#DEFINITION	Reference Metabolome for Prunus persica
#IDENTTFIER	RefMeta-Prunus persica.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Prunus persica
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Prunus persica was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.2470322	0.05
111.0173187	0.10
116.7744217	0.02
127.0740662	0.18
127.861618	0.04
131.1106873	0.01
134.0561981	0.08
135.07901	0.98
135.9884949	0.34
137.1399078	0.10
144.8165894	0.01
152.9384766	0.03
154.8700409	0.04
161.1284943	0.34
162.1847839	0.04
171.2429352	0.03
173.0737915	2.61
174.0921021	0.54
175.0751038	0.02
179.1097717	5.54
180.0408936	1.11
191.033844	100.00
192.041626	26.04
217.4360657	0.03
281.0236206	0.01
284.1015625	0.02
309.1255188	0.05
310.3150635	0.01
335.3674927	0.09
335.9877319	0.02
359.2640991	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.15
Annotation	Unknow
Peak:m/z	Relative Intensity
123.9665756	6.10
126.9774628	0.13
135.1342468	0.16
148.7874146	0.22
168.3481903	0.18
179.0031433	0.31
185.7789307	0.08
229.0158997	0.22
232.1203918	0.98
243.2627563	0.14
250.1284180	3.43
258.1446533	0.25
268.0262146	100.00
268.6534729	0.51
273.1848450	0.08
274.6214294	0.20
284.0196838	0.06
286.1670837	1.15
288.4963379	0.25
290.4281006	0.13
293.1427612	0.20
314.3922424	0.33
356.3165894	0.07
361.2203064	0.06
366.3865662	0.12
374.1791382	0.17
376.4087219	0.10
402.1747742	2.17
409.0259094	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
385.4685059	4.54
892.6212158	10.26
939.5337524	16.29
944.6958008	21.16
967.4075317	100.00
968.0811157	24.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1481
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9408112	1.71
164.9340515	1.19
178.8702087	0.22
183.8893738	0.32
187.0812073	0.96
201.0967712	1.52
223.0547485	1.41
229.1020203	4.19
230.8865356	1.80
233.1286011	0.70
243.0625305	2.25
247.0541992	24.83
247.6819153	0.44
253.2394409	1.69
256.9536438	0.98
259.1989746	10.58
270.9483643	13.56
273.2006836	1.97
275.1185608	12.11
282.7087402	1.17
285.2722168	0.70
287.0954590	8.12
288.2031860	0.47
289.1216736	20.83
290.1328125	1.09
291.1914673	59.53
295.2094116	1.96
299.1262817	1.36
301.0094604	31.30
303.1737671	3.72
313.4780884	0.30
325.2083740	1.67
334.2810059	1.10
391.9827881	0.33
393.4282837	2.17
396.8428955	1.28
409.2512817	70.78
411.2609863	17.07
421.2665405	3.84
423.3149414	0.22
425.5945435	1.52
427.1263428	100.00
427.7511597	0.23
435.2989502	3.90
439.0337524	3.56
451.0349121	0.33
453.0906372	4.88
509.3547363	1.61
522.1058350	2.98
533.4836426	0.96
535.0405884	0.35
541.1103516	1.67
543.0831299	0.90
551.8775635	3.61
558.9712524	1.15
561.1444702	8.81
588.6515503	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.13
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.9543304	1.59
164.0351868	0.16
164.8170776	0.16
175.0439911	1.54
179.1104126	0.07
187.2416382	1.02
188.2644653	0.30
196.9646301	0.35
201.1185608	0.27
202.0198975	0.26
203.0900726	0.56
205.1474304	2.56
206.9599915	0.15
212.0487671	0.23
216.5513000	0.27
217.2182159	0.06
225.2223816	0.11
227.4480286	0.26
228.0703735	0.17
229.0508118	0.08
230.1902008	0.32
231.0841980	0.10
232.3835602	0.19
235.1840515	0.19
242.9773560	1.98
244.1093140	0.93
245.1073151	12.15
246.0743103	0.85
247.1457825	0.52
255.0663452	0.51
257.1541748	0.09
259.1344910	0.16
261.1791382	2.47
262.2407227	0.50
269.1484070	1.39
271.3179016	0.83
273.0152588	4.38
277.3822021	0.13
280.9617920	0.58
283.6801147	0.06
285.1807556	0.83
286.0040283	0.28
287.1612549	21.16
289.1179810	51.95
290.1804199	1.64
290.9927063	0.31
295.4033508	0.45
297.1120605	0.46
297.9356689	0.11
299.1372070	7.25
301.2299805	0.14
303.4494019	0.06
321.4447021	0.53
322.8575439	0.17
325.1359863	0.34
327.3071289	0.63
328.9878540	2.02
330.2295532	0.26
331.2258301	1.09
332.1227417	0.13
333.2738647	0.70
337.1446533	0.41
339.0999146	1.15
340.5057983	0.10
341.1776123	0.42
349.3800659	0.19
353.0886230	0.29
356.1250610	0.49
357.3467407	0.09
359.2951660	0.11
361.2544556	0.40
363.3338013	0.59
367.2368774	0.66
371.2714844	0.12
376.2543335	0.21
379.3358154	0.42
380.2390137	0.15
381.3360596	2.53
382.3867188	0.32
386.9401245	0.13
391.4605713	0.33
393.5757446	0.36
395.3475952	0.21
396.2492676	0.84
397.4871826	0.40
405.2269287	0.68
406.6333008	17.00
407.2503052	100.00
408.1340942	3.68
409.3021240	1.28
410.2045288	0.48
411.3576660	0.21
413.1259155	7.66
414.2946777	0.74
415.4161377	7.82
416.1621704	0.96
423.2394409	1.61
424.4326782	15.80
425.2706299	98.59
426.3636475	1.43
428.3427734	0.26
431.2496948	0.37
433.3040771	1.12
435.2975464	0.13
436.2047729	0.75
437.0205688	1.21
437.6893311	0.55
438.3862305	0.25
441.2228394	0.12
449.1704102	8.39
450.4993286	3.95
451.2391968	40.31
452.2583008	3.43
453.3394165	1.36
454.3015747	0.38
455.1828003	0.36
457.5383911	0.25
458.7616577	0.15
465.3451538	0.08
467.2646484	1.55
468.3129883	0.22
469.1600952	0.67
471.2674561	0.16
478.3999023	0.55
481.3989258	0.26
482.4221191	4.14
483.2208252	0.22
491.4019165	39.48
492.3238525	2.10
494.2692261	0.84
495.2130127	0.06
500.3087158	41.70
501.2648315	3.09
504.0401001	0.76
504.8834839	0.86
513.3215332	0.74
514.2612305	0.88
515.2227783	2.45
521.2150269	0.35
523.2013550	0.24
525.4671631	0.66
527.3673706	0.77
528.4079590	0.11
530.3746948	0.15
531.2748413	1.74
532.2840576	0.58
533.2510376	2.13
539.0207520	0.12
540.3723145	0.16
541.3663330	0.87
543.3889771	0.60
545.2252197	1.11
548.9467163	0.40
554.8145752	0.22
557.3048706	1.42
559.2352905	11.09
560.4807739	1.69
561.5830078	0.97
567.1561890	0.20
577.1149292	0.07
587.2345581	1.25
589.1311646	0.52
595.5308228	0.23
617.4538574	0.24
619.3751831	0.29
620.1784668	1.65
633.3867188	0.21
650.8700562	0.62
651.4773560	0.30
661.4741211	0.36
671.0330200	0.33
675.1491089	0.32
677.4898071	0.19
678.4205933	0.07
683.3458862	0.70
687.2855835	0.43
688.1412964	0.21
693.0687866	1.52
694.4008179	0.68
695.2708130	4.22
696.2405396	1.24
697.2836914	1.59
698.0690308	0.09
701.1574097	3.29
702.2627563	1.94
703.1367798	0.38
706.1908569	0.07
711.8865356	0.86
712.7992554	0.08
713.4466553	0.67
714.3016968	0.20
715.1057739	0.71
720.3010864	0.64
721.2683105	0.37
722.3348999	0.26
735.4226685	0.42
736.5589600	0.15
737.2753296	1.12
739.4987183	5.42
740.4104004	2.86
741.3328247	0.16
743.0797729	0.14
786.2565918	0.31
804.1944580	0.07
813.2739868	1.17
820.2477417	0.06
821.3975830	0.99
831.1992798	0.90
832.1430664	0.26
839.4515991	0.21
841.5316772	0.24
845.4592285	0.31
847.6932983	0.41
849.1781616	0.09
857.2040405	6.60
858.2624512	1.52
859.1165161	0.08
861.2454224	0.25
863.1586304	15.96
864.3114624	8.94
865.2677612	13.83
866.2637329	8.63
867.1494141	2.69
875.2843628	1.40
876.2748413	0.35
877.1296997	0.18
878.0990601	0.20
890.0852051	0.15
906.3164062	0.38
907.4226685	2.42
908.4125977	0.58
909.4284058	0.34
983.3945923	0.51
984.1818848	0.12
987.3895874	0.23
1001.2907100	1.13
1002.3115840	1.42
1003.2387080	1.17
1010.2155760	0.95
1027.1887210	12.70
1028.3378910	4.72
1029.4826660	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9393
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9183350	2.35
183.0519562	0.03
199.1292877	0.11
217.1569214	0.19
229.0230103	0.42
257.0493469	0.07
270.9883423	0.08
272.9531860	100.00
313.9680786	0.04
341.1156616	0.40
359.1683960	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1355
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0360718	0.25
163.0728149	0.23
167.0028992	0.05
175.0973053	0.24
177.0633240	0.15
179.2167358	0.03
187.1186829	0.24
191.1261902	0.37
199.1385803	0.09
202.9651947	1.44
205.0291443	0.94
209.1549988	0.05
212.1644592	0.15
213.2926483	0.10
214.9453583	0.25
216.0502930	0.07
219.2646790	0.04
225.2359924	0.32
227.3113251	0.10
229.3283997	0.06
231.0194397	0.09
243.1303406	0.29
244.1044006	0.51
245.0672302	5.44
246.1547699	0.31
247.4249878	0.08
255.1259460	0.36
257.2473145	0.08
261.1512451	0.83
262.2662659	0.05
264.1174011	0.05
269.1342773	0.98
271.2865601	0.52
273.1641846	2.97
281.1763306	0.37
283.2152100	0.42
285.2123413	0.71
287.1362000	6.87
288.0092468	0.37
289.1563721	28.37
290.1547241	0.66
290.9993286	0.07
299.1786499	6.23
301.2952271	0.18
307.4694214	0.04
311.1013794	0.05
321.0687256	0.23
327.4215088	0.20
329.1885376	0.47
330.0126953	0.13
331.2778320	0.56
338.0432129	0.14
339.2070923	0.51
341.3297729	0.71
341.9805298	0.05
347.3361816	0.13
348.4083252	0.32
351.7758789	0.16
353.4702148	0.15
357.3058472	0.49
361.3163452	0.20
365.1741333	0.24
368.3286743	0.16
375.4598999	0.73
376.0697021	0.02
379.2157593	0.15
381.0506592	1.89
383.4989624	0.12
384.4293213	0.06
386.3941040	0.05
389.1864624	0.25
393.5962524	0.12
395.4062500	0.54
396.1336670	0.17
396.9888306	0.15
399.3810425	0.09
401.0792236	0.08
405.0116577	0.10
407.2290649	100.00
408.3792114	0.36
409.1513672	0.36
411.3221436	0.56
413.0914917	1.95
414.0843506	0.09
415.4851685	2.24
417.7904053	0.07
421.2957764	0.19
423.2767944	0.13
425.1505737	91.65
426.2329102	0.31
427.0595093	0.04
428.4334717	0.39
433.4285278	0.54
435.0493774	0.16
436.4017944	0.04
437.2346191	0.69
449.2565308	2.25
451.1323853	24.79
452.2020874	0.44
453.1774292	0.18
454.2978516	0.12
457.7175293	0.19
461.4168091	0.14
466.6679688	0.38
467.3109741	0.38
471.2540894	0.13
474.9514160	0.39
480.9016113	0.23
482.3594971	2.05
483.2736816	0.30
487.4049683	0.05
489.7324829	0.13
491.3510132	8.15
492.2639160	0.48
493.0355225	0.13
500.4088135	7.07
501.0631714	0.50
504.5852051	0.03
513.4629517	0.80
515.3218994	0.60
517.4945679	0.12
521.2132568	0.27
525.4815063	0.06
527.2682495	0.32
531.1694946	0.06
532.1968994	0.36
533.1754761	0.81
534.0720215	0.10
540.2489624	0.69
540.9989624	0.22
547.4920654	0.12
550.5299683	0.06
553.4426880	0.09
555.1209106	0.67
556.1168823	0.05
557.0801392	0.09
559.2131958	10.09
560.4013062	0.22
569.2347412	0.24
575.9673462	0.04
577.4779663	0.21
586.2648926	0.08
588.4351807	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.2
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
242.9789124	0.34
245.0289154	0.05
281.297821	0.12
283.2700195	0.26
287.2423096	1.16
289.1488953	0.69
292.8960571	0.04
295.2577515	0.04
299.1816406	0.28
313.2200623	0.09
328.2001648	0.09
329.2018127	0.31
387.4180908	0.09
395.2651978	0.47
398.0866699	0.10
403.2611084	0.31
405.3118896	0.24
407.3209839	1.64
408.3204956	0.43
409.4980469	0.07
410.1747437	0.12
411.0960693	0.69
413.2194824	0.29
413.9697266	0.05
422.894165	0.18
425.1610107	0.38
434.0157471	0.16
434.9110718	0.37
448.3898926	0.04
449.2380981	0.89
450.345459	0.25
451.3699951	1.06
452.2415161	0.22
459.3137207	0.06
465.3374634	0.08
466.8389893	0.12
494.2383423	0.25
499.1806641	0.04
513.4129028	0.32
525.4111938	0.04
542.2053833	0.08
543.3378906	0.12
557.0726318	0.15
559.2658081	0.56
562.8491211	0.20
567.3922729	0.43
568.1906738	0.26
570.3171387	0.15
570.9953003	0.07
573.1338501	0.25
574.0718384	0.09
575.298584	2.48
576.2863159	0.98
577.2493896	0.31
578.3513184	0.11
585.9558105	0.39
590.0571899	0.03
595.7014771	0.08
598.229187	0.11
611.5039673	0.13
617.0952759	0.41
618.461853	0.10
619.3931885	0.12
620.328186	0.23
625.2928467	0.11
627.1828003	0.12
631.5597534	0.25
634.0362549	0.10
635.7610474	0.46
640.9336548	0.05
644.512146	0.28
656.2495117	0.09
673.0352173	0.04
693.2073975	0.30
694.6951294	1.71
695.4265747	0.02
696.274231	0.04
701.3060303	0.74
702.65802	0.86
703.4842529	1.16
710.3972168	0.33
711.1116333	0.29
712.1638794	0.83
713.1235352	0.12
716.861084	0.26
719.605896	1.16
720.5098267	0.38
722.5021973	0.06
724.2393188	0.21
725.6166992	1.79
728.460083	0.23
733.5488892	0.31
735.3392334	0.24
737.2161255	0.35
738.4439697	1.15
739.4981079	0.60
740.2362671	0.03
757.0669556	0.14
768.2653198	0.12
770.4950562	0.14
774.2988281	0.26
779.2512207	1.01
779.9683228	0.93
785.1986694	0.05
788.5280762	2.68
789.1690674	0.02
801.4689331	1.13
802.3027954	0.57
809.3773193	0.06
826.2070312	0.13
828.7683716	0.18
831.5355835	0.51
838.322998	0.11
845.1212769	0.07
846.3286743	0.05
847.2808228	0.28
848.3347778	0.22
865.1990356	100.00
866.0258179	1.36
874.1074829	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1225
Annotation	Marein
Peak:m/z	Relative Intensity
126.8288269	0.07
130.9862976	0.05
134.9415131	3.07
137.0855713	0.28
138.9582367	5.38
145.04776	0.04
146.8871765	0.30
147.9084473	0.02
149.0233917	0.16
150.9981842	4.67
159.02211	0.10
161.278656	0.11
162.1773834	0.24
162.9181519	2.00
164.9417419	0.41
166.9548645	0.12
169.0890503	0.03
173.4715881	0.02
178.9501953	0.61
181.171875	0.26
184.1222076	0.09
185.8974915	0.02
186.8015442	0.05
188.9417114	0.17
193.0601196	0.26
201.0726929	0.16
205.0563049	0.36
207.0758362	0.09
210.9037476	0.09
213.003418	0.17
216.9889221	0.21
221.3847351	0.09
225.0909729	0.12
229.024231	0.07
235.0440063	0.25
237.0828094	0.03
241.0075073	0.16
243.2420044	0.20
245.1807556	0.04
247.0652466	0.31
249.3753052	0.08
253.0477905	0.28
255.1158447	0.19
259.1809387	0.87
261.0744629	9.40
265.0390015	0.27
271.1030273	3.10
273.1521301	16.35
277.1536865	0.47
283.1064453	0.85
285.266571	0.14
287.1349487	17.77
288.2086792	41.20
289.0716858	100.00
291.2019958	0.05
294.9343872	1.21
296.0032349	0.05
301.0658569	2.70
302.0412292	0.09
302.9259644	0.11
305.0613708	0.02
307.292511	0.11
308.9054565	0.10
311.2101135	0.07
313.199707	4.27
316.8967896	0.12
318.2453003	0.03
319.0604858	0.09
321.0534058	0.16
323.0290833	0.60
325.2800293	0.62
327.2159119	0.05
329.1841736	1.23
331.1651611	1.87
337.3658447	0.14
338.8481445	0.06
340.9988098	0.25
347.1023254	0.05
348.0713501	0.12
349.1795044	0.09
351.2758179	0.11
355.173584	3.16
361.0762329	0.33
367.1208496	0.13
369.114563	0.43
375.2073669	0.07
378.5432129	0.07
379.2137146	0.70
385.1143494	0.03
387.2127075	0.27
389.3127136	0.05
397.2048645	1.20
403.0558777	0.07
406.3562927	0.07
407.2411804	0.05
415.0863037	4.11
416.0777283	0.06
418.7345276	0.03
421.0912781	0.06
423.3786011	0.04
431.2971497	0.07
432.5630798	0.31
433.2958069	3.79
439.2418823	0.09
441.9217224	0.12
450.0361633	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
67.0810089	0.04
69.0252991	0.12
74.0403366	0.07
79.0625534	0.03
79.9806442	0.11
80.9748383	0.18
83.0006409	0.28
84.9870148	0.02
93.0455780	0.05
93.8163910	0.04
95.9307251	0.25
96.7041473	0.05
97.9627686	0.12
99.0011291	0.02
104.8758850	0.03
106.8223572	0.08
108.1394501	0.10
109.1107788	0.04
109.7433319	0.07
110.9421387	0.02
112.1720581	0.12
113.8003845	0.03
122.0743561	0.06
122.8983917	0.02
126.0589447	0.10
128.1347198	0.03
135.9766998	0.29
140.0745087	0.11
141.0085602	0.04
141.8813629	0.07
144.0378265	0.19
145.9470978	0.13
150.9889984	0.06
151.8878174	0.16
154.0399628	0.23
154.9241943	0.09
156.8155670	0.21
158.8202667	100.00
159.8123322	0.03
163.9741821	0.20
164.9710846	0.04
171.1844940	0.05
171.9615631	0.25
175.6604004	0.04
176.7651520	0.70
179.0262604	0.28
180.9885254	0.29
182.0525055	1.18
191.0734558	0.19
199.7484436	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	197.08
Annotation	1,2-Dihydroxymint lactone
Peak:m/z	Relative Intensity
75.0732117	0.04
95.9286194	0.55
99.9252625	0.03
107.1246185	0.18
109.0630951	0.37
110.9515686	0.34
113.1056976	0.12
124.9151001	0.27
127.0815735	0.02
135.1729584	0.21
136.9983978	0.28
149.1819153	0.04
150.9433441	0.42
152.9701538	100.00
154.9994812	0.16
161.0132599	0.07
169.0578766	0.18
177.0887299	0.04
179.0645905	2.65
179.8467255	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8857422	4.99
116.0851059	2.28
116.8856506	3.47
131.0088196	0.24
131.9538879	0.10
133.1266479	0.09
158.9381104	100.00
159.9445496	50.90
160.8890686	65.66
199.1076050	0.42
199.9348755	1.19
200.9716797	3.26
218.2413025	1.08
219.0441589	1.55
229.2165222	2.40
230.0063171	23.79
230.9325562	31.94
246.0851440	0.33
247.0579834	0.75
256.5499268	0.17
257.4257507	0.08
275.3302612	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2836
Annotation	Halisphingosine A
Peak:m/z	Relative Intensity
90.99891663	0.07
94.91015625	1.97
96.25094604	0.20
97.00010681	0.48
101.9821243	0.53
102.7870483	0.04
104.9801025	0.27
106.8699722	0.65
108.945488	2.73
109.9799118	0.06
111.0217514	0.90
112.0689545	0.10
113.9667053	0.16
114.9392853	0.09
117.1500854	0.06
119.0142822	2.02
121.0075836	1.27
122.984642	2.05
125.0937729	0.38
125.9102936	0.04
126.8847733	0.17
128.187912	0.03
129.3722076	0.09
132.0370789	0.12
133.0297394	1.67
135.016037	1.79
136.8692627	1.31
138.2371826	0.12
139.0866394	0.26
141.1286316	0.06
143.224762	0.03
145.5779724	0.10
146.9256897	0.69
149.021637	0.83
151.0057373	1.28
154.0427246	0.19
155.1022339	0.15
156.1531219	0.08
156.9526672	0.05
159.8101807	0.12
161.0614929	0.89
163.053009	0.88
164.9717712	0.38
166.8214111	0.08
170.3759766	0.17
171.0352783	0.05
172.871582	0.04
175.1581116	0.61
179.922287	0.09
181.3713531	0.19
182.3200684	0.08
182.9664917	0.04
183.9825897	0.03
189.1664581	0.15
195.1401978	0.10
196.3357849	0.13
198.4379883	0.20
200.9157562	0.42
201.9079132	0.09
204.0475159	0.11
206.9904785	0.67
209.0990906	0.34
213.9232178	0.13
216.0475769	0.11
217.123291	0.40
219.2120056	0.78
221.2106323	1.70
223.4049683	0.14
224.7966309	0.18
225.8991394	0.57
230.0204468	0.05
231.0650635	0.05
232.7078857	0.90
233.3138123	2.36
233.9274902	0.11
235.0879822	0.31
235.8206482	0.19
236.4437866	0.22
237.2837219	1.13
237.9768677	0.15
239.150177	1.83
241.2107239	0.06
242.2596741	2.38
245.2886963	2.23
249.3546753	0.38
250.3089905	2.93
251.2993774	3.16
252.2197571	0.26
253.2999878	0.35
254.2634583	0.47
255.3961792	0.04
256.1503906	0.20
257.3209229	0.04
262.3468018	6.75
263.3138123	4.01
267.184082	0.76
268.3592834	2.61
270.225769	0.29
271.199585	0.37
273.9725952	0.31
274.9324951	0.20
280.2709351	75.18
281.1881104	1.00
282.2780762	0.11
285.3226013	0.17
286.473114	0.12
288.3095398	0.18
292.7458496	0.20
298.2752075	100.00
299.2414246	1.52
306.7593994	0.44
316.9788818	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.1204834	0.03
152.6926575	0.05
161.2465515	0.10
165.7732544	0.14
180.1120453	0.05
196.0202942	2.48
197.0340271	0.38
201.3132629	0.03
214.0823364	1.81
227.0202942	0.04
233.3436737	0.75
234.3592224	0.11
243.1160889	0.06
259.3180542	0.31
260.0647888	0.14
261.2872620	0.06
269.3782349	0.04
275.4775391	0.38
277.2449036	100.00
278.2838745	15.28
286.4922485	0.02
289.4155884	0.09
296.0953674	0.03
301.1779785	0.04
305.1087341	0.04
313.2723999	0.06
331.2249756	0.02
341.3840332	0.09
342.9942627	0.03
357.1073914	0.04
359.1931763	0.02
369.2512817	0.24
385.3614502	0.04
391.2624817	0.17
401.0689392	0.11
411.9061584	0.03
413.2569275	0.55
414.3782654	0.16
415.1286621	0.08
416.2281799	0.08
428.5781555	0.06
429.3154602	0.30
431.2378845	0.14
433.5483704	0.05
436.1923218	0.03
439.6048889	0.03
446.7618103	0.21
457.3343506	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	2'-Methoxyflavone
Peak:m/z	Relative Intensity
76.87253571	0.30
94.87200165	0.63
102.9161987	4.13
104.8960266	2.56
106.9680328	0.79
122.9517212	5.17
125.0145416	1.08
126.9083862	1.06
128.9693756	20.13
151.0166473	100.00
151.9589996	5.93
154.0393066	2.25
157.1499176	0.80
165.8226776	1.87
167.0344391	2.59
168.9650421	5.78
171.121933	0.96
174.7097626	0.87
175.9683838	0.44
178.064743	0.50
179.1012421	4.73
180.1027374	0.75
182.1607666	1.36
183.2127686	1.07
185.0808716	2.37
186.1363373	0.25
193.1571655	1.32
197.0019531	6.14
205.0063934	0.28
208.9962921	0.55
210.1539612	2.76
211.1711884	3.04
217.4947662	0.82
225.0336151	7.87
226.1317902	1.48
235.001709	3.64
236.3572388	0.80
238.0474701	14.82
239.0083466	2.79
251.175705	0.39
253.090744	39.90
254.3086548	2.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	462.1592
Annotation	4-(2-Nitroethyl)phenyl primeveroside
Peak:m/z	Relative Intensity
126.8972473	0.05
137.9811554	7.41
144.8270569	0.67
147.9056702	0.06
156.6275024	0.12
158.1413574	0.06
162.1685486	0.94
162.9790192	0.31
169.0610199	0.23
173.9039307	0.11
179.9558716	1.14
185.0209351	0.17
186.0964661	0.30
187.1024475	0.23
198.0693970	0.23
204.3820496	0.70
216.0537567	0.10
216.9572449	0.13
221.8755798	0.23
222.7494049	0.30
230.2266235	0.11
241.2834778	0.05
246.1773376	0.76
247.1568909	0.42
254.9174194	0.14
264.0375366	12.97
266.0242004	0.20
270.8607178	0.23
282.1587219	2.61
288.9103699	0.75
292.9882507	0.06
296.1686096	0.25
298.7805786	0.24
300.0577087	13.17
301.1625977	0.45
306.5405273	0.09
310.2227173	0.10
314.4109497	0.25
315.1446533	0.08
325.0903320	0.63
329.0507202	0.19
333.4984741	0.10
348.3808289	0.10
351.9106445	0.04
354.3162231	0.04
363.2044067	0.07
365.5702515	0.41
372.3866577	0.22
373.2539368	0.24
381.7207336	0.19
386.3330994	0.09
390.3777771	0.38
397.3103027	0.14
406.4200745	0.15
407.3904419	0.05
408.3424988	0.22
416.1817017	0.37
417.5738831	0.07
420.8291321	0.13
424.4004211	0.06
426.1108093	5.91
426.7555237	0.02
427.7893982	0.10
429.2924194	0.86
436.0118103	0.50
438.3170776	0.24
444.2007141	100.00
445.2102661	0.11
449.6490173	1.16
451.6868591	0.75
452.7362061	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0721
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
108.0527039	0.22
108.8646393	5.60
148.9954529	0.45
153.0222321	100.00
179.4428711	0.64
190.9539185	0.49
194.8283844	0.15
223.1094971	0.87
231.1752625	0.11
234.8754272	0.18
243.0134277	0.71
253.1695557	0.93
269.086731	4.49
271.1899719	0.33
272.1696777	0.19
295.3531494	0.12
297.1447754	1.61
300.0961914	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	736.1353
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9780273	0.01
214.1239014	0.33
215.1290283	0.57
215.9977112	0.07
216.6984100	0.01
226.0795593	0.27
227.0048218	0.06
232.0605927	0.25
232.8724060	0.03
235.0966187	0.02
244.0965118	0.01
244.8178558	0.03
250.1737061	0.02
251.1350708	0.04
254.9729919	0.03
256.1688843	0.23
256.9324951	0.02
259.0593262	0.02
274.0266113	3.30
275.0406189	1.99
276.0410767	0.12
280.0510559	0.02
286.2102051	0.05
292.0205688	0.80
293.2998047	0.14
297.8867188	0.02
304.0752258	0.26
306.9468689	0.06
310.2362671	0.04
316.1876221	0.19
320.4530640	0.01
333.0353088	0.02
334.0117188	0.50
334.9752197	0.74
336.0836182	0.07
346.2772827	0.01
347.1172485	0.03
352.1688232	0.05
354.9291992	0.02
358.1926270	0.08
362.0354614	0.03
364.3270874	0.03
376.1170654	0.30
377.1935425	0.05
394.1058350	3.73
395.0639648	6.66
396.1898193	0.34
397.3184814	0.01
412.1560669	3.12
413.1583252	0.25
427.1757202	0.01
434.9487305	0.04
438.1556396	0.11
440.1883545	0.03
452.3098755	0.09
454.1479492	100.00
455.1452637	12.61
455.7651978	0.07
466.1203613	1.83
467.1819458	0.31
468.3092041	0.12
480.3796997	0.03
482.2720947	0.02
484.1351929	2.48
485.2571411	0.50
496.2834473	0.87
497.1657104	0.05
505.1617432	0.06
506.0270386	0.01
508.2042236	1.12
509.1044922	0.20
514.1199951	2.59
515.2255859	0.41
526.1168823	0.28
527.0775146	0.03
533.5390015	0.09
538.0795288	0.64
539.0834961	0.10
544.3023071	0.03
554.2614136	0.04
556.1974487	23.11
557.2600708	4.24
563.4420166	0.02
565.1469727	0.26
565.9799194	0.42
566.9237061	0.07
574.1825562	34.65
575.2872925	4.39
576.0560913	0.02
586.8294067	0.02
596.9879150	0.02
611.1466064	0.03
618.8475952	0.03
619.6769409	0.11
624.5841675	0.01
628.2171631	0.11
632.9400024	0.01
638.3626099	0.06
644.2921143	0.01
646.3984375	0.14
647.5781250	0.19
652.4259644	0.04
654.9002686	0.01
662.4971924	0.04
677.0869751	0.10
679.1021118	0.07
683.5508423	0.03
685.0026855	0.01
690.9666138	0.03
692.6430054	0.04
697.4762573	0.02
698.5281372	0.05
705.0240479	0.10
705.8448486	0.03
706.4793091	0.11
708.2896729	0.01
712.5944214	0.03
713.5791016	0.11
716.5148926	0.02
718.6686401	0.01
737.2728882	22.60
738.1430054	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1245
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
119.0508957	0.12
120.9806137	8.59
124.9886780	6.86
125.7980576	0.09
130.8600311	7.85
138.9876862	1.52
142.8265381	0.38
148.9329529	12.36
154.7644653	0.24
161.1002655	0.26
167.0237427	0.52
168.9979858	2.69
185.1751099	0.19
191.1042633	7.88
206.1855469	0.32
211.1540985	0.07
215.2404785	0.80
217.0856018	0.66
218.9908142	0.14
220.8585205	0.09
222.9480591	0.21
232.9887695	3.79
252.3518066	0.09
261.1924438	0.32
263.2082825	0.33
275.1301575	0.82
277.1976624	0.07
279.1866150	0.17
288.0516968	0.06
291.3373108	0.09
293.0613098	100.00
293.8467102	0.35
294.9984741	0.37
313.1801147	0.46
319.2398071	0.78
325.2320557	0.16
327.6365967	0.28
340.3540039	0.06
341.2949219	0.70
343.3159790	0.11
353.5718079	0.38
355.1303711	1.99
358.0169983	0.29
368.0918274	0.32
369.1112366	1.09
371.2508240	0.46
373.1448669	1.99
378.8277893	0.17
380.2451477	0.18
386.3687439	0.23
386.9879456	0.51
394.3883362	0.10
395.3450317	0.20
397.0721741	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.18
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9486160	0.25
131.0294342	0.04
138.8604736	0.03
140.8977509	0.06
144.9650574	0.08
148.9323883	0.04
151.0303497	0.05
155.0209961	0.11
156.9462891	0.07
157.9868011	0.15
159.1312866	0.05
160.0157166	0.04
161.0839539	0.12
162.3045807	0.10
173.6964569	0.17
181.2376099	0.10
182.1242676	0.10
188.9489136	0.15
191.2369385	0.32
193.2162476	0.05
196.2448273	0.06
211.2032623	0.10
212.0634460	0.06
217.1746979	0.04
218.1855316	0.23
229.1961670	1.59
230.2347565	3.23
231.2289886	1.09
239.3597717	0.04
240.1777039	0.28
241.2756042	0.06
255.1807556	0.04
257.1849670	0.55
258.2615662	2.57
259.2774658	0.15
261.1419678	1.11
263.1702576	0.05
267.2523804	0.11
272.3855286	0.12
274.9372864	1.23
275.6245728	0.08
276.2608643	2.50
277.1250610	0.25
278.2829590	0.07
282.3456421	0.04
287.2011719	0.05
293.0919189	0.12
298.8475952	0.03
300.3247681	0.16
303.3090210	0.04
310.1520996	0.07
315.1514282	0.07
317.1806641	0.09
318.2552795	0.47
318.9815369	0.04
320.2242432	0.09
325.1760864	0.11
330.3554077	0.15
330.9588013	0.07
335.0783081	0.08
336.4337158	0.04
340.5957642	0.07
343.1829834	0.18
345.1345520	0.08
350.2678528	0.12
351.4656067	0.05
353.0291443	0.18
357.2598877	0.07
358.4266052	0.06
371.4344177	0.08
375.1232605	0.07
376.6424255	0.14
377.7799377	0.27
378.5068359	0.13
384.3347473	0.34
392.2099915	9.62
393.2143250	67.54
394.1664124	0.16
395.2364807	0.05
396.3772278	0.22
400.5359802	0.38
402.2989197	3.55
403.4301453	0.42
405.1015015	0.06
407.7293701	0.11
419.0827637	1.71
420.3348083	100.00
421.3492737	19.79
422.4793091	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.08
Annotation	Novarubin
Peak:m/z	Relative Intensity
111.1255646	0.12
112.0149231	0.29
117.2540436	0.10
122.0668793	0.06
126.9853058	4.99
139.0722046	0.89
143.8713379	0.08
145.1013184	0.66
149.0682068	0.14
150.8551636	0.51
152.958374	0.13
155.0048523	26.14
160.065094	0.31
163.0428772	1.35
165.9165955	0.08
167.0379639	0.46
170.9285126	0.13
181.1037598	1.75
181.9192352	0.10
183.1913757	0.37
186.0022583	0.07
199.2435303	0.50
201.2770691	0.74
203.1475525	0.16
203.8269653	0.29
206.880249	0.08
207.5110474	0.12
209.114502	0.23
216.9351807	1.02
221.1431274	0.08
222.9488831	0.48
223.8780212	0.13
226.2409973	0.36
232.9898071	0.46
235.0786743	0.78
243.0237122	0.13
244.884613	0.13
247.1733093	0.77
248.9999695	0.34
251.4018555	0.38
253.1564636	0.24
256.9859314	0.15
257.9983215	0.15
261.0665894	4.96
263.1763916	0.75
265.1014099	0.60
266.1109619	1.29
271.1996155	21.56
273.116272	0.10
277.1380005	0.49
279.1252747	0.56
287.3782654	0.37
289.0793457	100.00
290.1857605	0.45
292.0802612	0.08
297.8358765	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	596.1519
Annotation	Antibiotic C 2801X 
Peak:m/z	Relative Intensity
178.5684052	0.30
200.9178772	0.89
247.0143433	0.81
274.1362305	0.08
281.1065369	0.55
281.9744873	1.27
288.2130127	0.26
289.1008301	0.18
290.0488281	0.31
291.2155762	1.26
299.1616211	4.33
300.0670166	0.43
303.1916199	5.46
303.9934692	0.27
311.0476074	14.59
312.0932007	7.05
313.1033325	0.63
329.1074829	48.55
330.1275635	7.64
346.0268555	0.40
348.0913086	0.58
365.3937378	0.32
383.1199341	0.99
383.9628906	1.58
417.1087646	0.15
427.1671753	0.11
431.8490601	1.75
440.2134399	1.56
441.1219482	0.78
449.1737061	28.10
450.1981201	7.67
451.2475586	0.42
453.1530762	1.81
458.1677246	100.00
459.2789917	17.11
466.5380249	1.75
467.1519775	11.59
468.1875610	3.90
483.8705444	0.51
503.2748413	2.97
504.2999268	2.41
515.4269409	1.07
521.2407227	11.39
522.2034302	2.22
561.5603638	2.50
569.5584106	0.22
578.2105103	12.29
579.0325317	3.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1663
Annotation	Verbasoside
Peak:m/z	Relative Intensity
130.8840790	0.12
143.0747528	0.13
148.9874878	3.72
161.0000305	0.65
172.8526611	0.01
174.7206116	0.02
179.0585632	0.28
191.1164856	0.64
220.7481842	0.97
231.2426605	0.06
237.2996368	0.01
238.0967865	0.02
239.1280212	0.05
245.2605896	0.15
250.8873596	0.47
253.3404236	0.03
257.0527344	0.01
260.9573364	0.04
262.8298035	0.04
275.1196289	0.10
281.1122131	0.29
282.9884644	0.26
285.3348083	0.01
293.1029663	0.70
298.2467041	0.03
299.2704468	0.05
310.5691223	0.27
311.1886292	1.56
345.3139038	0.02
365.3089905	0.15
367.2289429	0.02
370.4458008	0.02
374.4184265	0.04
398.3760376	0.02
402.1061707	0.04
415.1709595	100.00
415.8784790	0.12
417.4053955	0.07
426.4762878	0.02
433.5069580	0.03
440.1066589	0.04
441.0514526	0.03
441.7101440	0.02
442.4041443	0.08
443.3067017	0.20
445.1666870	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.2144
Annotation	Unknow
Peak:m/z	Relative Intensity
178.7375183	0.14
214.9799500	0.05
221.1051025	0.31
232.8854370	0.03
250.8574524	0.04
280.8984985	0.25
305.4278564	0.05
309.1542358	0.02
323.1773987	0.43
327.2802734	0.21
328.2680054	0.04
341.0521851	0.98
357.4715576	0.15
383.0191650	0.32
398.1652832	0.14
425.0655518	0.02
428.3529053	0.03
441.1286621	0.04
443.1006470	0.52
463.3616943	0.13
464.1273193	0.04
471.2818604	0.07
472.0485229	0.07
472.8103027	0.09
473.5421143	0.07
474.2333984	0.07
483.4736938	0.12
487.7209473	0.04
495.1235352	0.05
499.3242798	0.12
501.9398804	0.16
503.3499146	100.00
504.4946899	0.09
520.3191528	0.05
530.0889282	0.09
536.2382812	0.06
537.1574707	0.04
543.6118774	0.16
550.1472778	0.03
571.9530029	0.07
588.2649536	0.16
616.3329468	0.03
617.2472534	0.36
635.0590210	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.0183
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8377380	0.01
179.1961975	0.01
184.9675903	0.04
187.0292969	0.04
189.0475769	0.18
196.0919189	0.05
197.0278625	0.04
199.1524200	0.08
203.0581207	0.68
204.2126465	0.04
205.0048523	0.01
212.9384155	0.25
214.8919373	0.05
215.9323578	0.06
217.0517273	0.27
229.0581665	0.28
230.8243408	0.33
234.9574890	1.25
240.2743225	0.02
243.3067932	0.01
246.4572449	0.06
257.0441589	1.04
267.0686035	0.01
273.0168152	0.17
274.9295654	3.98
275.5657654	0.03
276.8912354	0.04
284.4168396	0.22
285.1951904	0.05
291.2019653	0.01
292.9315796	0.24
301.0702515	1.18
302.0427856	0.14
303.1606750	0.17
304.4123535	0.05
305.1367798	0.01
309.8597107	0.02
318.9900513	12.48
319.6187744	0.08
326.9433594	0.14
328.9506836	1.14
331.1416931	0.05
344.9616089	1.75
347.0516357	8.84
348.9573975	0.45
354.8179626	0.01
361.2095642	0.05
362.9690857	7.37
364.0243225	0.03
364.9607544	0.07
371.9490662	0.25
373.0305481	5.41
373.7508850	0.04
376.8597717	0.07
379.1869202	0.02
380.2220459	0.07
380.8577576	0.23
391.0056763	100.00
391.6719360	0.09
401.3710632	0.02
408.6222229	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.18
Annotation	Ixerisoside C
Peak:m/z	Relative Intensity
125.0425873	0.55
127.1627197	1.14
138.206604	0.84
143.0464478	0.55
152.9570923	32.13
155.1208649	0.43
156.9090271	0.47
160.6122284	1.62
172.2182007	0.45
175.1425171	2.09
186.037384	1.57
186.9953461	0.22
194.3134308	0.61
199.3447723	0.34
201.1511536	4.23
204.1016083	2.39
207.1013794	1.08
214.0563354	0.51
217.2602386	0.62
219.219635	15.62
225.175354	0.62
227.3342743	0.95
230.115799	0.34
234.9672546	1.62
242.9569702	1.27
244.9990845	1.95
251.1288452	1.75
260.9704895	1.96
263.1248474	100.00
267.9804077	1.15
271.3600769	0.38
272.0756226	0.90
272.9650574	0.67
279.9029541	0.47
287.163208	1.59
290.3241577	0.96
305.1324463	1.93
306.4380798	0.19
309.0386047	0.90
311.9369812	0.27
313.308197	0.62
323.237915	0.38
326.28125	1.13
328.197937	1.52
329.1776123	4.32
331.0381775	1.21
333.4029541	0.37
335.3569336	0.44
338.9985046	1.83
341.1577759	0.49
351.2397461	0.79
353.0712585	0.44
357.1044617	1.63
361.3744812	0.84
362.0378113	2.40
363.5852661	2.72
365.1773682	0.62
378.2486572	0.87
378.999115	5.37
379.6044006	0.16
380.2511597	0.29
381.269989	0.32
383.3497009	0.24
393.196106	1.64
402.953186	0.19
406.0587769	2.43
407.269989	4.04
408.4162903	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	266.98
Annotation	Unknow
Peak:m/z	Relative Intensity
78.8989410	0.25
86.9633484	0.03
95.0063171	0.70
96.9244156	2.92
112.9985809	9.93
114.0325165	1.66
119.8210297	0.02
130.9268036	100.00
220.7907104	0.21
222.8264465	0.06
248.9307861	1.86
250.0315552	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.87
Annotation	Unknow
Peak:m/z	Relative Intensity
256.0694885	0.07
313.3847656	0.05
321.0874023	0.11
335.1293335	0.08
350.8891602	0.18
374.9312744	0.43
387.0433960	0.30
388.8416748	0.48
392.1674194	0.17
400.7087402	0.25
418.9584351	1.39
428.9796753	0.82
445.1209717	0.11
446.8280029	1.59
447.6104736	0.10
454.0314941	0.20
463.5725708	0.33
474.9782104	0.86
480.0380249	0.06
486.4290771	0.07
492.8689575	100.00
493.5036011	0.19
505.6349487	0.11
506.9740601	0.43
508.6573486	0.23
510.5332642	19.07
511.2628174	0.88
516.0928345	0.56
516.7343750	0.09
528.9246216	0.12
533.1962280	5.44
533.8340454	16.89
540.3198242	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.83048248	2.90
96.92298126	1.00
100.9943619	0.21
109.1030273	0.87
110.8634186	0.52
113.0475845	0.95
119.011795	0.66
120.8340454	0.25
122.8560486	1.42
123.959259	0.33
125.0427628	1.28
128.9743042	0.75
133.1309509	1.56
134.9906464	3.41
137.0071106	0.94
139.0063782	2.66
141.025177	0.72
143.1712646	1.36
146.9253693	0.89
149.3765259	0.43
150.6280823	0.22
153.0302734	1.06
154.9853821	2.44
156.9447784	1.49
159.4033966	0.30
165.0377502	1.70
166.0744171	0.33
167.0934753	2.12
169.0462952	1.74
171.1546936	1.39
175.2035828	1.46
176.9993134	0.32
177.7743073	0.78
178.9864044	1.46
180.9780731	1.50
182.9741516	3.17
183.7063446	0.22
184.8979187	0.97
187.0584869	0.49
189.0210114	0.85
191.2405701	2.54
193.0690308	1.12
194.0126953	0.61
195.1633301	4.98
195.9877319	0.26
197.1048584	6.35
199.0143127	1.43
199.9579163	0.84
200.9398193	0.35
202.0190125	0.85
203.4926758	0.28
204.9294128	1.31
207.2259216	1.42
208.1542358	0.51
208.8776855	1.29
211.1045227	6.38
214.9502869	2.09
217.290863	0.99
219.0896912	1.32
223.1341248	2.67
225.1600342	3.97
227.0457764	0.20
229.1315613	2.85
231.1186523	0.18
233.242157	1.74
235.192749	2.50
236.9975586	2.98
237.7262573	0.75
239.1350098	4.19
241.543457	2.36
244.5193481	0.58
249.2504272	0.66
250.0499573	0.59
251.102356	4.11
253.0947266	21.00
253.8255615	0.57
257.1072998	0.51
258.3922729	0.61
264.2772522	0.58
265.3063965	1.33
267.2956543	0.41
269.1985474	3.09
270.1101685	0.11
271.3115234	0.77
275.2665405	33.42
281.1971436	0.73
283.1625977	0.42
288.1743164	0.23
291.2875366	0.24
293.2055664	100.00
294.089447	0.75
297.3057251	0.65
302.3385315	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.182
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1350098	0.10
165.1535797	0.07
191.1338501	0.02
194.9147034	0.03
205.0625610	0.04
212.1089325	0.04
215.1089630	0.04
217.3589630	0.01
227.0085449	0.02
229.0904846	0.01
255.0039368	0.04
283.1280823	0.10
285.0820007	0.04
295.0981445	0.02
301.0877991	0.11
306.8619080	0.04
322.8988647	0.08
325.0390930	0.08
337.2299194	0.03
343.1511841	23.49
343.7577820	0.06
345.1407471	0.03
346.3829651	0.02
351.0686646	0.02
365.4384155	0.11
367.0267334	0.05
371.3276062	0.02
373.1848755	0.02
374.9844055	0.04
377.4850159	0.09
379.3833923	0.02
388.3993225	0.02
403.6100769	0.03
417.1929932	100.00
419.4240417	0.25
420.0957947	0.04
442.1947021	0.19
444.1793823	0.08
445.2685242	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1031
Annotation	Cinchonain Ic
Peak:m/z	Relative Intensity
137.0765076	0.04
161.0474548	0.10
177.0701447	0.35
183.0875854	0.02
189.0471802	0.68
190.0055542	0.01
191.1842499	0.02
192.9831848	0.03
203.1936798	0.02
204.0718842	0.04
205.1709595	0.19
207.8125458	0.01
213.4813080	0.02
216.1940308	0.03
217.0306854	1.51
218.5087280	0.11
219.1970062	0.46
223.0930328	0.01
229.3528290	0.02
231.0203552	0.80
235.4700928	0.05
240.8440857	0.14
245.3593750	0.08
261.1413879	0.01
270.1388245	0.01
271.0622253	0.08
275.3192139	0.08
286.0315857	0.05
287.2716064	0.49
288.0676575	0.06
289.2240295	0.75
297.1420593	0.08
299.2090454	2.48
304.7314453	0.02
313.0129089	0.03
315.0412292	0.10
319.3135681	0.02
321.3959961	0.03
323.1581421	0.29
327.1591797	0.54
328.2047729	0.02
329.1305542	0.08
341.1106567	100.00
342.1393738	0.07
347.2727661	0.09
355.6549377	0.03
369.2643433	0.12
372.9076843	0.15
374.1176453	0.08
382.7937317	0.02
387.2054443	0.03
389.0836792	0.04
391.4852295	0.06
403.3243713	0.09
405.1549072	0.47
406.3422241	0.05
407.0792847	0.09
408.3264771	0.02
409.4967346	0.04
415.4213562	0.13
422.2354126	0.03
430.3028564	0.08
431.3527527	0.07
432.3717041	0.02
433.1929016	0.49
435.8174438	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.1905
Annotation	[3R-(3alpha,3aalpha,4beta,5alpha,6aalpha)]-3-[(beta-D-Gulucopyranosyloxy)methyl]hexsahydro-4-(hydroxymethyl)-5-methyl-2H-cyclopenta[b]furan-2-one
Peak:m/z	Relative Intensity
107.1923523	0.05
108.9815521	2.62
118.9163589	0.36
120.9622421	1.94
124.9878998	0.67
126.6396790	0.03
136.9810028	7.27
145.7904968	0.10
146.9743652	0.23
154.9890442	8.30
163.1653442	0.17
164.9606018	9.40
174.8278351	0.05
179.9652863	0.23
182.9204559	79.66
189.0365601	0.05
191.0567017	0.18
198.8527222	0.08
200.8354492	100.00
201.4451904	0.62
209.1940308	0.05
215.4007568	0.14
217.2715759	0.17
217.9674988	1.52
223.0721436	0.05
228.1029968	0.07
234.9424744	0.21
239.4007263	0.06
247.0756226	0.06
251.0985413	0.11
259.2493896	0.02
263.3135071	0.11
267.2501526	0.04
270.0607910	0.15
273.8853455	0.03
275.7251587	0.24
277.2702942	0.24
283.8480835	0.21
287.2642822	0.04
289.3737183	0.54
298.0854492	0.05
299.0463257	0.03
309.1671143	4.56
313.2299194	0.11
316.4338379	0.07
317.0522461	0.10
318.3309937	0.18
325.2593994	0.18
327.0424194	0.03
333.8627625	0.03
335.3895264	0.04
336.8411255	0.11
337.6862793	0.08
339.3054199	0.26
342.5759888	0.26
344.2806396	0.54
344.9848022	3.45
349.0497742	0.28
350.1806641	0.15
352.6703796	0.09
355.3298645	0.07
356.5803528	0.16
361.0755005	1.64
362.1918640	2.70
362.9289856	5.80
365.2561951	0.03
371.3059692	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	751.1476
Annotation	Unknow
Peak:m/z	Relative Intensity
287.1284180	0.88
313.3345337	0.21
409.1794434	0.04
432.2064209	0.20
435.2332153	1.03
437.7576904	0.37
453.3209229	0.05
463.0733032	0.92
501.5324097	0.09
543.3422241	0.51
571.2139282	9.14
581.4517822	0.27
589.1961060	100.00
589.8528442	0.44
599.2017212	0.07
619.2254639	0.62
630.8655396	0.06
638.8128052	0.22
668.9500122	0.07
671.4505005	0.06
685.9929810	0.26
700.1614380	0.04
732.3520508	0.05
733.5023193	0.06
751.2520752	1.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.19
Annotation	Unknow
Peak:m/z	Relative Intensity
125.2339859	0.13
129.0834961	0.05
135.2362823	0.28
142.9259949	0.54
161.0311432	1.04
163.0756226	0.06
165.0933228	0.26
167.2681732	0.15
175.1130524	0.21
179.3001709	0.18
181.0046082	0.72
182.9877014	0.32
192.2410431	0.30
193.2674866	0.67
199.2217102	0.20
205.3471985	0.13
206.8041229	2.38
207.7650146	0.21
209.0786438	2.94
210.0238037	2.84
211.0970459	100.00
219.1550903	0.14
220.1747437	0.07
228.8325653	0.11
235.0398254	0.31
237.0683289	0.26
238.4809875	0.23
239.2856445	0.16
243.2814941	0.44
253.1195068	1.57
257.4177856	0.40
258.3060303	0.70
259.2689514	0.25
261.4300232	0.11
265.0636292	0.52
268.2709045	0.15
273.4546204	0.32
275.5798035	0.24
279.1614075	0.09
283.1952515	1.50
295.2595520	0.17
300.3979187	0.06
301.2162476	0.80
305.1150818	0.73
306.2277832	0.48
311.3954468	0.30
312.2959900	0.25
313.1149902	0.19
318.2891846	0.11
323.2969055	0.16
324.1889954	0.19
325.0633240	0.16
330.3314819	0.13
333.1828918	0.10
339.4709473	0.07
347.1083374	0.04
355.0063477	0.63
356.2211304	0.09
357.4695740	0.13
370.9556580	0.50
372.0942688	4.77
373.0660400	67.38
373.7583618	0.14
374.4360046	0.13
375.1133118	0.77
381.0540771	0.06
383.2829895	0.21
387.6897278	0.31
390.3977051	0.29
398.1966858	1.32
399.3318787	0.08
400.3313904	0.72
401.3993225	1.99
402.2264709	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
140.0406036	0.18
153.0106201	0.30
173.7508392	0.03
196.1241302	2.86
213.9896240	1.25
226.3185883	0.03
255.2702026	100.00
271.5257874	0.05
340.9619751	0.02
351.3569031	0.02
391.3943176	0.18
393.5850525	0.04
405.6044617	0.06
406.4319458	0.10
407.4408875	0.11
409.4609680	0.03
433.8174438	0.08
434.5069275	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	240.0496
Annotation	Tridentatol A
Peak:m/z	Relative Intensity
70.6180573	0.01
79.7963486	0.03
89.0691528	0.04
105.9698639	0.64
108.5692444	0.03
110.9270020	0.01
116.9729919	0.02
120.0515594	0.01
123.8841553	100.00
133.0243073	0.07
144.0714264	0.02
162.2547913	0.02
163.0325775	0.03
174.0691071	0.04
177.9883728	0.03
181.7025146	0.01
193.3191681	0.02
194.0673218	0.03
195.1064148	0.21
199.0942841	0.06
209.0907745	0.03
212.0694580	0.03
217.0492401	0.01
221.3826141	0.08
221.9990387	0.23
223.2736511	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.106
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
271.1205444	0.03
287.0731201	100.00
287.6768494	0.32
324.4973450	0.03
329.2210388	0.02
386.0571899	0.02
431.2933044	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1346
Annotation	Semperoside
Peak:m/z	Relative Intensity
106.9982605	0.06
111.1995010	0.14
113.1357422	0.29
132.8087616	0.07
135.1734009	0.03
136.8092041	0.06
145.1703186	0.07
149.3158264	0.12
153.0857697	19.66
159.2985840	0.13
160.9866333	0.12
167.0753784	0.12
169.1184692	0.14
177.2080688	0.08
179.0933228	0.14
187.0866547	0.06
193.3074341	0.02
195.0552673	0.26
197.0082703	100.00
207.1437836	0.05
210.8888245	0.06
213.1667480	0.10
225.0647583	0.16
239.0765686	0.81
240.9632568	0.41
243.2606812	0.05
245.1521912	0.10
252.8584595	0.07
255.3294983	0.25
257.1429749	0.09
263.2459412	0.08
268.9294434	0.03
271.4342041	0.04
273.1547546	0.13
279.1332397	0.06
281.3031006	0.04
287.1354980	0.26
289.1157837	0.09
291.2868652	0.10
292.0206909	0.12
295.3159790	0.03
296.2355347	0.03
297.2061462	0.51
299.1705322	0.44
302.1380310	0.07
310.2824402	0.06
311.1161804	0.31
313.1501465	1.62
314.5181274	0.13
315.1907654	0.32
322.3556213	0.09
323.2485657	0.22
325.6353149	0.06
328.0655518	0.17
339.2053223	0.17
341.2486877	0.95
344.3561401	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
153.0923462	0.05
196.2008514	0.21
207.2021027	0.02
210.1173248	0.05
214.0800934	1.18
218.6716003	0.03
222.0871887	0.08
233.1039429	0.11
261.1123047	0.22
277.356842	0.06
279.2233582	100.00
280.1474609	0.03
309.6269226	0.12
382.436615	0.03
408.0757141	0.02
413.506134	0.07
414.188385	0.10
421.4556885	0.10
429.8413391	0.05
431.2114258	0.12
433.3177795	0.04
446.3835754	0.05
454.7314148	0.07
457.2787476	0.09
457.9579468	0.19
458.6545105	0.03
462.250061	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
84.7935791	2.34
108.8366547	10.37
120.8699341	5.58
126.1048431	12.55
133.9448547	6.52
135.0289612	3.51
137.1478119	3.51
139.2314911	10.81
141.1403961	4.13
147.2177582	11.70
149.0496521	5.20
151.1324005	10.71
161.0792999	36.51
162.8742371	15.86
165.193222	12.02
175.1935577	3.44
178.9731293	15.10
181.2473755	5.50
183.0166473	33.88
189.0244904	7.77
191.1925201	2.54
195.1849823	23.94
197.220047	1.53
203.1816559	9.01
205.1912079	35.57
206.6339417	7.22
207.4928436	23.12
209.0560913	35.82
219.0880432	3.61
221.1486053	32.56
223.1649933	19.88
228.0878143	2.97
230.9530182	7.40
233.0425262	91.53
235.220459	5.04
251.0695953	100.00
252.2043915	22.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2497
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.94148254	0.17
100.3526382	0.24
104.9523849	0.93
106.9826813	1.47
108.988884	0.58
110.9334259	0.18
117.1944122	0.09
119.2943726	0.31
121.0696411	2.68
123.11866	0.63
125.0013885	0.25
128.9139252	0.06
130.9087524	0.14
133.166687	0.36
135.0554504	2.80
137.056076	0.64
140.8616028	0.89
142.9069366	2.51
145.0746155	0.57
146.8198853	0.34
149.0824127	1.73
151.2058411	0.42
153.1066284	0.33
154.0444641	0.17
155.0404053	0.76
157.0042114	0.96
158.1212769	0.08
158.9772339	1.12
159.824585	0.19
160.9213257	0.67
163.0085449	0.28
165.1375122	0.77
165.9309692	0.28
167.0321808	0.05
168.0779114	0.07
169.0247498	2.30
171.1024017	0.58
173.0768433	2.12
177.0797577	0.08
179.2457275	0.09
181.0847931	0.06
183.0814514	1.96
185.180603	0.13
187.0904388	3.53
189.1402283	0.16
191.0410309	0.45
192.9732971	0.15
195.1834412	0.12
196.9829712	0.97
200.0493774	0.18
201.1495361	1.07
203.0830688	0.06
205.0046997	1.50
206.953949	0.24
209.1611023	0.63
210.9818115	1.46
213.2827759	0.05
215.1528931	0.18
217.2131042	0.41
221.008606	0.33
223.0376587	0.75
224.9639893	0.07
227.2148743	0.28
228.1583252	0.32
229.1202698	0.71
231.2159119	0.30
233.082489	0.21
235.3867188	0.09
236.8895264	0.10
239.218689	0.46
240.6228027	0.30
241.2902527	0.04
243.1864624	0.10
245.2197876	1.09
247.3079529	5.33
249.3449402	0.15
251.2742615	0.46
253.1901855	0.27
253.8787842	0.10
255.1437073	0.33
257.1869812	0.90
259.1817017	0.77
263.1687317	0.07
265.059082	0.12
267.3435974	0.59
268.3202209	0.08
269.231842	0.16
270.4144897	0.04
271.3520508	0.53
275.0516052	0.23
276.7531128	0.39
279.3734131	0.04
281.3204651	0.35
282.4046936	0.31
283.442749	0.30
287.3914795	0.18
293.0439453	0.07
295.2346802	2.16
296.0585632	0.43
297.5482788	0.46
299.2039795	1.81
305.1448364	3.06
311.0112305	0.50
313.2900391	1.70
323.2377625	100.00
323.8610229	0.75
341.1497498	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.17
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0901489	0.29
173.1457825	0.23
191.0194244	100.00
290.9299316	0.11
341.9656982	0.06
377.2211304	0.25
513.3105469	0.07
514.0872803	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.12
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.9032745	3.31
74.0658035	0.03
86.4578705	0.02
89.9238968	39.41
95.0082855	0.06
97.9408569	0.34
102.9987030	0.02
113.0806885	0.02
115.9755707	4.09
123.0281067	0.13
124.0582123	0.28
124.9176178	0.14
130.9603424	0.09
141.9881744	0.19
146.1000519	0.08
152.1832123	0.05
154.2996368	0.07
156.0346527	0.70
157.2232208	0.05
158.9586182	0.02
160.1394501	0.44
163.1787567	0.03
164.2404480	0.07
166.0233917	1.27
171.9790039	0.09
173.9422302	4.20
174.8605957	0.10
175.8099823	0.10
177.8347168	0.29
178.9976807	0.12
184.0521240	25.33
189.6488037	0.13
190.3012848	0.02
191.9314423	1.38
192.5528564	0.05
195.0875397	0.03
196.9262238	0.09
198.9864960	0.20
202.0587006	100.00
203.1087646	0.25
204.1205444	0.03
218.0958862	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1297
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
123.0402374	0.13
134.8787384	0.02
149.0230103	0.04
151.0444031	0.08
151.8860016	0.04
155.2089691	0.08
165.1404724	0.03
166.9461365	2.90
173.1790771	0.03
179.0861511	0.09
191.0128632	0.04
199.1831055	0.06
206.0724792	0.02
226.2884216	0.05
227.1469879	0.18
233.2100525	0.04
244.3576050	0.02
244.9645996	0.03
247.9999390	0.03
250.9515381	0.02
254.1691589	0.03
263.0238037	0.01
269.3151855	0.07
270.3137207	0.11
271.3520813	0.09
273.1068420	100.00
293.1235352	0.03
293.9903259	0.07
297.1483459	0.65
299.0911560	0.05
315.0415649	0.18
317.3588257	0.08
318.3630981	0.09
321.2459106	0.04
323.4797974	0.08
327.3663330	0.01
328.9410706	0.03
338.2614746	0.02
339.1665039	0.40
341.1556091	0.04
347.2368469	0.02
352.6716614	0.02
367.2442627	0.05
371.2010498	0.03
378.4024963	0.06
381.4949036	0.04
387.5181580	0.02
389.2750549	0.75
391.2927551	0.10
393.4844055	0.03
403.2207947	0.07
407.0816956	0.01
415.4129639	0.17
416.1877747	0.13
417.2735901	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
124.9517822	0.08
125.8652802	0.01
135.1114807	0.01
136.8037109	0.03
144.9475098	0.03
145.9578552	0.01
147.0036926	0.14
149.1313171	0.08
150.9979401	0.09
159.2974091	0.04
160.8544312	0.06
162.0960541	0.02
163.2339172	0.05
168.9356689	0.01
173.1407776	0.10
174.0258331	0.01
175.0363922	0.14
176.1432800	0.05
176.9896240	0.15
178.1300659	0.01
179.1599731	0.04
181.2237854	0.02
187.2808533	0.01
189.1090088	0.09
190.1921082	0.02
191.2098389	0.13
196.1574097	0.02
197.0595703	0.01
198.1812592	0.01
199.2364502	0.15
200.9913788	0.89
202.1562347	0.15
203.2066498	0.03
204.0393066	0.06
205.0702972	0.07
206.1378479	0.03
209.0902252	0.02
211.0429840	0.01
213.1380768	0.28
213.8106232	0.08
214.4241028	0.03
215.1809082	0.05
216.1339111	0.03
217.0847778	0.29
218.1115417	0.06
219.2491150	0.02
221.0970154	0.01
223.0875549	0.05
224.1451263	0.03
225.1029358	0.12
226.9057617	0.11
228.9544678	0.10
229.9926453	0.01
231.1670074	0.36
232.1426086	0.01
233.3391724	0.03
234.3588257	0.03
234.9625244	0.03
237.1886292	0.04
239.0907593	0.11
240.6034241	0.15
241.2297974	1.18
242.2935181	0.23
243.1654053	0.61
244.2033997	0.13
245.1242065	0.08
246.1904297	0.02
247.1568909	0.07
248.1518555	0.01
253.0883484	0.09
254.6338196	0.12
255.3809204	0.19
256.5124817	0.12
257.2803955	0.38
258.1838074	0.11
259.3618164	0.06
260.4801331	0.04
261.1235046	0.03
261.9493103	0.02
263.0682373	0.03
265.1066284	0.01
266.2722473	0.04
267.1647949	0.18
268.6755676	0.25
269.3230591	0.33
270.1326904	0.10
271.2184143	0.63
272.7110291	0.25
273.3623047	0.01
275.2216492	0.08
279.1592407	0.10
280.2453613	0.03
281.2174072	0.43
284.0996094	22.15
285.1257019	100.00
286.0997925	12.88
287.1631470	0.18
290.1779785	0.01
291.0104370	0.06
292.3206177	0.07
293.0579224	0.01
295.1678467	0.69
296.3604736	0.20
297.2136230	1.66
298.2661133	0.64
299.1252441	4.60
300.1729431	0.88
301.1629028	0.07
303.1993408	0.23
304.3674316	0.01
305.2632446	0.02
307.2466125	0.12
309.0612793	1.68
310.1583862	0.18
311.1659241	0.19
312.0777588	0.01
313.1658020	0.13
314.1683960	0.05
315.1561890	0.01
316.3880005	0.01
319.3176270	0.23
321.1390381	2.31
322.2595215	0.53
323.5407715	0.01
324.2255859	0.02
325.1844482	0.07
325.8498230	0.03
327.0740967	3.38
328.2366333	0.42
329.2643433	0.04
333.0533447	0.01
334.2892761	0.03
335.1311646	0.04
335.8132935	0.01
337.2691040	0.14
339.1836853	1.48
340.2599487	0.24
341.2495117	0.01
344.2895203	0.05
345.3678589	0.04
346.3771973	0.02
351.1890259	0.75
352.1522827	0.16
353.1102905	0.01
354.1567078	0.02
357.2153015	0.96
358.1386108	0.29
359.4226074	0.02
361.2701111	0.07
362.2784729	0.04
363.7653198	0.02
367.1274109	0.07
369.1693726	0.55
369.8054504	0.10
373.2756042	0.03
375.1710510	0.18
376.1232300	0.02
377.2497253	0.04
383.1413574	0.07
385.2084961	0.12
386.2749634	0.04
387.1399841	0.31
388.3166504	0.01
393.2822571	0.08
399.2111511	0.03
401.3630676	0.15
403.2323914	0.23
404.3323669	0.08
405.1954956	0.08
411.2583313	0.09
412.0993958	0.01
419.1166687	0.08
420.5492859	0.02
429.2252808	1.38
430.1498413	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1664
Annotation	trans-p-Ferulyl alcohol 4-O-[6-(2-methyl-3-hydroxypropionyl)] glucopyranoside
Peak:m/z	Relative Intensity
143.1175995	0.03
148.9651337	0.33
191.0844727	0.22
197.4634399	0.06
203.2914276	0.05
209.3069458	0.04
211.0104523	0.06
213.9631042	0.05
217.3615417	0.15
220.1609192	0.07
229.4020081	0.08
232.9769592	0.88
235.0969849	0.09
237.2739868	0.16
238.2228851	0.15
241.2057190	0.31
247.0490723	0.04
254.1835022	0.11
255.1810913	0.13
265.3290100	0.08
268.1267090	0.04
274.9316711	0.04
281.2511597	0.03
288.4269714	0.10
293.1210327	34.11
306.1671753	0.03
308.3535156	0.02
311.2272034	0.09
314.3400879	0.04
319.1099548	0.03
323.3479004	0.05
325.3493042	0.09
337.1145020	0.08
341.3089905	0.08
347.7536621	0.25
350.9124451	0.09
354.3002625	0.09
355.3784180	0.07
357.1043091	1.67
363.4990234	0.03
367.3522339	0.14
371.2077942	0.02
377.3522034	0.31
379.0334167	0.06
383.2460022	0.04
384.3807068	0.29
385.3517761	0.09
400.6072083	0.07
405.1419373	0.04
408.5234680	0.05
427.1338806	100.00
427.8392334	0.10
429.4264832	0.04
431.4778442	0.08
436.1355591	0.04
437.1539001	0.08
445.1967163	0.17
454.5192261	0.15
455.2214050	0.85
458.2124939	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	259.1898
Annotation	Diisobutyl adipate
Peak:m/z	Relative Intensity
76.9107208	0.11
83.2146149	0.09
84.8832626	0.06
91.1656494	0.02
95.0768738	0.06
109.3205109	0.03
115.0795593	0.08
116.9307556	0.21
121.0060883	0.12
121.9352875	0.04
126.8448639	0.03
128.9414062	0.05
130.8733673	0.04
140.9198761	0.15
144.9216461	0.15
145.9537048	0.41
150.8890533	0.06
153.1624603	0.08
155.0054932	0.48
157.0296478	0.02
158.8025055	0.03
162.1692657	0.02
162.9894714	0.16
164.2444305	0.06
165.1645966	0.18
167.0278473	0.17
169.0630646	0.21
171.0835419	0.04
172.9032135	0.04
175.1621094	0.13
175.7911072	0.07
177.1107788	0.62
178.9246979	0.06
181.0600433	0.13
182.9081421	0.04
184.8157043	0.19
187.0982361	1.13
193.0755463	0.07
194.2136993	0.04
195.0550079	0.08
197.2381744	0.02
199.1450653	0.23
201.1831360	0.11
203.1088715	0.20
205.1078186	3.35
207.2153931	0.07
211.0574646	0.04
213.0566254	0.45
213.8289490	0.06
217.6022491	0.46
218.3714142	0.10
219.1363373	0.02
223.1380157	21.53
224.1336517	0.02
226.6918488	0.04
229.1014557	0.17
231.0777588	0.11
232.0769501	0.04
238.5422974	0.04
241.0428925	100.00
241.8867798	0.02
245.3367920	0.09
249.7547455	0.14
259.2984619	0.18
260.1899414	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	660.1677
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0694122	1.60
190.0565186	0.16
190.8098755	0.52
192.4434814	0.25
193.7922668	3.39
195.0133820	1.68
196.0613708	0.21
199.1140289	1.38
200.2779236	0.36
201.0368805	0.58
201.9208832	0.04
206.9732361	9.14
208.0866852	5.83
209.0752563	0.82
211.0516663	2.79
212.1136475	0.57
217.9961548	0.38
218.9818573	2.50
219.9826355	0.33
221.1780701	0.13
225.1620941	0.13
231.1318054	0.20
236.0435944	11.98
236.9981842	1.13
238.0756531	0.13
239.0639038	0.24
240.1311951	0.27
244.1166229	0.09
247.1260071	0.24
254.1591492	0.20
256.1460266	0.57
256.9457397	0.83
259.0455322	0.12
263.9726257	100.00
265.0415649	10.73
265.6694336	0.13
266.8096619	0.13
274.1552734	4.46
275.2287598	0.58
276.1636658	0.57
297.0882874	2.86
298.0810547	0.37
301.9701233	0.08
303.0211792	0.14
306.3520508	0.51
307.3025513	0.04
319.2944946	0.19
320.3357544	0.59
321.1809692	5.09
322.1133423	3.77
323.1056519	0.58
327.0425415	0.16
331.1418457	0.27
339.0277710	11.12
339.9216309	1.45
340.5227051	0.15
347.1895142	5.19
348.1873169	1.79
349.2215576	0.15
350.1771851	0.35
365.2316895	4.70
366.3884277	0.41
369.2031860	0.07
370.3317871	0.08
375.1127930	1.35
382.3200073	0.17
383.9333496	0.08
386.5835571	0.12
393.1026611	34.42
394.2395630	5.48
404.9882202	2.96
406.0786743	0.49
410.3054810	0.30
411.2386475	0.46
423.1051025	2.69
424.3430786	0.77
426.5734863	0.18
428.0839844	4.19
429.3003540	1.47
432.3812256	0.11
441.4615479	0.11
450.1481934	1.40
451.2264404	1.43
451.9024658	0.09
468.1972656	20.48
469.1853638	3.49
486.4376831	0.48
494.9401855	0.10
496.1847534	0.43
497.0427856	0.11
513.2974243	6.50
514.1964111	1.52
527.2300415	0.18
531.1501465	42.66
532.1461792	9.18
539.2163086	0.30
557.5086060	0.39
567.1573486	1.47
568.0164185	0.28
576.8228760	0.51
579.4470215	0.24
580.3885498	0.35
585.2907104	44.26
586.3468628	14.91
597.3087769	0.25
598.0711060	0.31
604.2048950	0.22
614.5593872	0.78
624.8566895	0.48
642.1944580	6.96
643.3801270	4.67
644.4183960	1.11
646.2232056	0.12
661.2486572	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1084
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
111.0558167	0.04
114.7868576	0.72
132.8422089	0.01
137.1173859	0.06
155.0011597	8.37
155.6228027	0.01
159.1565247	0.04
161.1715546	0.03
165.0246582	0.07
166.9486694	0.14
179.0760956	0.07
181.0218658	0.05
187.1136322	0.04
199.0054016	100.00
208.5165405	0.12
213.0627747	0.01
215.1069946	0.02
217.0594482	0.02
221.1805725	0.02
229.1243896	0.39
230.8973083	0.02
235.1154480	0.07
241.3234253	0.21
243.0214844	0.07
251.0087280	0.09
252.3217163	0.03
253.2161560	0.15
255.2272339	0.08
257.0075684	0.15
261.1211243	0.07
269.1248474	0.32
270.2767944	0.05
271.1675110	0.28
273.0674133	0.02
279.1274414	0.26
283.2655029	0.06
287.2471924	0.09
295.1125183	0.07
296.5620422	0.24
297.3463745	0.13
298.2122803	0.02
299.2643433	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	576.1271
Annotation	Unknow
Peak:m/z	Relative Intensity
163.2447357	0.29
175.1022491	0.81
178.9531708	0.63
185.1410217	0.34
186.7856293	0.60
188.1191254	0.63
202.2371521	0.24
203.1747284	1.34
205.2261963	1.12
215.3248138	0.64
217.2133179	4.43
220.1100616	0.15
224.9576874	0.29
226.9567566	1.83
228.2089386	0.32
229.1749268	0.18
230.0364075	0.12
231.1157837	1.11
231.9779205	1.07
235.3796082	0.37
243.1344452	3.65
245.0737305	19.15
246.1350861	1.44
247.2241516	1.28
255.1178589	1.94
261.1505432	4.89
262.0291443	2.55
264.3964844	0.35
269.2256470	1.97
271.2349854	0.43
273.0722656	3.32
281.1033936	0.18
285.0532227	0.60
286.2111206	0.33
287.1885986	28.24
288.2190552	2.66
289.1051025	67.33
290.2963257	6.42
291.1957703	0.27
293.2015076	0.39
299.1438599	7.81
301.0841370	0.66
302.4942322	1.36
303.2634888	0.35
305.3442993	0.59
308.0126953	0.38
315.3993530	0.75
318.9187622	0.49
326.0695190	0.53
327.3809814	0.20
328.0020752	0.15
329.1701050	2.14
330.0393066	2.82
331.2821655	4.18
333.0419312	1.12
337.1083374	0.12
339.0078735	0.63
348.0441895	0.80
348.8168335	1.91
353.0659790	0.45
363.0883179	0.80
365.2749634	1.11
367.0382080	2.24
369.3067017	1.18
371.0064697	0.23
379.1595459	0.47
380.4456177	0.35
381.3278198	1.82
382.0021973	0.12
384.7142334	0.99
387.2145386	0.28
389.6210938	0.70
393.5896606	1.55
394.3369141	0.25
395.3374634	3.66
397.7938232	1.20
405.2587280	10.92
406.2286987	13.03
407.2429810	91.47
408.4202271	3.06
409.3037109	1.11
411.5144653	0.48
413.3429565	9.73
414.3317261	3.91
415.3645630	13.30
421.2790527	0.23
423.0836182	6.14
424.4440308	33.56
425.2288818	64.80
426.0923462	2.78
428.0388184	2.21
432.0781250	2.80
433.1417236	3.17
434.2853394	0.22
436.2813721	3.95
437.1256714	0.25
437.7515259	0.80
439.3621216	1.18
449.2922363	12.47
451.1098633	41.48
452.1290894	3.56
453.1644287	2.64
454.1685181	0.69
455.1286011	0.61
467.5007935	0.89
468.4470215	0.25
469.9065552	0.88
473.3739014	0.79
475.4666138	0.68
478.3523560	0.31
482.3206177	4.55
483.0966797	0.09
486.8289795	0.64
488.4311523	0.74
489.4808960	0.23
491.2273560	56.17
491.8924561	27.33
492.8829346	1.36
495.6060181	0.89
497.2759399	0.72
500.3638916	100.00
501.2017212	10.66
501.9816284	0.41
505.1185913	0.13
512.1805420	0.45
513.1423950	3.13
515.0592651	2.56
521.4815674	1.06
525.1729126	2.28
528.1608276	0.39
531.1301880	3.91
532.2825317	4.58
533.2791138	3.45
534.1614380	1.21
540.3906860	1.28
541.2652588	1.40
543.0565796	0.32
545.3425903	0.46
547.5863647	0.41
549.1716309	1.85
554.4216919	1.33
557.5217896	4.05
559.1502075	13.36
560.1952515	1.42
567.3815308	0.87
569.0919800	0.28
576.0862427	0.18
577.1795654	4.07
587.3093872	4.07
588.3568726	0.50
600.5023804	0.15
613.3250122	2.32
614.5097046	0.80
617.2267456	1.72
618.1870117	0.58
619.2158203	2.12
620.1880493	1.37
629.1792603	1.05
640.3020020	0.41
643.3352051	0.27
651.0386353	1.43
652.4306030	0.29
657.8775024	0.51
659.8732300	0.23
677.8124390	0.31
681.4114990	0.46
686.9573364	1.18
687.6130371	0.49
693.3126831	5.33
694.4743042	2.47
695.3572388	6.27
696.3748169	1.87
697.4746704	4.13
701.1718140	7.67
702.2587891	1.63
707.4332886	0.66
709.3947754	0.51
711.0635986	0.71
712.2658691	0.56
713.2949829	2.42
714.1412964	1.34
737.1617432	2.34
738.4057007	2.37
739.2800903	24.68
740.2908325	6.44
741.3830566	0.58
743.1477051	0.42
757.3169556	0.23
788.0509033	0.84
805.3517456	0.38
813.4931030	0.62
821.2944336	3.74
822.0518799	0.81
822.7029419	0.48
823.3889160	0.17
830.4413452	0.20
831.1802368	1.51
832.2852173	0.76
839.3735962	0.99
847.4712524	2.88
849.2407227	1.68
850.3959351	0.16
851.0475464	0.43
857.3788452	14.13
858.3942261	2.36
859.4960327	0.31
863.3179321	24.49
864.1574097	13.00
865.2304077	44.24
866.3236694	32.52
867.2647095	7.58
875.2827759	3.31
876.3691406	2.13
886.3598633	0.69
904.1863403	0.37
907.0783691	1.57
908.1275024	3.73
909.0679321	0.57
983.3023071	1.21
984.5795288	0.54
985.2291870	1.42
985.8952637	0.30
997.6250610	0.22
1001.1841430	0.26
1002.1126100	0.28
1009.5512080	1.03
1010.4513550	0.13
1027.2982180	28.48
1028.4287110	10.29
1029.2778320	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
153.1752167	0.03
166.8964539	0.03
195.9036865	2.47
197.2586517	0.13
214.0583954	1.56
215.1423035	0.05
221.2364655	0.03
237.3018494	0.10
240.2366333	0.02
255.2376404	100.00
256.2263794	16.80
283.3286438	0.12
291.5047607	0.04
310.0161743	0.06
321.1164551	0.03
381.580658	0.05
384.9568787	0.04
391.5682678	0.54
392.3686829	0.03
399.3610535	0.17
404.9716492	0.07
407.3500061	7.27
415.1295471	0.02
421.0500793	0.10
434.9325867	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2612
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
684.2950439	0.03
695.402771	0.06
847.4300537	0.02
983.4127197	0.03
1009.648804	0.06
1110.657471	0.01
1135.290039	0.15
1136.43811	0.10
1153.26709	100.00
1154.281738	27.41
1155.001709	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2497
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
97.00021362	0.16
105.1700821	0.49
107.0132904	1.15
109.0152283	2.43
110.9521942	0.39
116.8369293	0.43
118.9679565	0.03
120.9919357	3.14
123.0303802	2.04
125.1008148	0.62
129.0061035	0.29
130.7906647	0.45
132.9709778	0.78
135.0107117	3.35
137.0670471	0.32
139.130188	0.02
140.9967041	0.20
143.051239	0.42
144.7601166	0.25
147.0161133	4.56
148.3208771	0.14
149.0157623	1.56
150.8869019	0.50
155.1125793	0.10
156.9215851	0.78
159.0766602	0.36
160.9751587	1.87
162.969635	1.43
166.9536285	0.08
169.0459747	0.41
171.1857758	0.41
173.0282898	0.60
174.9428406	2.48
177.2612	0.13
178.1382141	0.09
182.9862823	0.58
185.1789093	0.32
187.0353394	1.24
189.0488892	1.20
191.0256042	0.11
193.0499573	0.04
194.9234009	0.12
197.0309906	0.53
201.1895752	0.24
202.9800568	0.55
205.1040497	0.65
209.125061	0.35
211.0196533	0.25
213.2636414	0.26
215.0480957	0.31
217.1421814	0.85
223.2449341	0.37
225.2603455	0.66
227.1637573	0.60
229.1476746	0.26
231.1427917	0.83
234.4841919	0.31
237.3547058	0.04
241.1401978	0.43
243.1092224	0.06
245.1043396	1.21
247.2554016	4.78
251.3247681	0.03
253.2205811	0.23
255.3094482	0.15
257.1565247	0.45
258.4645996	0.09
259.2563171	0.17
260.9192505	0.30
265.1745911	0.04
267.1402893	0.53
269.2112732	0.17
271.0550537	0.12
272.8250732	0.34
279.2493286	0.03
281.1227417	0.35
285.1744385	0.33
287.1329651	0.13
295.4172668	0.81
298.2230225	0.28
299.2536926	1.01
303.045166	0.26
305.3599854	2.01
310.3252258	0.08
312.3122253	0.06
313.6090393	0.08
323.2456665	100.00
324.4141235	0.18
341.1316223	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2607
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
556.8847046	0.01
599.4859619	0.01
697.2269287	0.02
739.149292	0.10
803.229248	0.12
847.3800049	0.03
863.4472656	0.01
983.0166016	0.02
1009.147949	0.08
1027.069824	0.04
1135.107178	0.40
1135.728638	0.23
1151.5896	0.01
1153.267944	100.00
1154.005737	0.11
1154.637939	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
112.6983261	0.02
143.0241089	0.03
178.8698730	0.20
224.9526978	0.06
281.5044250	0.03
341.1536255	100.00
341.7548523	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8494568	2.09
255.0741272	0.04
290.8233643	18.25
374.1406860	0.21
374.7697144	4.48
376.9664307	0.16
398.6035156	0.06
399.3308716	0.02
418.7407227	0.37
422.7546997	0.15
436.5247192	0.19
447.0166016	0.04
458.5646973	56.40
459.3488770	0.15
460.6776123	2.93
461.6417847	0.07
464.6926880	0.18
466.9699097	0.02
483.0843506	0.13
490.8840942	0.74
496.5620728	0.06
506.0680542	0.07
506.7412109	0.19
519.1392212	0.17
520.6110229	4.24
521.3344727	0.01
539.9749756	0.45
542.5139771	100.00
543.3357544	0.07
561.5452271	0.04
562.7557373	0.45
566.6213989	0.46
578.6431274	0.07
580.7567749	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	576.2452
Annotation	Saframycin Yd 1
Peak:m/z	Relative Intensity
161.0278473	0.08
163.0654602	0.18
166.9504852	0.04
171.1443176	1.54
172.1282349	0.04
173.1332550	0.43
174.9393921	0.28
183.1745605	0.03
185.4658966	0.06
189.2157745	0.90
191.2536163	0.05
199.2149811	0.07
201.2173157	0.63
203.1589355	0.02
204.8610229	0.05
207.1652527	1.64
212.7945709	0.02
217.0362701	0.09
219.1507416	1.04
220.9786835	0.05
237.1887512	10.78
238.2382507	0.66
244.1838226	0.12
245.1923218	0.19
269.2717896	0.05
273.3336182	0.25
279.1914673	0.05
281.1634521	100.00
282.1783447	1.85
285.3066711	0.07
287.1248779	0.21
288.1403809	0.06
289.0906372	1.38
298.9511719	0.20
300.3548584	0.04
328.9841919	0.05
360.1667480	0.05
368.2590332	0.03
377.3602295	0.04
378.4161377	0.07
381.3099976	0.17
395.2241211	0.16
397.2254028	0.50
405.4457397	0.04
407.2580566	5.07
411.3322144	0.02
413.0776978	0.13
414.3154297	0.07
423.4269409	0.18
424.2734375	0.09
425.1447754	3.10
449.4489136	0.07
451.2616577	0.63
452.1789551	0.09
454.1538086	0.17
476.2198486	0.12
481.4822998	0.13
482.4558716	0.27
491.4130249	1.09
500.3964233	0.27
531.5462036	0.05
541.3532104	5.54
542.3518677	1.27
556.5865479	0.04
557.2838745	0.08
558.4376221	7.98
559.5192261	4.29
578.3389282	0.07
587.1084595	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9306335	100.00
134.8858337	0.12
161.1089783	0.08
212.7494812	31.36
254.0888062	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2497
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
96.84587097	0.04
105.111618	0.41
107.0212173	2.61
109.0907364	1.66
110.9275665	0.37
112.9566345	0.08
116.8044815	0.47
120.9302673	6.04
123.0136185	0.94
124.981369	0.78
128.9206848	0.08
131.0290527	0.31
133.0224762	0.52
134.9803009	3.46
137.0916443	1.47
141.1309357	0.37
142.9785767	1.30
144.9653625	0.27
146.8542328	0.94
149.0021973	2.23
151.0745239	0.58
152.5636444	0.20
153.7251892	0.06
155.0568237	0.41
156.8990479	2.29
158.9382477	0.64
160.962738	0.41
163.028595	0.70
165.0620728	1.30
166.0051575	0.21
166.894104	0.25
169.1441193	1.15
171.1296387	0.96
172.9564819	1.94
174.9750671	0.55
177.0489807	1.01
178.0684509	0.12
178.9157257	0.44
181.2990112	0.06
183.0406799	1.42
185.2187805	0.25
187.077301	1.66
191.1655579	0.16
195.2131653	0.19
197.0493774	0.05
199.0232086	0.86
201.2213287	0.90
202.862381	0.53
205.2125702	1.55
206.841095	0.05
209.3327637	0.31
211.0305786	0.79
215.2585449	0.70
217.0232544	1.54
219.1111145	0.29
220.9867554	0.68
223.2121887	0.21
224.1158142	0.09
225.1277771	0.41
227.1125488	0.43
228.0307007	0.08
229.0967712	0.51
231.1532593	0.91
233.0755005	0.19
236.9882507	0.12
239.224762	0.26
245.2105713	4.17
247.2216492	7.97
247.8462219	0.10
249.2374268	0.04
250.8422546	0.10
253.2960205	0.13
255.3862915	0.06
257.1721191	0.50
259.0973206	0.84
261.5142822	0.24
263.2015991	0.12
264.9544067	0.08
267.1516113	0.45
269.1847534	0.38
270.2643738	0.21
271.2236938	0.06
273.2637329	0.09
276.0203857	0.13
277.2043152	0.22
279.2149353	0.05
280.9171143	0.42
281.553894	0.07
282.3264771	0.44
283.1991577	0.31
285.4294434	0.49
287.078064	0.56
292.3110046	0.17
293.2844238	0.17
294.0080872	0.34
295.336853	0.60
297.3509827	0.20
297.9703064	0.31
299.2538452	2.07
305.3156433	2.89
306.2692261	0.11
309.25177	0.04
313.1596069	0.82
314.3916626	0.11
319.3023071	0.40
321.7588501	0.04
323.2393188	100.00
324.242981	0.64
325.0203247	0.33
331.3052979	0.39
332.5505066	0.05
341.146637	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0331
Annotation	Unknow
Peak:m/z	Relative Intensity
78.7697067	8.97
88.7596970	0.32
96.8423157	100.00
97.7565994	0.08
112.9718018	0.13
127.9316406	0.12
132.6488190	0.46
143.1498108	0.05
149.0528870	0.40
178.9701996	0.07
192.6605072	0.60
216.9173889	0.39
221.0125427	0.12
222.0854492	0.13
227.9618835	0.61
229.1850281	0.30
231.2190857	0.36
238.9306641	0.64
241.2426758	0.20
246.0907593	0.21
258.3021240	0.41
259.3075256	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.3188
Annotation	Ixerisoside L
Peak:m/z	Relative Intensity
218.9414368	0.11
233.1516876	0.54
234.0748291	0.07
237.2657471	1.00
238.1208191	0.56
281.1981812	3.59
282.2223206	2.82
283.0133057	0.93
288.1058350	0.08
293.1411743	4.17
294.0775146	3.42
295.2051392	0.42
379.2528687	0.14
408.3580322	0.32
449.4338379	0.08
456.9062500	1.50
458.1776733	2.44
459.2257080	0.36
468.5426025	0.09
519.3575439	0.06
579.3945923	0.04
588.1399536	0.05
591.2173462	0.07
673.2294312	0.07
741.1887207	100.00
742.1044922	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.29
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.0748596	0.19
145.4240875	0.17
149.0716095	0.07
153.1037903	0.11
154.9895020	1.59
160.9230499	0.07
163.1467285	0.15
165.1996460	0.08
166.9722290	0.11
170.8887482	0.04
173.1787415	0.03
174.9055328	0.47
177.0274506	0.21
179.8988342	0.11
180.9572144	0.04
185.2030792	0.14
188.6894836	0.05
191.2515411	0.11
193.1545105	0.10
197.1097717	0.09
198.0731812	0.31
202.9015656	0.34
204.2630920	0.19
205.2510071	0.27
207.1091766	0.22
209.2400055	0.11
212.9855957	0.19
215.9975281	0.62
217.1794128	0.24
219.1530762	0.24
224.9995728	0.08
227.2146912	0.28
230.1561584	0.04
237.0117340	0.08
239.0569153	0.10
241.2970123	0.17
245.2208710	2.90
252.1740112	0.13
253.1817627	0.19
263.1724243	6.64
265.0202637	0.05
269.3332214	0.03
277.3295898	0.16
279.0184021	0.10
283.4126892	0.12
286.7610168	0.06
297.1588440	0.10
301.5562744	0.21
306.3524170	2.09
309.9765015	0.12
313.2883606	0.23
319.2173767	1.16
321.3009033	0.15
324.6521301	0.12
329.2674866	0.13
330.2930298	0.11
332.4156494	0.12
333.3414612	0.13
335.4314575	0.28
337.2939453	92.88
337.9323120	0.39
356.3955078	0.36
357.5565796	0.27
360.2843323	0.05
361.4697266	0.13
364.5806580	0.06
365.3854980	0.08
367.5260010	0.11
368.6213684	0.05
372.2111206	0.16
380.4217834	0.37
385.7078247	0.19
397.3912354	0.36
399.3107605	0.09
401.3884583	0.12
402.3016052	0.03
405.0464172	0.11
409.6492615	0.43
417.2465210	6.51
419.4722900	0.17
422.1158752	0.03
429.3329468	0.30
434.9125671	0.31
440.4389038	0.23
441.1665344	0.38
442.3520813	0.13
443.3021851	0.23
448.3798523	0.12
450.0679016	0.14
460.2268677	100.00
461.3937073	0.21
476.5527039	0.11
477.2095032	0.09
482.9373169	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
98.72122192	0.21
111.1118317	0.64
116.0657578	0.35
118.9391022	0.62
122.9412079	1.45
125.1623306	1.50
127.0342178	0.26
128.8272858	1.00
130.9202728	0.98
139.0210114	1.37
141.1195068	1.23
143.2133789	0.62
144.0318146	0.23
145.1547241	0.43
149.0317993	1.36
151.0813599	0.36
152.0234833	1.06
152.806366	0.49
155.1509705	2.27
157.0049438	1.08
165.2396393	0.20
169.1724091	0.88
174.7379913	0.88
177.1412964	0.69
179.0458374	0.18
184.7752686	1.22
191.2210541	0.19
193.1819458	1.41
195.0736237	3.52
197.0908203	3.29
198.0711975	0.76
199.0574036	0.14
201.1395416	1.06
207.0458984	0.90
209.0455933	0.44
211.1774902	2.12
213.17453	0.74
214.101532	1.54
217.2861633	0.56
221.0816345	0.88
223.3373108	0.99
225.4163513	0.76
227.0555725	0.82
229.2259827	0.59
233.3069153	0.92
235.2003784	0.87
237.2221375	20.82
239.2879944	0.70
240.3367004	0.90
240.9747925	0.25
246.2773132	0.50
247.2247314	1.36
249.2272949	0.59
250.2165222	0.27
251.2435303	1.71
253.1510925	7.47
255.1251221	12.88
257.3225403	0.60
261.8796387	0.20
263.6948853	1.16
265.0374756	0.48
269.22052	0.68
270.0500793	0.32
275.2409363	13.41
276.3718567	0.66
283.3081055	1.74
284.0390015	0.37
287.8042297	0.32
291.3989868	0.53
293.209198	100.00
294.1943054	0.31
297.2562866	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7943268	1.36
230.9726715	1.61
290.8321228	8.36
337.1702881	2.65
338.7689819	1.82
374.7350464	10.13
375.6264648	2.57
380.9328003	2.18
413.2174072	1.30
414.0251465	1.19
418.5984497	7.01
458.5838623	49.75
459.7398682	12.18
482.7247314	0.41
502.3919678	4.59
503.6020508	0.64
506.4429321	1.31
520.8761597	1.88
531.1080933	2.84
542.5665894	100.00
543.3031616	27.46
544.0004272	5.35
544.6693726	52.56
545.6293945	1.14
548.4796753	9.08
567.0208740	1.74
568.1298828	5.54
574.7142944	9.97
580.5604858	2.11
590.0962524	3.39
590.7021484	1.61
604.5979614	50.27
626.6605225	40.42
627.9306030	12.27
646.7438354	11.29
650.6808472	14.56
664.4094849	9.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9074402	3.38
160.0610657	1.04
173.7946167	0.04
198.9987183	0.86
199.8685303	0.54
217.0907135	0.39
228.9980316	0.63
230.1828308	0.33
272.9577332	73.97
274.0497437	23.29
361.1602783	0.08
372.0793457	0.08
385.0403748	0.25
386.9798584	100.00
387.9540100	47.14
412.1408386	0.09
426.9947815	0.19
428.3921814	0.06
456.0022278	0.06
458.2121277	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8747177	0.34
187.1728058	0.01
206.7943115	5.57
212.8112946	0.98
254.9532166	0.18
266.9379883	0.02
285.0502319	0.21
290.7731934	100.00
291.4377136	0.15
297.0846252	0.04
314.9343262	0.17
329.0540771	0.04
357.0558472	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
591.3254395	7.91
967.4332886	100.00
968.1113892	15.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
98.91108704	0.52
119.0873566	0.25
119.8801422	0.33
121.1633759	0.18
135.2268066	0.18
155.3980408	0.37
156.1475525	0.23
169.8690643	7.09
170.8870087	0.38
181.3213196	0.29
183.0059814	100.00
183.9490204	11.74
185.1116791	1.29
197.068634	12.79
198.1228638	5.35
210.2447815	0.15
211.0350342	3.44
212.0574036	1.45
225.0959167	1.69
225.8424377	1.72
227.1228638	0.36
234.402771	0.38
236.9937744	0.17
239.1576843	5.05
239.9822388	1.98
241.1828308	0.82
242.9493713	1.92
247.3477173	5.13
248.0385742	0.71
249.3484497	1.65
251.4005432	0.88
253.1724243	3.96
264.9331665	2.90
267.3148499	3.07
268.0357056	0.14
269.0306396	0.93
282.2196045	1.06
283.2099609	2.19
291.5578918	0.15
293.1709595	5.11
295.1402588	1.62
296.1242065	0.46
311.2955017	23.76
312.4310303	4.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2029
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
158.7718506	0.02
161.3377075	0.03
177.0904846	0.09
205.0448914	0.02
213.0715485	0.02
265.0518799	0.03
295.1370239	0.01
296.3428955	0.01
305.3518677	0.05
311.2246094	0.02
313.4267578	0.17
316.9741211	0.04
321.2949219	0.03
329.2869873	0.37
337.1768188	0.13
341.1314697	0.15
344.2468262	1.68
345.4008179	0.04
355.3633423	0.04
359.2362671	100.00
359.8500977	0.26
375.5053101	0.03
377.0989990	0.01
383.2222900	0.03
399.2348022	0.07
401.2351685	0.06
411.3409424	0.03
424.7809448	0.02
433.4677734	0.04
437.0691528	0.02
445.1420288	0.09
451.2238770	0.04
474.2506714	0.01
475.2116089	0.08
491.4369507	0.29
503.3181152	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1025.236
Annotation	Unknow
Peak:m/z	Relative Intensity
284.2664795	0.11
285.2226868	0.03
287.1467285	0.04
289.0876160	0.31
297.3161621	0.11
298.2012634	0.02
299.1833801	0.03
321.0523987	0.04
327.2889709	0.06
329.2656250	0.24
331.1163635	0.17
339.4008179	0.04
360.9555054	0.02
363.0608826	0.13
365.0405884	0.02
381.0426941	0.15
383.3421021	0.09
387.1315613	0.03
389.4866028	0.07
407.2973022	4.18
409.3128052	0.06
414.3543091	0.02
425.2217712	2.73
437.2968140	0.04
447.1537781	7.65
447.7541809	0.04
449.4237671	0.05
451.1911621	0.59
559.4414062	0.15
571.3446045	0.01
573.1217041	0.03
577.3201904	10.31
585.5305176	0.05
609.5428467	0.04
626.4517822	0.09
710.7145996	0.03
723.4978027	0.03
735.4042969	0.06
737.3076172	0.17
827.1663818	0.11
855.0517578	0.08
1007.3063960	0.03
1024.9475100	100.00
1025.8500980	0.62
1026.5332030	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
125.1985779	0.02
178.7806549	0.30
233.2052612	0.02
315.0929565	0.06
329.2492676	0.01
341.1348572	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	453.0125
Annotation	Primisulfuron
Peak:m/z	Relative Intensity
160.4366150	0.29
172.9277802	0.17
213.1447296	0.02
218.1416931	0.15
218.9709320	0.04
232.0212402	0.04
247.1523438	0.04
250.7114868	0.05
261.0427856	0.12
261.7764282	0.57
263.0910645	0.16
266.8709106	0.05
273.1105957	0.42
288.8960571	0.17
290.2656250	0.65
291.0690002	1.29
308.0966797	0.05
331.2094116	0.03
334.1537781	0.06
342.0760498	0.33
343.1781006	0.21
345.3695068	0.03
353.3784180	0.38
354.2060242	0.91
354.9853210	0.18
362.1645508	1.38
363.0600891	0.23
377.1332397	0.13
380.1134033	0.12
380.8954468	0.16
391.0355225	1.32
392.1607056	0.36
395.3859253	0.09
405.0175781	0.14
407.0621643	100.00
408.1152039	1.27
409.0765076	0.53
417.3183899	0.08
424.6930847	6.96
425.3545837	0.05
434.5680237	0.26
435.4219971	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.1659
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1638336	0.06
122.8809662	0.11
137.1632690	0.89
155.1147461	36.25
156.1542969	0.18
157.4062500	0.16
159.1480408	0.03
167.4423981	0.04
172.8540192	0.09
181.0263519	0.73
182.2441254	0.18
189.1374817	0.18
195.2879944	0.08
197.2145081	0.06
199.0382843	100.00
200.1437378	3.57
201.0745544	1.03
205.0093384	0.15
227.1296082	0.04
239.0706787	0.08
241.0804443	0.09
242.1515198	0.15
243.0986328	0.22
244.1453857	0.47
245.0493774	0.09
254.2148743	0.07
271.0516968	0.15
271.8952026	0.50
272.8799438	0.09
274.3160400	0.18
286.3007202	0.16
291.2311707	0.07
295.0683594	1.00
300.9536438	0.06
302.3679810	0.70
303.3243713	0.10
304.2189026	0.09
308.7778931	0.06
309.4874878	0.15
315.2866516	0.32
317.1445312	0.96
318.6052856	0.56
319.3672485	0.09
327.2338257	0.15
331.1860352	0.34
343.3146667	0.38
344.0289612	0.15
345.1315613	1.81
346.1278687	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
170.9087524	11.08
178.9238586	21.52
209.156189	4.13
