#DEFINITION	Reference Metabolome for Musa acuminata
#IDENTTFIER	RefMeta-Musa acuminata.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Musa acuminata
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Musa acuminata was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.26
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9866943	2.27
177.0623322	4.51
184.0367126	0.17
202.1211853	0.58
220.1417084	4.49
229.9916840	1.15
252.0920563	0.07
267.3473816	0.47
310.1507568	0.31
328.2570190	9.13
346.1840820	4.65
364.1863403	45.02
378.4832153	0.65
382.1596680	100.00
383.0015259	0.13
497.7932129	0.19
508.5852051	0.36
513.8836060	0.08
521.9950562	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.2
Annotation	Unknow
Peak:m/z	Relative Intensity
143.1214600	0.05
149.2704620	0.06
178.9502411	0.72
181.0084991	0.05
271.1630249	0.13
287.2692566	0.07
303.2101746	0.05
341.1029663	100.00
342.1375732	1.38
343.3266602	0.12
387.9939270	2.42
407.7532654	0.08
425.4762268	1.40
426.1039734	6.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.124
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
85.0113220	2.29
86.9409027	0.69
88.8785171	3.12
94.9988251	0.08
96.9895096	0.14
100.9287872	4.60
106.9286957	0.11
111.1455841	0.19
112.9747925	6.63
115.0332794	0.98
118.9181747	3.96
125.0240173	0.51
127.9279327	56.57
131.0465088	100.00
138.9187927	0.18
142.9407806	1.45
145.0464325	0.75
147.1297455	0.12
149.1692200	0.29
150.8753357	0.26
152.9187622	0.13
155.2468414	0.08
160.8586731	0.77
162.9956207	0.06
163.9224548	2.56
173.0036774	6.98
178.7815247	0.96
185.0256042	0.29
203.0394897	0.71
206.9947815	0.10
215.2974854	0.22
224.1325684	0.07
226.9689636	0.14
230.8944092	0.35
233.2900391	0.13
239.0083008	0.15
241.4892578	0.17
246.9109497	0.08
248.9663391	0.90
257.1252441	4.03
258.0676880	0.44
263.1357727	0.08
267.6052246	0.45
273.0464172	0.25
275.1705933	50.55
277.8202515	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.2632
Annotation	linoleamide
Peak:m/z	Relative Intensity
80.94725037	0.35
91.15223694	0.06
95.10572052	0.54
96.98554993	0.27
109.0786133	0.47
111.1231232	0.15
114.0326843	0.26
121.1443787	0.83
122.9834824	0.70
125.0673218	0.12
126.1578064	0.30
127.9909439	0.73
132.9802856	1.23
135.0315857	2.03
137.1094208	0.82
139.0192261	0.41
140.133728	0.07
142.2149963	0.59
147.0501709	0.98
148.0004425	0.05
149.0960083	2.68
151.0472412	1.52
153.0988464	1.13
154.0674133	0.90
156.0847778	0.65
161.1096649	1.90
163.1526031	1.26
163.9550018	0.25
165.0739136	2.82
167.15448	0.47
168.0221863	1.12
169.9776459	2.13
172.3626709	0.40
173.0812378	0.29
175.1092377	2.20
177.0862122	0.58
179.0842896	3.17
180.9229889	0.71
182.2712708	0.96
184.039917	2.72
189.138031	1.37
191.186203	0.23
193.2675781	0.56
196.1399841	0.63
198.1788025	2.29
202.8721619	0.31
205.3479919	2.05
207.2423706	0.49
209.3746033	0.06
210.2433167	1.56
216.2429199	0.23
217.5428162	0.33
221.2487488	0.99
223.9742432	1.33
224.5863953	0.10
237.2378845	0.41
238.1542969	0.65
245.1650391	42.28
245.8470764	0.53
249.1209412	5.63
263.242981	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
84.81371307	0.37
95.04393768	0.49
97.10932159	0.13
99.03424835	0.34
105.0060425	0.08
107.1952057	0.09
112.9727325	0.14
115.0134964	0.18
118.9567337	0.08
120.9694519	0.43
122.8692627	1.13
125.1221848	0.93
127.4745636	0.49
128.6979675	0.29
133.0695953	0.36
134.8261108	0.16
136.0692902	0.20
136.8731079	0.44
138.9757385	2.98
140.8692322	0.34
143.2086792	0.28
145.2056885	0.56
153.0133362	2.16
154.7329102	1.22
156.8501587	0.79
162.9674377	0.62
169.1932068	0.55
171.0461273	0.20
175.0866852	0.19
178.5894165	0.12
179.2754822	0.11
181.2339478	1.11
183.2160034	0.66
185.2064819	0.43
195.0167084	0.86
197.016983	2.33
198.0775604	0.11
199.1730347	0.70
203.1826172	1.32
209.2141724	0.26
210.9452515	1.76
212.966217	0.49
215.271698	0.39
219.3158264	0.43
221.2195435	2.72
223.2992859	0.85
225.3131104	2.21
226.4404907	0.33
227.1152039	0.43
230.7954102	0.18
235.2016296	0.27
237.1817627	3.10
239.1159363	8.50
241.5452881	1.16
243.3324585	0.85
248.8363342	0.27
251.1184692	1.28
253.0441284	0.24
255.217926	3.49
256.0626831	0.22
256.9693298	0.80
261.202301	2.61
268.833313	0.23
279.2338867	100.00
280.4561462	0.13
281.1680298	0.37
297.0450439	0.11
299.2033691	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.87
Annotation	Unknow
Peak:m/z	Relative Intensity
231.8989563	3.73
232.5454102	0.07
251.0130005	0.12
253.0664673	0.41
284.8479919	0.21
290.9331665	0.15
304.1066895	0.14
315.8284607	32.63
316.5269775	0.19
337.1565857	0.12
353.9450378	2.25
399.7230225	100.00
400.4325256	0.23
423.8465576	0.12
426.7886047	0.08
437.7309265	58.59
438.3439941	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.08
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
219.1145325	0.05
221.3134766	0.05
224.9946899	0.05
229.4314270	0.06
231.0655518	0.33
249.1582336	0.14
254.9126282	0.05
259.0948181	0.07
262.7812500	0.33
264.1234436	0.05
267.0191040	0.05
291.1875000	0.05
305.1452637	1.72
307.0158081	0.96
308.4175415	0.07
315.1117249	100.00
323.0809631	0.18
328.8827209	0.24
332.1215820	0.08
333.1018372	0.25
334.0717468	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.1582
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9128418	0.04
185.2799072	0.08
191.0769653	0.11
194.6668549	0.05
204.1735840	0.04
217.1142883	0.20
219.2223816	0.19
223.8340454	0.08
237.3319092	0.11
240.0470581	0.16
250.0641785	0.21
251.1109314	0.04
270.0556335	0.12
272.1344604	0.06
278.9331055	0.05
290.0167542	0.12
303.9661865	0.17
306.4771118	0.07
308.2511292	0.07
311.0203857	0.10
314.0538025	0.17
321.1732483	0.04
323.8955688	0.22
326.1669312	100.00
327.2189331	0.61
340.0424500	0.46
342.0741272	0.10
350.0812683	0.62
352.2714539	0.19
356.2001648	0.27
358.2156372	0.17
367.1609802	0.20
368.0261841	0.13
368.8963318	0.06
371.2508240	0.07
387.0564575	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	267.01
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0027313	0.07
225.9154816	100.00
242.1400299	0.11
243.7713776	15.41
244.4276123	0.07
248.9335938	0.07
265.5666504	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	633.0224
Annotation	Unknow
Peak:m/z	Relative Intensity
416.3645020	0.02
418.3394775	0.13
442.8064575	0.08
458.9200439	0.15
471.3773193	0.02
477.1926270	0.02
478.3343506	0.10
481.7392578	0.06
486.0466309	0.34
487.0925293	0.22
500.8924561	0.10
520.9904175	0.12
535.3508911	0.16
541.1063232	0.14
543.9490967	0.11
555.0431519	0.07
560.1930542	0.18
566.9723511	0.91
569.3692627	0.02
587.0489502	100.00
587.7560425	0.64
589.1458130	0.08
603.3159790	0.13
610.6611328	0.09
615.3023682	0.21
615.9545288	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	232.1174
Annotation	Suberylglycine
Peak:m/z	Relative Intensity
87.9259186	1.77
98.9008331	0.04
102.0263672	0.10
115.9458618	2.65
133.9120636	100.00
148.0044708	9.88
162.1274261	0.11
173.7759705	0.12
186.0523376	0.41
200.0588837	3.74
209.2691345	0.10
214.0520477	44.14
217.2573242	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1134
Annotation	Spicatolide C
Peak:m/z	Relative Intensity
96.7183685	0.04
106.7847290	0.03
131.0426331	0.05
136.9400177	0.10
141.0301819	0.02
147.1526489	0.16
148.9841309	100.00
150.1075287	0.10
167.0340881	0.02
180.9058838	0.05
182.9222412	0.05
184.7202301	0.11
191.1517944	0.19
193.3284302	0.03
197.4382324	0.03
198.1137543	0.01
201.0841217	0.03
212.4551697	0.07
213.2122803	0.04
214.7164307	0.03
223.4621887	0.05
224.4302063	0.04
227.1699219	0.04
230.7728271	0.15
239.1601562	0.05
240.9253845	0.02
249.1455383	0.08
251.0432129	0.04
255.2721252	0.04
263.2681580	0.21
264.9554749	0.13
266.3188477	0.10
267.1841431	0.43
269.0956421	0.05
273.1654968	0.08
274.8786316	0.01
276.8508911	0.02
280.2904053	0.02
281.6907654	0.08
282.8653870	0.03
291.1221924	0.02
292.1571350	0.13
293.0375977	0.69
294.4597473	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2783
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
139.935257	0.05
196.0733032	1.99
214.1325684	1.00
221.5968933	0.07
236.2855377	0.06
239.1870117	0.25
240.2918396	0.12
242.4474487	0.05
250.9963074	0.03
261.4474182	0.24
271.1409302	0.04
277.3361206	0.02
279.234436	100.00
279.8564148	0.52
298.2069397	0.04
322.4671326	0.03
362.9276123	0.05
371.2687988	0.17
384.0926514	0.04
387.5040894	0.07
388.2189026	0.03
389.6298523	0.05
392.1591492	0.04
408.5310669	0.02
414.2374573	0.05
415.2093506	0.32
416.2030945	0.05
430.1053162	0.13
431.4831238	0.16
434.0403748	0.05
439.9999084	0.07
457.7173767	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	897.2659
Annotation	Unknow
Peak:m/z	Relative Intensity
263.3446655	0.19
302.4645996	0.08
323.4922485	0.27
337.0702515	0.83
338.3187256	0.43
341.3130493	0.11
382.8039551	0.24
395.0573730	0.23
395.8947754	0.21
468.3912964	0.28
485.2908325	0.20
503.0802612	0.16
523.4595947	0.21
527.3549194	3.95
528.3184814	2.21
531.8212280	0.04
541.2285767	0.40
542.2609863	0.08
545.2815552	3.79
546.2879639	2.92
560.4828491	0.67
570.0471191	0.19
576.3975220	0.13
601.4772339	0.13
643.4545288	0.27
655.2079468	0.23
656.4553833	0.10
661.3712769	1.50
662.4860840	0.85
679.2966919	2.14
680.3309326	1.25
689.5863647	0.36
694.3699951	0.19
698.0869141	0.06
703.3347778	15.41
704.3753052	10.22
707.0586548	0.24
708.2722778	0.06
721.2727051	100.00
722.3778076	74.54
735.0654907	1.10
736.2723389	1.94
745.6972046	0.07
833.2300415	0.06
838.3989868	0.50
840.5106812	0.25
855.2380371	3.41
856.4396362	2.39
876.4014282	0.18
880.9797974	0.22
883.4519653	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1035
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
131.9690399	0.03
143.0120392	0.06
145.9736176	0.02
176.9953613	1.91
177.6031494	0.07
179.1336060	0.11
193.8995972	0.04
217.1391754	0.03
227.1008911	0.02
240.2410736	0.02
246.9336243	0.03
256.8287659	0.04
257.4484558	0.02
259.4073792	0.08
267.3085327	0.04
274.8954773	0.04
285.0358887	23.76
285.8646240	0.04
301.3424683	0.03
303.1675720	100.00
306.4566650	0.01
311.0526428	0.13
323.3579407	0.08
327.0805054	0.06
334.2112732	0.46
337.0444946	0.07
339.2062988	0.17
341.1360168	0.55
343.3285828	0.03
345.2563477	0.09
347.0548706	0.13
347.8835449	0.05
349.0026855	0.06
350.4060059	0.06
351.2945557	0.07
357.1268921	0.03
358.1464233	0.03
360.1374512	0.14
361.1169128	0.10
363.9735107	0.14
368.4855957	0.16
369.4797058	0.05
371.0660706	0.13
375.1436768	0.13
377.1405945	0.10
378.2636719	0.57
379.2247009	0.13
380.1516418	0.05
393.9023743	0.06
403.1689148	0.03
406.2509766	0.05
417.9993591	0.04
419.2658997	0.10
420.3213196	0.03
421.1629333	0.15
426.2433472	0.02
429.2463074	0.05
430.1855164	0.21
435.9326477	0.10
437.2301331	0.38
447.1349182	2.49
469.1515503	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1035.6372
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
288.1134338	0.17
308.0044861	0.42
333.0083008	0.15
335.0574341	0.13
441.2210083	0.47
500.3766479	31.18
501.4838867	7.70
518.3015137	100.00
519.3948975	23.02
532.3159790	5.66
533.3987427	2.43
604.3249512	0.09
621.2111816	0.42
624.4064941	0.14
642.3720703	1.25
643.4750366	0.10
683.5531006	0.36
684.5034180	0.43
701.2612305	15.85
702.2252197	3.88
767.2691040	0.11
958.0993652	0.17
976.4555664	2.46
977.3358154	0.70
977.9428711	0.10
1017.7650150	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
93.0131073	1.37
98.70245361	1.23
107.110054	1.08
119.1260147	1.83
123.0824585	1.54
125.1306458	1.34
135.0105286	1.20
139.0002441	15.27
142.8345642	0.77
153.2753296	0.97
162.8327637	1.87
167.1743622	1.21
179.0710297	0.47
181.0941772	1.21
183.1923218	1.58
195.3366089	0.33
197.0447083	13.93
199.0486145	0.86
209.2891235	1.40
211.2134399	2.06
217.1635132	0.80
221.1175842	1.04
225.4059448	3.76
231.3381348	3.46
237.0510559	1.94
237.7652588	0.66
238.4204712	1.93
239.0748901	13.89
239.6781921	0.41
250.8023987	2.02
251.4536743	0.65
255.0223389	2.43
256.1239624	1.05
257.2905579	2.60
261.3718567	1.37
279.2313843	100.00
280.8082886	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
109.0466461	0.24
112.9680405	0.18
123.0783997	0.63
125.1422119	0.40
128.9325409	0.16
134.9756775	1.81
142.9154358	1.44
147.0807495	0.51
149.2377472	1.50
151.1070557	0.90
157.0310974	1.60
159.0397034	3.19
163.1691895	0.18
165.1665039	1.25
169.2434692	0.53
173.0730743	3.33
177.0246124	1.31
179.0574646	1.69
182.8265228	1.25
186.9432678	3.28
188.9365387	0.72
195.3972931	1.01
203.2086487	0.49
207.1439819	0.63
211.2828369	1.86
217.0491028	0.32
219.3673096	0.48
221.2958984	1.34
223.1442566	1.70
235.1941223	0.21
235.9409485	0.51
241.2294922	0.35
245.3674011	1.88
247.2501831	2.32
256.2511597	0.87
257.2466125	0.65
269.4697876	0.32
273.2578125	0.25
281.1177063	0.67
295.3130493	3.35
297.1785583	0.36
299.4690552	2.02
300.7073975	0.46
305.2458496	5.27
308.4585571	0.65
311.1907959	0.20
313.3287354	3.71
323.2424622	100.00
324.4923096	0.99
325.1351013	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
108.9361725	3.56
121.0432205	2.34
126.4017944	1.12
133.0061646	0.65
135.3253021	1.41
147.0997314	1.07
149.0358734	1.35
163.0325012	0.68
173.2283783	3.09
183.1019897	2.52
187.3699799	1.55
193.451004	1.67
203.2132263	1.08
210.6334534	1.70
211.2782593	2.14
213.2404175	0.32
215.3240967	2.51
217.0022583	2.52
223.4664307	0.71
231.1264038	4.32
244.3045349	0.60
247.2511292	2.43
248.4083252	2.39
249.3530579	0.36
253.3996582	3.20
256.6798096	1.36
259.1936646	0.91
273.1726074	0.40
277.0222473	1.11
279.1634521	0.68
283.3436279	0.49
285.2837219	1.03
287.150177	1.65
294.8499451	0.80
295.7982788	0.32
299.3043213	0.57
305.3759155	11.38
313.359436	1.86
323.2347717	100.00
323.8668823	0.48
341.0782776	3.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3083
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
197.8849182	0.12
215.924469	0.20
308.5732117	0.49
315.3728027	0.16
339.2908936	100.00
339.9289246	0.37
419.3695374	0.27
427.1942749	0.07
462.2605896	4.93
463.4989319	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1429
Annotation	(+)-Abscisic Acid
Peak:m/z	Relative Intensity
109.0701752	1.30
130.1057434	1.18
161.1925201	1.60
173.0579529	0.79
173.7145233	0.96
178.0614166	3.67
187.3646088	2.33
191.1654968	0.60
194.8229828	0.59
197.1977692	0.45
199.1127472	2.30
205.0554047	5.39
206.2568512	2.68
206.9148712	1.72
209.2565613	0.72
219.0733185	4.08
220.8143768	1.02
223.1534271	1.70
228.836441	3.12
234.8322906	1.23
235.8090057	1.12
237.1378021	0.45
247.1271973	100.00
248.2221069	2.29
256.1177979	1.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1918
Annotation	Atticin
Peak:m/z	Relative Intensity
133.8222351	0.03
134.5382690	0.03
153.0382233	0.16
155.2095642	0.05
159.8843994	0.18
160.9794006	0.26
165.3749695	0.05
172.8905029	0.10
174.8872223	0.74
175.9095154	0.16
183.0940857	0.21
184.8437195	0.07
193.2115784	0.55
194.1252136	0.17
195.2271729	0.16
198.8874817	0.07
202.4333801	0.07
204.7808838	0.11
216.9441528	0.35
218.1721191	0.60
221.8276978	0.12
230.4963989	0.06
235.1490784	0.15
236.8378754	0.09
248.9559326	0.47
250.1768188	0.13
253.3792114	0.38
258.9417114	0.15
267.0646057	0.39
301.1349487	0.07
307.4254150	0.03
317.5882568	0.16
318.2077637	0.09
319.1886597	0.23
333.2267151	1.08
339.3238831	0.23
349.3095398	0.20
351.2540894	100.00
355.2768555	0.09
355.9887390	0.07
357.3032227	0.08
367.8424072	0.30
368.9957886	0.10
373.2138977	0.62
379.3581543	0.07
385.2000427	0.56
398.4062805	0.13
400.5236206	0.15
406.9090881	0.19
408.3876038	0.44
411.4208069	0.24
422.2149353	0.06
423.2862854	0.99
425.3570251	0.18
426.1538086	0.33
431.2259827	0.33
432.8517456	1.78
434.1638489	0.25
441.2973022	0.12
451.0410156	0.45
452.1611938	0.11
469.5721741	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0023
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9247894	0.07
130.7179871	0.12
154.8756104	0.06
173.0100098	1.92
190.9445038	100.00
212.9795074	0.15
230.8172302	0.08
240.0067749	0.09
241.0730286	0.22
255.0377197	0.18
256.9995117	0.04
260.8338928	0.04
273.1311340	0.53
298.9856567	0.40
317.0769348	1.54
333.3645325	0.04
359.0205078	0.02
384.6875610	0.08
385.3258972	0.06
388.2613831	0.03
403.0637512	2.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.36
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1225586	0.14
203.0621643	0.17
219.0128174	0.42
221.1198883	0.14
232.4195862	0.06
235.1295166	7.42
239.1493988	0.23
240.8584137	0.21
245.1262512	0.07
251.3759918	0.04
253.2563477	3.33
259.3016357	0.07
263.1090698	0.26
267.5558777	0.14
269.0701294	0.09
277.2118530	0.33
287.0872803	3.91
302.8598022	0.05
305.1062012	7.49
309.1918945	0.20
323.2046509	0.98
337.1769409	0.05
338.3117676	0.05
361.2067261	0.11
379.3018799	0.51
397.2597046	100.00
415.1801758	35.66
437.4916992	0.14
477.5257568	0.10
527.2847290	0.05
590.3225098	0.14
613.0394897	0.06
617.7892456	0.20
619.6265869	0.25
633.2847900	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.1757
Annotation	Neocalyxin A
Peak:m/z	Relative Intensity
133.4172363	3.91
134.0481567	15.45
144.7440186	4.99
161.9048157	0.94
162.9544678	5.20
241.2220764	0.92
258.7623596	2.43
288.8942566	5.26
293.7196655	0.35
294.9822083	13.86
295.9388123	67.14
305.8775024	1.06
307.0642700	3.57
313.0212708	12.95
313.9193115	100.00
324.8244629	35.73
325.5113525	0.39
341.8616943	2.70
342.7592773	3.82
343.4854126	1.34
414.1803894	0.99
439.5472717	0.70
456.4519043	1.71
458.0800781	43.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.23
Annotation	Rhodioloside B
Peak:m/z	Relative Intensity
145.0771332	0.13
148.8056793	0.07
171.2229462	0.35
187.0892639	0.26
205.0366821	0.20
215.3866577	0.19
217.2657471	0.09
223.1475525	0.29
228.2974548	0.07
230.1924744	0.07
241.4017944	0.07
246.8509827	0.10
249.0951996	0.22
255.8540344	0.08
274.9352417	0.14
277.2840576	0.54
286.3123474	0.24
295.2530518	1.78
295.8737793	0.11
301.8919067	0.28
311.3958740	0.73
313.3202209	41.51
314.4595947	0.70
315.1842651	0.84
327.2402649	0.14
329.3659973	2.44
331.3031616	100.00
332.3679199	0.47
333.2883606	0.10
339.3610840	0.22
340.8999634	0.21
343.1984253	0.32
345.4066467	1.40
348.3359375	0.17
351.2690735	3.83
352.1614380	0.10
355.3018188	2.64
356.4606323	0.14
359.5569458	0.06
363.2850952	0.15
365.2890015	0.17
371.3259888	0.16
373.6123047	0.45
379.0740662	0.07
384.1055298	0.14
385.4654846	0.22
389.1745911	0.10
393.3687744	0.10
396.1051941	0.15
399.2276917	0.31
403.1132507	0.08
405.2861023	0.09
406.3254395	0.20
408.6746521	0.48
409.2922974	0.07
412.9400024	0.15
