4190063	100.00
469.1568604	0.18
475.8494873	0.14
481.3211670	0.04
483.1850586	0.10
495.3606567	0.35
499.1256714	0.10
504.4661255	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1932
Annotation	Sambubiose
Peak:m/z	Relative Intensity
173.0003662	1.05
188.8934021	0.45
197.2234650	0.34
198.9575500	0.19
200.9947815	0.06
203.1211853	0.11
205.1782684	0.78
208.0770569	0.28
215.0237732	2.72
217.0915833	0.28
221.2550964	1.23
227.1835327	0.19
233.1652832	0.21
239.2171173	0.15
245.2063751	1.84
247.1415405	2.56
249.3050232	0.42
263.0066528	2.15
265.2136841	11.28
268.9799805	0.20
271.1776733	0.31
273.0744629	0.13
277.4985962	0.19
283.2055969	14.01
288.9669189	0.08
299.1140747	0.08
305.3057251	0.15
317.1637573	6.76
318.1596680	0.16
322.2044678	0.09
323.2847290	0.17
329.2611694	3.72
330.4954834	0.17
335.3099976	0.09
341.4464722	0.08
347.3787842	0.62
349.1980591	1.67
359.3328247	0.99
360.2382812	0.47
361.3111572	0.48
377.1810303	1.11
379.4281006	0.23
397.2293701	4.06
400.8817139	0.10
409.2755127	0.17
411.3102417	0.10
412.2061157	0.43
415.2495117	14.56
453.0031738	0.75
457.4449463	0.15
471.4024658	0.16
472.3554688	0.19
473.3608398	0.52
485.1852417	2.98
485.8425293	0.07
511.3716431	2.20
526.3024292	0.67
527.4067383	0.65
529.4218750	2.42
537.1949463	0.13
544.3551636	1.07
545.4979858	0.92
555.3250122	0.94
561.6072388	0.30
573.3703003	100.00
587.3025513	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1039
Annotation	Unknow
Peak:m/z	Relative Intensity
131.8522186	0.08
150.9950104	8.78
160.1162415	0.04
161.4149475	0.06
162.9733887	0.05
169.1134186	0.34
177.0463715	1.05
190.8491821	0.05
193.2658691	0.08
195.1479797	0.09
198.2426910	0.10
216.9145203	0.17
229.0647278	0.13
232.9852142	0.07
239.3722229	0.22
241.0011139	0.14
242.2039337	0.08
243.2858276	0.05
253.9783936	0.08
255.9919434	0.12
258.2472534	0.09
266.4675903	0.08
267.1360168	0.31
270.2037964	0.07
271.3413696	0.36
275.1914062	0.07
281.0633240	0.23
283.4819641	0.04
285.1736755	2.28
287.1386414	0.04
288.2264099	0.13
289.2490845	0.06
294.2566833	0.11
299.2760010	0.20
300.2916260	0.35
301.0614319	1.13
303.1190491	100.00
303.7602539	0.14
307.4899292	0.07
313.1774902	38.28
314.2265015	0.12
315.2633667	1.89
316.0729370	0.31
325.1834106	0.40
328.7958984	0.08
332.6080322	0.43
333.3245239	1.20
337.2797546	0.40
338.4440308	0.15
339.1459961	1.25
344.0928345	0.10
345.0834961	0.18
349.4407349	0.10
355.0548706	0.46
359.3782349	0.14
367.4554138	0.09
368.3699646	0.36
369.1889038	0.70
373.6353455	0.15
376.4985962	0.14
377.1067200	0.37
390.5260925	0.11
393.2971497	0.05
397.3859558	0.18
403.5418701	0.07
404.3937073	0.23
416.4436951	0.08
419.4179993	0.29
420.4259338	0.20
421.3779907	0.74
423.2089539	0.14
429.2919922	0.28
431.1276550	0.18
433.8348389	0.09
437.4018250	0.12
442.3968201	0.18
446.6106873	0.32
447.3062439	0.77
450.3196106	0.57
466.2269897	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
238.2532349	0.01
288.3856201	0.01
301.1243286	100.00
343.2222900	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.22
Annotation	S-Furanopetasitin
Peak:m/z	Relative Intensity
148.8520508	0.61
150.8974915	0.03
161.1358185	0.05
165.0800476	0.69
167.2496338	0.05
173.0926208	0.07
177.0440369	0.14
179.3220367	0.06
188.7274475	0.05
191.1616211	0.12
192.0659332	0.09
193.1567535	2.13
197.2336426	0.09
204.9427490	0.10
207.0840759	0.44
219.1832123	0.14
220.3220215	0.07
221.1585083	0.13
229.2862549	0.07
235.2925110	0.03
243.3311768	0.09
244.1250458	0.09
245.1592407	0.06
247.1971130	0.10
259.0041504	0.55
260.1574707	0.16
261.0506592	0.16
265.2226562	0.04
273.0236206	0.20
283.2431641	0.03
285.3732300	0.06
290.9317017	0.07
293.2729492	0.15
299.1217041	0.13
303.1538696	2.09
304.0967407	0.05
305.0166626	0.08
311.1853638	0.80
314.2020264	0.69
315.2274780	0.12
319.2498169	0.25
321.4107666	0.09
327.1331177	0.11
329.1640625	43.05
329.8757935	0.11
331.3063965	2.60
341.3318481	0.15
345.2599487	0.67
347.2174072	32.00
355.2398682	17.23
359.1812134	1.10
371.2590332	1.55
375.2733154	0.04
383.2523804	0.34
389.1660156	0.62
401.2829590	0.52
422.9976807	0.51
425.3308105	0.04
445.1536255	0.14
447.3005371	0.12
461.4049072	0.07
463.3681030	100.00
465.2790527	0.56
477.2427979	0.09
478.4295044	0.28
488.3366699	0.03
491.3265381	2.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.1797
Annotation	3,3,6-Trimethyl-5-heptene-1,2,4-triol
Peak:m/z	Relative Intensity
90.9696960	1.49
93.0014191	0.63
97.0491486	0.42
98.9298096	0.53
104.8714676	1.09
106.9509659	3.37
108.9933472	2.15
111.0039520	0.47
117.1127930	0.29
119.0201187	2.22
121.1307526	0.95
123.1362305	0.47
125.0503159	0.20
126.8100586	0.79
129.0767822	0.27
131.0067291	0.59
133.1109467	0.26
135.0246277	12.36
137.0664673	2.02
139.3043823	0.12
140.8633423	0.34
143.0506134	0.15
145.0681305	0.65
147.1263733	2.56
149.0399475	0.89
150.0340576	1.34
151.1065369	0.95
153.0607147	15.03
155.0667114	0.45
157.4519348	1.24
159.1574402	3.39
161.1123962	1.35
162.9727783	0.74
165.0352478	50.83
167.0693817	1.46
169.0492554	2.69
173.0809631	2.45
175.1163635	1.92
176.1042328	0.30
177.1397095	1.96
178.9702454	2.70
180.9646301	3.17
183.1040649	1.63
185.0873413	1.62
187.2542572	0.47
189.1196289	2.55
190.8081970	0.18
191.9947815	0.21
193.1471100	3.55
195.1432495	3.14
197.1973419	1.06
199.3478394	0.17
201.0637207	2.94
201.8959198	0.11
203.0754852	2.70
205.1752930	0.58
207.0963440	2.95
209.1985779	0.49
211.1831970	1.29
213.0387573	4.08
215.2108765	4.33
217.1451721	0.88
219.1116943	6.47
221.1951599	1.28
223.3012085	0.38
225.0352173	3.90
229.2079163	1.30
230.0612488	0.16
231.1718140	8.77
232.1009827	0.20
233.1843567	2.47
235.0774231	1.07
236.1864014	0.10
237.1452026	4.27
239.3462524	1.03
243.0780640	12.69
248.5986328	0.85
249.2017822	5.37
253.2048035	0.63
255.0346985	0.47
256.1998291	0.14
257.0599976	2.13
258.0827637	2.34
259.0753174	1.53
260.1948547	0.47
261.1982117	26.28
266.0602417	0.27
267.1481628	0.49
268.1898499	0.47
269.3272705	0.78
270.0061951	0.76
271.1862793	0.25
273.2218323	3.31
279.2093506	56.14
282.9946289	0.74
285.1464844	4.72
286.1607361	2.27
287.2544556	10.96
288.0994263	3.42
297.1940918	100.00
298.0785217	0.89
309.3547363	1.04
313.1853638	17.66
314.1822510	2.92
315.1428528	13.77
316.2376404	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	338.0865
Annotation	2,8-Dihydroxyquinoline-beta-D-glucuronide
Peak:m/z	Relative Intensity
96.9248123	0.11
111.9094772	0.05
114.9927673	0.33
116.0585709	0.08
118.1586456	0.08
129.1592407	0.24
136.9877472	1.03
143.9206390	0.09
144.9226532	0.46
154.9633179	7.34
163.0939636	0.16
163.9729462	0.78
167.0079803	45.91
169.9079590	0.07
173.1148071	0.58
174.1387634	0.10
175.2551727	0.31
187.0682068	0.13
191.4926910	0.19
202.9091797	0.41
217.0227356	0.25
222.1487427	0.16
224.1480103	0.22
233.4954834	0.06
239.1398315	0.24
241.2683411	0.08
242.0669861	0.16
243.4199524	0.11
249.1034851	0.05
250.1128845	0.62
257.1232300	0.34
263.4534302	0.12
265.2275391	0.27
268.0383301	0.13
270.5889893	0.24
272.2402649	0.16
273.3556213	0.12
274.1564026	0.24
275.1284180	0.06
279.1405945	0.09
280.1473694	0.16
285.3046570	0.28
289.3022461	0.17
290.2802124	0.09
291.3308411	0.29
292.0291138	0.32
293.1821594	0.11
297.3066711	0.05
300.0054932	0.15
301.1100464	0.93
302.2155762	1.39
303.1096802	0.48
304.0538025	0.19
305.3092041	0.14
306.1729431	0.12
307.5200500	0.14
309.2725525	0.46
315.0649414	0.14
316.4093018	0.16
319.1416626	3.92
320.0564880	8.93
320.8106079	100.00
323.2234802	0.18
324.5783081	0.41
329.2237854	0.11
331.3642578	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2183
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
148.9017029	0.02
167.1322479	0.30
168.1434021	0.07
176.0093994	0.02
178.9581451	0.01
191.3435059	0.02
192.1360779	0.02
194.1854858	0.01
195.2633972	0.02
209.1868286	0.14
210.1163635	0.03
216.4170837	0.01
217.9061279	0.01
241.1225891	0.01
249.2605591	0.02
257.4586182	0.02
291.2409668	0.01
295.2957764	0.02
299.4546509	0.02
302.1665649	0.07
313.2390137	100.00
314.2346191	21.91
315.1286011	0.12
319.1354370	0.01
322.2401733	0.03
327.2708130	0.02
341.5186157	0.01
344.3489380	0.03
347.3148193	0.01
350.9140625	0.02
355.2553711	0.02
361.5368042	0.24
362.5547485	0.02
365.3024902	0.01
370.2227173	0.01
371.1067505	0.01
372.2710571	0.01
398.0324707	0.01
399.1004639	0.01
405.5820923	0.02
443.3054199	0.01
444.3550415	0.02
453.5612793	0.01
462.3194580	0.01
474.3744507	0.01
475.5061646	0.03
476.8889771	0.04
477.4966431	0.12
479.8396606	0.01
481.1934204	0.02
492.2404785	0.02
493.6845703	0.02
496.4140015	0.04
504.1641235	0.01
505.3851318	0.09
506.1334229	0.06
507.4096680	0.02
509.4479370	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0884
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
163.1315460	0.04
191.3807068	0.02
193.0239716	0.06
201.0932922	0.02
203.1462402	0.12
207.8767700	0.03
233.2673950	0.02
237.2698517	0.08
239.2121277	0.03
240.2094116	0.21
248.0758667	0.09
249.1830444	0.07
255.3003845	0.03
265.0929871	0.08
267.2365112	0.04
267.9468994	0.05
268.8221436	0.05
275.1749268	0.06
284.0673828	0.08
294.9837036	0.16
307.1557617	0.19
308.2767944	0.08
309.3109741	0.03
311.0354004	0.31
312.2545166	0.07
315.3740845	0.09
317.5100098	0.03
323.0079956	0.03
325.0850220	0.02
329.2797241	0.08
330.3952026	0.02
339.1948242	0.21
341.4824219	0.08
342.3649902	0.07
343.3602295	0.19
344.1724243	0.34
345.2762451	0.07
346.2458496	0.06
354.2203369	0.02
355.0868530	0.06
357.3688354	0.05
358.8165283	0.07
368.3138428	0.05
369.2734375	0.23
381.1638794	0.06
385.3225098	0.10
386.4341431	0.13
387.2965088	0.51
395.2142334	0.05
397.1828003	0.08
398.1937256	0.12
399.1657715	0.23
401.2694702	0.54
402.3534546	0.52
403.1516113	0.10
410.5950317	0.05
417.2267456	0.12
428.1404419	0.10
429.4954834	0.03
431.3960571	0.03
433.2800293	0.03
434.9327393	0.03
445.2042847	0.29
447.1597290	0.12
451.2871094	0.40
453.1427612	1.24
454.3061523	0.31
459.0947876	0.05
461.3148804	0.19
462.1495972	0.09
463.3615723	0.33
468.3706055	0.07
469.0319214	0.04
469.9053345	0.12
473.5108643	0.24
474.5384521	0.03
477.4740601	0.03
485.3271484	0.07
486.0349731	0.12
487.7827759	0.38
488.4694214	1.06
489.4461060	0.63
490.2322998	0.05
502.2413940	0.41
503.2809448	2.43
505.2323608	100.00
506.1847534	0.01
507.2305298	0.04
512.4162598	0.03
513.3330078	0.20
516.1616821	0.03
521.1676636	0.08
526.2540283	0.07
529.1544189	0.06
530.3419189	1.48
531.3759155	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
135.0615997	7.47
137.0284424	0.09
161.2257690	0.05
165.0388031	0.07
178.9887085	100.00
179.7811890	0.02
206.9211884	0.04
217.0882568	0.10
219.0811157	0.04
220.9311523	0.15
232.9398499	0.03
251.1199036	0.37
267.1849365	0.02
281.2692566	0.31
295.1893005	0.23
297.2488403	0.10
305.2373047	0.05
311.2998657	0.04
326.2870483	0.03
327.0685730	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1827
Annotation	Scopolin
Peak:m/z	Relative Intensity
341.2504883	0.03
351.5294189	0.02
353.1870728	100.00
354.3344727	0.06
475.2526245	0.01
491.3338623	0.03
515.2321167	0.35
516.4088745	0.02
533.1373291	0.03
544.7990112	0.08
679.5769653	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1559
Annotation	Isoscoparin 2''-O-ferulate
Peak:m/z	Relative Intensity
182.0365753	0.02
183.1822052	0.03
187.2095490	0.02
187.9368896	0.04
189.0309601	0.03
191.0682678	0.02
199.0101013	0.15
201.0440826	0.06
205.0092773	0.06
206.0205688	0.02
207.0871277	0.11
210.2077942	0.04
211.1792450	0.08
212.2236176	0.04
213.2144775	0.02
215.1143341	0.04
218.9518433	0.07
221.2655182	0.06
221.8816528	0.03
223.1173401	0.02
225.0851746	0.02
225.9909668	0.17
227.0991364	0.65
229.1690979	0.11
235.3388062	0.06
237.1633606	0.03
239.0847778	1.21
240.0467834	0.09
241.0919952	0.11
242.1861572	0.13
243.0039062	0.18
244.0806427	0.11
245.4138184	0.02
247.0132751	0.03
251.2005920	0.08
253.1968689	0.37
254.0121002	0.11
255.0768280	3.33
256.2662964	0.03
257.0397949	0.34
257.9727478	0.06
259.1870728	0.05
261.0681152	0.05
268.2400513	0.02
269.2167664	0.54
270.0655518	3.34
271.0790405	1.40
272.0877991	0.21
273.0552979	0.07
275.1469727	0.08
281.3164978	0.09
282.0203857	0.24
283.1666260	0.29
284.5787659	0.28
285.2384644	2.46
286.1620483	0.69
287.1060791	0.52
289.2399902	0.15
293.2232056	0.08
295.0506592	0.07
296.3013306	0.04
298.0350952	1.92
299.1712036	4.26
301.0175781	0.08
302.7200317	0.04
305.1724854	0.21
307.2883301	0.58
308.4822998	0.04
310.7755737	0.08
311.4558105	0.18
313.0785522	4.15
314.2190552	8.98
315.2342529	0.06
324.1960754	0.02
325.2180176	0.14
326.0781250	0.05
327.1227112	0.31
329.1033936	100.00
329.9396667	0.36
331.0596313	0.24
333.2739868	0.04
337.2003174	0.08
341.3602295	0.08
343.2419434	1.61
347.2855835	0.06
350.1654663	0.13
353.4467163	0.07
355.1062012	0.07
356.2394409	0.15
369.2371216	0.10
371.2321167	0.54
379.1417236	0.10
381.4209595	0.02
382.6400146	0.10
383.2467651	0.14
395.0678101	0.15
400.8267212	0.11
401.5640869	0.02
404.9710083	0.03
406.8304443	0.09
413.4076538	0.03
415.2252197	0.16
425.0518188	0.04
428.4290161	0.02
429.2851562	0.04
432.3087769	0.04
433.3636475	0.02
435.4339600	0.08
436.1174316	0.06
437.9349365	0.12
441.2998047	0.20
447.3749390	0.08
455.5747681	0.03
456.4652710	0.04
457.1802979	0.03
463.3052368	0.26
467.2968750	0.02
469.3095703	0.02
470.0303345	0.03
471.4926147	0.11
473.2312012	0.20
474.2441406	0.31
475.2687378	0.78
476.4479370	0.03
479.4873657	0.02
481.9597168	0.10
485.2324829	0.12
486.3837891	0.01
487.1651611	0.05
489.1977539	0.11
491.2936401	2.04
492.4746704	0.15
493.2467041	0.23
499.3628540	0.12
500.3432007	0.08
510.3295898	0.09
511.2879639	0.28
515.4783325	0.05
519.2091064	0.05
529.5976562	0.02
531.2553711	0.05
533.3972168	0.02
536.5084229	0.04
542.3521118	0.04
544.5549316	0.05
546.2165527	0.02
547.2828369	0.06
549.4015503	0.02
551.2800903	0.09
555.0776978	0.04
556.6628418	0.04
559.3549194	0.11
560.2828369	0.06
565.2586670	0.19
569.2765503	0.30
572.1600342	0.05
573.4091187	0.11
575.2448120	0.04
576.2417603	0.11
577.3312378	0.07
578.5166626	0.12
586.1659546	0.10
589.8527832	0.12
590.4570923	0.48
591.3272095	0.74
592.4708862	0.07
593.2857056	0.21
598.2891235	0.02
600.2642822	0.49
601.2911987	0.15
604.0375977	0.05
605.2950439	0.12
606.4761963	0.02
609.3483276	0.12
618.2266235	0.30
619.3481445	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.1093
Annotation	Castamollissin
Peak:m/z	Relative Intensity
146.9858246	0.05
148.9543152	0.13
158.0320129	0.09
166.8805847	0.44
173.0483551	0.07
175.0593414	12.51
185.0067902	0.10
186.0201263	0.06
187.2136536	0.04
191.1464233	0.06
192.5286713	0.21
193.1700439	0.21
199.1712189	0.07
201.0331726	0.05
205.1385498	0.03
207.1891785	0.06
211.3032684	0.06
213.0140533	0.64
213.8441162	0.07
215.1356964	1.45
217.1053925	0.06
228.2864838	0.11
229.2073669	0.11
230.8143158	0.10
233.2210999	0.48
235.3408508	0.04
239.1478882	1.65
242.1881714	0.06
243.2810669	0.05
244.9359589	0.06
257.0935059	10.40
258.4512329	0.53
259.1738892	1.56
269.3826904	0.02
273.1185303	0.73
275.1295166	0.21
283.0900879	2.71
291.4202271	0.03
301.1286011	100.00
313.0543213	0.04
315.1651611	0.04
317.2595215	0.04
319.1209106	1.49
328.2305908	0.02
332.3903809	0.03
343.2816162	0.61
360.1911011	0.73
361.2594604	0.26
371.1910400	6.74
385.0527954	0.03
397.2768555	34.52
403.2360229	0.12
432.2365112	0.11
443.3936157	0.07
455.2402954	0.65
477.4204102	0.16
479.1327515	1.83
481.2752075	0.21
487.5900269	0.07
495.5752563	0.04
505.3359375	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.015
Annotation	Unknow
Peak:m/z	Relative Intensity
146.1262054	0.11
161.4248047	0.01
165.0663300	0.03
170.8426819	0.02
175.0698853	0.03
189.0303345	0.01
200.5338135	0.04
203.1856079	0.02
205.0700226	0.08
209.0953064	0.01
210.8585358	0.03
219.1319427	0.32
220.8863983	0.05
223.9411774	100.00
224.7633209	0.02
235.1345673	0.03
236.8414459	0.03
241.7378387	22.81
242.3761597	0.21
243.8307037	0.11
247.1030273	0.03
253.4422760	0.05
265.0487061	0.01
276.1011963	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0652
Annotation	5-Hydroxy-6-methoxy-3',4'-methylenedioxyfurano[2'',3'':7,8]flavanone
Peak:m/z	Relative Intensity
110.9726028	3.98
115.0177612	0.08
134.0417786	0.03
135.1789551	0.04
158.2598267	0.18
161.1062622	0.76
169.3616638	0.04
172.9814148	2.93
176.8136139	0.09
179.0217590	0.23
184.2290955	0.10
184.9330750	0.14
191.0373688	9.24
193.0912933	1.98
204.8159485	0.29
207.1936798	0.27
213.2500305	0.09
215.1510925	0.10
217.1394043	0.69
218.0955200	0.11
221.0077820	0.16
222.1610107	0.25
225.4952087	0.20
231.3588562	0.12
233.1958618	0.39
234.1683655	0.04
237.3928528	0.19
239.4906311	0.16
241.0824585	0.03
244.1308594	0.04
246.3363037	0.04
249.1627502	1.56
250.1824341	1.08
251.0413208	0.11
253.0625305	0.72
254.7563171	0.17
257.3078003	0.05
259.2697449	0.52
262.1113892	0.11
263.3909912	0.05
264.6365967	0.06
265.3819580	1.15
266.3398743	0.39
267.3053589	0.05
269.3369751	0.03
270.0385437	0.06
275.0083923	0.08
276.0888672	0.22
277.1578674	2.49
278.2307739	0.36
279.3497314	0.26
280.1138306	2.03
281.2285767	10.02
282.4758911	0.05
283.6010742	0.06
287.2118530	0.03
291.2905579	0.75
292.5103149	0.89
293.1862488	5.30
294.1300659	17.07
295.1456604	0.79
297.2453613	0.80
299.3647461	0.19
303.2461243	0.14
304.2899780	0.06
305.5003662	0.19
306.5458679	0.44
307.2432251	1.00
309.1986084	100.00
310.2213745	2.42
311.2467651	0.54
317.4482422	0.37
318.3608704	0.06
319.0954590	0.06
321.1996460	4.96
322.1437378	0.06
323.0773315	0.03
325.2451477	16.60
326.2758179	0.44
335.3098145	5.95
337.5135803	1.65
338.1217041	7.25
339.2144165	0.20
347.2571106	0.03
353.3027039	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2783
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
152.8846130	0.16
214.0321960	0.88
221.8880157	0.10
230.9076385	0.14
279.2873230	100.00
279.9270020	0.19
293.2085571	0.11
299.3622131	0.05
314.2319641	0.07
315.1520996	0.30
344.1641846	0.32
351.0434570	0.12
352.4750977	0.07
371.2812195	0.22
388.3440247	0.07
399.2535095	0.19
404.2936401	0.23
413.5130310	0.08
421.4632263	0.07
429.1233826	0.25
430.6114502	0.10
432.4163513	0.11
447.5986023	0.29
448.6830139	0.05
457.9486084	0.29
462.1984558	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.91
Annotation	3,3-Dibromo-2-n-butylacrylic acid
Peak:m/z	Relative Intensity
97.9300537	0.27
103.0059204	0.12
109.2549744	0.13
111.0912323	0.16
122.9356461	0.08
129.9938660	0.40
135.1215210	0.20
136.1589661	0.08
143.1895142	0.19
147.2671204	0.28
149.3183594	0.06
152.3792725	0.21
154.9537659	0.07
172.2451172	0.26
177.1521454	0.15
179.1605835	0.37
186.9894714	0.10
192.2005615	0.21
200.3461304	0.29
210.8025818	0.11
213.2572937	0.40
225.1172485	0.59
227.0678101	0.20
231.2939453	0.74
238.8865662	0.35
240.9323120	0.63
241.9853516	0.27
243.9285278	100.00
244.7405396	0.37
246.9480896	0.04
248.4490967	0.45
254.8276978	0.48
256.3205872	0.82
256.9980774	0.51
257.7808838	0.25
260.9821472	0.75
261.6475830	5.78
262.6456299	0.66
263.9974365	3.03
265.1408997	0.66
266.2529907	0.91
266.9400635	3.03
269.1728516	0.09
270.5119019	2.09
271.3603516	0.56
272.3767700	0.40
273.1612854	1.95
274.0777588	0.06
275.1249390	0.20
275.8244934	1.34
276.4748840	0.48
279.4757385	1.35
281.8729858	0.44
284.9036865	0.61
288.0573730	0.13
293.5836792	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1173
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
117.0006561	0.49
127.1290741	0.12
137.0584106	0.09
139.1560059	0.17
145.0112610	3.36
162.7621765	0.21
164.9936829	0.07
167.0557404	0.12
173.3828278	0.07
177.0624390	100.00
190.1379547	0.07
191.2735443	0.07
194.1369171	0.11
195.1205139	0.22
197.0479431	0.11
200.1874695	0.13
204.8498993	0.11
206.9591675	1.48
215.1690216	0.10
216.0961914	0.10
225.0585938	0.10
227.1349792	0.09
237.2124939	0.12
238.6724243	0.11
253.3908997	0.12
261.1929626	0.08
271.2322693	0.17
274.3087463	0.14
278.3804932	0.09
279.6908569	0.70
283.3568726	0.09
284.8040771	0.08
289.2140198	0.11
307.0856934	0.12
323.4619446	0.16
327.1406860	0.59
328.0820312	0.19
333.2767944	0.25
338.8896790	0.07
340.2297974	0.08
341.2694092	0.41
342.0930786	0.14
350.5452271	0.61
351.3235168	1.28
353.7511292	0.75
355.3900452	0.15
360.1265869	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1141
Annotation	Unknow
Peak:m/z	Relative Intensity
148.0024414	0.06
151.0485840	1.67
152.3529816	0.21
153.1366272	0.13
157.9259796	0.02
162.1676636	0.10
163.0386047	0.17
165.1765442	0.35
169.1279907	0.23
176.0688629	0.05
177.1080322	0.09
178.9422760	1.03
180.0224304	0.06
181.1096344	0.10
189.3533020	0.02
191.0367279	0.12
192.0498657	0.32
193.0127563	0.21
203.0961609	0.02
204.2460022	0.05
205.1202393	0.13
206.1190491	0.06
207.0836182	0.11
207.9891205	0.19
210.0866089	0.06
216.1831360	0.10
216.8894501	0.07
219.0468292	1.00
220.0150146	0.29
221.1869812	0.06
230.0028381	0.04
231.1605988	0.24
232.1529236	0.08
234.0849915	1.35
235.1147156	0.42
236.3720398	0.08
237.1338959	0.05
241.2279510	0.22
241.9812012	0.08
243.3192139	0.11
245.2247467	0.13
246.2246399	0.09
246.8858795	0.03
249.2585754	0.20
249.8674622	0.02
251.1541443	0.07
253.5402832	0.03
256.1795654	0.08
257.9682922	0.28
259.1094360	0.04
261.2113647	0.21
263.2258911	0.07
264.2359924	0.07
265.1036682	0.16
269.0662537	0.23
270.0171814	0.27
271.2640381	0.13
273.0542297	1.69
274.2300110	0.26
275.2100830	0.37
276.1561584	0.22
277.1440125	0.35
278.9064941	0.08
281.7987976	0.27
284.0171509	0.09
285.2377625	0.50
286.2517090	0.11
287.2405396	0.62
288.2447205	0.06
289.3030090	0.05
290.3339233	0.11
291.3185425	0.20
293.0165100	0.04
295.0783997	0.04
297.0672607	0.13
299.1950073	0.19
301.1437683	3.50
302.2217712	1.21
303.1082764	1.18
304.0659790	0.35
305.2177734	0.35
310.2683105	0.08
311.1700745	0.06
313.2874756	0.24
314.5374146	0.22
315.2466431	2.42
316.1570435	3.82
317.2373352	1.72
318.1386108	0.28
319.4611511	0.24
321.2136230	0.03
323.4017639	0.03
325.1806641	0.33
326.1470642	0.20
327.3388062	0.33
328.2243652	0.85
329.2372131	7.35
330.2104492	5.46
331.2212524	1.12
332.2369995	0.13
333.0184937	0.28
334.2775269	0.04
337.2464600	0.08
339.1875610	0.06
340.2584229	0.12
341.1729126	0.31
342.5974731	0.18
344.1672668	100.00
345.1529541	98.23
346.2294312	13.78
347.3956604	0.14
352.1997070	0.09
353.1686401	0.02
355.2374268	0.19
356.1746521	0.29
357.2429199	0.36
358.6037598	0.47
359.3183289	3.06
360.3833008	0.42
361.4567261	0.08
367.2438354	0.07
369.1520996	0.17
371.1847839	0.30
372.1997681	0.64
373.4736328	0.28
374.2384644	0.20
375.2763672	0.09
383.3461609	0.14
384.7507629	0.07
385.5641479	0.08
387.1900330	20.02
388.2033386	3.50
389.1731567	0.23
391.2715759	0.08
396.4343872	0.07
398.7164001	0.04
399.3990173	0.36
402.1094666	0.07
410.4944153	0.22
411.1034851	0.09
415.4689636	0.15
417.2074585	2.61
418.3695068	0.85
419.6741943	0.05
420.3428040	0.04
427.2545471	0.04
429.1877136	0.41
439.6710510	0.29
441.4277039	0.06
447.3908081	0.11
448.1454773	0.36
448.8669128	0.07
449.6047058	0.05
459.3896790	0.03
461.5154114	0.15
463.0537415	0.16
464.2993469	0.27
465.2604065	0.05
475.1982727	0.79
476.3153992	0.10
479.3246460	7.14
480.3551636	1.49
481.1804810	0.02
488.8818054	0.25
489.5607300	0.11
492.2015686	0.60
493.3480530	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3047
Annotation	Sphinganine
Peak:m/z	Relative Intensity
94.9839325	0.43
96.96862793	0.42
109.0275421	0.46
111.0433502	0.18
120.0860901	0.03
123.040657	0.40
125.1152573	0.06
130.8234558	0.02
137	0.25
140.167572	0.03
140.8858948	0.01
145.0967102	0.04
149.1486816	0.02
151.094635	0.12
152.9042664	0.03
155.2150879	0.02
164.9964294	0.15
165.9413452	0.03
169.175354	0.02
172.8152771	0.02
179.204071	0.05
183.165802	0.09
184.225708	0.04
185.875061	0.02
187.151535	0.09
187.8175964	0.01
189.2118073	0.03
190.9351959	0.02
200.1035461	0.05
202.1752319	0.05
202.9845886	0.02
204.313385	0.02
204.9856567	0.01
207.2121582	0.08
212.0038757	0.16
213.176239	0.13
215.2215271	0.01
216.2342224	0.03
218.3943176	0.03
220.1769104	0.03
226.4404602	0.03
227.1085815	0.07
228.9268188	0.14
230.4829712	0.02
235.2234192	0.09
239.4779053	0.05
240.4120789	0.49
242.1513062	0.04
242.9918213	0.08
244.8655396	0.02
247.2373657	0.09
249.1603088	0.23
253.0528564	0.05
254.3046875	0.17
255.2702637	0.02
256.1497803	0.06
257.1646118	0.74
258.4740906	0.06
260.4927063	0.13
261.1008301	0.03
266.4009399	4.51
267.3550415	0.40
268.402832	0.02
270.9133301	0.20
272.109375	0.02
272.9163818	0.01
274.234314	0.19
275.2301636	0.21
278.8997498	0.08
281.2727051	0.07
284.2907715	100.00
285.2362061	0.48
287.1838989	0.21
288.1895447	0.01
292.7589417	0.05
293.5717163	0.06
300.016449	0.03
301.7391968	0.10
303.2952271	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.0963
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
139.1795044	0.15
141.1214600	0.09
143.9712372	0.09
155.0305939	0.07
166.1332855	0.13
166.9018707	0.07
179.0929718	0.10
191.2131042	0.12
195.0894012	0.54
205.0890198	0.61
207.2430420	0.09
208.9318237	0.23
216.0953064	0.15
217.1819458	0.26
218.9514771	0.50
221.1440430	0.05
233.4118500	0.31
245.2055206	0.40
246.6750488	0.06
248.0854492	0.05
249.0448608	0.32
251.2669067	0.13
256.8098450	0.19
259.3081055	0.14
261.2537842	0.64
265.2319336	0.19
267.0785522	0.05
269.3197937	0.16
275.1646423	0.30
277.2615356	4.88
277.8834534	0.06
279.0891724	0.25
284.1174622	3.06
285.1988831	2.27
287.1522827	13.40
288.3278198	1.45
289.2286987	0.29
293.5269775	0.26
295.1146851	3.59
301.2113037	2.19
302.1935425	0.73
304.0778198	0.10
305.2098389	1.33
307.2949524	0.62
309.3295288	0.18
313.1010742	3.80
315.7629700	0.07
318.1903992	1.11
319.2776794	100.00
325.1433716	4.70
327.3485107	0.36
329.2973633	0.19
332.9993286	0.06
335.1205139	0.17
337.1270142	1.23
343.0584106	0.07
345.2844849	0.19
350.5675659	0.06
355.2406616	0.17
361.4343262	0.06
377.4066772	0.92
378.4973145	0.11
381.2509460	0.03
383.3749695	0.22
384.7064209	0.17
395.2059631	0.50
396.0285645	0.38
397.2792053	0.41
399.3092957	0.54
400.9702454	0.07
402.2938538	0.21
407.5768738	0.18
409.2960205	0.05
417.1029358	1.09
419.3236084	0.41
426.7968445	1.04
427.4076233	0.84
433.5331421	0.07
435.0356445	0.65
439.5242004	0.28
445.2233276	9.44
448.3763428	0.10
453.4898987	0.16
463.1492310	29.41
463.9748230	0.42
472.0444031	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1193
Annotation	Castamollissin
Peak:m/z	Relative Intensity
145.0321350	0.07
146.8615112	0.13
149.0629578	0.11
152.0096893	0.11
159.0485840	0.11
164.1646118	0.23
173.0398865	0.03
179.1991425	0.09
181.3134613	0.07
188.8673553	0.42
191.1598206	0.10
197.3159485	0.09
205.2793579	0.03
217.2559814	0.11
227.0374756	0.15
230.3898468	0.03
233.2232056	0.10
237.1922760	0.02
241.0441284	0.16
242.2023926	0.10
243.0413055	0.04
245.1456451	0.19
248.5320435	0.15
249.5080566	0.11
251.2078552	0.12
255.1718140	0.18
257.2975159	0.15
262.2763672	0.03
267.2071228	0.38
268.3057556	0.36
269.2191772	0.04
270.0340881	0.65
272.3563843	0.25
273.2129517	0.06
275.2744446	0.13
277.3058472	0.06
278.2923584	0.03
281.1264343	0.24
283.1824341	0.06
284.1691284	0.29
285.1618652	2.16
286.2100220	0.82
287.2641296	0.57
288.0486450	0.19
289.2915955	0.23
292.9749756	0.75
297.2499390	0.29
298.2702637	0.11
299.2622681	0.84
300.4208984	0.38
301.2827759	0.21
303.1743164	0.16
309.1029053	0.14
310.4503174	0.15
311.2025757	0.23
312.2642822	0.17
313.2157593	0.60
314.2463684	0.90
315.5323486	0.20
316.4179077	0.26
317.1300049	0.04
325.0867920	0.40
327.1327820	3.35
328.1779175	21.92
329.1829834	100.00
330.3165283	1.13
331.1992188	5.55
333.2188110	0.06
338.3754272	0.04
339.2667236	0.39
340.0097656	0.04
341.0654297	0.64
343.3026428	4.69
345.1882324	0.11
347.1069031	0.31
350.1607056	0.04
353.2105408	0.69
354.7898560	0.04
356.0322876	0.04
357.3321838	0.40
364.5874939	0.06
365.2353210	0.04
369.5303345	0.04
371.2082520	3.73
372.6337585	0.05
373.4121094	0.21
381.2399292	0.15
383.3496399	1.40
393.4739990	0.11
395.2216492	0.37
401.2569275	1.99
403.3058167	0.06
413.3061523	0.54
418.2399292	0.16
421.2642517	0.05
422.1411743	0.05
425.3105164	0.07
430.1354675	0.18
431.3505249	0.42
432.4273987	0.08
437.4906311	0.04
444.2040100	0.23
445.3108215	0.34
446.5613708	0.30
447.3118591	0.06
448.9832153	0.07
455.3382874	0.79
459.1702576	0.45
460.3460999	0.02
463.3052979	0.42
473.3288879	0.89
476.4868469	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2819
Annotation	Unknow
Peak:m/z	Relative Intensity
191.3361664	0.06
192.3524628	0.11
196.9565125	0.03
254.9831696	0.08
256.9651489	0.17
259.1665649	0.25
266.0953674	0.05
281.1741943	0.15
293.1386414	0.15
300.7320251	0.12
307.1631470	0.05
313.3873596	1.43
314.2933350	0.29
317.0934448	0.04
322.9564209	0.07
325.3909607	0.13
329.1694946	0.73
337.1149902	0.10
343.3961792	0.15
346.1647339	0.16
347.1500854	0.04
355.4448242	0.12
361.5507812	0.21
389.2299194	0.07
393.3869629	0.23
395.4489746	0.03
396.4432373	0.06
399.4019775	0.08
433.3390503	0.13
437.0343628	0.05
439.1279297	0.20
443.4745483	0.14
452.8095703	0.07
463.2139893	0.62
465.2590942	0.22
469.4213867	0.26
473.3271484	0.14
475.3426514	9.65
479.4127808	0.10
481.4346924	0.10
484.5456543	0.21
488.2448120	0.08
489.3645630	0.25
491.0637207	0.12
492.9738770	0.24
493.7572021	0.06
497.2564087	0.10
501.4044189	0.12
505.3416138	0.24
507.4984131	0.09
509.2300415	0.46
523.3836060	0.18
526.7250366	0.07
528.1579590	0.05
531.4306030	0.29
532.4486694	1.96
533.2481079	0.79
535.4107056	0.05
538.7561646	0.12
540.5600586	0.11
545.5250244	0.05
548.1226196	0.08
550.4414062	0.21
558.6263428	0.13
559.4237061	0.12
565.4141235	0.07
570.4024048	0.35
574.1501465	0.17
579.3109131	0.09
582.5081177	0.05
593.5396729	0.38
594.5858154	0.23
601.4103394	0.16
606.6859741	0.06
609.3715210	100.00
610.4439087	0.30
611.4717407	0.41
612.2793579	0.06
613.3421021	0.16
614.5394897	0.08
621.7266846	0.05
622.5277710	0.33
625.1044922	0.27
631.5223999	0.23
632.5338745	0.44
633.7743530	0.20
635.6802368	0.15
636.6658325	0.58
637.3681641	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1038
Annotation	Unknow
Peak:m/z	Relative Intensity
142.7248230	0.02
148.9092407	0.13
154.8879395	0.05
161.0353699	0.13
162.9689636	0.03
174.9862976	0.13
175.8671570	0.03
177.2968597	0.09
179.0855408	0.06
185.2293396	0.05
197.0503540	0.18
198.1412354	0.03
199.1397400	1.17
201.1728058	0.09
213.2002563	0.27
214.9399719	0.07
217.2049561	0.37
218.7404480	0.02
221.0560608	0.02
223.1193085	0.04
224.0379944	0.04
226.1667480	0.20
239.1531372	0.03
241.1041565	12.78
242.1919861	0.12
243.0683136	0.52
245.3049011	0.08
247.0162659	0.06
257.1060181	0.13
258.3222351	0.05
259.3653564	0.04
267.1307373	0.57
271.0747681	0.08
283.0148315	0.08
285.1475525	100.00
297.1482239	0.03
300.1185913	0.03
301.2489624	0.08
302.0965881	0.02
303.1744080	0.50
315.2409668	0.15
316.2072144	0.02
329.3849792	0.26
333.1294556	0.01
339.1346436	9.48
339.7686157	0.03
344.4295044	0.06
349.2566528	0.11
355.1715088	0.31
365.4577026	0.06
377.9422607	0.03
391.1338196	0.05
397.2475586	0.13
421.2500916	0.34
423.2414856	0.01
447.1813660	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0337
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
93.9814453	0.01
120.9179993	0.01
129.0463257	0.03
146.8832855	5.75
151.2492828	0.01
152.9156494	0.02
154.8950653	0.01
156.8252106	0.20
162.9596405	0.01
164.6366577	0.39
174.8833160	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	Anisindione
Peak:m/z	Relative Intensity
77.2255249	0.18
82.9132767	0.46
89.1716766	0.53
91.0211258	0.57
94.7197723	0.42
99.1998596	0.82
102.9846649	0.79
103.9576874	0.95
104.8591156	2.67
107.0074310	1.10
108.9940033	1.09
114.8841553	0.92
118.8204346	0.27
122.8915558	2.31
127.0412140	0.27
128.9677429	7.51
131.1333923	0.83
132.8213501	0.23
137.1214447	0.16
141.0522003	1.11
147.0842743	1.61
148.2698059	0.43
150.9832916	100.00
151.9981232	5.14
153.2985687	0.18
155.1593170	0.84
157.2479858	0.52
163.3272247	0.23
165.2581329	0.57
166.2362671	1.74
167.0868683	2.07
167.9841156	0.48
169.1231232	1.20
170.4955902	0.46
171.1932220	1.32
178.1235657	0.28
179.0949554	2.63
182.2129974	1.05
183.1362762	1.64
185.1856537	4.31
191.2215118	0.54
192.0826263	0.23
192.9349670	0.59
194.2420197	2.19
195.0731659	0.23
197.1384430	6.19
198.3453064	0.44
207.1080322	0.92
207.9937134	0.27
208.8106232	0.16
210.2002106	1.00
211.0453796	1.07
211.9186859	1.83
216.6590729	0.35
223.4249725	1.05
225.0591125	15.70
226.2819824	1.12
227.0533295	0.52
229.8941803	1.84
235.0564728	3.66
235.9330444	0.61
238.1589355	20.48
238.9512787	1.73
243.6013641	0.94
251.2475586	1.41
253.2130890	94.47
254.2704620	1.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1561
Annotation	Unknow
Peak:m/z	Relative Intensity
282.4814148	0.03
362.9692993	0.04
377.0574341	0.04
383.3096313	0.05
385.2562256	0.10
428.9447632	0.11
429.5530396	0.04
446.3926392	0.06
473.2939453	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	446.1514
Annotation	Quinic acid
Peak:m/z	Relative Intensity
131.1203918	0.45
143.1844635	0.05
144.8778992	0.12
160.9880219	0.27
170.1211853	0.05
178.4673767	0.06
179.0997314	0.70
183.0290375	0.07
213.8621216	0.04
251.0733948	0.13
259.0852051	0.15
265.2936401	0.07
272.8289795	0.05
281.0763245	0.04
300.2385559	0.12
303.0434265	0.13
316.3911438	0.12
322.9478760	0.34
323.6778870	0.16
325.4726562	0.09
341.2646790	100.00
355.9855347	0.17
361.4787292	0.09
362.1583252	0.10
384.1947327	0.04
385.0843201	0.21
399.5280151	0.07
402.4710083	0.03
403.4646301	0.09
428.2333069	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.3297
Annotation	Unknow
Peak:m/z	Relative Intensity
249.1459351	0.01
266.2554932	0.02
280.3582764	0.02
282.3449402	0.01
283.4375000	0.05
291.3973694	0.01
297.4505615	0.03
299.5283813	0.01
301.2483521	0.03
313.3043213	0.01
318.3433228	0.03
324.5061951	0.01
325.3970032	0.01
326.2679443	0.01
327.5286255	0.02
331.4979553	0.03
332.1837158	0.02
334.1753540	0.02
335.3501587	0.12
336.1393127	0.05
343.3611450	0.01
345.3244019	0.03
359.3495178	0.01
363.3045959	0.01
372.4063721	0.07
373.3810425	0.02
381.0601196	0.01
384.1528320	0.11
397.2728882	0.01
401.3084106	0.01
402.4437256	0.03
414.4096069	0.16
415.4221191	0.02
416.3335571	0.02
418.3667603	0.02
427.3923950	0.02
442.3959351	0.04
444.9432373	0.04
446.2517090	0.05
447.5236816	0.01
448.6890869	0.04
449.3245239	0.04
451.4912109	0.02
458.2653198	0.23
459.4680176	0.04
460.4125366	0.06
461.3608398	0.02
465.2683716	0.02
469.7077637	0.02
475.4037476	0.02
477.2693481	0.05
478.4560547	0.04
483.5638428	0.03
490.3218994	1.49
491.3524780	0.62
492.3745117	0.02
493.3787231	0.06
495.4761963	0.43
496.5831909	0.15
503.6235962	0.04
505.3046265	0.02
506.4382324	0.01
510.4425049	0.06
512.4351807	0.02
524.2059326	0.02
527.3146973	0.03
535.5370483	0.03
537.4512329	3.76
538.4353027	1.45
540.0591431	0.06
540.6644897	0.09
541.3094482	0.02
543.5025635	0.01
552.7003174	0.02
554.5537720	0.07
559.4857788	0.01
563.6352539	0.08
564.5015259	0.02
569.5255737	0.10
570.5001221	0.02
571.2072144	0.01
579.0839233	0.01
581.3875732	8.22
582.4007568	3.54
583.1260376	0.03
586.5986938	0.02
594.4627075	0.03
595.5408936	0.06
598.4439087	0.04
599.3512573	0.01
601.5496216	0.02
602.4720459	0.04
605.1567383	0.02
609.4197998	0.02
611.0783691	0.02
613.3986206	10.79
614.5001221	3.86
615.3953857	0.02
621.3596802	0.04
623.4584351	0.09
625.1191406	0.02
626.8947144	0.04
628.0313721	0.06
628.8107300	0.01
629.5797119	0.01
630.4835205	0.08
631.4244995	0.14
638.4426880	0.87
639.4592896	0.88
640.4332886	0.13
641.6258545	0.02
646.8394165	0.01
647.4727173	0.01
649.2221069	0.01
652.6196899	0.01
655.1105347	0.05
656.4185791	0.06
658.4575806	0.11
659.4220581	0.02
660.2577515	0.03
661.4474487	0.02
666.3515015	0.01
669.2301636	0.05
670.4133301	3.17
671.3911743	0.94
672.3110352	0.21
673.5513306	0.02
675.6247559	0.08
683.3616333	0.03
685.1256714	0.01
694.9068604	0.05
698.3497314	0.01
701.2963257	0.05
703.5161743	0.01
713.4687500	0.03
717.4930420	0.39
718.1151123	0.11
718.7305298	0.12
719.4885864	0.06
720.5233765	0.02
743.5337524	0.33
744.3915405	0.22
745.0176392	0.02
746.5098877	0.02
747.4906616	0.07
748.6033936	0.02
749.8960571	0.07
759.5148315	0.01
761.4650879	100.00
762.4502563	37.45
763.5233154	0.09
764.3245850	0.02
773.6397705	0.03
775.3800659	0.56
776.5410767	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	(plusmn)Abscisic Acid
Peak:m/z	Relative Intensity
82.9861908	0.32
96.86382294	0.10
109.161026	0.08
111.0168457	1.91
127.9882965	0.06
133.0560303	0.17
136.8809814	0.10
138.0570831	0.11
139.3498993	0.15
142.9579773	0.10
147.3340454	0.06
150.1789856	0.07
153.0965424	100.00
153.9214325	0.13
161.0499115	0.48
162.1643982	0.12
167.1976471	0.13
171.1354523	0.09
173.0731201	0.06
175.181076	0.41
178.1725922	0.06
181.2785187	0.19
183.1382294	0.14
189.3139954	0.20
191.0423737	0.17
197.2030029	0.09
201.0632172	1.35
203.0997925	0.42
204.2078552	1.73
217.2057495	0.93
219.2380066	28.58
221.1943817	0.30
227.300415	0.10
234.2965851	0.08
236.469986	0.22
243.3722534	0.50
244.2399902	1.19
245.1390839	2.48
258.9174194	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.0991
Annotation	Urolithin A 3,8-O-diglucuronide
Peak:m/z	Relative Intensity
179.0541992	0.10
181.0875854	0.05
191.0471802	0.16
208.0415955	0.05
221.2402802	0.11
232.1794739	0.07
245.1235962	0.12
249.0552979	0.08
253.2089386	0.26
255.3793488	0.12
270.0761108	0.04
271.2449951	0.12
298.2113342	0.15
300.3094788	0.07
314.6956177	0.13
315.3789673	0.10
316.9772949	0.14
325.4323120	0.05
329.0969238	0.04
331.1477051	0.07
335.2337036	0.08
344.1415405	0.07
345.2374268	0.11
355.3675537	0.14
357.2818604	0.03
369.7468262	0.22
373.4102783	0.17
381.3237915	0.09
386.2124023	0.18
386.9585571	0.05
403.2555542	0.15
408.2911987	0.03
416.2151489	0.34
417.2586670	17.96
417.8709717	0.20
426.3322754	0.18
427.0756836	0.05
428.3925171	0.08
433.4183350	0.17
434.3432007	0.11
438.2324219	0.04
442.0947266	0.05
443.1889038	0.17
446.9368286	0.12
452.1698608	0.04
453.5216675	0.06
459.3347778	0.34
462.4167480	0.15
463.1648560	0.15
465.3151855	0.15
467.4588623	0.08
472.7759399	0.10
483.3878174	0.17
487.4183350	0.17
488.3762817	0.92
491.5205078	0.17
493.0006714	0.55
493.6120605	0.17
495.3159180	0.08
499.1544800	0.04
503.1566162	0.07
515.2387695	0.12
517.5245972	0.05
518.6200562	0.06
521.3542480	0.24
525.0080566	0.15
532.2910767	3.52
533.2161865	0.81
535.2962036	100.00
540.5462036	0.03
547.1264038	0.26
549.3337402	0.07
550.4553223	0.29
551.6282959	0.27
557.3065796	0.22
559.4783325	0.26
560.9995117	0.96
561.8030396	0.16
565.1718140	0.25
569.7489624	0.08
570.5456543	0.14
587.4589233	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.1901
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1275330	0.10
227.0455627	0.05
232.7838135	0.03
241.2187500	0.12
243.1185303	0.26
244.2047729	0.10
245.1171265	0.13
257.0870056	0.02
259.1220703	6.53
278.2554626	0.06
281.0671692	0.05
299.0371094	0.02
305.2268677	0.14
323.1553955	0.41
334.6256714	0.06
339.2576294	0.15
341.1104126	5.23
341.7491455	0.07
345.9547119	0.11
355.3449097	0.02
361.0520020	0.03
371.1902466	0.02
379.9830322	0.05
383.3051147	7.82
401.8480225	0.02
412.9205322	0.85
419.4724731	0.03
420.0886230	0.04
421.4342041	0.02
425.2305908	0.09
437.0417480	0.06
443.0468750	4.64
450.8736572	0.04
458.7715454	0.02
465.3486328	0.01
467.0404053	0.18
473.0321655	0.02
480.3394775	0.04
481.2769775	0.02
483.2135010	0.05
485.2551880	3.90
493.3307495	0.03
503.1583862	3.23
504.2534180	0.02
512.3364258	0.04
517.5296631	0.17
518.9095459	0.07
523.3495483	0.04
527.1005859	0.05
541.2664185	0.07
545.4400635	2.46
563.6129150	0.02
565.4719849	0.16
577.4235229	0.03
583.2743530	1.44
583.9940186	0.02
587.3230591	0.20
591.1731567	0.16
592.3410034	0.24
601.2384033	12.86
601.8586426	0.14
605.6672363	0.02
617.0564575	0.13
619.0109863	0.04
620.9050903	0.06
622.4527588	0.03
630.9885254	0.02
665.3540649	100.00
673.3644409	0.06
679.5070190	0.02
685.1849976	0.03
689.4071655	0.17
703.5837402	0.11
708.7866821	0.03
710.6416626	0.14
715.1864624	0.03
717.2631836	0.05
745.3079224	14.99
745.9423218	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2339
Annotation	Ejap 3
Peak:m/z	Relative Intensity
163.8692932	0.15
165.0138550	0.40
167.0500488	0.45
177.0281372	0.08
195.0272217	1.71
201.0271301	0.06
205.1202393	0.03
206.5439148	0.04
207.1994324	0.07
245.1406403	0.04
247.0035400	0.04
249.2543945	0.09
265.9887695	0.15
267.6210938	0.06
278.3309631	0.13
285.3512878	0.12
297.5509338	0.03
299.1579590	0.28
305.2998047	0.18
311.2076416	0.45
314.3289795	0.20
315.1277466	1.66
317.1785278	0.10
321.1622925	0.05
322.9978027	0.24
325.2528687	0.05
328.0875244	0.12
329.3198242	18.98
332.4226074	0.05
336.0665283	0.11
341.3246460	0.11
343.2333374	18.89
345.2735596	0.18
347.1712036	0.11
352.3849487	0.07
354.1644287	0.08
355.2445679	0.11
358.8519287	0.44
361.0241699	0.16
363.0812988	0.05
366.0787354	0.03
367.2640381	0.06
373.2543335	0.53
374.7600098	0.06
377.2351685	11.99
389.7272949	0.14
391.1421509	8.19
391.7723999	0.03
393.1063232	0.13
394.8234253	0.14
400.4691162	0.11
403.5595093	0.04
407.1913452	0.04
409.1739502	0.11
411.4328003	0.06
413.4423218	0.13
415.2266235	0.04
419.3273315	0.17
420.9840088	0.31
424.4052734	0.05
428.3330688	0.04
429.4352417	0.13
439.1976318	0.08
453.3853760	0.32
454.7520142	0.17
467.3041992	0.05
470.5535889	0.03
473.5939331	0.07
477.3350220	0.22
483.7615356	0.04
487.1834717	0.10
493.5598755	0.12
498.9739380	0.04
505.2384644	0.07
510.2811890	0.05
511.2783203	0.11
525.3076172	100.00
526.7208862	0.87
527.4274902	4.40
528.2475586	0.26
529.3684082	0.51
534.9500122	0.06
536.5294189	0.49
537.2985229	0.05
540.6281128	0.12
542.1587524	0.12
543.3877563	0.38
550.3294067	0.18
553.1052856	0.10
555.2208252	2.32
556.8732300	0.13
558.5585327	0.24
563.6757202	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.2552
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1280975	0.17
167.2495117	0.04
177.0368042	0.08
190.0519104	0.04
191.0918579	0.71
201.0075684	0.15
206.0315552	0.04
210.7427979	0.04
215.1826172	0.05
220.9506836	0.19
222.0151062	0.04
222.9713440	0.07
225.3473511	0.08
226.8618317	0.04
231.0571442	0.09
233.1786499	0.16
237.3873596	0.12
238.9129486	0.14
251.1172333	0.19
255.2943573	0.20
257.1836243	0.03
263.4328308	0.23
278.0340881	0.07
282.2126160	0.03
283.2116394	0.09
292.9359131	0.50
293.9995728	0.81
295.0151367	0.07
311.0506592	1.62
312.0659790	1.11
313.1831055	0.30
321.2698364	0.06
323.2428589	0.18
327.2991333	0.10
333.1301270	0.06
337.2753906	0.50
341.2590332	0.62
343.0274048	0.10
345.1815796	0.34
356.7499390	0.03
359.0510254	0.04
368.4501343	0.06
369.3833618	0.23
370.0309448	0.09
371.2239990	1.08
381.1634521	0.25
385.3222656	0.86
386.2543335	0.88
387.3502808	2.18
389.1818237	0.07
391.5936890	0.06
399.4964600	0.23
417.4777832	0.90
419.4092407	0.07
421.6358643	0.15
427.3256836	0.14
429.2321167	0.11
441.4353638	0.05
449.5145874	0.03
453.3026733	0.10
459.4116211	0.22
461.1149902	0.04
462.3795166	0.28
463.2094727	0.16
464.9650879	0.36
468.0994263	0.33
473.4125366	0.05
474.1956787	0.06
475.4075317	0.26
477.1616821	0.04
480.5555420	0.05
487.6758423	0.04
488.8400879	0.06
489.6921387	0.06
491.3596802	1.31
500.1291504	0.07
502.2305298	5.43
503.3372803	100.00
505.2814941	8.88
506.4716187	0.14
507.3847046	0.08
513.5314941	0.06
517.1947021	0.27
529.0858765	0.16
531.2390137	0.86
532.4322510	0.09
535.0947876	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9679108	5.12
116.0822449	2.49
117.0365143	2.46
131.0539246	0.16
131.8980408	0.20
132.9130249	0.33
136.0715332	0.06
145.1766052	0.05
158.9236908	100.00
159.9763794	49.94
161.0208893	69.40
163.9365692	0.04
174.6496582	0.23
199.0030212	0.10
199.9693298	0.36
200.9454956	3.25
202.9006653	0.03
218.1628113	0.83
219.1031494	1.86
229.0882568	1.72
230.0046997	20.67
230.9302063	36.53
232.8643799	0.11
245.2427368	0.05
246.1224976	0.41
247.0588379	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.17
Annotation	Unknow
Peak:m/z	Relative Intensity
96.8383408	0.04
98.9064865	0.06
106.7484589	0.23
109.1420822	0.11
112.9750671	0.34
117.0011673	0.11
127.0420837	0.18
129.0038147	0.06
130.9173279	0.07
134.1414490	0.08
135.0636902	0.22
135.9512787	0.27
142.8075562	0.21
144.8602295	0.42
152.8899841	1.30
162.0714569	0.39
162.9962006	0.40
167.2515564	0.10
169.9311218	2.65
176.3865967	0.11
179.9880676	7.57
181.0691833	0.11
193.1349640	0.57
194.0293274	0.13
195.0604706	0.37
197.2735291	0.21
198.1757050	0.13
200.3227692	1.07
201.2522583	0.08
203.0545044	0.09
205.3839722	0.17
206.2127075	0.14
207.0037689	0.11
217.0877075	0.13
218.9926453	9.44
231.0678101	0.58
235.2148743	2.64
237.2245178	0.21
239.0753174	0.12
240.3185425	0.10
242.3497314	0.45
243.1518250	0.76
249.0911865	0.15
253.0205383	1.91
254.3963013	1.01
255.1326599	0.36
256.1391602	0.20
256.9082642	0.18
261.1016235	6.25
266.0633545	0.38
269.1825256	0.64
270.2050781	0.13
276.1217651	0.37
279.0466309	15.63
279.6789551	0.03
286.0623779	0.82
288.5985413	0.38
289.3086243	0.28
290.0242310	0.32
295.4370422	0.08
297.1975403	100.00
302.0874939	0.29
304.0665588	0.78
311.9163818	0.13
313.2347107	1.68
314.3137817	7.86
315.0934448	6.49
318.1625977	0.08
322.8417358	0.46
338.0087891	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.1721
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
127.0078735	0.02
142.2039642	0.02
148.9025574	0.03
184.9394836	0.10
191.0404358	0.08
193.1178589	0.55
200.1762390	0.02
203.0315399	0.41
207.1588745	0.06
220.1435394	0.10
227.2084656	0.15
230.3475494	0.08
235.1820984	0.30
243.1106262	0.04
245.1242065	0.69
251.3631287	0.02
261.1829224	0.17
265.2929382	0.09
271.1261902	0.07
273.1962891	0.04
279.1888123	0.11
289.1100464	1.09
295.0278320	0.04
309.2787170	0.05
320.6448975	0.03
325.6145630	0.05
327.2068787	0.07
329.4583435	0.05
337.2386475	0.52
347.1539307	0.13
355.3303528	10.20
367.0854797	0.03
367.8608704	0.08
369.5130005	0.05
379.3913879	0.46
381.2079773	0.03
387.1649475	0.03
397.3080750	100.00
398.1996155	0.19
404.3691101	0.16
408.3116760	0.24
422.1190491	0.18
423.3916931	0.20
427.6467285	0.04
432.3393250	0.28
442.2602234	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0775
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
98.1457672	0.03
99.0416107	0.34
101.0005035	0.21
109.0920334	0.03
110.9418564	0.25
112.9998169	1.47
113.8527145	0.09
114.9217987	0.88
117.0500107	0.08
119.1841888	0.09
122.8343353	0.03
124.9034882	0.03
126.9507980	0.56
129.0686035	0.54
131.1040192	0.28
136.7403717	0.08
138.9308167	0.17
140.9308929	0.16
149.0393677	0.26
151.1073914	0.06
152.9772949	0.31
155.1194763	0.13
156.0221558	0.09
157.0201721	1.56
159.3643036	0.02
161.0690765	0.08
165.2732086	0.04
169.0644531	1.31
174.0904541	1.32
174.9722748	1.37
178.9989777	0.02
