#DEFINITION	Reference Metabolome for Pyrus pyrifolia
#IDENTTFIER	RefMeta-Pyrus pyrifolia.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Pyrus pyrifolia
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Pyrus pyrifolia was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	Lactulose
Peak:m/z	Relative Intensity
178.7582092	0.03
322.7062988	0.03
341.1110535	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
77.01138306	0.12
94.88935089	0.60
97.10903931	0.28
98.67617035	0.35
100.7532043	0.48
104.9483948	0.23
106.9838867	0.49
108.0573807	0.25
110.0620041	0.48
111.0789185	1.77
115.0108337	0.37
116.1443863	0.09
116.9252853	0.29
119.1015778	0.18
121.1535034	0.44
124.9751663	1.30
126.9601135	1.18
128.9866333	0.87
131.1643982	0.95
133.1123352	0.15
135.0537109	0.09
137.0287628	1.82
138.1037292	0.32
139.0862427	1.36
141.0321655	0.96
142.2276917	0.18
143.2149963	0.47
147.2472229	0.22
149.0835266	1.04
151.315918	0.73
153.0166931	0.92
155.1306763	0.10
156.861496	0.54
159.0549927	0.11
160.9814758	0.24
162.9710236	0.22
165.0610199	0.35
166.9701538	0.38
169.0636902	1.18
170.8717041	1.53
175.1749573	0.53
177.0238647	0.90
179.1089783	0.12
180.065918	0.14
181.0768127	1.97
183.0563965	0.64
184.9358368	0.71
187.1101685	0.24
191.0638428	0.60
193.1390381	0.57
194.3156128	0.25
195.3006287	0.26
197.1730042	1.33
201.4070129	0.40
205.234436	1.47
206.3471375	0.33
207.1990356	0.16
209.1525574	1.58
211.2281189	1.12
212.0073242	0.18
213.18573	1.64
214.6801758	0.19
215.4784241	0.14
216.717804	0.61
217.3767395	0.25
222.5909119	0.45
223.3298035	0.30
223.9867249	0.51
225.1477356	1.38
227.0194397	2.32
229.2670288	0.63
230.2810974	0.92
231.0788269	0.25
232.3215942	0.48
233.2207947	1.04
235.3571777	1.79
236.2661438	0.40
237.1395569	2.61
239.0471802	0.91
241.2164917	1.70
246.9936218	0.80
247.6430969	0.18
249.0616455	1.19
251.3244934	1.31
253.1487427	7.52
255.1029053	0.54
257.2589722	1.49
264.0513916	0.64
265.038208	1.71
267.22995	1.71
269.1370544	1.61
275.260376	16.27
277.3027344	0.38
281.3364258	0.33
282.2655334	0.21
283.2399902	6.20
285.7163696	0.25
288.1393433	0.26
289.1226196	0.21
291.2254333	0.44
293.2137756	100.00
294.2492065	0.63
295.0712891	0.22
302.2998352	0.28
311.3681641	0.20
323.8168335	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.18
Annotation	Tanzawaic acid E
Peak:m/z	Relative Intensity
131.0279236	0.12
149.1413879	0.07
156.910675	0.02
165.9825439	0.01
167.0499268	0.03
168.9995728	0.03
189.1807556	0.03
191.1170807	0.05
209.3840332	0.03
210.8985291	0.09
219.3568726	0.14
225.3733826	0.04
227.2189941	0.13
229.4528198	0.05
230.4277649	0.03
231.1787109	0.04
241.9476318	0.08
243.1832886	0.14
245.2010498	0.18
247.2478333	0.09
253.3730469	0.20
255.1066589	0.16
262.6010132	0.27
269.3845215	0.08
271.1680908	100.00
273.1088562	3.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.1407
Annotation	Unknow
Peak:m/z	Relative Intensity
161.9960175	0.62
168.9456787	0.03
169.8567810	0.15
172.0448761	0.05
179.0162048	2.69
184.0411987	0.02
187.1420593	0.26
196.9607391	0.03
206.8197021	0.19
215.0097809	0.69
216.1328430	0.16
221.2527618	0.10
227.2011414	0.01
233.0690308	4.84
238.1262512	0.04
241.0927734	0.06
244.9397125	0.24
249.9463806	0.13
251.1181030	0.15
265.0466309	0.02
267.3164673	0.02
271.4282227	0.06
272.2104492	0.23
273.1193237	0.02
274.3825684	0.06
284.2000427	0.27
290.2146301	0.54
291.2206726	0.20
298.6221619	0.02
300.1094360	0.03
301.0245972	0.13
302.1357422	0.22
308.1930542	8.39
318.0687866	2.60
319.0802612	1.69
319.9389038	0.03
334.1859131	0.03
336.1603394	35.35
341.1206055	0.16
344.2020874	0.61
358.2898560	0.03
362.0054321	0.81
367.6019287	0.03
368.4168701	0.07
374.2018433	0.05
375.0882568	0.74
376.0839844	0.10
377.0936279	0.02
385.3300781	0.03
393.2125854	3.58
394.1283569	0.05
395.0626831	0.07
401.3637695	0.07
402.1361694	1.22
411.1008911	100.00
411.7804565	0.10
413.1769409	0.82
420.1444702	0.10
429.1678467	0.14
431.2178955	0.20
436.9756470	0.09
441.0541382	0.03
447.2669678	1.95
448.1209717	0.13
458.5648193	0.04
459.1982422	0.08
465.1251831	12.33
465.7736206	0.07
477.1974487	0.35
486.3147583	0.07
488.0724487	0.07
504.1517944	0.79
505.8533936	0.06
522.1525879	7.28
523.1795044	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	232.98
Annotation	Alcalinaphenol D
Peak:m/z	Relative Intensity
85.9453278	0.08
96.8244629	0.03
98.9491882	0.05
108.6544037	0.05
117.1295166	0.02
120.8674011	0.03
122.8766174	0.06
132.9206238	0.05
135.0019836	0.12
137.0032349	0.02
138.8582916	0.02
140.7767181	0.02
143.2794037	0.02
147.1393890	0.12
147.9033813	0.09
149.1389618	0.02
155.1890717	0.06
156.9630585	0.15
157.8030853	0.03
159.1325836	0.04
163.0483246	0.12
167.0385132	0.01
170.8169098	0.14
173.2104034	0.08
174.2065735	0.03
176.9431763	2.26
178.9030304	0.03
183.0442200	0.02
187.0661926	0.30
188.9898682	0.10
190.0894012	0.07
191.7947235	100.00
193.0016632	0.14
194.9313202	1.77
196.7774353	0.06
201.1258087	0.17
203.0581207	0.09
203.6937408	0.09
205.1245575	0.33
209.8181915	12.40
212.4540253	0.02
215.1099396	1.96
216.1560822	0.02
217.9097137	12.36
232.8302155	0.18
234.2072906	0.04
235.2197266	0.08
240.6931915	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.02106476	0.29
81.08535767	1.56
82.89378357	0.47
84.94871521	0.86
89.04549408	0.26
90.89094543	0.80
93.13576508	1.84
95.00543213	3.02
96.97134399	0.96
99.10005188	0.87
99.91273499	0.21
103.0373993	2.42
104.8764496	2.08
107.1473541	0.41
109.024765	1.67
111.0842896	0.48
112.8533478	0.45
118.900116	0.54
120.8865204	1.26
123.0455322	2.17
125.0744781	0.73
126.914917	0.39
128.1784058	0.16
128.9288788	5.27
129.9661865	0.26
133.0382385	3.73
134.9679565	2.10
136.9193268	1.69
139.1537933	0.99
140.9596558	1.04
146.9278259	1.78
149.0076904	0.88
150.9825287	66.24
152.0657501	5.36
153.0843964	1.03
154.2153931	0.17
154.9942627	0.72
157.2064209	1.08
159.1197052	0.29
161.1888428	1.51
162.9243774	0.33
165.2654572	0.62
166.0430756	0.21
167.0640259	2.22
169.143158	3.23
170.9796448	0.69
173.2787323	0.20
175.2352142	0.86
176.9585114	1.24
177.8979492	0.59
179.083847	4.64
179.9651337	0.78
181.7463226	0.41
183.2900848	0.33
184.0894928	0.25
185.0102997	0.89
191.2058868	0.32
193.2577362	0.20
194.9292297	2.14
197.0459595	3.14
198.5005188	1.20
199.1868744	1.47
207.1178131	0.88
208.1993408	0.25
208.9878387	1.36
210.1799774	0.31
211.2360992	1.64
211.9545135	0.15
217.1333771	8.01
221.0020447	0.35
223.9547882	0.23
225.1463776	9.22
226.100235	1.76
229.0149078	0.25
235.0838776	13.38
236.1128998	0.46
238.0541229	10.66
239.3280487	0.83
244.1557159	0.59
250.9828339	0.53
251.8199615	0.13
253.0937347	100.00
254.2014923	17.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.7019043	0.05
259.0511475	0.03
293.2905884	0.03
298.0836792	0.02
302.9515991	0.71
319.2282715	0.01
373.3039551	0.01
382.8144531	0.03
384.5544434	0.43
386.8039551	4.22
417.4666138	0.06
421.0151367	0.03
465.1400146	0.03
468.5423584	0.15
470.6773682	43.33
471.3351440	0.07
482.8752441	0.03
540.4429321	0.01
551.9478149	0.44
552.6254272	0.45
554.5194092	100.00
555.2532959	0.08
592.8952026	0.05
604.3217163	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9198
Annotation	Unknow
Peak:m/z	Relative Intensity
154.6565704	0.11
159.0843048	2.92
175.0332947	0.10
199.0219269	0.99
217.1780853	0.05
228.8551636	0.95
244.9314423	0.08
270.9161987	0.13
272.9686279	51.55
384.6530762	0.12
386.9008789	100.00
387.5101013	0.37
426.9351196	0.08
457.4604187	0.23
482.4250183	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1716
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1014328	0.11
110.0607605	0.13
111.1108856	0.12
113.9387131	1.17
115.1591339	0.07
120.9114532	0.19
124.1356964	0.07
125.0328293	0.05
130.9901733	0.52
136.0921631	0.07
138.1453705	0.16
149.8724976	0.08
151.1668091	0.14
153.0235138	0.57
162.0759430	0.06
163.9953308	0.17
165.1778564	0.52
176.0652466	0.11
176.9701233	0.15
179.0491028	0.11
191.2732239	0.05
195.0757141	0.23
201.1311646	3.13
203.1965179	0.25
204.2322388	0.21
205.2434387	0.69
206.0451202	0.05
207.0475922	0.30
215.1687164	0.25
219.2030945	4.47
220.0473633	0.06
222.9708862	0.10
229.2282104	0.43
235.0895996	0.05
244.1062622	10.35
245.1156311	1.69
246.9053345	0.29
251.0654602	0.08
262.2160034	9.85
263.1465454	0.06
272.7846680	0.39
275.2259521	0.13
278.2551270	0.08
281.2121582	0.20
282.3392944	0.26
285.0079346	0.12
287.1497803	0.11
288.2221069	0.18
289.2448425	0.08
289.9186707	0.04
298.4248657	0.21
304.9845581	0.46
306.9427490	0.10
313.0639038	0.40
315.2610474	0.74
316.2453613	0.35
317.3416138	0.28
318.2050171	1.09
323.1275024	0.49
330.9743042	0.80
331.5953064	0.29
333.2702026	5.20
339.7442627	0.18
341.0709229	1.89
341.9688110	0.15
343.1465149	0.06
357.3212891	0.19
359.2197571	100.00
360.0719604	0.20
361.4620056	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
72.82485962	0.15
78.62254333	0.25
81.07505798	0.58
82.96270752	0.33
85.06427765	0.17
90.91270447	0.75
92.88995361	0.57
95.02107239	2.97
96.79663849	1.27
98.59698486	0.61
102.9444275	0.43
104.1419067	0.27
105.0850677	1.68
107.0289612	1.69
109.0110321	3.47
110.7862091	0.45
113.2302704	0.54
114.9194336	0.49
116.9513245	1.22
119.0371399	1.80
120.0977783	0.30
121.0484772	0.87
122.9313354	1.67
125.1208344	0.29
126.8595734	0.72
128.9724121	5.16
129.884613	0.62
131.0480194	0.15
133.0708313	1.40
134.9415436	2.10
137.3289185	1.02
141.0006866	3.41
142.8266144	0.14
145.0006104	0.45
147.0890503	1.50
149.2996674	0.35
150.9676361	56.47
151.9852448	5.33
153.0185394	1.11
154.9100494	1.87
156.8613434	0.79
161.17659	1.24
163.0408783	0.24
164.9737549	2.57
167.0778503	0.75
168.6939545	3.00
169.3460083	0.13
171.0673523	2.24
173.1326752	0.19
175.161087	2.05
177.1446991	1.78
178.0339661	0.88
179.0331268	3.06
181.9809265	0.94
182.9633484	0.69
185.1522369	2.09
186.7313385	0.35
189.1994019	0.83
191.1351013	0.29
192.6302032	1.01
193.3800201	0.18
194.1857758	1.27
195.0772552	3.30
197.1503296	5.12
198.3326721	0.92
198.9774323	0.17
207.1444855	4.31
208.279007	0.27
209.1523743	1.53
210.9070129	3.79
211.5145721	0.20
217.1369781	9.80
223.1171875	0.17
225.156723	10.77
225.8890228	0.39
232.8777008	0.20
235.1838531	23.67
235.991333	0.17
238.0917511	6.19
239.1609955	1.05
243.5430756	0.60
251.1671295	0.21
253.0775146	100.00
254.12883	14.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.1591
Annotation	(+)-Validoxylamine G
Peak:m/z	Relative Intensity
104.9237595	7.29
106.9512329	0.16
111.0196762	0.26
116.8550034	0.28
118.2837296	0.06
118.9797974	0.10
121.1047134	0.06
122.9584503	0.42
125.0597229	0.29
126.9103851	1.96
128.7005920	0.06
141.1354065	0.12
143.3157043	0.06
144.9202728	0.78
147.3719788	0.09
153.1719971	1.11
158.9895020	0.51
160.8793335	0.31
163.0950317	0.29
164.1341858	0.10
165.1396484	0.22
172.7272949	0.18
173.4297791	0.12
176.0325775	0.16
177.1067505	0.92
178.2666626	0.06
182.8849640	0.14
184.0187988	0.05
185.0405273	0.16
188.5634613	0.05
190.9819336	0.23
195.0581207	6.14
197.2427979	0.06
200.4404297	0.16
205.1823425	0.10
211.2402954	0.16
212.2672424	0.06
213.0630798	0.51
215.1637878	0.13
217.2895508	0.04
221.1617737	0.22
228.9476013	0.15
230.9833984	10.23
234.1757507	0.12
240.8734131	0.10
246.2888489	0.20
248.9652710	100.00
250.9297180	0.05
251.9750977	0.22
253.3551636	0.05
255.1320496	0.40
261.2053223	0.08
262.0359497	0.37
263.0736389	0.28
266.3818359	2.16
267.1276245	0.79
269.1476440	0.25
270.5870972	0.17
273.2244873	0.10
275.2063904	0.08
276.9949341	0.28
281.0391235	2.35
284.0943604	9.49
285.2990112	0.06
286.2801819	0.04
287.2731628	0.11
288.9112549	0.08
290.0434265	0.36
292.8536072	0.29
294.2467041	0.26
299.0727539	7.49
303.3190918	0.17
306.1261597	0.18
307.4047546	0.24
308.0904541	0.18
310.9676819	1.62
316.9701233	4.39
317.6729126	0.02
319.7855225	0.12
321.4436035	0.17
324.2990417	0.20
328.9884644	0.05
334.0062561	2.31
334.9967651	1.05
335.6827698	0.29
342.9304810	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.65
Annotation	Unknow
Peak:m/z	Relative Intensity
207.0055695	0.37
290.7956543	4.47
374.6209106	2.43
406.8065186	0.05
458.6203613	24.65
460.9003906	0.03
472.7802124	0.07
537.2103882	0.21
542.5559692	100.00
580.6268921	0.08
618.9507446	0.05
624.0201416	0.16
625.9303589	2.57
626.5828247	21.07
663.6532593	0.25
689.5090332	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.18
Annotation	Dichotosin
Peak:m/z	Relative Intensity
171.1213379	0.06
185.1159668	0.86
189.0604858	0.23
192.9682617	0.04
197.3577881	0.11
252.5346069	0.08
253.30896	0.39
254.9293823	0.08
268.9015503	0.32
285.049469	0.08
287.1240234	100.00
288.303009	0.55
297.1801758	0.15
306.4434814	0.25
311.134552	0.26
314.7241211	0.07
322.5066223	0.05
332.3932495	0.07
340.958252	0.27
342.3473206	0.05
343.1739807	0.04
345.2084656	0.07
347.2271729	0.10
354.3818665	0.15
359.3856812	0.05
363.0618286	0.06
368.1228027	0.07
375.3650208	0.11
377.3939514	0.17
383.0522766	0.03
386.2241821	0.06
389.2648315	0.03
403.2222595	2.89
408.5069885	0.23
413.1520081	0.37
421.3102722	0.46
431.1842957	1.40
434.2609253	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	2859-88-3
Peak:m/z	Relative Intensity
83.01309204	0.54
97.10455322	0.50
101.0329742	0.50
110.041626	0.36
115.0154877	0.55
125.0296631	1.09
138.155365	0.50
139.1704865	0.62
142.9228058	0.40
161.0997772	1.45
177.3860931	2.02
179.3527832	0.33
180.2864685	1.71
183.0605469	3.63
188.9230652	0.74
191.2654419	0.43
194.4437866	1.02
195.3469238	1.78
197.2323761	0.89
207.0274506	5.56
207.9793243	5.85
209.169632	3.75
222.1678925	0.36
223.0960846	5.59
233.239151	4.35
234.9157104	0.47
251.0619507	100.00
252.1331787	11.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
74.77140808	0.28
82.66654205	0.36
85.10831451	0.29
95.8656311	0.21
96.92967224	0.52
98.96795654	0.34
100.7723389	1.88
149.1230774	0.95
149.8280945	0.21
169.1650085	0.27
177.0766296	0.26
177.8009491	0.59
179.1889191	0.99
180.2424774	0.65
181.1256104	0.57
183.014389	0.84
195.2050781	0.41
197.2041168	0.37
205.0596619	0.68
206.0107422	0.95
207.0825958	2.62
208.2476959	2.31
209.1491852	0.80
222.1035919	1.67
223.0573883	3.90
231.1229248	0.61
233.1393585	3.81
235.1063843	0.66
235.9246826	0.56
251.0716553	100.00
252.1458893	19.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.1283
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1365967	0.33
166.2175446	0.09
166.9261627	0.16
169.0455475	0.19
170.9950867	0.78
172.1703949	0.06
177.2557373	0.07
178.5071716	0.19
179.1171112	1.16
185.0922546	0.63
193.0891724	0.12
196.3908539	0.12
197.1439667	1.55
198.0979004	0.12
210.0825806	1.07
211.0303650	0.10
212.9998779	0.74
219.2366180	0.12
226.2553711	0.06
226.9709320	0.07
228.3244476	0.06
231.1362610	3.08
236.0754395	0.74
238.1166992	0.10
239.1015778	0.18
244.3215485	0.06
246.8789825	0.07
248.3601990	0.17
248.9673157	0.51
252.1948853	0.24
254.0878296	10.39
256.0287781	0.07
259.9599304	0.06
266.2111816	0.90
270.2045898	0.23
271.1584473	0.07
272.0407410	0.71
274.0977478	0.13
279.2744751	0.69
280.2367554	0.29
286.1728516	0.17
288.1185303	16.54
290.4046021	0.10
295.3656616	0.11
297.2971191	0.08
304.2263794	0.09
306.0723267	7.82
308.1270142	0.10
313.1794434	0.83
317.9838867	0.06
321.3005371	0.36
322.6970215	1.15
323.3214722	2.85
326.0208740	0.66
329.3059692	0.20
330.9793091	0.26
339.2849731	0.09
341.2021484	1.38
342.3565674	0.29
344.2667236	0.14
346.0566406	0.24
347.5129395	0.28
351.1941528	0.26
357.1904907	4.36
358.2517090	0.07
359.5571289	0.39
360.2984009	0.58
364.3372192	0.72
365.2752075	1.36
367.1181641	0.38
375.1380615	20.73
375.8135986	0.37
377.2970581	0.58
378.3043823	2.24
382.3688354	0.64
383.2141113	1.30
385.1787720	0.48
390.2776489	1.63
391.1395264	1.42
392.2289429	0.75
393.0386353	0.08
398.2344360	0.29
399.1289673	1.16
403.0593262	0.28
404.4436646	0.14
407.0950928	0.06
408.2238159	3.76
409.2563477	20.13
411.1948242	0.19
413.6265259	0.06
416.1828613	2.01
417.2008057	8.26
421.9881592	0.15
424.2441406	1.71
426.3543701	1.13
429.1478882	3.71
434.2580566	2.56
435.1857300	0.10
442.2192993	16.02
443.0120239	0.19
446.8461914	0.04
450.1665649	0.26
452.3078613	6.13
456.2037964	0.37
460.3538818	5.55
463.2210693	0.12
468.2058716	9.00
469.0817871	0.13
470.3081665	3.01
472.6123657	0.29
474.3826294	0.19
476.1964111	0.12
477.1696167	0.06
486.1932373	95.38
487.0968628	0.17
488.9263306	0.45
492.2408447	0.22
494.2575073	0.35
502.2626953	4.47
504.2731323	100.00
520.1686401	69.75
521.2614136	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.86372375	0.43
80.83102417	1.10
82.77294159	0.68
91.00367737	0.84
92.91845703	0.49
94.86727905	0.52
97.12304688	1.06
99.00727844	1.66
101.9715424	0.08
102.9430084	1.65
105.0116882	1.25
108.8622437	1.77
111.0059509	0.61
116.9401093	0.79
119.0244293	2.04
121.0062408	1.47
123.0543365	1.67
126.8144379	0.38
128.9976044	2.87
130.0928497	0.43
131.1429596	1.47
133.1619873	0.32
135.2115784	1.77
136.9297943	0.49
139.1240082	0.96
141.0068207	2.20
145.0554962	0.74
147.0010529	1.32
149.0805054	0.67
150.976059	49.93
151.8951874	4.30
152.9870453	1.50
153.956665	0.35
155.0478973	1.67
157.136322	1.18
159.14888	0.12
161.0926056	1.30
162.8620453	1.47
165.9009094	0.67
167.0232697	1.37
168.975769	2.49
170.1828461	0.25
171.147995	1.26
171.8716431	0.19
173.031601	0.16
175.1089325	1.10
177.1132355	1.33
179.0328522	2.37
180.1139679	0.79
182.1322937	0.16
183.0625	0.41
184.0713959	0.50
185.2259064	0.38
186.1918793	1.04
189.0453949	0.96
191.0755463	0.91
193.1848907	2.33
195.1204376	3.01
197.1352386	6.34
202.0128479	0.49
203.0650787	0.27
207.1318207	3.28
209.0771637	1.87
210.0245209	0.16
211.1586761	1.75
211.9425507	1.01
215.2376251	0.57
217.2102509	10.14
223.2923889	0.38
225.0883179	6.31
235.1277618	22.66
236.1392975	0.75
238.1508789	8.45
239.0969849	2.10
241.562561	0.17
244.1222076	1.13
248.4734344	0.26
251.1256256	0.18
253.0938263	100.00
254.2007904	20.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.76
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7729187	0.88
214.3655090	0.17
215.0023193	0.40
294.8452148	0.14
296.8085938	15.96
298.1461182	2.00
298.8664856	13.23
323.2102661	0.10
378.1061401	0.03
380.6190796	38.08
382.0393066	10.58
382.6617432	68.82
383.3375854	0.08
442.0250244	0.15
464.4859009	21.71
465.9517822	18.30
466.5632935	100.00
467.2590332	0.13
532.9462891	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1606
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
124.9410400	0.01
135.2119751	0.02
137.3519135	0.02
147.0549316	0.04
151.0338898	0.05
152.8477936	0.05
157.0342407	0.02
161.0475769	0.18
163.0211487	0.01
179.2194366	0.17
181.1507263	0.65
195.1200256	0.03
197.1071777	15.86
197.7306824	0.03
199.2056885	0.03
203.3133240	0.01
221.1879578	0.05
223.1456909	0.49
234.9757080	0.03
239.2832642	0.02
239.8908997	0.06
241.0665588	100.00
241.8565369	0.02
247.2100830	0.06
255.3574829	0.05
265.1451721	0.48
266.9074707	0.02
277.1060181	0.04
279.3907471	0.06
283.1664124	0.86
286.9623413	0.02
295.2044067	0.07
297.0642700	0.01
299.2839966	0.03
306.9066162	0.11
308.9236450	0.05
311.1376343	0.09
313.1551208	0.95
321.2819214	0.02
325.0036621	0.06
327.1876831	0.02
334.8988953	0.02
341.3695984	0.01
343.1133423	1.92
357.1744080	0.13
358.4057922	0.02
359.2229919	0.07
367.1670227	0.12
373.1023254	0.09
384.7041626	0.06
385.3157959	0.32
388.2789917	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9475555	0.07
160.9646759	0.90
179.0049133	100.00
191.0972290	0.37
299.1539917	0.10
315.2245483	0.13
327.3150635	0.06
329.1118164	0.08
341.2450562	5.43
385.3012085	0.21
394.8742676	0.07
432.8118286	0.13
445.0542603	0.14
446.4003296	0.10
457.1804199	0.08
485.1406250	0.72
486.4922485	0.15
504.4666138	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.19
Annotation	Testolate
Peak:m/z	Relative Intensity
92.86862183	0.15
125.0991898	0.16
140.957489	0.49
151.1794128	0.09
156.8945312	0.12
163.1773224	0.80
183.0345306	0.22
185.0402985	0.20
193.2828217	0.21
207.0618286	1.09
213.1101685	0.20
223.0375366	0.50
224.770813	0.10
226.0571594	0.15
237.1895142	0.24
239.2402649	0.11
240.1131592	0.28
241.2066956	14.52
245.1200867	0.47
257.24646	15.23
259.0967407	1.27
261.5282898	0.22
267.4053345	0.22
273.1235657	0.99
275.5396423	0.97
283.2539978	14.39
285.2974243	0.59
291.1849976	0.40
299.3793945	0.33
301.1904297	100.00
302.3147583	0.90
303.1123047	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.12
Annotation	Amotin
Peak:m/z	Relative Intensity
85.00110626	0.22
95.07622528	0.06
96.76329803	0.04
105.1512222	0.11
109.1595917	0.07
111.0646362	0.82
112.8988266	0.42
121.0225525	0.18
123.2329941	0.12
123.954483	0.09
125.1128616	0.08
132.9240875	0.59
137.0452576	0.70
138.0295105	0.09
139.1219482	0.31
149.1061096	0.30
157.0252228	0.20
163.1618958	0.82
165.223114	0.48
171.1143646	1.07
178.9877472	0.32
183.0083923	0.49
185.1897583	0.10
189.1535339	14.18
193.0507965	0.03
195.0641174	0.09
197.3127747	0.12
198.9279175	0.07
203.0996094	0.37
204.8917847	0.10
207.1582642	1.93
209.0436401	0.06
210.9277344	0.08
212.0884094	0.11
212.9173889	0.21
215.0869751	0.45
217.1798096	0.08
220.9952698	0.21
222.9814758	0.08
231.2031555	0.19
233.1674805	1.13
233.9291077	0.02
237.1736755	0.23
238.9409485	0.06
249.2190247	1.54
251.1326904	100.00
259.0951233	0.14
260.065094	0.05
265.2773132	0.17
267.1992493	0.05
268.1398315	0.05
277.1758423	0.55
280.0377197	0.19
281.149292	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.8994
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0178986	0.08
199.9984131	0.03
229.0373535	0.04
273.0562134	5.50
274.0027466	1.04
274.9437256	3.74
275.9160461	0.05
305.1274414	0.06
305.9726868	0.04
386.9692383	7.42
388.1886597	4.08
388.9204712	11.89
403.1196289	0.03
426.9236450	0.06
486.9943237	0.04
499.1382446	0.19
500.8947144	19.34
502.7969971	100.00
503.5098267	0.33
515.0846558	0.03
525.1625366	0.03
532.8163452	0.02
543.0886230	0.34
544.8352661	0.17
547.8928223	0.16
560.8290405	0.04
561.6346436	0.13
570.9485474	0.82
572.9592896	0.94
585.0690308	0.16
588.8063354	0.23
599.0275269	0.49
617.0537720	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	257.19
Annotation	3-Deoxyestradiol
Peak:m/z	Relative Intensity
74.9259491	0.36
76.92626953	18.07
79.09610748	0.08
81.04091644	1.82
81.84327698	0.06
82.89614868	2.19
86.8999176	0.14
88.82225037	0.05
90.95149231	0.07
95.0382843	2.47
96.96427155	2.66
100.9277649	0.59
105.0053558	0.62
108.9717407	3.23
110.8852081	1.79
113.2357635	0.04
114.9059906	1.52
116.9946289	0.12
118.9364014	0.56
121.121582	0.47
122.9822693	4.17
124.9103088	0.07
126.8868713	0.33
128.999588	8.42
130.9827118	0.71
132.890274	0.73
137.0595093	0.22
138.1070557	0.03
139.0432129	0.46
141.0298767	1.46
142.953125	13.95
145.0036163	0.17
146.9148407	1.55
151.0988007	0.69
154.9933319	3.19
156.9442749	7.88
159.0846405	1.09
161.0358734	2.22
163.053421	0.18
165.2786865	0.12
169.0649414	1.83
171.1564484	0.42
172.3470001	0.28
173.0793915	0.64
175.0731049	1.06
177.1551361	0.20
179.169342	9.15
183.1407776	0.65
183.93367	0.05
187.350174	0.40
193.1432343	0.35
196.4236603	0.29
197.145462	1.40
199.0320587	0.62
201.2089386	0.13
203.13591	0.24
208.9980621	0.12
211.2086029	3.39
212.9964752	0.10
214.3348236	0.22
215.0064087	0.39
216.0747528	0.20
219.7212677	0.28
221.197876	4.30
227.2094269	0.06
228.8435059	1.12
230.3144836	0.19
233.7427521	0.25
239.1741943	100.00
242.017746	0.21
243.1018524	0.08
248.7352142	0.03
257.1357117	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
116.9610748	0.13
120.8942413	0.13
141.2128448	0.16
148.8845825	0.22
155.1271057	0.15
164.2120972	0.08
165.3951874	0.20
169.0263824	0.36
174.2802429	0.27
178.4134674	0.19
179.0905151	0.18
180.9749146	0.10
187.0495148	0.08
193.7371521	0.43
195.2067871	0.22
204.9317627	0.61
206.1284027	0.51
207.0997009	4.18
208.1589203	1.87
209.0629883	0.77
210.2179413	0.12
221.0023956	0.17
222.0336609	1.95
223.0471344	2.58
224.1044006	0.75
233.2314301	0.36
251.0650482	100.00
252.1339874	18.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.1947
Annotation	ACS 67
Peak:m/z	Relative Intensity
193.276825	0.83
195.1602478	0.61
264.8851013	0.20
273.2553101	0.84
299.1750488	0.54
344.1810913	0.45
355.1937256	0.39
369.8734131	0.27
404.2498169	0.84
407.0994873	0.29
419.0136108	0.27
431.2667236	0.91
433.4866943	0.40
436.9694824	0.82
443.180481	1.00
449.25	0.91
450.3004761	0.65
452.430481	0.20
461.0809326	11.71
467.2384033	0.49
477.2753906	0.99
479.1716309	3.43
481.0655518	0.31
485.2539062	3.78
492.6004028	0.83
509.1936646	0.57
515.1488037	3.71
527.1489258	11.40
527.7558594	0.09
533.2019653	1.16
538.2786255	1.47
540.3461914	0.90
545.2476196	9.84
561.2942505	0.47
563.157959	91.66
563.9317627	0.34
569.2518311	0.81
576.8699951	0.55
581.1732178	100.00
582.6426392	0.75
583.7080688	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1763
Annotation	Prinsepiol 4-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
163.0460205	0.36
165.0400696	1.98
178.0266876	0.18
191.1288452	1.28
193.0257874	10.43
195.1763611	1.98
209.147522	1.26
210.9224091	0.42
245.126709	0.22
299.0932617	0.27
300.8507996	0.47
315.2616577	0.30
322.0079956	0.35
327.0462036	2.28
329.2451172	1.92
341.1266479	10.63
344.1780396	0.24
359.2636719	1.22
371.1502075	1.31
375.2332153	0.47
389.1290894	100.00
397.302124	0.46
430.7861328	0.34
443.0706177	0.56
447.1911011	0.64
449.7160034	1.19
456.1143799	0.42
461.0709229	2.85
463.3677979	0.62
474.7414551	0.49
485.3233032	0.38
488.9050293	1.50
491.0678101	6.80
505.2164307	3.14
506.4942017	1.03
507.3322144	0.56
510.9094849	0.56
519.3192749	1.29
533.0514526	2.02
548.7874146	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8117676	2.32
296.7783203	23.62
302.8577271	0.17
323.1516113	0.21
378.9228516	0.22
380.6914673	80.49
461.5000610	0.22
462.1062012	0.04
464.4989014	100.00
465.3584595	0.11
476.4721680	0.06
530.5892944	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.1414
Annotation	Unknow
Peak:m/z	Relative Intensity
154.1376953	0.05
155.0019073	0.06
161.9937134	1.01
170.1619415	0.05
178.9872284	2.97
187.0318146	0.50
188.0512695	0.06
189.8614502	0.15
199.0614319	0.04
204.7765198	0.07
206.9377594	0.29
215.0960999	0.87
216.1012573	0.18
222.3235016	0.03
227.1550140	0.03
232.9755096	4.13
240.4040833	0.05
243.1943970	0.09
245.3290405	0.04
247.1929474	0.06
251.0240936	0.04
257.0767822	0.14
271.8493042	0.29
272.9501343	0.10
274.2339478	0.10
284.1963501	0.50
290.2138672	0.33
290.9729614	0.27
300.3242188	0.20
301.1890259	0.41
302.3771362	0.15
308.0986938	10.95
312.1490479	0.03
318.1079102	2.99
319.0761108	1.70
326.5302124	0.13
329.9803467	0.06
334.0720825	0.26
336.0802612	36.63
336.6849365	0.12
341.1300049	0.19
344.1821899	0.84
359.3977661	0.06
362.0957031	0.85
375.2460327	0.99
376.1997681	0.02
377.8889771	0.13
384.1109619	0.15
390.3283691	0.07
393.2053223	4.16
394.0830688	0.20
395.0993042	0.09
396.2540894	0.03
402.2146606	1.20
408.2458496	0.03
411.1119995	100.00
413.2546997	1.03
419.4698486	0.09
428.6450806	0.06
429.2891235	0.20
430.1916504	0.05
431.1981201	0.16
437.2388916	0.03
447.2371826	2.33
448.2485962	0.09
459.2012329	0.06
465.1911011	14.78
470.6223145	0.04
477.1535645	0.51
488.3076782	0.03
494.3269653	0.02
504.1371460	1.03
506.2765503	0.22
515.6204224	0.07
522.1598511	8.33
523.2756348	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1189
Annotation	Grevilloside E
Peak:m/z	Relative Intensity
115.1779861	0.44
118.9670944	1.05
123.2539825	0.18
130.9419556	0.41
135.0170593	0.23
142.9173584	1.43
150.953949	0.62
153.0545349	0.82
156.9469604	0.41
159.1771545	0.33
160.8960266	1.27
162.0477295	6.43
175.1174469	0.18
177.086792	69.52
178.9969788	4.57
180.003067	0.39
190.8141479	0.29
193.0823975	1.22
195.0742035	100.00
211.2525787	0.41
213.1591187	0.34
219.1477661	0.42
224.9525146	0.38
235.0483093	0.56
247.2168579	0.21
253.3758545	0.32
267.0461121	0.56
269.039856	1.26
271.2323608	0.38
281.1975708	0.94
283.3445435	0.32
285.2153015	0.28
294.9428101	1.03
311.0781555	6.54
312.3121338	0.46
313.196106	0.99
319.1206665	0.49
327.3200073	0.50
329.3375244	0.21
337.1009216	0.16
339.0336304	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.3113
Annotation	neriifolin
Peak:m/z	Relative Intensity
234.9949036	0.15
277.3744507	0.19
318.0314331	0.07
353.3365479	0.30
355.4147949	0.34
357.1431274	0.53
371.3867798	0.16
373.5448608	0.12
379.4071045	0.13
383.4413452	0.07
387.3892822	0.10
395.4603882	0.62
403.5187378	0.18
405.1646118	0.12
407.2946777	0.71
412.8813477	0.10
415.5857544	0.11
416.5635376	0.21
417.2740479	0.04
421.4699707	0.06
423.8306274	0.41
425.4281616	0.43
426.4625854	0.10
427.5043335	0.25
433.3860474	0.15
437.3346558	0.05
437.9705200	0.05
439.3182373	1.27
441.3696289	0.15
443.4686890	5.31
444.4020386	0.25
445.4824219	0.23
451.2366943	0.15
453.4246216	0.66
460.5114136	0.06
461.4916382	6.10
462.4316406	0.23
465.1361084	0.06
469.6946411	0.20
471.4004517	18.37
472.3216553	0.38
473.4387817	0.23
479.1929932	0.14
487.3007202	0.45
489.4270020	100.00
490.4356079	2.82
491.5478516	0.08
497.1228638	0.05
497.7681885	0.09
503.5249634	0.16
505.7005615	0.15
514.3036499	0.15
515.3496704	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	492.1909
Annotation	Unknow
Peak:m/z	Relative Intensity
144.7039948	0.06
147.9445343	100.00
149.0614014	0.29
162.9795837	0.11
165.1076355	2.78
178.9692993	4.73
182.9694061	24.64
196.9011536	1.22
242.3537292	0.53
261.2330933	0.16
266.3820496	0.06
270.3964844	0.12
291.9633484	0.06
294.7716980	0.55
295.8285217	0.12
296.4927979	0.92
297.5692444	0.15
298.5546265	0.05
309.5706787	0.67
310.2180176	0.96
322.9890442	0.39
329.4513550	0.84
330.1507263	1.12
330.9989929	0.05
339.0026245	0.09
341.0083618	7.29
342.9635620	0.04
344.3366089	2.32
344.9896851	2.74
358.8790283	2.96
371.8843994	0.09
384.6272583	0.07
394.2849426	0.15
398.1932068	0.10
439.2810059	0.13
457.0721741	0.16
474.1098938	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	4'-METHOXYFLAVONE
Peak:m/z	Relative Intensity
74.9079361	0.23
76.96865082	0.25
78.72412872	0.12
80.99047089	0.34
83.11440277	1.10
84.89308929	0.29
91.04943848	0.34
92.83555603	0.35
94.99172974	1.31
96.99316406	1.70
98.88075256	0.22
102.9970398	3.44
104.9897461	1.69
106.9745789	0.87
108.9979858	0.99
111.0211639	1.63
113.0029449	1.20
114.7384949	1.66
119.1165466	0.48
121.0344086	4.10
123.0591583	3.05
123.94664	0.15
125.0046539	0.46
126.9943695	2.33
127.9367523	0.21
129.0497131	7.97
130.0994568	0.46
131.0797119	0.92
133.0484467	2.08
134.085495	0.49
135.0478973	2.06
137.3062744	1.49
138.726059	0.66
141.0116577	2.28
145.0074768	0.63
147.0315552	2.14
150.955246	68.16
152.0066833	4.80
152.9501953	2.74
154.874588	1.61
156.8913879	1.18
160.8770294	0.67
163.0463562	0.67
165.2527161	1.77
167.2769318	0.35
168.3029938	0.96
169.1819305	4.09
171.0181274	0.80
172.8768005	0.55
174.9763336	2.87
177.0363617	0.29
178.9568634	1.74
182.0259552	2.00
183.1066132	1.22
185.2476959	1.38
185.9705811	0.47
189.1363068	1.16
192.9842224	2.13
194.2897491	1.82
195.1848907	2.39
197.2384949	8.42
198.1399078	0.38
199.0961609	2.88
207.3075714	3.40
208.0148773	1.07
209.3022308	0.75
210.5716858	0.42
211.1768646	4.71
217.1607819	12.61
222.8723297	0.12
225.1219177	7.99
225.8114624	0.54
233.5027008	0.39
235.1783905	25.79
238.05896	10.69
239.1205444	0.72
244.1996002	0.76
253.0920868	100.00
254.1615753	16.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1297
Annotation	Unknow
Peak:m/z	Relative Intensity
162.1837769	0.02
219.2083130	0.03
252.9075623	0.37
341.0807190	0.12
343.1885071	100.00
371.0858459	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1034
Annotation	Ala-Phe-OH
Peak:m/z	Relative Intensity
113.1821518	0.11
121.0465393	0.20
125.9770966	0.14
128.030365	0.29
138.9504852	0.40
141.0518341	0.17
161.1006622	0.57
163.2275085	0.36
165.0214233	0.44
180.8062134	0.16
183.2790222	0.14
198.9421387	1.75
203.0696259	0.31
204.0758667	0.66
211.0942535	0.18
222.9421387	0.50
224.1265564	0.25
225.1358643	0.85
236.0572815	0.18
249.2258301	0.48
253.1998901	0.41
255.0545654	0.17
257.1031189	0.41
277.3161011	0.25
281.1447754	3.08
284.2902832	0.28
285.2084045	2.38
291.2499084	0.32
299.1060791	100.00
301.0300903	1.75
307.991272	0.35
309.209137	3.60
311.2127075	0.97
326.798645	1.49
327.4405212	0.23
328.2687073	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
106.8078918	0.15
129.9563751	0.41
134.9807281	0.31
153.066925	0.12
156.9026489	0.74
169.0569458	0.20
171.1695099	2.50
172.9885559	0.61
185.032959	2.06
187.2333069	0.92
188.6913147	0.17
189.4425354	0.21
199.1713562	0.93
199.9694061	0.18
201.0970764	2.73
203.0498505	0.29
213.1014709	2.88
215.1836243	2.41
216.7644653	1.11
217.528595	0.47
227.3579712	1.74
229.098877	2.55
231.2743835	0.75
241.1894531	2.17
243.1954041	2.78
245.1116028	1.13
245.777771	0.13
255.3081055	2.63
257.2350464	4.82
259.1973572	1.10
261.3695679	0.24
263.2773132	0.93
269.2423706	1.91
271.2738647	4.17
273.1950684	1.36
283.2931519	3.13
285.2239075	8.64
287.5293274	0.79
297.1933899	0.68
299.2515869	5.24
301.4544983	3.11
311.2746582	1.28
312.1686401	0.15
313.3979797	1.89
315.187561	1.51
321.0869141	1.66
323.3407288	12.73
325.24823	1.30
327.5246582	1.53
329.2077942	0.30
337.4156494	1.13
339.2550049	100.00
340.1169434	0.18
341.249176	21.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.2678
Annotation	(9Z,12Z)-Octadeca-9,12-dien-1-ol
Peak:m/z	Relative Intensity
76.90914917	0.11
78.96502686	2.58
80.9695282	9.22
82.96456909	25.01
85.02128601	1.38
86.88131714	0.13
90.71193695	0.17
92.79954529	1.19
94.97822571	38.42
95.89729309	0.44
97.04968262	28.20
99.05930328	1.36
101.1521912	0.26
103.1724854	0.66
105.0133667	0.28
108.9494171	34.54
111.0395203	20.56
111.9910583	0.15
113.0510406	0.08
115.1047058	0.34
121.0178375	0.72
122.9807587	25.78
125.0978851	5.11
126.7736969	0.52
129.1141663	1.10
133.1008453	1.37
135.2242889	1.15
136.0006409	0.22
137.1608887	15.84
138.8253479	1.49
140.9808807	0.06
143.0051727	0.87
146.9665833	0.55
148.9976196	0.46
151.0812073	13.98
152.9550018	6.07
154.9378815	1.09
157.0142059	0.91
161.2073669	0.30
165.1262054	13.66
166.6690216	1.76
167.2855682	0.50
167.9967499	0.44
169.0621185	0.85
171.1344299	4.20
172.9883881	0.07
179.1996307	9.26
181.2877197	0.29
183.0383301	0.20
185.1045074	6.11
189.2305145	0.43
193.0876923	7.03
194.0479736	0.26
195.4016876	0.08
197.0507965	0.29
199.298172	0.15
202.6649323	0.08
205.3054657	0.14
207.0811768	1.15
211.1661224	0.35
220.9337616	0.93
223.1364288	0.55
225.3779449	1.27
226.2915192	0.19
227.1969147	0.13
231.1663818	1.29
237.335495	0.18
239.0556488	0.18
249.2515717	100.00
250.1952515	0.52
251.0760651	0.65
257.7659912	0.34
269.1740723	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.166
Annotation	Coelovirin A
Peak:m/z	Relative Intensity
135.0401917	0.05
147.1434937	0.15
149.0630035	0.07
175.0305481	0.12
179.1343231	0.65
180.1324768	0.83
181.2123413	0.14
208.0355682	0.15
224.0634460	0.07
231.0879974	0.69
232.0083923	0.30
249.1777039	8.82
250.0625305	5.93
267.0961914	12.48
268.1430969	10.63
297.3486328	0.13
298.1834412	0.24
312.4931946	0.19
341.2576904	0.04
346.4317627	0.07
370.6869507	0.06
400.4668884	0.25
412.1451721	1.36
413.8664856	0.22
420.9665527	0.08
428.2076111	0.30
430.2200623	100.00
430.8432007	0.44
436.0169678	0.06
438.0700378	0.12
456.1382141	0.89
457.3993530	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	376.81
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8718109	0.47
208.8714905	0.78
214.7644653	0.06
256.8432922	0.03
262.2713623	0.14
272.0565796	0.07
272.7938232	0.06
290.7592163	24.07
292.8416443	100.00
317.0723877	0.47
330.8082275	0.07
340.9100952	0.04
358.1040955	0.09
359.0120850	1.15
359.6219482	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.0288467	0.06
112.1716156	0.02
126.9254456	0.19
128.040863	0.13
135.0435181	0.44
136.0505066	0.34
153.1733093	0.06
154.6886597	0.12
160.9956055	0.30
162.0827942	0.33
173.0814667	0.87
174.130249	0.81
179.0189819	3.20
180.0669403	5.57
191.0406189	100.00
192.0639191	79.15
217.0036316	0.03
238.0030212	0.04
246.2044067	0.16
305.4692688	0.02
308.2915955	0.06
310.2340698	0.12
327.2372131	0.07
336.4060364	0.03
337.1019592	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	364.96
Annotation	Unknow
Peak:m/z	Relative Intensity
128.6651917	0.25
168.9428406	0.04
176.8454285	0.18
183.2786865	0.15
214.9569397	7.83
229.0619507	1.06
232.9369812	100.00
260.9883118	0.05
266.3464966	0.11
267.0716553	1.21
281.1383057	0.06
305.2642517	0.09
316.8915405	0.06
319.1372070	0.27
347.0498047	0.74