415.4907227	0.27
421.1737671	0.08
425.2264709	1.08
427.2088318	0.10
428.6410522	0.07
430.6216125	0.07
432.7743835	0.08
433.5466614	0.93
434.9654541	0.36
447.2757568	7.70
449.0111389	0.50
451.3238831	11.88
452.0594177	0.11
455.1362610	0.52
456.0290833	0.26
457.0147095	2.35
458.0587463	0.64
470.7804565	0.22
474.5705261	1.55
475.3445435	16.00
476.0030212	0.87
478.8492126	0.32
484.5438538	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3124
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
161.1642761	0.04
177.8249817	0.03
187.0983734	0.07
235.1944427	1.27
236.1676025	0.05
242.9465027	0.05
253.1282501	8.70
254.1822052	0.51
263.3412781	0.01
271.3784790	0.14
277.2869873	60.35
278.2436523	6.40
278.8510742	0.09
297.2737427	0.02
317.9838257	0.04
351.3546753	0.20
379.0847778	0.09
413.4829712	0.03
428.3230591	0.05
445.9547119	0.07
456.7495728	0.10
479.3706055	0.05
481.3967896	0.06
487.3739624	0.02
496.2146606	0.06
498.5117798	0.08
501.2335205	0.02
505.4805298	0.23
513.1138916	100.00
514.0895996	10.84
514.9188843	0.01
517.1455688	0.04
521.2769165	0.04
524.2207642	0.12
541.1807251	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	516.16
Annotation	Neoacrimarine G
Peak:m/z	Relative Intensity
162.0607147	3.03
177.1387634	3.59
179.0261993	5.18
186.9187317	0.30
208.0618744	1.94
209.0211487	12.90
233.1749268	0.97
269.5185547	0.22
283.9205627	1.81
284.8577881	0.68
291.0398560	1.06
305.9835205	1.74
308.1745605	100.00
323.9974365	4.47
350.4796753	0.48
365.2520752	0.58
368.9514160	1.63
383.6652222	1.32
387.1472168	1.45
407.9793091	1.03
428.1998291	1.46
433.2954102	0.64
441.1731567	0.82
457.1309204	0.86
479.4437866	0.64
480.4955444	0.92
484.1549683	2.44
497.4817505	0.43
499.2959595	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.2692
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1575623	0.14
201.1561584	0.07
203.6437073	0.11
211.0670776	0.60
219.8735199	0.17
228.9850159	0.07
249.1912842	0.17
276.0376587	0.12
323.7114868	0.26
328.1384277	4.16
346.1145630	100.00
371.4153442	0.16
453.4592285	0.21
461.4419556	0.26
462.0536499	0.17
477.5967407	0.09
494.0039673	0.29
509.0686646	0.08
526.6067505	0.09
538.3687134	0.05
544.8723755	0.46
545.6144409	0.16
559.2774658	0.35
560.3479614	0.26
561.5432739	0.25
562.1593018	0.33
567.0404663	0.15
568.2528076	0.06
570.1726074	0.14
587.1203003	0.76
588.5556641	0.11
596.6293945	0.07
605.4312744	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1294
Annotation	Phloridzin
Peak:m/z	Relative Intensity
149.1085815	0.07
152.9307556	0.06
154.8779755	0.03
161.1748505	0.04
167.1561127	0.74
177.8550415	0.07
178.9406891	0.24
189.1307983	0.07
191.2734985	0.08
209.0699768	0.25
229.3063202	0.03
242.9336243	0.04
249.0987854	0.05
250.1159973	0.09
251.2217102	0.04
258.970459	0.10
269.1500854	0.20
271.1839294	0.30
273.0675964	100.00
273.673584	0.14
284.1957397	0.09
286.8284607	0.04
289.2029419	0.07
297.2686768	0.23
304.3717041	0.06
315.1688538	0.28
333.0055542	0.10
337.1063232	0.05
339.177002	0.47
340.3311462	0.05
351.0257874	0.45
352.1244507	0.19
353.2193298	0.06
355.4038086	0.22
362.4457703	0.03
373.2790833	0.09
373.9384766	0.10
375.3627319	0.06
376.4572754	0.19
387.0296326	0.03
389.1238098	1.06
390.6359863	0.16
391.2741089	0.02
392.2833557	0.23
395.4158325	0.08
398.4456787	0.07
399.4658813	0.34
405.5553894	0.08
407.6134644	0.09
416.0629883	0.25
417.1239929	0.53
420.4367371	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
94.70938873	0.09
98.9017334	0.16
100.951355	0.43
108.0086517	0.62
112.8990631	2.97
122.9979095	3.82
135.8955078	0.31
144.5056458	0.26
152.0386658	3.03
162.0970459	0.25
167.0332642	100.00
173.162262	0.29
181.1065063	9.82
182.9555969	0.24
185.7264709	0.27
194.0229492	1.09
209.0362244	98.85
209.7748718	0.26
217.0931396	0.39
217.921814	0.52
221.1488342	1.09
232.8798523	0.39
234.9837646	0.32
239.0579834	14.78
242.9197693	0.11
247.211792	0.40
248.005188	0.15
249.0731201	0.22
251.1550293	0.12
253.3900757	0.22
254.8998718	0.08
263.0686035	0.25
269.1249084	38.34
270.2699585	0.28
271.1307983	0.09
281.0532837	0.33
282.1333618	0.81
283.0787354	2.06
284.2333984	0.16
285.2039795	0.70
293.2778625	0.11
309.5630188	0.17
311.0612183	3.32
314.1565552	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0960999	0.08
210.7628479	0.90
212.8299255	100.00
248.6732178	0.03
251.0552063	12.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	697.365
Annotation	Cuscutic acid A2
Peak:m/z	Relative Intensity
287.0500488	0.07
305.2736206	0.18
359.1909790	0.08
397.2521973	6.73
412.9988403	0.06
415.1864014	1.58
474.3184814	0.07
510.6544800	0.03
624.8142700	0.12
643.4688110	0.29
644.9503784	0.25
651.2481079	100.00
651.9208374	0.19
653.4607544	0.15
660.4774780	0.08
681.7994995	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2996
Annotation	4-Hydroxysphinganine
Peak:m/z	Relative Intensity
95.06232452	0.08
96.81950378	0.19
109.0407104	0.11
123.1098022	0.21
135.2330322	0.09
136.9535522	0.36
163.3096771	0.04
164.9200439	0.21
187.1737671	0.07
205.1060486	0.31
211.1234741	0.34
219.2421875	0.05
221.1218262	0.23
223.6807861	0.06
225.0682678	0.07
226.3563538	0.05
228.9776611	0.14
236.6832275	0.09
237.9469299	0.10
239.1326294	0.08
241.1231079	0.09
247.1573486	0.14
251.2278748	0.10
252.6070251	0.90
253.3172913	0.37
256.2807617	0.17
264.2484436	0.86
265.3331299	1.97
265.9910583	0.08
270.2990723	0.92
271.2524414	0.05
282.3215332	35.46
283.0491638	0.93
286.0939331	0.08
286.9880371	0.07
296.9470825	0.40
300.2817993	100.00
301.2806702	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1611
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
130.9632721	0.04
166.8334961	0.03
179.0871887	1.12
181.0269165	0.49
183.9548035	0.19
185.0535431	0.06
197.0773773	13.83
223.1591187	0.52
225.1746826	0.06
228.1919861	0.06
238.5617676	0.14
241.0791931	100.00
241.6904602	0.32
257.3542175	0.09
264.1615601	0.16
265.0943604	0.18
283.1484375	0.99
287.1757812	0.11
295.5207214	0.05
305.3569946	0.08
312.8251648	0.20
326.9020996	0.07
329.7603760	0.05
340.9050903	0.39
343.1836548	1.79
357.0512390	0.49
359.2013855	0.10
373.2890625	0.11
384.9976501	0.34
386.0263062	0.23
388.2819519	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	518.25
Annotation	PS(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.1285095	0.10
152.9546814	6.88
170.9726715	0.94
187.0935059	0.06
213.0655365	0.05
229.0686035	0.18
237.0331116	0.04
239.9450073	0.19
242.0896759	0.02
257.9396667	0.08
277.1857910	0.05
401.6123657	0.04
413.1539917	0.07
416.0027466	0.05
431.2625732	100.00
432.3209229	0.03
446.1952515	0.20
450.4482422	0.12
474.4092407	0.04
480.1604004	0.07
482.1282349	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.31
Annotation	Buprenorphine
Peak:m/z	Relative Intensity
162.7965393	0.57
189.0684204	1.04
237.2973633	0.63
249.2082214	1.31
252.8606567	2.04
274.6847534	0.73
277.4405823	1.17
327.3473511	44.85
334.1790161	2.01
343.8529968	2.14
353.7570801	0.57
363.3981934	1.10
369.3451233	0.78
381.8607788	1.77
398.8018188	1.58
401.3543091	2.20
404.3468323	2.13
414.714325	2.07
415.3227844	1.91
421.3073425	1.44
422.2758789	9.47
450.3096924	100.00
451.54422	3.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1138
Annotation	Robustaside B
Peak:m/z	Relative Intensity
181.1140137	1.57
193.3206177	0.40
258.8756104	0.29
271.0839233	100.00
296.0925293	0.52
313.6844482	0.63
345.0827026	0.63
357.4556274	0.60
369.3179321	1.51
387.0276184	2.14
388.3547363	0.45
389.1987610	1.80
390.2002869	1.18
397.4660339	1.63
415.1631165	2.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0604
Annotation	Unknow
Peak:m/z	Relative Intensity
173.2137756	0.26
183.0402527	0.12
199.0495758	0.17
216.9153748	0.17
223.0704651	0.05
228.7921906	0.07
235.1669922	0.31
244.9730682	0.06
246.8736725	0.12
253.1266022	0.24
254.8142090	0.13
265.0394287	0.45
267.0747681	0.26
269.0063782	0.35
270.9044800	0.48
274.8921509	0.37
277.0174866	9.13
289.0805664	0.78
295.0116272	1.12
301.0109863	0.18
302.9050293	0.12
305.3161621	0.92
306.9756470	19.06
309.8497009	0.14
319.0103760	3.74
321.1748657	0.08
322.9508667	0.19
324.7525635	0.06
328.9930420	0.42
330.8887939	0.12
336.3725586	2.03
336.9933472	6.75
342.9945068	0.51
346.8909912	0.74
349.1810913	0.90
355.0315552	0.53
361.1502075	0.46
363.0167847	0.09
365.0985107	1.60
367.0083008	21.23
373.0463257	2.39
378.8673096	0.81
382.0948486	2.18
383.0171509	1.51
389.7897339	0.39
391.0834351	10.11
392.2335815	0.16
395.1232910	0.51
396.3385010	1.07
396.9966431	22.79
398.0032349	0.23
408.1734619	3.61
409.1019287	50.48
425.3420410	1.65
426.0753784	7.48
427.1058960	100.00
436.2650757	0.10
469.1884766	0.47
498.9989624	2.45
544.0799561	13.24
545.0462036	11.36
552.6411133	0.88
562.8630981	0.09
570.1272583	0.72
571.0964966	5.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.128
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
129.3540802	0.36
130.2036743	0.63
134.9252167	0.32
139.5693512	0.05
142.0452576	0.52
150.9210358	0.13
151.8585205	0.19
159.2201996	1.12
167.0121613	4.59
172.8343201	0.10
176.2948914	0.12
182.9742126	0.32
193.0487518	0.60
194.1000977	0.96
195.0922852	0.51
201.9246521	0.34
203.0180664	33.39
203.9756470	0.12
207.0272064	0.06
209.0456238	0.21
211.2164917	0.06
212.8693542	0.23
219.3114624	0.05
221.9610596	0.14
236.3361206	0.05
241.0063477	100.00
242.8602295	0.19
246.1281128	0.26
246.7632446	0.10
251.2688904	0.20
262.1912537	0.08
262.9229736	0.09
265.1105347	0.34
265.9803467	0.20
266.9390869	0.51
268.1615295	0.90
277.4241943	0.06
282.1837463	0.71
282.8427124	0.27
283.4764099	0.08
287.2853088	0.13
295.0639648	0.13
311.2021790	0.23
312.1667480	0.05
313.3330078	0.20
314.3017883	2.61
315.1079712	0.94
316.2155151	0.35
321.2790222	0.07
329.1592407	21.59
330.0885010	0.33
341.4193115	0.25
357.3167114	0.15
364.9063416	0.19
367.3279114	0.30
369.0375061	0.10
381.9519653	0.37
383.2196655	0.63
384.2405396	0.24
392.2681274	0.14
393.3444519	0.47
396.2122803	0.23
398.1254578	0.09
399.1180115	0.14
400.2074890	0.98
401.1519775	0.55
402.5368042	0.20
409.2926636	0.26
414.5067749	0.14
416.2855225	0.33
426.4960022	1.22
427.2710876	2.16
428.1182251	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9935913	3.17
159.9272766	1.64
160.9492950	1.77
173.2268372	0.04
198.8921967	0.34
200.0881348	0.35
201.4198761	0.79
202.0949860	0.04
219.1244659	0.23
229.0465240	0.33
230.1795044	0.65
231.1216278	0.86
232.4401855	0.18
233.2092896	0.08
272.9919128	21.57
274.0302429	26.74
275.0078430	58.56
275.9841003	17.93
277.0182495	9.70
346.0283203	0.06
363.2029724	0.04
386.9697571	2.93
387.9781799	35.82
388.9924011	100.00
389.9400024	89.48
390.9875488	60.66
430.1197815	0.18
431.1247864	0.16
457.8964539	0.49
458.9197998	4.14
459.9908142	0.65
476.7490845	0.11
485.5724182	0.05
487.0513611	1.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.93
Annotation	Unknow
Peak:m/z	Relative Intensity
198.5710144	0.25
203.7137451	0.64
260.7987976	0.28
312.7171631	0.35
425.0742188	2.09
426.9606323	100.00
428.0063477	2.89
443.2315674	1.37
444.0949097	5.13
445.7132568	0.32
468.5630493	0.73
492.8944092	0.38
493.9079590	2.82
494.9887695	44.23
496.0009155	0.39
497.2361450	0.30
499.7457886	0.47
512.0519409	3.77
512.9099121	10.31
513.9738159	1.37
516.8622437	0.15
519.3875732	0.56
520.0463257	0.56
526.1901245	0.54
527.4570312	0.62
529.2992554	1.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2271
Annotation	Unknow
Peak:m/z	Relative Intensity
147.1187744	0.15
158.9832153	28.62
159.5917664	0.06
169.2410583	0.11
177.1592102	0.59
187.4776001	0.20
193.5944519	0.11
230.1123962	0.14
243.2192078	30.35
258.4898376	0.52
260.2608948	19.64
260.9955139	100.00
267.4097595	0.30
275.3898621	0.33
283.3490906	0.08
309.2760010	0.31
317.3851929	0.83
329.3857422	0.09
335.2332764	20.27
341.7965698	0.11
366.9035645	0.10
380.2279968	0.08
387.0306091	0.38
401.3347473	0.19
408.1158447	0.14
409.2812195	0.18
417.4851990	0.07
418.4676208	0.12
419.1443176	3.96
435.3716736	2.47
436.1815796	9.57
436.8405151	16.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.27
Annotation	SQMG(0:0/16:1(13Z))
Peak:m/z	Relative Intensity
164.9569855	5.97
166.9084778	0.29
176.8673553	0.64
179.2194519	0.16
183.0142059	3.61
188.9609375	1.36
203.8139496	0.89
204.7884827	0.88
206.9835815	11.69
208.3266449	0.43
208.9773254	0.52
219.8627777	0.43
221.8429565	3.46
225.1151428	100.00
226.1631165	0.58
243.0920410	8.65
253.2049561	24.02
254.2320404	1.82
286.7943115	0.42
299.0557861	47.39
300.1495972	2.26
317.1159668	5.50
318.0372314	0.24
333.2495728	0.41
365.0996094	0.21
381.1362915	0.65
454.6163940	0.74
456.2211914	0.92
457.0239258	1.40
461.4299316	0.54
465.7734985	0.15
492.4722290	2.59
508.3162231	0.19
515.6113281	0.65
517.2461548	1.82
522.5449829	0.68
535.3357544	1.91
536.5194092	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1478
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
165.2048645	0.49
169.1126251	0.10
173.1720886	0.12
188.9992676	0.13
197.0590210	0.09
200.9655151	0.49
203.1544189	0.10
207.3215790	0.17
228.9340210	0.42
230.9266052	0.13
233.1837158	0.36
238.1191711	0.17
243.2303772	0.12
245.1439514	0.04
247.0803680	12.79
248.8006287	0.14
250.8124390	0.25
253.2932739	0.25
254.0252075	0.21
255.0951843	0.10
259.2608032	1.78
261.0542603	0.32
271.0640564	3.59
273.0592041	0.44
274.0905762	0.76
275.0264282	6.81
283.0769043	1.94
285.2232666	0.16
287.0117798	1.47
289.1681519	9.84
291.0681152	36.03
291.6685181	0.09
301.1524963	12.41
303.1108704	4.85
305.2162781	0.26
313.2132568	0.74
315.2427979	0.13
317.4454346	0.35
329.3040771	0.05
333.0667725	1.33
339.4676514	0.10
347.2585449	0.04
362.4377441	0.16
369.4028931	0.20
376.1457520	0.11
383.3860474	0.19
391.3357544	0.25
397.1480103	0.12
399.1279907	0.19
409.2281494	38.95
411.1452637	12.68
416.3675537	0.21
417.0034180	0.08
421.1126099	2.37
423.2485962	0.09
424.8064575	0.16
427.0348511	100.00
427.6873779	0.76
433.2495117	0.20
434.3051147	0.28
435.2440796	3.92
439.0968018	5.74
451.3375244	0.21
453.0202026	6.20
481.3581543	0.30
490.9999390	0.14
498.8999634	0.15
502.2520142	0.40
528.3682251	1.06
542.0578003	0.66
543.1992798	0.37
556.2812500	0.52
560.1856079	3.39
561.2081909	8.61
562.2315674	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.1462
Annotation	Dasatinib
Peak:m/z	Relative Intensity
143.9382019	100.00
324.0724487	1.47
342.3680420	0.89
358.2594910	0.69
370.1871948	1.02
396.9235840	1.86
398.3516235	0.94
439.3002014	0.27
468.0960083	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7430878	0.44
232.3458862	0.33
252.9337769	0.39
271.9768372	0.22
290.7724609	5.54
317.8519897	0.22
374.4910889	3.31
392.7315674	0.17
402.1708374	0.15
418.8294678	0.57
458.5891113	30.94
483.7080078	0.28
502.5938721	0.57
508.5861206	0.21
518.1679077	0.19
524.5506592	0.60
536.0936279	1.68
541.8906860	9.77
542.5646362	100.00
543.1882324	1.68
544.8257446	0.73
548.5466309	0.48
562.2634888	0.70
567.0144653	0.56
574.4519043	1.41
594.3678589	0.42
604.5092163	2.72
611.7130737	0.15
624.0504150	0.37
625.8948975	8.33
626.5845947	23.58
632.2539673	0.95
646.6228638	1.97
650.6165771	1.29
664.1678467	3.66
665.0664673	0.52
687.3018799	5.68
688.3923950	1.24
689.0184937	0.29
693.7614136	1.32
694.8955688	0.39
707.2868042	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
99.1660614	0.63
104.8694763	0.23
118.1383667	0.62
122.0537109	0.31
132.97966	1.32
138.120575	0.49
149.1029205	3.44
150.1207123	0.74
152.8725128	1.09
154.1438751	0.23
155.1166077	0.40
159.1290283	0.44
162.122879	2.58
165.3125305	1.02
166.1909332	0.66
169.123764	0.71
170.1393433	0.49
171.9746246	0.34
177.9449921	0.43
178.9227753	1.49
180.0654449	1.83
181.1399231	0.68
182.1091003	0.27
183.1004486	1.26
192.0026855	1.11
193.1149445	1.70
193.9233246	1.32
195.1145172	3.29
198.0037994	0.31
205.9426117	1.17
207.1840057	12.01
208.0903168	10.38
209.0530853	10.22
210.1779327	0.66
214.8553009	0.38
216.0898285	0.50
216.807663	1.86
222.1223145	8.95
223.1074829	14.54
224.1576538	4.33
225.0876312	0.51
233.2061157	0.75
234.182663	2.84
235.9848633	0.35
251.0778656	100.00
252.038559	32.21
253.1593781	5.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1237
Annotation	Bidensyneoside C
Peak:m/z	Relative Intensity
100.8111725	0.03
112.9628830	0.17
118.8641891	0.05
130.9014435	0.06
136.9758301	0.04
143.0711670	0.09
151.0443420	0.02
158.8707275	0.03
160.9163208	0.19
164.0526428	10.70
179.0097046	100.00
227.9880676	0.08
272.7719421	0.08
295.1387329	0.04
297.1832275	0.02
323.2270508	0.08
326.2546997	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	582.2223
Annotation	Unknow
Peak:m/z	Relative Intensity
221.9915771	0.86
254.1141663	0.28
307.1187134	0.13
318.8681641	0.15
322.3588257	0.84
335.7219849	0.27
337.0447998	0.64
347.8369141	0.04
355.2217407	0.10
359.3076782	0.08
368.2222900	0.39
392.2454834	0.11
400.3904419	0.27
405.2944946	0.05
408.0338135	0.16
409.3096924	0.14
418.3366699	0.14
419.2470703	0.14
426.2508545	0.79
427.3076782	1.04
428.2144165	0.40
435.1777954	1.08
436.2556152	23.08
437.2832031	0.35
440.4101562	0.19
441.8499756	0.09
453.2442627	0.24
454.0517578	0.29
464.4551392	0.07
468.2644043	0.39
474.2200317	0.04
486.2118530	0.09
490.2294922	0.21
504.1459351	0.15
505.2562256	2.25
509.0160522	0.10
510.0488892	0.30
514.4638062	0.13
518.0938110	0.11
535.1163940	0.42
536.2580566	100.00
536.8695679	0.75
540.1514282	0.11
543.5012207	0.04
544.8995361	0.12
546.0064087	0.51
558.9826660	0.27
564.2500610	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.1281
Annotation	Unknow
Peak:m/z	Relative Intensity
151.0002594	16.00
162.9051514	1.54
166.1433716	0.46
169.0533295	0.60
178.0460510	0.33
266.2036438	0.22
283.9744263	100.00
286.2346191	0.19
294.7093811	0.35
295.3404846	0.31
313.0322876	2.17
315.2368164	0.13
322.3199463	1.11
324.0740356	0.13
328.1779480	0.16
335.1252136	0.37
367.2639160	0.22
383.9907227	0.37
386.8978577	0.41
399.0913086	0.62
404.2976685	0.29
411.2487793	0.35
427.5919495	0.79
429.2883606	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.2632
Annotation	linoleamide
Peak:m/z	Relative Intensity
80.9605484	0.39
90.92999268	0.29
94.88569641	1.59
97.11690521	0.10
99.91269684	0.43
106.9564362	0.30
109.1287766	0.33
110.9169312	0.26
112.5626526	0.36
113.1954346	0.14
114.0568085	0.23
119.0781326	0.27
121.0313644	1.22
122.9461594	0.53
124.1086044	0.44
125.0647278	1.13
128.0157166	0.58
129.0387878	0.08
132.9178619	0.24
134.9136963	1.10
136.9475403	0.60
139.088501	0.77
142.100708	2.65
145.1334839	0.15