215.1432953	10.13
234.7709351	6.62
237.4202576	17.69
239.045929	4.84
248.9962158	6.68
276.1917725	4.13
277.338501	3.55
291.2319946	27.56
294.3082886	2.46
307.1699219	8.11
308.1350098	25.56
309.9180298	6.40
312.2316895	15.73
314.8905029	10.59
347.5174561	11.98
359.9295044	5.27
371.6522827	14.24
377.1902466	11.12
387.3546143	2.71
395.3815918	8.94
419.135437	5.26
421.2802124	2.99
440.9330444	19.92
444.3502197	4.13
445.4638672	5.81
447.4309082	4.13
453.0123291	42.28
459.4052734	5.28
461.130249	3.54
465.21698	40.99
465.8359375	12.23
471.0809937	29.15
473.1565552	26.24
476.3903198	4.97
483.2835693	15.60
489.3760986	11.09
491.1410522	11.37
499.1211548	7.12
500.2914429	31.84
501.1807251	100.00
502.0638428	11.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8535614	3.63
206.7925415	100.00
217.1594543	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.263
Annotation	linoleamide
Peak:m/z	Relative Intensity
80.95389557	0.89
83.04006958	0.26
86.14494324	0.17
91.00317383	0.11
93.04667664	0.15
94.92330933	2.36
97.0317688	0.64
97.92553711	0.16
99.0874176	0.44
99.99953461	0.28
101.2076416	0.09
104.8718262	0.12
107.070816	0.29
109.0146637	1.29
110.9942245	1.15
111.8764648	0.04
112.8081818	0.26
114.0115967	1.80
115.1103668	0.12
117.1472321	0.12
118.9963531	0.41
120.944191	3.05
123.0402069	1.56
124.8802872	0.81
126.1017303	0.17
127.0912476	0.21
128.071106	3.67
132.0785522	0.04
132.9924011	1.03
135.0470276	3.27
137.1039124	2.21
138.20401	0.15
139.0069275	1.52
140.2121277	0.20
141.0315247	0.09
142.0699768	3.33
145.0092163	0.13
147.052002	0.82
149.0007019	5.36
151.1408234	3.05
153.0015717	1.78
154.1148987	1.09
154.9995575	0.06
156.0864105	2.67
161.1125336	2.87
163.1149292	3.29
165.1402283	3.98
167.1551361	2.57
168.1145172	0.86
169.0696259	0.15
170.1111145	4.22
173.0160828	0.19
175.1134644	2.31
177.0109558	0.68
179.1450806	3.85
180.2284851	0.04
181.0438232	0.80
182.1335449	1.61
184.1723175	4.64
189.1150208	1.65
191.1432495	0.72
193.1080933	0.76
194.1110535	0.04
195.6280518	0.48
196.2373657	2.29
197.6076355	0.18
198.2121582	2.54
201.9460754	0.17
203.1778259	1.70
205.2015991	0.48
207.1925354	0.83
210.1816406	2.44
212.2996521	0.81
217.1217346	1.32
217.9507446	0.05
219.3042297	0.72
221.1078796	1.02
222.2166443	0.30
224.2816772	2.27
234.2657471	0.04
234.9701843	0.03
235.9646301	0.30
238.3735962	0.50
245.2729187	58.86
249.022644	4.98
249.6798706	0.03
252.4210815	0.10
261.5107422	0.09
263.2407532	100.00
265.1239624	0.20
280.4058533	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1608
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0432281	0.03
139.2721558	0.26
142.9285889	0.08
154.9667664	0.06
157.0780945	0.09
160.9092102	0.08
165.1010742	0.12
179.2477112	0.04
180.2173157	0.15
183.0294189	100.00
199.3628845	0.16
201.1340637	0.22
206.9445343	0.28
209.1099243	0.13
210.3029175	0.07
215.9112244	0.11
224.0986633	0.08
224.9907837	0.29
228.2466431	0.04
229.0755310	0.20
231.2962036	0.06
239.1406555	0.04
240.2148438	0.15
243.3041687	0.14
245.2608337	0.11
259.0596008	0.09
267.2481079	0.03
273.2458801	0.14
277.0654602	0.06
285.2409668	0.10
288.7229919	0.06
291.0033264	0.09
293.0741272	0.05
299.3039551	0.11
300.8757324	0.22
304.2127075	0.09
309.1739502	0.11
315.0296631	0.61
319.2223206	0.27
328.1574707	0.09
330.1102600	0.19
331.0551147	0.32
333.3084412	0.08
343.3294373	0.15
344.9036865	3.01
345.5271301	0.88
346.5202332	0.23
347.3881836	0.44
351.5470886	0.18
355.3857117	0.81
357.2352295	0.09
361.2452698	0.07
363.3823547	0.10
371.2168274	0.14
372.3550720	0.17
373.2154541	1.32
374.2875061	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	669.1189
Annotation	Unknow
Peak:m/z	Relative Intensity
201.3714294	0.05
212.2451324	0.08
214.9818115	0.21
226.7200623	0.13
232.2020874	0.06
242.0764160	0.05
251.9746399	0.03
267.7548218	0.20
268.5516968	0.10
280.1557007	0.08
285.7442017	0.08
298.9814453	0.26
305.3425903	0.23
321.9298096	0.15
323.3837280	0.39
327.2953186	0.04
328.1781616	0.05
336.0638733	0.09
345.0529175	0.35
350.9655151	0.06
353.6867676	0.08
358.7984619	0.10
362.5210571	0.08
363.1228638	0.02
364.2933960	0.09
373.3665161	0.10
378.5521851	0.17
384.8580933	0.10
397.3577881	0.10
408.6221313	0.27
421.0783691	0.10
422.9401245	0.20
431.4281006	0.09
438.4034424	0.24
449.3168335	0.24
452.4431763	0.10
456.6801758	0.05
457.5968018	0.25
463.1710815	0.14
467.5083618	0.36
472.5029907	0.22
475.0115967	0.05
477.4727173	0.25
479.4022217	0.14
480.3812866	0.25
482.2088013	0.43
495.4038086	0.20
497.5299683	0.03
501.2359619	0.02
502.0042725	0.14
504.6400146	0.04
507.7244873	0.22
509.4626465	0.17
514.8953857	0.06
515.6295776	0.12
520.6054077	0.38
521.2335815	0.11
521.9668579	0.06
523.2861938	0.10
527.9002686	0.23
534.7379761	0.04
535.6740112	0.03
537.9586792	0.07
538.6137085	0.26
545.8158569	0.24
548.8118286	0.34
549.7095337	0.36
558.4833374	0.12
562.6317749	0.06
563.5617065	0.05
567.8616333	0.44
570.7139282	0.07
575.8123779	0.30
577.2824707	1.23
579.6840210	0.10
582.3480225	0.05
584.5297241	0.42
587.4430542	0.33
591.5422974	0.66
592.1554565	0.41
593.3072510	0.30
594.0272217	0.04
595.7176514	0.50
596.4121704	0.35
598.6635742	0.12
599.4181519	0.12
600.3585205	0.15
601.6087036	0.55
602.4710083	0.24
603.9723511	0.17
605.7144165	0.11
606.4227295	0.03
607.0270386	0.03
608.5436401	0.64
609.2650757	0.38
610.2947388	0.70
611.9542236	0.43
612.8157349	2.08
613.7221069	0.88
614.7540894	0.86
615.3622437	0.92
616.4041748	1.47
617.6981812	0.11
618.4463501	0.22
619.6297607	1.92
620.3854980	2.46
622.5026855	0.12
623.2357788	0.46
624.0943604	0.57
624.8587036	0.28
626.4177856	0.91
627.8145142	0.30
628.8182983	0.29
630.5813599	0.95
633.5073853	1.76
634.4802856	0.83
635.4295654	0.13
636.8487549	0.54
637.9840698	4.21
638.7820435	0.21
640.2506714	4.29
641.1275024	0.85
642.2157593	0.72
644.4600220	5.34
645.0647583	7.69
645.8962402	0.24
647.0437622	0.95
647.8191528	0.66
648.6139526	0.58
649.2455444	0.50
650.8334351	0.77
651.4920044	0.67
652.1271362	0.65
652.8532104	0.22
653.6417847	0.45
654.9645386	0.79
656.5503540	0.19
658.3988647	2.03
659.2863159	0.10
671.0291138	0.21
678.1818237	0.08
680.3233032	0.07
681.1385498	0.32
683.1239624	0.22
683.9843140	0.82
684.6921997	0.27
686.2117310	0.24
686.8787231	0.18
688.7461548	0.03
689.5722046	0.11
690.4531860	0.10
691.7855835	0.50
698.2669067	0.33
701.5158081	0.09
705.5173950	0.78
706.3831177	0.08
707.6300659	0.36
708.8366089	0.03
710.1535034	0.08
711.4136963	0.25
712.1964722	0.07
715.1296387	0.36
717.3656616	0.23
718.5074463	0.72
719.2144775	0.17
720.0608521	0.17
722.3696899	0.04
725.3192749	0.07
725.9202881	0.38
726.7211304	0.03
727.7642212	0.04
729.6810303	0.22
731.0371704	0.08
732.3263550	0.59
733.4440918	0.39
734.1500854	0.23
734.9325562	0.17
736.2325439	1.36
737.8885498	0.48
740.3602905	0.07
741.4465332	0.13
742.8029785	0.33
743.5277710	0.32
744.8554688	0.35
746.2803345	0.68
747.4320679	0.11
748.2465820	0.19
751.1085815	0.15
755.7233276	0.17
757.9518433	0.04
758.8244019	0.04
759.7062378	0.48
762.7948608	0.26
764.7892456	0.03
766.0016479	0.62
768.9890747	0.18
769.8466187	0.04
772.6110840	0.21
775.0486450	0.03
776.0249634	0.23
778.1303101	1.11
779.0172119	0.89
780.0769653	0.32
781.4152222	0.24
782.3110352	0.18
782.9606323	0.08
784.8190308	0.33
786.9347534	0.24
787.6343384	0.29
788.3000488	1.98
789.1287842	0.45
790.3287964	0.28
791.5921021	0.19
795.4235229	0.36
797.5246582	0.50
798.9110718	0.07
799.5161743	0.21
801.1255493	0.90
801.9501343	1.07
803.4805298	0.09
804.5421753	0.08
805.7177734	0.42
807.0144653	1.75
808.0341187	0.70
808.9319458	0.09
810.0697632	0.27
810.8706055	0.27
811.8761597	0.16
812.7190552	0.14
815.6099854	0.99
816.5430298	0.62
817.3380737	1.39
818.7339478	0.08
820.6884766	3.18
821.5813599	6.70
822.3152466	1.04
823.3649292	0.29
826.1680298	4.55
826.8213501	3.14
827.9021606	0.24
829.1196289	0.13
830.3530273	0.21
832.1431274	0.06
832.8046265	0.73
833.5020752	0.39
834.9729614	0.96
835.6077271	0.17
837.0110474	0.89
837.7824097	0.63
838.6231689	0.22
840.4586792	1.96
841.4439087	0.32
842.2658081	0.26
843.5023804	1.09
844.3065796	0.47
846.9585571	0.69
847.9996948	0.84
848.9203491	0.62
850.1258545	0.94
851.2000122	0.16
851.8452759	0.14
853.4003296	2.60
854.0259399	2.90
854.7131348	2.08
855.3357544	0.98
857.1013184	0.58
858.5902710	1.93
859.2327271	25.22
859.9609375	19.30
860.9982300	1.45
862.1181641	0.39
863.8789673	0.53
865.6098022	0.68
866.2763062	0.10
868.2915039	0.33
869.3073120	0.59
870.5942383	0.23
873.8866577	0.16
876.3257446	0.16
883.6899414	0.06
884.8384399	0.04
886.7641602	0.13
889.8323364	0.05
890.6205444	0.19
891.8134155	0.12
893.4801636	0.16
901.7321167	0.06
903.2333374	0.06
905.4057617	0.10
908.6428223	0.05
910.1078491	0.03
911.3195801	0.19
912.9877930	0.14
914.9714966	0.33
920.3377075	0.23
921.8346558	0.45
922.5455933	0.16
923.2306519	0.08
927.4273071	0.07
930.5066528	0.31
932.6348267	0.26
933.6107788	0.05
934.3635254	0.15
942.1814575	0.17
945.2084351	0.12
945.8609009	0.31
949.1597290	0.08
950.8339844	0.19
952.9162598	0.13
960.7236938	0.05
962.5828247	0.27
963.5038452	0.14
964.7139282	0.11
966.4445801	0.13
969.6935425	0.13
971.7770996	0.63
972.8737183	0.10
973.6804199	0.13
974.4030151	0.05
975.2055054	0.10
976.1088257	0.19
976.7780151	0.06
978.3948364	0.04
979.2058716	0.17
980.1242676	0.18
982.0092163	0.02
982.7564087	0.16
988.4511719	0.13
989.5328979	0.03
990.3762207	0.16
991.7811890	0.10
994.4116821	0.02
1011.1474000	0.02
1012.1364140	0.17
1014.7185670	0.09
1016.6439820	0.06
1018.8854370	0.21
1019.7014770	0.08
1021.7412110	0.13
1022.4147950	0.06
1024.7490230	0.41
1025.5820310	0.36
1027.3298340	0.31
1037.2923580	0.08
1038.5876460	0.20
1046.4318850	0.29
1049.0361330	0.14
1053.4343260	0.07
1055.2158200	0.05
1056.8837890	0.15
1058.3007810	0.20
1060.7042240	0.16
1061.6469730	0.14
1074.3714600	0.56
1075.4169920	0.45
1076.6459960	0.19
1087.7409670	0.11
1089.0682370	0.42
1090.2578120	0.33
1093.1542970	0.07
1094.9382320	0.18
1099.8706050	0.05
1101.5637210	0.14
1102.6782230	0.26
1103.8425290	0.19
1104.7160640	0.19
1111.3573000	0.03
1114.7707520	0.03
1116.8927000	0.15
1118.2539060	0.20
1121.3790280	0.13
1124.4851070	0.07
1139.3660890	0.24
1140.1560060	0.07
1142.9270020	0.03
1143.6221920	0.13
1145.5632320	0.33
1151.7604980	0.17
1157.2683110	0.06
1158.0688480	0.10
1163.3052980	0.15
1166.3593750	0.06
1167.3979490	0.06
1175.0541990	0.04
1176.3671880	0.12
1180.1105960	0.03
1186.9829100	0.14
1187.9245610	0.13
1203.4486080	0.13
1208.4304200	0.12
1209.4013670	0.18
1212.1790770	0.24
1212.9161380	0.13
1214.9451900	0.16
1217.0478520	0.12
1243.6768800	0.06
1316.0821530	0.24
1361.1624760	0.05
1385.9206540	0.10
1428.8470460	0.10
1486.7045900	0.11
1512.9703370	0.07
1574.4786380	0.08
1584.0191650	0.07
1661.1306150	0.14
1694.6944580	0.03
1699.0909420	0.07
1736.4156490	0.03
1747.7331540	0.28
1784.0383300	0.32
1812.1779790	0.14
1842.5233150	0.22
1844.0089110	0.88
1864.7966310	0.03
1881.2955320	0.04
1882.9698490	0.03
1905.1492920	0.58
1908.7784420	0.50
1926.2951660	0.04
1933.3485110	0.03
1936.2751460	0.10
1973.0383300	0.21
1986.7276610	0.04
1993.0910640	0.09
1994.4289550	100.00
1999.8377690	2.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1298
Annotation	Phloridzin
Peak:m/z	Relative Intensity
125.0267181	0.06
145.9951477	0.02
147.0071106	0.03
149.0236206	0.22
150.9908142	0.09
162.1417236	0.05
163.3180084	0.03
167.03479	2.80
176.015625	0.03
178.9514465	0.20
189.1260223	0.03
191.0248413	0.10
198.9790039	0.04
201.5486145	0.04
203.0279694	0.03
205.1164551	0.12
213.2151642	0.02
223.0757446	0.01
223.9537048	0.02
226.608963	0.18
227.519043	0.18
250.9531555	0.19
255.3246155	0.09
255.9329834	0.02
263.1564026	0.07
265.2097168	0.03
269.2746582	0.03
271.1457214	0.25
273.0740967	100.00
274.0236206	0.02
277.3852539	0.03
281.2180481	0.01
287.536499	0.02
288.9739075	0.07
290.029541	0.06
295.2131653	0.03
297.170166	0.57
299.383606	0.03
309.1531372	0.03
313.3463745	0.03
315.2609863	0.40
317.2690125	0.08
318.2699585	0.03
319.3043213	0.01
321.3679199	0.05
327.3293457	0.13
329.1999512	0.05
336.3083496	0.01
339.236145	0.36
340.1379395	0.06
341.1341248	0.02
345.2141724	0.02
350.2797241	0.08
371.4281311	0.13
372.3197632	0.03
374.3437195	0.03
388.42099	0.18
389.3036194	0.53
391.4283142	0.15
392.4752502	0.02
399.0476379	0.03
415.4372253	0.03
416.2867432	0.29
417.3630981	0.40
438.0518799	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
100.8848419	0.10
107.9559937	2.08
121.0614319	1.19
123.0179367	1.66
124.9707565	0.06
137.1622620	0.06
149.0041809	0.33
152.0437927	4.96
166.9496460	100.00
177.0486908	0.06
193.0703278	0.04
203.0398712	0.18
209.1551208	0.45
210.9111023	0.23
219.4894714	0.14
220.6395569	0.05
227.0643311	0.14
228.9358521	0.26
232.0767822	0.17
232.9868164	0.23
235.9627991	0.04
237.0661011	0.14
238.1674805	0.20
239.2686768	0.14
239.9814758	0.24
241.7196350	0.70
255.1372986	0.03
269.3070679	0.10
271.3055115	0.03
273.2276611	0.11
282.0737915	0.03
283.0170593	0.95
285.2536011	0.03
290.8768311	0.05
293.0442505	0.19
299.2305908	0.10
301.1049805	0.09
309.2038574	0.23
310.3930359	0.19
311.2169800	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
195.9333801	1.93
214.0024719	1.70
248.7734375	0.04
255.2402954	100.00
255.8556519	0.45
265.4170532	0.04
271.3651123	0.19
291.6873169	0.03
304.038208	0.09
353.4493103	0.07
359.2440186	0.06
367.1520996	0.07
371.6976624	0.04
384.6343384	0.07
388.3821106	0.11
389.2314148	0.13
390.6088867	0.05
391.2378845	0.04
405.5415955	0.96
406.6203308	0.03
407.3335876	0.07
408.6402893	0.07
421.4538879	0.22
423.412262	0.63
424.7118835	0.12
432.0267639	0.07
434.292572	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8937912	0.21
138.9408569	0.01
206.8509521	4.10
290.7190247	100.00
291.3807983	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	864.1895
Annotation	Unknow
Peak:m/z	Relative Intensity
243.0411987	0.22
245.2704926	0.50
256.2280884	0.68
256.9629211	0.04
261.1553650	0.04
269.0142822	0.15
270.8378906	0.11
273.0856934	0.06
279.1348877	0.15
280.2673035	0.10
281.2233582	0.05
283.4947815	0.05
285.1756592	0.21
287.0826111	4.58
288.1098328	0.47
289.0650940	2.06
294.4630127	0.05
299.2250977	0.24
300.2189941	0.11
301.1109619	0.25
305.3098145	0.11
313.0133972	0.09
316.7606201	0.11
329.2204590	0.50
331.1447754	0.19
334.8495483	0.06
339.2991333	0.21
341.0046387	0.18
351.3982849	0.06
361.0936890	0.09
363.2224731	0.74
365.3817139	0.29
366.4349976	0.09
373.2119751	0.03
379.1281433	0.21
380.2793274	0.24
381.0942993	0.14
388.2323608	0.09
395.1784668	0.67
396.0748291	0.15
405.0869751	1.65
406.2767334	0.39
407.1946411	5.06
408.2503662	0.78
409.4132080	0.19
411.1937866	0.07
412.5399780	0.34
413.2316895	1.70
414.6723022	0.11
417.2283936	0.05
421.1240845	0.06
422.0559082	0.09
423.3298950	1.48
424.1429443	0.25
425.1511841	2.30
426.1490479	0.04
427.2976685	0.09
430.9074097	0.39
435.3480225	0.22
436.4134521	0.11
437.4296265	0.09
446.9227905	0.23
449.1719360	2.28
450.3524170	0.54
451.2789307	1.18
452.2726440	0.50
453.2845459	0.41
455.2384644	0.52
469.7675171	0.23
473.6455688	0.05
482.2070312	0.11
487.1406860	0.25
490.9826660	0.24
493.4266357	0.07
494.2822266	0.82
499.2044678	0.48
500.6082153	0.23
506.3472900	0.05
511.2405396	0.21
512.1701660	0.16
513.9512329	0.17
515.1755371	0.16
523.1940308	0.31
525.4420166	0.44
531.2304077	0.79
533.2316895	1.04
541.1707153	0.28
542.3428955	0.10
543.4417725	0.08
548.6721802	0.21
549.3146973	0.13
550.2950439	0.58
550.9342651	0.27
553.0513306	0.28
553.6965332	0.11
555.5172729	0.06
556.9869385	0.41
558.0121460	0.13
559.3094482	1.22
567.2828979	0.20
568.3705444	0.29
569.4949951	0.07
570.3135376	0.20
572.1893921	0.10
573.1130371	0.18
575.1854858	3.69
576.2207642	1.89
577.2050781	6.05
578.2085571	1.63
581.8097534	0.19
582.5072632	0.09
584.9679565	0.36
586.0491333	0.93
587.1967163	1.05
587.9776001	0.41
589.4165649	0.07
591.2529907	0.19
602.8040771	0.20
605.9246216	0.18
609.7871704	1.13
611.3285522	0.13
613.4864502	0.09
616.2140503	0.04
618.5335083	1.43
619.5403442	0.50
625.2510376	0.06
625.9441528	0.24
627.3374634	0.52
631.8898926	0.04
634.3994751	1.29
635.2238159	0.36
635.9816895	0.58
638.2355347	0.47
638.8620605	0.07
639.6542969	0.12
640.4675903	0.13
643.6948242	1.01
644.4907227	0.97
651.3214722	0.16
656.6275635	0.79
657.6547241	0.71
659.2338257	0.08
661.3929443	0.21
665.2502441	0.06
669.3748779	0.11
671.3471069	0.21
677.3668213	0.03
678.3802490	0.08
679.1742554	0.22
681.3458252	0.16
683.2251587	0.19
685.4916382	0.76
686.1325684	0.43
687.4443359	0.05
690.7337036	0.08
693.0739136	2.69
694.2127686	2.52
694.8750610	1.78
695.7620239	2.19
696.9174805	0.16
698.1176758	0.62
698.8712158	0.08
701.2953491	2.01
702.0910034	0.22
703.3140869	1.68
703.9301147	0.03
705.2969360	0.16
707.3704224	0.73
709.6475220	0.13
710.2858887	0.38
711.3023071	1.46
712.3961182	0.80
713.2584839	0.40
714.2927856	0.16
716.6488037	0.97
719.5945435	3.58
720.4229126	3.62
721.3689575	0.61
722.3244629	0.04
724.2442017	0.49
725.5661011	1.09
726.4130859	0.77
729.7084351	0.04
736.0097656	0.17
737.1859741	1.81
738.5078735	0.69
739.3167114	2.67
740.3410034	0.57
741.3665161	0.30
743.2288208	0.15
750.4537964	0.09
751.9255371	0.30
755.2098999	0.15
756.2612915	0.12
757.4485474	0.91
761.7504883	0.15
763.1602173	0.07
765.3768311	0.04
766.3086548	0.64
770.6787109	1.91
779.4453125	12.79
780.4707642	0.56
781.4288940	0.19
784.1773071	0.16
788.2577515	3.27
789.0466919	0.56
792.9710083	0.06
797.3632202	0.22
801.0606689	1.51
801.7205811	2.26
805.5839233	0.05
807.5272217	0.73
811.4320068	0.25
813.3838501	0.52
819.3814087	0.22
820.3118896	0.17
821.2297363	0.46
830.9817505	0.21
832.2307739	0.23
837.3001709	0.11
839.4506226	0.12
842.8925171	0.08
845.0193481	0.33
846.1316528	0.64
847.3963013	0.60
848.6708374	0.03
862.9669189	0.51
865.1331177	100.00
866.3438110	0.30
867.3451538	0.05
874.7990112	0.55
875.6298218	0.45
880.2697144	0.12
901.3912964	0.03
903.1137085	0.19
904.4411011	0.12
905.3122559	0.10
906.9749756	0.22
908.2605591	0.20
917.7365723	0.46
922.3253784	0.27
932.8654175	0.09
940.2575684	0.06
947.5666504	0.07
955.4472656	0.04
957.6338501	0.05
964.3183594	0.57
965.9671021	0.10
968.3945312	0.11
971.2646484	0.68
972.1935425	0.44
973.3643188	0.11
981.2643433	1.84
982.2664185	0.78
983.3558960	1.13
984.3351440	0.50
989.2138062	2.03
990.2988892	1.53
995.0569458	0.06
996.9227905	0.07
998.5941772	0.22
999.2819824	0.40
1000.4019170	0.24
1001.3716430	0.30
1002.3386840	0.41
1009.3390500	0.50
1010.2113650	0.16
1025.2243650	0.95
1026.4045410	0.71
1027.3398440	2.36
1027.9733890	0.37
1028.9360350	0.31
1032.2083740	0.08
1058.7070310	0.24
1070.1956790	0.09
1073.7685550	0.19
1107.0566410	0.63
1109.3216550	0.56
1110.3443600	0.44
1119.5698240	0.12
1126.0781250	0.16
1133.6311040	0.25
1134.9189450	0.23
1136.1295170	0.58
1142.9202880	0.39
1143.8132320	0.24
1145.4216310	0.21
1146.7305910	0.17
1150.7070310	1.68
1151.4025880	6.40
1152.3853760	4.22
1153.2546390	5.11
1154.2733150	4.62
1155.2572020	0.09
1162.0666500	0.16
1163.2135010	0.45
1164.4744870	0.04
1174.4337160	0.31
1189.8054200	0.18
1193.4287110	0.24
1195.9875490	0.70
1203.1701660	0.18
1211.0832520	0.06
1226.8376460	0.20
1234.3625490	0.35
1235.2288820	0.29
1256.4541020	0.22
1259.2794190	0.20
1263.4079590	0.07
1269.5198970	1.53
1270.3989260	0.15
1271.3718260	0.57
1272.4450680	0.73
1275.2008060	0.14
1277.1704100	0.68
1278.2387700	0.55
1279.5377200	0.09
1282.5982670	0.09
1287.2933350	0.12
1290.7518310	0.10
1298.4127200	0.02
1313.5174560	0.48
1314.3951420	0.25
1315.2954100	3.47
1316.3114010	1.40
1317.3950200	0.21
1331.5245360	0.25
1358.5179440	0.08
1397.2962650	0.20
1416.3770750	0.07
1423.1166990	0.44
1424.2254640	0.13
1433.0775150	0.31
1433.8876950	0.26
1434.6767580	0.27
1439.2020260	1.83
1440.2807620	1.45
1441.0992430	1.99
1442.2808840	1.60
1451.4614260	0.20
1452.5958250	0.14
1466.2678220	0.36
1477.2465820	0.08
1483.0473630	0.74
1484.4464110	0.58
1558.6116940	0.27
1561.4770510	0.07
1586.1514890	0.40
1603.3825680	1.72
1604.4237060	0.88
1605.4315190	0.28
1643.8312990	0.06
1648.2630620	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1451
Annotation	Lamiol
Peak:m/z	Relative Intensity
115.0360107	0.03
128.9280090	1.11
129.9919128	0.20
136.9284973	0.25
140.9967499	3.00
141.9703064	0.19
149.1007385	0.09
155.0489807	15.43
156.0876160	1.78
159.0782623	0.97
175.1178589	0.10
177.0667267	20.29
178.0783539	2.12
180.8851166	0.35
181.9760590	0.15
195.0873566	0.18
199.0449982	44.94
200.0736084	3.53
213.2796631	0.20
214.1813202	0.04
241.1200867	1.33
242.1539001	0.15
251.1490479	0.37
254.9452209	0.21
258.1026001	0.06
267.2294312	0.23
268.2754517	0.28
269.3813477	0.32
270.8969116	0.09
272.4269714	0.04
279.2132568	0.22
281.3900146	0.33
283.2442627	0.47
301.4377441	0.53
302.1731567	0.12
311.1853333	0.15
315.0221558	0.09
323.2445984	0.14
324.3865967	0.14
331.1771851	0.08
333.2101440	0.16
341.3425903	0.69
342.2775574	0.04
359.1724548	100.00
360.2363892	18.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.15
Annotation	Gibboside
Peak:m/z	Relative Intensity
112.9327545	0.16
116.9259109	0.05
129.0513458	0.20
130.9873047	0.10
132.9955139	0.08
134.9230652	0.04
137.1603241	0.25
139.2242737	0.10
142.8576508	0.20
153.0542603	0.30
155.0993958	14.99
160.9320068	0.43
162.8679504	0.05
169.0964813	0.11
173.0975342	0.02
175.1668243	0.04
177.0665588	0.21
178.9688721	0.05
181.1559448	0.25
182.7514038	0.04
195.2675934	0.06
197.0935822	0.16
199.0950928	100.00
205.316864	0.08
207.2000885	0.04
213.1485901	0.06
215.0214539	0.02
225.1731567	0.03
235.2961426	0.04
239.0733643	0.05
241.1107483	3.05
243.2275696	3.27
245.2164001	0.05
246.0430298	0.03
249.1955261	0.02
252.9968262	0.47
264.0697632	0.05
265.1578369	0.26
266.2399292	0.06
267.1765137	0.10
270.9960022	3.33
271.6261597	0.03
273.0133667	0.34
276.9607239	0.14
279.0727234	0.04
280.0831909	0.10
281.2437134	0.44
285.3648376	0.03
287.1296082	0.19
289.432373	0.11
299.2185669	0.32
301.078064	8.92
301.690094	0.07
307.3151855	0.05
313.1726685	0.31
314.9073486	0.62
317.3123169	0.18
325.2993469	0.55
329.2068481	0.05
331.1521606	0.76
341.0211792	0.19
343.2485962	1.76
346.334137	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	450.0713
Annotation	Unknow
Peak:m/z	Relative Intensity
135.8822479	0.14
140.9062195	0.22
142.7309570	0.42
147.0694885	0.30
149.0397034	0.21
150.9262390	0.66
156.0164337	0.21
159.2210693	0.36
162.2249603	0.08
167.1426086	0.09
171.1369934	0.53
172.8969727	0.15
175.2975464	0.39
179.1109619	0.30
184.8388672	0.30
195.2455750	0.15
195.8660278	0.07
203.0755615	0.16
204.9493256	0.10
211.0151520	0.62
213.9222717	0.06
215.2528076	0.43
218.9078979	0.20
223.1541138	0.06
225.1578979	0.10
228.7808990	0.09
233.2395172	0.16
238.7700500	0.09
240.1737671	0.45
243.1263123	0.23
244.9941101	0.22
247.1434021	0.31
251.3141785	0.36
252.0119019	0.09
255.3255920	0.31
267.2661743	0.33
269.1423035	1.00
271.2925720	0.08
273.1332092	0.19
279.2007141	0.37
281.0877686	0.38
287.0919495	100.00
288.1768799	18.55
293.7800598	0.08
298.3196411	0.12
299.3811340	0.33
300.2646484	0.32
302.9980164	0.09
307.3248901	0.34
309.2895203	0.40
310.9015808	0.32
313.2263184	0.92
314.8054199	0.15
317.0839844	0.40
322.2472534	0.19
324.3129272	0.15
325.0094604	0.42
327.3148804	0.54
333.1477966	0.35
344.9553223	0.22
346.8689270	0.33
349.3324585	0.23
351.2097168	0.49
352.4095459	0.23
360.1560364	0.53
362.6390381	0.16
368.1465759	0.62
379.0652161	0.09
380.1183777	0.06
383.1018372	0.14
384.0792542	0.27
386.2207947	0.04
387.3869934	0.14
389.4007263	0.53
397.2793274	0.17
400.8230896	0.09
401.9881897	0.05
403.6407166	0.35
404.4690552	0.50
405.2546082	0.72
406.3404236	0.14
407.8838806	0.26
413.3688660	0.08
414.4313354	0.29
416.5201111	0.18
417.3396301	0.06
421.8181458	0.40
426.3789978	0.59
428.5823669	0.99
430.0372314	0.18
431.1612549	0.72
431.9964905	2.67
449.5402832	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1504
Annotation	Icariside H1
Peak:m/z	Relative Intensity
110.8886490	0.10
112.9635086	0.13
117.0507660	0.07
118.9380646	0.14
123.2166214	0.11
129.0732727	2.26
133.0623779	0.64
134.9778900	4.93
143.0017242	0.20
145.0624084	2.28
146.2810059	0.37
148.8366394	0.17
150.0709686	0.17
150.8946381	0.11
158.9789124	0.59
161.1147461	2.88
162.8190918	0.20
168.0745544	0.23
171.1712341	0.21
177.0620880	25.17
179.1476746	33.61
181.0933838	0.06
193.0059662	0.51
195.0518494	1.16
198.9439240	0.13
201.1334534	0.06
202.9867554	5.05
204.8975220	0.55
207.1366730	13.47
207.8912964	0.27
215.3038330	0.21
217.2402649	0.35
221.0260315	2.99
223.0438232	100.00
232.6905823	0.14
234.1060486	0.18
235.1178589	0.20
237.3303528	0.19
238.0600891	0.20
246.2931824	0.23
247.0930786	0.12
249.0227966	0.27
251.2025452	0.78
253.2646790	0.24
258.0325928	0.05
259.3074036	0.08
265.0937195	1.95
269.9631042	0.19
271.3877563	0.29
276.4572144	0.58
277.2994385	0.63
279.1165466	0.18
281.1262207	0.30
283.4151611	0.11
285.3748169	0.26
288.1007080	0.20
289.0473633	0.63
295.1644897	1.00
297.2984619	0.12
301.3125000	0.30
305.9934998	4.48
307.1004333	1.46
313.1812744	0.11
323.4750366	0.19
325.0896301	2.60
326.9814148	0.44
335.4042358	0.11
339.2036133	3.96
341.2944031	0.44
343.3888550	0.41
349.4866638	0.55
355.1324768	0.20
365.0440369	0.16
367.1727600	1.78
367.7839355	0.72
370.1124878	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8876648	0.38
130.8785400	1.46
146.9203186	0.60
158.9669647	10.09
160.9111023	0.10
174.8851929	100.00
215.1703491	0.19
216.8649292	0.22
233.0598145	0.50
243.1442871	0.05
244.8507080	24.77
249.3485107	0.04
259.3606567	0.03
260.9863892	0.50
287.5553589	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.083
Annotation	dTDP-beta-L-rhodinose
Peak:m/z	Relative Intensity
167.1919556	0.11
171.0698853	0.08
173.0979156	0.09
189.0158234	0.10
190.6902008	0.13
201.9142456	0.04
213.3728790	0.11
215.2084503	0.10
216.3755798	0.06
219.0287476	0.10
221.0598907	0.13
229.1752777	0.13
233.2491760	0.06
235.0345764	0.09
241.1558228	0.59
252.8372498	0.06
254.9865417	0.09
264.1337891	0.52
265.0456543	0.66
272.1702271	0.06
279.9102783	0.37
281.2249146	0.13
283.1907349	0.20
285.1978760	0.05
293.1602173	0.29
304.2096558	0.20
308.1570435	57.52
309.1317139	100.00
310.9526978	0.22
321.1574707	0.39
322.1850586	0.49
323.1983643	1.00
324.0460205	0.09
325.0233765	0.06
334.1020508	0.22
334.9949341	0.13
337.1473389	0.55
339.1695557	0.24
340.0672607	0.19
351.1225586	4.27
352.0731201	30.21
353.1354980	16.86
353.7608643	0.13
357.4960938	0.14
361.1707764	0.19
367.2041626	0.41
371.7843628	0.28
379.1541138	0.11
380.3881836	0.15
381.5042725	0.93
382.7949219	0.23
383.5388184	0.08
389.3433228	0.67
391.1771240	0.11
393.2244873	0.27
393.9158936	0.14
395.2818604	0.05
396.2360840	0.17
405.4772949	0.43
410.8958740	0.12
417.3994751	0.11
425.3776855	0.10
427.2970581	0.47
429.2462769	3.05
430.1360474	0.96
431.1985474	0.43
442.2437744	0.28
443.3114014	0.04
447.1712646	0.40
451.1174316	0.17
468.1190186	0.18
469.3748779	0.56
471.1726685	66.90
497.1191406	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
573.3740234	1.10
657.3057251	1.46
658.3544312	0.56
696.4071655	3.67
804.4028931	4.36
843.4091187	1.04
919.8753052	3.74
930.7686157	0.96
966.350647	1.04
967.4436646	100.00
968.6500854	9.80
970.3240356	2.04
972.1195679	2.16
974.7988892	1.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1824
Annotation	Scopolin
Peak:m/z	Relative Intensity
292.0020142	0.04
353.1145020	100.00
354.0225830	0.03
500.2282104	0.11
501.1285400	0.25
515.0386353	0.49
545.0522461	0.16
635.2366333	0.24
664.4423218	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1435
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9472351	0.30
127.9035187	0.23
145.0550385	0.47
156.8665314	0.15
158.1919098	0.17
167.0559998	0.32
174.9882812	0.07
185.3005066	0.08
201.8618774	0.11
220.1304016	0.08
232.0423584	2.45
233.0585022	0.92
242.1965942	0.36
250.0079346	10.88
251.0487671	4.56
268.0444031	100.00
269.0720825	22.15
275.4196777	0.20
286.1129150	87.20
287.2197571	18.29
299.3984985	0.18
310.1054077	0.13
314.0031128	0.15
316.4234009	0.39
317.1494446	0.12
318.2681885	0.17
328.9757080	0.12
337.1746521	0.11
338.4776001	0.11
341.2479248	0.20
351.1596069	0.04
353.9226074	0.05
383.0710754	0.18
390.3090515	0.43
396.3870850	0.23
399.4286804	0.07
402.7596741	0.18
403.4241638	0.30
406.8414001	0.15
411.9783936	0.91
413.1833191	0.23
415.1766052	0.13
416.8779297	0.09
430.1393127	47.36
431.2456970	14.53
438.1098328	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.26
Annotation	Alangionoside O
Peak:m/z	Relative Intensity
155.1051178	0.14
161.0993652	0.27
178.7601013	0.44
195.0589905	0.06
206.1009216	0.09
207.2613678	0.08
213.1903076	0.63
215.1917114	0.10
220.8674927	0.10
245.0545959	0.20
254.9942322	0.14
259.0125427	0.13
263.1184082	0.12
268.2236633	0.14
296.3828125	0.20
299.1467896	7.11
311.3204956	3.70
323.1366577	0.32
328.8984375	1.15
329.8964844	0.18
339.1589966	0.08
343.2549438	0.25
357.3553467	3.66
359.4579468	0.13
365.2999878	0.22
375.3358765	100.00
376.3305054	0.30
377.5999146	0.23
393.4105225	0.15
417.4115601	0.26
419.1915283	1.68
420.5878906	0.43
421.5020142	2.09
422.5149536	0.32
441.4069824	0.10
443.1976929	0.24
445.7119751	0.10
446.3341064	0.07
457.6571655	0.36
475.4003906	0.07
490.7805786	0.49
491.4550781	0.52
492.2687988	0.27
493.1886597	1.04
499.2048950	0.17
501.2944336	0.46
517.2374878	0.32
519.4570923	11.06
522.6432495	0.09
538.5208130	2.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
116.4298401	0.06
117.0411301	0.61
124.9999466	0.07
131.9353027	0.20
132.9113922	0.06
133.8853149	0.20
134.9816284	0.88
144.9766541	3.94
147.0851135	0.06
163.0339661	100.00
164.870636	0.03
175.1571045	0.05
176.0636749	0.06
176.8794556	0.05
182.2358398	0.05
193.0553284	0.23
200.7406006	0.18
207.4094543	0.14
211.1271057	0.09
212.8978882	0.06
225.2156067	0.03
233.0827942	0.26
236.949646	0.05
238.9322205	0.04
239.9373779	0.04
242.1549683	0.09
246.5504456	0.02
248.9703979	0.10
252.8930664	0.15
255.1102905	0.08
257.1062012	0.17
259.1651306	0.26
261.0503845	0.09
263.2810364	0.09
265.7182007	0.04
266.8049316	0.08
268.0158386	0.02
279.3364868	0.12
281.1096191	0.07
282.1564941	0.20
284.1327209	0.26
285.0631409	0.10
291.1749878	0.24
293.0730896	0.36
295.4749451	0.13
296.3509521	0.11
297.1135254	0.09
299.1648254	1.46
300.1664124	0.30
305.573822	0.09
307.1904602	0.07
308.0835571	0.06
309.1372681	0.40
310.1517029	0.05
311.0198059	0.32
312.1726074	0.05
313.7711487	0.50
319.4026184	0.21
324.4682007	0.12
325.2200012	0.12
326.6172485	0.30
327.3123169	1.32
328.3786011	0.26
331.5673828	0.11
332.4616699	0.15
335.3345337	0.24
336.3800049	0.75
337.117157	1.56
338.2728271	0.09
346.8863525	0.11
355.1560974	0.74
356.4197083	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	805.3245
Annotation	Phyllanthoside
Peak:m/z	Relative Intensity
241.2155609	0.16
246.1123657	0.23
248.0365906	0.14
250.2575684	0.10
255.0309753	0.47
264.9938660	0.27
271.3031616	0.55
297.3511963	0.26
300.3799438	0.11
301.2714844	0.10
307.3710632	0.43
319.2666321	0.10
321.1906738	0.09
323.8225098	0.19
325.3206787	1.05
330.3101807	0.07
337.2695923	3.18
339.2519226	0.35
341.3937683	0.12
343.2985840	0.17
354.6701355	0.04
355.3218994	0.64
357.2331848	1.69
366.8377686	0.16
369.0475464	0.55
371.5787354	0.10
376.5269775	0.06
383.3035889	0.27
386.1109619	0.26
387.3852539	0.20
399.5523071	0.07
415.4698486	0.06
418.3302002	0.11
422.6208496	0.36
426.4898071	0.07
428.2908325	0.50
430.4168091	0.06
431.7399292	0.53
432.4526978	0.16
444.3603516	1.55
446.3408203	0.27
447.4615479	0.52
448.3329468	1.38
454.2799683	0.20
456.5963135	0.10
458.4729004	1.23
460.2579956	3.94
470.7479248	0.13
472.3942261	4.25
474.2454224	1.27
475.1273804	0.18
476.4645386	1.05
478.3856201	2.32
480.2267456	0.62
486.0216064	0.05
488.3760376	2.62
489.6008911	1.24
490.4167480	4.84
494.2968750	0.62
499.9188232	0.21
501.0509644	0.13
502.1865845	0.82
502.9554443	1.15
504.2675171	11.95
504.8805542	0.21
513.9200439	0.23
517.1557617	0.07
520.3358154	5.69
522.3241577	55.64
523.0700684	0.49
529.8110352	0.15
530.4431152	0.43
531.2688599	0.45
533.7100220	0.33
540.4241943	0.29
551.4297485	0.88
552.8133545	0.11
554.2009888	0.17
559.3585815	0.04
567.1304932	1.49
567.8084106	0.08
572.3145142	0.25
574.7729492	0.26
575.4878540	0.21
577.4279175	0.79
578.1527710	0.19
583.3536987	0.56
584.3805542	0.16
588.5756836	0.53
593.2300415	1.17
595.3067627	9.03
598.4165649	0.21
602.5286865	0.48
606.2184448	1.34
608.6624756	0.10
611.3051758	10.34
613.3615723	0.06
614.4796753	0.38
615.5332642	0.25
616.1340332	0.10
620.5513916	0.26
625.3431396	1.46
627.1260376	2.01
627.9514771	0.06
631.8261719	0.55
632.5816040	0.35
633.2033081	0.10
634.4567871	0.33
638.4835815	18.99
643.2630615	13.11
650.3367310	11.23
652.3180542	8.17
653.3449707	0.55
655.5962524	0.21
656.4414062	0.19
657.3768921	0.08
664.0960083	0.13
665.5690918	0.15
666.6951294	0.08
670.7142944	0.38
682.3455200	100.00
683.7804565	10.31
684.5213013	17.06
685.7429810	0.10
691.6339722	0.27
711.3611450	0.32
719.3937378	0.43
721.0883179	0.17
729.4550171	2.08
737.5438843	1.35
745.4772339	0.44
755.1696167	1.10
773.3746948	40.78
774.0139771	0.31
787.3757935	0.18
794.8484497	0.09
805.3612061	49.91
806.0330200	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0594025	0.14
198.8790131	0.38
217.0484619	0.03
229.0479584	0.25
273.0344238	21.09
274.9978027	0.03
289.1689453	0.06
370.9904785	0.11
384.0567627	0.03
384.9251709	0.32
386.9409180	32.97
412.9899292	0.02
427.1169434	0.14
445.2975464	0.04
451.2544556	0.06
457.4044800	0.13
469.1043701	0.03
479.8767700	0.10
484.6917114	0.17
488.6978760	0.03
498.3358154	0.16
499.2529907	1.31
500.8857422	100.00
501.5089111	0.45
513.0676880	0.06
523.0363159	0.07
530.1026001	0.06
531.7908936	0.07
538.3469849	0.03
540.9475098	0.45
547.7142944	0.11
563.9160767	0.07
567.0768433	0.02
567.9044800	0.22
568.9356689	1.05
570.8359985	0.46
571.8710938	0.14
582.0658569	0.20
582.9053345	0.20
595.6655273	0.12
596.7827759	0.06
615.0857544	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.8108826	1.53
84.8988800	0.02
101.9301758	19.76
129.9091949	100.00
130.9238281	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.2183
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9972229	0.31
143.0100555	1.52
144.1648254	0.03
149.0139313	1.89
150.2540588	0.11
153.1293335	0.37
159.1158142	0.06
161.0445099	3.66
162.0124054	0.12
167.0162048	3.97
168.1033630	0.43
177.1185608	0.02
178.9397888	5.78
179.9756470	0.24
187.8612061	0.02
203.1700745	0.14
205.3263855	0.03
207.0433807	0.19
208.0199890	0.13
209.0460205	0.06
225.0758057	3.19
226.1461182	0.30
226.8917999	0.05
227.8385620	0.07
231.1152344	0.27
232.1874237	0.11
243.2482300	1.99
244.2270203	0.60
244.9449768	0.27
246.2885437	0.15
253.1939697	0.05
267.0559387	0.03
271.3228760	0.34
272.1460266	0.06
285.2532043	0.06
286.1703491	0.07
287.4169922	0.24
288.5478821	0.59
289.1614380	3.59
290.1503601	0.79
297.2879944	0.25
299.0707397	0.16
300.4534302	0.04
315.4125671	0.03
327.3489075	0.44
331.1951294	0.04
341.1200562	0.06
355.3813477	0.09
371.4331665	0.05
392.3017273	0.03
398.3199768	0.06
405.1849670	100.00
406.2095642	14.52
407.2697754	0.43
408.8588257	0.23
410.4676819	0.20
423.2427673	0.05
433.4869690	0.51
434.4364624	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
84.85457611	0.55
90.66119385	0.18
93.14637756	0.62
94.77713776	0.41
95.39914703	0.09
96.88251495	2.69
98.95361328	0.12
107.0690002	0.53
108.9059677	2.23
110.9427414	0.50
112.9759064	0.58
118.8020325	0.23
120.9705276	1.56
123.1016388	1.01
125.029892	0.23
129.2005157	0.09
132.9397736	0.38
135.1563721	0.24
137.036377	0.40
139.0470276	6.58
142.7532043	0.25
144.9711304	0.10
148.9967499	0.10
150.9197845	0.14
152.9119873	3.08
153.9631653	0.19
155.0252075	0.09
157.118103	0.88
161.0565643	1.32
163.1038666	0.16
165.2653961	0.11
169.1772156	0.18
171.3214722	0.63
172.7246704	0.12
173.9103088	0.11
175.2322693	0.07
177.0523987	0.20
178.9728088	0.50
179.9293671	0.33
181.134613	0.85
183.1690674	1.21
184.2946472	0.49
185.1822205	0.64
189.2705078	0.36
192.042511	0.21
193.2141113	0.54
197.0686646	4.73
201.1595154	0.80
203.1969604	2.19
207.0774536	0.28
209.0933228	0.92
210.9890747	1.95
213.3020935	1.59
215.0463867	0.39
217.419342	0.47
219.1740112	0.76
221.1841125	2.17
221.9710083	0.13
223.2279968	1.26
225.1309814	0.93
227.2393799	0.22
228.1411133	0.58
237.1280823	3.02
238.6351318	2.65
239.2643433	17.94
241.198822	1.42
243.0389099	0.91
250.1894531	0.37
251.3356018	0.83
252.0892639	0.29
253.2154541	2.58
254.9480591	1.87
256.8155518	1.07
261.3248901	4.13
269.5513306	0.92
279.2352905	100.00
280.0864563	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.14272308	0.67
94.75601196	0.31
96.62242126	0.19
98.94950104	0.54
100.9456635	0.83
108.7471008	0.40
111.1282272	0.40
113.1293335	1.39
118.9289093	0.89
122.1725769	0.16
122.8047943	0.43
124.826088	1.82
126.8982773	2.37
129.101593	0.78
134.6907806	0.52
136.3551636	0.24
137.1926575	0.61
139.1828918	0.65
140.8634186	1.26
142.9172058	4.96
144.805603	0.49
147.0909424	1.07
149.0900726	0.85
150.9095154	2.77
153.3544312	0.68
154.8946838	1.25
157.0103149	1.49
158.8605042	0.79
162.9648438	4.75
165.0996704	1.46
167.0217133	0.83
168.5483551	0.54
169.18396	0.76
170.8970032	0.81
175.1112366	1.93
177.1225891	0.90
179.0118713	0.53
180.9337463	1.53
183.0864563	1.18
184.9411163	1.73
186.8666382	1.65
189.2483826	0.23
190.0001831	0.60
191.2366028	0.77
193.0381927	0.47
195.0238953	0.61
197.3729248	3.94
198.9698944	0.31
201.0272217	0.23
203.2056274	0.59
205.7183533	0.56
207.1881714	0.21
209.1510315	1.47
211.023468	3.14
211.9766541	0.53
213.2037354	2.41
215.1238708	0.88
217.2088013	0.32
219.2567139	0.92
221.1460571	3.27
222.7553711	0.24
223.571167	0.71
225.1973572	3.00
227.2965698	2.55
229.2696533	0.47
231.4006042	0.38
233.2993469	1.50
235.0974121	2.59
237.0566711	1.22
238.7658997	3.66
240.1513062	0.95
247.3255005	1.74
249.3776245	0.51
250.1382446	0.41
251.164093	4.44
253.0499573	10.74
254.9962769	0.27
257.1664429	2.94
260.8875122	0.30
263.3467102	0.75
265.0300293	2.08
266.098053	1.17
270.010498	1.12
273.3156128	0.50
275.2683716	19.64
283.5462646	4.54
284.2641602	0.30
287.2388	1.22
290.7365112	0.74
293.2142944	100.00
302.4167786	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
532.8097534	20.59
850.4130249	3.75
966.4092407	52.57
967.4091797	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.07
Annotation	Unknow
Peak:m/z	Relative Intensity
170.6832123	0.20
175.2965088	0.25
180.7412567	0.12
184.8308105	0.10
186.8781128	1.51
195.0771179	0.08
196.8450012	0.08
198.9609375	0.46
201.0411835	0.58
203.3238220	0.58
204.6012268	0.40
216.9460144	2.81
223.9890900	0.21
225.1137695	0.80
226.9813843	0.70
228.9962006	0.08
230.8456116	0.09
234.8825684	0.54
236.9985504	0.40
242.8238373	0.09
244.9774780	1.50
247.1437073	0.10
248.7342224	0.16
252.9306183	0.15
254.9812164	0.14
268.1659546	0.08
269.0492554	0.52
270.0570068	0.20
270.9105530	0.37
274.9911804	0.14
276.9914551	23.48
281.1173401	0.28
282.6264648	0.30
288.2985229	0.52
288.9945679	3.25
294.8423462	0.48
299.2987671	0.28
300.7418518	0.44
301.9769287	0.52
303.1024780	2.31
305.0795898	0.59
307.0003357	37.97
311.3134155	0.12
319.0627441	6.93
321.0163574	0.12
322.6766968	0.24
324.8812256	1.29
328.8280640	0.56
331.0212402	0.37
336.3947754	2.25
337.0593262	8.56
342.9666748	0.66
346.4382935	0.99
347.2046509	0.13
349.0476685	1.12
354.4639893	0.51
355.0855713	1.26
361.1981812	1.08
364.1636353	0.09
365.1148682	0.33
367.0389404	33.28
373.0651855	3.79
378.9159546	1.07
380.2064819	0.19
382.0974731	1.49
383.5172119	0.16
389.2501831	0.37
391.0093384	18.78
396.9300537	20.37
397.9781494	0.59
407.1564331	0.54
409.0172119	74.65
409.6697998	0.17
415.0232544	0.41
424.8784180	0.81
425.9074097	4.85
427.0396118	100.00
427.6669312	0.09
433.2342529	0.29
485.6547852	0.12
489.2991333	0.18
490.3385620	0.56
498.0245361	0.15
499.1350708	0.38
529.5569458	0.22
534.3942261	0.38
544.2099609	6.06
545.0473633	2.16
552.6142578	0.31
569.5416870	0.12
571.0942993	5.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.01489258	0.42
97.03581238	2.44
102.7415161	0.79
106.8113251	1.04
108.903183	1.10
111.0149078	0.40
112.6850281	0.27
117.9661865	0.47
122.8241119	2.49
124.9439545	1.19
129.1940613	0.36
133.0414124	0.85
135.1703033	1.78
136.930542	0.20
137.8470001	0.54
138.9234009	2.22
142.9394531	2.40
149.1424866	0.85
151.6843872	0.31
153.0851746	0.99
155.1699219	0.89
156.8687439	0.51
159.0082245	0.47
161.0629578	0.21
162.8529663	0.57
169.0330353	1.69
177.1204529	1.29
179.2789307	0.93
181.0670471	3.00
182.0320435	0.66
183.0087585	1.28
185.0869751	7.30
189.0961609	0.56
191.1288452	0.33
192.0704803	1.30
193.4179993	1.98
195.1382446	1.67
196.643158	1.66
197.2686615	0.24
200.0365753	0.83
201.3665619	0.57
207.0236816	0.39
209.2023621	1.15
211.2317505	4.10
212.9928284	1.33
217.1671448	0.55
219.2602234	1.28
221.0705872	1.86
223.263031	1.58
224.8405457	2.83
226.2993469	0.18
227.4780579	0.71
229.1983948	1.00
235.2385864	0.84
237.3363953	0.37
239.14505	1.26
244.8713989	0.73
247.1281128	0.37
249.2673645	1.27
251.2944336	3.25
253.0665283	9.77
255.0955811	0.61
256.9866333	1.47
258.2305908	0.22
259.3947144	2.20
260.8806152	0.73
261.9857178	0.95
265.2457886	5.35
267.3134766	5.13
268.3833618	2.14
269.1592102	2.16
270.2970276	0.47
273.9956055	1.54
275.2491455	17.65
283.2030945	2.67
287.9658813	0.80
291.1922607	0.37
293.2110596	100.00
294.2186279	1.21
301.3200989	1.09
310.4441528	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0664
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0285492	0.14
171.2313843	0.16
173.1551819	0.07
174.9782410	0.34
180.8664703	0.05
183.0131226	0.17
185.0506592	0.27
186.9380035	0.50
194.9255829	0.05
198.9877319	1.38
200.9797974	0.97
204.9079895	0.35
208.1053162	0.25
209.0806122	0.21
211.0207520	0.50
212.1174316	0.14
215.2015686	0.14
215.9486694	0.07
216.9089355	1.47
223.1471100	0.05
225.0152283	0.63
226.7519226	0.63
230.8601990	0.28
233.0237427	0.07
234.8324280	1.26
236.9797363	0.29
240.9131012	0.21
243.1165466	0.32
244.9145966	2.50
246.0794983	0.30
247.0241089	0.13
253.0142212	0.17
254.8934937	0.48
257.9519043	0.07
258.6461182	0.09
259.9895020	0.15
260.9678345	0.20
262.3290405	0.05
264.9575500	0.21
266.9959412	0.22
268.9833374	0.09
271.0722046	0.38
272.9322510	0.13
274.1515808	0.10
274.9630737	0.55
277.0600586	25.26
280.8082886	0.08
283.3872070	0.06
284.9066467	0.04
287.8816223	0.13
288.9751587	3.36
292.9100037	0.13
293.7451782	0.04
294.9793701	0.55
296.9768066	0.05
298.8089294	0.04
300.6436768	0.42
303.0885620	2.94
305.0119629	0.59
306.3146362	3.82
307.0590210	40.49
311.1503296	0.12
313.0406494	0.05
318.9655151	9.97
321.0010986	0.52
325.0599976	0.33
327.1127930	0.13
328.8162842	0.92
330.9282837	1.62
334.8572998	0.15
336.8116455	12.33
343.0349121	1.67
344.1441040	0.55
346.9802246	2.84
349.0042725	1.55
354.9367065	0.92
361.0651245	1.47
363.9647217	0.11
365.0441895	0.49
366.9812622	33.96
371.4498291	0.05
373.0160522	3.32
377.4100952	0.69
378.4873657	2.07
379.2001343	1.50
382.1325684	2.85
383.3156738	0.15
391.0263672	23.04
395.9577637	1.67
397.0102539	23.48
398.1658936	0.63
407.8530884	1.88
409.1605225	67.73
412.5665283	0.09
414.9934082	0.12
425.4337769	1.92
426.9758911	100.00
427.6741943	0.21
440.0716553	0.12
442.3130493	0.16
455.3328857	0.17
456.3711548	0.70
457.1457520	0.42
467.2116699	0.07
468.9284668	0.44
475.2767334	0.07
481.1073608	0.18
481.9348145	0.25
494.0930176	0.22
499.0906372	1.83
503.9613647	0.04
522.2727051	0.14
529.0050659	0.22
535.2105713	0.09
544.0741577	9.15
545.0842896	1.82
568.6964722	0.37
570.0024414	0.89
571.1243286	6.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
96.95249176	0.25
102.7770386	0.16
104.9304504	0.40
106.9900208	0.25
109.0258484	2.21
116.9298019	0.12
118.7268829	0.72
120.8910141	3.02
123.0731888	0.53
125.2395172	0.55
126.9666748	0.46
129.0703888	0.31
133.1077576	0.17
135.0188293	4.30
137.2330627	0.08
140.8139038	0.48
142.9215851	2.25
145.0473328	0.56
146.9518433	3.05
148.9992065	3.05
151.0905914	0.48
152.1713257	0.19
152.9649658	0.10
157.0207367	1.11
159.1373138	0.81
160.9143524	1.58
162.0372009	0.31
163.1913147	0.87
164.9913177	0.63
166.7426453	0.21
168.9703064	1.31
171.2116089	0.81
172.9711456	2.40
175.0077972	2.54
176.9929504	0.40
179.1007843	0.61
183.0203552	0.61
185.0829773	0.50
187.0401459	1.53
188.3711853	0.51
189.1614685	0.43
190.7332916	1.06
193.0692444	0.69
195.1381226	0.26
198.9472961	0.13
201.1409607	1.02
203.071991	1.28
204.9761505	1.00
206.974884	0.97
209.2449036	0.27
210.9191895	1.71
212.937561	0.34
215.0937805	0.74
217.2834167	0.25
221.1210327	0.19
223.2469788	0.21
225.32901	0.26
227.0031433	0.25
228.3010864	0.25
229.3919983	0.91
231.1863403	0.37
233.2213745	0.15
235.2744141	0.43
237.9515686	0.22
239.0005188	0.69
239.9310303	0.15
241.1728516	0.53
242.5114441	0.75
245.2173767	0.89
247.2485352	6.66
249.1325378	0.42
251.1205444	0.26
253.5064697	0.62
255.1486511	1.04
256.8339233	0.12
259.1810913	0.26
259.9967041	0.33
267.1363525	1.92
270.3342285	0.16
271.1271973	0.71
277.1702271	0.66
278.1229248	0.22
281.2737427	2.81
282.2520752	0.94
283.1088867	1.28
285.3250732	0.36
286.8976135	0.22
293.2333984	1.07
295.1079712	1.56
295.7311401	0.43
297.1209717	0.65
298.1895752	0.27
299.2577515	1.80
300.1538086	1.03
301.1860352	0.15
303.0231934	0.28
304.2846069	0.68
305.297821	2.76
306.2606812	0.34
311.2930908	0.08
313.2683105	0.78
317.8652344	0.24
319.1119995	0.24
323.2463684	100.00
324.3103943	0.92
325.3665161	0.31
331.7997131	0.96
332.4598389	0.42
340.634552	0.23
341.2690125	0.71
344.4892273	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
142.8253326	0.02
179.0611725	0.13
341.1829224	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.1296
Annotation	Unknow
Peak:m/z	Relative Intensity
122.0292358	0.03
123.0986481	0.04
124.7762451	0.03
151.1146698	0.01
166.9781647	0.01
177.0273285	0.02
183.0599060	0.20
194.1958466	0.01
196.9651794	0.02
198.3642578	0.01
201.3447571	0.01
208.1433105	0.01
213.0178375	0.03
219.0452576	0.01
223.0424500	0.05
224.0791931	0.04
233.2984924	0.02
245.1788025	0.01
252.0447998	0.02
253.0462646	0.01
253.7608337	0.04
254.9549255	0.01
257.3125610	0.01
259.3423462	0.01
262.8461609	0.02
271.1682739	0.01
277.6358643	0.04
279.2388611	0.08
283.3509216	0.01
285.1524353	0.01
287.2386780	0.06
288.9083252	0.07
291.1458740	0.02
297.1861572	0.01
298.2526855	0.05
299.2052002	0.21
301.2326660	0.59
302.2114563	0.06
303.1478882	0.04
303.9891357	0.04
308.1575012	0.03
309.1459351	0.02
310.2043457	0.03
316.3994446	0.02
317.2271729	0.03
327.1911926	100.00
328.2241211	0.10
333.6488647	0.01
345.2049866	5.26
347.2115173	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	205.09
Annotation	Ethyl trans-p-methoxycinnamate
Peak:m/z	Relative Intensity
92.8772430	0.02
106.0104828	0.77
143.1767731	0.02
146.2033844	0.01
150.1125488	0.41
157.0639038	0.08
161.0154572	100.00
187.0949097	0.18
204.9000397	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2709
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1503754	0.03
243.1263275	0.07
263.4166870	0.11
289.9766235	0.13
305.0861816	0.08
311.1724854	0.19
313.2879639	0.08
321.1191406	0.10
332.2693481	0.14
335.1954346	0.04
343.2871094	0.24
349.0349731	0.21
351.0748291	0.37
359.3640747	0.15
372.1772461	0.03
373.2578125	0.85
385.2809448	0.27
387.1565552	0.15
388.5425415	0.12
389.2074585	0.66
399.1599731	0.18
401.1686401	0.04
403.4000854	0.05
404.4757080	0.07
405.1968384	0.04
429.9460449	0.05
435.1955566	0.32
453.7449341	0.04
455.1388550	0.11
461.0055542	0.10
477.8126221	0.04
487.1803589	0.08
493.5006104	0.18
505.3247681	100.00
505.9266968	0.43
507.2327271	0.12
515.0926514	0.08
518.8513794	0.09
530.7487183	0.15
531.4124756	0.07
533.4194946	0.17
552.5045776	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.6909790	7.74
273.0547180	0.09
291.0475159	0.52
296.8021851	72.78
302.8758850	2.00
345.0135803	0.42
353.0565186	0.38
357.0199585	0.53
359.2644043	0.44
374.7400818	0.13
378.1985168	1.00
380.1209717	11.51
380.7622986	100.00
416.7946777	0.27
419.1317139	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1968
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
241.1520081	0.02
245.1803131	0.03
247.231842	0.02
269.1156921	0.05
270.1838684	0.02
282.9929504	0.02
287.0957031	0.09
299.1691284	0.06
301.982666	0.02
313.2676697	0.01
314.0651855	0.02
331.4730835	0.04
395.1468506	0.01
405.361145	0.02
407.328064	0.23
413.1831665	0.02
417.4381104	0.02
424.4945679	0.03
425.2873535	0.02
447.3199463	0.02
451.2922363	0.02
525.2992554	0.03
543.5669556	0.02
555.7055054	0.06
558.4632568	0.02
569.1655884	0.03
575.3981934	0.11
577.1184692	0.03
578.416626	0.02
587.2952271	0.04
626.9778442	0.02
629.383667	0.03
643.2529907	0.04
677.3098755	0.09
694.1824341	0.04
695.1569214	0.27
698.3561401	0.08
702.3164673	0.04
711.7954102	0.03
713.3363647	0.01
720.2965698	0.07
720.9737549	0.07
725.244873	0.06
726.0462036	0.01
738.0448608	0.02
779.71698	0.06
788.0249634	0.04
847.5831909	0.05
865.2005005	100.00
865.8579102	0.77
866.6751709	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.4319
Annotation	Trungapeptin B
Peak:m/z	Relative Intensity
206.8737946	3.39
279.2940674	5.31
293.2771606	7.31
392.1573486	1.77
430.6218872	3.95
443.1504517	5.65
456.5802002	1.69
461.3303833	14.33
554.3585205	2.28
650.6375122	1.12
679.112854	10.76
705.4484253	4.22
706.4408569	3.39
723.4301147	100.00
724.5150757	16.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1138
Annotation	Robustaside B
Peak:m/z	Relative Intensity
150.9569397	0.93
154.9314575	0.05
161.1205902	0.07
174.8811951	0.04
177.0079803	0.19
193.1801758	0.07
199.2044983	0.29
207.0611877	0.25
209.3679199	0.06
215.1923370	0.09
224.1424103	0.09
245.4266968	0.07
251.0786743	0.08
252.0334167	0.05
253.1608276	0.16
254.9948425	0.21
265.1169739	0.38
267.2675171	0.16
269.7980347	0.14
271.0773621	100.00
295.1460571	1.15
301.1163025	0.18
311.1698914	0.12
313.0162048	0.42
317.1577759	2.21
319.2251587	0.34
320.0639343	0.10
323.1519165	0.06
325.0806885	0.24
327.2816772	0.04
331.1667480	0.06
333.3330688	0.10
337.1114502	0.14
341.1386108	0.09
344.1541138	0.04
345.0728760	0.11
349.0485229	0.25
351.4783020	0.06
359.2942505	0.26
368.1000061	0.14
368.7293091	0.11
369.5505981	0.12
373.1835938	0.08
379.1618958	0.10
385.2986755	0.10
386.2148132	0.11
387.2745667	1.42
389.2215881	0.54
391.1784668	0.10
393.1333008	0.06
405.6517334	0.03
412.7921448	0.32
413.5130005	0.17
415.1397705	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.2424
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
133.1359558	1.16
161.0197144	4.14
169.3309631	0.83
179.0623474	11.63
189.2250671	1.51
197.0429382	19.73
214.9798584	100.00
229.0412903	0.50
243.7501831	0.54
274.2676392	0.63
283.1772461	0.92
303.9918213	0.66
321.0964050	0.59
323.2201538	0.62
330.1258545	0.62
347.8594971	1.84
363.7859497	1.57
370.7849426	3.46
375.2427063	1.32
376.5281982	16.54
377.1498718	3.64
379.4544678	3.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	286.0913
Annotation	Buchananine
Peak:m/z	Relative Intensity
81.2935638	0.01
84.8170700	0.01
93.0472412	0.01
96.9140930	0.05
98.9331284	0.09
105.9891663	0.24
108.9398651	0.29
115.9820251	0.01
121.0537872	0.02
123.9054718	100.00
124.8625031	0.07
126.9518280	0.56
133.0918579	0.02
143.0505371	0.01
144.9234314	0.11
147.0633545	0.02
147.8572693	0.03
155.3370209	0.01
156.1850128	0.01
161.0827942	0.04
162.3314362	0.02
163.0341797	0.01
165.9157562	0.02
169.0362091	0.02
174.9992371	0.03
176.0711670	0.01
178.2062988	0.02
179.9674225	0.02
181.8494720	0.02
183.1839905	0.02
184.1517029	0.02
189.0294037	0.04
190.0023346	0.01
192.9086151	0.01
196.5307312	0.02
197.2127380	0.02
198.0328064	0.03
201.8511963	0.02
206.8678284	0.01
208.2272644	0.04
223.9446716	0.02
225.1856079	0.03
229.0994263	0.01
232.0852661	0.03
236.7582397	0.01
239.0060120	0.01
240.0537720	0.01
243.0938721	0.11
244.3650513	0.10
250.1226196	3.58
256.0591431	0.03
261.6637573	0.01
268.0646973	2.78
269.2491455	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1507
Annotation	Gerfelin
Peak:m/z	Relative Intensity
164.2259521	0.25
165.2981110	0.14
173.0476685	0.36
175.0713501	0.27
179.0058594	0.86
183.1491699	0.05
185.2008514	0.12
187.1658630	0.18
188.1114502	0.09
199.0654297	0.09
200.0620270	0.13
203.0958862	1.44
204.9826050	1.29
206.2289734	0.55
211.1890106	0.15
220.9597626	0.38
223.1228027	0.13
227.2530212	0.54
230.1363068	0.13
230.9479980	0.11
231.7460022	0.07
232.3745422	0.06
242.1589661	0.05
245.1220398	5.77
246.2865448	0.60
247.1062317	1.03
270.7692871	0.13
272.1017456	0.08
272.9544067	0.14
275.2863159	0.14
287.2932129	0.10
289.0551758	100.00
290.1257324	2.92
291.2703857	0.76
292.2629700	0.13
299.3052979	0.20
300.3339844	0.16
301.4533081	0.09
303.4030151	0.11
312.8006897	0.30
323.2345581	0.20
325.2874756	0.12
331.1703491	1.57
332.4245605	0.47
333.1760864	0.27
341.3746338	0.44
342.8001099	0.20
352.5831299	0.05
357.1447144	0.08
383.4553833	0.55
384.3444824	0.03
387.9174194	0.18
388.8873291	0.07
397.5440674	0.28
401.4011841	0.47
402.4733276	0.20
403.1958618	0.40
404.3262329	0.08
407.2511597	1.04
408.2728271	2.85
409.3964233	3.76
410.2606812	0.41
417.4664307	0.84
423.2659912	0.44
425.1690674	1.55
426.2694702	3.52
427.2203979	7.58
428.2255859	0.34
435.1498413	0.20
436.3199463	0.21
451.3079224	3.71
452.1182861	0.42
453.3012695	1.81
454.5153809	0.43
469.2969971	6.07
470.3045654	0.86
477.2039185	0.12
489.7551270	0.21
492.6181030	0.28
533.1281738	0.59
535.2800903	1.01
536.7328491	0.25
541.3295288	0.33
543.3727417	0.58
550.6347046	0.08
559.4044800	0.07
561.2934570	3.19
562.2975464	0.85
581.4193726	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.18
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9694519	0.15
174.9333344	0.54
176.9479065	0.17
181.0758057	0.11
184.8055420	0.04
195.1961975	0.06
215.2508545	0.23
231.9790039	0.06
241.5881348	0.10
254.5736389	0.04
257.1701050	0.21
260.9552917	0.09
281.0235596	0.07
283.2797241	0.45
284.1277771	0.09
287.1288452	0.08
299.8822021	0.11
301.1034546	0.44
316.9453430	0.05
323.2358704	0.03
324.1878052	0.15
327.1432800	0.85
329.3120117	0.07
337.2681885	0.12
339.2890930	0.19
343.2868042	23.69
344.0589600	0.05
345.2162781	0.45
353.4959106	0.18
355.1735840	0.03
365.5568237	0.10
373.2225647	0.27
377.1809998	0.28
391.4375305	0.06
394.1385498	0.20
395.4672852	0.02
401.3062744	0.05
417.1879272	100.00
417.8445129	0.26
419.2753296	1.11
421.4767761	0.03
427.3646240	0.16
432.0242920	0.07
433.4930115	0.26
439.7409668	0.08
442.2854309	0.04
444.2107544	0.11
445.4260254	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	Abu-TyrMe-OH
Peak:m/z	Relative Intensity
119.9047699	0.35
166.1704559	0.22
180.9304047	0.50
191.1902466	0.28
209.0653076	0.05
253.3291321	0.29
254.965271	0.06
325.0332642	0.08
336.34375	0.13
341.1411133	13.42
342.3800659	11.74
343.1322021	100.00
371.1240234	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1396
Annotation	4-Hydroxy-3-prenylbenzoic acid glucoside
Peak:m/z	Relative Intensity
114.7840881	0.10
118.9299164	0.08
121.0140991	0.10
122.0056534	0.07
124.8464890	0.06
135.0823059	0.04
146.5675049	0.14
147.9610443	32.94
156.0364990	0.17
159.1398926	0.05
161.1371765	0.23
163.0495148	100.00
170.1754303	0.16
174.1594849	0.10
179.0175323	0.05
181.0831909	0.14
186.9010468	0.20
189.3892517	0.16
191.0834808	0.09
202.8414612	0.54
204.9701385	2.15
219.2301941	0.37
237.0908203	0.10
239.1448975	0.14
247.1110535	2.28
257.4341431	0.15
263.2223816	0.24
267.4268494	0.21
270.2052002	0.04
271.9929810	0.36
273.1983643	0.09
276.0168762	0.18
277.2022705	1.57
279.1871948	0.05
283.1973267	0.14
284.1841125	0.21
290.8843689	0.05
294.1329956	0.13
295.1226196	0.09
302.8496704	0.04
307.2090454	3.87
309.4071045	0.25
318.2074585	0.07
319.9284363	0.04
321.3512573	1.04
322.3562317	0.13
323.0341187	0.27
330.1693115	0.13
331.2549438	0.33
337.1095581	0.04
338.8947754	0.08
347.3823547	0.51
348.2195740	0.65
349.2275391	1.66
350.3133240	0.06
351.2705078	0.08
357.5835876	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.19
Annotation	Celorbicol
Peak:m/z	Relative Intensity
83.05387878	4.81
107.0570679	4.04
113.7126465	3.58
127.1716766	4.52
128.890152	4.94
154.9716644	2.67
158.2232513	12.65
159.1609344	2.17
169.9499207	6.60
170.9692841	4.33
183.193924	5.76
186.2161713	2.16
196.6725922	19.09
199.9451447	2.93
201.1703033	4.95
205.187973	4.59
207.0073395	12.60
211.0389099	9.61
212.871933	2.36
215.3745728	2.54
225.466568	2.73
229.0188141	3.22
235.3557129	3.62
253.1699066	100.00
254.4274292	5.12
261.7217407	6.43
271.2139282	8.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2451
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8316803	0.18
203.1693115	0.09
205.2544556	0.89
214.9191284	0.19
221.0873413	0.53
246.1798401	0.12
255.0509949	0.08
256.3585815	0.16
260.1261597	0.22
267.3292236	0.04
269.2117310	0.13
271.0855408	0.04
273.2123108	0.13
283.1853638	0.17
285.2747803	0.87
286.1144409	0.14
287.1741333	0.18
289.2374878	0.56
289.8395386	0.05
301.3325195	0.09
305.1538696	0.06
310.1006775	0.18
315.2057495	0.82
323.2232666	0.93
329.3786011	0.06
330.2102661	0.13
331.0599976	0.23
341.1808472	0.07
379.3027954	0.29
383.0867310	0.10
385.2764893	0.16
387.1159058	0.11
390.3186646	0.15
403.2438354	0.82
408.4152222	0.72
409.2806396	0.17
412.1170044	0.24
422.7050781	0.21
423.3610229	0.14
427.4534912	0.27
431.2805176	0.06
439.1043701	0.55
440.1597290	1.56
441.2108154	3.14
442.3030396	0.06
445.4444580	0.08
449.0353394	0.56
450.3877563	0.08
451.3777466	0.10
454.1095581	0.17
454.9967041	0.28
463.0552979	0.29
464.6500854	0.06
465.3266602	0.14
466.1676636	0.42
467.2528076	0.08
470.0848999	0.05
483.2210693	0.09
489.2272339	0.17
497.3878784	0.14
499.0648804	0.08
506.1325073	0.23
515.7450562	0.32
516.8588257	0.15
520.9754028	0.08
529.8976440	0.20
531.0369873	0.32
538.3327637	0.27
547.2810669	100.00
547.9193726	0.30
556.1754761	0.23
557.4563599	0.11
559.6179810	0.08
564.3404541	0.23
571.4299927	0.07
575.1899414	0.44
593.3668823	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8749
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9118958	0.11
171.0714417	0.04
174.9142303	2.32
214.8753662	0.05
229.0546112	0.10
244.8846741	0.08
260.9191284	0.04
273.0467529	4.12
273.9995728	0.21
287.9639282	0.03
289.0125732	14.68
301.8880615	0.06
303.9248047	0.13
304.9859009	13.11
348.2639160	0.03
386.9411011	5.84
387.9945679	1.61
388.9393311	0.03
403.0280762	8.54
416.9830322	0.03
418.8811035	100.00
419.5128174	0.45
443.0529785	0.10
444.3967285	0.04
457.1142578	0.04
486.1716919	1.09
487.0198364	0.04
487.7659302	0.02
489.0422974	0.11
503.3874512	0.07
505.1441650	0.34
514.0462036	0.34
521.1485596	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.26
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
407.6560364	0.11
557.3598633	0.14
575.1571045	0.03
695.3158569	0.04
739.236084	0.10
845.2231445	0.16
982.744873	0.04
1068.004883	0.09
1090.410156	0.15
1117.386719	0.08
1135.368408	0.06
1152.51062	13.53
1153.26709	100.00
1159.134033	0.15
1164.34021	0.09
1994.042847	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1718
Annotation	Rhododendroketoside
Peak:m/z	Relative Intensity
130.8914948	1.01
143.0794220	0.52
148.9712219	4.32
160.8799286	0.33
170.9012451	0.07
172.9949036	0.52
175.0521240	0.06
189.9507751	0.13
190.9638367	4.09
191.8508301	0.02
221.0149689	0.22
231.6840820	0.16
233.0982666	13.82
234.0982666	0.25
245.1272278	0.05
248.1557922	0.06
275.0236206	0.27
293.0951233	100.00
294.0422974	1.37
295.1291504	0.04
315.2741699	0.05
326.0225830	0.06
341.2400513	0.39
345.0855713	0.09
351.3398438	0.06
361.3565063	0.29
368.6373291	0.03
399.0932922	0.07
408.2804260	0.07
411.1643066	0.17
412.1543579	0.14
414.4123230	0.27
430.4474792	0.08
439.5111389	0.33
440.4745178	0.20
441.4655762	0.37
443.6622925	0.25
459.5135803	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
105.0365906	0.16
107.0016327	3.35
109.0409012	1.05
110.9945679	0.50
113.2049637	0.26
116.8659744	0.46
118.9247665	0.56
120.9194946	3.67
122.7502441	0.75
128.8757935	0.48
130.989563	1.75
133.1488953	0.63
134.9399109	2.94
137.0177612	1.27
140.9332581	0.24
143.063324	2.10
144.9728699	0.99
146.0555115	0.40
146.9527588	0.24
149.0714417	3.06
151.188385	0.53
152.0926514	0.35
153.1627197	1.23
155.0661011	0.71
157.0397949	4.30
158.7926331	2.88
161.1752777	0.95
163.0810242	1.19
165.121521	3.26
167.0825806	3.43
169.0127106	4.62
171.1169128	1.49
173.0000305	10.26
175.2053528	0.91
177.0760956	0.64
181.3023682	0.17
182.9099121	2.23
185.0484619	1.27
187.1849365	4.40
188.9352722	0.96
191.089798	0.41
192.8895721	2.32
195.0166626	0.14
196.0404358	0.23
197.0688629	0.82
198.8538055	0.18
200.984375	0.26
205.2152557	2.32
207.141861	0.59
209.0924377	1.03
210.976593	2.52
214.9961548	3.02
216.1883545	0.52
221.3709106	0.22
222.0690308	0.37
223.334137	2.24
227.2368164	1.58
228.1368713	3.87
229.0618896	8.51
230.1351624	0.35
231.2765808	1.84
233.1763306	3.11
235.3461609	0.32
237.0285339	1.04
239.2518005	0.51
241.0092163	0.16
243.0604553	2.11
245.0053406	2.75
247.0539551	10.42
249.3984375	0.48
250.5779724	0.74
251.5372314	0.60
252.2074585	0.27
253.2427673	0.31
255.0869446	0.14
256.0646973	0.29
259.371521	1.29
262.4771118	0.33
263.5834961	0.98
265.125885	3.49
266.1317749	0.26
267.1245117	0.95
269.1528625	0.26
270.3110352	0.35
271.5645447	0.76
273.7555847	0.48
281.0449219	0.65
287.2976685	1.82
294.2415771	0.27
295.3464355	0.84
296.3792114	0.42
297.0471802	0.51
299.2285156	4.76
300.6589966	1.02
303.5795898	0.21
305.3245239	5.28
306.3193665	1.05
309.3213806	0.46
310.8099976	0.99
312.3927917	0.21
313.3834839	2.94
321.4646301	0.23
323.230957	100.00
324.1948547	1.62
325.1946106	0.18
327.2286682	0.18
331.2681885	0.20
341.2695007	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	364.96
Annotation	Unknow
Peak:m/z	Relative Intensity
132.1121368	0.08
171.0916748	0.06
176.8758240	0.05
182.8137665	0.06
193.1318665	0.17
194.1415405	0.11
194.9338531	0.05
195.9203033	0.04
210.8793030	0.04
214.9058228	20.74
229.1217041	0.36
232.8835754	100.00
245.1254883	0.06
248.3415527	0.05
266.3525085	0.35
267.0827637	0.87
302.5083008	0.04
305.1228333	0.05
318.0026550	0.12
321.4064941	0.18
323.3120117	0.04
329.1132507	0.15
346.0470581	0.05
347.1279602	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1503
Annotation	[3R-(3alpha,3aalpha,4beta,5alpha,6aalpha)]-3-[(beta-D-Gulucopyranosyloxy)methyl]hexsahydro-4-(hydroxymethyl)-5-methyl-2H-cyclopenta[b]furan-2-one
Peak:m/z	Relative Intensity
113.0609894	0.05
137.1063232	0.27
155.0260315	16.94
161.0394440	0.10
169.2031250	0.10
181.1163940	0.13
194.9604950	0.02
199.0484619	100.00
201.3309784	0.09
213.1837769	0.05
232.9502258	0.05
241.0833435	1.33
242.0651245	0.07
271.0600891	0.26
273.2623596	0.21
299.3241577	0.07
301.0785522	0.52
307.3426819	0.03
316.9695740	0.04
319.3174133	0.06
343.2912903	0.20
344.3396301	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.12
Annotation	(2R,3R)-Taxifolin 3-glucoside
Peak:m/z	Relative Intensity
134.9438629	0.09
136.9214172	5.39
160.2229309	0.14
164.7263489	0.86
194.7502136	0.18
200.9751282	0.43
212.1282349	0.32
215.1017761	0.65
241.1043701	0.26
256.4139404	0.20
259.08078	0.09
272.2474976	1.27
272.8816223	0.32
277.1116333	0.94
286.0245361	0.27
287.0775452	9.18
287.8272705	0.79
292.9438782	0.20
302.395813	0.52
303.2963562	1.12
305.068512	100.00
309.6435242	1.20
310.9944458	0.19
313.1517334	0.11
321.1418152	0.63
326.0055542	0.08
328.9902344	1.92
347.027832	5.76
350.3930969	0.80
353.3033752	1.66
370.9724121	1.12
376.6367493	0.51
379.4018555	0.79
383.3474121	0.63
389.2062073	0.34
391.3410645	0.97
392.5439758	0.15
395.5479736	0.23
401.2084656	0.33
413.1394958	1.42
420.9804688	0.17
426.2962646	0.46
431.1387634	6.35
435.2327576	0.14
437.0247192	0.14
443.83078	0.99
446.9567566	0.62
448.2151184	2.84
449.2076721	50.43
449.8519592	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.8
Annotation	Unknow
Peak:m/z	Relative Intensity
190.9315796	0.16
192.7849884	0.23
206.7711792	0.25
234.9842224	0.13
237.2743835	0.14
269.1443176	0.10
280.2113037	0.10
290.7955933	1.83
298.2433472	0.16
318.0644531	0.11
371.1549072	0.14
374.6166992	0.20
397.2912598	0.27
413.9765625	0.22
415.1203003	48.03
416.2189941	4.93
421.1563721	0.23
424.8361206	0.21
425.8244629	0.74
427.2877808	0.83
433.0811157	0.57
442.6363525	0.27
484.6386719	0.23
500.9188843	0.33
508.3032227	0.10
510.1165161	0.93
510.9185181	1.45
530.9357300	100.00
534.9004517	0.11
546.8900146	0.64
548.2335815	6.53
548.9421997	3.31
550.2016602	0.22
553.0370483	0.17
566.5759888	0.21
576.6226807	60.16
577.2905273	1.09
594.6345825	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.9749451	0.09
126.8621216	0.12
134.9837952	7.86
136.9470520	0.05
142.9319611	0.10
154.7895813	0.11
161.0762939	0.66
171.0313110	0.23
172.9205627	2.82
173.5435791	0.09
178.9519806	37.15
191.0119781	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
813.6796265	13.51
866.4182129	2.84
948.6118164	6.96
967.4243774	100.00
968.0819702	3.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1038
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
135.0011749	0.17
148.9003296	0.49
152.0046387	0.10
160.9738312	0.65
162.9607239	0.02
165.0589752	0.48
167.0127716	1.73
170.7742615	0.06
173.1035919	0.05
175.0676880	0.57
175.9437866	0.09
177.0913391	0.44
179.0119629	0.07
182.2081299	0.07
189.0173035	0.04
191.1163940	0.05
192.4129639	0.38
193.1672058	0.32
195.1476440	0.02
197.0514221	0.48
198.2608032	0.37
199.0998535	2.73
200.1031647	0.06
201.0007629	0.80
213.0417633	0.26
215.3269958	0.07
216.5046082	0.14
217.2251892	1.62
219.0624084	0.26
223.1065369	0.59
226.0173950	0.21
231.4036713	0.02
232.9134216	0.06
234.9744568	0.16
241.0349579	21.28
242.0741272	0.14
243.0850525	2.12
257.0587769	0.09
258.0927429	0.07
259.2790222	0.76
265.0911865	0.04
267.0959473	0.70
271.4133911	0.05
273.3401184	0.09
275.0359802	0.49
279.1450806	0.08
281.4955444	0.04
285.0777283	100.00
301.0074768	0.04
303.1061096	31.15
307.0589600	0.04
327.1658936	0.07
329.2499084	6.37
333.2743835	0.05
339.1291504	10.06
341.1466064	0.07
346.1560059	0.06
349.1593018	0.02
355.2232666	4.78
357.4221802	0.04
397.1044006	0.08
418.0262756	0.85
419.1340332	0.40
421.3097839	0.78
429.2713928	0.11
447.3612671	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9262695	3.97
208.9197083	3.09
212.9905701	0.11
290.7358398	23.18
292.6953735	29.23
293.4367065	0.07
297.0602417	0.15
316.9606934	0.03
336.6414795	0.14
341.1023560	0.06
370.8253174	0.20
374.6718140	4.49
375.6971436	0.36
376.5368652	9.83
377.1637573	0.98
378.7984619	0.21
382.0314331	0.09
388.8031006	0.04
399.1926880	0.08
400.0499878	0.07
400.7642822	0.56
406.6064453	0.06
408.5338135	0.15
424.4490356	0.53
425.2244263	0.12
436.4932861	0.31
438.7301025	0.44
450.7962036	0.09
458.6461182	20.95
459.9356689	18.43
460.7633057	100.00
468.9382935	0.05
480.2542114	0.17
480.8875122	0.45
483.1964722	0.20
484.5819702	2.87
498.8682861	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	237.0405
Annotation	6,8-Dihydroxy-5,7-dimethoxycoumarin
Peak:m/z	Relative Intensity
70.8475418	0.13
75.0340195	0.40
76.9713287	0.29
109.1313477	0.18
110.8760986	0.45
113.0606842	0.20
114.9300385	3.79
120.9886475	100.00
122.1194153	0.10
137.2526550	0.07
146.9669952	0.08
156.8295288	0.18
158.9530029	0.18
161.9088135	0.08
162.8519745	0.79
168.9219208	0.15
175.1487427	0.40
177.2312012	0.26
180.1372528	0.08
191.1625671	0.50
192.0941315	0.10
193.1575317	5.21
195.0475769	0.11
204.9667969	0.06
207.1298065	0.07
209.2199249	0.42
217.0046844	0.06
218.4531708	0.11
219.1614227	0.59
220.9296112	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.1805
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1777039	0.19
141.2197876	0.24
145.1674500	0.36
146.1132507	0.14
146.7810822	0.07
151.2958221	0.06
183.9098358	0.22
194.9204712	0.14
226.9744110	0.15
232.8292236	0.09
247.2077332	0.06
262.9892578	0.04
268.0854187	0.12
287.2836914	0.12
293.4896851	0.09
299.1296997	0.33
307.2042542	1.60
308.2317505	0.24
315.2284241	0.25
317.0925903	0.21
319.9038391	0.12
325.1917419	8.44
327.3090210	0.43
331.3458252	3.15
340.2495117	0.32
348.6735840	1.05
349.2820740	13.82
359.3805542	0.19
360.3030396	0.25
364.0447388	0.70
372.5549011	0.46
378.7806091	0.30
386.6846619	0.05
389.1687927	1.11
391.4390564	0.17
395.1835632	0.13
397.5394592	0.44
407.1149292	1.78
409.3980408	0.38
410.4012756	0.60
411.2181702	0.05
415.2552795	11.02
417.9846191	0.17
422.9802551	0.76
424.3617859	0.08
428.2916260	0.16
433.1697693	40.12
436.4733276	0.19
439.3377380	0.14
441.5627136	0.26
449.1358948	0.43
451.1950378	100.00
453.3401489	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.1566
Annotation	Sibiricose A3
Peak:m/z	Relative Intensity
159.3306122	0.09
178.9220886	0.10
191.0657654	0.09
221.0463867	0.48
226.1604309	0.18
231.0566254	0.11
262.7884827	0.05
323.1538696	11.43
328.3374939	0.12
337.3612061	0.07
349.7160034	0.22
357.2678223	0.03
426.3005981	0.36
441.6897888	0.24
456.1093445	100.00
456.8494873	0.45
474.6340027	0.23
484.0686646	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2495
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
100.8419342	0.08
104.9799957	0.37
106.8900375	1.01
108.9963074	1.25
110.9402466	1.08
116.7602692	0.26
118.9824371	0.20
120.9777374	1.99
122.9975815	1.47
125.0121765	0.15
125.8513184	0.05
127.0252075	0.11
129.0329895	0.47
131.0937958	0.30
132.9177551	0.39
135.0254211	3.11
136.9029694	1.10
139.1777344	0.07
142.9281158	1.54
144.8553925	0.23
147.0048523	2.53
148.9645538	2.83
151.2161713	0.51
152.9950867	0.26
155.0198669	0.31
156.8521118	0.68
158.8755798	0.72
161.0640259	1.35
163.0559998	0.75
165.0220947	0.32
166.9979858	0.13
168.9687805	0.50
171.0618286	0.72
172.9380798	1.34
175.0648193	1.67
177.0431976	0.19
179.0732727	0.19
180.7093506	0.05
182.8788757	0.85
184.9506683	0.19
187.185257	0.40
189.0525513	0.53
191.2090454	0.66
192.9413147	0.49
195.2250519	0.25
199.119873	0.06
201.2152557	0.14
203.0763245	1.15
205.2618408	0.64
207.1429749	0.31
209.0409546	0.22
211.1863098	0.44
213.1446838	0.26
215.0084229	0.09
217.0102539	1.89
219.4064941	0.20
221.8280029	0.06
223.2162476	0.55
225.2287598	0.54
228.1604309	0.07
229.1178589	0.24
231.1904602	1.52
235.9839172	0.04
237.3708496	0.30
239.2713928	0.23
241.1321411	0.26
242.3008423	0.18
243.1907654	0.39
245.3110962	1.77
247.1880188	3.72
251.1645203	0.32
253.2367249	1.04
255.0415649	0.67
255.6670532	0.19
257.2217407	0.70
259.3122864	0.54
262.3112183	0.38
264.8926392	0.20
265.5947876	0.25
267.1775513	0.66
268.0213013	0.17
270.0355225	0.16
271.3416138	0.27
273.0952148	0.14
277.2697144	0.58
279.2807312	0.10
281.2192993	0.69
283.4017944	0.50
285.20578	0.71
288.4060669	0.09
291.7202148	0.08
292.375946	0.05
295.2321777	1.03
296.4686279	0.33
297.1932373	0.26
298.1821899	0.08
299.2545471	1.38
305.2301331	3.25
306.0983276	0.15
313.3444824	0.59
323.2384033	100.00
324.0108032	0.72
324.6921387	0.10
332.7770996	0.10
335.6766357	0.07
341.2168884	1.03
342.3392029	0.18
346.1338196	0.03
354.3319397	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.03
Annotation	Unknow
Peak:m/z	Relative Intensity
148.7006836	1.01
165.9998779	0.40
215.9114075	0.69
233.1823120	0.42
233.9659119	1.81
239.9326477	0.42
242.1573486	0.61
250.5917664	0.53
252.1441040	0.67
265.0324097	0.35
269.6611328	0.28
274.0985718	0.13
276.0359802	100.00
282.9470825	0.26
287.9948120	1.53
291.3472900	0.73
292.9823608	0.17
293.8006897	0.31
301.9581909	0.98
306.0491943	36.00
306.9428406	1.18
308.0400391	0.67
319.0835571	0.74
330.1223145	1.01
335.4674072	0.61
336.2716675	0.99
339.1367493	0.24
342.1996155	0.57
350.9266357	0.51
360.0363464	2.01
366.0499573	2.78
375.1407776	0.26
377.9606323	7.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
910.7307129	10.33
966.6240845	28.62
967.4243774	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1668
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1133881	0.41
160.9572754	0.81
168.8685608	0.06
171.2127075	0.04
175.0236969	0.56
178.9736328	0.05
185.4409485	0.06
187.1993713	0.23
189.0920563	3.43
196.1483765	0.31
199.0444031	0.09
203.1427307	3.32
210.9908752	0.06
229.4933014	0.14
230.9755096	0.14
240.3437805	0.16
243.1730042	0.11
253.2218018	0.07
277.0016479	0.13
285.0055237	0.14
285.8805847	0.27
287.1543274	0.37
293.1466980	0.10
295.1737976	0.08
303.2368164	0.10
305.2505188	14.77
310.2115479	0.14
312.1715698	0.12
319.3143311	0.21
321.2538452	0.19
323.1644287	100.00
326.9169922	0.08
331.0601196	0.12
334.1390991	0.06
339.4039001	0.14
341.1831360	0.17
347.1804504	0.21
348.1860046	0.05
351.3847656	0.10
365.1498108	10.50
371.3175964	0.13
372.2389832	0.19
373.3913574	0.65
374.1974792	0.16
375.9704285	0.04
377.2185669	0.14
381.2656555	0.32
389.4352722	0.07
391.2366028	0.48
393.1707764	0.19
395.2440491	0.14
403.1761780	0.17
405.3102417	2.51
407.3190002	1.14
408.1172791	0.10
412.8954468	0.12
420.2790833	3.01
421.3437195	1.75
423.2725525	0.16
436.0341187	0.06
447.1525574	0.23
448.7147522	0.53
449.4635925	0.22
453.1979065	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	462.1591
Annotation	4-(2-Nitroethyl)phenyl primeveroside
Peak:m/z	Relative Intensity
133.1414795	0.66
133.9629669	0.28
138.0188751	6.15
144.9589081	0.48
162.9681396	0.66
169.9732361	0.31
179.9989319	1.06
184.2921448	0.08
186.1300964	0.10
187.0359497	0.22
190.5441284	0.09
204.0213318	0.13
204.9140320	0.32
216.0404510	0.35
222.3092194	0.31
222.9325256	0.14
228.1384583	0.24
234.0824585	0.23
243.4451294	0.24
246.0418396	0.82
255.0673828	0.19
264.1453857	10.00
271.2695312	0.07
281.1940002	0.13
282.0118713	1.93
283.3172913	0.23
288.8450623	0.49
293.2498779	0.45
300.1259766	12.77
305.9121094	0.36
307.1678772	0.34
317.5155029	0.05
318.1210327	0.63
325.0069580	0.90
331.3995361	0.33
332.7517395	0.14
334.2059326	0.25
340.0974121	0.18
341.3352051	0.16
343.0002441	0.17
354.0734863	0.22
359.0452271	0.13
381.0455627	0.58
387.4472046	0.33
402.3773193	0.56
415.2095947	0.25
417.4237366	0.13
420.8662109	0.53
426.2044983	8.11
428.1650696	0.16
434.3797913	0.24
436.6639709	0.19
438.2664490	0.37
444.2116394	100.00
452.8023071	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	492.1355
Annotation	Glyburide
Peak:m/z	Relative Intensity
149.8489685	0.06
160.9737091	0.11
171.7344360	0.07
178.7602997	0.06
191.0525818	0.15
206.9157410	0.12
232.9791260	0.03
234.8821259	0.05
275.2640991	0.09
283.6080933	0.06
301.9718933	0.13
311.5753174	0.24
323.1890869	2.71
329.3248596	0.18
355.1257629	0.15
358.1616516	0.05
365.1439819	0.13
395.1896667	0.37
396.0639648	0.15
397.2758179	0.03
400.2272949	0.04
428.1298523	0.24
446.1659241	100.00
455.3030090	0.12
456.3926392	0.17
474.1735229	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
93.00608063	1.14
97.00909424	0.86
137.220993	2.92
139.1313477	1.67
149.1756134	3.37
150.2287445	2.92
152.2996674	2.18
153.0225525	8.52
154.073761	0.57
162.0813904	16.52
165.1935577	1.31
176.1553345	2.20
178.0445709	2.20
179.0539856	4.05
180.0706024	2.03
180.8774567	1.27
181.532959	1.56
190.0409546	4.93
190.76297	3.70
192.2448425	2.33
204.1820831	0.63
205.1399231	1.20
206.9992218	10.78
208.1832123	28.72
209.1842346	5.90
221.01474	2.61
222.2040253	4.45
223.1799774	12.92
224.0766754	2.75
225.0933228	1.47
233.1164093	14.48
234.1285858	10.91
237.279892	0.52
249.1183929	1.59
251.0685272	100.00
252.1483917	43.86
253.0792694	3.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.76
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9521179	1.17
259.1148376	0.02
295.2101440	0.05
300.8352661	0.02
302.8793335	34.24
308.8051758	0.10
309.9877930	0.06
310.9276733	0.02
333.0621033	0.37
334.2612305	0.61
335.2796021	0.02
383.4860229	0.01
384.7716370	0.08
386.6750793	100.00
387.3491211	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.2131
Annotation	Maryal
Peak:m/z	Relative Intensity
119.1607208	0.09
125.0870209	0.57
131.9990540	0.25
142.3763733	0.04
143.1539612	0.13
144.1186981	0.21
148.9982300	0.14
160.9964447	1.64
162.0148010	0.62
171.1599121	0.29
173.0365295	0.16
178.9573669	3.88
179.9581909	1.75
180.7572327	0.44
205.3025818	1.62
205.9811096	2.28
207.1021118	1.00
207.9597015	2.12
209.1508636	0.75
225.0781403	0.17
226.0355835	0.22
237.1567993	0.78
249.3089905	0.09
251.2690125	0.10
253.0262451	0.18
254.2210388	0.19
255.1727295	0.28
261.3920288	0.20
269.0588989	0.09
296.0284424	0.09
302.1601868	0.07
313.5598450	0.18
319.5645142	0.07
325.2947388	0.12
333.4938354	0.07
337.4073486	0.39
340.3677979	0.21
341.3244629	0.19
342.4723206	0.10
345.1509399	0.43
353.5206299	0.30
368.0668945	1.08
369.1877136	1.88
370.1867371	5.55
371.2201843	100.00
372.1060486	0.74
373.3118591	0.35
374.3457336	0.14
397.2902527	0.27
398.1195984	0.05
399.0480042	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.15
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.0514374	1.51
165.0650330	1.10
168.8500671	0.11
173.2127686	0.63
174.7617493	0.09
177.1083374	0.29
179.0143433	0.40
181.0313873	0.51
182.7149963	0.16
185.1943512	0.27
187.0970459	0.25
191.1472931	0.55
193.0478973	0.15
197.0240631	0.38
199.2541504	0.20
201.0510864	0.89
203.0777283	0.87
204.9324188	0.69
207.2357483	0.17
211.2834778	0.14
211.9765015	0.10
215.2829285	0.08
217.1016083	0.22
219.3881226	0.54
220.9702911	0.11
225.0915833	0.15
227.1328735	0.22
227.8364563	0.06
229.0260315	1.73
231.1417542	0.21
233.0131531	1.21
240.8346558	0.43
241.5449371	0.05
243.1790314	1.78
245.0422974	0.59
247.0896912	23.91
248.2604370	0.25
253.1646881	1.20
255.0681610	0.66
257.1351013	0.61
