#DEFINITION	Reference Metabolome for Phaseolus vulgaris
#IDENTTFIER	RefMeta-Phaseolus vulgaris.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Phaseolus vulgaris
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Phaseolus vulgaris was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0884
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
163.5402985	0.03
174.9482880	0.13
180.1632690	0.13
193.2954407	0.05
194.3608093	0.04
205.2351379	0.07
217.1594849	0.04
222.9705658	0.06
224.0418549	0.19
225.2325592	0.04
243.2254791	0.14
251.0173950	0.03
264.9720459	0.08
265.6659546	0.10
269.1466064	0.13
277.2989807	0.03
287.1556396	0.10
290.1307678	0.04
295.1712646	0.07
296.0604858	0.08
296.9729614	0.05
301.3877563	0.09
305.2143555	0.02
307.5435181	0.05
311.1388550	0.26
325.2985840	0.48
326.2864990	0.46
327.2530518	0.08
331.0606689	0.02
338.0333862	0.04
341.1453857	0.11
342.1008301	0.12
342.9978027	0.11
369.4335327	0.03
371.1805420	0.02
373.3214111	0.18
385.1259155	1.96
386.0930786	4.56
387.0976562	2.01
387.7814331	0.01
394.8804321	0.06
397.1113892	0.02
399.2665405	0.08
404.4498291	0.03
405.3883057	0.11
411.2031860	0.04
423.3922119	0.10
431.2786255	0.12
433.4227905	0.13
434.2646484	0.06
445.3502808	0.02
455.3426514	0.08
463.2630615	0.22
465.5607300	0.16
469.5458984	0.05
475.5380249	0.09
486.9556274	0.05
488.9786987	0.17
490.7343140	0.03
503.1137695	0.67
505.1311035	100.00
505.7567749	0.26
511.3680420	0.01
513.4547729	1.55
529.2315063	0.06
530.4038086	0.06
531.2077637	0.24
532.3460693	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2134
Annotation	Stachyose
Peak:m/z	Relative Intensity
202.986969	0.91
221.0373535	3.39
232.4650269	0.33
250.0307007	0.12
251.0417328	0.27
262.7192688	0.09
268.9091187	0.12
280.8565674	1.64
281.5153198	0.05
293.094635	0.13
305.0757446	0.68
310.7412109	0.43
321.2903442	0.13
323.0410156	4.23
340.9520264	23.55
341.5955811	0.09
347.3761597	0.24
365.1781006	0.28
383.1181641	100.00
407.3411865	0.55
412.0688477	0.35
412.9604492	0.94
425.0426025	1.16
439.43927	0.05
442.9177856	12.41
455.0952759	0.32
466.543335	0.94
467.3867188	0.22
471.1665649	0.60
473.0011597	0.57
485.2250977	28.84
503.0073242	2.67
545.2352295	0.59
647.5429077	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
56.9704361	0.07
72.8590851	0.03
84.9191437	2.77
86.9686890	1.08
98.9783325	0.09
101.0774231	0.10
102.9988098	0.07
110.8967896	100.00
117.1042480	0.18
119.1253662	0.07
129.0053864	2.38
130.9249268	0.77
145.0708771	0.02
147.0355072	0.74
154.9398041	0.65
157.4786682	0.09
163.4237823	0.06
172.9162750	37.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	935.2827
Annotation	Breynin D
Peak:m/z	Relative Intensity
265.3620605	0.18
267.0590515	0.07
282.2089844	0.07
283.2072754	0.06
301.1978455	0.11
309.3638916	0.11
311.2624512	0.09
327.4044189	0.14
341.1022339	6.65
369.2807007	0.15
371.1519165	2.15
383.1957397	0.24
387.4323730	2.90
389.1027832	8.73
401.0769653	0.44
403.3044128	0.10
416.3127441	0.05
419.3037720	0.05
429.2080688	1.21
439.5065308	0.10
441.0676270	0.12
461.4224243	0.27
467.5057983	0.08
468.9156494	0.11
487.0903931	0.12
491.3560791	0.06
517.2478638	0.19
530.2599487	0.08
531.0460205	0.11
549.1832886	0.98
550.4448242	0.05
551.4503174	0.13
563.2273560	0.25
567.1423950	0.22
567.8209229	0.10
576.3363037	0.08
577.4841919	0.51
579.5354004	0.12
581.4609375	0.32
593.4347534	1.98
595.2365112	17.39
597.4776001	0.57
611.2070312	24.29
611.9281616	0.08
623.5549927	0.33
635.3247681	0.39
637.2545776	6.61
653.3731689	1.11
658.8787842	0.28
664.9101562	0.70
677.2496948	2.60
679.4057007	0.04
682.7713013	0.38
707.2614136	0.06
713.2733154	0.59
715.9042969	0.07
725.4473267	0.17
737.0373535	0.19
738.2785645	0.53
739.1093750	0.15
740.0736084	0.10
742.9883423	1.56
747.0081177	0.10
755.5612183	0.48
759.3789673	0.13
766.5241089	0.05
771.4522095	0.11
773.2232666	6.90
773.8599243	0.06
777.2049561	0.26
784.9332886	0.60
788.4440308	0.13
791.0432739	100.00
791.7632446	0.24
793.0444946	0.08
811.0645752	0.22
819.1016846	0.13
833.0195923	26.20
833.8524780	0.07
871.5512085	0.53
873.1085815	12.43
887.1040649	0.04
891.4865112	0.28
899.2730103	0.34
917.0891724	3.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1982
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.1056061	2.01
245.0392151	2.11
247.0479431	0.24
250.2014771	0.17
255.0325928	0.44
256.8523254	0.10
259.2142334	0.50
260.9687500	1.51
269.3094482	0.48
270.9379883	0.50
272.9791870	0.65
279.1388550	0.32
281.0300903	0.40
283.0871582	0.64
284.2339783	0.45
284.9827881	0.78
287.0561218	11.51
287.6813354	0.44
289.1081848	5.66
290.1870117	0.31
293.3851624	0.10
297.1118774	0.29
299.1415405	2.35
300.1771851	0.12
303.1417542	0.38
304.9598389	0.11
311.1098022	0.33
314.3331909	0.12
315.2489929	0.30
319.5238037	0.12
323.2666626	0.12
326.9204712	1.08
329.2874146	0.97
331.2459412	1.03
335.1821289	0.16
337.0496216	1.41
338.9072266	0.48
341.0372314	1.42
343.1371155	0.15
345.2295227	0.27
347.1594543	2.35
348.2504272	0.27
349.1594238	0.33
353.2150269	0.64
357.1564941	0.15
363.1081543	6.01
365.2904053	1.78
367.2294312	0.72
369.2338867	0.22
374.3078308	0.06
377.3305054	0.39
379.1855469	0.26
381.1337891	1.53
383.0310669	1.09
387.0971985	0.39
389.1293335	0.58
391.0502930	0.57
393.1280518	0.28
395.2436523	3.86
396.6853027	0.07
405.0733032	7.35
405.7793579	0.15
407.1890869	30.64
409.2415771	1.63
411.0263062	0.11
413.1557617	6.03
415.1033936	1.24
417.2546387	0.18
421.1039429	0.07
423.0938110	5.43
425.1367188	16.39
427.2828369	0.27
431.3224487	0.06
433.2183228	0.52
434.6592407	0.89
435.3350220	1.68
437.2404785	0.21
438.2950439	0.72
439.1591187	0.28
441.4337769	0.16
447.8177490	0.55
449.1348267	16.52
451.1132202	10.94
452.1425781	0.86
453.3721313	0.22
462.9733276	0.14
465.1256714	0.67
467.1583252	3.96
485.2034912	0.42
489.1511841	0.20
493.1702881	1.25
497.3991699	0.16
501.2284546	0.14
505.3262329	0.33
507.1437378	0.36
509.1710815	0.62
510.3876953	0.42
515.2708130	0.97
517.1688232	2.12
519.2674561	0.55
520.8499756	0.45
523.3845215	0.51
525.2523804	2.90
527.4684448	2.52
528.3380127	0.21
532.1760254	0.22
533.1665039	4.17
535.2143555	1.59
539.0518188	0.13
543.1024780	16.28
545.2639160	0.55
548.9593506	0.77
551.3372192	0.46
553.1265259	0.57
557.1567993	6.01
559.2366333	5.99
561.0638428	3.33
561.9558105	0.37
563.3784790	0.10
565.1796875	0.31
569.0381470	4.94
575.1170654	27.14
577.1574097	44.84
578.1118774	0.22
585.0679321	1.00
587.0031128	13.56
588.3446655	0.31
589.8427124	0.23
591.0538330	0.10
592.9779053	1.29
597.5018921	0.05
599.1185913	0.48
601.2659302	0.57
602.3035278	0.43
603.3417969	0.39
616.2150879	0.91
617.0294189	1.14
618.0758667	0.06
619.1610107	3.28
623.3296509	0.48
625.3726807	0.11
627.3756714	0.08
629.2825928	1.32
637.4738770	0.04
641.4362183	0.44
651.1978760	1.09
653.2473755	0.24
655.1116333	0.55
657.2993774	0.09
658.4471436	0.22
668.9318237	1.94
671.0369263	0.31
675.0791016	0.34
677.1802368	5.53
681.1754150	0.49
685.2654419	0.86
688.7799683	0.12
695.0842285	100.00
695.8323975	1.42
697.0231323	0.37
702.3225708	0.22
703.3467407	12.96
704.3145142	0.27
705.5426636	0.17
709.2456665	0.33
711.1898804	1.63
713.1196899	34.18
717.3038940	0.07
721.1723633	2.26
723.5225220	0.24
724.2882080	0.43
725.0534058	0.19
727.1904297	0.59
729.3376465	1.02
736.8714600	0.29
737.8314819	0.69
739.1000977	36.63
739.8942261	0.36
740.8285522	0.15
742.2601929	0.18
745.2694702	0.24
747.4490967	0.63
749.5904541	0.14
755.2357788	1.16
759.3771362	0.59
771.3366089	0.08
778.1283569	0.19
803.4081421	0.89
805.4907837	0.76
818.8932495	0.52
821.0065918	1.79
830.3123169	0.14
834.0974731	0.44
847.2092285	28.16
848.5656128	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1051.5476
Annotation	Unknow
Peak:m/z	Relative Intensity
391.2606506	0.26
405.0350037	0.54
419.3937378	0.51
423.5916443	1.02
424.8816528	1.40
439.5784912	6.15
440.2890625	2.46
441.4558716	6.17
442.5028687	4.69
465.2330017	1.18
466.2665100	2.43
483.1352844	0.41
492.4535217	1.13
509.3293762	0.82
519.4141235	0.75
524.6118774	0.24
535.7094727	1.29
536.4638672	0.71
537.3905029	1.31
538.3427734	5.26
563.4139404	1.35
565.2976074	4.70
566.4901733	9.56
567.3490601	0.57
568.4744263	6.90
586.6325684	0.84
594.7199707	0.22
595.4415283	0.57
599.2512207	0.20
600.6437988	1.37
617.5231323	0.91
625.4059448	0.18
635.4478149	20.13
636.4851074	47.62
663.3352051	1.10
664.5258789	7.97
669.6961670	0.56
681.7457886	0.54
682.3845825	1.31
707.2446899	15.55
708.3422852	45.60
717.4435425	8.21
718.4621582	24.91
725.3366089	5.23
726.4467773	19.31
735.7036133	1.44
736.5976562	3.68
743.4593506	0.26
744.5518188	0.16
777.2950439	0.22
778.0238647	0.78
779.4724121	0.16
788.7337646	1.37
790.6165771	0.70
792.6634521	0.16
802.4758301	1.01
843.4271240	1.06
861.5670166	0.44
863.4487305	10.00
864.5446777	35.71
881.3453369	0.59
887.8002930	0.68
888.6125488	1.37
894.1740723	1.00
905.7420654	7.16
906.6345215	9.25
907.4307861	0.29
908.5417480	1.55
922.1217041	0.53
925.7916260	1.23
926.5643311	3.64
934.5474854	1.63
948.6466064	0.24
951.6190186	6.66
952.4885254	32.45
953.6611328	1.89
990.2578125	1.50
1010.4735110	2.21
1016.6157230	0.30
1034.3865970	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1671
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0256958	1.19
164.9729004	0.08
177.0435333	2.41
179.0721283	0.09
195.0302734	100.00
278.9738159	0.04
279.8496094	0.07
339.1520996	0.16
340.5787354	0.08
341.2818604	0.36
439.0839233	0.46
483.0841675	0.25
501.2993774	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	544.2704
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8353882	0.24
160.8349762	0.82
179.0127258	0.09
276.0546265	0.09
293.0338745	0.31
353.8906250	0.10
366.0296631	1.20
409.4912720	1.54
410.5191040	0.33
432.4362183	0.25
445.2534180	0.13
454.3914185	1.71
463.4935303	17.37
484.1692505	0.28
499.7268066	0.23
513.4496460	0.81
658.4327393	0.19
686.4174194	0.08
733.4328613	0.59
747.6704712	0.43
749.4965210	0.26
750.2101440	0.24
751.3798828	0.46
778.8591919	0.45
795.4948120	4.95
796.6369629	0.69
833.3036499	0.21
834.2935181	0.23
847.4491577	0.15
883.9180298	0.09
891.6948853	0.41
892.7004395	0.16
907.7037964	0.33
909.4783325	6.50
910.5653687	2.76
927.4612427	100.00
928.5324097	42.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	262.1278
Annotation	Epidermin
Peak:m/z	Relative Intensity
83.1564102	0.10
85.9826202	11.31
87.0601501	0.26
99.9868317	0.09
114.8934326	0.03
127.0176849	0.07
129.9591675	0.20
132.0563965	57.23
133.0643311	0.87
135.0147552	0.05
136.8937073	0.02
146.1227570	0.08
147.0696716	0.04
156.9926300	0.12
157.8690033	0.07
160.0056610	0.03
166.2363892	0.07
172.3904419	0.03
184.2675934	0.05
198.0998077	0.42
198.9569702	0.02
200.7798615	0.21
202.2700043	0.09
203.2321625	0.10
206.1385345	0.14
209.6561279	0.14
215.9826050	45.81
216.5878448	0.16
219.0103607	0.11
220.1805725	0.06
220.8690643	0.09
222.1206360	0.06
226.0446320	0.33
230.1482849	0.09
231.1356964	0.12
232.2317505	0.07
234.0610352	0.09
241.5699615	0.15
243.9823456	100.00
245.0901337	0.72
246.7263794	0.07
247.3737946	0.07
250.5930634	0.52
253.0124359	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.2203
Annotation	Unknow
Peak:m/z	Relative Intensity
142.1036987	1.77
143.1306763	0.19
149.9757843	0.22
152.0504456	0.98
160.8548737	0.12
169.1465302	0.17
169.8789825	2.52
170.8484497	0.34
178.7729187	0.12
186.8537140	1.45
188.0150452	0.04
197.2851868	0.19
199.7708893	0.16
202.0365295	2.33
202.7962646	0.33
207.2352448	0.35
209.2570953	0.10
215.2163391	0.14
217.2038879	0.09
224.9924622	1.04
226.0339966	0.10
229.1350708	47.54
230.1477814	0.89
238.6343384	0.07
247.0407257	0.16
248.1184387	0.47
253.0234375	0.16
256.1518555	0.26
269.9928589	0.40
281.1836243	1.29
282.3814697	0.14
298.5539856	1.31
299.3098450	0.22
310.2334595	0.23
312.2491455	14.51
313.1758118	0.75
314.4609375	0.47
317.0509338	0.08
317.7365417	0.22
319.6912231	0.40
323.0693970	1.74
324.4696655	0.10
326.2266846	2.41
326.9224243	0.16
328.3417358	0.06
340.2137451	100.00
341.3027039	4.71
346.0504456	0.32
353.3881226	0.07
358.2805176	9.74
359.1955566	0.36
360.0850830	5.12
365.4110107	0.04
368.3643494	0.40
369.3338013	1.40
370.2931824	0.25
371.2041016	0.28
372.3714600	0.11
383.1495056	0.11
388.5012512	0.05
390.4274597	0.07
398.5449524	0.14
413.3606873	0.54
416.1926270	7.76
417.3210144	0.84
421.0075989	0.22
427.3341370	6.47
428.6003418	0.61
429.2694397	0.18
430.1667175	0.27
443.3094788	0.08
447.2486877	0.12
448.1301575	0.32
457.3113708	2.33
466.4778748	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0737305	0.07
200.0175476	0.09
229.4268646	0.17
272.9624329	8.51
273.9614258	3.15
274.5909424	0.02
384.7767334	0.14
386.9584351	10.21
387.8979492	16.93
431.1913452	0.15
436.2254028	0.08
460.0330811	0.05
461.9607544	0.18
467.9178467	0.43
469.7452393	0.06
484.2120972	0.08
486.2343140	0.28
487.2022705	0.08
499.1505737	0.21
500.8287964	23.48
501.9338989	100.00
530.6349487	0.13
541.8383179	0.56
560.0852661	0.06
561.1586914	0.34
569.7811890	6.56
570.5383301	0.82
571.9000854	2.77
572.9524536	0.08
573.9430542	0.33
583.9343262	0.54
587.9793091	0.24
598.3728638	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1475
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9672852	0.57
165.0292358	1.08
173.0453033	0.21
174.9072266	0.10
178.8479919	0.08
181.0619202	0.30
182.7800598	0.28
191.0766449	0.27
201.0586700	0.42
203.1894379	0.03
205.3064575	0.12
207.1731873	0.16
215.0579224	0.09
216.9232330	0.16
219.2004700	0.11
225.0443726	0.33
227.1543427	0.13
228.9707947	2.10
230.9785461	0.66
232.9683838	0.10
243.1183167	0.61
245.9451294	0.04
247.0457611	24.14
249.0003204	0.22
253.1275482	0.28
257.2633972	0.09
259.1408691	8.08
260.7433472	0.07
267.4647827	0.30
269.1355286	0.64
271.1414795	7.71
271.9528809	0.27
273.0321350	3.79
275.1586914	4.35
283.0504456	3.14
285.0434875	1.42
287.1510620	3.38
289.0520630	16.16
291.0484619	48.98
297.0540161	0.28
298.9424133	0.35
301.0142212	21.13
303.1338501	9.07
307.0601196	0.17
309.9564514	0.11
313.1485596	3.04
315.1965942	1.65
325.2417603	0.56
330.7538452	0.41
333.1317139	2.79
341.2460938	0.14
380.1643066	0.06
381.0888672	0.07
391.3407593	0.17
393.1947632	0.06
397.3585815	0.06
405.1175537	0.09
409.1569214	52.22
411.1957397	8.91
414.8304443	0.14
417.1158447	0.56
421.1077271	4.67
423.2097168	0.90
425.3050537	0.74
427.0366211	100.00
427.7186279	0.55
428.4489746	0.04
429.2921753	0.10
432.2922974	0.33
433.2799683	0.80
435.1340942	8.29
435.8040161	0.21
439.0921631	5.77
440.9180298	0.34
450.0358276	0.13
450.9251709	0.26
453.0933838	27.33
531.4290161	0.19
532.6952515	0.31
533.3120728	0.10
534.1193237	0.06
543.0981445	4.83
561.0855713	13.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.2856
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
168.7446899	0.01
173.0536041	0.62
175.2214355	0.27
177.2533875	0.12
183.2093353	0.04
184.2534485	0.04
187.1640778	0.45
189.0890656	0.03
191.1761627	0.05
196.9694977	0.11
199.3408508	0.10
201.0719757	0.31
203.0762329	0.04
205.1319580	0.05
208.9847260	0.04
211.2652740	0.05
213.0897522	0.01
215.2857666	0.04
219.1553650	0.03
225.2168579	0.05
231.0848389	0.06
232.9279480	0.03
239.2507172	0.07
241.1605225	0.12
243.1538391	2.62
243.8753357	0.06
245.1810455	0.15
251.1365509	0.02
253.0868835	0.02
261.1832886	3.25
275.1723022	0.10
277.2575684	0.24
279.2926331	0.40
281.1516113	0.44
287.1748047	0.17
291.2586060	0.31
293.1221313	0.07
295.2778625	0.04
299.2279968	0.91
304.1798096	0.04
305.5336914	0.02
307.0942383	0.04
312.4791260	0.02
313.4772034	0.04
317.1974487	4.45
317.8429565	0.03
335.2548218	100.00
351.2822876	0.04
353.2528687	0.52
359.3602295	0.05
360.2918701	0.05
367.5401001	0.05
373.3681641	0.06
405.4841309	0.04
415.1723633	0.28
423.3048706	0.72
427.2963867	0.04
433.2432251	0.04
437.0604858	0.03
438.1864014	0.04
441.2048950	0.07
442.1438599	0.04
449.4133301	0.06
453.2793579	0.16
455.2673950	0.11
457.2940674	0.04
463.1931763	0.08
465.1302490	0.15
468.9338379	0.11
481.5496216	0.16
483.1129150	0.03
492.8572388	0.21
497.3565063	0.04
503.3085327	0.55
506.3735962	0.05
515.5187378	0.06
521.1280518	0.09
522.3447876	0.04
523.4942017	0.01
525.4756470	0.06
526.9728394	0.08
531.4583130	0.04
535.2464600	0.02
541.4013672	0.03
559.2595215	6.73
577.1168823	22.90
577.7664185	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.1229
Annotation	Tyrosyl-Glutamate
Peak:m/z	Relative Intensity
90.9972534	0.04
94.9060516	0.05
97.0564423	0.04
110.8655624	0.02
119.0488281	0.61
122.9264908	0.43
129.0554047	0.03
129.8629456	0.13
133.9628448	0.23
135.9797363	7.88
137.0917358	0.18
139.1074829	0.02
141.0678711	0.05
147.0572510	0.96
148.1820068	0.05
151.1785278	0.02
165.0674744	21.09
166.1449738	0.04
173.2545319	0.03
175.0491028	0.01
178.2804871	0.04
182.0066223	100.00
182.9805298	0.04
191.2267914	0.08
201.9991760	0.02
205.2857361	0.02
208.1597290	0.06
211.1462708	0.04
218.1934814	0.01
230.4267273	0.03
237.3633423	0.04
238.0765381	0.02
245.1387939	0.02
248.1160278	1.19
251.2440186	0.04
255.0588379	0.08
265.0495605	0.36
267.1721191	0.04
268.9962463	0.02
270.0036621	0.10
275.1732788	0.47
276.0550537	0.03
281.2732544	0.01
283.2937317	0.03
287.5187378	0.14
293.0629883	2.23
294.0937500	7.62
302.1057739	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.24
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
160.9937592	0.06
162.9028778	0.04
164.0345917	0.20
165.2046051	0.22
178.3936005	0.06
179.0389404	0.40
184.1195374	0.02
185.0934753	0.02
186.0796356	0.03
191.1637573	0.02
203.2032318	0.03
219.2315521	0.21
225.0351257	0.02
226.1007538	0.02
227.0748901	0.08
228.2044983	0.14
229.1803894	0.12
233.1404572	0.06
243.4080505	0.03
245.0686951	0.07
255.4399109	0.03
256.9797058	0.21
258.1837463	0.04
261.3380127	0.06
263.4546204	0.04
269.1519775	0.11
271.1118469	2.06
273.1987915	0.48
275.2731934	0.11
283.2233887	0.16
289.1123047	0.05
291.6490479	0.11
292.4104919	0.12
293.4735718	0.10
297.1778564	0.04
300.9872437	0.23
304.3800659	0.07
310.2191772	0.10
311.0004272	0.06
319.2728882	0.37
335.1080933	5.73
336.1516113	0.51
337.3884888	0.42
338.5947876	0.12
351.4320679	0.03
360.3901367	0.04
361.4038086	0.04
363.2197266	9.12
364.3409424	0.29
373.6967773	0.03
377.3171997	0.20
379.1214600	0.04
381.2116089	100.00
382.2811279	0.49
382.9700317	0.03
389.1813354	0.05
393.1208496	0.05
395.0790405	0.19
396.3125610	0.10
401.1727905	0.06
407.0738525	1.06
407.7443237	0.04
409.1812134	0.02
417.1555786	1.20
418.1835938	0.04
421.4015503	0.04
423.2653198	14.54
434.1389160	0.11
436.0653687	0.71
437.2114868	0.08
439.5864258	0.03
441.9477539	0.02
445.0079346	0.01
447.0617065	0.03
453.3410034	0.46
465.2302246	0.10
468.9991455	0.04
481.4874878	0.10
483.1489868	1.26
487.4322510	0.03
497.1480713	0.06
499.3776855	0.32
507.3313599	0.19
511.2698364	0.04
513.0347290	0.11
514.6927490	0.02
525.2821045	1.70
526.5914917	0.18
533.9519653	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1711
Annotation	Sculponeatin D
Peak:m/z	Relative Intensity
118.8486938	0.13
119.9625015	0.05
121.1798859	0.04
131.0188293	0.21
135.0178070	0.13
142.7932739	0.13
146.9151154	0.26
148.2253723	0.23
149.0159302	0.11
150.8184509	0.24
155.1473541	0.09
159.1596375	0.46
161.2094116	0.22
162.2897034	0.04
162.9939117	0.09
165.0688477	0.06
166.2159882	0.04
171.1638947	0.60
173.1681824	0.31
175.0582275	0.29
177.1980286	1.02
179.1546936	0.05
180.3772278	0.08
183.3313141	0.15
185.3804321	0.14
187.0804138	0.48
189.1219177	0.71
190.0728149	0.08
191.1734314	0.12
193.0792236	0.06
195.2607117	0.05
199.1587677	0.12
201.0974731	1.67
202.1102905	0.22
203.1791687	0.31
204.9717102	1.11
207.3646851	0.24
208.4124756	0.08
211.2020264	0.03
213.0823059	1.10
214.4070435	0.07
215.4585571	0.22
217.0545349	0.70
219.2152405	1.84
220.3830566	0.06
223.1957092	0.35
225.1175537	0.13
227.3167114	0.33
229.1875610	1.64
231.2181702	15.12
232.2438049	0.41
233.2164917	1.65
235.1264954	0.06
236.2654724	0.09
237.0940247	0.09
239.1986084	0.47
241.2459106	3.57
242.1225586	0.11
243.2339478	0.78
245.2081604	1.14
247.2937012	5.73
249.3462524	2.13
250.2969055	0.21
251.0415955	0.27
253.0674438	0.84
255.2256470	0.23
257.2361450	1.19
259.2566833	8.19
260.2670898	0.82
261.1744080	0.34
263.1369934	2.78
264.3574829	0.24
267.4798584	0.12
269.2404785	0.93
271.1794434	7.65
272.3455811	0.55
273.1409302	0.31
275.2490845	0.43
276.1401367	0.22
277.2364502	7.73
278.2811279	1.10
279.2829285	0.39
282.0928955	0.04
283.2425537	0.14
285.2399597	0.90
287.3356018	1.83
289.1154785	12.18
289.8011780	0.10
291.2057495	0.20
293.2610474	0.09
297.2648926	1.00
298.3912048	0.13
301.2503052	0.09
303.2524109	1.38
305.0895081	1.81
306.1509705	0.15
307.3103638	9.11
308.2700195	0.22
315.2392578	2.46
316.1571045	0.09
317.2807617	0.17
319.3460083	0.22
321.2097168	0.08
323.2426453	11.06
324.2692566	0.45
331.2905884	1.59
333.1868286	34.33
334.2376099	2.86
341.1048584	0.36
347.0370483	0.67
349.1933594	1.05
351.2222290	100.00
352.2495422	6.96
353.2050476	0.16
357.3379517	0.09
359.1823120	6.75
360.3625183	0.56
365.4225769	0.05
367.3006287	0.75
368.1854553	0.24
377.3017273	59.95
378.2236633	4.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1816
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.9971313	0.86
118.9293900	1.78
125.0931091	0.42
130.7218170	1.32
143.0654602	0.86
144.9637756	0.13
147.0911102	4.81
148.0042114	0.25
148.8114166	1.12
160.8993530	0.92
163.0752869	0.73
164.0766602	0.34
165.1879883	2.18
179.2259827	0.53
191.1784363	9.22
193.1791687	0.10
209.1726990	100.00
210.1194153	0.72
211.1057129	0.83
219.2250214	0.06
227.1669006	4.30
239.8166809	0.20
241.9451904	0.38
242.5842896	0.08
251.1446533	0.19
259.8321838	0.49
281.9815979	0.10
309.3538208	0.21
315.0399475	0.13
317.1979675	0.66
326.9718018	0.13
343.2252808	0.79
345.1958313	0.54
346.0058899	0.06
353.2348328	0.18
361.0976257	0.06
371.3110046	17.96
372.2973328	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.1508
Annotation	Unknow
Peak:m/z	Relative Intensity
153.8959656	0.03
156.0367432	0.03
181.1914368	0.01
184.1092377	0.01
192.2324219	0.04
199.1312561	0.08
201.2859497	0.05
202.1241608	0.17
217.9012451	0.08
219.1625824	0.03
220.0773315	0.03
225.1124268	0.04
229.0095062	0.23
230.0289001	7.45
247.0703125	3.40
247.9067688	0.23
250.1507874	0.01
253.1224365	0.17
265.0780029	6.32
271.1455078	1.70
278.0261230	0.42
286.7286377	0.05
297.0604248	0.03
298.6981812	0.13
316.1253662	0.29
317.0427246	0.14
318.2222290	0.03
319.2177734	0.10
328.1792603	0.01
329.2550659	0.09
331.3405762	0.05
334.3444824	0.26
336.0933228	0.17
337.0929565	0.95
345.9932251	0.05
347.1524048	1.60
347.9830322	0.03
348.9960938	0.03
358.2048950	0.01
364.1377563	1.35
365.1356201	12.01
372.9704590	0.02
376.2136841	0.17
382.1137085	100.00
382.7537231	0.14
397.2700195	0.03
399.2662964	0.15
427.1272583	0.28
445.1192627	0.26
448.0792236	0.52
463.0851440	0.10
475.0881958	0.16
493.2866211	2.29
494.4065552	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.28
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
305.4729004	0.01
323.1860352	100.00
325.2251587	0.03
448.9329224	0.03
495.3209839	0.03
509.0855713	0.04
572.3527832	0.02
611.2382202	0.02
627.2961426	0.01
629.0641479	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.2659
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1824188	0.11
241.1508179	0.41
245.2826538	0.03
253.1349640	0.05
275.3383179	0.04
286.5252075	0.11
288.6153259	0.03
293.1432800	0.17
295.2059326	0.05
301.1941528	0.09
312.9936829	0.05
323.1863403	0.05
355.1740112	0.18
367.3745117	0.11
371.4337158	0.01
373.2376709	0.14
374.8696899	0.01
401.1682739	0.35
415.1315918	0.18
416.9820557	0.02
418.0773926	0.03
419.1651611	2.32
421.3195801	0.02
427.3093262	0.03
433.2966309	0.02
443.2644043	0.18
457.0349731	0.08
461.1801758	1.20
462.4267578	0.08
467.2698975	0.02
481.2260132	0.06
486.9051514	0.05
492.9733887	0.02
496.4062500	0.04
497.4296875	0.07
499.3554688	0.05
501.2644043	0.13
505.3526001	0.06
517.1930542	1.51
528.9987793	0.08
545.4182739	0.05
549.2399292	0.04
559.2144165	0.25
563.2423706	0.41
564.8367920	0.02
577.2399902	0.04
581.0561523	0.15
583.3521729	0.06
589.3095093	0.15
591.3152466	0.11
593.0140381	0.25
599.2892456	0.06
604.3167725	0.10
609.3476562	0.19
611.3224487	0.10
625.3856201	1.86
633.4027100	0.10
643.2260742	100.00
643.8412476	0.31
661.2349243	1.35
667.2445679	0.55
669.1943970	0.19
671.0780029	0.02
672.9351196	0.07
685.2160645	37.89
706.6655273	0.09
707.2941284	0.13
709.2600098	0.09
715.5660400	0.02
725.3333130	10.37
727.1198120	0.74
728.1857300	0.09
743.2780762	0.17
751.8004150	0.12
755.0560913	0.02
764.1475220	0.10
768.0709839	0.07
769.0532837	1.11
777.8136597	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	426.88
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9006042	2.83
228.8806305	0.60
244.8036194	0.11
271.0889587	0.88
272.9620667	100.00
273.8505554	0.13
274.9607849	0.19
275.9530334	0.07
276.8825073	0.19
279.0346985	0.14
311.0733032	0.60
312.9519653	6.13
314.2472229	1.48
315.0286255	2.74
317.0825806	0.34
323.2909546	0.08
324.3705750	0.08
325.0608215	0.21
330.7571411	1.28
331.9174805	0.24
332.9226074	0.24
334.8950195	0.08
337.0542603	0.08
342.2896423	0.10
353.0128174	6.74
353.9598999	0.12
355.0075073	0.40
362.9650574	0.52
364.9090271	0.16
371.0463562	2.47
379.3060608	0.06
380.9962158	1.51
382.9157715	9.32
383.9912415	0.44
398.6800232	0.37
399.3486328	0.04
400.3125305	0.29
408.7827759	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1086.05
Annotation	Unknow
Peak:m/z	Relative Intensity
338.8350220	2.39
351.3115845	0.60
367.3515015	0.26
392.6812744	0.64
405.2311401	15.35
415.2981873	1.00
419.1769409	0.69
422.7123413	4.80
423.4114685	37.03
439.4515991	0.33
441.2122803	3.09
451.5074158	1.70
464.8829956	2.04
482.9906006	1.28
485.3007507	0.44
499.9081421	0.24
501.1298828	2.14
508.9913330	2.17
549.2820435	9.48
566.9476929	45.81
581.3507080	71.04
584.2515869	5.22
585.1782837	4.65
599.1000977	7.98
599.7258301	6.25
617.1102295	5.92
725.0661621	100.00
725.7799683	1.40
742.4752197	21.28
743.1145020	19.35
746.1865845	0.63
760.3504639	5.54
761.0350342	7.20
904.6851807	1.47
908.6549072	3.02
923.1043701	30.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.3041
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0467834	0.57
197.9368286	1.24
205.0424042	2.28
215.9114990	0.14
224.8548584	0.13
243.1361084	0.73
244.2093811	1.49
261.0765991	100.00
272.6899414	0.05
291.2827148	0.26
311.1489868	0.11
363.2771606	0.22
379.2434082	0.24
387.0750122	0.17
397.3086548	0.16
446.7432861	0.32
452.8757935	0.43
495.2310791	0.13
510.9406128	0.09
528.6777954	0.27
531.4973755	0.24
546.8189087	0.64
564.9589233	0.14
577.0883789	0.07
605.6521606	0.13
608.8274536	0.17
621.4236450	0.26
639.0855103	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.1596
Annotation	Unknow
Peak:m/z	Relative Intensity
82.9586792	3.59
83.8518448	0.32
85.8990479	0.10
100.0156631	30.84
107.1249924	0.17
113.1217346	0.02
119.2741165	0.03
120.0919952	0.02
129.9996033	0.44
133.2350006	0.02
137.0598755	0.07
138.9649048	1.62
145.9805145	100.00
147.9110107	0.74
149.0328369	0.44
165.0068359	0.02
180.8698120	0.06
183.0656433	0.21
184.8063965	0.07
187.2894897	0.07
195.9685974	0.12
201.2331238	0.06
212.1397095	6.06
215.0310669	0.07
223.2150269	0.02
229.0618591	1.12
233.0642090	0.34
234.1005554	0.04
239.2164917	0.38
245.1425171	0.06
247.2141113	0.08
248.2712097	0.04
254.1400757	0.27
257.0548401	5.70
258.1498108	24.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1
Annotation	N-Despyridinyl rosiglitazone
Peak:m/z	Relative Intensity
84.0388489	0.03
87.0314865	0.03
88.9308777	0.33
92.9914932	0.02
101.9978180	0.26
102.7895279	0.08
103.9658813	1.91
105.8790588	6.26
107.0145264	0.04
118.9404068	0.11
120.0551300	0.18
130.1803284	0.02
132.8866272	2.89
133.9948120	2.19
134.9325867	18.16
137.1989136	0.04
139.1773071	0.04
147.9270325	0.28
149.9622498	15.22
150.9396820	7.57
151.9402466	100.00
184.5853119	0.14
217.1127625	0.85
218.0484619	1.95
224.0689697	0.09
231.0693665	0.02
235.1503906	0.22
239.4242554	0.03
245.3222656	0.03
250.0378113	0.02
261.2489624	0.05
263.0985413	2.14
264.1073914	8.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.3176
Annotation	Cussoracoside C
Peak:m/z	Relative Intensity
213.1190186	0.09
227.2371216	0.14
231.1800995	0.27
235.3789215	0.10
241.0553436	0.21
249.3736267	0.09
255.1127319	0.19
259.1732178	0.31
261.1190186	0.08
264.5470886	0.07
273.2816162	0.52
285.1269226	0.25
289.2516479	0.23
297.2656250	0.16
299.3398438	0.09
305.0271301	1.06
307.2322998	0.17
314.9737549	0.04
335.2312012	100.00
335.8530273	0.48
349.3901978	1.49
354.2576294	0.11
370.3374634	0.41
375.1271362	0.17
377.0094604	1.09
377.6154785	0.33
385.1465454	0.06
387.1662598	0.06
402.0173340	0.13
407.4418335	0.06
417.0224609	0.06
419.0179443	0.39
419.6793823	0.03
435.3229370	0.19
437.1472778	0.10
439.0497437	0.13
443.1383667	0.06
458.9427490	0.09
461.2373047	0.61
463.2862549	0.09
473.3116455	0.13
478.6606445	0.08
479.2904663	0.59
487.3724976	0.13
497.0407715	3.16
497.7339478	0.20
499.2985840	0.07
527.0967407	0.27
531.0602417	0.28
537.2877808	0.07
539.1168823	1.65
540.7525024	0.15
547.1189575	0.22
555.0293579	0.10
559.0908813	0.19
564.0784912	0.08
565.1668091	0.08
579.0228882	1.23
580.3733521	0.49
581.3898315	0.98
595.2058716	2.80
596.4593506	0.12
597.0991211	6.51
598.5001831	0.06
605.0333252	0.18
606.2575073	0.09
609.1251831	1.04
613.8668823	0.08
617.9207764	7.68
623.2564087	2.41
624.2701416	0.07
627.0847778	0.05
639.5912476	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.2042
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1640930	0.43
197.4036407	0.04
205.0624542	0.55
209.2195435	0.03
216.1275024	0.04
237.2249298	3.62
249.1070404	0.64
279.0685730	0.36
281.0983276	100.00
281.9296875	0.04
316.8713989	0.07
340.8505859	0.17
373.3239746	0.11
386.2691650	0.06
393.3427734	0.28
400.5663452	0.34
434.1143799	0.20
442.4475098	0.08
454.0508423	0.20
460.9122314	0.24
471.8883057	0.07
473.0946045	1.17
473.7636719	0.03
476.3133545	0.03
486.2592163	0.32
494.1001587	0.24
499.8269653	0.04
524.3190308	0.07
524.9848022	0.31
539.2215576	0.09
548.9349976	0.04
562.4353027	0.05
577.2896118	0.14
579.3171997	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1113.5463
Annotation	Soyasaponin bg
Peak:m/z	Relative Intensity
465.1853027	0.06
480.9720459	0.05
509.7713623	0.07
521.4282227	0.12
525.3485107	0.11
540.4066162	0.10
593.5993652	0.25
609.4024658	0.19
621.2031250	0.12
665.4231567	0.15
681.2205811	0.40
693.4978027	0.08
699.4882812	1.06
711.2406006	0.07
717.4534302	0.19
755.3736572	0.05
771.1034546	0.13
789.3419189	0.18
810.2014160	0.03
817.4501953	0.17
835.2601318	0.31
879.3535156	0.28
907.7969971	0.02
909.5162354	0.06
923.7321777	0.36
961.7523193	0.06
963.3863525	1.34
969.1444092	0.04
979.3488770	0.03
981.8343506	0.03
1006.8614500	0.40
1007.4816890	4.11
1013.7028810	0.06
1016.4111330	0.48
1025.4086910	100.00
1026.1762700	0.09
1053.4118650	0.02
1054.9588620	0.28
1055.6220700	0.19
1069.1209720	0.04
1095.7304690	0.12
1097.3942870	2.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	599.2859
Annotation	Chisonimbolinin D
Peak:m/z	Relative Intensity
171.2323303	0.04
173.1698151	0.08
175.0038605	0.22
182.8003540	0.04
185.2101440	0.10
186.1825867	0.08
187.0704651	0.14
188.8602295	0.17
190.0485840	0.26
201.1443176	0.20
202.0447998	0.03
203.1387024	2.74
204.9952698	1.61
210.9979706	0.42
213.0002747	0.07
215.2285004	0.04
217.1219635	0.12
219.4515381	0.11
221.1605530	1.63
223.1352539	0.20
228.9842224	2.78
231.1042328	2.45
241.5475311	0.04
243.2491760	0.64
244.2766266	0.10
245.2596130	0.33
247.1597137	6.22
248.1585693	0.37
249.1830444	0.30
265.2763672	0.16
267.3645325	0.24
271.1401672	0.13
273.4425964	0.06
274.2537231	0.09
275.3076172	0.62
277.1884766	0.38
283.4205933	0.04
285.4769897	0.19
286.1134033	0.04
287.0756836	0.09
287.9356079	0.35
289.2327881	1.91
290.0655823	0.17
291.0817871	0.89
293.3191528	0.09
299.3893433	0.22
303.3095093	0.09
306.3355103	0.44
307.3734131	1.43
309.2894592	0.34
311.1581726	0.07
314.3379211	0.04
315.2351379	0.39
317.2254639	0.92
325.2171631	0.49
329.2229614	0.26
331.2229614	0.41
333.3402100	8.07
334.1889648	0.14
335.2949829	0.28
339.4916382	0.06
340.3659058	0.07
341.3557129	0.21
343.4021606	0.66
345.3044434	0.21
347.0445557	0.55
349.2987061	0.87
349.9258423	0.28
351.3032227	7.32
352.8441162	0.12
353.4978027	0.15
355.6337891	0.07
357.3021240	1.08
359.5027466	0.17
361.0578003	0.04
367.7039185	0.08
369.2269897	0.36
371.5447388	0.30
372.7322388	0.32
373.4213257	0.13
375.3462524	0.84
377.2383423	1.13
379.2576904	0.30
380.6771240	0.05
383.1670532	0.05
385.6610107	0.08
387.3511963	4.93
389.2768555	0.21
391.5595093	0.44
393.3793335	4.07
395.1917725	0.18
397.3862915	1.12
398.4827881	0.17
399.2446899	0.32
401.1113892	0.25
403.3419800	0.10
405.2919312	0.93
409.3656006	0.69
413.2697144	0.62
415.2447510	1.39
415.8770752	0.12
417.3734741	1.54
419.3840942	2.47
421.1996460	0.23
423.2610474	0.11
427.4095459	0.20
429.3006592	1.35
431.2578125	0.63
432.0793457	0.25
433.3413696	0.51
435.3869019	0.81
437.2093506	0.24
439.4464111	0.39
443.2751465	0.23
445.4413452	0.17
447.3341675	10.18
448.2432861	0.09
449.3768921	0.88
450.4702148	0.05
453.3536987	0.05
454.6065063	0.06
455.5422363	0.08
457.3115234	1.51
459.4018555	1.21
461.2177124	0.96
463.1149292	0.11
465.2476807	0.20
471.3236084	0.60
472.3189087	0.07
473.3287354	0.04
475.4070435	0.19
476.2678223	0.40
477.4468384	1.38
479.3502197	1.71
481.6715698	0.16
483.2917480	0.53
489.3614502	1.88
493.4041748	1.10
495.2218628	0.52
497.3383179	0.88
499.1091919	0.08
501.5382690	1.11
509.3530884	0.48
511.4412842	0.80
513.4487915	0.45
519.4117432	6.32
521.5336914	0.25
523.2904663	5.72
525.4079590	0.13
527.9505615	0.06
532.4234009	0.05
534.8678589	0.23
537.4393921	14.59
538.4156494	0.15
539.2823486	1.12
541.4879761	0.21
545.2012329	0.57
555.3245239	29.65
556.4453735	0.35
557.4823608	0.26
561.1780396	0.09
563.3658447	13.19
569.6110229	0.04
571.5805054	0.07
576.9136353	1.02
577.5863037	0.59
579.7009888	0.04
581.3159790	100.00
581.9268799	0.55
582.8256226	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	665.34
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0167084	0.19
198.0845795	1.04
205.0019379	0.05
243.9801178	1.23
261.1647949	100.00
314.1833496	0.04
374.0142212	0.42
405.1452026	0.13
418.5557251	0.10
421.4281006	0.05
431.7848511	0.31
495.1229858	0.15
503.3668823	0.18
535.4606323	0.11
536.4009399	0.35
551.2089844	0.39
575.3114624	0.19
576.4701538	0.17
579.5248413	0.37
597.6765747	0.04
607.3538208	0.46
608.5509644	0.29
618.9407349	0.08
646.3188477	0.19
647.2992554	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	356.2079
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
108.9715958	0.19
110.9756165	0.30
118.9979553	0.11
128.1149597	0.79
129.9925079	100.00
130.8679810	0.46
132.0486603	0.11
133.0913086	0.80
135.0623627	0.20
145.0502167	1.34
147.0561829	0.10
148.9811707	0.04
161.1032104	0.15
163.0245819	2.70
165.2038727	0.30
178.6189117	0.21
181.1319733	0.20
190.9988403	0.12
193.3018188	0.10
208.1417236	0.22
209.0666504	0.07
212.2692261	0.33
220.2543945	0.13
222.1368103	0.05
225.1140442	0.14
232.5851135	1.22
241.2484436	0.41
246.2463684	3.53
253.1790466	0.11
258.3016357	5.54
262.1090088	0.26
267.0020752	0.41
274.3225708	0.07
276.2404785	3.59
280.1031494	0.06
282.4285278	0.08
293.1870728	0.06
294.2229614	0.25
302.3120117	0.07
309.9960327	0.27
311.2052002	0.13
312.1474915	0.61
320.0983276	1.14
328.8736267	0.30
338.2312012	22.64
339.1480713	0.33
340.9082947	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9956360	4.46
159.9800262	0.54
160.9366302	0.64
198.9921570	0.44
201.0688019	0.53
217.0634155	0.03
218.8785248	0.12
229.1184082	0.57
229.8027649	0.09
231.0765991	0.49
247.0194244	0.11
272.9951477	35.85
274.0226746	11.03
275.0002747	33.59
343.0175781	0.05
345.0176697	0.13
386.9482422	36.41
388.1965637	24.53
388.9353333	100.00
390.9915466	0.11
393.1617737	0.05
395.2761536	0.03
406.0617981	0.08
417.4834595	0.18
418.1428528	0.06
428.8993225	0.11
432.2311707	0.02
440.7439575	0.30
446.3613892	0.02
456.9343262	1.25
457.8140259	0.05
458.8643188	0.34
461.2920227	0.17
473.0429993	0.09
474.6454163	0.07
480.0394897	0.25
497.9111023	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1508
Annotation	Gerfelin
Peak:m/z	Relative Intensity
163.3138123	0.01
164.0350952	0.04
167.0935364	0.25
173.1077576	0.03
174.9022522	0.20
179.0904694	0.32
182.7961121	0.08
183.8983612	0.05
185.1288452	0.06
185.7622223	0.03
187.2452393	0.44
188.1483765	0.27
190.1456299	0.03
199.1118622	0.21
200.9971924	0.13
203.1560364	2.49
205.0076752	1.67
209.2123413	0.02
211.0648499	0.06
212.0579071	0.07
217.1735535	0.08
221.3452148	0.03
225.2917175	0.06
227.2770386	0.33
229.2991180	0.17
230.3115234	0.07
231.2596741	0.27
245.1645203	7.69
246.2943726	0.11
247.0478668	0.37
263.3143005	0.02
270.2106323	0.08
271.2951050	0.36
281.2322998	0.03
287.1135864	0.05
289.0900269	100.00
290.1845093	0.57
291.1319580	0.14
299.2293701	0.09
300.9219360	0.07
313.1459045	0.03
315.1298828	0.08
317.2509155	0.16
328.3103027	0.02
329.2673950	0.04
330.0964355	0.09
331.2285156	0.81
337.1534424	0.03
343.3853149	0.03
364.9086914	0.04
371.3756104	0.14
372.1396484	0.04
380.9048462	0.02
383.1314697	0.12
386.0263062	0.06
386.7121582	0.02
388.2278442	0.05
388.8997192	0.03
393.1540527	0.14
394.1537476	0.20
394.9702759	0.05
395.6207886	0.08
397.4329834	0.12
402.2103271	0.04
407.0745850	0.18
408.1817017	0.31
409.1473389	0.16
411.1887817	0.16
412.8338623	0.05
420.2360840	0.12
423.2921753	0.09
425.2276001	0.56
426.1099243	1.25
427.2366943	1.57
428.1661987	0.03
435.1533203	0.12
439.0972290	0.04
440.2574463	0.12
441.3302002	0.10
443.1785889	0.07
449.7497559	0.11
451.2104492	0.93
452.1735229	0.17
453.3002930	0.24
454.3175049	0.03
459.2023926	0.04
467.4893799	0.02
469.2073364	2.73
485.1093140	0.12
489.1224976	0.26
492.2592163	0.04
493.0897827	0.04
498.3455200	0.12
499.1840820	0.05
501.1931763	0.04
502.1758423	0.05
503.2308960	0.03
515.1817017	0.05
516.3750610	0.23
517.3559570	0.04
518.2440186	0.05
519.2993774	0.02
533.1718140	6.05
534.3312378	0.35
535.2299194	0.67
542.2598877	0.06
543.2839966	1.61
548.2719727	0.20
551.2064209	0.06
560.2561035	0.99
561.1899414	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.3021
Annotation	Unknow
Peak:m/z	Relative Intensity
217.0487671	0.02
239.3432007	0.03
245.4101562	0.02
257.1824646	0.35
259.3101196	0.34
269.6640320	0.02
271.3214111	0.40
275.5208740	0.02
287.2829285	3.03
289.2335815	0.89
303.4266357	0.27
305.3072510	0.80
313.3392944	0.02
323.2777100	0.13
333.3330383	0.80
337.2051086	0.66
351.2614136	100.00
352.0870361	0.01
383.6081543	0.03
399.1252441	0.01
503.1179199	0.04
515.2288818	0.01
516.9989624	0.06
519.3126831	0.02
527.1458740	0.01
537.0480347	0.04
545.1749878	0.05
549.9063721	0.02
574.3262329	0.10
599.0806274	0.04
613.0401001	0.04
622.9277954	0.02
642.9143677	0.02
671.3801880	0.75
672.2970581	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3222
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
166.0438538	0.22
183.9886322	100.00
184.8506775	0.08
240.3306122	0.03
258.2913818	0.22
275.1158447	0.09
389.4305420	0.03
441.5178833	0.03
500.3729858	51.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.3232
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9370422	1.56
183.1792603	0.20
191.2212982	0.21
202.9936523	0.37
215.0317078	0.15
218.9800568	0.15
233.3848267	0.24
257.2889099	0.04
259.5823669	0.16
263.1210327	0.12
269.1782837	0.25
273.4121094	0.23
275.2759094	0.19
277.2567139	33.59
281.1382751	0.11
291.3873291	3.27
300.9896240	0.47
305.3076782	0.21
311.2598267	0.14
313.5982666	0.04
319.2239990	2.03
323.1785889	22.56
331.3223267	0.09
341.1337280	100.00
345.5486450	0.09
348.8670044	0.76
360.6397705	0.15
367.3461914	0.06
373.3392944	0.06
377.4959717	0.25
379.1159668	0.48
401.1949463	0.09
421.0198364	0.62
438.1702271	0.07
438.9783325	0.19
443.2568970	0.05
457.0936890	0.15
480.8109741	0.27
490.9889526	0.05
512.7890015	0.21
537.3954468	0.22
541.4173584	0.15
547.6431885	0.26
555.6779175	0.08
563.4413452	0.25
565.2215576	0.26
569.1385498	0.14
574.0845337	0.29
581.3172607	0.16
583.2371216	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.1347
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
88.7976379	0.77
95.0252228	6.54
96.7551117	2.04
100.9765015	62.14
112.9884033	100.00
117.0635910	0.86
118.9715500	87.63
124.9978180	10.57
130.8699036	28.24
143.0520325	43.12
148.9417877	7.73
158.9122314	0.96
161.0351715	21.44
178.8931580	32.18
179.5072021	0.35
305.7626343	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.1374
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
135.0159607	0.05
137.0577698	0.12
139.0044556	5.89
145.0984497	0.25
146.9154358	1.36
150.9832458	1.76
158.2968903	0.03
162.9928894	1.00
164.9971466	2.95
169.1569366	0.25
174.9168701	0.18
180.8093872	0.76
187.2551880	0.10
205.0692749	1.20
217.2160645	0.13
221.4037170	0.02
229.0482788	0.07
234.9933167	0.67
247.0247192	1.25
259.0740662	0.20
265.0280151	0.69
272.9794312	4.66
277.1222229	2.88
283.1083984	7.19
285.0404053	0.23
291.0493774	100.00
294.9706421	0.42
297.1318665	0.61
300.0189514	0.09
301.1063232	28.08
303.2087402	0.52
307.0081787	0.19
313.0606079	0.44
314.5108643	0.03
315.1381226	3.79
319.1094971	0.17
321.1281128	0.06
327.1029663	0.24
329.1567688	0.20
331.0906982	0.07
333.0328979	2.41
333.6816711	0.05
339.3191223	0.52
357.1040039	3.45
363.0709839	0.24
368.8292236	0.40
381.2770691	0.33
387.0895081	0.17
399.0574341	2.36
417.1212158	7.25
435.1398315	5.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.2712
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9272156	0.13
247.1455994	0.14
269.2648621	0.09
271.1766357	0.19
273.2094727	0.47
281.2600708	0.44
287.0129089	0.63
289.1825256	2.79
297.9471741	0.07
299.0839233	0.56
331.0943604	0.21
339.2802429	0.14
341.6811523	0.15
379.2634888	0.04
403.4068604	0.29
407.1864624	12.32
411.3081055	0.19
423.1656494	0.13
425.1375732	14.92
449.3511963	0.03
451.1427612	1.41
467.1879883	0.09
493.3339233	0.05
499.3900146	0.26
505.1787720	0.04
541.1221924	0.12
559.1640625	0.77
577.1481323	100.00
615.3547363	0.06
632.0520630	0.14
633.2454834	0.23
647.1223145	0.11
661.6998901	0.05
675.4320068	0.03
716.5901489	0.10
720.1368408	0.10
739.1903076	0.09
793.1356201	0.04
813.9546509	0.08
818.7180786	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	871.298
Annotation	Unknow
Peak:m/z	Relative Intensity
259.2166748	3.22
267.1672363	0.06
269.0933533	1.02
287.1423645	3.62
311.1589050	0.75
315.0224609	0.15
329.1825562	0.38
341.1243896	0.24
355.2427368	2.00
379.4015503	0.07
389.2895508	0.09
419.1525269	0.23
431.2550049	2.38
438.1734009	0.19
449.2650146	100.00
465.3782959	0.18
473.4027710	0.40
479.1969604	0.10
480.1844482	0.15
499.3531494	0.25
503.4624023	0.15
517.0072632	1.64
517.6311646	0.13
589.0731812	0.72
590.0856934	0.23
591.1179810	0.31
593.4784546	0.09
611.0910645	57.02
611.8280640	0.29
700.1323853	0.28
726.8988647	0.08
732.8646240	0.10
740.0557251	0.53
742.0183105	0.25
781.0814209	0.08
825.2872925	0.22
827.2598267	0.05
840.4987183	0.13
841.5935059	0.20
853.1406250	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	278.09
Annotation	Angustomycin A
Peak:m/z	Relative Intensity
127.9271011	69.49
128.9616089	56.97
148.0837555	1.79
148.9934692	1.65
167.8553467	0.08
179.9530029	0.12
190.0324249	0.10
197.9492493	0.10
209.0358582	0.10
211.8613586	0.15
214.0633545	0.19
216.1426697	0.10
241.1731567	0.09
242.1874390	6.35
260.1450500	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1475
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.8614502	0.71
165.0318604	1.43
168.9569244	0.11
173.0291748	0.49
177.2026978	0.12
179.1593781	0.18
181.0750885	0.11
187.1999207	0.10
188.1021423	0.09
189.0802002	0.17
191.0429993	0.16
193.1004028	0.17
197.1195984	0.23
200.3760529	0.32
201.0580139	0.94
204.6994629	0.05
205.3044739	0.12
206.8945618	0.10
211.1326141	0.14
213.0446320	0.21
215.1226196	0.08
217.1103363	0.12
218.9454956	0.09
225.0246277	0.27
229.0451660	2.26
231.2731323	0.76
233.1180267	0.50
243.0752869	1.13
244.8297119	0.10
247.1154022	28.34
249.0487518	0.48
253.0196381	0.19
255.1178284	0.44
256.9859924	0.67
259.0794373	7.48
261.1758423	1.09
267.1918030	0.21
268.9886475	0.19
271.0678406	10.78
273.0133362	2.41
274.1921387	0.09
275.1500244	11.85
283.1318054	3.95
285.0886841	0.70
287.1623535	5.61
289.0064697	26.74
291.0606689	60.76
291.6699524	0.11
295.0440674	0.16
295.7614136	0.21
297.1609497	0.20
299.1478271	0.98
301.0832520	19.75
303.1770020	8.41
309.3934021	0.04
310.7882080	0.03
313.2173462	0.34
315.1943359	1.24
317.3289185	0.07
319.1100464	0.53
321.0578613	0.06
321.9778442	0.07
333.2431641	1.60
354.2405396	0.12
355.1696167	0.07
375.7717896	0.09
378.4456177	0.05
393.2600098	0.48
397.2500000	0.11
399.2351074	0.03
401.5209961	0.07
403.0479736	0.12
405.0170898	0.17
409.1163330	67.74
411.1918335	14.62
414.4349976	0.19
417.2791138	0.56
421.1156006	3.15
422.3864746	0.27
423.1116333	0.85
425.4913330	0.23
427.0779419	100.00
427.6832886	0.65
431.2877197	0.04
433.2540283	0.15
435.1764526	2.68
439.0736084	4.40
448.4537354	0.16
450.2072144	0.06
450.9875488	0.23
453.1353760	6.03
490.2378540	0.04
503.1348267	0.10
512.2406616	0.03
543.0623779	2.35
560.6408081	0.16
561.2416382	4.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0856
Annotation	Gerfelin
Peak:m/z	Relative Intensity
104.9496460	0.05
106.1284180	0.06
106.9254150	0.05
111.0742188	0.33
119.0606384	0.26
120.9111710	0.03
122.8985748	100.00
123.8733063	0.21
124.9471054	0.08
126.9634933	0.86
130.1926575	0.03
136.8248291	0.62
138.9443970	98.14
139.8172760	0.07
146.9265900	5.85
150.9861450	23.76
151.9437561	0.03
152.8845673	0.62
155.0421600	0.10
162.9552612	0.21
164.9971313	44.91
169.0774841	0.99
180.8984985	0.74
189.1174011	0.06
197.3291626	0.13
209.2333984	0.05
217.0014954	0.03
227.0905151	0.04
231.0869446	0.03
243.0808716	0.11
244.9963074	0.21
246.3316040	0.11
249.1374512	0.64
255.1002502	0.24
263.0994568	0.12
271.0125122	0.19
273.0726318	20.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
111.1557159	0.05
128.8957825	2.26
137.1352844	0.02
144.8647766	0.09
147.0408936	3.03
172.9969482	2.69
191.0277863	100.00
193.1386414	0.54
204.9523163	0.12
209.1027222	8.85
223.0976257	0.83
255.2046814	0.03
297.3783875	0.06
313.0347595	0.07
323.1426392	0.21
342.9304199	0.15
349.1046448	0.32
367.1553040	7.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1511
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
167.0309296	0.08
174.0529022	0.07
175.0311737	0.05
182.1469421	0.32
182.9951630	0.15
185.2822266	0.08
186.9111633	0.46
189.1461792	0.08
193.1560669	0.04
195.0585175	0.51
196.0535889	0.16
197.0228882	0.43
197.9367981	0.07
199.1789093	0.32
201.1662750	0.03
202.6554871	0.05
208.4207153	0.10
211.1400299	0.19
213.0563965	0.77
214.2436523	0.05
215.0529480	0.02
217.0960693	0.13
219.0688171	0.02
222.9627686	0.20
224.2844849	0.11
226.2133484	0.14
227.1975098	0.46
229.0411682	1.92
237.4347534	0.09
239.0349274	1.12
240.1648865	0.13
241.0047302	0.68
243.1343079	0.11
244.2975464	0.03
245.1392059	0.06
255.0890961	1.32
255.9652252	0.45
257.0745239	3.55
267.2158203	1.75
268.1954346	0.11
269.2023010	0.20
271.3923950	0.03
277.2272034	0.04
280.9428101	0.04
283.1008911	0.80
284.9985046	100.00
286.1003113	3.59
286.7705688	0.07
287.4436646	0.05
293.3110962	0.09
295.1029053	0.04
297.0391846	0.08
298.3663940	0.21
299.2230835	2.14
305.1873779	0.21
324.9523315	0.05
327.0724487	3.61
328.0125732	0.24
335.2746582	0.10
337.0775146	0.09
339.1275635	0.09
341.2421875	0.28
342.1357422	0.19
345.2435913	0.07
349.1934814	0.03
351.1478882	0.02
357.2177734	0.68
358.7556763	0.22
368.1601562	0.07
369.1398315	0.06
384.0926514	0.03
385.2468872	0.06
393.1334229	0.31
397.0133057	0.05
398.1637573	0.18
399.2721558	0.15
413.0431519	0.03
417.3801880	0.31
418.1752930	0.13
423.4887695	0.07
431.2858276	0.82
439.3475952	0.03
440.3068848	0.06
441.0629272	0.20
443.5328979	0.07
445.6500854	0.15
447.1114502	0.23
449.4712524	0.14
451.8145752	0.05
453.2684326	0.22
455.5296631	0.13
458.1052246	0.09
467.2091675	0.06
472.3842773	0.03
473.1414185	0.05
491.0878906	0.02
498.8471069	0.07
500.3339844	0.12
503.4503174	0.38
511.4285278	0.07
531.4077759	0.22
547.0601196	0.11
549.1588745	0.28
551.3284912	0.18
555.0671997	0.19
557.2625122	0.37
565.0539551	0.26
575.1828613	1.07
594.0398560	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.2308
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0221252	2.57
128.9016113	0.04
130.1156006	0.07
131.0359802	1.28
145.2474213	0.02
151.2697449	0.04
153.0935364	0.22
154.3217163	0.03
156.0413513	0.42
170.7454376	0.02
173.0415649	7.67
174.2222290	0.05
179.0752563	0.25
180.0940247	0.09
189.4456482	0.05
197.1464233	0.28
222.4817657	0.16
223.1552429	6.75
224.1178589	0.19
234.1792297	0.04
239.7722473	0.01
241.0922546	3.51
242.1758728	0.40
244.1550293	0.98
247.9193420	0.04
249.1559753	0.23
251.3694458	0.05
259.2161865	2.72
266.1661377	0.70
267.2908936	0.03
268.3945923	0.04
269.2582092	0.22
284.2708130	0.72
286.2859497	9.81
294.5428162	0.06
299.2049561	0.02
309.5611572	0.03
318.3063049	0.04
329.5708618	0.05
331.2607727	0.02
335.2261658	0.08
336.2966309	0.43
337.3039246	3.27
338.2700500	0.16
341.3587036	0.08
353.2441406	1.32
354.4470215	0.62
355.2815552	11.29
362.2343750	0.25
371.3581848	1.43
373.2506409	7.47
374.3099976	0.14
378.7639465	0.08
380.2422791	3.00
397.2450256	100.00
398.3309021	6.03
399.2694092	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.1464
Annotation	Unknow
Peak:m/z	Relative Intensity
102.0507965	0.03
104.9165955	1.14
106.8710327	0.10
111.9478073	0.16
119.0034714	0.51
120.8802643	0.99
121.9131927	10.11
125.0371399	0.51
129.1062012	0.39
130.1073914	0.45
131.0599976	3.20
132.8579407	0.09
134.8246307	0.07
135.9102478	0.52
137.0709534	0.13
138.9676819	2.53
140.9725952	0.25
145.0017395	3.06
147.0968781	10.01
149.0193176	0.25
150.9981995	0.09
153.2189331	0.06
155.1180573	0.22
158.0433350	0.04
160.9521179	0.03
163.0083008	1.36
165.1311646	1.20
166.9885254	0.85
168.9565735	1.89
170.1653748	0.08
173.0878754	3.64
175.2555695	0.20
178.9990234	0.77
180.0993042	0.16
183.9475403	0.21
189.0679474	0.07
191.0222015	23.57
192.9910278	0.26
195.7263031	0.07
197.1842041	0.29
201.1241760	0.10
205.0732117	0.25
205.9987183	0.07
206.9736786	0.02
209.0886536	23.77
210.0881958	0.06
210.8900909	0.03
213.1228638	0.23
214.2080078	0.03
214.9820557	0.03
216.0671692	0.02
216.9105835	0.63
219.0464172	0.86
221.3178711	0.10
223.0734863	0.45
227.1120911	44.32
228.1997070	0.10
229.2686157	0.11
231.3637085	0.14
232.2865601	0.09
232.9728699	0.08
235.9425049	0.09
241.4028625	0.31
242.1214905	0.44
243.6833496	0.05
247.1885986	0.46
248.9282837	0.25
258.8370361	0.27
265.9814453	0.25
267.0847778	0.37
269.4938354	0.16
277.0313416	0.79
282.1744080	1.59
283.3308716	1.05
284.2325439	0.91
285.2285156	0.03
294.2615356	0.92
295.0318604	5.17
300.1107178	0.33
302.3815002	1.65
303.2794800	0.25
303.9389648	0.09
304.8878174	0.03
307.2205505	0.18
312.2846069	4.07
313.0090332	5.17
317.1217651	0.06
317.9777527	0.06
320.2732239	0.04
327.1033020	0.11
330.1336670	100.00
331.0077515	44.68
331.6133728	0.35
338.7973633	0.60
356.0121155	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2032
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
243.0694122	0.68
245.0986633	6.68
247.1095886	0.25
248.1934662	0.18
253.1794891	0.34
254.9718628	0.52
255.9473114	0.08
256.9614563	2.54
266.9096069	0.26
268.9699097	1.12
271.2237549	2.71
273.1178284	1.93
280.1147156	0.13
281.1270752	0.96
281.7501221	0.17
283.2145996	0.22
284.1255493	0.40
285.1535339	0.67
287.1655884	15.92
289.1794128	27.93
290.8703918	0.38
293.2343445	0.23
295.2088013	0.36
297.2193604	0.50
299.1503601	5.69
301.0490723	0.12
311.2853394	0.99
323.4258423	0.19
326.0877991	0.21
327.6091919	0.50
329.1981201	0.66
331.2213135	0.61
337.3695679	0.13
339.2102661	1.11
341.2084656	0.79
345.0559998	0.16
349.2577515	0.16
351.1434937	0.42
353.3695679	0.21
355.1539307	0.25
357.3814087	0.47
363.2803345	0.57
365.0604858	0.19
367.2021484	0.78
369.3613281	0.56
379.3291931	0.61
381.0690918	1.99
383.0994263	5.26
387.2561340	0.28
389.0953674	0.57
391.2269287	1.50
393.0913696	0.25
394.1842651	0.42
395.3582153	0.29
397.2362671	8.07
399.2209473	0.14
404.9660034	1.35
407.1549072	61.33
407.8629761	0.31
409.1954956	4.87
411.3057861	0.98
412.3869019	0.83
413.2192993	1.35
415.4042358	0.92
417.3152466	1.25
419.1995239	1.31
420.9902954	0.31
423.2827148	2.28
425.0806885	46.76
426.1696777	0.23
431.2742920	0.28
433.2951050	7.58
435.2410278	5.97
437.2057495	1.72
439.0216675	0.52
445.2061157	2.20
447.1679077	0.55
448.9861450	2.24
451.1525269	40.14
452.5712280	0.13
453.2427979	0.22
461.4030762	0.30
465.2432861	0.24
467.2346191	0.52
475.2999268	1.37
491.0623169	0.12
493.0401611	0.09
499.2859497	0.79
507.4191284	0.39
509.2528076	0.46
514.6685181	0.19
515.6270752	0.22
517.1384888	2.40
519.1328125	2.08
523.4368896	0.43
525.3388062	0.12
527.1601562	4.45
531.0446777	0.15
533.1625366	2.92
533.8524780	0.19
535.1839600	2.17
539.0517578	0.11
540.0838623	0.19
541.1552124	3.83
543.1962280	5.85
544.4109497	0.64
545.2448730	2.55
549.3691406	0.25
552.0526123	0.30
553.2417603	7.42
555.1242065	0.48
557.6890869	1.00
559.1179199	65.44
559.7616577	0.16
561.1312866	22.59
561.7815552	0.10
565.4663086	0.39
569.1832886	3.09
571.1452026	29.16
573.3497925	0.20
574.2352905	0.40
575.0552368	0.46
576.5913696	7.67
577.2354126	100.00
578.0859985	0.21
579.2287598	0.12
583.3357544	0.79
584.5604858	0.07
585.2985229	0.35
587.1793823	5.13
589.0105591	1.66
592.0993042	0.44
593.3202515	0.64
595.3004761	0.91
596.2621460	0.17
597.2035522	4.67
599.1874390	0.23
600.5127563	0.21
601.1947632	1.22
603.3720703	0.12
607.2633667	0.21
613.4365845	1.67
616.1593018	0.56
618.4722290	0.40
635.4276123	1.05
639.2861938	0.36
651.5112915	0.10
653.1940308	1.37
661.1000366	0.69
664.0939331	0.13
669.1696167	0.40
670.5414429	0.37
675.3510132	0.51
677.1157227	1.27
679.1386108	43.74
686.1637573	0.62
687.2499390	0.22
693.0784912	0.24
694.0986938	0.69
695.2438354	9.89
697.1129150	56.58
699.3287354	0.13
703.0122681	0.28
704.1001587	2.13
705.0798950	2.02
709.2405396	0.40
710.9968872	0.74
712.7066650	3.04
713.3676147	1.92
721.6510010	0.15
723.1602783	52.05
724.2210693	0.64
729.3507690	0.49
739.2313843	1.14
740.6257935	0.17
746.1510010	0.17
763.2996216	0.42
763.9291382	0.36
772.5734863	0.19
787.6297607	0.25
795.3203735	0.10
805.2169800	3.40
813.1862183	1.70
816.2032471	0.09
819.2313843	0.14
821.1950684	0.41
827.4146729	0.95
831.1526489	12.02
831.8811035	0.14
833.1122437	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.17
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1651230	0.20
129.0016022	0.09
136.9599609	0.46
139.1458893	0.10
141.1842499	0.08
143.0493011	0.34
143.9985504	0.12
148.9332428	0.18
151.0379486	0.28
153.1207733	0.03
157.1129456	0.47
158.9554901	0.07
161.0048981	0.56
171.1915894	0.05
173.2143250	0.06
174.8713684	0.90
177.1874390	0.20
183.2650146	0.15
204.9441376	0.10
217.0036011	0.10
225.1109009	0.09
229.3497925	0.13
231.0687866	0.13
242.8656921	0.23
247.0884705	0.10
249.2317200	1.25
251.2070007	0.12
255.0052795	0.07
271.1003418	0.33
273.0954590	4.40
274.0503540	0.04
287.1274414	0.82
289.1477661	0.05
291.3585205	0.05
293.1985474	0.06
299.1391602	0.95
307.3434448	0.25
310.8598938	0.13
328.3593750	0.05
339.2279053	0.50
341.2597656	0.44
341.9019775	0.06
345.3620605	0.47
348.8564758	0.03
353.2678833	0.07
363.4131775	0.67
365.1080627	0.72
366.3310852	0.09
367.5494690	0.03
379.1919556	100.00
381.1773987	2.93
383.1804504	0.48
389.0895691	0.82
407.1430054	58.81
407.7610168	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1412
Annotation	AN-7
Peak:m/z	Relative Intensity
257.2340088	0.05
320.3511353	0.16
403.1468811	100.00
403.7633362	0.24
405.1054077	0.06
431.4916992	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.1263
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
118.9727097	7.55
130.0285339	1.00
135.8896484	12.48
202.0557709	1.33
217.0852356	0.10
218.6394348	0.27
219.2459259	0.06
229.0465088	0.08
241.0138245	0.39
242.2262573	0.04
247.1102295	0.37
248.0531616	1.51
259.1517944	1.34
265.0636292	100.00
265.6692810	0.11
277.1164551	0.23
310.2606506	0.03
327.8263550	0.04
330.1970825	0.09
331.1514893	0.36
346.0359192	0.08
358.0267639	0.15
376.0843506	1.30
377.2066956	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.4765
Annotation	PE(16:1(9Z)/20:5(5Z,8Z,11Z,14Z,17Z))
Peak:m/z	Relative Intensity
233.2805023	0.69
241.2974701	0.03
247.1182556	0.13
255.2085724	0.03
259.1600647	0.24
265.0362549	0.11
275.0693970	0.66
275.7331238	0.07
277.2249146	100.00
277.8420715	0.21
281.5994873	0.12
282.4197998	0.10
289.1229248	0.07
291.1758118	0.08
292.5097656	0.08
293.3652649	0.15
295.2352905	0.10
297.3935547	0.15
299.6277161	0.05
307.3723145	0.06
310.3191223	0.10
312.5488892	0.05
313.3319397	0.05
327.4431763	0.21
328.5925293	0.06
392.1849976	0.17
412.9668579	0.29
417.1013794	0.09
424.0360107	0.12
436.0748291	0.19
440.6075439	0.10
448.0948486	0.10
456.3002319	2.13
474.2460327	13.23
474.8761597	0.18
512.2879028	0.10
514.2472534	0.12
531.8825684	0.14
550.3136597	0.16
557.3826294	0.31
580.2468262	0.10
598.1888428	0.04
600.3480835	0.10
606.4608765	0.12
618.5041504	0.05
637.0473633	0.15
642.2629395	0.13
644.3972168	0.24
653.1231079	0.14
662.7658081	0.07
670.8898315	0.03
673.1209106	0.06
674.6290283	0.49
675.5878906	0.28
688.1765747	0.18
690.3791504	0.30
706.4764404	0.28
716.3712158	1.68
717.3170776	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1305
Annotation	CMP-8-amino-3,8-dideoxy-beta-D-manno-octulosonate
Peak:m/z	Relative Intensity
200.9357147	0.20
218.5993958	0.11
219.2723846	0.15
290.1868896	0.36
296.5967407	0.10
307.2229614	0.05
359.3544312	0.05
363.1716919	2.11
371.2858887	0.24
381.1137695	100.00
382.2448730	0.34
397.1912231	0.05
451.5989990	0.18
461.5825195	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	756.2721
Annotation	Unknow
Peak:m/z	Relative Intensity
225.3385773	0.11
228.8197021	0.08
241.2392426	0.20
247.1856232	0.17
252.0651550	0.29
252.9352417	0.18
271.0079346	1.51
288.0266418	0.34
288.9235535	1.96
302.2242126	0.10
305.8398438	0.46
306.8674927	1.80
321.2320557	0.04
323.1401367	0.65
324.9108582	59.70
326.5092468	0.09
335.2228394	0.07
336.4238892	0.07
339.8263550	0.18
340.6699829	0.05
342.2919922	2.35
342.9639893	14.91
367.1125488	0.46
385.0454712	0.30
400.3898926	0.04
403.1152954	0.20
449.3881836	0.16
450.4539795	0.25
451.1719971	1.14
460.7828979	0.13
468.6502075	0.45
469.5947876	0.06
475.7770386	0.11
483.5017700	0.06
484.2943726	0.08
486.7933350	100.00
487.6869507	0.08
501.6411743	0.13
502.5158691	0.11
504.1569824	10.06
504.8376465	45.98
505.5335083	0.32
541.0310059	0.03
575.9573364	0.06
593.4058228	0.90
594.0875854	7.94
594.6993408	0.05
648.9268799	0.28
664.3422241	0.07
666.2195435	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	935.3813
Annotation	Oxytocin 1-8
Peak:m/z	Relative Intensity
313.4409180	0.04
343.4537048	0.08
369.2456360	0.64
387.1681519	10.64
402.9887085	0.53
411.3485107	0.51
429.2543335	8.75
441.3928223	0.06
443.3529663	0.10
475.3973389	0.25
493.3747559	0.80
511.2395630	0.18
545.3784180	0.04
547.5458984	0.07
549.2755737	1.34
565.2753296	0.74
567.4069214	3.34
575.4658813	0.41
579.2562256	0.10
593.2329712	10.12
593.8445435	0.11
607.5732422	0.53
611.3381958	100.00
617.4557495	0.04
635.2454834	0.23
651.3877563	0.09
653.3560181	5.79
665.2506104	0.78
682.9512939	1.67
683.5999756	0.51
695.3481445	0.10
709.2244263	0.05
712.4738770	0.28
713.2489624	5.95
715.2999878	0.06
737.2221069	0.20
741.1178589	0.15
754.1958618	0.21
755.2529907	5.35
758.3247681	0.27
759.6486816	0.60
765.1826782	0.18
773.2785034	41.08
783.3765869	0.11
799.0171509	0.14
849.3872681	0.22
873.6921997	0.06
875.3175049	0.16
881.4790649	0.15
891.2975464	30.55
891.9506836	0.08
899.4270020	0.08
917.3060303	11.70
917.9415894	0.12
918.6655884	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.15
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
161.1480560	0.47
163.2604980	0.27
165.0614166	1.53
169.3845520	1.29
171.1135864	0.14
173.0653229	0.36
175.3187561	0.59
179.1641541	0.37
181.1034241	0.09
184.9990082	0.39
187.0677032	0.24
189.1524048	1.67
192.9936523	0.28
198.2652588	0.10
199.0484467	0.39
201.0213470	0.18
203.0386505	1.18
205.1500549	0.09
207.3144989	0.18
213.0300293	3.04
215.2348633	0.60
227.1028900	0.25
229.1045532	1.06
231.0252075	37.96
231.9335327	0.06
233.2817078	0.43
237.1174622	0.59
238.9237671	0.81
240.7412720	0.53
243.1297607	3.48
244.0526581	1.45
245.1587677	5.15
246.0808105	0.11
247.1864014	0.69
255.0710754	6.80
257.0126953	1.09
258.9798584	0.44
261.1673584	16.60
267.0968628	2.23
269.3741455	0.12
271.0770874	1.21
273.1303711	58.12
275.1024475	9.72
275.8935547	0.21
279.3845215	0.10
281.2491455	0.24
285.1155396	33.04
286.9887085	5.29
288.4386597	1.05
289.1711426	1.24
289.8166504	0.13
291.0942383	82.87
297.0935669	1.29
299.0786743	1.06
301.1327820	1.30
303.1654663	9.07
308.9730225	0.49
311.0803528	0.43
315.2546387	1.23
322.9315796	0.13
327.1308594	0.54
331.1501465	0.31
333.2560425	1.54
349.1951294	0.11
351.2006226	0.12
353.1411133	0.67
357.1556396	0.37
365.1026611	0.89
376.2600098	0.09
377.1003418	1.13
383.2143555	4.21
387.1907349	0.48
388.2437134	0.26
389.1143799	0.42
391.2960815	0.48
393.1013794	61.97
395.1105957	20.06
395.7583008	0.05
401.0706177	1.04
405.0451660	3.12
407.0914307	2.22
409.1867065	12.37
411.0039062	100.00
411.6778564	0.25
417.8165894	0.57
419.2392578	6.04
420.1516724	0.22
421.2340088	1.92
423.0300293	5.09
424.9954834	2.83
427.1568604	40.48
433.0954590	0.81
435.2351685	0.15
437.0166626	18.80
438.6131592	0.62
439.2767944	2.53
441.0419922	0.20
445.0584106	0.19
448.2617798	0.40
451.3275146	0.38
461.3662720	0.16
481.3920898	1.01
486.2312622	0.22
490.9255371	0.48
503.0370483	0.33
509.4589233	0.30
512.9805298	0.37
516.9774780	0.13
518.9453735	0.16
520.9701538	0.17
522.2380981	0.77
526.5983887	1.18
527.2249756	7.22
531.3593140	0.22
533.5477295	0.14
541.0916138	0.27
542.9318848	1.06
545.0806885	17.85
553.8219604	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.18
Annotation	3,5,7,3',4'-Pentahydroxy-6-methoxyflavan 3-O-[glucopyranosyl-(4->1)-alpha-D-xylopyranoside]
Peak:m/z	Relative Intensity
179.0841370	0.11
191.0138092	0.20
203.1315613	0.54
204.9684143	0.06
220.9297791	0.10
229.3005676	0.04
230.1962280	0.10
241.2198334	0.04
245.2481995	0.17
251.1785889	0.11
252.7627106	0.08
262.8858643	0.06
271.0322266	0.23
273.0187378	0.13
274.3186035	0.39
275.1489563	0.28
289.0728149	18.66
299.1090698	0.96
313.0316772	2.26
324.9448242	0.02
355.1016235	0.02
375.1017456	0.02
397.2511597	0.04
430.1940308	0.10
433.3100586	0.11
447.2083740	0.03
451.1160889	100.00
451.7662964	0.28
453.0430908	0.03
461.3723755	0.02
477.2830811	0.25
493.3118896	0.09
509.1875610	0.10
513.1544189	0.13
515.1408081	0.13
517.2424927	0.13
522.8444824	0.03
529.3135376	0.12
540.1881104	0.05
543.7145386	0.12
551.5713501	0.05
565.6613159	0.17
567.0287476	0.19
569.2937622	0.09
577.1793823	0.13
595.2764282	0.63
596.3779297	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.16
Annotation	Nervilifordin C
Peak:m/z	Relative Intensity
185.0543671	0.03
194.8415833	0.02
199.1279144	0.11
200.1397552	0.03
201.1424713	0.19
213.1920776	0.07
213.9887695	0.08
215.0989380	0.18
240.9139862	0.13
242.2015991	0.14
259.0745850	0.26
285.1187744	0.10
286.1312256	0.85
287.1928101	0.96
301.0853882	100.00
301.7170715	0.20
323.3695068	0.04
331.4571533	0.14
337.2221069	2.08
341.3712158	0.17
343.3413696	0.29
364.9824219	0.16
371.1324463	0.05
373.1653442	0.10
374.1920776	0.06
387.6224976	0.09
416.4244995	0.11
427.3462524	0.08
430.9836426	0.06
434.4075928	0.22
443.2658691	1.94
449.1901855	0.12
463.2642822	0.32
495.0249023	0.49
495.7275391	0.06
503.3715820	0.04
519.3615112	0.14
524.4907837	0.06
537.2620239	0.44
554.2073975	0.32
558.0913696	0.18
561.8517456	0.07
563.2478638	0.14
577.2015991	0.20
591.4768066	0.03
595.0711060	0.40
603.2985229	0.04
607.2402954	0.88
608.2171021	0.18
621.1386108	2.18
621.7556763	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	957.5068
Annotation	Hoduloside I
Peak:m/z	Relative Intensity
323.3065186	0.76
375.4305115	1.29
383.1145020	2.19
391.4580688	1.79
393.0686646	1.04
409.2382202	1.04
421.7213135	0.30
425.6009521	4.11
437.3653564	24.28
455.5140991	5.25
457.3200684	18.90
458.4867554	1.21
480.6756592	0.57
499.2754517	5.11
513.2243652	4.94
525.5083008	100.00
526.6125488	0.65
553.2363892	0.56
570.9079590	0.56
597.3131714	51.40
615.4633789	37.39
621.4309692	2.43
633.5282593	11.68
679.4432983	0.49
733.4452515	26.40
751.4635010	9.19
777.5621338	8.49
778.2083740	0.95
795.4928589	61.81
796.3834839	2.89
895.4157715	39.82
912.1919556	1.20
913.4474487	1.20
921.7455444	1.00
923.4877319	2.28
939.4766235	71.10
940.5418091	6.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1401
Annotation	Gerfelin
Peak:m/z	Relative Intensity
158.2731628	0.04
161.0119781	0.30
163.9464569	1.23
164.9313660	0.17
167.1947937	0.05
168.0691528	0.03
172.9226837	0.13
175.0616150	0.32
176.0117188	0.27
177.0046082	0.06
178.8904877	1.11
185.1322937	0.57
187.1119385	0.78
187.9788818	0.41
188.9860840	0.19
202.4184875	0.27
203.1659851	2.12
205.0282593	1.38
209.1820831	0.12
212.1194458	0.10
216.9952087	0.18
227.0701141	0.83
228.2262421	0.30
229.1906128	0.17
230.1632385	0.08
231.3243256	0.36
237.0679932	0.61
239.1289368	0.12
245.1948242	6.94
247.0992584	0.55
248.1026611	0.10
250.8690491	0.17
253.2914734	0.30
255.0907593	0.23
271.1550903	20.90
273.0476074	4.15
278.7423706	0.30
279.4118042	0.06
283.1423340	2.18
284.1558228	0.10
285.2927246	0.29
287.1547852	0.76
289.0681458	100.00
299.0522461	0.91
301.1219482	0.10
311.3230591	0.04
313.2121582	0.31
315.2523193	0.33
323.1082153	0.76
328.1168213	0.60
329.1571655	4.90
339.1647339	0.30
341.2154541	0.71
357.3200684	0.06
363.7985840	0.07
365.3421021	0.07
370.9332275	0.08
375.3253174	0.06
381.1784668	3.03
391.0638428	1.20
393.2623291	0.32
395.0306396	0.09
398.1221313	0.04
405.1215820	0.14
407.1017456	18.52
409.2125854	6.10
410.1032715	0.54
411.1572266	0.51
413.0110474	0.07
415.3319702	0.04
416.4654541	0.42
417.3119507	0.41
420.1495972	0.08
423.2745361	0.34
425.1045532	23.21
433.1484985	0.50
435.1268311	36.33
435.9880371	0.13
438.2509155	0.30
441.4015503	0.07
451.2112427	0.42
453.3576660	0.05
455.3195190	0.07
458.2023926	0.12
459.1930542	0.15
475.4899292	0.07
477.1477051	0.36
483.2266235	0.09
484.1669922	0.34
492.8098145	0.27
499.2213745	0.90
500.1284790	0.05
515.1060791	0.67
515.7850342	0.11
517.1060181	1.44
525.2473145	1.02
541.2069702	0.09
543.1555786	23.92
543.9145508	0.08
545.3184204	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1034
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.0336456	0.69
87.9578171	100.00
125.9440765	2.15
129.2718048	0.16
144.1599884	0.16
146.0910034	12.90
156.0916595	0.06
168.2829132	0.07
170.0761414	1.60
174.1297760	2.29
187.1200104	0.08
190.1312561	0.28
199.9984131	0.94
202.9895477	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	794.2568
Annotation	Unknow
Peak:m/z	Relative Intensity
262.6283875	0.07
280.7141724	0.05
305.1834106	0.05
311.1136780	0.03
341.0739746	0.73
366.0900879	0.01
383.2207642	0.55
394.1092529	0.06
412.7668457	0.47
430.2797241	0.06
442.8939819	1.22
452.2988281	0.02
485.2888184	0.51
490.9822998	0.05
499.2691650	0.02
503.2344360	0.81
530.1427002	0.21
583.8519897	0.04
599.0302124	0.04
619.1532593	0.01
620.3976440	0.02
632.3429565	0.04
647.3668823	0.01
653.3801880	0.06
665.2166138	100.00
665.8351440	0.11
750.0993042	0.03
775.8679199	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.19
Annotation	L-Arginine
Peak:m/z	Relative Intensity
175.0496216	0.03
194.9443817	1.25
196.0947876	11.38
213.0848389	100.00
232.0556030	11.97
233.1905518	0.10
253.6473999	0.05
255.1524658	0.09
266.8672791	0.05
274.2990112	0.02
300.6358032	0.05
302.9816284	0.57
326.3991699	0.08
340.8876343	0.10
342.0447693	0.02
343.1460571	0.08
344.1468811	0.05
344.9982910	0.02
369.3313293	0.30
369.9951782	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0844
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
76.8322754	0.09
84.0336456	0.01
90.0096359	0.45
118.9104614	91.11
119.6900330	0.05
129.9711456	0.93
135.9358368	100.00
147.8706818	0.58
202.0171814	1.11
217.1149597	0.14
219.1326294	0.29
229.0604553	0.17
237.6375732	0.07
239.0320587	0.02
247.1314697	1.89
248.1183014	10.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.485
Annotation	Acankoreoside E
Peak:m/z	Relative Intensity
333.3174744	0.47
337.1775208	8.60
351.0604248	0.21
355.0912476	9.75
377.5552368	0.21
379.3945618	0.21
393.3273926	0.17
397.1020508	1.40
421.2656860	1.62
423.1246643	2.27
425.1418762	0.67
438.0175781	0.39
438.8504639	0.10
441.4481812	0.33
451.2236938	6.34
457.3164673	0.41
469.1036377	0.57
481.4196167	0.21
483.0549316	0.42
495.1013794	1.05
505.4729004	0.40
513.2011108	100.00
523.0571899	0.22
526.9805298	0.46
539.3993530	0.56
541.5287476	0.32
553.7241821	0.34
597.3676147	0.69
611.5608521	0.44
615.8521118	0.13
629.6056519	0.78
633.2992554	15.38
634.0941772	0.89
639.1511841	1.24
645.3563232	1.52
653.5637817	0.26
694.1212769	0.30
706.2590332	0.12
735.4356079	0.86
736.5043945	0.31
747.6739502	0.84
763.6253052	1.27
773.6703491	0.16
777.2695923	0.28
787.1323242	0.41
788.4983521	0.25
791.4470825	3.61
795.8488159	0.10
809.4706421	0.19
810.7073975	0.19
837.4133301	0.83
841.4927979	1.13
842.3982544	1.14
850.9675293	0.22
855.5037231	0.53
863.0975342	0.08
865.3777466	2.11
879.0247192	0.18
883.4519043	0.77
898.4788818	0.36
907.4142456	0.25
908.3461914	0.28
909.5029297	6.09
923.5607300	0.51
924.5645142	0.21
925.7409058	0.54
926.6287842	0.32
927.5325317	2.16
935.3991089	1.02
939.7745972	1.15
952.9179688	3.27
953.5798340	20.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.2081
Annotation	Unknow
Peak:m/z	Relative Intensity
236.9191284	0.10
239.9283447	0.25
243.1398468	0.56
244.0872345	0.21
245.0701752	1.60
246.2830200	1.22
252.9081879	0.05
255.0498047	0.14
257.0411377	0.67
260.2604065	0.08
264.1735229	1.07
269.0372620	0.35
271.0550842	10.42
272.0876160	6.02
273.1796570	2.55
274.2445984	1.09
281.2655029	0.69
282.0688477	1.38
283.1555176	0.87
285.2907104	0.14
287.2707520	0.73
289.1525269	24.27
290.1066284	8.69
291.0964966	0.57
294.8862915	0.80
295.9984741	0.15
297.2489624	0.11
298.3125916	0.60
299.5442810	0.21
300.9264221	0.81
302.1416626	0.25
302.8670654	0.17
309.3755188	0.14
310.2543335	0.17
311.1666260	1.76
312.1141052	0.64
313.1910400	0.27
315.2735901	0.19
320.1281128	0.40
321.3286438	0.12
322.2708740	0.48
325.9683228	0.49
327.0550232	0.40
328.7889404	4.95
329.4375610	0.29
330.1302490	2.35
331.3373108	0.19
332.2323303	0.54
337.0866089	0.56
339.3534241	0.33
341.1279297	1.49
342.1305542	2.12
343.2236328	0.07
344.3287964	0.16
345.3561401	0.32
346.3746338	0.15
347.3923950	0.40
348.1657715	0.37
349.9000244	0.29
352.1442261	0.21
353.1407471	0.81
356.1933899	0.33
361.4987183	0.09
363.0915527	1.01
364.0626221	1.09
365.2442627	0.37
366.2244873	0.33
367.2941284	1.05
368.1247559	1.18
368.9989624	0.44
372.0993652	0.19
373.2942505	0.14
374.1501465	0.67
375.1069336	0.23
376.1888428	0.41
379.0621643	2.92
380.0778809	0.62
380.9286499	1.25
382.0666199	0.57
383.1087341	2.25
384.2841187	0.89
389.1290283	2.01
390.2869873	0.51
391.4272461	1.73
392.3416748	0.81
393.3014526	1.05
395.0677490	0.38
397.2481079	4.51
398.2521973	5.26
405.3981323	0.26
406.1043701	1.02
407.1813965	10.70
408.1967163	6.57
409.1070557	0.84
410.1755371	1.56
412.1287842	0.32
417.2308350	8.87
418.2145386	9.91
419.2911987	2.51
420.2723389	1.40
421.3064575	0.18
423.0303955	0.32
424.2560425	0.24
425.1300049	3.59
426.0880127	2.48
432.9475098	0.72
434.1382446	2.53
435.1172485	12.98
436.2543945	14.00
437.1865234	1.89
447.1587524	1.29
448.0358276	0.19
450.0552979	1.12
459.2825317	0.30
460.3361816	2.02
464.1390381	0.06
475.3200684	0.24
476.1898193	0.60
477.1828003	3.77
478.1634521	1.31
481.3523560	0.20
482.2840576	0.61
483.3526001	0.35
487.1491699	0.24
495.2918701	11.54
496.4030151	3.71
499.6105957	1.99
500.2463989	0.53
502.2207642	0.69
503.9033203	2.57
517.2161865	0.79
518.1212769	0.27
519.2680054	5.40
520.3278198	4.29
525.0875244	1.49
526.2269897	4.76
527.3685303	1.22
528.3175049	1.56
538.3177490	0.27
539.0599976	0.10
541.9530029	0.08
543.1303711	52.72
544.2385864	88.04
545.1072998	1.24
546.2741089	3.44
553.1509399	2.49
554.0910645	5.73
555.0787354	2.04
556.2120361	4.59
558.9398804	1.56
560.2115479	3.85
561.1542969	42.80
562.2113647	70.76
569.0922241	0.12
571.2225952	5.38
572.2725220	10.22
582.1896362	0.14
583.2969360	0.37
586.2805176	0.13
596.9700317	1.08
598.2152710	0.27
599.8442993	0.34
601.2150269	0.48
602.3164673	0.55
622.2886963	0.20
635.0810547	0.36
638.0068359	0.49
644.3349609	0.83
646.4137573	0.06
653.3102417	0.56
654.2683105	0.71
661.1203613	0.18
662.3136597	1.65
663.3920288	1.57
664.4259644	0.63
672.2937012	1.70
679.0653687	3.67
680.0401611	15.65
681.1114502	1.93
682.1447144	7.38
682.9317627	0.50
689.9786377	4.35
690.6635132	0.35
695.4434204	0.47
697.2451172	1.22
698.1129761	4.42
707.0742188	18.21
708.1539307	100.00
708.7746582	0.86
714.4981689	0.13
718.1083984	0.08
723.0136108	0.61
723.9307251	0.32
730.9598999	0.08
745.9776001	0.16
771.7284546	0.44
772.3977661	1.41
789.5738525	1.44
790.3984375	0.96
798.1717529	0.80
815.3406372	4.62
816.2216187	24.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1035.6382
Annotation	Unknow
Peak:m/z	Relative Intensity
441.4601440	0.46
500.4453735	40.65
504.2154541	0.19
518.3978271	100.00
532.4387207	7.44
596.5586548	0.08
621.3066406	10.57
639.1286621	0.10
673.6485596	0.15
700.6619873	0.16
701.6766357	0.37
775.4925537	0.80
797.9645996	0.74
958.5638428	0.04
976.3991699	2.38
977.7490234	0.16
1002.9453120	0.05
1017.5876460	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.129
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
69.1249542	0.06
71.2736969	0.06
78.9738541	0.22
81.1006775	0.68
85.0819778	0.15
86.9624481	0.25
94.9067688	0.04
97.0236969	0.42
109.1472626	0.48
118.9357147	0.06
121.0363464	0.22
123.1394653	0.08
129.1141052	0.07
132.9248047	0.03
135.0156403	0.94
145.1505280	0.11
147.0327606	8.14
151.1638336	1.14
153.0501251	10.02
161.4377899	0.08
163.0876160	1.54
165.0654144	78.83
171.1766815	0.06
173.1094208	0.16
179.1805573	1.40
181.1971588	2.43
183.0675659	1.51
191.1546783	12.85
197.1033020	12.24
207.6584167	0.02
209.0954742	100.00
209.7147522	0.29
227.4880524	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2026
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
239.9667053	0.21
243.0989227	0.42
245.0146790	2.09
246.0421753	0.27
247.2622986	0.21
253.2220764	0.24
254.3247375	0.14
256.1287537	0.06
256.8844604	0.13
257.5979614	0.09
258.3214111	0.12
269.0325317	0.30
270.3196716	0.95
271.0599060	1.40
271.9564514	0.81
272.9754639	0.55
274.0546875	0.85
281.1819763	1.48
282.2225037	0.29
283.0917664	0.32
284.4193420	1.06
285.2553101	1.33
287.0925293	19.65
288.1889038	8.45
289.2480469	8.39
290.1396484	4.61
297.0445862	0.33
299.1708374	2.48
300.2033691	1.88
301.4284058	0.20
307.1657410	0.17
310.9515991	1.04
323.2018127	0.54
326.1357422	0.26
327.1870117	0.62
330.3698120	0.10
331.2847290	0.27
332.1799927	0.46
336.0743408	0.27
337.0282593	0.21
339.0215454	0.35
340.1854858	1.07
341.2156067	1.59
342.2437744	0.16
345.3792419	0.06
351.1993408	0.22
352.0617981	0.26
353.4206238	0.24
354.2146912	0.26
355.3117676	0.23
356.0874023	0.36
357.2435913	0.17
363.1996460	0.34
364.1869507	1.01
364.8226318	0.13
367.5197144	0.09
368.2760010	0.34
369.0189819	0.15
377.0447998	0.30
379.2946777	1.40
380.1878662	0.95
381.2800293	0.87
382.6917114	0.90
383.3577271	1.59
384.2579956	1.09
388.2001953	0.95
389.1940918	0.45
391.0406494	2.32
392.0917358	1.82
392.9823608	0.37
394.4258423	0.10
397.1218872	5.40
398.1956177	6.44
401.1173706	0.24
402.2557373	0.30
404.2934570	0.13
405.0802612	1.31
406.0319214	1.46
407.1687012	26.41
408.1383667	28.53
409.3320312	1.53
410.1779175	1.77
411.9716797	0.23
416.3558960	0.47
419.1852417	1.58
420.2722778	1.07
421.2443237	1.49
422.0775757	0.84
423.2038574	2.37
424.1054077	1.66
425.1137695	25.99
426.1396484	29.95
432.2021484	0.32
433.1192017	6.31
434.1311035	5.79
436.4036865	0.23
438.2537842	0.31
446.1631470	0.19
447.2474976	0.93
448.4688110	1.00
449.4494019	1.31
451.0182495	11.66
452.1996460	12.23
453.2472534	0.21
454.4006348	0.07
457.1745605	0.52
465.3754272	0.41
467.0882568	1.53
468.0800171	1.97
469.2728271	0.35
470.1842041	0.33
473.1099854	0.33
491.2167969	0.41
493.0667725	0.83
494.2982788	0.92
497.5947876	0.08
499.1414795	1.66
501.0234375	0.23
515.2675171	0.76
516.1110840	0.84
517.2133789	2.22
518.2332764	1.89
519.0416260	0.66
520.2224121	1.03
523.9304199	0.08
524.6982422	0.23
526.4003296	0.79
527.2212524	1.22
528.2371216	3.06
530.3258057	0.30
532.6546021	0.62
534.1394653	1.53
535.2859497	1.05
536.2729492	1.35
541.1300659	1.88
542.1156616	3.63
543.2201538	1.06
544.1357422	3.25
545.0763550	0.23
546.0770874	0.38
553.0357666	2.58
554.2738037	6.24
557.2095947	0.22
558.0825806	0.28
559.1405029	30.45
560.1204834	49.48
561.4513550	0.08
562.3072510	1.05
565.4009399	0.41
571.0411987	7.22
572.0956421	19.04
577.1390991	56.26
578.0835571	100.00
578.7543335	0.13
583.4846802	0.21
586.2075806	0.23
596.2352905	0.11
600.4444580	0.23
601.3655396	0.72
602.2181396	1.54
612.2457886	0.19
613.2725220	1.04
614.2221680	0.48
615.8687134	0.16
616.6552124	0.26
619.3872681	1.02
620.1289062	0.30
630.4807739	0.09
634.8048706	0.15
636.2879639	0.53
638.3504028	0.23
651.1099243	0.10
652.0899048	0.53
653.2236938	1.02
654.1773071	0.99
656.0361328	0.10
661.1193848	0.87
662.2862549	0.69
669.0243530	0.11
670.3744507	1.17
677.4329224	0.23
678.1998901	0.75
679.3152466	3.50
680.1317749	7.43
688.2207031	0.19
693.1575317	0.34
695.1783447	5.96
696.1714478	11.91
697.3754883	8.29
698.1903076	30.21
698.8436279	0.18
705.2302856	0.49
706.3560791	2.73
713.1563110	0.22
714.0100098	2.15
714.6328735	0.46
720.2155151	0.32
720.9447632	0.49
722.4960327	1.70
723.3036499	10.47
724.2066040	41.81
726.0674438	0.12
728.2163696	0.31
738.0839233	0.17
739.0473022	0.52
739.7721558	1.91
740.4788818	1.05
744.3591309	0.27
769.9739380	0.33
788.2138062	0.36
804.9489136	0.06
806.0291138	1.86
814.0587769	0.72
832.0622559	14.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.1653
Annotation	Unknow
Peak:m/z	Relative Intensity
108.9832840	0.21
111.9642944	3.22
113.0012207	0.19
113.9223251	0.83
114.9579010	1.84
115.9691925	2.99
116.9090118	1.42
122.8911591	0.11
127.0344238	0.45
127.9883728	0.14
130.0973816	2.06
131.2742920	0.10
137.1193848	0.10
138.9831543	6.84
139.9881439	0.49
141.0335388	0.30
144.9583740	10.04
153.1286011	0.08
157.0028381	12.98
158.0097351	58.05
158.9608459	0.51
161.1256714	0.06
165.1188965	0.08
171.2023010	0.06
175.0957031	86.79
176.9294128	100.00
177.9335327	0.59
183.1205292	0.37
198.8333130	0.28
201.0565033	13.06
210.0681763	0.38
219.1695251	0.13
236.1539917	1.70
243.3070679	0.10
245.8454895	0.10
247.1864624	0.47
248.0669250	0.75
260.9273682	0.05
263.0014038	0.07
265.1440735	0.10
271.2226868	0.07
272.1486206	0.72
273.1336060	2.41
281.9005432	0.26
287.1589050	0.50
288.1355591	0.87
289.2454224	0.41
290.1853027	2.81
291.1538696	15.97
292.2374573	3.58
305.2222900	1.13
306.2994385	0.32
307.2213745	1.64
309.1575928	0.25
315.2529907	0.99
316.1627808	2.04
317.2082825	1.52
319.4297485	0.17
323.1396790	0.13
333.1637573	75.62
334.1549683	79.89
335.1569214	1.60
340.5599365	1.22
342.2646790	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.0561
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
82.7573700	0.02
92.9277954	0.02
107.1812134	0.01
108.9478455	0.06
116.9939575	0.01
123.9646378	0.06
125.0391998	0.90
149.1250000	0.03
151.0148468	0.32
151.9918823	0.19
156.9245911	0.01
159.1762085	0.02
164.9247894	0.06
179.1084137	0.06
179.9807434	1.26
181.0754395	0.11
193.2171631	0.04
199.1229248	0.89
201.1101379	4.09
202.2214661	0.02
203.2478638	0.08
215.1300354	0.08
219.4869995	0.02
225.1394348	0.03
243.0883789	13.86
244.0128784	0.05
245.0492554	0.05
259.0692749	100.00
260.1038208	0.15
269.0582275	6.13
270.2210388	0.03
287.8946533	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1384
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8995056	0.80
221.2490234	0.19
259.1221924	13.69
280.0625610	0.37
280.8351440	0.25
323.1380615	0.32
341.1091309	2.95
421.3084106	0.92
439.1561279	49.33
452.5541992	0.13
503.2936401	100.00
583.1290894	23.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.2122
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
237.2228699	0.25
239.0066376	0.08
241.9264984	0.16
243.1590576	0.95
245.0180664	7.44
247.1138000	2.29
253.1584015	0.25
255.0788879	1.98
257.2748718	0.50
259.0239258	0.99
261.0491638	0.34
263.2137146	0.09
265.0569458	0.20
267.1502686	0.21
269.1582031	0.11
271.0055542	1.70
273.1260071	3.83
274.0953979	1.22
275.0641174	11.95
283.0796204	1.96
285.0670776	1.39
287.1735229	6.60
289.0424194	3.66
291.1951294	3.65
293.1126404	0.27
295.0766602	1.41
297.1691895	0.51
299.0478821	0.83
301.1132812	5.02
303.1440735	0.76
303.8330383	0.08
309.0476990	0.05
311.2109985	0.70
313.1282654	0.60
315.1004944	0.56
317.1102295	0.22
319.4105835	0.18
328.8961792	2.45
331.1996460	0.65
333.1466675	0.39
341.1945801	0.51
343.2142639	0.27
347.1752014	0.89
348.1171875	0.08
351.3231201	1.08
363.1351929	0.98
365.2048340	1.40
370.2874146	0.05
372.3855591	0.25
373.2428589	0.23
375.1022949	1.28
376.3504028	0.30
379.1051025	1.94
381.1251831	30.19
383.2120361	1.41
387.2236023	0.32
389.0773315	1.83
391.0192261	0.56
393.1126709	18.26
395.1194458	1.69
399.1287231	0.96
399.9073486	0.35
401.1143799	0.06
402.9645996	0.37
405.1138916	0.93
407.1040649	28.65
407.7576294	0.06
409.1087646	8.11
411.0944214	3.46
415.2955322	0.23
417.2294922	3.59
417.9385376	0.15
419.2009277	5.18
421.2078857	1.95
423.1258545	0.96
425.0992432	19.06
427.1209717	8.99
431.3078003	0.97
432.9759521	0.31
433.8144531	0.23
435.0532227	12.49
435.6848145	0.24
437.1992798	18.60
439.2292480	2.51
445.2665405	0.15
447.1052246	0.12
449.1185303	3.07
451.2282104	0.77
453.0785522	2.54
455.1254272	0.21
458.9884033	0.04
466.9716187	0.14
469.3280640	0.22
474.8412476	0.05
483.0913086	0.39
485.4630737	0.24
496.9776611	0.07
501.1594238	7.48
513.2081909	0.34
515.2130127	0.70
519.1607666	10.82
523.3038330	0.05
525.2590942	7.34
526.4446411	2.07
527.2431030	0.57
529.0701294	0.52
531.0546265	0.58
537.1811523	1.35
541.4760132	0.14
543.0700073	31.17
543.8439941	0.03
544.9669189	1.54
547.0844727	0.09
555.1735229	7.79
557.1574097	0.41
560.9631348	100.00
561.6702271	0.19
563.1091919	4.57
567.2250977	0.20
571.2163696	0.70
573.0631714	8.81
575.2795410	0.04
577.2235718	0.38
579.0277710	42.00
579.7534790	0.04
587.5668335	0.09
589.0758667	1.04
590.9871216	3.43
591.6954956	0.12
597.1780396	0.12
605.0419922	0.34
607.1823730	0.23
615.2188110	0.10
620.8717651	1.65
631.4436646	0.06
646.8754272	0.05
653.5916138	0.22
663.1362305	1.51
665.3272095	0.21
670.0276489	0.08
671.4928589	0.15
679.1287231	0.57
681.0879517	14.25
683.0989380	9.75
687.2191162	4.22
688.2229004	14.15
689.2243042	10.20
690.9143066	0.47
693.0354614	0.06
694.0592651	0.06
697.2371216	8.60
699.0701294	10.91
699.6923218	0.37
703.3344116	0.18
707.2677612	1.36
712.2815552	0.22
715.1110840	16.33
724.9646606	7.45
725.6998291	0.17
727.1260986	0.09
730.3547974	0.13
797.0053101	0.21
813.7977905	0.18
814.5308838	0.16
815.1689453	0.31
832.1581421	0.82
833.0464478	6.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.2136
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0174866	0.05
163.0809479	0.16
177.2700195	0.02
179.0252228	0.16
181.1125183	0.21
197.1660614	1.59
211.0687561	0.08
223.0709381	0.41
241.1360779	12.79
253.1404877	0.15
259.3094482	0.07
264.9185486	0.08
275.2032776	0.08
281.3604736	0.02
283.1968994	2.52
287.3103638	0.02
295.1807861	0.09
301.1879883	0.10
313.1307373	3.92
323.1187744	0.15
324.9830322	0.07
338.1357422	0.06
341.1867065	0.86
343.2194214	26.45
344.1873779	0.09
357.5629272	0.04
373.0237427	0.07
385.1745605	0.59
389.2266846	0.09
403.2084351	100.00
415.5224609	0.02
419.3526001	0.04
421.1873779	0.09
445.4569092	0.06
452.3079834	0.08
459.2896729	0.02
466.9973755	0.02
478.9524536	0.10
483.0594482	0.28
487.2745972	0.30
493.3107910	0.07
500.7836914	0.11
503.1912231	0.08
504.1565552	0.05
505.2835083	0.04
507.3033447	0.09
517.2128296	0.04
519.1957397	0.78
521.2767334	0.22
523.4033813	0.08
529.3748169	0.26
546.3370361	0.19
547.3747559	0.85
556.4854736	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1065
Annotation	Unknow
Peak:m/z	Relative Intensity
145.4902344	0.03
147.1687775	0.02
243.0582275	0.05
245.4031677	0.02
247.8963318	0.04
262.2070007	0.03
271.0947266	0.06
273.2157898	0.01
287.0758667	100.00
305.2053223	0.04
320.4236145	0.01
341.2357788	0.02
356.0095520	0.01
402.8898621	0.01
413.4295349	0.01
420.9842224	0.04
430.9566345	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1121.2712
Annotation	Unknow
Peak:m/z	Relative Intensity
321.0267029	0.25
323.0386353	0.38
325.6311340	0.10
328.9364014	0.99
339.3242493	0.44
341.2581787	0.26
345.2947083	0.18
355.0715027	1.53
363.3026123	0.72
371.1778870	0.31
375.2206726	0.69
379.1796570	1.74
381.3615112	1.11
383.2255859	2.44
389.2251892	0.77
391.2915649	1.34
394.9067078	0.65
396.1305542	0.31
397.2454224	3.94
401.1352844	0.41
405.2498169	1.56
407.1876526	43.48
409.1958313	0.70
411.3743896	0.18
413.0964355	0.51
417.2527161	1.39
419.3122559	0.70
420.1126709	0.19
421.1847534	0.38
423.2225342	0.55
424.5557861	0.40
425.1944885	17.97
429.1136475	0.09
431.2054443	0.12
433.2119141	3.62
435.1159668	2.19
436.2169189	0.87
439.2230225	0.22
446.4166260	0.15
447.2924805	0.81
449.0685120	1.59
449.9605713	0.16
451.0939636	7.36
453.0284424	0.84
459.3464355	0.12
467.0126648	1.70
469.4279785	0.14
473.1304626	0.09
474.3860474	0.22
475.3428955	0.32
477.2476196	0.58
481.3612976	1.38
491.0558167	0.80
493.1303101	0.19
498.5051880	0.10
501.3968506	0.46
507.4867554	0.09
511.0584412	0.38
513.2855835	0.75
515.0861816	1.11
517.1099854	1.23
519.1861572	0.68
525.2130737	1.11
527.1490479	0.31
529.7005005	0.09
534.8413696	1.93
539.1826782	0.34
541.2196655	2.33
543.1983032	25.85
553.1959839	2.86
557.0461426	0.29
559.1173096	20.19
561.1350098	8.00
569.1165771	0.38
571.2531738	6.49
577.1748047	100.00
582.9310303	0.28
585.3941040	0.15
587.3453369	0.25
596.8524170	0.22
600.0805664	0.47
601.4060059	0.83
609.0262451	0.29
611.1386108	0.13
612.6430664	0.30
613.2755737	0.90
618.9168091	0.09
625.2349243	0.20
627.2681885	0.32
629.3099365	0.58
633.2426758	0.47
635.1657715	0.26
637.2816162	0.39
639.1970215	0.61
641.3781738	0.96
645.3103027	0.69
651.1970215	1.01
655.1964111	0.13
659.4235229	0.66
661.0825806	1.82
663.0090332	0.28
669.1258545	6.81
677.2893066	1.88
679.1789551	2.87
679.9919434	0.42
681.4766235	0.47
684.9583130	0.84
685.5916748	0.91
688.9614868	0.20
690.9187012	0.20
695.0720215	3.99
697.0238037	3.38
705.2189331	7.09
707.2315063	1.96
709.0439453	0.24
711.9566040	0.13
713.0786743	1.25
721.1650391	0.71
723.1336670	15.44
739.1486816	0.30
745.5247192	0.16
749.2869873	0.10
763.0546265	0.78
765.2166138	0.52
772.9063110	0.75
789.1710815	4.28
791.0850830	2.33
799.1647949	0.51
805.1259155	0.81
806.9605103	0.64
813.1397705	2.30
814.7952881	0.83
815.5764160	0.67
817.1596680	0.19
825.1994629	0.28
829.5328369	0.41
831.0744629	48.06
831.8355713	0.05
833.2430420	5.89
840.8326416	0.14
843.0426025	4.54
846.7050781	0.17
849.0570068	57.01
849.7730713	0.23
857.4891357	0.26
858.4930420	0.24
871.2416992	0.26
883.1005859	0.16
885.1456299	0.27
888.1726074	0.35
891.2199707	1.36
907.0939941	0.81
923.0683594	0.91
924.8438721	0.10
932.8967285	0.58
941.2060547	0.99
949.4783936	0.70
951.2136230	8.51
952.9207764	0.51
966.9733887	7.53
967.6804199	0.19
968.9288330	11.97
977.2656250	1.74
984.8951416	0.39
985.5860596	0.39
995.2137451	15.70
1011.3880620	0.23
1013.1900630	0.23
1049.3881840	0.64
1077.3159180	1.17
1085.2407230	0.41
1103.0627440	20.01
1103.7885740	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0772
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.9080963	4.29
95.7563324	0.07
137.0116882	100.00
161.0938721	4.31
179.0200806	1.10
183.9710693	0.25
191.0573425	1.38
200.0525208	0.15
202.9938965	0.36
206.7225342	0.12
209.1141052	0.08
221.0944519	0.43
227.1321106	0.13
235.0891113	0.11
238.9731445	0.40
251.1607056	0.24
253.1596680	0.96
263.3758240	0.15
267.2786560	0.10
281.2007751	0.85
284.1401367	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.508
Annotation	PE(P-16:0/20:4(5Z,8Z,11Z,13E)(15OH[S]))
Peak:m/z	Relative Intensity
229.3661804	0.02
240.8548889	0.09
253.4249725	0.05
255.2583313	0.09
256.1726379	0.02
261.3865356	0.39
269.3111877	0.08
277.2970886	1.09
279.2045898	100.00
280.2304688	0.26
281.4658813	0.99
293.4251709	0.16
295.3169250	0.15
297.1824646	0.08
307.5740356	0.07
310.2813721	0.15
311.2281189	0.05
319.0560303	0.03
354.2695312	0.03
359.2330322	0.02
380.5761108	0.06
391.2279053	0.06
392.2058716	0.16
398.0146484	0.10
402.3351440	0.27
404.4738159	0.03
409.3037109	0.07
410.1029663	0.03
426.1729736	0.18
434.2809448	0.02
458.3859253	1.83
474.4310913	0.10
476.3657837	10.94
480.4767456	0.08
504.1253662	0.03
506.1911621	0.07
509.4598999	0.03
510.3085327	0.03
518.4691772	0.05
524.2061768	0.02
527.0697632	0.12
535.3026733	0.09
553.4035645	0.31
555.3798218	0.10
581.2455444	0.07
582.1318970	0.08
585.7112427	0.03
607.5338745	0.13
631.4125366	0.07
662.7716064	0.11
674.5477295	0.29
677.0598145	0.10
678.3671875	0.48
679.4202881	0.15
684.8097534	0.03
686.4332275	0.05
692.2858276	0.07
694.6536255	0.07
695.6137695	0.06
697.4756470	0.03
702.5438232	0.12
705.0836792	0.09
719.5054321	0.24
720.3444824	1.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	897.4851
Annotation	Pitheduloside D
Peak:m/z	Relative Intensity
279.3247375	0.20
293.4978638	0.17
295.3466187	0.36
299.2202148	0.32
319.1026611	0.12
325.0472717	0.17
329.1414185	0.22
333.5375061	0.50
337.2387085	0.28
343.3473206	0.08
359.0924072	0.62
363.3483276	0.56
365.3334351	0.61
379.5790405	1.10
385.4950562	0.50
387.6075439	0.08
389.4111938	0.22
391.1876831	0.36
397.8912964	0.21
406.5203857	0.07
407.4268188	0.59
409.3012695	0.38
419.5006104	0.15
423.4597778	1.49
425.3977051	0.19
435.2243042	0.07
437.5760498	0.81
439.2731323	1.33
441.9692993	0.07
455.4760742	1.17
457.4600830	3.45
461.3122559	0.10
463.4735107	0.72
467.4063110	0.07
469.4085693	0.24
483.7453003	1.58
493.4698486	0.08
511.2629395	0.80
519.5978394	0.21
522.9771729	0.10
525.5984497	0.64
527.3165894	0.58
535.4979858	0.06
537.3594360	0.49
539.3231812	0.13
541.4887085	6.52
543.7677002	0.26
551.1553345	0.08
552.4965210	0.07
553.4838257	0.36
555.4083862	2.19
557.4708862	1.23
559.5587769	10.38
561.5596924	0.38
563.4450073	0.08
564.3342896	0.18
565.4479370	0.11
569.4047241	0.71
571.4301147	4.87
572.4200439	0.10
579.2434692	0.14
581.1695557	0.13
587.7827759	0.43
589.0818481	0.18
589.7866821	0.43
597.4304810	0.29
599.1634521	0.50
601.5408325	0.19
613.4519653	0.89
615.4996338	8.99
617.3805542	0.11
627.5203857	5.11
629.5117798	1.48
641.4015503	6.20
655.2846069	0.37
663.2247925	0.10
671.3872681	0.08
673.4981079	12.59
674.5310669	0.21
691.4342651	3.07
699.3076782	0.29
705.5062256	0.24
717.3869629	70.02
718.4726562	1.21
719.2846069	0.18
725.4688110	0.36
726.3550415	0.63
727.7557983	0.39
735.3728027	1.03
736.6619263	0.20
738.5202637	0.21
753.5549927	0.43
754.2359009	0.36
755.5241089	0.42
764.3683472	0.18
765.5244141	0.09
767.6075439	0.69
768.5621948	0.08
769.2958374	0.84
773.4438477	0.20
775.4039917	0.11
777.5097656	0.32
779.4171753	0.57
791.4999390	0.39
792.1923218	0.87
793.5781250	0.76
795.5775757	15.25
796.5269775	0.12
819.2556152	0.14
821.4537964	100.00
822.5480347	2.73
825.5026855	0.24
833.3105469	0.26
835.4656372	28.85
836.4157104	0.71
839.4921875	0.18
850.5230713	0.06
851.6233521	0.12
853.5084839	4.93
860.1845093	0.16
861.2784424	0.08
864.9998169	0.15
878.1353149	0.59
879.3933716	4.63
880.0534058	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.198
Annotation	Kanamycin A 3'-phosphate
Peak:m/z	Relative Intensity
157.1434631	0.04
160.0576935	0.06
163.1146393	1.31
165.1500397	0.15
172.9798279	0.09
175.0299683	1.07
179.2309875	0.09
185.2964172	0.08
189.0684357	0.29
191.2747345	0.06
192.9121246	0.05
200.9683685	0.14
207.1957397	0.36
208.8943176	0.17
210.6255035	0.13
214.8408356	0.24
218.0017090	0.07
225.1715698	0.34
231.3985443	0.13
257.2281494	0.17
259.3988647	0.03
261.0632324	0.09
268.2290955	0.07
269.2452393	0.04
273.2587891	0.05
275.1716919	0.03
280.9385986	0.12
303.1368103	0.21
320.2151489	2.23
321.2337646	0.97
323.2203369	0.07
335.3583374	0.22
337.2361450	0.40
340.8208618	0.05
355.0885010	0.05
369.3100586	1.55
387.2127075	100.00
388.2999878	1.25
401.2495117	0.19
409.5577393	0.07
419.2727661	2.52
427.4866333	0.06
429.2576294	0.12
433.2924194	0.04
437.2916870	0.13
444.8380737	0.13
445.6416016	0.21
456.4301758	0.15
457.2792358	0.47
461.0710449	0.47
465.4766846	0.05
483.3010254	0.19
491.1390991	0.10
501.3536987	4.00
502.0747681	0.11
503.2291870	0.79
504.4111938	0.13
514.8024292	0.03
519.2916870	0.52
525.2824097	0.43
527.1109009	0.62
527.7644043	0.02
545.2253418	12.91
546.3302002	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.3046
Annotation	Khekadaengoside L
Peak:m/z	Relative Intensity
205.1092529	0.01
302.2007141	0.02
327.0724487	0.02
487.5634766	0.02
519.4971924	0.01
527.1213989	0.03
549.4410400	0.02
619.4208374	0.41
640.3413696	100.00
641.5474243	0.39
642.2266846	0.20
643.5853882	0.03
644.4133301	0.03
645.2099609	0.11
646.3030396	0.01
653.8302612	0.06
689.0247192	0.02
778.5519409	0.05
849.6116333	0.02
939.5554810	0.04
957.3007202	0.06
1101.6715090	0.07
1119.3697510	1.37
1120.4344480	0.12
1281.5588380	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.2897
Annotation	Unknow
Peak:m/z	Relative Intensity
180.9671173	0.27
183.0289307	0.43
184.0359192	0.52
186.8512421	0.24
190.8322754	0.77
195.0707245	1.15
199.2928467	0.84
206.8302155	0.19
210.6394501	0.20
211.2716522	0.15
212.8428650	1.48
215.3169098	0.40
219.2439575	0.26
221.4738922	0.29
223.1828308	0.06
225.2027740	0.19
227.1217346	0.09
229.2321014	0.48
230.8832245	1.25
239.2257385	2.46
241.4720764	0.25
243.3143005	0.07
245.2198181	0.24
246.8101196	0.60
248.8372192	0.81
251.3099060	0.61
253.1134338	0.38
255.0139771	0.09
257.1539307	6.60
259.2772217	0.75
261.3071899	0.18
263.2911377	0.83
265.1424866	0.39
267.1909180	6.89
269.2140198	1.81
273.0703735	0.20
275.2960815	2.79
283.1964722	0.07
285.1142883	8.45
287.2670898	0.07
292.0971375	0.09
293.5001221	0.41
295.1367798	1.30
297.3330994	0.40
303.2139282	5.44
305.3944092	0.38
311.1171265	0.17
313.1687622	14.71
315.1328125	11.15
315.7401733	0.20
319.1933289	0.10
321.2895508	5.85
323.2393799	0.18
324.0626831	0.14
329.2803955	0.30
331.0763550	33.63
331.6807251	0.17
333.2177124	3.00
337.1896362	0.08
341.1929932	0.19
349.1790771	36.64
351.3518677	0.60
367.1956787	100.00
372.9338989	0.17
383.9420166	0.09
384.8474121	0.21
389.4841309	0.31
394.3455200	0.15
395.2958984	0.31
397.1031494	0.18
406.1651611	0.13
407.1832886	0.06
411.1740723	0.29
413.1454468	0.53
414.8341675	0.20
416.4160156	0.11
419.2651367	0.33
424.1917725	0.57
429.4780273	0.09
433.8890381	0.09
438.9325562	1.81
443.0375977	0.18
445.4561157	0.83
450.4852905	0.15
453.1358643	0.18
456.2286987	0.35
456.8303223	0.21
475.1252441	0.53
479.1473999	0.23
480.1776123	1.76
484.5046387	0.52
485.2332153	0.42
486.0906372	0.11
489.3243408	0.10
494.2899780	0.16
497.3272705	0.35
502.9924927	0.27
505.1924438	1.41
508.3629150	0.45
515.1649780	1.08
521.1105347	0.24
522.3837280	0.20
523.1004028	0.06
524.8844604	0.57
533.0814209	1.64
541.1516113	0.86
543.0622559	7.56
550.7313843	1.35
551.5227661	0.05
556.2559204	0.38
560.5553589	7.40
561.1622314	25.61
568.7458496	0.37
573.2865601	0.20
576.9080200	0.13
578.9318848	57.54
579.6817017	0.27
580.7283936	0.26
586.1979370	0.59
593.9804077	0.37
596.3566284	6.78
597.0158691	37.31
597.7604370	0.27
600.5015259	0.24
604.4118042	0.33
614.1574097	4.89
614.9003906	51.13
616.0798950	0.90
640.4978638	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	590.2788
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1070251	0.87
176.4169617	0.06
191.0252533	0.16
193.1390076	3.48
211.2596283	0.37
232.0195312	0.13
236.1136932	0.12
248.3295898	0.50
251.0841370	0.07
254.1892853	2.21
254.8487854	0.23
259.8966675	0.52
260.5000000	0.76
264.3402100	0.07
278.3562622	1.08
283.9631348	0.13
291.8936768	0.25
294.0975037	0.72
305.3561401	0.12
306.2694702	4.34
322.1488647	0.11
324.1564941	24.75
324.7576294	0.13
338.4258423	0.21
342.2232056	100.00
348.2563477	0.14
352.4455566	0.23
353.4541626	0.07
355.7271729	0.15
373.9826660	0.11
380.1208496	0.05
382.0181885	0.28
384.5449829	0.10
396.2518921	0.37
414.2799683	0.26
419.3576050	0.06
428.2364502	0.15
432.2880859	0.20
437.7559204	0.28
439.2083740	0.17
443.4088135	0.16
450.2132568	0.29
451.2966309	0.13
454.1414185	0.25
456.1774292	0.08
458.5220337	0.29
474.6488647	0.06
481.2850342	0.11
492.0022583	0.48
497.8982544	0.13
500.3967896	0.24
510.2678833	0.14
528.1096802	1.85
532.5205688	0.14
546.2969360	0.08
553.9730225	0.35
556.2849731	0.07
563.3084717	0.06
572.3104858	11.71
573.1605835	0.42
581.9594116	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1767
Annotation	Flocoumafen
Peak:m/z	Relative Intensity
167.9522095	0.17
170.0802002	0.09
202.1413269	0.24
216.1570435	0.23
218.4462128	0.04
248.2490540	0.28
261.1811829	0.31
262.1619873	0.97
262.8056641	0.14
265.1885986	21.74
279.0531006	100.00
280.9421387	0.15
371.6478882	0.11
461.2411499	0.28
479.2128906	0.32
499.0531616	0.08
525.2466431	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	819.2228
Annotation	Guibourtinidol-(4alpha->10)-[7,8-dihydro-8-(2,4-dihydroxyphenyl)-6-(3,4-dihydroxyphenyl)-7-hydroxy-6H-pyrano[2,3-f]catechin
Peak:m/z	Relative Intensity
226.9694672	0.13
228.9627533	0.08
231.0885162	2.81
239.1281433	0.13
241.1407928	0.27
242.1071014	0.83
243.0395813	2.30
245.2067871	0.65
246.9279633	0.05
250.7128754	0.16
255.1527100	1.96
257.2052612	0.87
258.0892029	0.05
260.9442749	0.07
261.5775757	0.13
263.1273804	0.12
265.3154297	0.05
267.0667725	0.87
269.2681274	0.36
271.1767273	0.24
273.1077576	7.36
274.1459351	1.17
275.1196899	7.07
279.0762939	1.28
283.3899536	0.05
285.1143494	6.40
286.0060120	0.10
287.1536560	9.02
294.9529419	0.14
297.1444397	2.58
299.1026611	3.92
302.9535522	0.47
304.1972656	0.20
306.6535034	0.27
311.2416687	0.14
315.0914307	0.67
317.0938721	0.29
319.1324463	0.22
324.9218445	0.04
335.1582642	0.24
345.2296143	0.53
347.3643799	0.27
349.2416687	1.29
357.2443237	0.16
359.1196899	0.62
361.2456665	0.69
363.2093506	3.48
365.3981323	0.23
367.2114258	1.13
371.4148560	0.44
373.1988525	0.40
375.0596619	0.25
377.2364197	11.33
379.1095276	2.70
380.0347595	0.16
380.9410400	0.48
385.1224060	0.74
389.1063232	1.63
391.1776733	17.50
393.1850586	11.67
394.2514648	0.12
397.0129395	0.18
399.4384766	0.09
401.2202759	3.93
403.2254639	5.89
405.1414795	3.39
409.1201172	18.47
411.0386353	12.74
415.1050415	0.54
419.0878296	11.03
421.1495972	13.49
423.0811157	3.56
431.4061279	0.10
433.1638794	3.58
435.0543823	0.49
441.0680542	0.05
445.3746338	0.24
451.2453613	1.02
453.1736450	0.25
481.6825562	0.61
485.2489624	9.96
486.9434204	0.05
490.5604248	0.12
497.0736084	0.66
499.0714111	1.70
499.6821899	0.09
503.0874023	6.46
506.9458618	0.06
509.1301880	7.54
511.2082520	1.24
514.9938965	0.29
522.1669922	0.08
522.9843750	0.04
527.1579590	16.68
529.0817871	4.82
539.1396484	3.63
541.1162109	0.76
543.2295532	0.23
544.9704590	100.00
545.8472900	1.06
547.1234131	36.84
549.1179810	0.26
552.1174927	0.07
553.1405029	0.16
556.9928589	2.91
557.6139526	0.14
558.9896851	3.81
569.3160400	0.10
571.2211914	0.13
578.0518188	0.08
581.3346558	0.15
583.3286743	0.32
588.9722290	1.03
599.2981567	0.28
603.6068726	0.14
609.2022705	0.15
628.9385376	0.19
633.3038940	0.33
639.4727173	0.22
647.1364136	4.11
651.1833496	3.73
655.2529907	0.18
656.3795166	0.28
657.1098022	0.13
659.1611938	0.23
662.8544312	0.06
665.1469727	26.27
665.7677612	0.15
666.4011841	0.29
674.6983032	0.69
675.3535156	0.22
676.7642822	0.07
683.1232300	16.32
687.5729370	0.06
689.2001343	0.13
693.1201782	9.41
694.9349365	0.55
712.6478882	0.40
725.5654907	0.19
735.0496216	0.11
767.0555420	0.30
774.3820190	0.37
783.0390015	0.39
784.5396729	0.06
786.1437378	0.11
797.6093140	0.11
801.0394287	7.23
802.9855347	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	564.2114
Annotation	Unknow
Peak:m/z	Relative Intensity
162.7628326	3.34
170.9086761	0.73
201.1059570	0.39
204.9544373	0.18
219.1004791	0.76
236.8911133	2.41
254.9692993	100.00
258.8650513	0.26
276.7093201	0.39
295.1730347	0.27
309.8990479	0.15
312.8334961	0.34
324.5480347	3.31
325.1912842	0.48
381.5849609	0.09
384.2706909	0.10
402.0102539	0.58
416.2377930	6.55
416.9627686	30.25
546.4888306	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	241.1194
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
78.8421326	0.31
82.1498108	0.09
83.8709717	0.08
96.0119171	0.14
97.0879669	0.14
99.1130218	0.05
109.1583252	0.04
110.0157471	0.11
111.9932709	0.62
114.2770081	0.04
116.1183472	0.03
126.1639557	0.43
127.0339508	0.37
128.1706848	0.36
130.1484833	1.64
131.2340240	0.15
135.3923645	0.01
139.2151642	0.06
140.1744080	0.16
141.1498871	0.47
151.1686707	0.03
154.2864227	0.07
155.0879669	0.01
155.9738007	0.06
168.2411346	0.20
169.1585541	0.85
170.1505890	0.03
179.0986176	0.34
180.1488342	0.63
181.1893616	0.03
195.1971436	0.27
197.1391754	100.00
198.2397919	0.03
211.1503143	0.06
213.1150970	0.04
223.0981445	5.95
241.2890625	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.158
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
156.8010712	0.11
157.9770203	0.20
160.9217834	0.04
162.9668427	0.37
164.8386993	0.06
171.0203094	0.39
179.0998840	0.14
181.0368958	0.50
183.1407623	0.18
185.1061401	0.53
189.0261536	0.38
191.0431213	0.46
193.0056458	0.29
199.0412292	0.41
204.9456787	0.08
209.0091858	0.06
210.7633057	0.09
212.9183960	0.48
215.2652588	0.33
225.0654144	0.03
225.8036652	0.08
227.1756287	0.56
231.0280914	13.49
232.9508057	0.40
238.9524994	0.20
243.1363525	8.49
245.1069336	0.96
251.3197632	0.06
253.1011353	0.47
255.1468048	6.36
257.0765686	1.79
261.2106628	1.39
267.1236877	1.43
269.0927734	2.28
273.0535278	23.41
275.1292725	67.37
278.8778992	0.09
285.0582275	27.68
287.1772461	16.61
294.7702026	0.24
297.1868286	1.06
299.0808105	1.72
303.2697754	0.16
308.7625122	0.05
314.9892578	0.13
317.0585327	2.62
331.0347900	0.07
339.3463135	0.03
352.2860107	0.15
359.2265015	0.09
361.2612305	0.27
372.9879150	0.03
375.1607666	0.27
377.0598145	0.17
379.1326294	16.43
379.7557373	0.04
385.3039551	0.37
391.0965576	1.33
393.1190796	87.79
395.1652222	0.39
403.1455078	2.36
405.1878052	8.22
406.9862061	0.07
411.0383301	100.00
411.6753540	0.32
417.1386719	0.31
421.1121826	16.13
423.0435791	17.22
423.7192383	0.20
434.9984741	0.64
448.1802368	0.11
479.1836548	0.38
482.9797363	0.31
485.8047485	0.12
502.3205566	0.16
503.3859253	0.31
511.1302490	2.29
524.6549683	0.31
529.0385132	11.57
529.6781616	0.14
542.5404663	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	332.1252
Annotation	Tryptophyl-Glutamate
Peak:m/z	Relative Intensity
127.9356079	100.00
139.0795898	0.09
166.9120789	1.51
185.0996552	0.24
203.1235962	4.68
227.7991028	0.07
259.9010010	0.08
283.9441223	0.07
288.0545044	0.12
296.1344910	0.15
300.1553955	0.28
314.1259766	61.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.1321
Annotation	Dehydrodicatechin A
Peak:m/z	Relative Intensity
163.0767212	0.28
165.0678253	0.38
177.0036774	0.10
178.5994568	0.27
180.9768982	0.99
189.2603760	0.10
191.1254425	0.18
197.1379700	0.05
199.0797729	0.34
200.9768982	0.07
206.9913025	0.10
213.1965179	0.11
217.0625610	0.87
219.4199371	0.07
227.0915527	0.33
229.1894684	0.31
230.8856049	0.11
234.2896881	0.16
238.9324646	0.33
243.2642212	0.21
245.0955505	15.59
247.1156311	0.42
257.1051636	3.53
259.0780029	0.07
261.0568848	0.30
269.0751648	1.46
269.9679565	0.06
271.2075500	0.75
273.0057678	0.16
275.2084351	0.06
280.9849243	0.08
284.8355713	0.05
287.1442871	10.77
288.9359741	0.73
291.0685730	0.42
295.1445618	1.06
298.9941101	0.71
299.9932251	0.32
301.2726440	0.10
303.1473999	0.12
307.1558228	0.43
309.1707153	0.27
311.2331848	0.05
316.8249512	0.07
319.3186035	0.54
321.3024902	0.06
326.9948730	0.06
330.1985474	0.10
331.1812744	0.08
334.4154053	0.10
344.5342407	0.05
351.0876465	0.45
355.0034180	0.13
371.3930054	0.17
373.3488770	0.03
375.0894775	0.16
379.1188354	3.64
391.1608276	1.00
393.3297119	0.48
395.1667480	0.63
397.1579590	12.27
401.1301270	0.33
403.3180542	0.05
404.9116211	0.43
407.0650635	7.66
409.1311035	2.79
411.3024902	0.26
412.5497437	0.04
415.0019531	0.82
417.3950195	0.12
419.2291260	2.10
421.0146484	0.66
423.2232056	0.60
425.1195679	100.00
429.4815063	0.11
433.1967163	1.68
435.3397827	0.45
437.1324463	12.12
439.1378174	0.99
440.1826782	0.48
441.2257690	1.23
445.1242676	0.35
446.9921875	0.55
447.6119995	0.03
448.2391968	0.55
449.1570435	0.07
451.0432129	1.31
453.1915894	0.55
457.1870728	0.04
465.1611938	0.04
471.2177734	1.17
497.3115845	0.14
503.1828003	0.78
504.3302002	0.16
512.0092163	0.32
513.2581177	0.09
514.8469849	0.18
518.4874878	0.06
523.2528076	0.06
529.3287964	0.04
531.2805176	0.15
532.6246948	0.10
533.3277588	0.07
536.1583862	0.12
541.1506958	2.92
543.1842651	0.13
543.8616333	0.16
545.0904541	0.16
546.9642334	0.10
557.3447266	0.11
559.1438599	20.13
561.3178101	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1725
Annotation	Unknow
Peak:m/z	Relative Intensity
170.1531525	0.11
182.9770660	0.03
199.9463043	0.63
200.9841919	0.17
202.0619202	7.75
214.1101074	0.04
217.3640900	0.05
217.9915924	1.35
218.9585419	0.95
243.9544067	0.49
261.9896240	100.00
341.1812744	0.24
400.8336182	0.04
477.4826050	0.06
543.9817505	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	336.1212
Annotation	gamma-Glutamyl-S-methylcysteinyl-beta-alanine
Peak:m/z	Relative Intensity
125.9659729	0.17
130.0648499	0.16
132.3069153	0.05
144.0236969	1.40
148.1228638	0.01
154.9081421	0.02
160.1938782	0.02
160.9457397	0.03
162.2226868	0.01
163.3491211	0.04
168.1747437	0.02
189.9597321	33.27
195.2123566	0.07
200.8609009	0.03
205.2217865	0.05
207.0084686	100.00
217.8117065	0.02
219.0412598	0.01
229.1597900	0.17
247.0816956	2.32
262.3865356	0.03
265.2262268	0.10
270.7618408	0.01
272.1615601	0.08
273.0180969	0.02
273.6255188	0.02
282.9557190	0.03
300.0597839	0.21
318.1898804	4.38
319.0457458	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1064
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
130.1592407	0.08
159.9544373	0.04
173.3836975	0.03
192.7858276	0.01
205.9858704	0.02
244.2331543	0.01
246.0305786	0.02
254.8074036	0.02
271.135437	0.02
273.3258057	0.04
282.2776184	0.01
285.7578735	0.03
287.0491943	100.00
287.6783142	0.12
297.1541138	0.02
299.2312622	0.03
311.2717896	0.02
329.1612549	0.37
337.2119751	0.02
353.1381836	0.27
355.0276184	0.02
362.965332	0.01
370.1712952	0.03
372.3086853	0.05
377.3406372	0.05
378.7837219	0.03
381.3955688	0.03
383.1569214	0.17
384.9461975	0.01
385.6966248	0.02
387.2146912	0.01
395.1934509	0.14
403.4098816	0.01
413.1920471	0.17
431.1742859	1.29
432.2652893	0.02
449.0865173	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	673.31
Annotation	Argadin
Peak:m/z	Relative Intensity
201.1382751	0.09
224.2028046	0.04
231.2477570	0.02
235.1637878	0.01
240.9517822	0.14
270.8976440	0.09
271.5707397	0.06
273.2167969	0.05
277.0727539	0.08
283.1722107	0.06
286.8059387	0.05
289.3515930	0.02
302.7217712	0.09
309.3234863	0.09
317.6089478	0.04
319.2223511	0.23
322.1466675	0.05
326.7807617	0.08
335.2560425	100.00
337.0682373	2.59
338.3767090	0.04
343.2289429	0.28
349.5127563	0.04
361.2111816	0.79
364.7543945	0.01
367.3485718	0.07
369.1366577	0.05
379.2064819	0.09
393.9667358	0.07
397.1748047	0.08
408.7929077	0.06
409.4044800	0.07
427.4748535	0.02
430.1785278	0.02
431.2801514	0.02
433.2171631	0.04
445.0629272	0.02
445.6882935	0.02
451.1467285	0.06
457.2348022	0.02
458.8864746	0.04
475.4015503	0.04
479.1852417	0.11
481.0664062	0.03
493.4087524	0.02
495.2133179	0.12
497.5610352	0.18
503.3359375	0.13
504.9819336	0.14
509.1909180	0.02
511.3107910	0.11
521.9846802	0.02
525.3123169	0.02
529.2866821	0.03
543.0317993	0.01
545.1109009	0.05
547.2969360	0.03
553.3288574	0.06
558.0857544	0.03
591.1433105	0.10
592.4086304	0.04
595.4188232	0.07
597.4927979	0.06
608.1611938	0.05
611.4102783	0.46
627.4675293	0.03
629.2059937	0.12
637.4996948	0.13
641.3774414	0.08
655.2965088	0.73
658.8781128	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	697.2451
Annotation	Unknow
Peak:m/z	Relative Intensity
205.1749115	0.30
209.1631165	0.30
227.2033081	3.73
243.9681091	0.09
245.1510925	30.24
246.3081970	0.11
246.9746399	0.05
271.1755981	0.06
289.1242676	19.82
298.9864502	1.33
313.2807617	0.03
433.0728760	0.06
451.0888672	100.00
451.8416138	0.28
471.2028809	0.06
489.3186035	0.08
495.0217285	0.11
505.3438110	0.19
507.3122559	0.14
558.8469238	0.11
579.7290649	1.31
631.0357666	0.09
633.1498413	0.14
661.0023804	0.05
678.7946167	0.49
680.1532593	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	865.21
Annotation	Unknow
Peak:m/z	Relative Intensity
246.9647980	0.02
259.1903381	0.05
269.0488586	0.13
271.2963562	0.18
273.1208801	0.06
287.0859070	0.20
299.1952209	0.07
312.8557129	0.04
317.2487793	0.08
343.2249146	0.05
353.0686646	0.04
375.3214111	0.03
387.0416870	0.11
389.0953979	0.03
391.2233887	0.06
403.0417480	0.06
407.0321045	0.04
409.2023315	0.16
411.5948486	0.02
412.9139404	0.03
415.1646118	0.06
419.3545532	0.07
422.9969482	0.17
425.1055908	0.42
427.2294922	0.10
429.0363159	0.07
434.9348755	0.05
437.0007324	0.12
448.9542236	0.18
451.3311768	0.06
453.1278076	0.04
455.0837402	0.10
460.9728394	0.02
466.8754883	0.11
479.2261963	0.13
485.0703735	0.04
515.4061279	0.02
523.2194214	0.05
525.4085083	0.03
533.2463989	0.08
541.1112061	0.50
542.9803467	0.34
546.9752808	0.10
549.2119751	0.08
557.0618286	0.16
559.0870361	0.37
561.4561768	0.22
564.0050659	0.03
567.2472534	0.04
568.9899292	0.24
572.8283081	0.08
575.0715332	0.54
576.9303589	0.74
581.2066040	0.02
587.2633667	0.20
593.1077271	0.39
598.1717529	0.05
619.3540649	0.08
635.2620239	0.08
649.2655640	0.04
651.3386841	0.04
661.1685181	0.12
677.0743408	0.24
679.1699829	0.09
683.3624268	0.05
685.0614014	0.05
693.1893921	0.17
695.0422974	1.02
697.1170044	0.39
703.2047729	100.00
704.1763306	0.22
707.2515259	0.06
711.2487183	0.20
712.5538940	0.31
713.1659546	2.07
729.0935669	0.30
738.4894409	0.09
739.1541748	0.06
741.1856689	0.04
747.1738892	0.15
768.9254761	0.05
811.4742432	0.21
828.0722656	0.04
829.3418579	0.50
846.1929321	0.23
847.1580811	0.96
865.6242676	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.088
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0177307	1.03
142.7834167	0.12
147.0784607	2.78
173.0416412	2.02
174.2585449	0.13
190.9458923	100.00
191.9859161	0.34
209.0800171	14.39
211.0759888	0.07
223.1099548	0.74
253.0795898	0.23
307.1719971	0.07
311.4311523	0.42
341.2881165	0.23
343.1869507	0.17
353.1963196	0.20
354.8547974	0.05
371.3481140	0.05
372.3904114	0.10
379.1572571	0.69
387.3738708	0.24
397.1467896	6.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1243.6028
Annotation	Unknow
Peak:m/z	Relative Intensity
424.9150391	0.82
437.2946777	0.31
441.0876465	1.09
483.2079468	0.63
499.3680420	2.51
500.4339600	1.58
569.5104980	0.97
589.6606445	1.42
657.2185059	0.47
685.4670410	2.34
703.4696655	1.92
733.5632324	6.97
734.5439453	1.74
750.8635254	0.84
751.6256714	6.30
752.4046631	1.41
763.1479492	0.38
819.3626709	6.40
820.8048096	2.21
833.3500977	6.76
847.3251953	0.44
865.4348145	22.54
866.6756592	1.00
889.4921875	1.83
890.8334961	2.18
891.4801025	19.02
892.5263672	8.76
907.8828125	3.42
909.3537598	57.52
910.5443115	12.04
927.5717773	2.59
928.5410156	3.58
993.0548096	0.81
1009.2910160	4.00
1011.4893800	10.41
1027.3481450	44.86
1028.5720210	13.83
1045.5123290	2.98
1046.4625240	1.34
1063.9825440	1.40
1071.4970700	0.28
1072.4023440	1.76
1082.4995120	0.81
1089.4724120	22.39
1090.6069340	5.31
1091.6166990	1.06
1173.4326170	68.33
1174.4643550	17.13
1189.5246580	4.56
1190.2395020	2.24
1191.4711910	5.33
1192.4249270	2.82
1199.6521000	1.16
1215.5601810	1.03
1216.7956540	7.67
1217.4661870	100.00
1218.4958500	40.40
1233.4835210	2.56
1235.5139160	30.50
1236.5780030	3.37
1250.8486330	0.45
1251.4754640	2.54
1252.0822750	0.77
1252.7377930	2.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	759.2859
Annotation	Mono(glucosyluronic acid)bilirubin
Peak:m/z	Relative Intensity
217.0865479	0.23
217.9743042	0.04
219.3245087	0.08
223.0515289	0.08
231.0755310	0.05
235.0886688	1.33
235.9659119	0.07
237.0398254	0.03
238.9054871	0.03
245.1520844	0.13
247.0990295	0.30
248.2780762	0.07
249.2202606	0.08
250.2164917	0.07
251.1401978	0.55
265.1308289	0.65
267.0222473	0.13
269.2313232	0.06
277.0660095	0.15
281.0823364	2.05
282.7613831	0.35
287.2762146	0.43
289.0844116	0.03
293.5792542	0.10
294.6799927	0.11
295.3303833	0.13
297.6881409	0.05
301.4710999	0.02
321.2936096	0.13
323.0206299	0.09
327.2752686	0.11
335.5003052	0.09
337.2609253	0.19
339.1938477	0.94
341.1266479	5.07
343.5512085	0.09
351.4597778	0.07
353.2174377	0.43
355.1220703	1.21
356.8264771	0.17
357.6434937	0.04
366.4300537	0.05
367.9817505	0.09
369.1934814	1.61
371.0510864	0.68
379.0278320	0.11
381.2581787	0.27
383.1516724	0.17
385.3977661	0.19
387.2558594	40.66
389.0005493	0.80
399.4177246	0.07
407.1110840	0.13
413.4522095	0.18
423.3871460	0.03
428.4461060	0.03
429.1632080	0.35
431.2381592	0.42
438.3217773	0.17
440.9754028	0.07
449.1579590	0.85
459.3927612	0.25
471.3497314	0.27
473.5982666	0.11
476.9918823	0.08
482.6384888	0.16
485.3635864	0.31
489.2736816	2.21
491.2391968	0.07
503.3450317	3.11
515.3198853	0.09
529.2548828	1.21
531.2719116	3.50
541.4421997	0.10
543.0984497	0.90
545.3092041	2.24
546.2398071	0.07
549.4465942	0.14
555.1408081	0.03
561.2118530	1.16
563.2128296	100.00
564.1043091	0.13
577.2344360	7.54
577.8367920	0.01
583.3016968	0.05
585.3997192	0.63
586.0770874	0.03
587.3429565	0.06
597.3294678	0.16
599.2101440	0.11
603.0816650	0.03
604.5418091	0.14
605.3497925	0.63
606.9869995	0.05
617.3492432	19.47
621.9531860	0.03
631.4461060	0.10
632.2314453	0.15
637.2020874	1.28
654.5162964	0.06
661.2409058	0.09
663.0762329	0.06
667.2389526	0.84
679.4257812	0.65
683.5050049	0.20
685.1290283	0.65
690.2295532	0.06
691.3590698	0.24
695.3433228	0.13
697.4829102	0.13
698.2047729	0.13
699.5069580	0.27
704.4875488	0.06
709.4590454	1.56
711.1942749	14.66
713.2875366	0.19
714.7177124	0.50
715.5973511	0.37
720.7448120	0.08
723.2172852	2.70
727.2883301	0.64
736.3458862	0.17
737.0828247	0.36
738.3013306	0.31
741.1721802	21.84
742.3728027	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.148
Annotation	12-hydroxy-3Z,6Z-dodecadienoic acid
Peak:m/z	Relative Intensity
67.1727524	0.05
69.2787399	0.04
76.9638672	0.15
78.8458099	0.02
80.9295273	0.15
82.9760437	0.10
84.0168228	0.04
87.8516235	0.48
90.8734283	0.06
93.0116577	0.05
94.9912720	0.22
97.0101013	0.37
99.0956879	0.18
100.6740417	0.03
104.9342651	0.13
107.0024414	0.19
108.9809723	0.69
110.9212189	0.01
112.0011444	0.06
112.9664764	0.38
117.0819550	0.11
119.0714111	0.19
121.1287537	0.35
123.0573273	0.27
124.9645081	0.08
125.8057556	0.02
126.9532318	0.39
128.9633331	0.30
131.1385040	0.57
133.1671143	0.15
135.1360016	0.17
136.9603424	0.08
138.0532227	0.11
139.0179443	0.18
143.1459808	0.36
145.1279602	0.79
149.0319519	2.11
150.9454498	0.02
153.0819244	0.54
155.0559845	1.03
157.0836639	0.47
159.1311035	0.48
163.2764435	0.05
164.9685822	0.04
165.7407990	0.06
167.1546021	0.56
169.1217499	0.18
170.1118164	0.03
171.1058197	1.33
171.8390656	0.19
174.0757599	0.36
175.2222137	0.05
177.0295105	2.27
178.1020660	0.34
180.6229401	0.03
182.0831909	0.08
183.0449371	0.03
185.0753021	0.28
191.5930328	0.23
192.7333069	0.21
195.0099945	100.00
196.0234222	0.28
198.4350891	0.08
201.5271454	0.09
203.9812164	0.15
204.7112579	0.13
213.0776520	0.27
215.3105621	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.0861
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
103.9718018	0.06
121.0848541	0.04
131.8861389	0.03
140.9108429	0.08
148.0778198	0.16
151.1132660	0.03
165.8847198	0.20
172.0392761	0.04
196.1149750	0.02
206.0724030	86.35
206.8303986	0.05
210.0314789	0.07
216.8627472	0.02
225.1039124	0.05
233.9798431	100.00
251.8506927	0.15
253.2337799	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.3446
Annotation	Unknow
Peak:m/z	Relative Intensity
239.9989471	0.16
241.1728210	0.74
245.1312714	4.78
255.1165466	1.66
257.0097351	1.59
260.9881592	0.34
269.0796204	2.43
271.1537781	4.43
273.1981506	4.08
279.2581787	0.33
281.0682678	1.14
282.1305542	0.16
283.0848389	0.21
284.2953491	0.63
285.1277161	3.70
287.1580505	17.78
288.4112244	1.12
289.1557617	8.71
290.9046021	0.19
295.2188416	0.34
299.1568604	2.71
300.1712036	0.97
305.2563477	1.00
309.3753967	0.82
311.1300964	1.83
312.1286316	0.16
313.5540161	0.51
315.1614075	0.99
321.3954163	0.76
323.2407532	0.97
327.2654419	0.24
328.0971680	0.28
331.0767822	0.40
337.1129761	1.81
343.2774658	0.86
347.2694092	67.33
349.3533936	0.16
351.0452881	0.72
352.8744507	0.46
363.3234253	0.19
365.2149048	3.42
371.3897095	1.69
375.0286255	0.83
379.0925293	6.00
381.0402832	1.01
385.2306213	0.71
387.0200806	0.23
389.2286377	17.25
391.1472168	5.90
393.2461548	1.75
395.0812988	0.40
397.1844482	6.21
401.1986084	0.67
403.4276733	0.38
405.1465454	4.46
407.1796265	8.32
408.0836792	0.53
409.0927124	21.86
409.7045288	0.85
413.4825439	0.31
414.9817505	0.77
417.1832886	3.74
419.1437988	5.07
420.4993286	0.15
423.2412109	1.83
425.1298218	4.67
426.9774170	0.32
429.0715942	2.23
431.2206421	0.99
433.2312622	8.58
435.0507202	11.82
436.1330566	0.84
438.1502686	0.44
439.4380493	0.24
443.2589722	2.82
449.0797729	0.65
450.9672241	2.19
452.1424561	0.23
459.3402100	1.07
460.9757080	4.02
465.1598511	0.18
477.2524414	1.86
485.2143555	0.54
491.2374268	10.36
495.4652100	0.35
499.3151855	2.06
501.4212646	1.09
503.2203979	0.97
505.4509888	0.18
509.1301880	93.99
515.1069336	2.26
517.2136841	5.14
519.2637329	2.35
525.2252197	0.77
527.3272705	34.49
529.2608643	1.00
533.2522583	0.29
541.1289062	4.56
543.2170410	37.97
545.1433105	6.55
551.1725464	14.70
551.8442993	0.12
553.2171021	0.14
555.2412109	10.68
557.2943726	1.05
559.1962280	46.19
561.1082764	100.00
562.0283203	0.50
569.3262329	9.47
571.1388550	3.34
572.8858032	2.68
573.5798340	0.36
577.4598999	0.62
584.2617798	0.54
585.0988159	1.05
586.9851685	0.57
589.0390625	0.26
591.2802124	4.86
593.2519531	0.95
597.4895020	0.34
609.5015869	2.19
622.4358521	0.50
628.7039795	2.44
629.3674927	0.44
633.2914429	0.25
637.1139526	3.38
639.1551514	0.39
645.3468628	0.80
653.1486206	2.39
655.3668823	0.87
661.4226685	0.74
663.2744751	6.66
670.0836792	0.58
671.0421753	3.83
675.4070435	0.28
679.1032104	6.41
681.2113037	21.93
687.7088013	0.45
689.2450562	77.28
693.0746460	0.57
695.4558105	0.53
696.1079102	1.14
697.0858154	18.81
698.9581909	2.17
703.3244019	0.59
705.4755249	1.14
707.1226807	49.38
710.6838379	0.22
721.3443604	0.81
723.3121948	3.77
731.1834106	7.21
748.3532715	0.43
764.8178711	1.32
770.8609009	2.90
771.5863647	0.19
773.1969604	2.13
789.0285034	2.94
789.6432495	0.68
797.4981079	0.39
815.0863647	13.23
816.0691528	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1381
Annotation	Galactotriose
Peak:m/z	Relative Intensity
160.9707489	0.13
167.6423035	0.07
179.0234680	1.53
197.0380554	0.05
215.1245117	0.04
221.1307068	0.22
245.0144348	0.12
249.4414062	0.15
250.8364105	0.04
263.4784546	0.05
280.8617554	0.23
305.2435303	0.02
323.2366943	0.45
339.0045166	0.16
341.0821533	2.30
359.2551880	0.18
377.1282349	11.02
383.2139893	0.09
442.7392578	0.11
485.3089600	0.04
503.1836548	100.00
504.1974487	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.13
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
71.8964615	14.76
84.1206665	0.19
85.9494476	0.03
89.1410828	0.04
103.0235443	0.02
104.0627747	0.05
112.2076416	0.02
114.7438354	0.11
117.9530029	100.00
130.0078125	1.08
136.1419067	0.02
148.0468292	0.72
149.2656860	0.03
158.3719025	0.03
172.9805756	0.17
174.1274261	0.03
184.0868988	4.38
188.0350189	0.04
201.0526886	1.47
203.2849579	0.02
210.9571838	0.20
217.0169525	0.15
219.0670013	0.05
224.1517181	0.16
229.0352783	6.71
230.0497437	27.48
233.3661346	0.27
239.1238861	0.21
249.0249634	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1637
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
168.8758545	0.07
180.2956085	0.09
198.9339447	0.07
209.1939697	0.06
227.1142273	0.05
236.1906738	0.15
241.098587	0.05
242.9997864	0.13
258.0214844	0.07
258.7310181	0.04
267.3005676	0.10
271.0867004	0.21
273.1570435	0.40
277.2102051	0.12
287.0567017	100.00
287.7067261	0.23
295.3530884	0.15
301.0818481	1.68
304.2191162	0.05
307.0203247	0.06
311.2758789	0.04
313.0090942	0.04
323.9034424	0.10
329.2324219	0.25
335.3093262	0.07
343.3381958	0.15
350.3803101	0.14
353.0609741	0.04
356.6870117	0.12
366.2890015	0.22
379.0640259	0.09
382.8928833	0.14
390.0309448	0.03
395.1289673	0.33
413.2106323	0.13
419.1348267	0.16
425.2724609	0.22
431.0772095	0.68
432.8378906	2.40
437.1990356	0.47
442.8330688	0.25
445.4053345	0.37
449.017395	20.29
451.2281494	0.23
456.9648438	0.14
458.6235352	0.35
462.9489136	6.07
474.9194336	0.23
478.2098389	0.49
479.3496094	0.27
485.2190552	0.12
494.2381592	0.10
501.1087646	0.25
505.0036011	0.05
516.3580322	0.44
527.1956787	0.16
531.9129639	0.33
532.7021484	0.07
534.7026978	0.13
541.28302	0.17
559.458313	1.02
562.206665	0.08
565.0144653	0.23
567.6204834	0.13
571.2372437	0.22
573.2918701	0.04
577.2722778	0.75
578.5883179	0.18
580.9397583	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1827
Annotation	5,2',4'-Trihydroxy-3,7,5'-trimethoxyflavone 2'-galactosyl-(1->4)-glucoside
Peak:m/z	Relative Intensity
259.2742920	0.27
273.1469116	5.74
279.1323242	0.04
291.2391663	0.21
319.8937683	0.17
323.1904297	0.09
339.2301636	0.04
340.9149780	0.30
342.3918457	0.08
343.2241821	0.03
417.3727417	0.11
423.3112793	0.61
435.1868286	10.29
450.9475098	0.06
458.8635864	0.12
477.1116943	77.32
482.3229370	0.04
521.3403320	0.14
525.3867798	0.06
579.0247192	0.28
596.9675903	0.05
619.4006348	0.26
639.1353149	100.00
641.3786011	0.10
665.2533569	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	706.2098
Annotation	Unknow
Peak:m/z	Relative Intensity
271.2153931	0.08
283.4310608	0.33
291.1024170	0.28
300.6105042	0.26
303.1768799	0.41
351.0852051	0.14
366.9868774	0.52
378.9711304	0.17
380.5988159	0.19
421.2326660	0.06
439.1015625	0.37
524.6188354	0.20
567.9296875	0.75
590.9786987	100.00
591.7094116	0.32
595.2608032	0.57
630.4929199	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	279.0999
Annotation	Methionyl-Glutamate
Peak:m/z	Relative Intensity
84.0740967	0.02
84.8902588	0.13
87.0189285	0.15
101.9853287	0.53
103.8801956	6.02
104.9290009	0.07
115.1921387	0.03
129.8228149	0.13
132.9879150	18.34
133.7668457	0.02
148.0179749	0.41
149.9401855	100.00
184.9821167	0.04
205.1557007	0.09
216.0139160	1.98
231.0655212	0.04
232.7822266	0.14
233.8558350	0.02
242.7641296	0.03
261.0070801	2.18
262.1123047	8.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	935.3763
Annotation	Oxytocin 1-8
Peak:m/z	Relative Intensity
309.4956665	0.07
325.2823486	0.08
338.3165283	0.04
341.2211914	0.06
343.3304749	0.12
369.1954651	1.44
371.0054932	0.16
387.2452698	12.22
387.9199219	0.03
389.2581787	0.04
403.3001099	0.80
422.9483643	0.09
427.3239136	0.23
429.2002563	5.36
471.6113281	0.15
475.3625488	0.06
495.0709839	0.07
505.8417358	0.13
507.2759399	0.08
511.4395752	0.14
519.2090454	0.02
528.9846191	0.03
534.7959595	0.11
547.3391113	0.16
549.3396606	1.78
551.3856812	0.36
565.3469849	0.07
567.3582764	1.95
575.3065796	0.37
584.0355835	0.12
593.3346558	9.26
609.4877319	0.04
611.3554077	100.00
612.2844238	0.10
617.3930054	0.03
623.2651367	0.12
625.5215454	0.17
635.1765747	0.76
653.2912598	4.65
665.4288330	0.21
676.6004639	0.12
683.2411499	1.70
691.5100708	0.08
694.4276123	0.20
695.2948608	0.38
707.6041870	0.22
709.5323486	0.12
713.2384644	3.58
713.8616943	0.12
737.2478638	0.16
743.1620483	0.46
745.8839722	0.03
755.3046875	3.95
773.2111206	37.09
773.8565063	0.31
791.2567749	0.30
798.0841675	0.06
799.0842896	0.14
833.0812378	0.05
856.0908813	0.17
858.9414062	0.46
873.2186890	0.20
891.4067993	0.06
899.1616211	0.08
903.3634033	0.09
917.3242188	11.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.1172
Annotation	Unknow
Peak:m/z	Relative Intensity
157.8930664	0.19
170.9976501	0.15
174.6302490	0.49
181.1051178	0.21
183.8494568	0.08
189.1325378	0.10
191.3176880	0.40
192.1352844	0.18
205.2273254	0.13
207.1075439	100.00
207.8697815	0.07
217.3884888	0.16
231.0881195	0.21
235.2091217	0.33
243.2465210	0.29
247.2286072	0.10
253.0986938	0.32
281.0921936	0.08
284.2390442	0.37
303.2866516	0.14
304.5093384	0.16
315.7946167	0.41
342.6028442	0.07
352.3983765	0.10
357.2810974	0.28
359.2139587	0.69
361.0646973	0.09
367.2410278	0.29
368.2331848	0.20
382.1593628	0.07
383.1351624	0.13
392.5130920	0.17
393.4110413	0.16
395.0814819	0.76
397.5157166	0.30
410.1831665	0.38
411.1906433	0.60
413.3473816	0.53
419.2916565	0.83
425.3484497	0.15
430.2297058	0.11
437.1504822	7.16
437.8194275	0.17
441.4009399	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1113.5485
Annotation	Unknow
Peak:m/z	Relative Intensity
457.3262939	0.21
465.2087402	0.48
611.4317627	0.10
615.2512817	0.12
637.0671387	0.12
681.4093018	0.53
693.3969727	0.30
697.4022217	0.36
709.3587036	0.22
727.5090942	1.28
737.7883301	0.17
745.3016968	0.11
753.4028320	0.47
761.4938965	0.21
769.5665283	0.39
774.5327759	0.06
785.4777222	0.31
787.4360352	0.42
813.4058838	0.19
831.5104980	0.81
845.2978516	0.43
847.6191406	0.30
889.1614990	0.04
907.2244873	0.32
923.2719727	0.13
951.5518799	0.05
956.8096924	0.05
957.4934082	0.12
959.3585205	0.64
965.4189453	0.28
977.2185059	0.37
991.3684082	1.29
1009.3510740	0.09
1035.4472660	4.44
1053.4134520	100.00
1054.2260740	0.35
1081.7600100	0.10
1095.2911380	1.03
1096.5944820	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2706
Annotation	Ixerisoside J
Peak:m/z	Relative Intensity
175.2831573	0.02
179.0132904	5.77
224.9722137	0.52
259.0156250	0.15
261.2029419	0.12
265.4937134	0.05
269.0517883	0.09
273.1018982	0.15
285.2243652	0.40
287.1389771	0.17
289.0943298	0.36
295.3569946	0.05
297.1005859	0.03
303.3461304	0.22
309.0270386	0.13
310.9349365	0.05
327.0681763	0.09
331.3743896	0.06
341.3011475	0.04
343.2200928	0.03
346.0781250	0.10
349.2883301	0.66
352.3190308	0.11
359.2852783	0.11
367.2495117	100.00
372.9008179	0.05
380.9701538	0.02
384.3175049	0.06
387.3136597	0.03
393.4658203	0.09
395.3216553	0.32
403.3019409	0.04
405.3565063	0.07
406.2863159	0.09
407.1950073	0.12
408.9829712	0.68
413.1826172	0.53
421.3637085	0.06
423.0997314	0.46
430.5659790	0.26
433.3619995	0.14
435.1075439	0.07
435.9974976	0.04
437.0806885	1.08
438.9699707	0.35
441.1061401	0.02
446.7819214	0.11
448.6668091	0.37
449.3129272	1.22
450.8759155	0.03
452.1328125	0.17
453.0953369	0.08
455.4522705	0.59
465.0961304	0.03
468.4543457	0.23
469.0814819	0.60
473.3806763	0.05
489.2537231	0.09
494.3700562	0.10
495.4463501	0.17
498.6489258	0.05
499.3186035	0.03
500.9511108	0.05
505.1836548	0.10
507.2771606	0.15
512.0344849	0.30
513.1935425	0.15
514.9949341	0.52
516.9658813	0.07
521.7323608	0.38
528.9130249	4.24
529.5911255	0.07
531.3269653	0.25
532.2991333	0.03
539.1022339	0.50
543.2216797	0.07
547.4821167	0.09
551.7328491	0.16
557.1829224	1.33
559.2496948	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0147
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9576721	0.01
128.9831543	0.01
134.9678040	0.01
195.4484253	0.04
220.8136139	0.44
221.8506622	0.05
223.8720856	100.00
224.7642212	0.11
238.9698639	0.01
239.8289337	0.01
241.7883148	7.59
243.2603912	0.01
243.9488068	0.02
250.0411224	0.02
264.7592163	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.1429
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
130.1174011	0.18
131.0280457	0.52
137.1603546	0.31
138.8806915	39.71
140.5502777	0.10
144.9543762	0.43
149.0168304	4.44
152.9482117	0.11
162.0852966	0.08
162.9445648	1.75
164.9910889	0.44
165.9682922	0.12
171.9487762	0.12
175.1359863	0.22
176.9868774	0.27
181.0281372	2.85
181.8388977	0.15
186.7410889	0.13
188.9977722	0.73
204.2719879	0.31
204.9040680	1.45
213.0957642	0.97
215.1662292	0.08
225.0576477	0.13
231.0293884	0.06
233.1134033	0.15
235.0925293	0.94
239.4424744	0.06
242.3668823	0.06
247.0470886	0.96
251.5158691	0.14
257.2402954	0.06
259.1227112	0.14
265.0456238	2.89
270.1782532	0.15
271.2076416	0.07
272.4387207	0.15
273.3027344	0.06
274.5149231	6.67
275.1414795	100.00
276.2394104	0.10
280.8521423	0.15
283.0773315	28.77
285.0525818	0.10
286.8097534	0.38
289.0649414	0.57
290.4410400	0.14
295.1180420	0.21
297.0945740	0.15
298.2597656	0.30
299.0559692	3.59
301.1282959	45.08
302.7773438	0.58
305.1356201	0.60
306.5237122	0.82
308.3183899	0.10
309.6433716	0.13
315.1789246	0.11
317.0543823	4.10
319.3102112	0.64
322.9859314	0.15
324.1869507	0.16
327.2933350	0.20
329.0954895	0.23
333.1071777	0.15
337.3961792	0.36
341.0123901	4.12
344.9507446	0.22
349.2006836	0.64
350.2678223	0.29
351.4426880	0.08
352.7115479	0.07
356.9399109	0.33
363.3059082	0.44
365.0059204	0.37
369.2107849	0.31
370.8851013	0.46
372.6966858	0.54
373.4206238	0.21
383.0481873	1.02
390.9167175	0.52
392.3738708	0.31
393.3898010	1.02
401.1286926	14.67
409.1192932	0.26
410.0428772	0.12
417.0333557	0.07
419.1239014	13.52
427.8863220	0.61
438.3413696	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3149
Annotation	Unknow
Peak:m/z	Relative Intensity
277.2708130	2.86
502.2756958	100.00
502.9852295	0.73
503.7370605	0.03
528.3071899	0.10
564.3861084	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.37
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1037750	0.09
199.8169556	0.04
200.8395081	0.57
208.7200623	0.27
211.0166016	1.19
213.0847626	0.04
216.9321289	0.26
219.1119690	0.13
221.0208435	0.55
222.1094513	0.21
222.8549805	0.66
225.1363983	0.05
227.2588196	0.25
228.8865509	0.27
233.3088684	0.05
235.1918335	0.22
236.9409027	0.45
237.8965149	0.09
239.0423279	0.88
241.1119843	0.52
245.4146118	0.08
246.5669556	0.20
247.2421570	0.05
248.2508850	0.12
249.1725159	1.41
251.0424042	0.21
252.0315247	0.04
253.1787415	0.51
255.5878601	0.13
256.9175415	0.17
258.1866455	0.22
259.8830261	0.15
261.0645752	0.16
263.2146606	0.27
265.1063843	1.36
267.0140381	53.14
268.3713379	0.28
269.8667603	0.12
272.8595276	0.10
274.2260742	0.04
277.1795349	0.84
279.1187744	0.39
280.9438782	0.08
282.8888855	0.17
283.6394348	0.22
284.5173645	0.21
287.1701050	0.74
289.9103088	0.07
291.2002563	0.05
292.0252075	0.18
293.1184692	0.29
295.0038452	0.45
296.0397949	0.14
297.0465393	0.03
299.3632812	0.05
301.1407776	0.23
303.3404236	0.11
305.2618408	0.03
306.1286621	0.24
307.1927490	1.02
307.8811340	0.22
310.3318176	0.11
317.0804443	0.07
319.0404053	0.07
327.1658936	0.09
328.2639771	0.33
329.4017944	0.37
347.0283203	8.49
348.3687134	0.63
349.5145874	0.14
361.0156860	0.04
364.3739014	2.24
365.2301636	9.26
366.4362793	0.41
367.3549805	0.02
372.2130127	0.09
379.0477905	0.14
382.2291870	5.63
383.1184692	100.00
384.1278687	1.66
385.1466675	0.11
391.2507935	0.18
393.0187378	0.46
399.2132568	0.14
403.1256714	0.05
420.6568604	0.07
423.3980103	0.19
424.0702515	0.05
429.8816528	0.07
432.3959961	0.19
440.2860107	0.04
445.8556519	0.19
450.9741821	0.14
452.4520874	0.45
453.3101196	0.12
456.7041626	0.03
458.1273804	0.22
460.2329712	0.12
461.3051147	0.61
465.2160034	0.30
466.3432007	0.16
473.0030518	0.27
476.8668213	0.12
478.1893921	3.12
479.2361450	6.27