201.1988525	0.08
211.1911011	0.03
216.1304932	0.01
219.0049133	0.02
231.1443481	0.05
233.0632019	0.08
241.3850708	0.06
246.2647095	0.09
247.2093201	0.12
259.2218933	0.02
263.1406555	0.03
274.8488770	0.05
277.1396179	100.00
291.0252075	0.05
293.1260986	3.53
301.4462280	0.03
307.1864929	0.01
319.2352905	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9168
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9831543	0.18
175.0400696	0.63
202.6306763	0.01
229.0827942	0.02
244.9806213	0.20
273.0265198	4.10
287.2748413	0.08
288.9495544	100.00
329.1186218	0.08
346.6130371	0.07
347.9254150	0.01
349.1393433	0.02
357.1479797	0.07
358.2644958	0.10
359.1260071	0.10
374.8957825	0.04
384.9031067	0.13
393.1465454	0.09
402.8595276	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1295
Annotation	Erlangerin D
Peak:m/z	Relative Intensity
144.9881744	3.71
146.9232635	0.09
150.9951172	0.07
157.0570679	0.14
158.0489502	0.03
159.0482483	0.09
161.1373138	0.19
163.0354767	3.96
165.0786438	0.03
173.1443787	0.12
175.1125488	0.13
185.2471313	0.04
187.1158752	0.84
189.0902252	0.22
198.4683228	0.04
199.4031830	0.05
201.0348053	0.03
203.1571198	0.13
205.1352997	0.75
215.2427673	0.05
217.0395813	0.11
219.1275177	0.39
221.2244110	0.03
229.1689148	0.02
231.0672150	0.07
233.1768036	0.11
235.0328674	0.09
241.1202393	0.03
245.1204224	0.03
247.2211914	1.38
259.0083008	0.03
263.1267395	0.05
265.2274780	0.52
267.4743652	0.07
271.0585327	0.04
276.9331970	0.05
290.4444885	0.06
307.1152649	100.00
307.8445435	0.10
309.3173218	0.13
317.4710693	0.04
319.0182495	0.37
323.2664795	0.04
325.3407593	0.14
332.9273682	0.03
341.5604553	0.05
351.0684204	0.13
353.3092041	0.07
357.5486755	0.04
385.1919250	0.06
399.6346741	0.03
424.3068542	0.03
425.2344055	0.04
427.3540955	1.07
435.4910583	0.02
452.1614075	0.05
453.2441101	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1386
Annotation	Limocitrin 7-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
174.0944672	0.04
184.2939758	0.06
187.0198059	0.33
193.1434631	0.02
203.0643921	0.03
205.1529846	0.33
207.0874634	0.02
221.4257507	0.04
238.1866913	0.04
241.4855652	0.04
252.9783325	0.08
260.8424072	0.03
267.5059814	0.02
270.8906555	0.01
276.9781799	0.01
297.1343384	0.01
299.0612183	0.02
301.1432495	0.02
302.2840576	0.02
303.3053589	0.26
309.9275818	0.03
313.0249023	0.09
314.1035767	0.02
320.0190430	0.04
335.1367188	0.03
339.3004150	0.04
347.1544800	100.00
347.7637329	0.38
351.0592041	0.17
352.3729858	0.03
356.1101074	0.02
357.3054810	0.03
361.3950195	0.05
365.2726440	0.03
369.2906494	0.06
371.0415039	0.13
381.8267822	0.10
387.3649292	0.04
389.2786865	1.66
392.2598267	0.06
396.2045898	0.05
397.2763672	0.02
401.2528076	0.02
413.2495728	0.45
414.2527466	0.05
431.2467651	0.03
433.2869263	0.03
437.1523438	0.21
439.7080688	0.02
443.3704224	0.03
445.2139893	0.03
447.4190674	0.01
450.0535889	0.04
455.3018188	0.98
458.2286987	0.04
460.1995850	0.03
461.3378906	0.08
463.0654907	0.05
464.1259155	0.04
465.1050415	0.03
473.2958374	0.02
477.7021484	0.08
479.2092285	0.10
485.6267700	0.12
487.2905884	0.05
489.1802979	0.04
490.9306030	0.07
497.3081055	0.10
499.3516846	0.12
505.3349609	0.18
507.3798828	0.05
508.6116333	0.05
515.0809937	0.55
515.6819458	0.24
519.4297485	0.02
521.4589233	0.14
526.4140625	0.01
533.1847534	4.21
541.8775635	0.05
550.8810425	0.08
551.7561646	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1194
Annotation	Unknow
Peak:m/z	Relative Intensity
136.7760010	0.07
138.2861176	0.04
149.0619202	2.57
151.1527100	0.12
153.1782837	0.04
162.9139099	0.06
164.0552063	0.10
165.0282593	0.61
166.9904175	0.25
173.0491486	0.09
175.9800873	0.03
177.0405121	0.12
180.9646912	0.06
191.0950317	0.70
192.1253967	0.88
193.0444336	1.96
197.1099854	0.17
203.2086029	0.04
205.2923737	0.03
207.2360840	0.30
217.2425842	0.04
220.0419464	0.28
220.9698029	0.01
232.0898438	0.04
235.1535645	0.26
236.6770935	0.02
244.8814240	0.04
246.9766541	0.09
252.9983521	0.03
259.0467224	0.11
261.2236023	0.30
263.2921753	0.21
265.1506042	0.18
281.2016602	0.28
284.2249451	0.21
285.2789917	0.17
286.1711731	0.09
289.1014099	0.05
291.1642456	0.04
297.2715454	0.11
299.1495056	8.63
299.9457397	0.04
303.1423645	0.75
311.3258057	0.13
312.8910828	0.15
314.0843506	0.62
314.7785645	0.16
317.1602478	0.93
319.3049316	0.37
325.1680908	69.24
329.2135315	100.00
331.2006836	0.23
345.2821045	0.38
346.3240967	3.40
347.1857910	12.80
351.1624146	0.05
355.2290039	0.76
357.3544006	0.06
359.0747986	0.06
371.1291199	0.32
375.3436890	0.16
382.9577332	0.12
389.2173157	1.02
391.2438049	0.07
393.0050659	0.12
401.1112366	0.07
413.4335632	0.06
419.3055725	0.02
433.2647705	0.14
435.3548889	0.68
461.3080139	2.95
464.4836731	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
132.4662170	0.26
133.0825806	0.56
133.8398285	0.14
134.9869232	6.00
147.0420532	0.04
161.0131683	25.85
175.0809631	0.06
177.0739594	0.13
179.0028076	100.00
179.7751160	0.03
189.0295715	0.09
203.0970917	6.81
205.1835327	0.12
216.9372864	0.04
219.1994934	0.12
221.0896301	0.71
231.0202637	0.04
232.1858215	0.06
233.1247559	0.83
245.1484070	0.27
247.9273987	0.08
251.1823120	2.55
261.2416077	0.05
269.1448364	0.13
275.1291504	0.06
281.0758362	3.98
281.6784973	0.03
293.1875610	0.08
295.6965637	0.15
297.1246948	0.15
323.0754089	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0986
Annotation	Castamollissin
Peak:m/z	Relative Intensity
147.1123962	0.04
158.9536743	0.06
161.0716248	0.05
163.0262604	0.27
165.1992188	0.03
173.4167175	0.04
174.2142029	0.05
175.3165283	0.04
177.0074768	0.35
178.3213196	0.04
179.2718201	0.03
183.1238098	0.02
189.1918640	0.17
190.9925537	0.39
191.8031921	0.05
193.0200195	0.06
194.9702454	0.02
199.0427246	0.13
201.2035522	0.05
202.9311218	0.18
205.1574097	0.12
206.2216187	0.02
211.0921631	0.25
212.1809540	0.04
213.0348511	0.21
215.1259613	0.27
216.0975494	0.10
217.1786194	0.81
218.2211304	0.14
219.2236938	0.16
223.1071625	0.16
226.1130981	0.07
227.8958130	0.36
229.2372284	0.15
231.0107117	0.16
233.0668640	0.49
234.2568970	0.07
235.1735229	0.03
239.1737518	0.10
240.1658783	0.10
242.3298035	0.12
243.0250549	0.04
244.1295776	0.18
245.1467133	0.06
246.1374969	0.02
247.1470184	0.32
253.0866089	0.13
255.1479797	0.25
256.9766541	0.94
258.0388794	0.16
259.0802612	0.40
260.4114075	0.02
264.3396606	0.02
269.2689209	0.11
270.0182800	0.03
271.1412354	0.19
272.2625427	0.15
273.1960144	0.40
275.1036072	0.13
280.0712891	0.09
281.1920776	0.06
283.1520996	0.71
285.2144165	0.53
286.0174561	0.13
287.2543945	0.22
288.2575684	0.11
295.2311401	0.29
296.3108521	0.02
297.2417603	0.21
298.2643433	0.08
299.4335022	2.20
300.1716309	48.90
301.1402588	100.00
302.2097168	17.41
303.2109985	0.11
306.9340515	0.03
311.2030029	0.10
313.0739441	2.20
314.0872192	0.90
315.1393433	7.62
316.0916138	1.54
317.2960205	0.04
319.3292847	0.05
320.4852295	0.02
325.2368774	0.55
326.1589355	0.22
327.2973022	0.12
328.2013245	0.04
329.2755432	0.10
330.2937622	0.15
331.3587036	0.05
333.0335693	0.03
337.4526978	0.05
338.3921204	0.10
339.6964417	0.08
340.3371887	0.06
341.0781860	0.13
342.1162415	0.14
343.2048340	3.43
344.1667175	0.87
352.1830750	0.06
353.2546692	0.06
354.1682129	0.04
355.1615601	1.43
356.1237793	0.46
357.2891235	0.06
361.1236572	0.03
364.0810852	0.05
365.0361938	0.05
367.1958008	0.26
368.3544312	0.10
373.1934204	1.23
374.3417969	0.17
376.9727478	0.07
379.1790771	18.54
380.2665100	4.33
381.3737488	0.06
383.3815918	0.11
385.2226562	0.71
386.0284729	0.03
396.1674194	0.15
409.2961121	0.04
417.2686462	0.05
419.2809143	0.03
420.1360168	0.04
427.9718628	0.09
438.3389282	0.04
444.3169861	0.11
445.2668762	0.32
446.5820312	0.02
459.1684265	0.07
460.0610962	0.08
461.4119568	0.11
462.2648926	0.06
463.2444763	2.46
464.1975708	0.48
469.3136292	0.12
470.2775269	0.07
472.4475403	0.06
474.4822388	0.04
477.0353699	0.02
487.1403198	1.46
488.3935242	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.0912
Annotation	Avicularin
Peak:m/z	Relative Intensity
148.3432007	0.02
272.4087524	0.03
301.0180054	0.01
303.1405640	100.00
303.7615356	0.18
315.1497192	0.05
324.9233398	0.01
327.2899170	0.02
345.3013916	0.14
357.2779541	0.02
361.0538635	0.01
369.2970276	0.44
371.0829773	0.01
377.1650391	0.03
389.3031311	0.02
399.1998901	1.04
417.2559509	1.16
425.4598694	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1302
Annotation	Quinic acid
Peak:m/z	Relative Intensity
158.9724579	0.07
161.2898560	0.01
173.1547546	0.02
191.0961761	1.59
192.1387939	0.10
237.0617676	100.00
239.5440674	0.01
251.9191895	0.01
263.1246033	0.03
302.1039429	0.04
341.2818298	0.01
342.3011169	0.01
348.9924316	0.02
355.0581665	0.01
356.9181519	0.05
385.3458557	0.03
414.0491028	0.05
429.9441223	0.04
431.4507751	0.04
454.3926086	0.14
455.1527710	0.13
457.2826843	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.3416
Annotation	Unknow
Peak:m/z	Relative Intensity
224.6204834	0.03
245.9783783	0.14
250.3224030	0.06
261.3451538	0.19
274.6180420	0.09
287.0510559	0.08
301.2269592	0.04
304.1541748	0.04
313.3597412	0.18
323.2493896	0.08
325.4825439	0.04
329.3106384	0.19
331.2759399	0.44
337.2053223	0.09
339.0324707	0.06
341.5975342	0.06
343.4605713	0.03
345.1944580	0.05
347.4271851	0.13
356.9813843	0.03
361.4350586	0.19
367.2798462	0.22
371.2907104	0.24
380.4042969	0.19
388.5091553	0.04
390.0221558	0.08
399.3728027	0.25
411.2742310	0.05
421.4529419	0.24
427.3001099	0.07
434.4019775	0.18
439.3107300	0.06
442.6549683	0.13
447.4053345	0.10
449.4003296	0.92
458.3889771	0.03
460.3563232	0.95
461.0395508	0.05
466.0280762	0.08
474.3163452	0.10
475.2586060	0.40
476.1235352	0.17
477.3553467	0.50
478.2220459	0.25
481.1721191	0.94
489.5557861	0.11
491.7061768	0.10
492.3776245	0.16
498.5816040	0.08
507.0598755	0.57
509.4294434	0.10
510.3547974	0.74
528.4411621	0.12
541.5009155	0.07
565.3865356	0.05
570.7489624	0.07
575.5351562	0.05
581.3706055	0.13
583.3569336	0.32
587.6950684	0.04
591.6600952	0.08
593.3980103	0.08
596.5895996	0.12
600.1933594	0.52
601.2656860	14.76
606.4291992	0.05
614.5067139	0.32
615.4530029	0.38
618.3390503	0.05
623.9229126	0.15
626.7243652	0.06
628.4157715	0.24
632.5444336	2.26
633.2984619	9.27
639.8470459	0.46
640.4848633	5.41
641.4103394	0.56
642.7845459	0.12
643.3859863	0.04
654.6950684	0.10
659.5413208	0.11
660.3186646	0.42
661.4315186	0.10
662.7732544	0.25
663.4147339	0.97
671.3989258	0.33
672.4619751	34.48
673.4916992	0.46
674.4420776	0.31
683.8536987	0.24
694.4906006	0.05
709.1594238	0.08
710.5245972	0.06
713.6714478	0.08
719.5035400	0.53
726.6155396	0.05
727.4017944	0.26
733.3189697	0.09
741.1746826	0.06
745.4458008	1.97
748.3543091	0.24
749.0889893	0.15
759.7550659	0.05
763.3952637	100.00
764.1161499	0.51
766.5739136	0.03
768.2254639	0.19
776.3563232	0.51
777.2932739	0.74
779.4549561	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.0276
Annotation	Unknow
Peak:m/z	Relative Intensity
83.4892654	0.08
95.0261688	0.06
107.8649368	0.12
119.1374817	0.09
124.0180969	5.41
125.0440140	0.08
135.0091858	0.12
136.1315460	0.33
137.0705261	1.96
137.9596710	0.22
144.1473999	0.18
146.9821930	7.78
148.0018311	2.82
149.1737061	0.40
151.1175842	0.19
152.0947571	0.45
155.0178833	0.05
157.9500275	0.08
159.9157715	0.07
161.0719299	0.06
162.8791809	0.54
163.9735107	1.70
164.9111633	0.11
167.1483917	0.04
171.3179474	0.25
172.2020569	0.83
173.1107483	0.12
175.0155640	0.58
176.0929413	0.86
177.2135315	0.73
178.9586792	0.39
180.1093445	0.46
182.0326233	0.12
182.9417419	0.48
184.2364807	0.39
184.9661255	0.07
186.1371765	0.34
187.0599060	0.63
187.9562531	0.82
189.7930603	0.16
191.0020142	0.62
191.9880676	0.08
198.0929871	0.27
199.0642700	1.39
200.1424255	2.54
201.1199646	0.64
201.8045654	0.20
204.0594482	2.44
209.1317139	0.20
210.0941467	0.92
211.1352234	3.09
212.1604919	1.92
213.2079468	0.64
214.2029114	1.17
215.0838928	0.50
216.1364746	4.48
217.1659546	0.17
219.3761292	0.06
221.2059937	0.05
225.2615662	0.24
226.0869751	3.08
227.1449890	4.93
228.1956482	11.49
229.1436768	1.23
230.0896912	1.46
231.3125000	0.18
232.1263123	0.21
233.2693787	0.11
238.0110474	0.99
239.1554871	7.47
240.2006836	0.75
241.0521545	0.48
242.3657532	0.88
243.0042419	4.08
244.1612854	4.93
245.1336060	0.10
254.0039062	8.38
255.1401367	14.03
256.0884094	15.48
257.1510315	2.52
258.1445312	1.85
259.1157532	0.69
265.1057739	0.32
271.1191406	100.00
272.1033020	44.52
272.9518127	0.10
281.1924744	2.13
282.1971436	3.80
283.0957336	10.19
284.4349365	0.68
285.5373535	0.08
299.0980530	0.18
300.2649536	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.0584
Annotation	Unknow
Peak:m/z	Relative Intensity
180.8540039	0.04
198.0389404	0.11
227.2635040	0.07
228.4810333	0.17
229.9944611	0.07
235.0033722	0.24
246.2121277	0.11
264.8408508	0.06
293.0195312	11.48
295.2449341	0.18
296.3173828	0.10
302.2372437	0.22
310.0124207	0.10
310.9388428	0.17
324.2961426	0.05
325.1766663	0.06
340.2460938	0.04
343.7995300	0.04
345.5658264	0.08
351.3712769	0.32
352.8527832	30.28
353.5009155	0.09
354.5066528	0.47
359.1883545	0.12
361.2442932	0.72
364.9188843	22.69
365.5886230	0.07
366.2536316	0.10
368.4141235	0.06
369.7590332	0.06
375.1021729	0.17
376.6379395	0.98
379.1402283	0.27
382.9919434	100.00
383.6814880	0.16
385.0501099	0.16
391.7402039	0.76
393.2753601	0.14
395.0277405	0.88
397.0549622	0.61
401.2203674	0.14
407.2499695	0.59
409.2240295	0.06
411.1283264	0.16
412.9470825	16.04
415.3705139	0.05
423.2080688	0.90
424.7618103	0.24
427.2175598	0.08
428.0865784	0.09
437.1227722	4.31
441.1666565	0.52
443.0339050	0.63
453.2125244	0.05
455.0879517	24.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.4507
Annotation	Unknow
Peak:m/z	Relative Intensity
292.5186768	0.44
321.0731201	0.06
349.0717773	15.54
349.7794189	0.09
355.9971313	0.34
363.1539917	0.17
446.0528564	0.77
453.3433228	0.34
454.8460083	1.72
455.9528198	0.43
465.2489624	0.22
470.9558105	0.32
486.0625610	0.86
523.1369629	100.00
524.0945435	1.49
524.7165527	0.13
526.8715210	0.29
535.9673462	0.13
580.2136841	0.06
587.3057861	0.17
596.7628784	1.61
607.7951050	0.26
608.9724121	0.66
617.0886230	2.45
638.8814087	0.32
679.5267334	0.24
680.4425659	0.54
681.1213989	0.36
689.1619873	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.0831
Annotation	Unknow
Peak:m/z	Relative Intensity
141.0535583	0.03
142.4002380	0.02
149.0231934	0.66
151.1370697	0.38
152.1197052	0.04
152.7659454	0.04
160.7640686	0.08
163.0817871	0.04
164.0118408	0.04
164.8731537	0.13
167.0069275	0.02
169.1837463	0.03
175.1575928	0.05
177.1199646	0.05
179.0642090	1.21
181.0974274	0.03
191.1145630	0.38
192.0256042	0.11
193.0030670	0.20
194.9037476	0.03
201.0342560	0.05
205.1057434	0.07
211.0382843	0.03
213.1044006	0.02
221.0536194	0.10
227.1407776	0.12
229.3254700	0.09
231.9969788	0.07
233.1972656	0.03
242.3461609	0.04
244.1938934	0.02
247.1365356	0.03
248.9732971	0.04
255.1765137	0.07
256.0439148	0.08
257.3064575	0.03
259.0580139	0.23
261.4166260	0.12
265.2999573	0.07
267.3333740	0.12
271.1186829	0.18
273.3120422	0.04
274.4923401	0.08
281.2823181	0.14
283.1097107	0.03
284.3061218	0.02
285.3361816	0.20
287.1997681	0.06
289.1696777	0.34
291.2641602	0.06
293.2064514	0.15
295.0940247	0.05
297.2839966	0.88
299.1552734	1.06
301.2216797	13.03
302.1619568	0.52
303.4080200	0.09
307.3069153	0.05
308.2834473	0.14
310.9147034	0.02
314.2410278	0.03
315.3325195	0.41
316.3716736	12.06
317.1086121	100.00
318.1163025	0.73
319.3258972	0.02
320.1861877	0.05
323.1497803	0.30
324.1889343	0.54
325.1586304	1.49
325.8630676	0.02
327.0024719	0.06
327.6358032	0.04
329.1339722	2.65
330.0193481	0.06
331.2045898	0.09
333.3193970	0.02
341.0514832	0.16
343.2987366	0.10
346.6983643	0.41
347.3273926	0.56
353.3638916	0.03
357.2921143	0.15
358.1593018	0.03
359.2324219	0.31
369.2400818	0.05
370.3235474	0.04
373.4253235	0.09
381.2871704	0.03
382.3984070	0.03
383.3406982	0.03
387.2460022	0.04
388.9916687	0.07
391.2467957	0.17
392.3833313	0.04
393.3499451	0.12
395.3125305	0.06
401.4159241	0.07
402.3967896	0.12
407.2689514	0.04
419.5818481	0.15
431.4695129	0.05
432.6080017	0.13
433.2455139	3.03
434.2436829	0.11
435.3232727	0.55
436.4964294	0.03
437.8802185	0.04
441.2705383	0.03
443.0904846	0.13
447.1105957	0.05
451.4304504	0.06
452.3317261	0.06
456.3565674	0.02
459.8489380	0.13
461.1974792	5.18
462.2989807	0.04
462.9168396	0.17
463.7966614	0.05
478.3060913	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
196.1041718	2.17
214.1176300	1.32
235.6296082	0.15
261.4747314	0.30
271.4506836	0.08
279.2882385	100.00
279.9504395	0.05
291.2120361	0.25
302.3771362	0.10
314.3564453	0.15
356.5655212	0.09
357.4527588	0.17
359.3153687	0.05
388.4849548	0.12
389.3676758	0.12
410.1261292	0.17
411.5229492	0.09
413.3840332	0.05
415.4089050	0.07
417.6458740	0.04
429.2361450	0.05
430.2909851	0.04
431.8064880	0.35
432.5083923	0.27
439.9566345	0.32
446.5351868	0.18
447.1521912	0.12
457.3802795	0.40
458.1807251	0.12
459.5364685	0.08
460.4983215	0.08
475.7166443	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0563
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.8970871	0.46
58.9964485	6.96
60.8810501	1.13
70.9088745	2.91
73.0259323	1.22
80.7747955	1.39
83.1133041	2.10
84.9359741	87.06
86.8980408	18.27
92.9745178	57.27
97.1444702	0.67
98.9177551	5.94
101.1316681	0.40
109.0270081	23.14
111.0009460	75.59
114.9752350	1.56
127.0218964	79.98
128.9319305	1.35
137.0666199	2.70
142.9791107	1.54
145.0287018	2.42
146.9996338	0.27
153.0256348	5.35
155.0682373	13.40
171.0856628	33.96
172.9697571	100.00
190.8840027	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.1406
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0356903	0.02
161.9337463	0.24
169.1975403	0.06
171.3348999	0.02
173.0314484	0.06
173.9560852	0.02
178.9832916	1.52
187.0795593	0.39
188.0129242	0.04
198.9883118	0.24
201.1123962	0.02
207.0075836	0.37
214.0902863	0.03
215.0757141	0.52
216.1511230	0.15
227.1418457	0.06
233.1207886	3.21
243.1093292	0.09
245.3979950	0.03
251.0651550	0.09
271.4445190	0.15
272.3389893	0.06
274.3799438	0.05
284.2688599	0.56
290.1528931	0.56
291.0819702	0.26
300.2248535	0.09
301.1819458	0.38
302.1870728	0.12
308.1908569	9.74
315.5573730	0.05
318.2453003	1.97
319.1741943	1.39
326.1984253	0.14
334.2244873	0.03
336.1190796	32.75
336.7648315	0.06
341.2624512	0.07
342.1785889	0.10
344.2183838	0.85
345.1803589	0.08
359.3058472	0.15
362.2364502	0.84
374.1346436	0.08
375.2329712	0.41
376.4279785	0.06
377.1239014	0.05
378.1314087	0.08
384.3845825	0.02
393.3114624	3.87
394.1250610	0.33
402.2210693	0.71
411.1630859	100.00
411.7767334	1.00
413.2626343	0.44
419.1734009	0.08
420.1920776	0.04
429.1680298	0.34
431.0463867	0.01
437.2628784	0.07
447.1899414	1.50
448.3009033	0.14
458.9112549	0.14
465.2708740	14.88
468.2216187	0.07
477.1643677	0.24
487.9156494	0.07
488.7553101	0.02
504.2290649	0.64
506.0848999	0.07
522.2075195	7.99
523.2805786	0.89
531.4371948	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1297
Annotation	Unknow
Peak:m/z	Relative Intensity
100.9266052	3.43
112.9304581	9.59
125.0847168	0.14
127.3362122	0.25
128.9072418	0.56
138.9322815	0.28
144.9785004	0.04
148.8158875	0.11
155.3024597	0.14
156.9313965	0.19
165.1358032	0.31
171.2861633	0.11
174.9954224	2.59
183.2241211	0.11
183.9154816	0.21
187.1820984	0.55
189.0910645	0.24
202.9677124	0.14
205.0093079	0.32
219.2389221	0.06
231.0800781	10.87
249.1609802	100.00
261.0353394	0.15
262.0144653	0.12
265.1618347	0.27
267.2779846	3.61
275.2095337	0.23
291.2141724	3.11
305.1755676	1.06
315.2747192	0.68
322.4443970	0.09
323.2171021	0.10
333.2658691	18.55
336.9863281	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.1403
Annotation	Unknow
Peak:m/z	Relative Intensity
226.9740295	0.20
261.2663574	0.04
267.1539001	2.31
277.2881470	0.18
297.2678223	0.06
301.3494263	0.07
310.1865845	0.12
311.4136353	0.13
323.0211182	0.08
327.2702637	0.06
341.0064087	0.25
353.3410034	0.18
354.1224976	0.06
355.0841675	0.17
359.3414917	0.27
361.2844238	0.12
370.5153809	0.11
377.0772705	0.16
384.3212280	0.14
385.3092651	6.02
391.1992798	0.26
399.2821045	1.77
400.3306885	0.11
403.2170410	100.00
403.9335938	0.44
427.2774048	0.22
430.7398682	0.24
433.4144897	0.18
443.3339844	0.09
444.2359619	0.12
445.2020264	1.59
449.3721313	0.33
452.7402954	0.22
457.2767944	0.42
459.0919800	0.09
464.9923096	0.06
466.3654785	0.11
475.0045776	0.11
478.0971680	0.10
479.5386963	0.18
480.3972778	0.09
482.9130859	0.20
492.8469849	0.06
495.1055298	0.14
504.9417725	0.30
511.1504517	0.07
512.8615112	0.04
517.1298828	0.14
518.2917480	4.95
519.2810669	2.10
520.7979736	0.30
521.4526978	0.12
534.4306030	0.55
535.4298706	0.07
536.2150269	0.05
543.4352417	0.24
546.2692261	0.44
547.2772827	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.08
Annotation	6-Hydroxydelphinidin 3-(6-malonylglucoside)
Peak:m/z	Relative Intensity
171.7728271	0.05
179.3531799	0.03
191.1399689	0.06
217.1490326	0.05
218.9432373	0.12
220.9606934	0.07
228.1055756	0.07
235.3283081	0.10
243.2705078	0.06
245.1526794	0.12
249.3023376	0.33
258.2642212	0.05
268.3166504	0.08
271.3190918	0.09
275.1599121	0.06
277.2445068	0.09
283.1146851	0.03
299.2862549	0.07
301.0043945	0.09
303.9891357	0.07
305.3930664	0.09
312.3004761	0.16
315.1891479	0.40
317.2726440	0.19
322.9143677	0.08
327.0498657	0.37
331.9694824	0.05
333.2672119	0.09
335.2827759	0.04
337.2077637	0.12
339.0508423	0.44
343.2598877	0.57
344.5205688	0.04
345.3662109	0.21
354.1535034	0.05
356.1251221	0.18
356.8085938	0.23
359.9798584	0.27
361.4362793	0.08
371.5609741	0.25
373.8005981	0.03
379.2816772	0.05
384.1860962	0.03
385.0119019	0.15
386.3212280	0.08
391.2562866	0.08
392.9878540	0.16
394.8629150	0.06
399.0924683	0.33
401.2954712	0.09
403.1567993	1.14
409.4025879	0.07
411.3609009	0.03
413.5086060	0.09
415.3517456	0.15
418.9368286	0.06
421.5172729	0.06
429.2003784	0.64
433.2831421	0.27
434.0936279	0.07
434.8892822	0.15
438.3922119	0.16
440.0580444	0.05
442.1180420	0.02
445.4231567	0.20
448.5387573	0.08
449.2085571	0.11
451.2858887	0.05
452.1049805	0.12
453.2716675	0.03
459.0485840	0.10
461.2057495	0.09
466.1510010	0.02
467.3938599	0.03
469.2108765	0.26
474.1644897	0.19
475.2282715	0.35
477.5781860	0.04
478.1820068	0.02
479.2329102	0.71
484.4308472	0.04
485.0446167	0.04
486.2247925	0.06
489.2240601	0.06
491.2760010	0.08
501.3148193	0.45
502.4533081	0.04
504.1390991	0.03
505.4204102	0.39
509.3684692	0.08
511.5483398	0.09
518.2762451	2.76
519.3139038	11.82
521.2188110	100.00
521.8856812	0.40
528.7045288	0.03
529.4489136	0.10
533.3862305	0.34
535.4715576	0.11
536.6377563	0.27
537.4306641	0.02
539.2684937	0.03
544.6041260	0.07
545.5105591	0.37
547.3104858	1.05
550.2327271	0.24
555.4940796	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.3325
Annotation	Sandorinic acid C
Peak:m/z	Relative Intensity
196.9905701	0.10
215.0097656	0.06
289.3926697	0.77
290.3378296	0.10
301.4064331	0.21
307.2270508	0.09
323.4623108	0.06
352.8064575	0.10
367.5516663	0.08
369.7298889	0.06
371.3913879	0.05
381.7751770	0.09
393.6831970	0.19
395.5889587	0.35
397.6251526	0.12
407.5798950	0.35
409.4981384	4.66
413.3018494	0.04
421.4194641	0.06
423.4846497	100.00
424.4960632	0.49
425.5924683	3.67
431.6864319	0.05
441.7176208	0.06
450.2648010	0.39
451.4465332	2.01
452.2258606	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.0775
Annotation	Unknow
Peak:m/z	Relative Intensity
123.1096344	0.02
124.9241104	1.41
134.6041260	0.04
147.0243835	0.05
148.0063782	0.03
157.1079559	0.04
162.8288269	0.10
164.0115662	0.04
173.0595703	0.03
175.2694092	0.03
177.0663452	0.19
189.0473938	0.08
191.1471252	0.26
193.2610779	0.06
203.1759949	0.02
203.9588623	0.07
205.0758667	0.06
212.9918365	0.02
215.3735809	0.02
217.1729736	0.47
218.0376892	0.04
219.1167603	0.21
226.8451080	0.15
228.1612244	0.09
233.2782898	0.25
233.9780884	0.02
235.2537537	0.05
243.1816406	0.04
247.2056885	0.70
249.1713867	0.09
257.1403809	0.50
258.7523193	0.11
261.3093567	0.06
262.8234558	0.06
269.2042542	0.11
271.1868286	0.25
272.8393860	0.16
274.3068542	0.09
277.3275452	0.06
281.1821289	0.09
283.2832642	0.10
285.2386475	0.17
287.2658997	0.36
289.1434937	0.19
295.2509155	0.19
297.1865234	0.02
300.0840149	100.00
301.0986633	22.72
302.1174927	0.15
307.1934509	7.65
311.2326660	0.31
313.1801147	3.72
315.1546021	14.98
317.1246338	0.07
323.1457520	0.12
325.1377869	0.50
327.4505310	0.14
329.3655396	0.24
331.1611328	0.03
337.4207153	0.04
342.1080017	0.07
343.1552429	5.19
344.1051331	0.03
347.3806152	0.12
349.1810303	0.03
353.4811401	0.03
354.6629028	0.16
355.2684631	2.66
365.1839600	0.15
367.1977234	0.09
369.2221069	0.04
371.2920227	0.07
373.1633911	1.66
379.2697144	0.04
385.2910156	0.11
387.1838074	0.04
389.3596802	0.24
390.2804871	0.03
391.4014587	0.16
397.2992859	0.16
405.1717834	0.11
415.2274475	1.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	777.3315
Annotation	Unknow
Peak:m/z	Relative Intensity
257.9934082	0.02
262.2176819	0.05
270.1229858	0.03
281.3061523	0.18
284.9324341	0.06
303.2284546	0.06
319.2937317	0.02
331.1242676	0.05
370.0306396	0.13
383.5361938	0.08
386.2318726	0.25
397.3293457	0.04
398.4757690	0.03
400.2650146	0.07
428.1898804	0.18
429.1384277	0.03
450.3015137	0.08
451.7836914	0.11
457.4228516	0.24
465.3600464	0.06
477.2084351	0.03
478.2335815	0.05
483.7746582	0.03
489.1284790	0.02
515.5148315	0.10
519.2851562	0.11
529.2457275	0.07
536.9177856	0.05
549.5504761	0.05
554.9863281	0.04
557.4522095	0.19
558.1615601	0.06
562.7731323	0.05
568.5158081	0.12
570.3494873	0.24
572.3909302	0.14
580.5892944	0.15
581.4918213	0.61
582.4662476	0.46
583.4633179	0.02
586.4551392	0.41
587.6896362	0.07
592.4154663	0.11
593.4170532	0.17
594.6627808	0.12
596.6610107	0.23
598.4751587	0.19
599.6213989	0.12
604.3575439	0.34
608.5095215	1.28
609.4270630	0.86
610.3352661	0.09
614.1246948	0.03
615.3430786	10.58
618.4907837	0.15
619.4553833	0.08
622.4104004	7.65
623.5774536	0.11
627.6326294	0.04
635.6418457	0.06
636.3312378	0.11
642.2399292	0.53
645.4089966	2.10
654.3712158	55.73
655.3793945	2.38
665.5223389	0.13
677.5755005	0.15
683.3589478	0.07
686.5029907	0.20
691.2340698	0.05
696.3967896	0.14
701.6322632	0.08
703.5719604	0.16
709.3894043	0.90
711.1469727	0.43
727.5202637	2.95
733.0612183	0.05
741.4176025	0.20
743.3875122	0.23
745.3902588	100.00
746.0962524	0.24
748.7207642	0.17
753.4857178	0.19
756.4412842	0.02
758.5747681	0.31
759.6071167	3.52
760.8412476	0.04
761.9547729	0.04
764.1093750	0.06
778.0444336	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0718
Annotation	Gerfelin
Peak:m/z	Relative Intensity
83.2126617	0.05
84.8009872	0.05
95.2322846	0.03
96.8272934	0.04
99.1585846	0.10
108.9881210	0.62
110.9988403	0.02
123.0613556	0.58
124.9901657	2.73
126.0359802	0.04
127.0714111	0.05
135.1329651	0.46
136.9925842	2.49
138.9745178	0.51
143.0354156	0.08
147.0325928	0.09
149.1455383	0.11
151.1184235	1.40
156.9766388	0.02
159.0695496	0.53
161.1095886	2.27
162.0399323	0.19
162.9916687	0.10
163.9573212	0.65
165.0549011	2.99
167.0211945	1.09
173.2575378	0.08
174.2356262	0.12
175.1329956	0.86
175.7998962	0.06
177.0753632	0.03
179.1237793	12.06
180.0717621	0.09
183.1500549	0.03
185.1763916	0.24
186.0516357	0.23
187.1113586	1.18
188.1428223	1.07
189.0038910	0.03
191.0752563	0.04
197.1148682	0.02
199.2968750	0.02
201.1644287	0.41
203.0684509	7.41
203.9402161	0.06
205.1518250	32.75
212.2018738	0.10
217.1745605	0.97
221.2767944	0.19
227.1716309	1.38
229.2372742	0.17
231.1018982	6.67
231.9660645	0.06
242.9172363	0.02
245.1234131	100.00
247.0910034	6.51
248.9082642	0.02
253.0750427	0.13
257.1954346	0.03
258.9741821	0.02
261.0529480	0.03
271.1466675	5.39
273.3397827	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.13
Annotation	Castamollissin
Peak:m/z	Relative Intensity
146.8459320	0.03
149.0586548	1.39
150.1639557	0.11
150.8744507	0.01
152.9461212	0.02
153.7146301	0.01
154.8780975	0.01
158.9906616	0.02
163.0225525	0.13
163.9623718	0.12
165.0657349	0.48
166.0146484	0.11
167.0571594	0.09
168.2420959	0.01
177.0662994	0.02
178.9456177	0.02
181.1876373	0.01
189.0967407	0.03
189.9924316	0.03
191.0063934	0.20
192.0573578	0.63
193.1184998	0.47
194.2263184	0.04
195.1453247	0.01
197.0086365	0.23
198.2247467	0.01
199.1677399	0.01
203.1794739	0.03
205.1369781	0.03
206.1534576	0.13
207.1364136	0.27
208.0062408	0.04
209.1016541	0.06
211.2955475	0.04
212.2619171	0.01
214.1568451	0.01
214.9920349	0.03
217.1245422	0.08
219.1358337	0.07
220.1069946	0.02
220.9528351	0.06
225.1101532	0.01
225.9641113	0.01
226.8851471	0.01
232.1117401	0.03
233.1259003	0.01
235.1765747	0.21
236.5717621	0.04
237.1881866	0.16
238.5466156	0.03
239.1940460	0.41
240.2308807	0.08
243.2091064	0.03
245.1979065	0.08
246.2389526	0.01
247.0428162	0.09
248.1691895	0.01
251.0823669	0.04
254.2369385	0.02
257.1591797	0.04
258.2124023	0.03
259.1035156	0.09
260.1171265	0.12
261.3198853	0.44
262.3191528	0.06
263.2306519	0.07
265.2085266	0.16
267.3021240	0.01
268.0664673	0.01
269.2050171	0.12
270.2266846	0.06
272.3118896	0.03
273.2094116	0.15
274.7098389	0.02
276.2838135	0.01
277.4653931	0.03
278.2328491	0.02
282.4127197	0.01
283.4700928	0.01
285.1375122	0.25
286.0401611	0.01
287.0956421	0.18
288.3880005	0.07
289.2764587	0.03
289.9155273	0.01
291.2080383	0.04
293.1740723	0.39
294.3520508	0.02
295.1636353	0.01
297.1489868	0.28
299.1635742	0.14
300.2503662	0.08
301.3771973	0.13
302.3464355	0.15
303.2716064	1.93
304.2725830	0.38
305.3255005	0.07
311.2832642	0.42
312.1824341	0.07
313.1987305	0.06
314.1417847	1.42
315.2408447	0.92
316.1075439	0.01
317.3325806	0.03
318.5590820	0.03
319.2503052	0.58
320.4381104	0.06
325.2368774	0.05
327.1513672	0.33
329.1748657	100.00
330.2035522	21.89
331.2042847	0.37
332.2536011	0.03
333.0422363	0.03
337.3303223	0.06
341.2902832	0.30
342.1810303	0.10
343.2354126	0.08
344.2747192	0.04
345.1955566	0.56
346.1503906	3.01
347.1722412	4.05
348.2020264	0.75
349.1182861	0.01
350.1429443	0.02
353.2771606	0.02
355.1569214	17.35
356.1683350	2.78
357.3400879	0.02
359.1795044	0.46
360.3182983	0.05
361.2706909	0.03
362.2998047	0.03
369.3562012	0.01
371.1230469	0.11
372.1393433	0.07
375.1466064	0.07
376.4251709	0.01
377.3319092	0.02
381.3609009	0.23
382.0814819	0.06
383.1846313	0.24
384.2009277	0.01
387.1188354	0.01
389.1896973	0.58
390.2562256	0.22
395.2302246	0.02
399.4078979	0.02
400.2745361	0.02
401.0983276	0.07
402.1898193	0.01
404.1759033	0.01
405.3481445	0.02
411.3925781	0.01
419.1922607	0.22
420.3132935	0.06
422.2723389	0.28
423.3131104	0.39
424.2671509	0.11
425.5571899	0.05
431.2006226	0.04
433.2567749	0.01
441.3638306	0.04
442.1300049	0.02
447.3970947	0.02
456.3623657	0.01
463.4061890	0.15
465.2634888	2.30
466.3471680	0.49
473.5516968	0.08
481.4456177	0.02
491.2219238	2.54
492.3271484	0.72
495.4775391	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.99
Annotation	8-Acetylcaespitol
Peak:m/z	Relative Intensity
173.1638184	1.17
174.2179413	0.30
175.0071411	0.10
218.8441925	0.15
256.9817200	1.36
257.9809265	1.01
259.0444641	1.00
298.9774170	0.05
301.0256042	0.03
302.8898010	3.71
303.5149536	0.03
308.9564819	0.23
321.3665466	0.05
333.2285461	0.07
335.2628174	0.07
385.1419067	0.99
386.7868652	100.00
387.5352173	0.29
425.0333557	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1198
Annotation	Castamollissin
Peak:m/z	Relative Intensity
137.9599304	0.09
148.0633850	0.08
160.9426117	0.02
163.8011322	0.03
165.0158691	0.13
167.0071106	0.06
174.0199738	0.02
176.9857025	0.09
188.9041901	0.07
191.0618896	0.03
196.9880981	0.04
204.0507812	0.01
215.0569763	0.02
217.3499298	0.03
221.2357483	0.04
225.2039185	0.02
231.0737915	0.11
233.0500793	0.02
244.0190125	0.02
245.3545380	0.03
247.0312805	0.03
255.2704163	0.21
257.2910461	0.15
258.8893433	0.06
259.5282593	0.05
260.4210205	0.06
261.1628723	0.05
262.8148499	0.01
264.2346497	0.03
270.1903381	0.47
270.9261475	0.08
272.2614136	0.04
274.1436462	0.03
275.2169495	0.13
277.3394165	0.07
278.1559448	0.04
279.2149353	0.02
281.3815308	0.04
284.1117249	0.09
285.1231384	1.06
286.0997620	0.07
287.2181396	0.28
293.1842346	0.02
297.3453979	0.03
298.3833008	0.08
299.2455444	0.20
301.2558899	0.06
303.3683777	0.21
311.2376099	0.05
312.6799927	0.06
313.3061523	0.11
314.2555847	0.82
315.2746277	0.06
316.1345520	0.04
317.1904907	0.08
325.3085632	0.15
327.1686401	1.72
328.2938843	12.51
329.1637573	100.00
330.3563843	0.88
331.2701111	2.93
338.9929199	0.08
341.1141357	0.45
343.2399597	3.38
344.4291992	0.03
345.1643372	0.17
347.0665894	0.05
351.2390137	0.03
353.1110229	0.12
355.4848938	0.18
356.1620483	0.06
357.1033325	0.26
366.2879639	0.09
367.1958618	0.02
368.1527405	0.02
368.8629761	0.10
371.3120422	1.59
371.9954224	0.03
373.2130127	0.17
379.2356873	0.03
381.4376831	0.05
383.3135986	0.62
395.3130188	0.17
397.3957825	0.04
399.0612793	0.15
400.6395569	0.03
401.2630310	1.24
405.1593933	0.04
410.9387512	0.01
413.2024231	0.40
419.1314697	0.02
423.4291687	0.15
425.2496033	0.10
428.8415833	0.02
431.1393738	0.29
442.4912415	0.01
445.6101685	0.07
447.3520508	0.04
455.4430237	0.20
458.2019958	0.05
459.2394714	0.77
463.2832642	0.18
473.3208923	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2287
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
149.0134583	0.04
152.0672913	0.02
159.0540771	0.02
175.2477112	0.03
185.2160339	0.01
195.3843994	0.01
200.3164062	0.01
210.1898041	0.01
217.2819672	0.02
220.6701355	0.01
222.5301056	0.03
233.0195160	0.01
234.6674042	0.03
250.8981018	0.01
261.5045166	0.02
263.3126221	0.01
293.2330017	0.02
295.0003357	0.01
298.2503052	0.01
303.0649414	0.02
305.3341675	0.02
312.2811279	0.01
313.2005615	0.03
315.3002930	0.47
316.5125427	0.01
327.3949280	0.01
329.5408325	0.01
330.2950439	0.03
331.3519897	0.08
332.2681274	0.05
345.0220642	0.01
348.3244934	0.03
359.3246155	0.01
361.0654907	0.01
362.0707397	0.01
373.4328918	0.02
374.2127380	0.03
403.6538696	0.03
407.1729431	0.05
408.3953552	0.02
445.5449524	0.01
447.2861633	100.00
448.3365784	3.68
450.3962097	0.07
461.5660400	0.01
463.3093567	0.02
464.1846924	0.01
467.3851929	0.02
475.4421082	0.06
476.3104553	0.05
479.3418579	0.02
493.2517700	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1667
Annotation	Verbasoside
Peak:m/z	Relative Intensity
131.0506592	0.06
133.0639343	0.03
143.0065613	0.02
146.7961121	0.03
149.0555878	1.29
160.9111481	0.33
163.1967010	0.03
167.0814209	0.02
177.1870117	0.02
179.1084747	0.04
185.2295837	0.02
189.1144714	0.07
191.1555176	0.27
196.9026184	0.03
209.2848206	0.04
217.1455078	0.02
220.7740784	0.49
233.0615082	0.02
237.2050781	0.04
239.0145416	0.11
242.1212769	0.03
247.1122437	0.04
249.1265869	0.01
249.7742004	0.04
251.0647888	0.32
253.4988403	0.02
259.1919556	0.03
262.4771423	0.01
263.2070007	0.08
269.2543945	0.04
270.5310059	0.01
271.2988892	0.02
272.2819824	0.01
273.4320374	0.03
281.0673523	0.08
283.1826477	0.06
285.4490967	0.08
287.4076538	0.02
293.2097168	0.37
294.2916260	0.05
295.0875854	0.02
297.0110168	0.08
298.1149902	0.18
299.2075195	2.28
301.2870178	0.06
309.2929688	0.04
310.6060791	0.25
311.2537537	1.29
312.2894287	0.01
313.2373047	0.15
314.0531616	0.15
315.0695801	0.01
316.4458313	0.04
322.3572388	0.04
325.4951477	0.03
326.1166687	0.02
327.2785950	0.77
328.2709656	9.37
329.2272644	27.08
330.3374023	0.32
331.2232971	1.00
333.1626587	0.02
335.3727112	0.02
336.3858032	0.01
337.1829834	0.01
338.3291016	0.03
339.2079163	0.09
341.1490173	1.50
341.7694702	0.03
343.2838745	1.12
345.4564819	0.05
347.3468018	0.01
348.4940796	0.01
353.3763733	0.03
355.2904053	0.02
357.1029358	0.04
359.4282532	0.01
365.0746155	0.02
369.5537415	0.06
371.3962402	0.87
375.1544495	0.01
381.3844604	0.05
382.4635925	0.01
383.3863525	0.39
385.5737610	0.01
386.5655823	0.01
393.6577759	0.01
395.4154968	0.09
399.1272278	0.07
400.0872498	0.05
401.2378235	0.72
402.6303406	0.03
413.4000854	0.09
415.2093506	100.00
415.8404541	0.20
417.1427917	0.04
419.1144104	0.05
425.3957214	0.03
429.2288208	0.25
431.3079529	0.04
432.1218567	0.03
433.3377991	0.08
442.2402039	0.07
443.1983032	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	513.1202
Annotation	Unknow
Peak:m/z	Relative Intensity
219.3340454	0.39
332.9843750	2.88
340.6663818	0.21
341.5466309	1.42
342.2203979	0.50
349.0942383	0.44
351.1279297	100.00
366.4354248	0.32
398.8443604	0.13
423.2089233	0.30
451.4248657	0.27
490.4680176	0.59
495.4030762	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.2532
Annotation	Unknow
Peak:m/z	Relative Intensity
171.1209717	0.50
188.8777618	0.13
193.1817017	0.36
207.1551208	3.59
224.8574524	0.92
286.1095276	0.11
290.9223633	0.12
301.1291504	100.00
301.8291626	0.94
345.3849487	0.22
348.7929688	0.34
386.9926758	3.85
404.9777832	0.12
406.5341187	0.53
408.5985718	0.44
417.2186890	0.23
428.2963867	0.39
438.6809082	0.27
442.2478638	0.28
463.1406250	1.10
467.2427979	0.55
469.1690063	0.12
471.3063965	0.27
475.8076172	0.78
490.6256714	0.11
503.3368530	0.34
505.1935425	2.82
513.0620728	0.23
530.6026001	1.72
531.4931030	1.32
533.1144409	0.22
540.8719482	0.17
549.3128662	0.24
550.2822266	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	769.1534
Annotation	Unknow
Peak:m/z	Relative Intensity
248.1792297	0.01
263.0829468	0.01
285.3306274	0.01
287.2183533	0.08
295.0732117	0.05
301.9516602	0.03
303.1854858	0.19
304.1867676	0.01
304.8883057	0.03
315.1156006	0.08
343.2119141	0.02
344.1159058	0.05
345.2226562	0.74
377.4785767	0.02
405.2780762	0.01
421.3120728	0.01
427.5192871	0.03
435.3278198	0.07
439.2639771	1.83
440.2752075	0.04
449.1738892	0.01
451.4452515	0.03
453.2250977	0.02
462.1138306	0.01
463.2481079	0.02
465.2877808	0.17
466.3386230	0.07
467.2796631	0.04
468.0269165	0.01
480.3802490	0.09
481.3937378	0.22
501.2202148	0.01
505.4215698	0.05
507.1459961	0.35
543.2614746	0.02
570.2468262	0.08
577.0835571	0.04
583.1748047	0.02
588.4776001	0.30
589.2457275	0.98
601.3102417	0.22
605.3422241	0.97
607.2358398	100.00
608.0890503	0.00
615.3118896	0.01
619.1259766	0.02
624.3892212	0.02
625.3842163	0.02
635.3950806	0.02
636.4442139	0.01
637.3509521	0.02
639.4794312	0.01
643.5231934	0.05
648.5100708	0.04
659.5466919	0.02
672.9916382	0.03
675.6137085	0.05
678.5526733	0.03
684.7725220	0.05
687.1371460	0.06
702.3983765	0.05
707.5261230	0.01
708.6968384	0.01
740.5239868	0.05
750.3750000	0.22
751.2572632	0.09
768.6904297	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.2346
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1574097	0.02
191.0903473	0.05
205.2509613	0.19
209.0768280	0.01
243.1120911	0.01
251.1337128	0.02
290.3424072	0.02
293.3235474	0.23
303.3005981	0.01
311.0027466	0.13
317.3178101	0.03
327.4502563	0.06
345.2124634	0.02
355.4442139	0.01
372.2666016	0.01
373.1867065	0.05
383.8117065	0.02
385.1112671	0.02
387.3776855	0.07
401.2304077	0.08
411.1381836	0.06
415.2122803	0.01
417.1438599	0.01
418.8925781	0.01
441.6629639	0.01
443.1386108	0.03
445.1478882	0.07
473.1999512	0.09
486.6749878	0.06
487.9035034	0.03
491.0383911	0.01
517.3329468	100.00
518.3915405	0.06
519.2700806	0.03
543.3275146	0.02
544.3165894	0.02
545.3592529	0.09
548.1252441	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.0482330	0.05
84.9818573	0.22
86.9922104	1.17
99.1595459	0.02
101.0170441	0.07
102.9161224	0.02
110.9443970	100.00
111.6891785	0.07
126.9622498	0.04
128.9944305	2.38
130.8845062	0.82
146.9949799	0.04
154.9644928	0.43
172.9933014	21.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.0721
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
108.8877869	0.19
120.9877777	0.80
122.8312988	0.07
136.9934692	6.22
138.0540466	0.11
138.8854675	0.21
152.0898743	0.05
153.0308228	0.29
165.0027161	100.00
172.9817810	0.08
182.1799316	1.90
183.0794373	9.71
197.0929871	24.51
205.3692627	0.03
247.0874023	0.07
256.2773743	0.03
265.2034912	0.05
271.7902222	0.03
276.0827942	0.12
291.2458191	0.07
301.1649780	0.02
303.1618652	0.16
305.2164917	0.13
316.3472900	0.06
317.0730896	0.13
319.1565857	12.67
320.5720520	0.07
329.0601807	0.06
330.1214294	0.14
334.2487488	0.09
341.2933655	0.09
343.4471741	0.02
345.1259460	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1945
Annotation	Unknow
Peak:m/z	Relative Intensity
242.1377869	0.22
243.1611328	1.76
245.1046448	2.23
246.0794983	0.09
246.8548431	0.19
257.3379517	0.13
258.9035645	0.08
261.1080017	0.83
262.2996216	0.11
269.2103577	0.66
270.2933960	0.43
271.2937927	0.10
273.1004333	0.68
273.9576111	0.08
275.1244202	0.20
277.1310425	0.07
279.4903870	0.12
281.3349915	0.19
283.0025024	0.32
284.2066345	0.35
285.0053711	0.68
287.1787720	15.90
289.0717163	7.14
289.8594360	0.62
291.3416748	0.14
297.1687622	0.12
299.1860657	3.62
300.2322388	0.14
301.2662964	0.55
303.2979126	0.09
305.0388184	0.14
309.4097900	0.19
315.1712646	0.12
317.1968079	0.11
321.4894409	0.09
323.3894958	0.28
326.9048462	0.31
328.0800171	0.07
329.1354675	1.22
331.2979736	0.41
337.2342224	1.13
338.0484619	0.10
339.2160339	0.15
341.1873169	0.94
355.3673706	0.10
356.6823120	0.29
361.1466675	0.24
363.2408142	4.51
364.3510132	0.65
367.3608704	0.44
369.5103149	0.15
371.3855591	0.18
377.3016968	0.35
378.9775085	1.26
380.7562256	0.39
381.4120789	0.73
382.7194214	0.82
383.4910278	0.21
384.2472534	0.08
385.3014526	0.06
387.1748047	0.34
388.5439453	0.13
389.2993774	0.17
391.3101501	0.28
392.3428955	0.11
395.2673340	3.96
396.2583008	0.39
399.0170288	0.15
405.1737671	8.84
406.0513916	0.71
407.2855225	32.76
408.1939087	4.44
409.2266235	0.59
410.1867065	0.15
411.3507080	0.66
413.1904297	11.75
414.3750000	0.38
417.2800903	0.76
418.1768799	0.14
421.5569458	0.16
423.1477661	5.09
425.2373047	27.22
426.2600708	2.65
431.6051025	0.05
433.4813843	0.46
435.2308960	2.12
436.4577026	0.36
437.2748413	0.27
439.3081665	0.80
447.2081299	1.05
449.2287598	18.41
450.3795166	3.66
451.2804565	24.59
452.3245850	3.64
453.2631836	1.54
454.2021484	0.68
460.4193115	0.12
461.1470337	0.58
465.3424683	0.99
466.2031860	0.61
467.3035278	2.44
468.1168213	0.48
472.3155518	0.13
473.1096802	0.13
475.4022217	0.15
476.5697632	0.09
479.2405396	0.65
487.9894409	0.23
489.4897461	0.36
493.2098389	0.44
495.9714355	0.55
499.4668579	0.24
501.3953247	0.22
507.1221924	0.23
510.9780273	0.10
515.2838745	0.91
517.3825073	0.48
518.2640381	0.09
519.3988037	0.32
520.2290039	0.23
525.2318115	3.09
526.3143311	0.27
529.4636230	0.12
530.4154663	0.20
531.2454834	1.58
532.2755127	0.46
533.2550659	7.99
534.3385010	0.91
535.1625366	1.06
536.0912476	0.37
539.4883423	0.18
543.1856079	18.04
544.1719360	1.74
546.4270630	0.19
551.5159302	0.30
557.2431641	7.79
558.5367432	1.90
559.2598877	8.43
560.3745117	3.26
561.2429810	5.96
562.3346558	1.68
563.2429199	0.16
568.4274292	0.35
569.3248291	8.21
570.4033813	1.15
572.0794067	0.20
573.3786621	1.50
575.2199097	37.17
576.1857910	4.22
577.2333984	61.18
578.2998657	6.15
579.2005615	0.35
580.3414917	0.86
582.5289917	0.09
584.2785034	0.60
585.2710571	0.21
586.2207031	0.97
587.2544556	31.21
588.4569702	5.84
592.4891357	0.12
597.2233276	0.51
600.3734741	0.34
601.4281616	1.10
605.1420288	0.31
607.3053589	0.17
608.1439209	0.15
611.5817261	0.11
612.3778687	0.26
613.3897705	0.82
616.3917847	1.24
617.4322510	0.69
618.4075317	0.11
619.2426147	3.16
620.2765503	0.87
627.2711792	0.35
629.4244385	1.38
630.3797607	0.60
643.3732910	0.49
651.5286255	0.35
653.4513550	0.17
658.5553589	0.13
659.3073120	0.47
661.4710083	0.14
669.3253784	2.71
670.2736206	0.42
671.5225220	0.12
676.8383179	0.41
677.4383545	8.03
678.3583374	1.00
685.4203491	0.20
695.2523804	100.00
696.2725220	18.33
697.2576904	1.50
698.3297729	0.26
700.9882812	0.23
703.3029785	1.44
704.4008179	0.67
709.9253540	0.34
711.3041992	0.15
713.2022095	62.82
714.2332153	6.38
714.8478394	0.08
715.6843262	0.15
719.7902222	0.39
720.5044556	0.85
721.3685303	2.87
722.3626099	0.19
723.6118774	0.35
725.4000854	0.19
730.2835083	0.36
732.2529907	0.83
733.3936157	1.65
734.3486938	0.22
735.4376831	0.06
737.2817383	1.86
739.2557373	68.74
740.3687134	10.03
742.3297119	0.10
743.7069702	0.15
755.1940308	1.93
756.3527222	0.24
762.2041626	0.20
763.3302612	0.06
764.2738647	0.29
767.1658325	0.23
775.4293823	0.33
780.1658325	0.49
780.8723755	0.73
785.4408569	0.23
789.7995605	0.73
803.6036987	0.42
804.6563721	0.18
805.6874390	0.08
821.2713013	2.01
822.3798218	0.33
828.9356079	0.14
830.2562866	0.44
832.2439575	0.11
847.2764282	27.92
848.2805786	6.93
851.3465576	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.2233
Annotation	11beta-Acetoxyobacunyl acetate
Peak:m/z	Relative Intensity
165.0611572	0.44
168.0441895	0.04
176.8844299	0.01
180.1732788	0.01
181.0541382	0.02
184.2402496	0.02
192.0493469	0.01
195.0369720	0.90
195.6863403	0.02
207.3687439	0.02
208.4067688	0.01
209.4122772	0.01
212.2711639	0.05
219.2932129	0.04
220.0578308	0.03
221.1732483	0.04
223.2084961	0.06
253.1738281	0.02
257.9301147	0.02
275.1039429	0.01
283.2182007	0.01
287.1387634	0.02
296.3501587	0.04
300.0862122	0.03
300.6946411	0.02
309.2563171	0.04
311.2754517	0.03
312.1004028	0.16
315.2069702	3.99
317.1764526	0.01
326.2820435	0.40
327.3203735	1.15
328.0962524	0.08
329.2808228	6.43
330.3479004	0.01
331.1843872	0.04
341.3057251	4.79
343.2368774	1.61
344.2977295	2.62
345.2906494	0.73
347.6325073	0.02
355.2613525	0.05
357.1522827	0.14
359.2510376	0.17
369.3977051	0.02
371.4249268	0.05
373.3139038	0.18
387.3952026	0.02
390.7108765	0.13
391.6831055	0.01
393.0077515	0.02
397.2212524	0.02
399.6577148	0.02
401.2136230	0.02
403.3712158	0.03
406.2841187	0.12
408.7014771	0.02
409.5093384	0.02
418.5100098	0.01
419.3782959	0.04
420.5140991	0.01
436.8615112	0.04
439.4476929	0.04
457.5350952	0.01
459.2522583	0.06
464.1234131	0.08
469.1879883	0.02
474.1605835	0.07
477.5155029	0.50
478.2617188	0.01
479.9011841	0.04
483.4751587	0.03
487.4137573	0.04
489.4118652	1.98
490.6553345	0.01
493.5132446	0.02
494.4949341	0.02
495.5497437	0.07
497.5612793	0.03
507.3193970	100.00
507.9913940	0.48
509.3604126	0.23
511.1494751	0.26
512.4366455	0.09
518.3002319	0.08
519.0536499	0.06
525.4020386	1.86
527.1807251	0.02
532.3210449	0.07
535.1887207	0.02
537.2194214	1.57
537.8367920	0.01
538.8881226	0.02
555.4610596	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
174.1228638	1.29
177.9567108	0.95
179.9966125	1.26
181.343338	0.43
182.3472137	0.43
194.3659363	0.78
195.0570831	0.71
207.081192	8.70
208.20961	3.69
221.2781982	0.51
222.1832886	12.10
223.1851349	10.50
233.2271118	0.39
251.0805664	100.00
252.3127289	4.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1401
Annotation	6-Caffeoylsucrose
Peak:m/z	Relative Intensity
161.0537109	1.10
162.1292725	0.22
171.8036652	0.04
179.0119629	9.24
180.0106659	1.59
203.0939026	0.75
221.2201843	0.11
233.3840485	0.04
251.2405396	0.26