347.9684753	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.01096344	0.23
95.02839661	0.33
97.15129089	0.27
98.99276733	0.24
100.9838028	0.28
105.0970764	0.09
106.1578674	0.13
107.0174637	0.46
109.1010895	0.75
111.0790405	0.25
113.9906616	0.10
116.7509918	0.10
119.0630569	0.33
120.8194046	0.61
122.9335098	0.64
124.8330688	1.33
126.8466873	0.91
128.999176	0.63
131.0044556	0.42
135.0893097	0.85
137.0369873	0.68
139.013382	0.82
141.0818634	0.42
143.031189	3.29
147.0500488	0.20
148.8774109	1.08
150.050293	0.12
150.9875641	0.29
153.0875854	0.78
154.9012146	2.91
156.9842834	1.99
159.1411285	0.55
160.9673767	0.18
163.048645	0.29
165.1011353	2.10
166.6878204	0.46
169.1351318	1.87
171.125946	0.08
173.213562	0.62
174.9895782	0.68
177.0733337	1.08
179.1275177	1.02
180.0601501	0.14
181.0194244	3.28
183.0517273	2.20
185.1029816	0.50
187.2080536	0.91
191.2120056	1.07
193.227356	1.85
194.9941559	4.94
197.0942993	2.09
199.3181458	0.51
204.9797058	0.45
207.2275085	0.32
208.6837158	0.54
209.3114319	0.24
209.9364319	0.33
211.1917114	4.74
213.1274109	1.42
215.2934875	1.42
217.2246399	0.21
220.9692383	0.27
223.069397	1.22
225.1268921	4.54
227.125061	2.30
229.2734375	0.88
231.2790527	0.74
233.1917114	1.69
235.0805359	1.72
237.1000366	0.89
238.898468	0.49
241.2217102	2.30
243.6191711	0.21
246.6879883	0.47
247.302002	0.95
251.093811	4.61
251.7075195	0.25
253.151123	11.30
254.9387512	0.39
256.9691772	0.87
259.5544434	0.13
261.2859497	0.13
265.2987061	1.60
266.1785583	0.10
267.2324219	1.70
269.1801758	0.49
270.0637512	0.28
275.2648926	20.21
281.055603	0.11
283.1655273	5.15
291.4176025	0.12
293.2122192	100.00
301.8914795	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.99
Annotation	Unknow
Peak:m/z	Relative Intensity
71.0027924	0.08
111.0379105	0.05
114.8734436	7.60
126.8732300	0.04
132.9404907	100.00
134.1709595	0.22
142.0939331	0.04
155.0828857	0.16
201.5087585	0.05
244.9730835	1.64
260.9663391	0.17
287.0398560	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.03240967	0.10
138.1425323	0.08
148.8540192	0.27
157.1306	0.12
169.2680664	0.15
174.158432	0.25
177.0940399	0.17
179.0372467	0.21
179.8734436	0.37
181.1936188	0.20
183.1251526	0.90
188.9501343	0.19
191.0925751	0.37
193.1609039	0.14
195.1841278	0.19
206.1602631	1.06
207.111557	4.90
208.1352539	1.98
209.2228546	0.89
221.2465973	0.15
222.1265717	3.91
223.1008301	2.53
224.4551392	0.65
233.2214203	1.57
235.2259369	0.95
236.170578	0.36
251.0690918	100.00
252.1867218	17.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
116.842926	0.22
129.1584473	0.18
143.1331787	0.34
145.0113068	0.23
148.9358063	0.27
157.2274475	0.60
159.0829315	0.67
169.4245453	0.29
171.1483612	3.12
173.1179047	0.53
174.9653625	1.53
177.0248108	0.42
185.1764679	0.87
187.1364136	2.56
188.9822998	0.55
199.0956726	2.34
200.921875	1.48
203.2056427	0.61
205.412262	0.31
213.3864441	1.00
215.1509094	1.83
217.1047058	1.12
225.3277283	0.27
227.2129211	1.42
229.1863098	1.39
231.1312561	2.00
241.0698242	0.75
243.2555237	1.46
245.2851257	0.51
255.4735718	0.28
257.2442017	1.54
259.3311157	0.92
263.2039795	3.22
269.447937	1.55
271.1350708	4.51
272.2115784	0.27
272.9883423	0.88
277.4055786	0.53
279.5279236	0.90
281.1755981	0.23
283.164856	0.96
285.2007751	5.42
287.2706909	0.22
294.9403992	0.66
297.3570557	4.12
299.2919312	3.71
301.5335693	0.28
310.8134766	0.69
315.3143311	1.00
316.1464539	0.46
321.4208984	1.05
323.4553833	4.95
329.2427368	0.50
336.9042969	0.66
339.2521667	100.00
340.1134644	0.25
341.2884827	18.85
342.186615	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	716.61
Annotation	Unknow
Peak:m/z	Relative Intensity
208.9479370	0.01
213.0241699	0.01
290.7544250	0.37
292.9453125	0.19
295.0936584	0.13
296.8774719	0.05
376.9428101	0.03
379.3332520	0.01
380.8168335	1.19
395.9174194	0.05
458.6867065	0.04
460.7172241	0.06
461.6791382	0.01
462.7180786	0.23
464.6736450	5.32
513.0418701	0.03
514.0761719	0.02
536.2489624	0.09
542.7225952	0.09
544.3667603	0.10
546.0055542	0.81
546.6222534	0.97
547.7992554	1.06
548.5490112	16.39
549.1963501	0.14
609.8804932	0.01
610.5281372	0.03
630.1210327	0.15
632.4934692	100.00
633.1788330	0.14
670.3703613	0.02
671.0042114	0.01
674.0458984	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3281
Annotation	Unknow
Peak:m/z	Relative Intensity
280.2949219	0.04
338.6627808	0.12
403.0781250	0.10
470.3882446	0.05
488.1675415	0.03
491.2533569	0.17
502.0654907	0.09
518.2805786	0.12
534.4028931	0.12
551.7670898	0.13
552.4183350	0.06
564.3271484	0.31
565.2544556	0.08
568.5457764	0.07
594.1680298	0.10
606.1987915	0.25
607.3275146	0.36
611.3209229	0.21
636.9883423	0.27
650.4803467	0.60
651.3792725	1.13
652.3858032	0.89
654.5493164	0.14
658.0269775	0.08
662.5509644	0.62
669.4650269	0.04
670.6436157	0.34
682.3104858	1.17
683.2218628	3.03
684.1913452	0.15
686.3318481	0.12
688.2034302	0.29
706.0773315	0.05
710.4771118	0.03
716.3225098	0.21
727.0072632	0.05
728.5261841	0.12
729.5283203	0.58
730.2606812	1.60
745.4658813	0.08
746.6157837	0.12
752.6182861	0.04
755.4163818	0.15
756.1589966	0.81
756.9162598	0.04
762.6510620	0.23
774.2355957	100.00
774.9417114	0.60
778.3516235	0.15
788.2603149	0.29
806.6840820	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
66.8550568	0.09
69.9392548	0.11
72.2047577	0.05
79.8077850	0.07
80.7780151	0.02
82.0479202	0.16
83.6774902	0.25
85.9312286	0.04
87.9751434	0.04
93.1683807	0.08
94.1509247	0.10
96.7768402	0.06
98.0236053	0.23
100.0102234	0.07
101.0028076	0.03
107.0335846	0.10
107.9453430	0.05
108.7053680	0.04
110.0856628	0.12
110.9935150	0.38
111.7775879	0.11
112.8991241	0.10
115.0206451	0.11
116.0115509	0.07
118.2199554	0.14
120.9891815	0.05
121.8537750	0.17
123.0180359	0.06
123.9156647	0.09
125.1202240	0.17
126.0800781	0.03
126.9311981	0.07
128.0023651	0.14
128.9391632	0.02
130.3044891	0.02
133.9647980	0.04
135.9351501	0.22
137.9647675	0.05
139.9985504	0.21
140.9936981	0.17
141.9180603	0.04
143.9666443	0.12
144.7678680	0.03
146.1108551	0.14
148.8561249	0.15
152.1091003	0.43
153.0015259	0.06
154.1148529	0.43
155.0123138	0.31
156.0505676	0.28
158.9340057	100.00
161.0116577	0.03
164.0668182	0.12
164.9370117	0.14
170.0348206	0.72
172.1275177	0.32
175.9696198	0.09
176.6041565	0.65
179.5292358	0.13
181.0489655	0.03
182.0905609	2.62
183.0383759	0.41
184.0297394	0.13
184.8273468	0.11
188.1221924	0.12
188.9268188	0.03
191.0101318	3.14
196.1794281	0.12
199.9548492	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	230.01
Annotation	Unknow
Peak:m/z	Relative Intensity
78.8834381	0.17
87.9425812	0.02
96.9874725	2.10
97.8830566	0.02
113.9307556	0.04
115.2218781	0.02
123.7688599	0.01
131.9334259	100.00
132.7512360	0.02
145.1682281	0.04
183.2065125	0.05
186.1732788	0.03
203.1068573	0.04
211.1924286	0.03
212.0922852	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0149
Annotation	Unknow
Peak:m/z	Relative Intensity
100.3980560	0.02
177.0475311	0.01
218.9366760	0.05
221.9005127	0.04
223.9087067	100.00
241.8038483	13.38
243.7641754	0.03
246.9362793	0.04
248.3694458	0.01
265.0039673	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.18
Annotation	Sarmentol B
Peak:m/z	Relative Intensity
93.00068665	15.00
96.77624512	1.13
113.1915283	5.21
115.2110748	2.32
127.1580353	7.33
130.0847931	2.48
154.6346893	2.89
157.1206665	1.81
167.0864258	19.75
168.9362793	12.04
170.8470917	4.63
181.0000305	7.13
183.1711426	91.13
185.1174164	35.91
187.174118	3.09
199.2459564	6.19
201.1737366	1.59
209.0061188	3.89
211.1763306	100.00
212.0157318	6.17
213.0853577	10.18
226.9330292	2.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.13
Annotation	Unknow
Peak:m/z	Relative Intensity
153.2063904	0.44
159.9860535	0.15
165.7963715	0.06
167.0642395	0.71
170.0415649	0.13
171.0030365	0.29
177.0841217	0.17
178.1357574	0.32
179.0696564	1.33
180.3988953	0.07
184.2333069	0.74
185.1390533	0.60
192.2380981	0.38
194.3029480	0.11
197.1246185	2.54
197.9721222	0.28
199.2724304	0.18
204.2736816	0.10
210.2193298	0.79
212.8522797	0.26
214.8473663	0.15
224.1456146	0.12
230.2097321	0.05
231.0599670	2.29
235.1057587	0.14
236.2915955	0.10
239.2559814	0.05
240.4467926	0.32
243.9949036	0.08
246.2447662	0.11
249.0491486	0.18
254.0753174	8.33
264.0936584	0.17
268.2871704	0.16
269.9885864	0.68
272.0838623	1.56
277.2720947	0.04
278.9797974	0.13
280.1694946	0.15
288.1547241	20.71
297.3629761	0.21
298.4971313	0.18
300.1873169	0.50
304.7143555	0.18
306.1725464	10.18
307.8640747	0.27
313.1009521	0.90
314.4931030	0.05
321.2905884	0.47
322.6625366	0.54
323.3104858	1.89
325.0912476	0.45
326.0652466	0.86
333.2189331	0.12
338.6082153	0.11
339.4047241	0.17
341.1740112	2.70
342.1875000	0.76
343.1502075	0.09
344.9129639	0.22
346.3208618	0.44
347.4166260	0.23
349.0390625	0.43
351.1713257	0.52
353.4108276	0.11
357.1237793	3.81
358.0428467	0.23
360.0698242	1.26
364.3175049	0.31
365.1215210	0.62
367.2611694	0.51
370.0715332	0.17
372.5003052	0.08
375.1644897	23.44
376.4618530	0.03
378.3071289	2.45
380.2188110	0.08
380.9953003	0.06
382.2527466	0.16
383.2766113	1.30
385.3792114	0.33
390.1856689	1.19
391.2366943	0.76
392.2033691	0.80
395.2980957	0.52
398.1313477	0.08
399.2489624	1.74
406.0027466	0.09
408.3411255	3.68
409.1647339	21.51
409.7668457	0.16
411.1364746	0.05
416.2209473	1.92
417.2478638	9.00
422.3898926	0.12
424.1699829	3.09
425.9829712	0.96
426.5960693	0.06
429.1383667	3.28
430.0996094	0.04
434.2468872	2.08
442.2083130	12.81
443.0148926	0.71
450.3688354	0.06
452.2889404	7.53
458.2429810	0.08
460.2588501	5.32
463.2316895	1.05
468.2646484	8.11
469.2406616	0.10
470.2791748	4.11
474.2797852	0.96
476.3375854	0.49
481.5348511	0.29
486.1856079	93.38
487.4348145	0.25
494.2040405	0.15
502.1959839	2.72
504.2041626	100.00
504.8612061	0.85
520.1431274	72.30
521.0435181	0.47
529.2302856	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.1168
Annotation	7,2',4',5'-Tetramethoxyflavone
Peak:m/z	Relative Intensity
120.8813858	0.04
126.9075623	0.03
135.1941681	0.23
136.0925446	0.05
146.7015991	0.03
150.8301697	0.06
153.1227112	0.07
162.9257355	0.57
169.2248383	0.13
177.0899811	0.09
178.9354553	0.06
180.9224396	0.45
185.1015472	0.18
185.9165039	0.03
187.1203003	0.20
188.1377411	0.07
189.1347656	0.11
191.2780151	0.08
199.1821289	0.07
201.2188263	0.22
203.1261139	0.07
212.2258301	0.05
216.2735291	0.05
216.9337158	0.04
219.2154236	0.56
220.3888245	0.08
226.8470154	0.18
231.9065857	0.05
234.1426086	0.11
237.1050415	0.08
241.2243347	0.13
246.0033264	0.11
247.1237183	0.78
249.3788147	0.16
253.2247925	0.05
254.7205811	0.03
258.9456787	0.15
262.3947754	0.06
265.0366821	0.16
265.7506104	0.04
267.4703979	0.13
268.8103638	0.12
270.8675537	0.10
272.8698120	0.08
276.0493774	0.14
280.0252380	0.06
281.2042236	0.19
282.1802979	0.03
283.1789856	0.13
284.9142456	0.04
293.2039490	0.80
297.1851196	2.76
299.1383667	2.22
301.2752075	0.15
302.4583740	0.20
307.1875610	3.69
311.0887451	0.30
313.3228760	0.20
315.1834717	0.04
325.1383057	100.00
326.2816772	0.55
327.9708557	0.20
333.7720947	0.36
334.5970459	0.03
342.6913147	0.20
343.4989624	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.2076
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8062439	0.21
136.9884338	0.12
143.1707001	0.24
149.1496582	0.09
160.9894257	0.20
178.9098816	1.25
180.2001190	0.24
183.2026062	1.98
185.1359863	3.27
201.2448120	0.18
211.1433105	2.18
220.2050171	0.12
229.1378174	100.00
245.0642700	0.34
264.0083923	0.07
281.5470886	0.20
283.2192383	0.26
286.2933350	0.17
295.0795288	0.11
308.2681580	0.07
309.3217773	0.22
312.7641602	0.28
315.0791016	0.18
321.0996704	0.36
323.8981934	0.19
335.3657532	0.20
342.8901978	0.18
349.1321411	0.54
353.3018188	0.22
363.2399902	0.72
363.9517822	0.37
365.1569519	0.31
366.0676880	0.26
373.2486877	0.20
389.1059570	0.12
391.2582703	1.18
392.1779785	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.06
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.9205399	0.43
70.8843002	1.83
72.9719620	0.85
74.9823456	20.99
80.9635086	5.51
82.9607239	0.21
86.9473267	4.46
88.9559326	3.94
97.0283051	0.83
98.9484406	14.43
100.8621063	0.42
102.3962402	0.14
103.1648865	0.10
106.7722778	0.26
112.9934692	0.98
115.0410156	0.23
116.9575653	0.22
118.9140625	1.80
124.9358521	10.08
129.0353699	0.05
131.0086975	0.99
132.5332336	0.17
135.1885529	0.03
142.9373932	41.27
148.9315186	0.66
159.1886749	0.06
160.9435272	100.00
179.0079193	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	350.1606
Annotation	Anacrotine
Peak:m/z	Relative Intensity
104.0173187	0.22
107.9785156	0.05
108.9394913	0.04
120.9809875	0.06
122.1994171	0.40
124.2714386	0.29
124.9861755	0.05
134.9749146	0.06
136.2295837	0.11
137.0925140	0.11
137.7380676	0.03
147.0919189	0.02
151.2904968	0.22
153.0043030	1.37
154.1033630	0.17
161.0559082	0.18
164.1764221	0.10
165.0895996	0.50
166.0512695	1.20
167.9205627	0.84
171.1651306	0.08
175.1145325	0.24
177.1570892	0.65
178.1174622	0.15
180.2555542	0.03
187.1947479	0.17
188.9602051	0.29
190.1068573	0.25
192.2819214	0.06
194.1629333	0.10
196.1695862	0.24
198.0248718	0.18
201.1793976	3.96
203.1303101	0.70
204.2148438	0.08
205.3528748	0.16
206.1914673	0.13
211.2846680	0.04
212.0875854	0.13
217.2599487	0.16
219.2579346	4.34
220.1642151	0.10
224.2105103	0.04
227.1490784	0.06
228.3829041	0.02
229.1547241	0.10
230.1455688	0.33
232.4665222	0.24
234.4672241	0.05
236.1512146	0.19
237.9088135	0.14
240.1654968	0.06
240.8688965	0.08
243.2964478	0.12
245.1003723	3.38
246.0886230	0.09
246.9900513	0.03
250.2272034	0.04
252.3559570	0.22
255.0916748	0.15
256.0346985	0.04
258.2448425	1.49
259.1683960	0.08
260.1696167	0.15
263.3476868	0.39
270.2803345	3.87
271.9851685	0.04
273.4447937	0.77
276.2445068	1.11
278.3132935	0.17
286.0337524	0.11
288.2176514	10.18
290.4487915	0.12
291.3901978	0.86
296.3351135	0.07
298.4299927	0.03
302.1722717	0.62
303.5414124	0.12
304.1516724	0.30
304.9770508	0.03
306.2352905	1.55
309.2308350	0.06
314.1177979	0.71
320.1725159	100.00
321.3553467	0.18
322.4122925	0.03
332.1494446	3.54
333.8462524	0.06
335.2825012	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1361
Annotation	Unknow
Peak:m/z	Relative Intensity
170.8017273	0.39
173.0661469	0.17
179.1322632	0.05
187.8865662	0.08
190.9989471	100.00
193.2159729	0.29
197.1533203	0.15
247.1296692	0.09
257.1087952	0.15
285.2340698	0.27
304.9340210	0.07
368.9779663	0.12
397.2196655	0.15
421.8899536	0.12
489.3273315	0.07
515.3490601	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0347290	2.35
160.0474243	1.07
161.0329285	1.00
162.0291748	0.13
198.9400024	0.31
201.1573181	0.45
218.0939941	0.31
220.2753296	0.46
228.9667358	0.41
230.6586761	0.62
231.7888184	0.26
273.0108643	16.93
273.9934082	27.59
275.0255127	26.79
276.0563049	16.93
289.9324036	0.20
302.1775513	0.09
346.1643677	0.38
387.3566284	7.16
388.0410461	37.79
388.9673462	42.87
390.0190125	100.00
429.0729065	0.33
430.0701294	0.71
433.1977234	0.53
441.8135681	0.65
447.5561829	0.20
457.9397278	0.44
459.0060120	4.37
459.7354431	0.09
477.2824097	0.24
485.8550415	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1384
Annotation	Unknow
Peak:m/z	Relative Intensity
88.9608078	8.08
97.2068558	0.08
98.9567566	0.08
118.2131653	0.05
120.1912384	0.04
123.9589233	0.14
127.0657806	0.56
135.9763489	0.96
141.0689392	0.12
149.9623566	14.28
150.9688263	25.55
151.9120178	0.08
153.1538544	0.11
154.3207397	0.10
155.1445007	0.21
162.1475067	0.36
163.0243683	0.55
165.9140320	0.37
166.8219452	0.17
171.0770721	0.06
172.2212067	0.03
174.3278351	0.39
175.1740417	0.06
179.9144135	0.12
183.1238556	0.11
188.0538330	1.62
192.2879181	0.08
194.2811279	0.38
195.0594330	0.09
197.1130524	0.86
198.1823883	0.12
201.1176605	0.63
205.4066620	0.16
211.0817719	0.21
212.0856018	0.73
214.9357147	6.51
220.2952118	0.14
222.4983063	0.36
223.1825562	0.30
225.0083466	0.08
226.3719940	0.15
227.1089020	0.18
232.2626343	3.62
232.9308472	19.76
235.8981934	0.11
237.0153656	0.15
240.0574799	0.12
241.0487061	0.27
243.0166626	0.11
246.2635956	0.05
248.4840240	0.55
250.1077118	21.17
250.9442902	100.00
252.1792603	0.15
259.4727783	0.28
268.3457031	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9391
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9978638	0.95
161.0868835	0.19
201.0224304	0.10
205.1302032	0.03
219.0762024	0.05
229.2251892	0.21
231.1335754	0.08
247.0792847	0.02
272.9717102	51.10
274.1037292	20.82
275.0188904	100.00
298.9381714	0.04
326.7465820	0.04
342.1376343	0.14
343.0931396	0.36
345.0746765	0.11
345.9384766	0.04
366.0077820	0.03
370.3468933	0.05
370.9836731	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.1453
Annotation	verminoside
Peak:m/z	Relative Intensity
159.0294189	0.25
165.7999725	0.42
167.0477905	1.45
193.0274506	0.48
207.2492828	0.13
235.2087708	0.15
269.1974487	0.19
283.1567993	0.73
322.3275146	0.27
331.348938	0.25
343.5529785	0.31
355.3040771	0.49
361.1025391	100.00
361.7639771	0.42
403.0853271	3.37
427.4901733	0.38
433.2962646	0.59
437.1295166	0.64
462.9559326	1.69
477.3325806	0.58
479.0973511	0.17
493.2967529	0.67
494.7537842	0.55
496.0144043	1.79
505.1360474	2.65
506.043457	0.29
524.8157349	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
79.12809753	0.18
98.90725708	0.13
105.1472321	0.26
112.8468628	0.15
136.9786224	0.35
138.8744659	0.09
139.4797974	0.18
141.0891266	0.16
145.2059784	0.13
149.0077667	0.20
152.8354492	0.15
155.1838226	0.49
163.3394623	0.12
164.1111755	0.20
168.8806915	0.14
172.6547699	0.11
180.205246	0.19
181.1897125	0.82
183.052475	0.13
184.8931732	0.38
193.0172882	0.36
195.2594757	0.61
197.0478668	0.14
204.4944458	0.28
206.0905914	0.10
207.1303864	6.13
208.1572418	2.32
209.1626587	3.88
221.9594574	1.33
223.1795807	4.79
224.0878754	0.67
233.3218231	1.29
236.0161743	0.20
251.0826263	100.00
252.178894	21.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1616
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1377258	0.06
160.9275208	0.22
173.0402222	3.60
179.0349731	1.97
250.7650909	0.04
260.9515686	0.07
265.0479736	0.07
275.1139526	0.03
281.3854065	0.03
341.1828613	100.00
343.2918091	0.15
352.9476318	0.24
397.1633911	0.01
398.9087524	0.11
455.1979980	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2872
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
120.9476166	7.63
124.5696869	9.73
126.8270416	16.35
135.1307373	4.29
140.3206177	6.94
141.2308655	4.67
153.1907806	3.85
155.0161591	9.64
165.2640991	11.00
174.7679443	5.04
181.0163879	5.64
191.1430511	2.52
213.2800903	6.62
219.1443787	6.12
225.9645386	1.72
226.743042	2.72
231.3803101	4.89
233.9424438	4.03
239.3027039	19.61
244.1997681	6.82
245.3005676	15.86
249.5060425	7.89
250.4456482	2.32
280.8440857	17.92
282.1217346	1.72
285.1945801	4.43
288.500946	5.50
295.3969727	2.96
296.9507751	8.20
305.4228516	7.69
308.3798523	2.71
309.4485168	4.03
313.921936	22.10
325.4234619	2.72
332.418396	12.52
334.3936157	7.08
337.2392273	4.33
338.0979004	9.39
338.8735657	21.91
339.493103	7.58
340.1005554	12.17
366.1692505	6.41
375.0731506	4.52
377.4223328	12.17
381.5074158	7.40
382.4130554	8.48
385.3663025	6.02
390.2800293	2.71
394.8298035	1.96
398.2702637	8.01
408.2729797	100.00
409.5710754	27.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.1349
Annotation	Lamiide
Peak:m/z	Relative Intensity
128.8883667	0.26
160.8073730	0.27
165.1183319	0.14
190.9721375	0.31
195.0774231	9.91
232.7043915	1.07
250.9355774	0.56
253.0349426	0.04
267.4774780	0.10
269.2520447	0.12
275.5815735	0.06
277.3577881	0.06
301.1740723	0.09
303.4016724	0.30
307.3063965	0.13
317.2324219	0.05
327.0809326	16.34
337.2760010	0.11
339.1267090	0.09
357.0581665	75.47
358.1397705	0.08
374.9417419	100.00
375.6673889	0.13
377.3123474	0.08
385.5807190	0.04
393.3336487	0.05
398.7366638	0.15
403.0617371	0.16
403.8263245	0.74
404.5480957	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0787506	0.11
149.2552185	0.09
152.7309265	0.07
195.8642883	0.07
214.1181488	2.69
248.5566711	0.18
256.0757751	0.12
261.3341370	0.08
279.2806702	100.00
280.2809448	0.08
386.3183289	0.07
411.0180359	0.88
422.2527161	0.23
428.3352356	0.23
432.3656006	0.16
440.2452698	0.03
447.5679932	0.21
448.5738831	0.09
457.8515015	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8027954	11.10
208.8835754	10.72
280.7394409	0.47
290.7554932	53.19
292.7515564	100.00
299.2212219	0.08
341.0146484	0.27
374.2976685	3.17
374.9059143	3.98
376.5538025	31.25
377.3471680	0.10
393.0664978	0.09
400.1640930	0.12
400.7667542	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
147.8861694	0.15
171.245636	2.42
173.3474426	0.21
177.2321472	0.32
185.0327148	1.16
187.102066	1.28
199.0920105	0.66
201.0690918	1.79
202.9927063	0.66
209.3478394	0.22
211.1958313	0.36
213.1539001	0.65
215.0989685	1.23
217.2518005	0.18
227.3326721	0.19
229.2295532	0.92
231.0284729	0.64
239.2967529	0.11
241.5959778	0.82
243.1100464	2.00
245.4328003	0.66
247.1815186	0.17
253.4085388	0.31
255.1860962	2.42
257.2281494	1.62
263.2678528	0.80
266.9983521	0.29
269.2883301	0.33
271.1819763	5.48
273.3261719	0.39
276.0944824	0.36
277.323822	0.42
279.1667175	0.36
281.0628662	0.17
283.139801	0.53
285.3505859	5.37
287.352417	1.21
291.0004578	0.50
295.4985352	2.57
297.2878418	2.17
299.3241882	1.91
301.164032	1.07
302.8838806	0.50
311.1016235	4.61
313.2625122	1.41
314.1381531	0.87
315.274292	1.23
321.1134644	0.72
321.7893677	0.20
323.3328247	11.32
325.6732483	0.61
327.2946167	0.67
329.3651123	0.22
330.3613586	0.53
337.4168091	0.15
339.2512207	100.00
340.3336182	0.43
341.3686218	21.41
343.3683167	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0876
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
98.9921875	0.04
101.1100922	0.33
113.2839508	0.16
118.8881302	0.20
130.8494110	0.13
133.9352264	0.03
135.0658569	7.82
136.0717773	0.03
143.1213837	0.18
149.0429382	0.02
159.1836548	0.20
160.9364014	0.33
173.0879669	0.06
178.9957886	100.00
181.2701721	0.08
189.1109467	0.10
203.3963318	0.04
208.9580078	0.05
221.2903748	0.03
232.8538208	0.03
243.0661621	0.05
247.2295837	0.03
265.0532227	0.18
267.2664490	0.10
276.9023438	0.03
279.2220764	0.04
280.9823303	0.20
282.9582520	0.03
295.0354309	0.80
296.9732056	0.39
298.0293579	0.15
309.1242065	0.09
311.0341187	0.02
312.6976318	0.03
322.9478455	0.62
326.0690002	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2208
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.83750916	0.21
93.07424164	0.32
95.04373169	0.44
96.98500824	0.30
98.83955383	0.36
105.0033493	0.14
109.0443039	1.77
110.8697052	1.19
114.8228531	0.12
120.6548462	0.60
122.9080658	0.57
125.1316986	0.76
126.9989471	0.51
128.7325897	0.70
132.9312744	0.49
135.0393372	1.40
137.0647583	2.04
138.0405121	0.74
138.9187012	1.71
140.9147949	0.19
143.0295715	3.29
145.0362549	0.19
147.0505676	2.00
149.0625916	0.08
150.9606171	2.04
153.1752014	0.52
153.9707642	0.12
155.0999756	1.51
157.0638123	1.23
159.0695648	1.01
163.1146545	1.49
167.1706848	1.52
168.9904938	0.99
171.0437164	1.43
172.4673767	0.48
173.1261902	0.15
175.038559	1.38
177.0387573	0.78
179.0123138	1.50
180.9900665	1.43
183.0362549	0.21
187.1554565	1.15
189.1628723	0.58
191.1480103	1.00
193.0914001	1.01
195.0745544	1.92
195.7546844	0.79
197.0770874	0.76
199.3005524	1.24
201.0298157	0.47
204.223114	0.12
205.0708313	0.44
206.1556091	0.60
207.2410583	0.70
209.1486511	1.64
211.1848755	2.92
212.9057922	1.68
215.1837769	2.92
219.254364	0.55
221.1892395	1.21
221.8078003	0.44
223.2856445	0.57
225.0059509	1.42
227.1852417	2.64
229.1882935	2.05
231.0588074	0.21
233.0048218	1.18
235.1893311	0.69
237.3160706	1.94
238.9767456	0.53
241.2928162	1.09
245.3710327	0.50
247.1217041	1.04
249.1570435	1.36
251.0645752	2.36
253.0892639	5.10
255.2911377	0.16
256.8247681	0.93
257.4390564	0.30
263.5097656	0.27
264.4176636	0.48
265.3395386	2.11
266.3300781	0.23
267.1291504	1.41
269.074707	0.92
269.985321	0.79
275.2432251	22.42
279.24646	0.12
283.2498474	3.38
293.2029114	100.00
294.2981262	1.03
295.3253784	0.25
302.0458679	2.25
302.8970337	1.19
313.1344604	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2208
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.96118164	0.14
94.97671509	0.24
96.80303955	0.10
98.87864685	0.37
100.8455353	0.08
106.999527	0.18
109.0275116	0.52
111.0329895	0.65
113.135849	0.08
115.2260132	0.24
117.0466843	0.59
119.0761566	0.95
121.1080475	0.42
122.9963608	0.87
124.9361572	0.35
127.1943207	0.31
129.1462708	0.21
130.8860626	0.18
135.1400299	1.06
137.1937103	0.53
138.987381	1.78
141.0231628	0.08
143.1352539	1.64
147.1486206	0.23
149.1195679	0.56
151.0661621	0.19
153.0251923	1.11
153.8027344	0.09
155.0764008	0.85
156.92099	0.85
158.8755798	0.10
161.1106567	0.27
162.9576263	0.66
165.7395325	0.35
166.9797668	0.85
169.1709595	1.43
173.2027893	0.44
174.9007416	0.62
176.9405823	0.69
178.9645386	1.42
179.9720764	0.07
181.0926056	2.07
182.971817	1.64
184.5182495	0.53
185.180542	0.12
187.2294006	0.08
191.1448975	0.13
193.0788727	0.82
195.0270996	3.61
196.8273926	1.53
197.4826813	0.14
199.3576508	0.47
199.9927521	0.13
200.8638763	0.42
204.8198853	0.25
207.2946472	0.26
209.1593933	0.95
211.0667725	3.44
213.0735168	0.74
213.951355	0.12
215.2833252	0.87
216.1538391	0.14
219.1283875	0.21
220.1863708	1.35
221.0726929	0.13
223.0632935	1.68
225.0620728	1.00
227.2218933	1.43
229.1907654	1.09
231.3509216	0.23
233.2115784	0.29
235.2113037	1.51
237.1583252	1.54
239.0899658	1.67
241.1635742	0.94
242.2479858	0.39
243.199707	0.10
247.2171631	2.96
251.1201172	3.32
253.1774292	8.12
255.1441345	1.23
257.2335205	1.67
259.5898743	0.34
265.0516357	1.21
266.5375366	0.18
267.3013916	1.07
269.2548218	1.89
270.2303162	1.02
270.9196777	0.36
275.2977295	17.03
277.0822144	0.19
279.2567749	0.38
281.0537109	0.25
283.0335083	2.50
284.1124268	0.10
291.0005188	0.42
293.2181396	100.00
294.2941895	0.58
299.7229614	0.95
302.1029053	1.03
302.7208557	0.08
311.5752869	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	2'-Methoxyflavone
Peak:m/z	Relative Intensity
77.16569519	0.41
80.98614502	0.63
82.9773407	0.89
85.09169006	0.52
93.04330444	0.65
95.04977417	1.49
97.05025482	0.38
98.91781616	0.36
103.0495758	1.52
104.9453125	1.50
105.7190552	0.09
106.8796234	0.61
108.9919586	1.04
111.0145416	0.85
112.8178558	0.09
118.9733887	1.45
121.0137482	0.70
122.9261627	2.66
125.0855865	0.52
127.0081635	0.28
128.4390869	0.44
129.0470581	3.75
133.1364899	0.70
135.0724487	0.94
137.1027527	1.57
138.0196533	0.48
138.8468781	0.33
140.9990387	0.29
143.0731964	0.10
147.0034943	3.11
148.1508789	0.53
149.2336578	0.62
150.9976654	52.46
151.9330292	6.22
153.2453308	0.43
154.1419678	1.16
155.1380005	2.10
156.1397552	0.23
157.1701813	1.00
159.1403351	0.99
160.9688416	0.74
162.7423859	0.99
165.0705719	1.43
167.0760956	1.54
169.0711823	1.88
171.0406342	0.56
175.0684967	1.59
176.6521759	0.54
178.2796173	0.80
179.0785065	2.02
181.2124481	0.15
182.1229706	1.62
183.0860138	0.68
185.0463104	1.46
189.0474243	0.08
190.5787506	0.80
191.1929016	0.68
193.1578674	0.78
194.416626	0.84
195.0339813	1.87
197.19487	4.62
199.0746918	0.75
203.0643768	0.46
205.0359802	0.34
206.6488495	0.59
207.2946014	0.60
208.0631256	0.78
210.1522064	0.12
211.1297302	1.88
211.8871002	0.16
216.5306244	0.21
217.1976471	7.96
223.1606293	0.53
225.214798	7.13
226.0683136	2.42
235.056015	26.31
236.3399811	0.28
237.0073853	0.55
238.1587372	12.76
239.2648773	0.79
244.5880127	0.51
250.9637299	0.36
251.984726	1.07
253.0953827	100.00
254.140564	13.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.0831
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8495407	0.08
134.2492371	0.09
171.1508789	0.21
173.0227661	0.49
182.9077148	0.08
191.0029449	100.00
248.4411316	0.15
251.1261597	0.05
278.0101929	0.13
295.1390686	0.03
323.2919922	0.16
337.4208069	0.27
341.1901550	1.53
364.9281921	6.68
365.5948181	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.07529449	0.46
80.94128418	0.41
91.09931946	0.29
94.67272949	0.29
103.0015717	0.91
104.0946198	0.85
105.0226135	0.46
106.9057465	1.07
108.9335327	1.15
113.0357513	0.16
115.1407623	0.30
122.9372406	1.14
125.0414429	0.37
129.0745544	6.38
133.1356201	0.34
135.3269806	0.38
139.029129	0.65
141.1997833	0.65
142.1119232	0.16
144.8479309	0.30
150.92276	53.95
151.997879	3.71
157.1193085	0.27
161.243576	0.53
164.8264008	0.88
165.7494507	0.21
167.0023346	3.33
168.9244995	0.40
170.012207	0.29
177.0206146	0.13
178.1634369	0.53
179.401062	0.58
182.0045929	0.28
183.0020905	0.40
185.2162476	2.99
186.2594452	0.18
188.904541	0.43
191.188446	0.64
195.2961273	0.98
197.0969391	2.65
198.1690521	0.74
207.0849457	0.59
208.2266998	0.24
210.5153961	1.31
211.2172852	0.49
215.1766663	0.47
217.1607208	1.05
225.0413208	6.87
226.3947296	0.12
232.4685822	0.20
235.1762238	6.52
238.1507111	8.54
239.0650787	0.52
250.8292847	0.20
253.0912018	100.00
254.1578979	17.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.9333191	0.07
110.891861	0.17
120.8540344	0.06
127.0189133	0.17
128.040741	0.06
133.9906921	0.25
134.9953003	0.50
136.052597	0.23
144.1047974	0.05
153.9627991	0.04
160.8983154	0.09
161.9981689	0.44
172.0543518	0.09
173.069458	2.00
174.0812683	0.39
179.0942993	3.26
180.0894623	4.32
191.0578308	100.00
192.0178833	75.03
242.0282288	0.06
246.3890076	0.12
258.1026306	0.06
263.7883911	0.05
266.1360474	0.03
308.0977783	0.04
309.8679504	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
76.86764526	0.23
78.96389008	0.51
80.93682861	0.61
82.89692688	1.50
93.07197571	0.77
95.07202148	5.85
95.90322113	0.35
96.93173218	1.19
99.12902832	0.19
102.014389	0.37
103.0580597	1.14
104.8955383	2.61
106.2528381	0.84
106.9597321	1.15
109.0371246	3.52
109.9929047	0.62
111.0233765	2.85
111.9262695	0.42
112.9842987	0.59
115.075531	0.65
119.1261139	2.32
120.9315796	1.80
123.0964355	0.25
124.8979797	0.92
127.1411591	1.23
128.9377899	7.01
133.033493	1.24
134.9615936	1.91
135.993927	0.17
137.0249176	2.14
139.065918	0.87
140.9883575	2.31
143.1353302	1.58
146.9872742	3.56
149.0868073	1.06
151.0283661	50.27
151.9711304	1.71
153.0225067	1.39
154.9208221	3.42
157.0500641	0.23
159.2207184	1.05
161.0666199	0.74
162.8622894	1.59
165.062149	3.92
167.0393219	2.42
168.9584503	2.59
170.14888	1.02
171.0536804	2.67
175.0196533	1.60
176.9716797	2.24
179.0102386	0.79
182.2621002	1.22
183.1760712	2.10
185.1545105	1.74
189.4023132	0.79
190.9943085	2.84
192.9907837	4.45
193.917511	0.52
195.141922	6.93
197.0272522	6.28
199.1195984	1.03
200.7131348	0.34
207.0383148	4.28
208.3735657	0.37
211.1483307	7.30
217.1991577	13.19
219.2847443	0.63
221.2090912	0.19
223.1451569	1.11
225.2255707	9.00
235.1788483	31.31
238.0509796	4.40
238.8825684	0.79
244.1501465	0.36
250.9826813	0.92
253.0955658	100.00
254.1531525	15.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	gamma-Pentachlorocyclohexene
Peak:m/z	Relative Intensity
206.9251099	0.98
223.0632935	0.06
290.8428040	12.03
291.9473877	0.02
307.1332397	0.02
374.6580811	7.17
380.4197998	0.05
381.4005127	0.02
390.9226685	0.14
445.4149170	0.03
456.2373047	0.05
458.5463257	100.00
459.2786255	0.21
524.3444214	0.05
525.2075195	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1192
Annotation	1,3-Dicaffeoylquinic acid
Peak:m/z	Relative Intensity
173.0495911	0.20
178.8990479	0.72
180.0419006	0.09
191.04599	0.83
269.166626	0.22
292.7589417	0.71
300.1075439	0.18
301.2982178	0.15
332.9748535	0.31
335.2020874	0.53
353.0879517	100.00
353.7849731	0.36
441.2207031	0.99
455.1221924	0.16
456.9454346	0.27
464.1789551	0.16
469.2296143	1.36
471.4187012	1.36
479.4932861	0.27
497.2640381	1.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.09550476	0.63
78.85929871	2.12
81.06468964	2.70
83.02455139	0.27
91.08770752	1.13
93.03178406	2.88
94.98564148	7.12
95.80499268	0.24
96.83187866	1.93
98.9099884	1.33
105.25383	1.18
106.8815765	2.20
109.0449371	1.41
111.1035767	3.44
113.1536255	0.52
113.9084167	0.45
114.9507751	0.49
116.823288	0.33
118.8487854	0.24
120.9739227	3.02
123.0781097	6.19
125.0380859	0.56
128.9825897	5.72
130.9146729	0.22
133.1206207	1.53
135.1264954	1.31
136.9891663	3.43
138.7570953	2.19
140.9067993	5.88
143.0351715	1.36
144.9006195	0.91
147.0711365	0.79
148.8969574	0.95
150.9532928	67.29
151.9790955	8.86
152.8114471	2.76
154.1022186	1.10
155.1341553	2.09
157.1287842	1.87
159.1298676	0.44
163.0816803	2.94
165.0556488	4.32
167.0015564	5.86
168.0047607	0.36
168.9413757	4.29
169.9612579	0.15
171.2195892	1.77
173.0015869	1.56
175.0169525	5.11
177.0175171	3.21
178.1553497	0.43
179.1075134	0.31
180.2717438	0.56
181.095047	0.69
182.0516205	1.03
183.1686859	3.33
185.0847778	1.84
189.1121979	5.56
190.6234589	1.18
193.4076538	2.02
195.0088806	3.11
197.0750275	21.77
197.688736	0.69
199.2276306	1.83
207.1163635	6.98
209.284729	0.99
210.8772888	3.77
217.1187134	15.14
225.095871	14.78
229.331604	0.81
232.2692413	3.21
235.2126465	45.13
236.4372711	0.31
237.9694366	6.56
239.0970612	3.90
244.0801849	3.60
253.0894318	100.00
254.146347	29.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1503
Annotation	[3R-(3alpha,3aalpha,4beta,5alpha,6aalpha)]-3-[(beta-D-Gulucopyranosyloxy)methyl]hexsahydro-4-(hydroxymethyl)-5-methyl-2H-cyclopenta[b]furan-2-one
Peak:m/z	Relative Intensity
113.3810654	0.04
114.9054565	0.06
121.7304230	0.09
137.0763550	0.21
145.7362671	0.09
153.0690308	0.37
155.0738525	13.04
160.7883301	0.09
162.8092041	0.13
164.9801636	0.18
167.2184601	0.08
169.1623230	0.10
179.1232910	0.42
181.1195221	0.20
183.0818024	0.04
191.2982025	0.03
193.2226562	0.03
195.2952271	0.03
197.2938995	0.40
199.0574036	100.00
201.3718872	0.04
208.9324188	0.11
212.8432159	0.13
225.7547302	0.04
241.1907654	0.72
243.2755737	0.04
246.1107788	0.12
246.9642639	0.25
253.1348877	0.08
281.4386292	0.10
289.2537231	0.05
297.2324219	0.08
299.1836853	0.18
299.8969421	0.08
301.2299194	0.49
303.2394409	0.06
310.8937988	0.04
313.2541809	0.19
314.2612305	0.15
315.0566711	0.70
316.9616089	0.08
324.5379028	0.10
325.2340088	0.16
331.2971802	0.17
334.1739197	0.14
341.3862000	0.13
343.2391663	1.42
344.2393494	0.04
346.2149963	0.37
347.1854553	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.0349
Annotation	Unknow
Peak:m/z	Relative Intensity
63.0380440	0.01
89.2487793	0.02
109.8458405	100.00
110.9540100	0.02
121.0725250	0.02
127.8807220	4.00
130.3861389	1.29
132.8403473	0.01
139.3336945	0.52
146.1333923	0.06
150.7738495	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1346
Annotation	Semperoside
Peak:m/z	Relative Intensity
109.3042068	0.05
135.0559692	0.07
153.0704346	18.65
172.6675415	0.03
178.8875122	0.62
180.8895111	0.16
190.9129486	0.10
195.0446167	0.50
197.0913086	100.00
211.1014099	0.18
217.1464233	0.06
218.835968	0.05
225.3526917	0.21
238.9757385	0.39
241.0996094	0.14
243.0038452	0.23
251.3618469	0.17
262.9599609	0.09
269.1924744	0.16
276.7008972	0.09
283.0256348	0.06
287.3081055	0.08
296.7596436	0.26
297.3814697	0.05
299.1328735	0.67
300.8522949	0.13
311.1455688	0.16
312.9498291	1.92
315.1716309	0.63
315.9631958	0.19
323.2941284	0.36
325.4619141	0.15
329.2766113	0.76
336.5109253	0.32
341.203186	1.92
341.9842224	0.14
344.3467712	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9237518	4.89
115.9553223	4.46
131.1583557	0.18
131.9924316	0.11
158.9555817	93.05
159.9301758	100.00
186.0675507	0.03
198.9328003	0.41
199.9050293	3.11
202.1718140	0.16
218.0120850	2.23
220.1113281	0.13
227.8046570	0.16
229.0401917	2.95
230.0033264	51.23
246.0455322	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0561
Annotation	Quinic acid
Peak:m/z	Relative Intensity
59.0328827	3.42
60.8747635	1.17
67.1420441	0.70
69.1993103	1.61
70.9353867	8.93
72.9175720	0.48
80.9404449	0.50
83.0238342	3.25
84.9828033	91.65
86.9276886	26.25
92.9043121	48.97
96.9902039	0.43
98.9154205	6.90
101.0762787	0.44
108.9606476	17.63
110.9140930	42.54
112.9854889	1.95
115.0177460	2.39
118.9913788	0.63
126.9894104	100.00
128.9767761	2.66
137.0112152	1.39
143.0627441	1.38
144.6375580	1.40
152.9971161	7.25
154.9094391	11.13
171.0161743	30.77
173.0557709	84.55
191.1196594	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1764
Annotation	Prinsepiol 4-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
165.0311432	1.11
178.0303192	0.42
181.087616	0.15
190.8180847	0.14
193.085556	10.24
195.1079712	1.60
285.0612183	0.63
310.2963867	0.52
315.1444702	0.34
341.1759033	12.26
345.1939697	0.59
352.928894	0.17
355.0473633	1.14
371.0159302	0.57
389.128479	100.00
415.5258789	0.34
431.2858887	0.20
442.755127	0.18
450.0777588	0.14
457.40625	0.10
461.104248	0.69
465.3458862	0.18