485.6954956	0.23
494.5211182	0.09
497.1171265	0.12
498.7952271	0.04
508.0081177	0.26
509.3953857	0.20
511.3161011	0.06
513.3799438	0.16
516.3423462	0.18
517.3010254	0.23
519.2042236	0.19
520.2604980	0.05
525.5915527	0.12
527.4777222	0.16
528.0944214	0.10
529.1372681	0.46
531.3767090	0.12
533.3220825	0.20
534.1964722	0.24
535.2781372	0.17
537.2033691	0.11
540.2785034	0.54
541.4196777	0.12
545.2300415	0.30
546.3005371	0.08
547.8615112	0.07
548.5377197	0.04
549.3250732	0.21
552.3604126	0.16
553.3571167	0.33
555.4710083	0.15
558.0609741	0.42
559.0801392	2.41
560.1065063	0.45
564.7556763	0.05
569.6017456	0.28
570.4055176	0.17
576.2802124	1.51
577.1571045	5.82
578.3954468	0.04
579.2293701	0.11
581.1854248	0.07
583.1074829	0.13
588.6296387	0.14
593.5880737	0.81
594.4165649	4.12
595.0814819	11.47
595.9180908	0.98
600.3961792	0.08
603.1292725	0.29
604.1945190	0.13
610.8182373	0.03
612.1237183	0.40
616.9589844	0.16
621.2472534	0.20
623.2188721	0.02
624.2499390	0.04
634.4125366	0.17
639.3049927	0.13
642.0774536	0.08
645.1843872	0.12
653.4240112	0.13
657.2774048	1.22
659.4456177	0.17
661.3340454	0.25
664.6882935	0.12
665.6539307	0.25
675.1953735	4.10
677.5502319	0.10
693.1264648	9.93
693.7542725	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.2118
Annotation	Unknow
Peak:m/z	Relative Intensity
116.0563354	0.02
118.1034927	0.45
120.0612869	0.06
120.9512939	0.06
129.9783478	0.14
148.8472290	0.09
154.8689270	0.10
183.1183167	0.28
185.1768188	1.31
187.7182007	0.08
191.3545532	0.07
201.6069031	0.08
202.3979645	0.03
213.0976257	0.62
215.0271912	0.03
217.1285706	0.17
225.1294250	1.36
226.9706421	0.03
228.4315491	0.04
229.3206177	0.15
231.0890808	100.00
231.7070312	0.55
241.0352173	0.09
243.0550537	28.55
245.2670288	0.26
253.2821045	0.05
256.3764648	0.05
261.1755981	0.05
269.8969116	0.03
282.7359619	0.04
291.2378540	0.05
293.1942139	0.09
295.8133850	0.02
297.4210815	0.11
307.4058533	0.01
314.0463562	0.04
324.2100220	0.24
332.1211548	0.09
337.2949219	0.09
340.1629944	0.04
342.1943054	6.13
343.2892151	0.16
345.9693298	0.20
350.9017944	0.14
352.0621643	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1090.05
Annotation	Unknow
Peak:m/z	Relative Intensity
323.1245422	0.57
425.6246948	2.64
437.4185181	4.19
457.8106689	0.64
479.4196777	1.76
481.2465210	6.27
499.3098755	3.02
527.4362183	1.41
537.3544312	0.50
569.3896484	4.11
571.4114990	1.06
579.7893066	1.52
587.1337891	0.57
589.4174805	13.92
590.4074707	3.16
610.3747559	0.61
611.7620850	3.57
629.7243652	0.86
631.5002441	1.03
657.4857178	100.00
658.5241699	20.13
659.5020142	0.57
667.4732666	1.50
685.3501587	1.45
703.6250000	1.33
729.3288574	43.37
730.1033936	12.24
730.7203369	2.93
746.4793091	1.85
747.4168701	22.69
751.2299194	0.42
765.5958862	13.60
766.3848267	1.51
817.5079346	1.06
861.2553711	0.55
865.3626709	22.61
866.4492188	15.54
883.5710449	6.39
884.6873779	1.97
909.4213867	7.39
910.1324463	0.78
927.4459229	37.49
928.5234375	12.91
969.3059082	0.84
1027.3702390	16.03
1028.4742430	7.83
1046.6582030	0.68
1053.4270020	1.91
1071.3317870	19.70
1072.4775390	22.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2104
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
85.02772522	0.01
91.03770447	0.11
92.81490326	0.02
94.99021912	0.47
96.94734192	0.24
98.98630524	0.14
100.7942505	0.19
104.9222336	0.30
107.0165558	0.58
109.0642929	0.36
111.0193481	0.10
113.0470123	0.06
117.0691147	0.15
119.0249939	0.22
121.0388565	0.47
122.4705963	0.07
123.1651001	0.28
125.2271271	0.26
126.942215	0.12
129.1318359	0.07
131.0901184	0.37
133.1016541	0.74
135.0762024	0.27
136.3685608	0.02
137.044632	0.38
138.3264923	0.03
139.0488281	0.04
141.0454712	0.01
143.1111298	0.10
145.0751038	0.94
146.0140686	0.06
147.0938416	0.96
149.0455322	1.71
151.0365295	0.16
152.9055786	0.18
155.0499878	0.05
157.1048584	0.46
159.0225983	1.22
161.1564331	0.44
163.110321	0.90
163.9478149	0.01
164.9629669	1.03
167.1080017	0.07
169.0563812	0.42
171.0826416	1.48
173.099472	0.67
175.1300201	0.40
176.0682373	0.03
177.1521912	0.25
179.2645111	0.40
181.162735	0.13
183.0774841	0.35
185.1817169	0.10
187.1417694	1.50
188.1144104	0.01
189.1257019	0.16
191.0586243	0.22
193.1790466	0.34
195.1934052	0.17
197.1891632	0.40
199.2040405	0.19
201.0934143	0.51
203.0174561	0.10
205.1139832	1.72
207.1280518	0.43
209.2324524	0.13
210.4406128	0.05
211.0790405	0.31
213.3243103	0.12
215.2761841	0.27
217.0594177	0.21
219.1971436	0.92
221.1548462	0.13
222.1626587	0.02
223.2540894	0.54
225.0537415	0.03
227.2376099	0.03
229.2119751	0.70
231.3733826	0.04
233.0506897	0.19
235.1667786	1.18
237.0539856	0.37
239.2200928	1.89
245.1473999	0.05
245.775177	0.03
247.3137207	0.52
249.0733337	0.11
251.1017456	0.27
257.2597656	4.53
265.1898804	0.09
270.9736938	0.04
275.2017517	100.00
278.0106812	0.04
283.9489441	0.10
284.6991272	0.04
294.350647	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1028.01
Annotation	Unknow
Peak:m/z	Relative Intensity
324.8094482	0.02
337.2751770	0.02
499.4996643	0.02
567.7523193	0.04
613.3240356	0.02
639.6512451	0.13
640.3792725	0.05
657.5004883	0.27
675.6116333	0.07
775.4133301	0.06
793.2637939	0.01
793.8817139	0.03
819.3662109	0.05
853.3186035	0.02
887.3845215	0.02
921.4609375	0.39
925.1572266	0.03
939.3120117	0.13
941.3649902	0.54
942.5593262	0.10
965.3989258	1.52
966.3173828	0.10
981.6765137	0.05
983.4407959	100.00
984.5495605	6.48
990.9394531	0.02
1005.2802730	0.11
1005.9743650	0.02
1009.4620360	0.04
1010.5039060	0.07
1069.2620850	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.54
Annotation	Hoodigoside O
Peak:m/z	Relative Intensity
359.0292664	0.22
363.3455811	0.42
375.3637390	0.20
379.3959961	0.45
387.4366760	0.13
389.2505493	0.11
405.3468018	1.49
407.2483521	0.27
421.2306519	2.24
423.2552795	0.63
435.6854248	0.47
437.2120667	0.43
439.3413696	1.93
441.5848389	0.59
447.0000305	0.27
455.4847717	0.79
457.3723755	0.49
463.4006958	0.49
465.3794861	0.53
475.0510864	0.18
482.0219116	0.23
483.3301086	2.34
487.1210327	0.58
510.9378357	0.20
521.6300049	0.13
527.5446777	0.58
535.3587646	0.14
537.3638916	0.73
541.3942871	9.42
551.6358643	0.72
557.3560181	3.34
559.5151367	10.49
571.7198486	2.27
573.1815186	0.16
579.4720459	1.55
587.5574951	0.31
599.2841797	0.56
610.3627930	0.74
613.4235840	1.08
615.4852295	7.84
623.2723389	0.83
627.4958496	9.94
629.5727539	1.21
641.3376465	3.26
655.5004272	5.70
673.3563843	8.05
674.0097656	0.15
691.5699463	0.63
692.6102905	0.11
699.3664551	6.88
715.6417236	0.22
717.4586182	37.78
727.0532227	0.76
733.4116211	1.66
735.5414429	0.41
751.5056152	0.43
759.4157715	2.29
769.2938843	0.34
777.4733276	0.26
817.5214844	2.13
818.4840088	0.09
831.3658447	0.12
835.4411621	37.44
836.5333252	0.60
853.6141357	11.48
879.4957275	1.86
897.4355469	5.37
923.5690918	0.90
937.1342773	0.16
941.3811035	13.24
942.4041748	0.54
949.4782715	2.19
967.4716797	66.50
968.4061279	3.22
969.0156250	0.26
981.4591064	100.00
982.7164307	1.01
999.5439453	5.83
1025.4097900	34.30
1026.4635010	1.30
1928.5949710	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.13
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
94.9319458	5.97
96.9437332	2.79
100.9657288	71.83
106.7335052	0.73
112.9978333	88.84
114.9299469	1.58
116.5766144	0.37
118.9508514	100.00
125.0082092	2.70
130.9403992	28.76
136.6799316	1.30
142.9468536	57.93
148.8432007	9.49
160.9238739	28.26
179.0504456	37.07
243.4106140	0.85
265.1387634	0.41
305.2703552	1.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	396.1888
Annotation	Unknow
Peak:m/z	Relative Intensity
118.0361328	0.12
127.4374313	0.16
128.1028290	0.28
131.9831543	0.19
137.0279541	1.14
145.0270844	0.18
146.1689911	0.14
152.0494537	0.08
154.0917206	16.67
155.0091553	0.07
164.0793457	0.12
169.0593567	0.08
171.8570862	0.40
188.0343018	0.19
196.7927856	0.24
203.1006317	0.36
205.1096649	0.62
206.1573334	0.16
214.7238159	0.15
223.0673828	2.53
223.9344788	0.22
224.9445190	0.12
231.1061401	0.13
232.2602234	1.52
233.1798401	0.22
233.7843628	0.24
237.3682251	0.20
241.1117249	1.92
244.3028564	0.06
247.1415405	1.59
247.9937439	0.10
249.1958313	0.80
259.1777649	0.20
265.2111206	0.53
267.2004089	19.56
268.2775879	0.15
269.9755554	0.08
274.9830933	0.46
279.0390625	0.30
279.9449463	0.75
316.3130188	0.47
322.0249634	0.16
332.1447449	0.10
334.2947388	4.11
335.3886108	0.10
348.3080139	0.05
350.1326294	0.25
351.0292969	0.09
352.3058777	0.84
360.2644348	2.11
361.2906189	0.43
378.3073730	100.00
379.1074524	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.2108
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
105.1408234	0.08
107.2348175	0.06
109.1736298	0.20
110.9233246	0.06
116.8586960	0.02
118.9212265	0.03
120.8977127	0.39
122.9900208	0.04
125.1317291	0.19
128.0746918	0.06
130.9030762	0.32
133.0839233	2.51
137.1453400	0.54
145.1454163	0.13
147.3172760	0.14
149.1478577	0.09
153.1279907	0.10
155.0114746	0.07
157.1640015	0.16
159.0068359	0.03
161.1546936	0.07
163.1354065	0.04
165.2306671	0.21
165.9735107	0.05
167.0960083	0.24
169.3179932	0.05
171.1363373	0.16
173.0107422	0.09
174.9655762	0.11
177.0533142	0.09
180.9875641	0.12
182.4837036	0.06
183.2099304	0.12
183.8384399	0.11
185.0658112	0.19
187.0894470	0.14
189.0909729	0.17
195.1228943	2.27
197.0536652	0.09
198.9958801	0.32
201.4457703	0.06
203.3978271	0.10
205.0626221	0.09
207.2016144	0.48
209.2948303	0.06
211.2433929	0.22
217.1375427	0.26
219.0879517	0.02
221.2789001	0.17
223.0410156	0.38
223.7462769	0.07
225.2271423	0.07
227.2605896	0.40
229.1030273	0.20
231.2097778	0.05
237.1856689	0.40
239.2101440	0.74
241.1808472	0.80
243.0715637	0.07
245.1104736	1.72
247.0277405	0.04
249.3982239	0.24
251.3684692	0.25
255.0673828	0.18
257.2499390	0.92
259.2829590	0.23
261.2374268	2.89
263.1446533	4.76
267.2236328	10.70
268.1282959	0.01
269.3777466	0.13
270.9273682	0.04
273.0905151	0.45
275.4114685	0.53
279.8859863	0.12
283.1853333	0.18
285.1976013	12.63
287.2348328	1.41
289.3295898	0.14
291.2862549	0.38
292.9983521	0.17
295.2145996	2.64
301.2032471	2.41
302.5735779	0.14
303.1979370	2.08
303.8002625	0.03
305.1915283	1.20
307.2305908	0.03
308.2022400	0.12
313.1404419	25.49
313.8433838	0.09
319.3322754	0.09
320.3280029	0.20
321.2307739	0.56
323.1610413	0.30
323.8603210	0.18
325.6509705	0.05
331.2854004	24.95
335.0642700	0.05
337.2512817	0.09
339.3782349	0.07
349.2027588	100.00
350.2202148	0.11
351.1534729	0.08
352.1535950	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.0907
Annotation	Methysticin
Peak:m/z	Relative Intensity
83.0059586	0.01
102.9782715	0.42
106.9666595	5.59
108.9977798	0.04
119.3113403	0.02
121.0607910	0.59
126.7909317	0.11
138.9071350	100.00
148.9799500	37.00
149.7037354	0.02
151.0299683	0.25
163.0451355	0.02
165.0324402	0.02
168.9650269	2.25
173.1379395	0.07
178.7087097	0.01
181.0622864	0.54
188.9342041	0.03
191.2372742	0.10
229.0504761	0.06
231.1611328	0.03
233.0183716	1.12
239.2705994	0.06
246.8562012	0.01
257.0893555	3.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.2118
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8576660	0.12
162.9200592	8.07
164.0449524	0.38
171.0139465	0.97
172.2047424	0.07
173.1733398	0.15
200.7048035	0.25
216.1642761	0.25
218.7961426	0.52
236.7863464	0.38
237.4222260	0.53
254.8676453	100.00
256.0012817	6.05
271.1030884	0.49
288.7366333	0.21
306.8597412	0.23
320.0185547	0.46
323.4862671	0.09
324.4000854	1.15
325.0005493	3.26
341.1032715	0.26
342.5297852	0.23
416.0675659	4.03
416.7852173	48.94
417.8768921	1.87
433.5946655	0.18
457.1036377	0.06
478.2982788	0.29
486.8845825	0.35
513.8986206	0.07
530.2858887	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1084.04
Annotation	Unknow
Peak:m/z	Relative Intensity
323.4755249	0.75
359.3010559	0.31
407.6282043	0.68
437.5479736	1.53
457.5203857	8.83
465.2706299	2.62
481.3060303	1.61
525.2979126	1.75
543.3197021	0.42
551.3006592	5.58
553.4686279	1.58
563.5130615	8.98
581.3300781	0.64
583.5346069	17.40
584.3520508	4.02
615.5750732	1.31
623.4252930	3.23
651.4404907	71.45
652.5462036	12.86
653.5141602	0.45
655.2589722	0.69
679.4821777	3.12
680.2960205	1.22
697.2296143	1.32
698.0045776	1.10
698.6298218	0.55
723.2811279	49.71
724.2747192	6.71
731.1888428	0.95
733.5406494	13.59
734.3377686	12.11
741.4267578	22.96
742.4920654	8.62
751.4457397	3.81
752.4735718	0.55
759.4992065	3.62
760.5410767	3.57
794.9920044	7.92
803.2547607	0.55
821.6416016	4.17
859.1353760	2.21
877.4000244	1.37
878.8804932	0.79
895.2442627	14.77
896.6218262	7.26
903.9152832	1.50
913.7092285	1.88
921.5249023	25.37
922.3525391	4.97
923.0327148	0.40
925.4057617	1.33
939.4512939	2.42
940.8084717	0.35
957.5908203	8.30
958.5773926	6.33
962.7696533	1.65
964.4776611	0.39
983.4162598	100.00
984.5441895	39.57
1021.3010250	11.40
1022.5097660	2.02
1039.7897950	0.95
1041.3354490	7.24
1042.5083010	0.79
1055.7384030	1.42
1065.3093260	45.11
1066.3278810	19.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1979
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9860229	0.14
165.2789612	0.02
172.9885864	0.05
185.2331848	0.10
197.0155945	0.12
238.2345276	0.04
241.2250671	0.04
245.0213013	0.06
246.8714142	0.06
251.0809021	2.54
263.3363647	0.08
285.0380249	0.05
293.2504272	0.62
303.3452454	0.10
320.3519287	0.11
321.0538940	0.05
333.0507202	0.08
347.0893555	0.40
348.1321411	0.23
351.1816406	0.08
361.0886230	0.03
365.2965698	1.79
374.2621460	0.07
380.5954590	0.15
383.1734619	100.00
392.1818237	1.42
394.6058960	0.04
395.4433594	0.03
407.1527710	0.05
417.0344238	0.10
422.2753296	0.07
425.1652222	30.09
435.2605591	0.19
436.3143921	0.03
440.0864868	0.11
461.2043457	0.07
463.4108276	0.06
465.1924438	6.18
467.1697388	0.15
479.1017456	0.14
482.0084839	0.06
483.3936157	0.12
491.2448730	0.14
504.5697632	0.23
509.2761841	2.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.2118
Annotation	Unknow
Peak:m/z	Relative Intensity
120.0400238	0.57
126.7816772	0.01
127.7713394	0.03
130.0888672	0.14
142.9097290	0.04
145.8532257	0.02
149.7768250	0.01
166.0870056	2.58
169.0681000	0.07
173.1446838	0.02
190.8251038	0.02
197.1736603	0.21
203.3630371	0.04
211.1072388	0.03
215.0046234	0.02
225.0395660	1.02
233.1108704	0.55
237.3324585	0.01
240.1483765	0.03
241.1586914	0.10
243.1202698	32.95
245.1141357	0.32
246.0834656	0.11
248.9415894	0.03
251.3356628	0.03
257.0819092	0.51
260.9474487	0.23
262.9858704	0.02
272.1634827	0.01
277.1398315	0.05
279.1347351	100.00
279.8191528	0.23
281.5149536	0.09
282.8955994	0.04
287.2144165	0.57
299.1770020	0.05
302.1296692	0.05
310.4248657	0.02
312.0938110	0.06
317.9107056	0.14
318.9716187	0.03
326.8205566	0.12
341.7851868	0.03
345.0272522	0.15
347.0357666	0.20
349.7198486	0.08
354.4499512	0.07
355.5979919	0.04
362.4391479	0.11
372.2391357	0.19
376.2475586	0.02
378.1440125	0.12
381.2899170	0.02
384.1969299	0.12
388.3674316	0.06
390.1907654	4.16
391.1725769	0.63
399.3045044	0.06
408.3535461	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1145
Annotation	Lactulose
Peak:m/z	Relative Intensity
341.1474609	100.00
341.7584534	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.2758
Annotation	Unknow
Peak:m/z	Relative Intensity
165.1340027	0.04
171.1100922	0.08
193.2940674	0.03
201.0760651	0.04
214.8893280	0.03
217.4478760	0.07
227.2636719	0.10
231.2603455	0.06
239.2433472	0.04
253.2708282	0.10
257.0681152	0.19
269.1059875	0.09
271.1262817	0.08
272.0545654	0.02
273.0659790	0.08
278.9637146	0.07
280.2835083	0.07
281.1257935	0.04
284.9958801	0.26
286.8265381	0.21
289.2827148	0.05
298.0744019	0.05
299.0839844	0.06
302.5917358	0.04
307.1142578	0.30
308.3841553	0.05
311.0642700	0.03
313.3900757	0.12
319.0487061	0.18
323.9863281	0.02
325.2749023	0.05
327.0594482	0.16
331.2818604	0.04
343.4385376	0.17
352.7276611	0.07
362.8400269	0.08
364.2058716	0.21
364.9784546	0.04
367.1871338	0.16
371.4924927	0.03
375.1159058	0.25
377.1340942	0.12
378.3151855	0.51
379.0792847	0.06
380.2050781	0.10
381.2266846	0.09
383.2580566	0.11
388.0248413	0.14
391.1339722	0.89
392.2235718	0.11
393.1639404	0.63
395.2278442	0.27
396.1510620	0.02
403.2072754	0.13
404.9023438	0.11
407.2622681	0.80
409.2873535	0.15
415.2517700	0.11
419.2420044	0.06
421.2977905	0.43
423.2288818	0.44
424.3147583	0.08
430.3825073	0.09
431.5056763	0.13
433.2521973	1.94
434.1549683	0.18
434.9978638	0.10
437.3005981	0.70
438.1126099	0.09
439.2458496	0.60
449.1473999	1.05
450.3264160	0.41
451.9467163	0.06
453.1981201	0.42
454.1469727	0.07
457.0693970	0.03
458.1268311	0.03
463.3159790	0.09
466.6090088	0.04
469.2542725	0.02
473.3831787	0.12
482.3163452	0.14
492.1683960	0.06
500.0165405	0.04
502.3451538	0.07
509.5110474	0.01
511.4080200	0.03
513.2180786	0.20
514.1907349	0.08
515.2111206	1.05
516.6656494	0.04
517.3029175	0.02
523.2864380	0.58
530.1316528	0.07
531.3989868	0.06
536.2932129	100.00
537.2714844	0.94
538.0396118	0.03
538.9121094	0.24
539.7192993	0.13
541.0417480	1.03
541.7073364	0.03
542.5592041	0.11
543.1867065	0.04
543.9636230	0.02
546.4475098	0.09
781.3851929	0.08
782.3737183	0.14
827.3264160	0.16
829.2844238	0.06
833.3615723	0.07
893.3759766	0.05
911.5397339	1.18
942.7511597	0.09
943.5482788	0.05
1073.5355220	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
769.6438599	42.42
837.8058472	20.27
958.7849121	59.45
967.3999634	100.00
968.2982788	19.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	720.2245
Annotation	Unknow
Peak:m/z	Relative Intensity
301.0040588	0.51
303.3742676	0.19
304.1793823	0.14
326.1995239	0.25
363.9171753	0.15
366.3008423	0.09
438.9532471	1.48
452.9531250	0.40
491.2029419	0.34
494.3145752	0.11
500.5042114	0.21
540.7746582	0.37
550.1210327	0.42
558.3357544	0.30
559.4100342	0.56
561.0038452	0.89
568.8052979	0.35
573.3040161	0.26
587.3678589	0.19
591.1299438	100.00
604.7788086	0.19
605.4563599	0.34
702.2280884	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1299
Annotation	Phloridzin
Peak:m/z	Relative Intensity
124.9261322	0.87
137.0889587	0.84
139.0990295	0.02
147.0566711	0.11
148.9992371	0.32
160.9730835	1.33
164.8605347	0.06
167.5498505	0.02
185.8862915	0.02
187.2594604	0.08
191.1590729	0.16
203.0349426	0.06
211.0392303	0.06
214.2498779	0.06
229.0970612	1.06
233.0901489	0.04
249.3726196	0.03
255.2694702	0.05
269.0639038	0.03
271.2228699	0.04
273.0715027	100.00
273.9722595	0.04
283.3602905	0.02
285.031189	0.02
287.1253357	0.27
297.114624	0.63
299.0372009	1.10
314.2004089	0.02
316.0730591	0.01
327.6135254	0.08
332.4422302	0.02
347.2669067	0.02
373.5115356	0.03
387.1621094	0.03
399.1003723	0.02
407.2316284	0.10
417.1594849	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.146
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
174.2116852	0.09
175.1399994	0.03
179.0480652	1.50
182.7942200	0.05
187.0829163	0.16
189.1909332	0.09
190.0729980	0.06
190.7572632	0.05
191.8842773	0.44
193.0618744	0.63
195.9921875	0.11
197.1486816	0.26
199.0532532	0.26
200.1084900	0.10
200.9931641	0.13
203.2272339	0.17
209.1390076	0.07
211.0352325	0.23
216.8679504	0.16
217.9684601	0.03
219.1466980	0.05
221.1946564	0.26
226.0332031	0.04
227.1768646	0.44
228.1490479	0.39
229.0984497	0.29
231.1973114	0.06
232.7713623	0.08
234.8435211	0.23
238.8775177	0.36
239.9871826	0.04
241.5716248	0.15
243.1065369	0.19
245.0801697	0.09
248.1802521	0.21
253.3947144	0.10
254.1790161	0.30
255.1691742	2.88
256.2018433	0.41
257.1247253	0.62
263.5266418	0.08
268.9833374	0.04
271.1278076	5.87
272.0421143	0.58
273.1469421	1.54
274.1293030	0.04
275.1258545	0.08
281.2214355	0.11
283.1584473	0.59
284.0560303	0.19
285.0651855	2.08
286.0752869	0.19
295.1605225	0.20
297.0808411	1.32
298.2674561	0.36
300.0144043	31.65
301.0373535	100.00
302.1296997	3.57
309.6082153	0.16
311.8558960	0.04
313.1631470	0.94
314.2374268	0.18
315.1143799	0.28
319.4552002	0.13
321.2095642	0.12
323.2807007	0.12
325.1164551	0.35
327.0991821	0.06
331.3745117	0.04
332.3179932	0.03
337.0456543	0.31
343.1635132	7.73
344.1126099	0.62
349.4777222	0.17
351.9237061	0.09
355.2340698	0.30
359.7304688	0.10
367.4155273	0.07
373.1199951	1.08
374.0402832	0.07
383.4389648	0.03
385.0151367	0.09
387.0808105	0.19
399.0438843	0.14
408.8876953	0.17
413.2671509	0.29
417.1322632	0.09
425.5403442	0.28
427.1018677	0.10
428.2720337	0.16
433.2415161	0.10
437.3391113	0.05
445.2708130	0.09
447.2030029	0.12
453.4174194	0.07
455.2324219	0.17
457.4983521	0.04
461.2196045	0.05
462.0140991	0.13
463.1481323	0.79
465.3206177	0.53
471.3267822	0.13
473.1542358	0.08
477.0352173	0.06
483.2023926	0.23
489.1105347	0.62
499.5337524	0.19
500.2007446	0.07
505.4541626	0.03
507.5081177	0.10
529.3260498	0.03
532.6455078	0.06
541.0257568	0.07
546.8662720	0.06
547.5601196	0.13
549.2979126	0.24
550.2644043	0.14
561.3300171	0.07
563.2788086	0.09
565.1333618	0.50
566.2615967	0.16
573.1210327	0.08
579.6057739	0.12
582.7970581	0.05
591.1323853	2.10
592.2337036	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.1802
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0106354	0.02
235.1131439	0.03
251.1590576	0.09
260.9613037	0.10
271.2526855	0.02
283.3240051	0.02
298.1330261	0.04
299.2775879	0.03
303.1286316	0.02
304.3729553	0.12
307.0593262	1.00
307.6918335	0.05
311.3026733	0.04
315.0794678	0.02
317.0951233	0.11
322.1603699	0.03
325.2103882	5.75
331.1722412	0.60
334.3115234	0.03
339.3065796	0.05
340.2727661	0.02
349.1455383	9.34
349.8310852	0.08
375.4576721	0.03
389.1818237	0.75
404.8268127	0.10
407.0243225	1.49
409.5502014	0.08
411.4651489	0.03
415.1973572	7.87
415.8606567	0.02
430.9142761	0.02
433.1532898	29.59
433.7601318	0.12
449.1906433	0.06
451.1410217	100.00
461.2431946	0.06
469.5480042	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.143
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
70.9817886	0.09
76.6958389	0.06
84.1451187	0.03
85.1228180	0.02
99.0472565	0.14
99.6597290	0.16
106.9701385	0.15
109.2001953	0.07
117.0481567	0.04
119.0933380	0.07
120.7213287	0.04
128.8882599	0.55
130.0930481	0.25
131.0321045	0.06
133.1671295	0.05
135.1967621	0.26
137.0131836	0.02
139.1480560	0.02
141.1748810	0.06
144.9999847	0.03
146.9632263	0.40
150.1238556	0.01
151.0223846	0.11
152.1024475	0.02
155.1588593	0.20
156.1565552	0.05
160.9653778	0.04
167.2517395	0.12
168.3177185	0.38
169.0672150	2.24
171.0052032	0.05
175.0696564	0.11
183.0800629	0.22
184.1713257	0.04
185.1408234	0.04
185.9569702	0.02
186.9883575	0.20
187.9469757	0.35
193.1018677	8.43
201.0738831	0.25
206.2002411	0.15
207.9118195	0.06
208.9620514	0.13
211.0328217	100.00
212.0575256	0.29
212.7841644	0.07
220.0398102	0.28
229.1000519	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.4763
Annotation	Unknow
Peak:m/z	Relative Intensity
214.0480042	0.14
219.1953735	0.03
233.1628723	0.36
234.3530731	0.09
257.1784058	0.11
258.2578125	0.05
259.3532104	0.19
260.7531433	0.34
261.4280396	0.02
262.3161011	0.07
275.3981323	0.26
277.2350464	100.00
278.3449097	36.16
333.3217163	0.10
401.4074707	0.03
456.2294312	2.27
457.2622681	0.79
474.2412109	12.43
475.4081421	7.90
576.7119751	0.06
585.5425415	0.09
587.0482788	0.08
613.6495972	0.17
637.3131714	0.20
669.3438110	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	190.98
Annotation	Unknow
Peak:m/z	Relative Intensity
58.9270821	0.01
106.1683350	0.00
115.0951843	0.00
120.9641724	0.01
126.0339203	0.01
146.9803162	0.04
149.8127594	100.00
150.5447845	0.01
166.7805939	0.04
167.7248383	0.33
170.2237701	0.43
172.8583374	0.02
178.8516388	0.14
179.5645752	0.05
190.9151306	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1060.04
Annotation	Unknow
Peak:m/z	Relative Intensity
295.3073120	0.89
333.3463135	0.67
360.1826782	0.83
362.9493103	0.20
363.6687012	0.39
379.4164124	1.63
380.3404541	0.42
383.0961304	0.55
387.6038208	0.49
389.4000244	2.66
405.3659058	2.18
407.2186279	0.34
421.3074951	0.23
423.6318665	0.53
424.4748535	0.90
437.4162598	1.96
438.2866211	0.47
439.3178406	5.61
440.6426697	0.62
441.2631226	0.44
448.9402771	0.16
451.5438538	0.84
455.4614868	1.81
456.3186340	0.81
457.3283081	0.32
463.4617004	0.44
465.5811157	0.90
467.4185486	0.50
480.9363403	1.10
483.4723511	1.24
484.5126953	0.58
499.1835938	0.55
512.5092773	0.50
521.5599365	0.15
525.6846313	0.47
527.1716309	0.44
537.5261230	0.69
541.3615723	38.35
542.4057617	7.33
551.4095459	2.27
552.3867188	0.60
557.3765259	4.41
559.4550781	10.48
560.4686279	4.22
561.2606201	0.67
569.6182861	1.22
571.6751709	0.22
580.1643066	1.31
581.1479492	0.88
587.1140137	0.18
599.4951782	1.18
615.3903809	1.39
616.0686035	0.64
623.2312012	1.11
627.4503784	30.84
628.5437012	8.17
641.4498291	0.57
655.5938721	1.20
656.3734741	0.81
673.6013794	3.88
674.3635254	2.68
691.2741089	1.25
699.3886719	15.82
700.3725586	5.83
715.2396851	1.56
717.4202881	36.55
718.4771729	4.11
733.4420776	0.84
734.0571899	0.60
735.3975830	1.69
736.4373779	0.30
769.4954224	0.19
817.2758789	0.92
821.1428223	0.21
822.5810547	2.03
835.3267822	22.72
836.3793945	7.46
837.0878906	0.73
853.5737305	3.28
854.7298584	1.90
879.3548584	5.21
880.3789062	2.26
897.3239746	9.09
898.2987061	1.44
898.9925537	0.11
921.3549805	1.70
922.4782715	0.22
957.4788818	9.75
958.4392090	4.74
965.4837646	0.93
983.4650879	100.00
984.5487061	31.96
997.3908691	63.40
998.4525146	30.15
1015.3789060	2.48
1016.5146480	0.89
1041.3261720	19.46
1042.3604740	8.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.1481
Annotation	12-hydroxy-3Z,6Z-dodecadienoic acid
Peak:m/z	Relative Intensity
66.9149170	0.05
69.0083847	0.04
70.8361816	0.02
76.8029022	0.05
81.0124054	0.37
82.5028381	0.07
83.2053223	0.03
84.8654861	0.26
85.8218689	0.03
87.9064026	0.21
88.6690674	0.04
90.8263397	0.07
92.7826080	0.13
94.9675446	0.45
96.9883270	0.19
98.9983368	0.22
99.9048004	0.02
102.0688934	0.14
107.2379303	0.09
108.8985291	0.56
111.0230713	0.05
113.0494080	0.81
114.0665894	0.16
115.2465668	0.05
115.8520508	0.11
119.0122528	0.04
120.9868164	0.51
123.1631317	0.15
124.9875336	0.06
126.8969574	0.20
130.9258270	0.28
132.8291779	0.15
135.0876160	0.52
136.9430847	0.45
139.0278320	0.27
141.1975250	0.18
142.9585724	0.03
145.1034088	0.12
146.8989716	0.02
148.9572449	1.61
150.0728912	0.05
151.1408539	0.10
152.0728149	0.04
153.1196442	1.04
154.9235687	0.96
156.9667511	0.14
159.0888519	0.53
165.2462311	0.07
166.8318787	0.27
167.9463348	0.05
169.0260315	0.32
171.0330200	1.25
172.0465698	0.16
173.0813751	0.03
177.1522980	2.84
179.8452454	0.08
181.1851654	0.14
183.1536407	0.06
183.8649445	0.05
185.2292023	0.23
192.3251648	0.27
193.0412598	0.08
193.7052002	0.03
194.9790497	100.00
195.5943604	0.27
203.4675446	0.03
204.1521759	0.53
207.7182922	0.04
213.2040558	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.2214
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
104.9419098	0.08
107.1931763	0.01
109.0300293	0.02
119.3019257	0.08
120.9398346	0.06
125.1599350	0.03
128.9149780	0.02
131.2268677	0.81
132.1085358	5.33
136.8609924	0.05
138.9476318	0.08
142.1038666	0.04
144.9224243	0.19
147.0520325	0.17
149.0259094	0.71
154.1987000	0.07
156.0118408	0.30
163.1629333	0.28
164.7989807	0.05
167.0037231	3.87
171.0754547	0.03
173.1019897	0.84
178.9743958	0.14
191.0958099	4.58
192.1095886	0.07
194.2197571	0.05
206.2164459	0.35
209.0567627	15.26
210.1245117	0.27
225.9194336	0.08
227.1662598	1.18
231.0695496	0.01
233.9670105	0.12
237.3657227	0.14
238.1017456	1.17
243.2716980	0.02
244.0097656	0.03
245.4248047	0.07
252.1666565	24.70
256.1485596	0.88
258.1508484	0.68
266.3392334	0.04
268.1237183	0.10
270.2244263	0.97
274.4486694	0.04
276.1421814	4.58
276.7567749	0.02
278.1923218	0.14
286.2814331	0.04
292.2418213	1.52
294.2784729	5.72
298.4477844	0.43
299.2949829	0.08
304.2263184	6.79
305.1799927	0.03
310.1405029	0.43
312.2541504	3.92
322.1975708	23.92
328.0652161	0.63
330.2630615	0.10
336.2342529	0.03
340.1679382	100.00
341.3630981	0.10
349.2463379	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.4128
Annotation	Quillaic acid 3-[galactosyl-(1->2)-glucuronide]
Peak:m/z	Relative Intensity
241.0262146	0.14
251.2445679	0.12
255.2968445	0.54
269.2173462	0.04
289.5481262	0.06
297.2804565	0.03
319.1559143	0.02
337.1618347	1.07
353.3520508	0.01
367.0596924	0.02
374.5696411	0.02
387.3829956	0.06
391.3263550	0.26
395.4166870	0.03
405.0645142	0.03
406.3794556	0.03
407.3759155	0.06
421.1876831	0.02
423.4025879	1.46
424.0452881	0.02
439.4361572	0.10
441.4309692	0.07
451.4916382	0.11
464.2907104	0.03
467.2947388	0.07
477.4105225	0.03
481.3607178	0.03
485.3582153	100.00
499.2001343	0.12
511.4740601	0.03
527.8577271	0.04
535.2551270	0.23
549.3050537	0.03
553.3297729	0.48
562.1184692	0.01
564.4858398	0.06
567.3726196	0.01
571.2972412	0.24
577.2421875	0.10
605.3046265	0.02
609.4324341	0.01
615.6770630	0.02
625.2795410	0.04
643.3019409	0.01
645.3332520	0.03
647.2707520	0.13
653.2706909	0.02
661.4043579	0.05
667.2691650	0.05
681.4856567	0.04
695.4061890	0.07
703.6140137	0.04
716.4628906	0.01
717.1382446	0.03
721.0938110	0.12
725.1796265	0.01
733.6437378	0.03
734.4241333	0.05
748.1368408	0.01
749.5966187	0.33
754.6230469	0.01
755.3064575	0.05
761.4801636	0.03
772.8751221	0.07
775.1943359	0.06
777.3739624	1.47
778.0333862	0.02
785.5841064	0.02
787.1254272	0.05
789.4550781	0.07
795.4492188	0.05
800.9517212	0.03
805.3663330	5.26
806.3283081	0.21
807.0780640	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.163
Annotation	Pelargonin
Peak:m/z	Relative Intensity
197.7711487	0.05
226.1029358	0.08
243.0748901	0.02
247.0556946	0.11
271.0650024	72.51
283.026123	0.04
289.0210571	0.11
296.8481445	0.06
301.2068481	0.02
303.2589111	0.03
317.3809814	0.02
330.8751831	0.07
357.2819214	0.04
359.7897339	0.10
361.0161743	0.08
366.9639893	0.08
396.9453735	0.09
414.050415	0.06
415.0741577	0.20
425.3335571	0.14
427.2209473	0.05
433.1015625	100.00
443.2537842	0.07
558.5383911	0.06
577.31427	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1112
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
126.9654312	2.06
144.2920227	0.01
144.9356384	0.06
162.9640503	0.16
186.9424744	0.07
271.0610046	100.00
271.9820557	0.10
288.967865	0.22
305.5966187	0.02
306.8377686	0.15
397.0101624	0.01
415.0527954	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	855.2227
Annotation	Unknow
Peak:m/z	Relative Intensity
254.8559113	0.05
265.1078491	0.54
267.0770874	0.23
268.9883728	0.19
271.2078247	0.06
272.8898010	0.12
281.1301270	0.40
283.1496582	0.54
285.1317139	0.19
287.5027466	0.05
289.0752869	0.36
291.0732422	1.12
296.8687744	0.19
299.2053528	0.50
301.0257263	4.77
303.2186890	3.09
314.9475098	0.08
344.9920349	0.42
405.4311523	0.04
406.9392090	0.36
421.0765381	1.97
423.1853638	0.29
433.0640259	0.11
439.0286255	6.83
447.2031860	0.08
450.8695679	0.69
453.0694580	0.31
465.1631470	1.27
540.1290894	0.35
547.0206299	0.05
555.2285156	0.75
565.1408691	0.06
573.1155396	1.48
575.2191772	3.29
591.0328369	100.00
591.7625732	0.23
661.4736938	0.19
692.0728149	0.12
693.2888794	0.16
708.8087158	0.12
723.3894653	0.14
726.1129761	0.14
774.9330444	0.09
791.0115356	0.28
808.3593140	0.15
811.2567749	0.07
819.4169922	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	388.1725
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9780121	20.02
130.0721130	1.12
146.1732178	0.17
178.9325867	0.24
196.2143250	0.05
197.1289520	1.26
202.0798340	0.02
215.3376923	0.05
223.1809082	1.59
239.1028137	5.03
241.2027283	60.26
242.3243103	0.06
257.1356812	0.06
259.1216736	52.81
301.2049561	0.12
308.2899170	0.80
326.2195129	0.39
342.0725708	0.44
344.1943970	0.22
352.2723083	20.36
370.2359619	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0828
Annotation	Isoferulic acid 3-O-glucuronide
Peak:m/z	Relative Intensity
110.9439697	2.15
116.1965179	0.20
125.0374603	0.62
127.2884827	0.14
128.9750366	6.55
143.0956726	0.07
161.0542908	1.04
163.1354218	0.53
186.9827271	1.23
205.0413361	60.87
209.0868683	0.11
222.9875488	100.00
231.1384277	0.06
235.2447205	0.16
257.2704163	0.14
281.0109558	0.23
293.3089294	0.10
301.0163574	0.11
306.9609375	0.12
323.0800171	1.57
325.0031128	0.13
333.2317200	0.05
341.3703613	0.05
350.4614868	0.24
351.1718140	3.81
354.2752991	0.56
356.9561768	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1402
Annotation	Gerfelin
Peak:m/z	Relative Intensity
159.0198212	0.29
160.9479523	0.29
163.0077057	0.08
164.0020142	1.04
164.9255371	0.43
175.0748291	0.29
177.0298767	0.09
179.0563812	0.36
184.1133270	0.04
185.3132019	0.13
186.9732361	0.41
187.8708954	0.10
198.8869324	0.14
200.9926758	0.14
202.1656799	0.05
203.0903320	2.13
204.9933929	1.65
209.2050171	0.06
212.0238037	0.08
215.2212067	0.02
217.0848999	0.30
227.1635590	0.73
228.0382843	0.05
229.0113220	0.27
230.0472870	0.05
230.8948364	0.21
241.2683716	0.25
243.8563080	0.09
245.1168671	6.84
246.2692261	0.13
247.1205597	0.33
253.0397644	0.16
255.2526855	0.02
267.0339966	0.14
269.2641602	0.06
271.0855103	15.81
271.7267151	0.08
273.1328735	4.11
283.1274414	1.73
284.8953857	0.05
286.1640015	0.33
287.1242065	1.07
289.0674438	100.00
289.6818237	0.32
298.9326782	1.27
301.1586609	0.11
311.3233032	0.04
312.2394409	0.06
313.2834473	0.06
314.9778442	0.07
328.2908936	1.64
329.0864258	5.91
331.1601562	0.05
339.1810303	0.72
340.9472656	0.81
354.9313354	0.02
363.3723755	0.06
365.4368286	0.04
377.0747070	0.29
381.2396240	3.15
389.5101929	0.04
391.2172852	1.23
393.2452393	0.43
405.2011719	0.07
407.1431274	16.25
409.1887817	6.08
410.3138428	0.37
411.3525391	0.29
417.3063965	1.01
423.1744995	0.14
425.0827637	22.93
425.6915894	0.11
433.2556152	0.41
435.1204224	40.26
436.2291870	0.16
437.1468506	0.15
441.3934326	0.10
449.0308838	0.25
451.2951050	0.09
459.2230835	0.14
467.3848267	0.06
475.3662720	0.24
477.2163086	0.93
499.0908203	0.33
515.1923218	0.05
517.2183228	1.34
525.1818848	1.15
543.1283569	29.60
543.8634644	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.8947754	0.54
98.9108200	0.38
101.0090256	7.41
106.9534454	0.62
112.9871140	20.40
114.8402252	0.40
118.9533463	14.41
125.0213623	2.18
126.9120560	0.19
130.9902649	10.17
143.0292969	22.03
148.8094788	2.93
161.0231323	19.70
178.9842987	100.00
220.8709717	0.14
263.1511230	0.60
280.8079529	2.95
281.4300232	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	570.2324
Annotation	Decarbamoylnovobiocin
Peak:m/z	Relative Intensity
222.0528870	0.02
268.0466919	0.13
270.0526428	0.19
273.4786987	0.02
295.9580078	0.36
313.9224243	0.16
351.6243286	0.01
378.3971558	0.02
379.0988159	0.02
384.8744507	0.02
397.0962524	2.02
439.0509033	0.06
441.0656128	100.00
442.1497192	0.28
480.2249756	0.05
505.8816528	0.03
508.1337280	0.02
524.3580933	0.03
552.3104248	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.0405
Annotation	Datiscetin
Peak:m/z	Relative Intensity
96.6942062	0.02
121.0725555	0.07
123.0857773	0.04
137.0063782	0.46
138.0820618	0.02
147.0072937	0.12
151.1364136	0.04
153.2596588	0.06
163.0486755	0.77
164.9400482	100.00
165.9963837	0.43
178.1018677	0.06
190.9322815	8.39
191.9935150	0.14
198.9475098	0.02
200.1124878	0.08
205.0121155	0.02
209.0468750	0.35
213.0875854	0.17
216.9704285	1.64
217.9757080	0.36
225.9466553	0.02
239.0772705	0.02
241.1427002	5.70
242.1630554	0.04
243.3409424	0.19
257.0259705	0.25
267.2215576	0.81
285.0842896	0.22
286.0481262	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
137.1695862	0.10
143.1100464	0.04
148.9758453	0.08
150.9171906	2.48
152.039566	0.10
153.0240021	0.26
161.1088562	0.19
163.1700134	0.07
165.151825	0.37
168.9909668	0.23
170.1107941	0.09
171.2010803	0.23
172.9192505	0.17
174.0693359	0.23
175.1458435	0.53
176.5137024	0.12
179.0658264	1.07
181.1964722	0.15
184.9802399	0.45
186.8465271	0.50
188.9237366	0.17
190.9914551	0.08
192.6486206	0.45
193.3504944	0.03
193.9892426	0.05
197.0348206	0.14
199.0578613	0.05
200.8646545	0.11
203.1311646	0.09
209.9520569	0.07
211.0978546	0.53
212.9587402	0.33
214.9338531	0.25
217.218811	0.26
219.0510559	0.16
219.8601837	0.04
221.0284424	0.19
222.9320679	0.28
227.0530396	1.31
228.1484985	0.18
228.931427	0.11
231.2800903	0.13
235.2693939	0.06
237.0866394	0.10
239.2058716	0.13
241.229187	0.27
243.0056458	0.69
244.9987793	0.09
251.181366	0.07
253.0306702	0.13
255.1313782	13.20
256.0387268	2.51
257.018158	2.21
258.0798035	0.06
259.0888977	0.23
260.1500244	0.03
265.2815247	0.10
267.2549438	0.04
268.1654053	0.10
269.0726624	2.13
269.8547058	0.13
270.9893494	0.06
275.3045349	0.10
279.20578	0.11
281.1655884	0.39
284.0621948	86.03
285.0484619	100.00
286.0997314	1.27
287.318573	0.16
295.1581421	0.24
297.0030823	0.96
298.0896301	0.21
299.0889893	2.48
300.210144	0.17
303.2751465	0.25
307.052002	0.07
309.2582092	0.06
312.9980469	0.34
314.1422729	0.15
323.2312622	0.15
327.0599365	19.82
328.1650391	1.63
328.9580688	0.07
337.4179077	0.17
338.1229858	0.09
339.0765381	0.22
350.8510437	0.07
357.0652771	3.45
358.2185669	0.23
369.3182373	0.20
379.208374	0.04
387.0678406	0.28
389.1061096	0.10
393.3559875	0.18
401.2153931	0.35
403.1923828	0.07
419.2553406	0.60
428.9420471	0.24
429.5956116	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1044.05
Annotation	Unknow
Peak:m/z	Relative Intensity
295.3135681	0.37
363.5013123	0.53
364.7847595	0.24
375.2518921	0.46
377.3226624	0.70
379.4408569	1.01
380.3822327	0.90
393.4368896	0.50
396.6052246	0.15
408.2480164	0.64
410.4747925	0.33
423.5151978	1.39
426.2505188	0.66
437.2764282	0.24
439.2319946	6.79
440.2719727	0.92
441.6213989	1.04
452.7020264	0.78
456.3670044	0.25
457.3762512	2.90
458.5400696	0.56
463.3708496	0.84
464.9968262	0.82
466.2431641	0.12
479.5458984	1.20
483.3919983	1.88
506.5817871	0.52
527.3274536	0.36
533.7989502	0.11
539.4421387	0.22
540.7442627	0.58
541.4580078	14.78
542.5989990	5.87
551.5233154	1.40
554.5787354	0.89
557.3332520	1.32
557.9860840	0.89
559.3622437	9.01
560.2644043	1.39
560.8881836	0.41
571.3157959	2.34
572.1734619	0.59
579.2389526	0.32
589.6585693	0.22
600.4818115	0.13
613.0965576	0.30
614.3088379	0.63
615.5295410	5.13
616.6195068	1.49
623.2587280	0.22
627.4303589	10.02
628.5999756	5.42
629.3637085	0.38
633.5169678	0.78
641.5354614	0.68
642.1925049	0.18
655.3893433	2.43
656.3731689	2.49
673.5002441	7.65
674.5997925	3.67
679.3731689	0.25
691.4639282	0.97
692.0687256	0.21
699.3165283	6.81
700.3283691	0.85
715.4009399	0.64
717.3474121	34.69
718.3687744	8.60
732.9055786	0.49
733.7988281	0.52
751.8533325	1.12
800.4414062	0.45
817.5937500	2.90
818.3674316	0.68
822.3934326	0.52
828.1439209	0.51
835.4879150	35.71
836.4461670	10.96
837.0495605	0.36
853.5634766	3.66
854.5264893	1.26
877.5078125	0.16
879.4224854	2.88
880.5390625	1.42
897.4368896	5.41
898.4580078	0.99
905.2962646	0.96
923.5104980	0.68
939.4405518	0.53
941.4143066	8.44
942.6475830	2.34
945.5286865	0.26
949.5701904	3.42
950.3688965	2.01
951.0463867	0.15
963.6125488	0.50
967.4776611	59.85
968.5815430	22.63
981.4384766	100.00
982.5019531	35.12
999.5532227	2.40
1000.4967040	1.81
1025.3170170	24.30
1025.9191890	0.63
1026.5283200	7.91
1027.3968510	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	794.4827
Annotation	Unknow
Peak:m/z	Relative Intensity
227.0393372	0.06
236.2866211	0.05
240.9580688	0.12
243.2662506	0.87
244.0889893	0.79
249.4846497	0.38
255.2944946	4.77
256.3435364	3.09
260.7371521	0.22
264.9378662	0.04
269.2757263	0.59
270.1467896	0.22
280.3481445	0.09
287.2375793	3.26
288.2942505	2.97
290.1522827	0.16
291.2246399	0.14
299.3884277	0.10
305.2456055	5.39
306.3012695	2.84
309.0435486	0.12
312.3981934	0.11
323.1202087	1.27
324.2806091	1.65
328.1219788	0.22
329.3083496	0.16
331.4169006	0.20
339.5342407	0.55
341.2171631	2.77
342.2313232	1.47
343.3458862	0.11
359.7004395	0.27
387.4136963	0.05
393.5120239	0.11
413.5584717	0.14
427.5187988	0.13
434.3665161	0.10
435.1698608	0.35
452.3677368	1.43
453.3264160	2.14
460.3034058	0.09
465.3023071	0.06
477.2936401	0.29
478.1192017	0.18
480.4686279	0.24
482.0606079	0.07
497.4398193	0.07
502.4528809	0.26
503.3324585	0.14
521.2135010	0.82
525.4196777	0.15
527.6286621	0.41
536.2373047	0.05
538.3520508	1.14
539.3304443	1.14
540.3696289	0.45
541.7259521	0.24
543.4729614	0.08
562.5279541	0.21
572.5515137	0.11
576.3123169	0.11
577.4697266	0.06
581.3850708	0.58
603.2705688	0.15
606.2147827	0.04
617.1244507	0.07
618.6071777	0.09
619.3580933	0.13
633.2882690	0.18
634.6348267	0.06
635.5567627	0.13
636.2402344	0.08
637.0728149	0.26
637.7711792	0.13
646.3479614	0.39
647.3687134	0.22
650.5966797	0.22
651.5748901	0.07
660.2749634	0.13
661.5409546	0.39
662.2955322	0.29
665.2041626	0.12
677.5338135	0.06
679.6718140	0.15
681.4400635	0.34
689.3120728	0.24
691.6591187	0.07
693.1192627	0.38
701.8519897	0.07
705.2602539	0.35
708.1018677	0.21
709.4270630	0.03
718.3144531	0.40
719.5183716	0.95
720.5786133	0.38
731.0123901	3.78
732.3945923	0.06
733.7911987	0.21
741.3503418	0.41
749.5927124	1.33
751.1356812	0.07
759.5201416	5.53
777.4188843	100.00
778.1213989	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.9764099	0.04
158.9667664	1.89
160.0300293	1.33
198.8641510	0.21
200.0548096	0.32
217.0009308	0.13
229.4057770	0.44
230.1029663	0.27
270.9498291	0.03
271.7714233	0.06
272.9956665	33.16
273.9566956	28.29
356.4591980	0.05
372.9293823	0.13
386.9335938	28.39
387.9729309	100.00
416.9078369	0.26
427.9279480	0.21
443.9978638	0.05
455.4810791	0.10
457.6641541	0.40
458.2737732	0.03
472.1332092	0.05
474.0578003	0.06
474.7128296	0.03
484.0859985	0.06
491.7261658	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1298
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
125.0069351	1.61
137.0173492	1.03
137.9951782	0.02
147.2910156	0.07
149.0265656	0.31
153.0283661	0.10
161.0061951	1.47
165.8273468	0.02
179.0668335	0.07
187.1583862	0.15
188.1268005	0.14
188.9596252	0.03
190.9970093	0.04
215.4023438	0.02
229.1257019	0.67
230.9455109	0.09
239.2099304	0.05
250.8377380	0.02
255.1362915	0.23
269.0639038	0.03
273.0559998	100.00
281.2845459	0.07
287.0325317	0.29
297.1987915	0.68
299.0742188	1.71
314.8159180	0.04
333.8510132	0.01
337.3487549	0.02
375.3961487	0.03
391.3714600	0.05
393.1468201	0.02
417.0314636	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.23
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9404449	0.04
163.1057587	0.04
173.2944794	0.21
175.0357819	0.03
188.9835205	0.21
191.0411224	0.13
203.0502167	0.39
204.8948822	0.03
207.1406097	0.18
224.2328339	0.05
229.2399292	0.05
239.2131653	0.04
245.1027222	0.05
253.0955811	0.05
267.8739624	0.04
268.8204651	0.04
274.8334045	0.09
275.4779663	0.07
287.0512085	0.04
293.1159058	0.36
313.2074280	0.12
320.0778809	0.12
321.4481812	0.26
329.1629639	0.08
337.2356567	0.04
369.3437500	0.06
370.3598633	0.03
387.2169189	2.07
401.2120972	1.25
410.9883423	0.04
413.2003784	0.01
419.1555786	100.00
420.2069702	0.04
427.3075562	0.46
437.2437134	0.06
439.5125732	0.03
441.0180664	0.04
445.4536743	0.09
459.3174438	0.27
461.0769043	34.83
461.7171021	0.13
464.9556274	0.03
483.6271362	0.09
501.1881714	9.70
503.3148804	1.20
505.0319214	0.05
520.3142700	0.03
527.2416382	0.09
544.2201538	0.10
545.3768311	1.14
546.1905518	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2757
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
142.0293884	0.19
145.2333374	0.07
147.0134735	0.02
149.1156006	0.36
151.1393127	0.19
153.1879883	0.12
155.0403137	0.63
157.0387878	0.13
161.1839905	0.25
163.1580963	0.25
169.1258698	0.07
173.1257935	0.42
174.9714661	0.13
179.5156860	0.44
180.9629517	0.05
183.0211182	0.09
186.9262390	0.35
197.9623413	0.62
201.3071747	0.07
210.8004761	0.07
215.9803467	0.20
221.2514954	0.06
239.4530640	0.03
243.3021240	3.42
253.1587524	0.14
261.2920532	4.77
265.3759766	0.03
273.2215881	0.04
277.1272583	0.10
291.0453186	0.06
304.3095398	1.36
307.2874756	0.09
317.1370544	0.71
322.4318237	0.20
330.9515076	0.08
332.7776489	0.24
335.2846069	72.60
335.9403992	0.17
378.3662109	0.41
415.3239441	8.89
429.3697205	0.15
433.2511292	1.34
440.1531677	0.10
458.1883850	100.00
458.9195862	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.1168
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
68.9510117	0.11
70.9348297	0.79
73.0144196	0.03
76.9217911	0.03
78.9434357	2.33
90.9026032	0.38
92.8798676	3.52
95.0678101	0.25
98.8561249	0.05
104.9504242	2.62
106.9961090	2.83
108.9317627	0.15
111.1854706	0.15
113.3108368	0.15
116.7800751	0.04
118.9494019	0.78
120.9738617	22.27
122.8954620	0.11
125.1205597	0.69
128.9945221	0.40
130.9755402	81.31
132.9670715	0.18
135.0740814	2.33
138.9721832	1.15
141.0358429	0.37
143.0076904	0.10
144.9876404	13.43
147.0387573	6.36
148.9672546	19.08
149.5945282	0.10
151.0116119	0.37
153.0355072	4.83
155.1108704	0.30
161.0538177	0.03
163.0259094	17.09
165.0808258	15.50
167.0575714	1.71
172.9721375	1.79
176.9723206	0.45
179.0140076	0.11
181.0850983	0.79
191.0211639	100.00
192.0196228	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.3192
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9214325	0.02
285.1998901	0.06
310.2885742	0.12
319.2083740	0.03
367.2314453	0.01
392.2615967	0.01
413.4959717	0.01
425.8898926	0.02
429.5136719	0.01
432.4261475	0.01
434.1268921	0.04
465.1929321	0.03
475.2817383	0.07
475.9492188	0.04
508.4885254	0.04
517.3978882	0.05
518.4822388	0.04
532.2017822	0.05
543.9588623	0.02
549.3187866	0.04
564.5018921	0.01
571.4143677	0.02
592.4048462	0.02
594.3129883	0.02
595.4923706	0.02
598.0700684	0.03
611.3634644	0.10
612.3720703	0.08
626.1995850	0.01
675.4810181	0.04
676.3070679	0.10
677.7058105	0.10
683.4464722	0.02
686.2990112	0.05
694.5082397	0.01
697.1549683	0.01
702.4420166	0.13
708.9435425	0.01
710.2157593	0.02
712.4129639	0.01
718.4584351	0.01
720.1279907	0.24
726.5057983	0.02
733.5476685	0.03
734.5850220	0.02
735.9852295	0.03
744.2111206	0.24
745.3098755	0.02
761.0067749	0.16
761.7026978	0.09
762.3486938	2.16
764.4619141	0.02
765.1488647	0.05
765.8419800	0.02
766.5142212	0.01
769.2595215	0.01
770.5487671	0.10
776.5401611	0.09
778.3130493	0.19
788.3192139	0.31
794.3632812	0.17
802.0287476	0.07
806.2420654	100.00
806.9392700	0.26
808.5197144	0.03
810.2363281	0.12
815.8233643	0.07
820.2127686	0.40
820.8777466	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	233.1125
Annotation	N6-Acetyl-LL-2,6-diaminoheptanedioate
Peak:m/z	Relative Intensity
83.9766388	0.10
85.8318024	0.11
89.9062119	0.05
103.9045868	100.00
115.8451080	0.02
123.9538879	0.10
129.9742584	3.71
133.8712616	0.04
144.0384369	0.31
146.9770355	0.09
148.0953369	1.27
163.3697968	0.05
170.1123199	5.98
185.2177582	0.05
187.0192871	3.04
191.8236542	0.07
195.8607178	0.16
196.9438629	0.60
198.3470764	0.10
200.9907379	0.11
202.2994843	0.05
205.2541962	0.12
215.1139526	8.58
216.0578766	44.29
223.8028107	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1111
Annotation	Genistin
Peak:m/z	Relative Intensity
126.9999619	2.47
144.8318329	0.08
162.94104	0.17
225.9270325	0.01
271.0512695	100.00
271.6748657	0.24
286.2915649	0.04
288.679718	0.18
307.0562439	0.26
397.0915222	0.10
415.4225464	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1242.5935
Annotation	Unknow
Peak:m/z	Relative Intensity
425.1260376	1.17
437.3526611	0.24
465.4216919	0.42
481.2077637	0.64
498.8854980	0.80
527.3317871	0.87
533.6948853	0.21
569.5302734	1.22
588.3186035	0.32
589.7083740	0.14
637.4517822	1.50
655.5281982	0.37
656.5559082	1.15
657.6342773	1.69
659.7189941	0.50
684.4374390	0.43
704.5196533	0.45
727.4351196	0.52
744.4296265	0.90
745.2026367	1.11
745.8058472	0.48
746.4324951	0.30
749.4774170	11.08
750.6448975	0.76
751.3094482	2.11
753.5983276	0.86
790.0794678	0.46
799.7890625	0.24
806.2256470	0.73
808.5631714	0.31
817.3883667	8.24
818.4672852	5.53
819.4117432	3.51
820.5506592	2.00
831.1498413	2.23
835.5534668	0.30
845.3560791	2.23
846.5726318	2.02
847.4118652	1.89
849.5974121	0.17
863.1390381	1.37
863.8287354	1.15
864.8038330	2.10
865.5479736	0.78
866.4017334	0.72
881.3890381	0.45
882.2480469	1.77
883.2545166	2.60
889.2915039	19.58
890.3211670	15.05
891.4870605	1.35
892.4583740	2.20
907.3937988	30.65
908.3815918	18.03
909.4600830	7.21
910.3360596	4.13
927.4517822	1.59
928.3515625	1.32
929.7902832	0.44
930.5371094	0.37
940.8052979	0.43
972.5316162	0.35
992.3773193	1.40
1007.5150150	1.95
1008.6137700	1.20
1009.4112550	0.32
1010.5218510	2.02
1025.4213870	14.75
1026.4516600	16.40
1027.4658200	5.08
1028.2969970	3.57
1043.1674800	3.94
1044.3463130	1.10
1045.6014400	0.76
1071.3245850	1.01
1072.6573490	0.71
1087.4039310	4.54
1088.6156010	2.38
1089.4819340	2.01
1090.4487300	2.44
1153.4365230	0.60
1158.4311520	0.97
1171.3839110	48.82
1172.3806150	31.45
1173.3437500	10.08
1189.6186520	2.24
1190.3863530	0.35
1191.1585690	1.40
1215.3662110	100.00
1216.3929440	83.08
1217.3647460	10.12
1218.0288090	0.47
1232.8529050	4.58
1233.4702150	32.60
1234.3845210	5.34
1235.7255860	1.80
1251.4458010	1.60
1252.3385010	4.28
1253.3181150	0.96
1765.6158450	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.2228
Annotation	11-HpODE
Peak:m/z	Relative Intensity
98.7773895	0.03
100.9385529	0.14
107.1230621	0.05
108.9693298	0.08
112.9472046	0.39
126.8988419	0.03
134.9243469	0.09
137.0646973	0.18
138.2274475	0.03
140.8007812	0.08
167.1982422	0.11
171.1722870	0.82
177.3874512	0.36
183.0324402	0.34
191.3378906	0.32
193.4113464	0.07
195.5370789	0.07
198.9735718	0.04
201.1414185	1.33
203.2288513	0.05
205.2080078	0.42
207.3159180	0.64
209.1921082	0.63
217.2603149	0.15
219.2546387	0.29
221.2151489	0.53
223.1397400	91.49
224.2382202	0.16
225.1907043	0.37
226.1006165	0.05
231.2600098	2.46
233.3425903	0.07
235.1916504	25.27
236.2558289	0.27
237.1953125	1.20
238.2362061	0.07
244.2147827	0.20
247.1630249	0.23
249.3149109	1.22
251.2839661	0.11
253.1651611	9.01
254.1824951	0.16
255.5226746	0.26
257.2058716	0.12
263.2255554	0.08
265.3108521	0.58
267.3078613	0.09
273.2274475	0.29
275.2500000	39.05
276.2081604	0.11
288.9491577	0.11
291.2305908	3.10
293.2544861	100.00
293.8565063	0.40
294.4742432	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.2092
Annotation	Unknow
Peak:m/z	Relative Intensity
243.2823334	0.26
245.1435852	1.10
247.0675354	0.28
253.1896820	0.36
255.1843567	0.44
256.1591187	0.23
257.2079468	0.62
259.2013855	1.27
260.9961548	0.29
268.1394653	0.08
269.0722351	0.46
271.1648865	14.11
273.1747437	1.88
275.1206665	0.31
279.0266724	0.93
282.1658020	0.29
283.0322571	0.55
284.8471069	0.28
287.1410522	2.12
289.1847229	22.42
295.2958069	0.56
299.0524902	1.10
300.2081604	0.38
300.9419861	0.92
302.0205078	0.10
302.9368896	0.26
305.0256958	0.73
307.1452026	0.18
309.2465820	0.19
310.2058105	0.99
311.1843567	1.26
313.2715454	1.14
318.8915100	1.14
321.3430786	0.14
322.1112976	0.07
323.1405640	1.17
327.1823730	0.30
328.0438232	0.47
329.1089478	0.78
330.7951660	0.11
333.2284546	0.10
337.1098022	7.09
340.2969055	0.36
341.3770752	0.15
341.9997253	0.09
345.1992493	0.64
347.2423401	0.10
349.3001709	0.08
351.2513123	6.17
355.0905151	0.19
363.0346680	0.69
365.0734253	0.28
366.9522705	1.73
371.1465149	0.13
373.3263550	0.51
375.0816650	0.73
377.0778198	0.28
379.1883545	3.83
381.2520752	0.87
383.1637573	0.29
387.2552490	0.18
389.1180420	2.17
391.2630005	2.21
392.0538330	0.11
393.2244263	0.67
397.1317139	4.65
399.6536865	0.18
401.3819580	0.32
403.1057129	0.20
404.8131104	0.55
405.4513550	0.45
407.0978394	13.26
409.1711426	6.81
411.2462158	0.19
415.2980957	0.26
417.2583008	6.44
418.2319336	0.28
419.1401978	4.60
421.0001221	0.21
425.0561523	3.67
433.1325684	1.83
435.2243652	13.26
436.1748657	2.39
437.1796875	8.47
438.8720703	0.34
446.1549683	0.21
447.3509521	0.19
449.0848999	0.34
451.0455322	1.09
452.2424316	0.13
459.5532227	0.10
475.1863403	0.12
477.1350708	0.39
481.1957397	39.38
484.1707153	0.18
485.3926392	0.07
495.4484863	0.65
497.2731934	0.09
499.2406006	0.54
501.3221436	0.97
503.1632080	0.70
509.1872559	0.21
513.4406738	0.44
517.2697754	0.88
519.2753906	1.04
521.3225098	1.25
525.1304321	5.49
527.0996094	1.85
537.2892456	0.15
541.4630737	0.67
543.1470337	100.00
543.9415894	0.81
545.2147827	0.83
547.4263306	0.13
553.1878052	4.86
555.2861328	4.02
556.1791382	0.35
559.1826172	13.67
561.1893311	68.98
561.8499756	0.36
569.1899414	0.09
571.2474976	6.30
573.1746216	38.19
582.4591675	0.13
584.9085693	0.06
587.0190430	0.43
593.4390869	0.54
597.1499634	0.32
600.1787720	0.82
609.2017822	0.13
611.4408569	0.04
617.0844727	1.05
620.3192139	1.08
635.1498413	1.10
636.8807983	0.36
637.5496216	0.09
643.0583496	0.12
645.1071167	0.08
653.2243042	4.31
657.2492065	0.22
661.2714844	1.98
663.2080688	4.13
665.2136841	0.23
667.3168335	0.23
669.3208618	0.51
670.9963989	1.65
679.1057739	19.81
681.1802368	8.60
682.6943359	0.11
685.1141968	0.30
689.2586670	2.25
691.3823242	0.28
693.4412842	0.09
697.1106567	5.78
699.1656494	0.21
701.8807373	0.13
705.2866821	0.33
707.1812744	33.59
717.1282349	0.10
724.2749023	0.19
725.1221313	0.09
726.3865356	0.08
731.2250977	0.43
738.2884521	0.29
739.0971680	0.07
747.5099487	0.75
771.2039185	0.57
772.9108276	0.26
788.3867798	0.39
789.2499390	2.19
796.3682251	0.25
797.3576660	0.21
801.2806396	0.10
815.1504517	24.08
816.0557251	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.24
Annotation	Cucurbitoside J
Peak:m/z	Relative Intensity
163.0570831	2.04
167.2554932	0.28
169.2881775	0.71
171.0567627	0.59
173.0398407	0.74
179.1089478	0.54
185.1473083	0.46
187.0591431	0.80
189.0649414	0.34
191.0725250	6.59
197.8104553	0.07
201.1490173	0.65
203.0684509	0.32
204.1975250	0.09
209.0522766	19.51
213.0552063	1.06
215.0737000	1.24
216.0867767	0.16
226.8626099	0.28
229.1051025	0.35
231.0508728	15.84
239.0557861	0.18
243.1651306	9.48
243.9861450	0.74
245.0413971	0.47
246.6911316	0.15
248.1195068	0.19
253.1587830	0.19
255.0967712	6.77
256.5031738	0.55
257.2135620	1.20
258.1571655	0.20
261.1555786	5.69
265.0965881	0.30
267.0829468	0.33
269.1638184	1.98
271.3946838	0.29
273.0417480	31.27
275.0617676	71.04
275.7282410	0.56
278.9361877	0.14
281.2927856	0.21
285.1473389	22.60
287.1190491	15.62
297.1037903	0.56
299.2168884	3.15
302.8871460	0.08
309.3028564	0.36
315.2158203	0.54
317.1176758	1.73
319.6897583	0.08
321.9002075	0.19
323.2034912	0.23
335.3905640	0.08
341.3245850	0.31
347.4042969	0.27
361.2340698	0.59
364.2869263	0.17
367.0718384	0.10
368.3410034	0.16
370.9761963	8.08
375.4053345	0.44
379.2193604	14.81
385.2937622	3.61
390.6094360	0.26
391.2749023	1.83
393.1041260	80.83
394.2022705	0.32
395.1427002	0.11
403.1947632	4.42
404.5001221	0.49
405.1923218	7.07
406.2935181	0.56
409.4552002	0.40
411.0335693	100.00
411.6704712	0.25
412.3034668	0.28
418.5878296	0.19
420.0581665	0.51
421.1732788	16.67
423.0176392	20.84
425.2945557	0.55
433.4766846	0.11
435.2747192	0.30
442.2634888	0.57
459.3718872	0.14
485.2424927	0.59
489.0753784	0.22
502.4147339	1.49
503.3494263	1.74
506.1987915	0.17
511.1159058	2.50
513.1806030	0.45
515.1531372	0.12
517.1520386	0.31
529.0530396	10.17
529.9231567	1.00
537.5803833	0.16
547.1962280	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.2469
Annotation	Unknow
Peak:m/z	Relative Intensity
203.0827026	0.07
205.1611633	0.06
217.0848083	0.13
222.7624817	0.04
253.4072876	0.18
259.0920715	0.23
270.9374390	0.29
286.2482605	0.08
289.2612610	0.76
306.1309204	0.33
307.3157349	0.05
314.8825073	0.11
324.2412720	1.49
325.0000610	0.07
327.2784729	0.05
328.3428345	0.39
329.4031067	0.09
358.3749390	0.12
362.4085083	0.04
378.1767273	0.05
379.4020996	0.13
407.3140259	0.17
424.7923889	0.09
427.3588257	0.08
428.0812073	0.24
450.2543640	0.09
451.5302429	0.25
463.4873962	100.00
464.4140930	0.40
465.6510315	0.27
468.4649048	1.62
469.5475159	0.54
476.9298401	0.18
747.9686279	0.17
748.6237183	0.33
765.5233154	1.04
766.5624390	0.52
811.6930542	0.13
927.4399414	0.80
928.7602539	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	923.4954
Annotation	Unknow
Peak:m/z	Relative Intensity
257.2786255	0.32
259.2418213	0.14
261.6325378	0.30
262.3554077	0.35
267.1616211	0.27
269.2330933	1.84
271.1630249	0.21
274.6457825	0.30
281.1358643	1.38
283.2371216	0.67
285.3581543	0.64
295.4235840	0.92
296.1943359	0.11
297.2292480	3.07
299.2281494	0.14
309.1633301	0.19
313.1544800	0.30
319.9266052	0.10
320.9190674	0.07
323.1518860	0.20
325.1247253	0.65
329.4197998	0.45
331.3031311	0.13
337.2311096	0.44
338.5883789	0.08
341.4799805	0.66
345.5752563	0.26
347.1860962	0.21
349.4613953	0.40
352.9550781	0.21
355.5592651	0.11
359.0200195	0.21
363.3193970	0.36
365.2916260	5.73
367.7749023	0.12
371.2214355	0.19
377.3547363	0.67
379.3098755	0.22
385.3211060	0.47
387.1950684	0.33
393.3586426	0.57
394.7938232	0.42
395.5150757	0.55
403.4327393	1.13
405.4299316	28.41
407.1381226	0.73
417.3034058	0.25
419.4296875	0.54
422.8057251	6.42
423.4196167	100.00
427.5187988	0.13
429.3218384	0.26
433.5764771	0.53
435.4193726	0.15
441.2206421	6.29
451.5754395	0.20
465.0288696	0.39
465.6962280	0.10
471.3266602	0.30
483.1868286	0.55
504.8743286	0.17
508.1431274	0.30
509.0720215	1.07
535.2785034	0.13
537.1721802	0.96
549.0030518	8.06
549.9542847	0.13
552.9530640	0.18
563.4972534	0.83
566.9374390	62.71
567.7516479	0.06
579.4458618	0.14
581.2919312	72.76
582.0234985	0.48
584.0023804	0.75
584.9183960	6.39
585.5800781	0.20
598.8118896	3.77
599.4382935	18.22
617.0791626	0.80
618.5534058	0.40
619.3836060	0.36
625.8071289	0.26
662.5142212	0.55
679.3258057	0.88
707.2419434	0.12
724.5488892	7.87
725.1934814	77.45
729.0567017	0.11
742.5428467	4.54
743.1622925	17.11
747.0127563	0.67
760.8893433	2.78
761.5938721	0.34
779.0090942	0.18
820.5008545	0.09
905.2102661	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.0768
Annotation	Methysticin
Peak:m/z	Relative Intensity
80.1254120	0.06
80.8656769	0.82
85.0850220	0.08
92.9738617	1.70
95.1160736	0.34
97.0231018	2.65
99.2273865	0.08
105.0707397	0.27
106.9639893	0.20
107.9725800	0.02
119.0094299	0.21
121.1357269	0.09
122.0554581	0.45
122.9733047	4.78
125.0092087	0.99
133.0141602	1.60
133.9641418	0.13
135.0808716	1.92
137.0029144	4.15
138.0273743	0.64
138.9735107	4.53
142.9106445	0.12
145.0724792	0.37
146.0020752	0.04
147.0994263	0.29
149.2406311	0.77
151.0939331	0.10
158.1099396	0.10
159.3048096	0.04
161.0785522	0.50
164.0264587	0.95
165.4182434	0.99
166.0536194	3.31
167.0703430	3.86
169.1021576	0.09
171.1099396	3.20
175.2239838	0.48
178.9561768	6.08
185.0685730	0.79
185.9763489	2.23
187.0463715	33.44
189.0857544	35.64
200.1063232	0.06
201.1386719	1.40
203.0361633	0.04
205.0698547	2.35
209.1166992	0.15
211.1560669	1.69
213.1351929	0.15
214.0267639	2.39
215.0736694	9.05
216.2497253	0.08
227.1602173	0.24
229.0729980	100.00
231.0716248	18.47
241.3683472	0.10
243.3664551	0.03
245.3001709	0.11
253.0551758	0.07
255.1327515	30.79
256.0764771	0.30
273.1043091	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2138
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.9647827	0.68
202.7713318	0.09
221.098114	5.31
262.9855652	0.24
279.2948303	0.10
279.9725342	0.18
281.0767822	1.33
292.8602905	0.16
305.1551514	1.49
310.3277588	0.15
311.2070923	0.07
323.1015015	3.95
324.9283752	0.51
326.0274048	0.16
341.0276489	22.66
383.1298218	100.00
383.8641968	0.12
399.2365112	0.30
407.1254272	0.41
411.385376	0.11
412.6572266	2.43
425.0598145	1.42
442.99646	12.30
467.2403564	0.12
485.1947021	22.30
503.0515747	2.89
545.3126831	1.29
618.5960083	0.14
647.3259888	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.143
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
129.0506134	0.02
136.0397644	0.02
138.9104156	9.52
142.8913574	0.02
146.9966125	0.05
149.0193024	3.89
151.0860748	0.05
162.9825439	0.41
168.9511261	0.30
181.1257935	0.14
187.3550415	0.11
192.9342041	0.05
203.0193024	0.05
204.9494171	0.43
208.1658478	0.05
209.1208649	0.03
217.2369080	0.02
225.9678802	0.01
229.0718079	0.10
233.0093689	0.03
235.1861267	0.25
237.3819122	0.12
241.1161194	0.08
247.0526733	0.23
248.1107483	0.11
254.0774231	0.06
257.0559998	2.45
259.2195435	0.12
265.1085815	0.91
265.9719238	0.12
269.8921509	0.05
273.0231323	0.02
275.0650024	100.00
275.6763306	0.22
276.9649963	0.21
281.1111755	0.13
283.1322021	4.13
283.9907837	0.04
285.2153931	0.13
287.1651001	0.32
288.5802612	0.12
289.2673950	0.01
291.4919739	0.05
294.7052002	0.21
295.3625488	0.04
299.0112000	2.11
301.0604858	16.08
303.1593323	0.12
304.0292969	0.02
305.1179199	0.19
306.1926270	0.02
307.0350342	0.08
310.9789734	0.14
312.9057007	0.23
316.1592407	0.30
317.0797119	1.96
318.2410583	0.31
323.2326050	0.18
333.9747009	0.02
340.9995117	0.48
353.3388062	0.09
359.1253052	0.05
365.2159424	0.36
369.4231873	0.02
372.8855896	0.02
383.2080994	1.03
391.3306885	0.17
392.1524658	0.06
401.1055603	4.78
409.1264038	0.03
417.1828918	0.05
418.4860229	1.44
419.2245178	4.46
420.1027527	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2917
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
135.1681519	0.07
154.8914337	0.15
180.0526581	0.01
191.3774719	0.02
197.9738159	0.03
199.2214508	0.02
203.4731445	0.02
215.9810181	0.07
217.2238464	0.01
233.1455078	0.02
245.2580566	0.07
253.2412109	0.02
262.9815369	0.05
263.6259155	0.05
306.4519653	0.19
319.2753601	0.01
324.3565674	0.02
337.2855835	100.00
337.9473267	0.21
395.3650208	0.02
416.9857483	0.26
434.5821228	0.04
435.2355652	0.02
442.1972046	0.02
460.2068787	5.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	504.2789
Annotation	Mycalamide A
Peak:m/z	Relative Intensity
167.0432587	0.14
183.8155212	0.10
193.1130676	1.31
211.1607666	0.68
223.1817322	0.11
244.9519958	0.18
254.3095703	2.07
255.0652161	1.62
256.0617371	4.23
265.3794556	0.42
278.2283630	0.20
279.0209961	0.14
294.1656494	0.18
299.3867188	0.14
300.3886108	0.08
306.2285461	1.50
307.6496277	0.06
316.1506653	0.05
324.2568359	15.08
342.1950073	100.00
349.1385193	0.27
353.1876221	0.07
356.2641602	0.18
357.2524414	0.45
358.0552979	0.13
360.4642029	0.08
363.7783813	0.05
366.9930420	0.21
373.5742798	0.17
375.2106934	0.58
378.0585938	0.34
387.2337952	0.47
418.8006287	0.11
458.0004272	0.09
459.1863708	0.34
463.0425110	0.04
475.6776733	0.15
485.0392761	0.11
486.1954651	2.20
487.1561890	1.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.166
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.9713745	1.03
118.9558792	1.41
128.9285431	0.23
130.9281921	0.27
142.8821716	0.83
145.0458374	0.38
145.8466797	0.12
147.1533203	0.70
148.9894104	0.16
159.0163727	0.05
161.1244812	0.64
163.0173340	100.00
164.1759949	1.40
175.0438232	0.13
178.9170227	0.38
181.0021057	0.64
189.0541687	0.17
191.0708618	0.10
191.7632599	0.45
193.1062012	0.55
207.1439819	2.14
209.1724548	3.33
221.0902405	0.08
225.1572266	1.31
259.2279358	0.05
280.1244812	0.06
289.1964111	0.17
321.3459778	0.08
326.9555054	0.07
341.1888428	0.64
343.1842651	0.24
369.2409363	12.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.0793
Annotation	gamma-Glutamyl-S-methylcysteine sulfoxide
Peak:m/z	Relative Intensity
80.9183884	0.01
87.9139557	0.80
106.1549835	0.02
119.1433029	0.02
129.8962708	0.34
137.8957214	0.26
149.0357361	0.02
150.7299652	0.02
151.9075470	4.82
173.4358215	0.03
191.2353058	0.08
193.2922363	0.05
199.0646057	0.14
199.9714050	0.21
200.6084290	0.08
217.0548706	100.00
217.9366455	0.03
235.1322937	0.14
239.3553467	0.02
249.7327271	0.01
263.1205444	0.47
272.0495300	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1733
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
228.5187073	0.54
242.9098053	0.08
249.1823730	0.18
255.0602112	0.28
257.1213379	0.07
274.2290039	0.04
285.0354919	0.15
289.2408447	0.20
301.0782471	0.15
302.1339417	0.84
317.1906128	100.00
325.3868408	0.07
332.3880005	0.31
359.1637573	0.35
364.3386230	0.18
376.7492676	0.16
380.3775635	0.25
385.2690430	0.09
395.2065430	0.13
397.3002930	0.18
399.2453613	0.18
401.0388184	0.07
441.2278442	0.44
445.1881104	0.07
451.0461426	0.04
461.2422485	1.08
462.8653564	1.07
463.5948486	0.03
478.9279175	17.36
499.3710938	0.05
503.2156372	0.19
520.7578735	0.43
534.3673096	0.11
537.2842407	0.27
542.1940308	0.31
547.1359253	0.30
551.2329712	0.29
558.9951782	0.14
571.0817261	0.14
574.4635620	0.07
581.1527710	0.09
589.1557007	0.83
595.3485718	0.06
607.2849731	1.08
608.3718872	0.08
612.9586792	0.17
615.4456177	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	987.4786
Annotation	Ageratoside B1
Peak:m/z	Relative Intensity
281.1892395	0.17
325.2378235	0.35
379.5657654	0.43
383.1285400	0.29
411.4259033	1.36
423.3802795	0.78
425.7171631	0.38
439.4931641	0.38
441.3735352	7.33
451.2124023	0.22
457.5741882	1.48
459.5268250	2.74
460.5338135	0.15
469.4263611	16.22
471.4724121	0.16
473.5556641	0.52
481.3855591	0.12
483.8082581	0.17
485.3636780	1.56
487.4564819	8.04
499.2056274	5.79
501.5806580	1.57
507.2000732	0.23
515.3521729	0.27
517.6312256	0.22
527.4176025	12.60
528.0914307	0.04
529.7957764	0.68
537.2744751	0.22
539.1801758	0.11
541.4234009	0.22
544.2697754	0.23
555.4777222	44.16
569.6112671	1.07
570.9840088	0.44
573.4208984	7.68
574.3624268	0.50
583.5490723	0.40
599.6127930	0.51
601.4813232	15.76
602.3284302	0.48
617.3920898	4.57
619.7915649	1.40
627.3583984	11.92
628.1028442	0.22
645.3890381	43.61
663.6180420	2.10
691.6809692	0.28
692.8897705	0.18
695.5518188	0.06
722.3869629	0.19
735.2902832	0.94
737.6240845	0.25
745.4515991	1.14
763.3933105	12.44
764.3874512	0.60
781.5194092	3.37
807.3334961	1.10
823.2216797	0.42
825.4581299	13.47
826.4149170	0.43
853.6881104	0.74
855.4163818	0.24
857.3836670	8.42
865.4378662	0.40
881.6152344	0.95
899.2772217	0.12
907.6201172	2.29
911.6107178	0.29
925.4718018	100.00
926.3826904	0.18
927.3070068	0.21
940.1704102	1.10
940.8096924	0.82
943.4400635	7.56
944.3923340	0.18
951.8724365	0.39
955.0488281	0.23
969.4279785	35.02
970.3326416	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1522
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
161.0230103	0.39
162.9954834	0.26
165.0307007	2.56
169.1418304	0.16
171.1654968	0.18
179.0112305	0.65
181.1759186	0.15
183.1001129	0.10
184.9149933	1.95
186.9530945	0.18
189.0801849	1.94
191.0604401	0.13
193.0183258	0.36
196.8848572	0.33
199.0750275	0.46
203.0942383	0.16
206.9653320	0.09
208.9023438	0.40
213.0700226	4.66
214.9198151	1.48
217.3319550	0.14
227.2237244	1.65
229.1105347	0.33
231.1389465	38.81
233.0748901	0.14
238.8976593	0.17
243.1257019	10.52
244.5322266	0.30
245.1967010	1.44
248.8962402	0.04
255.1744080	9.47
257.2208252	1.36
267.1370239	2.60
269.1116943	0.23
271.1300354	0.12
273.0797729	53.16
275.0588379	12.08
279.1607666	0.25
283.5155640	0.18
285.0827026	26.13
287.1507568	6.87
291.1225586	100.00
297.1964111	0.26
299.1278076	1.85
300.9929199	0.21
303.1570435	10.97
310.9462280	0.13
315.1390381	1.73
325.2634277	0.37
331.3225098	0.24
333.1691895	1.26
365.5187378	0.05
373.2232666	0.22
377.1543579	0.12
393.1112061	80.54
395.2525635	20.52
401.1685791	0.57
405.2008057	5.03
407.2503662	1.21
409.1522217	9.00
411.0328979	94.90
411.6861572	0.51
419.2337036	4.51
421.3265991	0.91
423.1526489	2.17
427.1224976	32.00
433.3354492	0.16
437.0609131	7.10
439.1639404	1.33
448.3646851	0.22
451.3218994	0.74
525.3645630	0.16
527.1568604	2.88
545.0155640	8.87
545.6859741	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2915
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
179.9760132	0.06
184.0292664	0.05
185.1118774	0.03
198.1155701	0.06
216.1646729	0.03
239.3114929	0.01
253.3218079	0.02
273.7998047	0.01
282.3795776	0.40
313.2517700	100.00
334.8364258	0.04
393.1575623	0.04
394.3420715	0.02
408.5199585	0.02
436.1605225	3.67
436.8374939	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.2408
Annotation	Homoneoharringtonine
Peak:m/z	Relative Intensity
157.8904572	0.39
174.2599487	0.01
175.2083740	0.27
175.9830627	2.24
191.0782166	0.02
193.1208191	1.93
194.0031128	0.19
196.2503052	0.03
206.9289551	0.04
209.0791626	0.01
211.0372772	0.13
224.8712158	0.06
229.0830841	0.01
242.9470215	0.01
251.2257080	0.02
252.2784119	0.02
258.8801575	0.02
261.2777405	0.17
262.5064087	0.04
269.2127686	0.04
274.2843018	0.02
279.2237549	0.06
285.9644470	0.11
287.2700195	0.04
288.0667419	0.04
296.1765747	0.12
304.1391602	0.49
310.3034668	0.02
314.2443237	0.61
324.1279297	0.02
325.0490723	0.02
350.1198730	0.07
368.1688843	0.45
370.3104858	0.04
371.1959229	0.02
373.0997314	0.02
385.6727295	0.29
386.3290405	0.36
388.4191284	0.02
401.3558350	0.10
403.2385864	4.59
404.1716309	7.43
404.7886353	0.08
407.2058105	0.04
410.4345703	0.01
415.1972046	0.02
419.2836304	0.14
421.2129517	100.00
422.6552734	0.03
425.4888306	0.03
432.0888062	0.09
433.8477783	0.01
440.2850342	0.04
443.2909546	0.07
461.3661499	4.81
463.7092896	0.02
468.9705811	0.01
478.3692627	0.08
487.0722046	0.11
489.8871460	0.01
496.1768188	0.10
505.3909912	0.06
514.3917847	0.06
518.8850708	0.08
532.2425537	3.90
533.0154419	0.15
541.0437622	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	388.1726
Annotation	Unknow
Peak:m/z	Relative Intensity
112.2114868	0.07
128.0074158	20.79
130.1200104	0.86
149.9129944	0.15
190.9844666	0.10
192.9518280	0.55
193.9741211	0.22
197.1990662	0.94
210.3265381	0.19
213.1994781	0.03
220.2992554	0.03
223.1040955	2.68
224.0786133	0.22
238.1385193	0.23
239.1342163	5.62
241.1634521	61.59
253.2110291	0.05
259.1222229	56.62
271.5285034	0.08
308.2356567	2.21
326.4263306	0.53
341.0989990	0.18
342.1816406	0.51
344.2130127	0.10
352.2544861	24.92
360.2614746	0.09
370.1753235	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.2795
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
168.7867584	0.06
198.0466309	1.09
225.1882019	0.16
244.0543213	4.28
244.6563110	0.09
261.1542358	100.00
263.1916809	0.38
358.0899658	0.09
359.4603271	0.48
389.0733643	0.16
390.6119995	0.08
392.2744141	0.36
503.3654175	0.32
521.1110229	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.2892
Annotation	Unknow
Peak:m/z	Relative Intensity
121.1407623	0.11
122.9082794	0.16
125.1144333	0.18
126.9875870	5.06
133.0022583	0.12
134.8179932	0.12
136.8641052	0.12
138.9553223	0.20
140.0594940	0.08
143.8094177	0.21
144.9480896	2.02
147.0201874	0.15
149.1409454	0.06
150.4278870	0.04
151.1210938	0.12
157.1400757	0.07
163.0410767	0.08
165.2496033	0.28
168.9809875	0.18
172.8598480	0.10
175.2852783	0.05
177.2410583	0.18
179.0994568	0.08
183.9337769	0.77
185.1839600	0.04
190.7809601	0.07
201.3567505	0.10
205.1385193	0.12
207.1461182	0.03
217.1340179	0.13
221.0775909	0.09
235.0126343	0.22
237.2572021	5.42
239.0942993	22.08
246.3007812	0.04
249.0831604	0.04
251.0668945	0.14
252.9285583	0.39
256.5412292	0.22
257.2625427	0.35
259.2451172	0.08
264.0682068	0.14
275.4682312	0.11
277.3169861	0.08
279.1394348	0.35
284.5025330	0.04
285.1447754	0.04
293.2947998	0.90
297.7265625	0.23
299.5469666	0.06
301.3915405	0.02
304.7534485	0.12
305.9797974	0.11
307.3414001	1.11
312.8817749	0.21
317.2546997	1.79
327.3347778	0.09
334.4297791	9.01
335.1612549	100.00
335.8629761	0.53
338.4582214	0.07
341.3894043	0.26
342.5104065	0.18
345.3437500	0.18
346.1400757	0.21
352.2080078	0.15
352.9653931	0.04
359.0497437	0.07
361.1117859	0.07
363.0827942	0.03
364.7852478	1.53
365.4709473	0.15
366.2626343	0.08
370.3746948	0.06
374.4818420	0.11
383.0794983	6.24
384.1802979	0.09
391.6971436	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1083.5369
Annotation	Ciwujianoside D2
Peak:m/z	Relative Intensity
380.4461975	0.43
409.3215027	0.51
437.3300171	0.74
438.5613403	0.24
442.1452332	1.69
457.3253174	3.28
458.3698120	0.38
463.3397827	1.76
482.3369141	0.57
499.1621094	1.08
526.6010742	0.63
551.3234863	0.35
552.4067383	1.35
563.3529053	2.64
564.4588013	3.11
566.4471436	0.57
581.6068115	0.66
582.4918213	0.52
583.5358887	1.72
584.4853516	3.00
606.4754028	0.62
622.2318115	1.67
651.4817505	15.35
652.4395752	50.65
660.4966431	0.31
679.3012695	1.56
680.3876953	1.25
698.7570801	0.61
723.2742920	7.25
724.2960205	22.50
734.5568848	6.34
736.3991089	0.89
741.4307251	8.05
742.3467407	32.17
751.6708984	1.01
752.4108276	0.59
759.4409180	3.39
760.5250244	4.09
818.6785889	1.16
822.3741455	2.38
860.2539062	1.80
878.2291260	0.75
895.8275146	11.92
896.6059570	16.98
903.4892578	1.05
904.6931152	5.41
914.6040039	2.35
922.2412109	20.98
922.8525391	4.13
923.5937500	1.24
940.5892334	1.17
942.4262695	3.54
957.8870850	0.63
958.5068359	15.01
966.6989746	1.30
970.3029785	0.73
983.4044189	14.30
984.4700928	100.00
985.4042969	1.01
994.1704102	1.23
1021.5351560	2.77
1022.3845210	6.35
1039.3663330	0.30
1040.3544920	1.76
1041.1457520	0.79
1042.6618650	0.41
1043.4556880	2.37
1065.0095210	0.68
1066.3923340	34.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	518.2523
Annotation	PS(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
153.0043945	5.15
170.9859161	0.63
181.2252502	0.18
236.1898499	0.07
261.1393433	0.14
277.3220215	0.22
293.3290710	0.05
322.1141357	0.08
367.2712402	0.15
388.3802490	0.07
394.3602905	0.05
413.1685181	1.94
415.3037720	0.12
431.3316040	100.00
437.9015503	0.25
460.1536865	0.09
464.4924927	0.35
475.5209351	0.13
481.6624756	0.06
483.2438965	0.17
500.4656982	0.12
501.2632446	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.4864
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
241.0814819	7.76
259.1652222	0.67
275.3401489	0.64
277.2271729	70.70
278.1085205	0.49
287.0186768	0.16
295.0516052	0.21
297.0647583	15.95
305.0465088	0.35
315.2123718	1.30
381.3211670	0.36
411.1049805	0.26
413.3049316	54.53
414.5022583	0.41
431.2764893	2.67
431.9296875	0.04
463.2236938	0.48
483.0977173	0.18
501.6705933	0.56
518.3772583	0.08
519.4357910	0.14
550.4714966	0.12
575.2905884	100.00
576.4100342	1.12
593.4328003	20.94
691.6885376	0.45
717.3538208	0.38
722.4198608	0.55
789.7324829	0.76
791.2306519	0.48
793.1597290	1.22
795.6874390	0.20
807.5180054	0.10
834.5037231	0.20
835.4215088	2.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	640.3016
Annotation	Balanitesin
Peak:m/z	Relative Intensity
221.1329498	2.84
222.4038391	0.70
263.0193787	1.57
270.2759399	0.40
390.7368774	0.45
405.3291016	1.28
424.5441895	2.13
460.6089478	2.00
478.8510132	0.76
496.1434937	0.70
528.4589844	1.81
550.4627075	1.29
559.4453735	51.27
560.1804810	0.47
597.3046265	0.21
601.3234253	0.84
602.3515015	0.14
609.3931885	1.43
610.0947266	1.37
619.5250244	0.18
759.4291992	2.46
760.4041748	0.20
763.3176880	4.60
764.2756348	1.19
781.6109009	2.15
782.4385986	2.04
795.7404175	0.17
849.4165039	2.40
850.4294434	1.67
864.4687500	0.15
921.3266602	13.94
922.3923340	4.28
939.5725708	4.53
940.5046387	2.38
957.5025024	19.23
958.5117798	10.76
959.2465210	0.68
1057.6298830	1.10
1083.2922360	1.44
1084.7840580	0.59
1101.3859860	14.41
1102.5247800	6.46
1119.4738770	100.00
1120.4309080	46.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.2084
Annotation	Unknow
Peak:m/z	Relative Intensity
236.9188995	0.14
245.1099243	0.50
253.2072754	0.29
255.1148071	0.20
256.2689209	0.05
262.0570068	0.21
263.1258240	0.13
268.1317139	0.16
271.0505676	15.74
273.2605591	0.60
275.0551147	0.10
281.2255859	0.12
282.2390137	0.63
283.1225586	0.74
287.0589600	0.32
289.0529175	21.58
289.6689453	0.20
297.0967102	0.07
299.1515808	0.13
301.1249390	0.42
310.1484985	0.45
311.2675781	1.75
314.8704529	0.17
318.3616943	0.09
321.0477295	0.34
328.1998291	0.19
329.0743408	2.58
331.0932312	0.42
335.2797241	0.28
339.3580933	0.06
341.0515137	0.14
345.2275391	0.18
347.0816956	0.33
357.0200806	0.05
363.1781921	1.40
375.2100830	0.57
379.2523193	1.54
381.2196655	0.96
383.0399170	0.23
389.0486450	1.34
391.0850830	0.31
392.4472656	0.58
393.2551880	0.23
397.2001343	1.51
399.2861938	0.07
404.1685181	0.21
405.1791992	0.16
407.2208862	13.70
409.1032104	1.01
413.0498047	0.19
417.1486816	9.57
418.0576172	1.06
419.1305542	1.46
421.2593384	0.50
422.9163818	0.09
425.1301880	6.64
433.1838989	0.94
435.1931763	10.54
436.1586914	1.99
437.1528320	0.63
439.1300049	0.19
446.2159424	0.42
447.1336060	0.29
449.0361938	0.25
450.0361938	0.14
451.1760864	0.23
457.3127441	0.16
465.2904663	0.65
477.3757935	0.37
481.1635742	0.12
483.3056030	0.28
499.0430298	0.63
500.9890747	1.10
507.2935181	0.62
517.3037109	0.25
519.1361084	0.55
520.9934692	0.06
525.1121826	6.00
527.0836792	1.85
541.0272827	0.39
543.1789551	100.00
545.0524902	0.72
553.3208008	2.51
555.2770386	1.16
556.9419556	0.18
559.1741943	4.92
561.1785278	56.70
564.3603516	0.09
565.3425293	0.07
566.2198486	0.11
571.0333862	5.32
573.2047729	2.74
575.0062866	0.11
583.0184937	0.15
583.6347046	0.20
585.3015747	0.11
600.6034546	0.59
603.2681274	0.79
613.0573120	0.06
617.1802979	0.07
635.3131714	0.33
637.2042236	0.09
643.2920532	0.28
645.3095093	0.10
652.2593384	0.08
653.0310669	0.35
657.1463013	0.22
661.2028198	1.78
663.3495483	1.02
665.2037964	0.20
669.8256226	0.09
671.2169800	0.41
679.1517334	11.33
681.0922852	2.90
685.1456909	0.09
687.3082275	0.12
688.6141968	0.32
689.2699585	1.21
693.4098511	0.22
695.2829590	0.13
697.0977783	4.75
707.0668945	23.64
707.6773682	0.25
771.2960815	0.99
777.8246460	0.29
784.3410034	0.08
785.3202515	0.19
789.0214233	0.10
797.0863647	0.20
815.1993408	17.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.4379
Annotation	3-O-alpha-L-arabinopyranosylserjanic acid 28-O-beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
225.0714264	1.23
233.1332397	0.49
241.2207336	0.67
257.1039124	1.34
291.1196899	0.67
297.3588257	2.62
307.1909485	1.17
308.3088074	1.14
319.0707703	1.20
323.3188477	0.63
336.9861450	0.80
375.2649536	2.61
391.3811035	7.42
392.1362305	2.05
407.3064575	20.94
409.5383301	0.90
417.5607910	2.34
421.1510620	0.80
423.5025024	3.91
427.6428223	0.58
433.2766724	0.76
435.4764404	23.06
437.6382446	1.56
439.5178223	2.37
451.3598633	0.90
453.3135376	3.50
455.3830566	38.65
459.2705688	0.77
465.4570312	2.36
467.4358521	2.21
473.3523560	1.03
477.4114380	2.52
495.2145386	5.33
497.0679932	1.06
497.7433472	1.49
505.6575928	0.57
523.5098877	23.18
525.6942749	2.13
533.3307495	0.86
551.2748413	10.14
551.9307861	0.59
555.4581909	3.37
571.3935547	0.95
595.4703979	0.92
613.4073486	100.00
614.4786987	0.41
631.5267944	7.01
646.4512939	0.45
673.6314087	0.48
687.4835205	0.62
728.8903809	0.88
733.2789917	1.26
747.2866211	0.77
749.4579468	0.34
765.5510864	0.28
774.6021118	3.87
775.4533691	4.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2809
Annotation	Virescenoside N
Peak:m/z	Relative Intensity
164.0836792	0.03
201.9746399	0.04
215.2135773	0.02
259.2976990	0.02
271.2304993	0.01
279.0783691	0.08
281.2913208	0.02
285.3214417	0.07
287.8262939	0.02
293.0494385	0.05
294.9500732	0.01
301.3605957	0.07
304.4537048	0.09
317.2534790	0.01
324.1964722	0.03
325.2600708	0.03
327.4802856	0.04
335.3475342	0.04
339.1036377	0.11
343.2598877	0.06
345.3734741	0.05
355.1934204	0.04
362.9270630	0.06
367.3280640	0.02
391.2832031	0.06
405.4313965	0.12
407.4649048	0.08
414.3202515	0.36
417.1258545	0.15
421.0987549	0.02
423.5744019	0.04
446.1832886	0.02
457.4974365	0.03
463.4011230	0.04
491.3880615	0.04
492.8858032	0.05
497.3311157	100.00
499.4083252	0.10
500.3927612	0.01
524.3914185	0.02
525.3933716	0.19
534.5785522	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9532
Annotation	Unknow
Peak:m/z	Relative Intensity
182.8273773	0.03
229.1762085	0.06
267.8689880	0.06
269.0233154	0.07
270.9638977	0.15
288.4088135	0.06
298.0775146	0.03
307.4918823	0.10
308.9114380	0.35
309.9934387	1.33
311.0639648	0.83
311.8265381	0.08
323.5197449	0.04
326.9918213	0.10
327.8077698	0.14
329.0642700	0.10
334.7244263	0.10
339.0763855	0.11
345.8823547	0.23
347.5156860	0.14
350.5791016	0.28
351.2777100	0.16
352.0501099	0.08
354.3297424	0.20
360.0468750	0.10
362.0122375	0.13
364.3991089	0.04
367.3153992	0.15
370.5290527	0.03
377.9571838	2.77
379.2599792	0.24
379.9552307	0.13
380.7823181	0.33
382.9000854	100.00
383.5080261	0.28
395.2818298	0.34
396.0395508	0.51
396.8437195	0.32
397.9683533	0.14
399.0371399	0.53
399.9741821	2.58
400.5827637	8.77
401.6713867	0.45
405.8409729	0.13
414.1646118	0.04
414.8745422	0.44
418.6658630	0.08
424.8993835	0.17
433.6432800	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	356.2078
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
128.0283051	0.76
130.0096588	100.00
133.0528717	0.81
137.1737061	0.20
145.0964813	1.90
146.8649902	0.32
151.1743164	0.38
163.0835876	3.14
165.0556641	0.25
168.7463379	0.11
171.1105652	0.04
171.9880829	0.20
179.2225647	0.13
181.0887451	0.40
192.0878906	0.34
199.1068420	0.16
203.1289978	0.17
206.1823120	0.06
207.0246735	0.28
208.0044250	0.85
212.2134399	0.47
220.2116394	0.32
222.9129333	0.07
225.1275940	0.26
229.1186829	0.11
232.0737000	0.38
236.0021667	0.09
240.2017822	0.12
246.1322937	5.78
258.2193604	9.60
263.7214966	0.21
270.1341553	0.14
274.3518982	0.29
276.2949829	5.42
282.1909790	0.26
292.3867798	0.92
302.2088013	0.15
312.2834778	0.06
320.2358704	0.92
338.2525330	23.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
183.0721588	0.10
191.9644928	0.10
200.8840942	0.06
206.9500885	0.07
210.0561523	0.03
211.2203064	0.05
226.1058350	0.09
229.0381622	0.06
230.8566742	0.04
233.1956635	0.07
238.9550171	0.08
247.1414795	0.11
254.9536743	0.19
257.1307068	0.09
263.0912781	0.12
266.9991455	0.05
272.8256531	0.35
273.5229492	0.15
274.4057312	0.10
279.0620422	0.11
285.1540527	0.17
286.1003418	0.09
287.1762085	2.70
297.1397400	0.08
303.0670166	100.00
303.6809692	0.32
311.0580444	0.11
315.2883606	0.21
329.0410767	0.23
337.4448242	0.02
345.0922852	0.35
355.2161865	0.16
361.1413574	0.04
363.0278320	0.26
369.3012085	0.22
385.2537231	0.11
400.6165161	0.03
411.0667725	0.22
417.1247559	0.96
428.8003540	0.19
431.1802368	0.42
435.0729370	0.35
441.0626221	0.06
442.3063354	0.07
443.1660156	0.14
447.2255859	0.90
448.4924927	0.84
449.1259155	3.27
453.3206177	0.17
464.9270020	21.49
465.6845093	0.09
466.3154297	0.26
470.9237061	0.02
473.3876343	0.13
477.3655396	0.02
485.0259399	0.13
489.4383545	0.25
490.8414917	1.20
491.5133667	0.04
492.2158813	0.17
502.3982544	0.12
515.2889404	0.25
530.4174194	0.12
533.0573120	0.02
550.8391724	0.05
557.4227295	0.03
559.3734741	0.02
575.2293091	0.09
577.0090942	0.22
577.9114380	0.03
583.1804199	0.04
590.7212524	0.15
592.8776245	0.93
593.5521240	0.38
602.5476685	0.08
611.1348267	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2142
Annotation	Stachyose
Peak:m/z	Relative Intensity
179.0105133	0.22
221.0571289	6.48
235.2186279	0.13
250.8726654	0.34
281.2108459	0.92
305.0827026	0.68
311.1801147	0.54
323.1209717	3.09
341.0559082	25.88
343.3441772	0.34
346.819397	0.17
365.2661743	0.89
383.1290894	100.00
396.9320679	0.31
398.4052124	0.08
399.2307739	0.35
400.9633789	1.95
406.177124	0.29
413.0283813	1.36
424.9777832	1.26
442.8726807	18.02
467.2105103	1.06
472.9137573	0.54
485.2737427	31.06
503.0700684	4.10
545.3723145	0.58
574.8945312	0.24
629.4179077	0.41
647.3520508	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1281.61
Annotation	Unknow
Peak:m/z	Relative Intensity
408.9954834	0.32
437.2213745	0.99
463.2563477	0.83
499.1516724	1.88
527.3244629	0.40
571.7001953	0.26
601.3880005	3.52
605.6096191	1.82
617.5301514	0.65
619.5511475	4.43
621.7210693	0.65
625.2978516	0.31
633.3637695	1.35
687.5684814	5.62
715.2251587	0.32
733.5888672	1.55
735.4129028	1.51
751.5527344	0.26
763.1675415	11.83
763.7855225	2.21
781.5709229	12.22
795.6896973	0.51
849.4895630	29.94
855.4261475	0.65
863.3603516	1.26
875.3868408	1.25
877.3824463	8.04
880.5632324	0.29
895.3786621	19.98
903.5288086	0.51
913.3516846	5.91
920.7329102	1.24
921.3826904	39.76
939.4769287	100.00
941.5821533	1.03
957.3565674	8.38
1009.5354000	1.87
1035.4577640	0.87
1039.4282230	8.46
1057.5463870	47.66
1075.4714360	12.33
1076.2309570	0.56
1084.7052000	0.26
1101.5718990	9.38
1119.4541020	51.48
1120.3939210	6.28
1160.2532960	0.26
1191.3070070	0.63
1203.7160640	1.09
1219.4770510	58.87
1237.3083500	1.84
1263.4223630	63.09
1264.4873050	0.44
1937.6749270	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.9675446	0.20
159.0076294	2.55
160.0422363	1.65
161.0334473	0.84
171.9423523	0.10
200.0736542	0.14
201.9802551	0.22
209.2168274	0.09
217.3216400	0.10
218.1130066	0.12
229.1624451	0.11
230.0425873	0.14
231.0559540	0.82
232.1185913	0.07
272.9406128	16.18
273.9942322	30.67
274.9813232	27.93
275.9940491	16.88
277.0298462	0.12
301.6591797	0.13
345.9905701	0.50
354.1982727	0.16
355.1562805	0.21
387.1974487	5.81
387.9882812	36.01
389.0002747	52.43
389.9579773	100.00
391.0295105	0.09
414.1052856	0.56
416.0699158	0.22
419.0832520	0.65
429.9081726	1.06
430.9385681	0.22
432.0229492	0.12
448.0940247	0.11
458.4064026	1.58
459.0361023	4.53
459.8429871	1.38
476.0119324	0.19
485.8894653	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.3242
Annotation	Unknow
Peak:m/z	Relative Intensity
176.0157928	2.29
177.1697388	0.04
180.6169434	0.03
183.8843384	0.26
185.2216644	0.09
190.7935486	0.07
192.9308167	1.01
231.0033417	0.13
241.3171387	0.14
244.1117249	0.14
259.1991577	0.26
275.1095581	0.14
277.2655029	5.29
286.2348022	0.07
293.2789307	0.44
294.5430908	0.28
295.3029175	0.22
300.5300293	0.32
304.1528931	0.08
309.3482666	0.74
314.3366089	0.33
322.1202393	0.40
324.0221558	0.16
330.9898682	0.10
334.3596802	0.31
335.1595459	0.62
351.9717407	0.34
354.2855835	0.04
359.7282715	0.07
362.3898926	0.07
364.1774292	0.03
365.7263184	0.07
369.6870728	1.21
370.3038940	4.54
380.1913452	1.23
400.2601929	0.05
403.1980591	0.12
404.6303711	0.12
445.3791504	0.12
450.4251099	0.04
452.0952759	1.48
454.2360229	0.06
456.7853394	0.10
469.2285156	3.73
470.2264404	7.82
473.0704346	0.12
475.1578369	0.26
479.9509277	0.08
482.2150269	0.07
484.3186035	0.10
487.2448120	100.00
487.9425659	0.31
494.1015015	0.04
509.3501587	0.16
512.9750977	0.04
527.2462769	0.21
530.1395264	0.23
533.4061279	0.21
541.8909912	0.36
553.2143555	0.23
558.2839355	0.13
562.2888184	0.08
573.4434814	0.62
576.5763550	0.21
578.3075562	0.25
580.2026978	0.65
598.3051147	9.47
599.5178833	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1129.5428
Annotation	Eximisoside A
Peak:m/z	Relative Intensity
465.7380371	0.22
481.2963562	0.35
549.5743408	0.29
555.2930298	0.61
569.3210449	0.27
629.6103516	0.23
637.5108643	1.98
697.5404053	2.27
709.2538452	2.07
713.1806641	0.18
727.6112061	0.61
743.6561279	0.17
769.2716064	1.14
787.3206177	0.44
804.0660400	0.16
812.9082031	0.08
813.7153320	0.12
828.5872803	0.24
844.9184570	0.05
851.3394775	0.09
873.7164307	0.09
889.6451416	0.44
895.7451172	0.20
907.2779541	0.16
939.3986816	0.25
949.7635498	0.09
950.4171143	0.18
967.4672852	0.39
975.5369873	1.39
993.4207764	0.36
997.3991699	0.09
1000.2636720	0.04
1007.4290770	0.79
1017.2347410	0.13
1025.3007810	0.06
1037.6575930	0.48
1051.4506840	2.66
1069.4809570	100.00
1080.9812010	0.14
1092.6943360	0.17
1101.5598140	0.19
1111.3586430	3.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.0932
Annotation	N-Acetyl-DL-tryptophan
Peak:m/z	Relative Intensity
71.89292908	0.18
73.97605896	1.52
97.96202087	0.36
115.9701691	3.72
129.0472717	0.01
129.928009	0.16
142.1906891	0.05
157.175705	0.03
159.0996704	0.09
175.0741119	0.01
181.2830658	0.03
183.1387024	0.18
185.0424805	0.02
186.1212616	0.17
199.1277008	0.02
201.1288605	2.71
203.0800323	100.00
208.8719025	0.03
217.0602875	0.04
227.0150146	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.09
Annotation	Unknow
Peak:m/z	Relative Intensity
74.6842499	0.04
82.0866394	0.04
119.9666443	100.00
124.7680359	0.05
131.0750732	0.17
138.0042572	0.06
148.0912628	0.68
148.8897247	4.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2024
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
238.9891663	0.49
241.2378235	0.14
243.1237488	1.83
245.1125793	1.45
247.1107483	0.36
250.9566650	0.08
253.3749237	0.07
255.1711731	0.43
256.2822266	0.05
257.1322021	1.22
259.1493225	1.22
260.1415100	0.22
261.2624817	0.80
263.1479187	0.18
265.0442810	0.13
267.0011902	0.07
269.0727539	1.03
271.1535339	5.07
272.0813293	0.10
273.2090759	1.77
273.9560547	0.26
274.9258118	0.10
280.4273987	0.16
281.1777344	0.73
282.2352295	0.39
283.2549744	0.58
284.0242920	0.18
285.1643677	2.74
286.1138916	1.45
287.1549683	8.89
289.1862488	11.21
290.2890015	0.09
296.1555481	0.06
297.2012634	0.18
299.2805176	1.71
300.1260376	0.60
301.2525024	0.58
302.7749023	0.10
303.4705811	0.14
305.0778503	1.16
307.3436279	0.26
309.2338562	0.39
310.2427368	0.10
310.9901428	0.47
312.3013916	0.41
314.2224426	0.16
315.1390991	0.13
319.2541504	0.07
321.2152100	0.92
322.3588257	0.07
323.0730896	0.23
325.2080688	0.47
326.0683289	0.16
327.1531067	0.66
328.2576294	0.34
329.0788879	0.66
331.3960571	0.25
333.1838379	0.31
337.1567078	0.06
339.3044434	0.59
341.3200989	0.89
342.3315125	0.06
343.2245178	0.13
345.1973267	0.39
347.1563110	1.65
349.2955933	0.24
350.1096191	0.56
353.3685303	0.24
357.3552246	0.10
361.4031982	0.24
363.2106934	2.15
365.1734619	0.82
367.0804443	0.57
371.2602539	0.39
377.5267029	0.07
379.1905518	1.04
381.0436401	0.40
385.3674927	0.14
389.1266479	5.11
391.0679321	4.28
393.0299683	1.69
394.0078125	0.10
395.1898804	3.24
397.1511841	0.59
399.2027588	0.10
401.2185059	0.06
403.1013184	0.15
405.1060791	3.19
407.1672974	24.47
407.8623657	0.14
409.2167969	2.37
411.1824341	0.88
413.2293091	4.58
414.9798584	0.64
416.4113159	0.34
417.4513550	0.95
418.1978149	0.50
419.1883545	6.43
421.0682983	0.99
422.1968994	1.72
423.1574707	3.28
424.2501221	0.59
425.2561035	2.78
426.4652100	0.27
427.4221802	0.10
431.0552368	0.56
433.1290894	21.26
434.0891113	1.78
435.2361450	9.40
436.3868408	4.19
437.1789551	7.80
438.4540405	0.29
439.3714600	0.47
440.1745605	0.94
441.1939087	0.31
442.1276855	0.03
443.1851807	0.09
446.9518433	0.19
449.1491699	4.79
450.4277344	1.14
451.1726685	3.69
452.2401733	5.90
453.2160034	0.47
455.4310303	0.95
459.2131348	0.42
462.3576660	0.08
464.9172363	0.49
468.5391846	0.12
470.4331055	0.13
471.1141968	0.27
473.5056152	0.09
475.3435059	0.14
477.5022583	0.51
483.0760498	0.10
487.2357788	0.42
491.1643677	0.29
493.2315063	0.07
494.9714966	0.07
496.6047974	0.08
499.2542725	0.20
500.6096802	0.07
503.3046265	0.82
505.4472656	0.20
511.7619019	0.13
513.2547607	0.33
514.1950684	0.48
515.2316895	2.32
517.2315063	1.02
519.3496094	0.15
523.2544556	0.22
524.7473755	0.35
525.3906250	0.23
527.2529297	2.32
529.3088989	0.48
532.2656250	0.06
533.1877441	0.41
535.1768799	1.15
536.8281250	0.05
539.2256470	0.61
540.6873169	2.01
541.3666382	4.90
543.1478882	10.13
545.0783081	1.05
553.1649170	1.39
557.2403564	1.39
558.2393188	6.93
559.1760254	100.00
561.1588745	27.08
562.2980347	0.17
569.0980835	0.97
570.5379639	0.30
571.1843872	2.54
575.2152100	9.33
576.3023071	6.79
577.1843872	21.29
578.0701904	0.19
582.9251099	0.55
587.1414185	2.46
589.1699829	37.26
596.8804932	0.07
600.0531006	0.66
601.1134033	0.52
602.4869385	0.33
603.1828003	0.56
609.2534790	0.28
609.8820801	0.10
613.1780396	0.13
615.9302368	0.88
619.1966553	0.13
621.2741699	1.44
624.5607300	0.08
629.4105835	0.17
635.2849731	0.20
637.1431274	0.24
639.4672852	0.31
643.2399292	0.24
649.7346802	0.47
651.3524780	0.50
653.1747437	3.39
655.4032593	0.43
657.2665405	0.44
660.9337769	0.86
669.3524170	1.03
671.2322388	0.08
673.3197632	0.29
677.0267334	0.46
679.1257324	73.79
679.7535400	0.20
681.2593384	0.46
682.6890869	0.11
685.2330322	0.07
686.5236816	0.18
687.3027344	0.17
689.2014771	0.08
693.7112427	1.08
694.4349365	1.00
695.2088623	2.89
696.6154785	3.67
697.2443237	22.05
699.2691040	0.38
700.2883301	0.28
701.9487915	0.40
702.9122314	0.35
703.6011353	0.32
704.2329102	0.83
705.3467407	1.29
707.2056274	0.18
711.1300049	0.81
712.2008667	3.68
713.0894165	7.46
714.3014526	0.32
718.0838013	3.28
721.4849854	0.74
723.1644897	39.07
724.2697144	2.03
725.2758789	0.11
726.1720581	0.42
729.5427246	0.13
734.8395386	0.29
736.9499512	0.11
739.6058960	1.93
740.7794800	0.16
742.1837769	1.09
743.2833862	0.82
761.3092651	0.22
763.6853638	0.14
764.3520508	0.23
771.2685547	0.49
786.6228638	0.20
787.2410889	0.36
795.5913696	0.18
805.0006714	1.07
805.7350464	0.07
813.2657471	0.28
818.7324219	0.16
821.2257690	0.31
823.3029175	0.13
828.8464355	0.08
829.9466553	1.16
831.1226807	23.84
831.9853516	0.12
833.4002075	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.08
Annotation	Unknow
Peak:m/z	Relative Intensity
87.1319122	0.08
89.0025024	0.36
99.0783997	0.36
100.8012161	0.37
114.8545685	0.23
116.0993500	0.28
117.0997772	0.57
118.8619690	0.37
127.9362335	100.00
129.0905762	7.45
130.0522461	12.00
142.8380127	0.14
148.0985413	0.08
150.0519714	1.39
162.8187408	0.05
164.1946716	0.35
175.3832855	0.12
179.2210236	0.06
189.0957031	0.10
197.2048035	0.10
199.1969910	0.14
210.9555664	0.10
213.1555176	0.13
215.1681824	0.30
234.9217834	0.09
241.2713623	0.12
243.1412048	6.51
247.3482056	0.10
259.1210022	3.37
261.1384277	82.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.2367
Annotation	11-HpODE
Peak:m/z	Relative Intensity
90.6913452	0.09
92.9333038	0.07
95.0458908	0.25
97.2117157	0.09
98.8879013	0.07
100.3259888	0.05
105.1635895	0.08
105.8347092	0.04
106.9950256	0.15
108.9693146	0.20
111.0400391	0.02
113.0783539	0.30
114.9237900	0.86
117.1666031	0.11
119.0072937	0.12
121.0617981	0.95
123.0364151	0.41
124.8850098	0.13
126.9725647	0.07
129.0509796	0.44
130.8649292	0.19
133.0368195	0.12
135.0649414	0.32
136.1386719	0.04
136.8577881	0.36
138.7702484	0.02
141.1311035	0.24
144.9167175	0.28
147.0048828	0.49
149.0841064	0.56
151.0364532	0.22
152.8458405	0.19
154.9811401	0.17
157.1992493	0.26
159.1148682	0.22
161.1656647	0.29
163.1055756	0.67
165.1297302	0.41
167.0276642	1.04
169.1757965	0.31
171.0292664	0.59
173.0503235	1.78
175.1687927	0.11
176.8885651	0.08
179.2023468	0.09
180.1339722	0.03
181.1116333	0.12
183.0042877	0.15
184.0234985	0.08
185.0493774	1.13
186.9965515	0.51
189.1903839	0.38
191.0955963	1.14
193.1421661	0.65
193.9905090	0.09
194.9715271	0.25
196.5779724	0.22
197.2465668	0.07
199.1463318	0.28
201.0174408	0.44
203.1320496	0.25
205.0657959	0.14
207.1764221	2.19
209.0853577	5.43
209.7610779	0.02
211.0990601	0.52
212.8771362	0.20
215.1235962	0.07
217.2923889	0.07
219.0645447	0.35
221.1353455	0.58
223.2531738	0.41
224.2666016	0.13
225.1823120	0.80
227.0582886	14.46
228.5033875	0.02
231.2446899	0.24
235.1824036	0.09
237.1685181	1.26
239.2190552	0.17
241.3016052	2.09
243.2377014	0.35
244.1001282	0.03
249.1591492	0.19
251.4162903	0.20
253.0506592	0.55
254.5039673	0.06
255.1761169	0.19
256.1051941	0.04
257.0825806	0.29
259.1573486	5.90
259.7752991	0.04
261.9178162	0.09
269.1354675	0.16
271.0790405	0.28
271.9750366	0.05
272.9881287	0.04
275.1654968	0.03
277.1882629	57.09
279.3444519	0.07
281.2434082	0.12
282.2546692	0.04
283.1008911	0.14
284.2149353	0.04
285.3909302	0.08
295.1243896	100.00
296.1742554	0.08
304.2606812	0.12
312.8828430	0.09
321.0982056	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	146.12
Annotation	1-Nitroheptane
Peak:m/z	Relative Intensity
68.9710846	0.01
71.7384186	0.01
81.0987625	0.07
99.9650269	100.00
100.9377136	0.04
126.0434113	0.09
128.0616455	0.02
128.8875732	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	392.1133
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
111.6788330	0.07
125.5724564	0.09
127.9942627	28.98
134.0113831	0.93
134.9460754	0.08
153.0511017	5.94
168.2072601	0.05
171.0211182	0.62
179.0908508	0.38
195.2163696	0.07
196.0188293	0.25
197.0687561	5.51
201.1158142	0.21
215.0974579	2.65
217.1244354	0.18
226.9350891	1.71
228.9395752	0.10
239.0474548	5.00
242.9832764	0.21
245.0783386	63.67
256.1451721	1.16
256.8525696	0.41
263.0704346	58.70
264.1179504	0.94
282.1883850	1.82
290.1336975	0.11
299.9497986	1.21
308.1652222	0.29
312.1387329	0.48
326.0917664	7.85
330.3786011	0.50
344.1710205	23.01
356.1817322	23.08
356.8701477	0.14
374.1200562	100.00
374.7598572	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1973
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.0663147	1.72
245.1416779	2.76
253.1231537	0.14
254.9116364	0.98
257.3171082	0.44
258.3379517	0.09
261.1698914	1.65
267.1340332	0.59
269.1776123	0.62
273.0324707	0.38
281.0570984	0.70
283.0742798	0.49
285.1528931	2.34
287.0674438	22.63
289.1488037	3.84
295.1030884	0.19
299.0247192	3.19
301.1987915	0.12
301.9754333	0.09
303.1564331	0.24
305.1036072	0.38
307.1319885	0.10
308.1765137	0.07
311.5740967	0.35
313.0180664	0.15
317.5406189	0.15
321.2602539	0.14
327.1063843	0.33
329.2147827	0.19
331.2561035	1.43
335.0197449	0.07
337.1655884	0.30
338.0284119	0.37
339.2084351	0.28
340.9448853	0.32
343.2110596	0.22
345.3715820	0.37
347.1504517	0.60
349.2173767	0.19
351.0762634	0.07
353.5740967	0.28
359.5377197	0.17
361.1629944	0.57
363.0919800	6.16
365.0498047	1.51
367.1463928	0.34
368.8812866	0.45
370.9584961	0.13
373.1340942	0.33
376.9811401	0.33
379.2211304	0.06
380.9431152	0.72
382.9714355	0.27
387.2634277	0.79
388.9605103	0.11
391.2476501	2.27
393.1434326	0.20
395.2137756	4.36
396.9574585	0.71
405.1234131	11.58
407.1436157	28.80
407.7535400	0.06
409.1694336	0.92
413.0949707	6.68
417.1035767	1.75
421.2130127	0.17
421.9832764	0.34
423.1558228	6.57
425.1849365	20.80
431.3593140	0.21
433.0982666	0.20
435.1393433	3.36
437.2576904	0.20
447.1505737	0.09
449.1751709	16.38
451.0820923	10.76
452.3499146	0.25
453.4965210	0.33
459.4289551	0.17
465.0610962	0.86
467.1622925	1.28
469.1445923	0.32
473.3576050	0.51
477.2441406	0.76
478.4931641	0.17
485.3064575	0.23
489.2996826	0.29
491.2755737	0.36
493.1845703	0.77
499.1459351	1.08
509.4580688	1.44
510.2972412	0.20
513.2307739	0.32
515.3548584	1.52
517.2484131	1.27
518.8884888	0.34
521.2065430	0.50
525.1311035	5.85
527.3640137	0.95
530.7587280	0.16
531.4206543	0.73
533.0900879	3.15
535.0033569	1.22
539.1192017	0.17
541.3623047	0.08
543.2155151	16.71
545.1204834	1.59
555.1664429	0.39
557.0717773	4.57
558.3365479	0.14
559.3179321	3.83
560.5251465	0.57
561.2285156	5.07
565.3407593	0.31
566.6477661	0.09
569.2117310	4.47
571.4061890	0.40
573.0795288	0.29
575.1794434	29.05
577.1727905	36.03
585.1205444	0.24
587.0354614	21.28
587.6933594	0.12
591.2791748	0.17
591.9973755	0.20
593.1884766	1.86
595.4430542	0.07
607.2066040	0.43
609.5319824	0.19
616.0407715	0.20
617.0414429	0.73
619.1856079	5.24
620.7462769	0.14
627.3911743	0.23
629.3405151	1.33
630.2294312	0.48
641.2995605	0.80
645.2269287	0.17
651.5803833	0.46
657.2381592	0.31
659.3497925	1.08
662.3967896	0.08
669.1963501	3.75
673.2525024	0.24
677.1970825	7.10
679.3311157	0.28
681.5930176	0.26
684.9308472	1.00
693.2645874	0.27
695.0743408	100.00
695.7766113	0.51
697.4737549	0.19
698.8170776	0.39
701.3610840	0.07
702.3377075	0.98
703.3196411	6.41
710.1452026	0.44
711.3269653	0.08
712.5395508	1.25
713.1953735	31.34
721.2803955	1.26
722.9992676	0.39
724.2360840	0.15
725.1758423	0.51
727.2779541	1.37
727.9429321	0.99
729.2565308	0.16
737.3387451	0.30
739.1292114	35.06
739.9387817	0.27
742.2662354	1.14
751.1532593	0.51
755.2311401	0.82
756.3568115	0.72
760.4779053	0.17
776.5249634	0.11
777.4023438	0.18
803.0005493	0.57
803.6063843	0.38
821.0038452	1.83
823.2866821	0.13
829.1289673	0.80
847.0354614	16.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
111.0764923	0.14
128.9800110	1.25
136.9764099	0.03
144.8206482	0.10
146.9497681	4.32
172.9094849	1.65
181.1634216	0.11
186.9781799	0.03
190.9712677	100.00
193.2851868	0.56
209.0263062	9.70
218.9806519	0.07
223.3292236	0.05
247.2358093	0.07
252.3042297	0.10
286.8950500	0.04
314.7963867	0.07
323.1776733	0.11
325.0763855	0.36
341.4080200	0.23
343.1093445	0.19
367.1054688	6.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.2167
Annotation	Rhamnetin 3-rhamnosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
231.1910095	0.07
239.1994324	0.07
241.3488770	0.14
242.1665649	0.31
243.1717987	0.89
244.0099792	0.88
245.0592346	1.11
246.9646149	0.09
252.9955139	0.31
254.1013794	0.16
255.0356445	3.08
257.1714172	0.97
261.1814270	0.03
265.0759277	0.04
267.0942078	1.60
269.1622620	0.66
271.1152344	0.95
273.1395874	6.87
274.0212402	3.49
275.1916504	1.17
277.2350159	0.11
279.1108398	0.65
281.1371460	0.14
284.9998779	9.87
286.0666199	0.80
287.1029663	4.15
288.1996460	0.06
291.1702881	3.03
292.8364868	0.20
295.1320801	0.35
297.1327515	1.96
299.0601501	2.30
301.0624084	0.16
303.0024719	1.48
307.0535889	0.14
311.0530090	0.21
313.0444336	0.86
315.2360535	1.31
316.9775391	0.18
324.9616394	0.45
327.0893555	0.41
335.1327820	0.33
337.2621460	0.09
345.1190186	0.20
349.1599121	1.14
357.4967651	0.20
359.0755005	0.88
361.2098999	0.47
363.0305786	2.78
365.2384338	0.09
367.0795288	0.15
371.1700745	0.30
373.1296692	1.56
375.1951294	0.86
377.2523193	11.85
379.1423950	1.20
380.2355957	1.42
381.0993347	1.90
383.2666626	0.43
387.2846680	0.09
389.2035522	1.70
391.1268921	28.79
393.1266479	9.73
395.2946777	2.40
397.5957642	0.23
399.1069946	0.79
401.1501465	4.13
403.0922852	12.49
405.1206665	2.98
407.1216431	0.11
409.1052856	23.19
410.9832153	9.54
411.5911865	0.09
415.1719971	2.02
417.1487427	0.09
419.1361084	11.29
421.1837158	30.90
422.5994873	0.82
423.2082520	2.30
425.1293945	0.33
427.2691650	1.47
433.1764526	5.54
435.0051880	0.09
437.0006104	2.06
438.9235840	0.15
445.2341919	0.32
447.1587524	0.14
449.0891113	0.13
451.0841675	1.44
453.1412964	0.17
457.2359009	0.06
469.2357788	0.48
479.3269043	0.30
485.2399292	7.93
491.3408203	0.19
496.9674072	0.43
499.2760620	1.68
503.1478882	4.80
509.1920166	16.45
511.2157593	0.53
515.0207520	0.12
519.2683716	0.08
522.4624634	0.17
527.1160889	30.79
529.1763306	1.70
535.1357422	0.26
539.1434326	2.78
541.2543945	0.44
543.1610718	0.36
544.9481812	100.00
545.6700439	0.12
546.8454590	0.80
551.0846558	0.13
553.6004028	0.13
555.2075195	0.93
557.0689087	2.63
560.8378296	1.24
563.0297852	27.51
563.6799927	0.18
569.0014038	0.21
573.1514893	2.43
575.1214600	3.17
587.4003906	0.13
604.7753296	0.21
605.4185791	0.45
615.1486816	0.04
645.6286011	0.09
647.3040161	1.71
649.0825195	0.50
655.1892700	0.36
659.3580322	0.09
660.2344971	0.18
662.7066040	0.29
663.3836670	0.34
665.0222778	5.56
667.0531616	3.23
667.6954956	0.14
673.1654663	0.80
675.0199585	0.41
676.9962158	0.15
679.1182251	0.14
681.1185913	19.17
682.7514038	2.66
683.4365234	0.20
687.4418335	0.11
691.1184082	2.41
693.2516479	0.21
699.1342163	10.27
709.0137329	7.12
710.1255493	0.07
711.6339722	0.08
760.0355225	0.38
773.7255859	0.30
780.7496948	0.07
790.6008301	0.48
799.1410522	0.69
816.4360962	0.64
817.0898438	4.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2809
Annotation	Virescenoside N
Peak:m/z	Relative Intensity
164.3014221	0.03
171.2937164	0.02
195.3567200	0.01
197.2879028	0.12
237.0915222	0.10
241.0660706	0.22
241.9199219	0.30
246.1360779	0.03
269.0486755	0.08
271.2557678	0.03
293.1312256	0.27
307.0178223	0.05
321.2758179	0.03
327.2308960	0.35
393.4935913	0.05
395.2750854	0.03
399.1054077	0.04
407.4843750	0.07
414.2892456	2.81
417.1103516	0.14
419.1395264	0.06
423.3525391	0.09
457.0532227	0.03
463.3834229	0.04
474.1620483	0.05
475.2586670	0.10
482.4687500	0.16
483.4920044	0.03
484.3074341	0.05
485.0986938	0.03
487.5184326	0.02
497.3197021	100.00
497.9405518	0.41
500.4567261	0.04
507.2288208	0.05
521.0122681	0.10
525.2416382	1.16
526.2779541	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1302
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
159.1832733	0.04
161.0677032	0.30
190.9038239	0.06
216.2836151	0.03
229.1200104	0.06
262.9426270	0.03
273.1664429	18.88
274.9071960	0.06
289.3765869	0.21
290.4494629	0.02
299.5012207	0.05
310.2366943	0.03
321.1854248	0.26
322.9908447	0.10
328.2941895	0.25
329.0819092	0.22
340.9475708	7.49
343.1613159	0.07
345.2596436	0.14
347.3913574	0.03
353.0170288	0.08
358.6814575	0.14
359.3312988	0.97
371.2032471	0.13
376.9923096	0.13
385.0045166	0.04
389.2921143	0.12
412.9800415	0.15
417.0903931	0.11
419.9241333	0.10
428.9903564	0.10
435.1185303	0.18
447.2131348	0.07
449.1598511	0.04
457.3307495	0.43
458.9850464	0.04
460.4277344	0.15
461.3017578	0.05
475.4191895	0.31
477.1192627	100.00
477.7512817	0.14
484.2996826	0.10
486.1956177	0.11
503.0881958	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.45
Annotation	3-O-alpha-L-arabinopyranosylserjanic acid 28-O-beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
225.1662903	0.12
227.0982513	0.28
229.1882629	0.22
233.1842651	0.79
239.3660889	0.43
241.1383209	0.42
242.7921143	0.13
245.1705780	4.09
247.3025818	0.19
251.2148285	0.06
253.2263031	0.77
255.1676483	0.65
257.2699280	1.15
259.2792969	0.73
261.2470703	0.29
263.8449097	0.12
265.1463623	0.58
267.2431641	0.32
269.2075806	0.46
271.2729492	0.80
273.1791992	1.43
277.2069702	0.04
279.3106689	0.31
281.2043152	0.83
282.7173767	0.28
283.3748779	0.74
285.1459656	0.70
286.9992065	0.19
293.2412415	0.19
295.4725952	0.17
297.3786011	0.04
299.0991516	1.37
301.4614258	0.28
303.2668457	0.13
305.2077026	0.19
307.0662231	0.10
309.5192261	0.42
311.3857422	0.36
312.9148560	0.49
318.3768005	0.04
319.5027771	0.25
320.7088623	0.28
321.3098755	0.21
325.1457520	0.26
326.6505737	0.19
327.3036499	0.17
333.0592041	0.28
337.4143677	0.57
338.8208313	0.63
341.0456543	0.15
347.0828552	0.07
351.2155762	0.84
355.4677734	0.05
361.0938416	0.34
363.2492065	1.40
365.1335449	1.15
365.7717285	0.05
369.3078003	0.48
375.4732666	0.37
377.2496948	0.08
379.3062134	1.10
381.3293457	3.86
387.2138672	0.17
391.2969971	0.16
393.2363892	0.19
394.7673950	0.15
397.3121338	0.16
403.4446411	4.19
405.0123901	0.41
409.3320312	3.64
411.6317749	0.11
419.1231079	0.93
421.3287354	36.59
422.0042114	0.07
423.3997192	0.25
431.2253418	1.32
433.3181152	0.16
439.2967529	82.68
443.3664551	0.15
445.2544556	0.21
451.6943359	0.05
456.1373291	0.42
457.0546875	3.88
457.7691650	0.13
469.2979126	0.16
479.3215332	0.07
483.1079102	0.06
487.3778687	0.07
495.3456421	0.12
504.5894165	0.26
505.4581299	0.24
510.4285889	0.09
511.7259521	0.07
513.3400269	0.03
527.3042603	0.34
539.6104126	0.02
543.5786743	0.17
549.5659790	0.12
551.2560425	0.36
553.5698853	0.07
561.3178711	1.12
567.2540283	0.39
569.3638916	0.38
579.2750244	5.85
582.5431519	0.17
583.2869263	0.03
595.5392456	0.22
597.2176514	100.00
598.0596313	0.30
599.4223022	0.16
605.8414917	0.13
614.8718872	18.45
615.7791748	0.09
618.7305298	0.54
631.7720947	0.32
633.0057983	3.04
635.9619751	0.27
651.2521973	0.10
654.1907959	0.14
705.8264771	0.07
715.6035767	0.17
718.4895630	0.05
730.8578491	0.04
733.2572021	0.08
740.9366455	0.04
742.7655640	0.05
749.3436279	0.04
751.8121948	0.08
761.6733398	0.31
762.8954468	0.07
776.6026001	0.31
777.4105225	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1983
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.0943756	1.97
245.1365051	3.71
247.0685730	0.22
250.0998230	0.14
252.9044189	0.20
254.8461609	0.44
257.0582886	0.10
261.1151428	1.61
267.1079102	0.07
268.9709473	0.27
271.0642700	0.11
273.1156616	0.91
280.9407959	0.33
282.0896606	0.07
283.1177979	0.20
285.2043457	0.98
286.9966431	13.26
289.1354980	6.49
290.2210083	0.07
291.0885620	0.15
295.2538147	0.40
297.0430603	0.37
299.2022705	2.47
301.1706848	0.12
303.0343018	0.47
305.3734741	0.05
308.7841797	0.65
310.9210815	0.13
313.1413879	0.15
314.1431274	0.05
315.2600098	0.06
316.8638306	0.14
323.0039978	0.12
327.1926880	0.42
329.2157593	0.81
331.2953491	0.36
337.4514160	0.08
339.1240845	0.43
341.3005981	1.00
344.1466675	0.09
345.2474365	0.44
353.4174194	0.11
355.1053467	0.17
357.1920776	0.06
361.2091675	0.21
363.1298218	5.34
365.4094238	0.28
367.1662598	0.32
369.1982422	1.11
372.8312378	0.11
376.8504028	0.13
379.1025085	0.61
380.7463379	0.17
381.3561096	1.02
383.2295532	0.60
387.1922607	0.42
388.1824341	0.10
389.0446167	0.40
391.1246948	0.56
395.1631470	4.35
397.2095337	0.69
399.0887451	0.26
405.0998535	8.71
407.1199951	33.16
409.3421631	0.28
411.0653687	0.24
413.1185303	8.64
415.4370117	0.09
417.1535034	2.58
419.2719727	0.09
420.3530884	0.19
423.1624146	8.89
425.1757202	22.60
426.4195557	0.13
428.3071899	0.33
431.3539429	0.38
433.2692261	0.76
435.1218262	2.32
437.3184204	0.57
441.1204224	0.23
445.1943359	0.33
446.9204102	0.61
449.1575317	17.46
451.1268311	19.24
451.8432617	0.32
453.3369141	0.69
455.3240356	0.27
457.1238403	0.18
459.3463745	0.83
463.1871948	0.38
465.1798706	0.73
467.1029663	2.38
475.2949219	0.15
477.2370605	0.18
487.2745361	0.43
493.3139648	0.38
495.1953125	0.12
499.3380737	0.07
503.0820312	0.09
505.3863525	0.26
509.0286255	0.11
513.0620117	0.12
514.6506348	0.04
515.3647461	0.22
517.2799072	1.58
519.3565063	0.58
525.2022705	3.88
531.0877075	0.39
533.1643066	5.63
535.1829224	0.71
541.0843506	0.32
543.1930542	16.42
545.2012329	0.18
547.1736450	0.30
557.2514648	4.45
559.2045288	8.20
561.1305542	2.45
569.0853271	6.52
575.0919800	17.96
577.1061401	53.61
577.7628174	0.16
578.3634644	0.11
581.2290039	0.07
583.3536377	0.73
585.1550903	0.59
586.1254272	0.71
587.1972046	21.34
589.4508667	0.10
590.9240723	0.16
593.1889648	0.11
600.8102417	0.17
605.4529419	0.10
609.0735474	0.22
616.2520752	0.31
617.2236938	0.65
618.7495117	1.74
619.4392090	1.30
625.4945679	0.23
629.0576782	1.04
630.2549438	0.06
631.9000244	0.08
643.2351685	0.25
651.2055664	0.84
659.2662964	0.86
669.1860352	2.35
677.2269287	6.05
680.9884644	0.28
685.3380737	1.08
693.1748657	0.15
695.1557617	100.00
697.1328125	0.32
702.5906372	0.29
703.2616577	0.72
713.0496826	33.51
719.0535278	0.45
721.1862183	2.16
723.1371460	0.05
725.2702026	0.19
726.9359741	0.58
729.0939331	0.13
736.3308716	0.17
737.1548462	1.71
739.1005249	44.52
739.7636108	0.31
742.9870605	0.52
745.3071289	0.46
750.6183472	0.04
751.4436035	0.36
755.0304565	0.28
777.0303345	0.09
784.9496460	0.53
803.1260986	0.23
821.2977295	1.01
829.2174683	0.68
847.0213623	15.32
847.7584839	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.1276
Annotation	Robustaside B
Peak:m/z	Relative Intensity
122.9717026	0.34
128.0927277	0.05
129.0992126	0.08
131.2036285	0.12
135.1961060	0.04
138.9549561	3.61
143.1793518	0.09
145.0423584	0.19
146.9384918	1.39
149.0200958	0.09
151.0041962	3.08
153.1232147	0.03
161.1931000	0.17
163.0482178	0.05
165.0992432	0.03
173.0611115	0.02
175.1204224	0.04
176.9884949	0.34
179.0207825	0.10
181.0503540	0.04
183.1248169	0.04
184.5554352	0.09
185.9497986	0.04
187.2157593	0.02
189.0957642	0.02
191.2099915	0.20
198.8348541	0.05
201.2074585	0.02
202.1895752	0.03
202.8338013	0.02
205.0769653	0.13
214.8313141	0.11
217.1226501	0.09
218.0566101	0.03
219.2084656	0.16
221.0716248	0.06
223.3110199	0.10
229.1177979	0.05
231.1644897	0.08
232.7848969	0.03
235.0252991	0.15
236.1400146	0.03
237.1618652	0.28
239.0198364	0.08
243.1644287	0.23
245.1202393	10.16
247.3448181	0.19
249.1444092	0.33
249.9952698	0.05
250.9834900	0.17
253.1332092	0.10
255.1128235	0.96
257.0996399	13.41
258.9952087	0.12
259.9526367	0.03
261.1796570	0.03
265.0827942	0.26
266.1072388	0.11
267.1498718	0.75
269.2575073	0.04
271.0984192	2.60
273.0246887	100.00
273.8953857	0.29
275.0743103	0.15
277.2230225	0.21
279.1180420	0.67
281.1319275	0.09
283.0083618	0.09
283.9809265	0.07
285.1435547	2.16
287.0418091	0.10
288.8066406	0.09
290.9855652	0.17
294.8701172	0.29
295.7488403	0.07
297.1469116	5.98
301.1174622	0.06
303.0999146	0.71
305.2290649	0.11
309.1389771	0.78
311.1695862	0.13
313.1454468	0.35
315.2210999	1.82
315.8347778	0.04
318.9183350	0.04
321.1971436	0.26
322.9070435	0.32
325.3859253	0.09
337.1238098	0.04
339.1201782	3.37
341.1148987	0.44
345.4181213	0.03
348.3120728	0.03
351.3297729	0.10
352.0971069	0.09
353.0127563	0.02
357.1896057	0.07
360.2146912	0.11
361.1589661	0.03
363.1832581	0.42
365.3039856	0.08
369.2322693	0.20
376.9459534	0.02
381.1015625	1.34
385.4948120	0.10
389.4075012	0.05
399.1487427	5.77
407.1308899	0.10
410.3193665	0.02
417.1018982	7.19
417.8537903	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.1379
Annotation	Unknow
Peak:m/z	Relative Intensity
145.8993683	1.66
151.0330658	0.20
153.1026917	4.75
170.3940582	0.05
171.1309814	0.16
175.8550873	0.07
179.0778503	5.44
185.0875549	0.36
197.0914001	11.33
209.8798523	0.10
213.0071716	0.48
215.0286255	0.18
222.1033936	1.19
222.9858093	0.32
227.0255127	2.01
239.1984863	0.54
240.0411987	1.16
245.0199585	30.44
245.7651978	0.32
248.3135834	0.38
263.1281128	2.66
266.0377502	4.96
268.1589966	0.36
282.3235474	0.64
284.1281738	0.17
288.1989746	0.47
289.1903076	0.10
296.0051270	0.85
297.1043701	0.22
307.0786743	0.42
308.0819092	0.65
314.1198730	9.61
317.2342529	0.20
325.1675415	2.75
326.2636108	0.33
332.2365112	8.44
333.3000488	0.36
346.2141724	0.22
347.2053223	0.42
351.4099731	2.17
352.3851929	0.26
355.0639038	0.21
356.0941772	2.02
361.7360840	0.66
362.3444214	1.60
369.2457886	2.42
371.0645752	0.13
373.1941528	6.46
374.0566406	3.98
380.0870361	7.92
381.2971191	0.54
392.6240234	0.19
395.0873413	0.61
399.2332153	6.68
400.1737671	0.09
404.9580688	0.21
407.2119141	0.75
413.0994873	0.38
417.2398071	12.31
422.5209351	0.12
425.0724487	1.06
443.2791748	27.98
446.4301147	0.06
461.2167358	85.37
465.1072388	0.16
473.1458740	4.60
491.1582031	100.00
491.7815552	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1438
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
84.0532303	0.19
86.0127869	24.41
129.9607391	0.89
131.9598846	100.00
134.9606628	0.02
147.9869537	0.87
187.2071533	0.07
198.0014801	4.62
201.2710266	0.05
206.2629242	0.02
214.2931976	0.08
215.2065125	0.44
217.9317627	0.04
225.1357880	0.40
243.0863495	5.21
244.1115723	26.83
251.6059418	0.16
272.1290894	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0855
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.84546661	0.11
78.00584412	0.29
95.1439209	0.59
104.8243866	0.52
106.8928375	0.80
109.3156433	0.21
114.824234	0.24
121.0759277	0.26
122.9647217	0.87
129.0280914	4.46
130.4336395	0.14
135.2458191	0.13
142.8445282	0.22
146.9558868	0.76
150.9030609	58.83
151.9745941	6.16
152.7108459	0.32
154.2257538	0.16
155.0673065	2.13
156.9965363	0.48
157.9876709	0.16
159.1440735	0.29
161.1042633	0.24
165.3094177	0.55
166.1378632	0.34
166.9416656	0.51
168.8813782	0.81
170.0070801	0.72
171.0923309	0.53
177.0755463	0.39
177.9472198	0.10
179.0025482	3.14
180.4522705	0.20
181.2019501	0.10
182.1343842	0.54
183.1294708	0.43
184.0637207	0.77
185.118576	0.36
186.0028992	0.15
189.0423279	0.21
189.9911346	0.51
191.0396881	0.20
193.9251862	1.36
195.1053314	0.12
197.1039124	1.61
206.9812469	0.87
210.1839142	0.85
211.9970245	0.22
217.3758698	0.25
225.1023102	5.44
225.9903107	0.24
235.060257	2.27
238.1086273	10.21
239.0258636	1.31
250.8878174	1.22
253.0905914	100.00
254.1916656	23.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1089.55
Annotation	PS(20:4(5Z,8Z,11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
319.1767578	0.70
437.6913147	0.34
457.3384705	2.15
543.0595703	0.67
544.8870850	1.53
553.3173828	1.24
555.4746094	2.01
557.0241699	0.85
569.5153809	0.89
571.4399414	1.30
589.4703369	13.88
590.5144043	0.97
603.5405273	0.46
631.6489258	0.42
659.4683838	0.51
667.3932495	1.33
668.4783936	0.50
671.3699951	1.47
685.3599243	1.40
687.4449463	0.49
703.5144653	1.27
719.5349121	0.34
729.4176025	0.53
733.6068726	0.49
746.8410645	1.27
751.4476318	28.47
752.4819336	0.74
777.8569946	1.10
793.4448242	2.73
796.3010864	1.48
819.6384277	2.87
820.6759033	0.57
833.7324219	2.27
834.5115967	0.42
847.5015869	1.99
865.4295654	17.87
883.4852295	5.31
884.8548584	2.53
891.3526611	2.75
909.4326172	100.00
910.4788818	5.24
927.3820801	15.36
928.6513672	0.45
935.3720703	1.30
1027.4626460	3.85
1045.2602540	0.69
1071.5189210	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.1526
Annotation	delta-(L-a-Aminoadipyl)-L-cysteinyl-D-valine
Peak:m/z	Relative Intensity
115.6448822	0.13
118.0209656	0.41
118.9400482	1.06
122.0941925	0.03
123.8630066	0.02
130.1204529	0.14
134.4202881	0.01
135.9804382	1.33
150.7768707	0.03
158.5999146	0.01
171.9161377	0.05
183.0500183	0.12
189.1776886	0.23
190.0958252	1.42
198.4574585	0.01
201.8930817	0.08
211.3528290	0.10
215.1685028	0.05
218.0383148	29.62
218.9434814	0.06
223.1825256	0.09
229.0835876	1.68
229.6994019	0.06
233.2842407	0.06
235.0448303	100.00
241.2598877	0.04
247.1048279	7.43
260.0882263	0.04
265.1092529	0.25
275.0232849	0.04
278.1162109	0.04
280.0879211	0.16
282.6919556	0.05
284.4092102	0.04
290.1949463	0.03
297.9028931	0.07
301.0748291	0.09
303.1352234	0.04
304.2929077	0.01
316.4798279	0.06
318.2120972	0.09
328.1315308	0.07
346.2552185	15.48
347.2192688	0.17
352.8915405	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.17
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
113.0089340	0.87
117.0645905	0.30
118.8795319	1.06
124.9057922	0.21
130.7722931	0.28
134.0528259	0.18
137.2769165	0.19
142.1325684	0.11
142.8083954	0.63
145.4633026	0.11
146.9509430	0.84
149.0988312	0.09
158.9882812	0.48
161.0479736	1.00
163.0679321	100.00
164.1619110	0.15
166.1585083	0.24
172.7944946	0.16
173.9692078	0.23
179.0018921	0.36
181.0912018	0.29
191.0312195	2.78
191.9798737	2.01
192.9764404	5.19
207.0707550	1.48
209.1470795	3.34
210.1848755	0.23
211.1209564	0.67
221.1159668	0.11
225.1395569	25.84
247.1532898	0.05
249.2182312	0.35
251.3839417	0.10
267.1121826	0.23
286.9777832	0.35
289.1386414	0.96
321.3207092	0.11
325.3210449	0.07
341.2051697	2.56
342.9350586	0.18
358.7082520	0.32
369.2066345	25.73
370.2207947	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.2979
Annotation	Unknow
Peak:m/z	Relative Intensity
215.1288452	0.02
217.3562317	0.06
221.2866211	0.01
229.3581848	0.01
231.2357635	0.22
233.4154510	0.03
235.0868835	0.09
241.2960205	0.13
243.1378937	0.04
245.1095123	0.03
247.2351074	0.04
251.3701324	0.03
253.4510193	0.04
255.3188171	0.10
257.2131653	0.15
259.5393066	0.04
263.3764954	0.01
267.1540527	0.03
269.2951050	0.15
271.3901978	0.06
272.3717346	0.02
273.2362671	0.09
275.4145508	0.03
283.3430481	0.01
285.2098999	0.95
287.3470154	0.17
289.2868042	0.02
293.3136902	0.08
303.3378296	0.47
305.2624207	0.49
313.3599854	0.01
321.2971191	0.01
331.3702393	1.55
337.1687012	4.91
347.2210083	0.02
349.3422852	0.24
355.1946411	3.86
365.2783203	1.73
367.2312622	100.00
367.8617554	0.42
387.1317139	0.03
421.0424194	0.01
422.4621582	0.04
432.8819580	0.07
438.1364746	0.01
478.7820435	0.03
495.2009277	0.02
525.3583984	0.02
526.2596436	0.02
556.6992798	0.03
558.1181641	0.03
574.0928955	0.10
577.2537842	0.05
613.2067871	0.02
626.7477417	0.09
636.6285400	0.02
673.0593872	0.05
687.3152466	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.1351
Annotation	4'-O-methyl-(-)-epicatechin-3'-O-beta-glucuronide
Peak:m/z	Relative Intensity
145.0536957	0.13
147.1482849	0.03
151.1839905	0.05
153.0408325	0.21
158.9130096	0.08
160.9888916	0.74
161.9612122	0.04
162.9965210	0.17
163.9540863	0.04
165.0076904	0.27
167.1582184	0.26
173.1537628	0.03
174.9962158	0.03
176.9353638	0.07
179.0383301	0.40
185.4403076	0.03
187.0883179	0.07
191.0670776	0.08
201.1184082	0.07
202.4807739	0.13
203.1222839	1.08
205.0021362	0.64
207.1516571	0.05
225.1980896	0.18
227.2337952	0.17
230.1747131	0.04
231.1680603	0.13
239.8062439	0.05
245.1549072	6.71
247.1252899	0.34
251.0476685	0.15
271.1340332	1.26
281.2405090	0.06
287.2073364	0.05
289.0612793	100.00
289.6737976	0.16
313.0396729	0.49
315.3401184	0.04
316.1437378	0.05
322.9830933	0.13
331.1214600	0.72
339.1631775	0.04
340.9031982	1.70
342.9947205	0.08
347.4006348	0.11
349.3511963	0.13
355.1684875	0.18
357.0787048	0.65
369.0874634	0.02
371.0008240	0.05
375.1286926	0.08
389.2629700	0.16
397.2377625	0.11
398.1092834	0.06
399.3012390	0.25
403.2526245	0.07
407.2236023	0.13
409.2623596	0.12
415.1407166	0.22
425.3584290	0.06
433.1394348	1.24
449.1396484	0.20
451.1445618	31.19
451.7609558	0.10
465.3597717	0.03
475.2188110	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	770.2076
Annotation	Unknow
Peak:m/z	Relative Intensity
224.4115753	0.06
236.9891663	0.10
241.3096619	0.18
242.2463531	0.05
259.0163574	0.17
268.0840454	0.29
268.9985962	0.21
270.0566711	0.23
274.1219482	0.19
277.2662354	0.05
279.2456665	0.10
280.1445923	0.04
280.9414062	0.09
286.1098022	3.27
293.2911377	0.14
299.0536194	0.05
302.9475708	3.01
306.2478027	0.29
307.0619202	0.06
317.9783936	4.38
320.0907593	0.94
321.1444397	5.49
327.2029419	0.10
340.9774170	0.12
355.9231873	0.09
386.7804565	0.46
399.0396118	0.03
417.8649292	0.04
431.4890747	0.13
448.1301270	0.30
454.4591675	0.06
465.2568359	0.10
469.0791016	0.25
470.2803345	0.95
479.2512207	0.13
483.2062378	100.00
501.0693359	0.06
505.2330933	0.16
507.2149658	0.07
528.4666138	0.07
546.0172119	0.26
564.2155151	0.15
590.1094360	0.40
608.1879272	1.71
624.8070068	0.10
633.3140259	0.16
639.9852905	0.15
641.1580811	3.31
649.4986572	0.38
650.2799683	0.24
696.6361694	0.21
703.9176636	0.07
710.2082520	0.08
713.1354980	0.58
752.0811157	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1281
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
71.9694443	12.43
114.7845154	0.02
116.4529419	0.05
117.9547577	100.00
118.9844360	0.03
128.9589539	0.11
129.9316254	1.17
148.0472565	0.78
184.1061859	5.70
190.6885529	0.02
201.0056000	1.50
201.8976288	0.03
202.5349884	0.02
211.1127167	0.44
215.0529480	0.02
218.9132843	0.03
229.1276703	7.68
230.1270294	34.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.0881
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9191132	0.85
137.0595245	0.58
147.0200500	3.10
154.0584412	0.11
166.8933105	0.24
173.0170288	2.27
179.3597717	0.05
190.9967499	100.00
196.2312622	0.07
204.9609375	0.06
209.1094055	12.32
223.0997772	0.92
269.0313110	0.07
283.2566223	1.01
288.8614807	0.07
291.3878784	0.08
323.1406860	0.11
353.1927490	0.09
355.3515625	0.17
369.2294312	0.20
370.9825439	0.44
379.2293091	0.25
397.0528259	9.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	192.98
Annotation	Unknow
Peak:m/z	Relative Intensity
74.0534515	0.08
86.9353561	0.05
91.3186874	0.01
97.1905518	0.02
98.7961578	0.02
105.1570129	0.04
107.9732513	0.05
109.7622986	0.01
111.0066681	0.01
115.5697327	0.07
117.1364899	0.04
118.9066620	0.03
123.1849823	0.06
127.5335693	0.03
129.0933380	0.02
133.3006439	0.03
136.4186707	0.01
137.0699615	0.04
145.0736694	0.03
148.0308380	0.03
149.1338654	0.07
151.8467712	100.00
152.9012909	0.02
157.0811768	0.15
162.0229950	0.03
164.4845428	0.20
165.3022003	0.01
169.8757172	0.44
171.9065094	0.23
172.6031036	0.07
174.9117279	0.11
177.6801300	0.02
183.9170380	0.47
184.5359344	0.03
192.9390411	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.48
Annotation	PE(16:1(9Z)/20:5(5Z,8Z,11Z,14Z,17Z))
Peak:m/z	Relative Intensity
233.4268188	0.26
255.3061523	0.17
259.3356018	1.00
275.3007507	1.19
277.2704773	100.00
298.2074585	0.04
400.3949585	0.19
413.1670532	0.14
424.4483032	0.12
456.3134155	2.63
474.3830566	11.47
648.6316528	0.02
674.3383789	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9089813	11.19
212.8685608	9.54
268.1867065	4.37
269.1452942	2.69
270.1444092	7.21
271.3156433	1.24
294.9533997	0.16
296.6613770	100.00
297.3371582	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.2126
Annotation	Gallicynoic acid F
Peak:m/z	Relative Intensity
97.1051636	0.10
104.9241714	0.13
107.1776886	0.58
108.1492157	0.16
109.1067657	0.87
110.1185455	0.08
111.0378723	1.64
112.1609802	0.10
112.9101105	0.26
115.0661697	3.32
118.8460693	0.10
123.1721039	0.73
125.1033936	4.60
126.9593964	0.91
129.0319214	0.54
135.1370850	0.69
137.0798187	0.42
141.2654419	0.25
142.0977173	0.08
145.1286621	0.07
149.0154419	0.45
151.0030823	0.46
153.0485535	0.29
155.1103210	0.66
163.1919250	1.17
165.1806641	2.45
167.2702026	0.37
173.0710754	0.15
175.2060394	0.83
177.2410889	0.65
177.9249878	0.27
181.0899353	2.91
183.1736450	0.85
185.0711823	0.18
189.1682434	0.06
191.1332703	1.30
193.2274475	1.28
195.2060699	4.27
197.2564392	0.75
199.1754761	28.24
200.2490540	0.15
203.0051270	0.49
205.0838623	1.26
209.1063843	17.13
209.8467407	0.04
211.2481384	1.26
212.1614380	0.07
214.1421509	0.11
214.9795837	0.13
217.2430115	0.22
219.0539551	0.25
221.2149963	0.05
223.1461792	1.09
225.0072937	0.62
227.1722717	44.37
228.0430908	0.13
229.1508179	2.81
230.1740723	0.43
231.1356506	1.58
233.2032166	1.03
235.1998901	0.58
235.8769836	0.13
237.1521606	0.48
239.3001709	0.98
241.3188171	1.02
243.1575928	0.06
245.2668457	9.73
247.2326660	0.11
249.2438965	3.51
251.3004150	0.14
252.0071411	0.15
253.3330383	0.45
255.1427612	0.73
257.0639343	0.63
259.2878723	0.81
260.2993164	0.29
261.4598389	0.15
263.2534485	2.75
267.2474365	5.87
268.1345215	0.28
268.9382629	0.13
271.2158203	1.75
272.2703247	0.10
277.3991394	0.55
279.4238281	0.62
281.2394409	1.31
283.1321411	0.23
285.1907654	8.25
286.2894592	0.22
287.2177124	0.25
289.2694702	19.52
293.3243103	0.12
295.2939453	0.12
297.2318115	0.59
299.3652954	0.49
300.1238708	0.22
305.1054382	1.24
307.2039185	27.94
308.1972046	0.81
310.9737854	0.24
313.2034302	0.42
314.4349365	0.06
323.2456055	1.04
325.2274475	100.00
326.3544312	3.50
328.1184082	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.1828
Annotation	Unknow
Peak:m/z	Relative Intensity
143.2378693	0.09
179.0525818	1.00
341.1301270	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1639
Annotation	Pelargonin
Peak:m/z	Relative Intensity
187.0136719	0.02
215.380661	0.07
225.273407	0.03
243.0605469	0.03
247.1052551	0.10
255.1008606	0.04
271.0639038	69.07
271.6716003	0.13
283.0106201	0.04
289.1792603	0.11
318.8114929	0.01
379.1146851	0.08
383.3763428	0.04
399.1708984	0.04
415.3566284	0.02
420.1567383	0.04
422.5841675	0.03
425.1252441	0.15
426.9346924	0.04
433.0661621	100.00
433.6746216	0.26
443.0440674	0.24
455.208374	0.05
463.2329102	0.02
499.2489624	0.02
500.7739258	0.11
531.0630493	0.07
549.0662842	0.04
550.6622925	0.05
559.3608398	0.08
577.1119995	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.3071
Annotation	Unknow
Peak:m/z	Relative Intensity
202.3424225	0.18
223.2723083	0.08
235.1646118	0.33
255.3084106	0.17
273.3823853	0.08
286.0444336	0.12
293.2934570	0.33
294.1796875	0.09
311.2672729	1.88
312.2109070	0.13
317.3312073	0.08
320.1644897	0.28
325.2766724	0.41
335.5018311	0.07
343.3004150	0.82
347.3316040	0.08
351.2017212	0.05
356.1776123	0.13
357.3239136	0.07
367.2996216	0.77
374.7080688	0.06
384.6677856	0.07
385.7066040	0.19
389.3824463	0.11
395.5732422	0.03
419.8426514	0.23
425.6171875	0.08
427.1265869	0.13
451.4644775	0.08
455.3781128	4.31
456.3070679	0.09
467.4095459	0.09
471.2666016	0.23
473.3182373	100.00
474.3772583	1.54
477.3934326	0.12
479.3015137	0.08
487.1926880	0.10
487.7973633	0.07
499.0322876	0.08
499.6452637	0.05
513.2146606	0.16
515.5166626	0.47
516.5408325	0.05
523.4699097	0.05
541.1223145	0.13
543.3669434	0.54
547.2882080	0.22
555.4969482	0.17
559.5681763	0.05
563.3269653	0.23
565.9819946	0.20
569.3654785	0.49
570.7040405	0.04
587.4226685	7.03
588.8810425	0.93
602.8552856	0.02
605.4303589	1.95
613.2160034	0.23
621.2811890	0.15
625.9238892	4.48
631.2658081	8.51
632.4145508	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.2173
Annotation	Rhamnetin 3-rhamnosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
231.1723328	0.23
237.1051788	0.05
239.3582001	0.05
241.0667114	0.19
243.1499481	1.30
244.1147156	0.68
245.0688019	1.48
248.6994781	0.06
251.4682312	0.04
253.0507355	0.30
253.9134827	0.09
255.1208191	2.12
257.0318298	0.43
258.0931396	0.37
259.1452942	0.09
261.1793518	0.18
263.0749817	0.24
265.3180237	0.14
267.1397095	2.33
268.3768311	0.08
269.3299866	0.10
271.2675476	0.51
273.0533752	6.63
274.0621948	4.11
275.1733704	0.77
279.0861816	0.70
283.2652588	0.15
285.1589661	9.60
286.1321411	1.63
287.0343628	4.80
289.0767212	0.06
291.2414551	2.86
292.9154968	0.03
294.9154968	0.82
297.1468811	1.74
299.2169800	0.65
301.2245483	0.18
303.1164856	1.93
305.1009827	0.06
306.9972534	0.13
309.2136841	0.12
311.1661987	0.22
312.9130859	0.90
313.8261719	0.18
315.1102905	0.81
317.2916260	0.14
321.1283264	0.24
325.2177734	0.36
327.0609436	0.67
329.1635437	0.19
331.4287415	0.26
334.1160583	0.08
335.0701904	0.25
337.4525146	0.15
339.1665649	0.21
345.1521606	1.06
347.1563721	0.13
349.2997437	0.70
353.2448120	0.03
355.2521973	0.10
357.0892944	0.05
359.2485352	0.82
361.1410522	0.16
363.1648560	1.27
366.9856567	0.46
371.3370972	0.44
373.1881714	1.11
374.2852173	0.08
375.2387390	1.27
377.1882324	10.83
378.5788574	0.15
379.2503662	1.05
380.1521606	1.04
381.1947632	1.33
382.9357910	0.35
385.1900024	0.26
387.2259521	0.05
389.1773071	0.99
391.2080078	31.90
393.2020874	9.88
394.5971680	0.15
395.2399902	2.28
399.0839844	0.05
401.2620239	5.62
403.1593628	14.70
405.1196289	3.50
407.1131592	0.06
409.0767212	23.62
409.7002563	0.12
410.4609985	0.17
411.1236572	7.43
415.1503296	1.24
417.2189941	0.29
419.0439453	13.64
419.6474609	0.41
421.1744995	30.73
423.1175537	2.87
427.0703735	1.22
433.0787964	5.50
433.7163086	0.13
435.1367798	0.49
437.0775146	1.37
439.0023193	0.62
444.0750122	0.08
445.1547241	0.03
451.1805420	0.97
453.3189697	0.24
463.1541138	0.07
485.2138062	5.33
495.4188232	0.06
497.2243042	0.88
499.1549072	1.85
499.7774658	0.02
501.0253906	0.15
502.5955811	0.49
503.2627563	4.66
505.4479980	0.07
509.1989136	18.22
511.1264648	0.79
513.1550903	0.06
515.2134399	0.03
519.4332275	0.04
521.2283325	0.26
522.9639282	0.09
525.5255127	0.22
527.0786133	31.84
529.0384521	0.86
539.1179199	1.99
541.0551147	0.47
543.1455688	0.47
544.9743042	100.00
545.6749268	0.28
547.2174683	0.32
548.0656128	0.10
553.2415771	0.12
555.0228271	0.70
556.4261475	0.18
557.0378418	3.74
557.6864624	0.18
559.1719971	0.45
560.0593872	0.09
560.9236450	1.52
561.5258179	0.25
563.0308228	30.86
563.7586670	0.06
567.3352051	0.20
569.1281738	0.11
571.2868042	0.56
573.2203979	2.42
574.9884644	4.00
575.6039429	0.08
578.8757935	0.09
585.3402710	0.12
587.1473999	0.42
588.8029785	0.04
604.9697876	0.35
615.3796997	0.09
634.7066040	0.04
637.5092773	0.10
643.3051758	0.18
645.0082397	0.07
647.0542603	1.57
649.1618042	0.19
654.8471069	0.43
655.6022949	0.06
659.0830688	0.03
660.4472046	0.10
663.1592407	1.27
665.0205688	4.80
665.6278687	0.15
667.1823120	3.68
671.0009155	0.03
673.2417603	0.07
679.0928345	0.13
681.1897583	21.61
682.9198608	3.46
683.5369263	0.21
690.3710327	0.18
691.1663818	1.02
691.9026489	0.07
693.2875366	0.25
697.7318115	0.26
699.0321655	11.50
709.0608521	6.93
722.7699585	0.20
778.2640381	0.12
780.8802490	0.04
798.8895264	0.37
817.1094360	4.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	621.182
Annotation	Isocrenatoside
Peak:m/z	Relative Intensity
190.9323120	0.20
193.1002197	0.02
213.2987366	0.08
221.9019928	0.04
229.2232056	0.12
241.2699127	0.02
255.0433197	0.03
255.9860687	0.07
265.1918945	0.08
266.9860229	0.04
278.9079590	0.05
285.0993042	0.21
298.8428345	0.16
299.4482422	0.09
300.1696167	0.42
301.0833740	0.05
305.1969604	0.08
315.1092529	100.00
316.0552979	0.03
333.8699951	0.04
346.4794922	0.10
357.3022461	0.01
369.4674683	0.02
397.1144409	0.02
419.7023926	0.03
445.2142334	0.12
459.1979370	3.96
471.3785400	0.04
476.5614624	2.23
477.2763672	9.36
501.1444092	0.04
505.2925415	0.27
519.1942139	4.54
529.5911255	0.02
540.2252197	0.05
548.5201416	0.05
558.5719604	0.21
559.1953125	2.83
561.0732422	0.08
570.6738892	0.03
576.9367676	0.40
578.4110718	0.03
586.9672241	0.03
598.2334595	0.10
603.2648315	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1129.5437
Annotation	Ciwujianoside D2
Peak:m/z	Relative Intensity
433.3833618	0.03
461.5333862	0.04
481.2442322	0.09
499.0067139	0.03
509.5858765	0.05
521.4114990	0.07
539.4378662	0.05
541.6119995	0.08
609.5185547	0.93
631.6605225	0.13
681.3663940	0.58
698.6065674	0.02
699.4824829	1.28
710.4721680	0.03
717.5414429	0.03
751.6291504	0.04
771.2099609	0.98
789.3007202	0.35
807.6456299	0.10
817.3875732	0.12
823.6257324	0.07
835.3558350	0.03
879.4427490	0.56
895.5534668	0.06
897.5402832	0.04
921.5191650	0.03
923.4663086	0.09
939.4635010	0.14
940.0679932	0.12
969.3361816	0.28
979.3818359	0.77
980.1474609	0.03
997.4780273	0.20
1023.1668700	2.57
1023.7847900	0.17
1031.7746580	0.13
1032.4794920	0.06
1039.2834470	0.03
1041.4165040	100.00
1042.1733400	0.07
1053.1037600	0.01
1067.3955080	0.02
1070.3850100	0.38
1071.5041500	0.46
1084.0805660	0.02
1112.2363280	0.27
1113.4230960	2.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.2061
Annotation	Lysergic acid diethylamide
Peak:m/z	Relative Intensity
97.8503647	0.04
109.0932999	0.04
111.5800705	0.04
120.2477570	0.02
121.1424255	0.03
129.8576965	0.28
146.1566467	0.01
147.1513367	0.01
149.0555420	0.08
156.0484009	0.03
165.1794739	0.06
165.9533386	0.07
167.0788116	0.07
168.2551575	0.03
174.9533997	0.04
180.1346893	0.13
183.9431305	0.39
194.3222351	0.02
195.0425720	0.07
211.3439331	0.07
212.1284790	2.56
213.3173828	0.03
222.2937317	0.02
224.1416626	0.08
225.2467651	0.01
228.2608337	0.01
234.0268555	0.04
239.0382690	0.14
240.1356201	0.18
243.7075806	0.03
247.1790466	0.02
252.2469177	0.06
261.1674805	0.07
265.5883179	0.03
268.1137695	100.00