147.0325775	0.49
149.2243652	2.58
150.1070709	0.56
151.0918579	1.18
153.0568542	0.93
154.0053406	0.89
154.9514465	0.08
156.034729	1.32
158.0265961	0.28
160.9803314	2.34
163.1724091	1.01
165.1040649	2.45
167.2049866	0.15
170.133728	2.80
175.060379	0.50
177.0091858	0.87
179.1776733	2.78
181.1817932	0.53
181.9710083	0.60
183.9149475	2.98
184.5233002	0.25
189.0596771	0.40
191.1770325	0.48
192.308075	0.21
192.9627838	0.24
196.1020813	2.85
198.1021423	1.80
203.4163818	0.40
206.031311	0.14
209.3252563	0.31
210.1453552	2.53
212.6616516	0.13
217.1857605	1.57
219.138092	0.43
221.3241882	2.32
222.3814087	0.61
224.2905884	1.82
230.8757019	0.39
234.3520508	0.71
238.3372192	0.87
245.2368774	40.70
249.1139221	10.03
252.198761	0.87
253.2792969	1.30
263.2433167	100.00
265.130249	0.68
266.0782471	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
102.6918182	0.16
125.0145264	0.35
140.8069305	0.11
152.7457886	0.13
160.8506165	0.28
169.3052063	0.04
172.8894653	0.50
176.9011078	0.13
181.4166718	0.09
183.3031158	0.06
187.0255737	0.37
188.2319336	0.52
188.8901825	0.35
199.062149	0.39
201.2401581	0.07
201.9504242	0.09
202.8205109	0.62
204.7975922	0.09
213.1566315	0.31
214.8914948	1.10
216.1904907	0.17
217.2821808	1.16
218.0801849	0.09
218.9328766	0.54
222.7268982	0.50
223.8630981	0.21
224.9596863	0.45
225.8599091	0.10
232.0684357	0.16
233.0345917	0.91
242.0051422	1.16
243.1362915	100.00
244.2262115	0.39
245.2693481	2.17
245.9694366	0.28
260.9516602	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.11
Annotation	Taxicatin
Peak:m/z	Relative Intensity
101.0341949	1.49
108.7034988	3.16
118.8891144	1.18
119.747879	0.68
122.8630981	1.77
126.9866943	0.88
130.7997894	0.69
134.0980072	0.38
135.0702209	9.79
143.1069946	2.49
153.0591736	100.00
161.0094299	0.95
177.1375732	0.30
179.0871277	0.86
181.2642212	0.51
187.7452393	1.42
195.0684204	1.06
223.1468506	0.88
227.0332642	0.38
231.1478577	0.86
251.2047119	0.56
252.130188	0.50
253.0561829	2.51
269.0407715	3.21
271.0941162	2.51
272.0989075	2.38
293.0596619	1.24
297.1539001	2.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
95.06025696	0.22
102.1360168	0.16
106.9975739	0.26
111.0601349	0.26
123.1008759	0.72
127.0617065	0.36
136.9544067	0.34
138.9789429	5.73
141.0838623	0.59
147.0803528	0.19
148.85289	0.20
150.7910767	0.30
153.0167236	1.19
165.0367279	0.12
169.3569946	0.22
177.0328522	0.77
178.6154175	0.81
180.8429871	0.14
182.3219147	0.37
183.0462646	0.74
185.0308075	0.56
193.0821838	0.49
197.1039124	9.41
203.0072021	0.85
209.1932068	1.06
211.1370239	1.69
217.0600281	0.22
221.0205994	0.38
223.1423035	0.76
224.9708557	0.11
227.1914062	1.12
233.2420349	0.91
236.8546448	0.11
239.0662842	7.30
241.0415039	0.89
243.2991333	0.97
251.3927002	1.33
253.2661133	0.30
255.0984192	2.01
256.0822144	0.15
261.2962036	3.02
265.2648315	0.35
269.1906128	0.31
279.2346191	100.00
279.9925537	0.28
280.7116394	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	372.1281
Annotation	4-(2-amino-3-hydroxyphenyl)-4-oxobutanoic acid O-glucoside
Peak:m/z	Relative Intensity
156.3416748	0.11
164.0436096	4.52
180.1768799	0.05
209.9949341	100.00
210.6196442	0.41
211.4288483	0.04
238.0227051	0.06
245.2061768	0.04
252.1529541	0.04
260.0573425	0.14
279.1828613	0.05
283.2924805	0.03
290.5074463	0.24
291.1191406	0.43
311.1747131	0.19
326.3737488	0.05
327.5426025	0.08
335.5408325	0.10
336.8009644	0.37
354.1231689	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2498
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.9270782	0.40
106.9444275	1.23
109.0960541	0.50
116.887764	0.36
121.0370407	3.80
124.9587021	0.10
132.8863373	0.29
135.1376343	1.09
137.0140381	0.59
143.2240906	0.28
147.0549927	1.41
148.9938049	0.22
151.0495605	0.37
157.028656	1.13
158.6809387	0.36
160.2059174	0.47
161.0004272	0.31
163.219635	0.22
165.1201782	0.58
169.0058594	2.80
169.9591675	0.67
173.1216736	0.37
175.1042328	1.19
178.7978516	0.14
182.7636719	0.38
185.2510071	0.28
187.2079315	0.43
194.938324	0.21
199.1192474	0.12
200.8600616	0.92
203.1410217	1.37
205.1942139	0.98
209.2118225	0.37
211.1571045	0.64
213.114624	0.27
215.1699219	0.14
216.9515686	0.39
223.2268677	0.71
229.1156006	0.17
231.2339172	3.24
239.4983215	1.10
241.0511475	0.20
245.2244263	3.02
247.2695007	6.04
251.4293518	0.54
259.1136169	1.56
260.7379761	0.18
264.1369934	0.42
279.2312012	1.00
280.1947021	0.17
281.0516052	0.24
283.311676	0.26
284.1697083	0.36
292.2050171	2.11
295.6534119	0.27
297.1851807	0.42
298.3157043	0.19
299.4007568	3.13
305.2125549	2.12
313.2295532	0.65
323.2471008	100.00
324.1012573	0.46
324.9649048	0.11
345.8037109	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.9912109	1.83
109.0366516	1.21
110.5232162	0.71
111.1823502	0.29
113.8464432	0.72
118.9138412	0.25
121.0510254	0.50
125.0818481	0.21
135.059845	2.52
137.2110138	0.25
143.0318604	0.99
149.0928955	0.40
151.2456055	0.44
155.2008972	0.21
157.0165405	1.74
158.9552917	0.57
160.9242859	0.31
169.1784058	2.35
173.0616455	1.54
175.1503601	1.18
177.0301208	0.50
179.1911011	0.32
180.7761841	0.25
183.1376648	1.22
185.3388824	0.52
189.0790405	1.41
197.1226501	1.60
199.297821	0.61
205.1663513	1.45
208.7177429	0.48
209.3187561	0.28
210.7548218	0.97
212.9833679	0.52
217.1333618	0.28
225.0491638	0.20
231.0369568	0.35
232.9697266	0.21
234.9745178	0.28
243.0182495	0.77
245.1547852	2.65
247.2262878	3.35
253.2490234	0.51
257.0444641	1.35
259.0629883	0.36
267.4873047	0.39
270.9523621	0.31
277.3834229	2.77
279.556488	1.43
281.5814209	1.01
282.3421936	0.45
287.2596436	1.13
291.0331116	0.32
291.9539795	0.64
295.2615356	3.10
297.2602539	0.16
299.1929626	3.56
305.1936951	4.10
307.330719	0.60
311.1214905	0.13
313.5584412	0.76
323.2335815	100.00
324.2069092	1.64
331.5574646	2.21
341.1438293	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0875
Annotation	Chaenorrhinoside
Peak:m/z	Relative Intensity
100.9236755	2.04
107.1335602	0.10
112.9532623	3.28
115.1669159	0.04
118.9353027	1.81
125.0704498	0.18
130.9902191	0.79
133.1737213	0.66
135.0328827	5.29
141.2744904	0.06
142.9316864	4.87
148.9821167	0.53
160.98703	23.56
168.8875427	0.23
177.0901794	0.08
179.0260315	100.00
180.241745	0.06
180.8608704	0.06
182.7090454	0.06
189.0913849	0.25
190.9918213	0.03
203.0523682	5.82
210.0595703	0.10
210.9797363	0.10
221.1805115	0.94
225.2169189	0.19
232.9884338	0.68
237.164093	0.13
245.1861267	0.08
251.0474243	1.13
252.2095337	0.05
255.8729553	0.06
265.126709	0.07
266.2991333	0.22
267.1878967	0.07
269.4057007	0.08
270.3558044	0.19
271.3639221	0.14
277.2632446	0.04
280.049469	0.05
281.2028198	3.77
293.2741699	0.18
294.8539124	0.95
296.946106	0.30
304.9378052	0.08
307.2000427	0.20
309.1578064	0.05
310.1916199	0.11
311.0245667	0.07
313.5328369	0.31
323.1570129	0.29
324.0473022	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.1227
Annotation	Lactulose
Peak:m/z	Relative Intensity
126.9098816	2.25
128.1921692	6.37
144.9481812	3.90
162.4287720	2.15
179.9958191	1.67
180.8829498	0.98
202.3609314	3.13
243.4550781	1.44
244.1676941	1.01
259.8278198	1.35
271.3173218	2.56
272.2717285	6.29
288.8611450	7.21
289.9360046	22.27
310.6484375	0.56
324.9457397	100.00
326.0463562	42.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1035
Annotation	3,5,7,3',4'-Pentahydroxyflavanone 7-alpha-D-glucopyranoside
Peak:m/z	Relative Intensity
137.6881561	0.08
149.0135193	0.12
175.0469818	0.13
177.008606	1.51
178.9551392	0.08
185.2966003	0.04
191.0182495	0.14
203.2727356	0.03
208.0979614	0.08
239.1116638	0.11
240.241394	0.23
258.991272	0.25
268.1938782	0.29
270.9342651	0.17
274.8736572	0.40
282.9604492	0.11
285.0664673	24.87
285.6802979	0.21
288.2745667	0.18
289.1769409	0.06
292.9568481	0.15
300.242981	0.40
300.9478149	0.09
303.0590515	100.00
311.0076294	0.52
316.2116699	0.29
327.0747986	0.57
329.4876709	0.04
334.2061157	5.84
337.1450806	0.08
338.6899414	0.07
341.1487732	0.10
342.4675903	0.06
343.1004944	0.14
345.142334	0.15
360.2824402	0.22
363.964325	0.19
369.4057312	0.30
370.8963013	0.30
377.4283142	0.15
378.3334045	1.80
386.2326355	0.12
393.4484863	0.10
394.2428894	0.60
402.2849426	0.09
403.4490967	0.07
404.1881409	0.16
406.2328796	0.21
411.3233948	0.04
419.0744019	0.15
419.8461914	0.06
421.3055725	1.04
428.8652344	0.09
430.1509705	0.34
431.4974976	0.25
436.8443298	0.18
437.5350037	0.20
447.1739807	4.97
448.0194397	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1333
Annotation	Unknow
Peak:m/z	Relative Intensity
148.5440521	0.08
161.1394806	0.16
177.2278748	0.32
182.8110657	0.41
186.2334137	0.34
206.1863403	0.36
231.1884766	0.23
242.2459717	0.19
258.0651855	0.90
259.0485840	0.05
281.1327209	0.07
286.1029663	100.00
287.1109009	0.95
288.6526794	0.10
308.0236511	0.13
308.9845581	0.04
318.3575439	0.18
327.1714783	0.07
327.8839722	0.28
331.0940552	0.22
341.1551819	0.09
345.0878601	0.22
348.3111267	0.08
350.3683167	0.16
366.3051758	0.35
367.3807983	0.13
370.1797180	0.08
375.5479736	0.38
384.0047302	0.09
385.4978333	0.10
389.0875854	0.20
392.9115906	0.21
393.8424988	0.13
394.8133240	0.65
395.4650879	0.17
402.4424744	0.23
403.3110046	0.16
404.4085388	0.18
411.5116882	0.84
412.1447144	1.22
413.1816406	0.35
420.2287292	0.44
421.1202698	0.06
423.5109558	0.15
425.0324707	0.08
429.8200378	1.30
430.6187134	0.71
432.1460266	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.2838
Annotation	MG(0:0/16:0/0:0)
Peak:m/z	Relative Intensity
177.1476135	0.39
198.7528839	0.19
213.2568970	0.29
227.2153625	0.32
238.9713440	0.33
245.1832886	0.11
249.1964722	0.23
252.9766541	1.73
257.5193481	0.22
285.2115479	0.40
295.4002991	0.15
298.9600220	0.31
303.2684021	0.18
313.2873230	100.00
314.2864380	1.21
316.0487671	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.2402
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0468750	0.10
203.1340942	1.18
206.2343597	0.05
215.1278992	0.08
219.0847473	0.08
221.2169342	0.28
225.3991699	0.30
231.2864380	0.04
233.0663605	0.04
272.1738586	0.53
283.2420654	0.18
287.0585938	0.13
314.1834106	0.07
323.1743164	7.99
330.9183350	0.07
332.0773926	0.07
341.2083130	16.12
351.1772461	0.34
365.0408325	0.05
411.1850586	100.00
412.1463623	0.06
413.3128052	0.12
431.4436646	0.25
432.5153198	0.17
435.2667847	0.07
442.9389038	0.07
445.0628662	0.11
451.3504639	0.90
452.3786011	0.21
453.0863647	0.08
454.1137695	0.09
461.4904175	0.07
465.9231567	0.30
466.5358887	0.14
467.4184570	0.12
477.4091187	0.21
485.1634521	0.06
493.3065796	0.11
495.7250366	0.21
496.3319092	0.37
497.2763062	0.52
497.9688721	0.22
503.3200684	0.31
522.1372681	0.22
525.2975464	1.81
527.1893311	0.30
529.2169800	0.15
546.2107544	0.22
555.0233765	0.43
557.2216187	0.50
569.2321167	1.12
570.2786255	0.15
577.1354370	0.28
578.2852173	0.15
579.7203369	0.29
580.3586426	0.04
585.1968994	0.42
592.7193604	0.18
596.1082764	0.16
596.9132690	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.18
Annotation	Glycobismine-D
Peak:m/z	Relative Intensity
179.3030090	0.11
204.9563904	0.41
216.8603210	0.22
235.1074219	2.74
277.1464844	0.96
295.0839233	100.00
341.0895386	0.98
457.1646118	0.66
503.2561035	0.10
520.8737793	0.49
521.5343628	0.11
618.9800415	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.3753
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
191.0919495	0.09
199.0646973	0.37
202.9990540	0.10
217.1177063	0.03
219.0834198	0.07
221.1700134	0.18
226.9445801	0.06
235.1145325	5.76
236.1343079	0.24
245.1065826	0.28
253.2257385	1.49
254.2802124	0.10
258.9754333	0.09
262.1933899	0.05
263.2334595	0.39
269.1593018	0.05
277.0731812	0.18
279.3486938	3.05
280.5886230	0.52
287.2104492	2.96
288.2702637	0.26
293.0415039	0.05
301.4171143	0.29
305.1260986	5.98
306.1719360	0.06
319.2424927	0.08
321.4749756	0.11
323.1847534	0.82
324.1290894	0.09
349.4437256	0.09
356.5842896	0.11
361.3506470	0.23
379.4176636	0.11
397.1652222	100.00
398.2023926	8.09
415.1865845	32.66
416.3336792	2.99
428.1208496	0.08
549.1339722	0.09
641.5427856	0.05
648.6776733	0.06
660.3890991	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.3222
Annotation	PC(20:5(5Z,8Z,11Z,14Z,17Z)/0:0)
Peak:m/z	Relative Intensity
221.7180328	0.93
359.3325806	1.90
375.4863892	0.34
453.2354736	0.59
483.2747192	100.00
498.2272949	0.43
514.4310913	0.38
524.6950684	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	951.5414
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
335.2727051	29.97
336.2654114	5.26
440.2557983	0.27
458.2391968	1.57
459.0158691	0.33
476.1578979	100.00
477.2617188	17.13
509.8435059	0.30
561.9714966	0.08
922.4247437	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.91
Annotation	Unknow
Peak:m/z	Relative Intensity
244.8409119	0.35
272.9763184	0.68
386.7590332	0.72
427.1318359	5.58
472.6366577	2.70
500.8493042	1.03
502.6165161	0.21
540.8079224	100.00
541.6878052	1.00
542.8696899	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	346.1125
Annotation	Unknow
Peak:m/z	Relative Intensity
118.9813843	0.73
136.9439850	20.53
147.2337952	0.14
154.0192108	100.00
176.2564392	0.37
183.8485260	0.05
197.0051270	0.02
201.2088623	0.14
214.0804749	1.56
286.7395020	0.11
292.8840942	0.05
300.2345276	0.24
310.1682434	0.09
328.1387024	0.33
329.1077576	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	703.3851
Annotation	10,11-Dihydro-chalcomycin
Peak:m/z	Relative Intensity
183.7239838	1.03
202.9962463	0.42
347.2885742	0.89
365.0720215	4.27
366.4608765	0.48
421.2434082	1.17
473.6932373	0.25
517.3359985	0.79
532.4143677	1.24
541.4664917	100.00
542.5724487	10.61
578.1303101	1.02
613.6769409	0.82
641.3943481	0.35
685.0869141	0.24
685.9153442	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.3282
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
161.1459198	0.09
235.2728577	0.81
253.1320496	9.34
261.2286377	0.04
277.3489380	0.04
279.2711182	83.32
290.8089600	0.11
357.2191772	0.17
473.4297485	0.17
514.5748901	4.28
515.2169189	100.00
522.5006714	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.0757
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9012299	0.05
179.0003510	0.21
180.0097961	0.27
224.3576355	0.08
239.1370544	0.20
308.0807800	0.49
321.2203369	0.08
337.1992798	0.44
341.1175232	34.50
342.0705566	3.41
356.3093262	0.14
366.3963318	0.31
387.0901184	46.46
425.0223389	100.00
432.8738708	0.05
434.9720154	0.06
453.2707214	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2106
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
84.83476257	0.18
91.00246429	3.91
92.96376038	3.52
94.94490051	6.68
95.81451416	0.29
97.04892731	1.85
97.96780396	0.61
98.89439392	0.45
100.6213226	0.30
103.1588135	0.44
104.9077148	7.35
107.01828	5.37
109.1180649	3.76
110.7511902	0.85
112.8905029	0.32
115.0566101	0.55
117.0696411	1.97
119.0301132	3.00
120.9535904	7.06
122.1835327	1.42
122.9991302	5.27
124.9953766	1.31
127.1275482	0.21
127.9909286	0.47
128.9822998	3.13
131.021347	4.28
132.3184967	1.26
133.259491	3.20
135.1353455	4.17
137.0050507	1.97
138.9505157	0.38
141.0555725	1.80
142.9262695	0.29
145.0778809	9.92
146.7908936	1.18
149.0245972	8.27
151.0673218	17.96
152.9721069	2.10
154.1008606	0.62
155.0973206	4.25
156.2948608	0.69
157.09758	0.89
159.1157532	3.01
160.9844971	1.05
162.0704651	0.17
163.014679	4.27
164.3252258	1.97
165.2016754	7.41
167.0415344	0.82
168.9886475	2.23
170.9963989	3.18
171.8183441	0.73
173.0942688	4.33
174.1338348	0.39
176.997406	14.23
178.750473	1.97
179.4572601	1.21
180.2200012	0.30
181.1131439	0.41
183.0705872	0.49
187.0367126	1.31
188.9627991	1.86
191.1233521	1.15
193.211731	1.43
194.8825226	0.81
196.1922455	0.27
196.9863892	0.99
198.9883118	1.40
200.0592346	0.17
201.1271057	1.56
202.9828796	0.38
204.8277283	1.52
205.5354614	1.18
209.2930298	1.03
210.516571	0.87
211.2009277	0.80
213.1474915	0.37
214.262146	0.21
217.3640137	0.67
218.1746521	0.24
219.154541	3.02
221.1070862	2.61
223.1228943	11.19
224.8941956	0.17
229.2119141	0.50
233.1749573	1.42
235.0498962	1.77
237.1341553	30.75
238.1139221	1.19
239.2163086	1.00
242.2076721	1.03
247.2712097	4.09
249.2164307	1.99
251.2178955	1.94
257.2299194	8.65
258.4133911	0.62
262.5887451	0.50
275.1956787	100.00
276.2785645	4.25
283.4631348	0.53
293.2978516	8.49
294.3280029	1.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1084
Annotation	Maesopsin 6-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
135.9169769	0.03
148.8951111	0.05
153.024292	0.02
157.2401428	0.05
163.0553589	0.20
173.1433716	0.03
176.1337585	0.05
179.0221863	0.35
179.9777832	0.09
191.0493622	0.01
199.1751404	0.10
200.9637604	0.12
203.3402405	0.04
217.057373	0.05
233.1659088	0.06
235.0563965	0.04
241.226593	0.06
243.1766357	1.10
251.11203	0.16
257.0533142	0.08
259.0875549	37.01
264.9196472	0.14
267.0686646	0.12
269.0892944	36.03
269.8143616	0.28
283.2392578	0.32
287.0546265	100.00
287.8348389	0.01
290.8695068	0.03
293.201416	0.11
311.0939026	1.91
314.8539429	0.04
324.8771362	0.01
329.2078247	0.26
341.1503906	0.17
342.0443115	0.72
353.2587891	0.25
359.5984497	0.02
362.4041138	0.03
387.1795349	0.09
389.364502	0.06
410.9569092	0.10
412.0259705	0.03
413.1846924	0.04
421.2195129	1.53
430.3547668	0.07
431.2511902	3.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.0915
Annotation	Hexahydro-6,7-dihydroxy-5-(hydroxymethyl)-3-(2-hydroxyphenyl)-2H-pyrano[2,3-d]oxazol-2-one
Peak:m/z	Relative Intensity
122.9995270	0.11
135.9675293	0.16
155.8714752	0.10
158.3322906	0.11
167.2030334	0.06
168.2208557	0.29
182.1427307	0.23
193.1205139	0.17
210.0502625	0.49
223.2107239	0.20
233.8684998	0.15
235.3677368	0.25
244.5632935	0.05
252.0481262	47.08
252.6728210	0.12
254.3369446	0.11
256.3511963	0.10
257.1836853	0.24
262.0346680	1.80
265.3354492	0.07
267.1587830	0.10
273.0003967	0.44
274.6285095	0.10
279.9374390	100.00
280.8508606	2.21
289.1618042	30.92
290.1439209	2.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.38
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
222.0117493	0.00
227.9922485	0.00
235.0065308	0.04
253.0227356	0.00
279.5324707	0.04
287.1178589	0.04
305.2420044	0.10
323.4628906	0.01
336.7524109	0.00
372.2990112	0.01
378.3971558	0.00
397.3023071	5.19
398.2581177	0.00
415.3666382	1.02
450.7719727	0.01
453.1604004	0.00
454.5106201	0.01
527.3936157	0.01
650.0903931	0.01
659.6511841	0.01
660.6055298	0.00
663.4733276	0.02
677.2405396	100.00
678.1370239	0.74
685.0880737	0.01
687.1694336	0.00
688.4726562	0.02
705.2586060	0.04
706.2286377	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2389