259.1784973	10.53
260.0784607	0.20
261.0588379	0.61
262.1926270	0.05
269.0787048	0.93
271.1199341	9.04
272.2479858	0.10
273.1613770	4.11
274.1028442	0.14
275.1353149	11.19
276.8928223	0.22
283.1005249	6.02
284.9390259	1.48
287.1477661	7.40
289.0151978	17.83
289.7590942	0.03
291.0919189	38.54
295.1428833	0.76
297.1668701	0.06
299.1448669	2.78
301.0594482	27.81
302.5276794	2.01
303.1375122	10.20
306.9696045	0.11
311.0342102	0.04
313.0979614	2.40
315.2025757	1.54
319.0939331	0.05
324.5780029	0.04
325.2756348	0.44
328.9323730	0.05
331.2713013	0.22
333.0457153	1.64
343.3797607	0.26
368.2296143	0.40
369.5393677	0.23
373.1049194	0.16
378.2564087	0.17
379.1568604	0.47
381.3503418	0.05
382.3365479	0.05
389.1764526	0.18
390.9956055	0.28
392.4355469	0.09
394.4520264	0.16
397.2248535	0.76
398.3560181	0.04
399.4045410	0.32
400.9338989	0.07
403.0712280	0.10
405.1777954	0.22
407.3653564	0.95
409.0755615	74.99
409.9481201	0.72
411.2352905	11.77
412.1887207	0.09
417.1746826	0.81
419.0670776	0.12
421.2192993	5.76
422.3903198	0.13
423.4495239	0.34
425.2329712	1.84
427.1727905	100.00
428.5937500	0.03
433.0847778	0.89
435.3333740	12.99
439.1786499	8.83
447.2828369	0.09
449.4429932	0.17
451.1361694	0.61
453.1812134	23.45
457.3660278	0.06
468.1870117	0.12
468.9130249	0.40
477.7117310	0.27
493.2991333	0.29
494.0244751	0.13
508.3567505	0.24
514.0711670	0.04
523.6801147	0.10
525.4648438	0.07
529.5869141	0.11
533.3619995	0.24
541.2007446	0.05
542.1863403	1.59
543.2617798	4.59
560.1721802	2.90
561.1426392	9.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.09
Annotation	Methysticin
Peak:m/z	Relative Intensity
78.9299774	0.21
93.0594177	0.08
95.2500000	0.11
106.8889389	100.00
113.0789261	0.05
116.9040451	0.05
118.7845078	0.15
120.8961029	1.48
123.0837173	0.23
126.8894196	20.71
136.9732056	0.08
138.9802246	0.09
144.1369934	0.04
146.9641571	0.04
148.2424011	3.36
148.9472961	35.96
156.8909760	0.06
159.2447510	0.11
160.1852722	0.12
161.9402771	0.03
163.1898651	0.20
165.0103760	0.40
167.1784821	0.10
168.9138336	38.68
173.0974884	0.14
177.2786255	0.29
178.8831940	0.07
180.9410095	0.84
182.1786041	0.11
182.9786224	0.26
191.0543976	0.12
192.1180267	0.17
193.1333923	0.15
193.8118286	0.19
196.0065918	0.24
200.9269104	0.09
203.0870667	0.34
204.0524292	0.11
205.0495605	0.10
209.0307007	0.10
212.9394531	0.10
214.0302429	0.22
214.9413147	0.03
217.3388977	0.12
219.3665466	0.21
220.9582825	0.14
226.1004333	0.23
229.0382080	1.20
230.0314636	0.89
230.9578247	0.16
232.0845032	0.15
232.7658386	0.31
233.9453735	1.51
235.0658569	0.24
236.2675171	0.05
239.1639404	0.59
240.0231628	0.04
243.1696167	0.05
244.1366272	0.43
245.1387939	0.30
246.1574707	0.06
247.1623535	0.97
250.9550476	0.15
252.0371094	0.16
253.8939209	0.10
256.2088318	0.43
257.1085510	5.69
258.0939331	0.49
259.3085632	0.04
260.2024231	0.03
262.1928406	0.21
265.7126465	0.52
287.3562012	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2209
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
89.0491333	0.13
91.29075623	0.36
93.01803589	0.16
95.04582214	0.30
100.9523239	0.44
102.9045792	0.12
105.0199127	0.64
108.9123611	0.47
111.168396	0.19
113.0453796	0.60
114.8917313	0.44
116.0732574	0.17
119.0089722	0.33
124.7220764	0.20
126.8225555	0.41
128.9806519	1.12
132.9975586	0.13
134.9458008	0.21
136.5886841	0.54
137.2552948	0.30
138.7166748	0.81
140.7243347	0.25
143.0456238	0.56
151.0791016	0.48
153.1176147	0.47
154.9032135	2.92
157.1369019	0.68
159.0601501	0.16
161.155365	0.18
163.1463318	0.78
165.1117249	0.99
166.9772186	0.46
169.1361389	1.09
172.8788605	0.92
175.2191162	0.96
177.1118469	0.29
178.1169281	0.26
179.1748505	1.04
180.9749756	1.51
183.1017761	1.33
187.1794128	0.35
189.0618439	0.54
191.2149048	0.14
192.8787231	0.34
194.1382294	0.33
195.0172424	1.95
197.0707092	1.51
199.0503235	0.26
200.2562714	1.14
203.5696411	0.29
204.9729919	0.31
209.0818481	0.63
211.0545349	3.48
213.0080566	1.28
215.1581726	0.82
216.8392639	0.46
219.0228577	0.48
221.319397	1.72
223.1582642	1.61
224.3199158	0.25
225.1578064	0.99
226.8601685	0.49
229.104187	0.68
229.9918518	1.08
231.1922913	0.36
233.0401001	0.32
235.177002	0.67
235.9983215	0.89
237.0735779	24.51
239.0906677	1.95
240.1400452	0.20
240.9985657	0.74
247.2283325	1.42
247.945282	0.09
249.2595215	0.84
251.2891846	2.69
253.0806885	6.06
254.4318237	2.13
255.0981445	16.23
257.1980286	0.36
262.7179565	0.43
264.1672363	0.29
265.1470032	1.84
266.8475342	0.78
267.4654846	1.00
268.9607544	5.00
270.3302307	0.84
275.2992554	10.19
279.1635132	0.44
281.1485596	1.24
283.1370544	1.95
293.2141724	100.00
294.3114014	0.50
302.0829468	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.1584
Annotation	Raloxifene
Peak:m/z	Relative Intensity
145.8823395	0.07
148.0330353	0.49
163.2253113	0.06
165.1237183	0.06
166.8925476	0.05
177.1825562	0.12
191.1622925	0.67
193.0055237	1.81
214.7631531	0.08
219.2405396	0.11
221.3513794	0.13
233.0331726	0.09
234.1965942	0.10
236.0120239	0.84
254.1200867	0.09
256.0950012	0.22
258.0650330	0.26
258.6971436	0.02
264.3480530	0.24
273.3641968	0.23
274.8992615	1.06
276.9993896	0.10
300.1094360	51.88
316.2531738	0.05
323.5173340	1.32
327.2823792	0.06
332.9370117	0.09
338.1727905	0.17
343.1672974	17.06
356.4476318	0.23
359.1508179	0.11
360.2927246	1.13
367.1223145	0.57
368.9818115	0.13
371.1425476	0.03
377.1928406	0.35
381.1182861	0.17
382.3935547	0.27
385.2157898	12.06
386.3046570	3.11
387.2420349	0.04
398.0053101	0.07
404.2543335	100.00
405.8011169	0.06
407.7006836	0.07
408.7596741	0.11
411.3000488	10.76
422.9407043	0.07
424.9290466	0.64
425.6059265	0.02
428.2450256	0.78
429.3547668	14.28
430.3042297	0.07
435.3195190	0.68
442.4303589	0.10
445.0963440	0.10
454.2029724	14.18
455.3904724	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1172
Annotation	(2R,3R)-Taxifolin 3-glucoside
Peak:m/z	Relative Intensity
136.953949	4.85
150.8422546	0.12
153.0132904	0.84
156.2063904	0.35
159.0551453	0.58
164.9927368	0.91
172.9983215	0.15
177.1828003	0.11
179.0283203	0.71
183.0700531	0.12
203.1308746	0.24
224.2226715	0.40
239.0456085	0.62
242.3473969	0.15
245.1567383	0.51
249.3196411	0.29
252.9170837	0.35
258.8551941	0.96
267.1537781	0.22
269.0309448	0.38
270.2921753	1.90
275.9631042	0.28
281.1234436	0.50
287.0973511	7.61
297.2645264	0.41
299.0576172	0.20
301.025116	0.35
305.0578003	100.00
309.8143005	0.28
311.0870972	0.65
315.209198	0.57
321.3786621	0.33
323.4261475	0.09
325.2265015	0.34
326.2922668	0.30
329.1066895	2.40
335.4549561	0.28
339.3291931	1.01
342.8066406	0.60
344.0863647	0.12
346.3087158	0.17
347.1438293	5.21
352.8571472	0.14
355.1271362	0.32
366.8935242	0.93
369.4379883	0.24
371.2369995	3.38
379.2332764	0.16
381.1077576	0.13
383.65448	0.24
385.3703308	0.12
387.2943726	0.56
395.3299561	0.76
397.6213074	0.24
400.9616699	0.12
403.1926575	0.32
408.5207214	0.09
413.0554504	0.71
415.1465759	0.59
418.5087585	0.90
421.2405396	0.13
423.5387878	0.50
428.5622864	0.35
431.2004089	7.86
448.1857605	6.59
449.295166	48.46
450.2950134	0.96
451.7575378	0.74
454.6194153	0.40
467.3147583	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.2
Annotation	NORETHINDRONE ACETATE
Peak:m/z	Relative Intensity
115.0276566	0.62
118.7700958	1.94
127.0071106	0.57
147.0710144	0.95
155.9753418	0.54
163.0024414	0.29
168.9558258	0.50
169.9850159	4.60
177.1667328	1.02
183.0116577	100.00
184.0691528	6.95
185.049942	0.68
197.0107117	4.67
198.0587616	5.66
209.2068481	0.90
211.0857849	1.97
212.1937561	0.79
225.2516479	4.03
226.2541504	2.03
239.2462463	4.84
240.0979919	0.77
245.417572	1.94
247.490448	2.08
253.1260071	1.11
254.1947021	0.43
255.0378418	7.50
263.0344238	1.80
267.1970215	0.64
269.2600403	0.66
271.3338013	20.36
273.5454712	0.72
275.260376	7.00
277.4017029	1.43
279.125061	7.76
279.7622681	0.22
280.5803528	4.92
281.2416077	1.28
291.0494385	2.82
295.3070068	2.60
297.7443237	0.61
303.425354	0.84
307.543457	1.72
311.1302185	0.94
319.3392944	0.80
321.3430786	69.26
322.3352661	2.43
323.3773804	16.42
339.2521973	8.51
340.2019653	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1246
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9794159	0.25
164.6827087	0.08
178.8679810	0.08
180.8916321	1.73
183.9358521	0.15
185.0357361	0.54
198.8359070	0.38
208.6289368	0.15
214.7968140	0.09
223.0566711	0.21
231.0619202	11.69
245.0994415	0.06
257.3383789	0.13
262.3782043	0.05
263.1513672	0.49
264.7296143	0.05
276.3562012	0.45
288.0668335	0.79
289.0626221	0.85
299.0046997	0.07
306.1188965	21.04
308.0615845	0.17
310.3569336	0.16
316.2474365	0.38
317.1566162	6.84
334.0180054	100.00
349.4282227	0.15
357.0986938	0.06
364.2520752	0.16
366.8128052	0.40
373.9289551	0.21
375.1503296	0.16
390.9484863	1.65
392.1292725	0.30
399.8800659	0.19
409.1217651	47.58
417.0289917	0.09
445.1914673	0.29
456.9073486	0.19
463.2010498	0.85
475.3789673	0.08
478.0155640	0.06
494.2415161	0.06
495.3024292	0.16
503.3150635	0.05
520.2525024	9.88
521.2090454	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
97.1032715	0.41
99.0005646	0.16
100.9390030	9.17
104.2417908	0.24
106.8318176	0.78
112.9343338	27.63
114.9356079	1.38
118.8394547	15.88
124.9054718	1.19
130.9162445	12.02
142.9849701	29.28
148.9743958	5.49
160.8753662	23.31
178.8950195	100.00
209.1023865	0.84
221.1471863	1.49
250.8433533	0.82
281.0328979	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.8776
Annotation	Unknow
Peak:m/z	Relative Intensity
201.0903320	0.07
245.0554352	0.29
273.0515747	3.30
276.1262817	0.02
289.0088501	10.77
290.0643921	0.07
386.9730835	2.19
401.0573120	0.12
402.9522095	44.20
427.3380737	0.09
427.9564209	0.06
460.5647583	0.16
471.3099976	0.07
476.9194336	0.16
485.0238037	0.09
499.2106934	0.15
499.8665161	0.12
501.0451050	0.90
502.8861084	0.09
512.1725464	0.09
515.0233765	1.01
516.8508911	100.00
517.5117188	0.70
518.8203735	0.18
531.2135620	0.12
534.0652466	0.04
539.9032593	0.04
541.0452881	0.14
546.9515991	0.12
556.8383789	0.13
558.2554321	0.23
559.9261475	0.21
583.8563843	1.07
585.0862427	0.40
585.9969482	0.10
587.0620728	0.16
587.8330688	0.11
588.8075562	0.14
597.8557739	0.16
599.0727539	0.18
602.9476318	0.08
612.0682373	0.24
612.9543457	0.04
630.9337769	0.15
638.8526001	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
140.1195374	0.07
153.0530396	0.09
159.9396362	0.10
181.0719147	0.13
196.0666199	1.95
199.1254883	0.18
214.0567017	1.28
239.1669006	0.19
248.1676636	0.49
255.2374878	100.00
271.2991943	0.47
272.2787781	0.28
289.1134338	0.29
299.7809143	0.12
324.4519043	0.07
345.6217346	0.10
353.9972534	0.10
362.1761169	0.08
379.4062805	0.17
384.2024231	0.23
387.2153015	0.19
389.5882263	0.52
393.6210022	0.39
405.3847046	1.44
406.2395325	0.53
407.5473938	0.18
425.662323	0.27
432.1664124	0.40
433.5190125	1.24
434.8303833	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	2859-88-3
Peak:m/z	Relative Intensity
76.68656921	1.41
78.76080322	1.11
80.83216858	7.82
82.98282623	2.18
84.97624207	2.37
88.73912811	1.12
95.00374603	6.89
97.10096741	1.16
97.99925232	1.03
98.7996521	0.33
101.032486	0.91
103.0555573	1.53
104.8483276	1.24
106.1912994	1.02
107.0295563	1.12
108.9402924	3.48
111.028656	2.83
112.9185638	1.62
120.9412994	3.60
121.8827972	1.45
122.9257507	3.26
125.1538696	0.91
127.0441895	17.77
128.9766235	3.65
133.0285034	1.92
133.8583221	3.05
135.1638641	1.48
137.0077515	2.25
138.835144	5.24
139.8433075	0.78
141.0323639	3.51
144.9870911	2.72
146.926651	2.63
147.8475952	0.78
148.9333496	4.71
150.9710083	61.43
151.8710175	3.37
152.9995728	4.80
155.0122223	0.74
156.0751801	2.44
157.1959991	4.00
158.7794342	2.47
161.2059784	4.85
162.2577057	0.41
163.2351685	1.87
165.0922394	1.38
166.9296417	4.74
168.0490723	0.62
169.0477142	5.25
170.0079041	1.03
170.9636688	0.62
173.9170074	0.61
175.0036774	6.75
176.1364594	1.40
177.1828461	4.75
178.2008362	0.58
178.978653	6.93
180.9246979	0.82
182.1467896	4.25
183.0017395	6.65
185.0196991	1.41
189.0663605	3.66
190.8788605	2.44
191.9372406	6.49
192.9539642	10.91
193.939621	9.32
194.8887787	2.87
197.1327057	12.93
199.0270538	0.58
199.8912201	0.74
202.7395782	2.43
203.3892517	1.95
204.8596039	3.83
206.9268799	15.19
209.2208405	7.54
210.0571747	2.95
211.229538	10.97
211.8439484	2.41
215.9953003	3.91
217.099472	17.69
219.4864044	0.25
222.113205	2.26
223.9873505	18.97
225.1785889	22.50
234.0008545	6.37
235.0829468	100.00
236.2914429	0.94
238.0108185	6.27
238.6678619	1.23
239.5186005	1.57
244.2502594	2.11
252.0649414	0.87
253.0897827	30.30
254.2025909	2.26
255.2116241	3.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1169
Annotation	(2R,3R)-Taxifolin 3-glucoside
Peak:m/z	Relative Intensity
136.967041	5.91
150.8280182	0.27
152.802536	0.28
174.8269958	0.13
177.1320801	0.24
179.0164948	1.13
217.1291504	0.17
226.7171326	0.34
227.3217468	0.05
239.4518433	0.24
242.1914215	0.16
259.0794373	0.87
271.0495605	0.13
275.3602295	0.38
276.9933167	0.10
287.0656738	4.10
287.9814758	0.34
298.1369019	0.11
302.1876221	0.18
303.0755005	0.88
305.0569763	100.00
305.6780396	0.52
311.3465881	0.18
329.1315613	2.31
331.4632568	0.11
334.1500244	0.71
339.0618591	0.38
345.1557617	0.44
346.2186279	0.20
347.0995483	4.45
350.4463806	0.31
353.0792847	0.61
359.2294312	0.25
363.4331055	0.27
370.0985107	0.39
371.1626892	3.03
378.0915527	0.08
380.249176	0.19
383.2067566	0.84
390.6199341	0.08
394.5884094	0.17
395.4603882	0.19
398.3733215	0.19
399.493866	0.16
400.677063	0.23
403.4232483	1.01
405.6706848	0.27
413.0986633	2.97
421.2319031	0.75
422.8912659	0.14
431.2814026	12.17
435.0466919	0.58
449.2185364	57.84
450.4508057	0.35
459.0596313	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
104.9888916	0.28
106.0908813	0.17
140.8313141	0.18
142.9298706	0.57
148.8381805	1.22
150.0736847	0.33
168.937973	0.68
173.9209442	0.16
178.2038269	0.11
179.0999146	2.40
180.010025	0.23
180.9754486	1.15
183.0006561	0.24
185.0461273	0.37
186.3248749	0.22
193.0345612	0.48
194.1083832	0.54
195.1213837	0.82
206.0584564	1.52
207.1553497	8.59
208.0876312	6.36
208.9832611	2.49
210.3125916	0.31
222.0361176	2.82
223.1592865	12.64
224.1864166	1.25
225.2238159	0.11
232.5998688	0.16
236.1151581	0.64
238.1023712	0.23
250.0264282	0.43
251.0841217	100.00
252.1911011	23.70
253.1651001	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.5865
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2685547	0.03
212.2856293	0.11
228.0278168	0.03
232.2412872	0.04
235.6360016	0.16
244.2403870	0.05
251.1972504	0.05
252.1806030	0.05
258.2133179	0.07
259.0257263	0.03
269.9235535	0.08
284.1418457	0.10
285.1094971	0.07
311.0198059	0.03
323.2500000	0.19
332.2471313	0.18
333.2723389	0.03
335.0438843	0.16
336.5154419	0.22
344.3874512	0.16
348.4058228	0.16
350.1067505	0.39
353.3739624	0.50
358.4206543	0.06
365.1159058	0.06
367.2902222	0.13
370.1264648	0.15
371.1557617	0.07
373.4923706	0.10
374.3647461	0.26
384.0816650	0.05
386.9030151	0.09
394.3761597	0.32
401.1764526	0.04
415.4325562	0.36
421.4378662	0.37
422.4882202	0.46
430.5112915	0.19
434.2108765	0.02
436.3338623	0.12
438.5940552	0.17
443.5422363	0.08
449.4605713	0.35
452.5292358	0.20
457.5212402	0.10
463.1293945	0.48
464.2664185	0.03
466.4877930	0.04
475.0657349	0.08
476.5737915	0.12
479.8558960	0.15
480.6536865	0.03
485.9605103	0.39
486.5680542	0.33
487.2307739	0.21
488.8960571	0.15
492.5383911	0.07
494.8599243	0.15
499.3530884	0.13
502.3230591	0.32
505.8784790	0.06
507.4486084	0.19
509.7324829	0.08
515.2546387	0.28
517.4287720	0.13
520.4679565	0.29
521.2333374	0.03
524.1913452	0.03
524.8743896	0.22
525.7675171	0.41
526.3964844	0.33
527.6596069	0.22
528.9683228	0.44
534.4580688	0.21
536.1989136	0.24
537.9734497	0.21
538.7532349	0.30
539.6781616	0.39
540.7673950	0.08
541.6890259	0.59
543.7750854	0.88
548.3017578	0.48
549.3217163	0.23
550.9723511	0.10
552.3612671	0.87
554.3210449	0.12
555.6959229	0.32
556.8336792	0.61
559.0204468	0.65
559.8989258	0.11
561.0928955	0.07
562.5963135	1.18
563.4146118	0.39
565.4746704	1.17
566.4884033	3.61
568.4823608	0.03
569.8986206	1.43
571.1650391	0.27
573.6173096	0.49
576.5103149	3.13
577.4777222	0.27
579.0890503	1.88
580.0182495	2.75
580.6848755	0.15
581.6569214	0.57
582.4491577	0.06
584.2908325	2.22
585.5541382	0.10
586.5562744	3.37
587.4389648	1.39
588.9187622	0.11
591.0121460	7.89
591.6162720	5.29
592.3967896	0.50
593.6567993	0.17
594.8741455	0.54
595.7510376	0.03
597.6447144	1.33
598.4524536	0.33
600.3609009	1.49
601.3328247	0.90
602.3218384	0.70
603.1372681	0.53
604.5952148	3.23
605.2811890	0.81
606.0904541	0.21
607.0416870	0.02
619.4165649	0.19
620.4497681	0.10
626.7379761	0.27
628.1561279	0.35
628.7604980	0.45
630.0869751	0.16
632.5071411	0.23
634.3040161	0.41
635.7698364	0.07
636.7457886	0.13
637.9573364	0.24
638.9063110	0.96
642.8784180	0.41
645.2186279	1.36
646.2654419	0.73
646.9410400	0.07
650.0801392	0.51
650.7721558	0.07
653.4736328	0.03
656.6036987	0.06
661.7588501	0.10
663.9329224	0.07
665.1044312	1.06
666.0966797	1.07
667.0553589	0.30
668.6581421	0.14
670.9946899	0.41
671.7255859	0.49
672.6439209	0.60
674.7684937	0.53
675.6220703	0.15
679.2341309	0.19
679.9989624	0.85
680.6387939	0.16
681.5939941	0.06
683.9244995	0.06
686.6893921	0.32
687.3411255	0.08
688.5703735	0.26
689.3818359	0.14
693.0787354	0.40
694.0595093	0.12
695.7261353	0.08
697.6106567	0.21
698.7970581	0.35
702.1700439	0.24
703.3486938	0.72
704.9510498	0.32
705.6986084	0.41
706.6270752	0.08
707.5773315	0.68
708.4182739	0.16
709.7343140	0.05
712.1588745	0.12
713.1856079	0.25
714.0056763	0.11
715.0646362	0.33
715.7390747	0.17
717.0663452	1.38
717.7676392	0.09
718.4226685	0.28
719.3273926	0.31
721.0252686	0.13
722.3253784	0.12
726.4152222	0.59
727.6594238	0.58
729.4884644	1.23
731.8900757	0.17
733.5201416	0.58
734.6391602	0.86
736.0156860	2.86
737.0369263	0.51
737.9331055	0.04
739.2706909	0.16
740.9382324	0.40
743.1068726	0.38
743.8671875	0.70
744.5331421	0.08
745.3297119	1.83
745.9796143	1.33
746.6527710	0.09
747.4064331	0.26
749.2611694	1.04
750.3250122	8.10
751.2816772	0.61
752.1077271	0.02
753.0125122	0.10
754.8006592	9.53
755.7336426	2.77
756.6925659	0.40
758.2556152	0.86
759.6341553	0.10
760.2716675	0.16
761.4272461	0.10
762.9816284	0.63
764.2588501	0.25
765.0378418	0.44
766.3141479	0.10
767.2966309	0.36
768.8906860	3.48
769.6159058	1.11
770.2853394	0.57
771.7588501	1.33
772.4138794	2.03
773.0396729	0.76
775.7426758	0.90
776.4623413	0.26
777.9104614	4.20
778.8295288	1.56
779.4333496	0.65
781.4752197	1.00
782.0927124	6.55
782.7185669	4.23
783.5622559	1.90
784.8038940	0.67
786.6388550	0.42
787.3039551	1.30
788.0395508	100.00
789.6321411	1.46
790.8454590	0.55
791.9052124	0.39
795.9738770	0.15
797.6107788	0.19
798.4317017	0.39
800.3357544	0.32
801.4057617	0.05
802.4317017	0.15
805.2711792	0.30
807.6086426	0.32
808.5287476	0.41
811.6536255	0.38
812.3922119	0.49
814.5176392	1.06
815.3592529	0.66
816.0524292	0.04
816.7226562	0.10
817.6272583	0.20
821.6793213	0.10
824.3957520	0.16
829.1925659	0.06
830.5902710	0.13
832.8364258	0.43
833.6560669	0.13
835.2884521	0.10
838.4948730	0.12
842.7863159	0.07
843.7260742	0.13
844.3459473	0.12
846.2664185	0.54
850.3882446	0.30
853.2031250	0.20
854.0142212	0.73
857.5022583	0.39
859.3607788	0.20
860.7497559	0.36
864.4802856	0.86
865.2253418	0.09
868.4572754	0.23
871.6583862	0.39
872.7119751	0.71
877.6255493	0.03
880.1179810	0.14
886.6069946	0.05
889.8944702	0.17
890.6240234	0.04
892.3987427	0.10
896.3656616	0.14
900.5247192	0.12
903.9946289	0.24
904.9608765	0.03
907.2879028	0.23
909.1938477	0.05
910.1604004	0.12
911.8079224	0.16
914.0003052	0.20
917.8275757	0.24
921.8983765	0.12
926.1227417	0.06
928.8850708	0.13
930.2304688	0.05
933.8747559	0.29
939.7359009	0.10
941.4563599	0.33
943.1806030	0.66
943.8493042	0.03
945.2601929	0.22
946.8850098	0.13
950.0861816	0.09
950.7343750	0.37
959.3650513	0.12
961.8696899	0.05
967.2507324	0.63
968.3274536	0.02
969.7822266	0.38
971.7316895	0.27
973.6489258	0.15
977.5986328	0.20
983.6433716	0.17
986.7476196	0.10
987.6548462	0.08
988.4226074	0.05
989.8640747	0.06
991.3630371	0.16
992.1038208	0.11
995.1165161	0.03
996.8779907	0.14
1003.0349120	0.10
1005.1979980	0.22
1007.8432010	0.04
1011.7349240	0.17
1025.3537600	0.18
1035.9278560	0.07
1036.8081050	0.09
1041.7589110	0.19
1045.2690430	0.64
1046.3669430	0.09
1050.8814700	0.05
1054.3166500	0.23
1055.8448490	0.20
1058.6481930	0.09
1060.2335210	0.03
1061.1428220	0.20
1067.0034180	0.14
1070.3817140	0.44
1083.6872560	0.11
1087.7980960	0.06
1088.7458500	0.15
1095.8698730	0.10
1101.9982910	0.20
1102.7919920	0.13
1105.1396480	0.07
1109.6347660	0.13
1110.5520020	0.11
1115.7155760	0.14
1116.9038090	0.36
1122.8078610	0.11
1132.0463870	0.23
1176.4960940	0.04
1186.1016850	0.04
1194.6837160	0.10
1198.7575680	0.15
1202.6988530	0.08
1203.7072750	0.03
1215.6553960	0.20
1227.6717530	0.07
1238.9154050	0.12
1249.6419680	0.03
1288.8166500	0.09
1291.9608150	0.17
1293.6885990	0.03
1311.8157960	0.09
1344.3808590	0.12
1345.9954830	0.03
1359.0953370	0.08
1382.7144780	0.07
1395.1181640	0.04
1450.8182370	0.03
1468.6873780	0.15
1486.7593990	0.14
1487.4466550	0.03
1506.3779300	0.05
1532.5684810	0.14
1540.3381350	0.10
1546.1926270	0.06
1633.1180420	0.07
1699.3565670	0.04
1719.1192630	0.08
1741.3967290	0.05
1755.4855960	0.05
1757.3978270	0.12
1778.7292480	0.07
1797.6898190	0.03
1859.0648190	0.03
1871.5970460	0.80
1876.5953370	0.64
1877.4766850	0.02
1894.1789550	0.06
1918.3236080	0.03
1937.1358640	0.25
1960.3526610	0.03
1966.3548580	0.08
1969.3636470	0.12
1970.2911380	0.06
1976.6026610	0.11
1991.6654050	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.8
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0635986	0.03
130.9022369	0.00
158.7994690	0.01
178.0569763	0.02
215.2579041	0.00
218.9119263	2.05
233.0295410	0.01
272.9951477	0.01
300.5171509	0.02
301.2357483	0.01
302.8789062	100.00
303.7137451	0.00
327.1898804	0.01
340.1833191	0.03
341.1386108	0.02
369.2581482	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.2
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
243.1205444	0.07
245.1032562	0.06
246.1446533	0.02
258.9579468	0.02
261.1259155	0.02
265.1859131	0.03
267.1383972	0.05
269.1522827	0.07
273.2703247	0.06
281.5237122	0.03
283.2298279	0.08
284.5439453	0.02
287.1314087	0.74
288.1504517	0.12
289.1816406	0.17
295.3024902	0.02
299.1607056	0.12
300.2481689	0.01
303.5514221	0.02
306.2510986	0.02
309.2642517	0.02
322.3261108	0.02
326.3106995	0.01
329.2719727	0.04
337.2788696	0.01
339.0926514	0.02
343.1292419	0.03
347.0278015	0.04
359.2645264	0.04
361.0405579	0.01
362.3082886	0.06
363.411438	0.04
365.2208862	0.01
367.0879211	0.02
377.2705078	0.01
378.4960938	0.04
379.2146606	0.01
381.1619263	0.08
383.4634399	0.04
387.2717896	0.14
390.0523682	0.02
391.1780396	0.05
395.2540283	0.24
396.1818237	0.04
405.0906982	0.24
406.1204834	0.06
407.3049316	0.94
408.1824341	0.07
409.6848145	0.03
411.4105225	0.02
413.2771606	0.50
414.0262451	0.06
422.3944702	0.02
423.2600708	0.13
425.324646	0.58
431.4009399	0.08
435.4396973	0.04
445.4846191	0.01
447.425415	0.07
449.2434692	0.65
450.7451782	0.06
451.3737183	0.58
452.2339478	0.15
454.2219849	0.04
455.5546875	0.03
464.9885254	0.01
467.2088623	0.02
468.4029541	0.09
474.2593994	0.02
479.4451294	0.06
489.4766846	0.02
490.1065063	0.07
490.8771973	0.05
498.6702881	0.04
511.7147217	0.03
515.5562744	0.11
516.4945679	0.02
517.3540649	0.10
525.2544556	0.04
526.4515381	0.01
529.2478638	0.04
531.1505127	0.13
532.1151733	0.05
533.5028687	0.07
539.0419922	0.03
541.1903687	0.05
543.2509155	0.17
545.3621826	0.03
546.4237061	0.01
549.6010132	0.09
553.3306274	0.09
555.4213867	0.02
556.836731	0.02
557.4691772	0.14
558.1782227	0.10
559.2365723	0.17
560.2301025	0.04
567.3781128	0.02
569.3365479	0.03
570.4364624	0.04
571.3383789	0.04
572.3547974	0.08
573.3272095	0.02
574.2479248	0.08
575.2316895	0.72
576.3712769	0.29
577.2749634	0.67
578.2207642	0.15
581.3141479	0.01
585.3428345	0.07
586.2827759	0.07
587.1264038	0.08
595.4596558	0.06
599.3944702	0.01
600.2532349	0.06
601.4229736	0.08
613.7501831	0.10
617.1920166	0.05
618.4229126	0.18
619.3070679	0.04
624.725647	0.03
627.2521362	0.09
629.2930298	0.26
634.2280273	0.25
635.1372681	0.31
638.5545044	0.07
639.3699951	0.01
640.3058472	0.01
645.0023804	0.07
647.5454712	0.03
648.3340454	0.02
649.3843384	0.04
656.4445801	0.01
657.4653931	0.10
658.8419189	0.10
664.8311157	0.02
665.4859009	0.03
670.3618774	0.04
671.2001953	0.03
675.2227173	0.01
677.2080688	0.02
683.387146	0.13
685.725708	0.04
687.1893311	0.03
689.2856445	0.03
693.6246948	0.30
694.3283691	0.37
695.2597046	0.31
696.3895874	0.09
696.9916382	0.10
698.6865845	0.01
701.0958862	0.49
702.1064453	0.17
703.362854	0.75
704.1796875	0.02
710.6765747	0.24
711.3214111	0.08
712.3375244	0.19
713.3312988	0.06
714.3345337	0.02
716.3739624	0.21
718.0703735	0.02
719.411499	0.49
720.4703369	0.45
721.1248169	0.03
721.7555542	0.02
724.4290771	0.06
725.3148804	0.15
727.868042	0.01
737.2260742	0.23
738.2938843	0.18
739.2526245	0.36
740.3813477	0.10
743.1987915	0.04
753.6025391	0.02
757.9473877	0.01
766.2019653	0.11
770.3549805	0.27
770.9844971	0.07
778.3738403	0.03
779.5094604	1.50
781.461853	0.06
788.4497681	0.78
792.3232422	0.08
801.269104	0.31
801.944397	0.12
803.5265503	0.04
811.133606	0.01
813.0671997	0.02
819.4517822	0.01
821.7492065	0.01
831.1508789	0.02
831.8208618	0.03
837.5042725	0.01
838.2531128	0.01
845.6053467	0.18
847.4690552	0.40
848.2579956	0.05
863.2728271	0.11
865.1975098	100.00
866.3030396	0.11
867.5383911	0.11
868.324646	0.03
871.4558716	0.07
875.258728	0.06
882.3405151	0.01
887.291687	0.01
889.3922729	0.07
899.343811	0.02
901.3284302	0.04
906.309021	0.02
907.8684692	0.05
908.5222778	0.06
955.7338867	0.04
958.7315063	0.03
965.4594727	0.01
971.1061401	0.05
981.4262085	0.28
982.4988403	0.02
983.2332153	0.11
988.6948242	0.04
989.3556519	0.31
990.2658691	0.12
998.3388672	0.01
999.4213257	0.09
1000.453674	0.01
1001.551086	0.01
1023.26947	0.01
1025.216064	0.29
1026.216553	0.04
1027.302734	0.44
1028.34082	0.10
1031.089722	0.02
1041.331299	0.07
1056.242065	0.02
1091.224121	0.04
1099.228271	0.02
1102.089355	0.01
1107.259399	0.04
1108.815308	0.06
1109.477417	0.05
1110.424805	0.09
1117.497437	0.01
1119.459229	0.10
1120.568604	0.04
1125.460571	0.14
1126.516357	0.06
1131.375488	0.03
1133.534058	0.04
1134.677979	0.08
1135.661499	0.03
1144.205566	0.06
1145.388428	0.03
1146.405273	0.04
1151.228516	1.14
1152.514648	0.80
1153.345215	0.86
1154.20813	0.38
1154.986816	0.01
1163.458862	0.02
1189.091187	0.07
1193.293457	0.07
1194.40332	0.05
1195.449219	0.02
1196.316772	0.03
1201.618408	0.01
1211.137695	0.01
1216.239258	0.04
1224.829468	0.11
1243.298828	0.02
1250.899536	0.04
1252.619019	0.02
1259.045288	0.14
1259.645874	0.04
1269.785278	0.13
1270.518311	0.08
1277.427856	0.28
1278.508667	0.03
1287.393433	0.01
1288.188843	0.02
1288.834595	0.02
1289.607666	0.01
1290.843872	0.02
1297.361816	0.03
1313.5896	0.12
1314.321167	0.02
1315.277466	0.53
1316.216309	0.06
1354.866455	0.02
1397.543945	0.03
1421.396362	0.04
1433.355713	0.02
1434.317261	0.09
1435.44397	0.02
1438.758911	0.02
1439.464233	0.39
1440.748413	0.27
1441.570068	0.16
1442.488525	0.06
1464.689697	0.03
1478.342651	0.02
1483.350464	0.12
1483.953369	0.04
1534.522583	0.02
1561.347412	0.01
1585.834717	0.01
1603.210693	0.12
1604.703735	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.0034
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
193.0252075	0.29
211.0558777	3.25
214.8124390	2.54
223.0220795	0.40
232.8517456	0.28
241.1267242	5.65
242.8209229	0.22
256.9620056	1.76
259.3072205	0.39
261.8692322	0.63
273.0049744	0.14
280.0733948	2.14
286.7988281	0.48
292.2554932	0.11
298.7966919	0.80
304.7392578	0.16
311.1599426	0.44
312.6301880	0.13
315.0282593	0.06
318.0592041	1.29
320.9230347	0.24
323.0877380	100.00
326.2167969	0.48
329.0784302	10.17
334.1834717	2.30
336.1224365	0.19
341.1048584	0.13
353.8860474	0.10
359.0258789	3.90
369.9681396	0.06
371.1135254	0.26
371.9598389	0.36
377.0969238	10.64
377.7788696	0.26
380.0516968	0.44
382.4817505	0.10
385.2666626	0.08
388.2853394	0.53
391.0411377	1.35
398.1090698	1.17
402.1002197	0.10
406.2176514	0.14
416.1023560	0.15
419.0021362	4.79
423.0082397	4.15
424.1051025	1.52
426.0693359	0.11
430.7528076	0.43
434.7976685	0.58
440.0894165	5.26
441.1322021	44.11
444.2334595	0.89
446.7225952	0.40
448.9440918	1.00
452.0240479	2.32
452.9819946	0.10
458.2119141	0.76
462.3233643	0.73
466.4984131	0.62
470.1424561	14.21
472.9984741	0.41
483.1481934	36.55
484.8851929	0.13
488.0709839	4.40
491.1596069	6.09
499.9296265	0.27
504.4103394	0.26
516.2457886	0.31
518.6848755	0.89
524.0923462	1.52
524.9143677	0.68
541.9884033	2.63
560.2014160	66.78
585.1773682	18.45
602.9868774	1.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2916
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
142.1189270	0.09
152.9841156	0.12
170.7752075	0.18
180.2281189	0.03
182.2570190	0.02
195.1319580	0.04
195.9825287	0.25
197.8557434	0.19
203.1752319	0.06
205.1210480	0.24
211.1918640	0.04
215.0412598	0.09
216.2313995	0.36
237.3836060	0.07
239.0827637	0.15
245.2235413	0.06
254.9858093	0.06
267.4558411	0.03
276.1774597	0.04
282.3332520	2.81
283.6474609	0.17
295.4880371	0.14
297.3332520	0.06
300.4744263	0.06
305.0190735	0.15
313.3001709	80.64
321.1589661	0.13
322.2081604	0.02
326.0806885	0.15
327.1275024	0.09
328.3384094	0.04
330.8666077	0.04
337.2618103	0.05
342.3696289	0.07
349.2001038	0.18
356.7994385	0.28
365.3641968	0.15
379.4237366	0.10
383.3333130	0.03
393.2691956	9.27
400.9553528	0.18
408.9255676	0.17
413.4835510	0.06
417.7351074	0.20
418.5674744	0.68
419.3236389	0.04
423.3824158	0.32
436.1858521	100.00
436.8403931	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	864.19
Annotation	Unknow
Peak:m/z	Relative Intensity
243.1162872	0.18
245.1514740	0.17
251.2350464	0.11
252.9562683	0.02
255.0300293	0.03
256.0450134	0.02
257.4253845	0.04
260.9266663	0.25
267.0688782	0.10
268.8535461	0.04
273.3972778	0.04
277.8798828	0.04
282.9556580	0.14
285.0815430	0.14
287.1088257	1.27
288.6047668	0.28
289.2415771	1.89
295.0871582	0.02
297.2487183	0.27
299.0997009	0.15
301.0679932	0.03
306.0431824	0.19
313.2489624	0.05
321.1842041	0.03
327.1156311	0.10
329.2025146	0.22
330.9685364	0.02
337.1988831	0.02
339.3262329	0.15
340.4375610	0.11
341.3724976	0.02
359.5463257	0.10
361.2238159	0.03
363.0015869	0.10
363.9741211	0.03
367.1564331	0.08
369.3352966	0.10
379.2486572	0.29
381.2757568	0.11
385.4785767	0.03
387.0850830	0.20
389.3593750	0.08
391.3363647	0.13
395.0668945	0.44
396.1267700	0.17
397.1013794	0.03
403.1306763	0.11
405.0786743	0.76
407.1758423	2.77
408.1430054	0.05
409.4321289	0.08
411.3334351	0.16
413.1542969	0.70
414.2861938	0.06
417.2130127	0.19
421.1267700	0.06
423.2315063	0.71
425.2153931	1.02
430.3746948	0.10
433.4118652	0.02
434.2326660	0.07
435.1403198	0.17
436.9840698	0.03
439.1925049	0.06
445.3470459	0.02
447.2149658	0.33
448.2764282	0.07
449.1975708	1.20
451.2717285	0.78
453.1573486	0.02
455.1311646	0.05
456.8254395	0.01
465.2897949	0.09
473.4854736	0.05
477.0571289	0.04
489.2032471	0.05
490.2742920	0.03
493.2681274	0.15
494.3051758	0.03
499.1627197	0.07
501.5104980	0.02
509.4153442	0.07
513.1951904	0.25
515.2916260	0.12
516.4769287	0.05
517.8825073	0.08
522.9696045	0.05
525.0964355	0.28
527.1074219	0.04
529.1806030	0.11
531.2768555	0.47
532.8134155	0.15
533.4717407	0.23
535.1337891	0.17
541.1705933	0.08
543.2802124	0.32
544.2142334	0.03
548.9548950	0.14
550.4988403	0.05
553.1802368	0.30
556.6682129	0.11
557.3421021	0.63
559.2431030	1.14
560.0236206	0.10
562.2145386	0.43
567.2861328	0.15
568.0383301	0.03
569.2603760	0.14
570.2252808	0.16
571.7874146	0.39
573.2706909	0.20
575.2130737	3.11
576.2831421	0.43
577.3212891	3.17
585.3224487	0.26
586.9319458	0.20
590.5006714	0.04
594.7529907	0.03
596.7404785	0.10
598.4981079	0.05
601.3386230	0.17
604.1607056	0.03
605.2046509	0.11
609.3115234	0.24
611.5057983	0.05
613.2413940	0.14
614.4823608	0.21
615.4952393	0.11
616.3292847	0.02
617.1759644	0.21
618.2328491	0.05
619.5822754	0.05
622.5872803	0.09
628.4230957	0.06
630.3480835	0.11
634.2445068	1.17
635.3091431	0.38
638.0018921	0.09
642.6318970	0.04
643.4069824	0.15
644.3430176	0.53
649.3878784	0.14
651.3694458	0.21
654.8320312	0.24
655.7514648	0.03
656.5886230	0.25
657.4849243	0.18
663.4129028	0.19
664.4485474	0.16
666.8475342	0.02
668.5339966	0.05
669.2472534	0.09
675.2018433	0.07
676.2692261	0.05
677.4356079	0.02
683.0711060	0.10
685.4265747	0.02
689.5056763	0.03
690.1359863	0.03
691.4067383	0.04
693.1454468	1.59
694.3494263	1.39
695.2636719	1.43
696.2605591	0.05
697.2476196	0.11
698.2321167	0.13
701.2702637	0.74
703.1409912	0.38
703.7890625	0.06
705.4705811	0.05
710.5473022	0.24
711.2180786	0.59
712.1549683	0.74
712.7901611	0.05
713.5864868	0.09
714.3150024	0.05
715.7242432	0.16
716.4090576	0.20
719.3274536	1.72
720.2976685	0.61
721.2643433	0.25
722.0339966	0.07
723.9081421	0.03
725.4390259	0.55
729.4036255	0.05
736.4131470	0.26
737.3000488	0.91
738.2757568	0.06
739.3324585	1.00
740.2445679	0.04
741.5972900	0.08
755.2944946	0.08
766.2919922	0.09
770.3539429	0.69
779.2421875	4.55
780.1947021	0.18
781.3928833	0.28
788.3724976	1.85
792.5948486	0.08
795.4747925	0.04
801.3417358	1.13
802.1780396	0.29
803.3939819	0.37
809.4273071	0.30
813.4205933	0.11
815.5545044	0.01
819.2017212	0.46
821.3121948	0.11
823.3488159	0.07
831.4539185	0.11
832.5228882	0.04
842.5454712	0.40
845.4023438	0.38
846.4667358	0.22
847.3513184	0.56
849.4677124	0.11
864.6321411	100.00
865.4553833	2.71
866.3983765	0.39
867.5744019	0.27
871.3069458	0.08
873.5355225	0.10
875.3332520	0.06
889.4234619	0.09
904.3552856	0.14
907.2345581	0.34
936.9183960	0.10
939.2455444	0.02
945.6086426	0.14
958.1239624	0.09
967.0737305	0.09
971.4265747	0.27
975.3484497	0.08
981.2143555	0.99
982.5562134	0.14
983.2433472	0.56
985.7812500	0.01
989.2208862	1.26
990.4227905	0.13
991.5848999	0.16
993.4972534	0.11
998.2617798	0.03
999.1779175	0.25
1001.3574220	0.05
1004.4677120	0.03
1007.2539670	0.06
1007.9369510	0.02
1008.9304810	0.09
1025.3713380	0.56
1026.0935060	0.05
1027.2441410	0.58
1089.0397950	0.03
1101.6513670	0.19
1106.0611570	0.08
1107.1433110	0.23
1109.3471680	0.56
1110.2951660	0.02
1125.3918460	0.15
1127.7312010	0.04
1129.2941890	0.08
1133.4916990	0.04
1135.2236330	0.61
1145.5986330	0.08
1151.2474370	5.53
1153.2095950	4.03
1154.0622560	0.14
1163.3229980	0.06
1175.4602050	0.04
1187.3833010	0.09
1189.2714840	0.07
1195.3417970	0.04
1227.9675290	0.06
1258.8521730	0.10
1269.2762450	0.42
1271.1530760	0.10
1272.2541500	0.05
1273.3455810	0.04
1277.0501710	0.53
1277.7796630	0.02
1287.4375000	0.13
1289.4442140	0.02
1295.9349370	0.06
1297.3482670	0.08
1302.2830810	0.08
1307.3846440	0.07
1313.1971440	0.32
1315.3283690	1.01
1316.1759030	0.03
1331.8215330	0.06
1382.4892580	0.04
1395.3582760	0.07
1397.2362060	0.15
1407.4725340	0.13
1415.3585210	0.08
1421.7001950	0.11
1422.8646240	0.13
1433.4388430	0.43
1438.6158450	0.12
1439.2401120	1.76
1439.9227290	0.01
1441.2830810	1.04
1442.1695560	0.20
1465.8250730	0.07
1483.3542480	0.38
1561.3443600	0.11
1567.5179440	0.05
1603.3074950	0.72
1604.1922610	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
128.7192993	0.25
132.7702026	0.26
145.7881317	0.58
161.9501953	0.21
163.1427307	0.15
164.9020691	0.58
169.0904846	0.63
173.1622009	0.46
177.209259	0.20
193.3067017	0.63
211.2762451	0.54
216.3058624	0.22
223.0163879	0.32
225.2900696	0.35
231.0201111	0.52
241.1881409	0.07
249.4544678	0.13
251.4084778	0.83
253.2431946	0.44
255.6209106	0.20
259.0414429	0.31
260.9059143	0.90
265.0855408	0.61
268.0785217	0.22
271.4124146	0.31
273.229248	0.35
282.5812073	0.32
283.241333	0.20
285.1065674	0.23
287.0563354	100.00
287.7159119	0.31
291.1711426	0.19
297.2891846	0.32
300.4872742	0.44
303.1292114	0.54
313.2063599	0.40
314.098114	0.28
320.3629456	0.20
322.3841553	0.27
325.3456116	0.11
329.1826172	0.81
331.2216797	0.13
333.0817871	0.16
336.7753296	0.22
338.7000427	0.32
345.199707	0.11
345.9045715	0.81
349.1463013	0.41
358.7032166	0.40
360.186554	0.88
361.4490967	0.50
367.219574	1.39
369.3039246	0.12
371.0851135	0.16
381.1158142	0.83
383.1720886	0.11
385.1673889	1.06
386.1201477	0.19
388.2757263	0.19
393.4387207	0.16
394.6448364	0.48
403.3356934	0.29
404.8164673	0.27
406.173645	0.08
414.3157654	1.04
417.7949524	0.24
429.216217	0.52
431.3079529	4.70
433.7027893	0.36
439.2423401	0.44
449.0470276	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	365.19
Annotation	Unknow
Peak:m/z	Relative Intensity
111.9510040	7.58
140.1179199	8.81
158.0412292	100.00
179.0808105	0.44
233.3055420	1.12
263.1296387	0.70
281.5258179	3.25
317.1022339	0.95
320.0671997	15.86
330.1377258	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1921
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
121.8521271	0.08
129.0028076	0.19
137.0953827	0.22
138.1213989	0.08
143.1859131	0.15
148.9930115	0.04
151.2431793	0.04
152.9765472	6.41
158.9727020	0.28
161.0347595	2.74
179.0140991	0.29
187.0671692	0.33
189.0534821	0.07
198.4758301	0.11
205.2226715	7.07
223.0637207	11.44
246.9884644	0.09
264.9783020	0.19
265.6177979	0.11
276.9648438	0.07
284.4768982	0.05
287.2492371	0.08
295.1884155	0.22
307.2862244	0.03
385.1802063	100.00
385.8520203	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	2'-Methoxyflavone
Peak:m/z	Relative Intensity
76.79408264	0.23
77.93269348	0.47
79.7940979	0.57
80.97129822	1.37
82.91239929	0.47
90.74832153	0.19
93.9294281	0.23
94.78199768	1.78
96.35269165	0.19
97.02449036	0.39
102.9641418	2.13
104.829422	1.35
105.8920288	0.41
106.7903137	0.42
108.0084686	0.45
108.9785461	1.00
110.0701904	0.33
111.2342072	0.45
113.0034332	1.37
116.3015594	0.12
119.0177307	0.32
120.8089294	0.24
122.1338348	0.29
122.9689636	1.05
123.9568481	0.39
124.9497681	0.35
126.0626831	0.17
126.8453064	0.76
128.0011902	0.24
129.0114136	11.38
130.0189209	2.39
131.0726471	0.33
133.1304474	0.27
134.0126801	0.23
135.1676636	0.47
136.9980316	0.60
138.1948853	0.24
138.9891205	0.14
140.1129761	0.13
140.9903259	1.29
141.9328156	0.59
143.0137482	0.66
143.9782867	0.19
145.134491	0.09
145.9735107	0.91
146.8333435	0.56
147.9789124	0.17
150.9937592	100.00
151.895462	15.25
152.9125519	0.56
153.9485016	0.30
155.0924988	1.00
155.9992981	0.45
156.9740753	0.27
157.9445648	0.61
160.2390442	1.34
161.0682678	0.35
162.0217133	2.20
162.9363098	0.49
164.0597076	1.39
165.1616669	0.37
166.0565491	0.58
167.059433	2.22
168.0231781	2.59
169.1000977	2.73
170.1603546	0.67
171.2960052	0.53
172.0667572	1.11
172.8289795	0.12
173.9607697	0.12
175.4294281	1.51
176.1307068	3.23
176.8947449	0.32
177.9906158	0.81
178.9964752	2.82
180.0553436	0.78
181.1854095	0.72
182.0433502	0.66
183.0287628	0.86
183.9531403	0.31
184.9787292	3.32
185.7581177	0.42
188.1088104	2.50
189.8113556	3.13
191.0190277	1.32
192.1267242	1.38
194.0418396	2.32
195.0910339	0.89
197.0247955	7.91
198.315567	0.79
198.9396057	0.05
200.1210175	2.01
205.5396576	1.98
206.1425018	20.44
207.3547668	0.98
208.1144867	2.43
209.0468597	0.58
210.0237122	2.71
211.1366577	3.22
211.9425964	1.27
213.0571136	0.38
215.4603424	0.09
217.228714	2.50
218.0289459	10.45
224.4068146	3.29
225.1653442	10.13
226.1664276	4.57
231.1975861	0.23
235.2857513	15.23
236.1385345	31.14
237.087326	1.35
238.0037689	13.70
239.0778809	1.97
239.822876	0.94
241.7332611	0.32
245.3030853	2.99
251.0823975	1.53
251.9250946	0.29
253.0887299	59.38
254.221817	10.24
255.1078491	2.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.79911804	0.56
97.10432434	1.47
98.87940216	0.79
100.8288193	0.15
105.0091705	0.27
107.0771027	0.78
109.0778351	1.35
111.1483307	0.36
112.8128281	0.36
114.9473572	0.88
118.918541	0.25
120.9109879	1.23
123.0187759	1.86
124.9334869	1.24
126.9272156	1.09
128.9115906	0.84
130.8189392	0.79
132.9995117	1.41
135.1088867	1.49
137.0685425	0.77
139.1617432	3.79
141.1209869	0.21
142.9204102	2.17
145.0824432	0.15
147.0416565	0.52
148.9907227	1.47
150.9214478	3.11
152.9634399	1.70
154.9878845	1.15
156.9651031	2.29
159.0040894	0.94
160.9234161	0.32
162.9642029	0.66
167.070282	0.66
169.1778717	1.86
171.0265808	2.85
174.7900696	0.62
176.8479614	3.36
179.1114197	0.71
180.1303406	0.60
180.9730225	3.37
183.0208893	2.65
184.1229401	0.24
184.9291687	1.32
187.3823853	0.37
189.053833	1.55
195.2457275	0.55
197.2108154	0.41
198.1289978	1.55
199.1221161	1.12
200.8807678	1.21
208.9325256	3.14
210.9350891	1.68
213.0205994	1.51
221.0776367	0.95
223.0653381	4.40
225.0546875	1.94
226.9645996	1.88
229.4771118	0.23
231.3349304	0.55
233.1790466	0.78
235.197113	0.34
237.0184937	2.12
239.1778564	5.54
241.258728	0.79
247.0805664	0.15
251.0825806	2.72
253.0556641	7.73
257.1130371	1.18
259.5527649	0.36
264.0301819	0.35
265.1412048	1.37
267.1517944	0.86
269.2468567	0.36
270.1854553	2.11
270.9708252	0.17
275.2441711	22.93
276.5167236	0.33
281.6825256	1.06
283.3025513	3.64
284.1028137	0.29
293.2017822	100.00
294.0765381	0.77
295.2342529	0.89
302.2783203	0.94
311.1872559	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1222
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
127.3183136	0.02
132.9810333	0.02
134.9082336	3.17
135.9283752	0.35
136.9002838	0.09
138.9004211	6.32
140.0014343	0.47
141.1841125	0.02
142.9179688	0.03
144.9637604	0.13
147.0205994	0.43
149.0497742	0.03
150.9220428	4.47
151.9512634	0.70
155.2586365	0.04
155.9760742	0.04
161.0939026	0.12
162.9342499	2.05
164.0741272	0.16
165.1093597	0.08
167.0072021	0.25
169.0487976	0.06
170.0331879	0.03
173.9604950	0.02
175.0279083	0.11
178.0696411	0.02
179.1037598	0.22
181.1669312	0.10
185.3847961	0.03
189.0202026	0.21
190.9349670	0.04
193.1562805	0.33
194.0578613	0.03
201.0233307	0.16
203.1537933	0.05
205.1537781	0.08
206.5318604	0.10
207.1428223	0.15
213.3960114	0.02
214.1960907	0.02
215.2334900	0.04
217.1885986	0.16
219.1342163	0.17
222.1270599	0.04
223.1362305	0.03
225.0083466	0.03
229.1371613	0.11
231.2085266	0.07
233.3123474	0.07
234.5925293	0.03
235.2149963	0.18
241.1120911	0.08
243.1024170	0.48
244.0099182	0.08
244.9375000	0.04
246.0376587	0.02
247.1579590	0.34
247.9073486	0.02
249.1859436	0.07
253.1222229	0.15
255.0767822	0.13
259.1221313	0.62
261.1022949	11.66
262.2038574	2.14
265.1021423	0.24
265.9815369	0.07
267.2434082	0.10
271.1600952	2.93
273.0404053	14.72
274.1026917	2.45
275.0577393	0.06
276.1639709	0.03
277.0078125	0.16
277.9609375	0.03
279.1597900	0.01
283.0868530	1.01
284.0046997	0.11
285.2556152	0.09
286.2542114	0.09
287.1489258	2.16
289.0586243	100.00
290.1096191	15.14
290.7182922	0.08
292.2975769	0.02
295.0133057	0.98
296.4379578	0.13
297.2427673	0.05
301.0932617	1.76
302.1371460	0.28
303.2387695	0.03
305.0249023	0.11
307.1738281	0.10
309.4426270	0.05
311.1789551	0.19
313.0259399	4.72
314.1329956	0.85
317.1187439	0.22
319.1755371	0.18
323.1025391	0.20
324.2825928	0.05
325.1561584	0.69
326.2295837	0.11
327.2503967	0.15
328.1782837	0.07
329.1594238	0.26
331.1007385	1.61
332.2390747	0.51
336.9590759	0.17
340.3489685	0.07
341.1177673	0.10
342.3386230	0.04
343.5889893	0.16
347.4867554	0.04
351.0984497	0.10
355.1945190	2.14
356.2163086	0.63
361.1926270	0.14
362.2746582	0.04
367.1687317	0.26
368.0769348	0.10
369.1518860	0.11
371.1025696	0.05
373.2663269	0.02
374.1436768	0.01
376.4564514	0.05
379.2042542	0.87
380.3105469	0.09
385.2544250	0.21
386.4045410	0.06
387.4048157	0.20
390.2474060	0.04
397.1825867	1.57
398.1187439	0.25
403.4679260	0.07
406.3755188	0.04
407.0595703	0.02
408.2485657	0.07
410.0350647	0.06
415.1584167	3.18
416.2099915	0.86
423.8624573	0.09
427.3154297	0.04
433.1407776	3.96
434.1939697	0.57
436.1567078	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	183.0858
Annotation	Allitol
Peak:m/z	Relative Intensity
57.0726280	0.10
66.8180695	0.03
68.7721634	4.88
80.8828278	0.16
82.8395843	0.62
85.0672760	0.07
86.8438568	1.12
90.9135437	0.43
98.8684082	0.50
100.9007111	0.20
103.1656342	0.07
104.9102783	0.04
110.9345398	2.62
112.8298187	0.02
116.8940277	0.09
128.9857178	15.68
137.1324005	0.03
142.0711517	0.06
144.5058289	0.04
146.8328400	53.90
164.9260712	100.00
166.1464386	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.0759
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8832550	0.54
178.0846558	0.06
178.8925781	0.13
187.2904053	0.11
188.9258423	0.14
245.0156250	0.14
291.1507263	0.20
304.6838684	0.20
308.2025757	0.08
335.0887756	0.03
341.1840820	97.89
342.4983521	0.10
379.1564026	0.26
381.2039185	0.11
383.1000671	0.09
385.0939636	0.11
387.0247498	44.81
387.6731873	0.09
395.0536194	0.05
397.2175293	0.14
411.3648376	0.06
425.0409546	100.00
425.6941833	0.59
454.4866638	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
124.8741837	0.87
137.0178986	0.88
157.0567932	0.72
169.1686096	0.22
171.0718384	0.16
176.8741608	0.38
181.7232666	0.29
182.9268188	0.56
185.1808624	1.15
185.9693298	0.38
199.2027435	1.72
201.0832214	0.64
203.0620422	0.31
211.074707	0.31
213.0717468	0.43
215.1263733	1.24
227.1855164	4.53
229.1998291	1.12
231.1723938	0.43
239.3675232	0.41
241.0574646	0.64
243.1791077	1.07
244.1131592	0.36
252.980072	1.74
255.6325684	0.75
257.2338562	2.26
259.406189	0.41
261.2980957	0.24
263.2539368	2.19
267.475647	1.13
271.4456482	1.12
273.5576782	1.65
277.6582336	0.32
281.0443115	0.87
283.2373047	4.10
285.3294373	4.43
287.2664795	0.27
290.2107239	0.44
293.1795044	1.08
295.1600342	1.21
297.270813	3.52
299.296814	2.86
301.1910095	2.49
311.251709	1.39
313.2230225	3.03
320.4647522	0.34
321.4155884	3.43
323.2629395	9.06
325.3944702	3.83
327.3347473	1.45
329.2789917	1.65
339.2579651	100.00
340.1352234	1.54
341.3727112	17.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2782
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
137.1734161	0.08
195.9328613	3.33
197.1020355	0.13
214.1053772	1.55
215.0054321	0.09
237.1361084	0.16
241.043335	0.20
247.9977722	0.42
255.2351074	100.00
256.2669373	15.16
273.2197876	0.11
323.2947998	0.22
339.3124695	0.10
367.2034607	0.16
377.7572632	0.16
380.5766296	0.20
391.6051941	0.83
395.2036438	0.24
405.3858032	0.31
406.412262	0.87
407.4773865	51.89
409.2469177	0.78
434.9188232	2.76
435.5652771	0.70
454.8708191	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1716
Annotation	Folinic acid
Peak:m/z	Relative Intensity
148.8439178	0.15
163.2580109	0.10
194.8674927	3.12
195.8059387	0.12
203.0634308	0.10
213.1117859	0.09
239.9302368	0.16
245.1489563	0.08
261.1525574	0.29
262.1355286	0.08
264.8883667	0.03
282.0919189	1.41
293.3063049	0.04
301.3908691	0.38
304.1918945	0.07
308.3613892	0.07
309.7719116	0.35
315.3566284	0.07
320.1779480	0.03
327.1411743	100.00
327.8701782	0.40
345.2492371	18.68
346.4830933	0.13
355.0208740	0.08
356.2128906	0.06
358.3060608	0.06
359.2366638	0.06
378.7073364	0.16
384.1513062	0.05
389.7937012	0.08
402.2373962	0.05
411.3206787	0.23
412.1856689	0.19
419.4174500	0.09
428.0565491	1.21
429.1800537	0.08
430.3962708	1.33
438.1618958	0.30
439.1507874	0.17
454.2859192	0.07
456.2348938	12.57
457.3103638	0.10
458.9033203	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1765
Annotation	2-[4-(3-Hydroxypropyl)-2-methoxyphenoxy]-1,3-propanediol 1-glucoside
Peak:m/z	Relative Intensity
119.0766144	0.17
124.9046478	0.23
131.1179504	0.17
135.0160522	3.75
140.5944824	0.57
142.9775391	3.25
146.9190369	1.01
149.0219421	0.07
153.3279419	0.41
160.9897614	3.58
163.0902863	0.21
165.1622620	5.27
170.9643555	0.14
177.1148987	0.30
179.0106812	10.33
179.8860474	0.10
189.0221710	0.18
191.2158356	0.83
204.9934540	0.12
206.1144104	0.60
207.1078186	12.04
209.1418762	100.00
218.1310425	0.10
218.9786682	0.13
223.1921997	0.25
225.0725098	0.25
231.2677612	0.10
233.3462830	0.21
237.1406555	23.37
245.4529419	0.06
249.3799744	0.16
251.1391602	3.42
255.1419373	0.27
263.0411377	0.66
275.4114990	0.10
281.1409302	1.53
284.4304199	0.95
287.0491333	0.27
293.1395264	0.14
298.1780396	0.09
299.0279541	0.23
311.1054993	0.90
314.3268738	0.07
315.0479431	0.14
319.1504211	0.06
320.9114380	0.34
325.4621582	0.57
327.1593323	0.13
329.5148315	0.15
335.1664734	0.29
337.2908936	0.19
341.2542114	1.79
342.3203430	0.06
345.3391113	0.37
347.8724976	0.09
353.3492737	0.14
354.1210327	0.16
355.1008301	0.23
365.3330078	0.20
371.0185242	77.91
372.0120850	0.21
373.2207336	0.87
376.4349365	0.61
396.2771912	0.15
397.3154602	0.51
398.2556458	0.30
399.2576599	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1491
Annotation	Lactulose
Peak:m/z	Relative Intensity
108.8590927	0.46
111.0027008	0.10
126.8661804	6.69
136.0860596	0.19
144.9227905	5.91
152.0207520	0.18
152.7195892	0.27
156.0089874	0.46
162.1823273	1.15
162.8553925	6.27
179.9776764	5.00
180.8271027	0.32
185.2481384	0.29
197.1340332	0.11
198.1110077	4.46
201.1335754	0.09
210.7239075	0.10
211.9053497	0.18
213.1069946	0.20
214.9127502	0.18
215.9082947	0.38
223.0247498	13.65
224.0093079	1.52
227.0386658	0.41
228.1933899	2.11
239.9653320	0.23
241.0021057	0.15
243.0141602	0.12
245.1546936	0.26
246.6982727	0.40
248.0251160	0.16
253.0001221	2.29
254.6737671	0.44
257.4283142	0.34
259.0097351	9.44
263.0767212	0.59
263.7266235	0.60
264.3472290	0.13
265.1560059	0.28
270.1183472	100.00
271.0824280	1.37
272.2562256	0.29
276.3066406	3.05
276.9807739	3.74
277.8716431	2.86
279.0661621	1.61
282.3085327	0.26
285.5492554	0.42
288.3171387	1.39
288.9993896	16.82
294.1565247	24.91
295.7574463	0.64
298.3771057	0.18
305.6186829	0.89
306.9596252	11.73
313.1846313	0.40
314.0477905	0.31
316.0558472	0.39
320.4356384	0.10
322.3882751	0.20
323.5157471	1.41
324.2046204	40.08
324.9813843	66.84
326.2399292	0.21
342.3391418	30.42
343.0107117	24.31
343.7034912	0.13
359.3811340	0.16
369.3039246	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	gamma-CEHC
Peak:m/z	Relative Intensity
84.84810638	0.22
86.91508484	0.21
97.35982513	0.08
106.9371033	0.30
109.0176392	0.54
110.9603119	0.56
119.1372375	0.10
121.1782074	0.72
125.0997467	0.07
127.2377014	0.28
135.8868103	0.75
136.8297577	1.07
138.1716766	0.52
139.0707703	0.40
146.8228607	0.65
151.9409637	3.70
153.0210571	1.54
159.1608276	0.25
161.1846466	0.55
162.9765778	2.00
168.9798889	0.18
173.0946045	0.51
175.1603241	1.50
177.1842194	0.43
178.9823303	0.41
183.0365753	0.15
184.9451752	0.80
186.1608734	0.87
187.0601959	0.26
191.0462799	0.11
199.323761	0.20
201.2237091	30.67
203.2180176	0.83
204.1448669	24.93
205.1979675	0.42
216.9893646	2.90
219.1382751	100.00
221.2230377	0.19
235.0996094	0.45
237.3466339	0.32
245.1581421	11.83
246.8524017	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.2596
Annotation	(R)-1-O-[b-D-Apiofuranosyl-(1->2)-b-D-glucopyranoside]-1,3-octanediol
Peak:m/z	Relative Intensity
124.9853745	0.10
143.1038818	0.05
146.9864349	0.12
152.9413147	0.12
161.3174896	0.05
162.9792175	0.26
181.3208618	0.12
184.8729553	0.04
202.9485016	0.07
209.0094299	0.07
225.1249237	0.92
226.3110352	2.01
227.2593994	0.92
235.4692383	0.12
237.2419739	0.26
241.0416260	0.06
247.1249390	0.08
255.3233337	5.81
256.4743347	0.12
259.3786316	0.04
263.0966797	0.06
268.0267334	0.10
269.3435364	0.36
273.2228088	8.49
274.5395508	0.11
277.3191223	0.05
287.3293457	0.12
297.2469482	0.40
299.2073975	0.06
300.8166809	0.09
305.0420532	0.02
309.3025208	0.28
313.2210388	0.31
315.2279053	0.21
317.4133606	0.13
321.5140686	0.09
322.3115845	0.09
325.2267761	0.29
329.3087158	0.15
331.4260254	0.08
335.3107910	0.08
337.4616089	0.21
339.1265259	0.29
341.2521362	0.68
345.3912048	0.11
353.4098816	0.16
355.3524780	0.07
363.6658936	0.13
365.1531372	0.08
367.0920105	0.06
369.6445618	0.03
371.0758972	0.27
373.5580139	0.15
375.2674866	0.04
381.2145691	0.20
387.7811584	0.71
388.9996033	0.91
389.6049500	0.05
391.3916931	0.24
399.3405151	5.64
400.4510193	0.08
415.4502869	0.20
417.3489685	100.00
418.3629456	3.43
436.2008972	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1346
Annotation	Semperoside
Peak:m/z	Relative Intensity
110.8879395	0.41
112.7528152	0.43
133.0691071	0.18
134.9024048	0.06
150.9871521	0.18
153.0552673	16.72
154.0837555	3.69
156.8730774	0.06
164.9953308	0.12
168.2851868	0.09
187.0607605	0.07
197.0865936	100.00
198.0416412	22.89
211.0012512	0.08
212.1645203	0.13
218.0666199	0.31
226.0766907	0.09
235.1250916	0.14
238.6051636	0.36
239.237793	0.86
239.950592	0.07
240.9676819	0.05
244.2015076	0.20
245.0973206	0.07
247.0195923	0.11
251.42453	0.12
255.7508545	0.05
263.0635376	0.05
268.9251709	0.23
271.315918	0.10
273.1385498	0.06
291.4762268	0.08
296.354248	0.07
298.2515259	0.25
299.2979431	0.76
300.3024292	0.13
302.4077759	0.27
308.1817627	0.20
310.8396606	0.26
313.276123	0.48
314.1599731	0.79
315.2053833	0.32
316.2668457	0.62
316.9819946	0.28
323.2182617	0.24
325.2671814	0.15
330.0258484	0.10
339.1588135	0.58
341.2645569	1.41
342.3291931	0.41
343.1630554	0.36
344.2499695	0.32
345.2398071	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1436
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8665009	0.08
145.0152130	0.19
152.0281372	0.06
159.0299835	0.01
162.6283875	0.13
164.3327789	0.05
164.9751282	0.01
166.0787354	0.20
172.9848938	0.02
181.9030457	0.06
183.0705566	0.01
186.0754395	0.03
187.0172424	0.01
193.9260712	0.02
198.2871246	0.03
202.1907806	0.08
205.2216797	0.03
208.0629730	0.05
209.9298096	0.17
210.9695435	0.20
211.9766541	1.40
214.1931305	0.10
218.9747772	0.05
226.2096252	0.01
229.0481873	0.02
232.0238037	0.22
241.5852356	0.02
249.9621887	1.29
255.3199768	0.05
256.2201233	0.01
261.1018982	0.02
263.3052979	0.03
268.0406799	6.97
271.1187439	0.08
275.9875793	0.04
277.0270691	0.04
283.0680542	0.07
284.2703247	0.03
286.1158447	100.00
289.3190918	0.03
297.3538818	0.02
298.2254333	0.04
305.3016968	0.02
310.2473755	0.02
313.3632812	0.12
315.0272217	0.02
316.0231628	0.04
325.1063843	0.05
328.2084351	0.03
332.2528687	0.05
335.4798584	0.05
340.1213379	0.02
341.1242676	0.01
350.1809387	0.02
352.3036804	0.05
355.2265015	0.01
356.3800354	0.01
358.1011353	0.03
361.4942932	0.02
366.0482483	0.01
372.1395874	0.04
382.0974426	0.08
384.3883667	0.03
385.2443848	0.04
386.0138855	0.01
388.8850403	0.01
394.2367859	1.04
402.7221069	0.10
404.1128235	0.26
405.1607971	0.03
410.9353333	0.03
412.1606140	0.61
418.4882202	0.03
430.1567688	6.06
430.8912354	0.05
447.4876404	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2617
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
395.2554932	0.16
491.4242554	0.10
572.996582	0.02
629.2943115	0.07
739.4655151	0.05
845.2971191	0.06
847.2672119	0.05
965.0848389	0.01
983.4603271	0.01
1001.550537	0.02
1027.533936	0.06
1068.45752	0.02
1109.334839	0.08
1117.337891	0.06
1135.114136	0.19
1153.266968	100.00
1154.171875	0.01
1158.814209	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
111.0314026	0.80
114.8267517	0.24
116.9521484	0.25
124.7822571	0.43
139.1607971	2.45
146.3199921	0.67
149.0975952	2.86
150.1355743	0.69
154.1563721	0.22
162.0084991	2.76
165.0246277	0.58
167.139389	1.71
169.1828156	0.24
174.9823456	0.84
176.9658661	0.43
178.9983368	1.10
180.1119995	1.35
181.0594635	0.96
184.0793457	0.38
185.20784	0.14
190.0967255	2.34
191.0837555	0.58
192.1765442	2.91
193.2075348	1.65
195.4152679	0.65
204.0697174	0.40
206.1473236	4.78
207.1913605	12.66
208.0895233	13.46
209.0452423	5.27
211.2598877	0.53
220.91716	0.58
221.9751129	5.10
223.1207733	18.21
223.9160919	3.44
225.2765503	0.40
233.1355438	4.00
234.0087738	6.15
235.0522614	0.65
251.081955	100.00
252.1220245	33.21
253.1917725	5.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.1518
Annotation	Unknow
Peak:m/z	Relative Intensity
97.9450684	0.13
98.6744843	0.13
120.8571014	0.09
122.2113037	0.12
124.9868393	0.09
127.8348541	0.19
131.0537720	0.08
131.8480072	0.03
137.2333679	0.20
137.9989777	0.20
142.8264618	0.30
147.0964355	0.08
148.9528198	23.28
153.2128601	0.05
158.7228088	0.08
160.8756104	0.09
162.8801880	0.27
166.8114471	0.18
171.0460815	0.25
175.1554718	0.07
176.0983429	0.12
181.9989624	0.07
183.1530457	0.06
188.9202576	0.06
189.6568909	0.28
192.3709717	0.24
193.0863495	1.07
194.6950989	0.08
197.9864349	0.05
200.7466888	0.11
204.9996948	100.00
206.1868896	0.02
210.8805542	0.91
216.4259949	0.06
221.7399597	0.06
222.9392090	0.08
236.9454651	0.09
238.2384644	0.19
249.3577576	0.22
250.4834290	0.04
253.7402344	0.40
255.9433899	0.06
262.0911560	0.20
263.3503723	0.04
269.0282898	0.29
269.7828369	0.12
273.2033997	0.04
276.4991150	0.06
280.8547668	0.77
284.1123047	0.07
289.1271362	0.05
294.3501282	0.19
298.0280762	1.04
298.8887939	0.04
299.5266113	0.10
300.2604675	0.07
303.0815125	0.18
307.4122925	0.11
308.6624756	0.79
309.4362488	0.10
312.0559082	0.09
314.1408691	0.21
314.9173889	0.11
315.6511536	0.11
321.8647766	0.07
323.3513794	0.10
325.7984009	13.23
326.4671021	0.31
327.1237183	1.70
334.6760254	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.2233
Annotation	HC-toxin
Peak:m/z	Relative Intensity
127.0270615	0.04
130.9850464	0.28
138.9374695	0.05
141.1867981	0.11
143.0151978	0.10
155.1640778	1.37
156.0376740	0.03
157.0059814	0.03
158.7941742	0.03
161.1576691	0.13
165.9971619	0.03
167.0728302	0.03
168.0141907	0.03
170.2109833	0.03
170.8652954	0.08
173.1166687	2.87
174.3315125	0.15
175.1719971	0.08
178.9918213	0.03
181.2301331	0.02
185.3934937	0.04
191.1890869	0.06
195.2039185	0.11
199.8282776	0.03
201.1368713	0.40
207.9773560	0.03
209.9223328	0.17
211.3088074	0.05
213.2852783	0.19
215.0065308	0.08
217.4422455	0.06
218.1188354	0.05
219.0303650	0.32
223.0470428	0.05
227.1836700	0.15
228.2526703	0.17
231.4888916	0.02
234.2826538	0.05
237.0788727	0.38
238.2452087	0.12
239.4133301	0.08
252.5214539	0.07
253.2673950	0.09
255.2739563	1.24
256.2253723	0.27
256.9534302	0.04
269.3408203	0.07
271.1128845	0.18
272.0147705	0.20
273.2213440	2.79
274.3309326	1.08
275.2115479	0.10
279.3365784	0.03
281.3259277	0.08
295.5317688	0.03
297.5342712	0.02
298.1743774	0.14
309.3612671	0.02
314.9704285	0.08
317.2573242	15.49
318.3219604	1.29
319.2963257	0.07
325.4023743	0.06
329.0616455	0.06
331.9920044	0.02
335.2366333	100.00
336.2782593	16.27
337.2305298	0.02
341.0618896	0.01
343.1060181	0.04
345.3200073	0.06
347.8673096	0.05
352.1986389	0.07
355.6215820	0.14
357.3589172	0.04
359.4883423	0.16
360.2936707	0.20
361.3584290	0.05
363.3225708	0.31
369.9425964	0.04
371.4217224	0.14
373.2764587	0.12
375.1860962	0.19
389.2968445	1.15
390.2729187	0.99
391.0859680	0.56
392.0752869	0.35
399.3328552	5.09
400.2413025	0.43
415.6054993	0.08
417.3113708	15.35
418.3841858	3.09
419.5450745	0.67
422.5117493	0.04
437.7555847	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.2339
Annotation	Euodionoside E
Peak:m/z	Relative Intensity
152.0091705	0.01
153.1127625	0.02
153.8626709	0.04
161.1533813	0.02
176.7617188	0.01
197.2356262	0.01
199.1544800	0.02
201.3956909	0.01
202.0885315	0.01
219.3554688	0.02
221.0654602	0.05
223.2130890	0.01
224.3807678	0.01
226.9399414	0.02
231.3189087	0.02
234.0322266	0.01
237.4684601	0.01
239.3157349	0.02
241.0508728	0.12
243.0700684	0.02
263.0094604	0.01
264.1170959	0.06
273.0700073	0.03
281.2699890	0.04
282.2932434	0.01
285.1376648	0.59
297.4321289	0.01
300.2045288	0.14
301.1916504	0.62
302.2265625	0.69
303.1381836	0.17
305.4011536	0.01
315.3251343	0.01
317.1963196	0.01
325.3959351	0.02
329.0299683	0.01
331.1765442	0.04
332.2358398	0.03
339.1957092	0.07
343.1889954	0.01
343.9812622	0.02
345.1076965	0.04
346.2445374	0.01
359.2898560	0.01
362.3452759	0.01
369.2286682	0.04
374.7745056	0.02
375.5639954	0.00
377.4510803	0.01
381.2773438	0.02
383.5848694	0.02
386.5383301	0.01
394.2664490	0.01
399.5231018	0.03
400.4299011	0.06
401.4603271	0.05
403.9322510	0.01
404.8636169	0.02
416.9668884	0.01
419.3410034	100.00
420.4570007	0.03
421.3923035	0.02
423.2700500	0.01
426.1759949	0.06
427.1413269	0.01
429.3230286	0.02
431.4284363	0.03
432.5489197	0.02
437.5360413	0.02
443.2267761	0.01
444.4187622	0.10
445.3209534	0.08
447.1102600	0.79
447.7736206	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9638672	29.55
212.8544006	14.46
274.7723083	0.19
296.6575317	100.00
297.3449097	0.73
352.1984558	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1223
Annotation	Marein
Peak:m/z	Relative Intensity
126.8458862	0.04
133.9492645	0.14
134.9035339	2.98
135.7073059	0.21
137.0252228	0.31
138.960434	7.64
144.9872894	0.08
146.9292145	0.32
148.7733612	0.16
151.0171356	4.80
154.7832794	0.15
160.1694641	0.10
161.0144043	0.07
162.906601	2.42
165.2115173	0.09
167.0023804	0.28
177.3245239	0.11
179.0721436	0.48
180.9550476	0.09
184.0063171	0.05
185.2975159	0.26
187.0922241	0.06
189.0531921	0.27
191.0581055	0.10
193.0601654	0.86
195.1118469	0.05
196.8886108	0.08
201.0916443	0.44
203.1373138	0.09
204.988678	0.27
207.0579224	0.43
213.1374512	0.13
214.9183502	0.14
219.1592865	0.40
225.2138824	0.07
228.8957367	0.16
231.0582275	0.37
235.1109772	0.49
242.9894409	0.34
245.2088013	0.09
247.1612854	0.30
253.0838013	0.28
259.0607605	0.41
261.118042	12.68
263.1143494	0.05
265.1153259	0.19
266.8605042	0.08
269.2314758	0.09
271.0876465	3.76
273.1109924	13.84
277.025238	0.17
283.1702576	1.08
283.9381104	0.06
285.1723328	0.10
287.1160889	19.06
288.1411133	35.95
289.0767212	100.00
294.0827026	0.04
294.9591675	0.89
295.9973145	0.07
299.2738037	0.27
301.1473389	2.34
303.3226318	0.03
304.3253174	0.03
305.1802673	0.07
307.3344116	0.11
309.0402222	0.07
311.1539917	0.05
313.188385	4.08
317.0228271	0.13
319.2802734	0.05
320.0476685	0.08
322.9111328	0.38
325.1351318	0.83
326.4755249	0.11
327.078949	0.06
329.2045288	0.57
330.0907288	0.04
331.1708984	2.31
341.197937	0.36
343.2835999	0.04
347.3361511	0.13
348.6400146	0.05
350.6393738	0.09
355.2269287	3.27
359.0076294	0.10
360.1698608	0.26
361.2164917	0.22
364.4841919	0.09
367.209198	0.48
369.2918091	0.03
373.0331726	0.03
377.1689148	0.10
379.0313416	0.22
385.203186	0.42
391.0730286	0.04
393.1360168	0.09
397.160675	1.73
398.8220215	0.02
404.2765198	0.04
405.3330383	0.24
409.1088257	1.55
410.1896973	0.88
412.4827576	0.05
415.0836182	4.46
420.7037048	0.10
422.8009949	0.04
426.575531	0.09
427.287323	0.02
431.3258362	0.08
433.2124939	4.31
436.2694397	0.28
441.377655	0.10
450.9643555	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.2424
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
118.9047546	1.72
120.9619904	0.31
122.9942703	0.29
124.9662857	0.07
133.0316772	0.85
135.1413116	0.23
137.0240479	0.70
144.8482666	0.12
148.5087891	0.07
149.8766785	0.18
150.7254944	0.15
155.0449677	0.04
161.0591278	9.43
163.1046143	0.15
166.9042664	0.04
179.1265564	27.58
180.0606689	0.09
185.1794281	0.13
195.2861633	0.17
197.0718994	31.21
199.3569489	0.08
206.1277771	0.19
208.3393707	0.06
214.8939972	100.00
215.5050507	0.28
219.0833588	0.19
220.3010406	0.04
230.5982361	0.11
238.9662781	0.03
242.2059021	0.03
252.9536438	0.23
257.4302368	0.10
260.2763672	0.29
262.1663818	0.06
283.4125977	0.11
290.1031494	0.08
297.1151123	0.36
301.2176819	0.16
304.3477478	0.04
309.3296204	0.40
313.1304932	0.51
313.8230591	0.11
317.9165039	0.06
319.9770203	0.13
321.7685547	0.29
331.7443237	0.04
340.3493042	0.13
347.3721313	0.12
348.8041992	0.05
350.0996704	0.20
351.0175171	0.04
359.1882019	0.04
363.7677002	0.50
365.3443298	0.07
372.0254822	0.18
374.4788818	0.30
376.1152344	7.10
376.9106140	18.43
379.3947144	0.16
384.8633728	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.2
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
243.0297241	0.11
245.1279907	0.25
269.182251	0.04
272.9940491	0.25
279.9181519	0.10
287.1125793	1.56
288.4228516	0.23
289.2432556	0.90
290.0402222	0.07
293.1130981	0.04
299.2227783	0.16
301.2917175	0.05
315.3850098	0.15
320.424469	0.09
330.3495483	0.21
332.0852051	0.05
341.2538452	0.08
359.3204041	0.07
388.3308105	0.08
391.2635498	0.03
394.9442749	0.20
395.8591919	0.12
405.2672119	0.40
406.3010254	0.07
407.2039795	0.59
408.3726807	0.15
411.0956421	0.13
412.0994263	0.19
413.1225586	0.28
414.4847412	0.05
421.3374634	0.04
423.5650635	0.32
424.8391113	0.62
433.1918335	0.05
434.3189697	0.20
437.3342285	0.15
438.1481934	0.10
449.1946411	0.70
450.2623901	0.05
451.1361694	0.21
452.3190308	0.06
457.4731445	0.10
477.3610229	0.13
492.4543457	0.45
494.9534302	0.39
525.2623901	0.62
527.6094971	0.25
531.2495728	0.13
533.5611572	0.05
540.3035278	0.61
541.0457764	0.20
541.6629028	0.06
542.3155518	0.18
543.3395386	0.14
549.173584	0.17
553.3319702	0.15
557.2671509	0.30
558.0359497	0.11
559.2001953	0.67
561.2351685	0.21
569.1588745	0.33
572.6745605	0.28
574.1735229	0.27
575.2245483	1.33
576.3126831	1.46
577.3043823	0.83
578.213501	0.13
585.2692261	0.55
586.5604858	0.42
606.1448364	0.08
622.4503784	0.04
627.8208618	0.04
629.3024292	0.10
631.5055542	0.48
634.713623	1.61
635.3825073	0.37
643.7559814	0.21
656.2982178	0.17
662.8895264	0.19
665.7166138	0.11
672.6603394	0.25
680.1902466	0.20
684.5647583	0.08
693.2138672	0.29
694.3493042	1.33
695.416748	0.50
698.4478149	0.50
700.5559692	0.19
701.1897583	0.94
702.2012939	0.12
703.2377319	0.53
704.2039185	0.44
711.437439	0.64
712.4414673	0.05
713.5346069	0.20
714.2113037	0.11
716.0140381	0.62
716.8313599	0.08
719.2614746	0.33
720.3235474	0.52
734.4106445	0.04
736.588623	0.31
737.3626099	0.70
738.5039062	0.49
739.1289062	0.51
740.397644	0.13
742.3743286	0.14
744.6737671	0.06
750.8435669	0.29
755.6116943	0.07
766.4459229	0.05
770.3838501	0.15
771.3310547	0.66
777.555603	0.08
779.1665649	1.41
779.8132935	0.36
785.2232056	0.09
788.0852661	1.78
788.7700806	0.42
793.2597656	0.16
801.3128052	0.77
802.0095825	0.81
807.7385254	0.03
814.1930542	0.69
821.284729	0.08
837.0692749	0.19
841.4107056	0.05
843.2627563	0.18
843.8858643	0.53
845.4372559	0.38
846.5949707	0.34
847.2628174	0.07
863.0083618	0.19
865.2041626	100.00
866.0761719	0.98
866.94104	0.55
869.1826782	0.40
905.477478	0.07
918.3899536	0.05
945.7839355	0.08
957.6506348	0.13
975.0039062	0.25
982.3942871	0.12
983.2997437	0.17
984.7721558	0.24
989.4107056	0.70
991.2893066	0.24
997.3244629	0.09
1001.483948	0.16
1007.166077	0.20
1012.068542	0.23
1025.415405	0.17
1026.939697	0.80
1027.628418	0.26
1031.371338	0.08
1043.732788	0.08
1050.61084	0.13
1052.446533	0.07
1059.531006	0.06
1067.352539	0.16
1068.629517	0.22
1090.401489	0.13
1133.405273	0.07
1135.523804	0.47
1136.174561	0.41
1143.48877	0.09
1148.271484	0.49
1151.239258	1.57
1152.171631	0.31
1153.351929	1.05
1154.275269	0.48
1155.329102	0.34
1163.360107	0.27
1165.438965	0.20
1178.252197	0.07
1187.17981	0.14
1189.032715	0.19
1196.298096	0.16
1227.356445	0.05
1228.302002	0.41
1268.288208	0.16
1272.140991	0.47
1273.451294	0.14
1277.211792	0.38
1280.1073	0.17
1287.144897	0.16
1290.340576	0.10
1295.972534	0.23
1297.916016	0.04
1298.566528	0.22
1313.287109	0.27
1313.966431	0.27
1315.485229	0.30
1318.405884	0.05
1331.613647	0.03
1423.06897	0.25
1433.264526	0.05
1439.510376	0.43
1440.241821	0.15
1440.84729	0.58
1442.040405	0.76
1452.779907	0.22
1458.846313	0.04
1477.124268	0.26
1483.495239	0.04
1484.636475	0.11
1587.113159	0.17
1602.887573	0.25
1604.06604	0.61
1605.279053	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8974
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0197144	0.70
174.9525146	1.43
199.0406799	0.08
214.9738617	0.08
217.2545166	0.03
245.0228882	0.37
269.0168762	0.13
273.0303345	7.71
289.0075073	24.81
328.9723511	0.03
386.8957520	0.87
400.1109009	0.05
400.8569336	0.18
402.9194946	100.00
403.5221558	0.58
428.1386108	0.10
442.1130981	0.07
443.2629395	0.03
470.8926392	0.55
471.5180054	0.05
472.2006836	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.83
Annotation	Unknow
Peak:m/z	Relative Intensity
231.1553955	0.05
244.9369507	0.03
286.9406738	0.04
345.0061035	0.12
351.5437012	0.06
364.4307251	0.05
372.9125977	1.03
373.9912720	0.07
379.1486206	0.04
380.9797974	0.04
384.6770630	0.12
385.9829102	0.12
387.0437622	2.13
394.2135620	0.06
401.0579224	0.06
402.9085693	0.60
404.7013550	0.01
415.0042114	0.07
426.9199829	0.51
430.7091064	0.79
432.7069702	0.07
435.2306519	0.03
439.0739136	0.08
440.8194580	0.06
444.7626343	2.89
445.3774414	0.05
447.0232544	0.26
463.0438232	4.88
472.9262695	0.03
482.8403931	0.04
488.9810791	0.21
490.8662720	100.00
492.9370728	0.07
506.9498901	0.04
508.8934326	14.61
510.3430786	0.03
514.8358765	0.08
531.2939453	0.03
532.0393066	0.12
536.3218384	9.06
536.9308472	64.10
554.3606567	0.10
554.9902954	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.13
Annotation	Procyanidin B2
Peak:m/z	Relative Intensity
161.0539246	0.84
164.0697174	0.24
175.1033173	0.16
176.1102448	0.10
177.0059814	0.05
178.8563385	0.86
180.1579437	0.11
183.1945496	0.07
186.0281677	0.20
187.0555115	1.17
198.9136505	0.13
203.0680084	2.23
204.9845734	0.86
206.1286316	0.14
207.1404724	0.11
212.2209167	0.10
217.0673523	0.51
217.936203	0.25
225.3886108	0.07
227.0579224	0.73
228.1400146	0.55
229.0504608	0.91
230.1575623	1.39
231.187027	1.31
239.0114441	0.22
240.0530548	0.28
241.0765991	0.52
243.0716248	3.24
243.9825745	0.43
245.1454163	10.65
246.1973419	2.28
247.2229614	0.56
254.0425415	0.32
255.1435852	0.24
256.3753662	0.09
257.0479126	0.26
261.089325	2.38
262.1454468	0.17
263.118866	0.12
266.447876	0.24
267.2165833	0.24
269.0859985	1.47
271.3312988	0.40
273.0696411	3.97
275.0253601	0.04
280.1397095	0.23
281.2576294	0.11
283.0544434	0.38
284.9442139	1.58
286.0767822	1.18
287.145874	14.93
289.0687866	66.71
290.1342773	6.86
291.0347595	0.17
293.390625	0.05
298.1774902	0.24
299.2287598	6.52
300.1913452	0.08
301.1288452	0.26
302.0903931	0.21
303.2900391	0.10
304.1763916	0.33
304.9476318	0.17
308.6177979	0.95
309.2452393	0.26
310.2745361	0.11
311.5178833	1.37
313.2791138	0.30
318.4055786	0.08
321.1453857	0.20
322.9351807	0.05
327.1672974	0.61
328.3464966	0.35
329.3746948	0.95
330.1561279	1.17
331.3158569	2.22
331.9294434	0.08
334.2399902	0.24
335.4810181	0.07
338.484436	0.27
339.2265015	1.45
341.168335	0.37
342.4802856	0.11
343.1068726	0.05
347.1553345	0.27
348.1053467	0.20
349.3258057	0.09
350.4353027	0.32
351.7600098	0.51
352.3707275	0.63
353.1626587	0.54
355.3334351	0.06
356.2908936	0.37
357.4154663	0.18
361.2304688	0.23
363.0452271	0.28
364.4102173	0.06
366.3171387	0.20
368.0540161	0.11
369.2648315	0.48
370.2543335	0.06
371.0804443	0.35
372.2059937	0.70
372.9436646	0.10
375.2642822	0.14
376.2445679	0.35
378.9122925	0.53
380.0705566	0.09
381.2546997	1.89
383.2362671	0.11
384.496521	0.13
388.3444214	0.19
391.5539551	0.22
392.3114014	0.67
394.0442505	0.05
395.1149292	2.65
396.1741333	0.20
397.4208984	0.97
398.1807251	0.05
402.0925293	0.22
405.2108765	2.15
407.088501	100.00
408.2723999	2.49
409.2856445	1.41
410.2920532	0.30
411.190918	0.32
413.1506958	5.90
414.2696533	5.24
415.3935547	6.55
419.4563599	0.08
420.3901367	0.40
421.1999512	0.36
422.1369629	0.36
423.2692871	4.91
425.098999	90.06
426.0650635	0.07
427.31604	0.61
429.2097778	0.33
430.2837524	0.10
431.8064575	0.12
432.5750732	0.37
433.4186401	0.84
434.1203613	1.40
435.440918	0.41
436.5804443	0.93
437.3560181	0.25
438.0498047	0.10
445.2225952	0.18
447.3182373	0.25
449.1171875	7.11
450.3939819	4.93
451.2850342	31.96
452.3319092	3.53
453.2605591	0.39
454.4309082	0.48
455.2652588	0.40
465.2984619	0.27
466.7840576	0.94
468.0821533	0.26
469.8007812	0.46
470.4554443	0.58
471.4960327	0.16
475.1044312	0.10
478.263916	0.61
481.1453247	0.31
482.2883301	1.98
482.9070435	0.93
486.1487427	0.12
487.3657837	0.14
489.3037109	0.15
491.4685059	39.98
492.2279663	2.77
493.1645508	0.10
495.3672485	0.13
497.442627	0.24
500.4142456	32.21
501.2544556	2.88
502.1135254	0.12
503.3308716	0.23
505.3401489	0.18
509.2935791	0.34
510.3150024	0.09
512.3886108	0.46
513.2859497	0.77
514.197998	0.79
515.2868652	0.07
516.2959595	0.35
519.1151123	0.06
522.4747925	0.44
523.3690796	0.56
524.237915	0.05
525.4567871	0.12
529.30896	0.41
531.1513062	3.73
532.3863525	1.17
533.2526855	1.75
534.0049438	0.37
539.1659546	0.22
540.1855469	0.56
541.3150024	0.32
543.3863525	0.11
544.3807983	0.19
545.3179321	0.12
549.4628296	0.08
550.2947998	0.27
554.5480347	0.14
555.2510986	0.07
557.1987915	1.82
558.5678101	2.62
559.3473511	11.34
560.1849976	0.22
561.6445312	0.12
562.6998901	0.08
567.6353149	0.10
576.2362671	0.20
577.3465576	0.33
578.3029175	1.03
579.237854	0.33
587.2501221	0.51
591.166626	0.06
601.3741455	0.43
616.5796509	0.29
617.2294922	0.21
618.3341675	0.14
619.2312622	0.38
620.3343506	0.60
626.9559937	0.23
629.4222412	0.31
635.0098267	0.31
637.1800537	0.18
651.1824951	0.56
657.2191162	0.22
661.6369629	0.56
667.1528931	0.24
669.4776001	0.19
677.2706909	0.60
678.2819214	0.25
680.7067261	0.26
683.4690552	0.06
684.5097046	0.14
687.5161133	0.57
688.385437	0.06
693.2611084	2.31
694.2493896	1.00
695.3355103	2.64
696.4387817	1.24
697.2265625	0.57
698.5462036	0.43
701.2658691	5.24
702.2505493	2.33
703.0880737	0.40
708.2252197	0.06
711.3751831	0.14
712.0421143	0.40
713.5410156	0.40
714.3265991	0.09
719.5803833	0.07
721.3240967	0.19
722.4492798	0.23
729.6397705	0.32
737.1607056	2.56
738.4070435	1.46
739.3273315	5.71
740.3311157	1.91
741.338562	0.87
781.3532104	0.22
787.6246338	0.24
790.0393677	0.46
791.5583496	0.06
803.3361206	0.29
804.1170044	0.15
805.1425781	0.15
806.9819946	0.12
819.0408936	0.31
820.991394	0.42
822.3657837	0.46
823.1956177	0.30
831.5959473	0.57
832.3657837	0.07
839.1968384	0.28
840.210022	0.14
841.4657593	0.34
845.1008301	0.68
846.2629395	0.10
847.3840942	0.11
847.9921875	0.05
848.7571411	0.21
857.4561157	3.90
858.3983765	1.16
859.3471069	1.06
863.2075195	21.27
864.2301636	11.58
865.3771362	6.19
866.3181152	1.15
867.2678223	0.26
875.0546875	0.11
875.8657227	0.09
877.0944214	0.32
889.4673462	0.17
905.6669922	0.36
907.2913208	0.97
908.328186	0.81
909.3810425	0.12
939.0973511	0.23
958.5205688	0.09
983.1686401	0.62
983.9463501	0.08
984.5993042	0.10
1001.688721	0.68
1002.592834	0.27
1009.176331	0.86
1010.602966	0.38
1011.279846	0.10
1027.324707	10.56
1028.309814	10.05
1029.463135	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.1241
Annotation	Histidinyl-Tyrosine
Peak:m/z	Relative Intensity
117.0045776	0.19
124.9671021	0.09
134.8735809	0.23
137.1324768	0.37
151.1384583	0.04
155.0401611	28.47
181.0862885	0.20
182.9992981	0.04
199.0436707	100.00
200.2757416	0.11
203.2251587	0.03
208.0153198	0.04
209.0649109	0.03
213.1750183	0.07
219.0246277	0.05
225.0696106	0.29
237.0525513	0.32
243.3574219	0.03
255.2791138	0.81
257.0861511	0.08
259.2003784	0.03
271.1076355	0.26
273.1253052	0.35
281.2057190	0.25
283.1132202	0.25
284.0646667	0.30
288.1222229	0.08
289.1448975	0.42
297.4773560	0.04
298.1732178	0.02
299.2478943	1.23
302.3797302	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.1967
Annotation	Unknow
Peak:m/z	Relative Intensity
270.6793213	0.34
277.1111145	4.86
279.2156372	0.90
280.0614014	3.84
289.0867615	10.86
294.9696045	0.25
307.1779175	1.66
324.9561768	8.26
336.8453369	1.73
342.9255981	0.42
354.6151733	0.68
370.1832275	32.54
378.9490967	1.12
395.8217773	0.28
396.9395142	9.52
398.0875854	0.58
451.0557251	2.11
456.1055298	1.04
456.8266602	2.25
459.9458618	1.90
486.9967651	3.70
516.7599487	7.96
517.5161133	0.55
541.1609497	100.00
541.9603882	1.11
542.8348999	1.08
546.8601685	0.66
558.3707275	2.09
559.1468506	0.44
574.6661987	0.83
576.9213257	10.08
578.5357666	1.03
722.1351318	1.14
737.8829346	1.17
739.0224609	39.73
740.1225586	3.00
1081.0559080	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2604
Annotation	Alangionoside O
Peak:m/z	Relative Intensity
178.1408234	0.03
178.8294830	0.05
180.2223816	0.02
194.9573669	0.03
207.1245422	0.02
214.2416992	0.05
257.2784424	0.05
270.8834534	0.02
281.0337524	0.02
333.1015625	0.02
365.7217407	0.05
373.3070068	0.11
375.2797852	4.10
377.4990845	0.04
394.4809570	0.04
396.2084961	0.03
403.3978271	0.80
404.5578003	0.09
420.2966919	0.09
421.2882080	0.58
421.9577637	0.10
449.1925659	0.08
453.8408813	0.06
463.5911865	0.07
473.7139282	0.04
479.2758179	0.11
487.5457153	0.02
498.8963013	0.03
506.6759644	0.11
525.1387329	0.06
535.5222778	0.08
537.2993774	100.00
537.9297485	0.35
539.2586670	0.11
547.2935791	0.02
564.4783325	0.16
565.3432007	0.26
573.4067993	0.03
583.6658325	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1033
Annotation	Zidovudine
Peak:m/z	Relative Intensity
86.0063477	0.01
87.1296387	0.02
87.9349594	0.04
105.9872131	0.03
108.9235535	0.02
112.9457855	0.02
123.8214569	0.02
134.0613403	0.12
135.9013519	100.00
136.8079681	0.05
138.1091003	0.02
139.8947144	0.04
149.9544525	0.05
196.8021698	0.01
200.5881195	0.01
212.2400665	0.06
223.0366211	0.03
224.1828461	0.02
226.9662628	0.08
232.1821747	0.08
237.7996216	0.02
240.1329498	0.05
249.4993134	0.08
250.3628082	0.06
258.6285095	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1427
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
81.0740814	0.03
82.8840256	0.04
91.0220795	0.07
93.0424957	0.38
94.9894867	0.35
96.9130249	0.66
98.8821716	0.10
100.1620178	0.08
103.0132599	0.06
104.9399109	0.25
106.9109955	0.75
108.9983826	1.34
110.9188232	1.61
112.8858490	0.88
114.9488831	0.02
118.9899445	1.42
120.0914459	0.10
120.9168091	1.74
122.7730560	0.39
125.0675201	0.43
127.0059357	0.08
131.0743103	0.34
133.0699158	0.45
135.0580444	5.94
137.0380707	2.92
138.9960175	1.74
141.0377197	0.04
143.2665100	0.08
144.2833557	0.10
145.0956421	1.06
147.0583344	1.68
149.0424042	1.27
150.9878235	0.44
153.0673981	0.12
155.0176544	0.62
157.0261383	5.01
159.0554047	3.11
161.0329742	4.55
162.9285736	0.34
165.0446472	1.92
167.0560455	1.09
167.9236908	0.03
168.8738251	0.05
171.1187592	0.93
171.9105377	0.03
173.0774078	2.29
174.9753113	13.97
177.1754303	0.20
177.9623871	0.13
180.9969635	0.14
183.0481415	0.75
185.1994781	2.24
187.1086426	6.10
189.0648041	3.22
191.0862732	0.26
193.0709229	10.37
194.3067322	0.06