269.2734070	1.48
278.3139954	0.05
279.1656494	0.08
280.1979370	0.03
281.1434631	0.04
283.1607666	0.04
289.2050171	0.06
291.2921448	0.03
292.8435669	0.02
296.2261963	0.07
306.0199585	0.16
306.8657227	0.01
308.2324829	0.35
309.2392578	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.2052
Annotation	Blumiolide A
Peak:m/z	Relative Intensity
107.1067886	0.08
116.9100342	0.04
120.1769714	0.05
123.0470200	0.01
127.1490479	0.03
129.9952393	0.02
130.9959869	0.03
131.8004761	0.01
133.1181946	0.09
134.8841400	0.05
136.7254028	0.06
138.9726105	0.03
141.1545563	0.07
147.0927734	0.14
149.0833435	0.05
151.0129852	0.07
153.2234344	0.26
155.1932373	0.04
156.2951813	0.03
160.8220520	0.02
166.8239288	0.05
175.3609619	0.01
176.9630127	0.04
179.0156097	0.04
183.3051300	0.03
185.2623596	0.03
187.1542053	0.01
190.9508972	0.14
193.1388245	0.08
193.9892883	0.04
195.2456818	0.03
197.8857727	0.04
200.9402313	0.03
202.8839264	0.02
204.1090851	0.17
205.0623474	0.04
207.2806091	0.09
208.9917603	0.14
211.0537109	0.03
213.0044556	0.01
218.1407776	0.02
221.0908203	0.12
225.1592102	0.11
231.2898560	0.08
235.4431763	0.02
239.1252441	0.05
241.0894470	0.28
242.1383057	0.02
243.3831482	0.09
244.3562012	0.05
245.2000732	0.08
249.1587219	0.02
251.4188232	0.19
252.1293335	0.04
253.3723145	0.10
255.3790283	0.07
257.0865173	0.12
259.2526550	0.49
269.2026367	5.92
271.2265320	0.16
273.1029663	0.08
280.8779907	0.04
285.4362183	0.04
287.1839905	45.11
288.4744263	0.02
289.2902222	0.09
291.8726807	0.43
297.2218933	1.76
297.8261108	0.06
303.1051331	0.30
305.1504517	0.16
307.1941528	0.08
315.0951538	100.00
315.9699402	0.51
322.3171387	0.06
323.6309814	1.95
324.2913818	0.59
333.2133789	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2891
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.0073700	0.57
185.9983521	0.11
205.0548096	1.43
223.0711365	24.93
241.0301666	46.91
259.0409241	0.58
279.2321777	32.55
315.1517029	100.00
333.1422729	7.03
343.0385742	0.17
415.2517090	1.69
433.4201660	0.49
434.6103516	0.19
531.0101318	5.75
535.6463623	0.50
550.2952271	0.18
577.4714355	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.0699
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
92.9668808	0.07
95.0055389	0.02
97.2468185	0.03
104.9607849	0.05
107.0577164	0.08
111.1415100	0.04
112.9992752	0.04
117.1044388	0.03
119.1796875	0.01
120.8954391	5.30
123.0155106	1.14
127.0196381	0.19
130.0589905	0.09
132.8841858	0.04
134.8647766	0.26
136.9013367	0.05
138.9223022	0.12
142.7975616	0.01
147.1661377	0.07
148.7489929	0.06
151.0433502	0.44
152.9034882	1.85
160.9662476	0.03
162.9142761	0.48
166.9318542	0.03
169.4306335	0.03
171.1743774	0.28
177.0481567	0.02
179.1250763	0.08
180.9333191	0.04
184.7554626	0.02
191.0986023	0.02
194.9828186	0.22
199.3604126	0.04
201.3440552	0.02
205.0845032	0.10
211.0670166	0.03
224.9098511	0.11
227.0861511	0.23
229.2427673	0.23
230.0171204	0.02
231.0751038	0.08
243.0895691	3.08
245.1225586	0.12
248.2288208	0.13
252.9645691	0.11
253.9366455	0.04
257.9013367	0.02
259.0707092	0.19
261.1196289	0.58
270.9862976	100.00
271.5903625	0.21
288.2541809	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.15
Annotation	Apiin
Peak:m/z	Relative Intensity
187.3543854	0.15
193.045517	0.19
265.1577759	0.16
269.1362915	0.15
271.0528564	100.00
272.5300903	0.13
307.2868347	0.10
401.8724365	0.21
411.1464844	0.12
413.0820312	0.10
430.3433838	0.29
432.8510132	0.46
433.5204468	0.40
435.1886597	0.10
547.3921509	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	736.48
Annotation	Unknow
Peak:m/z	Relative Intensity
233.3021393	1.42
234.3785095	1.01
240.3503113	0.08
257.0951538	0.16
260.3251343	0.80
261.1304016	0.14
275.3521729	0.99
277.2484131	94.34
278.2527466	100.00
279.2945251	44.44
293.5835266	0.08
295.7227478	0.17
327.0190125	0.08
406.2252197	0.23
456.4531250	0.87
457.2285767	0.61
458.4549561	0.89
474.2443848	6.37
475.2636719	12.22
476.3504028	11.48
479.8920898	0.10
562.4173584	0.08
644.4376221	0.38
676.2974243	0.19
700.4533691	0.29
718.3035278	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	927.3453
Annotation	Unknow
Peak:m/z	Relative Intensity
273.2785339	0.10
281.3010559	0.13
293.3296204	0.24
295.9841003	0.22
297.3920593	0.44
299.2877197	0.20
315.0128784	0.28
321.2363281	0.42
322.9927979	0.18
331.2059326	0.28
337.2834473	0.87
343.1637268	0.18
353.0817566	0.11
355.4625244	0.12
357.0377197	0.18
365.3263855	0.49
369.2896729	0.07
371.3698120	0.69
372.4149780	0.07
384.1793213	0.12
386.6801147	0.24
393.3031616	0.05
400.0254517	0.13
401.2275391	1.64
416.1403198	0.24
423.5251465	0.11
429.0916138	0.06
433.1275635	0.82
442.3421631	0.16
448.1941528	3.05
449.9167480	0.12
454.5199585	0.19
464.2433472	1.83
474.3131714	1.53
476.5007935	0.14
482.3724976	0.39
490.1772461	6.31
491.7623901	0.58
494.6239014	1.28
495.5100098	0.08
506.1705322	2.94
508.2406616	0.60
522.1030273	0.53
526.2821655	0.19
545.3786621	0.46
547.3529663	0.07
558.7221680	0.73
563.2279053	1.45
573.0847168	1.24
575.2500000	0.33
577.1987305	0.11
585.2187500	0.44
587.0698853	0.64
603.0375977	2.00
605.1105347	0.29
607.2733154	0.40
611.2800293	3.56
614.5504761	0.16
621.2839966	0.19
626.3244019	0.66
629.2981567	2.64
632.9086304	0.18
643.2964478	1.62
647.2479248	15.93
647.9218140	0.07
653.5129395	0.14
661.2092285	1.62
668.5563354	0.22
679.2098999	10.17
682.3771973	0.59
684.2730103	0.09
701.6171265	0.21
702.5064087	0.09
712.3198853	24.01
718.7018433	0.31
719.5362549	0.28
725.0580444	0.45
726.3128052	0.39
738.2144165	12.72
742.2661743	0.09
744.0119019	0.35
749.4232178	0.23
756.0535278	7.81
758.0859375	0.79
759.6517944	0.08
765.5451660	0.69
770.1185303	42.89
770.7619019	0.20
771.3902588	0.52
781.3781738	0.09
788.2468872	0.48
791.1352539	1.04
796.3973999	0.22
797.5153198	0.28
801.0534058	0.11
809.3858032	1.70
815.5643921	0.18
823.1892700	0.81
833.5686646	0.74
835.2978516	4.36
841.2223511	1.60
847.2562866	0.59
849.2908325	0.31
851.1619873	5.06
859.1939087	2.84
865.3873291	0.12
867.3178101	5.31
877.1824951	9.40
877.9152832	0.84
883.3307495	0.26
891.1345825	7.05
892.6581421	0.41
895.2344360	100.00
895.9253540	0.13
898.7970581	0.33
909.0637817	8.30
909.7722778	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.1275
Annotation	Robustaside B
Peak:m/z	Relative Intensity
122.9875793	0.33
127.0472183	0.04
132.9762573	0.08
138.9617157	4.03
143.0086517	0.03
144.7486267	0.03
146.9346466	0.93
149.0364227	0.04
151.0001373	3.16
152.0140839	0.04
157.0863953	0.03
158.8331299	0.04
163.0695343	0.12
167.1795044	0.01
172.9833374	0.35
175.0575562	0.10
176.9080963	0.84
179.0029144	0.06
180.8006287	0.04
181.4493408	0.18
184.8157654	0.02
187.1421204	0.10
191.1328735	0.13
193.1452332	0.08
196.9254150	0.03
201.3115845	0.02
203.0287476	0.09
205.1142883	0.03
207.1815796	0.02
211.2206116	0.04
213.0502930	0.12
215.2120972	0.04
217.1658936	0.05
219.2603455	0.03
220.9879761	0.05
227.0542145	0.07
231.1890564	0.06
232.8833008	0.12
237.1076050	0.28
239.1584167	0.12
241.0649719	0.07
243.0166321	0.21
245.0381470	8.28
246.9790649	0.08
253.2044678	0.03
255.1437073	0.91
257.0523987	14.17
258.8836060	0.12
261.1290588	0.15
265.1579590	0.27
267.2042236	0.65
271.0791931	3.33
273.0420837	100.00
273.8378601	0.01
275.2820740	0.09
276.8030090	0.21
279.1023560	0.76
281.2277832	0.03
282.3116760	0.16
283.1417847	0.42
285.0856628	1.69
287.2046509	0.17
291.2350464	0.03
295.0173035	0.15
297.1375122	6.86
303.2300110	0.35
304.5810547	0.06
305.2735596	0.05
309.0318298	0.44
311.1488647	0.05
313.1172485	0.54
315.1346436	1.66
315.9281006	0.07
320.9968872	0.06
323.0515442	0.50
327.3096924	0.13
333.2028198	0.07
339.1061096	2.63
341.1524963	0.57
346.9411621	0.03
351.2026367	0.09
353.4134216	0.15
356.9632263	0.05
363.1327820	0.27
368.2560120	0.03
369.1387634	0.10
370.7782288	0.03
371.3871460	0.04
375.4234314	0.06
381.1952209	0.98
384.0723572	0.03
394.6469421	0.02
399.0507202	4.83
408.3843994	0.05
417.0919495	6.40
419.4028625	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.2367
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
92.8445435	0.11
94.6161118	0.38
106.9341812	0.15
109.1083755	0.42
110.6736755	0.15
113.0245743	0.31
114.9195557	0.18
116.9848480	0.10
119.0518417	0.10
121.0198975	0.25
123.1526794	0.14
125.2090607	0.29
128.9714966	0.16
131.0577393	0.08
132.9898224	0.25
135.1065674	0.32
138.2186279	0.32
145.1255188	0.46
147.0362244	0.23
148.8011780	0.19
150.3155518	0.06
154.9960175	0.44
157.1480103	0.07
159.0998840	0.41
160.1061401	0.42
160.9991608	0.31
163.1285095	0.27
165.0487671	0.29
168.0718231	0.08
169.1460571	0.07
170.8493347	0.06
173.1440582	0.50
177.2017822	0.23
181.0065155	0.23
182.9649353	0.41
184.9956970	0.13
187.1677856	0.23
188.7878723	0.37
191.0711060	0.13
192.2540741	0.09
193.1200714	0.37
195.0283813	0.33
197.1031799	0.22
199.0848541	0.25
201.1831970	0.60
203.1490479	0.51
207.0773926	0.50
212.9217529	1.17
216.6561890	0.13
219.1461792	0.31
223.1364136	0.38
225.0555420	0.35
226.9163513	0.22
232.9488220	0.08
235.0688171	0.10
237.3562317	0.14
239.0191956	0.15
241.1201172	0.77
243.2601013	1.80
246.1761475	0.05
250.9973755	0.31
253.2045593	0.50
254.2337646	0.16
254.9609680	0.73
257.1717224	0.42
259.0915833	0.44
265.1700439	0.25
267.1549683	1.01
268.5579529	0.11
270.1534424	0.36
271.4736938	1.12
275.3981323	0.20
277.1951294	8.00
282.9128418	0.26
285.3747253	0.40
293.2175293	0.05
295.1484375	100.00
296.1947632	0.37
303.7537537	0.12
306.7188416	0.60
313.1149292	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
179.0325623	0.10
203.0210571	1.23
221.1264038	6.75
250.9087372	1.26
263.0905762	0.83
268.164917	1.19
280.1647949	0.32
280.9908142	0.35
305.1155396	0.57
310.2094421	0.08
310.9946289	0.25
315.119751	0.17
320.965271	0.27
323.0093994	3.10
341.059082	28.62
365.4574585	0.14
371.5884399	0.48
383.1265869	100.00
407.4906006	0.15
411.0588989	0.15
412.6175537	1.60
425.2681885	1.79
442.9120483	11.39
467.2034302	0.34
485.22052	26.48
503.0752563	2.98
505.4230347	0.19
535.3067017	0.31
545.3314819	0.48
561.4133301	0.21
581.3734741	0.23
593.5508423	0.11
619.0374756	0.65
647.187439	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0856
Annotation	Gerfelin
Peak:m/z	Relative Intensity
90.7818832	0.14
93.0665436	0.05
94.6681900	0.11
97.8933563	0.05
105.0240784	0.11
108.9447784	0.12
111.0519104	0.12
114.9268799	0.03
118.9036255	0.12
120.8582001	0.10
122.9052658	100.00
126.8525543	0.38
129.1298523	0.02
130.1611328	0.10
132.1484680	0.38
134.8024597	0.09
136.9328308	0.73
138.8866577	94.14
139.5834198	0.07
146.9988708	5.79
150.9113159	25.01
152.9852295	0.35
154.7692261	0.06
159.0161285	0.05
161.9231415	0.06
162.8259735	0.19
164.9881592	48.44
169.0507812	2.28
181.1846619	0.27
186.9968262	0.11
193.3731232	0.09
205.0689697	0.31
207.0036316	0.16
215.1285706	0.02
217.3295593	0.06
219.1147766	0.04
223.8836975	0.07
227.0622253	0.15
231.1492310	0.16
232.9267883	0.06
243.1549683	0.31
244.1187439	0.05
245.2257080	0.44
245.9510193	0.03
247.0701294	0.06
249.0618896	0.57
251.7394409	0.20
253.4296265	0.18
255.0431824	0.39
263.2053223	0.37
264.4095459	0.08
270.8758545	0.15
273.0408630	28.24
274.2290344	0.04
275.9503174	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1822
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
190.1914062	0.10
207.1249847	0.06
257.0352173	0.09
259.0865479	0.13
269.0953979	0.15
275.2379456	0.16
309.3543091	0.06
315.3122559	1.22
325.4227295	0.19
327.0303345	0.10
329.2387085	0.10
331.3723145	0.08
343.3901367	0.15
345.2566528	0.20
357.1316528	100.00
357.7550659	0.21
367.3787231	0.28
369.2005005	1.60
373.1660767	0.10
381.3002319	0.13
385.2327271	0.06
387.2404175	66.63
388.0357056	0.18
393.0692139	0.09
399.1233521	2.44
411.2325439	0.24
413.2095947	0.07
417.2534790	22.82
423.0966797	0.04
425.1170654	0.22
429.1279907	2.09
432.9916382	0.19
435.1463623	0.76
441.3591919	1.44
444.9267578	0.27
446.1809692	0.30
447.1724243	1.05
449.0945435	0.37
453.1096191	0.29
459.2424316	18.78
471.2970581	1.32
477.0984497	64.77
477.7627563	0.20
479.1296387	0.05
489.2768555	14.74
493.2094116	0.21
501.2815552	0.91
507.0974731	5.35
507.7648926	0.02
511.1789551	0.28
516.3345947	0.25
519.4690552	0.40
521.3272705	0.48
525.2450562	0.07
528.6830444	0.27
531.1752319	0.03
537.0620117	0.74
549.2929688	0.80
551.0526123	0.26
552.1784668	0.22
553.0722046	0.42
553.6804810	0.23
561.2536011	3.48
579.1455688	14.55
579.7726440	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1505
Annotation	Gerfelin
Peak:m/z	Relative Intensity
162.3056030	0.02
164.0808868	0.12
164.9817047	0.13
167.1081848	0.07
173.1256104	0.02
174.0818481	0.06
175.1624908	0.20
177.1716461	0.12
179.0917358	0.50
181.1365509	0.02
183.1825714	0.01
185.0381165	0.08
185.9540253	0.02
186.9963379	0.59
187.9342957	0.39
191.0094757	0.03
199.2144470	0.03
200.1700439	0.01
201.4838257	0.18
203.0324707	2.31
204.9929810	1.62
209.1101074	0.04
211.1861725	0.02
212.2805786	0.14
214.0600433	0.01
217.0237274	0.14
221.0744171	0.03
227.0984192	0.55
229.2673645	0.02
230.2139587	0.20
231.0114288	0.44
243.1540222	0.06
245.1541290	7.02
247.0422821	0.43
269.2706909	0.01
271.0883484	0.37
273.2729187	0.03
275.0787964	0.01
286.9337158	0.07
289.0712280	100.00
290.2543945	0.03
299.2392578	0.07
300.1682434	0.09
301.2054443	0.03
311.1455688	0.01
313.2192688	0.01
317.1160278	0.06
329.2617188	0.01
331.2996216	0.54
343.1362915	0.05
352.1281738	0.03
354.1492310	0.01
355.0108643	0.01
381.9285278	0.02
383.2636719	0.02
393.0822144	0.01
395.3120117	0.02
397.3470459	0.02
406.3792725	0.07
407.1686401	0.01
408.3763428	0.08
412.2866211	0.01
416.3956909	0.06
420.0742188	0.05
423.1687012	0.08
425.1539917	0.02
426.5462646	0.26
427.3214111	0.93
433.2832031	0.04
435.1030273	0.02
439.4973145	0.03
441.2189941	0.04
451.2891235	0.78
452.3218994	0.08
453.0642090	0.01
469.2141724	2.65
485.0889282	0.01
489.0373535	0.08
490.3678589	0.03
492.5452271	0.01
499.4340210	0.03
515.8013306	0.01
517.2867432	0.06
533.2449341	0.10
534.7597046	0.16
535.4463501	0.19
560.0678101	0.34
561.1831055	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0718
Annotation	Gerfelin
Peak:m/z	Relative Intensity
82.8920288	0.06
92.8790588	0.10
95.0679092	0.02
96.8115845	0.19
107.1531982	0.03
108.8741226	1.20
121.0158234	0.17
123.1105194	0.71
124.8848648	3.09
125.5174713	0.11
135.0955811	0.26
137.0652161	3.37
138.7665100	0.29
143.1865540	0.05
145.2738953	0.05
147.1117554	0.06
149.0512085	0.36
151.0599670	1.33
158.1913147	0.02
159.0387421	0.30
161.1421814	2.31
162.0503235	0.34
163.0122681	0.33
163.9666901	0.69
165.0848694	3.21
167.0743713	1.46
173.3168793	0.02
174.9940796	0.96
176.9531708	0.19
179.0506897	11.76
180.0306702	0.05
185.1921997	0.16
186.0138092	0.43
187.1384888	1.51
188.0152283	1.05
188.6592712	0.06
191.0743713	0.03
199.1643372	0.03
201.1905212	0.30
202.2294617	0.57
203.1394348	6.90
204.9920959	36.12
206.3165894	0.06
212.4777222	0.05
217.1934204	0.52
218.8953247	0.02
221.0584717	0.33
227.1723633	1.43
229.0414124	0.12
230.4954224	0.85
231.1445007	7.29
245.0686646	100.00
245.7460632	0.29
247.0883179	5.50
253.2943726	0.07
260.8669739	0.04
271.1142883	4.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1821
Annotation	1-(3-Methylbutanoyl)-6-apiosylglucose
Peak:m/z	Relative Intensity
131.1383820	0.03
381.1913147	100.00
381.8596191	0.14
383.2638855	0.07
389.3667297	0.02
391.2282715	0.02
409.2171936	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	546.2889
Annotation	Unknow
Peak:m/z	Relative Intensity
156.9955750	0.02
161.1007385	0.01
165.0802612	0.16
169.2815704	0.08
177.0567932	0.07
182.9268646	0.10
184.7866669	0.04
188.8956146	0.05
194.9191589	0.21
197.0641327	0.08
199.0588379	0.04
206.2863007	0.04
207.0352478	0.14
208.1322021	0.05
209.0693054	0.10
211.0527954	0.07
217.1595154	0.14
220.9821930	0.03
223.1326141	0.09
225.1965179	0.05
226.6143341	0.19
227.3025513	0.19
229.4306946	0.04
232.1445770	0.02
233.8248291	0.05
237.2236938	0.07
239.3470764	0.37
241.1939087	0.24
242.9846497	0.02
243.9015808	0.15
245.1091003	0.86
245.9644470	0.03
247.1301880	0.02
249.2142944	0.29
255.1220551	0.36
257.0087280	0.30
260.5630188	0.05
263.0696411	0.70
267.1387939	3.95
267.8458252	0.16
269.2902222	0.17
271.9885864	0.78
273.1470337	0.14
273.9776611	0.09
275.2563782	0.70
277.2133179	0.04
285.1320190	4.77
285.7606812	0.01
287.2908325	0.10
295.1785278	0.41
296.9236450	0.03
299.9782715	0.04
301.0816345	0.49
303.2769165	3.34
304.1417847	0.06
310.1832581	0.02
313.1164551	11.47
314.1454468	0.03
315.3826294	0.02
319.1181030	0.19
321.1473389	9.24
322.1660767	0.12
324.3910522	0.03
331.1505127	11.87
337.0941162	0.06
347.6857300	0.21
349.2799072	17.24
365.3773804	0.08
367.1613770	100.00
378.0099487	0.20
384.1847534	0.26
388.0096436	0.01
390.9598999	0.03
392.2305298	0.09
393.8309326	0.14
394.5169678	0.06
398.7965698	0.02
400.2334595	0.11
407.4787598	0.02
409.0150146	0.07
410.3291626	0.60
411.1287231	0.01
417.2182007	0.36
419.1389771	0.06
420.2263794	0.25
433.3409424	0.02
434.2603149	0.03
437.2606812	0.04
439.0653687	0.01
456.0350342	0.02
458.0788574	0.03
467.3314209	0.02
486.4658203	0.08
493.0299683	0.02
500.2227173	0.07
502.5642700	0.05
508.4386597	0.07
510.0932007	0.05
510.8182373	0.04
511.4241943	0.18
528.2115479	0.50
529.0921631	0.04
530.2908325	0.04
532.1179810	0.03
537.2573853	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	640.3018
Annotation	Balanitesin
Peak:m/z	Relative Intensity
301.2332153	0.47
302.1831055	0.71
337.3173218	0.04
449.9716797	0.03
453.5391235	0.02
463.4656982	0.05
464.1453247	0.13
473.1610107	0.01
518.3067627	0.06
578.3442993	0.01
580.1881104	0.03
608.2529907	0.07
617.3538818	100.00
618.5182495	0.34
619.3388062	0.12
620.0199585	0.01
621.0249023	0.02
621.6702271	0.10
622.2853394	0.05
623.3081055	0.04
626.7616577	0.02
631.7273560	0.02
644.0874634	0.02
713.5409546	0.02
731.4326782	0.13
875.4879761	0.09
893.7208862	0.02
911.1306763	0.04
940.7124023	0.02
941.5553589	0.01
970.1026001	0.07
1011.4138180	0.03
1055.4823000	0.13
1073.4785160	1.32
1120.4274900	0.02
1235.3719480	0.37
1236.0648190	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.0474
Annotation	Unknow
Peak:m/z	Relative Intensity
171.9616241	0.49
191.0244904	3.67
197.7303619	0.14
199.9022522	36.18
213.8245697	0.65
216.0153351	0.72
223.1361694	0.57
224.0395660	0.13
230.1047516	0.31
232.0607300	0.36
234.0075684	0.35
239.9731750	0.15
240.8701782	0.08
242.1206055	0.50
243.9907837	1.10
250.0627594	0.21
255.3170776	0.21
256.1833191	0.68
258.1077881	0.58
260.1630249	0.49
261.8151550	0.76
271.4188232	0.10
272.1517029	0.57
274.0673828	1.14
286.0150146	4.79
288.2246704	0.16
290.0802612	0.96
290.8916016	0.67
300.1413879	0.17
302.2885742	0.45
303.9790039	100.00
306.0339355	0.58
315.9686890	7.56
317.7312622	0.18
320.1134644	0.97
332.2675171	0.57
333.4132690	0.17
334.0697021	11.24
335.0788574	0.18
336.0214233	0.26
346.1239014	0.12
348.1791992	0.08
358.0502319	0.20
364.0214233	2.98
375.9028320	0.36
378.1580811	1.03
393.9760742	0.83
395.0100708	6.56
396.1270752	66.11
405.9868774	40.05
406.5934448	0.17
412.0289917	6.95
424.0469971	35.41
435.8764038	0.67
436.4937134	0.62
437.2436523	0.08
452.1744385	87.43
454.1484375	1.82
465.3229980	0.49
466.0254517	0.17
466.8877563	0.27
479.6506958	0.66
480.4248657	0.38
482.0655518	57.30
482.7787476	0.20
488.0879517	0.30
495.9780273	7.03
498.1286011	33.36
522.1641235	0.19
524.0695190	0.71
526.0493164	0.95
539.0595093	0.06
540.2106934	0.22
542.1090698	10.76
550.1469116	1.12
554.1574097	0.25
566.9166260	0.10
568.0855103	40.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2731
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.0728607	1.10
204.6914673	0.51
223.0330200	31.19
233.3703613	0.37
241.0730896	57.78
259.1474609	1.63
277.3297119	27.93
315.1540833	100.00
316.1316528	1.36
333.1553345	10.75
413.3394775	2.24
431.1400146	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0988
Annotation	Quercetin 3-(6''-ethylglucuronide)
Peak:m/z	Relative Intensity
151.0609436	0.70
153.3220367	0.04
157.2393799	0.08
164.8139954	0.01
171.7465057	0.04
173.0160370	0.03
174.1694641	0.02
177.1708069	0.08
178.9490662	2.14
182.9806824	0.04
184.0879974	0.04
189.3108215	0.16
190.1285400	0.23
190.9280090	0.09
192.0746460	0.02
192.9323120	0.07
196.9244080	0.02
199.2977295	0.10
203.1230774	0.02
206.3428650	0.01
207.0469971	0.08
209.0544128	0.12
210.0626526	0.07
211.1731110	0.18
212.0548248	0.02
213.0201569	0.06
215.1679230	0.03
217.0643463	0.07
219.0101929	0.01
223.0464783	0.03
225.3238831	0.11
227.1355743	0.09
228.1852417	0.02
228.9054871	0.15
230.6746063	0.01
233.1676636	0.06
239.2926788	0.08
241.1929474	0.05
245.2117004	0.04
247.2103271	0.09
254.0320740	0.05
255.0637207	0.91
256.0182800	0.02
257.1524658	0.31
265.1994629	0.06
266.0845947	0.04
271.0909729	1.95
271.9634094	0.32
273.0670471	0.49
275.3415833	0.05
279.2363892	0.03
281.0341187	0.12
283.0613708	0.21
293.0799255	0.04
295.1774902	0.11
296.8974915	0.18
297.6012573	0.02
300.0827942	48.17
301.0606995	100.00
302.1110840	1.01
303.1110535	0.05
309.5528870	0.02
311.0641174	0.04
313.0791931	0.57
323.5083313	0.15
325.1509705	0.42
326.3256226	0.03
327.2188721	0.03
329.2536926	0.05
333.5444946	0.02
337.1419067	0.01
341.1047974	0.16
343.0395508	2.52
343.6688843	0.03
344.5358887	0.07
345.2935181	0.07
353.1812744	0.10
355.0767517	0.22
361.1927185	0.01
367.0870361	0.03
368.9105530	0.03
373.1646729	0.74
374.3300171	0.18
379.1597900	0.13
395.2342529	0.23
396.1195984	0.07
401.1890564	0.05
403.2492981	0.05
409.2665100	0.19
411.2373962	0.07
416.9758301	0.03
427.2382507	0.07
431.1211853	0.04
435.0694580	0.07
443.2610168	0.02
445.2183533	3.93
446.1910400	0.04
457.4080200	0.05
459.0024719	0.03
461.0965271	0.60
463.1377258	24.18
464.0807800	0.37
469.2568665	0.12
474.3786926	0.02
477.1590271	0.05
486.3371277	0.34
487.3251038	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2145
Annotation	Lychnose
Peak:m/z	Relative Intensity
179.3038635	0.40
203.2265625	0.24
221.1406860	5.45
232.9813538	0.13
234.0900116	0.16
235.3331451	0.22
250.6061707	0.48
251.2174072	0.07
262.9642944	1.12
272.7233276	0.07
280.9278870	1.35
303.0902100	0.18
305.1970215	0.73
310.6387329	0.08
311.4573364	0.16
323.1314697	3.72
328.2161865	0.58
341.0039062	22.94
346.2412109	0.30
365.2019653	0.25
383.1433716	100.00
383.9703979	0.05
384.9939575	0.25
397.1241455	0.11
398.1726685	0.38
400.0595703	0.18
401.3179321	0.08
408.1365356	0.72
409.0408936	0.12
412.3489990	0.44
413.0496826	0.66
424.5794678	0.27
425.2082520	1.45
437.4140015	0.14
443.0031128	16.40
454.9453125	0.23
467.1527710	1.43
473.1192627	0.20
485.1497803	19.55
503.0426636	2.10
528.2859497	0.13
536.1433716	0.19
545.2182007	0.64
576.9682007	0.42
600.7842407	0.07
617.4618530	0.09
619.0642700	2.48
628.8706055	0.06
635.2816772	0.71
645.0927124	0.13
647.1912231	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.2061
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
130.1531830	0.35
130.7646332	0.08
135.1439667	0.05
144.9369965	0.62
149.0174713	0.18
152.7292480	0.14
163.0011749	0.27
165.3805847	0.13
167.0978088	0.77
173.1278992	0.08
191.1147919	3.12
196.9895172	0.07
209.0697937	4.13
211.2084351	0.18
213.1141510	0.11
216.2244263	0.03
227.0925293	100.00
238.1956482	0.09
243.9803772	0.08
259.1374817	0.05
271.2596130	0.07
273.9085693	0.03
282.0606384	0.13
292.2162476	0.17
295.1494446	0.71
299.9054565	0.04
303.2691040	0.04
310.4749756	0.05
324.5989990	1.73
325.3404541	0.08
327.2229614	0.09
332.7875671	0.12
347.3793335	0.14
349.5489502	0.06
353.1923523	0.03
356.9821777	0.12
361.3121643	0.05
370.3381042	0.09
371.1616516	0.34
379.3978577	0.21
384.0253601	0.06
385.8156433	0.16
386.9148560	0.10
387.5994263	0.77
388.3047180	8.16
388.9197693	9.35
397.3724670	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3223
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.2025452	0.16
183.9868164	40.09
240.3270569	0.44
258.1826477	0.95
261.4634399	0.07
305.4912720	0.11
317.2689209	0.04
335.1013184	0.06
441.2194824	0.12
500.3359985	100.00
500.9451294	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1637
Annotation	Pelargonin
Peak:m/z	Relative Intensity
229.2908173	0.03
243.2982025	0.03
255.309906	0.04
261.287323	0.05
263.1115723	0.10
271.065918	78.86
279.0136719	0.02
281.0303955	0.03
289.2441406	0.06
301.1949463	0.04
303.093811	0.06
304.201355	0.15
311.2816162	0.07
333.2633057	0.03
367.3499756	0.12
373.0164185	0.02
375.4177856	0.09
376.9251709	0.07
391.3897095	0.12
392.2717285	0.16
397.0429077	0.16
409.675354	0.10
415.2537842	0.66
419.095459	0.04
425.0092773	0.16
427.0770264	0.03
433.0703125	100.00
433.6720581	0.27
434.8475952	0.03
437.3881836	0.11
439.1151733	0.06
442.8966064	0.06
449.1364746	0.15
457.1931152	0.04
459.22052	0.08
466.2553101	0.13
496.8242188	0.04
508.758606	0.12
526.3087769	0.07
531.3417358	0.20
541.5452271	0.13
551.1902466	0.05
553.8296509	0.02
577.0388794	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	636.3864
Annotation	Unknow
Peak:m/z	Relative Intensity
197.2003021	0.10
208.0746613	0.10
212.9941254	0.14
215.2394867	0.68
226.2011719	0.10
233.0356293	0.13
257.2822876	0.12
260.9750366	0.03
262.8841248	0.11
264.3260498	0.11
265.0987549	0.09
300.0619507	0.05
306.4099121	0.15
313.5404053	0.08
319.0569763	0.05
323.3971558	0.19
324.0668640	0.31
327.2024231	0.11
337.3767090	0.31
338.3267212	0.08
339.2734375	0.11
362.0878906	0.48
366.1193237	0.09
368.6099243	0.06
374.0193481	0.12
375.1898804	0.17
380.2416382	1.37
386.1193237	0.20
390.4557495	0.04
391.6676636	0.15
398.2465820	0.15
402.1522217	0.09
403.6228027	0.06
410.4003906	0.18
417.3613892	0.20
426.4919434	0.25
442.3340454	0.13
445.2977905	0.05
447.4938965	0.09
448.0947266	0.22
456.2608643	0.26
458.4528198	0.07
459.1015015	0.20
464.2739868	0.19
465.4814453	0.08
477.3574829	6.95
478.1447754	0.05
479.5161133	0.05
482.4327393	0.05
484.6140747	0.33
488.1431274	0.07
495.4100342	100.00
496.6627808	0.21
497.5433350	0.35
520.4262695	0.42
533.5177612	0.45
538.5856934	0.07
542.4844360	0.39
555.5852051	0.10
566.4551392	0.07
574.6881714	0.19
577.1593018	0.20
591.7686157	0.14
594.8243408	0.08
600.2816162	0.59
604.1258545	0.04
605.2162476	0.18
618.3946533	34.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1768
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
135.1734467	0.06
142.7868042	0.50
145.0060120	0.05
147.0750427	0.07
148.4764099	0.03
154.9992371	0.59
160.9699402	0.62
163.1458740	6.28
187.1535339	0.16
205.1395111	0.25
207.0725708	16.73
208.0062561	0.03
220.9881287	0.05
225.1363220	0.91
248.3897705	0.22
249.1345825	0.18
287.2754211	0.26
291.2650757	0.12
296.7875977	0.09
303.3930664	0.09
309.1793213	1.09
326.8497314	0.09
355.2578125	0.06
365.3611755	0.06
369.1891785	40.26
370.5293274	0.07
383.2395935	0.19
387.1990967	100.00
387.9432068	0.41
411.1056519	3.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0882
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
149.1580811	0.01
150.9388428	0.74
153.0686646	0.04
163.29245	0.01
165.0662079	0.06
168.9604034	0.01
179.0548401	1.29
187.150116	0.02
188.845932	0.14
190.1293335	0.22
191.1461487	0.05
192.0765381	0.03
192.9685669	0.11
197.2156067	0.02
205.0050964	0.03
207.1731262	0.03
211.1973267	0.02
213.1175232	0.04
215.0812073	0.03
217.0942993	0.10
221.1309814	0.07
225.9967957	0.04
227.0565033	0.11
229.1680603	0.07
233.1368713	0.03
236.9686127	0.02
238.800415	0.02
240.1714478	0.03
241.2080078	0.06
242.0457153	0.05
251.3859253	0.06
254.3617554	0.19
255.1257019	0.35
255.9562073	0.05
256.9062195	0.02
259.2386169	0.12
269.1378784	0.02
271.1607056	0.42
273.0843506	0.40
273.9536438	0.02
283.026825	0.13
285.2197266	0.06
286.9683228	0.01
295.3434448	0.02
297.2119141	0.01
300.0101013	25.08
301.0440979	100.00
301.9896851	0.97
309.0086975	0.03
310.9608154	0.06
312.960083	0.68
314.1542358	0.05
315.3016357	0.08
319.0927429	0.18
325.1783142	0.17
329.3041687	0.02
337.1447144	0.03
340.2593994	0.04
341.4266968	0.04
343.1954041	2.00
344.0593872	0.10
355.2835083	0.07
373.2672729	0.23
375.1479187	0.02
376.3695068	0.01
377.1673889	0.12
381.4385376	0.05
403.1563416	0.09
416.9152527	0.15
436.1960754	0.02
445.2727356	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.2263
Annotation	EI-1511-5
Peak:m/z	Relative Intensity
150.0081177	1.08
151.3323975	0.06
157.9431763	0.02
167.2835236	0.05
176.9277344	0.07
197.0880737	0.34
210.0935516	0.03
214.0963135	0.05
216.0174408	0.11
217.0649719	0.06
225.1377258	0.06
226.2831726	0.03
243.1926270	5.26
245.0764771	0.09
255.1881104	0.03
261.0776367	1.75
262.0530396	0.52
270.3394165	0.08
271.0490112	0.44
272.0627441	0.34
273.0375366	0.51
274.0732727	0.02
279.1311646	14.34
280.1497803	0.02
282.1544800	0.02
296.3040771	0.04
298.1498413	0.52
311.1323242	0.06
323.1957397	0.01
328.9350586	0.03
338.9829712	0.02
344.0661621	0.09
346.2377319	0.17
354.2758789	0.08
356.1704712	0.26
357.2269287	0.35
359.3379517	0.16
372.2374878	0.47
374.1026001	1.44
375.0568848	0.04
390.3441162	0.19
392.1695557	100.00
392.7761230	0.52
408.9164429	0.02
425.1506348	0.03
427.4785767	0.08
439.9143677	0.11
446.0949097	0.02
455.1230469	0.04
457.1354980	0.04
458.3238525	0.29
460.0773315	0.10
467.2559204	0.02
475.4033813	0.16
477.1522827	0.04
485.3170166	0.19
489.0487061	0.03
503.3041382	3.61
504.4396362	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1473
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.8509674	0.72
165.0226440	0.80
179.3053894	0.06
181.1708221	0.42
183.2213135	0.21
186.9396667	0.48
189.1758270	0.48
190.0867310	0.13
193.0138550	0.19
197.2118683	0.09
198.9675903	0.04
201.1295929	0.70
203.1722870	0.06
205.0327148	0.82
207.0809937	0.37
211.1992798	0.30
212.9791412	0.21
219.1996765	0.05
229.0704498	1.94
231.0528870	0.28
232.9611206	0.69
243.1130066	0.95
244.9299927	0.53
247.0573578	19.09
248.5094604	0.04
253.0450287	0.40
254.9728546	0.56
257.1341553	0.93
259.1876221	4.84
260.2092285	0.07
261.1026611	1.03
265.4658203	0.13
269.1160278	0.40
271.0948792	14.80
273.0456848	7.52
275.0981750	9.05
277.2571411	0.07
283.0958252	4.92
285.2156372	3.80
287.1229858	11.04
289.1221619	29.22
291.0812988	52.73
291.7115479	0.39
295.2462769	0.34
297.0526123	0.31
299.0735474	4.06
301.1452637	29.24
303.1915894	7.51
311.0328979	0.59
313.0989380	5.79
315.1973267	1.72
317.2526245	0.48
325.0565186	1.13
331.1486206	0.44
333.2353516	5.05
343.0711670	0.08
378.0529785	0.12
389.0834961	0.07
391.2633057	0.85
393.2711182	0.24
397.2189941	0.18
405.0720825	0.16
407.3961792	1.42
409.0747070	100.00
409.8541260	0.42
411.2465820	22.24
417.1961670	1.82
421.1852417	6.74
423.1244507	4.72
425.1191406	0.11
425.8388062	0.16
427.0661621	84.93
427.6842651	0.39
433.0613403	0.41
435.1967773	40.33
439.1676025	10.63
441.2802124	0.87
450.6077271	0.14
451.2837524	1.02
453.0565186	54.97
453.7686157	0.36
467.6245117	0.70
515.0863647	0.43
543.1195679	2.60
561.0722656	57.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.1453
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
157.9174500	0.17
159.2698059	0.12
160.6504974	0.33
163.0701599	0.30
164.0375366	4.29
165.0534058	0.78
167.0031128	0.03
171.1949310	0.12
176.1955261	0.24
176.9856415	0.06
179.0828247	0.17
183.0218353	0.19
185.0031738	0.60
185.9859009	0.50
187.0837708	1.83
189.1587372	0.93
191.1665039	0.06
193.1218414	0.08
201.1883545	0.33
203.1495667	0.34
205.0626221	0.13
207.9572296	0.06
214.7386780	0.22
217.1391907	0.14
219.0671387	0.41
221.2092438	0.67
222.8967590	0.08
227.1246338	0.55
228.1878510	1.41
229.1493073	2.88
231.1105804	0.62
245.2772827	0.26
251.2324982	0.18
254.0910187	0.22
255.1340179	1.16
260.7529907	0.34
268.5466919	0.21
269.3446655	0.31
271.1450806	27.99
273.0627747	60.86
281.1952515	0.17
283.0974121	1.85
285.0487061	0.81
297.2317810	0.06
305.2626343	0.07
311.1349487	0.35
312.1814575	7.59
313.1851196	8.39
315.3130493	0.18
316.9317017	0.14
320.2899780	0.54
321.9791260	0.07
323.2910156	0.57
325.3099976	0.17
333.5212402	0.04
337.1671143	0.26
342.4181519	0.14
353.0151367	0.43
357.2929688	0.23
365.3007202	3.83
367.2872925	0.33
369.3423462	0.03
375.2478027	1.24
376.3170776	0.19
377.2395630	0.08
381.1809082	0.04
391.2121582	8.84
394.3319092	1.31
395.2595215	0.45
399.3331299	0.07
401.4761963	0.32
407.4943848	0.09
409.1426392	32.31
409.7571411	0.09
417.1815796	0.40
419.1808472	100.00
420.1562500	0.09
421.3321533	0.05
433.1683960	0.35
441.1469727	0.04
442.9923096	0.14
447.0625000	0.11
457.4700317	0.14
461.3190308	0.18
480.8513184	0.10
483.1627808	0.87
485.0803223	0.07
498.4902344	0.08
501.2008667	5.17
509.2662964	0.82
515.3433228	0.35
527.1756592	25.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.2807
Annotation	Taxumairol L
Peak:m/z	Relative Intensity
199.0059204	0.12
201.0069275	0.09
203.1418152	0.13
212.7693329	0.13
217.0398254	0.45
221.1589813	0.06
229.8210449	0.03
237.2045898	0.26
237.9216003	0.09
240.5982056	0.13
245.9402466	0.07
252.1399994	0.06
253.2661438	0.81
255.1270447	0.11
258.2050171	0.19
259.0612183	0.62
260.8665466	0.08
269.2071838	0.10
271.2596741	0.90
277.0979614	1.49
294.3410645	0.05
295.0394287	0.05
300.9483032	0.05
309.3085632	0.06
311.2773438	0.20
315.2194214	100.00
319.0980225	2.83
326.4175110	0.07
329.5508728	0.27
337.1848145	5.97
338.1931763	0.12
347.4649048	0.24
355.1701660	0.21
356.2347412	0.20
363.3253174	0.09
366.9698486	0.10
371.2805176	0.09
377.1409912	0.24
387.4518433	0.03
388.1946411	0.20
393.2109985	0.14
402.2797241	0.21
415.0129395	0.12
457.0463257	0.05
463.3209229	0.07
476.3321533	0.10
477.3488770	0.08
482.6082764	0.58
491.3731689	0.08
504.5950928	0.11
517.3511353	0.09
518.5689697	0.10
519.9288940	0.15
524.2534790	0.17
525.2412720	0.16
527.4078369	0.17
553.7475586	0.04
563.5180664	0.10
573.2388306	0.22
579.4004517	0.03
593.4708862	0.88
594.7985229	0.04
605.0391846	0.22
607.1616821	0.43
609.3273926	0.13
617.1886597	0.52
622.4987183	0.23
635.3331909	0.98
653.4318237	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1401
Annotation	Gerfelin
Peak:m/z	Relative Intensity
159.0969238	0.16
159.8078766	0.03
161.1437531	0.02
162.1225586	0.05
164.0352783	0.70
164.9480743	0.26
166.8598938	0.20
174.1548157	0.08
174.9472656	0.17
177.1161499	0.03
178.9497375	0.64
181.0384979	0.11
185.1876373	0.24
186.3309631	0.04
187.2015991	0.73
188.0590515	0.48
199.0580902	0.11
200.1165009	0.05
202.1173706	0.05
203.1582336	1.96
205.0984039	1.80
209.1888123	0.02
212.4085846	0.14
214.0978546	0.05
217.0731201	0.10
218.9078674	0.11
221.0743561	0.04
225.3026733	0.03
227.3788757	0.03
228.0434265	0.08
229.1617737	0.39
230.0881653	0.21
230.9383850	0.31
240.0754852	0.03
243.1162720	0.34
245.0924225	7.98
247.1924591	0.48
252.9963837	0.38
255.0031433	0.04
259.2315674	0.10
271.0914307	20.98
273.1384888	3.09
283.1552734	1.74
284.1794739	0.05
285.1816406	0.38
287.1591187	1.04
289.0463257	100.00
290.2575684	0.06
295.0294189	0.08
297.2670898	0.05
298.3931885	0.14
299.1479492	0.72
300.0169373	0.07
301.1668701	0.09
310.0878906	0.06
312.1435547	0.08
313.2189941	0.08
323.0895996	0.02
327.4331665	0.56
328.3760986	0.92
329.1729736	4.16
330.0504761	0.03
331.2147217	0.05
339.1325684	0.27
341.1925659	0.70
343.3605957	0.03
349.5658569	0.09
351.2771606	0.27
352.3543091	0.29
355.4653931	0.11
363.4039307	0.09
364.9054565	0.08
366.1636353	0.13
367.2266235	0.13
370.8819580	0.05
375.1600342	0.14
377.2094727	0.07
379.1695557	0.34
380.1463623	0.33
381.1220093	2.86
383.6396484	0.09
387.1379395	0.13
388.1557617	0.06
391.1628418	0.65
393.2019043	0.95
395.0019531	0.06
397.2683716	0.03
398.3843994	0.11
407.2111816	18.37
409.1022339	8.60
410.3978271	0.34
411.3751221	0.11
413.2293091	0.17
415.4259644	0.22
417.3398438	1.08
422.1061401	0.06
423.0984497	0.33
425.0847778	24.45
425.6928711	0.14
431.4965820	0.24
433.3078613	0.59
435.1768188	39.93
437.4674072	0.05
439.3071289	0.02
440.3084717	0.11
449.2357178	0.10
451.1825562	0.37
451.8022461	0.03
459.0598755	0.24
467.4624023	0.15
475.3045044	0.47
477.0366821	0.60
483.3672485	0.55
484.0153809	0.22
485.1887817	0.28
490.2379150	0.12
491.2798462	0.04
492.7285767	0.83
493.4050903	0.12
499.2458496	0.72
500.2186279	0.22
513.9456787	0.07
514.8766479	0.18
517.1539917	1.18
518.4852295	0.20
520.6963501	0.35
525.2723389	0.70
526.4404297	0.04
537.5629272	0.12
538.7229614	0.03
543.1635742	29.29
543.9846802	0.37
545.4812622	0.21
551.6644287	0.42
566.1875610	0.04
570.8965454	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.0992
Annotation	Unknow
Peak:m/z	Relative Intensity
118.9371109	0.11
129.1268311	0.10
191.0922089	0.07
195.0064697	0.03
212.9045410	0.28
222.1425018	0.05
232.0090027	10.90
234.0703125	0.06
242.2254028	0.09
251.0835571	100.00
259.7336426	0.04
267.8121338	0.03
269.0140991	0.03
277.1990662	0.03
278.0834961	0.02
320.0822144	0.05
321.0779419	0.04
321.8981934	0.26
346.1751709	0.33
360.1339417	0.49
363.0816956	0.10
364.3359375	0.03
370.6966858	0.02
387.1561584	0.03
388.5357971	0.31
389.4241028	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1304
Annotation	CMP-8-amino-3,8-dideoxy-beta-D-manno-octulosonate
Peak:m/z	Relative Intensity
218.9409485	0.63
245.0656281	0.13
306.7243652	0.05
320.7932129	0.05
357.7610474	0.13
363.1190186	21.53
371.6679077	0.10
381.1105957	100.00
382.2203369	0.41
461.3050537	0.28
483.3497314	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.2213
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1144562	0.23
171.1546021	0.12
176.7933350	0.05
180.7671509	0.95
191.0949707	0.05
193.2170410	0.05
210.9599609	0.05
217.1123047	0.18
222.4094238	0.08
223.2620850	0.06
225.0584412	0.25
229.3737030	0.41
235.3820496	0.06
240.9603271	0.47
247.0807800	0.29
251.8518677	0.21
252.7464600	0.28
253.4255524	0.35
258.8685608	0.72
261.1986694	0.09
270.9263916	5.22
276.2538757	0.18
276.9154358	0.17
288.7800903	9.11
289.5115051	0.21
295.1743164	0.05
298.7641602	0.06
306.1064148	3.66
306.9084473	5.09
324.2404175	13.20
324.9628906	100.00
327.0475464	0.04
334.8511963	0.06
336.3478394	0.17
338.0738525	0.07
339.1104126	0.22
340.0332031	0.16
342.1920776	18.47
342.8818359	64.93
343.5918579	0.17
360.9236450	0.03
396.9448853	0.12
403.0273438	0.15
409.3424683	0.06
411.0187378	0.22
414.2266846	0.40
414.9219971	0.22
419.0161743	0.04
420.8023682	0.64
432.0695801	11.75
433.3336182	0.40
438.4555664	0.15
449.3999023	0.08
450.4547119	0.71
451.1669312	1.14
465.1102905	0.06
468.9117432	1.20
474.7285156	0.21
486.7688599	7.07
499.7336426	0.10
503.1207886	0.32
504.2653198	1.67
504.9515991	2.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1354
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.9888458	0.15
163.2100830	0.07
167.0011444	0.04
174.9237976	0.07
176.8283539	0.04
179.1439209	0.22
201.1513977	0.15
202.3875122	0.14
203.2947693	0.41
204.9849243	0.57
212.5454407	0.13
215.3399200	0.05
217.0859680	0.13
221.1830750	0.07
230.0013885	0.20
230.8994446	0.23
240.1736145	0.21
240.9777374	0.04
243.0820465	0.37
244.1922913	0.05
245.0859070	2.31
247.2740784	0.07
255.2440186	0.06
257.2553101	0.04
259.0533142	0.09
269.1929626	0.56
273.1275024	2.72
281.2078247	0.10
282.9583130	0.07
285.1997070	0.07
287.1739502	8.73
289.1738892	23.93
290.1804199	0.07
291.1188965	0.09
297.2207031	0.04
299.0931396	7.72
305.0154114	0.16
313.2863159	0.32
317.2733765	0.15
327.0360107	0.16
328.3352051	0.10
329.1672363	0.60
331.2178345	0.69
339.1894531	0.95
341.1839600	0.27
346.9429932	0.06
349.2844849	0.23
351.4661865	0.24
353.3832397	0.08
357.1087646	0.47
375.4708862	0.05
381.2186279	1.17
387.4866333	0.04
405.2414551	0.05
407.1265869	63.98
408.2616577	0.20
409.3393555	0.52
411.1383667	0.33
415.0929565	0.16
422.9475098	0.32
425.1066895	100.00
426.0306396	0.06
427.2534790	0.06
429.5014648	0.06
432.9690552	0.85
437.1102295	0.17
439.3517456	0.38
441.0944214	0.09
449.0560913	1.18
450.0799561	0.28
451.2119141	36.10
454.4916382	0.19
467.1914673	1.65
473.4257202	0.15
474.9332886	0.03
491.2480469	0.38
492.8917236	0.09
500.6027222	0.85
509.3788452	0.08
515.2790527	0.49
533.2075195	1.94
541.2633667	0.24
559.1743774	10.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.133
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
96.2073822	0.01
106.114212	0.08
107.9856262	2.49
109.0323105	0.06
124.0662766	0.22
124.7961884	0.02
134.0587158	0.76
136.021759	1.80
149.9520264	0.04
151.9813538	6.78
154.0682983	0.16
170.0135498	9.48
175.1426697	0.05
179.1831665	0.06
182.2069397	0.06
186.1326447	0.01
194.245636	0.02
202.0829468	0.01
208.2462769	0.01
212.270813	0.05
212.8735046	0.01
213.9872131	0.08
218.9983521	0.01
226.9390869	0.04
235.2432251	0.07
239.1955261	0.01
245.3381958	0.03
248.0999451	0.09
268.1474304	0.03
278.3719482	0.03
296.252655	0.28
314.1311646	100.00
315.2460327	0.13
323.036499	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
129.0233765	0.07
149.0285797	0.76
157.0883484	0.37
165.2524261	0.13
174.0415802	0.09
179.324234	0.38
181.2797089	0.65
182.0122986	0.11
192.8074799	0.12
205.2937927	0.07
206.4760284	0.47
207.2736359	2.12
208.0598297	1.60
209.082962	0.44
210.9128571	0.08
222.1197052	1.48
223.1303711	3.50
224.1744537	0.10
232.7520294	0.06
233.4287262	0.09
251.0834503	100.00
252.0745697	16.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.4072
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1697845	0.05
207.0755310	0.35
208.1238861	0.03
209.1262360	0.05
225.1434021	0.35
227.2335510	0.06
238.9693146	0.03
241.2017212	0.03
241.8325958	0.04
253.3346558	0.20
254.2577515	0.10
267.0455322	0.17
272.1315308	0.04
278.2775879	0.05
281.1765747	0.65
282.2125244	1.15
288.5541382	0.05
299.2231445	5.00
300.1206360	0.05
313.3876648	0.79
314.3163452	0.04
317.2381592	0.18
325.6172485	0.05
327.3361206	0.09
332.1924438	0.04
336.3844604	0.04
338.3534241	0.10
347.5397339	0.08
367.3854980	0.31
379.2304688	0.05
386.3840942	0.10
389.4750977	0.07
391.2111816	0.04
397.4139404	0.09
403.3446655	0.22
407.3656006	0.15
408.9931030	0.06
421.2691040	0.12
429.4609375	0.08
433.6549683	0.09
436.1971436	0.08
437.4495850	0.45
438.4643555	0.05
440.2074585	0.31
442.4538574	0.11
451.0165405	0.05
453.2871094	0.05
454.3264160	0.09
455.3574829	0.61
461.2637939	0.12
463.5834351	0.12
465.6258545	0.10
467.3986816	0.33
469.4474487	0.46
472.5753784	0.27
473.3895264	0.04
477.4973145	0.12
481.5128784	0.16
482.3775024	0.15
483.2848511	0.11
493.2532959	0.36
494.1805420	0.13
497.5971680	0.04
498.5333252	0.11
500.4434814	0.03
511.5313110	0.11
514.5700073	0.05
524.3123779	0.17
531.1433716	0.04
537.4076538	0.21
538.1502686	0.55
540.0056152	0.08
542.5691528	0.08
544.5281372	0.04
549.5178833	0.06
551.3243408	0.05
555.3717651	100.00
556.1104126	0.52
571.5696411	0.05
576.5338135	0.09
578.8171387	0.14
580.2670288	0.29
582.9878540	0.14
586.0508423	0.12
592.4226685	0.12
594.4646606	0.43
598.4924927	0.07
602.3140259	0.09
604.5108032	0.17
606.2307739	0.10
607.1376953	0.10
608.9733276	0.17
615.1765747	0.04
616.5795288	0.04
618.2460938	0.20
626.5328979	0.04
627.3000488	0.29
628.4019165	0.30
629.2631226	0.24
635.3867188	0.26
639.4262085	0.24
642.2950439	0.37
643.4873657	0.25
644.4683228	0.07
645.5280762	0.08
646.7293091	0.15
648.4566650	0.28
651.6561890	0.05
660.3103638	0.31
661.1058960	0.43
664.9116821	0.09
665.6761475	0.50
678.3167114	4.28
679.6010132	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1402
Annotation	Gerfelin
Peak:m/z	Relative Intensity
158.9968262	0.18
161.0797119	0.20
164.1337128	0.78
165.1584625	0.22
167.1320343	0.25
172.9340210	0.04
173.7034607	0.02
175.0535889	0.27
177.0368805	0.05
179.1507263	0.34
181.3428955	0.13
184.0515747	0.14
185.0254974	0.10
186.1284637	0.07
187.0154114	0.50
187.8865051	0.10
197.2789307	0.21
200.2234344	0.04
201.1294250	0.28
203.1046448	2.97
205.0674286	1.66
212.0582733	0.05
213.3135376	0.19
215.2197266	0.60
217.1217804	0.13
227.1035461	1.45
228.1534424	0.38
228.9805908	0.34
230.1792603	0.31
231.0472107	0.41
234.5610657	0.08
241.0700531	0.68
245.1283875	7.17
247.1592255	0.35
251.9492798	0.09
253.2395630	0.27
255.1181030	0.17
257.1378784	0.27
259.2541504	5.07
267.1854248	0.53
269.1160889	0.23
271.0924072	17.98
273.1815796	3.38
274.2083130	0.05
283.1036377	2.14
284.8583374	0.05
287.1071777	0.31
289.1625366	100.00
295.2091675	0.19
299.1328430	0.04
301.1703796	2.64
311.1878662	0.06
312.1645508	0.03
313.0539551	0.40
319.2852783	0.05
325.2285156	0.18
326.9998779	0.25
328.0115356	1.51
329.1317749	6.36
331.1088257	0.11
339.0327148	0.90
341.2016602	0.81
351.2257690	1.50
352.3906250	1.17
353.3513184	1.14
355.0443726	0.26
363.4392090	0.07
365.2768555	0.07
368.3088989	0.04
377.2906494	0.61
378.2135620	0.10
381.1279907	2.52
387.4057617	0.34
389.3755493	0.09
390.1446533	0.30
391.3475952	0.92
393.0676880	0.33
397.2775269	0.11
399.1530762	0.05
405.3877563	0.03
407.1436157	27.01
407.7655640	0.14
408.4229736	0.04
409.2113037	2.34
410.3515625	0.78
411.2704468	0.36
413.9926147	0.08
417.1870117	1.39
418.3029175	0.08
419.4674072	0.20
420.2949829	0.09
421.3082886	0.07
423.1098633	0.89
425.1724243	23.79
426.3334351	0.12
426.9915161	0.03
430.1665039	0.49
433.2529297	1.11
435.1044312	47.26
436.3204956	0.08
439.3364868	0.17
446.2200317	0.11
449.0861816	0.32
455.2764282	0.10
459.3917847	0.02
466.1267700	0.14
467.2762451	0.18
473.4395142	0.17
475.7178345	0.04
477.2150269	1.03
484.7196655	0.26
485.4215698	0.10
492.6579590	0.07
499.2106323	0.77
514.6490479	0.35
516.1767578	0.10
517.2653198	3.39
519.3674316	0.10
521.3614502	0.26
525.1439209	1.09
532.0496826	0.03
533.0964966	0.04
541.5046387	0.03
543.1586304	33.27
543.8527222	0.08
551.5785522	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.2756
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
163.1138306	0.52
165.1449890	0.06
169.0294189	0.09
170.9653473	0.12
173.0635223	1.21
175.3003998	0.42
177.1651917	0.27
178.1156006	0.03
179.0159302	0.10
180.9336853	0.06
181.9550171	0.03
183.1746521	0.31
184.1307373	0.18
185.2218018	0.60
187.2022705	1.18
189.2373047	0.40
191.4899750	0.06
197.2932129	0.22
199.1603851	0.79
200.9820557	0.61
203.0839386	0.20
205.2099762	0.13
207.0691376	0.25
211.2340698	0.28
213.1830444	0.27
215.2255859	0.33
217.0022888	0.27
217.6124725	0.02
219.1834106	0.17
223.3493805	0.11
225.0636902	0.44
227.1152649	0.30
229.0461731	0.09
233.2942505	0.28
237.3505859	0.15
239.1754150	0.03
241.3733215	0.07
243.1770630	16.11
243.7960205	0.27
245.2415466	0.46
247.2465515	0.16
251.0224152	0.14
253.2494507	0.05
255.2109375	0.02
257.1506958	0.03
259.3992920	0.15
261.1726685	12.75
263.4054871	0.47
265.3303223	0.05
271.2413635	0.06
273.4163818	0.06
275.2074585	0.53
277.2016907	0.79
279.1942749	0.14
281.1809082	1.21
282.1921997	0.06
287.3808594	0.02
291.2329712	0.74
293.1445923	0.10
297.1556702	0.12
299.2284546	3.62
299.8397827	0.01
305.2795105	0.81
306.7438354	0.07
315.1842651	0.58
317.2606812	21.55
319.1655884	0.09
321.2308960	0.04
323.3582764	0.05
331.1459961	0.10
333.1317749	0.34
335.2766724	100.00
336.8020630	0.22
337.4089355	0.49
345.1949463	0.11
351.2938232	0.14
353.1937866	1.09
354.0709839	0.12
359.4201660	0.06
365.0782471	0.08
369.2207642	0.22
387.3632812	0.06
393.3519287	0.18
395.2789917	0.05
400.2503662	0.25
401.0377197	0.09
403.2769775	0.05
405.3621826	0.34
415.2318726	12.81
415.9250488	0.02
416.7504883	0.03
420.1901245	0.02
423.2821655	5.58
429.9213257	0.11
431.1613159	0.04
433.3889160	0.19
440.9561768	0.07
445.3771362	0.03
447.1083984	0.04
451.1355591	0.25
452.5873413	0.08
453.3016357	0.20
455.2001343	0.16
461.0399170	0.10
463.3323364	0.28
465.2417603	0.10
469.0217285	0.25
472.0081177	0.11
481.0825806	0.04
481.9221802	0.05
486.5351562	0.30
489.4766235	0.12
493.0074463	0.24
503.4729004	0.47
505.2697144	0.23
507.1217651	0.04
511.2290649	0.04
518.5679932	0.05
519.4850464	0.44
520.2822266	0.09
521.0363159	0.03
523.2683716	0.07
529.5603638	0.07
531.0973511	0.11
541.4299316	0.50
545.1608887	0.15
545.7680664	0.04
559.1996460	56.42
560.2256470	0.21
568.0888062	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.1063
Annotation	Methyl aklanonate
Peak:m/z	Relative Intensity
119.0808411	0.13
120.8538055	1.26
123.0007477	19.10
126.9997406	0.22
128.8802338	0.14
138.9702911	16.42
147.2384796	0.12
150.9275970	7.89
155.9987793	0.11
158.0764160	0.14
159.0968323	0.25
162.2297363	0.53
185.2104187	0.13
188.9748383	0.18
203.2515259	0.17
212.9744568	0.23
235.0052795	0.17
238.6900330	0.68
241.9464111	0.07
243.1320801	0.76
252.2604065	0.50
255.0676270	0.52
273.0095215	100.00
273.6390991	0.26
276.0446472	0.14
283.0468750	0.72
284.9375916	3.77
287.3078613	0.30
290.8390503	0.10
295.3705750	0.13
297.2110291	0.21
299.0983582	0.14
301.1688843	0.10
306.3834839	0.13
310.9846191	0.87
313.3126526	0.08
317.2471924	1.31
319.0007935	0.08
320.2647705	0.25
323.1139221	0.37
325.0823975	0.41
349.1187744	0.12
350.6760559	0.18
352.4107056	0.27
353.3679199	0.32
365.2811584	1.81
367.0403748	0.25
369.0751648	0.30
370.3534546	0.41
375.1386108	0.48
375.7423096	0.14
379.8165894	0.24
381.4190063	0.11
383.6894836	0.25
393.2629395	10.31
394.3218384	0.79
394.9869690	0.18
402.9201965	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	712.4915
Annotation	PE(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
213.8847656	0.14
233.3656769	0.64
234.1909637	0.03
251.5514832	0.05
255.2693481	42.32
256.2630005	9.22
257.3010559	0.08
258.3171082	0.06
259.2604065	0.35
261.3768921	0.22
275.3872681	1.20
277.2364807	100.00
278.2497253	21.26
279.4661560	0.03
281.4466858	0.28
282.3303833	0.02
379.3010254	0.04
391.4229736	0.11
392.3903809	0.08
434.4269409	1.28
435.4158936	0.67
450.5363159	0.02
452.3244019	16.31
453.4489136	4.70
456.2463379	1.65
457.4169922	0.30
474.2889404	1.77
475.3934326	0.51
607.5914307	0.04
670.4142456	0.11
695.2270508	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.2078
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.2557068	0.45
245.1266479	4.25
247.2284851	3.72
254.8669434	0.18
257.1041870	0.73
258.2315979	0.20
259.1229553	1.15
261.2658081	0.36
263.0609436	0.34
269.2202759	0.52
271.1453857	5.95
273.1632080	1.00
273.9364014	1.22
275.1649780	7.53
280.9322815	0.27
283.2131348	2.06
284.9382629	1.82
285.9678955	0.17
287.1290283	9.72
289.0669556	12.93
291.2141418	2.40
295.3222656	0.47
299.3035889	0.88
301.1348572	4.87
303.1788025	1.21
305.2709351	0.08
311.1266785	0.72
313.2257080	1.40
318.9890137	0.08
323.3092041	0.70
325.0490723	0.25
327.1575317	0.30
331.1111755	1.31
333.1318359	1.16
339.2717285	0.21
341.2351074	0.48
345.0693359	0.67
347.1145020	0.10
349.2033386	0.51
351.1393433	0.18
355.0088501	0.30
363.0905151	0.11
365.3424072	0.10
367.2120667	0.12
373.0342407	0.12
379.2251892	0.85
381.3675537	1.30
383.0595703	0.45
389.1384277	0.70
391.1351013	0.55
393.5860596	0.07
395.4758911	0.40
397.2135620	22.40
401.2854004	0.10
403.1853638	0.54
405.3096313	0.64
407.2177124	34.46
409.0823975	20.98
411.0451660	4.26
415.2429199	1.60
417.3144531	0.20
419.1883545	5.79
421.1337891	2.92
423.3833008	0.91
425.0512695	33.96
427.0689087	7.18
431.1351929	1.60
433.1666260	4.83
435.1184082	1.54
436.2739258	0.32
437.1311035	19.42
439.1829224	3.08
449.1757812	6.97
451.0750732	12.68
453.0562134	0.80
461.3246460	0.17
469.1145630	0.33
512.9389038	0.07
517.2384033	8.47
518.1325684	0.10
521.9671021	0.20
524.6090088	0.20
527.0690918	0.33
529.2401733	0.23
533.3124390	0.29
534.4525757	0.89
535.1940308	7.74
541.2308350	8.40
542.1619263	1.21
542.9428711	1.55
545.1350708	1.10
553.3071289	0.12
559.0358887	26.80
559.6923828	0.23
561.1325073	2.37
570.4352417	0.70
571.1779175	2.00
575.0760498	1.08
577.0615845	100.00
579.0715942	31.08
587.0684204	0.56
589.0939331	5.87
591.0460815	3.07
591.9202271	0.22
600.9888916	0.10
605.4945679	0.88
606.8150024	0.09
613.4307251	0.10
619.5612183	0.17
621.0124512	1.97
630.9503784	0.09
654.4465332	1.09
655.4235229	0.68
679.1707153	3.73
687.5552368	0.59
695.2886353	0.20
697.1863403	21.84
699.1886597	8.04
703.3675537	1.87
704.2426758	2.60
705.2754517	8.26
707.9400024	0.25
711.0476685	0.51
715.1221313	27.02
723.3027344	2.09
726.9243164	0.53
736.9136353	0.20
741.1126709	5.55
759.6315308	0.05
830.9945068	0.86
847.8401489	0.14
849.1212158	5.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	797.466
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
225.0715942	0.17
227.2022705	0.07
229.1757660	1.13
231.3039703	0.04
233.0803223	0.79
239.3326721	0.24
241.3057404	0.10
243.2663727	0.45
245.2762604	0.45
247.2289429	1.29
251.1612091	0.09
253.3081055	0.13
257.2107239	0.62
259.2095642	0.30
261.3128357	1.04
264.2394104	0.12
267.2385254	0.30
269.2015686	1.00
271.3067627	0.40
273.1760254	0.41
275.3671570	0.21
281.5092163	0.28
283.4559326	0.49
285.3493958	0.40
287.3389282	0.25
291.1845093	0.05
295.3961792	0.52
297.3182373	0.10
299.3002014	0.64
301.2961121	0.56
302.5147095	0.45
303.2911682	0.05
307.3031921	0.06
309.2086182	0.51
311.3644714	0.41
313.4335022	0.29
315.2054749	0.25
320.6187134	0.38
325.3035278	0.38
327.2726440	0.94
329.3027954	0.45
333.2637939	0.11
335.1405640	0.13
338.7197876	1.26
339.3502808	0.10
349.2189331	0.11
351.1206055	1.78
363.0372925	0.38
365.2584839	2.78
369.4554443	0.25
370.8094482	0.16
377.0670166	0.24
379.0911865	0.24
381.5191040	0.39
383.1389771	0.55
383.8594360	0.12
389.6052856	0.06
393.1803589	0.21
395.1376343	0.06
399.3325806	0.18
403.1527100	0.30
405.4282227	8.71
407.3171387	0.16
409.2701416	0.36
411.3728638	1.45
412.1416016	0.09
417.3276978	0.44
421.3281250	0.75
423.3173828	52.52
424.0148315	0.21
425.4079590	0.60
435.3553467	0.25
436.7325439	0.18
439.4258423	0.29
441.3229980	60.14
443.9719849	0.06
456.5949707	0.11
457.5598145	0.08
458.5412598	1.22
459.2887573	0.10
471.2406616	0.29
487.1997681	0.32
491.4322510	0.07
492.6992798	0.30
497.4445801	0.35
519.3855591	0.28
535.3735352	0.12
537.3972168	0.19
539.4317017	0.13
545.0541992	0.08
553.2843628	0.18
563.1659546	0.91
571.0442505	0.10
575.6215820	0.10
581.3521118	19.91
599.2254028	100.00
600.0260620	0.23
616.4574585	1.62
617.1182251	14.89
619.7420044	0.24
621.2048950	0.10
622.7354736	0.29
634.9705811	3.28
743.4227295	0.21
745.5762329	0.15
759.9328613	0.47
761.2412720	0.26
764.0021362	0.07
779.0958252	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.119
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
160.9327393	0.60
162.7140350	0.27
163.6015015	0.42
165.0542908	0.72
173.0448914	0.14
174.9564819	2.69
176.9024353	0.13
182.9850769	0.09
185.4909363	0.11
187.1782227	1.13
188.1379700	0.37
189.0718994	0.29
193.9512177	0.05
197.2595520	0.11
199.1277924	0.22
200.4511719	0.18
201.1279449	0.35
203.1673889	1.29
205.0485382	0.43
211.0610352	0.34
213.0333862	0.66
214.2845764	0.48
215.1280823	1.26
216.9876709	3.65
219.1029205	0.18
220.9967957	0.11
223.1134033	0.17
225.1876984	0.37
226.1243591	0.34
227.1007080	2.19
227.9782715	0.50
229.0886536	13.94
230.9133911	4.42
232.9094849	0.38
236.9424744	0.13
238.4079895	0.15
239.3863068	0.03
240.2530365	0.05
241.0332336	2.67
242.1029816	0.34
243.1375732	8.55
245.0325623	6.31
246.0933685	0.10
247.1152344	0.84
250.9619751	0.07
253.2561951	0.07
254.2692413	0.16
255.1352234	0.62
256.1338501	0.16
257.0696411	1.02
259.0732422	0.24
263.1788635	0.20
265.0425720	1.00
267.1205444	2.24
268.1976013	0.45
269.0797119	1.67
270.0086975	1.55
271.1596069	8.77
272.9628906	4.25
275.1063538	1.85
275.7614136	0.03
277.0796509	0.12
278.0921021	0.22
279.1512451	0.14
280.9108887	1.59
282.5077820	0.68
283.1342773	5.89
285.1367493	3.23
287.0990601	40.65
289.2000427	1.00
291.5521240	0.26
293.2581787	0.55
294.0453186	0.25
295.2332764	0.46
296.0363159	0.33
297.2483215	1.81
299.2617188	2.48
303.2295532	0.23
305.0247498	0.21
307.1855774	1.79
308.6099854	1.09
309.3557129	2.15
310.0198364	0.18
311.1920166	0.33
313.3472900	0.61
315.0292969	0.22
317.2575684	0.13
319.0681152	0.46
321.2760010	0.87
322.1358643	0.19
322.9733887	1.02
325.1303711	5.61
326.3745728	0.76
327.2322998	3.16
329.2062988	1.99
331.3046875	0.06
333.1176147	1.06
335.2006226	0.31
337.2822876	0.59
339.1210938	1.23
341.2959595	0.05
343.3944092	0.15
345.1102295	0.22
347.1542969	1.02
348.6135254	0.86
349.2614136	0.28
351.1941528	4.82
352.8953857	0.33
355.4208374	0.17
357.0262451	0.31
360.2270508	0.52
361.1326294	0.82
363.1152344	0.84
365.1559448	2.10
366.3473511	0.06
367.1399536	0.35
369.2398071	2.02
373.1058960	2.78
375.2042847	1.29
376.0470581	0.17
377.3096313	1.51
379.2327271	2.42
381.0884399	0.44
385.4323120	0.52
386.6013184	0.31
387.2705688	0.80
389.1717529	1.28
391.2205200	8.35
393.1728516	14.70
394.1397095	44.97
395.1210327	7.81
397.2048340	4.69
398.1395874	0.05
399.2933350	0.06
401.3214111	0.46
403.5973511	0.42
405.2279663	5.59
405.9987793	0.13
407.2225342	26.67
408.0712891	0.12
409.1164551	4.70
410.4464111	0.15
411.2246704	0.45
413.1563110	12.09
413.7577515	0.03
414.3994141	0.08
415.0927734	0.10
417.2702637	0.22
419.2221069	3.22
421.2931519	0.64
423.1092529	1.55
427.3399658	0.52
429.4017944	0.51
431.1541748	26.71
431.8060303	0.16
433.2763672	0.08
433.9788818	0.07
434.9587402	0.80
437.2200317	27.63
438.3138428	0.18
439.0324707	0.84
444.3316650	0.37
445.3459473	1.21
446.0661011	0.12
447.2603760	1.63
449.1491089	100.00
450.2498779	0.40
451.1714478	2.25
451.8419189	0.15
453.1173706	2.78
455.2189331	0.08
459.3537598	0.15
462.3501587	0.22
463.1942749	0.47
465.1826172	2.19
467.1313477	0.09
469.2208252	1.34
470.1785889	0.16
471.1339722	0.10
473.1028442	1.06
474.9678345	0.05
477.1497192	0.81
479.3676147	0.21
481.0258179	0.10
485.1253052	0.27
487.2703247	4.05
489.2882080	1.09
491.1638794	0.48
495.3088379	1.83
497.1770020	0.57
499.2445068	0.30
505.0140991	0.36
506.1464844	0.14
507.2167358	0.25
511.2933960	0.17
513.1640015	6.28
515.2031250	1.60
517.2960815	0.28
521.2403564	0.11
527.2902222	0.18
529.4340820	0.59
531.2611694	8.06
532.3330688	1.66
533.1933594	4.59
539.1840210	2.60
540.1865234	0.09
543.3291016	0.29
547.2598877	0.34
551.4826050	0.38
557.0639038	14.44
558.1135864	0.87
565.7890015	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.18
Annotation	Unknow
Peak:m/z	Relative Intensity
264.7455444	0.07
268.1679077	0.19
333.0188293	0.18
378.3919067	0.14
538.7178955	0.14
626.7676392	0.15
665.2768555	37.76
684.9593506	0.67
703.1301270	3.47
703.7913208	0.11
711.3093872	0.53
748.9127808	100.00
749.5643921	0.54
763.3049927	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2608
Annotation	PC(11:0/0:0)
Peak:m/z	Relative Intensity
125.2136536	0.21
164.0026855	0.55
178.9754028	0.64
180.1648865	0.29
184.1934509	0.18
198.1078186	0.16
199.0274658	0.87
211.0584106	0.48
216.2281952	0.21
217.2130432	0.19
254.3684692	1.94
261.9550476	0.52
280.2301941	0.89
285.3147583	58.54
298.4998779	2.34
333.1168213	0.51
350.4699707	0.41
352.2674866	0.60
359.2927856	0.63
363.1164551	1.32
365.1916809	4.58
380.7361450	0.33
382.8649597	0.78
401.1131287	0.37
408.1164856	100.00
409.0460815	0.72
416.8131409	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2767
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
203.1703186	0.05
281.2068481	0.04
323.1586914	100.00
355.0825806	0.02
407.2822876	0.03
408.0667725	0.10
426.2252808	0.07
449.2404785	0.54
452.0484619	0.06
476.0711060	0.03
486.5133667	0.03
495.1083984	0.02
559.4623413	0.11
560.4394531	0.06
575.4175415	0.04
576.9999390	0.12
578.1604614	0.19
588.1646118	0.08
600.9526978	0.06
603.1734619	0.12
611.1041260	0.39
629.1880493	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.158
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
157.0556335	0.07
161.0434113	0.52
163.0401154	0.59
168.8629150	0.29
171.0841217	0.40
179.1694183	0.32
180.9077911	0.32
185.0759583	0.62
187.1912994	0.52
189.1325684	1.13
191.1072693	0.34
199.3317566	0.05
200.7481689	0.08
203.1502686	0.12
205.1746674	0.04
213.0739288	0.98
215.2170563	0.37
217.0150604	0.04
218.6065369	0.19
225.3515625	0.16
227.1853333	1.14
229.1085815	0.17
231.1633148	14.82
232.9552917	0.35
236.9922333	0.24
239.0882111	0.17
241.2338257	0.34
243.0583649	10.05
243.6735992	0.06
245.0586090	3.38
253.3518524	0.05
255.0633240	11.36
255.9484863	0.27
257.0602112	1.24
258.0628662	0.20
267.1555481	0.51
269.1077576	2.23
271.2291260	0.04
273.0351562	49.79
275.0770264	83.88
277.2550964	0.23
285.1229858	20.30
287.1128540	22.52
288.0672607	0.16
289.0906372	0.18
297.1552124	0.61
299.1345825	2.51
301.1884155	0.09
311.0743408	0.16
315.5181274	0.13
317.0173340	2.53
322.1904297	0.06
327.0456543	0.28
343.4505005	0.24
344.3897705	0.12
349.3612671	0.04
356.8825684	0.13
364.6168823	0.12
369.2255859	0.13
375.4520874	0.23
379.1959229	19.74
381.2391968	0.08
385.2042236	1.74
391.3067627	0.49
393.1163330	100.00
394.7557373	0.29
399.2368774	0.34
403.2186890	4.38
405.0665283	8.54
407.0458984	0.07
409.1078491	0.06
411.0699463	93.54
417.4812622	0.70
418.3677368	0.66
421.0350342	10.61
421.6837158	0.12
423.0866699	14.72
427.2146606	0.07
435.1062622	0.40
453.4203491	0.08
458.0602417	0.07
465.7378540	0.38
471.2328491	0.12
485.1328735	0.25
503.2641602	0.41
511.1449585	4.80
517.3104248	0.10
519.2849731	0.26
529.1317139	15.64
537.9151001	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.3044
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1043396	0.04
241.2794800	0.04
255.2088928	0.25
261.0609741	0.10
268.1633911	0.65
269.0888672	0.06
286.1083984	0.08
287.1593628	0.16
288.3463440	0.07
288.9519653	0.03
307.4191895	0.15
318.0566406	0.23
319.2439270	0.30
320.1829834	0.20
335.1654663	0.10
345.2829590	0.12
369.4523315	0.05
383.1780396	0.14
395.4382935	0.14
406.4041748	0.04
408.0705566	0.04
409.2787476	0.16
412.3124390	0.16
452.5083618	0.14
459.8939819	0.10
488.4091797	0.11
501.0429077	0.07
503.1832886	0.73
508.4804688	0.20
512.3864746	0.04
512.9895020	0.03
513.9436035	0.17
546.5314331	0.15
548.1760864	0.10
554.4801636	0.20
564.9403076	0.07
570.0520630	0.10
571.7935791	0.04
572.5536499	0.06
584.0763550	0.06
586.1860962	1.03
588.2637329	0.64
592.8412476	0.23
596.2357788	0.05
600.1190186	0.09
601.2102051	0.27
602.5220947	0.07
609.3209839	100.00
610.0736084	1.31
610.8775024	2.68
611.6768188	0.32
612.8690186	0.17
614.1311035	1.28
615.3261108	0.23
618.3829956	0.43
734.7063599	0.18
765.4230347	0.05
780.3575439	0.04
957.4204712	0.08
982.5495605	0.09
1039.3843990	0.34
1056.7849120	0.09
1057.7810060	0.47
1085.6738280	0.04
1088.4184570	0.07
1101.9937740	0.08
1103.4340820	0.29
1104.6674800	0.06
1219.3632810	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.294
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
140.0692596	0.06
152.8889008	0.15
196.1115417	1.65
214.0361328	0.99
263.1675415	0.02
281.3054810	100.00
282.2338867	0.04
417.3868408	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	619.2022
Annotation	Matsutakeside I
Peak:m/z	Relative Intensity
193.2018433	0.19
197.0828705	0.34
211.1478577	0.65
215.1041260	0.23
241.0931549	3.26
259.1969910	11.44
263.3465576	0.10
277.1101074	100.00
317.0910034	0.05
320.9610901	0.22
338.9496460	0.16
341.3085938	0.22
355.1828613	0.23
445.0780029	0.08
461.3123779	0.08
472.0545044	0.56
601.1741333	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.2134
Annotation	Furcatoside C
Peak:m/z	Relative Intensity
154.2019501	0.11
154.9257202	1.93
160.9963379	0.27
165.2634277	0.07
171.1826782	0.17
175.0069885	0.08
176.8202057	0.08
195.1190491	0.39
196.8254700	0.66
197.4479370	0.12
203.0626526	0.06
211.1536865	0.09
227.1626587	0.17
239.3039093	0.20
243.4259033	0.37
246.1287079	0.09
253.1690369	2.91
260.0180969	0.30
261.3607483	0.62
278.4515381	0.06
281.0463257	0.04
284.5350037	0.10
287.1400146	0.08
299.0580750	0.41
309.2051392	0.17
322.2840271	1.13
323.3856201	4.11
324.5338745	0.79
327.5231934	0.16
333.3759766	0.07
337.3746338	0.14
340.2387695	2.75
341.3201599	6.67
342.5972290	0.13
347.2063599	0.09
357.0460815	0.36
359.3724060	0.17
364.0155029	0.11
372.4310303	0.20
382.5118103	0.12
385.3668823	0.13
393.0653076	0.14
397.2753601	0.72
407.0005188	0.41
415.4996033	0.71
429.3387146	0.25
435.0668335	0.13
455.5025635	0.07
457.1711121	100.00
457.8368835	0.23
459.3208313	1.60
465.3739624	0.11
467.0524292	0.18
480.3197327	0.20
485.3429871	15.77
486.4220581	0.46
493.6903381	0.21
501.4926147	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2602
Annotation	Taxumairol V
Peak:m/z	Relative Intensity
269.0781250	0.04
275.3242188	0.25
286.9620972	0.02
303.3571777	0.02
319.4821777	0.08
335.3566284	0.05
343.2342529	0.81
347.2113647	5.32
359.3037109	0.05
361.1783447	1.00
363.2933960	0.15
365.2519531	36.25
371.2238159	0.20
379.1232910	0.03
385.6231689	0.03
387.3768311	0.10
388.0863037	0.10
389.2855225	0.78
391.3961792	0.04
401.4007568	0.15
403.4563599	0.14
407.3237915	30.04
415.3264771	0.03
416.5486450	0.04
419.3571777	0.28
421.3306885	0.07
427.4523926	0.02
430.0728760	0.06
431.0324097	0.26
433.3718872	0.05
437.4808960	0.04
449.2657471	3.16
451.5355225	0.10
461.2890015	0.69
465.4057617	0.03
473.2990723	0.02
479.5681763	0.13
481.2587280	0.24
491.2184448	0.36
495.1590576	0.03
509.1979370	100.00
509.8546753	0.25
525.2987671	0.02
527.2369995	4.45
539.1315308	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.2731
Annotation	Lovastatin acid
Peak:m/z	Relative Intensity
119.1607361	0.23
121.0449448	2.09
123.0258331	1.38
124.9964294	0.73
126.8981934	4.56
128.7798767	2.04
130.8489990	3.76
132.9775238	4.36
135.0355988	3.67
136.9636993	1.28
139.2888794	0.21
141.1257629	0.47
141.8833618	0.32
143.0599670	0.89
145.0537109	3.18
147.1082153	5.80
149.0109711	3.44
151.1598816	0.85
152.8619080	0.06
153.5512390	0.39
155.0671997	1.06
157.0350189	1.63
157.9679871	0.19
159.0649719	7.40
161.0598907	9.49
161.9835510	0.06
163.1059723	3.72
164.9639740	1.21
167.0754242	0.50
168.0605927	0.20
168.9883728	1.81
170.9998932	2.67
172.9958496	8.36
175.1134338	4.52
177.0768127	2.07
179.0938110	1.41
181.1215515	3.23
183.0176239	2.17
184.0126648	0.17
185.1011658	5.23
186.1085663	0.45
187.1652527	4.81
189.1928101	0.80
191.0552673	3.13
193.1361237	0.87
195.2261353	3.59
197.1226196	1.35
199.1478271	4.22
201.1428833	4.05
203.1784515	2.49
205.0981445	2.38
207.1701202	0.45
209.1788177	3.54
210.8445129	2.50
211.4587250	0.77
212.6105652	0.27
213.2525024	5.05
214.0837097	0.55
215.1927795	3.56
217.2343903	1.54
218.9336700	0.68
221.1922302	4.39
223.1530762	2.14
225.0093079	1.40
226.1808472	0.15
227.2046204	3.90
227.8453522	0.09
229.1762543	1.94
231.1718903	3.95
233.1488953	1.95
235.1860046	0.80
237.0731506	2.98
238.4189758	0.08
239.2713013	3.58
241.2001343	13.51
243.2788391	6.41
245.2378540	2.45
246.0491333	0.19
247.2056274	1.20
249.2512817	2.46
251.1357117	2.07
253.1651001	1.14
255.2968445	1.08
257.2521362	1.86
259.1537170	29.73
259.7639160	0.49
261.2123108	25.03
262.2007751	0.08
263.2371521	1.67
265.0550537	2.20
267.3212280	3.05
269.2354736	3.79
271.3117065	3.19
273.1782227	8.30
275.1838074	7.93
277.2229614	12.34
279.1922302	24.62
280.0576477	0.27
281.2524719	0.69
283.2575684	1.54
284.2128296	0.35
285.3394775	2.29
287.1976929	5.99
289.3679504	3.66
291.2418213	4.32
293.3072510	2.39
295.1602173	0.48
297.1710510	3.25
299.2549438	3.07
301.1640015	3.39
303.3528442	5.39
305.1811523	3.16
307.2796021	0.78
309.2440186	2.26
310.5346069	1.16
311.2433472	8.66
313.1528625	8.64
313.7890625	0.36
315.3544006	7.47
316.1672974	0.26
317.3302612	3.07
319.2114868	2.16
321.1914673	6.00
321.8634644	0.21
323.3097839	3.07
325.1869507	2.79
327.1842651	5.96
329.3144531	12.69
331.3975525	0.57
333.2858887	2.59
335.3261719	0.71
337.0830688	0.47
339.2207336	38.06
339.8867188	0.30
341.3843384	4.00
343.5018311	1.03
344.2153320	0.69
345.3596802	10.43
347.2752075	0.83
349.3908691	0.46
351.3657837	7.19
352.7855835	3.10
353.5172424	0.65
354.3691101	0.11
355.2227783	0.09
357.2294922	100.00
357.8616333	0.51
359.3210449	2.64
361.2099609	0.31
362.2709656	0.37
363.3358765	2.26
365.4777527	0.64
367.1579590	0.37
369.2641907	33.64
369.9263611	0.82
373.1107178	0.33
374.2304077	0.64
375.3122253	7.89
376.1261292	0.16
377.0615845	0.86
381.1106262	0.08
381.9787903	0.34
384.9160461	0.46
387.2865601	35.21
388.1039124	0.15
392.2012634	0.29
393.1527710	2.01
395.3707886	0.23
405.2724915	40.95
406.2045898	0.86
409.5109558	0.73
414.2416382	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1866
Annotation	Pinocembrin 7-O-neohesperidoside 3'''-O-acetate
Peak:m/z	Relative Intensity
171.0283051	0.38
178.9764862	0.42
197.0166779	0.46
215.0119324	0.73
227.0756989	0.90
245.1006775	3.64
263.0288086	100.00
265.1380005	0.17
282.1274414	0.07
284.8952026	0.06
303.0056763	0.05
323.1125488	0.05
372.8948364	0.02
382.0418091	0.05
413.2423706	0.09
425.2598877	0.02
430.4763184	0.04
431.1406860	0.09
438.0140381	0.07
440.3510742	0.03
443.0479736	0.03
468.0161743	0.07
469.9766846	0.22
475.6171875	0.13
505.0695801	0.02
515.2631226	0.08
521.3311768	0.02
559.4139404	0.80
587.0788574	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0854
Annotation	Gerfelin
Peak:m/z	Relative Intensity
88.9449387	0.08
95.1058044	0.06
104.9201202	0.20
110.9383087	0.33
119.1161957	0.12
122.9714890	100.00
124.6826096	0.04
127.0688019	0.33
137.0424805	0.83
138.8911438	95.41
139.5894623	0.03
146.9411926	6.50
150.9731293	28.90
153.0397186	0.37
161.0800629	0.03
163.1764069	0.05
165.0497131	43.56
168.9676514	2.36
181.0587921	0.28
204.9760437	0.23
221.2054138	0.09
227.2062988	0.12
245.0588379	0.21
249.1816101	0.33
255.3092041	0.11
273.0469055	20.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	712.4916
Annotation	PE(16:0/18:3(6Z,9Z,12Z))
Peak:m/z	Relative Intensity
233.1660156	0.29
234.2913208	0.09
237.2348480	0.17
240.4345551	0.15
255.2460785	38.19
256.3199463	9.77
257.1916199	0.05
259.3547363	0.80
275.4291077	1.09
277.2381897	100.00
278.3084717	20.17
279.2087708	0.13
378.6007080	0.07
391.2027588	0.06
392.1768799	0.10
434.3079834	1.38
435.2762451	0.59
452.2960205	17.49
453.4038086	4.65
456.2913818	0.76
457.4678955	0.18
474.3545532	1.84
475.2771606	0.44
571.4487915	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.1675
Annotation	Unknow
Peak:m/z	Relative Intensity
176.0281677	0.03
178.9221039	0.16
182.8720093	0.11
190.9283295	0.12
208.8683319	0.07
220.7756348	0.16
226.1751099	0.15
261.2563171	0.04
264.8014526	0.15
266.4427185	0.11
270.1649170	0.22
271.1909790	0.03
287.1430664	0.10
290.1266479	0.04
295.0881348	0.39
296.0437012	0.05
301.1466675	0.18
303.1279907	1.59
308.1787720	0.14
313.1621399	2.09
320.8213501	0.07
325.1325073	8.49
326.1004028	2.07
329.2799072	0.06
343.0993652	100.00
345.1133423	0.04
347.0584717	0.03
355.1076050	0.94
363.6351929	0.10
364.2848511	0.20
365.1017456	0.13
383.1663208	1.09
386.2153320	0.04
387.1805420	0.15
428.4385986	0.06
430.1621704	0.20
436.1191406	0.08
440.1433716	0.22
441.1185303	0.07
442.1126709	0.60
446.0834351	1.51
449.4002075	0.09
454.1376953	3.14
455.1263428	0.11
458.1497192	0.20
463.1166992	20.43
463.8408813	0.89
466.2440796	0.53
472.1751099	77.97
481.1357422	53.03
503.2477417	0.81
521.1889038	8.60
528.8024292	0.14
546.9426270	0.40
556.0946045	0.16
563.8954468	0.10
572.9866333	0.17
574.2473755	0.38
592.1212769	5.96
593.0501099	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	839.3354
Annotation	Unknow
Peak:m/z	Relative Intensity
287.0068970	0.07
320.3020020	0.02
323.2143555	0.02
347.4944763	0.03
369.1841431	0.03
389.1939697	0.01
422.3978271	0.02
423.1165771	0.03
475.1872559	0.01
491.1962280	0.01
492.2825317	0.04
501.5463257	0.06
515.2685547	0.03
516.2938843	0.03
517.2887573	0.05
531.1669312	0.03
532.5689087	0.03
549.3808594	0.04
552.1283569	0.02
564.2855835	0.03
575.5263062	0.07
577.2523804	0.11
591.2712402	0.05
593.2549438	0.03
606.2846680	0.03
607.7123413	0.02
610.3032837	0.06
617.7247925	0.01
625.3466187	0.05
638.5435791	0.05
650.2761841	0.64
651.2590942	0.15
654.4356079	0.07
663.3864136	0.05
670.4140625	0.11
677.3760986	0.12
682.1929321	2.06
683.1378784	0.07
686.3800659	0.04
698.1256714	0.03
700.4732056	0.03
701.5485229	0.05
703.3770142	0.39
708.3270264	0.03
721.5665283	0.11
735.2225952	0.01
745.5851440	0.10
747.3096924	26.85
748.0114136	0.06
749.4042358	0.02
751.3945923	0.08
761.6318970	0.02
763.4060669	0.39
771.3273315	0.06
779.2624512	55.29
779.9598999	0.24
789.3687134	8.94
795.3029785	0.13
802.2139282	0.02
803.3137817	0.16
805.1818237	0.06
807.2933350	100.00
814.8991699	0.01
821.2179565	12.58
821.8473511	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1469
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.0106506	0.75
165.1162109	1.36
169.1135406	0.13
173.0915680	0.57
177.0700073	0.11
179.1198578	0.21
181.0947571	0.24
182.9547272	0.39
185.1273193	0.05
186.9854736	0.07
188.9644165	0.12
190.9988403	0.23
193.1391754	0.11
197.2510376	0.26
198.1448364	0.15
200.9874725	0.61
202.9615173	0.27
205.1323853	0.34
207.4055176	0.18
210.9661713	0.09
213.0897827	0.11
215.0581207	0.17
217.2591858	0.04
219.1636047	0.16
225.4812927	0.10
229.0505371	2.72
231.1586304	0.91
233.0178833	0.97
243.0596619	1.70
247.1282349	23.52
248.9537659	0.05
252.8021240	0.26
254.9731903	0.43
257.2796021	0.05
259.0875244	6.77
261.0067749	1.11
267.0744324	0.33
269.3661499	0.14
271.0700378	12.26
272.3982544	0.09
273.1156616	1.88
275.0306702	8.19
283.1392822	1.98
285.0614624	1.13
287.0276489	2.92
289.0274048	31.32
291.0639648	60.83
294.8826599	0.08
296.7839355	0.08
299.1102905	1.29
301.0416260	22.37
301.6678467	0.04
303.1397705	9.24
311.2254639	0.41
313.1351318	0.80
315.1349487	0.48
317.2434082	0.18
324.9653931	0.14
331.0095215	0.10
333.1985474	1.47
343.1725464	0.13
379.0662842	0.10
391.0910034	0.25
393.1922607	0.17
407.2752075	0.37
409.1712036	68.62
411.1304321	14.15
417.2602539	0.36
419.1778564	0.04
421.0588379	4.94
423.1254883	0.46
427.0329590	100.00
428.0007935	0.18
435.0915527	3.61
439.0617065	2.85
441.0885620	0.12
451.1046753	0.15
453.2048950	5.33
533.1172485	0.04
543.0669556	3.70
560.5592041	0.34
561.2388306	4.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2625
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0720062	0.05
152.9462891	0.05
196.0293579	2.13
205.2344360	0.04
214.0724487	1.48
233.2872925	0.74
259.2651978	0.42
260.9602661	0.03
275.2247009	0.63
277.2340698	100.00
278.4776001	0.11
413.3586731	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	941.512
Annotation	Pharbitoside A
Peak:m/z	Relative Intensity
275.0863037	0.35
292.1969910	0.67
307.3797913	0.40
325.9629517	0.92
375.2116699	1.04
407.3663940	0.86
409.5766602	0.86
410.5632324	2.47
421.4951782	1.62
422.4512939	0.41
425.4442749	4.42
426.4893188	0.90
437.4816284	6.93
438.4932251	14.22
439.6408081	2.26
440.2421875	0.84
455.6290894	4.03
456.4339600	3.88
457.4874268	10.99
458.4625854	12.10
465.4410400	3.59
466.2998047	0.98
468.2310181	0.76
475.6235962	0.73
476.6845093	1.34
479.5583496	1.13
483.2114258	1.38
498.5809326	2.35
500.4444580	2.68
509.5945435	5.47
510.3284302	5.69
525.5348511	10.20
526.4244385	34.41
537.5498657	1.13
553.4860840	1.44
554.5477905	1.93
571.7692871	0.80
597.4840088	5.95
598.4744873	15.63
615.4667358	12.82
616.4244995	35.25
634.4512939	3.20
733.4021606	9.78
734.4570312	31.42
752.4301147	11.13
755.0391846	0.56
777.5297852	1.36
778.4747925	2.25
796.3024902	23.90
797.0036621	2.48
879.5660400	8.95
880.4721069	63.41
898.6306763	2.42
923.8926392	28.39
924.5667114	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1254.8998
Annotation	Unknow
Peak:m/z	Relative Intensity
368.9801025	0.21
387.1685181	0.17
415.3606873	0.17
418.5635376	0.14
438.5812073	0.28
473.6752930	0.59
480.8561401	0.14
483.8186035	0.13
487.3267212	0.22
491.3761292	0.36
513.0042114	0.12
530.8282471	0.11
554.2805176	0.15
560.4252930	0.11
565.3942261	0.41
572.4600830	0.20
593.3299561	0.03
599.2520752	0.09
604.4765625	0.05
616.2820435	0.36
622.3883057	0.23
637.3568115	0.26
651.9141846	0.19
654.5916748	0.36
673.5283203	0.30
674.3778076	0.29
713.3596191	0.05
756.7798462	0.05
772.3087769	0.18
773.4620361	0.18
785.5208130	0.15
790.3146973	0.20
797.5737305	0.30
817.2895508	0.24
819.4305420	0.07
824.1615601	0.12
831.1895142	0.54
854.3577881	0.22
881.6517334	0.22
911.8713379	0.45
932.2209473	0.18
933.1124268	0.11
941.0949707	0.15
950.4858398	0.63
969.3154297	0.40
981.8187256	0.60
986.7098389	0.36
987.6313477	0.25
992.1815186	0.54
997.5433350	0.37
1001.4700930	0.14
1002.2031250	0.13
1012.4007570	0.59
1015.1405030	0.05
1022.7668460	0.40
1024.5389400	0.76
1031.3496090	0.57
1032.0654300	0.52
1036.5656740	0.22
1040.1901860	0.24
1041.0052490	0.24
1042.1525880	0.24
1043.8657230	0.33
1044.9122310	0.46
1045.9381100	1.05
1051.1733400	1.47
1055.0142820	0.88
1055.9755860	1.84
1057.0302730	0.41
1061.4013670	0.17
1063.7969970	0.50
1064.5756840	0.11
1065.5632320	0.85
1066.7542720	0.85
1068.2141110	0.42
1070.7309570	0.40
1072.1035160	0.45
1073.4766850	0.69
1074.4820560	0.77
1075.4978030	0.05
1080.3779300	0.21
1081.1459960	0.39
1082.8969730	1.28
1084.7854000	0.17
1085.7541500	0.74
1086.4724120	0.32
1087.8044430	0.05
1088.8264160	1.44
1089.9173580	0.42
1090.6210940	1.02
1091.8142090	3.10
1092.7010500	0.54
1094.5844730	0.25
1096.3759770	0.83
1097.3916020	1.35
1099.1225590	1.47
1101.8692630	0.54
1102.4825440	0.60
1104.2604980	1.25
1106.8685300	2.16
1107.5484620	0.88
1108.5097660	1.14
1110.1870120	0.18
1110.9514160	0.52
1112.1899410	1.71
1113.2229000	1.30
1113.9479980	0.45
1115.5915530	1.29
1117.1826170	4.17
1117.9180910	1.30
1119.7795410	0.43
1120.7799070	1.55
1121.7927250	1.38
1122.5367430	1.34
1123.3222660	0.36
1126.1989750	1.78
1126.9992680	1.31
1128.6140140	0.68
1129.8034670	0.50
1130.7813720	1.08
1132.1198730	2.78
1133.1933590	1.74
1134.2165530	0.83
1135.3466800	1.12
1136.2026370	0.62
1137.4558110	1.17
1138.9218750	0.14
1140.3654790	2.11
1141.2709960	1.32
1142.3264160	0.73
1143.6684570	3.47
1144.6474610	0.76
1146.1115720	6.16
1146.7851560	4.26
1148.9317630	1.41
1150.0830080	3.84
1150.9473880	1.27
1152.7592770	0.34
1154.8072510	10.13
1155.6691890	5.57
1156.7775880	3.76
1158.2685550	1.33
1159.0236820	0.55
1160.1083980	3.45
1161.1457520	0.79
1161.9520260	0.16
1163.4727780	1.78
1164.2272950	1.26
1165.5124510	3.36
1166.5419920	4.28
1167.5561520	1.88
1169.5047610	1.36
1170.2241210	3.91
1170.8696290	0.11
1171.4805910	0.74
1172.5032960	1.58
1173.1079100	5.00
1173.8969730	1.94
1175.0587160	1.63
1175.8957520	1.31
1176.9492190	1.81
1178.0115970	1.56
1178.7490230	10.59
1179.8120120	8.77
1181.3897710	7.05
1182.2736820	5.86
1183.2878420	6.95
1184.0477290	5.84
1184.9971920	1.40
1187.8121340	39.02
1189.1711430	44.22
1190.1540530	6.32
1191.0113530	0.03
1191.8111570	0.18
1193.6044920	1.77
1194.4799800	1.02
1195.1959230	0.31
1196.3159180	1.68
1197.2130130	1.13
1198.3336180	1.63
1199.3125000	0.74
1199.9138180	0.69
1201.5095210	1.59
1202.3360600	2.41
1203.0913090	1.39
1204.3054200	0.45
1206.0455320	3.29
1207.2498780	4.27
1207.9090580	3.85
1208.8076170	0.28
1210.5975340	4.65
1211.5554200	5.24
1212.5968020	4.10
1213.2337650	9.25
1214.3184810	3.60
1216.4414060	17.55
1217.1546630	6.63
1217.9770510	4.19
1218.7255860	1.20
1220.0979000	7.33
1220.9282230	5.24
1222.3037110	100.00
1223.5708010	2.94
1224.6950680	0.36
1225.7386470	3.87
1226.6578370	1.08
1227.3929440	0.25
1228.1440430	0.46
1229.5704350	2.68
1230.2531740	0.43
1231.4063720	1.90
1232.1245120	0.61
1233.4725340	1.21
1234.5588380	9.24
1235.4670410	2.54
1236.7768550	7.16
1237.7121580	2.62
1238.4947510	0.15
1240.0283200	18.62
1240.7409670	9.45
1243.0124510	0.60
1244.0576170	0.89
1245.6817630	0.87
1273.7657470	0.87
1277.5488280	0.14
1280.0634770	0.30
1282.0942380	0.59
1289.3543700	0.68
1298.5993650	0.38
1302.0775150	0.13
1305.4436040	0.29
1316.5100100	0.56
1321.7957760	0.17
1323.1613770	0.73
1327.7646480	0.13
1336.2014160	0.33
1338.6284180	0.35
1343.2813720	0.65
1347.7248540	0.67
1352.7624510	2.42
1353.4313960	0.31
1354.2808840	0.28
1358.3436280	0.36
1360.0177000	0.48
1363.6007080	0.15
1372.1929930	0.39
1381.0522460	0.21
1384.3568120	0.20
1389.1845700	0.53
1390.6397710	0.28
1393.4151610	0.37
1394.6601560	0.12
1404.6700440	0.04
1409.3657230	0.25
1412.1671140	0.08
1414.9768070	0.31
1421.4759520	0.19
1429.0885010	0.38
1436.1799320	0.56
1437.7991940	0.10
1439.3812260	0.28
1441.5177000	0.20
1442.7104490	0.04
1445.4439700	0.23
1447.6939700	0.08
1449.5711670	0.22
1451.1694340	0.37
1454.9600830	1.10
1456.2586670	0.05
1458.2858890	0.16
1459.7396240	0.18
1461.6280520	0.62
1463.1595460	0.66
1464.9937740	0.30
1466.1705320	0.09
1469.6419680	0.20
1471.2867430	0.08
1471.9698490	0.19
1474.0738530	0.41
1480.6514890	0.50
1482.6383060	0.54
1484.6201170	0.31
1485.4595950	0.71
1486.5557860	0.17
1487.2307130	0.86
1488.2802730	1.22
1489.7952880	0.30
1490.4997560	1.01
1491.7681880	0.70
1492.8859860	0.06
1494.0197750	0.52
1496.5804440	0.58
1497.7864990	0.43
1498.4332280	0.47
1499.2158200	0.74
1500.0357670	0.35
1501.6395260	0.24
1502.5872800	0.67
1503.3310550	0.33
1504.2686770	1.45
1507.8634030	0.18
1510.2469480	0.38
1516.1915280	0.24
1518.0911870	0.04
1520.4221190	0.87
1522.7969970	0.55
1525.0728760	0.55
1525.8448490	0.29
1531.1070560	0.20
1535.2193600	0.74
1537.0249020	1.37
1538.1116940	0.57
1540.1726070	0.55
1542.6424560	1.13
1544.1314700	1.10
1545.0079350	0.12
1545.8266600	0.06
1547.4863280	0.95
1548.1292720	0.12
1548.8433840	0.33
1551.1263430	0.30
1552.2338870	0.14
1553.8826900	1.33
1554.7235110	0.54
1556.1220700	0.16
1556.7733150	0.05
1558.4390870	1.00
1561.6000980	0.24
1562.7792970	0.19
1563.6617430	0.12
1565.3228760	0.37
1565.9855960	0.36
1567.9801030	1.17
1568.8593750	0.88
1570.3920900	0.85
1571.1380620	0.25
1572.7969970	0.24
1573.8039550	0.94
1574.9776610	0.69
1576.3360600	0.45
1577.9738770	0.32
1580.1019290	0.10
1582.0452880	0.49
1582.8859860	0.53
1583.6284180	0.18
1584.4863280	0.27
1586.1489260	0.95
1588.5177000	0.94
1589.2772220	1.07
1590.9268800	1.08
1591.9302980	0.51
1595.2225340	1.88
1596.4769290	1.35
1597.1165770	0.45
1598.4947510	0.58
1599.5799560	3.15
1600.4578860	4.73
1601.1710210	0.92
1601.8730470	0.28
1602.8376460	0.90
1603.5715330	0.34
1605.9156490	0.23
1606.8551030	1.20
1609.2225340	0.09
1611.3309330	0.23
1613.8271480	0.47
1614.4637450	0.21
1616.0710450	1.31
1617.7238770	1.13
1620.8646240	0.23
1623.0089110	0.81
1624.0170900	0.59
1626.0467530	0.55
1626.9754640	1.09
1629.4796140	0.83
1630.3577880	0.66
1631.4615480	1.29
1632.5423580	1.15
1633.3409420	0.79
1635.5510250	0.43
1636.2939450	0.50
1637.1809080	1.38
1639.0106200	2.60
1640.0408940	0.68
1641.0897220	0.74
1645.6468510	2.02
1646.4166260	1.36
1647.3824460	0.68
1648.2801510	1.27
1649.3979490	4.40
1650.6409910	0.52
1651.5190430	1.28
1652.4857180	0.61
1654.2092290	0.34
1656.0975340	0.10
1657.3890380	1.43
1658.1746830	0.37
1659.6912840	0.84
1661.5788570	1.05
1664.6502690	0.61
1665.5445560	0.59
1666.6029050	1.09
1667.9234620	1.47
1669.4776610	0.76
1670.5269780	0.63
1672.5933840	1.33
1673.4571530	2.90
1674.2248540	2.40
1674.8685300	0.56
1675.4932860	0.21
1676.8988040	0.49
1681.9844970	2.54
1682.7183840	0.82
1683.6915280	0.30
1684.9375000	1.79
1685.9945070	1.35
1687.2703860	0.90
1689.2962650	3.22
1690.3140870	1.49
1694.6790770	0.04
1695.6729740	0.15
1696.6232910	1.21
1697.9240720	2.45
1698.7543950	3.93
1699.4010010	1.13
1700.1777340	0.67
1700.9403080	0.45
1702.0095210	1.66
1703.3155520	0.35
1707.0819090	1.94
1708.5465090	0.38
1709.1491700	0.05
1710.7229000	1.30
1712.0583500	0.11
1715.0697020	2.32
1716.7410890	1.48
1717.8043210	0.12
1719.1119380	1.32
1720.0228270	0.60
1720.6868900	0.54
1723.1634520	2.53
1723.9748540	4.47
1724.8902590	4.97
1725.8918460	1.78
1727.0144040	1.97
1727.8883060	0.49
1728.8138430	0.42
1730.6026610	0.05
1731.6375730	3.19
1732.6214600	5.41
1733.7355960	2.77
1734.3927000	1.81
1735.3192140	1.45
1738.1608890	0.43
1739.5770260	0.47
1740.8970950	0.37
1747.2574460	1.73
1748.2458500	1.98
1750.3449710	1.96
1751.4674070	0.42
1752.2740480	0.45
1753.9774170	0.70
1754.7492680	0.99
1755.6077880	1.22
1757.0931400	0.44
1758.1496580	0.90
1759.1829830	0.89
1760.0235600	1.75
1762.1925050	0.84
1763.3287350	1.27
1764.2342530	0.17
1765.5358890	0.61
1766.9196780	3.84
1767.5231930	4.66
1768.3270260	1.77
1769.6115720	1.79
1770.2574460	0.72
1771.6527100	2.46
1772.7453610	6.68
1774.0338130	2.01
1774.7445070	1.17
1775.5706790	1.01
1776.7229000	0.31
1778.2388920	0.38
1780.9876710	37.63
1781.7401120	21.40
1782.3596190	10.25
1783.0687260	5.87
1783.6740720	7.00
1784.3562010	4.86
1785.4211430	0.91
1789.3294680	0.70
1790.3205570	0.46
1798.2248540	0.34
1801.6610110	0.36
1802.6285400	1.18
1803.3913570	0.20
1808.2351070	0.66
1809.6784670	1.31
1810.4456790	0.19
1811.3240970	0.27
1816.2941890	0.49
1818.9432370	1.85
1820.7554930	0.36
1823.9493410	1.89
1824.8865970	1.34
1832.5880130	5.43
1833.4127200	4.25
1834.1551510	0.06
1839.8677980	0.14
1846.9285890	0.54
1848.6671140	0.22
1860.6188960	0.14
1912.6623540	0.25
1956.5487060	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1071.54
Annotation	Hoodigoside O
Peak:m/z	Relative Intensity
307.0921021	0.02
451.4701538	0.07
551.7835083	0.02
623.2486572	0.41
641.8166504	0.13
693.0416260	0.04
711.4866333	0.02
727.7224121	0.03
759.5499878	0.05
814.1328125	0.04
836.8961182	0.05
847.1726074	0.10
905.4038086	0.34
923.1148682	0.09
941.6297607	0.23
943.4814453	0.04
949.3769531	1.47
957.4659424	0.07
967.4744873	100.00
968.1711426	0.16
969.4179688	0.08
985.3618164	0.04
993.4128418	0.33
995.4987793	0.04
1011.4838870	5.60
1039.4294430	0.24
1043.2800290	0.08
1044.0510250	0.09
1044.6580810	0.02
1053.1119380	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.3049
Annotation	Unknow
Peak:m/z	Relative Intensity
192.2112122	0.25
196.2396851	0.40
205.0834351	0.66
220.8615570	0.22
277.1430054	0.19
289.9304199	0.70
294.7749023	0.75
307.1942139	0.73
317.9492188	0.24
380.3134155	0.29
390.3779907	0.88
424.1738892	0.33
424.8900146	0.52
430.2780762	0.29
435.7305908	0.16
437.2309570	0.55
447.4111328	0.20
452.3503418	0.19
460.3221436	2.81
461.0762329	0.60
465.2821655	0.31
469.8347168	0.65
483.4839478	0.19
485.3503418	0.14
488.2323608	0.58
493.6116333	0.45
499.4077148	0.51
518.5463867	0.82
520.3296509	1.09
521.4069214	0.21
528.3007812	1.98
529.0857544	0.77
537.4633179	3.42
542.5241699	2.23
551.5305786	73.78
552.5721436	0.64
554.2064209	0.36
555.1032715	0.26
559.4827271	1.32
572.6190796	0.60
586.2123413	0.93
587.0866699	0.33
588.4798584	0.11
596.7210693	0.86
601.4017944	11.26
602.0944214	3.64
610.9060059	0.18
614.3817139	0.66
615.5443115	0.31
619.5291138	0.47
623.2223511	5.16
661.3049927	0.24
672.3471680	0.15
687.3816528	0.10
688.5072632	1.87
734.6637573	1.00
759.3514404	0.14
763.5308838	3.28
764.3494263	3.40
764.9984741	0.70
765.6292114	0.70
779.4940186	1.10
781.4392700	6.72
782.5157471	0.69
797.6710205	0.14
824.1741333	0.58
849.7074585	0.29
850.7308960	1.04
863.9140015	0.62
877.6954956	0.65
879.4837036	0.41
895.5985718	1.47
905.5253296	0.44
913.2255249	0.16
921.4135132	1.85
922.5715942	3.26
924.5827026	0.27
925.6118774	0.15
939.5223999	8.80
940.5231323	1.93
941.5338745	16.74
942.4358521	6.52
943.1067505	0.23
957.3698730	0.47
958.5624390	0.28
969.7412720	0.41
995.0669556	1.43
996.4845581	0.46
1000.6900020	0.58
1040.4648440	0.72
1041.3182370	1.74
1067.2629390	0.58
1068.6121830	0.86
1085.4560550	16.80
1086.4764400	6.51
1103.4803470	100.00
1104.5216060	41.95
1105.1716310	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3078
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
141.9437866	0.09
147.1408691	0.12
154.8318024	0.24
157.079834	0.32
215.9912872	0.40
217.0952911	0.69
237.1166687	0.46
243.2363129	0.33
253.2015076	0.47
265.3885498	0.63
307.4306641	0.36
308.2427368	1.80
339.2924194	100.00
339.9271851	0.31
392.2388611	0.49
399.4824829	0.57
419.2044678	7.20
420.9983826	0.59
421.6224976	0.13
423.5120544	0.22
437.0290222	1.14
445.4710693	0.54
462.2223511	93.32
463.3410034	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	798.2493
Annotation	Unknow
Peak:m/z	Relative Intensity
292.7438354	0.04
294.0082397	0.03
321.0234375	0.07
340.9447632	0.39
382.0894775	0.02
382.9846802	0.03
384.3156128	0.25
412.1979370	0.13
442.8541870	0.03
486.3063354	0.16
502.9943237	0.33
504.1426392	0.07
546.5077515	0.13
618.4684448	0.03
649.2774658	0.02
665.2037964	100.00
666.2221069	33.83
666.8523560	0.14
667.6068726	0.06
751.7419434	0.08
754.1637573	0.08
755.3457642	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1065
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
147.3056335	0.01
173.094696	0.01
190.1963501	0.01
202.7686157	0.01
268.0110474	0.02
273.2946472	0.02
281.2264404	0.03
287.0564575	100.00
299.0352173	0.01
302.1514893	0.10
305.1463623	0.02
311.1539612	0.01
316.8191833	0.04
323.2519531	0.01
346.3294678	0.02
351.0961304	0.02
359.1749268	0.03
380.1417236	0.02
383.2663879	0.05
395.323822	0.04
405.1809387	0.01
407.1709595	0.01
413.0313721	0.01
431.1312561	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1766
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
137.0641174	0.15
143.0310059	0.46
145.0787811	0.05
147.1495972	0.39
148.6205139	0.10
160.3914185	0.28
161.0402679	0.93
163.0825500	7.64
164.2508240	0.05
179.0992279	0.37
191.1247559	0.53
205.1779327	0.10
207.0980988	1.36
209.0176849	0.13
217.1033936	0.24
223.0554504	0.36
225.0986938	2.55
231.3799133	0.05
235.3031006	0.07
249.2308655	0.24
279.1495972	0.59
291.1879883	0.15
300.9830627	0.32
315.2558594	0.07
336.0418091	0.05
351.3635864	0.14
369.2371826	54.51
371.1476135	0.05
383.0600281	0.69
387.2264709	100.00
387.8417358	0.21
393.2166443	0.13
396.3724365	0.18
397.1049805	0.33
410.2152710	0.12
411.2688599	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
208.8867188	0.17
212.8497009	0.05
213.9892120	0.07
290.8381348	0.14
292.7223816	1.34
374.4711914	0.12
376.7828979	0.27
434.0427856	0.20
437.1184692	0.21
458.5855103	5.07
460.5730591	12.18
542.4935913	15.13
544.4534302	100.00
545.2149048	0.44
581.2008667	0.13
582.1499634	1.79
583.6990967	0.26
584.8424683	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.308
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
163.2081909	0.06
182.026001	0.06
184.0565033	0.37
198.1110535	0.03
211.1274109	0.05
215.9538727	0.08
276.407074	0.05
308.3722229	0.37
336.8014221	0.12
339.2886963	100.00
340.0074768	0.14
346.8825684	0.03
351.3535156	0.30
398.9250183	0.08
406.277832	0.08
419.6006775	0.03
421.9780884	0.21
430.6564636	0.05
444.3154907	0.09
462.2602844	4.14
470.8923035	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	952.9066
Annotation	Unknow
Peak:m/z	Relative Intensity
272.1380615	0.15
273.5530396	0.07
329.5398865	0.04
335.1452637	0.06
358.4234314	0.03
403.5244141	0.08
416.1389771	0.08
435.3018799	0.64
448.8173828	0.09
449.5747070	0.12
453.2236938	0.02
478.1406860	0.02
506.6106567	0.04
518.8309937	0.02
522.9682007	0.09
533.9780273	0.12
536.3256836	0.84
537.1725464	0.15
549.4674683	0.06
551.4707031	0.21
560.3005371	0.05
585.7195435	0.03
604.0191650	0.06
636.5382080	0.27
639.3245850	0.04
640.1351929	0.10
670.9253540	0.06
686.6376953	0.03
691.5953369	0.18
692.4401245	0.02
709.8637085	0.04
715.6152954	0.02
726.7216797	0.04
758.1970825	0.02
759.3314209	0.09
762.3275757	0.10
763.4763184	0.05
782.2930908	0.05
790.4168091	0.06
791.9467163	0.04
799.5873413	0.04
801.2548218	0.07
818.4090576	0.42
824.0789185	0.04
832.0660400	0.07
838.2689209	0.21
842.0844116	0.27
847.1793823	0.04
849.1428223	0.14
851.7708130	0.22
853.6560669	0.34
854.5910645	0.13
856.0085449	0.05
859.2814941	0.15
864.2778931	0.23
868.3838501	0.02
869.3989868	0.07
870.4051514	0.15
871.3107300	0.01
876.6111450	0.12
879.7908936	0.73
881.2470093	0.20
882.0234375	0.07
883.8616333	1.09
884.5971680	0.89
886.5137939	0.58
887.5126343	0.09
888.4197388	1.56
889.0565796	0.39
891.0197144	0.04
891.8294678	0.31
892.6869507	0.94
893.4202271	0.88
895.5916138	0.15
896.7922974	1.08
897.7030640	0.18
899.5497437	0.72
901.0789795	0.10
902.6699829	0.07
903.9791870	1.46
905.3679810	0.84
906.0482788	0.08
907.0684204	0.08
908.5139771	0.18
909.3558960	0.41
910.0657349	0.74
911.0333862	0.73
912.2818604	0.97
913.6017456	1.87
914.5202026	0.81
915.7076416	0.73
916.8900757	1.77
917.8624878	1.19
918.6547852	1.51
920.7725830	33.73
921.9744873	1.38
922.6659546	0.43
923.3098145	0.18
923.9177856	0.25
925.1987305	8.68
925.9053345	1.81
926.7987671	0.20
928.2097778	1.66
929.4126587	0.95
930.3357544	1.85
931.1296997	0.45
932.1491089	0.32
932.8815308	0.62
934.6340942	8.82
935.7819214	0.66
937.7771606	0.76
938.5172729	0.06
939.5917969	0.83
940.6183472	0.25
941.8312988	2.55
942.8088989	0.51
943.9104614	0.09
945.5173950	0.09
946.8988647	0.19
953.9665527	0.14
966.4751587	0.07
969.5417480	0.21
989.0778198	0.23
992.2286987	0.10
992.9492188	0.15
996.2758179	0.06
998.3451538	0.15
1000.6708980	0.21
1002.2901000	0.04
1004.2793580	0.07
1008.1260380	0.04
1016.4821170	0.34
1017.7438960	0.33
1026.3200680	0.07
1029.8752440	0.04
1031.5190430	0.16
1034.7810060	0.50
1040.6396480	0.87
1041.2639160	0.36
1044.9327390	0.11
1045.5611570	0.29
1047.0117190	0.22
1048.3201900	0.30
1050.7607420	0.13
1053.5914310	0.38
1054.4290770	0.02
1055.2301030	0.17
1057.4222410	0.33
1058.7586670	0.18
1059.8580320	0.15
1061.8875730	0.11
1063.6959230	0.09
1064.5588380	0.21
1065.3743900	0.08
1067.4371340	0.09
1071.1052250	0.09
1072.3389890	0.32
1073.1440430	0.14
1076.9570310	0.21
1078.0751950	0.23
1079.1510010	0.25
1080.0891110	0.18
1081.4505620	0.07
1082.9040530	0.25
1083.9201660	0.38
1084.6302490	0.05
1087.1800540	0.25
1088.2448730	0.55
1090.3679200	0.35
1091.7529300	0.43
1092.4605710	0.53
1093.1992190	0.33
1094.4538570	0.52
1096.3017580	0.18
1097.8480220	0.61
1100.5039060	0.15
1103.5318600	1.43
1106.6370850	0.10
1108.4708250	0.39
1109.8601070	0.10
1110.5417480	0.18
1114.1303710	0.04
1116.7385250	0.14
1118.1374510	0.95
1119.0209960	0.39
1120.4135740	0.12
1121.6992190	0.31
1122.3834230	0.45
1124.3322750	0.16
1126.4111330	1.12
1127.3538820	1.22
1128.4117430	0.58
1129.1364750	0.38
1131.1567380	1.07
1132.5415040	0.24
1133.5982670	0.30
1135.4938960	0.07
1136.9588620	0.53
1138.7644040	0.50
1140.8977050	0.14
1141.6491700	0.15
1142.5358890	0.31
1143.8032230	0.05
1145.4204100	0.38
1146.0607910	1.05
1146.9168700	1.72
1147.5986330	0.04
1149.1455080	0.12
1150.3510740	1.14
1151.1791990	0.30
1152.2259520	0.60
1152.9277340	0.06
1155.3070070	0.27
1156.1455080	0.59
1157.2717290	0.31
1158.0393070	0.42
1159.2248540	0.35
1159.9543460	0.22
1160.8981930	0.96
1161.6638180	1.37
1162.9511720	0.04
1163.6743160	0.07
1165.2579350	1.28
1165.9774170	0.35
1167.0834960	1.45
1167.6981200	0.07
1168.8714600	0.14
1169.7368160	0.70
1171.0223390	0.71
1171.8005370	0.22
1172.6265870	0.15
1174.2346190	1.86
1175.2293700	2.78
1176.3303220	0.04
1178.1735840	1.27
1179.0537110	1.11
1180.1560060	2.66
1180.8850100	2.46
1181.5742190	0.57
1182.3845210	0.30
1184.2202150	8.67
1184.8737790	5.79
1185.8847660	0.26
1186.5772710	0.14
1189.5150150	1.76
1190.3762210	1.15
1191.1846920	0.28
1192.8574220	0.23
1193.9338380	0.48
1194.6927490	0.78
1195.3471680	1.55
1196.3985600	0.33
1197.6760250	0.20
1198.9083250	0.84
1200.1656490	1.51
1201.0891110	0.94
1202.1389160	0.62
1204.9451900	6.88
1205.8990480	0.69
1206.8420410	2.73
1207.9848630	0.23
1208.9002690	0.48
1209.9149170	0.53
1210.7211910	0.19
1212.4179690	0.53
1213.8277590	1.77
1214.5231930	0.63
1215.3421630	0.90
1216.2930910	0.55
1217.3525390	0.94
1218.2960210	0.78
1219.1634520	0.22
1221.7402340	8.89
1223.0507810	1.15
1223.8013920	0.42
1224.6075440	0.39
1225.6547850	0.09
1227.3059080	100.00
1228.2856450	1.53
1229.4394530	3.03
1230.3432620	0.28
1233.2672120	38.11
1234.0534670	7.52
1234.9438480	0.51
1236.2244870	0.48
1236.8924560	0.33
1237.9787600	3.36
1238.8190920	5.68
1240.4763180	0.09
1241.4571530	0.67
1242.5190430	0.19
1244.3536380	0.06
1245.3417970	0.13
1247.1081540	1.56
1247.8662110	0.05
1248.8715820	0.05
1254.3339840	0.08
1257.7309570	0.25
1287.4464110	0.19
1310.9494630	0.19
1314.5057370	0.10
1322.3756100	0.06
1324.0627440	0.23
1331.4106450	0.29
1336.1632080	0.12
1352.3587650	0.18
1353.9415280	0.14
1357.0592040	0.04
1370.9766850	0.09
1382.1224370	0.10
1389.5565190	0.25
1393.6225590	0.05
1399.5024410	0.07
1402.8764650	0.03
1405.5312500	0.09
1416.6777340	0.06
1418.8337400	0.04
1422.2100830	0.07
1422.8367920	0.15
1426.1446530	0.15
1435.3283690	0.09
1440.8194580	0.03
1444.2618410	0.08
1444.9139400	0.05
1448.4310300	0.07
1451.5255130	0.08
1453.2348630	0.14
1456.1507570	0.07
1457.9796140	0.06
1458.8636470	0.03
1461.0390620	0.13
1466.1121830	0.16
1467.0469970	0.10
1473.9962160	0.04
1481.0678710	0.13
1482.4038090	0.22
1485.9675290	0.12
1489.6386720	0.23
1490.6986080	0.12
1492.7238770	0.18
1495.1113280	0.50
1496.6092530	0.10
1497.6949460	0.24
1498.7877200	0.14
1501.0816650	0.04
1503.4527590	0.27
1507.1005860	0.24
1508.4788820	0.23
1510.9632570	0.09
1512.0952150	0.11
1516.7335210	0.06
1518.4351810	0.22
1522.6627200	0.12
1523.6533200	0.25
1534.8988040	0.06
1538.1728520	0.03
1544.7016600	0.20
1546.6867680	0.18
1547.9566650	0.10
1550.7127690	0.07
1551.5194090	0.21
1555.6575930	0.11
1558.1320800	0.10
1559.1545410	0.17
1560.4508060	0.12
1561.0760500	0.14
1566.2923580	0.08
1572.7310790	0.05
1575.4216310	0.32
1580.0458980	0.05
1581.6850590	0.23
1583.4217530	0.13
1584.5950930	0.19
1585.4245610	0.01
1592.1895750	0.11
1593.6009520	0.02
1594.5858150	0.08
1601.4208980	0.07
1602.0477290	0.04
1603.0568850	0.24
1604.5648190	0.09
1605.4329830	0.16
1606.7764890	0.06
1612.6834720	0.16
1614.5562740	0.28
1617.1383060	0.02
1621.4888920	0.06
1622.4884030	0.21
1632.1638180	0.23
1632.7945560	0.36
1639.0207520	0.14
1640.3275150	0.11
1641.0347900	0.14
1644.4517820	0.03
1650.9483640	0.46
1656.0369870	0.04
1663.6073000	0.03
1669.6682130	0.04
1670.9989010	0.18
1673.4844970	0.03
1675.1320800	0.13
1681.8869630	0.10
1688.8275150	0.17
1689.6717530	0.06
1691.6862790	0.22
1695.4880370	0.04
1704.6851810	0.08
1713.4401860	0.26
1714.3953860	0.17
1718.8444820	0.12
1719.6423340	0.05
1727.5598140	0.31
1728.9176030	0.13
1734.6203610	0.11
1736.2453610	0.02
1737.2718510	0.06
1741.8939210	0.13
1749.4317630	0.08
1758.5709230	0.13
1770.3918460	0.08
1785.7194820	0.06
1795.8472900	0.05
1825.6760250	0.28
1829.7336430	0.02
1839.5023190	0.05
1842.7579350	0.06
1858.7108150	0.09
1867.8836670	0.04
1871.2971190	0.09
1873.9735110	0.03
1892.0169680	0.03
1965.5026860	0.06
1974.8983150	0.12
1975.5133060	0.03
1977.8824460	0.03
1998.4906010	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.183
Annotation	Nitiducarpin
Peak:m/z	Relative Intensity
119.0219116	0.29
126.8532410	0.29
129.2804413	0.20
131.0729980	1.87
138.5105591	0.30
144.2507019	0.22
145.0745392	1.08
147.0298157	24.74
149.0714417	1.34
150.0726929	0.33
157.8750153	29.66
158.6835022	0.20
162.7781372	0.53
164.7428741	0.73
167.0065613	0.37
173.0760193	12.50
175.9767609	87.23
176.5894165	0.10
191.0381775	17.73
191.6599121	0.18
193.0735779	34.19
194.0290070	1.71
196.2082214	0.32
198.9829865	0.45
206.8242035	0.34
209.0166016	10.29
219.1245422	0.12
223.0339661	0.54
227.1440735	3.81
240.8551331	0.27
244.9412537	0.95
247.0448303	0.42
249.1766663	0.30
257.0485229	0.93
259.0538330	0.37
264.2834473	0.74
266.3838196	0.31
270.3406982	0.13
273.8031921	0.38
274.8540039	0.55
277.2850647	0.77
282.2130737	0.66
284.1122131	0.99
286.3486328	0.76
288.4619141	0.39
289.2629089	0.31
290.3823853	0.72
294.2231140	0.46
302.1887512	0.75
304.0007019	0.17
312.1081238	44.38
322.1492004	1.16
338.4064026	0.36
340.2153931	0.33
346.1217651	0.12
347.9682007	0.73
348.6019897	0.27
354.2474670	1.95
366.0983276	27.61
366.7646179	0.25
373.3609619	0.11
378.2304993	0.27
383.2712097	5.08
384.1886902	20.13
396.1557312	0.56
401.2105103	85.47
402.1124268	100.00
402.7607727	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.1647
Annotation	Galactotriose
Peak:m/z	Relative Intensity
126.7951584	0.30
144.3544312	1.03
145.0218506	4.02
161.2127991	0.06
162.9733582	45.31
183.1608276	0.04
198.8608093	0.14
207.0477448	0.16
216.9118958	0.29
228.9883118	0.25
235.0617981	0.05
241.0061493	0.47
246.8089294	0.04
253.0878296	0.13
260.2701721	0.13
260.9159851	0.12
264.9873962	0.27
270.8664551	3.17
271.5117188	0.07
280.7469482	0.25
288.8864746	5.80
291.0144348	0.10
304.5207825	0.16
305.2634888	0.06
306.8839722	5.05
307.5050049	0.02
322.4937439	0.13
324.2497559	11.47
325.0393066	100.00
342.5892944	0.04
360.8897095	0.06
366.3041382	0.07
367.0932922	0.11
379.8765564	0.09
387.0817566	0.08
415.2596436	0.19
433.2633057	0.27
450.3000793	0.12
450.9049377	0.84
468.7619934	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	690.2143
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9759216	0.12
266.0769958	0.07
284.9608154	1.91
291.1909790	0.04
303.1492310	0.22
356.9686279	0.04
381.3186646	0.12
383.3803711	0.10
399.5182495	0.10
400.2980957	0.25
405.2604980	0.08
423.0684814	0.93
439.0343628	0.31
452.8856201	0.08
483.0966797	0.23
509.4488525	0.38
510.4431763	0.45
528.4595947	0.08
529.4248657	0.09
534.2724609	0.26
536.4067993	0.20
538.2278442	0.14
543.2855225	0.22
555.3298950	0.20
557.4505005	0.21
559.4862671	0.05
561.1672974	0.15
564.4420166	0.15
566.2496948	0.27
573.0375366	0.37
574.9754639	100.00
575.6837769	0.36
587.0222778	0.08
600.9985962	0.21
603.0408325	0.18
614.5061646	0.11
628.3546143	0.08
645.3953247	0.24
666.9824829	0.29
672.2432861	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
117.1413269	0.06
129.0818634	0.10
138.8839569	0.47
146.1502991	0.32
148.9237061	0.42
165.3545685	0.17
179.2066803	0.34
180.2190094	0.09
183.2172089	0.12
194.0941467	0.06
205.9863892	0.07
207.0201874	2.22
208.1128235	1.94
209.0198822	0.86
222.0876007	1.01
223.0933075	3.30
224.2314301	0.40
233.5471954	0.36
235.2039185	0.12
236.2902374	0.15
251.081604	100.00
252.1498566	21.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1476
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9626465	1.02
165.0648193	1.51
169.0215912	0.04
171.1160889	0.03
172.9841919	0.29
175.0346375	0.09
179.3596802	0.05
181.0351410	0.77
182.8486633	0.13
185.0749817	0.14
187.2593842	0.48
188.9219513	0.05
193.0271912	0.07
197.0484772	0.16
201.0620728	0.38
203.1532440	0.14
204.9883118	0.14
206.7544861	0.04
210.8753662	0.05
212.7633362	0.22
215.1653595	0.09
217.1944580	0.02
225.2846222	0.27
229.2003479	1.32
231.1537476	0.60
233.1332397	0.86
235.1203918	0.04
241.9638977	0.02
243.1126709	1.10
245.0756226	0.18
247.0859375	18.09
253.1072998	0.03
255.1577759	0.15
257.1777954	0.70
259.0576172	5.39
261.1160889	0.89
267.0558472	0.24
268.9435730	0.31
271.1058350	12.89
273.1794434	8.06
275.1146851	11.71
283.0358887	3.76
285.1182251	2.54
287.1117859	8.32
289.1367188	29.06
291.1293335	45.09
295.2480469	0.16
299.2046509	3.34
301.1104736	25.27
303.1362305	7.55
304.7369385	0.07
309.3834229	0.06
311.2237549	0.03
313.0109253	5.71
315.1432495	1.92
325.1192627	2.42
331.1190186	1.17
333.0759888	3.02
343.1862183	0.14
363.9169922	0.02
367.3996582	0.19
373.3162231	0.11
379.2202148	0.16
384.6530762	0.06
389.1771240	0.22
391.1162109	0.12
392.9526367	0.35
395.1887817	0.04
397.3940430	0.05
399.0616455	0.05
405.0929565	0.13
407.3171997	0.60
409.1991577	100.00
411.1884155	22.40
413.5643921	0.06
415.1330566	0.13
417.1617432	2.23
419.1220093	0.16
421.2057495	6.17
422.6150513	0.59
423.2461548	3.87
425.2348022	0.59
427.0241699	91.31
427.7074585	0.19
432.4019775	0.13
433.2255249	0.66
435.1427002	34.04
435.7531128	0.08
439.0693970	11.33
439.6721802	0.04
441.0128174	0.58
443.4815674	0.04
449.0574341	0.06
449.9303589	0.16
451.0142822	1.37
453.0602417	50.70
453.6727905	0.15
469.0848999	0.34
507.4440918	0.13
543.1585083	1.84
551.1977539	0.07
561.1084595	49.38
561.7910767	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.2473602	0.08
167.0030975	0.08
174.9456787	0.30
177.1992188	0.05
187.0057678	0.06
187.9040680	0.20
193.1684875	0.04
197.3286743	0.04
201.0411682	0.14
203.1584167	0.31
204.0522308	0.02
205.0722656	0.20
206.8653259	0.04
215.2420959	0.03
216.9677582	0.19
219.3914185	0.03
226.3202515	0.10
226.9851227	0.02
228.0838470	0.02
230.8378448	0.02
238.9313202	0.14
243.1619110	0.64
245.0507202	2.72
247.1039581	0.11
255.1384125	0.18
257.1356506	0.23
261.3427124	0.05
269.0430298	0.58
271.1518555	0.09
273.0696411	3.86
282.7315063	0.05
285.3877563	0.13
287.1300049	12.37
289.1527100	18.52
297.1699219	0.04
299.1829834	4.85
300.9159851	0.09
305.0953979	0.05
309.0139771	0.03
313.4423523	0.11
314.9945679	0.08
320.3458252	0.06
328.8911133	0.19
329.5150757	0.09
331.1168213	0.50
335.3050537	0.05
339.3388672	0.13
341.4327393	0.10
353.1441040	0.27
355.1892700	0.05
357.3610229	0.04
369.3502197	0.29
371.1877441	0.07
377.2454224	0.06
381.1467896	2.11
383.2779541	0.12
389.3551025	0.03
401.3032227	0.11
405.3939819	0.18
407.1128540	58.91
409.1971436	0.32
410.1842651	0.08
411.3969116	0.23
414.5528564	0.05
423.2126465	0.42
425.0739136	100.00
425.6847534	0.73
427.2207031	0.06
429.4591675	0.04
433.2467041	0.71
437.3437500	0.03
439.2194824	1.17
441.2532349	0.16
449.1712036	0.48
451.1817017	23.55
454.3019409	0.13
456.2680054	0.07
467.1546021	0.72
471.4838257	0.13
475.1177979	0.03
491.2733154	0.50
492.1935425	0.15
493.4144897	0.19
494.4745483	0.06
500.2288208	0.39
501.1873169	0.21
505.3873901	0.13
513.7448730	0.08
515.2943115	0.23
521.7284546	0.29
527.3167725	0.04
533.2317505	0.63
541.0900269	0.16
557.1594238	0.02
559.1390991	8.33
559.8807373	0.05
581.4332275	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2025
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
242.9553070	0.65
245.0827789	3.43
253.0169525	0.53
254.8044128	0.80
255.8632965	0.36
256.7884827	0.34
259.1550903	0.15
261.0491028	0.10
267.4236145	0.10
269.1871948	0.38
271.1539307	2.40
273.0503540	1.00
279.2239685	0.31
280.2070007	0.42
281.1230164	0.46
282.2460632	0.05
283.1779175	0.18
285.0803833	0.19
287.1734314	16.56
289.1484985	12.85
295.0750732	0.16
297.3241882	0.15
299.1988831	4.06
301.0845947	0.64
310.9786072	1.11
312.2779541	0.08
315.0113831	0.09
323.4313049	0.11
326.5331421	0.10
327.1745605	0.90
329.2095947	0.32
331.2327271	0.08
333.1854858	0.06
337.0417175	0.07
339.2540283	1.45
341.1038208	1.35
343.2605896	0.17
347.1157532	0.11
351.3971558	0.12
353.2650146	0.08
357.5543823	0.06
363.3684082	0.49
369.0520325	0.55
372.3903809	0.07
374.2132568	0.13
375.5155945	0.10
379.1531982	1.82
381.2063599	2.20
383.1583252	2.83
385.2093201	0.07
386.7742310	0.08
389.2924194	0.35
391.0204468	2.32
391.7042847	0.17
393.1083984	0.26
394.9330444	0.32
397.1882324	7.90
401.4179688	0.29
405.1056519	2.18
407.1265259	38.73
409.2022705	1.66
411.5518188	0.12
413.0786133	0.36
414.9716797	0.04
419.1850586	1.08
420.4926758	0.09
421.2160645	0.40
423.1813965	1.46
425.0902710	30.99
431.2072144	0.31
433.1513672	9.50
435.1806030	0.42
436.0133667	0.09
437.5576782	0.58
439.0283203	0.62
446.0985718	0.47
447.2526245	0.34
449.1409912	2.38
451.2351685	18.32
453.2666626	0.66
455.2293701	0.28
467.1360474	1.56
469.5042114	0.18
473.1547241	0.12
475.3200073	0.49
479.3944702	0.11
489.2493286	0.16
490.8126221	0.43
491.5314331	0.68
493.0776367	0.82
499.0158081	0.39
500.9794312	0.11
506.2884521	0.09
511.3688354	0.18
515.2918701	0.76
517.1167603	5.12
519.2319946	0.23
523.2026367	0.12
525.2844238	0.16
527.0659790	0.68
529.1380615	0.54
533.1640015	1.79
535.1265869	1.99
541.1956787	2.56
543.2822876	2.41
545.1984863	1.94
551.5538330	0.13
553.2469482	5.03
554.1691284	0.31
556.9160156	0.21
559.1271973	51.40
559.7515869	0.13
561.1890259	2.50
571.1859131	11.69
577.1760254	100.00
583.4161377	0.13
586.2548828	0.20
587.3049927	0.31
589.1915894	0.15
599.0652466	0.16
600.1399536	0.87
601.1920776	0.91
601.8245850	0.07
603.0892944	0.10
613.1764526	1.17
616.1123657	1.10
617.2553101	0.22
635.1360474	0.26
637.2136841	0.13
651.2156982	0.11
653.1390991	1.21
655.6854858	0.29
661.0245972	1.73
667.4430542	0.14
669.1030884	0.12
677.4120483	0.85
679.0851440	8.45
681.0415039	0.07
683.3635864	0.16
695.0917358	10.60
697.1673584	26.90
705.3012085	1.95
709.0578003	0.09
713.1667480	1.83
721.3384399	0.62
723.1090698	39.38
723.8161011	0.19
727.4743042	0.05
729.2258911	0.08
739.1213989	0.53
762.9983521	0.25
765.4137573	0.20
787.3010864	1.03
805.2844238	1.20
813.0521851	0.32
831.0637817	12.67
831.7609863	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.3285
Annotation	Leueantine C
Peak:m/z	Relative Intensity
165.8421936	0.04
184.0998383	24.21
213.0900421	0.08
227.0977631	0.30
240.1656342	0.08
241.2687988	0.36
258.1188965	0.61
292.4323730	0.06
298.9503784	0.19
299.5596313	0.13
304.3601685	0.16
317.3456421	0.21
340.2098999	0.29
351.2702637	0.56
353.2122192	0.12
354.4459229	0.08
357.1319580	0.08
365.4677734	0.11
371.9972534	0.27
380.3578491	0.07
383.1781616	0.45
394.2449951	23.30
405.9665527	0.12
412.3200073	6.24
420.6309814	0.11
424.0148926	1.14
425.2514648	0.04
426.3984375	0.06
434.3302002	0.97
435.1427002	0.24
452.3420410	0.17
473.4564819	0.10
477.1176147	0.18
478.3070068	0.62
478.9753418	0.12
481.6017456	1.29
486.3076172	0.49
488.5928345	0.51
492.2847290	0.05
493.0733643	0.16
497.2328491	0.16
498.4208374	3.82
500.2258301	2.57
506.4191895	0.54
507.3925171	0.07
508.5583496	0.25
511.1093140	0.05
512.7445068	0.13
516.3389282	34.58
517.8599854	11.60
518.4656372	64.35
520.0216675	0.16
534.3465576	100.00
535.3235474	1.47
536.5803833	0.09
543.5285645	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1994
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
241.1341095	0.21
243.1895447	1.57
245.0570374	0.79
255.2210388	1.27
256.9901123	0.36
259.4886780	0.13
261.0934448	1.29
265.2098389	0.26
267.0726318	0.16
269.3596191	0.61
271.3302307	0.10
273.1121216	0.06
279.1333923	0.38
281.1652527	0.18
282.1234131	0.11
283.2983704	0.45
285.2109680	0.99
285.9639587	0.35
287.0995178	18.92
289.1936035	7.09
295.1260681	0.23
299.1018066	3.07
301.8505859	0.20
303.3087463	0.39
313.1700439	0.60
318.2872009	0.42
322.7996826	0.12
325.0137939	0.17
327.0877686	0.30
328.0365601	0.17
328.9228821	0.61
337.3428955	1.51
339.0599060	0.52
341.1286011	0.72
345.0559387	0.14
351.2987061	0.16
353.2586060	0.25
355.3941040	0.28
361.2249756	0.61
363.1129761	4.98
367.1674805	0.21
369.2906494	0.08
371.0851440	0.28
379.1488037	0.45
381.1907043	2.22
383.1909180	1.60
387.3412476	0.26
389.2302246	0.93
391.0118408	0.86
395.0981445	4.44
405.1431885	12.35
407.2222900	31.27
409.3684082	0.69
413.1209106	13.18
415.1813354	0.84
417.1963501	2.44
421.2272339	0.52
422.4678955	0.57
423.1493530	4.23
425.1248779	19.67
431.2330322	0.73
433.0595703	0.45
433.6676025	0.34
435.0800781	1.40
436.3256226	0.29
437.2490845	1.08
447.2085571	0.88
449.1971436	19.68
450.4455566	1.03
451.1546021	15.06
453.2456055	0.08
455.2188721	0.78
461.4407959	0.53
464.9776001	0.44
467.1253662	1.30
475.1118164	1.72
483.1199951	0.06
489.2387695	0.45
493.2926025	0.77
495.4484253	0.34
499.2017212	0.56
501.2185059	0.25
505.0463257	0.20
513.0676880	0.32
515.1892090	2.84
517.2150879	1.30
519.6285400	0.56
525.3037109	4.55
527.3319092	0.45
531.4655762	0.78
533.1788330	5.33
535.5469971	0.65
541.1245117	0.12
543.1188965	21.55
545.2261963	0.10
557.0444946	4.52
557.6884155	0.13
558.6895142	0.12
559.2956543	3.83
561.2265015	3.19
567.3306885	0.59
569.1572876	6.02
575.1209106	22.56
577.1462402	55.09
579.1506348	0.43
585.1502686	1.24
586.6201782	3.08
587.2680664	22.23
588.7947388	0.12
593.2032471	0.48
595.2306519	0.12
599.2905884	0.06
601.1868286	0.55
603.1967773	0.26
616.1479492	0.41
617.2696533	0.75
619.1510620	4.50
629.2351074	2.41
644.9750366	0.26
651.2108765	1.11
659.3140259	0.48
669.0841064	1.44
677.0845337	8.54
679.1275024	0.27
695.1436157	100.00
697.2274170	1.09
709.3746338	0.47
711.3810425	0.15
712.5701294	5.05
713.2009277	27.28
721.2064819	1.62
724.9950562	0.55
728.2345581	0.07
739.2102661	44.62
743.4967651	0.24
755.1505737	1.44
760.8554077	0.51
777.1942749	0.87
785.3529663	0.20
821.2561646	1.21
829.1868896	0.59
847.0452271	18.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.2761
Annotation	Unknow
Peak:m/z	Relative Intensity
226.8386841	0.22
229.2777405	0.06
251.1429749	0.09
252.2963409	0.04
264.9891968	0.03
266.1997681	0.04
279.6686707	0.26
280.4354858	0.43
281.3427429	0.41
287.3178406	0.22
288.2888184	0.12
292.0482483	0.19
292.8805542	0.12
293.9677429	0.19
297.2025757	0.09
305.1413574	0.38
309.1781921	0.46
321.3618164	0.25
323.2473145	0.14
335.2005615	0.27
338.2528381	0.34
339.3077393	0.35
341.0886230	0.20
353.1354370	8.07
366.1148682	0.06
368.9906006	0.47
371.0350952	0.47
373.2708130	0.17
381.1931763	0.30
385.1271973	0.03
387.2543945	12.15
392.9416504	0.03
395.0679932	0.16
397.1687622	0.09
401.8835449	0.29
417.2198486	0.12
419.0687256	0.14
425.0392456	0.10
431.3422852	0.21
434.9084473	0.10
441.1847534	0.11
452.7947998	0.10
473.3414307	0.12
476.1729736	0.06
478.3839111	0.05
497.2082520	0.10
503.3103027	0.05
515.3658447	0.20
527.3553467	0.54
532.3627319	0.16
536.2651367	0.15
539.5125732	0.09
545.2416992	0.10
546.5364990	0.28
548.2922974	0.03
559.6196289	0.08
563.2966919	0.19
567.4255981	0.03
571.2526855	0.17
579.4811401	0.14
582.0513916	0.07
587.1351929	0.11
588.9707031	0.37
595.8381348	0.10
597.3860474	0.06
605.3302612	8.22
609.3549805	0.42
619.2634888	0.11
637.2947388	0.17
649.1238403	0.55
652.7908936	0.09
663.4283447	0.84
665.2716675	0.28
667.4590454	0.32
668.2185059	0.08
673.4932251	0.09
678.4884644	0.10
679.2122192	0.24
681.4483032	0.10
682.2964478	0.10
683.5637817	0.12
691.4052734	1.01
693.3631592	0.09
693.9776001	0.03
695.5365601	0.11
697.3782349	0.41
705.2404175	0.82
708.4616089	0.14
709.5156250	0.13
711.2562256	33.27
711.9269409	0.09
723.2470093	100.00
723.8489990	0.77
724.5258179	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1329
Annotation	Ciprofloxacin
Peak:m/z	Relative Intensity
96.93404388	0.02
108.0162506	2.63
109.0566635	0.04
114.9139633	0.01
115.9850464	0.03
123.029129	0.33
124.1447601	0.20
132.1401367	0.01
132.8389282	0.01
134.036499	0.89
135.9624634	2.01
137.0515137	0.02
138.1172485	0.03
151.9749756	7.53
152.5869141	0.05
154.0796204	0.06
157.0508118	0.01
157.9980011	0.02
160.1752319	0.01
164.2691498	0.03
170.0725708	9.46
172.8728333	0.03
175.2062225	0.10
185.0380554	0.24
185.7949219	0.03
193.9579163	0.13
200.4970551	0.03
201.1600647	0.05
202.9071198	0.10
203.5535583	0.07
212.1668396	0.01
217.0527344	0.01
218.1396179	0.05
231.9560852	0.01
233.1238403	0.03
235.794342	0.03
241.8507996	0.02
267.3756104	0.17
278.1356506	0.02
285.7764282	0.03
288.2958984	0.24
296.1611633	0.25
314.1392822	100.00
314.9698181	0.24
317.3079834	0.03
323.1039124	0.04
331.7655334	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0671
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
100.9264526	0.17
110.9154129	0.78
115.0932465	0.08
127.0583191	0.06
128.9291077	2.45
144.8647156	0.21
147.0033569	3.47
163.1685181	0.41
164.9875641	0.08
173.0702209	2.46
190.9708862	100.00
192.0536957	0.04
193.0822449	1.67
208.9937897	36.24
231.1925964	0.15
234.1940308	0.07
249.0686340	0.08
265.1860962	0.09
275.0040283	0.09
292.8344116	0.04
295.4063721	0.11
309.1468811	0.27
311.2242737	0.23
312.1596680	0.17
319.0466003	0.16
325.9862976	0.20
327.2518616	0.14
337.0733643	13.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.247
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
99.1947403	0.19
101.0344315	0.03
108.0945969	0.05
111.0400162	0.04
112.9539719	0.14
123.1765594	0.25
125.0574036	0.18
126.8781357	0.18
129.0159912	0.20
132.9735260	0.03
136.0499268	0.22
137.0070953	0.03
140.9603729	0.13
147.1888733	0.16
152.9486389	0.08
154.9936523	0.06
156.9672546	0.06
160.9591980	0.05
162.7484436	0.09
164.7717590	0.03
166.7516479	0.06
169.0061646	0.14
171.2073059	0.10
174.0524597	0.04
176.9760895	0.12
180.2136688	0.05
185.1184845	0.08
188.6686554	0.11
194.2483215	0.06
197.1615295	0.15
199.3880615	0.08
201.1545563	0.19
207.1851196	0.12
212.9709778	0.70
216.3175964	0.15
218.1877747	0.07
219.1946411	0.18
223.1405334	0.12
225.0405884	0.19
231.2103882	0.21
233.3445740	0.04
237.1845703	0.06
239.1162415	0.11
240.0970154	0.60
241.2637024	0.71
243.0893555	1.17
247.1792603	0.03
253.0168152	0.33
254.8439026	1.51
257.3142090	0.04
259.4121094	0.12
260.2262573	0.19
261.3586426	0.07
268.2904053	0.09
269.9393005	0.06
271.1317444	0.23
277.2760315	3.15
285.0570984	0.21
287.4207153	0.06
288.2550049	0.03
289.1392822	0.17
290.1109009	0.11
295.1508484	25.76
296.0532837	0.04
303.1422119	0.46
310.3210449	0.03
311.1443176	0.04
313.1212463	100.00
314.0660400	0.93
314.8889160	0.07
316.2222900	0.03
319.5965576	0.24
322.1193237	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	283.0685
Annotation	Oxoformycin
Peak:m/z	Relative Intensity
102.8970413	0.03
108.0776520	0.29
116.1767197	0.03
128.0413666	0.06
143.1099396	0.05
150.9313049	100.00
151.9940643	0.09
154.0712585	0.04
156.9850311	0.02
168.1520844	0.05
203.1221313	0.05
207.2608032	0.05
211.1247559	0.02
234.0054321	0.02
236.8734436	0.18
239.1387329	0.16
240.1882019	0.05
247.1242676	0.02
252.9848633	0.04
265.1179810	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.11
Annotation	Robinetinidol-(4alpha->2')-dihydrorobinetin
Peak:m/z	Relative Intensity
167.0241089	0.08
173.9989624	0.06
175.1032257	0.31
177.1867371	0.12
179.0336609	1.80
191.1368408	0.05
193.1610718	0.16
200.9723816	0.65
203.1502228	0.12
215.1882019	0.04
217.1367188	0.04
224.9771118	0.19
228.1756287	0.04
231.2522278	0.33
233.0357513	0.04
235.3528748	0.04
241.1758118	0.17
242.2126770	0.04
243.2547607	0.23
245.0734863	0.26
251.2400513	0.14
257.2416077	0.59
259.1169434	1.05
261.0350952	0.10
267.2377625	0.11
268.1849365	0.25
271.2599182	0.41
273.2976074	0.05
275.3952637	0.07
279.1512451	0.08
282.0549316	0.05
285.1669922	0.30
286.3112793	0.58
287.1423950	1.35
288.1840210	0.14
289.0335693	2.08
290.1586914	1.03
297.1820068	0.05
299.1666565	0.73
301.0155334	0.59
303.1105347	14.54
307.1632996	0.22
309.1250000	0.15
311.2805786	0.10
313.0339966	0.12
314.2116699	0.07
315.0940552	0.25
320.1639099	4.57
321.2785645	1.84
325.2719727	0.08
327.3317871	0.24
329.1264648	0.18
337.0059814	0.09
339.1615601	0.05
343.2944336	0.59
354.1406860	0.22
355.0117188	0.12
357.3547974	0.05
365.2091064	2.48
371.1135864	0.07
383.3239136	29.98
393.1611328	0.48
395.3313599	0.35
397.1629639	0.13
400.9752808	0.17
403.3031616	0.39
405.2138672	0.07
407.2332153	2.09
409.2870483	0.06
410.6903687	0.06
411.3079224	0.52
415.2335815	3.83
421.0608521	12.26
422.5476074	0.43
423.2594604	5.62
425.0650635	0.33
427.2430420	0.69
428.5055542	0.03
429.3638306	0.61
433.2933960	0.32
434.4201660	0.65
435.0797119	0.29
437.2152710	0.88
439.0970459	100.00
440.6691284	1.68
441.2885132	2.08
444.4179688	0.06
446.3735352	0.17
447.3266602	0.52
449.2473145	0.36
450.1577148	3.04
451.1599731	9.98
453.0535889	1.82
455.1686401	5.84
457.1179810	0.24
459.3818359	0.05
461.1747437	0.20
463.1185913	1.69
465.2639160	5.71
466.1730347	0.23
468.2230225	1.61
469.2337646	0.62
471.2553711	0.25
472.0163574	0.16
481.4236450	0.21
483.4085083	0.09
484.0632935	0.10
485.0687866	0.49
487.3842773	0.23
489.2072754	0.42
493.0718384	0.04
501.1560669	0.48
507.2321167	0.57
510.7321167	0.25
511.3672485	0.05
514.2720337	0.11
527.1649780	0.06
529.2485352	1.32
537.1910400	0.65
544.9191895	1.36
547.1629639	4.33
547.8643188	0.12
549.2378540	0.21
555.2050781	2.20
561.3629761	0.27
563.1871338	0.23
569.0147705	0.08
573.1751099	9.37
575.0941772	0.08
576.0392456	0.10
577.0946045	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1154.5797
Annotation	Unknow
Peak:m/z	Relative Intensity
590.0275269	0.03
609.2524414	0.03
643.4082031	0.16
799.7102051	0.04
857.3818359	0.04
863.6933594	0.04
875.3345947	0.09
893.6904297	0.17
931.8618164	0.02
973.6893311	0.09
979.7570801	0.06
991.5206299	0.01
1087.0396730	0.05
1089.4819340	100.00
1090.5412600	23.66
1201.5803220	0.19
1202.5607910	0.14
1219.5253910	90.15
1220.4699710	25.25
1221.1860350	0.08
1966.2023930	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1270.2072
Annotation	Unknow
Peak:m/z	Relative Intensity
363.1965637	0.36
383.0622253	0.29
388.2073364	0.58
400.4437256	0.24
402.9819641	0.41
408.2535400	0.25
418.0725708	0.34
431.3489075	0.35
435.3158569	3.24
441.4246826	0.87
460.1832886	0.73
461.1219177	0.34
475.1848145	0.49
504.9257812	0.39
512.1003418	0.33
518.5368652	0.35
519.6263428	0.60
524.4694824	0.28
528.2191162	0.41
536.4509888	4.38
541.3769531	0.22
549.6384888	0.39
556.2990723	0.10
557.1219482	0.54
561.2426758	0.24
573.8739014	0.39
576.1401367	0.14
577.3561401	0.38
578.5880127	0.19
579.2412720	0.37
580.4099121	0.56
601.9539795	0.33
604.3046875	0.17
605.7172852	0.12
610.3298340	0.33
615.5936279	0.68
620.4913330	0.20
657.4032593	0.09
663.1983032	0.11
671.5245361	0.31
691.3908081	0.89
692.4560547	0.78
694.4653320	0.49
698.5458984	0.27
715.4066162	0.12
730.5416260	0.73
733.6098022	0.19
747.1516113	0.84
751.6821289	0.45
779.6856689	0.39
780.4929199	0.26
791.5900879	0.39
799.3677979	2.00
804.1489258	0.11
812.8082886	0.55
828.3655396	0.60
842.9814453	0.24
846.5045166	0.52
857.6839600	0.11
861.4606934	0.25
869.6917725	0.43
912.3804932	0.36
913.3205566	0.54
920.8557129	0.45
923.6625977	0.24
929.9699707	0.20
930.5953369	0.69
939.8626709	0.26
949.0185547	0.36
952.4921875	0.17
962.4677734	0.20
965.3930664	0.58
975.8189697	0.11
983.3765869	0.52
989.1817627	0.15
990.0994873	0.80
991.0826416	1.20
994.4873047	0.48
995.5316162	0.51
1002.2716060	1.01
1007.1054690	1.73
1009.3974610	1.52
1027.0410160	0.51
1030.4840090	1.52
1036.2348630	1.84
1040.8912350	0.47
1048.5479740	0.21
1050.7159420	0.24
1059.1091310	1.28
1059.7497560	0.42
1060.3508300	0.19
1060.9609380	0.69
1064.6120610	0.42
1065.7685550	0.13
1069.8431400	0.83
1071.9162600	0.39
1073.1678470	0.60
1073.9061280	0.80
1075.6799320	0.54
1085.8330080	1.27
1088.0427250	0.52
1089.0976560	1.32
1090.3442380	0.40
1091.5539550	0.23
1094.6728520	0.38
1097.2948000	2.17
1099.3704830	0.16
1100.4945070	0.50
1101.1922610	0.65
1102.4134520	5.61
1103.1492920	2.38
1106.5693360	0.46
1108.3203120	0.31
1117.3453370	2.26
1118.2121580	3.39
1119.7958980	1.41
1120.7741700	1.64
1122.7436520	0.93
1126.8332520	1.04
1127.7110600	3.22
1129.5894780	1.34
1130.8444820	1.01
1133.2478030	0.10
1134.3216550	1.04
1135.3690190	4.37
1136.1730960	0.80
1137.4550780	0.63
1138.6279300	0.35
1139.6486820	2.17
1140.3178710	0.97
1142.2382810	2.12
1145.3737790	4.77
1146.8231200	1.08
1149.1047360	1.90
1149.7944340	1.12
1151.6447750	4.24
1152.2700200	2.36
1153.0472410	0.43
1154.9899900	2.39
1155.8101810	1.17
1157.4971920	1.42
1161.1245120	6.82
1161.9779050	0.14
1162.8602290	1.30
1164.0620120	0.74
1165.0253910	2.19
1165.6909180	0.50
1167.0208740	2.96
1167.6643070	0.87
1169.0156250	1.26
1169.8972170	0.64
1170.7170410	0.39
1172.4304200	1.95
1173.1348880	0.35
1174.1669920	2.48
1174.9309080	3.41
1175.7139890	1.16
1176.4293210	2.94
1177.4415280	1.21
1178.5512700	2.41
1179.1634520	4.78
1179.8552250	0.85
1181.4475100	16.04
1182.2734380	6.82
1183.8803710	18.49
1184.9816890	3.14
1185.5905760	1.12
1186.5727540	0.68
1188.6998290	2.14
1189.3398440	4.03
1190.0767820	4.37
1191.0418700	1.76
1192.1533200	2.45
1193.3013920	3.32
1194.3260500	8.43
1195.2618410	11.44
1195.9111330	0.30
1198.1729740	12.22
1198.9050290	9.36
1199.9726560	3.53
1201.2850340	4.54
1203.7084960	5.33
1204.7055660	100.00
1205.8378910	2.97
1206.8312990	5.44
1208.2032470	3.15
1211.2243650	1.62
1212.1093750	7.46
1213.0023190	0.29
1213.9416500	3.10
1215.0200200	3.67
1215.9992680	2.87
1217.6667480	9.44
1218.6947020	0.37
1220.8261720	7.29
1221.5714110	4.39
1223.5031740	6.98
1224.3149410	0.66
1225.3813480	1.69
1226.7182620	53.93
1227.4416500	33.01
1228.4289550	1.92
1229.2205810	1.91
1229.9401860	0.10
1231.1870120	5.65
1232.1401370	6.85
1233.0333250	30.31
1234.1019290	2.85
1234.8873290	1.85
1235.8680420	4.55
1236.7585450	5.29
1237.6605220	7.10
1238.4978030	12.58
1239.6656490	9.29
1240.7780760	7.15
1241.7097170	4.78
1242.4163820	0.16
1244.0010990	1.49
1244.8358150	12.15
1245.4412840	87.61
1247.1484380	11.08
1248.1293950	1.20
1249.1124270	5.02
1250.0589600	4.84
1250.8609620	1.00
1251.8118900	3.41
1252.4636230	4.71
1253.5545650	1.46
1255.3144530	14.98
1256.1413570	12.76
1258.7052000	2.14
1260.9743650	3.29
1266.5588380	0.33
1274.6582030	0.23
1283.5467530	0.11
1285.6009520	0.77
1302.7995610	2.09
1310.1658940	0.81
1311.7713620	0.82
1318.1856690	0.71
1319.8031010	0.88
1321.0219730	0.63
1328.8602290	0.49
1339.0385740	0.66
1344.6414790	0.77
1346.7619630	0.54
1357.4611820	0.40
1366.8157960	0.22
1368.0775150	0.47
1369.1777340	0.38
1374.3826900	0.54
1376.5972900	0.37
1381.9816890	0.34
1385.9307860	0.38
1392.4266360	0.96
1400.1063230	0.56
1401.6604000	0.33
1405.3541260	0.56
1406.0120850	1.33
1407.6961670	1.15
1408.3497310	0.65
1409.6051030	0.50
1411.3287350	0.22
1412.8123780	0.71
1417.0948490	0.43
1420.0219730	0.28
1421.6876220	0.15
1423.4014890	0.30
1424.0292970	0.81
1424.6813960	0.19
1426.6385500	0.60
1435.1097410	1.25
1437.3187260	0.19
1438.1020510	0.60
1440.2061770	0.52
1444.8780520	0.48
1451.2843020	0.83
1454.3732910	0.44
1458.4620360	0.39
1459.1624760	0.60
1460.5347900	3.39
1462.0495610	0.11
1463.1828610	0.64
1465.6656490	0.83
1466.3753660	0.33
1471.5484620	0.56
1472.8092040	0.22
1475.6605220	0.36
1479.0184330	1.02
1479.8056640	0.24
1481.8135990	0.26
1485.9172360	1.92
1489.6730960	1.05
1490.6080320	0.57
1491.3209230	0.37
1492.9702150	0.43
1494.8389890	0.46
1496.5046390	0.57
1497.3297120	1.42
1501.6604000	0.46
1503.5006100	1.98
1505.2735600	0.70
1505.9986570	0.12
1507.5130620	0.46
1509.9033200	0.61
1511.7916260	1.77
1513.9178470	0.81
1514.5941160	0.35
1517.4393310	2.20
1519.4632570	0.10
1529.2949220	1.29
1531.2160640	0.26
1532.0086670	1.07
1533.8195800	0.63
1535.2132570	0.71
1536.7012940	0.35
1538.3363040	1.24
1539.5095210	0.69
1542.3101810	0.25
1543.5063480	0.73
1545.7399900	0.66
1546.7198490	1.69
1551.3079830	1.75
1553.7508540	0.81
1554.4542240	0.51
1555.3613280	0.21
1556.2968750	1.64
1559.7789310	5.74
1560.7867430	4.00
1562.1475830	0.31
1564.3282470	1.01
1565.8215330	1.23
1566.5588380	0.36
1567.2683110	0.32
1568.5375980	0.14
1569.9239500	2.07
1572.0133060	1.18
1572.9693600	0.64
1574.1218260	0.60
1575.0723880	1.72
1577.0439450	0.44
1582.5245360	0.61
1586.8341060	0.66
1587.9722900	0.84
1588.6562500	0.48
1589.4406740	0.85
1590.3092040	1.12
1591.2607420	0.16
1592.0164790	1.77
1593.4560550	1.59
1594.4970700	2.18
1595.7504880	0.09
1597.4870610	1.46
1598.1431880	0.34
1598.8221440	1.62
1600.4165040	0.69
1601.3328860	0.70
1602.7672120	1.90
1604.0644530	0.40
1605.4025880	1.20
1608.1983640	1.13
1608.9688720	3.17
1609.9667970	0.96
1610.8225100	1.85
1611.9934080	0.77
1616.3659670	3.52
1617.0896000	2.37
1617.8983150	2.06
1618.7703860	0.49
1621.3905030	0.34
1622.7086180	1.73
1623.4012450	0.73
1628.7064210	1.02
1629.5822750	0.42
1630.5217290	2.26
1631.9599610	1.04
1632.5898440	1.63
1633.4644780	0.90
1634.2133790	0.48
1635.0158690	0.16
1635.9987790	0.12
1637.2465820	8.30
1638.1469730	3.71
1639.6135250	0.30
1641.0577390	1.62
1641.8389890	0.14
1643.7110600	2.06
1644.5330810	1.00
1646.7976070	0.25
1647.5592040	0.55
1648.2875980	0.54
1650.0344240	0.69
1650.7657470	0.21
1651.5346680	0.25
1652.6395260	4.53
1653.4245610	3.48
1654.2159420	0.55
1655.2890620	0.18
1655.9528810	0.41
1656.5903320	0.24
1657.2735600	0.74
1659.9122310	0.44
1661.1123050	3.64
1662.2169190	0.30
1663.0228270	1.14
1664.8284910	1.07
1665.6477050	0.67
1667.3428960	0.66
1668.5739750	0.51
1669.3052980	0.29
1669.9918210	1.50
1670.8087160	2.45
1671.8385010	1.01
1673.2471920	0.65
1675.3380130	4.36
1676.5441890	5.65
1677.2237550	0.29
1678.5352780	2.54
1679.4798580	3.10
1680.3458250	0.52
1682.0411380	2.03
1682.9957280	0.63
1685.1662600	0.40
1686.2993160	0.57
1688.2989500	11.68
1689.2796630	0.55
1690.2597660	2.16
1690.9876710	2.23
1692.4528810	0.98
1693.7421880	0.21
1694.5501710	0.86
1695.6086430	0.42
1696.7554930	1.95
1697.6898190	0.44
1699.0484620	1.17
1703.7962650	1.50
1704.4460450	0.48
1705.1519780	0.51
1708.6727290	1.38
1710.1529540	4.27
1712.0354000	0.81
1713.8592530	1.25
1715.3757320	1.01
1717.3596190	1.06
1718.6695560	1.84
1719.4030760	0.44
1720.3392330	1.36
1720.9747310	0.55
1721.8044430	1.91
1723.6754150	0.31
1725.1834720	2.48
1726.0852050	1.98
1726.8264160	0.24
1727.9592290	0.41
1729.5667720	0.14
1731.3875730	3.16
1732.5511470	1.51
1733.6036380	0.41
1736.4094240	1.02
1738.0938720	1.09
1739.4984130	1.61
1740.3605960	2.76
1741.4771730	1.65
1742.8068850	2.01
1743.7523190	0.37
1746.3963620	1.82
1747.0328370	0.76
1748.1605220	1.50
1749.1462400	0.32
1750.5334470	2.51
1751.7569580	0.67
1753.2088620	0.68
1755.3249510	6.15
1756.4779050	1.67
1758.6384280	2.19
1760.5057370	7.28
1761.2478030	3.36
1762.1042480	0.74
1765.4320070	0.20
1766.2730710	1.09
1769.2199710	8.74
1769.8719480	10.42
1770.5482180	5.51
1771.2478030	2.13
1772.6511230	0.92
1773.7946780	2.86
1774.8327640	4.88
1776.1129150	9.05
1777.0333250	1.12
1778.3651120	0.62
1779.6590580	0.55
1782.6013180	0.37
1783.8674320	5.61
1787.4019780	0.09
1791.2434080	4.47
1792.2298580	2.74
1796.3782960	1.55
1797.1253660	6.08
1798.0632320	2.64
1800.7574460	0.39
1804.5052490	0.27
1805.6975100	15.10
1806.4489750	13.85
1807.1522220	7.30
1807.9802250	2.40
1809.1076660	1.03
1813.6715090	1.61
1817.1112060	0.84
1820.7686770	0.09
1821.6258540	0.40
1822.7186280	1.13
1826.4434810	0.53
1827.8756100	0.63
1828.9281010	0.57
1830.7525630	0.77
1831.3538820	0.23
1831.9696040	0.45
1833.0177000	0.92
1834.2269290	0.62
1836.0290530	0.69
1836.6838380	0.11
1839.1071780	0.89
1839.9475100	1.74
1840.7023930	0.31
1842.5773930	0.23
1847.3436280	0.58
1848.3918460	2.20
1849.1677250	1.75
1850.0438230	0.76
1855.0651860	0.47
1856.0964360	0.39
1856.9279790	2.66
1862.5725100	0.94
1877.3200680	0.23
1880.8021240	0.18
1897.7266850	0.14
1957.5599370	0.16
1967.7058110	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	921.484
Annotation	Unknow
Peak:m/z	Relative Intensity
292.9956665	1.68
319.0948181	0.94
328.4556274	0.62
337.0725098	1.05
408.3475342	1.77
437.4729614	1.88
438.4157715	1.86
457.4903564	4.70
458.4561768	1.89
486.6126099	1.59
499.5716553	0.82
500.4776001	0.58
505.5815430	0.58
535.1400757	0.68
538.1334839	1.34
552.5369873	3.34
562.6424561	0.60
563.6451416	3.71
564.4638672	6.02
565.3091431	0.41
581.6340332	2.75
582.2838745	2.51
583.4060669	11.04
584.5181274	10.32
588.6400146	1.00
594.6341553	1.75
595.2959595	0.61
605.2817383	0.62
606.5609741	1.61
615.0949097	0.47
616.3600464	1.14
622.8510132	0.62
633.8901978	0.85
641.8421021	1.55
644.7716064	0.41
651.4876099	8.53
652.4250488	9.83
654.3609009	3.55
662.3485107	0.37
679.2880249	0.59
680.3597412	6.09
698.5076294	2.09
707.5575562	0.51
723.3936157	1.62
733.2648315	1.62
734.2899780	1.83
741.3447266	25.63
742.3477783	49.50
743.5283203	0.52
751.5150757	3.44
752.4470825	5.03
759.8071289	0.90
760.5111084	6.95
766.4687500	0.99
776.0121460	3.66
795.5661011	3.49
796.5791016	9.25
821.4377441	41.09
822.5279541	100.00
862.3994141	3.93
877.0924683	1.79
878.5953979	2.26
879.2788086	0.58
880.4649048	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.1647
Annotation	Unknow
Peak:m/z	Relative Intensity
280.9547729	0.57
299.0698242	0.34
329.2018433	0.61
330.3409424	0.28
357.3662720	0.82
429.8016357	0.31
431.2991333	0.19
436.2478638	0.33
478.8504639	1.38
488.3714600	0.36
492.0461426	1.95
493.3621216	0.58
504.2333374	0.27
550.5741577	0.25
578.3919067	0.43
591.9930420	0.71
593.2261353	0.62
594.5659180	0.54
606.3749390	0.23
630.2050171	0.45
644.3646851	0.43
691.0531616	0.16
694.4378052	0.19
696.5217896	0.23
702.9254150	0.38
758.9980469	0.43
760.3936157	0.52
791.8524780	0.85
805.3954468	0.23
816.6610718	0.85
820.3752441	0.34
833.0975952	1.80
841.1456909	0.65
875.1719971	1.48
886.2456665	1.82
891.9216919	1.38
892.7968140	1.47
895.3864746	0.19
898.1049194	1.12
902.6264648	4.06
903.3959351	3.78
906.3776855	1.24
907.0602417	1.56
908.0572510	0.40
910.7570801	0.82
912.6683960	1.06
914.8345337	1.99
916.8259888	0.68
918.1831665	5.35
919.2064819	1.32
920.6621704	7.03
925.7227173	0.60
928.0529785	1.27
928.7649536	0.45
930.8817139	1.20
932.7149048	6.29
935.1664429	59.45
936.2597046	1.73
937.1854858	1.22
937.9040527	0.47
939.6330566	25.26
940.4031372	2.65
942.2292480	3.49
943.0258179	1.37
943.7758179	6.19
944.6506958	0.14
948.8105469	16.74
949.6876831	9.68
951.1098022	0.68
952.0199585	2.05
952.7932739	1.04
954.1010132	1.41
955.0734253	0.65
955.9076538	0.44
956.9980469	1.95
961.5230103	0.28
988.9830933	0.76
993.9260254	1.11
1003.0830690	1.04
1017.5167850	0.42
1021.6545410	1.38
1023.2373660	1.26
1033.8464360	0.20
1038.6901860	1.30
1048.8525390	0.58
1053.9499510	1.22
1059.9245610	1.34
1082.1368410	0.32
1084.3920900	0.30
1086.5047610	1.35
1087.4849850	0.64
1089.8640140	1.12
1091.3012700	0.42
1092.7508540	6.51
1093.5130620	0.86
1097.4198000	3.41
1098.3850100	0.44
1100.2558590	2.33
1102.7346190	2.92
1103.7294920	0.66
1105.4628910	0.15