471.6038208	0.67
472.9271851	0.10
483.4425659	0.17
490.9794312	3.08
494.9246216	0.40
498.9744873	0.21
504.4395142	0.22
505.0958862	5.87
507.0801392	1.66
513.3286133	0.97
515.1906128	0.15
519.0541382	0.25
533.1043091	2.51
541.7053833	0.47
553.0936279	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1721
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1069946	0.15
155.2209320	0.03
170.9239807	0.42
173.0026703	0.45
191.0424805	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1244
Annotation	1-O-alpha-D-Glucopyranosyl-D-mannitol
Peak:m/z	Relative Intensity
98.9778900	0.13
101.0070648	6.23
106.8421631	0.93
112.9936142	18.44
115.1123810	1.74
118.9307404	8.96
125.0045319	3.38
130.9854431	7.63
133.2359009	0.18
142.9910889	16.14
148.9790649	2.32
160.9645996	14.27
162.9281006	4.47
174.9328156	0.37
178.9840393	100.00
181.0360107	8.95
200.9593811	0.30
253.1611328	0.92
282.9890747	1.43
325.3104248	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
109.070694	0.54
111.8350372	0.18
112.9996643	0.53
116.9181366	0.19
122.9284973	0.87
126.7895813	0.16
137.2190094	0.47
149.1139374	0.59
150.741806	0.16
161.0468903	0.23
162.8257294	0.24
169.0952759	0.28
174.2952728	0.24
177.9938507	0.25
179.1807861	1.11
180.1645966	0.25
181.0048828	0.30
183.1664886	0.82
190.0014038	0.25
193.3912811	0.22
194.2771759	0.48
195.0186615	2.08
205.67836	1.19
207.0496063	6.50
207.9068756	1.34
209.2123871	2.89
217.3052826	0.66
221.0033417	0.12
222.1894073	0.49
223.1226654	5.91
232.4509888	0.13
233.1123657	3.67
235.3436127	0.27
251.0844879	100.00
252.1624298	20.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.0841
Annotation	Unknow
Peak:m/z	Relative Intensity
101.7105331	0.04
103.0336075	0.08
104.0305252	2.04
105.1570282	0.05
114.0095444	0.06
132.9400330	13.00
135.9343567	0.13
143.7385406	0.04
144.9246216	0.05
146.6086121	0.21
148.0452576	0.12
150.0392761	100.00
150.8920898	0.22
156.1186523	0.12
162.1343689	0.12
174.0374756	0.25
175.1365967	0.08
177.1116028	0.12
177.8868256	0.05
178.8188171	0.11
180.1036530	0.58
189.1430054	0.05
193.1644745	0.41
199.5563202	0.21
201.8593750	0.33
211.1383057	0.12
214.0209656	0.10
216.6851196	0.10
218.9557495	0.48
221.5272827	0.06
227.1993103	0.09
234.2729187	0.14
236.0985413	0.13
241.8955994	0.03
251.4915161	0.08
253.0589905	0.21
254.3549805	0.06
257.2278137	0.07
263.0392761	0.20
264.4648132	0.35
267.1461792	0.48
268.2106323	0.11
270.8162231	0.37
278.0979004	0.14
279.9566040	0.44
281.4216614	0.43
282.7058411	0.09
283.4961548	0.12
284.3111572	0.45
288.7209167	0.60
295.9989624	0.29
297.2857056	0.24
299.6670837	0.04
301.1673584	0.08
306.8499451	0.07
313.3766785	0.09
319.0854797	0.36
323.0375977	0.33
324.3960876	2.72
325.0863953	2.34
326.6554260	0.21
327.4583740	0.21
332.6688538	0.13
333.8725586	0.13
342.9042969	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	182.08
Annotation	Epinephrine
Peak:m/z	Relative Intensity
54.95895767	0.92
55.9319725	0.25
57.02902985	0.65
57.98653793	0.20
58.93426132	6.13
60.01002884	4.76
70.90744781	8.97
71.98445892	7.15
73.03943634	6.64
74.00135803	5.64
75.0014267	0.40
81.050354	0.67
82.04692078	0.41
84.1355896	0.70
84.88839722	1.94
85.95010376	3.31
87.02767944	3.04
88.19363403	5.02
88.87412262	29.33
89.8565979	26.70
96.00592041	0.22
96.98638916	1.02
97.91213989	4.37
98.97157288	0.67
100.9752808	31.08
101.980835	53.78
102.7408905	0.50
103.8721313	2.69
108.0852203	0.60
110.2488403	0.48
113.053299	4.30
113.9967651	21.23
114.9961853	2.15
116.0303802	11.04
118.9144745	19.05
119.9945679	30.28
121.8818665	0.46
126.0595398	2.18
127.9804077	2.75
130.9444427	5.77
131.9873352	29.86
134.0879974	0.58
137.9512634	1.05
144.0829926	19.09
146.0888977	1.69
148.8498383	2.07
150.0255585	8.91
161.3181915	1.78
162.0160828	8.79
164.067337	100.00
182.061615	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8351440	0.53
296.3080444	2.52
296.9132080	10.15
328.7171631	0.03
380.6717529	47.03
386.8244629	0.21
424.5474854	0.16
429.0708008	0.07
443.0334473	0.18
461.8268433	0.07
462.4517212	0.10
463.9995117	7.39
464.6569214	61.14
470.1423950	0.54
470.8212280	1.67
484.6112671	0.04
496.6307373	0.53
512.8097534	0.79
526.6707153	0.58
534.6192627	0.09
537.1550903	0.05
538.6103516	0.40
542.4363403	0.45
548.4193726	100.00
549.1929321	0.46
556.0415039	0.09
556.6599731	0.31
567.7361450	0.04
568.8537598	0.14
572.7454224	0.60
586.6128540	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
134.7242279	0.25
143.0993347	0.33
157.0889893	1.96
159.0795288	0.31
165.1466064	0.75
169.2148438	0.32
171.0133057	2.33
173.1006775	0.94
175.0003662	0.15
183.2045898	0.87
185.1401825	2.61
187.0220032	5.13
199.2502136	1.32
201.1956024	4.18
203.2320251	0.27
213.1824341	0.20
215.1888428	2.05
221.2379456	0.41
224.6487732	0.21
227.1486206	1.21
229.1477966	3.89
231.2620239	2.93
241.2666321	1.84
243.3854675	0.32
245.1148071	1.01
247.4812622	0.34
252.9319763	0.56
255.2173767	1.13
257.2220459	5.25
259.1922913	2.14
261.1992188	0.20
263.2650146	3.64
267.1269836	1.10
269.2605591	1.42
270.1742554	0.15
271.1002808	6.71
273.3117065	3.95
283.1312256	2.83
285.1991882	9.46
287.3535767	0.78
295.3110657	1.95
297.1951904	4.08
298.1016235	0.14
299.2870483	10.15
301.2606812	1.56
310.8374939	2.25
311.5780029	2.86
313.2030029	1.08
315.3753662	2.18
321.2033081	3.88
322.1482849	1.13
323.3432922	6.13
325.2482605	0.38
329.5863037	1.77
337.203949	0.52
339.2398376	100.00
340.0754395	1.59
341.2660828	25.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.28
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
241.0758362	0.05
287.1313782	0.03
320.5824585	0.05
325.5466309	0.23
340.7299194	0.11
355.2176514	0.09
431.4779663	0.07
444.5591431	0.05
448.3941040	0.06
460.7736206	0.10
462.2866211	0.55
470.3242188	0.27
471.7573853	0.05
475.4211426	0.05
483.3050537	0.03
485.3778076	0.06
488.3593140	2.91
491.7832031	0.09
496.3859863	0.05
497.7584839	0.03
508.3816528	0.32
520.2511597	22.20
521.2302856	0.12
535.1902466	0.18
541.4147949	1.62
565.2017822	0.24
573.6000977	0.03
581.5506592	0.05
583.4054565	1.66
585.2760620	18.97
591.3851929	0.06
599.0913086	0.22
599.7366943	0.04
600.3743286	0.43
601.3641968	1.92
603.4719849	0.08
615.3124390	0.03
617.3076172	69.03
618.0122681	0.06
619.2760010	0.08
627.3104858	20.50
627.9219360	0.07
630.6416626	0.03
632.3088379	0.25
633.2026367	0.07
641.3380737	0.37
644.2359009	2.05
645.3207397	100.00
645.9447021	0.67
647.2300415	0.05
659.2788086	39.88
659.9188843	0.08
677.1688232	0.08
678.8829956	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.14
Annotation	Unknow
Peak:m/z	Relative Intensity
98.7591248	0.04
103.1296768	0.07
106.9667664	0.07
109.1943970	0.11
114.1363831	0.03
116.9677124	0.07
123.2412415	0.02
124.9640656	0.03
127.0023727	0.14
132.9681091	0.04
143.1406860	0.04
144.8978424	0.08
149.0734253	0.17
151.0906677	0.05
153.2763977	0.06
156.9255676	0.03
162.9687805	0.14
165.1106873	0.06
169.0708160	0.11
172.9505005	0.08
177.0931091	0.07
179.8535614	0.02
181.0898438	0.08
184.1987305	0.04
185.1282349	0.30
186.9163208	0.02
191.1072083	14.64
192.9983673	0.12
193.7200317	0.07
201.1904297	0.18
203.0492859	0.18
205.2122803	0.13
209.0016479	0.05
212.0295410	0.83
213.1580505	0.87
215.9704285	0.09
218.9206848	0.24
220.1739807	0.04
225.2548523	0.10
227.0414429	0.02
228.7005615	0.10
229.4950867	0.10
230.8854065	0.02
233.1966858	0.05
237.4332581	0.06
239.2374268	0.08
240.3146973	0.06
244.1506042	0.16
247.0855408	0.35
248.9095154	0.02
251.4432373	0.02
252.2908936	0.02
253.1162109	0.45
255.1504517	0.11
257.7371216	0.03
259.0423584	0.34
263.1152954	0.16
264.0350342	0.04
265.0654297	0.38
265.6763916	0.09
266.3347168	0.09
268.1510010	12.14
269.1466370	41.85
269.7509766	0.06
271.1257324	0.26
276.9014282	0.05
278.1106262	0.02
279.0809326	0.47
280.0756531	0.29
281.2124023	0.38
283.0248718	0.09
284.0723267	0.12
287.6210938	0.08
288.8892822	1.45
289.5048218	0.40
293.2132263	0.53
294.2304993	0.06
295.1026001	0.09
296.3076782	0.13
297.0114441	0.11
298.0845642	0.12
302.3502808	0.12
307.1544189	100.00
308.3007202	0.79
309.3136597	0.23
310.2363892	0.14
313.6585693	0.04
316.5293884	0.43
324.0915527	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	770.1786
Annotation	Unknow
Peak:m/z	Relative Intensity
215.8178558	0.11
223.0072327	0.04
229.9377136	0.11
231.0420227	0.62
235.2137756	0.04
235.8792725	0.14
252.5075378	0.07
254.0364380	0.59
256.1075439	0.37
256.8931580	0.20
263.3450928	0.17
264.4696350	0.06
266.1596680	0.97
268.1432190	0.22
272.1830444	0.38
274.0802307	0.18
279.2637024	0.31
280.3229980	0.22
288.1670227	0.67
299.9590454	0.74
305.1124878	0.04
306.1435242	0.72
307.2836304	0.13
313.3038025	0.25
318.4969482	0.08
322.2465210	0.29
323.2476196	0.92
325.0769043	0.04
333.0037842	0.43
334.3241272	0.06
341.1881104	0.04
342.2005005	0.12
344.1953125	0.16
351.1556396	0.82
357.1135559	0.64
358.1008911	0.05
359.3108521	0.21
360.0925293	0.08
367.1370850	0.10
371.1214600	0.12
375.1890259	5.98
376.5138550	0.06
377.2915039	0.24
378.2440186	1.40
382.1555176	0.19
385.2290649	1.37
391.3188477	0.08
392.1145630	0.29
395.2615356	0.50
396.3236694	0.18
399.3082275	0.26
403.2097168	0.68
409.1831665	5.03
411.2716675	0.79
416.0823364	0.29
417.3020020	0.37
419.0425415	0.36
424.1385498	0.29
427.2296143	0.18
429.2333984	7.71
433.2696533	0.10
434.4396973	0.22
437.6430054	0.08
442.3540649	0.83
443.2012329	0.22
445.2903442	0.32
447.2786255	0.36
449.3604126	0.10
452.0969238	0.77
453.2162476	0.15
458.1277466	0.36
459.0997925	0.27
460.2911987	0.97
461.6989746	0.05
463.2258301	1.04
468.1864624	1.77
468.9604492	0.13
470.2448730	0.15
471.3945312	0.08
476.3159180	0.04
478.3504028	0.27
481.2769165	1.00
486.2284546	6.01
493.2515869	0.07
496.3652344	0.07
498.0124512	0.06
500.5338745	0.05
502.0253296	0.40
504.3701172	1.83
505.3887329	0.22
506.1837769	0.16
511.3598022	0.51
512.3215942	0.24
513.3076782	0.44
514.0159912	0.23
516.6948242	0.08
520.2689819	14.97
521.4347534	0.10
522.3733521	0.10
525.2993774	0.17
527.3865356	0.34
529.1388550	0.21
532.0518799	0.21
535.2448120	0.07
538.2601318	13.84
540.1553955	0.74
543.1666870	0.27
545.2147827	1.17
546.0358887	0.04
553.3213501	0.44
555.3537598	2.75
557.0963135	0.52
558.3312378	0.47
559.4782715	0.12
562.5727539	0.21
563.4508057	0.50
565.2669067	0.31
566.3654175	0.04
568.8305054	0.12
570.3350220	0.03
571.3380127	1.40
573.3009644	3.34
574.0876465	0.84
576.3322144	0.27
578.3527222	0.91
579.2769775	0.14
580.4993896	0.07
583.1726074	0.22
586.3093262	0.18
587.3029785	0.41
589.3151245	12.36
590.5386963	0.27
592.0348511	1.43
593.1406250	0.29
594.1801147	0.35
596.4171753	0.82
597.1787720	1.00
598.5629883	0.11
601.3814087	0.11
604.2712402	0.37
605.0748901	0.73
606.1908569	1.78
607.1798096	26.56
608.0717163	0.19
609.6246948	0.25
610.4342651	0.45
612.3175049	0.06
613.2786255	0.11
614.2896118	0.81
615.3443604	1.84
616.5292358	0.30
617.1889038	0.90
622.1553345	2.94
623.2684937	5.16
625.0018921	0.25
627.3174438	0.56
630.2119141	0.79
631.2835083	2.23
632.4304810	0.09
635.3035889	0.03
638.4611206	0.08
640.5404663	9.83
641.2414551	50.83
642.9846802	0.24
643.7135620	0.07
645.1156616	0.04
648.2498779	2.73
649.2794800	7.73
649.9727783	0.15
656.2543335	3.57
657.2328491	0.12
658.3368530	2.35
661.3115234	3.42
666.2348633	3.95
668.2207031	0.39
672.1023560	0.09
674.3345337	14.53
675.3532715	0.58
677.0071411	0.21
681.9909058	1.20
684.3641357	11.55
685.2446899	0.36
688.2092285	0.46
690.3372192	0.55
691.2070923	0.19
692.3836670	8.93
695.2426758	1.20
698.2240601	0.23
699.1925659	0.29
700.2837524	15.75
701.4041138	0.42
702.3552856	5.43
703.3780518	0.06
704.4525757	0.25
706.3499146	1.14
708.4437866	1.04
709.3379517	0.04
712.3286133	0.16
715.8302612	0.20
716.4740601	0.28
718.2070923	98.28
719.3110962	0.49
724.2557983	0.14
726.5296021	0.24
734.1422729	7.52
736.2491455	80.40
736.9652710	0.19
742.9776001	0.07
752.1931152	100.00
753.1460571	2.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9466019	0.01
206.8339691	0.90
212.8623657	0.29
229.0848694	0.07
254.8948059	0.19
266.7667847	0.04
285.1123352	0.04
288.5602722	0.01
290.7388916	100.00
291.3493042	0.32
294.8435669	0.03
296.8925781	0.05
314.8758850	0.45
329.0594482	0.02
329.9953918	0.02
339.3510742	0.06
356.9909668	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.3115
Annotation	neriifolin
Peak:m/z	Relative Intensity
199.1157837	0.02
257.2260742	0.02
353.2833252	0.03
356.1618042	0.08
359.2221680	0.04
371.3128662	0.05
373.1412354	0.04
387.3607788	0.04
399.0278320	0.08
403.3967896	0.03
421.5637817	0.04
427.4909668	0.04
429.5411377	0.26
433.2706299	0.07
437.1739502	0.03
438.3281860	0.06
443.3357544	0.15
445.4754639	0.25
453.4164429	0.62
454.0187988	0.06
459.3828125	0.04
461.4999390	0.22
471.4293213	5.83
472.0441895	0.05
472.8846436	0.09
479.4746094	0.04
486.8230591	0.13
488.1583862	0.04
489.4088745	100.00
490.4927368	0.19
498.0625000	0.03
510.8567505	0.07
515.2812500	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.1238
Annotation	Methyl helianthenoate F glucoside
Peak:m/z	Relative Intensity
100.7778702	0.03
121.2312927	0.15
121.9862213	0.09
123.0900803	0.07
129.0063477	0.15
130.1465149	0.10
147.0568542	0.44
148.9733887	100.00
149.8426666	0.03
165.3161926	0.02
169.9967041	0.02
170.9938660	0.02
173.0824890	0.42
179.1012268	0.32
181.0653229	0.07
191.0355225	2.96
202.8261261	0.21
207.2754059	0.02
221.0129700	0.04
231.3333740	0.07
257.0029907	0.05
259.5109863	0.02
263.0820923	0.04
265.1879272	0.06
272.0985718	0.04
273.7887573	0.02
279.2808228	0.08
281.4572144	0.02
283.2467041	0.05
285.2137451	0.06
291.3223267	0.05
293.2428284	0.66
294.4285889	0.03
295.2261963	0.05
299.1739807	0.04
301.2721252	0.03
307.2304688	0.29
309.1122131	0.37
310.4084778	0.02
311.2189026	0.23
311.9751892	0.03
316.2803955	0.07
317.2648926	0.09
319.0014648	0.13
321.2719727	0.04
322.1674194	0.04
333.2217407	0.02
335.3957520	0.57
337.3451843	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.11
Annotation	Androsin
Peak:m/z	Relative Intensity
102.8234329	0.05
135.9079132	0.18
145.0841980	0.16
164.9698639	100.00
173.3389282	0.05
178.8522339	0.10
181.0054321	0.14
194.9227448	0.06
208.9922180	0.05
216.0314026	0.05
221.1889954	0.03
222.8527832	0.08
225.0236206	0.12
232.9751892	0.11
235.0690613	0.14
235.9817200	0.08
236.9718933	0.14
243.3854980	0.04
250.8651428	0.11
265.3611755	0.10
270.1349487	0.11
281.1331482	1.50
281.9899902	0.04
283.0116577	0.20
290.9750366	0.07
295.3555603	0.07
297.1498413	0.03
307.0859375	0.05
308.5933533	0.22
309.2370911	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2993
Annotation	4-Hydroxysphinganine
Peak:m/z	Relative Intensity
90.96566772	0.09
95.09835815	0.41
97.11703491	0.20
107.0090637	0.22
109.0227661	0.66
111.0141144	0.06
121.1767578	0.12
123.0740662	0.36
124.966507	0.14
134.9811707	0.05
137.2374573	0.06
141.335144	0.04
144.1860657	0.04
145.8972168	0.08
147.1837921	0.02
149.1580048	0.45
150.4057617	0.06
151.0313873	0.09
156.9370422	0.15
161.1604919	0.09
165.1061401	0.28
168.8759155	0.17
170.73703	0.12
177.2003021	0.08
179.2091827	0.04
181.1569214	0.05
183.2132874	0.03
184.2974548	0.02
187.2426147	0.03
189.0492859	0.16
191.5262451	0.11
192.9353485	0.13
197.0529785	0.15
197.9254608	0.08
200.9940948	0.49
204.8672485	0.09
207.0215149	0.05
209.1416321	0.07
210.9640808	0.39
214.917572	0.15
221.2110901	0.25
223.2240601	0.04
225.0130005	0.10
225.630127	0.06
226.3910217	0.06
227.2693176	0.21
229.1929932	0.29
235.4205017	0.19
237.1488037	0.13
239.1303101	0.45
241.0548706	0.05
247.3100281	0.95
251.4177246	0.04
252.4355469	1.04
253.204895	0.42
255.07547	0.07
256.1752319	0.11
256.9619446	0.34
261.1895142	0.12
264.3030396	1.45
265.2970581	2.75
267.7906799	0.07
268.8731689	0.04
270.4338684	1.26
274.6817322	0.03
282.2735596	38.99
283.2269897	0.91
286.6482849	0.03
287.294342	0.05
290.3881226	0.05
293.8833618	0.23
300.2803345	100.00
300.9616089	0.69
309.6243286	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9168
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8672791	0.03
159.0801697	0.14
175.0164490	0.61
229.9942017	0.03
245.1547546	0.20
261.0132141	0.03
273.0710144	3.49
275.0299072	0.04
286.9698486	0.04
289.0097656	100.00
291.1199341	0.04
313.9479370	0.07
328.8289185	0.09
332.0971069	0.04
346.8730469	0.02
349.1152954	0.02
356.0376892	0.01
356.9897766	0.26
358.9805603	0.03
361.2957458	0.01
372.7842407	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.02
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9208832	6.11
95.0558929	0.04
96.8575134	100.00
97.7171478	0.03
113.0870209	0.26
131.0240021	28.80
145.1476288	0.02
153.7511902	0.03
181.3466644	0.03
200.1717682	0.02
211.0201874	3.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1012
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
107.1077576	0.05
116.9410019	0.59
132.8677063	0.05
135.0168762	0.20
136.8746338	0.05
144.9467621	3.64
146.8475952	0.15
154.0729523	0.05
158.9703674	0.13
161.0308838	0.11
163.0438232	100.00
173.3267975	0.25
180.9918671	0.41
182.9407043	0.26
188.3857422	0.08
193.1312256	0.21
194.041275	0.14
200.5891113	0.26
205.0550232	0.11
207.0844116	0.05
213.0074921	0.23
221.2895203	0.06
228.9085083	0.08
231.1947021	0.07
232.7339172	0.09
238.5872498	0.12
239.2934875	0.17
242.8540344	0.05
249.4050903	0.18
251.1907959	0.83
255.1314087	0.07
262.1688843	0.19
267.1192017	0.09
268.3497925	0.07
281.1997375	0.13
283.1428223	0.08
284.2915039	0.18
285.2680664	0.06
294.6348877	0.05
295.4300537	0.20
297.1523743	0.35
298.6188965	0.09
309.1602478	0.24
310.1539307	0.09
311.2166748	0.23
313.8551636	1.18
319.3751831	0.37
324.5272827	0.42
325.5906372	0.19
327.2098389	1.53
330.932251	0.15
332.2072449	0.18
333.0792236	0.19
337.1572876	2.69
338.2101135	0.33
338.820343	0.15
341.4185486	0.17
345.936676	0.41
369.3859558	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
84.88093567	0.26
88.909729	0.30
94.86270142	0.71
97.0173645	0.70
100.8641663	0.28
102.9777832	0.22
105.049881	0.22
107.0974884	1.17
108.9069977	1.33
111.0834351	1.01
119.0662537	0.92
121.1765442	0.21
123.1398315	0.26
123.9568481	0.74
125.0304718	0.66
128.991272	5.36
130.1607971	0.41
132.8589783	0.96
135.1330872	1.81
139.2969666	0.39
145.1556854	0.49
147.0142975	1.17
149.2380524	0.51
150.963974	60.74
152.0687103	2.37
157.019577	0.86
160.6522369	0.46
161.2938538	1.07
163.1101379	0.85
165.0364685	1.14
167.1221924	0.76
168.0988617	0.93
169.0675201	1.52
175.0719757	1.48
179.0336151	1.83
181.9031219	0.64
182.8827362	0.87
184.1139984	0.32
185.1124878	0.94
191.2253571	0.45
193.3552094	0.26
195.0642242	0.25
197.1580658	3.56
198.1230011	0.19
199.1840057	0.70
207.0762787	0.83
208.0749664	0.54
209.1968079	0.20
210.1586456	0.82
210.9089355	1.12
215.1161499	0.49
217.3130341	3.59
225.1148682	5.17
225.9826202	1.42
235.2203827	11.98
238.0865631	8.61
239.0775757	3.88
244.2851715	1.69
251.2837372	1.51
253.0776978	100.00
254.1574097	24.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
94.75959778	0.13
104.8418121	0.14
109.1216888	0.12
119.0240936	0.12
133.178009	0.15
148.9298859	0.35
163.1545868	0.06
169.1216888	0.11
177.0756531	0.23
179.0836639	0.69
180.1446991	0.28
181.0699005	0.32
193.1472321	0.39
193.9485626	0.12
204.8482513	0.29
207.0389557	4.63
208.0660858	1.91
209.0278473	0.13
221.0803528	0.33
222.082016	2.99
223.1206207	3.44
224.0278168	0.76
233.270813	0.28
235.0750885	0.27
251.0830231	100.00
252.1530609	15.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2416
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
88.45682526	0.11
90.81260681	0.24
94.99606323	1.13
97.0273056	3.00
98.90731812	1.07
100.7782135	0.23
107.111557	0.41
109.0042877	1.48
111.0539551	0.45
114.9735336	0.18
119.2099609	0.48
121.1595001	0.23
122.9994507	2.32
124.9080734	0.51
127.0140839	0.49
128.8825378	0.45
131.0949402	0.26
133.1683044	0.40
135.1308899	0.87
137.0959167	0.68
139.0416565	14.81
141.0675659	0.13
143.0465546	0.25
144.9957275	0.26
149.2072449	0.17
151.0522766	0.47
152.9328613	1.18
155.0908051	0.22
156.8966522	0.64
161.2871399	0.46
162.9376831	0.28
165.0544128	0.38
167.1454773	0.98
168.024353	0.21
168.9812469	2.21
171.0985718	0.73
173.0105591	0.10
175.1574707	0.35
176.7518005	0.13
179.1593781	1.94
181.1154785	0.26
182.772644	1.48
183.3726807	0.24
185.0477448	0.98
189.4865417	0.21
191.1191711	0.14
193.2094727	0.45
195.112915	0.96
197.0614624	8.25
198.2183533	0.20
199.1725159	0.93
203.0513611	1.15
208.7199402	0.33
209.4377136	0.25
211.058136	2.60
211.6882324	0.14
213.2126465	0.81
217.143219	0.79
219.2537231	0.50
221.177887	4.25
223.1799622	0.26
225.282074	1.62
227.2425232	0.18
229.2399292	0.22
233.3231201	0.89
235.1828003	1.20
237.2791443	5.77
238.57901	1.03
239.1859131	10.67
241.0392151	0.20
243.1590576	0.66
249.0327148	0.18
251.1398621	0.90
253.2634277	2.39
255.263031	2.30
256.477356	0.76
257.3037415	0.25
261.3138123	3.03
269.1591797	0.82
270.3527832	0.10
279.2345886	100.00
280.1447754	0.56
288.1571045	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1194
Annotation	Quinic acid
Peak:m/z	Relative Intensity
108.9795532	0.02
127.0903931	0.23
128.9834900	0.02
170.9715271	0.08
173.0835876	0.21
191.0203705	100.00
365.1979065	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
80.98419952	0.56
84.8993988	0.65
93.01129913	0.22
94.88632965	0.66
102.960144	1.14
105.0462646	0.31
106.471756	0.73
107.1509857	0.63
108.9245453	1.81
118.8415527	0.16
123.0294342	1.98
125.8191071	0.60
127.0830078	1.10
128.9635468	4.05
131.1323395	0.78
133.0336456	0.38
135.0261536	1.31
136.7656555	0.64
138.8578186	0.88
140.94487	1.02
145.1292114	0.49
147.1880341	0.87
150.9852753	61.52
151.9813995	6.56
154.1215668	0.22
154.8711395	1.59
157.1241608	0.94
160.7551422	0.22
164.927948	1.66
167.1270905	2.99
169.1530609	0.46
171.1600494	0.65
173.2342987	0.43
175.307251	0.94
177.0773163	0.73
179.1704254	2.41
182.0714264	0.29
182.9933014	1.51
184.9922485	2.25
186.2588348	0.58
189.1681671	2.12
192.3135681	0.13
193.1927948	0.78
194.0409088	0.66
195.05513	1.72
196.9008636	4.27
198.1919861	1.16
199.0937042	0.28
207.0783844	0.46
208.0015564	0.32
208.9198761	0.26
211.1302185	2.44
211.9253082	0.83
217.1891327	2.74
223.1385803	0.12
225.1680603	3.98
226.291214	1.35
233.2582245	0.16
235.2256317	9.56
238.1749115	7.38
238.9365997	2.06
243.3393707	0.95
244.1023407	0.33
251.0399933	1.02
253.0846558	100.00
254.1417847	17.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8318634	0.17
209.0416870	0.02
290.8615112	0.81
291.6528931	0.03
292.8773804	1.61
335.7332764	0.06
374.5786133	0.45
376.6976929	0.86
414.3048706	0.04
458.5267944	4.34
460.0592041	1.12
460.6702881	10.11
476.4215088	0.05
493.0234985	0.02
539.5265503	0.05
542.5363159	14.23
544.5080566	100.00
545.2564087	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
75.19837952	0.20
129.1259308	0.14
148.9558105	0.48
161.1861115	0.20
167.0011292	0.21
171.3790436	0.13
179.1676178	0.13
193.2520142	1.01
195.0817871	0.17
197.128891	0.30
206.1126404	0.45
207.2919159	3.95
208.0125275	1.83
209.1647491	2.00
221.1141968	0.31
222.1503448	1.77
223.100708	3.31
224.1818085	1.22
233.1296387	1.49
234.0318146	0.19
236.084549	0.13
251.0757904	100.00
252.1820221	15.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1323
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
78.8758469	0.05
83.0625076	0.41
90.9928589	0.05
95.1468124	0.17
96.8564911	0.28
103.2358551	0.07
106.9978180	0.04
108.9837036	0.59
110.9275055	0.75
113.1252441	0.08
119.0114594	0.11
121.0559235	1.77
122.0692902	0.10
123.0663452	0.23
124.8590240	0.25
127.0679169	0.08
131.0805511	0.05
133.0520782	0.46
135.0576782	1.25
137.0983276	0.43
138.7884521	0.02
141.2320099	0.20
142.9978943	0.21
145.0203705	1.40
146.9965210	1.24
149.0407257	2.21
150.0491333	0.48
151.0021515	0.41
153.0471954	0.77
157.2568817	0.41
159.1283722	1.34
160.0471954	0.87
161.0937347	0.70
162.9651794	3.48
163.5929565	0.01
165.0292358	0.17
169.0475464	0.09
170.3509674	0.32
171.1725311	0.25
172.0724030	0.03
173.0784912	1.68
175.1343079	0.16
176.3016357	0.06
177.2317963	0.11
180.5434265	0.11
183.0300140	2.84
185.1741180	1.59
187.0660858	17.47
188.1947784	0.11
189.1110382	1.22
191.1037445	18.03
193.0710297	0.24
196.0883484	0.36
201.0211334	13.27
201.9759064	0.04
203.2318268	4.19
205.0959015	2.80
206.2410431	0.11
211.1533661	6.75
214.1344147	0.03
215.0308075	0.28
219.1620331	1.85
226.3749237	0.04
227.2843018	0.04
229.0864868	100.00
230.1401825	0.17
232.0630493	0.05
247.2120209	0.11
248.2754059	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	770.1738
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0626221	0.09
230.9740601	1.47
232.9895782	0.44
250.2594604	0.02
251.1369629	0.06
256.3165283	0.09
257.1911926	0.05
262.7167053	0.07
265.0370483	0.38
268.2558289	0.05
271.2436218	0.01
283.6909790	0.05
285.1218567	0.02
289.0377197	0.04
301.9429626	0.03
306.2717896	0.05
308.1557007	0.54
310.1461487	0.11
319.2363586	0.02
323.1190796	0.01
327.6611938	0.03
334.0522461	0.19
336.3421021	0.02
340.1156006	0.18
344.3264771	0.05
351.1401367	0.06
352.2258911	0.06
362.2502747	0.12
364.0160522	0.09
368.1649780	0.25
373.0951538	0.04
380.9736938	0.02
385.9985962	0.05
391.2355347	0.12
392.1716309	0.41
395.1289673	0.07
409.1447144	0.85
411.1063843	0.16
413.2146606	0.11
414.1437378	0.05
416.9714355	0.02
419.2443237	0.14
420.0460815	0.11
427.1995239	0.07
431.1210327	0.30
432.4068604	0.02
434.3327637	0.05
437.2583618	0.84
439.1839600	0.06
443.1105957	0.55
445.1304321	0.27
447.1899414	0.05
448.9160156	0.01
463.0892944	0.43
465.1588135	0.08
467.2531738	0.26
468.2161255	0.17
473.2550049	0.02
475.0177612	0.02
477.2254028	0.01
479.0388794	0.04
480.9887695	0.02
485.9859009	0.13
488.2931519	0.10
494.3306885	0.35
495.0813599	0.04
497.2569580	0.31
502.2198486	0.04
503.1477051	0.38
506.2410278	0.04
512.2416382	2.61
513.9697876	0.32
520.1027832	0.71
521.1756592	0.45
522.2404785	0.40
530.4186401	0.22
532.2135620	0.14
538.1818848	2.44
540.2745361	0.63
548.0888672	2.14
549.0714722	0.26
554.3093872	5.22
560.0396729	0.02
566.1412964	39.31
566.8407593	0.04
568.4292603	0.06
572.1303101	1.89
572.8490601	0.07
574.4287109	0.17
577.8829956	0.06
583.9485474	0.02
586.1508179	0.03
589.2683716	0.19
592.3798218	0.02
595.0549927	0.09
596.0903320	0.66
604.0634766	0.07
605.3289185	0.06
606.0386353	0.08
606.9447632	0.04
613.1567993	0.19
614.2046509	0.05
615.3702393	0.04
623.1902466	1.96
624.2037354	0.14
629.0646973	0.02
631.0438232	0.35
632.1938477	0.87
633.1782837	0.07
641.2060547	100.00
641.8485107	0.27
643.2484741	0.14
649.2462769	0.72
650.3506470	0.26
657.5054321	0.04
659.2006226	0.05
667.0946655	0.23
674.6284790	0.12
677.2572632	2.36
678.2454834	0.03
689.2144165	0.10
695.1575317	17.36
695.8438721	0.06
700.4567871	0.03
707.1456299	0.77
718.4011841	0.19
725.3008423	0.19
734.3171997	0.13
736.3003540	0.32
752.2376099	9.52
753.1887817	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
86.0110931	0.01
88.8416443	0.07
104.6177826	0.05
122.7643890	100.00
123.5652618	0.03
132.9151001	0.01
144.9358826	0.03
166.1333618	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9509888	0.66
208.8943176	0.24
290.8516541	3.58
292.1236877	0.63
292.9039001	2.38
374.7720337	1.50
376.6278076	1.07
394.9998169	0.02
454.8944702	0.04
458.5484009	8.29
460.1204224	6.37
460.7848511	12.00
497.9295044	0.04
504.7127075	0.10
542.5033569	28.60
544.4583740	100.00
545.1928101	0.43
546.2154541	0.14
546.8197632	0.12
566.8032837	0.06
574.3764648	0.06
575.7919922	0.13
576.8342896	0.20
582.9492798	0.02
590.5571289	0.09
592.3800659	0.03
604.2615356	0.09
605.5986328	0.24
606.4841919	0.45
618.2634888	0.14
626.3870239	2.84
627.8303833	5.88
628.4336548	22.18
629.0815430	0.15
630.9973145	0.10
647.1872559	0.08
649.0330811	0.13
652.8334961	0.02
666.6668091	0.96
694.9453735	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.0616
Annotation	Calcium Gluceptate
Peak:m/z	Relative Intensity
163.1583557	0.02
179.0077667	0.13
181.0556946	100.00
181.8837128	0.03
207.2301178	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2836
Annotation	Halisphingosine A
Peak:m/z	Relative Intensity
90.80222321	0.26
92.74462891	0.15
94.0160675	0.13
95.02459717	2.02
95.7989502	0.17
97.01737976	0.37
99.8272171	0.12
100.7242203	0.05
101.8903427	0.10
104.9595947	0.48
106.9605103	0.57
107.9246902	0.07
109.0253143	1.55
111.0041199	1.24
111.9480896	0.36
113.1028748	0.15
114.9050064	0.24
116.1346512	0.10
117.1659851	0.05
119.0902405	0.51
120.9823837	0.99
122.1529236	0.18
123.0626755	1.60
123.806221	0.04
124.5442047	0.09
125.1967468	0.59
127.016243	0.09
130.1387329	0.27
133.108902	0.86
135.0336761	1.16
137.0929871	2.11
140.01474	0.08
140.9178162	0.14
143.1411133	0.05
147.0168457	0.61
149.0349121	0.95
150.9776917	0.72
154.8838501	0.32
156.1335449	0.07
157.2273407	0.20
158.0940857	0.11
161.0840912	1.38
163.0849304	0.23
164.9277496	0.25
168.4747925	0.04
169.1298828	0.32
170.1803894	0.18
170.9568176	0.25
175.2250824	0.80
177.1229858	0.36
178.1100922	0.11
181.1865845	0.05
183.2613525	0.07
187.3430328	0.07
188.154953	0.19
189.1398926	0.20
190.9821777	0.17
195.8251801	0.11
198.2798767	0.49
198.9417114	0.10
200.1195679	0.14
202.9462585	0.04
207.2578125	0.55
209.8696899	0.08
213.8360291	0.12
214.464325	0.18
217.0847778	0.28
219.2872009	0.46
221.1732483	1.24
222.0366211	0.12
222.9360962	0.22
224.1364136	0.08
225.0822144	0.34
226.1437988	0.46
227.4715881	0.06
229.2626038	0.03
231.0566711	0.07
233.1693726	2.12
236.2263489	0.12
237.1326904	0.63
238.4442139	0.44
239.2394714	2.64
241.2218018	0.06
242.2832642	1.01
244.5377502	0.42
245.2349854	1.80
249.3198547	0.06
250.3383179	1.71
251.1855469	1.90
252.3415222	0.21
253.4631958	0.28
254.3637085	0.40
256.4042358	0.23
261.3362732	0.40
262.302063	4.80
263.2555542	3.38
263.8973389	0.36
265.2457886	0.17
267.2092896	1.73
268.4029541	2.16
270.0510559	0.44
270.9853516	0.17
271.9497681	0.14
274.2589722	0.48
275.0641174	0.14
276.1235962	0.12
280.2866821	58.34
281.0608521	1.97
282.451416	0.06
283.0935974	0.22
284.2488403	0.21
287.2758484	0.10
288.1831665	0.08
295.3067627	0.12
298.2752991	100.00
299.2168274	1.66
306.6594849	0.53
307.3648682	0.46
316.484436	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.0876236	0.37
81.11006165	1.54
82.39282227	0.14
83.1599884	1.05
84.98669434	0.43
86.69920349	0.50
92.8782959	1.42
95.02729034	4.03
96.01667786	1.91
97.06324005	3.41
98.96955872	0.82
103.0275879	0.48
104.9685211	0.51
106.9177551	0.33
108.9018097	2.53
111.0670776	3.64
113.0385284	0.93
117.0726929	0.50
120.9860077	2.55
122.9358368	3.80
125.2428894	0.31
128.9539185	5.48
132.9987183	1.27
135.069809	3.03
137.0826569	3.27
140.9142914	1.77
142.934082	0.52
147.0181274	1.38
149.1033478	1.28
150.9362335	56.93
152.0522003	3.34
153.037384	0.29
155.2999725	1.89
157.0458832	0.27
158.1730804	1.01
162.8824615	1.48
165.093338	1.09
166.1571503	1.12
167.0704346	4.89
168.983078	3.98
171.0718536	2.23
173.1651459	2.44
175.1576538	0.95
177.2967072	4.02
178.1892853	0.71
181.1215973	1.80
183.1184845	2.11
185.1551971	2.28
187.1931305	1.41
190.1665497	0.22
191.2561646	0.74
192.1507416	1.05
192.8717499	3.29
193.584671	0.33
195.1704102	2.49
196.0631866	0.33
197.1515198	3.46
205.3053741	0.33
207.0478516	2.90
209.3245239	0.51
210.0594482	0.24
211.120285	2.57
217.1933746	12.43
220.8365631	0.47
225.1569061	10.82
235.2325897	37.86
236.0726166	0.80
236.7692719	0.30
238.0216827	8.04
239.121048	0.51
244.2499237	1.06
251.1917114	0.98
253.0875854	100.00
254.1635132	13.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9582
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9039307	0.20
142.0275726	0.14
155.8552094	0.70
170.0642700	0.85
173.1559906	0.05
182.0546570	0.12
183.9139709	1.06
197.8576355	0.20
199.9642487	19.88
200.9597015	0.74
214.0036926	3.38
218.0686493	0.50
227.1664734	0.30
228.0051880	0.79
239.8780212	0.12
241.3224792	0.11
242.2301331	0.38
243.8441162	7.45
245.8092041	1.02
257.9765930	76.32
260.0025635	0.22
262.0168762	3.05
267.8696289	0.33
281.2329407	0.11
283.9591064	0.76
285.8557434	4.17
287.8542480	9.95
288.6073608	0.07
289.8832397	1.62
300.0816650	0.06
301.8351440	47.36
303.1390381	0.17
304.0250549	3.64
314.0882263	1.14
326.0254211	0.08
327.8894653	2.87
329.0343018	1.56
329.8777771	4.77
331.9340210	100.00
332.5581665	1.41
338.1269836	0.05
342.1931763	0.07
345.7230225	21.53
346.3483276	0.36
347.9935608	1.50
357.8901978	0.36
359.6473999	0.10
373.3287659	0.95
373.9414978	2.21
375.5531921	0.28
392.0350647	31.66
399.7516174	3.52
400.3632812	0.17
416.0446777	0.04
417.9025574	64.05
418.5081787	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.83514404	0.53
77.88104248	0.42
79.05952454	0.11
80.93041992	1.02
83.0692215	1.62
84.93373871	0.15
92.85025024	0.20
94.96185303	1.66
96.31826782	0.61
102.9048767	1.37
104.9557953	0.59
106.9387512	0.96
109.0273285	1.19
110.806778	0.48
115.1472778	0.15
118.9807434	0.34
121.1310425	1.24
122.8553467	0.85
124.9334106	0.10
126.9691315	0.37
128.3110352	0.77
128.9729156	5.66
129.9693451	0.76
133.0158844	0.62
135.0838013	1.41
136.983139	0.15
139.0469971	0.28
140.8651276	1.19
142.9555817	0.42
147.0619507	0.50
150.940094	62.86
151.8939972	3.69
153.0581818	1.26
154.0074005	0.29
154.985611	0.44
157.0478973	0.14
159.2727661	0.57
162.6555328	0.19
165.0756073	2.59
165.9749756	1.70
166.962265	2.71
169.1135712	1.06
169.9784393	0.12
171.2302399	0.61
175.2252045	0.48
177.7644806	1.25
179.0740356	3.31
179.7700958	0.51
181.9085846	0.33
183.2123566	1.84
185.1026306	2.77
186.2345123	0.61
187.1783905	0.44
190.1069031	0.40
191.0888977	0.41
193.0939789	0.68
194.0164642	0.39
195.2187195	1.40
197.238678	2.80
198.0161896	0.59
206.1869049	0.72
207.2447052	0.79
209.0751801	0.84
211.0684052	1.64
213.0262604	1.19
217.1959991	5.34
223.9792633	0.48
225.0771942	8.45
226.1405792	1.85
235.1532593	11.36
238.1257324	12.66
244.1094818	2.09
251.1453857	0.18
253.0952606	100.00
254.1767426	19.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.76515198	0.84
79.04086304	0.22
81.04854584	0.95
82.96858978	0.34
85.02357483	0.61
88.86291504	0.12
90.91053772	0.57
93.05567932	0.16
94.80554199	0.70
96.70511627	0.25
98.91619873	0.95
100.6235809	0.12
102.9074707	2.42
104.1180725	0.36
104.8016815	1.46
107.0724487	1.08
108.9714508	1.24
109.816803	0.24
110.7769318	1.88
112.7468262	0.22
114.8886871	0.24
117.0453339	0.60
119.0867462	0.44
121.1226807	1.21
122.9996948	2.32
125.0144958	1.61
125.6801758	0.28
129.0112762	3.18
130.0829163	0.50
130.8486633	0.55
133.0325775	1.69
134.1941528	0.39
135.0355072	3.28
136.9957275	3.46
139.0611267	1.44
140.968399	1.22
145.1649323	0.97
146.9983063	1.72
149.1929169	2.87
150.4308624	2.90
151.0480804	60.47
152.0567627	3.80
153.0863647	0.67
154.1606293	0.17
155.134201	2.30
157.0251923	1.14
159.1485443	1.82
160.9211121	1.85
163.1160736	0.82
165.1773376	1.55
167.0624847	3.45
168.9852142	3.04
170.190567	0.77
170.9995117	0.93
175.1030731	1.14
177.1474762	6.51
179.0572968	0.96
180.0465546	0.25
182.0163727	0.31
183.0640717	1.27
185.1638031	1.34
189.1041412	1.53
190.2393951	0.16
191.0147095	1.54
193.1746521	1.43
194.9636688	2.17
197.061264	2.90
198.964035	0.75
201.2628632	0.32
205.2107086	0.16
207.0311279	1.96
207.9958954	0.25
209.0501709	0.98
211.0938721	3.31
217.2294769	11.48
221.9230499	0.18
223.4561615	0.16
225.120163	12.57
226.131424	1.27
230.0642853	0.39
235.1977081	24.38
236.868103	0.64
238.1660004	9.07
239.2467651	1.27
243.423996	2.05
244.3585663	0.65
251.0797577	1.25
253.0861053	100.00
254.1733856	11.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	194.95
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9741058	0.03
96.8928680	2.64
131.0679321	0.01
132.0405884	0.01
149.0742340	0.01
151.2048187	0.01
159.0586853	0.01
164.9656219	0.01
168.3573456	0.02
176.9180145	100.00
177.8211365	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1764
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0864716	0.06
131.1002960	0.23
137.2752533	0.19
142.8828125	0.04
145.0173645	0.12
160.9446106	0.11
163.0552673	1.06
168.0021820	0.12
177.9025269	0.07
179.0180359	0.22
181.0971375	10.58
183.0629272	0.27
207.0517426	4.80
213.3031006	0.06
223.1116333	0.13
225.1763458	100.00
225.9266968	0.10
243.1855469	2.82
247.2437439	0.05
249.1282349	0.07
269.5329590	0.09
280.9844360	0.05
285.2077026	0.42
286.8457031	0.06
291.2303772	0.15
299.3036194	0.13
303.2248840	0.08
307.2058716	0.16
309.2387695	0.16
311.1553345	0.09
315.1545715	3.37
319.2768555	0.10
329.0199890	0.79
331.0719910	0.22
339.1597290	0.08
343.3977051	0.55
345.2958374	0.07