195.3175049	0.08
196.1818085	0.02
199.1290131	1.15
201.1224213	4.84
203.0021057	13.64
203.6040497	0.08
205.1557465	2.17
207.1387939	0.61
209.0681915	0.33
211.0453644	6.47
215.0869446	0.03
216.5095062	0.46
217.1340790	10.07
219.1132660	5.52
221.1414948	1.09
223.1115265	0.26
224.0743866	0.11
229.0847931	15.51
233.0861359	0.07
235.0698853	8.88
237.2414093	0.52
238.1447906	0.04
245.1616211	0.10
246.9536285	100.00
247.5875702	0.24
249.3833771	0.24
250.2042999	0.24
255.4873199	0.32
265.1553955	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	428.148
Annotation	Unknow
Peak:m/z	Relative Intensity
121.0177307	0.21
124.9193726	0.08
127.8729248	0.09
133.8203888	0.03
135.1322327	0.08
135.9167175	0.28
136.8514862	0.03
148.2696228	0.16
151.4050751	0.61
152.0974579	0.02
161.9842834	0.35
163.8849792	2.11
165.7807159	0.02
167.9376526	0.07
169.1407471	0.44
170.0015564	0.16
173.9441528	0.12
175.8876953	0.27
177.0117798	3.46
177.9788361	0.10
179.9112549	0.25
183.8775940	0.28
185.0726776	0.21
185.9007568	1.06
188.1296387	0.04
189.9107666	0.31
191.8476562	0.07
193.9064484	0.06
194.9851990	0.04
198.1469421	0.06
199.9636841	0.25
202.0839844	0.10
204.2369080	0.05
205.1426086	0.29
206.0010071	0.71
207.9600372	5.87
208.9840240	0.08
209.9055786	0.27
214.0422211	0.27
215.8809509	0.74
222.1504059	1.21
223.9225159	1.86
225.9155731	0.36
227.3820343	0.03
228.0197449	0.12
229.7330627	0.18
232.1087952	5.26
233.2575073	0.28
233.9985657	0.42
235.1915588	0.14
237.0880432	0.04
239.7668457	0.07
244.1240234	0.14
246.1035461	0.85
247.9611206	4.74
250.0378723	16.90
251.1535950	21.81
252.0895691	0.37
253.0672913	0.08
257.6481018	0.07
259.1347656	0.45
260.0744324	0.39
261.0619812	0.59
262.1228638	0.25
262.9967041	0.16
264.1813354	1.32
266.0906677	100.00
267.3543091	0.83
268.2554932	1.24
268.9725647	0.81
271.1037903	0.12
274.0046692	0.31
276.1561890	0.13
277.8601074	0.18
279.3439636	0.14
280.4165649	0.06
281.3332214	0.47
282.2672729	0.22
283.3642883	1.95
284.0333252	15.84
284.6755371	0.18
287.1879578	0.03
287.9864197	0.14
290.0597534	0.27
292.1989441	0.36
294.0000000	0.87
295.2075195	0.31
295.9520264	0.08
300.0910950	0.17
302.0723267	1.42
304.1444092	0.13
305.2103882	0.08
306.1783447	0.61
306.8601990	0.26
308.1892090	5.34
309.1466064	0.29
310.0696411	0.32
313.0803528	1.06
314.3164062	0.04
317.3344116	0.09
318.3489990	0.16
320.2021484	1.17
321.3072205	2.35
322.1586914	7.73
324.2126465	0.63
326.1671143	26.27
327.0618591	0.57
334.2122803	0.72
336.3514099	0.13
337.2027893	0.85
338.0166016	1.35
339.1873474	1.88
340.1299438	1.31
342.1358032	0.16
346.1042175	0.08
346.9980469	0.14
348.0782166	0.13
351.0726318	5.14
352.2331543	1.44
353.3416748	0.06
354.2233276	0.95
354.9391479	0.08
355.8965759	0.19
358.4327393	0.12
361.6667786	0.34
362.3179626	0.47
366.1787720	9.39
368.0817566	0.14
369.1859436	1.49
370.4577332	0.07
373.2391663	0.24
377.1643982	1.00
379.3061829	0.20
380.2922363	0.70
383.3470764	0.31
384.2325745	4.78
391.1526184	0.11
392.2055359	2.50
393.5949402	0.16
395.2131042	9.91
400.2229004	0.02
401.0321960	0.07
410.1330566	17.43
410.8241882	0.04
413.3634033	0.17
418.8158264	0.30
433.3596191	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
819.6879883	45.74
967.3977661	100.00
968.1928711	62.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.1303
Annotation	Apholate
Peak:m/z	Relative Intensity
112.1165161	0.10
118.9201660	0.32
159.9271545	4.33
161.0447388	1.89
177.0161743	0.09
177.8758850	1.87
179.0860596	0.32
209.1001587	0.03
216.0342712	0.06
239.8840332	0.13
262.3474731	0.07
271.9988403	0.18
279.0184631	0.10
281.0329590	1.12
294.1839294	0.18
298.0206909	0.21
300.8712158	0.09
302.9435425	0.49
318.4730225	0.11
322.0233765	3.55
327.8145447	0.12
328.9482117	2.11
329.9388733	0.28
337.9935303	0.07
340.1220703	100.00
341.9127502	0.45
344.8588257	0.07
346.9590149	0.14
349.0672302	0.25
357.0755615	0.07
358.0601807	0.13
362.8069458	0.40
363.5373840	0.22
368.2886658	0.23
368.9456482	0.15
377.3887634	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1013
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
144.9555664	0.00
146.9121094	0.00
161.1728058	0.03
164.9970703	0.00
185.2773438	0.03
207.1608887	0.03
225.1806030	0.01
239.1289520	0.03
251.3153687	0.01
256.1918945	0.01
257.1722717	0.00
258.1842957	0.02
275.0001221	0.01
280.4101257	0.02
303.0968018	100.00
304.2551270	0.05
313.1399841	0.01
315.2411499	0.02
320.3809814	0.01
327.0994873	0.02
345.2697144	0.16
369.2462769	0.24
383.3439941	0.02
386.7321472	0.01
387.4899902	0.04
399.1490173	0.19
404.6013489	0.01
411.2975464	0.14
418.5548401	0.01
429.0745239	0.16
429.6900635	0.00
445.0343933	0.01
447.1655273	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
112.9086304	0.06
119.2192917	0.06
126.8764114	0.03
136.9547729	0.09
149.0447998	0.08
159.1164398	0.03
161.1961823	0.19
179.1143799	0.39
180.9892883	1.31
193.8435669	0.06
197.0585785	17.80
204.9580078	0.09
212.8087921	0.04
220.9559631	0.11
222.3921967	0.22
223.0771179	0.85
239.2304077	0.03
241.1142273	100.00
247.1673584	0.34
257.1758118	0.05
265.2330322	0.16
268.9347839	0.14
277.3827515	0.07
282.1087952	0.06
283.1554565	0.98
287.4558105	0.10
290.3068237	0.11
295.0876465	0.10
299.0351562	0.27
303.2527466	0.03
304.20578	0.13
305.0901489	0.15
307.2158203	0.44
311.0407104	0.06
313.3111572	0.03
323.239502	0.16
324.9298706	0.08
327.1642456	0.02
339.5390015	0.07
341.4698486	0.15
343.1364746	1.06
349.0265503	0.03
355.5944519	0.14
356.4987793	0.17
357.1706848	1.50
358.214447	0.15
359.0716553	0.25
367.4792175	0.10
373.3659668	0.07
382.3666687	0.04
383.0473938	0.08
385.1706848	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.1350098	0.03
153.0339355	0.14
196.0133667	2.01
214.1495056	1.29
233.2430573	0.01
261.2674255	0.52
273.3003235	0.07
279.2382202	100.00
279.8448486	0.32
295.4730835	0.03
325.0978394	0.02
331.3179016	0.03
341.2828979	0.02
368.0387268	0.03
388.2060852	0.01
404.7314148	0.03
406.4424744	0.01
415.5052185	0.34
430.5150146	0.04
431.3704834	0.03
438.6221619	0.08
448.1487122	0.01
454.9706116	0.07
457.469574	0.32
458.650238	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3305
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0148163	0.03
224.2490234	0.12
242.1491699	0.15
279.3500366	5.09
281.3147583	0.05
333.3812866	0.17
344.9383545	0.03
347.3887329	0.07
365.3880615	0.03
366.5075684	0.11
367.3593750	0.14
401.5545044	0.07
409.4829102	0.05
415.3836670	0.07
433.5229492	0.08
459.3971558	0.09
504.4310913	100.00
505.7196655	0.16
512.7124634	0.02
516.9865112	0.07
521.4867554	0.02
529.5924072	0.07
545.7227173	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1089
Annotation	2,5,7,4'-Tetrahydroxyflavanone 7-glucoside
Peak:m/z	Relative Intensity
130.9270172	0.02
132.0203705	0.02
132.7662201	0.01
136.9947968	0.23
159.1298065	0.01
161.0664368	0.51
163.1021729	0.03
165.1042328	0.10
166.289978	0.01
174.5643616	0.05
176.3243713	0.02
177.0596313	0.04
182.1914825	0.01
183.2216797	0.02
185.1174622	0.06
186.8156128	0.01
187.864151	0.01
189.2118225	0.02
191.5025635	0.03
193.1661377	0.13
197.1222687	0.12
199.0401611	0.17
201.1058197	0.07
203.0873108	0.14
206.8996429	0.02
209.9586029	0.16
217.0886383	0.06
219.0269165	0.03
225.0142059	0.42
226.1622925	0.03
227.208847	0.12
228.2541656	0.07
233.2772217	0.02
240.2159424	0.02
241.1091919	0.24
243.4260254	0.03
244.1069641	0.03
245.1502686	0.07
251.0788879	0.06
259.0348816	0.09
261.3056335	0.02
269.0596313	100.00
269.681488	0.05
278.9842224	0.02
282.0295715	0.02
284.1371155	0.11
285.1435547	1.13
287.0578308	22.30
288.3752136	0.06
289.2088623	0.07
290.2154541	0.04
294.2446899	0.06
295.2357788	0.09
296.0664062	0.04
297.0100708	0.05
297.8135071	0.02
299.2062988	0.25
300.1251831	0.07
301.1591187	0.01
310.6383057	0.14
311.3064575	0.10
313.1036987	0.02
317.3598938	0.05
321.1385193	0.02
322.1770935	0.05
323.1842957	0.35
327.1358337	0.10
328.1513062	0.04
329.2033997	0.15
339.5470581	0.02
340.5388184	0.05
343.0393982	0.03
353.2338562	0.06
354.4042969	0.03
355.1576538	0.26
364.3746948	0.02
374.8613586	0.04
376.7140198	0.04
385.4457092	0.01
389.5498657	0.03
402.1517944	0.79
403.3192444	0.45
405.3316345	0.08
419.9943542	0.05
421.3231506	0.10
430.2656555	0.12
431.2469788	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2185
Annotation	Laciniatoside V
Peak:m/z	Relative Intensity
164.1650238	0.05
164.9588776	0.18
179.3424072	0.05
181.1747284	0.03
191.1767120	0.03
195.0651703	0.93
196.1339874	0.05
206.7979584	0.03
236.8899384	0.02
243.2938232	0.02
265.2618713	0.03
269.9978027	0.02
282.1204224	0.06
285.0370483	0.16
289.0471802	0.04
296.5346069	0.06
314.1931763	1.59
327.2760620	0.08
329.2130737	73.21
358.9716797	0.86
375.2892456	0.49
377.1959229	100.00
389.4901733	0.05
393.5338745	0.02
406.1596680	0.03
407.2973022	0.05
423.3264160	0.07
437.5266113	0.02
450.7528687	0.10
461.4476318	0.01
465.0824585	0.02
479.0060425	0.03
489.4537354	0.03
491.1414185	0.08
496.4059448	0.11
499.6911011	0.05
507.5042114	0.02
509.0300293	0.10
510.3549805	0.04
515.7212524	0.08
523.9091187	0.07
525.1617432	0.07
531.3965454	0.12
538.0645752	0.46
538.7838745	1.09
539.5276489	0.02
540.4037476	0.17
541.3814087	0.04
561.3978882	0.06
564.4113159	0.11
565.5036011	0.24
567.3961792	0.02
586.6632080	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9475555	5.70
130.9631958	0.14
158.9634552	100.00
198.9600830	2.09
201.0514832	0.03
216.9251099	0.66
228.9013672	26.49
240.3876343	0.07
245.0561523	0.66
254.9984131	0.10
273.1258850	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2498
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
96.72628784	0.23
102.8784256	0.17
105.0713806	0.22
106.9690552	2.26
108.9941559	1.21
110.8670044	0.54
113.0693359	0.06
116.8623123	0.36
119.0681534	0.10
120.9743805	4.17
123.0506973	1.87
124.9011154	0.81
127.097641	0.09
129.2011414	0.23
130.9395599	0.34
132.9002991	0.67
134.9644623	6.81
137.0156555	0.56
139.0272522	0.10
140.8853912	0.08
143.0452881	2.68
145.0949097	0.32
146.9044495	1.94
149.1840668	2.81
150.9710693	0.90
154.7430725	0.10
157.0560608	1.45
159.0036926	0.66
161.0596313	2.22
162.2783813	0.45
163.1475983	0.64
165.1529541	1.85
167.08255	0.45
169.0282898	1.34
170.9207001	1.15
173.0235291	1.70
175.0881805	1.06
176.5042114	0.13
177.1152039	1.47
179.2187653	0.08
182.7648163	0.35
183.4526062	0.27
185.0847168	0.23
187.1307678	1.71
189.1741943	0.38
191.2206573	0.48
193.1398315	0.09
195.0579071	0.20
197.1788788	1.01
198.8371887	0.27
200.1508026	0.12
200.9697266	0.35
203.1086884	0.58
205.0653229	1.03
206.8687286	0.07
209.2360229	0.81
210.9388123	1.16
212.9595642	0.90
215.1210022	0.32
217.1143188	4.71
219.1029663	0.47
220.4554749	0.14
222.2268066	0.09
223.0368347	0.28
224.1054688	0.16
225.1583252	0.62
225.8671875	0.11
227.1211548	0.18
228.9708557	0.28
231.0886841	3.47
233.0455322	0.12
235.1681213	0.24
236.2263489	0.25
239.4218445	0.42
241.2598267	0.27
243.3919373	0.24
245.2720337	1.79
247.1815491	6.04
253.2668457	0.52
255.7401123	0.41
257.2076721	0.20
259.1362305	1.24
263.1691284	0.41
264.1834106	0.05
265.3013916	0.04
267.1188354	0.65
269.2910461	0.23
270.2032471	0.37
271.2203369	0.53
272.8980103	0.14
277.0132446	0.09
279.2490845	0.13
281.2484131	0.72
283.2281494	0.35
284.3349915	0.05
285.1919556	0.33
286.1324768	0.23
287.5031433	0.72
292.2014771	0.13
293.27771	0.16
295.2294922	1.09
297.1375427	1.17
299.2597046	2.07
300.0825195	0.25
301.668396	0.06
305.3773804	4.07
306.0300598	0.21
311.2348633	0.17
313.5312195	0.85
323.237793	100.00
324.1697388	0.20
326.0067749	0.11
331.796875	0.30
332.4508972	0.20
341.0622253	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.7071304	0.08
107.0633316	1.82
109.0051498	1.20
111.0008774	0.26
116.9007645	0.15
118.7135315	0.07
121.0151367	3.57
121.8946991	0.31
123.1492233	0.98
125.0195618	0.34
130.9830322	1.26
132.8402863	0.10
133.9043579	0.24
135.0587006	3.64
142.1977386	0.12
142.9958496	0.86
146.7921753	2.36
149.0222931	3.17
151.14328	1.74
153.1442261	0.19
155.0591125	0.20
156.9316711	0.99
159.1747437	0.21
160.9502258	2.92
162.91745	1.33
165.1148376	0.96
166.886673	0.37
169.1691437	0.42
171.0681763	0.93
173.0457611	1.47
174.9717407	0.76
177.0930786	1.33
179.0471191	0.88
182.9101868	0.63
185.2785339	0.44
186.1629333	0.91
187.0142517	1.10
188.9066925	1.71
194.9898834	0.58
197.0717163	0.99
201.2538757	0.42
203.1890259	0.57
205.1175995	0.48
207.4508209	0.15
209.1712952	1.05
210.0637512	0.48
211.0333252	2.34
213.8004761	0.36
215.1543274	0.13
216.0572815	0.14
216.986084	0.50
221.0308838	0.20
223.1064453	0.74
227.318634	0.42
228.152832	0.23
229.0584717	1.07
231.1683655	0.65
231.9342957	0.37
238.9915771	1.15
239.9847412	0.38
241.1925049	2.19
243.2203979	0.73
245.3041077	0.91
247.2521362	2.44
250.2257385	0.32
251.2542114	1.07
253.3278809	1.29
255.0553894	0.14
259.0518188	0.40
262.1960754	0.33
263.27771	0.39
265.2990112	0.63
267.1308594	1.32
269.322937	0.37
271.2374573	0.40
273.1955261	0.12
279.2277832	0.33
280.9850769	1.31
282.1868286	0.12
283.1382751	1.06
285.3374023	0.52
287.1681213	0.60
293.1607361	0.23
295.316864	1.39
295.9297791	0.69
297.142334	0.86
298.2080688	0.22
299.2444763	3.07
300.2830811	0.34
302.9794617	0.46
305.2583618	5.11
306.1461792	0.23
307.3867798	0.22
309.5212708	0.46
313.2322998	0.78
314.2183838	0.37
321.1954346	0.38
323.2435303	100.00
323.9271545	0.09
325.1711426	0.66
332.3830872	0.09
341.3077087	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.225
Annotation	Citbismine C
Peak:m/z	Relative Intensity
281.2690125	0.21
341.1737671	100.00
683.1724243	19.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	424.1464
Annotation	Hyaluronic acid
Peak:m/z	Relative Intensity
155.1241455	3.28
177.2134094	0.11
181.3315582	0.04
199.1327972	41.30
209.2697906	0.05
213.4546204	0.04
218.1565552	0.22
241.1614990	0.12
243.1775818	0.08
261.0002441	0.21
262.1281433	0.19
279.0368042	0.10
280.4086914	0.13
286.1537476	0.34
287.2312622	0.11
295.0281372	0.10
299.1556702	0.34
301.1770935	0.21
305.4732056	0.04
307.3571777	0.19
315.0779114	0.26
318.4568481	0.29
326.2078857	0.12
327.1892700	0.16
336.9599304	0.15
351.2969360	0.19
355.9026489	0.07
361.1670227	100.00
366.0392456	0.07
375.3426208	0.10
376.2661133	0.34
377.3291931	0.39
379.1498718	0.13
387.4020691	0.09
389.4855042	0.14
393.0616760	0.10
405.1912842	1.27
406.5068665	0.32
407.2994995	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	636.2
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9215546	0.07
220.9755859	0.29
222.1737671	0.03
232.8567657	0.13
251.0405579	0.26
262.8080444	0.04
280.4926147	0.07
281.4886169	0.14
323.3071289	0.49
324.2614746	0.04
340.8172607	0.67
341.4346924	0.02
366.7188110	0.04
383.3486328	0.34
384.4150391	0.12
425.1981812	0.14
428.3126831	0.05
443.0407104	0.30
465.1159668	0.16
473.3685303	0.09
478.0170898	0.02
500.3381348	0.06
503.2933350	100.00
504.3595581	13.05
538.2131348	0.18
589.1193237	0.10
617.0144653	0.14
635.9896851	0.81
636.6228027	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.3606
Annotation	3alpha,27-Dihydroxy-28,20beta-taraxastanolide
Peak:m/z	Relative Intensity
132.8962555	1.58
145.1021118	2.64
161.0953064	2.35
173.1952972	0.45
180.9495087	3.40
185.8383331	2.37
187.2621155	1.30
189.2495728	0.61
197.0198669	3.34
201.128067	1.65
203.4072266	3.63
204.9709473	3.11
207.1882935	0.80
211.0263214	0.73
225.0417786	0.94
227.1419067	2.28
229.1763611	1.15
237.3809814	1.21
239.1554565	3.42
243.1216431	1.15
249.17099	2.38
253.3170166	1.58
258.282196	1.63
259.5488586	3.11
270.5537109	1.36
277.1625977	1.92
282.8025513	0.73
301.1495972	2.79
310.9685059	1.20
315.0268555	2.57
317.5388184	1.21
320.258667	0.80
320.9226685	1.49
329.7297363	0.94
335.3469238	0.59
350.3065491	3.73
359.2230225	0.59
369.4156189	1.29
370.0647583	1.51
381.2741394	1.51
383.2027283	2.70
385.3279114	5.02
389.0849609	7.17
391.3583679	4.34
395.3806763	4.31
399.4026184	11.82
409.3297424	40.22
413.4831543	1.22
414.9583435	8.41
416.1754761	4.48
418.2268982	2.80
419.2231445	1.21
423.2644043	0.95
424.600708	0.93
427.2641907	4.46
437.3539734	24.54
439.3074341	2.41
455.3590393	100.00
456.1412964	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.9855652	0.03
126.9264984	0.08
134.0150757	0.04
135.0306702	0.59
143.0503693	0.02
145.1124268	0.05
152.9780273	0.01
154.9804993	0.04
161.0211639	0.23
170.9838257	0.02
172.9899597	0.54
179.0341034	2.97
191.0457611	100.00
192.4399109	0.02
209.2945862	0.01
251.0157166	0.02
261.2705383	0.04
264.9404907	0.07
266.0717773	0.03
269.1369934	0.03
271.3190308	0.02
275.2703247	0.03
291.1422729	0.04
293.4045105	0.02
303.2008057	0.03
307.1409912	0.17
308.5704956	0.03
309.1904297	0.04
317.0408325	0.11
322.3236084	0.02
323.5528564	0.02
325.3031006	0.01
333.0722046	0.04
335.5566406	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
112.7448196	0.35
165.1330566	0.16
171.0332794	0.74
173.1307678	0.92
182.9450073	0.39
185.1005249	0.43
187.3082428	0.66
197.0266113	0.36
199.1528931	1.43
201.2227173	0.97
203.4477539	0.16
213.2343445	0.62
214.2217407	0.42
215.0966492	0.65
227.2643433	1.13
228.9864197	0.69
230.9450073	0.34
240.2342529	0.32
241.1646423	2.32
243.1171265	2.23
244.2009888	0.37
245.6251221	0.35
247.0630493	0.40
251.3258057	0.37
253.285553	0.46
255.3164978	1.29
257.0881653	1.03
263.3900757	2.09
267.1884766	0.15
268.3405151	0.24
269.2326965	2.87
271.4107971	1.65
273.1323242	1.19
281.2206726	0.29
283.5584717	3.12
285.2281189	3.83
285.8707886	0.27
289.133728	0.67
293.3279114	0.38
295.2064209	0.85
297.2606812	1.68
299.3120728	2.96
301.1304321	1.27
310.0644531	0.77
311.200531	3.45
311.8531494	0.63
313.3642578	2.08
315.3635559	1.77
321.4121399	1.25
323.3370056	5.17
324.9785767	0.25
327.1091003	2.59
339.2484436	100.00
340.4907227	2.40
341.3317261	11.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.1221
Annotation	3-Hydroxysebacic acid
Peak:m/z	Relative Intensity
78.8003235	0.09
81.0286179	0.11
86.8992157	0.12
88.7748108	0.05
95.0343475	0.16
96.9284515	0.09
98.9562988	0.15
104.8887329	0.12
106.0489197	0.04
107.0880432	0.08
108.9668121	0.12
111.1062469	0.12
121.1107635	0.10
123.0123444	0.50
125.3735352	0.04
126.9678192	0.09
128.9231873	0.11
134.9817200	0.21
135.9493713	0.02
137.1750488	0.26
138.9770050	0.16
141.1100922	0.20
143.1978912	0.09
144.9686890	0.15
147.0880280	0.03
149.0115814	0.20
150.9832764	0.07
152.9828339	0.16
154.8000641	0.04
156.8508453	0.30
159.0295868	0.45
160.1653748	0.17
161.1426544	0.24
162.8975220	0.20
165.0409241	0.06
165.8842316	0.12
169.1825867	0.11
170.2180939	0.06
173.0856934	1.07
173.8939514	0.40
175.0828094	1.25
176.0533295	0.29
176.9860840	0.47
179.0490875	0.43
183.0222168	7.53
185.0786133	0.06
186.7908630	0.08
188.0219879	0.84
189.0137024	3.02
191.0225372	2.25
192.3164673	0.08
193.0917358	0.06
196.6867218	0.08
198.4015198	0.38
200.9874725	100.00
201.9302063	0.36
203.1582489	0.61
204.1715851	0.12
210.0066071	1.51
218.1661835	0.13
218.9506989	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.11
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
111.0646896	0.12
113.1972809	0.13
115.0020828	0.84
128.8968048	0.06
133.0294342	7.47
135.0412292	2.37
156.9092102	0.07
159.1386414	0.41
161.0953217	0.32
179.0688171	45.26
183.0552521	0.65
190.8948059	0.09
205.2254944	0.05
205.8392944	0.04
210.0710449	0.17
223.0298157	100.00
229.0209045	0.11
233.1373596	0.25
235.3808594	0.11
239.1628113	0.10
241.1876831	0.07
242.9507751	0.15
244.8960876	0.07
247.2375183	0.16
259.2057800	0.50
263.3452148	0.06
265.0428772	0.09
265.7326965	0.27
267.2174988	0.15
269.0007629	0.34
277.4095154	0.11
285.1972046	0.26
293.2108154	0.38
295.1142578	1.12
296.9671326	0.10
303.1132812	0.29
311.3376465	0.24
317.1754150	0.07
319.5742798	0.33
321.1177063	3.64
321.7627869	0.03
322.7645874	0.44
323.3890686	0.41
324.3221741	0.27
329.4694519	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.04917145	3.40
97.06700897	0.80
98.88633728	0.71
101.0258942	0.91
107.0218582	0.33
108.9198303	0.82
110.8029022	1.21
119.0443268	0.43
120.9004745	0.26
122.8915024	1.13
124.0340118	1.59
125.114418	0.43
126.6955338	0.30
129.0235901	0.36
131.0612488	0.53
132.7762604	0.83
134.987442	0.69
136.9416962	0.66
138.692337	1.65
141.071228	1.57
142.0209351	1.34
143.0708008	2.17
151.2269897	0.30
153.0065918	0.41
154.960083	1.51
156.8907623	2.70
163.1883545	1.68
167.1017151	0.48
169.0897827	0.66
174.9224854	1.09
176.0968323	0.45
177.3409271	0.46
180.7893524	0.71
183.0563507	1.70
185.0944824	1.34
187.1185608	0.60
192.9227142	3.62
194.4056702	1.63
195.2771301	1.43
197.1552734	2.32
199.2265015	0.31
201.1526947	0.59
205.7614136	2.00
209.0656433	2.85
211.1067505	6.84
218.4196777	1.19
219.2489014	2.37
221.0024719	1.86
223.3841858	2.87
224.9678345	4.02
228.0139465	0.83
229.1630249	0.74
231.3036194	1.77
233.1876831	1.56
235.2546997	5.05
235.9757996	0.78
237.2668457	1.33
238.9899292	0.41
243.0777283	2.91
249.2741089	1.49
250.9952698	4.11
252.9847412	5.59
255.5762634	0.84
256.5820007	1.48
261.0690002	1.05
265.127533	2.28
266.1317139	0.38
267.0612183	1.89
269.2511597	4.21
270.2668457	0.58
275.3497925	23.42
276.7201843	0.28
280.6533508	3.24
282.7380066	2.04
293.206665	100.00
296.1780701	1.55
302.3938293	2.21
309.461792	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2184
Annotation	Laciniatoside V
Peak:m/z	Relative Intensity
165.0374756	2.77
165.9108734	0.26
180.0285492	0.11
181.0802765	0.03
181.9591370	0.07
186.0624695	0.02
195.1102448	10.51
196.0209808	0.52
207.1526642	0.05
234.1668701	0.03
249.2672729	0.05
275.0678711	0.01
288.2362671	0.11
329.2059326	17.08
330.2677002	1.98
338.2464600	0.05
358.9644165	0.32
375.2667236	0.02
377.1531372	100.00
378.2048340	6.58
385.1817017	0.22
387.2852783	0.04
389.2437744	0.03
405.2931519	0.07
423.3132935	0.04
433.5300293	0.05
460.9146118	0.13
467.5391235	0.09
489.3414307	0.13
491.2535400	0.06
494.9719849	0.02
496.3359985	0.18
498.9609375	0.03
501.2991333	0.04
523.1266479	0.03
538.2763062	1.76
538.9838867	5.04
539.9799194	0.41
555.9342041	0.15
565.9967651	0.04
567.2743530	0.10
573.4069824	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	716.61
Annotation	Unknow
Peak:m/z	Relative Intensity
296.9066772	3.20
368.7072754	0.44
380.6785889	14.47
382.4826050	0.23
451.3191528	0.47
459.0366211	0.52
460.4528198	0.39
462.6936035	0.47
464.6174927	22.53
494.7554932	0.49
513.1301270	0.27
517.9559937	0.33
542.8399658	2.18
545.4055786	0.23
547.9207153	3.86
548.5869751	49.76
560.9202271	1.01
632.5587769	100.00
656.2116699	0.28
665.5744019	0.38
674.0798950	0.39
717.9475098	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	720.1582
Annotation	Unknow
Peak:m/z	Relative Intensity
205.3537903	0.39
223.2277527	0.44
243.1032257	2.35
243.9431152	0.97
245.1654053	7.06
246.0596619	0.93
257.5098267	0.42
261.0223999	2.54
262.2035217	0.84
269.1906738	0.21
271.3475647	0.92
273.0268555	0.99
284.0841064	0.41
284.9816589	0.77
287.1612854	20.64
288.1011353	2.61
289.1641235	27.19
290.1616211	11.54
297.0093079	0.33
298.8463745	1.61
300.3732300	1.20
303.1258545	0.67
313.3081665	0.25
328.2867432	0.36
329.2744141	1.75
330.1303711	0.97
331.1198120	1.99
332.4021912	1.14
335.4687195	0.38
337.2333984	1.10
339.2849731	0.96
340.3419495	0.24
341.1715088	0.46
349.0704346	0.31
353.2006226	0.31
362.1618652	0.57
363.2230225	1.15
368.1177368	0.37
369.5292358	1.10
370.1537476	1.39
378.0987549	1.67
379.4802246	0.36
381.2819214	3.30
382.2071533	0.36
387.3539429	0.30
389.3295898	0.48
393.8540649	0.21
395.1370239	5.26
396.0143433	1.57
404.0715332	0.19
405.2238159	1.25
406.4434814	2.07
407.2662964	22.92
408.3090210	9.68
409.2894897	4.03
411.1330566	0.23
413.2373657	8.26
414.3099365	0.54
415.0726929	2.07
418.3757324	1.50
422.1395874	1.38
423.3222656	4.81
425.1083374	15.82
426.2271729	3.06
427.2782593	0.60
431.2747803	1.29
432.4284668	0.68
433.2846680	0.78
435.1394653	0.19
437.2687988	1.92
438.7238770	0.97
448.4675293	3.16
449.3474731	5.21
450.5300903	4.06
451.3937988	8.13
452.1874390	3.68
453.1685181	0.51
455.5303345	0.23
465.6709595	2.70
466.4130249	0.22
467.3764038	0.33
468.7626343	2.86
469.6696167	0.93
473.9721069	3.34
474.7835693	2.46
480.7896118	0.42
483.2717285	3.67
487.6582642	0.26
490.1172485	4.33
490.7308960	0.89
491.7482300	0.56
492.5179443	1.13
494.7562866	4.33
499.1258545	4.60
500.0222168	1.62
501.4485474	0.34
505.3190308	1.33
513.5220337	1.03
515.0195312	0.38
517.8936768	0.93
519.8754883	0.40
525.2173462	0.36
526.6755981	0.23
527.4324951	1.09
531.2869873	3.90
532.6598511	1.47
533.3971558	2.16
534.3922729	1.03
535.3593140	0.39
537.8917847	2.74
539.6270142	1.55
541.6981201	1.67
542.4586182	0.78
546.6091919	1.09
547.3800659	1.65
549.4213257	0.94
550.6303101	11.38
551.3756714	1.74
553.2390747	1.27
554.3569946	1.74
555.3283691	0.46
557.1799927	2.41
558.2949829	1.13
559.3788452	38.68
560.3374023	5.27
566.4341431	0.84
568.5345459	7.74
569.3436890	4.69
570.2474976	2.59
571.3100586	1.31
572.4259644	1.43
573.4136963	2.39
575.1929321	22.50
576.1408081	14.00
577.1989136	36.70
578.3268433	13.91
579.2022705	2.37
580.6159058	2.00
581.7503052	1.37
585.0357666	0.53
587.3126221	2.58
588.4904785	2.16
589.9934082	0.96
592.1400146	1.68
595.4319458	0.38
598.4752808	0.18
603.3129272	0.19
605.3605347	0.77
614.3469849	1.99
617.3222656	2.14
619.3103638	3.06
620.3088379	0.55
621.4058228	0.34
622.6896973	1.98
626.7301636	6.12
627.4648438	0.73
630.1786499	0.64
631.1367798	0.60
635.6930542	100.00
636.4097900	12.67
641.9629517	0.57
644.2129517	15.87
644.8339233	54.15
645.6945190	1.35
647.0914917	0.41
648.8401489	2.36
650.5194092	0.36
651.3936768	1.40
652.0870361	0.47
653.4540405	0.18
657.3960571	9.10
658.3972778	1.37
665.6911011	0.57
667.2369995	0.71
673.0791016	0.31
675.2586060	0.37
676.4143677	0.17
677.1592407	0.75
678.2888184	2.24
679.4539795	0.60
693.4442139	7.25
694.3579102	1.43
695.2661743	4.15
696.5186768	5.03
701.1947632	10.17
702.2990112	9.79
703.3760376	1.93
721.0944214	1.96
722.3287354	1.82
737.3939819	5.01
738.3859863	2.97
739.2374878	6.92
740.1461182	6.13
741.2394409	0.41
742.5189819	0.29
743.2079468	1.01
744.3801270	0.32
745.4208374	0.17
756.8581543	0.36
771.4258423	0.54
794.4263916	0.88
798.5997925	0.27
801.2570801	0.33
806.3778687	1.31
812.4750366	0.32
814.4406128	0.18
815.3416748	0.83
816.3179321	0.88
819.6349487	2.67
820.3112183	3.38
821.0205078	0.86
822.3473511	1.06
823.2218018	0.46
824.6766357	0.78
832.3950806	1.10
833.1779175	0.59
838.3742065	0.15
845.3446655	2.04
846.0296021	1.88
846.6766968	0.52
847.5325928	0.68
849.1325684	0.26
857.3829346	2.41
858.1253662	0.34
859.3834229	1.71
860.9915161	0.41
863.1856079	29.20
864.2897949	37.17
865.3769531	34.62
866.5187988	23.56
867.3907471	1.39
873.4557495	1.67
875.2481079	0.46
876.4733887	0.25
879.6499023	0.60
890.2598267	0.23
891.4617310	0.34
904.5248413	0.29
906.4570923	2.07
907.1735840	0.56
908.3429565	0.71
930.2216187	0.41
940.2760620	0.86
946.4634399	0.54
948.0103149	1.72
958.6006470	0.41
965.3669434	0.47
966.1848755	0.73
971.0612793	0.46
972.3228149	0.18
976.4761353	1.44
981.1982422	4.48
982.7454224	3.76
983.3698730	1.02
984.2785034	3.64
985.2678223	1.37
986.2122192	0.41
989.1989136	7.76
990.4371948	7.89
991.4588013	1.49
995.4912109	0.50
999.2537231	0.41
1000.5811160	0.66
1001.2593380	0.48
1002.3601680	1.06
1009.4140620	1.77
1010.2968750	0.30
1024.4001460	0.87
1025.3291020	1.35
1026.5323490	3.74
1027.3378910	9.02
1028.3442380	7.11
1029.4453120	2.94
1033.2677000	0.44
1041.9641110	0.53
1109.9873050	0.39
1111.1777340	0.36
1121.7949220	0.30
1132.8017580	0.34
1133.5229490	0.84
1134.4949950	1.20
1135.1583250	2.84
1136.5292970	1.01
1138.3627930	1.34
1146.7169190	5.60
1147.3640140	0.52
1151.1918950	10.34
1152.3093260	40.60
1153.4088130	14.39
1154.4001460	15.66
1155.2475590	4.08
1163.7852780	3.91
1164.8979490	0.65
1171.4389650	0.44
1195.3381350	0.71
1196.4011230	4.81
1197.5292970	1.02
1272.0625000	0.23
1280.3935550	1.11
1298.2868650	1.64
1315.3117680	4.03
1316.4029540	13.88
1317.3280030	11.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2612
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
363.0885925	0.15
451.181366	0.04
803.1430664	0.04
844.7945557	0.04
845.5361328	0.06
847.3370361	0.02
1002.332275	0.02
1028.592651	0.05
1109.324707	0.09
1110.672119	0.04
1118.430908	0.03
1135.403076	0.02
1136.294434	0.19
1153.261719	100.00
1154.272705	38.22
1155.085205	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.1564
Annotation	Sibiricose A3
Peak:m/z	Relative Intensity
143.0403595	0.23
148.7477417	0.10
172.8523560	0.14
178.8596191	0.19
221.0344696	0.44
221.8206329	0.09
245.1318970	0.05
275.0601807	0.11
286.1617126	0.07
294.4622192	0.19
306.2138062	0.12
323.1758423	17.55
331.0466309	0.20
365.1146240	0.49
386.1200867	0.02
399.9409790	0.05
410.8005981	0.10
412.2709045	0.15
420.8191528	0.28
426.3461304	0.07
439.4243164	0.12
456.1568909	100.00
457.0809326	0.23
458.3959045	0.03
459.3157043	0.07
466.2463074	0.36
471.2964478	0.05
483.2972717	0.09
484.0917358	0.07
485.2351685	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
94.7464142	0.26
101.0686646	0.31
112.9750977	1.32
119.0328522	0.81
120.9893036	61.69
130.9974365	0.16
134.9640350	0.25
137.2134399	0.10
143.1288147	0.41
148.8675232	0.86
160.8691406	1.30
163.1725464	0.16
163.9094543	0.32
165.0724792	0.13
166.9804230	1.30
173.0855713	0.07
178.9660797	1.10
199.0126801	0.13
203.1000214	0.26
207.0499573	18.91
209.2158508	0.08
211.1521912	0.42
217.0260620	0.05
223.0705872	0.31
226.0422668	0.16
232.1867371	0.19
232.9840698	0.37
235.1761780	0.49
237.2373047	0.15
239.0259094	0.16
249.4244995	0.18
265.2967529	0.24
268.2479553	0.16
269.2098083	0.32
283.0241699	100.00
285.1618042	0.96
286.1373291	0.09
291.0873413	0.29
293.2462158	0.11
301.0853271	0.05
309.2602539	0.05
310.8830566	0.35
311.5116577	0.23
314.1876831	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.09
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
69.0235138	0.03
95.9133606	0.05
119.8964996	100.00
120.9960022	0.06
124.2169647	0.01
130.9032440	0.26
135.1343994	0.02
137.9317932	0.01
146.0194550	0.03
147.9656219	0.95
148.8728333	4.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.22
Annotation	Unknow
Peak:m/z	Relative Intensity
132.1276703	0.09
144.9520569	1.29
147.9602051	0.18
167.1906738	0.10
180.2614441	0.12
183.1179352	2.69
194.8432922	2.03
196.6341248	0.16
211.1027069	13.79
223.0692139	0.36
224.9471893	0.11
226.1866455	0.05
229.1059875	11.64
230.2391663	0.13
253.0823669	1.93
258.7591858	0.23
262.1902466	0.19
264.0226440	0.08
266.0851440	0.23
275.2875061	0.17
277.1307678	0.18
281.6373901	0.06
288.9656067	1.23
293.9880371	4.22
303.0044250	0.10
307.5517578	0.21
311.7767029	3.23
324.8939819	1.85
331.2009583	0.24
339.0347900	0.52
340.1521912	0.45
342.1714172	100.00
342.7739258	1.09
356.4739075	0.09
359.0597229	0.44
361.3357544	2.50
365.8851318	0.11
366.6161499	0.10
367.3619080	0.13
375.2845764	0.27
384.1977844	29.77
408.4000244	0.16
420.2446899	2.00
422.3388672	0.08
438.0173035	0.41
456.2612610	1.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.8019104	0.11
105.0846558	0.12
106.9284286	0.65
108.2372894	0.07
108.8897858	0.29
111.0125656	0.49
114.8366928	0.22
116.9550858	0.60
119.1136932	1.09
120.9828949	3.05
123.1171494	0.35
124.9493408	0.27
126.7695923	0.12
128.2289734	0.07
129.0498657	0.14
131.0495911	0.20
132.9387054	0.31
134.9553223	2.41
137.0501404	0.50
138.8154907	0.21
141.0444794	0.96
143.0234985	2.93
144.883728	0.26
148.236908	0.10
149.0231628	1.22
151.0464935	0.59
152.0281982	1.58
153.0412598	0.50
155.0787048	0.54
157.0084686	2.17
158.2764893	0.23
158.9642639	1.24
160.8997498	0.05
163.2589722	0.38
164.9066772	2.41
166.0283966	0.51
167.058548	1.89
167.9206543	0.13
168.9855652	4.21
170.9145813	0.99
173.0576477	2.08
173.8066864	0.06
175.1684265	0.49
176.2450867	0.10
176.9282227	0.14
179.0475922	0.93
180.673172	0.33
182.9514465	2.47
184.9588013	0.51
187.2357941	1.46
188.9935455	0.17
191.4412537	0.08
193.1448059	0.27
195.2370758	0.69
197.0383301	0.88
200.1316376	0.04
201.0531006	0.69
204.0308533	0.13
205.1799469	1.09
207.0882721	0.30
209.169342	0.13
210.9223938	0.53
212.3210754	0.23
215.0943604	1.99
216.2695618	0.26
217.2864075	0.51
218.9745483	0.07
221.2624512	0.13
223.2998962	1.20
225.1365662	0.16
227.0264282	1.63
228.1562195	3.85
229.0516052	9.38
230.1398621	0.28
231.2002869	0.58
233.0505981	1.81
236.462616	0.14
239.1407776	0.14
240.856842	0.51
241.8283997	0.55
243.1430359	1.53
243.87323	0.14
245.1494751	1.61
247.0969238	9.35
248.0186768	1.28
251.2988892	0.54
253.1771851	0.49
255.0906067	0.22
256.4153442	0.30
257.104248	0.66
259.1590576	0.11
260.2799683	0.55
263.2634277	0.34
265.1393433	1.10
265.8340759	0.34
267.0523682	0.21
273.3844604	0.40
277.224823	0.47
280.2316895	0.15
281.1411743	0.41
283.236145	0.19
284.6937866	0.20
285.3891602	0.27
287.2988281	0.83
291.4557495	0.39
294.1374512	0.56
295.1877747	2.36
296.1134644	0.09
297.0783691	0.32
298.3681335	0.50
299.2520142	1.84
301.2055969	0.30
303.2320557	0.08
304.1853027	0.06
305.2738037	6.94
312.535614	0.23
313.3091736	2.54
314.2389526	0.21
323.2403564	100.00
324.0792236	1.30
327.2390747	0.07
332.3259888	0.43
341.3067932	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
109.0233231	0.01
110.0460358	0.01
110.9648209	0.05
117.4499741	0.02
126.9200821	0.18
127.9312286	0.02
135.0247498	0.51
136.0580139	0.12
161.0122528	0.59
162.1776733	0.01
169.9992371	0.03
171.1647797	0.09
172.966156	1.61
174.1309814	0.27
178.9923401	5.45
180.0500488	0.74
191.0329895	100.00
192.1109009	11.21
307.4992065	0.04
309.2232056	0.11
310.5411377	0.01
325.99646	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
89.01803589	0.78
97.14266968	0.46
98.6459198	3.06
99.35658264	1.56
134.9741516	2.43
139.0194702	3.60
141.0470886	2.30
142.9957275	0.47
150.8794098	1.08
155.2528992	1.99
157.0692139	0.67
159.8794556	1.05
163.0391846	0.62
164.9554749	2.95
172.8658752	0.70
181.1677246	0.35
185.161377	0.74
190.1712341	1.79
193.3312225	1.20
201.0463409	0.97
209.1368408	2.61
211.3240051	9.62
213.0415955	0.70
215.1304626	0.83
219.2615967	1.21
221.7309875	0.46
225.20047	1.82
231.1956482	1.15
233.4270325	1.50
235.3187256	0.67
237.1263123	3.40
239.1247864	1.87
247.0666504	2.65
249.3561096	3.95
251.2227478	1.08
253.2827148	4.41
257.4808655	3.06
261.537323	0.57
270.1751709	1.05
275.2295532	11.41
283.0453796	4.82
287.4164734	1.41
288.1375427	1.18
293.2185059	100.00
302.1297607	2.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0855
Annotation	Gerfelin
Peak:m/z	Relative Intensity
93.0573120	0.11
95.1356659	0.27
110.8365326	0.09
118.9628067	0.35
122.8950195	96.79
124.8292084	0.06
126.9063568	0.99
135.1659546	0.21
136.9684296	0.58
139.0116577	100.00
139.8006287	0.04
146.9041443	9.78
150.9243774	25.34
151.5491486	0.22
152.9346161	0.47
156.9601135	0.07
163.1050262	0.40
164.9801483	47.40
169.0196075	3.14
180.9118958	0.45
205.0751038	0.14
208.0570679	0.05
226.9922791	0.13
232.0944519	0.10
249.0587463	1.32
255.0906067	0.21
263.2455444	0.03
273.0748901	14.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.2
Annotation	Ethyl 7-epi-12-hydroxyjasmonate glucoside
Peak:m/z	Relative Intensity
118.8761139	0.38
124.8356018	0.31
130.9781189	0.81
142.9698792	2.79
148.8945312	1.12
160.9310303	2.71
162.0357361	0.99
162.8379211	0.23
173.1985779	1.34
179.0499268	15.71
189.1675720	0.06
191.1407471	1.84
193.1736450	0.71
200.8940125	0.04
205.0170135	55.18
206.0943909	77.19
207.1167908	12.93
209.0747681	0.31
225.0040283	3.18
235.3604126	1.05
243.1521606	0.14
248.2248535	0.18
251.0094299	0.10
253.4187317	0.21
267.0876770	0.44
281.1018982	0.13
289.9735718	0.12
295.9729919	0.16
298.0500488	0.14
303.4677124	0.07
307.5348511	0.16
315.3135986	0.11
318.2280273	0.22
318.9639282	0.09
320.2864685	0.05
323.3023376	0.15
331.2105408	0.29
339.3864441	0.09
341.3970337	0.29
342.3812866	0.21
351.2321777	0.67
353.1057739	0.11
357.0293884	0.41
358.5433960	0.12
367.3280334	16.56
368.1101685	100.00
369.0971680	15.74
369.7302856	0.27
374.9513245	0.11
379.0968933	0.24
383.2236633	0.09
384.1803284	0.41
394.1360779	0.10
396.3349609	0.54
397.2677917	1.31
417.0946960	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1079102	0.30
212.9185486	4.56
295.5323486	0.24
296.7340698	41.99
297.3562012	0.48
303.0500793	0.51
323.0021362	3.40
344.5161743	0.46
374.8101196	0.11
378.3665161	0.33
380.6275024	100.00
381.2709961	0.81
386.8932495	0.23
404.5444946	0.68
412.3738403	0.72
428.6763916	0.42
454.6676636	0.14
462.0404663	1.16
462.9616699	0.69
464.4670410	58.51
465.3471069	0.22
489.0733032	0.59
502.2442017	0.51
503.1925049	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.239
Annotation	Unknow
Peak:m/z	Relative Intensity
124.8871841	0.05
126.9373932	0.09
137.0492706	0.06
139.2003326	0.09
142.7761841	0.03
153.2227783	0.03
154.8642578	0.07
157.0328979	0.49
158.8561859	0.05
159.7510834	0.03
161.0078125	0.29
162.2079773	0.06
173.0851440	0.23
181.3105164	0.06
182.2216492	0.01
183.0347595	0.04
185.3256836	0.03
196.3129425	0.10
199.0361328	0.02
201.3688354	0.05
213.1002808	0.02
215.3360748	0.02
219.3946991	0.01
221.1961212	0.05
226.9865723	0.03
229.2456512	1.53
230.2604980	0.38
235.1756897	0.01
239.2929688	0.16
241.3229980	0.05
245.0625305	0.05
247.0167847	0.06
255.1164246	0.02
257.2182922	3.28
258.3295898	0.57
271.3628540	0.15
274.1662598	0.07
275.3310242	4.09
276.2892761	0.51
283.4577026	0.07
295.4316101	0.02
299.3419800	0.08
300.3001099	0.13
301.2302856	0.06
302.2463379	0.02
305.2382812	0.01
306.0186157	0.07
316.3036499	0.03
317.2399597	0.38
318.4830322	0.03
320.1610107	0.03
323.1864014	0.05
329.6348877	0.02
331.3836670	0.01
332.6162415	0.05
335.1396790	0.22
337.3547974	0.03
348.1920776	0.01
351.0662231	0.04
355.4083862	0.12
357.4229126	0.08
363.2634583	0.02
364.4981689	0.03
371.4853210	0.04
375.2565613	0.26
376.2832031	0.04
377.4019165	0.48
383.4619141	0.19
384.3155212	0.05
391.3010254	12.39
392.3583679	3.85
393.0563049	0.05
394.5606079	0.01
401.3509827	4.41
402.2440491	1.48
405.5252380	0.02
417.1046143	0.03
419.3541870	100.00
420.3747559	18.56
421.4042969	0.25
439.4482727	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.1479
Annotation	Sundiversifolide
Peak:m/z	Relative Intensity
80.9582596	0.03
92.9850311	0.02
94.9385223	0.15
97.0659790	0.05
98.7624817	0.06
99.5693665	0.03
100.7295227	0.02
104.9622955	0.30
107.0582886	0.11
108.0241547	0.03
108.9267731	0.06
110.8948212	0.08
113.0803070	0.12
115.0818481	0.07
118.9701233	0.09
120.9773560	0.05
122.9761047	0.14
127.1227722	0.17
131.2109985	0.13
133.1191864	0.13
135.0897522	0.05
136.0774689	0.10
137.0854645	0.21
140.8073883	0.08
144.0789642	0.06
146.9783478	0.26
149.0670319	1.38
151.0914764	0.05
151.8126678	0.06
154.9805145	0.12
156.9105835	0.06
161.2071533	0.18
162.9868164	0.14
165.0875092	0.22
167.0856781	0.24
169.0511627	0.62
171.1551666	0.02
177.1179504	0.01
179.0101166	0.52
180.9912415	0.10
183.0538483	0.25
183.8428497	0.75
189.0792389	4.73
195.1711273	0.02
197.1333160	0.41
200.8852081	0.07
204.8250122	0.31
205.5325928	0.22
207.0460510	100.00
208.0297546	0.40
208.9664154	0.10
211.0256500	0.02
224.3101044	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
153.0105133	0.29
163.0319214	0.03
196.0888672	0.40
205.4150085	0.21
206.4401093	0.04
214.0132141	1.40
215.2259369	0.08
233.3847351	0.60
234.2477875	0.20
243.0948181	0.03
244.1752319	0.08
259.0651550	0.40
275.2803955	0.59
277.2890320	100.00
278.2825623	17.01
295.2466736	0.07
311.3244934	0.05
325.2371216	0.06
327.0682373	0.08
335.2070923	0.02
341.1768188	0.09
345.1912231	0.12
355.6188354	0.05
369.6034546	0.04
373.3917542	0.05
391.2149963	0.08
407.1121521	0.07
411.0960083	0.30
415.4006653	0.04
416.1968689	0.04
429.3125305	0.07
431.4375916	0.08
433.4558411	0.26
436.4681091	0.08
439.1090393	0.18
443.9512329	0.07
446.5536499	0.05
447.7043457	0.08
457.2545776	0.58
457.9100647	0.29
460.5300598	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.90010071	0.39
96.79595184	0.24
99.00215149	0.74
105.0627289	0.55
110.9673386	1.22
112.7980499	0.73
114.7511749	0.56
118.8316422	0.82
124.9861755	1.92
127.0056458	1.33
129.1032104	0.53
131.0469666	0.17
132.6445312	0.28
135.0372314	1.48
137.0092316	0.33
138.9568481	0.69
140.9672546	1.57
143.132019	1.18
145.3886261	0.19
146.8095551	1.14
148.9145508	0.83
151.073822	0.12
151.9097137	0.60
152.9906158	1.70
154.9847107	0.54
157.1582642	1.29
158.9734802	0.39
162.9722137	0.14
164.8905334	0.43
167.0137177	0.36
169.0191956	0.87
171.0297089	0.74
175.0896606	1.27
177.5516357	0.23
178.8963165	2.36
180.9816284	0.68
183.0083466	1.10
185.164856	2.02
187.1411133	0.29
188.2590637	0.25
189.0719604	0.10
191.3088837	0.99
192.6578064	0.50
195.0129089	0.49
197.1496582	0.54
198.9044342	0.37
199.9667206	1.07
202.0938416	1.28
203.2220764	0.37
205.1382141	0.61
209.2621155	1.18
211.1451721	4.31
213.1665955	2.77
214.9354248	1.37
217.1292725	1.48
221.0671387	3.19
221.7229614	1.17
223.0902405	1.11
225.2350464	1.60
227.0286255	2.40
229.4565735	0.33
230.71698	0.83
233.3381958	0.21
235.4104309	0.30
237.0766296	11.92
239.0939331	2.58
241.0255737	1.17
247.2445068	1.40
249.1107178	0.20
251.1907349	2.00
253.1416626	5.75
255.1674805	11.47
257.1528625	3.36
262.2352295	0.56
263.54953	0.43
265.2147827	3.00
267.1747437	0.75
268.1812744	0.53
269.9733276	0.38
271.2190857	0.50
275.1986389	11.41
281.0322876	0.50
283.1467285	2.71
291.1473083	0.28
293.202179	100.00
294.34021	1.25
295.2423706	0.21
302.1540527	0.71
324.8889771	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	197.04
Annotation	Unknow
Peak:m/z	Relative Intensity
58.7797928	0.13
66.9236298	0.13
68.9738007	0.50
70.9950561	0.21
76.8178406	0.15
78.8277969	0.07
80.7877350	0.18
87.9093170	0.06
89.9530640	0.15
95.0271759	0.57
96.1015320	0.62
96.9829864	0.18
98.8978577	0.46
104.8803864	1.71
106.9073639	0.41
107.7761383	0.08
109.0270386	1.78
111.0562897	2.03
111.8065033	0.25
112.6696930	0.13
115.9124146	0.10
119.0366669	0.68
121.1224060	0.09
123.0223694	1.39
124.7585297	1.71
128.7658844	0.18
129.7703705	0.20
130.6533356	0.10
133.1503296	0.54
135.0594482	0.95
136.7727661	1.26
138.0690308	1.37
139.1267242	1.88
141.0713043	1.67
150.9274750	100.00
153.0046387	1.81
153.8187103	0.27
154.9250946	2.15
155.8849335	3.74
156.6547241	0.30
160.9857941	2.40
162.1075592	0.19
164.8006287	0.13
168.1551056	1.37
169.0596161	0.55
173.7954865	0.59
174.6751862	2.16
176.2796478	8.33
177.0421906	0.36
178.0136871	1.76
179.0502014	12.46
183.5993805	0.34
185.2721252	4.31
188.1375580	2.27
191.0951843	0.53
196.7160492	0.37
200.2413788	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.18
Annotation	Garcinisidone D
Peak:m/z	Relative Intensity
131.9795532	0.03
132.6654816	0.15
143.0639954	0.16
145.0655518	0.10
161.0033875	0.28
161.8862762	0.06
164.9859619	0.04
178.9669800	2.14
180.0613403	0.20
181.3102417	0.63
221.0400543	0.16
232.9859009	0.03
251.9046021	0.03
265.2502747	0.06
281.1994934	0.59
282.4349670	0.24
289.2698364	0.12
294.9054565	0.05
303.0610352	0.76
304.1071472	0.44
305.0975952	0.17
306.4211731	0.04
312.3244019	0.07
337.1382751	0.04
341.0639038	1.81
343.1551819	100.00
343.7619019	0.40
356.1752014	0.02
365.7707520	0.02
374.9289246	0.04
376.4076538	0.23
377.2081909	0.35
380.8502197	0.03
383.0276184	0.02
385.3631287	0.04
429.0003052	0.11
430.2882996	0.13
431.1935730	0.04
439.1715393	0.06
456.5191040	0.28
457.2795410	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.153
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
114.9685211	0.87
118.8851471	1.80
136.8121490	1.27
150.9966736	28.67
174.9557190	0.76
180.9212952	3.28
189.0552063	15.90
207.0059814	3.07
227.2937317	2.51
238.2251587	1.07
249.0886536	0.42
253.0681458	0.60
255.0685425	1.78
263.1520996	0.68
269.2836914	0.53
272.8533936	0.99
281.1557007	5.31
285.2269897	7.26
287.1719971	64.76
301.0223083	0.47
313.2673645	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	328.1016
Annotation	Blepharin
Peak:m/z	Relative Intensity
95.0410156	0.02
123.9688263	1.38
126.7311859	0.04
128.8369598	0.07
131.0095673	0.03
132.9483032	0.01
134.1326599	0.06
138.0505371	0.07
142.1221924	0.08
145.3014526	0.03
150.8501282	0.05
153.1984558	0.04
165.9487305	100.00
166.7954102	0.03
169.0003204	0.05
171.0965424	0.03
174.9441986	0.06
175.7912903	0.15
177.1089325	0.06
181.8987579	0.09
184.1723328	0.03
188.1619720	0.05
194.0247803	0.02
197.3217773	0.01
210.1206055	0.20
213.9720154	0.05
214.8003540	0.09
215.9922485	0.23
224.0269470	0.07
227.6580505	0.05
229.1667175	0.07
230.1937256	0.15
233.0287476	0.11
234.0762024	0.05
236.4210205	0.07
239.0546265	0.11
240.0243835	0.04
242.0009766	0.05
247.0611877	0.17
251.0547485	0.15
252.1897583	0.13
256.0122375	0.10
257.6039734	0.12
259.5776062	0.04
266.0431824	0.06
269.2042236	0.12
270.1833496	0.04
271.2857971	0.11
277.3233948	0.01
281.7411194	0.06
283.2982788	0.21
285.1885376	0.03
286.9224243	0.11
292.2537842	0.15
292.8544922	0.04
304.6533813	0.06
308.3549194	0.02
309.8890991	0.57
311.0897522	0.22
318.8825989	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
96.94992065	0.44
102.8311234	0.17
104.96241	0.09
106.9711533	1.00
108.9164581	2.67
110.7716293	0.12
116.868042	0.52
119.1555481	0.16
121.0128479	3.64
128.9324188	0.21
130.9743805	0.49
132.7736816	0.46
135.0831757	3.19
137.0644531	0.63
138.1486511	0.49
139.0664978	0.10
140.929245	0.05
142.9283142	1.46
145.2362671	0.18
146.9353333	2.46
148.9497986	1.10
151.1333618	0.33
153.0279083	0.27
157.0405579	1.16
158.0126953	0.04
158.9715881	0.50
161.0538483	2.65
163.1607971	0.95
165.25177	0.53
166.9125061	0.12
168.9064484	1.40
171.1798706	0.07
173.1335449	0.76
175.0249329	1.42
176.9357758	0.42
179.1114807	0.15
179.9459839	0.04
180.9524231	0.09
183.0923157	1.07
185.1441345	0.34
186.9886322	0.62
189.0488586	0.43
191.1396942	0.89
193.2571411	0.11
195.1291351	0.54
197.1283722	0.55
198.1415405	0.05
199.0903015	0.55
200.8784943	0.04
201.7217255	0.20
203.0856781	1.87
205.0858307	0.47
207.053894	0.08
210.9156799	0.90
213.2807312	0.27
215.0375366	0.47
216.0591125	0.13
217.2609863	2.09
220.1117859	0.31
223.2125854	1.09
225.0734253	0.10
227.0767212	0.45
228.2028503	0.17
229.3631897	0.20
231.1419983	0.55
232.7017212	0.32
234.2750244	0.20
235.3881531	0.32
236.2485657	0.32
239.0391235	0.46
241.4096069	0.31
243.0806274	0.52
245.1405945	1.30
246.0440369	0.26
247.2129211	3.95
251.1852417	0.47
253.0922546	0.46
255.1304932	0.11
257.3934631	0.37
259.1594849	0.24
263.0946045	0.14
264.3751221	0.04
265.1809998	0.12
267.164032	0.42
268.2242737	0.13
271.3153687	0.45
277.1911011	0.08
280.7727661	0.94
281.4383545	0.14
282.0957947	0.10
283.3961792	0.12
285.1938477	0.13
287.2026062	0.39
291.039093	0.15
293.2953796	0.15
295.3993225	0.68
297.2947388	0.06
298.1213074	0.16
299.2354126	1.01
299.9418335	0.30
300.5765991	0.09
301.229126	0.31
303.4335938	0.09
305.1751099	2.42
306.0115356	0.09
311.4950256	0.08
312.8104553	0.36
313.5479736	0.21
323.2402344	100.00
323.8536072	0.70
325.1813354	0.06
326.2346191	0.14
332.2440796	0.22
341.2481689	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.26
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
114.8936310	0.08
117.0231018	0.11
119.0747681	1.99
121.0375214	1.14
123.0246124	0.07
127.1670685	0.09
132.9758453	5.12
133.9381714	0.07
135.0804138	1.18
137.1563416	1.75
138.8860168	0.09
141.0426941	0.21
151.1224365	0.27
152.8941040	0.07
158.9192810	0.20
161.0537415	23.86
165.2025146	0.09
171.1487732	0.07
173.0098572	0.08
177.1362000	0.05
179.0262146	53.96
179.6289978	0.50
181.9672852	0.13
189.0702515	0.45
189.9255829	0.24
191.1746826	0.08
194.0504150	0.15
196.9755096	48.17
203.9731140	0.26
206.0999146	0.20
211.3229370	0.25
214.9345398	100.00
218.1805420	0.33
228.8858948	0.13
231.0467529	0.16
240.3346252	0.18
245.0665894	0.24
246.2196655	0.58
248.8939514	0.15
250.9799500	0.30
252.2876282	0.04
254.7803650	0.24
256.7389221	0.14
264.2036743	0.61
267.1621399	0.19
268.0573425	0.13
292.1237793	0.72
298.4563599	0.58
299.3025208	0.26
301.7147217	1.24
307.2359314	0.48
309.0943909	0.26
317.5402832	0.30
318.2465820	0.95
319.1549072	0.64
323.0597839	0.13
325.6475220	1.09
327.1755371	1.54
332.3483276	0.26
336.4035034	0.28
345.4955444	0.47
348.4100037	1.00
349.1945801	0.22
353.5170898	0.06
360.0886841	0.17
362.2756042	0.31
363.4333191	0.62
365.1628723	0.27
370.0525208	0.24
376.6593323	0.96
380.2496643	0.43
385.5128174	0.24
390.1593933	0.56
391.0136719	0.99
395.9282227	0.98
399.1569519	0.42
416.6409607	0.23
419.9735413	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.18
Annotation	Unknow
Peak:m/z	Relative Intensity
133.0085907	0.16
134.0791626	0.55
134.9120026	0.37
146.9465179	4.37
164.8979950	10.61
183.0483398	100.00
184.0400391	0.80
278.7781067	0.27
294.9550171	0.46
296.2434387	0.11
315.2921753	0.91
325.8500671	0.54
326.9505615	0.55
344.7548828	19.13
434.3926697	0.25
459.7259216	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.1458
Annotation	Proteacin
Peak:m/z	Relative Intensity
139.1888733	0.08
148.9606628	0.74
188.9813690	0.20
191.2455902	0.06
202.9160156	0.06
232.2415009	0.27
233.2658691	0.05
253.9995728	0.18
263.3100281	0.19
264.1434631	0.03
267.1775208	0.05
279.1069641	0.06
280.6577759	0.13
289.9708557	0.03
291.1423950	0.05
293.0640869	14.14
293.6882629	0.04
319.6096191	0.98
320.2690735	0.05
323.4311523	0.11
338.3732910	0.23
348.5179749	0.03
349.2285156	0.59
353.3766479	0.16
371.4653320	0.20
375.1991882	0.11
379.3185730	0.11
381.3637390	0.16
384.4832764	0.05
385.2705383	0.04
387.1132507	0.05
397.1853638	0.15
398.3672791	0.11
426.1078796	100.00
426.7582092	0.24
435.2419434	0.08
436.2424927	0.17
444.2975769	0.22
451.4557800	0.12
453.4075928	0.44
454.0816345	0.14
455.0803833	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1719
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2139130	0.04
170.5899811	0.03
171.2457123	0.13
172.9698486	0.54
190.9975281	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1013
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9391327	0.02
110.7047653	0.01
116.8725204	0.74
128.9560699	0.01
135.0239258	0.63
144.9331055	3.81
156.8804016	0.08
162.9051514	100.00
181.0484314	0.18
192.9142456	0.08
216.8872375	0.01
281.1305237	0.01
295.1337280	0.01
308.8258057	0.02
319.2321777	0.01
326.8942261	0.03
331.7826538	0.02
336.9902039	0.23
337.6974182	0.01
355.3596802	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.0986
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
169.0423279	0.06
179.0412292	0.03
180.1554108	0.18
251.2710419	0.10
264.9795532	0.23
272.1849365	0.72
285.1702576	0.63
290.0796204	0.12
309.1559448	0.21
316.3378296	0.27
318.3262939	0.08
323.0317383	1.12
324.1664429	1.19
325.1458435	1.57
330.1206665	0.18
339.1889648	0.08
355.2587280	0.05
371.4057312	0.42
387.3475647	0.21
393.3655090	0.08
395.5063171	0.17
397.1783142	0.38
406.9144592	0.83
409.0626526	0.44
423.1272888	0.17
429.2491150	0.27
433.4430847	0.22
435.2717590	0.10
437.4416809	0.28
444.4769592	0.23
445.9960632	12.79
447.1959839	100.00
447.8409119	0.08
449.2783813	0.19
459.9809265	0.08
461.3334351	0.50
474.3185730	0.41
475.4681091	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.19
Annotation	Celorbicol
Peak:m/z	Relative Intensity
83.06689453	7.51
96.97019958	6.58
100.0590515	17.06
101.5784378	12.21
110.9253387	7.87
125.0857086	4.64
130.1513367	15.24
141.0312805	7.08
145.8312988	20.97
152.1525269	17.41
154.8908844	19.87
158.4652557	5.74
168.0259399	16.41
175.1959381	7.23
189.0711212	6.59
208.8504639	4.66
215.1637115	4.86
216.2271576	5.94
223.2936249	15.43
224.7533417	17.32
226.2092743	5.14
226.8279724	8.41
235.1745605	29.37
241.0407715	5.93
250.5844269	12.04
253.1824493	100.00
257.8645935	19.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1434
Annotation	Unknow
Peak:m/z	Relative Intensity
181.2048035	0.03
185.1398926	0.03
195.3597717	0.02
231.9223328	0.19
250.0797119	0.74
268.1217346	1.19
286.1302490	100.00
324.2890015	0.02
362.7404785	0.01
382.0976868	0.15
394.2603455	0.97
403.1965027	0.03
406.7981567	0.02
410.1492920	0.11
412.1318054	0.79
419.3721619	0.01
430.2415466	3.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1767
Annotation	Rhododendroketoside
Peak:m/z	Relative Intensity
145.0047302	0.06
148.8840637	0.88
160.9971008	0.24
170.9900208	0.08
173.1398163	0.16
175.2744751	0.23
191.1171875	1.48
214.8846741	0.05
233.0565338	6.44
275.4119263	0.07
293.1000977	100.00
338.1315613	0.14
341.0656738	0.03
387.3528748	0.03
455.2191467	0.05
457.1116638	96.56
488.2817688	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.0275421	0.02
108.7812042	0.01
111.0682907	0.10
117.0248566	0.05
118.9091644	0.02
126.9355316	0.14
132.7591095	0.05
134.0176239	0.38
134.9837646	7.41
135.9849243	0.93
136.9623413	0.05
143.063736	0.04
144.9709473	0.01
155.0384521	0.22
161.0405884	1.03
162.1393585	0.04
173.0454102	2.24
174.1636047	0.08
179.0288086	40.34
180.0028076	4.16
191.0277405	100.00
192.0972443	8.30
278.2458191	0.02
307.2753296	0.01
309.2607727	0.06
310.3378296	0.09
335.3491516	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.221
Annotation	Byzantionoside B
Peak:m/z	Relative Intensity
112.9585876	0.72
119.0927124	2.12
122.9951553	1.28
132.932724	6.02
134.7825775	3.50
136.9595032	1.11
140.7799377	0.94
144.8721161	2.00
146.7021179	0.54
148.9300537	1.71
151.1438446	1.05
161.1214142	1.09
165.1171265	0.50
174.0049133	2.29
175.1847076	12.89
178.9628601	1.31
181.1856689	1.88
190.927124	0.96
191.8764801	1.13
193.049118	5.85
194.963089	1.02
195.829361	1.14
209.0767517	3.49
211.1701813	100.00
211.9736786	2.60
218.4367676	1.03
220.0384216	0.60
227.1402893	1.16
229.0368347	0.57
233.1145325	0.85
238.8465881	1.04
243.1212463	1.67
248.9129944	0.35
259.0945435	0.57
263.1833801	2.52
273.2124939	2.02
279.1945801	1.65
281.1420898	1.38
283.0669556	2.84
284.739624	3.27
291.4152832	2.01
294.2892456	0.74
299.3912354	1.19
301.1417236	2.82
305.4696045	3.72
306.2485962	0.61
307.5397339	1.34
309.2042847	3.56
313.1662598	6.05
317.2479553	1.02
320.3461304	0.72
323.3052979	3.48
325.155365	1.53
327.0640869	7.36
328.9378052	0.31
329.8131409	1.22
332.1020508	1.92
335.1450806	3.07
336.9214478	3.54
337.6854248	5.98
339.1980591	2.79
341.2727051	5.42
342.4886475	1.28
343.1805115	4.59
354.5218811	2.36
355.2036743	24.61
355.9889221	2.93
359.2180481	2.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	199.0975
Annotation	alpha-Carboxy-delta-nonalactone
Peak:m/z	Relative Intensity
70.9516449	0.03
95.9108124	0.02
107.9651489	0.01
111.0028534	0.03
125.1046906	0.06
127.0233459	0.19
131.0740356	0.04
137.1221161	0.32
139.0522308	0.06
150.0666962	0.05
150.9564667	0.04
155.0421295	100.00
156.2159882	0.02
163.3231506	0.02
169.1177368	0.05
171.1155090	0.04
172.6611786	0.05
178.8016510	0.02
181.0607300	0.51
182.7686462	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.1071
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9971771	18.05
164.0662842	1.15
193.1585999	0.22
216.9511414	0.23
221.3052521	0.09
239.2809906	0.06
271.3225708	0.05
276.8190918	0.17
279.2419434	0.15
308.1845703	0.04
344.2230835	0.25
353.4141846	0.12
355.0981445	14.90
356.3287964	0.79
358.2822876	0.12
361.2086792	0.15
362.1859131	0.14
366.8491211	0.06
374.4556885	0.04
379.0678101	0.82
381.9634399	0.42
394.6746216	0.07
396.1001587	0.08
397.1807251	0.13
401.0039673	0.06
407.1296997	0.10
408.2026978	0.28
409.2056274	0.33
414.7759399	0.08
419.1888428	0.27
427.6118774	0.05
437.2689209	0.18
439.0001221	0.18
443.2959595	0.15
450.9830933	0.09
462.8513794	0.13
477.9057007	0.12
479.7713013	0.08
480.7781372	0.18
493.0963135	0.33
494.6232300	0.44
498.8464355	0.19
510.8204956	0.10
520.4010010	0.10
523.0473633	0.17
525.4219360	0.11
539.0000610	0.40
540.5806274	1.25
541.2816162	2.95
542.0401001	0.13
565.2084351	0.05
568.5526733	0.15
569.2620239	0.26
570.5740967	0.98
571.2418823	4.24
571.9048462	0.19
573.7135010	0.05
582.2500610	0.16
585.2457886	0.18
589.2109985	0.52
599.3030396	0.36
601.1099243	0.86
663.5376587	0.12
717.8295288	0.27
719.0928955	0.08
745.1822510	0.05
761.2242432	7.24
762.2322998	21.23
763.1299438	100.00
764.2293091	6.53
792.8058472	0.18
801.5480347	0.24
803.3037109	0.28
837.4287109	0.08
953.2141113	0.39
954.0075073	1.64
954.8934937	2.52
956.2998657	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2612
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
559.1212158	0.04
847.0998535	0.06
965.414917	0.12
983.2631836	0.04
985.4431152	0.03
1009.570679	0.07
1025.679565	0.03
1091.342896	0.10
1109.297852	0.08
1135.158447	0.19
1153.254272	100.00
1154.006714	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8811493	100.00
130.4503632	0.23
207.0982056	0.11
210.6501160	0.23
212.2399597	5.36
212.8508606	31.18
219.2046509	0.13
233.8814087	0.03
250.3997803	0.09
251.0298462	0.05
253.4623108	0.10
269.0309753	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1396
Annotation	Qing Hau Sau
Peak:m/z	Relative Intensity
82.8312912	0.08
95.18641663	0.05
98.82930756	0.08
104.9578857	0.10
111.0347137	0.24
112.8753815	0.02
118.9260254	0.52
120.9765472	0.69
123.018219	7.07
125.1635056	0.07
127.1303024	0.05
129.0897522	0.15
132.9637756	0.55
135.2184601	0.03
136.9582825	0.03
139.0310364	0.42
143.0068665	0.15
145.1269989	1.70
148.9736633	0.12
151.2024841	0.20
153.010376	1.99
155.1294861	0.15
157.8061218	0.05
159.1626282	0.64
159.9519958	0.04
163.5320282	0.11
164.1604919	0.04
165.1810303	0.13
169.1401672	0.12
171.1268616	13.25
173.3851471	0.03
175.1734619	0.49
176.0756683	0.02
177.1747131	0.25
187.2593079	0.14
189.0994568	4.97
191.2558136	0.11
201.0935669	7.08
205.1841736	0.07
207.0756226	8.70
215.3865356	0.13
219.1195374	12.27
221.0314636	0.05
235.0415344	0.13
237.155304	100.00
261.943573	0.04
262.9832153	0.27
264.0830994	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0027
Annotation	SC-58125
Peak:m/z	Relative Intensity
129.0807037	0.54
130.8767700	0.11
155.0873413	0.08
166.8896484	0.04
173.0250549	1.68
184.9574890	0.07
190.9873657	100.00
201.0687256	0.10
212.9396515	0.85
241.0290527	0.09
255.0421753	0.24
256.7993164	0.18
263.2624207	0.06
273.0867615	1.38
291.1002808	0.11
298.8157959	0.63
302.2954712	0.15
316.9298401	1.62
322.9186707	0.06
341.0264893	0.19
342.7385864	0.22
359.1513672	1.30
366.9678345	0.11
374.8109741	0.13
385.0042725	0.92
403.1025696	4.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1868
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
108.6604614	0.17
112.9502563	3.12
119.0007324	1.54
122.0087814	0.78
125.0021210	0.77
129.0009766	0.91
131.1463623	0.09
135.0489044	0.50
136.0226746	0.64
137.1795197	0.86
138.0444336	2.17
143.0347137	1.67
147.1398926	0.46
149.0219879	0.47
151.0215454	0.53
153.0464783	100.00
159.0507507	3.04
161.0003052	17.33
161.9209290	1.13
165.0928955	1.26
172.1133118	0.13
176.8656311	3.07
178.5191040	0.50
179.1713867	1.04
181.0442505	0.74
187.1737823	1.73
190.2144470	0.72
191.3163452	0.19
193.0397491	0.24
201.3531189	0.15
203.1444092	0.47
205.1565552	68.52
217.0740204	0.11
221.2973328	0.06
223.0641479	34.95
229.2238770	0.16
231.5424500	0.05
233.3079224	0.65
235.0691223	0.44
247.1085205	0.61
253.1063232	0.24
263.2286682	0.16
265.1677856	0.49
289.3101807	0.27
295.2352905	0.05
301.1911011	0.26
307.2084961	0.83
313.3377686	0.19
337.3469238	0.08
339.1950073	0.24
341.1801147	10.38
343.3398132	0.20
349.2832336	0.33
364.2437439	0.16
365.3021545	0.15
367.1645813	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8218536	33.13
212.8804169	15.85
218.9421997	0.20
261.1090393	0.35
268.0179138	0.89
270.3206177	0.82
271.2473755	0.23
279.1277161	0.10
296.2123413	12.71
296.8318481	100.00
334.5391846	0.15
362.8182068	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0338
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
120.9589233	0.07
129.0059052	0.01
135.0639801	0.03
139.0261688	0.07
146.9319916	6.70
156.9068909	0.51
163.9888458	0.12
164.8161316	0.22
170.1831818	0.20
172.6581421	0.03
174.8199158	100.00
175.6802826	0.00
184.4203033	0.01
187.8414764	0.02
192.7732544	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.19
Annotation	Unknow
Peak:m/z	Relative Intensity
120.8843765	0.22
130.1371307	0.04
130.9456177	0.34
136.9113770	0.31
144.9062958	0.09
147.0702820	0.05
160.9210663	0.77
163.3196411	0.25
175.1001282	0.06
179.1571350	0.07
191.1517487	0.16
195.3021240	0.14
197.4454651	0.13
200.7454071	0.08
207.0959473	1.82
209.0385742	0.13
211.1506958	100.00
222.9868011	0.26
225.3135529	0.45
232.9606323	0.05
239.1452026	0.15
241.5094910	0.08
243.2454834	0.55
247.1105042	0.08
253.2919312	0.65
257.1575623	2.75
259.2836609	0.10
261.1302185	0.28
265.2579651	0.24
270.9759827	0.20
274.2478638	0.13
283.1303711	2.27
285.3959351	0.13
287.2520447	0.08
295.1435852	0.08
296.2982178	0.14
297.5559998	0.13
299.1052551	0.78
301.0463867	0.20
305.5543213	0.06
312.5351257	0.30
313.5811157	0.07
323.3952332	0.15
323.9963989	0.15
327.3901367	0.11
328.4468079	0.14
330.2257996	0.22
341.1916504	0.04
345.3110046	0.62
347.1325684	0.15
351.0260620	0.14
355.2133484	0.85
357.3799133	0.29
359.4220276	0.29
371.1756897	0.10
372.5959778	6.32
373.2315979	16.74
375.3739014	0.97
376.2257385	0.25
380.2408752	0.22
383.1030579	0.55
389.1515198	0.19
399.0844727	1.00
401.3515930	1.48
404.2950439	0.06
420.2189941	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
125.0464096	0.19
144.8372192	0.04
147.1701202	0.14
149.0896912	0.10
163.1315918	0.14
165.0045471	0.02
172.9812317	0.04
173.9958191	0.02
174.8902283	0.07
177.0345459	0.30
179.0390320	0.02
183.0070801	0.02
184.8331909	0.05
186.8590088	0.03
188.9443359	0.16
191.1748352	0.30
195.1220398	0.05
199.0025024	0.10
201.0908813	0.64
203.0561981	0.07
211.3864594	0.07
212.3151093	0.07
213.1151428	0.08
214.2935333	0.05
215.3413086	0.05
216.1300354	0.03
217.0682068	0.55
219.0928040	0.01
221.2064362	0.11
223.1133118	0.02
225.0025635	0.06
227.0342865	0.04
229.3230133	0.03
231.0151367	0.15
237.0941467	0.02
239.1984253	0.16
240.3796997	0.15
241.0987549	1.08
242.0664673	0.04
243.0971375	0.88
254.3513184	0.09
255.1589355	0.33
257.0285034	0.50
258.9554138	0.09
260.3446350	0.05
261.0976562	0.07
264.8963013	0.01
267.0975037	0.43
269.2778320	0.58
270.1962585	0.14
271.2260437	0.31
272.5780029	0.05
273.2144775	0.02
275.1462402	0.11
280.9712524	0.65
283.2337952	1.23
284.0885925	26.91
285.0818176	100.00
287.1947021	0.10
291.0300293	0.11
293.1761169	0.17
295.1371765	0.73
296.0354919	0.05
297.0882263	2.16
299.1069336	5.43
301.0466309	0.08
303.1434631	0.46
307.1851807	0.01
309.1759949	1.19
311.1883545	0.27
313.2360229	0.25
319.1153259	0.16
321.1455078	3.05
323.2647095	0.09
324.0663452	0.04
325.5065918	0.24
327.0924683	3.24
329.3862305	0.17
337.2542419	0.27
339.0807800	1.83
339.6903076	0.04
341.0968018	0.05
343.4027710	0.08
351.1957397	0.52
353.4190369	0.04
355.2534790	0.08
357.2839661	0.70
359.2556458	0.05
361.2638245	0.05
363.2855835	0.06
365.4529114	0.09
367.2617798	0.02
369.2308044	0.61
377.2262268	0.05
379.3844910	0.07
385.2390747	0.27
387.3047180	0.24
393.1682129	0.01
394.2269592	0.02
399.3786621	0.06
400.2026062	0.06
401.2101746	0.12
403.2094421	0.12
405.0907593	0.04
411.2902527	0.20
419.4158936	0.06
429.2792053	1.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3226
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
166.0380859	0.05
177.0877686	0.06
180.7820740	0.04
184.0185394	39.84
193.0580902	0.11
209.2870178	0.07
251.2261963	0.26
258.2466431	0.95
283.9852295	0.26
337.3519287	0.11
347.3188477	0.08
383.6040649	0.20
385.1316528	0.09
397.1897583	0.10
433.6353149	0.13
441.4721680	0.67
468.1896362	0.07
482.2155762	0.08
489.4318237	0.06
500.4979858	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
129.0480042	1.99
129.9477081	0.87
132.9759674	1.13
149.0627441	1.09
153.0860291	0.23
169.8658905	5.03
179.0809784	0.26
183.0065002	100.00
184.0382385	6.86
197.0182495	7.83
197.9885559	5.09
209.3227234	0.30
211.1432495	1.39
212.0186157	1.02
213.1534424	0.88
215.2237549	0.74
222.9618225	0.76
225.190094	5.16
226.0735474	0.55
228.9317932	0.41
239.2528687	2.22
243.0660706	0.79
247.2930908	4.34
249.3225403	3.79
251.4174805	0.60
252.3269653	0.44
253.1372375	1.69
254.1721497	1.27
254.8067017	0.45
256.1977234	0.58
262.7918396	0.43
265.1473389	1.65
267.1800232	6.59
268.1679077	0.30
281.1584473	0.87
293.2371216	19.49
311.4097595	19.36
312.3256226	4.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.2169
Annotation	Unknow
Peak:m/z	Relative Intensity
111.6281815	0.61
118.8324203	0.67
120.8957596	0.16
123.0874329	0.61
123.8438873	0.62
126.9832001	2.64
133.2830963	0.63
135.9447327	1.29
140.2161865	0.33
146.8890228	1.27
148.9556580	2.00
149.9174194	0.43
154.9365997	1.39
164.9372559	2.45
166.0427856	3.05
167.0351257	0.66
174.2913818	0.64
182.0023193	13.37
183.0549774	11.05
186.9164124	0.23
189.1773224	0.16
192.0346375	0.20
192.8027191	0.12
194.1452026	6.44
195.2121429	0.09
201.3176270	0.27
202.0457306	2.49
205.9462280	2.14
211.0011292	55.81
212.9251556	0.10
220.3070221	0.16
228.9742432	0.27
231.1541748	4.34
234.9108582	0.25
248.1465759	35.41
251.9868164	0.09
258.1553345	0.12
261.0893250	0.46
265.1125488	100.00
265.7657776	0.15
273.3053284	1.82
275.3449097	0.51
281.1051636	4.64
291.1544800	1.55
293.2941895	0.76
303.2084961	0.68
307.3459473	0.84
311.3869934	0.62
314.9996033	0.45
319.1460571	39.35
319.7632446	0.20
321.1217041	0.62
331.3078613	1.23
332.1528625	0.28
339.3639526	0.13
346.1051025	5.36
347.1754456	15.76
357.2675171	2.57
364.2664795	36.55
374.2951050	20.08
375.1927490	30.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.1272
Annotation	Robustaside B
Peak:m/z	Relative Intensity
146.2607117	0.26
152.6767426	0.70
167.1362915	0.24
179.3549194	0.15
206.8678284	0.18
227.0038757	0.09
234.8424683	0.11
249.1598511	0.49
255.0362244	0.26
269.0961914	0.11
271.6650391	0.16
273.1175537	100.00
274.2539062	0.07
276.9558105	0.11
283.1650391	0.13
294.0205078	0.50
301.1575012	0.18
312.5649414	0.15
313.4403687	0.17
315.3332825	0.11
323.0083923	0.15
325.2871704	0.70
339.2440186	0.37
347.3144531	0.13
353.5567627	0.42
356.3207397	0.18
362.1455994	0.09
365.2987976	0.26
367.2614746	0.37
368.4482727	0.34
369.1897278	0.08
381.0295410	0.19
385.2589417	0.31
389.1096497	1.07
391.2088013	0.05
392.2400513	0.19
393.8152161	0.04
399.0988464	0.93
403.6474915	0.86
417.0044861	2.41
418.0324097	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	286.09
Annotation	Buchananine
Peak:m/z	Relative Intensity
80.9815216	0.30
84.9155731	0.37
86.9180679	0.02
96.9356384	1.45
98.8897552	0.97
105.8832703	7.45
108.8689575	6.36
110.0737305	0.02
111.0339203	0.04
112.2142639	0.03
115.9872742	0.27
123.9885330	63.59
126.9655762	5.42
141.1615448	0.02
144.9060364	0.66
146.5679626	0.09
147.1930237	0.16
155.1298523	0.19
155.8872833	0.05
157.2118683	0.17
166.0425720	0.59
167.6509399	0.06
169.2818604	0.04
171.2394104	0.07
174.0258331	0.02
175.0643158	0.02
178.0488281	0.18
183.2405701	0.04
184.2373352	0.09
186.7940521	0.06
188.1764374	0.05
190.0075073	0.95
196.1025391	1.31
197.1964111	0.29
201.3612366	0.27
202.0052490	0.35
204.9517212	0.07
208.2300720	0.38
209.9724731	0.06
211.1881714	0.04
212.5421143	0.05
214.3592529	0.06
222.0952454	0.33
223.0321045	0.02
225.0527344	0.13
225.9883728	0.19
227.0286560	0.01
229.2377014	0.07
232.0875854	1.75
238.2294617	0.05
240.1224670	0.36
241.1255798	0.21
243.3191223	0.22
244.4560547	0.24
245.2039795	0.11
250.0360718	100.00
257.3726807	0.13
259.7828979	0.02
263.4936523	0.07
268.0471191	62.78
268.7584839	0.40
269.4502869	0.08
276.8538818	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
153.7052155	0.08
158.8097229	0.12
159.9364624	0.12
161.0440979	0.04
175.3698730	0.09
178.1591797	0.24
225.5097046	0.07
276.1293945	0.21
283.8867798	0.07
287.2377319	0.15
299.2570190	0.31
309.3153687	0.47
313.0432129	0.09
315.0350342	1.61
323.2157593	0.09
329.1746826	100.00
335.3090210	0.12
336.8697510	0.08
341.1359863	0.37
355.2285156	0.08
359.0792847	27.37
371.2222290	0.44
373.1192017	0.43
377.0274658	0.30
385.2950439	0.08
387.3092041	0.30
399.2449951	0.25
401.3627930	0.78
403.4815674	0.84
405.2808838	0.23
419.2180786	0.32
421.2576904	0.11
423.3975220	0.08
424.8224487	0.16
425.4455566	0.10
435.5963745	0.08
437.4016724	0.48
461.4199219	0.11
473.9414062	0.56
475.3134766	0.77
476.5656128	0.18
477.3308105	0.82
485.1906128	0.13
491.2826538	0.06
501.1220093	0.63
503.2617798	0.99
506.6271362	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.1252
Annotation	Unknow
Peak:m/z	Relative Intensity
299.3008728	0.09
304.5057983	0.15
324.0323486	0.26
326.1860352	0.20
328.4544983	0.22
330.2892456	0.75
343.2677917	0.33
353.3602905	0.28
365.1447144	0.15
380.3091431	0.58
450.2924805	0.21
493.8734741	0.79
495.3175659	0.32
516.7160645	0.14
517.7918091	0.69
531.5070801	0.25
533.5513916	0.43
545.7725220	0.47
564.8290405	1.31
578.7637329	0.23
585.4686890	0.47
586.5273438	0.55
587.6951294	0.53
599.4715576	0.24
609.2720337	0.35
614.2505493	1.03
615.5827637	0.86
627.4416504	0.23
633.9650269	0.79
650.4968872	0.22
651.5906372	0.13
661.5463257	0.49
662.7262573	0.26
663.5902710	0.19
671.1675415	0.68
683.5417480	1.74
684.7562256	0.79
687.4929810	1.28
691.1383667	1.54
694.6555786	1.88
708.4944458	0.49
709.4038086	0.50
710.7814331	0.81
712.5217896	0.22
717.6860352	0.30
722.7009888	1.08
724.4497070	0.54
730.1926880	3.12
734.4411011	0.26
735.8369141	1.48
736.9049683	0.73
740.9299927	0.40
742.6143188	1.57
747.4944458	0.41
750.8807983	1.15
757.5368042	2.04
758.8063354	1.83
762.2235107	0.79
764.3651733	1.69
765.2997437	1.63
766.3618164	0.86
768.1301270	6.16
771.3668823	0.84
773.8387451	1.18
777.5352173	0.49
778.6221313	0.36
783.0446777	1.04
784.5496216	0.44
786.3049316	0.26
789.2658081	0.75
790.1339722	0.47
791.7976685	1.48
793.1007080	0.76
797.8305664	6.73
798.5670776	0.86
802.8168945	0.54
805.7357178	0.18
814.0648193	1.46
814.8037720	1.54
815.4522705	0.92
817.6213989	0.80
836.9629517	1.13
840.6984863	0.68
866.9057007	1.24
869.3453979	1.86
870.6494751	2.78
871.3704224	1.01
875.4729614	1.12
883.2319336	0.55
887.0122681	0.90
887.7215576	0.79
889.4785156	0.98
890.2229614	0.77
892.1998901	1.03
894.7620850	0.17
898.1056519	0.97
901.8649902	0.14
903.7788086	1.46
906.5761719	0.89
907.3635254	1.05
921.4133301	0.61
924.0927734	0.42
927.0973511	0.87
928.6930542	0.53
934.2658691	0.54
938.4796753	0.29
939.5037231	2.07
940.2521973	1.07
941.8124390	0.45
942.8403931	0.85
947.3883667	1.13
948.1868286	0.65
953.0830078	0.14
963.5326538	0.75
964.7097778	0.28
969.2124023	0.14
975.2775879	0.44
975.9450684	0.32
978.6969604	2.66
993.4777222	1.11
996.9078979	1.11
997.5695801	0.44
1003.6939090	0.39
1005.3981320	1.12
1007.2492680	1.08
1013.0582890	0.60
1014.3042600	0.69
1026.0922850	1.02
1027.5244140	1.00
1031.4854740	1.47
1038.8637700	0.62
1045.7014160	0.96
1052.1491700	0.41
1053.3984380	6.58
1054.3989260	0.70
1070.4516600	1.41
1073.9207760	0.62
1075.2799070	0.37
1076.0438230	1.67
1079.1442870	0.42
1088.2593990	0.99
1090.6632080	0.62
1094.9141850	3.37
1095.6909180	3.28
1096.3297120	1.07
1103.9597170	9.17
1104.8182370	2.52
1106.2916260	5.16
1117.6125490	0.65
1121.6766360	0.67
1123.0280760	2.02
1130.6350100	0.51
1132.2244870	0.79
1133.9344480	0.40
1138.0102540	0.55
1138.7595210	0.22
1144.1687010	0.44
1145.8210450	1.59
1146.5728760	0.35
1151.2165530	1.49
1152.0195310	1.00
1152.6992190	0.15
1153.7469480	0.68
1160.2536620	20.51
1161.1269530	10.32
1161.9497070	0.66
1164.0043950	0.65
1170.9497070	1.20
1179.8085940	1.70
1180.8562010	0.37
1188.5739750	7.86
1189.5904540	7.35
1190.3673100	1.32
1195.1557620	0.55
1196.5572510	1.06
1197.9851070	0.43
1205.2813720	1.32
1253.3364260	0.49
1272.7760010	0.75
1357.9215090	0.53
1366.1662600	0.39
1426.1522220	0.25
1452.3953860	0.45
1534.3011470	0.45
1567.9875490	0.40
1585.2967530	0.18
1591.3851320	1.71
1628.4249270	0.12
1699.4694820	0.23
1717.2536620	0.36
1721.9246830	4.04
1730.1136470	0.12
1743.0787350	0.38
1746.5651860	1.14
1755.7023930	0.15
1763.6164550	0.24
1764.5178220	0.35
1771.1916500	0.17
1777.8851320	1.95
1796.2185060	0.36
1819.6041260	1.36
1831.3372800	0.26
1862.5594480	0.48
1867.7308350	0.35
1887.8162840	0.39
1895.0588380	0.27
1903.3034670	5.66
1917.0137940	0.44
1918.2689210	0.12
1925.8992920	0.35
1928.6877440	0.25
1942.2048340	0.18
1966.7092290	0.23
1975.4450680	42.12
1982.3914790	0.11
1995.8499760	100.00
1997.8518070	34.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.239
Annotation	Unknow
Peak:m/z	Relative Intensity
131.2139893	0.07
140.8937073	0.06
142.9732208	0.09
149.0923615	0.03
153.1345673	0.05
157.1109009	0.50
159.0666199	0.05
161.1152496	0.23
172.8402710	0.07
178.8254089	0.02
180.9518433	0.05
183.1845093	0.03
191.1038818	0.02
195.3424683	0.07
201.2802124	0.07
221.0667725	0.06
227.1325989	0.03
229.2996063	0.28
239.2991028	0.21
253.4177246	0.04
255.1048889	0.04
257.2305298	1.67
271.3840027	0.03
273.1775513	0.21
275.3009338	3.39
299.4148254	0.03
301.4242554	0.02
311.1968079	0.15
317.3056641	0.15
318.9362183	0.04
335.3027954	0.42
345.4471130	0.06
357.6636963	0.22
363.2405701	0.32
365.2806396	0.08
373.5677795	0.03
375.3687744	0.60
383.2758179	0.47
391.0939331	0.24
401.3843994	3.48
402.1261292	0.09
417.4850769	0.11
419.3034363	100.00
420.3363953	2.27
438.5251770	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1876
Annotation	Baenzigeroside A
Peak:m/z	Relative Intensity
151.0191803	0.91
159.2054138	0.06
161.0453949	0.30
175.2209167	0.09
176.9870300	0.06
179.1554718	0.10
189.2543488	0.01
195.1748047	0.28
196.8973694	0.01
199.0717773	0.06
203.4427185	0.01
204.9100647	0.18
210.8778992	0.03
216.9307251	0.04
223.2220459	0.02
225.1870117	0.03
227.3454285	0.05
237.3211670	0.07
249.2441101	0.02
285.3688660	0.04
295.4364014	0.02
296.0419617	0.03
299.4448853	0.03
311.3179321	0.35
313.2443237	0.14
322.9348145	0.03
325.1607666	0.03
327.2805176	0.07
329.3500366	0.07
333.1157837	0.02
339.1773682	0.10
340.3779907	0.03
341.2545166	0.06
342.1507568	0.20
343.0474854	0.06
354.2510986	0.07
357.2078857	100.00
359.4403076	0.07
364.2669067	0.01
366.7933350	0.08
373.1290283	0.06
375.5350342	0.04
383.1906128	0.50
399.1990356	0.42
401.1766357	1.27
403.2167358	0.14
409.1425781	0.06
423.3249512	0.11
427.2131348	0.05
429.4720459	0.02
443.3640137	0.13
444.4835205	0.04
446.4039917	0.05
447.1903687	0.04
456.4599609	0.10
459.2160645	0.03
472.6577759	0.46
473.3163452	2.66
474.3023071	0.53
475.3210449	0.21
483.2564087	0.07
499.5694580	0.07
501.2813110	1.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.119
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
101.1191711	0.09
112.8252487	0.13
119.1708679	0.06
121.1851959	0.34
125.1300507	0.07
143.1324463	0.23
147.8940277	0.16
153.0982361	0.14
154.1473541	0.26
155.0318298	0.03
161.1913757	0.35
165.2003784	0.08
169.1304932	0.06
179.0078735	0.73
181.0462189	0.49
182.1303558	0.24
183.0056763	0.08
203.1247711	0.09
221.0465698	0.12
226.9563904	0.11
233.1133423	0.10
239.4219360	0.08
244.2581787	0.06
249.1997375	0.06
253.0252380	0.25
257.3125000	0.07
258.3007812	0.04
259.1028442	0.43
260.2381287	0.13
261.1539001	0.48
269.2339478	0.30
271.1026917	0.18
284.8946533	0.06
286.8649292	0.17
299.1927490	100.00
300.3306885	0.69
301.0603333	1.79
302.2358398	1.12
311.0677185	0.15
326.2975769	0.31
327.2498169	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.2285
Annotation	Euodionoside E
Peak:m/z	Relative Intensity
141.2372437	0.31
159.0275574	0.45
160.9119568	1.75
219.0988617	0.19
233.1878662	0.75
257.2471619	3.20
317.5463562	1.03
325.2937927	0.47
343.3515930	1.16
371.2676392	1.33
373.2851868	100.00
375.3756714	2.88
401.2546082	11.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2618
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
557.2226562	0.06
739.4746704	0.14
827.6561279	0.05
966.508667	0.06
1000.212402	0.04
1001.014648	0.12
1136.421875	0.26
1153.269531	100.00
1154.294434	53.90
1154.958496	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1616
Annotation	b-D-Xylopyranosyl-(1->4)-a-L-rhamnopyranosyl-(1->2)-D-fucose
Peak:m/z	Relative Intensity
124.8714218	1.07
130.8884583	0.91
136.9772949	0.03
138.9486694	0.07
148.9465332	3.26
153.1989136	0.09
172.9454346	0.18
190.9882507	1.08
221.0087738	0.30
232.1028595	0.13
233.0845490	0.62
250.5340576	0.08
275.1116333	0.30
278.2178955	0.05
279.2301025	0.06
293.1547241	58.51
313.2848511	0.08
314.7612305	0.26
323.2027893	0.15
325.2312012	0.04
339.0910645	0.72
393.3400269	0.08
395.1463318	100.00
398.4473877	0.06
405.1510620	0.11
423.1788940	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.239
Annotation	Unknow
Peak:m/z	Relative Intensity
127.1218414	0.02
139.1400146	0.03
142.0062256	0.03
142.8689270	0.04
144.2374725	0.03
150.9820557	0.04
155.0623322	0.06
156.9736633	0.48
158.0443115	0.05
159.0790100	0.06
160.9973755	0.22
162.0455627	0.04
173.0809326	0.05
179.1203613	0.04
187.2038574	0.07
190.8463135	0.02
199.1475220	0.03
201.2880249	0.03
213.3737335	0.21
221.4715271	0.03
222.3686218	0.02
229.1540680	0.26
230.4224701	0.03
235.1330719	0.06
239.3648987	0.02
240.5104370	0.05
247.2892151	0.12
257.2939148	1.60
258.2753296	0.22
265.2940369	0.03
273.4097595	0.05
275.2013855	1.98
276.2213440	0.40
299.4460449	0.02
301.0976868	0.30
302.2083130	0.03
315.7238464	0.04
317.3559570	0.07
319.5475464	0.09
323.2259827	0.09
335.3151550	0.69
337.4378052	0.04
340.2890625	0.06
347.2821655	0.12
357.5141602	0.17
358.3460083	0.05
363.3112793	0.45
364.2877808	0.06
365.5372925	0.03
372.1515808	0.05
375.1759338	0.69
376.3781128	0.18
383.5077820	0.77
384.5408936	0.16
389.3401489	0.02
391.3226318	5.15
392.3786621	2.77
399.1636353	0.06
401.3777161	3.97
402.3796692	0.93
407.5767517	0.08
417.4271240	0.14
419.3565674	100.00
420.3635254	19.67