1106.8697510	0.29
1107.8430180	0.65
1109.1330570	0.21
1110.3150630	0.58
1112.1947020	2.05
1113.5042720	0.97
1120.2788090	0.98
1121.4916990	1.15
1122.2261960	3.35
1123.8408200	0.67
1125.8845210	1.34
1126.8095700	1.08
1128.7272950	0.58
1131.6110840	1.75
1136.0546880	1.71
1137.5180660	2.13
1141.3190920	0.98
1143.8134770	0.44
1146.1508790	2.95
1147.4367680	0.86
1149.7061770	1.23
1150.3586430	0.28
1151.1472170	0.76
1156.0322270	1.15
1157.3598630	3.08
1158.6892090	2.03
1159.7412110	3.66
1160.8005370	1.16
1162.4045410	1.37
1165.3688960	3.93
1168.5628660	0.36
1169.1799320	1.24
1169.9902340	1.36
1171.2523190	1.29
1171.9794920	0.81
1174.4360350	3.53
1175.4605710	3.64
1178.8189700	0.21
1180.2097170	4.22
1181.6008300	1.02
1183.0867920	1.11
1184.7821040	0.50
1186.1514890	7.00
1188.6380620	2.81
1189.7094730	2.35
1190.7604980	1.21
1193.8703610	3.87
1194.7467040	6.16
1196.8680420	1.15
1197.7407230	1.65
1201.8151860	1.82
1203.3485110	26.86
1204.7771000	2.58
1206.7578120	0.25
1207.8464360	2.55
1208.6441650	1.90
1209.5935060	0.68
1214.0952150	2.26
1215.0540770	3.18
1215.7915040	0.45
1216.4021000	0.75
1218.1632080	0.57
1219.9296880	2.66
1223.9981690	6.22
1224.6696780	7.23
1225.7480470	1.31
1227.1103520	2.34
1227.9416500	0.51
1231.3803710	6.10
1232.0263670	1.10
1233.5539550	3.78
1236.8544920	1.78
1237.5488280	0.87
1240.5546880	15.53
1241.2866210	5.73
1242.3529050	0.82
1243.1711430	4.27
1245.6850590	9.93
1246.3199460	100.00
1247.0909420	33.10
1248.3653560	1.38
1251.5999760	9.34
1252.4609380	77.09
1253.5252690	4.66
1255.3907470	0.17
1256.7552490	5.57
1257.6240230	5.87
1258.4174800	2.13
1259.6602780	0.27
1260.7078860	3.84
1263.1579590	0.24
1265.3521730	0.64
1266.5216060	2.42
1270.1768800	0.41
1275.8286130	0.32
1288.5668950	0.78
1292.7166750	0.55
1298.6153560	0.69
1303.2871090	1.07
1307.3798830	1.75
1317.0040280	0.11
1358.8575440	1.26
1362.4224850	0.54
1366.8143310	0.39
1368.3784180	0.50
1388.6282960	0.99
1395.4427490	0.30
1405.8308110	0.69
1412.4550780	0.35
1422.9246830	0.13
1430.1093750	0.47
1441.4859620	0.84
1454.9954830	0.34
1456.8989260	0.36
1457.9122310	1.06
1459.3079830	0.47
1489.6927490	0.74
1490.4295650	1.20
1491.8220210	1.60
1497.8806150	0.18
1518.3153080	0.53
1523.5675050	0.27
1533.5706790	0.17
1538.2595210	0.71
1547.9870610	0.26
1556.8265380	0.21
1559.3940430	0.93
1574.1918950	0.35
1582.2562260	0.11
1586.9141850	0.23
1588.3347170	0.80
1588.9775390	0.51
1593.9857180	0.69
1611.9980470	0.48
1623.0567630	0.79
1670.7115480	0.58
1695.4543460	0.77
1698.3737790	0.43
1704.5755620	0.61
1705.7038570	0.77
1713.1600340	0.17
1756.2346190	0.63
1761.7580570	0.53
1770.8249510	1.57
1789.4401860	0.24
1829.8875730	0.86
1890.8229980	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	356.2078
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
107.1282578	0.18
109.1780167	0.10
113.0998840	0.06
125.2460632	0.05
128.2389069	0.19
130.0465393	100.00
130.9788055	0.24
133.2583923	0.39
134.0022736	0.24
135.1690369	0.18
138.0682220	0.06
142.7229919	0.21
145.0921631	1.12
147.2643127	0.11
149.2428589	0.20
150.8728485	0.45
154.2443542	0.04
160.9912109	0.07
161.9364319	0.07
163.0943451	2.10
165.2105408	0.25
167.2708435	0.18
168.7921143	0.07
169.8272095	0.05
172.0771179	0.22
173.0663910	0.11
179.0430450	0.66
182.8252869	0.05
190.1098175	0.11
191.0927734	0.08
192.9713745	0.21
194.1523895	1.35
201.1586304	0.13
204.4550629	0.23
206.2168579	0.11
207.2164001	0.70
208.1199036	0.34
210.0709991	0.04
220.2097778	5.77
225.3303833	0.21
232.4011230	0.14
238.1416931	0.16
246.2728577	3.95
258.2572021	4.60
261.9344177	0.05
270.0392456	0.13
274.3352051	0.16
276.2682495	4.74
282.1477661	0.16
294.2745361	7.47
296.1650085	0.08
300.8745117	0.11
302.0935364	0.23
310.3819580	0.08
312.1955566	0.95
313.9302368	0.20
320.1764526	0.21
336.1220093	0.22
338.2850342	13.04
339.2580872	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2913
Annotation	Taxumairol V
Peak:m/z	Relative Intensity
184.0752716	0.07
196.1079407	0.07
224.3749390	0.02
268.1492004	0.26
285.2496948	0.03
286.2837830	0.07
343.2144165	0.09
361.2833862	0.14
420.6108398	0.01
502.6414185	0.06
504.6750488	0.02
518.6799927	0.02
519.4091797	0.22
615.3344116	0.10
624.2999268	100.00
624.9412842	3.09
625.9219971	0.34
627.0287476	0.23
628.3700562	0.04
629.4830933	0.06
630.4390869	0.44
631.1743774	0.02
632.5734253	0.05
635.2337036	0.02
635.9794312	0.01
683.7402344	0.04
684.7127075	0.07
708.8526001	0.03
727.4834595	0.03
925.4650269	0.09
1069.4610600	0.28
1087.2924800	1.82
1088.5905760	0.24
1249.5242920	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	646.3016
Annotation	Unknow
Peak:m/z	Relative Intensity
196.1635132	0.03
224.4129333	0.11
225.2143402	0.07
263.2434082	0.03
268.1367798	0.03
286.2120667	0.39
302.1146240	0.12
307.0607910	0.09
320.1456909	10.45
325.2589722	0.04
341.9722290	0.06
358.1506958	0.11
371.1127319	0.10
471.4518433	0.02
478.9614258	0.04
499.0567017	0.03
514.0048828	0.06
526.2506714	0.35
527.5112915	0.04
544.2743530	2.99
544.9783325	0.66
546.2289429	0.06
547.3520508	0.09
565.3626099	1.78
570.9665527	0.07
577.5701294	0.26
579.4367065	1.08
585.4819336	0.08
589.3572998	0.07
592.2905884	1.06
592.9884644	0.07
594.6648560	0.31
598.5457764	1.17
607.3981323	0.66
616.4060669	30.20
617.3950806	0.07
619.2526245	0.16
622.4008179	0.03
625.4463501	100.00
626.5075073	0.32
627.2852173	0.03
629.8623657	0.02
710.7012329	0.07
733.4042358	0.03
775.3312988	0.06
819.0833130	0.20
891.0839844	0.08
891.7302856	0.16
909.5773315	0.06
910.8989868	0.05
914.4286499	0.10
925.4873657	0.10
929.5211792	0.03
933.5094604	0.12
940.6342773	0.18
951.6887207	0.05
955.5537720	0.10
957.4514160	1.56
958.7720337	0.19
1013.6557010	0.03
1014.4494630	0.08
1053.2667240	0.22
1057.7872310	0.09
1058.5131840	0.02
1069.6224370	0.07
1071.3947750	1.21
1072.3437500	0.21
1079.6694340	0.24
1089.4135740	4.09
1090.5664060	0.88
1113.2067870	0.05
1113.8159180	0.14
1131.5693360	0.71
1132.6540530	0.35
1141.6462400	0.15
1142.5214840	0.04
1143.1418460	0.10
1233.5155030	3.19
1234.5084230	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0965
Annotation	Ethotoin
Peak:m/z	Relative Intensity
117.9596710	0.05
131.9759216	0.09
159.0954742	0.23
187.9832916	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.4241
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9846649	1.20
157.0834198	0.28
159.0719604	0.83
161.1928101	0.35
162.2286530	0.45
162.9565125	0.37
165.1236725	0.13
166.1410065	0.32
167.0414886	0.28
169.1275635	1.29
171.1523590	1.37
173.0607910	2.32
174.1055603	0.15
175.3030090	0.19
177.0215302	1.25
178.9648438	0.25
181.0850067	1.47
183.1194000	3.36
184.0878296	0.15
185.0891724	1.87
187.1485443	1.47
189.1765137	0.39
191.2241364	0.26
192.2357788	0.12
193.2298889	0.60
195.0771790	2.00
197.2024841	1.93
199.1762695	3.21
201.1709595	0.61
203.1562958	0.74
205.3223572	0.49
207.2132568	1.04
209.1484680	1.65
210.1652222	0.07
211.2788849	1.87
212.2059631	0.06
213.2479248	2.50
213.9742279	0.07
215.0387421	0.04
215.6760254	0.14
217.1117859	0.13
219.2663879	0.39
221.2165985	0.57
222.1356506	0.28
223.1281586	2.94
224.0478363	0.11
225.1035309	3.06
227.1469421	4.29
229.3831787	0.44
231.1062469	0.26
233.2093048	0.32
234.1282501	0.19
235.2025146	1.20
237.3171692	1.74
239.2385101	1.28
241.1750488	1.58
243.2723846	0.73
245.0008240	0.06
249.1294708	1.70
250.5198975	0.40
251.1247559	2.21
252.6353760	0.49
253.2520752	0.80
254.3247986	0.42
255.2881775	1.77
257.2291260	0.47
261.1636047	0.70
263.3516235	1.43
265.1865845	1.41
266.0440063	0.21
267.3352051	1.02
269.3095093	1.57
271.5477295	0.35
273.2155151	0.28
275.3765869	0.74
277.1759033	2.47
279.2473145	2.64
281.2796021	1.74
283.1387329	1.61
285.1945190	1.66
286.0589600	0.05
287.1634216	0.52
289.4058228	2.32
291.2233276	2.18
292.7296753	0.22
293.3418579	0.94
295.2405701	1.75
297.3516235	4.34
299.2822266	3.32
301.2360840	0.83
302.4655151	0.09
303.2421265	3.08
305.3071289	2.39
307.1962891	0.78
309.3661194	1.39
311.3389282	1.58
313.3167725	3.35
315.3208008	1.38
317.2739258	4.47
319.1961670	0.44
320.9417114	0.99
323.1879883	1.85
325.3416138	1.22
327.3098755	2.96
328.1986694	0.15
329.3521118	2.43
331.3925171	3.36
333.1489868	1.31
333.7864990	0.24
335.2139893	2.28
337.2993164	2.85
339.3508911	1.53
341.3075562	6.83
342.4674072	0.27
343.4409180	1.38
345.3073120	2.51
347.3072510	2.49
349.3010254	1.66
351.3522339	6.42
353.4517822	0.87
355.3565674	8.02
356.3239746	1.14
357.4079590	3.21
359.2954712	2.60
361.1174927	1.45
363.3385010	2.44
365.3024292	5.41
366.6053467	0.84
367.4392090	0.77
369.3795166	13.28
370.6129761	1.37
371.5553589	0.36
373.3815308	0.71
375.2414551	1.80
377.4085693	1.92
378.3168945	0.22
379.2510986	3.43
380.4680786	0.49
381.4776611	3.24
382.2523804	0.74
383.3287964	7.36
384.4038696	0.44
385.2749634	0.41
386.3552246	0.08
387.2632446	1.26
388.6152954	0.28
389.2720947	0.74
391.3308716	2.97
392.3229370	0.13
393.4793091	5.85
395.4311523	2.44
396.6433105	0.31
397.4006348	6.79
398.3879395	0.44
399.4584351	0.86
400.3521118	0.12
401.5060425	0.48
403.3473511	1.81
405.2924805	3.86
406.1065063	0.58
407.2929077	3.73
408.3482666	0.13
409.3848267	4.44
410.3558960	0.80
411.3840332	10.18
412.6519775	0.37
413.6256714	0.15
415.3999634	0.78
417.4080811	3.96
419.4200439	2.85
420.4998169	0.20
421.4109497	1.45
423.4007568	1.96
425.3663330	2.51
427.4724731	1.06
429.4266968	3.33
431.4899292	2.87
433.4533691	3.96
434.4029541	0.21
435.2922363	2.56
437.5764771	0.91
439.4621582	1.15
441.2773438	0.82
442.4696655	0.09
443.5667725	2.56
444.5349731	0.28
445.5415039	2.40
447.3926392	10.73
448.2615356	0.30
449.4276733	2.00
451.4102783	0.45
453.4191284	0.56
454.6954346	0.19
455.3686523	0.72
457.3419800	2.34
459.4974976	1.22
461.5043945	6.37
463.6244507	0.11
465.4716797	4.40
467.3565063	1.59
468.6069336	0.05
469.5552368	1.57
470.2254639	0.29
471.4424438	3.10
472.3759155	0.13
473.5650635	0.19
474.3510742	0.21
475.4617920	0.83
477.5731201	0.19
479.3695068	2.37
480.5594482	0.36
481.5416870	0.60
483.3825073	12.26
484.6028442	2.28
485.4950562	1.96
489.4861450	1.11
493.5371094	1.38
494.2122803	0.10
497.5393677	3.15
499.3560791	16.46
500.2191772	0.34
504.0039062	0.09
505.4546509	0.45
507.4778442	1.51
510.5441284	0.19
511.4779663	3.04
512.6638794	0.10
517.4267578	91.81
518.4468384	1.45
524.4390259	0.21
525.4951172	1.88
526.5343628	0.06
535.4164429	100.00
536.4528809	4.76
543.8998413	0.09
544.5316772	0.87
553.4611816	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1662
Annotation	Spinosin
Peak:m/z	Relative Intensity
199.0327911	0.03
241.0475769	0.03
290.9919128	0.05
301.1872559	25.76
305.0189819	0.11
343.2932129	0.20
368.2001343	0.03
405.4823608	0.11
427.5442505	0.15
445.3179932	0.07
454.3972168	0.04
463.1475830	100.00
463.7622681	0.29
497.1660767	0.02
505.1532593	46.24
505.7855835	0.27
533.2229614	0.14
545.1951294	24.41
546.9334717	0.06
588.9748535	0.07
590.1329346	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0933
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
117.1401520	0.10
123.2172089	0.06
125.0775070	4.21
128.0946350	0.09
129.0390167	3.61
131.1088257	0.02
136.1726990	0.05
137.0280762	0.12
143.0373383	1.15
145.2814331	0.10
160.9317017	0.93
169.0197449	0.28
173.1607666	0.15
175.1553955	0.11
186.9454651	1.12
192.0723724	0.10
192.9001923	1.07
195.1634827	1.15
203.1539917	0.16
204.9920959	100.00
219.1576691	0.08
221.3303986	0.03
223.0122528	25.26
237.1817017	0.19
261.2213440	0.76
267.2783813	0.09
271.2652588	0.07
291.3299255	0.09
293.1759949	0.11
298.9948120	0.05
302.6383972	0.07
304.9568481	0.14
313.3516846	0.07
325.1067810	0.08
327.1303711	0.23
337.1543579	0.20
339.2875977	1.16
353.4338989	0.07
355.2369385	0.29
363.2677917	0.65
366.9135437	0.71
371.1145630	0.16
380.9913025	2.14
382.3991699	0.06
384.4171448	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.0969
Annotation	Alanyl-Glutamate
Peak:m/z	Relative Intensity
72.0542068	0.09
83.9935913	0.61
86.7357330	0.15
89.9124145	100.00
112.1313324	0.06
123.2465973	0.09
128.9318390	0.10
129.9964752	18.53
131.8180542	0.18
142.9506683	0.05
144.0571899	0.09
148.0850983	0.56
155.9418030	7.14
159.0714417	0.11
161.9702759	0.09
163.1604767	0.16
173.0368958	5.11
183.0023804	0.83
184.2114868	0.03
187.1187744	3.02
187.7229767	0.12
190.8202820	0.19
195.4706116	0.38
201.1661530	11.66
202.0387573	61.49
210.4611206	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9929428	0.64
128.9702301	1.81
135.9218903	0.06
137.9786530	0.06
145.2284851	0.06
147.0124054	3.29
153.0578308	1.46
161.1303406	0.11
173.0095520	1.60
179.2755737	0.14
181.1816711	0.64
190.9756012	100.00
193.0411377	0.51
205.0857086	2.12
209.0776215	12.89
223.0381775	2.90
234.9612122	0.12
246.8659668	0.33
261.1137390	0.15
265.2724915	0.12
287.3842163	0.12
303.7404785	0.14
312.9866638	0.03
321.4292603	0.15
323.2263794	0.04
325.4367981	0.28
341.3795776	0.04
343.4024963	0.15
349.0636597	0.06
365.4528503	0.03
366.9981995	7.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.2738
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
98.7908630	0.10
106.9985046	0.15
111.0583878	0.29
118.8458633	0.10
123.1379929	0.20
129.9779968	4.34
131.0133667	0.26
135.1167755	0.70
136.0894165	0.69
136.9613037	0.14
138.9897919	0.29
145.1083069	0.07
149.4598389	0.41
153.1279144	0.36
154.9921570	1.04
156.1141663	0.05
158.9656982	0.23
164.0544434	0.10
165.1515961	0.12
166.9105530	0.12
168.7860260	0.14
172.8506317	1.60
177.0979919	0.99
183.2080536	0.12
187.2138672	0.07
195.1032104	14.77
201.0483704	0.12
204.0592804	0.18
211.1717072	0.28
212.8885040	100.00
213.7638245	0.59
219.1020203	3.48
221.2018738	0.33
224.0691528	0.37
225.0936584	0.14
227.2679443	0.38
229.1106262	0.19
234.8769836	0.07
243.8348999	0.13
249.9485168	0.21
250.9449768	0.20
252.1889343	0.13
263.3279724	0.34
268.0592041	0.08
271.1122742	0.13
277.0829163	1.18
280.2528992	0.15
281.1654053	0.36
283.0445251	0.12
285.3482361	0.12
287.2135315	0.53
287.9682617	0.09
289.0334167	0.34
292.5279541	0.11
293.1556396	0.24
295.0871887	13.56
296.8536377	0.14
299.3768311	1.13
303.2389526	0.15
307.4068604	0.18
309.4205627	0.25
312.5777588	8.38
313.2658997	6.49
316.9553223	0.04
322.6693115	1.03
328.0216064	0.22
330.2954102	2.79
331.0823364	1.91
333.1781921	0.25
338.9981079	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.0807
Annotation	Nicotinate D-ribonucleoside
Peak:m/z	Relative Intensity
80.0952911	0.03
84.9820404	0.03
102.9792786	0.02
114.9321594	0.01
123.9290466	100.00
127.9219666	0.01
132.9788055	0.28
139.0735931	0.04
161.1098175	0.01
184.1913605	0.08
192.1810608	0.04
194.0765076	0.02
212.1777496	0.10
213.2141571	0.03
219.3046722	0.03
238.1873169	0.01
246.9171143	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1742
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9131470	0.36
177.1062622	0.08
187.1838074	0.03
190.9820251	0.05
193.1150208	0.05
204.9722137	0.10
211.0616455	0.02
217.0782623	0.04
223.0836487	0.07
231.0976410	0.04
234.9983521	0.07
241.1435699	0.42
251.0749817	0.07
252.6802673	0.08
255.2709045	0.04
258.8262024	0.37
265.4409790	0.09
266.1965332	0.08
267.2282410	0.19
271.1761475	1.12
272.3844604	0.06
276.9932861	0.10
283.2442017	0.04
288.2293091	0.20
288.8936157	1.32
294.9073792	0.18
301.1532593	0.40
302.9772949	0.02
305.3203125	0.08
306.9183350	2.98
307.7463989	0.03
317.1389160	0.02
362.2135620	0.03
365.2076416	0.09
367.1010132	0.37
367.7655029	0.05
385.0553589	0.43
388.8701782	0.09
397.1805420	0.20
402.5722046	0.17
403.1822510	1.46
413.0639648	0.07
414.4566040	0.09
415.1246338	0.20
416.1956177	0.02
419.5394897	0.03
421.0735474	0.91
433.0558472	100.00
433.6718140	0.21
435.4987793	0.22
436.2938843	0.25
439.0364380	0.68
511.2423706	0.02
529.2012939	0.21
546.9349976	0.50
549.1653442	0.05
555.8015747	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2144
Annotation	Stachyose
Peak:m/z	Relative Intensity
202.8348694	0.09
214.9591217	0.30
221.1242371	5.95
234.9154968	0.44
250.7078094	0.66
262.8867493	0.34
280.9206543	1.25
304.8775024	0.72
309.2887573	0.08
310.9884033	0.46
317.3503418	0.48
323.2436523	2.24
341.0524902	28.16
365.1487427	0.49
371.0136108	0.15
383.12677	100.00
383.7575684	0.49
385.3288574	0.32
407.2734985	0.59
409.2739258	0.95
411.355896	0.16
412.9094849	2.29
425.0042725	1.77
433.1864624	0.10
437.3163452	0.09
442.8685913	15.04
443.9053345	0.33
467.2561646	0.26
472.8326416	0.28
481.2758789	0.21
485.1702271	27.08
502.8864746	2.01
504.2348022	0.09
541.4168091	0.16
545.2189331	1.11
575.3848267	0.37
590.0311279	0.13
601.2408447	0.10
619.2712402	3.61
647.0961304	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
60.1006012	0.09
68.0137329	0.12
68.9616089	0.39
70.0077057	0.52
70.8525009	0.05
71.8769531	0.04
73.0260849	0.02
73.8191986	0.09
79.8899612	0.12
80.9068909	0.08
82.8990936	0.14
83.7030945	0.17
84.6188660	0.03
85.9506226	0.11
87.0357819	0.07
93.1001739	0.04
94.1582336	0.12
95.9428863	0.07
97.0063324	0.23
102.1451263	0.20
107.0223083	0.23
107.9962921	0.44
110.9032593	0.32
112.4805450	0.28
113.8067627	0.03
115.0770569	0.18
116.1052399	0.10
121.2084198	0.18
122.0737762	0.07
123.9158630	0.02
125.9845581	0.10
127.0931549	0.20
127.8575287	0.05
129.2245483	0.22
135.9145203	0.04
137.9387970	0.11
140.1544342	0.10
141.1310272	0.05
142.2789764	0.06
144.0655670	0.05
154.0603638	0.03
155.1181488	0.09
155.9327393	0.13
156.8806000	0.38
158.8315277	100.00
160.1272736	0.08
164.0924530	0.41
172.2433319	0.07
176.4230194	0.09
177.0384521	0.22
178.9324341	0.14
182.0005646	4.33
182.6356354	0.03
184.1308441	0.08
186.1484528	0.17
200.4303284	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	568.2192
Annotation	Decarbamoylnovobiocin
Peak:m/z	Relative Intensity
167.1206360	0.03
168.0889740	0.22
168.9990997	0.12
170.0547333	0.21
174.1533966	0.16
175.8529358	0.04
177.8861389	0.09
179.0346985	1.27
185.2991180	0.09
189.0784607	0.17
189.8458252	0.28
196.0902405	0.15
197.1690063	1.13
197.9450684	0.09
200.0375977	0.23
203.0892029	0.06
213.0344543	0.28
213.8914490	0.04
215.2130127	0.77
223.0709534	0.38
224.1714630	0.26
228.1280975	0.37
229.0601196	0.38
229.9665833	0.04
231.2012634	1.72
240.1613770	0.70
241.0404968	0.05
242.2565002	0.21
246.1002960	0.26
249.1528473	9.91
253.7904205	0.05
263.1494751	0.20
268.1719971	3.64
270.0814209	0.32
271.3525696	0.28
272.2288208	0.15
274.2500610	0.23
279.2839355	0.04
281.0452271	2.86
286.1582031	20.70
288.1148071	0.47
298.2089233	0.10
300.0123901	1.94
302.1088562	0.97
310.1655884	2.77
312.2459717	0.24
314.1405640	0.33
315.2224731	0.23
316.0045776	0.33
317.0210571	0.12
318.2017822	47.14
320.1377563	9.86
320.9646606	0.09
329.8638916	0.70
331.1211548	1.47
332.0619507	1.23
334.1022949	0.91
343.1718750	0.12
347.1973267	0.04
352.0734863	41.09
352.6808472	0.34
359.2786255	0.18
360.0697021	0.63
364.1129761	0.10
372.1476440	0.10
376.3428955	0.44
377.2033691	0.40
378.0843506	0.10
388.1707153	0.05
394.9181519	1.21
416.0087280	0.04
421.2456665	3.51
424.3050537	0.14
434.1422729	0.07
439.0729980	100.00
439.6740723	0.29
443.9677734	0.12
451.9350586	0.24
460.1013794	0.04
462.1938477	0.21
463.8541260	0.87
464.4704590	0.04
465.1917725	0.11
478.1349487	0.20
480.1933594	0.19
482.9083862	0.11
507.2061157	0.13
508.0728760	0.07
510.0938110	0.10
519.8455200	0.25
522.0488281	0.06
523.0355225	0.04
524.0270386	0.17
532.1987915	0.79
538.3251343	0.22
550.1318970	29.68
550.9414673	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1112
Annotation	Thiamine
Peak:m/z	Relative Intensity
79.9102249	0.03
80.8570404	0.92
84.9443436	0.07
108.7835541	0.01
110.0245972	0.70
121.9535065	100.00
126.0531769	1.05
137.9557037	0.09
143.9251099	52.84
145.0848846	0.06
156.0193634	3.70
180.9664764	0.03
207.3208313	0.06
230.2971802	0.09
233.9416962	0.05
235.2432861	0.14
247.0995026	0.13
248.2615814	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.34
Annotation	Unknow
Peak:m/z	Relative Intensity
242.7565002	1.59
243.8475189	0.14
245.0898743	1.77
246.0407715	0.32
252.9616699	0.58
254.8287506	0.83
259.3284912	0.28
261.0798950	0.22
269.2373657	0.95
271.1814575	2.32
272.9382935	1.09
281.1455994	1.71
282.1716614	0.12
283.2116394	0.47
284.2369995	0.36
285.0942078	0.90
287.1474609	21.10
289.1444397	16.61
295.2229614	0.23
297.1295776	2.76
299.2346802	4.90
311.2497864	0.18
313.1735229	0.23
320.8621216	0.57
326.4023132	0.31
328.9597778	1.00
335.4976196	0.52
337.2397156	0.65
338.9407349	0.96
341.3887939	1.88
345.3051147	0.21
349.2681274	5.21
350.2130127	0.85
351.0977783	0.16
363.2732544	0.41
368.9967346	0.41
378.3692017	0.88
379.2568359	1.30
379.9644165	0.20
381.2063293	1.21
382.9816284	2.27
391.3159790	1.90
395.2089233	0.87
397.1804199	5.77
404.3134155	0.92
405.2313843	4.49
407.2120972	27.76
409.2668457	1.47
412.2111206	0.58
413.2080688	1.43
419.1769409	2.79
423.0407104	1.52
425.0559082	36.66
425.6936646	0.41
433.1456909	5.40
435.2343750	0.90
436.2855225	0.99
437.2431030	0.15
445.0437622	2.17
446.3969727	1.07
447.1465454	1.29
449.2065430	2.46
451.1152954	27.07
464.0372314	0.39
467.1459351	1.78
473.1648560	0.33
475.5314941	0.43
481.2959595	1.97
482.4331055	0.28
483.2532959	2.23
489.3305664	0.33
491.4012451	1.09
493.3355713	4.96
499.2809448	1.00
507.7011108	0.15
511.3400269	48.15
512.4621582	2.87
515.1157227	1.18
517.1689453	1.32
519.0695801	0.70
523.0169678	0.64
525.3559570	1.13
527.1740112	3.75
529.0416260	0.63
531.2104492	0.43
533.2678833	0.18
535.2833252	2.25
541.1812744	3.54
543.2684326	5.99
545.2326050	0.50
549.4511108	0.60
551.4835815	0.78
553.1633301	12.36
554.3915405	0.22
555.4055786	0.32
559.0908203	60.95
561.1676636	11.70
569.3245850	0.88
571.0847778	18.52
572.1459351	0.33
575.3701172	0.49
577.1870117	79.77
578.9003296	0.23
581.3954468	1.60
587.1808472	1.47
589.1333618	2.94
594.9414062	0.25
597.1354370	3.98
599.0410156	0.21
600.1015015	1.43
601.2246704	1.18
607.4391479	2.24
613.3023682	0.76
616.3306274	0.23
619.3898315	1.89
625.4092407	11.63
626.5593872	1.45
631.4102173	0.34
635.1577759	0.22
636.9862671	0.28
653.1914673	2.12
657.2507324	0.67
661.1132202	1.15
665.1023560	0.34
669.2403564	7.02
670.6220093	2.06
673.2862549	0.31
677.0070190	0.87
677.6569824	0.38
679.0897827	25.03
687.3704224	42.04
688.4727173	4.40
695.2149048	8.49
697.1321411	36.89
705.0509033	2.66
711.2312622	0.75
713.0670776	2.82
721.0273438	2.50
721.7810669	0.51
723.1382446	48.79
724.3126831	0.78
731.1340942	2.05
731.8941650	0.76
763.9476318	1.04
772.0000610	1.11
772.6705933	0.14
773.2744141	0.32
777.3975220	0.78
787.1787109	1.00
787.9649658	0.21
789.3104858	7.54
790.3015747	0.43
805.2777100	3.50
806.0687866	1.29
813.3246460	3.34
814.3000488	1.52
818.8529663	0.24
831.2455444	100.00
832.4028931	16.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.14
Annotation	Unknow
Peak:m/z	Relative Intensity
176.9589233	0.85
193.2219696	0.35
202.2396545	0.48
203.2064362	0.12
205.4168549	0.17
235.0988922	0.32
243.2045593	2.28
269.0703125	0.39
271.0336609	0.18
281.5922852	0.33
287.0368347	100.00
288.2358398	0.45
290.9815063	0.29
297.1994629	0.53
300.3475342	0.31
301.2101440	4.53
319.3373413	0.18
323.2368164	0.40
335.1371460	0.56
337.1881104	8.84
339.2219238	0.42
341.1264038	0.22
343.5647583	0.36
352.0222168	0.25
353.3379517	1.87
355.0914917	1.74
365.0129395	0.72
368.0509644	0.16
393.2924194	0.36
405.2847290	0.84
407.3026123	0.35
417.3745117	0.28
421.3864746	0.65
425.4664307	0.18
429.3824463	0.25
431.2322388	2.64
432.2331543	0.25
433.2766113	0.17
437.1625366	1.68
439.5773926	0.21
447.1830444	6.90
449.1874390	52.19
450.3843384	0.19
455.2292480	22.21
456.0737305	0.36
473.1516724	6.04
474.3455200	0.33
475.2147827	0.39
481.4307861	0.33
482.1198120	0.37
489.4786987	0.45
499.1760864	5.30
507.4494019	1.68
519.2108765	1.98
534.9958496	0.50
537.4183350	0.95
539.4047241	0.27
545.5202637	1.11
563.3781738	5.11
565.2178345	3.12
566.4628296	1.09
571.3479614	0.25
579.1505737	0.73
581.1845703	2.77
589.3375854	1.20
592.2454224	0.47
594.2081909	0.32
601.6110229	0.46
602.8225098	0.56
607.1849365	32.15
608.0601196	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.3
Annotation	Spumigin B1
Peak:m/z	Relative Intensity
221.1367035	9.75
262.8073730	7.61
323.2785034	1.24
375.4591675	1.67
409.3692017	6.66
412.2238770	1.04
441.2060547	2.73
445.2084961	8.93
445.9629517	6.87
454.3846436	3.26
463.3857422	1.02
478.4353638	1.73
499.0493164	1.25
513.7498169	1.90
522.2969971	1.95
535.9495239	2.29
544.3768921	100.00
546.4531860	0.36
547.8266602	0.78
589.6452026	2.52
590.3038330	0.73
594.3964844	16.87
607.1722412	0.54
616.5637817	8.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0883
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
150.9685822	0.59
152.9629669	0.03
164.889267	0.05
169.077774	0.06
176.9391632	0.03
178.9194641	1.58
189.0079041	0.18
190.0454102	0.16
191.067749	0.08
192.6239624	0.02
197.2706299	0.02
198.2574768	0.02
201.230835	0.02
203.2503662	0.05
207.0808258	0.04
209.2253418	0.03
211.4223022	0.01
212.0506287	0.05
217.2482605	0.07
219.2702332	0.01
221.0107422	0.21
225.8905182	0.07
227.0183258	0.10
229.0848999	0.35
232.9646301	0.01
234.906311	0.03
241.1155853	0.02
241.8952332	0.02
242.9951782	0.01
251.2695923	0.02
254.1707153	0.03
255.131897	0.36
256.0629883	0.07
257.3091736	0.07
259.2649536	0.04
271.1276245	0.45
272.3110962	0.17
273.1430359	0.28
281.2341003	0.03
282.9842834	0.12
285.0210571	0.12
287.0247498	0.02
297.2529907	0.09
300.0739136	23.40
301.0305786	100.00
302.0716553	0.59
311.1421509	0.12
313.1727295	0.29
315.1394348	0.02
319.1044006	0.10
325.1699219	0.29
327.1547241	0.07
330.0227051	0.02
334.9750977	0.01
337.2523193	0.07
338.2062378	0.02
341.1107178	0.05
343.1645203	2.12
343.9607544	0.03
354.2547607	0.06
355.2999878	0.02
368.9737244	0.09
371.0795898	0.07
373.1121216	0.31
375.2972717	0.01
377.124115	0.02
381.2480469	0.04
383.4824829	0.03
385.4346924	0.02
387.1503906	0.01
395.5184326	0.03
403.1809387	0.01
409.2187805	0.04
414.9664612	0.08
419.3756104	0.09
435.3479004	0.02
445.0380249	0.29
446.394928	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	941.5119
Annotation	Pharbitoside A
Peak:m/z	Relative Intensity
277.3145142	0.14
322.9982300	0.09
373.3477783	0.13
389.1862183	0.71
391.1177979	0.16
393.1681519	0.10
395.3002319	0.17
405.5404663	0.13
407.5130920	0.37
415.6616211	0.09
419.1972046	0.56
421.6818237	0.14
423.4537354	0.69
425.7108154	0.11
433.3106689	0.14
437.2955322	0.80
439.3895264	15.67
440.0064087	0.05
441.3941650	7.08
442.0753174	0.30
457.6253662	0.21
463.1416626	0.87
465.8546753	0.17
467.7646484	0.24
479.2191162	0.11
481.2583008	0.38
491.6567383	0.21
509.4390259	100.00
510.3621216	0.53
525.4913330	0.26
537.5550537	6.70
553.7285156	0.20
555.4804077	0.21
581.2938843	27.58
581.9263916	0.12
586.2752075	0.21
593.6365356	0.21
597.5609741	0.14
599.4414673	5.68
615.4183960	1.03
617.3735962	1.29
651.3768311	0.08
717.4641113	3.51
733.2863770	0.32
733.8925171	0.15
735.6132202	0.65
750.7536011	0.25
761.5138550	1.56
769.3804321	0.11
779.5092773	9.71
780.6793213	0.73
790.6384888	0.12
805.6281128	0.18
834.3734741	0.12
863.7005615	0.38
864.9771729	0.42
879.4835815	5.03
897.4235229	0.09
923.3529663	26.09
924.4729614	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.2667
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
195.1058655	0.13
197.1454163	2.25
223.0779724	1.91
241.0888062	12.49
259.1226807	100.00
314.3299561	0.12
319.9747925	0.05
339.4721069	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	673.3073
Annotation	Argadin
Peak:m/z	Relative Intensity
207.2280884	0.04
216.9837952	0.04
220.5235901	0.04
259.0827026	0.06
261.4458008	0.04
276.9392090	0.06
299.6842041	0.07
301.2755127	0.03
303.5509033	0.04
318.8172607	0.04
319.4765625	0.07
333.4707642	0.06
335.2840271	100.00
335.9343262	0.04
337.1380005	3.11
343.2702026	0.02
367.1261597	0.06
377.0529785	0.03
383.3035889	0.04
395.0911255	0.05
397.2712402	0.02
417.2565308	0.03
435.4088135	0.02
467.0709229	0.01
487.2927246	0.02
497.3737183	0.03
507.2627563	0.02
511.1598511	0.06
513.3173828	0.05
525.2230835	0.04
540.1372070	0.02
543.8176880	0.02
552.4973145	0.05
555.4802856	0.05
575.1841431	0.03
592.4323120	0.07
599.0620728	0.04
601.2068481	0.12
609.0181274	0.04
611.2971191	0.10
628.3916626	0.06
629.0720215	0.18
637.5650024	0.03
639.2396851	0.03
641.7437134	0.07
655.3966675	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	783.1982
Annotation	Unknow
Peak:m/z	Relative Intensity
285.0823364	0.09
286.3180542	0.06
289.2038574	0.04
301.1573486	28.41
302.0826416	0.18
317.2351074	0.10
319.1925049	0.43
337.2236938	1.67
357.5769043	0.16
379.1784668	0.04
419.2441406	0.07
420.8244629	0.04
431.0458374	0.65
436.8985596	0.35
438.2365723	0.14
445.1159058	0.36
445.7890625	0.06
449.3436279	0.10
463.2445679	10.69
464.3423462	0.08
467.2865601	0.10
473.2312012	0.62
481.1993408	4.61
491.4191284	0.06
494.9882202	0.13
505.2617188	7.61
516.5036011	0.21
517.1160889	0.29
531.0993042	0.12
545.1129150	4.35
557.1897583	0.05
559.5299072	0.41
561.2442627	0.20
573.6478271	0.34
575.1034546	0.51
588.9315186	0.22
607.1889038	8.28
619.3786621	0.28
620.6894531	0.33
621.3676147	0.98
631.1704712	0.11
637.1754150	0.15
639.1869507	100.00
640.6243286	0.12
647.2875366	0.07
648.6557617	0.14
649.3955078	0.04
652.3578491	0.12
659.4263916	0.11
663.1829224	2.46
679.5595093	0.25
681.2302246	63.55
703.4705200	0.09
707.0791626	0.14
717.1776123	0.05
721.2179565	15.27
721.8499146	0.22
723.0919800	1.27
737.4307251	0.22
738.3737183	0.50
739.3406372	0.59
746.6163940	0.04
747.2844238	1.04
764.9706421	1.42
765.6120605	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1089
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
137.0868378	0.05
148.8686676	0.05
151.0126648	5.31
165.1112671	0.19
169.1053314	0.71
178.8247986	0.80
179.8353424	0.31
181.2475281	0.07
183.1204529	0.03
189.0742188	0.03
191.1027222	0.08
192.9384155	0.26
201.1331482	0.23
205.0474548	0.05
206.9888153	0.05
215.0892334	0.12
225.2907410	0.02
241.1111450	0.08
243.3435059	0.07
251.3955078	0.04
259.2052307	3.39
269.0582886	100.00
270.1257324	0.03
281.0676575	0.08
283.2222290	0.08
286.0678101	0.09
287.0571289	10.35
287.6767273	0.08
291.1620483	0.07
295.3400879	0.06
297.2304077	0.17
311.0972595	0.28
315.5159607	0.10
320.0321960	0.05
323.1681213	0.72
327.2968445	0.03
329.1869812	0.16
335.1858521	0.08
343.1573792	0.58
344.3604126	0.06
347.3020630	0.21
355.1743164	0.55
363.1658936	0.02
367.0521545	0.01
372.8036804	0.02
387.2231140	0.03
403.3824158	0.10
405.2011719	0.24
413.3536682	0.09
421.3147583	0.34
431.0586853	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.15
Annotation	Apiin
Peak:m/z	Relative Intensity
168.1549988	0.02
171.7815704	0.06
183.0058289	0.04
185.1140594	0.05
191.3006439	0.10
196.9536591	0.07
201.1854095	0.02
209.1112366	0.36
215.1105194	0.02
224.7589417	0.06
226.4047546	0.22
227.2952576	0.11
243.4303589	0.03
247.1479492	0.14
249.1335449	0.04
255.4106445	0.09
265.0579224	0.13
269.2281494	0.02
271.0605469	100.00
271.6746521	0.21
272.6509705	0.17
275.0914001	0.06
276.0579834	0.02
283.1162109	0.06
285.1816711	0.09
287.3012695	0.01
289.1990662	0.17
291.4342041	0.09
303.067688	0.02
318.9439697	0.03
322.3178101	0.07
322.937561	0.01
343.4455566	0.11
355.0333252	0.03
358.0559082	0.04
365.0081787	0.06
367.1590576	0.04
371.1917114	0.01
379.4481201	0.17
380.3751831	0.05
394.3579102	0.02
402.0925293	0.02
403.1495361	0.09
409.237854	0.02
411.1755981	0.06
413.0258179	0.05
419.3496704	0.04
428.1346436	0.04
430.3182983	0.06
431.149353	0.06
433.0767212	0.19
434.1715698	0.09
436.0584106	0.34
444.3173828	0.04
462.2739868	0.02
473.2227783	0.02
479.303772	0.03
480.3867798	0.07
481.6466675	0.21
488.3276367	0.03
489.2739258	0.13
490.4007568	0.01
499.1434326	0.07
501.3046875	0.05
507.2557373	0.03
512.9248047	0.02
516.9550171	0.01
518.9400635	0.03
521.0697632	0.07
529.0349731	0.30
533.131897	0.04
546.7460938	0.21
547.4053345	0.26
555.8546143	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	luteolin-4'-O-glucoside
Peak:m/z	Relative Intensity
132.0054626	0.05
136.9051666	0.24
141.0861206	0.03
142.9862823	0.04
144.966217	0.16
145.7393951	0.05
147.1237793	0.08
148.2409515	0.06
151.0159912	1.98
152.9552307	0.70
159.1800995	0.13
160.5683289	0.09
163.1297913	0.53
165.0221252	0.23
169.0757599	0.57
171.0574951	0.05
174.1534729	0.33
175.0143433	0.27
176.3560486	0.13
179.0777283	1.41
180.0854797	0.17
181.1298523	0.03
183.7687531	0.16
185.2214661	0.10
187.0154114	0.20
189.1127625	0.11
190.4396973	0.09
191.3022461	0.05
192.180954	0.09
192.9467468	0.56
196.0179596	0.03
197.1379242	0.06
199.0228577	0.08
200.253418	0.07
201.1281586	0.13
203.0511017	0.30
205.2614746	0.07
205.8653412	0.03
207.0927429	0.20
209.2650909	0.06
211.1305237	0.59
211.9345703	0.08
213.3745422	0.17
215.0727386	0.29
217.2015686	0.15
218.2608643	0.07
219.2056885	0.14
220.009613	0.05
221.3466492	0.06
223.1414185	0.06
224.2876587	0.07
224.9875488	0.05
227.0458527	3.86
229.7935486	0.11
231.1199799	0.18
234.1089172	0.08
235.1362	0.04
237.2492371	0.33
239.2796631	0.91
240.1064758	0.02
241.1018982	0.44
243.0619812	1.09
245.0940247	0.24
246.021759	0.02
251.3498535	0.21
252.9483643	0.22
255.1209106	14.79
256.1174927	3.22
257.1973572	0.86
257.8794556	0.06
259.1162109	0.77
260.3791809	0.12
265.1988525	0.22
267.1622925	0.33
269.1450195	1.82
269.8963013	0.12
271.1580505	0.34
272.8329468	0.15
275.2257996	0.24
281.1429443	0.40
284.0466919	91.40
285.0471802	100.00
286.0528564	0.91
297.334137	0.35
298.0918274	0.38
299.2005615	2.60
300.2594604	0.31
307.2908936	0.10
309.2044678	0.26
310.007019	0.02
311.0048523	0.34
312.9508362	0.10
314.1278687	0.10
320.3451233	0.07
321.074707	0.11
323.8215637	0.10
325.2608032	0.02
327.0766602	22.22
328.1719971	1.08
329.119873	0.09
339.0476074	0.22
351.1969604	0.02
357.1216125	2.41
358.3830872	0.16
368.3886414	0.05
369.2988586	0.02
371.4482727	0.04
379.1195068	0.08
387.3415833	0.03
393.188446	0.04
401.2290039	0.12
403.0671082	0.10
411.0637512	0.04
419.2098083	1.17
420.4277954	0.04
429.2075806	0.17
430.3415527	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	995.3035
Annotation	Parishin
Peak:m/z	Relative Intensity
280.2593384	0.15
283.2270508	0.08
285.2699280	0.11
294.8407288	0.47
310.9991455	0.07
323.1422119	0.19
387.2680664	0.82
390.2965088	0.12
401.0660400	4.19
431.2419739	1.09
432.2870483	0.24
443.3239746	0.30
445.0319824	0.10
449.0794678	15.99
449.6882935	0.28
461.3557129	0.31
483.7948608	0.09
500.9854126	0.07
558.9652100	0.42
563.2060547	0.13
593.4442139	0.11
606.9858398	0.10
609.1464233	0.64
621.1591187	0.19
625.1638184	9.95
627.1911011	0.38
637.6540527	0.24
639.5466919	0.04
651.2258301	0.07
653.3270264	0.23
656.6226196	0.27
667.2185669	4.52
671.3894043	0.32
679.2239380	0.06
682.6290283	0.21
689.5186768	0.08
706.8187256	0.78
708.4999390	0.08
721.4890137	0.05
722.1446533	0.09
725.2395020	0.55
749.1990967	0.19
767.6005859	0.74
768.2058105	3.13
769.1120605	0.59
788.3599854	0.35
789.2462158	0.12
802.7824707	0.50
817.4097900	0.13
819.3334961	0.60
823.3837891	0.47
825.3023682	0.22
833.2000732	0.66
837.1269531	0.59
844.5498047	0.26
851.0308838	100.00
851.6915283	0.49
859.2229004	0.26
861.0993652	0.48
878.9843750	0.35
884.5198975	0.30
887.2937012	0.29
893.1405029	22.28
914.5014648	0.21
933.0212402	7.28
935.7593994	0.06
946.9891357	0.23
959.1495361	0.11
977.4218750	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2142
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
240.1947479	0.09
241.3473511	0.07
255.9736023	0.10
258.4067993	0.08
259.0738831	0.14
263.2143860	0.07
265.0242920	0.35
268.3579407	0.13
272.2623901	0.04
276.2119141	0.05
277.1066284	0.20
285.1298218	0.17
299.1249695	0.48
300.0391541	0.36
301.2193909	0.69
303.2014160	0.18
305.0516052	0.32
315.1292114	77.57
316.2947998	0.12
319.1094971	0.55
327.3661499	0.14
337.1681519	6.24
341.1838379	0.20
355.1995239	0.26
361.2205200	0.03
379.2534790	0.71
384.5442505	0.09
397.2446289	0.16
400.5579224	0.07
414.3413086	0.07
419.1547852	0.25
421.4788208	0.04
427.3896484	0.08
437.1405640	1.21
438.6382446	0.07
441.6499634	0.05
445.1704712	0.14
447.4834595	0.06
459.3723755	0.92
462.9584351	0.17
467.3638306	0.07
477.2366943	1.39
481.1184082	8.62
487.1001587	0.21
489.1375732	0.04
490.2918091	0.25
505.3980713	0.39
513.2197876	0.04
519.1400146	0.84
527.0907593	0.10
549.0782471	0.09
553.2106323	0.12
559.1583252	0.43
571.4598389	0.25
576.8930054	0.06
591.3605957	0.62
594.3051147	0.11
602.3960571	0.44
603.2921753	0.03
617.4418335	0.42
619.3391113	0.05
621.1972046	4.29
627.6182251	0.23
632.4564209	0.23
633.3156128	0.59
635.1902466	1.73
647.4533081	0.05
651.5067749	0.71
653.1952515	100.00
663.1904297	0.42
665.5064697	0.05
666.3991089	0.11
670.4257812	0.08
671.2105103	0.06
675.1796875	0.20
677.0180054	1.43
695.2057495	67.45
700.9911499	0.06
703.2700195	0.13
706.1521606	0.09
709.8899536	0.24
715.5947266	0.14
717.2078247	0.11
724.2561646	0.05
732.7274780	0.07
735.1400146	18.76
737.0495605	3.11
738.4403076	0.16
740.8069458	0.23
751.0838623	0.11
752.4187622	0.94
753.5268555	0.42
757.8546753	0.07
760.9959106	0.22
761.6030273	0.16
765.9884644	0.05
767.4602661	0.15
768.5348511	0.09
769.5226440	0.16
778.1134033	0.36
779.0703125	1.83
779.9611206	0.12
797.4541016	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9944458	3.37
199.0089417	0.59
217.1430054	0.20
229.0515137	0.46
271.1988220	0.29
272.9184570	52.06
337.8514099	0.16
339.6875000	0.03
347.1512146	0.05
385.0443726	1.87
386.9295654	100.00
387.5834656	0.13
427.1738586	0.48
429.0823364	0.14
432.8310852	0.11
439.0063782	0.15
444.9450378	0.07
454.9361267	0.37
456.8080444	0.69
457.9071350	0.03
472.6617126	0.08
483.2446594	0.05
491.0579529	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.1956
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
244.0363159	0.08
287.1796265	0.16
341.1599121	0.19
349.1959229	0.10
359.1379395	0.08
361.0088501	0.07
376.0945435	0.46
383.4779053	0.69
395.1356201	0.14
396.7496338	0.20
407.0671387	0.17
411.1178589	0.47
419.2048340	1.74
423.0892334	0.12
425.1093750	0.46
431.3164673	0.57
437.1085815	2.21
443.1612549	0.91
446.5843506	0.15
461.1859131	14.33
466.7938232	0.10
479.0786743	3.85
484.9953613	3.75
485.7000732	0.06
487.1362305	0.23
491.3270874	0.18
497.1544800	0.59
509.2044067	0.80
514.4943237	0.29
515.1448364	3.09
517.7020264	0.39
525.2595825	0.27
527.1680298	7.71
533.0745850	0.11
542.5836792	0.40
545.1569214	8.49
548.6353149	0.15
563.2030640	84.22
565.1286011	0.22
571.2904663	0.32
581.1326904	100.00
587.7172241	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1245
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
136.9497375	1.83
147.2198181	0.03
148.7037811	0.01
151.1784668	0.04
159.1892548	0.03
159.8661194	0.03
161.0518036	2.60
163.0370789	0.04
165.0818634	0.06
175.0466919	0.01
179.0176697	0.19
181.0923462	0.02
187.3218994	0.01
188.1156921	0.04
189.1511688	0.03
191.0605164	0.22
203.1503906	0.08
205.1782837	0.17
209.0605316	0.04
211.2287598	0.03
221.1164703	0.01
227.3579102	0.02
230.9937134	0.04
238.8410339	0.04
245.1282349	1.98
257.4061890	0.05
269.5441284	0.12
289.1588440	100.00
290.0191040	0.05
299.0809326	3.53
313.2108765	0.15
327.1441650	0.02
355.0586548	0.05
367.4007874	0.07
373.3896484	0.02
407.3032837	0.15
433.1927490	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	799.3394
Annotation	Unknow
Peak:m/z	Relative Intensity
224.9933472	0.19
240.9207458	0.75
259.3132935	0.15
260.8211060	0.22
263.0897217	0.11
275.1227722	0.12
277.3663635	0.05
284.0833435	0.19
285.3340149	0.10
295.3139343	0.12
301.1185913	0.29
305.2035217	0.92
313.5736694	0.11
317.3508606	10.22
319.1451721	3.60
325.3542786	0.09
337.1746216	15.40
355.1624146	0.45
361.1533203	1.05
375.2316895	0.32
379.1566772	3.83
397.0578003	0.50
401.2583618	0.28
419.3462524	0.79
427.1347656	0.10
437.0949097	7.24
439.1690063	0.04
440.9217529	0.10
454.9205933	0.14
463.0628052	0.34
481.1907349	100.00
509.1713867	0.09
518.1281128	0.24
537.3410645	0.07
542.2885132	0.10
545.2452393	0.25
617.5214233	0.13
623.1268921	0.40
629.3781738	0.08
631.3538208	0.31
641.3400879	0.09
651.4556274	0.06
655.1896362	2.25
655.8114014	0.06
662.6102905	0.07
665.2875366	0.05
667.4191284	0.07
668.2400513	0.10
685.1204834	0.19
697.2332153	0.63
697.8530273	0.13
711.6387329	0.07
725.2672729	0.13
735.1554565	0.13
737.1830444	0.42
738.4554443	0.41
739.5516968	0.11
741.3209839	0.08
750.7723999	0.21
755.1651001	0.13
758.4163208	0.05
764.7636108	0.13
766.0870972	0.08
767.2096558	0.16
777.3492432	0.36
780.3839111	1.93
781.3696899	2.49
782.0984497	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1526
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
161.0184326	0.10
163.1369781	0.36
165.0361023	2.16
171.0184937	0.61
179.0717468	0.96
181.2009277	0.48
185.0967407	1.58
187.0075989	0.18
189.0907745	1.19
191.1381378	0.14
192.0373688	0.11
193.0044708	0.24
198.8361816	0.10
201.0654602	0.16
203.0041199	0.14
207.0575867	0.08
213.0376892	1.99
215.2328644	1.00
217.0544739	0.21
226.9959259	2.03
229.2292480	0.43
231.0943298	35.59
233.1917725	0.57
237.0657959	0.25
239.3657074	0.53
241.0058899	0.13
243.1315918	8.59
245.0689545	1.05
247.1167297	1.63
249.0207825	0.82
253.1343384	0.60
255.1010895	9.81
256.1252441	0.13
257.2215881	1.51
267.1675415	2.95
269.1614380	7.66
271.1218872	0.93
273.0521851	47.68
275.0669250	14.78
275.6920166	0.16
279.0902710	2.37
280.3435974	0.13
281.1584473	0.40
283.1803589	0.47
285.1368103	24.24
287.1661987	8.56
289.2407227	1.32
291.0322266	60.06
293.2235107	0.12
295.1544800	0.30
297.1508179	10.70
299.0991211	7.42
301.0031128	1.76
303.1509399	10.90
309.2404175	0.62
311.1925049	0.44
312.5026245	0.27
313.2501221	0.73
315.0251465	0.79
317.0398560	0.10
325.0888062	3.86
325.8016968	0.12
327.3675537	0.42
329.1444092	0.27
331.1154785	2.01
333.0610352	1.31
339.3281860	0.08
347.1074829	0.07
350.9406738	0.19
354.1499023	0.30
355.3956299	0.08
359.0548706	0.29
365.3081665	0.09
372.9523926	0.22
377.2348633	0.33
382.9851074	0.71
389.2587891	0.11
391.0029907	0.56
393.0737915	100.00
393.7288818	0.73
395.1228638	25.39
395.7598877	0.15
399.2603149	0.23
401.2135620	4.61
405.1739502	7.73
407.1352539	6.92
409.1557007	42.43
411.0590820	71.44
419.2143555	33.86
421.1154175	2.61
423.1244507	4.87
425.3685913	0.10
427.1499634	40.09
433.2760620	0.54
435.0803833	0.05
435.7893066	0.04
437.0472412	69.30
437.6692505	0.16
439.0581665	13.42
451.1027832	2.26
479.0083618	0.07
517.1729736	0.13
526.3627319	0.11
527.0922241	2.49
534.3740845	0.36
535.0921021	0.30
535.7649536	0.29
539.7169800	0.14
543.1470337	0.18
545.0516968	76.44
545.7606812	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	277.2158
Annotation	11E,13E-octadecadien-9-ynoic acid
Peak:m/z	Relative Intensity
78.8623505	2.72
80.9993744	5.47
83.0521851	0.34
85.0599976	1.52
91.0183258	3.97
92.9707794	15.67
94.9660187	10.67
96.7932053	4.28
98.8783188	0.35
100.9770126	0.20
104.8399353	3.03
107.0200348	16.73
109.0425873	6.82
110.9530029	1.54
113.0872879	0.29
115.0042725	0.29
116.9733810	1.91
119.0719833	8.30
120.9947968	36.79
123.0339432	2.46
125.0201721	1.35
126.9492722	0.44
129.0807495	0.85
130.9836731	3.16
132.9811249	10.07
135.0712433	86.20
137.0397644	2.27
139.0697937	1.36
140.8605652	0.88
143.0575256	0.61
145.1001892	6.92
147.0804443	10.39
149.0135193	100.00
151.1191254	0.92
152.9689026	3.45
157.1738281	2.00
159.0441895	12.39
161.1039886	17.70
163.0269470	45.11
165.0723877	1.25
167.0197601	6.49
171.1496124	4.82
173.1808167	7.79
175.0821228	10.25
177.0919800	13.15
179.1049194	4.62
181.0360260	19.14
182.8894348	0.15
185.1439209	7.91
189.0545044	3.25
191.2977753	1.64
193.1018372	4.85
195.1221619	22.52
199.1277161	8.62
201.1989136	0.29
203.0643616	7.43
203.6787720	0.12
207.1871948	13.58
209.1680908	5.29
213.1756897	9.76
215.0382080	0.44
217.1760559	9.68
218.0008240	0.24
221.1184082	24.51
223.3748474	0.54
231.1694946	14.39
234.0508423	0.09
235.2304688	19.19
236.0823975	0.28
240.0400085	0.18
241.1868286	37.31
245.1390381	0.10
249.2222290	0.74
257.1654358	0.24
259.2551575	42.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1558
Annotation	1-(3-Methylbutanoyl)-6-apiosylglucose
Peak:m/z	Relative Intensity
124.9667282	36.15
130.9387817	0.78
142.8780212	8.25
160.8962097	1.06
201.1748962	0.26
203.3130188	0.27
214.9731293	0.50
233.0344543	36.50
247.1978149	0.42
251.1434937	47.31
257.2144775	0.19
265.3439941	0.27
277.1943970	1.50
293.0234375	100.00
295.1076660	1.66
307.3634033	0.20
331.0184326	0.20
333.0740051	22.37
335.3617554	0.28
339.2471924	8.42
351.0897827	21.44
351.7729797	0.09
353.0340271	0.35
359.1810913	0.16
377.2237854	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1075.53
Annotation	Tyrianthin 5
Peak:m/z	Relative Intensity
303.5621033	0.22
307.3285522	0.08
333.3830566	0.21
353.3356934	0.40
362.3369141	0.16
369.3053589	0.77
375.1463928	0.36
383.4673157	0.08
407.3256226	0.19
409.3934326	0.15
412.0711670	0.23
415.6274109	0.27
437.3469849	0.19
439.3058472	0.34
455.3445435	0.22
457.7065430	0.31
471.2774048	0.22
481.2547913	0.42
487.3550720	0.13
493.5074768	0.44
497.1818848	0.27
499.3388062	1.17
508.2235107	0.19
511.2484741	0.13
514.8928223	0.19
515.5641479	0.21
517.2730713	1.81
521.3441772	0.38
523.0146484	1.18
523.7365723	0.77
543.7009277	0.38
553.5598145	0.32
557.3416138	0.08
563.6665039	0.23
566.3963623	0.20
575.3558960	3.13
580.0581055	0.71
583.4484253	0.12
595.2827759	0.25
599.2833252	3.95
613.6462402	1.25
616.5203857	0.26
617.6049805	0.14
623.6212158	0.11
631.6197510	0.17
637.0803833	0.47
643.3541870	17.19
655.2985840	1.69
661.5187988	0.20
667.4127808	0.17
669.5124512	0.16
673.9133301	0.25
681.1890869	0.40
683.4882812	0.49
685.5740967	0.24
695.6466064	0.24
697.3293457	0.50
704.3591309	0.08
705.6961670	0.77
707.3917847	0.81
709.3973999	0.16
710.3115234	0.10
711.6250000	0.60
715.2990723	8.18
717.1467285	0.75
717.7623291	0.25
721.1016846	0.12
722.3198853	15.26
723.3381348	11.63
731.3963623	0.40
733.4084473	5.33
735.2800293	41.86
736.0994263	1.27
747.3674316	1.17
748.8480225	0.29
749.4862061	0.41
751.7257690	0.25
761.2097168	0.85
778.2244873	0.25
779.5103149	0.41
793.5472412	1.07
801.4470215	0.27
807.5667725	0.27
815.1296387	0.38
821.9958496	0.21
823.5460205	0.13
833.3032227	0.17
843.9898682	0.68
844.6940918	0.52
857.6087646	1.64
858.2122803	0.12
863.3861084	0.28
869.3581543	1.36
871.4415283	1.46
884.4989014	2.08
893.1745605	0.60
895.3696289	1.48
907.3258057	0.75
909.6020508	4.96
910.6480713	0.20
912.7750244	0.68
913.4824219	4.18
921.7857666	1.05
922.3958740	0.45
923.6180420	0.26
925.4133301	50.08
926.0998535	0.26
937.4349365	3.97
939.6492920	16.38
940.5212402	36.25
955.4694824	100.00
956.2838135	0.19
957.3029785	0.47
967.1228027	1.18
985.4665527	18.57
997.5069580	1.61
998.3742676	0.43
1027.0715330	0.09
1039.5736080	0.31
1043.2321780	0.84
1057.4248050	21.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.2817
Annotation	Serinocyclin B
Peak:m/z	Relative Intensity
192.8544922	0.08
251.1445618	0.04
259.1777039	0.14
265.0773621	0.08
267.7161255	0.04
274.4795532	0.04
277.3262329	0.27
291.0810852	0.05
319.1315918	0.06
329.3179932	0.36
335.1044922	0.22
337.1936035	0.03
353.3368530	0.55
355.1555786	0.01
355.8661499	0.06
359.9693604	0.05
372.1827393	0.07
377.4304810	0.04
379.1441650	0.04
397.1412354	0.05
400.8900146	0.06
411.3018188	0.02
413.3989258	0.11
423.1595459	0.05
431.1744385	0.11
481.0567627	0.23
485.4319458	0.13
487.3443604	0.13
499.3993530	0.43
509.2601318	0.11
511.2738647	0.16
512.4619751	0.54
515.1362305	0.85
528.2496948	0.10
529.4857788	0.27
538.7191162	0.05
547.2944946	100.00
548.5354614	0.25
561.1506958	0.03
562.7039185	0.05
566.8817749	0.12
571.5789185	0.14
589.2964478	56.60
590.2647095	0.10
592.9905396	0.10
594.1930542	0.03
595.0407715	0.03
599.2268677	0.09
603.1964722	0.06
604.9860229	0.04
611.1955566	0.08
622.0278320	0.20
629.3419800	13.10
631.1881104	1.10
641.5407104	0.08
645.1437378	0.44
647.3125610	0.64
655.3218384	0.05
657.3947144	0.03
673.1569214	1.33
673.9804077	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.3663
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0122528	0.08
201.0561066	0.36
207.1094208	0.11
209.1569214	0.05
210.1296692	0.08
211.0010986	0.85
217.1696014	0.22
219.1275024	0.31
220.9694061	0.23
223.0611572	0.66
227.1339417	0.34
229.3006439	0.03
230.0062256	0.05
233.1103363	0.07
234.8953552	0.23
235.9892120	0.13
237.0502777	0.45
238.1940918	0.22
239.0487213	1.49
240.9902649	0.63
246.9945526	0.33
248.9782715	0.97
250.1916809	0.06
250.8885803	0.03
251.9528198	0.13
253.0866394	0.43
255.3282623	0.11
256.7326660	0.12
258.9183350	0.34
262.1791992	0.04
265.1743469	1.33
267.0242920	54.83
268.1176147	0.18
269.2858276	0.15
272.7251587	0.03
275.2665405	0.12
276.9243469	0.18
278.9551697	0.34
282.9921875	0.13
284.2719727	0.31
285.1382446	0.03
287.0227051	0.36
290.2641602	0.06
291.1156311	0.16
292.8670654	0.20
295.0315247	0.70
295.9303894	0.27
297.1026611	0.40
306.5246582	0.19
307.3744812	0.38
308.1552429	0.17
313.3844604	0.04
321.3162231	0.05
323.1171265	0.09
325.0292969	0.14
327.4513550	0.15
328.3074951	0.15
329.1444092	0.26
331.1755066	0.10
335.1412964	0.03
337.2191772	0.13
345.1094360	0.02
346.1587524	0.27
347.2217407	7.41
348.3544922	0.24
349.3529053	0.15
355.1291504	0.14
362.5840454	0.15
364.1991577	1.31
365.2014160	7.49
367.0583496	0.21
371.2922974	0.19
378.8099976	0.04
380.9886475	0.11
383.0638428	100.00
384.1824951	2.76
385.2464600	0.22
387.2371216	0.04
388.2416382	0.05
390.8133545	0.06
392.9995728	0.16
393.6069336	0.03
401.3339233	0.08
412.3090210	0.04
413.8705444	0.02
423.1286011	0.04
425.2938843	0.11
431.3686523	0.04
438.3024292	0.14
440.3370361	0.02
448.8967285	0.09
450.2167969	0.21
452.3815308	0.05
457.2958374	0.07
460.3187256	0.08
461.2056274	0.17
464.2808838	0.15
465.1774292	0.69
466.7080078	0.12
467.6595459	0.03
470.4766235	0.06
478.0745850	3.32
479.1184082	6.31
480.2647095	0.14
489.4622803	0.08
492.2106323	0.07
493.3073730	0.35
494.6229858	0.28
495.4274902	0.06
503.0214233	0.09
507.2420654	0.12
510.3089600	0.15
511.3403931	0.07
518.4339600	0.05
519.3781738	0.13
526.3273315	0.03
528.7637329	0.34
529.9381104	0.33
531.2281494	0.15
534.3982544	0.06
535.2877808	0.20
538.0921021	0.19
539.1122437	0.03
540.8739014	0.05
541.6879272	0.09
544.2117920	0.05
546.2338257	0.19
546.9462280	0.13
551.5753174	0.03
552.5286255	0.13
553.8948975	0.05
555.3041992	0.05
558.0456543	0.52
559.1878662	3.09
560.2898560	0.03
569.0491333	0.13
570.4981079	0.17
575.5375366	0.10
576.9812622	6.85
577.6437378	0.54
579.5532837	0.12
581.1483765	0.07
587.0772705	0.06
589.7011108	0.11
592.2143555	0.05
594.0685425	3.95
595.0874023	13.73
596.0521851	0.15
597.3938599	0.10
605.7448730	0.04
607.4909058	0.17
611.4736328	0.29
612.1101685	0.08
613.1997681	0.17
616.3941650	0.03
617.4459229	0.10
618.1354980	0.21
621.1772461	0.12
623.2176514	0.28
624.4719849	0.02
635.3578491	0.02
638.9420776	0.34
639.5713501	0.26
643.2202148	0.08
649.2250366	0.23
649.8822021	0.09
651.5984497	0.06
652.7031860	0.35
657.2502441	1.44
659.3286133	0.11
661.5259399	0.11
666.9107056	0.07
675.1742554	4.00
683.1906738	0.25
693.0559692	11.39
693.8801880	0.11
700.7485352	0.09
710.6832275	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
179.0444183	0.06
203.2639771	0.13
221.1025391	3.60
232.9304199	0.30
235.0441284	0.10
250.3194885	0.15
250.9555359	0.57
263.2669067	0.40
268.8882446	0.21
276.9885254	0.10
280.9104614	1.56
305.218689	0.55
310.9832764	0.34
321.2526855	0.41
322.4642944	0.09
323.0883179	3.78
340.9914551	25.47
341.6783447	0.09
347.1031494	0.04
365.2676392	0.39
383.1287231	100.00
383.7511597	0.15
407.0615234	0.28
412.2752075	0.65
412.8860474	1.22
415.2851562	0.59
425.0753174	1.45
425.7807007	0.06
437.21875	0.14
442.9272461	13.27
443.59021	0.07
455.0133667	0.32
467.2099609	0.70
472.440918	0.17
485.1469727	28.98
485.7635498	0.11
503.0803223	4.15
504.4495239	0.22
545.2179565	1.32
647.2098999	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	796.4954
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1139526	0.14
231.2333221	0.41
233.9662781	0.22
235.4601135	0.59
246.7996368	0.16
249.3717651	0.12
254.4149780	0.20
256.2435303	0.19
258.0917358	0.17
259.0322571	0.11
261.1153870	0.15
263.0307617	0.06
264.1430359	0.11
267.0747070	0.58
267.9731140	0.34
269.2702637	0.43
271.2518921	0.66
275.9409790	0.06
278.2678223	0.43
281.3683472	0.16
282.5675354	0.38
283.5942993	0.08
285.1353760	0.42
287.3898926	0.49
288.1312256	0.07
289.2499084	0.86
290.3210144	0.53
295.0256348	0.35
301.4092407	0.21
305.1857910	0.42
307.2244263	0.22
311.4185181	0.16
312.1666565	0.07
313.4559021	5.22
315.5343018	0.15
327.3825378	0.66
330.3259888	0.19
331.3025208	0.18
334.1838379	1.79
337.3670044	0.28
338.3449097	0.18
340.3018188	0.13
341.2594299	0.06
342.1827393	0.30
345.1709900	0.94
349.2295532	0.33
351.2579956	0.20
352.1787415	1.08
356.3942871	0.24
363.2625732	1.25
371.5035400	0.26
372.1169739	0.08
374.0902405	1.13
381.2095337	0.14
384.0780029	0.29
390.4807739	0.40
394.1725464	0.21
399.3955078	0.33
405.9009399	0.24
408.3368530	0.09
409.4834595	0.36
421.1654663	0.16
423.0156250	0.08
424.3348389	0.38
427.4092407	0.09
428.3619385	0.06
429.4381714	0.10
435.0922241	0.12
437.9785767	0.15
439.6621704	0.14
441.3789062	0.08
444.9869995	0.17
446.3151245	0.23
450.1739502	0.31
453.5747070	1.79
454.1830444	0.19
455.5892334	0.17
461.3909302	0.06
465.2991943	0.08
467.4230347	9.42
474.8380737	0.39
477.5227661	0.12
479.9534302	0.12
481.5035400	0.10
483.5870972	0.06
485.5792236	0.18
486.3319092	0.70
491.6270142	0.24
493.5133667	0.54
495.1154785	0.27
497.0173340	0.33
497.6707153	1.09
504.1035767	0.38
505.4601440	1.01
507.4649658	10.77
508.5888062	0.33
509.6630859	0.18
519.1216431	0.42
521.4341431	0.34
522.4834595	0.80
523.4385986	1.80
524.7127075	0.15
527.4475708	0.25
529.4848633	0.12
531.6148071	0.47
532.9535522	0.11
533.9320679	0.17
537.2921753	0.41
539.3554077	16.70
540.1818237	0.06
541.1798706	0.18
543.4243774	2.69
544.5791626	0.31
545.5650024	0.10
549.3097534	0.24
551.2557373	0.19
552.9100952	0.32
554.5355835	0.21
557.2311401	1.18
558.6733398	0.27
561.3956909	4.11
565.4887695	0.55
571.6002808	0.13
573.2376099	0.54
573.9627075	0.49
575.5430908	1.00
576.4296875	0.78
578.2417603	0.15
579.4618530	1.60
583.5327148	1.56
585.6044312	3.31
586.5210571	0.54
587.8562622	0.22
590.4776611	9.96
591.6454468	0.15
593.6400757	0.16
594.5584106	0.08
598.5158691	0.20
600.9168091	0.75
601.5300293	5.31
603.3713989	1.04
605.5298462	0.05
606.5158081	0.09
608.2152100	5.42
610.3713989	0.11
615.0543823	0.17
616.3541870	1.60
619.4387817	11.08
620.4406128	1.88
621.0493774	0.46
621.8329468	0.26
623.3651733	0.50
624.6275024	0.43
626.1821899	0.38
628.4884644	0.42
630.4675903	65.98
634.4879761	0.12
635.3034668	0.15
637.4036255	11.99
638.2036743	0.54
640.7467041	0.24
642.5927124	0.64
644.0787964	0.11
644.8716431	0.36
646.5922241	1.93
648.2356567	35.24
649.0417480	0.29
652.7073364	0.22
653.6467896	0.18
655.3317261	4.64
656.7854614	0.20
657.8291626	0.23
660.1935425	0.97
662.3521118	44.64
663.0169678	0.22
664.6088257	0.13
666.4171143	2.55
668.7745361	0.80
672.6540527	0.69
676.2080688	0.20
680.3093262	70.03
681.3362427	0.74
684.1964722	2.05
685.5086060	0.68
686.4526978	0.35
691.9808960	0.29
694.6141968	0.22
696.5092163	0.06
697.6671143	0.11
698.4357300	1.24
699.6353760	0.31
702.2953491	2.54
703.5419922	0.49
706.5827637	1.73
708.5482178	25.06
710.2645264	0.61
714.2984009	0.08
716.5342407	1.19
717.3993530	0.10
720.4550171	0.48
722.4434204	0.06
723.6586914	1.93
724.5807495	3.60
726.3538818	8.80
731.4502563	0.13
732.5822754	0.09
735.3109131	0.18
741.9234619	0.55
742.5587769	11.03
743.4147339	0.33
744.3787231	5.29
747.2687988	0.53
750.3664551	0.08
752.0137939	0.27
758.2202759	0.32
760.2857056	49.30
761.2725220	0.56
762.2767944	3.27
778.2295532	100.00
779.0100708	0.18
780.6743164	0.23
782.2348633	0.04
787.5834351	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.1143
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
116.0834351	1.62
125.1062012	0.09
127.9837799	100.00
144.1372375	0.06
153.0057220	0.94
156.1472168	0.06
167.1136017	0.08
173.0581665	0.06
180.7385559	0.14
197.0425720	0.29
202.0075226	0.24
209.0466766	6.42
227.1182709	33.75
229.8371582	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3071
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
180.2109680	0.07
197.9803162	0.12
209.5229187	0.07
215.8544159	0.11
308.4011230	0.52
339.3405457	100.00
418.6865234	0.05
419.3248901	0.09
436.7990417	0.10
444.5327454	0.01
449.2402039	0.02
462.2377625	4.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1015
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
157.1458130	0.01
158.8642273	0.02
176.0393677	0.01
182.2613831	0.01
183.7692261	0.00
187.3970947	0.01
190.9344025	0.02
192.2785645	0.01
204.2326660	0.01
208.9911499	0.02
219.5412445	0.01
221.1799622	0.01
227.2201843	0.05
228.3062439	0.04
229.1029968	0.02
231.0889282	0.04
234.3373413	0.01
249.1968384	0.01
257.1824341	0.02
263.1343079	0.01
266.0097961	0.01
279.3131714	0.00
285.2748413	0.08
287.2042847	0.02
301.2000732	0.02
303.0619812	100.00
304.1337891	0.03
306.9786377	0.01
313.3067627	0.02
314.8576050	0.01
320.4088135	0.05
321.6022949	0.02
327.0870361	0.20
337.1895142	0.03
338.7269287	0.01
345.1746216	1.85
353.1285400	0.02
356.1138306	0.04
359.4470215	0.01
364.1275635	0.02
369.1092529	0.25
371.3372803	0.06
373.0217285	0.04
383.1352539	0.02
385.2172852	0.01
387.3594971	0.02
389.3541260	0.02
393.3522339	0.01
398.2689209	0.03
411.1580200	0.26
416.8791504	0.01
421.3316040	0.02
422.4118042	0.03
425.2752075	0.02
428.7083130	0.02
444.9170532	0.03
447.2353516	0.02
451.3063965	0.02
453.3441772	0.01
455.0253296	0.01
465.0366821	0.14
470.2919922	0.04
471.1719971	0.03
472.1582642	0.07
476.2747192	0.04
485.4229126	0.02
489.2383423	0.12
489.8900146	0.01
497.1228027	0.08
503.2666626	0.02
505.0686035	0.09
507.4273682	0.01
515.1685181	0.45
518.9674683	0.01
521.3369141	0.01
533.0975952	3.03
533.9734497	0.01
542.4237671	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	238.0704
Annotation	Methyl 2,3-dihydro-3,5-dihydroxy-2-oxo-3-indoleacetic acid
Peak:m/z	Relative Intensity
69.9931335	0.26
73.8073578	0.42
79.0394898	0.07
87.8695679	21.70
97.1231537	0.02
97.9951782	0.03
104.9587708	4.37
115.9378815	8.05
123.0420227	6.30
126.0055084	0.03
127.8843079	0.07
131.7576904	0.07
136.0399017	0.04
147.9316101	0.03
160.0791168	0.07
160.9811554	0.02
164.0847473	0.06
167.0224304	0.05
170.0575256	0.06
175.1761017	0.01
178.1494446	0.09
180.2065277	0.06
192.0219574	2.33
193.1054230	0.20
193.9925995	0.26
196.1903534	0.23
196.9664764	0.14
202.1673737	0.08
202.9292145	0.15
207.0811157	0.37
210.1966553	0.07
211.4143524	0.02
220.0026703	100.00
220.9685364	0.06
222.0893097	0.06
229.1369629	0.29
239.2517700	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.0596
Annotation	8-Hydroxydaidzein
Peak:m/z	Relative Intensity
92.7920532	1.24
104.9925079	0.81
106.8483429	0.14
108.9248047	0.26
114.8881073	0.69
118.0002289	0.25
120.9322662	12.74
122.0275574	0.40
123.0115967	0.39
126.9370728	1.26
129.6926117	0.36
131.1326904	0.52
132.9222870	1.16
140.0905151	0.29
141.1121216	2.72
142.1564178	0.59
145.0160370	8.92
146.1608582	0.24
147.0830231	2.95
147.9080963	0.52
148.9876862	5.80
150.1019897	1.11
151.0890961	0.21
151.9348907	1.16
153.0893555	1.26
155.0444336	0.59
156.9919128	0.75
158.1361084	0.70
159.0927582	1.71
159.9122467	1.06
161.1284027	0.17
164.9709473	0.56
169.1051483	5.88
170.2267456	0.99
173.0625610	17.00
173.7965851	1.46
176.8353729	0.35
181.0186005	0.80
183.0909271	2.26
183.8853607	0.27
185.2019348	0.71
187.0374908	5.84
187.9650116	0.26
189.3812714	0.59
196.3706512	0.66
197.1290436	17.47
198.0896759	5.46
199.0765076	0.32
199.7896576	0.94
201.1286621	0.88
203.1503448	0.60
207.2076111	0.63
215.0367279	15.91
216.0711823	4.71
217.1581726	0.66
223.0930176	0.20
225.0797272	16.47
226.0872650	3.98
229.1999664	2.55
229.9552155	0.52
235.2915497	0.46
242.0222778	0.83
243.1078644	12.78
244.0638885	4.24
249.7102509	0.33
253.0401764	21.95
254.1594696	2.48
269.8643799	0.50
271.1316528	100.00
272.2384033	4.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.0991
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1862946	0.03
182.0413513	0.03
183.9843750	0.39
186.9159393	0.07
188.9216919	0.06
193.0902100	0.03
198.0902405	0.08
200.1479492	0.26
202.2117615	0.03
204.0087280	0.06
208.7569275	0.17
211.9253235	0.02
214.9653778	0.44
215.9631042	1.03
216.8923340	0.09
221.8944397	0.02
228.1306152	0.02
229.0761871	0.32
229.9923096	0.71
241.9360046	0.19
255.1042175	0.20
266.1766968	0.06
267.0437012	0.14
267.8694153	0.03
268.9277954	0.02
272.0975342	0.95
278.2290955	0.03
280.0906067	0.04
281.1947327	0.14
282.9174805	0.11
283.7922668	0.05
285.1110535	0.34
286.2755737	0.23
287.0383911	0.13
293.1921997	0.05
304.2302246	0.06
309.4505920	0.18
310.0729980	0.39
311.1582642	0.48
312.1760254	0.15
313.1503906	0.07
316.0870972	1.93
317.1076660	0.11
329.2445068	0.54
331.0612183	100.00
332.1997681	0.43
336.3427734	0.05
337.3256836	0.08
343.1024170	0.10
350.0842285	0.16
350.9680176	0.02
360.2160034	0.04
372.2905273	0.12
373.1548462	0.36
394.3097534	0.07
397.8251953	0.05
403.3683472	0.03
414.2102661	0.04
415.2420654	0.10
416.3128662	0.12
419.3026733	0.05
423.9515381	0.02
435.9801025	0.37
442.0088501	0.37
447.2486572	0.15
459.1216431	0.43
460.0300903	1.83
460.9471436	0.05
462.1120605	0.18
478.8905640	0.12
480.1505127	0.59
485.7622681	0.30
486.4850464	0.03
488.8926392	0.06
500.8134155	0.03
520.2899780	0.03
545.3758545	0.13
547.0507202	0.35
554.8688965	0.02
563.2828979	0.03
564.7739868	0.25
573.0844727	0.47
591.0488892	9.96
591.6685181	0.03
593.8800659	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	484.1734
Annotation	Unknow
Peak:m/z	Relative Intensity
139.0144043	0.93
158.0384979	1.37
159.1042633	0.05
162.9775543	17.68
164.9094391	0.08
166.9556274	4.45
172.9041138	0.04
174.9985352	0.28
175.9924469	1.27
180.0012665	0.49
183.9583588	0.24
192.9874115	18.13
199.1472778	0.09
216.0863342	0.19
224.0898132	0.11
227.1889038	0.07
233.1461029	0.83
237.8985901	0.08
247.0025635	0.17
259.1659241	0.19
261.3649597	0.11
264.3020325	0.06
284.1386414	0.05
286.2968140	0.07
304.6169434	4.75
305.7270508	0.26
307.3527832	0.04
309.2353516	0.09
322.0679932	100.00
322.7131042	0.33
353.4356384	0.08
354.4642944	1.93
355.0908813	12.40
373.3578491	0.07
380.5743103	0.23
382.7338562	0.05
394.0191650	0.83
395.0451965	1.65
397.3431091	0.16
398.1696167	0.16
409.0877380	0.08
425.4396667	0.11
440.1112366	0.03
442.7035217	0.22
448.9249573	0.19
466.1957397	2.48
467.0614929	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1251.6
Annotation	Spumigin B1
Peak:m/z	Relative Intensity
437.0205688	1.70
481.2772827	3.29
499.3283081	4.12
553.4595947	0.35
569.4692383	0.55
571.1949463	4.62
589.4512939	6.06
595.3629150	2.34
621.2136841	0.64
629.4617310	0.80
653.2172852	1.63
657.1239014	1.31
667.2445068	2.36
703.4321289	3.93
722.4815674	0.63
733.4467163	10.10
745.4860840	1.68
749.5357666	2.25
751.4605713	24.02
819.4924316	46.80
820.4841919	4.30
833.5319824	7.32
847.2922363	4.95
849.2280273	0.70
865.4088135	26.64
866.2285156	1.23
883.3948975	3.41
891.2523193	94.06
892.5444336	1.30
909.4167480	100.00
921.6614990	0.56
927.3934326	18.12
943.7515869	3.24
955.5838623	0.61
961.6064453	4.14
991.3225098	1.17
1009.4337160	4.99
1027.4467770	90.35
1028.0955810	0.60
1045.5688480	17.68
1071.3131100	9.07
1089.4530030	52.23
1090.2464600	2.67
1131.4023440	0.54
1173.5600590	1.40
1189.4202880	89.59
1190.5229490	2.88
1207.4472660	3.55
1233.4047850	70.25
1234.0180660	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.26
Annotation	Unknow
Peak:m/z	Relative Intensity
157.1111755	0.06
160.9613037	0.25
163.0305023	0.19
165.0727081	0.09
167.0755005	0.20
171.1281128	0.07
175.1131592	1.24
181.1495667	0.34
191.0458069	0.05
201.1943359	0.07
209.1683044	0.42
215.2416534	0.45
220.4387207	0.05
225.0771637	1.23
233.3856049	0.12
235.9606018	0.05
238.2001801	0.08
245.0710449	0.09
253.4366760	0.04
259.1362000	0.17
263.0733643	0.05
267.4491577	0.03
271.1236572	0.32
273.1219177	0.32
279.1160889	0.46
293.0377808	1.07
297.1717224	0.33
301.1687012	0.04
307.2012939	0.25
311.0255737	0.12
325.2154541	0.03
327.0574951	0.66
341.1177979	0.35
345.0645752	0.09
353.3385010	0.27
363.4206543	0.03
369.0133057	0.42
370.1754761	0.06
373.1840820	1.07
382.8630371	0.10
386.0426025	0.34
387.2518311	4.48
404.5333252	0.13
409.3399658	0.17
412.9725952	0.28
421.8599854	0.28
429.2052612	0.32
431.1554565	0.80
443.0522461	0.18
445.1425781	0.05
449.9578247	0.14
451.1875610	0.05
463.0411377	0.15
469.3319702	0.76
487.5123901	0.23
489.1978760	2.54
491.3950806	0.06
501.2241821	0.18
503.1613770	8.81
505.1629639	100.00
512.7780151	0.16
513.3878174	0.30
531.2917480	1.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1249
Annotation	Limocitrol 3-glucoside
Peak:m/z	Relative Intensity
160.9501038	0.26
208.3955536	0.04
289.1365967	3.70
297.2309570	0.01
313.3012695	0.01
340.3895264	0.14
341.1408081	1.57
355.3061523	0.02
357.1419678	0.29
374.7893066	0.11
375.3985596	0.12
386.2916870	0.03
390.2806396	0.06
408.3161621	0.05
422.4983521	0.08
433.4177246	0.06
447.1856689	0.03
451.1542358	1.08
493.1318970	100.00
493.7542725	0.20
495.2213745	0.02
501.4671021	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.939
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9563522	0.03
159.0205078	0.40
159.9650879	0.17
160.9133453	0.49
199.2234039	0.03
217.0525208	0.02
229.1301575	0.03
230.9447327	0.25
242.2040100	0.02
268.7912292	0.04
272.9869995	48.18
274.0069580	16.39
274.9468689	100.00
278.9580994	0.05
288.1297302	0.02
300.7047729	0.03
303.9548340	0.03
315.0632629	0.11
322.0022278	0.02
342.0542908	0.06
342.8540039	0.46
344.7508850	0.17
345.5228882	0.04
346.7496338	0.10
367.1494751	0.11
369.0160522	0.07
371.1839905	0.29
388.7725525	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	789.1428
Annotation	Unknow
Peak:m/z	Relative Intensity
418.8297119	0.02
486.7334595	0.08
581.1163330	0.02
607.1434937	0.03
621.0636597	0.02
658.6973267	0.03
705.2430420	30.59
705.8441772	0.16
710.1801758	0.05
743.2451782	100.00
766.2489014	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.13
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
127.0074921	1.39
163.0103912	0.03
168.8826752	0.01
271.0866089	100.00
272.1288452	0.01
289.1460266	0.09
307.2382507	0.13
415.1520386	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1247
Annotation	Limocitrin 7-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
162.9158936	0.03
189.0052643	0.01
191.1325989	0.04
198.3983917	0.15
199.1272125	0.02
203.1410065	0.02
243.1829681	0.23
249.1705780	0.07
255.2144775	0.14
267.3598022	0.02
279.1386108	0.06
285.3953247	0.19
297.2363892	0.03
299.3833313	0.02
301.1892700	0.51
303.1136475	0.03
315.4215088	0.01
319.3940430	0.02
341.2716675	0.06
343.4942627	0.02
345.3155518	0.13
346.7103271	0.01
367.3921509	0.03
369.2298584	0.06
402.1291504	0.02
403.1748657	0.17
405.4215698	0.07
407.5740356	0.05
409.1026001	0.01
463.1954956	0.12
474.3294678	0.03
481.2569580	0.10
486.9953003	0.05
488.9491577	0.28
489.5966187	0.01
503.3911743	0.08
505.1970825	100.00
506.3433838	0.09
508.8710327	0.08
511.6009521	0.04
513.3739624	0.92
530.2857666	0.17
531.3316650	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1032
Annotation	Zidovudine
Peak:m/z	Relative Intensity
93.8731079	0.02
118.9085846	0.06
120.0488892	0.08
120.9667664	0.39
122.0656586	0.27
135.9472351	100.00
136.9915771	0.12
137.9618988	0.48
138.9885101	0.34
232.4769287	0.02
250.0942383	0.04
251.0435028	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.44
Annotation	3-O-(2-O-(2E-decenoyl)-alpha-L-rhamnopyranosyl)-3-hydroxydecanoic acid
Peak:m/z	Relative Intensity
194.9739380	0.01
197.0282135	0.01
211.1809082	0.01
235.3115845	0.02
239.6477203	0.03
241.2865448	0.13
255.6095886	0.01
267.1682129	0.02
269.3365784	0.09
271.3537903	1.39
273.3617554	0.04
291.4687195	0.04
299.2577820	1.95
309.2290039	0.02
311.3121338	0.01
315.4122620	0.01
317.2324829	100.00
318.1140747	0.00
327.2334900	2.46
327.8508911	0.03
337.1586914	0.72
355.3381958	0.03
359.2611694	0.02
366.2102051	0.01
368.9539185	0.02
387.4225464	0.01
417.3016357	0.01
452.4943237	0.01
475.1383667	0.01
476.9861450	0.01
495.4199829	0.01
509.3220215	0.02
517.2581177	0.01
539.2906494	0.01
549.4843140	0.02
551.7404785	0.02
561.4055786	0.01
592.6360474	0.03
593.5089722	0.01
597.2419434	0.01
609.3922729	0.02
611.6187744	0.02
619.5093384	0.03
633.2976074	0.01
636.6807861	0.03
637.4450073	0.06
655.3521118	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3306
Annotation	Unknow
Peak:m/z	Relative Intensity
242.1321259	0.04
277.4674683	0.02
279.3328247	2.26
355.3903809	0.01
392.6438599	0.02
459.2843018	0.15
463.3078613	0.05
479.3868408	0.11
504.2902222	100.00
505.4022217	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.2668
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
150.8643799	0.34
153.2899475	0.18
153.9947052	0.21
169.1674500	0.06
179.2292023	0.36
197.1779022	1.65
216.9279480	0.18
223.1160278	1.54
241.1635437	10.11
259.1401672	100.00
287.1556396	0.23
315.1248779	0.21
321.0355225	0.08
357.2872314	0.12
500.3891602	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.8090210	0.02
153.0238800	0.11
196.0821686	1.93
214.0716400	1.38
237.4072266	0.09
255.2103882	100.00
255.9264832	0.27
391.2121887	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2782
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.3731079	0.04
140.0538025	0.10
153.0364838	0.11
165.8715973	0.06
196.1751099	1.36
205.1183777	0.03
214.0845032	1.00
261.2366638	0.20
279.2270813	100.00
279.8610840	0.17
343.2405090	0.05
362.1411743	0.04
415.1322327	0.19
430.5102234	0.03
458.6496277	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1282.11
Annotation	Unknow
Peak:m/z	Relative Intensity
437.5378418	1.30
439.4759827	1.37
452.0483093	3.31
457.1232910	0.34
481.1280823	1.01
567.6563110	2.53
572.5059814	0.85
601.6107788	2.83
619.2037354	6.33
621.2048340	0.34
685.4085083	1.00
687.3723755	6.67
688.3504639	3.54
715.6080322	5.75
733.3619385	4.34
734.3370361	0.71
763.5262451	19.74
764.3974609	6.74
777.7286377	3.00
781.4386597	13.72
782.1855469	1.34
782.7896118	1.01
837.5499268	1.34
849.3752441	45.62
850.4334717	6.72
863.5028076	3.61
864.8027344	2.54
877.4737549	4.92
893.4298096	2.34
895.5415039	35.88
896.6072998	3.26
903.2792969	1.87
913.1560059	12.15
913.8955078	3.66
921.2891846	59.96
922.3789062	25.73
939.4235840	100.00
940.4202881	25.48
957.4251709	10.93
958.4703369	2.18
985.6729736	2.11
1030.1187740	0.34
1039.3031010	8.24
1040.2271730	0.67
1057.4689940	56.85
1058.4599610	23.10
1075.4079590	11.62
1076.5976560	1.69
1092.3112790	1.67
1101.4545900	9.09
1102.7009280	0.55
1119.5772710	39.58
1120.5063480	13.01
1147.3209230	0.63
1201.4776610	0.73
1219.4401860	67.90
1220.5280760	32.00
1263.3730470	48.78
1264.1867680	16.34
1264.8392330	5.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.2104
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
104.9893799	0.06
107.1744385	0.08
109.0764618	0.37
111.0124359	0.05
115.0201950	0.03
116.3896332	0.03
119.1252213	0.08
120.9202042	0.11
122.6126633	0.01
125.1532440	0.06
129.1607666	0.06
131.0472412	0.19
133.0758362	2.57
134.9640350	0.03
137.0242004	0.36
143.0679474	0.07
144.9282227	0.18
147.0166779	0.47
148.9753723	0.17
153.0037231	0.44
155.1368866	0.03
157.2675781	0.06
159.0936279	0.19
163.0353699	0.16
164.8680267	0.12
167.0010529	0.36
168.8162231	0.03
171.0762634	0.10
172.9389343	0.07
175.0180664	0.18
176.9413147	0.03
181.1773071	0.08
182.7528687	0.18
185.1037903	0.13
189.0076752	0.03
190.9890747	0.13
193.0059204	0.17
195.1393738	1.93
197.2053375	0.05
199.1354980	0.29
201.0044708	0.07
203.1702881	0.26
205.1952820	0.05
209.1605530	0.08
211.2523956	0.08
217.1582031	0.07
219.0094910	0.02
223.1102295	0.51
225.1422119	0.13
227.1233826	0.56
229.2659912	0.25
231.2505188	0.04
235.1820984	0.06
237.1635742	0.17
239.1303406	1.19
241.1602173	1.01
243.1409302	0.28
245.1585083	1.46
247.3709717	0.16
249.1657410	1.00
251.1479187	0.05
255.0419312	0.08
257.1230164	1.04
259.1027222	0.25
261.2178040	3.65
263.2279663	3.78
267.1165771	13.12
267.7168274	0.10
269.3538818	0.23
270.8579712	0.09
273.2761841	0.40
275.1152344	0.72
277.4190674	0.07
283.2960205	0.18
285.2102966	13.91
287.2272949	1.28
289.1882324	0.19
291.1466064	0.02
293.4209290	0.06
295.1580200	2.30
298.7703857	0.08
301.1254578	2.51
301.7691040	0.03
303.2169800	3.84
305.2967224	1.01
309.3291626	0.04
310.4460754	0.24
311.0981445	0.05
313.1202393	26.83
313.7556458	0.06
319.2387695	0.62
321.1683960	2.32
322.0684204	0.03
322.7803345	0.02
323.4202881	0.17
325.0385132	0.12
326.0923462	0.03
328.9334106	0.02
331.1940918	26.60
337.2560730	0.07
343.6479187	0.08
345.0564575	0.03
349.2210083	100.00
350.2286072	0.03
357.5870361	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1436
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
83.8601837	0.44
85.9888611	22.84
129.9000092	1.41
131.9662781	100.00
132.7590790	0.03
147.9851837	0.48
198.0290070	5.12
215.0533905	1.23
225.2262573	0.47
243.0947266	5.44
244.0949554	25.85
244.7177582	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	798.317
Annotation	Unknow
Peak:m/z	Relative Intensity
229.1002502	0.28
241.0915375	0.23
253.0282898	0.05
271.0117493	2.94
276.2336426	0.39
288.9473572	3.31
293.9198608	0.33
297.9548340	0.47
305.8668518	0.77
306.9261475	4.15
322.8598328	0.34
324.1744385	4.78
325.0293884	62.85
334.9614258	0.09
336.1098022	0.20
341.7555847	0.61
342.9218750	11.52
384.8907471	0.14
403.0853271	0.10
404.2484131	0.23
433.2032471	0.29
449.9365234	0.41
451.0104980	1.91
468.9274292	0.43
474.0870361	0.13
485.0683594	0.73
486.8237305	100.00
487.6209717	0.28
489.1529541	0.08
503.3111572	0.82
504.1736450	1.83
504.7816162	32.15
505.4270630	0.29
507.1462402	0.09
522.0728149	0.17
618.2892456	0.69
628.3627319	0.11
634.0419312	0.38
635.2568359	1.44
636.1754150	24.50
644.2491455	0.13
669.1773071	0.07
707.2597046	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	335.2208
Annotation	8-iso Prostaglandin A2
Peak:m/z	Relative Intensity
108.9983673	0.04
121.0282516	0.02
130.931839	0.01
132.9167786	0.02
145.2346191	0.01
156.9886627	0.02
162.9280548	0.04
167.0471191	0.03
168.9906311	0.02
171.0088196	0.06
178.3669281	0.02
179.365509	0.03
191.2005005	0.03
192.1627502	0.09
193.1591492	0.05
195.2357483	0.20
201.0081177	0.01
204.0331116	0.01
211.1144714	0.07
215.3427124	0.06
227.9522095	0.02
231.541626	0.02
237.1005249	0.04
241.725647	0.03
243.320282	0.33
246.158905	0.04
249.8443604	0.03
253.2857056	0.55
255.3422852	0.03
257.1932678	0.19
260.2537842	0.01
261.0717773	0.09
263.6134338	0.01
264.3778381	0.04
265.1381226	0.02
271.2444763	24.58
275.2929077	0.18
277.2105713	0.03
279.104248	0.04
281.2096558	0.63
282.0079041	0.06
289.0175171	12.27
293.3288269	0.07
297.1748047	0.03
299.203064	100.00
305.2840576	0.04
307.091095	0.04
308.2492065	0.03
310.7227478	0.03
314.833374	0.17
316.4986572	5.28
317.1361084	9.35
318.307373	0.17
320.2542419	0.04
325.7986145	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.3752
Annotation	Janthitrem G
Peak:m/z	Relative Intensity
186.6871948	0.13
195.0127106	0.06
196.1078644	0.03
204.8481140	0.02
209.1976318	0.08
211.3847198	0.04
218.0826569	0.04
220.1449432	0.11
227.2307739	0.07
228.9669800	0.20
247.4329529	0.10
261.0981445	0.08
265.3554077	0.05
274.9184265	0.09
278.2239380	0.14
291.5726624	0.07
295.2206726	0.11
309.3317871	0.08
312.4915161	0.02
315.3248291	0.02
317.3985291	0.17
318.1693115	0.13
323.2640076	0.06
327.1933594	0.06
334.1803589	1.17
335.3369141	0.07
336.3435669	0.03
337.0876465	0.06
343.5584106	0.08
350.2264404	0.03
352.2219849	0.53
353.1203003	0.13
370.1728516	0.04
374.5460205	0.24
375.2502441	0.07
379.6550293	0.23
380.5106201	0.04
383.1962891	0.07
392.6080933	0.17
402.3419189	0.06
404.3587036	0.07
412.2863159	0.01
421.4107056	0.02
428.4472046	0.04
440.4482422	0.04
444.5114746	0.11
445.7995605	0.06
458.0620728	0.08
471.4821167	0.05
474.0227661	0.03
475.9216919	0.01
483.0098267	0.03
487.3668213	0.04
489.4545898	41.65
490.5335083	0.05
496.4490356	0.01
503.8323364	0.10
520.5089111	0.09
532.6595459	0.08
546.1898193	0.02
551.4297485	0.04
558.5817261	0.05
562.6598511	0.07
563.2960205	0.11
566.0427246	0.05
569.4572144	0.42
570.3726807	0.06
573.8410034	0.16
574.4539185	0.03
580.8337402	0.10
586.7781372	0.02
587.4669800	0.04
594.1209106	0.10
595.5169067	0.02
612.3708496	100.00
613.5791626	0.14
636.1077271	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	941.4747
Annotation	Cynarasaponin D
Peak:m/z	Relative Intensity
277.3328552	0.09
300.0633240	0.06
443.3905640	0.11
451.0554810	0.10
458.5431519	0.12
468.2940674	0.05
482.4721680	0.51
500.1604004	0.15
502.7310791	0.12
512.3199463	0.20
521.3157959	0.04
524.2798462	0.06
526.1326294	0.12
528.3911743	0.08
584.2804565	0.27
585.4777222	0.09
586.4039307	1.21
603.6009521	1.41
604.4191284	3.77
617.0491943	0.29
621.2866821	0.04
636.5025024	0.23
673.0971069	0.18
686.4312134	0.11
704.6608276	0.14
716.1268311	0.08
729.2655029	0.18
734.7046509	0.09
748.4891968	0.14
762.4328003	0.42
763.6699829	0.17
765.6399536	23.96
766.4783325	100.00
767.3927612	1.60
784.9578247	0.12
791.4766235	0.26
799.4708862	0.12
819.9732056	0.37
854.3163452	0.14
862.5599365	0.14
865.4276733	0.21
879.8928223	0.07
880.5464478	0.45
881.5377808	0.15
894.2701416	0.09
898.3930054	0.18
912.6129150	0.07
914.5922241	0.10
924.5568848	0.62
943.3013306	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.1583
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
160.9727173	0.26
165.1406403	0.10
169.3709717	0.50
171.1677856	0.15
178.9445801	1.28
181.1368561	1.26
185.1306915	1.12
186.9680176	0.19
189.1470184	0.33
207.1657410	0.09
209.2236481	0.23
213.0714417	1.71
215.1072235	1.17
217.2084198	0.09
219.1993103	0.19
225.2437744	0.10
227.1137085	0.86
229.1783295	0.51
231.0462494	24.09
241.1977234	0.44
243.0532532	5.68
244.1399536	0.06
245.1311646	1.08
246.9967041	0.44
253.1292419	0.25
255.0226898	4.28
256.9844971	2.00
259.1010437	0.95
263.0332031	0.06
267.1484070	1.32
269.1992493	0.27
271.1970215	0.17
272.9832153	21.10
273.5925903	0.13
275.0579224	93.91
279.3455200	0.19
283.2535400	0.07
285.0786133	24.34
285.7731323	0.16
287.1676025	17.80
290.9136658	0.10
297.8876038	0.16
299.0880737	2.84
300.1082153	0.22
300.9763184	0.76
304.3479614	0.11
315.1032104	0.45
317.1793213	1.33
339.2460938	0.04
343.7285767	0.14
345.3815308	0.10
355.2077637	0.19
355.8260498	0.20
357.5113525	0.79
367.0419312	0.31
373.0367432	0.34
379.1854248	14.64
381.0650024	0.35
382.1052856	0.17
383.4522705	0.27
385.0924072	1.21
387.7498169	0.42
391.2971191	0.79
393.2142334	90.69
395.3118896	0.32
399.1636963	1.23
399.9202881	0.27
400.5423584	0.45
401.1462402	0.31
403.1103516	1.36
405.2220459	0.27
406.3224487	0.35
407.0321045	0.14
409.2986450	0.34
411.1842041	100.00
418.4314575	0.64
421.0874023	12.88
423.2197876	0.52
434.6079102	0.35
439.2459106	0.11
458.6027222	0.52
471.2833252	0.41
483.2546997	0.43
484.3646851	0.29
486.3792114	0.27
487.2765503	0.28
492.4791260	0.38
493.2610474	0.52
510.9611206	0.14
511.8067627	0.11
519.0918579	0.32
520.2283325	0.08
522.9971924	0.51
529.1168823	7.62
530.0761719	0.24
531.6669922	0.79
537.9640503	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1766
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
142.9793549	0.20
144.9596710	0.06
147.1072998	0.29
148.9607544	0.11
160.8193359	0.33
163.1671753	7.72
164.0685272	0.23
165.9804230	0.23
167.0208740	0.25
178.9843140	0.11
189.1639862	0.11
202.7792358	0.13
205.0565796	0.88
207.1436462	13.40
209.0835419	0.05
217.1771698	0.35
220.9904480	0.18
223.1373291	0.57
225.0860443	1.99
231.0894012	0.14
239.0773010	0.04
287.5461426	0.45
303.1628723	0.38
308.4044189	0.07
321.0684814	0.15
323.2275696	0.06
327.0513611	0.14
329.3778381	0.05
343.2879333	0.26
361.0665894	0.17
369.2270508	57.58
370.2998962	0.16
383.1181335	0.39
385.6357117	0.26
387.2267761	100.00
388.3719482	0.08
397.1766968	0.10
411.2767639	2.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2028
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
242.3461914	0.55
243.2039642	1.13
245.1326294	2.30
247.1937408	0.29
255.2936096	0.82
255.9658661	0.24
257.1088867	0.34
261.8941650	0.11
269.0647888	2.34
271.1907043	2.55
273.2041626	1.07
274.9807129	0.43
281.0506592	0.53
283.2146301	0.58
284.3254700	0.10
285.4783020	0.84
287.1598816	18.14
289.1026917	17.66
290.1192932	0.14
291.2245789	0.42
295.2149048	0.21
297.2716064	0.38
299.1030273	4.76
301.3250427	0.49
311.1580811	0.64
319.4236450	0.87
323.1213379	0.34
325.3409729	0.43
326.9031982	0.33
329.1710205	0.35
335.2490540	0.16
337.1169434	0.57
339.2149658	0.47
341.2022095	0.88
342.0914001	0.14
349.1880493	1.51
350.9381104	0.30
353.1822510	0.25
355.1537476	1.28
359.0917969	0.26
363.3285522	0.90
367.0808105	1.63
379.1219788	5.21
381.0374756	4.45
383.2590332	3.53
385.2027588	0.29
387.4222107	0.29
389.1859741	0.92
391.1667480	0.97
392.3733521	0.17
393.2715454	0.75
397.1971436	10.33
403.4554443	0.59
405.0438843	1.81
407.1947632	45.61
408.3829956	0.60
409.3436890	2.55
411.2760010	0.55
413.3138428	0.33
419.1390381	3.65
419.7633057	0.24
421.2097778	0.82
423.2587891	2.62
425.2085571	43.16
429.6340942	0.44
433.2107544	7.51
435.1370850	2.62
437.2069702	3.61
438.9130859	0.46
440.2553711	1.06
446.3027954	0.59
448.0398560	0.37
449.1428833	3.89
451.2337036	19.65
453.4008789	0.45
455.1310425	0.50
467.0154419	0.97
473.2763672	1.34
475.3592529	0.34
481.1145020	0.71
483.0692139	0.38
489.4210815	0.13
491.3509521	0.87
493.2697144	6.23
499.3029785	1.62
505.3586426	0.17
507.1513062	0.12
509.3242188	0.71
511.3117065	30.05
512.5797119	1.41
513.3352051	0.48
517.2244873	5.43
519.2102051	0.65
523.2253418	1.53
527.0874634	3.71
535.0939331	6.13
541.1625977	2.78
543.3034058	5.88
545.0297852	2.14
545.6860962	0.80
551.3958740	0.28
553.1475830	10.71
557.4388428	0.83
559.2044067	76.26
561.2685547	7.15
569.1853638	0.93
571.2023315	23.26
572.1087036	0.43
573.3135376	0.31
575.2026978	0.31
576.0209961	1.65
577.1771851	94.95
581.3717041	1.63
586.5884399	0.93
587.2044678	0.53
589.0859985	2.48
595.4943848	0.39
597.1959839	0.95
600.1579590	2.00
601.1066895	0.66
607.5140991	3.64
609.3793945	0.66
610.9901733	0.24
613.0485229	1.38
616.1946411	1.32
617.0883179	0.13
624.7233276	0.53
625.3628540	7.40
626.2902222	0.79
627.9151001	0.63
635.4780273	0.79
636.1355591	0.20
643.7427368	0.49
648.8916626	0.10
651.4876099	1.08
653.1557007	1.84
661.0362549	1.25
663.3103638	0.15
665.2794189	0.17
667.5416260	0.38
668.1729736	0.74
669.3966064	5.92
670.2867432	0.45
673.3115234	0.53
677.0408325	0.30
679.1310425	16.25
681.3962402	0.19
687.2666626	38.86
688.0961914	0.19
691.5773315	0.18
693.0201416	0.47
695.2686157	10.84
696.5271606	5.89
697.2150269	39.50
699.2066650	0.58
703.5804443	0.93
705.1452026	2.39
708.9595337	1.02
711.0850830	1.76
711.8340454	0.60
713.2858887	5.70
723.0181885	46.91
723.7678223	0.26
727.8020020	0.18
731.1788940	4.04
738.8164673	0.24
743.7743530	0.11
761.0292358	0.28
764.3619995	0.66
769.4019165	1.24
771.6049805	0.30
781.0918579	0.18
787.1192017	1.25
789.2943726	2.24
795.1608276	1.61
805.0824585	2.75
807.2415161	0.25
813.3650513	1.31
817.3275757	0.72
831.2823486	100.00
832.4614868	3.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1817
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
100.9121094	0.21
110.9404526	0.40
112.9948959	2.78
118.9794540	2.44
123.2091827	0.74
129.0801086	1.48
130.8822937	0.52
141.1988983	0.47
142.9304199	1.88
147.0632629	3.86
148.8489075	0.09
159.0616302	1.20
161.0018616	3.20
167.1508179	0.37
169.2351379	0.63
173.1942139	0.49
179.0368347	1.09
190.9863281	0.64
193.0885010	0.43
195.0493164	0.13
209.1531982	53.34
210.0065613	0.36
211.2479706	2.01
223.1953430	0.34
227.1611938	14.65
228.1755981	0.44
237.3973083	0.17
239.2402344	0.29
241.1008606	0.56
259.1672668	0.48
266.8564148	0.55
269.3040161	0.64
275.2809448	0.56
281.2685852	2.53
289.2857056	1.72
311.0473938	2.22
327.2731934	0.33
329.1267090	6.41
330.1843872	0.62
341.2017212	1.25
345.0328369	0.85
353.1521606	1.74
369.3884583	0.30
371.2997742	100.00
372.3402405	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	648.2993
Annotation	Unknow
Peak:m/z	Relative Intensity
267.5282593	0.05
286.3841248	0.05
320.3265991	0.03
321.2075195	0.12
322.1310425	0.09
455.4495850	0.02
468.3578491	0.07
473.5343628	0.02
567.5919189	0.10
589.6578979	0.01
616.5191040	0.06
625.3058472	100.00
625.9092407	4.26
626.8368530	0.32
628.0858765	0.10
629.0101929	0.12
630.2482300	0.02
631.1960449	0.02
632.0751953	0.03
637.9297485	0.06
729.4169922	0.07
747.2058105	0.07
779.4224243	0.06
833.5267944	0.03
865.6088257	0.03
909.5075073	0.02
957.7229004	0.05
1011.7001950	0.07
1071.4010010	0.09
1089.4799800	1.45
1090.3371580	0.23
1121.5598140	0.02
1135.6564940	0.07
1251.4991460	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1297
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
125.0609360	0.08
132.8226318	0.39
134.8639679	0.09
137.0836182	39.75
149.0733185	0.32
151.0690155	0.52
159.2016296	0.19
160.9506989	62.45
165.1130981	0.04
179.0265198	0.37
191.0356140	5.00
203.0652466	1.85
208.9970703	0.10
214.1840210	0.09
221.1162109	2.53
227.1803741	5.44
229.3465271	0.06
239.0088806	0.37
240.2872009	0.06
245.2129822	0.09
247.3465576	0.05
251.0527039	1.18
252.9679260	0.09
254.3064880	0.08
262.9874268	0.21
273.1038513	9.98
275.1661072	0.11
281.0530090	1.19
283.0958252	0.09
288.2694397	0.07
289.1056519	1.12
296.9915771	0.28
298.9959106	100.00
313.3192444	0.05
314.1953735	0.81
315.3837280	0.26
329.2290649	0.46
340.7646179	0.08
344.0299377	0.06
345.3171387	0.04
366.8076477	0.19
370.9380798	0.06
387.9203796	0.30
389.1030273	5.65
390.1377869	0.46
397.3176575	0.08
403.5143738	0.10
417.2375488	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	571.2398
Annotation	TMC 2A
Peak:m/z	Relative Intensity
178.7935791	0.02
191.0084381	0.07
191.9117737	0.02
225.1971283	0.02
245.1803589	0.06
250.0776367	0.10
265.9667053	0.02
268.3074341	0.23
295.1647949	0.02
295.9490967	0.06
297.0480042	0.09
303.3152161	0.02
312.0831299	2.10
313.1071167	2.43
336.1516113	0.08
350.7424927	0.07
351.8811646	0.04
353.0303345	0.02
378.6738281	0.03
397.0987549	0.88
398.2344971	0.70
423.0164795	0.11
424.2066040	0.21
441.2308960	51.22
442.1196289	100.00
442.9460449	0.06
481.1469727	0.04
483.2045288	0.09
534.2229614	0.05
552.5889282	0.29
553.2649536	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.2473
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
96.8787689	0.03
105.0255508	0.07
112.9354248	0.25
121.0792236	0.13
124.8780823	0.02
127.1763306	0.17
128.7786865	0.03
133.0839386	0.09
137.0214539	0.07
140.7827606	0.10
146.9354553	0.13
150.9839783	0.06
152.9387207	0.17
159.0820007	0.09
163.1792297	0.07
164.9699707	0.05
169.3305054	0.19
172.8434143	0.06
174.8872528	0.05
177.0262604	0.12
185.2153778	0.10
187.0931702	0.15
189.1562195	0.12
190.5484161	0.06
195.0495605	0.14
197.2365112	0.06
198.9655304	0.02
200.7321777	0.06
204.9184570	0.04
211.0551147	0.07
212.9008789	0.87
215.0684814	0.04
216.9583130	0.08
218.4004822	0.17
223.3623047	0.06
225.0818787	0.03
227.1360168	0.03
236.3897095	0.06
237.4155579	0.32
241.1412964	1.09
243.2079468	1.29
247.2064514	0.05
251.1118164	0.07
252.8856812	0.64
254.8471375	1.33
259.2814636	0.56
260.0316162	0.09
272.2576904	0.55
273.2372437	0.23
277.2512817	3.51
281.1718140	0.10
282.5693359	0.11
285.1685791	0.60
289.3541260	0.04
295.1489868	40.10
296.0421143	0.13
299.0131836	0.11
303.4367065	0.05
304.0684814	0.02
313.1168823	100.00
313.9202576	0.47
329.8461609	0.71
341.4018860	0.13
344.1761475	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.2262
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
91.0256958	0.07
92.8883514	0.07
94.3161468	0.03
95.0362396	0.17
96.9825363	0.03
98.9478531	0.22
105.0529633	0.19
106.9396286	0.35
108.9798126	0.17
111.0217896	0.12
112.9315796	0.25
117.0705643	0.19
118.9481812	0.11
121.0090179	0.33
123.2272263	0.17
125.0147095	0.38
127.1367798	0.01
129.1658478	0.03
130.8949280	0.20
133.1264343	0.42
135.0151215	0.70
137.2619019	0.06
139.0550842	0.59
140.8513794	0.11
143.0273438	0.38
145.1458130	0.40
147.0447693	0.65
149.0794067	1.23
151.1167908	1.58
153.0114288	0.08
154.9428253	0.15
156.8898621	0.52
159.1303101	0.17
160.9886169	1.26
163.0763092	0.58
165.0922241	2.48
166.0449829	0.06
167.1349182	0.15
170.9857483	1.76
173.1749420	0.57
175.1558075	0.41
177.1721649	0.16
179.0960083	2.36
181.0878754	0.18
185.1249084	0.24
187.2009277	0.13
189.1042938	0.18
191.1247406	0.07
193.1094666	1.60
195.1319733	0.18
199.2531433	0.08
201.0903015	0.07
207.2196655	0.73
209.2394104	0.07
211.1859436	1.00
213.0556030	0.10
217.1478882	0.21
219.1111450	0.17
221.0117493	0.10
223.3736877	0.08
225.1081543	0.83
231.2076111	0.45
232.9664612	0.11
234.9979553	0.22
235.8470154	0.02
237.2281494	0.20
239.1732483	0.29
241.2495422	1.92
249.2365417	0.33
253.4461060	0.06
259.2075806	3.26
277.1900940	100.00
278.0072632	0.01
286.6945190	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1631
Annotation	Pelargonin
Peak:m/z	Relative Intensity
185.9928284	0.07
188.0060883	0.02
189.0039062	0.04
205.1014404	0.07
215.2277679	0.05
248.3652649	0.02
261.0117493	0.18
271.0623474	69.25
271.6722107	0.08
307.3782349	0.12
312.9449463	0.08
318.5194092	0.15
334.2634277	0.19
335.204834	0.26
358.0012817	0.10
367.3725586	0.14
391.0641479	0.05
415.2979126	0.70
429.3991699	0.08
433.0517578	100.00
433.6881104	0.38
437.3384399	0.04
438.2501831	0.06
450.8359985	0.06
465.5961304	0.02
466.303894	0.04
475.0335083	0.10
549.4796753	0.04
559.0547485	0.20
577.2191772	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1087.53
Annotation	Pitheduloside K
Peak:m/z	Relative Intensity
437.3856812	0.06
499.3534546	0.09
551.4715576	0.61
567.4350586	0.10
595.6324463	0.60
623.3226318	1.10
625.4920044	0.05
641.1132812	0.19
655.3867188	0.26
803.5255127	0.06
862.8420410	0.13
921.1363525	0.04
921.7392578	0.23
957.4422607	0.04
965.4266357	1.46
983.4401855	100.00
984.0723877	0.48
985.6220703	0.10
1009.2843020	0.44
1027.4958500	5.83
1037.5559080	0.08
1055.2216800	0.49
1055.8986820	0.15
1069.3272710	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1741
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
247.1930542	0.19
255.0284424	0.05
272.5587158	0.19
279.0274048	0.32
285.0551147	0.21
287.023468	0.11
292.0113525	0.08
302.1413879	1.62
312.8886719	0.11
317.0730896	100.00
317.6787415	0.26
330.821228	0.05
331.953064	0.10
346.651001	0.35
353.1486816	0.13
356.1245728	0.16
359.0809937	0.14
365.4505005	0.23
377.2786255	0.25
379.2439575	0.35
383.46875	0.08
397.1106567	0.14
411.7265625	0.37
413.3900757	0.22
421.1900024	0.12
443.3950806	0.60
445.4124756	0.34
446.3861694	0.12
449.1421509	0.25
461.3236694	0.74
462.6096802	1.07
463.2218018	0.85
474.3613892	0.11
478.9367676	22.38
487.3145752	0.19
502.3621216	0.29
503.2750854	0.27
505.4667358	0.10
522.6598511	0.14
534.3696899	0.33
553.2079468	0.46
559.7698975	0.21
565.8590088	0.41
578.8945312	0.17
581.456543	0.09
582.9134521	0.09
584.0346069	0.11
589.2515869	0.40
607.1985474	0.57
607.9781494	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1478
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.1273193	0.22
164.9890900	0.36
169.2372589	0.12
175.9473877	0.09
178.9474487	0.41
183.1773071	0.50
191.1522217	0.16
193.0359192	0.18
197.2922211	0.28
201.1016235	0.62
203.4159088	0.20
205.0986633	0.23
207.0077667	0.12
209.4204559	0.25
212.8873291	0.10
223.1890106	0.16
229.0928040	0.68
230.1522522	0.07
231.1418152	0.66
239.0699768	0.23
243.0912781	1.64
247.0955505	11.82
251.0404358	0.19
253.0951538	0.87
255.2454529	0.42
257.1943665	0.16
259.0379639	2.80
259.6804504	0.02
261.1354370	0.97
269.1638794	0.34
271.1231079	10.34
273.0759583	0.89
275.1591187	2.48
283.1397095	1.86
284.2822876	0.13
285.3120728	0.80
287.1889648	2.19
289.1120605	16.78
291.0641479	27.80
291.6697998	0.06
295.1728516	0.05
299.1310425	1.32
301.1022949	10.07
302.1546021	0.72
303.1673584	5.41
307.2310486	0.16
311.0705566	0.08
313.1353149	0.83
315.0432129	0.18
316.9829712	0.14
324.9091797	0.15
329.2977295	0.25
333.2201538	0.54
343.4850464	0.17
353.1941528	0.12
365.2426758	0.19
369.2308960	0.32
372.0629883	0.05
375.4646606	0.05
379.3178711	0.11
381.0708618	0.21
391.1912842	0.19
391.9742432	0.50
393.1441040	14.22
395.3833008	0.70
397.2836304	0.16
399.2012329	0.74
403.3598022	0.32
405.1271362	0.16
407.2218018	0.06
409.1358032	69.70
409.7593994	0.05
411.1484375	11.85
417.0122681	0.46
419.1674194	0.71
421.0885620	3.42
423.1894531	2.65
425.2141113	0.14
427.0484009	100.00
427.6808472	0.41
428.5044556	0.17
429.2050171	0.12
433.1570435	1.74
435.1983643	3.76
437.9532471	0.08
439.1250610	3.69
441.0551758	23.14
441.7020874	0.51
443.2828979	0.17
445.2534790	0.04
446.0922852	0.08
449.4844971	0.20
450.8310547	0.49
453.1618652	7.40
456.4555054	0.20
462.8519287	0.16
464.9528809	0.12
467.0502930	0.04
469.3663330	0.25
474.9107666	0.39
486.8109741	0.30
493.2316284	0.39
506.9067383	0.17
517.3853149	0.09
520.1288452	0.08
525.2078247	1.02
527.4172974	0.26
533.4246826	0.20
543.1875610	29.40
544.8072510	0.39
561.0396118	56.25
562.0924683	0.21
563.9588013	0.35
570.3859863	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	146.12
Annotation	1-Nitroheptane
Peak:m/z	Relative Intensity
58.1210022	0.03
59.9995766	0.01
83.0103302	0.03
88.0141907	0.02
99.9765167	100.00
101.9217377	0.01
104.2236328	0.01
128.1132965	0.01
129.0560760	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	546.2123
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0664673	2.38
158.1065674	0.41
159.1879730	0.12
177.9999084	3.12
178.9860229	4.15
180.1221313	2.77
180.8188171	0.11
182.1749573	0.15
184.0309296	0.71
184.8397675	0.51
186.0036926	0.21
191.1759491	0.76
196.0976257	7.00
197.1051788	3.56
198.1224976	0.61
207.1892090	0.17
209.2987366	0.23
213.8796997	0.11
215.2788086	0.43
224.1923523	4.85
225.1163940	4.37
226.2777710	0.20
231.8313293	0.05
242.0851135	0.52
243.1542358	0.10
249.9230042	0.40
251.2867737	0.33
258.4356079	0.23
259.1754150	2.65
260.1891785	2.74
268.0982666	50.28
269.0963745	35.79
270.3500977	0.37
283.1530762	0.51
286.1326904	43.69
287.1189575	27.36
305.4166870	0.15
310.3451843	0.13
311.6777954	0.23
313.1400757	0.23
320.2079468	0.52
321.1408081	0.97
322.1586914	0.22
323.2700806	0.19
341.1250000	0.07
345.2106323	0.38
346.2974243	0.46
353.3079224	0.20
376.0327148	0.45
383.1715088	0.18
385.1398315	0.43
397.1494751	0.14
399.3001099	0.80
400.1583862	1.33
401.2382812	0.20
417.1633301	36.79
418.2179565	58.97
419.2277222	0.67
421.2873535	0.06
427.3626709	0.16
437.2431030	0.19
439.2449951	0.31
443.3741455	0.22
455.2387695	0.68
457.2078247	1.44
461.3245850	0.25
466.4163818	0.06
474.6033936	0.76
475.2721558	1.89
476.3867188	0.06
485.4437866	0.12
486.3664551	0.15
499.7313843	0.11
501.2520752	0.23
503.3154297	0.82
510.6561890	1.21
511.4027710	0.88
528.3223267	24.12
529.2796021	100.00
530.1803589	3.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2787
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.8876495	0.08
153.1252136	0.09
196.0511932	0.22
214.1002350	1.69
237.3226929	0.02
255.2137451	100.00
390.3671875	0.04
392.1165771	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.156
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
187.2628326	0.06
189.1075745	0.25
191.2100983	0.14
193.1630249	0.04
198.0715637	0.09
199.0694733	0.33
201.0492554	0.05
211.2481232	0.05
213.0128632	0.08
215.4024658	0.20
227.1303406	0.04
230.2573242	0.05
232.9605560	0.06
235.3174133	0.08
239.0676270	0.03
240.1965790	0.02
241.0138397	0.20
242.1526794	0.22
250.9517975	0.10
257.1403198	0.24
258.0957642	0.14
258.9418335	0.06
267.0788574	0.02
268.3103333	0.08
269.3455200	0.05
283.2549438	0.13
284.9426270	0.13
286.0712891	0.29
287.3792725	0.04
289.2442932	0.05
299.6939697	0.16
301.0794373	100.00
302.1833496	0.32
319.2790222	0.07
322.2003784	0.08
323.3071289	0.04
325.1708984	0.03
331.0838013	0.03
337.0871582	3.60
337.7532349	0.01
343.0961304	0.05
355.0465088	0.03
359.3182983	0.09
387.0444946	0.06
405.0667725	0.05
413.2188721	0.16
431.1931152	0.63
433.9622192	0.11
437.3639526	0.04
443.2924805	0.07
447.3852539	0.03
449.2312622	0.41
461.5768433	0.15
463.1948853	13.27
464.0173950	0.25
467.4319458	0.03
469.2274780	0.02
476.0457764	0.05
477.5059204	0.01
487.6715698	0.04
503.3253174	0.12
505.2180786	0.17
507.5233765	0.06
509.1436157	0.06
514.7763672	0.08
515.5582275	0.12
517.4389038	0.09
519.2567749	0.08
531.2546997	0.06
543.5482788	0.06
549.3269653	0.04
551.1195679	0.31
571.3565063	0.05
576.7735596	0.63
577.3745728	0.95
578.2992554	0.08
578.9830933	0.05
589.3120728	0.15
592.9797363	0.04
595.2527466	1.61
603.0162964	0.17
607.2354126	0.51
614.1260376	0.05
615.6443481	0.02
621.2494507	5.20
622.0970459	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	832.62
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1281281	0.03
255.1391754	0.07
257.7726746	0.06
258.5838013	0.17
285.3009033	0.05
293.3301392	0.10
299.2718201	0.21
301.2048340	0.14
305.1774292	0.09
319.3945312	0.28
335.5295715	0.27
337.2691040	6.78
345.4414673	0.04
354.2492065	0.09
363.4176636	0.10
364.6023560	0.10
365.2543945	0.09
371.3581543	0.14
393.3759766	0.10
401.3148804	0.05
403.4168091	0.50
416.6290283	0.16
419.3577271	20.54
420.0195312	0.32
427.5446167	0.07
437.1232300	0.89
449.7348633	0.13
467.5273438	0.58
478.5407104	2.27
480.3600464	0.20
487.6749268	0.10
489.5122070	0.20
493.4535522	0.09
496.3862915	100.00
497.0832520	0.28
498.7164307	0.04
501.4212036	0.63
502.8594360	0.14
503.6220093	0.20
513.2896118	0.13
515.0200195	0.10
516.3704834	0.15
525.4779053	0.31
536.7479858	0.20
537.6401367	0.15
548.6934814	0.05
554.4500732	0.05
555.3911133	0.16
573.6727295	0.06
579.1950073	0.05
582.6442871	0.11
587.4553833	0.23
615.1997070	0.02
616.4646606	0.10
621.7050781	0.07
624.5613403	0.64
642.6498413	0.05
649.5486450	0.09
654.7078247	0.22
657.4665527	0.03
658.5036011	0.11
666.5370483	0.04
673.2655029	0.03
676.3598633	0.21
691.1410522	0.52
700.3927612	0.05
701.4351196	0.05
703.8116455	0.11
716.2100830	0.20
718.4890747	0.08
720.7073364	0.17
724.9048462	0.11
731.5062866	0.02
742.5321655	0.19
744.4041138	0.03
746.6712036	0.20
756.4301758	0.15
760.4733887	0.08
762.3770752	0.11
765.2504883	0.04
772.5780640	0.08
776.3948975	0.13
777.5208740	0.02
778.5956421	0.04
783.8366699	0.05
786.5702515	0.05
788.6409302	0.08
796.4953613	0.45
798.2599487	0.16
814.6951294	1.86
815.3461914	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
118.9971771	0.02
160.8081665	0.07
178.9285126	0.90
195.2900238	0.14
197.0615234	0.43
215.1172485	6.97
279.1857910	0.05
339.1091309	0.03
341.1701050	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.3129
Annotation	PS(20:2(11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
154.7576752	0.23
164.8486633	0.06
165.8265228	0.18
173.0166931	0.08
184.0413208	34.95
187.3001404	0.06
195.1721497	0.08
207.2854614	0.22
214.9670105	0.24
219.6608887	0.20
230.9443817	0.15
234.1909790	0.12
239.1044922	0.28
245.7964172	0.11
251.3123779	0.07
253.3401337	0.12
255.3250275	0.16
258.2033386	1.28
293.3746338	0.06
294.4262695	0.45
303.2712402	0.19
311.2971191	0.16
312.8018799	0.16
319.5081787	0.12
330.3975830	0.11
349.4464111	0.51
351.7038574	0.40
359.5321655	0.15
365.6167603	0.07
366.5670776	0.34
372.4476318	0.58
375.0643921	0.83
394.3944702	0.27
405.5006714	0.14
406.8771973	0.11
408.1724243	0.16
408.8421631	0.21
412.3405151	0.38
414.5226440	0.15
421.3423462	0.33
423.2566528	2.30
434.2899780	20.57
440.3241577	0.08
444.1145630	0.08
450.0927734	0.23
452.3218994	2.81
453.3356323	0.09
455.4356689	0.12
469.1215820	0.29
470.9057007	0.67
474.3616333	21.86
476.8426514	0.61
477.7666626	0.19
478.9531250	0.14
481.2775879	0.29
482.3770752	0.15
483.3401489	0.12
486.3746338	0.40
491.3005981	0.09
492.3505249	2.51
496.4212646	4.86
497.2984009	0.62
498.3490601	1.01
504.4242554	0.08
506.1528931	0.11
514.3431396	33.48
516.3912964	45.99
518.6607056	0.08
523.7684937	0.08
531.0399170	0.10
532.2947998	100.00
533.4044189	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.08
Annotation	Unknow
Peak:m/z	Relative Intensity
76.6443710	0.14
79.0309067	0.17
83.9125061	0.18
85.9551086	0.10
89.9317627	0.14
91.8267059	0.80
102.8309479	0.05
118.9001007	16.10
120.8762207	91.20
121.6539459	0.02
129.9696960	1.20
131.0855103	0.05
132.0127563	0.18
135.9312134	15.11
137.0372772	9.57
137.8923645	100.00
148.1685638	0.30
202.0764008	0.05
202.8347626	0.04
203.9261932	2.10
209.0865173	0.04
220.7343292	0.64
225.4348907	0.17
231.1064911	0.39
247.2308502	0.20
249.0189056	1.82
250.0913239	9.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.4877
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
240.9347992	10.76
251.4214325	0.15
259.1127319	1.70
277.2971191	66.36
278.4154358	0.39
297.0602417	11.39
315.0437317	2.62
332.2644958	0.16
357.0471191	0.22
413.1958618	47.98
431.3358154	3.02
451.2743530	0.25
466.4057007	0.29
501.5395508	0.28
519.2982788	0.84
523.4636230	0.14
575.3031616	100.00
576.0723877	2.83
593.3984985	16.20
594.3049927	0.83
675.4211426	0.48
691.3818359	0.54
704.1075439	0.30
719.6696777	0.63
750.5380249	0.45
793.4697876	0.20
807.3240967	0.12
809.5790405	0.12
835.3463745	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3149
Annotation	Unknow
Peak:m/z	Relative Intensity
224.0886078	0.03
277.1959839	0.69
426.0045166	0.01
456.8033447	0.01
502.3107300	100.00
503.0296021	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1243
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
137.0199738	1.62
151.0415344	0.22
161.0563049	2.28
163.3047638	0.07
165.1072083	0.03
179.0180664	0.22
190.9846191	0.24
199.0529633	0.02
203.1777954	0.11
204.9853821	0.32
221.0270691	0.07
231.2340698	0.02
238.8966064	0.07
245.1361694	1.80
247.0972290	0.05
251.1264038	0.03
271.2755127	0.03
281.3392944	0.01
289.0623779	100.00
290.0367126	0.05
299.0364685	3.04
313.1505737	0.19
315.4589844	0.12
326.9897766	0.10
329.1820068	0.02
355.1969910	0.08
361.0540466	0.07
368.1222229	0.02
390.9086609	0.02
405.4869080	0.03
407.0249939	0.22
433.2460022	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1252.1
Annotation	Unknow
Peak:m/z	Relative Intensity
455.4218140	0.74
480.6891785	4.48
481.4228516	2.27
539.6234131	1.66
551.7644043	0.69
571.7915649	5.52
589.3479004	15.54
590.5150757	3.83
657.5761719	4.94
671.3927002	0.50
703.4151611	5.50
716.5507202	3.42
733.5188599	13.71
749.2775879	0.61
750.5220947	0.89
751.3369141	10.83
752.0789185	0.50
793.2455444	4.12
819.3869629	40.69
820.4554443	2.80
833.5217285	4.51
834.6524658	1.39
847.2658691	1.51
865.4716797	19.78
866.4753418	7.78
883.3439941	3.17
891.3591309	100.00
892.3244629	27.72
909.3167725	63.06
910.3845215	37.12
911.0083008	0.35
927.4379883	12.46
928.7391357	8.55
1009.7592770	3.26
1027.4487300	66.11
1028.5749510	32.84
1045.2963870	14.28
1046.3923340	4.39
1062.2407230	0.60
1071.5174560	8.54
1072.7083740	6.01
1088.8463130	9.27
1089.4770510	47.56
1090.4133300	17.01
1189.4643550	85.85
1190.4184570	21.67
1206.9830320	6.03
1233.3935550	63.11
1234.3854980	39.07
1235.0997310	1.13
1992.4420170	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.0685
Annotation	Unknow
Peak:m/z	Relative Intensity
76.9480667	0.07
85.0595551	0.05
86.0460281	0.06
88.1156158	0.58
89.8355255	4.88
90.7692032	0.04
109.0895233	0.13
115.0272522	0.03
115.7279968	0.06
118.9106293	75.69
119.9802704	2.63
121.9572754	0.02
123.0289764	0.09
124.1341553	0.02
124.8297729	0.04
127.1284027	0.06
129.9301910	0.69
135.8962250	100.00
136.9981537	2.25
140.0009155	0.02
142.9669342	0.04
143.9031830	0.07
147.9098053	0.05
151.1359253	0.02
151.9297638	0.02
154.9073029	0.04
159.0414581	3.64
161.0277557	0.11
176.9061584	2.93
182.1464844	0.16
188.0084839	0.02
192.3978729	0.03
195.1602478	0.09
196.1560822	0.05
198.9477386	0.02
199.9567566	0.38
202.0967560	0.72
202.9148560	0.20
205.0967255	0.03
207.2492981	0.04
209.7912140	0.13
212.0852051	0.01
218.0948334	5.60
219.9933472	9.90
221.2808380	0.06
224.0004730	0.07
225.0911560	0.16
228.2314301	0.02
229.9427032	0.65
230.9371490	0.87
235.2839355	0.07
237.2504730	0.15
238.0150604	0.10
243.0251617	0.20
243.7490845	0.26
244.5465088	0.22
245.5734100	0.07
248.0099487	35.80
249.0420532	1.00
250.2727203	0.11
254.5467377	0.17
257.3274841	0.18
258.2587280	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.01
Annotation	Unknow
Peak:m/z	Relative Intensity
116.1260834	0.03
127.9809036	0.24
133.8730469	0.04
144.1137390	0.19
155.9623718	5.78
172.1239929	0.15
189.8448029	0.08
198.0512238	0.14
199.9346619	47.80
239.0722961	1.78
241.0390015	14.20
242.1908569	0.17
243.2448425	0.09
244.0480347	0.16
245.9831543	0.19
265.1419678	0.13
266.9252014	11.96
268.1059875	0.10
269.1561890	0.18
281.4070129	0.04
283.2062378	1.81
284.9601440	37.10
301.1438904	0.39
311.1856079	0.10
325.3146362	0.04
326.6065369	0.16
327.2702332	0.21
328.9755249	100.00
353.5203552	0.05
354.5983582	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.1748
Annotation	Unknow
Peak:m/z	Relative Intensity
98.9408112	0.66
109.3521957	0.13
115.5911865	0.14
117.0018311	24.91
127.1507187	0.05
127.8165970	0.03
130.0346985	0.50
131.8385315	0.03
151.9751282	0.03
155.9200745	0.05
160.4876404	0.15
162.9203491	100.00
169.0522461	0.07
180.0711823	1.30
195.3020020	0.04
207.5148621	0.05
209.0741882	0.16
210.2350464	0.13
213.1013184	0.37
213.7314453	0.03
217.6011963	0.05
225.0840149	0.02
228.2003479	0.05
229.3158569	0.15
230.3138428	0.16
233.0972595	0.04
236.2831726	0.07
245.0448303	0.07
247.8945618	0.10
249.9107056	0.10
257.1798401	0.07
259.3164062	0.10
263.2312012	0.07
267.1613159	0.07
277.4057312	0.71
278.1424561	0.27
283.0121155	0.04
286.2265930	0.12
288.7752075	0.36
296.9008179	0.73
297.7072144	0.23
301.0736694	0.08
306.6841431	0.07
315.2474670	0.11
320.7168579	0.10
321.7476501	0.33
323.8639526	15.36
324.7067871	97.14
325.5135498	0.20
326.9511719	0.05
328.1317139	0.09
332.4516907	0.56
333.1493835	0.19
333.8318787	0.21
334.4783325	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2253
Annotation	Lactulose
Peak:m/z	Relative Intensity
281.2050781	0.06
339.6680298	0.08
341.1029663	100.00
647.0857544	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1718
Annotation	Eupaformosanin
Peak:m/z	Relative Intensity
127.9662018	1.84
131.1417847	0.46
133.9224854	0.08
135.0213318	0.50
145.1127625	0.89
146.1087646	0.42
152.9831390	0.98
156.1805878	0.27
157.0594482	0.03
163.9584351	0.18
171.2892303	0.17
173.0970459	6.53
179.0605164	3.57
180.0280151	0.25
181.0932922	0.36
183.1908875	0.06
184.1791840	0.22
196.5393372	0.16
197.2115631	2.62
198.0779877	4.62
200.1298523	0.98
201.0146484	0.10
202.0081329	0.12
208.0471039	0.64
215.3210144	0.36
225.0659790	4.56
226.2208710	0.59
226.9346771	1.14
242.2066345	29.97
244.1621094	1.11
245.1734009	0.41
248.1702576	0.83
249.3590393	0.05
250.1235046	0.09
254.3138428	0.05
256.0289612	0.06
263.0347595	2.52
264.3142700	0.04
266.2516479	0.38
267.3250427	0.90
268.1358337	0.13
269.3193359	0.26
270.1969299	0.77
273.2080383	0.45
274.2018738	0.04
281.2292480	0.08
282.1651001	0.54
284.0972290	1.91
285.1910095	0.27
290.2605591	14.32
291.2101135	0.18
292.3522339	0.05
293.0156250	1.09
293.7497559	0.07
309.2722473	6.87
310.1530151	0.21
311.3227539	1.01
317.3407593	0.12
321.0597229	0.11
327.2619934	4.37
328.9790344	0.63
335.2933350	0.76
336.0173950	0.21
341.2242432	0.42
352.1114502	0.07
353.1744080	72.41
354.2623291	0.84
357.4956360	0.48
358.1123962	0.35
359.3105774	4.68
360.0682983	0.23
371.2381897	83.01
371.9706726	0.35
373.0890198	0.28
375.2798767	2.37
377.1566467	6.47
383.1139526	0.04
384.1445312	0.62
401.1886292	100.00
402.1604919	3.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1249.58
Annotation	Unknow
Peak:m/z	Relative Intensity
411.2056885	0.98
437.1574707	0.70
455.4534302	0.38
481.4543762	2.12
497.7224731	0.32
523.3491211	1.51
537.7824707	0.64
551.4866333	1.05
557.4822998	0.91
569.5440063	4.74
570.5656128	0.35
587.4272461	1.25
613.6530762	1.19
619.8258057	0.40
655.2858887	2.84
655.9495850	0.24
683.4497070	3.96
701.6453857	0.77
707.2381592	0.82
749.3316650	14.33
777.7856445	0.30
791.6768799	0.64
798.9673462	1.11
805.2209473	0.87
807.4890747	0.74
817.4453125	53.01
818.8538818	0.38
831.0797729	0.60
845.4229736	11.03
863.4730225	25.30
881.5490723	3.35
889.2276611	100.00
890.3553467	0.91
907.3875732	74.38
925.3018799	4.56
926.1336670	1.09
927.5502930	0.73
934.7893066	2.11
959.3090820	1.68
971.4328613	0.59
1007.3770750	2.95
1008.0394290	1.14
1025.3809810	63.60
1026.1019290	0.26
1043.4431150	10.19
1069.4473880	13.93
1070.3819580	0.74
1087.4646000	35.32
1088.5543210	1.85
1115.4840090	0.92
1141.6795650	0.78
1156.0969240	0.64
1169.6369630	2.83
1187.3332520	67.07
1188.0034180	0.21
1205.0571290	1.56
1231.3619380	99.52
1232.4360350	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.4872
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
241.0122681	12.29
259.3028259	0.84
261.4060364	0.32
275.4577637	0.14
277.2340393	60.98
278.3356934	0.95
295.2868347	0.84
297.0872803	15.84
315.1448364	2.24
413.1939087	55.97
414.3722534	0.15
431.1282349	1.76
483.2609253	0.57
497.3862915	0.42
518.9982910	0.40
575.3699341	100.00
576.3548584	1.89
585.5452271	0.72
593.4093628	22.75
594.4059448	0.37
690.0126343	0.34
691.4703979	1.40
721.2888794	0.16
745.4705200	0.25
789.5980835	0.23
792.4225464	0.37
806.5231934	0.28
809.2644653	0.20
817.1771851	0.30
834.4596558	1.64
835.3629150	1.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1355
Annotation	Unknow
Peak:m/z	Relative Intensity
167.2749786	0.19
173.0833740	0.05
175.0121307	0.42
179.0244141	1.90
180.0162811	0.19
181.2100983	0.40
181.9722595	0.16
185.1145325	0.11
187.3250122	0.18
188.9832764	0.02
191.0414734	0.28
193.1848145	0.13
199.1136932	0.43
200.0714874	0.30
201.2451935	0.16
203.0598297	0.06
210.8998871	0.32
212.1247559	0.06
213.1865845	0.45
215.1630249	0.14
217.0357056	0.20
223.2228394	0.08
224.0505676	0.10
227.1242523	1.77
227.8642426	0.04
229.2067413	1.31
230.2783813	0.18
231.0071411	0.10
232.8745575	0.05
235.0137482	0.04
236.1768799	0.06
237.1122131	0.14
239.2449341	0.30
241.1352692	0.71
242.9926453	0.13
245.2698364	0.20
251.9146423	0.05
253.1740723	0.23
255.1378174	19.79
256.2872925	1.94
257.1593323	7.01
258.9897461	0.41
265.1086121	0.37
267.1111755	0.57
269.1340942	0.38
281.1187134	3.16
282.1731567	0.09
284.0499268	100.00
285.1605835	73.78
286.1808472	1.28
289.0969849	0.69
291.1458740	0.60
294.9161377	0.23
297.1248779	0.32
298.3803406	0.33
299.3640747	0.22
300.0292969	0.19
301.2479858	0.16
303.7455139	0.05
304.8498230	0.09
307.2964478	0.54
309.1294250	2.58
310.2775879	0.32
311.2201538	0.31
313.1321411	0.60
319.4904175	0.36
320.1895752	0.27
321.1332397	0.04
323.0163574	0.09
325.0599365	0.46
326.1568604	1.59
327.1903687	10.23
328.2319946	0.31
329.0646973	0.15
333.0193481	0.46
337.5738525	0.09
339.0371704	2.42
340.9550781	0.12
342.1807251	0.06
343.1146240	0.13
347.9470825	0.09
349.2624512	0.89
351.2179565	2.44
352.2850342	0.29
353.0740356	0.29
355.0806274	0.39
355.9679565	0.04
357.2822876	0.98
360.3297729	0.16
365.3351440	0.19
367.2329712	0.97
369.0626831	2.29
371.0610352	0.36
375.5059204	0.13
376.4711304	0.16
379.2977295	0.14
381.1918335	2.16
383.1439819	0.14
384.9664917	0.23
387.2655640	0.69
391.1037598	0.10
393.2266235	1.88
394.1354370	0.04
401.2621460	0.68
402.3609619	0.38
403.3580933	0.08
407.3964844	0.07
408.3102417	0.74
409.1990967	0.24
411.0910645	2.61
412.2438354	0.59
415.1855469	0.27
416.3185425	0.25
417.1212158	0.19
425.1273804	0.95
426.2181396	0.43
427.2553711	0.04
429.1545410	77.74
430.3740234	2.88
431.2236938	2.22
432.3208008	0.10
433.8399048	0.03
435.2125854	0.59
438.1449585	0.23
439.4014282	0.17
440.8696899	0.35
443.4328613	0.06
445.1679688	0.10
447.1161499	21.64
448.3591919	0.65
451.3206177	0.18
452.1633301	0.26
453.2446899	1.09
459.0949707	5.18
459.8490601	0.05
471.6848145	0.21
489.2590942	0.29
492.2387085	0.06
498.1359253	0.07
500.9769897	0.16
502.0427856	0.09
503.3715210	0.20
507.1895142	0.19
517.3925171	0.39
519.1338501	0.19
523.1588135	0.08
525.5358276	0.15
530.9232788	0.10
533.3927612	0.52
534.0823364	0.12
534.9863281	0.99
541.2414551	0.12
543.3008423	0.18
546.4393921	0.31
557.3259277	0.19
561.0417480	1.16
561.6809692	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.5259
Annotation	Saikosaponin BK1
Peak:m/z	Relative Intensity
257.3058167	0.26
306.8969116	0.51
367.4800110	0.31
383.3805542	0.27
389.1728516	0.20
391.4014893	0.22
395.2505188	0.24
404.9269409	0.18
407.3927307	0.66
408.3718262	0.28
421.5587769	0.24
423.5704956	1.19
437.7987671	0.25
439.4226074	16.13
441.3862915	7.14
442.0233154	0.19
462.3558350	0.12
465.1881104	1.47
467.4459839	0.06
479.4954224	0.43
494.7705078	0.13
509.4339600	62.95
510.1126099	1.34
511.5371094	1.06
525.2191772	0.08
537.4575195	3.54
565.7693481	0.16
581.3015747	13.81
587.2002563	0.13
599.5337524	6.33
601.2943115	0.55
617.6522827	0.85
623.3396606	0.33
640.9563599	0.13
643.2590942	0.15
647.1956177	1.67
650.2983398	0.20
651.3041382	0.22
665.2243652	1.02
700.9727783	0.22
717.4623413	10.42
735.4138794	0.74
761.4988403	1.22
762.8937378	0.62
779.4433594	3.49
795.5791626	0.09
820.9799194	6.36
821.5874634	100.00
823.0518188	0.18
823.7178345	0.12
863.3901367	11.60
865.3635864	8.43
866.0942993	0.03
867.3963623	0.37
875.1041870	0.31
879.1266479	0.07
881.6473389	0.13
895.1525269	0.13
907.4530029	35.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1298
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
124.9460602	1.36
130.1798706	0.06
137.0391693	1.13
146.9548492	0.05
149.0919800	0.26
161.1239014	0.87
179.2197266	0.10
186.8990479	0.14
189.0190125	0.06
190.9633179	0.09
203.2894897	0.02
221.0259399	0.09
227.1109619	0.04
229.1495361	0.74
231.0635376	0.13
239.2232361	0.11
253.3977661	0.02
255.1201172	0.07
271.2437439	0.05
273.0625610	100.00
287.0912781	0.42
297.0973511	0.66
299.0160217	1.28
341.0468140	0.12
344.8461304	0.03
371.5320740	0.03
373.2669067	0.09
393.4027100	0.06
417.1985779	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.1971
Annotation	Unknow
Peak:m/z	Relative Intensity
157.9302063	0.09
175.0796204	0.82
181.9938354	0.02
209.2017365	0.03
212.9016113	0.04
229.1884766	0.03
240.8687134	0.01
255.2057495	0.06
268.5332642	0.08
273.0655823	0.02
283.2729492	0.02
285.0793152	0.21
313.2958374	0.07
327.3006897	0.16
328.8440857	0.01
336.9655151	0.01
339.1820374	0.03
343.0737610	0.03
345.2957764	0.05
357.2605591	0.05
358.8747864	0.04
361.3585205	0.58
365.6949158	0.07
368.1270447	0.03
385.2914734	0.63
392.9812927	0.02
403.2581482	100.00
411.3591309	0.02
419.2069702	0.20
419.9359131	0.02
429.2965393	0.25
430.3139343	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.0981
Annotation	Crotonoside
Peak:m/z	Relative Intensity
81.0364761	0.01
83.0960312	0.02
84.7828903	0.02
92.9674835	0.05
94.9823608	0.06
95.9516296	0.05
97.2107010	0.01
102.2821198	0.01
106.9758377	0.01
108.0347214	0.03
109.1267395	0.03
120.0132904	0.01
121.0127182	0.06
122.8582077	0.02
124.8955536	0.02
127.1271210	0.01
129.0894928	0.03
133.2702332	0.01
134.0833130	0.03
135.1900635	0.07
136.0911255	0.05
137.1002197	0.01
138.2887268	0.01
141.1345520	0.03
142.0662231	0.02
143.2776489	0.03
149.0765991	0.11
149.9503784	0.01
151.9750366	100.00
152.9998779	0.04
155.0246277	0.02
163.1270294	0.04
163.8546753	0.02
165.1278076	0.06
167.0738831	0.01
168.0170746	0.02
169.0545654	0.11
177.2881012	0.01
181.5054169	0.03
183.2892151	0.04
185.1496124	0.03
191.2347107	0.02
194.1958008	0.01
204.2270508	0.02
204.8715515	0.06
207.3260193	0.02
214.3054199	0.01
217.0107727	0.03
218.3036499	0.03
220.0379944	0.04
222.8144836	0.04
224.2576904	0.04
226.1803284	0.01
238.2015686	0.07
239.2898560	0.06
240.1462097	0.02
243.1508789	0.01
247.3450317	0.10
248.3368835	0.10
252.2749329	0.03
256.2257080	0.02
265.3995056	0.16
266.1644592	0.43
267.0635376	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
202.8268738	0.95
221.0826721	5.08
233.283371	0.53
235.0393677	0.21
250.6072998	1.44
258.9210205	0.14
262.9329834	0.59
268.5349426	0.56
280.6535645	1.50
305.2088928	0.98
321.2660828	0.70
323.1445312	5.17
333.2197876	0.38
340.9887695	23.71
346.1499634	0.23
383.1308594	100.00
384.9989624	0.79
397.0480347	1.24
398.2241821	1.18
402.0975342	0.18
407.2601929	0.40
412.6908569	1.70
413.2937622	0.32
425.3168335	0.47
439.5488281	0.26
442.9002686	11.66
467.2388306	0.60
477.3862305	0.22
485.2608032	29.59
502.9351807	2.37
517.8545532	0.16
545.222229	2.27
590.1505737	0.15
592.1123047	0.44
619.3602295	1.12
647.2103882	2.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.2497
Annotation	Unknow
Peak:m/z	Relative Intensity
203.0836029	0.02
297.1336060	0.12
303.2974243	0.02
333.4225464	0.04
343.3731689	0.71
347.2830811	1.11
357.1853638	0.06
361.1622925	0.54
365.2967529	11.89
387.1505127	0.07
389.1514893	0.62
401.3776855	0.20
407.2680054	24.03
419.2564697	0.12
430.9130859	0.11
433.1046753	0.12
437.2996826	0.16
448.6849365	0.30
449.2900391	1.42
461.2503052	0.11
467.3328857	0.10
479.4923096	0.17
488.9729004	0.02
491.3173828	0.52
500.0096436	0.17
509.2807617	25.35
511.4345703	0.09
527.1954956	5.56
528.2929077	0.02
551.1848145	0.04
552.3197021	0.15
555.2229614	0.14
567.5864258	0.16
569.1277466	100.00
569.8703613	0.11
571.1699829	1.46
571.7734985	0.09
580.3723755	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1067.5424
Annotation	Soyasaponin bg
Peak:m/z	Relative Intensity
308.2567749	0.59
377.1602783	0.21
382.9808960	0.75
392.5609131	0.52
393.3496094	1.57
425.0977173	0.31
434.5319214	0.66
437.3699646	1.13
439.4589844	0.88
440.3122559	0.48
441.3672485	2.48
442.1619873	1.72
450.3988647	0.70
458.2632141	0.51
468.3455200	2.51
491.7595215	0.35
507.8083496	0.54
509.5540161	0.51
510.6795654	1.30
527.5887451	0.35
536.4245605	0.51
537.5870361	4.13
538.4852295	2.76
551.2714844	0.75
554.2457275	1.66
563.3718262	0.99
564.6076660	4.36
565.2816162	2.55
566.7517700	4.32
568.6437988	4.82
581.4566650	1.72
583.3611450	2.32
584.1878662	0.82
596.3782959	1.02
624.4628296	0.81
626.1480103	0.22
635.4697876	18.53
636.4027100	68.54
638.4605103	0.19
651.7759399	6.54
652.6567383	1.94
663.3322754	3.06
664.4751587	6.28
667.6913452	0.60
679.4024658	0.38
680.1799316	0.39
681.6111450	1.02
697.0664673	0.98
707.2653809	16.15
708.2870483	55.63
718.2429199	10.00
719.3250122	0.29
720.3740845	0.84
723.9990845	0.26
725.2854004	6.57
726.3510132	8.27
733.5988159	1.32
734.4202881	3.78
736.2547607	2.15
741.3624268	3.22
742.5798340	4.38
743.6223145	0.48
744.7823486	0.77
752.3862305	1.08
759.5417480	0.31
836.7259521	0.61
860.5628662	0.46
862.4639893	0.28
878.4201660	0.24
879.5333252	5.31
880.4520264	23.97
887.3881836	0.35
888.5653076	0.37
898.4814453	1.38
905.5447998	2.13
906.5427246	13.63
910.6174316	3.71
921.7431641	2.93
922.6547852	4.48
924.0203857	0.85
924.6805420	1.92
926.6135254	0.52
941.7523193	1.28
942.6252441	10.41
949.6993408	0.21
967.5295410	7.04
968.5891113	52.23
969.6718750	1.07
1006.3525390	8.45
1025.2695310	2.08
1026.5456540	7.48
1050.4150390	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.2502
Annotation	Uscharin
Peak:m/z	Relative Intensity
193.1942749	0.04
194.0758057	0.07
207.2638245	0.13
208.3403625	0.03
211.2542114	0.06
227.3432312	0.07
251.3321838	0.06
269.2716675	0.02
271.0869141	0.06
285.4603882	0.09
289.0864563	0.06
291.1214905	0.04
292.7110596	0.08
294.3082886	0.03
303.1198425	0.02
318.0679016	0.03
320.1348877	0.09
336.1437988	0.15
340.5850830	0.03
342.7238770	0.03
354.2347412	0.12
361.2889404	0.01
362.4440918	0.06
369.6357422	0.18
370.5606079	0.12
371.5540771	0.02
387.2911377	0.31
388.2768555	0.45
391.3239746	0.24
392.2287598	0.03
404.2993774	0.10
406.3052979	0.17
422.4332886	0.09
424.2239990	0.08
441.1373291	0.14
443.3908691	0.05
444.0768433	0.06
448.2156372	0.08
449.1790161	0.06
454.5213013	0.03
461.4674683	0.03
466.4193726	0.05
490.1945190	0.06
494.4674683	0.29
500.2800293	0.46
511.4614868	0.01
512.3923950	0.23
523.4522095	0.16
524.2554321	0.17
526.4772339	0.13
538.4583130	0.18
542.3098755	100.00
543.2531738	0.11
550.1015015	0.17
563.8376465	0.06
568.1616821	0.72
568.8131714	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1246
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
133.0885773	0.05
137.0734863	1.14
161.0594788	1.79
161.9503479	0.06
162.8849640	0.21
165.2793884	0.02
175.0635376	0.07
178.9026184	0.28
188.9652405	0.02
190.8648071	0.05
201.1914978	0.02
203.1698608	0.26
204.2433777	0.08
205.1593018	0.48
221.2592316	0.02
227.1420898	0.11
229.0152588	0.05
231.5076599	0.05
239.1485901	0.03
243.2090759	0.19
245.0949402	3.35
247.0832825	0.20
251.0232544	0.02
255.9340820	0.09
260.8922424	0.05
271.0710754	1.09
280.8602295	0.03
287.3202515	0.03
289.0979614	100.00
297.1871948	0.03
299.0326538	2.12
303.1029663	0.02
309.1318359	0.03
311.0311890	0.03
313.1296387	0.14
320.1958008	0.11
321.2688904	0.07
324.9817505	0.01
327.2469482	0.02
331.1730347	0.13
355.1021423	0.03
367.1047668	0.10
373.0302734	0.03
391.1364441	0.01
401.2200012	0.05
405.0464172	0.26
407.2214050	0.35
408.2511292	0.02
409.3814392	0.02
433.3457336	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.3242
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1132507	0.96
176.0355835	3.63
177.0917206	1.35
188.8097687	0.25
192.9658203	20.59
194.0293579	4.62
214.9353333	0.28
215.7778778	0.34
223.3892822	0.08
229.1822205	0.06
230.9836121	0.19
232.9737701	0.58
234.1281281	0.51
236.1043396	0.07
237.1248322	0.17
241.1496582	0.08
242.2760010	0.26
243.1405029	0.40
257.7898560	0.46
259.0668640	0.23
260.0085754	0.37
260.9337158	0.09
270.9848022	0.17
277.2391968	0.89
278.1557007	1.76
285.9956970	1.07
287.1096802	0.15
288.0747681	0.09
302.2952881	0.13
304.1457520	0.32
306.2425842	0.28
308.2090454	0.13
322.1840210	11.55
323.1635132	4.58
327.1199951	0.10
336.2540283	0.24
339.0044556	0.15
346.9730225	0.09
351.7192383	0.07
353.1601562	0.18
354.5455933	0.17
356.7473755	0.33
365.5835571	0.15
370.1533813	1.92
371.2219849	4.74
383.4940186	0.18
385.5383301	0.05
387.0549927	0.45
390.9232178	0.05
406.3000488	0.12
407.2855835	0.15
415.3448486	0.27
421.9716797	0.05
430.1695557	0.06
455.3735352	0.17
469.2467041	0.86
470.1716309	2.13
470.8975220	0.20
487.3512573	27.47
488.3134155	100.00
514.8130493	0.29
519.3071899	0.20
527.8267212	0.93
528.5029297	3.38
535.4899292	0.49
543.7288208	0.51
558.0858765	0.15
563.1269531	0.08
571.2561035	0.12
572.7191772	0.12
579.1171265	0.06
581.3578491	0.10
598.6453247	0.75
599.3724365	7.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1972
Annotation	Carolenalin 4-O-beta-D-glucoside
Peak:m/z	Relative Intensity
125.1561203	0.14
128.0268097	0.02
134.9618835	0.02
138.0648956	0.25
143.0338135	0.05
147.1729736	0.09
151.0826263	0.09
152.5034790	0.62
153.1768188	5.85
157.0598145	0.08
161.0802307	0.41
165.3258362	0.42
167.4020081	0.03
171.9649658	0.04
179.2252197	0.04
187.0135498	0.29
188.9933777	0.05
205.1258850	5.72
214.2159882	0.03
223.1060791	1.28
231.2422638	0.04
236.9154663	0.04
244.2019043	0.08
245.2112427	0.04
246.9574280	0.16
257.1063538	0.06
263.2902527	0.07
263.9854736	0.32
265.4644470	0.04
279.5427856	0.10
289.2963562	0.09
297.1352234	0.06
301.4726562	0.05
307.4878540	0.10
315.1029968	0.13
317.4338684	0.14
329.1884155	0.13
341.1380920	0.10
359.1678467	0.07
365.2018738	0.06
367.1798401	100.00
381.1614075	2.25
383.2454224	0.26
385.2376404	1.37
399.1383362	0.12
409.2163696	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1251.6
Annotation	Spumigin B1
Peak:m/z	Relative Intensity
457.5365601	1.32
498.6388855	1.23
553.8497314	0.91
569.6415405	1.74
570.5251465	0.80
571.4233398	7.68
587.4401855	0.50
589.3596802	8.72
621.4954834	4.51
639.4865723	1.08
659.4791870	0.41
665.8914795	0.59
677.4160767	1.03
691.4523926	2.10
711.4161987	3.94
733.4403687	18.46
734.7579346	0.35
751.5118408	13.90
799.3412476	1.67
805.1583252	2.35
819.3519287	61.22
819.9604492	1.32
833.5658569	5.97
847.5352783	1.96
865.4219971	75.40
883.8231201	2.43
891.3643799	61.61
895.8109131	1.03
907.6881104	2.15
909.3642578	97.17
910.0125732	2.55
923.0549316	2.49
927.6105957	19.62
979.4564209	0.75
1009.4783940	3.71
1027.3828120	100.00
1028.0561520	0.68
1045.3771970	18.92
1071.4639890	14.53
1089.4980470	48.57
1090.4604490	0.64
1091.4735110	3.42
1189.4307860	89.04
1190.2248540	0.52
1207.4244380	12.66
1221.6557620	1.66
1233.3862300	66.56
1235.8242190	9.05
1236.5970460	0.54
1280.5671390	2.25
1281.5939940	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.2307
Annotation	Staudine
Peak:m/z	Relative Intensity
158.0349274	0.82
161.2206268	0.13
176.0115356	3.01
179.1878815	0.03
193.0518646	1.89
193.9185181	0.07
211.1105194	0.23
217.2846375	0.02
241.0770569	0.03
242.9616394	0.03
243.8058319	0.03
268.1196899	0.06
286.0981445	2.96
288.0204468	0.02
296.1183777	0.39
304.4536743	0.03
305.9522705	0.10
307.1939087	0.02
322.2615356	0.02
326.2968140	0.12
333.0372314	0.03
336.3673706	0.14
340.2796631	0.06
349.0596924	0.10
355.2048340	0.03
356.2291260	0.09
367.2379761	0.07
368.2332764	0.26
370.2930298	0.05
385.1972046	2.27
386.1912231	10.08
390.7268677	0.07
395.8671875	0.03
397.2317505	0.07
400.6802368	0.04
401.3207397	0.07
403.2533569	100.00
418.3216553	0.07
427.1822510	0.03
433.9628296	0.03
443.2117920	1.56
444.2961426	0.02
456.4231567	0.02
469.3151855	0.07
470.0797119	0.07
496.3440552	0.02
497.1930542	0.02
514.2576294	1.55
515.5189209	0.34
516.3236084	0.06
519.2479248	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1436
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
83.8120880	0.21
85.9245453	24.12
129.9319763	0.60
131.9687500	100.00
148.0186920	0.48
198.1100311	4.96
215.0656281	0.64
225.0611115	0.38
243.0324554	6.75
244.0644684	27.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.2103
Annotation	Manumycin G
Peak:m/z	Relative Intensity
151.2121277	0.02
155.2207642	0.04
181.1503601	0.03
192.9295044	0.04
197.2146912	0.65
202.1164093	0.03
203.0689850	0.02
215.2744904	0.07
216.9938812	0.17
225.1670227	0.34
225.9888763	0.08
229.1179962	0.02
230.9829407	0.02
243.0925751	6.61
246.9769897	0.49
248.0566101	0.24
261.1293945	0.76
265.1598206	14.87
279.1144409	0.05
282.3211365	0.02
284.4308167	0.02
293.9998169	0.05
297.1953430	0.03
312.2267761	0.14
314.0911255	0.01
319.1050110	0.08
325.2423096	0.09
327.1134033	0.12
330.1976624	0.49
331.4797363	0.02
332.2459106	0.15
338.4624634	0.01
342.0901489	0.15
343.1400757	0.29
345.2455444	0.11
354.2344360	0.17
360.1911621	1.24
361.1354370	0.04
367.7694397	0.03
372.1511230	0.45
378.1187134	100.00
378.7562561	0.10
380.2574463	0.01
392.3418579	0.02
394.1380615	0.02
423.3457336	0.04
426.7690125	0.02
430.1815186	0.05
441.1477356	0.16
443.9665833	0.48
444.6731873	0.06
445.2919617	0.03
447.3066711	0.05
458.8847656	0.08
459.6085510	0.01
461.3828125	0.10
469.6782532	0.07
471.2416687	0.16
472.3717957	0.02
485.2385864	0.02
489.1661072	4.04
490.1850281	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2133
Annotation	Docosanediol-1,14-disulfate
Peak:m/z	Relative Intensity
159.3897400	0.02
175.1917114	0.71
189.2914124	0.06
199.1979370	0.04
205.2753906	0.10
225.3079529	0.01
230.2713623	0.02
255.2265167	0.04
256.9357910	0.02
258.9934692	0.08
268.3374634	0.01
271.1897278	2.34
271.8424072	0.02
273.0759888	0.02
285.4760742	0.09
289.3148193	0.89
295.3417358	0.03
299.1454468	0.02
301.2907410	0.77
303.4721680	0.07
313.2891846	0.87
315.2450562	6.61
316.7709351	0.05
319.0713501	0.14
327.2130737	0.11
329.2836304	1.43
333.1527710	12.18
334.3296509	0.04
345.0405273	0.05
347.1663208	0.77
347.8166504	0.07
355.0635376	0.07
357.2145386	0.53
359.1796265	100.00
360.3439941	0.33
373.2033691	18.73
374.2246094	0.16
375.2678833	4.82
377.2205200	1.00
381.1233521	0.05
383.2621460	0.06
395.3587646	0.02
401.1653442	9.10
401.8306274	0.09
405.1589355	0.06
415.0510254	0.05
419.2523193	5.38
425.1948853	0.07
431.2420044	0.29
434.9139404	0.19
443.1351929	0.28
445.1944580	0.02
449.2377319	0.18
461.1686401	0.40
479.1075439	1.50
493.3429565	0.21
495.1204224	0.40
509.3129272	0.09
520.9497681	0.25
521.5712891	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1177
Annotation	Petunidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
176.8818970	0.06
180.8936310	0.03
184.0180359	0.40
201.1251221	0.04
213.2837524	0.06
217.0731659	0.02
227.1520996	0.07
242.2218170	0.04
251.9256592	0.06
256.3142700	0.10
257.9794312	0.02
271.1746521	0.10
291.0454407	0.05
293.0094604	0.02
302.3908081	0.11
317.0571899	100.00
317.7036743	0.27
320.6624146	0.04
321.7833862	0.03
329.1024780	0.04
331.4150391	0.04
337.2271729	0.03
341.2743530	0.13
359.1190796	2.00
372.8067017	0.03
376.1758423	0.02
383.0298462	0.30
386.5924683	0.03
397.2330933	0.08
399.1693115	0.03
403.5036621	0.04
405.5917969	0.21
411.2693481	0.01
413.4385376	0.02
425.3167114	0.16
436.0465088	0.07
461.0295410	0.08
470.4486694	0.01
476.6808472	0.02
477.5237427	0.02
478.9562988	0.26
485.3109741	0.08
488.9875488	0.06
501.3265381	0.10
502.8290405	0.16
511.0901489	0.02
513.0917358	0.09
517.1664429	0.05
521.0453491	0.08
528.1974487	0.11
529.0596313	0.64
546.5368042	0.73
547.2526855	2.77
550.0043335	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2178
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
99.3677292	0.02
125.1269608	0.04
137.1831665	0.09
141.2161255	0.03
151.1213074	0.08
152.8509521	0.02
154.9561157	0.14
157.0492859	0.04
163.9769592	0.05
165.2343292	0.06
171.1095428	8.90
177.3605957	0.08
183.1506042	0.35
185.2153778	0.19
189.2994843	0.02
194.5509796	0.08
195.1577301	0.30
195.9866333	0.21
197.1153107	0.29
201.1854858	4.26
207.1512451	0.37
209.1881104	14.76
211.0746765	0.46
213.1033325	1.13
214.3465271	0.02
219.5170593	0.05
221.2203674	1.71
223.0871887	0.52
225.2738647	0.15
227.3126831	0.21
229.3316040	1.25
231.4022522	0.07
233.1782837	3.18
235.2897034	0.04
237.1559143	0.15
239.1499023	1.71
243.1984558	0.30
247.3557434	0.40
251.1647339	21.55
253.1866455	0.26
257.4316101	0.06
262.6537170	0.06
265.5125122	0.03
267.3953552	0.19
269.1764832	3.58
270.2320557	0.11
273.2397156	2.91
289.2388000	0.13
291.2100220	11.15
291.8881226	0.22
299.3963013	0.05
307.2297363	0.07
309.2279968	100.00
310.4068604	0.11
311.2474365	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1235.61
Annotation	YM 47525
Peak:m/z	Relative Intensity
395.4534912	0.38
439.5322876	0.44
441.5797729	2.10
481.1855164	0.23
537.4561157	1.36
551.2021484	0.39
569.3620605	1.56
571.4658813	2.04
573.5077515	1.46
589.5655518	0.68
641.4302979	1.88
669.5278320	1.11
687.3090820	1.58
712.9295044	0.51
731.5358276	1.12
735.5478516	1.00
751.5155029	3.75
783.3085938	0.36
803.4683838	44.82
804.3935547	0.26
817.4193115	4.02
819.5346680	0.22
831.3967896	3.03
846.4693604	0.21
849.4991455	14.33
863.5490723	0.56
865.3352051	1.32
866.7180176	0.64
867.8173828	0.21
875.3085938	64.17
875.9604492	0.44
891.3395996	0.39
893.4305420	56.39
894.1029053	0.09
909.1519775	3.50
911.5223389	9.82
935.3331299	0.52
939.1302490	0.48
945.4476318	1.44
993.4407959	1.43
1011.4084470	26.31
1027.5611570	4.17
1029.4859620	5.41
1045.5037840	3.13
1055.6805420	6.80
1073.4918210	34.22
1074.6038820	0.29
1107.7448730	0.36
1173.4372560	33.30
1174.1064450	0.48
1191.4121090	0.37
1199.4299320	0.80
1217.4443360	100.00
1218.5174560	1.81
1363.6751710	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2145
Annotation	Stachyose
Peak:m/z	Relative Intensity
203.2095795	0.21
219.1966248	0.36
221.1422424	3.85
233.1943512	0.12
235.2062988	0.15
249.1525421	0.14
250.6174927	0.92
263.1665039	0.33
280.954834	1.26
287.1838379	0.22
292.0079651	0.12
299.2102966	0.09
304.9850464	0.83
311.0948181	0.60
318.1835938	0.59
321.1728821	0.36
323.0733643	7.57
341.1046753	25.46
377.5303345	0.40
383.1258545	100.00
385.1117554	0.21
407.2310791	0.87
409.1672974	0.15
411.1668091	0.31
412.734436	2.23
425.2086792	1.62
439.4272461	0.54
442.3867188	1.31
443.0393066	9.98
454.8927612	0.12
467.3096924	0.27
473.0933838	0.19
485.2333374	24.63
498.0053711	0.13
503.1031494	1.95
514.317749	0.15
540.3306274	0.54
544.4447632	0.12
545.3327026	0.98
553.0371704	0.06
562.164917	0.06
566.946228	0.10
583.4127197	0.07
601.4521484	0.18
605.1606445	0.13