Annotation	Briaexcavatolide K
Peak:m/z	Relative Intensity
164.7273865	0.03
173.3403625	0.04
174.9903412	0.12
177.3401184	0.02
179.0252838	0.14
181.0438995	0.34
186.8520203	0.04
189.9504089	0.08
190.9744263	0.16
194.0655823	0.20
194.9974518	0.19
196.1023254	0.24
204.0758667	0.04
207.2828979	0.03
207.9951019	0.01
217.2638245	0.07
221.0958557	0.09
221.8929596	0.07
223.0908051	0.08
232.1120300	0.03
235.2131958	0.16
240.2692261	0.04
266.3334656	0.03
284.1928711	0.08
286.0658569	0.06
298.3111267	0.12
299.1282959	0.18
312.1487732	0.03
313.1390381	0.16
315.0799866	0.07
325.2607422	0.03
326.3152466	0.04
327.2390137	1.33
328.1931763	0.16
341.3084106	0.98
342.2286987	0.28
343.2891235	0.17
343.9762573	0.36
345.3480225	0.08
357.3630981	0.50
358.3806152	0.79
359.1865234	0.11
360.3931885	0.06
361.1901855	0.19
371.2543945	1.07
373.2523193	1.03
374.2462158	2.09
375.2570801	0.44
376.1046143	0.15
377.3861694	0.08
381.3402710	0.03
383.3706665	0.16
385.7449951	0.03
387.0820312	0.03
388.2605591	5.58
389.3079834	3.31
390.2017212	0.61
391.0768433	0.07
392.2479858	0.31
393.1506958	0.18
394.4099731	0.15
396.9149780	0.03
403.2754517	8.04
404.3260498	1.98
405.3471069	0.40
406.3833618	2.61
407.3515625	2.84
408.3277588	1.16
411.2194214	0.08
415.2748413	0.07
421.2320557	100.00
422.3207397	25.87
423.3745117	0.26
424.3430786	0.03
432.2305298	0.12
436.3203125	0.06
448.1170044	0.17
449.4113770	0.04
451.3621216	0.11
454.4117432	0.23
461.4315186	0.04
462.3634644	0.10
463.5510254	0.28
464.3077393	0.02
470.2564697	0.07
476.0090942	0.02
477.2847900	0.09
486.0711670	0.06
494.3782349	0.09
496.3918457	0.04
497.0587769	0.06
498.1618652	0.10
505.1277466	0.09
510.9445190	0.04
521.2192993	0.71
522.5592041	0.12
531.1454468	0.07
535.8332520	0.10
537.3357544	0.14
538.3862915	0.33
539.4064941	0.06
540.2844849	0.11
542.0548096	0.11
547.1528931	0.02
548.2485962	0.05
550.3243408	0.08
551.1966553	0.19
552.6658325	0.16
553.6669312	0.14
554.4393921	0.04
565.2931519	0.46
566.3905640	0.18
568.3274536	10.16
569.3905029	2.76
570.4061890	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	378.19
Annotation	O-Methylhernandine
Peak:m/z	Relative Intensity
114.7964554	0.16
118.1101990	0.09
131.1702576	0.22
138.7573547	0.11
140.9120941	0.26
142.9437561	0.24
144.9381104	0.37
156.9349976	0.35
162.2152100	0.16
162.9855347	0.14
164.0098572	1.47
165.0659943	0.19
169.0035400	0.20
185.0189209	0.84
186.9918823	0.33
193.1622925	0.41
196.4552917	0.25
197.5177917	0.16
199.1561279	1.33
213.1879425	0.92
215.0982208	0.66
216.9725952	0.90
219.0600891	0.12
221.2542419	0.11
227.0145264	0.51
229.3422241	0.08
230.0825500	0.32
231.0469360	2.65
233.0177612	0.67
239.1288147	0.47
243.0160828	0.33
245.1703186	0.36
246.3873901	0.70
250.0669861	0.34
251.2139893	0.49
252.1335449	0.32
258.0411377	0.28
261.3921204	1.07
265.3311768	0.46
269.2930908	0.73
278.5547485	0.24
279.6050415	0.11
280.7925720	0.48
281.3954468	0.33
283.3099976	0.18
287.1589355	0.29
289.1004944	0.71
291.3016968	0.24
293.2114258	0.24
295.5516052	0.54
296.2072449	0.32
297.2207947	10.15
298.0828247	0.18
307.2390747	3.39
311.1480103	0.92
311.9011841	0.32
313.0974731	0.35
314.2571411	1.41
315.2515869	8.33
316.0957031	0.09
319.1182251	0.20
324.3089600	1.00
325.2819824	8.76
328.8562317	1.58
331.2709351	2.35
332.1536865	1.09
333.1769409	1.62
334.3521729	1.03
342.2265625	7.77
343.2640076	30.03
344.3820190	0.54
345.9794617	0.11
347.2951965	0.47
348.1988220	0.27
350.5283508	0.96
357.1598206	0.40
360.2520447	43.05
361.3169556	100.00
362.1810608	1.37
368.7472229	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2876
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
139.1398315	4.71
141.2745209	1.66
169.1043396	5.14
170.8253479	7.83
203.1914062	8.63
209.0153046	5.41
216.9703064	6.89
222.2308044	4.12
224.2335663	7.66
228.3298645	1.78
243.2172546	2.12
245.3419189	4.37
247.2264709	1.47
254.2689819	1.29
256.7113647	1.27
257.8443604	1.66
281.0414734	3.44
288.1408386	8.91
291.1169128	4.47
294.9533081	9.32
306.2110901	5.87
309.3852234	3.31
314.2873535	4.08
317.2376404	8.25
339.381958	11.97
340.8352051	3.83
341.553772	6.44
342.2015076	7.92
343.1533813	2.50
357.3051147	11.86
359.1102295	3.45
364.1151428	4.99
365.2820435	3.96
366.5386047	17.59
367.1964417	4.22
373.2608948	4.35
377.1668091	6.84
378.2292175	11.05
385.3799133	3.69
390.314209	25.20
391.0923767	5.36
394.1259155	2.29
395.2831726	12.52
398.5184937	4.09
407.065033	6.36
408.2761841	100.00
409.2926331	50.43
412.1695862	8.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	424.1436
Annotation	Unknow
Peak:m/z	Relative Intensity
166.0966492	0.63
173.9444427	0.73
183.4150391	0.70
184.2887878	3.12
202.0888062	8.41
212.3529205	0.74
220.1514587	100.00
246.9175110	1.55
259.1481934	9.36
261.1900635	0.68
262.2908020	1.34
293.5733643	0.54
294.2043152	1.46
332.1618042	0.48
361.8860168	0.16
380.2257385	0.58
388.2625427	4.73
406.0531616	94.19
406.7773132	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	540.1126
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0916748	4.19
173.3053589	0.04
192.0431213	0.14
309.0021973	4.40
309.7551880	0.33
328.1129761	1.40
347.0659790	100.00
347.6896362	0.19
366.0068970	19.88
366.9692993	1.25
385.1062622	4.78
404.1911011	0.19
408.0939941	0.22
419.9181519	0.05
454.1342163	0.20
494.0447388	0.36
501.9385376	0.07
503.7676392	0.35
521.3433228	0.19
522.1443481	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.2915
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9499664	0.11
158.1114502	0.08
165.9758911	0.72
183.9982605	93.99
215.1003265	0.17
219.3625946	0.12
240.1385193	0.11
244.8963013	0.05
248.3235779	0.24
257.9948120	0.09
263.1786499	0.10
284.9336548	0.11
293.4679565	0.25
305.4152222	0.25
307.4606628	0.60
312.9761353	0.14
321.3878784	0.13
323.2500610	0.07
329.3294983	0.11
341.2192688	0.06
359.1550598	0.10
360.2384644	0.23
370.5320435	0.14
385.1899109	0.10
398.1863098	0.08
405.2070312	0.12
406.3694763	0.48
409.3414001	0.20
413.2650452	0.34
422.7552795	0.04
427.0825195	0.29
437.0711670	0.61
439.3720398	0.23
442.3154297	0.09
444.2073364	0.50
445.8686829	0.16
453.9964905	0.28
455.3807678	0.13
459.1117859	0.05
472.3438110	100.00
473.1520386	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0717
Annotation	Gerfelin
Peak:m/z	Relative Intensity
82.9223709	0.02
96.8834915	0.32
109.0330048	1.19
111.0114365	0.04
113.0814667	0.06
121.0464630	0.16
123.0204010	0.20
125.0679245	2.45
130.1306763	0.05
135.0412292	0.49
137.0133057	2.26
138.9112549	0.24
143.2821655	0.02
145.0542908	0.04
146.1069031	0.09
149.1381531	0.11
151.0244141	1.70
159.0575409	0.78
160.1239014	0.03
160.9948273	2.07
162.1779480	0.16
163.0410156	0.39
164.0957794	0.40
165.0505066	2.42
167.0855713	1.25
173.2595215	0.05
175.0515900	0.41
179.0942688	9.88
183.8025208	0.05
185.0365753	0.46
186.1919556	0.41
187.1015167	0.34
188.1020813	0.77
199.1158447	0.11
201.1589661	0.52
202.5166626	0.58
203.1777649	6.55
205.0458069	29.04
209.2499695	0.08
211.9715271	0.08
216.0646667	0.06
217.1573486	1.05
220.7908630	0.10
227.1554565	1.39
229.1291199	0.23
231.1011658	5.37
243.1848755	0.03
245.1075134	100.00
247.0915527	6.49
252.9976196	0.09
271.0874023	4.53
273.2692566	0.02
274.2213440	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8888092	1.17
206.7585449	100.00
272.1627808	0.05
293.3919067	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	177.1018
Annotation	153310-48-6
Peak:m/z	Relative Intensity
131.2542267	0.06
137.1429138	0.04
149.2801666	0.09
160.0831451	100.00
160.8630524	0.05
168.0290527	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0010986	0.08
157.8710175	0.08
158.9767303	2.70
160.0463409	0.86
161.0458679	1.01
161.9368134	0.08
170.8676147	0.04
199.0872803	0.09
199.9908752	0.12
201.0439148	0.27
201.9003601	0.05
217.1514587	0.11
217.8323212	0.02
229.0919647	0.38
230.0365753	0.35
230.9895020	0.62
232.0022125	0.02
245.2341461	0.02
272.9887085	26.05
274.0255432	16.80
275.0162048	31.98
276.1197510	5.05
361.3998718	0.06
386.9991455	22.86
388.0023499	23.63
388.9479065	100.00
389.9375305	28.78
429.9942627	0.07
431.3612366	0.03
441.6630554	0.03
448.2488708	0.03
454.8677673	0.02
457.8937683	0.49
459.1470032	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	489.1916
Annotation	Unknow
Peak:m/z	Relative Intensity
147.9031067	100.00
310.3093262	0.72
324.8450623	1.26
327.8962402	0.41
344.0215454	0.37
365.2646179	0.56
391.6926575	0.90
472.2103577	2.31
473.1163025	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.1083
Annotation	Paeonoside
Peak:m/z	Relative Intensity
100.9257278	1.42
102.9550476	2.38
112.9988098	2.56
118.9793472	3.27
123.9421082	0.41
124.9615784	0.21
131.0820618	1.11
136.9971771	0.88
143.1489563	0.85
144.7943268	0.11
147.0405579	56.75
149.0419312	0.08
149.9889832	1.47
154.6935425	0.05
160.9219971	0.81
162.7889862	0.06
165.0491638	100.00
168.0561829	0.15
177.2373962	0.21
178.9815063	1.17
181.4297485	0.09
185.3632507	0.10
189.2211304	0.12
192.9801788	0.09
207.0592804	0.45
211.1850281	0.06
221.0267029	0.15
237.1975403	0.15
251.1166077	0.15
254.9352417	0.09
260.9819946	0.26
265.1317749	0.04
266.9429321	0.30
268.1255493	0.03
281.2320557	0.61
282.2648315	0.34
283.0641785	0.44
283.7191772	0.06
290.1358032	0.13
298.4277039	0.18
308.8829041	0.34
311.8793335	0.35
339.3257751	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Lactulose
Peak:m/z	Relative Intensity
323.2724609	0.02
326.9561157	0.06
341.1433105	100.00
342.0748291	0.01
368.5772095	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1082
Annotation	2-[hydroperoxy-(4-glucosyl-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one
Peak:m/z	Relative Intensity
151.0236816	4.54
155.9788055	0.12
161.3924866	0.12
163.1212006	0.77
164.9862823	0.19
168.864563	1.85
179.0496521	0.57
180.0548096	0.12
203.3433533	0.12
240.8784485	0.13
259.1555786	0.89
267.1908264	0.19
268.0800476	0.31
269.0550537	100.00
270.4445496	0.34
273.438385	0.38
286.5586853	1.35
287.2099304	9.50
297.1441345	0.27
313.1847534	0.32
315.555603	0.17
323.2163696	1.37
326.9953308	0.16
330.470459	0.30
343.1798096	0.36
350.050293	0.15
355.1480103	0.54
360.5559998	0.21
367.3625793	0.25
377.1742554	0.53
388.3862	0.25
401.1152649	0.32
402.1946716	0.42
402.8968506	0.71
405.5482483	0.23
406.2267761	0.19
407.1926575	0.39
410.8838196	0.29
413.2202759	0.37
417.3396912	0.19
420.1186523	0.41
421.2041321	0.39
429.0965271	0.32
430.2878418	1.03
431.2332458	3.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.1926
Annotation	Myricetin 3-rutinoside-7-glucoside
Peak:m/z	Relative Intensity
231.1502380	0.04
241.0439758	0.10
243.0797272	0.03
245.2300873	0.03
247.1840515	0.03
251.2480927	0.10
253.2737579	0.04
259.1176147	0.03
269.0100708	0.02
271.1282654	0.25
287.0616760	0.50
289.1226807	0.12
296.0068359	0.02
297.1787720	0.15
299.1248474	0.02
307.8761292	0.02
315.1046448	2.84
315.9760437	2.13
317.0851746	4.76
327.2025146	0.03
328.9854126	0.18
331.1055298	0.22
337.3513794	0.10
341.1509399	0.27
346.2014465	0.09
347.3162231	0.06
348.1473389	0.02
349.0141602	0.07
353.0170593	0.05
359.1429443	0.44
371.3080139	0.02
373.0877686	0.02
383.0187378	0.10
387.1452637	0.06
389.3938599	0.06
398.9656982	0.06
400.2374268	0.15
400.8886108	0.15
415.0583496	0.05
431.0254517	0.17
437.3138428	0.19
438.1880493	0.56
439.2736206	0.47
440.3174438	0.04
445.2645264	0.05
449.1254883	0.04
451.0523682	0.06
455.0456543	0.06
457.1345215	0.03
460.9800415	0.05
473.3164062	0.13
478.1475830	11.22
479.2510986	8.48
482.9995117	0.04
485.5744019	0.06
499.4281616	0.03
503.0150146	0.03
521.2705688	0.57
539.5968628	0.05
545.1350708	0.06
551.2206421	0.22
557.4063721	0.04
583.2880249	0.02
602.1601562	0.04
607.3518677	1.17
620.9777222	0.03
625.1817017	100.00
626.2508545	0.53
641.4168091	0.05
667.3153076	0.43
689.2865601	0.05
691.2346802	0.02
697.2932129	0.17
709.6541138	0.12
738.1640625	0.03
741.2824707	0.26
743.2029419	0.12
752.2828979	0.02
755.3558350	0.08
769.4830933	0.91
786.8203735	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.2675
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.0504303	0.08
152.9669800	7.76
154.0428162	0.25
166.2198486	0.02
171.0625916	0.73
171.9627991	0.05
240.1424255	0.34
258.1530151	0.08
259.2714844	0.01
279.5949707	0.01
283.5169067	0.01
309.6122437	0.01
313.1412964	0.03
336.2780762	0.03
356.2348633	0.01
359.5006714	0.03
391.1166992	0.01
394.2340088	0.03
415.4335938	0.03
416.3467407	0.05
421.5193481	0.04
433.2700806	100.00
434.3071289	14.84
446.4026489	0.07
447.0697021	0.02
449.1398926	0.03
462.3513794	0.01
467.2764893	0.03
474.3394775	0.01
476.8969727	0.01
482.2634888	0.02
483.3062134	0.07
484.2075806	0.11
485.1887207	0.09
488.4423218	0.01
493.2908325	0.01
502.4119263	0.02
503.3099365	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	450.2626
Annotation	PE(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9853516	0.16
152.8674622	0.24
196.0709229	0.21
197.0360260	0.01
214.0305786	2.02
215.1450806	0.10
246.0653992	0.02
253.2113342	100.00
254.2232361	17.41
254.8717346	0.06
271.2752380	0.01
317.2363892	0.01
351.0245972	0.01
370.0944519	0.03
376.1858215	0.01
388.4411926	0.03
389.3986511	0.05
391.8360596	0.02
405.3201294	0.06
407.1747437	0.07
408.7830505	0.01
413.1486206	0.02
414.3767090	0.04
415.2455750	0.01
422.2077026	0.01
433.0869446	0.01
448.8941956	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	397.3092
Annotation	16-Dehydroepicalcitriol
Peak:m/z	Relative Intensity
137.1227875	1.92
142.9475403	1.10
145.0163574	1.07
148.8409119	1.16
156.9703979	1.52
159.0615997	0.37
161.1467896	0.11
165.1734314	0.68
171.1089783	0.53
181.1741333	3.51
187.3691864	0.69
203.5163269	0.68
209.1636200	0.20
211.1575470	1.28
215.2039948	13.03
225.0932007	0.40
235.4034119	0.63
241.4086304	1.26
246.9147034	0.71
249.4121704	0.61
251.0838013	1.51
253.2073975	100.00
263.7062988	0.85
265.1798706	0.76
268.9659119	0.85
271.1801147	2.65
275.2714844	0.52
279.2269897	0.65
281.4264221	2.18
283.3280029	15.02
285.1629639	0.50
291.3615723	0.31
293.2484436	1.57
297.2460938	1.31
299.2767639	0.37
303.2158813	0.46
311.5339355	0.91
315.5828247	1.53
319.3990479	0.40
323.2688293	3.70
333.2617798	0.50
338.9245911	0.52
351.3317566	1.62
361.3601685	0.46
363.2572327	0.35
379.3222351	32.84
379.9292297	0.40
380.5712891	1.43
398.3829956	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	687.2391
Annotation	Unknow
Peak:m/z	Relative Intensity
195.9787903	0.05
209.2007141	0.05
213.2471924	0.66
214.1655273	0.02
230.9404602	0.23
244.8326569	0.07
259.1701050	7.52
273.0793457	0.39
291.0963135	0.02
305.0584106	0.04
309.0285950	0.03
327.1829224	0.04
357.5297241	0.08
359.2246704	0.89
371.2584839	0.34
373.1657715	12.26
404.8868408	0.02
413.1417236	0.03
426.8960571	0.56
427.5139160	0.18
459.3302612	0.04
471.1128540	0.02
473.2695923	100.00
486.9251709	0.40
513.2186890	0.14
526.9365845	0.06
531.0306396	0.02
539.4135742	0.07
540.3140259	0.10
551.1487427	0.11
559.0054932	0.11
573.1535645	1.94
596.8857422	0.07
602.9364624	0.10
612.9917603	0.03
614.2414551	0.04
615.2052612	0.04
626.9826050	0.03
638.2709961	0.07
639.6599731	0.26
640.4855347	0.26
641.1737061	0.73
642.0793457	0.13
668.5444946	0.23
669.2854614	0.16
670.1592407	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.2172
Annotation	Crepenynic acid
Peak:m/z	Relative Intensity
80.8498611	0.86
83.0028076	1.43
90.6045608	0.21
104.7682724	0.85
125.2438202	0.41
134.8809509	0.32
137.0404053	0.46
139.0438538	0.36
141.2891541	0.21
148.0789490	0.26
161.0792694	0.61
163.0138092	0.66
163.6819763	0.85
177.3224640	1.02
179.1634827	4.51
191.1151123	2.56
201.1816406	0.95
203.2376709	0.57
205.2815857	2.74
215.2729187	0.31
219.1290588	2.47
220.0892944	0.19
231.2474365	0.57
233.2712402	100.00
239.0572205	0.62
241.1983032	0.73
243.3368530	0.31
249.4056702	0.88
257.1141968	5.92
258.0524292	1.42
259.2226562	47.39
259.9744263	0.44
261.2389221	5.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	461.2923
Annotation	Unknow
Peak:m/z	Relative Intensity
160.1629028	0.05
287.3946533	0.17
306.1900330	0.12
315.1900024	100.00
315.8353271	0.09
332.7370605	0.05
343.3602905	0.08
349.1341553	0.12
363.7593994	0.66
371.1895447	0.13
373.0944824	0.20
383.2743835	0.72
384.1686096	0.44
388.3550720	0.65
389.0598450	0.34
392.3312073	0.21
395.7837524	0.28
403.4842224	0.76
404.4130554	0.18
406.7570801	0.23
409.5265198	0.04
411.2674255	0.22
413.2466736	0.29
415.0851135	1.55
416.3407593	0.08
423.7929077	1.19
425.6225281	0.15
428.6148376	0.53
434.4897461	0.14
437.6097107	2.56
438.4655457	6.19
439.0867615	0.04
440.5933228	0.09
443.2873230	2.59
447.1707764	0.32
448.7749329	0.21
452.1177368	1.33
452.8500671	2.55
455.8486023	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	702.62
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0765991	0.90
231.9906616	0.19
280.7461548	0.59
282.9774170	0.92
292.5267334	0.52
294.6229248	0.43
315.6318970	0.16
351.8511963	0.27
353.9679565	0.44
363.8163452	0.35
366.5340576	1.06
376.5806885	0.65
399.7540283	0.62
448.7169189	4.40
450.6157227	16.64
452.7082520	0.13
456.0617676	0.18
457.0239868	0.45
458.2133179	0.84
461.0787964	0.55
472.0526733	0.56
488.5847778	0.61
490.4518433	0.44
498.5834961	0.13
529.5324707	0.59
532.5899658	18.15
534.5007935	100.00
535.1729126	0.42
540.0547485	0.13
542.5582886	2.83
544.4998169	6.20
555.0166016	0.41
555.9196167	0.33
558.9661255	0.73
570.3669434	0.80
572.5642090	5.15
577.8297729	0.19
582.7909546	0.33
594.4796753	0.18
608.2197266	0.76
614.7019653	0.62
616.4702759	5.64
617.9362793	28.52
618.6000366	97.55
619.2555542	0.34
626.6279907	1.74
628.2509155	1.47
630.5658569	0.75
642.5688477	0.29
655.4994507	4.70
656.6009521	18.47
657.2576294	0.19
665.8348999	1.73
666.5027466	0.59
678.6547852	1.68
679.5350952	2.77
682.1986084	0.34
686.3479614	2.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	662.2201
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0647278	0.26
192.9335938	2.71
204.8977661	0.49
205.5510712	0.42
206.2289734	0.13
233.0724182	0.78
243.7570801	0.13
246.0137024	0.13
267.9196777	0.52
289.9468384	0.41
291.1341858	0.42
298.0932007	0.19
302.4475098	0.22
308.1923828	33.82
320.2242432	0.04
337.7048950	0.40
341.2197876	0.14
350.4078979	0.11
370.8123169	2.52
371.4760742	0.14
378.3588257	0.23
386.0634766	0.14
394.9087524	0.13
413.9658813	0.06
417.2425537	0.31
433.7790527	0.27
434.6041260	0.22
452.1830444	0.27
456.8233643	0.27
458.3412476	0.59
463.3623047	0.22
470.1901855	1.38
481.2091675	0.33