351.4310913	0.08
359.1506653	0.97
360.6961670	0.62
369.1025085	0.30
372.9896851	0.89
375.1884155	0.58
377.0124817	0.15
385.2004089	0.92
387.2522583	2.29
390.3076782	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.2247
Annotation	Unknow
Peak:m/z	Relative Intensity
341.4444275	0.14
350.0953979	0.06
353.2124023	2.72
498.1083984	0.03
501.1347046	0.14
503.3072510	100.00
532.3279419	0.17
597.2997437	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
79.06736755	0.26
80.81411743	1.76
82.8986969	1.80
84.83509827	0.38
92.05857086	0.45
94.99562073	3.73
96.07195282	0.50
97.11047363	0.27
99.10237122	0.15
102.8666687	0.21
103.6938629	0.33
104.9784546	2.07
106.7713928	0.21
107.9394836	0.81
109.0983582	3.21
111.077652	0.75
113.1040649	0.57
119.1930389	0.44
121.0019226	1.90
122.9874268	1.34
124.9230194	0.44
126.9542389	1.54
128.9567108	5.00
129.8209076	0.15
131.1893463	0.36
132.8797607	0.85
135.0760345	0.89
137.3111725	1.04
140.991684	2.02
143.340744	0.60
149.1508789	1.15
150.9844208	54.44
151.9972229	4.69
154.1262054	0.59
155.0526581	1.14
156.9670868	0.59
158.9289246	0.59
161.1298676	1.14
163.0569305	0.40
165.0012512	0.70
166.2448578	0.14
167.0642853	2.59
169.1295776	4.56
171.2262421	0.99
175.0943146	1.11
177.2708435	0.18
179.2201691	0.43
180.7969666	0.39
182.1618195	0.25
183.1294708	3.78
185.1939545	2.21
188.2041473	1.00
189.1542511	1.96
191.081131	0.62
193.0449829	0.46
194.4549408	0.77
195.163681	2.22
197.1244354	5.45
198.1179352	0.46
199.3525391	0.20
207.1848297	1.59
209.098114	1.39
210.9445953	0.88
217.1710815	5.75
225.1098328	6.36
226.2354126	2.36
235.1663971	18.80
236.3903046	0.40
238.1086426	7.84
239.0653839	1.68
243.997818	3.09
244.7535858	0.51
251.1783905	0.76
253.1066132	100.00
254.1410065	20.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	746.86
Annotation	Unknow
Peak:m/z	Relative Intensity
231.0492096	0.05
246.3721619	0.20
272.9972534	4.17
273.9693604	1.04
274.9844666	1.81
285.9587097	0.37
288.9393311	4.83
289.9398193	0.69
304.5449524	0.05
305.1849365	0.06
386.8892212	2.73
388.0595093	0.98
389.0250244	1.19
389.7329102	0.05
402.9552002	14.99
403.9534302	4.00
405.0125122	4.51
501.0021973	2.36
501.9279785	3.90
502.9532471	4.45
504.1414795	0.22
516.8487549	29.40
517.8374634	24.40
518.8637085	40.60
520.1700439	0.07
532.9010620	0.20
533.9917603	0.18
566.0819702	0.06
587.8779297	0.17
596.9694214	0.14
601.1958008	0.62
616.0588379	1.11
616.8908691	0.51
617.5989380	0.22
630.7971802	31.04
631.8241577	60.25
632.7783813	100.00
633.5725708	0.46
644.1113281	0.11
645.0297241	0.29
645.6767578	0.12
646.6783447	0.28
656.7626343	0.50
671.9755249	0.13
672.9275513	0.66
673.8720093	0.26
682.1550293	0.13
699.8366089	0.25
700.7119141	0.38
702.8498535	0.30
723.7887573	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1011
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9408722	0.02
116.9097748	0.44
134.9920349	0.50
138.9339447	0.01
144.9894409	3.02
147.1645813	0.03
156.8318176	0.04
162.9506378	100.00
175.0447845	0.00
180.8623810	0.11
183.2229614	0.02
185.8977356	0.02
193.1337585	0.16
201.3270264	0.02
204.7000275	0.03
217.0080261	0.01
239.2916260	0.02
250.2342834	0.01
276.3278198	0.00
297.1927795	0.02
308.4384460	0.01
309.1764221	0.05
310.1364441	0.01
314.1368408	0.02
327.1311035	0.07
337.1871338	0.43
337.8447876	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.14
Annotation	X 14847
Peak:m/z	Relative Intensity
95.9871750	0.04
97.0282135	0.12
97.9892578	0.13
100.0393372	0.04
101.9824371	0.09
108.0131073	0.23
108.8648758	0.06
114.0208435	0.23
114.9658966	0.10
125.9210663	0.92
126.8864365	1.31
130.0603333	0.02
144.0369263	2.85
145.0000305	0.14
158.2289429	0.02
159.0399780	0.02
161.9857483	100.00
162.7801514	0.02
214.9114990	0.10
219.1262817	0.13
220.2242737	0.03
230.2385864	0.05
236.1282959	0.06
239.1523132	0.02
245.8853149	0.57
251.9511108	0.07
255.1898804	0.04
262.0875854	0.05
275.1701965	0.06
279.0106812	0.02
280.5593567	0.06
281.4322815	0.02
282.7753296	0.07
285.4290771	0.04
286.8750916	0.12
288.9924927	0.07
296.0191650	0.37
299.6725769	0.02
300.9636841	0.22
302.0883789	0.04
306.0521851	0.16
307.0507812	0.16
310.8277283	0.06
312.9077759	0.15
314.0209656	0.01
316.0064697	0.01
318.8072815	0.23
319.4795227	0.10
321.5429688	0.37
322.2942810	0.05
323.8784790	0.44
325.0207214	0.44
325.8010864	0.20
328.1982422	0.06
333.5021362	0.04
341.3903198	0.02
342.5689087	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.3277
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
160.9895325	0.03
206.1341858	0.04
235.0174561	0.95
253.1312256	8.66
261.4350281	0.10
279.2739258	100.00
356.5278320	0.07
427.2924805	0.06
443.5321045	0.06
444.3134766	0.08
448.2949829	0.13
459.2747803	0.06
469.1958618	0.05
480.1440430	0.06
488.9762573	0.10
507.6180420	0.05
515.1256104	98.11
515.8919067	0.25
517.2255249	0.24
525.1466675	0.19
542.7865601	0.10
543.3887329	0.12
544.0520630	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.22
Annotation	Desacetylvindoline
Peak:m/z	Relative Intensity
194.9958191	1.21
213.3700256	1.33
231.4750366	1.60
233.0387268	11.66
237.8007507	1.24
239.2265015	0.97
242.8484802	3.40
249.3001404	3.65
252.9396973	0.97
265.3093567	2.22
266.9114075	1.51
285.3040771	4.89
293.0922241	1.06
294.9996338	1.76
305.4522095	4.72
311.0794067	5.91
312.8258057	3.18
317.036438	4.27
323.0553284	8.56
330.0373535	1.33
333.5769653	12.31
334.255249	2.94
341.3748169	1.60
342.2355347	2.41
349.2956848	2.82
351.3049622	3.88
353.1979675	100.00
353.8779297	0.95
357.2725525	1.69
359.3591614	1.24
367.2688293	9.42
368.6862488	7.56
369.4582214	2.55
371.3182068	1.24
372.1887817	2.20
376.2967834	6.84
377.2923889	3.27
378.0926208	21.33
381.1175842	3.67
390.775116	1.24
395.2839355	12.10
396.1773987	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	724.64
Annotation	Unknow
Peak:m/z	Relative Intensity
303.0425415	0.40
303.9503784	0.13
304.8392334	0.17
324.0415039	0.13
384.4528809	0.04
386.9720459	0.12
388.6266479	0.31
434.9877930	0.16
442.2500000	0.39
443.5465088	0.07
465.7656250	0.22
470.7535400	2.91
472.6920166	5.59
480.9930420	0.07
495.3012695	0.04
517.3842163	0.05
529.2293091	0.16
531.6301880	0.08
544.7341919	0.37
546.0848999	0.21
550.9012451	0.05
552.0067749	0.83
552.9050293	0.04
554.4924316	8.06
556.0773926	4.27
556.6788940	19.76
558.7240601	0.03
563.0126953	0.12
577.0852661	0.26
579.9420776	0.30
588.2864990	0.20
589.0221558	0.42
591.9750977	0.13
598.0084229	0.29
598.7990723	0.06
604.6215820	0.11
612.9710693	0.09
617.8327637	0.14
638.5325317	9.94
639.9401855	9.24
640.6663208	100.00
641.5952148	0.30
646.6267090	0.03
678.9406738	2.78
682.0325317	0.13
700.7731323	0.13
706.8046875	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0074
Annotation	Unknow
Peak:m/z	Relative Intensity
133.0755157	0.05
151.2864685	0.03
156.8020935	0.14
160.9253387	0.08
173.8350830	0.08
175.0366669	0.11
190.1064758	0.07
197.9030457	0.05
200.0342255	0.43
201.3078918	0.12
209.8495636	0.21
211.8200226	0.37
213.3946075	0.05
216.0361328	0.11
217.9009094	0.33
223.8569336	0.14
229.9604187	0.81
236.1522827	0.20
245.2248535	0.06
246.0486450	0.15
251.1965027	0.06
253.9468384	0.51
255.8610535	0.07
258.0311890	0.70
259.2976990	0.06
263.1552429	0.03
264.2124023	0.07
265.8884888	0.12
267.3090820	0.09
271.8692322	0.14
279.2128906	0.03
283.9492798	0.20
285.2417603	0.05
287.2368774	0.16
290.7657166	0.07
293.0484924	0.09
297.8597412	0.13
301.2061157	0.10
301.9606323	0.46
304.1446533	0.05
305.2445374	0.04
305.9694214	0.65
309.3946228	0.05
312.1840820	0.03
313.1752319	0.16
317.1286316	0.03
317.9721069	0.22
319.9172363	0.05
328.4978943	0.12
329.9607544	0.07
336.0245361	16.75
338.2708740	0.09
339.3544312	0.04
342.1240540	0.14
344.1601868	0.05
345.9482117	0.37
350.1109314	0.04
354.1522217	0.10
359.7241211	0.04
362.0238037	0.08
363.7925720	0.41
364.9685364	0.13
366.0987854	0.08
366.9338684	0.10
368.5837097	0.08
377.9382629	0.15
380.0797424	0.05
382.0165710	100.00
383.0990295	0.10
396.2044373	0.17
397.3628235	0.17
407.4304199	0.82
408.0629883	1.43
408.7648621	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.0877
Annotation	Opuntioside I
Peak:m/z	Relative Intensity
100.8688507	0.02
107.8944244	0.03
109.0488434	1.81
113.0683365	0.02
135.0789337	0.12
143.4940796	0.02
150.9060669	0.07
154.9533386	0.03
157.9759216	0.02
159.0645142	0.08
161.0713348	3.13
192.9812775	0.21
224.9022217	0.04
232.2055664	0.02
245.1840210	0.08
268.9951477	0.02
271.1480408	100.00
273.2605591	0.08
297.0539551	0.03
299.1169739	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.2056580	0.04
290.8287354	4.33
374.6642456	1.22
392.7880859	0.06
418.5361328	0.17
458.5718994	17.51
459.2758789	0.18
502.5770874	0.09
542.5095825	100.00
543.1896973	0.45
581.0498657	0.06
586.6774902	0.36
605.0796509	0.02
625.8573608	6.94
626.5031738	46.67
628.5636597	0.53
646.6835327	0.04
658.5993042	0.15
664.8745728	0.03
688.3402710	0.76
689.1144409	0.04
709.7799683	6.86
710.4464722	66.59
718.1997070	0.06
730.4852905	0.28
734.6754761	0.04
748.4012451	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
77.8855972	0.01
119.9493561	100.00
130.9799347	0.17
136.9630432	0.01
147.8346558	0.68
148.9832764	4.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.74045563	0.15
81.13305664	0.45
83.04707336	0.97
94.95243835	0.48
102.9629059	2.22
104.8579407	0.29
106.9586182	0.95
108.9547882	0.65
116.9593353	0.30
118.8949585	1.74
120.7525024	0.61
123.0357361	1.16
125.0352783	0.17
127.1417084	0.48
129.0186615	6.49
130.0271149	0.72
132.8523865	1.16
135.0915375	0.45
137.0572052	0.23
138.8215027	0.18
141.1257019	1.04
146.6956024	0.33
148.9832611	0.81
151.022171	57.02
152.0964203	5.39
153.1231842	1.41
154.1465759	0.17
155.1585846	0.55
157.0109711	0.12
164.02948	0.13
166.0500031	0.57
167.1666412	0.98
168.9690247	2.21
170.0837555	0.86
171.4102631	0.19
177.2454071	0.86
179.103775	1.79
180.4569244	1.53
181.1342316	0.29
182.1934204	0.37
183.2099152	1.21
185.2551727	1.92
188.9907379	0.26
190.8739166	0.54
193.0569458	0.80
194.0659027	0.61
197.0442657	2.98
207.3999786	0.84
208.023468	0.12
210.1166229	1.16
216.4138031	0.15
217.1383209	2.48
223.178421	0.29
225.1619568	7.04
226.0689087	0.17
235.2087555	7.13
238.1640778	11.18
238.9542694	2.00
241.3403931	0.57
251.124939	0.29
253.0824585	100.00
254.1278534	21.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.294
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
205.0693054	0.08
222.8713379	0.26
227.2100525	0.17
232.7666321	0.20
246.0905304	0.20
247.1194458	0.32
271.4129944	0.13
273.2614746	0.16
287.2341919	0.24
294.9001465	0.09
299.3175354	0.59
300.1035767	1.13
309.3648682	0.56
310.3454895	0.42
311.2578735	1.63
312.1821289	0.06
313.4552002	0.06
315.3175659	1.67
316.2789917	0.44
323.0551758	0.07
324.4145508	0.05
325.3519287	0.25
326.2864380	0.36
331.0079956	0.08
337.2192688	0.39
338.0366211	0.57
339.1240540	0.26
340.1822815	0.61
341.4975281	0.38
355.2309570	0.22
357.2230835	0.65
359.2814941	0.35
370.0352173	0.11
371.6165771	0.29
372.3571777	0.03
382.8615723	0.32
384.2287598	0.32
387.1800537	0.43
401.1887817	1.90
402.2233887	2.30
416.2941895	0.45
423.4194336	0.20
433.1215820	0.78
434.0278931	1.07
439.3709717	0.24
446.6279297	0.18
451.2116089	0.31
455.8627319	0.55
457.9307861	0.33
463.6224365	0.99
464.2604370	2.86
465.3323364	13.69
467.2542114	0.53
476.3183594	0.20
477.4265137	0.86
482.3362427	0.06
483.4296875	0.28
490.4241943	2.67
491.3416138	6.72
495.1646118	1.24
505.5250854	0.16
508.3871460	1.05
509.0692749	7.41
509.9489746	0.08
511.2346802	0.09
515.2238770	2.07
519.1864624	0.22
522.3834229	8.19
523.3295288	24.73
524.1368408	0.39
526.0968628	0.44
527.1818237	0.84
543.1889038	0.16
580.1179199	0.20
583.3521118	0.32
584.2842407	0.31
586.4937744	0.40
587.9947510	1.69
603.3037720	0.48
604.2911987	4.60
611.8088989	0.68
612.4152832	3.98
614.1239624	0.15
614.8768311	0.51
620.2949829	2.46
629.3425293	1.01
630.2883911	14.30
644.3648071	5.91
648.2491455	100.00
648.9398804	1.16
662.1185913	1.72
662.7789307	0.38
680.6627197	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	182.08
Annotation	Epinephrine
Peak:m/z	Relative Intensity
59.00531769	9.91
59.93537903	4.92
70.87887573	8.31
71.9934845	7.41
73.09268188	4.49
74.05576324	5.00
80.93886566	0.17
82.0322876	0.47
82.99185181	1.52
84.82872009	2.48
85.87658691	4.82
86.80284119	3.46
87.97431183	3.68
89.03292084	32.21
90.02095032	30.18
91.05632019	1.34
92.18826294	1.16
97.01942444	0.35
97.86868286	2.41
100.3718262	2.14
101.0019836	27.04
102.00737	56.69
102.9781342	0.81
103.9301605	2.32
106.9785004	0.91
109.8459473	0.26
112.9252167	6.31
113.9131622	15.52
114.9819946	3.82
116.0015411	21.48
118.9091949	22.97
119.855835	33.74
121.8009186	0.34
124.9920807	0.46
125.8509827	1.05
127.9957886	1.65
130.9763641	3.26
132.002121	27.01
137.9308472	0.40
138.5520477	0.17
143.9283142	16.61
145.8565369	2.22
149.8591614	13.43
162.0252228	10.36
164.0730133	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
66.6212082	0.03
68.9700623	0.28
70.0391464	0.06
70.8423386	0.05
71.8844605	0.04
72.8756256	0.14
76.8338699	0.06
78.8716507	0.10
81.6533814	0.42
82.8809357	0.34
83.8263702	0.15
84.8741302	0.15
85.9924393	0.40
87.9257660	0.05
89.8767700	0.07
90.9583740	0.04
96.0440064	0.37
97.9316406	0.14
98.9843140	0.20
99.9323120	0.07
100.9089355	0.10
102.0121307	0.04
107.7803497	0.43
109.1419983	0.12
110.0250397	0.03
110.9902954	0.13
112.1273346	0.15
113.8495026	0.16
114.5642395	0.04
121.8774109	0.75
122.8691406	0.05
123.8274384	0.13
125.1040344	0.18
126.2314148	0.31
128.1274414	0.03
129.1096497	0.03
129.9068909	0.13
133.9873810	0.14
136.9192352	0.12
139.0568542	0.05
140.8611908	0.15
142.6675873	0.19
143.8797150	0.08
153.0911865	0.09
154.1037140	0.63
154.9646912	0.18
155.8692169	0.20
156.9641266	0.14
158.8375397	100.00
160.5764008	0.08
164.0434113	1.00
164.9729767	0.15
168.2904816	0.08
168.9699707	0.04
170.1430054	0.09
171.0873718	0.17
172.0014343	0.58
173.1759186	0.16
176.7294922	1.70
177.9962769	0.19
179.4879761	0.60
181.9015656	1.85
183.0908661	1.57
183.9354706	0.32
185.0402985	0.21
188.1957397	0.55
190.6437073	0.06
191.4847870	1.75
200.1062317	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.6121
Annotation	Unknow
Peak:m/z	Relative Intensity
145.2479095	0.08
145.9108734	0.18
153.0460968	0.08
160.0950012	0.05
167.1047516	0.25
170.2168732	0.11
177.0455322	0.19
178.9444427	1.02
184.0561981	0.07
185.2019653	0.09
197.0080872	1.15
198.2361450	0.06
204.9312134	0.11
213.0355530	0.56
213.9319305	0.05
231.1206360	0.83
236.2293243	0.04
240.4792633	0.41
254.0174866	0.67
255.9037170	0.06
264.2133484	0.25
266.2716980	0.03
270.1018677	0.06
271.3997498	0.07
273.1163635	0.06
278.5542908	0.14
282.3229065	0.14
288.1863098	1.33
289.1118469	0.26
290.0644836	0.13
291.4132690	0.15
294.6891785	0.31
296.3026733	0.12
300.2954102	0.08
302.2272339	0.06
303.2141113	0.49
304.7446289	0.06
306.2133789	0.32
307.5430298	0.27
310.7628174	0.11
318.3248596	0.08
324.0887146	0.20
325.9716492	0.39
327.6249390	0.24
329.0439453	0.08
331.3011780	0.15
336.8434753	0.17
340.8586731	0.16
342.2691040	0.66
347.5412598	0.13
350.8816223	0.14
353.2286377	0.29
354.4394836	0.42
357.0741882	1.02
358.8133240	2.05
359.8742065	0.34
361.8667603	0.32
366.9653320	0.58
367.7349243	1.09
369.2401428	0.22
371.4403687	1.33
374.7333984	0.39
375.6632690	3.00
376.5875854	2.26
378.0237427	0.80
380.4157715	0.80
381.6909790	0.23
383.2599792	0.05
384.6374207	3.32
385.4660645	2.87
386.2752075	0.10
388.9405823	0.17
389.8653259	0.29
390.8000488	0.47
392.1629028	0.25
393.3706360	3.42
394.4757385	0.36
395.2127686	0.50
395.8386841	0.07
397.6405334	0.95
399.4009094	0.39
402.3705139	7.92
403.2424927	1.23
405.0970764	0.31
406.7153625	0.13
409.0722046	0.92
410.3956604	4.15
411.1296997	1.55
412.2716064	0.12
414.3251953	1.00
415.1510620	0.10
417.0844116	0.04
419.3378601	33.97
420.2281189	5.44
420.8371277	0.48
421.5196228	0.40
422.5581055	0.44
423.2148132	0.18
424.2632751	0.59
425.7873230	0.10
427.1366272	3.53
427.9710693	0.46
429.1657715	2.39
429.9930420	0.94
431.1049805	0.24
431.9361572	0.28
433.0778809	0.16
434.7831116	0.04
436.1416321	27.61
437.0119629	5.71
438.5699158	0.34
440.2627869	2.89
441.3432312	0.81
442.7132263	0.44
443.9782410	1.12
444.9056396	2.12
445.9065857	0.72
446.6345520	0.26
447.3778381	0.07
448.9679260	2.98
449.8330078	0.52
450.8586731	0.34
452.8377991	10.99
453.7859497	2.08
455.5545654	0.20
457.8783875	14.68
458.7890320	1.47
459.9186707	0.34
461.9364624	6.55
462.7655945	1.09
463.4745178	0.42
465.8052673	9.10
466.8456116	13.51
467.8287659	2.23
469.0520325	1.27
469.9107361	0.64
474.6710815	51.11
475.3917542	23.43
476.1715393	0.12
478.7372437	0.57
483.8309631	100.00
484.7717896	10.55
486.2765808	0.67
487.1853943	0.18
491.8080139	38.89
492.7543030	3.44
493.4461975	0.05
494.1100464	0.13
496.0897827	0.06
504.8118286	0.29
520.3883667	0.30
521.2841187	0.13
522.2163696	0.13
523.2571411	0.25
524.2308960	0.09
532.0447388	0.34
538.3663940	2.09
539.2623901	0.53
540.2888794	0.40
546.1981201	0.06
558.2196655	0.03
566.4357910	0.05
572.4964600	0.05
573.4288940	0.16
583.2199097	0.42
584.5383911	0.12
589.2226562	0.30
590.2853394	0.20
591.6405029	0.33
592.4088135	0.25
593.3948364	0.09
597.5198364	0.04
607.1608276	1.80
608.1778564	0.70
609.2498779	0.59
612.5163574	0.15
614.2812500	0.14
617.6157837	0.24
624.1220093	0.60
627.3494873	0.19
628.3367310	0.12
631.3813477	0.21
641.2689819	2.59
642.2625122	1.09
643.2009277	0.43
644.1929321	0.46
649.3085327	0.16
660.2339478	0.19
661.2178955	2.73
662.2783813	1.15
662.9631348	0.07
663.5945435	0.27
674.3973999	0.27
675.1873169	0.04
676.2420044	0.15
676.9688110	0.64
686.3823853	0.18
690.3078613	0.17
693.7627563	0.05
694.5150757	0.16
695.6009521	1.19
697.3623047	0.21
700.5028687	0.03
702.1530151	0.07
708.2485962	0.06
709.3200073	0.07
710.4583130	0.08
718.1847534	0.42
719.4141846	0.45
720.0917969	0.07
727.5300903	0.26
736.2067871	0.08
737.6368408	0.04
738.4432373	0.04
743.4633789	0.30
745.2459717	0.21
752.2053833	1.22
753.1470947	0.38
753.9463501	0.34
768.2211304	0.19
769.4703369	0.61
770.2710571	1.40
771.1867676	1.40
772.2951050	0.49
773.4641724	0.24
776.9664917	0.11
778.9111328	0.21
786.9357300	0.29
787.9911499	0.42
789.3431396	0.73
790.5421753	0.30
791.2052612	0.10
792.7363892	0.05
795.2567749	0.26
796.0402832	0.16
803.6014404	0.20
804.3709106	0.04
805.3424072	0.25
806.4205933	0.30
808.3427734	0.06
821.2043457	1.91
822.2222290	0.45
823.3601685	1.31
824.3214722	1.10
825.2265015	0.34
839.3624878	1.88
840.3335571	0.66
841.3087769	0.18
855.3040161	0.43
863.2299194	0.20
864.4008179	0.15
873.3284302	0.20
874.5585938	0.25
875.4329224	0.07
882.3005371	0.10
884.4485474	0.18
925.5241089	0.18
949.9850464	0.05
951.3866577	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.12
Annotation	Carboxybupranolol, 4-chloro-3-[3-(1,1-dimethylethylamino)-2-hydroxy-propyloxy]benzoic acid
Peak:m/z	Relative Intensity
116.0880280	0.06
122.1916656	0.12
132.7256317	0.07
146.1371155	0.05
148.2544861	0.13
151.9247742	0.39
154.1946106	0.07
163.1083069	2.45
164.1090393	7.36
165.0444946	0.07
165.9649658	0.21
168.0579376	0.20
172.2618866	0.03
175.3777771	0.10
176.2479553	0.07
178.2216949	0.07
180.6060486	0.33
181.2120056	1.23
184.0284729	0.65
186.1334839	0.51
188.3767548	0.07
190.0401917	0.32
197.1619720	0.16
197.9871826	0.22
202.9599609	0.14
206.0255127	0.08
211.1510315	0.06
213.3067017	0.08
215.1481628	2.26
216.9889832	0.08
219.2225342	0.10
222.8667297	0.09
226.2415771	0.13
231.1173096	0.16
241.1868896	1.30
242.1092224	0.04
243.0917358	0.31
244.0030518	0.22
250.1896667	0.31
255.0053711	0.12
256.0911255	0.43
257.1593933	0.37
258.1397705	0.14
259.0862732	0.07
260.9102173	4.74
261.8651733	0.26
265.9336548	0.19
267.1494141	10.14
268.1618652	0.11
271.2611389	0.13
273.0976868	100.00
274.8184204	0.45
278.7786255	0.86
279.6788330	0.05
281.0091553	0.95
281.6847534	0.07
284.2002563	5.17
285.2413025	67.10
288.0143433	0.53
289.0913696	0.13
290.0335693	0.09
291.3193359	0.11
293.3872986	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.1186
Annotation	Amotin
Peak:m/z	Relative Intensity
94.98296356	0.27
96.80722046	0.09
97.91801453	0.12
99.0546875	0.05
104.9419098	0.05
109.0399017	0.13
110.8865509	0.20
113.0451965	0.52
115.1397705	0.05
121.1133728	0.22
122.9867096	0.07
137.0758972	0.63
138.6401062	0.10
139.3263855	0.06
147.1373596	0.08
149.0257263	0.33
157.1369019	0.04
158.9990845	0.06
160.2536621	0.09
160.9594116	0.16
163.1059265	0.24
165.1983795	0.30
166.2149353	0.07
168.9547577	0.05
171.0841064	1.35
177.1032104	0.10
183.0076294	0.21
189.1820831	14.42
193.2420197	0.07
198.9210205	0.08
203.1706848	0.07
205.0746155	0.06
207.1733398	2.04
209.0083618	0.05
213.1678162	0.15
223.4548035	0.08
231.063446	0.26
233.0085754	0.91
235.1904297	0.06
239.1488647	0.02
249.0969543	3.26
251.1281738	100.00
254.8851318	0.05
257.7252502	0.03
259.0130615	0.19
264.9721069	0.15
277.1579285	0.90
279.3066406	0.20
280.3120728	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.2
Annotation	Fibrauretinoside A
Peak:m/z	Relative Intensity
167.0552063	0.98
179.1812744	0.74
191.1722717	0.43
209.3389282	1.62
211.2254333	1.55
222.7592621	0.33
241.2488861	1.47
307.1431274	0.98
327.3968506	1.62
331.3373413	0.77
339.2219238	0.53
345.0874023	25.62
355.3617554	0.53
356.1630249	0.76
362.3887329	0.76
375.1511841	100.00
432.0127563	0.36
441.1947021	2.00
450.8956299	1.03
459.4360962	0.33
465.2183228	0.36
477.2698364	0.87
483.4276733	0.73
485.232605	1.73
489.5351562	1.81
491.3879395	2.21
493.5726318	1.05
503.1951294	0.36
505.7241821	0.83
506.8508911	1.18
519.0248413	6.45
527.0808716	2.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1344
Annotation	Semperoside
Peak:m/z	Relative Intensity
113.0975189	0.04
119.2334595	0.14
120.7511826	0.06
131.0947876	0.04
147.0448151	0.06
153.100647	14.85
162.9829712	0.08
171.056015	0.05
178.9981384	0.65
191.0088959	0.17
195.1068878	0.41
197.0750122	100.00
215.164978	0.08
229.1489258	0.05
239.0318298	0.14
243.0344238	0.09
259.9009705	0.11
263.1433716	0.15
264.1715698	0.19
269.0171509	0.53
274.4322205	0.19
287.0828552	0.09
289.0289307	0.09
296.9511719	0.11
299.1119385	0.51
305.2236633	0.11
313.0865479	1.09
315.2756042	1.53
321.2875977	0.09
322.9239807	0.18
329.494751	0.05
341.151062	1.80
344.3493652	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	768.1625
Annotation	Unknow
Peak:m/z	Relative Intensity
226.0780945	0.05
229.1678772	0.12
230.2547913	0.15
231.1133118	0.07
233.8041840	0.05
238.7017670	0.10
240.4052124	0.03
241.1372375	0.13
243.2265930	0.17
246.1339874	0.05
248.1965637	0.08
249.1292419	0.08
254.1290436	0.97
256.5074463	0.05
263.2727661	0.20
264.1470642	0.20
266.1383667	0.35
267.6502991	0.21
272.1087036	0.04
277.0773926	0.11
279.1734009	0.13
280.3534546	0.23
281.1293335	0.15
282.2737427	0.08
283.0778198	0.07
286.1546631	0.10
288.0600281	0.88
290.3819275	0.04
292.5095520	0.07
296.2695618	0.06
297.1917114	0.11
298.1240540	0.04
300.2153320	0.31
301.2604980	0.07
302.0025635	0.17
304.0787964	0.04
306.1035156	0.66
307.9690552	0.40
311.2668762	0.16
314.3191223	0.08
315.3641663	0.04
317.0168762	0.10
318.0203857	0.10
320.0548706	0.83
321.4243774	0.07
323.2363892	1.60
324.3565063	0.17
325.5781555	0.17
326.3156738	0.15
329.3367310	0.18
332.1337891	0.25
333.1946106	0.22
334.3200378	0.02
335.2234497	0.07
338.0037842	0.42
339.2970581	0.04
341.1841431	1.94
342.0906372	0.04
349.3279419	0.17
350.3926392	0.19
351.3209229	0.78
352.5655823	0.05
353.4219360	0.03
355.2297974	0.17
357.4553833	0.26
359.2695312	0.50
360.1658936	0.10
364.3186646	0.05
365.1864624	0.40
366.1818542	0.05
366.8584595	0.02
369.2600098	0.08
372.3351440	0.10
373.1815186	1.26
375.2574463	1.07
376.3300781	0.04
377.2432251	0.43
378.1210938	0.41
383.1735229	0.49
384.4020386	0.02
385.3342285	0.58
389.0482178	1.11
390.1159058	0.10
392.2192993	0.03
395.2265625	0.65
396.1726685	0.24
400.2527466	0.05
401.1210327	0.11
407.2192993	5.05
408.1817017	0.21
409.1060791	0.20
410.1239014	0.19
411.1235352	0.38
414.2705688	0.03
417.2300415	0.04
420.2177734	0.03
422.1580811	0.09
424.1884766	0.07
426.5579834	0.04
427.3114014	0.23
428.6605835	0.84
429.3406372	2.54
430.2362671	0.17
431.0489502	0.11
432.3347778	0.07
433.1926880	0.09
434.4007568	0.13
435.1463013	0.07
440.3464355	0.04
441.2227783	0.31
442.3282471	0.57
443.0318604	0.35
445.2704468	0.14
447.4844971	0.18
452.3419189	1.23
454.3084717	0.25
458.4988403	0.25
459.5808105	0.03
461.1274414	1.88
462.2930298	0.06
463.2845459	0.46
466.2080688	0.22
468.1035156	0.27
470.3641357	0.58
473.0556641	0.09
474.5966797	0.03
476.2328491	0.15
477.3496704	0.45
479.0254517	0.54
480.4842529	0.04
482.0914917	0.04
484.2080078	0.55
486.3479004	3.30
492.3918457	0.08
493.2156372	0.14
494.1414795	0.05
494.9311523	0.16
495.5321045	0.07
498.3535767	0.24
499.2752686	0.03
500.1575317	0.43
502.2836914	0.50
503.2902222	0.25
504.2855225	1.87
505.4862671	0.34
509.2540283	0.10
511.3696899	0.39
512.2208862	0.25
514.3001709	0.45
518.1474609	5.09
519.1493530	0.22
520.2101440	0.37
521.2767334	1.13
522.4028320	0.07
527.3953247	0.41
528.1871948	0.10
529.3408813	0.14
530.2354126	0.46
532.3572388	0.09
534.1843872	0.06
536.2167969	5.44
537.2633667	0.77
538.3795776	1.05
539.3948364	1.31
540.2744751	0.16
543.2046509	0.45
549.4465942	0.10
552.1910400	1.14
553.2808228	0.60
555.3063354	3.12
557.8781128	0.29
558.4894409	0.09
559.2561646	0.03
560.3776245	0.17
561.4266968	0.38
562.4597168	0.20
563.8341064	0.42
564.4407959	0.35
566.3309937	0.05
569.3420410	0.77
570.2543945	2.07
571.2585449	1.21
573.2387695	7.22
574.0296021	0.30
576.6657104	0.33
577.3734741	0.26
579.3004150	0.21
580.3635864	0.11
581.1226196	0.23
581.7883911	0.07
582.5803833	0.26
583.4138794	0.17
585.4207153	0.19
587.2410889	3.30
588.2124023	0.43
589.2470093	0.98
590.0097046	0.27
593.5858154	0.06
594.2825317	0.14
596.7881470	0.49
597.4234009	0.77
598.2406616	0.05
599.5495605	0.16
603.2373047	0.62
605.2766724	21.20
606.4937744	0.92
607.3156128	0.40
608.2611694	0.52
609.1249390	0.29
609.7670898	0.04
611.2216187	0.45
612.2385864	0.52
613.4143066	0.07
614.4822388	0.59
615.3438110	2.54
616.3737793	0.16
621.1123657	4.69
622.0512085	1.19
623.0159302	0.16
624.3292236	0.82
625.3292847	0.08
627.1646729	1.32
628.1677246	0.36
629.1770630	1.33
631.2954712	0.14
632.2116089	0.50
633.2603760	0.14
636.5709839	0.03
639.1797485	28.35
640.2954102	2.37
641.4627075	0.27
642.2671509	0.11
645.4006958	0.03
646.2333374	1.69
647.2199097	3.49
649.2617798	0.77
650.3386230	1.13
654.3256836	1.31
655.0181274	0.14
656.3732300	1.16
658.4242554	1.98
659.3339233	2.39
660.3373413	0.10
662.3439331	0.11
663.4169312	0.50
664.4767456	0.23
665.2941284	0.39
666.2305298	2.18
667.3714600	0.21
668.4935913	0.25
672.2169189	8.43
672.8471069	0.05
675.3676147	0.61
680.3620605	0.79
681.2443237	0.63
682.1576538	0.87
683.1412964	0.18
684.3532104	7.84
688.3055420	0.32
690.2235718	8.45
693.2603760	0.77
698.2640381	4.45
700.2145386	0.61
702.4313965	11.47
704.3997803	0.07
706.3232422	2.33
714.3019409	0.22
716.2315674	37.49
716.9760132	0.43
717.5784302	0.21
724.3051147	0.69
729.1005249	0.05
732.2577515	6.64
734.3091431	63.58
750.2715454	100.00
751.1265869	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1667
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1374817	0.01
179.2511292	0.01
250.7968903	0.01
323.2304688	0.03
341.2315063	0.11
367.4608765	0.10
370.9850464	0.02
383.5229492	0.03
442.7753906	0.06
485.4265137	0.05
503.2036743	100.00
503.8425293	0.19
531.2367554	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.05198669	0.78
110.9066772	0.16
117.0046692	0.14
130.1669617	0.10
137.1601715	0.26
149.1356201	0.26
160.91716	0.17
163.0532227	0.67
169.1421204	0.39
171.0129852	0.14
179.1838837	0.65
180.1827087	0.60
181.0485687	0.06
183.0419617	0.21
191.1241455	0.12
193.108078	0.31
195.3993988	0.34
205.1190491	0.41
207.0179596	4.08
208.1814117	2.12
209.0345917	0.79
221.0111237	0.22
222.1840973	3.07
223.1971588	3.04
224.070755	0.70
233.1650391	0.58
236.0652466	0.16
249.1865997	0.24
251.0691376	100.00
252.0915985	16.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9241638	100.00
212.8045044	41.61
225.3901978	0.06
251.4347229	0.16
267.0513916	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1918
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
153.2729034	0.33
154.0405426	0.06
161.0243225	0.32
161.9827423	0.04
179.0071411	1.50
180.8611450	0.11
190.9836273	0.14
205.4766083	0.23
206.1884003	0.08
223.1407471	0.44
224.4860535	0.98
225.1663513	1.35
255.9926147	0.15
266.9980774	0.15
270.0722961	0.10
271.1712036	0.03
289.3219604	0.09
294.2521362	0.23
303.0538635	0.06
306.2078247	0.37
309.5087891	0.15
337.1289673	0.08
342.2202148	0.06
343.2578735	0.09
361.1695251	0.27
373.3947144	0.06
385.2461853	1.13
387.2243042	100.00
388.1268616	0.15
389.3085022	0.23
390.4065857	0.09
403.0907288	0.46
405.3163147	0.08
410.5339661	0.15
413.2989197	0.13
415.1914673	0.09
415.9748230	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.1453
Annotation	Barbatoflavan
Peak:m/z	Relative Intensity
164.2409973	0.23
167.0489807	0.54
178.6148682	0.16
193.112793	0.92
199.2112427	0.20
207.0439301	0.10
208.875885	0.16
234.946579	0.22
237.2779541	0.32
287.1233826	0.25
289.2484741	0.17
304.6994629	0.14
317.1166992	0.50
331.1682739	0.22
337.9640503	0.08
358.4821777	0.43
361.0950317	100.00
375.2471313	1.63
379.1140747	0.15
399.1382446	0.21
403.1583252	4.75
407.3563232	0.13
412.2909546	0.09
431.5575562	0.09
433.1101074	3.12
436.1820068	0.69
437.2584839	0.13
445.1975098	0.21
463.1295166	2.63
469.520752	0.15
476.8468018	0.38
477.5288696	0.58
479.138855	0.54
481.0305786	0.22
486.93396	0.42
490.2194214	0.34
491.1694946	0.24
505.1621704	1.94
514.7385254	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
96.60354614	0.79
148.9454498	0.61
169.151947	0.21
179.1647491	0.75
179.9497223	0.11
180.9843597	0.85
189.302063	0.25
193.1539154	0.40
197.0275726	0.18
205.0811005	1.02
206.4139709	1.26
207.1814117	3.38
208.0488586	1.35
209.1837921	0.95
221.3039703	0.29
222.3383942	2.02
223.2277222	2.88
224.4079285	0.98
233.098999	1.02
251.0769196	100.00
252.1470795	15.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
104.9234772	0.74
110.9795227	0.34
132.1244812	0.24
148.8446503	0.39
165.1120148	0.21
167.1867371	0.11
169.1377411	0.10
179.2587128	0.39
179.8934937	0.29
180.9752045	0.46
183.2051849	0.14
193.1469421	0.11
193.9361725	0.14
195.0873871	0.27
205.1389618	0.20
205.8326874	0.29
207.1306	2.43
207.9808502	2.42
209.1608124	0.45
221.1345062	0.08
222.0943451	2.87
223.1980896	3.23
224.174057	0.15
233.2423706	0.39
235.1655273	0.28
236.1610565	0.36
251.0823212	100.00
252.1912994	22.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	279.99
Annotation	Unknow
Peak:m/z	Relative Intensity
85.9959869	0.07
87.7189484	0.08
92.8694153	0.02
94.9239654	0.12
111.0519257	0.03
112.1856613	0.10
113.8620148	0.08
117.0370712	0.07
120.9642639	0.03
124.1070251	0.13
125.2293243	0.03
128.0133972	0.03
132.1012573	0.05
135.6849365	0.13
142.6447601	0.14
143.9807434	0.46
147.0223694	0.06
149.0530396	0.33
150.1026917	0.34
152.1108398	0.05
158.2511597	0.15
159.9974670	0.07
162.7042847	0.06
164.4613800	0.11
165.0615234	0.10
167.8796997	1.41
170.1457520	0.12
171.8771210	2.78
173.9656067	0.14
175.8995209	0.23
177.7131958	0.52
180.9924011	0.06
182.8058167	0.26
183.9734802	0.09
185.8955231	0.54
189.0580444	0.07
190.0106964	0.11
193.3751831	0.05
198.0171814	6.62
199.2844543	0.15
200.1914062	0.14
203.7823792	0.21
204.9176331	0.71
206.0354309	0.96
208.7751770	0.13
209.9095459	0.10
212.9893799	0.04
213.8437195	0.28
215.3185730	0.44
215.9395447	0.60
218.2641296	0.11
219.0599060	0.07
219.9254456	0.13
221.1139221	0.32
221.9009399	0.14
224.0988159	0.06
226.0311584	0.46
226.9941101	0.06
231.1939087	0.06
231.8483887	0.30
233.9998474	6.03
235.4396057	0.43
236.1055908	0.32
237.6578369	0.08
238.9955750	2.56
243.8611450	13.83
247.1043091	0.08
249.1401062	0.56
249.9891968	0.30
252.0024414	0.51
256.9318542	0.52
259.1646118	0.12
261.8435669	100.00
263.1152649	0.65
271.0286865	0.23
271.7818604	0.15
279.4687805	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1198
Annotation	1,3-Dicaffeoylquinic acid
Peak:m/z	Relative Intensity
173.0302582	0.10
179.0153046	0.11
190.9928131	1.92
247.1178589	0.15
308.96875	0.77
321.1917114	0.14
335.2115479	1.41
336.1609497	0.07
341.2363281	0.28
351.4896851	0.13
353.0814209	100.00
379.0491943	0.41
399.0917969	0.59
419.5209961	0.51
441.1586914	0.29
469.3814087	0.37
471.3469238	1.42
474.6771851	0.31
478.8446655	0.34
479.5878906	0.18
485.4046021	0.30
495.2193604	0.07
497.3754272	2.20
498.3774414	0.09
501.0727539	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9504013	0.44
86.9838791	1.22
100.9683838	0.05
110.8789062	100.00
111.9169464	0.04
126.8010254	0.11
128.9710388	1.58
130.7593689	1.40
147.0442047	0.09
155.2569733	0.08
172.8965302	21.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.01870728	1.23
91.19232178	0.49
94.95648193	0.32
102.7205658	0.64
104.0025177	0.27
104.9614258	1.07
109.0625305	0.93
122.9088593	1.53
128.9708099	5.95
150.9533844	60.84
151.9717865	2.83
154.7563019	0.69
156.1044159	0.28
166.9110107	0.72
169.0953522	2.14
170.2715607	0.64
171.0962677	0.96
179.2224274	2.06
185.0791016	1.64
186.0901947	0.24
188.8087311	0.38
193.0106659	0.23
197.087326	2.75
198.0967255	0.23
211.054245	0.32
217.2544403	0.17
225.0647125	7.94
235.2855835	0.40
238.0692291	6.25
239.0508423	1.69
251.2990112	0.28
253.0842133	100.00
254.1688385	14.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
74.86686707	0.07
115.1175232	0.11
166.9635315	0.05
169.2646942	0.06
171.1230927	0.09
181.1062012	0.25
186.9312134	0.45
189.1126556	0.09
192.8641815	0.12
197.3357086	0.04
199.1559296	0.58
203.2775726	0.20
206.8479004	0.11
214.8934784	0.60
217.1489868	0.48
218.8686371	0.13
225.0892944	0.52
232.7856293	0.10
243.1414642	100.00
243.7750397	0.41
245.1638794	2.38
245.8952179	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0876
Annotation	Chaenorrhinoside
Peak:m/z	Relative Intensity
96.78044128	0.11
101.0839691	0.08
112.7173157	0.92
118.9879074	0.23
123.1828613	0.10
131.0314636	0.51
134.9427185	5.07
142.9743958	1.11
159.1634827	0.45
160.9822388	0.50
177.1391907	0.20
179.0291748	100.00
194.2164307	0.06
203.1188812	0.38
205.1843109	0.05
210.0955505	0.09
221.1927185	0.13
237.0225525	0.18
240.9073486	0.13
249.2850037	0.23
251.2183228	0.36
257.4313965	0.12
261.3364258	0.04
277.5837402	0.05
280.2269287	0.22
281.0366821	0.59
282.9004822	0.10
295.1575317	2.47
297.3931274	0.28
299.0797424	0.08
305.192627	0.22
313.5942078	0.07
323.0257568	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.0486
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9382019	2.93
96.8179932	100.00
97.7344360	0.11
98.8071594	0.32
207.2352600	0.05
233.0832825	0.13
261.1791992	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.3192
Annotation	Unknow
Peak:m/z	Relative Intensity
255.5311584	0.10
256.4560852	0.05
554.3820190	0.06
625.1758423	0.06
639.4420166	0.28
645.7266235	0.05
675.5437622	0.30
690.9558716	0.06
699.3145142	0.11
701.4938965	0.41
719.5691528	0.17
727.3798828	0.11
760.8282471	0.37
761.4485474	2.53
775.6780396	0.18
777.5713501	0.36
793.6671753	0.19
805.3950806	100.00
807.4775391	0.11
814.8966064	0.06
819.0222778	0.66
819.6329956	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.76
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8157654	0.68
214.9547424	0.72
296.1677246	1.87
296.7717285	11.67
298.2542114	3.27
298.9131165	12.44
323.2177734	1.10
324.1044922	0.37
325.1972046	0.11
378.0435791	0.38
380.6138306	36.56
382.0813599	14.90
382.7639160	59.70
415.1371460	0.06
464.5490112	22.85
465.9290161	17.76
466.6525879	100.00
506.7646484	0.04
531.0676270	0.07
532.9675293	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	981.4498
Annotation	Unknow
Peak:m/z	Relative Intensity
422.3758240	0.37
436.4974976	0.31
549.2660522	0.06
559.5356445	0.39
567.5781250	0.05
597.3903809	1.10
696.4042969	0.23
720.5078125	0.06
772.5124512	0.13
784.4017334	0.04
816.1638184	1.32
827.3389893	0.36
846.3978271	1.68
859.5668945	0.27
860.5234375	0.20
864.4885254	1.48
876.4636230	0.66
877.8436279	0.14
886.4530029	0.17
891.5679932	0.54
894.5505371	2.62
903.2135010	0.24
921.4355469	7.77
922.1104736	0.08
933.5058594	1.65
951.4510498	100.00
952.1827393	0.15
963.4270020	6.52
964.3349609	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