261.2777710	0.03
267.9830627	0.05
281.3316650	0.11
289.9042969	0.02
294.9312134	0.04
303.0945740	0.03
305.1330566	0.07
319.6818237	0.11
321.0886841	0.04
322.1049194	0.07
323.3237305	0.22
324.2143555	0.08
338.9552917	0.07
341.1759033	100.00
342.2111511	20.78
349.2490845	0.08
354.2396851	0.06
365.3752136	0.38
366.2951965	0.08
371.2762146	0.05
373.3665771	0.12
383.2532349	0.21
385.5372314	0.04
395.0614319	0.05
395.8243713	0.05
409.3317261	0.10
410.1475220	0.05
413.2927856	0.24
425.7882385	0.07
443.3246155	0.24
443.9360046	0.09
450.1202393	0.10
457.9452820	0.04
460.5194397	0.19
467.2737732	0.07
468.3983765	0.06
475.0615845	0.16
483.2868042	0.10
485.3318176	0.15
486.3634949	0.12
487.3150024	0.04
489.8883667	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.114
Annotation	Lactulose
Peak:m/z	Relative Intensity
178.9804077	0.08
191.1222534	0.10
206.4718018	0.03
207.2102966	0.03
209.3276062	0.04
215.4885254	0.02
247.3911743	0.02
256.2174377	0.07
266.0837402	0.05
297.5720215	0.07
310.9266052	0.01
321.3108521	0.02
324.4086914	0.03
326.1914673	0.04
339.8291321	0.02
341.1967773	100.00
342.0054321	0.01
342.8413696	0.05
343.4944458	0.06
351.1454773	0.06
356.4762878	0.01
357.3867798	0.01
368.3750610	0.05
369.3025208	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.12
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0300293	0.17
161.9187469	0.15
162.6063232	0.03
165.0167999	0.51
166.8116150	0.05
171.0384827	0.12
181.2756348	0.06
182.3509827	0.05
189.1968536	0.10
190.5212708	0.29
191.1767120	0.20
191.9781189	0.04
193.0011444	0.77
194.1239014	0.28
195.1027527	0.33
201.7765808	0.05
203.0249939	0.05
207.0615692	0.19
209.3583221	0.21
220.6681824	0.12
221.3149567	0.13
229.0129395	0.10
233.8828125	0.05
240.2435913	0.04
240.9730682	0.09
247.1378174	0.05
249.2284241	6.66
251.3420410	0.14
261.1739197	0.48
262.1292114	0.17
266.3634338	0.05
267.3770752	0.05
269.2325745	0.34
271.9773254	0.04
273.1655579	0.10
281.0769653	0.05
283.7091064	0.05
293.2958679	0.07
294.3840332	0.02
299.3104248	0.06
303.1721191	0.29
304.1309204	0.40
305.1916504	0.04
307.6723633	0.08
311.0673828	0.44
312.3128662	0.10
314.1870728	0.65
315.1623535	0.65
316.2371826	0.38
319.2413940	0.15
320.4580688	0.14
321.3905640	0.08
329.2202148	7.58
330.2202148	9.78
331.2243042	4.35
332.2190552	0.03
333.7866821	0.12
335.3920898	0.09
342.5879517	0.10
343.2188110	0.16
344.1699829	0.45
345.3682861	0.04
346.5338745	0.40
347.1921387	9.84
348.2357178	21.10
349.2962646	2.60
354.3536987	0.37
355.2224121	0.08
356.9521484	0.06
358.2612915	0.28
359.1948242	0.13
360.0628052	0.06
362.4798584	0.05
365.4237671	0.12
371.4630737	1.44
372.3208008	0.61
373.3556519	0.75
374.3439941	2.17
375.2031250	0.15
376.4522705	0.47
377.2713013	0.42
381.3283081	0.04
389.2621460	0.09
390.2576294	0.11
391.3753662	7.68
397.2874756	5.77
398.3459473	11.55
399.2539673	0.97
401.2258911	0.42
402.2547607	0.22
404.2398682	0.03
405.1918945	0.16
406.5109253	0.12
420.4976196	0.26
425.1522217	0.07
433.0688477	0.41
433.6746826	0.02
444.2017822	0.36
447.2249146	0.08
449.0787964	0.03
450.0263062	0.12
462.4429932	0.08
463.1544189	0.06
464.7975464	0.10
465.4332275	0.15
467.6585693	0.03
468.3564453	0.12
476.2980957	0.04
486.9833374	0.23
489.2221680	0.04
491.2897339	0.04
492.4465332	0.03
493.5691528	0.11
506.2664795	100.00
507.3280640	6.15
508.5430908	0.40
509.2907104	0.17
510.4887085	0.10
516.9105835	0.13
523.4619751	0.35
529.4020996	0.51
530.1262817	0.13
533.8312378	0.26
534.4321899	0.91
535.2795410	0.47
537.1559448	0.10
538.3736572	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1455
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
173.1935425	0.02
177.2093506	0.02
179.0580597	1.69
180.0102692	0.23
183.0354004	0.06
184.1220093	0.04
185.1647034	0.01
187.0839844	0.06
188.9842224	0.19
190.7654266	0.34
193.0871277	0.43
195.3006744	0.05
196.9859619	0.01
197.9741669	0.04
199.1742706	0.07
200.8645935	0.20
203.2027893	0.18
205.2010651	0.03
207.2187958	0.12
211.1130676	0.18
211.9185944	0.05
213.1603241	0.20
214.5520935	0.13
215.1746826	0.10
217.0457458	0.35
217.8417664	0.01
219.1199951	0.02
221.2278442	0.03
223.5614624	0.02
224.5307007	0.02
226.4544830	0.16
227.1749420	0.25
228.3210297	0.04
229.1731873	0.46
230.0969238	0.19
231.0524292	0.06
231.6603699	0.02
233.0229187	0.02
237.3091125	0.05
239.3473358	0.05
240.1759033	0.09
241.1671143	0.07
242.2418671	0.09
243.1747437	0.39
244.1563721	0.02
245.1939087	0.23
247.2648926	0.03
248.1669464	0.02
252.0719299	0.05
253.5455780	0.10
255.0421295	3.05
256.1635132	0.61
257.1376343	0.31
258.2254944	0.05
259.1180725	0.01
264.2230530	0.03
266.1485596	0.04
266.8773804	0.03
269.9931030	0.04
271.1900024	4.37
272.1629639	0.96
273.2155762	1.75
274.2065430	0.13
275.2557373	0.07
277.3859253	0.01
281.2847595	0.13
283.1833496	0.39
284.2594604	0.04
285.1104736	0.06
295.0349731	0.03
297.1183472	0.86
298.5850220	0.13
300.0952148	29.75
301.1129761	100.00
302.2001953	13.83
303.4110413	0.03
310.0115356	0.03
311.1120605	0.12
313.1611633	0.50
314.1222534	0.06
315.0325928	0.30
316.0746460	0.03
317.0526123	0.02
319.1814575	0.03
323.0233765	0.06
324.0899048	0.01
325.1220703	0.47
326.1348267	0.10
326.9848633	0.05
331.1879883	0.11
337.3049316	0.05
338.3266602	0.02
343.1437378	8.17
344.1916504	1.49
345.1341553	0.02
347.9845581	0.01
353.3552856	0.07
355.1815186	0.19
356.1071167	0.04
367.2295532	0.08
368.3015747	0.02
373.1964722	0.80
374.1949463	0.28
385.3109741	0.10
397.2804565	0.01
401.4057007	0.02
403.2352905	0.03
409.3300171	0.09
410.1714478	0.04
413.3231201	0.04
419.5528564	0.01
420.4709473	0.02
421.3290405	0.03
427.2804565	0.24
428.3703613	0.06
429.4114990	0.01
437.1383667	0.03
445.3092041	0.06
446.3425903	0.02
447.0253906	0.10
448.2855225	0.10
456.5151367	0.14
457.1342163	0.11
457.9721680	0.08
458.9353027	0.02
461.2625732	0.02
463.3158569	0.61
464.2727661	0.06
465.3410034	0.46
466.4392090	0.07
473.3170166	0.02
474.0994263	0.06
481.5750122	0.04
483.3032227	0.22
487.1680908	0.01
499.4447632	0.09
500.3444214	0.08
506.3891602	0.06
519.2450562	0.04
524.1342163	0.05
531.4903564	0.03
549.0227661	0.14
550.3195801	0.10
563.1983643	0.09
565.3985596	0.17
567.4855957	0.02
573.1532593	0.06
591.3707275	1.18
592.4062500	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1023
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
159.0100098	0.01
180.1595154	0.00
209.1170654	0.01
214.0762329	0.05
230.9793091	0.05
249.3640747	0.03
258.0530701	0.01
303.1602783	100.00
304.0963745	10.93
304.7514648	0.00
313.0183716	0.01
315.3040771	0.09
327.1860352	0.20
328.0728760	0.04
329.1894531	0.01
340.5822754	0.05
343.0199585	0.01
345.1663208	2.37
346.2838745	0.55
347.6080933	0.01
353.4650269	0.01
354.2913818	0.03
363.2131958	0.02
369.1717529	0.26
370.0971069	0.03
372.5086060	0.03
381.3351440	0.05
385.3255615	0.02
389.2689819	0.06
392.2365112	0.03
393.2317505	0.03
394.1472778	0.01
399.1349487	0.06
400.2196045	0.01
405.4999390	0.01
411.1700439	0.49
412.1849365	0.12
417.6991577	0.01
429.4157715	0.07
430.2465210	0.02
431.7392578	0.02
439.1656494	0.01
447.3459473	0.17
448.1544189	0.02
448.9007568	0.03
453.0465698	0.03
454.2856445	0.02
455.0068359	0.01
455.9549561	0.01
465.1174927	0.15
469.4597168	0.02
470.1467896	0.01
471.2398071	0.08
486.2973022	0.02
487.3832397	0.03
489.1007080	0.29
489.9766235	0.02
491.3301392	0.05
493.6394043	0.03
495.6677246	0.03
501.7295532	0.03
513.3393555	0.02
515.1356812	0.87
516.1782227	0.14
519.7997437	0.01
521.1625366	0.01
522.2802734	0.02
532.1016235	0.05
533.2133179	4.05
534.3113403	1.02
537.6215210	0.03
551.2747803	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1663
Annotation	Diospyrososide
Peak:m/z	Relative Intensity
135.9899445	0.06
143.1225586	0.06
149.2153931	0.04
156.9960175	0.05
159.2676086	0.14
160.7570343	0.04
164.3251648	0.17
175.1944275	0.16
179.1141052	1.07
193.0310364	0.11
205.1945343	0.12
207.2167664	0.04
223.0074158	0.05
230.9347534	0.78
249.1063232	13.09
267.1350708	33.86
271.2156067	0.13
276.9071045	0.14
281.3555908	0.04
293.2247009	0.07
297.2327271	0.92
301.0385132	0.08
305.1418152	0.11
308.0285034	0.07
310.5929565	0.14
311.4400635	0.03
315.3371582	0.04
323.1201782	0.43
326.2884521	0.19
329.9817810	0.04
334.1082153	0.27
341.2637939	0.12
342.9727478	0.10
351.5123901	0.06
353.5137939	0.35
357.4677734	0.05
359.6273193	0.05
369.1651306	0.08
373.3249512	0.05
377.3735962	0.06
383.1532288	0.12
386.0875549	0.08
389.2033386	0.02
392.4457397	0.04
393.3708801	0.06
395.1928711	0.02
398.3838196	0.09
399.2923889	0.02
401.3302307	0.24
407.4949646	0.07
411.2998352	1.43
413.3404541	0.15
421.4820251	0.21
422.3078613	0.06
427.4296265	0.52
429.2791443	100.00
429.9360657	0.18
431.4590454	0.05
435.3118286	0.14
436.1542664	0.35
450.2795105	0.24
455.2911682	3.18
458.2834167	0.67
459.2425842	0.07
473.3617859	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.1068
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
177.1425018	0.03
185.1775360	0.01
193.4171600	0.01
213.0251770	0.02
214.9449463	0.03
271.0301208	0.02
275.4310913	0.04
285.1026001	0.03
287.1127014	100.00
290.6386414	0.03
301.0903931	0.07
307.2210693	0.04
315.2125854	0.02
321.4114990	0.04
325.2341919	0.23
331.2519531	0.52
332.2711792	0.02
337.3421021	0.02
343.0874634	0.29
351.5828247	0.03
354.3842773	0.06
359.3924561	0.02
361.2600098	0.03
367.1711426	0.09
371.3018188	0.13
372.2597046	0.05
373.2319946	0.45
376.2541504	0.01
377.5833740	0.02
381.6138916	0.01
385.4982910	0.07
386.7891235	0.06
392.4262085	0.03
397.4371948	0.02
400.5121460	0.01
403.4008789	0.02
407.3963013	0.01
412.8911133	0.02
419.2544556	0.20
426.4750977	0.02
432.2767334	0.05
433.3851929	0.01
449.2819214	2.40
454.0633545	0.30
465.2285156	0.06
467.5279541	0.05
469.4094849	0.16
471.6187744	0.02
475.4688110	0.02
476.9931030	0.05
481.1159058	0.04
486.3518677	0.07
487.2874146	0.04
491.2136841	3.15
492.8727417	0.07
493.7759399	0.07
499.3699341	0.08
501.3211060	0.03
505.4553833	0.12
506.3979492	0.03
507.2772217	0.12
508.0988159	0.04
516.5933228	0.31
517.2205811	0.94
525.5093384	0.07
526.3726196	0.02
528.9749146	0.11
535.5385132	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	747.2869
Annotation	Alangisesquin C
Peak:m/z	Relative Intensity
221.0184631	0.06
223.2267456	0.03
248.1555786	0.01
255.2063751	0.05
256.0314941	0.02
266.0512390	0.08
267.1043091	0.03
269.4678345	0.01
283.5136108	0.01
284.3331604	0.02
287.4645996	0.04
295.3447876	0.07
297.2321472	0.06
298.9560852	0.04
301.1818542	0.12
309.5620728	0.07
310.1806946	0.02
311.3445435	0.15
315.2567139	0.02
326.0350037	0.04
327.2358398	0.20
328.5616455	0.02
329.4292603	0.02
330.4700317	0.14
337.2848511	0.07
342.3441772	0.34
345.3067627	3.88
347.5588989	0.01
351.6058960	0.01
353.3362427	0.02
355.5524292	0.05
357.3044434	1.83
359.2839966	0.49
365.3758545	0.07
367.1571045	0.03
370.2203979	0.20
371.3227539	0.74
375.0944824	0.67
384.6708374	0.03
385.5020142	0.03
386.4041748	0.03
387.2362671	0.05
389.2212524	0.09
391.4169922	0.09
393.3717651	0.04
399.4161987	0.27
407.5333252	0.06
408.4861450	0.08
415.5440063	0.03
417.3096924	0.16
421.2841187	0.03
423.1138306	0.03
424.3019409	0.04
431.1899414	0.03
435.4179688	0.02
437.3011475	0.08
438.2301636	0.07
445.4035034	0.01
449.2451172	0.11
459.3242188	0.02
463.4618530	0.02
465.4100342	0.06
495.0126343	0.04
496.5504761	0.05
499.7574463	0.02
501.3837891	0.03
507.4617920	0.15
510.3732910	0.03
519.4248657	0.24
523.2595215	0.07
524.4146729	0.05
535.3156738	0.02
537.3341675	0.49
544.0013428	0.05
552.5893555	0.04
553.9266968	0.03
554.9017944	0.12
557.6045532	0.05
565.5660400	0.07
567.1569214	0.76
569.2697754	0.06
571.5300903	0.04
572.9153442	0.10
575.5047607	0.05
579.7226562	0.02
581.1122437	0.11
583.5299072	0.10
585.2914429	100.00
585.9854736	0.26
586.9722900	0.02
590.5475464	0.13
595.5438232	0.03
597.1270142	0.02
601.7450562	0.02
609.6470947	0.08
611.3659058	0.05
613.2935181	0.15
614.5353394	0.15
615.7716675	0.02
617.8593140	0.04
621.3223267	0.76
623.4751587	0.02
626.7677612	0.12
627.4129028	1.53
629.2980347	0.02
637.1295776	0.03
638.3735962	0.01
649.5314331	0.02
651.5306396	0.04
657.8690796	0.02
659.8154907	0.08
660.7911987	0.23
661.4334717	0.12
662.4317017	0.07
663.3908081	0.05
665.6848145	0.05
666.5925293	0.07
670.5622559	0.04
684.5778198	0.05
687.2940063	0.27
699.1935425	0.10
700.9408569	0.03
701.6917114	0.06
702.3433228	0.05
703.5631714	0.19
714.8287964	0.03
717.3634644	0.61
719.8850708	0.04
724.9193115	0.05
728.4390259	0.15
729.5032959	0.53
731.2299194	0.02
738.0923462	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.0861
Annotation	Melicitrin
Peak:m/z	Relative Intensity
135.0122223	0.12
149.3440857	0.12
151.1993866	0.25
153.0688171	0.55
177.4194336	0.16
186.9418030	0.12
200.7586060	0.34
218.1269531	0.27
225.3115997	0.32
235.0118408	0.39
241.3531799	0.40
243.1669617	0.32
244.0794373	0.21
271.2879639	0.54
272.2051392	0.66
286.9932861	0.39
289.5983887	0.22
294.9336548	0.15
301.3295593	0.35
303.1558838	0.28
308.8272705	0.21
313.1168213	0.11
315.3664856	0.90
319.1538696	46.34
320.1139526	100.00
329.1303406	6.83
330.0797119	8.07
331.2269897	0.64
332.2572632	1.30
343.1268616	3.85
344.1317444	4.09
352.4199829	0.14
354.3618774	0.13
355.6192017	0.47
359.5315552	0.11
360.5141907	0.21
361.4768372	0.99
362.1973267	1.56
370.5949402	0.26
373.2127075	2.65
374.2902832	3.63
380.3805847	0.14
385.1929016	3.97
386.1795654	3.56
387.1510315	0.16
397.2004089	0.85
398.3047791	5.06
407.3234558	0.33
408.6724243	0.22
411.0921326	0.20
415.4654236	1.73
416.2741394	5.24
433.2149658	3.40
434.1286926	10.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1089
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
135.0168457	0.08
166.9337769	0.08
171.3049316	0.13
177.2384033	0.55
178.1737976	0.05
187.0874023	0.24
189.2660522	0.09
193.0488739	26.50
197.0475159	0.31
201.8945465	0.12
203.3280334	0.16
207.3189545	0.08
221.1470642	0.41
237.2361145	0.09
249.2062988	0.11
256.2702332	0.10
269.2148438	0.27
274.1767273	0.23
276.9477234	0.06
310.5466003	0.17
313.0602112	0.11
315.2721863	0.21
317.3857117	0.16
341.2290344	0.37
355.1677551	100.00
357.0480957	1.03
365.5822144	0.09
373.2927246	0.15
377.1203918	0.24
383.0380554	0.40
386.2005615	0.06
392.8635864	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.13
Annotation	N2-(2-Carboxymethyl-2-hydroxysuccinoyl)arginine
Peak:m/z	Relative Intensity
112.0041580	0.74
113.0546875	0.01
113.9271698	0.12
114.8461761	0.15
115.9685287	0.94
117.5787659	0.03
121.0699615	0.05
128.9011536	0.10
130.0884094	1.30
133.1039734	0.09
136.4025726	0.05
139.0876923	0.10
140.1822052	0.02
144.0569153	0.01
144.8688812	0.02
146.0159912	0.03
147.0085907	0.05
151.0341949	0.02
152.0485992	0.03
154.7759705	0.03
156.9983215	2.41
158.1160278	2.32
162.7778015	0.05
175.0899658	100.00
175.8676605	0.02
180.2418823	0.04
186.6714935	0.06
203.1692963	0.04
204.3289337	0.02
207.6755524	0.06
213.9899902	0.07
215.3049011	0.04
217.1091309	0.09
228.9202271	0.04
232.2261963	0.04
233.1048889	0.06
234.9965210	0.03
243.1761780	0.03
249.1158447	0.02
250.3183289	0.83
251.3347778	0.41
252.1780090	0.17
253.2428589	0.29
254.0947266	0.79
257.0985413	0.05
259.0181885	10.33
259.8054199	0.02
265.5726929	0.01
267.0278931	0.02
267.7865906	0.05
271.0928345	0.28
276.1753540	0.08
277.0375366	0.03
289.2593994	0.29
301.3076172	0.03
302.1580811	0.03
303.1246948	0.26
304.1524658	0.07
305.0400391	0.06
314.1396790	0.25
315.2779541	0.07
316.8991089	0.05
319.1423950	0.27
321.1411133	0.14
330.2133789	0.20
331.1410522	1.20
332.0594177	0.13
333.0844116	0.09
339.3621216	0.07
340.1685181	0.35
354.8797913	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	646.8549
Annotation	Unknow
Peak:m/z	Relative Intensity
233.2768555	0.05
245.1035156	0.09
248.9564056	0.04
273.1558228	0.37
275.1911926	0.05
289.0051880	4.41
305.0778809	0.87
312.3364258	0.04
387.0880737	0.36
388.1256714	0.10
388.9367676	0.06
402.9921265	9.79
417.0617065	0.06
417.9030762	0.03
419.0650635	7.68
490.9158325	0.03
492.9745483	0.04
500.2485962	0.21
500.9957275	4.21
501.9215698	0.80
503.1677856	0.27
516.9848022	3.62
531.2245483	1.02
532.9064331	100.00
533.5154419	0.69
545.0482788	0.07
549.3356323	0.04
555.9158325	0.06
562.9526367	0.06
572.3168335	0.41
573.1115723	0.26
574.5210571	0.02
575.4448853	0.05
578.8972778	0.03
584.8513794	0.15
591.0737915	0.31
599.4692993	0.26
600.2940063	0.27
601.0542603	0.26
602.0795288	0.06
603.2050171	0.16
615.0350952	0.03
618.2628784	0.02
619.1486206	0.10
628.4608154	0.03
632.5520630	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1067
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
119.0388565	2.43
121.2095184	0.07
123.0071869	0.07
127.1157837	0.08
135.8943939	0.10
137.0614014	0.16
141.1763916	0.05
145.0088959	0.07
146.9467773	100.00
147.6759644	0.07
149.1274872	0.20
153.2091675	0.07
154.8806458	0.18
156.1269226	0.49
159.1877441	0.06
161.0623779	0.08
163.0674591	0.13
164.0547638	0.12
164.8772888	0.25
167.0119476	0.98
168.0605164	0.86
170.1665649	0.05
177.1547546	0.16
180.3554077	0.41
181.0261841	0.10
184.1370392	0.12
187.1868286	0.05
193.3073273	0.06
196.3539581	0.05
197.0543518	0.11
201.0176697	0.21
218.4929504	0.11
225.5032043	0.38
227.0952148	0.22
231.1260376	0.15
231.9894409	0.12
233.0162354	0.23
235.3890381	0.12
245.3684692	0.05
247.0656433	0.17
247.9811707	0.17
249.1270142	0.18
250.3563232	0.12
251.4107056	0.24
257.3257446	0.41
261.1425171	0.09
264.4553223	0.10
265.3225708	0.12
270.4108276	0.21
274.4705200	0.13
276.1240540	0.16
277.3183594	0.17
279.3443298	0.40
280.7969971	0.16
282.6519470	0.11
289.8665161	0.13
291.0726013	0.06
293.2232056	0.52
294.2153320	0.30
295.1247864	0.06
296.8786926	0.11
298.0058289	0.46
300.2534790	0.16
301.0859680	0.34
303.2966919	0.42
307.1282654	0.12
308.3199463	0.16
309.1900024	0.31
310.2799988	0.18
311.1261292	0.64
316.1701965	0.05
320.5841064	4.06
321.5532837	7.16
322.4284668	0.04
326.9954224	0.18
330.1083374	0.85
337.1648865	0.09
338.6003723	0.05
339.2718201	0.15
348.8691406	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0881
Annotation	Castamollissin
Peak:m/z	Relative Intensity
146.7559662	0.23
147.9014893	0.03
162.9750061	0.08
165.1742249	0.12
173.0502472	0.12
175.0502930	0.24
177.1109924	0.24
188.9830933	0.29
191.0757446	0.86
193.1430054	0.38
201.2739105	0.07
203.1573792	0.11
205.1086731	0.18
207.2779541	0.03
211.3762817	0.10
212.9786682	0.14
215.0536499	0.39
217.1643066	1.38
219.1817322	0.34
221.0675354	0.11
229.2123718	0.09
230.0584412	0.04
231.0661621	0.07
232.8824768	0.29
237.2351990	0.05
239.2621155	0.09
241.0328522	0.10
242.3750916	0.10
243.2170410	0.19
245.3258972	0.06
247.1840515	0.22
251.3381348	0.05
255.1076050	0.41
256.1968689	0.20
257.2102966	1.20
259.4127197	0.10
267.2542419	0.06
269.1657410	0.97
271.1777039	0.53
272.1416016	0.08
273.1047058	0.31
275.2696533	0.10
277.0518188	0.16
281.3178101	0.07
282.0663452	0.25
283.1338196	0.70
285.2656250	0.77
286.4199219	0.05
287.1031494	0.76
288.6677246	0.30
289.3677063	0.13
294.9818420	0.10
300.0992432	78.34
301.1083069	100.00
302.6216431	0.39
303.2694702	0.03
311.3185730	0.44
313.2706299	4.93
315.1327820	21.98
319.3778076	0.09
320.3498230	0.04
325.1793213	1.67
327.0954590	0.37
330.3471375	0.04
337.2546692	34.97
341.1451111	0.20
341.9468384	0.11
343.3090210	8.99
345.2416382	0.04
353.1046753	0.05
355.1574097	3.37
355.7580566	0.03
367.4197083	0.67
373.2263489	2.64
376.9692688	0.09
385.2966614	1.01
395.2197266	0.03
409.3363953	0.55
415.0440674	0.07
417.1282349	0.11
419.2536621	0.49
427.5457153	0.15
429.2919617	0.17
445.3166504	2.02
447.9934692	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.3378
Annotation	Clethric acid
Peak:m/z	Relative Intensity
160.9403687	0.57
167.1066742	0.10
179.0325470	0.20
180.0616608	0.07
199.2590179	0.09
220.9806671	0.43
241.2016296	0.06
253.3317261	0.11
299.0798950	0.18
341.2321167	0.10
347.3263550	0.13
359.2416382	0.21
369.2848206	0.32
371.9326172	0.11
375.4728699	0.14
384.3301086	0.10
387.4081421	1.54
393.6135559	0.42
397.3791199	0.12
403.3344421	0.23
405.2936707	0.19
407.5694275	0.21
409.3812561	0.20
411.4729309	0.49
412.7798157	0.18
413.6426086	0.19
419.3634949	0.31
421.5751953	1.61
422.4492493	0.20
423.5633850	0.30
425.6968384	0.07
427.5241394	0.08
436.4786072	0.08
437.3702087	0.20
439.4850159	2.30
441.5291443	3.32
443.4948120	4.10
445.2485962	0.37
448.5508728	0.11
449.7255249	0.53
457.0655823	0.84
457.9190369	0.15
459.5411072	8.61
465.4094238	0.10
467.4826965	0.66
468.3786011	0.09
469.6972046	0.04
473.5122681	0.57
483.4516296	0.25
485.4529114	100.00
486.4347839	0.25
494.3560181	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1325
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
76.9436264	0.03
78.9612656	0.03
82.9543838	0.30
91.0097351	0.05
92.9508667	0.12
96.9090042	0.05
100.9645844	0.04
102.9294434	0.06
104.8716278	0.03
106.9546509	0.15
109.0254669	0.28
111.0295868	0.46
119.0853424	0.16
121.0344391	1.94
122.9382477	0.26
124.9059906	0.10
126.8741608	0.18
130.9740601	0.04
133.1062164	0.41
135.0503235	1.22
137.0212555	0.49
139.0468903	0.11
141.0907440	0.11
143.0192108	0.12
145.1043091	1.18
147.0145111	1.42
149.0487366	1.76
150.0075531	0.57
151.1199341	0.26
153.0346375	0.46
157.0098114	0.38
159.1084442	1.34
160.0664673	0.79
161.1458588	0.64
162.9654083	2.64
165.0899811	0.08
167.1320343	0.09
169.2788696	0.23
170.0516205	0.15
171.0847626	0.12
173.1076508	1.87
174.1123199	0.06
175.0309601	0.28
177.3296051	0.06
178.2651825	0.07
179.3218842	0.02
183.1303101	3.33
185.1454926	2.03
187.1650543	17.92
189.1553192	1.18
191.1278839	16.21
193.0630798	0.24
196.0085602	0.10
201.1389465	13.95
202.0473633	0.06
203.2280731	4.19
205.0814362	3.00
207.1409149	0.04
211.0593109	6.57
213.2689667	0.02
214.0980988	0.03
215.1490631	0.07
217.2686310	0.05
219.1792450	2.58
220.9671631	0.02
223.8788910	0.02
229.1016388	100.00
230.3146515	0.04
233.2664948	0.07
238.0508423	0.14
239.3031616	0.07
248.0748291	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.0546
Annotation	Unknow
Peak:m/z	Relative Intensity
138.9978180	2.13
143.0453644	0.15
149.1109314	0.04
150.9092255	0.13
153.0916443	0.25
163.3032074	0.16
165.0251617	0.33
166.9770355	0.08
169.0586243	0.34
177.0238953	0.08
179.1136475	0.04
181.0040131	0.41
182.1929016	0.14
192.0247803	0.20
192.8879089	0.04
197.1243286	0.88
199.8097839	0.02
221.3969574	0.04
223.0039978	1.63
232.1473541	0.15
233.0885010	0.12
238.9495544	0.03
241.1174316	100.00
242.2421265	0.08
243.1440125	0.07
248.9387512	0.02
257.0859375	0.02
259.0607605	0.14
260.9974670	0.09
269.1710815	0.04
274.0809326	0.02
275.0597534	0.03
277.0596619	0.33
281.0328674	0.02
282.0546265	0.10
289.3169250	0.02
291.4255371	0.04
301.3519897	0.04
310.1340332	0.06
311.1459961	0.03
313.3255310	0.29
314.2498169	0.03
316.0895691	0.12
325.3263245	0.16
329.0660706	0.06
335.2506409	0.04
349.2867432	0.21
350.2918396	0.03
358.2900696	0.14
365.2653503	0.09
367.9029846	0.05
377.0802917	0.11
392.6424255	0.06
393.5451965	0.11
394.4637146	0.02
395.4064636	0.22
397.0623779	0.02
403.1375732	0.56
408.7514954	0.02
412.5011902	0.02
421.1813354	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1037
Annotation	Unknow
Peak:m/z	Relative Intensity
136.9837036	0.04
143.1969604	0.02
147.0555725	0.12
148.0895233	0.07
149.0392914	0.03
155.2033997	0.02
158.9975891	0.02
161.0393982	0.07
163.0867310	0.18
165.0814667	0.02
168.8129883	0.09
173.0707855	0.05
175.1021271	0.11
176.1388245	0.07
177.0870667	0.25
177.9091339	0.03
183.0603180	0.03
186.2002563	0.11
189.0873718	0.05
191.1017761	0.12
193.0643005	0.05
195.0890808	0.02
197.1368408	0.05
199.1714020	0.19
201.0830383	0.34
202.0508728	0.16
203.1145020	0.06
205.0820160	0.03
211.0869141	0.04
212.5976562	0.06
213.2644043	0.18
214.2010345	0.12
214.9840546	0.12
216.0535583	0.06
217.1989899	0.49
218.1906738	0.12
219.0884247	0.04
222.9347534	0.10
224.9268341	0.09
225.9661102	0.03
227.6974792	0.07
228.6875610	0.08
229.3244934	0.33
230.1679382	0.12
231.2138062	0.03
233.2637329	0.06
239.2404022	0.06
240.3757172	0.16
241.2232666	1.10
242.4643860	0.13
243.1505127	0.80
244.1407776	0.09
245.2032623	0.11
249.2361755	0.06
251.2327576	0.03
253.2411499	0.03
254.3768921	0.07
255.2934875	0.28
256.1949768	0.30
257.2203369	1.01
258.1235046	0.05
259.3253479	0.33
261.2748718	0.28
265.4599609	0.02
266.6265259	0.21
267.2883301	0.34
269.1726685	0.42
269.8904419	0.04
271.0368042	0.27
272.1322021	0.12
276.2247620	0.05
279.1683960	0.07
280.0758667	0.11
281.1929321	0.71
282.2019043	0.16
283.1472473	0.93
284.0864868	21.02
285.1101379	100.00
286.1863708	18.66
287.2732544	0.06
288.3113708	0.06
293.3793335	0.08
295.1228333	0.67
296.3159180	0.36
297.0938110	2.09
298.1860962	0.37
299.1589966	3.03
300.2054443	0.89
301.2546997	0.06
303.2541809	0.19
307.4842224	0.06
309.2388611	0.69
310.1924438	0.22
311.1494141	0.29
313.2038574	0.31
314.9208984	0.08
315.6928711	0.11
317.2189331	0.07
320.2576294	0.04
321.1448669	0.29
324.4530640	0.09
327.2547913	3.32
328.2176514	0.92
329.1683350	0.04
335.4865112	0.02
339.1854248	1.60
340.2301331	0.14
343.1632080	0.19
345.1898499	0.06
346.2554932	0.11
350.0511780	0.07
351.1269836	0.90
352.1618347	0.11
357.1313171	0.94
358.0351868	0.17
361.2565918	0.11
363.0979309	3.53
364.0924683	0.28
365.8782043	0.19
367.3322754	0.23
368.9950256	0.17
370.3506470	0.07
371.5070496	0.17
375.6079102	0.10
376.9837036	0.05
379.1669617	0.24
381.2974548	0.04
385.5899963	0.04
388.3436584	0.12
393.0271912	0.26
394.2126160	0.06
395.2229919	0.05
399.4020996	0.07
401.4410095	0.15
403.3080750	0.37
404.1104126	0.03
411.3100891	0.08
412.2771301	0.06
418.5458984	0.05
420.2303772	0.03
421.3590393	0.10
426.6109924	0.02
427.2883606	0.06
429.1657410	0.59
430.7915039	0.04
442.9504395	0.07
445.2276917	1.65
446.2687683	0.29
447.2520447	1.01
448.3039856	0.21
453.0289612	0.14
454.4853821	0.03
459.5906067	0.08
461.2507324	0.06
471.2532654	1.78
472.3069763	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.1284
Annotation	Melicitrin
Peak:m/z	Relative Intensity
153.0424194	0.08
165.0115356	0.36
167.1069031	0.17
180.9927673	0.33
191.1259460	0.08
209.0731201	8.67
221.3072815	0.06
234.9330902	0.06
247.2594299	0.10
249.1377563	0.10
253.2595825	0.06
255.4446716	0.08
271.0299072	0.16
274.9243469	0.06
289.2292786	0.45
290.0120850	0.22
291.2866211	0.22
291.9389038	0.06
305.1321106	0.12
317.1802368	2.69
331.5903320	0.06
333.1252136	1.86
335.0359192	100.00
335.6689758	0.16
341.3027039	0.13
343.0458984	0.14
347.3880615	0.08
353.3344116	0.16
359.0923462	0.93
366.2883301	0.12
367.9680481	0.08
376.0432739	0.25
377.1793823	0.64
381.2758179	0.08
383.2638245	0.23
391.6262512	0.11
396.2112732	0.18
400.5326843	0.05
401.1744080	1.35
404.0633850	0.10
406.7507324	0.54
407.4519043	0.04
412.1554871	0.14
415.1365051	0.07
423.7088013	0.12
425.1785278	0.10
432.2411499	0.22
432.9944153	0.11
443.3901978	0.25
450.5505981	0.08
451.3840027	0.12
452.4776611	0.08
453.2548523	0.17
454.1280823	0.14
461.1555481	1.26
467.0758972	0.26
470.1508484	0.16
473.1643677	0.17
478.4270325	1.50
479.2010193	9.69
479.8969421	0.13
482.8996277	0.10
488.0725403	0.26
497.2299500	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.1122
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
257.9988098	0.01
285.1478271	0.02
301.1888428	0.08
303.1223145	100.00
303.9530029	0.05
313.9569092	0.02
331.3007507	0.01
345.0993042	0.01
462.6975403	0.01
469.1960754	0.02
486.3129578	0.02
489.2138977	0.01
492.2902527	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0023
Annotation	SC-58125
Peak:m/z	Relative Intensity
129.0416870	0.06
131.1709442	0.05
155.0660858	0.16
172.9375610	1.30
191.0043945	100.00
201.1120605	0.04
212.9411926	0.28
233.1324158	0.05
240.2038879	0.03
240.9601440	0.07
246.3266907	0.06
254.8755188	0.29
268.2039795	0.05
269.9870911	0.03
273.1189270	0.81
285.0210876	0.06
286.2227783	0.04
288.7870483	0.16
298.9731445	0.81
300.2277222	0.06
303.1467285	0.08
304.2893677	0.08
315.3548584	0.12
316.4378662	0.35
317.0718384	3.40
332.2767639	0.05
341.4520264	0.04
356.8979492	0.09
359.1351318	0.99
374.7295837	0.15
385.0780334	0.70
392.3904114	0.09
403.1036072	6.77
406.0757446	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.0302
Annotation	3,5,8,3',4',5'-Hexahydroxyflavone
Peak:m/z	Relative Intensity
95.0353851	0.06
99.1106720	0.07
106.9720306	1.73
109.1555481	0.35
111.0536423	0.18
113.1090851	0.17
123.0962067	0.08
124.9160233	0.46
135.0283508	0.04
137.0204010	4.50
149.0335083	0.05
151.0455017	32.93
151.9628906	0.38
153.0387573	0.05
154.9970093	0.14
162.9982452	1.90
163.9923248	0.42
165.0801544	1.68
173.1855927	0.09
175.3366241	0.07
179.0280762	100.00
180.1222839	0.58
185.8698120	0.05
188.9463043	0.09
190.1723328	0.11
190.9902954	4.27
192.0518646	11.21
193.0599213	8.41
194.2319031	0.12
201.1135712	0.19
202.9996948	0.05
205.1091919	0.15
207.1725769	0.20
208.9136963	0.13
214.2945557	0.10
216.2319641	0.19
217.3023071	0.19
218.9988098	0.10
221.1401978	0.14
227.1221008	2.88
228.1834106	0.08
229.2127686	0.31
230.6835938	0.19
231.2852478	0.64
233.1736755	0.05
238.9861755	0.04
245.1256409	1.99
247.2092285	0.17
249.0809937	0.35
255.1715698	4.92
256.3370972	0.20
259.3694458	0.08
261.3046265	0.07
271.0429993	2.43
272.2243042	0.42
273.1163330	1.98
274.1672974	0.12
274.9729004	0.07
281.4611206	0.07
287.1990051	0.11
288.9736633	3.53
290.3759460	0.15
298.6080933	0.26
299.3108521	3.63
301.1715698	0.15
302.1597595	0.14
317.2341309	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.018
Annotation	Sulfoquinovose
Peak:m/z	Relative Intensity
71.0182495	0.18
73.0420685	0.12
78.8732452	1.02
80.9566269	4.32
86.8570404	0.58
94.9750366	0.11
96.8809204	5.79
99.0240021	0.14
100.9476318	6.08
113.0117035	1.88
114.9038239	0.25
122.9213562	10.58
124.9642487	4.58
126.9678345	0.17
131.1286926	0.11
134.8527527	0.34
141.0692749	0.33
143.0038300	4.31
145.1421967	2.05
151.0484467	0.24
152.9031677	61.89
161.0398407	0.09
165.0682220	1.75
168.2645874	0.09
177.1575317	0.61
183.0610809	100.00
189.1118317	0.19
194.9611969	0.30
201.2085114	0.05
207.0163727	39.59
208.5664520	0.27
213.0499725	2.07
225.1083832	14.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2334
Annotation	Dihydrobuddlenol B
Peak:m/z	Relative Intensity
178.9262695	0.22
180.0894928	0.63
181.0415649	0.35
182.3868103	0.11
183.1968689	0.05
193.0512390	0.07
194.0930939	0.05
195.2190552	0.24
196.1515198	0.09
208.1551208	0.79
209.2130280	1.45
210.1784058	0.41
211.1798248	0.07
223.1900635	3.54
224.1799927	2.14
225.1914368	0.22
237.2888794	0.03
252.9001770	0.05
255.9090424	0.08
263.6267395	0.03
283.3761597	0.04
293.3958130	0.06
294.4089355	0.13
298.2664490	0.06
301.0656128	0.10
306.1130371	0.04
310.2504272	0.04
311.1445312	0.45
312.3005371	0.13
313.3229370	0.32
314.4787903	0.24
315.1277466	0.03
316.2730713	0.08
317.3328247	0.10
325.2025757	0.37
326.3799438	1.85
327.3685303	1.87
328.3420410	1.19
329.2544556	0.12
330.2982178	1.00
331.2854614	1.31
332.5917969	0.11
339.0234375	0.08
340.3238525	0.25
341.4859009	0.19
342.2424316	1.66
343.3832397	1.59
345.2937012	68.71
346.3046265	100.00
347.2826538	15.06
348.3088989	0.47
349.2421875	0.03
353.6611328	0.02
356.2020874	1.14
357.3380737	29.53
358.2803345	43.75
359.3103638	26.88
360.2642212	37.54
361.3179321	5.55
362.4143677	0.99
363.4085693	0.11
368.2791748	0.09
369.1197510	0.02
371.2548828	21.72
372.2608643	42.16
373.2733765	5.31
375.2013550	7.26
376.1558228	11.15
377.2531738	2.12
385.2659912	0.03
389.3338623	0.69
390.2197876	1.75
391.0886841	0.15
395.1398926	0.04
400.1491699	0.05
403.4577026	0.10
404.2849121	0.19
405.3485718	0.32
406.1453857	0.04
407.3256836	0.13
411.2632446	0.11
415.3719482	0.04
423.1693115	0.08
424.1961060	0.06
424.8314209	0.07
434.2381592	0.07
435.3439331	0.04
443.3515625	0.08
446.8860474	0.03
448.9495239	0.05
451.2667847	0.13
461.2901001	0.07
463.3324585	0.16
464.6030273	0.08
467.4030151	0.09
472.2564697	0.09
488.9544678	0.04
493.5885620	0.03
496.4075928	0.17
498.4035034	0.02
500.0239868	0.11
501.2162476	0.06
503.3351440	0.02
511.3037720	0.08
514.2103882	0.02
517.6107178	0.13
519.5867310	0.11
525.2943726	0.11
526.2520142	0.16
527.5615234	0.07
536.5125732	0.05
539.0186157	0.08
539.6720581	0.04
541.1768799	0.28
542.1005249	0.25
543.3567505	0.49
550.1940918	0.11
554.4849854	0.06
555.4152222	0.31
556.3544922	8.02
557.3822632	1.78
558.3145142	0.62
559.4411011	0.27
565.1447754	0.09
566.5469360	0.06
567.5064087	0.29
568.2807007	4.46
569.2748413	2.34
571.3611450	0.23
572.3904419	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0496
Annotation	Bracteatin
Peak:m/z	Relative Intensity
92.9642944	1.11
106.9546661	0.23
109.0185699	1.75
110.8901596	5.37
111.9608002	0.05
117.1429977	0.17
121.0179291	3.58
121.8916016	0.19
122.9462433	0.32
127.1217194	0.21
128.9827576	0.19
133.1972198	0.14
135.0507507	0.12
136.9425964	15.56
138.0512390	1.06
138.9866943	0.80
143.1556702	0.23
144.9893799	0.31
146.9944763	0.40
148.9485779	6.70
150.0853577	1.49
151.0729980	0.21
152.9970398	11.03
153.9893494	0.32
158.9690857	0.27
160.9789581	3.20
161.8857727	0.11
162.9955750	4.94
164.9558563	53.72
166.0236816	5.94
167.1006775	0.67
171.0742493	0.09
173.1205139	0.62
174.9697876	0.67
177.0244141	3.32
179.0957947	0.22
183.0615845	1.06
184.2854309	0.32
185.1009674	0.28
186.1219788	0.49
187.0052185	1.32
188.2033386	0.27
188.9109955	0.43
189.9554291	0.25
190.9808960	1.80
193.0178833	1.65
193.9535065	0.35
195.1050415	6.23
196.0531311	0.25
198.9044189	0.33
201.0702209	4.52
202.0094910	0.68
204.3486328	0.43
205.1699219	2.99
206.0435486	0.23
207.1954956	0.40
210.9341125	0.69
213.1322327	5.22
214.1863403	1.01
215.0287170	2.39
217.0787964	0.44
219.1408386	5.60
221.0091858	0.13
222.9887085	0.48
224.1505127	0.37
229.1153564	65.10
230.1163940	5.89
231.4082336	0.06
233.0045776	0.84
239.1618652	2.24
241.1218872	1.91
242.0387573	0.14
243.0383911	0.25
247.0467834	30.39
248.1670837	2.63
257.1054993	100.00
258.0639648	10.38
258.9333496	0.09
261.1174316	1.20
267.1958618	0.52
273.0194702	0.12
274.0907898	12.47
275.2115479	14.99
276.2294922	1.11
279.2844849	0.08
285.0709229	56.21
286.1447449	8.76
287.1489563	0.18
303.1818848	33.68
304.0735474	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.0755
Annotation	5,7,2',3'-Tetrahydroxy-8,6'-dimethoxyflavone
Peak:m/z	Relative Intensity
92.2490768	0.33
106.9974365	0.30
109.0362091	0.63
109.9173279	0.48
110.8071899	0.55
111.4835358	0.36
113.1652985	0.08
120.8220520	0.22
123.0413208	1.06
124.9975586	0.30
132.8329773	0.59
135.4016571	0.17
136.7820129	1.14
138.1388245	1.95
138.9757996	16.35
140.0304260	0.50
140.8434906	0.07
147.8023987	0.11
148.9719543	0.29
149.7704163	0.29
150.9573364	0.46
152.9507294	76.03
154.0460815	2.07
155.0500183	0.54
159.4711304	0.10
163.1362457	0.09
164.4207764	1.39
165.0826721	24.55
166.1506500	0.21
167.2681885	0.25
174.9484406	0.38
177.8590851	0.27
179.2210388	0.37
181.1001129	9.40
183.4280396	0.11
185.2051239	0.09
189.0033569	0.17
192.2716522	0.41
193.0393372	0.31
194.2226715	0.09
197.0370483	0.19
199.0873413	0.17
201.8676300	0.05
204.8627472	0.07
206.0612488	0.48
207.1548462	7.03
207.9619751	0.58
215.1556702	0.25
221.0307922	0.05
225.0324707	0.56
226.8768921	0.10
229.6582031	0.36
231.2063904	1.20
232.3149414	0.30
234.9130249	0.05
241.0468445	0.69
242.1133728	0.37
243.2903748	0.06
245.1516724	1.44
246.9087830	0.72
248.6217651	0.29
249.3132019	0.67
252.1166077	0.06
253.0119019	0.18
254.0985107	0.22
255.2339478	2.72
256.2033997	0.54
257.1509094	0.20
257.9061890	0.73
259.1730347	3.67
261.1906738	0.20
263.1689148	1.39
265.3414307	0.34
269.1115417	4.42
269.9372559	0.07
271.0106812	0.86
272.0036621	0.27
273.2120361	0.72
274.3594971	0.19
276.7257080	0.18
280.2701721	0.26
283.0972290	3.78
284.0795288	0.63
285.4781799	1.36
286.1307678	7.94
287.1511841	77.42
288.1073608	3.22
291.1552734	100.00
292.1629639	4.79
296.1366577	0.19
297.1835327	1.72
300.0878906	0.47
301.1245728	1.19
302.2855530	0.16
303.2205200	1.65
304.2041931	0.62
305.1988220	0.09
309.7875366	0.09
313.0403442	0.28
314.2111206	13.27
315.0956421	41.18
316.2102051	2.65
317.5337524	1.39
318.1618652	9.51
319.1766968	6.42
320.2786865	0.59
325.3899231	0.10
327.7475891	0.67
328.4585571	1.45
329.1967468	4.28
329.9486389	0.14
331.0591431	2.55
332.1000366	44.41
333.2201538	1.78
338.0623779	1.02
345.2478333	0.24
346.1491089	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.1455
Annotation	Cistanoside F
Peak:m/z	Relative Intensity
144.9619751	0.08
152.8843689	0.06
156.8948975	0.17
160.9989624	3.27
163.1511536	0.06
177.9417877	0.31
178.9172668	0.05
193.0096130	100.00
203.1673279	0.04
213.2173004	0.06
221.2693176	0.02
236.2052002	0.08
241.1617279	0.03
249.2676086	0.45
255.1310425	0.07
261.1321716	0.03
269.0210876	0.07
278.4857483	0.03
279.1773987	0.18
287.3066711	0.41
291.2625732	0.05
294.9559326	0.07
307.2507629	0.76
316.4999084	0.05
317.2185059	0.09
319.0120544	0.07
323.1215515	0.03
324.0510864	0.30
325.4511719	0.05
329.2359924	0.03
333.3861694	0.11
347.2789612	0.06
355.2861633	0.36
368.1725159	0.13
372.1436462	0.08
377.0943604	0.05
385.5278015	0.03
387.4812317	0.03
391.2943115	0.07
398.2651672	0.06
399.4917297	0.05
410.2208557	0.10
414.4198303	0.05
415.6123352	0.21
425.2637634	0.25
427.1535950	0.09
432.3027344	0.07
440.2685852	0.36
441.2009583	1.17
442.3065491	0.53
443.4309387	0.48
449.6033936	0.14
451.2601318	2.03
453.1762390	0.11
454.4351196	0.04
457.2911072	0.07
459.1518250	0.05
467.4027710	0.16
469.2887878	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.1733
Annotation	Unknow
Peak:m/z	Relative Intensity
245.2073517	0.02
302.3446655	0.11
303.3220825	0.04
304.3347168	0.07
317.1124573	0.11
329.1676636	0.10
333.2096252	0.16
359.3880005	0.25
361.2770996	0.08
366.9597168	0.07
407.0635986	0.05
439.2397461	0.09
453.3027344	1.58
459.0258179	0.02
462.9167480	0.03
464.9727783	0.13
467.3253784	0.22
469.2427368	0.17
472.3046265	0.04
493.0711060	0.06
495.5144043	0.02
520.2091064	0.09
521.2163696	0.08
536.1846924	0.06
541.2382202	0.11
575.3242188	0.09
577.4885864	0.03
585.0802612	0.08
593.4962158	0.03
595.4149780	0.02
602.3538818	0.21
603.2501221	0.77
607.6068726	0.06
611.5020142	0.06
614.3075562	0.04
615.3310547	0.07
619.2964478	1.74
621.2020874	100.00
621.8399048	0.42
629.1394653	0.07
630.0358276	0.10
636.5681152	0.08
650.2412109	0.23
651.2838745	0.10
652.5294189	0.15
669.2031250	0.02
681.4208984	0.04
683.7405396	0.12
698.4723511	0.13
701.1681519	0.03
703.3233032	0.07
707.4473267	0.12
719.3442993	0.07
731.5891724	0.03
739.3118286	0.28
748.0775757	0.04
764.2405396	0.18
765.3655396	0.27
769.0630493	0.06
791.6699829	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.15
Annotation	Barlerin
Peak:m/z	Relative Intensity
129.1042480	0.07
135.0459137	0.17
139.2172852	0.07
153.1544189	5.09
157.0952148	0.40
161.0618744	0.06
162.9857788	0.03
175.1267395	0.77
179.0233612	0.09
183.0081482	0.08
187.1982422	0.27
189.0149536	0.14
196.9906006	0.86
205.0429535	1.05
207.2628632	0.14
219.2167053	0.09
223.4105835	0.28
231.0949402	3.18
243.2023926	0.05
249.1251831	37.83
267.1499634	37.25
271.2653503	2.94
279.5481567	0.03
283.9371948	0.14
285.1244507	0.71
295.0597534	0.08
297.1495667	0.16
299.3359070	0.04
313.2207031	0.29
314.2987671	0.27
315.1723633	0.73
327.4056396	0.06
341.3074951	0.04
343.1978760	0.17
349.1727905	0.27
350.2838135	0.24
359.3893433	0.34
367.1335754	0.31
385.3092957	5.91
387.3770142	0.31
401.3078918	0.04
403.2815552	100.00
403.9294128	0.10
405.1314697	0.08
411.1850891	0.04
419.3619080	0.55
426.1990967	0.07
428.6063538	0.13
429.2644958	7.25
432.0839844	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.1
Annotation	Unknow
Peak:m/z	Relative Intensity
126.6971741	0.06
138.9204712	0.16
152.9768066	1.22
164.9937286	0.34
187.0307922	0.20
193.1107178	0.06
195.1132355	1.06
200.9509888	0.09
209.0693665	0.17
223.2459869	0.05
229.1111755	1.30
237.1937866	0.62
241.0865173	3.67
243.0003967	0.21
247.0078430	0.06
259.1488037	0.77
266.9629517	0.29
270.9929504	0.24
272.8951416	0.22
274.7786865	0.41
285.0056458	0.26
287.0907593	31.01
288.1285400	79.77
289.0861511	75.86
290.1048584	100.00
291.1677551	13.52
294.9956055	0.13
303.1944580	0.90
308.9324646	0.46
318.1958313	0.27
319.1379395	0.72
321.1343384	63.29
331.2514648	0.17
338.1509705	0.14
345.1244507	1.87
349.0946960	0.20
357.3278809	0.17
362.4813843	0.23
363.1743469	1.03
368.9682007	0.64
371.2392883	0.34
373.6307678	0.13
375.1794434	0.20
381.1457825	0.25
387.0957336	7.70
399.0686951	2.32
407.0440979	0.27
417.2103577	4.58
417.8169250	0.29
434.6031799	1.26
435.2558289	48.92
437.4330750	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2786
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.9622192	0.17
155.1575775	0.10
196.0028687	1.57
213.0966492	0.12
214.0456238	1.43
245.2014160	0.11
255.2897949	100.00
283.3300171	0.11
284.3297119	0.35
285.1167603	0.07
299.3438721	0.05
302.2181091	0.41
325.3502197	0.47
391.4400330	0.40
392.5344543	0.18
406.8060913	0.15
407.6402588	0.16
408.5660706	0.28
433.9223328	0.49
434.9310608	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	414.0441
Annotation	Unknow
Peak:m/z	Relative Intensity
119.5956802	0.06
132.9533234	0.06
188.8488159	0.19
191.2570038	0.07
201.1342773	0.04
234.1303711	0.20
241.4269714	0.21
242.9503479	0.27
248.9016418	0.15
250.9696350	0.13
253.0321350	0.08
258.1898499	0.15
263.3726501	0.06
265.1188660	0.08
276.1745300	0.13
288.0458679	0.25
294.0608521	14.06
295.8085022	0.05
297.3756104	0.54
301.1869507	0.55
305.9118042	1.66
306.9229736	0.18
311.3598022	0.10
318.1778564	0.61
324.0913391	100.00
325.1105347	0.85
327.3694153	0.10
330.0230713	0.18
341.5748901	0.10
343.4090576	0.07
351.1072388	0.21
352.2270508	0.05
354.0779114	0.51
355.4159546	0.09
357.6864319	0.05
360.0281067	0.06
366.0946960	1.17
367.2150879	0.17
369.6414490	0.20
372.3048401	0.08
377.8795471	0.76
384.0554504	0.12
385.1730042	0.21
394.7462463	0.14
395.9294434	12.25
396.5633545	0.17
397.5838928	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	777.3314
Annotation	Patellamide D
Peak:m/z	Relative Intensity
285.2511902	0.04
301.2868042	0.08
331.1687622	0.06
335.3569336	0.06
359.4475708	0.05
371.5831909	0.03
385.5806274	0.04
400.2158813	0.03
435.2209473	0.04
442.3967896	0.07
450.3483276	0.15
465.2637939	0.14
466.2529297	0.07
487.1417236	0.13
508.4172363	0.12
515.5755615	0.05
535.0053711	0.10
567.6136475	0.06
568.2379150	0.06
574.9099731	0.04
580.4334106	0.13
581.2519531	0.07
582.4550781	0.65
583.5952759	0.22
584.5726929	0.04
586.2610474	0.25
589.3945923	0.13
594.1506958	0.07
594.8150024	0.04
600.4322510	0.12
602.2571411	0.07
604.4905396	0.07
605.3281860	0.05
606.3320923	0.09
607.3670654	0.04
608.5330200	0.34
609.3838501	0.46
610.3325806	0.23
611.3716431	0.09
615.3685913	0.27
616.1104126	0.52
618.5950317	0.15
622.3671265	4.67
623.3001709	1.18
623.9426880	0.04
624.5531616	0.07
625.5629272	0.04
631.3483276	0.11
633.2293701	0.05
634.2825317	0.26
636.7392578	0.45
642.2473755	1.25
643.3165283	0.22
644.6609497	0.16
645.5038452	0.23
646.2672119	0.23
648.3632202	0.06
654.3923340	60.56
655.3817749	17.09
656.2146606	0.15
656.8478394	0.11
659.4071655	0.05
661.4516602	0.04
667.1600342	0.05
677.4075928	0.06
680.5984497	0.07
687.6303101	0.25
688.3314819	0.03
701.5703735	0.35
703.4413452	0.19
704.3783569	0.04
705.5495605	0.10
706.2282715	0.14
708.8521729	0.10
709.7245483	0.27
710.5271606	0.31
719.3655396	0.09
727.3417969	1.77
728.5734253	0.64
735.5012207	0.06
741.4921265	0.18
742.3776245	0.23
743.3450317	0.07
745.4379272	100.00
746.4310913	33.01
747.0885010	0.07
748.3757935	0.10
753.5792236	0.04
758.6481323	0.08
759.6036987	0.59
760.5934448	0.60
777.7857666	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1022
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
134.9663696	0.09
146.5083618	0.07
151.2108307	0.06
171.2754364	0.06
183.1933594	0.14
216.8424835	0.10
219.0960846	0.31
223.3032837	0.05
227.2221069	0.21
231.7261963	0.08
232.9988708	0.05
255.2864075	0.12
267.2682800	0.25
283.2644958	0.06
287.1921997	0.42
293.1000061	0.06
295.4487915	0.11
299.0484619	0.12
301.2067566	0.72
303.1016235	100.00
311.0682678	0.11
313.1355286	0.27
319.3357544	0.35
320.3159790	0.13
328.3405151	0.05
331.2509460	4.16
332.4315186	12.88
333.1830139	66.51
339.1705322	0.14
343.2833252	0.26
345.1745911	0.18
347.0318909	0.17
348.3401489	0.10
350.4906616	0.08
363.0495605	0.71
366.3400269	0.10
369.2955933	0.67
375.2566528	0.29
381.2234497	0.04
381.8250427	0.22
387.1895447	0.12
389.0873108	0.15
393.3665466	0.04
399.1983643	0.46
401.1197815	0.14
406.2944336	0.09
411.2703552	0.26
414.8855896	0.11
419.1530762	0.18
420.4957581	0.10
423.4356689	0.12
424.5818787	0.30
429.2862244	1.74
429.9250488	0.09
430.6000977	0.05
433.2017212	0.47
435.2273254	0.29
446.5795898	0.88
447.3002319	1.96
448.3044739	0.41
450.3179626	0.16
451.4407654	0.07
456.2009583	0.35
465.4508362	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
109.0871582	0.02
111.0440521	0.04
132.4222717	0.06
133.0549011	0.38
135.0034485	5.54
160.9955750	16.92
164.0043488	0.03
165.0838928	0.02
175.1789856	0.07
176.5061493	0.08
177.1784058	0.02
179.0094604	100.00
189.1075592	0.19
198.9419250	0.02
203.0855255	4.63
207.3031006	0.04
217.0265198	0.03
219.1746216	0.08
220.1221313	0.04
221.0460510	0.30
231.1067810	0.02
233.1538086	0.37
245.1440430	0.08
247.0621643	0.05
251.1731873	1.37
259.3722229	0.04
261.2963257	0.15
263.6610413	0.17
267.2254333	0.02
278.0730896	0.03
281.2550049	2.82
282.2815552	0.05
293.3354797	0.01
295.2826538	0.03
297.2235718	0.05
305.1793823	0.03
313.1221924	0.13
319.8442993	0.05
323.2734985	0.17
324.4337769	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2242
Annotation	Citbismine C
Peak:m/z	Relative Intensity
221.0657043	0.03
263.1948547	0.11
289.5249634	0.01
312.1548462	0.01
339.3762207	0.09
341.1920776	100.00
342.1021729	0.09
534.7781982	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.24
Annotation	Patrinoside
Peak:m/z	Relative Intensity
149.0351257	1.45
163.1489868	0.58
167.2484741	0.62
178.9845886	0.36
191.0584869	1.03
205.2386475	0.10
208.8162842	0.16
209.4462585	0.03
219.0691833	0.04
220.5209351	0.17
221.1434937	0.24
233.1858368	0.71
234.8135986	0.06
239.1526947	0.15
245.4312897	0.07
262.8965759	0.06
264.9244385	0.27
275.0520935	0.53
279.2193604	0.07
280.9818420	0.16
285.0903320	0.06
289.6639709	0.10
293.1274719	23.17
298.9091492	0.35
301.2333069	0.08
311.0765991	1.95
317.0940552	0.05
324.7070618	0.16
325.4598999	0.27
327.1734619	0.05
333.1346436	0.04
339.2260132	7.03
340.9613647	0.22
344.3789673	0.04
345.3832397	0.32
357.2164917	0.23
359.1002808	0.04
365.3515320	0.06
368.3373413	0.05
371.0062866	0.38
381.1421814	0.05