619.1400146	1.51
644.8656616	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	756.3126
Annotation	Unknow
Peak:m/z	Relative Intensity
337.1717529	0.04
343.1705933	0.04
367.0979004	0.03
371.2324219	0.01
387.3242798	0.03
389.4281006	0.01
412.6628418	0.01
437.3979492	0.02
447.2816162	0.05
452.1012573	0.01
457.5681763	0.01
461.0853271	0.06
470.4077759	0.02
519.2012329	0.02
528.8471069	0.02
530.1926880	0.02
545.4274902	0.01
547.1744385	0.01
550.4091797	0.02
553.0807495	0.01
554.2149658	0.03
575.4126587	0.01
576.1431885	0.01
580.1990967	0.03
583.1198120	0.02
585.3935547	0.06
586.1519165	0.01
588.6494751	0.01
603.3796387	0.02
606.2170410	0.02
615.1899414	0.02
658.7368774	0.01
664.3617554	0.01
666.3442993	0.03
667.0762329	0.03
695.5787964	0.02
696.3479004	0.01
711.3451538	0.03
712.4772339	0.28
713.7009888	0.11
725.3289185	0.33
732.7608032	0.06
734.4671021	100.00
735.4037476	0.21
736.2814331	0.06
737.7954712	0.03
738.5262451	0.04
739.6699829	0.01
745.5750732	0.02
830.2646484	0.01
865.6176147	0.01
951.3984985	0.03
1037.4978030	0.01
1051.4218750	0.07
1067.6115720	0.01
1109.2894290	0.01
1127.3278810	0.07
1128.6098630	0.01
1228.1588130	0.02
1246.7137450	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.0793
Annotation	gamma-Glutamyl-S-methylcysteine sulfoxide
Peak:m/z	Relative Intensity
87.9822235	0.56
94.8762131	0.03
108.9688721	0.01
121.9651031	0.04
124.1882935	0.01
129.9638062	0.31
147.0111389	0.02
152.0078735	4.62
158.3605957	0.03
176.8559570	0.02
180.8465881	0.01
182.8503113	0.04
190.0630493	0.01
199.1893616	0.08
200.0393066	0.17
204.9049988	0.03
206.7707825	0.02
216.9965820	100.00
217.9529724	0.04
235.0462036	0.05
239.3544006	0.10
245.3513489	0.07
251.2767334	0.03
263.0004578	0.43
263.7258911	0.02
265.1281738	0.05
272.6133728	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	154.0622
Annotation	L-Histidine
Peak:m/z	Relative Intensity
66.1211090	0.13
66.9936066	0.26
71.9483032	2.88
80.7653198	0.68
92.9108887	10.13
93.5126190	0.20
108.0494995	3.76
109.1284943	9.92
110.0725098	7.86
118.0177002	5.36
135.9961090	90.65
137.0398712	100.00
154.0717010	4.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	874.5042
Annotation	Unknow
Peak:m/z	Relative Intensity
792.6654663	62.11
856.5267944	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.2334
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
97.0195770	0.07
121.0974579	0.37
125.1260757	0.06
127.1391983	0.17
137.0601196	0.19
139.0549622	0.26
141.0781860	0.16
145.1705017	0.06
153.2218628	0.68
155.1094360	0.28
157.2351990	0.10
163.2035522	0.18
165.2403870	0.04
169.3653564	0.21
171.1718750	31.61
172.1713257	0.10
173.1892242	0.20
177.0157471	0.29
178.6925507	0.08
183.1498108	0.51
184.3609772	0.05
185.1613312	0.11
195.2172241	0.12
197.2312317	0.23
199.0375671	0.16
201.2063599	0.99
204.1805878	0.06
207.6757965	0.04
208.3156738	0.08
209.4076233	0.31
211.2168274	0.48
212.1377258	0.22
213.2059021	0.51
217.0393982	0.12
220.2467346	0.04
221.3270874	0.20
222.1997375	0.06
223.1734009	1.83
225.1356506	0.14
227.1249390	0.24
229.2432251	4.00
230.7221680	0.16
231.3683472	0.73
233.1786499	0.09
235.2957153	4.06
237.1567993	0.45
239.1697083	1.14
241.2692871	100.00
242.4745483	0.29
243.9129028	0.03
245.2847900	0.09
247.2500916	0.04
249.3327942	0.18
251.0967407	0.16
253.1690979	7.72
255.2656250	0.09
257.2669678	0.11
259.1864624	8.80
260.2582092	0.15
261.0388794	0.25
265.3670044	0.18
267.2514648	0.34
269.2553711	0.73
271.2760620	4.62
272.0500488	0.04
273.2467651	0.34
275.2481995	9.20
275.9503784	0.13
281.4769897	0.07
283.2413940	0.42
285.3250122	0.63
286.2045898	0.08
289.3157043	0.17
291.3601074	0.89
292.2626953	0.13
293.2446594	12.09
294.1940308	0.31
295.4880371	0.11
297.2490540	0.05
299.4388428	0.18
301.0031738	0.14
307.4133606	0.15
309.2412109	2.54
311.2570496	83.33
312.2877197	0.59
313.3562622	0.15
314.2878723	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.166
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
112.8995667	2.63
118.3738480	0.49
119.0068970	5.14
121.1781464	0.84
129.1291351	0.69
131.1536560	0.96
142.9918518	3.18
144.5413208	1.50
146.9926605	4.91
148.9149475	0.40
155.0609131	0.34
161.0182190	0.49
163.0427856	100.00
163.9310760	0.25
179.0567627	2.13
190.8793030	0.80
207.0550232	25.22
209.1763000	4.01
218.0084839	0.46
225.1223755	14.15
226.2159424	0.24
231.1589966	0.38
249.1210022	0.37
261.4158630	0.75
279.1282349	4.59
280.1357422	0.65
341.0725098	3.26
369.1301575	28.59
369.7653198	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2176
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
94.9639816	0.20
96.9826660	0.12
101.0876083	0.17
110.9697952	0.29
113.1227188	0.05
114.8971405	0.12
115.5554810	0.12
119.1904678	0.05
123.1267242	0.95
125.0911942	1.71
127.1055984	0.96
129.3065796	0.12
137.2085266	0.07
141.1518860	0.10
149.2360840	0.30
151.2684937	0.21
152.3374939	0.06
153.3515015	0.39
155.2278137	3.77
159.2043610	0.07
163.1354675	0.37
165.1414948	7.51
167.1325836	1.78
171.1418152	23.83
175.3652039	0.19
177.1138916	5.98
178.2013550	0.18
179.0939941	0.47
181.0442352	0.10
183.0464630	7.68
185.1095428	3.10
187.1977692	0.10
189.2410736	0.22
191.2020874	0.54
193.1450806	7.40
195.0569458	0.60
197.1456604	2.10
199.3775635	0.99
201.0622711	0.07
203.1022491	1.73
205.3971558	0.72
207.3287201	0.15
209.0960693	14.46
211.1863098	56.54
212.1233826	0.47
213.0486450	0.65
217.3430786	0.10
218.9103088	0.28
221.2291260	20.26
222.3271484	0.37
223.2370300	0.42
227.1594543	2.95
229.1496582	100.00
230.1131592	0.33
235.1449280	0.14
237.2449341	0.21
237.9943848	0.23
239.1712646	13.39
239.8605347	0.24
241.1765442	0.14
245.3075867	0.13
247.2427979	10.64
251.2816772	0.52
255.3489380	0.30
257.3365479	0.59
258.1433105	1.21
263.1996460	0.28
265.2479248	0.48
269.2181396	1.44
271.2353516	0.30
273.2293091	4.77
279.2103882	0.73
281.4432983	0.32
289.2890625	0.27
291.2078857	68.82
292.2952881	0.48
293.9723511	0.60
297.3540649	0.55
299.2626038	1.16
307.2677917	1.32
309.3410950	17.52
310.4434814	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.3286
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
225.2710419	0.24
230.9581604	0.05
245.4576721	0.10
301.0639343	0.30
309.3286133	0.10
312.1685791	0.06
325.0349731	0.06
326.9592896	0.24
356.2742310	0.03
369.1987305	5.01
387.1875000	100.00
388.3264160	1.63
389.3766479	0.31
397.3468628	0.03
406.0667725	0.31
409.9838867	0.07
411.3087158	0.10
413.2534790	0.10
419.1951904	0.05
423.2534180	0.13
429.3103638	3.60
430.3557129	0.22
431.1423950	0.06
435.1622925	0.27
450.4099731	0.18
453.3115234	0.22
457.1674805	0.04
475.4948120	0.07
476.2268677	0.04
484.0790405	0.09
486.3074951	0.03
509.3212891	0.17
514.7780762	0.09
519.1567993	0.58
529.2753906	0.37
532.2970581	0.05
535.3243408	0.07
544.9642944	0.16
551.3829956	0.14
553.3290405	0.22
561.2158203	0.08
562.4925537	0.13
563.3798218	0.13
577.2601929	0.69
579.2431030	0.08
580.4716187	1.10
581.5021362	0.30
587.2826538	0.11
594.1569214	0.11
595.4468994	0.43
599.5321655	0.10
601.1272583	0.06
605.3663330	0.17
612.1505737	0.31
613.1707764	0.16
619.0708618	0.16
623.5433960	0.25
635.0695190	0.08
637.3059692	0.05
655.2955933	0.16
657.0805054	0.06
684.9691772	0.16
705.0686646	0.05
711.1925049	0.14
713.6797485	0.10
721.2135010	0.22
724.8963013	0.17
739.3287354	2.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	987.51
Annotation	Moroidin
Peak:m/z	Relative Intensity
321.2476501	0.05
335.3908691	0.35
365.1464233	0.12
379.2624207	0.19
405.4989624	0.08
500.9035034	0.10
581.1647949	0.09
627.3347168	0.32
645.1931152	0.13
790.6000977	0.21
825.1113281	0.09
925.5258789	0.15
936.7064209	0.09
1978.2019040	100.00
1979.4930420	19.02
1986.0383300	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.3
Annotation	Unknow
Peak:m/z	Relative Intensity
205.2892456	0.72
247.0188141	6.79
276.8325195	0.54
409.5703125	9.83
410.2695923	0.95
423.5618896	1.62
445.4071655	2.50
454.4967041	4.47
482.4690552	5.13
488.2329712	2.80
505.6262817	5.75
509.5401001	3.32
513.1901855	15.99
513.9190063	7.17
518.5740356	2.86
535.4338379	3.92
536.5045166	100.00
544.4292603	5.93
570.6176147	1.68
586.2260742	32.15
586.9229126	19.16
608.5626221	14.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1219.61
Annotation	BQ 123
Peak:m/z	Relative Intensity
421.3197632	0.16
439.8214722	0.52
465.2449951	0.76
555.3174438	0.27
571.4354858	1.43
573.5111084	5.35
605.4161377	0.65
615.5657959	0.57
641.5449219	0.66
667.5581055	0.47
669.4244385	2.58
687.4476318	0.60
711.4605713	0.62
731.2858887	1.17
735.3499756	6.89
739.2093506	0.19
783.4750366	0.64
793.6300049	0.95
803.5343018	23.37
804.6101074	0.86
813.3248291	1.37
817.4518433	4.09
831.1163330	2.06
831.8988647	0.58
833.9248047	0.70
848.9484863	3.70
849.6171875	26.26
850.6049805	1.02
867.5994873	2.15
875.3519287	51.46
875.9957275	1.55
893.3929443	62.91
894.0450439	1.43
903.1770020	0.51
911.3996582	6.65
925.6383057	0.27
959.2934570	0.72
993.3671875	2.73
995.4277344	16.28
1010.8415530	2.87
1011.4832760	43.81
1013.4526370	1.88
1029.5644530	4.19
1037.3078610	0.34
1055.6250000	3.05
1057.5568850	0.27
1073.4383540	17.50
1074.4135740	0.71
1157.4482420	92.51
1158.3730470	0.41
1175.6121830	2.97
1201.4013670	100.00
1202.2087400	3.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.4872
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
241.0335846	7.62
259.1245728	0.72
275.1156921	0.11
277.2259216	55.50
278.1965332	0.69
297.0914917	11.62
298.0165405	0.48
315.1430969	1.67
355.2561035	0.32
413.2257690	43.93
414.0135498	0.20
430.6884155	0.79
431.4022217	1.94
519.3303833	0.67
553.0917358	0.28
575.2689819	100.00
576.4476929	2.06
593.3148804	15.01
637.4235229	0.48
691.6149292	0.65
697.3002319	0.37
699.5585327	0.90
733.4425049	0.44
774.5928345	0.41
792.3013306	0.20
793.7638550	0.07
817.4172974	0.49
834.4846191	0.84
835.3281250	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.27
Annotation	Taxumairol V
Peak:m/z	Relative Intensity
263.0900269	0.02
275.2451172	0.26
289.1446533	0.13
299.1207886	0.05
325.0141602	0.09
337.4382324	0.07
343.2687988	0.37
347.3027954	1.02
361.3449707	0.28
365.2677612	12.57
379.3020630	0.07
387.3613281	0.20
389.1787109	0.13
391.3291626	0.09
403.2135620	0.16
407.2540894	23.99
419.3786011	0.08
420.9915161	0.02
431.4391479	0.26
435.4199219	0.04
437.2244873	0.02
449.2282715	1.18
460.8731079	0.06
463.3894043	0.02
466.9317017	0.04
479.3424683	0.07
480.8379517	0.12
491.2010498	0.72
509.2089844	26.94
509.8884888	0.11
511.3847656	0.04
527.1312866	3.19
537.3717651	0.03
567.3560181	0.29
569.1356812	100.00
569.8958740	0.20
571.3161011	2.24
597.4530640	0.37
598.5231934	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1829
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1304016	0.44
173.1935730	0.06
180.6286011	0.02
191.1514587	0.08
209.0529785	100.00
216.3228455	0.04
222.9092255	0.07
224.2558289	0.05
242.2846985	0.03
261.2863770	0.19
269.1842651	0.11
271.0555420	0.21
289.2170105	0.43
326.8356934	0.04
332.3524780	0.04
336.8096924	0.07
348.1399536	0.03
349.4276123	0.04
378.0988770	0.02
392.8545532	0.07
405.5477905	0.03
414.2502441	0.11
415.0868530	0.02
487.1964722	0.04
489.0806274	0.02
503.4663696	0.12
504.3970337	0.08
505.3745117	0.35
533.4427490	0.02
534.9816284	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Safflomin A
Peak:m/z	Relative Intensity
175.2021332	0.01
189.0296936	0.01
191.1376495	0.02
193.0599213	0.17
199.9837189	0.03
231.0863190	0.04
233.1703033	0.01
239.9041138	0.02
243.3567810	0.03
255.2891998	0.08
259.0635376	0.08
267.5426636	0.01
269.1561279	0.40
273.2011719	1.01
275.0957642	0.02
279.3015747	0.05
281.0927429	0.02
287.1517639	1.60
293.1323242	0.02
297.1160889	0.05
298.1217041	0.02
303.2658691	0.05
311.1002808	0.20
313.3947754	0.04
322.5493164	0.07
323.2865601	0.15
337.0399170	0.05
343.3166504	0.06
353.0114746	0.07
355.1831055	2.99
358.9858398	0.02
377.0530396	0.03
378.8704834	0.11
386.5460205	0.02
395.2526245	0.02
405.1662598	0.07
407.4361572	0.04
409.1339111	0.03
413.2788696	0.06
421.0900269	0.02
431.2433472	0.88
433.3589478	0.04
436.8740234	0.05
438.1453857	0.03
445.0955200	0.03
449.1362305	100.00
449.7518921	0.18
461.0166626	0.02
465.2507324	0.03
473.1530151	0.65
475.2943726	0.05
480.2838135	0.19
481.2682495	0.06
489.1364746	0.03
491.0864868	0.14
503.1642456	0.06
506.0952759	0.05
515.2293091	0.03
517.0479126	1.16
519.2765503	0.07
525.2287598	0.04
533.0122681	0.01
551.4808960	0.04
564.1537476	0.07
565.3325806	0.06
567.3740234	0.03
569.4917603	0.03
573.1900024	0.08
575.2125244	0.07
581.3479614	0.02
591.3301392	0.11
593.1484985	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.1575
Annotation	Neoacrimarine I
Peak:m/z	Relative Intensity
156.0834198	0.19
158.0392761	2.44
163.3210297	0.05
167.1125183	0.59
170.0847931	0.42
170.9166412	0.14
175.1244202	0.62
176.0240936	1.82
177.0404053	0.07
181.2734833	0.20
193.0582581	26.71
197.0595551	0.38
208.9277954	0.08
211.0340729	7.76
214.6143036	0.10
215.3196564	0.53
223.0454559	0.12
233.0416870	1.25
259.1226196	0.31
269.2307739	0.34
286.2279968	0.14
288.2921143	0.77
301.2889404	0.27
304.0289307	0.86
305.0855103	0.06
316.0912476	0.27
320.2671509	0.11
322.1479492	100.00
370.1377563	0.09
385.1225586	0.11
387.4736328	0.05
402.9691772	6.67
410.9472046	0.19
443.2461548	0.80
453.0364990	0.60
472.2883301	0.28
485.8341675	0.16
514.3273315	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.3704
Annotation	PC(16:0/5:0(COOH))
Peak:m/z	Relative Intensity
174.9674377	0.09
200.2618256	0.01
206.2780914	0.05
207.2895660	0.02
209.1912689	0.09
213.0685883	1.22
219.2806091	0.01
231.0595093	0.14
238.4517822	0.01
252.2395172	0.14
256.0635376	0.07
265.0446777	0.01
268.5396118	0.02
275.4211426	0.06
276.3843384	0.19
290.5718689	0.08
293.1318359	0.39
296.0606079	0.05
310.8912964	0.17
312.9583130	0.07
313.5634155	0.04
316.3179321	0.03
328.7715454	0.02
333.2558594	0.01
334.2106323	0.06
336.3520508	0.18
354.2269897	0.24
358.2359619	0.03
359.2833862	0.05
372.2064819	0.06
388.2847900	0.04
389.3059082	0.04
393.5235596	0.09
398.3953857	0.06
418.7276001	0.14
422.4752808	0.02
436.0953369	0.16
436.7019653	0.05
437.9522095	0.09
452.5504150	0.13
453.8064575	0.05
454.4779053	0.08
455.5166016	0.07
456.4057617	0.04
457.2371826	0.02
463.4426880	0.01
469.3833008	100.00
470.0095825	0.38
477.6210327	0.06
479.3531494	0.12
480.7888184	0.17
482.8962402	0.02
490.6212769	0.03
494.4381714	0.16
500.4755249	0.02
504.1364746	0.03
508.5777588	0.04
510.5956421	0.04
518.5201416	0.04
521.3681641	0.03
526.1383057	0.01
530.4023438	0.04
533.5479126	0.05
534.8340454	0.10
536.1557617	0.05
538.4826050	0.03
539.7989502	0.16
543.3231812	0.05
549.3967896	0.45
560.5889282	0.06
561.3008423	0.04
564.3463745	0.10
566.8333130	0.26
567.4991455	0.09
574.3881226	0.03
575.1805420	0.04
578.3227539	0.04
579.7396240	0.02
583.7890015	0.04
592.4536743	0.74
593.3950806	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1973
Annotation	Manumycin G
Peak:m/z	Relative Intensity
146.0703125	0.55
153.0150146	1.65
171.1659241	0.57
178.9657898	0.55
180.0937500	0.71
181.1253815	0.74
182.9145508	0.09
196.3379211	0.64
197.0567627	2.47
215.2021027	0.24
221.1501312	0.07
223.1321106	5.38
238.9753113	0.46
241.2006531	16.11
245.0305023	22.38
247.9271851	0.11
249.3597717	0.49
259.1940002	3.52
263.0952148	2.26
266.2489624	0.94
269.2615967	0.17
284.2218018	1.23
292.3867493	0.08
293.1200562	0.14
297.3836060	0.34
298.1519165	0.08
307.3204956	0.10
308.1426392	0.10
310.2239075	4.44
322.9651184	0.13
325.4792786	0.10
328.3889465	0.97
333.3950806	0.08
334.0791016	0.10
341.1330261	0.58
351.2612610	0.45
352.1302795	3.01
358.1077881	4.49
369.2650757	15.42
370.2468872	5.20
373.1293335	0.05
376.1945190	4.82
387.2080994	0.17
388.5048828	0.10
395.2271423	10.21
413.3392334	19.65
415.2722168	0.08
421.1604614	0.75
439.1701355	11.17
439.8471375	0.09
443.2746887	0.51
451.3780212	0.35
457.2133484	75.93
458.0416260	0.28
459.3241882	0.88
460.3618469	0.19
461.3063049	0.56
469.1637878	4.14
470.1635132	0.18
487.2262878	100.00
488.2528992	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.2102
Annotation	Manumycin G
Peak:m/z	Relative Intensity
148.3411255	0.06
150.8453979	0.04
197.1995544	0.48
202.1838989	0.23
215.0904388	0.10
220.1495056	0.06
225.1750031	0.42
226.0210114	0.02
231.2297516	0.07
240.8144836	0.05
243.1029205	7.00
247.0720978	0.35
248.1676636	0.24
261.1396790	0.75
265.0520630	13.95
293.9048767	0.24
311.1166992	0.01
312.1446838	0.36
315.1085815	0.02
324.7939453	0.10
326.3280945	0.03
330.2595825	0.55
331.9921265	0.20
342.0742798	0.19
343.1889038	0.48
345.2571411	0.08
354.2020569	0.26
358.2088318	0.11
360.2286987	0.64
361.2794800	0.05
372.1057739	0.34
375.3334351	0.03
378.1421509	100.00
378.7799683	0.38
390.2040710	0.03
423.1577148	0.06
425.8318176	0.01
428.2068787	0.04
441.4283752	0.11
443.1325378	0.03
444.2603149	0.24
459.2566833	0.15
471.2015076	0.09
489.2404480	3.82
490.2057800	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.2115
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
243.0637512	0.57
245.0209351	4.89
247.0675659	0.97
251.2081604	0.11
253.5939331	0.11
255.0775299	0.78
257.1687622	1.00
258.8703308	1.07
259.5478821	0.27
263.1993713	0.16
265.1962585	0.05
267.0928345	0.47
269.1426392	0.74
271.1846924	1.67
273.0765381	5.40
274.0529480	1.88
275.1121826	9.70
279.1645813	0.99
282.0281372	0.08
283.0577393	1.15
285.1440430	2.00
286.1681824	0.61
287.0562744	8.06
288.9002075	1.66
291.1470032	3.21
293.0920410	0.14
295.1734619	0.37
296.4712524	0.06
297.2135010	0.64
299.0604248	1.43
301.0531616	3.34
303.1852722	1.27
307.4215088	0.24
311.0384521	0.30
313.0681152	0.41
315.1569824	0.41
317.0586548	0.46
328.9962158	0.18
330.9927979	0.63
333.2141724	0.20
335.0545044	0.07
337.3988647	0.04
339.1315918	0.22
341.1593323	0.27
347.2542114	0.54
350.9803467	0.31
357.2419434	0.02
359.0419922	0.09
360.9298706	0.56
363.0886230	0.39
365.2666626	0.64
369.2185364	0.15
375.0846863	1.43
377.1411743	0.20
379.2161865	0.88
381.1182861	28.70
383.1479492	0.59
385.3515625	0.29
386.9311523	0.26
389.1716919	0.81
391.1824341	4.28
393.2072754	12.04
395.1920776	1.46
397.4967651	0.03
399.2731323	0.38
401.0905762	0.07
402.9464111	0.98
405.1940308	2.28
407.1359863	23.65
409.0747681	9.70
409.6753540	0.07
411.1187744	3.75
415.1650391	0.38
417.1680298	3.44
419.2711792	5.30
421.0397949	3.11
421.6641846	0.30
423.0921631	1.62
425.0602417	18.65
427.0847778	10.00
431.2132568	0.91
433.2252197	1.79
435.0993042	9.41
437.0944824	18.29
439.0204468	0.92
444.9705200	0.06
449.0695801	2.07
451.0524292	0.84
453.1027832	1.96
467.1527100	0.14
469.0236816	0.03
481.0740967	0.17
494.9754028	0.18
501.2034912	8.20
510.9606934	0.54
513.1390991	0.53
515.3399048	0.65
516.3676147	0.04
519.1754761	9.09
525.1614990	9.35
527.1476440	0.51
528.9896851	0.35
529.6331787	0.06
531.3079224	0.45
537.5140991	0.15
539.5844727	0.29
541.3101807	0.03
543.0583496	27.54
543.7572632	0.06
545.0695801	1.35
555.1928101	5.04
556.5483398	0.10
557.1929932	0.23
558.1220703	0.15
558.9674072	0.73
561.0150757	100.00
562.9602661	2.99
563.7287598	0.25
567.0601196	0.34
571.2715454	0.13
572.9942627	4.90
575.4044800	0.06
576.8384399	0.30
579.0138550	39.98
579.6784058	0.12
580.9898071	0.26
585.2166138	0.04
589.1774292	0.35
590.8646851	1.36
591.5679321	0.29
597.1342163	0.15
605.3311157	0.34
606.8718872	0.15
615.2459106	0.07
620.7410278	0.79
621.3969116	0.22
647.1989746	0.05
652.9901733	0.26
663.1090698	3.81
665.1052246	0.76
675.0787964	0.15
675.7332153	0.07
677.1836548	0.11
679.0991211	0.46
681.0656128	13.84
681.8943481	0.05
683.0853882	9.15
683.7659912	0.06
687.6552124	0.65
688.3270874	0.92
689.5642090	0.17
691.2115479	0.39
693.3963013	0.04
694.3062744	0.11
696.6382446	0.94
697.2805176	7.40
699.1036377	11.22
707.2156372	1.03
708.2720337	0.10
715.0524292	15.38
716.2639771	0.06
724.9830322	6.71
725.6026001	0.11
729.2886963	0.10
739.3858032	0.35
766.4562378	0.43
797.1493530	0.18
814.3316040	0.16
815.2348633	0.18
833.0610352	5.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.209
Annotation	7,7-O-Dihydroebuloside
Peak:m/z	Relative Intensity
126.8377991	0.05
127.9560623	0.58
130.2738647	0.08
146.0203857	0.10
151.1015930	0.15
166.9438782	0.26
179.1531067	1.27
180.0981445	0.05
185.2468262	0.04
187.4458923	0.09
197.0912781	0.84
201.0973511	0.17
203.1161194	3.83
213.3336945	0.03
223.0792084	15.77
225.0201721	0.04
240.4439697	0.22
241.1047363	3.21
254.4327087	0.07
257.3048706	0.03
265.5050659	0.15
266.2819824	0.08
270.1504211	0.12
272.2452393	0.04
280.3442993	0.14
296.1936035	0.31
297.3504639	0.04
298.2410278	0.91
299.7045593	0.11
301.1968689	0.11
310.1842651	0.09
314.2222290	0.14
316.2890625	11.92
325.2653809	0.21
331.4330750	0.03
339.4497986	0.05
365.3034058	0.05
383.3141785	2.91
384.3793030	0.09
392.2290344	0.04
400.4433899	0.10
401.3004456	0.21
410.3824158	0.06
427.2711182	100.00
428.3337097	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.1273
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
66.8927231	0.40
78.8675766	0.03
84.8937531	9.10
99.0319824	0.45
105.0553894	0.03
111.0693970	0.40
118.9945374	0.62
121.0505219	0.31
122.8975220	0.02
124.9930267	0.09
127.0349121	0.15
129.1015015	0.13
131.0885162	0.88
135.0569611	0.09
143.0486145	1.48
145.0126648	2.38
147.0071564	0.08
149.0286713	1.76
154.9111176	0.01
163.1041565	1.81
165.2218933	0.16
167.0954742	4.98
169.1742706	0.04
173.0360565	0.07
179.1970673	0.11
181.0406647	0.04
183.1255035	0.02
191.0450287	42.81
196.2726288	0.02
197.0711212	0.45
207.8378448	0.03
209.0870514	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.1657
Annotation	(+)-Trachyspic acid
Peak:m/z	Relative Intensity
129.0854645	0.14
158.9708557	0.13
173.2985840	0.28
175.0462036	0.29
177.0952454	0.24
187.3984680	0.12
200.9303589	0.57
203.1662598	0.20
207.3317871	0.13
213.2167206	0.27
215.3786011	0.20
217.2567596	0.27
221.0895386	0.22
225.1362762	0.28
228.2093506	0.08
229.0988159	0.10
231.2366943	0.46
233.2837524	0.33
234.1813660	0.15
235.0776062	0.19
237.0789795	1.49
239.3631592	0.08
242.9855347	0.10
243.8604736	0.14
245.3374329	0.77
247.2315369	0.88
249.1138306	0.54
257.3532410	0.10
259.5520630	0.25
263.1981506	0.23
265.2010193	0.67
267.1017761	0.42
269.2120667	0.12
273.2429199	0.07
274.1135254	0.29
275.1278076	1.68
279.1872559	2.63
280.6538086	0.14
281.2966309	0.08
287.1784058	1.30
293.2144470	8.99
294.3362122	0.37
301.3961182	0.09
303.2206116	0.06
305.2048645	2.04
306.4606323	0.16
311.1862183	27.97
312.3536682	0.81
319.2855530	1.12
323.2583618	1.34
331.2804260	0.90
337.3110657	4.95
338.2237549	0.24
349.2618103	15.10
350.2922363	0.94
355.1981812	100.00
356.2685852	4.11
365.4110413	1.11
367.2214661	59.22
368.3561401	0.45
379.0140076	0.29
390.7929382	0.11
391.4083557	0.18
393.2165833	0.98
394.3367920	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0775
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9467545	0.21
128.9714508	1.98
144.9883423	0.12
147.0174255	2.29
173.0127258	2.25
191.0126648	100.00
193.0602722	0.61
207.0513153	0.14
208.9908447	7.27
223.1250610	0.02
232.8160706	0.05
257.4119873	0.12
283.2680359	0.05
290.3724976	0.09
305.3845215	0.06
313.1377563	0.11
323.1361694	0.20
327.1937561	0.05
349.1611633	0.21
367.0953064	8.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.33
Annotation	Unknow
Peak:m/z	Relative Intensity
243.0992889	1.54
245.1490021	2.13
249.3490295	0.19
255.9835510	0.19
257.2774658	0.26
259.2764893	0.19
261.1611633	0.65
262.0486450	0.28
265.3500366	0.20
269.1998291	0.40
273.1818848	0.69
275.3091736	0.93
281.1517944	0.13
282.1517639	1.31
282.9005737	1.36
285.0037537	1.97
287.1602173	16.94
289.1661377	5.41
297.2198792	0.19
299.2270813	1.40
301.0536804	0.40
302.9787598	0.38
305.1082458	0.93
311.4165649	0.21
315.1340942	0.45
318.2531738	0.99
319.2411499	0.41
321.3322754	0.53
327.0849609	0.65
328.2509766	0.97
329.0793457	0.59
331.2316284	0.13
337.1754150	1.04
338.1386414	0.15
339.2402039	0.47
341.1180420	2.27
345.0938416	0.31
347.2480469	9.25
348.2406006	0.15
355.1655273	0.14
357.2225952	0.27
363.0746460	5.09
365.3292847	0.44
367.2807617	0.50
369.0794678	0.43
379.2673340	0.59
380.3341980	0.13
381.1514282	3.06
383.1035156	0.78
385.2933960	0.12
387.0691528	1.41
391.0900269	1.55
395.1351624	2.40
397.1570435	0.59
405.0741577	9.86
407.1372070	36.87
409.2131348	0.76
412.1203613	0.31
413.1085815	9.40
415.0637207	3.26
417.3505859	0.65
421.3640747	0.32
423.1017456	7.11
425.1135864	22.20
426.2960815	0.11
428.9790039	1.84
431.5131836	0.69
433.2142334	1.68
435.2211304	1.73
436.9047852	0.92
440.9316406	0.96
447.1328125	1.50
449.1101685	19.98
451.1350098	19.44
454.9959106	0.12
457.3238525	0.58
461.1406250	0.58
465.2122803	0.41
467.1192017	0.89
477.1588135	0.59
489.2960815	0.31
491.0513916	0.22
493.0393066	0.40
497.5693359	0.19
498.4151001	0.27
499.3517456	0.98
505.2556763	0.08
509.4958496	1.32
510.1790161	0.47
515.2884521	1.13
517.2464600	1.51
519.3289795	0.60
525.1204834	4.38
527.3038940	6.98
528.1840210	0.12
531.0223389	0.70
533.1579590	7.36
535.2775269	0.91
540.1121826	0.13
541.3630371	0.33
543.2062378	24.07
545.3325806	0.88
548.2080078	0.20
557.2113647	4.43
558.2739868	0.37
559.1237793	8.65
561.0577393	11.49
562.7023926	0.34
569.1013184	7.19
571.0994263	1.75
575.1030273	33.12
577.1812134	49.66
578.4100952	0.34
584.8052368	0.61
585.4498291	0.22
587.0336914	26.10
591.1095581	0.21
593.1890869	1.32
596.0844116	0.69
598.3052368	0.21
605.3508911	0.11
612.4707642	0.16
613.3511963	0.74
616.2317505	0.42
617.3062134	0.58
619.1193237	3.07
629.1270142	0.81
630.4179688	0.78
633.2694702	0.08
637.0719604	0.26
641.5432739	1.86
651.4503174	0.29
659.0427246	0.49
667.1399536	0.41
669.0167847	0.98
669.7228394	0.49
677.2442017	6.17
683.5249634	0.53
685.3104858	0.49
689.3029175	0.21
695.0967407	100.00
697.1553955	0.76
702.7399292	3.57
703.3611450	33.76
704.2327271	9.03
711.0027466	0.31
713.1572266	42.03
714.2763062	0.31
721.0369263	1.41
725.5245972	1.32
727.5059204	0.22
728.7034302	0.56
737.0761719	1.33
739.1078491	46.78
739.9502563	0.47
747.3865356	0.28
750.1792603	0.55
755.0249023	0.15
757.5541382	0.60
759.1783447	0.42
772.0812988	0.34
777.5428467	0.19
784.9977417	0.16
801.8438721	0.24
803.2879028	0.97
805.4425659	0.90
819.3403320	0.42
821.0961304	0.70
829.0613403	0.52
839.0426636	0.98
843.5598755	1.32
847.1832275	42.54
848.3229980	2.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.2969
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1927795	0.03
208.1719360	0.16
223.1136627	4.07
225.1828918	0.06
245.3886414	0.04
251.0679321	0.09
256.0982056	0.04
260.9235229	0.17
265.1735229	0.15
266.1588745	0.16
273.1147461	0.04
287.1109314	0.16
289.2851868	0.04
295.3823242	0.06
302.2521973	0.03
311.4486694	0.07
313.2393799	0.16
319.2372437	0.82
320.3484497	0.07
323.1423950	0.22
327.1852112	0.03
329.2346802	0.16
333.3639221	0.05
334.4251099	0.03
335.3937378	0.08
336.2756958	0.40
337.2891235	0.27
339.2935791	0.03
355.0837402	0.95
355.8712769	0.20
363.5071411	0.03
369.0216675	0.14
374.1641846	0.08
392.1950073	0.10
397.3444214	0.06
403.1535034	1.05
404.2122803	0.13
423.3011475	0.05
425.1832886	0.06
430.2412109	0.23
431.3040771	0.05
433.2698975	0.04
434.3086548	0.09
437.2520142	0.04
449.0297241	0.25
451.0552368	1.26
460.3568726	0.30
462.3275146	0.08
470.5371704	0.21
474.4709473	0.11
486.2244263	0.31
487.3291626	0.17
495.0305176	0.07
497.2755127	0.05
499.8005371	0.05
503.2165527	1.02
507.0740356	0.06
510.4818115	0.09
512.4691162	0.16
513.5610352	0.07
514.1979370	0.15
521.5759277	0.03
523.3330688	0.20
524.4407349	0.10
525.4575806	0.10
531.3442993	0.61
537.3524170	0.03
539.3335571	0.85
543.0827026	0.13
549.0856323	0.09
553.8709106	0.07
557.4259644	1.25
558.2824097	0.05
562.8795776	0.20
563.4926758	0.08
565.5387573	0.03
571.3865356	0.21
575.2599487	0.16
581.3779907	0.59
583.3290405	0.58
587.2533569	0.06
597.0763550	0.17
599.2943115	52.17
600.1080933	0.06
601.4436646	0.11
602.3455200	0.46
604.9506836	0.04
610.2846680	0.04
613.3244019	0.21
615.2888794	0.28
617.5812378	0.03
620.5752563	0.09
625.6146240	0.56
627.3186035	0.99
629.2115479	0.20
631.3424683	2.39
635.8522339	0.04
639.0258179	0.46
643.2184448	100.00
643.8461304	0.66
645.5680542	0.04
647.3886719	0.24
651.4651489	0.42
652.6672363	0.23
653.6721191	0.08
657.2239380	1.30
659.2299805	0.05
695.0714722	0.07
941.4683228	0.57
942.4529419	0.48
969.3806763	0.17
984.2809448	0.30
1046.8139650	0.05
1092.5375980	0.15
1093.3122560	0.03
1126.4781490	0.06
1127.3824460	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1085
Annotation	Unknow
Peak:m/z	Relative Intensity
118.8514557	0.98
120.0235825	0.05
122.9131622	0.07
129.8817291	0.24
134.1076050	0.15
135.9953461	1.25
137.1523132	0.23
155.8868256	0.05
157.0216980	0.14
169.1623230	0.04
177.2829590	0.07
182.9247589	0.05
187.0030975	0.05
198.0472870	0.04
200.2392731	0.08
201.0990448	0.46
202.1037292	0.48
203.2387238	0.92
204.9424744	0.10
207.0587463	0.04
207.9531555	0.33
218.2435608	0.15
219.4255676	0.96
220.1904602	1.36
220.9035187	0.09
225.0465393	0.17
227.6890564	0.12
229.1001282	0.89
230.1365967	0.05
231.4075623	0.07
232.2813721	0.06
235.9957886	64.22
238.8009949	0.06
245.8412781	0.02
247.1220093	16.30
248.3226929	0.05
249.0391541	0.04
251.3075256	0.18
253.0799255	100.00
261.3024902	0.09
263.9751892	0.05
266.1214600	0.55
272.4774780	0.32
274.4570618	0.05
277.2129517	0.14
279.5442810	0.22
284.3675537	0.09
293.1923218	0.14
294.1520081	0.13
295.1210022	0.14
300.3835754	0.14
301.8162231	0.18
304.1626587	0.04
306.1047363	0.03
308.9323730	0.05
310.1983032	0.06
310.9376221	0.06
314.8932495	0.02
316.0704041	0.42
317.6832886	0.07
318.5189209	0.16
319.1414795	0.19
328.2708130	0.55
334.1916809	0.31
336.1252441	2.09
337.1999512	0.05
338.2487183	0.05
340.9522705	0.17
342.0074463	0.12
346.0915527	3.14
350.2995911	0.04
358.7708130	0.14
364.1273804	17.40
365.1740417	0.63
373.3538818	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
125.2410126	0.01
127.0188675	0.06
138.9604645	0.04
152.1107178	0.01
159.047348	0.02
161.1542358	0.01
181.1205139	0.06
186.9854431	0.08
193.397049	0.05
196.8697662	0.02
199.3048706	0.02
204.8033447	0.03
222.7538147	0.02
227.1021881	0.05
229.0174866	0.16
235.3120117	0.03
241.2861023	0.05
242.9520569	0.04
247.2495728	0.01
253.2456055	0.01
255.1180115	0.15
267.1537476	0.07
269.0655212	0.13
271.0631409	100.00
271.9074097	0.30
276.9970093	0.02
281.2468262	0.02
285.1222534	0.07
289.147644	0.56
300.088623	0.02
300.8111572	0.03
301.664032	0.02
303.8987427	0.03
309.0180054	0.01
312.851593	0.01
313.5255737	0.02
318.1307068	0.03
331.1884155	0.03
343.1686096	0.01
370.2596741	0.07
371.297699	0.07
387.0656128	0.04
388.1670227	0.05
389.1808777	0.06
396.9472656	0.04
403.2061768	0.05
404.912384	0.01
415.162384	0.18
417.4867249	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1404
Annotation	Gerfelin
Peak:m/z	Relative Intensity
157.9864655	0.05
158.9524841	0.10
161.1163635	0.50
162.1820679	0.04
165.0440369	0.12
173.0747375	0.07
175.1449890	0.21
177.9920502	0.02
180.1663666	0.03
186.9923859	0.03
191.1261597	0.05
192.9730835	0.57
198.0856018	0.06
203.0459137	0.13
215.9127502	0.02
217.2452850	0.54
229.2258301	0.37
242.3613281	0.38
243.0934601	1.66
244.9671783	1.29
252.9344788	0.12
253.6000977	0.08
255.0555725	2.09
257.2720642	0.46
259.0701904	0.06
261.0478516	0.28
268.9356079	0.09
270.1328125	0.06
271.1821594	1.08
272.1787720	0.08
273.0693359	6.56
281.1533813	0.09
282.9715576	0.19
285.1466675	0.16
287.1367188	8.68
289.0516968	4.06
296.1387329	0.11
297.1687012	0.04
299.1522217	7.94
309.2871704	0.10
311.0169067	0.07
312.0004883	0.07
313.2307739	0.22
314.8187866	0.33
320.9546509	0.09
323.0042725	0.53
324.1336060	0.06
325.3514404	0.05
327.3355713	0.03
329.1457520	0.29
333.1345825	0.06
337.0471191	0.06
339.4381714	0.10
341.2696533	0.08
354.9628296	0.04
361.6466064	0.12
363.2345581	0.56
365.1408691	0.06
367.1848755	1.56
368.9215698	0.33
371.1888428	0.10
377.2580566	0.06
381.1942139	1.40
389.1645508	0.06
391.1126709	37.41
393.2891846	0.27
395.1010132	0.24
397.3834229	0.13
407.1085205	3.25
409.1008301	100.00
411.2100830	0.09
413.2096558	1.27
415.7766724	0.11
416.6967773	0.16
417.4100952	0.18
420.9987183	0.08
422.9343262	0.15
425.2107544	11.06
431.8040161	0.02
433.0349731	0.17
435.0700684	26.09
436.0208130	0.09
441.3441772	0.07
449.1915894	0.08
451.1732788	1.21
468.9849243	0.04
473.1833496	0.05
475.5029297	0.08
480.1414185	0.13
484.2882080	0.10
488.4718018	0.06
499.0670776	0.10
501.2782593	0.04
502.3591309	0.05
512.2297363	0.04
514.3751831	0.28
516.5494995	0.43
517.2946167	0.47
518.9546509	0.03
532.4570312	0.10
533.4047852	0.07
542.2648926	0.16
543.2390137	2.75
544.0819092	0.10
561.4087524	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	687.2866
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1412354	0.32
200.8864594	0.05
203.3451538	0.13
207.0046387	0.06
212.1732025	0.04
215.3102417	0.02
217.0212402	0.23
229.3022156	0.05
230.3071594	0.06
231.4341431	0.02
235.0315247	0.11
241.2668915	0.02
242.2445068	0.08
243.5090942	0.02
244.5419617	0.05
245.2525330	0.23
247.2913971	0.06
255.1748352	0.06
257.2776489	0.04
259.4009705	0.06
267.5296631	0.03
269.2504883	0.35
271.2673950	0.04
273.1887207	0.16
285.2832336	0.66
287.2791443	0.56
288.3928833	0.03
289.3544006	0.17
301.5836182	0.05
303.2610474	0.61
305.3046875	0.07
306.1319885	0.03
313.3630676	0.03
320.2351685	0.04
328.3903198	0.08
331.2197876	0.70
337.1773682	4.99
339.3674316	0.03
340.9753418	0.03
343.3627930	0.14
344.1317749	0.07
345.3468323	0.04
347.3245850	1.57
349.2353516	100.00
349.8398438	0.15
352.8170776	0.04
355.1039429	5.06
361.3970337	0.11
362.2734375	0.22
363.3125610	0.06
367.1797485	0.06
372.4535522	0.01
387.5039673	0.07
391.1613770	0.04
393.1955566	0.02
400.3737183	0.01
410.4853516	0.04
421.1862183	0.07
429.1004639	0.01
434.9777222	0.03
465.2424316	0.02
473.1228027	0.02
509.4261475	0.03
510.4135132	0.03
511.1232300	0.03
512.4041748	0.03
523.4026489	0.04
524.3012085	0.02
525.3049316	0.38
542.4057007	0.06
557.0382690	0.01
593.1296997	0.03
624.2992554	0.03
626.6627197	0.15
639.5052490	0.03
640.8978882	0.09
643.3298950	0.85
651.0095215	0.03
669.0817261	0.36
670.2949829	0.02
672.7422485	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	567.1619
Annotation	Jamaicamide A
Peak:m/z	Relative Intensity
166.3288574	0.02
173.0235291	0.17
174.1319733	0.04
176.1541290	0.03
188.0433960	0.01
193.2092133	0.04
193.9003601	0.02
196.9155579	0.04
202.0805969	0.58
209.1456146	0.07
210.7398987	0.05
215.2539368	0.07
219.8244171	0.02
225.1703186	0.11
229.2440491	0.03
231.2104797	0.04
247.3173523	0.28
248.1710358	1.46
249.2351685	0.02
265.1417542	100.00
265.9469910	0.02
271.1182556	1.24
272.1809692	1.09
273.1772766	1.06
277.0728760	0.43
281.0663147	0.13
283.3244019	0.11
291.4186401	0.06
297.0983276	0.09
303.1784058	4.94
322.3858643	0.03
324.3728027	0.07
327.0168457	0.06
341.8923340	0.02
358.9913940	0.06
364.3283691	0.03
399.2623901	0.05
404.4880371	0.06
405.4555054	0.19
419.2897339	0.02
421.4680786	0.02
425.2515259	0.08
431.4442749	0.10
432.9912109	0.12
435.1753540	0.19
437.1561279	0.49
439.1119995	0.08
449.1740112	0.06
457.3327637	0.06
458.8715210	0.10
475.3081055	0.05
476.6175537	0.08
490.2268677	0.06
491.2691040	0.09
495.0482788	0.02
507.2451782	0.06
513.3690796	0.05
523.2957764	0.10
526.1947632	0.19
547.9766846	0.15
549.2067871	0.39
557.9020996	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	650.3294
Annotation	Unknow
Peak:m/z	Relative Intensity
192.9652710	0.31
200.8562775	0.10
211.1635742	0.16
212.9767456	0.03
216.7091980	0.11
221.2505646	0.03
226.3560638	0.09
238.9958649	0.08
249.1642609	0.08
257.1434631	0.05
259.0305786	0.13
260.1202087	0.02
261.1200562	0.07
267.0610046	0.06
275.2006531	0.27
281.3414307	0.09
287.0950317	0.04
288.1390381	0.03
291.1885376	0.38
293.2295227	1.84
299.2508850	0.06
302.3673706	0.19
309.3527527	0.21
310.8863525	0.19
322.0505371	0.10
324.3486938	0.10
325.2334900	0.12
329.1525879	0.15
343.2869263	0.15
343.9633789	0.06
357.0447388	0.12
360.1579590	0.10
362.3608398	0.05
369.0789795	0.40
383.3090210	0.07
386.2696533	2.07
387.3255615	0.65
396.5325928	0.12
397.1697998	0.06
400.7895508	0.20
403.8677368	0.05
404.5325928	0.06
406.7963867	0.12
414.4586792	0.08
423.2667847	0.10
427.1467285	0.03
450.4152222	0.14
467.2469482	0.09
468.2318115	0.82
472.8821411	0.14
480.3436279	0.03
485.5790405	0.63
486.2309570	2.90
498.2679443	0.09
503.2531128	100.00
504.1644897	0.31
521.2296753	41.73
521.8577271	0.34
526.6876831	0.23
543.2180786	0.79
546.1901245	0.23
561.3624268	1.18
578.3191528	0.09
596.1978760	0.19
597.0400391	0.16
604.0598755	0.06
606.5444946	0.03
614.3973389	0.88
615.3816528	0.04
632.2594604	32.98
633.1849976	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2783
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.1068726	0.03
153.0965881	0.06
196.1679077	0.18
205.3880920	0.02
214.1503296	1.24
261.3255920	0.14
279.2704163	100.00
462.3705750	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	695.4015
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1951599	0.03
203.1701202	0.07
205.2995911	0.03
206.2193146	0.06
207.1147308	0.04
209.1536713	0.06
211.0740051	0.12
214.2357941	0.05
219.4073639	0.07
221.0554810	0.26
223.1402435	3.99
225.1275330	0.05
233.0656281	0.04
235.0994263	0.06
239.9367371	0.03
240.9578857	0.03
243.0102539	0.02
251.1781616	3.00
253.2737579	0.04
256.1832886	0.08
261.3279724	0.11
261.9833679	0.06
263.0386353	0.05
267.2681885	0.05
273.3397827	0.06
275.5286255	0.02
279.1929932	0.09
280.1727905	0.05
281.0909424	0.10
289.1170044	0.05
290.7084351	0.26
291.3961487	0.10
296.2554321	0.10
300.9698486	0.17
313.2740479	0.29
331.2321472	3.72
335.0921631	0.10
340.4705811	0.06
346.5377197	0.05
348.1554871	0.25
349.3162842	1.97
367.1757202	100.00
367.9209595	0.31
368.9517822	0.03
369.7260132	0.08
371.5223999	0.07
379.0399170	0.02
382.9599609	0.10
384.3348389	0.11
389.1942139	0.04
393.2933960	0.03
405.5892334	0.11
406.5165405	0.13
410.5390015	0.02
417.2600098	0.06
424.9353638	0.09
443.0899658	0.02
447.0238647	0.09
468.4730835	0.01
473.2971191	0.07
500.3870239	0.05
503.6296997	0.03
507.6464233	0.04
518.5341187	0.03
521.3217773	0.14
525.3380737	0.02
530.2979126	0.03
532.8571777	0.11
536.6576538	0.11
543.3239136	0.09
554.4910278	0.08
577.5274048	0.04
585.1521606	0.10
612.8336182	0.10
615.9309082	0.02
619.1026001	0.06
623.2973633	0.02
625.5503540	0.03
628.4176025	0.11
636.5057983	0.07
637.3040771	0.04
640.9807739	0.09
659.3683472	0.28
663.5477295	0.13
677.3829956	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	598.2192
Annotation	Unknow
Peak:m/z	Relative Intensity
180.9767761	0.51
205.1337280	0.18
227.0652771	0.09
230.9963989	0.31
268.1273193	0.07
270.2838745	0.08
271.2125549	0.71
272.1882324	0.63
273.1241455	1.02
295.2193604	0.38
302.2730713	0.04
322.1029053	1.36
339.1441650	100.00
339.7526855	0.20
349.0249023	0.25
352.1084595	0.09
361.4990845	0.11
362.3883667	0.14
363.5184937	0.07
379.1621704	0.97
380.2568359	0.03
391.2182617	0.05
404.1420898	0.07
433.1789551	0.23
434.1721802	0.38
435.4238281	0.88
436.3013306	1.88
438.8082275	0.52
447.3758545	0.08
450.2344360	5.38
451.1993408	5.19
468.1481934	65.95
469.2963867	8.99
509.3068848	1.37
510.0332642	0.10
541.8504028	0.14
553.1225586	0.09
562.4961548	0.39
580.3370972	9.32
581.3737183	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.01
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8344879	0.08
195.3942108	0.11
196.1416321	0.04
209.0939484	0.02
213.1162567	0.38
218.1769562	0.01
231.9695435	100.00
232.8421021	0.14
247.3303223	0.02
250.9945374	30.57
251.8549194	0.02
269.9840698	0.02
312.5065613	0.04
315.1396484	0.04
323.9015503	0.04
338.8257141	0.08
340.8862915	0.10
360.8091431	0.03
365.2272644	0.03
379.0902405	0.24
408.4690247	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.3687
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0716095	0.28
200.9593506	0.05
211.1862335	0.11
219.1256561	0.18
220.1445618	0.16
221.1795502	0.24
223.0350647	0.34
225.1623230	0.07
227.0101624	0.10
229.1396179	0.17
232.5643616	0.12
236.0868225	0.06
237.0095978	0.73
237.9453125	0.10
238.9992676	2.38
245.4367218	0.11
246.0742493	0.28
247.0231018	0.10
249.1678467	0.58
249.9375458	0.14
251.3670807	0.33
252.0763550	0.15
253.0899048	0.07
254.8616028	0.22
260.1352539	0.07
261.0731201	0.08
265.1514893	0.93
267.0501099	22.51
268.0032959	1.11
269.0526123	0.46
275.1782227	0.11
277.1759644	0.48
279.2997437	0.55
287.2592468	0.54
288.9200439	0.11
290.1207886	0.19
294.3745728	0.10
295.2936096	0.60
297.0226746	0.69
301.0690002	0.17
305.3396606	0.08
307.0985107	1.17
307.9999084	0.33
311.0900269	0.10
314.7398682	0.13
319.8865356	0.09
325.1562500	0.43
327.1896362	0.21
329.3099060	0.56
335.0518799	0.09
338.3866577	0.17
343.2026978	0.04
345.2231445	0.68
347.1732178	17.11
348.2047729	0.44
364.0709229	1.14
365.1560669	13.78
366.1942139	0.70
367.2349854	1.60
370.1019897	0.14
383.0673828	100.00
384.1380615	12.02
384.7810669	0.05
385.3907471	0.56
387.8353271	0.08
396.0549927	0.07
400.4282227	0.15
401.4500122	0.13
406.0657959	0.17
407.2606201	0.07
414.1253662	0.07
427.0301514	0.07
437.0895996	0.12
439.0687866	0.20
443.8204346	0.08
450.0249634	0.61
453.0816040	0.36
453.9346313	0.25
463.0096436	0.15
471.4647217	0.19
476.0245972	0.26
478.3208008	0.46
479.4114990	1.06
480.1770020	0.97
487.6848145	0.37
493.1935425	0.55
505.5559692	0.14
506.3059082	0.12
507.2285156	0.34
509.1126709	0.24
518.2020264	0.39
519.5562134	0.37
522.1276245	0.17
524.7509766	0.28
532.4013062	0.15
540.7103882	0.35
542.4776001	0.37
543.2007446	0.62
545.4555054	0.19
553.5874634	0.63
554.6896973	0.20
557.0372314	0.06
559.2284546	0.64
560.3209229	0.95
563.4782104	0.08
565.1215210	0.14
566.9856567	0.26
569.0548096	0.63
570.1321411	0.50
577.0347290	1.10
578.1987915	0.87
578.9939575	0.08
580.4279175	0.45
594.0311890	1.28
595.1666260	8.06
596.0160522	15.94
598.3532104	0.29
599.4449463	0.04
601.6497192	0.18
607.0983276	0.33
607.8416138	0.10
613.3358154	0.32
616.0056763	0.16
617.5320435	0.25
626.1203003	0.75
630.1411133	0.68
634.7266235	0.87
643.3947144	0.12
652.5329590	0.19
657.5106812	0.93
659.4091187	0.07
665.5456543	0.12
675.2105103	5.08
689.0392456	0.13
692.0216675	0.18
693.2055664	7.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1563
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
178.9594727	0.06
184.9000549	0.09
187.0970154	0.03
188.0412598	0.05
198.2569427	0.01
199.0334625	0.07
200.0131226	0.04
201.0828552	0.05
211.2571716	0.04
213.9939880	0.06
215.1336975	0.07
216.1553955	0.05
226.2213440	0.06
230.2411041	0.11
240.2069702	0.06
241.0864868	0.11
242.0951843	0.48
251.1567841	0.29
257.0024414	0.09
259.4909668	0.02
271.1378174	0.02
282.9069519	0.06
285.0238037	0.06
286.2028198	0.38
287.1733398	1.23
301.0842285	100.00
301.9300537	0.03
303.0128784	0.02
325.4084473	0.11
330.9097900	0.02
337.1914673	1.33
338.3434448	0.02
343.1028442	0.35
355.1939087	0.06
373.0896606	0.25
374.1757812	0.10
385.2679443	0.03
413.1505737	0.01
426.8511963	0.03
431.4097290	0.07
435.1006470	0.07
443.3105469	0.09
462.4816284	0.04
463.2970581	0.10
489.2338257	0.02
495.3894043	0.11
501.4690552	0.12
503.3000488	0.09
519.2156372	0.14
523.5597534	0.02
537.4285278	0.05
549.6520386	0.04
557.6590576	0.14
563.0755005	0.13
577.2302856	0.14
589.0836182	0.03
591.3353271	0.07
595.2621460	0.22
602.0951538	0.03
603.5167847	0.04
607.1425781	0.71
621.2945557	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8401489	0.51
208.8966522	0.55
290.7493896	5.54
292.8234863	7.72
373.2281494	0.07
374.6657715	2.58
376.5763550	5.86
456.1085815	0.08
458.5444946	14.68
460.5374146	100.00
461.2506104	0.08
491.5164185	0.07
497.7225952	0.04
498.9776001	0.07
527.4271240	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0855
Annotation	Gerfelin
Peak:m/z	Relative Intensity
95.0360413	0.09
104.9611359	0.28
110.7112732	0.04
118.9837494	0.09
120.8564224	0.07
123.0036011	100.00
125.1655350	0.12
127.0845413	0.06
135.2841034	0.06
136.0168762	0.06
137.1013184	0.82
139.0000305	96.41
147.0269928	6.42
150.9350433	26.11
153.1034851	0.30
160.9796753	0.05
162.9050751	0.28
164.9763489	41.45
168.9890747	2.35
178.8059692	0.04
181.0833130	0.41
205.0905762	0.14
220.1801758	0.09
231.2512817	0.22
243.2925110	0.13
249.1864929	0.80
249.9483032	0.15
254.8481750	0.30
273.0579834	18.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8255768	2.57
296.6700439	20.74
297.3365479	0.07
323.1066895	0.05
378.1033936	0.23
379.2471924	0.38
380.5765991	89.88
381.2643433	0.48
461.9518433	4.11
463.8392944	11.98
464.4765625	100.00
465.1701050	1.34
503.1590576	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.4874
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
241.0464478	9.36
243.2119293	0.14
259.1616821	2.47
275.3327637	0.08
276.2136230	0.22
277.3057251	55.55
278.3646545	0.44
297.0713196	10.74
298.1438599	0.11
306.1255493	0.25
309.3830566	0.10
315.2659912	2.68
333.0638733	0.26
342.4171753	0.69
413.2001953	59.28
413.9272461	0.44
431.2684937	1.17
435.1005859	0.09
477.1397095	0.38
501.3986206	0.47
519.1321411	1.77
575.2977905	100.00
576.4324341	1.30
593.3196411	19.19
594.2940063	0.36
691.3231812	1.46
705.3781738	0.19
718.6382446	0.33
733.5678711	0.07
745.6074219	0.21
792.5841675	0.17
807.3971558	0.13
809.1432495	0.66
818.9148560	0.11
835.1778564	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1782
Annotation	Afzelechin(4alpha->8)pelargonidin 3-O-beta-glucopyranoside
Peak:m/z	Relative Intensity
203.1133575	0.02
271.1354980	0.25
283.1606445	0.13
284.1250000	0.13
285.2178650	0.05
311.3369141	0.01
313.1556091	2.35
331.2022705	0.11
336.9854126	0.01
350.0207520	0.06
350.9784546	0.01
375.2549438	0.03
389.3533325	0.13
407.2053223	2.56
415.4202271	0.02
417.2357788	0.23
419.2642212	0.03
429.0285034	0.06
433.1986084	0.22
446.2723389	0.03
453.0701294	0.07
454.4031982	0.05
463.2359619	0.04
472.1954346	0.03
475.1683960	0.29
525.1706543	2.47
535.2854614	0.01
536.8240356	0.03
540.1953735	0.02
543.1564331	100.00
543.7590332	0.41
544.4003296	0.04
550.1257935	0.02
551.3568726	0.01
553.2011108	0.08
553.9382935	0.11
569.0446777	0.12
571.5903931	0.03
575.9346313	0.01
579.0305786	0.09
590.1466675	0.05
639.4017334	0.03
661.7997437	0.02
674.5335083	0.18
687.1077271	0.59
688.2075806	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.2763
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
163.1946564	0.09
165.1925964	0.16
167.2495270	0.09
169.2299194	0.11
171.1822205	0.20
173.1110229	1.42
175.1633301	0.80
177.0453033	0.39
179.2204895	0.22
183.2008057	0.09
185.1709137	0.45
187.1490479	1.05
189.0480499	0.22
191.0046539	0.47
193.0632172	0.07
199.2470398	0.39
201.1519775	0.82
204.9251556	0.07
207.2536316	0.07
208.4994965	0.06
211.0844269	0.17
213.3180542	0.33
215.1652069	1.00
217.3402863	0.04
219.2609558	0.30
225.0717316	0.43
227.1678619	0.24
233.2114105	0.18
235.1722717	0.06
237.1287994	0.07
239.2881775	0.40
241.1002350	0.17
243.2179260	15.84
244.8478088	0.63
245.5693665	0.10
247.0024414	0.05
249.3043518	0.19
250.9694366	0.23
253.2485199	0.03
255.3933411	0.16
257.1646118	0.20
259.4312744	0.25
261.2810059	13.60
263.4551392	0.13
265.2260132	0.09
271.3583984	0.46
275.2110596	0.75
277.1161499	1.33
279.2086792	1.43
281.2529602	0.82
285.2849121	0.11
286.9501343	0.06
290.2160339	0.04
291.4810181	0.75
293.0219421	0.26
296.9328613	0.36
299.1775818	4.34
303.4815674	0.09
305.9595032	0.12
310.1073914	0.03
311.3197632	0.03
315.1508179	0.40
317.1939087	25.62
317.9213257	0.03
320.9100952	0.05
327.2553711	0.06
331.2341309	0.05
333.0220337	0.31
335.2715454	100.00
336.0756836	0.17
337.3309937	0.63
345.4160156	0.06
347.0269165	0.07
349.3981934	0.13
353.3610840	0.35
361.1967163	0.14
387.2348022	0.06
389.2859497	0.15
395.2149658	0.14
405.4467163	1.00
410.7169189	0.13
415.3076172	14.90
423.3925781	3.16
428.1355591	0.04
433.3027344	0.04
434.7382202	0.28
435.4663086	0.23
436.9093018	0.16
437.5149536	0.15
441.0894165	0.04
443.2631836	0.05
451.2144165	0.15
453.3655396	0.13
455.4165039	0.02
461.3642578	0.04
465.5297852	0.11
467.1234131	0.06
469.4878540	0.45
475.3290405	0.06
479.1749268	0.20
482.9448242	0.14
485.2691650	0.11
487.3267822	0.09
488.5402832	0.18
489.3457031	0.08
494.7748413	0.12
503.3258667	1.04
505.5395508	0.05
507.0428467	0.79
512.8661499	0.10
515.1619263	0.17
517.5079956	0.10
520.4008179	0.08
521.2582397	0.42
523.4077759	0.15
531.1834717	1.32
541.5421753	0.31
545.2387085	0.06
549.6658325	0.23
559.1979370	59.40
559.9259644	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1528
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
162.9937897	0.39
165.0615540	2.93
168.8359985	0.39
171.1072998	0.16
179.0176697	0.60
180.9078217	0.16
184.9464111	0.58
187.2956543	0.65
188.1982727	0.33
188.9203796	1.00
191.1236267	0.37
197.2257385	0.14
197.9296570	0.86
199.2470245	0.26
200.9649200	0.18
203.1604767	0.25
207.0050354	0.23
213.1775208	1.89
215.2800293	0.76
215.9333801	0.12
217.1857605	0.16
225.9253540	0.09
227.0442505	1.66
231.0626831	45.65
233.0983887	0.28
243.0823517	6.82
244.2036896	1.86
245.1051941	1.02
247.0022888	0.61
248.6345520	0.38
253.1843872	0.10
255.1276703	6.09
256.5588684	0.38
257.1727600	0.79
259.0338440	0.11
260.0454102	0.12
261.1302490	31.32
263.0006104	0.10
267.0847168	2.72
269.0859375	1.32
271.2951050	0.24
273.1174316	49.28
275.0973511	14.34
282.6932983	0.26
285.1608276	27.92
287.0464478	5.68
289.1394653	1.14
291.1449585	93.31
297.0686951	0.67
297.8911743	0.08
299.0177612	1.86
300.9987488	1.20
303.2060547	7.79
307.1276855	0.23
308.2840576	0.24
309.2501831	0.15
311.3424072	0.25
315.3117676	0.78
316.0543823	0.15
321.3830566	0.49
325.2695312	0.18
331.2820435	0.18
333.3834229	1.40
337.0425415	0.14
339.0382080	0.56
349.3751221	0.09
351.2610474	1.14
353.0263672	0.24
354.0629883	0.30
358.5143433	0.39
365.1511841	2.45
367.2666016	0.15
369.3399048	0.42
370.9317627	0.38
377.1810303	1.17
383.2023315	23.93
385.1082153	0.60
387.3129272	0.25
391.1708984	1.14
393.0939331	68.14
393.7459717	0.13
395.1343384	22.60
396.9590454	0.78
398.1714478	0.30
401.0527344	0.24
403.2186279	0.56
405.1260986	4.92
407.1886597	1.60
409.2053833	16.59
411.0415039	100.00
412.3657227	0.43
413.4446411	0.15
416.2506104	0.54
419.0978394	6.95
421.0772705	0.15
423.0261230	6.25
425.1642456	0.45
427.1464844	39.40
432.6660767	0.36
436.3927002	1.60
437.1540527	12.19
439.1828613	2.82
440.1044922	0.14
441.0693970	0.13
451.2310791	0.21
481.5820312	1.12
487.2351685	0.14
495.3801880	0.26
497.1572266	0.50
499.1083984	0.54
500.3926392	0.19
506.2307739	0.39
509.1209106	0.16
514.9590454	0.30
517.1986694	0.39
521.2845459	0.11
524.0548096	0.55
527.1648560	6.72
533.2785034	0.07
535.4335938	0.33
545.1221924	35.06
545.8375854	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1645
Annotation	Indole-3-carboxylic acid beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
121.1005020	0.01
125.9474182	0.13
127.0748062	0.06
145.0964966	0.10
149.3727570	0.01
151.0515747	0.04
152.1002197	0.02
163.0938416	0.01
168.0463562	0.01
169.0487671	0.01
169.9246674	0.02
171.2670746	0.01
172.9126892	0.03
177.0463257	0.92
184.1253357	0.03
189.0377197	0.21
191.9894409	0.71
194.0010681	0.03
196.9403992	0.03
198.0883789	0.25
203.8818359	0.02
204.8690796	0.03
207.0529633	0.55
210.1230621	0.13
220.0909424	2.45
221.1040344	0.03
222.0206909	0.05
229.3894348	0.06
238.0498962	100.00
239.0068970	0.33
244.1499023	0.22
249.0969543	0.02
256.0836182	7.92
256.9138489	0.05
262.8894043	0.01
267.0115662	0.47
268.9701843	0.02
277.9590454	0.01
281.0360413	0.04
285.3776245	0.03
287.0809021	0.04
289.3458862	0.01
312.8926697	0.01
323.3057251	0.12
325.1716309	0.04
327.1079102	0.20
328.3760986	0.03
333.2327271	0.08
345.9546509	0.05
351.2711182	3.24
352.1298523	0.04
360.4071655	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1353
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1269531	0.11
164.2760620	0.04
165.0783997	0.25
167.1295624	0.09
173.1128845	0.10
175.0608673	0.04
177.0832214	0.07
178.9920959	0.02
186.5843506	0.11
187.2094116	0.08
188.2358551	0.03
189.0415344	0.03
191.1721344	0.04
201.3310242	0.05
203.1741638	0.23
205.1357117	0.06
213.0024109	0.10
214.8877258	0.09
216.9864349	0.17
229.0753784	0.34
239.0363464	0.09
241.1706543	0.09
243.1474609	0.13
243.7766876	0.06
245.0441284	1.75
247.2867126	0.01
251.2072601	0.04
253.4032898	0.07
255.0420380	0.18
257.0369263	0.03
259.1857910	0.06
261.2010803	0.11
267.1708679	0.03
269.1710815	0.55
271.2826538	0.08
273.0748901	1.57
275.1719360	0.18
277.1882324	0.03
281.2552490	0.10
283.1093750	0.10
285.1005249	0.11
286.5130615	0.10
287.1945801	6.09
289.1259155	15.96
293.1973877	0.09
295.1562805	0.13
299.1082764	5.62
301.1646423	0.15
310.2675171	0.04
321.3317871	0.05
327.0401611	0.22
329.2476807	0.35
331.2233276	0.67
333.3841553	0.02
334.1707764	0.13
335.4627686	0.06
339.0189819	0.38
341.3062134	0.40
352.9895630	0.12
357.0934448	0.21
359.1265259	0.02
367.3314819	0.22
368.2912598	1.24
369.3410034	0.25
375.0682983	0.03
377.1259766	0.14
379.1395264	0.47
381.2568359	1.04
383.4088745	0.10
388.9701538	0.12
391.0554199	0.03
393.2781982	1.33
395.3800049	0.16
397.4583740	0.05
403.3975830	0.04
405.3485718	0.15
407.2026367	55.70
409.2230225	0.26
410.1785889	0.03
411.1942749	0.19
412.9683228	0.11
415.3073730	0.10
416.2388916	0.11
417.2332153	0.06
419.3142700	0.06
421.2036133	0.06
425.1303711	100.00
430.2326050	0.04
431.1790771	0.05
433.1180420	0.41
435.6047363	0.02
437.2568970	0.20
439.0614014	1.55
447.3812866	0.11
449.2609253	1.06
451.1879883	22.11
453.0466919	0.04
454.3031006	0.09
455.0518799	0.10
457.2410889	0.02
463.1817627	0.03
467.1788330	1.17
470.1961060	0.17
471.2571411	0.27
475.5699463	0.06
489.3372192	0.01
491.1881714	0.33
492.0612183	0.06
493.3165894	0.30
497.0704956	0.06
500.0891113	0.26
501.2180176	0.04
511.2176514	0.01
514.2128296	0.11
515.3220825	1.11
516.1848755	0.03
523.6916504	0.09
530.7877808	0.16
532.5644531	0.27
533.2107544	1.40
541.3269653	0.64
542.2128296	0.11
559.2453003	9.44
560.0736694	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.1777
Annotation	Unknow
Peak:m/z	Relative Intensity
232.2003784	0.01
239.0401611	0.01
245.1385498	0.04
249.2357483	0.04
257.1604309	0.02
272.8915405	0.04
275.9256287	0.04
282.1192932	0.04
289.1137390	0.30
305.2533569	0.08
313.2352295	0.36
323.1430054	0.18
324.3197021	0.07
328.8021851	0.04
340.9427795	0.10
355.1936646	0.03
374.0825806	0.69
375.1187134	0.85
376.2690430	0.08
377.2166138	0.05
386.2270508	0.03
431.2308960	0.06
433.9298706	0.24
434.9359741	0.07
449.1699219	0.01
451.3000488	0.90
472.1643677	0.07
474.2258301	0.12
475.2073975	0.12
493.2257690	11.84
539.1812134	0.02
554.9940796	0.02
595.0263062	0.09
608.8595581	0.05
613.2063599	0.15
635.0661621	0.12
655.2365723	100.00
656.1093750	0.04
681.1284180	0.22
682.4725952	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.2
Annotation	Sporotrichiol
Peak:m/z	Relative Intensity
104.9196472	0.07
107.1795197	0.09
109.0635681	0.76
110.8372650	0.02
118.8890076	0.15
121.0312805	0.17
122.9982910	8.05
127.0653763	0.10
129.1136322	0.18
131.0239868	0.13
133.0842896	0.36
133.9550781	0.03
134.8984985	0.08
136.9360809	0.56
139.0269470	0.08
143.1367340	0.31
145.0996857	0.22
146.1355286	0.04
146.9936676	0.06
149.0373688	0.75
150.9209595	0.44
155.0569153	0.19
156.9058228	0.52
159.1399231	0.06
161.0437927	0.06
163.1497498	0.12
164.9865417	0.96
166.0881042	0.05
167.1681976	0.32
169.0619812	7.95
171.2122803	0.13
173.0481262	0.12
175.1207123	0.14
177.0258331	0.16
178.9864197	0.84
181.0552979	0.03
183.1270294	0.40
184.6302948	0.13
187.1804352	0.27
188.9441833	1.21
191.0813599	0.31
193.1373291	0.99
195.0812683	1.20
197.2078857	0.10
199.2612000	0.64
201.0825500	0.34
205.0417328	0.41
207.0400085	28.00
209.0969543	0.92
211.2189026	0.19
212.8057251	0.22
214.1830444	0.03
215.1206970	0.43
217.0565186	0.15
219.1555176	0.36
221.1416321	0.43
223.1225586	0.40
225.2005005	0.69
227.2391052	0.05
229.1028442	0.33
231.3820496	0.02
233.0707397	0.62
235.1663208	0.28
237.1293640	0.25
239.1378784	2.42
241.1712036	1.08
243.1136475	0.62
245.2093201	1.29
246.2847290	0.06
247.2796936	0.54
249.2025757	1.06
251.2651367	0.19
253.2670288	0.25
255.0824585	0.67
257.1974487	3.22
259.0898132	0.36
261.1658020	5.48
263.2919922	0.36
264.8459778	0.03
267.2298584	8.36
269.2963562	0.60
271.1171265	0.68
273.2739258	1.20
275.2591553	1.31
277.2456970	0.41
283.1521912	0.21
285.2054749	27.90
286.3851013	0.02
287.2661743	0.28
288.3076782	0.06
289.2546692	0.32
291.1371460	0.04
295.2608032	2.66
299.3016357	0.22
300.0885620	0.17
301.1517944	1.19
303.1416626	40.82
303.9349060	0.18
305.2736816	0.95
305.8813477	0.02
307.3837280	0.15
309.2432556	0.03
313.2225952	25.11
314.2226562	0.11
316.9090881	0.04
319.0697021	0.20
321.2129822	0.21
328.7252502	0.12
331.1501160	100.00
331.8832397	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.2737
Annotation	Anandamide (18:3, n-6)
Peak:m/z	Relative Intensity
91.1927414	0.21
92.8845215	0.15
94.9084701	1.52
97.9742889	0.26
98.9976273	0.57
100.0292587	0.57
100.9938889	0.42
104.7936935	0.46
109.0129395	2.64
110.0128326	0.23
110.7012711	0.30
111.9555130	0.09
113.3007355	0.13
114.9900665	0.46
116.9574738	0.20
118.9841309	0.39
120.9288788	2.67
122.9616241	1.13
123.9248734	0.49
125.0481262	1.04
127.8773956	1.76
130.0469208	0.42
131.0389404	1.82
133.1217957	2.05
135.0113373	3.26
136.9818420	1.64
139.1487732	1.11
140.1368561	0.37
140.8615112	0.54
142.1586914	1.43
143.0717773	0.47
144.0154724	3.18
144.9586487	2.74
146.9937134	3.38
149.0375977	3.18
151.0164490	3.41
153.0549316	0.14
153.9876709	0.47
155.0108337	0.14
156.1053772	0.16
157.0599670	0.20
158.1324158	6.93
159.1058350	1.21
161.1824646	2.67
163.0874176	7.48
165.0691528	1.87
165.9841156	0.27
167.3908691	0.34
169.0244751	0.51
170.1341553	2.42
172.2638550	8.26
173.1326599	3.90
175.0511932	1.62
176.0077972	1.00
177.1605377	4.86
179.2265625	0.59
182.0152588	0.17
183.2688904	1.48
184.1273193	1.72
185.4466858	1.63
186.1646118	11.76
187.0615082	5.19
189.3355713	0.55
191.0519562	2.08
192.9675140	0.56
194.2196960	1.21
195.2156982	0.41
196.2765961	0.93
197.1014709	0.17
198.1567383	4.16
200.1338501	19.39
201.1314697	2.58
203.2713013	0.58
204.3768921	0.37
204.9887390	0.51
206.0563049	0.41
207.3182373	0.07
210.1939087	2.36
210.9419250	0.36
212.1091614	4.85
214.1046448	14.32
215.1232300	0.68
217.1980896	1.75
219.3143921	1.21
222.1291504	0.18
222.9148560	0.25
224.1592712	5.24
225.1837158	0.20
226.1263123	8.98
228.2940674	6.58
231.2940979	0.13
233.1681213	1.87
234.2425537	0.27
235.4956055	0.09
236.1961975	0.31
237.0139160	0.15
238.1945801	12.71
240.2512817	10.27
242.2918091	8.39
243.2203979	52.87
245.1220703	6.34
248.2123108	0.14
249.5257263	0.47
250.2340088	1.79
252.2416077	7.86
253.2337952	0.76
254.1143799	3.06
255.0167542	0.31
256.2673340	1.01
261.2441406	51.91
263.3078308	5.36
264.4462891	1.53
266.1721802	11.63
269.2066040	1.34
272.6593018	0.79
277.4215088	0.59
279.4296265	2.59
280.2704468	4.84
283.3121948	0.35
287.3588257	2.86
292.4493713	0.18
294.4960022	0.09
295.3738708	0.24
304.2994995	100.00
305.3716125	49.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.79
Annotation	Liothyronine
Peak:m/z	Relative Intensity
231.8103180	0.12
316.0275269	0.56
354.0075073	0.02
377.0057983	0.04
396.1292725	0.05
399.6937866	1.09
400.4412231	0.06
401.6553345	0.01
407.9401245	0.06
420.9974976	0.03
425.2158203	0.03
437.8289185	1.25
439.0226440	0.10
440.0593872	0.12
443.9730835	0.11
456.0506592	0.04
457.1968994	0.03
458.0762939	0.35
459.3119507	0.20
477.1114502	0.10
480.9070435	0.03
482.1527100	0.15
483.6790161	4.18
484.3032227	0.04
498.0449219	0.09
521.7077637	5.95
565.7201538	0.16
567.5989380	18.85
568.2617798	0.08
605.6513672	100.00
606.3394165	0.12
608.1889038	0.06
648.6392212	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2967
Annotation	Dicliripariside A
Peak:m/z	Relative Intensity
193.0751495	0.11
241.1429901	0.56
251.4704437	0.08
253.2510376	0.26
255.0937653	0.11
258.9517822	0.08
269.3010864	0.61
271.3423462	4.12
272.9624939	0.06
287.1400757	0.35
289.0764160	0.03
299.2124939	7.65
299.8563843	0.40
311.0154724	0.05
315.2948608	0.19
317.2396545	100.00
335.2741089	0.05
337.0830688	1.11
339.5433960	0.33
349.1604004	0.21
356.1875000	0.26
379.7149048	0.04
409.4100342	0.16
415.2745361	0.09
427.3526001	0.14
429.2255859	0.03
433.3890381	0.12
438.8541870	0.24
449.0552368	0.17
455.4653320	0.17
475.6961060	0.06
489.2667236	0.05
502.9933472	0.10
511.4405518	0.22
515.1116333	0.06
531.2849731	0.13
553.5079956	0.03
555.1901855	0.16
563.3158569	0.10
575.3670044	0.05
579.4716187	0.30
581.2882690	0.25
592.1934204	0.05
593.6220703	0.11
594.3538818	0.06
595.4927368	0.16
596.2645264	0.02
605.3078613	0.06
609.2858276	0.13
611.4278564	0.65
623.1209106	0.08
624.7769165	0.13
637.3804321	1.15
638.4135742	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.2124
Annotation	9,10-EpODE
Peak:m/z	Relative Intensity
93.1391144	0.03
97.0721512	0.01
109.3314667	0.01
113.0000610	0.06
121.1067276	0.70
124.9797211	0.45
127.3577271	0.01
137.0032654	0.07
141.1676941	0.18
149.0463409	0.28
151.1831360	0.12
155.1512451	0.05
159.2312317	0.05
163.2397156	0.11
165.1690979	0.13
167.2020569	0.14
169.3004761	0.06
171.1317139	22.95
177.1616821	0.61
179.1579895	0.04
183.0247650	0.12
185.1919250	5.71
190.8015594	0.10
195.3904266	0.11
197.1999512	2.30
199.1751099	0.02
203.2135010	0.04
205.1442871	0.06
207.0873718	0.07
209.2662964	0.86
211.2302246	0.74
213.1517029	0.06
217.3853149	0.02
219.1983032	0.71
221.2151794	0.68
223.1856384	0.32
231.3043213	1.92
233.0260010	0.09
235.2398376	8.47
237.2333069	0.24
242.9620361	0.02
245.3848572	0.06
247.3032837	0.04
249.3312988	1.28
249.9863281	0.02
251.1776733	0.10
255.3478394	0.03
257.3353882	0.28
263.4213867	0.07
265.3536987	0.71
273.4354248	0.02
275.2158813	100.00
275.8441772	0.11
277.3853149	0.04
293.3030701	0.02
294.4375610	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2235
Annotation	Icariside E7
Peak:m/z	Relative Intensity
172.1328125	0.06
175.8794250	0.67
189.0636597	0.08
190.0467834	0.06
191.1668396	1.10
193.8432922	0.12
205.1345978	0.59
207.0375977	0.82
208.2155609	0.05
209.0686646	0.24
218.8426819	0.03
223.1773071	0.54
225.4133148	0.13
233.2896729	0.08
234.8445740	0.13
236.0269165	0.18
241.0276184	0.47
250.0668488	0.24
251.1056671	0.21
264.9212036	0.99
269.1724854	0.08
277.2511902	0.27
278.3283081	0.15
281.1755981	0.51
295.3318787	0.23
299.1580200	0.19
301.3685303	0.24
305.1886597	0.06
311.1143799	0.86
313.1400452	0.04
315.0804443	0.43
325.0356445	0.31
327.3062744	0.03
333.1785278	0.03
347.0818481	0.09
357.5455322	0.14
358.1544800	0.12
362.1994019	0.12
367.4069824	0.06
369.2063599	1.50
371.1170654	0.18
385.1453857	0.27
387.2420654	100.00
388.1989746	0.26
392.4114990	0.14
393.2018433	0.09
399.2529297	0.11
402.0899658	0.20
405.1306763	0.03
413.2687988	0.34
414.9167480	0.03
421.2208862	0.03
427.2102051	0.07
431.3018188	0.27
447.1744995	0.26
449.2289429	0.98
450.3099365	0.06
474.8870850	0.13
479.2054443	0.29
483.2506714	0.05
491.1329956	0.09
493.2402344	0.49
497.1577759	0.16
501.2924194	0.05
502.1939087	0.17
503.0803223	0.07
505.1635742	0.22
508.3591919	0.19
519.2515869	10.26
520.1511841	0.30
524.8928833	0.06
531.2977295	0.10
533.3236694	0.35
543.2573853	0.08
546.9501343	0.59
547.5546265	0.16
549.3198853	0.03
551.3778687	0.17
555.1196289	0.74
557.2667847	1.09
561.2473145	21.11
562.2797241	0.76
565.1160278	0.06
570.4658813	0.14
574.7186890	0.17
575.3312988	0.36
578.3834839	0.47
583.7153320	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.971
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1407471	0.07
170.9761963	0.03
180.1527100	0.07
199.0197296	0.13
201.0342407	0.08
202.7844849	0.18
213.1651306	0.05
226.4043884	0.28
227.2216187	0.02
228.9017334	0.15
243.0588684	0.15
245.0629578	0.12
247.2124023	0.25
269.2907104	0.03
270.9359741	1.17
272.9005737	0.23
275.2036743	0.05
276.1002197	0.17
277.0987854	0.22
287.0332031	0.47
289.0212402	0.03
297.3253784	0.08
305.0894775	3.69
306.8345642	0.47
307.7347412	0.05
309.0249634	0.13
310.2188721	0.21
311.3695374	0.09
312.6317749	0.05
314.9663696	2.30
317.1001282	0.16
329.9923096	0.07
330.9570923	0.19
333.0042114	7.26
334.3787842	0.18
335.1847839	1.31
340.9871521	0.07
342.2676392	0.04
349.0809326	1.14
358.9818726	0.95
374.3591003	0.40
375.3598938	0.29
376.9736633	5.24
378.9920959	0.14
385.0785828	0.16
394.1250305	6.49
395.0015869	60.96
402.9778137	10.66
420.9353027	100.00
421.5921326	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	791.4353
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1307678	0.08
237.2048950	0.21
239.1689758	0.27
241.2259979	0.47
247.0085297	0.15
251.3919983	0.21
255.2666016	0.23
269.5175781	0.26
281.4103394	0.11
291.2739258	1.90
295.5734253	0.12
297.1709900	0.38
305.2040405	0.17
307.2536011	0.33
309.2713928	1.83
317.2384949	0.05
325.1741943	0.25
327.2590027	46.05
328.5605469	0.41
347.1222534	0.18
367.5385742	0.56
389.3297119	0.81
391.2656860	0.12
407.4292603	0.08
429.3845215	0.22
435.3109131	0.07
454.1406860	0.09
461.1062012	0.23
463.2420044	100.00
464.1721802	0.80
473.4733887	0.04
481.2315674	18.91
481.9077148	0.23
483.6063843	0.07
521.4697266	0.43
535.1448364	0.14
553.3306274	0.78
597.5684814	0.42
624.1256714	0.11
625.3132935	0.12
629.3673706	0.14
635.3118896	0.12
647.3677368	0.10
653.6290283	0.18
654.5001831	0.13
655.1354370	0.30
661.0751953	0.12
675.3101196	0.09
685.3134766	0.07
706.3212280	0.21
727.3765259	0.14
729.5867310	0.17
731.5878296	0.72
733.3091431	0.52
743.1153564	0.26
745.5784302	0.09
747.6423340	0.23
758.8943481	0.43
761.2011108	0.07
773.5183105	4.23
774.4700317	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.12
Annotation	Unknow
Peak:m/z	Relative Intensity
105.9322815	0.04
107.0027084	0.02
108.9616394	0.02
112.9690170	0.01
116.9889374	0.02
118.2025528	0.01
119.8325500	0.08
121.9992523	2.15
122.8870010	0.07
124.0311737	0.33
124.9606705	0.01
126.9592438	0.01
131.1149750	0.04
141.8176575	0.02
146.1227112	0.11
147.9786835	0.11
152.7207947	0.02
153.5797729	0.08
155.2053528	0.07
156.0429382	0.02
157.1070404	0.02
159.2254333	0.03
163.1547852	0.02
164.9342041	0.04
166.0414734	0.10
168.0569763	0.12
169.2930603	0.09
177.3490601	0.01
184.1434631	0.01
191.0349426	0.03
195.0731506	0.01
203.1404724	1.11
204.3977661	0.14
205.0689392	1.25
205.7598267	0.01
207.8587646	0.02
209.0515747	0.57
209.9879761	0.02
211.0751801	0.28
211.8246765	0.04
213.3407898	0.03
217.9660492	0.04
223.2545471	0.01
226.1735229	0.01
226.9960022	0.01
235.2335205	0.02
239.0614624	1.41
241.0117493	100.00
242.2872314	1.22
243.0402222	8.59
246.3659668	0.03
247.2527161	0.07
251.2218933	0.04
253.2080383	0.02
256.5162964	0.05
257.2063293	0.03
271.0756226	0.18
277.1402893	0.10
279.1913452	0.02
280.1345520	0.04
284.0815430	0.04
289.0208435	0.17
297.1870728	0.01
300.2210083	0.01
301.0997314	0.02
304.1887817	0.06
308.4381104	0.02
315.2332764	0.08
318.2793579	0.04
319.1999512	0.04
319.8457336	0.01
322.1316833	0.06
326.0527954	0.05
327.9776001	0.03
329.2057190	0.12
332.2514954	0.17
333.2056274	0.02
334.2068481	0.02
344.1842346	0.01
346.0796509	0.51
347.1683655	0.14
349.2728271	0.01
354.6985168	0.02
355.3247986	0.02
364.1795959	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.29
Annotation	Unknow
Peak:m/z	Relative Intensity
192.9762115	0.74
197.2273407	0.01
201.2054596	0.03
224.9660187	0.06
227.1945801	0.02
235.0196075	0.18
237.4472656	0.02
241.1885681	0.34
252.9874573	0.16
253.6245880	0.06
255.3677216	0.28
257.1825562	0.79
265.5246887	0.02
267.3107300	0.01
269.1493530	2.25
270.0651855	0.05
271.3364258	0.79
285.1879272	0.13
287.2634583	1.21
289.2836304	0.45
297.5312500	0.02
301.1864624	0.04
303.2731934	0.06
308.8306580	0.06
313.2761841	0.18
315.2955933	1.27
316.4114380	0.02
322.4769287	0.05
331.2044678	1.95
333.2317505	100.00
337.1112366	5.11
339.3487549	0.02
342.2010498	0.10
349.2664185	0.03
353.0789795	0.06
355.0783081	6.70
365.0656738	0.18
369.0915527	0.02
372.4688721	0.02
389.3317871	0.02
433.6256104	0.04
440.7536011	0.04
451.4467163	0.03
461.2249756	0.04
465.2199707	0.04
494.4891357	0.07
495.3163452	0.08
499.2391357	0.01
503.4492188	0.01
509.2862549	0.04
515.6410522	0.01
527.2066040	0.08
539.4102783	0.02
545.4703979	0.01
555.3563843	0.01
566.0361938	0.02
573.5067749	0.08
579.0109863	0.02
584.4271851	0.02
597.0265503	0.01
608.3899536	0.02
609.4580078	0.06
611.2880249	0.06
613.5628662	0.13
623.7969360	0.02
624.8766479	0.05
626.8587036	0.28
627.6414795	0.22
635.1257324	0.07
638.5204468	0.03
639.4463501	0.07
641.2222900	0.05
643.0134888	0.05
647.6815796	5.24
648.3786011	0.59
652.4445190	0.09
653.2713623	0.45
656.5253906	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.51
Annotation	PE(P-16:0/20:4(5Z,8Z,11Z,13E)(15OH[S]))
Peak:m/z	Relative Intensity
233.3043365	0.76
256.9421997	0.05
259.1382446	0.18
275.3021851	0.97
277.2379761	88.37
277.9827271	0.33
279.4090881	2.95
281.2431030	100.00
281.8439331	0.35
404.4209595	0.08
412.3585205	0.11
456.3100586	1.49
460.2669678	0.72
474.2573853	9.55
474.8714600	0.09
475.4854736	0.08
476.3096924	0.22
478.3374023	14.74
514.2601929	0.13
584.2070923	0.04
654.0611572	0.05
660.2722778	0.06
678.4328003	0.64
694.3947144	0.27
719.7867432	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	699.4328
Annotation	Preparaherquamide
Peak:m/z	Relative Intensity
195.0012817	0.05
207.2318573	0.52
209.2152557	0.09
215.0887451	0.04
218.8346558	0.05
220.7859192	0.15
221.4276581	0.04
223.0688477	2.32
227.1322937	0.04
233.3056030	0.15
235.5500793	0.05
237.1987000	0.35
238.9655762	0.06
241.0558472	0.06
246.9462585	0.09
251.1977539	8.42
253.9226074	0.17
268.4787292	0.38
272.2549744	0.10
277.0331726	0.11
279.8853149	0.07
281.1147461	1.41
291.4795532	0.05
299.2348938	0.06
300.1742554	0.02
305.4019775	0.04
313.3495483	0.13
315.1903687	0.92
321.0630798	0.12
333.1895752	9.12
334.2581787	0.10
348.3530884	0.07
349.9868774	0.04
351.2952271	5.04
351.9835205	0.06
362.8025513	0.20
364.4681396	0.17
369.2035522	100.00
370.3078003	0.25
371.3425903	0.25
373.9869995	0.08
385.3914185	0.24
386.5098267	0.27
408.7574463	0.27
409.7191162	0.23
414.2235718	0.06
422.2680664	0.04
440.5023804	0.27
445.0684204	0.05
451.3386230	0.08
454.3774414	0.07
468.3239746	0.07
469.5830078	0.04
506.4600830	0.09
507.2523804	0.05
516.1403809	0.38
524.3391113	0.11
533.4069824	0.03
536.0576782	0.07
537.3734741	0.15
545.4132690	0.06
558.3027954	0.09
569.0098877	0.17
581.2394409	1.77
599.4964600	0.09
614.7065430	0.03
616.2510376	0.04
616.9032593	0.26
621.8052368	0.15
625.8962402	0.59
637.7014160	0.30
639.0687256	0.18
640.0637817	0.17
640.9331055	0.37
656.2868042	0.06
660.5194092	0.05
663.3190308	0.56
665.2358398	0.50
666.7942505	0.41
677.0900879	0.26
681.3309326	5.75
682.8334961	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.508
Annotation	Phosphatidylethanolamine 18:2-18:2
Peak:m/z	Relative Intensity
217.4528046	0.10
219.0279541	0.07
234.4208374	0.26
255.2703094	0.06
261.5076599	0.14
275.0887451	0.16
277.2558594	2.76
279.1969604	100.00
280.2290039	0.66
281.2600403	4.75
281.9638977	0.06
287.2052612	0.07
293.1689453	0.12
295.2692871	0.39
297.114563	0.19
305.3832092	0.12
317.0863037	0.05
333.1704102	0.19
339.416626	0.09
391.3900757	0.05
392.359436	0.14
395.2572632	0.14
401.8184814	0.12
415.2277222	0.31
458.3389282	2.32
474.4000854	0.82
476.2699585	13.77
476.9240723	0.04
502.2539673	0.08
516.1652222	0.12
541.4766235	0.12
548.1027222	0.04
551.4661255	0.07
554.6175537	0.11
573.9867554	0.18
578.1495972	0.04
585.4549561	0.10
589.4920654	0.03
590.1417236	0.17
608.1698608	0.04
620.7362671	0.22
622.3952026	0.08
632.5623779	0.04
639.3751831	0.08
659.6384888	0.06
661.359314	0.09
664.3798828	0.06
666.5004272	0.15
678.3294067	0.65
679.1809692	0.36
680.0408936	0.12
692.1481934	0.05
702.0757446	0.05
720.1333618	0.87
721.161499	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.2293
Annotation	Kunzeaphlogin E
Peak:m/z	Relative Intensity
205.1063843	0.12
217.2176514	0.10
219.2130737	0.15
229.1589050	0.13
232.9665527	0.32
235.1730957	5.76
244.1358643	0.23
245.8826752	0.06
247.1551666	0.08
249.9960175	0.27
254.1588287	0.22
257.2301331	0.04
265.0632019	1.05
271.1651917	0.16
282.1004028	0.11
286.0198059	0.63
287.1746521	0.13
289.0541382	0.26
290.3279419	1.39
292.3258057	0.29
295.0736084	0.51
297.1676636	0.15
299.2941895	0.14
301.4359436	0.41
309.0868530	0.07
312.2169800	0.07
318.8958740	0.09
322.9984131	0.46
327.1514282	0.65
337.1583862	0.94
339.3863525	0.21
341.1150208	17.25
355.1417847	0.54
363.4787598	0.08
371.1873169	2.16
374.2862549	0.24
375.6448975	0.09
379.0017090	0.25
380.2307129	0.34
381.2062988	0.30
383.2228394	6.65
387.0852051	0.12
389.0372925	86.32
389.7058105	0.29
395.2131958	1.07
397.2232666	0.21
399.1178589	0.23
403.0192261	0.39
405.9434204	0.18
407.3399048	0.25
408.1584473	0.26
409.1647949	0.32
412.2286987	0.08
413.1366577	0.45
422.4528198	0.69
424.9616089	0.37
426.2013550	0.11
431.0892334	35.92
431.7734375	0.10
432.6367798	0.10
434.8747559	0.22
442.8801270	2.37
443.6292114	0.54
445.3084106	0.46
449.1436768	0.69
451.1209717	0.77
452.0953369	0.18
455.0250244	0.22
460.9222412	23.07
461.5670776	0.51
463.3729858	0.22
466.9367676	0.09
473.0739136	2.70
479.3471069	0.10
483.8988647	0.21
484.7632446	0.36
486.0836182	0.30
488.3615723	0.20
491.0033569	100.00
491.8301392	0.52
493.2040405	0.32
500.2603149	0.14
503.0045166	0.25
514.8009033	0.28
517.1365967	73.13
520.9139404	1.18
531.0478516	0.40
533.0393066	5.33
536.5756226	0.07
537.2752075	0.13
542.8508911	1.07
545.3671265	0.04
547.4492798	0.32
550.9489136	61.23
551.7545776	0.05
557.2053833	0.27
559.2272339	0.77
560.8117065	1.36
562.0098877	0.65
563.4794312	0.25
566.2391968	0.22
567.6979980	1.78
568.6866455	0.47
570.1292114	0.29
571.9683228	0.14
573.7081909	0.29
575.0966187	0.43
576.7183228	3.96
577.4516602	1.31
578.1410522	0.58
578.8971558	0.09
583.1683960	0.17
593.4199829	0.20
602.4067993	0.50
605.7168579	0.35
618.9531860	0.44
621.2829590	0.34
627.4614258	4.58
628.2185059	0.94
635.1350708	0.11
636.4769287	2.79
637.2386475	1.02
640.7925415	0.23
644.1150513	0.16
644.9958496	0.64
648.6914673	0.37
649.6638794	0.08
653.0584717	0.46
658.1675415	0.58
662.1350708	0.11
665.0053711	4.67
666.2401123	0.25
668.6718140	1.08
669.3683472	0.08
675.7494507	0.07
677.4498291	0.29
685.0069580	0.22
686.0352173	0.70
691.9603271	0.29
694.6190186	0.71
695.3554688	1.44
696.2710571	0.08
722.5556030	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.3019
Annotation	Unknow
Peak:m/z	Relative Intensity
218.0931091	0.02
239.2294769	0.07
257.2219238	0.49
259.3963318	0.26
269.1960754	0.02
271.2884521	0.40
273.4955444	0.01
275.4163208	0.09
285.0962219	0.05
287.3043518	3.13
289.2986450	1.24
290.1081848	0.02
292.3157349	0.04
297.4585876	0.11
301.2016602	0.07
303.1478882	0.25
305.3704834	0.66
308.2789917	0.02
323.2469177	0.03
331.3529663	0.18
332.0991821	0.01
333.2533875	0.94
337.1510620	0.91
349.2613525	0.13
351.2610474	100.00
363.2584229	0.01
364.0349731	0.03
375.1864014	0.02
381.1281128	0.25
382.2434082	0.14
383.2075806	0.08
398.7729492	0.05
399.4129639	0.03
414.3358765	0.01
415.0357666	0.03
425.4121704	0.03
430.0462036	0.02
445.4547729	0.01
447.1785889	0.07
459.2672729	0.03
465.2748413	0.03
476.7869263	0.01
498.2261353	0.02
513.4351807	0.05
519.3933716	0.03
537.2421875	0.04
544.3663330	0.19
545.2261353	0.16
553.0702515	0.03
560.2533569	0.05
569.3012085	0.08
573.0642700	0.02
573.9174805	0.16
591.1708374	0.03
599.7025757	0.02
610.5080566	0.03
611.2919312	0.02
613.2456055	0.02
627.5037842	0.15
644.3858032	0.06
645.1760864	0.12
653.1873779	0.05
670.1083374	0.02
671.2999878	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1089.55
Annotation	Kudzusaponin SA3
Peak:m/z	Relative Intensity
338.9068909	0.77
409.0534058	1.17
419.0552368	2.89
423.3182983	0.47
437.5915527	0.95
441.1808472	1.19
451.3020630	0.92
455.3128967	1.13
481.2687073	0.39
499.4874878	2.26
527.6118164	0.39
542.1697998	0.86
545.1266479	2.51
557.6442871	2.63
569.3969727	4.64
571.1568604	1.12
587.3666992	0.90
589.5119629	30.07
637.3166504	0.35
657.4796753	100.00
685.2561646	0.33
689.1961060	0.39
703.4061279	8.24
727.3282471	0.58
729.3207397	39.56
747.3883057	41.11
765.5591431	12.49
766.4606934	1.09
865.4433594	24.15
883.5316162	5.93
909.5523682	2.64
927.5150146	50.45
986.1826172	0.36
1027.5084230	40.56
1045.4509280	1.32
1053.6816410	0.66
1071.3168950	78.70
1072.0760500	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.1596
Annotation	Unknow
Peak:m/z	Relative Intensity
318.2214050	1.11
329.1687622	0.68
332.3659363	0.17
360.5032349	0.12
361.1057434	0.05
375.1697388	0.14
390.3899231	0.25
401.3472290	0.14
403.3883667	0.07
404.2618408	0.25
431.3052368	0.29
436.3643799	0.68
448.1018677	0.08
448.9927979	0.15
461.2971802	0.20
485.1375732	0.13
492.1768799	1.53
503.1056519	0.39
505.3547363	0.18
521.7434082	0.34
549.7969971	0.63
550.4542236	0.07
558.1269531	0.06
560.6596680	0.11
566.3843994	0.17
577.0567017	0.49
578.2376099	0.15
592.3649292	0.09
593.5977173	0.80
595.0916748	0.15
629.4038696	1.29
630.0607910	0.48
665.7448120	0.25
668.9950562	0.07
672.2031860	0.69
677.3236694	0.21
682.3638306	0.12
691.3839111	1.35
692.3969116	0.04
700.4098511	0.08
731.8778076	0.45
736.5541382	0.33
757.9431763	0.75
758.8397827	0.11
791.3114014	1.03
820.7809448	0.50
827.5510254	0.07
830.5441284	0.50
836.2842407	1.01
838.9268188	0.13
857.7297974	0.50
858.9743652	2.33
860.6786499	1.03
874.4093628	1.28
878.6582642	1.17
880.7462769	0.58
882.8682251	0.50
885.3920288	0.76
891.0991211	0.45
892.7362671	1.25
894.5735474	1.48
895.8879395	1.78
898.3126221	0.42
900.5571289	2.00
902.8585815	5.27
903.9583740	0.76
904.7051392	0.43
905.5446167	2.07
907.0471802	4.27
907.8723755	0.18
909.3098755	0.10
909.9688110	0.90
913.7374878	0.97
914.7954102	1.00
915.6505127	2.06
916.2728271	1.04
917.2131958	1.03
918.3022461	4.55
918.9454956	1.13
919.6864014	0.80
921.0822144	1.64
922.2515869	0.22
922.8965454	0.05
923.9923096	3.01
926.1390991	0.17
926.8773804	0.83
927.7673950	2.82
928.5458984	2.47
929.2281494	0.10
930.5870972	7.55
931.4686890	3.18
932.5216675	2.27
933.7108154	1.15
935.0801392	76.89
935.9655762	3.09
937.0237427	1.48
938.1972046	3.39
939.3760376	17.83
940.1264038	7.99
942.0634155	1.34
943.3388062	3.53
944.2611694	3.79
945.0953979	4.09
945.9225464	0.66
946.8904419	0.11
948.8595581	18.76
950.1466675	2.92
951.1260376	0.19
952.0399780	3.50
952.6687622	1.38
953.5702515	2.49
954.2849121	2.15
956.3837891	5.20
957.3975220	1.18
958.0993652	0.18
960.8263550	0.33
968.9628906	0.29
982.3386230	0.37
984.2511597	0.08
986.4143066	1.12
989.6621704	0.12
990.6307983	0.60
995.6322632	0.53
1018.1606450	1.08
1021.3182980	0.42
1022.2789920	1.17
1026.6862790	1.13
1039.0688480	0.97
1040.8044430	0.92
1047.5896000	0.47
1048.6561280	0.59
1050.6998290	0.73
1051.9394530	0.83
1053.2316890	0.63
1054.3840330	0.92
1059.7581790	3.26
1060.6910400	2.17
1069.0610350	0.14
1077.7756350	1.08
1082.9713130	1.90
1084.0112300	0.87
1085.8293460	1.24
1088.1662600	0.73
1089.4306640	0.40
1092.8361820	2.30
1093.8974610	1.02
1094.5871580	0.21
1096.3035890	0.71
1097.6699220	2.42
1098.6292720	0.34
1100.7646480	0.83
1102.5318600	1.27
1108.8159180	1.02
1112.2563480	1.04
1114.6611330	2.10
1115.9555660	0.83
1116.8948970	0.84
1117.8813480	0.78
1120.5354000	0.07
1121.4155270	1.02
1122.0534670	0.60
1125.5341800	3.17
1126.3323970	4.44
1127.4072270	1.32
1128.1962890	2.09
1129.3432620	0.68
1130.6693120	1.27
1131.4047850	1.19
1132.3381350	1.49
1134.2167970	0.24
1135.4221190	0.30
1136.7847900	2.64
1137.6945800	2.64
1138.5621340	0.50
1140.5007320	0.26
1142.6746830	0.12
1146.3787840	4.22
1147.1765140	6.63
1148.0339360	0.48
1148.6789550	0.35
1153.4918210	0.72
1156.2221680	0.11
1157.5515140	0.39
1158.1964110	0.29
1159.1489260	0.32
1159.8173830	2.47
1162.5168460	0.73
1165.3498540	4.71
1166.3424070	2.78
1169.3159180	0.74
1170.9132080	1.83
1171.5212400	0.64
1173.9188230	0.28
1174.6809080	1.89
1175.2934570	1.56
1177.4354250	0.09
1178.1811520	0.30
1179.0522460	0.19
1180.4384770	10.92
1182.3205570	0.96
1184.6634520	4.46
1186.1491700	7.30
1188.4501950	2.14
1189.6755370	0.43
1190.3615720	0.15
1192.1842040	0.80
1194.0428470	7.16
1194.9880370	0.63
1197.1857910	3.84
1197.9423830	0.45
1199.0583500	1.70
1199.7203370	0.36
1200.3740230	0.65
1201.6846920	0.44
1203.4222410	29.24
1204.5867920	1.90
1205.6425780	0.38
1208.2166750	1.90
1209.1865230	1.75
1209.8072510	1.87
1210.8811040	0.10
1211.6229250	0.32
1214.0950930	5.36
1215.0200200	1.76
1217.4108890	0.15
1218.4140620	4.83
1220.2384030	0.90
1223.3847660	6.04
1224.1809080	10.04
1224.8612060	5.69
1226.1020510	5.07
1227.4250490	0.66
1228.5648190	1.77
1231.2203370	1.07
1232.1000980	0.40
1233.1761470	1.82
1233.8367920	2.82
1236.0808110	0.12
1236.7429200	1.27
1237.4989010	2.35
1238.3608400	1.51
1240.7863770	23.72
1241.9123540	2.33
1243.2850340	5.65
1243.9012450	0.28
1246.0460210	100.00
1246.6710210	96.37
1248.1278080	4.93
1249.0792240	2.16
1252.2419430	89.65
1252.9130860	30.49
1253.8613280	1.62
1255.2685550	0.41
1257.0673830	9.95
1257.9267580	10.43
1258.8654790	0.41
1260.8374020	0.34
1266.0616460	6.06
1267.1186520	1.44
1271.5755620	0.05
1274.7403560	1.02
1287.7432860	0.42
1289.8317870	0.80
1294.8812260	0.36
1311.5388180	0.22
1322.1331790	0.48
1328.5860600	0.48
1336.9565430	0.30
1339.3988040	0.51
1347.5672610	0.38
1349.2120360	0.33
1360.4315190	0.64
1363.0572510	0.38
1383.4244380	0.32
1401.6688230	0.25
1403.4455570	0.20
1410.2069090	0.22
1416.6427000	0.15
1422.3232420	0.56
1425.4593510	0.65
1429.7388920	0.40
1465.8157960	0.19
1472.9703370	0.99
1475.1954350	0.36
1480.3790280	0.56
1482.0809330	0.50
1483.5430910	0.24
1498.4699710	0.06
1508.8117680	0.50
1509.4885250	0.26
1525.1737060	0.25
1528.5091550	0.11
1532.2689210	0.27
1535.1696780	0.61
1539.0159910	0.24
1540.7883300	0.59
1548.9859620	0.76
1557.8409420	0.14
1560.7635500	0.31
1577.6180420	0.64
1579.1529540	0.19
1581.9735110	0.68
1585.7855220	0.10
1587.4951170	0.20
1589.5831300	1.07
1595.7117920	0.69
1597.0780030	0.45
1597.6973880	0.37
1602.2611080	0.13
1607.0980220	0.44
1620.5504150	0.51
1625.3498540	0.56
1639.2467040	0.36
1669.1346440	0.75
1672.1760250	0.70
1693.4910890	0.47
1699.8688960	0.38
1704.6322020	0.77
1705.3702390	0.31
1706.1429440	0.25
1714.7503660	0.14
1717.3548580	0.88
1718.4539790	0.35
1723.4029540	0.05
1732.0272220	0.37
1737.5318600	0.18
1743.0861820	0.54
1770.9489750	0.23
1807.7015380	0.34
1880.0812990	0.15
1884.6832280	0.76
1942.1934810	0.14
1943.6315920	0.15
1946.9891360	0.23
1953.7873540	0.17
1995.7883300	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.7807770	0.20
115.0286255	0.10
128.9314575	2.54
147.0643311	2.81
153.2590942	0.08
161.1086426	0.15
163.0580750	0.06
172.9652710	2.16
181.0765381	0.06
187.1223450	0.09
190.9917755	100.00
192.0655823	0.05
193.1260834	0.94
197.1083984	0.04
205.1521912	0.56
209.1302185	8.98
223.1163635	3.05
241.1552429	0.07
272.2518921	0.09
279.2862854	0.12
280.7299500	0.08
323.2322083	0.07
325.1105652	0.10
327.2883301	0.06
339.1128540	0.15
341.4196777	0.07
348.9836121	0.41
353.3093567	0.05
367.0922546	9.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Apigenin 7-O-glucoside
Peak:m/z	Relative Intensity
126.7033157	0.01
130.005127	0.01
132.5596924	0.01
135.0769501	0.02
138.9251862	0.07
144.665741	0.01
160.7228394	0.04
165.1975403	0.01
179.116806	0.04
183.3880157	0.01
187.1007996	0.09
190.9733887	0.01
193.2423859	0.07
199.2224426	0.02
203.4674225	0.02
210.7393494	0.02
213.2512207	0.02
225.1878662	0.01
226.0037842	0.01
227.197403	0.09
229.1810303	0.07
243.2635193	0.01
253.0769043	0.09
255.0786438	0.13
267.1094971	0.01
271.0687866	100.00
272.0180359	0.10
273.1141357	0.06
274.8597412	0.05
277.171875	0.01
282.9814453	0.02
288.9726868	0.32
297.0354004	0.00
299.9880371	0.03
304.2589417	0.02
305.3432617	0.02
306.9746704	0.02
309.0178833	0.01
313.0550537	0.03
336.235321	0.01
339.1992798	0.04
343.1298828	0.01
351.1366577	0.01
353.3722534	0.02
355.0943909	0.04
358.8118591	0.01
367.1891785	0.01
368.1260986	0.02
371.1695557	0.09
374.3149414	0.03
376.2168884	0.03
376.9741516	0.02
379.1056824	0.02
385.3632507	0.01
386.1930237	0.02
387.1268616	0.09
387.9810486	0.03
397.0628967	0.07
402.9191589	0.02
404.3788757	0.01
415.0331116	0.30
416.4926758	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.5081
Annotation	PE(P-16:0/20:4(5Z,8Z,11Z,13E)(15OH[S]))
Peak:m/z	Relative Intensity
214.1524048	0.16
233.3824158	0.09
259.4928284	0.04
263.3561096	0.08
277.2467957	49.10
278.6661987	1.31
279.4008789	3.50
281.3007507	100.00
282.0869446	0.02
291.5878296	0.05
330.5374756	0.07
413.5264893	0.14
451.5791626	0.06
456.3999023	0.97
458.2706299	0.22
460.4105835	0.60
474.4162598	9.84
476.5242920	0.12
477.7487183	0.30
478.4018555	5.29
502.9027710	0.04
563.3485107	0.06
567.5645752	0.04
630.9763794	1.20
652.2770386	0.28
677.6527710	0.27
678.2927856	0.04
679.1290894	0.11
719.7776489	0.23
720.5853882	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.1537
Annotation	Unknow
Peak:m/z	Relative Intensity
151.1690979	0.23
153.0631409	1.30
156.9031067	0.16
167.3022614	0.37
171.0316010	0.18
178.8316956	0.38
193.1902771	1.86
197.0458984	4.76
198.0004120	0.19
199.1095428	0.83
199.8948059	0.11
210.4711304	0.19
211.1102753	3.35
214.9911041	0.87
216.0174866	0.15
227.1512756	0.16
229.8259583	0.11
236.2122955	0.64
237.9309082	0.11
239.0729370	0.41
241.0913391	3.91
245.1246948	15.70
257.0237732	0.22
259.1656494	37.40
261.0334473	0.06
262.1266785	0.08
263.0577393	2.66
263.8524170	0.06
273.2655029	0.09
276.1625366	0.18
277.1781616	2.97
279.6644897	0.21
280.2739868	1.72
281.1579590	0.07
284.2415161	1.13
289.3713379	0.10
295.5998535	0.11
302.2603760	0.77
308.1203613	0.06
310.1595459	0.52
310.9288330	0.10
316.1987915	0.11
317.0755615	0.09
319.2603149	0.34
326.1674194	0.04
328.0515747	5.26
343.0967407	0.07
346.1967163	6.61
356.1279297	0.44
359.0332031	0.73
360.0366821	0.25
362.3833008	0.06
369.1329346	0.88
370.1114502	2.15
372.6815186	0.05
374.3088989	0.06
376.0733643	5.90
377.0730591	0.31
379.2019653	0.47
387.2741699	10.95
388.2148438	2.73
390.9021606	0.08
394.2356567	8.59
395.2133179	0.66
413.2540283	8.26
421.1547241	0.24
431.2117310	11.49
439.0153809	1.21
439.9317017	0.04
449.1702881	0.17
451.3212280	0.23
457.1858521	17.09
458.1934204	0.67
459.5212402	0.06
461.2204590	1.63
475.1622925	56.88
475.7638550	0.14
477.8973389	0.09
479.4262085	0.82
487.2477417	8.01
505.1199341	100.00
506.1744995	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.135
Annotation	4'-O-methyl-(-)-epicatechin-3'-O-beta-glucuronide
Peak:m/z	Relative Intensity
151.0366516	0.06
153.1927185	0.07
159.0557861	0.03
161.0680389	1.61
162.1005554	0.03
162.9600372	0.02
163.9809723	0.18
164.9382019	0.14
172.9724884	0.03
175.1113892	0.16
176.9815063	0.02
179.0696869	0.69
179.9081879	0.06
184.1220093	0.04
186.1436005	0.03
187.1989746	0.09
188.0647888	0.25
190.8387756	0.30
195.7995911	0.02
201.9419250	0.02
203.1614380	0.62
205.0622864	1.05
209.0644073	0.05
215.1483307	0.01
217.0868683	0.08
226.7975922	0.06
230.1553650	0.11
231.1356964	0.05
233.3171387	0.08
243.1900482	0.07
244.1447449	0.22
245.1879883	5.35
246.9786377	0.11
260.9535522	0.10
271.2402039	0.54
281.0659180	0.02
285.1086121	0.04
287.1502991	0.03
289.1141052	100.00
313.2556152	0.21
327.1007080	0.08
328.2539062	0.03
329.0382080	0.05
331.0733948	0.48
340.9230042	1.79
341.6724854	0.01
349.5988464	0.07
350.9538574	0.05
355.1658020	0.22
355.9315491	0.01
369.1403809	0.04
385.6403809	0.05
389.2981873	0.23
403.5570984	0.04
407.2027588	0.06
421.1421204	0.12
425.3887329	0.02
433.2131653	2.64
449.1654358	0.12
451.1385193	31.66
451.8079529	0.11
475.1913757	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0932
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
116.7826691	0.03
125.0401230	3.35
127.8749466	0.03
128.9645233	4.08
133.7963715	0.10
135.1308289	0.11
136.0648193	0.26
142.9957886	1.46
151.1886139	0.18
161.0484161	1.03
164.9278717	0.02
169.1575928	0.16
174.9731140	0.05
186.9844360	0.90
193.1146088	0.41
195.0439453	8.07
204.9499359	100.00
207.0744934	0.05
219.1942291	0.05
223.0015411	29.25
237.3186951	0.10
261.0625000	0.11
279.2727051	0.04
323.0545959	0.09
337.1186523	0.05
339.3874817	0.32
343.0399170	0.10
353.2782898	0.26
355.2587585	0.44
363.2015686	0.18
367.2929382	0.07
381.0267029	1.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.294
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
140.052124	0.14
153.1045074	0.12
196.0899963	1.61
214.0966187	0.83
262.1836548	0.02
281.2453613	100.00
281.8560181	0.28
417.2742004	0.45
463.3084412	0.01
479.298645	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1059.5377
Annotation	Pitheduloside K
Peak:m/z	Relative Intensity
354.9622498	0.39
360.3722839	0.56
363.4310303	1.09
364.6877747	2.34
375.6391296	0.14
380.2675781	4.15
383.0554199	0.23
387.3589478	0.41
389.2432861	0.86
390.4345093	0.80
403.2899780	0.49
404.4242249	1.09
405.8635864	0.65
406.4856262	0.36
407.3961182	0.29
408.4741211	0.98
410.4353638	0.75
424.3669434	1.69
433.6037292	0.44
437.7607727	1.55
438.4437866	1.22
439.3236084	6.79
440.4664307	3.16
454.5421753	0.44
455.4979858	0.49
456.6362915	1.08
457.4872742	0.79
458.5523682	0.92
463.2338867	0.20
466.4882812	1.04
479.3414307	0.16
481.0858154	3.54
494.4625549	0.95
496.5392456	0.21
499.4545593	0.13
504.4623413	0.45
511.3121338	0.94
512.3661499	0.17
526.6477051	0.90
536.2696533	0.55
541.5201416	23.32
542.4632568	27.29
551.4340820	0.25
552.5693359	0.71
556.2122192	0.86
557.5072021	2.35
558.6604004	7.24
559.6152954	2.93
560.4825439	7.80
570.7584839	0.32
571.4292603	0.14
574.4309082	0.52
579.8194580	0.26
582.4476318	1.66
590.8078613	0.27
615.6727905	0.60
616.6259766	0.74
624.3051758	0.25
627.3217773	14.02
628.5579834	26.19
642.3511353	0.43
656.5318604	1.06
673.2845459	3.94
674.4616699	5.02
692.6694336	0.14
699.5806885	10.99
700.4418945	14.28
716.5642700	1.69
717.5570679	16.75
718.4772949	20.78
719.3096313	1.03
735.8245239	2.40
736.5316162	0.48
752.6295166	0.99
758.6624756	0.33
795.3728027	0.29
804.4932861	0.98
818.4643555	2.38
822.6221924	1.06
835.3895264	4.23
836.4261475	28.92
837.4973145	0.49
854.0241699	1.52
854.6816406	4.47
880.4141846	1.55
896.4826660	0.61
897.4295654	0.77
898.3848877	15.92
898.9885254	0.85
922.5986328	1.19
926.8974609	0.13
940.1859131	1.45
954.7990723	0.88
958.1676025	17.69
958.9960938	1.31
959.6953125	0.35
966.0234375	1.73
971.7084961	1.36
983.4145508	11.91
984.5716553	100.00
985.6555176	1.22
998.3940430	80.13
999.3907471	1.19
1015.6961670	1.58
1016.4541020	2.10
1017.5292970	0.41
1041.2409670	1.23
1042.4896240	23.72
1043.4940190	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	319.1013
Annotation	Opuntioside I
Peak:m/z	Relative Intensity
109.9698105	0.13
110.9400177	0.14
114.1006165	0.05
116.9031525	0.07
119.0490417	0.17
120.9720383	0.05
129.7069092	0.04
135.7768097	0.10
138.9768829	0.03
153.1018372	0.10
156.9643250	100.00
158.2577972	0.07
159.1426086	0.17
161.0320282	0.06
165.0062408	0.08
169.0272217	0.10
171.0205536	0.10
175.1395569	0.20
177.1152191	0.10
179.0426636	0.26
186.9947205	0.11
187.8956604	0.01
189.2404480	0.19
190.1156006	0.29
195.2515717	0.10
196.7470398	0.02
198.5238953	0.02
202.1888428	0.07
204.1188049	0.03
226.8974915	0.13
228.8865356	0.05
230.0830078	0.06
231.1624146	0.03
233.0208130	0.11
235.9768677	0.03
244.0623169	0.11
245.6956177	0.14
249.1940918	0.13
249.9484863	0.06
253.1768188	0.03
255.3351135	0.02
256.9454956	0.16
258.9561768	0.15
261.1845703	0.04
272.9668579	0.29
274.0993652	0.07
275.0554504	0.25
276.3642883	0.09
278.1363220	0.17
279.0584106	0.06
283.0330811	0.21
285.2203979	0.33
287.7172546	0.17
292.1392212	0.17
301.0729065	0.61
302.1242676	0.92
306.1157837	0.02
310.1171265	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1196
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
147.8919373	0.10
151.1024628	0.81
151.9994202	0.35
153.1213684	0.09
163.1504211	0.09
165.1418915	0.28
166.0642700	0.06
173.9319458	0.11
175.9322662	0.15
178.9562683	0.16
179.8123779	0.39
197.0873413	0.07
199.1189880	0.05
211.1486969	0.19
213.1206512	0.04
214.0063629	0.14
215.1641083	0.12
216.0843201	0.10
229.1554565	0.26
230.3139801	0.66
231.2209320	1.83
233.1742554	0.03
240.1405945	0.09
243.2405701	0.06
245.1843567	0.15
249.3460999	0.08
255.3094482	0.14
256.9795227	0.11
258.0009155	1.29
259.3948059	0.15
270.1818848	0.08
271.1471252	0.66
273.1723633	5.73
274.1055298	1.23
275.0915833	0.03
289.0659485	86.01
290.1260681	0.84
297.5068970	0.20
299.1982727	4.21
305.2975769	0.05
311.1787415	0.06
313.2057495	1.27
314.4671631	0.17
315.2154541	0.20
317.0805054	100.00
318.2107544	0.47
327.0320435	0.05
329.2750244	0.15
331.4517212	0.50
336.1679688	0.06
341.1032715	0.19
342.8905640	0.15
343.9570923	0.02
344.9658203	0.04
347.2118225	0.39
348.2609863	0.05
359.1666260	0.15
361.1475830	0.18
365.9569702	0.03
389.2394104	0.08
393.0876160	0.06
405.4087219	0.14
413.2574463	0.05
417.1534729	0.18
417.8525085	0.06
425.0843811	0.08
433.3129578	0.45
434.0102844	0.17
435.0852356	0.51
449.3230591	0.08
451.0932312	0.91
452.0818787	0.09
461.1491089	4.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1428
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
78.8716431	0.02
80.9682312	0.09
82.8343658	0.02
84.8457489	0.03
91.0015411	0.08
93.0026093	0.63
94.9632874	0.48
96.9704742	0.35
98.9066620	0.32
100.9973755	0.08
104.9536896	0.13
107.0455780	0.48
108.9074097	1.04
110.9462738	1.10
112.9546356	0.76
118.8960419	2.20
120.4334717	0.09
121.0857391	1.12
123.0430298	0.28
124.8737030	0.13
131.0424805	0.10
133.0273743	0.53
134.9784241	5.05
135.9567261	1.31
136.9831390	3.10
139.0001526	1.10
142.9555511	0.44
145.0467834	0.98
147.0435791	1.19
149.0613708	0.71
150.9820099	0.16
153.1341705	0.03
155.0725708	1.05
157.0767059	4.10
159.0085449	1.86
161.0614166	3.50
162.9572296	0.48
165.1479797	3.04
167.0294647	0.39
169.1719513	0.17
171.0210266	0.94
171.9411163	0.03
173.2002716	1.70
174.9811096	10.82
175.5925598	0.03
177.1255493	0.43
179.3392792	0.02
181.0604248	0.11
183.0128937	0.42
185.0768585	2.07
187.0393829	6.55
189.0833435	2.73
191.1978455	0.30
193.1168060	6.32
195.0592804	0.07
199.0959473	0.56
201.0979156	5.07
201.8403778	0.09
203.0683441	10.96
205.0328369	1.53
207.0580597	0.90
209.1319733	0.09
211.1379700	4.47
217.0247345	10.07
219.1259308	4.72
221.0988312	0.34
222.2933502	0.04
223.2867279	0.02
224.0238495	0.05
229.0495911	12.59
235.0936127	7.81
243.7849731	0.03
244.8981323	0.03
246.9907379	100.00
247.6418304	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.3
Annotation	Spumigin B1
Peak:m/z	Relative Intensity
201.3422852	0.02
205.2479858	0.02
230.9182281	0.10
239.3379517	0.07
241.4434814	0.02
253.3817139	0.03
256.2798157	0.18
267.2257080	0.07
269.3005371	0.20
271.3046265	0.26
285.3939819	0.11
287.2486572	0.43
289.3756714	0.01
297.2758179	0.14
315.3252563	0.75
333.2159424	100.00
337.1182861	0.84
345.2647095	0.02
346.2730103	0.07
363.2637329	0.04
365.0267944	0.01
401.4082642	0.07
407.1118774	0.06
476.2674561	0.10
493.3263550	0.07
494.4348145	0.02
495.4027100	0.18
501.1970825	0.03
507.8504639	0.04
508.4692993	0.15
526.5258179	0.02
541.2661133	0.02
608.3795776	0.02
627.1506958	0.02
652.2201538	0.09
653.3356323	0.07
843.3922119	0.03
1252.4769290	0.11
1253.8259280	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	879.214
Annotation	Unknow
Peak:m/z	Relative Intensity
279.1579590	0.05
293.3699951	0.04
301.0336304	0.06
305.1901855	0.07
315.3902893	0.06
335.2883911	0.16
339.2312622	0.18
340.1599121	0.05
373.3314819	0.20
375.5463257	0.12
381.2751465	0.19
382.9520874	0.04
391.3998413	0.16
399.3050537	0.15
401.0996094	0.28
405.1639404	0.12
413.5595703	0.09
417.1950684	0.41
418.9806519	0.12
425.0634766	0.06
431.2211304	2.50
441.3427124	0.06
445.0524292	0.67
447.2941895	0.62
449.3482056	0.11
450.0570068	0.17
450.9015503	0.16
459.2024536	0.29
463.9815674	0.10
464.9111328	0.07
467.1177368	0.09
473.2776489	0.57
497.1087036	0.21
497.9340820	0.16
500.9737549	0.08
502.6588135	0.15
519.2386475	0.08
521.3057251	0.51
523.0934448	0.12
525.2093506	0.10
531.3738403	0.05
533.3287964	0.16
539.2989502	0.03
543.5471191	0.12
551.2142944	0.27
553.3681641	0.29
557.2503052	0.10
559.0958862	0.10
563.2038574	0.31
573.1694946	0.07
574.3356934	0.18
575.3698120	0.15
576.2789917	0.10
577.1301880	0.08
578.2425537	0.03
579.1185303	0.04
581.2041626	2.37
585.1561279	0.05
591.4426880	0.29
593.1204224	2.14
593.7683105	0.02
596.1065674	0.12
597.1950684	1.25
599.0973511	0.18
607.1958008	0.61
609.3834839	0.11
612.0510254	0.14
621.7182617	0.17
625.1011963	2.13
642.9384155	0.18
657.5213013	0.12
659.5427856	0.12
667.7219238	0.21
675.1188965	0.23
690.8279419	0.37
701.2400513	3.69
702.3660278	0.18
703.3110962	0.14
709.9619751	0.11
710.6814575	0.26
711.3289185	0.05
713.1734009	0.37
719.0911865	100.00
719.8369751	0.13
725.2022705	0.24
727.2807617	0.13
729.2913208	0.30
729.9032593	0.04
730.9365845	0.12
737.3193359	0.09
742.3320923	0.18
743.3264160	0.64
745.0880737	0.22
755.1592407	2.96
760.0370483	0.04
761.2424927	5.54
762.1896362	0.06
773.2548218	0.14
787.1555786	2.18
791.1760864	0.40
799.3483276	0.14
819.7091675	0.22
827.1431885	0.22
835.2304077	0.04
837.3599854	0.07
845.5206909	0.09
863.0391235	5.27
864.5119019	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.11
Annotation	Indole-3-carboxylic acid beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
101.9683304	0.10
125.2161255	0.02
129.9426422	20.25
134.6813202	0.05
144.9985352	1.24
149.0100555	0.03
151.0932007	0.61
153.2294006	0.03
155.8090668	0.03
174.0593872	0.05
176.9697266	100.00
177.7622681	0.01
183.0612335	0.02
183.9526367	0.53
195.0224609	7.34
203.0311279	0.03
204.1285706	0.08
212.1428528	1.71
220.8116760	0.02
224.1487122	0.10
232.4631958	0.04
236.3720703	0.04
239.0401001	0.04
240.2011108	0.03
251.5911560	0.04
254.1136169	0.03
265.2484436	0.04
268.1441956	58.27
268.8572693	0.18
275.1070557	0.09
276.0405884	0.04
278.0708618	0.03
280.1055298	0.08
282.9756775	0.03
288.4707642	0.01
305.5567627	0.14
306.2252808	0.40
307.2271729	0.06
308.3327637	0.08
317.6550293	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.17
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0559082	0.25
188.9989319	0.28
193.0210724	0.10
194.2474060	0.03
194.9836426	0.12
195.9977264	0.11
198.9164429	0.33
205.1261292	0.92
206.1613617	0.16
207.1318054	0.13
208.1887360	0.24
209.1561890	0.05
224.8581543	0.16
226.0664825	0.30
235.8730469	0.02
237.8514709	0.02
252.0654602	0.09
267.1734009	0.03
270.1269836	0.21
272.2040100	0.03
273.0792847	0.06
280.0983276	0.05
284.1647339	0.08
285.3394775	0.11
288.1478882	0.19
295.0195923	0.23
296.0122681	0.31
297.1472473	0.06
301.1060791	1.69
303.1317749	8.15
307.0259399	0.11
308.1822510	0.08
311.2055969	0.12
313.1267090	7.87
319.1060791	0.21
320.0733643	0.07
321.0235901	0.10
322.2478027	0.31
325.1342468	57.84
326.1588745	0.69
329.2371826	0.34
331.7343140	0.05
337.0816040	0.02
340.8914795	0.03
343.0581055	64.73
343.6766968	0.24
346.1683350	0.73
347.1660767	0.28
349.7093506	0.03
355.5838623	0.08
362.3693237	0.11
364.0609131	1.30
365.0772705	0.29
370.9790039	0.08
383.1330566	1.81
388.0361938	0.10
396.0618896	0.17
406.0525513	0.10
424.2291260	0.05
430.3057861	0.32
442.3698120	0.24
445.1231689	0.14
446.0808105	0.56
453.6460571	0.17
454.2581177	2.87
455.0679321	0.02
461.3222656	0.04
463.1722412	78.82
464.1969604	0.35
466.0065918	0.39
472.1229248	82.38
472.7627563	0.30
481.0892334	100.00
481.7127686	0.85
482.4037476	0.10
485.4010620	0.16
503.2151489	3.20
521.2017822	17.18
529.2083130	0.08
546.9441528	0.32
556.2120972	0.17
563.9578247	0.04
568.8543091	0.05
573.9661255	0.69
575.3690186	0.06
592.1685791	18.22
593.0919189	0.29
600.8812866	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	388.94
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0309372	0.02
159.0969238	0.85
159.9902649	0.12
160.9351196	0.45
228.8159485	0.11
230.9196167	0.20
239.1343994	0.03
271.1463013	0.15
272.9819336	44.99
274.0812378	17.68
275.0122986	100.00
277.1446533	0.04
286.2288208	0.04
294.2771606	0.05
300.8598633	0.10
315.1218262	0.27
324.5654907	0.02
329.0493774	0.05
333.0524292	0.06
342.9076233	0.89
344.3427124	0.07
345.0582581	0.37
345.8732605	0.13
360.8792419	0.06
370.9588928	0.47
372.3348083	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	924
Annotation	Unknow
Peak:m/z	Relative Intensity
256.8831787	0.28
267.1822815	0.40
269.0314331	0.32
271.4081421	0.11
273.2324219	0.07
277.3355408	0.08
281.2511902	0.92
283.2776489	0.95
285.1516113	0.12
287.2510681	0.30
295.2274780	0.42
297.0450745	0.28
299.2724915	0.14
302.9101868	0.17
309.1542969	0.06
311.2599792	0.45
313.4477844	1.04
315.2246094	0.21
320.5518799	0.11
321.2728882	0.40
323.2212524	0.14
325.3658142	0.05
327.1475220	0.50
329.2073975	0.04
333.0376587	0.14
335.3715820	0.43
337.1708984	0.22
339.3706055	0.62
341.2303467	0.06
349.4041138	0.27
351.2741089	0.30
359.2603149	0.15
361.2577820	0.19
363.4280396	0.12
365.3791809	5.57
367.5794678	0.31
375.4421692	0.26
379.4716797	0.19
383.2167969	0.11
387.4794922	0.29
389.5339966	0.25
391.5916138	0.05
392.4171753	0.10
393.4138794	1.02
395.4119263	1.13
403.5710754	0.50
405.4185181	23.33
407.1171265	0.49
407.7244568	0.13
417.3173828	0.48
419.2389526	0.14
421.3958130	0.30
423.3925171	100.00
433.3202515	0.87
435.5856323	0.23
437.2528076	0.15
438.8071289	0.07
439.4982300	0.15
441.1680908	8.98
441.8417969	0.04
445.1114502	0.44
450.8234253	0.79
451.5234985	0.95
457.3764648	0.13
459.3958740	0.12
469.3386841	0.29
471.3651123	0.45
487.4183350	0.20
508.9890137	1.32
535.5321045	0.16
537.2422485	0.63
545.7015991	0.18
549.1658325	9.49
549.8582153	0.16
553.2967529	0.05
557.0180054	0.05
563.6359863	0.24
566.3690796	5.09
567.0855103	48.92
581.2939453	77.25
581.9492188	0.23
584.9049683	10.23
585.6712036	0.03
599.2635498	21.73
600.0419312	0.41
615.8775635	0.20
617.1867065	0.64
641.2459717	0.15
661.2496338	0.10
671.6176147	0.14
677.5701294	0.06
689.2745361	0.25
697.3648071	0.09
707.5101929	0.37
721.5195923	0.13
725.0726929	85.51
725.8357544	0.08
729.2210693	0.81
740.9890747	0.11
742.9647827	24.90
743.7750854	0.05
746.8604126	0.47
747.5484619	0.12
750.0640869	0.06
759.2424927	0.35
760.2874756	0.35
760.9192505	3.24
761.6015015	0.14
780.5365601	0.04
787.4572144	0.08
791.5975342	0.05
851.1234741	0.10
868.9280396	0.06
873.4058228	0.13
886.9539795	0.24
904.8827515	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.0699
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
94.9225540	0.16
106.9174652	1.50
111.1529999	0.03
116.8807526	0.06
119.1030960	0.05
120.9114990	0.30
123.2223587	0.14
126.9846802	0.60
131.0478516	0.03
134.9810791	0.19
139.0830078	0.07
141.2888336	0.03
143.9912720	0.04
145.1521606	0.05
148.0715942	0.12
148.9867859	1.68
151.1226654	0.14
152.9244537	50.27
155.0279846	0.41
156.0909424	0.08
158.1352081	0.05
158.9353180	0.01
160.9822693	0.01
163.0745850	0.35
165.1874695	0.04
166.9676819	0.06
171.1413422	0.49
173.1352844	0.03
175.2431335	0.09
177.1529999	0.13
179.0368500	0.11
182.9664001	0.19
185.0254211	0.06
187.2101898	0.04
188.0760040	0.07
188.8728638	0.10
191.2200928	0.03
193.0950623	0.03
194.9693298	9.81
200.0470886	0.02
200.9647217	0.03
203.1701355	0.10
211.1612244	0.08
213.1632080	0.02
215.2316284	0.29
217.1321716	1.54
217.7370605	0.04
222.8708191	0.10
224.9479370	0.09
226.0602417	0.08
227.0444641	0.08
229.2113037	0.25
231.0998535	0.08
233.1856995	0.07
235.2444763	0.05
236.1735840	0.15
243.0503540	49.06
243.8413086	0.01
245.0921021	0.25
245.8426208	0.02
247.8819275	0.02
252.6260986	0.22
253.3414307	0.42
257.0475769	0.08
259.3264465	0.16
260.9902344	0.78
262.1344604	0.06
268.1210632	0.12
271.0852051	100.00
271.8800049	0.09
273.3020630	0.03
279.6692505	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2658
Annotation	Dendroside D
Peak:m/z	Relative Intensity
166.9595337	0.04
170.9680023	0.09
175.0925903	0.07
177.2361450	0.02
178.9952393	3.65
183.2882690	0.05
190.1625214	0.05
193.0520020	0.36
200.0486603	0.13
200.8665161	0.02
202.9753418	0.05
204.1134338	0.05
205.1371155	0.16
213.2423706	0.06
217.0764771	0.17
222.9459839	0.03
224.9658966	0.14
233.1367188	0.03
241.0598755	0.02
245.0715942	0.08
245.9076385	0.05
247.2744446	0.02
253.2516479	0.02
256.9353943	0.24
258.9945068	0.14
263.2120361	0.03
268.3402100	0.26
269.1801147	0.06
271.1659241	0.34
273.2246094	0.26
285.2291260	0.20
286.4030762	0.12
287.1712646	0.21
289.1544800	0.36
290.2835693	0.21
291.3428955	0.05
297.1191406	0.03
299.1842041	0.25
301.1118164	0.42
303.1947021	3.41
310.0608521	0.07
311.3154602	0.11
313.0568542	0.26
314.1817017	0.04
316.9176941	0.10
320.1106873	0.41
321.1797485	0.52
325.0598755	0.10
327.1787720	0.11
329.0152588	0.04
330.3556519	0.04
331.3290405	0.16
337.0027466	0.09
341.4127808	0.07
343.2997437	0.10
345.2532349	0.03
347.3461304	0.19
353.2640991	0.06
355.1384277	0.06
356.3852539	0.06
365.3215942	6.17
366.9998169	0.04
377.1087036	0.05
383.2498779	100.00
383.8558350	0.61
392.9999390	0.06
395.1505127	0.31
397.3111572	0.14
403.0703125	0.15
405.0157471	0.11
407.2196045	0.85
411.1236572	1.51
413.0512085	0.02
415.3106689	3.70
421.0974121	3.16
423.1240234	1.46
424.8633423	1.18
426.9235840	0.05
429.3021240	0.22
434.2342529	0.35
435.0086060	0.07
437.1881104	0.71
439.1419678	26.92
441.1416016	0.53
447.0233765	0.23
449.2772217	0.12
450.2501831	0.67
451.1879272	1.92
453.1618652	0.21
455.1069336	2.61
457.3762207	0.05
462.3339233	0.05
463.3756714	0.19
465.1744385	2.08
468.1820679	0.23
469.2787476	0.31
471.2670288	0.12
477.1361084	0.07
484.4806519	0.42
485.1469727	3.05
486.3130493	0.10
487.1466064	0.04
491.2344971	0.02
507.3121948	0.03
511.6190186	0.04
515.1119995	0.03
529.3269653	0.89
531.4057007	0.22
542.8212280	0.04
545.0513916	6.64
547.3681030	2.11
548.6698608	0.09
549.4393311	0.05
555.1455078	0.74
555.8026733	0.04
559.3724976	0.20
560.9741211	0.21
561.6519775	0.05
562.2979126	0.07
572.6853027	0.66
573.3074341	3.25
582.1508789	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2966
Annotation	Dicliripariside A
Peak:m/z	Relative Intensity
208.2518616	0.03
241.1372223	0.06
243.3638000	0.11
258.9818115	0.24
261.1008301	0.04
269.0562744	0.03
271.1850891	0.31
273.2918701	0.05
284.9631042	0.03
287.2556763	0.18
299.2302856	0.54
315.2585449	0.26
317.2334290	100.00
319.0263062	0.21
329.2965088	0.06
337.1615906	2.62
343.3848267	0.04
385.2703247	0.06
389.0072021	0.06
407.1821289	0.05
460.4066162	0.06
472.3037109	0.09
479.2133789	0.17
491.6099243	0.02
493.3745728	0.24
505.4153442	0.06
509.4273071	0.02
511.2969360	0.03
512.0110474	0.05
531.6523438	0.02
542.3989868	0.03
553.2764893	0.09
559.1634521	0.15
567.3424683	0.06
575.1322632	0.11
579.2880249	0.16
581.2316284	0.08
587.2069702	0.04
594.0748901	0.28
595.2343140	0.17
609.0692749	0.14
611.2398071	0.48
616.9956665	0.05
619.5092163	0.11
623.3544312	0.19
632.4876709	0.06
637.3037720	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	146.12
Annotation	1-Nitroheptane
Peak:m/z	Relative Intensity
97.8354645	0.08
100.0119781	100.00
100.9211121	0.10
129.0687256	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.88774872	0.14
94.98914337	0.34
104.7572556	0.09
107.0251236	0.72
109.0259628	0.12
116.0025711	0.08
119.0401459	0.25
121.1376038	0.46
122.9563141	0.18
123.9534683	0.04
127.0739212	0.42
131.0340881	0.30
135.0104828	0.34
138.9943542	0.04
143.0116577	0.15
144.8727112	0.02
147.1087341	0.22
149.1348572	0.52
149.9035187	0.09
150.9503784	0.82
154.8953094	0.36
157.0444031	0.41
159.1358643	0.30
161.0414429	0.08
163.0485382	0.38
165.1237183	0.31
166.125824	0.08
169.0820465	0.18
170.9989929	0.94
172.9516144	0.24
175.1385498	0.48
176.2645874	0.30
176.9864807	0.21
179.0519714	0.22
179.8442841	0.09
181.0639038	0.21
183.1079407	0.34
185.1549988	0.04
186.3365784	0.22
187.2742615	0.25
190.9690247	0.83
195.125351	0.86
197.1903381	0.67
198.9880829	0.35
203.0123291	0.19
204.9473267	0.43
207.026123	0.45
208.0010071	0.17
209.2815552	0.16
211.1062622	0.42
212.9597778	1.72
215.2276306	0.58
216.6447754	0.30
219.1573792	0.43
221.1490479	0.52
223.205719	1.12
225.4165649	0.59
227.0606079	0.45
228.9831848	0.18
230.9645691	0.08
233.004303	0.65
235.1961975	4.24
237.1826172	0.72
238.9691162	1.53
241.1495056	0.20
247.369751	0.31
249.2897949	0.87
250.0467224	0.04
251.0379028	1.13
252.0029907	0.08
253.2211914	0.62
254.1772461	0.22
255.0619507	0.15
257.1733398	4.06
261.9646606	0.13
262.9236145	0.07
265.2582397	0.53
266.2251892	0.15
267.0188599	0.63
269.2271729	0.41
270.0648804	0.12
275.2531128	48.24
276.190094	0.19
277.2727661	0.23
278.9569092	0.12
279.9364624	0.26
280.9448547	0.20
283.1949463	0.63
284.1887817	0.03
293.2033691	100.00
294.1827393	0.12
301.9573364	0.57
311.3726196	0.29
312.8409424	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.1921
Annotation	Methionyl-Glutamate
Peak:m/z	Relative Intensity
168.0799103	0.29
186.0052338	0.02
213.1818237	0.12
214.8880463	0.07
216.1141968	0.38
261.1413269	0.38
262.0928040	1.24
279.0604248	100.00
279.6720581	0.14
290.9973145	0.02
428.1683960	0.03
437.2175903	0.04
449.2864380	0.04
452.9061279	0.04
485.1995850	0.03
493.4219971	0.34
496.8899536	0.04
510.9505615	0.07
516.0574951	0.10
533.2256470	0.03
538.5065918	0.07
539.2437134	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.3392
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
225.2213440	0.06
272.0180969	0.09
316.9339600	0.12
319.9585876	0.16
322.1054382	0.09
341.3555603	0.03
353.2048950	0.04
368.5693970	0.19
369.3115234	0.05
373.1167603	0.07
375.3536987	0.05
375.9569092	0.06
387.2030029	100.00
388.2370605	0.28
389.1968994	0.59
398.2139893	0.15
415.0083618	0.08
418.8701782	0.24
433.0490723	0.02
447.0551758	0.09
455.4534912	0.05
461.2402344	0.04
467.0696411	0.06
487.4336548	0.06
490.2082520	0.37
504.8732910	0.22
507.2604370	0.19
529.3565674	0.17
541.3531494	0.03
551.2557983	0.13
561.2145996	0.07
564.2246704	0.11
565.3473511	0.03
574.3422852	0.07
580.2124634	0.05
598.9876099	0.18
613.1358032	0.04
627.2767944	0.10
635.1898804	0.09
637.3513794	0.12
647.5359497	0.10
653.4688110	0.16
655.1680298	0.80
658.9980469	0.11
683.4275513	0.29
684.1528931	0.40
685.4121704	0.10
686.4723511	0.14
687.1488647	0.05
714.1826782	0.10
718.8388062	0.09
722.4803467	0.04
726.3777466	0.04
727.3592529	0.07
730.5296021	0.13
731.3833618	0.55
736.8096313	0.07
739.0696411	0.28
744.1162720	0.07
755.2844238	0.04
757.3919678	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.386
Annotation	PS(12:0/12:0)
Peak:m/z	Relative Intensity
176.2384491	0.13
189.1580200	0.02
192.9783478	0.07
193.9803162	0.04
207.2738037	0.06
213.9981384	0.14
217.1672668	0.02
227.0748749	1.48
245.1797485	0.53
274.1891479	0.07
280.8198853	0.08
284.3312378	0.04
286.5192871	0.09
289.4040527	0.03
292.0819702	0.04
300.9373779	0.07
307.0328674	0.35
313.7884521	0.04
318.3598022	0.13
321.1401367	0.05
322.1811523	0.07
323.1489868	0.08
325.0279541	0.21
327.3365479	0.04
329.9221497	0.08
335.4680786	0.10
344.7201538	0.03
347.4158325	0.10
349.3737183	0.11
352.2656250	0.10
354.2093506	0.09
366.4099731	0.04
368.1121826	0.23
375.2028809	0.07
379.3100586	0.25
384.4421997	0.08
386.2673950	0.10
389.3344116	0.10
393.3354492	0.20
394.1553955	0.10
395.4655151	0.03
396.5159302	0.02
410.4063721	0.10
418.3795166	0.10
419.5998535	0.09
431.3348389	0.22
436.2562256	0.18
437.2736206	0.06
439.3884888	0.03
440.4476929	0.17
441.5800781	0.05
449.3038940	0.05
451.6140747	0.05
452.3342285	0.07
454.3288574	0.25
459.5347900	0.04
465.4425049	0.02
470.2231445	0.05
476.6307373	0.06
480.3603516	0.02
481.5316772	0.03
483.3726807	100.00
484.0225830	0.34
487.3010254	0.02
495.1799316	0.15
508.1306763	0.13
515.6962280	0.03
524.8866577	0.04
526.5687866	0.03
529.6323242	0.06
537.4502563	0.05
540.4404907	0.07
541.2621460	0.09
546.2067261	0.05
547.0408936	0.05
547.9141235	0.15
557.6459351	0.12
560.7391968	0.04
561.4495850	0.02
563.2648315	0.50
567.8411255	0.17
568.6383057	0.09
575.3374634	0.32
577.9840698	0.12
579.2944336	0.03
579.9268188	0.13
581.2675171	0.05
588.6907959	0.13
592.4733887	0.06
593.2487183	0.23
596.3510742	0.13
605.2692261	0.10
606.4843750	1.81
607.6660767	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
107.0174408	0.01
119.9518890	100.00
130.9639740	0.24
146.9356842	0.04
147.8817596	0.56
148.9956818	4.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	190.98
Annotation	Unknow
Peak:m/z	Relative Intensity
57.9569626	0.01
58.9907455	0.04
72.9248810	0.02
80.8892059	0.04
84.0083084	0.06
91.0438919	0.01
101.0456238	0.01
108.6869659	0.01
111.0034180	0.08
114.7416077	0.02
118.0654449	0.02
119.0940704	0.07
121.0462799	0.02
129.2112427	0.03
130.1024017	0.04
131.8010559	0.03
133.0577087	0.03
135.2723846	0.01
140.0827484	0.02
141.7932739	0.22
145.0666809	0.06
146.0633240	0.08
147.0425568	0.13
149.9420319	100.00
150.6688995	0.02
154.7830505	0.02
160.7539368	0.07
163.2158051	0.13
167.9076538	1.13
170.1866608	1.81
173.0122833	0.73
173.7385406	0.02
178.8314056	0.25
179.4920807	0.13
181.8539734	0.12
182.6939850	0.03
190.9893951	0.05
201.0509186	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.268
Annotation	Menisporopsin A
Peak:m/z	Relative Intensity
341.0795898	0.26
383.1610718	0.07
412.7445679	0.11
442.6321411	0.10
443.3260498	0.16
473.4302979	0.03
485.1564331	0.11
503.1074219	0.44
515.2603760	0.06
665.3264771	100.00
750.9138794	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	798.4563
Annotation	Unknow
Peak:m/z	Relative Intensity
233.2986755	0.28
235.3013306	0.74
237.3931274	0.30
245.4227295	0.13
247.3380890	1.84
248.4924011	0.28
249.1434326	0.35
251.1375427	0.15
255.3667145	0.14
256.1646118	0.39
262.1626587	0.06
263.3902588	0.33
267.0522461	0.06
273.3031616	3.21
275.2355347	0.17
277.1682129	0.89
279.1773682	0.22
281.2366943	0.11
287.4802246	0.11
289.2195129	0.66
291.2179260	100.00
292.2581787	0.25
293.2801208	1.12
295.1453857	0.08
297.5049438	0.04
303.2460632	0.06
305.3632812	1.06
307.1503601	0.66
309.3173828	0.58
311.6415100	0.06
316.5532532	0.24
322.2400818	0.23
323.2785645	0.21
324.2534790	0.18
334.4405518	0.83
335.4233704	0.08
336.4977417	0.13
339.9727173	0.04
341.2603149	0.25
342.2996216	0.04
348.4452820	0.20
351.4735718	0.15
353.7642822	0.03
356.3843384	0.22
357.2677612	0.04
361.6552124	0.05
363.3911743	0.10
365.0485840	0.26
374.0441895	0.06
380.5341187	0.03
383.2243652	0.04
389.8963623	0.04
392.1083374	0.10
396.5000610	0.04
400.3275146	0.05
404.9111938	0.08
409.9925537	0.06
413.3261108	0.16
414.4163208	0.34
417.1987305	0.03
420.0677490	0.06
420.7610474	0.10
425.4754639	0.05
427.1892700	0.78
428.6907349	0.24
432.0852051	0.21
434.3436890	0.06
441.2005005	0.22
442.4100342	0.11
443.2614746	0.03
445.3113403	0.17
455.4862061	0.10
458.0711670	0.13
459.5043945	0.19
460.2699585	0.19
469.8464966	0.91
470.4556274	2.88
471.2403564	0.05
473.3975830	0.12
474.4650269	0.10
476.4452515	0.25
477.2894897	0.26
480.6934204	0.04
482.4730225	0.08
484.3305664	0.34
486.2183228	0.09
488.3391113	13.61
490.0808105	0.32
497.2828979	0.07
498.6115112	0.20
501.2060547	0.10
502.2175903	0.45
504.4361572	0.05
506.3701172	0.25
507.5006104	0.20
512.4511108	0.04
513.1704712	0.23
514.0466309	0.06
516.1983032	0.19
519.4906616	0.19
520.2939453	0.13
528.3265381	0.21
538.2026978	0.06
542.3282471	0.18
543.3032837	0.10
544.3645020	0.34
547.6455688	0.12
553.0308228	0.10
553.7561646	0.17
556.4940796	0.50
559.1835327	0.08
564.1417847	0.15
565.7407227	0.19
570.6295166	0.05
571.4619751	0.09
580.5837402	0.15
582.5258789	0.03
584.4279785	0.33
585.2542114	0.11
588.3840942	0.12
593.4531860	0.06
595.1862183	0.14
596.3643188	0.30
597.2393799	0.47
599.2546997	0.07
602.0568237	0.12
609.5053711	0.09
611.4354858	0.16
612.5980835	0.29
613.4860229	0.25
614.3969727	0.27
615.4933472	0.23
628.4891968	0.10
636.4120483	0.05
642.5761719	0.19
644.7251587	0.21
650.3030396	0.09
652.2910767	0.07
653.0685425	0.05
654.0128784	0.56
656.5073853	0.08
660.2820435	0.03
663.7065430	0.08
666.5985718	0.77
667.5508423	0.09
682.3118896	0.05
685.5567017	0.06
691.3650513	0.05
692.1212769	0.07
692.8850708	0.07
694.3233032	2.20
695.2774658	0.18
696.2235718	0.20
698.2014160	0.04
703.9995728	0.15
706.4212036	0.79
710.3254395	0.19
711.7047119	0.66
712.3688354	1.01
713.3807983	0.07
714.6620483	0.07
719.3831177	0.17
720.2559204	0.31
721.5347290	0.22
722.4546509	0.32
726.4502563	0.38
733.3149414	0.07
734.3956909	3.65
735.4264526	0.06
736.1654663	0.04
737.7175903	0.14
738.4258423	0.60
739.9136963	0.13
744.1956177	0.19
746.4722290	0.14
747.6818237	0.14
748.4303589	0.11
752.3861694	1.69
762.3963013	12.72
763.3452759	0.08
764.4268799	0.28
765.4970093	0.07
766.2473145	0.42
770.4328613	0.14
780.2290649	13.65
781.0484009	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1099.532
Annotation	Hoodigoside O
Peak:m/z	Relative Intensity
437.3845215	0.06
483.3587646	0.09
485.7425232	0.11
498.2683105	0.09
501.5176086	0.03
517.1652832	0.07
523.6019287	0.04
553.4916992	0.45
555.5076294	0.20
580.2905273	0.10
597.4444580	0.47
598.3337402	0.58
599.5222168	0.78
615.5693359	0.06
623.7062988	0.19
625.1475830	0.49
643.7809448	0.07
651.3086548	0.04
667.3775635	0.62
681.4210205	0.48
689.3322754	0.10
695.3353271	0.60
706.1276855	0.21
713.4595947	0.67
733.3168945	0.32
739.3442383	1.03
755.5857544	0.17
757.5327148	0.44
775.4082642	0.14
823.6416016	0.20
875.7149658	0.28
877.1793213	0.14
893.7430420	0.16
895.4868164	0.07
923.4350586	0.24
935.9617920	0.06
937.7836914	0.06
939.2430420	1.52
939.8508301	0.11
941.3371582	0.49
955.7619629	0.19
957.4597168	25.61
958.3132324	0.27
959.3262939	0.94
965.3411865	0.21
967.5095215	2.29
976.3801270	0.06
980.7429199	0.06
983.5473633	0.62
985.4282227	100.00
986.0895996	0.28
993.0975342	0.07
999.4432373	0.12
1008.9714360	0.05
1010.1865230	0.17
1011.6369630	0.14
1037.4251710	1.50
1051.4517820	0.15
1055.5109860	19.94
1057.4913330	0.46
1079.8638920	0.08
1081.3148190	6.71
1081.9871830	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.06
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
80.9985962	0.05
92.9580765	0.07
107.0472107	1.31
123.7937927	0.35
124.9960556	2.80
128.9544983	0.06
130.9219360	0.08
135.0712891	2.25
136.9415283	0.16
141.1576233	0.05
148.9178009	0.07
150.9688263	100.00
154.8215179	0.16
159.0500183	0.08
160.0769348	0.16
161.0457153	0.82
167.1127777	0.08
177.0894775	0.26
179.2952881	0.09
185.1375580	0.06
189.2166748	0.07
193.3961792	0.03
199.4581909	0.06
200.9682922	0.27
202.9371643	0.12
207.1571350	0.42
214.8833618	0.06
219.1714783	0.08
225.3080750	0.58
227.1592407	0.84
229.1069031	1.05
233.0843201	0.04
241.1056213	0.18
243.0947266	3.48
245.1352539	0.08
251.1132202	0.54
253.0208740	0.30
259.1923828	5.35
267.1050110	0.12
269.1947021	6.25
271.1224060	0.41
297.1898499	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
126.9332962	0.07
131.3223724	0.03
165.0484314	0.01
173.0627136	0.00
187.4046021	0.01
197.2203674	0.01
199.2289581	0.00
227.1379089	0.03
228.9576721	0.04
240.039856	0.01
249.3643494	0.01
253.0177002	0.01
255.2445679	0.05
271.0635071	100.00
271.6824341	0.23
273.1384583	0.03
279.4777222	0.02
280.3855286	0.00
283.1592102	0.02
286.335144	0.01
289.069519	0.08
303.0620117	0.10
304.1773682	0.32
317.1783447	0.04
321.0202026	0.04
348.0028076	0.02
382.2460327	0.02
388.465332	0.02
397.2322388	0.01
402.9901123	0.01
405.2540588	0.02
414.7339478	0.06
415.4993591	0.01
421.3058777	0.01
423.8641663	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	450.26
Annotation	PE(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9534760	0.05
196.1098022	1.62
206.9739990	0.04
214.1336212	1.89
253.2614746	100.00
288.4346313	0.04
336.1473999	0.06
389.3615417	0.35
404.2125549	0.11
410.3509827	0.03
432.7358093	0.09
433.8398438	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.18
Annotation	3,5,7,3',4'-Pentahydroxy-6-methoxyflavan 3-O-[glucopyranosyl-(4->1)-alpha-D-xylopyranoside]
Peak:m/z	Relative Intensity
174.9627228	0.59
179.0311584	0.24
186.1248016	0.09
187.1766968	0.45
188.2021637	0.26
191.0903015	0.31
193.1555634	0.27
198.8551025	0.05
202.1708221	0.19
203.0477448	2.92
205.0790253	1.58
208.9351807	0.06
211.2260895	0.05
217.0455933	0.14
218.1735840	0.03
221.3117371	0.05
227.0324402	0.97
228.1972046	0.19
229.0168152	0.08
230.1012726	0.25
230.9417877	0.11
245.0703583	9.21
247.0822144	0.90
253.1347046	0.10
255.1159668	0.05
256.0347290	0.16
263.1316528	0.21
271.1590271	0.66
273.0735474	0.22
274.0608521	0.21
275.1058044	0.90
289.0517273	100.00
290.3073730	0.05
302.1502075	0.07
304.3181458	0.11
309.5698853	0.15
313.1823120	0.34
315.0027161	0.05
337.3045044	0.10
338.1468506	0.03
345.2096558	0.30
355.0359497	0.40
371.3938599	0.10
378.9059448	0.07
397.3037109	0.11
405.3749390	0.11
431.3135986	0.12
449.3610229	0.35
451.0409546	0.94
452.2916870	0.10
461.2053833	7.69
465.0913086	0.07
476.9802856	0.21
479.0256348	0.12
484.2282104	0.12
489.3239746	0.36
491.1810913	0.26
517.3851929	0.09
527.3447876	0.11
529.2954102	0.23
555.2364502	0.06
567.2035522	0.18
569.2183228	0.41
577.1709595	0.29
578.3223877	0.04
585.3298340	0.09
594.9485474	0.64
595.5722046	0.73
596.4796753	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1974
Annotation	Manumycin G
Peak:m/z	Relative Intensity
145.0961914	0.14
145.9282074	1.07
151.1461334	0.61
153.1192169	3.04
167.0715485	0.24
171.1864166	1.23
179.0609589	1.11
179.9751587	0.25
181.0656738	0.81
197.0667419	3.44
223.1389923	5.48
223.8318481	0.06
227.3373566	0.24
239.1814270	0.53
241.1740417	19.56
242.2773438	0.19
245.0113220	24.67
248.1391296	0.38
259.1161499	2.73
263.2060242	3.31
264.3884583	0.62
266.1235046	2.21
284.2290344	1.09
292.2982788	0.83
297.4851990	0.12
301.0563354	0.10
308.2700500	0.23
310.1663208	3.60
315.1511230	0.10
328.1307373	0.94
334.0201111	0.17
339.6127930	0.53
341.2747192	0.57
351.3189087	0.62
352.2759094	2.32
358.0599976	3.62
358.7175903	0.26
369.2573547	15.76
370.2588501	3.59
376.2701721	6.98
384.9303589	0.21
388.5079041	0.37
395.2986145	8.39
413.2214966	25.45
413.9459839	0.23
439.2548828	16.46
440.1416321	0.45
443.3502808	1.61
451.4436951	0.50
457.2708435	77.41
461.3671875	0.45
469.2427063	3.52
470.3786926	0.11
487.2601929	100.00
488.2431335	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.1636
Annotation	Unknow
Peak:m/z	Relative Intensity
157.9916229	0.62
174.9769287	100.00
232.9556427	0.16
341.6109619	0.09
383.9121704	0.15
431.0556641	0.12
474.1743164	0.98
498.9504395	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	676.28
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9594269	0.04
205.0925751	0.07
208.1951447	0.04
227.8878479	0.10
235.4326172	0.13
238.1368713	0.23
243.5354004	0.03
245.1929016	0.09
246.2676544	1.06
262.1618652	0.03
270.1605225	0.07
272.1634521	0.30
274.4356995	0.06
281.3879395	0.10
290.1918335	4.16
297.3442383	0.11
301.3507385	0.11
308.1559448	0.47
316.2833252	0.12
323.1909180	0.07
329.1478577	0.10
333.6260376	1.25
334.2873535	4.59
340.9992676	0.04
352.1785278	30.51
352.9203491	0.02
357.0496216	0.06
358.3433228	0.11
362.2469482	0.06
364.0321655	0.32
373.9530029	0.06
376.3619385	1.02
388.2236328	0.38
392.5438843	0.03
394.1634521	2.14
395.1306152	0.06
406.2458496	0.52
416.7285767	0.04
418.3347168	0.57
421.2955322	0.06
424.0827637	3.28
436.3754272	0.84
454.2498169	18.56
460.3735962	0.25
478.1950684	0.12
480.2281494	0.16
484.3455811	0.51
495.6213989	0.23
496.3431396	0.86
500.3389893	0.10
505.1035156	0.07
514.2107544	100.00
514.8360596	0.21
529.4238892	0.06
531.2133789	0.06
532.3809204	0.10
545.3421021	0.06
573.9923706	0.19
576.5050659	0.07
601.0764160	0.30
615.4129028	0.32
629.1660156	0.10
630.0379028	0.30
644.0360107	0.42
658.0975952	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2142
Annotation	Stachyose
Peak:m/z	Relative Intensity
221.0161743	5.46
232.4036407	0.30
250.1412354	0.63
250.9048157	0.33
263.0922852	0.12
268.0595703	0.11
280.7589722	1.25
305.1221313	1.88
321.1408081	0.83
322.9519653	3.53
341.0650024	32.21
346.8961182	0.42
365.2250366	0.44
376.8585815	0.18
383.1149902	100.00
385.2044678	1.41
407.1654663	0.57
412.8532715	3.76
425.2460327	2.10
434.2188721	0.85
442.9682617	9.91
467.2773438	0.60
485.2016602	31.53
489.878479	0.59
492.2033691	0.44
498.2412109	0.09
502.2084961	0.38
502.9796753	3.63
514.1273804	0.38
526.774353	0.69
536.1445923	0.26
545.0523071	1.64
645.0545044	0.51
647.4292603	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.1955
Annotation	Unknow
Peak:m/z	Relative Intensity
144.6771698	0.06
162.9175415	8.69
164.0709534	0.20
170.9458771	1.10
181.1104279	0.10
198.7755127	0.15
200.8885498	0.07
218.4086914	0.07
219.1575317	0.04
236.9970703	1.73
237.9669495	0.09
253.2531738	0.10
254.9133759	100.00
256.0172424	1.45
257.1571045	0.08
288.5483398	0.21
295.9794312	0.14
307.0373535	0.26
322.8876343	0.09
324.7442627	5.46
325.9738159	0.67
342.6967163	0.37
362.8992310	0.15
381.0102539	0.17
415.0768433	0.64
416.7719727	49.98
417.9587402	3.14
430.1312256	0.14
456.4719849	0.16
458.1318970	0.05
469.3933716	0.03
484.1207886	0.14
531.7942505	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1195
Annotation	6-O-b-D-Fructofuranosyl-2-deoxy-D-glucose
Peak:m/z	Relative Intensity
112.8156815	0.24
119.0110016	0.74
124.8692474	0.22
128.0920410	0.13
130.9998474	0.19
142.9402008	0.11
146.9537964	0.17
160.8767700	0.37
179.0447083	0.12
191.1527710	0.08
193.0482788	0.06
218.8186951	0.23
224.9627991	0.28
238.7702026	0.13
242.2246094	0.17
251.1722107	0.06
260.6413574	0.21
262.8565063	0.21
281.2640381	0.07
307.2685852	2.22
309.0650635	0.07
313.4311523	0.12
325.1065063	100.00
327.0529175	0.17
335.2577820	0.06
353.1269531	1.05
356.1907349	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.4763
Annotation	PE(16:1(9Z)/20:5(5Z,8Z,11Z,14Z,17Z))
Peak:m/z	Relative Intensity
223.0096130	0.06
233.2476654	0.62
257.2390747	0.03
259.2035522	0.11
261.5169373	0.16
275.2878418	1.00
277.2191772	100.00
277.8745422	0.25
281.2249146	0.08
413.4076538	0.03
456.2398071	1.40
474.3223267	14.77
526.5524902	0.04
646.0421753	0.07
672.6042480	0.09
673.5299683	0.03
675.4056396	0.05
716.3657837	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.3845
Annotation	PS(12:0/12:0)
Peak:m/z	Relative Intensity
183.8237152	0.09
196.3442993	0.07
227.0925446	3.68
245.2738647	0.24
270.2680664	0.10
282.2351379	0.09
296.0542908	0.17
307.1856995	0.28
310.6283569	0.03
313.2901611	0.35
368.2131348	0.15
386.1055298	0.05
386.7374268	0.05
417.7834473	0.31
418.4913940	0.17
431.9428711	0.05
436.3596802	0.34
444.3051147	0.15
454.1713867	0.31
464.2123413	0.04
471.1519775	0.06
483.3494873	100.00
484.0392456	0.34
486.3241577	0.09
488.3300171	0.12
498.6260376	0.04
503.3225708	0.12
510.1057129	0.26
532.4601440	0.35
539.1470947	0.06
542.0294800	0.25
551.4103394	0.08
552.7803345	0.05
559.6398926	0.05
563.4024658	0.41
569.5028076	0.15
574.6145630	0.27
576.0278931	0.10
577.1920776	0.10
578.0665283	0.05
579.3845825	0.14
580.8320923	0.19
581.4843140	0.04
582.7675171	0.10
583.8131714	0.17
587.2200317	0.15
592.6082153	0.18
596.2363892	0.02
597.1111450	0.11
599.2855225	0.07
601.3399048	0.37
602.4490356	0.13
606.4033813	0.94
607.1629028	0.09
608.2925415	0.50
613.7413330	0.07
615.2447510	0.28
623.5054321	0.32
624.3843994	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.1999
Annotation	7S,8S-DiHOTrE
Peak:m/z	Relative Intensity
78.8458862	0.95
79.8174896	0.13
81.0335770	1.85
82.9466629	0.76
84.9275742	0.27
90.8786697	6.95
92.9224930	1.67
95.0248871	4.56
96.9848404	1.41
98.6000671	0.20
101.1095734	0.28
103.0243988	0.71
104.9718628	13.08
106.5048828	0.65
107.1079025	2.01
108.3664856	0.29
108.9790573	3.10
110.9633789	0.88
112.9215546	0.91
117.0022278	3.14
118.9814301	12.06
119.5837631	0.25
121.0918503	4.45
123.0276489	1.37
125.0156250	0.62
128.9638824	1.68
130.9699097	10.63
133.0072632	22.93
134.0027466	0.18
135.0836639	4.63
136.8880463	1.13
138.9043732	0.46
141.0997314	0.80
141.9348755	0.13
143.1225586	1.49
144.9849243	23.61
147.0574036	27.93
149.0186768	5.73
150.9781647	0.91
153.1043701	0.73
155.0513306	3.24
157.0512085	7.06
159.0810852	26.46
159.8914948	0.37
161.0893402	19.11
163.1154633	2.49
165.0330811	2.43
166.9589844	0.62
169.0870056	5.39
171.1350708	7.13
173.0989227	22.94
174.0411072	0.34
175.1756897	5.63
177.0101318	2.65
179.0852356	0.43
180.9822693	0.92
183.1253204	6.49
185.1539917	3.17
185.9275208	0.36
187.0769653	5.86
189.0204163	1.73
191.0817566	1.99
193.1130371	2.01
195.0867615	0.96
197.0878296	12.74
199.1610107	1.47
201.1008301	4.58
203.2620544	0.90
205.1865540	2.21
207.0870361	2.47
209.1732178	0.39
211.1887512	6.47
213.2308655	3.64
215.1704712	6.17
217.0916748	0.35
219.1876221	5.00
224.2896118	0.09
227.1542358	0.10
229.1167908	18.79
229.7788391	0.05
231.1178589	0.37
233.0742798	5.27
235.9210205	0.07
237.2969055	0.28
239.1784058	43.41
245.1907043	0.30
247.2413635	11.75
255.6207581	0.10
257.2234497	100.00
265.4201355	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.2119
Annotation	Unknow
Peak:m/z	Relative Intensity
242.8795776	0.07
255.0321503	0.05
257.3906555	0.05
263.0697021	0.03
266.7981567	0.07
269.1365662	0.04
276.0767517	0.07
277.3681946	0.43
281.1323547	0.09
285.0410767	0.10
287.0054932	0.16
289.1644592	0.52
293.1983337	0.04
294.8838806	0.06
296.2071838	0.03
297.2420349	0.10
299.0400696	0.92
301.0322266	0.12
309.2216797	0.06
311.0943909	0.05
336.4305115	0.05
339.1831055	0.04
347.1984558	0.05
365.0317383	0.08
373.4152832	0.08
381.3877563	0.05
386.2300415	0.06
393.0082397	0.06
400.3269653	0.04
401.3005371	0.02
407.0403442	0.35
413.3079834	0.43
417.0040894	0.01
419.2249756	10.79
422.1281738	0.06
425.1732788	0.06
427.3209839	0.07
428.0203247	0.07
428.8858032	0.09
433.3020630	0.04
437.2196655	29.21
438.1768799	0.02
447.1366577	0.10
451.1512451	1.71
453.1530151	0.07
463.1651611	0.14
472.1442871	0.03
479.3046265	0.03
511.2864380	0.06
545.2341919	0.12
553.1663208	0.05
558.2562256	0.39
559.2408447	2.26
563.3137207	0.07
566.6400757	0.06
571.2627563	0.47
573.0468140	0.37
575.2668457	0.36
577.1577759	0.81
580.9953003	0.05
587.1445923	0.03
589.0923462	100.00
589.7622681	0.24
593.1939087	0.14
607.2731934	0.04
638.2103882	0.10
691.2630005	0.12
701.3527832	0.03
708.2693481	0.04
718.0953979	13.71
722.9295044	0.03
733.2257080	0.25
735.3573608	0.08
753.0935669	0.15
768.0593872	0.15
781.0788574	0.09
785.2570190	0.05
788.8366089	0.09
791.3234863	0.08
805.3281860	0.04
809.2899780	0.21
821.2591553	0.05
823.2462158	0.06
830.1403198	0.14
835.0266113	0.95
835.6842651	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.0881
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9053040	1.37
143.4129333	0.15
147.0187073	2.64
173.0497284	1.50
175.3996582	0.05
190.9752502	100.00
196.1389008	0.05
209.0608673	14.56
223.1288757	1.00
291.0461426	0.11
311.9580688	0.04
315.0638428	0.23
340.9423218	0.07
353.2280273	0.07
379.1215210	0.27
384.4247742	0.10
397.0258179	7.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.225
Annotation	Unknow
Peak:m/z	Relative Intensity
157.9984741	0.59
164.9934998	0.03
173.0625610	0.36
175.9567108	1.53
191.0940247	0.35
193.0566559	1.72
194.0690918	0.05
203.9916077	0.05
209.1224976	0.17
210.1785583	0.03
219.1511841	0.01
226.9891663	0.29
231.2975159	0.06
259.1770020	0.02
270.4104004	0.03
281.3726807	0.01
284.0764771	0.13
285.2830200	0.02
286.1078491	0.07
288.2957153	0.02
290.3263550	0.05
294.0583801	0.03
295.2777710	0.01
302.0975952	0.17
303.2143555	0.01
304.2662048	0.03
309.3093872	0.03
312.1671753	1.63
322.3528442	0.07
338.2521973	0.05
341.9925537	0.02
348.0701294	0.29
366.1709595	0.71
378.1072388	0.01
383.9396973	0.91
384.5399170	0.09
385.5256958	0.20
386.4050903	0.07
387.2713013	0.02
399.5552979	0.01
401.2083130	6.93
402.1628418	5.76
419.2064819	100.00
419.8496094	0.19
422.6034546	0.02
432.1720581	0.05
441.1310425	0.21
459.3103027	6.05
485.3220825	0.03
501.3652954	0.01
502.0632324	0.06
511.8131714	0.09
512.4635620	0.04
530.2836304	5.94
531.3131714	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	362.13
Annotation	Unknow
Peak:m/z	Relative Intensity
106.9099655	0.15
107.8276672	0.02
112.8679504	0.06
115.6666489	0.01
120.0554047	0.01
122.0176315	3.21
122.9020004	0.13
124.1494064	0.46
125.0490570	0.01
126.0191650	0.01
130.0214691	0.08
130.9128418	0.02