105.0392761	1.02
116.8187408	0.13
149.0618744	0.33
153.2244415	0.33
160.875	0.11
165.3349457	0.08
167.204071	0.16
169.0402374	0.10
177.9700165	0.16
179.1449432	0.39
180.3821259	0.95
181.3131561	0.23
193.1140594	0.16
194.2112274	0.12
195.0611115	0.27
206.157547	0.78
207.0504608	1.84
208.1555023	3.84
209.0818634	0.73
221.0814667	0.27
222.0890961	1.43
223.1557465	3.89
224.4350128	0.11
233.2455597	0.19
235.3800812	0.09
249.8093262	0.08
251.0818634	100.00
252.123291	20.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.28
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
152.9830017	0.33
195.9620361	1.81
214.0532379	1.33
255.2313843	100.00
255.8484497	0.39
269.5833435	0.17
270.3978271	0.12
271.2773743	0.60
272.2713928	0.17
308.2625427	0.55
333.2732849	0.23
335.2045288	0.16
376.8024902	0.48
377.9164734	0.18
406.6517029	0.15
407.3356323	0.33
407.9966736	0.15
416.2382507	0.29
432.314209	0.15
434.2955627	2.08
435.2075195	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	2859-88-3
Peak:m/z	Relative Intensity
72.80440521	0.29
96.85864258	1.01
110.9278564	0.60
119.0623322	0.51
124.8246613	0.50
141.0687714	0.56
148.9482727	2.15
159.3107605	0.37
160.9290619	0.83
173.1532593	0.62
183.3250885	0.29
191.7284088	2.10
193.1342468	1.97
195.0819702	0.79
205.1461487	0.78
206.5087128	0.73
207.1837311	2.79
208.0568695	2.48
209.2231293	5.84
214.9237823	1.16
221.9697113	1.90
223.0104828	4.28
224.3225098	0.62
233.1398163	3.50
251.0627899	100.00
252.1466827	12.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.1616
Annotation	Sch 54445
Peak:m/z	Relative Intensity
174.1449738	0.05
187.0740967	0.23
206.9993744	0.09
212.9591064	0.07
215.0413208	0.90
216.2074585	0.38
217.9765015	0.12
219.0891266	1.10
227.4995117	0.13
233.0208282	3.85
236.1368256	2.71
245.0425568	0.07
251.3296967	0.05
264.9219971	0.08
267.0950012	0.70
273.0503540	0.07
278.9567261	0.43
283.9731445	0.71
291.2339783	0.18
300.0186768	0.28
301.4252930	0.09
302.1588745	0.51
308.2369385	0.70
310.3941040	0.18
317.0625610	0.51
318.1271362	2.84
319.1425781	1.19
322.3142090	0.10
326.1455688	0.13
328.2032471	0.23
329.3096313	0.24
330.1994629	0.05
336.1066284	32.69
344.0951538	1.88
347.3322144	0.47
348.3551025	1.13
352.9703979	0.14
354.0731201	0.50
362.1762695	0.27
365.2125854	14.84
370.2150879	0.15
374.3273926	0.43
380.0244751	0.17
384.8031006	0.42
395.0736694	0.42
399.1997070	0.40
399.9635620	0.09
401.8491211	1.17
402.4711914	0.29
413.2027588	0.81
417.2221680	0.05
419.2989502	0.08
420.1384888	0.15
421.2523804	0.12
423.1103516	0.11
429.3180542	0.15
431.8743896	0.22
433.2545776	1.63
437.1904297	0.42
447.0811768	2.24
450.1572876	4.31
451.1409302	8.95
459.4935913	0.35
465.1531372	23.30
465.7618408	0.12
468.1386719	100.00
468.7969360	0.47
470.6874390	0.06
480.7850952	0.19
482.7433472	0.08
491.0297852	0.05
516.4198608	0.59
527.4999390	0.05
534.4434204	0.11
535.5385132	0.32
544.2107544	0.11
551.2909546	0.09
553.1314087	0.03
561.2748413	0.30
562.2780762	2.23
579.3005371	9.37
580.2728882	17.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1118
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9543762	0.83
99.0824127	0.03
108.9144135	1.07
126.9419632	6.98
129.0477905	0.04
135.0263062	0.15
139.0231934	0.10
144.9826660	8.62
149.2382507	0.07
153.0946198	0.08
156.9233704	0.05
162.9488983	13.58
165.1121674	0.52
169.1455078	0.25
170.9088135	0.02
172.8853455	0.04
175.0393982	0.07
179.1063995	0.06
179.7848816	0.05
180.8503571	0.13
182.7861938	0.04
188.9933014	0.11
191.0302429	0.25
192.3193665	0.07
192.9537659	1.47
194.3888855	0.14
195.0671692	0.24
197.2195129	0.03
198.4606934	0.07
199.0643311	1.34
202.8892517	0.05
204.9808960	0.89
207.1061401	0.34
210.3064575	0.16
211.0867615	1.04
212.0368347	0.13
216.9128113	3.34
222.2866211	0.27
223.0234680	3.36
224.9465942	0.41
229.1215210	2.09
235.0427856	0.44
240.7418823	1.43
241.3902893	0.06
243.0489197	0.74
243.7795410	0.02
247.1239319	3.77
252.9587708	9.03
257.4463501	0.59
258.2135620	2.61
258.9423218	13.17
260.8112793	0.15
261.4232178	0.07
264.9587402	0.05
266.6489258	0.03
268.2115479	1.96
269.1652832	0.77
271.0081177	26.96
275.6347351	0.06
277.0174561	0.13
278.8845825	0.56
280.4585571	0.05
281.3612976	0.06
282.4208374	0.09
283.0960083	0.04
284.0755615	0.12
285.0180969	0.08
286.4583130	0.66
288.1133728	11.42
288.8273315	100.00
289.5097961	0.27
303.5424805	0.03
307.0240784	9.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8537598	0.36
290.8468323	2.22
347.5148315	0.01
372.7952881	0.04
374.5867310	1.07
398.6325684	0.02
413.2004395	0.02
418.8062744	0.04
458.6285400	16.83
460.7383423	0.31
483.0345459	0.01
490.7755737	0.17
497.0056152	0.01
506.6743774	0.05
520.4603882	1.25
521.1201172	0.03
542.5218506	100.00
543.2418823	0.49
562.3644409	0.12
566.6965332	0.54
579.9656372	0.26
580.7131958	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
79.01426697	1.01
80.91140747	0.79
81.83760834	0.12
83.11261749	0.14
84.90700531	0.09
90.77764893	0.37
94.91493225	2.23
98.95146179	0.44
102.9985199	3.75
105.0192566	1.87
106.1116486	0.11
107.0656433	0.39
109.0108032	1.09
111.0580902	1.49
113.0472717	1.18
114.774704	0.61
116.7574158	0.13
119.0901337	0.33
121.01091	0.95
123.0514679	2.48
125.2260895	0.80
127.1957245	0.90
128.029892	0.34
128.9719086	6.02
129.9690399	0.59
131.1555176	0.23
132.9274292	0.56
135.0708771	2.24
137.0709991	0.85
138.9759674	1.18
139.8884125	0.09
141.1003571	1.79
144.8873444	0.13
147.1086426	0.99
148.9844666	1.60
150.9674377	56.74
151.9998474	3.97
153.2380371	0.14
154.2787018	0.53
155.1851044	0.98
157.0700836	0.89
158.0633392	0.31
159.0351868	0.58
161.1755829	0.68
163.0360413	1.45
164.387619	0.41
165.1260529	0.82
166.1210175	1.41
166.9123383	1.37
169.2419586	1.51
170.9427338	2.13
173.1060333	0.48
175.2462158	1.48
176.8401184	1.03
178.0140533	0.22
179.203125	2.02
180.0879059	0.11
181.0760193	0.11
182.0568085	0.77
182.964325	1.48
185.0975189	1.85
186.2989044	0.63
189.995163	0.19
191.0632782	0.19
192.986557	2.85
194.2608948	0.92
195.042511	1.75
197.1650696	5.34
199.223526	0.69
207.041748	1.38
208.1782379	0.31
209.0033875	1.15
210.8954926	2.97
211.7970886	1.10
215.3862457	0.87
217.1925354	11.07
220.8297272	0.11
222.2119446	0.92
223.3992767	0.39
225.0747833	10.57
225.8573761	1.73
228.921936	0.12
233.4367218	0.42
235.0581665	19.45
235.718338	1.02
238.1466217	8.76
239.0922394	1.76
244.2076874	2.75
251.1583252	0.97
253.0787811	100.00
254.2020111	17.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	502.6254
Annotation	Unknow
Peak:m/z	Relative Intensity
162.0924225	0.03
169.8401184	0.02
176.9564362	0.26
179.0961609	0.65
180.1403809	0.06
186.9477234	0.05
188.0409393	0.03
203.4655762	0.07
215.1385956	0.07
229.0330505	0.09
233.0650635	3.08
234.0437622	0.16
243.2581787	0.06
245.1021576	0.29
251.2941284	0.03
262.9450684	0.04
265.0381165	0.02
266.0311890	0.06
272.3737183	0.10
283.0235291	0.08
290.0247192	0.18
308.1459351	6.24
309.2333984	1.42
336.2738647	0.32
340.1928711	0.05
341.1043396	0.05
344.5840454	0.03
352.9835815	0.04
362.2402039	0.09
366.5434875	0.13
369.6239319	0.07
373.6162720	0.23
377.8040771	0.08
392.0441589	0.06
400.8499756	1.28
405.3283997	1.58
411.3274231	0.13
412.2806091	0.06
413.4657593	0.03
414.2380066	0.07
415.5626831	0.10
426.4545898	0.08
429.1408691	0.33
429.7861328	0.14
431.3216858	0.14
438.1797180	0.73
438.9113464	0.20
440.8529663	0.03
442.7799072	0.05
443.9865112	0.08
445.0613098	0.02
448.7248230	0.47
450.1636658	0.05
451.3110046	3.87
452.2748108	0.19
453.5697937	0.04
454.3465271	0.03
456.1949768	1.71
456.8327332	0.48
457.5652771	0.06
459.6377869	0.28
465.3035583	100.00
466.2139587	2.10
467.1805725	0.43
468.0899048	0.10
469.5219421	0.02
470.2665710	0.02
471.2438049	0.16
473.2201233	0.11
475.3528748	0.09
476.7362976	0.50
479.7870178	0.40
483.2500305	0.16
484.8747864	1.14
485.8252563	0.22
489.0794373	0.06
493.6535339	3.18
494.2953491	1.01
495.3770447	0.31
496.5800476	0.07
502.0624390	0.03
514.0685425	0.03
517.4147949	0.06
522.8920288	0.12
540.1521606	3.62
541.2454224	0.51
542.2180176	0.03
550.2653809	0.17
566.2843628	0.07
568.2587280	0.44
569.1744385	0.11
575.9336548	0.02
577.2257690	0.13
585.4627075	0.05
594.2888794	0.26
595.3742676	0.10
621.3652954	0.06
627.2466431	0.06
633.1907959	0.02
643.5029297	0.04
645.3045654	0.13
653.4335938	0.22
660.6492310	0.05
679.2263184	0.72
680.0358887	0.26
681.1983032	0.13
685.5681152	0.04
695.7118530	0.03
697.1551514	12.18
698.2696533	1.93
700.6631470	0.25
715.0197144	0.15
754.3651733	0.07
772.3056030	0.34
800.3698730	0.22
801.3347778	0.07
808.4215698	0.10
820.5678711	0.04
826.1366577	0.82
827.1565552	0.32
827.8606567	0.04
875.3778687	0.29
876.2827148	0.07
911.2561646	0.44
912.1721191	0.07
929.2166138	6.23
930.2354126	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.0614
Annotation	Mono-trans-p-coumaroylmesotartaric acid
Peak:m/z	Relative Intensity
113.1336441	0.07
115.0209198	0.28
119.1120911	0.06
129.0356598	0.33
133.0543060	0.84
145.0544739	0.07
149.0026550	0.19
157.0985107	0.04
160.8253326	0.24
165.2974548	0.06
181.1611328	0.02
182.8850250	0.19
193.0108643	100.00
201.0122833	0.04
213.2258606	0.06
223.2144775	0.13
227.2274170	0.16
229.1082764	0.04
233.1159363	0.04
237.4496155	0.09
246.3781128	0.05
248.6540527	0.04
263.1098328	2.00
264.8890076	0.22
265.5424194	0.09
270.9831848	0.10
273.1149292	0.36
290.0254211	1.04
290.9941406	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
85.0537262	0.15
104.9799652	0.19
109.7515259	0.17
113.1098022	0.24
124.2083435	0.30
131.0711975	0.53
137.846756	0.58
149.0750885	0.46
165.0345612	0.46
168.8599396	0.27
173.0540314	0.40
173.8961182	1.15
175.1732483	0.33
178.100174	0.52
179.0973663	0.39
183.1855011	0.86
188.9125977	0.31
191.0413971	0.88
193.1384125	0.56
195.1014557	1.03
197.1542511	0.24
204.872406	0.74
206.0510101	0.26
207.1584473	6.34
209.1335297	3.50
215.0703888	0.24
222.1088715	4.72
223.0270844	3.41
233.138504	5.32
234.8289948	0.71
251.0701447	100.00
252.171524	20.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
78.83073425	0.14
80.91941833	1.77
82.92768097	1.00
85.06463623	1.05
92.91768646	0.13
94.95397186	3.32
97.00508118	1.39
99.07284546	0.24
101.0349579	0.77
103.0766907	0.35
104.9141998	0.26
106.8066406	1.02
109.0354004	1.01
109.7423706	0.09
113.056427	0.17
115.2535248	0.19
119.2149506	0.30
120.9760437	0.84
123.0093842	2.22
124.8255768	0.53
127.0537872	0.20
128.9439392	4.26
131.2515106	0.13
133.0520477	1.11
135.0585632	0.69
136.8630524	0.64
140.9747925	1.10
144.8323822	0.45
146.9521637	1.27
148.009613	0.79
148.8873749	0.39
151.0008392	52.73
151.9829559	3.87
153.0307159	0.90
153.9186554	1.77
155.0442963	1.54
156.9608917	0.99
161.2670135	1.19
165.0825958	1.63
165.9603271	0.55
166.9985504	1.85
169.0366058	1.44
171.0867615	2.33
173.5045319	0.22
175.0879669	2.23
177.1092987	0.41
178.9726868	1.94
181.2068634	1.16
181.9509735	0.60
184.875473	0.48
186.0535889	1.00
188.4777679	0.88
189.2717896	0.37
191.1393127	0.73
193.2197418	0.75
194.2888031	1.42
195.2204742	2.29
197.1291351	2.93
199.0422211	1.06
207.1997833	1.30
209.038681	1.45
210.4029541	0.83
211.2961578	2.86
217.164093	5.70
222.9617462	0.20
225.0226288	8.16
225.6439667	0.37
235.1566315	19.85
238.1154633	9.53
239.1088409	0.95
244.2331696	0.97
251.1732788	0.33
253.0949554	100.00
254.2069092	15.16
254.931778	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0561
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.7541122	0.42
58.8533020	1.80
60.8808479	1.29
66.8933258	0.51
70.9487991	5.46
73.0919113	0.49
81.1037750	0.60
82.9982452	2.27
84.9996414	77.82
86.9256897	14.43
88.8847504	0.69
92.9877625	42.73
95.0311279	0.20
97.3083649	0.11
99.0310364	4.42
100.9655609	0.99
109.0066071	19.24
110.9974518	38.27
113.1533203	1.20
114.9429321	1.21
125.1611328	0.23
126.9030762	72.75
129.0546875	1.21
131.0657501	0.82
136.9762421	2.17
143.1047363	1.47
144.0709381	0.26
145.1624603	0.84
146.9320831	7.49
152.9979095	3.47
155.0227509	5.76
161.0602417	0.51
163.1393738	1.80
171.0488739	27.98
173.0088806	100.00
176.0782166	0.46
191.0419464	2.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0601
Annotation	Unknow
Peak:m/z	Relative Intensity
180.1723328	0.03
184.0065765	0.05
185.0302734	0.13
189.2145691	0.05
195.1415405	0.13
196.9940338	0.16
200.0558167	0.26
201.1775208	0.13
212.3292847	0.11
215.9666748	0.22
218.9909973	0.13
226.0194092	0.10
234.0057373	0.24
238.9309998	0.07
241.0482941	0.06
245.1882935	0.10
246.2690430	0.07
247.1239624	0.09
251.2450104	0.12
255.2508850	0.10
256.1536865	0.17
258.1092529	0.31
258.9429932	0.08
259.7962646	0.12
260.9750366	0.10
263.9804688	0.13
266.0121155	0.56
266.9460449	0.09
269.1955261	0.41
273.1685791	0.10
274.8170776	0.32
276.0351257	0.68
280.0614624	0.13
285.0409851	0.31
290.0579834	0.54
291.8179321	0.16
292.9631958	0.04
294.3923950	0.06
300.2258911	0.08
305.2750854	0.58
306.0794373	2.17
306.9603271	0.08
308.1900635	0.87
309.9691772	0.10
311.1417847	0.13
314.1453247	0.22
316.1427002	0.11
317.1605835	0.45
318.0162659	0.29
319.6865540	0.08
321.3164673	0.17
323.8797607	0.08
325.1757812	0.16
329.0064697	0.07
330.1270752	0.15
334.4682007	0.53
335.6642456	1.49
338.0420532	0.08
345.9019165	0.12
347.0518188	0.31
350.0236816	0.66
353.4953003	0.04
357.4005127	0.05
358.0886841	0.10
358.9947510	0.33
360.1002197	0.35
361.8517456	0.16
363.3980103	0.36
364.0993652	1.89
364.9942017	0.92
365.9649048	1.24
367.2138672	0.66
369.2568970	0.31
371.2948608	0.21
375.4021606	0.07
379.9310913	0.90
382.0831299	26.72
383.3417358	0.15
384.1008911	0.42
389.3225708	0.68
390.0955811	0.60
393.0393066	0.21
395.0231323	1.74
396.0604858	2.10
397.9452515	3.04
399.2864990	0.06
404.5932617	0.33
407.0314941	4.73
407.9763184	9.76
411.2890015	0.22
414.1649780	0.34
421.3742676	0.14
425.1296997	9.58
425.9322510	35.88
426.9708252	0.90
440.3704834	0.13
441.0769653	0.16
441.8697510	1.47
447.7431030	0.28
453.2644653	0.22
454.3419189	0.24
455.2835693	0.22
456.3079834	0.09
458.1947021	0.08
458.8731079	0.16
460.5325317	0.16
467.2166748	0.12
468.1957397	0.11
469.7820435	0.06
471.2205811	0.09
474.3796997	0.58
475.4672852	0.17
489.4884644	0.59
490.1987915	0.16
492.1809692	0.70
496.3613892	0.14
498.0277710	0.43
499.3203125	1.04
506.9912720	0.06
512.3123169	0.23
513.4258423	0.21
515.3444214	0.46
525.3828125	0.04
526.3823853	0.03
527.2047729	0.18
528.0686646	0.11
531.3931274	0.10
541.4697266	0.87
544.1194458	100.00
551.2734985	0.38
552.1228638	0.16
553.5785522	0.04
560.2030640	0.13
561.0809937	0.14
563.9570923	0.23
568.9627075	1.40
570.2774658	2.59
571.3893433	0.52
576.4114990	0.16
578.9955444	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.4938
Annotation	Unknow
Peak:m/z	Relative Intensity
279.3436890	0.25
291.2250977	0.15
302.1858826	0.03
308.2271118	0.19
315.6879578	0.17
321.0355835	0.10
334.0761719	0.07
336.3275146	0.17
342.9912109	0.21
353.3042603	0.06
400.2284546	0.18
407.4501343	0.10
411.2657471	0.14
460.7223511	0.20
471.3481445	0.10
492.3423462	0.23
513.8563232	0.17
560.1549072	0.39
563.0835571	0.15
565.0777588	0.22
566.0963135	0.06
576.5170288	0.12
590.3428955	0.26
597.0280762	0.10
604.4194946	0.08
607.3523560	6.18
609.2839355	0.53
619.5377808	0.17
627.5367432	0.38
631.4116821	0.13
632.4887695	0.28
637.8250122	0.41
643.5401611	0.09
645.2825317	0.20
647.9959717	0.14
648.7917480	0.23
650.3934937	0.07
653.2290649	0.13
657.9852295	0.27
661.5932007	0.26
663.3635864	100.00
664.0853271	0.14
666.4346313	0.20
675.9069214	0.23
676.7742310	0.09
677.8755493	0.07
679.3045044	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
171.1681671	0.50
195.928894	1.69
210.7500305	0.25
214.1894531	1.33
221.9652405	0.14
225.9968872	0.53
261.3491211	0.34
279.2232666	100.00
280.0162659	1.66
281.8104553	0.50
292.303772	0.60
394.3540955	0.38
398.4920654	0.88
412.059845	0.23
415.2158813	0.55
419.2792053	0.22
422.3503723	0.45
431.7451477	0.56
458.0395508	1.08
461.3760376	0.10
475.7340393	1.42
477.0382385	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
59.0342255	0.02
70.8879242	0.02
84.9066009	0.75
86.9214477	1.17
93.0775909	0.12
99.4096680	0.10
100.6644745	0.07
109.0290070	0.21
110.8888397	100.00
115.0685883	0.03
126.7830353	0.49
128.9759064	2.29
130.9234467	1.01
137.0268555	0.03
146.8723450	0.92
153.0519257	0.03
154.8806305	0.35
170.9678802	0.18
172.9903564	20.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.11
Annotation	alpha-D-Galactosyl-(1->3)-1D-myo-inositol
Peak:m/z	Relative Intensity
98.84901428	7.40
101.0419922	5.30
112.9906845	10.79
118.9614029	7.03
122.8964233	3.24
124.806076	1.59
131.1459351	8.92
137.2424469	1.95
143.2696228	4.39
159.0798187	6.51
160.937149	21.22
173.177063	3.56
179.0546722	61.89
180.9969482	24.06
185.240799	1.83
189.2610779	2.37
190.9547577	2.54
193.0880432	4.50
199.0386505	1.95
207.1842346	4.98
209.1558838	2.78
211.1922607	1.78
213.0559998	3.58
227.1037598	2.61
243.3009949	6.30
250.2002258	1.59
250.8513794	3.32
255.1321411	2.42
257.2119141	2.42
265.1251831	2.42
272.9220886	3.29
277.1976929	4.14
278.9902954	10.15
281.0834351	11.86
295.1760254	29.64
296.1295166	1.12
297.1643982	38.47
298.2904663	3.24
304.9934082	7.93
309.4060974	2.07
311.1785583	0.89
313.1459045	1.59
321.0496216	9.82
323.1067505	100.00
325.3213806	2.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.8864288	0.13
110.9742889	0.11
126.9631653	0.03
135.017395	2.24
136.9954529	0.31
153.0289612	0.06
154.9651337	0.32
161.125946	0.35
171.1830139	0.10
173.0722656	26.68
174.2235718	0.07
178.9631653	19.96
181.1765747	0.08
191.0260468	100.00
199.0182495	0.03
217.0472107	0.26
233.0559998	0.33
237.0483093	0.20
237.8600159	0.09
249.087738	0.19
250.9330444	0.02
254.3560791	0.07
255.160614	0.03
256.1321106	0.03
257.6785889	0.05
261.1049805	0.08
262.9338684	0.24
265.0947266	0.30
274.9388428	0.04
281.2851868	0.02
294.9937744	0.07
299.1343994	0.05
307.1297607	0.41
309.2409058	0.06
311.0855408	0.11
316.0308838	0.05
317.2264099	0.04
323.0451355	0.08
335.2348328	0.53
338.3394775	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1616
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1539001	0.16
173.0543976	3.50
178.9510498	1.49
233.0255280	0.06
281.1330872	0.02
327.2190552	0.05
341.1105957	100.00
341.7860107	0.31
343.1781616	0.07
353.2008667	0.08
381.4043579	0.06
382.1235962	0.10
395.2362671	0.24
427.1542969	0.08
449.6829834	0.16
454.7819824	0.06
469.3005371	0.12
497.4096680	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8431854	15.57
212.8248901	0.14
290.7818604	100.00
296.8838196	0.15
369.0518799	0.08
374.5400085	25.65
375.2767639	0.11
398.8316956	0.67
412.9938965	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.2598
Annotation	11beta-Hydroxy-6alpha,11-dimethylpregn-4-ene-3,20-dione
Peak:m/z	Relative Intensity
102.768837	0.25
108.9414978	1.45
111.0586166	0.42
112.1474457	0.44
112.9663391	0.44
118.5229187	0.26
121.1387863	1.34
122.9906998	1.19
124.359108	0.60
132.0164032	0.28
133.0904541	0.21
135.0261841	3.59
140.980957	0.82
143.0430145	0.16
145.1344604	0.44
146.9299316	0.83
148.9498901	1.14
151.1144409	0.39
154.8935242	0.53
160.9369354	1.25
163.2073975	0.88
173.1032715	0.53
180.2308807	0.72
185.0668945	0.82
187.1083374	2.95
193.1075745	0.62
196.9417725	0.19
199.2255249	1.00
205.1423645	1.03
206.0215149	0.71
206.633255	1.07
209.1364136	0.73
211.1794739	1.27
213.3188171	0.67
217.1016235	1.42
219.1099243	2.78
223.6672974	0.46
224.342804	0.47
226.4535522	1.03
231.0588684	0.30
233.1715393	0.64
239.1645203	0.66
242.2648621	0.28
244.0785217	0.21
245.0631714	3.33
246.2591858	0.52
247.2515869	8.34
249.869812	0.40
251.2476196	15.40
252.9387817	0.77
254.8647766	1.69
259.2600708	1.70
260.1251831	0.66
262.4078369	0.49
263.3208618	0.42
264.1685791	0.68
265.2675171	7.53
267.3504333	1.34
269.2282715	2.37
271.2832642	2.11
273.3635864	1.92
275.0941467	0.35
276.2056274	1.49
277.1358032	0.65
281.0447998	0.66
283.4332886	0.16
284.3634033	0.37
285.2522888	1.08
288.2764587	0.44
291.2003479	0.98
295.4534912	1.86
296.2981567	1.94
298.9476013	0.35
300.1397095	0.23
301.1593018	0.23
301.8010864	0.85
305.2351685	0.44
310.3035889	4.07
313.2460327	3.38
315.1046143	0.94
316.0238647	0.25
317.2346802	1.05
318.1428528	0.62
323.2481995	16.80
324.2166138	1.27
327.1358643	0.21
328.1854858	0.51
337.3054504	0.95
339.33255	0.28
341.2384033	100.00
342.1826172	1.87
350.4516296	1.35
359.0632019	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	212.92
Annotation	Unknow
Peak:m/z	Relative Intensity
85.8810883	0.04
112.9799805	0.03
122.9509888	0.04
126.9754333	0.03
128.8577576	100.00
140.9689331	0.06
145.1162872	0.26
153.3444672	0.02
167.1268921	0.07
167.9741516	0.13
169.0349274	0.15
170.1247711	0.02
178.9203033	0.05
185.0614014	0.13
195.2514038	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.9298401	0.03
111.1738358	0.04
112.878334	0.04
127.0705414	0.03
133.0931396	0.04
134.0696716	0.03
135.0005646	0.46
143.0183868	0.05
155.1924744	0.08
161.0513916	0.24
171.0765991	0.02
173.0705872	1.16
179.0707703	3.82
191.0286102	100.00
208.942749	0.04
217.0679932	0.06
221.2428284	0.03
240.0817566	0.01
241.006012	0.01
262.7634277	0.05
270.9887085	0.02
273.3323364	0.01
281.1312561	0.03
293.1071777	0.02
307.2013855	0.02
309.0841675	0.13
317.2705994	0.04
322.9907837	0.02
324.9206238	0.03
335.2221375	0.04
338.0357666	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
273.0516052	1.65
273.9778442	0.49
275.0545654	1.50
276.2857056	0.10
289.0090332	4.69
289.9729004	0.66
291.0079346	0.97
363.9108276	0.04
387.0630493	0.83
387.9062500	0.06
389.0439453	2.21
402.8958740	13.38
403.9907227	4.49
404.9803467	13.14
444.0454102	0.07
459.2769775	0.08
472.0112915	0.11
502.7828979	0.37
516.8756714	31.73
517.9840088	18.34
518.8566895	100.00
519.5086060	0.19
521.2644653	0.04
542.8336792	0.10
544.9136963	0.03
548.2190552	0.04
549.1253052	0.07
559.0850220	0.04
575.8489990	0.10
586.9412231	0.68
588.9423218	0.54
590.0090332	0.10
602.6572876	0.03
605.0938110	0.11
615.2465820	0.25
650.7974854	0.11
745.1063843	0.19
876.9152832	0.13
989.7028198	0.04
991.6823730	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8752747	100.00
161.0308533	0.03
212.7964172	41.07
235.3362732	0.04
279.2178345	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	365.11
Annotation	10-Hydroxycamptothecin
Peak:m/z	Relative Intensity
120.8321686	0.02
129.9787598	0.08
133.0083313	4.20
141.0896454	0.02
145.8964539	0.03
152.9384766	0.06
162.0697021	0.14
164.8306580	0.02
173.0773621	0.04
174.0444031	0.27
183.0948334	0.30
184.2387390	0.19
185.1168823	1.59
186.5453796	0.05
187.9771118	0.05
190.0982819	0.12
190.9606934	0.03
193.1336823	0.25
193.9308777	0.11
201.0711517	0.79
202.0354309	4.83
203.0757446	2.84
204.5134277	0.05
215.0793762	0.75
215.9728851	0.30
218.1342773	2.74
219.0246277	24.79
230.2105103	0.04
231.5737915	0.06
233.1009827	32.53
236.0203552	100.00
242.7191772	0.03
248.9207458	0.07
251.1193542	0.90
253.1712341	0.09
266.2765808	0.05
274.2116089	4.39
275.1297302	0.28
283.0007324	0.08
284.0915833	0.46
284.9566650	0.19
301.0909424	0.05
302.1699524	1.10
303.3144836	0.05
319.1200562	0.21
321.1436157	0.08
328.5530396	0.07
329.1713257	1.27
330.0266724	0.07
347.0768127	5.15
348.1765747	13.31
356.1754456	0.05
367.0073242	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
72.83755493	0.36
76.82260132	0.89
80.95524597	1.20
82.92717743	0.62
84.96947479	0.60
88.86174774	1.19
95.02215576	4.11
96.97850037	1.90
103.0576019	1.81
104.9651794	2.08
106.9338226	1.00
108.8325806	2.16
110.8641663	1.44
113.1654205	1.39
115.1990967	0.52
116.9949799	0.66
119.066864	1.59
121.0253448	2.69
122.9037628	1.93
125.1382599	1.32
126.8741302	0.26
128.9645081	6.47
130.0748749	0.34
130.9623413	0.25
133.06427	2.75
135.059494	1.53
136.1325684	0.47
137.1168365	2.42
139.0583954	3.49
140.420639	0.75
147.0786591	3.26
149.1468811	1.62
151.0491486	57.71
152.1337585	5.54
154.9673004	3.41
157.041687	1.24
159.1951904	0.83
161.1269989	1.22
163.0800171	0.82
165.0617523	2.20
166.0108032	1.37
167.1485901	0.81
169.2428589	1.80
170.8487549	0.73
175.0978241	3.85
176.4280548	1.27
177.1548615	6.84
178.9992981	5.48
181.0626526	0.38
183.0612183	2.18
184.0961456	0.27
184.9567413	1.38
189.1924438	0.34
191.2533875	1.32
192.1328735	0.59
193.2297516	1.66
195.1453094	5.27
197.1195374	6.32
198.1783905	0.14
199.0750885	0.27
203.1375732	2.12
205.7521973	0.66
207.1754761	1.02
209.1750793	0.87
209.9638062	0.22
211.1026459	6.22
215.3789673	0.32
217.1514893	9.00
223.3897552	0.65
225.1392059	12.60
226.3469238	0.34
229.1728058	1.24
235.0916595	40.39
235.7650604	0.65
238.1265259	10.05
239.1536255	0.66
244.262146	0.79
251.2490082	0.77
253.0872955	100.00
254.1846466	19.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.97
Annotation	Unknow
Peak:m/z	Relative Intensity
118.2479630	0.05
125.8729324	0.04
130.1274109	0.02
131.0556641	0.05
134.1588287	0.02
147.8805237	0.10
160.8664551	0.02
161.9028168	0.07
166.0038452	0.01
169.8522644	0.06
175.1296692	0.04
179.1953430	0.29
182.1026306	0.11
185.7834930	0.04
186.9416504	0.07
196.5659485	0.04
198.1228027	0.07
200.1260986	0.03
201.8009949	0.16
204.8451385	0.05
213.1874237	0.02
215.4251709	0.18
216.0503540	0.80
219.4854126	0.04
229.8210449	0.03
231.3198242	0.02
233.0956116	2.62
234.1102600	0.90
239.0893555	0.05
240.9580078	0.05
246.0037231	0.03
247.0471191	0.02
250.0029297	1.45
251.0412598	13.54
262.1048584	0.02
263.1246338	0.15
273.7497559	0.02
276.1911621	0.08
277.0046082	0.23
289.8856812	0.72
291.2041626	0.03
296.1706848	0.21
298.2645264	0.07
300.1893616	0.04
305.1225891	0.05
307.3439941	0.06
308.1487122	0.04
314.1706238	0.03
315.4791870	0.03
317.4045715	0.54
318.0927734	0.10
322.6895752	0.09
327.3136597	0.06
332.9508362	0.01
334.0850220	0.15
335.9795532	100.00
336.6005554	0.16
337.2895813	0.04
341.0183411	0.10
342.3017273	0.06
343.8404236	0.16
345.4321899	0.10
348.6220093	0.06
351.3334351	0.07
352.5517578	0.01
361.2418823	0.61
362.2265320	1.28
363.3075867	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1606
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
113.0161896	0.07
135.0439453	0.07
136.8973694	0.05
150.9073486	0.08
161.191391	0.10
179.1240387	0.15
181.0865173	0.60
192.8700409	0.02
195.0106201	0.03
197.1823425	16.59
203.2563171	0.10
209.1712036	0.05
221.3274536	0.02
223.201416	0.50
239.3499756	0.09
241.1133728	100.00
246.2449036	0.02
247.4003906	0.08
251.3389587	0.01
254.9759521	0.04
265.0726624	0.17
267.2120667	0.03
279.134552	0.06
283.1690063	1.31
297.2421265	0.03
299.0993042	0.02
304.9510193	0.05
311.569519	0.09
313.1722717	0.79
314.8356018	0.05
324.9922791	0.01
343.1993103	1.20
357.0766296	0.19
358.5090027	0.08
367.2116089	0.11
373.2084656	0.04
373.8843079	0.02
375.4000549	0.08
385.1874084	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9880447	4.79
130.9118042	0.10
157.6516724	0.03
158.9134827	100.00
198.9374084	1.34
199.5443726	0.04
201.1592407	0.03
216.9258423	0.96
227.1853638	0.02
229.0061340	23.81
229.9150391	0.02
245.0445557	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1139
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
112.9271545	0.09
126.8750000	0.02
128.9423523	0.04
139.0836792	0.07
149.0774841	0.03
151.1360626	0.03
153.2432098	0.03
157.2391968	0.08
169.2247925	0.08
175.0614319	0.07
178.9452515	0.06
180.5804291	0.04
187.1666870	0.01
203.0709686	0.11
205.0846405	0.36
207.1448975	0.07
221.2590637	0.06
223.1592102	0.02
231.1231689	0.13
247.3363647	0.03
249.0825500	9.10
252.2225342	0.01
265.3934021	0.09
267.0788269	100.00
267.8395081	0.02
268.5120850	0.03
269.1761475	0.02
275.2010193	0.06
283.2198486	0.08
289.2349548	0.02
295.1139526	0.55
298.4952087	0.01
301.2244568	0.02
305.3131714	0.02
325.2507324	0.37
333.2371216	0.01
337.5815430	0.01
339.1396790	0.33
341.8839111	0.02
343.2958374	0.01
347.4023438	0.02
350.0864258	0.08
355.1929626	0.10
367.2301331	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	270.1538
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
81.8106995	0.07
84.8193817	0.08
89.9938049	0.21
90.8407593	0.14
95.8829193	0.12
96.8665924	0.30
108.0231628	0.16
108.7108765	0.09
120.3684692	0.37
122.0677795	0.06
124.0419769	0.14
124.8784485	0.11
136.2487488	0.14
139.0269775	0.17
140.0135956	0.27
145.0415497	0.06
148.0680084	0.24
150.1726532	0.07
150.9765625	0.05
152.2266388	0.11
158.1507111	0.44
162.7927704	0.13
168.0078888	0.15
169.2490082	0.25
180.6081543	0.49
183.0601044	0.19
185.9710388	0.11
186.9838562	0.16
188.0980377	0.57
190.1145782	0.38
195.2082367	0.19
196.0989990	0.58
197.1942291	0.08
198.3811035	0.07
199.9242249	0.09
206.0517120	0.15
207.1350708	0.18
208.2265167	0.26
209.3326874	0.24
211.0154877	0.14
212.1092072	0.36
213.1682587	0.10
214.3538361	0.08
216.2480011	0.22
224.0304718	1.29
225.0478668	0.09
227.6159363	0.10
228.4751740	0.40
229.0759277	0.19
234.1567841	1.09
239.2390900	0.25
240.0908051	0.17
242.0392303	0.74
247.5845490	0.11
252.3589478	13.84
252.9963989	100.00
253.6532440	0.31
254.9637299	0.22
260.6278381	0.12
261.5591736	0.13
269.9700623	0.12
272.9073486	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2244
Annotation	Citbismine C
Peak:m/z	Relative Intensity
220.7587128	0.03
251.3212891	0.01
339.3667603	0.40
341.0886536	100.00
520.6196289	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.92967987	0.13
78.62636566	0.20
80.46060944	0.41
84.60667419	0.14
91.10682678	0.34
92.99386597	0.54
94.93768311	0.72
96.8445282	0.36
102.9892273	0.10
105.1250305	0.36
106.0195465	0.63
106.9300385	0.25
108.7825775	0.22
109.4755096	0.25
110.966217	0.87
116.8823547	0.30
119.164917	0.59
121.0509644	1.68
123.0761871	1.33
128.9798889	4.71
130.1600037	0.26
131.1572113	0.37
133.0363617	0.89
135.1513062	0.21
136.9605255	1.07
138.9619446	0.85
141.1439514	1.31
142.3928375	0.58
143.1706696	0.20
147.0742035	0.17
149.1613007	0.68
150.9492645	53.05
151.9938354	4.28
153.1168518	1.46
154.0231934	1.48
155.1113739	0.79
157.200943	1.02
160.8330688	0.25
164.9667969	1.33
166.3532867	0.31
167.0193787	1.11
169.1443024	0.85
171.0419769	1.04
172.9619446	0.95
174.8384247	0.42
179.0637054	1.65
180.0966949	0.48
181.1751251	0.69
181.9687653	0.18
182.9409027	0.15
184.9132538	1.57
188.997879	0.48
189.9871521	0.33
195.0367737	0.40
197.0034485	1.76
198.3803558	0.13
199.1713104	0.12
200.4808807	0.20
207.0835876	1.38
207.9844971	0.46
209.1300354	0.74
211.0259705	1.33
216.0591736	0.37
217.2805939	4.28
223.672699	0.59
225.2323761	5.80
226.1717377	0.49
235.1408081	11.18
238.0454712	8.26
238.7453461	0.25
251.2285614	0.48
253.0862579	100.00
254.2004547	14.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.875
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0609589	0.07
174.9469757	1.57
214.8873444	0.05
245.0791779	0.46
260.9152527	0.05
273.0274658	0.86
274.1363831	0.08
275.9085083	0.04
288.9647522	12.34
303.8572998	0.08
305.0108032	5.47
386.9671631	1.43
388.0462036	1.02
389.3074341	0.01
402.9383545	8.04
418.8823242	100.00
419.5067749	0.20
439.1749878	0.05
444.1149902	0.32
448.1235352	0.10
456.7618408	0.04
458.7141724	0.15
460.8700562	0.06
486.0459595	0.16
486.9130859	0.94
504.9585571	0.19
505.9324341	0.03
507.2369995	0.03
514.1233521	0.01
515.1923828	0.13
522.6232910	0.03
523.2534790	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.0616
Annotation	Calcium Gluceptate
Peak:m/z	Relative Intensity
70.7174683	0.03
87.2820511	0.05
88.9523010	0.24
106.7008057	0.06
110.9125977	0.10
113.1163330	0.01
118.9755096	0.45
125.0604553	0.04
129.1755524	0.16
131.0153961	0.04
142.9862976	0.29
149.0282745	0.08
161.0588379	1.09
177.1234131	0.02
178.9330139	100.00
188.5738678	0.03
207.0316162	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9115601	0.80
208.8374634	0.66
290.8352661	6.73
292.8255005	8.93
374.4965820	2.03
375.1972656	0.08
376.6696167	4.97
383.4291382	0.05
456.9735107	0.08
458.6149292	15.81
460.5348511	100.00
461.2681274	0.24
498.6190796	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9581
Annotation	Unknow
Peak:m/z	Relative Intensity
142.0918732	0.16
156.0000763	0.70
170.0781860	1.55
184.0520630	0.72
195.7357330	0.06
197.7840881	0.06
199.9900513	19.91
201.1157379	0.70
214.0456848	4.29
217.8189697	0.46
228.0271912	1.24
228.8659973	0.27
242.1596680	0.12
243.9291382	7.12
245.8354492	0.97
255.3958435	0.13
256.1475830	0.08
257.9427185	74.43
259.8934326	0.09
261.8731079	1.16
268.0331421	0.32
271.5303345	0.09
284.0522461	1.82
285.8695068	3.76
287.9021606	8.43
289.8834229	2.13
294.2034302	0.11
298.5638123	0.23
301.7817993	38.88
302.4239502	0.24
303.9347839	2.38
306.5126953	0.06
312.2277832	0.08
314.0047302	2.41
319.1068115	0.07
328.0013428	3.37
329.3458252	2.55
329.9774780	4.58
331.9911499	100.00
345.8861694	22.85
347.8694458	1.69
358.0793457	0.29
362.0255127	0.07
373.8798523	3.73
375.7239685	0.07
391.9899902	34.85
399.9776917	3.84
401.2704773	0.31
416.0476685	0.05
417.9070740	74.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.3112
Annotation	neriifolin
Peak:m/z	Relative Intensity
173.2242737	0.24
191.0353851	0.07
192.7641907	0.14
210.6515808	0.13
215.1042328	0.13
249.5357056	0.06
257.1846924	0.08
277.0571289	0.10
292.0270691	0.54
293.2254639	0.25
333.3720703	0.13
339.5477295	0.08
357.1492920	0.15
365.2976074	0.26
387.4097290	0.44
398.9854736	0.05
406.2138672	0.09
427.4370728	0.07
429.3850098	0.14
437.2145386	0.08
441.4701538	0.10
445.3543091	0.20
453.5017090	0.95
459.2352905	0.38
471.5099487	7.61
487.0311279	0.26
489.4052734	100.00
490.4619141	0.67
492.0371704	0.21
495.1743774	0.58
515.4130859	2.72
516.1702881	0.25
518.1525879	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9076080	1.57
296.7670288	25.99
378.7324829	0.14
380.5900269	82.45
381.3466187	0.27
462.4776611	0.22
464.4901123	100.00
465.2570801	0.10
501.3812866	0.18
503.1409302	0.11
548.5574341	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1017
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8488464	0.55
181.1511536	0.40
222.7554474	0.19
343.2071533	100.00
387.4017639	0.34
423.2391357	6.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
93.04542542	0.08
108.9165039	0.06
124.9056091	0.08
131.0386505	0.19
149.1304932	0.08
158.9325409	0.03
163.1014862	0.20
166.9330597	0.04
170.8082123	0.07
179.1585083	0.11
181.1991882	0.38
183.3554535	0.07
187.1298065	0.71
187.9871826	0.07
199.3461761	0.14
201.335556	0.16
202.0102081	0.03
202.9515228	0.13
215.1149445	0.44
217.2241058	0.11
225.0970917	0.15
227.3680267	0.11
229.0984344	0.08
243.1468658	100.00
243.7936249	0.25
245.1611938	3.62
245.8247223	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.02
Annotation	Unknow
Peak:m/z	Relative Intensity
92.9582825	0.01
121.3347626	0.01
151.3225708	0.03
155.0167389	0.01
183.2422638	0.02
190.7340088	0.01
202.2449646	0.04
209.5159149	0.04
219.9945984	0.05
224.0039825	11.38
225.0281372	100.00
229.4293365	0.02
238.1625366	0.11
242.3538208	6.27
242.9827728	9.18
243.7147827	0.02
244.7787018	0.11
247.5532379	0.05
248.3820190	0.03
261.2375488	0.03
266.1358948	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.1987
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9930420	0.07
214.8024597	0.04
217.1160889	0.80
226.2846069	0.11
303.0319214	35.04
303.6776733	0.11
318.9885254	0.05
321.0255737	100.00
380.3004761	0.08
399.0479736	0.25
411.1638794	0.09
433.1944580	0.05
442.2061157	0.05
456.4351807	0.12
469.2609863	0.22
471.2015991	0.05
493.1937866	0.05
502.1730347	0.14
517.9888306	0.05
530.4495239	0.10
531.3804321	0.76
565.0089722	0.24
573.4833374	0.08
576.0443726	0.25
577.1041870	0.28
599.1763916	0.09
617.0462036	0.04
618.6174927	0.33
619.2783813	0.03
627.5628052	0.12
643.1669312	0.04
645.2962036	4.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
140.2042999	0.17
153.044281	0.19
196.1011047	3.11
214.1699524	1.45
255.2254944	100.00
255.8410339	0.37
286.4188538	0.07
365.4667969	0.23
391.4773865	0.18
393.3641052	0.08
406.0594177	0.24
409.5368958	0.32
433.816803	0.37
435.4176941	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.69554138	0.20
78.93946838	0.92
80.98381042	0.18
83.02502441	0.19
90.751297	0.17
94.94543457	1.69
102.9223785	0.60
104.9742126	0.25
106.9081879	0.28
109.0183411	0.29
111.0890961	0.27
113.053009	0.27
114.910202	0.11
121.0039215	0.57
125.0710602	0.09
126.9675446	0.46
129.0393829	5.97
133.1183777	0.37
135.0275421	0.78
137.3634491	0.27
138.9772644	0.14
141.1382904	0.17
142.1178741	0.23
147.2829742	0.29
149.1795959	0.66
150.9341583	53.69
151.9919128	4.28
152.8745575	0.60
153.8971558	0.14
157.1251984	0.56