382.9286194	0.03
389.1320496	1.01
394.8955078	0.12
400.9925232	0.60
411.3925476	0.06
418.3442688	0.07
433.0509949	0.05
434.5774536	0.06
435.3880615	0.08
439.4410095	0.05
442.9416809	0.22
459.4624939	0.07
461.1570435	100.00
461.8460083	0.15
479.0523071	0.04
489.3323364	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1828
Annotation	Scopolin
Peak:m/z	Relative Intensity
230.1665649	0.01
309.2832642	0.03
323.5955200	0.02
329.2994385	0.03
351.8333130	0.06
353.1578979	100.00
354.4441528	0.03
379.0911255	0.03
417.0000610	0.04
514.5402832	0.15
515.2422485	0.26
545.3495483	0.01
597.5097046	0.14
645.7402954	0.03
689.5009155	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.03
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0039673	0.33
255.1106415	0.04
272.9179993	0.24
299.0794678	0.11
317.1070557	1.99
359.0576172	0.11
381.0798340	0.09
385.0568848	0.28
394.0924072	0.17
403.1159668	5.31
421.0706787	100.00
432.9763794	0.32
437.9268799	0.08
439.1354980	0.15
445.4550781	0.03
447.3811646	0.13
454.0545044	0.15
473.1381836	0.12
489.0419922	0.09
492.3795166	0.18
506.2592773	0.09
507.1515503	0.04
509.3247681	0.26
515.3715210	0.06
525.2589722	0.22
569.3288574	0.13
576.2084351	0.10
583.3048096	0.07
594.9284058	0.28
595.6430054	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1382
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0514832	0.98
180.1269531	0.03
203.1847687	0.03
221.1813660	0.27
233.1524963	0.03
241.0808105	0.10
242.6963959	0.07
259.0947571	5.12
260.0862122	0.33
263.1818848	0.07
280.9796448	0.13
281.6334229	0.03
305.1226196	0.08
321.0642700	0.16
323.2643127	0.31
324.1640015	0.04
340.7651978	0.61
341.3770752	0.36
342.0679321	0.13
379.3453979	0.18
383.2714233	2.60
384.3125000	0.27
396.3654785	0.05
401.1386108	0.10
403.2029419	0.14
404.6627808	0.05
421.2442627	3.56
422.2137451	0.16
425.2556152	0.12
439.2934570	17.37
440.1953125	1.93
440.9439697	0.03
442.8941650	0.43
444.3764648	0.02
473.5460205	0.06
485.3735352	0.23
487.4427490	0.07
503.2999268	100.00
504.2867432	15.01
511.1114502	0.16
541.2642822	0.34
542.3579712	0.03
555.1404419	0.03
583.2527466	15.52
584.3827515	2.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1035
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
107.0341187	0.06
113.0251160	0.28
132.1192017	0.06
134.0362244	3.24
137.0051422	0.29
142.8529510	0.29
147.0587616	0.08
149.0872955	1.69
160.0471954	2.67
162.1606750	0.09
163.2284546	0.17
164.0551758	0.49
165.0707092	1.89
172.8940125	0.18
175.0121002	31.38
178.2402649	0.53
179.2018433	0.10
179.8424683	0.33
188.1084137	0.10
189.2523804	0.06
191.0607605	7.01
192.1065979	5.58
193.1009979	100.00
202.1411591	0.66
202.9888916	0.51
205.1053467	0.19
207.0196075	1.89
208.2412720	0.12
217.1560364	53.36
219.1183777	0.11
221.1754150	0.15
226.0290833	0.10
229.0026855	0.12
232.8440552	0.05
235.1215820	10.39
236.0379333	0.17
237.3126221	0.42
245.0815430	0.07
247.0169067	2.28
248.3535461	0.17
250.8365784	0.17
256.9993286	0.08
259.0629272	1.25
261.2982178	0.07
265.2238770	4.75
275.0988464	0.17
277.1192932	0.69
278.8959961	0.07
281.2961731	0.11
283.3060303	0.35
295.1784058	6.27
297.5551147	0.10
307.9710083	0.13
309.2216187	0.09
310.2370300	0.17
322.5072021	0.32
325.2217407	0.04
326.2388916	0.17
327.0468750	0.14
328.2687683	0.06
337.2190247	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0616
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
101.1106262	0.03
108.8638153	0.05
112.8188858	0.08
121.0654831	1.04
129.1961060	0.03
137.0564270	3.89
139.2209778	0.03
143.1442566	0.04
147.0276184	0.03
149.0761261	0.03
161.0287781	0.17
163.1084290	0.45
164.9872589	100.00
179.0213013	0.19
182.0461426	0.04
183.0846710	0.71
190.0695648	0.07
191.0505829	1.07
192.9062805	0.18
206.0299988	0.02
209.0748596	0.02
245.3335571	0.04
249.1611938	0.03
256.7329102	0.08
269.8338928	0.04
271.2245483	0.02
273.0054626	0.03
277.2581787	0.06
281.0591125	0.03
285.1831665	0.04
285.9975586	0.15
287.1412048	0.07
299.3482971	0.03
300.0499878	0.06
301.2675781	1.61
315.2097168	0.97
316.2697754	0.02
317.4598389	0.03
327.2192688	0.63
329.0420532	0.07
330.1203613	24.43
331.2395325	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2288
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
148.9922180	0.03
161.1520691	0.05
162.0128174	0.06
173.3286438	0.02
179.3159485	0.01
190.8905334	0.02
191.5180969	0.04
205.8675537	0.03
220.3029633	0.01
237.3381195	0.02
239.2908630	0.07
265.4463196	0.04
274.7388306	0.02
275.6872253	0.02
283.3170471	0.06
287.2514954	0.03
302.0220947	0.08
307.3593445	0.01
311.2723083	0.08
312.5644531	0.04
313.5078125	0.08
314.3798218	0.06
315.3132629	0.18
316.2313232	0.08
322.8780823	0.01
329.2192383	0.02
330.2048035	0.02
331.3089905	0.89
332.2978516	0.12
339.1585693	0.07
341.1229248	0.03
343.1436157	0.03
344.3844910	0.03
345.0269165	0.04
347.2325134	0.04
352.3452454	0.01
358.0791626	0.02
361.4066772	0.04
364.5281372	0.05
373.6851196	0.03
374.3463135	0.03
383.6126404	0.06
394.0962524	0.03
398.2033386	0.08
403.2506409	0.13
404.3374939	0.05
417.5755310	0.03
419.1644592	0.02
421.1841125	0.02
429.6856079	0.04
445.7227173	0.04
447.2676086	100.00
448.2467346	14.46
449.0170898	0.19
450.2911682	0.06
456.6438599	0.02
457.2597351	0.05
458.3776245	0.05
462.4788513	0.10
471.8208923	0.11
473.2033997	0.03
475.4331360	1.03
476.5109253	0.46
477.2751770	0.03
479.2841492	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0492
Annotation	Bracteatin
Peak:m/z	Relative Intensity
93.0005417	0.21
102.9500580	0.07
108.9728241	0.07
111.0238495	0.14
119.9241943	0.18
120.9870682	0.05
123.0296173	0.45
125.0128403	0.18
126.9783478	0.20
131.0142059	0.61
132.9233856	0.04
134.9042358	0.13
136.9514771	0.09
139.0166168	0.23
145.0768738	0.18
146.9902649	0.31
148.9338989	2.26
149.9040527	4.79
150.8232727	1.10
153.0049744	1.66
153.9389038	0.25
155.0375671	0.11
157.7945862	0.09
159.0429993	0.16
161.0198975	0.16
162.8496399	1.16
164.3246613	0.79
165.0871277	2.06
166.1572418	0.12
173.0524597	1.69
174.1791382	0.32
175.0925751	0.10
177.0308685	1.43
178.0365295	0.06
178.9485321	0.86
183.0862732	0.61
185.0732727	0.08
186.0412445	0.08
187.1440125	1.10
187.9332581	0.13
189.0965271	0.25
191.1426697	2.23
192.0409698	0.82
193.1544342	0.26
193.8553467	0.17
195.0043030	0.25
201.1156921	4.13
202.0679321	0.34
203.0889282	0.23
204.9850769	2.17
206.1690369	0.18
207.2641296	0.19
211.1569824	0.19
212.1239014	0.05
213.0307007	0.80
214.0529175	0.47
215.0636292	1.88
216.2386169	0.34
217.0078735	0.29
218.5464478	1.39
219.2454529	1.38
220.1780396	0.61
227.8522034	0.11
229.0570984	10.94
230.0334167	3.81
231.1678467	0.36
232.0884094	0.11
233.0614624	0.69
233.6718445	0.14
235.2876587	0.06
239.1462708	0.48
240.7497253	0.46
241.9610291	0.17
246.3421021	1.89
247.1346436	4.42
248.1696167	0.52
257.1001587	57.80
258.0839233	11.80
259.1437988	0.44
261.2490540	0.20
262.2100830	0.17
266.9806824	0.23
268.1617126	0.06
271.9949341	0.04
274.3051147	0.88
275.0674744	3.66
276.1478882	0.43
285.0681763	4.97
286.2187195	1.65
303.1296997	100.00
304.1231995	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.0044
Annotation	Unknow
Peak:m/z	Relative Intensity
145.0411377	0.01
161.1617737	0.09
189.0625610	0.23
191.1758118	0.82
192.0718689	0.72
193.0556030	0.12
196.9117737	0.02
199.0457458	4.19
216.2222900	0.05
217.1496582	0.03
225.2029877	0.02
226.2777405	0.01
227.4699097	0.06
230.9456482	0.09
233.0369263	22.31
237.1313171	0.03
243.0335083	1.15
251.2071228	0.01
253.3981628	0.07
257.9933777	0.03
273.1611328	0.13
275.1053467	10.73
276.9166870	0.02
285.1028748	4.61
289.0556335	0.02
301.1875610	0.19
303.0964355	100.00
315.0945435	0.07
316.9997864	0.02
329.0588074	1.18
333.2985840	0.06
345.1160889	0.86
346.9808960	1.76
360.9016113	0.04
371.1470032	2.91
389.1091003	70.90
390.0166931	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.23
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
133.1080017	0.35
173.8310852	0.13
196.9187927	0.15
201.1961365	0.51
223.4915924	0.18
224.1909943	0.09
249.3479919	0.26
268.5148926	0.13
269.2369690	0.64
281.0723877	0.14
284.8771973	0.35
287.2763672	0.39
299.1341858	0.29
301.3345642	0.77
303.1233826	84.07
303.7557983	0.23
315.2859802	0.09
317.1817932	0.31
331.2294312	32.50
332.1867676	32.49
333.2074585	100.00
335.2497253	0.61
337.1955872	0.16
338.3347168	0.46
339.2628784	2.17
341.3772888	0.36
345.2996216	0.15
353.6997681	0.32
355.0535278	0.29
363.3078918	0.74
369.1342773	1.17
376.4354248	0.32
381.3728943	0.41
382.4013672	0.12
384.1552734	0.17
412.4177246	0.28
419.0364685	0.31
423.3993835	0.13
429.0418396	0.12
430.5933228	0.48
437.3197327	0.65
447.3465271	2.64
450.4239197	0.43
451.0671082	0.18
465.2771912	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	778.7369
Annotation	Unknow
Peak:m/z	Relative Intensity
264.2125854	0.40
329.0939941	0.30
451.3035889	0.30
613.5952759	0.45
615.4541626	2.55
616.3859253	10.67
617.3534546	6.20
629.3712158	0.83
646.5990601	1.82
647.2997437	2.35
649.7836304	1.58
689.4441528	0.29
697.6011353	0.62
736.3259277	3.79
744.4876099	1.39
749.7369995	2.50
755.6564941	2.21
758.4116821	0.54
759.7972412	5.37
761.0179443	2.73
766.2816772	2.48
770.2913818	2.31
778.4879150	0.42
868.9319458	3.60
888.6785278	2.13
900.1159668	6.38
903.0427856	4.63
905.4301147	4.37
906.8595581	14.23
909.6970825	3.10
920.3798218	8.98
921.0993042	2.07
931.5858765	10.95
932.9797363	2.33
937.7498169	2.04
940.0197144	1.56
941.4479370	4.33
942.0982056	1.75
944.1938477	5.60
945.5466309	7.02
948.5253296	22.13
949.1547852	100.00
949.8674316	2.02
950.5646973	0.55
955.9600220	47.30
963.3283691	1.11
1037.8580320	0.68
1485.2163090	0.25
1517.5655520	0.52
1553.9500730	1.33
1571.0515140	0.23
1674.3343510	0.59
1696.7043460	0.18
1735.8714600	0.20
1804.8348390	13.73
1806.6008300	0.59
1835.0217290	0.57
1854.5767820	0.25
1863.4322510	0.56
1867.7717290	0.33
1882.9085690	1.37
1884.5716550	0.23
1899.5100100	1.55
1906.6579590	1.26
1916.9486080	3.41
1940.6594240	2.42
1943.4639890	1.17
1950.3123780	3.71
1952.2840580	8.44
1953.6019290	10.63
1971.0300290	7.41
1974.6475830	5.53
1982.0238040	86.26
1988.9632570	0.25
1998.7664790	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1404
Annotation	Castamollissin
Peak:m/z	Relative Intensity
162.9827423	0.25
164.0823822	0.07
165.0157318	1.68
167.0677643	0.30
177.2672424	0.07
179.1469574	0.07
180.8266296	0.03
186.3715668	0.05
191.8385315	0.33
193.0766296	4.29
197.0061340	0.19
207.0476990	0.15
215.0299377	0.10
216.2828674	0.30
217.0236359	0.12
218.2990875	0.07
219.1464233	0.05
224.0593262	0.05
235.1251526	0.09
239.0989227	0.10
245.8944550	0.23
251.4735565	0.18
258.2847290	0.06
259.3480225	0.69
261.1463318	4.62
263.1988220	0.04
265.4774780	0.06
270.2612915	0.10
272.2864380	0.13
273.3557739	0.13
275.3125610	0.09
277.2861328	0.04
283.2392578	0.04
286.3546753	0.16
287.0750427	0.04
288.1883545	0.17
293.2627563	0.10
299.2271729	0.76
301.3135376	0.33
302.2805786	0.05
303.2644653	2.33
305.3573608	0.06
311.2329102	0.09
312.2188110	0.03
313.6981201	0.42
314.3051758	3.47
315.2440796	0.06
317.3256836	0.06
319.2471924	1.51
327.3936768	0.13
329.2059326	65.47
329.8335571	0.08
331.3800659	0.16
341.2635498	0.05
345.5802002	0.36
347.1483765	100.00
347.7603149	0.22
348.7504883	0.08
353.4607544	0.07
355.2145996	0.18
359.1487427	0.31
369.3554077	0.05
371.3203125	7.67
383.1860962	0.09
384.4991455	0.06
385.3984375	0.08
388.3652344	0.26
389.3001709	0.61
395.4609985	0.05
397.2191772	48.25
401.3480835	1.14
403.2138672	0.05
417.1420898	0.03
419.3391113	0.10
429.3059692	0.04
430.0386963	0.10
434.4122925	0.18
447.2506104	0.03
459.6414795	0.04
461.2890625	0.14
462.3998413	0.07
463.4254761	0.08
464.4934692	0.06
465.3727417	0.04
471.2673950	0.03
474.3886108	0.07
479.4725952	0.04
483.2129517	0.10
490.5256348	0.18
491.5856323	0.02
492.3819580	0.03
503.3430176	0.18
504.2987061	1.29
505.4086914	4.29
506.2314453	0.07
507.3286743	0.44
509.4733276	0.11
515.4522095	0.06
530.9556274	0.32
533.3287354	3.14
536.5222778	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.23
Annotation	9-OxoODE
Peak:m/z	Relative Intensity
94.94509125	0.30
96.96453094	0.36
99.14987946	0.07
109.2034912	0.08
111.0528793	0.09
113.1678848	0.14
118.9850388	0.32
123.0610504	0.32
124.7825851	0.10
135.0734558	0.09
137.1303406	0.77
143.1417847	0.22
145.1955872	0.09
145.8839417	0.13
146.7780151	0.21
151.117569	0.31
152.9481812	0.26
155.1733093	0.09
156.9532013	0.21
167.0706177	0.58
168.9607544	0.31
171.0818787	0.82
173.000351	0.17
175.0109253	0.51
177.265625	0.39
180.2507935	0.09
181.1487885	0.32
183.1357269	0.33
189.1664124	0.34
191.1153259	0.46
193.3657074	0.15
195.272522	0.17
201.517395	0.22
203.702301	0.05
207.4613342	0.05
208.9983521	0.11
211.2209473	0.34
215.9931641	0.10
217.3624268	0.08
218.9462585	0.32
221.2286987	0.23
225.2378235	0.20
231.1229553	0.18
235.0122375	0.40
237.1953125	0.83
238.1805115	0.05
239.1515808	0.52
240.9294434	0.12
245.7205505	0.12
249.2092285	0.52
253.2681274	0.91
254.9916382	0.20
259.2847595	2.51
265.0471802	0.11
267.3660889	0.16
277.2116089	100.00
277.8415222	0.31
286.7320557	0.24
294.0794067	0.12
294.9057922	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	733.3069
Annotation	Unknow
Peak:m/z	Relative Intensity
239.6007690	0.05
249.2233276	0.15
267.1637878	0.08
289.0179443	0.08
295.4454041	0.13
302.6517334	0.04
310.1607056	0.03
312.5274963	0.14
313.2852478	0.63
326.1761475	0.22
327.2497253	10.82
335.2714233	0.12
338.1223145	0.06
341.2498779	0.28
343.1046448	0.15
355.1361084	0.07
357.3351440	1.43
358.5076599	0.06
369.2486572	0.12
370.3151245	0.11
375.2550049	0.04
387.3193970	0.15
390.8262329	0.10
405.0782471	0.21
409.2712402	0.06
411.6766968	0.04
415.4520874	0.03
417.3595581	0.07
419.4608154	0.03
428.3907471	0.02
431.2733765	0.02
433.3130493	0.05
448.6034546	0.03
461.3854370	0.07
467.6494751	0.09
490.6660767	0.05
491.5135498	0.20
492.3284302	0.18
493.5134277	0.07
502.8756714	0.11
504.2428589	1.79
505.4249268	0.29
506.5719604	0.20
507.4512329	0.02
517.5882568	0.15
518.5831299	0.30
519.2971802	0.04
521.6579590	0.29
529.0760498	0.11
535.4130859	0.03
537.3489990	20.92
539.2681274	0.13
540.2741089	0.33
541.3037720	0.08
542.6511841	0.22
553.4723511	0.16
558.6953735	0.08
571.3574219	0.29
571.9745483	0.04
580.5244751	0.04
581.1516113	0.05
586.3927612	0.09
587.2664185	0.03
595.2891846	0.02
597.3547974	0.25
600.4873657	0.06
607.4505615	0.08
611.3789673	0.16
613.4054565	0.03
614.3568726	0.19
615.4330444	0.05
619.1759033	0.07
624.4490356	0.05
635.4614258	0.03
637.4046021	0.23
640.3900757	0.03
642.8995972	0.10
643.5590820	0.08
645.5586548	0.11
647.7042847	0.21
651.2236938	0.05
652.4924927	0.13
656.4904175	0.06
661.3339233	0.06
666.5073853	0.09
669.3358765	0.04
685.3818970	100.00
686.1506958	0.44
687.2569580	0.42
688.3701782	0.28
689.2072144	0.14
696.4527588	0.03
702.1886597	0.09
713.2633667	0.32
714.3494263	1.71
715.3447876	4.28
716.0072632	0.01
719.5540771	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.9782639	0.01
111.1150589	0.01
117.0971451	0.01
126.8710785	0.10
135.145752	0.63
143.262146	0.03
154.984848	0.03
161.1207886	0.47
172.9906006	0.51
179.1419067	3.95
191.0519409	100.00
195.1759949	0.02
258.2045288	0.01
273.2361755	0.05
290.9779968	0.02
306.8337402	0.03
309.26828	0.13
317.2465515	0.03
335.2747803	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1453
Annotation	Orchioside B
Peak:m/z	Relative Intensity
145.0333862	0.93
153.1598511	1.03
157.1559448	0.07
160.9825897	0.12
162.9226685	0.14
179.1120911	0.09
184.9613647	0.09
187.0324707	0.62
189.2561951	0.05
195.0287781	0.09
202.9966278	0.07
205.2629395	0.18
218.9159851	0.03
228.9077759	0.15
241.1799774	0.07
247.1976318	0.63
249.4600525	0.05
257.0158997	0.14
259.2839966	0.05
280.6057434	0.17
289.1991882	0.04
297.1078796	0.24
299.2254944	0.19
301.1781006	0.19
307.1831665	100.00
315.2404480	0.89
317.4916992	0.05
328.1985168	0.22
329.0319214	0.17
337.2138672	0.17
339.2448425	0.05
365.2528381	0.04
369.1832886	0.08
376.3319397	0.06
377.2574158	0.02
378.2106323	0.08
396.1128235	0.12
397.3611450	0.05
402.2658691	0.06
415.2625427	1.93
417.1773376	0.26
433.5341492	0.05
443.1838379	0.02
446.0820312	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.46
Annotation	Unknow
Peak:m/z	Relative Intensity
241.4211884	0.03
245.4890137	0.05
254.9148254	0.03
261.4523315	0.11
263.3862305	0.03
266.8793640	0.04
281.1891479	0.03
283.2224731	0.08
285.2727966	0.03
287.2870178	0.05
299.4946289	0.04
301.2880249	0.04
306.2726440	0.59
309.6264038	0.05
310.4407349	0.07
313.3411865	0.02
319.3436890	0.34
321.5338135	0.07
323.6463623	0.04
325.4915161	0.05
333.6021118	0.03
335.2735901	0.29
337.3509521	0.42
354.8755493	0.02
359.1830750	0.04
379.4565430	0.07
392.9280396	0.07
403.7433472	0.03
407.0681763	0.03
411.1806641	0.07
417.2097778	0.11
423.4528809	0.17
427.3853149	0.02
440.5428467	0.05
441.4274292	0.17
442.5367432	0.24
449.3759155	0.09
460.2043457	0.30
461.4899902	0.04
462.5335083	0.09
465.7974243	0.06
469.5190430	0.10
471.2789917	0.07
474.2343750	0.06
478.2499390	0.13
485.3461914	0.12
501.5023804	0.07
503.6068726	0.06
507.7043457	0.12
509.6387329	0.11
515.4970093	0.18
525.5465698	1.22
533.4275513	0.04
543.5521240	6.94
547.3340454	0.09
552.8239136	0.12
556.0430298	0.03
561.4520874	1.34
569.3742065	0.04
585.8552856	0.07
587.5260010	0.02
599.5730591	100.00
600.6461182	9.16
610.3937378	0.10
611.3695068	0.09
624.4021606	0.04
628.4522095	0.37
629.4930420	0.74
630.1100464	0.09
642.6435547	0.08
643.8414307	0.02
651.5966187	0.02
666.1184692	0.03
687.3458862	0.16
694.5260620	0.04
697.6112061	0.21
705.3054199	0.34
705.9971313	0.07
707.7963257	0.09
709.2567749	0.10
722.9434204	0.83
723.7068481	0.37
724.6762695	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9941864	0.59
131.0071106	1.94
146.9683685	0.59
158.9967957	8.93
174.8866882	100.00
178.9679108	0.02
214.7848816	0.22
217.1243896	0.04
232.9336853	0.18
243.2581177	0.03
244.9368591	26.25
258.7490234	0.08
261.0858154	0.59
269.8221436	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1
Annotation	Castamollissin
Peak:m/z	Relative Intensity
147.9336700	0.03
149.0855560	0.12
150.9549255	1.02
153.2343140	0.06
161.1465912	0.12
169.3235168	0.04
172.9575043	0.03
174.9423065	0.11
179.0532532	1.77
189.4506073	0.26
190.1446228	0.04
191.0289001	0.05
192.0766296	0.08
193.0225525	0.05
197.1835327	0.05
199.2669983	0.04
200.7341309	0.09
207.0963745	0.05
209.1004944	0.07
211.1704407	0.21
213.3237762	0.13
217.1779785	0.09
219.1695251	0.13
221.3134003	0.14
226.7834320	0.08
228.0565796	0.10
229.1434479	0.41
230.0457916	0.15
231.9640198	0.07
233.1335144	0.04
234.3896027	0.14
239.1078339	0.18
240.0465393	0.21
241.3274231	0.07
242.0807190	0.04
244.1872253	0.03
253.2704163	0.13
254.1687622	0.06
255.2056885	1.75
256.2652283	0.06
257.2169800	0.25
258.1736450	0.05
269.3793945	0.03
271.1480408	1.95
272.2882080	0.21
273.1749573	0.58
275.1767578	0.06
279.4107971	0.02
281.2620850	0.04
283.0648499	1.04
285.8854980	0.02
293.1889954	5.63
294.2555542	5.63
295.1673889	0.72
296.1852417	0.05
297.2966309	0.29
299.0912476	2.53
300.1562195	62.36
301.1497192	100.00
302.3855591	0.15
307.0956726	0.04
309.1663513	0.02
311.1283569	0.04
312.6823730	0.11
313.2957764	0.10
314.0709229	0.09
315.2427063	0.18
317.8655396	0.13
319.1471252	0.06
320.2463989	0.04
323.2921753	0.27
325.2332153	0.44
326.1297913	0.04
327.3020020	0.36
328.4685974	0.15
329.4370728	0.06
331.1142578	0.15
335.1453552	0.05
336.4020996	0.18
337.1787415	0.04
341.3031921	0.16
342.2528687	0.60
343.2826843	2.59
345.5408020	0.07
352.2294922	0.11
352.9295349	0.03
355.2799988	0.39
357.1882935	0.08
359.1338806	1.77
361.1812439	0.29
365.1747742	0.05
367.3594055	0.14
368.0594482	0.10
369.3033447	0.17
373.2762756	0.21
379.1079102	0.63
383.3799744	0.20
385.3588257	0.07
395.0870972	0.08
401.2317810	0.02
409.4788513	0.25
411.3052979	0.10
412.4676208	0.07
419.3440552	0.04
427.3929749	0.35
430.5300903	0.02
443.3957214	0.13
444.2915955	0.05
445.2355957	4.50
446.0672913	0.03
456.6488342	0.40
457.8836060	6.56
458.8391418	0.38
459.4664307	0.38
460.3645935	0.22
461.4069519	0.28
463.2061462	43.40
469.3783875	0.06
473.1355591	0.03
475.4677124	0.20
477.3628540	0.06
480.4712830	0.12
484.3783875	0.05
486.4677124	0.17
487.2427368	1.02
489.4256897	0.43
490.5704956	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2394
Annotation	Unknow
Peak:m/z	Relative Intensity
149.3519745	0.02
160.3205719	0.09
161.0260468	0.24
162.2280426	0.06
177.0231628	0.06
179.0071106	0.22
191.1377869	0.65
191.9142609	0.09
193.1255798	0.16
203.1105042	0.03
206.1398621	0.07
220.2962036	0.28
221.0181885	0.83
222.3053741	0.17
225.1373901	0.12
232.6165771	0.08
238.7636414	0.03
241.2642365	0.11
245.0952301	0.03
247.1159210	0.03
249.1621399	0.21
250.3117065	0.03
251.0556030	0.48
253.0629883	0.04
262.7206726	0.04
269.0676880	0.05
274.7751465	0.14
281.1075439	0.52
283.4410400	0.03
286.2717285	0.05
287.1450195	0.05
293.0730591	1.24
294.1543274	0.08
295.2666016	0.06
299.1679688	0.06
309.0640869	0.05
311.0654907	6.16
312.1148071	1.95
313.1791992	1.16
343.5242310	0.06
345.0993042	0.03
353.3955078	0.04
357.0419922	0.04
358.8456421	0.03
367.3615112	0.03
369.2219849	0.51
371.1145630	0.52
373.0795288	0.05
385.1723633	0.05
386.8692017	0.41
387.5287476	0.41
389.3983154	0.06
399.2879028	0.08
419.2406616	0.03
424.2117920	0.08
428.4400635	0.06
429.5028076	0.06
433.7710571	0.07
443.2789307	0.07
447.3737183	0.08
457.3084717	0.06
459.1780396	0.14
461.5310669	0.04
463.2939453	0.02
464.7481689	0.16
468.0897217	0.05
471.4848022	0.08
473.6989746	0.14
477.7570190	0.04
479.7398682	0.06
485.2911377	0.27
486.3593140	0.08
489.3848877	0.08
491.2182007	0.27
501.5399780	0.23
503.2357788	100.00
504.0967407	0.03
505.3065186	0.46
507.3880615	0.07
511.3352661	0.14
520.4118042	0.03
531.3483276	0.11
534.1527710	0.11
539.3469238	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.07
Annotation	1D-1-Guanidino-3-amino-1,3-dideoxy-scyllo-inositol
Peak:m/z	Relative Intensity
130.9291534	0.13
156.1491241	0.20
173.1028748	100.00
214.9516907	0.11
239.1696320	0.52
241.0631256	0.06
242.1490631	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1805
Annotation	Spinosin
Peak:m/z	Relative Intensity
182.8601685	0.02
188.9607544	0.17
201.4087830	0.02
202.1138458	0.04
213.2264709	0.05
228.3019714	0.01
229.1950378	0.09
230.2327423	0.07
231.0026855	0.01
241.0235748	0.04
242.8651886	0.04
257.1901855	0.07
258.1806030	0.32
268.3028870	0.14
286.0981445	4.67
286.6997681	0.03
301.1419373	100.00
301.8203125	0.22
346.1015625	0.02
367.6581421	0.01
411.3569336	0.03
423.4160767	0.03
430.9029541	0.02
447.2796021	0.95
463.2374268	18.51
476.3676758	0.15
481.4390259	0.03
520.1547852	0.10
590.3463745	0.04
591.2278442	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1765
Annotation	Unknow
Peak:m/z	Relative Intensity
119.1038132	0.08
121.1020660	0.09
131.2387085	0.03
139.1764984	0.03
142.9505615	0.11
149.1049042	0.04
153.1112061	0.05
161.0905151	0.08
163.1744080	0.82
174.8471832	0.05
176.2128296	0.04
179.0507812	0.33
181.1968994	9.67
183.3142700	0.04
199.0265808	0.03
207.0898590	4.77
223.3717804	0.10
225.1222839	100.00
241.4349060	0.02
243.2278748	3.12
249.1605530	0.20
250.2640076	0.32
266.1325073	0.02
267.4826050	0.02
268.2164001	0.09
276.1256104	0.03
283.7713623	0.06
285.1937256	0.04
295.6177063	0.06
299.2538452	0.08
325.0637817	0.02
328.3548584	0.05
330.1237488	0.05
332.2694092	0.03
343.3024902	0.04
345.4353333	0.09
359.4013977	0.26
360.2620239	0.03
361.2956848	0.14
362.5372620	0.06
369.3471375	0.02
373.0018616	0.02
376.0740051	0.11
377.1754150	0.08
385.1002808	0.04
386.1951599	0.10
387.2382507	0.69
388.2657776	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	509.1275
Annotation	Eupatolitin 3-glucoside
Peak:m/z	Relative Intensity
219.1627502	0.08
228.2075806	0.02
295.5350952	0.05
303.2258301	0.22
304.1713257	0.39
305.2046509	0.27
316.9144287	0.03
318.9702759	0.05
347.1694946	100.00
351.2111206	0.02
355.3259888	0.05
358.9865112	0.07
371.1005859	0.02
377.2196655	0.10
379.3560791	0.12
389.2379150	0.43
413.2942505	0.39
425.1017456	0.03
428.3787842	0.01
442.3280640	0.03
443.2095337	0.44
455.2846069	0.04
473.3610229	0.47
481.1537476	0.02
491.2178345	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2809
Annotation	Dictamnoside G
Peak:m/z	Relative Intensity
181.3257141	0.05
191.0912781	0.23
197.1671753	0.12
221.0079346	0.12
223.0198059	0.05
229.2648773	0.10
233.1692200	0.32
234.8702087	0.03
239.1363220	0.19
241.1462097	0.19
250.3066406	0.04
251.0997620	0.14
255.0223999	0.09
265.0089417	0.06
272.3711853	0.14
274.7992554	0.03
275.4426270	0.08
280.6978760	0.09
282.9910889	0.06
285.3129272	0.06
293.2224426	0.89
300.0686340	0.12
307.0907898	0.04
311.1467285	1.13
325.3308105	0.09
331.2711792	0.51
333.5883179	0.23
335.1469727	0.07
343.5649414	0.06
377.2949219	0.07
395.2971191	0.05
397.3596802	0.08
407.3300171	0.07
413.1213379	0.07
423.0737305	0.08
427.5736694	0.10
430.9477539	0.06
445.3096924	11.54
447.4422607	0.10
461.5248413	0.07
463.4086304	2.52
469.6328125	0.04
472.1444702	0.11
489.3057251	0.08
505.4559937	0.07
519.9312134	0.12
529.3552856	0.08
537.5557251	0.05
547.2648926	100.00
548.0114136	0.05
549.3773804	0.05
557.2399902	0.07
560.3694458	0.10
566.8699341	0.07
575.2540283	0.46
576.4356079	0.22
594.2407837	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.17
Annotation	Verbasoside
Peak:m/z	Relative Intensity
136.9849854	0.07
146.8181458	0.22
149.2137146	0.09
166.9084320	0.15
177.4495392	0.13
181.1081238	0.08
186.8952789	0.29
189.3058472	0.04
191.0373535	0.28
192.8670044	0.08
216.7635498	0.29
219.0583649	0.24
221.0330658	0.18
232.9492493	0.42
237.3431549	0.10
241.0858459	0.15
242.8763885	0.13
247.4279785	0.15
263.3236084	0.09
268.9171448	0.09
272.3769226	0.21
281.2167664	0.24
284.3092651	0.07
285.1823730	0.30
293.4196777	0.16
297.2501831	0.33
298.7059326	0.30
299.3367310	0.97
311.1555786	0.54
312.1368103	0.08
313.3153687	0.70
314.1033630	0.72
315.3591309	0.39
317.1260376	0.10
318.9956665	0.34
327.2416687	6.72
328.1921997	47.38
329.1659241	100.00
330.1574707	1.02
331.2119446	5.76
333.2167969	0.41
334.2236023	0.17
337.4696350	0.06
338.1201477	0.12
341.2435913	1.87
343.2475281	5.67
345.2551270	0.18
347.0429077	0.13
353.2738342	0.65
354.2984924	0.12
357.0452271	0.30
363.0921021	0.08
369.3610840	0.07
370.7291260	0.39
371.3470459	4.23
373.3645325	0.10
375.3293762	0.08
381.4739075	0.08
383.2760620	3.00
386.4124146	0.14
387.5317688	0.07
392.9610291	0.20
395.4511108	0.10
397.5057983	0.11
401.2560120	4.32
402.6860657	0.07
411.4149780	0.59
413.1763306	0.38
415.2322388	11.83
415.8600769	0.06
417.2932739	0.10
418.2759094	0.31
425.2174377	0.82
429.3564758	0.95
433.2670288	0.08
434.1502991	0.15
442.3254089	0.08
443.2318726	0.92
446.0354004	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0859
Annotation	Gerfelin
Peak:m/z	Relative Intensity
104.9630890	0.26
110.9065857	0.09
112.7583466	0.06
119.0945282	0.28
123.0330048	99.23
124.9156494	0.06
127.0420380	0.79
136.0339203	0.05
136.9927673	0.40
139.0151062	100.00
140.1415710	0.06
143.1635437	0.09
147.0145569	7.33
150.9766846	25.91
153.0522461	0.56
165.0513611	49.02
168.9627533	1.77
177.0914154	0.06
180.9079285	0.39
205.1449280	0.44
207.3017883	0.03
227.0335693	0.03
229.2706604	0.06
231.2365112	0.27
233.2049255	0.03
243.2359009	0.09
245.1193237	0.25
245.9837341	0.04
247.2803040	0.03
248.9776001	0.33
249.5949707	0.01
255.0767212	0.31
262.9303894	0.15
270.0034790	0.11
273.0651245	26.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.23
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
143.0560608	0.32
149.4741516	0.02
151.1121521	0.59
158.8371887	0.36
161.0597076	2.78
163.1087952	0.04
165.0547028	0.05
169.1274872	0.08
176.2884216	0.03
179.0713501	1.35
180.0456238	0.03
189.0841522	0.21
191.0822449	0.03
192.0536194	0.05
197.0275269	0.02
199.1110229	0.04
205.1982117	0.11
209.2644043	0.02
215.0735779	0.07
219.1527405	0.06
220.0328979	0.21
221.1203766	0.02
222.9948273	0.01
226.1422424	0.03
227.1748352	0.03
228.1499176	0.02
234.4082642	0.04
235.4055481	0.02
239.1033630	0.02
243.0660095	0.13
244.0516968	0.08
245.3622437	0.13
247.0607605	0.04
248.1362915	0.04
249.3033752	0.04
250.9734650	0.07
256.1661682	0.01
257.1667175	0.04
259.2811890	0.06
261.5018311	0.07
263.0327148	0.12
267.1735229	0.09
268.1885376	0.12
269.2639465	0.03
270.3255615	0.08
271.0619812	0.14
272.2410889	0.08
273.1922913	0.04
277.4609070	0.04
280.0707703	0.04
284.3986511	0.02
285.2679138	0.37
286.2392883	0.04
287.0723572	0.44
288.0445251	0.17
288.9178467	0.13
290.9459534	0.09
297.2631836	0.12
298.2405090	0.20
299.2488098	0.08
301.2099609	0.19
303.1612244	0.67
304.2995605	0.03
306.2348633	0.09
309.0782471	0.02
313.2150879	0.41
314.4002380	0.10
315.1127930	1.79
316.2026672	1.73
317.3274536	0.16
318.5155029	0.04
323.2008667	0.24
324.3449707	0.03
325.0667114	0.09
326.3879395	0.01
327.2815857	0.31
330.1381531	60.43
331.1532593	100.00
332.2506714	0.93
337.2615356	0.02
338.2468872	0.02
340.2999268	0.01
341.2334595	0.62
343.1798706	0.34
344.3117676	0.03
345.1342163	0.09
348.9420166	0.06
355.3394165	0.13
358.1328735	0.05
359.3019409	0.22
360.1924438	0.15
361.3228455	0.08
365.2150269	0.11
367.2716675	0.24
368.2407837	0.03
371.0417480	0.09
373.1532898	2.49
374.1538086	0.05
383.2302856	0.04
385.0875244	0.28
388.1002502	0.04
395.3606567	0.04
397.2296753	0.08
403.0779419	0.16
405.6003723	0.04
407.3855896	0.02
412.5624390	0.07
415.2447815	0.20
421.4808655	0.03
425.2549133	0.19
430.4073181	0.05
431.2036133	0.03
433.3704529	0.15
446.5309753	0.07
447.3889160	0.29
449.2790833	0.94
451.1711121	0.10
461.3311462	1.32
462.2706604	0.10
463.4150085	0.08
465.3150024	0.08
474.5848694	0.19
475.3706665	0.60
478.2146912	0.80
478.9236450	0.08
491.0130005	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1064
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
287.1407166	100.00
316.9761047	0.01
384.9930420	0.02
403.4720764	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1324
Annotation	Glu Val
Peak:m/z	Relative Intensity
78.65779114	0.07
80.64755249	0.09
82.92298889	0.34
85.06822205	0.02
87.03018188	0.04
92.11429596	0.05
93.04680634	0.05
97.03767395	0.30
98.88832092	0.01
105.0838165	0.06
107.1144104	0.20
109.0395813	0.41
110.9533081	0.31
113.1560974	0.03
114.8368835	0.04
117.2572632	0.07
118.9868469	0.30
120.9414825	1.72
122.9178619	0.48
125.0359497	0.15
126.9868164	0.07
128.6884613	0.04
130.7961121	0.02
133.1577606	0.08
134.9585876	1.26
135.956192	0.03
137.1126099	0.60
138.9840546	0.18
141.242569	0.08
143.1329803	0.43
145.1012421	1.00
147.066391	1.40
149.0642395	2.56
150.0657043	0.54
151.0901947	0.45
153.0503845	0.56
155.4244232	0.05
156.9859467	0.35
159.109787	1.37
160.1093903	0.76
161.0175629	0.53
163.085556	3.11
165.0894165	0.39
167.1400452	0.02
169.0572662	0.44
170.0980377	0.29
171.213623	0.11
172.4423676	0.30
173.1404114	2.35
175.0635529	0.27
177.2762604	0.14
180.8144836	0.10
183.1309967	3.48
185.1391907	2.07
187.0379181	19.17
188.1916504	0.24
189.0931854	1.39
191.1108551	15.16
193.1639862	0.53
194.9932404	0.12
196.0786591	0.25
199.112915	0.09
201.0853119	10.40
201.8348846	0.04
203.1376038	4.43
205.0910339	2.19
206.4814911	0.02
207.1062469	0.05
211.1734772	4.75
213.2604065	0.03
214.2819824	0.35
217.1576538	0.06
219.1220551	2.05
219.7623138	0.04
229.1082306	100.00
230.1255035	0.17
232.1465454	0.02
259.0996704	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.225
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
133.9585724	0.05
136.1392517	0.07
143.0455017	0.11
144.0533142	0.11
146.2140503	0.39
147.1539459	0.03
148.1272125	0.09
149.1082458	0.06
163.0997009	0.64
163.8459473	0.05
165.2640533	0.10
166.2780914	0.05
174.0099030	0.37
178.1689148	0.03
180.1189575	2.29
184.0180511	0.07
190.1079407	0.15
191.1700745	2.58
193.2708282	0.17
193.9531555	0.11
199.9124146	0.05
201.2088928	0.03
202.3672638	0.06
207.1640320	0.59
210.2897949	0.05
211.1455078	0.07
213.1115112	0.03
214.1889801	0.06
217.1246490	0.03
218.1299133	0.87
219.4140320	0.05
222.3036194	0.19
226.0008240	0.05
228.3511353	0.40
229.3846436	0.10
230.1447144	0.07
235.1559296	10.02
237.1705933	0.03
240.2496033	0.03
241.9001465	0.07
244.4293823	0.13
245.3041382	0.27
247.2242126	0.04
248.1394653	0.07
249.4417114	0.09
252.1698914	6.49
254.2526550	0.96
256.3178711	0.22
257.3211975	0.08
258.0145264	0.03
259.4716797	0.10
261.2228699	0.14
266.2807922	0.63
267.1292114	0.05
268.0424194	0.05
270.2977905	0.24
275.1654053	0.17
279.2049255	0.54
280.3885193	0.06
282.0962524	0.03
284.0335693	0.12
285.1090088	0.64
286.3834534	0.25
287.4300842	0.04
289.1956787	0.23
291.3904419	0.03
299.2363586	0.21
300.1139221	0.05
302.2752686	0.05
304.1720276	0.03
306.3208923	0.33
310.7129211	0.05
314.1742249	0.57
315.1830444	0.34
316.1194458	0.06
317.0364990	0.02
318.2653809	0.27
319.2095337	0.12
320.2785339	0.04
321.2344360	0.05
324.4245605	0.14
325.2828979	0.13
329.1616821	0.33
330.2668762	0.20
331.2888794	0.09
332.1174316	0.10
334.4448547	0.13
339.2375793	0.07
341.4053955	0.13
342.7601929	0.34
343.4674072	0.38
348.4360962	0.20
358.2867432	2.13
358.9274292	0.03
360.2843323	0.22
368.2709045	3.02
369.4001160	0.32
373.3287354	0.08
375.3290100	2.87
376.5772400	0.09
386.3075867	100.00
387.6582947	0.07
390.3052063	0.25
392.4952087	0.19
401.2483215	0.12
403.3310547	4.55
404.3107605	0.11
412.4358521	0.90
413.3999939	0.04
415.6072693	0.04
419.2960205	1.99
420.4349976	0.07
430.2622986	36.69
430.9358521	0.04
432.2073059	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.09
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9293518	0.13
149.0721283	0.21
151.0099640	1.35
152.3687744	0.19
153.0526428	0.09
158.7493896	0.25
161.0670166	1.88
163.1236725	0.45
169.0769958	0.14
173.2054901	0.06
175.2836609	0.07
177.2990570	0.10
178.9856262	0.70
179.8880310	0.22
181.1312256	0.11
189.4298706	0.21
191.1670837	0.23
199.1660309	0.04
201.0412292	0.12
203.2521362	0.09
204.1896667	0.29
205.1649170	0.53
216.2146912	0.03
219.1437378	0.03
219.9478302	0.06
221.3064117	0.27
225.1227570	0.11
226.1008911	0.03
227.1414795	0.04
229.1972656	0.09
230.8946533	0.17
241.1329346	0.04
243.1015320	0.82
245.0319519	0.28
248.9601135	0.08
250.4794312	0.05
257.2253113	0.48
259.3350830	0.06
263.3157349	0.04
265.1248779	0.03
266.9479065	0.22
268.5626831	0.14
269.5316772	0.06
270.5227051	0.57
271.1979065	2.58
271.9314270	0.27
273.0737610	2.29
275.1082153	0.06
279.5493469	0.08
281.3514404	0.10
283.0959167	0.20
284.5516968	0.83
285.2314453	3.85
286.2474365	1.25
287.2081909	0.19
289.1969299	0.22
295.4223328	0.03
297.6893921	0.16
299.0902100	3.21
300.0527954	0.75
301.2652283	0.11
302.5481567	0.22
303.2656860	0.56
311.1760864	0.09
314.1120911	100.00
315.2426758	34.00
316.1790161	0.09
317.4432678	0.11
325.4022217	0.08
327.3392334	0.03
328.1228638	0.09
329.1991577	2.74
339.2685547	0.12
341.3739929	0.12
342.1098328	0.22
343.2230530	0.41
353.9587402	0.07
355.1281433	0.16
357.2431641	11.82
359.1487732	0.11
369.2381897	0.13
372.1708679	0.06
375.3025818	0.11
379.3089905	0.04
383.5003357	0.24
387.2917480	2.56
393.1895752	0.17
399.0796204	0.07
401.3591309	0.16
403.3171387	0.38
415.3623962	0.14
419.2474365	1.40
427.2167053	0.26
429.2913818	0.35
432.0490723	0.09
433.2089844	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1017
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
115.8803101	0.03
118.7502823	0.03
126.9650269	0.10
132.9842529	0.10
137.1141968	0.09
139.0193481	0.12
144.9983521	0.13
148.2605591	0.21
148.8968048	0.31
149.8458557	0.28
150.9566345	1.12
151.7166901	0.03
160.8844299	0.02
161.7908630	0.08
163.2723083	0.22
164.8958435	0.06
165.9671936	0.03
167.1595001	0.10
168.9772949	100.00
177.0458832	1.72
178.2513580	0.85
179.0708313	2.70
180.0833740	0.31
180.9813690	0.20
184.7954712	0.02
188.9824677	0.09
190.0857391	0.16
191.0881958	0.20
193.1426086	0.29
194.0385132	0.11
196.9953308	0.07
199.1316833	0.06
200.0122681	0.07
201.0534668	0.11
203.2796173	0.13
204.3044281	0.14
207.1168823	0.19
210.8793945	0.19
213.6771240	0.03
215.3475952	0.15
219.2811890	0.03
220.2650757	0.05
221.2492065	0.33
225.4673462	0.08
228.1180115	0.05
229.2144165	0.19
230.1925354	0.05
231.0651855	0.35
235.1846008	0.32
238.3148804	0.12
239.0797729	0.03
240.0636902	0.13
242.0574951	1.75
243.0560608	0.37
244.2254333	0.10
245.4975891	0.05
247.1172180	2.03
249.1509705	0.05
250.1869812	0.34
252.0081482	0.19
253.2163696	0.34
255.1087646	0.16
255.9363403	0.10
257.0693359	0.46
259.1828613	0.19
260.2879333	0.13
263.1567993	0.05
264.8147583	0.07
267.0555725	0.07
269.0412292	0.61
270.0511475	8.52
271.1565247	1.92
271.9703064	0.20
273.0647278	0.26
277.1504822	0.19
280.0681152	0.06
281.2708130	0.22
284.2420959	0.17
285.2742920	0.22
286.0972900	0.77
287.0974121	15.82
288.2310181	2.45
289.2818604	0.21
290.3345642	0.10
295.3001404	0.19
298.0727539	8.13
299.1106262	19.43
300.1791687	1.78
300.9852905	0.32
302.1262817	0.19
303.2658691	0.89
313.0827332	2.95
315.1378174	17.59
316.2246704	22.58
317.0712280	2.00
331.2507324	6.85
332.3840027	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1409
Annotation	Castamollissin
Peak:m/z	Relative Intensity
174.3002625	0.07
174.9948730	0.02
177.0659943	0.11
179.0540771	2.42
180.0624390	0.31
182.9709930	0.05
184.3334961	0.03
187.3114624	0.06
189.0937805	0.36
191.0735474	0.22
192.0365295	0.15
192.9997711	0.35
195.0989532	0.07
196.9795532	0.23
199.1415100	0.09
201.0497131	0.10
203.2535248	0.29
204.1455231	0.03
205.0379944	0.16
206.0269928	0.36
207.2033997	0.68
209.0875854	0.14
211.1741028	0.03
211.9546661	0.04
214.0200653	0.69
217.0956879	0.17
218.9585876	0.34
220.3706665	0.02
221.2125854	0.06
225.1754761	0.20
226.2050629	0.07
227.1067810	0.58
228.3151093	0.08
229.2187195	0.35
231.1497498	0.14
232.2709198	0.08
233.1457214	0.70
234.1663055	0.09
237.2156982	0.19
239.0913696	0.02
242.0914459	0.96
243.1271667	0.93
244.1878357	0.09
245.1579742	0.77
246.3142700	0.06
247.1907501	0.19
248.8391266	0.25
250.3070068	0.03
253.2704315	0.07
255.0902557	0.42
256.1712036	0.06
257.1357727	0.26
258.1182861	0.17
259.1929626	0.86
260.1985474	0.20
261.2372742	0.25
263.1109924	0.18
264.0520935	0.08
267.0466919	0.03
268.0805969	0.04
269.1465454	0.17
270.0562439	2.11
271.1917419	11.52
272.1689148	2.10
273.2023315	0.57
274.0612183	0.15
277.0701294	0.06
278.8462219	0.04
281.0731201	0.13
282.2722778	0.13
283.1711121	0.14
284.8695984	0.74
287.1223755	5.08
288.1509399	1.75
289.1259766	1.04
290.2305298	0.44
291.3900452	0.04
295.3489380	0.15
297.2211304	0.39
298.2055359	0.11
299.1961060	0.67
300.1970825	0.67
301.1403809	1.72
302.2438049	0.17
303.2763672	0.20
309.0256958	0.12
311.1365356	0.16
312.1860962	0.71
313.0977173	1.67
314.1955872	0.15
316.0750732	100.00
317.1367798	85.29
318.1640625	11.41
319.1760864	0.11
323.3763428	0.02
325.0858154	0.10
327.2852783	0.25
329.1712646	4.36
330.2193604	0.62
331.1464233	0.07
332.2497559	0.04
339.5394287	0.10
341.1492310	1.06
342.0441895	0.12
343.2429199	0.43
348.3751831	0.03
353.2506104	0.31
354.4037476	0.13
355.3162842	0.09
357.1317749	0.23
359.1278076	3.17
360.2440186	0.93
363.0299683	0.08
365.1068115	0.19
369.2996826	0.09
370.2396851	0.09
371.3614502	0.75
372.2722168	0.16
373.2795410	0.11
377.2280884	0.03
378.2556152	0.03
382.1423950	0.11
383.4594116	0.21
384.2919312	0.06
387.2132568	0.04
388.1990967	0.02
389.2231445	0.95
390.2849121	0.10
393.1920166	0.05
397.2606812	0.04
401.0300903	0.26
411.3010864	0.02
413.3069458	0.34
417.3597412	0.05
425.3496094	0.27
426.4434814	0.07
427.2120361	0.15
431.1648560	0.97
432.4412231	0.24
443.2802124	0.17
445.2315674	0.80
446.3942871	0.22
447.2219238	0.05
455.1024780	0.09
456.3504639	0.10
461.2701416	0.28
462.2404785	0.14
463.3579712	0.54
464.5231934	0.10
472.4936523	0.09
473.3027344	0.94
474.4276123	0.26
479.2854004	0.28
480.2960815	0.27
481.1579590	0.29
482.6074829	0.09
483.2434082	0.04
492.2976074	0.10
494.2611694	0.02
497.3987427	0.16
499.2692261	2.19
500.2881470	0.50
501.6714478	0.07
504.8605347	0.03
505.5955200	0.04
515.3091431	0.57
516.1948242	0.07
517.2009277	0.06
521.3324585	0.26
522.3168335	0.07
529.6641235	0.12
534.2806396	0.13
538.0262451	0.09
539.2245483	0.04
540.7157593	0.19
545.3529663	0.02
547.3043823	0.08
549.3524780	0.05
550.0215454	0.03
553.3565674	0.11
557.6429443	0.11
563.5258179	0.04
564.4813843	0.21
565.3045044	0.16
566.3872681	0.12
579.3549194	1.05
580.3540649	0.50
581.3186035	0.36
582.3566284	0.37
588.9543457	0.20
589.7479858	0.27
590.5514526	0.03
595.2086792	0.07
607.2539062	14.80
608.3626709	4.62
611.4801636	0.10
612.2667847	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1405
Annotation	6-Caffeoylsucrose
Peak:m/z	Relative Intensity
147.0536346	0.05
160.9865570	0.61
162.9175415	0.01
179.0723572	9.81
203.1278076	0.44
205.0737915	0.04
207.3838501	0.08
233.2415771	0.02
237.0707245	0.03
243.4186707	0.02
251.0818939	0.08
255.3638000	0.06
257.2160950	0.02
279.0517883	0.06
280.9195862	0.18
283.2437744	0.03
296.0794373	0.03
297.3181152	0.13
301.3457642	0.05
308.3557129	0.03
321.3796692	0.03
323.2805786	1.93
324.2453003	0.07
336.9241638	0.04
339.3696289	0.05
341.1776428	100.00
342.0765686	0.05
343.0629272	0.08
347.3208923	0.03
351.2030640	0.08
358.5545044	0.10
359.3012695	0.07
365.3211060	0.91
367.1598816	0.06
368.1756897	0.03
369.2549744	0.13
371.2960510	0.05
376.2930908	0.03
377.4764099	0.06
383.1876526	0.32
395.1657104	0.18
398.8540344	0.06
412.6992493	0.52
413.4068909	0.62
415.2492981	0.02
432.9900513	0.02
443.2659302	0.54
457.3258362	0.15
458.3046265	0.04
458.9783630	0.06
461.0538635	0.10
463.1441345	0.02
465.3834839	0.02
467.3975220	0.03
472.0970764	0.04
485.1487427	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.161
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
124.9159546	0.08
131.1768951	0.04
135.2811890	0.02
137.2636871	0.07
140.9045410	0.02
143.2178802	0.11
155.0290527	0.03
160.9874573	0.37
167.1824341	0.03
179.3251343	0.07
179.9515533	0.12
181.1236877	0.50
195.1765594	0.05
197.1818085	17.58
205.2383728	0.04
221.2936249	0.02
223.1728821	0.63
228.1364136	0.02
237.3262329	0.03
239.1598511	0.19
241.1118164	100.00
243.0635681	0.22
246.8799438	0.03
265.2565308	0.13
269.3399353	0.14
270.2148743	0.52
271.2428284	2.41
272.1296387	0.09
283.1427002	0.92
294.0315552	0.05
295.3727112	0.02
299.3087769	0.07
301.5132141	0.02
313.1782227	0.38
321.1184998	0.04
322.2800293	0.19
325.1723633	0.06
327.2995605	0.11
341.3728638	0.10
343.2058716	1.95
357.2688904	2.15
358.4760742	0.05
359.1025085	0.02
360.3348999	0.05
375.2717590	1.29
382.3675537	0.11
385.4963074	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1141
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
311.3713379	0.18
341.1890564	100.00
342.1753540	23.95
369.5939941	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.214
Annotation	Glucosylgalactosyl hydroxylysine
Peak:m/z	Relative Intensity
155.0811462	0.28
156.6279297	0.28
167.0366211	0.07
176.0886536	0.17
179.0017242	0.06
185.1093140	0.11
193.1765289	0.72
203.1156311	2.32
204.0018768	0.11
209.0716858	0.11
216.0470886	0.09
229.2288208	0.05
232.0968933	0.09
235.2048035	0.20
238.2223663	0.12
240.9534302	0.10
243.0023956	0.07
245.0365295	1.89
252.3045654	0.57
252.9611816	0.44
259.2996216	0.21
261.4018555	0.05
263.0927734	0.07
265.1929932	0.86
273.2019348	0.24
275.1124573	11.13
276.3025513	1.21
297.1322021	0.28
305.3436584	0.08
306.8482971	0.06
310.2306213	0.08
317.1794434	3.55
318.1967468	0.74
324.9039917	0.32
333.2105713	0.32
335.1734619	100.00
336.2137451	7.24
341.2718811	0.05
351.4424133	0.12
355.2533569	83.71
356.4025574	8.75
363.2847900	0.15
366.3137207	0.12
367.2444458	0.55
374.3406677	0.10
376.3900452	0.21
377.0724182	0.19
378.2318726	0.08
380.0905151	0.41
382.8944397	0.10
385.6534729	0.07
389.1202087	0.05
391.3575745	0.13
392.3443604	0.16
393.2574768	0.06
394.7459412	0.06
399.6118774	0.21
404.9057312	0.05
409.4994812	0.09
410.5791931	0.27
411.4795227	0.52
412.8813782	0.42
414.5584106	0.05
420.3846130	0.29
442.1806335	0.15
442.8002319	0.15
445.1857605	0.06
457.3939514	0.09
459.3019714	0.04
469.1920776	1.49
470.1520386	0.24
477.5434875	1.94
478.4002991	0.37
486.4453735	0.07
487.8415222	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.0181
Annotation	Sulfoquinovose
Peak:m/z	Relative Intensity
68.6972885	0.06
71.0064621	0.06
73.1123581	0.36
80.8917313	4.83
83.0124664	0.22
87.0041275	0.30
95.0808563	0.05
97.1410523	0.07
99.0237579	0.10
101.0354919	5.53
113.0765076	2.21
114.9357605	0.13
122.9098053	11.71
125.0733337	3.02
127.1058044	0.19
132.9664917	0.04
135.0119171	0.23
143.0695648	3.84
147.9452667	0.04
150.8567810	0.26
152.9834442	59.36
160.9636688	0.47
165.0616608	1.37
177.1191254	0.26
179.1538696	0.10
183.0151978	100.00
188.9460754	0.26
194.9902496	0.03
207.0251465	35.37
213.0748596	2.67
225.0984192	12.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.32
Annotation	Hordatine B
Peak:m/z	Relative Intensity
187.2750549	0.05
191.1856384	0.02
203.2167358	0.04
217.0565796	0.05
235.4343719	0.09
241.2811432	0.12
249.1065521	0.06
251.1556091	0.03
266.7526550	0.04
269.4677734	0.05
293.7183228	0.03
295.1229248	0.04
296.4671631	0.04
299.3872070	0.13
301.0928345	0.14
302.2663574	0.07
302.9660034	0.17
312.0285034	0.02
313.0176392	0.15
315.2613525	0.02
318.1643677	0.12
331.2320557	0.03
333.1452026	100.00
333.7839966	0.50
337.4395752	0.15
341.4378662	0.03
345.2283936	0.03
348.9572754	0.06
354.0517578	0.03
357.2019653	0.44
375.2357788	1.24
377.4647827	0.12
379.2806396	0.06
383.3507690	0.03
388.3555298	0.10
393.1036377	0.09
399.1242065	1.00
408.7369385	0.12
411.0281372	0.10
412.4027100	0.08
419.2494507	0.10
423.4197998	0.27
424.5104370	0.06
428.2072754	0.10
431.1342773	0.04
433.3299561	0.07
434.4036255	0.10
439.8752441	0.05
441.2443848	0.99
449.0472412	0.09
451.6201172	0.04
459.2191162	0.19
460.8792114	0.01
476.8434448	0.11
478.6010742	0.05
479.3507690	0.05
483.4493408	0.04
486.3074951	0.08
489.2942505	0.05
491.1088257	0.05
492.1849976	0.07
495.2800903	0.03
499.5477905	0.45
500.5153198	0.28
501.3293457	0.09
505.2435913	0.02
509.1936035	0.07
513.1563721	0.03
515.0695190	0.16
517.0866089	0.15
519.2257690	0.66
520.4122314	0.06
525.5451050	0.12
527.0671997	0.09
533.4246216	0.03
535.0320435	0.07
536.8540649	0.08
538.4859009	0.06
545.1859741	1.01
548.4617920	0.21
551.3548584	0.04
554.5583496	0.05
558.3952026	0.04
563.2521362	7.39
564.2423706	0.25
565.1573486	0.08
572.9461060	0.03
580.1557007	0.06
581.3104248	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.1715
Annotation	Unknow
Peak:m/z	Relative Intensity
205.2060852	0.22
206.9547424	0.33