137.7772827	0.25
141.0589142	0.14
146.0336609	0.39
148.0574646	0.27
148.9821320	0.04
151.9700012	0.12
152.9530334	0.02
154.0753326	0.04
154.9353333	0.02
161.8517456	0.04
163.9634857	0.15
165.9888611	0.26
167.9027100	0.02
175.1463623	0.03
180.0602875	0.05
182.0573425	0.08
191.0012207	0.11
195.3847961	0.03
203.1176758	2.27
205.0466614	2.85
206.1394196	0.10
207.0830994	1.69
209.1073456	0.97
211.1522675	0.06
221.3944397	0.12
223.2768555	0.04
224.4050293	0.04
233.1177979	0.02
236.0329895	0.02
237.2072144	0.02
239.0465393	100.00
240.2339478	1.36
241.0292053	10.12
241.9517212	0.03
243.2015381	0.01
244.0472717	0.07
245.3681030	0.03
247.0821533	0.03
249.6379700	0.05
251.2274780	0.14
252.1291504	0.08
255.3399658	0.01
257.1757202	0.14
261.2956543	0.02
262.3209839	0.06
269.0762024	0.25
270.0799255	0.09
275.4423523	0.01
277.9551086	0.07
279.2120361	0.02
281.2268677	0.10
283.1413269	0.01
287.1405945	0.48
288.1397095	0.03
291.3787537	0.01
293.2070007	0.04
295.2049561	0.24
299.1106567	0.15
301.1438599	0.02
303.2743835	0.03
308.1479492	0.03
309.1901245	0.05
310.1864014	0.01
312.1390381	0.02
313.0538940	0.25
316.3499146	0.10
317.1750488	0.11
318.2886658	0.15
320.5768433	0.12
326.5715332	0.09
327.2198486	0.20
330.1593323	0.61
331.0531006	0.06
339.0373535	0.02
340.3135681	0.05
342.4111633	0.02
344.1726379	1.45
345.0780945	0.24
346.3605957	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1326
Annotation	Griselinoside
Peak:m/z	Relative Intensity
126.9270325	45.09
130.0129089	1.21
131.0777588	0.48
139.0695496	0.04
143.1635132	0.07
144.2881775	0.06
144.9416809	2.25
151.1183777	0.03
162.9152832	2.31
168.9747467	0.07
174.9935303	0.03
180.9790039	0.14
187.1019287	0.29
191.0895691	0.12
200.9442749	0.06
205.0474243	0.34
207.0745239	0.14
209.3264008	0.03
225.2649689	0.05
226.1579590	0.04
226.9437866	0.09
235.2598877	0.05
253.0484314	0.20
255.2367249	0.04
261.3708801	0.03
267.2982178	0.02
271.1111755	100.00
281.0845337	0.05
288.9125366	3.56
294.8710327	0.02
303.0723267	11.51
304.1001892	24.17
307.0458984	3.68
321.1015015	0.04
323.0165100	0.13
324.8235474	0.14
327.4099731	0.11
330.9906616	0.08
347.2534180	0.01
369.6558838	0.06
371.1803284	0.13
381.7084656	0.02
386.6527100	0.07
387.3127136	0.08
396.9687805	0.47
412.9460754	0.04
415.1787109	1.36
416.3614807	0.04
432.9206543	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1412
Annotation	Unknow
Peak:m/z	Relative Intensity
241.3462219	0.04
265.9358521	0.05
283.3872375	0.04
292.7377319	0.09
321.4825745	0.03
332.1001892	0.06
403.1833801	100.00
407.5858154	0.03
431.3068848	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.0951
Annotation	gamma-L-Glutamyl-L-methionine sulfoxide
Peak:m/z	Relative Intensity
87.8409119	0.04
101.9463501	0.27
119.8410645	0.02
126.9626617	0.01
130.2683105	0.03
131.0500183	0.36
147.7884827	0.47
148.9028625	5.10
163.0031128	0.03
165.9247894	100.00
168.0313568	0.01
223.3257446	0.05
231.0499878	0.83
232.0659485	1.34
247.3073425	0.05
248.2355957	0.04
249.0843506	0.05
259.2478943	0.09
277.0628662	3.89
278.1294861	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.3044
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0894928	0.76
194.1146088	0.12
198.1498413	0.70
204.9862671	3.19
218.8142090	0.17
225.0902405	0.07
244.0792236	6.39
261.1360474	100.00
273.0217590	0.61
291.0098572	1.92
301.3668823	0.50
313.2042236	0.36
315.3131409	0.24
322.2503052	0.17
323.3791809	0.17
346.3759155	0.13
353.2205811	0.12
396.2076416	0.15
397.1927490	0.19
417.0463867	0.11
429.2504883	0.14
434.8818359	0.48
452.4244385	0.74
453.0450439	0.62
494.2835083	0.30
495.1547852	0.77
503.3311768	0.12
511.1170654	0.21
529.2336426	0.07
540.5568237	0.16
547.2392578	0.37
549.3526611	0.22
558.6074829	0.06
620.5461426	0.21
630.5413208	0.30
639.1783447	1.01
639.7825928	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.8497314	0.07
175.2196960	0.19
176.9792328	0.12
179.1047058	0.09
181.9570160	0.07
183.1245728	0.06
184.4686890	0.22
187.2059326	0.18
193.1040039	0.07
201.3361664	0.19
202.8036041	0.15
203.4680939	0.09
204.4936829	0.13
205.2229767	0.21
212.0915070	0.26
226.1657104	0.06
230.7097931	0.12
242.9821472	0.44
244.9579620	3.82
247.1244202	0.04
255.1703491	0.32
267.1580811	0.50
269.1027222	0.57
271.0473328	0.16
273.0582275	2.53
281.1608887	0.21
287.1318970	8.03
287.9886780	0.11
289.0787964	23.79
290.2752991	0.19
297.0438843	0.04
299.1947632	4.32
301.4086304	0.07
305.2474060	0.21
314.3014832	0.14
316.1035767	0.08
317.1705322	0.11
323.2694092	0.08
326.9985962	0.20
329.2832031	0.21
331.2543335	0.59
339.1274414	0.18
341.2872314	0.48
342.3415527	0.08
350.6328735	0.04
353.1449585	0.14
354.8676147	0.21
356.9105225	0.28
371.2653809	0.20
381.2391357	1.45
393.2879639	0.12
405.2489014	0.08
407.2121582	70.08
408.2473145	0.20
409.0022583	0.30
411.2200317	0.24
415.7553101	0.06
421.1867676	0.14
423.2629395	0.21
425.1113281	100.00
425.7897949	0.44
433.1185913	0.98
437.1451416	0.05
447.3833008	0.07
449.1441650	1.43
451.1628418	30.33
453.5097656	0.09
467.2790527	0.73
471.1504517	0.14
475.2820435	0.02
491.4992065	0.66
493.3015747	0.19
497.1223145	0.21
500.8159790	0.04
515.3042603	0.50
533.2877808	1.48
541.4320679	0.07
559.2266846	11.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1403
Annotation	Gerfelin
Peak:m/z	Relative Intensity
159.1415863	0.38
160.9403381	0.47
162.9567566	0.19
163.8984833	1.00
164.9470520	0.87
167.0186615	0.54
174.1932526	0.14
175.2089539	0.77
177.0467072	0.55
179.0085907	0.32
185.1701660	0.20
187.1579590	0.24
188.0560913	0.30
188.9958801	0.04
193.1666260	0.10
196.0125275	0.11
199.0678406	0.12
201.2159729	0.39
203.0316162	3.20
205.0956421	1.04
206.1205750	0.12
218.9373474	0.16
226.7586670	0.86
227.9962769	0.64
229.1565552	1.17
230.1627808	0.11
231.0655823	0.37
233.1036987	0.08
235.1557159	0.29
241.2735748	0.25
243.1928406	0.95
245.1291656	6.74
246.2140350	0.05
246.8887482	0.16
253.1091919	0.64
255.0196686	0.36
259.3768311	0.54
263.0927429	0.07
265.0163879	0.07
267.0558472	0.18
269.0698547	0.87
271.0764160	17.25
273.1687622	10.06
281.1402588	0.41
283.1290894	3.02
285.2429810	0.06
287.0435181	4.74
289.0751343	100.00
290.0992126	0.26
297.4342651	0.52
299.1481323	5.19
301.2343445	0.20
309.3864136	0.13
310.1122437	0.05
311.0537720	0.28
313.0094604	1.63
313.6174927	0.10
315.3344116	0.36
320.0374756	0.13
320.6405640	0.15
323.1372681	0.17
325.2006226	0.11
328.1160889	3.14
329.1639404	8.66
331.3475342	0.69
339.2092285	0.59
341.1176147	0.67
351.2432861	0.66
353.0545654	0.23
355.3289795	0.43
361.3854370	0.19
364.8897095	0.23
367.1858521	0.21
369.2894897	0.14
371.1656494	0.24
373.0435791	0.06
375.1770630	0.42
377.1907349	3.59
379.3201904	1.14
381.1889648	4.79
385.3583374	0.31
387.5873413	0.32
389.2173462	0.20
391.1818848	2.34
393.2175903	0.40
395.4066772	0.35
397.2877197	0.12
398.0968018	0.15
402.3936157	0.51
405.1411743	0.53
407.1351318	25.81
409.2216797	17.62
410.3720093	0.54
411.4567871	0.30
413.3850708	0.15
417.1237793	0.91
419.3878174	0.33
423.2285156	2.69
425.2045898	28.32
431.3222046	0.20
432.9321899	1.05
433.5587769	0.37
435.0875854	75.28
435.9904175	1.13
437.2811279	0.59
439.2269897	0.20
445.4208374	0.12
446.3016357	0.18
447.0357666	0.12
451.0996704	0.78
453.8048096	0.40
455.1069336	0.27
459.1660156	0.37
464.8931274	0.09
467.0432739	0.25
473.2214355	0.30
475.5287476	0.18
476.1823120	0.12
476.9715576	1.15
481.0585327	0.39
483.0451050	0.26
483.9049072	0.61
485.1065063	0.48
488.2725220	0.25
492.7532349	0.40
499.4094238	0.88
501.3563843	0.37
515.1380005	0.13
515.9680786	0.13
517.2752686	5.16
525.2236938	1.79
530.0936890	0.43
531.9491577	0.31
533.4557495	0.05
543.2365112	60.23
544.2796021	0.21
545.0236816	0.17
552.0430908	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.2762
Annotation	PE(15:0/0:0)
Peak:m/z	Relative Intensity
124.8538971	0.46
130.2805023	0.21
137.1717224	0.45
155.2608948	0.36
165.9634705	0.15
172.9863586	0.46
180.9904785	0.28
184.0282288	10.26
185.2030945	0.80
189.4287415	0.19
192.9968719	0.86
198.1080627	0.75
205.2782135	0.31
216.0344543	0.46
223.2428436	0.55
225.4559631	0.23
230.8378143	0.39
237.1990051	0.59
252.3666687	0.64
266.8364258	0.11
268.4675293	0.71
280.7404480	0.24
289.2261658	0.31
299.2572632	71.50
326.2829590	0.15
328.1434326	0.11
355.1514282	0.41
366.5928650	0.36
379.1921997	5.63
380.3280334	0.34
381.0934753	0.08
384.8058472	2.05
393.6110535	1.52
395.0782776	0.56
396.5962219	0.31
397.3310852	0.16
401.4568787	0.98
409.8175964	0.72
410.5054016	1.21
413.3032837	0.83
414.7880859	0.26
417.3932800	0.64
422.1903381	100.00
423.2999573	4.59
424.3530579	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1236.11
Annotation	Unknow
Peak:m/z	Relative Intensity
407.1664429	1.04
440.4851074	0.35
441.5892029	1.36
481.1511841	5.36
499.8194580	0.73
535.6690674	0.28
551.1687012	0.91
569.8040771	0.36
571.5751343	3.37
573.4416504	2.76
579.3598633	0.36
589.3220215	0.87
605.5649414	0.88
641.4969482	7.64
642.2958984	0.85
734.1087646	0.33
735.3589478	1.80
736.1583252	1.02
751.4346924	7.95
761.5358887	1.11
771.4164429	1.26
803.4099121	46.47
804.4193726	8.05
819.5480957	1.71
833.0313110	4.20
848.3131104	1.34
849.4307861	15.80
850.4920654	4.60
865.4490967	5.64
866.4638672	1.85
867.7126465	1.43
868.5606689	0.41
875.3742676	100.00
876.3829346	23.14
883.4681396	1.42
884.3109131	0.99
891.3466797	4.02
893.4604492	54.40
894.4906006	10.13
907.2623291	0.95
909.3865967	11.81
910.4228516	7.24
911.4942627	7.10
912.8355713	2.48
927.5494385	1.17
928.8673096	0.47
941.5391846	0.30
979.5349121	1.86
1009.5483400	0.27
1011.3524170	45.24
1012.4921880	11.75
1027.3283690	8.53
1028.5467530	3.84
1029.4541020	2.22
1045.5119630	0.89
1055.6064450	13.49
1056.3786620	5.45
1071.5031740	0.79
1073.5368650	25.19
1074.5715330	10.46
1089.1606450	5.55
1090.3116460	1.32
1173.4973140	65.24
1174.4962160	11.66
1191.6259770	1.60
1192.6123050	0.24
1217.3663330	96.71
1218.5656740	35.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.2252
Annotation	Unknow
Peak:m/z	Relative Intensity
158.0243683	0.59
158.9780579	0.02
163.2231293	0.02
173.0762634	0.05
175.3858337	0.11
176.0444336	1.44
180.9718628	0.05
189.2689209	0.02
191.0273285	0.37
193.0867920	1.18
193.8978119	0.04
195.1647797	0.04
204.2445374	0.08
209.0384216	0.03
217.7320557	0.05
227.1569672	0.21
231.2660980	0.04
241.1869812	0.01
249.6961060	0.04
259.0022583	0.08
261.2806091	0.03
267.0196228	0.02
270.3737183	0.09
283.9724731	0.08
285.2219238	0.21
286.4319458	0.06
297.4926147	0.01
302.0051270	0.22
302.6329041	0.08
304.3337402	0.04
312.0886841	0.08
320.2847900	0.03
322.2407837	0.12
323.1060181	0.09
324.2423096	0.36
328.1586914	0.16
348.2484741	0.26
363.2576904	0.07
366.1909180	0.57
383.4248657	0.22
384.1292114	0.91
387.4107056	0.07
399.2786255	0.03
401.1265259	8.52
402.1499023	9.57
402.7817993	0.04
417.2139282	0.01
419.2037354	100.00
419.8422241	0.22
421.3197021	0.01
431.4315796	0.01
434.5789185	0.02
440.8788452	0.03
459.2321167	6.68
459.8457031	0.02
484.0875244	0.01
485.3410645	0.02
502.1373901	0.06
512.1659546	0.13
530.1952515	8.62
531.2085571	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1014
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
154.9054260	0.03
205.0590973	0.08
206.7658691	0.09
258.4147034	0.06
260.1628418	0.24
275.1873779	0.06
278.2226257	1.45
283.2172241	0.19
284.9419556	0.16
295.1558838	0.05
299.4436340	0.09
303.1281128	100.00
311.1307373	0.12
318.2894897	0.07
327.2658081	0.29
333.0765686	0.10
334.1090393	0.05
345.0097656	0.81
367.1618958	0.02
369.0193481	0.08
377.2334900	0.06
379.9870300	0.17
380.8967590	0.08
384.2373352	0.63
385.3557739	0.06
391.2990417	0.34
396.3769226	0.03
399.4371033	0.04
401.2038879	0.07
403.4689636	0.41
411.2443542	0.10
429.3482361	0.33
433.2401428	1.01
443.9313354	0.32
447.1811829	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.2333
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
95.1845245	0.07
97.0946045	0.19
99.0000458	0.63
111.0675125	0.06
123.0670319	0.13
125.0210724	1.53
127.1260452	1.25
129.0938110	0.09
139.0908966	0.53
141.1311646	0.48
151.2412567	0.05
153.1865234	0.20
155.1201782	1.76
157.0246582	0.15
163.1393127	0.28
165.0960999	0.59
167.1293030	1.64
169.2207031	0.15
171.1318512	6.77
175.1443939	0.28
177.0024109	0.03
180.2744141	0.10
180.8901215	0.23
183.1282043	4.84
185.1547241	2.90
186.0226135	0.08
193.1549988	2.57
195.2019653	0.81
197.1782837	2.81
199.1582184	3.11
201.2805786	0.19
203.4162292	0.12
209.1240540	4.50
211.1268921	50.37
212.1856689	0.21
215.0831299	0.06
223.9321289	0.04
227.0332947	0.41
229.1345825	100.00
230.3518677	0.31
231.5515747	0.10
239.3040771	0.13
241.2285156	0.66
242.2575378	0.03
247.3568115	0.33
248.2521667	0.05
249.2814026	1.26
258.6457520	1.55
259.2994995	7.56
263.2142944	0.04
265.3767395	0.33
267.3001099	0.28
273.5607300	0.11
275.3235168	0.81
279.1724854	0.08
281.4005127	0.54
283.3009338	0.77
291.2141418	4.89
293.3407593	30.27
294.3677368	0.14
299.2346191	0.56
307.1564941	0.19
309.2603455	6.85
311.2426758	52.77
312.3497925	0.81
313.1831055	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1067
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
147.0662079	0.03
203.8784485	0.02
205.4632721	0.02
235.0190735	0.03
236.0382996	0.05
266.7880859	0.01
268.967041	0.07
271.0317383	0.07
273.0499573	0.04
285.0996704	0.01
287.0480957	100.00
287.9182129	0.01
322.7631226	0.02
347.0872803	0.18
359.0280457	0.05
373.2997437	0.01
382.8256531	0.03
404.299408	0.02
431.2663879	0.05
448.924408	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	855.2229
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9336090	0.03
257.1202087	0.07
259.2299500	0.32
265.2175293	0.74
271.2385254	0.20
273.1290894	0.20
281.2877197	0.37
283.0680237	1.07
285.2860718	0.13
287.1211243	0.56
289.1679382	0.15
291.1476746	0.62
299.0957031	0.49
301.0605469	4.91
303.0933533	1.00
310.8935547	0.16
313.2419434	0.07
326.6272583	0.06
327.4019775	0.10
345.0794373	0.71
349.3402405	0.14
359.0519714	0.15
381.4357910	0.17
395.3183289	0.06
409.0872192	0.07
411.2417603	0.24
421.1335449	3.16
423.1796875	0.30
432.4026489	0.34
433.0784302	0.32
439.0297241	7.93
451.0696411	0.93
462.6187134	0.15
465.3026733	0.59
468.9013672	0.05
538.9356079	0.07
555.2654419	0.21
563.4873657	0.08
566.9545898	0.19
573.1069946	2.32
573.7086182	0.05
575.1911011	1.09
579.1558228	0.04
591.0282593	100.00
591.6723633	0.35
608.8621216	0.17
698.7345581	0.23
726.2660522	0.23
804.1491089	0.09
837.7616577	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1395
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
83.1119995	0.18
93.0380173	0.03
95.0685425	0.07
105.0601044	0.09
111.0628128	0.31
118.9887390	0.37
120.8628998	0.21
123.0614700	6.52
133.0999451	0.24
135.2055969	0.11
136.9190369	0.09
139.1921997	0.14
143.0180664	0.14
145.1455078	0.83
149.1099243	0.31
151.0709686	0.07
153.0079041	1.93
159.0807190	0.56
163.1893311	0.08
167.3027649	0.06
169.0992279	0.34
171.0564575	9.07
175.0559235	0.21
177.0937347	0.19
179.4206085	0.06
188.5401917	0.55
189.2215881	4.59
193.2125549	0.02
199.1310120	0.05
201.0961914	4.79
205.0080261	0.04
207.0959473	6.36
207.7210999	0.11
209.2684326	0.05
219.0309753	11.11
223.2723694	0.09
237.1167603	100.00
262.9457703	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.11
Annotation	Nopalinic acid
Peak:m/z	Relative Intensity
114.0641022	0.27
127.9322662	100.00
130.1749878	0.15
131.9801025	12.35
145.1514587	0.06
146.0606537	0.26
153.0044403	1.02
155.0266571	0.06
171.0204163	0.21
178.9848938	0.20
184.9323883	0.43
187.2200775	0.09
192.0004425	0.05
197.0144348	0.05
199.2898865	0.33
215.1152954	0.06
217.1737518	0.03
225.1345825	11.11
231.1586914	0.03
243.0794525	92.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1248
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
134.9578247	0.18
150.9864197	0.06
153.1831360	0.10
161.1125641	0.24
165.0754242	1.78
183.1913452	0.06
190.7872620	0.07
222.3040771	0.03
235.3155518	0.05
254.9756775	0.03
256.4452209	0.09
283.2091064	0.10
287.0088196	0.06
297.0664062	0.05
301.0816650	100.00
302.2604370	0.03
319.7714844	0.07
325.3101196	0.03
335.8040161	0.03
360.6293640	0.06
373.2200623	0.09
395.0052185	0.12
403.4319458	0.04
405.3860779	0.21
407.1861267	0.04
419.4261169	0.10
427.1308594	0.18
430.3254089	0.16
432.2972107	0.03
443.2109070	0.06
445.1777039	0.03
448.0937195	0.02
451.2913513	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3307
Annotation	Unknow
Peak:m/z	Relative Intensity
219.8932800	0.04
224.1842346	0.02
242.0482178	0.06
243.0189667	0.01
255.1917114	0.03
264.8478394	0.03
279.3132629	0.66
281.2370911	0.03
312.6962280	0.02
339.3507080	0.02
367.2554321	0.03
409.4486084	0.02
410.4030762	0.02
415.1779175	0.16
434.0349121	0.06
504.3274536	100.00
505.3458862	0.28
519.4882202	0.01
544.0877075	0.10
549.0050659	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.3288
Annotation	Leueantine C
Peak:m/z	Relative Intensity
166.1422424	0.34
180.7053528	0.11
184.0382843	56.47
225.0972290	0.09
258.0869141	0.46
259.2279053	0.21
269.5795898	0.26
303.0881653	0.06
327.1401367	0.08
338.4271851	0.13
351.0464478	0.22
368.3112183	0.17
380.3486328	0.82
383.3245850	0.26
394.3091431	1.00
412.2016602	0.92
423.4235840	0.27
434.2491455	30.22
434.8518066	0.61
438.4756470	0.86
442.9638672	0.09
444.4614258	0.41
452.2627563	2.37
464.3258057	0.19
469.6337891	0.39
472.8269043	0.12
478.5490112	0.11
480.5783081	0.34
498.4267578	2.52
500.2566528	2.24
516.3199463	23.77
518.2379150	52.97
519.0105591	0.10
534.3279419	100.00
535.4598999	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.2564
Annotation	Docosanediol-1,14-disulfate
Peak:m/z	Relative Intensity
145.2241211	0.46
146.2842102	0.25
156.3174591	0.19
167.8894501	0.19
169.0997009	0.21
179.1015167	0.69
180.0707855	1.90
181.0526428	0.21
193.2476196	0.06
195.1877136	0.48
197.1849365	7.40
208.9166260	0.16
215.3277893	0.03
223.1814270	5.94
223.9072723	0.19
239.1228027	0.18
241.1213684	70.62
259.1277466	9.68
264.3191223	0.22
269.3272705	0.04
285.1146545	0.06
292.7183838	0.28
310.4494019	0.79
326.0866699	0.14
328.3069763	0.16
334.3032837	0.26
335.8550720	0.11
337.2793579	0.60
352.2512207	1.73
354.2379456	11.05
355.4829712	0.32
369.9358215	0.55
372.2812195	9.93
381.3835754	0.09
382.2880249	0.08
388.0980225	0.09
395.2904663	0.07
411.6932678	0.08
419.5293274	0.25
421.3624268	0.69
423.4377136	0.10
439.2489929	2.43
440.2855530	0.50
447.4275208	0.15
448.2100525	0.13
449.2159424	0.18
457.3052063	0.63
465.3805847	6.93
481.2707825	0.07
483.2540588	100.00
484.3045349	0.64
501.3072205	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.1066
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
159.2111359	0.02
169.0896759	0.01
183.8859253	0.02
213.2834015	0.02
229.0771942	0.02
230.4754486	0.02
231.1633606	0.03
255.0414429	0.04
281.4929810	0.01
284.9768066	0.04
287.0567932	100.00
287.6764526	0.21
299.2649536	0.03
311.0770874	0.21
327.5932007	0.06
329.0979004	2.02
337.0968018	0.01
347.2291870	0.01
353.2645264	0.16
356.8021240	0.04
373.3432007	0.01
377.3608398	0.02
395.1529541	0.45
399.1265869	0.04
403.2485352	0.02
406.2584839	0.02
412.9163818	0.01
423.4842529	0.02
431.3258667	0.02
432.9169312	0.02
445.1819458	0.01
447.1378174	0.09
449.0303345	0.08
455.1674805	0.04
470.6282349	0.01
473.2925415	0.10
475.1777954	0.04
481.1962280	0.01
487.3623657	0.01
499.2222290	0.47
503.0546875	0.01
517.0477905	3.04
518.0979614	0.06
535.8765869	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	809.4328
Annotation	Lucyoside J
Peak:m/z	Relative Intensity
241.0150909	0.85
243.0087128	0.12
256.2142944	0.07
278.2330017	0.24
285.4476013	0.26
297.2454529	0.50
305.1528320	0.09
307.4713745	0.07
397.2183838	0.10
417.2229004	0.12
425.4688721	0.40
441.0874023	0.24
452.3121948	0.15
466.1930542	0.19
471.4171143	3.87
472.5894775	0.23
481.1998291	0.14
497.3291016	0.08
499.3131104	0.08
525.4546509	0.38
539.2835693	0.46
553.1819458	0.32
567.4181519	0.27
575.2898560	0.05
577.5050049	0.08
591.7220459	0.15
593.2935181	0.20
599.1764526	0.22
607.6030273	0.11
613.2777710	0.24
615.4113159	14.98
616.3729858	1.67
616.9945679	0.06
620.4011230	0.09
621.3497925	0.11
627.5104980	0.29
629.2954102	0.12
633.4622803	100.00
634.4960327	6.27
637.2000732	0.08
643.3058472	0.28
648.0226440	0.33
658.3583374	0.10
667.3607178	0.34
671.1175537	0.07
673.4283447	2.26
674.4827881	0.56
675.6632690	0.58
677.3110962	0.22
691.6377563	0.91
692.5808716	0.43
701.4432373	0.64
703.5159912	1.49
704.4586792	1.89
719.2185669	0.08
719.8377686	0.52
729.2814941	2.99
731.4425659	0.66
744.8958130	0.24
745.7003784	0.14
747.4701538	55.41
748.4326782	4.90
749.4924927	3.55
750.3502808	0.22
754.2030640	0.04
755.3905640	0.40
763.3411865	0.29
765.4190063	15.83
766.6453247	1.16
771.1576538	0.13
773.3577881	0.77
777.3436890	0.11
779.6221924	0.34
790.1787720	0.11
791.4787598	7.35
792.3554688	2.27
794.6390381	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	648.2997
Annotation	Unknow
Peak:m/z	Relative Intensity
471.2669678	0.02
502.3003540	0.03
625.3143921	100.00
626.1986694	0.43
626.8816528	0.37
627.6492310	0.18
628.2745972	0.14
629.6383667	0.11
631.6126099	0.01
632.3782959	0.02
633.3401489	0.03
639.8267212	0.03
657.4506226	0.03
729.4348755	0.11
747.5500488	0.17
765.6516724	0.01
865.3425293	0.03
909.6323242	0.04
927.1337891	0.01
957.6503296	0.12
1071.4809570	0.16
1089.4248050	2.37
1251.4744870	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.15
Annotation	Apiin
Peak:m/z	Relative Intensity
161.0474243	0.03
193.2733154	0.07
196.9319611	0.02
199.6987457	0.02
201.1918945	0.04
209.1560974	0.05
227.1368408	0.03
233.129364	0.02
235.0215149	0.03
242.9183044	0.02
248.1787109	0.04
265.2686768	0.39
266.1690063	0.03
266.8838501	0.02
271.065033	100.00
277.3578491	0.03
284.9406738	0.03
303.5358276	0.05
318.2503662	0.04
320.4276733	0.03
323.2269897	0.07
325.2879028	0.02
338.6428833	0.05
364.3280029	0.06
365.7658691	0.05
369.3078003	0.04
378.7642212	0.03
382.2056885	0.06
385.1158447	0.04
389.1638184	0.03
391.9979858	0.04
403.1339722	0.09
403.9810791	0.05
411.2996826	0.04
412.1470947	0.05
413.2996826	0.09
417.3805542	0.04
419.1074219	0.06
421.1849365	0.10
427.5263672	0.12
429.1495361	0.05
430.1550903	0.03
433.0085449	0.78
434.4094238	0.20
435.3129272	0.17
436.276001	0.25
442.6557617	0.08
446.1405029	0.06
453.2504272	0.06
505.6982422	0.02
506.4577026	0.06
517.9880371	0.02
540.3860474	0.02
544.7002563	0.07
547.1047363	0.21
547.9242554	0.01
552.9315796	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	555.1796
Annotation	Methionyl-Glutamate
Peak:m/z	Relative Intensity
167.1003723	0.75
169.0659637	0.04
170.9955292	0.06
193.3041077	0.04
197.1029510	0.18
198.0218353	0.07
200.1104736	0.02
211.0849915	0.68
215.1569519	1.20
241.1092072	2.63
259.0730286	13.44
277.0651855	100.00
320.1901245	0.03
331.0493164	0.02
335.2943726	0.03
426.3067017	0.02
536.0452271	0.05
537.0049438	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0753632	0.04
209.1114807	0.03
288.9890747	0.08
297.2721863	0.04
341.1111450	100.00
341.7520752	0.08
369.4600525	0.15
387.2973022	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.8283844	52.36
69.9305191	6.01
71.8719330	1.79
84.0183105	0.13
97.0259399	0.67
98.0228424	0.29
112.0079346	5.81
112.9079895	0.67
114.0345154	4.82
115.9547119	55.55
130.0602264	36.79
131.0511169	0.14
133.1270142	0.98
140.0161285	2.91
141.0266876	0.52
157.0143280	74.68
158.0705414	100.00
175.0684509	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.2347
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9950714	1.25
162.9219971	1.59
163.6741486	0.13
169.1249390	0.47
173.0236359	0.16
175.0570984	2.85
184.9937744	0.11
189.1195679	0.81
192.8106232	0.46
203.1667023	0.15
207.0760193	4.05
219.0990601	0.27
225.2292480	0.11
238.9419250	0.69
272.7776489	0.14
286.2722778	0.16
293.1650391	0.26
309.2476807	0.20
319.4160156	0.11
320.1575317	0.19
321.3125000	0.70
329.2686768	0.23
335.3392944	0.07
337.1318359	1.69
369.0315552	0.95
387.2224121	98.50
388.2531128	1.93
391.1834106	0.14
401.2107544	0.62
411.1887207	0.16
419.1470947	100.00
445.4253540	0.40
457.4785767	0.45
458.3646851	0.20
461.1662598	34.69
465.3889160	0.35
483.2871704	0.58
485.0512695	0.19
487.2213745	0.13
501.1842651	14.55
503.2285767	4.06
515.3949585	0.20
516.9081421	0.09
519.0704956	1.02
527.3638306	1.00
531.0975342	0.46
545.2406616	16.97
546.2366333	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.2252
Annotation	Unknow
Peak:m/z	Relative Intensity
157.9750824	0.43
163.1493683	0.05
165.1702271	0.04
167.3403931	0.04
173.0611725	0.30
175.9972839	1.76
177.0264435	0.03
189.1806488	0.05
191.0344849	0.64
193.0862427	1.35
193.9806061	0.12
194.9645996	0.03
209.0959625	0.19
210.1229858	0.02
225.8318176	0.05
227.2050018	0.32
231.2325745	0.05
258.9787598	0.01
267.1129456	0.06
277.1463928	0.05
284.2150879	0.08
285.2378540	0.03
286.0473633	0.03
294.1455078	0.09
295.2849731	0.11
302.1784058	0.42
312.0866699	2.08
317.0036621	0.03
320.3626709	0.01
322.3510132	0.11
324.2122803	0.01
331.8993530	0.03
340.2494507	0.17
342.2127075	0.04
348.1926270	0.06
363.2395630	0.02
366.0569458	0.60
383.2011108	0.21
384.1377563	0.80
399.0776978	0.03
401.1990356	9.63
402.2233276	4.44
419.2210083	100.00
419.8428955	0.13
422.8760986	0.03
441.2406006	0.21
459.2223511	5.69
484.9820557	0.01
502.2897339	0.01
504.2775879	0.01
506.6909790	0.06
512.1323242	0.18
516.0580444	0.03
530.2334595	14.16
531.1299438	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.0876
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1270676	0.20
109.0126190	0.15
110.0041199	0.20
118.1540985	0.15
131.1030731	0.38
135.9715271	1.56
137.0281067	1.86
154.0271606	100.00
156.3841858	0.03
173.1336975	2.46
191.9151611	0.08
209.8966370	0.21
219.1104126	0.09
257.1652832	0.06
261.9198608	0.12
263.1144104	0.12
274.3660278	0.02
302.2054443	0.04
303.1212158	0.06
329.6379395	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	653.79
Annotation	Unknow
Peak:m/z	Relative Intensity
232.2644653	0.12
234.0998993	0.03
269.8413086	0.06
315.8640747	0.17
317.8634033	0.34
336.9379883	0.09
349.0643311	0.04
349.8459473	0.14
356.0009155	0.15
378.7161255	0.07
396.4197998	0.04
399.4724121	0.43
400.0748901	0.51
401.8005371	0.61
437.7667236	0.02
439.8373413	1.08
441.5084839	0.42
442.4071045	0.09
444.2014160	0.06
446.3097534	0.03
458.2167969	0.24
459.9915161	0.38
461.1036987	0.03
479.1635742	0.34
480.0859985	0.19
483.6647339	1.05
485.7076416	2.80
486.4446411	0.06
498.2143555	0.28
500.1228027	0.10
501.1506958	0.10
502.1635132	0.04
521.7393799	0.76
523.6252441	3.30
567.6714478	1.49
569.7012329	12.97
570.8138428	0.08
605.6586914	0.55
607.6390991	100.00
608.3449097	0.29
609.4025269	0.06
632.6510620	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	255.1585
Annotation	Gliocladic acid
Peak:m/z	Relative Intensity
77.0767517	0.13
80.8755188	1.06
83.0203323	0.27
85.1171799	0.06
86.2879334	0.45
87.2356415	0.36
94.8995666	0.31
97.0215454	0.23
98.7916565	1.53
101.1317902	0.47
108.9542847	0.90
111.0817413	0.08
114.0811920	0.18
116.9613190	1.48
120.9808655	3.86
123.1032104	2.15
124.9582672	0.43
128.2478790	0.08
130.0001984	6.20
132.9261475	0.77
135.0523682	1.91
139.0376434	3.67
141.0607605	0.34
143.1349335	0.07
144.8893280	0.11
146.8791656	0.80
149.0686798	2.32
150.9935150	0.09
152.1393280	0.11
152.9315338	0.69
155.1238556	0.43
156.9198761	6.24
159.1832733	0.49
161.0450745	1.10
163.1428070	1.72
164.9071503	0.39
167.0450592	0.70
169.1950836	0.49
170.9398346	1.15
173.1460724	0.78
175.0081329	1.06
177.0115814	0.94
179.0942688	1.03
181.0502930	0.70
183.0528259	0.76
184.9733124	0.62
187.0245361	0.25
190.9976044	1.63
191.9831238	0.23
193.0167694	0.27
195.0577698	0.28
197.1220093	1.10
199.1684418	0.70
201.2344818	2.96
207.7425995	0.18
209.1413116	3.90
210.5533905	0.41
211.3335419	0.10
213.0894928	2.05
213.9880219	1.15
219.0502777	37.16
225.0593109	1.69
227.0944977	1.59
237.0637970	100.00
237.7322540	0.81
239.9634247	0.15
245.6547241	0.89
254.9915009	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.51
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1870422	0.16
233.8623352	0.63
260.3268433	0.21
275.3295288	0.74
277.2377319	66.16
278.3008118	31.33
279.1333618	3.40
281.2597961	100.00
282.3579712	54.38
293.3195801	0.25
294.4456482	0.07
365.3306274	0.21
387.4356079	0.14
404.6412964	0.10
418.4586182	0.12
456.3240967	0.61
457.4313965	0.85
460.4848022	1.27
461.3701782	1.80
474.2563477	7.67
475.3507690	8.61
476.2943726	0.23
477.2740479	0.28
478.2708130	6.86
479.3850708	7.15
505.7169189	0.19
511.2238770	0.27
567.0271606	0.33
608.2338257	0.41
618.2861328	0.16
631.0530396	0.90
675.4891968	0.28
676.7097168	0.42
679.4041748	0.53
680.0618286	0.19
703.3596802	0.32
721.5079956	2.88
722.6804810	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	608.155
Annotation	Unknow
Peak:m/z	Relative Intensity
178.0717316	0.14
179.1443939	0.43
179.8585968	0.08
181.0069122	0.38
183.0444336	0.30
184.8267517	0.11
186.9841919	0.11
189.3265991	0.06
190.9089966	0.08
193.1177826	0.46
195.1048431	0.10
196.0038757	0.31
197.1293488	0.12
199.0210419	0.03
200.0086060	0.10
200.9445801	0.09
203.1358948	0.06
214.9942017	0.33
218.9599915	0.04
220.1722107	0.03
224.1444092	0.17
225.2734680	0.11
228.8339844	0.10
234.5905762	0.36
235.2079163	0.73
237.1032715	0.24
241.9287720	0.17
242.9859467	0.08
245.2008972	0.09
246.2125702	0.08
249.0093994	0.10
253.0726318	0.14
254.9738312	0.16
260.9868164	0.14
268.0404053	1.12
269.0450439	0.58
274.9494019	0.11
277.1602173	3.28
277.8676758	0.08
278.8616333	0.45
284.8773804	0.04
286.1614380	13.96
287.2623291	1.22
301.3510742	0.06
303.0765686	2.34
308.3088989	0.08
313.0444336	0.08
321.0336304	100.00
321.6819153	0.42
322.8593140	0.14
337.2493286	0.22
341.5658569	0.04
353.0028687	0.26
366.9863892	0.04
403.0759888	0.06
408.1019897	0.04
424.4417725	0.24
426.2850952	0.06
432.1728516	0.10
437.0017700	0.07
446.0026855	0.21
451.3023071	0.03
452.1528320	0.10
461.1126709	0.10
462.1529541	0.13
464.4300537	0.14
470.1384888	8.52
477.4165039	0.33
479.1586914	7.11
482.1317749	0.04
491.2126465	0.11
492.0957642	0.26
502.3204346	0.20
516.2439575	0.04
518.2058716	0.16
520.6128540	0.09
528.3340454	0.23
546.3246460	1.40
561.9782104	0.26
562.6314087	0.26
564.4413452	0.18
572.1749878	0.21
578.0103760	0.40
590.0748291	2.41
590.8650513	0.19
598.9008179	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1428
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
76.6558838	0.05
79.1141663	0.06
81.2469025	0.03
87.0327530	0.08
90.1643219	0.10
91.0054321	0.10
92.9195709	0.19
94.8976593	0.25
96.9794311	0.39
98.9536896	0.18
100.9430389	0.05
105.0653839	0.29
106.9479370	0.28
108.9982300	1.34
110.8807220	1.33
111.8273010	0.05
113.0282135	0.93
113.9592438	0.03
118.9664764	6.27
120.9640503	2.26
121.6960754	0.06
123.0646210	0.46
124.9431152	0.28
129.0858917	0.02
129.8162994	0.09
131.0739441	0.04
133.1208954	0.25
135.0005493	5.03
135.8924561	5.17
136.9505920	2.67
139.0013428	1.18
142.9238892	0.23
144.9772339	0.42
146.9897156	1.21
148.0132599	0.06
149.0077667	0.38
150.9987488	0.12
152.1360168	0.01
152.9880676	0.18
155.0093231	0.52
157.0741272	4.92
159.0876770	2.23
160.9602356	3.04
162.8675079	0.60
165.0886230	2.86
165.8405304	0.02
166.9986267	0.27
169.2184906	0.14
171.0248566	0.30
173.0259705	1.46
174.9968262	9.51
177.0957794	0.13
179.2297668	0.05
181.0742035	0.14
183.0997467	0.18
185.1129303	1.59
187.1554718	5.45
189.1309662	2.40
191.0529022	0.27
192.9946442	6.12
196.9234161	0.15
199.0993042	1.00
201.1210175	5.04
202.9508209	14.63
205.0410461	1.54
207.0195465	1.16
209.0701752	0.12
211.0565796	5.00
216.4659424	0.55
217.0885162	6.40
219.1314545	4.55
220.9690399	0.77
223.8975983	0.10
229.1413879	12.94
235.0708771	9.03
237.0638885	0.06
244.5462799	0.16
246.9785004	100.00
247.8251343	0.39
250.2433624	0.11
251.1517334	0.21
255.6975250	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1405
Annotation	Gerfelin
Peak:m/z	Relative Intensity
161.0844574	2.81
162.0923767	0.05
163.0914459	0.34
164.0123901	1.16
165.0259094	0.60
167.2178650	0.19
171.1942749	0.11
172.9525604	0.08
175.0796204	0.70
176.1967773	0.05
176.9996643	0.21
185.2113800	0.15
186.1304779	0.46
187.1206665	0.57
188.4820404	0.25
199.1370544	0.19
201.1987915	0.62
203.1710052	1.39
205.1061249	1.36
211.0355988	0.07
212.0430145	0.10
215.0531311	0.40
217.1629486	0.05
222.8641663	0.22
224.3111115	0.33
225.0927124	0.35
227.0035400	0.55
228.2893372	0.18
229.1269836	0.85
230.2006836	0.08
231.0826569	0.06
233.0453796	0.13
240.1839905	0.18
241.0978546	0.25
242.0186462	0.24
243.1434326	1.48
244.9928894	9.28
247.1848755	0.49
252.9944458	0.38
255.1579590	0.54
257.4512024	0.10
259.2276001	0.19
264.3078918	0.13
267.1441345	0.40
269.0494385	1.31
271.2019653	9.98
271.9997559	0.11
273.1591797	37.28
274.1300049	0.14
281.0837402	0.15
283.1458130	3.54
285.2739868	0.88
287.0747375	28.56
289.1016541	65.30
297.1384888	0.24
299.0642090	26.12
306.3333130	0.10
309.4338379	0.16
311.3267212	0.14
313.1246948	0.47
315.1341553	0.36
319.1248779	0.25
323.1370239	0.74
324.3726807	0.06
325.0471802	0.17
327.1503906	0.72
328.2988281	2.20
329.1572266	7.13
335.0451660	0.42
336.9702759	0.23
339.3923950	0.65
341.3285522	0.52
351.3121338	0.42
353.2991943	2.10
357.0457153	0.30
358.7340698	0.07
359.4633179	0.24
361.1455078	0.48
363.2974243	0.30
365.2855835	1.79
367.0596924	0.21
372.9786987	0.10
377.2249146	6.40
379.1319580	0.82
380.1173706	1.11
381.1922607	3.96
382.9988403	0.22
387.3862915	0.19
388.2196045	0.06
389.0902100	0.05
391.2374878	9.22
393.1031494	1.12
394.1851196	0.53
395.2663574	1.27
398.3525391	0.38
405.1998901	0.49
407.2147217	19.82
409.1548462	80.54
410.0924683	0.30
411.1498413	0.14
413.2158203	0.44
415.4230347	0.17
417.0756836	1.77
421.2383423	0.93
423.1855469	2.55
425.1614990	33.38
431.4560547	0.46
433.1466675	1.95
435.1495972	100.00
436.3453979	0.36
437.1679077	0.25
438.4614868	0.39
440.9830933	0.10
449.2006836	0.13
451.3218384	0.74
455.1473999	0.71
457.2600708	0.14
459.1230469	0.55
467.1597900	0.34
471.0524292	0.14
473.2178955	0.44
475.3918457	0.20
477.1865234	1.44
481.0963745	0.12
492.6293945	0.05
498.6225586	0.21
499.3193970	1.61
500.9768677	0.34
503.2778320	0.35
512.3146973	0.45
513.1937256	0.12
515.2537231	0.41
517.2149048	8.36
518.7136230	0.08
519.3920288	0.20
523.9569702	0.28
525.1665649	0.62
527.2705688	0.05
538.7839966	0.20
541.6341553	0.59
543.2583618	41.85
544.1873779	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	561.1375
Annotation	Rubellin E
Peak:m/z	Relative Intensity
162.9713745	0.17
179.0676880	0.08
181.0493774	1.48
182.2146301	0.04
188.5029907	0.14
189.1301880	0.72
190.1326294	0.08
198.9794617	0.08
205.3967590	0.24
209.1231537	0.05
216.0855713	0.07
217.0651245	0.67
227.0156555	0.09
229.2698364	0.14
231.1280518	0.15
237.2008667	0.08
238.8879547	0.06
240.9489441	0.16
245.0851440	18.78
246.1883240	0.26
251.0875092	0.32
255.2073669	0.08
257.1669922	0.44
261.2982178	0.08
269.2119141	0.91
269.8435364	0.05
273.1622314	0.28
275.2274780	0.56
279.2903442	0.08
282.2252197	0.04
287.1915283	0.71
293.2854004	0.67
297.2709351	0.05
299.2228394	0.03
308.2351074	0.08
309.4123535	0.20
321.2947998	0.17
322.4179688	0.05
323.2210083	0.11
334.1717529	0.06
334.8970947	0.06
350.9887085	0.35
355.6932983	0.30
357.2313843	0.05
358.9674683	0.26
363.1361084	1.87
364.3121338	0.16
365.2760620	0.10
366.9476929	0.16
370.9520874	0.10
375.2168579	0.09
376.0342407	0.07
376.7960815	0.30
377.5483398	0.06
379.1210327	0.37
381.1425781	12.07
382.2991333	0.08
385.6093140	0.18
387.1738281	0.08
392.2967529	0.12
392.9895020	0.91
395.1610718	0.23
396.5564575	0.12
397.3840942	0.14
398.6547241	0.16
399.2917480	0.21
403.2570190	0.09
404.3581543	0.39
405.1322021	0.44
407.2048340	1.54
408.1265869	0.30
409.2175293	2.25
413.0159912	0.15
414.2902832	0.19
415.3090210	0.03
417.0887451	1.01
419.2689209	0.31
420.1640625	0.42
421.3054810	0.28
423.1868896	0.17
425.1088257	100.00
426.0104370	0.79
428.3480835	0.11
430.0430908	0.05
431.2166748	0.08
432.3833008	0.42
433.8865356	0.20
435.3830566	0.23
436.9220581	0.34
443.1060181	0.03
451.2045288	0.06
454.9705200	0.17
461.1848755	0.09
473.3757935	0.07
479.0839844	0.12
479.8016968	0.10
480.6902466	0.12
481.9919434	0.45
485.1613159	0.06
487.4042358	0.31
490.2142334	0.04
495.4205322	0.08
497.7005005	0.11
502.7839966	0.09
506.7197876	0.08
509.2907104	0.05
520.1077271	0.10
525.1374512	1.21
529.1650391	0.05
533.1483154	0.32
538.2423706	0.32
543.1393433	3.75
543.9486694	0.16
551.8539429	0.22
552.8836670	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	841.345
Annotation	Unknow
Peak:m/z	Relative Intensity
236.1738281	0.53
246.3045349	0.22
263.1812439	0.13
287.1414185	0.27
291.1141052	0.10
297.0792236	0.12
299.1919556	0.64
305.2875671	0.29
311.0702209	0.63
315.1918335	0.64
333.1416321	0.21
343.3029785	0.38
357.1636963	0.79
359.0687256	0.18
365.1944580	0.11
369.3265381	0.49
371.2466125	0.49
375.3226318	0.36
383.0626526	0.20
388.1319275	0.23
396.9908447	0.08
401.1970215	1.91
406.5325317	0.16
409.2282104	0.27
415.2973022	0.15
424.3322144	0.29
433.2497559	1.97
438.2092285	0.53
446.3498535	0.14
448.3052368	0.39
461.2088623	0.21
462.0927734	0.08
464.2510986	3.50
472.3693237	0.47
476.4738159	0.34
478.2103271	0.53
480.1046753	0.14
482.2959595	0.49
485.2927856	0.14
486.9847412	0.25
490.1196899	5.22
492.8887329	0.44
494.4760132	0.51
497.4349365	0.12
506.2291870	0.36
508.1931763	1.30
509.2517700	0.60
510.3048096	0.19
519.0858154	0.40
522.2871704	6.35
526.2138672	0.89
536.1505737	0.11
537.8334961	0.19
551.2720947	0.07
553.0177002	0.17
574.8180542	0.22
585.1305542	0.82
587.1603394	0.13
603.1925659	3.73
611.3818970	1.35
615.2677612	0.20
619.5124512	0.54
625.1212158	0.10
626.3632812	15.91
629.2987671	3.48
634.1923828	0.43
643.1196289	5.61
647.2429810	44.15
647.9249878	0.08
652.3079224	20.65
656.1467896	0.58
659.1195679	0.12
660.7858276	1.17
661.4231567	1.39
665.3101807	0.24
670.0871582	3.04
672.2391968	0.35
679.2286987	41.48
684.2005005	30.88
685.0757446	0.42
685.7986450	0.07
703.0665894	0.82
706.7933960	0.09
731.4494629	0.11
749.1925659	1.53
749.8298950	0.14
765.0918579	1.51
773.1315308	2.95
774.4819946	0.34
781.4766235	1.10
783.8571167	0.56
791.2156372	6.44
797.1234741	0.26
805.3543091	3.05
809.3479614	100.00
813.2822876	0.26
823.2695923	3.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.3324
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9401398	0.08
128.9481201	0.23
129.9941711	1.18
130.9464722	0.50
132.8803864	0.37
135.0183868	0.84
137.0223694	0.08
138.1134796	0.14
138.9592743	0.11
140.0611877	0.56
141.0445557	0.24
143.0975647	0.11
143.8166351	0.29
144.9366760	0.56
146.0426331	0.33
147.1059875	0.37
148.0923615	0.40
149.1007385	0.61
151.1062622	0.14
153.9626160	0.22
156.1125946	0.24
157.1931610	3.05
158.1055908	26.40
159.0708771	1.72
161.1385803	0.33
162.0182800	0.10
162.9542542	1.36
164.0468445	0.23
165.1154327	0.26
165.7278442	0.13
167.0761108	0.05
168.1012268	1.15
168.9445648	0.19
170.0303345	0.17
173.0642090	0.12
175.1805420	13.15
176.0964661	0.50
177.0573730	0.30
178.2096558	0.07
180.0905762	0.19
180.9206238	0.20
182.1097107	0.21
184.0356140	0.85
184.9747620	0.10
186.1210632	0.16
187.1926727	1.14
188.1052551	0.08
189.0916595	0.53
190.2701569	0.44
191.0939026	0.52
192.2306519	0.26
192.9821014	0.09
194.3333435	0.15
195.0379028	0.28
196.1585083	0.06
201.8519135	0.10
202.9711456	0.07
205.3368378	0.30
206.1924591	0.17
207.3683319	0.56
208.2991180	0.61
209.1049652	1.16
211.2674561	0.45
213.2548370	0.07
217.4066162	0.17
219.1464539	0.20
220.4719696	0.07
223.2289734	0.04
224.1086121	0.14
227.1067200	0.15
229.2457275	0.24
231.2627869	0.10
232.1036224	0.22
233.1371460	0.18
234.3713074	0.13
235.1671753	0.09
236.0846252	0.64
237.0338440	0.13
239.1704407	0.04
241.2331238	0.13
242.1876526	0.15
243.2313232	2.64
246.3526917	0.05
248.5053711	1.50
249.1597900	0.80
251.1801453	0.64
255.2376099	0.18
256.2950745	0.05
258.2767334	1.36
259.1633606	1.16
260.2343445	0.55
261.2178650	2.36
262.1734009	0.12
263.2588501	0.67
265.3587952	0.60
266.0049744	0.07
267.4494019	0.14
268.3023376	0.66
269.1276245	0.33
273.1768188	0.28
274.3441162	0.06
275.1890564	0.08
276.3523865	0.15
277.2396851	0.40
279.3309326	0.33
281.1776123	0.25
282.3486633	0.24
283.3654175	0.77
284.3007202	0.25
285.1918945	0.28
286.2437134	4.70
288.1920166	1.29
289.2291870	0.71
291.1274414	0.27
292.6566467	0.69
293.4521179	0.14
295.1165771	0.46
297.5019226	0.16
298.2045898	0.28
299.1287842	0.03
301.1351318	0.30
303.2387695	2.56
304.4771118	1.40
305.3520508	9.31
306.3393860	0.59
307.2112122	5.75
308.2543945	0.18
309.2955933	0.43
310.4180298	0.27
312.4305420	0.12
313.3807068	0.63
314.2787476	0.25
317.4078674	0.30
319.0950317	0.03
321.4538879	0.04
322.2840576	0.31
323.3004456	1.90
324.3205566	0.41
328.5008545	0.12
329.4119263	0.50
330.3479004	0.87
331.4215088	0.85
332.3904419	0.97
333.5763855	0.14
334.3084412	0.16
335.3538513	0.65
336.4587402	0.22
337.1322937	0.11
339.3302612	0.26
341.2378540	0.29
345.2387695	0.21
347.1948853	10.91
348.2177124	0.92
349.4156799	0.47
350.1227417	0.20
355.2087402	1.37
356.2155762	2.38
357.3251953	3.23
358.2537537	0.13
359.3809204	0.46
361.2816467	2.56
362.3022766	0.16
372.4162903	2.33
373.3625183	3.26
374.3569031	2.27
375.3733215	15.21
376.3793030	14.25
377.4105225	0.82
382.5121155	0.26
384.2538147	0.24
386.2333374	0.08
389.4719849	1.37
390.3752136	0.80
391.4408264	1.25
393.2901001	0.87
396.9649963	0.19
399.4419250	0.49
400.6004333	3.00
401.3262634	5.00
402.1310730	0.40
404.2603760	0.15
405.3085327	0.11
417.3267822	33.29
418.3330383	100.00
419.4968567	5.95
425.8648682	0.42
426.9234314	0.09
427.7336731	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	733.2923
Annotation	Unknow
Peak:m/z	Relative Intensity
225.0723572	0.04
233.2405090	0.16
245.1530609	0.15
273.3022766	0.16
288.1410522	0.06
297.1127014	0.14
312.4329224	0.27
313.2355652	0.05
321.0169067	0.03
327.2919922	0.09
328.3767395	0.06
345.5625610	0.14
361.1273193	0.04
363.2134399	0.17
364.2454224	0.48
387.0266113	0.11
399.2620239	0.05
412.9711914	0.06
415.4646606	0.03
426.9552002	0.06
433.3037109	0.11
443.5230713	0.39
447.4035645	0.10
449.4237671	0.03
451.0700073	0.53
453.1665649	0.11
455.2681274	0.22
457.2938232	0.06
460.1129150	0.11
467.0917969	0.05
477.7042236	0.12
480.9483643	0.07
482.0443726	0.15
485.1596069	0.18
491.9514771	0.03
498.5732422	0.08
505.8203735	0.08
507.3963013	0.06
508.1500244	0.08
519.3917847	0.07
527.4065552	0.07
529.6499023	0.14
531.3365479	0.27
534.9213867	0.06
544.0557861	0.06
545.5568237	0.10
553.4465942	0.81
557.3174438	1.57
559.3430786	0.23
563.7926025	0.19
567.1684570	0.08
569.1811523	0.88
571.2042236	1.39
575.1907349	0.14
581.1798706	0.37
583.3937378	0.16
589.2640991	100.00
590.4397583	0.38
593.8552856	0.14
595.5414429	0.60
596.5798950	0.05
611.1161499	0.41
612.3532104	0.66
613.1287231	1.05
631.3517456	54.62
632.4082642	0.75
653.0683594	0.16
662.2359009	0.20
671.3364868	13.07
672.0108032	0.02
673.1895142	0.75
684.9421997	0.13
687.0990601	0.60
687.9461670	0.47
689.2737427	0.75
689.9738770	0.13
697.1965942	0.13
699.2482300	0.11
700.1575928	0.07
701.2783813	0.52
702.3023682	0.09
714.3726196	0.56
715.3603516	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.093
Annotation	Unknow
Peak:m/z	Relative Intensity
132.7839203	0.04
135.1914062	0.15
135.9483337	0.12
145.1380157	0.11
146.9823303	0.22
149.1861572	0.17
150.8907166	2.69
152.8495636	0.07
161.0260925	0.07
162.7530975	0.54
164.1588898	0.03
165.0884552	0.63
169.0308685	0.23
174.0010834	0.82
175.2074890	0.48
179.0704651	1.17
179.9745483	0.09
181.0094604	0.05
185.0644989	0.20
186.8826447	0.06
191.2106323	0.04
192.6628418	0.26
196.8366241	0.02
198.8231201	0.03
201.1790924	0.10
203.5153656	0.12
204.2838745	0.27
205.2690277	0.02
206.0107727	0.03
207.1765442	0.23
209.2541199	0.09
211.2739868	0.22
213.0575714	0.27
215.2395630	0.16
216.0417938	0.09
216.8367310	0.05
219.2375183	0.03
223.2325439	0.17
227.0514526	1.67
228.0784912	0.14
229.2468414	0.32
230.2962189	0.04
231.1909027	0.31
232.9704285	0.05
237.0458679	0.10
238.1282043	0.06
239.2995300	0.11
241.1556396	1.47
241.9528198	0.08
243.1428833	1.33
244.0160828	0.02
245.0009155	0.07
253.1028748	0.11
255.0213928	13.87
256.0972900	3.49
257.1150818	1.17
259.0591736	0.79
260.2676086	0.09
262.8367004	0.04
265.1698303	0.16
267.2483521	0.28
268.0789795	0.05
269.1442871	2.32
271.2891541	0.33
272.9191589	0.12
274.7644348	0.17
277.2144470	0.03
281.1953735	0.24
281.9766846	0.04
284.0456543	85.49
285.0635376	100.00
286.1710205	1.47
291.3599243	0.07
295.1705933	0.52
297.0634155	0.41
298.2720642	0.35
299.1787415	2.74
300.1146545	0.11
300.8998108	0.14
303.9949951	0.02
307.1137390	0.06
308.9850769	0.17
311.2950439	0.12
312.8886108	0.03
314.1823730	0.26
321.2206726	0.06
323.0286255	0.10
325.1191101	0.09
327.0792236	18.72
328.1608887	1.11
339.1819458	0.50
341.1402588	0.05
350.9399719	0.30
357.1425171	2.14
357.9306946	0.06
358.5664062	0.04
379.3785706	0.21
380.2975159	0.13
382.7867737	0.29
393.1167908	0.04
419.2616577	1.48
429.2426453	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3077
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
162.0445862	0.28
163.1158905	0.25
184.164978	0.19
198.1320496	0.51
253.2709045	0.05
265.2067566	2.53
293.0924988	0.22
305.2687988	0.14
307.1388855	0.06
308.2540283	1.56
318.802063	0.08
321.3894043	0.19
326.2418518	0.17
339.2811279	91.97
339.9382935	0.29
382.4532471	0.38
386.3495483	0.15
392.2037048	0.07
404.4103699	0.16
406.1436462	0.05
419.1802673	5.47
424.2674866	0.08
436.6383362	0.28
437.5110168	1.52
444.4527588	0.16
462.2601929	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.1452
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
154.9645691	0.31
156.9869843	0.13
163.9008942	6.12
165.0963440	0.96
168.9703674	0.29
173.1018372	0.75
175.3054504	0.10
176.5777740	0.84
177.2718506	0.07
185.0900879	2.31
186.1239014	1.07
187.6104431	0.69
189.1437531	1.14
199.2528534	0.17
201.1517029	0.69
203.0884705	0.82
205.1320496	0.06
209.1592865	0.08
211.3209686	0.16
213.0834351	0.09
214.9199219	0.27
221.1609039	1.01
227.3083496	1.61
228.0900269	3.60
229.2532959	3.07
230.8808441	0.50
241.0923004	0.34
245.2767639	0.15
253.3378906	0.50
255.0006866	2.78
261.3455811	0.17
267.2116699	0.08
269.1780396	0.30
271.0828857	62.87
273.1251221	100.00
275.0866699	0.32
281.1251526	0.65
283.1196899	1.61
285.1105347	0.31
286.0166016	0.39
287.3438721	0.66
289.0969238	1.40
291.2743225	0.47
292.7927246	0.80
304.2721252	0.21
311.3880615	1.71
312.1641846	3.02
313.1676636	5.15
315.1453857	0.22
322.1257324	1.56
323.1626587	4.91
325.0820312	0.82
333.1635132	0.42
336.4901123	0.74
347.2774048	0.17
350.8580322	0.42
365.2037354	3.02
366.0452881	0.24
367.6455078	0.16
375.5877075	0.14
377.3400879	0.94
383.0433350	4.06
391.2035522	8.27
394.2039795	0.78
395.2593994	0.52
397.3245850	0.38
399.1174927	0.28
401.3004761	0.82
409.1162720	38.47
409.7523804	0.06
410.9359741	0.06
417.1633911	1.93
419.2281494	52.17
420.3248291	0.43
423.1868286	0.21
436.4474487	0.38
441.2340698	0.66
447.1380615	0.06
449.3082275	0.45
455.1849365	0.67
461.1729126	0.33
477.1306763	0.60
481.1305542	0.37
483.1435547	0.92
484.3815308	3.08
485.3363647	2.45
499.1591187	0.73
501.1994629	4.69
502.2086792	2.11
503.3734131	1.78
509.3430786	1.45
513.4940796	0.05
527.1232300	17.44
527.7631226	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.33
Annotation	Antibiotic BU 2867TA
Peak:m/z	Relative Intensity
159.3040009	0.21
166.0028229	0.10
183.9862671	14.76
185.0494843	10.75
186.0370636	10.29
187.0103760	2.32
195.1197815	0.21
226.0515747	0.12
227.3036804	0.27
234.1589050	0.08
242.2113342	0.03
243.0153046	0.05
260.0950317	0.18
267.1151123	0.29
277.3395691	0.09
283.0266418	0.22
305.2749634	0.15
329.2098389	0.25
335.3613281	0.14
336.3465576	0.54
337.5184326	0.18
347.3170776	0.18
349.3032837	0.08
369.2013550	0.29
376.9050903	0.20
416.3803711	0.12
423.2929077	0.10
428.7891235	0.10
444.1179810	0.11
447.9987183	0.70
450.5681763	0.07
461.0685425	0.06
465.8024902	0.17
469.4654541	0.42
483.5823364	0.22
485.4667358	0.10
501.3540039	6.73
503.3557739	100.00
504.0096436	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1662
Annotation	Spinosin
Peak:m/z	Relative Intensity
171.1133575	0.04
221.1759644	0.08
229.9783630	0.15
237.1320648	0.06
265.0528259	0.03
283.2344055	0.05
301.1354980	31.24
305.1185303	0.21
361.3218994	0.06
369.6054688	0.04
387.5725708	0.06
403.5167847	0.05
426.3856201	0.02
431.3020020	0.37
435.4139404	0.04
442.8480225	0.05
445.1810913	0.52
449.3370361	0.02
463.1016846	100.00
505.1808472	15.92
511.0655518	0.07
521.0348511	0.01
527.3538208	0.09
545.0458984	3.02
545.6842651	0.07
546.8762817	0.06
561.6853638	0.03
563.3181763	0.03
569.5770874	0.06
570.3898315	0.12
571.3564453	0.09
575.3729858	0.03
589.3469849	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.19
Annotation	Tubastrindole H
Peak:m/z	Relative Intensity
145.9654541	0.34
153.1531219	4.01
171.1064606	0.73
178.9688110	5.02
185.0733337	0.24
197.1008911	13.48
199.1406555	0.26
222.1347046	0.72
226.9143677	3.71
239.2695007	0.27
240.1613617	0.53
245.0100098	35.42
245.9291840	0.19
248.0599670	0.11
248.8689575	0.37
251.1021118	0.17
252.1176910	0.18
263.1416626	5.09
264.1828003	0.09
266.0903931	2.67
270.4302063	0.26
281.3042603	0.27
282.3161011	0.07
283.9926758	0.32
288.0850525	0.22
296.0078430	0.09
297.1882935	0.81
307.5198975	0.15
308.3125000	0.10
314.1806030	7.73
325.2686157	3.13
326.3197021	0.12
329.1999512	0.15
332.1164551	7.05
333.1571655	0.69
345.0416870	0.12
346.7457275	0.17
350.9940186	1.53
351.6068726	0.20
355.1109619	1.33
356.1177368	2.28
362.1329956	1.93
369.2265015	1.69
373.2226562	8.16
374.1909180	4.07
375.0028076	0.23
380.1781006	5.54
381.2633667	0.49
395.2794800	1.32
396.3943481	0.11
399.1586304	6.99
399.7589722	0.05
413.0980835	1.66
417.1719360	12.61
418.4895630	0.62
425.2490845	2.86
443.2750854	24.57
444.2376709	0.45
447.0215454	0.38
461.2047729	84.97
462.0203857	0.57
463.2287598	0.11
473.1039429	2.87
474.0493164	0.17
491.1272583	100.00
492.2422485	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
85.0154419	0.25
86.9834595	1.18
100.8922119	0.07
110.9547577	100.00
111.8080750	0.08
113.1150970	0.03
129.0064392	1.73
130.9545288	1.33
155.1066132	0.13
172.9934235	18.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.0706
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
85.8372040	0.13
109.9432983	0.07
127.9567566	100.00
133.9967346	1.36
153.0992432	3.12
171.1320038	1.39
179.0011292	0.16
197.0447693	1.88
198.9078217	0.03
215.0885315	6.01
227.0076752	4.86
244.9850311	34.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2731
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
170.8892365	0.13
178.9888611	0.20
223.0595398	4.43
233.1168671	0.45
241.0811310	40.51
259.2077637	0.21
275.2455750	0.84
277.2430725	100.00
278.0551147	1.40
315.0442200	49.93
333.1918335	1.11
413.2511597	43.84
414.2905273	0.45
431.2774658	1.21
458.6248169	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2399
Annotation	Newbouldioside A
Peak:m/z	Relative Intensity
216.9096985	0.24
222.9264679	0.13
241.0091248	0.19
259.2909241	0.16
261.0915527	0.07
271.3220215	0.13
272.1119385	0.06
277.1438599	0.95
279.1950073	0.11
283.6023865	0.14
289.1962280	0.06
295.5688782	0.13
301.1631470	0.26
311.0447083	0.21
319.2198486	1.22
321.3100586	0.11
322.0639648	0.22
323.2862549	0.14
327.3383789	0.10
337.1354980	5.63
339.0947266	0.67
341.0005798	0.23
349.0395203	0.12
359.4033203	0.19
367.0910645	0.43
369.2846680	0.23
371.3870850	1.40
372.2205200	0.60
373.2994385	0.32
387.1860962	10.60
388.2848511	0.27
401.1924438	0.27
402.1876831	7.37
403.1588745	13.50
403.7931519	0.03
417.2187500	100.00
445.4832764	0.14
447.4262695	0.13
449.4051514	0.20
452.9546509	0.18
455.2826538	0.14
467.4676514	0.39
483.0937500	0.27
491.3121338	0.05
492.2297974	0.11
503.1494751	0.05
507.2293091	0.17
517.2021484	0.32
543.1307983	0.42
547.1662598	0.08
551.2582397	0.11
561.2431641	0.72
565.1813965	3.14
575.0978394	0.15
576.2402954	0.11
579.3627930	0.86
589.2487793	0.06
592.3623657	0.14
593.2886353	0.35
603.3364258	0.14
605.1132812	0.35
607.2498169	0.10
609.2996826	0.31
622.0044556	0.49
629.5864868	0.08
634.6699219	0.10
635.3031006	0.10
645.1268921	0.11
647.2297974	0.39
653.4667358	0.16
663.3186646	1.28
668.8847046	0.08
679.3502197	0.44
693.0619507	0.31
695.0390625	0.46
700.3189697	0.27
705.1489868	0.13
706.6149292	0.08
709.4052734	0.40
711.3916016	3.58
713.5734863	0.11
717.2600708	0.05
718.9846802	0.75
723.1724243	4.94
736.7611694	1.32
737.3955688	1.73
738.4065552	0.68
739.0510864	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.0706
Annotation	N-Acetylcystathionine
Peak:m/z	Relative Intensity
85.9569855	0.21
128.0433655	100.00
134.0534363	1.15
153.0641479	2.50
171.0830841	1.70
179.1994171	0.22
197.0420074	2.28
215.0170135	7.67
226.9949341	4.99
245.0112152	36.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1063
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
130.1864624	0.02
221.2042236	0.02
237.1256561	0.05
241.0072327	0.05
275.0381775	0.02
287.0793762	100.00
287.6883545	0.26
288.9531860	0.02
292.4970703	0.02
299.3551941	0.01
322.8887939	0.01
328.1473083	0.02
329.2291870	0.39
353.0639648	0.09
367.6979065	0.02
383.1913757	0.19
395.1456299	0.26
403.7562866	0.03
404.4771118	0.01
411.1493530	0.01
413.1600037	0.27
417.2098694	0.03
431.1765442	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.4759
Annotation	PE(16:1(9Z)/20:5(5Z,8Z,11Z,14Z,17Z))
Peak:m/z	Relative Intensity
204.9112549	0.04
213.8218231	0.05
233.3285217	0.63
234.3260498	0.15
259.2869263	0.57
261.3863525	0.02
275.3809814	0.40
277.2339478	100.00
278.2025757	29.49
413.0621338	0.04
414.2136230	0.30
417.8345337	0.02
456.2675171	2.30
457.3746948	0.63
474.3184814	11.40
475.2877808	6.13
671.0917358	0.02
685.6784058	0.04
699.5753784	0.10
717.2578125	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.135
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.8211060	0.05
174.3213501	0.06
175.2353668	0.20
177.0827789	0.07
186.9305725	0.27
187.6994324	0.19
189.0117035	0.05
190.9738770	0.09
197.1549683	0.08
199.0062561	0.02
202.5100861	0.10
203.1436157	0.35
205.1465759	0.23
217.1957397	0.04
222.6828613	0.07
223.9815674	0.07
225.0434265	0.07
229.0985107	0.12
229.8388214	0.02
241.1722107	0.03
242.9226685	0.21
245.1463165	2.96
247.0856628	0.05
255.1144104	0.29
257.0271912	0.09
267.0978394	0.04
269.1110840	0.46
271.2345581	0.13
273.1098633	3.27
285.2745361	0.20
287.1679382	14.69
289.1389771	21.29
290.0801392	0.14
291.1740723	0.02
299.1775513	4.54
301.3492432	0.02
305.2182007	0.03
309.1746826	0.04
326.9760742	0.04
328.3828735	0.02
329.0761108	0.35
331.1482544	0.54
337.1456909	0.04
339.2045898	0.50
341.0832520	0.13
352.8790894	0.20
357.0853271	0.32
381.0426025	1.38
383.5968628	0.06
389.0889282	0.14
393.1372070	0.02
397.1569824	0.05
407.1589355	49.58
407.7944336	0.16
409.1919556	0.65
411.2244873	0.06
413.1463013	0.05
421.0878906	0.17
423.2816772	0.35
425.0834351	100.00
425.9303589	0.08
427.3733521	0.11
431.1304932	0.06
432.8390503	0.54
433.5178833	0.02
437.1599731	0.19
439.1386719	0.42
449.0932007	1.21
451.1185913	26.44
455.3580933	0.02
467.1873169	0.98
471.5681152	0.06
475.1364746	0.08
487.0744629	0.02
493.2653198	0.09
500.2324829	0.08
514.5184937	0.17
515.4149170	0.05
533.1358032	0.64
541.2902832	0.14
559.2393799	10.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.11
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
127.0274658	0.09
130.1220093	0.07
163.0889587	0.06
164.9255676	0.01
166.9299011	0.04
184.9484253	0.24
208.9524384	0.05
234.2991333	0.08
235.1609802	0.04
244.2737427	0.03
259.071106	0.03
263.2058716	0.04
265.839325	0.01
271.0550232	100.00
274.7697754	0.01
281.0504761	0.03
285.236084	0.16
286.0341797	0.08
287.1094971	0.10
294.8729248	0.02
297.0338135	0.01
299.1514282	0.01
301.3927307	0.04
316.3348999	0.03
326.0484924	0.03
327.0215759	0.01
331.4400635	0.02
338.8126221	0.06
345.6884155	0.06
351.9979248	0.02
356.7979736	0.04
360.1833801	0.02
361.2332458	0.05
369.0766907	0.08
371.3083191	0.05
372.2174988	0.02
373.3539734	0.02
381.2707825	0.02
387.1626892	0.07
389.9804077	0.01
397.1462708	0.13
404.8600769	0.10
405.5627441	0.03
415.0837097	0.96
416.144928	0.06
432.928009	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1568
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9369659	0.94
165.0415344	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0983
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
125.0798340	0.30
143.0420074	0.04
146.9229736	0.45
150.8068695	0.03
162.9455109	0.12
164.8854523	0.14
169.1673126	0.04
175.1846619	0.07
178.9913025	0.05
191.1340027	0.08
193.2004700	0.07
197.2341309	0.08
198.8600159	0.13
203.1657715	0.06
215.1669312	0.03
216.7546997	0.03
223.0272522	0.02
224.1897125	0.17
225.1376801	0.71
227.1870117	0.04
233.1721497	0.05
239.2386780	0.07
241.1215210	0.35
242.8540955	0.11
255.1622620	0.06
257.1449280	0.02
267.1145630	0.10
269.0005493	100.00
269.6006470	0.33
270.4432983	0.21
271.1276550	0.34
273.3747559	0.05
281.0774841	0.29
283.1346436	1.08
293.1190491	0.15
294.0440674	0.04
305.2962036	0.08
311.0904541	0.76
322.9318848	0.09
328.6820068	0.49
329.2836914	0.05
341.1504822	0.74
345.2061157	0.03
369.2842712	0.42
413.2597961	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3083
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
141.9094238	0.06
154.8523865	0.13
180.1874695	0.10
184.2095947	0.19
195.2963562	0.03
198.1507263	0.06
216.0152588	0.07
219.0838318	0.09
222.5010681	0.02
265.4758911	0.11
277.3188477	0.04
279.303894	0.07
298.4057617	0.07
307.5784302	0.08
308.3869629	0.22
309.2841797	0.09
326.2086182	0.08
328.3817444	0.05
333.3695679	0.12
339.2853699	100.00
357.5022278	0.04
364.0892334	0.08
390.1176147	0.08
406.6033936	0.03
413.4137573	0.18
418.7672119	0.16
419.486969	0.07
421.1126709	0.09
422.3889465	0.13
437.198822	0.10
446.225708	0.04
462.2297974	4.25
463.4400024	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	819.223
Annotation	Guibourtinidol-(4alpha->10)-[7,8-dihydro-8-(2,4-dihydroxyphenyl)-6-(3,4-dihydroxyphenyl)-7-hydroxy-6H-pyrano[2,3-f]catechin
Peak:m/z	Relative Intensity
228.5367432	0.35
231.0184937	4.45
237.1841736	0.06
241.0424042	0.74
242.0822449	0.41
243.1345367	1.65
244.2820129	0.65
245.0422211	0.84
247.8836517	0.20
251.3565521	0.34
253.7389526	0.45
255.1045532	3.87
257.0205688	0.55
265.2696533	0.05
267.0718079	1.39
269.0891724	0.81
271.0807190	0.84
273.1947021	8.17
274.1429749	4.43
275.0344238	4.08
279.1553955	1.08
283.1899414	0.09
285.1483154	4.98
286.0162354	1.44
287.1392822	4.95
288.9067078	0.06
293.0794373	0.05
295.2687988	0.79
297.0652771	2.50
299.0408020	0.96
303.1865234	1.59
310.9360352	0.15
312.9590454	0.31
313.5949402	0.56
315.2909241	0.75
317.1445007	0.42
323.0093384	0.16
325.0954895	0.35
327.0603027	0.16
335.1128540	0.30
341.2618408	0.26
345.2158203	0.74
347.3503418	0.30
349.2177124	1.05
351.1416626	0.30
359.3446960	0.88
361.3352356	0.20
362.0505981	0.06
363.3161621	1.56
365.1774902	0.17
367.1853638	2.05
370.9146729	0.11
372.8827515	0.86
373.5370789	0.57
375.2142334	1.01
377.1977539	9.06
379.1833496	1.80
380.3532104	1.09
381.2550049	0.27
383.1981812	0.26
385.2927856	0.10
389.1710205	2.07
391.2412109	24.15
393.1939087	13.29
394.3273926	0.07
396.9124146	0.47
398.9169922	0.17
401.1240845	5.22
403.1093750	11.52
403.7832031	0.21
405.1705933	4.19
409.0355835	28.33
411.1206055	6.01
415.2093506	0.93
417.0502319	0.39
419.1181641	12.17
421.1475220	23.38
423.1473389	2.31
433.0715942	3.69
435.1983643	1.32
439.0789795	0.17
449.6281738	0.19
450.5593262	0.20
451.4528198	0.24
453.4215698	0.15
478.1979980	0.25
485.2419434	5.86
497.1442871	1.01
499.1539307	1.40
502.6026001	0.47
503.2137451	4.70
509.1474609	15.74
511.1517334	0.77
513.3906250	0.08
515.2373657	0.31
517.0778809	0.24
521.4133911	0.28
523.0139160	0.05
527.1661377	26.41
529.1042480	4.50
536.1264038	0.09
539.0400391	3.13
541.0330811	0.67
544.9390869	100.00
545.6436768	1.06
547.0994873	23.88
548.0223999	0.23
549.5025635	0.23
550.5494385	0.11
553.2652588	0.19
557.0427856	2.61
559.1390991	4.10
563.0543213	0.28
571.2234497	0.17
588.8920288	0.99
599.0149536	0.31
604.7432861	0.23
621.2344971	0.12
629.2254028	0.08
633.1217041	0.47
639.2651978	0.47
642.3697510	0.12
647.1564331	2.96
651.0606079	4.55
651.6840210	0.09
657.2791138	1.20
659.2827148	0.36
662.8814087	0.07
665.1653442	21.45
666.0820312	0.14
674.7274170	0.45
675.3317871	1.76
677.1646118	0.34
683.1614990	14.18
693.0783691	6.83
694.6652222	0.07
707.3511353	0.26
748.6392212	0.78
757.2897339	0.16
775.4912109	0.09
778.1170044	0.36
783.2164917	0.19
786.6449585	0.25
787.4265747	0.11
801.0631714	4.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2187
Annotation	Ficusesquilignan B
Peak:m/z	Relative Intensity
164.9907074	0.42
171.2631531	0.03
180.3759613	0.05
195.0516357	2.76
201.3160248	0.07
208.7965698	0.04
221.2400665	0.02
249.1847992	0.05
270.2929993	0.07
293.3890991	0.07
314.4315186	0.08
323.2550659	0.34
324.0358276	0.06
325.1907959	0.49
327.2345581	0.46
336.9682617	0.46
338.1071777	0.54
339.2945557	2.18
340.1817017	0.14
341.4736938	0.29
342.2722168	0.17
343.2189331	0.39
354.2349854	3.09
355.1917114	0.48
357.2163086	27.70
367.3674927	0.09
369.2643433	46.54
372.2341309	0.07
373.0592041	0.07
381.2139893	0.10
382.4797974	0.03
384.1250000	0.12
385.1797485	0.23
386.7084351	1.51
397.2933960	0.13
399.4299927	0.03
401.0643921	0.04
403.2830200	0.10
406.5643311	0.08
412.0691528	0.05
415.2385254	0.07
417.9352417	0.06
421.1704102	0.26
429.2236938	0.12
463.1877441	0.05
469.5885620	0.14
475.2898560	0.08
487.3123779	0.25
489.1362305	1.65
493.5955811	0.04
497.1329346	0.07
499.1817627	0.05
505.3033447	0.81
505.9562988	0.07
511.2241211	0.18
516.6920776	0.05
517.3123169	2.74
521.3347168	0.16
522.2546997	0.07
523.4091797	0.31
524.4823608	0.16
533.6101074	0.03
535.1755371	100.00
535.8345337	0.44
537.0166626	0.11
539.1673584	0.99
543.3377075	0.07
545.4604492	0.34
546.9818726	0.08
547.9924927	0.30
549.3737793	0.12
551.2982178	0.07
553.2416382	2.06
560.2826538	0.09
565.0432129	6.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1631
Annotation	Pelargonin
Peak:m/z	Relative Intensity
196.967926	0.11
247.0210876	0.15
259.485199	0.25
271.0554199	74.58
275.2474976	0.35
283.2329712	0.31
288.9741211	0.09
290.5153198	0.21
303.3261108	0.29
304.2236328	1.82
313.0095215	0.09
336.6920166	0.18
368.9121094	0.06
389.3095703	0.40
422.9784546	0.59
425.1150513	1.11
426.987793	0.24
431.2268677	0.05
433.0908813	100.00
433.7633057	0.51
443.2809448	1.96
451.1796265	0.43
454.9141235	0.19
462.1566162	0.48
463.263916	0.32
464.1917114	0.49
466.0395508	1.59
475.0090942	0.18
499.5484619	0.09
534.4151001	0.23
546.5415649	0.12
549.2761841	0.18
577.1743774	3.31
579.171936	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	849.22
Annotation	Itoside J
Peak:m/z	Relative Intensity
245.2170258	0.02
249.8790894	0.07
255.0330200	0.07
257.4411011	0.05
258.2133179	0.03
270.1890259	0.08
271.3802795	0.04
273.1228027	0.08
277.1241150	0.08
279.4550171	0.06
285.2588196	0.04
287.1022949	0.13
297.2853394	0.07
299.1135864	0.02
303.2383728	0.06
305.1060181	0.03
318.2257080	0.05
321.3652039	0.04
328.7465210	0.04
331.9595642	0.01
337.2328491	0.09
342.5624390	0.04
343.2667236	0.11
347.2267151	0.02
361.2491455	0.16
363.0581055	0.17
368.9221191	0.05
371.1697998	0.34
377.1631470	0.03
379.2281189	0.17
381.2009277	0.04
387.2655945	0.03
389.0521851	0.11
391.0565796	0.10
392.9918213	0.07
395.2382812	0.04
399.1881714	0.46
400.0654297	0.65
403.0338135	0.15
405.1881104	0.09
415.2888184	0.05
417.3143311	0.02
419.1014404	0.03
425.3658447	0.06
431.3856201	0.05
437.2205811	0.03
448.9113159	0.03
454.7058716	0.04
461.3553467	0.19
478.9704590	0.08
497.3530884	0.13
499.2333374	0.06
505.2053223	0.02
507.1571655	0.19
509.2888184	0.27
517.1495361	0.32
519.3391113	0.17
523.3870239	0.39
524.6173096	0.85
525.3027954	13.83
526.4142456	0.05
529.0338745	0.02
533.3779297	0.01
535.1594238	0.12
541.2192993	0.45
543.0855713	0.23
545.1260376	0.02
549.1213379	0.02
550.4395752	0.01
553.2005005	0.04
557.2388306	0.22
559.1333618	0.61
561.0703125	0.30
564.7356567	0.10
566.8875732	0.05
569.0390015	0.04
571.3485718	0.11
573.3246460	0.15
575.0036011	0.04
577.2274170	0.13
579.0248413	0.04
591.3270874	0.07
639.4141235	0.02
645.4617310	0.05
661.2545776	0.15
665.4791260	0.05
669.2984619	0.03
678.4864502	0.19
679.1852417	0.75
685.7050781	0.02
687.1519165	100.00
687.8473511	0.24
693.0102539	0.10
693.6979370	0.07
695.6632690	0.05
696.7045288	0.17
697.4208374	0.11
701.4060059	0.09
703.2269897	0.04
713.1534424	0.77
720.1461792	0.06
722.9337769	0.09
765.1627197	0.09
771.8004150	0.14
777.1992798	0.02
791.2990112	0.15
795.1345825	0.12
805.5490112	0.08
813.0207520	0.11
830.3085938	0.09
831.1050415	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.2997
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9851990	0.13
220.9136047	2.81
246.7304688	0.12
262.8711548	1.56
263.6290283	0.18
303.0197144	0.30
320.3540039	0.14
353.1320190	0.29
401.5956421	12.64
402.3029175	0.09
437.3759155	3.88
438.0098267	0.21
455.2393188	0.60
463.5731812	0.34
478.9802246	0.52
481.0267334	0.48
494.2479858	0.31
499.1577148	0.24
505.4559937	1.02
513.3562622	0.43
526.6124268	0.16
527.3871460	0.97
536.2973022	5.18
536.9682007	7.73
544.7006226	0.50
552.6119995	0.14
557.2243042	0.85
565.8296509	0.88
572.6049194	0.16
582.1453247	0.20
584.4487915	0.47
586.2942505	2.06
605.4510498	0.25
608.2794800	2.74
713.3181763	1.61
714.2636108	0.36
719.2823486	0.72
729.3184204	0.68
730.3688354	0.56
732.6984863	0.15
733.3435059	0.15
735.3856201	0.53
736.4280396	0.28
751.5462646	0.65
752.6575928	0.21
803.4898071	2.02
833.5518799	0.11
865.1414185	0.71
875.3820190	11.24
876.3286743	2.78
890.9777222	0.23
893.5584106	3.09
894.4499512	1.13
907.3973999	0.17
911.2243652	0.13
912.4140015	0.29
923.6857910	1.84
941.5298462	8.84
942.3263550	3.89
958.7072144	0.37
1009.4924930	0.21
1011.7614140	0.61
1012.5268550	0.57
1030.3278810	0.10
1037.9025880	0.72
1038.8098140	0.45
1055.4390870	14.93
1056.6209720	3.75
1073.4599610	100.00
1074.4541020	42.52
1132.5335690	0.19
1134.6618650	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	865.21
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
244.2302856	0.10
246.8819427	0.10
259.2716370	0.15
261.3288269	0.30
265.2523499	0.03
271.2079773	1.17
272.8887024	0.12
283.1790161	0.08
287.0405884	0.23
299.3173828	0.05
305.0801392	0.22
317.1957703	0.22
332.9838867	0.02
357.2183228	0.09
358.8190613	0.04
367.0115356	0.05
375.2485352	0.23
385.2224121	0.16
391.1710510	0.07
395.4070435	0.06
407.1819458	0.67
411.0855713	0.04
413.1013794	0.11
415.1399536	0.51
423.1324463	0.19
425.3254395	0.05
429.1269531	0.04
433.3001709	0.42
435.0153198	0.03
439.0502319	0.30
442.0726929	0.04
449.0167847	0.13
513.0666504	0.22
514.3562012	0.05
515.4000854	0.11
523.1865234	0.13
527.3944702	0.14
533.1847534	0.23
541.1552734	25.18
541.7687378	0.10
545.2022095	0.08
551.2610474	0.05
553.4727783	0.23
557.3329468	0.14
561.0596924	0.11
565.1790771	0.04
569.1815186	0.10
572.8442993	0.15
574.6710205	0.52
575.3639526	0.18
577.0923462	0.16
578.0969238	0.10
583.6485596	0.27
585.3026123	0.03
587.0844116	0.15
591.2357788	0.14
593.1241455	0.12
595.4992676	0.02
601.4641724	0.10
603.2446899	0.15
607.1200562	0.13
617.3004761	0.06
618.1658936	0.06
619.2196655	0.07
621.2460327	0.04
677.2396851	0.13
684.8084106	0.03
695.1185913	0.94
695.7308960	0.13
703.1215820	100.00
703.7629395	0.62
704.3706055	0.04
707.2020874	0.07
711.2455444	0.23
713.1891479	1.28
725.1987305	0.07
729.0873413	0.08
793.6234741	0.09
829.0770874	0.07
847.1126099	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1413
Annotation	AN-7
Peak:m/z	Relative Intensity
205.137085	0.06
256.997467	0.03
389.3709412	0.06
403.1558533	100.00
403.7609863	0.19
405.4534607	0.13
431.4528503	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1664
Annotation	Butrin
Peak:m/z	Relative Intensity
188.1922302	0.09
219.1994324	0.30
226.2974854	0.04
235.0522156	0.09
271.0328369	0.34
272.9971313	0.43
277.0571289	0.06
283.0294800	0.16
285.1599731	0.23
286.8547974	0.09
289.0114136	1.16
291.1060181	0.07
293.1921997	0.35
299.1589966	0.11
307.0891724	0.05
313.1578369	1.26
316.0914307	0.72
341.2030029	0.76
343.1723633	1.07
349.3205566	0.12
352.6318359	0.11
353.3646240	0.19
355.1893921	100.00
367.1613159	2.22
371.1591797	0.30
379.1115723	0.33
381.1405029	0.05
383.2103271	0.18
385.1521606	97.83
385.7584229	0.30
397.1443481	2.52
399.2900391	1.12
411.2483521	0.87
415.2570190	32.55
421.2413330	0.23
425.4381714	0.08
427.2425537	1.91
429.3764038	0.11
432.9448242	0.44
433.5645752	0.15
437.2261963	0.04
439.1678467	1.26
440.3269653	0.13
443.2985840	0.28
445.2774658	2.59
449.1877441	1.70
451.1559448	1.97
457.1734619	21.92
459.2327271	0.25
469.1829224	1.83
473.3524170	0.06
475.1737671	65.64
476.2791138	0.06
478.9187622	0.21
487.1835327	15.48
494.5308838	0.14
499.2053833	0.46
501.1067505	0.37
505.2520142	27.35
517.3270874	1.18
523.2094116	0.24
529.4918823	0.15
531.2734985	0.62
535.0954590	0.18
541.1006470	1.06
549.2454224	4.49
551.2572632	0.97
559.2384644	3.68
560.3170166	0.11
572.2429810	0.99
577.2546997	14.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	328.1738
Annotation	Unknow
Peak:m/z	Relative Intensity
117.7807388	0.06
130.9442139	0.08
134.7116699	0.04
136.0846252	1.14
137.0537872	0.77
153.9864197	100.00
154.9732971	0.10
156.1234741	0.02
173.1038513	5.04
217.9803772	0.19
222.7625427	0.08
238.4425354	0.03
241.2616272	0.22
244.0687256	0.32
265.0308228	0.04
265.7301331	0.11
266.3661804	0.35
270.9948120	0.15
281.9964600	0.63
283.7312622	0.07
309.7962036	0.07
327.8397827	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1089
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
131.0136871	0.07
145.0879211	0.05
148.6296539	0.06
150.8882599	0.04
152.0045471	0.26
154.0946808	0.10
156.2215576	0.15
157.1707916	0.21
158.2218933	0.08
164.8717651	0.09
172.0807800	0.04
172.9916687	0.33
175.0569916	0.11
176.9145508	0.03
178.9597778	0.03
179.9425659	0.41
181.2170715	0.03
197.1490479	0.31
199.1014252	0.19
200.1768494	0.18
201.1481018	1.18
202.7597504	0.04
215.0396118	0.19
218.8888397	0.07
227.3861847	0.05
241.1375122	0.32
243.1603394	4.73
244.0439148	0.07
245.2874146	0.06
259.0644836	74.13
260.2553711	0.27
269.1683044	5.23
270.2059326	0.20
283.0895691	1.71
285.4100342	0.04
287.0541382	100.00
288.1741943	1.70
297.1679688	0.06
300.9790955	0.32
311.0783386	0.32
313.3019104	0.04
325.1415405	0.04
329.2242432	0.51
341.2644653	0.05
355.1278687	0.13
371.3230896	0.15
404.2103271	0.11
417.1390686	0.17
419.2746887	0.03
421.2252808	1.35
422.3445435	0.05
431.1306763	3.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1089
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
134.9393616	0.08
137.0710297	0.37
149.0644226	0.73
162.9496613	0.09
163.9454956	0.08
165.0195923	1.16
167.0290833	0.04
176.8094025	0.13
179.1823425	0.06
190.8171082	0.07
193.0181732	13.18
198.0688171	0.04
199.1392517	0.06
201.0461121	0.28
206.9644318	0.06
219.1314240	0.12
222.8468018	0.05
226.2477112	0.02
227.2915497	0.03
234.9593353	0.05
236.0517273	0.04
237.2740326	0.10
239.0693054	0.03
243.0413818	0.81
258.0518799	0.02
259.2439270	0.21
265.4372864	0.03
267.1488953	0.06
269.1512451	30.03
281.3017273	0.08
283.1999512	0.10
284.0068665	0.12
285.2695312	0.13
286.4533081	2.74
287.1096191	28.06
295.2637939	0.03
299.0466919	0.34
304.8378296	0.03
311.1053467	0.09
314.9151917	0.12
321.3189087	0.18
327.3051453	0.03
329.1828308	11.74
331.0734863	0.12
341.3175049	0.04
355.0986633	100.00
359.2204895	0.03
363.0479736	0.16
371.2259216	0.04
387.5593567	0.10
401.2532654	0.19
401.9166565	0.05
403.3069763	0.80
405.2370911	0.46
431.1239929	3.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.18
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
124.3450851	0.04
124.9549408	0.27
129.0262909	0.38
131.3143921	0.14
132.1946411	0.11
142.9659271	0.33
147.0208588	0.52
149.0155945	0.16
155.0431976	0.06
160.9308777	1.42
163.1269073	31.55
168.8975220	0.28
172.8346405	0.27
178.9801636	0.03
187.0213623	0.29
189.0441895	0.26
202.6691895	0.08
203.3151093	0.29
204.9830933	8.80
207.0555267	0.36
209.1157837	0.90
221.2106628	0.46
223.0428772	10.55
225.0007935	9.58
249.1298523	0.22
260.9619751	0.13
287.1789551	0.24
313.3281250	0.29
321.2081299	0.39
324.8100586	0.13
336.9218445	0.16
341.0268555	0.18
343.2190552	1.24
351.3199158	0.46
353.3655396	0.15
369.2093811	38.59
370.4565735	0.63
373.2943420	0.11
381.3946838	0.08
382.9465637	0.58
385.4480591	0.74
387.2741089	100.00
392.9859314	0.18
411.2000427	3.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.1453
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
158.9951477	0.04
161.0424652	0.13
162.8626404	0.27
164.0020447	6.00
165.0781708	1.68
166.2192993	0.13
167.0589905	0.13
172.0931396	0.15
175.2274323	0.05
176.1188049	0.14
176.9072113	0.23
179.2247925	0.06
183.9515381	0.10
184.9055176	0.59
186.9607849	1.77
188.1307526	0.05
189.1104736	0.64
201.1072388	0.08
203.2300568	0.68
205.0831451	0.23
209.8865356	0.05
214.6424408	0.08
218.7975006	0.10
227.0189819	0.88
228.0559692	1.89
229.0749969	3.01
229.6917419	0.07
231.2413483	0.53
233.0694275	0.07
235.1278229	0.30
239.3126526	0.06
241.1056213	0.14
243.1533813	0.20
251.0614624	0.08
253.0859985	0.27
255.0854492	0.55
259.1742554	0.50
261.2566833	0.04
265.0483704	0.05
269.1465454	0.86
271.1036987	31.44
273.1759033	61.73
274.2489624	0.20
275.2322998	0.06
280.2106323	0.15
283.1008301	1.16
285.2460327	0.31
293.0726929	0.16
296.1924438	0.05
312.1461792	8.24
313.0951538	7.58
315.2055664	0.13
323.2199707	0.47
325.1870117	0.77
326.1749268	0.05
337.3883057	1.17
340.0778198	0.10
348.1697998	0.07
349.3150635	0.16
350.9946899	0.28
357.0424194	0.15
365.3135986	3.43
367.2788086	0.32
375.2428589	1.12
377.0248413	0.44
381.3386841	0.10
382.2935181	0.49
383.4881592	0.27
391.1993408	8.23
393.7734985	0.18
394.3960571	0.08
395.2296143	0.50
397.2753296	0.18
400.1429443	0.09
401.1837158	2.90
402.2407227	0.02
407.3119507	0.05
409.1317139	36.26
409.7538452	0.06
410.9637451	0.12
415.1815796	0.16
417.1182251	1.10
419.1392822	100.00
419.8425903	0.89
421.1528320	0.38
423.1764526	0.08
424.0945435	0.24
425.1854248	0.10
430.9321899	0.25
433.2227783	0.14
439.1419678	0.06
441.3130493	0.11
442.7196655	0.08
443.3624878	0.32
449.1337280	0.23
451.2480469	0.23
457.2796631	0.15
459.4726562	0.06
461.0913696	0.66
466.3633423	0.04
483.2743530	1.29
499.2916870	0.36
501.2695923	3.96
502.9412231	0.03
504.2308960	0.10
509.2138062	0.58
525.3746948	0.22
527.2075806	21.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1661
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
109.1179199	0.24
112.9927826	3.29
118.9940796	2.54
124.9302826	0.85
130.4127655	0.83
131.2213593	0.16
142.9169006	0.64
145.1545715	0.91
147.3543854	0.13
148.9537506	0.20
161.0797882	0.98
163.0387268	58.89
163.7542877	0.76
165.0266113	0.58
179.0206299	0.39
189.1526794	0.18
193.0376587	0.76
207.1540070	100.00
208.0478363	0.19
208.9495850	0.11
217.3219299	0.07
225.1799011	5.66
244.3166504	0.24
249.1390076	0.29
251.3658142	0.47
273.1646118	0.36
287.1724854	0.71
288.8882141	0.45
341.1768494	0.33
342.6427917	0.13
369.2221375	26.24
370.4585571	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.323
Annotation	PS(10:0/10:0)
Peak:m/z	Relative Intensity
184.1429901	9.49
187.5679626	0.10
239.0229950	0.08
258.2682800	0.19
259.2578735	0.08
261.0166626	0.11
271.3020935	0.09
285.4041748	0.08
288.4566650	0.11
301.3521423	0.17
319.4551392	0.06
347.5473022	0.05
351.9999390	0.10
360.9667358	0.08
371.1418457	0.13
375.2885742	0.10
382.6029663	0.14
396.3060913	0.22
406.5396729	0.15
407.2697144	0.07
409.2337646	0.13
410.1768799	0.15
412.3367310	1.02
415.2687988	0.07
419.5574341	0.21
427.2804565	3.70
430.0261230	0.21
434.3082275	3.06
436.1726685	0.18
439.2366333	0.16
452.3471069	43.95
462.2518311	0.14
473.3356323	0.17
474.4089966	1.13
478.0964966	0.62
479.4933472	0.18
492.2648315	13.19
495.9787598	0.81
496.5970459	0.58
514.4569702	9.96
532.3944092	38.45
536.9562988	0.19
540.6201782	0.15
544.7140503	0.47
545.9916382	0.41
550.2688599	100.00
551.3345947	0.30
558.6849976	0.11
559.3923950	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1744
Annotation	Unknow
Peak:m/z	Relative Intensity
160.1192932	0.04
183.9158936	0.09
193.1651917	0.13
199.8803711	0.03
202.1592712	0.47
216.8997498	0.06
220.2161865	0.06
247.1461945	0.20
248.1555176	1.49
254.1541138	0.03
260.1572266	0.04
261.1115723	0.06
265.0357971	100.00
267.0740356	0.12
271.1013794	0.14
271.8912964	0.02
273.0438232	0.22
277.0268860	0.43
280.5103149	0.02
281.1773682	0.29
285.3634644	0.12
288.7235718	0.03
291.0296021	0.15
303.0597534	7.04
322.1751099	0.10
344.0530396	0.03
355.3076782	0.06
370.1568604	0.06
386.3415527	0.14
387.1761475	0.09
399.1030273	0.03
401.2211914	0.06
403.5814819	0.05
405.2774658	0.54
432.9160156	0.58
433.9787598	0.63
435.1622925	2.07
437.3619385	0.20
438.5498047	0.04
443.2676392	0.07
477.1077271	0.10
481.0424805	0.02
511.1085815	0.08
513.8665161	0.03
530.7966919	0.08
535.1493530	0.06
539.0282593	0.32
548.6914062	0.08
549.3434448	0.04
550.0941162	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1859
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0533447	0.32
131.9719543	8.67
139.2399902	0.03
148.0595856	0.07
168.2837830	0.04
198.1283875	1.79
205.0218811	0.02
209.2047729	0.03
215.0064545	0.51
225.2502136	0.07
226.3739319	0.01
227.2331848	0.02
228.2209167	0.05
238.2835693	0.01
241.1424561	0.72
243.1932678	1.50
244.1468506	3.44
249.2036438	0.02
259.2157593	0.41
261.1110535	100.00
274.8756104	0.02
277.1653748	0.15
284.1934204	0.11
309.2261963	0.03
314.4633484	0.01
317.5405273	0.11
326.2127075	0.21
327.2145691	0.72
335.9381104	0.04
344.0396118	0.09
354.2822571	0.26
358.2486267	0.05
372.1727905	1.09
373.1449280	0.57
381.8528442	0.08
388.2782898	0.03
391.3157654	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	340.213
Annotation	Unknow
Peak:m/z	Relative Intensity
110.0044174	0.19
114.0119934	0.07
119.2494354	0.07
128.0922241	2.00
129.9754486	100.00
130.9439392	0.09
135.8772736	0.07
137.0183716	0.25
138.9381866	0.30
141.2118683	0.29
147.0239563	2.05
154.2231445	0.07
165.0585327	1.35
167.2818604	0.57
171.3287659	0.07
172.0938721	0.46
175.0632172	0.13
177.9588623	0.18
181.3531494	0.12
183.3212128	0.19
189.2238770	0.09
192.2820435	0.20
193.9685211	0.08
209.3930969	0.33
213.0591125	0.08
222.2030640	1.05
226.2242432	0.09
228.3283997	0.09
242.3021545	0.06
250.1414490	0.14
252.1774902	0.13
255.3023682	0.06
260.2836914	20.47
261.2884521	0.21
276.1680603	0.24
278.0502930	0.35
282.2469788	0.18
293.7467041	0.28
294.5145264	0.06
296.2262573	1.15
297.2492676	0.12
304.2034302	0.16
310.9442139	0.07
320.0981445	0.08
322.2469177	9.63
323.3337402	0.59
325.2305603	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.1272
Annotation	1-Acetoxy-7-hydroxy-3,7-dimethyl-2E,5E-octadien-4-one
Peak:m/z	Relative Intensity
66.9769287	0.57
70.9115753	0.14
77.0197754	0.03
84.9569855	8.91
88.0220032	0.02
94.9696350	0.03
97.0352020	0.09
99.0098877	0.57
100.1291962	0.01
106.9808960	0.02
110.9931488	0.44
113.9045715	0.06
117.1597443	0.03
118.9803925	0.39
121.0582733	0.15
123.0476532	0.01
125.0879364	0.17
126.8557892	0.15
129.0863495	0.13
130.9942169	0.98
133.0532532	0.05
134.9282379	0.11
139.3774109	0.02
140.9349823	0.03
142.9987946	1.01
145.0707855	1.61
146.9705048	0.15
149.0741882	1.49
153.2574615	0.03
155.0170746	0.07
159.0455322	0.19
162.9749908	1.77
165.1403961	0.06
167.0505829	4.50
169.0923157	0.06
173.1865845	0.11
179.0167542	0.54
181.0383453	0.11
182.5799103	0.01
191.0821838	41.22
194.8105164	0.04
197.1070404	0.83
199.0872345	0.06
206.1570435	0.29
209.0569000	100.00
215.5043182	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1117
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
123.1138992	0.01
126.8324814	0.04
131.1724091	0.03
135.070343	0.01
139.0180664	0.16
156.1522064	0.01
160.9992218	0.01
162.4271698	0.03
163.0971222	0.10
165.0119171	0.04
177.1998901	0.01
180.366272	0.03
185.0950623	0.06
187.0331421	0.44
192.9281006	0.07
198.9746094	0.01
202.7187958	0.01
207.0231323	0.07
208.2420654	0.03
209.0609283	0.02
211.2068939	0.02
213.2119598	0.01
217.9290619	0.01
225.0280609	0.05
225.8766174	0.01
227.0010681	0.32
228.3013611	0.01
229.1148987	0.22
231.1903839	0.02
232.2294312	0.04
243.0959167	0.18
244.9595032	0.03
252.9775391	0.20
255.085968	0.69
263.245636	0.02
269.0184937	0.04
271.0575562	100.00
272.1665955	0.03
273.0599365	0.08
277.2229614	0.01
279.5545959	0.02
281.2594299	0.09
282.0745239	0.03
285.9855347	0.02
287.1334534	0.01
289.0655212	1.18
294.7816467	0.03
296.8705139	0.01
300.0428772	0.01
301.2745361	0.01
303.2715149	0.02
304.0656128	0.02
309.156311	0.04
311.0136108	0.02
313.2778931	0.19
315.1224365	0.01
320.2199402	0.00
321.1829529	0.05
337.2309875	0.01
339.0890503	0.04
344.2809753	0.02
347.1193542	0.03
351.1677856	0.01
361.0408325	0.03
367.5448303	0.05
369.3420715	0.03
379.2850037	0.07
387.7685547	0.00
396.8389587	0.03
397.4631042	0.06
401.0021057	0.01
404.8902283	0.02
415.1390686	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8851013	0.25
290.9005127	4.53
374.6430054	1.43
456.2150879	0.36
457.0305176	0.32
458.6054688	19.58
480.0534668	0.05
499.2250977	0.05
516.9931641	0.09
534.9077148	0.11
536.0929565	0.35
539.8699341	3.30
540.8894653	0.86
542.4229736	100.00
543.4955444	0.08
544.6043701	0.09
623.7932739	7.94
625.8496704	61.03
626.6551514	18.79
627.4231567	0.06
664.0792847	0.34
664.7918091	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.1168
Annotation	1,5-Secovibralactone
Peak:m/z	Relative Intensity
69.1146393	0.04
70.8499832	0.73
76.7991562	0.08
78.9831085	1.48
82.9349976	0.05
85.0966949	0.17
90.9544983	0.34
92.9812622	3.40
94.7141724	0.13
98.9922180	0.04
103.0789185	0.04
105.0301971	1.96
106.9692535	4.23
109.0261536	0.20
112.9455414	0.13
116.8063812	0.11
118.2047577	0.03
119.0842133	0.58
120.9425659	17.10
123.0397644	0.48
125.0686646	0.16
126.8915405	0.67
128.8880768	0.94
130.9761810	79.58
132.9058685	0.20
135.0473480	3.68
136.9489899	0.11
138.9430847	0.55
141.1330414	0.03
143.1438751	0.02
144.9705658	15.74
147.0592499	7.79
148.9809723	21.78
150.8567352	0.76
152.9860229	6.02
155.0752716	0.34
163.0874786	15.75
165.0280762	13.11
166.9369965	2.53
167.7091675	0.04
172.3534241	0.48
173.0984039	1.46
175.1111145	0.12
177.0388947	0.04
179.1716156	0.22
180.3907623	0.10
181.1838989	0.39
184.6522827	0.15
190.9964142	100.00
191.6332550	0.17
194.3333130	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	656.2966
Annotation	2'''-N-Acetyl-6'''-deamino-6'''-hydroxyneomycin C
Peak:m/z	Relative Intensity
209.3504639	0.05
231.0000305	0.06
241.0639343	0.04
243.4798126	0.02
249.0860748	0.03
251.3357697	0.05
267.1969604	0.03
271.3614502	0.04
286.3640747	0.04
289.0858154	0.17
291.2435608	0.05
298.2734985	0.07
298.9674683	0.04
300.2875977	0.09
303.3890991	0.02
305.4341125	0.24
313.0860596	0.02
318.2425232	0.08
319.2030640	0.06
320.1881104	0.04
323.3353882	0.05
341.3534546	0.09
345.4953613	0.04
349.4371338	0.02
351.2285767	0.41
357.0310669	0.03
367.2005005	0.09
368.8714600	0.03
370.1780396	0.02
385.3651733	0.02
387.5166016	0.26
388.2736816	0.07
389.0841675	0.03
393.1732178	0.05
394.3784180	0.13
403.1033325	0.10
433.0452881	0.02
442.6284180	0.06
451.1096802	0.10
452.2166748	0.10
459.3211670	0.05
461.4062500	0.08
462.6639404	0.03
465.0458374	0.04
468.2087402	0.12
474.2446289	0.09
477.4213867	0.09
480.5446777	0.36
481.5115967	0.07
485.7337036	0.03
487.1571655	0.06
488.2000122	0.02
495.3986816	0.11
498.4003296	0.23
507.0083618	0.09
525.1958008	0.21
536.5825806	0.04
545.9883423	0.07
554.7529297	0.04
579.3154907	0.07
591.2133179	0.03
594.4949951	0.07
595.4071045	0.05
596.5366821	0.23
597.2534790	0.21
604.5214844	0.19
608.7276001	0.08
610.1701050	0.18
611.5089722	0.30
612.4143677	0.04
613.3852539	0.09
618.4469604	0.22
621.2929077	0.06
622.1859131	0.08
625.3020020	0.03
629.4161987	0.05
633.3737183	100.00
634.4505005	0.25
635.1167603	0.05
635.9752197	0.20
637.5095825	0.08
638.2969971	0.51
639.2451782	0.72
640.3567505	0.20
644.9617920	0.06
673.4873047	0.10
749.3847046	0.07
887.1434937	0.03
925.0397949	0.05
941.4409790	0.06
973.4234009	0.06
1087.3489990	0.04
1088.0944820	0.05
1105.4721680	0.78
1106.2559810	0.04
1251.5463870	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	322.0933
Annotation	Indole-3-carboxylic acid beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
102.0064697	0.26
110.0464249	0.03
128.0594788	9.52
133.9707642	0.49
136.1856384	0.01
146.0546265	9.05
147.9449158	0.04
149.0536804	1.07
150.9794006	0.02
154.3477325	0.03
159.9680176	0.30
161.0836334	0.09
172.0728149	0.42
175.0559845	11.31
177.0530243	0.52
178.4431152	0.03
186.1625061	0.10
193.0504456	27.69
201.2419128	0.04
204.1353455	0.03
216.0327148	0.36
218.1077576	0.04
228.3023682	0.03
232.0690918	1.85
232.9453125	0.04
234.0151062	0.61
242.1918030	0.27
246.1615295	0.44
250.3004150	0.07
260.1551514	3.64
262.7352905	0.01
276.0079346	0.03
278.1713562	11.49
281.0544434	0.04
285.2911987	0.02
286.5610962	0.03
287.9563904	0.08
294.4526672	0.04
302.2593994	0.03
304.1023560	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.0932
Annotation	N-Acetyl-DL-tryptophan
Peak:m/z	Relative Intensity
71.92086792	0.20
73.94075775	1.37
86.67381287	0.02
97.98027039	0.18
115.9250183	3.69
130.2657928	0.15
142.089035	0.04
158.0901031	0.02
159.3388214	0.05
167.4047699	0.01
171.2942657	0.01
173.2994232	0.04
180.8611908	0.06
183.0622101	0.10
185.1674957	0.17
186.0668335	0.52
187.040741	0.09
199.0877228	0.03
201.0920258	3.21
203.0825348	100.00
227.2377319	0.47
245.3300934	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3068
Annotation	BQ 123
Peak:m/z	Relative Intensity
203.2719269	0.28
209.7632904	0.26
220.9448242	0.18
259.0607910	0.75
269.4904175	2.78
272.1656494	0.15
273.1834106	0.22
289.1153564	1.94
290.3150940	0.20
297.0273438	0.19
301.3060913	0.70
313.4212646	0.12
314.2215881	0.13
315.2366333	1.12
317.3007812	0.15
320.3915405	0.15
327.2620239	0.26
331.5198364	0.20
343.2446899	0.15
347.4596558	0.12
348.9265137	0.17
365.4980469	0.14
368.4205322	0.17
369.1751099	0.08
386.4680786	0.07
387.4505005	0.53
389.3159180	0.27
391.2077637	0.14
394.4365845	0.06
403.4675903	0.14
433.4416504	0.14
485.2720337	0.17
493.1358643	1.06
503.3394165	0.22
511.3885498	0.30
512.3612671	0.31
516.1018677	0.17
538.1831665	0.18
541.5828247	0.08
545.3328857	0.31
547.0396118	0.25
559.4068604	0.13
566.3347778	0.22
595.3599243	0.67
596.7667847	0.58
603.4058228	0.08
608.1385498	0.04
609.0361328	0.43
611.2785034	1.07
622.6176147	0.17
632.3417969	100.00
633.3385620	0.04
635.6600952	0.11
637.3604736	1.84
638.5630493	0.45
752.8886108	0.28
765.7124023	0.37
923.3916016	0.18
1024.8420410	0.10
1103.3989260	0.63
1221.6179200	0.38
1265.5622560	0.57
1266.6937260	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	784.3029
Annotation	Unknow
Peak:m/z	Relative Intensity
208.8827362	0.13
223.1501617	0.11
241.1705017	0.05
244.2655640	0.34
271.0613708	3.98
280.1365967	0.79
288.4757690	0.28
289.1067505	4.01
300.7822876	0.05
306.7224731	2.86
307.3330688	0.30
312.9765015	0.25
322.6136780	0.11
324.8504639	80.27
325.5929871	0.17
333.8318481	0.26
342.7963867	21.63
343.7619629	0.47
356.3000793	0.27
367.2540283	0.26
384.6756592	0.44
400.0684814	0.51
402.8740234	0.05
414.6164551	0.05
437.9155884	0.09
438.8402710	0.29
441.5551147	0.21
443.8168945	0.08
450.2067261	1.38
450.9352417	0.48
460.0808105	0.32
462.9783936	1.02
468.7448120	0.63
471.9596558	0.13
479.9669800	0.07
481.9921265	0.58
484.7638550	0.12
486.7934570	100.00
487.6745605	0.47
493.8981323	0.08
501.7359009	0.07
504.2008057	4.61
504.8268433	34.60
505.5778809	0.13
509.9396973	0.18
525.8919067	0.72
527.8209229	0.27
547.7278442	0.37
567.0507812	0.24
589.4148560	0.32
591.2603149	0.17
591.8856812	2.02
594.3668823	0.62
604.3228760	0.12
608.7514648	0.24
610.8724365	0.16
612.4110718	0.56
622.0517578	25.47
622.7584229	0.09
638.7864380	0.14
654.7793579	1.32
655.4806519	0.25
666.8706055	0.05
675.7996216	0.18
685.8297729	0.08
694.1895142	0.42
710.0226440	0.25
719.9852905	0.09
738.6906128	0.19
765.9209595	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2238
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0864258	0.11
163.2143097	0.66
164.1110382	0.53
165.2005615	0.42
174.9628601	4.03
187.0374908	0.09
191.1378326	0.32
192.9888000	100.00
194.2150726	0.57
209.0897217	0.07
211.2237854	0.29
217.0337524	0.12
221.0082092	0.35
229.1649475	0.10
232.2607422	0.29
235.0976868	22.78
260.9286194	0.11
271.3875122	2.01
273.1868286	5.61
276.9741516	0.12
305.8429260	0.38
312.1743774	0.42
313.0570679	0.97
320.1723022	0.95
333.3135376	0.23
335.0927124	0.11
337.1000366	79.13
337.7115479	0.21
355.1741943	18.65
375.0087280	0.14
383.3281860	0.47
389.3681030	0.25
391.2056274	0.08
397.3359375	0.20
401.0718994	1.06
407.1217041	0.11
409.1422729	2.52
419.2216187	6.53
438.3441772	0.25
443.1387329	0.85
445.0737915	0.25
469.2363281	0.67
481.2132568	0.31
483.4909058	0.12
485.4137573	0.29
489.5426025	0.33
498.6026001	0.12
501.2371216	6.64
509.0559692	0.08
524.9720459	0.12
527.1713257	4.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1293.61
Annotation	Unknow
Peak:m/z	Relative Intensity
367.3724365	0.27
383.1226196	0.40
439.5496216	0.27
457.4750366	0.34
461.6535034	0.35
481.3215027	0.84
499.3572998	0.21
551.7009888	0.74
553.6499023	0.67
567.5296631	0.20
589.6498413	0.14
622.9722900	0.12
630.9762573	0.17
637.4188232	0.47
657.5446777	0.22
685.8145752	0.17
699.0261230	0.22
723.5258789	0.13
727.4918213	0.24
733.2836914	2.36
733.9262695	1.69
735.2681274	0.32
747.4938354	0.24
749.3154297	0.32
751.5724487	4.28
753.4427490	0.23
775.4417114	0.50
793.5756226	3.13
799.5422363	0.25
801.4056396	1.30
818.9410400	2.76
819.5615234	9.40
847.2786865	0.82
849.5647583	0.20
861.3825684	1.44
865.4084473	7.43
883.5765381	1.59
891.2860107	10.76
909.4791260	10.37
927.5700684	1.77
933.2442627	12.81
934.0106201	0.14
951.3769531	8.08
961.5833740	0.31
969.4169922	1.62
972.7673340	0.12
983.3420410	0.13
1007.6425780	0.10
1009.3494870	2.15
1027.3621830	29.90
1028.0124510	0.24
1033.6843260	0.14
1035.0063480	0.51
1045.5849610	2.26
1053.6766360	0.70
1071.3416750	0.73
1089.5234380	1.06
1113.4746090	1.15
1117.4654540	1.37
1131.3925780	7.97
1132.5833740	0.36
1161.3999020	0.21
1171.4868160	4.94
1189.4455570	100.00
1190.0837400	0.27
1207.4575200	2.14
1215.3062740	1.56
1230.2180180	0.21
1231.5877690	0.34
1233.4211430	35.37
1234.4296880	0.10
1235.3867190	0.36
1251.4383540	55.17
1252.3723140	1.14
1257.4377440	0.21
1275.4309080	24.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0855
Annotation	Gerfelin
Peak:m/z	Relative Intensity
96.7046356	0.16
105.0633163	0.16
110.9394455	0.14
119.2416687	0.18
122.9198456	100.00
124.8993073	0.15
127.0681915	0.38
130.0036011	0.08
137.0685120	0.74
138.9334717	97.29
145.1457214	0.15
147.0073547	6.35
150.9653625	28.24
152.9774475	0.58
163.0253296	0.39
164.9699402	50.42
169.0418396	1.99
181.1004944	0.39
185.0717010	0.05
188.9853668	0.03
192.2769775	0.06
203.2531433	0.09
205.0229797	0.36
209.7543335	0.23
231.2791138	0.15
233.0772095	0.19
245.3750610	0.08
246.2136841	0.08
247.1796265	0.16
249.0915527	1.26
255.0630493	0.23
272.9752808	22.51
273.6199341	0.14
282.4666138	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1027.51
Annotation	Pisumsaponin I
Peak:m/z	Relative Intensity
377.1326294	0.05
467.5083008	0.09
567.5459595	0.17
639.3994751	0.31
657.5259399	0.35
701.4696045	0.05
775.2685547	0.04
819.5541992	0.13
837.7309570	0.08
881.4138184	0.12
921.4610596	0.45
941.6029053	0.93
955.2686768	0.04
965.3330078	1.28
967.2303467	0.07
983.4387207	100.00
984.1716309	0.16
1005.4405520	0.21
1007.3132320	0.04
1009.4855960	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.2079
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9011383	0.10
243.1835632	0.44
245.1610413	0.74
250.0586548	0.05
250.9262695	0.09
253.2218323	0.25
255.2210999	0.17
259.1507568	0.07
268.1616821	0.11
269.0263672	0.31
271.0372314	14.71
273.1692810	1.90
276.1745605	0.14
281.0775757	0.19
283.1575928	0.68
284.1136475	0.10
285.1263123	0.43
286.9540100	0.28
287.5794067	0.09
289.1810608	32.60
293.0092163	0.41
296.1463013	0.09
300.0603638	0.17
301.2508240	0.97
302.8126221	0.14
305.1402588	0.04
310.1771851	0.46
311.1240234	1.72
311.9469910	0.14
313.1029968	0.76
321.2222900	0.19
323.1308594	0.11
327.2287598	0.54
328.1596069	0.95
329.1293640	2.80
331.1531677	0.29
339.2597961	0.09
341.2075806	0.40
345.3076782	0.15
350.2709656	0.07
355.3293457	0.42
356.2016602	0.20
357.2753601	0.33
363.1580811	0.61
364.3522034	0.05
367.2694702	0.77
369.9519653	0.12
374.2263184	0.18
375.2386475	1.11
379.2478638	1.45
381.2250977	1.08
383.2124634	1.44
389.0694580	0.72
391.2072754	0.38
393.0809326	1.12
397.2376099	4.11
399.6559448	0.12
401.0634766	0.08
407.1695557	11.36
409.2354736	0.24
410.1316528	0.09
413.1376953	0.14
415.3057861	0.11
417.1972656	9.78
418.0697021	0.15
419.1134644	1.15
421.2220459	0.14
425.1726685	7.94
431.0435181	0.21
433.0870972	0.47
435.1561279	13.46
436.2231445	2.22
437.0985718	0.32
438.9539185	0.05
439.6126709	0.12
446.1609497	0.16
449.2393188	0.07
457.1097412	0.11
459.3201294	0.93
461.2796021	0.32
475.2653809	0.58
477.1827393	1.42
481.3258667	0.40
483.0873413	0.07
495.3415527	0.34
499.3139648	0.94
501.1363525	1.41
503.2432251	0.40
507.2684326	0.12
509.4366455	0.50
516.9809570	0.08
519.2203369	4.48
525.2637329	3.01
527.2723999	1.47
541.5971069	0.10
543.1148071	100.00
543.7741089	0.48
545.1943970	0.28
546.7838135	0.27
549.2772217	0.09
553.2536621	3.20
555.1687012	1.89
557.4187622	0.15
559.1202393	1.02
561.1073608	59.38
561.7828979	0.46
571.1475830	3.88
573.5180054	0.11
577.2383423	0.13
577.8731079	0.07
581.9791870	0.24
597.2206421	0.42
600.0558472	0.62
603.7300415	0.06
617.2503662	0.36
621.9724121	0.03
635.2742920	0.70
643.1680298	0.19
645.6412354	0.16
653.2080688	2.08
655.2518921	0.13
661.2587891	0.52
663.2505493	0.80
670.2836304	0.10
671.2969360	0.14
679.1442871	8.20
681.0903320	4.51
689.2092896	3.59
696.1187134	0.50
697.1942749	4.71
707.0851440	56.58
707.6883545	0.49
709.4598999	0.14
721.6383667	0.05
728.3536377	0.06
735.4075317	0.34
739.4628906	0.07
747.4610596	0.07
753.4586182	0.14
756.1896362	0.24
770.3272095	0.07
771.4226074	0.27
788.2964478	1.55
789.3786621	1.27
796.6864014	0.04
797.3224487	0.50
800.3943481	0.25
815.0546265	11.14
815.8859863	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.338
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
165.8865967	0.55
183.9837189	100.00
240.2230835	0.13
258.2716675	0.22
337.3209839	0.11
489.3709106	0.20
502.3958130	55.24
503.0115967	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.1905
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0346069	0.10
250.5692902	0.06
258.9590759	1.02
281.2102051	0.03
292.7052917	0.04
305.3406677	0.05
322.8555298	0.17
337.1132812	0.06
341.0247192	4.51
383.1736450	6.49
412.6654663	1.26
413.4411011	0.02
425.4086304	0.12
442.3329468	0.70
442.9923706	4.07
466.9404297	0.19
473.3200684	0.28
485.2681274	4.34
502.9518433	2.95
522.9537964	0.13
545.2080078	0.33
565.0518188	0.03
583.2262573	1.78
601.1837769	11.52
665.2393188	100.00
666.0938110	0.32
667.4727173	0.17
745.2684937	14.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0718
Annotation	Gerfelin
Peak:m/z	Relative Intensity
85.0765305	0.02
92.4101486	0.04
97.0464020	0.13
98.9342728	0.04
108.0593872	0.07
108.9441757	0.86
116.8769379	0.03
121.0579071	0.21
123.0553741	0.62
124.9992981	2.02
135.0954285	0.31
136.9869690	2.64
139.1283875	0.34
143.0339050	0.01
146.9814453	0.13
149.0892639	0.06
151.0731812	1.13
153.2693481	0.04
158.9276733	0.77
160.9554291	1.85
161.9217834	0.13
163.0756989	0.30
164.0522766	0.45
164.9945526	2.34
165.7384186	0.03
166.9637146	0.93
173.6813202	0.03
175.0818787	0.57
177.1804810	0.03
178.9725952	10.44
180.0517120	0.08
182.9945068	0.06
184.9284821	0.25
186.0864105	0.44
187.0251465	1.08
187.9944458	0.94
191.2161102	0.05
199.0587158	0.07
201.1000977	0.31
203.1134338	5.99
205.1046448	30.48
206.0002747	0.24
210.8440247	0.03
212.0415039	0.10
217.1001892	1.56
221.1169739	0.22
227.1037598	1.19
228.8905640	0.24
230.9877319	6.28
232.1204529	0.06
243.2424316	0.05
245.1156006	100.00
246.4731445	0.30
247.1871643	5.16
248.0566406	0.05
253.2438354	0.07
258.9672546	0.06
259.9279175	0.02
261.1152649	0.05
271.1601868	4.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	796.4951
Annotation	Unknow
Peak:m/z	Relative Intensity
222.1214142	0.09
222.9508514	0.11
226.9790344	1.22
229.0920563	0.27
231.2426910	2.74
236.0298462	0.27
241.2287750	1.36
245.2122192	0.17
249.1534424	7.16
251.2140808	0.88
253.1041718	0.20
255.2659912	1.38
257.7271423	0.66
259.4826660	0.07
261.1452026	1.20
267.1466064	1.84
271.1698608	0.66
273.3983154	0.54
274.3023071	2.24
275.4293213	0.34
278.0180664	2.58
279.1259155	0.38
281.1442566	0.36
282.2669067	5.59
285.2455444	0.21
287.1394958	3.29
289.2794800	1.57
291.2173462	0.83
292.3768921	0.80
293.4347229	0.08
296.0809021	1.97
305.1749573	2.85
306.2551270	1.18
307.2990112	1.38
309.2094727	0.64
311.4400635	0.30
313.3158569	32.08
314.0725098	0.46
319.3810730	0.28
321.1331787	0.15
323.2036133	13.78
324.1901245	0.42
325.1495361	0.46
327.2669678	1.74
329.6983032	0.50
332.5059814	0.59
334.1939697	12.45
335.2766113	1.13
338.2598267	0.16
341.1318970	0.73
345.2005005	0.97
347.4869995	0.53
352.2376099	19.44
353.4294128	0.51
358.2035522	1.32
359.3829346	0.09
360.8208923	0.97
363.3645020	1.51
364.7603760	0.18
365.4055481	1.63
368.3369751	0.13
369.2086792	0.78
372.0488281	1.07
376.5302734	0.34
381.1288452	2.65
386.3775635	0.27
387.4004517	0.77
388.6333618	0.16
390.3294067	1.57
397.2998657	0.17
397.9821777	0.15
399.0861206	1.15
399.6931152	0.12
403.2407227	0.28
405.3779907	0.26
408.9795532	0.25
410.4339600	0.34
414.5322266	0.08
415.4692993	0.33
422.5039673	0.24
423.2089233	0.75
428.3026123	2.74
432.3569336	0.29
436.0735474	0.33
437.6242676	0.24
438.2395630	0.43
439.2282715	0.65
441.3190918	0.33
446.3113403	0.54
451.4540405	0.11
453.5125732	0.11
454.3185425	0.46
455.2915649	2.19
456.3421631	0.22
461.2740479	0.50
464.4907227	0.41
467.3737793	70.97
468.3807373	0.65
469.3514404	1.11
470.4287109	0.35
474.6859741	0.68
477.4094238	0.95
479.3188477	0.64
481.4838867	4.49
482.2628174	0.12
483.5537720	1.04
485.6176147	0.33
487.3814087	0.18
491.3140869	0.47
493.4518433	4.07
495.3928223	0.65
496.3135986	0.29
497.3576050	2.91
498.4018555	0.79
501.3801880	0.60
505.4417114	20.23
506.2368164	0.08
506.8761597	0.50
507.5095215	6.12
508.5271606	0.20
510.9901123	0.32
511.6284180	0.24
517.3927002	2.64
521.6779175	1.51
522.5031128	1.69
523.4042969	3.69
524.0408325	0.53
527.5617676	0.17
528.3671875	0.27
531.4607544	0.64
535.6986084	0.93
537.5880127	0.68
538.3670654	0.10
540.3471069	0.62
543.5231934	7.30
545.6264648	2.43
546.5639648	0.29
547.2183228	0.25
547.8259277	0.08
548.8839111	1.48
552.4552002	0.82
553.3107300	3.37
555.7252808	0.11
559.5700684	0.16
561.3823853	36.96
561.9846802	0.53
563.9989624	0.74
564.7470093	0.28
565.4370117	2.51
568.2363892	0.13
572.7792358	0.20
573.6477661	1.71
575.5012817	0.21
576.5041504	0.54
579.3534546	30.88
580.5404663	1.56
583.3193970	0.66
585.3978882	7.49
586.0942993	0.09
587.7545776	0.42
588.3776855	0.26
590.4442139	77.46
591.4952393	0.72
594.1502075	0.50
595.1304321	0.30
597.3374634	3.62
598.6585693	0.85
600.6557007	0.06
601.4401855	5.81
602.4642944	0.47
603.4413452	17.56
604.4060669	1.80
605.4760132	0.12
606.7909546	0.27
608.0957642	3.45
609.7760010	0.63
610.5601807	0.50
616.6034546	0.89
619.4912720	7.60
621.4447021	25.57
622.8846436	0.74
623.6722412	0.63
624.8129272	0.59
627.0574341	0.11
628.3796387	7.71
629.2086792	0.12
630.4656372	43.90
634.4424438	0.74
636.5327759	0.13
637.5004883	11.50
640.2518921	0.45
646.4797974	2.74
648.3906860	11.34
652.4598389	0.20
655.4087524	100.00
656.3273315	0.30
661.2422485	0.14
662.3186035	0.67
664.1499023	0.67
666.5774536	3.50
670.5608521	0.45
672.4577026	0.32
674.0345459	0.90
679.3665161	0.18
680.4364624	1.34
683.2825317	0.99
684.4069824	9.62
685.0200806	0.53
685.9904175	2.18
686.6970215	0.23
688.4099731	3.09
690.7130127	0.42
695.2846069	0.32
696.5136719	0.09
699.0125732	0.13
699.6204224	0.45
701.3637085	0.13
704.7118530	0.05
706.7746582	1.01
708.3685913	11.76
714.4849243	1.65
716.0014038	0.18
719.4007568	0.16
720.1441650	4.74
720.7651978	0.26
721.5122681	0.43
722.7119141	0.38
724.4471436	2.60
726.2879028	52.05
727.3429565	0.63
731.7138062	0.22
732.4514160	0.46
735.3113403	5.84
742.5595093	5.54
744.3535767	72.44
745.0718384	1.51
745.9584961	0.44
747.7012329	0.11
750.8140259	0.31
752.5673218	0.31
760.3446655	6.08
762.2649536	78.30
763.0119019	0.46
771.0795288	0.42
778.2997437	31.68
779.1454468	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1475
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.0064087	0.92
165.1232452	0.75
167.0885925	0.08
168.8817902	0.17
173.0441895	0.04
181.1254120	0.26
182.9513245	0.06
187.0174255	0.05
189.0146790	0.30
190.0899353	0.11
190.9013977	0.08
192.9025269	0.03
197.1627960	0.12
201.0118408	0.55
205.0602722	0.43
211.2150574	0.17
215.0811005	0.34
216.9113464	0.05
219.2377472	0.07
225.1467285	0.19
227.0891418	0.05
229.0590515	1.59
231.4497833	0.06
233.0058136	0.15
240.9799805	0.27
243.2113037	0.34
247.0547638	21.09
247.8604431	0.07
249.0052185	0.15
253.0433807	0.77
257.1049805	0.43
259.1432495	6.17
260.0579834	0.03
261.1688232	0.34
267.3063965	0.08
269.1328430	0.30
271.0439453	8.40
273.1565552	3.73
275.0700073	7.06
283.0300293	1.95
284.8955688	0.76
287.1098022	2.23
289.0556030	17.75
291.1432495	38.82
293.2227173	0.10
294.1790771	0.04
295.2499390	0.25
296.9761963	0.10
299.1454468	1.66
301.0396118	21.52
303.0694580	11.48
311.0648193	0.20
313.0673218	2.70
315.0529785	1.72
317.1050415	0.05
325.2222900	0.85
329.3258667	0.10
331.0003052	0.27
333.0245361	4.06
358.0088501	0.18
390.6283569	0.07
393.1969604	0.48
396.9866333	0.31
397.9934082	0.17
399.1108398	0.22
402.0993042	0.22
405.0927734	0.57
407.1541748	0.25
407.7990112	0.08
409.1091919	55.31
411.1784668	8.91
414.8361206	0.09
416.2282715	0.09
417.1448364	0.66
419.2509155	0.44
421.1530762	3.92
423.0600586	0.96
425.3114014	0.57
427.0933228	100.00
433.1949463	0.45
435.1094360	5.63
439.0037842	6.02
439.6180420	0.37
441.1343384	0.35
448.2424927	0.10
449.0864868	0.32
451.0048218	0.52
453.1509399	28.79
489.3012695	0.09
498.1068726	0.26
515.1284790	0.18
527.2416992	0.16
543.0274048	2.55
561.1414795	10.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3072
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
154.9795227	0.21
177.0684509	0.20
179.7240601	0.03
198.2365570	0.30
216.0060425	0.40
247.3961182	0.04
265.1852417	0.94
308.2664185	1.30
321.1448975	0.22
339.3703003	69.30
349.0307617	0.07
382.4400330	0.12
401.2335205	0.05
419.1645508	5.96
433.4944763	0.05
436.7966614	0.26
445.0420837	0.27
462.1854553	100.00
462.8215637	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.1451
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
160.9642487	0.39
163.0807495	0.40
163.9253845	4.32
164.9931641	1.26
166.0537567	0.32
167.1979523	0.18
169.2644196	0.16
171.2386475	0.05
173.0196533	0.10
175.9653320	0.05
177.2047424	0.30
179.1647339	0.04
180.2091522	0.04
183.9741211	0.11
185.1696472	0.48
186.1761780	0.35
187.0127258	1.26
187.9895172	0.05
188.9592590	1.32
199.0472870	0.08
203.1386871	0.06
205.0254822	0.54
214.2414856	0.03
215.0998230	0.16
220.9375305	0.14
227.0748901	0.52
228.0783081	0.92
229.0801086	2.52
231.2044830	0.59
243.1906128	0.25
245.0783844	0.07
253.1335144	0.30
255.1486664	0.67
258.3393250	0.06
263.5020752	0.10
269.1604614	0.87
271.1575317	31.69
271.8863525	0.19
273.0992432	63.12
281.1094360	0.73
283.2189331	0.89
285.3468628	0.13
286.1728516	0.11
295.3112183	0.10
312.0385742	6.55
313.0747681	7.15
315.2263184	0.26
320.2518921	0.47
323.1836548	0.44
325.2323608	0.74
333.2734985	0.10
337.3502197	0.22
351.0745239	0.20
357.6487427	0.09
365.2807617	2.43
367.1115723	0.68
375.3518066	0.29
377.2754517	0.39
391.2600098	6.36
393.6354980	0.13
394.3775635	0.29
395.1160889	0.33
397.0174561	0.09
401.2893677	0.38
409.2306519	31.00
411.4518433	0.23
415.0867310	0.03
417.2129517	0.99
419.1522827	100.00
419.7966309	0.37
420.4395752	0.05
421.0916138	0.12
430.1120605	0.26
431.2191162	0.27
433.3217773	0.37
439.3317261	0.09
440.7645264	0.14
443.2533569	0.09
451.3265381	0.66
456.2593384	0.09
459.2097168	0.27
461.0153198	0.16
471.3806152	0.27
480.8522949	0.05
483.3356323	0.30
487.1640015	0.20
500.6838379	0.42
501.2938232	2.89
503.4624023	0.07
509.2229614	1.64
514.2850342	0.37
527.2117310	22.51
528.1187744	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.3043
Annotation	Unknow
Peak:m/z	Relative Intensity
262.9520569	0.18
269.0296021	0.02
286.2004395	0.03
289.0745239	0.03
320.1136475	0.05
336.3480835	0.05
416.7567749	0.08
452.4473267	0.11
489.6178589	0.02
499.2724609	0.02
503.6672363	0.07
551.3419189	0.32
552.0990601	0.05
601.9445190	0.23
609.4130249	100.00
610.5371704	0.48
611.4043579	0.65
612.2020874	0.10
613.0359497	0.07
614.5786743	0.05
615.3876343	0.02
617.6386108	0.07
621.9518433	0.02
625.5140991	0.08
747.1074219	0.06
765.4784546	0.07
849.4541626	0.03
863.2849731	0.17
875.5535278	0.05
905.5515747	0.22
906.6325073	0.04
924.4473267	0.10
925.5054321	0.04
957.5795898	0.16
958.5752563	0.32
1039.6016850	0.15
1041.4820560	0.18
1057.5356450	1.09
1058.7149660	0.08
1085.2711180	0.14
1086.3304440	0.10
1103.3859860	1.83
1104.4318850	0.95
1105.8050540	0.20
1219.3461910	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.2
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
241.1647186	0.13
243.0479736	0.87
245.0947876	3.94
253.2240448	0.35
255.1101074	0.48
256.0202026	0.41
257.1398621	0.74
261.0099487	0.89
263.1924133	0.38
265.8933411	0.26
269.0554199	1.14
271.0531616	6.52
273.0783691	1.11
275.0873413	0.29
278.2769775	0.13
281.1900330	0.28
282.2370911	1.04
283.1617737	1.09
284.1325684	0.14
285.1399841	2.69
287.0681152	7.38
289.1375122	17.19
298.1513672	0.24
299.0357666	0.25
300.0107422	0.87
300.7372742	0.13
303.3267517	0.39
307.3162231	0.13
308.3813171	0.11
310.2582703	0.09
311.3534546	1.16
312.1276855	0.24
313.0632629	1.34
318.9172974	0.09
321.1938477	0.38
323.4218750	0.12
325.2350464	0.12
326.0078735	0.47
327.1722107	0.96
328.3072510	0.86
328.9695435	0.79
331.1539001	0.52
331.9112244	0.09
339.1763916	1.01
341.1890259	0.92
343.2439575	0.13
345.3253174	0.55
347.1572266	0.96
349.5491333	0.07
350.9910583	0.21
353.2817383	0.27
363.1990967	3.10
365.1264648	1.60
366.9196777	0.89
369.1987915	0.35
371.0724487	0.40
373.3400574	0.15
381.1491089	0.71
383.2402954	0.18
389.1187744	6.07
391.1485596	2.60
393.1655884	0.51
395.1726685	4.66
397.0006714	0.08
405.2390747	0.64
407.1072998	33.27
408.1507568	0.62
409.2681885	1.27
409.8918457	0.19
413.0101318	7.54
413.6331177	0.20
415.3061523	0.27
417.2184448	1.39
418.0859375	0.76
419.0852661	0.28
421.3007812	0.14
423.0018921	0.48
425.1007080	5.69
431.1960449	0.78
433.2101440	29.19
435.1550293	16.86
436.2608643	3.46
437.0789185	0.39
439.4450073	0.08
443.3913574	0.15
446.9650879	0.42
449.0247803	1.76
449.6417847	0.38
451.3076782	1.26
452.1712646	1.23
453.4593506	0.11
459.4589844	1.40
463.1114502	0.28
464.1592407	0.34
465.2035522	1.00
467.3027344	0.32
473.1315918	0.25
475.2720947	0.55
477.1856079	2.87
479.1910400	0.23
497.3470459	0.43
499.1679688	0.94
503.1899414	1.13
509.1705322	0.15
511.4663086	0.88
515.2471924	0.86
517.1755371	4.32
519.3576660	3.05
523.0535889	0.50
525.3114014	1.84
527.1658325	0.73
528.9271240	0.58
537.0792847	0.32
541.1564941	5.39
543.1757812	18.51
545.3687744	0.81
546.9713135	0.10
553.1633301	1.31
559.1700439	100.00
561.1000977	61.89
561.7584229	0.15
565.2218628	0.28
569.1786499	2.42
571.0657349	3.59
573.5382690	0.52
575.3506470	0.63
577.2053223	1.69
583.2491455	0.46
585.2307739	2.24
587.2183838	4.80
601.1134033	0.52
603.1871948	4.45
610.3325195	0.49
613.2860718	0.80
626.2966919	0.17
627.1373901	0.61
629.1196899	0.77
635.0844116	0.16
643.0544434	0.31
651.2784424	1.22
653.1351318	2.66
661.2637329	2.90
665.4066772	0.19
667.3178711	0.14
669.0322876	0.21
677.4352417	1.36
679.1189575	66.41
681.2763062	0.37
694.6166382	0.72
695.2628784	2.26
697.1226807	17.43
703.0415649	0.14
705.2778931	4.38
709.3644409	0.58
711.1364136	0.27
712.8869629	2.74
713.5000610	0.51
715.4201050	0.30
718.4951782	0.18
721.4194336	0.92
723.1027222	91.79
723.7777710	0.50
726.2993164	0.23
727.3705444	0.25
729.1636353	0.26
739.2327881	0.73
745.2932129	0.43
769.3338623	0.11
787.1360474	2.11
795.2506104	0.26
805.1195679	2.15
813.1707153	2.70
831.0531006	29.95
831.6768188	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0328979	0.06
153.0712433	0.10
157.2552643	0.02
191.1972046	0.10
196.1336670	0.14
214.1058655	1.69
229.3274231	0.01
233.2348328	0.50
259.0813599	0.17
275.3871460	0.45
277.2403870	100.00
277.8644409	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.1258
Annotation	Unknow
Peak:m/z	Relative Intensity
83.9159546	1.01
84.8521271	0.07
86.1037293	1.82
93.7801056	0.04
101.9886322	0.03
111.9713440	0.02
129.9402161	26.94
130.9704285	1.47
132.0201416	0.09
144.6028595	25.51
145.4911041	0.18
146.2529602	0.02
164.6248627	0.09
167.7570496	0.02
168.7283783	0.04
175.1428833	5.20
176.1716614	0.32
177.6396179	31.24
178.6688995	0.35
179.8352509	0.03
181.9630737	0.01
185.9588013	0.95
191.1978607	0.01
192.2337799	0.05
200.6401825	100.00
201.7271576	0.88
202.5471649	0.09
203.5828400	0.12
204.8757019	0.08
225.2194824	0.25
226.5278931	0.04
243.1657715	1.26
244.1905060	0.21
245.2937622	0.01
269.1184082	0.10
288.1772156	34.22
289.2353821	5.18
290.2855530	0.18
303.9731445	0.08
354.4281616	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	624.2889
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1810608	1.73
262.7440796	2.78
263.9498291	0.24
319.9760132	0.37
379.4182739	1.38
399.4019165	1.19
408.2127686	0.13
444.2954102	4.88
453.2338867	0.24
496.1815796	0.28
513.0892944	1.35
530.1184692	0.70
534.3306274	1.14
535.0260620	0.36
543.5136719	18.47
544.3778687	2.72
579.3556519	0.21
580.1674805	1.79
593.5101929	2.43
615.3089600	3.12
637.3657837	0.75
649.2855225	0.65
683.5769043	0.43
703.5612793	0.60
704.5308838	0.17
709.7962036	0.29
726.7316284	0.30
728.1541138	1.16
746.5413818	0.30
747.3704834	0.24
749.4929199	0.21
759.6367798	0.33
760.4638062	0.17
799.3102417	0.35
817.5789795	4.40
818.7438354	0.75
846.2174683	0.44
889.2856445	11.21
890.4282837	6.29
907.4631348	3.15
908.5321655	0.48
925.5781250	2.35
937.6833496	0.33
955.4019165	4.17
956.6089478	2.06
1025.4865720	1.50
1043.3425290	0.59
1052.4862060	0.25
1069.4813230	14.64
1070.4995120	3.42
1087.4306640	100.00
1088.5483400	44.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.3129
Annotation	Unknow
Peak:m/z	Relative Intensity
216.2979584	0.05
217.0470886	0.05
243.2533722	0.04
268.9445190	0.11
270.9222107	0.07
271.8959351	0.05
287.2490540	0.09
289.1932678	0.06
312.0953369	0.10
339.3761292	0.07
347.5121155	0.10
349.2662964	0.15
351.1912842	0.04
381.2924194	0.06
391.2830200	0.14
399.1188965	0.07
405.4382935	0.07
407.3308716	0.22
409.9114380	0.11
429.4203491	0.15
431.2753906	0.20
449.2347412	0.31
451.1452026	0.06
455.1475220	0.14
468.5526733	0.29
477.2709351	0.27
482.5404053	0.12
502.1428223	0.04
511.4660645	0.31
539.3777466	0.05
545.1475220	0.23
554.0076294	0.05
557.2382202	0.30
558.4763184	0.46
559.3597412	0.28
567.3070679	0.09
570.0498657	0.33
570.7468262	0.15
572.9928589	0.21
575.3159790	0.07
577.3790894	0.04
581.4036255	0.30
583.3621216	0.15
591.0879517	0.06
591.9610596	0.42
593.2429810	0.20
596.2684937	0.06
598.0711060	0.04
599.1972046	1.35
605.6290894	0.10
615.2208252	0.09
620.5769043	0.31
623.2914429	0.14
630.4739380	0.04
634.3298950	0.55
642.6012573	0.06
643.2274780	0.45
650.2308350	0.07
650.8309937	0.15
659.8219604	0.06
666.8628540	0.05
671.4159546	0.83
673.2034302	100.00
673.9109497	0.53
675.4240112	0.07
683.4064331	0.20
697.3180542	0.15
700.2968140	0.06
701.1181641	0.62
709.3844604	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.128
Annotation	L-gamma-Glutamyl-beta-phenyl-beta-L-alanine
Peak:m/z	Relative Intensity
90.8870239	0.04
101.2338867	0.02
102.9007797	0.37
118.1575394	0.01
120.0679398	18.87
120.8644714	0.04
129.9435120	0.07
131.0369263	0.21
147.9550781	0.11
149.0370483	1.03
165.9834290	100.00
186.1906128	0.05
189.0778961	0.06
232.1777954	0.91
249.0743408	0.18
250.3323059	0.04
259.2327271	0.31
277.0921021	1.68
278.1630859	7.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	789.2957
Annotation	Unknow
Peak:m/z	Relative Intensity
220.8514404	0.39
233.0825043	0.28
235.1617432	1.51
247.1356812	0.46
249.0973663	0.25
250.0747986	0.05
250.9728088	0.95
257.3136597	0.46
265.0375977	2.56
266.8493042	0.06
277.2654419	0.26
279.8671875	0.06
281.0944214	2.44
284.1536865	0.20
288.9088745	0.67
295.1780090	2.53
307.1959534	0.07
312.3283691	0.08
323.2324219	0.31
327.3701782	0.29
335.3074951	0.42
337.3419189	0.23
338.8580322	0.12
341.1526489	5.90
355.1248779	4.81
357.3610229	0.16
359.3252563	0.17
368.6123047	0.21
369.2880859	1.47
371.1486816	0.83
383.0100098	0.15
387.2955322	34.51
398.9912720	0.10
401.2432251	0.31
407.4020996	0.05
413.2022705	0.36
419.1892090	0.91
421.4157104	0.08
429.1560059	0.26
430.8061523	0.21
447.0567627	0.38
451.3496704	0.28
458.7440796	0.80
459.5269165	0.04
461.1420288	0.19
471.4160767	0.06
473.2832031	0.20
473.9332275	0.38
477.3907471	0.28
487.2498779	0.22
489.2787476	3.42
491.0576782	0.08
501.2534180	0.30
503.3316650	3.91
507.0192871	0.03
509.2440796	0.63
519.4382324	0.22
520.8798828	0.13
525.4582520	0.59
529.3102417	0.04
531.3681641	2.76
537.1717529	1.09
545.2177124	2.72
555.3469849	0.03
557.2360229	0.06
563.1983032	100.00
563.8441772	0.35
573.4728394	0.05
577.2949829	12.70
579.3706665	0.10
585.3281250	1.44
589.2367554	0.03
592.0139160	0.07
593.2271118	0.05
596.7849731	0.23
603.4819946	0.15
605.2092285	0.52
611.3101196	0.57
613.3854980	0.08
617.1841431	16.96
627.4904175	0.66
635.3282471	0.25
645.4340210	1.17
651.2538452	0.16
653.2227173	0.42
657.3934326	0.05
661.2069702	0.08
667.3333130	0.92
669.4172974	0.09
683.0081177	0.09
687.2921143	0.07
691.5507202	0.19
697.2854614	0.40
709.2543335	1.02
715.0628052	0.95
721.1162720	0.06
727.5907593	0.13
728.4683228	0.19
729.2351685	0.44
735.4215698	0.33
737.1558228	0.25
739.3140259	1.04
741.2829590	16.99
744.0462036	0.05
745.4063110	0.81
753.3318481	3.08
757.4176636	0.42
758.8012085	0.44
771.1627808	17.39
771.8994751	0.11
775.1663818	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.0879
Annotation	beta-L-Arabinofuranosyl-(1->2)-beta-L-arabinofuranose
Peak:m/z	Relative Intensity
81.4158936	0.89
83.0087967	1.51
84.0155335	0.16
84.9458160	9.82
86.9889069	7.95
88.9927292	0.55
91.1303558	0.13
94.9657059	7.48
96.9186706	0.50
98.9491806	1.34
101.0397339	0.25
102.9210358	11.05
105.0902710	0.22
107.0955811	1.65
108.9346619	1.50
110.2131271	0.52
111.0209961	2.78
112.0926285	3.33
112.9396439	87.68
114.7532654	0.11
121.1880035	0.21
125.0139465	0.37
126.9060211	2.90
127.9617920	1.59
128.9862366	9.00
130.2392273	1.24
130.9325867	5.58
133.8799438	0.15
139.0428772	5.60
143.0077515	1.45
144.0169220	0.40
144.9823914	0.96
150.9285126	0.32
153.3259735	0.10
156.9560394	3.64
160.8858337	2.23
161.6689453	0.20
162.8867950	1.39
169.0926361	1.38
170.1139069	0.17
175.1387329	0.16
179.0077209	0.19
187.0734406	4.62
188.8522949	3.88
195.0372314	0.70
197.1221619	0.61
200.9391174	0.31
205.0846252	64.17
215.0679321	0.08
217.2573853	0.27
231.0869751	4.10
237.2347412	63.85
244.9836731	0.25
249.1080017	100.00
263.1486816	1.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1067.543
Annotation	Soyasaponin bg
Peak:m/z	Relative Intensity
373.3804321	0.68
423.4131470	0.41
425.2759094	0.32
437.4285278	3.07
457.3558960	2.74
465.6333008	0.92
467.2074585	0.76
483.2623901	0.72
535.3785400	0.99
551.3090210	3.28
563.4637451	6.22
571.3537598	0.94
583.4712524	12.78
593.3811035	1.63
619.4288330	0.38
623.6038208	1.71
625.2727661	1.23
651.5223999	11.01
653.4725342	1.37
679.4241943	6.52
688.9664917	0.25
697.5155029	2.40
723.2357178	16.39
733.4454346	35.38
741.4174805	33.94
751.2199097	6.27
759.5134888	1.78
807.5706787	0.45
855.5587158	1.07
858.6938477	1.30
859.4364014	5.32
877.4569092	1.40
879.4855957	46.24
897.3713379	0.62
903.5794678	2.32
909.5579834	0.50
921.5490723	13.71
941.4847412	19.13
942.7840576	0.45
949.3989258	2.14
953.3051758	0.72
963.5251465	0.49
967.5980225	100.00
968.3505859	1.48
1005.2517090	1.14
1005.9266360	0.58
1025.3177490	6.60
1048.8762210	12.50
1049.4971920	58.81
1050.8305660	0.60
1052.8670650	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.3022
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
189.1802673	0.39
191.3150635	0.14
213.0931702	0.15
216.2052917	0.04
221.1775513	0.37
239.3373413	0.09
240.1407776	0.13
243.2320862	0.04
245.1802368	1.22
247.2976685	0.33
255.1188354	0.11
261.2075195	1.41
262.1788025	0.20
263.2130432	1.00
265.2888184	0.08
283.2107544	0.08
287.7255249	0.12
297.1166382	0.11
307.2575073	0.06
313.4610901	0.32
315.3771362	0.04
317.2077637	0.95
319.3903503	0.38
331.3403320	0.04
335.0823975	1.49
337.2870483	100.00
339.5418701	0.13
351.0982666	0.09
351.9548340	0.21
355.1342163	0.12
357.0050659	0.06
375.6245117	0.14
383.2171021	0.13
385.3359375	0.13
393.3037109	0.08
399.1719971	0.26
403.5355225	0.06
407.5688477	0.07
413.3323364	0.40
414.5076294	0.25
415.2056274	0.08
417.6026611	0.07
425.0086670	0.65
425.8085327	1.08
433.3121948	0.43
435.5477295	0.22
437.3189697	0.14
439.6002808	0.40
455.5922852	0.51
456.5473633	0.36
460.9744873	0.29
484.5336304	0.64
491.2182007	0.12
499.4313354	0.14
504.7434692	0.14
505.3984375	0.08
513.2671509	0.16
517.1046753	0.13
522.2382202	0.08
523.5051880	0.44
527.0259399	0.17
537.3267212	0.31
539.4594116	0.26
547.3507690	0.20
548.4570923	0.09
550.6456299	0.08
561.2490234	12.78
569.5825806	0.15
570.3493042	0.25
579.1410522	29.71
579.9412842	0.14
587.8795166	0.13
592.4392090	0.22
596.5056763	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	608.1555
Annotation	Unknow
Peak:m/z	Relative Intensity
171.3362427	0.06
174.0920105	0.14
177.1233368	0.07
179.1775513	0.27
181.2109222	0.21
183.1408691	0.53
190.9026642	0.05
192.9862213	0.41
196.2216949	0.18
201.1198120	0.06
202.9167175	0.10
203.9301758	0.02
215.3000183	0.14
219.2741089	0.42
219.9125214	0.10
221.1755219	0.12
224.1060791	0.38
224.8514099	0.12
227.3587952	0.09
228.3548279	0.08
232.8662262	0.03
233.9302368	0.07
235.1747131	0.74
236.8990784	0.44
239.9031067	0.07
241.3401337	0.05
242.0428009	0.14
243.1430359	0.68
245.1666565	0.04
245.8862762	0.02
251.9346313	0.06
259.3142700	0.13
261.2875977	0.18
267.0011292	0.07
268.2098389	1.57
269.1686096	0.35
277.0857544	2.62
277.8145752	0.04
279.0210571	0.30
286.1148071	15.14
287.1074219	0.46
288.1708374	0.11
295.1652832	0.15
297.0978394	0.06
303.1259766	1.81
304.2236633	0.09
308.4296875	0.03
317.9818726	0.05
321.0452271	100.00
321.8794250	0.59
328.1873169	0.02
341.2341309	0.22
344.1983032	0.03
370.3107910	0.02
389.0897827	0.05
395.0841675	0.03
400.2926025	0.22
407.1619873	0.09
408.2392578	0.59
432.5177002	0.03
438.0958862	0.04
452.1506958	0.30
460.4303589	0.06
461.1770630	0.38
462.1148682	0.05
470.2077026	9.67
479.1925659	9.48
482.2005615	0.04
519.2874146	0.10
528.1753540	0.32
546.2496338	2.60
562.0952759	0.02
564.1754761	0.04
578.1052856	0.02
585.0870972	0.14
586.1398315	0.04
590.2216187	3.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.125
Annotation	Limocitrol 3-glucoside
Peak:m/z	Relative Intensity
161.0479431	0.10
166.6225891	0.07
213.1699677	0.05
258.9791565	0.07
261.4429321	0.10
289.1560974	2.81
311.3774414	0.06
315.3978882	0.09
320.6769409	0.04
321.3320312	0.56
322.2668457	0.02
326.9714355	0.05
340.9454346	2.19
345.3643188	0.20
357.1155396	0.25
375.1383667	0.61
387.0436401	0.07
432.9774170	0.14
447.5012817	0.03
450.9353027	0.94
451.7213745	0.14
491.3312378	0.25
493.1253052	100.00
493.7588501	0.15
507.3229370	0.12
519.3595581	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	817.3292
Annotation	Unknow
Peak:m/z	Relative Intensity
241.0744781	0.19
252.5439301	0.06
263.1102905	0.17
265.1718445	0.11
281.4113770	0.32
295.3495483	0.39
299.2102051	0.12
303.1270142	0.07
306.8439941	0.06
310.0783997	0.10
329.2368164	0.08
331.6419067	0.04
333.6737061	0.18
335.1038208	0.07
341.9904785	0.07
343.5840759	0.09
351.5747375	0.05
352.2362061	0.05
364.4264526	0.09
367.0998230	0.47
385.3086548	0.11
387.3353882	0.34
401.1331787	1.44
410.4299927	0.07
419.2271118	0.37
426.4313965	0.08
429.1960449	0.09
430.6927490	0.23
431.3152466	0.48
440.9433594	0.06
443.3876953	0.24
447.4930420	0.03
449.1240234	1.28
462.7804565	0.05
472.9387817	0.56
477.4651489	0.09
479.4041138	0.42
485.0525513	0.07
504.0277100	0.04
515.0546265	0.13
517.3922729	0.13
521.6574097	0.10
527.3400269	0.12
527.9736938	0.03
543.0791016	0.11
545.1559448	0.52
547.3114014	0.10
549.4650879	0.18
555.2690430	0.03
561.4231567	0.20
565.0106201	0.10
573.4719849	0.10
576.4574585	0.11
577.4043579	0.10
579.1513672	0.09
583.0786743	0.07
591.3346558	100.00
593.3864746	0.29
599.0488892	0.33
607.3096924	0.08
613.2410278	0.23
623.1526489	0.22
629.7106323	0.20
640.6950684	0.09
645.0258179	0.04
647.2744751	0.29
649.4353638	0.10
655.4544067	0.21
662.3475952	0.03
673.3970337	0.16
675.1920166	0.26
681.5653687	0.09
685.3092651	0.07
691.4109497	0.21
697.0541382	0.06
709.2717285	0.04
715.4993286	0.23
727.0084839	0.06
727.8195190	0.12
739.3805542	0.25
741.2454224	0.42
755.8065186	0.12
756.4570312	0.16
758.9050903	0.04
765.4308472	0.06
767.4237061	0.05
769.1234741	4.71
771.4889526	0.11
773.3823853	0.22
799.2382202	1.98
809.1080933	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3087
Annotation	Serinocyclin B
Peak:m/z	Relative Intensity
241.1499023	0.05
242.3795471	0.01
259.1604309	0.02
301.2053223	0.01
321.0126343	0.03
325.2823486	0.10
340.4531250	0.12
343.3192749	0.09
375.1063232	0.10
383.3334351	0.03
387.3245850	0.02
389.1861572	0.02
403.2077026	0.05
408.4732056	0.02
413.3284302	0.06
415.2036743	0.03
431.3385010	0.06
435.2847900	0.11
442.9848022	0.04
447.2804565	0.04
452.2767334	0.06
457.1534424	0.06
468.2464600	0.05
470.3630371	0.01
472.4542236	0.03
475.4730225	0.02
476.5825195	0.09
477.3770142	0.07
479.4041138	0.03
493.3872681	0.16
494.2353516	0.05
500.6604004	0.08
505.8818359	0.06
511.6695557	0.07
517.4205933	0.06
518.1831055	0.03
530.0101929	0.04
553.2526245	0.05
579.3095093	0.08
592.8977661	0.02
596.3236694	0.07
609.1559448	0.02
610.4670410	0.03
611.3475342	0.06
617.5020142	0.18
619.6834717	0.02
627.2684937	0.03
632.3667603	100.00
633.3850708	0.49
634.2703247	0.26
634.9910278	0.04
636.0854492	0.10
637.2950439	0.46
638.0244751	0.22
639.1074829	0.11
764.6149902	0.07
777.4362793	0.03
804.9793091	0.07
941.4399414	0.10
957.5466919	0.04
969.5166016	0.05
1023.3067020	0.06
1085.0957030	0.03
1103.3686520	0.55
1104.2773440	0.03
1265.6549070	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1349
Annotation	Syringetin 3-galactoside
Peak:m/z	Relative Intensity
150.1128387	0.07
152.9328766	0.02
164.9882050	3.75
179.3275604	0.12
182.9093933	0.11
190.9810486	0.03
253.2890320	0.13
283.0657959	0.44
287.2462769	0.09
301.0796814	100.00
301.9588013	0.16
308.9237671	0.03
326.4062195	0.05
327.4447021	0.06
339.2350464	0.19
343.0838318	0.18
348.9407654	0.03
375.8916016	0.03
385.0368347	0.09
425.4993286	0.05
427.0959778	0.03
430.8577576	0.07
443.4169617	0.07
445.1804504	4.13
457.2928772	0.05
460.7021179	0.04
463.2037048	3.17
469.5396423	0.02
487.1424866	0.17
490.1566467	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1281
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
71.9086380	11.20
72.5242615	0.08
83.6616058	0.06
114.7868958	0.01
117.9496460	100.00
129.9732819	2.30
148.0600281	0.70
174.0841827	0.04
174.9964447	0.07
184.0370178	5.62
184.6946564	0.03
201.0474548	1.31
204.8544464	0.08
211.0227509	0.62
229.0610504	5.85
230.1616364	32.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1458
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
175.0044861	0.19
176.8573608	0.91
193.1708984	0.05
211.3443756	0.09
255.5061951	0.06
271.0634155	100.00
271.6709290	0.18
283.0770874	0.06
285.1212769	0.15
286.3132019	0.09
287.0574341	0.08
310.8663940	0.04
313.0946045	0.57
319.2222900	0.05
321.3694458	0.11
325.1381836	0.08
326.9896851	0.10
337.1240234	2.94
338.2030640	0.18
343.2410278	0.57
368.0037231	0.04
409.4254761	0.15
415.2582397	0.09
419.1298218	0.04
427.1110229	0.09
429.4089966	0.27
433.3253784	0.32
439.3159790	0.07
446.9891357	0.27
450.8817749	0.06
456.8305664	0.35
463.3549805	0.04
465.5339355	0.47
471.2597046	0.20
477.0188599	0.14
482.8861084	0.02
489.2168579	0.39
507.2549438	0.18
518.7268677	0.11
523.1001587	0.18
546.9524536	0.11
549.5360718	0.28
563.5575562	0.06
565.3603516	0.45
591.1353149	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.1143
Annotation	Leucyl-Aspartate
Peak:m/z	Relative Intensity
84.1551361	0.02
115.9491730	1.02
123.1098175	0.05
127.9468384	100.00
129.2029114	0.04
144.9864960	0.01
153.1321564	0.30
172.4140472	0.01
173.9241180	0.02
175.0943298	0.04
187.0616608	0.12
188.2526550	0.07
197.0081329	0.11
201.1887970	0.14
202.0747223	0.01
203.1143951	0.54
209.1848602	3.27
216.9774628	0.07
227.0417328	40.12
245.1312714	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	898.2278
Annotation	Unknow
Peak:m/z	Relative Intensity
259.1389160	0.26
262.1521912	0.17
264.1132202	0.37
271.3751831	0.43
283.2397461	0.55
284.2286377	0.19
287.0602417	0.08
293.3155212	0.34
294.2240601	0.18
295.2423401	0.05
300.9863586	0.06
303.1560669	1.94
307.0490723	0.19
319.1370239	0.45
320.7510986	0.18
325.1611938	0.13
326.1461487	1.01
328.1671448	0.35
329.2412720	0.06
335.1386719	0.78
343.0763550	22.62
343.6877747	0.13
345.0454407	0.15
347.0715332	0.36
353.1378784	7.22
383.1342468	0.87
393.2186890	0.45
408.1932373	0.14
426.1403198	0.28
426.8037720	0.11
429.0402832	0.28
436.2854004	0.12
437.0020142	0.11
443.3023071	1.36
444.0875244	0.61
446.0637817	0.24
454.1356201	0.56
454.9298706	0.06
455.5497437	0.27
460.9902954	2.24
462.0759888	0.17
463.2136230	2.59
463.8897705	0.07
472.2028809	12.92
479.0991821	7.85
481.1387329	18.33
484.3112183	0.11
501.4379883	0.09
503.0969238	0.37
519.2661743	1.35
521.2534180	2.75
529.3179321	0.09
556.0765991	0.14
557.2303467	0.30
573.4295044	0.08
590.2658691	1.40
592.4455566	0.85
593.0875854	0.09
599.3369141	1.42
600.1718750	0.30
601.1448364	0.18
608.1481934	24.22
610.1052246	100.00
610.8093872	0.52
625.5918579	0.17
631.4758911	0.35
634.0409546	2.03
643.4199829	0.28
650.4421997	0.44
683.3953247	0.09
728.0446167	1.91
730.2526245	0.50
733.1433716	0.29
736.0879517	0.24
742.5192261	0.16
746.1331787	0.58
751.6369629	0.81
754.0337524	0.21
760.5023193	0.10
768.9501343	7.05
769.5637817	0.35
772.3724976	0.38
809.1482544	0.52
809.8124390	0.11
844.3302612	0.46
862.0576782	0.12
880.0452271	2.52
880.6555786	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1235.6
Annotation	YM 47525
Peak:m/z	Relative Intensity
377.1801453	0.53
391.3198242	1.26
395.2218628	1.45
421.6057129	0.31
425.2689209	1.22
457.7680054	3.70
465.4711914	0.45
483.1696167	1.00
557.5546875	3.24
568.9197998	0.60
569.6610107	1.48
571.4506226	1.71
589.4819336	4.45
615.8464355	0.44
657.1273193	1.40
659.7186279	0.39
671.1361084	0.74
685.7019043	0.31
703.0089111	1.44
703.8258057	1.22
733.6650391	6.57
749.4915771	0.39
751.4020996	20.27
752.5228271	3.88
763.5826416	2.44
765.5583496	0.73
819.4014893	7.89
820.0120239	0.19
833.6191406	5.50
847.6058350	8.72
848.3513184	0.45
849.2529297	0.56
863.4713135	0.25
865.4400635	50.51
866.3400879	3.41
883.4445801	8.42
884.6103516	2.13
891.4261475	19.02
909.4522705	94.10
910.5485840	5.71
927.4934082	6.02
955.2399902	0.31
957.5345459	1.19
961.0891113	0.76
993.5626221	1.25
1009.4975590	5.01
1011.3222660	15.83
1011.9246830	0.29
1025.2567140	0.60
1027.3756100	71.87
1028.5601810	1.65
1029.5609130	0.48
1045.5361330	9.33
1046.2873540	0.42
1054.4747310	2.02
1071.4782710	6.93
1089.4550780	22.65
1101.5537110	1.37
1171.7641600	1.18
1173.3826900	100.00
1174.4661870	2.88
1191.5521240	5.23
1217.4361570	70.57
1218.3903810	6.62
1219.0236820	1.17
1507.3686520	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1401
Annotation	Gerfelin
Peak:m/z	Relative Intensity
158.8805847	0.07
161.0768280	0.23
162.2112732	0.05
163.2727051	0.15
164.0944366	1.09
165.0605164	0.17
167.2095337	0.06
173.9576111	0.07
175.0540009	0.33
176.1094360	0.11
177.2320862	0.09
179.1616821	0.28
181.2466736	0.05
183.0786438	0.03
184.1928711	0.03
184.8089905	0.07
186.9852295	0.78
187.9660034	0.31
189.1109161	0.04
199.1332092	0.13
202.0715485	0.23
203.1299896	2.68
204.9946899	1.41
207.3157959	0.06
211.5820007	0.20
212.2205353	0.21
217.0777130	0.26
225.2890778	0.12
227.2060547	0.76
227.9635315	0.04
229.2091217	0.07
230.2532043	0.10
231.1112671	0.41
245.0905914	7.78
247.1402893	0.39
250.8731079	0.10
253.2161255	0.27
257.2069397	0.07
267.4584351	0.05
269.1159058	0.19
271.1714478	17.89
273.1104736	3.82
281.0921021	0.04
283.1006470	1.25
285.1993408	0.05
289.1189575	100.00
290.3355713	0.13
293.2115479	0.03
299.3542480	0.07
301.2894897	0.11
311.2186279	0.14
323.3450928	0.15
328.0006104	1.30
329.1274414	4.43
331.1834717	0.11
333.0013428	0.02
339.2429199	0.42
341.2098389	0.47
349.2548828	0.12
351.0552368	0.03
363.2385864	0.29
373.4967041	0.03
381.2313232	2.84
391.2410889	0.69
393.3110352	0.56
405.3031006	0.03
407.1547852	17.95
409.2413940	1.36
410.2759399	0.21
411.0967407	0.19
415.3853149	0.02
417.3128662	0.94
419.2802124	0.06
423.2474976	0.07
425.1270142	20.20
425.7727661	0.03
429.3121948	0.06
433.0422974	0.34
435.1621094	39.72
436.2760010	0.07
437.2793579	0.06
449.2954102	0.30
453.0486450	0.03
459.1248169	0.15
467.2074585	0.19
477.1985474	0.53
499.1162720	0.07
501.1443481	0.02
516.1802368	0.06
517.3535767	0.70
525.1771851	0.45
543.1969604	32.99
544.1857910	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.1749
Annotation	Unknow
Peak:m/z	Relative Intensity
98.9817963	0.09
110.1343994	0.15
113.9575653	0.14
117.0070877	23.49
126.8755569	0.05
128.0446472	0.16
130.0788879	0.04
132.0581818	0.22
134.0593872	0.18
137.3027039	0.09
140.9548645	0.04
144.6345978	0.23
146.9008484	0.06
149.1695557	0.21
150.2268677	0.40
154.0184631	0.13
156.0397949	0.09
160.6295166	0.12
162.8937683	84.53
165.9122162	0.14
167.0735321	0.16
175.2438812	0.19
180.0423126	1.41
187.0923767	0.04
191.1698303	0.09
192.2989197	0.15
194.0939636	0.10
195.1262970	0.39
196.0015564	1.51
199.1339874	0.08
201.2249756	0.16
205.1459351	0.06
206.1108398	0.06
212.0868225	3.85
213.1408691	3.63
221.0816345	0.10
223.9784241	0.10
227.0629272	0.14
228.0480652	0.15
229.2568665	0.46
236.4143982	0.08
237.0984497	0.09
239.0604858	0.55
244.9855347	0.19
253.1997986	0.24
254.2808838	0.16
258.9677734	0.06
265.2640076	0.49
267.9842834	0.06
270.0879822	0.98
276.9675293	0.62
279.3761597	0.22
280.5247192	0.43
281.6863403	0.27
283.2180481	0.05
288.9969788	0.05
293.6977234	0.28
296.1583252	1.01
297.0975037	0.82
298.3840027	1.46
307.2159424	0.63
310.6432495	0.67
321.1728516	0.08
322.0395508	0.33
323.7615356	7.63
324.7896118	100.00
342.3222351	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	648.3862
Annotation	1-Palmitoyl-2-(5-keto-8-oxo-6-octenoyl)-sn-glycero-3-phosphatidylcholine
Peak:m/z	Relative Intensity
181.1130981	0.07
198.9778900	0.19
205.3910828	0.03
207.3605042	0.11
214.1245422	0.07
227.1796722	1.70
231.3677979	0.05
232.3962402	0.10
245.3668976	0.04
252.9888000	0.03
255.0070953	0.08
255.8245239	0.10
284.8859253	0.02
299.3543091	0.07
306.4733276	0.25
307.0997925	0.15
310.7348022	0.11
312.1652832	0.04
319.5078125	0.04
325.0871582	0.09
337.3012695	0.09
338.1951294	0.04
356.3845215	0.05
368.1115723	0.33
374.5521240	0.14
378.3854370	0.08
392.0328369	0.04
410.3659668	0.05
411.2843628	0.03
422.4802856	0.20
423.4735718	0.05
424.6442261	0.18