161.2014313	0.57
166.1185608	0.26
167.0153351	1.12
169.0252838	2.44
170.2737274	0.88
171.1232452	0.44
177.1536102	0.87
178.8525696	0.66
180.1313629	0.42
181.0336456	0.82
182.2206116	0.23
183.1108398	0.39
185.2076263	2.98
189.3413239	0.10
191.3122253	0.25
193.7368469	0.75
194.354538	0.17
195.1557465	0.43
197.1561737	2.54
198.0570221	0.46
198.8958588	0.38
203.1578979	0.48
204.8513641	0.13
206.9631805	0.78
207.8111725	0.56
209.0568085	0.25
210.8290405	0.88
212.0159302	0.36
217.1124878	4.87
225.2028809	5.29
235.1438446	12.38
238.1483917	6.94
239.0601807	1.86
251.044632	0.11
253.0776367	100.00
254.0782013	17.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1606
Annotation	6-O-Veratroylcatalpol
Peak:m/z	Relative Intensity
151.7491608	0.65
159.2741852	1.39
167.1324463	7.07
181.1345825	4.51
195.2514648	4.81
245.0397644	0.66
259.1903076	1.27
269.0768433	1.94
301.1289062	0.92
315.3053589	9.17
329.2045288	1.31
345.0966797	2.13
361.1082764	0.69
363.1047363	100.00
365.9835205	0.98
400.7866821	2.52
410.980896	1.03
413.0160522	1.21
429.1467896	1.94
434.9914551	2.78
437.0874023	0.43
438.1730957	0.92
440.8255005	1.48
452.8823242	0.47
479.0536499	3.67
481.0752563	2.41
489.2622681	4.65
491.2792358	0.96
496.7701416	2.23
503.0847778	0.83
507.0148315	2.98
517.8306274	2.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.19
Annotation	Celorbicol
Peak:m/z	Relative Intensity
76.91837311	1.68
80.92290497	0.20
82.72938538	0.46
91.06018066	0.63
92.81123352	0.13
94.30539703	0.11
95.11341858	2.12
97.02816772	1.17
98.85237122	0.46
105.2415314	1.25
106.9421387	1.42
108.9512634	0.37
109.8957825	0.53
110.9466553	0.76
116.8517151	0.17
118.975296	0.35
121.029953	0.46
123.1282654	1.44
125.1382599	0.32
127.0092316	0.42
128.7427368	2.19
131.0969696	0.54
132.9991302	1.88
135.1604004	0.11
137.009903	1.25
138.9654541	0.34
140.5900269	0.38
142.9973755	2.44
144.9747314	0.47
147.1230927	3.88
150.9121704	0.40
152.2413177	0.18
153.1222687	0.67
154.9302673	3.74
157.0030823	2.25
158.2428436	0.74
159.0532227	0.63
160.0875702	0.18
161.1482697	1.48
168.1934204	0.36
169.0382538	1.29
169.7201385	0.12
171.2725372	1.76
173.0283661	0.76
175.0237274	0.87
176.9705505	2.23
181.6690521	0.61
183.1680908	0.69
184.1983795	0.08
186.9993439	1.03
189.0467682	1.07
193.227417	3.70
194.9162598	0.56
196.8843384	1.04
199.161911	0.74
201.1214752	0.78
207.2370911	0.32
208.970871	1.35
210.9838104	2.72
212.2011108	0.25
213.2437439	1.67
214.6709747	1.63
215.3371582	0.13
217.1203461	0.33
220.3705597	0.94
224.7998962	2.03
227.3636322	0.61
229.2035675	3.53
230.1439972	0.62
235.1845856	4.49
235.9123993	0.25
239.0847015	0.52
240.1209259	0.18
241.1556244	0.24
243.2359467	1.63
251.221756	0.35
253.1711273	100.00
254.1726227	0.38
261.7747498	1.88
271.1101685	0.49
275.2733154	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1815
Annotation	Patuletin 3-rhamnoside-7-(3''',4'''-diacetylrhamnoside)
Peak:m/z	Relative Intensity
217.3721619	0.06
295.1173401	0.02
309.1647644	0.04
340.0112305	0.04
353.1029053	100.00
387.0291748	0.03
389.0982666	0.04
391.4346313	0.08
393.2070923	0.13
394.1117554	0.04
402.5977783	0.05
406.3071899	0.04
432.9441528	0.11
463.0730591	0.03
493.4575195	0.10
500.4176636	0.07
506.8528442	0.09
511.3828735	0.04
514.6546631	0.29
515.2658691	0.22
538.1253662	0.10
544.5609131	0.12
545.2220459	0.12
551.3356934	0.03
592.2922974	0.02
617.2668457	0.20
662.8435059	0.16
671.4130859	0.11
673.4917603	0.08
684.6344604	0.31
689.0443726	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1119
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9429703	0.43
98.8232422	0.12
106.0197678	0.03
108.9883728	0.34
110.7890778	0.14
116.8463898	0.04
118.1147079	0.46
118.8714066	0.02
120.9044418	0.10
126.9473114	2.66
130.3370972	0.06
131.1015625	0.03
133.0011444	0.22
134.9667358	0.19
136.8516235	0.19
138.1965027	0.04
139.0723267	0.16
140.2688293	0.09
142.0470886	0.08
144.9028015	3.43
149.4277039	0.09
150.0619965	0.26
151.1980591	0.07
153.0783997	0.10
156.0860291	0.08
157.8683167	0.15
159.1312408	0.12
160.9833679	0.07
162.9078674	5.82
165.1447144	0.11
167.0902100	0.02
168.1746521	0.03
168.9672699	0.12
173.0792542	0.05
175.3046417	0.03
175.9294891	0.02
176.9080811	0.18
179.0736694	0.15
180.2413635	0.06
182.0510406	0.09
183.1192474	0.05
184.0817261	0.58
185.2631531	0.28
186.0225983	1.40
187.7618713	0.02
189.1789398	0.04
191.1536255	0.09
192.9805298	0.39
195.0097961	0.12
197.0824890	0.23
199.1014404	0.45
201.5623779	0.07
202.5290222	0.08
204.0952148	1.94
205.0903931	0.17
207.1001892	0.92
207.7862854	0.11
209.0570068	0.34
210.9421082	0.42
212.1106567	2.55
213.0849304	0.61
217.0033569	0.45
219.1761475	0.16
221.0404053	0.02
222.4614563	0.12
223.0742188	1.46
224.7111816	0.15
225.7633057	0.04
229.1970215	0.62
230.3486938	0.01
232.9487915	0.21
234.1056519	0.19
235.0806274	0.71
235.9699097	0.04
237.0614624	0.46
238.2382202	0.05
238.9432983	0.22
240.6962891	0.70
241.4353333	0.06
243.0717773	0.15
244.1036682	0.37
245.1004333	0.03
247.1350098	1.34
248.3030701	0.04
252.9142761	3.12
254.9776001	0.14
256.2987061	0.07
258.3233032	2.40
259.0326843	3.07
260.9501953	0.27
262.0413208	0.04
263.0760498	0.98
265.3393860	0.30
268.1566467	100.00
269.1500549	39.14
271.0493774	9.86
272.6513367	0.04
275.2221680	0.02
276.8475952	0.09
279.0323792	0.71
280.4443970	0.57
281.1524963	0.38
283.7747803	0.06
284.3935852	0.02
285.0227661	0.04
285.7663574	0.02
288.3394165	8.02
289.0191040	24.82
293.1590881	0.14
294.8215942	0.02
296.2323608	0.04
297.3982544	0.10
299.2564697	0.09
306.4862671	0.73
307.1508179	3.97
308.2610168	0.89
309.3468628	0.21
315.6008911	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9715
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9178772	0.02
157.2230835	0.02
175.3204651	0.03
184.1532898	0.04
187.5672302	0.04
201.9918976	0.10
211.9635315	0.03
231.7150269	0.02
239.0268555	0.04
242.0464478	0.01
245.8760071	0.03
250.2051086	0.01
260.1795654	0.03
269.9020996	0.02
275.9367981	0.03
297.5726624	0.04
303.9013672	0.40
308.2322998	0.07
314.1697388	0.08
330.0306396	0.04
331.8939514	0.24
347.9748535	1.00
361.9716797	0.09
373.4700012	0.01
375.9897156	0.15
392.0289917	0.07
393.9690247	100.00
401.5267334	0.01
402.1769104	0.08
404.3235779	0.04
419.9687500	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.069603	0.03
112.0715408	0.04
127.104599	0.16
128.035675	0.14
134.0858459	0.13
135.1040955	0.80
136.052948	0.96
137.1970978	0.02
143.0167999	0.10
151.2279663	0.08
155.0296936	0.10
161.2777405	0.14
162.1017609	0.34
171.1828918	0.05
173.0364685	3.02
174.1186523	2.20
179.0372314	5.02
180.0211792	7.13
191.0278625	100.00
192.0341949	83.32
234.1955566	0.11
246.2221069	0.08
264.0691528	0.10
266.0921326	0.02
274.590332	0.08
292.1085205	0.06
308.7142029	0.17
310.1444702	0.16
336.3446045	0.13
338.1976929	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0672760	0.11
152.0361328	0.30
153.0583801	0.16
194.7596130	0.07
196.0845947	2.93
214.0818634	0.79
261.3237305	0.27
271.0758667	0.05
274.1091309	0.13
279.2664185	100.00
328.4209595	0.19
344.6235657	0.16
359.6905823	0.13
394.2154846	0.16
404.2467346	0.04
415.0531921	0.30
418.2089539	0.06
430.1016541	0.14
433.4849243	0.05
457.1090088	0.22
458.0707092	0.53
459.3504333	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.08
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0849762	0.07
155.1990509	0.05
165.2140961	0.14
166.9166870	0.08
179.0828094	0.73
181.0712128	100.00
183.1192017	0.19
191.1105957	0.31
199.3278046	0.08
209.1732635	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
135.3508301	1.06
136.0526428	1.64
137.0116577	0.13
155.8726196	0.10
161.084137	0.58
161.8841553	0.13
173.0403748	15.13
174.064682	9.62
177.197998	0.29
179.0026703	8.49
180.0252075	17.06
191.04216	100.00
192.1046753	73.95
210.0271912	0.15
218.409729	0.37
226.0765991	0.50
234.1810303	0.27
236.8492432	0.26
240.1218567	0.18
250.1473694	0.27
255.9493408	0.17
257.9462891	0.18
261.2749023	0.22
264.1210938	0.47
266.289917	0.13
267.070282	0.46
270.0929871	0.22
294.0108032	0.44
308.2325439	0.21
309.8404846	0.86
311.1819763	0.14
318.1378784	0.22
335.877533	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2773
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.096344	0.18
180.1817322	0.16
182.2659454	0.22
196.1596985	1.24
214.1325989	2.45
231.1037445	0.17
261.4272156	0.14
279.2270203	100.00
279.8437805	0.34
290.9805908	0.11
305.9381104	0.50
328.0820312	0.13
373.947876	0.26
379.1755066	0.08
397.4444885	0.09
404.6558838	0.13
415.2165222	0.36
432.5829163	0.25
440.4606934	0.12
457.8997803	1.10
459.2756958	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1191
Annotation	2'',6''-Di-O-Acetyl isovitexin
Peak:m/z	Relative Intensity
154.9357147	0.04
169.9525146	0.06
173.0736847	0.30
179.1027374	1.23
191.1185608	2.11
203.1239624	0.17
226.8594208	0.03
247.1888733	0.02
273.1285400	0.06
281.3375244	0.05
283.2059937	0.04
297.1817627	0.04
298.9403992	0.14
312.0601807	0.05
317.2691650	0.03
335.1710815	0.72
353.1309814	100.00
361.2023926	0.02
369.1213379	0.10
379.1553345	0.20
392.9159546	0.05
412.2114868	0.05
419.5877075	0.02
423.2902222	0.06
426.1724243	0.03
467.3426514	0.05
471.2801514	0.11
474.2290649	0.04
478.6655884	0.06
483.5720825	0.09
485.3234863	0.07
487.3028564	0.05
497.4823608	0.30
510.0460815	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8574066	0.82
208.9332581	0.73
212.9067535	0.06
286.8267822	0.03
290.7141418	5.68
291.6614380	0.38
292.8213501	9.14
296.4614258	0.01
324.3765869	0.05
336.5244751	0.02
360.0288086	0.02
374.7059937	1.94
376.7190552	8.38
378.7041626	0.02
380.4765015	0.02
381.3634644	0.02
382.9073486	0.16
398.2233276	0.03
408.5449829	0.09
414.8751831	0.02
424.9075317	0.16
430.9433594	0.02
437.7387085	0.09
438.6340332	0.08
445.0936890	0.03
446.7939453	0.02
453.6878662	0.03
454.7952271	0.06
458.6085205	15.10
460.5406494	100.00
461.2662354	0.31
479.6417236	0.02
480.6394653	0.09
482.4905396	0.09
483.9362183	0.03
484.7640991	0.65
486.7741699	0.02
496.3130493	0.01
498.0599365	0.55
498.8466797	1.93
514.6842651	0.05
526.0335083	0.04
527.2005005	0.06
528.2047729	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
88.88418579	0.28
97.05303955	0.96
105.1374512	0.25
110.03302	0.26
133.1808014	0.46
139.1112518	0.68
145.2925568	0.35
146.2419128	0.22
154.9947662	0.26
165.2362976	0.37
166.7447357	0.21
167.3854065	0.27
179.171524	2.39
194.2417603	0.44
195.1290741	0.36
205.1104736	0.67
206.9091644	9.58
208.1306152	1.75
209.2222137	4.48
221.1582184	0.18
222.1021271	2.43
223.0090179	10.34
224.0626678	0.37
233.2091217	2.00
237.2610626	0.22
249.1979828	0.92
251.0658722	100.00
252.1657867	18.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
127.0093613	0.12
132.9179688	0.05
134.9530029	0.88
145.1208191	0.01
155.1226501	0.01
161.0664062	0.48
173.0831604	0.99
179.1223450	4.09
191.0189514	100.00
219.1024170	0.01
309.2263184	0.07
335.6036987	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.67684937	0.54
79.06050873	1.08
80.92782593	3.95
82.97722626	1.32
85.07756042	1.02
89.06806946	0.63
91.03147888	0.17
92.91980743	0.96
94.99186707	6.41
96.71353912	1.35
102.9711609	0.33
104.311615	1.23
104.9317932	0.41
106.9423828	1.51
108.9738312	7.79
110.8642578	2.46
112.853363	0.83
119.0445099	3.07
120.8866119	3.08
123.0709686	2.36
124.7841797	0.30
127.5435333	1.04
128.9570312	7.52
130.1180725	1.70
131.0640869	0.43
133.1607819	4.03
135.0549469	4.51
136.2667084	0.81
137.0511017	4.39
139.0047913	1.20
140.8612823	3.31
147.2034912	3.43
148.9919891	0.19
150.9496307	50.80
152.0390167	2.10
152.9793091	2.29
153.9575348	0.58
154.9595337	2.95
157.216568	0.89
158.4249878	0.70
161.1452484	1.12
163.0185394	1.13
164.9004517	3.31
168.0398407	0.26
169.0843506	3.17
170.89711	2.52
172.8353271	0.49
175.3205261	1.73
177.1580505	1.02
179.1721191	1.06
180.1746979	0.87
181.1952209	0.42
181.8727875	0.23
183.1464233	2.01
185.0999908	2.69
187.9740143	0.72
189.2524872	3.16
190.1548157	0.84
191.1175537	0.30
192.1294708	0.15
193.225174	1.59
195.0159454	2.38
197.0574341	7.80
199.194809	1.78
201.2081757	0.37
203.2535858	0.22
207.0526276	5.43
207.8848114	0.23
209.2500153	2.56
210.0175323	0.98
211.0263977	7.02
212.1316681	0.95
217.1932526	12.07
218.9388275	0.41
225.0825653	19.65
225.7783661	0.81
232.3889313	0.62
235.2000275	42.34
236.8083038	0.47
238.0935211	9.19
239.0646362	1.26
244.0836182	1.80
244.8002777	0.44
253.0865326	100.00
254.1234283	19.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.8327
Annotation	Unknow
Peak:m/z	Relative Intensity
304.9664001	0.07
379.0229492	0.05
408.4948730	0.13
430.9169312	0.28
432.7320557	0.08
444.5785522	0.38
446.9135742	0.16
462.7772217	1.37
490.8867798	69.38
492.9826050	0.34
494.4481812	0.12
507.2651978	0.08
508.7459106	14.54
509.4630737	0.20
510.6161499	0.18
520.1923218	0.03
536.7792969	100.00
537.4201050	0.22
538.1278687	0.09
549.9280396	0.08
554.4160156	0.38
555.1795654	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2246
Annotation	Lactulose
Peak:m/z	Relative Intensity
281.0790405	0.02
323.1328735	0.07
339.3068237	0.03
341.1454468	100.00
443.0545044	0.05
503.1636353	0.05
664.9728394	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1086
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
134.0250854	0.23
149.3069458	0.09
178.0958252	0.04
191.1356659	0.05
193.1170349	26.47
195.1848145	0.07
197.2346649	0.03
201.3143311	0.06
207.1561890	0.14
219.3465271	0.02
221.4802704	0.03
235.1514587	0.12
239.4909973	0.05
244.0605774	0.03
249.3439636	0.04
253.1424866	0.07
262.1904602	0.03
264.9789124	0.02
267.1152954	0.19
277.0834045	0.12
281.4128418	0.03
283.0097961	0.05
287.0942993	0.03
295.0536499	0.35
305.2792969	0.07
311.0914001	0.07
327.0025330	0.02
332.8831787	0.05
341.3373108	0.13
355.0959473	100.00
356.4268494	0.06
357.1333313	0.06
381.3329163	0.08
383.2590637	0.41
386.1682129	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.0509
Annotation	Diaportinic acid
Peak:m/z	Relative Intensity
78.8510284	0.08
89.0127945	0.02
96.9976196	0.08
114.9841766	0.23
119.0986938	0.78
133.0292664	2.04
137.4449463	0.06
153.1161499	0.06
154.6058350	0.03
157.1361542	0.03
162.9715576	100.00
164.0900574	0.04
164.9732208	0.02
166.1351929	0.02
188.8703308	0.47
199.0915527	0.02
207.1598511	0.10
211.1386414	0.04
218.9968567	0.04
223.1726990	0.03
224.6730347	0.06
233.0189209	0.49
234.9604797	0.37
243.0813293	0.14
245.2547607	0.03
249.1089478	0.10
251.1488953	0.02
258.8541870	0.08
260.6925964	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
92.9355011	0.06
125.1444244	0.14
158.9194336	0.05
161.0449677	0.05
165.1937714	0.08
173.1324615	0.12
181.2557678	0.18
187.1411743	0.23
193.0072174	0.06
197.2610931	0.04
199.1248016	0.10
200.2978058	0.06
202.1731415	0.05
215.047226	0.61
217.10849	0.49
218.96492	0.06
221.0558014	0.32
225.0437927	0.05
227.3709259	0.22
232.0975494	0.20
232.9924927	0.33
241.1487427	0.10
243.1442719	100.00
245.2679596	2.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.2679
Annotation	(9Z,12Z)-Octadeca-9,12-dien-1-ol
Peak:m/z	Relative Intensity
79.03116608	2.10
80.93670654	18.03
83.02232361	24.77
85.04886627	0.89
91.04141235	0.89
93.07164001	0.11
94.93151855	32.56
97.03469849	32.04
98.94155884	0.43
101.0025635	0.15
107.1274872	0.15
108.9711456	39.42
111.014267	18.65
112.9253235	0.75
114.9701691	0.49
121.0466766	0.49
122.9775238	21.68
125.0457611	5.25
126.9465485	0.55
134.9523773	1.94
136.9701233	15.55
138.9621582	3.94
141.0419922	0.67
141.8091583	0.25
149.0467987	0.52
151.0410767	16.16
151.934845	0.35
152.95784	5.48
154.8395233	1.04
157.0707397	1.10
161.0640106	0.45
165.0853424	12.92
166.0422363	0.30
166.9552307	2.79
168.9378815	0.31
171.1898346	7.00
179.1787262	9.29
182.9347687	0.55
185.1721039	6.14
191.1651764	0.40
193.0365753	10.41
195.3295898	0.18
196.9895172	0.71
205.0091705	0.90
207.2957916	0.77
208.1260834	0.10
209.0876617	0.13
211.0196686	1.18
213.1582184	0.42
221.1911163	0.35
222.4020233	0.12
223.2202454	0.24
225.2554169	1.67
226.0362701	1.17
228.2096252	0.15
231.2055817	1.08
236.0869751	0.73
238.9271851	0.50
241.386795	0.13
249.2523193	100.00
250.075058	0.17
251.0101776	0.42
251.9340363	1.08
266.8511353	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	182.08
Annotation	Epinephrine
Peak:m/z	Relative Intensity
58.92922974	9.22
59.92663574	3.82
70.89764404	6.13
71.86712646	7.91
72.99423218	6.34
74.04039764	11.68
83.94799805	2.11
85.27053833	1.61
86.01722717	3.72
87.06433105	2.29
88.02322388	4.29
88.98467255	30.50
89.97471619	33.42
91.00375366	1.30
91.97106934	1.31
98.00531006	3.39
100.9372253	30.20
101.9890747	51.51
102.9499664	0.17
103.8417816	2.11
105.8856964	0.29
107.139267	1.70
111.5966797	0.27
112.8894043	4.61
114.0322418	18.36
115.1393433	4.77
116.0076141	15.16
118.8853302	22.94
119.9174347	36.96
121.0022583	0.29
126.0483093	3.44
128.0782318	1.75
130.9400482	6.68
132.0322113	17.52
133.263092	0.82
140.1327209	0.68
142.7962189	1.24
144.0429077	19.93
145.9626465	1.35
148.8566895	3.58
149.9139862	13.52
153.973175	0.64
154.828186	0.79
161.9528503	18.07
164.0765533	100.00
166.8883362	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2416
Annotation	Moniliforminol A
Peak:m/z	Relative Intensity
84.95901489	0.22
91.07826233	1.00
92.95648193	0.23
94.97828674	1.18
96.81135559	0.96
99.03952026	0.54
100.9105988	0.04
103.1488953	0.29
104.9808197	0.48
106.95401	0.26
108.9964447	2.34
111.0218353	1.17
113.0545654	0.24
114.9178467	0.20
117.2402191	0.10
118.9783401	0.61
120.9391861	2.30
122.9878387	1.57
125.1343842	0.90
126.9584351	1.01
128.8322754	0.59
131.1329651	0.48
132.2005005	0.12
133.187149	0.58
134.9754944	2.23
137.1758118	0.62
139.0472412	1.86
140.8851624	0.75
142.9038696	0.57
144.9852905	0.14
147.0621033	0.75
148.967926	0.48
151.0121155	1.12
153.0466309	2.30
155.0466614	0.85
157.026535	0.14
159.2056885	0.16
160.980011	0.64
163.0901642	0.43
165.1350403	0.47
167.2154846	0.50
169.0529633	1.69
170.0383606	0.14
171.1993561	0.23
172.4826355	0.41
173.1103516	0.05
175.2236481	0.40
177.0468903	0.23
179.2902832	0.62
181.0582428	0.74
183.0537415	3.14
185.1221771	1.59
187.1434631	0.58
189.121994	0.90
191.0871887	0.50
192.0666809	0.30
193.2241516	0.57
195.1773376	1.48
196.5208893	0.64
197.1769714	3.70
198.2097473	0.70
199.152771	1.44
201.1296082	0.14
203.1638489	1.20
205.2996216	0.05
207.3226318	0.40
209.2227783	1.19
211.1448669	2.66
213.1691589	1.57
215.0056152	0.86
216.9638062	0.14
219.2275391	1.60
220.0418701	0.09
221.0716553	2.47
223.3236389	0.59
225.1808777	2.43
226.2674866	0.46
227.1058655	1.75
228.8876343	0.04
233.1974182	3.02
235.061554	0.05
237.2531128	4.75
239.1571045	11.73
240.0643005	0.45
241.1769409	1.17
243.2523193	3.96
247.4677429	0.05
250.2070618	0.12
251.1069946	2.73
253.2057495	1.01
255.1950989	1.08
257.1729736	0.38
261.1158447	3.44
262.1470032	0.34
265.4792786	0.26
269.3567505	0.39
274.8212891	0.31
276.4891357	0.21
279.2250977	100.00
280.4229736	0.41
281.123291	0.68
282.1509094	0.16
288.0573425	0.36
288.7285767	0.09
293.454895	0.12
297.1286621	0.14
303.1400452	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0337
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
58.7469101	0.02
68.7741318	0.01
69.7088471	0.05
72.7927551	0.02
86.9980011	0.03
90.9658203	0.02
114.8010712	0.02
117.0583496	0.12
120.8950500	0.03
128.6879272	0.06
131.2331543	0.05
133.5689850	0.01
134.7446136	0.02
135.9039154	0.02
137.1542206	0.01
138.9588928	0.03
145.0933075	0.03
146.9281616	6.66
148.9814301	0.02
156.8680573	0.83
160.7001190	0.04
162.8939819	0.03
164.3679657	0.28
165.0024872	0.22
170.0374298	0.44
170.6526947	0.01
174.8642731	100.00
176.0278168	0.14
183.5356598	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1195
Annotation	Unknow
Peak:m/z	Relative Intensity
108.7281876	0.09
113.1645813	0.04
125.1342468	0.03
160.8946838	0.12
179.0144806	5.97
189.0705109	0.14
190.9785156	100.00
244.1903992	0.03
253.1352234	0.03
325.0750427	0.74
325.6968994	0.07
339.2457886	0.12
353.4018860	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9659271	0.58
296.2201843	0.99
296.8410950	10.23
380.5915527	41.63
381.2598877	0.12
445.1348267	0.08
464.4542847	65.34
465.1754761	0.20
546.6589966	0.29
548.4504395	100.00
549.2584229	0.05
551.8319092	0.09
615.2722778	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
79.76539612	0.24
96.84988403	0.89
111.1367188	0.29
117.2731934	0.67
127.0419922	0.12
129.9661407	0.12
141.0301361	0.29
145.737381	0.38
155.2138519	0.13
163.0407562	0.15
165.9881897	0.39
166.9633942	0.19
169.0197906	0.43
173.390625	0.53
178.9026337	0.53
180.1210175	0.47
181.3351593	0.20
182.0166321	0.36
182.9534912	0.89
188.9285736	0.23
193.1717529	0.12
194.2422638	0.20
205.2089539	0.16
206.0094452	0.16
207.2023468	2.81
208.1003876	2.33
209.1907806	4.02
221.1170349	0.47
222.1629791	1.61
223.2309113	5.00
224.1403351	0.98
233.1247101	1.65
251.0783539	100.00
252.1717987	20.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.127
Annotation	Noricaritin
Peak:m/z	Relative Intensity
123.02742	0.79
134.9453583	0.12
136.9484863	3.96
146.89888	0.45
151.2171631	0.59
155.0616608	0.26
159.0296021	0.71
161.0951843	0.16
162.9900208	0.62
170.9746399	0.38
175.1826477	0.62
177.0412598	1.29
179.0885315	1.32
180.1621399	0.12
183.026413	0.91
191.2253723	0.45
194.8662872	0.18
201.1017761	2.51
207.0488586	2.51
208.5194092	0.40
211.3755646	0.52
212.8735046	0.16
215.2014313	0.20
218.9557495	25.19
221.0787048	0.36
225.1022949	0.38
227.3131714	0.30
230.3215027	0.38
231.0809631	1.52
240.9447021	0.19
242.0719299	0.29
245.2289429	0.27
249.1337891	0.84
253.0170898	0.41
265.3714905	0.31
266.9318542	1.12
272.9559021	0.19
274.9442749	1.27
276.8268433	0.75
279.4071655	0.29
281.1535645	0.16
282.2676392	2.21
282.9852905	1.34
285.1128235	0.86
297.2554932	0.54
299.1234131	0.24
300.2442627	0.90
303.0653381	0.34
311.1272583	0.93
313.2218628	1.92
314.1906128	0.35
319.0280762	0.31
320.223877	0.20
323.2145386	0.66
324.2765198	0.31
325.1513367	9.67
327.4580688	1.21
329.008667	1.09
331.5289917	0.67
332.2815552	0.60
337.1832886	2.96
339.9851685	0.21
341.2034912	1.28
343.0281982	100.00
343.6841431	0.26
355.1239319	97.55
356.2048645	3.71
357.0880432	0.30
358.1590271	0.75
363.6994934	0.55
372.6591492	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
73.01544189	0.27
79.94152832	0.26
99.04821777	0.18
100.9835358	0.19
116.7705841	0.48
117.4036102	0.09
146.1637878	0.11
149.0441437	0.11
169.2895355	0.35
179.0847015	0.47
185.0802155	0.27
189.5514374	0.12
193.1462555	0.52
194.1326141	0.26
197.3850861	0.33
205.0814362	0.90
206.3209991	1.17
207.0949097	4.95
208.1635284	2.96
209.0489044	0.73
222.0735321	3.13
223.153183	3.37
233.1824341	1.09
236.135025	0.17
251.0799561	100.00
252.1629639	20.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
79.07335663	0.90
81.06326294	1.44
82.88124847	0.44
85.22369385	0.21
88.96248627	0.69
91.09040833	0.58
95.03349304	1.23
96.99360657	1.66
102.8661957	1.21
104.9996185	2.23
107.0397491	1.26
111.0613251	0.65
112.8130646	1.07
114.9630585	0.37
119.1844635	0.94
120.9408875	0.82
122.2006073	0.59
122.9544525	0.14
125.0123444	0.56
129.0412292	5.45
130.0667267	1.22
131.004715	0.22
132.999588	1.02
135.176712	2.11
136.9698486	0.53
138.9013672	0.78
141.1343384	2.61
147.0151978	0.55
149.1359711	0.21
150.9389648	55.74
152.0550385	4.70
153.0816498	0.51
155.2068939	0.92
156.97966	1.02
159.1916351	0.35
160.8916779	1.15
161.5168457	0.15
163.0810394	0.39
165.1676788	1.14
167.0424042	0.61
169.1878204	2.41
171.1954956	0.23
173.0467834	0.32
174.8134308	0.94
177.0235138	1.72
179.2082672	2.59
180.931076	1.06
182.2622223	0.85
183.119339	1.73
185.4050751	1.19
189.0605316	0.80
191.0964203	1.34
193.4347076	1.65
195.0808563	1.48
197.0131378	3.76
198.2341003	0.19
207.1423645	2.04
208.8977509	0.94
210.0631409	0.27
211.076416	1.74
212.1177216	1.22
217.2413635	7.51
223.2411804	0.66
225.1169434	6.61
226.1407013	1.68
235.1553802	22.87
236.0730591	1.96
238.0800629	9.91
239.3033447	0.97
244.1320343	0.76
253.0819702	100.00
254.2045441	16.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
80.75604248	0.50
83.18017578	0.39
93.0511322	0.32
95.02928925	1.25
96.01693726	0.47
97.02091217	0.34
102.8240662	1.61
104.9501495	0.64
105.8240814	0.21
109.0808258	0.92
119.1689911	0.46
122.8339081	0.69
125.1394806	1.87
128.9112244	5.38
130.0986176	0.80
138.7389526	1.13
141.4693756	0.32
144.9953156	0.22
146.8103333	1.49
150.9526215	60.09
152.0329742	3.93
152.7856903	0.32
153.9862518	0.79
155.0694733	1.84
157.1598663	2.07
159.1454315	0.62
161.1798553	2.50
163.331543	0.20
165.1755219	1.40
166.0884399	0.38
167.0710907	1.76
168.0198059	0.67
169.2647705	1.37
171.159256	0.53
173.0726318	1.14
175.1598206	2.09
178.0173035	0.41
179.2805939	2.40
182.119339	0.82
183.2399139	2.44
184.9217987	1.94
189.2631989	0.76
190.6237793	0.32
191.3039856	0.86
193.8999481	0.50
195.0809479	1.93
197.1173553	1.78
198.004364	0.17
199.2417755	0.10
203.2690582	0.71
206.973999	0.74
209.3824921	0.90
210.9749298	2.17
211.9738312	0.18
217.2626495	6.01
225.3843842	6.12
226.3031769	0.35
235.2084808	20.86
238.1072845	9.56
239.2731476	1.01
253.0882416	100.00
254.0918121	20.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
109.1736145	0.33
145.0888367	0.28
156.8460083	0.69
159.0439148	0.15
168.9907837	0.59
170.9846191	1.29
173.0006561	1.02
183.0603485	0.62
185.0391388	1.99
187.0208588	1.86
195.0332642	0.23
199.2375793	2.54
201.1090393	2.12
203.5549316	0.40
213.1699829	2.15
215.1559448	2.87
217.3015442	0.65
227.2996216	2.38
229.322998	4.61
231.3546753	0.88
241.0917664	0.74
243.1781006	3.44
245.1410522	1.62
253.3513184	0.40
255.3078308	0.98
257.31427	2.67
259.3903198	0.70
261.0930176	1.27
263.1679688	3.10
269.1965942	1.46
271.2785034	6.77
273.2128601	0.72
277.672821	0.29
283.4275208	1.00
285.3796387	7.87
287.2743835	1.21
293.2166138	1.29
295.3647766	0.15
297.4086914	2.14
299.3165283	4.69
301.4885254	1.20
303.3976746	0.21
311.2029724	0.44
313.8049316	1.17
315.4072876	1.93
321.3492432	0.90
323.3286743	7.05
325.272583	1.27
327.4385071	0.24
329.6782227	0.26
337.4904175	1.50
339.2475586	100.00
341.3455505	16.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.0772
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8307648	0.01
181.0007172	100.00
181.9033051	0.02
209.0111542	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1386
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8187408	0.61
196.8552094	0.15
221.2034912	0.09
232.5545502	0.63
250.9196167	0.08
259.1004639	0.35
268.0792542	0.11
277.0284424	0.15
280.8447876	0.07
323.0452881	0.67
341.0537720	0.61
367.1437988	0.09
383.1190186	3.32
403.4892578	0.34
421.1286011	7.63
425.2442017	0.26
430.8750610	0.08
439.2612915	2.07
442.9996948	0.48
503.2010498	100.00
511.2556763	0.14
541.2528076	0.35
555.2693481	0.20
583.2308960	17.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.91766357	0.46
79.00169373	0.27
80.94921875	1.79
82.92102814	0.52
85.06896973	0.37
88.73002625	1.05
93.0660553	0.86
94.90263367	3.79
96.62511444	0.59
98.91053772	0.71
103.0115814	3.36
104.1547394	0.87
104.8103027	1.37
106.82164	0.80
109.037796	2.65
111.1500854	0.78
112.8224487	0.74
115.2117767	0.35
119.1492004	1.15
120.9536133	2.20
122.9846039	2.81
124.6605225	0.56
125.2878876	1.05
128.9488831	3.66
129.912262	1.16
132.0598145	0.65
132.9800415	0.59
135.1357269	3.87
137.0064087	2.15
138.6180878	0.24
140.9868317	0.25
144.7714386	0.68
147.0550385	2.03
149.170105	0.44
150.9971771	59.49
152.0610504	5.30
152.955719	1.81
153.9771881	0.22
155.1222687	1.17
157.0753937	0.88
159.1891174	0.22
161.0464172	1.48
162.9970551	0.63
165.0482483	3.84
167.1781158	1.64
169.0755768	1.12
171.1023712	1.17
177.0849457	1.82
179.0687561	4.92
180.931015	0.43
182.0147858	0.96
183.1148224	0.95
184.0354004	0.24
185.1778412	1.22
189.2764282	0.75
193.0211182	0.93
195.0925903	3.86
197.1485901	5.31
198.2099152	0.73
199.3958588	1.18
201.1241608	0.20
207.2340546	1.84
209.2559967	0.30
210.2476044	0.84
211.0969086	2.18
215.7668915	1.43
217.2410736	7.89
223.3293304	0.34
225.1709747	9.88
226.0977936	1.94
235.1835785	19.23
238.1774139	12.10
239.2084808	0.41
244.1637573	2.98
250.8267059	0.69
253.0810394	100.00
254.1600952	16.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.1294
Annotation	Unknow
Peak:m/z	Relative Intensity
108.8319855	0.02
111.0232086	0.03
125.1290131	0.03
126.9052582	0.02
144.8882599	0.02
159.2275696	0.07
163.0574799	0.02
165.1345825	0.03
166.1814880	0.02
173.1452179	0.05
177.9663544	0.02
185.1609802	0.03
187.2596130	0.04
189.1559143	0.08
191.2443085	0.01
207.0213928	0.02
211.3173523	0.03
212.9930573	0.04
215.1206360	0.03
228.1288757	0.02
230.2798462	0.01
234.7652283	0.01
239.2947388	0.01
241.4251709	0.03
245.3605652	0.04
253.1532593	0.04
254.8779297	0.02
260.0506287	0.07
264.1581421	0.03
267.1846008	0.02
270.1481934	0.02
274.5791016	0.02
283.3143311	0.18
285.3790283	0.09
289.0264587	0.01
294.4653625	0.01
297.2211914	0.01
298.2236938	0.09
299.0352783	0.08
301.2058716	0.34
303.1375122	0.11
304.0146484	0.06
309.1149292	0.19
315.1711426	0.02
317.1058350	0.01
321.9557190	0.07
327.1505737	100.00
328.2302551	0.22
334.2943726	0.05
336.1791992	0.07
345.2050476	4.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.119
Annotation	4'-N-desmethylolanzapine
Peak:m/z	Relative Intensity
88.9672470	0.09
100.9286652	0.05
115.0484695	0.45
116.9456100	1.60
131.0087585	0.06
143.0475616	0.05
148.7816467	0.10
161.1232300	0.52
175.0406342	0.04
179.0631409	0.12
181.0553589	0.25
191.1294098	0.18
222.8492126	0.07
225.0825195	0.26
233.0938110	0.07
237.1329041	0.06
239.1109619	0.10
251.0725098	100.00
251.6823425	0.31
252.9998779	0.10
255.5001526	0.04
261.2636108	0.03
267.0700684	0.05
269.1117249	0.10
279.1936951	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.1239
Annotation	Methyl helianthenoate F glucoside
Peak:m/z	Relative Intensity
102.9838409	0.03
105.0295868	0.09
107.9483490	0.03
116.8595276	0.05
119.1206131	0.02
120.9693375	0.04
121.9727783	0.09
125.2470932	0.04
128.7629700	0.06
130.0692444	0.15
131.1368713	0.06
135.0416870	0.15
144.9887543	0.03
146.9888611	0.59
148.9953918	100.00
150.9712219	0.09
172.8346863	0.46
173.4739685	0.09
179.1380920	0.45
187.2113495	0.06
191.0056458	4.90
208.1520386	0.06
214.7296448	0.02
245.2252808	0.06
256.9657288	0.04
262.5936584	0.04
263.2573547	0.04
265.0782471	0.21
277.2436829	0.06
291.2321472	0.07
293.2090759	4.26
299.5056458	0.07
307.2320862	0.29
309.3354492	0.09
311.0451660	4.76
311.6805725	0.07
315.9763184	0.08
317.1281128	0.20
325.2172241	0.09
333.3807373	0.04
335.2609863	1.30
337.2286377	0.13
338.2728271	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.76398468	0.72
78.96349335	0.65
80.99907684	1.21
82.89613342	1.46
85.03987122	0.75
91.07872009	0.73
93.02043152	0.18
94.9924469	4.32
96.90531921	4.06
99.05180359	1.05
102.8388977	2.23
104.6171265	0.62
106.7937622	0.80
109.0575409	5.19
110.0649719	0.66
111.0499725	0.78
112.9545135	1.78
115.0361023	0.74
116.8241119	0.23
118.7805328	0.46
121.1620789	3.12
123.0079956	1.28
124.9656219	1.83
126.8230896	2.90
128.1242371	0.56
129.0929565	4.31
133.190918	0.83
135.1931305	3.38
137.0859985	3.29
139.1001129	1.43
141.0196228	2.42
142.8795319	3.35
144.3547821	0.39
145.0784149	1.45
146.7515717	1.11
148.8992004	1.67
150.9246826	67.83
152.0720673	2.67
153.1990967	0.26
155.0191345	4.38
156.8457489	1.21
158.8209686	0.27
161.5717926	0.99
163.1916199	1.04
165.0446777	2.82
166.1088715	0.35
167.0684052	2.25
169.0776825	4.58
171.1783752	0.83
172.9664764	0.43
175.2298737	1.70
176.9851227	1.94
179.0685425	4.26
179.8749237	0.72
182.0457611	3.50
183.1296539	4.06
184.1057434	0.23
185.0777435	0.67
189.0480804	1.45
191.0449982	1.22
192.0309296	2.20
193.045517	2.44
193.987854	1.97
195.0485992	6.38
197.1056366	7.22
197.8432312	0.94
199.0799713	2.17
207.0900269	4.83
209.126358	1.37
210.2496643	0.60
211.0443573	4.42
217.1298065	13.47
225.1869049	16.55
226.1138458	0.57
229.8570557	0.31
235.1401215	48.93
237.0773773	0.18
238.0751953	12.88
239.1272125	2.97
240.9666748	2.51
244.3033295	2.29
251.2416534	0.16
253.0855865	100.00
254.2197723	13.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.07
Annotation	naproxen sodium
Peak:m/z	Relative Intensity
87.13760376	0.74
96.88844299	0.37
100.8395233	1.36
113.1694183	0.48
137.1920013	0.36
156.7533417	0.33
160.9571381	1.42
163.2844696	1.18
169.0744019	1.10
180.0520782	0.96
181.1521606	3.10
183.1600494	1.45
195.2488251	1.92
207.0990906	7.81
208.1973724	1.39
209.1252289	2.42
214.9904022	0.30
221.0912933	0.30
222.1760559	1.87
223.1730194	7.42
224.3980865	0.76
233.1686249	5.43
251.0607147	100.00
252.1035156	12.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1345
Annotation	Semperoside
Peak:m/z	Relative Intensity
108.9253159	0.14
113.1167450	0.32
119.0238495	0.03
134.9468842	0.10
153.0733032	17.48
167.1503601	0.16
177.3163757	0.04
179.2686157	0.16
184.6292114	0.03
192.8317108	0.08
195.2712402	0.09
197.0287323	100.00
211.2204285	0.13
225.0349731	0.15
226.7503662	0.11
228.0487671	0.03
229.9011536	0.05
239.1545715	0.25
247.2095642	0.07
249.3053284	0.10
251.1242676	0.08
255.0856628	0.03
269.0891113	0.43
271.2606201	0.11
279.2968140	0.06
281.4146729	0.06
283.2315369	0.04
297.1024475	0.43
299.1504211	0.96
313.1028137	0.71
315.3060303	0.32
317.1140442	0.04
323.1386108	0.36
331.1460266	0.13
341.2441101	1.92
342.0054016	0.07
342.8899231	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1194
Annotation	Unknow
Peak:m/z	Relative Intensity
107.8181610	0.06
108.7945480	0.04
111.1329803	0.05
112.9976349	0.09
126.9242706	0.08
131.1043701	0.01
160.6858521	0.06
173.3210754	0.06
189.2038269	0.02
191.1065063	100.00
293.5130005	0.05
325.0693359	0.05
338.9702148	0.02
353.1155701	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2417
Annotation	Moniliforminol A
Peak:m/z	Relative Intensity
92.73167419	0.28
94.98518372	1.97
96.96232605	1.73
99.01226807	0.55
103.0068283	0.57
105.1201324	0.06
107.0019836	0.14
109.0236359	2.04
110.9271851	1.00
112.9528351	0.59
116.9345093	0.46
121.1273804	0.76
121.7798843	0.09
122.943718	2.02
124.8763657	0.74
126.8790894	1.06
131.0580902	0.13
133.0681763	1.01
135.0788879	1.52
136.8065796	0.37
139.0267639	6.26
141.0744324	1.29
143.1819305	0.08
144.9642029	0.05
147.1413879	0.97
148.9683838	0.11
151.0969391	0.43
153.0572205	2.55
154.2501831	0.31
155.0855103	0.57
157.1036377	0.49
158.7852173	0.04
160.9994812	1.40
163.0166473	0.32
165.2530212	0.65
166.9219666	0.84
168.2169189	0.11
169.0713348	0.74
171.0728607	0.73
172.0363007	0.28
175.1354675	0.51
177.0592041	0.39
179.1245422	0.68
180.9596405	0.44
183.1337433	1.01
185.1800385	0.87
187.1412048	0.29
189.1109467	0.53
190.9303589	0.10
192.6387939	0.23
193.3077545	0.33
195.1372986	1.71
197.1052246	4.89
199.1412048	0.60
203.197052	2.96
205.2319031	0.08
207.1102295	0.36
209.242157	0.85
211.2558289	0.99
213.10849	0.56
215.2433472	0.26
219.2157898	0.32
221.2097168	5.67
223.245636	1.14
225.0842285	1.45
227.1313171	1.32
232.9614563	1.11
235.1577759	0.40
237.1824646	3.94
239.2041016	7.74
241.1018066	0.25
243.1535034	0.69
251.28302	0.93
252.2911377	0.13
253.3211975	0.91
255.1203918	1.75
255.960083	0.30
256.8471375	0.27
259.2962341	0.13
261.2692261	3.62
269.2606506	0.48
279.2260742	100.00
280.1534729	0.22
280.8878479	1.00
288.9012756	0.21
296.2341309	0.08
297.1903687	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.1961
Annotation	Unknow
Peak:m/z	Relative Intensity
133.7738037	0.15
147.0188446	3.78
148.1237793	0.29
164.9714661	6.13
179.0281525	0.07
183.0329895	100.00
184.9973145	0.10
193.3182983	0.24
214.0605164	0.08
223.2638855	0.14
242.1805420	0.48
260.7190857	0.23
268.3595276	0.87
281.9344177	1.67
291.2450867	0.47
296.3387146	0.14
301.6892700	1.08
302.3066711	0.38
303.3058777	0.10
324.7924500	0.17
331.0496521	0.15
332.9169922	0.10
343.5549011	0.53
344.8911438	12.43
367.1082153	0.53
375.5592346	0.15
463.8914490	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.32
Annotation	Anandamide (20:2, n-6)
Peak:m/z	Relative Intensity
105.0737152	0.05
107.0569153	0.20
109.0157471	0.47
111.0432510	0.30
112.9896393	0.09
113.8267136	0.06
115.0412369	0.08
118.8818436	0.08
121.1175766	0.08
122.0030289	0.03
122.9988022	0.94
124.0657196	0.03
125.1010513	0.17
128.9532623	0.08
131.2104645	0.07
132.9231873	0.11
135.0238647	0.04
137.1020660	0.96
139.0051422	0.19
142.2439575	0.13
143.0343628	0.11
149.1895447	0.03
151.0796814	1.03
152.7840271	0.04
155.1036377	0.21
157.0435028	0.19