237.2380829	0.06
285.1644897	0.50
327.2411499	0.47
345.1842651	100.00
346.2680359	10.00
357.4047241	0.16
384.2402344	0.11
395.0522461	0.16
511.5317993	0.07
588.3658447	0.07
617.4798584	0.05
627.1495361	0.34
646.3567505	0.03
671.3043823	0.04
673.3726807	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.1237
Annotation	Villosin B
Peak:m/z	Relative Intensity
82.5648804	0.09
86.9364471	0.36
90.9481811	0.07
96.8530273	0.48
107.1671219	0.23
109.0621490	0.13
111.0751266	0.68
111.8238297	0.11
112.8854523	0.07
116.9756165	0.04
123.1971512	0.75
125.0172424	1.87
135.3999786	0.20
136.0802002	1.40
137.1740417	1.26
139.0392303	12.06
147.0309448	0.42
149.1748962	0.04
151.0516357	28.20
153.0109253	0.20
157.8938904	0.05
158.8932037	0.23
161.0735931	0.54
163.1586456	0.08
165.1234894	0.70
167.0840759	0.43
168.1550903	4.40
169.0208588	15.95
171.0930176	0.37
173.0255432	0.34
173.9555664	0.10
175.1178131	0.64
177.2068024	0.58
179.1972046	0.99
180.1999969	0.29
184.1997070	0.07
187.1990967	21.25
189.2423248	1.79
190.5705261	0.17
191.1982117	1.60
193.2856140	0.20
199.1076355	3.04
200.1750488	0.03
202.2467651	0.61
205.2054443	18.10
207.1852112	0.31
208.0781555	0.04
215.0814819	1.46
217.1271973	100.00
219.0647583	0.68
223.0608521	0.08
231.1665955	0.03
233.2988892	0.77
235.1428833	20.51
237.2422791	0.12
243.2239990	0.18
249.1484680	17.64
251.4029846	0.19
261.1017151	15.24
262.9829712	0.09
264.1616821	1.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	955.3817
Annotation	Unknow
Peak:m/z	Relative Intensity
283.3716125	0.10
291.1319580	0.13
293.2458496	0.10
327.4734802	0.06
335.3239136	0.11
355.1143799	0.11
365.6698303	0.04
372.3379822	0.17
373.1875000	0.10
402.5397339	0.05
409.1796875	0.06
414.2616577	0.15
418.4671631	0.15
458.3395386	0.28
459.4949951	0.26
480.5499878	0.13
490.3726807	0.54
493.7173462	0.04
495.5744019	0.19
496.5676270	0.11
499.3225708	0.03
521.3973389	0.05
537.4690552	1.82
540.1339722	0.14
545.4412842	0.07
547.1799927	0.04
553.2709961	0.05
566.3521729	0.05
581.3771973	3.82
613.3519897	4.16
621.3291016	0.03
625.5352783	0.09
631.6965332	0.16
639.7706909	0.02
647.5685425	0.11
648.2802124	0.02
660.4568481	0.06
701.2112427	0.05
717.1641235	0.06
719.2638550	0.10
721.2984009	0.03
734.7894287	0.04
741.4618530	0.14
743.1913452	0.05
760.6168823	0.04
773.5435791	0.08
774.6637573	0.03
785.3064575	0.06
792.7025757	0.85
800.5321655	0.63
801.4537354	0.42
802.2680054	0.03
803.5838013	0.05
818.9927979	0.08
823.3424683	0.12
832.4230957	1.37
834.4280396	0.30
837.3788452	0.04
848.3540649	0.33
853.0458374	0.04
873.1287842	0.04
875.6170654	0.14
879.5407104	0.03
893.5374756	0.07
894.5676880	0.50
895.5698853	0.06
904.6855469	0.14
905.5234985	0.30
909.5991211	0.07
911.4174805	0.21
921.2529907	0.04
923.5789185	100.00
927.3864136	0.04
936.4755249	0.32
937.5127563	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1018
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
144.9254761	3.82
163.0389099	100.00
192.9967346	0.28
243.19104	0.14
253.3152771	0.09
254.4121399	0.38
267.1602478	0.49
278.8206482	0.64
282.2219849	0.29
309.2585449	0.25
327.3662109	0.61
337.2061157	0.28
339.2243652	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.1123
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
144.7938232	0.02
162.9174805	0.02
180.1356506	0.01
187.0171814	0.09
189.3232727	0.02
199.0411987	0.05
204.6661987	0.01
205.3639221	0.04
223.3968811	0.04
243.3254395	0.02
252.5859070	0.01
258.1122742	0.04
281.1181030	0.11
283.3941956	0.03
297.1500244	0.01
299.0346069	0.04
300.2970581	0.02
301.4619141	0.20
303.1150208	100.00
311.3878784	0.05
314.1421509	0.07
315.3477783	0.02
317.2444153	0.10
323.1909790	0.17
325.5608215	0.03
326.9877014	0.09
332.4289551	0.02
333.4223022	0.04
335.2483826	0.43
345.2536621	0.78
353.0893250	0.17
359.4652405	0.01
369.2376099	0.11
373.3995972	0.02
374.2744141	0.04
376.3356934	0.06
385.1277771	0.03
393.2043457	0.06
395.0120544	0.07
404.7523193	0.07
411.1304016	0.41
411.7673645	0.07
431.2497253	0.02
434.1742249	0.02
437.1471863	0.07
441.2526245	0.04
446.9830017	0.04
453.2008362	0.14
457.1567688	0.02
461.3752747	0.01
463.6204529	0.04
469.0861206	0.02
471.2194214	0.32
475.2760315	0.01
479.2638245	0.10
487.2473755	0.05
489.2647095	1.83
490.0510559	0.04
506.6886902	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	749.3023
Annotation	Unknow
Peak:m/z	Relative Intensity
209.3090057	0.08
225.2210236	0.25
231.3371277	0.04
242.3949890	0.12
249.3372803	0.03
253.1802216	0.05
273.2266235	0.10
310.9887085	0.18
313.2086182	100.00
314.2627563	0.05
315.4211426	0.06
324.3962708	0.04
327.1896362	0.68
329.0105286	0.09
339.3375244	0.50
341.3308105	0.05
343.4810791	0.02
353.2817383	0.02
357.3490601	0.26
367.1771240	1.42
374.4119263	0.12
375.3192749	0.10
378.3237915	0.08
381.5299683	0.14
385.3142700	0.06
386.3576660	0.06
402.2481079	0.12
413.2310791	0.10
417.2649536	0.05
418.4365845	0.03
424.2472534	0.06
426.2213135	0.04
433.1222534	0.02
435.1321411	0.11
457.4832764	0.07
459.3488770	0.07
460.8013916	0.04
463.4308472	0.12
465.4099731	0.04
472.0158081	0.10
473.3369751	0.07
475.6976318	0.04
479.3669434	0.04
485.6980591	0.06
489.2067871	0.09
491.3666992	0.36
493.2512817	0.05
503.4395752	1.16
505.3941650	5.58
507.6644897	0.19
517.5191040	0.03
521.3484497	0.72
522.4447021	0.08
523.1275024	0.07
525.1879883	0.04
525.8931885	0.10
535.4549561	0.19
539.3478394	1.01
545.2671509	0.05
549.2243042	0.07
553.4100952	1.02
555.4749756	0.08
556.4840698	0.24
557.4243774	0.38
561.7112427	0.04
567.2606201	0.08
569.1528931	0.05
570.3328247	0.14
571.2734985	0.03
575.6587524	0.10
584.2991333	0.04
586.1580200	0.62
587.3748169	0.31
595.6717529	0.19
596.4884644	0.05
597.4782715	0.14
598.6531982	0.07
599.2890625	0.20
600.6154785	0.03
601.4847412	0.03
602.2998657	0.03
609.3054199	0.08
610.4360962	0.06
613.0875244	0.08
615.1887207	0.04
616.2311401	0.13
617.9382935	0.08
627.9621582	0.03
630.2835083	0.08
640.7069092	0.05
645.6953735	0.07
651.3174438	0.08
652.3809204	0.03
653.5165405	0.14
659.4002686	0.03
661.4527588	0.06
662.6019897	0.14
663.6923828	0.05
666.5602417	0.10
668.2933960	0.06
686.6210938	0.04
687.3935547	0.14
689.4851685	0.35
691.4121094	0.09
700.6629028	0.68
701.7901001	0.23
702.7222290	0.03
703.5347900	0.08
704.2767944	0.18
705.4479370	0.27
708.5037231	0.04
713.2584229	0.27
716.4705200	0.28
717.2815552	0.09
718.1626587	0.07
719.3797607	0.12
725.9481812	0.31
728.5364380	0.13
729.4669189	0.10
730.2362671	0.20
731.4359131	0.51
733.9330444	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.14
Annotation	Villosin B
Peak:m/z	Relative Intensity
84.9522400	0.20
86.9521866	0.09
94.9204254	0.30
99.0613403	0.33
106.9090500	0.13
108.9995117	0.54
111.1154099	0.22
116.7913284	0.11
118.7569885	0.06
122.9705505	0.15
126.9964600	0.24
132.9708252	0.27
135.0236206	0.39
136.1024475	0.18
143.0200500	0.07
144.8898010	0.09
146.7689819	0.15
148.1221313	0.17
149.0921783	0.27
150.0884705	0.10
151.1562500	0.14
152.1365814	0.30
153.0565796	0.24
154.8552551	0.17
157.1246033	0.22
158.8134460	0.13
160.9192200	0.20
163.0253601	0.23
165.0056000	0.78
168.9179230	0.17
171.1424713	0.36
174.9112854	2.00
178.5530548	0.04
180.1167755	0.05
180.8902130	0.06
182.1166382	1.05
183.0342255	0.09
185.0244446	0.04
186.9747009	0.62
189.1802063	0.13
191.0204773	13.50
192.0410614	0.14
193.5435791	0.26
195.3498535	0.09
197.0969238	0.15
198.9230347	0.63
200.0696411	37.60
201.1496582	0.50
202.9564209	0.26
204.9491272	1.60
206.0465393	0.04
207.0293579	0.82
208.1896057	0.28
209.2252808	0.08
210.2220154	0.16
211.2520447	0.06
213.2487793	0.28
214.1525269	0.26
215.2143860	0.09
217.1607361	0.97
219.2188416	0.77
220.9658203	2.42
223.0306091	1.07
224.1135559	0.09
225.1534729	0.27
227.1511536	0.31
232.9737854	1.08
234.9721375	25.50
235.7478638	0.22
237.2015991	0.82
239.1041565	1.14
240.0769653	0.55
245.1898804	3.33
249.0600586	0.39
251.0898438	100.00
252.3641357	0.05
252.9948120	1.25
260.9981689	0.27
263.0073547	34.79
264.0293579	0.43
265.2282715	0.71
266.6654663	0.06
272.0663452	6.73
272.7987061	0.59
280.1510925	0.07
283.2158813	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9197
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0041199	5.03
159.9378967	0.65
176.0979156	0.07
198.8401947	0.36
228.9417267	1.12
230.1978455	0.07
245.1499176	0.07
257.1693115	0.05
271.1658630	0.26
272.9707642	64.50
274.0161438	17.72
289.0822754	0.11
371.0935669	0.07
385.2679749	0.09
386.9804382	100.00
388.0003967	55.92
410.5836487	0.10
412.3099060	0.11
427.4397888	0.26
428.2493591	0.11
428.8786926	0.25
446.2048645	0.07
456.2843323	0.06
457.5484619	0.29
458.1941833	0.22
474.2944946	0.08
483.8300171	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1302
Annotation	Castamollissin
Peak:m/z	Relative Intensity
163.2306519	0.01
165.1802673	0.02
179.2915955	0.01
189.1535034	0.03
205.2124329	0.02
225.2528229	0.01
227.2530670	0.02
241.1559143	0.07
253.0627136	0.05
254.9420929	0.03
256.0121460	0.04
257.2290344	0.01
259.3711548	0.03
261.1260986	0.04
265.3675537	0.03
270.2097168	0.37
271.3421021	0.08
272.4298096	0.04
283.1207581	0.04
285.1692200	0.48
285.8554688	0.06
287.1729736	0.03
288.2693176	0.02
297.0625916	0.08
298.0606079	0.04
299.1198120	0.40
300.4309692	0.02
301.1250916	0.01
309.4365234	0.02
311.1845093	0.01
313.2172241	0.74
314.2472534	2.28
315.2931519	0.02
327.1275635	0.67
329.1140747	100.00
330.2109375	0.17
331.2266235	0.79
341.3034668	0.20
343.2189331	0.68
345.1475220	0.03
353.0642090	0.12
355.3489380	0.07
369.2501221	0.02
371.1660767	0.56
371.7764282	0.02
373.4353638	0.02
379.2170410	0.01
383.1890869	0.03
395.4067993	0.01
399.2286987	0.01
401.3124390	0.52
413.2202148	0.07
457.3764648	0.03
473.2905273	0.31
487.2285156	0.03
489.1876831	0.01
491.1685791	0.16
501.3734741	0.01
515.3779907	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.0276
Annotation	Unknow
Peak:m/z	Relative Intensity
106.8594971	0.04
108.1114044	0.07
110.8479614	0.03
122.1123047	0.01
122.9341202	0.02
124.1134949	0.03
124.9694672	0.02
136.2882080	0.06
138.2563477	0.01
146.1152344	0.05
147.9903564	0.03
149.9825134	0.02
151.0155640	0.33
157.9492035	0.04
161.2424927	0.01
163.1053162	0.20
164.0113831	0.10
165.2639160	0.02
171.0383606	0.03
172.0867462	0.09
174.0750732	0.02
175.0671997	0.02
182.1037140	0.01
190.1023865	0.17
190.8922424	0.11
199.3067627	0.08
200.0363464	0.05
203.1380920	0.04
204.1916809	0.04
211.1789551	0.05
212.1839600	0.04
215.3164062	0.03
216.1694641	0.15
225.9903259	0.93
227.1301575	1.07
228.1417236	0.29
230.1603088	0.12
237.4074402	0.08
238.1421204	0.07
240.3069153	0.10
241.1025085	0.02
243.0697021	2.80
244.2388611	0.67
246.2939148	0.01
254.1473999	7.14
255.0990906	55.11
256.2130737	0.45
257.0708618	0.02
258.3303223	0.09
269.1863098	0.02
271.0706177	100.00
272.1856079	6.76
281.3230591	0.37
282.3483887	0.04
283.1868896	0.17
284.1658936	0.52
285.0256042	0.05
300.0690918	0.30
301.0435181	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	438.9795
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0487976	0.04
183.1523743	0.02
190.9472809	0.03
197.0615692	0.06
199.0316467	0.07
200.9783936	0.07
202.9787903	0.03
213.1775208	0.02
215.3737793	0.05
218.7102661	0.02
227.0243225	0.03
228.8679657	0.10
242.7867126	0.04
244.9806213	0.12
246.9283752	0.02
260.2093811	0.02
267.2621460	0.02
270.9577942	0.82
272.8381348	0.04
274.1299438	0.02
274.9273987	0.04
276.1388245	0.48
277.3283997	0.21
287.0421448	0.35
288.4772339	0.02
289.1226196	0.17
304.9865112	2.36
306.2136536	0.06
307.0831299	0.61
314.9929810	1.20
316.9066467	0.05
319.2873535	0.02
333.0657043	7.33
335.0360718	0.86
338.3500061	0.04
341.3102722	0.02
343.2537231	0.01
347.9453735	0.05
349.1072693	0.52
359.0794983	0.72
363.3804932	0.02
367.9706116	0.07
371.0306091	0.09
375.0498047	0.04
376.9703979	5.14
378.3045349	0.02
379.1085205	0.12
384.9393311	0.24
394.0890808	5.11
395.0787659	3.10
403.0345154	11.35
421.0053406	100.00
439.5832214	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.4036
Annotation	Unknow
Peak:m/z	Relative Intensity
300.9104919	0.02
316.9966431	0.02
379.3059082	0.11
383.9147339	0.03
386.3279114	0.19
400.4514771	0.02
403.2587891	0.05
414.7096558	0.06
442.3347778	0.02
452.5757141	0.03
456.2188721	0.02
459.4804077	0.07
460.5107422	0.02
461.6698303	0.02
463.0870667	0.06
464.4810791	0.02
473.4208679	0.04
475.4537964	0.07
476.1224365	0.03
477.7662964	0.04
483.4160767	0.02
485.5639648	0.01
495.3781738	0.01
503.5565491	0.04
519.6967163	0.08
520.6325073	0.07
533.1081543	0.03
535.4792480	0.20
537.3547363	0.62
552.5054321	0.04
555.3977051	0.17
557.3875732	0.02
563.3705444	0.63
564.6412354	0.11
566.3760986	0.18
573.4056396	0.06
578.5429688	0.04
581.4929199	1.65
584.5268555	0.03
585.5693359	0.05
587.1838379	0.07
594.3035889	0.04
595.5810547	0.05
597.2937012	0.07
599.3913574	0.02
605.4439697	0.11
609.1016846	0.08
613.3664551	0.11
614.4538574	0.09
619.2152710	0.09
620.5283813	0.68
621.5666504	0.03
623.3548584	0.26
624.4243164	0.04
625.1548462	0.01
627.5679932	0.04
629.3405762	0.04
635.8427734	0.04
637.2358398	0.05
639.4079590	0.02
645.4559937	0.10
646.5543213	0.06
650.5877686	0.04
651.3572388	0.03
653.4597168	0.03
655.5194702	0.11
662.4326172	0.23
663.4323120	0.22
664.4464722	0.05
667.3709717	0.05
668.3238525	0.10
672.4329834	0.07
680.5467529	0.02
681.5879517	0.06
683.2415161	0.16
687.5036011	0.16
690.2475586	0.05
708.5927734	0.18
709.3966064	0.06
710.1493530	0.09
711.5966187	0.03
712.6168823	0.03
715.5460205	0.04
717.5817871	0.19
719.4471436	0.02
726.0759277	0.04
727.5003662	0.04
728.3559570	0.03
735.4745483	0.02
737.3679810	0.04
740.3969116	0.01
743.4111328	3.49
746.3145142	0.02
758.4683838	0.18
759.7498169	0.03
761.4166260	1.41
763.3768311	0.04
769.8316650	0.03
770.4998779	0.06
775.4234619	0.07
787.5002441	0.12
790.4602051	0.04
793.5582275	0.20
800.0701904	0.11
800.7136230	0.03
801.8229980	0.07
803.2883301	0.04
805.0722656	0.03
813.4508057	0.25
815.5841064	0.02
820.0617676	0.19
821.4234619	0.02
822.1215820	0.08
826.3742676	0.05
831.4519043	10.27
832.2558594	0.06
834.5941162	0.04
835.6357422	0.21
838.4113770	0.04
839.3618164	0.39
841.3729248	0.02
845.3848877	0.39
848.5062256	1.44
849.4478760	0.10
861.0532227	0.15
862.8422852	0.22
863.5305176	4.77
867.6397705	0.06
871.3881836	0.12
873.7126465	0.02
875.5986328	0.23
876.7860107	0.17
881.0428467	0.13
881.6523438	0.05
887.2316895	0.01
888.4241943	0.22
889.4844971	1.03
907.6156006	0.12
908.6916504	0.06
911.4714355	0.16
920.5673828	0.67
921.5715332	0.14
922.2548828	0.02
923.5622559	0.68
943.6556396	0.05
949.6911621	0.03
951.7459717	0.02
961.6235352	0.05
964.4770508	0.04
967.4061279	0.24
969.6971436	0.13
970.6300049	0.23
981.4720459	0.02
982.1752930	0.03
983.5128174	0.12
993.5870361	1.18
1008.8955080	0.12
1011.4892580	100.00
1012.1296390	0.36
1013.8061520	0.13
1024.9656980	1.36
1025.6552730	0.88
1026.7646480	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.0758
Annotation	Beta-Citryl-L-glutamic acid
Peak:m/z	Relative Intensity
93.1013489	0.12
102.0375214	0.14
120.7743225	0.14
121.8994293	0.10
129.9873352	100.00
134.0453644	0.14
139.1871948	0.05
148.9236145	0.25
158.9779663	0.14
162.0396271	0.50
175.9735107	17.67
179.0615540	0.84
184.0228577	0.14
189.0343475	0.51
193.0049133	32.75
205.3037415	0.06
210.1764221	0.10
218.9399109	0.12
225.1683960	0.09
229.0225525	0.85
232.1238403	1.19
232.9154663	1.00
235.0606995	0.07
247.1129150	2.58
249.0896606	0.18
250.5644226	0.11
251.2460938	0.10
256.5835571	0.34
257.2301636	0.24
258.2582397	0.18
259.0915527	0.27
260.2397156	0.36
261.1354980	0.10
265.3117676	0.12
266.4218750	0.09
274.3339844	0.14
275.9231262	0.65
278.2429199	1.19
279.0620422	0.08
280.0847168	0.22
283.9797668	0.40
285.0426331	0.53
286.2488098	0.57
291.4327698	0.18
303.0599365	1.81
304.2132568	4.89
305.4393005	0.14
308.6682129	0.07
313.4276123	0.40
314.2697144	0.12
321.2223511	0.23
334.9167786	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	337.0911
Annotation	Scopolin
Peak:m/z	Relative Intensity
105.2808685	0.08
106.8861542	0.12
117.1183624	0.04
123.0276031	0.06
135.1342468	0.13
138.9779968	0.51
143.0623169	0.04
144.9736633	1.86
147.0191650	0.07
156.2043457	0.08
156.9733582	0.33
159.0218658	0.04
162.9497986	100.00
168.0214691	0.17
171.2423706	0.09
174.0773621	0.26
181.0185547	1.88
191.5605164	0.09
201.3450317	0.10
204.0829315	0.28
222.9362183	0.37
229.0225830	0.14
231.3104248	0.05
234.8100891	0.10
241.1803284	0.03
246.8356323	0.25
249.0485840	0.07
257.1910706	0.18
265.1836853	0.10
271.1358643	0.03
273.2203979	0.16
274.2081604	0.04
277.1205139	0.04
283.1757202	0.04
287.0037231	0.07
290.3168945	0.10
291.1775208	0.26
301.0222168	0.66
306.1523132	0.04
313.5339966	0.06
318.3727722	0.17
319.2660522	1.44
320.9835510	0.12
329.0820618	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.102
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8544846	0.08
138.9905090	0.09
147.2147522	0.07
153.0176239	1.32
153.8695984	0.08
162.9414673	0.26
164.2926025	0.11
169.8168182	0.06
175.0859375	0.08
189.0931396	0.06
193.1111755	0.63
195.0302124	0.89
207.2599640	0.08
209.1248474	0.07
216.8953552	0.05
223.1054688	0.48
227.1974030	0.07
229.0587158	2.20
236.0569763	0.09
237.1458740	0.14
239.0789795	0.18
241.1239014	6.16
243.0473022	0.28
247.2971497	0.07
259.0214844	0.54
261.1340942	0.20
263.2100525	0.08
265.2123413	0.07
271.0974426	0.14
271.9939880	0.26
273.1628113	0.18
283.2561951	0.06
285.1078186	0.16
287.0929871	20.77
288.1587219	45.70
289.1388245	46.52
290.1397705	56.03
291.2118225	5.32
301.2228394	0.41
303.1477661	2.32
306.1423035	0.24
307.1877136	0.09
309.1647644	0.29
315.2532959	0.89
319.3454590	0.13
321.0941162	100.00
325.0651245	0.09
326.1407166	0.35
327.1467590	0.79
330.0363159	0.32
333.3612671	0.18
339.2606201	0.12
341.0108643	0.03
345.1558533	4.66
347.9541016	0.21
350.9462280	0.14
353.2962341	0.07
363.1452026	1.86
369.0657959	3.13
371.1636963	0.51
372.0707092	0.08
373.1672668	0.13
374.9952698	1.17
376.2081604	0.30
380.3545532	0.31
381.3138123	0.75
387.1205750	12.87
389.1192627	0.13
396.1988831	0.11
399.1176758	3.05
405.4796448	0.07
406.4907227	0.07
407.1958008	0.11
409.2599792	0.17
415.1376953	0.06
417.1406555	11.99
417.7612915	0.04
420.3746948	0.04
435.1547546	77.04
435.7647400	0.29
444.3319702	0.13
452.1001892	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.0467
Annotation	SC-58125
Peak:m/z	Relative Intensity
108.9440460	0.08
113.1321030	0.04
126.9795914	0.18
130.1423035	0.06
133.1906738	0.17
134.0958405	0.41
146.0078430	0.08
147.0856934	0.02
160.8971558	0.12
172.9898376	1.55
175.0663147	0.11
177.3045044	0.03
179.1032104	0.03
181.1360474	0.03
188.0945892	0.09
191.0097198	100.00
203.1011658	0.18
205.1186829	0.03
207.0197906	0.08
209.2547455	0.06
221.2443695	0.05
226.8536987	0.08
245.1814270	0.19
247.0161438	0.11
247.9645081	0.05
263.0083008	0.25
267.2037048	5.78
275.1867065	0.06
280.0123291	0.06
285.1775208	0.19
293.2412720	0.65
297.2035217	0.13
305.1912537	0.11
311.0235291	0.06
320.9223633	0.02
323.2276306	1.16
324.9084473	0.07
336.9837036	0.28
339.2816162	0.27
341.2241211	1.67
345.3692017	0.03
347.0026550	3.21
352.0998840	0.05
353.4455261	0.13
360.7447815	0.08
364.9467773	21.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1353
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.2900391	0.04
167.1029358	0.07
174.7614136	0.02
176.3068085	0.06
177.1540527	0.07
179.1266174	0.22
187.0852509	0.15
188.1405334	0.10
200.9085999	0.08
203.1018829	0.31
205.0804901	0.50
219.0836487	0.09
224.3082428	0.04
225.0384827	0.03
227.1983032	0.17
229.3047791	0.06
230.9700928	0.06
237.2257080	0.08
241.1990662	0.04
242.8848724	0.41
243.6104736	0.04
245.1283875	3.32
246.3961792	0.09
247.3082428	0.03
255.3311005	0.12
257.1574402	0.16
259.2508850	0.03
261.2331543	0.17
267.3125000	0.19
269.1401367	0.26
271.0770874	0.04
273.1736450	2.14
275.3020020	0.10
283.2224731	0.07
287.2166138	13.86
289.0850220	21.04
290.0961914	0.03
291.3260498	0.06
299.2653198	4.64
300.9499817	0.21
305.3062134	0.04
322.8986206	0.04
325.1908569	0.08
327.3349609	0.03
329.2476196	0.99
330.2742920	0.06
331.2362061	0.51
339.3417358	0.38
341.2664795	0.19
344.4806519	0.11
351.2509155	0.09
355.3223877	0.04
357.2001953	0.23
363.2430420	0.03
367.1418457	0.05
369.2835693	0.04
381.0980835	1.01
384.2839966	0.07
385.3578491	0.07
387.3164673	0.04
389.3924561	0.09
390.6932373	0.20
396.2748413	0.15
399.3485718	0.10
407.2870483	52.14
409.3211060	0.69
411.3104858	0.37
413.3251953	0.71
415.2375488	1.95
415.8653564	0.47
423.3264771	0.39
425.2145996	100.00
432.2531738	0.12
433.3614502	0.62
436.1093140	0.45
437.4682617	0.22
438.2276611	0.04
439.1901855	0.38
445.0441895	0.03
447.3953857	1.43
448.5488892	0.13
449.3372803	0.97
451.2126465	26.27
452.3494873	0.47
453.0281982	0.03
454.2862549	0.47
455.6079102	0.15
460.3467407	0.16
463.2584839	0.03
466.2373657	0.11
467.3311157	1.06
468.2714233	0.05
471.6197510	0.04
475.2070312	0.05
479.3236084	0.20
480.5519409	0.15
482.7761841	0.24
484.3707275	0.03
485.1542358	0.20
487.1506348	0.04
489.2200317	0.11
491.4694214	3.18
492.3897095	0.11
500.4379272	5.19
501.3577271	1.03
503.7905273	0.14
505.3276978	0.11
509.0426636	0.04
512.2815552	0.09
513.9096069	0.86
515.3180542	0.16
516.0658569	0.08
517.2826538	0.03
519.4023438	0.06
521.8808594	0.21
529.4086914	0.15
530.7323608	1.03
531.3850708	3.28
532.3458252	0.34
533.2166748	1.58
539.3740234	0.35
540.3385620	0.21
544.4072266	0.06
545.9785156	0.49
547.2829590	0.35
554.3347168	0.06
557.2460327	0.16
558.7435913	1.48
559.3895264	7.17
561.5682983	0.13
563.2952881	0.11
567.6209717	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0026
Annotation	SC-58125
Peak:m/z	Relative Intensity
129.0156555	0.14
172.9873047	1.58
191.0666504	100.00
206.9410095	0.05
213.0205994	0.80
235.4026794	0.06
241.0505981	0.10
255.0048828	0.37
261.5216370	0.06
271.2379456	0.05
273.0369568	3.03
280.2675781	0.18
289.0673828	0.25
299.0679321	1.29
305.2263794	0.23
317.1141357	7.12
322.3087463	0.12
347.1631470	0.08
357.2027893	0.07
358.9897461	1.07
384.8298950	0.45
403.1183167	16.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.3486
Annotation	Argenteanol C
Peak:m/z	Relative Intensity
149.1223755	0.10
204.9933167	0.08
217.2512512	0.21
218.9035645	0.05
257.4219971	0.07
273.1901550	0.09
297.2517090	0.40
343.4060059	0.12
351.3495483	0.47
353.4695435	1.32
355.3098755	0.34
369.4857788	0.40
372.4835205	0.10
373.5665283	0.06
375.2088013	0.10
377.5580139	0.14
391.2006531	0.18
393.5665894	0.58
397.7908936	0.27
403.4157410	0.13
405.6404724	0.14
407.5791321	6.01
409.5946960	12.87
411.5013733	5.73
412.3312073	0.15
413.1607056	0.04
423.4051208	0.54
424.8293152	0.25
425.5115662	0.76
426.2998962	0.09
427.5790100	2.99
429.5385437	0.08
434.7514954	0.19
435.5887756	0.44
437.7347412	0.08
440.6001282	0.19
441.6077576	0.20
451.5320740	4.60
453.4803162	100.00
454.3529358	0.04
455.5109863	0.20
470.1495056	0.16
471.0544739	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1517
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9951019	0.78
172.7264862	0.24
179.0109558	0.74
181.0395660	1.29
182.8703156	0.25
201.1345367	1.02
205.2174988	0.27
213.9249573	0.25
229.1149445	0.58
247.0726013	6.67
258.0263367	0.69
259.2323303	1.32
261.1093140	1.34
268.2575684	1.09
271.0924683	3.12
273.1589050	2.61
275.2053223	2.82
283.1311951	0.51
285.0785522	1.55
287.1386108	3.14
288.9544678	11.07
291.2401733	21.84
294.5899658	1.28
299.1426392	0.22
300.9965820	12.18
303.1265564	1.38
313.2256470	4.26
325.6545410	0.75
331.2041626	100.00
333.1218262	0.17
345.4185791	0.46
348.2852783	0.36
372.9776611	0.28
391.2832642	0.48
405.4711304	0.64
409.2398071	31.01
410.0828857	0.25
411.0949097	8.38
416.2331543	0.51
419.1694336	0.36
421.2265625	0.31
423.0606689	0.84
427.1120605	22.48
435.2570801	4.75
437.2614136	0.47
439.1911011	5.48
451.5379028	0.35
452.6710815	2.20
453.2728271	15.18
454.4093018	2.57
487.4301758	1.80
488.2609863	1.00
489.2472534	2.05
491.5105591	0.28
492.4553833	0.58
493.2091675	1.73
516.6886597	0.42
522.0889893	0.51
523.2129517	0.25
533.3367310	1.95
535.4475098	2.36
537.3339844	0.59
543.6449585	1.65
548.1365356	0.50
559.3110962	1.02
560.5392456	4.15
561.3207397	17.82
570.4641724	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2289
Annotation	Ssioriside
Peak:m/z	Relative Intensity
163.2776794	0.04
165.0454712	0.06
175.0140381	0.02
177.2246552	0.03
179.1247406	0.06
180.1173096	0.06
191.1533203	0.04
192.0416718	0.05
195.2279663	0.20
207.0646210	0.10
209.1136322	0.07
219.8554077	0.03
225.1398468	0.34
227.1523132	0.06
249.2020569	0.03
250.1415710	0.06
251.2189331	0.02
257.3009949	0.03
271.0889587	0.01
275.4640503	0.06
286.1755981	0.02
297.3179932	0.02
301.3215027	0.06
303.2768250	0.02
304.3545532	0.02
311.5809937	0.03
312.3441162	0.03
313.1134644	0.05
327.3273926	4.09
329.0540771	0.13
330.2201538	0.16
331.2460327	0.10
341.3151855	0.16
342.2413940	0.11
343.2636108	0.36
345.1885986	0.99
347.2777710	0.15
348.2444458	0.25
349.3206177	0.08
353.2098389	0.16
355.2526245	0.04
359.5367432	0.01
361.1487427	0.06
372.7163696	0.05
373.3977051	0.63
381.2415161	0.62
387.0050659	0.03
388.4684448	0.06
390.3504028	0.13
391.1164551	0.18
391.8846436	0.02
396.1713257	0.02
397.2874756	0.19
398.1288452	0.15
399.1486206	0.04
403.4508667	0.29
406.4228516	0.09
410.1938477	0.02
421.3893433	3.15
430.0310059	0.02
431.2517090	0.22
432.3850708	0.02
434.3046875	0.07
437.3291626	0.03
443.6837769	0.05
447.4356689	0.10
457.3908081	0.02
462.3779297	0.04
463.3970947	0.40
466.4934692	0.03
467.3656616	0.03
476.5421753	0.11
477.5730591	0.02
478.5314941	0.04
485.4928589	0.17
487.3995972	0.15
489.1370239	0.18
492.6001587	0.06
493.4422607	0.16
502.2853394	0.17
505.3187866	100.00
506.4040527	1.33
507.4272461	2.11
509.3712769	0.19
517.1499634	1.58
517.8870239	0.05
521.1452026	0.03
523.7634888	0.07
525.1046753	0.02
532.6692505	0.11
533.3424683	0.03
534.1967163	0.40
535.3213501	2.63
536.2219849	0.01
538.5942993	0.09
539.2098999	0.07
543.5732422	0.05
544.3876953	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.26
Annotation	Elaphopilosin B
Peak:m/z	Relative Intensity
177.1534424	0.21
184.1266785	0.07
184.9511261	0.07
192.9641418	0.19
207.0674133	0.11
229.2411194	0.20
238.9648438	0.05
255.0403442	0.07
269.4188843	0.07
281.0030518	0.08
284.0505371	0.14
285.2117920	0.09
287.2278442	100.00
290.9407654	0.28
303.0987549	0.57
305.1670532	0.07
307.4932251	0.15
311.1406250	0.13
313.1485596	0.37
322.2205811	0.07
325.3854370	0.17
326.8364868	0.05
331.2663574	0.07
337.5421143	0.22
339.2380371	0.35
341.4093018	0.18
345.1939087	0.08
347.1612549	1.61
359.1233521	0.09
368.7879639	0.08
371.0419312	0.38
381.3634644	0.04
388.2391357	0.09
389.2395630	0.20
395.1330566	0.22
403.0685425	0.07
418.4714355	0.58
427.2725830	0.06
448.0490723	0.09
449.1788330	0.20
453.5327759	0.53
455.3449097	0.10
471.4341431	0.23
480.1810303	0.15
481.2819824	0.08
485.3812256	0.09
489.2117310	0.80
491.5393677	0.41
493.2163696	0.10
494.0814209	0.08
497.3402710	0.04
503.6465454	0.15
505.2808228	0.91
506.0825195	0.07
507.2164307	0.17
515.2236938	0.92
519.1503906	0.19
522.4948120	0.10
533.2218628	3.23
533.9425659	0.11
541.7334595	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	436.2171
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
130.3353271	0.72
134.9640198	8.17
147.1658478	0.30
153.1030579	100.00
170.6248474	7.44
181.1423187	0.30
204.3936005	0.53
217.9534302	0.19
230.2760925	1.66
249.0748596	4.04
253.3418274	1.06
257.1678467	0.72
261.1214905	0.33
267.3444824	0.39
273.3601685	4.44
274.2225342	4.48
279.2513428	0.48
293.2526245	0.51
303.0620728	3.92
304.1404114	5.66
304.9510498	3.20
329.3819580	0.56
335.4199219	0.30
343.2813416	0.87
346.4588928	0.73
351.3908081	0.89
362.2623596	0.30
365.3280640	0.98
380.8460388	0.47
382.6205750	6.67
383.2552795	2.05
391.1251221	1.04
408.4147034	0.22
418.7868958	96.00
419.6705627	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
154.7721710	0.02
158.9875336	0.41
175.0094604	0.39
199.1358032	0.34
217.0723572	0.15
229.1717987	0.12
233.0746765	0.04
245.1447449	0.20
272.9801025	5.76
289.1206665	9.15
387.0715942	0.63
400.3011475	0.04
401.0341797	0.04
402.9833984	100.00
403.5862427	0.12
415.2225952	0.10
442.2562866	0.06
443.0614014	0.12
471.3464966	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	495.1123
Annotation	Quercetagetin 7-methyl ether 6-glucoside
Peak:m/z	Relative Intensity
153.0525360	0.63
170.5806580	0.16
194.1737366	0.04
227.1380463	0.04
231.3452148	0.04
258.5586243	0.10
271.3370972	0.03
284.8920288	0.07
288.7092896	0.04
291.3218384	0.07
294.9443970	0.07
300.1406860	0.03
303.4168701	0.10
315.0981445	0.04
321.1493225	0.06
331.2159424	0.37
333.1234131	100.00
334.2279053	15.06
343.2353821	0.05
344.2830505	0.03
345.2294006	0.13
357.2239075	0.14
358.1776428	0.12
363.2429810	0.09
375.1530151	1.51
376.0801392	0.34
385.2996521	0.05
387.1632996	0.09
391.1702881	0.04
399.1957703	1.33
400.2608337	0.42
411.3150940	0.07
412.2732849	0.03
417.6940613	0.02
424.1316833	0.02
425.9731140	0.11
429.1397705	1.00
430.3100891	0.34
441.1934814	0.49
442.1376648	0.21
447.0071716	0.03
459.1255188	1.05
460.1598816	0.21
465.1727905	0.08
467.4584656	0.10
477.1715393	3.19
478.3082581	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	631.2765
Annotation	Dysinosin A
Peak:m/z	Relative Intensity
191.1423645	0.04
202.0667419	0.21
229.1742249	0.05
241.4933929	0.06
275.1696472	0.09
282.9223022	0.09
286.1005249	0.04
286.9457397	0.08
293.5314941	0.09
299.2203369	0.06
301.3648682	0.27
302.2778015	0.18
311.4441833	0.10
313.0513916	0.22
335.3198853	0.05
343.2754517	0.03
345.3674927	0.04
352.8349609	0.18
354.5863647	0.09
357.2672119	0.11
372.5274658	0.15
377.3906250	0.08
382.4782715	0.26
390.4453735	0.22
391.5150146	0.58
399.3128662	0.19
414.7301025	0.39
417.1536865	0.13
419.4800415	0.06
421.5249023	0.09
432.2164917	1.40
433.3436890	0.35
436.3709106	0.17
437.2783203	0.10
438.3932495	0.06
443.3507690	0.05
446.3473511	0.17
449.4802856	0.12
451.3602295	0.27
458.5547485	0.22
462.5896606	0.04
463.2309570	0.30
464.2441406	0.37
476.3710327	5.16
477.4010010	2.21
478.3394165	0.37
479.3662720	0.19
482.3100586	0.06
490.3388672	0.82
491.2285767	0.21
492.2783203	0.08
493.3744507	0.08
495.4155884	0.60
496.3925781	0.88
497.4551392	0.30
500.1891479	0.13
508.3220215	37.04
509.3965454	17.03
510.5470581	0.27
511.8339233	0.17
512.8022461	0.08
513.4689331	0.36
514.4589233	0.51
525.3428345	1.03
526.3719482	0.19
527.4598389	0.10
532.3897705	0.15
537.4271240	4.83
538.4745483	3.84
539.1720581	0.07
540.1912842	0.41
546.3054810	0.08
551.3888550	0.06
555.4651489	18.77
556.5285034	10.35
557.3366699	0.04
558.5219116	0.23
559.5116577	0.27
563.3293457	0.08
568.8336792	0.07
569.8162842	1.31
570.6414795	0.10
571.6178589	0.15
581.4773560	4.43
582.4613037	3.15
583.1152954	0.06
584.2824097	0.22
585.4791260	0.35
586.4447632	0.19
587.2739868	0.16
587.9121094	0.12
589.9305420	0.09
594.2440186	0.34
596.1109009	0.12
599.3953857	100.00
600.3655396	49.94
601.3851318	1.82
602.4113159	0.73
603.2195435	0.25
613.3208618	6.93
614.3273926	3.24
615.8817139	0.19
617.2283325	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1249
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9892578	0.12
163.0400391	0.18
164.1412659	0.05
165.0395660	0.06
166.0090179	0.22
168.9334717	0.05
171.1163635	0.05
174.8994446	0.04
179.1526489	0.18
181.0646362	0.30
182.9479370	0.07
188.1226196	0.09
189.0786133	0.25
190.0605011	0.20
190.9184113	0.11
192.1022339	0.24
193.2121582	0.07
197.4189911	0.07
202.1126404	0.16
204.0998077	0.10
205.0926971	0.15
205.9472351	0.06
215.3134460	0.06
216.3543549	0.08
219.1322784	0.64
219.9383240	0.11
221.2824707	0.12
221.9579773	0.04
223.2429352	0.09
231.1270447	0.49
231.9169006	0.09
233.3228149	0.11
234.2106171	1.31
235.1411896	0.99
237.1620789	0.05
238.7538452	0.09
241.1410370	1.13
242.1701355	0.85
243.2070618	0.29
245.2476654	0.04
246.9362030	0.21
248.3778992	0.06
250.0834045	0.13
251.2281494	0.06
255.6328125	0.24
257.1923523	0.40
258.3080750	0.53
259.1045532	0.31
261.3153687	0.14
262.3467712	0.08
263.2526245	0.05
265.4158325	0.04
267.3725586	0.05
268.0755920	0.08
269.0101929	0.53
270.1328125	1.38
270.8909912	0.26
272.1011353	0.13
273.1120605	4.93
274.1619263	0.06
275.1413574	0.29
277.3092041	0.25
284.1433105	0.16
285.0907593	0.84
286.0698242	0.55
287.1298828	1.58
288.4063721	0.14
289.0212402	0.09
291.1892090	0.30
293.2415466	0.22
295.2539062	0.04
297.1633911	0.34
298.2675781	0.10
299.2597656	0.38
300.3851318	1.53
301.2365112	7.07
302.0948792	0.47
303.1738892	1.92
304.9949341	0.15
309.2854004	0.22
311.0896606	0.56
312.3011475	0.25
313.1383667	0.58
314.6054688	0.42
315.2393188	4.11
316.1524048	6.49
317.1704712	0.67
319.2999268	0.43
324.8491211	0.11
326.7611084	0.50
327.4436646	0.11
329.1362305	8.54
330.1847534	3.51
331.1105347	0.27
338.2253418	0.13
339.2183838	0.14
340.4681396	0.13
341.2564697	0.59
342.2308960	0.16
344.1254883	100.00
345.1571655	39.63
345.9185791	0.48
346.5275879	0.10
350.4328613	0.13
355.0435181	0.39
356.3442383	0.31
357.2080688	1.07
359.2343140	5.31
360.3743896	0.11
361.4623413	0.23
365.1931763	0.20
367.3256836	0.60
369.3497925	0.55
371.4420776	0.26
372.2246704	0.91
373.3942871	0.54
374.0088501	0.17
375.2990112	0.08
379.4683838	0.06
382.3370972	0.09
384.7008057	0.08
387.1566772	25.21
387.9603271	0.88
395.0242310	0.09
399.3742676	0.50
400.2505493	0.14
402.3767090	0.17
405.3179321	0.09
411.2598267	0.05
416.4768677	0.04
417.2344360	2.23
418.3447876	0.06
425.2767334	0.14
427.2587280	0.14
429.3293457	0.08
430.6311646	0.06
444.1097412	0.12
453.5313110	0.07
458.2986450	0.13
459.3234863	0.19
459.9590454	0.17
461.2443848	0.25
462.4971924	0.08
463.4188232	0.35
465.7116699	0.09
468.1647949	0.36
471.0979004	0.16
472.4254761	0.14
473.3630981	0.16
476.4357910	0.05
479.4649658	0.04
481.0883179	0.04
485.6375122	0.07
487.5219116	0.43
489.2510986	2.69
499.2793579	0.06
501.5090942	1.11
502.4255981	4.64
503.2881470	2.82
504.6141357	0.43
505.5179443	1.41
507.3743286	0.23
510.6827393	0.08
517.1995239	0.35
519.5231934	0.13
521.3129272	1.14
522.4520874	0.05
526.7749634	0.05
528.2545776	0.69
529.4015503	0.32
531.3187866	0.48
534.2061157	1.16
535.3161011	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.107
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
145.1842651	0.01
180.9847412	0.03
193.2474670	0.01
195.0070038	0.03
209.1020813	0.06
225.9166718	0.04
233.1465454	0.07
241.3641663	0.03
247.1550293	0.03
256.2785645	0.04
265.0253906	0.02
273.3534851	0.04
275.1214600	0.03
283.1836243	0.02
284.2544556	0.04
287.2147217	6.38
305.0647583	0.04
317.1376648	100.00
317.7506104	0.13
319.4218140	0.01
323.3080444	0.06
343.4601440	0.01
346.1963196	0.02
348.3887939	0.04
351.3420410	0.09
353.2352295	0.01
362.2953796	0.02
365.2827759	0.09
371.4334106	0.02
377.1436462	0.02
394.9265747	0.09
403.2116089	0.08
413.3762512	0.08
431.2536926	0.23
432.2832947	0.10
449.1276855	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.3438
Annotation	Unknow
Peak:m/z	Relative Intensity
241.1260071	2.87
253.3534241	0.07
255.3779907	2.23
256.4105225	0.56
259.0603638	0.19
277.3981934	0.88
278.3170166	0.24
281.5350952	0.04
287.1323547	0.09
297.1817932	1.05
298.2954102	0.10
307.1221313	0.14
315.4223633	0.11
337.3285217	0.06
345.6258545	0.08
356.9274292	0.18
371.3768311	0.13
385.3235474	0.15
391.2918701	4.05
392.3613281	0.27
396.3359375	0.08
413.3572998	0.65
414.4526367	0.54
425.0483398	0.05
428.5908203	0.20
429.2938232	1.50
430.2719727	0.46
441.2855225	0.97
442.3714600	0.22
443.5701904	0.81
444.3569336	0.40
455.3828735	0.67
459.3056030	0.42
475.6062622	0.07
497.5941162	0.08
501.5767822	0.20
539.4704590	0.15
553.4050293	7.75
554.4983521	1.88
555.3743896	0.09
565.1763306	0.05
567.3511963	0.43
571.4401855	1.62
572.5832520	0.28
575.4157104	0.46
576.2959595	0.59
585.3158569	0.07
593.3398438	0.56
594.7525635	0.16
602.3759155	0.27
608.6884766	0.22
619.4736328	0.12
621.4458618	0.16
631.8156128	0.19
637.5937500	0.17
640.5209351	0.27
643.1165161	0.05
652.7581177	0.24
667.8121948	0.19
669.3098755	100.00
670.3358154	11.88
681.4620361	0.18
682.6987305	0.05
687.0290527	0.27
692.1588745	0.23
699.5314331	0.16
701.9592285	0.08
709.2630005	1.18
710.3250732	0.15
711.4038696	0.08
727.3758545	0.06
729.2510986	0.17
744.9426880	0.58
747.6175537	0.20
753.2201538	0.12
754.6456909	0.10
758.3162231	0.25
769.2759399	0.25
770.9168701	0.38
772.7058716	0.20
787.4346313	0.37
795.3775024	0.61
796.4572144	0.23
799.7954102	0.09
813.4771118	0.30
814.4528198	0.32
815.3197021	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0763
Annotation	Glutathione
Peak:m/z	Relative Intensity
98.9845886	0.33
108.9720764	0.03
110.9209137	0.06
116.1127014	0.07
119.7297974	0.08
124.9455185	0.07
128.0655975	9.16
130.1592102	0.03
134.8740234	0.04
143.0757751	9.35
144.0611267	0.04
145.9931335	1.30
155.0300598	0.09
160.0686340	10.39
166.2140198	0.50
167.0493774	0.52
169.1695862	0.05
170.0657654	0.15
171.1324463	1.21
177.0899963	9.12
179.1184082	8.62
183.2871094	0.08
185.1378632	0.73
191.0198669	0.32
197.0984955	1.52
201.0425110	0.18
203.0725098	0.20
210.0617676	5.64
212.9860229	1.79
215.1153564	0.15
221.1622620	0.02
228.3262024	0.25
231.1700134	1.27
233.0956726	0.30
233.9920654	0.03
236.0882874	1.40
237.1994934	0.08
242.1689453	1.80
244.3226929	0.13
246.1522827	0.08
254.1084595	97.73
258.2284241	0.04
259.3450623	0.23
261.4929810	0.09
262.3165894	0.05
263.0328979	0.06
270.1604919	0.18
272.1159973	100.00
288.1597290	71.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1039
Annotation	Unknow
Peak:m/z	Relative Intensity
139.0986938	0.07
148.9259796	0.08
150.1342010	0.09
155.0489807	0.04
159.0349731	0.06
161.0183105	0.25
163.1685028	0.02
165.0906982	0.03
167.0947723	0.14
175.1134949	0.03
177.1710815	0.13
179.1126404	0.01
190.1192322	0.04
191.1283569	0.36
193.0174866	0.02
194.0204773	0.03
197.1235657	0.02
206.0029297	0.04
207.1090851	0.02
212.1420441	0.08
214.9769897	0.02
216.3064575	0.04
217.2609253	0.17
217.9828949	0.02
223.2432098	0.02
226.8804779	0.03
229.1745300	0.25
231.1504517	0.08
232.0216980	0.02
239.1924591	0.02
241.1894836	0.20
243.0614014	0.21
247.2540894	0.18
249.1622620	0.03
251.4815063	0.07
255.1394043	0.02
256.2327576	0.83
257.3500977	0.01
260.0708313	0.03
261.0123291	0.03
263.0993652	0.07
264.2419434	0.03
271.1144409	5.80
283.1496887	1.28
285.0960693	2.02
287.3457642	0.21
289.0693665	0.13
297.0882568	0.36
298.2763062	0.02
299.2388000	2.68
300.1381226	2.11
301.1317139	0.75
302.1931763	0.34
303.3168945	0.85
307.2224426	0.27
312.0964355	0.09
313.2495728	0.05
315.1292725	100.00
315.9415894	0.03
317.2583008	0.06
319.0590210	0.04
325.1553345	3.09
325.8583984	0.10
328.3220215	0.02
330.4302063	0.03
331.2451172	0.20
333.2137146	8.34
339.1265869	9.94
339.8342896	0.02
343.1158447	0.03
344.1733093	0.05
345.0811157	0.05
349.3746338	0.23
355.2476196	0.04
357.4628601	0.04
363.4059143	0.06
364.5318604	0.01
374.0564575	0.08
375.2196350	0.18
378.9808044	0.09
381.2696838	0.02
389.3243103	0.02
390.4953918	0.09
393.3276062	0.19
397.3145447	0.08
403.1551819	0.15
419.2065125	0.09
420.4875183	0.04
421.3275452	0.74
422.2520447	0.19
423.0653687	0.03
433.2039490	0.37
437.2030945	0.04
438.1967163	0.14
441.8418274	0.08
445.5498962	0.02
446.1615906	0.01
447.1718445	0.22
449.7579346	0.08
450.5444336	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1248
Annotation	Quinic acid
Peak:m/z	Relative Intensity
128.9644775	0.04
137.0947723	0.04
144.9446869	0.06
151.0074005	0.05
155.1172180	0.05
171.0699463	0.13
173.1705322	0.31
189.2729187	0.08
191.0185089	100.00
192.0175476	0.06
237.0808411	55.07
251.1397400	0.04
378.8669434	0.04
408.3128662	0.05
409.2458801	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.2234
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
127.1056595	0.12
128.8041687	0.09
131.0503082	0.86
142.9192810	0.90
145.9437256	0.09
148.7630005	0.87
151.1727448	0.14
158.9301453	1.19
161.0056610	15.99
163.2058868	0.06
173.2859497	0.29
185.1513062	0.04
185.9539948	0.12
191.1540527	0.15
215.1349487	0.13
233.0999908	0.87
257.3654175	0.15
270.9969177	0.09
275.0889282	0.20
283.9843140	0.17
285.2456665	1.17
293.3271790	0.58
295.0424194	0.05
297.2893677	0.05
299.2723083	0.42
311.1748657	0.14
313.0590210	0.06
314.0989685	3.16
315.2446899	100.00
327.0470276	0.05
329.3679504	0.06
347.1826172	0.12
351.6509399	0.14
355.2551270	0.51
357.2756958	0.94
359.4808350	0.09
367.2730713	0.25
387.3286438	0.05
391.3558655	0.11
411.4490356	0.08
427.6005554	0.06
429.4802246	0.41
432.4009399	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0773
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9747772	0.05
111.0253067	0.41
116.9900513	0.10
133.3094025	0.13
135.0829163	20.17
137.0407410	0.22
154.9781952	0.40
159.1430511	0.05
161.0852356	2.63
173.2106934	0.03
178.9925079	100.00
179.6331787	0.18
199.0266724	0.21
207.0246277	0.03
209.1115112	0.04
216.9607239	0.05
225.1114502	0.03
229.2655945	0.09
247.1135864	0.13
255.1564331	0.08
261.2058105	0.02
262.8965149	0.10
271.1840210	0.04
273.1702271	0.09
274.9468384	0.03
281.5184326	0.06
286.6939697	0.05
288.0735474	0.18
289.2961426	0.14
291.1655273	1.89
299.2716675	0.10
301.1869812	0.03
306.3041382	0.03
317.2153931	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0824
Annotation	Methyl gallate 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
96.7025757	0.15
99.0160217	0.13
100.7962875	0.19
107.0447845	0.03
113.0172958	0.04
118.8998795	0.29
121.2321548	0.09
123.0322571	0.25
130.7799072	0.08
135.1047974	0.07
138.9676514	100.00
143.2370911	0.03
145.2914581	0.05
148.0450439	0.21
149.0592041	0.25
150.9090576	0.08
152.9327698	0.52
159.0539093	0.14
160.9645081	1.62
163.0981140	30.90
165.0312042	0.97
167.1297302	0.12
173.0946808	0.07
175.1894836	0.14
178.7508392	0.43
181.0702820	2.31
183.0852203	10.22
193.0535126	7.82
197.3134003	0.09
205.1610107	0.88
207.0081177	32.62
211.0095215	0.14
213.1088562	0.28
223.1219482	0.69
224.9734802	0.42
235.3145752	0.10
237.1473999	1.95
241.0108948	0.21
249.1404724	0.64
261.1617126	0.04
265.1206665	0.27
267.1514893	1.46
271.3318481	0.17
280.6721802	0.13
283.0853882	0.95
285.1713867	7.75
299.1137390	0.81
301.0029907	0.48
302.1066284	0.10
308.9278564	0.06
315.2431641	0.15
327.1810303	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.2612
Annotation	Unknow
Peak:m/z	Relative Intensity
303.1300659	1.02
304.2970581	0.21
321.0161133	1.55
322.4638672	0.08
381.2718811	0.77
419.0386963	0.15
437.2331543	0.37
453.3239746	0.08
467.1718750	0.13
468.1057129	0.06
477.6874390	0.14
479.2519531	4.31
480.2840576	0.42
485.9906006	0.35
497.3149414	2.27
509.0590210	0.21
527.6247559	0.12
539.4019775	5.38
540.3121338	1.34
557.6337280	0.09
581.4509888	0.33
625.2500610	11.50
626.3027954	3.21
643.2882690	51.00
644.2862549	10.57
644.9470215	0.05
695.5050659	0.08
703.4505615	1.80
731.4356079	0.12
738.7241821	0.11
741.3262329	0.21
742.2882690	0.12
745.4790039	0.07
746.3163452	0.08
759.2434692	1.23
760.8004761	0.27
789.3856812	2.14
790.4455566	0.52
801.3323975	5.22
802.4359741	2.36
807.4396362	2.44
808.3444214	1.15
817.4487915	0.09
819.4082642	3.85
820.3959961	1.13
831.3767700	0.47
832.6472778	0.07
835.7197876	0.05
843.1497803	0.22
844.4601440	0.06
849.2034302	0.21
858.8605347	0.13
861.3534546	16.71
862.3898315	7.03
873.4315796	0.09
876.2512207	0.16
877.6053467	0.23
886.4428101	0.33
903.5800781	0.99
904.5155640	0.06
906.3951416	0.18
920.9795532	0.17
922.4857788	0.13
929.6105957	0.91
930.6969604	0.38
947.3432617	100.00
948.3876343	30.83
974.6946411	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2288
Annotation	Ssioriside
Peak:m/z	Relative Intensity
161.9743042	0.01
164.2386017	0.01
166.0707245	0.01
168.0014343	0.01
177.3507233	0.00
179.2248230	0.02
182.2198486	0.02
183.1499786	0.02
185.1582489	0.01
191.2496948	0.00
194.1051025	0.02
197.2426453	0.10
199.2646484	0.00
205.1571960	0.00
209.2143707	0.05
210.0626373	0.01
211.1928711	0.03
217.0102997	0.01
225.2030792	0.01
250.2784882	0.01
256.5851440	0.00
260.9920044	0.01
264.8774109	0.01
297.3146362	0.01
302.2019043	0.00
307.0618896	0.01
313.3641968	0.00
327.3006592	0.08
328.2596436	1.54
329.3334351	0.32
333.1898193	0.00
343.2664795	100.00
344.2187500	9.70
346.3420410	0.00
347.3325806	0.01
348.8298340	0.01
355.3083496	0.01
357.3393555	0.00
361.1473999	0.01
362.2023926	0.01
363.0948486	0.01
369.4618530	0.01
372.1707153	0.01
373.2249146	0.00
380.9914551	0.00
388.2263794	0.00
391.0795898	0.01
399.2994995	0.02
405.2094116	0.02
407.5801392	0.00
421.7437744	0.00
426.3244019	0.01
436.2744141	0.00
437.4974976	0.00
453.3802490	0.01
456.9539795	0.00
458.3020630	0.01
463.7179565	0.02
465.6567993	0.02
467.4654541	0.05
468.1364136	0.01
482.0444336	0.01
491.4440918	0.01
498.7000122	0.00
505.5061646	0.02
506.5747681	0.01
507.3030396	0.03
509.3325806	0.03
510.3175049	0.03
515.2478638	0.00
517.6510620	0.01
521.2836914	0.05
521.9263306	0.01
523.4234009	0.02
524.0892944	0.02
533.1425781	0.01
535.3853149	0.04
536.4102173	0.04
537.1656494	0.00
538.2991333	0.00
539.2185059	0.00
554.5872803	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
143.2207794	0.02
149.1236725	0.49
150.1536407	0.03
160.9664001	0.06
162.9866028	0.22
165.1841583	0.29
167.0870667	0.05
168.2311707	0.04
179.1755676	0.12
184.7035217	0.08
191.0438538	0.09
194.5075378	0.06
200.1922607	0.09
201.4854736	0.05
205.4647217	0.05
219.2970276	0.06
221.3583984	0.18
222.7805634	0.05
231.1172943	0.03
233.1936493	0.14
234.1922302	0.03
239.3314362	0.03
241.4619598	0.02
242.0778809	0.03
250.8760986	0.08
270.2182617	0.06
273.0506592	0.10
275.1868591	0.07
285.3892212	0.16
288.2035522	0.05
289.3845215	0.04
293.1562500	19.85
294.1461487	1.92
298.4451294	0.03
299.0576172	0.04
300.1582336	0.02
301.3158569	0.13
302.2241821	0.11
303.2616577	0.04
310.9985962	0.15
312.3767395	0.12
313.4256287	0.03
314.2945557	0.06
316.2286987	0.08
325.3738708	0.11
327.3618164	0.06
330.0004883	0.05
331.3651428	0.12
339.1974487	2.72
340.4235229	0.03
341.1431274	0.04
342.2080078	0.02
344.1939087	0.73
345.2739258	0.80
346.3690796	0.14
353.5997009	0.05
356.1748657	0.04
357.2892456	0.11
359.6526489	0.05
360.3018799	0.07
364.0460205	0.07
371.1836548	0.03
376.5660400	0.05
382.3312073	0.05
387.3208923	0.04
389.3491821	0.04
411.3687439	0.05
417.9728699	0.10
420.4436951	0.06
447.2106628	0.10
448.3407898	0.05
450.3307190	0.15
461.1838684	100.00
462.1972656	11.37
463.5862427	0.19
464.5713196	0.13
465.6962280	0.05
477.3476257	0.54
478.6641541	0.26
479.6298523	0.07
480.3373718	0.10
481.1566772	0.12
489.3675232	0.55
490.3072815	0.33