482.1173096	0.42
483.2859497	0.09
500.1869507	100.00
532.7113037	0.30
544.6636963	0.28
560.1279907	0.08
589.3372192	0.28
626.1770630	0.67
633.3124390	0.75
644.1928711	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1087
Annotation	Lactulose
Peak:m/z	Relative Intensity
98.9687653	0.33
100.8770065	6.74
106.2460938	0.25
112.9355087	21.40
115.0883255	0.18
116.9895325	0.19
118.9660110	13.49
119.9120636	0.09
124.9888916	4.11
130.8484039	5.94
142.9984741	17.92
149.0255432	2.94
160.8903809	17.97
177.7247925	0.51
178.9231567	100.00
179.6094971	0.32
221.2882385	0.16
251.4270020	0.38
262.9286194	0.45
279.5604858	0.15
281.0169678	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.0701
Annotation	Swertinin
Peak:m/z	Relative Intensity
110.942688	0.15
112.9681549	0.31
132.9547119	0.14
152.9545288	0.44
171.2100067	0.90
173.9471436	0.10
175.0379028	0.98
191.1781616	0.16
192.8148956	0.13
194.8963318	0.19
197.4013367	0.17
200.9507751	0.29
227.2171631	0.20
240.0488281	0.23
242.9824829	2.31
245.9093933	0.29
253.1051025	0.18
261.2558594	0.26
266.060791	0.23
271.0699768	100.00
272.1022339	0.64
279.0035706	0.11
292.7938843	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1352
Annotation	Speranculatine A
Peak:m/z	Relative Intensity
130.0559387	0.24
131.9761353	0.19
148.1194611	0.05
159.9684753	0.12
161.0856171	0.14
163.2079468	0.03
173.0627289	15.11
174.0199432	1.40
188.1285553	0.06
195.9203186	0.06
200.2091370	0.46
201.2411804	0.03
214.2316437	0.05
228.2406616	0.04
231.0804291	0.04
232.7245331	0.02
233.5708771	0.08
239.2271423	0.03
243.2438965	0.11
244.3686218	0.08
245.3212891	0.08
257.4405518	0.06
260.9281006	0.04
264.2693481	0.04
265.0856018	0.12
266.0766602	0.04
269.1829529	0.22
269.8661499	0.07
271.2735901	0.09
272.3548889	0.13
288.4207764	0.11
289.3374023	1.01
290.3109131	0.08
290.9682922	0.02
292.1776123	19.65
293.2350464	5.02
297.4744873	0.03
299.1623230	0.12
301.3721008	0.03
317.2631226	0.02
318.7088623	0.29
325.5440063	0.12
333.3333130	0.07
335.1611938	64.97
336.1214294	100.00
337.2130127	14.84
343.2742920	0.10
353.8514709	0.14
356.0261230	0.10
379.6941833	0.16
389.3434448	0.46
390.2431030	0.19
391.1497192	0.02
405.0606995	0.05
407.2499390	4.08
408.3229675	1.16
415.2320251	0.69
416.2442932	0.57
423.3747559	0.06
428.5920105	0.04
431.3945007	0.04
433.1540222	82.03
434.2524719	16.56
435.4048157	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.119
Annotation	Oenin
Peak:m/z	Relative Intensity
145.0281982	0.10
161.1905670	0.13
162.9949951	0.17
174.8724518	0.29
181.0628204	0.11
193.2834473	0.07
203.1325684	0.22
204.1539612	0.14
229.0994720	0.14
231.1380768	0.09
241.0330811	0.31
246.0901794	0.24
247.0099792	0.08
253.1355591	0.22
259.1708679	0.13
261.4032898	0.07
273.2951050	0.05
282.9307556	0.09
293.4379272	0.09
294.4928589	0.11
297.1520996	0.24
298.3280640	0.13
299.3040161	0.25
303.1352234	0.03
305.2080078	0.11
310.1116028	0.28
311.3063354	0.88
312.0542908	0.03
313.1283569	2.69
314.1107788	7.14
315.1904297	2.17
316.0864258	0.11
316.9651489	0.04
323.1093140	0.18
327.2213745	1.21
328.2040100	9.66
329.1179199	70.69
330.2273560	4.13
338.2557983	0.04
341.0254517	0.11
342.1803589	0.14
343.2341309	4.53
348.8110352	0.09
350.0706177	0.11
351.2947388	0.50
355.9781494	0.69
357.2484131	0.91
358.2180176	0.67
362.5040894	0.06
371.2020264	2.73
372.2312012	0.28
373.1553040	0.23
383.3122253	0.10
385.7941589	0.15
395.2240295	1.03
398.4130249	0.12
401.2268372	2.00
411.4189758	0.08
415.1482849	0.04
417.5593262	0.07
420.1428528	0.26
427.0976562	0.04
430.9768372	0.25
432.4485779	0.10
444.0276184	0.22
445.2283020	1.77
446.1558838	0.04
447.3503723	0.12
448.4644470	0.08
449.3951721	0.18
453.0775757	0.70
454.2525330	0.55
455.1902771	1.13
456.1130066	0.45
458.2530823	0.13
459.2698059	0.21
460.1326599	0.13
461.2149963	1.31
462.3713074	0.26
471.6536560	0.06
473.1825867	1.36
475.0526428	0.18
476.1924133	100.00
477.2532349	11.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.1428
Annotation	Unknow
Peak:m/z	Relative Intensity
207.7663269	0.12
222.8016663	0.05
225.9312897	0.03
228.9704895	0.11
242.1576233	0.09
243.8280792	1.03
244.8283997	0.07
260.9721680	0.05
271.2297058	0.09
282.9717407	0.04
284.3828735	0.13
291.2338867	0.04
292.1575928	0.06
292.9619141	0.09
299.8110962	0.13
304.0998535	0.04
304.7991943	0.08
306.1492920	0.06
309.2554626	0.13
318.0753174	0.05
319.9685059	0.23
321.1502075	0.03
321.9226074	0.06
323.6621704	0.11
332.9580688	0.12
337.2600098	0.08
339.4541016	0.10
345.1131592	0.17
347.3781738	0.03
361.0549927	0.13
362.1931763	0.15
363.2023926	0.06
373.0807495	0.16
374.9865112	0.07
380.2875366	0.06
381.2738647	0.02
401.0297852	0.18
402.0305176	0.03
413.0844727	0.07
417.0701294	0.14
418.0820923	0.04
419.3286743	0.16
430.5230103	0.04
433.4476318	0.04
454.2578125	0.48
457.2695312	2.80
459.0699463	0.05
460.4552002	0.03
466.1650391	0.09
468.2249756	0.50
473.3120117	0.09
475.3207397	0.52
478.3807373	1.57
479.2969971	0.68
484.1026001	0.09
485.1338501	0.23
487.1122437	3.27
488.4417114	0.13
491.0771484	0.16
495.2908325	0.34
496.4494019	0.06
498.2401733	0.11
499.4669189	0.65
501.1051636	22.07
501.8508911	0.07
503.1188965	0.06
507.4868774	0.32
510.9113770	0.11
513.1813354	0.06
516.3355713	0.20
517.1566162	0.05
518.1898804	0.79
519.1978149	5.83
520.7435913	0.78
521.7648315	0.50
527.5835571	0.56
528.4138794	0.66
529.2900391	0.77
530.3641357	12.66
531.1537476	100.00
532.2688599	0.14
533.2440796	0.08
537.6813354	0.71
538.3173828	0.94
539.1201782	1.18
540.3757324	0.06
543.0541382	0.05
546.3486938	0.37
547.2833252	0.68
548.0694580	0.48
549.0194092	0.12
551.4178467	0.27
556.2597046	1.90
557.4172974	1.21
558.7045288	0.58
560.1021729	0.14
565.2680054	0.16
566.0068359	0.05
567.2279053	0.05
568.2269897	0.35
571.5656128	0.22
574.0071411	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	378.9814
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1931000	0.06
191.2478638	0.49
192.0051575	1.01
192.7879944	0.05
208.9489288	100.00
210.9938354	0.06
224.1158447	0.07
225.0924072	0.15
293.0615234	0.03
294.8611755	0.41
333.9189148	0.05
341.0510559	0.03
343.1048889	0.11
359.8907166	0.10
361.3528137	0.71
362.1018372	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
159.2145386	1.24
166.9860229	3.86
168.9696808	3.34
171.0055542	3.64
181.1930542	2.20
185.3061218	2.93
195.0800018	2.52
210.9177551	3.34
214.7643433	4.01
223.1170654	13.35
227.0620728	1.95
233.0146484	1.71
241.0555725	9.64
251.4616089	14.81
253.0849915	5.04
264.9944458	23.88
266.5866699	5.25
267.2741089	4.78
268.0027466	5.09
270.0040283	4.13
275.2546082	19.50
293.213501	100.00
310.4459839	13.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	422.19
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0923309	0.46
211.2129517	1.11
245.0668945	1.37
269.0469666	0.29
281.2090454	35.81
359.2291565	0.98
361.0421143	0.63
380.1711731	2.25
386.3960266	1.27
404.2568970	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	424.95
Annotation	Unknow
Peak:m/z	Relative Intensity
203.3960571	0.19
223.2821503	0.23
309.8826599	0.35
310.9492798	1.28
326.8569031	0.39
329.0643921	0.20
350.5134888	1.90
353.2124023	0.19
365.3263245	0.07
367.3065491	0.12
378.2906189	0.07
378.9922180	0.26
381.7901001	0.14
382.9278870	4.35
383.9339905	100.00
395.6859131	0.56
397.0325623	1.08
397.9250793	0.29
399.4836426	0.23
400.4508972	1.68
401.1770325	11.92
401.8412781	6.42
406.9621277	1.36
408.2419434	0.45
412.2016296	0.22
427.5584106	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1251
Annotation	b-D-Glucuronopyranosyl-(1->3)-a-D-galacturonopyranosyl-(1->2)-L-rhamnose
Peak:m/z	Relative Intensity
154.7685699	0.11
160.9954224	0.07
171.1106873	1.38
172.0299683	3.86
173.0323792	5.24
175.3623199	0.11
178.9735718	1.32
218.1637268	0.05
219.0801849	0.05
244.9598083	0.02
259.2987061	0.03
281.1338501	0.09
293.1809998	0.03
294.0692749	0.03
298.9545288	0.16
311.0892334	0.02
321.1981201	0.04
330.2219238	0.05
335.3619385	0.44
341.1580200	100.00
342.2470093	0.35
343.1952515	0.14
351.9920044	0.08
353.0192871	0.12
368.7460938	0.05
378.2041016	0.26
379.0097046	0.16
381.9597168	0.05
384.1235352	0.05
385.3104248	0.03
395.0067749	0.05
409.1251221	0.08
424.1873779	0.07
443.6843872	0.07
451.5015259	0.15
452.4937744	0.03
454.2850342	0.08
455.1977539	0.13
468.6744995	0.11
469.3200073	0.53
470.0351562	0.21
471.1737061	0.53
472.3563843	0.03
478.7048950	0.07
479.4375610	0.13
496.7039185	0.16
497.4917603	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0785
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
86.9976196	0.01
130.9739075	0.02
139.9884491	1.45
145.0797729	1.83
158.1195831	0.12
167.0507812	0.07
169.1325836	0.01
196.0467377	5.15
211.3923187	0.11
213.0382538	100.00
214.0559540	1.05
215.0433197	0.11
218.0278778	0.01
230.9622650	16.95
233.1497345	0.05
240.9989777	0.11
242.2518768	0.06
259.1499023	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	592.3333
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9354248	0.23
184.9005432	0.05
227.3505249	0.04
240.9868164	0.09
261.8706665	0.06
307.3415527	0.13
311.2529907	0.08
312.2886047	0.34
314.4096680	4.01
315.3614502	1.33
316.4100342	0.13
339.7752686	0.23
369.3526001	0.18
377.1835327	0.06
385.8879395	0.04
389.1172485	0.12
413.2745972	0.14
430.6780396	0.08
431.3494263	0.06
459.3355713	0.29
460.5002441	0.05
467.2461548	0.11
468.6771851	0.11
470.7009888	0.07
476.4002686	9.40
477.3999023	100.00
478.4303589	24.18
498.2808228	0.18
509.1062622	0.55
525.9759521	0.15
527.0049438	0.27
530.3473511	0.41
532.6239014	0.59
533.6225586	0.14
546.9629517	0.46
548.5068970	4.82
549.4240723	0.91
550.1362305	0.19
555.2573853	0.28
556.8228149	0.18
557.6232300	0.08
574.3412476	8.74
575.4641724	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	658.2535
Annotation	Unknow
Peak:m/z	Relative Intensity
280.2107544	0.83
298.3787231	1.64
316.1599121	100.00
316.7631226	0.27
325.1642456	0.12
478.2521973	0.14
498.0513916	0.25
510.2033691	0.36
519.0194702	0.25
525.2844849	0.26
560.1610107	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9363785	0.39
86.9893494	0.91
110.8697968	100.00
111.6714630	0.02
128.8977966	2.10
130.9087982	1.01
147.1448212	0.09
154.9038544	0.36
171.6221771	0.05
172.9440765	21.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	546.3625
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
160.9062195	0.25
173.1366882	2.71
177.2098694	2.10
182.3143616	0.68
184.0865784	0.35
187.0774841	0.38
195.1010437	0.41
205.0933380	0.42
215.2348633	0.43
221.4018097	0.89
231.0876465	0.20
233.3568726	1.02
243.2192078	15.96
261.2972412	19.98
263.0275574	1.64
265.4261169	2.70
279.1079712	0.90
287.3255005	0.91
293.3651733	0.64
295.2913208	0.36
317.4460449	0.98
335.3479004	41.54
353.3046265	100.00
399.2540283	0.22
405.1466064	0.70
441.3630981	1.15
461.1040039	1.52
462.3490601	0.85
467.6579590	0.51
479.4113770	2.64
488.1069946	0.83
493.2160645	3.04
493.9005127	2.02
496.8323364	0.64
497.4700317	12.21
511.1640625	14.90
511.8179932	0.40
514.7343140	0.44
518.3724365	0.41
527.5390015	1.50
528.3279419	2.77
529.1616821	3.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1332
Annotation	Bequinostatin D
Peak:m/z	Relative Intensity
126.8005981	0.08
128.0283508	11.16
134.9898987	0.23
153.0814819	2.22
158.9214478	0.23
166.9449158	0.22
170.9886627	0.70
179.0478210	1.31
212.8999176	0.54
215.1379547	1.37
217.1194153	0.21
231.1633911	4.38
237.0810242	0.63
243.0591736	0.22
247.8867798	0.34
249.0214233	100.00
260.2441101	0.28
274.8141785	0.34
278.1728210	0.98
278.9884949	0.72
283.2504272	0.35
307.3955688	0.15
311.6881714	0.47
313.4193726	0.30
319.4118958	0.32
321.2561951	0.27
325.2454834	0.13
328.8595581	0.10
336.7729187	0.07
339.2104492	0.17
342.7150574	0.63
345.0012207	0.15
351.4316406	0.12
361.3386536	0.51
366.9089661	0.22
368.8297424	0.42
381.1734009	0.27
382.8413086	0.22
383.7301331	0.41
386.0662537	0.38
394.3830261	1.00
395.0475159	1.44
396.0216064	0.21
397.3765564	0.15
403.4541626	0.29
404.3897400	0.19
405.1802368	0.69
406.2200012	0.13
408.5307312	0.18
410.5492859	0.08
418.5298767	0.08
421.0432434	0.27
422.0643311	0.05
423.1516418	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	871.38
Annotation	Unknow
Peak:m/z	Relative Intensity
247.9812469	0.09
249.1255646	0.05
250.0469360	0.06
250.8229980	0.17
257.9648438	0.13
259.3609009	0.21
260.1158447	0.07
265.0681763	0.22
265.7650146	0.09
274.9671631	0.10
277.3690186	0.18
288.1231079	0.13
289.1391296	0.13
304.5921631	0.14
305.2531128	0.21
316.1020203	0.14
319.3306885	0.14
320.1466980	0.19
323.2108154	0.42
324.3072205	0.64
325.2981873	0.14
337.1727295	0.68
338.1153564	0.38
355.2365112	0.03
356.2053833	0.43
363.1005859	0.06
369.1818542	0.03
380.2816162	0.06
383.9408569	0.06
388.0835876	0.21
391.2603760	0.04
396.5250854	0.10
423.3187866	0.06
435.2763672	0.03
441.2651367	0.28
441.9566650	0.12
463.1632080	0.08
472.0050049	0.06
481.3499146	1.00
482.2891846	0.76
483.1726685	0.30
485.3064575	0.47
486.3649292	0.44
487.2952271	0.35
495.1182861	0.17
496.0515747	0.04
497.3044434	0.13
499.2552490	7.90
500.2286377	6.61
501.3570557	2.74
507.5459595	0.21
513.3369751	1.83
514.2716064	1.50
515.2222900	0.86
517.2902832	3.17
518.2576294	6.32
519.3235474	2.96
527.3921509	0.12
528.1099243	0.04
531.2965088	0.09
532.3185425	0.09
573.1492920	0.08
600.9574585	0.04
603.2588501	0.18
604.0493774	0.02
605.2919312	0.03
614.4269409	0.08
661.1976929	1.09
662.2654419	3.73
663.3229370	1.42
675.3257446	18.33
676.2479248	45.75
677.2509155	23.43
677.8788452	0.46
680.2599487	0.51
681.3862305	0.20
689.3883667	0.18
690.3832397	0.75
691.4674683	0.60
693.2987671	33.22
694.2450562	100.00
695.2208252	49.07
695.9253540	0.08
707.1451416	1.49
708.1896973	1.90
709.2587280	1.27
721.8453979	0.08
724.3923950	0.12
733.2572632	0.03
734.2234497	0.07
754.6380005	0.06
755.4744873	0.06
810.5484009	0.03
852.5739746	0.11
853.3917847	0.03
855.4578857	0.60
856.3919678	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.13
Annotation	Unknow
Peak:m/z	Relative Intensity
124.8938675	0.68
160.1338501	0.21
166.1753235	0.16
201.8899536	0.29
228.6345215	0.36
240.9519043	0.42
257.8207092	0.85
276.1207886	1.02
307.4927368	0.44
318.8137512	0.42
344.3140259	0.33
345.3787231	0.51
370.1576233	0.16
371.1032410	0.63
388.1885071	100.00
395.2929993	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.117
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
110.9384003	0.34
112.9425201	0.07
116.6127319	0.21
118.8717117	0.15
122.9694824	0.92
133.0796509	0.65
137.0671844	0.16
140.8684692	0.17
150.9699249	1.92
152.9740448	4.74
155.0625610	10.40
158.6972504	0.12
159.9653168	0.68
160.9950562	2.94
162.0282288	0.51
168.9239502	1.62
170.9104309	1.11
178.9344788	0.46
186.8315125	0.09
188.9113922	0.73
193.0036621	12.58
194.0218811	1.08
196.8953400	7.99
202.6558838	0.43
204.1799316	0.64
210.6365204	0.52
215.0131531	100.00
224.1615906	0.11
225.4386902	0.46
228.0080872	0.25
228.9028931	0.20
233.2588806	0.61
234.9911499	1.14
239.0346985	0.56
240.8658447	0.18
248.3366699	0.09
253.2404175	0.18
257.3685303	0.37
270.7795105	0.27
273.1058350	0.55
275.4774780	0.18
276.7901306	1.60
280.0556335	2.19
281.1334839	0.49
282.9893799	0.25
284.2612915	0.11
289.3099670	0.13
292.3398438	0.29
293.2014465	1.00
303.4166870	0.24
304.9073486	0.33
309.2119751	1.30
312.2200012	0.22
322.7573242	1.37
324.2243958	0.43
325.2038269	0.35
327.1435242	3.55
329.2219543	0.96
330.1449585	0.44
332.2773438	0.20
333.1462402	2.04
334.1823120	0.91
336.5676880	0.63
337.2157898	0.68
339.2976379	0.59
340.3325195	0.20
341.0402832	0.67
341.9963989	0.45
345.2301636	0.23
349.2961731	0.25
351.1877747	7.42
352.3226624	2.88
359.9048157	0.67
368.4155579	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1054.6117
Annotation	Unknow
Peak:m/z	Relative Intensity
303.6776733	0.27
317.6491089	0.28
336.2833557	0.32
343.0162048	0.13
437.2146912	0.36
453.2247925	0.62
498.3663330	0.91
501.5845642	0.24
508.2840271	1.31
518.5365601	0.83
532.1926270	1.84
533.2783813	1.09
537.5822754	30.80
538.5417480	1.32
556.3862305	1.68
630.1196289	0.96
636.3292236	0.28
637.4133301	0.76
650.4040527	0.57
680.3668823	1.29
749.6124268	0.16
795.7288818	4.44
796.3398438	100.00
797.0474854	21.09
835.5128174	1.68
836.7678223	0.35
887.8017578	1.83
888.6363525	0.87
892.0499268	0.16
913.1608887	1.24
916.6176758	0.51
965.6708984	0.18
970.0059814	2.88
970.8864746	0.37
971.5301514	2.75
972.5081787	1.62
984.1350098	0.83
1002.0632320	1.24
1014.4211430	0.23
1060.1230470	1.44
1061.5789790	0.51
1073.2244870	0.51
1074.9244380	0.37
1091.0823970	1.13
1152.9328610	0.18
1153.7543950	0.20
1154.6926270	1.31
1168.8449710	0.28
1198.1904300	0.69
1198.8496090	0.93
1256.8660890	1.72
1487.7587890	14.59
1488.7072750	15.69
1489.6333010	6.04
1490.7484130	0.66
1531.6324460	1.72
1532.4661870	0.89
1533.4593510	0.21
1554.9827880	0.85
1576.6994630	3.19
1577.7294920	15.16
1578.9552000	4.78
1591.4332280	0.88
1670.4801030	0.23
1671.7380370	2.54
1673.3098140	1.61
1715.0555420	1.67
1717.1286620	1.32
1736.6810300	0.24
1744.7532960	0.32
1768.7834470	1.27
1793.3116460	0.46
1803.3670650	0.74
1804.8507080	1.19
1809.1817630	3.21
1816.3382570	0.12
1817.4676510	0.67
1826.6521000	0.19
1845.9382320	0.18
1850.1021730	0.28
1852.0388180	0.24
1865.3807370	0.21
1867.7955320	0.35
1872.0935060	0.50
1878.1604000	0.13
1879.2741700	0.32
1885.2274170	0.17
1886.1319580	4.28
1894.6643070	0.18
1899.2791750	6.08
1901.1423340	0.31
1904.1844480	4.66
1905.7844240	1.56
1906.5423580	0.85
1907.5505370	1.18
1914.3907470	0.63
1920.5858150	0.53
1921.5279540	16.42
1922.9592290	0.14
1925.3664550	0.16
1929.4885250	0.29
1930.3747560	0.13
1931.7606200	24.48
1934.3819580	52.01
1936.3430180	2.79
1937.4747310	0.26
1945.8806150	0.18
1947.5462650	0.36
1954.4605710	0.17
1956.2615970	1.97
1958.5059810	0.27
1959.2342530	0.35
1960.3258060	1.07
1961.4060060	0.56
1962.2781980	1.10
1963.9996340	0.14
1968.2056880	1.16
1972.2604980	1.97
1975.5885010	0.12
1980.7264400	4.35
1982.6239010	0.39
1985.4796140	2.21
1987.3000490	7.26
1989.2971190	0.14
1990.8762210	10.44
1991.9060060	0.63
1994.4460450	38.92
1995.5052490	3.30
1997.3885500	20.25
1998.9660640	9.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	970.5174
Annotation	Unknow
Peak:m/z	Relative Intensity
328.2574158	0.45
357.9061890	0.38
385.9304810	0.65
1231.4228520	0.59
1425.5811770	0.27
1447.1683350	0.85
1464.7762450	0.93
1479.4941410	0.23
1595.8966060	0.23
1610.9554440	0.23
1618.5578610	0.17