451.2180176	0.05
460.0205688	0.05
462.2091064	0.17
466.9610596	0.03
471.5454712	0.13
475.4627075	0.08
476.5462036	0.18
478.5097046	0.22
483.4395142	0.30
489.5570068	0.37
491.3718262	0.09
492.2534790	0.07
503.2560425	0.05
507.3641968	100.00
508.0197144	0.52
515.4160767	0.17
518.5561523	0.04
526.4088745	0.17
532.3053589	0.07
538.3552856	0.09
547.1611938	0.11
550.3745117	0.58
558.1588745	0.15
574.3631592	0.10
577.6206665	0.13
586.6734009	0.04
590.4193115	0.02
594.4887085	0.13
596.5531616	0.13
602.7352905	0.34
605.3211670	0.06
611.8805542	0.07
612.7167358	0.17
621.6330566	0.09
630.3007202	2.00
631.6999512	0.07
650.2567139	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	827.2672
Annotation	Lantanose A
Peak:m/z	Relative Intensity
250.0923462	0.06
280.9207458	0.68
290.9815063	0.14
293.3535156	0.12
323.1791992	1.04
340.9507446	12.57
341.5617676	0.55
365.1389465	2.00
376.9747620	0.04
383.1967163	27.75
412.5303345	0.60
413.1511841	0.12
425.0596313	0.42
442.3626099	1.68
443.0382080	11.36
449.3901367	0.17
465.4578857	0.05
467.1978149	0.35
472.8380737	0.07
482.9957275	0.55
485.1974487	3.09
503.0406494	11.74
509.4028931	0.26
527.3054199	0.26
545.1735229	100.00
569.2086182	0.69
575.3208618	0.33
587.2588501	1.89
593.0554810	0.12
604.8904419	0.81
611.3898315	0.48
629.3892822	0.47
647.1951294	4.59
665.4216309	0.06
707.2813721	0.67
809.2972412	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1173
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.8822250	2.35
83.2966156	0.04
87.0728149	0.13
89.9869385	41.71
94.8004456	0.05
97.9100647	0.39
105.9412689	0.02
112.9047089	0.02
114.1008453	0.09
115.8766785	4.31
117.8427887	0.20
118.8596344	0.16
124.1316528	0.06
128.4096985	0.05
129.9251709	0.04
131.0205994	0.31
132.1370544	0.10
135.1636658	0.06
141.9770203	0.19
145.8914032	0.65
148.1542664	0.02
150.2068329	0.04
154.0218964	0.12
156.0602875	0.84
159.2741394	0.05
159.9858856	0.17
163.8961334	0.18
165.9837952	0.59
172.0104828	0.35
174.1504669	6.03
176.1274719	4.61
178.0502014	0.22
179.1038361	0.10
184.0693207	23.51
191.9844666	0.27
198.4621735	0.03
202.1199951	100.00
203.0168610	0.06
210.8420105	0.50
211.4943390	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1301
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
160.9839325	0.30
181.4646912	0.09
190.8272705	0.09
196.8822021	0.17
208.0293732	0.08
245.0608368	0.14
258.9255371	0.09
261.3208008	0.16
273.0625000	22.70
296.9780273	0.07
315.1026611	0.07
323.1736450	0.20
329.2230225	0.04
331.4943848	0.23
339.2196655	0.10
341.0977173	7.39
343.1350708	0.04
352.3403320	0.06
359.2422485	21.16
372.9768066	0.11
375.0429077	0.23
383.2384033	0.10
389.3137207	0.08
433.1101685	0.03
435.0528564	0.12
439.1973267	0.17
440.2868042	0.24
449.1627197	0.25
450.1458740	0.10
457.1920776	2.09
459.2852783	0.26
475.0636597	0.22
477.1144409	100.00
477.7556152	0.23
479.4995728	0.24
484.2195435	0.05
485.2064819	0.40
502.1209717	0.61
503.2010498	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1170.5746
Annotation	Unknow
Peak:m/z	Relative Intensity
470.2246094	0.03
596.3444824	0.12
721.3531494	0.06
891.6834717	0.08
994.2626953	0.13
1089.4619140	100.00
1090.4594730	27.93
1091.2167970	0.24
1103.6389160	0.11
1105.4433590	0.14
1107.5903320	0.07
1121.5484620	0.06
1189.4746090	0.05
1233.5487060	1.14
1234.4519040	0.20
1235.5017090	0.52
1249.7224120	0.13
1251.4306640	89.87
1252.4943850	25.56
1253.2523190	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.3243
Annotation	Hirsein B
Peak:m/z	Relative Intensity
223.3424377	0.14
241.0223541	0.49
259.2367554	0.19
269.2839966	0.05
277.3675232	0.39
278.1226807	0.09
279.1484985	0.04
286.3727417	0.21
293.4795227	0.07
307.4363098	0.08
315.7265320	0.05
318.5060425	0.03
336.1127930	0.14
337.3864136	0.19
350.9315186	0.05
353.5487061	0.03
355.2490234	0.66
373.2914429	0.30
374.3945923	0.07
380.2799072	0.08
397.2404785	3.10
398.1000366	0.02
415.2838745	100.00
639.1112671	0.02
647.1246948	0.50
649.2725220	0.26
658.0729980	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.16
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
169.0377655	0.04
181.1748962	0.02
187.2295074	0.04
225.0840454	0.14
229.2107697	0.02
240.9197235	0.03
247.4221191	0.02
271.0760498	69.90
271.7138367	0.31
281.3656616	0.05
287.2771606	0.06
291.2433472	0.04
304.0500488	0.13
367.2625122	0.04
381.1544189	0.02
390.6110840	0.01
400.2464600	0.02
415.2129517	0.34
417.9516602	0.04
425.3160400	0.05
427.1413574	0.08
430.7814331	0.03
433.0347900	100.00
433.7042236	0.32
443.0881958	0.04
465.2472534	0.04
505.3192749	0.02
528.4132690	0.05
540.8208618	0.03
548.9642944	0.10
559.3120728	0.04
576.7241821	0.05
577.6743164	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.304
Annotation	Aristolin
Peak:m/z	Relative Intensity
193.0401917	13.93
211.1994781	0.44
215.0115662	1.59
233.0741425	2.97
241.1278381	0.82
251.4774628	0.48
291.2079468	2.73
303.9117432	0.49
319.0000610	0.32
322.0567017	100.00
374.0884399	1.52
435.2352295	0.67
469.2281494	0.37
474.2744141	0.57
478.9882812	0.51
483.1748047	0.31
501.2407227	2.80
540.3078003	0.57
612.1493530	0.57
621.5785522	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	955.49
Annotation	Tuberoside A (Ullucus tuberosus)
Peak:m/z	Relative Intensity
323.2871399	1.73
330.1871948	1.19
383.3195801	1.08
391.4241943	4.08
407.2714844	12.37
408.5468140	2.23
423.5006714	1.58
435.4463501	23.97
437.1918335	0.51
453.3705444	10.41
455.4144897	43.89
467.5436401	2.50
475.3319702	1.18
477.6704712	4.00
481.0458984	3.45
497.8806763	2.41
499.6408691	1.17
505.3583984	0.73
523.5298462	100.00
533.7341919	1.02
551.2539673	2.25
569.4513550	1.62
594.3204346	3.31
595.2890015	44.47
613.3895874	55.18
631.4520874	10.47
632.3209839	1.79
665.7106323	1.29
711.4653931	1.64
731.4372559	48.16
749.3032227	10.02
775.3214111	6.44
776.1558228	2.47
793.4336548	22.93
794.5255737	9.13
810.3350220	1.34
893.3186035	42.22
894.8840942	3.49
936.0420532	4.10
937.3207397	52.32
937.9223633	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.198
Annotation	Kaempferol 3-xylosyl-(1->4)-rhamnoside-7-rhamnoside
Peak:m/z	Relative Intensity
205.0407715	0.11
206.1590576	0.28
211.0318298	0.10
215.2636414	0.13
217.0940399	0.23
218.8626556	0.09
220.2004700	0.05
221.1804047	0.36
222.3757324	0.33
223.1263733	0.20
224.1352234	0.04
232.2226562	0.10
232.9336548	0.72
234.2771149	0.06
235.2413177	0.08
238.3686829	0.13
239.0578766	0.07
244.3857117	0.08
245.3542480	0.10
247.2101135	0.36
248.2308197	0.28
249.2265167	0.34
251.0165710	2.17
251.8260193	0.04
261.1838074	0.42
263.0369568	2.01
264.1750488	1.29
265.1759033	0.44
266.3167725	1.54
267.0962524	3.53
273.4193726	0.12
276.1653442	0.09
277.1762085	1.44
278.6264343	1.80
279.2490234	5.45
280.2644653	0.13
281.5118713	0.17
282.2751465	2.87
283.1900940	0.41
287.0788879	0.07
289.3052979	0.04
290.1990662	0.21
291.0062866	0.10
292.9584351	0.88
294.0790405	10.20
295.1449280	0.86
296.0037842	0.07
297.0941772	3.47
297.7023926	0.10
302.2898560	0.20
306.1182251	0.05
307.1845703	1.08
308.1508789	1.06
309.1214905	8.92
310.2495117	1.36
317.2288818	0.21
320.0775146	1.30
321.2685547	1.44
322.2264404	4.25
323.1694336	10.22
324.3946533	0.23
325.2460938	0.22
326.1727295	1.00
327.2692261	0.97
333.5029297	0.48
335.4075928	0.21
336.0603943	0.08
337.2555542	3.27
338.1427917	22.21
339.0901489	1.57
341.2114258	47.65
342.1715698	0.24
345.3496704	0.36
347.2967224	0.06
351.3262329	0.17
353.1477966	100.00
354.2053223	0.88
355.3275452	0.12
357.3964233	1.27
363.3420410	0.10
369.5139160	0.06
371.0421753	1.57
375.3206787	0.12
391.3438110	0.15
393.5034790	0.05
397.1503906	0.07
409.0044556	0.25
418.0653687	0.16
421.2919922	0.15
422.3871460	0.07
437.0924072	0.69
441.3020630	0.13
463.4572144	0.11
467.2833252	0.04
470.9501953	0.37
481.3544922	0.12
499.2554321	0.47
500.3522339	0.52
501.3249512	0.21
505.3049316	0.14
511.6273804	0.14
515.1995850	0.04
519.4166260	0.27
532.4042358	0.18
533.2976074	0.30
547.3131104	0.27
553.2788086	0.17
554.3213501	0.04
557.1397095	0.06
563.3653564	0.22
564.3561401	0.76
565.3232422	1.27
571.0808716	0.17
573.4038696	0.23
578.2118530	0.17
580.2988892	0.08
583.2698364	0.06
589.4861450	0.36
595.2467041	0.14
602.3975220	0.11
603.2963257	0.42
604.0873413	0.37
606.3607788	0.09
617.6238403	0.18
619.3710327	0.29
621.5671997	0.07
622.4013672	0.10
625.2365723	0.05
634.1045532	0.16
635.3030396	0.46
647.1635742	1.13
648.2741089	0.07
649.2346802	0.51
658.7868042	0.06
663.1315308	0.14
664.7119751	0.37
667.2202148	0.13
673.3105469	0.49
677.0109253	0.68
677.8914185	0.10
678.7241821	0.10
681.2379761	0.19
690.1770630	0.12
691.2246094	2.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1064
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
130.0478668	0.08
130.9481506	0.05
145.117981	0.01
287.0543213	100.00
287.6717529	0.12
292.343811	0.03
297.4189758	0.03
300.8226929	0.03
302.1035767	0.35
311.2189636	0.06
313.0639038	0.05
318.4772644	0.01
320.3015442	0.02
327.2147827	0.01
329.1653137	0.44
345.0524597	0.05
348.2391968	0.06
349.964447	0.01
353.1922913	0.19
355.1155396	0.02
367.0614319	0.01
368.0126648	0.04
383.1362	0.10
386.0644836	0.03
390.2471619	0.02
394.964447	0.18
395.6496887	0.02
401.2584229	0.05
412.9853516	0.09
431.1530762	1.05
432.3683167	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.2941
Annotation	LysoPE(0:0/20:3(8Z,11Z,14Z))
Peak:m/z	Relative Intensity
153.0529633	0.14
161.1294556	0.02
168.3180847	0.11
191.2512360	0.03
198.7944031	0.02
204.9938049	0.18
224.0470886	3.57
233.1997833	0.72
242.0779724	2.05
249.3802490	0.04
257.0989685	0.02
259.3566284	0.37
275.3150635	0.42
277.2246094	100.00
278.2875061	0.29
323.3666382	0.11
344.4132690	0.11
413.3013916	0.43
441.1095886	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9685745	0.01
160.8318176	0.03
178.9796448	0.03
187.1529236	0.03
224.3650513	0.01
225.0889282	0.06
255.2123718	0.06
258.3476562	0.05
275.2750854	0.05
276.6116333	0.02
277.3710022	0.04
324.5774841	0.04
341.1122437	100.00
343.1032104	0.10
369.2455139	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.0569
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0970001	0.19
179.2073669	0.13
184.7450867	0.33
215.0711365	0.39
223.2266388	0.18
228.9766541	0.10
229.9838257	0.63
240.0856323	0.09
242.2188416	0.10
245.1385956	0.14
251.1038208	1.78
255.0137482	0.24
268.0322876	0.27
269.1369019	0.21
271.2501831	0.18
272.8827515	0.07
283.2187500	0.18
284.0919800	0.78
284.9012451	0.69
286.0432434	0.63
287.3478394	0.08
289.1160278	0.14
292.0476990	0.36
294.0947876	0.39
299.0206909	5.74
300.2362671	0.35
300.8563232	0.10
302.1679688	0.91
303.0064087	0.23
309.2845154	0.22
311.1658325	1.89
316.9917603	5.69
318.1820679	2.53
319.5167847	0.51
320.2687988	0.05
322.3229980	0.13
332.2479248	0.09
336.1387939	0.59
340.1019287	0.10
342.1597900	6.59
343.0643921	0.25
346.9182129	0.20
355.2160645	0.06
360.9647217	1.23
362.0362549	7.25
367.7384644	1.45
371.0027466	0.08
372.0536499	0.10
380.1185303	6.88
381.2930298	0.07
386.0924072	3.81
387.0214233	0.71
398.5999146	0.29
400.3531494	0.10
401.2490845	0.50
405.1634521	2.98
407.3110962	0.06
416.1738281	1.26
417.1944580	0.13
419.3732300	0.34
423.0914917	1.68
427.7960205	1.07
428.4146118	0.82
430.8541260	0.09
433.2842407	2.63
434.1807861	6.39
435.1091309	0.35
448.9865112	1.42
453.1085815	7.81
467.3092651	0.25
469.4477539	0.21
471.0910034	100.00
472.1685791	1.18
473.3768311	0.10
478.9708862	4.05
480.0757446	0.10
491.2423706	0.60
497.1144409	23.85
498.0608521	1.30
499.2752075	0.06
501.2484741	0.23
513.2199097	0.24
515.0674438	17.07
516.0407104	0.93
516.9405518	0.59
519.0315552	1.36
527.1253662	0.93
531.0339966	0.31
545.0007324	18.40
545.8807983	0.91
546.5151367	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0595
Annotation	Unknow
Peak:m/z	Relative Intensity
171.8894043	0.14
177.1601562	0.13
186.9902954	0.44
189.9705658	0.05
215.8909607	0.35
217.0130920	0.07
218.1658020	0.08
223.8825073	0.04
226.0685883	0.15
234.0782166	0.31
242.0380859	0.39
253.8302002	0.07
257.9356079	0.22
269.0841064	0.32
276.1807251	0.44
277.9802551	0.13
291.8339539	0.27
293.7380981	0.13
301.0500488	0.27
305.9671021	2.44
310.1376953	0.05
316.8662415	0.04
318.2022705	0.16
334.9388428	0.24
335.9673462	0.74
345.9152832	0.33
351.2471313	0.26
358.2050171	0.21
364.1408081	2.89
365.1691284	0.35
365.9948120	0.35
366.9219971	0.06
382.0002441	27.10
382.6303711	0.28
389.2345581	0.30
390.0223389	0.11
396.0745850	1.19
398.0445557	1.70
407.8496094	9.02
412.0360718	0.09
425.2056885	2.13
425.9648438	37.61
427.2186279	0.15
430.2873535	0.10
432.5240479	0.12
436.9102173	0.10
437.8139038	0.39
438.7068481	0.22
441.8497314	0.15
443.1335449	0.03
444.9118652	0.11
445.9772949	0.21
453.9871826	0.08
457.4035645	0.05
459.4725342	0.04
462.3615723	0.14
468.9574585	0.11
484.9643555	0.48
490.1023560	0.25
499.2604370	0.08
512.8809814	0.10
521.3174438	0.47
524.1317749	0.60
526.0550537	0.49
544.0399780	100.00
544.6678467	0.24
556.0342407	0.09
561.8280640	0.14
569.1490479	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	334.1388
Annotation	Tryptophyl-Glutamate
Peak:m/z	Relative Intensity
99.0471039	0.04
117.1515503	0.06
117.9469604	0.03
130.1055756	0.25
132.0960541	0.13
144.1040955	0.17
146.0294647	0.98
148.0139313	0.02
159.1183777	0.50
161.1348267	0.03
166.3654175	0.03
170.0646057	0.01
176.9608612	0.11
184.9239655	0.02
188.0729065	65.21
194.2701416	0.03
204.9783325	100.00
207.9071960	0.05
223.0873413	0.01
225.0205994	0.06
228.1349182	0.10
229.9473877	0.10
231.1355896	0.02
245.1468201	0.05
249.6402283	0.04
252.8275757	0.02
258.2283020	0.24
271.0360718	0.82
285.0038452	0.02
287.2862854	0.05
291.0422363	0.07
293.1477051	0.03
298.1668701	0.06
302.0839539	0.03
307.2173157	0.06
311.0406494	0.07
316.1166077	2.89
317.1513672	3.75
320.2202759	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2142
Annotation	Stachyose
Peak:m/z	Relative Intensity
178.9357452	0.30
221.1155243	5.08
249.6485596	0.26
263.1913757	0.13
280.3291931	0.89
281.059845	1.30
299.1610107	0.59
305.2260742	0.34
311.0570068	0.67
321.1013794	0.81
322.9190063	4.51
328.0581055	0.14
340.5111084	3.69
341.1235352	28.39
348.015564	0.32
364.9761353	0.35
383.1161499	100.00
397.1013794	0.80
407.0321655	0.42
409.1878662	0.21
412.9699707	4.05
425.0846558	1.54
438.1959229	0.49
442.8140869	18.84
443.456543	0.65
454.7269897	0.43
467.2559814	0.52
485.2811279	27.88
502.7161865	1.19
541.1188354	0.18
545.1685181	1.86
572.9827271	0.60
577.5343628	0.11
601.1327515	0.20
624.1030884	0.11
628.9573364	0.46
647.5239868	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.217
Annotation	ent-Fisetinidol-(4beta->8)-catechin-(6->4beta)-ent-fisetinidol
Peak:m/z	Relative Intensity
240.9769287	0.05
243.1652985	0.26
244.7824707	0.79
247.1773987	1.46
253.0501099	0.18
254.2098694	0.06
255.1038361	0.58
256.9546204	0.26
259.1681519	0.94
261.1091614	1.22
266.9567566	0.06
269.0905762	0.11
271.0494080	0.76
273.1308289	1.08
274.1106873	1.10
275.1352844	1.31
280.4422607	0.25
283.1149597	0.40
285.1710510	1.40
286.0639038	0.13
287.1338501	1.68
289.1365356	1.45
291.2184143	0.51
295.0569458	0.68
297.2145996	0.16
299.1361389	0.53
301.2108459	2.37
303.2301636	0.93
307.0354004	0.17
311.0818176	0.88
315.1748657	0.16
331.2313538	0.10
345.0823669	1.00
347.2552185	0.16
363.0222168	0.50
365.4751587	0.10
367.2084961	0.18
373.2284851	0.11
375.0898438	0.05
379.2290039	0.21
381.1359253	0.19
383.2127380	0.10
388.8375854	0.04
391.1105957	9.72
393.2432861	3.07
395.2277832	0.70
396.2033691	0.11
397.2907715	0.75
399.3208008	0.05
401.3837891	0.13
403.2008057	2.66
405.3081055	0.10
407.1627197	1.86
409.1622925	8.57
411.1641235	2.26
415.1696777	0.55
417.1409912	0.53
419.0674438	0.59
421.2105713	8.70
423.0573120	0.18
425.0488281	1.30
427.1602173	0.24
433.1333008	2.41
435.0586548	2.05
437.2317505	1.14
439.0422363	6.49
441.9177856	0.11
443.2492065	0.08
449.1484375	0.67
450.8967896	1.13
453.2731934	0.50
465.1268921	0.04
467.4050903	0.07
468.1248779	0.08
471.1375732	0.05
482.8955078	0.07
485.1109009	0.04
487.1380615	0.17
499.0100098	0.30
500.3133545	0.07
501.0750732	1.25
513.3157959	0.06
516.2342529	0.31
516.9626465	1.10
517.5755615	0.14
519.0385742	1.21
525.2033081	1.46
527.3906860	0.06
529.0150146	0.18
529.8626099	0.08
531.0657349	0.27
533.0112915	0.05
535.0927124	0.51
537.4791260	0.28
539.1008301	0.07
541.2050781	0.72
542.0142822	0.06
543.1179810	3.04
543.9346924	0.45
545.1419678	1.60
553.2547607	0.13
555.0135498	0.43
556.9702759	0.08
559.2171021	1.35
561.0530396	21.23
563.0014038	11.86
571.2034912	0.82
573.1903687	1.32
575.2202759	0.66
577.0847778	4.42
578.1858521	0.25
579.1611938	1.16
583.2847290	0.31
589.2449951	0.47
591.0632935	100.00
591.7573853	0.29
603.0143433	0.22
605.1187134	0.59
644.8568726	0.11
658.6631470	0.43
662.0575562	0.18
663.0405884	0.84
671.0715332	0.06
675.1295776	0.13
679.0708618	1.01
681.0739746	3.97
681.6799927	0.09
683.0376587	1.04
688.5463257	1.46
689.3251343	2.21
694.5110474	0.05
695.4206543	0.41
696.3153687	0.53
697.1239624	5.21
699.1971436	5.26
705.6094360	0.33
706.7420044	0.55
709.1079712	0.58
713.1891479	0.23
715.0776978	4.44
724.9768066	2.65
726.9366455	0.16
738.8919067	0.06
754.9271851	0.14
755.5475464	0.14
765.5690308	0.72
797.2484131	0.18
814.6251831	0.30
815.4358521	0.15
832.4130859	0.49
833.1047974	3.54
837.2590942	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.1321
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
165.0356445	0.19
167.0667419	0.06
187.0521698	0.05
193.0725098	0.08
203.0760193	0.15
204.5455322	0.06
212.0556183	0.10
213.0001526	0.07
217.0021362	0.11
229.0092926	0.06
231.1568909	1.06
236.7608032	0.06
239.3387756	0.22
242.8686218	0.30
245.0761719	2.34
251.2081909	0.11
253.1596375	0.24
255.3854523	0.29
257.1071777	0.66
259.0688477	1.26
261.3751831	0.06
265.2742615	0.10
266.9464722	0.07
271.1626892	3.59
273.0507812	0.59
275.1827087	0.22
283.2114258	0.05
285.2957764	0.06
287.1055908	7.52
289.0667114	1.82
291.1342773	0.95
294.8553467	0.18
299.0219421	1.45
301.1362915	1.06
303.0977173	0.55
307.1135254	3.21
309.3233032	0.11
311.1957397	0.90
313.1549072	2.50
315.0156860	0.25
317.3572388	0.46
319.0840454	1.69
327.2341919	0.08
329.2402344	0.33
330.9526978	0.98
345.2977905	0.14
349.3262939	0.46
351.2901611	0.05
355.3615112	0.12
359.5057373	0.22
364.3051758	0.24
365.0302734	0.08
369.0204468	0.18
372.1506958	0.10
373.4192505	0.45
374.8013306	0.11
377.0868530	0.40
379.0848999	0.65
381.3932495	0.05
390.8049927	0.22
395.2910767	0.62
397.2395020	2.92
400.3286133	0.45
401.2110596	0.25
403.1476440	0.23
405.0402832	0.30
407.1033325	14.88
409.0446777	1.92
411.3338623	0.25
412.0923462	0.06
414.4775391	0.88
415.1317139	3.24
417.3154297	0.06
419.1155396	3.26
421.1141357	0.35
423.1860352	5.57
425.0523071	100.00
425.6779785	0.19
429.1120605	0.06
431.0289307	0.07
433.1649780	4.16
434.1337280	0.08
435.2219849	0.52
437.0402832	15.68
438.9430542	0.39
440.9964600	13.00
447.4486084	0.56
448.3646851	0.06
451.1083374	2.78
453.0679321	4.03
455.0250244	0.43
457.2706299	0.22
465.1257935	5.48
468.8664551	0.12
471.0498047	13.50
471.7607422	0.11
477.6622925	0.22
488.3140869	0.14
489.2418823	0.17
503.3462524	0.28
507.7836304	0.09
510.9125366	0.03
513.2709351	0.72
517.1603394	0.34
527.7559204	0.42
531.1255493	0.20
535.2890015	0.25
536.0120239	0.18
541.0969849	4.54
541.8242798	0.05
548.4557495	0.10
549.8787842	0.15
550.9165649	0.17
559.1497192	29.35
560.3121948	0.11
561.4006348	0.26
585.9447632	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
188.8335724	0.11
199.0399628	0.08
228.6513214	0.05
235.3543854	0.06
273.0379944	5.62
273.9668274	0.99
275.0509033	4.91
275.8446045	0.38
386.9308472	8.92
387.9099731	3.70
388.9857788	13.54
461.0305176	0.20
462.9977417	0.22
468.9028320	0.41
483.4343872	0.04
500.8818970	25.38
502.0766602	19.12
502.8892212	100.00
503.5110474	0.26
527.0071411	0.10
543.0076294	0.25
549.7405396	0.20
553.3293457	0.12
561.1210938	0.13
570.1687012	0.62
570.9378052	6.78
572.9150391	2.65
585.0050659	0.16
588.5750122	0.90
593.3709106	0.10
598.8073120	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.2215
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
105.0563965	0.06
107.0379639	0.12
119.1691971	0.07
121.0219269	0.05
123.3423157	0.06
127.9719696	0.04
130.0346069	0.37
131.0823975	0.14
132.1165619	1.18
137.0628204	0.07
144.9324493	0.11
147.1172943	0.15
148.9011688	0.09
156.0357056	0.16
161.0442505	0.02
162.1443481	0.03
163.0256958	0.25
164.8879089	0.11
167.0363770	0.60
173.0150299	0.40
177.2246094	0.01
179.0427856	0.24
188.9324493	0.04
191.0238037	1.38
206.1714935	0.10
209.1330566	8.91
211.9516296	0.03
219.7918396	0.02
227.0784912	1.13
229.5635376	0.05
234.0112915	0.09
236.3006287	0.05
238.1971130	0.26
242.2704163	0.01
245.1276245	0.10
252.1662598	10.68
254.4537659	0.04
255.9963074	0.10
256.6166382	0.01
258.2054138	0.32
263.2147827	0.03
268.9108276	0.04
270.2456055	0.44
276.1743774	1.40
278.2597046	0.07
286.2804260	0.07
286.9400940	0.03
289.0768433	0.05
292.1580811	0.43
294.2987671	4.43
295.0220642	0.08
295.9936523	0.03
297.2568970	0.03
298.2297974	0.06
298.9441223	0.03
304.2231445	3.93
309.0417480	0.04
312.2555542	4.33
317.1120605	0.11
322.1651001	15.10
323.0670166	0.11
327.2747803	0.02
328.0825195	0.68
328.7857666	0.01
340.1436768	100.00
341.0873108	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.046
Annotation	Unknow
Peak:m/z	Relative Intensity
83.0042114	0.05
84.9997559	10.59
85.7811127	0.02
87.0342712	0.12
98.9592133	0.02
100.8475647	0.21
102.9500732	0.08
110.9878082	10.16
113.1297150	0.02
125.1942902	0.11
128.9875336	1.19
142.9740906	0.22
147.0831757	0.48
159.0624695	0.13
161.0704041	0.92
173.0505219	0.46
177.1253815	0.07
179.0493774	0.03
184.9230194	0.04
187.0020294	2.74
195.0029755	0.21
205.0702820	100.00
206.1994934	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.167
Annotation	Galactotriose
Peak:m/z	Relative Intensity
340.9510498	0.02
415.2472534	0.17
416.3738403	0.03
503.1851807	100.00
515.2780151	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.7704773	4.08
292.5638428	0.13
320.9804688	0.07
374.5643921	1.76
413.6741333	0.10
420.2206421	0.03
423.4884033	0.03
458.5097656	17.70
459.2537231	0.03
460.4937744	0.20
470.5785522	0.04
539.8521118	0.05
542.4891968	100.00
543.1766968	0.18
544.8207397	0.05
581.2312622	0.06
582.2244263	0.10
592.4129639	0.14
616.1189575	0.13
623.6447144	0.11
626.3445435	47.33
627.0299072	0.41
652.1145020	0.03
664.5811157	0.09
692.5568237	0.09
707.8466187	1.86
710.2039185	78.30
711.0151978	0.12
747.9253540	1.31
749.7651367	0.08
752.7482300	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.1581
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
156.8713989	0.65
158.0643005	0.29
161.1816559	0.15
162.8921967	0.08
164.0645447	0.05
164.9837341	0.10
167.1981506	0.06
168.9651489	0.77
171.0080872	0.81
172.8849792	0.09
175.0090637	0.06
175.8810730	0.07
178.9690094	0.91
181.1051941	0.46
185.0463867	0.90
187.0077515	0.37
189.0518951	1.64
190.8826752	0.27
192.9522858	0.70
198.7504272	0.24
203.0222778	0.14
205.0744781	0.13
213.0663910	1.50
215.2724304	0.06
221.8693542	0.24
227.1206207	1.47
231.0038757	17.89
232.1833191	0.09
233.0290985	0.86
237.1767731	0.17
238.9298096	0.25
243.0883331	10.42
244.3102264	0.30
245.0451660	1.72
246.6891174	0.05
253.0132294	0.06
255.0843506	7.18
257.0647278	0.84
259.2609558	0.11
267.1578979	1.72
268.1078186	0.05
269.1480103	1.97
271.0628662	0.42
273.1123352	53.43
275.0723267	92.33
275.6840210	0.08
279.1747437	0.19
280.9277954	0.03
285.1027222	23.84
287.0800171	20.64
289.2849121	0.17
291.7089233	0.31
297.2159729	0.21
299.1195679	3.67
315.1488647	0.11
317.1347046	0.96
322.1146240	0.12
327.1820068	0.22
335.1942749	0.13
339.0630493	0.17
351.5131836	0.05
361.1734619	0.37
367.1827393	0.31
375.1364136	0.18
379.1489258	17.97
381.2474976	0.31
385.3963013	0.13
391.1635132	1.30
393.0843506	98.19
393.7385254	0.88
397.1116943	0.19
403.0827637	4.38
403.7363281	0.20
405.1493530	11.87
409.1342163	0.39
410.9988403	100.00
411.6692505	0.17
417.4411011	0.18
418.0894775	0.10
421.1626587	7.33
423.0427856	12.77
423.6761475	0.06
434.7703857	0.66
435.4097290	0.07
453.4580078	0.08
501.2698364	0.15
503.1943359	0.26
511.1694946	5.37
529.0829468	12.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.2189
Annotation	Unknow
Peak:m/z	Relative Intensity
156.8671570	0.04
166.9565430	0.05
174.9345093	1.39
195.0442047	0.04
199.1980896	0.52
209.0420837	0.14
215.0822144	0.06
225.1652069	0.07
243.1884918	0.07
247.3323822	0.07
285.3466797	0.06
299.4029541	0.04
301.9877930	0.06
315.8806763	0.07
327.3095093	0.09
328.6356201	0.05
337.1321411	0.14
339.6373291	0.06
340.3199463	0.16
343.3606567	2.09
361.1837158	100.00
362.2854004	1.13
370.1075439	0.11
371.4835815	0.13
377.0375366	0.04
385.2849121	0.30
386.3075562	0.13
387.4767456	0.18
393.0822754	0.07
395.1510620	0.15
403.3359985	0.35
411.3438110	0.15
413.5581665	0.16
419.2442017	0.15
427.2268677	0.11
429.5336304	0.23
431.4636841	0.20
439.1531982	0.11
457.3324585	1.08
459.1907959	0.05
469.1585693	0.07
473.2052612	0.22
475.3059082	5.49
476.5130615	0.20
477.4301147	0.26
491.2161255	0.12
493.2614746	1.44
501.0534058	0.22
507.3248291	0.10
509.3060303	0.04
519.2850342	14.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.21
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1040039	0.45
179.1503296	0.03
190.9907379	0.09
203.4397888	0.02
216.8311462	0.06
219.0907440	0.07
231.2153625	0.05
238.9790802	0.81
241.0663605	0.06
245.1090088	0.09
249.0963898	0.05
251.1268616	0.04
259.0821838	0.17
262.0244141	0.20
263.4506836	0.03
270.9279785	0.04
275.3152466	0.09
280.9723511	0.05
283.1999207	0.03
285.3482056	0.03
286.3590698	0.26
287.2918701	0.34
288.1793213	0.02
289.0274658	0.69
290.1353760	0.10
291.2264404	0.03
293.2855835	0.16
295.0882263	0.14
297.1702576	0.03
299.1371460	0.49
301.1044922	0.07
303.2824097	0.07
305.2750854	0.65
311.2393494	0.04
313.2159424	0.03
314.0230713	0.05
315.0661011	0.05
320.4738159	0.12
327.7860107	0.03
328.3933105	0.03
329.2133789	0.31
331.2572632	0.06
337.0562744	0.03
353.2249756	0.02
363.0750732	0.06
365.3218384	0.10
367.2811279	0.16
374.4530640	0.04
381.4676514	0.10
383.2178955	1.46
385.4559326	0.04
387.2907715	0.05
393.2285156	0.07
395.1540527	0.02
397.0492554	0.20
399.2781982	0.11
401.2169189	100.00
402.0977783	0.91
407.2068481	1.94
408.2991333	0.07
409.1633911	0.12
414.4353027	0.32
415.1535034	0.28
421.4680786	0.02
423.1310425	0.54
425.1456909	2.37
427.0698853	0.06
428.6850586	0.17
431.3133545	0.11
433.4746094	0.04
435.2517090	0.20
437.7141724	0.19
438.8516235	0.06
440.3641968	0.10
441.0397339	0.27
443.3280029	0.48
447.8576050	0.07
449.2411499	0.13
450.1718140	0.17
451.1263428	2.18
453.3201904	0.18
454.3035889	0.35
455.1047974	0.31
456.9523926	0.21
459.5832520	0.08
461.6991577	0.03
469.1524658	0.18
471.2650757	0.17
473.3057861	0.05
481.0607910	0.06
487.1510620	0.03
489.6323853	0.05
491.1838379	0.21
492.1874390	0.07
493.2216187	0.10
497.1226196	0.74
501.1712036	0.04
503.3487549	0.06
505.2888794	0.02
514.6170044	0.19
515.3520508	5.49
516.2402344	0.19
517.3405151	0.23
528.1447144	0.01
529.2687378	0.13
531.2985840	3.53
533.1770020	1.84
534.2141724	0.07
535.3475952	0.07
540.1294556	0.11
541.2199097	0.79
554.0372925	0.05
557.2005005	0.07
559.2207642	8.18
560.3031616	0.07
565.3351440	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2731
Annotation	LTF4
Peak:m/z	Relative Intensity
185.0526123	0.06
188.4522247	0.03
192.9514465	0.11
217.1151886	0.05
282.9931030	0.02
295.2916260	0.03
325.3191528	0.09
343.1007690	0.02
351.3256226	0.02
353.3056641	0.09
362.3195190	0.12
373.0867310	0.07
386.9183960	0.04
391.0206909	0.17
392.6890869	0.10
406.4560547	0.12
438.8062744	0.08
445.3065186	0.08
452.0036011	0.02
521.0753174	0.14
523.4718018	0.05
531.4862671	0.05
537.1907959	0.05
539.4858398	0.03
544.3880005	100.00
545.3790894	0.50
546.4052124	0.10
547.5420532	0.07
549.3442383	0.07
550.3875122	0.14
551.2315674	0.04
657.4689331	0.03
765.3447266	0.04
795.5516968	0.03
880.4834595	0.03
927.5136719	1.81
928.5288086	1.33
1089.5812990	0.65
1090.5133060	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.28
Annotation	Unknow
Peak:m/z	Relative Intensity
240.8489532	0.26
242.3041534	0.18
243.1250305	0.63
245.0134888	0.65
254.9342194	2.12
257.2086487	1.02
261.3101196	0.47
267.0662231	1.81
269.2617493	1.31
271.2479858	0.20
273.0356445	2.71
274.1359253	1.28
275.1614685	0.34
281.2942810	0.13
283.0022278	0.47
285.0729370	5.79
286.4173889	0.47
287.1155396	1.08
289.0592041	0.85
291.0983887	1.85
294.9924622	0.12
297.1597900	0.73
299.2002258	1.80
301.1639404	0.54
303.1396484	0.49
311.1002197	0.29
313.0892029	0.18
315.0554810	0.24
317.0795898	0.16
324.8146057	0.19
327.3236084	0.21
331.1316528	0.40
339.2850952	0.22
349.3778076	0.51
351.2869873	0.65
359.4537048	0.82
367.2890015	0.11
371.2081909	0.09
373.3347778	0.25
375.2040710	0.10
377.2457886	1.94
380.1437378	0.13
381.1192017	0.58
382.8590698	0.26
389.1112671	0.79
391.2688599	5.96
393.1801147	3.60
395.0625610	1.15
396.3049316	0.21
401.2856445	0.79
403.0998535	2.25
405.1870728	4.40
407.3017578	0.85
409.1576538	5.86
411.0889282	1.81
415.1772461	0.50
417.3648682	0.64
419.0917358	2.74
421.1177979	4.62
423.1371460	6.42
424.9640503	0.94
433.0648193	0.31
435.1339722	1.32
437.1842041	1.95
439.0414429	0.93
445.0362549	0.38
451.1202393	0.98
453.2889404	0.13
467.3480835	0.11
481.5222778	0.10
485.1393433	0.33
491.6251831	0.27
501.2209473	0.24
503.2485352	0.52
509.2232666	1.45
511.3662109	0.28
513.1513672	0.91
515.4062500	0.54
519.0417480	0.16
521.0847168	1.46
525.3371582	0.83
527.1398315	3.85
528.8685303	0.73
529.5054932	0.25
533.2699585	0.11
537.3466187	0.30
539.1038208	3.03
540.8302002	0.16
543.0621948	2.15
545.0191040	15.48
545.7064819	0.29
547.1076050	3.74
555.2048950	1.85
557.1337891	3.26
558.7808838	0.21
561.0835571	9.55
563.0405273	16.71
571.1605835	0.17
572.9717407	3.19
573.5942383	0.68
575.0070190	100.00
575.6733398	0.16
587.0802612	0.38
589.0667114	0.27
604.1494751	0.15
605.1411133	1.58
620.3472290	0.13
639.5517578	0.22
647.1563110	1.15
651.2217407	0.08
652.2413940	0.14
655.3206787	0.13
659.1084595	0.10
661.2766113	0.13
663.2023926	0.78
665.2379761	2.99
667.1483765	0.94
672.7602539	0.40
676.8129883	0.07
679.1160278	0.09
680.9849243	8.08
681.5858765	0.03
682.9374390	3.46
683.6717529	0.15
688.2897949	0.15
691.3689575	0.69
699.0394897	4.94
703.3889160	0.86
708.9951782	4.01
709.6008911	0.17
711.1301880	0.21
716.4520874	0.08
754.5988159	0.10
767.8932495	0.35
789.2340698	0.08
813.2898560	0.35
817.0970459	5.72
818.0435181	0.13
824.6398926	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
111.1078796	0.17
114.9073944	0.04
118.9822464	0.07
129.0071564	1.53
143.1315918	0.04
145.1805725	0.11
147.0133209	3.00
172.9678345	1.53
177.9797516	0.07
179.3436584	0.07
189.2153015	0.04
190.9537964	100.00
193.1434479	0.31
208.9672089	9.51
233.1492310	0.16
261.0390625	0.13
311.6115112	0.15
322.9678040	0.06
340.9781494	0.16
348.7942810	0.05
367.0811462	9.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	798.317
Annotation	Unknow
Peak:m/z	Relative Intensity
290.1895142	83.74
324.9656982	31.76
326.0118103	40.50
488.2770996	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.17
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
109.0498199	0.31
113.0345764	1.76
113.9044189	0.15
118.8563080	1.89
120.2432175	0.16
124.9886017	0.34
131.0364685	1.60
143.0196686	1.31
145.0910187	3.39
147.1122742	0.30
148.8561096	0.29
160.9264221	0.72
163.0348206	41.14
164.1127625	1.37
165.4366455	0.25
179.1058960	0.94
189.2738647	0.53
207.1528931	100.00
208.0451355	1.77
225.1752319	3.91
232.0311279	0.30
287.2649536	0.67
295.3513794	0.49
341.1267090	0.11
367.3576965	1.28
369.2537842	19.94
370.3336487	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.143
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
70.8755951	0.04
77.0017776	0.03
82.8052750	0.05
90.7766724	0.04
92.8500977	0.04
95.1834869	0.08
96.0145874	0.02
97.1246491	0.11
98.9342956	0.01
99.9820557	0.04
106.9814606	0.02
113.3152161	0.04
115.0459442	0.04
116.2859497	0.05
117.3265991	0.07
119.1826477	0.02
121.0785522	0.09
128.9403687	0.24
130.9302521	0.18
132.9529114	0.42
135.0335083	0.44
137.1104279	0.07
138.8841095	0.02
140.8499298	0.02
143.0716248	0.07
147.0584259	0.76
148.9438477	0.22
150.9893951	0.25
153.0195007	0.06
154.9897003	0.23
157.2539368	0.12
165.0510101	0.02
168.9529419	0.18
171.1127167	0.21
172.8251801	0.06
174.5222778	0.12
175.1628113	0.54
182.7437592	0.02
183.9581909	0.09
185.1628418	0.11
186.4538727	0.18
187.1603851	0.43
188.0390778	0.20
191.2802124	0.10
193.0431671	14.78
195.2418671	0.06
197.0908051	0.01
201.0354156	0.33
205.7034149	0.09
207.8519745	0.13
209.1337433	0.02
211.0193176	100.00
212.0112762	0.04
213.0684662	0.10
213.9125824	0.09
220.0136566	0.14
221.2858429	0.05
225.3031464	0.06
229.0026855	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	819.3079
Annotation	(+)-Phyllanthostatin 2
Peak:m/z	Relative Intensity
228.0676880	0.09
239.1694794	1.50
247.0465698	0.13
249.1872864	1.53
251.2118988	0.15
251.8683777	0.13
253.2148438	0.27
255.0578156	0.09
264.9672241	0.73
265.6115112	0.05
267.0302429	3.58
272.1051331	0.08
276.9143372	0.08
279.1237793	0.47
281.4625244	0.08
283.0357971	0.18
284.7419739	0.10
291.1172180	0.13
293.0504150	0.12
297.0116577	2.84
299.2267456	0.23
301.3004456	0.17
311.0606995	0.21
312.1733093	0.13
312.9266357	0.54
315.4246216	0.21
325.1451416	0.28
327.0037231	3.71
329.4244080	0.05
335.3222046	0.29
336.8923340	0.18
338.1036377	0.23
339.2291870	0.03
349.2379761	0.08
351.3624268	0.45
352.2296448	0.23
355.3942261	0.56
357.4542847	0.15
365.2902222	0.16
367.1605835	0.10
369.3084106	3.21
371.1380310	0.18
372.0715332	0.73
373.1242065	1.14
378.0523071	0.22
383.3127441	0.22
385.4336243	1.30
387.2327271	26.48
387.8425293	0.13
389.4056396	0.16
397.6135254	0.16
401.2068481	0.28
407.4945679	0.15
411.4910889	0.17
413.3020630	0.08
415.4066162	0.04
418.7260742	0.05
427.3899536	0.11
432.9725952	0.04
434.8977661	0.03
437.2480469	0.24
438.4579468	0.28
441.2171631	0.33
442.3798828	0.14
449.1452026	0.80
452.2045898	0.59
455.2521362	0.16
457.1988525	0.08
459.2755737	0.30
464.5267334	0.12
475.0297852	0.44
477.1704712	0.20
480.5724487	0.60
483.2313843	0.09
485.1896973	0.35
486.0040894	0.14
488.2720947	0.53
489.3461914	0.05
491.2504272	0.16
493.2133789	0.50
494.4866943	0.03
500.2711182	0.09
501.2033081	1.18
503.0697021	0.18
513.3662720	0.25
515.1717529	0.69
516.2366943	14.54
517.2553101	2.09
519.2722778	13.90
523.4306030	0.04
528.0412598	0.28
529.1512451	0.25
532.3719482	0.21
533.3092041	2.76
536.2582397	0.05
537.4627075	0.08
544.3348999	0.11
545.2229614	0.27
546.2014160	0.23
548.2281494	1.26
549.4221802	0.62
555.2640991	0.11
559.3926392	2.56
560.2660522	1.86
561.2790527	7.23
563.1348267	0.08
573.5029297	0.35
575.3783569	2.24
577.5066528	0.06
583.1556396	0.08
585.4299927	0.07
592.1078491	29.95
593.3046265	100.00
607.3513794	12.36
613.4398804	0.04
615.3020020	0.30
616.8062134	0.13
617.4761353	0.46
629.6597290	0.27
633.3400879	0.15
634.7792358	0.14
635.4574585	0.39
639.2902222	0.21
643.3507690	0.75
645.1006470	0.19
646.7695312	0.25
647.3891602	19.73
651.0371704	0.61
655.7512817	0.14
657.2902222	0.11
665.2655640	6.09
667.6234741	0.12
674.3343506	0.28
675.2444458	3.44
681.3828735	1.02
687.0773315	0.13
693.3600464	0.21
695.1564941	0.13
699.2089844	0.26
703.4827881	0.04
706.2106323	0.77
714.4100952	0.09
717.2158813	1.88
721.6822510	0.09
728.4879150	0.08
729.6909180	0.20
733.6719971	0.24
739.1988525	0.31
745.2916870	0.40
750.9572144	0.36
754.7492065	0.08
757.0238647	0.80
757.6838989	0.03
759.2094727	0.33
760.6188965	0.16
769.2940063	1.32
771.2742310	3.25
773.0796509	0.12
774.8623657	0.21
775.5208130	0.71
781.2888184	0.09
783.2543945	0.34
787.2262573	1.12
789.3429565	0.14
797.2190552	0.62
801.2739258	10.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.15
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
157.2012787	0.07
157.8686676	0.05
159.0022430	0.04
163.0196381	0.35
164.0631714	5.32
165.0211182	1.54
166.1761780	0.08
168.7473755	0.09
171.1477509	0.03
172.2311554	0.02
175.0739746	0.02
177.0798340	0.18
178.9945374	0.06
180.0713654	0.05
184.9232330	0.10
187.0504150	0.73
189.1386261	0.77
191.1878662	0.07
193.0824432	0.66
199.1534729	0.06
201.1968384	0.04
203.2010040	0.27
204.9279938	0.16
209.0973053	0.16
211.0902863	0.21
211.9732666	0.08
214.2201843	0.04
216.9645996	0.03
227.0066071	0.48
228.0474854	0.73
229.1931152	1.46
230.4396057	0.37
231.2877045	0.28
235.1116028	0.70
243.0297241	0.13
251.5465088	0.08
253.0190430	0.27
255.1595001	1.02
260.1929016	0.14
269.1581421	0.79
271.0682373	32.70
273.0882568	56.25
274.5272217	0.06
277.3168335	0.06
281.1041260	0.23
282.2998047	0.04
283.1377563	1.21
285.0972900	0.19
285.7633057	0.03
287.5698242	0.19
289.3471680	0.09
292.8174438	0.05
295.4044800	0.13
303.1822510	0.04
309.4717407	0.13
310.2341003	0.14
311.9789429	7.48
313.1051636	9.69
314.0244141	0.04
315.2067261	0.36
317.2322388	0.09
319.2589722	0.06
320.4145508	0.13
321.1547241	0.04
323.2352295	0.64
325.1030884	0.08
335.2406006	0.37
336.1425171	0.38
337.1674805	1.01
338.0890503	0.28
339.4533691	0.12
345.2221680	0.05
346.3804321	0.10
348.4007568	0.04
349.4371338	0.04
351.1574707	0.09
355.0801392	0.40
357.3258057	0.17
363.2333984	0.75
364.3420410	1.10
365.2685547	2.11
367.1826172	0.21
375.2444458	0.88
377.2482300	1.02
379.2129517	0.12
381.3387451	2.56
382.3051147	5.22
383.2113647	1.31
389.3283691	0.21
391.1845703	8.22
393.2174683	0.04
394.5498657	0.73
395.2509766	0.77
399.3950806	0.03
401.2543945	1.23
403.3088989	0.27
404.4841919	0.05
407.2428589	0.67
409.1337891	33.31
409.8532715	0.05
411.2443848	0.13
415.2767944	0.10
417.2510986	0.68
419.1410522	100.00
420.2520142	0.25
421.3013916	0.06
422.9780273	0.04
424.3604126	0.56
425.3616943	0.15
433.1857300	0.08
436.2966309	0.35
437.2418213	0.06
438.2029419	0.17
439.3522339	0.09
441.3129272	0.08
443.0068359	0.11
451.0130615	0.12
454.1735840	0.13
457.1703491	0.15
459.1671143	0.15
461.1838989	0.23
462.3856201	0.09
467.4304199	0.38
470.5534058	0.10
483.2011108	1.43
485.3601074	0.24
498.7764282	0.03
501.1184692	4.25
501.9440918	0.06
509.2329712	0.56
527.2133179	20.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2145
Annotation	Unknow
Peak:m/z	Relative Intensity
340.5430908	1.25
383.0382080	1.63
407.4367676	1.26
444.2224121	0.27
469.3878784	0.45
503.1746826	100.00
504.2874146	1.97
529.2078857	0.73
604.5117188	0.45
632.1092529	3.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1348
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1833649	0.10
175.0284729	0.17
176.7831116	0.08
182.9385681	0.05
184.9018097	0.05
187.0532837	0.32
198.9876099	0.04
201.1882629	0.02
202.4203491	0.22
203.1711273	0.19
204.9839478	0.33
211.1152496	0.03
212.0794373	0.15
225.1268158	0.06
227.2353821	0.14
228.9750824	0.05
229.9915161	0.07
231.0402222	0.06
243.2658081	0.52
245.0367432	3.11
247.2280884	0.09
253.2262268	0.06
255.1265564	0.17
268.9697876	0.72
273.0588989	2.26
278.8515015	0.05
283.3254395	0.13
285.1163635	0.17
287.1520996	8.93
289.1873779	20.81
293.3845520	0.21
299.1412048	6.32
301.0898438	0.10
305.1364136	0.13
313.2864990	0.31
315.1076660	0.03
327.2460327	0.14
329.0054932	0.63
331.0515137	0.71
339.1861572	0.31
341.1633301	0.29
353.1433105	0.29
357.4243774	0.06
363.3930054	0.03
368.2536011	0.06
369.1433105	0.11
371.4351196	0.04
375.1051636	0.15
379.2990112	0.09
381.2391357	1.96
388.9566650	0.05
393.2312012	0.36
396.1503296	0.07
405.1607666	0.02
407.1472778	60.23
407.7608032	0.19
408.3739624	0.06
409.2142334	0.73
410.1191406	0.15
411.1177979	0.20
415.3946533	0.02
423.1034546	0.64
425.0947266	100.00
433.2672119	0.66
436.8622437	0.37
439.2427368	0.61
449.0970459	0.68
451.0972290	30.85
451.9274902	0.01
467.1699829	1.72
491.0232544	0.20
493.3634033	0.05
495.5005493	0.11
497.2837524	0.17
515.3057251	0.37
533.2310181	1.68
541.2993164	0.46
559.2061157	13.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1816
Annotation	Lychnose
Peak:m/z	Relative Intensity
381.0781250	0.07
483.1716919	0.18
525.0789795	0.43
543.1952515	100.00
544.1886597	0.36
615.3852539	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1816
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.8878784	1.54
118.9571228	2.14
124.8527985	0.23
130.9639893	1.06
143.0569153	2.71
147.0987701	3.29
148.0461426	0.32
148.9196777	0.74
160.9268188	0.43
163.2967529	2.80
164.2766113	0.40
165.1807861	2.48
175.1536255	0.14
178.9619293	1.44
189.1383820	0.13
191.1244965	8.38
197.2468414	0.10
207.1495361	0.07
209.0722809	100.00
210.1354675	1.23
211.2354279	0.65
227.1582642	3.78
240.2240295	0.13
241.4758911	0.15
247.0877686	0.09
281.3136292	0.22
305.0854492	0.15
327.1665344	0.08
335.3878174	0.16
342.1521606	0.07
371.2096863	20.60
372.0291443	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2911
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.2143250	0.05
154.9448547	0.97
163.1397095	0.20
164.9307404	0.15
173.0395203	0.05
175.3690186	0.09
179.1767578	0.35
179.9095612	0.15
180.8398743	0.06
198.0814667	0.22
216.1257324	1.10
245.2350464	2.08
249.2278442	0.16
253.2508850	0.05
263.3020935	3.96
279.5684814	0.16
283.2111816	0.03
306.4224243	2.31
307.2388611	0.12
312.6187439	0.11
319.4487915	0.25
332.9302368	0.12
337.2969971	75.75
337.9630127	0.13
353.0718689	0.31
361.2763367	0.08
375.3499756	0.16
380.4036560	0.20
399.1571960	0.20
417.2459106	3.65
435.2718811	0.62
442.3227234	0.24
460.1922913	100.00
460.8424377	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	264.0706
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
82.0267487	0.03
86.6755905	0.02
101.9310684	0.70
109.9768066	0.28
116.0776215	0.05
128.0397034	0.29
129.9561462	0.17
138.0011902	0.14
144.0635834	0.27
151.2157288	0.03
151.9289093	0.03
158.0865631	0.49
164.1532745	0.05
166.0419769	0.06
166.9796753	0.05
167.8151703	0.02
170.0053558	0.03
173.9820709	2.58
182.0600128	0.06
184.1169739	0.05
197.9283295	0.34
200.0664215	9.76
202.2283478	0.04
204.4353180	0.02
210.0175476	1.15
216.0256195	0.25
218.0743256	2.79
220.1137848	0.51
222.1407318	0.05
228.0322723	20.61
229.1161499	0.07
244.0445709	0.04
245.9683228	100.00
246.7902985	0.10
264.0456848	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393.2741
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0870209	0.22
132.8961945	7.60
134.9486389	0.12
136.8661194	0.10
144.9251099	0.13
147.0892181	0.06
149.0351868	0.15
150.0219727	0.05
151.0698853	0.15
155.3627930	0.05
159.1188354	0.16
161.2183228	0.07
163.1439819	0.46
167.0851746	0.05
171.9951630	0.26
173.0659180	0.11
177.1214294	0.07
182.1043701	0.15
184.2461395	0.15
185.0603790	0.10
186.0350342	0.04
188.9385223	0.03
191.2035217	0.05
194.1186981	0.25
199.2013245	0.33
201.0377960	0.03
205.2259827	0.10
209.1773376	0.14
212.0780945	0.18
215.0929871	0.13
216.9594269	0.35
219.2482910	0.12
220.9671631	0.02
226.2022400	0.25
228.8858032	0.03
231.1818848	0.05
233.1608887	0.14
236.3035278	0.07
237.9942017	0.17
240.1336060	0.21
241.1873779	0.13
243.2294922	3.38
245.3938599	0.05
248.3336182	0.17
250.1042480	0.04
252.3544922	0.17
253.2279663	0.08
254.0073242	0.31
255.2088623	0.19
257.3275452	0.13
259.2581177	0.14
261.2077637	10.20
264.1101074	0.24
266.2133484	0.38
267.2783813	0.28
268.1173096	0.07
271.0944824	0.27
278.3930359	1.14
279.3198853	0.72
280.2197266	0.78
282.9031067	0.17
285.4031677	0.05
286.9439087	0.13
287.5617676	0.08
288.3939819	0.19
291.1657104	0.06
292.3513489	0.54
294.0757751	0.42
295.3794556	0.27
296.3864441	0.06
297.3437195	0.06
299.0849609	0.31
302.2431030	0.24
303.2824097	0.10
304.5825195	0.15
305.2565918	0.35
306.2258606	0.40
308.4929810	0.23
310.2273254	0.26
312.1699219	0.44
313.2411499	1.11
314.2901306	0.07
315.4516907	0.05
316.2866211	0.25
320.2359619	1.38
321.4109497	0.20
323.2402954	0.67
327.4914856	0.13
328.8379517	0.07
330.2944946	1.83
331.2315063	0.07
332.0522461	0.07
334.1206360	0.66
335.3197327	0.05
337.1305847	0.35
339.1484070	0.09
340.2089233	0.34
341.1992188	0.07
347.6396790	0.92
348.3779602	6.03
349.4529419	0.03
351.4253540	0.19
352.1666870	0.08
357.3229065	0.44
358.3369141	5.96
359.2660522	0.39
362.5548401	0.24
364.5822449	0.16
365.4850159	0.38
369.8876648	0.14
376.2115173	100.00
376.8453369	0.44
384.7865295	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.16
Annotation	Phaeosphenone
Peak:m/z	Relative Intensity
157.0272217	0.17
163.2741241	0.17
167.1232758	0.22
170.9184875	0.61
179.1083221	0.71
181.1299896	0.36
184.9538269	0.48
189.0457001	0.55
191.1593170	0.94
193.1132202	0.26
199.3625641	0.25
202.9136963	0.09
204.9151764	0.24
209.1264038	2.59
212.9810181	1.26
214.7670746	0.11
223.2946167	0.05
227.0648193	0.62
231.0788879	12.10
231.7256317	0.15
233.0517578	0.67
243.0757751	9.24
245.0846100	0.92
251.2097778	0.06
255.1506042	6.36
256.3873901	0.39
257.1510620	1.23
261.2436523	0.13
263.0075684	0.16
267.1109314	1.07
269.0308838	1.24
271.0720215	0.16
273.0311584	28.69
275.0480652	80.03
275.6679077	0.08
285.0805664	20.32
287.1830444	18.00
289.1824341	0.06
297.0210571	0.89
299.1539917	3.05
310.9384155	0.19
315.1119995	0.56
317.1484375	3.35
320.4494629	0.19
323.2682495	0.17
327.0052490	0.20
337.3067017	0.35
339.4164429	0.05
361.3592529	0.56
362.9254150	0.11
370.9918213	1.68
372.8742676	0.13
375.1123047	0.33
379.1370850	14.76
381.0532837	0.16
385.3854370	1.27
391.2803345	1.04
393.1577148	80.21
401.5112305	0.18
403.2169800	4.28
404.0336914	0.70
405.0859985	9.75
407.3009033	0.39
411.0358887	100.00
411.6715088	0.33
417.1366577	0.03
421.1547852	15.94
423.0339966	18.51
426.9296875	0.12
435.0300293	0.35
466.3225708	0.17
469.1946411	0.26
487.3370972	0.35
499.3070679	0.06
502.0404053	0.60
503.3292236	0.32
504.3701782	0.12
511.1339722	3.58
511.9956665	0.13
515.5568237	0.35
529.0800171	14.21
529.8072510	0.04
530.4260254	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2917
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
198.0581665	0.24
215.9201050	0.42
282.3447876	1.45
313.3914490	70.53
331.0293579	0.09
393.1396790	4.35
393.7882690	0.06
410.7716980	0.08
418.2539673	0.32
436.2487488	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
96.99262238	0.04
104.8332214	0.04
113.1833801	0.06
116.8490906	0.08
118.0313721	0.13
130.2545929	0.07
131.9952545	0.08
145.0416412	0.08
146.0079498	0.05
148.9552002	0.17
150.1892242	0.05
153.0788116	0.06
165.1945801	0.10
167.1324615	0.11
168.9964752	0.24
174.0578156	0.18
177.0367737	0.10
178.1054993	0.33
179.0661163	0.41
180.1279449	0.09
181.1540222	0.05
183.0876312	0.09
185.1098938	0.08
190.8808441	0.31
192.9534912	0.10
195.1660004	0.19
195.8284302	0.12
205.1990662	0.06
206.1193542	0.27
207.1582184	1.64
208.1171417	1.68
209.1678925	0.78
222.0283356	1.74
223.0830994	3.72
224.0933075	0.30
231.2219086	0.05
232.1264648	0.13
233.1469116	0.28
251.0656891	100.00
252.1813354	17.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.1552
Annotation	Unknow
Peak:m/z	Relative Intensity
80.0178986	0.24
80.9807510	0.33
83.1054306	0.06
83.9077148	0.30
85.0345993	2.50
87.0462418	0.26
93.0261841	0.20
95.0432129	4.21
97.0087433	8.85
100.9734955	0.76
107.0449677	1.59
108.0628967	0.47
109.0714569	3.79
111.0592346	15.69
112.9894409	6.32
114.9775696	17.34
120.9875183	0.72
122.8850250	1.40
124.4683075	0.72
125.0822449	3.42
127.0561981	18.74
129.1380463	1.04
132.9798737	0.26
137.0603485	16.66
138.4375000	0.23
139.0857544	2.72
140.5436096	0.16
141.1449738	4.21
143.1160889	0.54
143.9705353	0.28
144.9748993	0.18
147.0960236	0.11
149.1131439	2.01
150.9374237	7.43
151.6338654	0.12
153.1593475	0.82
154.9777222	100.00
157.0578613	13.83
159.1471100	0.53
163.0688477	0.88
164.0456085	1.96
165.0841217	1.37
166.9741974	1.96
169.0277710	1.90
171.1819916	0.05
173.1263885	1.97
175.0243988	0.23
177.1288605	3.88
179.2086029	0.66
180.1032257	0.75
181.2069244	0.59
183.0588531	0.46
185.1381531	1.43
187.2061920	3.03
189.1072845	1.34
191.1832428	44.49
192.3120575	0.11
195.0684052	19.19
199.2203369	2.97
203.2017517	0.52
207.2132111	2.20
209.1892395	3.82
210.8971100	0.13
213.1685638	11.72
215.0652466	0.40
217.0983887	7.12
225.0950928	4.54
227.1986847	2.00
228.1776886	1.74
229.3793488	0.22
233.2152557	0.06
235.1634369	53.25
243.0772858	0.75
250.9007721	1.53
253.1505585	31.49
254.6489258	0.77
255.3027344	0.10
256.1740417	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.19
Annotation	Bis-gamma-glutamylcysteinylbis-beta-alanine
Peak:m/z	Relative Intensity
191.0381165	0.19
193.1832275	0.04
199.0673218	0.12
204.0900726	0.01
207.0055389	0.06
222.9642944	0.02
225.0081482	0.72
230.9655151	0.51
248.3316345	0.18
249.2096863	0.18
265.2044983	0.03
267.2847900	0.08
270.4378967	0.21
276.1792908	0.43
279.5540466	0.03
288.4064331	0.01
294.0153198	0.04
302.2195435	0.16
312.1319275	0.06
335.9948120	0.04
353.8919067	0.03
377.1834717	0.04
383.1572266	99.42
405.2938843	0.13
423.2113037	2.60
445.2947388	0.02
449.1961060	0.02
494.2337036	5.02
512.1614990	100.00
512.7639771	0.44
516.0776978	0.07
533.9434204	0.08
552.1517334	2.72
578.2299805	0.07
605.0823975	0.09
623.1934814	19.66
623.8438721	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1035.6387
Annotation	Unknow
Peak:m/z	Relative Intensity
309.4802856	0.38
441.3242188	1.04
442.5275879	0.27
480.5077209	0.16
500.3662415	37.50
501.4350281	36.10
518.2464600	100.00
519.2423706	75.38
519.9223633	0.19
532.3146973	5.49
533.1728516	5.45
643.2860718	0.90
684.6518555	0.25
689.7538452	0.28
701.2188721	8.63
702.2442627	18.30
785.5296021	0.83
804.6241455	0.46
920.6920166	0.64
944.6157227	0.64
976.9116211	1.61
977.5742188	2.22
1000.5666500	0.30
1018.8459470	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	898.2276
Annotation	Unknow
Peak:m/z	Relative Intensity
258.7179260	0.14
265.2981567	0.11
270.2999268	0.24
284.0200195	0.11
288.0061035	0.06
301.1053162	1.78
303.1455078	2.67
307.1355896	0.15
313.1142578	1.91
319.1328430	0.21
325.1781311	15.70
329.1670837	0.04
335.0509338	0.14
343.1649475	4.86
353.2073975	1.06
365.1673584	0.13
383.2248535	0.37
416.3856201	0.08
443.2169800	0.12
454.2244263	0.98
458.7287598	0.13
461.2369385	0.23
462.5155640	1.17
463.1964111	7.82
466.2042236	0.46
472.1538086	10.24
475.0380249	0.19
479.1802979	1.14
481.0827026	18.01
503.2614746	0.63
505.0881348	0.14
519.3192139	0.21
521.0354614	2.09
521.7706299	0.40
574.3817749	0.64
583.0398560	0.13
590.3469238	0.25
591.2463989	0.30
592.1572876	2.03
598.7732544	0.57
599.7000122	0.19
604.1763306	0.24
608.0452881	3.32
610.1058350	100.00
610.7715454	0.42
617.3774414	0.09
622.3176880	0.07
625.1267700	0.20
626.3070068	0.20
630.7888184	0.59
634.2700195	0.99
643.5521851	0.24
716.3816528	0.10
728.3163452	0.70
730.0560913	0.55
732.9704590	0.56
734.8458862	0.19
735.8201904	0.34
736.5258179	0.64
744.2974243	0.07
745.9691772	0.42
751.0690918	0.35
754.2407837	0.18
760.2116699	0.10
768.9397583	2.79
769.6100464	0.05
772.1791382	0.18
776.8263550	0.15
791.1682129	0.79
809.1882324	0.94
879.9992065	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.2079
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
245.1035461	4.79
247.0730286	7.21
252.9149323	0.16
255.0786133	0.17
257.1042175	0.52
259.0182800	1.79
261.1080017	0.36
262.9085999	0.23
270.1414795	0.31
271.1642456	5.10
272.9925842	0.38
275.1021423	8.17
281.1118774	0.12
282.1815796	0.34
283.0910339	2.60
285.1379089	0.64
286.5455017	0.94
287.1886597	4.75
289.0624084	11.14
291.1481628	2.34
295.3269958	0.14
299.1257324	0.61
301.0250244	3.44
303.0191956	1.36
313.0842896	2.51
315.2549438	0.13
317.0791626	0.57
323.1021423	0.06
328.8734131	0.14
331.1477051	1.17
333.1903076	0.35
341.0590820	0.09
343.2137451	0.10
361.2260742	0.76
365.1098022	0.17
368.8941650	0.16
372.8917236	0.13
375.3145752	0.22
379.5316772	0.54
381.1527100	0.63
383.1360474	0.94
383.8704834	0.11
387.2789307	0.19
389.0976562	1.06
390.6660156	0.09
391.2981567	0.95
393.4033203	0.13
395.1149292	2.11
395.9750977	0.32
397.1499023	15.78
399.7410889	0.20
401.0688477	0.32
403.0713501	0.38
405.3594971	0.62
407.1319580	30.96
409.1106567	19.75
409.7608032	0.05
411.2039185	3.41
415.0908813	2.13
417.1079102	0.81
419.1419678	4.27
421.1661987	1.55
423.4406738	0.30
425.0229492	25.53
425.6725464	0.05
427.0631104	8.97
427.7051392	0.13
431.2949219	0.67
433.1895142	4.74
435.1986084	0.11
437.0844116	11.31
438.9983521	3.03
449.2235718	6.21
451.0711060	11.74
453.2082520	1.78
461.1328125	0.14
464.9616089	0.24
469.0044556	0.56
494.7471924	0.16
504.9176025	0.14
517.2055054	6.02
527.2191772	0.10
529.0827637	0.70
531.2748413	0.17
533.5060425	0.12
535.1810303	10.80
538.9648438	0.72
541.3242188	5.94
542.4508057	0.80
543.2711792	1.98
545.0618896	1.80
547.0460815	0.61
553.3263550	1.35
557.2075195	0.39
559.0482178	19.51
561.0588379	3.45
563.3384399	0.26
568.9978638	1.02
571.1259155	4.63
575.6873169	0.11
576.9707031	100.00
577.6785278	0.09
579.0752563	36.85
585.1353149	0.08
586.9779053	0.17
588.9952393	4.87
589.6099243	0.23
591.1564941	2.40
591.8029175	0.29
595.1825562	0.16
601.3953857	0.07
603.0449829	0.57
605.4710083	0.10
621.0048218	3.48
639.7608032	0.13
657.6707764	0.52
659.2538452	0.39
679.1165161	4.73
681.5801392	0.14
687.2804565	0.18
691.1790771	0.28
697.1965942	27.26
699.1414185	16.25
703.2603760	0.75
704.2142944	4.40
705.1178589	3.62
709.1413574	0.63
711.0161133	0.48
713.0368042	0.51
715.0794678	28.72
715.8778687	0.54
723.1448364	1.44
726.9937134	0.16
729.1918335	0.28
740.1540527	0.21
741.0775757	4.40
802.3222656	0.88
813.0580444	0.56
830.8913574	1.04
848.3806763	0.18
848.9882812	6.03
849.7694092	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.2901
Annotation	Unknow
Peak:m/z	Relative Intensity
114.4497375	0.02
115.9815369	0.07
118.9363251	0.11
128.9945984	0.03
132.9850311	9.94
135.3017731	0.06
141.1380005	0.03
144.7781067	0.04
150.9908142	0.04
153.1039886	0.06
167.0177002	0.12
177.1262970	0.03
191.7803040	0.03
238.9526978	0.39
241.3468628	0.02
243.2610779	0.03
251.3607178	0.09
269.2318420	0.09
275.1085205	0.05
276.2552490	0.03
283.9127502	0.03
286.1428223	0.02
307.4582520	0.09
308.7893066	0.29
313.2493896	0.06
325.2711182	0.11
326.0750427	0.13
329.2816772	0.11
335.3612671	0.24
336.1979370	0.06
340.0601196	0.02
343.0355835	0.05
349.5062256	0.15
353.5038757	12.53
354.2194214	100.00
354.8581238	0.31
361.9707336	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.2912
Annotation	Unknow
Peak:m/z	Relative Intensity
239.1599731	0.09
255.0841980	0.07
273.3280029	0.26
275.3743286	0.75
277.2864685	0.08
283.3865051	0.05
285.5827332	0.10
293.4122925	0.04
303.1575317	0.32
315.2501221	0.15
319.4598389	0.39
321.4172363	0.06
333.3657837	2.08
335.3031006	0.04
337.4052734	0.07
343.2259521	1.26
347.2640991	2.94
361.3589478	0.43
365.3248291	100.00
369.6254883	0.04
371.1665649	0.06
374.4759521	0.10
377.1256104	0.06
379.4292603	0.17
383.0322266	0.06
387.3228149	0.14
389.2158203	2.30
391.3780518	0.31
399.2167969	0.27
401.2295532	0.27
403.6019897	0.05
405.2033691	0.13
407.2661743	18.02
415.5129395	0.04
419.3987427	0.62
421.3967896	0.12
431.3927002	0.40
437.3104248	0.99
447.3607788	1.63
449.2304077	0.97
466.9547729	0.26
479.5230713	0.05
489.4813843	0.03
491.3018188	1.28
500.9379272	0.10
509.2670898	27.70
527.2200928	58.83
563.6909180	0.18
565.4301147	0.18
569.1650391	7.78
604.2219238	0.15
604.8701782	0.05
609.2844849	2.03
611.0039062	0.31
621.0730591	0.08
627.2492065	26.26
628.7639771	0.04
653.2376099	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0672
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
110.9506073	0.49
114.9156647	0.07
127.2315369	0.06
127.9221420	0.04
129.0383301	1.61
147.0390778	4.21
161.1684570	0.05
162.9868927	1.11
165.0968781	0.03
172.9864044	3.26
191.0350189	100.00
192.2099915	0.21
193.2393951	0.38
209.0176392	40.82
209.6195374	0.14
231.2455139	0.04
249.0527954	0.05
269.2561035	0.06
291.0184326	0.03
293.0171814	0.36
311.2030029	0.10
313.7615051	0.03
328.0848389	0.04
337.1420898	11.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.1313
Annotation	Microphyllaquinone
Peak:m/z	Relative Intensity
128.8653412	1.51
145.0788879	1.59
148.9691315	0.16
171.4648438	0.06
174.9094543	0.17
177.0108643	16.31
183.9401855	0.08
193.0466003	6.16
198.9814148	0.43
201.0670319	0.97
201.9725647	6.93
219.0703430	1.02
228.9728699	1.15
247.0575562	100.00
261.2431641	0.06
265.0991516	2.85
287.3135376	0.16
290.8675537	0.13
297.4075317	0.13
306.0565491	10.23
311.2160034	0.04
319.2373657	0.19
324.1697388	0.53
325.2136230	0.19
330.9026489	0.24
370.6318054	0.46
378.7682190	0.09
381.4870605	0.19
392.8020325	0.06
394.9879150	0.18
404.0699158	0.23
423.0375671	4.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0854
Annotation	Gerfelin
Peak:m/z	Relative Intensity
94.9764252	0.11
104.8801117	0.18
106.9225998	0.69
109.0749664	0.18
110.9144669	0.15
119.0570679	0.37
122.9396820	100.00
123.8089600	0.47
127.0150604	0.81
133.1574554	0.20
135.9969635	0.13
136.9961243	0.29
139.0106506	97.48
139.9340210	0.21
147.0344849	7.49
151.0381470	28.06
153.1603546	0.67
155.0502319	1.83
162.0744019	0.38
164.9654999	43.22
168.9385986	2.01
169.7585754	0.08
171.2004089	0.06
175.9368896	0.06
181.0141754	0.65
184.2118835	0.19
185.0141449	0.04
190.9786377	0.12
201.0537720	0.05
203.1765442	0.06
205.1838379	0.23
210.0472107	0.08
227.1347046	0.19
227.9392700	0.14
229.0030518	0.22
231.0113831	0.20
245.2283325	0.16
249.1536255	0.83
249.8980103	0.04
255.1827698	0.44
259.0692139	0.22
261.8429565	0.19
272.9735413	32.51
273.5965271	0.18
281.7982178	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	800.26
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9854279	0.28
259.2874451	0.19
271.1071777	0.62
277.5577393	0.55
288.3654785	2.82
289.1217651	0.60
295.0607910	1.77
295.8779297	1.32
305.3179321	0.90
307.0478516	1.93
307.9107361	0.23
324.2888794	8.79
324.9617920	44.41
325.9199219	5.77
339.5732422	0.67
342.9094238	10.45
385.2583618	0.45
450.7238770	0.64
456.9267578	0.21
457.9539185	0.31
474.8308105	0.60
486.8443604	100.00
488.0164795	8.15
503.2259521	0.50
504.1768799	7.60
504.8796387	30.44
505.8582153	4.00
601.0309448	0.19
619.5488892	0.40
620.2572021	0.63
637.2270508	26.82
638.1262817	25.24
666.8313599	0.99
763.8001099	0.39
782.0845947	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.27
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
190.1791382	0.03
193.4626312	0.08
208.0528412	0.26
208.9315643	0.04
219.1184692	0.05
223.1157684	2.75
236.1753693	0.04
239.2662964	0.02
241.1940765	0.06
243.1306915	0.01
245.0149384	0.05
256.3198242	0.01
257.1387939	0.01
259.1142883	0.12
260.2827759	0.05
265.3757935	0.03
269.0859680	0.01
273.2748108	0.05
285.1763916	0.08
287.0007935	0.12
289.1214600	0.05
295.1969910	0.05
301.4122009	0.04
302.7404785	0.05
304.1282654	0.01
305.2687378	0.05
313.2678223	0.38
316.4827881	0.05
319.2291260	0.36
319.9053345	0.03
323.1541748	0.12
324.4517212	0.05
327.1895752	0.15
328.1891479	0.09
330.0716553	0.04
331.4674377	0.01
333.3034058	0.31
334.3636475	0.37
335.3243408	0.58
336.3977051	0.26
337.3637085	0.07
339.0881348	0.02
352.0549927	0.02
355.2247314	0.32
357.3218384	0.01
358.0219116	0.04
368.0385132	0.05
369.3518066	0.19
373.2042236	0.07
386.9932251	0.03
392.1641846	0.40
399.6444702	0.03
401.3003540	0.04
403.2070312	0.23
411.3867798	0.03
434.1765747	0.12
437.6193848	0.03
439.2224731	0.04
446.3900757	0.06
449.2591553	0.25
451.1510620	0.82
456.2448120	0.05
459.8877563	0.09
462.2155151	0.13
476.2923584	0.07
480.0814819	0.05
498.4573364	0.05
503.1793823	0.25
506.5935059	0.03
509.9330444	0.14
513.2240601	0.06
517.0999146	0.01
520.8438721	0.02
522.3423462	0.04
523.2391968	0.15
525.4141235	0.03
531.1875610	0.20
538.2343750	0.05
539.3057861	0.41
543.5645142	0.02
544.5772705	0.02
549.0347290	0.03
551.3663940	0.09
552.4188843	0.02
555.5390625	0.05
557.3955688	2.33
558.2147217	0.06
563.4619141	0.03
569.3009033	0.20
570.3032837	0.03
571.3845825	0.13
575.2660522	0.05
581.3747559	1.12
583.3192749	0.91
585.1297607	0.13
593.7943115	0.04
597.8185425	0.08
599.2968140	59.75
599.9226685	0.22
601.1486816	0.40
602.3649902	0.54
603.4833984	0.15
604.8495483	0.01
612.8487549	0.13
613.4978027	0.07
615.1509399	0.41
625.2953491	0.42
626.9965820	0.52
627.8862305	0.06
629.1719360	0.14
631.0689697	0.64
631.6876221	0.27
632.4439087	0.08
638.1215210	0.07
639.1937256	0.26
643.2084351	100.00
643.9649658	0.23
646.3963013	0.01
647.2861938	0.20
651.6563721	0.29
652.3280640	0.02
653.1577759	0.04
656.6948853	0.23
657.3332520	0.57
658.2883301	0.02
721.7078857	0.03
739.1919556	0.02
941.6801147	0.25
942.7948608	0.25
969.5559082	0.09
970.7118530	0.08
1052.4196780	0.12
1067.7326660	0.02
1089.8349610	0.03
1092.3947750	0.02
1126.3996580	0.05
1127.7136230	0.03
1225.2919920	0.02
1273.5703120	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	431.1172
Annotation	Bispyribac
Peak:m/z	Relative Intensity
125.9582977	0.07
126.7751923	0.14
130.0197144	0.37
137.0539246	0.49
140.9968719	0.98
144.8869019	0.59
151.2897949	0.24
159.1322479	0.18
163.1979218	0.06
164.9189148	4.56
165.5596771	0.05
175.1260071	0.07
176.8423767	0.19
178.9897156	0.10
181.5081787	0.08
182.9840393	73.98
186.9503174	0.18
187.9520264	0.16
189.0676575	0.06
193.2368164	0.41
195.2735596	0.19
198.8833923	0.14
203.0731812	0.27
207.0044556	20.98
209.3093872	0.17
213.0310516	0.11
216.6947937	0.06
217.8479767	0.25
219.0184326	0.09
221.0869751	0.22
225.0375366	34.72
231.0154114	1.45
237.1071167	0.07
243.2451172	0.06
244.1939392	0.37
249.1264954	21.39
255.1713867	0.70
259.0842896	0.08
261.2747803	0.11
268.1753235	0.09
268.9273376	0.53
271.1640320	0.07
273.1067200	2.73
277.3521729	0.12
282.4298706	0.16
283.2814026	0.05
285.0596313	0.13
286.1438599	0.22
287.1594238	0.26
291.0242920	16.05
292.4423828	0.03
302.4496155	0.15
309.0916443	0.38
312.0691223	0.04
313.1387634	0.09
315.0305481	0.11
320.8019409	0.08
325.2968750	0.54
326.9004211	0.29
330.9813843	0.30
333.1002197	0.91
335.0010986	0.29
343.2859802	0.09
345.0814209	0.41
346.9154053	0.06
349.5704346	0.09
351.1702881	0.91
358.9650879	0.50
360.8412476	0.05
369.5564575	0.53
370.1748352	0.26
371.0135193	0.20
377.1461487	5.40
381.3476868	0.04
383.3705750	0.11
385.1835632	0.34
386.2758484	0.26
395.1597595	37.31
399.0097961	0.19
400.2235413	0.15
402.0585327	0.07
403.2616577	0.32
404.3430176	0.46
413.0196838	100.00
413.6732483	0.35
414.5658875	0.04
415.8561707	0.12
422.2527771	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2105
Annotation	12-OPDA
Peak:m/z	Relative Intensity
90.9852829	0.05
93.00901794	0.07
95.00926971	0.29
96.96412659	0.15
101.0125732	0.16
104.9829559	0.25
106.9570923	0.24
109.1656647	0.10
111.0430298	0.17
117.0637131	0.24
119.0968018	0.22
119.8201294	0.02
120.9508362	0.26
123.0863647	0.22
125.0025024	0.16
126.9878235	0.02
129.0471191	0.12
130.9613647	0.40
132.8946228	0.42
135.0314331	0.31
135.6882019	0.02
137.0885162	0.52
138.9920502	0.32
142.9001465	0.06
143.9522705	0.04
144.9632263	0.83
147.0438538	0.71
148.4617615	0.09
149.1362	1.40
151.068573	0.37
153.0529785	0.08
155.1172485	0.15
157.1117859	0.36
159.1070862	0.97
161.0772095	0.76
161.7140808	0.03
163.0735779	0.77
165.0081787	0.78
169.0076904	0.49
171.0122986	1.18
173.1619263	0.93
175.0945892	0.30
177.2112427	0.20
179.2381439	0.35
181.0158691	0.09
183.0476379	0.23
185.0137634	0.20
187.1253967	1.12
189.1464691	0.29
191.0341797	0.29
193.0837708	0.33
194.7914429	0.03
195.3980865	0.06
197.2046204	0.61
199.1642151	0.26
201.1769104	0.40
201.9214172	0.03
203.3182678	0.16
205.1957397	1.39
207.2325439	0.15
209.2234802	0.07
211.0936279	0.51
212.999176	0.14
215.1600952	0.22
217.0780334	0.21
219.2155457	0.41
221.0502319	0.07
223.1035156	0.47
224.7741699	0.06
227.2042542	0.07
229.2547302	0.77
231.20401	0.07
233.2081299	0.19
235.1548767	0.92
237.1374207	0.19
239.2315979	1.75
247.3215942	0.48
249.1728821	0.29
251.3110352	0.07
253.2731628	0.12
257.1704407	4.62
265.3061523	0.13
266.9739075	0.04
275.1914062	100.00
276.175415	0.02
302.3966064	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Unknow
Peak:m/z	Relative Intensity
97.1866531	0.17
99.1519852	0.63
100.9833984	6.62
102.8191528	0.19
105.4894257	0.15
106.2812347	0.08
113.0147247	24.54
114.9160156	0.75
117.6800232	0.10
118.8876495	16.39
124.9294815	2.89
128.2541504	0.31
130.9235840	8.29
143.0503998	25.85
148.9292908	3.63
159.0949707	0.31
160.9893951	22.81
178.9159851	100.00
191.1188965	0.38
209.0856018	0.41
212.1228027	0.08
221.0421753	0.14
226.1166992	0.41
228.1396179	0.44
280.5209961	0.66
281.1250000	2.18
283.2784424	0.30
292.9235229	0.60
295.3859558	0.43
297.0045776	0.64
304.8526306	0.19
322.2024231	0.13
323.2134705	1.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	354.1901
Annotation	Sarracine N-oxide
Peak:m/z	Relative Intensity
100.9953461	0.02
103.0066223	0.11
104.0136108	0.09
110.2111053	0.01
118.1386261	0.01
120.0015564	0.04
121.2641449	0.02
128.0233765	0.24
130.7055206	0.03
132.0269470	0.21
135.0378571	0.12
150.2145081	0.02
155.8975830	1.25
162.9598694	0.34
171.1163330	0.03
173.1206665	0.02
174.8591156	0.05
177.2342377	0.01
181.1394958	1.79
198.0367279	0.03
201.2034302	0.01
205.0715790	0.81
206.5541382	0.02
208.4314575	0.04
210.2341919	0.06
215.3081665	0.02
216.0605469	0.09
217.0093689	0.04
225.1742249	0.06
230.1891479	0.06
238.1304016	0.13
238.9998169	0.10
251.3957825	0.03
256.2880859	0.06
257.1697388	0.04
262.3353577	0.02
265.1623230	0.09
266.0990295	0.04
268.1597290	0.02
270.1875000	0.03
272.7947998	0.03
278.3072510	0.04
280.2639160	0.06
282.0069885	0.05
283.1316833	0.02
284.3974304	0.02
286.1850891	0.07
289.4185181	0.06
290.1783142	0.67
292.4416809	0.12
293.4883118	0.05
294.3533936	0.02
296.2974243	0.14
300.4196167	0.02
304.5601501	0.03
308.1264343	21.95
309.3602905	0.02
310.2634888	0.02
313.1985779	0.05
318.3190918	2.16
319.5776367	0.05
321.0827637	0.04
324.1803589	0.12
326.3334961	0.15
329.6583862	0.04
331.4190063	0.02
332.7663269	0.05
336.1071167	100.00
337.3552246	0.20
354.5401611	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.1281
Annotation	L-gamma-Glutamyl-beta-phenyl-beta-L-alanine
Peak:m/z	Relative Intensity
93.0205994	0.05
102.9890289	0.34
115.2416687	0.03
120.0648804	19.62
130.0161285	0.10
130.9912720	0.29
135.9132843	0.13
137.0212708	0.02
139.9599304	0.03
148.0027161	0.11
148.9978027	0.61
150.0654602	0.82
150.9530182	0.04
156.9645081	0.01
162.2065735	0.02
165.9865723	100.00
170.4238586	0.03
201.0386658	0.04
206.7465210	0.02
214.7169495	0.02
223.2166748	0.07
230.8793640	0.01
232.0480347	1.10
237.1460266	0.07
240.9697876	0.04
248.5115967	0.08
249.1222534	0.39
250.1468811	0.04
259.1309814	0.39
260.2657166	0.02
270.2198792	0.03
271.7175598	0.10
277.0576172	2.07
278.0847473	6.79
278.6911926	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.1035
Annotation	Luteoskyrin
Peak:m/z	Relative Intensity
161.0091400	0.06
163.0317383	0.07
164.2082672	0.03
165.0485840	0.02
177.1747284	0.02
186.2196350	0.03
215.1925659	0.02
218.4119873	0.02
220.4299622	0.02
225.0867920	0.01
229.1802063	0.01
231.1386414	0.03
235.1780853	0.03
236.1576691	0.02
245.0479584	0.04
255.3896179	0.02
257.1798096	0.07
273.1456299	0.07
283.0590820	0.05
289.1752319	0.35
297.0147095	0.01
299.1111450	0.01
300.3295288	0.02
301.2403870	0.24
305.2911987	0.03
309.0632935	0.05
311.1058960	0.02
314.1785278	0.01
316.1773682	0.05
319.1740723	0.07
325.1445923	0.06
325.8571777	0.01
327.1647339	1.82
341.2006226	0.10
343.5238647	0.03
348.9851074	0.02
351.2044067	0.06
353.1582031	0.07
354.2921143	0.04
355.2027588	0.02
365.2100830	0.08
369.4696045	0.06
379.2373047	0.06
381.5030518	0.04
388.4712524	0.02
391.2598267	0.06
392.3843384	0.01
393.2821045	0.05
403.2681885	0.02
404.1786499	0.01
409.2470093	2.41
411.3713379	0.03
417.3594971	0.04
419.2365112	0.12
421.0917358	0.10
423.3350830	0.01
428.9215088	0.10
435.1928101	0.75
437.1041870	0.33
439.5106201	0.01
441.5811768	0.01
447.1211548	3.70
447.7350464	0.04
450.2255859	0.01
451.0385132	0.04
453.0869141	100.00
454.4075928	0.02
463.1765747	0.03
478.4808960	0.02
486.9732056	0.06
489.4331055	0.06
492.7168579	0.03
504.9674683	0.09
511.4387817	0.03
512.1998901	0.01
513.3742065	0.09
523.1387939	0.19
524.8950195	0.02
527.2167358	0.13
529.1651001	0.75
530.6626587	0.03
534.8248901	0.02
537.1266479	0.23
541.2836304	0.52
542.3865356	0.12
545.2296143	0.15
551.1398926	0.09
554.2906494	0.13
555.2272949	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2886
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
170.9098969	0.91
200.8962860	0.13
205.4126892	0.14
223.0222626	22.78
240.9941101	54.16
259.0921326	1.60
279.3226929	33.56
280.3386841	0.54
315.1579590	100.00
333.0796509	7.71
353.2658691	0.82
380.0996704	0.10
415.2320557	1.94
433.0048828	0.66
463.2125244	0.14
531.0606079	3.98
549.1652222	0.39
551.7075806	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1481
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.0451355	0.23
165.0107269	0.74
172.9616547	0.20
179.0356140	0.26
180.9231567	0.10
183.3179321	0.16
187.0798340	0.54
191.1558990	0.17
193.1419373	0.19
201.1682587	0.46
203.0310974	0.06
204.6199036	0.11
217.2813568	0.16
218.9566040	0.19
224.9682922	0.23
229.1318970	1.57
231.1507263	1.09
232.9946594	0.66
243.1367493	0.80
247.1137695	21.51
248.2217255	0.11
251.1735992	0.12
255.1607361	0.10
259.0756836	5.47
261.1216431	0.84
265.1247253	0.19
271.1197510	6.74
273.0239258	1.44
275.1012573	6.57
281.2584839	0.09
283.0902710	3.34
285.0828247	1.44
287.1500854	3.43
289.1281738	21.32
291.0686035	52.49
295.0488281	0.81
297.2878418	0.22
299.1801758	2.01
301.0341797	21.02
303.2133179	4.49
309.3588867	0.38
310.8448792	0.26
311.8544312	0.25
313.1611938	0.17
315.2684326	0.94
319.1568604	0.32
322.0010986	0.16
323.0473633	0.07
325.8275146	0.26
333.3032837	1.27
335.4829712	0.27
353.2442627	0.97
365.2631226	0.14
369.0627441	0.08
381.1875610	0.12
393.0887451	2.22
395.3049316	0.44
397.3540649	0.74
399.2014771	0.08
403.1251221	0.29
405.1820679	0.24
406.9861450	0.22
409.1174927	52.75
409.9273682	0.04
411.2077026	9.52
412.2460938	0.35
417.1513672	0.28
418.9802856	0.08
421.2350464	3.66
423.2757568	0.16
424.2572632	0.33
425.1384277	1.13
427.0539551	100.00
427.6824341	0.44
432.9512939	0.39
434.5019531	0.49
435.1400146	5.41
436.3697510	0.50
437.0858765	0.26
439.1106567	5.28
439.9496460	0.05
441.0906372	2.12
443.2153931	0.62
445.3451538	0.14
448.0907593	0.05
449.2606812	0.66
450.3204346	0.09
451.1632690	0.09
452.9774170	11.04
453.7692871	0.18
459.2754517	0.46
463.0743408	0.07
474.3544922	0.23
490.2466431	0.17
512.8923950	0.17
533.3136597	0.29
535.6278687	0.34
536.8864136	0.30
543.1611938	4.13
560.5192261	0.78
561.1441650	17.00
562.3075562	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9582
Annotation	Unknow
Peak:m/z	Relative Intensity
127.8990326	0.12
142.1445770	0.37
155.9992065	0.84
162.0358582	0.19
170.0857391	0.75
183.9308472	0.44
191.0838470	0.24
198.0411377	0.05
199.8930054	21.78
201.0278625	0.73
213.9269562	5.57
217.8474121	0.49
228.1063385	0.24
242.0916138	0.11
243.9211731	7.37
245.8366394	0.34
255.9641724	0.07
257.9592590	70.13
259.9928894	0.08
261.9304810	2.17
268.0114136	0.05
279.2154846	0.06
282.2683105	0.11
284.0997925	1.18
285.2933044	0.26
285.9353027	3.51
287.4244385	1.98
288.0590210	7.10
289.8765869	2.43
299.0544739	0.14
300.0966797	0.15
301.8090820	39.51
302.5022583	0.06
303.9795532	1.67
313.9171143	1.43
320.3515625	0.27
324.8851624	0.09
327.9752808	2.70
329.6456909	7.52
330.3377075	0.03
331.8718872	100.00
332.5216064	0.20
335.1337280	0.06
345.2421570	3.20
345.8926086	19.15
347.9734192	1.81
358.0286255	0.41
372.1774597	0.12
373.7188110	3.67
374.4261780	0.03
375.9266052	0.34
390.4917908	0.04
392.0067444	32.43
399.8757324	2.64
417.8923645	59.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	513.2682
Annotation	Cuniloside
Peak:m/z	Relative Intensity
145.1734161	0.09
153.2200775	0.41
159.1827240	0.11
164.7323761	0.48
167.0228119	0.38
183.0620575	0.16
189.1737213	0.16
190.9245300	0.21
195.0360260	1.25
197.1556854	0.54
198.8361511	0.32
199.4455872	0.18
201.0691681	0.78
205.0538330	0.29
207.0409241	0.47
209.1579895	0.61
216.9497528	0.11
227.0016022	0.48
236.9929047	0.30
239.0411072	0.09
241.2092438	1.67
243.2260590	0.28
247.5212097	0.32
250.9257965	1.19
251.5891113	0.05
253.3163300	0.07
257.1518555	0.29
259.3219604	1.77
261.4279175	0.21
269.1802979	5.06
269.8462524	0.06
275.3713989	0.07
285.1758423	0.48
287.2200928	8.67
289.2741699	0.28
297.0799255	2.71
303.2120972	0.23
305.2340088	2.43
307.3352661	0.25
314.5091553	0.71
315.2731323	21.36
321.2075195	0.08
326.9476318	0.12
331.2158813	0.34
333.1885986	52.98
335.2966919	2.98
349.2013550	0.78
351.1649170	100.00
351.7703247	0.30
369.1542969	1.07
375.3368530	0.13
379.3413086	0.17
383.3767090	0.24
384.2164917	0.06
390.9183960	0.19
395.5545654	0.20
409.0622559	0.11
411.1400146	0.52
421.1539917	0.24
430.9862061	0.11
435.3924561	0.23
459.6164551	0.13
467.4715576	0.25
469.4327393	0.03
485.5995483	0.24
495.2128906	9.92
503.8363037	0.26
505.3977661	0.07
515.2645264	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.273
Annotation	Unknow
Peak:m/z	Relative Intensity
446.4828491	0.03
483.3729858	0.07
521.4118042	0.03
544.3515625	100.00
545.7029419	0.50
546.8926392	0.18
547.5540161	0.02
548.4061279	0.07
552.9697266	0.02
554.3131714	0.04
562.2727661	0.01
657.9098511	0.05
747.4263306	0.02
765.4938965	0.04
795.2092285	0.06
799.4472656	0.04
883.6027222	0.02
909.4246216	0.30
910.4624634	0.06
927.4971313	1.89
928.5689087	0.55
1089.2294920	0.30
1089.8933110	0.17
1090.5241700	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	662.2968
Annotation	Unknow
Peak:m/z	Relative Intensity
213.9257660	0.08
224.2652283	0.21
245.2070770	0.11
262.0759888	0.06
268.3044434	0.03
286.1533813	0.27
289.4803467	0.23
295.2144470	0.23
320.3066406	0.14
337.4727783	0.14
350.3216553	0.37
356.6082153	0.33
372.1574097	0.11
376.3411865	0.08
446.3786621	0.06
452.4461060	0.15
468.2766724	0.11
469.4678345	0.14
482.3653564	0.04
487.4930420	0.09
510.2853394	0.26
517.3644409	0.16
532.0673218	0.05
533.3948975	0.80
549.3240356	0.10
552.1740112	0.11
554.1494141	0.16
559.6538696	0.42
596.4222412	0.80
597.5239258	0.08
602.6245728	0.09
616.0144653	0.59
616.7035522	0.07
618.1423950	0.24
624.6581421	0.24
626.0914917	0.09
639.3197632	100.00
640.4923706	0.84
641.6243286	0.61
643.2047729	0.08
644.1898193	0.58
647.1563721	0.10
651.2244873	0.07
757.4791260	0.14
937.4789429	0.25
955.6007690	0.23
1055.5766600	0.27
1099.6385500	0.23
1117.4368900	3.53
1265.1158450	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	955.99
Annotation	Unknow
Peak:m/z	Relative Intensity
297.1575012	0.69
320.4621277	0.60
323.5434570	1.58
338.3629150	1.67
391.3681030	1.69
392.6462402	2.76
407.3514404	2.43
408.5906982	0.88
409.6842651	1.65
410.3351440	1.16
411.0542603	1.11
419.1746216	1.55
423.6483765	3.78
435.3446045	20.44
436.4534302	6.55
453.6217041	0.98
455.3322754	32.30
456.3184814	9.12
480.9909058	0.63
491.2900391	0.55
495.2611084	0.60
523.4261475	100.00
524.2886963	21.74
525.0633545	5.33
551.5746460	9.00
569.3945312	1.11
595.3663940	39.15
596.4111328	15.38
613.4981079	39.25
614.3600464	14.95
631.4729614	14.15
731.0401611	3.61
731.8113403	18.28
732.6981201	3.38
749.1828003	7.32
775.2135620	3.40
776.5514526	5.08
793.4118042	25.68
794.5863647	26.72
866.5375366	1.43
893.3648682	25.85
894.5508423	5.08
937.3696899	64.04
938.2214355	25.51
938.8616333	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.2693
Annotation	Docosanediol-1,14-disulfate
Peak:m/z	Relative Intensity
169.0117035	0.07
197.4009705	0.17
198.1193848	0.11
199.0300751	0.06
214.9845276	0.13
225.0480957	0.21
226.1308899	0.07
227.2106018	0.06
240.1369019	0.10
243.2013245	6.97
244.1651154	0.65
261.1732788	16.34
292.9204407	0.02
310.1742554	0.10
311.3360596	0.01
320.8595886	0.01
327.5146484	0.19
328.2790833	0.58
338.2448730	0.18
339.1726685	0.49
354.2723694	0.19
356.1975708	1.16
357.0174561	0.03
372.4407654	0.14
374.1590576	100.00
374.7658081	0.48
390.3652649	0.04
394.9653320	0.06
421.1130066	0.08
440.0749512	0.38
449.2391052	0.02
467.1484680	0.11
485.2775574	4.17
486.2036438	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.2348
Annotation	L-gamma-Glutamyl-beta-phenyl-beta-L-alanine
Peak:m/z	Relative Intensity
179.0435791	0.37
193.0162048	0.94
209.1851044	0.15
218.9224091	0.10
233.1913757	0.16
235.0608368	0.13
237.2622070	0.11
244.9422150	0.09
250.1202393	0.03
253.1681976	0.09
263.3669128	0.03
313.0127563	0.14
315.1942139	0.18
319.2121582	0.06
333.1743774	0.15
335.2556763	0.10
337.0184326	0.07
340.2511597	0.19
355.0506592	0.19
357.2255249	0.05
366.8795776	0.21
377.2153320	0.21
379.0976562	0.48
381.3197021	0.40
393.2144775	0.11
397.2282715	0.28
399.1971436	3.15
407.2385864	0.42
408.1728516	0.07
418.1201782	0.03
420.0061035	0.48
421.4857788	0.23
423.1319580	0.34
425.3762817	1.50
433.0443115	0.06
441.1472778	0.63
441.7577515	0.19
443.2365723	100.00
451.2686768	0.24
455.3089600	0.22
461.2906494	0.31
483.3709106	0.06
485.2780762	55.56
500.3649292	0.05
501.3859253	0.11
507.3781738	0.08
508.5741577	0.10
511.0711060	0.05
525.2129517	22.81
526.1348267	0.08
527.1688843	1.41
540.3164673	0.05
541.1542358	0.08
543.1970825	0.65
551.0725708	0.29
555.3738403	0.12
559.7135010	0.36
568.2190552	0.03
569.2969360	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.2224
Annotation	7,7-O-Dihydroebuloside
Peak:m/z	Relative Intensity
130.2793274	0.02
132.1363525	0.04
144.1064453	0.07
146.0373993	0.27
151.1753998	0.04
166.0282593	0.02
175.1894226	0.02
188.0623169	2.30
192.1236267	0.03
197.1589966	0.83
205.0243835	9.44
225.0926361	0.22
228.9491272	0.03
243.1707153	24.03
245.4519958	0.01
254.9698181	0.01
261.2432556	0.07
272.2072754	0.09
273.1679077	0.25
278.9808350	0.08
285.2738953	0.06
300.0978394	0.22
316.2981262	0.07
318.1264954	100.00
318.9298096	0.03
324.2890930	0.04
326.8797607	0.10
337.3685608	0.02
342.3579712	0.04
344.8134766	0.03
366.4643250	0.04
370.7630920	0.02
384.2048645	0.10
399.1704712	0.05
401.5993652	0.10
403.2438354	0.05
404.4474182	0.05
409.3372192	0.04
411.3138733	0.01
429.3256531	4.50
430.3721313	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0965
Annotation	Ethotoin
Peak:m/z	Relative Intensity
132.0037842	0.13
158.9115143	0.13
187.9826508	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.14
Annotation	gamma-L-Glutamyl-gamma-L-glutamyl-L-methionine
Peak:m/z	Relative Intensity
122.1470337	0.05
129.8681335	0.71
132.9351807	3.61
147.6784363	0.06
149.9700623	19.29
160.1460571	0.38
184.0513000	0.06
185.9979248	0.06
190.1260376	0.06
192.8193054	0.18
202.1915283	0.39
205.9551239	0.10
207.2576599	0.09
209.8098450	0.07
216.1308746	0.94
230.2252808	0.05
231.0036316	0.10
232.9767151	0.29
234.0610657	0.07
241.3078003	0.34
245.1739807	0.06
250.9799500	0.10
259.1463623	0.84
260.9885254	0.95
262.1171265	1.54
267.2102966	0.24
273.2737427	0.10
273.9620667	0.09
276.9725342	0.30
279.0771484	100.00
279.6941528	0.64
288.0756531	0.15
303.1066284	0.17
318.0793152	0.16
322.1259766	0.30
344.0206299	0.24
345.2735291	1.26
346.9821167	0.15
352.1517639	0.07
354.0443726	0.17
363.4360962	0.75
364.2890930	2.65
365.1665955	0.03
366.8503113	0.24
372.0084229	0.22
373.1695862	0.61
377.1738586	0.53
385.2424316	0.26
388.4010620	0.23
390.1773987	2.93
391.1282654	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	841.3441
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1101227	0.15
246.2402954	0.08
261.1330261	0.09
269.2427673	0.23
281.0879517	0.08
281.8819885	0.15
298.3794250	0.05
299.2748108	0.61
309.3263245	0.06
311.0739136	0.49
315.2763977	0.35
319.0119019	0.07
326.9638062	0.06
337.3262634	0.22
339.2750854	0.06
344.4927673	0.04
350.1477051	0.10
351.0548096	0.07
357.0101318	1.00
359.0134888	0.06
360.8014526	0.13
369.3989258	0.27
371.1872559	0.69
372.8762207	0.15
375.2600708	0.25
383.1990967	0.18
389.2493896	0.07
401.1854858	4.65
404.4381714	0.11
407.3424683	0.40
421.2214966	0.20
433.0585938	0.63
434.1246948	0.17
435.0986938	0.17
437.8840332	0.09
446.2462769	0.21
448.2088013	0.28
450.2223511	0.46
459.2480469	0.18
461.2692261	0.06
462.2030029	0.23
463.1680298	0.15
464.2084961	3.64
464.8124390	0.04
466.3909302	0.29
469.0465698	0.16
472.1487427	0.15
476.0358887	0.09
477.2368774	0.05
478.0790405	0.15
482.2002563	0.40
486.1923828	0.15
490.2252197	2.46
494.3906860	0.44
508.1029053	2.74
510.1718750	0.09
514.2976685	0.50
519.2664795	0.08
522.2178955	5.33
526.2330322	1.15
531.4167480	0.27
532.2954102	0.03
533.5965576	0.19
557.2653198	0.13
569.2766724	0.40
575.5373535	0.28
577.1313477	0.18
583.1376953	0.05
584.8904419	0.14
587.4428711	0.13
601.1567383	0.12
603.2136230	3.86
606.5049438	0.21
608.5763550	0.50
611.3751221	3.71
619.3308716	0.51
624.4019165	0.12
626.1751099	17.11
626.8787842	0.27
629.1858521	5.50
634.3538818	0.22
638.1743774	0.05
643.1033325	4.85
647.2661743	48.09
651.0240479	0.29
652.2785034	25.11
653.3876343	0.19
661.2911377	0.68
663.4703979	0.10
669.6632690	1.65
670.2680054	5.36
672.3829346	0.34
679.2457275	38.04
680.6067505	0.21
684.2474976	42.28
687.1123657	0.18
689.1929321	0.18
705.1176147	0.34
710.0432129	0.07
728.2720337	0.09
747.0711670	0.33
748.6202393	0.09
749.2754517	0.97
765.2682495	1.74
773.3316650	1.16
781.2183228	0.77
787.1491089	0.17
788.3807983	0.10
791.2000122	9.20
791.8452759	0.14
794.7301025	0.15
797.3895874	0.18
805.1130981	2.88
809.2211304	100.00
809.9393311	0.20
813.0676270	0.13
817.6705933	0.32
820.3713379	0.08
823.1124268	2.68
824.1077271	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1250.08
Annotation	Unknow
Peak:m/z	Relative Intensity
423.0885010	0.54
437.1533813	1.35
438.1379700	0.99
474.6346741	0.73
551.5816650	0.46
557.3735352	0.43
569.3293457	6.57
570.4025269	0.91
587.6184082	1.99
611.6695557	0.55
619.4210205	1.14
648.5571289	1.36
655.1502686	3.78
675.7220459	2.31
683.5992432	3.36
684.3955078	0.41
703.7500000	1.98
717.3754883	1.00
745.4196167	2.30
749.4332275	20.37
750.7963867	1.09
775.3800049	1.66
799.6739502	1.51
817.4331055	41.06
818.4009399	13.07
827.5585938	1.51
831.3117065	0.31
832.5843506	0.66
845.3653564	2.60
846.5192871	1.00
863.4729004	24.03
864.2719727	4.75
881.4556885	1.57
889.3615723	100.00
890.3837891	11.12
905.7995605	1.53
907.4649658	40.26
908.4558105	13.15
925.6729736	7.95
926.3918457	3.36
939.4182129	0.53
971.4473877	0.81
1007.4272460	0.34
1025.3908690	43.66
1026.5883790	17.46
1043.3217770	10.65
1044.4196780	4.19
1069.3815920	2.41
1070.6418460	3.56
1087.4182130	46.21
1088.4018550	12.66
1171.4796140	0.71
1187.3797610	44.87
1188.5454100	21.70
1231.3240970	77.77
1232.4114990	27.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1957
Annotation	(1xi,3S)-1,2,3,4-Tetrahydro-1-methyl-beta-carboline-1,3-dicarboxylic acid
Peak:m/z	Relative Intensity
155.8290558	0.06
157.1584320	0.02
170.0057373	0.02
187.1113586	0.48
231.1623688	0.97
275.0037231	51.36
289.0628662	0.02
296.3615112	0.07
297.1082764	0.02
317.1960449	0.02
321.3113403	0.06
324.3335571	0.03
367.4987793	0.02
368.1310425	0.90
369.1524658	0.06
387.3477173	0.04
411.8904419	100.00
412.6173706	0.31
420.2714233	0.10
482.9724731	0.04
484.0816040	0.06
504.8399048	0.02
513.4808350	0.06
531.1217041	0.08
549.0988159	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1131.5231
Annotation	Sinocrassuloside II
Peak:m/z	Relative Intensity
456.3009033	0.10
499.4898682	0.07
537.3956299	0.33
541.3762207	0.20
579.7913818	0.05
627.2583618	0.31
635.3276367	0.05
663.4459229	0.03
771.3380127	0.12
791.6551514	0.05
907.2591553	0.05
927.5939941	0.26
951.3021240	3.83
955.4582520	0.07
957.2269287	0.05
969.4206543	100.00
970.0842285	0.08
973.4445801	0.06
983.2812500	0.05
985.7626953	0.17
990.6447754	0.05
991.9371338	0.04
994.7995605	0.19
1011.3365480	1.14
1026.2319340	0.08
1027.4965820	0.78
1060.4318850	0.13
1071.4931640	0.35
1072.3533940	0.07
1108.4467770	0.07
1113.5146480	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	618.2146
Annotation	Unknow
Peak:m/z	Relative Intensity
181.2769012	0.08
191.1445618	0.01
205.0419617	0.46
207.1700592	0.11
210.9820251	0.03
212.7997742	0.03
229.1340027	0.06
231.0503845	0.08
235.0647125	0.17
243.2138977	0.06
245.3198547	0.02
247.3995667	0.09
254.7755890	0.03
259.3219910	0.09
264.9735718	0.23
271.3688965	0.09
273.0700684	2.44
276.9407959	0.22
283.1893616	1.73
291.1232300	100.00
297.0139771	0.04
301.0845337	11.56
302.9885254	0.06
312.9142151	0.23
315.1395264	0.49
320.8413086	0.05
327.3568115	0.16
332.9733887	0.83
339.1661377	0.31
357.0727539	0.41
361.9168701	0.03
369.2695923	0.07
376.5283203	0.05
380.9865112	0.04
396.1942139	0.18
399.5300293	0.04
417.0403442	1.58
434.9728394	1.34
435.6301880	0.09
446.3255615	0.05
448.9746094	0.06
450.4801025	0.03
451.3442383	0.63
452.3597412	10.75
453.0131226	86.87
456.2743530	0.29
471.2876587	0.03
489.3818970	0.04
496.1478882	0.07
538.2453003	0.08
542.1111450	0.04
600.0951538	0.28
601.0673218	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1525
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
162.1413116	0.04
162.9533539	0.25
164.9349365	1.27
165.9650574	0.98
167.2194061	0.10
168.1591949	0.15
169.0442810	0.17
171.2269287	0.52
172.0289612	0.15
174.2663422	0.39
174.9693756	0.19
176.0510559	0.27
179.1188049	0.62
181.2016296	0.08
182.1567078	0.41
183.0846558	0.43
183.9653015	0.06
185.0398254	0.52
186.1287231	1.49
188.2061005	0.23
188.9765930	0.33
190.1398621	0.42
191.0609283	0.15
193.2624969	0.19
193.9318085	0.42
200.0894165	0.14
202.1387634	0.04
204.0339661	0.11
207.8772583	0.21
210.1784668	0.07
213.0918427	0.77
214.0755463	1.56
215.1464691	0.19
216.3489990	0.40
225.3317261	0.05
227.0428772	1.37
228.1016541	0.95
229.0200348	0.41
231.0629425	27.44
232.0855865	19.95
234.0964813	0.14
243.1651306	3.43
244.1959839	4.36
245.1916809	1.78
246.1006927	0.49
246.8380127	0.43
250.8855896	0.12
252.1809235	0.06
253.4411774	0.63
255.0242920	5.15
256.1427612	6.07
257.1104126	0.47
258.0202332	0.18
259.2609253	0.14
260.0111084	0.07
261.3411255	0.06
267.1949158	2.47
268.1452026	0.89
269.0818481	6.20
270.0815430	5.13
271.2666016	0.48
272.1503906	1.53
273.0188599	29.43
274.0747070	29.90
275.0846558	11.60
276.1929932	10.06
279.0001526	1.70
280.0814209	1.06
281.2360535	0.08
285.0742188	15.01
286.1411133	13.25
287.2435303	7.67
288.0648804	6.40
289.0142822	0.75
291.0723267	42.04
292.1080933	33.39
294.2406006	0.12
297.0734253	7.73
298.1009521	10.72
299.1791992	3.59
300.1359253	2.35
301.0308838	0.50
302.3103027	0.27
303.0599976	8.13
304.1400757	9.76
305.2488403	0.11
306.0698853	0.08
309.3770142	0.13
310.2354736	0.35
312.0948486	0.71
315.1234436	0.88
316.1294556	0.79
317.0519409	0.24
320.2783203	0.22
325.0866089	2.79
326.2131958	2.90
330.9513550	1.43
332.1979980	2.69
333.4854736	0.32
334.1249390	0.68
346.2859497	0.12
354.0280151	0.06
359.2416382	0.50
360.0986938	0.24
365.3114014	0.24
366.2496338	0.14
367.0396729	0.07
369.9478760	0.28
373.4838257	0.21
374.0925293	0.51
382.3939819	0.32
384.0393677	0.34
387.4038086	0.05
390.2781372	0.65
393.0608521	38.08
394.1024780	100.00
395.2365723	11.93
396.1622925	19.67
401.0760498	1.36
402.1854858	5.21
402.8017578	0.26
405.2796021	2.52
406.1375122	7.46
407.1538696	1.11
408.2412720	5.47
409.2634888	18.09
410.2109985	33.84
411.1831665	28.20
412.0519409	60.25
412.6681519	0.12
417.1416626	0.20
419.3100586	13.18
420.1709595	34.58
421.2960205	0.99
422.2041016	3.69
423.0286255	0.67
424.0201416	3.80
425.1743774	0.19
425.9312134	0.05
427.0836792	16.12
428.1748657	38.90
433.1353149	0.73
434.3756714	1.63
437.0637817	20.34
438.0661011	69.11
439.1163330	5.48
440.1229858	11.77
440.8419189	0.06
446.9390259	0.40
449.2777100	0.61
451.0977173	0.88
452.2275391	1.49
462.1293335	0.37
471.6954346	0.43
497.2520142	0.05
498.9937134	0.05
499.8611450	0.19
502.4441528	0.04
507.2534790	0.25
510.0640259	0.12
512.2966919	0.17
516.1298218	0.65
518.8593140	0.23
520.5226440	0.34
527.3195190	0.49
528.0863647	4.67
532.1077271	0.08
545.5244141	6.11
546.1563110	82.70
547.2076416	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.2253
Annotation	Unknow
Peak:m/z	Relative Intensity
158.1023865	0.23
160.0961151	0.09
165.1824646	0.05
170.9028320	0.03
173.1307068	0.03
176.0523224	0.68
177.0540924	0.05
191.2288055	0.12
193.0976868	1.94
194.0826874	0.06
195.0720825	0.10
207.9906616	0.06
210.0310974	0.03
217.1525879	0.03
225.2024231	0.05
227.2465210	0.04
229.3685760	0.05
259.0858765	0.04
265.8874207	0.04
266.6284485	0.04
270.2127991	0.07
276.4704590	0.04
284.1166992	1.00
293.9624023	0.09
302.2164917	0.13
303.1870728	0.04
304.1353149	0.05
306.7502747	0.06
312.2101440	0.15
313.1695557	0.02
322.2901001	0.21
323.2408447	0.16
324.2519531	0.30
327.9674683	0.13
338.3613892	0.10
345.1116943	0.09
346.9377441	0.02
365.4219971	0.24
366.2905273	0.12
368.8091431	0.15
371.2236938	0.08
371.9867554	0.05
383.0894775	1.59
384.2377930	2.83
385.2260132	0.21
386.0846558	0.15
398.7087402	0.04
401.1606445	75.29
402.2079468	0.21
413.0639648	0.07
419.1441040	26.10
419.8511353	0.07
423.0764160	0.13
436.2015381	0.08
441.2647705	1.21
444.0051880	0.05
453.7918091	0.02
456.6271973	0.02
457.3887329	0.04
459.3211670	1.93
485.1099243	0.06
494.0502319	0.03
503.4851685	0.11
512.2908325	1.58
513.3815918	0.08
530.1979980	100.00
530.9490356	0.17
538.6298218	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.323
Annotation	PE(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
155.2939606	0.08
163.0915985	0.06
184.0719452	39.86
193.9290466	0.07
225.5062561	0.09
239.6418762	0.20
240.2783813	0.04
254.8042297	0.06
258.1874390	0.72
311.1368713	0.20
353.4268188	1.04
412.4450073	0.12
423.9778442	0.07
433.5765686	0.22
435.2654724	0.32
451.2394714	0.07
462.8670044	0.13
472.3821411	0.26
476.3530884	100.00
477.0066528	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.0979
Annotation	Unknow
Peak:m/z	Relative Intensity
99.9797592	0.07
101.3206635	0.08
101.9362488	0.15
127.1828308	0.09
129.9551392	78.13
131.0270081	3.39
132.0627136	0.23
148.8818970	0.71
157.9767456	0.17
158.9718018	0.24
160.1788330	0.12
172.1758728	0.10
176.0049133	0.70
190.0193176	0.22
190.9614716	1.15
192.2368317	0.06
192.9413910	1.66
197.8268280	0.67
198.7400818	0.39
199.5109863	0.05
200.2878265	0.16
203.1031189	0.23
207.1413269	0.18
212.2230835	0.36
216.0459900	0.96
225.0782166	0.86
226.0904236	0.14
231.1210022	2.87
232.8160095	0.08
238.5877686	3.24
245.0670166	0.16
247.5831604	8.14
248.1977539	3.17
249.1354065	0.30
252.1225586	0.17
256.6163330	100.00
257.9092407	0.29
259.3533936	0.18
265.1829529	0.40
267.6799622	1.41
270.2461548	0.14
271.3696899	1.08
272.0969238	0.07
275.8110962	0.80
276.5978088	4.42
277.2989502	1.95
280.5914612	2.81
285.9586182	0.31
288.3128662	0.54
289.5955811	30.41
290.4332275	1.17
292.1500244	0.06
298.0426941	0.69
302.1791382	0.75
303.1503296	4.26
304.1495972	0.67
304.7643433	0.82
305.5173035	0.28
312.4252930	52.49
313.2789001	6.93
322.0259705	0.19
323.1214600	0.08
354.0726013	0.70
355.2682495	0.41
364.9569702	0.14
378.3303833	0.30
383.0809631	82.80
384.1921387	12.37
395.0208740	0.77
396.2087097	0.21
401.1379395	0.07
405.0936279	1.67
406.3162842	0.44
423.2544861	8.81
424.0279846	1.48
446.8511658	0.20
449.2008667	0.34
477.9941101	0.18
494.2563171	2.74
495.0278931	0.37
512.1836548	66.40
513.2251587	11.66
522.2387695	0.24
534.2390137	1.16
535.4403687	0.16
552.2102051	10.53
553.3463745	2.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1299
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
161.0048676	0.08
197.2938690	0.17
207.0873260	0.12
217.4611664	0.06
235.1109009	0.20
241.2457581	0.93
243.1014862	0.33
261.1551514	0.62
273.1515503	23.27
277.1394043	0.10
279.1764526	0.17
301.2078247	0.08
322.7999268	0.36
337.3159790	0.14
341.0001221	5.45
345.1789551	0.97
354.1679688	0.28
355.3225098	0.10
372.1278076	0.19
374.2569580	0.23
387.0187988	0.13
391.1961670	0.14
392.2650757	0.18
401.5717163	0.33
419.0705566	0.20
431.2484131	0.69
435.2891235	0.54
447.3702393	0.14
459.5220947	0.20
470.8118286	0.18
475.2891235	0.21
477.1600952	100.00
485.3508911	0.11
493.1978149	0.08
502.2457886	0.47
503.2681274	5.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7362213	0.08
159.1274719	0.02
198.0333862	0.37
199.0428467	0.39
200.0834351	0.53
206.9036102	0.78
213.3681030	0.21
290.7445984	100.00
291.3501587	0.58
329.2700500	0.03
336.3588867	0.04
355.1260071	0.07
357.4515686	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2176
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
97.0581970	0.66
109.1077423	0.73
113.1135788	0.35
115.2663269	0.09
123.0226288	0.27
125.0945282	2.03
129.2292480	0.49
137.3629761	0.25
144.1500397	0.03
151.1708374	0.48
153.0233459	0.22
154.9140320	1.07
159.2022400	0.19
165.0405579	0.38
166.3027344	0.41
167.1328888	1.08
168.9231415	0.09
171.1296387	1.11
173.2039795	0.06
176.8266449	0.39
177.4728394	0.19
179.0913086	0.16
181.2492065	1.05
183.0983887	36.53
183.9314575	0.08
191.0366974	0.39
193.1293030	2.36
195.1095581	11.55
196.0073395	0.10
197.3219604	0.62
199.1430664	0.32
207.1799469	0.95
209.1875305	0.34
211.1256104	86.92
212.2230835	1.05
213.1662292	4.24
214.9800415	0.07
217.2431641	1.01
219.1008301	1.08
221.0391541	1.64
223.2970276	0.59
225.1769104	0.82
229.2060852	4.56
231.2252502	0.07
233.1925964	1.41
234.0844727	0.21
235.2757263	0.98
237.2883606	0.55
239.1053162	0.86
241.2084351	1.77
242.2128906	0.08
243.3126831	2.97
245.1212463	0.04
247.2599182	4.49
249.0515442	0.30
251.1595764	11.47
253.0404663	0.24
255.2989807	1.89
258.2432251	0.13
261.3391724	0.46
263.1394653	0.53
265.3150635	0.32
266.3136292	0.06
267.2580261	0.60
269.1669006	21.84
270.2595215	0.06
273.2739563	3.39
274.0249329	0.08
279.3411865	0.20
281.4097900	0.45
283.3948975	0.35
289.2438965	1.61
291.3088074	100.00
292.3155823	0.26
297.1699219	0.44
298.9629822	0.09
307.3495483	1.96
309.3014832	46.40
310.2821350	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1617
Annotation	Unknow
Peak:m/z	Relative Intensity
161.2511749	0.07
163.3296814	0.05
175.1681519	0.11
191.1793976	0.10
203.1015930	0.05
207.2557678	0.21
268.4038391	0.03
275.3488770	0.12
287.0895996	0.42
293.1210327	0.76
301.0427246	0.04
320.3608398	0.06
335.0468140	0.04
339.4839478	0.09
341.2390137	0.16
369.3126831	0.26
371.0584106	0.04
387.2546387	13.47
388.2286987	0.12
401.1394043	1.44
419.1363525	100.00
419.7727661	0.27
427.2531128	0.09
437.3587036	0.37
443.6435547	0.02
445.4178467	0.08
457.3328857	0.22
459.2391357	0.16
461.2106323	40.56
465.2030029	0.06
483.3670044	0.04
501.1926880	9.31
503.0604858	0.24
519.0988159	0.05
527.3491821	0.04
545.2497559	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.508
Annotation	PE(P-16:0/20:4(5Z,8Z,11Z,13E)(15OH[S]))
Peak:m/z	Relative Intensity
213.0643463	0.08
214.1916199	0.04
223.2055664	0.03
241.1265869	0.05
247.2675323	0.12
255.2024384	0.10
256.2908936	0.11
261.2766113	0.37
270.1634216	0.03
277.2513428	0.25
279.2539978	100.00
280.3460999	0.09
281.5371094	0.36
293.0943604	0.24
297.3771667	0.11
311.0727844	0.56
315.2918701	0.10
333.8782654	0.28
392.9135742	0.03
415.1619873	0.16
458.2955933	1.28
471.1163330	0.13
474.5692749	0.10
476.4296265	10.03
481.5092163	0.11
517.3948975	0.12
521.4720459	0.05
536.4568481	0.20
566.6217651	0.04
589.5248413	0.07
592.3396606	0.05
618.2008667	0.09
625.2111206	0.09
628.1229858	0.13
631.2523804	0.17
660.3397827	0.10
674.5704956	0.04
676.2626343	0.12
678.3919678	0.57
679.5989380	0.16
688.5684814	0.27
692.8599854	0.26
702.0519409	0.10
706.1752319	0.18
719.8526001	0.08
720.4880981	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	633.1794
Annotation	8-Demethyl-8-(2,3-di-O-methyl-alpha-L-rhamnosyl)tetracenomycin C
Peak:m/z	Relative Intensity
197.0626984	0.02
222.2831116	0.02
225.3425446	0.06
241.0040283	0.07
259.1608887	0.03
287.1383057	0.02
314.1624756	0.02
331.0346680	23.81
333.0628662	0.02
441.1966553	0.70
459.3062744	0.86
459.9551392	2.76
484.3231812	0.03
486.0127563	0.19
503.9136353	100.00
504.6609497	0.11
569.4891968	0.01
588.7600708	0.08
614.8871460	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1741
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
225.5171509	0.25
229.0417633	0.15
251.0913239	0.18
254.8888245	0.29
269.1398926	0.90
271.3244629	0.25
272.2824707	0.18
275.3347168	0.07
280.0575256	0.39
285.1351624	0.65
301.901062	0.58
311.2653809	0.73
317.0734863	100.00
317.7487183	0.29
341.1787109	0.44
348.8659668	0.12
359.4041138	0.17
373.3123779	0.07
378.1127319	0.18
384.0731812	0.15
386.5612183	0.18
394.0643921	0.17
415.1583252	0.09
425.0795898	0.27
444.5072021	0.36
445.3428955	0.31
446.7042236	0.36
457.046814	0.31
461.3931274	0.68
462.8126831	2.20
463.4355469	0.19
464.3270874	0.27
471.0373535	0.09
472.7489624	0.87
478.9937744	19.48
496.1057129	0.37
535.0197754	0.27
539.1378784	0.17
571.2539673	1.11
581.3268433	0.36
583.3733521	0.12
589.1415405	0.13
592.3938599	0.35
593.1821289	0.50
607.0800781	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.8909454	4.51
130.9057007	0.07
148.0750122	0.12
158.9375610	100.00
159.9745789	0.30
160.8294373	0.04
198.9880981	1.67
200.7832947	0.05
201.4261169	0.07
217.0136414	0.96
227.1849670	0.10
228.9361267	26.51
230.0208130	0.08
245.1852112	0.19
254.7432251	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1114
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
126.9656296	7.75
129.9291382	0.03
144.9251099	0.35
162.9874268	0.50
165.0292816	0.02
187.098175	0.09
204.9114532	0.01
253.2857361	0.10
269.9412537	0.06
271.0549316	100.00
271.6685486	0.09
272.3774109	0.03
273.1077881	0.03
279.9385681	0.02
289.0441284	0.31
291.2781982	0.03
303.1538086	1.26
304.1347656	1.84
306.3245239	0.08
307.1230469	0.18
311.0343018	0.02
341.0014038	0.02
397.1122131	0.06
415.2713928	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	722.3387
Annotation	Unknow
Peak:m/z	Relative Intensity
204.3192139	0.11
205.9334717	0.06
207.0847015	0.85
219.0768433	0.09
220.1328430	0.05
225.2368164	0.26
226.8104858	0.07
228.2450562	0.18
229.9560089	0.37
230.9001465	0.14
235.1985931	0.14
238.0771179	0.10
239.1536865	0.50
242.4916534	0.14
244.1637421	0.21
246.2065125	0.76
247.5651855	0.30
249.0948486	0.07
252.9859314	0.08
272.1069946	0.13
274.1574707	0.13
276.2019043	0.06
287.2296143	0.12
290.1897583	3.46
291.2430115	0.22
293.2426147	0.05
299.1959534	0.12
305.2739868	0.06
308.3781433	0.10
315.4174500	0.12
319.1567993	0.14
323.3554688	0.05
334.1930847	2.49
344.0852051	0.08
350.2604370	0.10
352.2180176	0.90
354.5440063	0.05
358.1601562	0.11
366.2094116	0.06
369.2487183	3.92
370.3599243	0.12
376.0791016	0.08
384.4819336	0.11
387.1987915	100.00
388.1859741	0.56
392.2533569	0.08
406.3175049	0.05
411.3909912	0.11
429.3020020	1.01
432.6288452	0.04
433.4026489	0.09
436.3695679	0.38
442.0645752	0.03
449.3141479	0.07
476.4616699	0.09
478.3306885	0.10
484.3864136	0.07
494.2164307	0.18
497.4933472	0.11
500.3356934	1.23
512.4926147	0.27
528.3012085	0.26
545.9969482	0.10
546.6128540	0.16
547.4467163	0.16
549.4191895	0.70
555.3645630	0.12
558.2304077	0.05
566.6581421	0.05
578.5727539	0.39
582.0739746	0.10
585.2905273	0.07
591.2787476	10.59
592.1516724	0.20
606.3851318	0.12
609.3078003	0.10
618.4493408	0.05
620.4321899	0.44
625.8057861	0.13
647.9035034	0.13
658.5357666	0.11
660.2768555	0.76
661.7683716	0.48
662.6854858	0.16
675.9724121	0.14
678.1427002	0.18
686.4494019	0.05
688.2618408	0.44
691.7765503	0.10
704.2898560	5.95
705.1878052	0.23
713.3072510	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	640.3018
Annotation	Balanitesin
Peak:m/z	Relative Intensity
286.1477661	0.02
326.9507446	0.01
359.4211426	0.03
389.3803101	0.02
608.4126587	0.14
617.3200684	100.00
618.7927246	0.40
619.7758179	0.13
620.5326538	0.02
621.5424805	0.07
622.4647827	0.02
624.4295044	0.03
625.0688477	0.17
651.6683960	0.06
657.6939087	0.02
729.2083130	0.04
747.7333374	0.03
865.6589355	0.05
909.5618286	0.06
927.5901489	0.02
928.5380249	0.03
939.8705444	0.01
940.8693848	0.01
1011.9096680	0.02
1055.5905760	0.14
1056.6533200	0.03
1073.4528810	0.97
1074.5996090	0.01
1118.4189450	0.03
1235.4451900	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.208
Annotation	Unknow
Peak:m/z	Relative Intensity
241.1161194	0.24
243.1567993	0.16
245.3847198	0.08
246.8584900	0.13
255.1651459	0.33
257.0545654	0.05
258.6719971	0.10
261.2092896	0.10
268.4225159	0.21
269.2901611	0.88
270.4088135	0.86
271.1345215	3.44
272.9743652	1.11
273.9559937	0.07
281.1909180	0.44
283.0729065	0.52
284.2514648	0.21
285.0507812	0.09
285.9487915	0.27
287.1276855	1.75
289.0157471	5.78
290.1881104	0.31
291.1038513	0.09
292.0727539	0.08
299.0217285	0.12
301.1069946	0.30
303.5015564	0.26
308.1155090	0.22
309.7382202	0.54
310.4114990	0.70
311.1564026	0.59
313.2074890	0.14
314.9359741	0.05
328.8624878	0.64
330.2679749	0.25
331.2846069	0.12
333.1655884	0.11
337.2265625	0.12
339.1926880	0.20
341.1353760	0.33
345.1566772	0.09
347.2232056	0.25
351.4285889	0.25
363.2598572	0.53
365.3449707	0.58
367.1327209	0.10
369.2814941	0.08
373.2997437	0.39
375.3729248	0.17
377.3435059	0.20
379.1506958	0.82
381.2247314	0.66
383.2180176	1.34
389.2780151	1.45
391.2615967	0.84
393.5495605	0.64
396.5739136	0.27
397.2466431	2.30
398.4059448	0.13
400.9802246	0.07
405.3088989	0.29
406.6358032	0.87
407.2881470	5.06
409.1558838	0.63
410.1781006	0.22
413.2306519	1.48
414.2921753	0.13
415.5562134	0.08
417.1228638	3.31
419.3496094	1.36
421.0421143	0.10
423.1334229	0.44
425.0653687	2.72
426.3032227	0.13
429.1310425	0.48
433.2318115	0.58
435.1911011	6.67
436.3262329	0.92
437.1019897	0.54
447.2670288	0.09
450.2250366	0.07
451.9501953	0.06
455.1215210	0.23
457.3076172	0.11
459.1660156	0.82
464.0518799	0.06
467.0653687	0.12
469.3718262	0.14
474.4042358	0.26
475.2530518	0.11
477.2400513	0.83
481.2304077	0.29
495.5954590	0.34
499.2479248	1.01
501.0569458	0.03
503.0036011	0.20
506.1668701	0.09
507.0819702	0.15
509.3677368	6.34
511.3501587	0.17
515.6623535	0.13
516.3101196	0.10
517.2108154	0.84
519.1503296	4.21
525.3453369	0.71
527.2603149	60.41
527.8650513	0.43
531.1652832	0.26
533.1749878	0.08
535.2095337	0.24
543.1428223	30.02
543.9034424	0.08
545.1649780	3.68
547.3386230	0.19
551.3715820	0.75
553.1508789	0.46
555.4338989	1.17
557.2288818	0.20
558.0213623	0.74
559.2096558	3.91
561.1094360	28.36
561.9157104	0.30
569.3963013	3.57
571.1731567	4.14
573.2498169	0.41
577.3517456	0.23
581.1878052	0.40
583.1295776	0.65
585.0485840	0.33
591.3676147	0.09
595.1776733	0.18
597.1702271	0.05
600.2338257	0.31
605.4843140	0.08
609.2513428	0.53
615.0492554	0.08
617.1906128	0.23
623.0572510	0.08
625.1392212	0.12
634.1694336	0.19
635.2221680	0.28
637.3944702	0.26
651.9746094	0.06
653.2178955	1.44
655.8651733	0.42
657.5347290	0.21
661.0364380	0.72
663.2857666	1.91
670.6564941	1.90
671.4003296	15.01
677.5562744	0.22
679.0468750	5.12
679.7720947	0.16
681.0851440	2.42
687.2027588	0.24
689.2632446	100.00
693.1362915	0.05
695.4971313	0.25
696.5062866	0.17
697.1332397	1.99
698.3121948	0.06
699.4251099	0.05
704.3151855	0.31
707.2174683	22.27
708.1356812	0.06
711.4877319	0.31
712.6142578	0.53
713.3790894	0.13
717.8317261	0.14
721.3552246	0.08
725.0984497	0.12
726.1467896	0.05
731.2943115	11.07
733.6723633	0.13
739.2623901	0.47
742.9778442	0.57
747.6763916	0.21
749.5255127	0.06
755.1091919	0.09
756.6807861	0.71
757.8973999	0.09
765.2700806	0.85
769.7783813	0.35
771.2851562	1.03
786.9472046	0.26
788.3628540	0.22
789.1278687	0.10
789.8743896	0.14
795.4571533	0.06
797.0004883	0.09
800.1810303	0.10
811.5850220	0.08
814.4827271	1.50
815.2017822	6.22
815.9570312	0.20
818.1583862	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	376.1523
Annotation	Dioncolactone A
Peak:m/z	Relative Intensity
111.9970398	0.68
118.8785248	5.79
129.0580444	0.23
130.0689697	0.99
133.0802155	0.03
135.9417419	6.73
137.0343018	0.20
138.2324524	0.04
147.0038147	0.04
150.1387329	0.06
151.0295410	0.14
181.2127228	0.04
182.1704407	0.50
195.0602417	0.72
199.1042175	0.52
201.9814148	1.33
213.1536713	1.64
214.3587952	0.11
217.2590332	0.03
218.5435486	0.25
219.2510376	0.31
220.2488403	0.13
223.1067200	1.21
225.2421875	0.09
229.0984497	0.74
230.2810059	0.02
241.0688171	21.58
242.1014404	0.36
243.1842651	0.09
247.0570679	8.61
248.0038147	0.37
251.2989502	0.12
258.2755432	1.15
259.1736145	8.14
260.0072021	0.15
261.2629395	0.11
265.0248413	100.00
266.0487976	1.01
267.1280823	0.09
280.0757446	0.10
280.9722290	0.04
284.1785278	0.99
285.9522705	1.04
289.2578735	0.09
296.0845642	0.04
301.2543945	0.22
310.2146912	3.02
328.2161255	23.97
329.2227783	0.46
330.1909790	2.48
335.0606689	0.04
340.2927856	0.25
353.8342590	0.24
358.1709900	8.35
359.2752380	0.31
366.4734497	0.23
367.3263855	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2188
Annotation	Unknow
Peak:m/z	Relative Intensity
221.4323425	0.04
268.3027954	0.06
271.2655945	0.02
286.2785645	0.02
287.1918640	0.01
291.0250549	0.15
301.4670715	0.02
313.3150024	0.10
321.4967041	0.01
323.3074951	0.03
327.2216797	0.04
331.1628418	0.03
357.2742920	0.06
367.0614624	0.05
373.0172119	0.03
387.3555298	0.08
459.2053223	0.03
465.2909546	0.03
467.2034912	0.20
500.8068237	0.04
507.0385742	0.07
527.2744751	0.11
531.3327637	0.07
553.1367798	0.03
561.3475952	0.14
563.6126099	0.06
577.2903442	0.04
579.3156128	0.04
582.1472778	0.03
587.0572510	0.03
600.5246582	0.01
603.2310791	100.00
604.0965576	0.03
629.1105957	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1162.5769
Annotation	Unknow
Peak:m/z	Relative Intensity
388.3781128	0.04
569.7779541	0.10
614.1716309	0.05
659.3680420	0.11
739.3626099	0.03
910.3796387	0.07
975.5129395	0.03
1042.2309570	0.08
1054.6115720	0.05
1055.5676270	0.06
1060.5229490	0.07
1071.7351070	0.07
1074.5966800	0.06
1087.6423340	0.09
1089.4437260	100.00
1090.4361570	27.13
1103.3447270	0.15
1103.9935300	0.07
1104.7239990	0.15
1105.6162110	0.31
1106.6125490	0.05
1116.7592770	0.03
1118.5242920	0.08
1131.1370850	0.22
1144.7895510	0.03
1174.3397220	0.15
1217.2031250	0.41
1218.0549320	0.24
1218.7749020	0.18
1219.4106450	0.09
1220.5778810	0.15
1235.4395750	76.45
1236.4477540	28.32
1237.2396240	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.23
Annotation	EI-1511-5
Peak:m/z	Relative Intensity
167.3208466	0.10
168.9859467	0.04
170.3179932	0.04
189.0218201	0.08
191.0876770	0.03
197.2194824	0.09
198.1191254	0.09
205.1617432	0.08
209.2989807	0.09
211.4583588	0.04
213.3258057	0.03
214.9475250	0.17
225.3339386	0.05
243.1762543	1.48
244.0679321	1.12
245.0581055	0.03
251.1752167	0.03
257.2992554	0.12
261.1512451	18.24
264.6218872	0.05
271.0833740	2.33
272.0909729	1.98
273.1735840	3.22
275.2493286	0.08
279.1091309	1.06
284.3224487	0.09
298.3060913	0.08
310.9608154	0.04
326.2493286	0.06
328.6453857	0.13
329.3480835	0.03
341.2109985	0.35
344.2319336	0.30
345.5053101	0.08
346.4423828	0.35
347.3475342	0.04
356.1686401	0.51
357.5396118	0.24
358.4432983	0.16
359.4027710	0.20
364.5537109	0.07
365.2760010	0.05
367.9409180	0.05
372.2221680	0.28
374.1735229	0.97
375.2980347	0.15
383.3739014	0.10
390.2756348	0.35
392.1815796	100.00
392.8406372	0.13
394.9417114	0.05
408.4031372	0.08
414.4243164	0.03
435.1532593	0.12
439.6295776	0.18
440.4774170	0.07
446.1143188	0.07
458.2711182	0.38
475.2715454	0.20
480.1325684	0.03
484.9555054	0.23
493.7294922	0.08
503.2474976	3.47
504.3969116	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9494781	5.33
115.9193954	3.97
131.0300293	0.06
131.9209290	0.06
156.0666809	0.10
158.9239655	93.07
159.9198303	100.00
160.7890472	0.07
185.8586121	0.09
189.1330719	0.19
198.8112183	0.15
199.9822998	3.77
200.8950500	0.12
201.5487061	0.06
202.1520081	0.16
217.0607605	0.32
217.9138794	0.38
228.1050415	0.15
229.9319458	52.99
246.1665649	0.33
255.9996338	0.04
274.0955811	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1332
Annotation	Griselinoside
Peak:m/z	Relative Intensity
126.8961258	100.00
129.9609680	0.02
135.9134827	0.08
144.9493713	3.66
158.1669922	0.04
162.9017639	5.00
168.2955322	0.06
168.9794617	0.21
176.9750366	0.03
178.9225159	0.13
186.9629669	0.50
187.9577942	0.26
190.9819946	0.28
205.0345154	0.58
215.1335144	0.07
216.9404449	0.05
227.1145477	0.05
230.1142273	0.12
244.9330444	0.04
252.9719543	0.53
261.2026672	0.05
263.1472168	0.08
269.8520813	0.06
271.1455078	35.90
275.3999939	0.14
279.1322632	0.04
283.3305359	0.05
284.9938354	0.05
287.2879333	0.09
288.9048767	6.24
289.5545044	0.07
295.7437744	0.15
303.2343750	1.33
304.1466675	1.56
307.0580139	5.82
310.8614502	0.11
313.0784912	0.04
320.9447632	0.03
331.3041992	0.05
343.3063354	0.07
369.8715515	0.10
371.2880554	0.73
373.1158142	0.09
388.7512512	0.02
389.3979797	0.06
397.1411438	1.41
401.3337097	0.19
405.2208557	0.14
406.3268127	0.05
411.3356018	0.14
414.9551697	1.99
416.3029480	0.04
424.8620911	0.21
439.1535950	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	259.13
Annotation	gamma-L-Glutamyl-L-pipecolic acid
Peak:m/z	Relative Intensity
73.8655548	3.24
83.9450455	2.34
94.9998779	0.22
98.9724121	0.03
102.0909119	0.14
104.0938873	0.67
105.0640869	0.50
108.8127441	0.09
111.2102509	0.03
111.9218292	0.16
112.9209747	1.13
114.0409088	0.05
114.8610687	0.03
116.1170654	0.03
121.0050659	0.17
123.0541687	0.08
126.9318085	0.20
129.9357605	100.00
141.3222809	0.07
147.0521393	0.38
148.8724823	0.13
150.5504150	0.07
151.9880676	0.25
153.9024506	0.03
158.3925629	0.11
159.1655121	0.04
167.2218475	0.12
169.3699188	0.08
170.0446167	0.17
171.0777435	0.08
172.0837250	0.03
172.9124908	0.93
174.9308472	0.55
179.9892578	0.04
184.9107819	1.43
187.1478424	0.18
193.3080292	0.06
196.0250702	43.92
200.0067749	0.07
203.1821442	0.06
204.9435577	0.26
212.8352509	3.09
213.9718628	0.21
214.9375305	1.01
217.8047485	2.98
221.1850128	0.16
222.9501801	0.26
224.1905975	0.04
227.0696259	0.12
228.2388916	0.30
229.0523224	0.06
231.2864380	0.41
233.1584320	0.24
235.8113403	0.68
241.0883179	10.21
242.0444336	22.90
242.9404907	0.05
243.8579712	0.21
249.6942139	0.45
260.1573792	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.211
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
98.9752808	0.13
104.9766006	0.38
106.8257675	0.14
110.9059448	0.21
116.1183090	0.05
116.9445267	0.14
119.0721283	0.88
121.1234665	0.50
123.2197800	0.09
126.9128418	0.24
127.9399109	0.45
129.5027618	0.15
131.0321655	1.46
131.9703064	8.94
134.9728699	0.24
137.0290680	0.53
142.1492157	0.24
144.9840088	0.63
149.0746155	2.69
149.9852295	0.47
151.0261230	0.07
155.1984558	0.09
155.9236450	0.67
158.2778625	0.06
161.1709595	0.15
163.0471802	0.55
165.1238403	0.24
167.0288696	42.03
173.0253754	2.08
173.9665222	0.16
178.7974243	0.07
187.1605682	0.17
191.0650482	13.65
192.2891235	0.31
196.0850067	2.27
206.0528259	1.66
207.3076477	0.17
209.0675964	86.11
210.1663513	1.25
215.8722839	0.11
216.9615784	0.04
223.0100098	0.08
226.1989136	0.14
226.9801941	0.47
228.0571899	0.04
234.1222839	0.15
238.1123047	5.56
240.4482422	0.07
243.3649597	0.16
246.3999634	0.33
248.3826294	0.17
252.0903015	7.01
256.1813354	16.04
258.2818909	1.22
258.9198608	0.04
260.0604248	0.14
262.3836975	0.08
264.3305054	0.11
269.3547668	0.06
272.8070374	0.08
276.2055359	27.09
277.0039978	0.12
278.3392944	0.17
284.9413757	0.11
292.2746887	1.58
294.2241821	16.16
296.2435913	0.35
298.0786438	0.57
299.7136230	0.04
300.5254517	0.10
304.1917725	40.55
304.9931335	0.11
308.7385254	0.16
310.2243652	2.36
311.1061707	0.05
312.3049316	1.09
322.1231079	100.00
322.9406128	1.04
330.8733521	0.26
331.4814453	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.2106
Annotation	Manumycin G
Peak:m/z	Relative Intensity
148.2606812	0.05
153.1071167	0.07
165.1228943	0.01
169.0653992	0.07
180.2711487	0.02
186.0385895	0.01
197.0750122	0.03
198.1387329	0.17
201.0323792	0.01
201.7460327	0.08
216.1143799	0.04
219.0312500	0.02
221.0951385	0.02
222.4329834	0.03
229.3925476	0.17
230.0932465	2.11
231.4303436	0.06
241.1513062	0.02
243.2823181	0.66
244.1405182	0.47
247.1540527	3.39
248.0560913	0.10
261.0856934	5.42
265.1629028	1.18
267.3596802	0.05
270.1089478	0.04
272.0872498	0.02
284.2986145	0.03
295.0057373	0.08
296.2199707	0.01
296.9331055	0.03
300.3282166	0.04
310.1234741	0.02
314.5784607	0.29
315.2255859	1.03
316.1489868	0.11
330.1343689	0.25
332.1674805	1.18
333.1633301	3.18
342.0135803	0.25
343.1493225	3.26
345.1087341	0.01
348.5686035	0.05
353.9724731	0.04
354.8540649	0.02
360.4065552	3.66
361.1479492	12.73
361.7579346	0.02
376.0078430	0.34
378.1477051	100.00
378.7683411	0.39
394.3187561	0.09
395.1019897	0.01
397.9026184	0.03
423.2717285	0.21
426.0671997	0.11
428.2746887	0.02
435.1709290	0.05
441.3548889	0.22
443.4359741	0.08
444.2726746	0.60
447.3291931	0.09
448.3396301	0.13
453.2594910	0.01
459.4403687	0.05
461.2123718	0.08
462.2201233	0.06
471.0599670	0.28
479.5191956	0.05
489.1686401	3.78
490.2456970	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2445
Annotation	Wanepimedoside A
Peak:m/z	Relative Intensity
191.1867523	0.07
202.9928284	0.43
207.1951599	0.10
224.0620728	0.05
225.1955109	0.32
234.9365845	0.02
241.0326691	0.15
245.0338745	0.43
247.2411499	0.03
258.9252930	0.10
268.0667114	0.06
271.0919800	0.10
283.2596436	0.04
287.2543640	0.05
289.1479187	6.21
294.0510864	0.03
318.1983643	0.04
320.4146118	0.03
323.2508850	0.04
350.7832642	0.06
353.2416382	0.11
356.3417969	0.04
369.2669678	0.17
387.2337646	100.00
387.8496094	0.20
388.5941162	0.14
390.2255249	0.37
400.3878174	0.04
407.3458252	0.05
429.2592773	0.03
435.2592163	0.06
473.2838745	0.10
481.1353149	0.03
486.4812012	0.06
497.4533081	0.16
509.9873047	0.23
514.6483154	0.11
515.4423828	0.19
518.0667114	0.03
533.2031250	1.34
541.3069458	0.07
545.2634888	0.14
546.3483276	0.22
548.4049683	0.60
553.2053223	0.09
555.4473877	0.02
587.3634644	0.04
588.2932739	0.18
601.2625122	0.14
617.2435913	0.03
630.8833618	0.30
631.5430908	0.15
634.2715454	0.07
654.5526733	0.19
658.3255615	0.35
659.3799438	0.42
660.6464844	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
113.0554199	0.47
114.8931198	0.04
118.8454208	0.03
127.9668198	0.46
133.7509918	0.42
137.0898132	0.66
142.9114990	0.11
153.0747986	0.27
155.0393982	0.21
161.0789337	1.13
172.8325653	0.03
179.2012634	0.40
181.2005615	0.21
183.2031097	0.05
195.1364136	0.07
199.0919189	3.13
202.9993439	0.07
214.6752930	0.17
215.2799835	0.12
217.0367432	0.40
223.1285706	0.02
226.0277100	0.18
243.0631104	0.05
245.1214294	3.71
251.1253662	0.69
263.1572571	4.18
279.0257568	0.14
287.0400085	0.06
295.0719604	0.19
299.0725403	0.06
308.3001404	0.17
313.0781860	0.35
315.3762207	0.14
325.0109253	1.18
330.9918823	0.38
332.6766968	0.17
335.0791626	0.11
341.2280579	0.51
343.0920410	27.35
361.0591125	100.00
362.2576904	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1923
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9106598	0.13
128.9228210	0.03
138.0937805	0.02
143.0567017	0.29
146.9055786	0.23
149.1598969	0.07
151.2116699	0.05
152.0116119	0.06
153.1388550	3.65
158.9587250	0.46
160.9590302	2.92
163.3461609	0.03
164.9484253	0.17
166.1806183	0.02
172.9598389	0.06
175.2174072	0.03
177.1463928	0.03
179.0652771	0.64
181.1229858	0.02
187.3513184	0.08
188.9064941	0.02
191.0288696	0.08
205.1608582	4.49
207.3676453	0.04
209.0253601	0.09
210.2942352	0.05
212.9725342	0.11
223.0802307	6.68
224.0577393	0.23
225.0417480	1.07
225.8847198	0.02
227.0824280	0.24
233.1558533	0.06
237.1132507	0.05
239.2471008	0.10
241.1291199	0.05
253.2732239	0.11
255.4785461	0.04
257.2206726	0.02
265.2911072	0.02
267.1788330	0.72
268.2370300	3.90
269.0700378	42.15
270.1922607	0.21
271.1062317	0.38
279.3839111	0.12
281.4373779	0.03
283.1998901	0.92
284.9930420	0.05
286.2247009	0.03
293.2965088	0.06
297.2982483	0.03
299.2878113	0.23
304.2987671	0.24
309.1558838	0.07
311.0132446	0.40
323.2255859	0.27
339.9826660	0.12
341.3484802	0.32
352.9954224	0.17
362.8934937	0.06
369.1080627	0.03
370.3674927	0.25
371.2031860	0.46
382.8341064	0.02
385.1302490	100.00
386.0242615	0.01
387.3379211	0.07
388.2988892	0.13
389.2953491	0.30
391.0572815	0.02
395.4458923	0.05
401.1315613	0.06
409.2470703	0.06
411.0647888	0.01
413.2951965	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.2439
Annotation	Unknow
Peak:m/z	Relative Intensity
129.4243469	0.05
130.1498871	0.16
131.0838013	0.02
138.9455261	0.05
140.0471802	0.11
140.9822693	0.11
141.9520874	0.03
156.1929932	0.51
157.2482300	0.76
158.1228180	1.06
171.0237579	0.04
175.1186066	32.16
176.1393127	0.02
180.0897217	0.07
202.6595459	0.01
204.8095093	0.02
209.3296509	0.04
210.0718689	0.03
225.2758026	0.14
225.9808197	0.01
228.2642822	0.25
229.1843262	0.11
231.0211792	0.04
243.2383423	0.15
246.2885742	0.02
250.9635010	0.03
253.2576294	0.64
254.2165833	0.03
255.1444702	0.11
268.2515564	0.41
270.2510986	1.05
271.2749634	1.15
273.1645813	0.02
286.5211792	0.03
288.1995239	100.00
289.0899963	0.03
291.1967163	0.06
301.9582520	0.09
312.2229004	0.04
314.2512817	0.01
322.5372314	0.02
328.0860596	0.04
328.8797607	0.03
336.2949829	0.02
338.0474854	0.02
339.2357178	0.10
355.4143982	0.02
356.2583313	0.11
357.2096252	0.03
369.4004517	0.01
371.4244690	0.10
372.2929382	0.33
372.9741821	0.02
375.5616760	0.03
376.4329224	0.07
381.2457581	0.37
382.2901001	0.79
389.2195129	0.04
399.2787781	20.54
400.3533020	4.60
401.1960754	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.3179
Annotation	Cussoracoside C
Peak:m/z	Relative Intensity
205.1689606	0.29
225.1324463	0.27
240.9242859	0.23
242.0019836	0.40
261.0792236	0.12
273.0879822	0.33
279.3460083	0.19
282.0361938	0.11
285.1526489	0.25
289.0163879	0.49
301.5324097	0.19
305.0338745	0.61
307.3948364	0.23
315.0075684	0.18
325.4898987	0.28
333.2403870	0.14
335.2766113	100.00
335.9554443	0.28
349.2678223	2.02
369.4146118	0.04
371.5114746	0.12
375.5187378	0.22
377.2332764	7.07
387.6265869	0.16
389.1614990	0.51
406.6166992	0.11
417.2651978	0.54
419.3563843	0.30
421.2175903	0.18
424.6704102	0.09
461.3017578	0.11
469.2808838	0.08
471.1577759	0.28
479.2723999	0.57
485.4279785	0.08
497.1170654	5.89
498.4105225	0.08
506.4489136	0.06
515.2665405	0.11
538.9200439	1.05
539.5942383	0.03
553.3900757	0.36
560.9393311	0.55
565.2517700	0.04
567.2601318	0.11
578.9854126	1.25
581.4504395	0.61
586.8711548	0.23
595.1700439	0.89
596.7329102	0.86
597.4168091	4.20
602.8817749	0.07
609.3781128	0.46
610.0184326	0.30
617.9796753	3.57
623.3292847	2.37
626.9409790	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.2105
Annotation	Manumycin G
Peak:m/z	Relative Intensity
152.2360687	0.06
175.9202881	0.09
180.8056641	0.03
198.2898102	0.17
199.0411987	0.02
201.9519806	0.10
203.2241516	0.04
204.1030884	0.02
215.1386566	0.03
225.0500183	0.03
230.0270081	1.64
243.0823364	0.15
244.0657501	0.20
247.0783081	3.35
261.2210083	6.19
265.0580444	0.83
267.2290344	0.05
295.1552124	0.18
297.0625610	0.03
303.4908447	0.08
310.1033936	0.05
315.0661621	1.24
326.0903625	0.06
330.0865784	0.08
331.1257324	0.13
332.3632202	1.09
333.1279297	2.03
343.0708313	3.74
343.7531433	0.01
354.3284912	0.06
358.0986328	0.04
360.2229919	2.28
361.1015015	13.26
371.8472290	0.06
376.1718140	0.64
378.1163940	100.00
378.7527771	0.13
394.1069031	0.23
423.2391357	0.11
441.2728882	0.26
443.4088135	0.15
444.0515747	0.54
450.6734619	0.12
459.1715393	0.06
461.5285950	0.01
470.8279724	0.10
489.2451782	3.62
490.2304993	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.26
Annotation	Unknow
Peak:m/z	Relative Intensity
180.1399841	0.01
190.0124817	0.01
225.2821045	0.02
229.2359161	0.02
231.0757599	0.03
259.0474243	0.01
271.0431519	100.00
313.2372437	0.03
353.2550049	0.03
356.4752197	0.01
381.5331421	0.04
385.8361206	0.07
433.1179810	2.34
475.1433716	3.33
475.7555542	0.02
500.4463501	0.23
501.1390991	0.58
518.8969116	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1403
Annotation	Gerfelin
Peak:m/z	Relative Intensity
161.0649414	0.35
162.1400909	0.04
164.0957947	0.95
164.9875641	0.15
173.2653046	0.04
175.0738831	0.55
175.9810028	0.31
177.0219727	0.08
178.8851776	1.01
180.0439301	0.13
182.3891907	0.06
183.0427094	0.11
184.0067749	0.17
184.9840240	0.15
187.0693665	0.54
189.0643463	0.07
191.1479797	0.23
193.1804962	0.03
197.0571594	0.16
198.9642487	0.08
201.8121643	0.11
203.0165863	2.73
205.1137390	1.73
209.2089844	0.67
211.1815186	0.14
215.0514221	0.33
223.1863251	0.26
225.2495117	0.04
226.5960846	0.20
227.2016296	1.03
229.1144562	0.46
230.2651215	0.06
231.1343536	0.17
240.9911804	0.53
243.1191559	0.14
245.1369324	7.53
246.5165405	0.28
247.2784729	0.18
252.9857178	0.39
255.1850739	0.11
259.1659851	2.67
260.9746704	0.08
267.1898193	0.15
268.2239380	0.03
269.2348022	0.09
270.0909729	0.10
271.0950928	18.25
272.0818481	0.22
273.0513306	4.35
273.9249878	0.04
275.4644775	0.13
283.2032471	3.01
284.1622314	0.12
285.2211304	0.57
287.1213989	0.17
289.1329956	100.00
290.0891724	0.28
293.1772461	0.05
294.8417053	0.13
299.1691895	0.79
301.1309814	1.27
303.3402100	0.10
310.9856567	0.29
313.4206543	0.59
327.4676514	1.08
328.2612915	2.09
329.1167603	8.57
330.9627075	0.43
335.2824097	0.24
337.2366943	0.21
339.1670532	1.30
341.1593018	1.02
347.3781738	0.09
349.0393677	0.13
353.0327759	0.03
355.4261475	0.15
361.2905884	0.55
362.5224609	0.04
363.2122192	0.16
365.1994629	0.04
367.1633301	0.27
371.3485107	0.43
375.1839600	0.07
377.2199707	0.69
381.1638794	3.45
389.0983887	0.12
390.2014160	0.05
391.3715820	1.01
392.1270752	0.08
393.2084351	1.44
395.0516357	0.42
397.1046143	0.36
398.0487671	0.47
403.1026001	0.09
404.5791626	0.09
405.2730713	0.18
407.1594849	22.03
408.1928711	0.24
409.2221680	3.28
410.1809082	0.58
411.1005249	0.36
413.8057861	0.18
417.1840820	0.76
418.1203613	0.06
421.1606445	0.16
423.1888428	1.81
425.1427612	24.13
426.3017578	0.04
427.0419922	0.06
428.9921265	0.40
430.0552368	0.70
431.1399536	0.68
432.9099121	0.40
435.1965942	44.36
437.9882202	0.08
440.0731812	0.27
441.0407104	0.03
443.0843506	0.11
445.4539185	0.33
449.0329590	0.21
451.1879883	0.11
454.2017212	0.63
459.1724243	0.84
462.3499756	0.12
467.5631104	0.10
469.4840698	0.21
473.1336670	0.06
473.9397583	0.29
475.1452637	1.10
476.0450439	0.21
477.2333374	1.01
481.5491333	0.53
483.3190918	0.93
484.7323608	0.39
488.8817749	0.09
492.3167114	1.27
493.3229370	0.04
498.2681274	0.06
499.1812134	2.51
500.7551880	0.47
501.3605347	0.23
502.9624634	0.22
506.8246460	0.39
507.5283203	0.15
510.1848755	0.09
514.0744019	0.12
515.2938843	0.06
516.7055054	0.28
517.3059082	2.97
518.1932983	0.22
518.9341431	0.17
525.2745361	1.57
539.2861938	0.06
543.1495972	38.61
543.9097900	0.53
551.1515503	0.23
569.9899292	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.46
Annotation	Nodularin
Peak:m/z	Relative Intensity
241.0675354	9.70
251.1618042	2.20
255.214859	7.06
269.3216553	1.90
297.1688232	5.28
313.2122192	0.76
315.2235107	1.44
330.2512817	0.51
351.1367798	0.20
377.3453369	0.26
387.2822876	1.80
391.2695923	9.46
405.3510132	0.43
409.3135986	1.62
427.3908691	0.40
439.0580444	0.56
441.06604	1.87
447.5401001	0.72
451.2561035	7.54
493.0773315	0.57
495.5010986	0.41
507.2913818	0.23
517.1717529	0.54
535.3327026	5.00
549.2699585	2.83
552.7173462	0.38
553.3762207	15.59
567.3371582	2.16
571.3777466	5.87
589.5027466	0.85
605.4549561	1.19
617.5460815	0.54
641.4378662	0.32
643.4639282	0.98
661.4501953	0.40
667.2556152	0.17
681.8522339	0.31
694.869751	0.40
735.0358887	0.72
739.8832397	0.14
749.4477539	6.15
763.3984375	0.69
777.4259033	38.68
789.4597778	0.44
790.2061157	0.25
791.3580933	0.30
805.4110107	100.00
806.3622437	4.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3
Annotation	Dicliripariside A
Peak:m/z	Relative Intensity
239.5131226	0.03
241.1033325	0.18
267.1619263	0.03
269.2636719	0.20
271.3931274	1.00
273.1770325	0.01
294.3863220	0.03
299.3294067	1.23
313.1721802	0.02
315.3416138	0.03
317.2453613	100.00
325.2387695	0.01
327.2446289	0.62
337.2808228	0.54
341.0440674	0.06
357.1292725	0.02
369.1843262	0.04
377.1469727	0.01
384.1235352	0.01
391.0949097	0.02
411.1473999	0.02
423.2691040	0.06
449.3414917	0.02
461.3297119	0.02
475.5842285	0.03
478.3263550	0.06
479.4782104	0.01
483.3400269	0.01
485.1232910	0.02
491.6265869	0.01
506.2561035	0.04
511.0934448	0.02
536.5578613	0.03
541.5020142	0.01
564.6821899	0.01
579.5099487	0.02
581.0610352	0.02
593.5477295	0.02
597.0870972	0.01
609.2940674	0.02
611.2047119	0.01
613.6498413	0.03
619.4489746	0.04
622.9037476	0.04
631.8890991	0.08
636.6633911	0.07
637.3836670	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3411
Annotation	Unknow
Peak:m/z	Relative Intensity
246.3701782	0.38
273.2012329	0.09
297.4143982	0.15
299.0229492	0.74
310.9267578	0.16
315.9980469	0.19
318.9750061	0.35
337.0312500	0.19
343.0065918	0.33
357.2644043	0.42
367.0968018	0.25
369.5998535	0.59
375.2801514	0.08
398.4186401	0.07
399.2639771	0.19
414.6141357	0.07
430.4708252	0.14
448.2708740	0.84
449.2845459	0.44
450.2295532	0.06
455.2268066	0.23
458.2733765	0.35
459.1416016	0.26
460.3049316	0.16
461.3789673	0.69
474.3927002	0.23
476.8525391	0.48
478.3542480	0.55
480.1245117	0.66
486.3541260	0.51
490.2377930	0.60
492.1402588	0.49
495.2716064	0.10
505.3177490	0.98
512.0993042	0.12
520.2113037	0.13
522.2686768	1.14
571.1994019	0.06
594.9563599	0.40
595.8038940	0.11
599.2358398	0.24
610.4143066	0.45
611.5704956	0.14
612.2298584	0.13
613.3289795	26.41
619.5277710	0.10
624.4228516	0.18
631.3235474	0.76
632.2218628	0.10
634.0341187	0.39
639.2265015	0.27
645.2707520	12.92
652.3528442	2.70
653.0105591	0.07
654.6239014	0.31
660.3413696	0.12
670.3332520	0.11
675.5297241	0.23
678.4144287	0.60
683.5050659	1.09
684.2073364	7.74
686.2700195	0.47
695.4834595	0.39
697.3630981	0.11
713.3792114	0.29
727.3921509	0.09
731.3861084	0.40
733.0489502	0.21
739.4948120	0.62
740.7952271	0.37
741.5210571	0.12
743.5745239	0.08
757.3798218	1.51
759.6290283	0.23
775.2791138	100.00
775.9304810	0.33
789.3834229	0.34
806.5548706	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1090.05
Annotation	Unknow
Peak:m/z	Relative Intensity
337.4568787	1.62
398.3114014	0.37
425.2951965	0.37
437.2739258	1.60
455.2463684	0.92
457.4708862	1.38
498.4874573	0.91
551.2434082	0.78
557.4553223	1.51
558.6247559	1.65
569.5001221	3.52
570.4688721	0.95
571.4476929	1.51
587.5266724	0.98
589.4635010	7.31
590.4162598	1.63
657.4667969	2.38
671.1531982	1.00
672.7606812	0.90
685.2145996	1.34
685.8276978	0.59
686.6595459	0.44
703.2664185	3.78
704.3372803	0.40
733.5599976	2.53
747.5724487	1.23
749.3551025	0.77
751.4411621	25.50
752.5167847	19.10
787.2965088	0.71
806.5802002	0.68
807.5618896	0.52
808.7058105	0.47
809.3428955	0.68
820.1745605	1.08
833.3385010	3.45
834.4815674	3.25
847.5164795	3.74
848.6082764	2.20
850.3233643	1.32
865.3935547	12.50
866.2303467	7.33
867.0115967	0.40
883.5931396	6.18
884.5987549	2.93
890.9813232	1.20
891.7375488	3.76
909.4205322	100.00
910.4932861	43.60
925.1363525	1.47
927.5076904	4.33
928.7163086	4.58
1027.5629880	19.02
1028.6481930	4.76
1045.2700200	4.60
1046.0886230	1.53
1071.3918460	4.39
1072.6260990	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	260.13
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9590607	87.76
128.9731598	77.58
130.0365448	1.53
131.1195526	2.49
143.9886780	0.28
155.0340729	0.10
168.2126617	0.23
171.9342194	0.09
188.2340851	0.25
197.8063965	0.44
200.1410980	0.26
210.1307831	0.08
214.0125732	0.55
215.9301453	0.15
218.1957703	0.11
223.5358276	0.73
224.1700287	11.29
226.3447723	0.09
232.2108612	0.17
242.1260986	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2176
Annotation	Sorbitan laurate
Peak:m/z	Relative Intensity
95.1806259	0.18
96.0146484	0.20
97.0620117	0.54
98.2544403	0.09
98.9553680	0.03
108.1606140	0.15
111.0318985	0.18
112.1502838	0.06
112.9771423	0.18
115.0716858	0.88
120.9838943	0.08
123.1236343	0.05
124.9789429	1.13
125.9724731	0.51
126.9398193	0.06
129.4785309	0.12
130.2406311	0.47
135.8769379	0.22
141.0452271	0.06
145.3232727	0.10
147.9931030	0.12
153.9897766	0.11
155.3336639	0.51
156.2127380	0.17
160.9832153	0.08
165.1541290	0.39
166.1358185	0.40
167.1670532	0.82
168.2265625	0.17
170.9933472	0.73
172.1539154	0.47
173.1242676	0.09
177.0341187	0.16
178.1217804	0.75
178.9821625	0.43
180.2603760	0.07
181.2417908	0.23
182.0653992	0.85
183.2405701	19.50
184.2311859	26.04
186.2548218	0.20
190.2533875	0.28
192.9897003	0.68
194.0603943	1.47
195.1679077	4.05
196.1862488	6.90
197.9803925	0.76
200.3383789	0.27
204.4306946	0.07
208.2902832	0.64
209.3283386	0.17
211.0876770	32.36
212.1072998	59.41
213.1870728	1.86
214.2004700	1.97
216.0585938	0.10
217.1631165	0.32
218.3107910	1.08
219.2398987	0.08
220.1533813	0.34
222.1032104	0.90
223.1576233	0.37
224.1296997	0.67
225.1753235	0.73
226.3140259	0.15
226.9806213	0.14
228.1969299	0.11
229.3338318	0.80
230.3262329	2.66
231.3265686	0.04
234.0545044	3.32
234.9322205	0.06
236.1340027	0.29
238.1520081	0.59
239.3482056	0.85
240.2115173	1.69
241.4284973	1.18
242.1804504	1.01
243.0837097	0.44
244.2781677	1.72
246.2277527	0.34
247.0987549	0.10
248.2756348	3.82
250.2465820	0.34
251.1805420	2.32
252.1668091	13.10
252.7675476	0.10
254.2468262	0.27
255.2004089	0.72
256.2865906	1.70
257.9821777	0.12
259.0977173	0.10
262.2589722	0.09
264.2884521	0.90
266.3875122	0.88
267.2626648	0.07
268.3986511	0.13
269.2299500	3.87
270.2380371	21.23
274.2863159	3.88
279.3435364	0.06
280.1838989	0.37
282.2048950	0.70
283.4768066	0.14
284.4935608	0.14
290.2872925	1.89
292.2598572	100.00
295.1420898	0.09
296.3130188	0.17
298.4152832	0.06
299.0546875	0.10
300.2981262	0.52
300.9691467	0.10
308.2879028	2.02
310.2350159	54.59
311.5411987	0.06
312.2126160	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1170.5746
Annotation	Unknow
Peak:m/z	Relative Intensity
903.2365723	0.03
994.4626465	0.09
995.3925781	0.05
1087.8255620	0.07
1088.7166750	0.23
1101.6145020	0.04
1103.8955080	0.28
1105.4445800	94.66
1106.4245610	9.50
1107.1699220	0.01
1151.6735840	0.05
1153.8134770	0.09
1217.3229980	0.32
1235.4802250	100.00
1236.4665530	8.97
1237.4643550	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.3019
Annotation	Unknow
Peak:m/z	Relative Intensity
191.1090851	0.04
193.1906738	0.21
205.2207031	0.01
217.2398376	0.02
219.4026947	0.07
225.3482819	0.01
229.2866974	0.02
231.1245422	0.06
235.1533508	0.04
241.1151733	0.02
245.2608337	0.03
257.2048950	0.27
259.1852722	0.16
269.1290588	0.11
271.2444458	0.07
273.1126099	0.09
275.3231506	0.30
282.2590332	0.02
285.2670898	0.46
286.1406860	0.01
287.2156982	1.31
287.8889771	0.03
289.3333435	0.21
301.2762756	0.04
303.4765015	0.08
305.2258911	1.82
305.8620300	0.01
307.3289185	0.51
313.2968140	0.06
315.2957153	0.04
321.3529053	0.02
331.2828979	0.02
333.3169556	0.79
337.1822510	5.00
341.0417175	0.02
349.2536011	2.06
351.2578125	100.00
355.0936890	3.66
363.3321533	0.04
365.3178101	0.07
367.0996094	0.04
367.7167969	0.05
373.0196533	0.01
374.9906616	0.01
381.3265991	0.03
382.2935181	0.13
398.2644653	0.01
411.2778931	0.02
414.1129150	0.02
417.1790771	0.05
419.0146484	0.06
427.5646973	0.02
436.0836792	0.01
453.2980957	0.10
485.1989746	0.02
527.2889404	2.02
527.8905640	0.02
537.2395630	0.03
542.9113159	0.02
544.1884766	0.05
545.4660645	0.05
552.8961792	0.03
569.1616211	0.04
572.8366089	0.01
574.3396606	0.02
575.0700073	0.02
579.9838867	0.05
587.3876953	0.03
595.3408813	0.01
602.8449097	0.01
607.8629761	0.06
612.8470459	0.01
623.1688232	0.02
626.4052734	0.07
629.2797241	0.04
630.0681763	0.04
635.3694458	0.04
643.4393921	0.02
645.1455688	0.02
653.1522827	0.07
654.4232178	0.02
671.2407837	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.8754349	0.90
120.8103256	0.03
123.0333099	1.42
125.2635498	0.01
128.0312958	0.04
137.1164551	0.03
151.9369202	2.99
159.0915527	0.02
166.9544067	100.00
176.8725281	0.04
189.0925903	0.02
209.1890869	0.21
218.0292358	0.02
221.0094299	0.05
229.1810913	0.02
239.1743774	0.04
249.1243286	0.07
284.0098267	0.08
285.2271423	0.15
293.3329163	0.06
311.0997925	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.1117
Annotation	Patuletin 3-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
164.8762817	0.01
225.2431335	0.01
243.3949890	0.02
247.1253052	0.01
253.1412354	0.01
264.9977722	0.08
271.0607910	100.00
272.1341553	0.18
281.2562256	0.07
284.9573669	0.02
309.2553101	0.01
322.9882812	0.01
325.1241455	0.06
326.2981567	0.08
343.1661987	0.01
355.2376709	0.11
357.1069946	0.06
369.3912964	0.01
372.3233032	0.02
372.9867554	0.05