492.3815613	0.14
493.3080750	0.03
494.4444275	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.2753
Annotation	Unknow
Peak:m/z	Relative Intensity
157.2214813	0.10
173.9311066	0.08
182.0508423	0.04
183.0978394	0.03
185.0755157	0.91
186.0957031	0.06
188.3546906	0.04
191.0886078	0.07
191.8870544	0.03
205.6482239	0.05
209.1956177	0.12
213.0784149	2.31
214.1146393	0.76
215.9448090	0.13
217.9941101	0.10
220.1185303	0.60
221.0290222	0.06
225.4357605	0.04
229.6954956	0.02
231.1523743	0.06
232.3091736	0.03
237.0470581	1.18
238.0484314	0.19
244.1327057	0.24
262.1110840	2.27
263.1650085	0.90
264.1394653	0.03
272.5493774	0.06
278.0255127	0.11
280.2461548	0.59
281.2952881	0.04
284.0979614	0.04
290.1719360	1.95
291.1981812	1.39
292.2096558	0.04
293.3731689	0.07
305.2349854	0.11
306.2828979	0.12
308.1672363	22.25
309.2885742	4.67
313.4558105	0.02
317.1309814	100.00
319.2350464	0.07
327.1506958	0.02
331.1996460	0.18
333.3069458	0.06
337.0421143	0.01
344.4327393	0.10
345.2738647	0.11
346.4187012	0.06
347.3396606	0.01
357.3574219	0.03
359.4761963	0.08
362.4196167	0.10
371.3069458	0.10
372.5592651	0.04
373.4434204	0.07
375.4505615	0.24
376.3280029	0.14
378.2783813	0.16
379.2714233	0.42
380.3510742	0.03
389.2304077	33.80
390.2762451	10.32
391.1270752	0.03
395.3027344	0.11
404.2361450	1.15
405.2434082	0.13
407.2709351	7.32
408.2794189	2.91
414.4027710	0.04
417.2973022	0.20
418.3131714	0.04
421.2875977	1.65
422.2869263	0.99
431.2274780	0.71
432.2691040	1.68
433.3298340	0.47
435.2631836	0.11
446.4095459	0.17
449.2493286	10.11
450.2861328	5.56
451.4547729	0.03
457.0012207	0.31
457.7188110	0.08
458.4427490	0.20
459.4208984	0.85
460.3742676	0.81
466.6118164	0.02
467.6206055	0.06
474.2817993	0.28
475.3337402	0.73
476.6148682	1.64
477.2985229	8.25
478.3137817	4.88
478.9298706	0.03
484.5731201	0.13
485.1919556	0.14
486.5910034	0.13
492.3746948	4.93
493.4400635	2.00
494.3817749	0.07
502.4303589	19.37
503.3872070	13.65
504.3243408	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1332
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
189.0305176	0.01
205.9374542	0.01
242.2875519	0.01
247.0318298	0.09
248.2707825	0.04
262.0260620	0.01
267.5702209	0.01
270.1763306	0.13
271.2652588	0.05
272.0513306	0.02
287.0889282	0.04
288.0064392	0.01
288.9609985	0.01
290.1803589	0.01
291.2178955	0.10
298.3721313	0.06
299.1472778	0.10
300.2047119	0.02
301.4171753	0.03
303.2021484	0.03
304.2803955	0.02
315.0990601	0.11
316.2191772	0.25
317.1289673	0.01
324.0596924	0.02
331.1571655	100.00
332.1635742	17.69
332.7772217	0.12
336.1604614	0.01
344.2999878	0.01
350.8059082	0.01
354.3370972	0.06
355.1990967	0.01
366.9447632	0.02
371.1986084	0.02
372.9661255	0.01
375.3853760	0.01
378.1683960	0.01
381.1373901	0.03
385.1250000	0.02
396.2054443	0.06
403.2918701	0.06
405.3339233	0.02
409.1286621	0.07
410.2546997	0.01
414.2297363	0.01
416.9646606	0.05
418.0784912	0.02
420.1151123	0.03
427.2673340	0.09
428.1683350	0.01
430.2149658	0.02
433.0980225	0.01
435.0194702	0.02
438.2070923	0.04
439.0066528	0.05
447.3320312	0.01
453.1495361	0.06
454.0516968	0.02
488.9486694	0.09
491.7811890	0.03
493.2158813	1.26
494.2174683	0.29
514.2627563	0.05
517.5095215	0.02
518.4653320	0.01
525.5056152	0.04
533.3007202	0.01
533.9833374	0.01
535.2211914	3.84
536.2786865	0.83
543.6859131	0.01
544.9055786	0.01
549.6552124	0.01
559.1735229	0.02
561.2031250	0.33
562.2654419	0.03
563.4260864	0.01
564.1491089	0.02
566.1677246	0.01
568.9815063	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1242
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9221191	0.12
153.0735779	3.03
176.9028625	0.35
195.1880951	0.25
237.0911407	0.30
238.2401276	0.19
239.3288727	0.10
244.0225372	0.12
251.2257690	0.10
255.2752380	0.15
269.3075562	0.09
278.4757080	0.13
297.2819214	0.21
313.8148193	0.20
315.2501221	100.00
323.0260010	0.18
345.5544739	0.26
346.3066711	0.32
359.0651550	0.16
387.3322144	0.15
403.0282288	0.50
417.4026794	0.11
430.3875732	0.08
433.5449829	0.08
440.1783142	0.53
458.4345703	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	5-Methyltryptamine
Peak:m/z	Relative Intensity
59.85852051	42.77
69.88051605	5.88
71.98345947	1.79
84.0178833	0.21
86.98284912	0.12
88.14605713	0.06
97.14675903	0.06
97.96994019	0.41
111.9547729	4.64
112.9336853	1.40
114.1040344	4.33
115.1784821	3.27
115.9562683	48.89
130.0556183	40.18
131.0016174	0.13
132.9694824	1.06
139.9799347	2.28
140.9703217	0.22
145.2228241	0.16
154.506485	0.19
157.0019989	77.61
158.0947876	100.00
166.1452179	0.08
173.3027496	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.0826
Annotation	Taxifolin 3-apioside
Peak:m/z	Relative Intensity
125.0037766	1.80
127.0089340	0.02
137.1012726	0.08
147.1214294	0.07
148.1225433	0.01
149.0109253	0.05
152.0888672	0.01
153.2968140	0.06
159.1065979	0.01
160.9828644	0.02
163.2054749	0.25
164.9973145	0.04
166.5078278	0.04
173.1444092	0.09
175.2070312	0.08
176.2378693	0.01
177.1157227	0.23
180.8625183	0.03
181.4737549	0.02
187.0266876	0.02
189.0366821	0.11
191.0821686	0.43
193.0657654	0.05
195.3072205	0.01
197.1856689	0.01
199.0584106	0.03
201.1799469	0.32
203.1526489	0.22
210.9712219	0.09
213.2727661	0.05
215.2037964	0.06
217.1606750	0.66
221.1901245	0.07
225.3667755	0.10
225.9850159	0.01
227.0489197	0.17
231.1489868	0.38
232.9625854	0.12
234.2619019	0.02
235.2345276	0.06
239.2249146	0.20
240.2144470	0.02
241.2508850	1.04
243.0862122	0.90
245.1628723	0.14
247.2131348	0.01
249.2633667	0.05
253.3214722	0.11
255.2127686	0.19
256.0056152	0.03
257.2937622	0.20
258.2529297	0.01
259.1181030	0.06
261.1730652	0.09
263.2443848	0.25
265.2789917	0.26
267.0446777	0.25
268.0499573	0.03
269.2812195	0.43
271.2010498	0.54
272.2919617	0.04
273.0606995	0.24
277.3331909	0.03
279.3391113	0.04
280.5112305	0.06
281.4144287	0.17
284.0910645	100.00
285.1276245	61.65
286.2471313	0.03
289.1108398	0.35
291.2084045	2.55
293.2272339	0.03
294.1047974	0.10
295.0997314	0.57
297.1234131	9.36
297.7610779	0.01
299.1183472	11.50
300.9334717	0.01
303.2194519	0.09
304.2626343	0.01
305.3691406	0.03
307.1854248	0.31
309.1882019	1.37
310.3417053	0.04
311.0406494	0.21
313.1730347	0.20
314.1870728	0.09
315.2606812	0.04
316.1010742	0.03
319.3286743	0.06
321.1488037	0.08
322.2323608	0.02
323.2059937	0.02
324.1145020	0.02
325.2185669	0.25
327.1559448	6.99
328.3775024	0.04
331.2051392	0.21
335.2314453	0.06
337.3916321	0.08
339.1760864	2.80
340.3840637	0.01
341.0940552	0.04
343.5354614	0.01
345.1774292	0.06
347.3515015	0.03
349.2458496	0.06
351.0752563	0.27
351.6912537	0.02
353.3597107	0.12
355.3026123	0.30
357.1162415	2.28
359.1848145	0.04
363.5833130	0.03
369.2258911	0.30
371.2128601	0.08
373.1619568	0.59
375.2917175	0.13
381.1820984	0.65
385.3744507	0.06
387.2119141	0.04
389.2350159	0.03
399.2652893	1.89
402.1048889	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.2138
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0940857	0.09
179.0835876	2.30
203.2354736	0.06
204.8484802	0.13
206.1968689	0.04
221.0230408	0.26
223.1542053	13.62
225.0188293	0.03
232.9095459	0.05
239.1660614	0.08
241.1601868	0.15
265.1149292	0.55
269.2477417	0.10
283.3474426	0.02
295.1641846	0.15
309.6979980	0.07
311.0951538	0.34
323.3463135	0.05
325.1995850	0.29
329.1859741	0.13
341.1695557	0.10
346.2095947	0.09
359.3389893	1.42
367.0893555	0.20
381.4136963	0.03
385.2160645	12.31
385.8367920	0.03
401.1181030	0.05
403.2611084	100.00
413.4068604	0.05
425.9708862	0.08
429.4126587	0.03
433.3728027	0.03
443.2386475	0.03
445.2290649	0.09
447.3785400	0.04
451.3825684	0.06
456.9196167	0.04
462.3518066	0.04
467.1685181	0.04
473.8455200	0.11
475.2269897	0.13
477.2390137	0.01
478.5684814	0.14
480.9875488	0.15
483.3686523	0.03
487.0910034	0.14
489.4298706	0.24
491.2276611	0.33
493.1487427	0.05
501.4570312	0.03
505.3450317	0.11
517.6531372	0.23
519.0273438	1.20
519.6448364	0.27
520.6340942	0.04
521.2638550	0.36
535.5242920	0.06
536.1551514	0.04
538.2734985	0.31
546.3971558	0.10
547.3070679	0.23
548.1276855	0.03
548.8511353	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
59.6496735	0.06
66.8714752	0.11
67.8561783	0.07
68.8755798	0.28
69.9359589	0.28
70.8057632	0.12
71.8936920	0.13
72.8450623	0.23
74.1590271	0.14
75.0742645	0.12
79.0093994	0.04
79.7919998	0.05
81.0104523	0.27
82.9185181	0.07
83.8325500	0.44
85.9527664	0.05
86.6587372	0.07
88.0203247	0.18
89.0692444	0.06
91.9419708	0.16
95.0656891	0.21
95.9619904	0.59
96.9383850	0.29
97.9410095	0.58
99.7414703	0.03
100.9568176	0.38
102.0123901	0.06
106.7141724	0.06
108.2137299	0.03
109.2128143	0.09
110.9864044	0.23
111.8487854	0.40
114.9500275	0.22
121.1649475	0.09
122.0750275	0.27
122.9438934	0.07
125.1192169	0.13
128.0569153	0.16
129.2171936	0.60
136.3278809	0.03
141.1498260	0.11
146.7243500	0.17
150.8532410	0.17
154.0447845	0.47
155.9029999	0.41
157.1473541	0.19
158.9380035	100.00
163.0626373	0.21
164.2487640	0.23
169.9740753	0.50
171.4776764	0.27
172.1296234	0.54
175.4608612	0.09
176.7235870	1.57
179.6019440	0.06
181.0976410	0.51
182.0103760	2.27
183.1168518	2.06
185.0932770	0.17
186.0662079	0.06
187.4096832	0.26
188.1233978	0.46
190.4874725	0.12
191.1140594	1.51
197.9654083	0.07
200.3154144	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1307
Annotation	Castamollissin
Peak:m/z	Relative Intensity
163.1076813	0.38
189.0073547	0.17
191.0692444	0.21
203.0468750	0.16
204.9591980	0.12
213.0989838	0.24
214.7736359	0.05
217.1040039	0.40
223.2062683	0.17
231.2832642	0.05
236.2258301	0.06
239.0993652	0.05
243.1730652	0.08
246.1496582	0.11
255.0178986	0.37
257.3163147	0.17
258.1246948	0.17
259.1911621	0.45
261.3406677	0.28
269.1674194	0.19
270.1105347	1.53
271.1422729	0.54
272.1764526	0.13
273.2416077	0.77
275.1464233	0.24
282.0717163	0.21
283.2752075	0.34
284.2127991	0.58
285.2315063	2.06
285.9777222	0.05
287.1803589	1.09
288.3057251	0.21
292.4499512	0.15
293.2035522	0.17
295.2456055	0.11
296.7257080	0.24
297.3373413	0.71
298.1116333	0.23
299.2596741	1.67
300.6948242	0.56
301.4141235	0.07
302.0617676	0.25
303.3533936	0.45
307.2207031	0.09
308.1644287	0.07
309.3143921	0.18
311.5794067	0.35
312.4456177	0.14
313.1693115	3.20
314.2353516	4.09
315.2088623	0.29
316.4519043	0.06
321.1850586	0.15
325.3079834	0.37
327.2546997	11.03
328.1429443	71.57
329.1593628	100.00
330.4417725	2.85
331.1619873	14.74
331.7640381	0.14
333.7280884	0.10
335.3448486	0.06
338.0740356	0.08
339.1329956	0.64
341.2448730	5.77
343.1561279	10.85
345.1611938	0.27
347.1181641	0.08
350.9851685	0.16
353.1854858	2.90
353.9815063	0.08
355.1932983	0.21
356.1046753	0.07
357.2145996	0.35
358.2526245	0.14
358.9757690	0.22
362.3360596	0.26
365.0795898	1.08
367.1516113	0.34
368.1888428	1.15
369.3274536	0.96
371.1533203	6.66
372.6738892	0.15
373.3615112	0.19
379.0523071	0.05
381.3071289	0.31
383.3045654	7.55
385.2200317	1.43
387.2163696	0.60
389.3322754	0.38
393.3391724	0.20
395.1353149	2.16
397.4784546	0.17
399.1851807	0.12
401.2741699	2.66
405.4964600	0.06
407.1522827	0.22
411.2351074	0.41
413.2828979	2.01
425.1995239	0.85
427.2855835	0.15
429.4893188	0.09
431.1672974	0.31
435.2475586	0.06
437.2777100	0.64
441.3374023	0.11
442.3661499	0.19
443.1971436	0.55
447.3948364	0.07
455.2915649	1.43
456.8003540	0.11
461.2037964	0.04
471.4196167	0.09
473.2993164	13.50
483.0949707	0.07
486.1117554	0.22
487.4129028	3.53
489.1158447	0.34
491.2667847	16.83
497.0763550	0.67
501.1900024	2.28
502.0414429	0.05
502.6542969	0.16
513.2352905	0.09
514.4357300	0.21
515.3129272	0.44
518.3759155	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0985
Annotation	Castamollissin
Peak:m/z	Relative Intensity
151.0473938	0.89
152.0320892	0.06
163.0418854	0.22
169.0818481	0.14
179.0027618	2.54
180.0730896	0.12
184.3883362	0.06
188.9443054	0.16
190.0701141	0.12
191.0856323	0.11
193.0486755	0.29
194.0488281	0.10
196.9884644	0.07
199.1330566	0.05
202.8662415	0.03
204.3613586	0.03
207.0647583	0.06
209.1398621	0.20
211.1986389	0.10
213.0512390	0.17
215.1766968	0.02
216.0524902	0.06
216.9945068	0.12
218.1050873	0.12
218.9652863	0.02
221.2259521	0.13
225.1261292	0.07
226.7205353	0.05
227.3242493	0.26
228.8814545	0.14
233.1546021	0.04
239.6676331	0.07
240.6487122	0.05
241.3888855	0.04
243.2679749	0.10
245.3008423	0.04
247.1027832	0.13
247.8674774	0.04
254.1520386	0.09
255.1757812	0.88
256.2603149	0.26
257.1481628	0.22
267.3641968	0.06
271.2546692	1.52
272.1870728	0.45
273.1340637	0.91
274.1966858	0.16
275.2472534	0.05
279.2442017	0.04
281.3678589	0.10
283.2987671	0.30
287.2897034	0.07
291.2332153	0.06
293.0946655	0.15
296.0090942	0.08
297.2447205	0.14
298.5371399	0.22
300.0718079	58.02
301.0992737	100.00
302.1219482	13.87
309.4038696	0.02
311.2698364	0.02
313.2055359	0.30
314.9819946	0.08
323.4060059	0.03
324.2843628	0.03
325.3058472	0.47
329.2010803	0.33
335.3088684	0.06
337.1671143	0.04
340.2126770	0.09
341.3529663	0.13
342.1688843	0.06
343.1922607	3.00
344.1920471	0.58
351.3403625	0.06
353.4026489	0.06
355.2394104	0.48
360.1278687	0.03
361.3684082	0.42
362.4890747	0.16
367.3012085	0.28
369.3211670	0.08
370.2271118	0.09
373.2603149	0.15
374.2865295	0.09
377.1147156	0.08
379.1953735	0.26
380.1228943	0.06
383.2780457	0.03
385.0605164	0.03
391.2931213	0.02
395.6058350	0.08
396.2798767	0.03
397.2666016	0.14
399.5018921	0.03
401.1104431	0.03
402.6088562	0.08
404.6383667	0.08
409.1826477	0.08
417.8527222	0.09
427.3080750	0.29
428.3957214	0.10
434.3918152	0.04
445.3265076	1.99
446.1633301	0.73
460.4240723	0.05
461.3369751	0.66
463.1963196	56.26
464.2556763	10.21
464.8829651	0.11
469.3693542	0.07
473.1828918	0.18
474.3965454	0.11
475.3895569	0.27
477.2895203	0.13
487.2669067	0.79
488.3535767	0.15
490.5395203	0.03
492.6284485	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1035
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
150.9981537	0.15
178.0343323	0.04
191.1704102	0.38
193.0460510	100.00
195.3997345	0.06
204.9754028	0.06
260.9900513	0.03
261.6147461	0.03
268.3043823	0.04
271.1758423	0.06
295.2407837	0.14
311.2750244	0.06
313.1508484	0.09
313.8455200	0.03
316.8500977	0.09
319.4743958	0.03
323.1099854	0.03
337.2731323	0.12
340.2729492	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.1736
Annotation	Unknow
Peak:m/z	Relative Intensity
243.1060181	0.09
287.3990479	0.25
302.9731140	0.10
329.2708435	0.14
330.3625488	0.24
343.3930664	0.15
345.1587524	0.07
359.2163696	2.89
391.3397217	0.13
439.4558716	0.14
453.1029053	2.33
454.0874023	0.13
465.1298218	0.18
477.5248413	0.15
479.1179810	0.22
481.3795166	0.13
495.3880005	0.43
507.4500732	0.09
521.3498535	0.45
550.9512939	0.06
554.9515991	0.19
590.1574097	0.17
591.2540894	0.11
602.3835449	0.42
603.3056030	1.47
604.7362671	0.15
614.4706421	0.04
615.2639771	0.44
621.2946777	100.00
630.2271118	0.20
631.1751709	0.09
646.3225708	0.12
650.3473511	0.07
653.5344238	0.11
654.4264526	0.10
692.3211670	0.12
698.4229126	0.30
706.5875244	0.11
747.2109985	0.07
755.9198608	0.13
764.3496704	0.49
765.1682739	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2079
Annotation	Glaucarubinone
Peak:m/z	Relative Intensity
147.0776672	0.06
149.3537445	0.04
153.2019806	0.04
157.3414917	0.01
158.7913513	0.05
160.1579285	0.03
161.0854340	0.18
163.1433716	0.04
165.0361938	0.22
173.4496155	0.02
174.1093140	0.05
175.0892792	0.04
178.1716461	0.02
178.7824249	0.01
187.1203461	0.01
190.0258026	0.03
191.2180786	0.21
192.1110840	0.04
193.3196106	0.02
205.2471313	0.05
207.0628662	0.11
209.0946960	0.05
217.3231049	0.03
227.0054321	0.02
228.9544983	0.01
233.2453918	0.03
244.2136841	0.06
257.4491882	0.03
264.7973022	0.09
266.4712524	0.08
267.5727844	0.02
269.4510498	0.01
272.8022461	0.03
273.5448608	0.01
282.3446045	0.01
283.3255920	0.02
284.3067017	0.02
286.2004089	0.02
287.4000854	0.13
293.2397766	0.01
296.2608337	0.02
298.2373047	0.06
299.2807617	0.81
300.2674561	0.02
301.2278137	0.09
302.0007324	0.01
303.2844238	0.06
305.4417114	0.03
310.1425781	0.02
311.0917969	0.12
313.3340454	0.98
314.2689819	0.54
315.2251892	0.08
316.2859802	0.05
317.1911621	0.02
325.1870117	0.05
327.2630310	0.06
328.2802124	0.47
329.2403564	4.12
330.2743530	0.69
331.2919006	1.22
332.7714539	0.09
333.4568481	0.21
334.3712158	0.01
343.3455200	5.83
344.5576172	0.02
345.3320312	0.03
346.4209290	0.34
347.3645935	1.17
348.3114624	0.05
355.2922668	0.04
361.2677917	100.00
362.2583618	0.22
365.3779907	0.04
367.3825378	0.05
371.1395569	0.04
373.0788269	0.02
385.0224915	0.05
389.4136658	0.02
403.2659607	0.13
417.2824097	0.04
431.1145935	0.02
433.3846741	0.02
447.2486267	0.29
449.3245850	0.03
451.4118042	0.07
457.1129456	0.04
461.4186707	0.11
463.4220581	0.93
464.1099548	0.01
465.0664978	0.02
473.5370789	0.02
474.8473816	0.08
475.4600525	0.24
478.4480591	0.64
479.6862488	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.89896393	0.12
82.92404938	0.04
84.8770752	0.03
92.11267853	0.04
103.0133972	0.18
104.1108551	0.10
104.8825836	0.19
106.1112366	0.04
106.8974152	0.02
109.1218719	0.03
109.9736938	0.02
116.2563171	0.05
119.0658264	0.09
121.7629089	0.03
123.0121918	0.13
126.914917	0.06
128.9532166	0.54
130.0855865	0.85
134.1810608	0.07
138.3011627	0.03
140.8713226	0.17
144.8849945	0.03
146.1196289	0.06
147.1016083	0.02
148.1000824	0.12
148.9863129	0.04
150.0103302	0.05
150.9470673	9.70
151.9642792	4.02
152.9832916	0.22
153.8572845	0.11
155.0464935	0.14
156.2134247	0.12
157.0591583	0.11
162.1767426	0.17
164.0544586	0.08
164.7553406	0.02
165.9985046	0.08
167.0302582	0.22
168.1382599	0.15
168.9906769	0.15
170.1647339	0.41
171.0751648	0.11
172.0649261	0.11
173.0406342	0.06
177.1691589	0.06
178.2042694	0.24
179.1450043	0.24
179.9637756	0.24
181.0626526	0.02
182.1289825	0.08
183.0574646	0.10
185.0989227	0.29
186.0032196	0.18
188.9266815	0.05
189.8206024	0.06
193.1486359	0.06
194.1296844	0.16
195.3390503	0.05
197.2604065	0.30
198.1498871	0.34
208.4696198	0.15
210.0048523	0.11
211.3056183	0.13
212.4139404	0.11
223.3476868	0.04
224.0206757	0.03
225.3269501	0.85
226.1496124	0.79
226.8789825	0.03
234.9986725	0.02
236.1538086	0.46
237.1594849	0.25
238.1544342	1.98
239.2617645	0.77
251.0654449	0.22
253.0861206	100.00
254.1288452	6.63
255.2876434	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0985
Annotation	Castamollissin
Peak:m/z	Relative Intensity
150.9814453	1.40
152.0074463	0.08
162.0249634	0.12
163.0761566	0.09
167.1016235	0.03
168.9271088	0.07
172.9896240	0.04
175.0148621	0.15
176.2050781	0.08
179.0139771	1.94
179.9888306	0.09
187.1885986	0.03
189.0920410	0.50
190.1689453	0.04
190.9918518	0.19
192.8085327	0.15
194.0331726	0.03
198.0493774	0.16
201.2236633	0.03
203.1461182	0.12
205.0985107	0.09
206.1515808	0.04
209.1898193	0.10
211.0162659	0.13
212.1209106	0.06
213.2697601	0.03
214.0901489	0.09
217.0171661	0.12
218.0573730	0.07
221.0555420	0.19
222.0317078	0.10
226.2554321	0.12
227.2812500	0.21
229.1171875	0.14
230.1353760	0.03
233.0785217	0.30
234.0322418	0.09
235.3079529	0.07
236.9002075	0.07
243.2680969	0.29
245.9057617	0.17
246.9039917	0.02
254.1379395	0.30
255.1644897	0.96
256.0683899	0.33
257.2282410	0.24
267.2694397	0.03
271.1462708	2.38
272.1443176	1.04
273.2225647	0.84
274.3456726	0.28
275.1482239	0.04
277.1906128	0.08
281.1165771	0.13
282.1758118	0.06
283.2241211	0.23
283.9638062	0.10
285.1258240	0.08
287.2700500	0.06
291.2719116	0.02
293.2560730	0.17
295.1823425	0.13
297.1407776	0.43
298.2146912	0.08
299.1018982	2.26
300.1060181	67.76
301.0897522	100.00
302.2122498	13.99
302.9513245	0.14
305.3137512	0.06
306.4537659	0.06
309.2727661	0.05
311.2463379	0.06
313.2449951	0.52
314.1905518	0.04
315.0085449	0.13
317.3073730	0.06
319.1731873	0.11
323.2167969	1.11
324.2028809	0.21
325.1399231	0.41
326.3298950	0.41
328.1326599	0.11
329.1499023	0.22
335.2891846	0.05
337.2850952	1.67
338.1254883	0.18
339.3361816	0.04
341.3648987	0.21
342.3472900	0.04
343.2195129	3.47
344.2096863	0.48
345.5313721	0.07
347.2674866	0.10
349.1679077	0.02
350.5538940	0.12
353.4027100	0.20
355.2351074	0.43
363.2879639	0.04
367.1406555	0.21
368.3173218	0.23
369.4996338	0.03
373.2525635	0.28
374.1629639	0.04
379.2731934	0.22
385.9788513	0.09
387.0941467	0.09
395.4578857	0.02
396.2413330	0.09
397.3432312	0.02
398.6717224	0.02
401.3504639	0.09
403.0785217	0.09
409.5839844	0.10
410.2837219	0.13
417.7762756	0.12
427.2587280	0.27
428.0843201	0.10
437.2067566	0.10
445.2315674	3.99
446.2211914	0.68
459.0275574	1.06
460.1346436	0.07
461.3084106	0.20
463.1999512	57.59
464.2953796	13.14
473.3739319	0.04
485.2956848	0.11
487.3026428	0.52
488.0881958	0.03
491.6336365	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	567.0968
Annotation	6-Hydroxydelphinidin 3-(6-malonylglucoside)
Peak:m/z	Relative Intensity
179.1226654	0.11
223.2112122	0.05
225.0009460	0.12
231.1846313	0.03
248.8838501	0.18
255.2455444	0.03
259.1404114	0.02
270.0520630	0.05
295.2605286	0.09
299.1366577	0.16
301.2162476	0.21
302.2012329	0.11
303.2088013	0.23
317.0631714	0.09
319.0979614	100.00
329.1317139	0.40
330.9575806	0.04
339.4128418	0.03
343.2741089	0.43
345.2207031	0.62
346.1546021	0.04
349.2538452	0.18
350.9981079	0.08
355.2719116	0.08
356.9168091	0.03
361.1668701	1.79
363.1455078	0.59
364.0717773	0.10
369.0972900	0.03
370.7698364	0.02
373.1980591	0.17
374.0394897	0.08
375.2579956	0.02
377.3689575	0.07
381.3455811	0.05
385.3032837	1.61
386.2977905	0.08
387.1715088	0.24
389.9773560	0.12
397.1926880	0.18
398.7718506	0.06
399.8710938	0.07
400.8648071	0.08
403.3009033	0.14
405.2249756	0.03
409.1776123	0.11
413.7297363	0.14
416.0761719	0.17
417.1936035	0.09
418.1491089	0.06
422.3710938	0.07
427.2847900	1.51
440.9450073	0.03
445.1171265	0.32
446.1237183	0.08
463.2887573	0.50
469.2983398	0.09
470.9168701	0.10
474.0335693	0.06
476.4177856	0.05
477.2415771	0.16
480.7866821	0.05
481.4186401	0.21
487.1843872	0.53
491.3505249	0.10
492.4592896	0.03
496.1864624	0.03
497.3208008	0.16
503.1255493	0.04
505.2631226	3.75
513.1666870	0.16
514.1940308	0.02
518.1292114	0.15
521.3811646	0.13
522.3743286	0.05
524.2592163	0.09
531.1333618	1.95
534.4878540	0.09
536.1992798	0.07
537.4005127	0.13
539.7140503	0.06
542.2253418	0.15
547.2393188	0.15
549.2071533	8.92
549.8667603	0.18
558.0049438	0.13
558.8809204	0.09
565.8971558	0.05
567.1680298	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	735.4079
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1236267	0.30
310.3817139	0.02
387.0972900	15.44
544.2531738	0.04
561.1036987	100.00
562.0701294	0.76
567.8705444	0.04
570.2725220	0.12
580.1412354	0.04
581.4309692	0.11
605.2841797	0.05
605.9575806	0.10
649.8298340	0.02
651.9492798	0.29
661.4873657	0.11
725.0715942	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2239
Annotation	S-Furanopetasitin
Peak:m/z	Relative Intensity
148.9734650	0.09
160.1871796	0.07
180.1253662	0.02
192.9066925	0.38
194.0933228	0.06
195.0702209	0.05
203.2261200	0.12
217.2213745	0.03
221.0278015	0.04
226.2243652	0.04
232.7871399	0.10
234.0630493	0.11
243.2778168	0.10
248.2417297	0.08
261.2774048	0.28
271.2833862	0.21
291.0198975	0.03
303.9393311	0.05
311.1436157	0.16
316.4531250	0.09
319.2875366	0.16
327.2743530	0.21
328.2632446	0.09
329.3424683	1.30
330.1861572	0.54
331.2206421	0.76
332.5426025	0.05
341.4497681	0.05
344.8776245	0.05
347.0979614	2.36
348.1745605	0.60
348.9532471	0.08
352.1450806	0.05
353.4034424	0.10
355.3175659	0.37
359.2114868	0.25
360.5033569	0.11
361.3864746	0.16
371.3314819	0.22
372.2801514	0.04
377.4650879	0.08
378.3853149	0.08
400.2738037	0.08
404.9544067	0.07
410.4088135	0.07
421.5731201	0.04
422.8012085	0.10
428.4863281	0.09
434.7835083	0.31
437.9929199	0.05
443.5350342	0.07
451.1856689	0.09
463.3035278	100.00
464.2739868	49.41
465.3309326	0.10
467.3750000	0.17
473.4165039	0.03
476.7316895	0.14
482.4535522	0.05
491.5265503	0.35
492.3460083	0.27
493.2577515	0.25
494.0470581	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.1189728	0.04
111.2214203	0.01
117.0159836	0.40
118.5583115	0.04
135.0678406	0.55
145.0123901	3.10
147.2349854	0.01
162.9630737	100.00
163.8138428	0.06
181.0756836	0.11
186.1029510	0.00
193.0464783	0.16
281.2087708	0.02
327.2079468	0.03
337.1860962	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.2863
Annotation	Sedumoside F2
Peak:m/z	Relative Intensity
188.9862061	0.18
199.1821289	0.18
223.4463501	0.07
234.9490967	0.17
250.7648010	0.10
261.2186279	0.10
273.2576294	0.15
309.1668091	0.07
330.0144043	0.10
334.9328003	0.12
339.5581665	0.08
341.2120972	0.45
343.2047119	0.30
345.5490112	0.06
351.4293823	0.05
357.3013916	0.09
362.3862915	0.15
370.2156982	0.24
374.8486328	0.11
377.3098145	0.11
385.0576782	0.07
385.6714478	0.06
387.3581543	0.11
393.3553467	0.09
395.1828003	0.19
397.9014893	0.13
401.4262695	0.09
405.0346680	0.06
408.0781250	0.09
419.3605957	0.19
422.1711426	0.10
432.1864624	0.10
434.2154541	0.07
445.4055176	0.20
447.4102173	0.15
469.1904907	0.08
470.1669922	0.18
476.2398682	0.13
485.6452637	0.15
508.1456299	0.04
509.4214478	0.10
519.4436646	100.00
520.4946899	22.94
521.5582886	0.14
522.2011719	0.15
529.4658203	0.75
530.1347046	0.22
533.6799316	0.13
535.4624023	0.32
545.4295654	0.26
547.4790649	0.39
548.3854980	0.58
549.4345093	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	495.24
Annotation	Rhodioloside B
Peak:m/z	Relative Intensity
138.9164124	0.20
147.0442505	0.14
153.1204224	1.23
155.0705109	0.23
156.8203125	0.13
159.1661835	0.08
163.0179138	0.33
167.0801086	0.99
170.5598907	0.35
179.0782471	0.46
181.1210327	0.31
183.0609894	1.26
187.2350159	0.12
193.1085663	0.06
199.1425781	0.15
207.0426483	1.25
223.2411499	0.06
229.5573120	0.07
233.3001251	0.04
235.2959442	0.12
237.1486664	0.06
240.1607819	0.10
249.0927734	0.17
255.1756897	0.09
271.1380005	0.40
283.2110291	0.22
289.0895996	0.65
291.2296753	0.23
295.2278442	0.24
297.2981567	0.12
299.4184875	0.07
301.2840881	0.40
305.1321106	6.09
305.7763367	0.22
311.2268372	0.07
313.3721924	0.07
314.3119202	0.08
315.2232666	1.92
317.1989746	5.76
319.1053467	100.00
319.7073364	0.59
325.0752869	1.27
327.0924377	0.07
331.2606812	7.18
332.3532410	14.18
333.2471924	27.72
339.2700195	0.15
341.2068481	0.17
343.1469116	0.67
345.2059937	1.02
348.8634949	0.31
355.3477173	0.10
357.3043213	0.80
358.5673523	0.22
360.9721375	0.06
363.2416687	4.83
369.0753479	0.38
370.3839722	0.22
371.0246887	0.17
375.2502136	0.45
379.2635193	0.07
385.4250183	0.15
387.4236755	0.21
399.2905579	0.57
405.3320312	0.21
409.5095825	0.16
411.3290710	0.47
415.1766663	0.21
423.8399963	0.50
435.2706604	0.15
441.2841492	0.13
444.9188538	0.07
446.7657776	0.06
449.5121765	0.30
452.2493286	0.20
458.1710815	0.12
459.2122498	0.62
459.9000244	0.41
464.3046570	0.18
464.9708557	0.06
465.9256287	0.29
467.0163269	0.67
467.6361694	0.34
477.2384338	6.86
478.0408630	0.51
481.4071350	1.60
485.9053040	1.03
486.5295105	0.12
489.6548767	0.15
495.1519470	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0984
Annotation	Castamollissin
Peak:m/z	Relative Intensity
149.1066589	0.05
150.9897614	1.37
152.9207458	0.05
161.1209106	0.04
163.1615143	0.11
164.0176392	0.01
165.0548706	0.02
169.0796356	0.06
173.2566833	0.03
178.9424438	1.85
179.9774170	0.32
187.0693359	0.02
189.1191559	0.25
190.0487976	0.13
190.9815216	0.13
191.5871582	0.09
193.0709839	0.16
194.0076294	0.08
195.0903320	0.02
200.9893341	0.01
205.0455627	0.11
207.2010193	0.08
209.0837402	0.01
210.0329590	0.04
211.0777740	0.18
212.0876160	0.07
213.2518921	0.05
214.1635742	0.07
215.1214142	0.06
217.0015564	0.16
218.0422363	0.04
219.1870575	0.02
221.1290894	0.05
227.3549194	0.02
228.1639099	0.02
229.1468811	0.31
231.0236664	0.06
232.0889282	0.01
233.2729187	0.03
237.3062744	0.02
239.0551758	0.10
240.1359100	0.07
241.2414856	0.10
242.2158051	0.18
243.2581482	0.17
247.1515198	0.02
247.9315643	0.01
251.3057251	0.06
252.9418335	0.10
254.1902771	0.18
255.1318054	0.93
256.1767273	0.23
257.1943665	0.49
258.0172729	0.09
259.0548706	0.06
265.2206421	0.02
266.1364136	0.02
269.3279114	0.06
271.1680908	2.18
272.2180481	0.26
273.1248474	0.94
274.3394165	0.11
275.2355042	0.01
281.2657776	0.10
283.0562744	0.57
284.1357422	0.23
285.3133240	0.17
287.3550415	0.03
295.1689453	0.01
297.0945435	0.17
300.1581421	47.04
301.1220093	100.00
302.1463318	13.84
311.1538086	0.10
312.1205750	0.02
313.2411499	0.53
314.1551819	0.06
315.2456665	0.06
316.0311279	0.03
319.2047729	0.02
321.3019104	0.05
323.3114319	0.04
324.2158813	0.09
325.2231750	0.37
326.5309143	0.10
327.2846375	0.01
329.2672729	0.22
330.5121460	0.05
333.2630615	0.02
336.1545410	0.02
337.4542847	0.05
342.1480713	0.08
343.1437073	2.50
344.2228394	0.44
345.1957397	0.04
353.2936401	0.04
354.4938354	0.02
355.2496948	0.16
356.3223572	0.21
359.0410767	0.03
360.2336121	0.01
361.2495117	0.15
362.4385681	0.01
367.2426147	0.09
367.8855591	0.03
369.2099304	0.07
371.0309448	0.02
373.2528992	0.29
377.2662964	0.04
378.3485107	0.01
379.1116638	0.16
380.3901367	0.03
382.3958435	0.03
383.0471802	0.02
385.2283630	0.15
386.7181091	0.01
395.1054688	0.03
395.7271729	0.01
396.4283142	0.08
401.1157532	0.07
409.4106140	0.04
419.2361145	0.03
427.3372498	0.14
428.0792542	0.02
433.3747253	0.03
436.1180725	0.04
441.3205872	0.01
445.3049622	3.50
446.2168274	0.77
459.1656189	0.09
460.4988098	0.04
461.4082947	0.04
463.2077942	23.35
464.3114929	4.75
465.5189209	0.03
477.4438782	0.03
485.6646118	0.02
487.2890320	0.50
488.2787781	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0725
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9304886	73.46
111.7645264	0.08
113.0725250	0.13
119.0349426	0.13
126.1644516	0.11
128.3844452	0.13
130.9884491	0.16
143.0655365	0.22
144.1152039	0.13
154.8686218	0.08
160.9135437	0.96
172.8849792	100.00
175.6536560	0.12
179.1788330	1.01
190.0474548	0.16
191.2424622	0.86
198.0154419	0.07
221.0427246	0.28
237.0809326	0.36
244.3809509	0.09
263.2621765	0.36
281.0453186	0.10
293.0714722	1.32
307.1754761	0.21
308.9629517	0.19
317.2586670	0.97
333.4215088	0.10
334.2165222	0.42
335.1427612	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.1667
Annotation	Kandelin A-1
Peak:m/z	Relative Intensity
225.1183319	0.34
229.1048737	0.20
231.0651093	0.09
239.4738770	0.06
243.1735840	0.21
245.2539673	0.54
247.0519104	0.25
249.1832581	0.72
250.9872131	0.30
267.1876221	0.06
269.1184692	0.04
271.2777100	0.05
277.1091614	0.05
281.1370850	0.22
285.1113892	0.23
287.2271729	1.58
289.1604614	11.30
295.6066284	0.19
297.2457275	1.21
299.1475525	0.74
303.0899048	0.25
307.1527100	0.39
308.3663330	0.06
311.3270874	0.13
312.9795227	0.06
321.0889282	1.45
325.2337036	0.55
329.4722900	0.13
331.5216370	0.09
337.3285522	0.76
339.2019043	20.14
340.0787964	0.26
341.2689819	0.88
347.1091919	0.11
348.0291138	0.10
352.5003052	0.12
353.2857666	0.05
371.2760010	0.38
372.9002075	0.11
379.4442139	0.21
381.3040771	1.07
383.3375244	0.19
389.3778687	0.23
391.5305786	0.08
394.4661255	0.06
401.3508301	0.12
405.1176758	0.07
407.3317871	1.55
409.3164673	0.97
411.4237671	0.14
413.2643433	0.05
415.1848755	0.43
417.2965088	5.90
423.6189575	0.26
426.2788086	0.10
429.1276245	0.10
431.1529541	0.68
433.3150024	2.14
435.2589722	33.41
437.2927246	0.15
445.3027954	0.60
447.4086914	0.05
449.1783447	16.50
450.0192871	0.04
451.2009277	18.40
455.2361450	0.27
457.3239136	0.29
459.3753052	5.13
461.1314697	0.36
463.2005005	0.56
467.3419800	0.24
469.9476929	0.10
471.1430054	0.06
472.5506592	0.15
473.2545166	0.12
475.3100586	0.06
477.2771606	5.02
489.3798218	0.49
491.1714478	0.49
493.2828979	0.07
501.5402832	0.30
502.3933105	0.28
504.1417236	0.12
506.3145142	0.11
507.3139038	0.75
517.4498291	0.06
525.2377319	0.06
527.4384155	0.24
531.2186279	0.07
533.5619507	0.30
535.1289062	0.09
543.2274780	1.00
549.2429810	0.21
558.1066284	0.12
559.2086182	1.12
567.5228882	1.49
569.2844238	28.39
570.2917480	0.12
571.3422241	0.54
572.5397949	0.08
573.4875488	0.64
575.2634888	0.89
576.1497192	0.30
577.3962402	1.51
585.2602539	2.76
585.8604736	0.07
587.2324219	100.00
588.2681885	0.28
589.4651489	0.97
593.3588257	0.17
594.3881836	0.27
597.5050659	0.14
599.3843384	0.73
606.5264282	0.53
611.2989502	5.04
612.0722656	0.09
613.3668213	2.95
617.4707031	0.22
619.3390503	0.18
626.7324829	0.39
629.3418579	16.64
631.5043945	0.19
634.7185059	0.06
641.0477905	0.26
643.1177368	0.15
648.4498901	0.15
651.3356323	0.04
653.4179688	0.09
657.2485962	0.33
658.3806763	0.27
660.8209839	0.20
662.1557617	0.93
662.8821411	0.10
663.5127563	0.07
666.4059448	0.38
677.2274780	1.07
678.5513306	0.27
679.3732300	0.07
691.7982178	0.12
693.4945068	0.42
695.3643188	4.78
702.0171509	0.19
703.3367310	0.59
707.2051392	0.18
711.8459473	0.18
717.1977539	0.34
719.5060425	0.26
720.4082642	1.24
721.4182129	10.44
722.9027100	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	618.86
Annotation	Unknow
Peak:m/z	Relative Intensity
236.0192719	0.05
273.0508423	0.28
274.0766907	0.38
275.0941772	0.86
276.1478577	0.15
277.1298828	0.04
289.2084961	0.31
372.9544678	0.03
387.0704346	0.32
388.2544556	1.19
389.1365967	1.55
390.0850220	0.74
391.0534668	0.53
404.2276611	0.05
405.3544922	0.03
418.9473267	0.05
427.2345581	0.04
458.9365845	0.24
460.1937256	0.05
463.0475464	0.08
472.0454102	0.04
473.0605469	0.21
474.1605225	0.05
475.0187988	0.15
479.0932007	0.02
487.1941528	0.09
487.8104248	0.03
489.1832275	0.32
501.2426758	0.33
502.0559692	2.93
503.0068970	5.39
503.9873657	7.83
505.0152588	7.81
512.6634521	0.04
516.9519043	0.09
517.8286133	0.05
527.2426758	0.04
533.1585693	0.06
534.2247925	0.07
545.0620117	0.19
548.0469360	0.05
549.9411621	0.09
550.7582397	0.19
562.6830444	0.11
572.9024048	100.00
573.8681641	0.84
575.1560669	0.57
577.6790161	0.08
590.9756470	0.11
591.9984741	0.10
600.0881958	0.14
600.9364624	0.09
608.9597168	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.104
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0851746	0.47
154.0842438	0.02
161.2987823	0.03
169.0341644	0.04
171.2668457	0.06
174.1341553	0.05
174.9604492	0.24
175.9887390	0.02
177.1625366	0.03
185.3175354	0.03
196.0223694	0.07
197.2126465	0.31
198.2031860	0.06
199.0557861	1.33
201.0598450	0.29
211.2955017	0.04
213.0568542	0.13
217.1036682	0.96
219.1712494	0.09
223.1956940	0.10
241.0622864	14.67
242.2858276	0.27
243.2075195	0.63
245.1541138	0.06
259.2752991	0.03
267.0712891	0.59
275.2868652	0.06
281.1584778	0.03
283.3135071	0.05
285.0907898	100.00
287.3024902	0.02
300.2219238	0.02
301.1232300	0.08
302.2942810	0.13
303.2599487	1.62
312.9908142	0.03
315.1982422	0.18
315.9181213	0.08
329.2173157	0.49
339.2482300	7.58
355.2929993	0.43
378.1390686	0.02
381.2828064	0.16
397.2760315	0.17
403.2794495	0.04
421.2711487	0.45
433.1082153	0.02
434.3577576	0.04
435.1968384	0.04
447.0462952	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1034
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
109.0773010	0.11
110.9071808	0.17
119.1132736	0.17
127.1669846	0.02
134.0968018	0.28
154.9831238	0.04
163.0175476	1.47
165.1909485	0.04
170.8930969	0.13
173.0747375	1.45
175.2317200	0.10
178.0418091	0.09
179.1423340	0.05
187.2554932	0.11
191.0456543	100.00
193.0932007	6.16
200.7910767	0.07
264.9607544	0.09
286.1199341	0.04
295.3755188	0.08
321.3292236	0.12
323.2056274	0.08
324.1605835	0.03
336.1739807	0.04
348.2900696	0.03
349.1950989	0.07
352.2549133	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.317
Annotation	Juncin J
Peak:m/z	Relative Intensity
224.0422058	0.03
224.9659119	0.03
238.1306458	0.04
239.1902618	0.05
253.2856445	0.03
255.9545746	0.03
300.2709351	0.07
311.2262573	0.03
313.2762451	0.03
328.1796875	9.06
329.3193359	0.62
343.2201538	100.00
344.3326416	8.60
357.3554688	0.05
358.3521423	0.09
379.1098022	0.04
381.3725586	0.02
429.4081421	0.01
447.1494141	0.02
461.7094116	0.01
499.5567017	0.04
522.6104736	0.01
543.1593018	0.02
547.5281982	0.02
553.6559448	0.14
554.5042114	0.03
559.5608521	0.02
567.5667725	0.06
568.6843262	0.04
571.3428345	0.06
601.5885620	0.03
612.2647095	0.06
622.5814819	0.05
628.7249146	0.05
650.4522095	0.02
675.7297363	0.02
676.4755249	0.02
684.2203979	0.04
727.8164673	0.05
733.3997803	0.02
734.3112793	0.02
744.2088013	0.03
745.5176392	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	933.6971
Annotation	TG(13:0/22:4(7Z,10Z,13Z,16Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))[iso6]
Peak:m/z	Relative Intensity
355.4997864	0.11
395.3994751	0.04
405.4976807	0.20
407.4495239	1.84
455.4491577	100.00
456.0896606	0.20
456.7238159	0.09
494.7307129	0.04
587.7373657	0.13
591.8102417	0.04
619.4962769	0.20
704.0465088	0.05
704.8676758	0.09
710.5415649	0.05
721.8031006	0.03
728.2890625	0.05
744.1912231	0.17
776.9684448	0.05
790.5081177	0.04
800.0325928	0.09
813.9338989	0.03
829.0190430	0.07
831.4990234	0.05
842.0515747	0.03
861.7808228	0.25
870.7475586	0.03
871.3618774	0.09
874.0283813	0.22
875.0855713	0.08
875.6975098	0.14
889.7492065	0.04
905.3025513	0.10
915.0950317	0.43
915.9395752	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0858
Annotation	Gerfelin
Peak:m/z	Relative Intensity
91.3772278	0.28
95.0222778	0.41
105.0207672	0.18
119.0032501	0.13
122.9152908	84.46
127.2050781	0.35
129.4386292	0.21
134.9869995	0.71
137.1656952	0.16
138.9400024	100.00
139.9564209	0.12
146.9491119	7.17
151.0101471	22.30
153.1579285	0.21
162.9363708	0.79
165.0615540	46.37
167.2896118	0.09
169.0744934	2.03
181.0563354	0.54
199.1443176	0.28
200.3030396	0.35
209.0179138	1.11
209.9201660	0.51
227.0423279	0.26
235.0372009	0.29
245.1267090	0.50
248.9833069	0.55
273.0044556	28.91
273.6771851	0.72
279.7586060	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.0932
Annotation	Taxifolin 3-apioside
Peak:m/z	Relative Intensity
124.9287415	0.06
149.1623230	0.08
155.2653351	0.01
160.9664307	0.04
164.9219208	0.04
167.1513214	0.06
169.3448486	0.04
174.7745972	0.03
177.3821106	0.02
182.0981293	0.01
192.0906067	0.05
194.2016602	0.02
197.2350006	0.01
199.0586243	0.24
201.1397705	0.01
213.2472229	0.02
215.2750549	0.01
217.0525665	0.11
219.0014801	0.02
220.2331543	0.01
226.2951965	0.02
230.1106720	0.01
231.0230408	0.02
241.1832886	6.20
243.1618958	0.17
244.0444946	0.08
255.2811279	0.01
257.1503296	0.08
266.9935303	0.13
271.2378540	0.06
272.3037109	0.09
285.1314087	100.00
299.0918579	0.68
300.1285400	0.19
301.1289673	0.19
302.2573242	0.11
303.1544800	1.28
307.8977051	0.07
309.2088013	2.71
313.9682922	0.06
316.1734314	0.04
325.2023926	0.60
330.3337402	0.02
332.2705994	0.02
344.1966248	0.02
349.1123047	0.03
351.1790161	0.01
367.2020569	0.03
380.3378601	0.03
388.5267029	0.01
389.2420959	0.04
391.1520081	0.09
404.2083130	0.02
406.2559814	0.15
420.2436218	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1721
Annotation	Malvin
Peak:m/z	Relative Intensity
183.1637878	0.02
193.0909119	0.03
201.1402893	0.06
202.9604797	0.07
206.9531555	0.01
209.0759735	0.04
215.1622620	0.06
216.2613678	0.04
219.1887665	0.07
220.2449036	0.02
225.0035400	0.02
226.1969757	0.02
227.2077942	0.02
229.3873596	0.02
230.0713501	0.01
231.1564026	0.01
233.0364380	0.03
234.2577515	0.01
235.2205658	0.01
236.2464294	0.01
240.1066284	0.01
241.5529938	0.04
242.2558289	0.07
243.1600800	0.23
244.3128357	0.03
245.2292023	0.01
249.3666992	0.01
250.0425415	0.02
253.1339722	0.02
255.0060272	0.01
256.2183228	0.02
257.0899963	0.01
258.4528809	0.12
259.1780396	0.41
260.2396240	0.07
263.2973022	0.04
267.5575562	0.01
269.1585083	0.09
270.4456177	0.25
271.2678833	1.22
272.1948242	0.22
273.1361084	0.18
274.2749023	0.19
275.4398193	0.01
277.1412354	0.03
283.5371094	0.07
284.4662170	0.07
285.1774902	0.62
286.1711121	0.19
287.1635742	1.96
288.1589355	0.20
289.2916260	0.26
290.0349731	0.02
290.9884033	0.02
297.2271118	0.10
298.9323120	0.13
300.1910400	0.09
301.1078491	0.46
302.1726685	0.51
303.1738281	0.08
305.4203796	0.03
309.2363281	0.05
312.3079224	0.01
313.2970581	0.04
315.1288147	9.13
316.2052002	1.03
317.2447510	0.95
318.2478027	0.19
319.5064392	0.03
324.2761841	0.05
326.8688049	0.02
328.1295166	0.20
329.3097839	1.66
330.1781616	13.70
331.1760864	2.71
332.1495972	0.07
337.1163330	0.02
338.4816284	0.01
343.2372437	1.34
345.1188354	100.00
346.1881714	16.67
350.9380493	0.02
352.1784058	0.01
354.1477051	0.01
355.0418091	0.01
356.2697144	0.07
357.2211304	0.07
358.1702881	0.02
359.3594360	0.08
361.1035767	0.04
367.9785767	0.02
369.2493286	0.01
370.3544922	0.01
372.2145386	0.03
373.5754395	0.03
383.5652466	0.02
385.5582886	0.04
387.2395020	0.96
388.1832886	0.12
397.3898315	0.02
402.1838989	0.03
417.2149048	0.11
418.1805420	0.01
427.1297607	0.02
439.3720093	0.04
445.4566040	0.02
449.1949463	0.01
453.1553345	0.04
455.3078613	0.01
461.0372314	0.02
471.1690674	0.06
473.3560181	0.07
474.3973999	0.07
490.3988647	0.07
491.3127441	0.09
492.0110474	0.01
493.2679443	0.08
494.3146973	0.01
499.3393555	0.01
500.5991211	0.07
502.7861938	0.02
505.2422485	0.03
506.2938232	0.01
507.3975830	0.04
509.1539917	0.11
515.6308594	0.01
520.6461182	0.02
521.3174438	0.04
522.5645142	0.01
523.5617676	0.08
527.5641479	0.02
529.5664673	0.03
531.4865112	0.02
538.4274902	0.02
545.4215088	0.02
547.9068604	0.02
557.2644653	0.03
561.4464722	0.06
564.7648315	0.02
566.9059448	0.01
569.3406372	0.01
571.5254517	0.05
572.4170532	0.05
576.9027710	0.06
579.3383789	0.02
589.3967896	0.09
592.8652954	0.03
593.5532837	0.01
594.3619995	0.04
607.4131470	0.50
608.3500366	0.03
609.4702759	0.02
610.4139404	0.03
617.3535767	0.03
621.3527222	1.08
622.5067749	0.21
623.5801392	0.03
625.2000122	0.49
626.2963257	0.10
633.4002686	0.04
635.4695435	0.08
636.1339722	0.01
638.4240112	0.22
639.3640137	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1295
Annotation	Erlangerin D
Peak:m/z	Relative Intensity
145.0275574	2.39
152.0635834	0.07
152.9127808	0.07
155.2828369	0.04
157.0508728	0.08
157.9635315	0.06
159.1682587	0.08
160.3721924	0.07
161.1945648	0.13
163.0540314	12.35
171.1369629	0.08
173.1621552	0.14
175.1369324	0.10
177.0826416	0.04
185.2333374	0.05
187.1289978	1.23
189.1867828	0.07
191.3162384	0.11
203.0631409	0.22
205.0031738	0.38
215.1616211	0.11
217.1303253	0.10
217.9594574	0.10
219.1616821	0.10
229.0719910	0.12
230.9804077	0.08
235.0092621	0.17
241.2873840	0.17
247.1624146	0.61
249.1924438	0.48
265.2825012	0.19
267.2301636	0.40
289.0464478	0.04
307.1293945	100.00
309.1776123	0.13
379.2655334	0.03
413.4404602	0.04
425.2471924	0.04
427.2209778	1.06
427.8815918	0.02
453.2556152	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2554
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0223236	0.09
167.0479126	0.04
175.1625366	0.03
177.1734009	0.04
179.0225220	0.03
189.1464996	0.02
191.0194702	0.08
193.0404053	0.03
217.4054260	0.03
236.3691711	0.02
237.1982880	0.05
272.4908447	0.01
273.3775024	0.02
287.2758179	0.13
288.1293945	0.03
289.0449829	0.14
305.1834717	0.04
314.3524780	0.03
315.3553467	0.09
319.3593750	0.02
321.3317261	0.03
331.3055420	0.06
333.3489380	0.02
335.3549805	0.79
336.3128662	0.10
337.3706665	0.15
343.2073364	0.01
345.2604980	0.05
351.1517944	0.15
355.2770996	0.05
357.0571899	0.15
367.3167114	0.05
387.1952515	0.02
391.2347412	0.04
393.1041870	0.03
407.2304688	0.02
408.4285889	0.05
409.2678223	0.04
414.3303833	0.07
423.3778687	0.03
424.7312012	0.03
428.4221802	0.16
431.5576172	0.09
436.3708496	0.09
437.3641968	0.11
445.1030273	0.05
451.1278687	0.12
452.1896973	0.05
458.2617188	0.03
458.9405518	0.02
464.4635620	0.63
466.2595215	7.27
467.3511963	100.00
468.1776123	0.02
469.2740479	0.46
471.2432861	0.06
477.4053955	0.06
479.2554321	0.02
480.5685425	0.24
481.5432739	0.23
483.4905396	0.10
489.7225952	0.03
494.9707031	0.49
495.5718994	0.17
497.2504272	0.04
498.5620728	0.08
504.3010254	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.0561
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.9530907	1.33
61.0658913	0.08
70.9952087	3.68
73.1238785	0.42
74.9967270	6.24
80.9643326	6.03
85.1976700	0.15
86.9921112	6.84
88.9672775	15.34
96.8849029	1.00
98.9713440	20.85
100.9345398	3.08
106.4673767	1.42
107.1066742	0.36
112.9945831	4.91
115.0007172	0.86
116.9555054	0.77
118.9847870	8.55
125.0783234	7.36
130.9022064	6.26
133.0089722	0.38
140.9746399	0.09
142.9457550	100.00
148.9324799	2.21
151.0584869	0.12
159.0305939	0.14
160.9785004	47.79
164.1352997	0.05
179.1802216	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1406
Annotation	Castamollissin
Peak:m/z	Relative Intensity
163.1395569	0.07
165.0192108	2.20
167.0143738	0.18
174.9896698	0.05
180.2480164	0.08
181.1457520	0.12
190.9449158	0.10
193.0083160	5.99
195.1617279	0.22
197.1403503	0.07
203.0129395	0.09
205.1321716	0.05
207.1033020	0.28
217.0966339	0.06
220.8970642	0.02
228.0140686	0.05
229.1715240	0.04
231.0065918	0.20
235.3282318	0.05
242.4487762	0.15
244.2263947	0.07
245.2401276	0.07
246.2663574	0.22
258.2557373	0.03
259.2243042	0.12
261.1779175	3.56
265.0633545	0.17
270.3415527	0.18
275.2230225	0.04
277.2741699	0.12
285.7727051	0.06
287.0308838	0.19
288.2218628	0.25
297.0579224	0.05
299.0519714	0.13
301.2294312	0.23
303.1833496	3.12
314.2189941	2.71
319.1639404	0.79
329.2252808	55.37
331.1666260	0.49
332.4736328	0.03
341.0538330	0.03
345.4569702	0.39
347.1290283	100.00
349.1551514	0.05
353.2727661	0.24
354.9835205	0.26
357.2299805	0.08
359.4514160	0.11
368.1420898	0.05
369.5135498	0.22
371.2844849	4.99
383.1770630	0.07
386.2308960	0.24
389.3803711	0.37
397.1600952	67.40
397.7895508	0.25
401.3446655	0.74
419.4227905	0.03
425.2721558	0.05
465.3328857	0.28
467.5352173	0.06
471.2918091	0.03
491.5082397	0.04
505.3574829	0.35
507.0816040	0.21
509.1420288	0.06
531.2380981	0.13
533.2622681	3.55
536.1648560	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2707
Annotation	Ixerisoside J
Peak:m/z	Relative Intensity
178.9014130	0.06
190.0709839	0.09
191.1281891	0.07
195.2994995	0.05
209.2390137	0.06
211.0902710	0.03
219.0061035	0.07
220.8233337	0.02
221.8031616	0.12
228.2408600	0.04
239.0787354	0.04
245.0288849	0.13
249.0852356	0.05
255.4631653	0.10
259.2189331	0.03
276.2619019	0.05
277.4000854	0.04
281.6940918	0.11
285.0556641	0.06
289.2360229	0.07
293.1730347	0.67
294.2448120	0.52
301.3760986	0.09
305.2214355	0.16
310.5000305	0.09
311.1859436	0.09
312.0073853	0.04
321.1656494	0.05
323.4187012	0.18
327.5767822	0.05
335.0990601	0.11
343.1368408	0.08
357.6334839	0.12
370.4511108	0.04
377.3822632	0.06
386.0384521	0.03
395.2866821	0.44
396.6748047	0.45
397.3024902	6.79
404.4354248	0.23
407.3511353	0.04
408.4667358	0.03
412.1079102	0.09
413.2642212	0.71
417.4889526	0.06
421.3357544	0.08
427.2001343	0.50
429.4378052	0.12
430.2155151	0.09
431.2999268	0.13
435.4105225	0.18
436.5899048	0.07
443.0912476	0.07
448.5620117	0.05
449.4425049	0.28
453.3041382	0.05
454.6502686	0.13
459.4761353	0.04
464.4147339	0.33
471.6779175	0.17
483.3723145	0.07
484.4958496	0.15