1648.1115720	0.27
1680.9719240	0.34
1701.9381100	0.61
1717.7864990	0.44
1724.0289310	0.16
1731.2928470	0.31
1742.7902830	0.60
1760.9654540	0.14
1773.1311040	0.59
1776.1453860	0.28
1798.3229980	5.13
1801.5051270	0.64
1802.1717530	0.31
1805.8854980	1.35
1814.0992430	12.70
1819.3548580	0.62
1841.4771730	4.28
1854.4763180	0.27
1859.5184330	0.36
1861.1871340	0.61
1864.1099850	1.32
1864.8884280	1.61
1867.6378170	100.00
1869.1384280	1.86
1871.4678960	1.45
1875.7071530	0.49
1886.6407470	0.63
1892.1687010	0.67
1896.0765380	0.20
1899.6239010	6.11
1902.2884520	1.22
1906.3326420	0.14
1909.7725830	1.22
1911.7237550	0.66
1914.4241940	0.67
1915.2537840	0.32
1916.5012210	4.98
1917.8381350	0.16
1919.0955810	6.48
1920.5954590	0.61
1922.1644290	0.57
1922.7926030	0.84
1924.0013430	13.51
1926.5003660	0.25
1927.7559810	0.87
1930.8679200	0.64
1932.3577880	5.62
1935.0643310	1.34
1936.3889160	2.49
1938.4378660	0.46
1939.7912600	2.08
1941.4632570	4.05
1942.5715330	4.06
1945.8615720	0.48
1946.8519290	3.01
1947.6188960	0.21
1950.6195070	7.61
1951.6893310	1.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2417
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
92.75251007	0.29
94.89431763	0.26
96.99177551	0.73
107.0121918	0.27
109.2527771	0.31
110.8750916	0.48
112.8991089	0.96
118.8974228	1.30
120.821167	0.13
123.9342651	0.64
124.9259415	0.27
131.0160217	0.41
135.052887	0.31
138.9942322	5.79
141.1435547	1.11
153.0796356	3.03
155.099411	0.66
156.8999634	0.18
161.1433563	1.36
167.1724854	1.01
168.6711121	0.70
170.3639679	1.06
173.1773224	0.74
174.8903046	0.13
179.2004852	0.61
183.0945129	0.42
184.1764832	0.40
185.3402557	0.16
189.0941162	0.35
191.2998962	0.41
197.0438232	2.20
201.3852844	0.34
203.2785645	0.27
209.293457	0.76
211.0725403	6.01
219.1882935	0.82
221.2939453	0.87
223.144928	0.42
225.1767883	0.87
227.3917236	0.16
228.8364563	1.11
233.1427612	0.26
237.1146545	1.93
239.0318909	6.01
243.4275513	0.32
253.3989563	2.94
255.2019043	2.88
257.1558228	0.32
261.3034058	1.75
277.2250977	0.42
279.2289429	100.00
282.4948425	0.16
297.2712097	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.3624
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
165.1059875	1.08
175.1032562	0.66
203.4894104	0.59
209.2061768	0.20
245.0045013	3.58
245.6590576	1.19
251.1632385	0.49
253.0847626	0.55
263.0943604	6.46
265.4857178	1.51
281.2620239	0.29
283.4652710	1.11
305.2868652	1.34
307.4109497	1.15
309.2908936	0.59
311.2490845	0.49
312.1889648	1.01
324.7576904	0.40
325.5526123	0.22
337.2269287	16.48
343.0410156	0.19
346.1329346	0.17
353.4620972	1.33
355.1605225	100.00
357.6295166	0.15
371.2666626	3.56
389.4620972	6.70
390.8024902	0.80
393.1277466	0.57
407.2889404	17.03
425.1246948	22.11
425.7608643	0.17
427.4503784	0.52
463.5076904	0.46
466.9846191	0.78
498.7555542	4.30
499.3704224	27.40
500.7999268	0.46
503.2008667	1.44
505.7796021	0.27
506.6474609	0.45
516.2409058	10.82
516.9833374	34.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3389
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0671844	0.54
184.0771637	76.15
198.8326416	0.23
257.9852295	0.45
322.0902100	0.12
337.3336792	0.13
502.4360962	100.00
503.0968628	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	468.1442
Annotation	Unknow
Peak:m/z	Relative Intensity
134.9705505	0.07
142.9848022	0.96
145.9936829	0.18
149.0707092	0.05
159.9932251	0.98
166.9236603	0.08
170.0952454	0.03
171.2224121	0.17
176.9840088	1.40
179.0686035	2.34
183.1127625	0.06
185.1666870	0.05
192.1609192	0.06
197.1518402	0.15
210.1512299	1.96
213.0901642	0.03
226.2511444	0.04
228.0491333	0.29
231.1606598	0.05
235.9919128	0.07
237.1555328	0.03
242.2847595	0.08
254.1634827	8.93
272.1217346	11.45
288.1737366	13.45
306.0717163	100.00
306.6718750	0.15
320.2526550	0.04
338.9736328	0.09
339.6157227	0.02
390.1310425	0.10
393.2671204	0.06
409.2612305	0.03
449.9188538	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.03
Annotation	Unknow
Peak:m/z	Relative Intensity
166.7422638	0.21
170.8328552	0.12
238.1669312	0.10
241.9399109	100.00
247.2365112	0.11
259.2233887	0.83
259.8250427	15.66
262.1575623	0.35
264.8723755	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	675.35
Annotation	Unknow
Peak:m/z	Relative Intensity
310.1116333	0.89
312.3218994	0.88
495.6085205	0.63
513.4656982	100.00
514.4907837	12.77
659.7034912	2.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2104
Annotation	10-OPDA
Peak:m/z	Relative Intensity
85.2193146	0.06
91.8973694	0.13
92.9758148	0.10
96.8077545	0.23
105.0132446	0.25
106.8272781	0.20
121.1811371	0.46
123.0241165	0.25
131.1416931	0.21
133.0022278	0.42
135.1688232	0.12
136.9884949	0.33
141.0316772	0.26
141.8747711	0.08
143.2815857	0.06
144.8448792	0.10
147.2185059	0.26
149.0745544	0.50
151.0300598	1.13
151.9034424	0.37
155.0226593	0.40
157.2443848	0.63
161.0505371	1.11
163.2393188	0.81
164.3270416	0.54
165.0370331	0.07
166.2797699	0.23
167.2934875	0.46
171.2216492	0.13
172.9925537	0.90
175.0730286	0.37
176.7585297	0.59
178.9668427	0.20
182.9645233	0.34
187.1503601	0.51
189.2897491	0.20
191.0142822	0.22
195.2630157	0.17
197.3142548	0.10
198.9593811	0.28
201.1858826	0.29
204.7470703	0.23
205.3499451	0.43
207.2210999	0.34
211.1396484	0.35
213.3186951	0.44
214.9750977	0.16
215.9409485	0.98
217.2764893	0.64
219.3015747	0.31
223.1802368	0.35
229.2444458	0.24
233.2123108	1.22
235.1748962	1.71
237.1405029	1.24
238.1300964	0.29
239.2939148	1.65
248.7648010	0.20
250.7814941	0.49
251.4350891	2.35
257.2792358	7.00
261.0355835	0.55
265.0966797	0.85
275.1593018	100.00
275.8417969	0.97
294.5191650	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	660.207
Annotation	Unknow
Peak:m/z	Relative Intensity
185.0950165	0.13
187.2222290	0.22
191.0310822	0.12
192.2017975	0.83
193.2017517	0.35
196.5580750	0.13
197.2393036	0.70
200.8771973	0.08
210.1329193	6.14
211.1680603	0.55
211.9006042	0.09
213.0156250	0.26
224.1648254	0.26
225.2176666	0.60
226.1510010	0.09
228.4279480	0.79
236.1575928	1.11
242.1272430	0.41
244.1351318	0.14
245.2376099	0.15
254.0822296	47.08
255.1260376	6.34
258.9603271	0.06
262.0525513	0.04
266.9067078	0.15
270.2009277	1.02
271.1817627	0.73
272.1956787	63.34
273.1500244	6.71
275.7804565	0.20
278.9002075	0.58
286.3619995	0.08
288.1023560	45.26
289.2071838	4.84
294.4556885	0.05
295.9031372	0.24
302.0880127	0.65
304.1569214	0.07
306.1544800	63.64
307.1459351	6.92
311.8303833	0.40
313.2942810	0.25
319.2369995	0.29
320.1719055	3.41
321.2225647	0.59
330.2412720	1.98
331.1507568	0.12
336.9345703	0.08
338.9403076	0.45
340.0223999	0.06
347.8105469	0.93
348.4119873	1.72
349.3034668	0.29
350.3045044	0.05
356.3245239	0.13
360.2907104	0.05
361.8375854	0.18
369.0715332	5.64
370.1552124	1.39
371.8615723	0.17
373.2554321	0.37
374.2929077	0.88
377.2163696	0.04
377.9732056	0.23
379.0583496	0.07
387.1383667	1.09
388.4904785	0.20
389.3090210	0.04
390.1473389	1.90
404.5172119	0.21
405.2886963	0.57
406.3584595	0.04
408.3590088	0.50
410.9157104	0.18
417.0889893	0.17
423.3249512	0.32
424.1331787	0.65
432.3579712	0.11
434.2329712	0.28
439.4426270	0.65
448.2080688	0.27
450.0466919	0.56
462.4885254	0.04
466.2205200	1.09
468.1472168	4.73
469.2501221	1.41
470.7141113	0.11
473.0153198	0.05
474.2641602	1.16
475.1930542	0.08
480.0430908	12.19
481.0958862	2.92
484.1915894	0.07
498.1293335	100.00
499.1897583	23.70
499.8544922	0.16
505.1392212	0.07
521.6584473	0.06
531.1853638	25.45
532.3056030	5.50
540.2409668	1.25
541.2255249	0.23
567.1780396	1.55
568.2182007	0.45
570.0288696	0.18
571.2907715	0.08
580.0805054	0.05
581.6550903	0.08
585.2520752	0.74
586.2960205	0.53
600.0676270	1.06
610.5095825	0.06
616.1057739	0.31
628.3135986	0.85
629.6552124	0.15
642.2000732	89.77
643.2102661	27.36
643.8942261	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1502
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
159.0178528	0.06
162.6059418	0.11
170.7752380	0.08
184.5903931	0.09
190.7852173	0.26
195.2025299	0.13
200.1925964	0.20
251.0661011	0.08
253.2014160	0.15
283.9954834	0.11
285.1297913	0.09
290.0946960	0.13
299.1177368	0.13
309.6146851	0.14
312.3051147	0.09
329.2413025	0.16
342.2293701	0.11
353.9925232	0.10
355.3286438	0.18
361.1433105	0.10
380.9990234	0.05
383.4194031	0.20
385.5025330	0.26
389.1942444	0.49
391.2267761	0.07
401.2608337	100.00
402.4239807	0.33
403.3050232	0.63
405.7221985	0.07
406.5632324	0.23
412.0832825	0.22
418.2872009	0.18
428.2257080	0.24
429.3650208	0.13
430.1876221	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
122.9737091	0.05
135.9855194	18.59
146.8572235	0.04
164.9979706	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.2303
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0335083	0.33
224.8313293	0.16
308.4429321	0.13
344.0566406	0.05
352.8016357	0.14
355.2160645	0.20
365.3120117	0.16
368.6821899	0.75
369.3569336	1.74
370.8496704	2.71
376.2491455	0.21
391.5709229	0.08
396.0639038	0.13
399.0281982	0.46
406.2754517	0.36
418.1140747	0.23
425.4013062	0.16
441.1631470	0.56
453.9985352	0.09
455.2733154	0.26
477.2449951	0.35
493.4461670	0.39
500.3740234	0.37
505.1766968	0.56
507.2154541	0.31
522.2742310	100.00
545.1234741	0.66
558.2210083	0.62
569.0617676	0.10
575.2167969	0.26
576.3228149	0.66
614.8311157	0.11
621.5042114	0.09
624.0119629	0.75
633.2839966	30.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.1593
Annotation	Neocalyxin A
Peak:m/z	Relative Intensity
140.1011658	0.69
145.2343292	0.20
158.9668274	2.04
165.9124756	0.05
166.9749756	0.04
168.9262085	0.04
170.0883026	0.04
184.9725037	0.04
196.0355377	1.37
209.2333221	0.02
211.1654053	0.15
213.0812378	10.31
214.1915131	0.19
231.1118317	1.71
244.9969025	0.16
256.8767700	0.07
259.1242371	100.00
272.9998779	0.68
291.3264160	0.04
322.5613098	0.08
323.3050537	0.02
325.9593201	0.03
326.7255249	0.03
359.2882385	7.43
365.0873413	0.11
383.0523071	0.02
390.4647827	0.15
400.6182861	0.12
401.5167542	0.05
412.7595215	0.02
426.2270203	0.32
427.1388245	3.70
429.0254211	0.02
431.3716736	0.09
455.3356628	0.14
473.1417542	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.3014
Annotation	Unknow
Peak:m/z	Relative Intensity
144.1315765	0.09
149.1138306	0.18
157.0949097	0.19
161.1274109	0.18
162.7543335	0.20
171.2294617	0.34
172.3886414	0.11
187.1816406	0.42
199.2111969	0.08
203.1239777	0.05
209.1830139	0.13
210.6347809	0.15
223.3175659	0.44
237.0579224	0.30
241.1344604	0.79
255.3733826	0.09
259.9697571	0.03
261.3168945	0.07
273.3293152	0.45
291.4109192	0.44
293.4054260	0.17
295.3936157	1.80
297.5616760	0.21
300.9430542	0.12
307.2822876	0.16
309.2682800	0.38
311.3305054	1.05
313.2852478	40.36
314.3802795	1.80
315.1101685	0.05
324.3410950	0.36
327.2621460	0.09
329.3681641	2.72
331.2736206	100.00
332.3856812	3.81
339.5520020	0.17
341.4776001	0.16
343.2897339	1.19
345.3237610	2.78
346.3376770	0.15
351.0955811	0.37
353.4213867	0.16
355.3080139	3.54
356.4398804	0.25
357.4126587	0.14
362.9872131	0.12
365.5168457	0.11
367.6268921	0.39
371.3405762	0.83
372.2480469	0.17
373.2890930	0.86
377.0786133	0.10
385.2626953	0.36
397.3965454	0.24
398.2707520	0.25
403.4163513	0.24
408.3544006	0.11
411.4665527	0.32
415.7214355	0.14
418.9383850	0.12
420.3632507	0.04
425.3675842	0.65
433.0392761	0.13
435.4632874	0.13
436.9501038	0.08
439.2472839	0.07
445.4198608	0.15
447.3001404	6.94
448.4562378	0.08
449.1954651	0.46
451.3838806	0.93
455.2195740	0.58
456.5881042	0.77
457.2492981	1.07
458.2301025	0.44
462.9761353	0.14
464.2612610	0.34
473.0415344	0.22
474.4256287	0.95
475.4352112	16.08
476.5005493	0.85
493.1069031	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.04
Annotation	Unknow
Peak:m/z	Relative Intensity
109.8560333	100.00
127.8722839	7.67
130.4167938	4.51
139.2931061	3.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.88
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1313629	0.09
229.1589661	0.13
230.8316040	0.09
272.9721375	10.60
274.0301208	4.17
274.9375610	4.28
275.9098816	0.61
386.8709717	5.92
387.9988403	6.33
389.0076294	9.57
390.0244141	2.02
500.8959351	22.91
502.0480347	33.07
502.9198608	52.55
503.8625488	19.17
505.1069946	0.27
505.7249146	0.09
514.7817383	0.08
518.6519775	0.13
561.3118896	0.05
585.9328613	0.07
611.9345093	0.34
612.7642822	0.08
614.8464966	16.32
616.0335693	30.88
616.8845825	100.00
617.9376221	45.42
619.1419067	0.16
628.4456787	0.27
629.1174316	0.16
640.7428589	0.08
656.8595581	1.76
658.0628052	0.81
674.8132324	0.37
676.5347290	0.27
677.3131104	0.16
684.8906860	0.91
686.0518188	0.87
687.8614502	0.33
700.6790771	0.19
704.0296021	0.20
708.0068970	0.34
712.7407837	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	815.2242
Annotation	Syringetin 3-rutinoside-7-glucoside
Peak:m/z	Relative Intensity
230.9726410	0.30
240.9619751	0.24
243.2125397	1.05
255.1972351	0.21
257.0864258	0.08
259.0715332	1.54
260.1229858	0.08
269.1439209	0.31
271.0268250	1.13
271.9587097	0.46
277.2937622	0.05
284.0476685	0.07
285.1172180	0.33
287.1177368	6.53
288.2269592	0.40
290.3280945	0.06
295.1461182	0.10
297.1266785	0.35
298.9978027	0.16
300.1440125	0.24
301.0909729	0.30
302.1665649	0.69
313.3577271	0.10
315.0568848	16.75
316.0825806	3.48
317.8897095	0.14
329.1505737	0.85
330.1315308	13.40
331.2005615	2.71
332.1166992	0.25
337.2234497	0.08
343.2590942	0.31
345.1256409	100.00
346.2169800	16.30
347.2861938	0.08
359.2182617	0.05
387.1943970	0.33
449.1997070	0.32
457.1732788	0.06
491.3309326	0.59
493.1383057	0.11
511.3173218	0.09
520.3737793	0.27
535.1149292	0.23
543.9115601	0.14
578.0894775	0.07
607.4461060	0.20
624.2835083	0.09
626.0885620	0.08
639.1110229	0.10
650.2723999	0.11
653.2959595	2.43
654.3739624	0.31
655.5618286	0.09
661.1023560	0.06
693.3197632	0.20
694.3397827	0.15
703.9352417	0.27
735.3173828	0.15
747.1706543	0.11
753.4130249	0.36
756.4383545	0.97
783.3006592	0.62
787.1664429	0.38
800.1762085	0.82
801.4895630	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8598404	1.69
175.0545502	0.04
206.7407227	100.00
252.9885864	0.12
272.8295593	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1084
Annotation	2,4,6,4'-Tetrahydroxy-2-benzylcoumaranone 6-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
132.7249908	0.06
148.9645386	0.29
151.2067566	0.01
152.0144806	0.08
152.9962921	0.08
162.9486694	0.11
166.8894806	0.08
173.3210754	0.09
175.21698	0.04
179.0198669	0.26
179.9315796	0.15
191.1022949	0.18
199.0065155	0.11
201.1669312	0.30
204.9056244	0.02
215.2089539	0.11
219.0233765	0.12
225.204071	0.08
233.1661377	0.02
243.0687561	1.93
251.033844	0.12
259.1347046	34.43
267.0562439	0.13
269.125946	34.21
283.2667236	0.48
287.0557556	100.00
287.6700134	0.15
292.9750977	0.21
311.1677856	1.86
313.2937622	0.12
315.1426086	0.14
325.2553406	0.06
329.1106873	0.33
341.1102905	0.51
342.1535034	0.67
352.1811523	0.09
353.1407471	0.30
385.3765564	0.06
403.0912781	0.15
405.0779114	0.28
421.0954895	1.26
431.1719666	5.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	488.1837
Annotation	Unknow
Peak:m/z	Relative Intensity
156.5468597	0.17
325.1448364	0.06
326.1919250	0.13
333.1527405	100.00
333.7700195	0.43
341.1754150	0.24
342.2158813	0.34
351.9664612	0.03
390.1670837	0.50
398.3942566	0.04
407.2954102	0.44
409.7978821	0.17
421.9798889	0.15
441.0081787	0.10
443.9567871	0.16
470.4483032	0.03
471.2993469	0.05
480.1705933	0.22
488.0672913	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.0741
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
175.1553650	0.10
176.8925781	0.51
186.0571289	0.07
199.1487579	0.11
211.0929108	1.01
212.0524750	0.16
213.2917938	0.15
216.9640503	0.05
222.0418701	0.66
233.1694641	0.08
240.0490417	0.32
241.1320801	0.54
241.7436371	0.03
242.7278442	0.15
243.3422852	0.06
246.1521149	0.97
255.2274323	0.26
257.0103760	0.04
259.2943726	0.06
261.0042114	2.01
262.2098694	0.32
264.1174927	1.17
273.0259705	15.58
276.9882507	0.07
279.9633179	0.10
282.0515747	35.79
291.0305786	0.72
294.8722229	0.17
300.0374756	5.61
305.0808105	5.96
313.0410767	0.12
318.6257324	0.21
319.8959045	0.08
323.1093750	31.24
324.1129150	1.92
325.0701294	3.85
325.6859436	0.09
329.0553589	0.10
330.9409180	0.11
334.1743164	0.04
344.1336670	2.29
348.9241943	0.11
359.0426636	0.18
360.0903931	0.04
360.9397583	0.30
362.0771484	22.15
363.2883301	0.06
364.2121582	0.12
370.0465088	0.08
371.8485107	0.09
374.2399292	0.28
378.0640259	0.04
379.0331421	1.38
380.1459961	0.50
381.9097900	0.07
385.0624390	100.00
385.6768188	0.19
396.3215332	0.11
399.8383789	0.05
403.0602417	55.65
404.0943604	0.04
406.6701050	0.09
411.2041626	0.41
413.2666626	0.07
419.4169922	0.09
421.0945435	0.07
423.8824463	0.14
425.0526733	0.26
425.9463501	0.10
426.9817505	0.55
429.3562622	0.11
431.1187134	1.33
432.0748291	0.24
433.0621338	0.09
441.1901245	0.88
442.1021729	1.20
443.0295410	4.39
444.1317139	0.22
446.6159058	0.20
447.4165039	0.05
449.3013916	1.30
450.1637573	9.22
451.2235718	13.72
459.0006714	0.22
464.8521118	0.07
470.3913574	0.08
471.1965332	0.06
472.1229858	0.98
472.9576416	0.61
483.1140137	0.64
485.1544189	3.88
486.0122681	0.32
490.0101318	0.09
493.3129272	0.82
494.1132812	2.40
504.8028564	0.08
506.0662231	0.07
508.2416992	6.10
513.4983521	0.06
514.8550415	0.03
516.4086304	0.89
526.1255493	0.73
543.9846802	0.08
559.0160522	1.01
560.0464478	0.13
561.1167603	0.06
562.1130981	8.70
563.2241821	3.13
564.1926270	0.27
587.0922241	3.90
587.9583740	0.16
588.8251343	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.1366
Annotation	Eupalinilide A
Peak:m/z	Relative Intensity
121.9539566	0.38
130.0744629	0.12
130.9460602	0.62
148.1028595	0.03
162.9667969	3.68
163.5985565	0.02
183.9783630	0.01
187.9381561	0.16
197.2314453	0.02
201.8199615	0.03
233.0787048	0.13
234.1459045	0.71
238.0824280	0.01
251.0495300	100.00
252.1511230	0.02
255.0364075	0.05
262.9640503	0.02
277.3404846	0.02
283.9851685	0.93
292.2245789	0.02
297.5015259	0.08
301.3744202	0.11
307.3399963	0.05
311.4105225	0.05
314.4585571	0.01
318.3030701	0.03
336.9847412	0.01
358.4530945	0.02
362.4042053	0.02
365.2649841	0.02
367.1044922	0.02
369.7794800	0.03
376.4129639	0.05
380.9980164	0.04
385.6200867	0.04
394.2861938	0.35
395.1940308	0.26
396.1554565	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.0681
Annotation	Unknow
Peak:m/z	Relative Intensity
129.2589569	0.01
136.9136200	0.18
139.2814941	0.04
142.9908752	0.01
151.1852264	0.01
154.0494843	0.01
158.8575134	0.09
168.9842834	0.02
173.2943726	0.01
176.8351135	0.02
181.1433868	0.01