421.2480469	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2746
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0887146	4.04
197.0718994	10.68
225.0196991	0.11
233.1061096	0.05
247.0744629	1.44
247.6810913	0.07
266.1962280	0.07
294.0552368	0.08
312.1782837	1.01
326.0618286	0.29
329.9314575	0.07
335.4865723	0.13
344.2164917	100.00
344.8402710	0.36
351.5026245	0.28
356.5903320	0.07
357.2603760	0.09
365.0269775	0.25
377.2741089	0.47
378.3793335	0.84
382.1967773	0.21
383.4546509	0.29
393.2978516	1.32
396.3588257	0.07
403.2118530	0.40
410.7025146	0.62
411.3218384	6.59
412.3743286	0.17
443.5587158	0.21
453.5748901	0.07
457.3973389	0.12
462.1329346	0.20
469.8384399	0.55
489.2638550	0.23
498.5869141	0.12
506.2656860	0.85
511.8931274	0.40
522.4844971	0.48
523.4265137	0.11
531.2702026	0.13
536.9321899	0.26
539.1516724	0.31
540.2401733	4.04
541.3500977	0.56
558.8751831	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0433044	0.03
152.9674683	0.05
179.1437836	0.04
196.0486755	0.20
214.0863800	1.80
215.0248718	0.03
227.1931152	0.02
234.5783234	0.02
251.3079834	0.02
261.3874512	0.19
262.4531860	0.10
279.2931519	100.00
280.2601624	22.11
280.8812256	0.15
286.0165405	0.02
289.2156982	0.01
299.3567200	0.04
339.2380371	0.03
341.3374634	0.05
345.5390930	0.02
391.0297852	0.01
393.1626892	0.18
408.0235901	0.05
413.2279358	0.09
417.2235107	0.02
423.0830383	0.03
431.3489075	0.11
433.3670349	0.04
434.3573303	0.02
435.0680237	0.04
441.3978882	0.04
450.2377014	0.02
457.3461304	0.02
459.1088867	0.18
470.9108582	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1971
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9989929	3.62
114.9049683	0.07
118.9131165	2.10
124.9376602	0.20
130.9660645	2.13
141.0589142	0.20
142.9050903	3.70
148.9426270	0.55
160.9603577	1.90
178.9785767	11.91
180.0161285	0.07
180.9358368	0.07
183.1049347	0.79
190.9510193	0.90
193.1615753	0.16
207.2041016	0.21
209.2482758	0.20
211.0939178	100.00
213.3111725	0.13
225.1582642	0.12
229.1522827	1.37
233.2711487	0.21
253.9055786	0.14
255.2520752	0.12
267.2625122	0.14
300.8975220	0.19
314.9619751	0.07
319.3345642	0.06
331.3509216	0.09
333.1492920	0.07
345.0414429	1.42
346.8329468	0.32
347.4966125	0.29
349.0368042	0.11
355.4084778	0.78
361.4146729	0.11
372.7850037	0.51
373.5372314	0.94
399.3362732	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	PD 169316
Peak:m/z	Relative Intensity
113.1299973	0.48
134.8655701	1.13
151.0366821	4.78
152.9453125	1.28
161.063446	1.98
164.0357056	0.19
178.9277191	9.67
179.9881592	0.46
191.1170807	0.17
196.9789429	4.49
205.3347931	0.17
217.103241	0.48
218.9725342	0.28
220.8614502	0.39
225.2840576	0.32
226.1688843	0.26
233.0786133	0.38
235.0211792	0.25
239.2647095	0.50
243.0878296	0.53
251.2685852	0.20
257.2248535	1.17
259.198761	0.41
263.0216064	0.11
268.7652588	0.28
271.0249634	0.35
299.0099487	1.29
301.1968079	0.32
313.1020508	100.00
315.2214661	0.81
323.0047302	0.33
331.0585022	0.93
338.2358398	0.58
339.3639526	0.38
341.3901672	1.76
349.7857666	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.161
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
116.1586151	0.08
118.8983002	0.09
123.3027573	0.06
135.1143494	0.11
136.9880066	0.03
140.0102692	0.05
148.7189636	0.05
153.3375397	0.07
158.8712158	0.04
161.0567932	0.26
162.8848877	0.08
179.2158508	0.77
181.0457153	0.70
183.0897675	0.06
197.1111145	19.72
203.2621460	0.09
205.2295685	0.08
221.2851257	0.05
223.1549988	0.66
225.1646118	0.07
229.0502319	0.07
241.0879517	100.00
247.3628235	0.22
255.1024170	0.10
260.0503845	0.05
263.0458679	0.08
265.1304321	0.08
267.2239990	0.22
269.4282837	0.05
277.1536255	0.16
281.2048340	0.05
283.2776184	1.15
289.8000488	0.15
291.2912292	0.13
304.9239502	0.46
306.0525208	0.06
306.8008423	0.10
313.2165527	0.07
341.0726929	0.02
343.1966553	1.00
355.9744568	0.18
357.0132446	0.87
359.2668762	0.57
361.3460083	0.60
366.0101929	0.02
367.1885071	0.07
373.4728699	0.06
375.1003418	0.10
376.3733826	0.11
385.2247620	0.63
387.1467590	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3305
Annotation	Unknow
Peak:m/z	Relative Intensity
205.9966736	0.04
217.1725311	0.02
224.2823181	0.03
242.1630554	0.15
261.5934448	0.09
279.3613892	15.97
343.2538452	0.03
429.5736694	0.09
459.4369507	0.02
467.5364990	0.03
468.3476562	0.10
501.4237671	0.04
504.3650513	100.00
505.4608154	0.70
518.4583740	0.11
544.3804321	0.11
546.4274902	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1012
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9311523	0.11
111.2331238	0.02
117.0099335	0.69
128.8928528	0.02
134.9709473	0.97
138.9282532	0.07
145.0073395	3.64
156.6834106	0.01
162.9017029	100.00
181.2894897	0.08
193.0277863	0.13
246.8464050	0.01
266.9797363	0.04
326.9271851	0.02
337.1260986	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Scopolin
Peak:m/z	Relative Intensity
109.1469879	0.01
127.077774	0.02
133.0863037	0.03
135.0144806	0.54
135.9632416	0.14
155.1220703	0.05
156.2170715	0.02
161.0847778	0.61
162.0692444	0.01
171.0337372	0.05
173.0663605	0.42
174.1211548	0.01
179.0949554	4.13
180.0974121	0.36
191.0271301	100.00
192.1066589	9.60
192.9059143	0.02
216.1445923	0.02
217.1724243	0.01
266.2059937	0.01
307.3584595	0.03
308.9901123	0.14
333.3639221	0.03
335.0457153	0.02
336.2511292	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2389
Annotation	Dictamnoside D
Peak:m/z	Relative Intensity
161.0157166	0.71
172.8140259	0.05
177.9119568	0.05
205.0306702	0.14
269.4776306	0.06
270.1932373	0.21
284.9555969	0.07
295.1544189	0.05
325.1346130	0.19
359.6136169	0.17
373.1695862	0.06
375.2926025	0.06
381.2039490	0.20
389.8627625	0.07
401.0649414	0.07
403.3506165	100.00
404.4299622	16.06
405.2536011	0.10
406.7154846	0.13
414.0550537	0.45
429.0038757	0.05
430.3128357	0.33
431.4573975	0.45
432.0863647	0.06
433.4565125	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2251
Annotation	Lactulose
Peak:m/z	Relative Intensity
280.6985779	0.16
339.2695312	0.62
341.2435303	100.00
683.1219482	16.71
683.8989868	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.1062660	0.05
84.9788666	0.57
86.8297043	1.33
100.8336945	0.10
110.8551025	100.00
111.7980347	0.03
127.0706482	0.07
129.0099030	2.04
130.8189087	1.05
145.1016693	0.03
154.8699799	0.53
163.0767670	0.03
172.9313660	19.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2112
Annotation	Rhododendroketoside
Peak:m/z	Relative Intensity
137.0243835	3.26
144.9626160	7.95
150.0010834	4.48
150.9591217	0.81
157.1157837	1.11
161.1853638	1.43
162.9714355	1.25
164.9879303	18.28
174.9248505	10.83
177.1350403	7.61
183.0634613	2.43
189.1774902	2.44
195.1105652	0.99
201.1100922	13.72
203.1694641	1.72
204.7030334	3.45
207.1224060	3.79
211.1087646	0.84
215.0701141	3.79
217.2566376	1.42
222.9694977	9.83
229.0992737	1.20
230.9971008	5.42
233.2017517	1.40
241.0171204	16.77
243.1243744	6.29
251.1275940	1.40
258.7806396	100.00
261.0085754	16.59
272.6418152	1.08
273.2621155	2.46
277.1831970	14.82
278.9944458	11.64
291.4219971	7.72
292.9794922	1.15
294.5816650	29.70
295.1924438	35.71
296.7934265	6.16
311.7486572	1.13
312.3942871	1.52
343.9295654	0.58
405.1091003	1.41
430.2220154	5.79
444.2547302	0.63
458.4086914	2.82
459.5379028	1.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2415
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
91.05953217	0.09
92.94795227	0.15
94.88452911	2.04
96.94663239	1.50
99.00347137	0.47
107.0860596	0.50
108.9702911	0.96
109.8740005	0.07
110.914856	0.21
112.8382111	1.23
115.0254288	0.12
117.2890244	0.19
118.7942429	0.41
121.0975342	0.18
122.9463959	1.16
124.2546921	0.21
125.0464401	0.16
129.0570831	0.12
130.8691406	0.17
132.9782104	0.25
135.0189209	0.79
136.9892883	0.49
138.9827118	8.78
140.8664856	1.06
143.0615845	1.11
146.947113	0.53
149.1142883	0.14
150.9933472	0.23
153.0089722	5.80
154.5775146	0.42
155.2012024	0.37
156.9463806	0.07
158.9922333	0.28
161.0947266	0.51
163.016098	0.13
165.0295258	0.06
166.2030792	0.15
167.2912598	0.38
169.3257446	0.14
171.0760956	0.58
172.0058594	0.38
175.4765472	0.36
176.9723969	0.23
179.2862549	1.09
180.9746704	0.77
182.9463043	1.17
183.5977936	0.09
185.1242981	0.30
189.3181152	0.38
191.8553619	0.54
192.702713	0.10
194.0895538	0.17
195.1796875	0.85
197.0039062	4.18
203.1186829	1.83
205.3809204	0.42
207.1304932	0.61
208.1541748	0.19
209.323761	0.35
211.1225891	1.46
213.2947998	0.07
219.3429565	0.41
221.0410461	2.71
223.2644348	0.77
225.1710815	0.92
226.38797	0.23
233.1671753	1.32
235.2286072	0.50
237.1636658	5.13
239.2109375	10.90
242.3326721	0.27
243.3280029	1.21
248.9202271	0.43
251.3296509	1.40
253.2203064	0.99
255.2597656	2.74
256.0584717	0.64
257.4746399	0.18
261.1949463	2.96
267.1408997	0.23
269.2582092	0.15
270.2430725	0.27
279.2369995	100.00
280.3248291	0.46
281.0852051	0.31
297.1921692	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	596.1523
Annotation	Antibiotic C 2801X 
Peak:m/z	Relative Intensity
166.7865448	0.09
178.9727173	0.13
181.1594543	0.26
202.0975037	0.18
206.9574585	0.08
208.1609802	0.38
226.0959778	1.04
229.3153534	0.17
247.0417786	0.54
253.9012146	0.30
266.0480042	0.35
269.4163513	0.39
270.8305969	0.36
271.4399109	0.47
281.1364136	0.62
282.0178223	2.93
287.2810059	0.15
290.4046021	0.55
291.1783447	0.14
299.0743408	1.35
303.1295471	2.74
306.1139221	0.12
308.2488708	0.10
311.1829529	6.44
312.1370239	2.54
317.1140137	0.42
321.1656494	0.74
329.1626587	70.86
335.8085327	0.39
346.1956787	0.62
347.1245117	0.58
353.0503540	0.08
354.3648682	0.29
361.7384644	0.10
364.1131592	0.50
365.2208862	1.44
375.0170898	0.19
383.2033691	1.20
395.1319580	0.32
398.2517090	0.12
416.0612183	0.15
422.2819824	0.30
423.0474854	0.16
425.3246460	0.19
426.4381714	0.15
427.3944092	0.36
432.1198730	1.69
433.4086304	0.19
439.0891113	0.27
440.1584473	6.11
441.1477661	0.08
443.2036133	0.28
448.1851807	0.63
449.1482544	16.08
450.0904541	0.66
451.1567993	0.14
452.4067993	0.64
458.1647949	100.00
458.7675171	0.46
467.0167847	10.69
467.6232910	0.18
470.2713013	0.15
482.4555054	0.23
485.3126831	0.61
503.2996216	2.65
515.4252930	0.26
519.1329956	0.22
519.8848267	0.12
521.3485718	13.99
524.0407104	0.18
532.8654175	0.14
560.4491577	0.58
577.2058105	2.13
578.3051147	5.01
579.6820679	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
105.9924316	0.04
107.0656433	0.03
107.9003906	0.02
111.0107422	0.22
113.0218887	0.02
116.665184	0.03
127.0316696	0.17
128.0344849	0.10
129.1307068	0.02
132.9485474	0.06
134.063446	0.28
135.0122375	8.37
136.0461121	5.76
137.0287323	0.60
137.9198608	0.02
144.7699432	0.01
146.949646	0.03
154.8977051	0.06
156.2086639	0.12
160.984436	0.71
162.124054	1.11
163.1210938	0.19
173.065094	2.35
173.9809418	1.97
175.0312805	0.50
176.1121826	0.03
178.9994812	35.67
180.0052643	41.74
180.9928741	6.04
181.6754456	0.03
191.0578461	100.00
192.0227966	76.03
193.0660095	17.23
218.1174927	0.05
219.1491089	0.07
253.2135925	0.10
263.1770935	0.03
276.3166504	0.07
290.7581787	0.08
310.42276	0.09
311.3985291	0.05
319.2332153	0.04
336.1629028	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
137.0892944	0.05
207.4193573	0.02
212.8836823	6.39
224.6940002	0.03
228.9115906	0.03
254.0998230	0.04
285.0864868	0.05
296.8055420	75.70
302.7006836	0.06
374.5696106	0.10
380.6883240	100.00
388.1281433	0.04
408.9301453	0.26
416.1566162	0.10
417.9959717	0.10
419.1878967	0.03
420.6969299	0.05
435.9078369	0.05
436.6418457	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.6329041	0.22
199.9248047	0.13
201.1704407	0.17
216.9838562	0.29
228.9396210	0.48
230.0243835	0.19
231.0568085	0.32
244.9943695	0.17
257.3653870	0.05
273.0145874	22.20
274.0179443	8.53
275.0951843	7.70
312.9499817	0.10
386.9404297	19.98
388.0378418	19.75
388.9945068	18.51
420.9875488	0.08
455.1158447	0.20
459.1738892	0.04
480.0484009	0.06
485.8049316	0.03
500.9601440	39.42
501.9347534	100.00
503.0104370	87.06
526.0273438	0.07
526.8107300	0.06
532.0461426	0.05
533.0418091	0.16
541.9850464	0.05
543.0388184	0.27
543.9769897	0.05
548.3112793	0.15
559.3957520	0.09
561.1381226	0.29
570.3314819	0.43
571.0768433	0.17
572.9763794	0.24
588.7788696	0.04
598.2744141	0.09
616.8621216	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	594.1398
Annotation	Antibiotic C 2801X 
Peak:m/z	Relative Intensity
171.1183777	0.12
177.2634583	0.05
178.9927216	2.96
180.1803284	0.12
180.9805298	0.23
183.0682220	0.41
192.2887268	0.15
197.1178436	0.25
201.0744629	0.12
210.0254822	3.24
211.2475891	0.14
217.0780029	0.73
219.1536560	0.08
225.1816406	0.60
228.1021576	0.45
228.8734741	0.07
235.0330658	0.46
236.9554291	0.37
243.1140137	1.06
245.9582367	0.04
251.1788330	0.27
254.0054474	9.81
255.2751923	0.64
269.1061401	0.62
270.5949097	0.08
272.1391296	59.78
273.1798096	6.37
275.3348999	0.04
277.1359863	2.39
278.6810913	0.89
279.3187256	0.05
280.0469055	0.08
286.8914795	0.28
288.1284485	0.34
289.9804077	0.26
303.1920166	1.97
303.8849792	0.06
306.1151123	0.60
306.9953613	0.08
321.0969238	100.00
322.1058960	13.53
353.1960449	0.23
366.2759399	0.21
380.5187378	0.09
387.2218018	0.16
395.1073608	0.07
406.1292725	0.89
407.4093628	0.54
415.0609131	0.48
424.8294067	0.40
433.1192627	0.26
439.1653442	0.27
441.0695190	0.87
442.4071655	0.44
443.2852783	0.56
445.3596802	0.29
456.1802979	10.08
457.1557617	2.06
465.2303467	3.92
466.2628174	0.68
470.3901978	0.15
495.0894775	0.68
501.3688965	0.21
509.2147827	0.13
518.9968872	0.24
531.8114624	0.35
532.4291992	0.08
542.4580078	0.20
547.4022827	0.06
548.4035034	0.14
549.2922363	0.48
558.4379272	0.09
559.5372925	0.20
576.0848389	2.46
577.2929077	0.64
595.3715820	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1619
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0123138	100.00
215.1043701	0.18
343.1797791	0.19
445.2468262	0.28
473.3065796	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.1534
Annotation	11-O-Debenzoyltashironin
Peak:m/z	Relative Intensity
81.05779266	0.48
82.90994263	3.07
84.92237091	1.21
85.69495392	0.63
88.85766602	2.61
92.82331848	0.87
94.94293213	7.80
97.0305481	1.20
106.9819565	6.65
107.9754486	0.45
108.9331589	2.79
110.7553482	1.52
115.0880432	0.74
121.0554352	1.50
122.9829865	1.32
124.6908264	1.04
126.9467087	3.57
133.0325317	2.99
134.1134644	0.50
135.0776672	5.47
136.99617	3.71
138.870697	1.04
140.8240356	2.49
143.2980042	1.27
145.0405731	1.38
147.0780792	6.33
149.1499023	7.83
151.2444153	4.55
153.2248535	2.09
155.1730804	1.36
159.0350037	0.67
161.0100403	1.56
163.0753326	5.37
164.8812256	2.36
167.1171875	5.05
169.0234375	2.49
170.9795837	2.08
177.1361084	6.83
183.1247406	0.66
184.8130493	0.41
186.8131714	0.44
189.050354	0.91
191.1395569	2.98
192.9716339	9.31
194.0135803	0.54
195.0035706	2.12
196.6851501	1.65
199.18927	1.94
201.0904846	3.75
201.946167	2.03
203.2722168	0.46
205.1391907	0.83
206.8989258	2.02
209.0570068	3.88
211.0027771	1.23
212.9258423	2.87
216.4868774	1.68
219.1665649	1.94
221.2423096	0.59
222.8530884	1.21
224.1980591	0.78
225.0079346	4.70
226.5716553	1.88
229.0224609	1.07
233.3573914	0.21
234.1765747	5.13
235.0828247	3.82
236.9636841	5.78
238.0704346	0.79
239.2769775	1.56
240.2008667	0.27
241.1798096	5.86
241.9530334	5.56
247.2751465	31.37
248.1295166	2.03
251.0523071	0.50
252.1095886	0.41
255.1731567	2.80
259.4104004	1.80
265.1478577	100.00
266.0731201	0.71
267.0654297	0.47
268.000885	1.65
271.7060242	1.82
274.1036987	2.27
282.9653625	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1764
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9681854	0.01
127.0732117	0.01
128.9190979	0.03
131.0808105	0.00
139.0710297	0.28
140.1215820	0.03
143.0285187	0.02
161.1019745	0.09
162.1656494	0.02
163.0415955	0.06
164.1168518	0.04
165.2532349	0.06
168.8656769	0.01
170.1599731	0.01
179.2161560	0.01
181.2290649	1.27
182.1569214	0.10
183.0932312	1.49
184.2390747	0.08
184.9396210	0.01
197.2108765	0.03
199.2015991	2.62
200.2024841	0.15
207.1266632	0.16
217.2769165	0.01
221.5052490	0.02
225.2453308	2.17
226.1383362	0.13
227.3779602	0.00
231.4562683	0.01
237.4498596	0.00
239.2981567	0.05
243.1030884	100.00
244.1356812	4.18
246.8372803	0.03
249.1515503	0.27
250.2705383	0.07
257.4198608	0.01
267.0267639	0.21
268.1042175	0.01
269.3930969	0.02
279.2407837	0.03
285.1520996	1.39
286.1636047	0.06
297.1054688	0.05
304.2470703	0.01
309.0946655	0.02
311.7631226	0.01
315.1273499	0.29
316.2156372	0.01
318.4265137	0.01
327.3305359	0.01
329.1423950	0.01
331.3343201	0.04
331.9723511	0.01
333.2180176	0.01
334.4220581	0.04
339.5479736	0.00
342.1935120	0.00
343.3489990	0.01
345.1526489	1.61
346.2283630	0.07
351.0133667	0.02
359.3342285	0.12
360.1557922	0.02
362.1500549	0.01
363.1354065	0.02
364.5446472	0.01
369.4589844	0.03
374.4167175	0.01
375.1160583	0.04
387.2432251	0.29
388.1840515	0.10
389.0787048	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1008.2219
Annotation	Unknow
Peak:m/z	Relative Intensity
287.5852966	0.01
315.2050476	0.01
379.2113037	0.02
405.2385559	0.03
407.5162964	0.01
409.0662231	0.02
413.4201050	0.01
417.0748596	0.01
423.0011597	0.01
425.2642517	0.01
435.4196167	0.03
448.9987793	0.01
469.2247620	0.02
525.4995117	0.03
531.1875000	0.01
574.7701416	0.02
575.4894409	0.05
577.2320557	0.05
587.1085205	0.07
614.5578613	0.01
643.3853760	0.02
659.4266968	0.02
701.6059570	0.01
710.3257446	0.11
713.6249390	0.01
719.4016724	0.03
720.5559692	0.02
724.2772217	0.08
737.2010498	0.01
739.3963623	0.01
740.3107910	0.04
749.5670166	0.02
773.1912842	0.01
778.4031982	0.11
784.2971191	0.03
800.2160645	0.02
827.7559814	0.01
839.4902344	0.04
845.3564453	0.01
847.8525391	0.03
863.4381104	0.14
865.2219238	0.06
877.1641846	0.01
905.1379395	0.01
923.2630615	0.12
933.7686768	0.02
936.5581055	0.01
945.5069580	0.05
983.2363281	0.01
987.2714844	0.07
989.1864014	0.04
1008.5891110	100.00
1010.9448240	0.15
1011.8908690	0.10
1013.0327150	0.09
1013.8023680	0.03
1014.7364500	0.04
1015.6159670	0.03
1017.2130130	0.07
1020.6237790	0.04
1025.4245610	0.04
1026.6367190	0.04
1027.6884770	0.02
1115.6638180	0.01
1143.2490230	0.01
1151.1693120	0.10
1151.8287350	0.07
1153.1956790	0.22
1251.1279300	0.02
1253.6644290	0.02
1269.7219240	0.03
1270.5058590	0.02
1271.5848390	0.02
1272.4533690	0.01
1277.4483640	0.07
1313.0430910	0.04
1315.6673580	0.02
1381.0090330	0.05
1395.3204350	0.04
1421.2370610	0.02
1439.2141110	0.10
1439.8582760	0.04
1441.3790280	0.11
1442.3922120	0.08
1443.7078860	0.03
1565.4716800	0.01
1603.5239260	0.04
1685.5809330	0.03
1709.3630370	0.05
1721.2777100	0.02
1727.6158450	0.01
1729.7391360	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0149
Annotation	Unknow
Peak:m/z	Relative Intensity
93.0520630	0.02
151.1253357	0.01
164.8885040	0.04
171.1083221	0.03
174.6815491	0.07
188.5251160	0.02
205.2665405	0.01
219.0051117	0.04
221.0102386	0.03
223.8721161	100.00
234.9971924	0.02
241.7997284	15.30
242.7583008	0.02
264.9686890	0.13
267.1223755	0.05
270.0034790	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1688
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1383057	0.04
157.0447845	0.04
161.8277283	0.08
179.1481628	0.08
186.6198120	0.13
203.0804749	0.12
209.0162811	0.16
213.9672852	0.06
233.1655884	0.21
239.8863525	0.04
250.2565308	0.03
250.9477844	0.04
259.5222473	0.08
275.8701172	0.04
277.1229553	0.09
280.2596130	0.20
283.3723450	0.39
294.2471313	0.08
296.0961304	0.97
312.9768066	0.25
313.9783325	0.59
326.1718750	0.20
330.1808472	0.07
338.1173401	0.64
342.9803162	0.03
345.4789124	0.27
350.8881531	0.13
356.1051636	17.26
357.0262146	2.66
367.3873901	0.58
368.1708374	0.30
369.2061462	0.83
370.1840210	0.15
373.4482727	0.05
374.1821594	0.39
380.3153992	0.07
385.4462891	0.37
386.1378784	0.46
391.9278259	0.08
394.0111694	0.24
396.2624817	0.09
398.1321716	0.16
399.0661926	0.03
402.7051697	0.04
407.2792358	0.19
411.4966431	0.21
416.0526428	5.78
416.7624207	0.10
422.3262329	0.15
425.4305115	0.07
429.9328308	0.26
430.8673096	0.04
439.9785156	4.07
440.5950012	0.08
441.3826904	0.18
443.0104065	0.12
445.8882141	0.12
446.8161926	0.04
447.7654114	0.27
449.3078918	0.11
458.1287537	100.00
459.1315613	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.2592
Annotation	(R)-2-Hydroxystearate
Peak:m/z	Relative Intensity
115.064743	3.95
144.8957672	1.38
155.061203	2.09
171.2147522	12.40
172.0587769	2.48
185.0557404	9.03
186.8527832	0.90
199.2593994	6.38
200.0101013	3.60
211.3164368	2.17
213.2414856	0.81
214.9573059	4.44
225.4939575	6.98
227.2219849	2.02
228.1362	7.10
230.9417419	3.44
237.2528687	11.22
239.3469543	1.33
241.0200195	1.57
252.2427368	3.51
253.2609253	100.00
254.2423096	25.12
255.3860779	28.60
257.3894043	4.69
263.3594055	21.40
265.331543	1.30
269.1766968	2.67
271.2163696	1.38
280.2656555	28.25
281.2557068	98.55
283.0800476	5.30
284.1184387	4.64
299.4052734	5.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2029
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0960541	10.18
156.0646667	1.37
160.9722900	1.25
169.1129150	0.64
170.0267944	0.11
181.0692139	0.06
182.0601196	0.20
197.2534790	0.09
199.1227722	74.12
200.0199280	11.26
206.0599976	0.17
210.2827759	0.12
211.1476135	0.05
213.0464935	0.94
225.2396240	0.81
226.2088623	0.33
241.0772552	11.72
242.2629395	3.18
243.0669556	0.25
253.1255035	1.22
254.2914124	0.17
265.4607544	0.04
270.8858032	8.39
272.1019287	1.72
295.2662354	0.10
301.0662842	32.85
302.2232666	9.69
315.1748047	0.31
324.9710693	0.28
331.2036743	0.29
343.1971436	1.29
344.3102417	0.10
361.1445312	100.00
362.2006836	23.43
402.1121216	0.15
405.2647095	1.98
406.3397217	0.21
432.4666748	0.09
478.3358765	0.48
478.9537354	0.08
488.3984985	0.12
505.1618042	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
967.4169922	100.00
969.1990356	44.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2392
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2537994	0.05
167.1358490	0.04
198.9038849	0.06
293.2449036	0.04
297.8118896	0.06
317.5485229	0.05
341.2940063	0.05
343.0722656	0.15
345.7053833	0.07
360.1069946	0.24
361.3729248	0.82
363.0294800	0.02
403.3771362	0.12
419.2624512	0.05
433.1463623	0.30
437.4749146	0.14
448.9797363	0.22
463.1824951	0.12
465.5600586	0.11
476.4022827	0.04
477.3827515	0.48
479.3800049	100.00
487.2506714	0.15
494.5622559	0.24
495.1960449	0.04
503.6608276	0.10
505.1224976	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.1237
Annotation	Villosin B
Peak:m/z	Relative Intensity
84.8750839	0.18
89.0279846	0.11
92.7868576	0.06
97.0009766	0.63
98.7274170	0.05
109.0325470	0.44
111.1139374	0.13
118.9966660	0.14
121.9791489	1.05
123.9733276	0.14
133.1121826	0.07
135.2542725	0.12
136.9343414	18.64
139.0293579	17.04
144.9430847	0.08
146.9777832	2.50
149.1890259	0.03
151.1169434	0.22
158.2436066	0.09
160.8311615	0.28
161.9417725	0.09
163.1866760	0.12
168.0510559	0.96
168.9872131	0.73
171.0998535	0.27
172.9555206	0.10
175.2096710	0.34
177.1525421	0.89
178.3051758	0.09
179.2801514	0.06
180.1612244	0.47
187.0212708	1.99
189.2350159	0.71
190.1056671	0.10
191.2600403	0.14
193.4637146	0.07
195.1819763	0.21
202.2857361	0.23
205.1399841	100.00
207.2449646	0.27
212.8579407	0.07
215.1535034	0.16
217.1275024	7.29
219.1734009	0.08
220.3222656	0.06
223.2885742	0.06
225.1487122	0.11
230.9587708	0.39
233.0190125	1.54
235.0837708	31.91
237.0976257	0.14
238.9907227	0.08
243.1805420	0.04
249.0865479	2.61
251.3250122	0.20
259.2465515	0.53
261.1871338	1.23
262.9531555	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1451
Annotation	Lamiol
Peak:m/z	Relative Intensity
110.8384933	0.25
128.8967285	1.33
137.0815735	1.28
141.0606079	1.57
142.9577332	0.53
155.1088562	42.34
156.7555237	0.17
158.9966736	1.21
169.0358582	0.19
176.9595947	10.49
179.0164337	0.17
181.3567505	0.23
190.9251862	0.07
193.3404541	0.15
195.2028503	0.58
196.2778320	0.10
197.0681152	0.08
199.0378418	100.00
203.1922455	0.42
214.1485901	0.10
216.9975586	0.47
221.1093140	0.18
226.2686157	0.10
227.3397217	0.28
228.2381287	0.06
233.0542908	0.09
241.1394958	0.78
245.7255249	0.15
247.1371765	0.21
251.1781921	0.09
253.6832581	0.10
255.3877563	0.11
257.1203613	0.34
258.1355896	0.06
259.4444885	0.19
263.3380737	0.16
270.8930054	0.15
280.3679810	0.13
281.1474915	0.09
283.5592957	0.16
286.0471191	0.08
291.0507812	0.33
293.2123718	0.37
305.4289551	0.22
309.1127014	0.22
313.3866577	0.14
315.7177734	0.15
323.1860962	0.10
329.8975220	0.08
331.1706543	0.43
333.1196899	0.31
335.4484253	0.16
339.4728088	0.04
341.0515137	1.55
343.2652283	0.06
346.9393311	0.08
349.3197632	0.61
350.3437805	0.23
357.1265564	0.28
359.1712646	28.65
361.1840515	0.11
362.4482117	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
156.8347626	0.05
158.9986572	5.26
159.9867859	1.76
160.8870850	1.12
189.2105408	0.08
198.9749908	1.20
199.9336243	0.63
201.0285950	0.48
218.2041626	0.13
218.9443512	0.45
228.9257965	1.64
230.0390320	0.25
231.1297913	0.81
259.3004761	0.04
272.9703369	69.52
274.0660706	45.73
275.0874939	38.30
276.0107727	0.08
361.3763428	0.12
372.2009888	0.03
376.1401367	0.05
386.9799500	45.91
387.9916687	72.85
388.9278870	100.00
411.8947144	0.04
419.1886902	0.06
428.2436218	0.19
456.2724915	0.59
457.1569824	0.45
459.0837097	0.19
485.0175171	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2612
Annotation	Unknow
Peak:m/z	Relative Intensity
683.4338989	0.01
847.4694824	0.03
984.5231934	0.04
1136.3504640	0.02
1137.2194820	0.00
1154.2319340	100.00
1155.2429200	1.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3383
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0393677	1.19
184.0537109	100.00
502.5385132	52.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.112
Annotation	Unknow
Peak:m/z	Relative Intensity
95.0235367	0.03
96.9123840	3.05
98.8883209	0.09
100.7890320	0.03
109.0094681	0.91
111.1522598	0.04
114.7933044	0.55
117.1520233	0.04
123.0897980	0.02
126.8810120	14.96
129.0754089	0.08
129.9230194	0.11
134.8763580	0.05
138.9264832	0.23
140.8253174	0.09
144.9273224	16.33
146.9180298	0.05
150.3417664	0.07
152.9677277	0.07
155.1816864	0.03
160.9573364	0.02
162.8156433	23.86
163.4215393	0.04
165.0108337	0.18
168.9475403	0.06
171.2787476	0.06
174.9879761	0.44
176.9821930	0.22
178.9973602	0.10
181.0142212	0.33
183.0305939	0.25
186.8484802	0.08
189.0923920	0.22
191.0307312	0.05
192.2365417	0.30
192.9016571	1.83
194.8057861	0.31
197.0213928	0.08
198.9817352	2.77
204.0275574	0.04
204.9354248	0.65
206.9663696	0.50
211.0791931	1.50
212.1878967	0.30
213.1910706	0.08
215.8171692	0.26
216.9547729	3.20
219.2304688	0.08
221.8123169	0.24
222.9588013	3.53
225.1038208	0.63
229.1462097	2.51
232.9820557	0.06
234.2340698	0.31
235.0639343	0.56
240.5597229	0.96
241.1933899	1.22
243.1114197	0.97
245.1073303	0.15
246.9744263	3.25
253.0574646	11.80
256.8585815	0.07
258.2685852	3.41
258.9624634	12.78
261.0791931	0.73
268.2096558	8.58
269.2579041	3.31
271.0846252	34.93
272.1203003	0.31
273.5636597	0.18
276.2499390	0.11
276.8805237	0.08
278.4756470	0.03
279.0995789	0.13
279.8223267	0.19
283.2823181	0.16
284.1290283	0.02
285.4347534	0.07
286.2579346	0.20
288.8237305	100.00
289.5905762	0.16
307.0514832	8.12
308.1366577	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.0667
Annotation	Unknow
Peak:m/z	Relative Intensity
116.9014053	0.03
118.9812164	1.46
126.9725800	0.03
134.9714661	2.71
137.1705627	0.06
139.0812378	0.05
162.9299469	100.00
164.1230164	0.03
170.0066223	0.02
175.2175293	0.05
183.1203613	0.03
187.2134399	0.13
194.7762451	0.09
201.1967773	0.05
206.2161255	0.03
207.2679443	0.05
209.2192078	0.02
211.1025696	0.11
220.0688171	0.05
221.1121826	0.08
222.3871765	0.04
233.3145142	0.02
235.0743713	1.51
235.9046021	0.03
237.0872803	0.57
252.5356445	0.08
260.8883667	0.10
263.0372620	0.33
265.0202637	0.05
281.0476074	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.13
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0271301	0.63
162.5176239	0.11
173.0554199	0.07
174.9881744	0.17
175.7158813	0.11
176.8127594	0.18
178.7545166	0.14
185.1180878	0.33
186.8831024	0.21
188.9819183	0.08
190.0980835	0.11
193.2880249	0.16
199.1313171	0.25
203.1273804	0.96
205.1233368	0.70
211.1757812	0.30
215.2065125	0.44
227.2075195	0.38
227.9824219	0.11
229.1999512	1.00
231.3038940	0.08
232.0845184	0.13
241.9544067	0.38
243.1853943	1.41
245.1436157	5.45
246.1345825	0.60
257.2263184	0.37
258.9141235	0.09
261.0026245	1.13
263.2173767	0.39
269.1798096	0.29
270.1751099	0.10
272.2206726	0.11
273.1430664	4.09
275.1553650	0.04
279.3682251	0.13
281.1359863	0.19
282.1363525	0.34
283.2182007	0.12
285.2809448	0.56
287.0592651	7.25
288.5185852	2.31
289.1339722	37.44
290.1542358	2.32
291.0904541	0.19
297.1470947	0.07
299.1434937	6.75
300.0715637	0.10
305.2446899	0.09
307.2728271	0.06
308.1212158	0.14
310.1973877	0.10
313.1422729	0.19
326.4196777	0.16
327.1212158	0.06
328.4670410	0.43
329.2346802	1.40
329.9164429	0.08
331.0483398	1.61
331.9345703	0.31
337.2327271	0.17
339.2412109	0.78
340.9425049	0.31
348.6461792	0.12
350.2781982	0.14
355.2196655	0.35
357.2175293	0.19
363.1886597	0.20
365.2193604	0.21
369.3449707	0.23
373.2297363	0.05
379.2988892	0.30
381.1398315	1.99
382.3961792	0.33
383.3964233	0.33
389.3036499	0.39
391.3156128	0.08
395.2234497	0.80
397.3770142	0.17
405.2418823	1.11
406.6156006	7.20
407.2244263	99.94
408.1657104	1.17
409.3479614	1.60
410.1115112	0.35
411.2936401	0.58
412.7470703	1.14
413.3698120	1.17
414.3067627	0.11
415.3952637	4.83
423.1409912	0.67
425.1558838	100.00
426.4441528	0.40
431.1707764	0.51
432.2295532	0.16
433.1754761	0.63
435.3165894	0.28
436.3773193	0.38
437.3478394	0.23
439.2782593	0.05
445.3158569	0.07
449.2666016	3.33
450.2532959	1.31
451.2404175	26.46
452.2296753	0.62
453.0465088	0.19
465.2522583	0.84
467.2645264	0.53
469.2519531	0.57
469.8773804	0.28
475.6004639	0.44
478.5711670	0.76
482.4773560	2.28
483.1072388	0.09
491.3362427	9.71
492.2455444	1.61
500.1493530	10.87
500.9262695	5.34
506.0087280	0.05
513.2149658	0.08
515.2201538	0.44
521.1293335	0.07
521.9479370	0.19
522.9064331	0.05
525.4177856	0.14
526.2025146	0.46
527.4651489	0.08
531.3134155	0.85
532.2711792	0.36
533.2710571	0.85
540.7807007	0.19
543.2343750	0.33
545.1087646	0.17
546.2945557	0.42
548.2460327	0.09
551.2074585	0.04
554.2713013	0.22
555.2258911	0.05
557.2352905	0.14
559.2865601	6.58
560.4942017	0.11
564.3176880	0.06
567.0046997	0.06
577.1846924	0.11
583.3543091	0.11
585.3043823	0.27
589.3369751	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1012
Annotation	Scopolin
Peak:m/z	Relative Intensity
102.9467773	0.01
107.0829468	0.04
116.9976501	0.77
118.8775177	0.02
135.0612335	0.93
138.2355499	0.02
144.9263916	4.14
146.8105164	0.03
156.5243073	0.03
162.9123383	100.00
169.9718933	0.02
180.9652710	0.15
235.0647278	0.03
267.1542053	0.02
289.9832153	0.01
326.5456543	0.05
327.5216980	0.03
336.3511353	0.01
337.1040344	0.36
338.1354065	0.05
359.3888855	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.2367
Annotation	Tsangane L 3-glucoside
Peak:m/z	Relative Intensity
106.9945755	1.38
109.1148834	0.24
110.7914352	0.41
118.8340073	0.14
120.9409561	8.17
122.6392517	0.12
125.0834045	0.68
135.1102753	2.75
137.0143890	0.08
138.9190369	0.06
149.0445862	1.02
152.5453491	0.05
159.0400543	0.14
163.1549072	0.52
173.3734131	0.09
175.2638245	0.25
177.0962982	80.22
178.9911194	0.33
180.8309021	0.38
187.0123596	0.30
193.0400543	0.40
195.0249329	21.44
201.3283997	0.21
203.0581665	0.51
204.9944458	0.38
207.2469482	0.52
213.0025482	100.00
213.6128540	0.61
217.1670227	0.09
223.3577576	0.23
227.3058472	0.07
233.2940979	0.70
241.4177856	0.18
249.0944519	0.25
254.8390198	0.17
261.0563354	0.04
267.4671631	0.17
270.0256958	0.17
277.2958984	0.06
282.9234619	0.05
285.2094116	0.93
291.2391357	0.49
297.2288208	0.17
300.2968140	0.21
303.0437317	0.38
308.1296997	0.26
313.2731018	0.10
315.0947266	0.26
316.0415649	0.18
318.9375305	0.12
321.2290039	0.85
326.1528931	0.11
327.2752991	0.15
329.2491455	0.54
330.3581238	0.20
339.0875549	1.09
339.8654175	0.32
352.7769470	0.16
355.2895508	0.03
356.5977783	3.37
357.2416382	7.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8184967	1.99
295.9430542	1.83
296.7806091	38.41
380.6055908	100.00
381.4332886	0.17
412.0514526	0.23
428.6276245	0.21
462.9243774	0.16
463.9360352	2.61
464.6322632	50.76
505.5192261	0.25
530.0723877	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	363.16
Annotation	Trimethaphan
Peak:m/z	Relative Intensity
112.9494019	0.45
113.9326172	0.14
115.0338593	0.04
131.0482483	0.07
137.2277374	0.22
138.1820831	0.13
139.2196960	0.09
142.7261963	0.20
153.1405182	0.21
155.0697632	23.72
156.0394592	12.13
157.1035156	2.99
160.8575439	0.41
161.9845734	0.17
163.0729065	0.05
170.0291595	0.06
171.1814423	0.17
178.0680542	0.04
181.0706482	0.57
181.8504333	0.11
183.0874634	0.04
184.8778381	0.04
199.0455170	96.53
200.0677643	100.00
201.1215973	21.34
213.1661682	0.02
214.0857239	0.12
215.4230652	0.05
238.9429016	0.15
240.4230957	0.04
241.1326904	1.99
242.0825806	2.49
243.2233887	0.35
244.0470581	0.03
252.8537292	0.06
254.2024231	0.36
265.2036133	0.19
271.0009766	0.13
272.0711060	0.32
272.9247742	0.09
274.2505493	0.07
275.2898865	0.04
289.4262390	0.04
290.2270508	0.07
295.0719910	0.24
301.8629761	0.56
303.1873779	0.12
315.1852417	0.06
316.0172119	0.05
317.1150513	0.39
318.2149658	0.33
319.3032227	0.10
320.3175049	0.03
326.3263550	0.12
335.3350830	0.11
343.2080688	0.47
344.3432617	1.77
345.3154297	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Chrysanthemin
Peak:m/z	Relative Intensity
125.0010071	0.17
145.1778107	0.05
147.012146	0.29
148.1672974	0.02
149.0003052	0.01
151.2450256	0.04
152.0215454	0.04
161.177124	0.14
163.0688782	0.22
165.0242767	0.07
168.9404907	0.03
171.048233	0.05
173.0038757	0.21
175.0934906	0.20
175.9358673	0.07
177.0091248	0.16
185.1152344	0.04
188.9848785	0.06
189.9378967	0.07
191.0590515	0.11
193.1470947	0.02
197.2090302	0.13
199.0986938	0.08
201.1202698	0.97
203.1583099	0.20
205.0764465	0.05
206.0609131	0.15
209.1649475	0.03
210.9204407	0.11
213.1090698	0.45
215.4600983	0.07
217.0296021	0.39
219.1105042	0.08
221.1370697	0.15
225.2528839	0.05
227.1134491	0.11
228.1123962	0.01
229.2060547	0.05
229.872345	0.03
230.973877	0.15
233.1173096	0.03
235.3453522	0.01
236.15979	0.02
238.9737854	0.13
240.4872742	0.08
241.1679382	1.31
242.9990234	1.35
245.1211243	0.03
255.0896301	0.28
255.9249878	0.05
257.1846924	0.44
259.0296021	0.03
261.3418884	0.02
263.0050964	0.02
265.3338318	0.03
267.1515503	0.36
269.0882263	0.72
271.2883301	0.24
273.3513489	0.10
275.2424316	0.02
277.3348389	0.02
278.3575745	0.02
279.1619568	0.02
279.9244995	0.08
281.2386169	0.66
284.0219727	22.66
285.0505676	100.00
287.1250916	0.26
291.499939	0.01
292.2243652	0.03
293.3630981	0.03
295.1384888	0.74
295.9401245	0.04
297.1524048	1.65
298.6182861	0.19
299.2269287	4.54
301.1430054	0.10
303.1390076	0.22
305.3234253	0.03
307.0276489	0.10
309.2095337	1.48
311.1556396	0.13
312.5569763	0.02
313.3209839	0.06
314.0857544	0.05
315.0805664	0.02
319.1410217	0.15
321.1967163	3.18
323.1485596	0.17
325.0566406	0.27
326.4500732	0.21
327.115509	3.63
332.9598389	0.04
337.2460632	0.03
339.1080322	1.11
341.2487488	0.07
342.3577881	0.02
343.1014404	0.04
345.1536865	0.04
347.2796021	0.07
349.1618652	0.01
351.1558228	0.42
357.1698608	0.99
359.2380981	0.05
360.8394775	0.03
361.4620361	0.02
363.1303711	0.07
365.3359375	0.07
367.5106201	0.04
369.0284729	0.31
372.4811096	0.02
375.1749573	0.07
377.3508301	0.03
383.1734619	0.08
385.2653809	0.15
387.1573181	0.32
389.1980591	0.05
393.4762878	0.19
399.117218	0.01
401.0513	0.33
403.3312988	0.07
405.0343323	0.03
410.0188599	0.07
410.7149353	0.02
411.3173828	0.15
419.2076721	0.01
429.1332397	1.67
430.3016663	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	516.19
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
173.9943085	100.00
184.1493835	0.75
395.0733032	0.21
472.3468018	1.26
486.1051025	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1304
Annotation	Galactotriose
Peak:m/z	Relative Intensity
181.3864594	0.25
195.0834808	0.16
200.9040985	0.50
219.0292969	0.21
273.0035400	0.07
290.3640747	0.09
291.8818970	0.20
295.5289917	0.08
321.2636719	0.15
331.7440186	0.13
363.0589600	21.11
370.5446167	0.07
381.1464844	100.00
398.3651123	0.09
399.1412964	0.17
453.2517090	0.20
460.8791504	0.21
483.0067749	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
497.2796021	0.67
551.3757935	1.77
755.8627319	4.31
967.4209595	100.00
968.1871948	60.49
969.1959839	9.61
970.3608398	5.23
972.5285645	9.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.12
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
142.9217529	0.11
160.9725647	0.60
178.9324951	1.79
202.8769531	0.06
235.1634521	0.32
274.9857788	0.23
280.9634094	0.28
295.0305786	0.65
305.3948059	0.17
341.1357727	100.00
385.3821716	0.46
411.1272888	0.16
439.2088318	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8541718	1.63
207.7660675	0.27
208.8906250	1.54
290.8060608	9.84
292.8049316	14.52
316.9006958	0.22
321.7114258	0.34
337.0062256	0.31
374.5360107	2.59
375.5374756	0.37
376.4602051	6.58
377.1365356	0.81
419.8650513	0.11
421.1231079	0.09
458.5473633	27.56
459.9923706	16.06
460.6828613	57.68
461.4234619	0.08
462.9794312	0.34
464.7376709	0.43
492.8751831	0.29
497.0691528	0.33
499.0025024	0.04
521.0385742	0.39
522.0905151	0.14
522.8268433	1.05
536.7863770	0.16
540.9580688	0.13
541.9837646	0.27
542.5851440	18.44
543.7809448	27.56
544.6138916	100.00
545.3388062	0.08
567.9394531	0.20
582.8137207	0.21
610.8822632	0.48
629.5139771	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.01828003	0.56
94.75033569	0.70
96.79962158	0.88
98.92274475	1.62
100.5253067	1.28
107.0578308	0.94
108.9693527	1.15
111.0416946	0.98
115.5844421	0.32
118.9260559	0.34
120.933754	1.94
123.0458069	0.74
124.9540405	0.82
126.983429	1.31
128.9600067	1.31
132.881134	0.80
135.1096497	0.80
137.0110168	0.56
138.8418121	2.85
141.0066833	0.43
142.9222717	0.32
146.8460693	1.47
148.8540649	1.90
151.1134033	0.20
152.8751526	0.94
154.9110718	3.12
156.2078094	0.50
158.9034424	1.29
161.4685211	0.31
163.1871948	1.94
164.9921265	0.48
166.8475037	0.60
168.9090271	6.21
173.2163696	1.75
177.2896423	0.82
179.1022644	1.44
181.2552185	1.29
185.1534882	0.66
187.1381836	0.51
188.4924316	0.69
190.0188599	0.42
191.2588654	0.80
193.0178833	1.28
194.8057709	0.46
197.0196228	3.62
199.0068665	0.24
201.2245483	0.78
206.9472351	0.18
209.315094	0.92
211.1730652	1.57
213.0324707	1.74
219.037384	0.16
221.1766663	2.70
222.1483765	0.70
223.1491699	3.02
227.1469727	0.34
228.6056213	0.46
230.1167297	1.53
233.0692139	1.59
235.0547791	1.03
239.1569214	1.02
240.9366455	0.38
241.5536194	1.16
247.2977905	0.42
251.2207031	4.28
253.2693481	11.84
254.8343201	1.04
257.1068115	0.38
257.9303589	0.20
263.0925903	0.57
265.1714478	2.72
267.3358154	3.36
268.1948242	0.30
269.1551208	3.38
271.3529358	0.75
275.3689575	18.23
283.2341309	2.98
287.305542	0.89
288.4200745	1.07
293.2036743	100.00
294.1329956	0.19
295.888916	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
116.8491821	0.03
126.9667969	0.20
128.6616669	0.03
135.0305176	0.30
143.0957336	0.01
161.1223450	0.47
170.9641724	0.08
173.1105042	0.51
179.0081177	3.36
191.0075531	100.00
317.1927795	0.05
333.0024414	0.05
335.0825195	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.2
Annotation	LMPK12030015
Peak:m/z	Relative Intensity
243.1758881	0.32
244.0055847	0.17
245.1636353	0.42
255.0973816	0.03
256.0292969	0.08
261.0604248	0.25
261.8149414	0.03
269.1008606	0.19
276.0073547	0.07
281.2550964	0.01
283.4832764	0.03
284.2999573	0.06
285.2570801	0.03
287.0769653	2.14
288.2885742	0.55
289.1908264	0.55
290.2922058	0.14
291.3306274	0.04
299.0732727	0.09
301.3942871	0.02
303.0695496	0.07
313.106842	0.05
325.211853	0.04
328.8789673	0.10
331.3674927	0.07
332.3546448	0.03
338.2165527	0.05
339.0084534	0.04
361.2260132	0.03
363.2091675	0.16
364.3952637	0.03
366.407959	0.08
370.5587158	0.06
380.1123047	0.04
381.3284607	0.30
387.3355103	0.03
388.4519653	0.11
389.1707764	0.12
391.2040405	0.14
393.3974609	0.05
395.2237244	0.47
396.1969604	0.07
405.1970825	1.20
406.1394043	0.09
407.2808228	1.59
408.2662354	0.39
409.3929443	0.09
411.2969971	0.43
412.5979614	0.17
413.246521	0.78
414.2050781	0.18
417.272644	0.02
419.3538818	0.02
420.2421875	0.10
421.2523193	0.03
423.1799927	0.59
425.0101318	0.71
428.3874512	0.07
429.567688	0.03
431.1768799	0.10
432.1125488	0.05
435.1311646	0.11
439.250061	0.08
444.9935913	0.08
447.1377563	0.08
449.2210693	1.53
450.119751	0.21
451.1309204	0.85
452.3538208	0.04
455.1008911	0.12
456.324707	0.05
459.3718872	0.02
462.8419189	0.25
464.9820557	0.15
467.1762695	0.06
468.2446289	0.07
469.5050659	0.04
474.5065918	0.04
478.0545654	0.05
490.3197021	0.06
491.4439697	0.23
493.2213745	0.04
494.3045044	0.20
495.3237915	0.06
499.229248	0.04
499.982666	0.04
507.5926514	0.08
515.0018921	0.04
517.5392456	0.11
522.8241577	0.05
525.3231201	0.17
526.22229	0.05
527.2695923	0.08
531.2513428	0.35
532.2271118	0.30
533.043457	0.28
534.3240967	0.15
541.6986694	0.13
543.0540771	0.77
544.2932739	0.07
545.4484863	0.13
546.1192627	0.08
548.0457764	0.08
549.2240601	0.14
550.4204712	0.12
553.3896484	0.17
555.3278809	0.01
557.2341309	0.45
558.272583	0.25
559.1394043	0.57
560.2024536	0.29
561.0955811	0.24
562.1077271	0.13
564.3766479	0.12
567.3389893	0.25
568.4238281	0.15
569.2316895	0.59
570.3705444	0.06
571.3806152	0.03
573.7727051	0.19
575.12323	2.72
576.3234253	0.78
577.2727051	1.72
578.2821655	0.42
580.2851562	0.03
581.3678589	0.13
583.2052002	0.03
586.5567627	0.02
587.2313232	0.60
588.178772	0.36
605.4200439	0.05
609.0864868	0.03
611.1655273	0.09
612.4918823	0.01
613.3354492	0.16
615.2640991	0.09
616.7744751	0.15
617.4472046	0.02
618.6646729	0.11
619.5391235	0.06
627.1907349	0.08
628.1732788	0.03
631.4658813	0.07
634.2295532	0.06
635.373291	0.85
637.5098267	0.10
638.333313	0.35
639.3927002	0.06
640.4802856	0.23
643.2565918	0.19
644.1605225	0.85
645.1866455	0.07
648.4055786	0.07
649.916687	0.45
653.4260864	0.09
656.3326416	0.17
657.3529053	0.22
662.0661011	0.02
663.0504761	0.04
665.7074585	0.05
667.3314819	0.10
670.2853394	0.10
675.3482056	0.04
677.3120117	0.20
678.1795044	0.11
681.6950073	0.08
682.6392212	0.08
683.242981	0.06
685.286499	0.20
685.946228	0.05
687.4482422	0.12
689.4815063	0.05
690.2265015	0.11
693.1459351	0.47
694.3130493	1.58
695.1519775	2.49
696.1322632	0.25
696.7352295	0.08
697.3606567	0.05
698.4788208	0.06
700.336853	0.12
701.3710938	0.71
702.3460693	0.19
703.6074219	1.44
704.9381714	0.08
706.2501221	0.09
707.3775024	0.21
708.177063	0.08
710.1893921	0.23
711.4568481	0.99
712.3634033	0.86
713.3289185	0.19
716.5096436	1.24
717.5079956	0.10
719.8959351	2.87
720.9254761	1.56
722.2660522	0.08
722.8877563	0.03
725.2508545	0.61
725.8833008	0.03
731.4267578	0.07
732.2022095	0.02
736.2332153	0.11
737.3604736	0.57
738.3625488	0.43
739.2637329	1.13
740.515564	0.27
741.2940063	0.18
743.2822876	0.04
748.8320312	0.17
751.757019	0.16
753.3527222	0.07
754.5509033	0.05
757.0440674	0.02
761.8406372	0.23
766.1985474	0.25
766.90271	0.11
770.5896606	1.68
778.1262207	0.05
779.4529419	7.89
780.3109741	0.29
781.3121338	0.13
782.3999634	0.23
788.3640747	2.40
789.203186	0.03
791.3694458	0.14
792.7310181	0.29
796.1091919	0.10
796.9237671	0.08
801.4153442	1.13
802.0799561	0.62
807.9083862	0.54
809.3207397	0.21
811.1972046	0.04
813.1021118	0.05
813.9098511	0.44
819.1101685	0.07
820.2145386	0.13
821.0540161	0.30
831.3040161	0.16
833.5679932	0.05
837.197876	0.15
838.5383911	0.11
839.4082642	0.12
840.4258423	0.02
842.7520142	0.21
845.3408813	0.06
846.468811	0.62
847.3515015	0.42
848.2556763	0.15
863.340271	0.09
865.201355	100.00
866.1101685	0.93
866.7474976	0.19
867.543335	0.02
869.4725952	0.02
873.2301025	0.02
875.1182861	0.07
880.5787964	0.05
895.223938	0.03
901.5354004	0.07
902.8617554	0.04
905.4163818	0.15
906.0795898	0.02
907.2009277	0.20
917.3600464	0.09
937.5415649	0.03
939.2375488	0.15
945.4432983	0.23
949.1321411	0.03
957.4301758	0.04
965.9281616	0.14
966.9228516	0.04
971.4359741	0.12
973.4116211	0.13
975.609436	0.12
981.2493286	0.43
982.0839844	0.17
983.3484497	1.30
984.3754272	0.24
987.0946655	0.15
989.1018066	0.45
990.2497559	0.56
991.1200562	0.10
992.9511108	0.04
999.336731	0.12
1001.021057	0.37
1002.156189	0.13
1008.23407	0.05
1009.188416	0.03
1010.013611	0.13
1010.68634	0.03
1024.319946	0.04
1025.244141	0.52
1026.353394	0.27
1027.231812	1.35
1028.29248	0.67
1029.657471	0.16
1032.555176	0.05
1038.984985	0.08
1041.915649	0.21
1066.789307	0.33
1069.366577	0.19
1073.491943	0.12
1081.393188	0.16
1102.252686	0.04
1107.064697	0.06
1108.158325	0.10
1110.33374	0.14
1111.824951	0.11
1120.193604	0.03
1127.434204	0.07
1132.859863	0.05
1133.853516	0.14
1135.400635	0.11
1136.185059	0.30
1138.385864	0.08
1145.219727	0.21
1146.481934	0.09
1148.795654	0.16
1151.172607	2.65
1152.325562	0.86
1153.321289	3.61
1154.276611	2.09
1155.289795	0.05
1161.379883	0.13
1162.392578	0.12
1163.310669	0.23
1164.297119	0.03
1165.077637	0.02
1166.406738	0.10
1187.198242	0.09
1189.259644	0.17
1193.078491	0.10
1195.314941	0.44
1196.437012	0.01
1200.284302	0.05
1202.964722	0.09
1211.665771	0.03
1212.560791	0.23
1228.438599	0.01
1233.821411	0.03
1235.036377	0.01
1252.546753	0.04
1253.412231	0.12
1269.21106	0.12
1270.828247	0.14
1271.536499	0.10
1272.618286	0.03
1273.610229	0.01
1274.55481	0.13
1277.48584	0.55
1278.555786	0.22
1279.341553	0.03
1287.538818	0.06
1289.421021	0.04
1295.457886	0.02
1296.796753	0.16
1297.976685	0.18
1308.51709	0.10
1311.390991	0.12
1313.398926	0.41
1315.221313	1.84
1316.369995	0.99
1317.361572	0.03
1332.52063	0.12
1358.157837	0.09
1416.312988	0.04
1421.434937	0.03
1422.390381	0.21
1423.189697	0.20
1433.456421	0.04
1434.645508	0.08
1439.114502	1.33
1440.476196	0.71
1441.55603	1.56
1442.464355	0.67
1451.428345	0.03
1452.570801	0.09
1466.364624	0.04
1477.249146	0.17
1478.445557	0.18
1483.428223	0.26
1484.368286	0.51
1557.445435	0.02
1558.570068	0.13
1566.071411	0.10
1567.764404	0.02
1586.714478	0.09
1603.23938	0.99
1604.201904	1.04
1604.921631	0.18
1727.603149	0.10
1729.096558	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
121.0043259	4.77
123.4817963	4.17
124.9119873	3.98
130.8735962	3.69
134.8826141	6.19
136.813858	8.78
150.9902344	7.30
156.83815	14.82
165.2274475	10.52
171.8092957	7.94
178.9967499	8.81
180.9586792	21.57
183.3009949	5.97
185.0776215	2.90
188.8842163	4.30
202.9750824	3.96
209.243042	6.88
228.1863251	6.06
232.9597168	6.61
237.0228577	18.18
239.0262451	1.87
245.1620483	8.72
263.2203369	11.64
264.0648193	6.90
265.2528992	2.52
270.4300842	22.94
271.1037598	4.18
281.1221924	17.11
287.1679993	17.18
296.3198242	6.48
297.135498	10.01
304.229126	18.35
305.4143066	3.34
322.3998718	5.43
328.2727966	13.62
337.0054321	6.03
339.350769	11.06
341.3597717	11.52
342.3070068	16.37
354.0531616	4.54
355.8565979	12.17
357.1176147	6.90
359.3995361	7.73
364.4053345	4.38
365.3678589	4.14
366.4956055	10.12
372.9730225	3.26
380.34552	14.25
382.1235657	3.12
389.4460754	3.50
391.0436401	10.17
397.3982849	4.05
398.8547668	15.29
406.2208557	5.42
408.2720947	100.00
409.0913391	27.62
410.4958191	2.91
417.6619873	7.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1712
Annotation	Folinic acid
Peak:m/z	Relative Intensity
138.9147186	0.04
148.5915680	0.03
176.7861633	0.12
193.8760376	0.03
194.9491882	4.14
204.9110718	0.02
210.8408203	0.05
228.8156586	0.11
240.1758575	0.32
246.8453827	0.08
255.7819519	0.04
273.1824646	0.02
280.2016907	0.07
282.0303040	1.13
293.9698792	0.08
298.1879883	0.08
300.0777588	0.09
301.2886353	0.26
308.3893433	0.03
322.9429321	0.05
327.1456604	100.00
327.9175415	0.19
333.2954712	0.27
335.9224243	0.06
342.0536804	0.14
345.1820679	18.02
347.2374878	0.06
359.5864868	0.11
368.5776062	0.14
377.3489380	0.07
383.7080383	0.10
385.3237305	0.06
396.1905212	0.13
401.0347900	0.04
405.1869812	0.03
412.3843384	0.13
428.2021790	1.38
429.7142029	0.09
430.3350830	0.98
438.0032959	0.03
439.2273865	0.04
442.9053955	0.03
456.2562866	10.92
457.1346741	0.27
474.1349182	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.261
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
407.4540405	0.07
846.2629395	0.05
1027.230957	0.02
1136.439453	0.08
1153.267212	100.00
1154.251587	28.15
1154.996338	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	Dehydroeffusal
Peak:m/z	Relative Intensity
76.72264862	0.62
77.93872833	0.14
78.82855988	0.37
80.88356781	0.09
82.94169617	0.57
91.03262329	0.17
94.87017822	0.42
96.10679626	0.07
97.04447937	0.22
102.9172363	3.70
104.9915314	1.73
107.0067139	0.88
109.0242615	0.84
110.1403656	0.07
114.8199158	0.52
118.9376678	0.25
119.8601685	0.12
120.9698944	0.22
122.0251923	0.31
122.9649048	0.72
125.0927124	0.18
127.0771027	0.22
127.9067535	0.44
128.8672485	14.63
130.0381622	1.97
130.8561859	0.62
133.0797882	0.57
134.0230713	0.11
135.0894165	0.18
137.2352142	0.69
138.6434631	0.64
140.0553741	0.33
141.0518646	1.08
141.9430389	0.30
142.6357574	0.23
144.122345	0.17
145.9550629	0.64
147.0981445	0.19
149.1363678	0.26
150.963028	100.00
151.9798431	11.43
153.1485596	1.47
154.1403351	0.23
154.9422607	2.00
157.0565948	0.20
158.0410614	0.13
159.276474	0.59
161.1212921	0.45
161.967804	0.20
162.964035	0.11
164.0228119	0.41
165.0698242	2.00
166.0080872	1.63
166.9796448	5.06
167.9431	0.54
169.1205902	2.35
170.1190491	0.74
171.1379242	0.24
172.1136627	1.11
173.9868622	0.14
176.153717	1.71
177.1398315	0.80
178.0684357	0.47
179.0762329	4.65
180.1312408	1.04
181.1383209	0.91
182.04776	2.14
183.0573273	1.89
185.1118927	4.62
186.2194366	0.31
188.1721649	1.29
190.0234985	0.58
193.0804596	0.95
193.9664459	1.51
195.289978	0.37
197.0388336	4.40
198.0234833	0.78
200.069397	0.23
205.095993	1.17
206.0662384	14.84
207.5310364	1.23
208.1630402	1.22
209.1280365	0.08
210.0817566	1.68
211.0513763	1.90
212.3310089	0.84
213.036499	0.15
217.3850403	1.36
218.0678864	5.54
223.2841949	0.16
225.0919647	9.23
226.1615448	5.50
227.4221649	0.24
233.0816498	0.34
235.0830536	5.16
236.0803375	27.78
237.179184	3.01
238.1008301	21.64
239.0821533	4.78
240.1858368	1.03
244.5789642	0.88
245.3541412	0.18
251.157608	3.53
253.0844727	51.70
254.1369629	9.54
255.2223663	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9452057	0.09
212.8682251	1.60
215.0226135	0.22
216.0044250	0.04
290.7168579	0.83
292.5993958	0.15
296.8197632	4.56
297.8560181	0.02
332.7988892	0.04
352.8079834	0.03
378.3392944	0.09
380.7955933	27.22
386.7178955	0.02
417.0415039	0.02
454.2740479	0.02
458.1879883	0.12
459.8417358	0.03
460.8560181	0.10
462.6663818	0.18
464.7352905	75.38
468.6400757	0.05
469.7346802	0.12
489.1240234	0.10
494.9248657	0.09
496.1735840	0.07
522.8071289	0.04
544.7953491	0.08
545.5607910	0.10
546.7229614	0.08
548.5399780	100.00
549.3423462	0.08
561.0498047	0.08
568.9573364	0.10
585.7764282	0.07
614.9404297	0.12
634.5606079	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.1688
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9956207	1.14
115.2215347	0.08
121.0086823	0.07
121.8950653	0.30
126.9718933	0.09
128.8144226	1.02
132.9023743	0.40
135.0499573	0.17
137.0300751	1.46
144.7522736	0.08
146.9859161	0.83
153.2236633	0.21
155.0899048	0.81
157.2116089	0.14
162.8274841	0.15
165.0902405	3.15
167.1469727	0.10
175.9002075	0.11
182.9278107	10.07
185.2409973	0.26
189.1055908	0.29
193.0282898	0.23
200.8710938	3.85
203.0602722	0.17
213.1364136	0.21
215.1873474	0.12
220.3338623	0.18
226.8707581	0.19
228.8559570	0.10
230.2243652	0.15
231.9936523	0.22
235.2266235	0.09
254.9695740	0.26
256.2993774	1.04
258.9504089	0.07
263.3659363	0.23
264.9955444	0.57
266.2324219	0.92
267.0676575	0.39
270.0129395	0.18
271.3969727	0.48
273.1941833	0.07
280.2471008	0.16
281.7002258	0.22
283.0984497	0.56
284.3382874	0.25
286.3652649	0.45
289.2645874	0.13
299.0994263	0.45
301.1351929	0.36
302.4885254	0.07
303.3388062	0.29
305.2433167	0.27
311.2106323	24.17
313.4273682	0.44
317.1744995	1.31
319.3111267	0.20
329.1762085	100.00
330.2841187	0.49
337.1107483	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	720.1588
Annotation	Unknow
Peak:m/z	Relative Intensity
203.1224823	0.31
207.1216278	0.48
217.1854706	1.52
227.0696411	0.74
228.9141846	0.38
243.2322235	3.01
245.0889587	11.11
246.0567627	3.49
255.1787415	0.83
257.2425537	0.41
261.0776978	0.41
269.0063477	2.30
270.9964905	1.30
273.1771851	0.69
283.2465515	2.80
285.0695801	1.92
287.0331116	19.50
287.8323975	1.19
289.2430725	49.20
291.4982910	0.57
297.2180481	2.12
299.2345581	2.35
301.1917419	0.47
304.3209534	1.62
313.1145020	0.67
325.6639404	2.26
327.2113647	0.48
329.3013000	0.81
331.0685120	3.32
332.2678833	0.94
333.2884521	1.26
337.1676025	0.43
338.0629883	0.64
339.1453247	0.80
355.2511597	0.46
363.0795288	0.23
377.2939453	0.44
379.1250610	2.46
381.2255859	2.33
387.1051025	0.71
389.2250366	0.53
394.9235229	5.11
400.2817993	2.85
402.3911133	2.88
405.1752930	3.66
406.2232056	1.87
407.2269897	33.06
408.3490601	2.15
409.0285645	2.22
413.2144775	5.57
414.3386841	3.30
416.9526978	2.67
419.1345215	0.54
420.3770752	0.40
421.4931641	0.69
423.2785645	4.73
425.2140503	5.45
431.3190308	0.93
434.2716064	0.82
435.2280884	0.60
437.3144531	1.41
439.3449097	2.26
449.2933350	14.97
450.2723999	4.00
451.2795410	20.29
452.4141846	2.76
453.4862061	0.50
455.1638794	0.53
456.8176880	2.71
465.1166992	0.45
469.1596680	1.15
470.9467163	0.88
474.4407349	4.93
477.9656982	0.22
483.3189697	0.78
490.8066406	2.75
494.3167114	4.25
496.2260132	2.03
500.1450195	0.61
508.3253174	2.49
511.4002686	0.39
513.1282349	0.55
525.3106689	3.76
528.4207764	1.09
531.4580078	6.25
533.4123535	4.93
536.2329712	0.36
537.5120239	2.12
541.3046265	2.57
549.0814819	1.83
550.1932373	27.00
550.8503418	3.50
552.2207642	1.27
555.3668213	2.38
557.2288208	2.20
559.3225098	31.51
560.4562378	8.06
561.4857178	1.77
562.1964111	1.48
566.1820679	0.45
567.4852905	12.06
568.2592163	7.12
569.3414917	1.53
572.1301270	2.92
575.2758179	45.26
576.1406860	3.39
577.3112183	56.69
578.2432251	5.27
579.5162964	1.37
581.2648315	7.19
584.2151489	0.39
585.3358765	1.79
587.1527100	0.60
588.2000122	0.34
595.4695435	1.76
596.9318237	1.66
601.5310669	0.90
608.2717285	1.73
614.7790527	2.51
619.1579590	3.08
620.2639771	1.31
625.3209839	0.44
626.2832642	7.38
635.4568481	100.00
637.4099731	2.42
644.2405396	39.73
644.8864136	30.69
648.3916626	1.02
649.3886719	1.73
651.3939209	0.45
657.2374878	15.11
665.3930054	2.38
676.4524536	2.40
677.3761597	1.66
678.8345947	1.92
683.0894775	1.80
684.3884277	1.45
688.5247192	0.47
693.3748169	8.23
694.7805786	2.55
695.5228882	7.24
696.3432007	2.69
697.1500244	1.47
698.7076416	0.95
701.2217407	20.56
702.5055542	8.21
720.9624023	6.76
723.0487671	0.44
735.5748291	0.54
737.3892212	2.64
739.3721313	15.11
740.2376709	2.02
741.1179810	0.51
755.6409302	0.93
781.1934204	1.78
796.6661987	0.38
803.8211670	0.43
804.4998169	0.54
812.4874268	1.78
815.3500366	1.51
819.2704468	4.30
821.2882080	2.96
822.2234497	3.09
823.2069092	0.79
824.3777466	1.57
829.9924316	2.91
837.5236206	1.35
838.4186401	1.27
843.2824097	0.61
845.4834595	2.20
846.7548218	4.10
848.0755005	2.83
849.4860229	2.96
855.0917358	0.77
857.4017334	5.80
861.2018433	1.06
863.1864624	71.44
864.0556030	11.28
865.2947388	46.26
866.2604370	10.41
874.5663452	1.64
875.2199097	4.15
905.2927246	1.86
907.2758789	2.41
908.2121582	1.39
939.7644653	2.24
945.7441406	2.47
947.4231567	0.88
963.2495117	0.28
971.3967896	3.23
975.2175293	1.67
981.4179077	8.22
983.5493164	0.87
984.7302856	0.53
989.1994019	12.76
990.3246460	2.15
991.5894165	0.41
993.0104370	2.13
995.2897339	2.58
999.2827759	1.62
1001.3804320	4.23
1025.5136720	7.55
1026.1698000	0.43
1027.2423100	16.05
1028.1405030	0.61
1044.5212400	1.12
1095.2087400	0.36
1103.5241700	0.31
1107.1135250	0.38
1109.3244630	1.43
1110.2897950	1.76
1119.1968990	0.39
1127.6101070	1.15
1133.5587160	2.46
1134.5767820	0.47
1137.1018070	0.90
1145.1062010	8.48
1146.1871340	0.82
1151.2111820	65.51
1152.3005370	26.58
1153.3493650	12.33
1154.4169920	11.17
1163.2580570	1.75
1164.4733890	3.23
1177.2709960	1.01
1178.5026860	1.32
1179.2868650	0.81
1195.2656250	3.83
1196.4689940	0.90
1297.5601810	3.33
1298.6212160	1.17
1315.3629150	22.15
1316.2056880	15.47
1316.9334720	0.72
1317.6149900	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.1639
Annotation	Villosin B
Peak:m/z	Relative Intensity
93.0964813	0.96
108.7538147	0.92
126.9842224	3.41
136.2020569	1.92
151.8263092	4.31
158.8966980	0.42
170.9906616	1.38
185.0839539	0.88
188.0851440	1.17
192.1482544	0.60
193.1428375	4.18
194.0491180	1.15
196.9552307	1.05
202.2512817	0.39
215.0608521	0.45
217.4360352	0.89
220.1329651	0.63
224.0167236	0.98
232.9409485	0.20
235.3664856	0.49
241.8668213	1.37
244.8315125	8.09
250.9090576	1.62
255.4885254	0.95
256.1806335	0.38
257.0775452	1.07
262.9600830	42.65
269.8614502	1.10
279.1701050	2.72
280.2096252	19.07
280.9871216	100.00
289.4686279	16.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.359
Annotation	Unknow
Peak:m/z	Relative Intensity
169.1971893	0.23
172.8286743	0.59
192.7002106	0.19
196.9867859	6.62
197.7630768	0.24
200.9932556	0.83
219.1132812	13.85
220.2895508	0.13
221.1744385	0.11
266.1383667	1.07
277.0718994	0.49
281.8449707	0.10
284.1528320	5.53
287.1398926	0.30
289.1016846	0.46
290.3021851	0.22
299.0582581	0.57
302.0877075	0.38
310.0889587	0.15
318.3051453	1.30
341.1797485	0.84
351.4285889	0.27
359.7448730	0.22
365.9598999	0.24
369.6535034	0.33
373.1748657	0.83
379.3544312	0.28
393.6770020	0.36
397.2290649	8.58
398.4577637	1.35
400.1522217	0.62
405.3958740	0.75
408.2682495	0.17
415.2697144	52.30
416.2964478	6.65
417.5256348	0.51
420.0909424	0.18
421.6957397	0.91
422.8636475	2.43
429.8740234	4.89
452.0729980	1.08
455.4602051	0.65
457.4329834	0.67
463.9862061	0.26
465.5214233	5.39
466.6647339	8.44
467.3742065	0.91
469.1820068	0.29
470.1121216	0.42
471.0291748	0.97
473.3540649	2.34
473.9895020	1.11
478.5138550	1.40
479.5267944	7.14
480.2189331	0.50
494.8566284	0.48
499.0291748	0.65
500.2247925	2.26
501.1920166	0.22
505.2821045	3.40
507.6698608	0.84
509.0127563	2.34
509.7782593	0.61
511.2861938	0.15
513.9690552	13.75
514.8776245	2.43
515.7147217	0.25
518.3223267	0.85
520.8399048	0.80
521.9221802	0.40
522.8529053	23.37
523.4745483	22.04
524.6157227	1.43
525.3591919	0.77
527.3670044	0.48
528.2708740	4.08
529.4224854	0.88
532.3919067	0.48
533.1690063	0.48
534.3023682	2.28
538.4629517	0.11
556.4418335	2.72
561.1795654	1.48
562.3435669	1.78
565.7963257	3.70
566.4500732	0.15
567.7009888	0.55
570.4491577	12.75
571.1033325	4.41
574.9082642	1.65
579.3168945	1.37
610.1944580	1.26
620.5830078	0.47
624.4932251	0.63
631.7224121	0.35
633.9290771	0.27
642.5017090	0.34
648.5621338	1.51
649.4712524	0.62
676.5856323	0.26
727.1780396	0.37
727.9129639	0.25
733.7258301	0.58
735.6453247	0.91
743.7129517	1.67
744.5907593	7.54
745.5476685	1.18
756.2359619	1.66
761.5297852	100.00
762.6278076	45.57
763.6093140	1.89
815.8933716	0.38
816.7398071	0.21
817.6248169	0.36
818.5801392	0.83
830.5260620	0.56
831.7003784	0.50
841.2788696	0.99
844.7402344	2.04
845.9857788	0.73
848.9838867	0.77
849.7290649	0.40
858.8460083	1.53
859.7639771	0.11
875.6337891	0.62
892.5114136	0.51
913.7518921	0.17
914.6811523	0.36
926.6558228	0.52
927.6575317	0.20
931.6218262	1.46
932.4382935	1.79
940.5082397	0.48
941.7055664	0.80
943.6572876	1.99
944.6404419	0.28
947.3237305	0.44
957.6218872	39.66
958.6470337	19.74
959.7744751	1.99
1026.8906250	2.01
1027.5915530	0.63
1028.9760740	0.16
1041.2486570	0.41
1044.5589600	2.46
1045.1944580	0.51
1046.6275630	0.55
1062.8215330	1.08
1063.5231930	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	286.09
Annotation	Buchananine
Peak:m/z	Relative Intensity
80.8881836	0.18
83.0897064	0.14
84.9294739	0.10
94.7958527	0.04
96.9543762	1.20
98.8072205	0.73
105.3115082	0.27
105.9552307	4.63
108.9686127	4.39
115.1087723	0.07
116.1771469	0.09
116.8762207	0.11
122.1973267	0.22
123.9050674	100.00
126.9297256	4.31
134.8709412	0.04
144.8845367	0.70
147.0868225	0.19
155.1670532	0.16
160.0296631	0.14
165.9536133	0.06
169.0425110	0.09
171.0972443	0.12
173.1672668	0.13
177.9679260	0.12
180.9702148	0.08
183.2787476	0.09
185.0630188	0.14
186.4440918	0.11
187.3536682	0.33
188.9130859	0.04
190.0362549	0.68
196.0315552	0.63
196.7954407	0.03
197.4245300	0.21
199.3488770	0.12
201.8455200	0.87
203.2373962	0.08
204.2413940	0.04
206.2222595	0.04
208.0273743	0.43
209.2223206	0.12
211.4216919	0.14
220.0669250	0.29
221.1683655	0.06
222.0158081	0.07
223.9545898	0.12
226.1349182	0.20
226.8776550	0.03
231.1606140	0.11
232.1805420	1.15
238.3055725	0.04
240.3167114	0.25
241.1209717	0.19
243.1984253	0.12
244.2610474	0.03
245.1304932	0.18
250.1147156	61.18
254.9536743	0.10
256.1223755	0.03
262.9223022	0.13
268.0874634	50.92
269.0693054	0.11
287.2251282	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	217.11
Annotation	3-Hydroxysebacic acid
Peak:m/z	Relative Intensity
72.9224701	0.31
93.0450134	0.09
94.9615784	0.02
96.9237671	0.55
100.9451294	0.06
109.0675812	0.09
118.7429657	0.07
121.9288635	0.03
123.2942047	0.05
125.0645447	1.47
133.1721497	0.03
137.0141754	0.11
141.0626068	0.04
142.9660339	100.00
145.1106720	0.20
152.9247284	0.14
155.0222473	27.45
157.0345764	0.62
161.3745270	0.08
171.0498505	0.29
172.9669037	0.43
174.9008942	0.22
178.7901611	0.16
181.2504883	0.06
189.0939789	0.24
196.9872742	0.25
199.1135712	29.96
200.2634430	0.04
201.1462402	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1296
Annotation	Robinetinidol-(4alpha->2')-robinetinidol-4beta-ol
Peak:m/z	Relative Intensity
165.0696411	0.23
175.1201019	0.05
176.6027069	0.21
189.8648987	0.05
201.0189209	0.22
203.1453857	0.41
209.8356934	0.09
217.1332092	0.13
219.4609375	0.05
220.8728333	0.05
227.0092163	0.14
228.0374908	0.04
230.1885529	0.08
242.9350281	0.04
244.9797516	1.54
246.1913757	0.22
260.9925537	0.17
262.1992188	0.18
269.0423279	0.04
271.0065308	1.81
272.0406799	0.39
279.2476807	0.03
284.1301270	0.09
287.2096558	2.78
288.3443604	1.45
289.1549072	7.51
290.1759644	0.85
291.3492432	0.11
293.1002808	0.07
297.2324829	1.79
298.2073364	0.05
305.0852661	1.14
306.2149048	0.03
313.0825500	0.03
315.0789795	18.15
316.1058960	2.53
321.2572021	0.09
323.1921387	0.13
326.1237793	0.13
327.0285645	0.09
332.3503418	0.05
337.2667847	0.03
345.1820068	0.15
355.9763794	0.04
357.1527710	0.20
361.5963745	0.09
379.2702026	0.14
381.4895630	0.18
382.1266479	0.10
385.0642090	0.04
395.0579224	0.95
396.1917725	0.38
397.1019287	0.23
401.3642578	0.06
407.2754517	0.08
408.1249390	0.07
413.1364136	2.28
414.2590332	0.49
423.1748047	2.80
424.3070068	0.20
425.1417236	0.04
426.2501221	0.03
431.0700684	0.10
439.3488770	0.03
441.1379395	100.00
442.2112427	15.39
447.1861572	0.06
449.1571655	0.55
450.4774780	0.03
456.2726440	0.18
465.2904053	0.02
467.2242432	0.66
468.5380859	0.05
477.3091431	0.03
483.2546387	0.10
493.2943115	0.05
547.5452881	0.31
557.0565796	0.80
558.3893433	0.12
575.3282471	2.29
576.3175659	0.64
578.3041992	0.18
594.3340454	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	206.0459
Annotation	4-(2-Aminophenyl)-2,4-dioxobutanoate
Peak:m/z	Relative Intensity
118.1507721	0.08
133.9509125	76.80
135.0278320	0.09
135.9788208	0.11
144.0524139	31.30
146.0147095	100.00
146.7006683	0.05
160.0189514	0.24
161.9428558	47.58
163.9644165	0.06
178.1116638	0.07
179.1780853	0.03
187.0998840	0.05
188.0772858	4.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2186
Annotation	Laciniatoside V
Peak:m/z	Relative Intensity
165.0841522	0.10
180.1679688	0.06
195.0429535	0.89
196.1396790	0.06
243.3494720	0.18
250.9720459	0.04
297.2040405	0.05
299.3768311	0.01
314.2871704	0.66
315.1374512	0.09
323.2545166	0.06
327.2681885	0.02
329.2411499	40.26
330.2411499	7.61
339.3333740	0.03
358.4865112	0.26
359.1083374	0.69
360.0275269	0.13
361.3862915	0.01
367.3466797	0.04
368.5487061	0.02
369.1934204	0.04
375.0550537	0.07
377.1101074	100.00
378.1197510	10.51
389.4732056	0.08
403.4484863	0.13
405.0777588	0.09
405.9827881	0.13
407.2293701	0.15
424.4368896	0.03
427.1408081	0.03
439.4216919	0.12
456.5354614	0.05
461.2357788	0.06
462.9716797	0.07
469.1744385	0.01
489.2621460	0.03
490.0702515	0.10
496.2021484	0.09
499.8657227	0.02
512.3920288	0.05
517.2107544	0.03
524.3876343	0.06
525.2205200	0.03
528.0111694	0.05
538.7770386	2.27
540.0429077	0.16
549.4616699	0.09
556.4784546	0.02
557.9830322	0.07
563.4168091	0.04
565.0787354	0.30
568.4562378	0.03
587.5293579	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0772
Annotation	Gerfelin
Peak:m/z	Relative Intensity
137.0095825	0.05
153.9954224	0.06
161.1683960	0.11
165.0913239	0.13
171.3379517	0.03
179.0579834	0.68
199.0529175	0.05
215.3362122	0.13
228.1443176	0.03
229.1847534	0.05
233.3444824	0.03
237.2220764	0.18
238.9878540	0.04
243.3839417	0.18
244.9620972	0.07
247.2473145	0.22
249.3380737	0.04
263.3878174	0.04
271.4282837	0.03
272.0522156	0.03
277.1116028	0.07
289.0974731	100.00
290.1248779	0.10
291.3078308	0.33
293.2116394	0.04
296.3134766	0.20
304.8344421	0.18
307.1694641	0.13
315.1777649	0.66
316.2796021	0.04
317.1673889	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.1844
Annotation	Citronellyl propionate
Peak:m/z	Relative Intensity
70.9195557	0.01
80.9704056	0.02
82.8587189	0.04
84.9586945	0.13
87.9783325	0.13
90.9645081	0.01
94.9174347	0.61
96.7636108	0.03
98.9716644	17.59
101.8047180	0.02
102.9630737	0.02
106.9453430	0.10
108.9891357	0.06
111.0290833	0.21
113.2890930	0.06
119.0827942	0.01
120.9841614	0.46
123.0218658	0.07
123.8787537	0.02
124.8412476	0.08
127.0855255	0.01
129.0664520	0.03
132.8650055	0.11
134.9498901	0.06
137.0725555	0.02
139.0884552	0.10
142.0008545	0.05
144.8147888	0.04
149.0196991	0.18
150.9513550	0.08
153.0623322	0.19
154.9153290	0.09
157.1606903	0.10
159.0706635	0.05
165.2702789	0.02
167.0931244	0.09
167.9397430	0.03
169.1172028	0.17
171.1151581	0.05
171.8927155	0.04
177.0875397	100.00
182.8049774	0.03
184.8394318	0.02
191.5063324	0.01
192.5750427	0.05
195.0208893	47.90
195.9687042	0.03
196.9272461	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
97.0046539	0.11
98.9023895	0.52
100.9314117	8.06
112.9729614	30.21
114.8907471	1.28
116.9490967	0.21
118.9089661	21.11
125.0690689	1.49
130.8880615	10.90
142.9512024	27.73
149.0015259	5.61
160.3010864	1.20
160.9542847	25.20
177.1272888	0.16
178.9096375	100.00
191.0852661	0.41
221.1069946	0.15
280.9587402	1.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	895.1943
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
255.2504883	0.15
256.0440674	0.51
257.0515137	0.30
261.2829895	0.14
265.3930664	0.06
266.0883179	0.05
266.9885864	0.06
269.1113586	0.09
271.3002930	0.42
278.8650513	0.05
281.2778625	0.17
283.0770569	0.56
284.0494995	9.27
285.1818542	6.44
287.2072754	0.03
289.4053345	0.24
298.1839600	0.29
299.1175537	0.93
303.1205750	0.04
309.2681580	0.14
311.1640930	0.19
321.1320496	0.23
327.0737915	0.32
339.3980713	0.34
351.0692139	0.10
361.7159119	0.04
379.1096802	0.07
393.2969360	0.08
422.9055786	0.04
425.0437012	0.12
429.0446167	0.20
447.1509399	100.00
447.7625732	0.34
451.1062622	0.04
466.9290161	0.14
471.2789307	0.10
509.1107178	0.07
535.6684570	0.11
553.2705688	0.05
588.9945068	0.10
591.4396362	0.04
605.3655396	0.26
625.3165894	0.10
647.1738892	0.07
715.0835571	0.07
725.3950195	0.15
728.4920044	0.35
732.2753296	0.06
733.4274292	2.23
742.4628296	0.04
743.4431152	0.05
759.1437378	0.35
763.2391968	0.14
849.1956787	0.30
851.2901001	0.16
859.0984497	0.14
865.4097900	0.09
875.3130493	0.03
894.9761963	4.27
896.1856689	2.12
896.8468628	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0875
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.0025635	0.03
108.0409241	0.01
111.0301514	0.05
118.0074005	0.01
127.062355	0.12
127.8961105	0.01
133.0491028	0.02
134.3467865	0.47
135.0141907	5.28
136.1184387	0.44
143.2973938	0.01
153.9317932	0.01
155.0552063	0.10
156.1430969	0.03
161.08255	0.65
162.0925446	0.11
171.1722565	0.03
173.1056824	1.67
174.0802765	0.18
179.0313416	30.79
180.0854645	2.48
189.2020264	0.01
191.0296631	100.00
192.0632019	4.97
217.2344666	0.01
273.3218689	0.01
292.1820984	0.00
307.0723572	0.04
309.2213745	0.03
323.1596069	0.01
336.035614	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
76.90167236	0.35
86.89349365	0.63
96.89393616	0.91
107.1123352	0.69
109.9439545	1.15
110.6801605	1.38
125.0512848	0.37
131.2104797	0.35
137.1181946	0.29
139.0831604	0.71
149.1411743	0.37
160.9144745	1.02
162.9859772	3.60
171.9324036	0.55
176.9775543	0.95
179.1499481	2.38
180.1285706	0.87
181.2112732	4.49
181.9673767	0.56
183.2413177	0.93
185.1438141	1.11
189.0099945	1.82
189.9240723	1.86
191.0954132	2.01
191.7601471	0.43
193.0165253	0.67
194.0847931	0.36
195.7694397	0.62
205.1298676	0.98
206.4319458	1.54
207.1008606	13.40
208.0541534	5.61
209.1584167	7.99
215.181839	1.02
221.1483307	1.02
222.2465057	3.39
223.1460114	10.16
224.3891144	0.69
233.1123657	6.21
235.8236542	2.30
236.4690552	0.44
251.0844574	100.00
252.1751709	10.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.17
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
98.99268341	0.74
118.6179047	0.81
128.9726257	1.62
131.1209412	1.79
133.0831604	1.59
147.2313843	0.57
153.1854248	2.19
165.0397949	1.41
167.2584381	1.26
169.9697571	3.87
177.1426239	1.21
183.006012	100.00
184.0570374	11.17
191.1799469	0.74
195.3366852	0.52
197.0666809	5.07
197.7853851	5.94
198.503418	0.53
201.1600189	0.36
211.1760864	1.69
213.1841125	1.72
217.26474	1.29
225.8004456	0.53
227.0308533	2.95
239.3221741	5.99
239.9775696	1.34
243.0524292	6.11
247.2142944	12.96
249.2993469	19.56
251.4416504	1.17
253.2070923	2.56
265.1564026	3.17
267.2050781	17.13
275.5395508	2.22
280.2369995	1.39
283.3013306	2.24
293.2354736	39.06
311.2356873	25.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8252258	2.11
295.3364258	0.10
296.8059692	38.03
354.2591553	0.11
378.4852905	0.13
380.5781860	100.00
381.3447266	0.34
439.3607788	0.16
464.5115967	95.61
465.2659912	0.49
540.9398804	0.25
546.6503296	0.56
548.4886475	54.26
549.3472290	0.19
585.9793091	0.45
586.7427979	0.08
612.0940552	0.08
632.4180298	1.58
633.0383911	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8170624	4.20
208.8152161	3.72
290.7800598	22.83
292.7835083	24.61
296.5369873	0.16
368.9252319	0.15
370.9146118	0.03
374.5971069	4.40
376.5277100	9.91
377.2510986	0.01
389.1161499	0.17
458.6027222	18.93
460.5413818	100.00
461.3566895	0.10
497.6288452	0.10
526.8574829	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.1384
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
217.0728455	1.70
221.1347504	0.20
243.3059082	0.54
309.3019409	0.23
353.1280823	2.99
373.1595459	0.37
378.7526855	0.48
391.2073364	100.00
447.0548706	0.77
477.1891479	0.53
527.4686279	0.38
535.4051514	0.61
547.0469971	0.79
553.0390015	3.98
565.1796875	11.06
571.0332642	0.70
579.3596802	0.71
583.4911499	1.88
590.0575562	0.78
690.9675293	0.53
709.3948364	2.27
712.8568726	0.29
727.2722778	14.08
745.1271362	42.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
88.1128540	0.10
96.8596802	0.34
100.9580154	8.86
106.4242706	0.33
112.9754333	18.98
115.0420074	0.55
118.9593811	17.80
124.9167023	2.33
130.8239441	10.49
143.0122375	26.31
148.8810730	4.76
160.9974518	21.36
175.9580078	0.14
178.9661255	100.00
221.1059875	1.25
250.9318848	0.11
257.0690918	0.20
281.0458679	2.41
283.5647583	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	432.81
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9885559	0.35
134.9226074	0.04
219.1281433	0.09
296.2528687	0.04
302.9395447	8.18
311.2174072	0.04
312.7631226	0.16
315.0884399	0.01
330.5711060	0.03
334.3652649	0.09
346.0186768	0.21
348.6540527	0.57
349.2709961	0.02
369.0169983	0.06
371.2757263	0.03
372.0135498	0.06
372.9834900	0.09
376.9477844	0.03
386.7928162	100.00
387.4248352	0.35
412.9861145	0.07
414.7267761	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1215
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1974792	0.07
161.0415955	0.10
179.0693970	0.05
209.1602020	0.16
211.9648132	0.07
227.0466919	0.29
243.0120239	0.08
270.8211670	0.08
279.0410156	0.10
280.0177612	0.11
285.0359497	0.15
293.2667236	0.14
297.3306580	0.08
300.2274780	9.88
341.3799438	0.78
343.1867676	100.00
345.0000000	0.72
361.0428772	0.31
370.8066101	0.45
371.4080811	0.16
374.2852783	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9716
Annotation	Unknow
Peak:m/z	Relative Intensity
150.1237488	0.01
183.0065002	0.02
183.7627258	0.02
200.8512573	0.06
201.9848633	0.34
214.0181274	0.04
219.7464752	0.01
225.1549683	0.03
230.0317993	0.01
231.8076172	0.01
256.0516052	0.04
259.7903137	0.25
264.1221313	0.01
268.7620544	0.04
269.6548767	0.01
285.8871460	0.14
288.0631409	0.02
302.9886475	0.16
303.9402161	1.17
313.1149292	0.13
313.9402466	0.03
316.1524048	0.02
321.8512878	0.04
330.0587158	0.46
331.1109619	0.21
331.9263000	0.66
332.9887085	0.06
334.0585327	0.01
339.0601807	0.02
347.9576721	2.85
349.0342407	0.02
357.0903625	0.05
358.1049194	0.11
374.8835144	0.10
375.6840820	0.21
376.4822083	0.01
383.3027039	0.02
392.1176453	0.10
393.9990540	100.00
394.6005859	0.32
400.9190979	0.15
402.1748352	0.02
402.8360901	0.02
410.3682556	0.01
417.0089111	0.01
418.9335022	2.52
420.0448914	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1665
Annotation	Unknow
Peak:m/z	Relative Intensity
137.2338867	0.04
143.1426086	0.16
144.0825958	0.34
149.1120148	0.21
160.9530334	0.24
176.9937134	0.19
179.0086670	0.14
189.0986328	0.06
203.0660248	0.06
205.1327820	0.06
207.1759033	0.09
220.5762024	0.14
221.2351379	0.03
243.1860657	0.13
247.2188416	0.57
250.5849609	0.22
255.1454163	0.05
261.5535583	0.17
262.3605347	0.04
262.9666748	0.11
271.1594849	0.06
272.1598816	0.08
273.1934204	0.18
275.1791687	0.08
285.1352844	0.05
286.3844604	0.10
287.1562500	0.09
293.1480103	0.13
297.2138062	0.04
299.0493164	0.16
303.2781677	0.05
306.9105225	0.05
311.1704712	0.18
318.1508789	0.09
319.4216614	0.03
322.9400330	0.12
329.2494507	0.07
334.3389282	0.11
337.2199097	0.02
339.0945740	0.02
340.2320251	0.08
341.2790222	0.19
351.2674561	0.13
361.3256226	0.03
363.3836975	0.08
365.1560364	0.14
379.2861633	100.00
380.2058411	0.05
381.1272583	0.43
395.4779968	0.24
396.9424744	0.03
407.2817993	9.31
409.2599487	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
101.0001907	0.07
112.9441910	0.07
119.0239563	0.15
136.9433899	16.91
144.0184479	0.13
163.9182739	0.10
165.0446777	0.52
178.9276733	0.11
180.9797974	0.19
183.2528076	0.04
215.1658020	0.10
216.9055481	0.03
223.0697021	0.10
230.9906921	0.26
243.0068970	0.15
248.5317383	0.33
253.1462708	0.20
256.9719238	0.06
261.0295410	0.10
266.0409851	0.09
273.2435303	0.06
281.0362244	0.10
282.1680908	0.09
283.0934448	0.17
284.0449219	0.07
299.1656494	100.00
300.0209961	0.17
301.2100830	0.34
307.1570129	0.06
316.9892273	0.12
325.3033447	0.10
326.8353882	0.27
344.8889465	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	Unknow
Peak:m/z	Relative Intensity
119.2175369	0.03
160.7033081	0.02
179.0140686	0.41
225.1954956	0.05
341.1524048	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0561
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.6753311	0.98
58.8969421	4.70
60.9357758	1.53
67.1941223	0.63
69.0104065	0.92
70.9721146	2.88
82.9747467	1.95
84.8736572	85.59
86.9114761	19.54
92.8791199	55.36
95.6573791	0.93
98.9905395	6.73
101.0396271	1.14
108.8899536	15.56
110.9633026	40.25
113.0169678	3.98
115.1102295	2.87
126.9795532	100.00
129.0899200	2.59
136.8135223	2.33
142.8243408	3.18
144.7988129	0.20
153.0574493	4.16
154.9378052	12.43
171.0273285	36.76
173.0022736	77.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1051
Annotation	Unknow
Peak:m/z	Relative Intensity
111.0257568	1.05
126.8741302	0.13
129.2041626	0.12
136.8893738	2.35
138.1780243	0.19
142.9204712	4.45
152.8456268	0.56
154.0792389	0.22
155.1011200	4.84
156.0483704	0.07
156.9635925	0.18
173.1102905	3.59
181.0990906	0.33
191.1058197	4.72
191.7552338	0.18
198.0557098	5.11
198.9981384	16.90
200.0616455	1.13
210.8843079	0.09
216.0614166	13.57
217.0922241	58.21
217.9361115	1.24
229.0194397	0.14
258.1426392	5.77
259.1616516	29.34
260.1333008	0.20
287.1218872	0.97
292.2553406	0.10
300.4339600	0.15
304.0300903	0.39
305.2269592	0.14
309.6573486	0.29
311.2151184	4.76
312.1889038	0.14
327.1878967	0.30
342.7783203	0.79
343.3958435	0.67
344.3015137	0.30
346.4496765	0.29
347.3994751	0.33
355.2509460	4.50
372.1596680	13.11
373.1957397	100.00
374.3954163	0.67
390.3747864	0.94
391.2635803	2.22
392.4701233	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1978
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
243.1325989	0.01
261.0744019	0.03
270.7866211	0.02
280.9595947	0.01
282.949585	0.01
285.1164856	0.04
287.1308899	0.15
288.4118958	0.01
289.2698975	0.01
298.0783386	0.01
298.988678	0.04
331.2152405	0.01
332.197937	0.01
337.3626709	0.01
367.2060547	0.03
370.2732544	0.03
374.2825928	0.01
381.39328	0.02
382.2224121	0.02
383.2825623	0.02
391.2741089	0.02
395.2321472	0.08
405.3471069	0.07
407.300415	0.19
408.3004761	0.09
409.1699829	0.01
411.2454834	0.02
413.2423096	0.13
414.2254639	0.04
423.0495605	0.05
425.0953979	0.12
435.0649414	0.02
449.2722778	0.09
450.3955078	0.03
451.2324219	0.16
453.2485962	0.04
454.8273315	0.02
483.2255859	0.02
496.1991577	0.03
496.9258423	0.02
509.2770996	0.02
525.3669434	0.03
531.4647217	0.01
533.4133911	0.08
537.2160034	0.01
541.4006958	0.03
542.6060181	0.01
543.7644653	0.06
549.3286743	0.01
553.0822144	0.01
559.4474487	0.05
560.5508423	0.05
569.3215942	0.01
575.2466431	0.14
576.1245728	0.12