485.3118896	0.11
489.4131470	0.83
491.2767334	0.07
497.2887573	0.05
507.6145020	0.34
511.4246216	0.39
513.4763184	0.06
514.2756958	0.04
515.5287476	0.17
526.2780151	0.19
529.3074341	100.00
530.0604248	0.33
531.2744141	1.56
532.4879761	0.07
537.3193359	7.22
538.3229980	4.96
539.3743286	1.25
540.2516479	0.04
544.5850220	0.03
545.4965210	0.05
547.2890015	0.06
554.3834839	0.13
555.3113403	0.27
556.3583984	0.82
557.3650513	1.10
560.4545288	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.02
Annotation	Unknow
Peak:m/z	Relative Intensity
78.8669891	16.54
87.0386734	0.10
96.8724213	100.00
131.1119843	0.28
138.9306641	6.39
143.1102753	0.07
144.1652374	0.17
161.0878754	1.72
168.8738556	19.09
171.0180817	0.69
172.0617981	0.15
173.1385040	1.01
174.1010590	0.12
175.1855927	0.54
177.2403107	0.14
181.1591797	0.16
182.8370361	0.20
185.9184723	0.14
192.2965546	0.33
199.0181580	26.72
204.8444824	0.08
214.2286987	0.37
215.1338959	0.19
222.9603119	4.14
228.8963470	0.97
241.0211945	29.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.1088
Annotation	Unknow
Peak:m/z	Relative Intensity
150.9909515	0.27
163.1105042	0.07
168.9344177	0.04
179.0730896	1.50
180.1740875	0.11
185.0802307	0.03
188.0902100	0.07
191.2834778	0.02
191.9613647	0.04
192.9939575	0.06
197.1849976	0.05
203.1122742	0.13
205.1054230	0.22
206.1766968	0.07
207.4435272	0.01
209.1229401	0.05
213.2404175	0.08
214.1954041	0.05
215.2801514	0.04
217.1420898	0.03
218.2325745	0.07
220.0199432	0.14
221.0564880	0.12
226.3230591	0.06
227.0433655	0.05
228.1046906	0.02
230.3416748	0.05
231.2530518	0.15
231.9856262	0.06
234.1045532	0.03
239.0807953	0.07
241.3032379	0.03
242.1564331	0.08
242.9929504	0.18
244.2270508	0.04
245.2313080	0.03
246.0844879	0.07
247.0926361	0.05
254.9550629	0.22
255.9139404	0.04
257.2709045	0.04
259.1748352	0.09
269.0547485	0.05
270.0744019	0.37
271.1587524	0.38
272.3803101	0.07
273.3161621	0.03
274.0232849	0.07
275.2435913	0.13
276.9909668	0.09
283.1055298	0.04
284.1425781	0.12
285.1293945	0.49
286.1047974	0.16
287.1356201	0.48
288.2449341	0.24
289.2212524	0.12
292.1471252	0.05
297.2790222	0.02
298.2343750	0.68
299.2921753	0.14
299.9863586	0.15
301.2190552	1.28
302.2643433	0.23
303.2039185	0.22
308.3904419	0.06
310.2015381	0.04
311.4168701	0.13
312.3193970	0.20
313.2003174	0.57
314.0308228	0.04
315.1135254	3.72
316.1804810	5.02
317.0570068	0.09
319.2080688	0.15
320.1644287	0.03
322.2225952	0.04
323.2050781	0.17
327.1793823	0.29
328.0385742	0.21
329.5247192	2.20
330.1555786	51.51
331.1502686	100.00
332.1124268	0.24
335.3829346	0.07
336.9971313	0.19
341.0885010	0.36
342.5017090	0.10
343.3519287	0.36
346.3672485	0.04
353.2504883	0.13
354.0855103	0.07
355.2451782	0.03
358.2250977	0.06
359.4866333	0.03
367.1654663	0.05
369.1575317	0.23
370.0991821	0.10
371.4097900	0.05
373.2927856	2.68
376.3273315	0.02
383.1979980	0.26
388.2928467	0.02
393.0050049	0.06
394.0723877	0.08
395.8311157	0.04
403.3802490	0.04
404.2374268	0.06
407.0037231	0.04
409.3649292	0.08
411.4004517	0.03
413.4943237	0.02
415.3572388	0.07
423.9576416	0.15
425.6799927	0.04
429.1248779	0.01
430.1764526	0.06
443.1991577	0.08
447.4373169	0.03
449.3499146	0.19
451.0317993	0.04
454.5178223	0.04
461.4458618	0.21
463.1527100	0.02
466.6132812	0.09
473.5333862	0.09
475.1779175	2.45
476.3465576	0.08
477.4159546	0.07
487.5535278	0.03
488.7214355	0.55
489.3972168	1.10
491.4016724	0.25
493.2154541	11.53
498.0057983	0.03
499.2885132	0.02
501.5929565	0.11
502.2851562	0.04
503.3543091	1.17
507.2632446	0.04
516.2734375	0.09
517.3583984	0.97
518.3637695	0.09
519.7951050	0.26
520.3961792	0.78
521.6216431	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	723.1519
Annotation	Thonningianin B
Peak:m/z	Relative Intensity
249.2167664	0.09
287.2359619	0.14
313.1712036	0.04
329.4095459	0.17
336.7077637	0.09
397.2529297	0.05
416.3414917	0.04
419.6184692	0.02
423.2986450	0.65
424.2539062	0.06
432.9376221	0.08
453.1295166	0.11
460.8203125	0.12
462.0225220	0.06
465.4519043	0.05
479.2783203	0.02
514.1426392	0.07
515.3397827	0.04
525.2386475	0.06
538.4191284	0.05
552.4396973	0.04
555.2122803	0.03
556.2542725	0.04
558.4890137	0.03
560.2428589	0.04
561.3629761	0.18
562.3931274	0.22
567.1309204	0.02
572.1154785	0.03
573.3515625	0.47
574.4604492	0.04
591.2468262	100.00
592.3418579	34.05
593.7525635	0.05
619.4505615	0.02
621.3977661	0.08
633.2933960	0.04
634.9122314	0.04
641.8834229	0.08
654.2622070	0.17
687.8030396	0.07
692.3583374	0.05
705.1926880	0.14
706.1363525	0.07
707.2698364	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0459
Annotation	Amaronol A
Peak:m/z	Relative Intensity
97.0235825	0.03
108.9963226	3.71
121.3175354	0.05
136.2855377	0.08
136.9751740	0.61
139.1156921	0.13
142.9646301	0.05
151.0849609	0.22
152.9480896	50.98
164.9874878	100.00
171.2117615	0.10
178.9610748	0.09
183.0308228	39.71
183.6646881	0.17
193.0673370	4.03
219.2213135	0.06
231.2793274	0.09
275.0645447	0.47
301.1656799	2.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
85.13937378	0.45
88.97668457	0.81
107.2538452	0.55
109.2132721	0.87
120.6761475	0.30
133.0371704	0.84
141.0389709	0.84
149.1890717	1.47
152.8956146	0.64
167.0644073	0.71
169.3143463	0.69
177.2655029	0.89
178.9395294	1.56
180.0381317	0.85
181.1704407	1.79
183.3029175	0.33
189.099411	0.33
191.2302856	0.27
193.269928	2.09
195.0782013	1.61
205.0502167	3.72
206.0378876	0.49
207.141098	13.19
208.1837921	4.70
209.1839142	2.76
214.9237366	0.93
221.1503143	0.85
222.1569977	8.74
223.1094513	10.69
231.9738007	0.88
233.1784821	10.07
234.3386688	0.48
235.173584	0.37
236.0704498	0.78
251.0791779	100.00
252.1403046	8.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.1364
Annotation	Unknow
Peak:m/z	Relative Intensity
287.3800964	0.05
303.2884521	0.20
305.1340637	0.02
314.9133301	0.03
319.2116089	0.02
329.2098083	0.03
343.1075134	0.02
359.2659302	0.01
373.7191162	0.10
386.1512451	0.04
451.3519897	0.12
453.3597412	0.02
467.1823120	0.05
468.0909424	0.03
469.3225708	0.02
470.0266113	0.04
494.2250977	0.03
495.4023438	0.19
525.5852051	0.02
532.1381226	0.02
543.2104492	0.02
575.0140991	0.02
584.9640503	0.01
589.2559204	0.02
593.1194458	0.05
603.3263550	1.33
607.2897339	0.02
611.1689453	0.01
613.0637817	0.01
615.0734863	0.03
617.4022827	0.03
619.3084106	0.67
621.2097778	100.00
622.0899048	0.01
627.1546631	0.02
632.4837036	0.04
633.4350586	0.04
638.0965576	0.01
647.3510742	0.08
650.5391235	0.34
651.5043335	0.21
652.2111206	0.01
655.0891724	0.02
658.2041626	0.01
684.1580200	0.07
694.0504150	0.02
698.8035278	0.04
703.3958740	0.03
704.6258545	0.01
717.1653442	0.02
721.7551270	0.03
722.9962158	0.01
737.4063110	0.03
739.0443726	0.01
746.4154663	0.01
747.4043579	0.02
759.1544189	0.01
764.1397095	0.01
765.2446289	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	233.0853
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0377655	0.07
88.9201126	0.27
96.9549255	100.00
98.9812469	0.48
100.8994904	0.08
129.0863342	0.05
130.8241425	0.06
138.9370117	0.09
142.9550323	0.32
145.2216339	0.15
146.4949036	0.05
152.9948883	0.12
157.0285034	0.26
159.1473236	0.38
161.0193634	0.20
164.9215393	0.12
171.1992645	0.10
172.9616394	0.32
173.8068542	0.11
177.3722687	0.05
189.0611420	1.55
190.9335480	0.29
197.0958405	0.16
205.0193176	0.57
215.0750885	3.64
217.1668854	0.13
233.1400299	2.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.197
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.1871490	2.01
245.1941223	1.82
246.3345490	0.14
249.1331024	0.11
255.0648499	0.27
257.3671875	0.37
258.1575012	0.09
259.2412109	0.19
261.1752930	0.59
268.1293945	0.39
269.1395264	0.48
270.0872498	0.08
273.0993958	0.63
280.8462524	0.50
285.2393799	0.36
287.1108704	15.27
288.1959839	0.87
289.2295532	6.06
290.1083374	1.19
291.2891846	0.38
292.9627075	0.09
294.1858521	0.08
297.2614746	0.40
299.1667480	4.34
300.0356445	0.28
303.3038025	0.46
306.8951721	0.26
309.1668701	0.12
311.2559814	0.09
315.0480347	0.10
326.0731506	0.15
327.2395630	0.33
328.4883118	0.16
329.3091125	0.98
330.4893188	0.20
331.2918701	0.82
335.2167053	0.11
337.3335571	0.35
339.1952515	0.56
341.2947388	0.46
342.2954102	0.21
345.1871948	0.05
349.3665771	0.18
350.8416748	0.13
351.4977722	0.17
352.5255127	0.14
353.4165039	0.16
355.3173218	0.16
356.4735718	0.12
359.3883362	0.21
363.2211914	5.33
364.2859497	0.57
365.3420410	0.59
367.2581177	1.22
369.3306885	0.78
371.4628296	0.44
379.2149963	0.52
381.2000122	0.71
383.4514160	0.31
384.2423706	0.10
385.3388062	0.06
387.2583618	1.03
388.1811523	0.18
389.1652222	0.18
390.2410889	0.30
391.2463989	0.32
393.4219360	0.25
395.2475586	4.55
396.1390381	0.71
398.4586182	0.05
403.1577759	0.63
405.2461548	8.90
406.1445312	0.95
407.2067871	24.99
408.3393555	2.67
409.3599854	0.87
411.2167358	1.16
412.6394653	1.85
413.2857666	7.72
414.2373657	1.03
415.0182495	0.13
417.2045288	0.98
418.2124023	0.24
421.3835449	0.13
423.2661133	6.70
425.1647339	24.25
426.3652344	0.66
429.2771606	0.06
431.1458130	0.53
432.0588379	0.06
433.3453369	1.03
435.2696533	2.10
436.2216187	0.22
437.1891479	0.68
447.0832520	0.38
449.1749268	14.25
450.2028809	2.22
451.2990112	18.77
452.2144165	1.99
453.4178467	0.84
454.4699097	0.10
455.6281128	0.22
459.3113403	0.10
465.1965332	1.45
467.3136597	2.51
468.4928589	0.05
473.4145508	0.09
475.3967285	0.28
477.4003906	0.38
483.4608154	0.24
489.3085938	0.07
491.4502563	0.86
493.2846069	0.52
494.2588501	0.07
495.4863892	0.20
499.4128418	0.61
500.1211548	0.10
501.2980347	0.13
509.3355713	0.36
515.1240845	0.78
516.4284058	0.31
517.3729248	1.49
518.8357544	0.78
525.3126831	2.94
526.3400269	0.19
531.5440674	0.58
533.2200317	7.27
534.3231201	1.41
535.3546753	0.57
536.5247803	0.06
539.0856934	0.12
540.4486084	0.24
541.6377563	0.23
543.3645630	16.60
544.3056030	1.47
545.3538818	0.47
555.3087769	0.08
557.3237915	4.44
558.2238159	0.99
559.3417358	4.97
560.3469849	0.97
561.3010254	4.19
562.2396851	0.59
563.3070068	0.07
567.4310303	0.50
569.2673950	4.08
570.4096069	0.54
574.6251831	5.86
575.2598267	27.36
576.1691895	4.22
577.3231812	57.31
578.3308105	5.21
579.3633423	0.11
583.1949463	0.09
585.3911133	0.38
587.2533569	19.87
588.3934937	2.96
589.3319702	0.15
593.6597290	0.11
598.4146729	0.24
599.3619995	0.23
600.3292236	0.18
601.3150024	0.51
602.9229736	0.33
603.5497437	0.18
617.4440308	1.00
618.3239136	0.37
619.2752075	5.18
620.3919067	0.65
629.3751831	1.30
630.4076538	1.06
634.8698730	0.06
643.5631714	0.19
645.4971924	0.34
651.4336548	0.91
652.2742310	0.10
654.3930054	0.13
658.3586426	0.17
659.3807373	0.73
661.5302124	0.09
667.1997681	0.09
669.3298340	2.62
670.2124634	0.29
671.3760986	0.11
673.4501343	0.17
677.2188110	6.86
678.5562134	2.19
679.3799438	0.10
680.2013550	0.21
684.3492432	0.19
687.5421753	0.19
693.3641968	1.18
695.2565918	100.00
696.2258301	9.84
697.5026245	0.53
698.3275146	0.19
701.6119995	0.24
703.4098511	1.58
704.4255981	0.51
709.3170166	0.39
711.1678467	0.74
712.5425415	9.14
713.2635498	43.57
714.2198486	6.98
717.1576538	0.30
720.2429810	0.79
721.2637329	3.40
722.2752075	0.41
725.5916138	0.54
733.2716675	0.54
735.0521851	0.10
737.6119995	0.81
739.2756958	50.29
740.3132935	10.23
743.3469849	0.37
754.7352295	0.31
755.3900757	1.89
756.4674683	0.25
759.4447021	0.08
762.9688110	0.16
771.8202515	0.18
780.1694336	2.20
785.3513184	0.14
789.0722046	0.93
789.8590698	0.95
797.6431274	0.09
802.6939087	1.15
803.3731079	0.61
815.2891846	0.12
819.3120117	0.25
821.4435425	2.88
822.4828491	1.04
829.5312500	0.49
830.4992676	0.11
834.8402710	0.05
837.4652710	0.06
847.2944946	18.09
848.2751465	6.18
849.3910522	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1142
Annotation	Castamollissin
Peak:m/z	Relative Intensity
148.9181519	0.06
150.9169617	0.32
153.2739563	0.11
157.1372223	0.03
160.0460052	0.03
160.9214935	0.03
162.9279785	0.30
165.0274506	0.34
173.0668945	0.08
174.0658569	0.06
175.0395660	0.10
176.1269836	0.06
178.0488892	0.07
179.0643005	0.76
179.8645782	0.15
188.3881989	0.09
189.0378571	0.48
189.8941345	0.23
191.2253113	0.27
191.9492798	0.30
193.1669312	0.17
195.0778046	0.04
201.0875549	0.18
202.0539856	0.06
204.1710358	0.55
205.1553040	0.63
206.4226532	0.10
208.9047241	0.09
214.2671814	0.22
215.1246796	0.33
215.9569855	0.04
218.1029053	0.08
220.0607910	0.07
221.0288391	0.20
222.3681183	0.14
223.1156311	0.18
224.7655792	0.05
226.4047394	0.31
227.3567810	0.03
228.1309814	0.09
229.0600891	0.17
232.5339966	0.11
233.2918396	0.09
234.0366821	0.10
235.2272339	0.15
238.2418365	0.06
239.2250671	0.10
240.5335693	0.12
241.2358246	0.09
242.1507721	0.27
243.1506042	3.59
244.1586456	0.16
245.1319733	0.31
246.0190125	0.03
247.1680298	0.29
248.4336243	0.29
249.3249207	0.28
252.3175354	0.09
254.1311798	0.25
255.1151733	0.12
256.0815735	0.30
257.2055969	1.14
260.1732178	0.06
261.2210693	0.62
263.1944275	0.03
269.2703247	0.71
270.4785156	2.28
271.2107544	6.85
272.1582336	0.32
273.0697021	1.54
273.9879456	0.03
275.0501709	0.23
281.3475952	0.16
282.1800232	0.13
283.2637329	0.19
285.0748291	11.39
286.0990906	3.99
287.2221069	0.97
288.0104370	0.05
289.2053223	0.37
291.1597595	0.13
294.2166748	0.03
296.3849487	0.11
297.0335388	0.12
298.1932373	0.79
299.1736450	6.01
300.1502686	5.51
301.2612915	0.39
302.9492188	0.05
309.0791016	0.08
311.3246460	0.85
312.2694092	0.31
314.1129150	100.00
315.1297607	35.68
316.2470703	1.08
317.1364136	0.06
319.2432861	0.02
320.4987183	0.03
323.2527466	0.06
324.1383057	0.36
325.3621216	0.11
326.6002197	0.55
327.2986450	0.78
328.0787354	0.03
329.1577759	2.65
331.3109741	0.16
333.3096924	0.05
337.2426758	3.34
338.1923218	0.33
339.1763306	0.80
340.0205078	0.22
341.2595215	0.20
342.2236938	0.99
343.3481445	0.07
345.3042603	0.32
347.2301636	0.12
353.3082275	0.09
354.4018555	0.10
355.2531128	0.14
357.1422729	24.37
358.1961060	0.69
359.1078491	0.23
360.3916016	0.07
365.3079224	0.13
367.2193604	0.10
367.9019775	0.02
369.2590332	0.31
371.2813721	0.22
372.4081421	0.06
375.3295898	0.06
381.3070068	0.29
383.2321167	0.04
385.1146240	0.03
387.2267456	1.54
393.0520630	0.10
399.3367920	0.45
401.4064941	0.42
407.3861694	0.11
410.7145386	0.13
413.0625610	0.03
413.6693115	0.04
417.1564331	0.06
420.3521118	0.20
423.4202271	0.13
428.3546753	0.08
429.2104492	0.19
430.4010620	0.04
431.2766113	0.07
433.9769897	0.08
438.2527466	0.08
439.3156738	0.05
441.2797852	0.16
456.4234619	0.05
459.3049927	2.62
465.4612427	0.15
472.6428833	0.22
473.4696655	0.37
474.2836914	0.54
475.3640137	0.40
476.3179321	0.05
477.4650269	0.29
480.4818115	0.05
483.4231567	0.05
491.3828735	1.81
499.1872559	0.05
501.2546387	0.85
503.3930054	0.02
504.3299561	0.78
505.1151733	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.0934
Annotation	3,4',5,6-Tetrahydroxy-3',7-dimethoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
151.0184937	0.44
152.2742004	0.04
153.0611725	0.08
161.3637695	0.08
163.9509888	0.06
169.0821991	0.03
176.2518005	0.03
176.9203796	0.06
178.9368896	2.09
183.3145752	0.04
189.1745911	0.05
190.1178284	0.02
193.1390076	0.04
195.2431183	0.10
197.1441193	0.03
198.9200745	0.10
201.0922546	0.03
206.0209656	0.07
207.1338501	0.19
209.1016998	0.08
215.2820587	0.07
218.9489594	0.10
229.1403656	0.13
231.1509094	0.09
233.1443939	0.05
235.1377869	0.02
237.2414551	0.17
242.2012329	0.20
243.1297760	0.06
245.1388550	0.38
246.8855591	0.02
249.1599426	0.03
250.0857086	0.06
255.1396027	0.09
257.3314209	0.03
258.2958679	0.03
259.1528320	0.32
260.9722900	0.04
263.1033325	0.06
267.1841736	0.15
270.1508789	0.76
271.1898193	2.15
273.3438110	0.24
285.1295776	0.02
287.2081909	1.03
288.1836548	0.22
289.1019287	0.31
291.0992737	0.04
297.1948242	0.10
297.8673401	0.03
299.1038208	0.42
301.1072388	0.32
303.3117676	0.05
307.0646362	0.06
308.0486450	0.03
309.3270874	0.01
311.5671387	0.03
313.1720581	0.16
314.0911865	0.03
316.1168823	100.00
317.1372070	30.44
327.2143555	0.29
329.2039185	0.83
334.4229126	0.02
337.2709351	0.12
341.1811523	0.51
343.4758911	0.03
346.1182861	0.04
347.5051270	0.28
349.6676636	0.02
351.0838623	0.03
353.4173584	0.17
355.2546997	0.02
357.3860474	0.13
358.4815063	0.87
359.3098755	2.04
367.3625488	0.10
369.3358765	0.18
371.3517456	0.41
377.3686523	0.10
378.9033813	0.06
381.3526611	0.02
383.0889893	0.05
387.0853882	0.03
388.1857300	0.04
389.2351685	0.16
395.2633667	0.71
397.5710449	0.02
399.4075317	0.06
411.2359619	0.06
417.5635986	0.04
425.1465454	0.05
431.3012085	0.14
433.4519653	0.01
434.3942871	0.02
441.7520752	0.03
443.2674561	0.03
459.4727173	0.09
461.2381592	0.99
463.1156616	0.06
471.6872559	0.03
475.2326660	0.37
477.1390991	0.12
479.2098999	23.38
479.8495483	0.07
485.1171875	0.03
489.3981934	0.12
493.6065063	0.03
501.3632202	0.03
502.2894287	0.15
503.3384399	2.31
504.1234741	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1193
Annotation	Quinic acid
Peak:m/z	Relative Intensity
126.9585266	0.11
155.1111755	0.10
173.1248474	0.12
191.0253143	100.00
193.3463898	0.07
202.0819092	0.05
202.9303894	0.21
218.1797180	0.24
219.2093506	0.14
310.2414856	0.08
364.1857910	0.12
365.3439636	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1348
Annotation	Semperoside
Peak:m/z	Relative Intensity
110.5703583	0.03
113.0358276	0.10
135.3278503	0.05
142.9070282	0.09
151.2819977	0.16
153.0115051	14.81
159.0786743	0.04
161.1372681	0.16
167.2344818	0.03
173.1315765	0.07
179.1493073	0.48
192.5277100	0.07
195.1045227	0.17
197.0591278	100.00
209.1709900	0.07
211.3733215	0.09
221.3834229	0.06
238.0876160	0.09
239.1626892	0.75
251.1470947	0.04
269.0774231	0.29
272.2852783	0.20
275.3101807	0.05
287.2321472	0.08
296.1470032	0.06
299.0753479	0.73
301.1693726	0.07
315.1038818	0.76
341.2658081	0.73
344.3475037	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.056
Annotation	Quinic acid
Peak:m/z	Relative Intensity
57.1127968	0.11
58.8400002	2.92
60.8336906	1.67
67.0381775	0.34
68.9737473	0.30
70.9825134	7.92
72.9175110	0.55
80.9930344	1.56
82.9459076	0.80
84.9017639	93.96
86.9515686	17.30
93.0130768	55.10
96.1026611	0.41
99.0431976	6.06
100.9496002	0.27
108.9355621	22.31
109.8573608	0.18
110.9339600	35.39
112.9064941	0.95
115.0215149	4.00
126.9481659	100.00
128.9532623	2.63
130.9422607	0.52
137.0518341	3.29
143.1221771	1.90
144.9220123	0.53
147.0867310	1.03
153.0940094	3.53
155.0957794	13.08
171.0049896	24.75
173.0477600	77.98
191.1177826	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
98.9890976	0.73
100.9956207	7.11
106.5483246	0.39
111.7369308	0.20
112.9859924	21.08
114.7693024	0.63
118.9740295	18.93
125.0314102	2.25
130.9352417	8.01
143.0622711	17.50
148.9867554	5.05
158.8331604	0.20
160.9671936	21.87
170.0027161	0.40
179.0116577	100.00
183.0815735	0.11
190.9154968	0.47
214.7983704	0.19
219.0251770	0.24
221.0436401	0.70
225.0413513	0.22
228.2095642	0.17
235.3460693	0.21
241.9316711	0.14
255.4448242	0.43
256.9965210	0.37
258.9015808	0.60
277.1650391	0.13
278.3643188	0.38
279.2610168	0.45
280.0951843	2.33
281.0747681	0.39
290.9890137	0.32
295.1896973	3.12
296.0367432	0.27
297.0196533	1.08
310.5623169	0.90
323.3080444	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9863892	0.82
296.7731323	16.74
297.5174561	0.07
323.2354736	0.44
334.3504639	0.05
335.3093872	0.06
380.7556152	67.63
386.8125610	0.44
428.7564087	0.07
442.8794556	0.24
458.8474731	0.06
462.2495117	0.21
464.5097656	100.00
465.3439941	0.27
484.9714966	0.03
488.7687988	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.0828
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
107.9205399	0.08
111.1269455	0.22
128.8900146	0.35
129.9955292	0.03
134.0152283	0.70
143.0786743	0.20
154.9551697	0.03
170.9578552	0.09
173.0736389	0.52
178.2262268	0.08
188.1035461	0.29
191.0334778	100.00
201.1300201	0.03
203.0919037	0.12
209.2236176	0.32
215.1312866	0.21
218.8727417	0.09
233.3037720	0.06
234.9549561	0.04
248.2270508	0.43
249.1563721	0.04
255.0326233	0.04
256.0146484	0.04
257.1011353	0.09
258.9794617	0.08
263.0368652	0.46
264.8605042	0.04
267.0802612	2.53
268.2260742	0.07
278.8253784	0.04
286.9558716	0.12
292.1469727	0.03
293.0686646	0.21
299.2403564	0.20
301.1167297	0.04
305.2343140	0.14
308.6898804	0.05
321.1878052	0.16
323.1913147	0.15
325.0278320	0.07
336.0552368	0.24
337.1455994	0.09
341.1980896	1.14
347.0100708	1.30
364.9011230	14.78
365.6183777	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.0981
Annotation	Crotonoside
Peak:m/z	Relative Intensity
80.6718369	0.05
82.0907898	0.02
83.0130768	0.07
84.0932312	0.05
85.1465302	0.05
88.8036499	0.06
92.9014893	0.08
94.9635773	0.32
96.0022049	0.02
97.0412598	0.11
98.7735367	0.02
107.0087051	0.10
108.2377090	0.03
108.9592743	0.23
110.4312744	0.04
111.0354843	0.14
111.7001648	0.04
120.0836258	0.06
120.9997635	0.10
122.0401764	0.13
122.8975677	0.10
124.8836212	0.07
127.1355972	0.02
129.0788574	0.02
132.9981995	0.11
135.0951843	0.71
136.1930542	0.11
137.0243225	0.24
141.0534058	0.04
143.1944275	0.07
144.9991455	0.09
146.0410156	0.02
149.1824646	0.59
150.2183533	0.03
151.9642334	100.00
154.1346741	0.07
163.1016235	0.19
165.0751343	0.07
167.0185242	0.10
169.4795532	0.07
170.1120148	0.01
177.1145020	0.20
178.2989197	0.08
179.2061768	0.03
181.1310730	0.03
181.9898987	0.02
182.9893799	0.05
184.0991058	0.11
185.6616058	0.04
186.9671936	0.03
188.0262756	0.15
191.0171967	0.02
192.9928589	0.27
193.6435547	0.54
195.1524658	0.18
196.7397461	0.07
200.1376038	0.02
202.3871765	0.04
206.0315552	0.04
207.2668762	0.04
212.4351196	0.06
213.1328735	0.04
214.0354614	0.02
219.4751587	0.05
220.0925598	0.21
223.3994446	0.08
224.2342834	0.03
225.1591492	0.08
227.3834534	0.05
228.1377563	0.03
229.2237244	0.14
231.1815491	0.01
236.0296326	0.02
238.0804138	0.80
239.1320801	0.13
240.2355652	0.08
241.3561096	0.09
242.2106018	0.03
243.2296143	0.07
247.1862183	0.81
248.2513733	0.49
248.9229126	0.07
252.4526978	0.04
255.7637329	0.11
256.9216003	0.03
264.2760925	0.18
265.2984924	1.03
266.3447876	0.87
267.1152649	0.31
270.2029114	0.70
274.5329590	0.26
275.1795959	0.21
291.1459656	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.23
Annotation	9-OxoODE
Peak:m/z	Relative Intensity
94.74339294	0.08
96.88106537	0.13
98.91911316	0.19
101.1471786	0.10
104.9920807	0.08
106.8558578	0.04
108.9402847	0.04
116.4793472	0.08
121.0334549	0.07
123.0739288	0.32
125.1006317	0.22
127.041832	0.18
135.0000458	0.60
136.8913116	0.09
139.1081848	0.19
141.0104065	0.14
143.1902466	0.25
145.1374512	0.38
149.1277618	0.16
151.1276245	0.32
153.1255798	0.06
155.1277161	0.44
163.1538391	0.22
165.1711426	0.14
167.0425262	0.06
169.1265259	0.05
171.0198975	0.13
173.1408386	0.11
175.0445099	0.14
177.0936279	0.04
180.5138397	0.18
181.2525482	0.08
183.0861053	0.29
185.040863	0.05
189.2944641	0.06
191.1862183	0.14
193.1617889	0.28
199.1913757	0.05
200.6639099	0.05
201.3165283	0.19
206.8633423	0.27
209.2999268	0.05
211.0795898	0.24
217.2822876	0.30
219.0661316	0.22
221.1733704	0.35
231.1042175	0.24
232.9813843	0.20
233.7000122	0.09
235.2967529	0.85
237.2018738	1.96
238.3605347	0.82
239.3214722	0.16
241.2835083	1.09
249.1316223	0.24
250.6372681	0.60
251.4864197	0.23
253.2046204	0.62
259.1876221	0.97
267.266449	0.69
268.2946167	0.05
277.2163391	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1816
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9428101	1.48
119.0079041	2.60
125.1543732	0.15
131.0172424	1.07
142.9114990	2.67
146.1795959	0.25
161.0716858	1.57
179.0111847	13.50
194.8805695	0.13
211.9883728	0.10
281.2740173	0.21
289.1354065	0.17
293.2057190	0.25
301.6809387	0.16
315.5027771	0.13
319.1791077	0.13
331.1364746	100.00
331.7630005	0.60
359.2207947	0.23
362.2438049	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.0145
Annotation	Myricatin
Peak:m/z	Relative Intensity
169.9895935	0.02
187.9580383	0.13
208.3030243	0.03
214.8803711	0.24
225.1569214	0.02
229.0376587	0.14
237.3083191	0.03
243.0820007	0.25
255.3034821	0.06
257.0596008	0.03
258.2192993	0.05
262.7839050	0.02
271.0450439	0.15
281.2371826	0.08
283.3843384	0.03
284.1520996	0.03
287.2081299	0.02
297.1757812	0.01
298.1734009	0.10
306.1087646	0.02
315.1040039	3.59
315.8538208	0.16
325.3882446	0.03
327.0548096	2.02
333.1552734	0.57
341.1369629	0.13
342.8203125	0.02
355.2391968	0.12
357.0021973	0.36
359.0443726	100.00
360.0783081	3.11
361.1008911	1.08
401.2092285	0.03
416.9239502	0.20
422.1704102	0.14
429.3919678	0.02
445.2341309	0.08
446.8320312	0.20
447.5487671	0.02
461.1602783	0.20
462.4653320	0.04
463.1765747	0.27
503.2268677	0.02
504.4552612	0.23
507.0910034	5.50
533.1390991	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0883
Annotation	Castamollissin
Peak:m/z	Relative Intensity
150.9917603	0.61
152.0013428	0.02
153.0264282	0.07
154.8202667	0.06
157.3420410	0.01
159.2979126	0.02
161.4291077	0.01
163.0151062	0.04
168.9955597	0.05
176.9887390	0.05
179.0193024	1.38
189.2135925	0.10
190.9272156	0.02
193.2221985	0.07
197.0426331	0.05
200.9110870	0.03
206.0968018	0.05
207.2467804	0.09
208.9337158	0.14
219.2526245	0.09
220.3159027	0.08
221.0703583	0.23
228.4458160	0.04
232.1688843	0.05
235.1803589	0.09
239.3274384	0.02
241.2112427	0.04
242.0977783	0.06
243.2339478	0.08
244.9397278	0.03
247.3116760	0.04
249.1494141	0.03
251.1506958	0.08
255.3948059	0.04
256.1965942	0.03
257.2006836	0.06
258.5842896	0.03
259.1946716	0.03
261.3754578	0.07
263.1808167	0.08
267.3981934	0.02
269.1425476	0.26
270.2023926	0.04
271.1923218	0.18
273.4654846	0.03
274.1872559	0.02
275.1795959	0.06
277.1249390	0.07
279.1852722	0.08
281.2191772	0.02
283.2890320	0.14
285.1523743	0.22
285.7608032	0.04
287.1347046	0.12
288.1562805	0.09
289.1318359	0.04
293.3233948	0.05
295.2233887	0.01
296.6066284	0.03
297.2860107	0.11
300.1714172	1.40
301.2048950	4.76
303.1626587	0.45
307.2819824	0.16
308.4738770	0.07
311.4390564	0.01
313.3492126	0.13
314.0270691	0.03
315.2297668	0.83
316.1521606	0.40
317.3712463	0.02
318.3064575	0.01
319.2462769	0.13
323.2919312	0.03
325.5249023	0.02
327.2387695	0.28
328.2884216	0.11
330.1237183	100.00
331.2147827	47.95
337.2267456	0.39
339.2574158	0.03
339.9967957	0.02
341.1855774	0.45
343.2137451	0.55
344.4011536	0.04
353.0489197	0.06
355.2814941	0.25
358.1929932	0.02
359.2015381	0.04
367.1536560	0.04
369.3661194	0.04
371.2022400	0.03
373.2578125	2.58
375.2747803	0.02
379.2292175	0.05
385.1772156	0.04
387.1894226	0.02
388.4129333	0.02
389.3818665	0.01
394.9383850	0.08
403.1221008	0.26
404.2046814	0.01
409.3995361	0.01
413.4058838	0.04
415.2373047	0.02
416.8883057	0.08
417.5162048	0.01
419.2600098	0.11
421.2287598	0.08
427.1034241	0.06
431.3227844	1.02
432.2330017	0.07
435.1475525	0.06
445.1974487	0.55
448.1688232	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	733.3065
Annotation	Taccalonolide A
Peak:m/z	Relative Intensity
209.4400940	0.01
255.4081116	0.03
270.4100647	0.01
274.8584595	0.01
289.3288879	0.02
293.2284546	0.01
295.4932251	0.02
296.8356934	0.08
313.2239990	100.00
314.2043457	6.85
315.4494629	0.01
326.3075867	0.01
327.2551270	0.12
328.3887329	0.02
329.4509277	0.03
330.3098755	0.02
334.7647095	0.02
343.3307495	0.23
355.2352905	0.03
391.3523560	0.02
392.0756226	0.02
433.4201660	0.08
449.5628052	0.01
491.5244141	0.01
493.6671753	0.01
494.9434814	0.04
505.2037964	0.01
523.3252563	0.29
524.2180176	0.04
537.3770142	0.25
538.9336548	0.05
541.3894653	0.03
542.3414917	0.04
567.2250366	0.04
572.0020142	0.07
601.0917358	0.05
607.4558105	0.06
614.4161377	0.01
623.5498047	0.01
642.3132324	0.06
646.6466675	0.02
661.5612793	0.04
669.8025513	0.04
689.1686401	0.03
689.9154053	0.01
696.4497681	0.03
701.3622437	0.03
703.3685913	0.14
704.0424194	0.01
713.3539429	0.09
715.4950562	0.26
716.4745483	0.03
718.2913818	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
101.0155182	9.21
104.5519257	0.17
106.8906097	0.28
113.0024261	17.51
115.0245056	0.31
118.9778519	15.06
125.0442734	2.07
131.0099182	6.59
133.2497253	0.18
143.0392761	18.89
148.9632568	3.32
154.8102112	0.06
161.0082397	14.95
173.1802979	0.12
177.2600555	0.11
178.9683838	100.00
183.1005249	0.06
190.7938843	0.19
220.9578552	1.38
233.0129395	0.10
237.1333618	0.82
261.3183289	0.06
281.0798950	0.93
323.3006592	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	249.0803
Annotation	2-(5'-methylthio)pentylmalic acid
Peak:m/z	Relative Intensity
79.8570557	14.10
93.0473785	0.13
96.9087830	100.00
98.8718567	0.24
147.1002197	0.32
169.3861389	0.28
171.4496918	0.11
177.2251434	0.61
187.2255249	0.60
203.1647339	1.52
204.2895813	0.17
205.0701141	0.38
220.2085419	0.16
221.3264618	0.80
230.2049103	0.54
231.2796173	1.76
249.3622894	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.24
Annotation	Unknow
Peak:m/z	Relative Intensity
273.9425049	0.05
279.4124146	0.03
287.9419250	0.04
301.4181824	0.06
303.2088928	0.20
343.2696533	0.22
374.3955078	0.14
432.3015747	0.08
451.4857178	0.06
465.0187988	0.06
468.3387451	0.09
469.2229614	0.04
479.1495361	0.04
495.1686401	0.05
535.0982056	0.05
536.6669922	0.23
578.8499756	0.38
589.6491699	0.07
602.1317749	0.18
603.2270508	1.75
611.9420166	0.18
619.3873901	0.69
621.2004395	100.00
621.8428345	0.29
647.1285400	0.06
650.3196411	0.13
651.2637329	0.09
660.5003662	0.12
761.9631958	0.13
765.4130249	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1429
Annotation	(+)-Abscisic Acid
Peak:m/z	Relative Intensity
74.96382141	0.29
91.03918457	0.32
94.58604431	0.92
101.1134186	1.16
106.967453	0.34
110.7746887	0.87
112.7673492	0.34
117.0296021	0.41
118.9212036	0.25
120.8609924	0.21
122.3145142	0.23
122.941391	0.56
125.0879517	0.89
127.0474701	1.55
135.0493774	2.99
136.9033661	1.78
138.9255371	1.43
144.9214783	2.24
147.1508331	1.54
148.0538635	0.32
149.0401459	0.73
149.9542694	0.79
151.095932	2.57
155.0614319	1.03
156.9363556	1.30
159.0146942	2.83
163.1060333	2.98
163.9388733	0.62
165.1847076	1.91
168.4678497	1.25
169.2532654	1.77
170.6942596	1.71
173.0231171	0.54
175.1582184	1.09
176.0370483	0.30
177.1417542	1.92
181.1474457	2.18
182.8264618	0.61
187.1774902	1.71
189.0156708	3.65
190.7902374	1.75
192.2310944	0.68
193.0498505	2.69
201.0422821	2.51
203.0836639	1.73
205.233139	9.99
206.0368347	0.95
207.1356354	2.82
209.0862274	13.88
215.200592	0.62
216.8483582	0.78
219.1863098	7.40
221.1894226	3.95
223.0394897	0.56
228.1614838	0.25
229.159668	7.32
232.926651	0.96
234.9615479	0.91
237.100296	1.63
247.1266937	100.00
251.3091888	0.81
256.1143188	0.30
273.434021	1.54
274.386261	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1404
Annotation	2''-O-Feruloylorientin
Peak:m/z	Relative Intensity
177.3059235	0.02
179.2004242	0.07
186.9002991	0.06
188.9666901	0.04
191.4869537	0.02
194.4772797	0.06
200.9660950	0.02
203.1199646	0.10
204.8537903	0.02
209.1220398	0.04
211.1806335	0.07
213.4102478	0.04
214.1165161	0.02
216.8850098	0.11
220.1877136	0.05
227.1934204	0.08
228.0685120	0.19
229.0413208	0.11
231.1791992	0.02
235.3293152	0.07
239.1564484	0.06
240.2368927	0.10
241.2799683	0.07
242.0534363	0.06
243.1393585	0.37
244.0847015	0.30
245.2114410	0.04
247.4081726	0.02
254.1210175	0.24
255.1434631	0.89
256.1551514	0.14
256.9936829	0.07
259.2089844	0.06
265.1740112	0.05
269.9407959	0.08
271.1275635	1.98
272.1564331	1.44
273.1791992	0.03
282.2915649	0.07
282.9719849	0.03
283.9869995	0.23
285.2175293	0.20
286.2483826	0.04
287.1762085	0.71
288.4033813	0.05
289.2677612	0.12
290.0892639	0.02
297.0787964	0.04
300.0845032	17.89
301.1302795	3.21
303.0966797	0.03
307.2319946	4.22
308.2599487	0.59
313.1709595	0.44
315.1077271	100.00
316.1832275	14.87
323.2146606	0.04
324.1743164	0.04
328.3677673	0.06
329.2301025	0.12
332.9060059	0.04
337.2930298	0.06
339.2290649	0.04
340.2550659	0.01
343.1588745	0.07
357.1654663	0.51
358.0656128	0.51
368.9561157	0.07
371.5152588	0.02
372.4912109	0.03
383.1026001	0.06
385.2271118	0.06
387.5918579	0.03
388.4362183	0.08
389.0950317	0.04
397.2337036	0.05
399.3198242	0.07
400.5665894	0.03
404.2554932	0.02
405.4782104	0.03
411.4548340	0.05
413.4970703	0.04
415.0914917	0.10
423.0368042	0.05
431.7855835	0.02
440.3148193	0.03
443.3710327	0.07
446.2154541	0.03
459.3184204	0.42
460.1939087	0.12
461.4146729	0.27
463.0151978	0.06
473.4447021	0.02
477.2261963	5.38
478.4331665	1.17
496.3797607	0.02
497.3554077	0.07
502.4559937	0.02
503.3733521	0.04
514.5656738	0.02
519.8933105	0.08
521.1846924	0.06
527.5646973	0.08
531.2894897	0.03
533.5432129	0.04
537.2391968	0.02
547.8081665	0.11
551.6577759	0.05
552.4118652	0.05
560.1742554	0.02
563.1887207	0.06
564.4141235	0.06
577.2708740	0.33
578.3168945	0.09
579.0021362	0.03
585.3403931	0.10
587.3695679	0.10
588.5809937	0.07
591.1348267	0.09
593.2289429	0.09
594.3150024	0.04
595.1168823	0.04
596.4884644	0.03
605.3765259	0.37
608.1687012	0.07
609.1448975	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	482.2585
Annotation	Unknow
Peak:m/z	Relative Intensity
134.9365540	0.86
145.1398010	0.80
153.0662079	100.00
162.8474121	0.15
165.3233948	0.56
170.6560059	21.97
171.3368225	0.11
180.9593353	0.32
188.9725800	0.27
198.9428558	0.59
204.7299194	0.25
212.8214417	0.25
216.3387909	0.20
217.0296326	0.93
223.0898590	0.43
238.9727783	0.23
240.9162140	1.46
257.1687927	0.42
259.0738220	15.40
266.9953613	1.11
276.1665955	0.91
276.9887390	3.37
279.1073914	0.60
285.2607117	0.91
294.0286865	0.67
295.0057983	24.22
302.0269775	4.21
302.8851318	30.64
310.0037537	0.11
312.7476196	2.14
313.8026123	0.23
317.1796570	0.13
320.0776367	0.51
329.9623718	0.26
332.0817871	1.82
332.7753296	13.40
333.5088806	0.07
344.8290405	0.49
362.2611694	0.42
363.0566406	0.34
379.2630920	1.02
411.1486206	0.33
428.1886597	0.46
428.8387146	3.33
431.4792175	0.41
439.1850891	0.48
446.5140381	0.25
447.4604187	0.53
462.9180298	0.25
464.8882751	80.04
465.5900574	0.23
466.5186157	1.03
481.6830750	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	325.0929
Annotation	6-O-p-Coumaroyl-D-glucose
Peak:m/z	Relative Intensity
117.1401215	0.04
119.0155258	6.39
120.8001251	0.05
123.1847992	0.03
145.1963806	0.10
147.0176086	0.03
149.1122742	0.03
161.3104553	0.04
162.9776764	100.00
164.2584076	0.16
165.0166016	0.29
167.0258789	0.06
177.2213135	0.03
182.9162598	0.07
187.0658112	0.29
191.1075745	0.41
192.1714478	2.75
193.1513367	1.89
201.2734680	0.08
202.9984131	0.01
205.0065613	0.15
207.1119995	0.61
219.1991272	0.17
233.1989746	0.04
235.1674194	0.18
247.1271362	0.12
253.1630859	0.10
265.2362061	0.50
281.1654053	0.03
283.1855469	0.04
289.3567200	0.09
297.2646179	0.10
307.1841736	0.29
310.2074585	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1692
Annotation	(1S,2R)-O-Methylnyasicoside
Peak:m/z	Relative Intensity
158.9008789	0.16
165.7351379	0.43
168.8811798	0.09
177.1563721	0.62
183.0497894	0.21
231.1839142	0.42
233.4186096	0.24
246.1873474	0.25
255.1178894	0.22
263.1719055	0.08
263.8185730	0.41
270.3809204	0.15
272.2810059	0.51
277.1423645	0.62
285.2102661	0.45
288.9458313	0.92
297.3155823	0.23
324.5737000	0.09
326.1309204	0.12
331.1732788	100.00
332.1512451	78.64
333.2353516	0.31
338.9802551	0.24
340.3879089	0.27
351.2839966	0.52
353.3115540	0.23
371.6558533	0.09
374.0906982	0.11
382.3787231	0.36
385.5903015	0.25
410.8328857	0.23
435.1484680	0.17
436.1952820	0.14
448.4509277	0.28
450.4360046	0.08
457.4471436	0.37
467.3941040	0.43
475.1781921	0.90
476.2459106	0.99
485.1851196	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2995
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
93.0558701	0.16
94.8849106	0.04
96.9070129	0.09
105.1013412	0.04
108.9416962	0.15
110.9282990	0.04
112.8294144	0.10
121.0719147	0.34
123.0952835	0.43
125.1685181	0.07
135.1113739	0.05
136.8321533	0.06
138.1388855	0.05
149.1391602	0.26
151.0827637	0.18
165.0286102	0.19
171.1790771	0.06
177.2600555	0.05
181.2589111	0.07
183.2156677	0.02
190.8161011	0.07
191.4901733	0.07
192.2189331	0.15
197.1246796	0.03
203.2867432	0.04
211.0876770	0.56
220.8369141	0.03
225.3251343	0.22
228.2397156	0.10
235.1396790	0.36
239.2630920	0.04
240.5448303	0.03
241.2603760	0.06
245.4048157	0.02
247.3078308	0.45
252.4462280	1.37
253.3016663	0.34
256.3789673	0.36
262.2618408	0.03
264.3331604	1.40
265.3685608	3.32
270.3724060	1.28
282.3392334	44.40
283.1881409	0.78
300.2993774	100.00
301.2692871	0.10
319.2544556	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1031
Annotation	Cinchonain Ic
Peak:m/z	Relative Intensity
142.8141479	0.05
155.0792084	0.08
160.9756165	0.05
162.1236877	0.10
177.0588684	0.31
189.1287842	0.40
191.0081482	0.03
196.1087799	0.08
202.8780060	0.03
206.7942352	0.07
217.1597900	1.02
219.1544037	0.34
225.2460327	0.03
229.0998230	0.14
231.2334290	0.17
235.2437134	0.07
243.2638245	0.05
247.1277466	0.12
266.2347412	0.03
270.9867859	0.04
281.2129822	0.04
282.6472168	0.08
287.2689514	0.06
289.1925049	1.10
297.3075562	0.17
299.1662598	1.11
301.1663208	0.68
302.2891235	0.05
313.3345337	0.12
315.3477173	0.16
316.3787842	0.44
317.2591248	0.30
318.4366150	0.64
319.1474915	0.06
323.2464905	0.24
327.1022949	0.14
341.2099609	100.00
342.1016235	0.08
352.9725342	0.06
354.0856628	0.03
361.3044739	0.18
363.6404419	0.04
377.1694641	0.04
379.3121948	0.03
380.1456604	0.04
387.4805603	0.24
391.4448547	0.28
404.1161804	0.07
405.4238586	0.14
407.3598633	0.16
414.4791870	0.02
423.2182312	0.07
429.3890076	0.03
431.2211914	0.05
432.5551147	0.03
433.1960754	0.16
436.3921814	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.0939
Annotation	Unknow
Peak:m/z	Relative Intensity
164.9907837	0.54
169.0196228	0.56
182.9953918	0.15
191.1223755	0.08
214.3292694	0.08
218.3061218	0.14
228.3548431	0.19
229.5218048	0.37
230.2634125	0.70
242.7678986	0.16
248.1504211	0.09
256.1817322	0.45
257.1375732	1.02
258.1987305	0.39
271.1979675	3.88
272.1296387	4.43
273.1929932	1.50
274.1510925	0.24
275.1738892	0.09
283.2070923	0.34
284.2607117	1.34
285.1552429	0.11
289.2665405	0.23
297.1286621	0.11
298.1377869	0.22
299.6741638	0.27
300.2908325	1.09
301.1888733	1.44
302.2775574	0.55
308.2369690	0.14
315.1578369	45.71
316.1525879	100.00
317.1351929	22.64
320.3858032	0.14
328.0316162	0.05
329.3521729	0.11
330.0311584	0.12
331.1623230	0.32
333.1781006	0.07
335.0654297	5.42
337.3227539	0.27
338.4568481	0.19
343.3339844	0.29
347.2712402	0.12
349.3109741	0.08
355.3225098	0.42
356.1212158	0.44
357.2557068	0.30
365.0496521	0.30
369.3320618	8.90
370.2156372	21.18
371.1987305	4.47
377.3057556	0.41
378.9312134	0.07
407.0412292	0.98
417.7812805	0.06
424.5174866	0.20
428.3603821	0.44
429.1585083	0.19
433.4365540	0.17
434.3535461	0.14
437.4202576	0.25
451.2165222	5.52
452.4425354	0.64
453.2310181	0.74
461.5774841	0.15
479.2200317	0.76
497.1621399	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.0806
Annotation	5,6,4'-Trihydroxy-7,3'-dimethoxyIsoflavone
Peak:m/z	Relative Intensity
111.0628357	0.05
122.0695343	0.28
123.2596512	0.07
126.1833191	0.25
127.0665894	0.10
137.9841003	0.26
138.9408875	1.08
140.1393890	0.14
148.9000854	1.11
149.9877930	2.61
150.9756470	1.52
151.9685059	0.13
152.9112396	0.14
158.9310303	0.06
162.0280762	0.36
163.1283875	0.11
164.9884644	0.28
166.0641479	1.19
167.1875916	0.20
177.2201843	1.13
178.0809937	2.65
178.9884186	10.36
179.9834595	0.62
181.1759033	0.17
184.0451050	0.07
184.7717590	0.08
189.9955597	0.95
191.1009521	0.28
192.2015381	0.10
193.9714966	0.43
195.1137238	0.25
200.8599548	0.32
204.0406494	0.08
205.7208710	0.08
212.1200256	0.15
213.4663086	0.08
215.1393433	1.30
219.2465210	0.36
226.0245972	0.18
228.1804810	0.29
229.1938477	0.38
231.1661072	0.39
241.0596008	0.14
242.1712036	10.45
243.1766052	1.92
244.2249146	0.15
245.1396179	0.34
246.1081848	0.34
247.1847229	0.12
248.2472534	0.09
252.6244507	0.72
253.2790222	0.66
254.1875610	0.20
255.0500488	0.08
256.4546509	0.44
257.2678833	0.86
258.1597900	0.15
259.0233765	0.37
260.1769409	1.09
269.1165161	4.12
270.1113586	44.68
271.2061157	7.58
272.0121765	0.69
273.0849609	0.40
274.4132690	0.08
275.0545349	0.10
280.1528015	0.42
281.1829834	0.94
284.4273682	0.52
285.2700195	0.36
286.2476807	2.44
287.1433411	59.16
288.1433716	12.08
288.7480774	0.06
289.3490906	0.26
298.0316162	33.39
299.1070251	85.78
300.1252441	6.18
301.0940247	1.47
302.2169189	0.45
303.2722168	0.59
313.1304321	0.09
315.1428223	83.14
316.1424561	100.00
317.1921387	6.42
331.1595459	27.78
332.1186829	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.3416
Annotation	Unknow
Peak:m/z	Relative Intensity
240.0746765	0.09
246.1763916	0.17
250.1328735	0.11
258.2484741	0.05
268.1791992	0.05
271.4528809	0.17
279.1696167	0.08
285.0753479	0.13
287.1064758	0.21
299.2295532	0.13
302.9595947	0.15
307.3766174	0.08
313.2287292	0.41
317.4634094	0.04
331.3253174	0.07
337.1645813	0.15
341.1380005	0.04
345.2199707	0.61
367.2934570	0.69
381.3295898	0.10
399.0761108	1.11
421.1104736	0.43
434.3349609	0.14
435.3930664	0.08
437.3186035	0.10
438.4957886	0.65
449.1026611	0.20
451.3984985	0.08
453.4634399	0.22
459.3154907	0.12
460.1218872	0.27
463.2399292	0.04
464.2961426	0.45
465.1842041	0.29
467.1178589	1.14
473.1119995	0.10
475.4201050	0.74
478.3834839	0.93
480.1715088	0.09
481.2029419	1.06
492.8175659	0.27
497.2223511	0.19
498.7305298	0.10
501.2222900	0.05
507.3025513	0.91
508.3683472	0.11
509.3109741	0.58
510.3670654	1.25
511.3105469	0.42
515.2944336	0.06
519.1669922	0.07
557.7643433	0.21
559.4393921	0.18
570.2316895	0.70
582.3092651	0.21
583.4566040	0.91
591.2286987	0.15
596.3380737	0.17
599.3936157	0.66
601.3527832	29.74
602.0037231	0.06
604.3612671	0.29
606.3106689	0.24
611.4461060	0.06
613.5725098	0.25
614.9548950	0.53
617.2515259	0.16
618.7299805	0.08
622.6858521	0.12
625.4931641	0.26
626.4013672	0.05
627.4371948	0.91
628.6555176	0.48
632.3092651	1.03
633.2775269	14.22
640.3660278	3.10
641.2360229	0.11
642.3121948	0.11
643.3046875	0.34
645.3837280	0.13
659.3089600	0.33
662.2955933	0.25
663.2131958	0.50
665.2344360	0.11
672.4057007	9.08
673.2955322	1.84
675.2825928	0.05
681.7310181	0.05
683.3991089	0.15
695.5679321	0.04
701.5874634	0.26
711.2933960	0.25
712.9976196	0.38
719.6077881	0.20
727.7756958	0.12
733.3845825	0.18
745.4586182	2.59
750.7004395	0.09
759.3606567	0.25
762.8886719	14.70
763.5200806	100.00
766.7340698	0.21
776.3025513	1.44
777.2435303	1.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	749.3015
Annotation	Unknow
Peak:m/z	Relative Intensity
210.2000885	0.16
211.0845337	0.20
225.2734985	0.23
253.3914185	0.04
254.2686157	0.03
275.1290283	0.04
301.1088257	0.02
310.3318481	0.06
311.2585449	0.24
313.2742920	0.50
314.0680542	0.02
328.1749268	7.38
329.3056030	2.92
330.3955688	0.26
331.2711182	0.05
343.1961060	100.00
344.3383179	10.90
345.0994263	0.09
359.3348389	0.17
361.4929504	0.04
363.2854004	0.05
365.1134644	0.02
381.5579834	0.03
389.1861572	0.04
398.3602295	0.05
405.2518921	0.03
407.3898926	0.04
433.4277344	0.07
437.3029175	0.18
441.1994629	0.04
447.4688721	0.03
461.2158813	0.09
465.1064453	0.05
466.6168213	0.09
475.5807495	0.04
477.0747070	0.02
483.4602661	0.03
505.2164307	0.07
507.0593262	0.14
509.2493286	0.07
513.0836182	0.05
515.1673584	0.03
519.2720337	0.05
523.4808350	0.15
533.0698853	0.20
535.4726562	0.38
541.1690063	0.09
549.3113403	0.02
553.3866577	0.47
554.5232544	0.14
556.8495483	0.06
557.5764160	0.09
560.0558472	0.03
567.3939819	0.06
569.2714233	0.21
570.0263062	0.10
574.0989380	0.04
587.2578735	0.05
588.5968018	0.14
595.4647827	0.04
599.4624634	0.06
600.1373291	0.06
603.5039673	0.03
609.0222778	0.07
613.1658325	0.11
614.6483765	0.05
617.5952759	0.12
621.8110352	0.03
639.3052979	0.04
658.4540405	0.08
659.5491333	0.02
660.2065430	0.03
663.4783936	0.13
665.3565063	0.07
683.5217896	0.17
686.7817383	0.02
688.8850708	0.06
701.3892822	0.74
702.2438354	0.19
703.2223511	0.05
705.3959961	0.12
706.2106934	0.08
713.4790649	0.12
718.7996216	0.15
719.4418335	0.07
723.4713135	0.06
731.2280884	0.47
732.3964844	0.44
734.0484009	0.03
736.4900513	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.2912
Annotation	Segetalin H
Peak:m/z	Relative Intensity
195.1933899	0.07
205.0112305	0.03
209.3014679	0.05
247.1341400	0.07
271.1771240	0.03
278.7982178	0.14
286.0535583	0.08
286.9919434	0.11
288.0994263	0.03
301.2835693	1.01
302.2481079	1.34
303.1252441	0.40
305.1918335	0.02
308.4419556	0.04
316.2632751	0.04
317.2593384	0.11
337.0331421	0.07
339.4366455	0.04
350.4869385	0.04
351.3176270	0.04
355.3712769	0.09
356.3186035	0.07
393.2930908	0.07
404.3765869	1.43
405.4635620	0.34
407.3933716	0.03
413.3711548	0.05
420.9881592	0.20
421.6987915	0.06
426.2014160	0.04
429.2843018	0.15
431.1552124	0.44
432.2686157	5.66
434.4052734	0.18
436.2267456	0.10
437.4406738	0.05
440.9745483	0.12
447.2630615	0.13
449.2424927	100.00
449.8556519	0.72
455.1998901	0.10
457.5346069	0.11
458.5003052	0.18
459.1104126	0.02
461.1387329	0.40
463.4018555	0.28
464.4916992	0.43
465.3817139	0.11
471.2455444	0.20
479.2609253	0.33
491.3256836	0.23
494.4351807	0.08
511.5226440	0.03
521.5509644	0.06
527.4408569	0.45
530.4564819	0.25
539.6141968	0.02
549.0444946	0.07
557.2093506	0.04
562.7893677	0.12
564.0816650	0.06
565.3587036	0.06
568.1660156	0.04
569.0935669	0.07
573.1936646	0.07
575.6190796	0.26
579.9874878	0.12
583.6163330	0.28
591.1260376	0.03
591.8845825	0.05
593.2292480	1.78
593.8643188	0.05
596.6127930	0.02
602.5177612	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
119.9568787	100.00
130.8717499	0.29
137.9140778	0.03
147.9042511	0.52
149.0070648	4.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	603.0839
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0185547	0.09
216.9807281	0.08
235.1543884	0.11
239.0939941	0.07
243.1014709	0.17
245.1054688	2.72
256.9955750	0.32
259.3315430	0.13
274.9496460	2.92
277.1425781	0.52
283.1262817	0.25
285.0247498	0.17
289.0075073	2.76
293.0218506	0.09
302.9354858	0.41
307.1463013	0.95
309.0618896	0.69
319.0374146	1.82
320.2448730	0.08
321.1625671	0.37
322.3107910	0.73
332.4122314	0.06
334.8743286	0.22
336.9509888	1.11
338.8084717	0.48
341.2231445	0.07
346.9604492	0.27
347.9235229	0.22
349.0882568	11.06
364.0681152	1.22
365.1492920	10.25
366.7843018	0.20
368.7514648	0.16
373.4318237	0.33
379.2179565	0.95
380.9962769	0.48
391.0039062	2.47
393.1369629	0.50
397.1669312	0.24
405.4950562	0.55
406.9932251	0.39
409.0339966	100.00
409.9584961	0.64
411.0343628	0.08
420.4345703	0.08
423.1212769	4.21
428.4744873	0.38
439.5487671	0.60
441.1319580	31.40
451.5020142	0.14
453.0164795	0.08
455.1329956	0.36
483.0902100	2.22
495.1881714	0.20
504.7212524	0.32
506.1356201	0.57
506.8816528	0.34
508.1436157	0.14
509.3140259	0.30
511.0658569	1.90
512.7081909	0.41
513.3423462	1.07
514.1013184	0.08
525.0821533	0.75
526.9205933	0.57
527.6150513	0.20
539.7999878	0.19
543.1570435	9.85
544.1480103	0.41
548.5628052	0.06
549.5249634	0.19
553.1109009	2.81
558.1203003	1.15
558.8632202	1.69
559.5626221	0.18