191.9919128	0.06
194.0478516	0.05
196.9476013	0.05
198.6774750	0.02
211.1266785	0.08
215.1661682	0.02
229.1375732	0.02
230.0350952	0.04
233.0890808	0.10
241.1349182	0.11
243.8707581	0.03
254.2628479	0.03
254.9782104	0.28
256.1078186	0.04
259.1250305	0.07
264.1359253	0.01
271.1392517	0.03
273.9831543	100.00
274.7646179	0.02
277.2830200	0.02
281.9250183	0.03
282.7052917	0.03
291.6495667	0.01
294.7438965	0.05
295.3872986	0.08
297.0098572	0.02
301.0534668	0.01
309.1120605	0.01
313.0224915	0.16
316.6632385	0.01
329.0541992	0.05
331.1333313	3.05
339.0901489	0.16
355.3518677	0.01
369.0527649	0.02
383.1150818	0.04
384.8156433	0.04
393.1810608	0.03
411.1094666	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	473.3275
Annotation	(3beta,17alpha,23S)-17,23-Epoxy-3,28,29-trihydroxy-27-norlanost-8-en-24-one
Peak:m/z	Relative Intensity
151.1118164	0.02
151.7937317	0.04
152.9718018	0.06
175.0189514	0.06
205.9907837	0.03
208.2185059	0.04
221.9286957	0.02
224.8902283	0.05
241.3712769	0.02
247.0553741	0.02
248.3290100	0.03
252.0740662	0.01
266.4090271	0.02
267.1241455	0.02
271.2220154	0.03
277.2306519	0.17
317.5396729	0.18
318.4518433	0.05
320.3844910	0.03
321.2660828	0.05
327.2349854	0.01
341.4749146	0.11
346.2957764	0.02
354.5161133	0.06
355.5397949	0.09
356.6037598	0.19
357.5120850	0.69
358.4824219	0.36
359.2625732	0.09
360.3066406	0.06
361.0329285	0.10
362.1314087	0.03
371.2972717	0.02
373.2414551	0.06
378.4191284	0.03
383.6198120	0.04
384.9168396	0.06
385.5357971	1.08
386.5248108	0.86
389.0330505	0.04
389.8304138	0.12
391.0787659	0.01
396.0801392	0.04
397.7039795	0.03
399.5511169	0.05
400.1759949	0.02
401.5942688	0.07
402.4994202	0.37
411.3970337	3.83
412.3644714	2.04
413.2880859	0.10
415.2485657	0.07
416.2065735	0.13
419.8460999	0.07
420.6689758	0.03
429.4391174	100.00
430.4332581	64.70
431.3070374	0.08
432.3488464	0.03
435.5483093	0.01
437.8592834	0.07
441.5110779	0.08
442.4844666	0.02
447.1640320	0.04
455.3462219	0.07
456.4847107	0.17
457.4093628	0.35
458.4900818	0.08
459.4302063	0.03
473.2389221	0.02
475.4385071	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.1454
Annotation	Mannopine
Peak:m/z	Relative Intensity
94.9927139	0.26
110.0364685	1.47
155.9934998	100.00
175.0215302	0.10
229.8539429	0.23
259.4224243	0.25
267.5086670	0.30
270.1290283	0.44
273.7371521	0.25
283.8961182	0.15
292.3002319	0.83
293.2283630	2.46
294.2265015	1.77
311.0816040	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.65
Annotation	Unknow
Peak:m/z	Relative Intensity
234.0892029	1.17
290.5331421	1.07
293.0134888	2.93
374.6594849	1.14
376.4819946	2.63
412.7720947	0.27
421.0540161	0.19
426.8471680	0.62
458.6746826	10.76
459.8524170	5.51
460.6693115	9.69
468.8092651	0.27
482.0224609	1.22
500.6018066	0.71
515.3393555	0.20
532.7608643	0.15
540.6790161	0.94
542.5720825	47.53
544.0784302	39.92
544.6994019	100.00
552.7100220	0.97
556.7607422	2.79
557.8294067	0.48
558.9909058	0.51
560.0471191	0.20
580.1045532	2.58
582.7509155	0.89
604.6567993	2.66
615.0263062	0.55
619.0043335	0.33
622.4400635	0.27
626.4450073	7.02
627.8269653	30.40
628.5214233	66.06
629.1680908	3.38
634.7528687	1.29
636.6889038	1.80
638.7830811	5.58
640.6746216	1.78
652.7756958	0.98
655.5578613	0.52
666.0835571	13.36
666.7540894	26.24
689.2634888	12.95
690.1808472	0.89
691.4710083	0.86
693.9025879	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	468.1442
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9386292	0.24
160.0700989	0.15
166.0655823	0.18
171.0605774	0.11
177.2429810	0.24
179.1358337	0.41
186.8315735	0.07
210.3068237	0.08
213.1812134	0.04
226.2300720	0.04
236.4633484	0.05
243.9403381	0.06
254.0579529	2.68
272.1623230	4.04
283.1127930	0.09
288.0626221	5.34
301.0444336	0.08
306.0989380	100.00
307.1211853	0.03
334.0764771	0.07
336.1224365	0.03
339.1173706	0.12
347.1313477	0.17
348.1505737	0.18
364.4647522	0.05
365.9426575	0.03
374.0418396	0.22
386.0322571	0.16
387.4999695	0.09
396.4946594	0.14
406.1213989	0.05
408.1960754	0.25
421.9923706	0.16
423.1326599	0.13
424.6481628	0.32
430.1709290	0.31
432.2166138	0.26
441.0504456	0.12
450.2270203	0.15
451.1646118	0.18
453.0257263	0.12
454.2534180	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1662
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1766357	0.24
130.9210205	0.18
137.0423889	0.22
138.9479828	0.18
141.3741455	0.05
143.0270386	1.47
149.1282501	0.06
150.0707703	0.03
151.0569458	0.19
154.9588776	0.18
158.9975128	0.25
160.9427643	2.14
170.7550964	0.06
173.1577454	0.14
179.0817261	1.40
180.0665588	0.28
191.2018890	0.40
197.0345154	0.10
203.0849915	0.04
215.2311401	0.38
224.9356842	0.10
232.4040985	0.28
233.3074951	0.09
244.9621582	0.38
249.2679138	0.09
256.5620117	0.12
263.0389709	1.29
273.2223816	0.14
281.3122559	0.04
289.2104797	0.10
293.4137573	0.26
299.0765381	0.10
300.5013428	0.04
323.1693726	40.23
327.3053284	0.14
329.2129822	0.04
335.2352905	0.13
341.1378784	100.00
342.3968811	0.15
346.3988342	0.07
347.1203308	0.10
355.0353699	0.25
361.0950928	0.05
363.2695312	0.13
364.9922180	0.38
379.2409973	0.42
381.3368835	1.07
382.0696411	0.06
383.3771362	0.18
386.9475403	0.06
389.1210632	0.55
395.3326416	0.22
397.4551086	0.04
402.3608398	0.07
407.2478943	2.01
408.2381287	0.12
408.9595642	0.08
409.7327576	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.138
Annotation	Galactotriose
Peak:m/z	Relative Intensity
154.9606018	0.01
161.0829773	0.22
178.9444885	0.36
208.1367950	0.01
219.2159119	0.02
221.1667938	0.26
222.0444031	0.01
233.0282898	0.36
234.0942993	0.08
251.0104065	0.11
251.8199768	0.01
253.2455444	0.01
263.0227356	0.04
272.9389038	0.04
281.1019287	0.10
287.1809082	0.01
294.7829590	0.01
304.9370728	0.04
306.3460693	0.01
323.1355591	0.57
324.1544189	0.14
329.1657715	0.03
341.0570679	0.55
342.0162354	0.08
353.0111694	0.04
355.6171875	0.05
359.1718750	0.56
360.0600586	0.01
367.1289673	0.02
368.5089111	0.06
369.1851196	0.00
369.9716797	0.01
377.2373047	0.74
378.2876587	0.10
383.2607422	0.34
384.3023071	0.07
391.8602295	0.06
393.8164673	0.10
395.5919189	0.00
413.4543457	0.03
419.9653931	0.04
423.7910767	0.02
424.8786011	0.05
426.2128906	0.04
431.0106812	0.02
443.2476196	0.10
444.1733398	0.01
449.8849487	0.04
454.8920288	0.02
462.2916260	0.01
464.8375244	0.01
465.8814087	0.05
467.0079346	0.02
494.1951294	0.01
503.2261353	100.00
504.2871704	20.30
505.4938354	0.01
521.6981812	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
134.8362122	7.30
140.9654541	5.61
143.0930328	3.63
149.0372162	1.72
176.9699707	2.09
181.2756195	1.54
214.1854401	4.53
243.2115479	6.90
252.0094299	10.12
255.2173767	2.27
281.2410889	2.83
282.4640503	17.49
285.370575	2.46
289.0452881	4.48
295.2960205	12.37
300.355835	4.51
307.2655029	2.65
308.240448	2.83
320.406189	11.96
326.0403442	7.27
328.3219604	12.62
330.2367554	15.15
333.444397	12.85
339.5630493	4.20
353.2266235	10.11
354.4841003	7.18
356.2602844	10.41
357.007843	1.73
360.5808105	14.76
364.6487732	13.03
365.5364075	7.84
372.3200378	2.91
373.2359924	8.01
377.3075562	10.30
378.1813049	6.73
381.4628296	4.66
382.3184509	7.39
390.5968933	25.91
394.9596863	2.54
407.6700134	39.30
408.2819519	100.00
409.3486023	51.89
417.2327576	9.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	742.0855
Annotation	Unknow
Peak:m/z	Relative Intensity
382.2421265	0.05
417.2130737	0.10
425.0018921	4.84
425.6731567	0.02
442.8022461	0.34
449.2257690	0.02
454.8310547	0.03
485.1362305	0.13
500.0361328	0.03
506.0967407	0.02
539.2102661	0.20
542.6167603	0.04
556.7979126	0.08
559.1872559	0.02
568.9613037	0.22
580.1345825	2.06
587.0079346	100.00
587.7550049	0.27
610.1614990	0.11
663.6124878	0.07
664.6211548	0.29
678.2996216	0.15
682.1697388	0.04
695.3687744	0.37
696.0123901	0.05
710.0508423	0.08
718.7630005	0.13
723.9363403	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1272
Annotation	Unknow
Peak:m/z	Relative Intensity
139.0128479	0.05
142.9162292	0.04
147.2036896	0.04
177.2246399	0.03
178.9236603	0.58
184.9779968	0.06
189.2049866	0.02
193.3021851	0.02
203.0743713	0.13
204.1607971	0.05
214.9237366	1.46
219.0231323	0.07
239.0620422	0.04
241.8392029	0.43
242.9542847	0.61
245.1008911	0.05
248.8777771	0.14
249.5032043	0.05
251.2218628	0.14
263.4026794	0.01
267.2309265	0.04
277.1555786	0.09
278.2510071	0.10
285.2842407	0.27
303.2853088	0.03
310.0877075	0.03
316.9630737	0.09
323.2296143	5.06
325.3287964	0.10
329.2386780	0.28
330.8979492	0.59
331.5917358	0.11
332.3089905	0.10
341.2320557	9.62
359.2180481	0.12
367.9375305	0.04
370.9773865	0.04
382.9877014	0.12
384.1544189	0.05
389.1562805	0.04
393.0286865	0.02
399.3830261	0.05
401.1723328	1.08
402.0052185	0.08
403.4848328	0.09
408.7173767	0.10
411.1598816	100.00
415.2115784	0.11
417.4802856	0.08
419.2844849	0.05
420.0656433	0.06
427.0536499	0.18
428.2881165	0.18
429.4648743	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.2968
Annotation	PS(20:3(8Z,11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
183.9503937	100.00
184.9754181	14.24
364.9248047	1.48
387.1248169	6.22
431.5230713	0.76
450.3604736	4.17
471.4827271	0.84
492.6670532	3.41
498.9792480	0.51
511.2523804	1.33
512.2490845	2.29
530.4575195	54.06
531.3300171	18.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0856
Annotation	Gerfelin
Peak:m/z	Relative Intensity
101.1356812	0.56
104.8810196	0.20
119.0923767	0.36
123.0108643	93.29
132.9002686	0.20
137.0975494	0.38
138.9144135	100.00
140.5070801	0.12
147.0003204	6.96
151.0535583	27.20
152.8172607	0.46
163.0589905	0.36
165.0375824	80.47
169.0265808	1.97
173.0370789	0.42
177.0119324	0.49
177.9466705	0.11
181.0823212	0.26
188.0629272	0.41
188.9137878	0.36
191.1671295	0.17
193.1444702	0.06
195.1918335	0.56
202.1967468	0.22
204.0664978	0.47
205.1226501	0.82
218.9412842	0.92
226.3030090	0.60
227.1416016	0.85
231.1292725	0.48
232.9379883	0.29
235.1353455	0.09
241.1240234	0.24
242.7683716	0.12
244.9069214	5.29
248.2902832	0.32
249.1494446	2.82
250.0567017	1.18
254.8942261	1.87
255.5164795	0.14
273.0036621	58.86
274.3343811	0.21
290.5056152	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.29
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9284439	2.83
144.9820099	0.34
151.2833252	0.20
165.3939056	0.19
175.0080261	0.26
204.8047180	0.07
209.2616272	0.07
211.1013947	0.05
220.8304291	0.29
224.9822540	0.09
233.3562927	0.13
237.1486816	2.53
237.7783203	0.13
239.0419922	20.38
239.6865845	0.33
251.0227051	0.24
257.3950195	0.09
264.2919617	0.30
275.0775757	0.22
277.5491028	0.07
278.1564941	0.11
279.6763916	1.13
281.3684082	0.05
283.3285522	0.06
285.3485107	0.08
287.1744995	0.10
289.2093506	0.18
293.2724304	0.43
298.3038940	0.09
306.1241455	0.14
307.2285156	0.39
309.2404785	0.08
311.3901367	0.40
312.3955688	0.36
317.2400513	1.71
324.2840881	0.06
335.0355225	100.00
335.8547974	0.56
336.9443359	0.05
342.4571533	0.05
353.0661011	0.24
355.1373291	0.59
364.8884888	2.92
370.2095642	0.37
373.1393127	0.08
383.1612549	7.34
391.8514404	0.21
393.0067444	0.18
400.1713562	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.1722
Annotation	Lactulose
Peak:m/z	Relative Intensity
326.0392456	0.20
345.0971680	0.43
354.2054443	0.39
363.0751343	8.39
435.2366333	0.67
506.7205811	0.12
516.2974854	0.53
525.2022095	100.00
526.2997437	3.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2995
Annotation	Epothilone H2
Peak:m/z	Relative Intensity
137.0254211	0.83
139.4227753	0.09
142.9502563	0.33
144.9396667	0.31
152.0100861	0.16
152.7144775	0.10
157.2082214	0.15
158.9712372	0.16
161.3005676	0.34
162.1112671	0.20
162.9302216	0.26
165.2647400	0.04
167.1266022	0.54
169.1711121	0.05
170.3686523	0.40
171.1372375	0.13
172.9181976	0.29
178.9530945	0.05
181.0194092	0.11
183.0876923	0.11
185.0578156	0.14
188.8470459	0.46
190.9770813	0.50
194.9533081	0.08
199.1347351	0.59
203.1990356	0.44
210.9666443	0.04
213.0858765	0.04
217.0417328	1.03
219.3144379	0.25
221.2140045	0.08
223.0469513	0.85
225.0173340	0.16
227.1600800	0.70
232.8910980	0.09
235.0482330	0.31
237.2709808	0.51
239.2313232	0.27
241.2142181	0.09
249.1755066	0.20
251.1226807	0.16
253.2491760	0.16
255.0625610	0.84
259.3595276	0.25
265.3259583	0.97
267.4085083	0.33
271.2312012	0.28
273.2335815	5.08
275.5082397	0.11
277.2812805	0.26
278.2788391	0.04
285.2497253	1.50
287.2062683	0.16
288.6874695	1.06
289.2931824	3.85
291.2854614	100.00
293.3470459	0.09
297.5607300	0.43
299.1775208	0.76
300.8367615	0.47
303.1336060	5.06
305.2144165	2.39
306.2430725	0.04
309.3954468	0.31
311.2774048	0.26
315.3312683	3.94
316.2844849	0.22
317.2390137	1.73
320.3938293	0.22
321.3977051	0.04
323.3574829	0.87
325.3891907	0.20
327.3746948	0.45
329.4268799	0.62
331.0287170	0.18
334.3144836	0.21
337.2981873	0.17
339.3794250	0.42
341.0702515	0.12
343.5123291	0.17
345.2292480	1.88
347.0483398	0.34
349.3687134	0.11
353.5116272	0.32
354.3864746	0.06
355.3245850	1.69
356.5439453	0.25
357.1478271	0.67
358.2660522	0.22
362.9905396	0.58
365.4477234	0.24
367.4996338	0.50
369.3945923	0.74
371.2914429	0.54
372.9932556	0.62
379.1992493	0.17
381.3885193	1.06
383.2966309	0.43
385.3585815	0.82
387.1730042	0.30
389.3569031	0.17
391.2826843	4.66
395.3576050	0.40
397.4396362	0.28
399.2992859	0.97
401.5235596	0.16
404.5696411	0.10
407.2241821	0.24
409.3388367	17.17
411.3372498	0.26
414.3665161	0.17
423.3025513	0.67
427.2387695	27.66
427.8437805	0.16
430.2925720	0.13
440.4149780	1.57
441.3119202	15.86
444.3043518	0.57
445.5101624	0.08
458.5207214	7.61
459.3412781	13.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	193.0869
Annotation	[2-(4-Methylphenyl)-1,3-dioxolan-4-yl]methanol
Peak:m/z	Relative Intensity
93.0110931	0.01
103.0919800	0.01
105.0505066	0.01
115.1272278	0.02
116.9888763	0.01
119.0225372	0.06
121.0035400	0.07
121.9466553	0.05
123.2199249	0.01
131.2565918	0.03
134.0698700	1.34
137.1414490	0.09
143.2573700	0.03
146.7877655	0.12
148.9820404	0.58
149.9666901	0.01
151.0472870	0.12
151.9633789	0.03
161.0734406	0.65
163.1625214	0.87
165.1100464	0.10
174.1147614	0.02
175.1448669	0.27
177.9847870	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.2938
Annotation	1-heptadecanoyl-glycero-3-phosphoethanolamine
Peak:m/z	Relative Intensity
153.0100098	0.21
170.3409119	0.16
196.0010071	1.93
214.1483154	2.03
241.4357605	0.37
269.2412109	100.00
280.2582092	0.34
298.1412354	0.28
338.5446472	0.35
366.1842041	0.07
378.7267761	0.10
385.5472717	0.87
394.7446594	0.40
404.3917542	0.11
405.2493591	0.44
408.5388489	0.55
420.4559326	0.24
421.144165	0.31
422.5122986	1.34
430.2024841	0.10
437.5505066	0.26
447.5158997	3.12
449.3908386	43.30
451.1150208	2.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.067
Annotation	Unknow
Peak:m/z	Relative Intensity
85.2087021	0.23
86.9458771	1.04
88.8582382	5.81
95.0507050	0.45
97.0609589	0.42
100.9426422	4.50
105.8041229	0.11
106.6981354	0.82
112.8412781	6.06
115.0081177	5.12
118.8894882	6.95
124.9449158	1.02
127.1016235	0.36
131.0035706	3.14
132.9356384	44.02
137.1724243	0.10
142.9412689	6.24
147.0483398	0.14
147.7912598	0.38
148.9538879	2.26
157.1048279	0.44
160.9402161	11.47
175.0153351	2.63
177.6126709	0.55
179.0302429	100.00
187.0751495	0.53
189.0383606	0.26
204.9673767	12.89
207.0623474	0.18
215.0599670	0.50
216.9561462	2.44
235.1066284	78.40
259.0765381	0.17
265.2244873	1.38
277.0381470	16.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2916
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
177.2687683	0.04
189.0498352	0.04
198.1730652	0.11
210.2748108	0.06
215.9771271	0.23
247.2282104	0.03
253.2676392	0.05
263.4066467	0.02
306.3309937	0.50
337.2637634	100.00
337.9318542	0.16
380.9110718	0.06
416.7198792	0.04
417.618988	0.03
434.6108704	0.10
447.3222046	0.04
449.4058838	0.15
460.2778625	5.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0933
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9426575	0.08
157.0213623	0.13
160.6781311	0.08
162.8859558	0.35
177.0351868	0.03
190.2157440	0.07
203.0818481	8.94
205.0967712	0.08
214.9130249	0.21
219.2570801	0.17
223.0012207	0.13
230.2299805	0.15
230.9238586	0.33
233.0081177	0.18
239.2366638	0.20
240.9557190	0.15
243.1300659	0.09
245.0009460	0.27
247.1164551	0.20
255.0408630	0.25
257.1722412	0.12
258.5007019	0.12
259.2260132	0.36
260.2030029	0.20
265.4537964	0.09
268.8973694	0.17
273.0654907	0.82
275.1322021	1.19
277.0110168	0.07
281.2966614	0.09
283.1638794	13.60
283.9667358	0.05
285.1853027	0.10
289.0645752	0.20
301.0510864	100.00
301.8896484	0.19
304.0829163	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
92.89173889	0.30
122.8494568	0.15
125.166626	0.04
126.9975739	0.11
158.7067413	0.25
160.8382416	0.44
163.0506134	0.05
175.0959167	0.19
176.9381561	0.21
182.7124481	0.09
184.9719696	0.24
187.0511627	0.08
189.0264435	0.25
191.0356598	0.06
201.154007	0.13
203.1378937	0.23
204.1795197	0.06
207.1345673	0.22
214.9250946	0.13
217.0251617	1.38
218.4289093	0.12
219.1039276	0.53
223.0045013	0.30
224.0005035	0.08
225.6876221	0.26
227.2031403	0.16
230.8633881	0.26
232.0246124	0.06
238.9625092	0.19
241.1187592	0.05
243.1417847	100.00
243.8303833	0.58
245.2826385	2.07
262.0755005	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2918
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
141.0891724	0.07
179.9404602	0.07
185.2055969	0.01
198.1742249	0.06
213.1443329	0.04
215.9968109	0.06
224.8989563	0.02
227.1106873	0.05
242.7495422	0.05
245.4315033	0.05
247.1489258	0.12
263.2238464	0.18
267.028717	0.10
277.2041626	0.08
298.6444092	0.01
301.4239502	0.01
303.7246704	0.01
306.3688354	0.48
319.4048767	0.09
335.1873779	0.11
337.279541	100.00
337.9332275	0.26
343.1753235	0.05
369.3929443	0.05
373.605896	0.07
380.6044617	0.06
387.2568665	0.04
398.2609253	0.05
399.0276184	0.03
407.7904358	0.08
411.4720459	0.02
415.1390686	0.11
417.2991638	0.23
421.8457031	0.04
435.214447	0.12
442.1633911	0.03
443.0207214	0.13
447.3399353	0.05
450.6515198	0.04
460.2763977	6.06
461.2900391	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2252
Annotation	Lactulose
Peak:m/z	Relative Intensity
199.0716248	0.01
220.9611664	0.04
269.3240662	0.02
281.1895752	0.05
295.0982056	0.02
339.4244995	0.13
341.1411438	100.00
430.5925293	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2076
Annotation	Stecholide L
Peak:m/z	Relative Intensity
173.1329498	0.12
207.0529022	0.21
254.9415283	0.11
264.2375488	0.25
271.0034180	0.07
286.0291138	0.10
323.0950928	0.34
334.1824951	0.34
340.7736816	0.17
349.1551514	0.26
355.3924561	0.12