577.1974487	0.25
593.8886719	0.01
609.50354	0.02
613.3943481	0.04
614.7409058	0.05
617.2936401	0.06
618.3255615	0.04
626.2513428	0.13
631.942688	0.04
634.3557739	0.01
636.1099854	0.02
638.3857422	0.13
640.5907593	0.03
643.1398315	0.01
656.2560425	0.05
657.3746948	0.02
668.3025513	0.03
677.7689209	0.01
679.4586792	0.02
680.1072998	0.00
681.4160767	0.02
682.9508057	0.01
694.1843262	0.18
695.2444458	0.21
696.0350952	0.19
701.2892456	0.12
702.9281616	0.24
703.5779419	0.05
712.4093628	0.15
713.3210449	0.05
716.0518188	0.10
716.7365112	0.02
720.1586914	0.04
725.2067261	0.03
737.3754272	0.04
738.2705688	0.07
739.3515625	0.11
741.3417358	0.03
742.373291	0.02
770.4093628	0.02
779.2230835	0.49
783.4020386	0.04
789.0143433	0.08
792.3538818	0.05
795.1148682	0.01
801.1903687	0.21
801.833313	0.03
807.8579712	0.09
811.3418579	0.02
813.2165527	0.02
814.2903442	0.01
819.4949951	0.05
822.3918457	0.02
829.2451172	0.01
842.0297241	0.08
847.348877	0.12
863.2008057	0.10
865.2064819	100.00
866.0453491	0.42
867.5541382	0.05
868.9507446	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0928
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
98.9029236	0.06
111.0869904	0.05
118.9931335	5.88
129.0709839	0.02
136.1886292	0.04
136.8576660	0.09
143.2002258	0.11
144.8135986	0.05
151.1380920	0.02
151.7553406	0.03
154.9967804	0.59
163.0300598	100.00
173.0434875	4.03
191.0362396	8.10
194.6419373	0.10
210.0664673	0.03
212.1015015	0.08
229.1012268	0.06
247.1012573	0.19
252.1445923	0.06
253.3103333	0.04
257.1461792	0.03
267.3190918	0.02
274.1755371	0.13
275.1115112	0.11
275.9044189	0.01
283.1514893	0.03
291.1322021	0.10
293.0836792	0.30
294.0776978	0.13
309.2043457	0.07
316.4903564	0.04
317.1153564	0.04
319.0747375	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2416
Annotation	Moniliforminol A
Peak:m/z	Relative Intensity
84.94820404	0.24
90.99432373	0.83
92.81369019	0.53
94.99269867	2.11
96.90563965	1.97
98.71238708	0.37
108.963829	3.60
110.9509048	0.59
112.8569946	0.98
117.0092087	0.22
118.8385773	0.67
121.0085754	0.97
122.9458313	2.35
124.973587	0.95
126.8265381	0.51
128.9957428	0.72
131.1853485	0.20
133.2118835	1.53
135.0737915	1.61
136.9829407	0.58
138.1044312	0.44
138.8815308	3.82
140.1700745	0.25
141.1117096	0.94
143.159668	0.36
147.0115814	1.17
149.0240479	0.73
151.1137848	0.61
153.0030823	1.49
153.8995972	0.34
154.9655457	1.08
156.0822449	0.12
157.1430664	0.51
159.1023865	0.72
161.2058716	0.22
163.0921326	0.46
165.0541534	1.20
167.1620941	0.11
168.9960327	0.83
171.0140991	0.12
172.9807434	0.75
174.1750336	0.07
175.1119843	0.92
177.2648621	1.03
178.9523315	1.87
180.9454346	1.57
183.1362915	1.50
185.278656	0.43
186.1467285	1.14
187.1348419	0.19
189.0729218	0.41
193.2365723	1.49
194.3510437	0.78
195.1103516	1.92
196.9676514	5.29
198.9978333	0.25
201.756958	0.28
203.194519	0.94
205.2688904	0.60
206.9396667	1.97
207.9090271	0.53
209.1540222	0.74
211.0772705	1.02
213.0177307	1.00
215.3228455	0.60
217.0931702	0.62
219.2402649	1.24
221.0648193	2.23
223.3025513	0.42
225.1302795	2.01
226.0310974	0.39
227.0223389	0.53
233.0430603	1.44
235.2210083	0.13
237.1839905	4.76
239.1152954	11.17
243.2826538	2.50
248.9118652	0.17
251.0511169	1.75
252.0630188	0.58
253.2693481	1.96
255.1866455	1.65
256.4000549	0.28
257.2539673	0.47
261.020752	7.43
268.8605042	0.26
277.1437073	0.47
279.2259827	100.00
280.2905884	1.24
281.1951904	1.32
282.3099365	0.11
288.1867981	3.00
288.8685913	0.83
296.9623718	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2812
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0361786	0.01
248.1230316	0.01
285.3301392	0.05
325.3091431	0.16
331.5015869	0.02
337.4279175	0.02
343.9938354	0.05
355.3111572	0.16
356.2064209	0.07
373.3765259	0.63
374.6953125	0.01
378.1714478	0.02
411.2866821	0.05
445.3772583	0.03
461.2259521	0.03
492.0473022	0.06
495.1085815	0.05
496.4175415	0.11
535.3739014	100.00
536.3513184	8.85
563.5346680	0.10
582.4490967	0.08
587.5458984	0.01
589.0069580	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.26
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
557.3488159	0.11
847.2977295	0.20
1135.523682	0.38
1153.256226	100.00
1154.026123	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
74.93236542	0.08
92.84085083	0.45
98.79293823	0.07
113.0466003	0.20
134.9594879	0.06
144.9821777	0.06
156.4667816	0.05
159.1225281	0.08
167.1558838	0.28
168.7831879	0.10
170.9776459	0.21
172.4944305	0.14
173.2993011	0.14
175.785675	0.12
177.0301056	0.10
181.2536774	0.26
187.2614899	0.35
189.0434418	0.22
192.7876129	0.14
199.0436859	0.48
201.0337067	0.05
202.4165649	0.12
212.9745636	0.11
215.1829987	0.72
216.9586487	1.17
218.8853302	0.87
225.2998505	0.40
226.8699188	0.13
229.1791992	0.10
230.260849	0.15
233.1717682	0.70
241.8968048	0.23
243.1464233	100.00
245.1342163	2.32
246.1655273	0.42
260.9129028	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	864.1892
Annotation	Unknow
Peak:m/z	Relative Intensity
243.3629456	0.23
244.1587830	0.19
245.1540375	0.25
246.0009918	0.06
246.9253082	0.19
255.2888184	0.07
256.1745605	0.14
257.3342896	0.12
260.7827148	0.15
272.9411926	0.15
281.4655762	0.12
283.1726074	0.52
284.0723267	0.19
285.1575928	0.22
286.1737366	0.18
287.1844482	3.86
288.2634277	0.44
289.1663818	3.01
290.1710815	0.12
299.3096924	0.42
300.9280090	0.06
304.7834167	0.45
311.4338379	0.43
314.9140625	0.06
321.2303772	0.41
329.3992920	0.07
330.8954163	0.31
332.1938477	0.05
337.3281860	0.14
339.1608582	0.05
342.0619507	0.08
353.0176086	0.08
363.3818359	0.12
367.0803833	0.59
369.3110962	0.17
371.3618164	0.44
379.1405029	0.05
381.2938843	0.06
383.3464050	0.11
387.0519104	0.64
389.0417480	0.05
390.8602295	0.06
393.3050537	0.14
394.1361694	0.12
395.3798523	0.77
396.8023682	0.35
403.2197266	0.13
405.1622314	1.80
407.1300049	5.55
408.1732788	0.17
413.2364502	1.20
414.3212280	0.15
420.3048096	0.08
423.2014160	1.20
424.4073486	0.23
425.2444458	2.41
430.9224854	0.22
432.1582642	0.09
434.9671631	0.55
437.2220459	0.15
438.9455566	0.18
447.3152466	0.47
449.2791748	1.14
450.2411499	0.83
451.1843262	0.83
452.3627319	0.67
454.1773071	0.30
454.8941040	0.07
455.8121338	0.07
463.2797852	0.13
465.3393555	0.08
468.3139648	0.26
469.0827637	0.38
474.7762451	0.07
485.3213501	0.08
490.2238770	0.34
493.6342163	0.05
513.3113403	0.22
515.4234009	0.56
516.3870850	0.10
517.3422241	0.07
523.3628540	0.32
525.3396606	0.37
526.2663574	0.33
531.1391602	1.32
532.4009399	0.36
533.2931519	0.65
536.7473755	0.06
543.3821411	0.44
544.2064819	0.23
547.1987305	0.17
549.3024292	0.14
550.7578125	0.27
553.2531128	0.15
555.2129517	0.34
556.2360840	0.20
557.2487793	0.77
558.0532837	0.24
559.3149414	0.91
560.2661743	0.33
561.2627563	0.17
567.1582642	0.35
569.2926636	0.92
570.0802612	0.09
571.2294922	0.27
574.0172729	0.53
575.1751709	2.75
576.2022095	1.79
577.2741089	5.81
578.3866577	1.39
579.9310303	0.52
580.5900879	0.07
585.1167603	0.12
586.2755127	0.08
587.1676025	0.42
590.0297241	0.14
592.3619995	0.69
599.2723389	0.05
601.3916016	0.10
602.2774048	0.05
603.5401611	0.19
609.3905029	0.52
610.6432495	0.08
611.4229126	0.22
613.2959595	0.55
614.1511841	0.31
617.6964111	0.92
618.9504395	0.85
621.8014526	0.22
622.4867554	0.16
625.2211304	0.33
627.0267944	0.51
629.4664917	0.34
630.1932373	0.12
631.0491333	0.12
631.8604126	0.04
634.1753540	1.26
634.8513184	0.98
635.5319214	0.40
636.8695679	0.44
638.1467285	1.30
638.8204956	0.29
640.0546265	0.25
640.9526367	0.06
643.1074219	0.85
643.8509521	0.67
644.6217651	0.37
647.9329834	0.48
649.3599243	0.24
650.7792358	0.33
651.5065918	0.22
652.7362671	0.13
656.2156372	0.05
656.9760742	0.36
658.0075684	0.18
667.2948608	0.49
668.8546753	0.22
675.2530518	0.20
676.2033081	0.38
677.5882568	0.28
678.6627808	0.14
681.2285767	0.47
682.9605713	0.25
684.1658325	0.12
689.7701416	0.33
693.2147217	1.22
694.3760376	4.57
695.3203125	2.72
696.3622437	0.40
698.0578003	1.10
701.2526245	1.73
702.7661133	0.70
703.6360474	2.86
705.4071655	0.22
707.6606445	0.11
710.5080566	0.72
711.2992554	0.12
712.4826050	1.81
713.3523560	0.45
716.5709229	1.48
717.3424683	0.38
719.6480713	4.76
720.5761719	2.44
722.1176758	0.11
724.1242065	0.17
725.8106079	0.72
737.2561035	1.30
738.6982422	1.16
739.5167847	1.17
740.1672974	0.61
741.3685303	0.19
743.6882324	0.29
744.3867798	0.08
745.5230713	0.54
747.3779907	0.06
757.4605103	0.28
766.6686401	0.31
770.6426392	1.99
779.4660034	12.48
780.3236084	0.18
781.0146484	0.21
788.3588257	2.34
788.9710083	1.72
792.4608154	0.48
793.1897583	0.44
801.6818237	1.88
802.4392700	0.16
806.1741943	0.18
809.3790283	0.12
809.9816284	0.34
811.0731812	0.11
812.4022827	0.22
819.4180298	0.26
820.4830933	0.24
821.4414062	0.40
826.5556641	0.04
829.6853027	0.07
834.1696167	0.10
837.7238159	0.21
842.8842163	0.07
845.1757202	0.80
846.4172974	1.28
847.2860107	1.25
848.4511108	0.42
849.4582520	0.04
863.3999634	0.05
865.1400757	100.00
865.7654419	0.22
866.3729248	1.03
867.4647827	0.26
872.8512573	0.08
875.3876343	0.30
876.3959351	0.11
899.2630005	0.07
902.7107544	0.17
907.2531738	0.36
915.2199097	0.10
932.1442261	0.07
938.8081665	0.72
957.3486938	0.09
963.3433228	0.06
964.6181030	0.26
965.3468628	0.74
967.2554321	0.10
971.5856323	0.15
972.4528198	0.03
981.2209473	0.56
982.2470703	1.24
983.2875977	0.96
984.2478638	0.24
989.3182983	3.11
990.2507324	1.11
994.5160522	0.15
998.5797729	0.25
999.5713501	0.15
1001.7406620	0.26
1002.5468140	0.22
1009.4106450	0.18
1010.4265750	0.09
1025.7346190	1.20
1027.1599120	0.96
1028.2679440	1.56
1031.6673580	0.11
1032.7872310	0.06
1064.5200200	0.08
1065.2918700	0.10
1069.9069820	0.28
1084.3791500	0.17
1089.2912600	0.24
1102.1096190	0.04
1107.1243900	0.22
1108.3480220	0.28
1109.3374020	0.04
1110.4733890	0.29
1119.7985840	0.21
1126.4533690	0.21
1127.4643550	0.26
1133.0649410	0.17
1133.8937990	0.05
1135.4133300	0.79
1136.1237790	0.17
1137.1867680	0.31
1138.4592290	0.21
1144.9843750	0.05
1145.6428220	0.11
1150.5024410	0.35
1151.3350830	6.37
1152.3525390	4.42
1153.4472660	3.74
1154.2686770	3.16
1161.3334960	0.12
1163.0205080	0.16
1193.0048830	0.22
1195.1082760	0.43
1196.0858150	0.73
1197.5609130	0.05
1227.5695800	0.03
1253.4467770	0.07
1254.4781490	0.35
1258.7855220	0.05
1260.6602780	0.08
1269.1478270	0.17
1270.2481690	0.19
1271.3337400	0.60
1277.4769290	2.23
1278.6682130	0.31
1288.3232420	0.59
1290.0130620	0.13
1298.2933350	0.12
1301.4400630	0.15
1311.1000980	0.08
1313.1541750	0.40
1314.6738280	1.35
1315.6253660	0.93
1316.4910890	1.22
1317.2155760	0.13
1373.4049070	0.20
1397.0877690	0.09
1398.4232180	0.38
1421.3011470	0.05
1422.2703860	0.07
1434.3609620	0.35
1439.4097900	2.99
1440.3543700	3.40
1441.3697510	0.82
1442.2669680	1.43
1443.3485110	0.09
1452.1533200	0.47
1483.3868410	0.98
1484.3669430	0.06
1485.8233640	0.24
1559.4829100	0.15
1602.6075440	0.15
1603.4313960	1.70
1604.5201420	1.89
1605.5202640	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	REBAUDIOSIDE A
Peak:m/z	Relative Intensity
483.8681641	4.73
522.8991089	1.12
682.3944702	0.60
705.6240845	1.42
923.4570312	5.11
967.4562378	100.00
968.668396	2.73
973.0842285	3.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1764
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
143.1327820	0.13
159.0874329	0.33
161.0176392	0.62
167.1594391	0.38
191.2043762	0.20
192.1620789	0.13
212.1743164	0.11
245.4041443	0.19
269.2548218	0.07
272.0879517	0.05
278.1388855	0.43
287.4205627	0.32
329.2525024	0.55
330.3210144	1.25
347.2155151	100.00
347.9096069	0.53
374.0309753	0.97
375.2091064	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.917
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9843369	0.07
130.9191742	0.10
147.1026001	0.02
158.9107208	0.29
175.0102844	2.17
228.7762756	0.05
244.9699097	0.52
273.0340881	3.59
273.8353882	0.03
286.0713501	0.02
287.1136780	0.05
288.9526978	100.00
321.2091675	0.03
329.1471558	0.06
330.9853516	0.15
344.8903198	0.02
345.7949829	0.06
346.8159180	0.03
356.2304993	0.21
357.0619202	0.05
359.3562927	0.02
373.7909851	0.02
374.6119080	0.06
376.1951294	0.07
384.8565063	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
85.03800201	0.21
86.82963562	0.09
90.92004395	0.10
92.93747711	0.83
94.88848877	1.45
96.95252991	1.15
98.21442413	0.32
99.15834808	0.66
104.9833145	0.72
106.9303741	0.66
109.0270844	3.17
109.7953949	0.05
110.9144211	1.21
112.8825989	0.62
114.2913208	0.10
118.920517	0.14
120.3394012	0.32
121.1477356	0.58
122.9953613	3.61
125.0187988	1.26
126.9210434	0.87
129.0358582	0.14
131.0121307	0.24
132.8140564	0.50
134.9775391	3.39
136.9001465	2.04
138.9645996	5.93
140.7776184	0.61
143.0652771	0.36
146.9998169	1.77
149.0583954	0.78
151.104126	1.14
152.0714111	0.14
153.075531	3.21
155.0170898	2.59
156.8965759	0.72
159.063385	0.20
161.0856323	0.89
163.0834503	0.90
164.8387451	1.33
167.0558929	0.73
169.0971527	0.40
171.1633301	1.40
173.0359497	0.81
175.0935059	0.56
177.024292	0.77
179.1590118	0.14
181.1503906	1.17
183.2098694	0.94
185.0099792	0.16
189.2088928	1.25
190.7839661	0.14
192.2532654	0.13
193.223999	1.08
195.1249084	1.34
197.0075073	8.56
199.168335	0.86
201.2338867	0.60
203.136322	1.14
207.1713562	0.36
209.1011963	1.02
210.9337463	1.51
213.153717	0.86
215.0758057	0.32
217.2252502	0.20
219.134613	0.51
221.1149292	8.54
223.2787781	1.00
225.0466003	0.40
227.2322388	0.79
233.2814026	1.50
234.4678345	0.10
235.3156128	0.20
237.2085266	13.32
238.156189	0.25
239.2242126	12.24
240.1175537	0.06
241.3740234	0.19
243.2216187	2.72
248.97229	0.42
250.7472534	0.68
251.3709106	1.45
252.0375061	0.11
253.1497803	1.25
253.9693298	0.08
255.1781616	2.43
256.2487793	0.17
256.9624939	0.67
261.2420959	3.19
267.2480469	0.13
269.1621704	0.62
270.3616028	0.45
276.8629761	0.10
279.2398071	100.00
280.0557556	0.48
281.1493835	0.21
296.1844482	0.16
297.4176636	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1194
Annotation	Quinic acid
Peak:m/z	Relative Intensity
108.9667740	0.02
111.0898895	0.04
126.9619675	0.29
128.9111328	0.09
142.8824615	0.03
155.1178436	0.13
170.8458252	0.05
173.0646973	0.21
191.0555420	100.00
218.1330414	0.03
323.1080627	0.03
337.1016846	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
93.0160141	0.14
96.95292664	0.04
138.9579773	0.10
143.1894379	0.04
150.9540863	0.07
153.1379242	0.04
153.9472809	0.13
154.927536	0.13
155.8823853	0.08
165.2536469	0.12
166.931366	0.04
180.8222046	0.07
183.322525	0.10
187.0545807	0.07
189.0210266	0.21
197.119873	0.12
199.3023071	0.26
201.0525055	0.10
202.7024536	0.09
204.2298126	0.06
214.7433777	0.17
215.3548889	0.25
217.0763702	0.41
225.1082611	0.33
233.2411957	0.21
241.3116608	0.12
243.1485748	100.00
243.7562103	0.23
245.0961304	3.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2612
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
451.3894043	0.03
558.296875	0.07
683.2028809	0.01
807.4677734	0.02
846.1697998	0.04
889.303833	0.10
907.3701172	0.05
984.7060547	0.04
1118.54834	0.01
1153.256104	100.00
1154.260254	26.87
1154.93335	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9198
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0098572	4.21
198.9836884	1.13
217.1486359	0.23
227.1697083	0.02
228.9499817	0.58
270.8321228	0.04
272.9722290	74.30
371.2160645	0.09
385.1151428	0.57
386.9266968	100.00
398.1993713	0.04
426.0144348	0.10
426.9556580	0.17
430.4164734	0.06
456.3228760	0.03
457.1268921	0.02
471.7160339	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.4725
Annotation	Unknow
Peak:m/z	Relative Intensity
103.1437683	0.17
103.8008270	0.26
109.9535828	2.15
119.8804550	20.36
120.9698868	2.02
129.0502167	0.12
129.9545898	0.12
164.9489746	0.32
173.1944580	0.75
190.1968384	0.76
191.0148163	0.36
193.2097626	0.52
200.1117859	0.14
210.0294800	0.21
216.9929504	7.18
218.1565247	1.57
219.0799255	0.79
226.3204041	1.11
231.1790771	2.61
231.9293213	0.33
235.0625916	1.97
236.1351013	1.25
236.9731750	0.30
241.1268005	0.36
251.1980896	0.67
254.0472107	0.24
263.0757751	8.06
267.3284607	0.17
271.0525208	0.58
271.9656067	0.35
291.7666626	1.59
297.7368469	0.39
298.8551636	1.15
299.8825684	0.93
302.3206787	1.06
304.1132507	0.64
307.3890381	2.33
313.9860229	0.38
315.5557251	1.73
318.5386658	1.45
326.0687256	0.79
329.5332947	4.88
332.5705566	3.72
334.0041504	1.73
335.3256226	17.46
335.9525146	1.39
336.5868530	0.29
338.6671143	0.21
360.2327576	0.69
362.9104309	0.89
367.7531433	0.88
370.4767761	2.25
371.3970947	0.24
372.3385010	0.38
375.0090942	1.45
376.3674927	17.47
377.5789490	0.71
378.7011414	0.62
385.4247131	29.31
386.3216858	4.42
386.9804077	0.20
389.8467712	1.08
391.2497253	0.21
399.3245544	1.45
425.0112915	2.93
428.9928894	1.48
432.5972595	1.14
433.9342957	20.56
434.7798767	2.88
435.4168091	0.11
436.3523254	0.54
438.8636169	1.20
439.7886658	1.68
442.9420471	100.00
443.8350525	16.70
447.8180237	1.79
450.1642456	0.69
452.7413940	1.36
453.9875183	0.63
458.7644958	1.49
460.3727112	0.32
466.2969666	0.42
467.8315735	3.45
482.9171448	0.44
483.5342712	0.46
484.6148376	0.40
487.3208923	0.78
498.2915344	0.27
499.3404846	0.44
501.2360535	0.35
505.4346313	0.33
527.5077515	0.30
613.9349976	0.44
651.8283081	0.58
653.6586304	0.35
656.3309937	0.20
661.1008301	0.22
684.5944214	0.40
747.2243042	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1613
Annotation	b-D-Xylopyranosyl-(1->4)-a-L-rhamnopyranosyl-(1->2)-D-fucose
Peak:m/z	Relative Intensity
124.9554825	0.25
130.8729553	0.41
131.8361969	0.02
149.0076904	1.63
150.1809540	0.06
167.0385590	0.04
173.9858093	0.06
184.9484253	0.08
191.0627441	0.33
197.0548706	0.02
220.3936310	0.07
221.0644073	0.08
233.1576385	0.31
244.3739319	0.02
261.4729309	0.08
263.0963135	0.01
275.1411133	0.77
288.8766479	0.01
291.9530029	0.03
293.1034546	29.34
294.0836487	2.55
304.2585449	0.11
304.9733887	0.03
310.5358276	0.04
311.5325012	0.04
314.9572144	0.17
321.1515808	0.02
323.1797791	0.06
325.9796143	0.03
329.4513855	0.04
334.7575378	0.04
339.0952759	1.20
341.5700989	0.13
344.2835083	0.18
355.4470825	0.01
363.4048462	0.06
366.3832092	0.09
380.3187561	0.07
387.3159790	0.04
393.3088989	0.06
395.0454407	100.00
396.0952454	6.46
397.1575623	0.27
397.8836670	0.07
399.0584717	0.02
414.1062317	0.02
423.0605469	0.05
424.3410645	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.23
Annotation	Rhodioloside E
Peak:m/z	Relative Intensity
150.8384399	0.14
151.9944458	0.08
161.0373383	0.02
163.0953674	0.01
166.9297485	0.02
175.1614838	0.02
179.1209106	0.15
180.1934967	0.03
180.9933777	0.09
187.2826691	0.03
191.1474915	0.03
193.0588684	0.06
199.1115417	0.15
208.1852570	0.01
209.3519897	0.01
215.4018707	0.03
217.2716370	0.02
230.0770874	0.08
232.0589905	0.08
233.9805603	0.02
241.1567383	0.23
242.1412354	0.04
243.0722809	0.05
257.2263489	0.12
270.2424011	0.02
271.3428650	0.03
272.3197021	0.09
273.0720825	0.07
276.6328430	0.01
281.3451843	0.06
283.0572510	0.13
285.0385132	0.68
286.1757507	0.07
300.1094055	2.20
301.1422119	10.18
302.1171570	15.40
303.1516724	4.51
304.1337280	0.05
313.3063049	0.04
314.2832642	0.07
319.1657104	0.04
320.3396301	0.01
325.3189087	0.04
326.0362244	0.01
329.2041016	0.07
338.2355957	0.03
339.3172607	0.04
343.3454590	0.14
344.3036194	0.11
345.1836243	0.16
347.9277649	0.02
351.9177856	0.01
353.1496277	0.02
355.2745361	0.02
366.9403687	0.03
373.3442688	0.01
374.2060852	0.04
375.2805786	0.09
389.3908386	0.01
390.2142639	0.02
391.1350708	0.01
400.3894348	0.08
403.4566956	0.03
411.3492126	0.01
419.3786316	100.00
421.3128357	0.04
429.3664551	0.08
430.4880066	0.03
445.0771790	0.15
446.3597717	0.02
447.3462830	0.87
455.1258545	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.0699
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
88.8797913	0.05
92.9846344	1.23
95.0251007	0.06
104.9111176	0.16
106.8965454	0.12
107.9295349	0.09
108.8570099	0.22
110.9621429	3.46
114.9601059	0.11
116.8940735	0.44
122.8945847	14.15
125.1043854	0.21
126.9075546	6.05
134.9031982	75.68
138.9545288	45.64
144.0644226	0.06
144.9153748	0.06
147.0218506	0.32
148.9888000	0.48
150.9608612	42.40
154.8252258	0.04
158.8147278	0.11
162.8664703	38.55
165.2214966	0.12
167.0604858	1.19
170.9642487	0.38
173.0769348	0.16
174.9597626	0.51
177.0170593	0.52
179.0691071	9.50
180.2124023	0.05
180.9178619	0.13
183.0491333	0.09
186.9614563	0.08
188.9904633	0.52
190.2169800	0.18
191.9738617	0.16
193.2721558	0.17
197.2032776	0.22
199.0321655	0.09
201.7417908	0.25
203.2109070	0.24
205.2376404	0.64
208.0292358	1.32
209.0458679	0.04
210.9696350	0.10
214.1847839	0.21
214.8037720	0.33
216.1903992	0.52
217.1370850	0.25
218.3026123	0.04
221.1642761	0.06
222.1947327	0.18
225.0110779	2.09
226.0143127	0.18
227.0830994	0.46
228.1380005	0.16
229.0723267	0.22
230.2180786	0.17
230.9011841	0.50
233.1270752	0.22
235.1964722	0.23
238.9347229	0.10
241.8413086	0.59
243.0893860	1.97
244.0719910	0.22
245.1127319	1.02
247.0754395	2.20
247.9711609	1.08
252.0029297	0.23
252.9654846	0.38
257.0861206	0.16
259.1369019	14.39
261.0769958	100.00
262.2420044	0.19
271.1496887	50.57
272.2196655	0.19
279.3825073	0.06
288.7667236	0.06
293.0211182	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.09
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
81.2132568	0.09
88.6882019	0.08
102.8440399	0.11
105.0496521	0.08
109.9822998	0.29
114.7563171	0.10
116.7289276	0.04
117.8511200	0.05
125.8799591	0.15
126.8659210	0.12
132.9297943	0.10
139.9585114	0.10
151.0675507	0.81
154.1337280	0.34
158.9938202	0.17
161.9228363	0.28
163.0707855	0.09
166.1181183	0.11
167.2771759	0.19
168.0348663	0.15
168.9405823	0.44
171.3526917	0.07
174.9542694	0.72
176.0054779	0.09
180.7102356	0.30
189.1838531	0.10
189.9466858	0.25
191.8703003	0.21
193.0201569	0.15
203.9608154	0.36
206.0171661	91.45
207.0880585	1.94
208.0563507	0.23
209.1000824	0.05
210.0878448	0.36
211.0159760	1.53
216.0466614	0.12
217.5966187	0.07
221.1155853	0.14
224.0005188	2.21
224.8716278	0.08
228.9844360	0.11
233.9116821	100.00
235.5896149	0.39
237.0789032	0.09
238.0420685	0.37
243.0233307	0.30
253.0667114	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	4-Caffeoylquinic acid
Peak:m/z	Relative Intensity
107.0700684	0.10
109.1877289	0.03
126.9742279	0.24
134.97789	7.13
155.1520996	0.34
161.0874023	1.43
170.9395447	0.05
173.0764771	2.66
179.0345001	40.59
180.0419312	0.12
184.0072937	0.10
191.0461121	100.00
200.9597626	0.02
206.0107574	0.03
217.0611572	0.03
249.2876892	0.04
265.0817566	0.06
273.2786865	0.02
280.2446899	0.08
286.7365417	0.03
289.151062	0.07
289.9318848	0.34
291.1207275	0.04
293.4151611	0.05
297.4376831	0.02
306.4869995	0.36
307.3800049	0.85
308.3643799	0.05
309.1754761	0.11
310.3208618	0.03
311.0249329	0.02
317.1234741	0.06
320.8556519	0.11
325.2068787	0.10
329.8262329	0.09
333.0166016	0.07
335.1410217	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
140.1343079	0.09
152.9836578	0.20
167.0832825	0.03
175.0149231	0.10
179.2629395	0.05
196.0676422	1.58
196.8517609	0.16
211.5173187	0.08
213.1099701	0.21
214.0496216	1.43
255.2380066	100.00
256.259613	17.10
271.2105103	0.05
302.8169556	0.04
305.3556519	0.03
340.8157959	0.05
342.31073	0.04
363.262146	0.02
365.2229614	0.06
369.4454651	0.06
378.9578247	0.02
383.4314575	0.03
387.1107178	0.03
389.3265686	0.05
391.4786072	0.25
392.4546814	0.20
395.535675	0.04
407.4009705	12.23
408.3636169	0.05
409.3946533	0.04
418.6091919	0.05
420.0627136	0.02
423.3534546	0.05
425.2952271	0.04
434.8332825	0.42
435.5075378	0.24
464.990509	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2968
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0434875	0.04
177.0986633	0.21
178.9161072	0.07
197.0738525	0.06
204.9208374	0.19
211.1347046	0.24
213.1511536	0.54
214.9652100	0.34
218.1130219	0.05
220.8492126	0.27
225.3171692	0.14
235.2116547	0.09
237.2415314	0.11
239.3050690	0.13
241.2346344	2.34
245.2022095	0.48
257.2185974	0.76
259.1411743	2.60
259.8451538	0.02
261.1921997	0.06
263.2464905	0.34
269.2938232	0.11
270.7980347	0.06
273.2033691	0.30
282.3577881	0.20
283.3609619	0.25
289.2412720	0.44
291.1773376	0.05
297.1079102	0.06
301.2749023	0.48
305.2492065	0.39
307.1207886	0.02
308.1752319	0.09
309.2753601	0.09
311.4048462	0.08
313.2644348	0.06
314.9854736	0.79
321.4708252	0.03
323.5294189	0.14
336.2507324	0.06
337.3731689	0.14
345.1475220	0.13
347.0166016	0.07
349.4985352	0.09
355.4415894	0.11
359.2596436	0.07
367.4813232	0.23
373.3062134	0.05
375.5751343	0.03
377.2451782	1.71
379.4381104	0.03
382.5692749	0.39
383.3720093	0.44
385.4086304	6.84
386.3487549	0.05
387.4437256	0.07
388.3812256	0.09
398.2569580	0.27
401.1244507	0.08
403.4358521	100.00
405.3267822	0.21
407.2576294	0.05
411.5395508	0.06
413.4187622	0.12
419.3339844	1.02
420.2398682	0.11
421.3667603	45.63
422.3923340	0.13
429.5854492	0.07
431.2349243	0.14
435.3687744	0.14
436.1395874	0.04
437.0964966	0.13
445.5109253	0.39
447.4743042	0.46
448.8890381	0.11
451.3545532	0.19
461.0971069	0.08
463.3278809	0.08
473.4741211	0.06
497.6687622	0.54
498.3059692	0.03
506.0014648	0.36
507.3524780	0.43
510.2789917	0.12
515.7918091	0.20
519.0073853	0.05
525.4462280	0.15
534.3198242	0.07
536.8406372	0.79
537.4782715	3.59
538.8435059	0.19
539.5518799	0.12
547.4230347	5.22
553.4708862	0.17
560.5369873	0.12
565.4887085	91.27
566.5261841	1.09
584.4306030	6.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	366.21
Annotation	cis-10-Hydroxylinalyl oxide 7-glucoside
Peak:m/z	Relative Intensity
187.0413666	100.00
277.2931519	4.11
323.7066650	2.10
348.7525330	19.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	394.9757
Annotation	Ethiprole
Peak:m/z	Relative Intensity
169.0932617	0.03
185.4834290	0.04
207.9890137	0.07
232.1107788	0.14
239.2217407	0.04
255.2475586	0.06
265.1210632	0.02
268.4747925	0.04
283.4824524	0.09
295.7597656	0.05
305.2388611	0.18
317.2778015	0.10
326.4619751	0.06
331.0881042	100.00
334.2220764	0.04
335.0013428	0.04
349.0037537	0.37
349.6048584	0.01
350.9632568	0.36
351.7846375	0.05
366.5960083	0.13
372.5738220	0.08
376.5122681	0.30
377.2779236	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.2066
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
245.1080322	2.55
247.0539856	1.15
254.9691772	0.17
261.2188110	1.35
262.7279358	0.77
265.1891785	0.59
270.1890259	0.42
271.1828613	0.90
272.1012573	0.94
273.0463867	0.47
274.0293884	0.16
275.2084961	3.39
283.1160583	1.41
285.1605835	1.40
285.8289795	0.31
287.2679443	2.40
288.9969482	4.00
290.3668823	0.28
291.2776794	1.79
295.0153503	0.84
298.9593201	1.09
301.1282654	4.20
301.9447021	0.08
311.0833130	0.22
313.3224182	0.40
315.0369873	0.28
317.3684082	0.62
322.3215027	0.17
327.2781677	0.47
331.2937927	1.46
341.0489502	0.31
342.3701477	0.42
364.0946350	0.45
369.2723999	0.42
388.5674438	0.45
389.3588257	0.27
391.3609009	1.81
393.3713379	0.28
395.1382446	1.10
396.2127075	0.32
397.2037354	5.11
403.4326172	0.29
407.1741943	14.43
408.3731079	3.16
409.1845093	10.61
410.0970459	1.09
411.2171631	1.61
412.2428589	0.60
415.0862427	0.34
419.3757935	3.05
420.5021362	0.63
421.2164917	2.02
423.3253174	0.32
424.9948120	12.25
426.0919800	0.17
427.1535645	6.42
431.1372681	1.74
433.1850586	2.44
435.1179810	0.27
437.2321777	6.05
438.7128906	1.47
439.3772583	1.36
440.2296753	0.46
449.1787720	2.62
451.1723633	5.88
453.2321167	0.25
469.2424927	1.67
503.0744629	0.33
517.1940308	3.17
523.1404419	0.40
529.2497559	0.73
535.1218872	6.25
539.9273071	0.21
541.1881714	3.82
542.3956299	0.38
545.1828003	4.15
546.1516113	0.65
547.2578125	0.87
553.0980225	2.34
554.8498535	0.55
557.2006226	0.99
559.2311401	7.64
560.0862427	0.99
560.9313354	0.91
563.1665039	0.53
571.1914673	7.58
572.3684082	0.56
577.0715332	35.95
578.0552368	2.92
579.0541992	10.87
580.2073364	0.87
589.1812744	6.00
590.3796997	1.60
591.4455566	0.23
602.8802490	0.14
621.1148071	1.62
622.2488403	0.31
662.4566040	0.28
667.5453491	0.48
679.3228149	0.95
680.0426636	0.65
681.0744019	0.30
697.3187256	12.77
698.3680420	2.57
699.2631836	1.49
700.2882690	0.12
705.3214111	0.16
715.2716675	11.74
716.2643433	0.60
741.0186157	4.72
742.5968018	0.42
813.2255249	0.55
832.0980835	0.49
848.8638306	0.47
849.5602417	1.41
850.3540649	0.28
868.1520386	100.00
868.8345337	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
113.1805420	0.03
143.1733551	0.01
161.0803986	0.02
178.9878845	0.18
256.8896179	0.04
268.9271240	0.02
341.1546631	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1716
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1338501	0.05
175.3831177	0.03
176.9636230	0.10
187.2227631	0.22
192.2042236	0.06
195.1422119	0.60
235.4003296	0.08
259.2054749	0.05
266.9991455	0.05
281.1848145	0.12
308.9984741	0.17
324.2650146	0.04
351.4514771	0.24
358.3256226	0.20
359.2252808	0.18
368.5677490	0.07
381.3229980	0.11
383.3688965	0.53
384.4157715	0.05
408.7894897	0.07
419.9547729	0.19
425.3548584	0.05
427.3095093	1.17
435.1260986	0.23
441.4650269	0.17
445.4142456	1.72
447.4992065	0.16
451.2753906	0.19
453.1245117	0.02
455.5307617	0.32
456.4232788	0.19
469.3024902	2.12
470.1273193	0.06
485.1361694	0.38
487.3706665	100.00
489.4731445	0.03
499.6664429	0.17
501.6145630	0.07
511.0634155	0.31
513.4354248	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.1135
Annotation	Juglanoside A
Peak:m/z	Relative Intensity
100.8857880	0.08
113.0955658	0.11
114.9315338	1.73
129.1835022	0.32
132.0778656	0.24
133.0028992	0.86
142.8961487	0.36
145.1573639	1.63
159.3947144	0.15
161.1400299	0.31
162.6844482	0.21
165.0644531	0.07
173.1323547	0.11
177.0088806	0.59
183.2189331	0.07
185.0627441	0.29
192.9304657	0.08
202.2870331	0.33
203.1344910	0.05
207.0318909	100.00
207.6687012	0.11
208.4429626	0.06
216.9696350	0.05
220.7691650	0.25
227.4474792	0.33
230.9950256	0.71
232.1736450	0.05
233.1993103	0.46
236.7783508	0.11
243.0580750	0.18
259.1522522	0.40
269.0260315	0.11
277.1757202	5.60
278.9714355	1.69
280.0328369	0.27
281.1307983	0.11
283.4269714	0.08
287.1906738	0.80
293.0659790	0.37
295.0733337	0.18
299.0236206	0.08
303.1317139	0.45
304.2673950	0.18
305.2720947	2.47
307.2147217	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	573.1047
Annotation	Hegoflavone B
Peak:m/z	Relative Intensity
247.1726227	18.31
291.1298523	6.52
297.3120117	2.22
306.8255615	7.34
320.8994141	20.48
332.682373	5.62
337.0026855	6.57
361.4857788	4.43
372.9154663	2.43
381.1724243	33.61
411.024292	4.61
438.9541016	5.29
441.5467529	7.35
458.75354	4.71
493.0636597	14.41
537.0620117	2.88
555.086853	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1198
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
131.1486053	0.04
142.9645844	0.22
161.0022278	0.41
178.3661957	0.34
179.0345612	2.24
208.9473877	0.02
264.0671082	0.02
276.9606323	0.08
281.0552979	0.05
295.2593384	0.16
341.1726685	100.00
341.7736816	0.24
384.3212585	0.04
409.8022766	0.07
439.2186279	4.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
108.2402878	0.00
110.9348526	0.03
112.936409	0.01
126.9884949	0.05
133.0189209	0.02
133.6578369	0.01
135.0691986	0.51
135.8209839	0.13
143.0145874	0.00
144.8873901	0.01
155.164032	0.03
161.1040802	0.39
162.015564	0.04
165.2047119	0.00
171.1075134	0.05
173.0235748	0.41
174.1998901	0.02
179.0974731	3.52
180.1109009	0.23
191.036087	100.00
192.0912476	4.66
215.1137085	0.01
225.0682678	0.01
281.2907104	0.01
299.2789307	0.01
309.2713318	0.04
310.010437	0.01
333.3999023	0.01
335.1564941	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2611
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
740.3673096	0.02
831.5108643	0.07
846.4632568	0.02
965.7818604	0.03
983.2365723	0.17
984.8444824	0.01
1002.262695	0.04
1092.216431	0.03
1136.030396	0.16
1153.264893	100.00
1154.243652	34.43
1154.928833	0.15
1160.797485	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	576.63
Annotation	Unknow
Peak:m/z	Relative Intensity
161.2007599	0.27
164.0226746	0.30
167.2814026	0.31
175.0307922	0.62
177.1779175	0.60
178.9917145	1.88
184.3160095	1.69
189.2221375	0.95
197.0321045	1.30
203.2368927	2.83
205.0841522	0.68
206.1188354	1.00
217.0929871	2.76
225.4184113	0.74
227.0763092	0.46
229.0906677	0.94
230.2277832	0.91
231.3462219	0.57
243.0503998	7.13
243.9406433	0.30
245.1930542	14.04
246.2060394	3.63
254.9564362	2.15
261.0150146	5.12
269.2436523	2.04
273.0434570	1.21
285.0405884	1.70
287.1303101	23.02
288.1771851	4.93
289.1535034	100.00
290.2113037	8.35
299.1144409	3.62
300.3047485	0.38
300.9749146	0.34
303.3109131	0.36
311.0415039	0.99
312.2972717	0.22
314.1994019	0.27
327.1977539	2.25
329.1949463	6.63
330.0966187	3.82
331.3023071	3.27
336.4716797	1.57
337.2615356	1.59
339.1658936	1.41
348.5245972	0.87
351.1950073	1.26
354.2963257	0.27
356.8319702	0.72
357.7030640	1.00
360.3598022	1.96
362.3978271	0.56
363.2637329	0.56
365.2758789	1.30
366.4736328	1.12
367.2015991	0.96
369.2106323	0.99
371.0038452	1.16
373.6124878	0.30
381.6385498	1.49
384.2351074	4.44
393.7666626	1.83
395.2282715	6.92
396.4830322	1.51
402.2738647	0.40
403.1408081	0.48
405.2216187	7.99
406.3333740	22.98
407.3302612	59.33
408.1726685	1.21
409.2810669	1.02
410.2802124	0.43
411.5404663	1.52
412.3154907	0.65
413.1948853	13.80
414.2998657	7.82
415.1168823	4.64
415.7231445	2.73
421.2247925	0.31
423.1193848	2.03
424.3014526	14.37
425.2761230	14.20
426.0206909	1.70
432.7947388	2.00
436.0608521	3.10
436.8927002	0.39
447.1889648	1.25
449.2554932	6.20
450.4071045	6.22
451.2248535	37.60
452.4418335	2.12
453.1080933	0.55
455.6614380	0.23
456.2828369	0.27
465.1817627	0.61
466.3483276	0.81
467.4456787	1.67
468.1033325	0.16
469.2269287	1.67
471.3431396	0.44
478.0415039	2.16
478.7194824	0.64
482.3151245	6.63
482.9714966	10.09
484.3706665	0.97
487.9893188	0.44
491.4042969	72.78
492.5787354	1.07
493.2966309	0.38
496.4832153	0.32
499.2921143	0.96
500.3703003	57.64
501.3740234	2.30
513.4491577	0.29
514.4712524	0.18
515.1201172	0.69
516.9752808	0.79
521.1271973	0.49
526.1505737	0.29
530.6894531	0.85
531.5646362	4.65
532.6838989	3.36
533.4443359	1.81
540.1373901	1.02
549.2512817	2.36
550.2018433	0.47
557.2692261	2.84
558.0695190	1.25
559.2529297	22.82
560.4139404	3.62
561.0454712	0.63
576.3427124	1.74
577.1710815	7.85
578.3368530	1.51
586.3974609	0.69
587.4840698	1.45
588.3193970	0.52
598.9542847	0.25
601.3665771	2.53
618.1710815	0.23
619.3073120	5.59
633.4816284	0.43
651.1439819	2.14
652.2634888	0.25
661.3446655	0.25
662.4591675	0.84
669.3418579	1.98
682.8504028	0.19
684.2592163	1.30
687.4475708	0.56
688.5675049	0.38
693.3137817	12.08
694.3173218	0.84
695.3616333	3.86
696.3170166	5.71
700.7882690	1.37
701.4688721	5.68
702.3008423	0.51
703.4395142	0.38
706.4539185	0.16
711.5842896	2.91
712.2642212	1.34
713.3895874	1.21
714.2377319	2.26
721.3180542	1.70
735.4082642	0.27
737.1076050	2.33
738.4614868	3.99
739.3359375	10.71
740.1806030	2.81
741.4205322	0.27
743.3721313	0.42
754.3446045	0.19
769.1659546	0.31
779.4066162	0.70
787.8229370	1.50
795.0172729	1.14
814.1448364	0.31
821.3630981	1.80
822.2922974	0.51
831.3191528	0.38
832.4197388	0.73
838.9706421	0.22
845.7092285	0.55
849.2778931	1.05
850.1706543	0.46
857.6171265	6.75
858.3947754	1.26
863.2685547	63.41
864.2438965	19.93
865.2261353	14.73
866.3126831	2.83
875.4685669	2.18
876.1896362	1.49
907.1774902	2.24
907.9609375	1.28
939.2834473	0.29
958.3971558	1.30
965.4345093	0.33
983.2954712	1.05
984.3937988	0.69
985.2218628	0.92
1001.3899540	2.09
1002.0369260	1.69
1009.1824340	2.79
1027.2528080	24.08
1028.4825440	13.03
1029.3559570	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0476
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
192.9246979	0.14
210.9440460	2.64
241.0657959	1.80
258.7161865	0.06
262.0911255	0.02
273.0553589	0.42
280.0821533	1.27
290.7816162	0.05
303.0541382	0.06
305.0587158	0.45
321.1235352	1.29
323.1572266	100.00
385.1685181	3.80
394.8778687	0.20
396.7850342	0.25
403.0826416	2.80
467.1161499	0.12
478.7900391	0.62
480.8237915	1.44
522.1602173	0.08
547.2956543	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9670868	1.78
121.9109802	0.07
123.0545731	1.88
125.2161865	0.08
149.2466431	0.06
152.0050049	5.15
161.1928711	0.36
167.0273743	100.00
182.1982117	0.07
187.0223083	0.06
191.0994873	0.45
192.0697937	0.10
197.9886169	0.12
206.7244263	0.10
209.053772	0.72
210.9725342	0.07
213.2151794	0.12
221.1973267	0.12
223.0578003	0.14
227.0939026	0.08
233.0812073	0.34
235.0957336	0.32
235.921051	0.11
236.6409607	0.09
250.34198	0.06
254.2636719	0.24
255.1408081	0.06
265.4740295	0.10
268.2693481	0.11
272.1479492	0.30
282.3117065	0.14
283.1734619	1.22
285.0979614	0.72
286.04245	0.08
291.0980225	0.19
293.2244873	0.08
310.1362915	0.08
311.2246704	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1346
Annotation	Semperoside
Peak:m/z	Relative Intensity
108.969902	0.09
113.0819092	0.14
122.7984619	0.05
135.2574158	0.08
139.7889099	0.10
153.0084839	21.00
155.1173401	0.26
161.0184937	0.16
163.0292664	0.13
167.2242584	0.11
171.2330322	0.16
173.3661804	0.14
178.6828613	0.13
179.3182678	0.05
181.2316284	0.08
190.0656738	0.04
192.9867401	0.04
194.9125671	0.10
197.0779419	100.00
199.1585999	0.06
212.0934143	0.14
213.2057495	0.04
214.9515381	0.08
225.4300842	0.10
231.2894897	0.05
239.3005981	0.23
241.2298279	0.13
244.0098877	0.05
250.9717407	0.23
253.0399475	0.17
263.3098145	0.18
264.1289062	0.15
265.2996216	0.10
267.2092285	0.17
269.0682983	0.12
271.1401978	0.46
273.2944946	0.07
278.009613	0.12
283.0708008	0.15
291.1938782	0.17
296.2494507	0.08
299.1894531	0.65
303.223114	0.08
311.4824829	0.10
312.4094238	0.66
313.1955261	1.06
314.0491028	0.26
315.1007996	0.62
331.1481323	0.08
338.900177	0.44
341.1044617	1.73
341.7295227	0.13
344.3016968	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1827
Annotation	Scopolin
Peak:m/z	Relative Intensity
273.1471558	0.18
289.1286926	0.62
329.3676758	0.50
353.1795044	100.00
377.1932983	0.26
391.0191040	0.18
417.1748657	0.10
514.1516724	0.14
515.1362305	0.09
543.4005737	0.44
545.1853638	0.22
555.3684082	0.22
639.5453491	0.26
706.9478760	39.23
707.6870728	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0773
Annotation	Scopolin
Peak:m/z	Relative Intensity
138.0014954	0.08
159.1238708	0.54
183.9865417	0.13
209.1244507	0.09
216.2673645	0.15
219.0252686	0.44
249.1908875	0.32
260.3451843	0.12
262.8171692	0.05
273.1477051	0.16
274.8971252	0.29
281.0496216	0.05
289.1120300	100.00
291.1583252	0.48
299.1854858	0.22
304.1441650	0.14
307.0971985	0.09
316.3003540	0.18
317.3485718	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.2863
Annotation	Sedumoside F2
Peak:m/z	Relative Intensity
217.4177246	0.12
235.1964417	0.36
243.0578766	0.03
301.2727661	0.03
302.1961670	0.06
351.4397583	0.08
357.3125000	0.03
427.1679077	0.17
434.0084839	0.05
449.5334473	0.12
469.3800049	0.17
471.1502686	0.08
475.5209351	0.03
479.5862427	0.20
504.4743652	0.15
519.3798828	100.00
520.3724976	13.81
523.5826416	0.08
545.3680420	0.03
547.3558960	0.18
548.7329712	0.42
550.6325684	0.10
566.4462891	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1396
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
82.7304306	0.02
92.9141083	0.08
94.7924728	0.15
100.9819794	0.07
110.9337387	0.52
113.0680847	0.20
119.1602554	0.06
120.9236603	0.06
122.9771957	0.03
125.2854843	0.08
132.8793640	0.09
135.0580750	0.22
136.1576233	0.04
137.0797729	0.11
139.0614014	3.70
145.1502380	0.11
149.0440826	0.11
151.1589661	0.07
153.1553040	0.85
155.0907440	0.04
159.1636200	0.30
163.4779053	0.12
167.0162354	0.06
167.6555786	0.11
169.3486481	0.08
171.0853729	7.43
175.2743835	0.14
176.2055664	0.06
177.1734924	0.07
179.1397705	0.03
189.1380768	3.39
191.2252655	0.06
201.1000061	3.65
207.0903625	4.93
209.1184692	0.06
219.1283875	17.91
235.0235596	0.49
237.1144409	100.00
251.2973633	0.06
261.3115845	0.22
263.1637878	0.14
265.1274719	0.02
275.1271973	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2512
Annotation	Unknow
Peak:m/z	Relative Intensity
180.0969543	0.39
202.9188232	0.11
218.1351013	0.17
237.3218689	0.05
251.1301270	0.17
272.0501404	0.14
279.1112061	1.75
285.1619873	0.13
293.3489685	0.19
295.8451538	0.13
297.0032349	1.51
298.5886230	0.12
305.0388184	0.38
307.2214355	0.18
308.2479553	0.10
311.0535278	0.04
316.3665161	0.39
318.0922241	0.19
328.2159424	0.18
348.1577759	0.09
352.0997925	0.18
360.1797485	0.52
365.1468506	0.72
369.3599243	0.13
373.0011597	0.06
375.3723755	0.07
377.2355957	0.05
378.3198242	0.53
381.1882324	0.07
386.3201904	0.11
390.3852539	0.92
396.5863037	0.24
397.5697021	0.04
403.3781738	0.15
407.3639526	0.21
414.4596558	0.04
415.3623657	0.19
417.3830566	0.18
418.1959229	0.04
422.3932495	0.24
424.2381592	0.04
426.4866333	0.48
428.5050049	0.09
429.5475464	0.28
431.1643066	0.32
433.2521973	0.07
434.8541870	0.09
440.9670410	0.32
444.4288940	0.25
450.9841309	0.69
453.2766724	0.08
459.2960815	0.06
461.5535889	0.57
467.4205933	0.08
473.2534180	1.28
477.2041016	0.04
481.3835449	1.05
497.3452759	0.65
500.8269653	0.10
513.0388184	0.04
515.3631592	0.25
517.3082886	1.88
521.7531738	0.05
529.7184448	0.36
530.4564819	0.24
531.3556519	0.92
532.4630737	0.08
533.2746582	0.74
541.4064331	100.00
542.4385376	0.13
546.9378662	0.12
558.4719238	0.37
559.4691162	2.52
578.0357056	0.04
578.7247925	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.261
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
599.1917114	0.05
662.2174072	0.03
848.2806396	0.05
1110.1682130	0.03
1118.1218260	0.04
1137.1848140	0.02
1154.2448730	100.00
1155.3806150	6.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1376
Annotation	Jamesonin
Peak:m/z	Relative Intensity
81.01351166	1.72
86.82258606	0.31
94.90827942	4.19
98.90336609	5.15
108.9634628	1.82
113.0031738	3.58
116.8105469	0.91
124.0697937	2.13
127.1545944	0.62
130.9080811	1.10
134.995636	6.37
136.8088074	1.36
138.8841248	1.98
141.0483093	0.82
142.920578	2.93
145.0481262	0.97
147.3000183	2.89
149.0662231	0.99
151.3650055	1.92
152.1256256	1.17
153.0260468	1.46
158.0564575	1.96
159.2705688	1.13
160.9936981	1.43
165.1449127	1.76
166.9526062	2.85
168.1087952	2.15
168.9410095	0.99
171.1862183	4.81
175.0895233	2.91
177.0724182	0.91
179.3321075	1.77
183.4309998	0.54
184.9457245	0.79
187.3151245	3.35
191.0572205	17.68
192.0707397	1.38
193.2822571	0.91
197.2363281	4.21
200.078949	47.00
201.0871887	2.58
203.1047058	1.85
204.9243774	3.46
206.8798828	4.01
209.0152588	4.01
214.0924988	3.16
215.0858765	1.43
217.368927	2.43
218.9854126	3.51
219.5958557	6.31
221.1809082	11.30
221.8352356	1.30
222.8908997	4.38
225.1882019	5.48
227.1097107	1.75
228.567627	1.04
231.7239075	1.24
233.0502319	4.78
235.0380554	32.01
236.263855	3.33
237.1046143	4.28
238.2415771	1.58
239.9454346	2.64
245.1268311	27.36
249.2621155	1.30
251.0128479	2.79
253.1073303	6.11
254.8928223	0.60
257.1343689	2.97
261.8837891	1.37
263.1284485	100.00
264.2608032	2.04
266.2001343	5.44
272.1772461	20.79
276.1296692	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.09506226	0.19
105.1618042	0.57
105.8540649	0.13
109.0189972	0.16
112.95578	0.71
124.0245056	0.13
126.1069946	0.11
130.0504913	1.83
133.0066376	0.23
137.1730499	0.19
145.8783875	1.26
148.8927612	0.79
149.9790192	0.15
153.0311127	0.75
154.9801483	0.27
156.953598	0.17
161.0543518	0.62
162.0262299	0.62
163.0174713	0.24
163.9727478	0.28
164.9592896	0.44
165.8387604	0.76
169.0479279	0.58
173.0597687	0.31
174.9807281	0.66
177.1001434	0.15
177.9754944	0.79
179.0451965	1.48
179.8328705	0.55
181.2015839	0.57
183.0753937	0.97
184.9940338	0.43
191.3089142	0.83
191.97995	0.25
192.8750153	1.56
194.4016876	0.17
195.1500397	1.18
195.9317474	0.66
202.0081177	0.34
204.9890594	0.24
206.1846161	1.44
207.096405	11.64
208.0535736	12.07
209.180069	5.24
210.2324677	1.66
216.1518707	0.30
219.4364319	0.22
221.1067047	0.27
222.4399719	5.59
223.2008057	9.09
224.2335358	2.52
233.2559662	3.14
234.2987518	0.53
235.100769	0.64
236.3619995	0.16
237.1081085	0.53
251.0689697	100.00
252.1457672	29.77
252.9545441	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.0591
Annotation	alpha-D-Galactosyl-(1,1')-sn-glycerol 3-phosphate
Peak:m/z	Relative Intensity
96.8158569	0.24
141.1165924	0.06
150.8789520	0.90
152.8961487	100.00
170.9698181	3.30
223.2738647	0.10
241.0227051	99.47
247.1097717	0.27
259.0895691	2.20
286.9664307	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1926
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1746063	0.15
174.0767670	0.08
186.7741241	0.12
192.9468231	0.21
196.9364624	0.25
201.9045868	0.48
206.1848755	0.05
214.4303284	0.11
216.1780396	2.21
227.0546265	0.19
230.0733795	1.79
233.1689453	1.18
241.4710388	0.12
243.3267212	0.22
247.2173767	0.12
249.2549133	0.20
253.1713867	0.13
255.4289246	0.17
257.3077393	0.38
259.1692810	100.00
260.2280884	1.02
261.1903687	0.08
266.9601440	0.08
272.3872375	0.38
277.2537537	5.89
278.3746948	0.44
284.0940857	48.78
285.2412720	1.09
286.1331482	0.10
287.4272156	0.32
288.6832886	0.15
301.1277771	58.56
302.1973267	8.74
303.1801147	0.87
312.6849365	0.17
314.4931946	0.10
315.3955383	0.50
316.2674866	0.10
319.2579956	29.88
320.2647705	0.16
344.2163696	0.48
346.0731812	0.27
347.2735901	0.72
349.2979431	0.20
360.1467285	0.22
362.6592712	0.98
363.4776611	0.72
370.2290955	0.26
381.5270386	0.17
384.7408142	1.46
385.3691101	0.79
388.3405457	9.21
389.2099609	0.46
395.0907288	0.18
402.3899536	5.50
403.2338562	0.41
404.4277649	0.99
406.2753601	43.85
407.2635193	1.57
408.9500732	1.04
410.2831116	0.36
411.4846497	0.77
413.1616516	5.60
414.3666687	0.25
425.1611633	0.23
429.7080383	2.53
430.3158875	42.46
431.3056946	15.23
432.2489624	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.2003
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
108.8312759	0.15
112.8795471	0.12
118.9713821	2.59
121.0211029	1.15
122.9288330	1.59
125.2585602	0.23
126.7239838	0.66
131.0584412	0.96
132.8714600	0.19
134.9448395	3.78
136.8542175	0.41
145.0776978	0.73
147.0654907	3.86
149.0488129	14.36
151.1812744	0.93
153.0329895	0.07
155.5874634	0.36
156.9564667	0.16
161.0586243	8.20
162.9132080	2.98
165.0843201	1.74
171.0774536	0.64
174.2772217	0.09
178.8157349	0.73
187.2056580	0.16
189.1028748	12.52
191.1861267	0.46
205.0868378	0.13
207.1186218	100.00
208.9887390	0.37
215.3009644	0.08
220.2854614	0.13
223.1308899	0.14
224.8549805	29.46
225.5429993	0.76
228.1573486	0.32
233.2841187	0.38
234.9215698	2.54
246.9885559	1.42
249.0503540	1.57
251.0074158	0.31
253.2511902	0.27
266.9567871	0.14
269.8024597	0.19
291.0490417	0.77
297.6062012	0.20
305.1810608	0.11
314.9438171	0.22
317.7611084	0.18
323.0630798	0.15
332.1620178	0.09
333.6941223	0.63
342.0919189	0.09
344.1010437	0.17
350.9774780	1.44
359.1541748	0.20
360.2701111	0.10
365.1571960	0.55
366.1740112	0.27
367.1038513	1.71
368.1749573	10.31
369.0257874	27.97
369.9540100	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.2274
Annotation	Unknow
Peak:m/z	Relative Intensity
180.6997833	1.56
210.7345276	0.86
223.2832336	3.06
229.1274414	1.89
235.0488892	0.80
240.7380066	2.05
241.3810120	1.74
246.8441925	0.28
252.8356628	0.50
259.1343079	3.51
260.0444641	0.77
270.9901428	17.62
280.6119080	1.01
288.8162231	13.16
289.4636536	1.68
294.4813232	1.94
295.1461792	15.51
304.8059082	0.59
306.4800415	13.13
307.0975952	11.45
313.0423889	1.65
319.9230347	1.01
324.3436279	13.27
324.9765320	100.00
325.9818726	1.95
342.6920776	52.47
343.4144287	2.81
344.1246948	0.88
360.8287354	3.19
421.3887329	0.37
457.0507812	9.68
475.0095825	72.85
476.4611206	0.99
484.9835205	0.26
486.8391113	9.26
504.6126709	2.47
619.2478027	2.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1015
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9920731	1.33
149.1575623	0.35
160.8023987	0.25
162.0401306	0.15
179.0352173	2.71
179.8768463	0.92
181.1158752	0.96
220.7910767	0.47
222.2133179	0.96
242.1674194	0.59
259.1473083	1.57
277.5741577	0.19
288.1061401	0.44
320.2251587	0.15
343.1667175	100.00
362.0424194	0.13
379.9385071	1.04
421.8980408	0.98
423.3085022	3.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2621
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
696.2958984	0.13
845.3424072	0.18
847.4863281	0.30
983.6334229	0.07
1153.267578	100.00
1154.270386	66.43
1154.940918	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
107.0850372	0.04
113.0354767	0.08
118.8193130	0.04
142.8559113	0.09
159.0539856	0.02
161.0853271	0.21
175.8854675	0.02
178.9634247	1.34
197.0527344	0.27
215.0544128	6.09
341.1687622	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8052063	0.39
212.8558655	0.99
214.9689026	0.03
290.7868652	1.01
292.0318298	0.08
292.8622437	0.19
294.9614258	0.74
296.8198853	4.76
297.5123291	0.02
298.6792603	0.27
372.9251709	0.04
376.8254395	0.14
377.5400391	0.05
378.3223877	0.06
380.8106689	48.23
386.9736328	0.03
412.1455688	0.16
430.8725586	0.04
461.6259155	0.08
462.6660767	0.98
464.6535034	100.00
549.7153931	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2607
Annotation	Alangionoside O
Peak:m/z	Relative Intensity
175.9202423	0.07
179.0405426	0.03
211.1377869	0.03
213.1816711	0.03
215.1670532	0.13
217.1434326	0.02
220.8131409	0.03
223.2440491	0.02
231.2124176	0.10
241.2231140	0.16
254.8946533	0.01
257.1946106	0.06
259.2994690	0.06
260.4678345	0.02
263.3179321	0.02
283.6995544	0.04
287.1276855	0.09
289.1715698	0.18
294.2055664	0.05
299.4671021	0.07
301.0334473	0.02
302.2185059	0.01
315.3126221	0.02
321.3393555	0.06
327.2052002	0.05
350.2502441	0.04
361.2482910	0.02
367.2605591	0.05
375.3904419	1.22
376.3937988	0.24
377.1193237	0.04
378.1261597	0.08
385.1636353	0.34
386.4191895	0.21
387.2006836	0.03
388.7294312	0.01
392.2045288	0.01
403.3505249	5.02
404.3471069	0.89
405.4421997	0.01
407.3362427	0.07
413.1007080	0.04
415.1033936	0.01
421.3422852	4.07
422.4284668	0.96
424.1094360	0.02
431.5675659	0.06
438.3577271	0.03
439.0747070	0.01
447.1391602	0.03
451.2763062	0.03
453.6963501	0.02
454.3404541	0.02
461.5092163	0.03
464.5268555	0.05
466.5023193	0.02
474.4854126	0.02
479.3815918	0.03
488.0445557	0.02
516.2938232	0.14
520.3627319	0.04
537.3576050	100.00
538.3417358	10.67
539.0616455	0.10
547.2952271	0.18
548.4064331	0.13
563.0497437	0.01
565.5079346	5.78
566.5227051	1.19
584.1054077	0.08
591.3026733	0.04
592.3332520	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.13
Annotation	Dracunculifoside J
Peak:m/z	Relative Intensity
131.1918945	0.06
139.1134491	0.24
140.8839874	0.10
147.1588898	0.13
148.6044922	0.16
159.0121613	0.33
162.5837097	0.37
167.1024933	0.82
168.7243805	0.10
185.0668030	0.26
186.9029541	0.39
189.3376007	0.45
195.0888519	0.31
197.2236786	0.17
198.9665527	0.08
201.0916443	0.12
209.1124573	0.78
212.9514160	0.08
215.1121826	0.57
223.2678986	0.75
227.0315552	4.30
230.0570374	0.18
241.1119385	1.61
242.0963745	0.19
245.3467102	0.20
251.1642151	0.30
254.9347839	0.26
258.3197937	0.11
258.9815369	0.11
268.8468018	0.12
271.0419006	2.51
272.1306152	0.21
273.0158691	0.23
277.1593628	0.23
285.4231567	0.28
291.4861450	0.26
295.1267700	0.48
309.5392761	0.44
311.3692627	0.21
313.0378723	0.14
313.9635925	0.06
317.2825928	0.05
321.1088867	0.10
322.2627258	0.25
323.3471985	0.31
327.3176880	0.19
329.1937866	0.15
331.1547241	0.05
335.3352661	1.27
336.2162170	0.31
339.1018677	0.56
339.9710693	0.08
343.3880005	0.08
347.3588867	0.46
349.2359924	5.05
350.1624756	1.37
351.2080688	0.18
353.3428345	2.66
354.0460815	0.14
355.3805542	0.08
357.1111450	0.08
361.3260803	0.42
367.3424988	0.68
370.7099609	1.21
371.3913574	0.76
372.3644104	1.44
373.3261414	4.55
374.4955750	0.78
375.9002380	0.07
377.0606995	0.34
381.0158691	0.12
384.6757202	0.19
385.4324036	0.20
386.3788452	0.50
387.8080750	0.15
389.4126892	1.15
390.0326843	0.16
391.2829590	100.00
392.3291626	2.29
393.8229065	0.23
398.2004700	0.20
399.0630188	0.57
399.6795654	0.52
401.2852478	0.30
403.5704346	0.17
405.3873596	0.09
416.0520325	1.33
417.1825562	2.07
418.1182251	0.40
420.4951477	0.27
434.7250671	0.08
438.2326355	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1765
Annotation	[3R-(3alpha,3aalpha,4beta,5alpha,6aalpha)]-3-[(beta-D-Gulucopyranosyloxy)methyl]hexsahydro-4-(hydroxymethyl)-5-methyl-2H-cyclopenta[b]furan-2-one
Peak:m/z	Relative Intensity
112.7803268	0.15
118.9812393	0.57
141.2552795	0.14
143.0440979	0.26
147.0087891	0.19
154.9409180	0.13
158.7281189	0.07
161.0493469	1.20
167.0987854	0.12
177.1527405	0.08
179.0561523	0.21
185.0854034	100.00
187.1289673	0.09
194.8346863	0.03
197.2243195	0.16
199.0459442	0.30
205.2601013	0.04
207.0531769	3.36
209.4539948	0.03
211.0425262	0.14
211.9854736	0.13
213.2725372	0.12
227.2031555	1.84
229.2160645	0.04
230.5522461	0.10
231.2111206	0.16
239.2482910	0.82
245.3291016	0.05
257.0083923	0.75
267.3913879	0.20
276.2652893	0.03
279.1558533	0.08
283.2428894	0.25
285.2103271	0.14
287.1247864	0.24
301.2367554	0.24
303.1982117	0.06
317.3123779	0.06
320.5183716	0.06
329.2146606	0.31
331.0055542	0.15
340.6494141	0.08
343.1172791	0.21
345.1466675	0.10
346.9854736	16.38
347.9642334	0.21
349.1760254	0.13
350.5135498	0.08
357.1414795	0.22
374.2690125	0.37
375.2664795	1.53
376.3278809	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0903
Annotation	Glutathione
Peak:m/z	Relative Intensity
87.7873306	0.10
115.8917694	2.25
129.9138794	0.20
143.8946533	3.83
145.0217590	0.04
145.8331299	0.02
149.1135559	0.04
150.8518982	0.06
160.6705170	0.01
161.9890137	29.46
170.0372314	0.03
174.8281250	0.04
178.9353333	100.00
187.0176086	0.02
189.6126556	0.06
204.4778748	0.08
212.1010742	1.02
215.0084839	0.49
233.0332336	17.92
245.0432129	1.21
263.3941345	0.02
272.0663757	1.27
290.0684204	5.57
291.1365967	1.81
298.6984253	0.05
299.6384277	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	344.0986
Annotation	Unknow
Peak:m/z	Relative Intensity
100.9028168	0.39
113.1092529	0.48
118.8934479	0.28
127.0907898	0.10
130.0545959	0.12
136.0188599	100.00
143.0715790	0.05
149.0526428	0.26
160.2146912	0.23
161.0419006	0.37
179.0327148	1.13
180.0846863	0.37
181.1708984	1.55
181.8268738	1.00
182.4595337	0.19
183.1185455	0.09
198.0259552	0.08
207.0516357	6.75
207.9174652	0.34
257.2263794	0.15
260.2165527	0.14
266.2728882	0.18
280.1764832	0.57
297.9913940	82.04
298.7044983	0.44
300.1253662	0.12
302.3198853	0.14
308.4116821	0.10
326.1558838	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2081
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
206.9375610	0.46
255.3507080	0.15
265.2956543	0.08
269.1699219	0.38
283.1796875	0.71
309.0898438	0.18
311.2801514	0.59
313.8297119	0.37
314.4893188	0.86
315.2241211	0.49
316.4524536	0.12
325.1522827	0.31
326.1926270	5.13
327.1607666	0.33
328.1149292	0.70
329.2304077	98.71
339.3330688	0.05
341.2647095	100.00
356.9785767	0.08
358.1503296	1.47
359.0029907	14.54
386.9741821	0.16
405.4649048	0.11
443.3022461	0.28
475.4476929	0.16
483.4501953	0.15
507.2974243	1.53
519.7078857	0.75
520.8562622	7.85
521.5885010	0.03
522.5059204	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.2183
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9434967	0.08
136.0475006	0.19
137.1207428	0.08
143.1515198	0.81
144.9580383	0.08
149.0671234	1.89
150.0267029	0.52
153.0517273	0.09
159.1093140	0.12
161.0580139	1.48
161.9088135	0.32
167.0874939	3.35
168.1017456	0.62
171.1136780	0.04
178.9459229	6.32
179.9280090	0.09
195.1728210	0.22
203.3453979	0.05
206.1459961	0.13
207.4733734	0.16
208.9517059	0.05
217.1985168	0.06
225.0609283	3.77
226.0751648	0.19
227.2031250	0.16
230.9535217	0.05
233.3733521	0.04
243.1660156	2.56
244.1836548	0.48
245.1100159	1.19
246.1377258	0.17
253.2612915	0.17
271.2088928	0.80
272.3081360	0.09
284.5557861	0.08
289.1686401	8.51
290.2954712	2.69
295.2487488	0.04
299.3743286	0.28
300.2638245	0.29
302.3470459	0.04
313.0736694	0.10
323.0258179	0.08
325.1933594	0.39
326.1517029	0.10
327.2457886	0.38
328.3033752	0.13
330.9361877	0.09
337.2758179	0.21
341.1979370	0.08
342.2911377	0.09
347.2909546	0.12
352.1515198	0.15
355.3568115	0.09
361.7098999	0.10
365.2349243	0.03
380.9836731	0.22
384.0493469	0.04
389.2706299	0.07
390.9431763	0.11
392.1009521	0.24
405.1784363	100.00
406.2936707	20.16
407.3338928	0.45
408.2294006	0.08
410.1676636	0.06
421.6666565	0.36
433.3057251	0.32
434.1006775	0.12
435.5050964	0.54
451.9510193	0.11
453.2063599	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
656.5426636	9.28
800.1835327	53.46
918.2870483	46.34
921.1032104	29.44
966.7103882	33.67
967.420166	100.00
968.1766968	6.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.1956
Annotation	Isopentenyladenine-9-N-glucoside
Peak:m/z	Relative Intensity
103.1494751	0.38
105.7291870	0.18
107.1315002	0.19
120.9309464	9.42
126.1241302	0.15
133.0439148	0.76
148.9788971	32.45
155.0591736	0.42
162.0796204	0.17
167.0325928	100.00
180.1128082	1.42
184.0176086	3.88
184.7635651	0.33
186.9270935	0.53
202.0354614	2.20
206.9261017	0.36
242.7935181	0.51
256.6802979	0.21
268.2283325	0.74
268.8969116	0.46
272.0293579	1.12
275.3150330	0.49
283.1068726	0.91
284.0091858	0.13
310.1646118	0.34
310.9371948	0.82
314.1231079	0.31
318.0580444	0.39
320.6107788	0.30
326.4368591	0.51
328.1311035	9.93
328.8226624	6.93
329.4428101	0.21
345.8633118	1.21
347.1506653	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.1401
Annotation	Unknow
Peak:m/z	Relative Intensity
172.9830017	1.07
186.9734497	0.71
189.9821777	0.47
229.1565552	0.49
246.7367859	0.85
264.5247192	1.04
276.7860107	1.48
279.9196777	10.88
287.9715881	1.08
289.1103516	32.68
290.0682373	0.51
300.8014221	0.44
306.5222168	0.76
323.6783447	1.67
325.0567627	1.78
336.8031616	2.46
354.9547729	5.17
370.0516968	97.32
370.7065430	3.00
371.8349609	1.53
396.9946899	9.97
414.8535156	0.23
456.1862793	0.46
456.8159180	3.54
460.0673828	0.72
486.1079102	0.27
487.0546875	5.12
516.5685425	4.86
517.2330933	7.23
557.1404419	1.27
558.7114868	3.57
559.4358521	0.84
574.6101685	0.58
575.9910889	2.35
576.9954834	23.69
648.8500977	0.18
737.1531372	1.81
739.1977539	100.00
740.1954956	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.13
Annotation	gamma-CEHC
Peak:m/z	Relative Intensity
93.05230713	0.24
98.8782959	0.20
107.1329041	0.21
109.1299744	0.58
111.0341949	0.49
112.8262787	0.09
119.0597076	0.14
120.418396	0.17
121.056076	0.45
123.0772705	0.08
123.8663788	0.12
125.015564	0.60
126.9896088	0.09
135.2667999	0.21
136.0890198	0.33
137.134079	1.12
138.1889801	0.60
139.0395203	0.38
147.2056274	0.42
147.9851532	0.92
149.6832123	0.31
150.649826	0.39
152.0422363	4.75
153.0509796	2.65
160.9637146	1.55
162.807251	2.15
170.9741364	0.07
172.9363556	0.89
175.0470581	0.64
176.2195282	0.68
177.1363831	0.32
183.2010651	0.17
185.1808014	0.18
186.2299652	1.43
189.2036591	0.41
189.9998474	0.24
190.9637604	0.44
201.1034393	30.70
203.1367188	1.20
204.0946655	28.61
205.1211243	0.68
215.8998871	0.25
216.9929199	1.36
219.1395264	100.00
219.8246002	0.22
230.3018341	0.13
234.9456177	0.54
243.0891571	0.46
245.1640625	15.48
248.1166534	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1346
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.7818298	0.14
164.9344940	0.21
176.8387604	0.34
179.1985931	0.07
182.0736847	0.05
183.2821350	0.05
184.1010132	0.08
184.9847107	0.10
187.2097168	0.23
187.9751282	0.11
199.2328949	0.05
200.9113770	0.24
203.0522003	0.94
205.0512390	0.61
210.1112671	0.06
214.9802856	0.04
217.2123108	0.06
221.0291138	0.10
225.1402893	0.06
225.8539276	0.07
227.0437317	0.07
229.2311707	0.23
243.1923218	0.40
245.1365967	4.92
250.7691650	0.07
255.0742188	0.58
257.0948792	0.18
261.0068054	0.09
269.0488281	1.11
271.2410278	0.24
273.1198120	3.01
278.9874878	0.13
281.0170898	0.47
283.1096191	0.09
283.9649963	0.51
285.1580811	0.42
287.1615601	6.03
289.1873779	31.40
290.4047852	0.17
291.0524597	0.07
297.2295837	0.48
299.2005615	8.31
301.0281982	0.20
313.3458557	0.05
315.2105713	0.38
324.3636475	0.27
329.0528564	0.25
331.1621094	0.78
339.1073608	0.62
341.0060425	0.41
357.3305664	0.68
371.2025757	0.07
381.2876587	2.91
383.4002075	0.06
389.3452148	0.44
405.1780396	0.55
406.0468750	0.07
407.2741089	100.00
408.3546143	0.17
409.1530151	0.13
410.0406494	0.26
411.3801270	0.32
418.3590698	0.03
423.3613281	1.26
425.2471924	93.22
433.2301025	1.71
436.0341797	0.10
437.2073364	0.33
449.2644653	2.53
451.1986694	28.61
452.2210083	0.11
467.3165283	1.53
472.9581299	0.23
483.3566284	0.41
491.1867676	0.92
492.0275269	0.95
493.4506836	0.60
515.3562622	0.27
517.3716431	0.12
519.3628540	0.05
533.2646484	1.36
541.1460571	0.68
559.3055420	12.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1198
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
142.9045105	0.11
160.9548950	0.14
172.9337616	0.10
179.0433655	2.62
187.1731415	0.10
202.7236633	0.12
245.2122498	0.47
276.0811462	0.04
293.0953674	0.04
295.0571899	0.32
305.0859070	0.23
341.1746216	100.00
342.4368896	0.06
365.3383484	0.18
410.1727600	0.27
411.2905273	0.27
439.0466614	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1037
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
143.0084839	0.02
147.7978821	0.01
149.0572357	0.30
150.0630493	0.06
154.9015503	0.09
161.0065308	0.31
164.9870758	0.01
167.1066437	0.11
169.0260315	0.07
170.8678131	0.04
171.7870026	0.05
173.9843445	0.02
175.0874329	0.24
175.8948517	0.01
177.0863647	0.04
179.9757385	0.02
184.9454041	0.02
193.1719055	0.06
195.0727692	0.03
196.0591125	0.01
197.1990967	0.25
198.9700165	1.82
200.0610352	0.33
201.0734100	0.22
202.1697998	0.03
204.3360901	0.01
211.1944580	0.02
213.1510162	0.36
214.2521667	0.03
215.2014008	0.11
217.0451355	0.82
218.3126984	0.12
219.1199493	0.01
223.0729828	0.38
224.1282654	0.08
226.2353210	0.14
227.1291351	0.01
241.1146698	17.50
242.1250000	2.74
243.1756592	0.92
244.2362671	0.15
249.3826599	0.02
255.2959290	0.01
257.1361084	0.16
259.5169067	0.02
265.3732605	0.01
267.0956726	0.56
268.0744629	0.04
275.3451843	0.02
285.0636902	100.00
286.0836182	13.14
303.1622925	1.48
304.3133240	0.21
315.3370972	0.01
329.2284546	0.57
330.2957458	0.04
339.1365967	6.74
340.1499023	0.93
355.2289734	0.79
356.2005310	0.08
358.2516174	0.01
378.2326355	0.01
381.2230530	0.01
382.1455994	0.01
383.4847107	0.01
397.3307495	0.12
408.2169800	0.03
418.2832031	0.01
419.2720337	0.11
421.2027893	0.39
422.2851868	0.02
447.1885681	0.00
448.5045471	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
130.2114868	0.13
142.1225586	0.08
145.003067	0.13
172.8327637	0.04
180.3708496	0.13
182.1728516	0.05
190.9874268	0.08
195.0905457	0.06
200.359024	0.05
204.0841675	0.10
204.9628601	0.04
210.8002777	0.08
212.9896545	0.09
217.2928772	0.03
219.02742	0.15
221.0661469	0.11
223.0331726	0.05
224.14505	0.05
241.0267639	0.14
248.8374023	0.08
255.2594299	0.06
259.1213684	0.09
269.1404114	0.06
273.2226868	0.15
285.0440369	0.03
287.0628967	100.00
288.0700684	0.03
297.1556396	0.36
300.4468384	0.06
310.9706116	0.06
314.0095215	0.13
316.1921387	0.23
318.1838989	0.40
322.8374329	0.05
324.2141113	0.09
328.4350281	0.11
337.2662964	0.17
339.1807251	0.04
341.0682983	0.14
345.2538757	0.13
349.1410522	0.05
353.9336853	0.05
360.0009766	0.05
367.2136841	0.55
368.2033386	0.09
371.3656921	0.11
383.4817505	0.10
384.4182129	0.39
385.3578796	0.04
389.5672302	0.12
395.3477478	0.08
401.465271	0.11
403.1512756	0.51
405.1106262	0.07
407.1446838	0.09
413.0075073	0.84
416.9445801	0.09
417.6423645	0.06
419.1409607	0.33
422.3278198	0.17
426.1325378	0.08
428.3807373	0.06
430.0931091	0.45
431.179718	1.44
432.3120422	0.14
439.2480774	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.985527	0.04
110.7907104	0.09
113.1801605	0.03
126.9360504	0.40
133.1271362	0.10
134.9317627	7.87
137.0567627	0.02
155.0349731	0.15
161.0273743	0.78
171.0265503	0.11
173.0006561	2.52
179.0501556	43.05
188.978775	0.02
191.0337677	100.00
335.2159424	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.1187
Annotation	Amotin
Peak:m/z	Relative Intensity
108.996994	0.21
110.9918289	0.27
112.9370422	0.99
115.1730347	0.04
122.0207825	0.20
123.0795288	0.13
132.9729767	0.18
135.1049194	0.13
137.0950623	1.67
139.0217896	0.33
147.2236938	0.07
148.9494934	0.35
150.8472595	0.06
153.0890656	0.17
154.920929	0.26
158.9809875	0.21
161.0923767	0.05
163.0548401	0.68
164.9472809	0.54
166.8918457	0.29
171.0765228	1.44
173.1143188	0.08
179.0964355	0.11
181.1260223	0.62
181.9267578	0.18
182.8759918	0.09
187.541748	0.06
189.1425781	22.15
195.1847229	0.04
199.1309814	0.09
201.1617737	0.10
203.0693359	0.11
205.2146606	0.29
207.1046143	2.50
209.131012	0.07
211.176178	0.16
213.0884399	0.10
215.2139282	0.08
220.2767944	0.28
221.3065491	0.16
231.0149536	0.49
233.193634	0.99
234.3924561	0.04
235.1638794	0.04
237.0128479	0.17
249.0518188	3.64
251.127594	100.00
267.2392578	0.23
268.8733521	0.07
277.0666504	0.68
280.2605591	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
118.9654388	0.02
143.1819153	0.08
178.1286621	0.04
179.0554810	0.24
189.2920837	0.04
341.2544556	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.088
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
151.0413361	0.88
160.9412842	0.01
169.0933990	0.10
170.9161682	0.03
175.2280731	0.02
178.9881287	1.80
185.1078491	0.05
188.2036438	0.07
188.9085693	0.02
190.0686798	0.03
191.0556335	0.06
192.3116760	0.02
193.0473328	0.16
196.9165344	0.11
198.2054749	0.02
203.0332336	0.16
206.9181061	0.03
211.0127563	0.10
213.1691284	0.08
215.2575684	0.08
216.9541016	0.19
218.1843872	0.03
225.0554657	0.04
227.0647888	0.08
229.1181641	0.11
231.0264587	0.02
233.1743622	0.07
236.0863037	0.02
239.2877502	0.07
242.1798401	0.18
243.0276184	0.05
245.3640747	0.10
247.0327759	0.05
255.1712341	0.58
255.9386292	0.04
257.2550354	0.03
266.3523254	0.02
271.1540222	0.37
272.1932068	0.10
273.0007019	0.69
281.0472717	0.16
282.2702332	0.08
283.1897888	0.11
287.1401367	0.07
291.2093811	0.01
297.2601318	0.10
300.0894775	31.44
301.0650635	100.00
301.9797668	0.33
311.1126709	0.02
312.1736145	0.02
313.1236877	0.06
319.1923218	0.39
324.9472961	0.31
327.3160400	0.04
331.1365967	0.07
337.3027649	0.09
341.3712769	0.11
343.1312256	2.99
343.9530029	0.03
345.2793884	0.02
353.2999573	0.08
354.2757874	0.02
367.1232910	0.10
373.1303406	0.12
397.4501343	0.01
399.3224182	0.17
400.6015625	0.07
401.8706665	0.02
403.2455139	0.12
414.9776917	0.07
416.1926270	0.24
417.1699829	0.56
435.1223755	0.04
443.3243103	0.11
445.1647034	0.38
464.3169556	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.4325
Annotation	Trungapeptin B
Peak:m/z	Relative Intensity
207.3660126	3.76
253.2806396	2.28
279.230896	2.45
281.2373657	1.48
299.29776	3.31
379.4741821	1.42
425.6834717	1.16
443.3430176	7.45
459.4932861	1.58
461.3476562	3.03
469.7787476	0.86
528.8136597	2.84
623.3817749	4.04
669.4712524	1.18
684.1595459	2.09
690.6636353	0.79
703.453064	1.50
705.4452515	0.81
723.4402466	100.00
724.2887573	1.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2996
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
94.9708862	0.59
97.0253448	0.13
98.8754044	0.23
107.0257874	0.29
109.0538101	0.46
110.6518021	0.14
121.0899429	0.06
123.0366669	0.77
124.2108765	0.09
124.9931564	0.07
126.8775253	0.04
133.1177368	0.08
136.9730835	0.30
139.3242035	0.07
140.8341370	0.17
141.9037781	0.07
142.7876740	0.10
146.9068909	0.09
148.8312683	0.09
150.9026794	0.23
156.8637695	0.13
163.2448120	0.06
165.1063538	0.67
169.0481720	0.17
173.8614044	0.02
177.7992859	0.07
181.0923615	0.03
183.1166229	0.09
185.0088196	0.05
185.7992859	0.10
189.8463898	0.05
192.1338806	0.05
192.9884491	0.03
197.1084290	0.10
199.1390991	0.03
201.1005096	0.05
207.0315857	0.14
208.1079712	0.03
211.0047607	0.38
220.2528381	0.05
221.7358398	0.02
223.4343872	0.03
225.4102783	0.09
226.1269531	0.03
227.1795349	0.04
229.2273560	0.16
236.2766418	0.32
238.9203796	0.17
240.0739746	0.21
241.2514954	0.06
242.1254272	0.10
243.0935364	0.03
247.1755371	0.09
251.1764526	0.10
252.2944946	0.69
254.1997070	0.15
256.3701172	0.20
257.6537170	0.14
258.3712769	0.16
259.1713562	0.09
261.1649780	0.31
262.2088318	0.09
264.2832031	1.93
265.1526184	3.19
265.8557129	0.06
267.0898743	0.07
267.8526611	0.03
268.7557983	0.07
270.3097534	2.60
274.9655151	0.04
277.1311646	0.13
282.3525391	47.38
283.2154541	0.41
287.0962830	0.11
290.1537781	0.22
291.2638245	0.06
300.3144226	100.00
301.1758118	0.13
309.9264526	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	466.3005
Annotation	Euodionoside E
Peak:m/z	Relative Intensity
131.0971222	0.99
132.9689331	0.30
135.0888977	1.49
139.1088257	0.19
141.2252197	0.16
145.0782928	2.33
147.1195984	0.57
149.0292511	1.68
150.9731750	1.77
152.9785156	0.55
155.1417999	0.12
159.0881500	0.63
161.1903992	0.17
163.1113281	4.67
165.1348267	1.00
166.9985046	0.70
169.2911987	0.15
174.9895020	0.39
177.1828156	9.53
179.1144104	0.58
180.9330597	0.10
184.0453186	0.12
185.1304932	0.09
187.1534424	14.11
205.1338043	16.76
223.0848999	36.56
224.1185303	0.15
227.4263306	0.53
232.6955872	0.14
239.3510437	0.10
241.0858765	65.11
242.8838806	0.24
255.4804688	0.33
257.2541199	0.74
258.9414368	100.00
267.2155457	0.67
281.2946167	0.32
283.2420349	0.35
286.3916321	0.38
290.4956360	0.17
291.3403625	0.07
297.5285645	0.19
303.0032959	1.29
304.0919189	1.16
307.5845947	0.25
322.7536011	0.24
333.9683228	0.51
351.5462341	0.23
354.2660828	0.21
362.8638611	0.24
384.7020569	0.49
388.2002258	0.30
399.1932678	0.47
405.8020630	0.16
410.2781067	0.19
412.0633240	0.31
420.3666687	0.77
427.9805298	1.15
430.3525085	0.98
431.3625183	0.72
443.0339966	0.19
446.1528015	14.01
447.3023987	0.27
448.3950806	2.50
449.3208923	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	902.4902
Annotation	Unknow
Peak:m/z	Relative Intensity
266.4831543	0.36
268.2801208	0.29
285.2634583	0.10
294.2807617	0.70
295.2349854	0.67
312.1263428	0.39
327.1372681	0.07
338.4628296	0.15
339.2353210	0.47
364.2354736	0.08
365.3912354	1.78
366.1437073	0.40
377.3217773	0.26
378.4353638	0.14
380.2582397	0.16
381.9028320	0.14
385.3273315	0.25
394.4167480	0.22
397.3238525	0.59
398.3223877	0.81
400.2570496	0.47
407.2485962	0.17
411.6197510	0.10
422.2673950	0.37
431.3563843	0.14
437.9389648	0.17
442.1212769	0.37
443.9726562	0.38
449.5813599	0.48
451.3638916	0.08
453.3487549	0.18
456.1944580	0.08
459.5935059	0.37
466.4801636	0.74
467.2965088	0.28
468.3900146	0.51
478.4245605	0.06
479.2747803	1.36
480.4288330	0.24
483.7648315	0.17
487.4342041	0.14
493.5502319	0.43
498.3115234	0.16
499.2282104	0.31
511.0749512	0.26
514.1000366	0.11
517.5452271	0.20
520.7432251	0.17
531.3001099	0.70
532.5152588	0.39
533.2845459	0.14
535.8916016	0.56
537.0725098	0.56
541.4338989	0.75
547.9187012	0.18
549.1015625	0.12
550.3861084	2.63
551.6208496	0.26
559.4328003	0.20
563.1433105	0.13
566.3003540	0.06
568.3103027	0.12
569.8239136	0.08
577.4635620	0.82
592.5233154	0.07
593.7794189	1.18
607.2639771	0.15
608.4222412	0.62
609.5153198	0.30
611.2202148	0.25
613.5337524	0.52
615.4951782	0.24
616.3051147	0.18
620.0186768	0.16
620.7334595	0.10
623.5551147	0.21
627.2666626	0.31
628.5170288	0.30
634.9826050	0.53
636.3394165	0.94
645.3229370	0.35
651.2500610	0.38
654.0219116	0.15
656.4115601	0.48
659.7338257	0.10
663.5322876	0.67
664.4788208	0.43
675.4627075	0.37
679.3423462	0.10
684.1502075	1.20
685.2492676	1.07
686.0939331	0.78
686.8614502	0.09
691.3449097	1.50
692.4485474	0.09
693.4458008	0.27
694.0570679	0.25
695.0459595	1.03
696.6511230	0.60
700.2573853	1.62
700.9574585	0.28
706.0859985	0.35
708.2622070	0.20
708.9865723	0.41
710.5336304	0.12
714.4589844	0.62
719.4060669	0.35
720.7679443	0.56
722.2331543	0.37
725.7380371	0.68
726.9536133	0.95
729.4275513	0.16
730.4736938	2.50
734.5902100	0.23
735.3477173	0.51
736.3384399	0.72
738.2098999	1.10
739.6005249	1.29
740.9976807	3.63
742.2322998	0.32
746.4693604	1.05
747.7531738	0.52
749.0417480	2.13
751.9045410	0.29
752.5300903	0.46
754.9978638	0.55
756.2612915	0.86
757.2783203	1.52
758.2208252	1.30
759.6674805	0.67
760.5995483	0.69
761.7347412	2.48
762.7500610	1.01
764.5088501	1.56
765.3519897	0.67
766.0582886	0.80
767.3545532	1.49
768.0145874	2.29
773.6553345	0.64
774.4575806	2.25
777.0238647	0.78
782.4520874	0.39
786.0491333	1.35
787.1809082	1.21
788.3970337	0.37
790.7832642	0.28
791.6141968	0.20
792.3807373	0.91
793.6576538	0.95
796.0766602	2.30
796.9133301	0.62
797.6755371	2.85
800.0800171	0.25
803.3764648	0.16
803.9815063	1.99
804.6630859	1.53
805.7192993	0.49
806.6588745	0.37
808.4502563	0.27
809.1756592	0.37
811.7659912	0.37
814.0120239	1.58
814.6176147	0.89
815.4734497	0.28
816.2744751	1.12
817.5698242	1.83
818.3678589	3.44
820.2966919	0.78
821.9954224	0.88
823.3245850	1.86
824.0460815	1.58
824.8154907	0.40
825.7603149	0.96
826.6463013	1.36
828.1188354	0.22
829.7239990	10.85
830.4931641	1.43
831.4996948	0.50
833.0302124	0.43
833.9370728	1.43
835.5565796	16.61
836.5382690	2.00
837.5016479	0.93
838.3001709	0.56
839.4937134	0.83
840.2243042	0.14
841.1494751	1.37
842.2106934	1.78
843.2323608	2.47
843.8546753	0.40
847.3608398	1.11
848.3924561	0.68
849.6418457	1.70
850.7688599	1.14
851.5474854	1.26
853.1087646	0.55
854.3267212	0.91
855.3278198	0.77
857.1158447	0.18
858.9046021	1.88
859.5569458	1.90
860.3999634	3.03
861.7229004	0.57
863.1299438	6.68
863.9827881	1.53
864.8441772	0.69
865.8656006	1.66
866.6161499	0.45
869.1251831	0.22
870.7450562	0.49
871.4848633	1.74
874.5507812	0.15
877.6683350	0.71
878.5272217	0.41
879.2207642	0.76
879.8521118	0.94
882.6255493	3.37
883.4608154	0.51
884.2210693	0.78
885.1779175	1.01
885.8076782	0.78
887.7654419	0.51
888.7202759	0.44
889.9563599	2.78
890.8045654	3.56
891.9700317	0.20
904.0052490	10.01
911.9238892	0.20
916.0836792	1.19
918.7163086	0.13
920.7887573	1.28
921.9810181	0.12
923.3389282	0.77
930.2396851	0.07
931.6469727	0.27
935.4944458	0.37
936.4434204	0.06
938.9731445	2.90
939.9799194	1.42
940.9290161	1.97
941.7788696	0.39
945.8676147	1.04
946.5950317	0.44
947.2051392	0.38
953.6948242	0.30
956.1867676	0.85
957.8310547	0.87
959.9580078	0.27
968.9460449	0.81
970.6732788	0.35
972.1635742	2.86
973.2483521	1.24
974.6416016	1.23
975.4495239	0.76
976.7894897	0.35
977.7454224	0.59
986.6398315	0.19
987.6038208	1.08
992.8074341	0.42
995.9225464	0.20
997.1835938	1.80
997.9040527	0.69
1001.7743530	1.00
1002.6310420	0.12
1004.2072750	1.31
1004.9836430	0.28
1005.8851930	0.41
1007.0641480	0.16
1009.0805660	0.72
1013.5048830	1.05
1014.5921020	1.08
1015.6641240	0.30
1018.2838750	0.17
1018.9924320	0.39
1020.2563480	0.55
1022.9641110	1.28
1025.5266110	0.21
1026.7771000	0.35
1027.8322750	0.22
1029.6229250	0.84
1031.2669680	2.65
1032.2869870	1.67
1033.4512940	0.88
1035.5948490	0.53
1037.0498050	0.12
1041.3635250	1.31
1042.3267820	0.96
1044.7922360	1.40
1045.7166750	0.08
1046.8444820	0.83
1047.6613770	0.32
1049.2950440	0.52
1050.5504150	0.74
1052.8637700	3.92
1053.6215820	2.99
1054.4815670	1.39
1056.9876710	0.16
1058.4003910	0.73
1059.0693360	0.66
1061.7155760	0.53
1065.8836670	0.87
1068.3498540	0.52
1069.9641110	1.01
1070.8022460	0.80
1071.8413090	0.25
1073.3698730	0.83
1074.2993160	0.34
1075.4216310	1.94
1079.0703120	2.31
1079.8159180	0.92
1080.5878910	1.82
1081.4377440	0.46
1082.2128910	0.75
1083.3664550	0.19
1086.7025150	0.60
1088.1279300	0.59
1089.3088380	0.60
1090.2525630	1.13
1090.9639890	0.32
1092.2351070	0.97
1094.2681880	5.36
1095.1867680	0.68
1096.0021970	0.61
1097.9069820	1.68
1098.6823730	1.20
1101.4622800	0.53
1103.2606200	2.76
1104.0797120	1.09
1106.0483400	1.49
1106.9183350	1.71
1108.0031740	1.23
1111.8474120	1.02
1114.6279300	3.31
1115.5249020	1.13
1117.3195800	0.49
1122.8902590	0.82
1123.7082520	0.80
1124.8762210	0.39
1126.9641110	0.52
1128.8356930	0.65
1129.8422850	0.54
1130.6296390	0.25
1131.6816410	0.86
1132.4439700	0.54
1133.4362790	0.39
1134.0957030	0.51
1134.8415530	0.46
1136.4381100	1.37
1137.9553220	1.34
1138.9960940	3.06
1139.9672850	0.77
1141.6119380	1.30
1142.2227780	0.28
1142.9943850	0.47
1143.7647710	0.24
1144.8154300	0.26
1145.7609860	1.46
1147.1367190	1.63
1150.8376460	6.35
1151.8874510	1.88
1152.6263430	0.47
1154.2354740	5.76
1155.0581050	4.97
1155.9978030	1.86
1156.6386720	0.48
1157.3138430	0.15
1159.0517580	1.45
1159.8259280	9.85
1160.8486330	5.29
1162.1804200	0.37
1164.1517330	0.25
1167.8990480	0.26
1169.8208010	0.34
1171.7613530	1.71
1172.4509280	1.59
1173.4943850	2.00
1174.8895260	0.49
1177.1958010	0.13
1178.4470210	1.47
1179.8511960	1.50
1180.5559080	1.51
1182.8510740	0.24
1186.5034180	1.71
1187.3579100	1.20
1188.5383300	6.13
1189.5046390	0.80
1190.1047360	0.30
1191.4814450	0.32
1193.6820070	1.03
1195.0324710	0.74
1196.1193850	5.94
1196.8679200	0.39
1198.1959230	0.77
1198.8406980	0.58
1201.1982420	0.50
1201.8901370	0.68
1202.9809570	1.50
1203.7729490	2.54
1205.1748050	5.42
1205.9744870	0.46
1206.9526370	3.72
1207.7851560	2.81
1208.5312500	1.14
1210.1801760	0.18
1212.4967040	0.84
1214.2945560	0.20
1217.6867680	0.43
1221.3228760	1.17
1222.8471680	0.62
1224.3337400	1.04
1225.3577880	0.30
1227.9490970	0.46
1228.8131100	0.51
1229.9910890	0.72
1230.7233890	1.18
1233.9309080	1.02
1234.7062990	1.15
1235.3448490	2.91
1238.4274900	1.85
1239.9763180	0.80
1243.5395510	17.23
1244.5375980	8.55
1245.4473880	0.93
1246.1772460	0.86
1246.8100590	2.95
1248.3344730	1.19
1252.5755620	100.00
1253.4874270	32.08
1254.3103030	2.96
1255.7482910	0.33
1257.6943360	0.12
1259.3455810	0.41
1261.2967530	13.72
1261.9002690	7.26
1262.6220700	8.76
1264.1787110	0.60
1266.5902100	0.42
1268.8793950	0.10
1280.0941160	0.52
1281.2139890	3.07
1281.9798580	0.57
1289.7672120	6.04
1290.5909420	4.82
1291.4649660	1.90
1292.4259030	0.14
1293.5281980	0.12
1294.8216550	0.52
1297.9598390	0.45
1302.9129640	0.31
1304.2290040	0.32
1306.4208980	0.42
1309.8870850	1.18
1311.1589360	0.22
1312.8533940	0.33
1332.9335940	0.23
1340.9381100	0.23
1341.8881840	0.24
1342.9495850	0.56
1357.1666260	0.29
1367.0396730	0.09
1369.8281250	0.34
1382.1630860	0.09