567.1394653	0.52
571.0551758	15.57
571.6710815	0.09
583.8945923	0.13
585.0697632	7.67
585.7684937	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.11
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.9469070	0.08
110.9566193	0.48
113.0267639	0.56
128.7349243	0.06
130.9723206	0.06
135.0708618	0.28
138.2000427	0.72
143.3044586	0.07
147.1708679	0.08
148.9850006	0.98
150.9411316	0.13
152.0878296	0.25
153.0935364	22.21
159.0401001	0.77
161.0499878	5.54
162.8519287	0.44
164.0129700	2.84
165.1934814	0.08
175.0886536	0.09
177.2276001	0.22
178.9558716	2.71
180.9231873	0.70
182.9487000	0.15
190.0935059	3.16
191.2017975	0.58
192.0545959	0.11
193.0869446	0.28
195.2199402	0.12
203.0545044	0.44
205.0581665	56.41
206.1054688	0.24
207.0856018	0.15
208.3699036	1.26
218.3309326	0.31
219.3229980	0.53
221.1891937	1.45
223.0572815	100.00
232.0066528	1.26
233.1776123	1.06
237.2137146	0.34
247.0480347	50.01
247.7544861	0.06
249.0627136	0.13
251.3146667	0.17
259.3853455	0.11
262.5137024	0.17
265.1309814	7.49
275.4068298	0.08
277.0626831	1.41
279.1484070	0.31
289.2120361	1.57
295.1369934	3.61
297.0299988	0.47
305.2440186	0.31
307.4029541	0.17
322.2503662	0.18
325.2512512	4.90
339.2839661	0.09
341.2120056	2.25
343.2375488	0.38
364.4135437	0.09
365.2784119	0.27
367.0964050	1.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1504
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9778595	0.24
164.9015350	0.40
174.0542755	0.10
191.0599976	0.27
197.2010345	0.22
200.9594116	0.98
203.2083130	0.22
215.1007690	0.24
217.2406006	0.31
229.1069336	0.54
231.3634491	0.23
233.3386536	0.17
243.0562744	0.69
245.1146698	0.78
247.1222534	10.99
253.2835388	0.21
255.4211731	0.12
256.8088989	0.09
259.1202393	1.73
261.1742859	0.31
265.1914978	0.10
268.7046509	0.22
271.1661987	7.21
273.0748291	5.07
275.0827332	3.73
276.1040649	0.09
281.2214355	0.07
283.1562195	1.74
285.1721191	1.04
287.1121216	3.64
288.1101074	0.13
289.1283569	12.74
291.1101685	23.39
295.1522217	0.14
298.0118103	0.07
299.2467651	0.75
300.5471802	0.28
301.2088623	11.10
303.2275085	4.22
311.4374695	0.23
313.2084656	2.85
315.2050781	0.32
316.1553345	0.36
323.3861694	0.17
324.9734497	0.91
331.2482300	100.00
332.2752686	0.25
333.2896729	3.23
339.4060059	0.34
343.2707520	0.06
347.3738403	0.09
348.1218262	0.30
349.9000854	0.59
353.2624512	0.27
357.1538086	0.19
367.1632690	0.06
369.1911011	0.15
371.3618164	0.24
375.2623901	0.12
380.4970703	0.05
386.9789429	0.06
388.1502686	0.26
393.0367432	0.12
395.3365479	0.06
399.3384399	0.16
405.2393188	0.34
407.2713623	0.04
409.1432495	54.44
410.6873169	2.45
411.3607788	11.27
415.1801758	0.09
416.0520020	0.17
417.2512817	0.76
419.2674561	0.17
421.1578979	2.79
423.1303711	1.89
427.0987549	49.57
427.7546997	0.07
435.3071899	16.51
439.2138672	4.91
447.2325439	0.56
451.1475830	1.00
453.1691284	30.15
453.8496094	0.10
456.2197876	0.05
463.5652466	0.35
493.1853638	1.18
498.4466553	0.52
512.6614380	0.31
514.8461304	0.07
533.1040039	0.44
535.3031006	6.23
536.7366333	0.45
537.3780518	0.26
543.3347778	0.89
544.3458862	0.29
549.1752930	0.19
553.7170410	0.16
560.6656494	3.53
561.2874756	26.63
562.3930054	0.59
570.3338013	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.0724
Annotation	Castamollissin
Peak:m/z	Relative Intensity
151.0811920	0.37
152.1174316	0.10
153.1117554	0.11
161.2957153	0.02
162.9859619	0.01
164.1128540	0.01
169.0759888	0.12
170.0109406	0.02
175.2873230	0.01
176.7698364	0.04
179.0049438	1.75
180.1835022	0.25
189.2279663	0.05
190.1439209	0.04
193.1835938	0.03
196.9345551	0.12
198.1186523	0.03
202.9938660	0.03
204.9388123	0.01
206.3154602	0.07
207.1374817	0.10
209.0347290	0.04
217.1880951	0.03
218.9696960	0.01
221.0945129	0.05
222.0939026	0.03
223.1252136	0.04
228.1546478	0.04
229.2824860	0.05
232.0814514	0.03
233.1069794	0.11
233.9745026	0.07
235.7291260	0.02
240.2948608	0.03
241.2719116	0.01
243.2125244	0.02
244.2280273	0.07
245.1175232	0.11
245.7983398	0.02
249.1773682	0.04
252.2198181	0.01
253.1107788	0.04
255.3104248	0.12
257.1137085	0.04
258.9442139	0.04
260.1011353	0.04
261.9281311	0.10
262.9469299	0.11
264.1508179	0.03
270.1354980	0.01
271.1724548	0.25
272.1539001	0.06
273.1340942	0.04
274.1507874	0.02
283.3771362	0.02
284.1311035	0.01
285.1712036	0.09
286.4554443	0.03
287.1076660	0.27
288.0384827	0.17
289.1826172	0.29
290.4673767	0.02
297.2868958	0.24
298.3244629	0.09
299.1117554	0.08
300.2781372	0.01
305.1853943	0.05
311.3085632	0.01
313.0690613	0.17
314.2586670	0.09
316.1142578	100.00
317.1349487	52.42
318.2029419	7.17
319.2978210	0.06
323.1844482	0.57
324.2046204	0.04
325.1915588	0.02
327.0627747	0.01
328.4140625	0.07
329.2534180	0.43
330.2326050	0.36
331.2020874	0.11
339.1992188	0.01
340.3617554	0.08
341.1625671	0.35
342.2247925	0.14
345.3169556	0.06
354.1306152	0.02
359.2463074	1.73
360.2475586	0.50
369.4822998	0.03
371.0977783	0.19
375.3481445	0.07
381.1141052	0.02
382.2523499	0.08
387.3937683	0.06
389.1946716	0.75
390.2720642	0.10
395.1484375	0.03
396.0968933	0.01
401.2891541	0.06
404.2305908	0.03
405.2390137	0.15
406.3255310	0.06
413.2833557	0.13
414.5130005	0.04
419.5415955	0.03
431.1435852	2.06
432.2247620	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1349
Annotation	Patuletin 3-(6''-p-coumaroylglucoside)
Peak:m/z	Relative Intensity
191.0493622	0.04
217.1711121	0.06
221.0911865	0.21
225.0346680	0.10
226.2729797	0.10
227.0476532	0.04
228.9609528	0.06
232.0118103	0.04
233.2793427	0.08
235.0343628	0.22
249.1732483	0.09
254.0169830	0.16
255.1392822	0.30
256.1093140	0.10
263.2254028	0.03
271.2045593	0.53
273.1327820	0.19
280.1755981	0.04
282.9845886	0.18
293.0661011	0.10
299.2065430	0.24
300.2341919	5.05
301.1260376	16.96
310.7868652	0.15
315.0993958	9.81
323.0827026	4.94
323.6974487	0.27
325.9573059	0.11
329.1314697	0.13
330.3479614	0.34
334.5601196	0.04
335.4204102	0.15
343.2258301	0.71
355.2599487	0.12
356.9839478	0.07
361.0388184	0.04
373.1614990	0.18
374.3187866	0.06
381.3438110	0.13
423.2830811	0.09
433.4032593	0.05
435.2037964	0.03
445.3345947	0.40
447.4500732	0.08
449.4502563	0.04
457.3524780	0.06
459.1629028	0.35
463.2045898	100.00
465.2150879	0.11
471.2882690	0.20
475.5394287	0.13
477.3087769	18.22
478.2814941	0.04
481.4423828	0.23
493.3272705	0.58
495.0348511	0.06
503.2035522	0.07
507.7161255	0.05
516.2841187	0.15
527.0449829	0.22
529.6447754	0.13
531.4210815	0.23
537.3245239	0.04
542.5936279	0.17
545.5321655	0.03
547.1112671	0.12
549.5410767	0.04
550.8762207	0.08
553.7314453	0.08
566.2975464	0.07
567.7108765	0.08
574.8612671	0.06
575.5175171	0.05
578.4585571	0.08
580.4628296	0.04
587.6458130	0.07
591.2989502	0.13
592.5913696	0.35
593.3980103	0.21
594.9263916	0.58
596.4714355	0.14
601.6776733	0.05
602.5484619	0.23
603.1705322	0.24
609.2361450	0.09
614.2127075	0.16
620.3565063	0.14
621.5886841	0.19
624.2714233	0.10
631.1138306	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1277
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0662231	0.11
176.5195465	0.15
190.5415649	0.05
207.1455688	0.04
219.1220703	0.07
223.2193451	0.05
236.9838867	0.03
252.1767273	0.03
252.8749847	0.02
255.1039429	0.11
265.4600830	0.05
269.1986694	0.06
276.9884033	0.16
279.2286987	0.08
287.2305908	1.55
291.1663818	0.12
292.2841797	0.06
293.1454468	0.04
295.2314453	0.05
301.1404114	0.16
304.2405396	0.04
314.0502319	0.21
314.8420715	0.09
317.0805664	0.12
331.3402710	0.16
332.1054688	0.06
341.2222290	0.12
343.2943726	0.03
347.1653442	100.00
348.0155640	0.10
359.2758789	0.13
368.1514893	0.13
369.1245728	0.24
371.1364136	0.22
376.4130249	0.04
387.0971069	0.09
388.0236206	0.05
389.3021240	1.43
397.0686646	0.06
398.4105225	0.34
399.3272705	0.03
400.4031982	0.13
403.0462646	0.06
411.2559204	0.20
413.2076416	0.64
414.6353149	0.05
416.6726074	0.03
417.3388672	0.03
422.4669189	0.03
428.6479492	0.09
429.2694702	0.06
432.6444702	0.08
437.0461426	0.06
441.3181763	0.09
452.2914429	0.13
455.2092285	0.45
459.3955688	0.05
463.0036011	0.05
468.3079224	0.17
473.5728760	0.15
476.9291382	0.07
481.6009521	0.08
483.5545044	0.08
491.3196411	0.11
502.2982788	0.10
504.6250000	0.18
513.0582275	0.05
514.1156616	0.13
515.2927246	0.11
527.4334717	0.05
532.1527710	0.05
533.3303833	0.36
535.2793579	0.13
541.4539795	0.10
547.1641846	0.11
549.4674072	0.12
559.1736450	1.06
563.4276733	0.06
564.3098145	0.08
565.5056152	0.10
566.4452515	0.18
575.0203857	0.06
576.4692383	0.36
577.3321533	3.56
578.2192993	0.11
585.7461548	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1085
Annotation	Vitexin 3''-O-acetate
Peak:m/z	Relative Intensity
137.2046661	0.07
145.0390778	0.07
165.1924438	0.06
176.0404663	0.04
177.2062683	0.03
179.4284973	0.02
187.5119324	0.11
190.8370361	0.03
192.1459351	0.02
205.3871307	0.04
206.1871948	0.04
207.0654297	0.12
210.8733215	0.04
212.3099670	0.11
221.2498779	0.04
236.0437622	0.07
249.0561523	0.04
256.3756104	0.04
265.1954956	0.03
271.2841797	0.13
274.1482239	0.07
275.1482849	0.03
277.2556458	0.07
288.2114258	0.03
295.0501709	0.04
299.2409058	0.15
302.1599731	0.05
307.1109924	0.32
308.1727295	0.32
308.9342651	0.06
312.6031494	0.05
315.2277222	0.26
323.2797546	0.04
329.1652222	10.02
331.1979675	1.92
333.4591675	0.03
339.4825745	0.14
341.3038025	0.21
343.2800293	0.44
344.0078735	0.09
345.2295837	0.06
347.0751038	0.07
351.2955322	0.23
353.2293091	0.07
354.3341370	0.02
355.1144104	0.13
356.1741943	0.04
356.8204956	0.10
357.8831177	0.28
359.2074585	0.18
365.4375000	0.04
371.1076660	0.52
373.2263794	0.04
377.1754150	0.18
378.0364075	0.04
379.1862793	0.17
382.2361145	0.08
383.1152344	0.26
387.3176575	4.26
393.2625122	0.08
395.1364746	0.03
397.2363586	2.24
398.3677063	0.07
399.2870483	0.12
400.2134705	0.04
401.4238586	0.22
403.2399597	0.05
405.1336975	0.03
410.4531555	0.04
411.3495789	0.17
412.1847229	0.09
413.2277222	0.75
415.2117920	100.00
415.8370056	0.13
421.6016541	0.08
425.3588257	0.09
427.4828796	0.28
429.2525024	0.28
431.4767151	0.09
433.8172913	0.03
435.3119812	0.03
441.2076111	1.03
445.3249817	0.14
454.1502686	0.19
455.0376282	0.15
455.6469727	0.30
458.1558838	0.17
458.8436584	0.02
473.4659729	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.2
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9640808	0.23
145.1836090	0.05
153.2087555	0.06
160.9581451	0.13
162.9311676	0.05
179.1589203	0.06
180.8632507	0.23
184.1314240	0.08
187.0864868	0.09
211.2205353	0.06
220.3546906	0.16
227.0360413	0.15
229.3364563	0.14
231.2998962	0.07
237.1335144	0.15
241.1454315	0.12
244.9033508	0.08
248.1337891	0.05
254.8927002	0.19
257.2211914	0.06
263.3687439	0.07
273.2732544	0.08
275.1322327	0.05
281.0889282	0.04
283.1489563	0.05
284.2439575	0.77
285.2088928	1.91
293.1682129	4.00
307.2486267	0.59
312.9535828	0.08
315.4342957	0.12
323.0296021	0.27
325.0946045	0.40
326.4757996	0.58
327.2742615	1.00
329.2054443	0.38
330.7225952	0.37
331.3823242	0.29
332.3746948	0.08
337.2944946	0.04
341.4686890	0.06
343.2952881	0.32
353.2481079	0.29
368.2179871	0.05
373.5490112	0.36
374.9325867	0.07
379.2062683	0.28
381.1643066	0.70
387.4742737	0.41
392.4583435	0.06
395.5327454	0.07
405.3504333	0.23
407.2685547	0.06
412.3325500	0.06
415.5298767	0.08
427.5647278	0.35
429.0735779	0.05
430.4934387	0.24
431.2242126	0.44
434.5050049	0.07
443.2204895	100.00
444.0334778	0.56
445.3719177	0.93
447.4286499	0.11
451.3667297	0.56
453.2909241	0.28
455.4674683	0.11
459.6654663	0.09
461.1678772	0.22
462.0578308	0.13
469.2943726	0.32
471.3569641	1.48
473.4766235	0.08
474.3528748	0.13
489.5618286	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.17
Annotation	Nervilifordin C
Peak:m/z	Relative Intensity
198.2257385	0.60
214.6789551	0.14
217.1606750	0.30
220.2376709	0.22
223.1125793	0.10
229.3758392	0.10
262.4221802	0.09
275.2001343	0.10
278.4407349	0.17
293.2656860	0.30
295.7323608	0.12
300.8612671	0.23
303.1458740	4.71
304.1229248	0.25
305.1242676	0.06
308.8549194	0.14
317.0918579	0.58
320.9816895	0.50
331.3844604	0.56
333.1271973	100.00
341.3164673	0.10
345.0811768	0.23
347.2681274	0.14
357.3046875	0.33
358.4226074	0.55
359.3773804	0.60
365.4041138	0.14
373.4117432	0.30
375.1796875	1.96
391.9806519	0.24
396.1704102	0.55
417.2869263	0.33
425.5576172	0.12
434.3814697	0.59
443.2283325	0.68
452.9317017	0.37
455.1002197	0.25
457.5297852	0.34
461.2569580	0.07
463.2679443	0.27
473.5640869	0.51
474.9281616	0.35
475.8577271	0.14
477.2930298	1.02
479.0895996	4.07
495.0104370	15.28
495.6203003	0.82
496.3959351	0.52
499.3403931	0.12
502.9111938	0.08
503.6292114	0.30
508.2618408	0.17
509.1187134	1.40
521.3987427	0.42
533.2067261	0.40
542.9793091	0.22
544.5249023	0.09
550.3249512	0.22
551.0907593	0.40
559.8737793	1.43
562.8309937	0.15
567.7028809	0.11
575.2245483	0.58
595.3703003	0.44
603.8957520	0.14
605.3654785	0.30
609.3461304	0.37
618.3502808	0.12
622.4769287	0.25
623.3992310	0.53
625.5761719	0.38
627.4440308	0.60
631.6360474	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.0565
Annotation	Rhodolauradiol
Peak:m/z	Relative Intensity
103.1459351	0.03
108.8193207	0.04
121.0253754	0.38
124.0103378	0.78
125.0591354	0.09
137.0254974	1.74
139.0307465	1.43
146.9929504	0.06
157.2424927	0.10
164.9765625	59.98
166.0939789	0.63
167.0388184	0.58
168.0585938	3.43
169.4506989	0.03
180.7489929	0.10
183.0979767	100.00
183.9420319	0.07
187.9998016	0.03
193.1984100	0.05
194.0586243	0.05
195.1998901	0.21
203.2942352	0.06
208.9293671	0.07
223.1119690	0.10
246.1136169	0.04
258.7406006	0.06
260.3821411	0.06
261.0289307	0.19
262.0076294	0.13
263.2453003	0.25
263.9746704	0.08
265.2732544	0.07
268.2907104	0.17
273.2385864	0.07
289.3985596	0.17
290.2925720	0.06
302.0733032	0.04
303.1632690	0.22
304.3814087	0.61
305.1907349	1.31
306.5077515	0.05
313.4739685	0.16
316.0995789	0.09
317.1322021	0.24
318.6627197	0.07
320.4565430	0.08
329.5303955	0.04
330.2970276	0.30
331.2255249	1.63
333.1830750	0.34
334.1732788	0.05
349.3933716	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1083
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
96.0579071	0.03
109.0298843	1.73
110.3019409	0.15
122.0034790	0.15
122.9692078	5.43
124.0226593	0.77
126.9923248	0.06
138.0540466	1.29
150.7054749	0.04
153.0100403	100.00
154.0541382	19.08
165.0391235	0.20
173.1705780	0.04
179.3076477	0.03
194.8274078	0.09
201.2060547	0.09
205.4275513	0.03
206.5045471	0.08
207.3131714	0.04
208.2856445	0.09
208.9058838	0.08
218.1366577	0.03
228.0754089	0.03
230.4549561	0.02
236.9490051	0.13
254.2392273	0.03
257.2246704	0.07
269.9448853	0.53
288.1347046	0.03
297.3410645	0.11
298.2325439	0.12
300.2270203	0.33
301.1759644	0.10
315.0543213	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.12
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1119385	0.16
177.2668915	0.04
179.0397339	0.10
180.1519318	0.13
192.9473877	0.04
196.3434143	0.03
207.0523071	0.14
213.0199432	0.05
218.4708862	0.30
219.2101440	0.17
220.1355438	0.03
220.8201141	0.04
229.0185547	0.12
234.2827454	0.07
235.1519775	0.06
236.8917999	0.03
241.0813751	0.03
242.1403503	0.15
247.1320953	0.04
249.3008423	0.35
250.4452057	0.03
255.9635925	0.06
258.9888916	0.06
260.1154785	0.07
262.0216980	0.03
263.2007446	0.08
269.0853271	0.22
270.0692139	0.05
271.2193604	0.25
273.0649719	0.54
284.4266357	0.12
285.4360962	0.03
286.9689941	0.59
287.6440125	0.08
289.4999695	0.02
293.1582031	0.14
299.4073486	0.25
300.1112061	0.09
301.0945129	0.78
302.2310181	0.31
303.1921692	0.44
304.3455811	0.05
305.5064697	0.10
311.1895142	0.10
312.2008057	0.03
312.9223633	0.08
315.1206665	2.26
316.2210083	1.27
317.1693726	1.30
318.9364624	0.11
322.8350220	0.12
326.2008057	0.05
328.1620483	0.38
329.1791992	2.97
330.1416016	6.04
331.2792358	0.12
336.3674927	0.02
337.1392822	0.07
339.1918945	0.07
341.0009766	0.09
342.1488647	0.06
343.4465332	6.37
344.2261963	33.95
345.1782227	100.00
346.2423096	0.03
351.2708740	0.04
355.1177368	0.30
358.3513794	0.04
359.1398315	0.53
367.2992554	0.12
369.0988159	0.24
372.3303833	0.10
373.3292236	0.16
376.2795410	0.04
377.1885986	0.03
383.1538086	0.07
384.4185181	0.25
385.3114014	0.10
386.0930786	0.12
387.1768799	4.32
388.1651001	0.04
393.4172974	0.02
399.3062134	0.20
405.5198975	0.07
406.6630859	0.03
411.1998901	0.05
413.1122437	0.10
417.2059326	0.45
422.4027710	0.03
427.1501465	0.16
435.2977295	0.11
441.3317261	0.03
453.3579712	0.12
457.7589722	0.10
463.3546143	0.11
472.3868408	0.04
478.9651489	0.16
481.3505859	0.10
485.4806519	0.07
489.3584595	1.61
491.4435425	0.03
492.5953369	0.04
498.5795898	0.04
502.1495972	0.59
503.3358154	1.19
504.2839355	0.12
505.2648926	1.09
507.1950684	3.27
513.2543335	0.13
517.3497925	1.46
518.1172485	0.07
519.7142944	0.03
521.1259155	0.78
521.7374268	0.03
526.3016968	0.26
530.3673706	0.28
531.5623169	0.24
532.4348755	0.05
534.2033691	0.29
535.1990356	0.03
539.8421021	0.04
547.3424683	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	571.2186
Annotation	5alpha-Ethoxy-6beta-hydroxy-5,6-dihydrophysalin B
Peak:m/z	Relative Intensity
162.0387573	0.02
165.0361023	0.35
170.1136322	0.03
180.0790863	0.30
181.1285095	0.19
188.2556152	0.02
191.3007202	0.03
192.2280579	0.02
195.0899048	1.77
196.4464264	0.03
208.1906281	0.93
209.3667603	0.02
211.1347046	0.03
221.4160156	0.02
223.2503662	0.17
227.0142822	0.03
231.2255402	0.04
249.3249817	0.05
257.1324463	0.03
259.0810852	0.02
260.8868713	0.08
263.1333008	0.13
267.1271362	0.09
268.9863892	0.21
278.8995972	0.04
283.5390015	0.01
287.2291870	0.15
291.8143311	0.04
293.1569214	0.09
295.3914185	0.14
298.2335510	0.05
301.2700195	0.03
310.1984253	0.08
311.3397217	0.19
312.2095947	0.36
313.3486938	0.34
314.0108643	0.03
315.1681519	0.07
325.1561279	0.62
326.1589355	1.48
327.2855225	0.96
328.3440552	0.12
330.3489990	0.91
335.2244263	0.04
337.0119629	0.02
340.3696289	0.01
342.2440796	2.26
343.2484741	3.56
345.2510986	75.49
351.9153442	0.04
355.1025391	0.29
357.2904053	29.12
359.2432251	0.18
361.3608398	0.06
363.4441528	0.05
367.1049805	0.19
369.5681152	0.04
371.2117310	0.24
373.1147461	0.51
375.1622925	9.52
375.8342896	0.02
381.5311890	0.02
387.1599731	0.08
389.2970581	0.02
391.3102417	0.06
395.3270264	0.06
396.3576050	0.02
399.3195801	0.06
400.7285767	0.02
408.4155884	0.13
409.4547729	0.09
413.0850220	0.06
415.2667236	0.09
416.2570801	0.06
421.7777100	0.05
426.3541870	0.02
429.2957153	0.32
432.1232300	0.04
441.1896362	0.02
443.3256836	0.06
445.2808228	0.04
447.1995239	0.14
449.3848877	0.04
450.5499878	0.02
452.9201050	0.06
456.6235962	0.03
461.4034424	0.02
462.1469727	0.07
465.2372437	0.02
468.3094482	0.15
469.4321899	0.02
472.9462891	0.09
475.6390381	0.14
481.2673950	0.05
492.4965820	0.04
493.3713989	0.26
495.9216309	0.05
499.3111572	0.13
504.4748535	0.08
505.3600464	0.63
510.6314087	0.14
511.5158081	0.04
513.3193359	0.09
514.0975952	0.03
523.3495483	100.00
524.6928711	0.81
525.5606689	0.15
526.6886597	0.05
527.4525757	0.39
533.3192749	0.17
534.9662476	0.16
535.6307983	0.11
538.3732300	0.04
539.0603027	0.03
540.2139282	0.11
541.4122314	1.12
543.2499390	0.04
551.4483032	0.04
553.1349487	6.48
553.8425903	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	331.0669
Annotation	2-Galloylglucose
Peak:m/z	Relative Intensity
98.9964676	0.09
108.1019211	0.12
112.9146347	0.04
115.2150497	0.03
122.2130737	0.04
122.9843750	0.07
124.9986267	3.63
132.9700317	0.02
139.3907318	0.06
150.3855133	0.03
151.0608826	0.06
152.9341431	0.09
153.9970703	0.12
155.1609192	0.04
158.9015503	0.10
161.1627655	0.03
163.9559326	0.09
165.1423035	0.07
167.0595245	1.80
168.9617310	100.00
178.9739075	0.06
180.1846771	0.02
196.2619629	0.03
205.0647888	0.05
206.8947144	0.20
210.1804810	0.08
216.9743042	0.12
221.2153625	0.03
231.1461182	0.12
235.0721130	0.13
239.1818848	0.02
243.2796631	0.06
245.0661011	0.03
253.0632629	0.04
255.4331055	0.04
259.1259766	0.14
268.0903015	0.04
269.5284424	0.10
271.2130737	0.09
272.1690063	0.05
274.1414490	0.03
283.9737244	0.05
285.2018433	0.41
287.0037537	0.46
288.2316895	0.03
295.0613708	0.06
297.0688171	0.06
299.1729126	1.10
299.9111023	0.07
300.6698303	0.06
303.3055420	0.47
304.1353149	0.03
313.1443481	0.55
315.4030151	0.04
316.2406921	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1401
Annotation	Sinocrassoside A1
Peak:m/z	Relative Intensity
145.0475006	0.03
147.1715546	0.02
149.0615540	0.29
152.1031647	0.07
153.0719757	0.05
159.0496063	0.10
160.1044312	0.40
160.9648132	0.20
163.0818176	10.40
169.0523682	0.09
173.9425507	0.04
175.0780334	2.73
175.9091187	0.09
177.1090088	0.81
178.4556885	0.24
179.1439209	0.76
183.0575714	0.03
185.2636414	0.03
188.0081787	0.13
191.0942078	0.22
191.9407654	0.05
193.1268616	2.27
195.4228973	0.02
201.1526337	0.07
202.2210846	0.29
203.0651855	0.11
205.3153381	0.03
207.1341858	0.02
215.1036987	0.08
217.0587463	1.06
221.0908661	1.55
231.1504517	0.24
232.1276855	0.11
233.1407776	0.21
235.1273499	0.74
242.2197876	0.06
244.1845398	0.02
245.1809082	0.24
247.2496338	0.11
249.1476593	0.16
251.2848969	0.08
257.1831360	0.14
258.0797119	0.06
259.5307312	0.03
263.0078735	0.18
265.3819275	0.02
275.3632507	0.07
277.1934204	0.62
280.2398682	0.29
281.3112488	0.07
286.1376038	0.03
287.2669067	0.11
289.1223755	0.07
290.2953186	0.08
291.3251648	0.02
295.1136169	0.19
296.1873169	0.06
297.5752563	0.05
301.5107727	0.05
305.0954285	0.10
307.2497864	1.21
319.3121338	0.05
321.0601501	0.03
323.1838074	27.35
327.2512207	0.08
334.1867371	0.05
334.8466187	0.02
335.5284119	0.13
337.1513367	100.00
337.7709351	0.16
339.2169800	0.05
343.3028870	0.09
344.9782715	0.02
346.3317871	0.09
359.4741211	0.02
365.2700195	0.05
369.2511597	0.24
370.4673462	0.03
371.2353516	0.06
374.3753662	0.08
379.0935974	0.21
381.3482971	0.06
382.5484619	0.02
387.2168579	0.04
394.4491882	0.02
397.1249084	0.05
405.1365356	0.23
407.4085999	0.04
408.9962769	0.04
411.0967102	0.04
412.1007996	0.07
413.5089111	0.05
421.1128845	0.03
429.0476379	0.02
433.2821045	0.15
437.4657898	0.03
439.2709045	0.08
445.5091248	0.08
454.1831970	0.29
455.1372681	0.31
455.7745056	0.01
457.2487488	0.65
458.2019958	0.09
459.7789612	0.03
469.3673706	0.03
471.1800842	0.05
474.2734985	0.07
480.4579163	0.03
481.5125427	0.06
482.5138855	0.27
483.4103394	0.42
486.3145142	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9541779	11.40
212.3877258	0.02
246.0975037	0.15
281.0693665	0.01
290.7882385	100.00
291.4269714	0.14
296.9383850	0.03
346.2141724	0.14
348.2793579	0.31
349.3798218	0.03
368.9643250	0.05
374.1937866	3.11
374.8070984	24.11
398.9438782	0.23
415.1151123	0.05
428.6368713	0.02
440.1436157	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.23
Annotation	Unknow
Peak:m/z	Relative Intensity
161.2326660	0.03
166.0429535	0.03
177.1018829	0.03
185.0090332	0.02
187.3598938	0.06
191.1226501	0.04
192.2689667	0.02
203.1726532	0.03
220.8285828	0.05
239.2259064	0.15
249.2098694	0.02
257.2213440	0.05
259.0715332	0.07
267.2937622	0.06
279.3702393	0.02
283.1506348	0.02
290.8766479	0.02
293.1476440	0.16
295.1950684	0.09
296.3430176	0.02
300.8061829	0.05
303.4454346	0.11
311.0142212	0.37
323.3612671	0.07
327.7545166	0.10
335.6247559	0.03
339.6661987	0.04
343.1826172	0.05
345.2302856	0.06
346.0670776	0.06
347.1013184	0.26
349.2118530	0.17
353.1871338	0.03
363.4083252	0.13
365.5095215	0.04
367.2922974	0.03
377.3151245	0.08
379.2120972	0.10
381.5543823	0.03
382.5412598	0.04
391.7971802	0.02
400.4613647	0.05
409.2578125	0.02
417.3898926	0.02
421.3156738	0.03
436.5516968	0.02
441.3560181	0.03
445.8818359	0.06
447.4131470	0.12
450.2374268	0.03
451.7144165	0.04
465.2502441	0.03
479.3244629	0.06
481.3281860	100.00
481.9353638	0.45
484.2092896	0.07
491.1840820	0.13
495.2857666	0.05
497.6333618	0.05
502.7396851	0.13
507.0739136	0.09
509.5075073	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1246
Annotation	Unknow
Peak:m/z	Relative Intensity
177.2845001	0.01
179.0474396	0.13
180.0555573	0.01
187.3052368	0.02
202.2419891	0.01
211.1657715	0.01
215.3012390	0.01
217.1547394	0.00
226.1787415	0.01
227.2007446	0.01
228.9446411	0.04
231.1167145	0.01
233.0901031	0.02
236.1201324	0.02
243.2755432	0.01
254.0438690	0.01
255.1983337	0.22
258.0329590	0.01
271.2191772	0.14
273.0499268	0.14
283.1882935	0.17
284.1530151	0.06
295.4097900	0.02
297.4617004	0.01
299.0736084	0.11
300.3064575	1.87
301.1357422	12.72
302.2383423	1.86
307.1458740	0.03
308.1826172	0.01
313.2217407	0.01
315.2797852	0.01
325.1722412	0.02
326.0514526	0.04
328.2166748	0.01
337.1502075	0.02
343.1187744	0.17
344.1228638	0.01
394.4770508	0.02
401.2438354	0.04
403.2276001	0.02
419.1929321	0.03
429.2933350	0.03
436.5383301	0.02
445.3150635	0.58
446.4162598	0.11
447.1976318	0.07
447.8016357	0.02
448.4069214	0.01
449.5122070	0.00
457.3122559	0.01
460.0682983	0.02
463.2240601	100.00
464.2966309	21.46
465.3895874	0.02
477.2037354	0.03
489.3339233	0.02
500.2382202	0.01
505.2611084	0.01
538.4808960	0.04
547.3277588	0.02
562.8718262	0.09
563.4776001	0.09
565.2865601	0.10
566.0857544	0.02
567.5668945	0.02
573.3574219	0.03
577.1162109	0.02
578.2703857	0.02
579.2969360	0.02
591.3525391	0.09
592.1973267	0.01
592.9260864	0.04
595.3574829	0.06
601.2947998	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.2916
Annotation	Taxusabietane E
Peak:m/z	Relative Intensity
213.3195343	0.14
258.1902771	0.09
278.4149780	0.16
283.2697144	0.25
285.0402832	0.04
288.3731384	0.06
295.2234497	0.22
299.3757935	0.12
302.3453979	0.08
307.0985107	0.07
311.6919556	0.19
313.2989197	100.00
315.1353760	0.06
319.1366577	0.04
326.0680237	0.08
327.3566284	0.91
333.2370605	0.04
339.1731567	0.10
343.2221069	0.11
354.2509155	0.10
355.1928711	0.18
356.0499878	0.21
357.1128540	0.19
361.3626709	0.25
367.2444458	2.13
368.2924194	0.44
372.4526978	0.18
373.4432983	0.08
374.1002197	0.07
379.7537231	0.03
381.3925781	0.20
385.1937866	0.08
391.3344727	0.09
395.2659912	0.12
398.4776611	0.06
407.3883057	0.05
421.4737549	0.08
425.2615967	0.18
435.3852539	0.20
437.2441406	0.05
438.4443970	0.09
443.4070435	0.05
449.0122070	0.18
451.2091064	0.09
461.2124634	0.86
463.4525146	0.08
465.1915894	0.09
471.7382202	0.06
473.3688965	1.54
475.3295288	11.36
475.9396362	0.12
477.4310913	0.04
487.5972900	0.04
489.2202759	0.12
489.9057007	0.15
491.3860474	4.83
492.3894043	5.13
493.4392090	0.65
494.2341309	0.09
503.4224854	1.86
504.3747559	5.19
505.3327637	1.44
506.5187378	0.04
507.6124268	0.18
508.3546143	0.53
509.4362183	0.70
511.2424316	0.19
513.8873901	0.23
515.5180664	0.25
517.2990723	0.33
520.3049927	0.14
521.4282227	0.09
523.2338867	0.94
524.6883545	0.05
542.6076660	0.07
544.2940063	0.30
547.0708008	0.05
553.5934448	0.12
556.2057495	0.12
557.3909302	0.36
564.2349243	0.10
565.4495239	0.08
570.5921631	0.09
574.0597534	0.04
576.5406494	0.16
577.6096191	0.04
583.4227905	0.17
585.2207031	0.23
591.6227417	0.11
596.1574707	0.25
599.2010498	0.04
603.6115112	0.07
604.6256714	0.11
607.8867188	0.09
616.4281616	0.58
619.6490479	0.08
620.5215454	0.42
622.4512329	0.05
623.2379761	0.14
627.2122192	0.26
632.5150757	0.17
637.3330078	0.16
638.9592896	0.07
642.3309937	0.11
643.5449829	0.50
647.3293457	0.15
649.9013672	0.05
651.1384277	0.04
652.3853149	0.98
653.4158936	0.33
659.5368042	0.21
669.6764526	0.35
670.5030518	4.46
671.4869995	0.85
672.1732788	0.33
672.7778931	0.10
674.3039551	0.31
675.3876343	0.41
681.5492554	0.09
683.4938354	0.48
684.4935913	0.28
686.6171265	0.07
688.2263794	0.33
700.4033813	1.68
701.3550415	1.08
704.1279297	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.16
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
285.2480774	0.04
301.1843262	0.17
331.1658020	100.00
331.7791748	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.1279
Annotation	Unknow
Peak:m/z	Relative Intensity
120.7597275	0.02
121.9190292	0.02
129.8283386	0.03
131.9927979	18.94
149.0801392	0.09
159.0912476	0.04
160.1690063	0.02
162.1757050	0.10
166.1260071	0.03
167.2402039	0.07
168.2859192	0.05
172.0223083	0.02
173.3617249	0.03
175.0092621	0.06
176.2173462	0.02
177.2500305	0.05
180.1852417	0.06
182.2205200	0.04
184.0362549	0.61
190.1133118	0.03
191.2034454	0.01
192.3580933	0.01
193.1604614	0.29
194.2345123	0.07
195.1204529	0.02
197.1456909	0.02
202.2174072	0.07
203.0358887	0.02
207.3872070	0.02
212.1432800	2.84
217.3090210	0.03
218.2806396	0.04
224.2841187	0.10
226.1912537	0.02
228.1923523	0.18
229.6734924	0.01
231.0131226	0.03
233.0741272	0.02
236.0977783	0.03
237.3272095	0.02
240.2022400	0.09
242.1281738	0.04
247.3466797	0.02
248.5480652	0.02
251.6843872	0.04
259.0831909	0.04
260.6270142	0.03
268.1725464	100.00
269.1693115	0.02
272.0758667	0.14
277.6946411	0.05
279.2534180	0.06
281.3900757	0.05
288.1043091	0.10
294.9437256	0.03
296.4790649	0.04
297.4554749	0.02
305.3698425	0.27
306.0949707	0.30
307.0758667	0.07
308.4274902	0.36
309.2771606	0.03
316.6415100	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1348
Annotation	Syringin
Peak:m/z	Relative Intensity
113.1971130	0.10
147.0781555	0.05
149.0042114	11.40
161.1627502	0.14
163.0749359	0.13
165.1134186	0.11
191.0190430	0.20
209.1651917	100.00
219.2850037	0.09
250.9871826	0.28
260.9347229	0.10
265.4834900	0.17
311.1985168	0.29
313.2283936	0.12
326.3317261	0.17
335.0722046	0.07
341.0393372	0.09
353.3443909	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1821
Annotation	Unknow
Peak:m/z	Relative Intensity
143.1613464	0.10
144.9806671	0.10
161.1081543	0.09
163.0296631	8.31
205.1861572	0.81
230.7595215	0.05
233.0656586	0.08
233.8712616	0.32
234.8873596	2.74
243.0675812	0.09
249.2096252	0.05
252.7538147	0.16
264.4052734	0.70
265.0447693	3.67
271.1573486	0.71
288.8377686	0.09
293.8048401	0.05
295.2098999	0.32
307.2587891	1.43
313.2603760	0.05
319.1222534	0.04
324.9318542	5.46
325.5366821	0.34
329.0029297	0.11
342.2985535	0.08
353.1266174	0.07
387.2563171	0.11
391.2121277	0.09
403.3070984	0.16
429.1763000	100.00
429.8357849	0.10
430.7116089	0.12
431.4139709	0.06
439.0465393	0.10
447.3172302	0.07
456.1038208	0.11
457.2926331	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1033
Annotation	Cinchonain Ic
Peak:m/z	Relative Intensity
137.0118103	0.05
151.2249603	0.05
160.2597961	0.10
161.1560822	0.06
169.8798981	0.01
175.2683258	0.04
177.1317139	0.17
181.0583191	0.02
184.8801575	0.02
185.9545593	0.02
189.0179749	0.69
204.1305695	0.02
204.9071503	0.02
216.1620331	0.04
217.0502625	0.86
219.0919037	0.26
231.2036285	0.23
233.1824951	0.04
237.3815918	0.01
244.9401550	0.07
247.4649963	0.04
253.3131104	0.05
255.1216736	0.09
257.4438782	0.01
271.2377319	0.04
278.6899414	0.08
279.3045349	0.14
287.2178345	0.38
288.3305054	0.09
289.1750488	1.17
297.3099976	0.13
298.6128235	0.13
299.2456055	1.66
301.1300659	0.30
315.3128052	0.09
317.3295288	0.03
318.2225342	0.01
319.3265991	0.05
323.1908569	0.17
327.0803833	0.17
329.4317932	0.01
332.0661011	0.02
333.1040039	0.02
341.1420898	100.00
353.2383423	0.03
363.0354919	0.02
391.0770264	0.02
395.3165588	0.03
405.1731873	0.05
407.5081177	0.12
415.4369202	0.02
433.2045288	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.0968
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
181.0478668	0.10
193.3126373	0.02
195.1390381	0.01
223.0635071	0.15
229.0963593	0.05
235.4546814	0.01
240.9716492	0.06
247.0776367	0.02
259.2193298	0.04
275.2879639	0.01
279.3818970	0.02
293.1780396	0.03
301.3139038	0.01
312.9963379	0.01
319.1080933	100.00
320.0039368	0.03
329.0923462	0.33
331.2811890	0.11
339.4683838	0.03
343.2111206	0.51
349.2119446	2.36
355.3872375	0.04
357.0571289	0.01
361.1432190	0.52
367.3742371	0.02
373.2579346	0.13
381.0289307	0.03
385.1097107	1.03
390.9476013	0.05
397.1530762	0.19
399.3151550	0.02
408.9506226	0.06
415.1401062	0.91
427.2431030	0.33
445.0926208	0.90
463.2040100	2.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.2919
Annotation	Argyrin E
Peak:m/z	Relative Intensity
239.1122742	0.07
262.4458923	0.16
273.2565613	0.19
327.1021729	0.07
330.3432617	0.12
348.4954834	0.10
359.2112427	0.23
363.2773438	0.09
371.2339478	0.23
379.0012207	0.04
385.6053467	0.11
400.4277344	0.05
405.9730225	0.11
407.4854126	0.07
421.5789185	0.08
422.2781982	0.03
423.3013306	0.13
424.3398438	0.14
427.4287109	0.12
433.2358398	0.06
434.9909058	0.08
445.3829346	0.21
447.3486938	0.04
456.4197388	0.04
461.3890381	0.05
463.3408813	0.04
464.1900024	0.17
465.2034302	0.05
469.6937866	0.05
470.4970093	0.04
471.2005615	0.28
475.0902100	0.06
491.6549683	0.16
497.4508057	0.03
499.2050171	0.06
505.1647339	0.23
506.3378296	0.06
512.1452026	0.03
520.4371338	0.21
522.1972656	0.09
532.1358643	0.04
534.5241089	0.12
537.4519653	0.16
538.5838623	0.14
549.3656616	0.08
550.5494995	0.15
557.8536377	0.06
560.2433472	0.05
567.1886597	0.31
569.2173462	0.24
579.3442993	0.14
581.2897339	0.54
582.8084106	0.11
585.2723999	100.00
586.3240356	2.15
589.4790649	0.04
595.6437378	0.10
596.2761230	0.04
601.8094482	0.20
604.6977539	0.12
609.8107910	0.08
611.3884888	0.11
612.5043335	0.26
613.3998413	1.97
614.2868652	0.39
627.1759033	0.49
628.1728516	0.09
628.8816528	0.03
630.3260498	0.30
631.4397583	0.84
632.3554688	0.20
637.0042114	0.03
639.0929565	0.18
641.0092163	0.14
642.3271484	0.07
643.4201660	0.46
644.3570557	0.15
645.5449219	0.11
646.1736450	0.07
652.1558838	0.33
653.0135498	0.55
653.9330444	0.25
660.1187744	1.17
661.4002686	0.54
662.1196899	0.04
665.2631226	0.15
667.1997681	0.10
669.3990479	0.10
670.0598755	0.03
671.3073120	0.43
672.4554443	0.24
675.3950806	0.06
679.4514160	0.04
682.4505615	0.03
683.3627930	0.47
684.4951782	0.14
691.4522095	0.18
695.0333862	0.14
703.1403198	0.09
705.5870361	0.06
708.2498779	0.37
708.8856201	0.48
713.2625732	0.20
717.3300171	0.11
718.2731323	0.18
719.4611206	0.08
722.5296631	0.02
724.7988281	0.09
725.4523315	0.25
733.6998901	0.12
736.9636230	0.07
741.6571045	0.04
745.5466919	0.81
746.8211060	4.08
749.2885132	1.39
750.4728394	0.82
757.5504761	0.10
759.3507080	0.21
760.4387817	0.03
761.4984131	1.67
762.4108887	0.49
770.9511108	0.26
771.9197388	0.08
773.7148438	0.12
775.4707031	0.69
776.3945923	0.99
779.6098022	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1504
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
112.7980499	0.38
130.9241638	0.06
135.1306458	4.22
149.4352417	0.17
158.9618073	0.35
161.0377502	2.29
165.0137482	0.66
175.3083038	0.11
179.1625824	48.58
186.9647827	0.12
193.0413208	0.39
201.4356689	0.07
203.1674500	2.01
211.3157349	0.15
215.1551514	0.06
217.1019287	0.14
221.2309875	0.90
223.0510406	100.00
233.2175903	0.32
234.5559387	0.05
237.3118591	0.06
246.1797180	0.07
247.1882019	5.13
251.0936584	0.20
256.2261658	0.07
265.0708618	8.84
267.1125488	0.21
277.2051086	2.46
279.3159790	0.12
281.0147095	0.11
289.1473999	1.50
294.3818359	0.63
295.2105408	4.14
297.2412720	0.45
305.4038086	0.23
307.2363892	0.19
322.2944031	0.23
323.0977478	0.09
324.4919739	0.27
325.2343750	11.04
339.1534424	0.43
340.2208252	0.16
341.3059082	1.86
343.5522461	0.07
346.9551392	0.09
349.0564575	0.33
355.3519592	0.36
356.6845093	0.20
367.1467590	3.13
369.0753479	0.12
370.1329956	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1195
Annotation	Unknow
Peak:m/z	Relative Intensity
137.9489136	0.08
139.1230774	0.08
149.0249939	2.04
149.9116364	0.07
151.1296082	0.23
161.2411804	0.03
164.0875854	0.07
165.0207367	0.28
167.0911865	0.20
177.0734100	0.15
179.0480194	1.43
181.0999451	0.08
182.2493591	0.05
182.9142761	0.03
189.0376587	0.05
191.2377319	0.26
192.1482239	0.58
193.0528870	1.69
195.0236511	0.10
197.2472534	0.05
202.8467712	0.05
205.1596985	0.15
207.2434845	0.21
215.1241760	0.07
217.0678101	0.10
220.2742615	0.11
221.1401825	0.04
225.2183838	0.06
229.4322662	0.05
232.9789429	0.36
234.8207245	0.12
237.3419495	0.16
239.0100708	0.10
245.1243591	0.25
248.9185791	0.04
254.7788086	0.05
259.2703247	0.17
261.0467834	0.48
262.8504028	0.05
265.1226501	0.31
271.2275696	0.39
275.1243591	0.21
281.0288391	0.55
285.3027649	0.22
286.1130371	0.06
293.0620117	0.04
297.1655273	0.90
298.2077026	0.55
299.2712402	6.84
301.8583984	0.13
303.1134033	0.82
311.1095581	0.08
313.0667419	0.35
313.9511108	0.70
316.0863037	40.59
317.1201172	25.45
319.1493530	0.58
325.1479492	42.93
327.5866089	0.15
329.2260437	100.00
330.9977417	0.13
333.0781555	0.09
341.0772400	0.04
345.1887207	0.35
346.2113953	3.08
347.2765503	13.52
348.4666748	0.11
353.2022095	0.21
359.2263184	0.45
360.2632751	0.14
369.2639160	0.07
373.0043335	0.08
375.1555786	0.29
377.4928894	0.07
382.3687744	0.06
383.2911987	0.16
389.2903137	1.02
392.3050842	0.25
393.3341980	0.19
401.1813660	0.40
410.0678101	0.06
419.2221375	0.49
421.3829651	0.13
435.2728577	0.69
441.4026794	0.10
443.6034851	0.09
460.5762024	0.38
461.2482605	5.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	482.2585
Annotation	N-acetyl-LTE4
Peak:m/z	Relative Intensity
135.1109467	0.71
137.0617065	0.30
145.0005341	0.59
152.9804993	100.00
154.0253296	0.26
162.4805603	0.72
163.1266785	0.44
168.2105560	0.62
169.1767273	0.98
170.1604919	4.83
170.8639832	24.35
175.1483459	0.14
217.1406250	1.09
223.0227203	1.26
225.2478638	0.12
227.0142212	0.23
235.2121887	0.17
241.0349274	2.42
247.0110168	0.50
259.0326538	9.43
266.6813354	0.19
271.1969604	0.16
277.0109863	2.27
279.5162354	0.15
285.1981812	1.08
289.2516174	0.21
294.9204407	15.19
301.1278687	0.25
302.4106750	7.95
303.0256653	12.93
313.1090088	0.79
314.8800659	0.14
318.0953064	0.19
331.1959839	0.16
332.3569946	0.95
333.2767334	1.23
344.8609314	0.26
362.3701782	0.41
401.1763000	0.51
409.5181580	0.17
410.8965759	0.27
428.2756958	0.35
428.9837952	1.69
436.9600525	0.48
447.0538025	1.00
464.3406067	6.11
465.0665894	30.93
482.2221375	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.143
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
76.9739990	0.13
79.7905884	0.18
82.9362030	2.44
85.0834656	0.14
91.0441437	0.19
92.8260193	0.72
94.9218140	1.06
97.0233460	7.39
98.8991394	0.45
104.8758087	0.35
107.1152954	0.07
108.9716492	6.98
111.0062866	4.82
113.1852112	0.72
117.1928864	0.50
119.0233307	3.84
121.0054932	3.55
123.0315857	2.33
125.0365448	3.31
126.9209137	0.59
128.8419647	0.16
131.0321503	0.68
133.0001068	1.31
135.0959015	3.77
136.0967865	0.11
137.0625305	1.19
139.1610565	1.62
144.9373322	2.96
147.1337128	5.37
149.0008087	3.99
151.1072845	16.76
153.0745087	7.93
154.9196320	0.49
157.1312714	1.88
158.2149506	0.18
159.1107330	4.26
161.1491394	4.58
163.0258331	16.11
164.9936371	0.95
166.8155975	0.28
169.0065918	0.97
170.1788177	0.97
171.1501465	0.40
172.1577301	0.07
173.1032715	8.91
175.1446991	1.84
177.1654358	9.01
179.1639252	0.47
181.0496063	19.55
183.0857239	0.91
185.1294861	7.59
185.9905548	0.55
187.1776886	19.29
189.1083374	1.98
191.0425873	9.16
195.1496582	0.14
197.3886261	0.15
201.0840454	24.06
203.1495361	5.86
205.0702667	62.19
207.0666962	2.60
209.0757294	100.00
211.1292877	2.35
213.1698303	0.69
214.1322784	0.16
219.2119141	16.28
221.2574921	0.23
223.8516388	0.35
229.1694946	40.32
235.0445099	0.48
237.0681915	1.39
242.4622345	0.59
243.9678192	1.27
244.6673126	0.28
247.1689301	93.48
249.0934448	0.10
252.9141998	0.19
265.0313110	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1194
Annotation	Castamollissin
Peak:m/z	Relative Intensity
141.2817841	0.04
149.9896088	0.06
151.1015930	0.07
153.3112488	0.06
159.1348877	0.03
161.1569519	0.08
163.1755676	0.11
164.0911865	0.18
165.1014709	0.18
167.0217285	0.05
176.0279083	0.04
177.0049133	0.17
178.0836792	0.03
179.1755219	0.16
181.0575562	0.26
183.2425537	0.04
189.0548859	0.32
191.0369568	0.09
193.1071472	0.05
201.0649109	0.15
203.1296387	0.06
207.1591492	0.08
212.1996002	0.03
217.1902161	0.33
219.0596313	0.36
224.2486877	0.04
229.0656586	0.31
231.1128235	0.08
232.2133026	0.02
233.1561890	0.19
234.3086243	0.22
244.3074646	0.05
245.1990662	0.02
246.5235901	0.04
247.2449799	0.10
253.0729828	0.13
254.7369690	0.08
255.3778992	0.11
257.3453979	0.39
259.0738220	0.15
261.1853638	0.11
263.1949158	0.26
266.1854248	0.03
268.3862610	0.13
270.1344910	1.07
271.1343384	0.22
272.1255798	0.33
273.1672668	0.30
274.4408569	0.09
275.2863464	0.28
277.1702271	0.17
279.2186890	0.09
280.1233215	0.02
284.0961304	0.29
285.1559143	2.42
286.3071899	0.04
287.1941833	0.73
288.2520752	0.06
289.2323608	0.03
293.3485107	0.07
296.2119751	0.21
297.2280884	0.40
298.1248779	0.08
299.1843262	1.40
301.3926086	0.24
302.2406006	0.46
303.2856140	0.24
307.3917236	0.07
308.2239075	0.05
310.1802673	0.03
311.3211060	0.17
312.1161499	0.36
313.2273560	2.34
314.2101135	1.75
315.2233276	0.27
315.8843994	0.07
319.4820862	0.09
321.3329468	0.08
322.1400146	0.05
324.5230713	0.11
327.1661987	12.38
328.1589966	58.62
329.1614075	100.00
330.1933289	4.09
331.2520752	17.57
337.3370972	0.33
339.2488403	0.57
341.3202515	2.07
343.2410278	15.70
345.1653442	0.57
347.1223450	0.53
351.2961426	0.12
353.2734375	0.41
354.1957397	0.05
355.2799683	0.50
356.9924011	1.37
357.6265869	0.08
359.3466797	0.25
366.8653564	0.06
369.1783142	0.49
370.0795288	0.26
371.1693115	8.58
371.8377686	0.03
372.6646118	0.06
373.4017639	0.18
381.3059998	0.23
383.2232361	3.78
384.5301819	0.23
385.5012817	0.09
387.3156433	0.30
393.2966309	0.09
395.2845154	0.42
399.3563538	0.10
401.1879883	5.05
409.3019714	0.10
413.3346252	2.24
425.3049011	0.09
427.2871399	0.17
429.2526855	0.07
431.3158264	0.14
437.1643372	0.22
441.0134583	0.04
443.0535583	0.15
445.2951965	0.78
447.1984558	0.33
455.2234497	1.00
459.3219604	3.66
463.3190308	0.19
471.2206726	0.03
473.2745972	1.27
476.2704468	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7769775	1.44
284.0517273	0.06
296.8293457	27.57
302.9848022	0.18
308.9374390	0.08
378.3183899	0.33
380.6553040	100.00
381.4376526	0.43
393.0015869	0.24
404.7502747	0.09
417.3205872	0.02
447.1655273	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.1694
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
120.9488297	1.97
122.9863205	0.76
135.1072998	4.55
144.9408417	1.64
147.0473938	3.20
153.0524902	0.62
156.9457245	0.38
157.8449860	1.64
159.0345764	4.88
161.0545044	0.74
163.1822357	8.76
165.0951080	8.52
167.1481934	1.11
170.9563599	1.47
175.5525665	1.55
176.3510742	1.18
177.1032715	2.76
179.0175171	0.74
181.1561432	4.06
187.1516113	0.81
189.0692749	2.00
193.2361298	1.76
197.2541046	1.18
199.0269165	2.06
200.8840637	1.22
203.8113098	1.64
206.9720459	2.97
213.0967102	1.04
215.0674744	0.50
217.3134918	1.96
218.9575195	2.90
225.0296936	6.16
231.2067566	4.00
233.0421448	1.89
237.2331848	0.98
243.0682678	13.42
249.0444031	0.74
258.8119507	0.68
261.1276245	31.21
274.8117676	1.46
279.2149658	19.22
281.2070007	0.44
283.0510559	0.62
285.3302307	1.66
286.3877869	2.43
287.1046753	1.31
289.2760315	1.47
293.3483582	1.30
296.2732544	0.68
297.0869141	2.20
299.5437012	0.44
303.4711914	2.26
309.3662415	4.44
321.2332764	16.53
327.2090149	2.30
329.3320312	1.86
338.1816711	0.94
339.2341309	2.71
347.2093811	15.76
351.1463318	3.46
353.4112854	0.56
355.2706604	2.26
365.2319641	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.2196
Annotation	Citbismine C
Peak:m/z	Relative Intensity
207.3359833	0.04
237.0786133	100.00
239.0604706	0.03
262.8648071	0.05
267.1180420	0.31
291.2841187	0.03
292.3174438	0.07
293.1823730	0.25
297.2740784	0.08
311.1604004	0.18
323.4484863	0.05
324.5515747	0.03
353.1787109	0.03
368.2839355	0.04
369.3634644	0.46
399.1589966	0.06
435.2557373	0.07
455.2076416	0.03
470.9784546	0.05
472.1899414	0.05
473.3677368	3.67
474.2842407	0.04
490.1375122	0.07
498.5262451	0.05
502.1027222	0.04
503.6178589	0.12
518.4923706	0.07
520.2598877	0.03
521.2244873	0.32
549.1209106	0.06
550.2899780	0.05
562.9697876	0.09
577.2154541	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	749.3026
Annotation	Unknow
Peak:m/z	Relative Intensity
211.3135071	0.08
220.3881226	0.02
224.1802673	0.15
225.1887207	0.05
226.9778137	0.03
235.7591248	0.08
256.1673889	0.01
266.9105530	0.09
269.3846130	0.10
285.4410400	0.04
292.1214600	0.04
301.3822021	0.02
309.1325989	0.02
310.2148743	0.02
311.2955627	0.02
313.0680542	0.04
328.2971191	8.99
329.2360535	1.08
331.2116089	0.07
333.2335815	0.03
341.0606079	0.02
343.2138062	100.00
344.2073975	10.81
345.1848145	0.03
347.2133789	0.10
355.3257446	0.05
357.3641968	0.02
360.4272461	0.02
361.4585571	0.20
387.4105835	0.03
395.4426880	0.02
396.6696777	0.04
419.4923096	0.04
435.5449829	0.09
443.2202148	0.04
496.4794312	0.02
502.3876343	0.06
507.2028809	0.02
511.2539062	0.06
523.3248291	0.09
525.2310181	0.04
530.6946411	0.01
539.4931030	0.02
544.3711548	0.02
548.9380493	0.03
550.4916992	0.05
551.9195557	0.07
553.4032593	0.20
555.4028320	0.05
556.6367798	0.04
557.3933105	0.07
562.3790283	0.05
564.1393433	0.02
567.2847290	0.02
568.1481934	0.01
569.2312622	0.08
575.5499268	0.04
577.6694946	0.06
579.3087158	0.02
583.3252563	0.02
585.8991089	0.04
587.6250000	0.04
599.5359497	0.05
613.6240234	0.02
617.4116821	0.07
625.3274536	0.19
627.2920532	0.19
629.3685303	0.01
631.6216431	0.03
635.2545776	0.02
639.4352417	0.01
640.1137085	0.02
643.9201660	0.01
646.9318237	0.01
653.1387329	0.09
653.8023071	0.04
655.7115479	0.02
660.3749390	0.08
663.1581421	0.04
664.3760376	0.05
666.7221069	0.04
684.4506226	0.02
687.1796875	0.08
689.3696899	0.03
699.7214966	0.01
701.2998047	0.85
702.5064087	0.28
703.3867798	0.03
704.3347168	0.08
705.5398560	0.05
706.3673706	0.22
713.4846802	0.20
719.1458740	0.09
719.7531128	0.07
720.6483765	0.03
722.4157715	0.07
728.4796753	0.06
729.5422974	0.08
731.2830200	1.00
732.3676147	0.29
741.4526978	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.0804
Annotation	5,6,4'-Trihydroxy-7,3'-dimethoxyIsoflavone
Peak:m/z	Relative Intensity
123.2143402	0.45
137.8171692	0.36
150.0318604	0.85
151.1605835	2.59
162.9874725	3.66
178.0349121	3.22
178.9104919	9.48
194.0120544	0.72
201.1956177	0.50
214.9727478	2.60
220.0409241	2.94
227.0230713	0.45
237.2040100	1.85
241.9735413	9.56
243.2032166	3.37
253.2313538	0.59
255.2189331	2.10
257.2336426	0.85
259.3431396	0.91
260.3291931	0.50
268.9759521	0.72
270.0509033	52.77
271.2009277	16.29
272.4836731	0.98
275.1738586	2.43
283.9161377	1.84
285.2109985	4.20
286.1276855	2.83
287.2130127	51.12
288.1811523	4.34
289.7861938	0.45
298.0588684	26.29
299.1324158	70.25
300.2009888	16.37
303.0734253	1.18
307.3607788	1.09
313.3074341	5.49
315.1753235	77.71
316.1737976	100.00
317.0958862	6.25
331.1546326	27.46
332.0461731	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
182.9797058	0.12
191.1829376	0.06
206.7602997	0.08
215.1708069	0.04
216.2966003	0.03
243.1976624	5.09
244.1344910	3.05
254.9301147	0.04
259.1277466	0.10
265.1632080	0.11
282.0046387	0.09
289.3720703	0.04
290.0310974	0.06
299.8239746	0.07
303.2480774	0.15
304.0226135	0.03
307.1515198	0.12
322.0245972	0.03
341.2477722	100.00
351.1909790	0.05
368.1464539	0.19
369.3124084	0.10
370.1363831	0.05
END