158.1948547	0.03
159.2997742	0.74
161.1606750	0.41
163.1724548	0.27
165.1726532	0.33
166.2257843	0.12
167.4867859	0.20
168.5626221	0.44
170.9749298	0.35
173.1712036	0.12
175.0598145	0.08
177.1030579	0.39
179.1792450	1.35
180.9564209	0.45
183.0702515	0.12
187.2098694	0.55
191.0797119	0.31
193.2797394	0.32
194.5739594	0.55
195.2964935	0.44
198.9973145	0.08
201.1964722	0.11
203.2150879	0.15
205.4178467	0.05
207.4395294	0.71
208.5131989	0.67
209.1958618	0.64
210.2330933	0.33
211.1281891	0.09
212.1303558	0.93
213.2000427	0.25
215.2631531	0.31
215.9626160	0.05
217.1359253	0.75
219.0811462	0.32
221.1432495	0.34
222.7837830	0.33
223.4553223	0.32
224.7043152	0.11
226.2849426	1.76
227.9464417	0.29
230.5451965	0.06
233.3387146	0.94
235.0984192	0.28
236.4060059	0.17
237.5051270	0.38
238.2747498	0.22
243.5788879	0.11
249.3823547	0.04
251.1765442	1.27
252.2276611	0.27
253.6499634	0.17
254.4035645	0.63
257.1368103	0.04
262.2635193	0.13
264.1088562	0.61
265.2509766	0.86
266.2556763	0.26
267.4730835	0.30
270.9260864	0.08
275.4135132	0.16
279.2028198	0.38
280.3713989	0.40
284.8448486	0.22
289.7589111	0.47
293.3374939	0.34
295.4088440	0.15
299.2936401	1.52
303.2735596	0.56
306.2406921	0.28
307.2801514	2.16
308.1519165	0.26
310.0799561	0.41
311.2767029	0.22
315.9714966	0.10
317.3140869	6.26
321.1781616	0.26
322.1360474	0.05
324.2528687	0.09
334.4660950	11.68
335.3126221	100.00
335.9253235	0.16
337.1600952	0.04
344.2793274	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1145
Annotation	Lactulose
Peak:m/z	Relative Intensity
161.0694275	0.07
179.0102234	0.08
191.1783600	0.35
192.0728149	0.04
192.9135437	0.12
194.1540985	0.03
195.0223389	0.03
322.9872742	0.01
341.1432800	100.00
367.2107239	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9628983	4.49
115.8607254	1.21
116.9682159	5.27
131.0759277	0.59
132.1466675	0.07
132.9239960	0.22
158.9219666	92.01
159.9808807	19.37
160.9038849	100.00
170.9190521	0.12
184.8417664	0.08
191.1450653	0.09
198.6406250	0.11
200.9129944	3.40
203.2807617	0.03
217.9953918	0.15
219.0398865	1.18
229.0261230	0.83
230.9126587	49.75
247.1132812	0.71
257.0690002	0.17
275.3077393	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.0133667	0.38
101.1544189	0.09
119.1568146	0.12
125.0224609	0.05
137.078186	0.10
146.1456604	0.13
148.9704437	0.10
153.0552826	0.12
155.0870819	0.17
158.9046173	0.12
161.1738739	0.44
166.2004852	0.21
169.1625214	0.18
178.9314423	0.34
179.8924561	0.09
181.0148773	0.21
182.9727936	0.23
191.0722504	0.08
193.2098541	0.76
204.968338	0.12
207.0647736	4.96
208.0720367	2.96
209.0342865	0.99
221.246582	0.09
222.1633453	1.64
223.0663757	4.13
224.0693207	0.86
233.2047729	2.25
234.2724457	0.23
251.0670319	100.00
252.1421661	13.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1489
Annotation	Tetrahydropentoxyline
Peak:m/z	Relative Intensity
115.2643585	0.06
117.0469894	0.16
129.8995514	0.12
132.1565857	0.05
140.8854523	0.05
144.0230103	1.48
146.0713196	0.36
148.0103302	0.10
149.2628937	0.17
153.0979614	0.06
156.2600098	0.24
159.1428375	0.05
159.9239655	0.09
163.0174561	0.05
165.9172363	0.08
170.1255493	0.05
171.8124390	0.06
173.0786438	0.60
175.0288696	0.18
187.9963379	33.47
201.2095947	0.23
202.0624237	1.13
202.9106903	0.28
205.0683289	100.00
210.9521790	0.14
213.0994568	0.24
215.0349731	0.70
217.1154480	0.76
219.1489258	0.25
220.7517700	0.03
224.0231018	0.13
227.0629578	0.17
229.0603943	9.98
230.1254272	3.27
230.7262268	0.03
233.1026306	0.04
235.1217957	0.75
237.2249146	0.08
240.3765564	0.11
244.9532471	0.17
247.0222778	28.98
249.0937195	0.16
250.9026489	0.06
253.2329712	0.17
254.1765747	1.56
257.9751892	0.43
259.0762329	0.22
271.1692505	5.03
276.0888672	3.59
277.1672363	0.35
279.2017822	0.06
283.0703125	1.60
288.9323120	0.07
290.3359985	0.23
293.8646240	0.34
295.1831970	0.39
296.2153320	1.04
301.0702515	1.77
303.1964417	0.31
306.5285034	0.42
307.1502075	0.16
308.2382202	0.32
310.8917236	0.04
313.2315063	3.31
314.1748352	1.60
319.1432495	0.04
321.2371216	1.90
323.4044189	0.08
325.3626709	0.23
326.0816650	0.52
331.1695557	10.69
332.2034607	2.29
335.1465149	0.08
335.9759521	0.11
337.0978394	0.22
339.0247803	0.14
343.9295349	0.09
349.1868591	26.17
350.2049255	7.53
352.3863831	0.19
357.6371765	0.10
366.4750977	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	232.98
Annotation	Alcalinaphenol D
Peak:m/z	Relative Intensity
73.0928955	0.02
91.0685043	0.02
115.0522919	0.07
116.8350830	0.03
119.0653992	0.03
137.0041809	0.17
143.0509491	0.06
144.8791656	0.11
147.2294769	0.09
149.0074463	0.01
157.1027679	0.11
158.9619141	0.01
160.9571228	0.04
163.1495209	0.08
171.0325012	0.16
173.1941071	0.03
174.1646881	0.04
174.9709778	0.07
176.0305328	0.01
176.9777069	2.73
186.9580078	0.37
189.0791321	0.30
191.8349762	100.00
194.8040009	1.34
197.1520538	0.07
204.9187012	0.08
209.8196716	10.88
212.0371246	0.16
214.9686584	1.57
215.8737946	0.03
216.5827484	0.03
217.8713531	13.60
225.1406860	0.02
232.8694305	0.06
233.9715576	0.15
235.4230957	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.1722
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
162.0490112	0.08
165.1026154	0.04
184.1756897	0.03
184.8778076	0.10
189.1821289	0.04
193.1599731	0.56
201.2961121	0.03
205.1044006	0.03
218.9044647	0.04
221.2227478	0.08
225.2341003	0.16
227.0313873	0.16
233.1161346	0.10
235.0844269	0.36
241.2211609	0.09
243.0024109	0.06
245.1736450	0.58
249.1186523	0.04
265.0226135	0.08
265.8796082	0.02
268.4951172	0.02
271.0513306	0.46
276.8513184	0.02
279.1076965	0.03
289.1181641	0.72
290.9991760	0.08
293.3791504	0.18
295.0755615	0.15
297.4519653	0.04
307.7690430	0.03
309.0932617	0.08
315.2232971	0.07
319.0455933	0.21
321.1128845	0.08
331.3683472	0.02
337.2545776	0.08
341.0253296	0.11
344.4725647	0.03
347.3273315	0.19
353.2171631	0.18
355.2901306	10.36
357.0559387	0.03
361.4372559	0.03
367.8462830	0.22
369.3254089	0.10
377.1757507	0.08
379.3560486	0.44
385.7986145	0.08
394.1437683	0.04
395.3052063	0.14
397.2305908	100.00
398.2464294	0.72
411.4560242	0.05
423.3132324	1.00
440.1598511	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	672.3901
Annotation	Unknow
Peak:m/z	Relative Intensity
197.2263489	0.40
199.8334656	0.73
203.2399139	0.48
204.0222015	0.19
242.0998535	0.14
256.2275696	0.60
257.0776672	0.29
271.9537964	0.19
274.4565430	0.29
280.0725708	0.21
284.2213745	0.34
284.8613281	0.07
289.9320068	0.10
310.2802124	0.62
325.5645447	0.14
326.2822876	0.13
328.2259216	2.05
329.2972412	0.49
341.2401733	0.74
342.4509888	0.11
353.1597290	0.35
355.1526489	0.43
369.1063232	0.31
371.2182617	0.12
373.3127441	0.70
385.0939941	0.45
387.2709961	0.57
388.6211548	0.07
391.3499146	1.53
403.8284302	0.09
432.1288452	0.16
455.3750610	0.31
457.0413818	0.11
458.3493042	0.30
461.2465820	0.07
468.0115356	1.31
469.1957397	0.27
478.0319824	0.31
486.2328491	2.36
487.2991333	0.30
514.4524536	0.23
515.1882324	0.65
527.2643433	0.43
527.9272461	0.91
528.6346436	2.27
531.8495483	0.70
540.3579712	0.52
541.4239502	3.37
542.5146484	1.01
544.7685547	0.17
548.5339355	1.27
549.5221558	0.59
553.4700317	1.54
555.4771118	0.33
558.1129150	0.29
558.9396362	0.11
562.5681763	6.03
563.2676392	0.14
565.6352539	0.33
571.2583008	3.65
571.9818726	3.14
573.3948364	0.13
575.8673096	0.14
579.4293823	3.71
580.0615234	1.16
580.8406372	0.09
581.7932739	0.19
583.3317871	0.36
584.3758545	0.99
585.1953125	0.46
586.0070190	0.34
587.2141113	0.15
589.0790405	2.04
592.9033813	2.33
593.5941162	0.32
597.8807373	24.77
598.4979858	8.70
599.4924927	2.73
600.3600464	0.80
606.8311157	14.46
607.5155640	8.67
610.1895142	0.25
611.3576050	0.09
614.4910889	0.52
615.3470459	0.41
617.3457031	90.09
618.3552856	17.13
619.3488770	0.27
626.9403687	0.12
628.4442139	7.03
629.3858643	0.89
630.9012451	0.49
635.2098999	0.35
636.1652222	0.34
641.9829102	0.31
643.4378052	0.15
645.3234253	0.97
650.1522827	0.64
654.5375366	4.97
655.4256592	1.09
663.5366821	0.11
699.2922974	0.27
709.6104126	1.87
710.4286499	0.21
716.4189453	4.74
717.4302368	3.22
719.4716797	0.49
727.4543457	100.00
728.4744873	29.04
729.2659302	0.78
729.9763794	0.23
741.6223755	0.29
751.6370239	0.09
766.3150635	0.17
783.5086670	0.07
785.4823608	0.64
786.8798218	0.74
790.3018799	0.44
791.2828979	0.19
796.0422974	0.30
796.7245483	0.15
809.4520874	0.33
811.6237183	0.67
815.8977661	0.09
829.4522095	1.63
830.3757324	0.27
851.6703491	0.24
867.0590820	0.53
867.6994019	2.47
868.4072266	0.31
880.4508667	0.17
884.3444824	0.22
885.4867554	0.43
904.9483032	0.29
949.7592163	0.21
953.5214844	4.65
954.6170044	1.69
957.4627075	1.88
986.5056152	0.25
996.4697876	0.15
997.6230469	0.20
1008.7060550	0.07
1011.8175660	0.33
1052.9093020	0.15
1054.6124270	2.86
1055.5158690	1.77
1067.1035160	1.04
1070.6854250	0.39
1077.3066410	0.34
1085.0948490	0.59
1092.8034670	0.23
1099.6940920	0.11
1116.3178710	0.21
1123.5859380	0.44
1124.5451660	0.16
1141.4680180	1.83
1142.5943600	1.13
1143.2218020	0.24
1157.6030270	1.25
1158.8424070	0.97
1179.6035160	0.15
1197.6948240	0.20
1198.8293460	0.12
1212.8533940	0.19
1226.2921140	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.23
Annotation	Unknow
Peak:m/z	Relative Intensity
115.9754868	0.03
116.9598160	0.02
119.1235886	0.07
124.0561676	0.10
128.9818115	0.11
130.0062408	0.11
132.6333313	0.11
147.0766296	3.68
149.8299255	0.08
151.8041840	0.12
156.3595581	0.02
164.3537292	0.32
165.0737000	4.84
180.0404816	0.57
181.9815674	0.86
182.9118347	0.05
187.9762726	0.01
191.1193390	0.04
195.0276184	0.09
197.1741486	0.08
203.0744019	0.02
212.1416931	0.13
213.2551880	0.04
222.9536133	0.03
224.2298889	0.11
227.9145813	0.12
233.6406250	0.05
235.0950623	0.05
239.2876587	0.19
240.4042664	0.04
241.1147461	0.08
249.1430359	0.08
251.8061523	0.02
253.0935059	0.21
255.1342468	0.04
256.1774292	0.05
265.8970642	0.16
266.9584045	0.02
268.2064209	0.17
272.9756165	0.15
276.1043091	0.02
282.0036621	0.15
284.0879517	0.02
285.1329346	0.03
285.9973450	0.08
294.9158630	0.04
298.1279297	0.51
299.2726440	0.15
300.0218201	0.09
302.8555298	0.14
304.0302124	0.07
305.9089355	0.04
308.9008789	0.88
312.2641602	0.05
316.2400513	0.12
320.7446899	0.16
327.1525269	100.00
327.7766113	0.39
329.0128479	0.03
332.8870239	0.24
335.1018066	0.10
335.8665161	0.26
346.9785767	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.033
Annotation	Unknow
Peak:m/z	Relative Intensity
78.9180756	4.65
96.8554611	100.00
149.1384888	0.23
178.9177094	0.13
216.8176880	0.08
238.9364014	0.69
241.2297974	0.26
247.1371765	0.14
259.0306396	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.28
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
186.0840454	0.16
196.1017456	3.37
214.1697083	2.49
255.2370605	100.00
255.8534851	0.37
269.9933472	0.23
271.1931458	0.59
272.270813	0.77
322.9300537	0.24
354.8869019	0.17
359.0748291	0.52
384.33078	0.53
388.5129395	0.19
391.2644958	0.78
392.2776794	0.74
395.0888977	1.51
406.5259399	0.64
408.3699341	0.26
425.1996155	0.96
434.2934265	0.99
435.6218872	1.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.0822
Annotation	Thiophanate
Peak:m/z	Relative Intensity
126.9245300	0.70
144.9382935	2.54
162.8121796	1.26
175.0965271	0.15
177.0761108	0.30
200.0914612	0.36
205.0966644	0.23
209.0733643	0.31
217.0282745	0.04
236.9262085	0.06
245.1953125	0.10
264.7857666	0.12
272.2504578	0.39
274.8805847	0.07
278.6410217	0.13
280.0975342	1.05
281.0975342	10.23
282.0693970	0.09
282.6887207	0.10
283.8642273	0.56
289.9959412	100.00
291.0785522	1.00
292.1395264	0.33
293.0930786	0.26
294.2845459	0.17
296.7056274	0.03
299.0274658	0.13
308.4024048	0.23
309.9258423	0.81
310.7034912	0.11
312.9732666	0.29
316.5458679	0.30
321.1995544	0.07
324.8770142	0.35
326.9838257	1.10
327.6477661	0.18
329.8510132	1.59
330.9059753	0.13
338.8679199	0.26
340.6744385	0.23
347.7968750	0.48
350.2318420	0.08
353.0216980	0.83
353.7047424	0.05
355.2926331	0.18
357.0978394	0.53
361.6642761	0.83
362.5958557	0.04
380.0121460	0.23
399.0080872	0.95
416.6018372	0.21
417.2377930	0.17
429.0565186	0.04
444.8468628	0.11
456.9513855	0.22
459.0171509	2.49
470.9792175	0.44
488.9656372	4.59
516.4885254	0.22
517.8459473	0.16
518.9871826	0.96
560.1841431	0.03
561.0704956	0.21
576.3374634	0.07
577.1190796	0.13
578.9691162	15.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	2'-Methoxyflavone
Peak:m/z	Relative Intensity
79.0880661	0.22
81.04192352	0.87
82.79684448	2.94
85.01753235	0.65
86.7288208	0.28
88.86175537	0.15
94.89389038	0.83
96.96205139	4.33
103.0591278	1.93
104.1062012	0.18
105.0407257	1.62
106.8614655	0.91
109.0453339	0.23
110.9351349	0.91
112.5865326	0.38
121.0231476	1.88
124.8132172	2.35
125.452652	0.46
126.1445465	0.17
126.9017792	0.69
128.9279633	10.51
130.1353149	0.44
133.1265717	2.43
135.1610107	2.36
137.1760254	3.53
138.886795	0.14
141.0211945	2.56
142.02565	0.29
144.9707336	1.76
149.1094055	1.49
150.960556	65.92
151.9782867	3.16
153.0001678	1.60
154.1305695	1.34
154.925354	2.55
157.1349792	0.71
160.8856354	0.60
162.5955811	0.65
165.1155243	2.21
166.9080658	2.79
168.7897491	2.08
171.0668182	0.48
172.9286499	0.37
175.0019989	0.17
178.0379639	0.53
179.040741	3.05
181.211319	0.65
182.1072235	0.83
183.1491241	1.69
185.0527344	0.40
191.0970459	1.40
192.0583344	0.74
195.1090546	1.41
197.0370941	8.63
199.076416	1.70
207.2249603	2.25
209.1030731	3.62
210.0099487	0.37
211.1817169	0.46
212.2666473	1.02
217.2474213	4.83
222.8940277	0.57
225.1664581	11.87
225.9707184	3.36
235.0960693	20.74
236.1864777	0.52
238.1067505	10.91
239.2345123	1.34
244.6711884	0.56
250.9569244	0.68
253.0953827	100.00
254.031662	19.00
254.668869	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.83631134	0.91
94.70300293	0.89
98.98425293	0.24
100.768631	0.14
105.0541687	0.31
107.1274796	0.47
108.9289474	0.25
110.8532639	1.52
113.013092	0.46
114.8586273	0.21
119.1209717	0.81
121.2243652	0.22
123.049881	0.82
124.0498886	0.55
127.0147324	1.07
128.8552551	0.25
131.0966492	0.15
132.9616394	0.56
134.9305725	1.23
137.0406799	0.36
139.1090088	0.91
140.9973297	0.52
141.9636688	0.13
143.1559448	0.91
144.7790833	0.57
148.7539673	0.40
150.9552917	0.81
153.1052856	1.04
154.6002808	1.73
155.3210754	0.35
156.1377563	0.13
157.1778107	1.57
158.9152222	0.48
161.3050079	0.09
163.0511627	1.00
165.1165009	0.51
166.6793976	0.91
167.3711243	0.41
168.8134308	1.38
170.8486481	0.73
172.9851074	0.58
173.9624634	0.31
174.9672089	0.30
177.0177917	1.54
179.246933	0.17
181.0709381	2.38
182.9890442	2.53
184.9549713	1.36
187.3241882	0.13
191.3315735	0.47
193.0991516	1.40
195.0289307	1.07
197.1644592	2.33
199.0723724	1.41
201.3047638	0.53
203.4011536	0.23
205.066803	0.56
207.0029602	0.10
209.0255737	0.80
211.1332397	3.44
213.1140442	2.06
215.3382263	0.32
217.2529907	0.56
219.2597046	0.18
220.2815857	0.12
221.1205444	0.44
223.0781555	0.25
224.0410156	0.22
225.3190308	0.96
227.0589294	2.05
229.1919861	0.95
230.3752441	0.32
233.1279907	1.96
235.0103149	0.52
237.2324829	1.78
239.1423645	0.76
241.3261108	0.23
247.0841064	1.32
249.2085571	0.96
250.0854492	0.32
251.1904602	1.77
252.5352173	1.21
253.1676331	4.88
257.2081299	0.31
265.1122742	1.48
265.984436	0.09
267.1913452	1.72
268.0885925	0.28
269.0873108	0.27
270.376709	0.18
275.2404785	12.18
280.0317383	0.11
282.2125549	0.17
283.1963196	2.59
284.0265198	0.13
290.833374	0.14
293.2086792	100.00
294.0105896	0.09
302.4227295	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.90119171	0.12
92.94457245	0.23
95.02774811	0.47
96.86218262	0.76
98.9552002	0.27
100.7880707	0.13
103.0959625	1.13
105.0056	0.40
106.9528351	0.17
108.9018478	0.06
111.1055756	0.17
117.1045532	0.21
119.0007935	0.11
121.1266632	0.16
123.1348724	0.84
124.8528595	0.16
125.9231873	0.19
127.0216141	0.31
127.8159485	0.36
129.1204529	0.93
130.8026276	0.14
133.1482849	0.32
135.0963593	0.52
137.0088654	0.38
139.0307007	0.64
140.8540344	0.61
143.1364136	0.63
146.9897003	1.37
149.1106415	0.52
150.9984131	1.64
152.2266846	0.23
152.9805603	0.69
154.1984863	0.56
154.9545288	1.28
158.9678802	0.50
160.9190063	1.04
163.0591888	0.71
165.1442566	0.39
167.276001	0.19
169.0393066	1.58
171.1289368	0.15
173.20755	0.70
175.1809235	0.96
177.0698242	1.60
180.1697388	0.20
180.9989166	1.93
182.9137878	1.33
185.2188873	0.17
186.8111572	0.16
189.1370087	0.21
191.8676453	0.68
193.0274506	1.22
194.9763947	0.36
197.0454559	0.75
200.8900452	0.34
205.0572205	0.78
208.9918823	0.19
211.092865	3.36
212.0321655	0.33
213.0794678	0.40
214.9640198	0.26
219.0867615	0.75
221.1109314	0.09
223.1320801	1.27
224.1745911	0.47
225.1262817	0.95
228.1784363	0.18
229.2147522	0.57
230.1567383	1.52
231.1062927	0.11
233.2167664	1.46
235.2351074	0.41
237.2978821	1.23
239.1881409	1.84
241.2287903	0.67
244.0306396	0.74
247.0876465	2.03
249.4244995	0.80
250.1164246	0.18
251.0601807	4.16
253.200531	5.44
255.3518372	1.96
256.1776733	0.54
257.3229065	2.09
260.8084106	0.33
263.2739868	0.15
265.2881165	2.64
267.0738525	0.75
268.3207397	0.34
269.2792969	1.54
270.1187134	1.06
270.7485352	0.38
271.9334106	0.24
275.189209	13.78
279.1488647	0.73
279.8596191	0.16
281.2011108	0.47
282.7258911	1.29
283.330719	3.18
287.8721924	0.31
293.2097473	100.00
293.8556824	0.13
294.7828064	0.20
296.1822205	0.21
302.2635193	0.45
311.4345703	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.88
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8259583	0.03
232.9421234	0.01
244.1882629	0.06
245.0004120	0.02
247.0032501	0.05
273.0276489	1.83
274.8413391	0.04
288.9489136	4.97
299.7532654	0.05
342.6835938	0.08
387.0031738	2.10
389.0601196	0.02
389.8624268	0.03
401.1344604	0.05
402.9332886	20.37
404.3542480	0.07
474.9375000	0.05
501.0025635	0.75
515.0783691	0.36
516.8182983	100.00
517.4280396	0.54
540.2479858	0.07
540.9542236	0.03
542.9694214	0.05
546.0214233	0.03
556.9699097	0.16
563.0125732	0.06
575.1524048	0.02
583.6705322	0.06
584.7521362	0.84
585.3611450	0.04
586.9722900	0.06
598.8342896	0.07
600.5040894	0.12
602.9982910	0.05
613.1454468	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2416
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
84.94185638	0.08
91.0355072	0.07
92.89742279	0.20
94.92173004	0.79
95.84706879	0.09
97.06967163	1.87
99.07440186	0.46
102.9991913	0.21
106.8019791	0.18
108.9802399	1.93
110.888092	0.48
113.0225677	0.24
114.8530273	0.29
119.0498505	0.46
121.0939331	1.05
122.9292908	1.59
125.0729675	0.17
127.0155869	0.23
133.0990295	0.30
134.910965	0.45
137.0259399	0.22
139.0394745	8.72
141.0964508	0.33
142.994873	0.48
144.9008026	0.11
149.1408997	0.15
151.1092834	0.68
153.1063538	0.63
153.8724976	0.24
155.1446838	0.34
157.1112061	0.13
161.0118713	0.17
163.0047302	0.36
165.2035217	0.22
168.8388062	0.93
171.1770325	0.07
173.1253967	0.48
175.0611267	0.87
177.2399902	0.14
179.1505127	0.59
181.2245941	0.11
183.0366211	0.52
184.7963257	0.20
186.2233887	0.13
187.2703094	0.35
189.0441132	0.23
193.0988007	0.09
195.0856934	0.55
197.1494446	6.41
199.1046143	0.74
201.2023315	0.30
203.1723328	1.35
208.907135	0.42
211.1025085	2.13
213.2799072	0.34
215.2864685	0.37
216.1029663	0.11
217.06073	0.10
219.3178711	0.24
220.6469421	0.28
221.2485352	3.33
223.0235291	0.29
224.043457	0.10
225.1591797	0.46
227.3649597	0.10
228.124939	0.14
229.3719482	0.06
233.0732727	1.16
235.3986816	0.33
237.2105713	3.65
239.1366577	13.86
241.2001648	0.53
243.2633057	0.72
246.4859314	0.32
250.1546326	0.25
251.3648071	0.34
252.1635742	0.10
253.1746521	1.11
255.0683289	3.13
255.78302	0.12
257.0924072	0.93
261.208313	4.69
269.2709961	0.73
271.111908	0.32
273.9252014	0.06
276.238739	0.64
279.2330322	100.00
281.0967712	0.53
287.6994324	0.55
288.5215454	0.97
297.1362915	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.65
Annotation	Unknow
Peak:m/z	Relative Intensity
207.1163940	0.01
211.0573730	0.04
212.8113861	0.04
290.8297119	0.17
293.0578308	0.04
294.7631226	0.06
296.7621460	0.33
380.7970581	7.89
411.0640869	0.02
453.1823120	0.02
460.5046387	0.07
462.0719604	0.12
462.7202148	0.09
464.6115723	31.63
465.3619385	0.06
466.2102051	0.01
544.6411743	0.02
545.8159790	0.07
546.6668701	0.55
548.5737305	100.00
564.2168579	0.03
568.7468262	0.07
590.7822266	0.01
614.9685669	0.07
615.9423218	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	292.92
Annotation	Unknow
Peak:m/z	Relative Intensity
97.1781921	0.05
102.9391937	0.08
120.9739990	0.03
131.0928802	0.07
169.0111237	0.04
173.1016541	0.03
176.9514771	2.44
189.4477386	0.02
194.8738708	100.00
202.8776855	0.44
219.1875000	0.02
227.1372375	0.05
229.1710815	0.02
244.8617554	0.03
275.1627808	0.16
284.4348145	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1349
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
173.1599274	0.11
175.2225647	0.16
177.0064392	0.37
179.0191803	0.05
187.1157532	0.55
190.8566895	0.07
202.4982452	0.29
203.1006927	0.36
205.0238190	0.33
217.0865326	0.09
223.1665649	0.16
227.1796722	0.06
231.2672729	0.07
241.3242188	0.05
245.1712341	2.63
255.3043823	0.34
261.2966003	0.21
269.0626526	0.16
271.1967773	0.16
273.0888062	2.38
281.2990112	0.07
287.0625000	5.45
287.7765808	0.11
289.1535339	16.46
290.2709351	0.10
299.1394043	5.29
301.4026489	0.09
305.3187866	0.10
327.3572388	0.05
329.1045532	0.30
331.1041870	0.94
339.2464600	0.52
350.9404907	0.06
353.2885742	0.13
357.0325317	0.24
361.1218262	0.12
365.2397461	0.12
367.3723145	0.12
369.1467285	0.04
381.2478638	0.78
385.1044312	0.62
397.1273193	0.18
407.1561890	60.23
409.3403931	0.45
410.2188110	0.48
415.1465454	3.01
416.3302612	0.10
423.3560181	0.37
425.1624146	100.00
430.9827881	0.15
433.0610352	0.41
449.3533936	0.44
450.1387329	0.36
451.2273560	22.48
457.1256714	2.35
467.0411987	0.53
467.6458740	0.13
471.1246948	0.11
480.6513062	0.38
487.1083374	13.80
487.7550659	0.04
491.5372925	1.32
492.2973022	0.12
493.1312256	0.48
497.2857666	0.29
499.1409912	0.23
500.5527954	1.27
515.4916382	0.42
517.2742310	1.52
528.3358765	0.18
529.1484375	0.08
531.3637085	0.08
533.3050537	1.31
541.0058594	1.17
541.7108765	0.20
547.2088013	0.31
548.3702393	0.14
557.4048462	0.77
559.2717285	5.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9715
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9206848	0.01
152.8854065	0.02
173.1061096	0.05
187.9363708	0.03
201.9667358	0.12
203.9545135	0.02
222.0442505	0.01
228.0409393	0.01
244.0157166	0.07
257.3426208	0.01
260.1292725	0.06
264.0766296	0.02
269.9824829	0.05
275.3150024	0.05
276.2182312	0.07
282.2200012	0.03
285.9722595	0.02
298.5280151	0.02
304.0463867	0.22
305.4740601	0.03
307.1015015	0.02
308.0648804	0.03
314.1488037	0.01
321.3289185	0.09
329.3991089	0.07
330.0867920	0.06
332.0840759	0.33
333.7768250	0.16
334.9380188	0.02
348.0337830	1.46
363.3481750	0.01
376.0138245	0.16
378.8642883	0.03
385.0625916	0.08
392.0958557	0.04
393.9978638	100.00
401.0040894	0.02
402.0263977	0.02
403.0679016	0.04
404.4187927	0.12
419.9448547	0.73
420.7407837	0.04
423.8482361	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
128.0860901	0.09
134.0073395	0.51
135.0618439	0.33
137.0487366	0.13
156.0271759	0.19
162.078064	0.18
173.0608826	1.82
173.9684601	1.04
179.0236053	1.88
180.0063477	3.85
184.8097229	0.11
191.0306702	100.00
192.0582581	80.30
204.9263153	0.37
280.1055298	0.09
308.2154846	1.02
310.2579956	1.15
318.2614136	0.23
336.2438354	0.16
337.1802673	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.89529419	0.88
80.97528076	2.76
83.02935791	2.40
85.102005	0.68
90.83473206	1.36
93.06134033	0.26
94.95495605	6.43
97.06309509	2.56
98.98301697	2.90
102.7955017	2.97
105.0504303	2.98
108.9515076	0.47
111.007431	2.26
114.8926392	1.11
117.2163391	0.34
119.0349274	1.59
121.0751953	2.06
123.0221558	3.74
124.9139709	1.26
126.9039764	1.00
129.0133209	8.86
129.8702087	0.87
133.1109619	3.58
135.0721741	3.93
136.8828583	2.79
139.2154694	1.35
140.8174896	2.71
143.2149811	0.36
144.9796448	1.87
146.0841064	0.65
146.8273773	1.01
149.2477264	1.85
151.0007629	62.11
152.0095978	3.04
153.9950714	0.74
154.9479523	7.94
157.1232452	0.80
161.0235138	3.18
163.2204742	3.20
165.1517944	2.74
167.0717316	2.44
169.127243	7.08
171.1137848	0.67
172.0207672	0.61
175.0817413	2.63
177.0788727	2.82
179.2274017	6.02
180.0784454	0.50
181.1790009	2.77
182.9766388	2.09
184.8886871	2.30
189.0098114	0.99
190.9158173	2.23
193.229599	1.55
194.1331024	0.45
194.995575	4.88
197.0484467	6.09
199.1527405	0.70
203.0519562	0.17
205.0524445	1.44
207.0870514	4.48
208.2654572	0.98
209.1961517	4.29
210.2607574	0.63
211.0885162	11.81
217.1298065	17.20
219.2723541	0.85
223.1815033	1.46
225.1883087	12.29
225.8575287	0.40
232.7335205	0.30
235.1780396	45.40
236.1505127	0.61
237.9936066	9.07
239.2335358	0.34
253.0877838	100.00
254.1777496	16.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
109.0565948	0.02
111.1147461	0.08
127.3727112	0.02
129.0950623	0.03
133.2496643	0.02
134.9940643	0.85
137.263382	0.02
142.8069	0.04
155.0032654	0.09
161.0375366	0.40
170.813446	0.02
173.0084839	2.76
179.0281677	4.93
191.0342255	100.00
217.1677246	0.04
219.0039978	0.03
307.052063	0.06
309.1051941	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.19
Annotation	Machaeriol D
Peak:m/z	Relative Intensity
134.9926758	0.12
147.0181274	0.42
150.9146118	0.71
166.0911255	0.16
175.0036926	0.27
177.1858826	0.27
187.1651306	0.46
191.2403259	0.32
197.1608734	0.15
206.9226074	0.26
212.9814301	0.50
215.9083252	0.16
217.0831757	0.71
223.1405945	0.32
229.0422974	2.32
234.9189758	0.34
239.0744629	2.03
243.140564	0.34
247.1210632	1.54
248.0864258	0.20
249.0755005	0.73
261.4889832	0.39
262.973877	0.22
266.898468	0.24
277.0643311	0.32
279.036499	0.66
289.0956726	1.05
289.9754944	0.66
291.2480164	0.19
297.2640991	0.24
298.2298889	0.52
299.2431641	0.68
306.1916809	0.48
309.5100098	0.16
312.2597961	0.46
316.1132202	1.63
317.338623	0.96
317.9687805	0.16
321.4179382	2.42
325.5556641	0.16
330.3000488	0.39
334.2103882	0.33
335.3622437	0.32
337.092926	0.46
337.7428894	1.02
342.82901	1.81
344.1348572	1.73
347.1703796	0.25
349.9454651	0.59
351.3572388	0.13
361.1808777	100.00
362.2169495	28.71
363.0990295	0.17
370.8312988	2.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1086
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
126.7672272	0.03
134.0742950	0.15
144.9446106	0.09
148.9900055	0.09
160.9264832	0.15
164.9409485	0.06
179.1540527	0.06
191.1047058	0.26
193.1009674	29.58
195.1134338	0.03
206.0113678	0.04
207.1622925	0.17
219.2738342	0.07
221.1331635	0.57
223.1868591	0.05
225.2410583	0.05
235.1583862	0.03
239.0729370	0.10
249.1420898	0.10
255.3099976	0.05
256.6203003	0.05
261.0199280	0.14
265.1755066	0.22
267.1496887	0.87
276.7819824	0.15
281.2758789	0.10
295.1364441	0.43
296.1997070	0.08
300.2379150	0.04
303.9230347	0.06
307.3458252	0.15
309.0893555	0.19
311.0520020	0.11
325.1142273	0.16
340.9639282	0.26
344.8141174	0.15
355.1881714	100.00
357.3124084	0.24
365.3211365	0.18
371.0324402	0.03
381.1408386	0.05
383.0574951	1.10
383.9404297	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.9152985	0.04
126.97892	0.07
128.2005463	0.10
135.1546936	0.47
135.9724579	0.90
154.9539948	0.11
160.9715424	0.61
162.0084839	0.48
171.0787354	0.11
173.0409546	3.09
174.0774231	1.68
179.0920715	5.32
180.0904236	4.93
191.0386658	100.00
192.1091309	86.41
266.9906006	0.05
307.5293579	0.04
310.1690369	0.41
318.2280884	0.05
336.0752563	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9868927	0.22
212.9483795	0.21
247.2987671	0.09
284.3530273	0.02
290.8162231	0.81
292.6033936	0.05
293.2087708	0.07
294.7584839	0.08
296.7332764	1.81
297.5234375	0.07
298.5633545	0.19
299.2377930	0.03
358.8002930	0.02
375.2080078	0.02
378.4973755	0.21
380.8031006	22.92
460.2269897	0.07
461.8246460	0.28
462.6503296	0.89
464.5875244	100.00
465.2702637	0.32
483.3956909	0.06
502.9885254	0.06
504.3449097	0.02
529.9161987	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.1967
Annotation	13-Hydroxymyristic acid
Peak:m/z	Relative Intensity
72.89746094	4.26
92.86169434	2.11
94.85954285	5.69
113.1663513	5.02
115.8633423	2.11
129.2824402	1.53
135.0274811	3.55
158.9330292	1.97
161.0370178	1.67
162.9363251	2.40
168.9129639	1.84
171.2192535	3.26
174.9035187	25.49
179.136322	7.31
181.1962891	38.08
183.1251068	14.46
185.1964264	1.39
187.0740356	2.69
195.2865448	2.90
197.146225	46.39
199.1620941	23.81
201.0878448	3.72
215.2687988	2.40
223.1179657	3.40
225.1933136	100.00
225.9880371	1.38
227.2430267	17.45
243.1706085	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8550110	0.13
290.8624878	4.60
374.6274414	1.72
436.6475220	0.03
458.5758667	20.64
459.2823486	0.06
482.6899414	0.02
502.8348389	0.14
520.6076660	0.03
539.7819824	0.11
542.4942017	100.00
543.1931763	0.64
544.6116943	1.13
548.8694458	0.12
550.7725830	0.03
566.6696167	0.11
574.4109497	0.31
580.4944458	0.15
590.6387329	0.18
604.4562378	2.65
605.2788696	0.03
624.0436401	0.07
625.7996216	3.17
626.4605103	19.78
627.1736450	0.06
627.7833862	0.02
646.5468140	0.18
650.6404419	0.71
664.5462036	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0874
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.8172684	0.12
111.2287216	0.08
125.2306213	0.26
127.2498627	0.11
135.0708313	7.03
143.3312988	0.08
155.0798035	0.56
161.0563354	0.47
167.1296082	0.07
171.0164337	0.24
173.0860138	3.67
179.0069275	44.12
191.0225830	100.00
199.1250305	0.05
210.9663544	0.09
221.1287231	0.05
233.0821533	0.05
238.0358582	0.16
268.8353271	0.04
281.3080444	0.25
288.5837402	0.17
291.4166260	0.15
293.2427368	0.11
295.1926270	0.15
307.1997681	1.13
308.9533691	0.38
310.1539307	0.10
323.1888733	0.21
334.9022827	0.14
335.5764160	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
143.1338806	0.11
146.1255646	0.39
154.6845856	0.06
158.863205	0.09
164.9784851	0.07
169.8329926	0.22
179.0733185	0.45
180.2765808	0.96
181.3687134	0.62
183.1572113	0.14
193.0859528	0.48
194.0780334	0.26
206.1332092	1.21
207.0744476	2.98
208.1177216	1.90
209.161911	0.77
210.3172455	0.08
213.2648468	0.05
222.0782013	2.08
223.0333099	4.05
224.0964661	0.85
233.292923	0.69
251.0661469	100.00
252.0745239	19.42
252.6940918	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
134.0931396	0.05
135.1654816	0.20
136.0223999	0.23
143.9311523	0.10
155.1436768	0.13
160.8363342	0.20
162.0289154	0.40
171.1318359	0.07
173.1057587	1.71
174.0965576	0.58
174.9545288	0.14
179.1153259	3.16
180.0733032	4.90
182.2895966	0.08
191.0521393	100.00
192.1093292	79.30
192.9990082	0.36
199.9169769	0.19
263.9290466	0.53
269.0995483	0.20
274.2427979	0.20
288.0958862	0.07
295.3606567	0.07
308.2507324	0.20
309.5497437	0.23
310.4456482	0.13
319.0849609	0.20
336.1869202	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
84.91862488	0.20
117.0568542	0.41
145.9296265	0.16
148.9533539	0.31
157.1751556	0.17
161.0718689	0.40
169.0110931	0.43
177.0792084	0.56
181.1212006	0.78
183.4423523	0.15
194.1624603	0.23
195.1891174	0.49
199.1438141	0.21
204.8199005	0.53
206.0972443	0.83
207.1135712	4.79
208.1554413	3.40
208.9260864	1.80
222.2092133	2.90
223.0261688	4.80
224.0886688	0.43
233.4055023	0.97
235.2261353	0.26
251.0828247	100.00
252.0963745	16.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
131.0609741	0.27
170.9905548	0.30
181.1745148	0.54
184.9871521	0.89
187.0591736	0.46
196.7603455	0.32
198.989563	0.92
201.0093384	2.10
213.2979736	1.10
214.8817749	2.95
221.2540894	1.07
222.7844543	0.47
227.4474182	0.54
228.5606689	1.65
229.1896057	1.51
239.3908386	0.28
241.2317505	0.67
243.2999573	1.67
244.9996948	0.80
253.2206726	0.21
255.1332397	0.23
257.2239685	1.37
259.3765869	0.38
261.0574951	0.20
263.1591492	3.02
267.1962891	0.64
269.2706299	2.36
271.2124634	5.68
273.2149658	0.19
279.4234619	0.29
283.1400146	2.87
285.4653015	5.48
291.5342712	0.30
293.3929443	0.20
295.2191162	1.28
296.2590637	0.16
297.1530151	0.51
298.105896	0.30
299.2041626	2.89
301.1329346	0.28
303.1777039	1.52
311.0361328	3.00
312.1129761	0.19
313.0827637	2.99
315.2577209	3.29
321.1306763	1.39
323.3700562	9.95
327.4448242	0.23
339.250061	100.00
341.2645569	25.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.1229
Annotation	Unknow
Peak:m/z	Relative Intensity
104.1771851	0.15
115.8234482	6.54
133.9904175	100.00
147.1200256	0.05
153.1390686	0.12
159.3350525	0.12
160.4068604	0.04
163.1185913	0.05
183.0868530	0.10
187.1112213	0.06
191.3466492	0.09
211.0711670	0.21
213.1115112	0.14
215.3404236	0.09
225.1337585	0.07
238.9185486	0.04
243.2993164	0.05
246.1588745	0.13
271.1461182	0.06
273.2960205	0.59
288.4163513	0.03
289.6550903	0.19
293.9353333	0.19
297.7772827	0.95
298.6455078	0.25
299.3772278	0.13
307.4562378	0.21
308.5710449	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
97.0919342	0.04
105.0224457	0.03
109.1227875	0.27
110.9891510	1.79
117.2441864	0.04
125.0704193	0.06
135.1150513	0.06
135.8477173	0.03
136.7469177	0.04
138.0076599	0.06
139.0821991	0.12
142.9893799	0.02
147.0117950	0.06
148.0900879	0.08
149.2319183	0.02
149.9433899	0.14
151.1132812	0.16
153.0120239	100.00
159.2169342	0.05
161.1090851	1.09
175.0812225	0.06
176.3690338	0.03
177.0370331	0.19
179.1856842	0.04
185.6739960	0.21
189.0484467	0.03
201.1876831	3.03
203.2592316	0.71
204.1895905	2.34
211.3633118	0.04
217.1505127	0.17
219.0899963	31.40
219.6903076	0.19
221.2075043	0.20
226.9320374	0.05
228.6295624	0.04
230.0003204	0.02
242.9965973	0.06
244.2783813	0.16
245.1309052	1.98
247.1798248	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.9922
Annotation	Unknow
Peak:m/z	Relative Intensity
80.9570007	0.10
96.9456177	0.87
98.9233551	0.08
109.1694641	0.28
109.8627167	0.08
112.0003128	0.51
113.7632751	0.41
116.1432495	0.09
125.8923798	0.28
127.1222839	0.08
127.9866867	0.43
131.8769531	0.60
136.0432281	0.08
139.8480377	0.56
142.0439148	0.23
143.8815918	2.52
144.8526611	0.84
146.2345123	0.09
148.0806580	0.08
151.9318542	0.24
153.7846985	1.32
154.8362122	0.50
155.8706665	0.89
156.7376709	0.72
157.9265289	0.62
158.7733765	0.24
160.8939209	0.13
162.0281830	1.23
162.9057312	0.16
163.8647156	0.34
166.0077820	0.29
167.9050293	0.76
168.8072815	0.42
169.9593811	47.82
171.9681549	0.75
173.8654785	94.68
177.0990906	0.13
178.1155396	0.22
179.1636963	0.12
181.8963013	15.09
183.9440613	1.62
185.0681763	0.15
185.9248657	5.44
187.6641235	5.23
191.7965546	1.03
193.9198608	0.90
195.9486694	0.29
196.9317627	0.68
197.9703064	21.07
199.9623718	51.23
201.9151917	1.94
203.9637451	4.47
210.0011902	28.61
211.9479065	35.90
213.1232605	0.32
213.9004822	1.28
215.8365784	37.17
216.9666443	5.22
217.9510498	7.54
219.0530090	0.46
221.0061035	0.34
227.9066467	100.00
229.0675659	1.74
229.9155273	21.15
231.7368774	2.20
232.8243408	0.73
234.8526306	49.63
235.9633789	2.00
238.4396667	0.16
239.9259644	13.05
240.6884155	0.63
241.7626953	0.11
243.8243713	1.25
245.8326111	19.26
247.1979980	0.66
247.9047852	3.08
248.8094482	0.37
249.7862549	0.25
252.8627625	7.69
253.4721069	0.18
254.9714966	5.68
255.9470825	1.96
257.8782959	89.79
261.1610413	0.36
261.9953003	0.53
263.4324646	0.77
264.2924805	0.38
266.4094238	1.54
267.0638428	3.86
270.3462219	0.30
272.1397705	0.09
275.8516235	3.04
276.5467529	1.10
284.7071533	0.90
285.4256897	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2416
Annotation	[R-(E,E)]-13,14-Dihydroxy-6,10,14-trimethyl-5,9-pentadecadien-2-one
Peak:m/z	Relative Intensity
87.16825867	0.25
90.99641418	0.88
93.03855896	0.62
95.01818848	0.90
96.80904388	1.26
98.98348236	0.50
101.377861	0.11
102.9138718	0.43
105.0427399	0.24
106.9939728	0.72
109.0774994	3.04
112.8943863	0.77
114.9719162	0.28
116.8431244	0.17
118.9678955	0.93
121.0487366	1.76
121.9344025	0.09
123.0804138	3.71
124.9263611	0.41
127.0780716	0.06
129.1554565	0.07
131.0046692	0.81
132.9669342	0.58
135.1255798	1.83
137.2073975	0.64
139.0697327	2.82
141.1636963	0.19
142.3623962	0.13
143.0170288	0.93
145.0132446	0.80
147.2068787	0.53
148.9887695	0.79
150.0153503	0.10
151.0388489	0.51
153.0354919	2.90
155.0151978	0.79
155.9662628	0.11
157.0265198	0.77
158.1372375	0.18
159.1933289	0.19
161.0187683	0.84
163.1080933	0.68
164.9760284	0.49
167.194458	1.37
169.1087952	1.78
171.1540985	2.29
173.1884308	0.32
175.3083801	0.78
177.2156219	0.91
179.2337189	0.35
180.1676025	0.05
180.9435425	0.16
183.0707855	3.93
185.2444153	1.18
187.1320496	1.02
189.0453186	0.10
191.1384125	0.77
193.0389709	0.47
195.207901	0.44
197.139389	5.99
199.1488647	0.47
201.2025146	0.36
203.1480713	0.20
205.368988	0.17
207.0340881	1.08
209.134491	1.46
210.0892944	0.31
211.0481262	2.77
213.2763367	2.19
215.5050659	0.35
219.1810608	2.10
221.1997681	2.73