1382.9470210	0.43
1390.9256590	0.44
1398.8570560	0.19
1400.1193850	0.18
1408.1346440	0.39
1412.9151610	0.20
1425.7570800	0.10
1432.1252440	0.35
1438.1473390	0.36
1466.2569580	0.41
1479.7568360	0.43
1481.2916260	0.24
1494.3995360	0.82
1499.0028080	0.20
1511.7186280	0.32
1513.9970700	0.05
1554.2655030	0.09
1555.0504150	0.18
1570.0899660	0.36
1580.8275150	0.23
1596.1978760	0.08
1599.5106200	0.16
1617.1444090	0.55
1631.1965330	0.08
1652.0310060	0.56
1663.1527100	0.12
1677.3052980	0.49
1680.0255130	0.06
1691.9180910	0.46
1699.0548100	0.27
1714.9744870	0.22
1725.1627200	0.30
1734.2375490	0.09
1739.3018800	0.29
1740.2476810	0.43
1742.4875490	0.32
1761.1968990	0.45
1763.9437260	0.43
1772.1359860	0.28
1773.9367680	0.30
1781.3551030	0.28
1790.3018800	0.18
1794.0889890	0.37
1800.7159420	0.11
1801.6861570	4.72
1810.7513430	0.19
1814.9724120	0.10
1827.1451420	0.42
1840.3996580	19.05
1861.1193850	3.59
1873.0992430	0.07
1877.6312260	0.05
1878.5941160	0.16
1885.2647710	0.08
1910.4879150	0.67
1912.7271730	0.25
1915.8900150	1.03
1917.2957760	0.25
1926.4864500	0.22
1937.4686280	0.31
1941.2316890	0.08
1950.1768800	2.83
1951.1951900	0.08
1952.3045650	1.21
1958.1453860	40.96
1959.5477290	0.16
1961.1868900	0.33
1967.9953610	0.36
1976.4703370	0.45
1985.0101320	0.21
1989.7166750	0.91
1994.1934810	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	492.1913
Annotation	D-Galactopyranosyl-(1->3)-D-galactopyranosyl-(1->3)-L-arabinose
Peak:m/z	Relative Intensity
147.9359131	100.00
149.0970764	1.66
150.1180420	0.59
164.9664917	1.16
179.0320129	0.86
183.0619354	12.57
242.4467773	0.37
260.0534973	0.06
287.2683716	0.21
296.4869385	0.63
303.1693115	0.68
310.1414795	0.29
328.9091797	0.14
329.8343201	0.53
338.9691162	0.20
340.4396362	0.27
341.1450195	0.27
344.9782104	3.43
359.1245117	0.31
360.4285278	0.42
375.8966064	0.09
394.2889099	0.10
447.4194641	0.49
474.3180237	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0025
Annotation	SC-58125
Peak:m/z	Relative Intensity
129.0061951	0.15
154.5031586	0.04
172.9087372	2.74
190.9642639	100.00
256.8710022	0.04
273.1024475	0.59
298.8211060	0.22
303.2710266	0.24
305.1268005	0.11
316.9869385	0.56
341.2452087	0.03
342.6317749	0.04
359.0582275	0.05
376.2261047	0.04
377.1101685	0.08
384.9952393	0.14
403.1290894	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1256
Annotation	b-D-Glucuronopyranosyl-(1->3)-a-D-galacturonopyranosyl-(1->2)-L-rhamnose
Peak:m/z	Relative Intensity
160.9250488	0.14
170.9822083	0.23
172.3001099	0.73
172.9566040	7.57
179.0081177	2.93
208.9880371	0.26
222.3406067	0.07
233.0805511	0.57
323.2703857	0.61
335.2549438	0.16
341.1788330	100.00
353.0108032	0.59
383.1738892	0.34
395.1882324	0.21
400.6910400	0.23
431.2032471	0.27
452.9871826	0.22
469.1370239	0.11
471.2888794	0.13
479.2125854	0.14
496.6036987	0.23
497.2817383	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.244
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9518509	0.15
126.1070709	0.01
128.8558960	0.05
131.1289368	0.03
139.1991272	0.04
141.2456665	0.08
141.8563232	0.01
143.0491791	0.01
143.8175964	0.04
148.9846191	0.02
151.2823792	0.03
159.0231934	0.13
161.0896149	0.28
162.0924225	0.05
169.1869507	0.02
170.6092987	0.01
195.3200684	0.10
211.2524719	0.15
213.1125793	0.36
221.1967468	0.09
223.3603821	0.10
224.1970215	0.07
225.1123962	0.06
227.1282349	0.02
230.0111237	0.01
238.1640625	0.01
239.5717468	0.07
240.1759033	0.00
241.1983032	5.24
242.2849426	0.81
243.1512756	0.01
249.2873230	0.04
252.4128418	0.01
253.3937073	0.02
255.3780823	0.08
256.4768372	0.01
257.0963440	0.16
259.2291565	12.01
260.2760620	1.79
263.1778870	0.01
265.1699829	0.06
266.1621094	0.06
267.3293457	0.01
271.2972412	0.15
273.4902039	0.04
278.2017517	0.02
283.2956543	0.66
284.3294678	0.17
285.2517700	0.03
294.3302307	0.04
295.5181274	0.02
299.4952393	0.05
301.3684082	0.09
302.2205200	0.01
309.5329590	0.03
311.3076172	0.12
312.3453369	0.01
313.7218933	0.02
315.4229126	0.01
319.2034302	0.04
325.3024902	0.10
327.4375000	0.02
329.2095032	0.01
333.0650635	0.02
338.5215454	0.02
343.5979309	0.02
355.3326416	0.07
356.2542725	0.03
357.5588074	0.01
361.2029724	0.08
367.3963623	0.05
368.3978577	0.02
373.6259766	0.03
374.8602600	0.07
375.5376892	0.06
378.5809326	0.05
383.6839905	0.03
385.3265381	6.54
386.3930664	1.63
389.0101013	0.01
401.3428955	0.19
403.3708191	100.00
404.3551025	18.66
405.4847107	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.8306961	0.09
108.8746338	0.03
111.1182098	0.07
114.9129868	0.09
127.0097580	0.14
133.9865570	0.30
135.0405731	8.13
137.1753387	0.03
154.9568787	0.44
161.0519409	1.13
172.9966583	2.43
178.9725952	39.59
190.9818115	100.00
230.3724976	0.10
309.0182190	0.17
335.2614441	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0678
Annotation	Unknow
Peak:m/z	Relative Intensity
165.1029968	0.05
170.9459839	0.21
174.9090881	1.24
182.8257294	0.33
186.9654541	0.41
198.8265839	1.99
201.0503845	0.50
203.0294647	0.19
204.9050903	0.05
211.0130005	1.30
216.7634277	2.07
224.8901215	0.77
226.8921204	0.78
229.0832825	0.43
232.9216156	0.07
234.9365082	0.86
236.9286346	0.23
241.7478333	0.37
243.1468658	0.22
245.0636139	0.75
246.7630920	0.31
251.1556396	0.09
252.8912964	0.37
254.9686127	0.70
256.9661255	0.18
258.7770081	0.45
261.0198364	0.09
264.9540405	0.48
267.1914062	0.28
269.1094360	0.78
271.0491943	0.42
273.8221436	0.03
274.9126587	0.70
276.9681396	24.72
280.0859375	0.12
281.2098389	0.08
282.9959106	0.11
284.9120483	0.34
288.8255920	4.35
289.4421997	0.17
290.9274292	0.06
294.1761475	0.04
294.9275513	0.58
301.0137329	0.43
303.0693359	3.05
304.8879395	0.39
306.9520874	40.80
310.8604736	0.05
318.9985046	8.76
321.0679321	0.52
324.3093262	0.19
325.0803833	0.32
329.1627808	0.71
330.9584351	1.62
334.9688110	0.08
336.7752686	14.24
337.4221802	0.08
343.0294189	1.28
347.1549683	1.93
349.1163940	1.60
353.0751953	0.11
355.0079956	1.31
360.1932983	0.30
361.0410156	1.08
364.9938354	0.74
366.4295044	0.92
367.0533447	28.61
371.4124146	0.06
373.0767212	3.60
378.9064941	0.76
382.0662842	0.69
382.7282715	0.63
383.3491821	0.02
391.0438843	23.64
395.0426636	0.26
397.0235596	27.78
398.9648438	0.09
404.2103271	0.18
407.4494019	0.25
409.0343018	74.13
410.3471680	0.14
415.3520508	0.10
425.2139893	0.65
427.0771484	100.00
428.5934448	0.17
441.4201050	0.08
450.1696167	0.29
454.4189453	0.08
459.3240356	0.05
462.7073364	0.16
488.0559692	0.07
499.1797485	1.03
510.6437378	0.24
511.4851685	0.24
544.2056274	2.78
544.9834595	0.49
553.0961304	0.39
560.4331665	0.33
570.9671631	7.09
571.8433228	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1116
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
136.0134277	0.01
137.9028931	0.08
144.6720428	0.01
156.1147919	0.04
162.8696442	0.02
209.1368713	0.03
224.1452942	0.01
227.1624298	0.06
231.3290863	0.02
241.2972717	0.05
245.1528015	0.07
256.9485779	0.04
269.2494202	0.03
271.0587463	100.00
272.1273499	0.05
272.9590149	0.02
277.1500244	0.02
282.3613892	0.03
283.8679504	0.04
287.5056152	0.08
295.6697388	0.01
300.1576538	0.03
303.164856	0.04
312.1577148	0.02
312.9439697	0.04
317.187561	0.02
321.0462036	0.01
339.2297058	0.07
342.6558838	0.05
345.0638428	0.02
351.7512817	0.07
355.0929871	0.02
360.6350098	0.13
365.3431702	0.08
373.0555115	0.03
386.0128174	0.02
387.0066833	0.05
397.3763123	0.13
401.3926086	0.02
403.2145996	0.02
405.1551208	0.13
411.6372375	0.06
414.1149597	0.21
414.9944763	0.21
415.6052551	0.16
416.4474792	0.03
446.709259	0.02
459.2933044	0.03
511.0258179	0.05
520.8544312	0.02
542.460022	0.13
545.0081787	0.05
549.5884399	0.01
588.6627808	0.04
595.2269897	0.02
596.6063232	0.13
622.6443481	0.05
640.4342041	0.02
653.4717407	0.02
700.8445435	0.04
702.0686035	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Scopolin
Peak:m/z	Relative Intensity
111.2011566	0.02
127.0083771	0.17
132.8714905	0.14
134.0969391	0.39
135.055481	6.35
136.0401764	0.65
137.013916	0.05
143.1509857	0.03
153.204071	0.08
154.9788208	0.30
156.0505371	0.07
161.1113892	0.91
162.0662231	0.06
173.0472412	3.36
174.0360565	0.24
178.9640503	40.95
180.0475769	6.14
191.0335388	100.00
192.1141968	14.84
205.9960175	0.04
217.2915039	0.04
256.1965637	0.05
259.2213745	0.06
266.4317322	0.08
309.2928467	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9712
Annotation	Unknow
Peak:m/z	Relative Intensity
130.1152954	0.02
136.0812225	0.05
145.2362366	0.04
146.9637451	0.03
161.4778748	0.01
165.0887756	0.02
169.3819122	0.07
179.1290131	0.11
182.1307526	0.04
182.8803406	0.03
186.1924133	0.04
186.8920898	0.02
188.0451508	0.03
193.2767944	0.17
197.6509705	0.04
199.1129456	0.07
200.1846619	0.02
200.8634033	0.02
201.9477539	0.67
205.2028198	0.04
212.9849548	0.11
216.9738159	0.03
226.8627625	0.04
228.0739441	0.01
232.9950714	0.03
238.9992981	0.16
239.9246216	0.05
240.7384644	0.05
242.0655212	0.03
242.9701843	0.01
244.0725098	0.16
245.0511169	0.17
246.2172852	0.15
249.3230896	0.05
256.4801025	0.09
260.0224915	0.12
261.1745300	0.02
263.2924500	0.03
266.1786499	0.24
268.7526855	0.07
270.8371277	0.05
275.2947388	0.11
276.2544861	0.01
280.1459045	0.05
284.4238281	0.16
285.0458069	0.03
286.0516968	0.22
300.3552856	0.04
303.0838623	0.42
304.0043945	1.33
305.1204834	0.26
306.1849976	0.10
308.0268860	0.05
312.9886169	0.05
314.1831055	0.05
316.7449951	0.03
319.1891785	0.03
319.9657593	0.07
321.7216797	0.03
322.5454407	0.11
323.2436218	0.01
326.0865784	0.03
326.7997742	0.02
329.4356384	0.06
330.3365479	0.10
331.0650024	0.31
332.0123901	0.51
333.2786255	0.14
334.1207275	0.02
341.5825806	0.11
343.0067139	0.04
344.2490845	0.02
346.1304932	0.04
347.9711304	2.17
348.9532776	0.05
350.1356812	0.04
351.2968140	0.08
356.9222412	0.02
358.0778198	0.07
363.1860352	0.09
373.3334656	0.12
375.1870117	0.63
375.9890137	0.29
381.2417603	0.13
384.0465088	0.04
385.1843567	0.03
386.2571716	0.02
392.3819885	0.51
393.9681091	100.00
394.5838928	0.15
401.0722351	0.46
402.2286072	0.14
403.2509460	1.94
405.1383057	0.05
407.1035461	0.06
408.2778320	0.11
410.3433838	1.50
419.0093994	5.95
420.1304626	3.94
421.1700745	0.53
428.8332825	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.0598
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0042877	0.15
170.9212952	0.11
174.1387634	0.14
174.9173737	0.56
185.0736847	0.12
186.9918213	0.24
190.0299683	0.40
199.0676727	0.44
205.1470032	0.36
214.8838654	0.47
216.9497375	0.89
232.9428558	3.71
234.1889801	0.08
234.9341125	0.17
240.9388428	0.59
244.8912354	0.13
252.9638367	0.05
258.4226074	0.28
259.1081848	0.39
260.8669128	0.14
262.7608337	0.98
274.9745483	0.16
277.0516357	46.89
286.8902283	0.07
288.9880981	6.43
293.1019897	5.22
295.0478516	0.59
299.0847168	0.16
299.8789673	0.30
304.8901978	0.19
306.8865967	44.26
309.0247803	0.07
316.9843140	0.60
318.8536377	0.60
323.2407227	0.24
330.7642822	0.22
335.1176147	1.78
336.3090210	2.91
336.9249268	20.04
348.9009399	0.45
353.1004639	19.13
355.0849609	0.29
361.0582275	0.17
366.2675171	1.10
366.9918213	0.80
378.0803223	0.06
378.8607788	1.26
394.9594116	0.21
396.9570312	100.00
397.5924072	0.34
424.1907959	0.08
425.1884766	0.72
437.5972290	0.14
495.0664062	0.21
497.0513306	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1967
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
245.1801147	0.01
269.0440063	0.05
281.1882324	0.01
285.2222595	0.03
287.1524963	0.18
289.0456543	0.01
339.3375854	0.06
341.1959534	0.01
353.1914062	0.02
363.2528076	0.01
377.3260498	0.03
379.1949463	0.04
381.3400269	0.03
387.1743469	0.01
395.3314209	0.02
405.3612671	0.07
406.2164307	0.01
407.053894	0.15
408.0491943	0.01
413.2348633	0.03
414.4499512	0.03
423.2556152	0.01
425.2164307	0.05
449.1442261	0.03
451.2738647	0.10
473.2789307	0.02
488.0395508	0.04
488.8502808	0.03
495.5244141	0.02
514.6342163	0.02
525.2791748	0.02
530.4338379	0.02
541.3109741	0.01
543.1218872	0.02
549.100769	0.01
553.3847656	0.07
556.3060913	0.01
557.312439	0.00
558.1465454	0.01
559.4195557	0.04
565.3131104	0.02
569.2964478	0.11
573.31073	0.10
575.2836914	0.13
576.25	0.05
577.3477783	0.15
578.2822876	0.01
585.2745361	0.01
587.418396	0.08
599.3295898	0.01
613.1868286	0.12
617.1256714	0.01
618.7505493	0.03
626.2672119	0.01
634.7163696	0.07
635.373291	0.02
638.5605469	0.02
643.3599243	0.01
644.619812	0.02
657.2266235	0.08
670.2828979	0.02
676.4328613	0.02
686.3779297	0.02
693.196228	0.02
694.1451416	0.03
695.0499268	0.14
695.7025757	0.01
697.6951294	0.01
698.3135376	0.07
701.5370483	0.04
703.168396	0.01
705.2520752	0.01
709.1747437	0.02
712.4331665	0.08
713.3510132	0.01
716.59198	0.06
719.37677	0.07
720.2024536	0.08
722.2365723	0.02
725.401062	0.04
737.5293579	0.01
739.5762329	0.06
741.2034302	0.05
770.4978638	0.01
777.1071167	0.01
779.3551636	0.38
780.1420288	0.12
788.5153198	0.06
792.15448	0.00
801.5360718	0.10
805.0567017	0.01
807.7543335	0.06
809.5722046	0.03
813.3800659	0.08
819.2941284	0.06
839.3996582	0.03
845.0998535	0.02
846.1519165	0.02
847.2588501	0.09
863.3568726	0.02
865.1947632	100.00
866.0367432	0.33
867.3253784	0.05
868.2303467	0.04
869.7528076	0.01
872.7434692	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1172
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
136.9178467	4.31
144.8527374	0.06
146.9484100	0.10
161.0394287	0.08
163.0335846	0.27
166.6768494	0.05
172.9886475	0.33
174.8632812	0.04
179.0409241	0.68
191.1455688	0.21
194.2677612	0.18
195.0721130	0.08
201.2981873	0.04
203.0333252	0.24
212.9764404	0.37
235.3102112	0.11
241.0045013	0.43
245.2428894	0.18
268.0270386	0.09
268.9152832	0.19
271.2322083	0.31
274.3723450	0.09
275.8388062	0.12
285.9260864	0.15
287.1660767	4.10
291.3271179	0.14
295.1702271	0.44
298.1107178	0.14
299.3026428	0.08
305.1245728	100.00
308.0565491	0.36
311.1865234	0.20
313.3586121	0.11
315.0172119	0.23
316.8632812	0.05
319.1514893	0.42
319.9928589	0.13
326.2590637	0.32
329.1794739	3.78
331.1818848	0.60
333.1088867	0.15
335.2698975	0.07
338.9662170	0.09
342.2795105	0.19
347.1487732	2.25
352.1149292	0.34
352.9204102	0.46
355.2796326	0.15
357.6070251	0.14
365.9502563	0.16
371.0384827	4.42
374.5914001	0.21
378.9266663	0.27
380.3795471	0.08
392.8779602	0.75
395.2589722	0.35
401.2395020	0.13
402.2049866	0.11
403.2533264	0.10
404.9174805	0.03
407.1572876	0.35
407.9295349	0.12
412.8636475	1.27
417.1652527	0.13
419.9815369	0.05
421.1304321	0.82
424.7792664	0.15
426.0437927	0.56
431.1490173	10.51
438.1649475	0.41
443.4430237	0.06
446.0989380	1.20
447.2631226	0.11
449.1858521	59.77
455.1125183	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.17
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9182281	0.10
123.0677643	0.04
131.1212158	0.10
143.0041809	0.08
145.4031677	0.14
148.0000916	0.04
161.1904755	0.35
163.0692444	0.98
176.9903259	0.08
178.8773804	0.06
181.1701050	11.47
184.8382874	0.11
187.1212311	0.04
195.1567841	0.05
205.6318970	0.20
207.0522156	7.90
209.3087921	0.08
215.2068481	0.06
217.0573578	0.09
220.0983582	0.06
223.1136475	0.20
225.1609192	100.00
239.0212708	0.22
241.1007080	0.04
242.0643311	0.04
249.1726379	2.21
253.1816406	0.06
257.0842590	0.06
261.2770386	0.51
263.2035217	0.10
267.1724243	0.91
269.2276306	0.17
278.9692688	0.33
281.4725647	0.22
291.2188721	0.30
295.8728943	0.03
297.1871338	0.39
303.1462708	0.22
309.0230713	0.42
315.0567627	0.17
318.8806763	0.05
322.8594360	0.08
326.1222534	0.32
327.2015686	1.46
333.2297363	0.44
341.2355042	19.29
342.3028259	0.02
343.2760620	0.22
345.1326904	0.04
349.4755859	0.04
351.3114319	0.15
354.1939392	0.08
355.2636414	0.20
357.0578003	0.03
367.2952576	0.19
369.2563782	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.14
Annotation	10-Acetoxymajoroside
Peak:m/z	Relative Intensity
142.9568787	0.53
146.8714294	0.09
149.0644531	0.38
160.8065796	0.46
166.9874420	0.20
179.0808105	3.59
190.9419861	0.20
221.1659851	1.23
244.5914459	0.21
284.8403931	0.06
290.1193848	0.11
305.1092529	2.04
309.1868896	0.31
323.1018066	48.91
342.9923096	0.09
347.3339539	0.32
352.9860535	0.15
357.3035278	0.12
395.1394653	0.18
397.1862183	0.31
401.2547302	0.08
415.2841492	0.99
441.2825623	0.07
445.0838623	100.00
445.8544312	0.16
447.8732605	0.23
453.1662292	0.25
461.4980469	0.32
471.3190002	4.57
472.3349304	0.25
473.2892151	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
78.88426971	0.80
82.73349762	1.25
103.0571442	1.02
105.011734	2.29
107.0304718	0.42
108.7151031	1.31
122.754303	1.62
128.9466858	6.76
140.8903198	1.00
145.1287842	0.36
148.983139	1.71
150.9518738	100.00
151.9351959	6.26
153.8261261	0.42
155.0486145	2.98
165.2348328	1.54
166.2277985	4.30
167.1585846	1.94
168.2314301	1.45
169.1816254	1.44
169.8491516	0.58
171.0608063	1.95
179.1221313	1.57
185.0949097	0.97
190.8530121	0.58
192.065979	1.96
197.0658112	5.57
198.1777649	0.64
208.2565155	1.89
210.4322357	2.05
211.1891785	0.21
225.0100555	13.33
226.1602783	1.06
238.1282959	10.88
239.1208038	1.85
253.0787354	38.14
253.9802856	7.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	718.61
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9034729	1.23
214.5849304	0.92
290.7525635	2.16
291.4167480	0.97
296.7505188	0.57
298.6552734	0.87
319.0260620	6.07
320.7478638	1.14
331.0525818	0.48
340.0615845	2.40
347.8054199	0.37
354.6937866	1.45
356.8261108	0.28
368.9476929	1.52
376.4779663	0.68
380.8082275	7.64
381.8717651	0.27
382.7673950	17.66
420.9658203	10.93
439.0975952	36.83
458.6239624	0.66
464.7447510	13.52
466.0747681	1.14
466.7191772	37.31
474.9406128	58.98
504.7047729	1.20
515.3739014	2.13
542.6998291	3.70
544.0930786	1.62
544.8140259	4.43
545.7409058	1.08
548.6309204	22.19
549.8297729	6.85
550.5713501	82.82
551.2546387	0.22
557.1262207	6.02
585.7651978	3.76
598.7814941	2.54
603.5695801	0.73
632.5140991	26.21
633.8887939	41.65
634.6037598	100.00
638.1188965	0.99
675.7754517	6.71
695.1928101	2.08
700.9779053	1.22
719.3657227	4.37
724.6287842	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	197.04
Annotation	Unknow
Peak:m/z	Relative Intensity
66.8703690	2.15
68.6463318	0.53
70.0808563	2.42
82.9816437	0.51
94.9713287	0.46
104.8030548	1.57
112.7934113	0.57
119.0390320	0.76
130.8627472	0.76
134.9670258	0.82
136.8507233	1.36
138.3385468	1.18
138.9528656	2.13
140.8516998	0.95
150.8454437	100.00
152.4599304	0.93
155.1479034	1.88
156.0813599	6.99
161.1497192	3.00
168.4671173	1.57
169.2283936	0.91
175.7728577	4.26
176.7051392	0.74
178.9880829	8.27
180.0789795	1.13
185.4961700	1.19
187.7469330	1.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1113
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
144.9642334	0.02
162.21521	0.03
165.7977448	0.02
189.1491852	0.02
212.9827881	0.03
227.1222229	0.01
229.1655579	0.02
241.0192871	0.03
246.1916199	0.06
252.4031372	0.03
258.2068787	0.10
271.0679016	100.00
271.984436	0.06
283.4770813	0.08
284.0948792	0.05
300.2424011	0.03
302.2354126	0.06
308.6786499	0.06
317.3723755	0.05
318.3380432	0.01
327.2598267	0.02
329.2834778	0.03
330.3369751	0.06
331.4295044	0.02
340.0809631	0.08
343.1524658	0.09
351.5033569	0.08
355.1651001	0.02
358.1783752	0.02
361.2242126	0.09
369.0622559	0.05
369.7847595	0.03
371.2476807	0.02
372.291687	0.04
372.9482117	0.03
374.3088684	0.11
376.4776611	0.08
387.243866	0.13
388.3594971	0.05
396.4400635	0.05
405.4241943	0.04
406.3299255	0.08
411.5961609	0.03
414.9039307	0.17
415.6342468	0.05
416.3244324	0.01
426.9539795	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
103.0518188	0.44
126.9039001	0.31
129.0335388	0.47
134.9596252	11.97
143.5265198	0.21
145.1510925	0.29
153.0684357	0.39
154.1435242	0.31
155.0076294	0.71
160.9250488	0.55
173.0309753	4.33
179.0131836	33.97
191.054657	100.00
205.0310059	0.77
213.1151123	0.44
217.2475586	0.87
219.0994263	0.62
220.8956604	0.15
230.9427185	0.28
234.9179688	0.68
257.149231	0.17
258.7344971	0.71
261.081665	2.54
264.9275818	0.29
266.9429321	0.16
277.1356812	0.36
291.2930908	1.17
292.8920288	0.52
305.0635986	0.75
307.0586243	8.94
308.1299438	0.14
309.3143005	0.24
323.432312	1.14
334.9834595	5.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	789.0471
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1970367	0.07
228.7609711	0.23
267.0241394	0.25
268.8148499	0.16
273.0024414	0.17
286.0318298	0.14
287.0928955	1.83
288.2037964	0.04
299.0046387	0.17
315.1378174	0.33
320.6974792	0.08
325.2985229	0.05
327.0964661	0.22
329.0596008	1.35
329.8868103	0.09
341.0777588	0.22
344.4753418	0.16
345.9066772	0.15
346.7914734	0.37
372.8517456	0.06
374.9008179	0.13
386.8149414	0.62
387.8126831	0.47
388.9772949	4.61
390.1320190	0.87
399.2514648	0.13
401.0012817	0.05
404.6844482	0.24
405.4433594	0.45
406.2379761	0.06
416.8281860	0.13
427.1101685	0.18
431.0543213	0.23
446.7661133	0.66
448.9258423	0.79
449.8772583	0.25
450.6353149	0.04
454.2823486	0.28
465.6721802	0.08
477.0338135	0.23
478.4802856	0.48
479.1763306	0.32
485.7545166	0.08
490.9680786	0.12
493.7689819	0.49
500.0627441	0.30
507.0012207	3.40
508.2804565	17.73
509.0477905	100.00
510.0166626	21.32
510.9389038	0.22
519.2113647	0.10
521.2237549	0.19
528.0709229	0.56
528.9631348	0.17
529.9049683	0.12
537.3018799	0.71
538.1062622	0.18
545.9443970	0.20
549.0924683	0.41
550.2051392	0.87
556.2744751	0.07
557.9634399	0.32
561.3062134	0.07
562.2361450	0.24
563.1265259	0.09
565.7266235	0.85
566.8420410	10.56
567.9771118	3.20
568.8306274	0.53
569.8283691	0.46
578.9285278	0.45
588.1300049	0.09
591.3352661	0.24
592.1270142	0.43
592.9954224	0.55
594.0336304	0.17
595.2428589	0.08
600.6207886	0.24
609.0944214	0.69
610.1105347	0.58
611.2108154	3.83
612.2324829	1.10
613.3322144	0.17
618.4408569	2.90
619.2240601	8.74
620.2297974	1.10
622.3682861	0.56
625.2731934	0.08
627.1217651	19.20
628.1719971	3.82
628.7794800	0.04
630.2051392	0.28
640.1918335	0.17
648.0359497	0.50
648.8383179	0.95
649.6690063	0.11
651.3123169	0.06
651.9398804	0.19
655.7517090	0.12
663.6166382	0.53
664.9480591	0.37
668.9334106	0.23
669.8366699	0.42
671.0519409	0.32
671.7145996	0.31
672.3309937	0.05
674.1071167	0.13
676.9242554	0.05
678.1362915	0.21
682.0290527	0.25
684.4369507	0.04
691.4603882	0.10
697.8666382	0.08
699.4157715	0.10
700.1255493	0.24
706.3671265	0.20
708.5755005	1.12
709.6853638	0.16
718.7071533	0.06
720.7075806	0.41
728.9616089	0.41
730.0739136	0.34
730.9588623	0.14
734.1092529	0.16
736.4217529	0.43
743.5979614	0.66
744.2340698	0.04
745.7783813	0.08
752.5064697	0.17
759.0262451	0.24
766.5375366	0.16
771.6530151	0.05
790.1896362	41.94
800.8303223	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1816
Annotation	(1R*,2R*,4R*,8S*)-p-Menthane-1,2,8,9-tetrol 9-glucoside
Peak:m/z	Relative Intensity
112.8163452	0.47
118.9295731	0.22
122.7888718	0.02
125.0202789	0.04
128.9512177	0.02
143.0318298	0.17
147.1001282	0.04
149.8763885	0.11
156.0246887	0.05
157.1549683	0.12
159.1566315	0.07
160.9618835	0.05
167.0895844	0.37
183.2438049	0.10
184.0890656	0.06
185.1506042	3.62
186.1080627	0.07
189.1381531	0.04
190.8821411	0.14
197.4113312	0.05
199.1256866	0.14
201.1816711	0.07
203.1051025	4.87
204.0249023	0.03
204.8738708	0.06
207.3368988	0.04
208.8715668	0.05
214.0229492	0.05
245.2295532	0.04
251.1674500	0.10
255.0923767	0.10
255.9685059	0.08
275.2420044	0.19
277.2438965	0.08
279.1054993	0.09
281.2433167	0.07
283.1120911	0.04
285.4795837	0.08
292.2373047	0.01
295.2270508	0.03
302.4624329	0.03
305.0094604	0.02
310.8919373	0.19
316.1242371	0.07
316.9457703	0.06
319.1678772	0.50
321.1545410	0.23
329.2975159	6.10
330.2749939	0.06
337.4213257	0.02
345.1734009	0.23
347.2315979	100.00
348.3616943	1.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.1622
Annotation	Unknow
Peak:m/z	Relative Intensity
148.8583221	0.09
161.0492249	0.04
178.9931946	0.57
180.1709747	0.18
181.1762543	0.20
182.2404022	0.03
202.9583740	0.03
222.9373779	0.07
228.9575348	0.09
236.8669128	0.11
237.9291687	0.03
265.6875305	0.04
280.7251587	0.03
281.9084778	0.02
284.0317688	0.26
297.2107849	0.02
303.2005005	0.04
304.2789307	0.07
304.8847046	0.10
341.1862793	0.08
343.2082825	100.00
344.2367554	3.82
354.5379028	0.22
355.5322266	0.03
371.7198181	0.09
374.1151733	0.09
377.0853577	0.08
377.8721619	0.18
384.1759338	0.02
389.2142639	0.06
399.4841614	0.05
412.0125122	0.10
430.0825195	0.03
432.2297668	0.14
435.2390442	0.12
458.0959167	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.2441
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0760956	0.09
143.3441467	0.02
159.0570526	0.09
161.0560913	0.22
165.2558899	0.19
179.2191467	0.04
191.1147461	0.02
195.3980560	0.04
203.2326660	0.13
208.9081726	0.06
209.8675537	0.10
211.0369110	0.06
212.2071533	0.22
213.3032379	0.45
214.7384033	0.19
223.1718292	0.16
237.2559204	0.13
239.1831665	0.18
240.2663574	0.09
241.2738647	4.86
251.4037476	0.05
253.1555786	0.05
254.3265076	0.10
255.3860474	0.13
257.2109985	0.49
258.3518066	0.13
259.2378540	11.78
267.4304504	0.12
271.4680176	0.02
273.3601074	0.30
277.6513062	0.06
283.3249512	0.47
287.2718811	0.03
295.1331177	0.14
297.2985229	0.06
299.3150940	0.06
300.6475830	0.08
301.4028625	0.16
305.3952026	0.08
307.5197144	0.10
311.3900146	0.08
323.4068298	0.40
325.4214478	0.10
329.2428894	0.06
331.2755737	0.14
333.2208557	0.09
341.4269104	0.05
345.4382629	0.07
347.2467041	0.21
349.2248840	0.17
353.1599731	0.07
355.4791260	0.06
357.3070374	0.03
360.5967407	0.06
363.3183899	0.04
367.6748352	0.13
373.7558899	0.84
374.3741760	2.29
375.3853149	1.37
376.4167175	0.16
377.2090454	0.14
383.3112793	0.08
384.6973877	0.42
385.4056702	8.45
386.3056030	0.05
388.2415466	0.03
399.9966736	0.06
401.0650940	0.20
403.3364563	100.00
404.2702942	0.95
404.8873596	0.12
407.4086914	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.21
Annotation	Icariside H1
Peak:m/z	Relative Intensity
121.0893860	0.16
128.7451477	0.20
130.9062805	0.30
133.0641479	0.06
135.0882568	1.03
142.9358368	0.43
147.0608826	0.77
149.1153412	0.47
161.0088501	1.95
165.1495361	9.11
173.1467285	0.06
174.9580231	0.20
176.9867554	0.12
178.9117432	1.53
183.1277466	0.19
187.0493774	0.04
189.1956024	0.18
191.1104584	1.02
193.0652161	0.07
201.1033325	0.20
202.9811859	0.11
204.9364014	0.22
207.0646362	3.53
209.1387939	70.65
219.0773926	0.33
223.1092377	0.61
225.1376953	0.04
233.0179749	0.93
237.0611572	0.37
243.3870850	0.17
251.1554565	3.09
255.0133972	0.14
257.3547058	0.04
263.1102600	0.36
271.1448364	0.04
281.1577759	2.78
285.0683594	0.14
293.2206421	0.29
295.4566345	0.04
297.1410522	0.07
298.7265625	0.83
302.9333801	0.17
305.3268738	0.12
311.0329285	1.89
313.2626953	0.19
315.3038330	0.06
323.3099365	0.09
324.9049683	0.10
341.2728882	0.61
342.2703857	0.11
343.2939148	0.14
345.4689941	0.19
349.0942993	0.09
353.2515869	0.37
355.4520264	0.04
368.7806702	0.04
371.0208740	100.00
371.9340515	0.04
373.1813660	0.44
374.1300659	0.17
377.2390442	0.06
381.0823059	0.06
396.1982422	0.09
398.7695007	0.26
399.4584351	0.52
402.5102234	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.2338
Annotation	Rhodioloside E
Peak:m/z	Relative Intensity
161.0768433	0.66
175.0826111	0.31
199.3298035	0.17
205.3791809	0.11
213.0978851	0.06
241.0806274	0.36
242.9690247	0.14
257.2383118	1.02
259.0935974	0.07
261.2109680	0.10
267.2297974	0.06
285.1250305	3.06
286.1126709	0.07
289.2324219	0.07
299.0783997	0.04
301.3731079	0.15
302.2778320	0.22
303.3298340	0.27
307.2283325	0.05
309.2964783	0.09
323.1212463	0.13
328.7207031	0.17
330.9962769	0.50
332.3507080	0.08
338.9761658	0.44
339.7551880	0.20
341.3322754	0.05
343.3238831	0.06
346.6333618	0.05
349.4990845	0.13
351.3482361	0.16
369.1952820	0.09
379.3167419	0.09
401.4196167	4.40
404.4011841	0.11
419.2957153	100.00
420.5249634	0.18
421.2709961	0.22
422.7956238	0.24
427.5109558	0.19
446.6467590	0.91
447.3285828	6.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1066
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
108.9044724	0.12
118.9642029	2.15
129.9839172	0.10
146.8901367	100.00
147.9977875	0.08
149.0975037	0.03
154.0590820	0.03
156.0123291	0.18
159.1474304	0.15
165.0087585	0.03
171.9228058	0.02
177.0679321	0.34
184.2718353	0.06
193.1005859	0.32
194.9256134	0.20
196.0467529	0.20
204.6967468	0.03
219.1209106	0.11
223.0107117	0.09
226.1388245	0.15
239.9202271	0.03
242.3422546	0.16
249.2682190	0.48
252.9741821	0.04
254.2965088	0.03
272.2731018	0.91
273.1310425	0.03
275.0487061	0.20
278.5638428	0.11
279.4150085	0.15
280.0609131	0.11
285.5997620	0.48
292.0486450	0.24
292.9157715	0.07
294.0498047	0.14
297.0569763	0.26
301.2597351	0.29
303.4244995	0.15
305.1749268	0.14
306.9436646	0.04
309.2419434	0.11
311.0724182	0.28
312.0997925	0.05
319.2039795	0.07
320.1960449	0.61
321.0883179	2.42
322.4801636	0.05
323.2312012	0.05
324.1968079	0.03
329.6631165	0.35
330.2770386	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.1533
Annotation	11-O-Debenzoyltashironin
Peak:m/z	Relative Intensity
81.08425903	1.83
84.9686203	0.53
88.84342957	2.30
90.92004395	2.37
93.10655212	1.50
94.84182739	4.07
96.97188568	5.96
99.05345154	1.86
106.8973999	2.48
108.982254	1.98
110.9861603	2.96
115.0969238	1.40
121.0852661	4.33
123.0363388	3.81
130.7758636	1.09
132.9640808	4.89
135.0404358	4.67
137.1655426	1.48
138.9872437	1.13
140.9310913	1.52
146.7344666	2.55
148.9972076	6.74
151.2011871	2.29
152.0437775	1.30
153.047821	1.64
157.2259064	1.21
159.1411285	0.98
161.2281952	2.86
163.0577393	4.80
164.9618835	2.03
171.1378326	1.61
173.1416626	0.41
177.1042175	4.31
179.3463593	0.61
181.0470581	0.98
182.8858948	2.60
184.9158936	3.10
187.1914673	2.71
189.2086487	4.85
191.103653	1.62
192.2727051	1.47
195.0055847	4.48
197.1695557	2.52
198.063324	1.18
199.1183777	4.23
201.0883179	2.72
205.3253479	1.02
207.1151733	1.24
209.1128235	1.91
210.3162842	0.59
213.13797	1.77
214.0802917	2.52
215.1321716	1.93
216.7972412	0.36
218.7145081	1.58
221.1957092	3.00
223.3278503	0.27
224.0334473	1.85
225.0436707	1.87
227.0056152	2.72
229.0125732	0.76
233.2245178	0.30
235.2037354	0.92
237.0665894	20.15
238.2955627	0.92
239.305481	4.70
241.1223145	7.97
242.0367432	3.34
247.2460938	27.40
248.007019	2.37
251.275177	2.91
252.0274048	1.57
253.2977905	1.97
255.1345215	8.15
262.83078	2.12
265.14505	100.00
266.4957886	0.65
268.0636902	1.61
268.7468872	1.82
273.9573975	0.80
274.8019409	2.25
283.1051636	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	864.69
Annotation	Unknow
Peak:m/z	Relative Intensity
239.2023926	0.08
243.0657349	0.09
244.9499359	0.43
255.1051483	0.14
259.1487427	0.36
284.2097473	0.05
286.1754150	0.12
287.0961914	0.67
289.2055359	0.86
294.9242859	0.07
315.1302490	0.04
315.9678955	0.12
327.2769470	0.46
328.9854126	0.06
331.1827393	0.49
339.1127014	0.25
349.3102112	0.07
363.4007568	0.04
367.1033325	0.08
368.1649780	0.14
375.0310669	0.06
380.2007446	0.12
386.9735107	0.15
395.6233215	0.07
397.0724487	0.10
405.2279663	0.76
406.2136841	0.16
407.3876343	1.59
411.3018188	0.10
412.1734009	0.07
413.1378784	0.47
414.3045044	0.30
423.1031494	0.55
424.5660400	0.07
425.2623291	0.39
427.5084229	0.06
433.4276733	0.14
435.3051758	0.14
449.2894287	1.13
451.1469116	0.37
453.3765259	0.07
463.3309937	0.11
465.1108398	0.19
493.1395874	0.12
499.2783813	0.33
500.2871094	0.51
508.3200073	0.18
515.3234863	0.23
525.2998657	0.94
529.3881226	0.08
531.3034668	0.23
533.1832886	0.05
541.1630249	1.05
542.2877808	0.09
549.4188843	0.21
557.8052979	0.97
558.6876221	0.58
559.3767090	0.56
561.0629883	0.19
568.2837524	0.32
569.4340210	0.08
570.5146484	0.31
572.3123779	0.14
572.9455566	0.08
573.7345581	0.10
575.1930542	1.52
576.2160645	0.62
577.2633667	2.75
578.1559448	0.07
580.0375366	0.16
585.2898560	0.54
597.3909912	0.15
609.4854126	0.09
617.4003906	0.18
618.6793823	0.46
619.6329346	0.24
627.3562622	0.33
629.3992310	0.09
634.1754761	0.33
634.8345337	0.24
635.7483521	0.94
638.4255981	0.11
639.6873169	0.03
643.2221069	0.35
644.4794312	0.35
649.3489380	0.19
651.2770386	0.27
656.4784546	0.10
657.3010254	0.20
662.4194336	0.35
664.2958374	0.41
668.3096924	0.23
685.1276245	0.05
693.2604370	0.75
694.2262573	2.49
695.1947632	0.68
701.3911133	0.68
703.3704224	1.42
710.2370605	0.27
711.0178833	0.37
712.1859131	0.80
713.3606567	0.33
716.3936768	0.63
717.4849243	0.20
719.2800903	2.30
720.6392822	1.15
724.4722290	0.72
725.3587036	0.06
736.2944946	0.07
737.3881836	0.55
738.0409546	0.54
739.4081421	0.67
740.4674072	0.15
741.4797974	0.21
747.4796753	0.09
755.6632690	0.19
756.8044434	0.83
770.4470825	0.66
779.3755493	2.99
782.8668213	0.18
788.4151611	0.45
792.4002075	0.42
801.3241577	0.84
802.0971069	0.04
803.4141846	0.14
807.3287354	0.25
812.9942627	0.29
819.2158813	0.29
821.5404663	0.23
837.4054565	0.17
845.6784058	0.29
847.3187866	0.46
864.1790161	22.01
864.8921509	100.00
866.6033325	0.16
867.2810669	0.13
871.5654297	0.11
873.7733765	0.28
877.9836426	0.44
900.4922485	0.13
905.1203003	0.12
913.2070312	0.14
915.4851074	0.25
916.3036499	0.06
931.4028320	0.21
945.1273804	0.14
955.1406860	0.18
965.1115112	0.13
965.7722168	0.11
983.0991211	0.14
985.4619751	0.11
989.3298340	0.86
997.2157593	0.07
999.1670532	0.50
1001.4972530	0.12
1023.9858400	0.34
1025.3742680	0.38
1027.3679200	0.56
1028.0345460	0.07
1029.2663570	0.12
1041.5212400	0.06
1091.1312260	0.10
1107.3149410	0.23
1133.3913570	0.63
1134.1657710	0.38
1135.3383790	0.34
1136.0618900	0.10
1136.9743650	0.10
1145.3876950	0.26
1149.0649410	0.51
1150.0434570	0.09
1151.2996830	2.38
1153.3125000	2.56
1155.2797850	0.49
1161.4040530	0.07
1193.0734860	0.17
1211.8634030	0.20
1233.6253660	0.28
1259.1245120	0.10
1261.1773680	0.09
1269.0535890	0.12
1271.3463130	0.81
1277.4343260	0.18
1278.3228760	0.13
1297.2967530	0.04
1313.4572750	0.33
1314.7213130	0.47
1315.3712160	0.85
1319.7409670	0.23
1357.1502690	0.09
1421.2948000	0.25
1422.2042240	0.04
1423.4270020	0.14
1433.5782470	0.22
1439.2921140	1.01
1440.2435300	0.73
1441.4060060	0.61
1442.3780520	0.23
1484.0325930	0.34
1492.2489010	0.17
1585.3389890	0.30
1603.5343020	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	199.0977
Annotation	alpha-Carboxy-delta-nonalactone
Peak:m/z	Relative Intensity
88.9949951	0.03
111.0858917	0.02
137.0247345	0.59
141.0641022	0.01
155.0371552	100.00
181.0784454	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.15
Annotation	Unknow
Peak:m/z	Relative Intensity
97.0060883	0.07
98.7786560	0.14
99.8720398	0.27
101.9904709	0.02
115.9954529	0.11
123.0761414	0.25
123.8739471	0.37
126.8418045	0.04
141.1307373	0.07
145.1490021	0.18
150.9492798	0.42
153.1547241	0.09
159.9957275	0.02
168.9845734	100.00
169.6051025	0.19
174.7390442	0.05
177.0193787	0.14
187.0752716	0.08
188.9567719	0.11
190.1770935	0.04
192.0626221	0.11
195.3986816	0.11
204.8401947	0.06
207.0572662	0.07
211.1575623	0.04
214.1206055	0.10
215.0584412	0.14
227.8513184	0.06
230.1795044	0.04
231.0439453	0.05
234.8381958	0.06
239.4252930	0.03
240.8319702	0.02
241.5654907	0.07
250.0398560	0.50
252.9613647	0.56
254.9673767	0.50
255.9904785	0.04
259.0227661	0.22
260.0726318	0.04
261.0123596	0.02
269.1745300	0.09
270.1510925	0.04
271.2329102	0.17
272.1340332	0.08
275.2250061	0.06
284.8517151	0.09
294.9166260	0.11
297.9864807	0.08
298.9988708	0.20
308.0782166	0.10
313.1831665	1.01
322.1297913	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	Epoxycantabronic acid
Peak:m/z	Relative Intensity
80.05337524	0.03
82.84309387	0.29
94.8263855	0.16
101.1446991	0.11
110.962738	3.17
123.9382019	0.09
127.1076508	0.44
135.2415771	0.09
138.098999	0.84
138.8903809	0.03
146.9241638	0.35
150.3592224	0.08
151.0873413	0.09
153.0035706	100.00
154.1061249	0.21
161.0361176	1.92
163.0618439	0.10
164.7457581	0.17
173.0614777	0.10
175.0458221	0.46
177.0886993	0.13
178.8849945	0.10
181.233902	0.29
185.1867065	0.10
186.3066254	0.13
187.0879059	0.12
189.1799469	0.06
191.0630951	0.23
201.1231842	4.07
203.1327209	0.61
204.185791	2.34
205.1201172	0.07
206.878479	0.06
212.1449127	0.12
217.1021576	0.41
219.1312408	29.73
221.1639099	0.12
235.0231781	0.38
243.2659454	0.03
244.2706909	1.05
245.1787262	2.41
247.0321655	0.03
254.1862335	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	590.2005
Annotation	Unknow
Peak:m/z	Relative Intensity
172.8667297	0.10
175.1864014	0.14
207.8405914	0.39
223.7481537	0.10
227.9384766	0.09
229.8529358	0.25
231.9458008	0.36
246.1991272	0.25
250.0170441	0.90
251.0586853	2.57
252.2606049	0.34
263.9388123	0.11
265.0289001	0.41
266.0841675	7.41
267.1692505	0.16
268.0764160	0.22
275.8822937	0.40
283.3742065	0.47
284.1315918	0.62
287.1237793	0.19
290.0076904	0.16
299.9115906	0.18
308.3427124	0.29
313.0909424	0.14
317.9295654	0.20
322.1046753	0.45
326.3048096	1.73
337.7878418	0.07
351.2299194	0.48
352.1737061	0.18
354.1259155	0.52
361.8930054	0.17
369.9734497	0.14
378.2579346	0.47
383.4336548	0.36
384.1959839	0.53
392.0910034	1.10
395.1115723	0.38
396.3214722	0.23
403.3555298	0.11
410.1032715	2.01
421.5527344	0.08
425.3618774	0.26
426.2125854	0.55
427.0250244	1.04
428.2327881	100.00
429.2619629	1.65
446.2201538	0.12
456.2828369	0.08
458.3837280	0.18
459.8519897	0.14
468.0434570	0.20
489.2204590	0.33
492.3444824	0.17
499.2931519	0.27
508.2844849	0.34
526.0501709	0.61
545.9854126	0.32
547.0712280	1.31
552.6884155	0.23
557.4783325	0.19
563.0859985	0.58
569.1412964	0.19
571.6580200	0.42
572.4571533	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7716675	23.42
213.0218658	0.02
290.8182983	100.00
296.8912659	0.07
314.9317627	0.02
322.9471436	0.02
338.8338013	0.30
347.9838257	0.01
353.1215515	0.11
356.8651428	0.02
374.6083984	22.85
375.3579407	0.12
398.8533630	0.76
412.6192322	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.239
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1254196	0.06
129.1784363	0.05
141.0833893	0.03
142.9983673	0.14
144.2873840	0.03
148.9947052	0.02
157.1481323	0.44
158.6748810	0.16
159.7274017	0.09
161.0421295	0.32
162.1703644	0.09
173.1167450	0.03
174.0894470	0.04
199.0357056	0.02
201.0774078	0.05
203.4748535	0.06
211.1983643	0.03
213.2192078	0.13
219.1830902	0.05
221.3629761	0.03
229.2969055	0.05
231.4091187	0.05
235.3196106	0.03
239.2557983	0.22
239.9412537	0.05
241.3800659	0.06
243.1780090	0.07
255.1481628	0.19
257.3049622	1.03
258.1670532	0.12
263.0804443	0.01
272.0707703	0.03
273.4337769	0.02
275.2393188	2.64
276.4266663	0.38
283.4789124	0.01
285.3367920	0.04
288.3193970	0.04
289.5128174	0.06
298.0810547	0.07
299.4486694	0.05
301.4521790	0.05
316.9757080	0.18
317.6788940	0.03
318.3728638	0.09
319.5561218	0.16
329.6430359	0.07
333.2487793	0.05
335.3230591	0.44
336.3705444	0.08
337.6489258	0.04
345.4463501	0.03
358.4143372	0.05
363.3623352	0.68
364.4613647	0.02
371.5948792	0.04
373.6635132	0.04
375.4000549	0.54
376.2377930	0.16
377.3381653	0.01
383.2448425	0.34
384.4019470	0.12
391.1969299	0.32
392.3430481	0.41
394.2036743	0.20
399.5338440	0.03
401.3159790	2.57
402.3731384	1.10
403.2392883	0.04
417.3604126	0.09
419.3127441	100.00
420.3435059	23.72
421.3923645	0.54
425.3395081	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0089111	4.99
115.8865738	0.89
116.5062866	0.01
130.9463501	0.24
132.0040283	0.10
156.8831482	0.01
158.9216614	100.00
159.9069824	20.83
172.8823242	0.01
185.0634918	0.02
199.0023193	1.59
200.0603638	0.93
201.0534363	0.06
201.8101807	0.03
216.9724426	1.16
217.9973145	0.44
218.9866638	0.01
224.3134766	0.01
228.9234009	20.89
229.9122925	8.56
245.0549316	0.44
246.0693359	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.2916
Annotation	Hordatine A
Peak:m/z	Relative Intensity
231.3096924	0.04
273.3269043	0.01
286.2161255	0.04
287.0037231	0.01
315.2699585	0.09
329.4952393	0.04
356.1805420	0.04
373.5534058	0.01
391.6024170	0.04
403.4722900	1.29
404.5299072	0.15
405.2899780	0.01
413.2160645	0.03
415.3474121	0.01
424.5294800	0.01
431.5890503	0.09
437.6217651	0.03
440.1687012	0.01
445.4300537	0.04
472.3964233	0.07
476.6850586	0.01
481.5764771	0.03
496.3430176	0.03
515.4783936	0.04
535.4992065	0.04
547.6628418	0.04
550.8189087	0.01
552.3837891	0.01
554.1793213	0.02
565.4185791	100.00
566.4608765	6.93
573.4380493	0.02
574.2731323	0.01
576.1434937	0.01
578.1132812	0.02
578.9780273	0.12
581.6179810	0.05
585.4777832	0.01
593.4518433	0.08
594.6492310	0.03
597.0977173	0.01
612.3444214	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.1072
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8839417	17.57
163.8915405	0.15
214.8977203	0.07
263.0505981	0.06
285.0489502	0.10
301.0654297	0.09
312.9776001	0.05
315.1898193	0.05
326.3816528	0.20
332.6098633	0.02
337.0891724	0.19
346.1676025	0.14
352.2279053	0.03
355.0126953	11.46
356.1933594	0.21
360.8507690	0.06
364.2712402	0.07
377.8977661	0.06
379.2140503	0.54
381.8628540	0.40
396.3669434	0.15
407.3101807	0.11
409.0940552	1.10
409.9987793	0.14
411.2380371	0.04
417.3814087	0.08
419.3156128	0.03
422.4912109	0.07
439.3888550	0.10
462.7849121	0.25
465.4906006	0.05
478.0298462	0.06
480.9989014	0.14
483.3771362	0.30
485.2910767	0.10
493.0243530	0.05
494.8700562	0.21
498.6881714	0.03
499.4066162	0.04
522.6488647	0.15
530.6671143	0.13
532.6832275	0.12
539.1701050	0.07
540.2883911	0.06
541.0578003	1.01
543.4837646	0.03
553.4360962	0.14
569.2985229	0.26
570.5666504	1.04
571.2039185	4.56
583.2429810	0.19
586.7522583	0.17
589.0436401	0.48
599.0571289	0.03
600.1998901	0.02
601.2006226	1.40
603.1524048	0.08
709.3829956	0.11
718.0801392	0.57
718.9110718	0.18
744.2300415	0.13
744.9175415	0.07
761.0956421	5.41
763.0160522	100.00
764.1143188	2.81
790.1111450	0.05
803.2258911	0.16
854.6184692	0.13
952.7636719	0.44
953.7926636	1.32
954.8313599	2.73
955.9700317	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3226
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
165.9006958	0.58
169.0814056	0.05
174.9720764	0.14
183.9816742	100.00
197.9301147	0.04
201.2425995	0.06
208.8804932	0.09
227.0503387	0.05
228.0833740	0.08
237.3862000	0.38
251.0795898	0.09
258.1271362	0.09
270.3822632	0.09
295.6804199	0.44
307.2990112	0.12
315.7418823	0.23
318.5628052	0.07
323.3096313	0.05
338.2412109	0.03
352.2672729	0.09
353.6434326	0.04
380.5055542	0.13
387.2567749	0.24
423.0303955	0.08
426.9099121	0.12
428.0336304	0.09
439.3912964	0.07
443.6731567	0.06
444.4338379	0.05
453.7842407	0.11
461.2620850	0.04
464.5021973	0.11
475.2894897	0.04
476.7144775	0.37
481.8558960	0.10
482.7562866	0.07
484.7943726	0.17
486.8755493	0.17
487.6273193	0.03
488.4426270	0.37
500.4026489	50.79
501.0435181	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
159.0708923	6.71
174.2014618	20.83
184.5260315	11.39
211.2282562	14.63
227.0731201	4.26
233.0111389	5.97
277.0714417	17.56
281.2810669	3.02
282.401123	28.17
285.1801758	2.44
290.1670532	13.00
294.2693481	15.58
309.5012207	9.73
324.0648804	18.62
338.5269775	37.93
357.0999756	27.90
385.0585327	28.59
397.0525513	6.15
399.336731	3.02
408.1937256	21.21
436.1114502	7.02
445.5223999	5.22
464.9212036	5.97
473.4615479	28.28
483.6989746	9.42
500.2158203	42.51
501.190979	100.00
501.9161987	13.14
502.9428101	18.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	350.1621
Annotation	Unknow
Peak:m/z	Relative Intensity
104.9843826	0.48
106.8022003	0.16
110.9622498	0.64
114.9344635	5.01
118.9208450	0.82
121.8898315	23.18
122.8367996	0.04
125.2377777	0.34
134.8233490	0.10
136.1289062	0.05
137.0391846	0.91
140.8575134	0.07
147.1752319	1.36
151.1901245	0.49
153.1269836	0.06
155.0500183	7.29
158.0542908	0.04
161.1157532	0.20
164.9014282	0.73
167.1853027	0.20
170.8614960	0.28
174.9866333	1.18
180.9498596	0.39
183.0428162	1.03
185.0828705	0.09
188.3307953	0.47
190.1860046	0.03
190.9710846	0.10
193.0697632	4.15
199.1072998	0.35
199.9762421	0.19
206.1116333	0.08
207.9968872	0.12
209.2608032	0.22
211.0325470	100.00
211.6781769	0.09
214.3279419	0.11
221.9610596	0.21
223.9957275	0.12
225.1750793	0.30
227.2023926	0.68
229.0401917	21.84
229.8522949	0.18
238.2657471	0.44
243.2367859	0.14
245.0670776	1.05
247.3114014	0.04
248.1373596	0.15
253.0354614	0.16
258.1780090	0.20
259.9526367	0.07
261.2435303	1.37
263.4196777	0.23
265.2152710	0.17
267.1669312	0.11
269.1411133	0.21
271.1962891	0.21
274.0665894	0.20
276.0648804	0.05
282.9151001	0.36
284.1842651	0.11
286.2304688	0.10
287.2769165	0.35
288.0939026	0.52
291.9691162	0.05
301.9785767	0.07
304.1295166	0.86
305.0772705	0.59
306.1251221	0.20
307.1418457	0.13
309.3445435	0.05
311.3430786	0.08
314.7064819	0.26
319.0559692	0.09
322.4057617	0.17
331.3294678	0.77
332.3015747	4.03
333.1666260	2.65
341.0198669	0.47
341.8446960	0.75
349.3892212	0.05
355.2947083	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	477.1913
Annotation	Garcinisidone D
Peak:m/z	Relative Intensity
133.9618988	2.26
135.0306244	0.83
146.8584900	6.23
163.4359894	0.98
164.9149780	10.11
178.5395813	0.22
183.0542145	100.00
183.9192657	0.48
228.3769531	0.36
297.0634460	0.65
315.0507202	0.17
318.8356934	0.15
326.9079285	0.93
343.6453857	0.41
344.7229614	6.75
345.4309692	0.63
419.1692200	0.15
433.9584961	0.54
437.1475220	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1349
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.7346344	0.28
163.9231262	0.04
165.0126038	0.17
167.1266785	0.07
173.1112823	0.05
174.9975281	0.31
176.9212494	0.22
178.8794098	0.13
185.2763367	0.32
187.1431580	0.88
188.0491333	0.12
199.0847626	0.08
201.2597198	0.04
202.5128937	0.42
203.2351990	0.88
203.9906769	0.03
205.1063232	0.66
212.0645752	0.10
215.3363037	0.03
217.1444092	0.82
221.2700195	0.09
226.9898224	0.21
229.1672058	0.28
231.1501160	0.32
235.2009277	0.90
241.1736298	0.07
243.1926575	0.25
243.8627625	0.14
245.1215973	3.12
246.2920227	0.09
247.3301392	0.07
250.3331299	0.04
255.1749115	1.05
256.1371155	0.08
261.0354614	0.28
268.9929199	0.54
271.3567810	0.33
273.1535034	6.07
275.7103882	0.26
281.3191833	0.24
285.0779114	0.50
287.0971680	11.24
289.1601562	31.70
290.2188721	0.22
294.2189331	0.03
295.4841309	0.27
297.2004395	0.24
297.9731445	0.06
299.1940613	6.92
302.0742798	0.06
305.2523804	0.05
321.1066895	0.16
322.0367432	0.12
328.8480835	0.34
330.5345459	0.07
331.1971436	0.50
339.1372070	1.71
341.2425537	0.66
344.3261719	0.07
356.9982300	0.70
361.2759399	0.06
363.3920288	0.11
365.1642456	0.29
367.0333252	0.05
369.4249878	0.18
372.3486328	0.19
381.2098999	3.12
389.5103760	0.17
395.2740479	0.30
397.3447876	16.99
402.2188110	0.11
403.4572144	0.08
405.8787842	0.63
407.1679077	100.00
408.2413940	0.29
409.2046509	1.12
410.2459717	0.28
411.1798706	0.18
413.1546021	0.42
414.2312012	0.52
415.5413208	0.68
417.5993042	0.05
421.3876343	0.11
423.2388916	1.03
425.1569214	85.57
427.3364258	0.18
428.1655273	0.06
429.1524658	0.20
433.1834106	1.20
436.2337036	0.05
437.2041016	0.58
439.2875366	0.12
441.4490967	0.11
443.2802734	0.11
449.0902100	1.40
451.2110596	28.04
452.2996216	0.06
453.2193604	0.04
454.1753540	0.22
457.5144653	0.06
461.4678345	0.05
463.2276611	0.11
465.4730835	0.26
467.1789551	1.11
470.4512939	0.12
475.1814575	0.05
482.2741699	0.64
485.5709839	0.07
491.3354492	5.30
492.2263794	1.04
493.1174927	0.25
497.4948120	0.08
500.2824707	4.92
501.1331177	0.78
502.2210693	0.21
504.3005981	0.06
506.7850952	0.15
513.9003296	0.17
515.6683960	0.06
517.5004883	0.18
520.9118652	0.06
521.6870117	0.04
522.4303589	0.08
531.2314453	0.46
532.3049316	0.15
533.3739014	1.25
534.2163086	0.08
539.4019165	0.45
540.3211670	0.42
541.2731323	0.24
543.2517700	0.24
548.0427246	0.31
549.4152222	0.12
557.0971069	0.21
559.2768555	9.03
560.6550903	0.20
561.2995605	0.09
569.2755127	0.08
576.5222778	0.11
578.3789673	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8295593	1.70
207.9117584	0.23
290.7294922	15.60
292.7648010	12.96
348.9010010	0.16
354.9567261	0.25
374.0390625	0.52
374.6796265	2.19
376.4247437	3.53
377.0325317	0.60
381.7587891	0.90
458.6111450	13.41
459.9154663	16.41
460.7481689	57.59
466.2889404	0.18
542.5695801	20.15
543.6135864	24.87
544.6467285	100.00
581.9402466	1.04
582.7459106	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.9005585	0.43
106.8243256	1.11
108.945343	0.70
110.807106	0.18
118.842392	0.40
120.9496613	3.34
121.8079758	0.30
123.0017853	0.53
124.9705887	0.16
126.7686462	0.36
130.9789124	0.19
132.9861298	0.63
135.0571899	4.31
137.0099182	2.14
142.9649963	1.50
144.7110901	0.09
146.9727478	3.00
149.0267334	1.95
151.03125	1.85
155.1819916	0.10
155.9342346	0.63
156.9445496	0.37
158.8864746	0.10
161.0140991	1.57
163.0166931	1.54
164.7952118	0.50
165.6985168	0.28
167.2619629	0.07
168.8448334	0.56
171.0103302	0.53
172.8519592	0.91
175.1855164	1.40
176.8660583	0.07
179.1021118	0.40
182.1419373	0.07
183.0582733	0.51
184.7232361	0.20
187.0707092	1.36
189.0452271	0.24
193.1373444	0.09
196.0948334	0.37
197.1863251	0.61
201.0518188	0.65
202.8965149	0.51
204.965271	0.45
206.9281464	0.38
208.9934998	0.44
211.1923523	1.36
213.1801453	0.24
215.069397	1.23
217.1507874	1.72
218.7489014	0.24
223.2654724	0.57
225.203125	0.41
227.1430359	0.49
228.8502502	0.46
231.096283	0.31
237.1582336	0.39
241.0415344	0.98
245.041687	2.75
247.1192322	2.41
253.0889893	0.99
254.5356445	0.39
257.4497375	0.19
259.227356	0.39
260.2051392	1.02
261.5070801	0.19
264.7105713	0.05
265.3250732	0.14
267.1907349	0.25
271.2782288	0.78
273.2661133	0.12
275.3698425	0.35
281.3579102	0.40
283.391449	0.47
284.1209717	0.20
285.1216431	0.68
287.3851318	0.27
293.9330444	0.13
295.1201172	0.98
297.5123596	0.17
299.2182617	1.60
300.3399658	0.24
305.258667	2.02
310.5505981	0.06
313.2827148	0.29
314.2190247	0.13
323.2453003	100.00
324.3623047	0.70
325.4833679	0.53
340.9988708	0.85
341.6595764	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.1384
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
217.0236969	0.61
289.3637085	0.71
303.1854248	0.93
309.2702332	0.73
313.1195984	0.51
319.2464294	1.14
328.1556396	0.38
353.0910645	5.81
378.913147	0.96
387.2598877	0.27
391.1936035	100.00
396.7748413	0.72
446.9779053	0.93
477.3182373	0.49
479.0855713	0.20
487.3867188	0.57
505.352417	0.37
516.40271	0.78
535.2418823	0.85
543.2181396	0.15
553.2307739	7.19
563.3120117	0.18
565.1359253	4.61
571.1245728	2.36
583.1784668	3.55
668.0307617	0.96
698.2966309	1.10
709.4678955	0.94
713.6417847	1.27
726.7583008	1.92
727.4234619	10.86
745.1314697	43.20
745.8513184	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.14
Annotation	(+)-Abscisic Acid
Peak:m/z	Relative Intensity
79.04917145	0.66
80.91527557	0.46
85.02516937	0.84
94.79949951	1.39
96.9521637	2.82
97.99403381	0.31
98.88873291	1.76
100.69487	1.08
107.013443	2.43
108.9245148	2.56
110.8607178	2.99
112.0662384	1.60
116.6908417	0.54
119.0958862	1.20
121.0473938	0.37
123.1120605	1.31
135.1514587	0.82
139.0631256	3.76
144.9851379	0.93
146.9742279	0.95
148.8913269	1.55
150.9695129	1.72
153.1267853	2.45
155.2365723	3.19
159.1628265	1.11
162.9245758	3.15
165.0205994	0.54
168.9819794	2.73
170.9395294	1.27
173.0117493	0.60
175.0704956	3.52
176.2402649	2.61
177.133728	2.19
178.1305389	4.94
180.9481659	0.48
185.057663	1.55
187.2501526	2.71
188.954422	12.43
189.6972046	2.79
191.1607513	1.79
193.07164	2.15
195.1090851	1.36
199.3092499	0.42
201.0836792	5.10
203.103653	5.17
204.9188385	3.66
206.2863007	0.24
207.1094818	2.18
208.8451538	3.23
211.9468994	0.46
215.1375885	0.79
216.4116669	2.85
217.0843048	0.53
219.0084534	9.66
220.2143097	1.66
222.1669464	2.00
223.2173615	3.50
223.9494476	2.26
229.1850433	5.99
235.1157074	4.86
237.265213	6.70
244.9116669	2.87
246.3297882	2.71
247.1259766	100.00
248.0493317	9.67
248.6749268	0.26
252.4155884	0.34
255.5217743	6.97
265.3275452	1.52
269.9556885	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1427
Annotation	Enokipodin C
Peak:m/z	Relative Intensity
94.83831787	2.41
130.8700256	1.23
135.0448151	1.70
137.2019348	12.14
139.1671295	3.44
169.2207642	3.77
171.0121307	1.36
180.9646606	1.36
191.1305695	7.19
194.7779694	4.30
205.0532379	9.88
211.1829071	9.45
216.9635925	2.62
219.04039	5.07
229.2743378	1.62
238.1295929	2.34
247.1415405	100.00
249.0231323	6.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	238.0356
Annotation	Tridentatol A
Peak:m/z	Relative Intensity
77.9702911	0.66
114.9386597	0.88
121.8653412	100.00
136.8525238	0.14
166.1805573	0.05
167.1063080	0.07
178.0778809	0.17
193.0235138	0.04
193.9339142	0.25
205.0859833	0.05
209.3828278	0.03
217.8728180	0.05
219.7725830	0.19
223.2617340	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3148
Annotation	Unknow
Peak:m/z	Relative Intensity
233.4771576	0.07
235.2900085	0.03
242.0772705	0.18
259.4759827	0.09
271.3235168	0.02
277.3106079	15.51
300.6050720	0.11
356.3841553	0.09
365.6785278	0.14
386.0308838	0.13
457.5991821	0.24
466.1113892	0.02
472.4705200	0.05
488.4659424	0.07
502.3446045	100.00
503.2227783	0.19
535.4208984	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.1717
Annotation	Unknow
Peak:m/z	Relative Intensity
140.9789734	0.44
155.0637817	7.32
155.9441833	0.07
159.2424622	0.09
175.1302185	0.09
177.0737610	5.34
191.1069031	0.20
199.0983276	19.08
200.2279816	0.39
206.1977234	0.12
221.1553650	0.60
233.3229675	0.18
237.6284332	0.31
241.0854645	1.10
245.0187683	0.55
255.8666382	0.06
257.3723755	0.18
265.2569580	0.19
281.1605530	0.27
287.2823181	0.05
300.9213257	0.07
302.0529175	0.21
303.1106567	0.09
303.9435730	0.16
313.3375854	0.10
315.3019104	0.58
317.2095032	6.25
322.9256897	0.05
331.2580872	0.29
333.2067871	0.76
341.1357727	1.13
343.2530823	0.10
347.1008301	0.06
353.1206665	0.37
357.3357239	1.05
359.2564697	74.51
361.3152466	0.27
362.3980408	0.09
366.2194824	0.11
369.2362671	0.12
372.7263489	0.07
375.1072388	0.07
377.2473145	100.00
389.2645874	0.11
391.2412415	0.27
393.4788513	0.13
394.1621704	0.17
399.4306946	0.06
403.2648621	0.18
410.1861572	0.17
415.3148193	0.42
416.2369385	0.08
419.2302856	6.00
421.1199036	0.56
431.1195984	0.38
433.3249207	1.07
448.2301331	0.69
449.5359192	0.42
451.3509216	0.65
458.4440613	0.21
459.4008179	0.28
462.1099548	0.21
463.3577576	0.99
467.2303162	0.20
477.2325745	58.75
477.8893738	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	302.04
Annotation	Cyanofenphos
Peak:m/z	Relative Intensity
88.0301285	1.03
95.0050812	1.01
95.8678284	0.18
97.0162811	0.17
112.9261780	14.37
113.9602051	4.13
114.8818970	2.72
130.9217834	100.00
131.9176331	88.18
152.9572144	0.16
158.7859955	0.05
167.2068787	0.05
182.3499756	0.12
203.2262878	0.04
204.2455444	0.07
211.0935974	0.11
212.0690002	0.10
239.8340759	0.05
242.0897217	2.73
253.4719849	0.12
255.2290039	0.07
257.1973877	0.21
273.3239136	0.08
283.1080933	1.32
284.1608887	3.02
285.1618652	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	583.2523
Annotation	Biliverdin
Peak:m/z	Relative Intensity
167.0612335	0.32
171.0461731	0.15
172.0012512	0.03
181.1768494	0.10
183.2380981	0.02
184.0211487	0.08
186.1271515	0.08
187.2288818	0.09
191.8921509	0.14
192.9137268	0.10
194.1300659	0.27
194.8642883	0.26
195.9279785	0.21
197.1708679	0.28
198.0902557	0.38
199.2471313	0.11
205.3785706	0.19
207.0781250	0.11
209.0446472	3.30
210.1273651	1.85
211.1968384	0.34
212.0276642	0.14
213.0562134	0.40
216.2063599	0.14
217.0579987	0.03
219.1770325	0.12
220.8763123	0.04
222.2601776	0.15
223.1644440	0.20
224.2881622	0.48
225.0870514	0.55
226.1466370	0.09
227.1665497	0.24
228.3838501	0.33
230.3568726	0.04
235.1755371	0.41
235.9728088	0.37
237.1374207	1.98
238.0971680	2.16
239.1594849	0.39
240.2214050	0.13
241.3749695	0.58
242.3310547	0.43
243.0520935	0.12
247.3025513	0.13
248.9161987	0.03
250.2203827	0.02
251.3181152	1.22
252.0369568	0.17
253.3210144	2.31
254.2662354	0.94
255.1271667	0.72
256.1791992	0.28
257.1320801	0.03
263.2252197	0.04
265.1249390	0.16
266.0728455	0.15
266.7950745	0.06
268.3710632	0.37
269.2136536	4.50
270.2262878	0.68
271.2189941	1.36
272.0610352	0.17
273.2579651	0.16
274.1774292	0.13
275.1053162	0.10
278.2029419	0.09
279.1231689	0.13
280.1369019	0.25
281.1657715	0.55
283.5217285	0.04
284.3200989	0.29
285.3283081	0.99
287.4834595	0.37
289.2830200	0.16
293.2507324	0.06
295.1589966	0.43
297.1984253	100.00
298.2392578	16.10
299.2183228	12.32
300.2799072	1.19
301.2395630	0.51
307.3864136	0.11
309.1798706	0.53
311.2256470	0.06
325.3784790	1.07
334.1897583	0.20
335.5470581	0.18
342.9495850	0.26
349.3801270	0.04
350.1966553	0.18
351.3423462	0.04
352.0796509	0.17
357.1270752	0.19
358.0086060	0.06
362.4770508	0.08
364.2554321	0.15
367.4689331	0.17
369.3688354	0.04
370.1608276	0.10
372.3850708	0.17
374.4102783	0.06
376.9390869	0.04
379.3809204	0.03
380.5198975	0.06
381.5016479	0.20
383.8534546	0.12
386.3135986	0.03
387.3894043	0.03
388.2026978	0.36
393.3446045	0.69
394.4683838	0.13
395.3868408	0.14
400.0578003	0.10
401.5621338	0.05
402.2778931	0.19
402.9192505	0.35
403.6438599	0.29
404.7486572	0.19
407.3203735	0.05
412.5864258	0.37
414.5256348	0.08
416.4071045	0.36
417.6658325	0.16
418.5702515	0.40
421.2675781	0.08
426.8460693	0.20
428.3750610	0.26
430.9258423	0.39
431.5353394	0.02
432.3334961	0.20
434.2064209	0.09
435.3646851	0.06
436.5462646	0.07
440.5582275	0.11
441.3157349	0.07
442.3510132	0.08
443.4177246	0.20
444.4268799	0.23
446.9680176	0.26
447.5726318	0.16
448.3069458	0.26
449.2258911	0.11
450.3020020	0.37
451.4001465	0.79
452.4079590	0.22
453.8170776	0.28
455.6290894	0.13
458.6243286	0.33
460.1785889	0.32
460.9031372	0.21
461.5543213	0.57
462.8538818	0.11
465.4366455	0.04
466.2741089	0.65
467.4091187	0.12
469.4754028	0.16
475.2550659	0.24
476.5444336	0.93
477.3774414	0.65
480.5042725	0.05
481.3386230	0.59
482.2822876	0.28
484.7015991	0.18
486.9846191	0.05
488.1128540	0.32
493.6079712	0.45
494.6117554	0.13
495.4679565	0.23
496.3979492	0.28
502.4879150	0.30
503.2077026	0.15
504.9780884	0.03
505.5781250	0.21
506.3076172	0.03
507.3598022	0.04
509.0263672	0.32
510.4349976	2.72
511.3386230	0.64
515.5380859	0.08
520.5050049	0.35
521.2844849	0.28
522.4487915	0.37
524.1975708	1.71
524.8500977	0.14
525.5994873	0.09
527.1569214	0.09
529.5366211	0.21
530.4060669	0.09
531.5267944	0.13
536.5848999	0.15
537.6058960	0.72
538.4954224	0.83
539.4300537	2.71
540.3906250	3.07
541.3724976	0.31
547.1947021	0.15
548.3873901	0.21
549.2411499	0.09
550.6869507	0.09
551.8109741	0.10
554.1720581	0.04
555.5248413	1.51
556.5200806	0.33
565.4308472	15.85
566.4909058	8.23
567.5498657	0.67
568.5203247	0.06
569.2463379	0.17
584.8441772	0.07
585.6408691	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	372.0934
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
119.9945526	0.09
121.5971527	0.05
147.9412384	0.13
150.0745392	0.20
163.9359894	100.00
164.5600281	0.86
171.8834839	0.12
178.0218201	0.12
187.1713715	0.06
191.0379791	0.09
192.1456604	0.45
193.7182922	0.08
201.0778809	0.20
209.9355164	0.12
211.1350403	0.42
266.1606140	0.11
268.2216187	0.26
276.2906494	0.19
279.0742798	0.60
280.9800720	0.38
286.2672119	0.11
299.3891907	0.14
312.0430908	0.17
313.2365417	0.37
314.0266113	0.32
323.9227295	0.26
326.0274963	5.18
327.1484680	0.30
328.2814331	0.33
341.5165710	0.52
351.4136047	0.10
352.0746765	0.43
353.3664246	0.17
354.1218567	0.87
355.4077454	0.04
362.3396301	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	618.1757
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1872253	0.36
250.7761536	5.37
256.3205872	1.16
269.0365295	4.44
323.0321045	1.00
323.6831055	0.79
349.9808960	8.08
350.5936890	0.46
379.1250610	3.73
403.9959106	4.74
404.5969238	0.26
406.1017456	2.17
417.7088013	0.73
433.9364014	1.73
470.6262207	71.11
471.7263794	1.73
472.5658569	3.79
473.3576050	3.99
474.2746582	2.16
475.4517212	1.00
478.2141724	2.94
482.2013550	1.51
512.0349731	11.51
515.4863281	0.39
538.9445190	1.09
644.4559937	23.56
645.1351929	100.00
646.1741333	10.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1475
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9864502	1.24
165.1004639	1.01
168.9722748	0.07
172.8942566	0.18
175.0425873	0.13
177.1391449	0.11
179.0234375	0.33
180.7949524	0.04
183.1219330	0.29
184.7783813	0.29
186.9737549	0.51
188.9532318	0.18
190.7723846	0.45
197.0435486	0.29
199.2033997	0.09
200.9850769	1.21
203.2371979	0.09
205.0708618	0.28
207.3764954	0.14
213.0115356	0.20
215.0982056	0.27
218.2097168	0.17
219.0196075	0.11
224.9826355	0.29
229.1279907	2.45
230.0403748	0.04
231.0907898	0.77
233.0435791	1.12
239.3107147	0.04
243.0613403	1.45
245.2072296	0.15
247.1272888	29.12
249.2221985	0.10
253.1238403	0.58
257.0960693	1.45
259.0303955	10.26
261.2275696	0.21
269.0367432	0.21
271.1151428	11.68
273.1258850	1.16
275.1052246	16.42
283.1237793	6.08
285.0225220	1.03
287.1145020	10.86
287.9122009	0.20
289.1656189	27.19
291.0761719	52.35
295.1933594	0.19
297.2988281	0.36
299.1094360	3.16
301.1285400	27.18
303.1050415	10.73
313.0452881	0.61
315.1949463	0.52
317.2143555	0.36
324.9771729	0.11
331.1727905	0.19
333.1918335	2.09
355.1093750	0.07
367.2681885	0.16
379.1093140	0.27
391.0974121	0.04
393.2743530	0.45
398.4389038	0.05
409.1679077	96.30
411.2650757	15.10
417.2639160	0.73
419.3629150	0.05
421.2382202	3.96
423.1731567	1.33
425.5723877	0.18
427.1328125	100.00
433.2210083	0.10
435.2611694	3.98
439.1542358	5.34
451.1856079	0.54
453.0131836	5.03
467.4359131	0.07
542.3322144	0.49
543.2924194	2.82
561.1202393	5.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1012
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9905853	0.06
116.9758759	1.01
135.0175476	0.75
139.0041504	0.02
144.9503479	3.19
146.7594452	0.01
157.8879089	0.04
162.9104004	100.00
163.6692810	0.00
181.0160828	0.08
192.8202209	0.07
212.9622345	0.03
327.0655518	0.03
337.2110596	0.32
338.1164551	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0038300	0.40
268.3085327	0.28
270.3840942	0.10
298.1309204	0.02
302.9648132	15.67
362.8138428	0.07
374.7776489	0.16
378.0931396	0.34
379.3729858	0.11
380.1892090	0.32
381.0779419	0.11
384.8004761	0.17
386.8045044	61.47
392.8990479	0.02
399.8444214	0.12
442.1614380	0.18
444.1916504	0.83
470.7718506	100.00
479.1358032	0.10
490.9328003	0.29
526.1352539	0.16
536.8734741	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8278198	2.61
219.0042725	0.47
261.0772705	0.11
272.9191895	0.21
296.1756592	2.91
296.8038940	32.29
297.4288330	0.11
303.0289917	2.82
309.2371826	0.85
333.1299438	2.06
334.1075439	3.57
335.5368042	0.48
352.9443359	0.86
374.7209473	0.47
378.4009399	0.13
380.6784668	99.14
386.8479614	4.45
401.1552124	0.09
412.9929810	1.03
424.8922119	2.80
428.7398071	3.50
442.8141479	0.71
449.0528564	0.40
462.1633911	2.16
463.0099487	0.88
464.0230713	13.50
464.7119141	100.00
466.7044678	8.17
470.5886230	8.04
484.8904419	1.27
488.9636841	0.61
496.7098999	4.50
503.2047119	0.08
508.4020386	0.32
512.5278931	3.25
513.1784058	0.17
526.7445679	2.62
538.5615845	0.22
545.9717407	3.46
547.8765259	9.04
548.6003418	82.16
549.2625122	0.67
556.5244141	1.86
567.2918701	0.18
568.9352417	0.98
572.8947144	1.35
586.5181274	3.76
615.0173340	0.68
632.5871582	3.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0718
Annotation	Corynether A
Peak:m/z	Relative Intensity
83.11450958	0.03
97.01483154	0.50
106.9437943	0.02
109.0259323	1.21
121.1022491	0.03
123.0219269	0.39
124.9853287	2.08
134.9282227	0.25
136.9151611	3.12
138.9745483	0.37
142.808075	0.07
144.9470215	0.12
148.9882202	0.03
150.9315948	1.97
159.0430603	0.35
161.0655212	2.78
162.0827332	0.55
162.9671783	0.23
164.0826416	0.75
165.0533752	3.35
167.027832	0.90
172.9830017	0.06
173.9702148	0.06
175.00354	1.04
177.1424866	0.23
179.0325623	9.98
180.1080933	0.02
180.9972382	0.15
185.175415	0.18
186.0754852	0.28
187.0037994	1.94
188.0083313	1.30
190.3862152	0.02
199.0880737	0.05
201.2051697	0.87
202.3284607	1.03
203.1704407	8.23
205.0117798	34.44
212.2889404	0.14
217.1159363	0.54
227.0681763	2.35
229.2498474	0.10
230.1142578	0.53
231.1083069	7.42
245.0892334	100.00
245.7984619	0.47
247.0884399	5.51
271.1965637	3.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
917.6130981	20.83
967.446106	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	660.1674
Annotation	Unknow
Peak:m/z	Relative Intensity
187.2144318	0.40
188.8321838	0.32
190.8973999	0.19
191.9643097	0.18
193.0650024	2.93
194.0688171	0.81
194.9821777	2.53
199.1104889	1.55
202.1320190	0.60
206.9539490	9.08
208.1062927	5.87
209.1163330	2.04
211.0672302	2.71
212.2037811	0.25
219.0851440	2.54
220.6014862	0.88
221.2389069	0.80
225.3417816	0.13
231.3361206	0.81
235.9099426	9.57
237.1044922	3.17
237.9769135	0.18
239.0283203	0.47
251.0391693	0.54
256.0474854	0.39
257.1192322	0.44
258.0908813	0.21
263.9539185	100.00
265.0442200	13.74
274.1410828	2.37
275.1377869	0.30
275.9818115	0.15
297.0545044	3.16
298.3157349	1.03
301.4858398	0.25
318.8211060	0.31
320.7709961	0.53
322.0046387	3.73
323.2295532	0.15
339.0001831	7.55
340.1246948	2.22
347.1634521	8.45
348.1806641	2.15
349.2906494	1.35
357.0377197	0.21
365.2035522	4.12
366.1665649	0.36
370.3354492	0.21
375.3186646	0.65
386.7318726	0.20
387.8777466	0.54
393.0440674	31.33
394.1769409	7.87
404.9213867	2.43
405.9190063	0.86
423.2374268	1.85
424.0787354	0.41
428.2088623	2.96
429.0654907	1.19
450.2426758	2.18
451.2421265	1.71
468.0861206	17.64
469.2122192	4.74
484.9088745	0.24
486.3103638	0.58
496.3316650	1.03
513.3026123	4.34
514.2702026	1.07
531.1657104	39.88
532.2277222	7.14
539.5601196	0.53
540.3813477	0.22
543.5127563	0.21
567.2626953	1.03
579.2512817	0.29
585.2359009	46.21
586.3724976	14.68
596.9124146	0.51
598.3807983	0.17
642.2261353	4.73
643.2706909	6.91
644.2756958	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	599.2921
Annotation	Unknow
Peak:m/z	Relative Intensity
181.2464294	0.14
213.1062012	0.16
221.0242920	0.05
229.3966522	0.05
232.9697876	0.08
244.9305267	0.08
257.2102966	0.19
258.2170410	0.04
263.5516357	0.12
269.3566589	0.05
273.4088440	0.03
274.0115051	0.04
275.3208008	0.72
288.3895874	0.18
289.3885193	0.20
299.4614563	0.03
317.1345215	0.09
319.2609253	0.04
321.1401367	0.08
335.6749268	0.02
357.2958374	0.18
361.2761841	0.02
363.1905518	0.34
372.2417603	0.11
375.3842163	0.40
383.3074341	0.39
391.0748291	0.05
401.3621826	2.03
403.2193604	0.04
406.4017944	0.02
407.3294067	0.12
411.4750366	0.04
419.4147949	27.57
421.3685913	0.31
437.3876343	7.63
443.2308350	0.12
447.0684204	0.18
461.4607544	0.16
465.2538452	0.03
479.4010620	0.31
489.4634399	0.12
493.1077271	0.15
497.4854736	0.25
511.4874268	0.11
514.3373413	0.02
521.4694214	0.08
523.3026123	0.23
525.4492798	0.37
530.8056030	0.45
537.4921265	0.08
545.3882446	0.37
553.4199219	0.52
563.4223022	6.34
576.4798584	0.09
579.4097290	0.08
581.4735718	100.00
582.5135498	0.97
599.5294800	0.53
600.5324097	3.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8077087	23.99
288.0015259	0.02
290.7282715	100.00
291.3606873	0.41
296.7889404	0.04
321.1064148	0.08
348.1990967	0.22
374.6781311	20.68
404.9331970	0.03
459.0027466	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0719
Annotation	Gerfelin
Peak:m/z	Relative Intensity
93.0366211	0.08
96.9464264	0.10
106.7062225	0.03
108.7939453	1.21
111.1073761	0.02
120.9808807	0.03
123.0024567	0.36
124.9818420	3.22
133.1410675	0.06
135.0266418	0.60
137.0506134	2.86
138.9729309	0.03
144.3807373	0.15
146.9701538	0.05
149.0306244	0.17
151.0285645	1.27
159.0556030	0.81
159.7839661	0.06
161.0473785	2.68
162.0523376	0.26
163.0494232	0.21
164.0510254	1.01
165.0253296	3.29
166.0133667	0.03
167.0883789	1.38
173.0488281	0.06
174.0310974	0.03
174.9421844	0.73
177.1047516	0.13
179.0644684	11.41
180.0553284	0.12
184.0474548	0.11
185.0618896	0.16
186.3193359	0.84
187.0482941	1.09
188.0389099	0.71
199.0868835	0.12
201.1544495	0.50
202.0189514	0.24
203.0661316	7.98
205.0102234	31.99
212.3517456	0.08
217.1805420	0.91
221.1910400	0.18
227.1466064	1.65
228.1395874	0.03
229.1820374	0.41
231.0164185	6.32
243.1364746	0.05
245.0997314	100.00
247.0601196	6.24
253.1606445	0.01
271.0715942	4.46
271.6960449	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
128.9641571	0.68
143.0656128	0.44
149.1694183	0.33
156.114563	0.80
159.1311951	0.96
165.0005951	0.65
166.8803711	0.29
169.1131592	0.18
171.26091	0.47
173.0382538	1.63
181.0146637	0.53
183.16539	0.63
185.1679688	2.29
187.2081757	1.25
193.2279205	0.23
194.0633087	0.37
201.2918549	0.75
213.3827209	1.13
215.1439514	2.62
221.3302307	0.28
225.3294983	0.46
227.2851257	1.80
229.2903137	2.67
233.1729736	0.46
239.4349365	0.42
241.3813782	0.27
242.3590393	0.32
243.116394	1.05
245.3457031	0.60
255.383667	1.61
257.3233032	1.96
259.5449219	0.40
260.9528198	0.73
263.2922974	1.83
269.1588135	2.78
271.1786499	6.71
273.0181274	0.47
280.9764709	0.92
283.2215576	1.07
285.3182983	5.04
287.0334167	0.44
293.1704102	1.08
295.3801575	1.41
297.5233765	2.32
299.2895508	4.94
305.1309204	0.52
307.626709	0.34
308.7416687	1.21
311.3126221	5.30
313.2068787	2.73
315.2105713	4.88
321.3531799	3.04
323.3552246	10.50
329.425293	0.36
337.1358032	0.70
339.2561646	100.00
339.9705505	1.73
341.256134	14.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7647400	100.00
145.1555939	0.04
151.0394592	0.02
164.6187744	0.05
187.9478912	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.9135
Annotation	Unknow
Peak:m/z	Relative Intensity
196.9968872	0.25
214.0694580	0.56
219.1456604	2.38
228.4518433	0.20
229.3480377	0.09
238.9846191	0.10
251.2993774	0.44
264.0928650	0.09
266.3993835	0.11
282.3206482	0.16
284.2924194	3.84
292.2175903	0.06
297.9713135	0.05
309.5639648	0.31
319.4859924	0.08
321.9882812	0.14
327.2252197	2.05
328.2940369	0.60
329.1663208	0.34
334.3334961	0.11
353.1035767	0.04
356.0678101	0.13
379.0907593	0.08
384.1931152	0.58
389.6849976	0.28
392.9328613	0.22
397.3038330	2.98
410.3165894	0.12
415.2818604	30.93
416.3397827	3.78
436.9364624	0.08
447.1398926	0.22
452.3368530	0.29
454.2048340	0.17
459.4517822	0.12
469.3917236	0.35
478.5150757	0.04
480.1091309	0.25
487.0438232	0.19
487.9269409	0.06
491.7051392	0.34
497.4760742	1.41
498.5378418	0.23
509.0379639	0.07
510.5783691	0.17
513.7300415	0.70
520.8653564	0.45
521.4716797	0.45
523.2936401	0.30
527.7301636	0.51
528.4767456	1.50
529.5663452	1.87
530.2827148	0.14
533.3375854	0.09
534.2892456	0.13
536.3734741	2.13
537.0731812	0.78
542.6225586	0.23
543.3285522	0.17
544.5263062	0.40
553.1970215	0.19
555.7544556	0.18
561.3922119	0.04
564.2765503	0.17
565.0322266	0.29
568.9697266	0.56
572.5830688	0.76
573.5200806	0.44
577.6250610	2.71
578.6341553	0.56
579.5686646	0.80
586.1531372	6.05
587.0917358	0.19
588.5587769	2.91
589.1702271	0.45
594.4277954	0.12
603.2822876	0.10
606.9281616	0.39
610.2178955	0.12
612.0681152	0.21
612.8421021	0.30
614.4120483	0.28
615.6293945	0.24
616.3765259	0.26
620.8611450	3.22
621.5369873	0.90
623.0954590	0.05
624.2576294	0.13
628.3408813	0.09
629.6781616	12.26
630.5669556	0.45
632.9049683	0.06
635.1867065	0.69
638.1403198	0.19
642.4884644	0.43
648.2044678	0.08
649.6594849	0.20
663.4173584	0.11
664.4042358	0.28
668.9552002	0.96
672.0642700	0.37
674.5581665	0.17
676.7360229	1.51
677.5549927	2.14
678.3923950	0.18
679.3634644	0.05
680.9205322	0.08
684.0086670	0.30
696.1562500	0.06
743.3339233	0.05
744.5277710	0.39
747.4834595	0.04
748.6267090	0.52
755.4087524	0.26
763.6231079	0.10
775.3881226	0.09
787.6656494	0.17
815.7634888	0.58
830.5431519	0.07
844.5020752	0.46
846.5797729	0.07
856.5354614	0.06
861.5830688	2.79
862.6008911	1.85
875.6433716	0.24
882.8007202	0.08
892.6759644	1.30
893.8830566	0.53
894.6867676	0.11
905.8488159	0.10
912.7015991	0.10
927.9061890	0.15
931.7760620	0.52
939.5741577	0.05
942.7224121	0.19
946.2465210	0.08
947.6979370	0.29
953.6785278	0.18
957.1152344	0.54
957.8572388	1.27
958.6541138	0.49
974.6767578	100.00
975.6697388	32.68
976.3767700	0.26
1005.8639530	0.35
1006.7496950	0.12
1019.5303340	0.31
1028.8515620	0.18
1030.8659670	0.12
1041.4659420	0.23
1042.7979740	0.14
1043.9705810	0.14
1045.0334470	0.04
1052.6098630	0.10
1062.7181400	3.09
1063.7250980	1.70
1072.8376460	0.27
1084.7436520	0.23
1087.4753420	0.13
1088.7409670	0.33
1142.0129390	0.06
1145.5773930	0.50
1153.7830810	0.06
1155.1208500	0.22
1156.8062740	0.57
1157.8039550	0.34
1159.9116210	0.41
1170.7965090	5.55
1171.8748780	3.39
1174.7691650	0.16
1175.6939700	1.67
1176.8924560	0.99
1223.0247800	0.09
1240.0072020	0.15
1275.7082520	0.08
1284.6802980	0.07
1366.7139890	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
94.86175537	0.69
126.8799744	2.31
148.8144684	1.18
179.0161285	2.50
180.1564331	0.34
188.8713226	0.23
192.8525238	0.57
202.061554	0.30
204.9698334	1.03
206.1371307	0.31
207.0573425	6.92
208.1641083	7.29
209.1136932	1.87
210.1364746	0.58
221.1875763	1.29
222.3549957	12.90
223.2134552	7.19
233.1392212	2.17
251.0755615	100.00
252.1349945	14.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1244
Annotation	Theviridoside
Peak:m/z	Relative Intensity
121.9392395	0.13
123.2522507	0.09
149.9260254	6.38
151.8920593	0.04
153.0126801	0.11
158.9855957	0.30
164.9935150	15.90
166.9631653	0.33
172.8352966	0.17
177.2980194	0.07
179.1465759	0.21
180.2029724	0.76
180.8204956	0.18
191.1925964	0.44
194.9850769	100.00
207.0279999	1.07
210.9239502	0.10
223.1670837	0.16
231.0210571	0.05
240.3616028	0.11
241.1861572	0.31
247.0343933	0.16
254.2678223	0.07
255.1543274	0.11
278.7776489	0.06
280.9545288	0.16
283.2167664	0.04
287.3313599	0.29
290.8478394	0.03
304.9566956	1.78
307.0676270	0.54
313.4450378	0.12
317.1162109	0.11
318.8284912	0.06
329.1866455	0.05
331.0268860	0.06
335.1894226	0.13
339.3999939	0.06
343.0840454	0.34
355.3542175	0.18
356.9928284	1.52
359.1998901	0.29
367.1818542	0.99
375.4232788	0.12
383.2157898	0.79
385.1347046	6.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
148.0318451	0.07
154.8275452	0.02
158.9761658	5.13
160.0186920	1.25
161.0868530	1.26
161.9573975	0.05
171.2070770	0.04
198.9935303	0.51
200.0978394	0.23
201.0071106	0.48
202.1695557	0.06
217.1516266	0.19
218.0250549	0.04
219.2496338	0.09
229.0830994	0.44
229.9537659	0.27
231.0063934	0.80
231.9909363	0.06
271.3142700	0.07
273.0075989	39.91
274.1038818	22.38
275.0313416	46.88
276.0458679	5.75
328.2052917	0.05
345.7639771	0.04
374.2185059	0.02
385.4205627	0.02
387.0476990	29.81
388.1708374	29.17
388.9563904	100.00
390.0415649	23.12
391.9093018	0.03
414.0782166	0.06
418.1958313	0.04
428.8120422	0.02
429.8844299	0.15
430.8127441	0.02
446.9399719	0.05
447.9420776	0.11
457.3575439	0.05
458.4339600	0.13
459.0772400	0.75
460.1973877	0.07
461.0024109	0.04
473.8204651	0.02
474.9308472	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	361.1483
Annotation	Lamiol
Peak:m/z	Relative Intensity
108.9804306	0.19
111.0697937	0.10
112.7634430	0.10
126.5256195	0.22
132.8063965	0.41
137.0165405	0.87
154.6512146	0.43
164.9816589	2.75
181.0975952	0.21
182.3525238	0.30
183.0260468	5.65
188.3061981	0.13
189.2770996	0.34
191.1862793	0.07
196.7972565	0.09
199.1369934	0.19
200.9708862	1.54
212.9414062	0.40
221.0517578	0.12
229.1932068	0.07
231.2482910	0.24
232.1428223	0.21
233.9661560	0.08
235.6708069	0.44
240.7115479	0.18
241.3532104	0.09
247.9855652	0.47
252.9944153	0.13
256.5360718	0.38
269.6613464	0.22
271.3219299	0.47
275.1778259	0.25
284.2339172	0.25
288.8014526	0.67
294.3090210	0.20
297.2266846	4.42
298.8197021	0.07
300.3409424	0.18
301.1755676	0.15
305.3875122	0.34
312.8732300	0.08
314.2071533	0.87
315.1425171	4.44
325.1363831	18.86
325.8619385	0.29
328.4574585	0.11
331.1674500	0.61
332.1623230	0.36
333.3328857	0.25
341.2857971	0.55
343.2018127	100.00
344.3078003	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.2338
Annotation	Rhodioloside E
Peak:m/z	Relative Intensity
176.9418793	0.00
215.0330200	0.01
217.0878601	0.02
241.2548523	0.03
267.3937378	0.01
273.1316833	0.01
284.9552917	0.12
301.1737366	0.04
302.4880371	0.04
303.3370667	0.05
325.3468323	0.01
329.0928345	0.00
335.0498962	0.01
339.2590332	0.03
341.5173340	0.01
360.5062256	0.03
361.1217041	0.02
373.4080505	0.02
401.4186707	0.06
405.5497437	0.01
407.3638611	0.01
419.3562317	100.00
420.2655945	0.02
429.5546265	0.01
444.2551575	0.03
447.1354980	0.20
448.0120239	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1869
Annotation	Unknow
Peak:m/z	Relative Intensity
135.1350250	0.04
142.9953461	0.18
152.0447998	0.14
153.1475525	0.49
154.2294617	0.03
159.3644562	0.03
161.0070496	0.40
165.3197632	0.02
171.1904907	0.05
172.9700012	0.03
175.1007385	0.08
177.2041168	0.07
178.8876953	0.26
185.4267883	0.02
186.1947937	0.06
188.8812714	0.03
190.3005066	0.02
194.7849579	0.02
201.1294250	1.23
202.1266174	0.15
203.2754211	0.08
204.1987457	0.73
205.2461548	0.15
206.9525452	1.16
209.0847473	0.02
211.3611908	0.06
215.4186707	0.01
219.2325745	5.42
220.2260895	0.58
231.0744629	0.21
239.9959412	0.02
241.2046051	0.02
243.2451172	0.21
244.0895081	0.04
245.2288513	0.33
246.4132385	0.05
253.3198242	0.03
259.8865967	0.02
261.2933044	0.01
263.1163330	100.00
264.1951294	12.13
269.2582092	0.04
271.4564514	0.01
273.2077332	0.10
277.2148438	0.32
278.4041748	0.04
282.2389832	0.02
287.2449341	1.69
288.1572571	0.14
289.3141785	0.08
291.1688232	0.03
301.1319580	0.08
305.0582886	4.26
306.0209045	0.65
308.9438477	1.27
309.8309326	0.12
311.1067200	0.05
317.0803223	0.18
324.2744446	0.02
327.3005066	0.02
329.1921387	0.34
330.1797485	0.03
331.2980652	0.02
333.7733765	0.02
335.1201782	0.22
336.0983887	0.02
341.2781372	0.03
344.4273071	0.01
346.9848022	0.02
348.1646118	0.05
352.6228027	0.09
356.3002625	0.01
359.4345703	0.02
360.2969971	0.03
364.7357788	1.27
365.6093445	0.04
371.2149353	0.05
376.5816040	0.04
382.9755554	0.02
384.1852112	0.15
385.1425476	0.07
387.1723938	0.03
388.4671326	0.02
405.6389465	0.01
407.0911255	0.02
408.4737244	0.05
413.5535583	0.07
414.2033081	0.02
424.9526062	18.49
425.9979553	2.11
426.6216125	0.04
427.4310913	0.01
428.3428040	0.12
436.2518311	0.08
439.6932983	0.02
441.0631409	0.03
451.3606567	0.24
452.1882019	0.03
453.1749573	0.09
454.4462585	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0927