376.4670410	0.04
390.2100830	0.01
405.0026855	0.01
413.2685547	0.02
428.1743164	0.01
433.1189575	2.47
434.0741577	0.06
438.3943481	0.06
450.7030029	0.02
454.9807739	0.01
457.3713379	0.02
464.2460938	0.02
473.6039429	0.10
475.2214355	3.78
476.0365601	0.02
483.2651367	0.04
487.1449585	0.01
500.0465088	0.06
501.1796875	0.70
503.1400757	0.01
518.3768921	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0983
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
125.050766	0.02
129.2269897	0.02
143.1351624	0.07
147.0636902	0.34
148.0320282	0.03
149.0959625	0.02
154.8972168	0.03
160.9458008	0.03
162.9172363	0.06
164.7889404	0.03
179.1025696	0.06
191.0656738	0.04
194.2165833	0.01
199.1034088	0.05
202.5942688	0.13
203.2069092	0.01
213.2060242	0.06
216.9436646	0.06
224.0802917	0.13
225.2088013	0.13
227.073822	0.01
231.1878662	0.01
239.1794434	0.11
241.0918274	0.23
243.2060852	0.03
247.0201111	0.11
252.9492493	0.08
255.4493103	0.08
266.8860474	0.27
269.0490112	100.00
270.0539856	0.26
271.1964417	0.52
279.2312317	0.02
281.1467896	0.24
283.1088867	1.13
293.1571655	0.17
295.4103394	0.09
296.9624634	0.02
298.8305359	0.02
305.2487793	0.01
306.9613647	0.01
309.0246277	0.04
311.1120605	0.98
313.1977539	0.04
323.2139893	0.34
328.9039001	0.16
341.0750732	0.47
351.0636292	0.03
353.1626587	0.25
363.3833313	0.02
368.9567261	0.23
385.2381287	0.11
395.2340393	0.02
413.379425	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3073
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
141.8876343	0.07
179.465744	0.01
198.1002045	0.19
216.0379333	0.11
247.6809998	0.04
265.196167	0.02
307.7895203	0.03
308.4348145	0.46
321.3280029	0.03
322.7163086	0.11
335.241333	0.02
339.2961121	100.00
339.9364319	0.59
419.1255188	0.05
462.1480103	3.59
462.7880554	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1974
Annotation	Manumycin G
Peak:m/z	Relative Intensity
145.8228607	0.26
152.9608612	0.43
156.1638794	0.09
167.2546692	0.35
168.1390076	0.30
179.0389862	2.42
179.9585571	0.05
180.9423828	1.16
182.1942902	0.45
197.1436615	9.29
198.9813843	0.07
212.0354004	0.32
213.2143555	0.25
215.1198273	0.15
217.0317383	0.21
220.3377686	0.15
222.1700287	0.49
222.9862061	1.31
226.9755402	1.44
227.7018433	0.17
239.1577301	1.24
241.1655273	58.79
245.0235291	5.84
249.3149109	0.13
259.0984497	6.62
263.0329285	1.03
263.8208008	0.13
266.2126770	0.69
267.2330933	0.26
284.2616577	0.53
289.4618530	0.07
292.1708374	0.49
293.5005188	0.19
308.0875854	1.11
310.1338196	10.97
326.0361328	0.51
328.2220764	19.87
332.3735962	0.17
334.3442993	0.12
336.9221802	0.05
338.3315430	0.56
341.0804443	0.36
352.0635986	1.39
355.8745728	0.26
357.6347046	0.62
358.2720337	4.20
359.3450928	0.22
370.1732178	0.20
374.1615601	0.54
376.2481689	11.63
377.3065186	1.19
378.3165894	0.10
390.1831360	0.07
392.0559387	0.22
394.6750488	0.21
395.3776245	3.23
413.3840942	1.78
421.2440491	4.28
421.9604492	0.20
439.1613159	26.53
443.0383606	0.80
444.3173523	0.24
457.1971741	47.86
458.0728149	0.12
461.3872375	0.31
469.2644653	5.03
487.2000122	100.00
488.2044067	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	712.4918
Annotation	PE(19:0/13:0)
Peak:m/z	Relative Intensity
214.2705078	0.12
221.3378601	0.05
233.2000732	0.84
234.3382874	0.14
240.8630371	0.02
255.2001953	36.78
256.2662048	8.06
257.0401306	0.03
259.3038330	0.57
260.2341919	0.20
275.2647095	1.13
277.2862549	100.00
278.2753601	19.70
279.1313477	0.02
339.0935669	0.04
378.4329224	0.09
391.3202515	0.25
392.1893311	0.46
401.3318481	0.02
416.0485229	0.03
434.3698730	1.28
435.2940063	0.59
447.4438477	0.11
452.3070679	15.19
453.2985229	5.13
453.9472656	0.06
456.3582153	0.57
457.2555542	0.46
474.3562622	2.50
475.4234009	0.66
536.9600220	0.06
583.0584106	0.11
653.2959595	0.12
694.8347778	0.02
695.5704956	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.2561
Annotation	Wanepimedoside A
Peak:m/z	Relative Intensity
209.2027740	0.52
226.9236603	0.73
252.0574799	0.13
258.2024231	0.05
270.3370056	0.06
271.4611816	0.06
276.2652588	0.09
288.2423096	0.13
289.2967834	0.03
291.0529175	0.53
292.1887817	0.05
304.2365723	0.13
311.7422485	0.19
319.1352539	0.05
328.1559448	0.19
329.0332336	0.16
330.0814819	0.06
340.0695801	1.26
341.0505981	0.16
342.2333984	0.10
347.1437988	0.12
354.2454834	0.04
357.6687012	0.12
358.2840576	1.61
366.1669312	0.10
380.1315308	0.29
386.3777466	0.06
390.2103882	0.82
398.3057861	0.21
402.2764893	0.14
408.1745605	0.09
411.1831665	0.21
412.0681763	0.19
415.0534668	0.17
416.3492432	0.55
419.3190308	0.46
420.0303345	0.32
425.2501221	0.04
431.3297729	0.11
433.0883179	0.34
437.3056030	0.07
439.0146484	0.06
443.1828613	0.31
444.1963501	0.14
447.6751709	0.07
461.2431641	0.25
478.9695435	0.03
481.1465454	0.08
487.4840088	0.30
488.4813843	0.06
494.8887939	0.13
497.1785889	0.89
498.4172363	0.30
505.0747070	0.49
509.1133423	0.10
514.3544922	0.24
515.1918945	1.19
516.3316650	0.22
517.2032471	0.40
527.1567993	0.24
528.8751221	0.11
533.2260742	8.10
546.1166992	0.08
547.9032593	0.05
548.5080566	0.19
550.2971802	100.00
550.9327393	0.16
554.3651123	0.07
572.3979492	0.69
575.0895386	0.14
590.3380737	7.11
590.9447632	0.07
599.3922729	0.03
615.3263550	0.06
616.6135254	0.31
630.2495728	0.09
633.0485840	0.18
643.3115845	0.33
646.9138794	0.14
651.1036987	0.09
661.3381958	3.92
662.3778687	0.10
680.2551270	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.3129
Annotation	Glaberianthrone
Peak:m/z	Relative Intensity
221.1174622	1.72
222.0155945	0.38
236.0152283	0.31
257.0707703	0.14
262.7932739	0.50
263.9987183	0.44
283.3338013	0.47
323.3131104	0.58
379.3404541	0.40
437.0750732	0.50
447.2556152	3.33
453.6253052	10.42
463.4196167	8.69
464.0304565	0.28
470.0814819	1.37
481.1889038	1.73
488.8663330	0.53
497.6169434	37.53
511.2714844	1.66
519.5494385	0.39
520.4893188	0.88
533.3123779	20.98
534.1798706	0.08
542.3948364	14.44
551.3662109	1.47
569.6201782	0.72
570.2852783	0.11
571.3152466	0.94
573.3655396	0.70
601.6115112	8.32
610.3894043	6.57
611.0253296	1.51
623.4702148	3.04
625.2273560	4.28
626.1778564	1.39
627.2772217	1.77
629.0607910	0.64
632.3320923	17.13
632.9960938	10.05
649.2161865	0.69
651.1799316	0.68
661.0602417	0.41
667.2633667	4.01
669.2050171	0.30
674.0487671	0.51
682.5479126	9.71
683.2726440	0.44
695.5772095	2.32
703.5193481	0.76
704.3027954	1.42
704.9121704	0.64
729.5219727	0.30
750.9911499	0.55
769.1968384	0.45
865.2631226	1.63
878.1677246	0.19
879.3442993	1.59
880.4160156	0.18
881.2107544	2.51
895.5795898	0.45
906.8723145	0.31
909.4680176	100.00
910.4709473	35.90
911.4506836	1.37
925.4574585	2.69
927.4785156	42.65
928.5822144	12.03
956.8527222	0.23
957.5349121	0.18
966.3134155	0.16
969.7739258	1.87
970.4811401	1.82
973.7725220	0.31
995.5183105	1.87
996.5150757	0.13
998.1481323	0.19
1009.3515620	5.06
1010.3308720	2.85
1020.6199340	0.24
1023.4797360	9.07
1024.4990230	3.75
1027.3822020	0.36
1028.4372560	0.33
1041.5673830	6.75
1042.4182130	2.05
1059.4377440	0.59
1060.5678710	0.68
1067.3413090	7.34
1068.4389650	6.93
1069.6346440	0.31
1071.5286870	0.39
1072.2712400	0.14
1085.4162600	58.88
1086.4199220	29.10
1089.5949710	3.28
1090.4808350	2.57
1162.9680180	1.20
1185.4620360	1.48
1186.7880860	0.79
1190.3083500	0.54
1203.5871580	2.03
1204.7905270	0.22
1233.4283450	0.31
1234.4010010	0.32
1251.4659420	14.74
1252.5772710	6.12
1253.5814210	0.51
1280.4874270	0.90
1351.7288820	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.3066
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1427307	0.02
221.1611023	0.02
232.7458801	0.07
234.1046448	0.07
235.1784668	0.20
239.0411072	0.12
254.0570374	0.08
265.4786377	0.05
266.3507080	0.06
277.1369324	0.05
282.3143311	0.04
284.6412354	0.03
287.1223755	0.05
289.4173584	0.03
294.8182373	0.04
297.6309814	0.19
298.3410339	0.02
313.1927490	0.21
321.2723999	0.11
326.4676514	0.07
327.1038208	0.23
330.0820923	0.14
337.2623291	0.43
341.0873413	1.13
343.1605225	0.07
346.5134888	0.07
347.5366211	0.03
354.9539185	0.11
367.0353394	0.22
371.1701660	2.31
377.3496094	0.03
379.1642456	0.10
381.4705811	0.19
386.2992554	0.06
389.0993652	0.82
391.4871216	0.18
395.1453857	0.02
403.2604980	0.07
409.4932861	0.07
413.0584717	0.33
419.3768311	0.07
423.0484009	0.05
429.3654175	0.06
431.2745972	0.43
434.4492798	0.23
436.4241943	0.12
443.1667480	0.05
460.0929565	0.08
461.2042236	0.07
472.9562988	0.18
475.6325684	0.11
477.0357056	0.04
478.5404053	0.06
485.0812378	0.36
489.1623535	0.02
491.0701294	0.18
505.1176147	0.17
509.2250977	0.03
514.9772949	0.09
519.1336670	0.02
520.6369019	0.06
541.4113770	0.09
543.2189941	0.03
551.1889038	0.23
555.2937622	0.04
559.5075073	0.04
561.2645874	100.00
569.7084961	0.01
572.2212524	0.07
575.5136108	0.04
577.2317505	0.12
580.3689575	0.02
581.3451538	0.16
584.5353394	0.07
589.1107178	0.10
591.8505249	0.04
593.0275269	0.10
595.2693481	0.59
606.2747192	0.06
637.3106079	0.07
638.4497681	0.03
647.0714722	0.05
649.2242432	0.36
666.5764771	0.06
670.5702515	0.12
681.2662964	0.79
688.3822632	0.01
691.1836548	0.03
695.4218750	0.02
697.3885498	0.11
702.0700073	0.06
709.1732788	4.62
710.1707764	0.06
711.0539551	0.09
712.0608521	0.10
713.4265747	0.15
721.4403687	0.04
725.4541016	0.03
726.1516724	0.14
727.2203979	0.36
734.7280273	0.63
735.4114990	0.12
739.2575073	6.38
740.2590942	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1351
Annotation	Syringetin 3-galactoside
Peak:m/z	Relative Intensity
148.8211975	0.05
150.9582062	0.97
159.3478546	0.01
164.9850769	0.06
174.8406677	0.01
176.0889893	0.02
177.0306702	0.55
179.1271973	0.13
198.9122009	0.03
205.2166443	0.05
215.3206635	0.01
221.0759430	0.04
223.0883942	0.04
224.9451752	0.03
230.3907928	0.01
239.2297668	0.08
240.2823029	0.06
242.1269379	0.05
257.1121216	0.02
258.2239075	0.04
269.2312622	0.02
281.1506348	0.09
283.3705139	0.03
286.2442627	0.18
289.1227417	0.03
301.0893555	100.00
307.1464844	0.01
325.2373047	0.11
327.3542786	0.06
328.9403992	0.02
343.1462402	0.66
356.2393494	0.01
361.3414917	0.59
367.7240295	0.03
387.4948425	0.01
395.0658264	0.04
402.2919922	0.02
403.3947754	0.28
409.3215027	0.01
431.4012146	0.01
440.0999451	0.06
440.9105835	0.03
445.2388916	1.15
463.2173462	1.48
487.1157837	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2655
Annotation	Phaeantharine
Peak:m/z	Relative Intensity
223.2689209	0.05
286.3049927	0.10
289.3390503	0.05
290.6248169	0.15
309.2068787	0.13
320.3430176	0.04
323.1019287	0.07
337.2005005	0.05
342.0753784	0.13
353.9418335	0.04
365.3722534	0.08
366.2644043	0.08
367.2738647	0.10
387.4102173	0.34
388.4725342	0.05
408.2767944	0.09
417.1614380	0.03
437.1276855	0.05
451.1867676	0.10
463.2150879	0.05
465.3659058	0.12
467.0362549	0.04
471.4041748	0.11
477.0493164	0.15
489.1610107	0.03
497.3413696	0.07
509.1965942	0.07
519.4533081	0.14
524.6246948	0.03
541.7011719	0.04
542.9973755	0.14
550.7505493	0.10
563.4525757	0.03
567.4351196	0.21
569.1347656	0.38
575.1854858	0.05
576.1351929	0.05
581.1403809	0.15
583.2860718	100.00
583.9178467	0.22
585.2289429	0.28
593.2809448	0.27
597.1325684	0.34
606.6425781	0.15
611.3670044	1.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1402
Annotation	Gerfelin
Peak:m/z	Relative Intensity
161.0366669	5.84
164.1865387	0.22
165.3475189	0.21
172.2872925	0.08
173.0561981	0.22
175.2322998	0.34
177.0751343	0.04
186.0990906	0.29
187.1211548	0.38
187.9596558	0.15
200.7266846	0.47
203.0273895	0.53
205.0860291	0.27
208.2666168	0.08
211.2427521	0.28
215.1506042	0.10
216.9299622	0.05
226.9341431	0.41
227.9852295	0.43
229.1235809	0.58
229.7980957	0.10
230.9071655	0.08
243.1406403	1.46
244.0791016	0.71
245.1376495	4.85
247.0498352	0.14
255.1380615	1.11
256.2740479	0.15
259.1621094	0.16
260.9378662	0.13
263.2012329	0.42
268.6203613	1.13
269.3132935	0.96
271.0844727	3.02
273.1340332	42.66
274.2622070	0.08
281.3953247	0.11
283.1091309	0.46
285.0994568	0.14
287.0948486	34.58
288.0548706	0.25
289.1726074	14.99
290.2460327	0.60
291.0933838	0.34
297.1250000	0.08
299.1183472	42.49
311.2711182	1.67
312.2223511	0.20
313.1491699	0.60
315.3356323	0.06
317.2243042	0.13
320.5107422	0.10
323.2145386	1.05
325.2397461	0.32
328.1296387	0.68
329.1718750	2.94
331.0841064	0.32
332.0180664	0.16
333.2943726	0.06
337.1853638	0.19
341.2819214	0.24
347.0821533	0.07
349.1243286	0.07
352.6666870	0.11
353.4104614	0.14
357.1867676	0.15
361.3098755	0.12
364.6551514	0.24
365.3211060	2.81
367.0394897	0.20
377.2067871	1.06
379.3367920	0.06
381.1265869	1.08
383.2316284	0.32
389.4027710	0.06
391.1412964	9.71
392.2699585	0.07
393.3141479	0.77
394.5424194	0.62
395.3475342	0.46
397.0759888	0.07
398.0812378	0.23
405.2951050	0.03
407.1789551	7.67
409.1497192	100.00
410.1102295	0.17
411.1733398	0.16
413.0093384	0.13
417.0156250	0.47
417.6397705	0.20
420.4153442	0.28
421.3042603	0.18
423.2467041	2.14
425.1993408	17.87
427.4216919	0.37
431.1387939	0.12
433.2263794	1.26
435.1082153	86.67
436.4031372	0.94
437.3575439	0.08
439.2445068	0.80
443.2545776	0.07
449.2318726	0.09
451.1567383	1.45
453.7410278	0.06
456.2204590	0.13
459.1259155	0.27
467.1957397	0.14
470.5189819	0.16
472.2780762	0.09
474.6463623	0.76
475.9924927	0.58
477.1796265	0.19
483.5919189	0.46
484.3479614	2.83
488.1666870	0.07
492.5427856	0.61
498.6766968	0.17
499.2886963	1.66
503.0763550	0.12
514.9567261	0.54
517.1795654	6.55
519.4150391	0.19
525.0230713	0.32
532.3812866	0.10
543.1289673	15.21
543.9551392	0.58
552.1405029	0.37
569.1707764	0.13
571.0643921	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.17
Annotation	beta-D-Glucopyranosyl-11-hydroxyjasmonic acid
Peak:m/z	Relative Intensity
113.0251846	1.42
118.8199005	0.74
124.3959808	0.10
128.9575500	0.87
131.1435699	0.93
135.2395630	0.32
143.0013428	1.33
145.2499847	0.15
146.9452820	2.57
148.9141541	0.28
158.9988556	0.71
160.9464722	2.43
163.0606995	100.00
164.1879883	1.02
165.0181580	0.26
166.0388489	0.50
179.0061951	0.35
190.9367981	4.94
192.1211853	2.61
193.0230713	6.40
206.9518738	4.98
209.1705627	1.49
210.0247192	0.45
211.1559753	1.08
217.0207520	0.12
225.1159058	2.31
226.9952393	0.18
234.8334961	0.12
245.1578674	0.10
251.8706055	0.52
273.0604248	0.37
274.3355713	0.08
276.9264221	0.64
294.1163330	0.17
295.1144714	0.27
341.2198181	9.55
343.3183594	0.88
345.1593628	0.35
351.0526123	0.10
369.1653748	30.86
370.1532898	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.2522
Annotation	Unknow
Peak:m/z	Relative Intensity
158.1723785	0.15
159.3106995	0.11
162.7686310	0.06
165.1350555	0.84
173.2781372	0.13
175.0603638	16.78
179.0455627	0.27
191.0018158	0.39
193.0928040	25.70
202.9456482	0.14
207.3026886	0.10
208.9688416	0.08
211.0301361	100.00
211.6751099	0.20
213.9844055	0.19
215.0314331	0.23
225.2677765	0.06
226.9824066	0.30
230.9810638	1.06
232.0750885	1.28
233.1138306	0.87
243.3652191	0.36
244.0206909	0.63
245.2520447	0.27
250.9687195	0.05
254.8605652	0.43
256.1123352	0.61
257.1834717	0.13
260.3380737	0.09
261.2302551	0.18
262.3239136	0.35
265.4136353	0.09
269.3610229	0.25
270.2617798	0.25
271.2556763	0.15
273.1212769	0.68
273.9846802	1.06
275.1011963	5.03
276.2270203	3.55
277.0983276	3.24
278.2483521	0.14
282.2566528	0.20
285.1156311	1.55
286.2621765	1.51
287.1987915	1.61
288.1729126	1.68
289.0972900	0.71
298.2612305	0.15
299.0714722	0.43
300.1021118	0.19
301.0115051	1.77
317.1290283	0.13
320.2689209	0.35
321.1567993	0.25
338.9265747	1.38
345.1362915	0.23
350.4525146	0.04
351.8314819	0.08
357.3055420	0.08
372.4438477	4.99
373.0992432	57.58
379.1331787	0.48
380.3240967	0.47
381.2636108	0.90
381.9740601	0.08
387.0830078	0.15
392.3443604	0.88
393.1669922	3.18
394.2066040	6.92
395.1502075	5.44
395.8851929	0.45
398.2303467	0.07
404.4183960	0.11
405.2509766	0.55
407.1833496	0.36
410.2667236	0.14
411.3864136	4.04
412.1842041	9.64
413.0977783	8.08
414.0361328	0.12
421.3759766	0.05
422.0145264	0.85
423.1812744	1.81
424.2124634	2.05
425.1870728	1.07
429.3498535	0.07
432.8952637	0.06
437.7869873	0.61
451.3253784	0.22
453.7005005	0.08
467.9235840	0.15
473.1085205	0.28
480.6927490	0.17
483.5466919	0.22
487.3900146	0.06
495.1562500	0.02
502.4241333	0.08
505.3915405	0.06
506.3312988	0.24
508.3505859	0.21
512.1843872	0.32
513.1478271	1.07
519.2349854	0.15
522.2191772	0.35
528.9747925	0.38
530.6697998	2.45
531.3325806	2.09
550.0972290	0.18
558.5393677	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0967
Annotation	N-Malonyltryptophan
Peak:m/z	Relative Intensity
88.0072937	0.03
90.8139801	0.02
103.9135284	0.01
109.1116333	0.06
114.9775543	0.01
117.9030609	0.22
118.9874954	0.03
122.9272919	0.02
130.0027313	3.94
137.1773682	0.03
138.9165955	0.11
144.0603180	0.02
145.1048737	0.01
149.0656433	0.07
150.9866638	0.04
155.9421997	0.12
159.1101990	1.40
161.1198120	0.05
162.0462341	0.04
162.9788971	0.10
164.9875336	0.02
169.1430664	0.03
170.1124573	0.08
172.7196503	0.02
174.0073853	1.47
177.2947693	0.05
184.0064697	0.03
188.0041809	4.70
189.1152649	0.03
190.1143341	0.02
191.0112305	0.05
195.0209198	0.01
196.9660339	0.03
201.0847473	0.76
202.1488037	0.07
205.0854187	1.17
211.0233459	0.19
213.2546692	0.07
217.2635193	0.02
218.0106506	0.19
218.9689636	0.06
227.0166016	0.01
229.1662903	3.12
231.2235718	0.06
237.3045044	0.12
245.0370483	23.94
247.1330566	5.13
255.1059875	0.88
263.2041931	0.11
273.0206604	100.00
275.9595337	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	939.4966
Annotation	Hoduloside I
Peak:m/z	Relative Intensity
275.1663513	1.14
307.4293823	1.07
324.3988647	0.66
367.1600952	0.58
377.5034790	2.50
391.4217529	5.64
407.3349609	10.99
421.1555176	0.59
423.5914307	6.19
435.4262695	9.66
436.7023315	1.17
437.3679810	3.43
453.4142456	5.20
455.4722290	28.24
463.5765381	1.51
473.2182007	0.74
479.3793945	2.30
480.3151245	0.37
489.6292114	1.60
495.4123535	0.92
523.3802490	41.55
525.5707397	1.27
551.3179932	5.35
569.2714844	2.98
595.1368408	14.51
613.4242554	71.56
631.7304688	4.96
632.3605347	0.72
646.2933960	4.47
665.3371582	3.06
713.0388184	0.74
727.4370728	1.22
731.3920288	45.05
749.4887695	9.32
775.4877930	1.56
793.3626099	23.63
794.8352661	1.73
795.5226440	0.83
839.5345459	1.52
849.1094360	0.44
871.1831665	1.06
877.3921509	46.98
893.4367065	4.05
921.3644409	100.00
922.1113892	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	907.5735
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
256.9052429	0.58
282.1466370	0.52
300.6418457	0.17
313.2925720	24.46
313.9173889	0.07
393.1852417	2.39
436.2382812	18.23
454.1867676	100.00
454.8458862	0.23
687.5357056	0.13
691.2979126	0.23
727.8426514	0.04
777.2725220	0.10
787.6418457	0.25
789.3874512	0.14
830.3499756	0.14
844.9353027	0.23
845.8259888	0.50
861.3877563	0.25
862.0035400	0.30
889.1094971	2.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	665.3141
Annotation	Unknow
Peak:m/z	Relative Intensity
197.9998474	0.64
225.0941772	0.39
243.4669495	0.82
244.1103210	2.45
261.0907288	100.00
387.2173462	0.20
405.1282959	0.05
421.0120850	0.18
448.0512085	0.08
467.2208252	0.29
476.9854126	0.20
511.3674316	0.18
532.3298340	0.10
535.6060791	0.19
536.5243530	0.91
569.4736938	0.32
585.2761841	0.28
646.7382202	0.13
647.4262695	0.43
668.4288940	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.1503
Annotation	Unknow
Peak:m/z	Relative Intensity
153.2187805	0.02
171.0592651	0.06
198.8450623	0.05
201.9714508	0.04
219.0886230	0.01
224.7468872	0.06
229.1136780	0.52
229.9902954	7.57
235.8392639	0.02
241.2593384	0.08
247.0859375	3.80
248.0622253	0.16
249.8892822	0.12
253.2771912	0.05
265.0468140	5.94
271.1251831	1.80
277.9668579	0.55
297.9808960	0.08
299.1463013	0.19
302.0714111	0.03
316.2728271	0.26
317.1784668	0.11
319.1713867	0.22
328.0571289	0.10
330.4156494	0.02
334.0664673	0.31
336.2271118	0.02
337.0980225	0.38
345.8405151	0.06
347.1088257	1.73
358.0569458	0.04
363.8207397	0.41
365.1234131	11.62
376.3469238	0.34
382.0899658	100.00
382.9212646	0.01
394.2785034	0.13
427.0795898	0.33
430.1131592	0.05
445.1787720	0.06
448.0974731	0.53
451.5366211	0.01
463.3537598	0.04
475.2883911	0.05
493.1665649	3.13
494.2411499	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	452.2763
Annotation	PE(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
137.0364685	0.38
138.8096008	0.25
142.1654816	0.10
154.8859406	0.43
156.5463715	0.12
159.1977234	0.17
173.2006378	0.12
184.0688477	2.03
216.0881653	0.09
219.2211304	0.16
227.2069092	0.78
237.2121124	1.89
239.1549683	0.17
266.3426208	0.17
272.2333984	0.39
280.3452759	1.33
291.4996338	0.18
298.0209045	0.10
311.2708435	80.37
314.1530151	0.26
348.0192566	0.54
359.3863220	0.23
379.2378845	0.44
387.9581604	0.25
390.9930115	5.87
391.7608948	0.04
392.3645020	0.23
405.2204895	0.33
405.9925232	0.82
409.0535889	0.83
414.2969360	0.17
416.3656921	0.17
420.0322571	0.32
422.3317566	1.00
424.1417847	0.82
429.9557190	0.26
432.3982849	0.31
434.1392822	100.00
434.9368286	1.42
443.7428284	1.51
458.4523621	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	Gerfelin
Peak:m/z	Relative Intensity
93.0625610	0.07
97.1065369	0.12
106.7688751	0.08
108.1280212	0.09
109.0000687	0.49
121.0128860	0.12
122.9878006	0.71
125.0687714	1.69
135.0477295	0.78
137.0238953	2.47
138.3533630	0.04
139.0957336	0.22
145.1166382	0.03
147.0672913	0.14
149.0564575	0.04
151.0401306	1.78
152.0066223	0.03
153.0615540	0.04
158.9790649	0.75
161.0326385	1.95
162.0203857	0.36
162.9812775	0.26
164.2243042	1.27
165.0301666	2.17
166.9478760	1.28
173.2139587	0.03
173.9824982	0.02
175.0429535	0.74
176.8374634	0.06
179.0005951	11.72
180.0509949	0.11
181.1353455	0.08
185.1569824	0.13
186.0799866	0.33
186.9271851	1.13
188.0398865	0.88
188.9949646	0.04
191.2924805	0.08
199.3126526	0.05
201.8079834	0.80
203.0664062	7.94
204.9831848	28.97
205.9234314	0.18
209.2310791	0.02
212.1733398	0.09
217.1449890	0.66
220.7676086	0.07
227.0912170	1.91
229.9245605	0.42
231.1210022	5.32
245.0765076	100.00
245.9855957	0.15
247.0371704	5.92
248.1723022	0.03
271.1501465	4.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8501129	1.16
251.2701416	0.01
290.8128662	13.59
344.4190063	0.02
367.4956665	0.05
374.6112061	5.75
387.2685547	0.35
406.2321167	0.01
456.0417480	0.26
458.5177002	100.00
459.2349243	0.24
496.8779907	0.03
498.3344727	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	621.1816
Annotation	Isocrenatoside
Peak:m/z	Relative Intensity
188.7942200	0.29
195.1670227	0.09
197.1757812	0.07
199.7885132	0.13
204.9847107	1.30
231.0516205	0.14
237.0809631	0.79
249.0880737	0.80
261.9962158	0.15
279.1251831	0.58
280.0964050	1.17
281.1491394	100.00
341.7451782	0.05
353.7233887	0.07
356.6697998	0.06
367.8745728	0.13
373.1318359	0.17
380.1995239	0.22
398.0260620	0.04
404.2586670	0.13
415.4440918	0.15
419.0613403	0.07
429.6651001	0.09
431.2290039	0.37
434.0164185	0.24
443.2371826	0.08
448.0230103	0.28
451.3234253	0.13
475.8315430	0.10
476.8335571	0.06
477.9118652	0.39
481.2595215	0.18
486.0871582	0.88
487.9423828	0.11
488.8944702	0.42
490.1962280	0.10
492.0679932	0.29
506.1434937	0.43
522.1456299	0.25
524.9872437	1.30
534.6952515	0.07
535.9882202	0.20
561.0585938	0.18
577.0841675	0.60
578.0607300	0.36
578.8439331	0.12
580.0908203	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.247
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
99.0143051	0.16
107.2526855	0.05
108.9154587	0.10
111.2142792	0.03
112.9200516	0.20
114.9503632	0.25
117.1351318	0.03
119.2937012	0.05
123.0643921	0.21
124.8637772	0.09
126.6503448	0.06
128.9244232	0.10
131.0371246	0.04
132.9185486	0.05
135.0146179	0.17
136.8320618	0.08
141.1008301	0.03
143.1798859	0.05
148.9203186	0.16
150.9633179	0.18
154.9082947	0.06
158.8104858	0.13
160.9870605	0.07
163.0938416	0.24
164.8449097	0.04
167.0491943	0.20
169.1017151	0.15
170.4598694	0.08
171.0801697	0.25
173.0014648	0.11
175.2158508	0.14
177.2197113	0.02
179.1015167	0.22
181.2274780	0.03
182.9581909	0.16
185.0309753	0.18
187.2047729	0.09
189.1614990	0.05
191.1736908	0.40
193.1794891	0.03
195.2246552	0.14
196.9732361	0.19
199.1484833	0.09
203.0216675	0.21
204.9809418	0.50
207.3468170	0.07
209.1150818	0.68
211.2239685	0.07
213.2713928	0.11
214.3038330	0.03
221.2753601	0.25
221.9559937	0.07
223.1062927	0.22
225.1619263	0.69
226.9298706	2.46
231.2737427	0.13
235.0853271	0.07
237.2072144	0.61
239.3801575	0.03
241.2945557	0.99
243.1938171	0.03
247.3129883	0.05
248.9528198	0.11
253.1072388	0.40
254.9753723	0.76
257.0547791	0.08
259.2012939	1.81
264.0354919	0.04
268.1402588	0.13
269.3098145	0.06
270.1925659	0.02
270.8879395	0.09
273.1248779	0.06
277.1561279	23.77
277.8369141	0.08
282.0407410	0.04
285.1228027	0.93
289.3196106	0.02
290.2315063	0.02
295.1613159	40.29
295.8890991	0.34
296.9261780	0.02
303.2106018	0.24
307.6391602	0.17
310.6549377	0.31
311.5368347	0.15
313.0697327	100.00
313.9147644	0.49
321.5571289	0.36
322.9343872	0.11
332.1949158	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1101.5483
Annotation	Protoprimulagenin A 3-[glucosyl-(1->3)-galactosyl-(1->4)-[rhamnosyl-(1->2)]-glucuronide]
Peak:m/z	Relative Intensity
347.1437988	0.19
363.3801575	0.13
379.2464600	0.35
387.2154541	0.14
391.0928040	0.14
393.3173218	0.10
419.2478027	0.12
437.4846497	0.77
439.8262634	0.24
441.6433411	0.32
451.4768066	0.06
455.3567200	1.21
457.4493408	1.43
459.5008240	0.05
463.3545227	1.95
465.4557800	4.20
477.4320679	0.34
481.0859070	0.84
483.4555664	1.60
495.6978149	0.51
499.2894287	0.62
507.4994507	0.12
509.4666138	8.66
525.3793945	1.74
527.2932739	0.80
551.4300537	3.62
553.3888550	0.10
555.5488281	0.13
577.0164795	0.14
579.4273682	0.36
583.3504639	10.03
599.4434204	1.10
601.0179443	0.34
601.6486816	0.25
609.3287354	0.13
615.4788818	0.30
623.4515381	0.97
641.4251709	0.70
669.4938965	18.36
683.7248535	0.21
685.4111328	2.17
715.6226807	0.40
733.4171143	2.31
736.3825073	0.46
737.2491455	0.10
741.2671509	6.33
759.3883057	10.70
775.6353760	0.16
777.4298096	2.28
785.2965088	0.30
803.5402832	0.93
821.6499023	0.56
859.8326416	0.16
877.4055176	2.44
895.3811035	3.14
903.4919434	0.75
921.5662842	2.63
927.5426025	0.24
931.8000488	0.28
939.4602051	6.44
941.4749756	1.27
953.3538818	1.08
955.5988770	0.20
957.5688477	3.52
965.4310303	3.01
973.3491211	0.68
974.2622070	0.46
983.4322510	100.00
984.1494141	2.29
987.3273926	1.05
989.5156250	0.17
1001.4975590	0.42
1021.4270020	0.60
1027.3289790	0.63
1037.5718990	0.10
1039.4587400	41.13
1055.7631840	0.21
1057.4072270	2.48
1079.7556150	0.39
1083.4494630	16.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	525.1669
Annotation	Unknow
Peak:m/z	Relative Intensity
167.2060699	0.13
170.0948029	0.09
188.0104980	0.03
198.0447083	0.21
201.9000854	0.03
215.0660095	0.11
215.9348145	0.04
232.9535675	0.02
243.4104004	0.77
244.2438660	0.13
246.9676514	0.20
248.2753296	0.33
261.1424561	5.73
265.1376953	12.35
276.8925476	0.03
279.1467285	0.37
285.0529175	0.03
287.3959961	0.02
288.2675781	0.14
290.2468262	0.09
297.3565063	0.06
311.8938599	0.10
313.4105225	0.04
329.9893188	0.47
331.1478271	0.09
332.2042236	0.22
333.0965576	0.19
345.5612793	0.03
348.1488037	1.21
349.2043457	0.04
350.1170654	0.33
354.6962280	0.11
360.2192993	0.08
361.1851196	0.28
363.0394287	0.07
363.8792114	0.09
372.2637329	0.09
378.0391235	0.84
379.1589966	0.52
382.1723022	0.12
390.2561035	0.09
396.1056519	100.00
396.7672119	0.35
419.5225830	0.07
436.2664185	0.03
437.5528564	0.07
441.1181030	0.38
447.3189697	0.16
459.2546387	0.68
461.2912598	0.49
462.2222290	0.55
463.2023315	0.09
465.0516968	0.09
477.0757446	0.28
479.1248169	0.02
481.2302856	0.54
488.9072876	0.18
489.9500122	0.03
507.1793213	3.41
508.0385132	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3384
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.2062378	0.11
175.2461548	0.11
184.0347900	38.08
258.2426758	0.38
337.3406372	0.12
439.0319824	0.11
443.4217529	0.18
471.5596313	0.08
502.3990479	100.00
503.0685425	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	269.1031
Annotation	Benzyl beta-D-glucopyranoside
Peak:m/z	Relative Intensity
92.8600159	0.02
97.4138794	0.02
100.9819489	0.04
105.0290527	0.04
109.2788849	0.01
122.9850311	0.22
135.1381683	0.09
137.2074585	0.03
143.0495758	0.02
147.0421295	0.02
149.3331146	0.01
151.3311615	0.04
153.1872253	0.65
163.1818085	0.89
168.6229095	0.04
169.4409637	0.01
176.0382538	0.01
179.1448975	0.55
181.1673431	0.49
188.9007416	0.01
197.1428375	0.09
207.1646881	1.52
208.8267975	0.01
211.0536957	0.03
223.0368652	0.03
225.1013947	100.00
237.0280609	0.03
241.1731415	0.06
241.9822845	0.02
251.1504974	3.34
253.2308197	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2551
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
201.2362061	0.03
343.3568726	0.44
347.4117432	0.16
361.0871582	0.74
365.2942505	85.27
367.4395752	0.03
375.2115479	0.04
377.3338623	0.05
379.3711548	0.15
389.1463013	1.13
407.1533813	2.91
407.7561035	0.02
419.3991699	0.54
421.0839233	0.13
435.5618896	0.04
437.2182617	0.97
447.1932983	0.09
448.7245483	0.28
449.4124756	0.40
453.1290894	0.20
466.8098755	0.11
479.4118652	0.07
509.1713257	0.10
525.3024292	0.04
527.1158447	100.00
529.1400757	0.06
554.9425659	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1616
Annotation	Unknow
Peak:m/z	Relative Intensity
174.5590668	0.10
176.0460510	0.04
178.6869507	0.05
191.0101776	0.08
195.1423492	0.03
203.0810547	0.38
205.0296021	0.03
209.1757660	0.05
257.1984253	0.11
265.1014404	0.02
268.1718750	0.02
287.0823975	0.06
293.1967163	0.38
297.0647583	0.03
305.0697632	0.05
320.2280884	0.13
321.2819824	0.19
323.2424927	0.09
329.1783447	0.09
335.2805786	0.05
349.0637207	0.20
371.1654663	0.03
385.0203857	0.17
386.1531372	0.12
387.3461914	0.56
391.2499390	0.10
401.1112671	1.79
401.8438110	0.03
419.1845093	100.00
437.1752319	0.18
444.4744873	0.11
445.3601685	0.03
448.9184570	0.06
459.2028809	0.21
461.1250610	37.66
461.7536011	0.07
465.2780762	0.13
473.3879395	0.15
501.1895752	9.31
502.5420532	0.12
514.4257202	0.05
544.3500977	0.87
545.3143921	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2706
Annotation	Ixerisoside J
Peak:m/z	Relative Intensity
161.2346497	0.03
163.0198822	0.09
179.0047913	0.11
188.0617828	0.05
191.2744598	0.19
192.9745483	0.22
197.1628113	0.21
201.0610657	0.17
203.1342468	0.05
205.3625031	0.08
213.1095276	0.10
216.9104919	0.20
225.0111237	0.09
226.9418335	0.11
229.0839844	0.20
235.1351624	0.12
237.1390686	0.27
241.1684418	0.69
243.0988464	0.05
245.0986938	1.09
249.2975311	0.04
257.1643982	0.73
259.0999756	0.18
263.2082520	0.08
264.9879761	0.23
267.1883545	0.03
269.0333862	0.10
271.0419922	0.39
272.8710022	0.07
275.3313599	0.17
281.1190186	0.03
285.1359253	3.81
287.1252747	2.21
289.1014404	3.35
290.3789978	0.16
295.1822510	0.04
297.1376343	0.79
299.1470947	0.23
299.7526855	0.05
301.1050110	0.48
301.9928589	0.15
303.1300049	0.97
305.0079346	0.05
309.0617676	0.12
310.3583374	0.11
311.0585938	0.06
312.9300232	0.22
319.3878174	0.04
325.1840210	0.34
327.1858521	2.75
328.2032471	0.31
329.1556396	1.73
331.2156982	0.13
333.3286133	0.04
335.0402222	0.10
337.0590210	0.19
338.9806519	0.28
341.2606812	0.13
351.2495117	0.26
356.3471680	0.13
365.2381592	1.05
366.3200073	1.11
367.3362427	1.61
369.2332153	0.11
373.3792114	0.14
376.3834839	0.11
379.3461304	0.15
387.2412720	0.36
389.5022583	0.03
391.2668457	0.29
393.0991821	0.14
394.2628174	0.28
395.2197876	0.03
397.0671997	0.18
399.2523193	0.45
404.3045044	0.14
405.1725464	0.49
407.1747437	3.42
408.2138062	0.14
409.4776611	0.21
410.0793457	0.08
411.0816040	0.54
413.1173706	0.12
414.2070312	0.14
417.1226807	0.09
419.0792847	0.24
420.9668579	0.17
423.2037964	9.55
424.2225342	0.34
425.2742310	0.06
427.0358887	0.07
428.0679321	0.07
431.1636353	1.10
434.0693359	0.13
435.0554199	1.63
436.3441772	0.19
437.2654419	2.24
439.1434326	1.58
440.1549072	0.04
441.3626099	0.08
446.1882324	0.14
447.2351685	1.33
449.1285400	23.87
450.1622925	1.29
452.0491333	2.31
453.1554565	2.47
455.1615601	0.73
456.2820435	0.05
463.2129517	0.12
465.4289551	0.90
466.3667603	0.03
467.2487793	0.21
468.1109009	0.16
469.1767578	0.19
481.1417847	0.11
482.0696411	0.06
487.4459229	0.15
488.9844360	0.26
489.7940063	0.06
491.0974731	0.16
495.2809448	0.06
497.5757446	0.25
499.1027222	0.17
507.2355957	0.25
513.2561646	1.36
514.9125366	0.39
516.2749634	0.34
517.8117065	0.20
525.2355957	0.06
527.9982300	2.17
529.3088989	100.00
530.0217896	0.17
531.3326416	2.17
532.3818359	0.12
533.3159790	0.14
534.0072632	0.08
539.1351318	6.12
540.0693359	0.21
552.3406372	0.36
553.5917358	0.31
557.0895996	9.72
558.2481689	0.47
587.3019409	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.2794
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
152.2498779	0.10
169.2703094	0.13
170.2043610	0.05
188.0877075	0.11
198.1284485	1.49
242.9384460	0.46
244.1714630	5.71
261.0534668	100.00
261.7335815	0.33
270.4387817	0.04
273.5017700	0.34
281.4853516	0.05
351.5000610	0.29
359.2192993	0.30
386.3966064	0.23
391.8979492	0.22
397.7860107	0.29
460.3750000	0.34
476.0856323	0.20
495.6415405	0.18
503.0056763	0.20
522.3441772	0.44
523.1878052	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
137.0176086	4.84
173.0671997	0.03
178.1752930	0.05
183.3284302	0.06
184.9332275	0.05
193.2294006	0.11
198.9341431	0.04
200.0912781	0.05
208.3096161	0.10
225.2867737	0.05
234.1993713	0.10
252.6721497	0.02
254.9202881	0.03
257.2140503	0.06
261.3005371	0.03
272.1137085	0.07
281.0383301	0.09
284.8842163	0.06
299.0398560	100.00
301.3042297	0.29
302.0787048	0.04
309.2126465	0.03
315.1329651	0.04
317.1901855	0.18
317.9187622	0.04
324.9580994	0.05
326.1108093	0.04
326.9688110	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	656.297
Annotation	2'''-N-Acetyl-6'''-deamino-6'''-hydroxyneomycin C
Peak:m/z	Relative Intensity
187.0714874	0.10
251.3669739	0.14
259.2294617	0.06
273.1302490	0.14
288.9048767	0.07
295.0459900	0.05
301.1078491	0.05
305.1714172	0.50
310.2374878	0.07
317.9174194	0.06
319.6830444	0.41
323.1781616	0.19
327.3222046	0.07
350.4756470	0.08
351.3896484	0.50
358.4569092	0.06
360.7940063	0.32
363.3761597	0.16
367.2514648	0.12
387.2962036	0.05
388.4277954	0.18
395.2305908	0.16
398.3558960	0.14
409.4114990	0.05
412.0009766	0.07
430.1697388	0.22
431.0585327	0.23
433.3865967	0.05
440.3126221	0.31
449.5049438	0.05
457.3258057	0.20
463.0800171	0.04
465.3649292	0.12
480.2478638	0.18
486.0267334	0.17
487.4567871	0.25
494.0766602	0.18
495.2236938	0.51
502.5467529	0.20
505.1468506	0.05
506.1194458	0.16
513.3113403	0.13
517.7373657	0.87
519.8254395	0.03
521.5374146	0.16
522.9055176	0.33
533.4900513	0.04
541.4816284	0.12
550.8718262	0.12
553.8805542	0.11
566.8707275	0.06
569.2744751	0.05
569.9146729	0.05
571.4207153	0.44
573.1452026	0.11
575.5606079	0.10
579.3302612	0.06
580.3984375	0.04
582.5810547	0.17
585.4277344	0.16
587.4710083	0.21
596.0452271	0.13
596.9995728	0.10
598.8891602	0.11
610.2963257	0.62
611.2473145	0.27
612.4480591	0.55
621.1688232	0.25
624.2301636	0.15
627.0491333	0.11
633.3628540	100.00
634.5196533	0.40
638.2120972	0.39
639.3742065	0.47
641.1953735	0.11
643.1671753	0.09
644.0525513	0.05
709.4069214	0.08
737.3154297	0.04
1069.6574710	0.17
1103.4367680	0.06
1105.4993900	0.72
1150.7336430	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
100.9526978	0.13
105.2014313	0.08
149.0224762	0.67
173.8471069	0.11
176.9116211	0.19
179.2504578	0.51
181.1906738	0.07
192.1177521	0.13
193.1657867	0.48
194.0317841	0.08
195.0698395	0.30
206.0773315	0.83
206.9956818	1.55
208.0535736	2.57
209.1338959	0.71
210.1371307	0.17
221.4688263	0.34
222.2968597	1.30
223.1008759	3.51
224.2494507	0.27
251.076889	100.00
252.1426849	24.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1039
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
133.1372070	0.03
137.0097351	0.28
148.9630280	0.19
163.0970612	0.13
164.8802185	0.11
173.0133362	0.07
175.0199280	0.40
177.0429993	10.65
179.0784607	0.46
180.0806885	0.06
199.1423340	0.12
201.1105499	0.07
205.1541595	0.05
213.1819153	0.05
214.0211487	0.04
215.1337738	0.38
217.0412598	0.22
241.0832520	1.34
243.0115509	0.12
246.2905273	0.06
257.1763916	0.31
259.2141724	0.96
275.1213684	0.80
285.0624390	100.00
289.1386414	0.03
299.2999268	0.11
303.0533447	86.15
307.1602478	0.05
309.0861816	0.34
315.0009460	0.11
321.4209290	0.09
327.0703430	0.44
329.3242798	0.10
339.2601318	0.51
341.0183105	0.19
343.2523193	0.14
344.9491577	0.06
368.9465637	0.10
377.3946838	0.06
379.0715942	0.09
387.3748169	0.22
401.3669434	0.22
404.7527771	0.15
411.1892395	0.18
419.0692444	0.04
421.1638794	0.05
437.1838684	0.30
447.2091064	3.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.0795
Annotation	gamma-Glutamyl-S-methylcysteine sulfoxide
Peak:m/z	Relative Intensity
87.8961792	0.82
110.2778931	0.05
130.0266876	0.36
151.9891357	5.10
183.1564331	0.03
190.7803955	0.06
198.9219055	0.11
216.9937134	100.00
218.0647583	0.07
220.7021790	0.05
221.9782715	0.02
245.2304382	0.01
253.2301636	0.02
263.1199646	0.24
272.0534668	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1083.538
Annotation	Ciwujianoside D2
Peak:m/z	Relative Intensity
411.5163269	1.10
437.2005005	1.38
441.3992310	3.21
454.3762207	2.22
457.7662964	1.03
458.4893799	1.80
486.5433350	0.73
500.1955261	4.54
526.5283203	3.38
535.7503052	0.62
552.4670410	1.29
563.5824585	8.30
564.7675171	3.64
581.5413818	1.26
583.4410400	15.11
584.4149170	3.05
605.3408813	0.87
610.6676636	1.38
616.3077393	1.14
623.5721436	3.88
624.6081543	0.40
634.6578369	0.57
651.4689331	51.35
652.5227051	71.16
654.3040161	0.75
659.3612671	0.57
661.5239868	1.04
662.7441406	0.95
679.4074097	1.66
697.2507935	1.37
698.2083740	0.69
723.2641602	18.91
724.3067627	39.07
733.4639893	10.25
734.4325562	16.30
741.7538452	11.27
742.3922119	40.24
751.3195801	2.74
752.3675537	7.28
759.4477539	9.26
760.3406982	15.41
818.2387695	1.41
822.6994629	1.41
860.4423828	1.77
861.2430420	0.62
869.6552734	0.49
877.3699951	1.63
880.3050537	2.66
895.4942627	11.40
896.4708252	29.30
903.5592041	1.95
904.5418701	8.98
908.7153320	0.59
914.4599609	4.00
921.5634766	6.97
922.5241699	30.43
923.5991211	3.53
926.5793457	4.40
939.7728271	1.41
942.5500488	5.00
957.6456299	10.41
958.6499023	5.24
969.2878418	5.43
970.5849609	9.02
983.8010254	37.23
984.5942383	100.00
985.9079590	0.86
993.5629883	1.68
1021.3618160	2.34
1022.2373050	3.34
1040.9097900	2.12
1041.5588380	4.42
1042.6632080	5.03
1043.4992680	1.07
1065.4344480	14.24
1066.4433590	59.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1236.1
Annotation	Unknow
Peak:m/z	Relative Intensity
421.2154541	2.37
556.6850586	1.43
569.6367188	2.72
571.6390381	3.55
572.3770752	0.53
589.4744873	6.31
590.7332764	1.62
685.6259766	0.69
686.6342163	2.14
704.6096191	1.49
733.3095703	0.92
734.3774414	3.43
747.3950195	1.36
751.3865356	26.42
752.3661499	2.55
794.3929443	1.81
810.2062988	1.59
819.7138672	12.09
820.7826538	3.54
829.3151855	2.31
833.6421509	5.74
847.1794434	3.24
848.4816895	1.25
849.4666748	1.43
865.2274170	49.46
866.5084229	26.71
879.3194580	0.70
883.6146240	6.43
884.6428223	4.07
891.2979736	15.14
892.4230957	1.70
909.3900146	84.10
910.5289307	30.11
919.1610107	1.92
921.4382324	2.53
927.5534668	6.39
1009.4166260	6.56
1010.4296880	7.47
1011.4490970	8.62
1012.4167480	5.47
1027.4797360	65.53
1028.5217290	28.25
1045.3557130	19.83
1071.4906010	6.43
1074.5306400	3.41
1089.5598140	18.65
1090.6025390	5.33
1130.5673830	0.83
1173.4519040	100.00
1174.5439450	51.40
1191.4387210	2.72
1192.3310550	2.85
1200.3247070	2.35
1217.4630130	60.27
1218.4641110	18.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.1299
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
127.9160004	100.00
130.0149994	1.55
223.1396332	3.73
241.1484985	56.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1859
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0216064	0.37
131.9878540	8.89
139.2155151	0.02
147.1208801	0.04
148.0417480	0.01
156.2134247	0.01
168.3033600	0.08
169.7844543	0.02
198.1005249	1.77
204.8463135	0.04
214.9480591	0.36
224.9818115	0.19
227.0080566	0.06
228.3210144	0.03
238.1396179	0.04
241.1800537	0.35
243.1473999	1.47
244.1554871	2.93
254.1699524	0.02
255.4685059	0.01
259.1941528	0.41
261.0918884	100.00
276.9431763	0.15
308.9945679	0.04
314.3207397	0.04
326.0587769	0.06
327.1491089	0.37
328.2022705	0.01
344.1970825	0.05
354.2037048	0.20
358.3406067	0.10
359.1011658	0.02
372.2258911	0.96
373.2077942	1.16
381.7122803	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.143
Annotation	Monnieraside III
Peak:m/z	Relative Intensity
127.9227905	0.02
129.1343842	0.17
138.9088745	6.20
139.9510345	0.30
144.1035156	0.11
144.9991608	0.03
147.1389465	0.05
148.4543457	0.34
149.1019287	2.01
150.6696167	0.02
163.2156067	0.11
168.9758301	0.22
175.0353088	0.19
176.0163879	0.05
177.0796204	0.07
178.8951721	0.12
189.1329346	0.11
199.6683502	0.10
201.9318848	0.09
205.1141968	0.22
207.0798798	0.06
212.1515656	0.19
226.9968414	0.12
239.8330383	0.26
241.4084167	0.09
242.9645691	0.05
247.3033447	0.16
253.3833923	0.17
256.2876892	0.10
257.0129089	1.32
263.0047913	0.20
264.9766541	0.32
271.1261597	1.49
272.1609802	2.31
273.0628052	8.12
275.0161743	100.00
277.0593567	0.41
281.2017212	0.09
282.9357910	2.41
284.6828918	0.14
285.3363647	0.15
287.1774292	0.17
288.2332153	0.13
291.1651611	4.07
293.3329163	0.20
295.0086670	0.08
297.3367310	0.05
299.0381470	0.90
301.0460205	7.03
305.1700439	0.35
306.8666992	0.15
317.0567932	1.44
318.9667358	0.21
323.3633728	0.22
327.3974609	0.19
329.4580078	0.18
334.0480042	0.20
341.1060791	1.20
343.1524048	0.07
347.2864990	0.10
349.1451416	0.20
353.4849243	0.13
365.2742920	0.26
375.1117249	0.04
377.3374329	0.04
381.2897644	0.08
383.1952820	0.39
391.0879822	0.53
392.1539917	0.08
401.0571289	3.06
408.8724976	0.53
418.9147339	3.06
419.5730286	0.16
428.2572327	0.28
443.1922302	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.2213
Annotation	Broussonetine R
Peak:m/z	Relative Intensity
105.0658188	0.03
116.0156860	0.02
118.9487457	0.03
121.0335007	0.08
129.9032288	0.22
131.0507660	0.09
132.0677338	1.49
137.0705719	0.08
145.1798553	0.04
147.0364380	0.04
149.0755920	0.29
156.0511932	0.05
157.2012024	0.03
158.9949951	0.01
160.0480347	0.02
161.1168060	0.02
163.1722107	0.02
165.0067902	0.05
167.0401001	1.31
172.0827332	0.04
173.0356598	0.44
178.9241333	0.18
184.9208679	0.03
191.1007996	1.21
195.8120270	0.05
206.2372742	0.02
209.1218262	3.34
211.2804871	0.01
216.7915649	0.03
227.0569458	1.09
229.2307739	0.04
233.8612671	0.04
238.1195374	0.27
245.1292725	0.10
248.0880127	0.03
249.8663635	0.09
252.1360474	4.61
253.9063721	0.04
256.4691772	0.17
258.2052002	0.14
266.1237488	2.23
268.0191345	0.04
270.1844482	0.04
276.3161011	0.65
277.9590759	0.09
280.1948242	0.06
285.1198120	0.04
286.0994873	0.12
287.6923828	0.04
291.1749878	0.05
292.3353882	0.51
293.6661987	0.02
294.2793274	0.75
295.8972473	0.18
297.0453491	0.01
297.9741211	0.04
301.0013733	0.01
304.2401733	2.27
309.3474731	0.04
310.1864319	0.14
312.1964722	1.29
313.3862915	0.07
314.2986450	0.14
315.2919312	0.07
322.2329712	14.48
326.2845459	0.02
328.1948547	0.37
329.1564941	0.04
331.3120728	0.06
340.2160645	100.00
341.1896057	0.12
349.3548889	0.05
358.2694397	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1329
Annotation	Griselinoside
Peak:m/z	Relative Intensity
126.9071655	100.00
127.8960571	0.09
130.1140289	0.43
131.0591431	0.20
143.6869202	0.09
144.8793030	4.16
162.9491577	6.21
168.5584869	0.10
186.8490143	0.59
190.8902130	0.08
198.3432465	0.05
205.1048889	0.79
207.0266418	0.04
209.0707092	0.19
235.0656738	0.12
240.7539673	0.06
252.5636597	0.20
253.2286987	0.42
255.2556152	0.07
271.0058289	10.98
281.2255554	0.08
282.7993164	0.23
286.1999207	0.11
288.9974060	6.22
291.1766968	0.04
297.1472778	0.14
298.4807129	0.03
303.0771179	7.48
304.2151794	17.87
306.8923340	7.07
307.5288086	0.15
317.9740295	0.19
330.2458191	0.03
331.3075562	0.24
342.9377136	0.13
352.1112671	0.08
362.1381836	0.03
369.5119629	0.12
370.7256165	0.52
371.3694763	0.11
373.1311340	0.33
387.4927063	0.18
395.4356079	0.11
396.5346375	0.27
397.1390076	0.82
403.3408813	0.07
403.9508972	0.11
405.2579346	0.09
406.1933289	0.09
415.0366211	2.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.09
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
73.9532318	0.01
74.9840851	0.02
93.8161926	0.02
94.8895569	0.01
107.0050354	0.02
108.1802979	0.04
119.9507904	100.00
120.6726837	0.01
121.3000031	0.04
131.0191803	0.32
137.9640961	0.04
147.8693695	0.43
148.9832306	5.03
150.8772583	0.04
166.1823883	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	855.2222
Annotation	Unknow
Peak:m/z	Relative Intensity
245.3876190	0.02
247.8766785	0.03
254.8542023	0.40
259.1817017	0.26
261.0893860	0.04
265.1196289	0.46
271.2432251	0.18
281.2001953	0.05
283.0588074	0.79
285.1318970	0.09
287.1390381	0.63
289.1627197	0.13
291.1373291	0.19
299.1324463	0.55
301.0809631	1.62
303.1365662	0.45
310.9953003	0.24
333.2742920	0.04
343.2224121	0.04
345.2375183	0.30
408.1477051	0.14
409.1892700	0.07
411.1199341	0.73
418.1458130	0.07
421.1955566	4.42
423.1399536	0.27
429.0441895	0.17
433.3511963	0.42
435.2103882	0.08
437.0684204	0.07
439.0831299	7.88
451.2492065	0.04
453.1926880	0.13
463.3036499	0.07
465.4064331	0.44
467.1315918	0.09
476.6206055	0.13
526.8579102	0.08
555.0140381	0.30
560.2297363	0.25
560.8861084	0.06
564.7375488	0.09
573.0683594	1.20
574.9979248	0.19
578.9977417	0.28
589.2667847	0.03
591.0313110	100.00
591.9268188	0.03
607.5335083	0.02
620.9337158	0.18
648.5846558	0.04
659.1584473	0.10
675.1016235	0.06
680.3068848	0.06
688.9595337	0.07
693.3524170	0.30
701.1962891	0.19
707.0860596	0.03
709.1547241	0.13
741.3000488	0.08
790.4370728	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	853.49
Annotation	PI(18:4(6Z,9Z,12Z,15Z)/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
240.8931732	7.54
259.0498352	1.83
277.2187500	60.53
278.2547913	0.87
297.0531006	11.29
315.1099243	1.47
413.1785278	47.25
414.4974976	1.39
431.4050293	2.55
483.6066284	0.20
519.5820923	0.17
557.0458984	0.10
575.3020020	100.00
576.1655884	1.93
593.3919067	25.91
594.3120117	0.12
609.2379761	0.13
636.6084595	0.21
691.3355713	0.08
747.4457397	0.65
765.2360229	0.18
768.3598022	0.88
781.3674927	0.44
793.3057861	0.25
794.4586792	0.38
807.1506958	0.35
835.4213257	1.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	392.1131
Annotation	(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteine
Peak:m/z	Relative Intensity
125.4136734	0.07
126.3753662	0.35
127.9827423	29.59
134.0419922	1.30
153.0764465	7.92
171.2148285	1.11
178.9953003	0.76
197.0909271	4.24
199.0356445	0.04
215.1413269	2.74
227.0601807	1.82
238.5497131	0.17
239.1676331	6.14
245.0323486	63.59
256.3697205	1.10
257.1859741	0.05
263.0821228	59.95
264.1234741	0.61
282.1185608	1.92
283.9317627	0.06
292.1037903	0.19
300.2189636	0.77
308.0958252	0.88
312.3043213	0.52
320.0638428	0.11
326.1148682	5.41
344.2126770	24.05
356.1032410	31.04
358.2103577	0.10
374.1084595	100.00
375.5120544	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.11
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
126.8529053	0.02
130.144455	0.02
131.125	0.01
132.9281464	0.01
138.9486084	0.19
143.1662903	0.04
147.0012054	0.01
150.9906311	0.02
153.9510956	0.01
159.2099609	0.01
161.0531464	0.01
163.0404816	0.02
163.9049683	0.01
165.3278198	0.01
167.0469055	0.01
175.1633911	0.04
187.0631104	0.59
188.9934998	0.02
196.8342896	0.03
199.1515961	0.04
200.8820496	0.04
203.1439056	0.01
206.9895782	0.05
207.9971313	0.06
209.1658783	0.03
213.0570221	0.08
214.9090424	0.00
225.0301971	0.07
226.0700989	0.01
227.1020508	0.20
227.9942627	0.03
228.9970703	0.25
231.208252	0.02
243.1199646	0.05
245.1307068	0.07
246.1329651	0.01
247.0740662	0.01
253.1463013	0.24
255.059967	0.72
257.138031	0.04
258.1812744	0.01
263.2202148	0.01
267.139801	0.03
269.17099	0.09
271.0682678	100.00
272.0560303	0.02
273.1132812	0.06
275.001709	0.01
281.3144531	0.03
283.0370178	0.07
287.0024414	0.01
289.06427	1.15
292.9116211	0.04
294.1482849	0.01
295.0361023	0.01
300.182312	0.02
301.1183472	0.02
302.2865601	0.01
304.2852173	0.02
307.109436	0.07
309.241333	0.04
313.0786133	0.06
327.0815125	0.02
331.050354	0.04
332.8389893	0.02
349.1311646	0.05
351.0770569	0.01
361.0301514	0.03
367.0539856	0.10
379.2457275	0.03
383.3346863	0.04
385.3078308	0.01
387.8450012	0.03
391.6151428	0.01
396.2342834	0.03
397.1799011	0.09
405.1399231	0.01
414.0198059	0.02
415.2567139	0.15
416.4807434	0.06
424.2669983	0.04
508.5178833	0.02
585.9356079	0.02
623.2886963	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1114
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
126.9004517	0.03
129.7029114	0.01
136.2974396	0.01
139.1109009	0.01
145.0454407	0.01
155.0246735	0.01
157.8076935	0.01
161.0782318	0.03
162.9353943	0.01
165.1117554	0.02
181.1718597	0.01
185.053894	0.03
187.1259155	0.14
196.9852753	0.01
199.0028534	0.01
200.9075165	0.00
207.0936737	0.02
209.2726288	0.03
212.9863281	0.01
227.1346893	0.10
228.1999969	0.03
229.107193	0.10
243.5059204	0.03
247.1003723	0.02
251.2275085	0.01
253.1469727	0.03
255.0717773	0.12
257.0862122	0.01
266.2615662	0.01
267.1574707	0.07
269.0958862	0.01
271.0661011	100.00
271.9381409	0.02
273.005127	0.03
274.205658	0.02
280.6647339	0.02
281.3738403	0.02
282.0651245	0.01
284.9165039	0.01
286.2425232	0.02
289.0275879	0.45
295.2437439	0.02
298.3456116	0.01
299.2494507	0.03
303.1401367	0.04
304.0430908	0.03
306.7124329	0.02
312.8747559	0.03
320.9758606	0.07
332.4688721	0.01
351.9078064	0.08
367.3871765	0.01
369.0178528	0.04
370.3602905	0.01
371.3503113	0.06
385.1060791	0.08
387.0892639	0.08
389.1648254	0.02
390.2461853	0.01
392.0050354	0.04
397.0278625	0.18
401.249054	0.01
403.0958557	0.45
405.0293884	0.02
413.098175	0.05
415.2202759	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.0561
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
57.0627556	0.08
69.1086349	0.04
70.9269409	1.34
72.8552856	0.37
74.9940643	6.92
81.0488968	6.90
87.0026550	2.81
89.0738602	0.52
97.0406342	0.72
99.0041657	23.97
102.8766632	0.09
113.0456848	0.13
115.0732880	0.26
116.9013977	0.31
117.9024658	0.04
119.0569305	0.14
125.0216827	5.57
130.8592377	0.05
133.0343933	0.53
134.1737366	0.07
135.0601501	0.28
142.9875031	100.00
143.7951202	0.03
161.0301666	31.69
179.0497894	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.0932
Annotation	N-Acetyl-DL-tryptophan
Peak:m/z	Relative Intensity
72.07324219	0.10
73.92645264	1.18
97.92236328	0.29
115.9328613	3.68
130.0552673	0.13
142.1287384	0.04
158.8426056	0.06
169.2165375	0.04
172.1846008	0.02
177.0089569	0.05
180.924118	0.02
183.0158234	0.10
185.9488983	0.24
201.1791992	3.09
203.0799408	100.00
203.9769897	0.08
227.1103516	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.36
Annotation	Hirsutatin A
Peak:m/z	Relative Intensity
217.1887054	0.12
227.1766205	0.12
235.1898651	4.19
245.0823669	0.10
250.8769379	0.08
253.2543640	3.23
266.9139404	0.09
269.6166992	0.15
277.1560059	6.11
281.1740112	0.17
287.0824585	3.60
290.4960938	0.11
293.2137451	0.73
294.3750305	0.22
303.3411865	0.15
305.1264648	4.74
312.2664185	0.17
323.2538452	1.50
325.7954102	0.17
335.1392212	0.14
343.2094116	0.23
349.1612549	0.08
351.3381348	0.13
361.4532471	0.44
365.2595825	0.07
367.3944092	0.35
378.7314453	0.41
379.3953857	0.19
382.3442383	0.16
391.5416870	0.11
397.2324829	100.00
399.3591919	0.05
415.1895142	36.59
415.8068237	0.31
424.3993530	0.22
471.4732666	0.14
473.3518066	0.14
478.5643311	0.08
481.4295044	0.22
487.3114624	0.14
491.2479858	0.10
498.2060547	0.11
513.2621460	0.42
587.4948730	0.07
615.3851929	0.14
616.4232178	0.19
630.2789307	0.25
631.2055054	0.19
638.9651489	0.07
643.0809937	0.32
656.2546997	0.08
657.1441040	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.15
Annotation	Apiin
Peak:m/z	Relative Intensity
163.0393982	0.04
168.6335907	0.02
182.0241699	0.05
191.1118774	0.04
192.1430206	0.04
197.1521454	0.15
201.0219727	0.03
205.1192322	0.02
215.2128296	0.06
225.1507568	0.07
227.0102539	0.05
243.2490997	0.08
247.1078949	0.03
248.1170349	0.05
265.1204529	0.35
266.104248	0.01
271.065094	100.00
283.085083	0.02
288.8168945	0.07
292.9796143	0.01
304.1422729	0.03
317.2226562	0.01
320.3617554	0.03
322.2458496	0.11
324.8786011	0.05
326.1674805	0.05
338.9752808	0.02
363.8580322	0.01
382.1573486	0.06
384.9743652	0.02
389.7207642	0.06
391.0114136	0.03
393.1086426	0.01
393.7897339	0.03
395.2332153	0.09
403.2703247	0.01
410.2875366	0.03
411.4624634	0.06
415.2042236	0.02
416.901123	0.03
417.7175293	0.03
420.7978516	0.02
428.6246338	0.17
429.9677734	0.01
433.0873413	0.53
435.6015625	0.26
436.484436	0.05
440.8361206	0.02
461.1968384	0.02
466.8430176	0.05
473.1958618	0.13
474.9943237	0.04
482.9682617	0.01
483.9400024	0.01
487.6917114	0.05
496.5598755	0.02
511.352356	0.02
512.2017212	0.07
517.5022583	0.07
520.4694214	0.08
547.1089478	0.34
548.6067505	0.25
549.3442993	0.01
565.6419067	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1637
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
201.2092896	0.06
203.2524719	0.06
207.0632324	0.02
225.0825500	0.03
241.1638184	0.20
253.0753021	0.13
259.1461792	0.13
269.1039429	0.02
271.1102295	0.09
272.8909912	0.21
276.0170288	0.11
287.1191406	100.00
291.3027344	0.06
301.1107788	1.93
303.9842224	0.04
314.6312866	0.02
327.0450439	0.15
329.3278809	0.23
339.3798828	0.08
343.1986084	0.08
353.0319824	0.16
354.2742310	0.32
383.0825195	0.26
407.4799194	0.14
409.2940063	0.36
413.1741943	0.15
414.7838745	0.06
419.0900879	0.34
425.0310059	0.40
426.1648560	0.03
431.1400146	0.69
432.4368286	1.07
433.1109009	2.93
437.4193115	0.04
439.2214966	0.13
442.5625000	0.06
448.4409180	1.32
449.0603027	21.29
453.3258057	0.10
457.2396240	0.08
462.9572754	6.26
463.5889282	0.03
466.2772827	0.06
473.2865601	0.03
475.1833496	0.52
476.4817505	0.03
489.0218506	0.03
492.4544067	0.16
497.7029419	0.23
512.4428101	0.06
513.7875366	0.23
519.3038940	0.05
523.2943726	0.21
529.3703003	0.11
542.4624634	0.21
547.4152222	0.07
548.6037598	0.05
551.4420776	0.03
559.1248779	0.70
560.7016602	0.05
561.9357300	0.02
577.0346069	1.39
577.7726440	0.06
583.1292114	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.1373
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
136.9837494	0.03
138.9993286	6.41
147.0905914	0.88
150.9945374	2.39
152.7129822	0.05
159.0698242	0.05
163.0580139	0.26
164.9617462	2.57
169.1205750	0.08
175.0862274	0.10
177.0958252	0.06
180.9298401	0.36
187.1029053	0.05
205.0614319	1.50
217.0707550	0.32
229.3607788	0.15
234.9931946	0.29
240.9956970	0.03
242.6669312	0.03
245.0811157	0.12
246.9856567	0.47
254.9249878	0.18
259.2619324	0.05
265.0664062	1.89
271.0971375	0.05
273.0869751	9.38
277.1235046	1.12
283.0727539	5.54
285.0862427	0.05
291.0786743	100.00
291.6973572	0.18
295.2868042	0.23
296.7810669	0.43
297.4302979	0.06
299.0276489	0.11
301.0790405	26.15
301.6950684	0.09
303.2753296	0.12
312.8328857	0.92
315.1088867	3.70
317.3547974	0.07
319.1759033	0.20
321.2783203	0.13
323.9907837	0.10
327.3121338	0.03
333.0680542	3.62
357.1939392	2.55
362.9044495	0.07
363.5547485	0.03
369.2189636	0.25
374.9689026	0.05
381.2496643	0.23
387.0301208	0.04
399.1268616	1.48
417.1855774	8.00
422.9118042	0.12
435.0538635	6.93
435.6766968	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	441.1014
Annotation	3,5-Dihydroxyphenyl 1-O-(6-O-galloyl-beta-D-glucopyranoside)
Peak:m/z	Relative Intensity
126.8334961	0.15
128.9734497	0.05
137.0258942	0.05
139.0491638	0.02
145.0203247	0.12
146.9617310	0.42
150.9908295	0.31
176.9956360	0.05
183.9006195	0.07
187.0295715	0.09
192.9873352	100.00
202.2290497	0.04
205.0675507	0.01
212.9694519	0.04
229.3854828	0.01
231.0373230	0.01
235.0442200	0.12
247.1274109	0.47
259.1021118	0.08
261.3406067	0.02
278.9030762	0.06
283.0298157	0.02
289.2497864	0.08
291.9077454	0.04
301.1836548	0.14
306.0487366	0.21
308.5578613	0.06
310.9300232	0.07
326.1624756	0.27
328.4327393	0.04
333.2784119	0.02
337.1843567	0.19
347.1626587	0.08
352.0832214	1.46
353.1950073	0.07
355.0041504	9.90
365.2605591	0.02
368.0289001	0.17
369.9822388	0.05
385.6537170	0.09
387.0053711	0.02
388.8333435	0.04
394.4239197	0.03
395.1373596	0.06
396.4157410	0.09
397.1357422	0.84
405.0772705	0.30
408.1386719	0.02
415.8711548	0.05
422.9979553	1.81
424.0071106	0.03
432.8231812	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.1379
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9611053	1.21
153.0835266	4.54
171.0113220	0.55
178.4777374	0.65
179.1555176	3.55
184.0586548	0.06
185.1290894	0.08
196.9767609	8.29
198.0318298	0.13
204.3107452	0.18
208.2694550	0.08
215.1362305	0.05
220.3033447	0.08
221.9251099	1.15
222.5966797	0.03
223.3486633	0.25
224.2281189	0.07
226.9900055	1.27
239.1527405	0.68
240.2602234	0.66
243.1472778	0.24
243.8324280	0.18
245.0303650	35.66
246.0923157	0.25
248.1778870	0.07
263.0916138	2.28
263.8703003	0.20
266.0197144	2.49
268.7747498	0.06
270.0378418	0.27
271.1453857	0.52
283.8999939	0.81
288.1624756	1.13
296.3228760	0.08
297.1997070	0.07
307.2216797	0.47
308.1731567	0.28
314.0557251	5.62
325.1873169	2.77
326.2364502	1.12
328.9499512	0.25
332.1789551	6.27
333.3350220	0.15
343.8279419	0.18
345.0316162	0.38
351.2205200	2.39
355.1827393	0.69
356.0543213	0.83
362.0861206	3.08
369.1974487	2.86
373.2499390	7.96
374.1552124	3.96
376.8912354	0.55
380.1235352	7.48
381.1320801	0.37
392.1444702	0.19
395.2809448	0.96
399.0710449	6.24
399.7880249	0.23
413.2702026	1.09
417.1797485	12.36
425.1715088	1.85
435.1123047	0.17
443.1510010	27.98
444.0574951	0.33
461.1176147	87.22
461.7517090	0.12
465.0937500	0.45
473.0847778	3.50
491.1188354	100.00
492.0425415	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1778
Annotation	Afzelechin(4alpha->8)pelargonidin 3-O-beta-glucopyranoside
Peak:m/z	Relative Intensity
231.1650085	0.09
246.9430389	0.04
257.1710205	0.04
265.1261902	0.01
271.1792603	0.24
283.1331177	0.26
284.0969849	0.08
285.2845459	0.05
287.3325195	0.05
313.1949463	2.32
329.1928711	0.01
345.2426147	0.01
369.3962402	0.02
375.2785034	0.12
380.7595215	0.02
399.3864746	0.07
407.1103516	3.23
415.3060913	0.01
417.2152100	0.32
419.0632324	0.05
433.2219238	0.03
435.1806030	0.03
438.2110596	0.01
440.3787231	0.04
442.9509888	0.03
475.0825195	0.56
475.6834106	0.02
501.3258057	0.02
506.3271484	0.02
525.1707153	2.85
525.8530273	0.03
533.2446289	0.02
537.2893677	0.02
538.0670776	0.06
543.1653442	100.00
543.8295288	0.17
558.4013062	0.01
568.7859497	0.04
573.1596069	0.04
574.9522095	0.44
576.1300659	0.79
579.0631714	0.03
584.5276489	0.03
590.4475098	0.01
673.3848267	0.04
686.9948120	0.24
687.6145630	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1729
Annotation	N-Malonyltryptophan
Peak:m/z	Relative Intensity
173.1272583	0.02
183.0904236	0.07
186.1425018	0.42
191.1982117	0.18
201.1078491	0.64
203.0553894	14.36
241.1517029	0.10
245.0703735	100.00
251.1126709	0.17
255.2159576	0.06
257.1630554	0.03
263.2090149	0.06
268.9940186	0.07
282.9899292	0.15
285.1614380	0.94
288.8105164	37.94
289.5097046	0.12
297.2587891	0.04
329.1089478	0.14
330.0654907	0.04
336.9449463	0.29
341.1324463	0.16
353.1645508	0.37
355.0226440	0.12
358.2461548	0.06
362.1260376	0.03
371.2075195	1.16
385.2226562	0.09
387.3182983	1.40
388.8820190	0.03
397.1149902	0.31
399.1621704	0.05
400.6994629	0.07
403.2160034	0.53
407.1161499	0.46
408.2162476	0.05
409.2678223	0.04
415.1128540	0.75
416.9586792	0.08
419.3408203	0.07
427.3071899	0.33
429.3550415	0.10
433.2492065	4.09
434.3583984	0.06
435.4060059	0.39
442.0040283	0.05
443.0621338	0.06
446.6460571	0.05
451.5043335	0.05
458.4224243	0.03
459.2053223	0.07
460.1931763	0.03
462.4227905	0.03
486.8405151	0.03
489.1156616	0.23
502.2333374	0.16
503.1864624	0.59
507.0603638	0.15
511.2457886	0.05
515.0031128	0.80
517.2891235	0.16
518.4215698	0.07
519.4762573	0.21
533.0183105	4.37
533.7731323	0.07
534.8348999	0.96
535.5946045	0.25
547.1090698	0.02
551.2425537	0.08
556.1859741	0.04
560.1448364	0.12
561.1964722	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.167
Annotation	Unknow
Peak:m/z	Relative Intensity
142.7094421	0.02
160.2955170	0.03
161.2171326	0.15
175.2200470	0.11
189.1117554	1.04
203.2140045	1.58
233.2723083	0.06
287.3739319	0.19
291.0867920	0.01
305.1372986	8.57
323.1458740	100.00
324.0746460	0.02
365.1125183	9.67
365.7534485	0.01
368.7251587	0.02
405.0766907	1.63
405.7207947	0.03
420.0564270	0.09
421.0670471	0.07
434.9035950	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1349
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1255951	0.11
170.8465576	0.04
174.8877258	0.15
178.9926453	0.09
181.0015259	0.07
187.1234589	0.27
188.1204224	0.13
191.1625061	0.10
195.0026550	0.05
201.0737610	0.12
202.9763031	0.25
205.0350037	0.29
213.1179810	0.13
215.0297546	0.06
219.0667419	0.13
225.1223145	0.13
227.1801300	0.10
229.0660248	0.26
230.3631744	0.16
231.1099243	0.04
233.1450806	0.05
238.9985962	0.03
240.9802704	0.21
243.2566833	0.26
245.0841064	2.74
247.1047211	0.28
250.0657043	0.05
255.0479279	0.30
257.1267090	0.13
261.2210083	0.03
267.1710510	0.17
269.1740112	1.13
271.0391541	0.03
273.1397705	2.05
281.2966309	0.06
283.3094482	0.05
285.1076050	0.32
287.1016541	5.95
289.1688843	18.11
296.8876343	0.09
299.0811768	5.60
303.2985840	0.05
305.2101440	0.06
309.1737671	0.06
311.2026978	0.04
312.2826538	0.06
315.1785278	0.21
327.2524414	0.22
329.1089478	0.83
331.3023682	0.48
332.1670532	0.13
335.3016357	0.03
339.2108765	0.18
341.1016846	0.26
347.3735962	0.04
351.2536011	0.05
355.3781128	0.04
357.1169434	0.46
367.2349854	0.69
368.5346069	0.23
371.3206787	0.06
374.9851074	0.12
381.0629272	1.04
383.0574951	0.05
387.6283569	0.04
389.3745728	0.02
393.2325439	2.06
395.0592651	0.29
396.4995117	0.06
397.1889648	0.26
407.1455078	52.89
407.7510376	0.15
408.4752808	0.03
409.1297607	0.28
410.3417969	0.06
411.1832275	0.52
412.7903442	0.34
415.3341675	0.08
417.0294189	0.17
419.3034058	0.15
421.4960327	0.05
423.1768799	0.22
425.1632080	100.00
427.5499878	0.05
431.0086060	0.07
433.2225342	0.61
436.6264648	0.25
437.2782593	0.03
439.0783691	2.21
447.0599365	0.10
449.2022095	1.03
451.1938477	25.32
452.2565918	0.05
467.0347900	0.49
470.9846802	0.31
471.6704102	0.13
479.3146362	0.04
489.3515015	0.06
490.9047241	0.89
491.6987915	0.73
492.3643188	0.17
493.3049927	0.26
497.3411865	0.23
500.2421265	0.85
501.1023560	0.04
509.0466309	0.10
515.1312256	0.33
526.2930908	0.09
531.1484985	0.04
533.1388550	3.66
533.8276978	0.06
535.0630493	0.35
540.0148926	0.07
541.2137451	0.56
545.2627563	0.18
559.2315063	10.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	640.3018
Annotation	Balanitesin
Peak:m/z	Relative Intensity
242.2314758	0.04
271.3944397	0.02
302.1301880	0.01
317.0332336	0.01
369.1788940	0.06
463.7235718	0.02
474.9124146	0.03
503.0025024	0.11
528.2835083	0.03
559.4452515	0.07
573.4362183	0.08
593.0906372	0.05
599.4850464	0.03
608.4804077	0.04
610.4582520	0.27
617.3550415	100.00
618.6229248	0.75
619.3699341	0.45
620.4341431	0.13
621.1882935	0.07
622.3615112	0.08
623.5951538	0.14
625.8486938	0.03
747.7960815	0.03
939.5903320	0.03
993.4312134	0.02
1055.6494140	0.06
1073.4820560	1.21
1074.3754880	0.22
1101.6024170	0.04
1119.6198730	0.03
1235.5957030	0.41
1236.7304690	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.214
Annotation	Lychnose
Peak:m/z	Relative Intensity
178.9003754	0.12
203.1153412	0.22
221.0940704	5.05
223.2000122	0.14
249.4456787	0.40
250.7854004	0.89
262.3126526	0.19
280.3360291	0.23
281.0825806	0.78
305.1751709	1.06
310.7850342	0.46
321.3784485	0.13
322.4061279	0.37
323.1045532	3.89
337.4001465	0.23
341.0505371	28.50
363.2438354	0.14
365.3630371	0.12
381.7127075	0.17
383.1562500	100.00
383.7821045	0.25
394.8541870	0.16
407.4066772	0.17
412.5457153	1.59
413.2592773	0.03
425.0804443	0.91
442.9604492	18.19
449.4254761	0.16
455.2811279	0.57
467.1972046	0.14
472.7390137	0.04
485.1757202	29.16
485.7894287	0.19
503.0837402	3.13
545.1369629	1.07
647.4154663	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.4818
Annotation	Fargoside B
Peak:m/z	Relative Intensity
258.8485107	0.68
323.5594788	1.11
335.1688843	0.21
337.0687866	0.88
341.0015869	0.15
355.1063232	0.59
369.4566345	0.17
372.7973022	0.09
375.3406372	0.13
387.6559448	0.07
391.1027527	0.16
398.0612793	0.14
409.5471802	0.15
443.1414185	0.45
451.2896118	0.21
463.3603516	0.49
465.5365601	0.07
489.0754395	0.24
493.4206543	1.34
497.2185059	0.11
505.5860596	0.56
507.3308105	0.53
516.2738037	0.09
521.2948608	0.54
523.6557617	0.10
533.4932251	0.20
545.3164673	1.17
547.3579712	1.64
549.3468628	0.07
551.1962280	0.17
557.5840454	0.14
560.2955933	15.24
561.3656006	9.56
573.4044800	38.32
574.2564087	2.06
575.4743042	0.23
580.4232788	0.19
585.5437012	0.64
587.5581665	0.19
593.4143677	0.08
597.1984253	0.39
598.6782837	0.44
599.4602661	3.26
613.1657104	0.51
616.5280151	0.09
617.5097046	0.27
639.6967163	0.30
643.5479126	1.95
645.3481445	0.16
671.3349609	1.27
682.4710083	0.83
695.2318115	0.45
705.2976685	0.27
707.6365356	0.51
709.6604614	0.75
710.4875488	0.30
715.5153809	0.30
722.2720947	2.15
722.9500122	0.11
725.6248779	0.08
733.5099487	2.36
747.5504761	1.83
750.3843994	0.87
751.1084595	0.50
751.7387085	0.11
763.5400391	41.84
777.6957397	13.05
778.4660645	37.32
779.1866455	0.15
793.4214478	100.00
794.0852661	0.21
795.0174561	0.62
805.5238647	0.13
821.5728149	0.12
823.5595093	24.55
836.3648071	0.71
837.3619995	0.36
839.6970825	0.15
849.7589722	0.14
851.8375244	0.24
853.4675293	0.24
859.5270386	0.95
865.5652466	0.53
867.3958130	1.55
877.6140747	0.18
881.5989380	1.06
895.4664917	18.31
896.4170532	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	779.4537
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
218.1846924	0.12
219.0338440	0.91
220.1510315	0.29
225.1830444	0.15
229.3062897	1.92
230.2564392	1.47
231.0269012	0.37
233.1209717	0.75
239.3616028	0.23
240.4192810	0.39
241.3383942	0.67
243.1050415	1.01
244.2209320	0.83
245.2885590	0.49
247.2807922	0.14
248.1232147	0.54
255.3798828	0.68
256.1729736	0.46
257.3146667	1.45
258.1952209	0.67
259.1992493	0.27
261.2183533	0.57
267.0913696	1.44
268.2975464	0.81
269.2589722	0.49
270.3216858	0.46
271.2146301	0.90
272.1291504	0.71
274.2818604	0.44
278.2838745	0.20
279.0748901	0.49
280.9779663	0.09
282.8006592	0.40
283.4557495	0.11
284.3660278	1.85
285.2613525	0.56
296.4469299	0.29
298.3981323	0.87
302.8727417	0.16
304.9072571	0.55
309.6119995	0.43
310.3048096	0.32
311.5288086	0.07
312.2771912	0.45
314.1455688	0.30
317.2744751	0.26
320.8175049	1.12
322.0820923	0.28
323.1856689	0.22
325.3750000	0.34
326.3777466	0.39
329.9138794	0.33
335.5516052	0.19
337.2460938	0.18
338.9615479	2.10
340.1348877	1.74
349.0146484	0.51
350.4399414	1.07
351.4209595	1.83
352.3519897	0.82
353.1616821	0.45
354.6056519	0.44
355.2153320	0.25
358.1523438	0.12
361.2861328	0.11
362.9683228	0.16
364.2841187	1.41
365.2765198	3.89
366.2669678	3.40
367.1795654	0.26
368.6856689	0.54
377.9266968	0.88
379.8389282	0.43
384.3358154	0.18
391.3114624	0.19
392.3339233	0.42
393.3290405	0.21
394.2781372	0.08
396.4702759	0.14
404.4220581	0.92
405.4585571	14.42
406.4015503	19.96
408.4356079	2.04
418.4805298	0.15
419.1666870	0.18
420.2200928	0.50
421.1314697	0.57
422.6740112	2.00
423.2788696	27.24
424.2962036	72.54
425.0260010	0.18
427.5887451	0.42
430.0417480	0.32
436.0554199	0.32
439.6065674	0.28
440.5760498	1.01
441.6259766	0.60
443.3734131	0.16
445.2576904	0.49
462.5850220	0.67
471.3407593	0.32
484.4786987	0.13
485.6113892	0.09
488.4505615	0.10
512.1744995	0.25
518.2844849	0.53
526.3781738	0.12
527.5781860	0.18
535.2551880	0.35
538.3859863	0.26
540.8979492	0.08
546.1939087	0.11
552.4857788	0.29
563.5956421	1.15
564.5299683	2.59
566.9631958	0.23
581.3901978	24.75
582.3113403	100.00
582.9290771	0.85
599.1062622	7.27
600.0867310	25.70
600.7977905	2.32
603.3547974	0.51
605.3451538	0.08
610.5950317	0.18
616.2397461	0.24
617.3203125	0.20
618.0048828	2.53
623.2478027	0.06
635.0702515	0.06
662.5183716	0.14
705.6633301	0.49
730.2483521	0.10
744.4325562	0.39
762.4122925	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1289.2126
Annotation	Unknow
Peak:m/z	Relative Intensity
388.0311890	0.13
400.4005737	0.39
403.0662231	0.51
408.6871643	0.06
416.1378174	0.18
430.8461304	0.21
436.1192627	0.07
448.1258545	0.34
450.6106567	0.11
461.4804688	0.34
465.2815552	0.19
474.0628357	0.40
475.6666260	0.07
492.3242188	3.55
493.3484497	0.76
494.1232300	0.10
499.5868835	0.15
505.2536621	0.59
506.2213745	0.20
526.0872803	0.15
531.0531616	0.33
550.2152100	0.22
555.4786987	0.08
560.5802002	0.50
577.0063477	0.51
579.3844604	0.18
593.3491211	0.85
594.5240479	1.21
595.6013184	0.14
597.3677979	0.24
618.1984863	0.22
631.3436279	0.25
644.4819336	0.87
645.4750977	0.23
657.3615723	0.17
661.1870117	0.42
663.3223877	0.16
691.3052979	0.75
716.3665771	0.40
719.3079224	0.88
732.3612061	0.07
742.4155273	0.26
764.7009888	0.36
772.7294312	0.92
776.4069824	0.18
781.4063110	0.09
790.5586548	0.28
791.1917114	0.29
794.3473511	0.21
801.4881592	0.13
805.5775146	0.09
806.3132324	0.28
808.8721313	0.25
821.3867798	0.42
823.6608276	0.24
838.2646484	0.19
840.0949097	0.14
843.5327759	0.09
847.0443115	0.53
855.9772949	1.23
857.5733643	0.31
861.2059326	0.36
864.3452148	0.37
873.9802246	0.19
874.8489990	0.54
886.2462158	0.16
886.8778076	0.31
889.4302979	0.24
894.0338135	0.85
924.9128418	0.17
933.4287109	0.11
937.7434082	0.19
941.2436523	0.40
945.3504639	0.28
948.1363525	0.13
949.5134277	0.33
968.8845215	0.20
970.6186523	0.76
975.3236084	0.26
984.6411133	0.34
987.9709473	0.29
995.2316895	0.31
1006.4863280	0.20
1007.4245610	0.38
1018.2532960	0.61
1022.0271000	0.48
1026.3226320	0.54
1026.9727780	0.38
1032.6883540	0.45
1037.6828610	0.34
1039.9987790	0.23
1040.9311520	0.14
1046.5108640	0.77
1050.5157470	0.28
1051.4002690	0.16
1052.4621580	0.27
1054.0772710	0.79
1068.8260500	0.75
1074.8590090	1.24
1076.1672360	0.69
1079.4677730	0.32
1080.1132810	0.32
1084.6708980	1.86
1086.7697750	0.09
1089.5733640	0.35
1093.6152340	0.95
1094.8360600	0.97
1097.5444340	0.48
1099.2646480	0.49
1104.7968750	0.81
1109.2069090	2.05
1110.2006840	0.11
1113.9080810	1.43
1114.8829350	0.40
1116.0603030	2.43
1117.2476810	0.53
1119.2233890	3.23
1121.5109860	1.89
1123.0024410	0.56
1127.5100100	0.50
1128.1494140	0.32
1129.2110600	0.70
1129.9719240	1.15
1131.0568850	1.70
1133.0148930	0.26
1133.9161380	1.00
1134.9167480	0.73
1135.8785400	1.27
1136.6621090	2.89
1137.3261720	0.89
1140.4393310	0.40
1142.1910400	1.27
1143.9307860	0.07
1144.9433590	0.76
1147.8779300	2.47
1150.5935060	0.23
1152.4194340	0.56
1153.5695800	2.13
1154.5053710	0.75
1156.6986080	2.16
1158.9309080	0.62
1160.9909670	1.62
1161.9357910	0.24
1163.9879150	0.37
1165.3728030	2.26
1166.3809810	0.80
1168.2631840	1.59
1169.3066410	1.51
1170.5206300	0.96
1171.6132810	3.16
1173.5418700	0.99
1174.6983640	1.88
1175.3735350	0.54
1176.5467530	0.51
1177.7495120	2.37
1178.5793460	1.91
1179.8337400	5.84
1180.5727540	3.23
1181.9887700	0.22
1183.7070310	1.12
1184.7360840	1.27
1186.2615970	2.72
1187.8726810	1.51
1188.6380620	1.79
1190.0012210	2.22
1191.2054440	3.64
1193.7932130	7.96
1194.7062990	8.02
1196.0148930	1.14
1197.0534670	2.89
1198.2146000	5.25
1199.1643070	2.70
1200.5563960	8.47
1201.2681880	9.40
1202.2114260	5.39
1203.2183840	20.11
1204.2358400	7.38
1204.9970700	0.16
1206.7529300	2.03
1208.6088870	5.45
1209.7241210	2.05
1211.1640620	6.17
1212.2803960	4.01
1213.5073240	4.52
1214.4102780	10.51
1215.2120360	2.10
1216.5424800	1.08
1217.6826170	10.67
1218.7609860	4.56
1220.4649660	3.14
1223.7081300	100.00
1224.7075200	12.37
1225.8879390	5.95
1227.2226560	2.40
1228.4133300	1.12
1230.3591310	2.86
1231.2082520	1.09
1232.2026370	1.66
1234.1030270	0.52
1234.9235840	3.16
1236.7452390	9.29
1237.7386470	3.18
1238.6369630	0.43
1239.9096680	8.12
1240.6542970	9.91
1241.4747310	2.61
1242.3731690	3.13
1243.2323000	4.34
1245.9144290	52.14
1246.7097170	36.24
1248.1882320	2.60
1249.0153810	1.39
1250.0612790	1.87
1251.1250000	5.46
1252.0833740	23.99
1252.8585210	5.93
1254.1569820	2.70
1255.4528810	4.22
1256.9758300	21.68
1257.7280270	15.12
1258.8402100	10.78
1259.8446040	2.87
1260.5009770	3.06
1261.3107910	0.43
1263.7882080	1.58
1264.4338380	63.39
1265.3559570	14.09
1266.3016360	5.15
1267.2414550	0.25
1268.6950680	7.51
1270.1043700	3.32
1271.5054930	4.54
1272.3481450	1.23
1273.5434570	2.26
1274.4523930	17.58
1275.2736820	8.03
1276.5439450	1.01
1277.6494140	2.78
1278.5295410	2.03
1280.9746090	0.59
1303.8452150	0.38
1307.1154790	0.82
1310.3206790	0.29
1315.0706790	0.22
1316.1364750	0.60
1318.7745360	0.09
1321.3457030	0.09
1323.5659180	0.43
1328.5385740	0.51
1332.4431150	0.55
1337.4025880	0.42
1338.4152830	0.06
1344.7294920	0.68
1357.5505370	0.46
1360.9538570	0.28
1371.0582280	0.65
1372.4921880	0.26
1374.7286380	0.46
1377.0667720	0.30
1380.4182130	0.11
1382.4471440	0.47
1395.2413330	0.85
1396.3702390	0.07
1397.3676760	0.40
1404.6242680	0.20
1407.4421390	0.13
1409.6702880	0.33
1412.0614010	1.03
1414.3166500	0.38
1419.4259030	0.20
1422.1363530	0.41
1423.4614260	1.02
1425.9705810	1.17
1429.3139650	0.47
1436.1478270	1.60
1441.4371340	0.46
1443.4971920	0.34
1448.8814700	0.24
1453.0972900	0.71
1454.4239500	0.14
1455.4882810	0.40
1456.3763430	0.49
1457.9543460	0.36
1461.1440430	0.26
1462.3394780	0.45
1464.3892820	0.36
1470.8325200	0.20
1472.6076660	0.46
1474.9643550	0.86
1478.3753660	0.19
1480.3311770	0.10
1482.5128170	1.18
1483.4583740	0.33
1484.2236330	0.73
1486.4642330	0.39
1487.2250980	0.24
1489.7806400	2.25
1498.2709960	0.18
1500.3096920	0.63
1503.5306400	0.08
1504.8995360	1.63
1505.7567140	0.47
1507.5366210	0.24
1509.2379150	0.24
1510.6546630	1.01
1511.7014160	0.62
1512.5147710	0.35
1513.2392580	1.14
1514.2659910	0.89
1515.6259770	0.12
1516.6008300	0.99
1517.6357420	0.45
1518.5446780	0.29
1522.2440190	1.01
1523.2098390	0.28
1524.0136720	0.36
1524.8238530	0.22
1525.6068120	0.72
1527.5507810	0.17
1529.4593510	1.13
1530.5783690	0.56
1531.3538820	1.14
1532.0712890	0.31
1533.3642580	0.54
1535.5214840	0.34
1537.7686770	0.93
1538.9927980	1.83
1539.5985110	0.80
1540.2156980	1.88
1541.4798580	0.93
1544.5173340	0.24
1545.5689700	2.56
1546.7711180	0.87
1548.0704350	2.68
1548.7376710	0.71
1549.3511960	0.66
1550.5349120	0.46
1553.5388180	0.14
1554.9416500	0.94
1556.1436770	0.58
1557.8792720	0.53
1559.1470950	0.31
1560.7465820	0.38
1563.4594730	2.75
1564.6575930	0.45
1565.5244140	0.58
1566.6129150	0.61
1567.3184810	0.31
1568.1494140	0.74
1569.3955080	0.61
1571.2049560	0.77
1572.5477290	0.36
1574.4486080	2.64
1575.0891110	0.71
1575.7886960	1.32
1576.7115480	0.89
1578.9774170	0.18
1579.7725830	0.69
1580.5377200	2.32
1581.1435550	0.80
1581.8435060	0.88
1583.1655270	0.91
1584.6862790	0.40
1585.8922120	1.93
1587.1346440	2.03
1588.5737300	3.49
1589.3137210	2.89
1590.2056880	1.65
1591.4967040	0.58
1594.1733400	1.30
1595.0469970	0.84
1597.1439210	0.07
1599.5224610	0.54
1603.0894780	1.56
1603.9156490	0.43
1605.2257080	0.15
1609.0299070	0.13
1609.9232180	0.44
1611.8710940	1.05
1612.6793210	0.93
1614.3620610	0.69
1615.8228760	0.80
1616.7553710	1.14
1619.8563230	0.63
1620.5462650	0.58
1622.8308110	4.25
1623.6579590	2.49
1624.4639890	0.78
1625.4251710	1.19
1627.0106200	0.68
1628.1187740	0.51
1629.0465090	0.17
1630.0916750	0.23
1631.1383060	2.12
1632.3483890	0.30
1633.3157960	1.76
1634.7235110	0.45
1636.8410640	5.40
1637.8575440	8.87
1638.7940670	5.57
1639.7332760	1.36
1640.7071530	0.97
1641.5950930	0.83
1643.7056880	0.62
1644.6926270	4.18
1645.7731930	2.94
1646.6614990	0.66
1647.3857420	0.35
1650.6436770	0.48
1652.0733640	1.25
1652.8947750	0.53
1655.6397710	2.95
1656.7592770	1.00
1658.1333010	0.30
1659.4354250	0.61
1660.3538820	0.14
1661.4368900	0.24
1662.4671630	0.77
1663.3433840	1.07
1664.0433350	0.36
1664.8155520	0.65
1665.8577880	1.62
1666.8514400	0.59
1667.8685300	2.45
1669.0921630	1.51
1670.4520260	1.89
1671.1651610	1.57
1672.4241940	5.50
1673.2233890	2.35
1673.8492430	0.31
1675.5521240	0.47
1676.6734620	0.92
1678.8341060	1.83
1679.7716060	1.96
1680.7257080	0.72
1681.6823730	5.99
1682.5349120	1.09
1683.6055910	0.55
1684.2697750	0.18
1688.3437500	11.94
1689.2999270	1.64
1690.3759770	3.81
1691.3489990	0.79
1692.7374270	0.61
1695.0543210	0.31
1696.1954350	1.19
1697.1038820	0.96
1699.2359620	1.18
1702.4687500	1.51
1703.8873290	1.31
1704.8072510	3.02
1705.9219970	1.42
1710.2799070	0.99
1711.2586670	1.55
1711.9854740	0.69
1712.7103270	0.51
1713.9030760	0.47
1715.5799560	0.52
1716.5782470	0.47
1718.7766110	4.38
1719.6502690	4.61
1720.5599370	0.08
1721.4411620	0.15
1725.0216060	0.41
1726.1521000	0.30
1726.8679200	0.43
1727.6696780	0.12
1728.2897950	0.22
1729.9671630	1.20
1730.9486080	0.11
1732.5645750	0.37
1734.6442870	0.49
1737.3826900	0.71
1738.1534420	2.04
1739.0467530	0.73
1739.9455570	0.84
1743.2072750	1.12
1744.6087650	0.11
1745.8375240	1.34
1746.7110600	2.77
1747.8801270	3.17
1748.5740970	0.78
1749.3464360	0.40
1752.0155030	0.74
1753.0792240	1.25
1755.6995850	1.14
1756.3458250	2.11
1757.0806880	0.37
1758.1395260	0.18
1760.7786870	7.65
1761.6026610	5.02
1762.5174560	0.45
1763.2198490	0.11
1768.1833500	1.30
1769.5574950	16.58
1770.2020260	7.13
1770.9499510	6.44
1774.5133060	0.51
1775.6232910	1.53
1776.4227290	0.64
1777.4154050	0.57
1778.0601810	1.01
1778.7966310	0.22
1779.6345210	0.45
1780.4337160	0.98
1782.1232910	0.17
1786.2000730	0.54
1787.5002440	2.57
1788.4777830	0.43
1789.6892090	1.08
1790.6317140	0.84
1791.7166750	0.62
1793.1524660	0.42
1794.2424320	0.32
1795.4270020	1.42
1796.5789790	1.92
1797.4538570	1.34
1799.1716310	0.44
1800.2176510	2.30
1801.0355220	0.37
1801.9191890	0.25
1802.9685060	2.24
1803.7023930	7.98
1804.7957760	2.78
1805.7521970	0.95
1807.1613770	1.35
1808.7069090	0.82
1809.5379640	0.35
1811.3513180	3.26
1812.0740970	0.44
1812.9680180	1.15
1813.7369380	0.63
1815.3507080	0.27
1817.9686280	1.22
1820.0838620	4.32
1821.1276860	1.37
1822.3011470	1.86
1823.9007570	0.85
1825.4735110	1.11
1826.1153560	0.17
1826.9925540	1.74
1828.7741700	1.44
1831.9578860	0.42
1832.7940670	0.25
1834.8013920	19.34
1835.7995610	15.46
1836.9471440	0.66
1837.9710690	3.00
1841.4035640	0.72
1842.7061770	0.49
1846.1253660	0.58
1847.2648930	0.19
1848.7115480	0.73
1851.2188720	0.33
1851.8936770	0.56
1855.1546630	1.06
1859.2083740	0.79
1860.8780520	3.16
1863.1473390	0.72
1864.5745850	0.15
1865.8302000	0.21
1868.1287840	1.90
1869.8658450	0.82
1877.3430180	5.04
1878.3609620	0.75
1883.9259030	0.90
1884.5285640	0.20
1885.6021730	1.31
1886.4270020	0.97
1890.3552250	0.56
1895.7645260	0.28
1899.0921630	0.11
1902.6927490	0.35
1920.6258540	0.31
1924.8107910	0.11
1968.9383540	0.14
1970.3531490	0.14
1971.5867920	0.08
1974.8455810	0.41
1987.8560790	0.17
1994.6998290	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	304.96
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0540009	0.01
129.2681427	0.05
142.0166626	0.02
151.0302887	0.03
153.0129700	0.01
155.3509827	0.02
169.2552795	0.03
190.0964661	0.02
204.1480408	0.01
226.0419312	0.02
230.2983093	0.01
231.9158325	0.01
237.1979675	0.02
242.7962036	0.02
245.1843872	0.01
246.3581543	0.01
247.5120544	0.03
257.1549683	0.03
258.8593750	0.24
259.5867310	0.04
260.9023438	0.01
263.8574524	100.00
264.8057251	0.02
269.3596497	0.01
275.0743408	0.03
276.9012756	0.02
277.9194946	0.02
281.5567017	2.51
282.5432129	0.03
283.7070312	0.04
284.4380493	0.03
286.7330322	0.15
287.4360962	0.06
290.9308472	0.03
292.5641479	0.02
295.2655640	0.01
296.2055664	0.04
299.5029602	0.07
302.9691162	0.01
304.8414612	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2883
Annotation	Unknow
Peak:m/z	Relative Intensity
209.2087402	0.07
220.9436340	0.15
232.5527039	0.11
259.0769348	0.11
282.3603210	0.06
313.3935242	0.15
315.2648926	0.08
318.7755737	0.17
320.3414917	0.08
324.3359375	0.06
329.1637878	0.25
331.0490723	0.13
343.3144531	0.25
349.4829712	0.25
351.3540649	0.22
361.3554077	0.33
374.8203735	0.38
386.9650269	0.11
393.3560181	0.39
397.5149536	0.07
421.2125854	0.20
447.6196899	0.31
449.2957153	0.06
451.2673340	0.18
459.4509888	0.20
460.3049927	0.09
475.2393188	0.04
476.4533081	0.26
479.4309082	0.09
497.1367798	0.13
526.9264526	0.11
542.8416138	0.28
561.6419067	0.21
565.5292358	0.35
575.0222778	0.23
589.4708862	0.07
597.6229248	0.16
610.1348877	0.16
611.3881836	0.14
615.9683228	0.17
619.9620972	0.29
632.4217529	100.00
633.5971680	0.82
634.7521362	0.93
635.8000488	0.14
637.5441284	0.87
638.6209106	0.15
641.5588989	0.09
642.5556030	0.22
676.4700317	0.12
751.3539429	0.28
764.1483154	0.20
766.5097046	0.10
991.3745728	0.08
1019.4624630	0.14
1085.3004150	0.04
1103.6593020	0.79
1122.0684810	0.22
1132.7250980	0.07
1147.3043210	0.12
1149.4807130	0.04
1265.4530030	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.21
Annotation	Stachyose
Peak:m/z	Relative Intensity
221.0387878	6.23
245.0446777	0.18
250.783905	2.50
262.2695618	1.30
262.9990845	0.22
268.8692017	0.24
280.9671631	2.00
305.043396	0.69
310.8017883	0.17
322.9078064	1.24
325.1318359	0.27
329.2072144	0.14
340.9277344	28.01
341.5314941	1.40
364.9979248	0.18
383.130188	100.00
408.3566895	0.64
409.1019287	0.21
412.7288208	4.43
425.0281982	0.55
429.2521362	0.28
442.201355	0.87
443.0439453	12.19
448.9607544	0.67
473.0597534	0.24
485.1613159	26.79
502.7258301	3.20
545.1750488	0.39
590.2324219	0.31
617.0758667	0.61
619.2813721	0.61
647.2125244	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	334.1078
Annotation	gamma-Glutamyl-S-methylcysteinyl-beta-alanine
Peak:m/z	Relative Intensity
110.1674881	0.06
113.0599213	0.31
127.9721527	27.39
135.5232086	0.21
137.8856354	0.08
140.0204010	0.13
145.8723755	0.04
152.2014771	0.14
153.1277924	0.65
157.0069885	7.92
158.4915161	0.38
159.1399231	2.62
169.9261169	0.20
177.9583740	1.41
179.0784760	8.56
181.3020630	0.07
181.9168549	0.05
183.9399872	2.69
185.1528625	4.12
189.6975555	0.10
196.0668945	16.19
197.0927429	2.91
199.2269592	0.37
205.0758057	6.75
206.2418518	0.17
214.1181030	0.88
219.9560852	0.10
224.1993713	5.03
225.1659546	0.15
226.2674866	1.37
227.0915527	1.83
233.3252258	0.19
241.0061035	0.10
242.1699219	3.67
244.0987854	2.38
245.1339417	0.25
246.0744324	0.10
250.0727234	0.75
250.9631958	0.10
262.0949097	3.14
263.0701904	0.13
268.0956726	100.00
269.0589600	0.04
270.3357544	0.16
275.1077271	0.14
280.2437744	0.05
286.1385193	96.93
287.8114014	0.24
290.1810303	0.02
316.0933838	94.10
316.9249878	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1628
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
196.8284607	0.05
214.8541718	0.02
227.0208740	0.07
243.1985931	0.04
260.8359680	0.01
271.0950317	71.70
273.0950012	0.02
274.2931213	0.02
301.0401611	0.06
303.1322937	0.07
304.1734009	0.07
317.2868042	0.03
349.0170288	0.03
372.7833252	0.02
379.3209839	0.02
391.2089844	0.05
392.2564087	0.05
415.1229248	0.21
425.3520508	0.08
433.0684204	100.00
433.7015991	0.55
439.1637573	0.03
443.1867676	0.05
455.0898438	0.03
464.4500122	0.04
465.8358765	0.11
475.2536621	0.06
492.4473267	0.05
503.2012329	0.07
531.2974243	0.02
532.9027710	0.06
541.1488037	0.03
549.9968872	0.02
551.2518311	0.03
577.2415161	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.2313
Annotation	Frajunolide G
Peak:m/z	Relative Intensity
187.9729919	43.22
188.6058960	0.29
201.1420288	0.05
203.4500732	0.15
205.0019684	100.00
236.9890442	0.06
256.7380371	0.48
265.1351929	0.08
275.1506042	8.61
277.2175903	0.31
283.2311401	0.27
301.0292664	0.20
305.0403442	0.30
333.5385742	0.06
334.2152100	0.12
341.6193237	0.23
342.3551025	0.28
383.2064819	0.56
410.9992676	0.05
417.3050537	0.26
418.3561401	0.29
419.1676025	0.25
422.9051514	0.12
433.0438232	0.07
436.9535522	9.14
444.5202637	0.07
462.1293335	0.48
468.1830444	0.24
477.2290039	0.76
478.2067261	0.99
479.2111816	1.35
484.3853760	0.25
489.2321167	0.12
494.8982544	0.05
499.5687866	0.30
503.0967407	0.05
512.2379761	0.08
521.3685913	0.28
537.3836060	0.19
569.2359619	0.14
579.3867798	0.09
605.0628052	0.38
615.2520752	0.26
623.2047729	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.13
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
128.0303040	100.00
130.1474915	1.30
197.1508026	0.06
223.1602783	4.16
241.0940552	56.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.1227
Annotation	Patuletin 3-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
153.1335754	0.16
163.0727997	0.63
173.9042969	0.04
177.0847931	0.08
178.7678223	0.05
185.2794189	0.07
189.1325378	0.41
194.9727936	5.66
196.7039185	0.04
200.0674438	0.26
203.2887878	0.14
204.7464905	0.06
218.8479462	0.11
220.8563538	0.09
230.9701538	0.20
235.0992126	0.21
248.5994263	0.04
251.1380157	0.11
252.9133606	0.07
253.5646667	0.13
254.6922302	0.09
267.3999023	0.15
279.1970825	0.06
287.2601318	1.27
288.2433472	1.23
289.0702515	24.23
303.1025085	0.06
310.1404419	0.08
313.1445312	10.92
321.1070557	0.08
325.4227295	0.14
327.5368042	0.26
329.1768799	0.17
331.1649780	28.72
355.1845703	9.57
365.0710449	1.27
368.6156006	0.11
373.1415405	0.45
379.1032104	1.97
383.0792236	2.59
390.9186401	0.18
395.2886353	0.09
397.1883545	16.98
401.1176758	0.07
403.3290405	0.04
408.8330688	0.06
415.0618896	0.71
417.3337402	0.15
436.7482300	0.14
439.3486938	0.12
451.2367554	0.31
457.1690674	1.09
463.2611694	0.08
465.1503906	0.50
477.8884888	0.08
481.4862061	0.07
483.1715698	2.89
501.1088257	28.51
509.1110840	0.11
515.3426514	0.77
519.1169434	100.00
520.0519409	0.18
520.7633667	0.06
528.0159302	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1614
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
183.9618530	0.03
193.3452454	0.05
194.9690094	0.11
208.1174316	0.11
215.1577759	0.03
223.0865479	1.26
224.9970551	0.03
226.5937347	0.10
227.2283630	0.23
233.1091461	0.07
239.1371002	0.10
241.1813660	0.12
243.1728210	0.70
244.3916626	0.19
253.9744263	0.27
255.0747833	3.20
256.1583252	0.42
259.1111450	0.09
261.2302856	0.06
265.1296387	0.09
267.1074219	0.05
271.0269470	6.45
272.0734558	1.73
273.2714233	0.17
278.7252502	0.07
283.0109863	0.06
284.3816528	0.11
285.8461304	0.04
287.1885376	1.00
290.3056641	0.21
296.9913940	0.11
300.0017395	24.17
301.1145020	0.27
303.1289673	0.05
313.1826172	0.67
314.0396729	2.53
315.0678711	100.00
316.1697998	0.73
317.1315918	0.20
327.1954346	0.03
328.3159790	0.10
328.9653931	0.03
339.1405029	0.04
341.1077271	0.20
355.1018677	0.05
357.2456055	0.89
358.4802856	0.06
359.2833252	0.17
360.3463745	0.06
373.8917847	0.09
375.1869507	0.03
389.2329712	9.49
402.2432861	0.07
413.2492065	0.14
417.3057251	0.07
419.0740356	9.93
425.0469971	0.12
427.2899780	1.57
428.9417114	0.14
432.8628540	0.05
449.3420410	0.15
460.8484497	0.09
462.9381714	0.04
471.3159790	0.05
478.2480469	0.18
479.2672729	0.07
484.1075439	0.04
490.0415039	0.14
509.1050415	0.07
521.3197632	0.23
531.1976929	0.04
533.0353394	0.24
534.1578979	0.06
534.9296265	0.04
560.3545532	0.12
561.6085815	0.07
563.2720337	0.53
575.1296997	0.30
576.3986816	0.32
579.2824707	1.76
581.0510864	0.06
589.2166138	0.09
589.8806763	0.04
591.2319946	0.56
592.3003540	0.17
593.2636719	0.17
594.5849609	0.09
595.2385254	0.37
596.0451660	0.06
601.2507935	0.09
604.6483765	0.30
605.4784546	0.26
608.3405762	0.15
609.9229126	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0863
Annotation	Methionyl-Glutamate
Peak:m/z	Relative Intensity
127.9390564	100.00
147.9880676	1.56
167.0679474	0.07
191.2757263	0.21
211.1466370	0.04
229.2309265	0.05
241.0809937	5.23
259.1585083	70.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	650.33
Annotation	Unknow
Peak:m/z	Relative Intensity
189.9464569	0.03
193.0042114	0.27
208.8626404	0.06
211.4321594	0.14
215.1613312	0.08
221.3232422	0.05
223.3685303	0.04
233.0934448	0.04
235.4478760	0.05
237.3896484	0.06
250.9775085	0.07
270.1817322	0.06
275.2488403	0.36
286.2331848	0.02
288.4208984	0.02
291.3180542	1.21
293.2951050	3.27
296.2469177	0.03
303.2680359	0.17
304.3055420	0.14
307.1203918	0.04
309.2588501	0.06
311.1388550	0.36
314.2266235	0.06
315.2811279	0.02
322.0726318	0.24
323.4360046	0.09
324.7624512	0.02
326.3370972	0.03
333.3370056	0.23
342.2731323	0.10
343.3397217	0.07
344.3312378	0.09
353.2200928	0.03
357.9541016	0.05
360.0494995	0.17
361.1622314	0.05
362.5825806	0.04
369.1839600	0.41
373.0957031	0.08
379.6137085	0.04
386.2476807	2.43
387.2199707	0.51
390.3558350	0.03
396.3163452	0.21
401.2711792	0.21
403.4299927	0.09
414.2724609	0.02
416.1054688	0.09
418.2113037	0.03
421.5982056	0.02
432.2929077	0.04
443.1885376	0.11
450.2799072	0.09
467.4619751	0.35
468.3018188	1.30
474.9747314	0.10
477.9887085	0.09
479.1835327	0.03
486.1184692	5.17
489.1298218	0.23
498.5371094	0.08
500.5398560	0.16
503.2706909	100.00
504.1802368	0.02
521.2524414	69.77
521.8568726	0.48
530.1391602	0.06
543.4641724	0.51
561.2865601	2.97
569.3024292	0.06
587.1745605	0.27
590.1118774	0.14
607.4809570	0.12
608.6998901	0.21
614.4044189	0.82
615.2707520	0.11
618.9745483	0.11
620.5413208	0.08
630.2637329	0.29
632.2363892	36.97
632.8952637	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0776
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9839630	0.26
128.9478760	1.82
145.0543671	0.05
147.0396118	3.34
173.0150452	2.43
190.9717102	100.00
192.9065857	0.37
209.1308594	9.74
222.9388428	0.44
305.2337341	0.14
323.3762512	0.05
348.9489136	0.17
367.0024719	7.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.32
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0153198	0.07
208.7162170	0.82
209.4474182	0.28
227.0369873	0.34
239.2534790	0.12
244.8359222	0.10
252.3007202	0.06
253.4848328	0.12
258.2392578	0.34
270.1613770	0.11
287.1409912	0.10
288.2461548	0.08
291.0721741	0.44
292.1587524	0.06
293.2511597	0.03
294.3890381	0.09
301.2554626	0.07
303.1389160	0.04
304.6353760	0.25
319.1785278	0.06
322.1266479	0.11
323.2271118	0.07
328.1788330	0.03
336.1001587	0.04
338.1431885	0.04
340.2351074	1.22
347.1618652	0.42
358.0435791	1.85
366.1655273	0.14
388.8590698	0.26
390.0818481	0.32
398.2472534	0.08
402.1269531	0.04
405.0124512	0.04
406.9095459	0.26
416.2836914	0.47
419.2431641	0.16
420.2067871	0.55
426.3206177	0.06
433.2452393	0.31
437.3259277	0.09
443.3791504	0.31
451.2576904	0.07
452.9819946	0.03
467.3051147	0.16
479.1495972	0.19
481.1469727	0.07
487.3588867	0.13
497.4125977	0.94
500.9270020	0.12
503.2191162	0.03
504.7268677	0.07
505.3594971	0.06
513.3238525	0.25
514.5978394	0.43
515.3640747	1.20
517.3101196	0.27
521.1543579	0.03
525.7614136	0.12
527.1489868	0.26
532.5470581	0.91
533.2570190	6.82
533.9201050	0.02
535.1170044	0.11
544.4300537	0.02
546.2361450	0.12
548.1752319	0.28
550.3173218	100.00
554.5792847	0.05
562.9812012	0.18
571.9570923	0.72
572.7161255	0.26
585.4097290	0.11
590.3869019	7.10
599.1130371	0.05
602.0723877	0.12
609.1233521	0.08
615.8728027	0.04
633.0812988	0.43
642.9408569	0.18
643.5438843	0.13
649.3861694	0.17
659.9627075	0.40
661.1320190	3.40
662.0863647	0.23
667.0823364	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	239.0562
Annotation	(1R,6R)-6-Hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate
Peak:m/z	Relative Intensity
86.9829788	0.43
91.0300903	0.09
94.7507629	0.04
105.8047333	0.02
107.0331879	2.59
133.0176544	1.09
135.0869904	2.51
148.9747162	59.57
150.9041595	0.58
177.0691833	59.56
179.0426483	100.00
192.8567963	2.59
195.0351410	14.34
202.9832611	0.19
209.2167206	0.04
211.8977509	0.05
221.0554962	14.20
238.9697723	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1521
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
161.0799408	0.20
163.1189575	0.23
165.0055084	3.29
167.1407013	0.20
169.1282196	0.19
171.1033783	0.39
178.9499054	0.78
181.1469421	0.25
185.1348877	1.01
186.9291992	0.60
188.9787598	0.77
191.0842896	0.24
193.0751648	0.15
199.2011566	0.42
201.0676880	0.16
203.0336761	0.10
207.0461121	0.34
213.0359802	3.41
215.0715637	0.80
216.6686401	0.05
227.0316467	1.42
229.3391418	0.35
231.0211792	32.18
233.1049957	0.74
243.0215302	7.32
245.0927124	1.62
248.9503021	0.16
251.2769470	0.16
253.0336609	0.07
255.1513672	8.42
257.0629883	1.14
259.1130981	0.18
267.1151123	1.69
271.1927795	0.09
273.1262817	46.81
275.0823975	8.26
285.0482178	28.45
287.1643982	3.73
289.2515564	0.11
291.0636597	93.48
297.1491699	0.71
299.1751709	1.46
303.1052856	8.76
308.7954712	0.12
315.1493835	0.57
317.1461792	0.31
325.2474365	0.33
330.9540405	0.14
333.1137695	1.29
361.1233521	0.09
377.4072876	0.38
381.3005371	0.08
390.9057007	0.11
393.1080933	73.76
395.1793213	16.16
401.1823730	0.17
405.0883179	4.89
406.9860840	0.95
409.1471558	8.10
411.0247192	100.00
412.0490112	0.17
419.2497559	3.17
421.2887573	0.12
423.0727539	5.27
425.3002319	0.21
427.0832520	24.27
427.7020264	0.14
428.3485718	0.12
434.2374268	0.16
437.0123901	5.82
439.1459351	1.06
441.1094971	0.27
527.1909790	2.82
545.0513306	4.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.163
Annotation	Pelargonin
Peak:m/z	Relative Intensity
180.7213745	0.04
271.0603638	69.44
271.916687	0.03
287.0256348	0.13
303.2901001	0.12
304.7766724	0.04
313.2627563	0.03
331.8936157	0.02
347.2318726	0.08
367.2981567	0.08
397.4197388	0.06
406.8490601	0.04
411.284729	0.08
415.3775635	0.16
417.0372314	0.05
423.187439	0.11
425.3082275	0.17
433.0993042	100.00
447.9087524	0.13
459.1639404	0.04
465.220459	0.02
466.1176758	0.02
480.5530396	0.05
498.1911011	0.19
507.2098389	0.04
541.0792847	0.04
548.0352783	0.15
549.4473877	0.05
577.2451782	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	839.3297
Annotation	Unknow
Peak:m/z	Relative Intensity
276.8339233	0.33
285.1841431	0.20
303.3510742	0.16
320.9602356	0.06
325.0052490	0.35
387.4146729	0.29
427.4127197	0.27
487.1753540	0.52
505.9519043	0.12
518.9323120	0.06
520.2496948	0.16
560.5263672	0.10
604.4440918	0.11
609.2810669	0.45
623.3159180	0.12
627.2017822	7.08
645.3436279	1.93
659.2268066	24.84
666.9481201	0.10
669.0262451	0.21
671.2570190	0.34
675.5497437	0.28
677.1829224	0.78
700.1843872	0.15
703.4215088	0.15
723.1250610	0.81
746.6802368	0.74
768.8577881	0.35
785.2175903	0.45
789.1931152	18.05
790.6480103	0.86
799.7855835	0.39
803.1763306	0.34
807.0311890	10.33
807.7030029	0.38
809.0161743	0.29
821.0979614	100.00
821.9187622	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1756
Annotation	Bis-gamma-glutamylcysteinylbis-beta-alanine
Peak:m/z	Relative Intensity
178.1508789	0.15
179.0721741	0.69
184.1854095	0.27
189.0708008	0.09
191.1159363	0.18
195.9863586	0.50
197.2017670	0.20
212.1265259	0.08
214.1650848	0.11
223.2189941	0.10
224.2204590	0.46
228.1363220	0.30
231.0364227	0.11
240.2483521	0.35
242.0813599	0.37
248.2383881	0.07
255.9389648	0.05
262.9587402	0.12
268.1421204	6.78
274.1735229	0.05
286.1869202	23.25
300.1826172	0.26
302.2160034	4.72
318.1578979	16.86
320.1359863	100.00
320.7450256	0.64
333.9160156	0.37
352.0968628	28.97
381.0731812	0.68
492.1169434	1.98
510.2732544	55.43
603.1195679	0.76
603.9528809	0.65
609.3106689	0.07
621.1679077	28.02
622.2300415	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	158.9785
Annotation	Unknow
Peak:m/z	Relative Intensity
56.4008446	0.03
71.0133820	0.34
85.1858520	0.05
97.0222015	0.23
112.9730530	0.14
114.8643036	100.00
128.7460327	0.06
130.9350281	2.80
133.1103973	0.06
141.0650635	0.18
158.8900757	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.2579
Annotation	Atractyloside D
Peak:m/z	Relative Intensity
170.0845032	0.58
181.0385742	0.08
188.0133820	53.60
191.1977997	0.01
199.0114746	0.13
203.7734528	0.07
205.0869751	100.00
226.6628876	0.02
234.8631134	0.40
244.1361084	0.04
252.7812042	0.06
259.1233521	2.51
261.0243530	0.04
270.5790710	0.02
277.0685120	0.11
289.4909668	0.03
299.2197266	0.13
306.5366821	0.03
317.1855164	0.11
325.0976562	0.03
341.4034424	0.05
343.0152588	0.24
361.0708618	3.07
364.0099487	0.03
377.3035278	0.04
379.0142822	10.45
379.6749878	0.04
396.8505859	3.39
431.1269531	0.05
435.0557251	0.03
438.9474487	0.03
555.4635620	0.09
567.3027344	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.1982
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0375214	2.55
131.0989075	0.76
168.0352020	81.54
245.0124512	0.44
278.1712341	0.19
282.1341553	0.25
292.2303467	1.40
294.6816711	0.63
295.8571167	16.57
296.7971802	100.00
297.6953125	0.55
310.1617737	0.37
311.3873901	0.53
314.2852173	0.43
315.0066833	1.13
362.2429504	0.71
407.9913940	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8858032	11.80
246.0422974	0.50
251.2334290	0.32
290.7316284	100.00
291.3466797	0.52
347.3179932	0.07
348.0524902	0.42
349.0913086	0.55
374.6517029	19.25
430.2248230	0.11
431.3903198	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
113.1324997	0.04
145.1296997	0.02
160.8885193	0.08
162.1324463	0.03
179.0541077	0.69
181.2276001	0.06
199.1179504	0.32
215.0152283	0.31
217.0681763	8.18
341.1453857	100.00
342.1104126	1.04
343.1621399	10.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	759.3076
Annotation	Unknow
Peak:m/z	Relative Intensity
225.3506165	0.13
244.4444275	0.12
245.1444092	0.08
289.0208130	0.08
307.1041565	0.10
335.2116089	0.66
353.4915466	0.22
369.0865479	0.37
370.1895142	0.15
371.1809082	1.10
387.2783203	0.30
389.1989746	1.74
429.3899536	0.07
431.2850952	0.57
454.9320068	0.06
461.0996704	0.04
487.3037720	0.11
511.1607056	0.12
519.4265137	0.09
543.3668823	0.05
553.3508911	0.32
557.0238037	0.06
562.5384521	0.19
565.6284790	0.07
578.2484741	0.05
579.1604004	0.11
581.2681885	0.18
582.2903442	0.09
582.9242554	0.04
586.2643433	0.06
596.4451904	0.13
597.4525757	0.08
614.5626831	0.19
617.2201538	0.06
643.1321411	0.10
651.2892456	0.13
655.4605103	0.24
656.5255737	0.09
664.1115723	0.18
667.7067261	0.05
673.2897339	0.55
675.0955811	0.10
693.1093140	0.15
695.4175415	0.11
696.8030396	0.16
697.4193726	0.05
698.9733276	0.54
711.1262207	0.14
713.2151489	0.30
715.2296753	100.00
715.8469849	0.47
723.4370728	0.19
727.5888062	0.14
731.0753174	0.25
740.2659912	0.04
741.3854980	0.90
742.4594116	0.17
744.4032593	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.1551
Annotation	Unknow
Peak:m/z	Relative Intensity
81.1241760	0.07
83.1560211	0.44
84.1733093	0.16
85.0032120	5.62
86.9315948	0.16
94.9481659	2.08
96.9918518	8.13
98.8652496	0.48
101.0970306	0.89
106.0853882	0.15
106.9455872	0.27
109.0518188	3.35
111.0441742	19.41
113.0395050	5.84
115.0191956	16.28
118.9925537	0.14
121.0112305	0.62
122.9191742	0.57
125.0651855	1.52
126.9681244	22.17
129.0697937	0.10
133.1139526	0.86
134.9964447	0.76
137.1188660	19.08
139.0011444	2.41
141.0540619	2.98
143.1396942	0.58
143.8656769	0.56
145.1988678	0.32
149.0956421	1.40
151.0321655	8.18
153.1316833	1.39
155.0225983	100.00
156.9918060	16.45
159.2216949	1.22
160.9969025	1.45
161.8665314	0.08
163.0148621	0.71
164.0380707	2.08
164.8790436	0.64
166.0019073	0.19
167.0996246	3.01
169.0822296	1.17
171.1777954	0.92
173.0543518	3.42
175.1555023	0.21
176.0440674	0.23
177.0854340	2.71
178.0504303	0.16
179.1481323	1.04
180.0608368	0.22
181.0845337	1.25
183.2705536	0.24
184.1136169	0.20
185.1791534	0.48
186.9736938	1.20
189.1417694	0.56
191.1713409	40.77
195.0106354	25.38
199.0975800	2.56
200.7901306	0.15
202.3025055	0.59
202.9925690	0.54
205.2624664	0.26
207.2632904	1.30
209.1333618	7.79
212.0550385	0.24
213.1703033	14.97
215.4032440	0.57
217.1984558	12.07
221.2280121	0.25
222.9167938	0.87
225.1814575	2.90
227.1395569	1.29
227.9245148	1.72
235.2182465	58.34
236.9702301	0.45
243.0564575	0.74
251.1787720	0.64
253.2256927	30.72
256.0969238	0.07
270.9573669	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1528
Annotation	Gambiriin B2
Peak:m/z	Relative Intensity
160.8410339	0.06
163.0018311	1.57
165.0728302	0.11
170.9787292	0.13
173.1129456	0.28
181.2778778	0.11
182.2023926	0.13
184.9578552	0.05
186.9657593	0.29
191.1484070	0.13
193.1671906	0.11
197.2289886	0.27
200.9731598	0.36
205.0223999	0.42
207.1216431	0.27
215.1756287	0.09
219.1604156	0.15
225.1000061	0.55
226.7982025	0.27
229.1716766	1.55
231.1403503	2.61
233.0469818	1.09
239.0511017	0.26
241.1247253	0.94
243.0111237	2.73
247.0260468	14.15
247.9753876	0.20
253.2504272	1.47
255.0625916	1.24
256.8350220	1.83
257.4436951	0.23
259.0138550	15.09
261.0848083	1.02
262.3156128	0.13
269.0473633	2.16
271.0592651	14.35
272.0950317	0.44
273.1046143	7.39
275.1202393	100.00
279.0859070	0.24
281.0598755	0.31
283.1438599	2.52
285.0079346	1.05
287.1768188	23.31
288.9966431	49.64
289.6998291	0.40
291.1006775	7.11
295.1086426	0.48
296.9855652	0.05
298.3956909	0.70
299.1056519	4.34
301.0164185	22.18
303.2398071	0.29
310.8092041	0.08
312.7095947	0.40
313.4107666	0.41
317.1124268	3.09
322.4732056	0.16
325.1678467	0.74
327.3629761	0.57
329.3626709	0.45
334.3464966	0.14
363.0601807	0.33
374.3157959	0.07
377.1456299	0.41
383.1523438	0.10
387.1334839	0.39
391.3726807	0.49
393.1686401	23.94
393.7711182	0.25
395.0795898	15.24
395.6883545	0.30
400.9606934	0.20
403.3338013	0.15
404.9540405	1.05
407.0865479	0.92
409.0613403	75.61
409.6776123	0.37
411.0641479	42.45
411.6776733	0.38
415.0136719	0.28
417.1392822	0.28
419.1326904	10.15
421.2001953	10.43
422.9871216	1.74
424.8595581	0.37
427.1368408	83.61
428.3207397	0.18
434.8388062	1.19
437.0386353	17.03
437.6674805	0.03
439.0659790	17.93
442.1907959	0.40
468.5116577	1.21
469.3937988	0.33
478.1558838	0.51
505.3262329	0.13
514.1796265	0.21
527.1710815	6.07
531.7136230	0.26
535.2907104	0.42
545.0233154	13.64
553.6921997	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.1541
Annotation	Unknow
Peak:m/z	Relative Intensity
95.1674728	0.07
96.7234344	0.17
97.9518051	0.44
101.9439087	0.09
110.1496964	0.11
111.0407410	0.19
112.0052643	3.43
115.9252930	0.03
122.6248016	0.06
129.1383514	0.26
130.0086975	0.03
135.0242920	0.10
136.0360718	0.59
137.1968536	0.62
140.0219421	2.66
147.2995605	0.12
148.1145325	0.76
157.9753571	100.00
158.9775391	0.07
167.1543274	0.13
167.9811096	0.14
170.9223633	0.09
172.6216278	0.05
176.9252930	0.74
180.0940399	0.20
184.0711975	0.05
184.9605103	0.46
185.7398071	0.13
194.1152496	0.05
200.8504181	0.29
202.8627625	0.07
205.0717773	0.08
210.2179565	0.71
218.2420654	0.16
227.3320312	0.13
228.2267151	0.28
229.7426147	0.06
230.6460571	0.18
234.2068481	0.36
237.1396790	0.44
240.7943115	0.06
243.4080505	0.14
244.9538574	0.36
245.5819092	0.52
249.6443176	0.17
251.2902832	0.21
252.7738342	0.17
254.1995544	0.34
255.2235718	0.23
257.0633545	0.35
259.1614685	0.08
265.2056580	0.09
269.1042786	1.52
271.1745300	0.81
273.1480103	2.40
273.9467468	0.81
287.0695496	0.09
288.3652954	0.10
292.6591187	0.04
297.1336670	4.35
298.1746521	1.06
304.5564270	0.50
306.0711060	0.09
306.6996460	0.32
309.0354614	1.05
314.2626953	0.04
315.2409973	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1297
Annotation	Phloridzin
Peak:m/z	Relative Intensity
125.032196	1.57
133.9460297	0.04
137.0093384	1.02
138.8424072	0.02
147.0869598	0.15
148.8566589	0.23
161.0588531	1.12
167.3551331	0.04
172.2276306	0.02
179.0084534	0.09
186.2260132	0.14
187.1504669	0.18
188.2541504	0.06
189.1481628	0.11
191.2109375	0.30
201.1529999	0.09
205.1743774	0.02
221.0675507	0.07
227.0688171	0.02
228.1224518	0.03
229.137558	0.81
231.2961121	0.04
249.2203979	0.06
251.0644226	0.04
255.2292786	0.31
273.0717468	100.00
287.0620422	0.14
297.15448	0.42
299.038269	1.48
312.1025391	0.05
329.2103271	0.03
332.7553101	0.05
334.2415771	0.03
343.0497437	0.02
364.0851746	0.02
375.0634155	0.02
380.9217529	0.04
389.1205444	0.01
393.2287903	0.18
417.3995056	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.3757
Annotation	Janthitrem G
Peak:m/z	Relative Intensity
190.0786133	0.08
213.0726624	0.09
219.1250610	0.04
229.2897034	0.01
238.2721405	0.06
261.7102966	0.11
267.1786499	0.03
273.1972046	0.01
276.4492798	0.03
289.7526855	0.06
295.0572510	0.09
296.1367188	0.03
297.3023071	0.05
317.4273682	0.14
318.3029175	0.16
319.3491821	0.04
321.8467102	0.06
334.3120728	0.33
352.3248291	0.18
366.5606079	0.03
367.7891846	0.09
370.0189819	0.04
379.7403564	0.02
386.6348877	0.02
392.2205811	0.04
401.3253174	0.08
405.0911865	0.02
423.5620728	0.02
426.4547729	0.04
436.4751587	0.02
448.8591919	0.07
450.7922363	0.03
453.2008667	0.02
458.3364868	0.08
461.5896606	0.04
479.2705078	0.04
483.1237183	0.03
489.4682617	41.64
501.3694458	0.12
505.5081787	0.11
514.4017944	0.01
520.6500854	0.05
526.4633179	0.05
532.4724121	0.03
560.1980591	0.04
563.3865356	0.04
569.5046387	0.08
570.8738403	0.05
571.4898682	0.08
577.1791382	0.08
581.0945435	0.04
582.3955688	0.10
588.5487671	0.03
592.3720703	0.02
595.0760498	0.03
598.0137329	0.16
599.2384644	0.13
602.8025513	0.09
608.0090942	0.15
612.4010620	100.00
613.5570068	0.10
619.6815186	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.18
Annotation	O-Methyl-waltherione A
Peak:m/z	Relative Intensity
130.1087494	0.24
132.9624786	0.15
145.0303955	0.20
147.0000458	0.05
150.0501404	0.49
157.9821472	1.37
159.8932190	0.15
162.0531921	0.46
165.1973877	0.16
165.9259491	0.04
175.9966278	10.90
191.9827118	0.02
193.0679321	11.08
197.1578369	0.04
199.0249786	0.03
201.0177765	0.04
205.1046295	0.04
220.0950623	0.04
225.3514709	0.06
227.3106384	0.04
234.0204468	0.18
242.0328979	0.84
243.3098450	0.06
246.0926819	0.22
251.2919006	0.08
256.0120239	0.04
260.2024231	3.30
261.3263245	1.68
262.0139160	3.09
265.0232239	0.13
271.3484497	0.08
273.1029663	0.11
279.0520630	100.00
286.2952271	0.04
287.0581055	0.05
288.2704163	0.04
290.9051514	0.05
293.0579529	0.06
296.1049805	0.02
305.0299377	0.04
319.1530151	2.72
322.2479248	0.11
327.2044067	0.14
344.7261963	0.25
345.9824524	0.07
347.1728821	0.04
360.4096985	0.06
361.3593750	0.07
362.0235291	0.56
363.1136169	0.07
364.1816406	0.40
372.3025818	0.39
373.1673889	0.41
377.2192688	0.04
390.0600891	3.05
390.7784119	0.25
391.4955139	0.21
399.9534302	0.03
419.3728943	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.9608
Annotation	Unknow
Peak:m/z	Relative Intensity
188.3964539	0.02
195.2125092	0.05
209.1936340	0.07
219.1741943	0.02
227.5759125	0.01
231.0615845	0.04
236.2790985	0.02
255.3503723	0.03
264.4432983	0.06
269.1136475	0.09
272.9123535	0.02
281.4562378	0.04
282.0753479	0.09
291.2725220	0.03
292.4454346	0.01
294.2130127	0.05
297.4310303	0.06
300.4088745	0.01
313.8879395	0.02
315.3082275	0.03
319.1638184	0.02
330.2243042	0.02
331.2640381	0.06
335.4034424	0.01
344.4736938	0.02
345.3283691	0.08
346.3472900	0.02
354.3494873	0.03
355.5117188	0.02
359.3751831	0.02
363.2432251	0.01
380.2391357	0.02
381.1215210	0.05
384.4248657	0.08
386.2442627	0.02
396.5063477	0.01
402.1832275	0.12
403.1293335	0.04
406.3026123	0.02
426.2205811	0.04
429.2228394	0.07
449.3701172	0.04
452.4089966	0.02
453.3004761	0.03
461.5241089	0.02
463.3341675	0.04
465.5829468	0.02
477.2698975	0.02
510.4890747	0.05
523.7015991	0.03
525.3258057	0.03
529.2702026	0.06
543.3244629	0.07
556.5281372	0.01
557.5261841	0.04
566.5005493	0.03
567.5338745	0.08
581.0006714	100.00
581.6128540	0.22
583.6999512	0.01
587.2706909	0.02
597.3519897	0.03
598.6043091	0.07
600.8324585	0.69
601.6420898	0.03
606.1902466	0.03
608.4654541	0.29
609.2789917	0.03
624.9573364	0.23
627.3026733	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.5082
Annotation	Phosphatidylethanolamine 18:2-18:2
Peak:m/z	Relative Intensity
214.2452393	0.03
233.1115112	0.10
241.9206696	0.08
243.2501984	0.04
251.3636017	0.03
255.2137756	0.05
257.6273193	0.02
258.4783936	0.04
261.2246704	0.24
262.344574	0.21
267.1394043	0.04
277.2648926	7.71
279.1820068	100.00
280.1885376	2.01
281.3503723	11.21
291.3111572	0.15
293.7368469	0.02
295.2393799	0.03
296.15625	0.05
305.6738892	0.03
324.1969604	0.10
345.1027832	0.24
391.2988281	0.02
408.2595215	0.03
410.1970215	0.16
414.9941406	0.15
425.508606	0.03
455.8414307	0.12
458.2423706	1.62
458.9437866	0.05
459.6729736	0.05
474.222168	0.80
475.3966064	0.99
476.3311157	12.79
477.3955078	0.62
478.2859497	0.14
485.3424683	0.07
494.0918579	0.02
520.3671875	0.06
521.362915	0.08
538.4066162	0.18
544.6271362	0.07
551.461731	0.04
552.4669189	0.05
553.2665405	0.27
553.8721313	0.11
554.87323	0.13
566.5380859	0.10
567.2415161	0.04
576.194397	0.03
581.24823	0.12
584.6201172	0.08
602.309021	0.07
606.1079712	0.12
619.7144165	0.04
630.682373	0.29
660.2984009	0.04
661.4416504	0.03
673.8131104	0.04
678.2388916	0.27
679.5670166	0.17
694.677063	0.05
700.2584839	0.05
705.5706177	0.04
720.4320679	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	206.0823
Annotation	2-Acetamido-4-methylphenyl acetate
Peak:m/z	Relative Intensity
70.0547562	0.28
91.1265793	0.04
147.0834198	10.29
162.0887756	0.41
164.0115356	100.00
165.1313324	0.06
188.1120300	1.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	817.3489
Annotation	Unknow
Peak:m/z	Relative Intensity
240.9817047	0.41
245.0073700	0.47
258.9743042	0.09
271.1175842	0.15
273.2431030	0.08
281.1886597	0.09
283.3249512	0.13
286.1464844	0.04
288.9624634	0.23
311.1156311	0.09
312.1981812	0.16
314.2012634	0.09
319.3031006	0.15
329.2804260	0.11
331.5307312	0.11
333.2720642	0.26
335.3345642	12.81
337.2175598	4.10
349.5420532	0.34
351.6134033	0.25
354.5173340	0.06
355.3385010	0.20
361.1789551	0.04
365.1861877	0.38
379.0665894	1.23
397.2531738	0.28
406.9254761	0.19
408.9408569	0.06
409.5577393	0.16
418.0854492	0.17
419.1958008	0.23
420.1462402	0.05
423.4054565	0.19
436.9957886	0.39
461.0505371	0.15
479.0418701	0.11
481.0753174	12.72
481.6806030	0.16
483.5988159	0.15
492.6773682	0.23
493.3944702	2.69
495.4790649	0.13
496.8627319	0.15
503.3314819	0.27
507.1982422	0.16
509.4976196	0.15
511.2755737	59.04
517.4744263	0.13
527.3695679	1.60
529.2550049	0.12
532.9686279	0.09
535.1964111	0.38
543.1245117	1.78
545.1345215	1.54
545.9929810	0.23
553.3284302	7.75
555.3367920	0.73
557.5892944	0.13
565.2130737	0.03
571.4080811	0.05
575.2124634	0.22
593.2312012	0.97
593.8524780	0.05
595.5658569	0.12
607.0203247	0.95
611.5791626	0.31
622.3464966	0.19
629.1560059	0.13
635.3988037	0.14
637.4420776	0.19
639.1384888	0.17
641.3291626	0.37
655.2022705	12.79
655.8035889	0.29
663.1583862	0.19
673.2401733	100.00
673.8607788	0.79
679.8508911	0.13
681.0822144	0.21
687.0415649	0.27
690.4149780	0.34
691.0437622	1.76
692.0953369	0.12
715.1939087	19.34
717.2833862	0.10
739.6322632	0.24
741.0164185	0.06
746.5836792	0.33
748.7897339	0.34
754.6963501	0.28
755.3323364	2.91
757.2433472	0.38
771.3612671	0.33
773.0431519	0.60
799.0744629	1.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.0882
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9442139	0.09
145.0317535	0.21
147.0880432	1.97
173.0600281	1.87
191.0096283	100.00
191.9514313	0.07
209.1107483	14.50
223.2576294	0.45
253.1636963	0.12
299.0225220	0.10
303.0700378	0.19
307.2805481	0.07
352.8474731	0.05
354.9480591	0.05
369.3655701	0.10
371.0012512	0.30
397.1073303	8.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.31
Annotation	Unknow
Peak:m/z	Relative Intensity
178.1186676	1.93
179.0772247	3.71
180.2023315	0.31
183.9962921	1.90
185.0012817	0.78
188.9199066	0.33
195.9587097	6.86
197.0711212	0.43
198.9189606	0.22
203.1530151	0.21
206.8829956	0.15
214.2393494	0.25
224.1237335	3.90
225.4855652	0.10
226.1075592	0.20
228.1758728	0.10
242.0731812	0.57
246.2546692	0.11
250.2137299	0.68
268.1524963	54.59
269.2249756	0.76
286.1808472	49.98
290.2691650	0.40
293.4584961	1.02
300.2536621	0.68
317.6605225	0.25
318.4469910	0.16
319.1197510	0.15
320.0616150	0.31
322.0352478	0.33
325.2261047	0.13
327.2188721	4.68
370.3724976	0.05
388.5028076	0.22
413.2958374	1.30
435.0489502	0.14
454.4606934	0.12
455.2609253	0.19
485.3073730	100.00
486.2773438	0.32
506.9733276	0.22
512.3507690	0.23
521.0385132	0.38
523.2592163	0.51
524.3936768	1.30
525.3048706	0.12
534.0606689	0.06
542.3460083	3.59
554.2496338	3.10
568.1567993	0.38
570.5305786	0.10
592.9187622	0.35
596.3159790	83.03
597.3402100	1.47
604.6349487	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.1527
Annotation	Tryptophyl-Glutamate
Peak:m/z	Relative Intensity
125.2273865	0.01
126.7232437	0.05
129.0596924	0.04
130.0218964	0.03
135.1097412	0.04
135.9890137	0.06
147.0857086	0.03
152.0430450	0.06
161.0414734	0.02
163.0350189	0.05
166.0636902	0.30
172.1820221	0.02
175.1943665	0.05
176.9430084	0.02
184.2791290	0.05
189.9875336	0.08
194.3099976	0.03
200.9487000	0.12
202.2663879	0.10
203.0710449	0.49
204.0917664	0.09
208.0136566	0.04
218.0122986	0.39
218.8695984	0.02
219.9654541	0.07
226.8038177	0.03
229.2202148	0.27
232.1337585	0.13
232.9932861	0.09
234.9333496	0.01
237.0599976	0.07
238.1245728	0.87
244.3969421	0.03
247.0496826	9.21
248.9183960	0.03
250.7291260	0.17
259.0600281	0.06
259.9862976	0.01
263.0099487	0.18
266.0278015	46.29
268.0212708	0.02
272.0983887	0.04
274.9979553	0.03
276.2100220	0.06
277.0790405	0.09
280.8356323	0.02
281.6256104	0.04
283.0469360	100.00
283.6882324	0.16
285.2133179	0.02
286.1909790	0.23
288.2147217	0.02
290.0474243	0.04
291.4740906	0.03
292.1793213	0.03
293.1527100	0.04
294.8184814	0.27
298.3109131	0.02
299.4150085	0.08
308.2283936	0.04
310.5928955	0.01
312.9756775	0.03
320.3265991	0.04
328.3059692	0.05
331.2899170	0.04
337.0826111	0.06
345.9824219	0.10
348.5677185	0.05
350.7723389	0.03
351.9913330	0.14
353.0893250	0.11
360.5596008	0.03
364.2704468	0.03
365.9079895	0.13
368.1358948	0.05
376.1315918	0.07
377.3498230	0.01
394.2118835	3.83
395.0164185	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2141
Annotation	Stachyose
Peak:m/z	Relative Intensity
179.0056763	0.25
221.0467834	7.31
223.1014099	0.19
232.7596741	0.22
249.4104614	0.15
250.8282013	0.19
266.1879883	0.18
268.0154114	0.54
268.901001	0.14
280.7338562	1.16
305.343811	0.58
310.9626465	0.51
314.3512573	0.21
323.085083	4.33
325.1964111	0.19
340.9929199	25.21
347.2322998	0.28
383.1098022	100.00
384.9682617	0.31
403.3237915	0.17
407.1963501	0.69
411.3217163	0.22
412.0944824	0.45
412.8764038	1.20
424.9817505	1.48
442.911377	16.28
467.1990967	0.47
472.9197998	0.55
485.1712036	24.81
503.0463257	2.54
511.1289062	0.12
514.409729	0.15
536.1466675	0.09
545.0234985	1.72
618.4786987	0.51
619.1784058	0.43
645.4179077	0.39
647.0167847	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.999
Annotation	Unknow
Peak:m/z	Relative Intensity
80.8264160	0.21
95.0698242	0.07
96.9482269	0.14
109.0686798	0.07
109.8063507	0.05
124.1311035	0.05
135.1080322	0.15
140.2327118	0.10
148.8949432	0.26
150.4497223	0.04
158.8159027	0.05
163.0153046	0.19
164.1776123	0.22
166.6443329	0.06
175.1427460	0.08
178.1239014	1.47
182.9569550	11.64
184.0679474	0.16
187.0853424	0.31
195.9593353	7.30
196.6009827	0.15
197.9131622	1.10
198.8642273	0.25
200.8710938	6.01
204.1024323	0.12
205.0912628	0.24
205.9791718	0.07
209.1098480	0.10
212.0589294	0.37
212.9785614	0.06
214.0546722	1.17
215.0659943	0.04
218.8812561	0.52
220.2285309	0.55
221.3426056	0.72
223.9288940	100.00
224.9179688	0.17
227.2636261	0.24
230.3728790	0.13
232.0983124	0.27
241.8255768	3.51
242.8619232	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	701.1907
Annotation	Unknow
Peak:m/z	Relative Intensity
195.9111328	0.09
219.1685791	0.02
221.0072632	0.03
279.2518311	0.02
280.9126587	0.01
305.2872925	0.03
311.2516479	0.03
322.9108276	0.11
341.0191040	1.94
383.2017212	2.36
412.8679810	0.84
424.9447632	0.04
442.4761353	0.46
443.0767212	2.94
455.0197754	0.02
467.0615234	0.07
472.6882935	0.05
473.3739014	0.05
485.2460938	1.28
502.9801636	2.80
504.1240845	0.03
539.2326050	3.92
540.5249634	0.05
545.3243408	0.07
605.1742554	0.09
646.1804810	0.06
647.3993530	0.04
665.2142944	100.00
665.8406372	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.11
Annotation	Apigenin 7-O-glucoside
Peak:m/z	Relative Intensity
127.0737	0.07
134.8956909	0.01
136.2271118	0.02
138.9680634	0.18
147.1063385	0.01
148.8800507	0.03
151.1048889	0.01
156.9945679	0.04
158.8674774	0.02
160.9033966	0.11
162.8911133	0.04
170.9937744	0.01
172.8042297	0.04
178.0274353	0.01
184.8063354	0.02
187.0429688	0.36
188.989624	0.02
197.2572632	0.03
199.2484741	0.02
200.9524231	0.01
203.2223969	0.05
207.1161804	0.02
210.8957825	0.02
213.0630951	0.03
215.1016235	0.02
218.961731	0.01
225.0669861	0.09
226.1278534	0.12
227.1183472	0.24
229.0614777	0.24
243.0209351	0.06
246.964386	0.04
250.8980103	0.01
253.0365601	0.21
255.1975403	0.52
261.3682861	0.01
262.9367676	0.03
265.1523438	0.05
269.0410156	0.16
271.0690308	100.00
272.1283569	0.09
273.2153015	0.13
280.2098999	0.02
283.0179443	0.05
284.9620972	0.02
287.4644165	0.01
289.0707092	1.08
291.145813	0.04
295.0783997	0.03
297.2860718	0.01
300.2599792	0.04
301.2672424	0.08
301.9416504	0.03
302.9902039	0.03
304.1253052	0.06
305.2065125	0.04
307.2567749	0.02
309.2002258	0.09
312.0088196	0.01
313.0093994	0.09
315.2927246	0.01
321.1625366	0.02
323.331543	0.03
325.7259521	0.06
326.352356	0.06
333.2119141	0.02
337.337677	0.03
347.3711243	0.03
348.7734375	0.01
349.4119873	0.02
351.1712036	0.04
354.9771118	0.04
360.9684143	0.02
367.0019531	0.16
371.3813171	0.03
386.9235535	0.04
388.214386	0.02
393.3283386	0.01
394.2537842	0.04
397.2416382	0.05
403.2298279	0.02
405.3242493	0.01
410.6547546	0.01
415.1761169	0.23
416.2937927	0.12
417.1492615	0.02
701.5108032	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3075
Annotation	Serinocyclin B
Peak:m/z	Relative Intensity
244.5019684	0.01
255.2178802	0.03
259.1015625	0.01
262.6289062	0.02
313.0372314	0.01
317.3355103	0.02
323.3955688	0.02
329.4352417	0.02
331.5408325	0.04
343.4205322	0.02
351.4508667	0.03
355.2135620	0.01
365.2819214	0.00
373.1782227	0.07
375.3602295	0.04
387.0577393	0.09
388.5369873	0.01
393.1174927	0.00
395.5924072	0.01
411.3705444	0.04
415.3007812	0.03
433.3071289	0.01
439.4381714	0.03
440.4329834	0.01
449.1455078	0.01
452.2539673	0.01
475.3557129	0.01
475.9797363	0.04
479.2824707	0.02
480.4525146	0.04
487.2202148	0.01
493.5382690	0.02
494.9862671	0.01
511.4085083	0.03
543.3986816	0.02
563.0000610	0.03
593.5975342	0.04
595.3491821	0.04
609.3557739	0.05
610.0908813	0.01
611.4473267	0.05
612.8001099	0.01
623.3085327	0.07
625.0256348	0.03
632.3551025	100.00
633.8890991	0.41
634.7910767	0.11
635.4327393	0.03
636.4843140	0.04
637.4104614	0.21
639.6480103	0.02
716.8174438	0.01
741.7900391	0.01
743.2316284	0.01
767.3363037	0.02
779.3818359	0.03
793.7329712	0.01
795.6065063	0.01
811.5761108	0.04
812.6785278	0.02
905.5115356	0.02
923.5785522	0.04
941.4800415	0.18
969.6650391	0.04
971.2722168	0.01
1023.3894040	0.01
1085.2961430	0.03
1087.5523680	0.02
1103.4980470	0.78
1106.4744870	0.09
1107.5351560	0.06
1135.4366460	0.01
1136.5429690	0.01
1148.3676760	0.01
1149.6311040	0.02
1265.2945560	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	959.5156
Annotation	Hoduloside I
Peak:m/z	Relative Intensity
268.8055420	0.18
272.2312317	0.57
281.2277527	0.82
283.2180176	0.19
284.6557007	0.95
288.6429138	0.67
293.1796875	0.54
296.2871704	0.33
297.5610962	0.10
301.2087402	0.41
302.4923706	0.20
303.2121887	0.39
305.4084473	0.47
309.2840881	1.17
311.0151672	0.08
312.0430908	0.27
313.0564575	0.21
315.3178711	1.32
320.7409973	1.55
321.7158203	0.38
323.1128540	0.49
324.9678955	0.89
326.3325195	0.49
327.3016663	0.77
329.3125000	0.64
335.1267090	0.13
338.9093018	2.92
339.9516296	0.70
343.1859131	0.11
345.2434387	0.17
348.3759155	0.56
349.1032715	0.91
351.0982971	3.03
353.0992737	0.44
360.5156860	0.34
363.4580994	0.39
365.2297363	3.67
366.1835938	0.89
367.1589355	0.54
368.5800781	0.09
369.2275391	0.21
376.8965454	0.27
379.1571045	1.30
379.7987061	0.47
381.7279053	0.40
383.3809204	0.59
384.2015991	0.15
393.3006287	0.82
394.4836426	0.46
395.5169678	1.14
403.3839111	1.38
405.3855591	6.14
406.4330444	3.08
407.5492554	1.29
411.4221802	0.28
412.3645020	1.01
413.4094849	0.14
419.3460083	0.52
421.4421997	0.95
423.2911987	39.44
424.3680420	12.64
424.9999390	0.32
433.4723511	0.23
434.7196045	0.12
441.2526855	58.06
442.2556763	19.42
447.0771484	0.10
451.4456787	1.29
458.0498047	0.82
458.9672241	2.13
479.1371460	0.44
482.6211548	2.27
484.1772461	0.26
487.6304932	0.12
488.2876587	0.12
500.8469238	5.49
502.2498779	1.48
521.5197754	0.18
546.5011597	0.86
553.5139160	0.43
563.4938965	0.34
566.6635132	0.14
568.9598389	0.16
571.4520264	0.34
581.3276367	25.54
582.4874878	7.45
597.6821899	0.23
598.5387573	2.96
599.2296753	100.00
600.3114014	39.54
603.7025146	0.42
604.5897217	0.45
616.9751587	52.36
617.9698486	12.36
618.6757812	0.13
620.8511963	3.43
621.6863403	0.84
622.3087769	1.10
634.3247070	3.67
635.0833130	11.66
636.1130981	2.09
686.4303589	0.32
727.5903931	0.26
764.9129028	0.55
768.2429199	0.48
778.6020508	1.25
779.8811646	1.10
783.1112671	2.98
784.2807007	0.38
797.1256714	35.78
798.1085815	13.08
812.4663086	0.37
941.1916504	0.22
942.3825684	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1386
Annotation	Limocitrin 7-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
159.1080627	0.04
160.9252777	0.07
165.0246124	0.03
171.0223541	0.08
177.0319214	1.26
178.9788818	3.22
184.0915527	0.13
189.0413513	0.18
191.1161194	0.08
193.1363831	0.04
195.0257874	4.63
203.1022034	0.25
207.6121826	0.08
217.1440430	0.22
219.1211548	0.04
221.0555420	0.04
223.1479187	0.02
229.2088928	0.06
231.1929626	0.13
234.8328552	0.08
236.0816040	0.12
242.2364807	0.11
245.1423645	0.13
245.9569855	0.05
253.6060028	0.02
261.1775818	0.44
265.0647583	0.06
279.1683960	0.15
285.2191162	0.64
287.0388794	0.04
296.1710815	0.10
301.0556641	0.02
303.0826721	100.00
313.6300659	0.07
321.3205566	0.06
323.1112671	0.10
325.0159302	0.04
327.1205444	6.98
339.1832886	0.13
342.9230347	0.12
345.1235962	17.85
347.0513916	0.24
357.3262329	0.08
361.3228149	0.13
364.4927368	0.05
365.1177979	1.39
369.1987305	6.45
372.8959351	0.05
377.2645264	0.15
381.1724854	0.13
383.1022949	6.23
384.8792114	0.08
387.2442627	0.32
391.2501831	0.04
393.0894165	1.18
399.0529175	0.20
399.8760376	0.33
401.0713501	3.24
404.3984375	0.03
406.7685547	0.13
409.1115723	0.23
411.1636353	8.51
417.0470581	0.03
418.0663452	0.03
425.1455078	0.13
426.9222412	0.22
429.2224121	1.18
436.4824829	0.21
444.9575195	0.03
446.9410400	0.12
449.0883789	0.10
453.0199585	0.44
461.5555420	0.02
464.9777222	0.31
469.4575195	0.67
471.0455933	1.94
473.3146973	0.17
478.9788208	0.40
487.2967529	0.03
489.2738647	0.04
496.9917603	1.57
501.0730591	0.19
502.1981812	0.02
505.3141479	0.14
510.6834106	0.03
515.0165405	19.09
515.7051392	0.06
523.3983154	0.02
525.5341187	0.13
526.2705078	0.10
530.9998779	0.05
533.0816040	43.45
541.5258179	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2499
Annotation	Parvifoliside
Peak:m/z	Relative Intensity
166.9358978	0.21
215.1034393	0.06
243.4961853	0.01
245.2071991	0.01
257.2276611	0.06
275.2601624	0.32
277.0137024	0.06
281.0215454	0.03
288.0802612	0.02
303.2489624	0.04
305.4383545	0.03
314.1779785	0.05
319.0409546	0.04
321.1963501	0.05
324.7374268	0.02
329.0474854	0.05
333.0701904	0.03
335.2285156	0.02
337.4054565	0.03
343.2731323	1.13
345.1947021	0.12
347.2761841	0.67
359.2160034	0.07
361.1591797	1.34
361.8395996	0.00
363.3562012	0.09
365.2286987	100.00
365.9230347	0.26
370.1325073	0.03
371.3790894	0.01
383.1574097	0.04
388.0553589	0.02
389.2904053	2.05
391.2985229	0.19
405.7407837	0.02
407.2276611	2.65
410.5513916	0.02
419.1974487	0.80
420.4608765	0.05
437.1864624	0.48
449.2546387	0.62
450.3379517	0.11
467.1054077	0.06
472.0597534	0.02
482.5268555	0.01
483.2363892	0.05
497.4723511	0.02
509.2402954	0.17
518.2581177	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	275.1595
Annotation	Unknow
Peak:m/z	Relative Intensity
83.0003815	0.02
83.9294434	0.08
84.8422012	0.11
93.1777191	0.03
100.0186386	30.85
103.2321777	0.04
106.7340927	0.10
120.8805008	0.04
124.9092331	0.02
129.4051819	0.07
130.0125885	0.77
136.9033051	0.06
138.9565430	0.22
146.0816345	100.00
147.9507446	0.71
149.0295715	0.19
151.0718384	0.07
163.0718536	0.08
165.9765778	0.02
180.9991302	0.13
187.0275879	0.03
188.1013641	0.09
196.0400391	0.01
204.7322083	0.02
211.1561890	0.09
212.0787354	4.33
213.9496155	0.04
215.2691040	0.08
218.2286377	0.02
221.3258057	0.10
227.1910706	0.06
229.0327148	0.36
230.7537842	0.12
233.0264587	0.21
233.7940369	0.09
235.1748047	0.05
238.7708740	0.27
239.3997803	0.23
244.0825195	0.16
248.1004028	0.05
257.0747070	4.90
258.1820679	23.91
285.4696350	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
105.0601044	0.41
142.6676483	0.07
145.7617798	0.11
148.9696198	0.18
151.8500519	0.08
157.1078949	0.24
165.1800995	0.19
169.1055298	0.17
173.9202728	0.17
175.1194916	0.09
179.1421356	0.09
181.3766632	0.12
194.0907593	0.07
196.2421417	0.13
202.8307037	0.27
206.2860565	0.08
207.0396881	2.99
208.122818	2.12
209.1896057	0.26
222.105835	1.19
223.1417236	2.96
224.2167664	0.08
233.3028564	0.24
236.0720978	0.11
249.2241058	0.05
251.0724945	100.00
252.1906586	17.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.1117
Annotation	Patuletin 3-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
185.1550903	0.01
204.2819672	0.02
215.2553558	0.03
237.2308197	0.02
243.2283020	0.02
247.0585785	0.02
253.3541412	0.02
254.0138550	0.05
271.0427856	100.00
272.1574707	0.22
288.9295654	0.03
296.6233521	0.02
309.2027588	0.02
343.5102539	0.05
357.0426025	0.04
393.3748169	0.05
425.5898438	0.03
433.1331177	2.51
434.2206421	0.04
475.1633911	2.85
501.2069702	0.74
502.9162598	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1111
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
138.9827881	0.04
163.1333313	0.04
271.0885620	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1614
Annotation	Galactotriose
Peak:m/z	Relative Intensity
142.9409485	4.72
148.5788574	0.36
159.1363983	0.49
160.9390717	15.35
166.8828430	0.41
176.9634705	1.85
179.0456238	88.21
184.7181396	0.57
221.1464539	100.00
232.8677521	0.93
245.1855621	1.45
249.2900848	2.67
250.5764771	1.40
263.2161560	1.10
268.6334839	0.47
278.7098389	0.57
280.6245422	6.99
281.2708130	7.70
293.2891235	1.53
305.2892151	2.23
310.9789429	2.55
323.2088928	28.49
340.9387817	29.42
445.5455933	1.26
485.2359924	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	783.2407
Annotation	Unknow
Peak:m/z	Relative Intensity
261.0036621	0.11
277.1412964	0.83
278.3734131	0.08
279.2553101	0.57
315.0737305	0.07
331.2259827	0.06
382.8313599	0.27
412.5454102	0.09
441.2219238	0.19
443.1469727	0.40
485.3697510	0.45
503.0200195	0.54
665.2129517	100.00
665.8964233	0.89
667.1386108	0.70
736.6561890	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1868
Annotation	Pinocembrin 7-O-neohesperidoside 3'''-O-acetate
Peak:m/z	Relative Intensity
170.9694977	0.10
178.9783478	0.17
197.0558014	0.45
215.1594849	0.66
218.9338379	0.03
227.1422882	0.92
245.0023804	3.99
263.0290833	100.00
264.8533936	0.06
277.1638184	0.05
285.8056030	0.04
302.6761475	0.10
322.6680908	0.10
324.4001160	0.11
325.2249756	0.13
341.2530518	0.96
393.9824219	0.08
457.9003296	0.05
470.2653809	0.18
476.3722534	0.04
508.1947021	0.04
513.2346802	0.04
521.0179443	0.03
551.2547607	0.03
559.2028198	0.02
568.8790894	0.20
587.0663452	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	525.1664
Annotation	Unknow
Peak:m/z	Relative Intensity
150.0582581	0.33
162.9854279	0.02
167.0571442	0.07
181.9214935	0.05
188.1879578	0.06
201.1690979	0.02
202.3870850	0.04
213.5789795	0.07
215.2231140	0.27
217.2496338	0.14
229.9979553	0.51
233.1348572	0.14
243.1284027	0.16
244.0717773	0.10
247.0661621	1.14
247.9771576	0.10
249.1854095	0.05
261.1757202	4.53
265.1925659	10.39
267.1957397	0.02
279.1559448	1.90
285.1380005	3.66
296.4223022	0.02
302.5508423	0.12
303.3418579	0.11
310.2791138	0.03
311.8029785	0.01
313.1427002	0.19
321.2042236	0.02
328.2475586	0.01
331.1229858	0.15
333.2227173	0.02
343.1347046	0.03
345.1650391	0.02
348.3478394	0.33
349.8785400	0.10
351.0103760	0.15
360.3856812	0.15
361.1415405	0.28
361.7709351	0.02
363.2505493	0.16
372.1295166	0.07
373.3393555	0.05
376.4027100	0.05
378.0671387	0.61
379.1767578	4.01
390.2070923	0.21
394.0910645	0.05
396.1477661	100.00
396.7732544	0.58
401.5382080	0.07
408.3692017	0.26
423.0954590	0.04
435.4725952	0.01
443.9576416	0.09
450.0918579	0.04
459.1312256	0.35
461.2965698	0.21
462.1333008	0.66
477.5204468	0.02
479.2835083	0.04
489.0830688	0.19
507.2088013	3.05
508.1810303	0.30
516.4301758	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1807
Annotation	Unknow
Peak:m/z	Relative Intensity
109.7056122	0.13
118.8929749	0.05
125.0359955	0.02
130.1037292	0.06
136.0021667	0.09
151.2644348	0.05
156.2216644	0.11
157.1600952	0.12
164.2239380	0.02
165.9806366	0.03
175.0102844	0.14
176.1232605	0.02
177.1436462	0.02
179.9956360	0.01
185.0663910	1.13
186.2333069	0.09
187.1094666	0.05
196.1093445	0.07
196.9748840	0.08
197.9961243	0.03
198.7563171	0.02
200.9360046	0.13
203.0889893	100.00
204.0542908	0.07
211.1618042	0.13
214.8917236	0.03
225.1876831	0.51
230.1078491	0.42
231.2939758	0.09
232.1401062	0.06
243.0541687	8.14
244.0998535	0.03
245.2107544	0.19
247.1847534	0.28
251.0551453	0.02
251.6847534	0.23
256.1009216	0.16
258.1835327	0.11
259.2558594	1.56
260.1428833	0.13
264.6559448	0.10
267.6904602	10.68
269.2492676	0.09
273.9772644	0.03
280.7696838	0.05
283.0541687	0.02
286.1942749	0.24
287.2041931	0.06
288.3445129	0.68
289.0865479	0.03
291.4733887	0.04
292.1925049	0.03
296.4905396	0.05
299.3059082	0.04
300.6806030	0.22
301.9712524	0.06
304.2258606	0.05
308.2817383	0.27
311.2493286	0.03
314.1433716	5.72
315.2637939	0.27
323.5896912	2.56
324.2801208	0.55
325.1156616	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1044.01
Annotation	Unknow
Peak:m/z	Relative Intensity
626.8740234	0.18
639.3832397	0.05
716.7832642	0.02
911.3787842	0.03
981.3944092	0.29
999.4765625	100.00
1000.5136720	4.29
1001.7125240	0.03
1021.2495120	0.48
1025.2930910	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2104
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
82.87476349	0.05
91.09044647	0.08
93.02114868	0.09
94.95516968	0.28
97.26525879	0.14
99.02183533	0.12
99.96002197	0.05
100.9094162	0.12
104.9644775	0.73
106.9352951	0.37
108.9718933	0.21
112.9271545	0.06
117.0739899	0.13
118.9718323	0.08
121.1522141	0.02
123.0642776	0.15
125.0862885	0.38
127.2503052	0.04
128.9475708	0.12
131.0873566	0.71
133.2637329	0.50
135.0529785	0.22
136.8982544	0.56
138.9617767	0.07
143.0690613	0.17
144.958252	0.51
146.9950562	0.59
148.9845276	0.39
151.1424561	0.05
152.9411621	0.26
155.0638123	0.37
157.1760864	0.29
159.1704102	0.56
160.9902344	0.43
163.0192108	0.95
165.0517883	0.67
166.5653839	0.16
167.1786957	0.13
169.1522675	0.13
171.2479858	1.08
173.0536652	0.43
174.1456146	0.11
175.2440796	0.22
177.0368652	0.31
179.1446533	0.49
181.1797333	0.48
182.9794312	0.56
184.8921509	0.08
187.2033691	0.65
189.1610718	0.43
191.1682892	0.38
192.5402527	0.24
193.1639099	0.40
195.2182922	0.12
197.1072998	0.24
199.0362244	0.32
201.1149902	0.30
202.9902954	0.59
205.0780334	1.42
207.121582	1.11
209.0075378	0.11
211.1426697	0.73
213.3235168	0.20
215.2460327	0.15
217.0651245	0.38
219.2900085	0.94
221.080719	0.19
222.9336243	0.14
229.3238525	0.16
231.1504211	0.37
233.1459045	0.23
235.1705322	1.40
237.0800171	1.33
239.1731873	2.24
245.1582642	0.18
247.2828674	0.86
249.1690369	0.18
250.3448486	0.02
251.1016541	0.16
252.0592346	0.12
257.1812439	4.36
264.7909546	0.62
265.4634094	0.16
270.6959839	0.04
271.7689819	0.07
275.1966553	100.00
276.010437	0.04
278.526123	0.08
284.243927	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.11
Annotation	Pelargonidin 3-O-glucoside
Peak:m/z	Relative Intensity
122.8532715	0.03
127.0075073	0.04
129.9842987	0.03
131.2463684	0.01
139.0075378	0.03
147.0056915	0.01
149.151413	0.01
153.2404022	0.01
157.1717834	0.02
165.1583862	0.01
181.01297	0.01
187.0308533	0.29
196.7839661	0.02
209.1529236	0.02
210.1647644	0.05
213.0359192	0.07
221.3476562	0.01
227.1181641	0.21
228.1359711	0.04
228.9361267	0.09
231.1291199	0.01
232.3961182	0.01
239.2825012	0.01
241.165802	0.05
246.7437134	0.01
253.0279236	0.11
255.1208496	0.28
258.9715576	0.01
268.9784241	0.05
271.0652466	100.00
272.0924072	0.15
272.9773865	0.02
279.2061768	0.04
280.8995056	0.04
286.2238159	0.01
288.9865112	0.72
289.6086731	0.04
295.2691956	0.05
299.3691101	0.03
301.0534058	0.03
302.9829102	0.03
304.0892639	0.03
307.1843567	0.03
313.273468	0.04
331.1377563	0.04
337.3558655	0.01
339.3584595	0.04
349.3370361	0.02
351.1278687	0.01
352.7733154	0.01
361.186676	0.01
367.1014099	0.05
369.2038879	0.01
371.1483765	0.21
373.0072937	0.05
377.4850159	0.01
385.0978699	0.33
387.098114	0.15
389.0995483	0.12
397.2043457	0.78
403.2279053	1.09
405.124115	0.04
410.2853394	0.00
415.0974426	1.62
416.0458374	0.06
424.8908386	0.03
END