222.2993164	0.22
222.999054	0.71
225.261261	2.69
227.137146	1.35
229.1557922	0.31
233.1889343	1.01
235.1740723	0.64
237.2660217	2.70
239.2104187	11.72
241.1294556	0.90
242.7268982	0.11
243.3503418	2.55
250.8228149	2.80
251.4402161	1.18
252.1417236	0.05
253.1651001	1.92
255.2547607	2.03
256.7113342	0.19
257.3167725	0.31
259.3777771	0.18
261.2803345	5.27
263.3921204	0.07
269.0328369	0.70
279.228302	100.00
279.8636475	0.31
281.2817993	0.47
288.1957092	2.21
297.2434692	0.45
298.5683899	0.19
302.4717102	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2417
Annotation	Moniliforminol A
Peak:m/z	Relative Intensity
84.77568054	0.04
88.66188812	0.06
91.11359406	0.19
92.91712189	0.10
94.08137512	0.13
95.00302887	2.41
97.06030273	2.06
98.17539978	0.10
98.98728943	0.78
99.86569214	0.07
101.10112	0.21
103.0148239	0.20
105.1318741	0.07
106.9876709	0.25
108.2883759	0.14
108.9600906	2.04
111.0087357	0.63
113.122261	0.31
114.0008698	0.09
114.9170532	0.40
119.0449371	0.26
121.0047455	1.29
123.032486	3.00
125.007515	1.05
126.9251709	0.82
129.0908661	0.43
131.0091095	0.29
133.0207062	0.18
135.0856323	1.62
136.4228821	0.39
137.0925903	0.94
139.0569458	4.81
141.037735	1.26
143.1229553	0.15
144.8786469	0.06
147.1207886	0.13
149.0610352	0.75
149.78862	0.05
151.1019897	1.40
153.0715332	3.03
154.0856018	0.05
155.062973	1.93
157.0362091	0.57
161.0421448	0.45
162.9775391	0.28
165.1036377	0.71
167.2166748	0.47
169.1009521	0.73
171.0776672	1.07
173.0491638	0.27
175.1420593	0.78
177.2803955	0.42
178.0914001	0.08
179.2372437	0.64
180.5291443	0.13
181.171814	0.29
183.1801605	1.33
185.1402893	0.85
187.1545258	0.27
189.0774231	0.30
191.3588867	0.14
193.1897583	0.86
194.895813	0.45
196.6092834	0.22
197.2117004	3.88
198.2285461	0.09
199.1600647	0.68
203.145752	2.76
205.1487732	0.17
207.1446228	0.53
208.2051086	0.26
209.1786194	0.92
211.0793762	1.06
213.2219849	0.58
215.1863403	0.05
216.9668579	0.11
219.2551575	0.84
220.7254944	0.69
221.3297729	5.01
223.1264343	1.09
225.1783142	1.37
227.1356506	1.11
229.2210083	0.03
233.2261658	1.89
235.4173584	0.55
237.2604675	9.94
239.2081604	19.59
240.9854431	0.39
241.9917603	0.11
243.2160034	1.81
249.1536255	0.05
251.2762451	1.68
252.2568665	0.19
253.1828003	1.01
255.2225647	2.69
256.8910828	1.26
257.6105957	0.13
259.3559875	0.05
261.1517334	4.64
263.3644714	0.10
267.45401	0.16
271.2541199	0.21
277.3930664	0.11
279.2338867	100.00
280.1967468	0.36
281.2596436	0.26
283.2583923	0.09
288.0732727	1.01
297.0540771	0.23
297.790863	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
126.8190613	0.06
128.0622559	0.07
128.960144	0.04
133.9457092	0.03
134.9926453	0.72
136.0136261	0.47
143.2938995	0.02
144.4940186	0.13
156.0842438	0.02
161.0073853	0.18
162.1145935	0.21
170.9967804	0.03
173.0794983	1.69
174.123291	0.85
179.0385742	3.14
180.0936584	4.38
191.0449066	100.00
192.0253906	75.96
268.1004639	0.05
308.210968	0.02
310.2606812	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
76.82385254	0.27
79.17100525	0.90
80.96929169	1.98
83.06015015	2.16
84.9122467	0.43
89.05047607	1.01
91.05887604	1.23
92.78572083	0.26
94.87193298	5.78
97.1426239	1.92
98.99403381	2.46
100.9084015	0.84
102.78862	0.31
104.8423004	0.62
106.9245911	0.44
108.8911743	3.09
110.9399109	1.59
113.0251312	1.86
114.9666901	0.77
116.7621155	0.20
119.004776	0.74
121.0782318	4.51
122.9505615	1.78
125.0482025	3.03
127.1468353	0.55
129.0318909	8.95
133.1278076	1.53
135.0301819	6.12
136.8804016	3.42
137.5142212	0.12
138.9258118	2.65
141.1074982	0.52
147.1068726	3.26
148.2333527	0.74
149.2053833	2.51
151.0001984	62.62
152.0243683	4.58
153.0462799	1.64
155.0240936	3.78
157.3345337	0.19
161.1527405	0.68
163.0460663	1.86
165.0660095	0.92
167.1299438	0.34
169.0722504	5.47
170.9925385	0.20
173.0485535	1.05
174.5870056	2.45
175.2099457	2.42
177.2131195	1.35
179.1340942	2.44
180.1348572	0.30
180.964859	1.34
182.5944366	0.90
185.2818909	2.65
186.0342102	1.34
189.0730133	3.39
191.1062012	1.37
192.2906189	0.24
193.1794434	2.29
195.063858	5.20
197.1524963	2.99
197.9490509	1.44
199.2978973	0.78
203.1500397	0.36
205.8755951	0.45
207.1558075	7.34
208.1620636	0.27
209.1779785	2.02
211.1869507	10.58
212.0869751	1.19
217.2218933	13.06
221.30513	0.16
223.2714996	0.55
225.2408447	9.64
226.2319183	1.83
235.1724396	44.81
236.1022186	0.24
238.0337677	4.88
238.8853912	0.22
244.6749878	1.76
253.1074982	100.00
254.1263275	15.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.95249939	0.11
80.96311951	0.10
84.94657898	0.63
88.81997681	0.34
90.93582153	0.10
94.96572876	2.17
97.14163208	0.85
98.68450928	1.16
100.9178619	0.11
103.0629578	0.47
104.8343353	0.30
107.0021362	0.22
108.9005737	0.61
111.0389099	0.52
117.034317	0.17
118.804657	0.98
120.9238129	0.90
122.8295288	0.97
124.3697357	0.44
125.0769806	0.64
127.0418549	0.27
127.9452515	0.30
128.9147644	4.03
129.846756	0.19
132.9693909	1.35
135.1698914	1.67
135.9802704	0.34
137.1550598	0.38
139.1498871	0.43
141.0563965	1.22
142.8518066	0.18
147.1704712	1.17
148.0103912	0.18
149.1634369	0.16
150.9603577	54.66
151.9190674	2.33
152.7733307	0.86
155.0852203	1.29
156.8858185	0.29
161.1844635	0.85
163.2427063	0.22
165.0532227	1.20
167.042511	1.40
169.0972137	0.92
170.9160004	0.17
175.0518799	0.63
176.9343414	0.51
178.2195587	0.74
179.0759125	1.12
180.8519287	0.16
181.9430695	0.21
183.087738	1.03
184.9873047	0.79
190.9251709	0.89
192.0944061	0.26
193.0361786	1.23
195.1370544	0.94
197.1577759	4.18
198.1129608	0.23
207.2580719	0.12
209.15242	0.44
211.2055969	1.73
217.1431122	3.60
225.098938	6.59
226.1043701	0.18
229.3029938	0.24
235.100708	12.31
235.710022	0.19
237.9898529	6.12
239.0919189	1.07
243.671402	0.36
250.9829559	0.63
253.0938721	100.00
254.1188507	15.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
84.9187851	0.31
96.94897461	0.27
101.1049957	0.96
114.9289398	0.11
123.8329468	0.25
149.0179749	0.36
150.4487762	0.38
152.4372864	0.12
155.0521088	0.31
157.0298767	0.17
166.8864441	0.22
169.2239685	0.13
170.5636749	0.89
178.2585907	0.15
179.1794281	0.93
180.1805878	1.26
180.940094	0.37
182.9745483	0.41
192.9675598	0.12
195.1585083	0.76
196.973465	0.39
204.9027863	1.06
207.2313232	6.62
208.0662537	1.93
208.887619	1.63
215.3447876	0.45
222.1429596	1.02
223.184433	3.32
232.056015	0.11
233.0951996	2.10
237.0304565	0.56
242.0616302	0.16
251.074646	100.00
252.1688385	15.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0874
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
126.9267502	0.04
135.1139526	0.44
137.0027618	0.09
154.8400726	0.11
160.8944397	0.27
171.1755066	0.12
173.1140137	2.93
179.0756226	4.68
181.033493	0.17
185.410614	0.04
191.0488739	100.00
199.0332031	0.10
237.3680725	0.03
241.0100708	0.06
262.989502	0.40
265.0181885	0.17
278.9615479	0.08
281.1366272	0.19
282.140686	0.04
291.0122375	0.10
295.3837891	0.06
301.0185242	0.08
307.1887207	0.85
309.216217	0.93
314.9178162	0.06
323.1101685	0.12
333.1907654	0.04
335.3141479	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8100586	0.32
208.9869843	0.66
212.8338318	0.55
254.8735809	1.08
284.8445435	0.03
290.8876343	3.97
292.8084412	2.49
296.9590759	0.08
314.9687500	0.82
336.9030151	0.11
374.6997681	1.56
376.3621216	0.76
376.9989014	0.21
415.1975708	0.89
416.3101807	0.05
456.8564453	0.03
458.5625610	10.28
459.8618774	2.89
460.6731567	17.04
489.3551636	0.03
532.9863892	2.29
542.5519409	29.35
544.4717407	100.00
545.5469971	0.36
625.3288574	0.06
626.4620361	3.28
627.7890015	9.35
628.4890137	20.82
629.0938721	0.10
665.6032715	0.09
669.5196533	0.06
695.2634888	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
127.1212463	0.04
128.151947	0.06
135.0755463	0.70
135.9572144	0.63
137.8531189	0.05
159.0962219	0.02
160.8355408	0.08
162.0201111	0.15
172.1467133	0.02
173.0103455	0.74
174.0412445	0.59
179.0692902	2.57
180.0270081	4.82
191.042984	100.00
192.0457764	76.34
199.8092041	0.11
246.0856018	0.10
264.405426	0.13
266.1964722	0.07
279.2241821	0.05
292.2989807	0.17
293.0377197	0.04
296.257843	0.04
310.2270508	0.29
324.0502014	0.12
326.0079041	0.03
327.2620544	0.04
336.6105652	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9794464	0.47
100.8722839	5.89
106.9017258	0.55
112.9977570	17.34
115.0268936	0.14
117.0780792	0.20
118.9695892	14.60
124.9133911	2.56
130.9952698	7.27
143.0383759	17.79
148.9685974	4.28
161.0195923	17.82
178.9685211	100.00
191.0382538	0.12
221.0563049	2.47
262.9671021	0.09
277.2996826	0.10
280.9484863	2.75
293.0068665	0.39
295.0869751	0.41
313.0780029	0.38
323.3325195	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393.15
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8087387	0.04
117.0437393	0.13
122.8027191	0.08
124.1013489	0.05
126.9558182	0.14
129.3008881	0.08
134.8104858	0.03
138.9358978	0.03
139.9107971	0.06
142.9406586	0.11
145.0855408	0.08
148.9951630	0.13
149.8621368	0.15
150.9677582	0.25
164.0524597	0.06
165.9331360	0.61
166.8608093	0.18
168.3436890	0.12
168.9488831	0.22
172.0870667	0.43
175.1054077	0.15
177.9925537	0.13
191.1948853	0.10
195.1430054	0.58
196.1863403	0.27
201.1490784	0.05
204.1951141	1.52
207.2160797	0.15
210.1020508	0.33
212.9943848	0.23
216.0358887	37.56
217.0050049	0.40
218.9649963	0.12
224.0516052	0.07
228.0932922	0.10
230.1112671	1.14
234.0398560	0.23
239.0860596	0.39
246.0552979	1.10
252.7549133	0.33
258.0243530	0.28
260.5622559	0.13
261.3934021	0.09
262.0867004	0.25
262.8009338	0.06
268.2827148	0.25
272.0426025	0.44
274.3198242	0.13
279.8823547	0.13
281.1509094	0.04
283.2848511	0.29
286.2224426	0.19
287.3485107	0.23
295.9059753	0.35
300.1126404	100.00
301.2650146	0.62
305.3439941	0.11
311.8807983	0.11
314.7803955	0.11
315.4420166	0.42
317.0772705	0.82
329.3069763	0.13
333.1134033	8.78
333.7570801	0.03
334.8903503	0.10
343.1870422	5.63
344.3446350	0.06
345.0593567	0.12
346.4841309	0.40
347.2544250	0.22
348.0107422	0.19
349.2640381	0.43
352.1530762	0.25
357.2055054	0.32
361.1610718	30.61
361.9189148	0.09
363.3358459	0.16
365.2523499	0.14
371.5118103	0.28
375.1132507	61.70
376.0917358	0.63
384.4138184	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
122.8817139	6.66
130.8811798	9.75
134.8580933	5.98
137.200531	2.48
141.2941284	5.48
149.0396118	2.63
153.2588654	2.49
154.8660126	3.53
156.8170776	2.48
165.2262268	3.51
173.0213928	1.72
180.9433899	8.15
187.3201599	15.03
189.0126038	6.88
197.09552	3.36
207.0841064	4.16
215.2494049	3.93
220.0065918	16.18
229.1331482	1.87
234.0126648	3.86
237.2175293	6.25
239.3476257	1.72
245.430542	7.67
246.3667603	3.97
248.0068054	6.45
249.16922	3.58
256.7846375	1.72
258.979248	1.88
266.1843567	2.02
268.2305298	2.36
269.197937	1.72
270.2837524	10.08
272.1542358	2.50
281.3828125	3.54
284.2711792	5.06
285.0950317	5.08
293.1565247	10.42
294.2426147	1.72
298.1868896	4.43
308.1229248	2.48
312.26828	5.80
313.1264648	4.60
325.0995789	14.20
328.49646	2.79
330.5353394	14.66
336.4557495	4.58
339.2900391	33.87
341.0145264	25.01
342.2437439	8.62
342.9043579	2.95
354.5735168	1.75
362.5369263	2.18
365.6223145	8.35
366.4795227	2.33
373.4007874	5.59
375.1806946	4.02
376.77948	3.05
380.346405	5.68
381.2217102	6.76
382.3432312	4.16
384.4792786	2.94
385.8641052	32.44
390.2406311	13.56
391.2557373	9.10
395.3128967	7.37
398.3681946	25.79
399.238678	5.58
407.0273132	1.72
408.2756653	100.00
409.1904602	20.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.09
Annotation	Gerfelin
Peak:m/z	Relative Intensity
95.0459137	0.14
103.9924622	0.22
104.9655457	0.58
108.9483337	0.18
110.8339081	0.10
114.7532501	0.03
118.8665619	0.12
122.9166183	100.00
124.7210083	0.07
126.9832458	0.38
127.9673615	0.25
132.9338226	0.08
134.6907959	0.06
136.9340515	0.47
138.9842529	98.77
141.1613922	0.04
147.0207214	6.56
149.1363220	0.17
150.9595032	27.47
153.0738525	0.53
154.9509888	0.21
159.0664825	0.16
163.0743866	0.19
165.0490265	47.88
169.0664673	1.60
173.2401581	0.16
175.1949463	0.12
176.9095306	0.15
180.8849792	0.50
187.3795624	0.31
191.1335297	0.08
193.0962067	0.11
195.2505493	0.25
200.9488525	3.61
202.1139221	0.16
203.2714539	0.07
203.9088135	0.15
205.0363159	0.56
206.3865051	0.11
207.1083679	0.13
209.0603027	0.06
212.6996460	0.15
216.1920776	0.09
217.0830688	0.10
218.0648804	0.18
226.9708557	0.24
228.0489807	0.13
228.7495728	0.19
230.9493713	0.43
233.1175842	0.12
235.2072754	0.18
236.8833923	0.34
241.3026733	0.19
243.3982544	0.15
245.0297241	0.92
245.7987671	0.45
247.2703247	0.26
247.9279175	0.27
249.1244202	2.64
249.9682617	1.25
250.9974365	0.17
255.5339661	0.34
256.4673462	0.04
260.0726929	0.09
262.5320740	0.85
263.3082886	1.15
264.2429199	0.13
266.9712524	0.06
268.0043640	0.23
273.0308228	26.63
274.0628052	0.40
274.8130493	0.38
281.8529053	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9018555	9.90
211.3507233	0.08
212.8452911	5.76
220.7996216	0.04
228.9812012	0.14
296.6905823	100.00
297.3670044	0.66
334.0680542	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	722.64
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0556793	0.02
296.8959961	0.03
299.1253967	0.04
300.0615845	0.02
303.0038452	0.36
323.0740662	0.18
380.9461060	0.06
382.7343750	0.05
383.8482666	0.02
384.6605835	0.09
386.7634888	1.12
464.5241699	0.03
466.0139160	0.04
467.1997070	0.30
468.6012573	0.04
470.6952515	9.84
471.3342285	0.02
508.8645630	0.05
535.7459106	0.03
550.6720581	0.04
551.5800171	0.20
552.6149902	0.45
554.5628052	40.36
555.2709351	0.15
587.3286743	0.08
593.1350708	0.01
635.8598022	0.17
638.4340210	100.00
639.1782227	0.13
676.0161743	0.04
678.8037109	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2995
Annotation	4-Hydroxysphinganine
Peak:m/z	Relative Intensity
92.88179779	0.13
95.0279541	0.40
97.17800903	0.07
98.8507843	0.03
107.0543518	0.52
109.0966339	0.11
111.0565033	0.17
112.8503189	0.19
114.9011459	0.08
119.0057755	0.03
121.0088196	0.21
123.1026154	0.18
124.102684	0.04
126.7019119	0.10
129.0766907	0.06
130.9561615	0.09
133.1137695	0.09
135.1512451	0.29
137.1107788	0.46
139.2911682	0.27
141.0695801	0.34
142.979187	0.03
144.942688	0.05
146.313324	0.10
147.1361694	0.30
148.9267883	0.17
150.9770508	0.24
152.8641663	0.32
154.775238	0.08
156.7601318	0.03
160.115448	0.04
161.2350769	0.09
162.9703979	0.21
163.654892	0.20
164.9850769	0.09
169.1101532	0.14
171.0523987	0.12
173.0940247	0.11
175.2558289	0.09
179.1048431	0.13
181.1276245	0.14
183.1222076	0.12
184.1901398	0.04
193.3226929	0.03
195.2058868	0.21
197.1403809	0.06
198.1289825	0.14
201.1175232	0.09
202.8058777	0.04
207.1643982	0.54
209.0652161	0.19
211.1742249	1.40
212.8632812	0.45
215.2740479	0.25
218.307373	0.06
219.2158203	0.21
221.0073547	0.22
225.1890259	0.14
226.274353	0.22
227.3572083	0.47
229.1568604	0.10
230.0142822	0.13
238.8045044	0.10
240.1300049	0.03
241.1719055	0.24
243.9532166	0.13
247.2403564	0.77
252.2230225	0.98
253.3814697	0.77
254.9351807	0.13
256.2993774	0.50
261.0657959	0.09
262.1329346	0.21
264.5837097	1.59
265.3694763	2.86
267.1040039	0.07
269.2298279	0.43
270.4223328	1.39
273.1676636	0.20
274.2593994	0.09
276.007019	0.10
277.0852661	0.10
282.2799072	48.76
282.9290466	1.01
283.5336914	0.28
285.9911499	0.13
287.0670776	0.53
290.3964844	0.03
291.836731	0.03
300.2891235	100.00
301.1571045	0.99
308.974762	0.18
310.4039001	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1344
Annotation	Spicatolide G
Peak:m/z	Relative Intensity
125.2036743	0.08
133.2457581	0.08
137.9837952	0.26
163.0613861	0.33
164.0705261	24.19
178.9911194	100.00
179.6052399	0.14
201.4279785	0.07
202.8442688	0.05
209.0763245	0.32
211.1340332	0.16
214.1751556	0.08
234.9573669	0.39
239.3680420	0.07
240.8323059	0.05
251.1782837	0.05
257.2235413	0.08
263.9986877	0.10
269.3097839	0.07
283.3623352	0.12
287.4062500	0.16
293.1373901	0.90
309.1315613	0.12
311.2380676	0.10
312.3836670	0.14
315.0674438	0.09
318.9950256	0.10
320.9480286	0.11
323.2053833	0.85
325.9909668	0.09
337.1118164	1.30
338.8907166	0.31
341.2603455	0.38
345.1253662	0.15
347.3064270	0.92
352.9458313	0.15
355.1845703	0.05
363.0140686	0.11
365.1668396	0.56
366.1165771	0.17
369.2244568	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
97.2175064	0.25
98.9281921	0.35
100.9729462	8.56
106.6848297	1.40
112.8907471	14.78
115.1128998	0.19
117.0600281	0.26
118.9476242	18.94
125.0469360	1.73
130.9531860	8.55
142.9678650	18.29
148.4006958	0.11
149.0093994	3.01
159.1609192	0.14
160.9730225	25.43
176.9464111	0.22
178.9264221	100.00
180.9052124	0.45
220.4817810	0.76
221.1283264	0.10
250.8042603	0.26
281.1303406	1.36
323.3452454	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
79.11105347	0.74
80.9874115	3.20
82.74469757	2.36
84.69216919	0.60
89.06463623	0.39
90.93554688	0.20
94.99123383	3.99
96.98277283	3.84
98.91944885	1.05
106.9860382	2.47
108.9581909	1.86
111.1112976	1.27
112.921051	1.95
116.904129	0.22
118.0447845	0.49
119.0483856	0.84
121.0509949	2.94
123.0688477	6.48
124.9460297	3.53
128.9624786	4.06
130.223114	0.31
133.0351562	4.23
134.9584503	4.21
135.7481079	0.31
137.0737457	1.88
138.9946747	0.68
141.0716705	1.25
142.8516083	0.29
145.037262	2.10
147.1060638	3.02
149.1468201	0.61
150.9112396	52.95
151.9290771	4.76
153.0366669	0.70
154.1495514	0.25
155.0396881	6.48
157.0775909	1.41
158.8875275	1.45
161.1662903	2.62
163.1704559	1.63
164.0438385	1.73
165.0753021	1.95
166.1814575	1.05
167.0324097	2.14
169.1201324	5.59
171.1781464	2.07
172.0600891	0.26
175.1777039	3.04
177.1369019	6.11
179.0078888	2.03
182.0593414	2.50
182.9833374	5.19
185.2108917	0.89
189.174469	1.85
190.3750305	0.31
192.8100433	1.12
195.1526184	4.26
197.0968781	7.43
198.9500122	1.94
200.0653687	1.81
207.133255	7.79
208.0745087	0.24
209.0274353	1.04
211.179184	10.51
211.9993744	0.33
216.1377716	0.61
217.1244049	19.52
221.1938019	0.70
224.2421112	3.37
225.1143341	10.29
231.4217529	1.17
234.5272217	3.99
235.2038422	44.73
236.0520477	1.11
238.1187897	12.10
239.2195435	1.90
251.0267944	1.06
253.1066437	100.00
254.1565399	13.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0875
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
101.0198288	0.27
109.1429901	0.04
113.1384964	0.65
117.0780334	0.09
118.7838287	0.52
123.0231628	0.11
125.0960388	0.14
130.9986420	0.31
134.9369049	3.39
139.1633301	0.08
143.0533600	0.75
159.0609436	0.22
160.9894714	3.04
178.9759521	100.00
193.1655121	0.35
197.2162170	0.09
203.0264893	0.66
210.2296753	0.05
221.2747498	0.07
226.2556152	0.16
232.9650574	0.78
240.3361511	0.10
240.9756470	0.06
249.3627930	0.04
251.1195068	3.06
253.2027588	0.10
257.1185303	0.09
266.1871643	0.11
268.8381348	0.07
277.2164917	0.07
279.3969116	0.11
281.1157227	1.08
293.2901611	0.24
295.1654968	1.23
297.0805969	0.23
298.3864136	0.07
303.1953430	0.17
305.0142822	0.20
311.3211365	0.07
313.1458435	0.39
323.0924988	0.51
323.7578125	0.26
324.6388550	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2246
Annotation	Lactulose
Peak:m/z	Relative Intensity
238.0997925	0.06
243.0785675	0.06
341.2121582	100.00
385.3522339	0.10
400.3354492	0.10
401.1661987	0.08
458.9190674	0.05
491.0434570	0.07
503.0435791	0.13
536.1145630	0.04
567.3068237	0.08
597.0416870	0.07
665.2472534	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
93.01246643	0.09
96.90193939	0.57
98.88449097	0.08
100.9459534	0.19
117.0801849	0.37
131.1564941	0.15
148.9898071	0.36
155.2245941	0.12
163.0511627	0.20
165.3098602	0.10
167.0864105	0.19
174.0171661	0.07
179.1372833	0.48
180.2845001	0.39
181.3381348	0.09
183.3499603	0.14
187.2617645	0.09
188.8848419	0.15
191.8000946	0.23
192.8294678	0.23
207.0177765	4.58
208.1534271	2.79
209.2805176	0.95
215.3035431	0.36
220.8908539	0.10
222.116684	1.66
223.0561676	4.07
224.1462097	0.09
231.1704254	0.16
233.1811371	0.88
235.9914398	0.11
251.0807953	100.00
252.115921	18.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9366
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8850174	0.98
130.9765930	2.25
147.0509033	0.71
158.9949951	8.82
174.9140930	100.00
204.3753052	0.03
214.8785706	0.30
217.2089844	0.02
232.9827271	0.42
243.2305908	0.25
244.9061279	27.99
261.0365601	0.40
271.0703735	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
115.0183258	1.18
127.0370789	0.14
155.1806946	0.26
169.1855469	0.62
170.9977722	1.13
173.179306	0.89
177.1257324	0.68
185.239624	1.30
187.1312714	0.17
191.22612	0.42
199.1476746	0.53
201.2380829	1.26
209.5112	0.21
213.1065674	0.46
215.1459351	1.36
217.321167	0.88
221.3774719	0.75
226.9432068	0.64
229.3234253	1.30
231.1620483	2.08
241.1853333	0.93
242.9074707	2.12
245.1871643	0.42
253.2132263	0.53
255.2086792	1.45
257.2001953	0.93
259.0346375	0.82
263.2186584	0.75
269.3244324	2.75
271.2677002	1.71
273.3957214	0.94
283.0241699	0.29
285.3973389	3.72
287.3114929	1.59
295.1446228	0.26
297.2996826	1.59
299.3519897	2.78
301.3710327	0.21
311.1187744	4.65
311.7766113	0.15
313.1584473	1.80
315.3979492	0.44
321.349884	3.64
323.2739258	10.74
325.5696106	0.78
337.4480286	0.94
339.2477722	100.00
339.9193115	1.63
341.281189	12.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.1188
Annotation	4-Hydroxy-5-(phenyl)-valeric acid-O-glucuronide
Peak:m/z	Relative Intensity
108.0072021	0.33
108.9799957	0.46
135.9345398	0.51
159.1329956	0.11
160.9626770	0.19
165.0232849	100.00
171.1974792	0.09
173.1008911	0.09
177.1428223	0.14
189.0077515	0.11
191.0938110	0.18
192.7990570	0.22
195.2614441	0.07
207.1217957	0.57
211.3271637	0.44
232.8887634	0.15
241.0086975	0.14
245.1052551	0.03
257.1682434	0.21
267.2387085	0.12
279.2657471	1.37
283.0943298	0.08
287.3350525	0.13
289.2651367	0.06
295.1435242	0.17
309.2510986	2.23
315.4551086	0.33
323.0723267	10.50
323.7092590	0.12
324.7225952	0.08
325.3325195	0.28
327.2119446	1.84
332.3758545	0.26
333.2559814	0.19
337.5548096	0.30
339.8011169	0.05
341.2132874	0.19
349.8260803	0.28
351.0952148	1.64
354.2832031	0.53
355.2465210	0.11
360.4478455	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.69
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7293396	0.58
296.7678833	11.62
364.9769287	0.11
376.4744873	0.07
380.5834351	34.90
381.2604980	0.18
464.4777222	56.60
465.1824951	0.37
546.6505737	0.39
547.9614868	8.86
548.5971680	100.00
622.0789795	0.03
630.4216919	0.19
631.7937622	10.21
632.4270630	67.74
633.0933228	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.2061
Annotation	Lysergic acid diethylamide
Peak:m/z	Relative Intensity
105.9246979	0.02
109.1316528	0.04
119.8674774	0.03
120.9475098	0.09
129.0440216	0.01
130.1023254	0.02
135.2866821	0.02
147.0413971	0.01
149.0581665	0.22
156.1366577	0.01
166.2091827	0.03
167.1665649	0.10
167.9070282	0.02
177.9813385	0.01
180.2099915	0.06
182.3428345	0.01
184.1528320	0.59
195.2940369	0.09
196.4365387	0.01
198.2769165	0.02
212.0604553	3.37
213.2290955	0.02
214.0816040	0.03
221.6050110	0.01
224.1529846	0.04
236.9265442	0.02
240.0758972	0.19
243.3249512	0.04
244.9346313	0.02
251.8580933	0.07
253.1908569	0.02
261.2029114	0.08
265.2684326	0.06
268.1264038	100.00
269.2227783	0.70
271.1263123	0.05
275.4948730	0.01
278.3336792	0.18
279.1916504	0.13
280.4093933	0.03
281.3854980	0.03
282.9285278	0.34
283.5979919	0.02
285.7407837	0.03
288.1719055	0.04
289.0146484	0.05
294.4583130	0.06
295.8543701	0.21
296.6611938	0.07
300.8694763	0.21
303.5285034	0.05
305.1913147	0.12
306.0634766	0.22
308.3334656	0.17
309.4760742	0.30
310.3359375	0.01
313.9812012	0.01
314.9554443	0.01
316.0092163	0.26
319.1751099	0.09
323.7969055	0.06
325.0328369	0.04
327.1490479	0.02
330.3805542	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8271484	8.72
212.8492737	6.99
219.0679932	0.04
260.6886902	0.05
268.2412109	0.06
271.3872681	0.11
296.7480469	100.00
321.1455078	0.29
337.3144836	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1256
Annotation	b-D-Glucuronopyranosyl-(1->3)-a-D-galacturonopyranosyl-(1->2)-L-rhamnose
Peak:m/z	Relative Intensity
154.9852295	0.06
160.9470673	0.08
171.1413879	0.32
172.2664795	0.31
173.0800476	2.45
179.0585022	1.67
190.9769592	0.22
192.9691162	0.06
211.0084229	0.08
218.8537140	0.09
229.4208374	0.03
233.0286407	0.62
247.4158630	0.10
251.1933899	0.03
263.0472412	0.01
281.0327454	0.10
303.1776123	0.07
304.8225098	0.07
309.2115479	0.06
321.0477905	0.03
322.3414307	0.02
323.2314453	0.25
334.6289673	0.12
335.3103638	0.16
341.1427612	100.00
341.7607422	0.16
343.4143066	0.03
353.1405640	0.55
365.1664429	0.15
397.2829590	0.08
398.1560669	0.06
399.3247681	0.04
425.2470703	0.14
428.0001831	0.09
441.0990601	0.02
453.4836426	0.03
455.2277832	0.12
471.2004395	0.02
478.9810791	0.03
496.8150024	0.58
497.4509888	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
268.4663696	0.04
269.3120728	0.04
270.2020264	0.03
298.2431030	0.09
302.8986816	0.92
331.0631714	0.01
354.2423706	0.01
377.1481934	0.01
380.3054810	0.07
382.8967285	0.08
383.9597168	0.02
384.7267456	0.05
386.7326050	11.24
387.3474121	0.07
444.2317505	0.13
466.5389404	0.01
468.2754517	0.17
470.6443481	100.00
471.2658081	0.49
490.9586792	0.01
518.6047974	0.06
535.8875732	0.03
536.9839478	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.69
Annotation	Unknow
Peak:m/z	Relative Intensity
212.4455872	0.31
213.0588074	0.29
296.6821899	8.58
297.3438110	0.04
380.0280762	2.04
380.7128296	31.12
460.7103882	0.02
462.2853394	0.22
464.5195923	45.28
465.2537231	0.10
470.9832153	0.15
496.5786743	0.04
508.7846069	0.44
526.8175049	0.26
545.9373169	0.58
546.6559448	0.40
548.4580688	100.00
549.1726074	0.17
550.6661987	4.16
554.7233276	0.54
555.4475708	0.06
572.7509155	0.40
580.5604248	0.60
586.7688599	0.17
606.3622437	0.15
610.5451050	0.22
626.7745972	0.13
629.8751831	0.76
630.5755615	0.11
631.6909790	4.87
632.4013062	69.84
633.1248169	0.36
652.5529175	0.09
656.5021362	0.65
669.9362793	0.16
670.7129517	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0902
Annotation	Glutathione
Peak:m/z	Relative Intensity
89.1006088	0.02
115.9147568	1.12
118.0868988	0.02
128.9612122	0.02
130.0003967	0.30
143.9384460	2.25
144.9464417	0.03
145.9538879	0.05
149.8829651	0.02
150.8875732	0.09
160.8791809	0.09
161.9123993	26.30
164.9440155	0.05
178.9557190	100.00
191.0501709	0.02
194.1176453	0.02
204.7620544	0.11
205.7839355	0.05
211.9205627	0.19
215.1343994	0.67
218.0543213	0.02
219.1809387	0.05
233.0085449	17.08
240.9660645	0.02
244.0674438	0.14
245.0895996	0.91
262.1231689	0.04
264.1047363	0.04
272.1263123	1.12
285.4743347	0.07
290.1209717	6.34
291.1661987	1.25
299.0095825	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	319.15
Annotation	Unknow
Peak:m/z	Relative Intensity
90.9937897	0.03
97.1621628	0.08
103.0660706	0.04
105.1075592	0.02
109.8196487	0.03
111.0538864	0.11
116.7789536	0.16
126.9171448	0.25
129.0566101	0.08
131.2387390	0.13
139.1408386	0.16
140.8623962	0.34
145.2381897	0.10
146.8944244	0.09
151.0458374	0.12
154.8960876	0.61
158.9387207	0.03
170.8926239	0.13
172.5001831	0.03
173.1302185	0.65
178.9703064	0.76
187.1751404	0.12
188.1604156	0.14
193.1035156	0.08
197.1022644	0.12
198.8823242	0.09
200.2339630	0.14
201.1075745	0.12
203.0709686	0.03
205.3550110	0.03
206.9729004	0.18
213.4584351	0.07
216.9741821	0.05
219.1695251	0.22
221.1853943	0.04
225.1767883	0.07
227.9548340	0.08
228.8640137	0.15
231.1621399	0.15
233.2842102	0.82
234.2591248	0.77
236.1571960	0.04
238.1419983	0.20
255.0816345	0.05
257.0854492	0.27
258.3692627	0.23
259.1709900	1.82
260.9117432	0.09
265.2496338	0.13
269.5229797	0.12
273.0173645	0.49
275.2409058	0.52
277.1525269	100.00
278.1262817	0.64
279.1420288	0.06
284.1014404	79.89
285.2762756	0.76
291.0794067	0.27
300.1531982	0.26
301.1958313	22.23
302.1165466	16.34
303.0616455	0.38
304.2310486	0.06
310.4254761	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.34
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
165.7741852	0.98
172.9709778	0.09
183.9656525	100.00
189.9870300	0.07
223.1574707	0.25
239.8393860	0.25
258.2341614	0.15
259.2624512	0.12
263.1604614	0.25
267.1919556	0.37
270.3067017	0.12
272.3004761	0.48
280.3640747	0.09
290.1867371	0.17
293.2124023	0.05
307.3991089	0.54
313.2598877	0.08
318.1589355	0.17
329.2138672	0.08
374.3059082	0.06
420.4052734	0.28
423.1041260	0.20
433.1484985	0.19
447.5629883	0.26
458.3583984	0.12
461.3853149	0.33
463.7329102	0.75
471.1838989	0.08
480.4042358	0.22
502.3702393	49.22
503.3910522	1.59
504.1354370	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.09299469	1.78
82.93369293	0.66
84.71607971	0.40
88.89334106	0.12
91.10520935	0.20
94.03792572	0.17
94.95704651	1.95
96.822052	1.56
98.95681763	0.22
102.8760834	2.08
103.657959	0.76
105.9377747	0.86
107.017395	0.54
109.2688599	0.71
111.1615601	0.90
113.2488861	0.63
114.9902039	0.28
119.0413208	1.15
120.9686279	0.28
123.2748718	1.54
124.9850922	0.36
127.1200867	0.53
127.9340057	0.29
128.9931183	6.63
129.759903	1.22
131.0319061	1.19
132.9940948	2.66
135.0182343	0.96
136.8253326	1.33
138.96521	0.66
141.0070038	2.51
142.8813019	1.41
145.1122437	0.31
147.0765686	0.52
149.1865845	0.94
150.9529877	68.82
151.9880829	4.26
153.0040588	1.60
155.0085907	0.31
160.9088898	2.10
163.0435486	0.63
163.998291	0.25
165.2660065	0.16
166.0558472	0.40
167.0748138	0.92
168.8364105	2.41
170.161911	0.84
171.0598602	0.68
175.2006378	1.87
176.2403412	0.30
177.1968689	1.07
178.3490906	0.69
179.0780029	3.63
179.9685822	1.46
181.1580505	1.71
182.0065918	0.17
182.9820099	0.79
185.225296	0.56
189.223465	2.25
193.2813873	0.46
195.2419891	0.80
197.1244202	3.65
199.4185181	0.28
203.9210968	0.45
207.18013	0.56
208.1370392	0.23
209.2725677	2.46
211.3298798	2.37
212.2507782	0.45
217.0602264	7.57
222.0314789	1.40
224.1096191	0.88
225.0763397	9.07
226.2301483	0.46
232.2909546	0.17
235.1606293	30.39
236.3175659	0.50
238.0089264	5.05
239.1064911	4.47
243.9095459	4.22
253.0877686	100.00
254.1997223	21.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1239
Annotation	Samaderolactone A
Peak:m/z	Relative Intensity
122.1066742	0.16
123.0502167	0.56
131.0399628	0.05
136.1360321	0.50
136.9803925	0.19
138.9484711	0.10
143.2407379	0.08
150.1309204	0.77
151.0440979	4.25
165.2668152	0.36
167.1620483	0.06
178.9352722	0.26
181.0619354	7.61
183.1761169	0.05
193.0765228	1.46
194.4869690	1.74
195.1618958	3.80
197.2751160	0.28
207.2897644	0.09
209.1594238	0.49
233.1747437	0.22
235.1208496	0.10
242.0589294	0.08
252.6873169	0.11
257.2114563	0.07
261.0576782	0.11
267.0479431	0.12
273.3479614	0.19
275.2428589	0.09
287.0886230	0.14
298.9203491	0.11
303.2349243	0.24
311.3221436	0.21
317.4474182	0.10
318.8967285	0.12
329.1546936	0.09
331.4302063	0.38
333.1593628	0.11
337.2496338	0.23
341.1387634	0.16
343.1802673	100.00
345.0531616	1.90
347.2457886	0.76
355.2667236	0.15
356.3262634	0.08
359.2759399	0.07
360.8721619	0.32
361.4963684	0.17
363.4837036	0.08
364.0925598	0.14
373.2296143	2.34
376.5189514	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	242
Annotation	Unknow
Peak:m/z	Relative Intensity
84.3271484	0.08
127.0946198	0.12
141.0204010	0.13
164.1949921	0.15
166.6423492	0.33
182.8702850	13.39
183.9193573	0.28
186.2222137	0.24
195.9072723	9.95
197.7760162	1.20
199.0403900	0.50
199.9752045	3.41
200.8780670	100.00
204.1036530	0.62
205.0910645	0.24
205.7679443	0.11
206.5740356	0.48
212.6791382	0.41
213.9597626	2.15
216.3278961	0.37
218.7310333	11.56
219.8089905	0.27
223.9226837	84.26
225.0004730	0.67
227.6747437	1.77
231.8418732	0.21
233.0765533	0.32
241.8321991	8.19
242.9829865	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8482819	0.50
174.9058685	0.33
198.8779297	0.02
215.0548096	0.12
228.9682770	0.05
244.8890076	0.06
272.9539795	6.71
289.0130310	10.79
387.0271606	0.60
388.1899414	0.13
400.1462402	0.07
401.0036621	0.09
402.8839111	100.00
403.5194092	0.25
442.1318970	0.03
443.0975342	0.26
444.9458008	0.05
461.7728882	0.03
470.8098145	0.10
472.8493652	0.02
488.9866333	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	770.1736
Annotation	Unknow
Peak:m/z	Relative Intensity
231.0849609	1.41
233.1999817	0.41
247.1557465	0.04
255.4637756	0.04
261.1473999	0.12
265.1123962	0.82
283.8759155	0.07
302.1488342	0.13
306.1769409	0.13
308.2721558	0.69
310.3118591	0.27
313.0562744	0.11
317.0557556	0.20
325.1520081	0.06
328.1911316	0.06
334.1126709	0.78
346.0611267	0.33
350.5283508	0.11
351.9840088	0.18
362.1170044	0.65
364.1830139	0.15
368.2330933	0.90
381.2141113	0.12
386.1046753	0.28
391.9157715	0.61
409.0131226	0.24
410.9280396	0.56
413.5731201	0.18
426.3749390	0.14
427.1229858	0.04
428.1531372	0.19
437.0767212	1.20
443.1023560	0.49
444.9751587	0.38
447.3191528	0.12
463.2889404	0.20
467.1936646	0.93
469.1271362	0.21
477.0566406	0.17
479.3545532	0.09
494.4004517	0.29
495.4206543	0.09
497.2142944	0.30
503.1188354	0.56
512.1958618	1.78
514.0877075	0.24
519.9020386	0.21
520.5260010	0.28
521.4434814	0.39
522.0653076	0.25
528.2031860	0.21
532.2294312	0.08
538.2904663	3.11
540.1525879	0.07
548.0275269	1.79
549.1810913	0.05
554.2668457	3.13
566.2310181	35.12
572.0982666	1.91
578.3616943	0.06
589.2947998	0.14
595.1732178	0.15
598.0248413	0.06
623.2581787	2.52
631.6234131	0.07
632.4026489	0.37
641.2010498	100.00
641.8479614	0.32
649.3358154	0.54
650.6261597	0.09
661.3217163	0.25
677.3436890	1.76
689.0495605	0.05
695.1445312	13.47
707.3299561	0.28
725.1182861	0.49
734.3598022	0.32
736.2188110	0.14
752.3016357	7.52
753.2786255	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0660400	0.03
229.0696716	0.12
273.0233459	7.36
275.2078857	0.16
289.2301025	0.12
368.8052368	0.03
385.1077881	0.08
386.9667969	16.57
402.9714355	0.07
442.9474487	0.08
452.8416748	0.03
453.4754028	0.06
456.6301880	0.06
459.0057983	0.08
460.9596558	0.05
468.9122925	0.16
481.3812256	0.09
499.0313110	0.09
500.9750366	100.00
524.8768921	0.15
526.9695435	0.04
528.9235229	0.05
530.1889038	0.02
541.0351562	0.19
553.2295532	0.09
567.2174683	0.04
568.9772339	0.71
570.8496094	0.42
583.1140747	0.11
586.6618042	0.19
614.9978638	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	772.1891
Annotation	Unknow
Peak:m/z	Relative Intensity
216.0049133	0.42
216.9561920	0.16
220.9431763	0.02
223.0810699	0.12
227.2215729	0.03
233.0634155	5.18
242.9801483	0.05
243.8951874	0.02
245.0028839	0.08
249.9846802	0.12
250.9981537	0.39
257.0881653	0.23
261.9214478	0.06
267.0338135	0.15
271.0703430	0.11
271.8773804	0.17
273.0463257	0.20
273.7060852	0.05
274.3262024	0.03
276.0109558	0.07
281.1045532	0.03
284.2027893	0.62
285.2124634	0.03
290.2540894	0.21
291.1217041	0.25
295.8952026	0.03
298.3107605	0.03
299.3491516	0.03
301.0704956	0.44
308.0557251	9.91
318.0850220	2.28
319.2685547	0.67
324.0650635	0.07
326.1177673	0.60
336.1625977	12.33
342.0714722	0.03
344.1005249	1.17
350.1586914	0.09
353.1851196	0.29
354.3352356	0.23
356.2705078	0.20
357.9879761	0.06
360.2387695	0.07
362.1585083	0.66
366.9741211	0.41
367.8764038	0.11
380.1148071	0.36
384.1973877	0.60
385.3388062	0.05
386.2711182	0.06
387.2612305	0.26
387.9593506	0.03
393.0249023	0.29
395.3482056	0.61
400.0919189	0.11
401.1739502	0.34
402.2138062	1.89
404.7133789	0.12
411.1351318	11.08
411.7618408	0.05
413.2080688	2.01
419.3104248	0.58
420.3137817	0.09
421.2809448	0.19
425.4728394	0.05
429.1887207	0.55
430.3745117	0.08
431.4541016	0.07
435.0769653	0.16
437.1965332	0.34
439.1511230	1.03
446.0720825	0.10
447.1122437	5.51
448.1296997	0.11
452.1295776	0.12
454.8541870	0.05
463.2903442	0.04
465.2230835	20.13
471.0797119	0.06
473.1926880	0.10
475.0474243	0.17
477.1864624	0.24
478.0774536	0.06
482.3079224	0.05
483.1265869	0.51
488.1799927	0.05
493.4273071	0.02
495.3753662	0.03
505.1342773	0.73
506.1117554	0.13
516.1221924	1.38
517.5108643	0.04
522.2678833	2.14
523.0087280	0.21
524.0812378	0.09
530.1763916	0.11
531.1622314	0.12
532.1087036	0.11
533.3425903	0.32
534.4083252	0.29
540.2342529	26.19
542.1561890	0.12
548.0527954	0.11
550.1876221	6.28
551.1277466	0.18
558.1370850	1.47
562.3035278	0.05
568.2378540	20.64
573.3550415	0.17
574.4048462	0.10
576.2678833	3.24
577.3467407	0.02
588.2442627	0.03
589.2286987	0.05
591.3259888	0.56
594.2340698	2.18
597.2903442	0.08
598.2202759	0.03
607.2479248	0.74
609.2530518	0.10
625.1170044	5.45
625.7567749	0.02
627.1167603	0.21
634.1909790	1.18
635.3916626	0.07
641.1381226	0.05
643.1792603	100.00
643.8526001	0.39
645.1564331	0.62
651.1234741	0.18
652.4099731	0.10
655.0852051	0.13
661.2301025	1.28
669.2467651	0.18
679.2413940	9.03
680.1552124	0.36
691.3087769	0.17
697.2189331	25.35
702.3383789	0.07
718.2788696	0.11
720.3707275	0.29
722.2487183	0.08
726.1209106	0.12
736.3261719	1.22
737.2361450	0.16
738.1566772	0.04
754.2203979	16.67
755.3063354	0.51
END