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
114.9941330	0.99
132.9745331	2.43
152.9972839	32.04
155.1674805	0.06
159.1097412	0.02
164.8993225	0.03
176.9983826	0.05
179.2075195	0.14
187.1627808	0.05
195.1546326	0.15
197.0622559	100.00
198.7913208	0.03
201.1043701	0.06
213.2515564	0.07
227.2378540	0.05
228.7602234	0.03
233.3378906	0.13
235.2063599	0.04
239.3540649	0.09
241.1778564	0.03
250.9595947	0.46
267.1671143	0.12
269.1981201	0.24
269.9255981	0.10
271.1096191	0.21
276.9364624	0.04
295.1353149	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
118.9806366	0.04
124.9650574	0.01
131.0502777	0.03
178.9368896	0.29
341.1564941	100.00
341.9320679	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.0231
Annotation	Unknow
Peak:m/z	Relative Intensity
78.7813339	8.04
96.8626556	100.00
112.8406982	0.49
113.8703156	0.16
114.9932861	0.22
131.0043640	30.01
169.1659393	0.15
211.0500946	3.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.1714
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0479431	0.92
132.9866943	0.09
139.0749969	1.02
140.9836121	1.87
144.8283997	0.06
158.9837646	0.99
163.1896667	0.15
173.3123169	0.21
177.0312195	7.08
180.4768982	0.16
181.1772308	2.20
183.1231842	4.46
184.0842896	0.05
197.0940247	0.18
199.1382141	3.22
207.1829681	0.55
213.8870544	0.07
219.0479584	0.11
225.1198883	4.90
232.9051514	0.11
237.1147461	0.07
239.1316528	0.15
241.1435547	0.61
243.1046753	47.24
251.1830444	0.23
257.1670532	0.37
258.0558777	0.36
259.1890259	0.25
261.2811279	0.24
264.7563782	1.11
265.3727722	0.78
277.4168091	0.09
282.7662659	0.04
285.2606812	2.85
286.9601746	0.07
297.3126831	0.09
299.3413391	0.12
301.3615723	0.57
311.4355469	0.17
313.3866272	0.05
315.2758179	0.51
319.3033142	0.17
323.9868164	0.06
325.2143250	0.97
326.8776245	0.25
331.0775146	1.58
332.9430542	0.05
341.1151428	0.18
343.3204346	0.15
345.2272034	1.93
347.4145508	0.13
355.4518433	0.10
357.4621277	0.29
359.2210693	5.01
359.8720093	0.04
361.2845459	3.71
367.3172913	0.17
373.6430359	0.05
375.2538452	0.55
377.6499329	0.21
384.2729187	0.09
385.3878784	4.17
388.3520508	0.07
390.1538391	0.20
392.3848572	0.18
394.2088318	0.13
397.8250122	0.13
400.8666687	0.11
403.3281860	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0555
Annotation	Bluensidine
Peak:m/z	Relative Intensity
94.9822540	2.24
96.9870300	0.53
112.9120789	13.41
113.9640427	3.64
126.9895477	0.11
130.8932495	100.00
138.9234619	0.03
183.9506989	0.14
199.0077209	0.09
199.9934082	0.16
203.1021729	0.08
228.8077393	0.04
282.8439026	1.22
283.9979858	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.17
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1296234	0.19
155.0884705	0.12
170.9422302	0.64
173.0840607	0.88
190.9963379	100.00
385.2307129	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.119
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
115.0709534	0.11
120.9557190	0.08
132.9611511	1.04
135.1201172	0.15
135.9092102	0.05
136.9586487	0.05
150.8735046	0.26
153.0102386	0.06
155.2406311	0.07
167.2389526	0.06
176.0600433	0.05
176.8768005	0.07
179.3504486	0.04
181.1346130	0.05
191.0802002	0.21
194.9283142	0.06
197.1424255	21.89
213.3619995	0.03
223.1372070	0.25
241.0555725	100.00
243.1901550	0.13
261.1294861	0.02
266.2020874	0.17
267.2026978	0.10
270.3233032	0.09
271.1998596	0.09
272.4741211	0.03
277.2392578	0.09
280.9369507	0.02
285.2524109	0.13
287.4670105	0.07
293.1035767	0.02
295.0532227	0.04
297.2211914	0.02
299.2747498	0.02
303.4127502	0.02
311.0080872	0.41
312.1630859	0.10
313.2702942	0.11
320.9946289	0.14
321.6528320	0.07
327.2231750	0.14
329.2379150	0.06
337.2600708	0.10
338.3696289	0.13
339.3418579	0.32
342.2223206	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.1618
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9217377	100.00
178.9698792	0.16
243.0311890	1.76
341.4889221	3.89
342.5521851	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.0858
Annotation	9,10-dibromo-stearic acid
Peak:m/z	Relative Intensity
129.0465240	3.02
140.8789062	4.09
148.9829407	2.31
178.7984924	13.31
221.0068512	3.01
241.0121460	3.17
250.6933594	5.75
259.0716858	64.58
276.9870300	19.35
280.7651978	1.89
323.1557922	4.89
341.2089844	100.00
349.3286438	1.99
379.5768433	2.21
421.1840515	37.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	340.1038
Annotation	Indican
Peak:m/z	Relative Intensity
96.8630371	0.42
98.8043213	0.48
100.9543610	0.48
112.9411316	0.95
129.0308838	0.16
143.0608368	0.82
158.9009399	1.64
160.9101868	51.56
169.9838409	0.30
187.8977966	100.00
188.9738770	0.05
293.9545288	64.33
294.6061401	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.19
Annotation	Celorbicol
Peak:m/z	Relative Intensity
81.03929138	9.34
84.96444702	3.51
108.9954834	9.13
111.1002197	4.86
112.7875061	1.42
123.0235138	13.35
143.1129761	6.64
145.127655	8.38
147.0684662	1.80
148.9286652	1.23
159.088028	2.34
166.1335754	6.66
169.1487885	15.43
174.9296417	2.19
176.9786072	2.95
181.1450958	9.17
185.1797333	1.99
193.1699982	9.11
194.0783234	5.95
195.057724	4.24
208.133194	3.44
209.2996063	9.13
221.7900696	2.37
225.1247101	28.51
226.0059052	8.68
235.3187408	7.33
238.5668488	5.23
240.1007233	5.20
250.6755219	12.88
253.1738892	100.00
254.5289307	7.11
272.4151917	6.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.27
Annotation	N-Acetyl-leu-leu-tyr-amide
Peak:m/z	Relative Intensity
163.0697021	0.48
174.7073517	0.33
181.2102661	0.12
187.1183777	0.10
196.0885010	0.28
210.6589203	0.23
223.0989380	0.29
233.1717834	0.61
241.0361938	0.15
253.1339417	0.67
259.1970825	0.19
268.5587769	0.94
269.3310242	3.85
285.6372070	0.12
287.1228027	100.00
289.1826477	0.20
289.9590454	0.16
291.2298584	0.41
297.3925781	0.16
303.2467651	0.17
312.8724060	0.54
321.1723022	0.16
323.2750549	0.14
332.8039551	0.57
349.1756592	0.08
359.1829529	0.90
366.8432922	1.81
367.5533142	0.25
368.1951904	0.26
371.4413452	0.22
375.6756592	0.37
383.1699524	0.47
385.2738953	1.27
402.4975586	0.10
403.1933289	0.32
408.0540466	0.40
421.1634827	0.33
426.8483887	0.12
427.8917847	0.70
429.3274231	0.65
430.1089783	0.90
431.1983337	2.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.1609
Annotation	TyrMe-Nap-OH
Peak:m/z	Relative Intensity
158.970871	0.93
167.9968262	0.81
187.0504913	0.81
231.1319885	0.28
234.9762878	1.38
252.8991699	0.87
268.4658813	0.26
273.8980103	0.35
283.883728	0.26
286.9523315	0.90
289.3452759	0.86
309.1409912	0.47
346.9301758	1.05
363.4480591	0.38
365.0581665	1.69
367.1723022	0.79
385.4396973	0.22
393.2833252	0.20
397.2633057	1.89
399.3635254	0.50
409.2163696	7.64
417.3811035	0.54
423.7960205	0.46
427.4039307	2.25
433.0423584	0.42
449.1494141	0.33
451.1712646	0.59
467.2471924	3.07
469.1616211	100.00
469.8430176	0.26
476.3825684	0.22
477.5375366	0.28
481.2648315	0.91
492.3949585	2.48
493.258667	0.50
495.0220337	0.73
495.756897	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.193
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1805573	0.13
159.0054321	0.22
160.9408875	0.24
176.9597473	1.37
178.8341064	0.02
180.9928894	0.09
182.2075500	0.23
183.2524567	0.04
194.9228821	0.25
196.9313202	0.33
199.1347351	5.08
231.4206848	0.17
238.9298706	0.12
245.3656006	0.05
262.9678040	0.05
266.7279358	0.07
269.1943970	0.06
273.1962280	0.07
287.1204834	0.06
296.1834106	0.03
297.5771484	0.17
316.2025146	0.11
321.3023071	0.04
323.2910156	0.29
326.4370117	0.08
341.2636108	1.10
347.3818359	0.13
349.4860229	0.03
353.2263794	0.05
357.0767822	0.32
359.2473145	28.18
373.0087280	0.05
375.3453369	5.87
377.1900635	11.36
378.0513916	0.18
383.2874756	0.13
391.1986694	0.21
392.2202148	0.34
393.2554932	0.72
409.2796021	0.17
411.4201660	0.11
419.1227417	0.77
427.3984375	0.14
433.1419678	0.15
437.3709717	0.47
439.3390503	0.27
443.2601318	0.11
455.3132324	0.07
459.0460815	0.05
461.3121338	0.10
471.1500854	1.59
475.3325195	0.75
479.3536377	4.70
483.3773804	0.11
493.4879761	1.37
501.3350830	12.33
508.8914795	0.12
509.5932007	0.06
510.7362061	0.05
519.2063599	1.83
525.5476074	0.05
537.2938843	100.00
538.3443604	0.10
556.4050903	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.1452
Annotation	4-Hydroxy-3-prenylbenzoic acid glucoside
Peak:m/z	Relative Intensity
161.0756836	1.08
205.0781555	100.00
366.4727783	4.58
367.0861511	32.20
369.2895508	0.04
386.5160828	0.03
393.3125000	0.03
395.3728027	0.02
398.3995667	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.25
Annotation	Withaperuvin H
Peak:m/z	Relative Intensity
161.1475372	0.34
163.8929291	0.04
173.0823669	0.92
177.0862579	0.16
179.1037598	0.69
183.0365448	0.22
186.1757507	0.04
187.1116486	0.23
187.8886719	0.13
192.0538025	0.16
203.0765228	0.20
205.0901337	0.18
207.4634399	0.06
217.1974640	0.95
219.2393799	0.09
220.7837524	0.04
225.1929016	0.13
226.9382935	0.24
228.5763550	0.27
231.3459015	0.08
235.2034454	3.95
243.2474060	0.25
244.0778046	0.36
245.0958252	2.29
246.1261597	0.05
247.2741394	0.29
253.0582275	0.09
255.3850403	0.13
257.1008911	0.25
262.4460754	0.05
269.0621033	0.25
273.1354980	2.48
274.1990051	0.22
280.8225708	0.22
283.3336182	0.13
284.9010010	0.14
287.1509399	4.52
288.0387573	0.11
289.1840820	13.54
290.1960754	0.37
295.3015747	0.19
297.3752441	0.38
299.1945801	3.91
300.5314941	0.15
301.2462769	0.06
304.8447876	0.10
311.1524658	0.09
319.5924683	0.06
323.7721558	0.15
327.1433716	0.13
329.1970825	0.29
331.2278442	0.21
339.2778320	0.58
340.2316284	0.05
341.3874512	0.11
345.3988037	0.23
351.2595825	0.22
353.2233887	0.07
367.4685669	0.05
371.2252197	0.10
375.2864990	0.31
381.2634888	0.97
382.3248291	0.10
389.4482422	0.05
392.0496826	0.06
395.1362915	0.09
397.2800903	100.00
403.2695923	0.20
405.3432007	0.03
406.0877075	0.73
407.1671753	51.88
407.7692261	0.22
408.5003052	0.59
409.3770142	0.09
410.3646851	0.11
411.4018555	0.10
413.2786255	0.49
414.1867065	0.32
415.1452637	0.24
415.7915039	0.43
421.0570679	0.04
423.4141846	0.17
425.1598511	44.28
425.7946167	0.31
433.2034302	0.23
435.0771484	0.14
449.1705322	0.74
451.2365723	15.36
459.4483643	0.17
461.0722656	0.17
467.1481323	0.38
470.8171997	0.13
481.3804932	0.73
482.7954102	0.28
489.2918091	0.24
491.0764771	0.30
491.9540405	2.10
500.4133911	2.99
501.0170288	0.10
508.6784058	0.11
515.2480469	0.47
529.1327515	0.18
531.4028931	0.36
533.0899048	0.43
535.6340332	0.03
541.4002686	0.05
545.3058472	0.41
551.4326172	0.27
557.2124634	0.10
558.6240845	1.51
559.3964844	5.28
578.1940918	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
349.2289124	8.45
642.7651978	10.00
860.3313599	3.36
967.4003296	100.00
968.2866211	23.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1349
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1763763	0.09
161.9708557	0.11
173.0497894	0.13
177.2263641	0.12
178.9887695	0.06
185.1083679	0.03
187.1690674	0.11
188.1440430	0.30
197.1553497	0.07
199.0192719	0.08
201.3190002	0.17
203.1532593	1.09
203.9327087	0.04
204.9974365	0.17
214.8423157	0.03
217.2743225	0.23
225.0515137	0.18
227.1027222	0.35
229.0744019	0.45
230.3425598	0.06
231.0481720	0.05
235.4215698	0.06
237.1319275	0.05
239.1466980	0.39
241.3754272	0.10
243.2645264	0.29
245.2219238	2.82
247.0693512	0.10
253.2211304	0.21
255.2721863	0.14
257.0603638	0.80
261.2141113	0.11
269.2463379	0.91
270.1741943	0.05
271.0992126	0.32
272.2640381	0.04
273.1449585	3.11
281.0509644	1.19
283.2863770	0.14
285.1780396	0.44
287.0499268	8.83
287.7306519	0.16
289.0959473	25.73
297.1837769	0.29
299.1553955	3.42
301.3709717	0.27
303.1211548	0.08
317.1137695	0.17
328.0508423	0.03
329.1766968	0.63
330.1427002	0.30
331.3029175	0.39
337.3478394	0.24
339.1939697	1.65
341.1036987	0.18
347.2137451	0.10
351.3142700	0.05
356.2798462	0.08
357.3036499	0.13
362.9860840	0.19
381.2178955	1.96
383.2369385	0.08
393.2723999	0.15
397.3943481	2.89
402.2143555	0.13
405.5856323	0.05
407.1811523	100.00
407.9240723	0.21
409.2582397	0.56
410.0126343	0.34
411.5820312	0.17
413.1449585	0.06
414.1583252	0.05
423.2886353	0.24
425.1597290	86.47
425.7612305	0.16
427.5524902	0.11
433.3308105	0.98
436.3724365	0.31
437.2714844	0.52
449.2407227	1.37
451.2194214	29.38
453.5151978	0.07
455.0779419	0.10
467.3375854	0.36
469.3016968	0.07
471.1874390	0.17
480.3382568	0.10
481.3228149	0.09
487.3667603	0.16
491.3605347	1.38
500.3321533	0.77
513.5560913	0.10
515.3584595	0.60
525.6533203	0.21
531.5066528	0.07
533.0155640	0.69
533.6173706	0.11
541.1851196	0.51
551.2859497	0.19
559.2586060	8.75
589.2525635	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1711
Annotation	4,6,2',4'-Tetramethoxychalcone 2'-beta-glucoside
Peak:m/z	Relative Intensity
151.0460510	0.58
177.0925293	0.08
179.0773010	0.09
181.3182068	0.06
183.1830139	0.07
206.9350281	0.07
209.2690735	0.07
210.2492065	0.08
227.0961304	0.15
229.1275787	0.07
234.9383392	0.06
279.3081665	0.05
283.3785706	0.12
299.5193787	0.09
313.3015137	0.09
315.4824219	0.07
325.4537354	0.10
329.3228149	0.19
343.1579590	100.00
343.7814331	0.21
357.4369812	0.07
372.3460083	0.37
387.4991150	0.23
401.2965393	0.16
407.1007996	0.27
407.7289734	0.11
414.3883057	0.20
415.4421997	0.05
417.1399231	0.28
429.1537170	0.05
431.2303162	0.17
443.1499939	0.19
450.4604187	0.09
459.4561768	1.23
461.2622375	0.51
463.4391785	0.09
467.1269836	0.26
469.4284363	0.38
485.3258667	0.58
487.2648621	0.47
488.2461853	0.29
506.4902039	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1614
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
118.9865265	0.25
120.8774109	0.12
129.0736389	0.21
133.0810547	1.91
135.1607208	0.13
143.0742493	0.30
145.0698090	4.73
149.0891418	0.05
154.9544983	0.10
161.0471497	0.96
163.0749817	0.91
172.8544617	0.09
175.2085571	0.08
177.1461792	0.45
178.9356842	1.96
186.2104034	0.07
187.2534027	0.16
188.3084564	0.04
189.1590424	0.33
198.8403015	0.04
205.1367798	0.39
207.0588226	100.00
209.0659790	0.02
210.9489746	0.08
217.1449432	0.15
221.0023956	0.04
221.6436462	0.12
224.9474182	0.37
231.1208191	0.04
232.9528198	0.11
234.1841736	0.13
234.9680786	0.14
248.8385315	0.41
249.5323181	0.02
251.3544006	0.09
252.7652893	0.16
259.1546021	0.02
260.9959412	0.18
265.7601624	0.03
267.0105591	0.15
278.9987183	0.10
283.1904297	0.16
285.1669922	0.05
292.8864746	0.04
295.3930359	0.03
296.2626343	0.02
297.1032104	0.09
299.5542603	0.05
309.0467529	0.62
315.4284058	0.03
319.3620300	0.06
321.5326538	0.07
323.3109131	0.04
326.1067200	0.13
327.5350037	0.12
334.3928223	0.09
341.2351074	0.07
354.4684448	0.05
355.6323853	0.08
368.8977356	29.89
369.6091614	0.15
371.2500000	0.10
373.6151428	0.05
379.4674072	0.04
395.1507568	0.05
397.2051697	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
66.6784058	0.11
85.0197601	0.06
87.0040436	1.45
108.9759521	0.07
110.9388123	100.00
126.9663239	0.08
128.9084320	1.69
130.1335754	0.10
130.9349518	0.88
147.0626068	0.16
155.0394745	0.82
172.9686890	19.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
142.9615631	0.14
179.1172333	0.18
297.2144470	0.01
341.2309570	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	592.789
Annotation	Unknow
Peak:m/z	Relative Intensity
172.7982025	0.09
256.1290283	0.06
294.7217407	0.07
306.3240356	0.06
338.1280518	0.05
340.8242188	0.08
343.0491943	0.04
356.7998657	0.03
372.9316406	0.06
382.8669434	0.12
410.8925781	0.04
421.7738037	0.12
423.8270874	0.18
424.9442749	0.49
426.8490601	0.02
428.9638672	6.21
433.2874146	0.18
440.5036621	1.70
441.1267090	0.04
442.9243164	0.35
446.9656372	0.29
451.5505371	0.06
456.8483887	0.62
460.9212646	0.03
461.8615723	0.08
462.5142822	0.08
468.7656860	0.32
470.9618530	2.22
475.2303467	0.06
482.8743896	0.48
484.9124146	0.47
486.1262817	0.43
486.8395386	1.13
491.6380615	0.17
500.8291626	1.54
502.9141235	0.24
505.6193237	0.09
508.0509644	1.00
508.8576050	0.24
514.6589966	0.08
516.3711548	0.04
518.4088135	0.51
519.0597534	0.05
527.9099121	0.11
528.8688965	3.45
530.2023315	0.20
530.9746704	1.29
544.0592651	0.04
544.7703857	0.03
546.0065918	2.83
546.8515015	35.07
548.7009888	0.07
549.4226074	0.02
564.3911133	0.29
572.7585449	0.13
574.8502808	100.00
592.8304443	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
96.86514282	0.03
98.81608582	0.15
104.9682007	0.09
106.8605194	0.75
108.9662476	0.60
109.9347992	0.11
110.8459244	0.12
112.7897797	0.05
114.9056091	0.03
116.9976578	0.27
119.0061722	0.43
120.9826813	2.79
122.940506	0.20
125.0856934	0.15
128.8810425	0.30
131.0413513	1.16
132.8288269	0.65
134.9242554	2.39
136.9940796	0.58
139.2759094	0.15
141.1212921	0.28
142.9950409	3.59
145.0819702	0.24
146.9113312	0.51
149.0909729	0.67
150.9339905	0.36
151.983429	1.66
152.965332	0.50
153.9371033	0.51
154.9031372	0.40
157.0658875	2.17
157.8235779	0.03
158.9025879	1.09
161.0843811	0.31
163.0574951	0.96
165.0588379	3.10
166.2831421	1.55
167.0222473	3.16
167.8328247	0.57
168.9886017	3.11
171.0134888	0.43
173.0438995	2.38
174.9372253	0.94
176.1754608	0.08
179.0291901	0.48
181.0447083	0.15
182.2489471	0.34
183.0794373	1.05
183.8125305	0.16
184.4312439	0.11
185.1025848	1.05
185.9713135	0.05
187.0266266	1.74
191.0854187	0.08
193.0809021	0.24
197.0839081	0.55
199.1276703	0.25
201.1592712	0.61
203.0142059	0.16
205.012146	0.95
207.0403137	0.16
208.3952332	0.15
209.0890503	0.32
211.0361328	1.95
215.1212463	2.01
216.1907959	0.08
217.1930847	0.14
219.2989502	0.18
221.3368835	0.28
222.7090454	0.23
223.3425903	1.01
224.9946289	0.08
226.191803	0.16
227.1801453	0.17
228.03125	3.98
229.1130066	11.37
230.1001587	1.71
231.0555725	0.07
233.0869141	1.40
234.1250305	0.11
235.2115173	0.20
237.1278076	0.17
238.1135559	0.08
238.8995667	0.05
241.1876221	0.51
242.098877	0.29
243.2093201	2.31
244.0422363	0.48
245.1744995	1.85
247.0435791	14.04
248.1492615	0.90
251.1481018	1.30
253.2313843	0.28
255.3379211	0.38
257.2949219	0.11
259.2676392	0.09
261.1689453	0.09
262.3048401	0.09
263.0493164	0.07
265.0772705	1.71
266.1837769	0.07
267.1403503	0.69
269.269165	0.09
270.0390015	0.06
271.1312256	0.10
273.0120239	0.14
276.2098999	0.10
277.4994812	0.65
279.2676697	0.30
283.5518799	0.22
285.3217773	0.80
287.2327271	1.22
293.9122925	0.15
295.1644287	2.75
296.2276611	0.48
297.447937	0.37
299.3828735	1.29
303.2959595	0.30
305.1340637	6.31
305.8106689	0.16
313.2443848	2.21
323.2324219	100.00
324.1235352	0.27
325.2508545	0.20
332.79245	0.43
338.3559265	0.05
341.1986389	0.72
342.3742371	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.07
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
76.88023376	1.34
88.92201233	2.74
110.807785	2.96
111.8951874	0.73
122.825119	1.10
126.8235931	2.62
133.3287811	3.53
135.1064758	1.82
137.0540619	1.07
139.9880676	1.41
149.064682	1.21
150.9255219	0.91
153.1680603	2.79
154.341568	1.34
155.1093903	1.13
161.2320404	2.59
162.9336243	4.93
164.7583466	3.29
166.8761139	0.78
170.207428	3.26
173.2931519	1.84
174.9788055	1.14
176.8544769	1.69
178.0927124	1.85
179.0682068	1.52
183.0684052	0.76
186.4522247	0.95
187.1816254	1.31
189.1247406	1.78
190.330658	4.04
191.1236572	2.49
192.117157	2.76
192.9133606	0.78
194.1562653	11.82
195.0838623	4.46
197.3829041	1.72
203.047348	6.28
205.1083069	9.30
206.0414581	2.77
207.3554535	37.06
208.0940857	6.43
209.2256775	14.30
215.1798401	2.32
220.5594635	5.37
221.2357635	4.75
222.4144287	5.64
223.1014557	9.05
231.2279205	2.35
232.1093292	4.50
233.1529388	48.40
235.1603546	4.42
237.0042877	1.03
251.0738983	100.00
252.2671356	12.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.0831
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9847412	0.04
126.9410858	0.23
149.0531616	0.02
155.0387878	0.05
171.0436096	0.08
173.0021057	0.91
173.9360962	0.04
175.0468445	0.12
188.1766052	0.07
191.0147095	100.00
267.2079468	0.04
285.1598511	0.06
292.4676514	0.06
305.2688293	0.05
337.2741699	0.03
341.0953979	0.10
346.8842773	1.79
365.0123596	9.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.13
Annotation	Sibiricose A3
Peak:m/z	Relative Intensity
131.0552063	0.05
146.1265564	0.02
149.0343933	0.84
152.9674530	0.02
163.0501404	0.03
167.2072754	0.03
191.0803833	0.24
193.1811523	0.03
195.0306396	0.01
196.0882263	0.01
205.3880920	0.02
210.2895966	0.03
214.6147003	0.01
220.9525909	0.07
227.0943909	0.02
227.9997101	0.02
230.1169281	0.02
231.0186462	0.06
233.3890381	0.07
252.8969421	0.01
254.9930725	0.17
257.0403442	0.06
259.3045654	0.03
270.1770020	0.01
275.1356201	0.36
276.3176575	0.04
279.3947144	0.06
289.3142700	0.03
293.1372375	13.17
294.2532043	0.22
298.1600342	0.03
299.3204346	0.13
311.3699341	0.04
328.3380737	0.02
333.4462280	0.04
339.2518921	2.21
340.3513184	0.04
343.1157532	0.12
359.3456116	0.04
375.1826172	0.04
376.1950684	0.02
387.7322083	0.03
389.7977295	0.06
393.4376526	0.06
398.2039490	0.04
415.1491394	100.00
416.1507874	0.86
417.1738892	0.08
418.0904236	0.04
433.9408875	0.01
441.4066772	0.02
443.2599792	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1291
Annotation	Epoxycantabronic acid
Peak:m/z	Relative Intensity
82.9959259	0.21
109.1594238	0.18
110.8643646	2.16
112.9455719	0.10
121.2705231	0.08
127.071991	0.10
137.6587677	0.90
139.1749878	0.16
141.0409088	0.32
147.0258942	0.22
149.0318909	0.18
151.0773926	0.53
153.0024261	100.00
155.0100861	0.29
161.1265106	2.17
163.1563263	1.13
167.0039368	0.11
173.0509338	0.88
175.2911835	0.13
176.2057037	0.29
177.2856445	0.30
178.1565247	0.12
188.9935455	0.19
191.946991	0.08
201.2082825	2.99
203.1589813	0.61
204.0973969	2.73
204.8789215	0.12
206.2798462	0.24
214.9127808	0.25
217.1719513	0.74
219.1480865	27.34
221.157196	0.61
227.1940155	0.31
243.0524902	0.08
245.1104126	4.91
247.93013	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
675.4446411	6.57
918.8999634	22.44
967.4387817	100.00
968.0958862	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.149
Annotation	Lactulose
Peak:m/z	Relative Intensity
109.0680313	0.76
126.9256897	7.97
144.9639740	6.98
157.2052612	0.46
162.7512360	13.21
163.4194336	0.04
180.0018921	6.09
181.0858154	0.12
187.2067261	0.13
194.3031006	0.23
198.1304016	5.05
211.1638794	0.30
222.6677246	0.15
228.0382080	0.24
229.0006104	0.12
240.8512573	0.11
243.2812195	0.53
245.4106445	0.15
246.7565613	1.29
257.6161804	0.32
258.4519653	3.45
259.1290283	5.01
270.4339905	0.12
271.0340576	0.97
276.2886353	1.65
276.9275513	4.37
285.8719482	0.20
288.8471680	19.27
292.6127930	0.49
293.6059570	0.23
303.9214783	0.28
306.1417542	3.55
306.9340820	8.90
308.4355164	0.11
309.8693542	0.25
312.3179626	0.18
322.6675415	1.08
323.9859009	5.28
324.8187561	100.00
325.5097961	0.52
340.5612793	0.55
342.4084778	18.12
343.0172424	38.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2631
Annotation	Arecatannin A2
Peak:m/z	Relative Intensity
373.046875	0.03
451.2619934	0.02
692.9666138	0.05
739.1137085	0.02
846.9301758	0.07
1026.274658	0.16
1135.679688	0.05
1136.537354	0.13
1153.256958	100.00
1154.346924	19.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0716
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.03184509	2.18
110.9454041	1.43
114.7692719	1.60
122.5971222	1.01
124.9169006	1.45
129.1439362	3.48
136.0531616	1.86
136.8842316	6.42
139.1433105	4.94
148.8804169	0.84
150.2067413	0.75
151.1340485	4.31
157.2433929	1.44
162.9256134	2.12
164.9418488	2.61
172.8851471	0.81
175.1424713	3.05
176.671463	5.10
178.9368134	5.52
189.0705872	5.86
189.7412567	2.24
191.008316	7.62
193.1575775	3.57
194.1556549	5.51
195.2289886	3.61
202.9288788	3.26
205.0725555	5.14
206.1812286	1.60
207.0925751	26.89
208.2498016	4.81
209.298111	8.06
215.1225433	3.05
221.0760956	6.87
222.058609	9.72
223.2927399	36.54
233.0798187	29.14
236.3829498	1.89
251.0752106	100.00
252.1361084	16.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9532
Annotation	Unknow
Peak:m/z	Relative Intensity
140.8404388	0.14
180.8218079	0.12
182.1183167	0.08
221.0051575	0.06
263.3085632	0.22
294.0770874	0.12
297.2507935	0.11
307.0054932	0.59
307.9656067	0.08
309.1293030	1.91
310.1370850	1.56
311.0062256	0.52
327.7548828	0.14
328.9748535	0.24
337.0107727	0.22
337.9908447	0.09
340.0119934	0.18
349.9949341	0.22
350.9506836	0.41
355.0950623	0.07
366.2640686	0.14
369.1050720	0.28
377.5959778	0.35
379.2391968	0.28
380.1029358	0.27
381.4951172	0.13
383.0075378	100.00
385.0905762	0.38
388.0699158	0.14
394.8225403	0.52
395.6900940	0.20
396.9544373	0.12
399.6957092	4.89
400.5905762	15.72
406.0862122	0.18
412.6031189	0.56
415.5675354	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393.1169
Annotation	Garcimangosone D
Peak:m/z	Relative Intensity
118.9743805	3.08
123.2392426	0.36
126.8736801	2.14
140.9118805	0.39
142.0468750	0.07
144.7299805	0.32
147.0115509	100.00
148.9273987	1.79
150.0042725	0.09
151.0715179	0.27
156.8825226	0.20
161.1175537	0.13
164.9408112	0.78
167.1020508	0.67
168.8883057	11.39
171.1443787	0.14
177.4287415	0.38
179.0703125	0.09
185.2051849	0.77
189.2462158	0.35
210.8547058	0.30
212.9824982	0.82
227.1276855	1.04
231.1576233	0.24
241.0399170	0.39
242.9657288	0.55
245.0998535	0.53
255.1352844	12.09
261.0647278	0.24
273.1015320	78.50
278.9633179	0.47
280.3190002	0.21
293.2077332	0.15
303.0233765	0.24
312.2157288	0.10
314.8653564	0.09
333.0941772	0.49
339.2854614	0.24
346.9791260	0.22
351.1765747	0.14
357.1212158	0.52
361.3027649	0.11
363.2593384	0.43
372.4983215	0.39
374.7537537	0.22
375.5656433	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.5930481	0.01
108.9693146	0.01
111.1527252	0.01
112.1295929	0.00
126.9557037	0.07
128.1974487	0.04
135.1073303	0.40
136.1739502	0.07
137.0548859	0.01
143.0507507	0.02
143.8630371	0.01
144.9948730	0.01
152.9756470	0.00
155.0862427	0.06
156.2434998	0.00
161.0211182	0.26
162.0671082	0.02
171.1590576	0.02
173.0583649	0.35
174.2057800	0.03
176.7976379	0.01
179.0968018	2.82
180.1987915	0.23
183.8390656	0.01
191.0732422	100.00
192.0206604	5.67
215.9748230	0.00
234.1744995	0.01
249.2120056	0.01
263.3565063	0.01
265.3960876	0.01
266.2325439	0.04
291.2290039	0.01
293.9815063	0.01
307.0960693	0.10
308.0616150	0.01
309.0501099	0.02
310.2243042	0.02
325.3788452	0.01
333.3527222	0.01
335.1936646	0.01
337.3231506	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	737.1663
Annotation	Xanthochymusside
Peak:m/z	Relative Intensity
255.1532898	0.02
269.0849609	0.02
285.0587769	0.09
287.1447144	0.79
299.0968628	0.51
300.1371460	0.14
301.1888733	0.05
329.2265930	5.61
361.5989380	0.02
407.0209961	0.09
423.2356567	5.12
435.2703247	0.40
443.1875610	0.09
449.2041626	0.90
491.3053589	0.38
492.3997192	0.03
557.2953491	5.85
558.0087280	0.01
575.2193604	100.00
575.8828735	0.64
585.3449097	0.03
624.3112183	0.02
694.0193481	0.13
718.2930908	0.02
737.2036133	5.74
737.8460083	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.1694
Annotation	Spicatolide F
Peak:m/z	Relative Intensity
104.8965759	0.96
108.9517670	0.22
124.0276642	1.81
132.9502411	2.57
136.8638611	9.42
165.0375824	100.00
180.1117249	0.86
189.2377472	0.33
209.9743042	0.12
231.0803528	1.53
232.8541870	0.35
242.8602600	0.15
255.2235107	0.28
263.3717346	0.63
273.4295349	0.74
280.0591431	0.91
291.2304688	0.83
299.0329590	0.67
303.2437134	0.53
308.9357910	1.86
323.9804382	0.19
325.3167114	3.36
326.1232300	3.43
327.2061768	3.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.4091
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
513.8034058	0.51
621.638916	1.69
636.5945435	2.27
768.5805054	0.53
786.2820435	1.01
934.3131104	2.34
945.4021606	0.89
948.5006714	0.60
967.4432983	82.37
968.0864868	9.94
969.6395874	1.72
971.74823	0.87
977.6310425	0.35
981.6132812	0.78
988.1035767	0.80
1015.154968	1.75
1048.179565	2.15
1052.999023	0.72
1078.920044	2.43
1094.901123	2.50
1117.620117	0.63
1133.213013	0.66
1178.264648	3.50
1222.081421	4.70
1227.047119	0.45
1282.875488	0.26
1318.93457	3.33
1349.61853	1.17
1361.12793	4.00
1676.734253	0.53
1773.649048	0.44
1814.109619	3.23
1820.237915	0.72
1851.928345	100.00
1867.62854	0.26
1871.798706	0.58
1914.775146	0.56
1917.299072	0.26
1930.17981	1.13
1940.102295	1.65
1954.589111	0.17
1958.140869	12.63
1959.940674	1.02
1972.349243	2.49
1986.841431	0.28
1990.728394	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.1142
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
161.1842041	0.06
177.2178040	0.21
195.1590576	0.10
198.9895325	0.18
257.0120850	1.14
269.1257324	8.62
278.9116516	0.06
285.4198914	0.27
287.0805664	2.39
299.8302612	0.09
315.0549927	0.15
333.0951233	0.65
342.9013672	0.11
346.4080200	0.28
349.2145386	0.06
351.2713928	0.29
357.5979614	0.45
359.3761597	1.49
367.2056885	0.24
377.3341370	1.27
395.9603271	0.10
397.1075439	0.80
398.1676941	0.34
399.2714539	0.37
405.3070984	0.34
415.4869690	0.20
418.3766479	0.22
421.1691589	0.12
423.2432251	0.13
431.7562561	0.61
435.0373840	0.44
435.6820374	0.13
449.1212463	100.00
449.7531128	0.21
450.3596191	0.28
458.3105164	0.08
462.3405457	0.13
464.3301697	0.06
474.1652222	0.19
475.3554077	0.17
477.1256409	1.75
496.2055359	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.4312
Annotation	Trungapeptin B
Peak:m/z	Relative Intensity
207.1703186	4.38
267.2131958	1.13
279.5102844	0.84
336.3079834	3.31
375.3370361	0.56
461.4402466	12.50
601.5826416	3.26
634.9746704	1.85
658.8084106	3.64
668.5744629	1.70
678.9262085	10.02
687.6376343	3.99
705.5794067	3.61
723.4293823	100.00
724.0542603	7.53
724.8675537	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	818.439
Annotation	Unknow
Peak:m/z	Relative Intensity
268.0671387	1.32
285.7637329	0.30
296.0381165	4.77
312.2286987	0.09
313.9655151	3.78
315.1243896	0.21
328.3142090	0.20
330.3574524	0.55
331.4485474	0.06
399.4155884	0.47
425.1784668	1.76
426.2117920	0.20
429.3132935	0.16
439.2313843	0.15
443.1631470	11.50
444.4167480	1.62
463.5742188	0.23
483.2213135	0.12
498.1455688	0.42
500.3918457	0.78
509.0307617	0.37
514.0050049	0.20
524.2254639	1.29
525.2291260	0.42
542.2089844	13.51
543.3109131	1.53
551.7359009	0.06
559.4656372	0.14
566.2103271	0.25
579.3560181	0.32
595.2771606	2.77
612.6605835	1.02
613.2690430	11.60
614.2311401	1.80
656.4707642	0.18
671.4923096	0.11
694.8107300	0.14
708.1419067	0.39
710.3374634	0.49
714.1498413	0.42
747.2113647	1.66
748.5690308	0.45
750.2777710	0.37
751.2062378	0.29
763.5153809	0.08
775.7388306	0.18
780.9365845	3.00
781.9051514	0.14
783.9271851	0.12
798.2846069	0.33
801.4953003	1.26
802.2114868	0.80
806.7770386	0.41
816.0265503	0.09
819.2605591	0.10
836.9118042	1.43
837.5485229	0.43
852.0233765	0.12
872.5873413	0.47
912.2149048	3.02
921.3662109	100.00
922.3272095	2.20
923.2307129	0.74
924.0307617	0.32
927.1674194	0.15
947.8065796	0.97
954.3146362	0.10
956.8721313	69.21
957.9729614	1.46
959.2282715	0.32
960.6621094	0.09
961.8336792	0.16
997.5375977	0.27
1005.7797240	1.24
1006.4094850	63.39
1007.2771610	0.40
1008.0686040	0.05
1010.9448240	0.36
1025.6530760	0.33
1060.7630620	0.21
1061.7495120	2.76
1062.4581300	0.21
1070.9062500	81.95
1071.7592770	1.58
1072.5058590	1.98
1073.4663090	0.82
1074.4857180	0.39
1077.4564210	0.30
1120.3131100	2.19
1121.1510010	0.75
1130.6232910	0.46
1221.5839840	0.24
1241.8276370	0.12
1355.1217040	0.41
1372.0906980	0.10
1482.6854250	0.08
1508.8817140	0.14
1554.2158200	0.29
1635.9396970	0.18
1637.6326900	0.08
1718.8581540	0.05
1743.8511960	0.14
1767.1038820	0.05
1772.1593020	0.15
1778.5988770	1.16
1783.5524900	0.14
1795.9608150	0.10
1844.2164310	0.06
1850.1804200	0.06
1857.5925290	1.41
1860.3547360	0.06
1867.6097410	0.07
1880.1413570	0.05
1916.8695070	7.40
1918.0466310	3.88
1923.3404540	23.47
1930.4774170	0.21
1933.4400630	0.37
1959.9078370	0.34
1968.0570070	0.11
1970.7198490	1.28
1983.8197020	0.49
1995.2928470	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	688.4158
Annotation	Unknow
Peak:m/z	Relative Intensity
197.1986389	0.31
200.8657074	1.60
201.5983734	0.08
219.1149139	7.16
220.1676636	0.51
223.0426636	0.10
227.4016266	0.18
228.1704102	0.59
241.5517883	0.23
243.4131927	0.19
253.3661804	0.92
263.1740723	0.16
266.2510681	2.23
267.0230713	0.28
284.2398071	1.34
285.5977173	0.26
286.9873047	0.43
288.2296143	2.29
290.5275269	0.52
296.1307373	0.58
301.3681946	1.68
302.6449890	0.31
308.1482544	0.20
314.3272705	1.01
318.1153259	0.71
320.3222046	0.10
324.5563354	0.17
332.1968994	0.20
336.2545166	0.19
337.3392639	0.69
341.9906921	1.06
346.3037720	0.25
351.4227905	0.36
355.2606201	0.07
365.2810059	0.14
369.1921387	1.10
370.4985962	0.28
371.4938965	0.18
379.2675171	1.23
380.3213501	0.41
383.1158447	0.22
387.3337402	0.10
393.3359985	0.19
397.3244629	2.21
399.2399292	0.15
401.4614868	3.90
402.6022949	0.65
419.3685303	3.69
420.1279907	0.47
421.4204102	0.46
430.0052490	0.46
431.3566284	0.19
433.5484009	0.23
438.4142456	0.59
447.0606079	0.19
447.9726562	0.30
449.5833130	2.73
452.4663696	0.34
456.4857788	0.49
458.0164795	0.35
458.6232300	0.35
464.0937500	1.81
465.0547485	1.37
465.6575928	0.85
466.6313477	2.43
467.5288696	0.41
468.6795654	0.29
472.4674683	0.39
474.7553711	0.26
478.8361206	1.75
479.8832397	2.81
481.8442383	0.47
484.2548218	3.83
485.6439819	0.38
492.3539429	1.06
498.2927246	0.66
499.2915039	2.20
500.5648193	0.94
501.1799927	0.75
502.2454834	0.50
505.4691772	1.92
506.3441162	0.60
507.0758057	0.62
509.0952148	2.20
510.3818359	0.41
511.1455078	0.57
512.7813721	2.74
514.0194702	13.60
514.8191528	7.03
515.6087036	0.44
519.2203979	0.27
520.8456421	5.25
521.5751953	4.77
523.0540161	21.59
523.9244385	2.29
525.2667236	1.47
528.7915649	0.43
530.1118774	0.29
534.5239258	1.91
535.4952393	0.33
537.8745728	1.50
539.0254517	1.86
543.7911987	0.36
548.3009644	4.25
549.0008545	0.73
553.0313721	0.90
554.1982422	0.50
556.3507690	4.37
557.3468018	8.25
558.3941040	1.48
559.6379395	0.77
561.1283569	0.67
562.0467529	14.40
563.2178345	0.60
564.6068115	1.98
565.7761841	11.14
566.6873779	23.68
567.5530396	0.57
570.3897095	18.67
570.9971313	19.65
571.6676636	5.36
572.4612427	1.30
573.5740967	1.02
574.1824341	0.76
574.8635254	0.37
579.6848755	35.95
580.6202393	1.63
583.4722290	0.25
584.6973267	0.05
591.3862915	0.52
592.5985718	0.44
597.4385376	6.58
598.5530396	1.42
600.5942993	4.33
602.6843872	0.55
603.3704224	0.76
605.0803223	9.78
605.8557129	3.20
606.4993286	0.58
608.9218140	10.05
609.7515869	4.44
610.5991821	0.62
614.1249390	36.92
615.4514771	84.95
616.4995728	22.08
617.5402222	6.05
619.4528809	0.46
620.8555908	0.15
621.8372192	0.42
623.2314453	71.02
624.1189575	13.66
625.3015137	0.53
629.0536499	0.17
631.5081177	1.17
632.4108276	0.37
633.4032593	1.58
637.2971802	0.75
641.1376343	0.40
643.3187866	0.55
647.9875488	1.37
648.5939941	6.26
649.5583496	2.89
650.4874878	0.27
653.9983521	0.59
657.0696411	1.81
657.7122192	0.17
661.3936157	1.36
662.3317261	1.47
665.6452637	1.21
666.2706909	0.21
670.8617554	19.07
671.6228638	3.02
674.7866821	0.38
676.6374512	0.15
691.1450195	0.08
700.7620850	0.43
702.7098999	0.37
708.1428223	0.32
710.5543823	0.25
715.6182251	0.13
717.4986572	0.13
725.5618286	1.08
726.6188354	0.10
728.4904175	2.59
729.4813843	2.71
730.4957886	0.32
733.6586914	1.06
734.5714722	1.50
735.5947876	0.39
744.0007935	4.83
744.7727661	5.46
745.6080322	2.86
746.5460815	0.10
750.7265015	0.35
761.5708618	100.00
762.5765991	42.48
763.6835327	9.86
768.4544067	0.53
787.2931519	0.09
793.1254883	0.12
803.4807739	0.39
805.5922241	0.15
817.7296753	1.12
818.8175049	0.53
824.5958862	0.25
829.8362427	0.77
830.6424561	3.27
832.0569458	0.14
839.2601929	0.15
842.5715942	1.24
843.5980835	2.41
845.3005371	0.12
846.6115112	0.44
849.1505737	0.32
850.0386963	0.32
855.6138306	0.25
857.3014526	0.08
858.6267700	0.59
860.9597778	0.18
867.8285522	0.35
874.7947388	1.59
875.6811523	0.17
881.2432251	0.26
901.6376953	0.30
904.6245728	0.75
905.2257690	0.41
909.7153320	0.09
915.7365112	0.43
916.3932495	0.28
917.5042114	0.26
918.9373169	0.36
926.3876343	1.36
927.7434082	0.56
928.5969849	0.29
935.5102539	0.10
940.9360962	0.28
941.9251099	0.20
943.6774292	10.12
944.7313843	4.13
945.6005249	0.97
955.5231323	1.30
957.7233276	36.84
958.8344116	13.38
960.0400391	1.60
961.7529907	0.59
962.7734985	1.12
963.6641235	0.21
1000.9631350	0.41
1009.8027340	1.10
1017.8808590	0.50
1018.4878540	0.09
1019.3664550	0.35
1026.6412350	3.08
1027.6799320	1.36
1028.7945560	0.48
1030.5648190	1.16
1031.9287110	0.52
1032.7416990	1.41
1044.6726070	12.36
1045.7358400	6.81
1046.5371090	1.95
1047.1452640	2.03
1048.8015140	3.09
1049.8127440	2.98
1050.7702640	0.13
1061.3262940	0.43
1069.5490720	1.30
1078.3795170	0.08
1086.5357670	0.48
1092.8588870	0.71
1095.8498540	0.19
1096.6047360	1.23
1101.9522710	0.50
1103.9993900	1.04
1113.6562500	1.41
1114.6577150	0.82
1128.9920650	0.11
1131.8051760	2.57
1132.7972410	1.70
1133.5024410	0.95
1134.1660160	0.28
1139.8828120	0.54
1140.9409180	1.42
1142.0080570	0.71
1142.8724370	0.23
1157.1939700	0.27
1157.8198240	17.33
1158.8586430	12.01
1159.9067380	5.06
1161.5795900	0.21
1208.9215090	0.33
1226.6710210	1.90
1227.8663330	0.50
1228.9906010	0.79
1264.1119380	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.97075653	0.18
95.15473938	0.28
98.12306976	0.27
98.91781616	0.58
108.8312225	0.68
114.9548492	0.22
116.9711151	0.65
118.9226685	0.35
121.0563278	0.34
123.9142456	0.79
125.0776443	1.45
128.7957306	0.58
133.2640076	0.42
135.2195129	0.47
136.0253601	0.52
137.1691895	1.12
138.9744263	1.58
141.0814514	0.44
143.1847076	0.97
151.0745239	1.21
153.0387878	3.03
157.0518799	0.53
158.9202576	1.48
160.9994507	0.77
162.844574	1.33
165.0212402	0.25
166.9763794	2.05
171.0410767	3.07
171.8058777	0.45
173.0453339	0.37
177.1332397	0.82
178.9726257	2.82
180.9861145	2.48
181.9929199	1.25
183.1550903	1.86
185.3668518	1.65
187.0752106	0.54
191.2874603	1.28
193.1470032	0.47
195.0831909	5.79
197.1571655	4.68
199.2514343	1.58
201.0626678	0.24
203.1239624	0.36
208.1427612	0.67
209.1710815	0.21
211.2384033	8.55
213.1445923	3.12
215.0914001	1.64
221.065979	0.75
223.0783081	1.78
225.0725403	3.54
227.4754639	1.17
233.231842	0.65
235.1946716	3.43
237.0966187	1.28
239.0751648	5.67
241.2140808	0.63
243.451355	0.14
245.3395081	0.33
247.0696106	0.90
249.1660461	0.31
249.8510132	0.31
251.0583496	2.89
252.3129272	1.30
253.0657654	3.32
254.9880066	0.77
257.1587524	1.26
265.4089966	0.55
266.265564	0.29
267.2667847	1.74
269.2637024	3.75
270.3511047	1.37
275.3009033	17.92
276.2688599	0.58
283.3089905	1.81
287.7703247	0.40
291.3314209	0.41
293.2155151	100.00
294.2430725	0.60
302.3874207	0.96
311.0802002	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.0673
Annotation	Unknow
Peak:m/z	Relative Intensity
168.6582642	0.25
171.0505981	0.08
174.9387054	0.15
186.7896271	0.55
198.9337769	0.47
204.8815918	0.15
210.7400513	0.06
214.8175049	0.75
217.0265808	0.63
224.0376434	0.06
231.9362488	0.31
232.9596405	2.49
233.7723541	0.08
235.0023956	0.85
245.0988770	0.33
252.9320984	0.20
259.1117859	1.11
262.7150879	0.86
271.0987244	0.24
276.3347168	5.34
276.9989624	41.55
287.0560913	0.48
288.9583740	5.37
291.7146606	0.17
293.1053467	3.00
294.0800171	0.15
294.9818726	0.56
300.8651123	0.25
303.7986450	0.06
306.8900146	37.45
307.5021973	0.08
317.1793213	0.56
319.0070801	0.51
324.8833008	0.07
331.1370239	0.04
334.0461426	0.37
335.0012817	1.03
336.7902832	17.73
337.4551392	0.27
348.6838379	0.17
349.2927856	0.08
352.9871826	18.99
360.6988525	0.18
366.6969604	0.95
367.4195557	0.11
370.9177856	0.11
378.3895874	0.40
379.0087280	0.26
380.9485474	0.25
385.1004028	0.24
394.8920288	0.40
396.9266968	100.00
424.8965454	0.37
454.4101562	0.23
455.1916504	0.06
459.0467529	0.15
469.4381104	0.05
471.3242188	0.60
486.9674683	0.24
496.3182983	0.21
497.2326660	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1396
Annotation	4-Hydroxy-3-prenylbenzoic acid glucoside
Peak:m/z	Relative Intensity
105.8482666	0.22
112.9936752	1.21
118.7885284	0.23
125.1408005	0.12
128.9831848	0.03
131.2017212	0.06
139.1196899	0.10
147.1217346	0.14
149.0138702	0.12
157.0933380	0.03
159.2207642	0.04
161.0448608	5.43
162.0392151	0.84
163.1390381	0.05
169.0219116	0.09
173.1313171	0.05
174.3111267	0.07
179.1727295	0.26
189.1165314	0.72
203.2947998	0.40
205.0425262	100.00
206.0499268	14.34
207.2280579	0.07
216.2022247	0.14
219.1072693	7.00
220.0661926	1.90
222.9662781	0.26
225.2619629	0.08
243.2555542	0.15
247.0932617	75.03
248.0915222	10.75
249.4837341	0.04
253.3113403	0.05
259.1578369	0.67
260.1706543	0.22
261.3064575	0.04
262.1395264	0.08
266.7419434	0.06
269.1825256	0.09
271.2314453	0.41
272.2614441	0.03
277.1117554	14.96
278.1400757	3.06
279.3887939	0.10
289.1404724	0.08
291.2201538	0.22
293.9750671	0.17
297.1574707	0.07
301.3340454	0.70
305.3171997	0.28
307.1618347	72.90
308.1068726	12.25
312.1315918	0.18
321.1655884	0.43
322.2283630	0.33
323.1721802	0.13
324.3447266	0.32
325.3993225	0.17
332.2427673	0.22
338.1240845	0.09
339.1140442	0.13
347.3239136	0.04
349.1387024	1.21
350.2495117	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1974
Annotation	Arecatamnin A1
Peak:m/z	Relative Intensity
242.9499817	0.04
245.1342163	0.01
255.3350372	0.01
269.1302795	0.02
280.9576416	0.01
285.1314392	0.03
287.020752	0.18
289.088501	0.03
298.0402832	0.01
299.1384888	0.01
331.0756226	0.02
337.233429	0.15
363.3571167	0.02
369.2650146	0.03
379.4415894	0.03
391.0100708	0.02
395.0244141	0.04
406.2885132	0.07
407.3019409	0.26
413.272522	0.02
414.1204834	0.01
423.1244507	0.19
424.9533081	0.15
425.5960693	0.02
432.0928955	0.01
435.3034058	0.01
448.2945557	0.01
449.3101196	0.06
451.2410278	0.09
472.3329468	0.02
489.4828491	0.05
507.477478	0.02
516.177124	0.02
517.5127563	0.01
524.4519043	0.06
525.1773682	0.10
531.1886597	0.03
532.1758423	0.03
537.774353	0.04
541.3098145	0.04
543.2973022	0.11
549.2874146	0.11
556.3734131	0.03
557.1922607	0.12
559.185791	0.05
568.8825684	0.07
574.1166382	0.08
575.2979126	0.29
576.2709961	0.17
577.2622681	0.20
580.1841431	0.03
587.3201294	0.04
588.1045532	0.02
613.8821411	0.04
619.6083984	0.06
620.5237427	0.02
622.7317505	0.05
626.2841187	0.05
627.2025757	0.05
631.3737183	0.17
635.020813	0.11
635.8272705	0.09
638.3104858	0.09
640.5050659	0.06
643.897522	0.03
644.8654785	0.10
650.387085	0.05
677.2973633	0.04
681.585083	0.02
685.2585449	0.09
690.2852783	0.02
693.0404663	0.01
694.2843628	0.17
695.0202637	0.18
701.2513428	0.12
703.7157593	0.28
710.2670288	0.01
711.187439	0.02
716.7113647	0.02
719.576355	0.10
720.2954712	0.17
725.2311401	0.06
737.5632935	0.15
738.2311401	0.01
739.3283081	0.12
740.3388672	0.02
743.2103882	0.02
779.3032227	0.19
779.9788208	0.17
787.6531372	0.11
788.7216187	0.09
796.2508545	0.05
801.1633911	0.15
802.6710815	0.10
815.4164429	0.03
819.0994263	0.02
821.5046997	0.05
831.3341064	0.01
837.3346558	0.04
846.5336304	0.19
847.4231567	0.01
863.2503052	0.07
865.208374	100.00
866.1098022	0.70
867.831543	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.94216919	0.60
103.0494614	0.26
107.0447922	1.21
108.9664612	1.89
110.9225235	1.51
112.9204407	0.09
116.8340607	0.67
119.0572815	0.15
121.0334778	3.64
123.1065521	0.55
124.8721542	0.14
126.9518738	0.44
129.1118164	1.56
131.0356445	1.50
133.1761627	0.15
134.9942932	3.71
137.0919495	1.21
141.1092224	0.15
142.9460449	7.07
145.0948792	0.64
146.4380188	0.12
147.2355652	0.34
149.0257874	1.17
151.0868683	0.88
152.0000458	2.03
152.887085	0.91
155.1154175	0.51
156.8858032	1.43
158.9849243	4.39
161.0455627	0.91
162.3531799	0.12
163.1051941	0.94
165.1522675	2.39
165.9700928	1.38
167.1769257	0.39
168.0014648	0.49
169.0783386	5.28
171.0784607	0.41
173.025116	5.25
175.0613403	1.07
176.0126343	0.11
176.8214111	0.26
181.0343323	0.92
183.0344849	3.16
185.0039368	0.66
187.0935516	2.32
188.981842	1.21
191.302063	0.90
192.3033447	0.97
193.0273438	0.29
197.0215302	1.83
198.797699	0.13
201.0240936	0.81
202.213089	0.43
205.129303	0.45
207.2710266	0.70
209.2267151	0.38
210.9510193	2.55
212.8994141	0.58
215.0420227	2.18
216.1758728	0.22
217.0532837	0.51
219.2163391	0.28
223.2039795	2.33
225.1148987	0.48
226.8392639	0.96
228.2753601	3.52
229.0704651	6.44
230.1373596	1.88
232.1473999	0.11
233.0675964	2.19
234.1614685	0.29
235.194519	0.66
237.2797546	0.46
239.0799866	0.75
240.0500793	0.24
241.1201172	1.27
243.3200378	1.29
245.0626221	2.56
247.0583496	10.41
248.1521606	1.32
249.0549316	0.31
250.1647644	0.12
251.246521	0.33
253.1732483	2.25
254.5139771	0.16
257.2194824	0.24
258.4156799	0.29
263.0477905	0.09
265.1520996	1.54
266.2105713	0.40
267.2589111	1.42
269.1440125	0.57
275.2497864	0.23
277.1390381	0.16
279.2759399	0.20
281.3484192	0.61
287.3572388	0.60
295.266571	5.29
296.4352417	0.12
299.0978394	2.06
299.7076721	0.32
300.3264771	0.25
305.1759644	4.53
311.1985474	0.27
313.1321106	3.22
323.2383728	100.00
324.043396	1.09
332.8632507	0.37
341.6356812	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.06867218	1.05
101.0066681	0.36
107.0534744	0.78
108.9698181	0.48
111.0458984	1.52
112.8466721	1.11
118.8894653	0.61
121.0579224	0.65
123.0170135	0.86
124.8619232	3.15
126.8910217	1.07
128.9206085	0.50
133.2702332	0.44
135.0589447	0.97
135.839035	0.45
136.8261719	0.84
138.9157104	2.81
141.2192078	0.43
142.4298706	0.42
143.0317383	4.10
145.1333923	0.79
146.9882965	0.29
149.0613098	0.92
151.0370483	1.00
152.9951172	3.05
154.9470215	0.92
157.15271	1.93
158.8460999	1.78
161.0099182	1.99
163.182373	0.27
165.1963806	1.37
166.2059021	0.37
166.8227081	1.07
169.1377106	1.49
169.9487762	0.24
173.0518188	0.40
176.970459	0.38
179.0559692	0.57
181.1023712	0.49
183.0403442	1.53
184.9535675	0.67
188.8586121	0.74
191.1745453	1.39
194.3559723	0.51
195.0309143	0.35
197.1145935	3.10
199.1184082	0.33
203.1057129	0.53
207.3656616	0.24
209.1891785	1.38
211.3593445	2.42
213.1263428	5.55
215.0736389	0.57
217.0932312	0.21
219.3690491	0.24
221.1046143	2.67
223.0435181	2.14
224.8309021	1.29
225.4415894	2.55
227.0185547	1.35
229.3248901	0.32
230.2934265	0.19
230.9308472	0.83
232.8845825	1.41
235.2920837	2.19
237.1836853	3.25
239.1858521	2.44
241.2709351	1.67
250.2307739	0.74
251.22052	3.10
253.128418	9.05
255.1802368	0.68
257.1291504	0.32
260.3143921	0.98
261.0375977	0.43
263.3405762	1.20
265.1283264	4.44
267.0154419	2.12
269.1349182	1.18
270.1156006	1.04
275.1390991	18.77
279.2299805	2.28
280.876709	0.71
283.1445618	3.08
284.1690063	0.34
290.9804688	0.30
293.2189941	100.00
294.3806152	0.45
296.2437744	0.59
301.2442017	0.30
301.9631958	3.70
302.7817383	1.59
311.078186	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
93.03475189	1.34
127.037262	0.88
169.8841705	3.71
183.0045166	100.00
184.0650024	19.47
185.0962524	3.40
187.1097107	1.01
197.0956573	16.10
197.9787292	0.99
210.9836121	0.43
212.035675	3.10
215.1882935	1.06
217.4729309	1.31
225.4210205	3.24
226.1792603	2.69
231.1386719	0.88
239.1001282	3.12
240.2158813	1.17
243.1400146	3.09
247.2553711	10.58
249.3262329	8.12
253.1901245	2.01
254.0932617	1.98
254.8433533	1.17
263.2960815	2.24
267.1674194	9.48
268.2337036	0.51
269.2507324	0.86
271.214386	0.75
283.3485718	2.06
293.2941284	27.37
295.3275452	1.44
311.261261	14.45
312.4294128	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1088
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
125.1679306	0.02
132.1600189	0.02
136.9292297	0.28
160.9909973	0.38
161.8712311	0.02
163.0154724	0.01
164.9744568	0.13
168.4298401	0.03
173.2821045	0.02
175.2317505	0.06
179.1690369	0.03
182.9293213	0.03
192.8499451	0.10
196.9795685	0.04
199.2886658	0.04
201.0879211	0.04
203.2404785	0.02
207.9563293	0.02
210.1024475	0.01
212.7458344	0.06
215.3086395	0.05
217.3969116	0.04
219.1406708	0.02
223.1605530	0.01
225.2030792	0.42
227.1006622	0.05
231.2792664	0.04
240.0759277	0.06
241.0794067	0.17
243.1265564	0.17
243.9096985	0.01
253.3043213	0.01
255.2261658	0.01
259.1300659	0.25
261.2485657	0.03
269.0905762	100.00
270.5244446	0.04
283.3340759	0.01
284.9875793	0.54
287.0971985	22.52
289.0307007	0.02
299.0764771	0.11
300.2419739	0.03
303.2097473	0.05
305.4909058	0.02
311.1337280	0.09
313.1414185	0.02
322.2288208	0.07
323.2290344	0.34
325.3630371	0.07
329.2697754	0.16
331.1105347	0.03
333.4402466	0.03
335.3985596	0.06
341.2619629	0.02
347.4233398	0.02
349.2768860	0.01
351.4144897	0.03
352.2260132	0.04
355.1353760	0.15
357.2974548	0.02
358.1353760	0.03
359.3471069	0.06
361.3541260	0.03
363.1815796	0.01
375.4245911	0.07
387.0087585	0.02
401.7044067	0.09
402.3924561	0.17
403.1665039	0.19
407.2077026	0.03
419.0659790	0.01
421.4136658	0.08
430.3651733	0.04
431.3051758	0.14
432.9623413	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	576.63
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1128082	1.07
173.0391388	0.36
174.8365173	2.62
177.3219147	0.28
179.0917358	0.44
185.1644897	0.31
187.0655518	1.54
194.9295197	0.38
200.0932312	1.51
201.0921326	0.76
202.1505127	0.50
203.1520996	1.83
216.7724457	1.38
217.3793030	0.36
225.1965027	0.21
228.9575653	2.27
230.9784546	0.88
243.1398468	7.75
244.1797791	0.29
245.1619415	15.74
246.0215149	2.14
255.1676636	1.70
257.2415771	1.34
261.0455017	1.64
262.1953125	0.72
271.2439575	1.00
273.0564270	2.34
278.9906616	0.78
281.3409424	0.88
284.0112305	1.04
287.1315918	21.83
288.5762024	15.32
289.2135010	80.32
290.2465210	8.59
299.2300720	11.04
300.4910889	0.95
301.2994995	0.65
308.1368408	0.42
311.3293457	0.42
314.1656494	0.41
321.3112793	0.66
324.2520752	0.73
329.1930542	2.97
330.4880981	5.79
331.2874146	0.37
337.5493774	0.32
339.3270264	5.72
341.0915527	0.39
343.0248413	0.46
348.0844116	0.72
349.4337769	0.17
350.3209229	0.46
355.1603394	1.93
357.0203857	0.89
361.0926514	0.39
364.5209351	0.51
369.2764893	1.14
381.1755371	3.66
393.8007202	1.24
395.4954834	0.92
396.2391357	0.73
397.5331421	4.12
402.1826172	1.29
405.2111206	5.26
406.2297974	11.62
407.2282715	100.00
408.3034668	1.96
408.9803467	0.57
411.4886475	0.44
413.2370605	8.77
413.9700317	2.46
415.3051147	16.77
418.8579102	0.93
423.1721191	1.67
425.1469727	78.30
425.7553711	0.18
427.7486572	2.60
431.4213867	0.27
432.2875366	0.68
433.3289185	1.80
436.9160767	2.20
445.0063477	1.01
448.5651855	2.39
449.2693481	5.12
451.2009277	77.13
453.0135498	2.06
454.3339844	1.21
465.1165771	0.85
467.3742676	0.49
469.3248291	1.46
478.3686523	0.83
479.5247192	0.59
482.3208618	1.90
491.1605835	40.71
491.8004150	18.48
498.3532104	0.80
500.1673584	38.29
500.8164062	4.01
502.0578613	0.67
503.1760254	1.22
508.2647705	0.78
513.8574829	1.27
526.2710571	0.21
526.9442749	0.19
531.3383179	3.69
533.2034302	3.74
534.3663330	0.34
540.2034912	2.04
541.2038574	0.57
548.5424194	1.72
549.4420776	0.19
551.5407104	0.29
558.2982788	10.54
559.4168091	20.97
560.1729736	1.70
567.2182617	0.36
570.2858276	0.27
577.3071289	36.65
578.2013550	0.43
587.4033203	1.88
588.2028809	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	286.0915
Annotation	Buchananine
Peak:m/z	Relative Intensity
81.0657730	0.03
84.8829727	0.15
96.8156891	0.27
98.8867722	0.53
105.9618454	1.58
108.8910217	1.93
115.9409714	0.08
120.9556122	0.08
123.9019547	100.00
124.7788620	0.09
126.9290924	1.24
132.8005981	0.06
144.8054504	0.31
146.9870300	0.24
149.9516602	0.08
151.8553619	0.04
153.1652527	0.17
154.0982819	0.20
155.1958466	0.15
156.8964844	0.05
159.2118835	0.07
163.0177460	0.14
166.0411530	0.33
169.1145325	0.03
173.3926239	0.09
174.9620056	0.02
176.2043457	0.03
177.9594574	0.03
180.0073242	0.08
181.9360046	0.05
184.8628082	0.02
187.0728149	0.11
188.0167694	0.03
189.1947632	0.17
189.9343567	0.05
193.2388000	0.03
196.0878601	0.24
197.4398499	0.11
198.0686646	0.17
199.1286926	0.04
200.1751404	0.05
201.3240967	0.06
202.2621155	0.02
203.2718506	0.11
206.0246277	0.05
206.8232117	0.03
207.8110962	0.10
208.8699036	0.06
210.9878845	0.13
212.1732483	0.06
214.1600037	0.14
218.5114441	0.02
219.1216125	0.06
223.1906433	0.04
223.8630066	0.33
225.1065979	0.15
226.2877197	0.14
229.3166504	0.17
230.3216858	0.06
232.1031494	1.00
239.1233215	0.07
240.0423889	0.20
242.1674805	0.13
243.0795288	0.12
250.0944214	17.02
254.0871582	0.11
257.1486816	0.16
258.2815552	0.13
268.1091309	12.93
269.0972595	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.088
Annotation	Tuliposide B
Peak:m/z	Relative Intensity
84.8898849	2.17
86.7299652	0.09
88.0015869	0.14
88.9208679	14.74
96.8135071	2.89
98.8715515	13.75
100.9785385	12.21
108.9943008	0.21
110.8817749	0.85
112.9761963	8.87
114.8420410	0.21
116.8630295	0.32
118.8504028	4.30
125.0208664	73.60
126.9063416	1.04
130.8773499	20.65
142.9798279	2.32
145.1574097	0.14
148.9502869	16.99
160.7405853	6.28
167.3222961	0.18
171.2555389	0.45
172.8738098	2.44
174.9447937	0.32
189.0833282	1.21
191.0236664	22.57
196.8231812	0.40
198.9780884	0.43
203.1708374	0.27
207.3062134	0.26
214.8025818	0.49
220.9072266	0.22
233.0075989	100.00
241.0948486	0.26
243.3276978	0.23
245.1957397	0.28
249.2349548	0.18
256.2847900	0.18
257.2047729	0.46
264.9400940	0.33
265.5733032	0.22
274.2488098	0.23
275.1180420	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
910.4085083	4.11
912.3671265	23.26
940.6721191	11.05
966.1082153	4.12
967.4472656	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0856
Annotation	Gerfelin
Peak:m/z	Relative Intensity
82.8376389	0.04
95.0139694	0.14
104.9284668	0.04
107.0109253	0.03
108.9415359	0.11
110.9555435	0.15
119.0047836	0.08
122.8940125	95.21
123.7427979	0.03
125.0930405	0.13
127.0914001	0.44
133.0446167	0.08
135.1617737	0.04
136.9715576	0.90
138.9087524	100.00
140.9635315	0.05
144.6875000	0.13
146.9629517	8.56
150.9487305	23.55
153.0078125	0.73
156.8630524	0.05
162.9452515	0.35
164.9046021	48.11
165.5078125	0.09
167.2093811	0.03
168.9090729	3.01
172.9064941	0.03
180.9261932	0.16
182.2561951	0.04
183.2608490	0.13
189.0267944	0.04
191.6183167	0.07
193.2056274	0.07
200.2430725	0.05
201.0178833	0.04
205.0282898	0.26
207.1055603	0.05
209.3066711	0.08
217.3161011	0.20
219.1930847	0.16
220.2625732	0.05
227.1525574	0.06
230.1242371	0.12
230.9658203	0.15
236.5442505	0.09
237.1667480	0.18
241.5553589	0.14
245.2205811	0.20
249.0233459	1.32
250.1736450	0.04
254.9931030	0.65
259.1624451	0.05
260.9183655	0.17
262.2778320	0.03
263.1910400	0.08
272.9912109	19.22
274.1860962	0.05
281.6746826	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
106.9768066	0.56
108.0293579	1.46
113.2095337	0.15
118.9344635	0.58
119.6885376	0.23
120.9437485	40.70
122.9636307	0.97
128.7506409	0.26
148.8948364	0.55
151.9813538	3.26
167.0318298	100.00
178.7791748	1.07
191.0651398	0.49
192.7732239	0.36
195.0794678	0.27
201.029129	0.20
208.9028625	0.16
233.0710754	2.04
235.0474243	0.49
236.1085205	0.32
239.2579346	0.22
241.0167542	0.41
242.971283	0.54
244.1115112	0.87
255.0615234	0.23
256.3760986	1.31
257.2627258	0.34
258.0249634	0.23
266.949646	2.55
269.1907043	0.60
283.083313	12.54
285.1146851	1.86
287.203186	0.63
301.1895142	1.22
310.9541931	1.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1921
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
134.6849060	0.14
137.1672211	0.23
143.1142883	0.39
149.0955353	0.19
160.9279480	2.20
166.3056793	0.23
167.1847534	0.37
179.0088806	0.86
189.0949402	0.14
195.1513062	0.15
201.1141357	0.11
207.0685730	5.70
208.1181641	0.34
209.1825867	0.87
211.1467896	100.00
219.1404877	0.10
221.3978577	0.18
225.1378479	0.29
233.0491791	0.08
238.0595093	0.40
239.1165771	0.10
241.3370667	0.21
246.6815186	0.22
251.7545166	0.40
253.2548523	1.61
257.0846252	0.91
259.0437012	0.26
265.0008545	1.45
269.2835083	0.14
271.2621155	0.11
279.0631104	0.07
280.4128113	0.07
283.1488953	1.58
285.1417236	0.08
296.0725098	0.10
301.2621460	0.29
307.2919617	0.27
309.1588135	0.20
312.1322021	0.26
313.2143860	0.54
315.2140808	0.11
323.2649536	10.04
328.3728333	0.17
331.1398315	0.45
333.3422852	0.13
336.1577148	0.21
337.4000244	0.10
338.1742554	0.07
342.3505859	0.61
343.9680481	0.19
345.1046448	0.05
346.3933105	0.37
347.1653442	0.28
355.3034973	1.07
357.3877869	0.21
363.0849609	0.05
371.5632935	0.95
372.4677734	9.76
373.1655579	95.26
375.2145996	0.35
381.0098267	0.46
383.4678040	0.54
388.0047913	0.10
389.2555237	0.34
399.2837524	3.92
401.2193909	7.23
401.9307556	0.13
404.0331726	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.2284
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0467682	0.03
125.0414734	0.03
126.9107056	0.03
129.0102997	0.08
141.1020508	0.09
142.9187012	0.04
159.0423584	0.13
161.0746155	0.30
162.2433319	0.10
180.8785553	0.06
197.0663757	0.29
198.1931152	0.04
199.1911469	0.58
200.3334808	0.03
206.1271057	0.02
209.0655975	0.15
215.8536072	0.04
219.3126984	0.08
225.1698303	0.04
227.1529846	4.47
228.1984558	0.52
240.1570129	0.08
241.2967834	0.07
243.2315674	0.22
245.1839905	9.64
246.2729492	1.80
249.1894531	0.02
251.1042786	0.05
257.2468872	0.04
258.2858887	0.10
259.4077148	0.09
267.4323730	0.07
269.2681885	0.26
270.2657166	0.06
271.4191895	0.05
277.9705200	0.03
285.3376465	0.03
287.4215698	0.06
288.0874634	0.03
296.9526672	0.10
298.5853271	0.02
299.3970947	0.03
302.0539551	0.08
311.6331787	0.23
312.3096008	0.03
318.8984680	0.02
324.5067749	0.04
328.5139160	0.02
329.6451416	0.04
330.4561462	0.02
341.2145996	0.02
345.4330139	0.08
347.2614136	0.02
352.0987854	0.06
353.5029297	0.19
354.3763123	0.06
359.2873535	0.03
362.3866272	0.19
363.7333069	0.02
371.3505554	4.97
372.4108582	2.45
387.4890137	0.12
389.3481445	100.00
390.3406067	22.02
391.2189026	0.15
393.5588074	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9625549	0.82
259.1246338	0.35
292.9956665	0.03
298.8119202	0.06
302.9794312	8.47
319.2344666	0.05
373.0205078	0.19
384.6669922	0.14
386.7818604	29.87
387.4198608	0.05
388.2779541	0.09
417.4274292	0.09
430.7674561	0.06
435.2852783	0.05
440.0855713	0.09
449.1255493	0.07
451.7836914	0.02
461.4960327	0.03
464.9930420	0.73
466.8939209	0.02
468.6464844	0.43
470.6873169	100.00
471.3360596	0.16
482.8740234	0.61
494.0292969	0.04
509.4311523	0.08
540.4840698	0.10
552.1652832	1.48
554.5209351	48.99
555.2397461	0.57
592.1329956	0.19
592.8671265	0.18
603.9216309	0.03
620.4975586	0.04
638.5080566	1.04
639.3126831	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.151
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
161.3094025	0.06
169.0494232	0.04
175.0604553	0.02
199.1339569	0.02
239.0806885	0.06
241.0557556	0.02
269.0833130	1.57
281.3837891	0.01
284.1509705	0.25
285.1830444	0.97
292.8290710	0.06
296.9385071	0.04
309.1427002	0.02
321.5195618	0.01
327.0299683	0.06
351.1569214	0.04
363.3457642	0.06
401.1382141	100.00
402.0305481	0.02
429.1658630	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.8518066	0.44
164.0554657	0.28
174.9895325	0.32
177.0715790	0.05
178.8939209	0.22
186.1194458	0.03
187.0776672	0.29
188.0989532	0.14
201.1252594	0.16
203.1035156	0.77
205.0327759	0.86
212.2700195	0.05
215.1697693	0.25
217.2882385	0.07
227.0197449	0.36
229.0565338	0.08
230.3124390	0.06
231.0570679	0.20
233.0390015	0.04
237.2563782	0.03
243.1419678	0.52
244.0292358	0.07
245.1945953	4.53
247.1968384	0.18
253.1582336	0.08
255.2040405	0.50
257.1806641	0.11
263.1251221	0.05
266.0677490	0.09
268.9506226	0.33
269.6385193	0.02
271.1237488	0.19
272.2218628	0.09
273.0713501	2.80
275.3093872	0.12
281.0408936	0.47
283.2161255	0.07
284.1288452	0.05
285.1514893	0.29
286.0841675	0.03
287.2030029	5.02
289.1652832	29.49
297.2047424	0.10
299.1803284	6.43
301.1544189	0.20
303.0361023	0.12
305.3497925	0.04
311.4024048	0.04
327.2322388	0.10
328.2579956	0.11
329.1473999	0.76
331.1696167	0.63
337.0412598	0.27
339.2745972	1.11
341.2481689	0.10
347.2741699	0.04
356.8880005	0.14
363.1156616	0.16
365.2752686	0.05
367.1495361	0.04
369.3388672	0.14
375.3538208	0.02
381.2545166	3.05
382.2035522	0.09
383.3386841	0.08
389.0397949	0.18
395.2067261	0.02
397.3384399	0.17
405.4288940	0.08
407.1857300	100.00
408.0471191	0.65
409.3488770	0.35
410.0693970	0.03
411.4013062	0.30
414.3767090	0.28
423.4032593	0.28
425.1834106	82.06
431.4099731	0.12
433.1420288	1.20
436.9903564	0.86
449.2118530	1.16
451.2614746	28.01
452.0928345	0.14
457.1858521	0.17
467.2923584	0.72
471.4284668	0.14
473.5211792	0.05
475.3983154	0.23
485.2557983	0.06
491.5200806	0.45
493.3881226	0.21
500.2654419	0.26
501.1779175	0.26
515.3690796	0.55
531.0888062	0.59
533.2460938	1.29
540.9276733	0.10
541.5588379	0.14
559.2828369	9.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1171
Annotation	(2R,3R)-Taxifolin 3-glucoside
Peak:m/z	Relative Intensity
136.8986511	6.86
138.9280396	0.32
153.0712891	0.28
160.7561798	0.09
164.2280884	0.15
178.981842	0.58
192.7149048	0.19
193.9745178	0.13
194.9729004	0.74
203.0883484	0.24
225.4716644	0.15
227.1046753	0.23
245.1350708	0.09
249.1477356	0.06
252.7055054	0.31
256.967041	0.21
259.1401978	1.11
260.9931641	0.21
268.0069885	0.31
273.2460632	0.18
275.0255432	0.43
277.167511	0.08
281.1795349	0.17
285.078064	0.12
285.9208374	0.21
287.1172485	7.05
288.1990967	0.10
303.1929626	0.66
305.0580139	100.00
311.1274414	0.47
312.4335632	0.27
313.3267212	0.38
314.1928711	0.27
315.2406311	0.11
325.2314148	0.25
327.2345276	0.37
329.038147	4.13
336.2582397	0.37
339.4937134	0.07
341.2362366	0.10
347.069397	2.01
350.1639404	0.15
351.1101685	0.33
353.2024536	0.77
353.9758301	0.23
359.147522	0.24
369.1588745	0.22
371.104126	1.49
374.1723938	0.27
375.4345398	0.33
381.2915955	0.06
385.3114319	0.08
395.2541809	0.86
397.0404968	0.17
401.233429	0.09
404.7915649	0.15
408.3140869	0.70
409.2347717	0.20
412.2662964	0.29
413.2408142	0.30
431.2229919	11.12
432.2524109	0.13
443.9846497	0.21
444.6257019	0.17
446.8375549	0.26
449.1555786	59.11
449.7818298	0.62
466.9681091	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1136
Annotation	Asparagine
Peak:m/z	Relative Intensity
86.9089050	2.13
87.8910980	0.04
115.0514832	0.03
115.8828430	0.12
122.1141510	0.08
132.9277039	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.1
Annotation	Ethotoin
Peak:m/z	Relative Intensity
59.9338455	0.02
82.8683701	0.07
95.9004669	0.02
96.7916412	0.01
107.9669342	0.41
109.0516205	0.10
110.9175873	0.01
113.9703369	0.05
115.1007385	0.06
121.0049133	0.03
122.9621887	0.05
126.9515686	0.02
131.8807068	0.21
135.0958099	0.04
138.0892639	0.02
143.5418243	0.04
144.9692230	0.14
145.8499146	0.02
157.2173462	0.03
158.8961792	0.23
159.8847656	0.02
160.8766174	0.06
162.0341797	0.01
163.3223114	0.07
169.0731964	0.16
175.1308746	0.02
177.2052155	0.43
178.8405762	0.02
181.8773346	0.01
187.9959869	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.1851
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
114.9744720	0.30
116.9531174	0.04
126.9413605	1.87
128.1574097	0.20
129.0328064	0.97
130.7003326	0.10
132.7300262	1.42
133.3540955	0.05
138.9981079	0.03
140.9256744	0.09
143.0666351	0.86
144.9570923	3.86
147.1980743	0.20
148.9302063	0.96
149.9802551	0.85
150.9755707	0.08
153.0119019	0.33
155.2589264	0.03
157.0040894	0.94
159.0699768	0.70
160.8927917	2.59
162.9082336	2.32
165.0949707	0.18
167.0223083	0.03
169.0200500	0.99
171.0783081	1.53
175.0362549	1.07
177.1683044	0.32
179.2154236	0.09
180.2204285	0.05
181.1719971	0.14
183.3194275	0.07
187.0397339	2.43
188.8612061	0.39
191.0714111	0.27
193.1300507	0.43
195.3053741	0.31
199.0393372	0.83
201.1925354	0.05
205.0876160	4.68
206.6551208	0.05
208.2915955	0.11
211.0056000	0.50
212.9109650	0.17
217.0306396	4.96
219.2989807	0.03
222.1353607	0.27
222.9706726	3.79
227.0895996	0.04
228.0873718	0.26
228.9856720	0.23
234.1222839	0.20
235.0112305	4.84
235.7722168	0.01
237.1369019	0.03
238.6391907	0.26
240.2427673	2.77
240.9609375	8.37
245.2214050	0.08
247.0177002	0.08
247.6302795	0.04
252.3281860	2.26
252.9816284	13.58
257.6355286	0.34
258.8816223	15.90
259.5422058	0.11
267.8711548	0.18
268.9677734	0.02
270.2779846	2.61
270.8930969	13.95
271.5231018	0.07
273.4923401	0.13
276.3709717	0.61
277.0658569	0.63
277.9656982	0.20
282.9109497	0.15
284.9055176	0.05
287.0583801	100.00
288.0836182	39.05
288.6993713	0.19
293.1786499	0.61
295.0104370	57.64
297.4973145	0.09
300.2884216	0.07
312.0132446	0.38
313.3134766	0.10
315.1891785	0.04
317.0307007	0.14
329.7484131	0.05
330.6910400	0.06
343.1813660	0.15
344.0537109	0.05
348.9710999	0.15
355.1939697	0.12
356.0724487	0.15
361.0266113	0.07
366.8099670	0.20
368.2180481	0.05
374.1932068	0.24
378.2859192	0.13
379.1095886	0.05
383.0325928	0.11
384.9512024	1.14
391.1518555	0.12
393.0854797	0.03
399.7957458	0.06
401.5665588	0.41
402.7168884	8.04
403.4370422	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
438.1398926	8.48
614.4850464	15.77
967.4110718	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
67.0460510	0.11
67.6933136	0.02
68.9013443	0.12
69.9420166	0.17
70.8246307	0.10
71.8085327	0.13
73.9321823	0.24
75.1175537	0.02
78.9703293	0.10
79.9613342	0.03
80.8591309	0.17
82.9305267	0.18
83.8914337	0.19
85.9830627	0.07
86.9713821	0.10
91.9519959	0.03
93.6502075	0.09
94.9935608	0.05
95.8723602	0.04
97.0204620	0.38
98.0611572	0.19
99.9515381	0.04
100.8837738	0.09
107.4595642	0.12
108.2387390	0.11
109.0631409	0.17
110.0298767	0.02
110.9653473	0.13
111.8912201	0.48
114.1371918	0.02
114.9061737	0.12
120.1810913	0.10
122.1184082	0.25
122.7476654	0.09
124.0045471	0.04
125.9144897	0.08
128.0258331	0.19
129.0240479	0.39
130.0556946	0.05
134.9831696	0.10
139.9938049	0.09
140.7366638	0.03
142.7579651	0.23
143.4270782	0.16
146.0753632	0.04
147.0533600	0.05
152.8277435	0.07
154.1100006	0.11
155.0716553	0.03
156.0296936	0.17
157.1405945	0.08
158.9167938	100.00
162.9454956	0.33
163.9454651	0.33
171.1694183	0.03
172.0791016	0.17
176.7440338	0.79
179.0035095	0.03
180.0551910	0.02
181.9075775	3.77
182.9125671	0.15
185.8792267	0.03
187.9361420	0.18
190.3704987	0.44
191.0920410	0.81
199.1990509	0.06
199.8148956	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.2406
Annotation	Ligurobustoside A
Peak:m/z	Relative Intensity
133.1088867	0.26
135.0543213	0.10
136.0411835	0.23
138.0052185	0.44
141.0024109	2.92
143.8579254	0.14
149.1110840	0.15
150.0192871	0.10
151.9967194	0.21
153.0672607	0.34
155.2553101	0.69
158.0174103	0.25
160.3197021	0.13
160.9651947	0.29
162.9517212	5.07
165.0001831	3.27
167.0243835	1.37
173.0454102	0.63
174.2325592	0.17
175.9603119	0.54
180.0730896	45.22
181.2474060	1.73
183.2667236	0.23
190.0746765	0.25
192.3102417	0.21
193.1581116	2.56
194.1885986	0.24
194.9511719	0.23
198.1435547	0.45
199.1243744	0.21
200.1015320	0.56
201.1852570	0.59
217.1158447	0.27
218.5301819	0.96
219.2186279	6.71
220.3852844	0.84
227.0899200	0.36
228.4220734	0.65
233.5009155	0.24
234.1867218	0.34
235.1854553	9.12
236.1906891	20.42
237.2302551	4.62
238.3097687	0.11
243.5742798	0.18
244.2990417	1.10
245.3239746	0.23
247.1146240	0.18
249.2579651	1.07
251.0886230	0.30
251.9211121	0.35
254.2477417	2.59
256.1918640	0.76
261.1673279	6.93
262.3234863	9.09
263.1680603	19.99
266.2136536	0.07
268.2402039	0.26
279.1665039	100.00
280.2455444	67.54
281.2173767	0.19
289.1737061	1.26
292.1204224	0.29
299.2808838	0.08
301.1170959	0.71
305.2301025	5.06
306.3987427	0.38
307.2812195	1.89
308.1677246	0.40
308.8763428	0.24
311.2820435	2.60
312.4765015	0.25
315.2287292	0.11
319.4813538	0.16
327.2630615	0.31
329.4523315	1.86
330.2779846	1.20
331.1777649	1.15
337.3413696	0.61
340.4383545	0.22
341.1204224	0.38
344.2249756	0.21
346.2946777	0.93
347.2336731	0.17
348.3530884	1.61
354.3532104	0.20
355.1893311	3.70
356.3511353	0.30
357.3032227	0.61
358.3485107	2.00
372.1908264	0.76
373.2514343	4.67
374.3113098	41.38
375.4107056	2.21
376.4082947	0.84
381.3080444	0.20
390.3924866	0.69
391.4131165	1.29
399.4368591	0.98
400.4067078	1.70
414.0354004	0.84
415.2178345	4.49
417.4952087	13.72
418.3078613	50.60
418.9248352	0.38
420.2589417	0.30
426.3835144	0.38
434.4317322	0.25
443.1273499	0.41
444.4247131	0.31
462.5825500	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	215.1636
Annotation	5-Oxododecanoic acid
Peak:m/z	Relative Intensity
94.9810333	0.99
96.8330231	1.49
98.9826202	0.24
100.8368073	2.83
109.0452881	1.48
110.9207153	0.55
112.0715179	0.74
114.1031342	0.63
116.7758789	0.87
123.0204315	1.15
130.9576569	1.45
144.0983124	0.37
147.1336212	0.43
155.1187897	3.24
168.9676208	0.73
172.8488922	1.55
179.0296783	8.26
183.8957520	0.90
187.1164246	2.35
193.8723450	2.96
195.6135864	0.71
197.0612183	100.00
198.1389008	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
215.1494904	0.04
217.1005249	0.11
228.9754486	0.06
231.2175293	0.08
233.0845490	0.13
245.8781281	0.09
271.8715515	0.04
273.0001221	4.02
274.0075073	2.05
274.9621887	1.26
288.9791870	12.45
290.0457764	3.20
291.0504150	2.54
328.8910217	0.05
386.5836182	1.08
387.9893799	2.57
389.0018921	1.81
390.7949829	0.05
402.9579468	32.20
403.9334717	20.63
404.9526367	17.77
431.1947021	0.15
459.0333862	0.07
472.0510254	0.07
475.0092773	0.08
476.1999512	0.10
496.0581055	0.05
497.5333862	0.05
498.2156372	0.12
501.4251099	1.11
502.0717163	1.22
502.9623413	1.01
516.9184570	47.48
517.9130249	100.00
518.8881226	73.51
519.5095825	0.27
526.2417603	0.04
531.1113892	0.02
540.5364380	0.04
542.2321167	0.06
543.9879761	0.15
545.2072144	0.05
560.0449829	0.17
561.2462769	0.19
576.7922974	0.10
585.7302246	0.99
587.0365601	0.86
589.0227661	0.27
603.0197754	0.06
605.0747681	0.07
606.0627441	0.13
612.1381226	0.07
632.9532471	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
97.04890442	0.04
98.8625412	0.20
100.9808044	0.10
106.8877106	1.01
108.9809723	2.56
111.0408936	0.11
113.0054245	0.09
116.9063721	0.84
118.9631958	0.10
120.8675842	2.18
123.0414276	1.42
125.013588	0.17
129.0806885	0.52
131.0875549	0.26
133.0055542	0.65
133.9178009	0.15
134.9480286	2.78
136.8084412	0.69
139.8584595	0.06
140.9719238	0.35
142.9279633	0.74
144.9521027	0.68
146.9636536	2.45
149.0922852	1.90
150.9354553	1.25
153.029892	0.25
155.0220032	0.04
156.9708252	1.07
158.4307251	0.26
159.0746765	0.20
160.9717102	1.96
163.0863647	0.76
165.1334534	0.41
167.0928955	0.23
168.9881592	0.37
171.1877747	0.15
173.1800079	0.58
174.9549255	1.12
176.9678497	0.36
178.9183197	0.07
181.1795044	0.03
183.1457214	1.98
185.3216705	0.25
187.0640564	1.08
189.1630249	1.56
191.0337524	0.78
192.3560638	0.30
193.0972443	0.10
195.2071838	0.10
197.0771484	1.15
199.0550232	0.63
200.9073334	0.42
203.0410614	1.10
204.9290771	1.21
206.9971466	0.09
207.9771118	0.17
209.1697998	0.10
210.9567871	0.40
212.8508911	0.11
214.9819946	1.08
217.1852417	1.74
219.0102234	0.21
221.0226746	0.41
223.3075562	0.85
227.1876526	0.53
229.0795898	0.31
231.1477966	1.09
232.5011597	0.18
235.1420288	0.41
237.047699	0.35
239.3687134	0.18
241.0385437	0.36
243.032196	0.26
245.2544861	1.11
247.1634521	3.28
249.3955994	0.30
251.2885132	0.10
253.1090393	0.32
254.0082703	0.50
255.2623901	0.63
256.7308044	0.40
257.4709473	0.14
259.3363647	0.43
260.3096924	0.14
264.1913452	0.17
265.3729248	0.11
267.308075	0.06
269.4178467	0.42
271.0394592	0.10
272.3210754	0.07
275.1180115	0.13
277.1465454	0.08
279.2717285	0.94
280.915802	0.09
282.6673889	0.21
283.5531006	0.20
284.2489929	0.08
285.1498108	0.54
286.4155273	0.30
287.3104858	0.45
288.1673584	0.38
295.2471008	1.01
297.1555786	0.75
298.0515137	0.12
299.161499	1.26
305.2540283	4.30
310.2404175	0.48
310.8954468	0.23
313.2117615	0.79
320.4021301	0.13
323.2435608	100.00
324.2061157	0.48
332.4741211	0.42
335.3708191	0.09
341.1571045	1.68
353.4999695	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	721.1919
Annotation	5,7-Dihydroxy-3,6,8,4'-tetramethoxyflavone 7-glucosyl-(1->3)-galactoside
Peak:m/z	Relative Intensity
209.1190796	0.20
227.1876526	0.80
228.3615570	0.14
250.9388580	0.75
259.2263794	0.19
269.1331787	1.78
270.2304077	0.20
271.0946655	0.17
272.3973694	0.15
287.0993042	1.58
288.1730652	0.09
293.2614746	0.09
329.2280884	0.77
330.1419678	0.60
333.1900024	0.32
355.2098083	0.28
373.1173706	5.77
374.2750244	1.89
397.4640503	0.04
415.1627197	4.41
416.1990967	0.46
421.3339233	0.15
433.1679688	100.00
434.1751099	39.79
434.9276123	0.07
437.4334717	0.55
443.5336914	0.35
461.3359985	0.18
469.1936035	0.08
470.2546387	0.17
475.1553345	0.18
476.6272583	0.24
492.3451538	0.06
497.4304810	0.26
515.3726196	0.10
557.4296265	0.08
560.0636597	0.32
577.3200684	0.36
593.4326172	0.10
601.5592651	0.67
602.4693604	0.22
639.7251587	0.11
661.4459229	5.63
662.3670044	4.74
703.6881714	0.81
722.2293701	0.79
723.5604858	0.60
725.0934448	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
124.7924652	0.03
129.0745239	0.15
137.7885132	0.04
139.0559692	0.03
142.9838867	0.32
151.1419525	0.01
152.9768372	0.30
154.9686890	0.06
158.9832153	0.68
161.0242004	8.78
161.9378357	0.54
164.4396973	0.04
165.2930603	0.03
179.0959167	0.46
181.0540771	0.06
192.0850067	0.03
225.1746521	17.84
226.1716003	2.37
237.3417969	0.08
249.4061279	0.05
252.8751831	0.06
255.1145020	0.18
263.0466919	0.08
267.3193970	0.15
271.1419678	0.25
275.2158203	0.09
282.9447937	0.05
292.3029785	0.05
296.9679871	0.03
302.1146851	0.11
303.1885986	0.07
305.3008423	0.05
309.3262329	0.12
310.3357544	0.09
313.1113892	0.07
315.5127258	0.03
318.3776245	0.10
333.0221558	0.02
337.2450256	0.05
341.3121338	0.02
343.9042053	0.04
348.4635925	0.07
356.3137207	0.02
369.1449585	0.08
371.3302612	0.18
372.4787292	0.03
387.1907654	100.00
388.2619629	12.74
389.3974915	0.04
390.1743774	0.12
391.0932922	0.09
413.3115234	0.15
415.5395203	0.03
416.2132263	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3147
Annotation	Unknow
Peak:m/z	Relative Intensity
224.1443634	0.09
242.2189331	0.14
271.3347778	0.03
277.3066406	4.92
281.2993774	0.02
298.9962158	0.02
319.6174316	0.04
337.1931763	0.02
347.1642456	0.08
355.4162598	0.04
413.1992188	0.03
431.2871704	0.06
451.3323975	0.03
473.4655762	0.06
502.3983765	100.00
503.4080200	0.20
505.5637817	0.08
515.6360474	0.11
516.5286865	0.06
525.8294067	0.01
526.5584717	0.02
543.4567261	0.08
562.6281128	0.03
563.4152222	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0773
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.9443054	0.24
151.1861877	0.11
161.1434326	0.10
162.9569397	0.24
217.0182190	0.20
231.4174500	0.15
236.0896606	0.11
238.0484619	0.06
245.3380127	0.03
251.2272034	0.09
253.3210754	0.07
255.3107910	0.12
256.9986572	0.06
259.4377136	0.06
273.3623962	0.18
274.7304688	0.12
281.2201233	0.05
289.0696411	100.00
290.2303162	0.11
291.2769775	0.58
293.1258545	0.03
316.9246216	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.8205872	0.36
162.0350494	0.07
164.9939880	0.04
174.9240112	0.08
178.2526398	0.04
179.0463715	0.11
185.9281464	0.04
187.1799622	0.23
188.0122070	0.09
199.4152679	0.21
201.0287781	0.20
202.0182495	0.04
203.0329895	0.48
204.9115295	0.59
206.0142212	0.04
215.1090698	0.05
219.3382416	0.10
225.2449951	0.18
227.2186584	0.32
228.3105774	0.13
230.1383667	0.04
231.1551208	0.25
241.1828613	0.05
242.9287720	0.18
244.5610809	0.21
245.1833191	2.83
246.2034760	0.83
253.2955780	0.04
255.2794342	0.51
256.1411743	0.26
257.2455750	0.17
258.9943237	0.13
269.0998230	0.38
270.0639038	0.03
271.1944275	0.16
273.1457520	3.15
275.1588745	0.03
277.1788330	0.02
281.1077881	0.28
281.9721680	0.10
282.8316650	0.10
285.1274414	0.13
287.1707153	6.12
289.0893250	24.12
290.0887451	3.09
295.1986084	0.09
297.0486755	0.19
299.1775208	6.58
300.0864563	0.65
301.2749023	0.08
305.1028442	0.04
309.3480835	0.12
313.2458496	0.29
316.2700806	0.04
323.2371826	0.05
327.2597046	0.13
328.0382690	0.09
329.1859131	0.57
330.0927734	0.39
331.2733765	0.39
332.1316528	0.06
339.2182007	0.36
340.2610474	0.04
341.1170654	0.24
342.3363037	0.09
349.2110596	0.04
357.3113403	0.13
363.3099976	0.20
365.3077393	0.06
369.3265991	0.08
377.2654419	0.04
381.3206177	1.78
382.3145142	0.31
389.0658569	0.30
393.0499268	0.06
395.1548462	0.05
405.2033691	0.09
407.1777344	81.72
408.2695312	17.30
409.2440796	0.67
410.2652588	0.14
411.5598755	0.14
412.3043823	0.06
415.3433838	0.11
416.4246216	0.07
418.1140747	0.11
423.1738892	0.49
425.1491699	100.00
426.2235107	17.67
429.4207764	0.40
431.5428467	0.02
433.2411499	0.58
434.3057251	0.49
436.1554565	0.18
437.3231812	0.14
438.2922363	0.08
445.3465576	0.02
449.1447144	1.56
451.1832275	24.73
452.2203979	4.63
452.8399048	0.05
455.1273193	0.09
467.2312622	1.20
468.1842041	0.26
471.3131104	0.22
472.3717651	0.06
474.1697388	0.05
475.0736694	0.09
488.9473877	0.04
491.7317505	0.64
492.6642456	0.07
501.2733154	1.18
505.3325806	0.07
508.1681519	0.07
509.1004028	0.05
513.5219116	0.09
515.0460815	0.16
515.8735962	0.31
516.6393433	0.04
518.2291260	0.07
531.1736450	0.25
532.0897217	0.15
533.5119019	1.16
534.3566895	0.10
535.2432251	0.27
541.3742676	0.06
546.1669922	0.04
559.2163696	7.50
560.2973633	1.97
561.2963257	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1397
Annotation	4-Hydroxy-3-prenylbenzoic acid glucoside
Peak:m/z	Relative Intensity
106.0511703	0.03
161.0595245	4.23
187.3593750	0.07
205.0574646	100.00
205.8423920	0.04
236.8411865	0.01
239.1194458	0.02
243.1950989	0.04
247.2150269	0.08
275.2463074	0.05
277.0577087	0.07
285.4005127	0.30
286.2090454	0.02
287.4495239	0.13
293.1073303	0.08
295.1682739	0.05
303.3259277	0.22
305.3156738	0.08
307.0296326	0.11
311.5642090	0.05
321.2532349	0.30
331.3758240	0.14
336.2610168	0.03
338.2014160	0.14
347.1567688	0.24
349.2197876	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.2
Annotation	Unknow
Peak:m/z	Relative Intensity
113.0060196	1.87
118.9550247	0.43
121.1222000	0.30
125.1768570	0.28
129.0223999	0.43
132.9518738	0.07
134.9645233	0.39
139.1756439	1.26
142.8681335	0.84
145.3100891	0.09
146.8998718	0.29
149.0231018	0.16
161.0719757	4.22
172.8239746	0.29
178.9858398	2.91
183.0283508	92.37
188.8832703	0.45
190.9848175	1.62
193.2058716	0.53
194.9740143	0.49
197.1912384	0.21
207.1118317	14.82
211.2914734	1.36
225.1085815	2.48
229.1564331	4.79
237.2642212	0.45
243.1818848	0.51
255.0163574	0.74
265.0454407	0.11
267.1548767	0.28
272.7695312	0.39
284.8572388	2.76
285.5112915	0.06
301.1813965	0.27
303.2191772	0.30
329.0385132	0.33
345.0226440	100.00
345.6834717	0.42
347.2335205	0.18
354.9226379	0.11
363.1263123	0.09
372.7660522	0.66
373.3787537	4.88
END