376.4921875	0.14
381.1229858	0.25
392.1402588	0.55
393.1697998	0.15
395.3998413	0.31
415.2843018	0.06
417.2545776	100.00
427.2850952	0.33
442.9900513	0.09
449.2067871	0.05
459.3936768	0.31
481.3049316	0.15
483.2680054	0.12
487.0003052	0.58
489.4491577	0.06
493.2000122	0.31
498.1417847	0.26
503.5883179	0.26
515.9605713	0.08
525.4817505	0.06
531.7581177	0.14
533.1522217	1.74
534.4220581	0.43
535.2788696	0.26
538.8790894	0.10
543.0557251	0.58
545.1788330	0.16
548.1187134	0.16
557.2761841	0.43
560.7092285	0.21
561.3950806	0.18
570.0059204	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.0196
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9526367	1.38
198.9806671	1.41
200.1484680	1.06
200.8909607	0.13
218.8556976	0.14
228.8996124	2.64
230.1043091	0.32
230.9748230	0.45
245.0140686	0.25
258.7669373	0.48
259.4026184	0.43
272.9425049	80.99
273.9422302	63.16
275.0116577	48.66
288.9635010	3.52
351.1536865	0.23
373.2064209	2.62
374.0709839	2.52
375.1182861	1.18
386.9717407	53.99
387.9175415	58.42
389.0247803	100.00
398.1261597	0.13
402.7266235	0.70
427.2755127	0.57
428.0964966	0.63
429.1309204	0.21
443.1098022	1.36
472.2349243	0.39
472.8886108	0.19
486.8388062	5.50
487.9912720	6.63
489.0258179	7.59
542.9105835	0.53
545.0556641	0.16
556.1561890	1.67
556.9468994	18.36
574.9598999	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3047
Annotation	Sphinganine
Peak:m/z	Relative Intensity
95.04077148	0.41
96.92274475	0.39
107.069519	0.09
111.0790787	0.16
122.928833	0.25
124.7780609	0.28
136.7394714	0.06
182.8778229	0.38
193.0325165	0.20
240.4199219	0.54
242.173584	0.53
249.2381592	0.43
251.1921387	0.26
254.3224487	1.00
255.313446	0.13
256.4573364	0.07
266.409668	3.71
267.331665	0.57
271.0272217	0.50
284.2994995	100.00
285.0965576	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.16
Annotation	Sibiricose A5
Peak:m/z	Relative Intensity
148.1255798	0.12
149.0684052	1.29
160.0270081	1.13
160.9904480	1.25
166.9127808	0.23
173.1263885	0.08
174.0744324	0.61
175.1428986	1.97
176.0820312	0.28
178.0621490	6.53
179.0179749	3.47
188.0403137	0.39
191.0363617	0.40
193.0024872	100.00
193.8165131	0.13
197.9417572	0.04
202.0055542	0.59
207.2322388	0.06
208.0386047	0.17
215.0824890	0.31
216.0761414	0.06
217.0809479	9.44
221.0559082	4.37
226.2318573	0.07
235.1650238	2.71
243.8706055	0.18
244.9911804	0.21
247.0970612	2.75
254.0734406	0.09
257.0861816	0.06
258.9663696	1.29
263.2012939	1.67
265.0375366	1.15
272.2723999	0.05
274.2131958	0.08
275.0527344	0.09
277.0016479	0.19
287.9154053	0.07
291.1943359	0.05
293.3312378	0.04
295.2231445	0.12
301.2504883	0.07
304.1755371	0.11
305.1264648	1.09
306.2591553	1.41
307.2271729	0.78
309.1773071	0.04
315.1619263	0.12
318.9902954	0.42
322.5496216	0.38
323.1690063	17.73
324.2163696	0.70
334.9458008	0.20
337.1635742	1.19
341.0213013	0.44
355.0195923	2.16
360.6731567	0.12
364.2478638	0.15
394.9169922	0.36
397.1838379	2.32
399.0842285	0.11
401.3536987	0.22
416.3018799	0.28
427.2401733	2.82
433.1552734	0.30
439.2901611	0.66
457.1934204	6.11
458.9920044	0.17
463.0521851	0.12
470.4938354	0.22
471.1625366	0.57
472.6417847	0.32
473.6090088	0.17
474.4038086	0.10
479.2431030	0.13
481.2722778	0.31
483.2901611	0.16
498.1493530	0.07
499.2501831	1.83
510.7050781	0.19
517.1484985	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
231.8276978	0.16
314.3148804	0.22
328.2250977	0.28
380.8400269	1.49
418.7525635	10.43
420.1855469	0.10
420.8100586	0.40
462.9456177	0.56
464.5864868	16.18
502.6342773	13.70
512.8668213	0.22
534.4370117	0.15
535.2738647	0.23
546.8908081	2.58
548.5833130	100.00
549.3441772	0.14
559.5022583	0.39
572.8261108	0.16
586.4511108	79.24
587.2739868	0.55
589.7030640	0.22
590.8685303	0.60
609.4794922	1.58
614.8278198	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	438.2625
Annotation	PE(15:0/0:0)
Peak:m/z	Relative Intensity
139.9720764	0.14
152.9691162	0.25
196.0733948	2.21
214.1337585	1.92
228.9358673	0.04
241.1867981	100.00
255.3730774	0.06
271.3661194	0.06
281.1890259	0.03
297.2280273	0.02
300.3518982	0.03
309.5260620	0.01
323.2631226	0.07
331.1630249	0.03
339.9270630	0.09
349.3742981	0.03
357.2615662	0.03
377.3285217	0.65
381.9812012	0.01
392.2843323	0.07
393.4178162	0.09
394.1585388	0.01
395.3407593	0.08
398.0041809	0.03
400.3114929	0.02
401.0530090	0.13
402.3396912	0.15
403.2862549	0.21
409.9782715	0.04
411.4163513	0.02
419.3008728	0.15
420.2752380	0.12
420.9783936	0.01
433.3883057	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0771
Annotation	Altersolanol A
Peak:m/z	Relative Intensity
107.1599579	0.08
110.9046860	0.76
116.5391998	0.24
134.0350037	0.93
135.0484161	20.50
137.9196930	0.09
155.0270386	0.67
160.9801331	3.10
162.8441772	0.06
166.8937836	0.07
172.8646393	0.07
177.2107239	0.09
178.9629517	100.00
189.0839233	0.05
199.0749664	0.10
203.1739502	0.04
209.2454529	0.28
220.1763916	0.15
221.2070618	0.10
235.1851807	0.04
247.1869202	0.15
254.6616821	0.09
255.2793579	0.09
261.8513184	0.06
263.9504700	0.14
270.3662720	0.13
273.0899353	0.05
288.0770874	0.12
289.0512695	0.29
290.0535889	0.48
291.0895386	1.88
293.2644348	0.06
297.6691284	0.04
299.0469971	0.40
301.8022156	0.05
305.3720093	0.09
307.2657471	0.38
314.1915588	0.15
315.7943420	0.18
316.4744568	0.09
317.2263184	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.2789
Annotation	Sterebin M
Peak:m/z	Relative Intensity
116.9882965	0.04
123.2989960	0.06
151.1258240	0.07
153.4423523	0.04
157.7506714	0.25
161.0000000	0.03
170.9984283	0.10
179.0479279	0.37
182.7585144	0.23
198.0042419	0.03
201.4138489	0.10
210.9918213	0.65
226.2499084	0.11
241.1367188	0.05
244.0688782	0.09
251.1580811	0.08
252.8031006	0.02
256.3556824	0.11
268.2067871	0.08
275.3229370	0.89
279.4695435	0.18
280.2136841	0.03
283.1918945	0.07
288.3122253	0.06
293.2237244	0.86
303.2587280	0.08
307.1607056	100.00
307.7645874	0.47
310.3670044	0.11
311.9662170	0.22
315.0067749	0.47
317.4548340	0.02
319.4756775	0.05
321.3593750	0.22
325.1744690	2.07
327.1830444	0.19
328.0387268	0.13
331.5309448	0.08
333.3232727	0.07
335.7772217	0.03
336.5862427	0.20
337.7579651	0.78
338.9915161	23.36
340.0336914	0.08
355.5118103	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.21
Annotation	7S,8S-DiHOTrE
Peak:m/z	Relative Intensity
96.8449020	0.18
110.9503021	0.16
122.9790497	0.19
126.9594116	0.36
151.0808411	0.20
154.9084473	0.22
158.9627991	0.21
165.0113220	0.26
167.2910767	0.19
169.0531158	0.04
171.2418823	0.34
179.0619812	0.14
180.7495117	0.33
191.3519592	0.23
193.2182770	0.88
195.3730164	0.17
197.3301697	0.06
209.1887817	22.51
211.9333191	0.25
212.8263855	0.32
215.1925964	0.30
217.8595276	0.11
219.0063171	0.24
219.9513855	0.13
221.2226562	0.12
222.9995117	0.05
223.9722290	0.16
230.8157043	0.07
237.0234375	0.18
237.7873840	0.06
239.5033264	0.28
241.4291077	0.23
245.0086975	0.14
247.4801331	0.98
249.2713623	0.36
250.4383850	0.11
251.3159180	0.09
253.3891296	0.14
259.1793213	0.10
263.2005920	0.43
265.2839966	3.24
267.3512573	0.32
270.9076843	0.45
271.9391479	0.15
273.1716003	2.31
274.1152649	0.84
276.2213745	0.12
280.3289795	0.13
281.3565063	0.36
288.8639832	0.09
291.2424011	100.00
294.2285156	0.42
309.4987183	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.74
Annotation	Unknow
Peak:m/z	Relative Intensity
213.0562134	0.07
214.8279724	0.02
251.0285645	0.59
252.1394958	0.28
253.0087891	0.53
292.6801147	0.23
294.7604065	0.33
297.0052795	0.29
378.6273499	0.26
380.7669373	15.52
418.7146912	100.00
419.3359680	0.20
445.9212952	0.10
448.0189514	0.04
462.9270325	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.3591
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1117401	0.17
204.2718353	0.08
219.1614075	0.21
220.8772888	0.41
227.0317993	0.07
233.1607666	0.03
235.1194305	6.80
236.0570374	0.58
245.0909576	0.55
245.9749908	0.11
253.2837830	2.85
254.1860352	0.37
258.8179016	0.12
260.2581177	0.06
264.1645508	0.11
277.2679443	0.03
278.2094727	0.14
283.3436890	0.21
287.0896301	5.23
288.1291199	0.95
303.4433594	0.08
305.1590881	5.24
306.1969604	1.77
309.9373779	0.06
323.1469727	0.96
324.4153748	0.11
330.2037964	0.12
336.6669922	0.05
355.3336792	0.09
361.1655884	0.42
362.4609375	0.04
373.3198242	0.12
379.2979736	0.31
380.2828979	0.09
397.1473389	100.00
398.1987305	26.93
400.1445312	0.28
401.9373169	0.08
415.1558228	32.97
416.3001709	9.57
430.3912354	0.13
452.2561646	0.07
456.2855225	0.06
523.3715210	0.11
533.0924683	0.13
572.5484619	0.37
584.2894287	0.18
606.0389404	0.18
607.3016968	0.20
613.4776001	0.16
614.1127930	0.26
616.2197876	0.06
620.1500854	0.08
624.5058594	0.26
633.5106812	0.09
635.0173950	0.11
637.0068970	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1058.6451
Annotation	Unknow
Peak:m/z	Relative Intensity
539.4208984	1.36
799.2517090	10.78
872.2250977	1.30
974.4689941	1.43
1063.1889650	1.97
1142.8503420	1.93
1494.4068600	1.76
1537.8424070	0.60
1583.0357670	1.56
1677.5863040	1.19
1718.3780520	0.27
1739.4763180	0.51
1759.7614750	1.36
1761.1158450	2.94
1766.0109860	1.93
1785.0123290	1.14
1797.8732910	0.26
1809.7789310	0.41
1824.9034420	0.41
1827.6018070	0.27
1838.3605960	2.38
1853.4332280	1.50
1861.9324950	0.85
1868.7946780	2.30
1876.0614010	5.71
1876.7834470	0.78
1881.9425050	0.45
1885.2956540	0.80
1887.7087400	12.88
1889.1517330	1.46
1895.0676270	1.00
1897.0137940	2.03
1898.5734860	3.75
1902.9108890	10.27
1908.3934330	5.16
1916.9971920	0.87
1924.4173580	0.78
1927.0555420	9.96
1927.9971920	3.69
1932.5130620	2.89
1934.4318850	8.90
1935.0505370	30.14
1937.6141360	16.46
1946.2952880	3.38
1949.6618650	15.32
1952.7669680	5.39
1954.0545650	2.91
1960.9973140	6.81
1961.8157960	3.37
1963.1304930	1.05
1964.5998540	15.18
1965.3571780	0.25
1966.3868410	0.46
1970.3282470	0.70
1974.6324460	0.92
1976.9099120	4.93
1977.6359860	1.89
1980.7896730	6.84
1984.3524170	1.39
1986.3990480	0.73
1987.5267330	16.12
1988.2161870	1.44
1989.1453860	0.43
1992.5794680	100.00
1993.7581790	0.25
1996.2528080	4.96
1996.9527590	0.52
1998.3133540	9.72
1999.3226320	1.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1715
Annotation	Unknow
Peak:m/z	Relative Intensity
149.2150879	0.05
158.8296661	0.10
168.8298035	0.03
172.7273254	0.08
178.9746094	0.05
184.9374390	0.04
192.9990845	1.56
201.1331940	0.04
203.0185852	0.03
209.0897369	0.09
213.0902863	0.07
215.0456543	0.03
219.0982056	0.04
220.2822113	0.03
224.3176727	0.21
232.0604858	0.06
239.0286560	0.09
245.2182617	0.05
275.1734314	0.23
276.9877319	0.06
279.1202698	0.08
281.1522522	0.15
309.4577942	0.06
322.9798584	0.05
339.3870850	0.11
339.9983521	0.06
341.3511963	0.56
354.9055481	0.42
381.1349182	0.06
387.0680542	0.35
403.3900452	0.04
409.2979431	0.16
410.2244263	0.24
411.2821655	0.35
425.2612000	100.00
427.2206726	0.53
433.1827087	0.20
434.2169495	0.12
435.1513672	0.12
442.8988647	0.11
453.1310730	0.68
454.2211609	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	373.2211
Annotation	Blumenol C glucoside
Peak:m/z	Relative Intensity
134.8610229	13.13
175.0968323	11.91
192.6186218	5.16
193.2275696	23.49
202.3082275	1.96
211.1633606	100.00
280.2722168	10.21
284.2183838	6.95
354.9347534	12.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1975
Annotation	Creoside IV
Peak:m/z	Relative Intensity
173.8278961	0.03
176.9087219	0.05
193.1883850	0.05
197.8550720	0.06
203.0600586	0.04
223.2149200	0.02
226.0460663	0.04
229.0490723	0.02
232.0620117	0.10
235.1653748	0.07
244.9310608	0.04
248.9396057	0.17
253.2023010	0.04
261.0575867	0.28
264.9601135	1.09
266.1130371	0.07
273.0494080	0.01
274.0905762	0.05
276.8798523	0.02
277.8414917	0.17
292.9044189	0.09
296.4628906	0.05
297.1835022	0.08
302.3546143	0.08
303.1024780	0.04
304.0383301	0.03
309.1335754	0.06
327.2526855	0.02
339.0478516	3.03
341.2446289	0.21
345.2081299	0.05
349.3260498	0.08
353.5877380	0.03
357.1264038	0.20
379.3480530	0.21
381.3888855	0.08
383.0880432	0.07
385.8247375	0.03
395.1965637	100.00
396.0543518	0.35
397.6654968	0.24
400.7432556	0.09
404.3082886	0.07
411.4225159	0.07
423.0677185	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	154.06
Annotation	L-Histidine
Peak:m/z	Relative Intensity
66.9636536	0.42
71.9487610	4.16
81.0444336	0.35
93.0045166	6.83
93.8819733	0.15
108.1526489	4.99
108.9360809	6.33
109.9361115	7.02
117.9702606	5.01
135.9341583	84.48
136.9273834	100.00
154.1217957	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.0589
Annotation	Acetylelatol
Peak:m/z	Relative Intensity
114.9191513	7.81
130.9549561	0.05
157.0780334	0.33
158.8994751	100.00
208.0563660	0.04
213.1092377	0.49
222.1933899	0.04
225.1989441	0.08
231.3059387	0.18
255.1631165	0.09
257.0998840	0.54
259.1172791	37.79
293.8512268	0.08
295.0549927	0.09
299.2487488	0.15
301.2881470	0.19
308.1557922	0.22
309.4498901	0.16
310.1602173	0.12
311.1771851	0.39
325.3572388	0.12
326.1290283	0.18
327.1365967	10.61
329.1392822	0.06
344.8284912	1.76
345.5151062	0.08
355.3106384	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.2
Annotation	Rehmaionoside C
Peak:m/z	Relative Intensity
113.0755463	1.55
119.1003571	0.80
125.1965408	0.17
131.0442200	0.34
136.9692688	0.18
142.9746094	1.02
148.8851318	0.29
152.0406647	0.19
153.1529694	0.26
153.9986267	0.27
159.1025543	0.46
161.1012726	4.47
162.7770996	0.22
170.8455505	0.14
173.0657349	0.08
178.4517975	0.20
179.0725708	4.60
185.1699371	0.24
186.0230103	0.04
189.2746735	0.06
191.9670715	0.10
205.1529694	0.31
206.0922699	0.12
207.1661835	0.61
223.2523499	0.39
225.1664124	21.34
233.1425171	0.13
235.7510376	0.09
241.1150818	0.29
244.8018188	0.17
247.1098633	0.09
249.0187378	0.73
259.0158386	0.24
267.1417236	0.24
271.3630371	0.68
272.3527832	0.09
283.1953735	0.06
289.1026611	1.40
297.2017822	0.17
299.0870972	0.41
307.4604187	0.63
315.3845825	0.13
321.3674622	0.29
326.3875732	0.26
327.1624146	0.42
329.2190247	0.16
341.2215271	100.00
343.0732117	1.17
343.9786682	0.41
350.7598877	0.17
352.2023315	0.15
353.1104431	0.34
356.1649170	0.32
357.3800049	0.15
359.0382080	0.05
366.9747620	0.31
368.5744629	0.04
369.3632507	0.82
370.7212219	0.19
372.4414978	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1818
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
124.1556854	0.04
125.1314087	0.05
131.1195221	0.01
160.9228210	0.03
168.9914093	0.10
185.2726440	0.03
201.1381531	0.73
202.2664490	0.09
229.0442200	0.02
241.4374084	0.10
249.1761780	0.16
257.2936096	0.04
259.2109680	0.09
260.0625000	0.07
263.7292786	0.02
265.4992981	0.06
288.4636841	0.04
295.2272949	0.04
306.3422852	0.03
324.2989807	0.16
325.1954956	0.08
326.8490601	0.05
329.3741760	0.02
341.2379761	0.15
342.1752319	0.12
345.2501831	0.03
352.3373413	0.02
353.2458191	0.05
367.2974548	0.13
368.4340820	0.10
369.1274414	0.13
381.2463989	100.00
382.9343262	0.38
385.4084473	0.02
388.0722351	0.04
391.0824280	0.17
391.8434448	0.09
394.1502686	0.07
396.9789734	0.10
408.2275696	0.02
409.1452332	0.41
411.7551575	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2028
Annotation	Sesaminol glucosyl-(1->2)-glucoside
Peak:m/z	Relative Intensity
194.2593384	0.10
203.3277893	0.08
204.2909241	0.22
217.4131317	0.17
221.0624542	0.13
222.2655945	0.12
230.9931335	0.38
233.1495056	0.23
235.0533142	0.79
235.9346008	0.10
242.2615509	0.17
246.8044891	0.84
248.0517273	0.51
251.0876465	0.13
251.8854370	0.12
259.0262451	0.26
262.1257935	0.17
265.1286926	2.24
266.1099243	0.41
272.4086914	0.17
276.2364197	0.08
289.1540527	0.19
292.2799683	0.10
295.0613403	0.32
299.5800171	0.14
302.3017578	0.17
305.0876160	0.28
306.2261963	0.06
307.2297363	0.19
308.3092651	0.08
319.1973877	1.79
323.1330872	1.47
324.2907104	0.43
326.1205444	0.17
337.1644287	4.17
338.1735229	1.09
341.2495728	0.15
355.1275024	0.69
356.1450195	0.05
377.2650757	0.19
380.0284424	0.08
394.0349731	0.08
395.2290649	0.39
396.0663452	0.08
412.2540283	0.08
421.2476196	0.10
441.0795898	0.12
479.9536133	0.07
481.1740723	0.23
482.5245361	0.20
485.3488770	2.25
486.4126587	0.93
488.5480957	0.12
489.2344971	0.05
494.5365601	0.68
496.3477173	0.38
499.2357178	69.20
500.1826172	17.89
503.2123413	0.25
504.5329590	0.19
507.6436768	0.09
513.2231445	5.48
514.2612305	2.21
517.1774902	100.00
518.2756958	29.91
530.8936157	0.04
548.2653198	0.07
562.5434570	0.09
579.3744507	0.08
602.8206177	0.12
609.7949829	0.84
612.3529663	0.33
631.2404785	0.11
638.6698608	0.10
647.4390869	0.48
650.3980103	0.09
671.1580200	0.44
671.8746948	0.15
676.7125244	0.20
695.1176147	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.2003
Annotation	CHEBI:59526
Peak:m/z	Relative Intensity
113.0068665	1.12
154.5417786	1.46
161.0135498	0.98
187.125061	0.61
235.9170837	0.55
237.1782532	3.96
243.3977356	1.44
249.193634	1.17
251.3243408	1.36
280.0818176	0.88
291.8928833	0.52
332.7319031	2.03
342.4176331	3.45
343.4354248	1.07
350.9512634	0.52
355.1536865	3.08
356.3026123	3.11
361.1508484	0.55
364.7234192	1.58
369.5753479	1.85
374.139801	0.52
378.5291138	3.67
381.9886475	1.12
386.4368286	0.35
387.421051	9.78
391.0992126	3.43
394.3260803	0.74
405.188446	100.00
406.3063049	1.78
407.4732056	0.97
414.3033447	3.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	470.256
Annotation	Unknow
Peak:m/z	Relative Intensity
147.1452026	0.14
324.2350769	100.00
345.0269165	0.32
364.8447571	0.07
372.3911438	0.07
380.1549988	0.86
389.1677551	0.15
389.9489136	0.17
397.0681458	2.18
403.9029236	1.73
408.1492920	0.05
409.7678833	0.11
415.2129822	0.24
423.1531677	0.19
424.2309265	1.54
425.4285583	0.36
428.9800720	0.10
434.0622559	0.48
434.6807251	0.05
437.6258240	0.14
441.0168762	0.15
446.6849976	1.81
447.3112488	1.29
449.0137024	0.06
449.6789856	0.20
451.6078796	0.16
453.3530273	0.07
456.9772034	0.24
461.1384583	0.83
470.0586243	0.05
470.7575073	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1559
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9497528	0.05
205.1066895	0.26
224.1415253	0.08
234.0936890	0.10
245.0421753	0.04
254.2660828	0.14
271.2044983	0.10
272.0876770	0.05
276.2997437	0.05
294.0940552	0.13
295.1441650	0.22
301.0240784	0.05
303.1305542	0.06
317.7996521	0.02
323.0799255	0.89
325.3912659	0.22
327.2802734	0.12
329.2879333	0.15
336.2394104	0.13
339.1805725	0.08
341.1875610	2.01
344.3209839	0.04
363.4149475	0.07
364.9251099	0.05
367.3604126	0.06
370.2701111	0.11
373.1077881	0.05
381.1575928	0.12
383.0729370	0.07
395.8941650	0.12
411.1610107	100.00
413.0216064	0.17
414.3999023	0.07
415.1744690	0.09
420.1560669	0.08
421.1644592	0.24
438.1123657	0.07
439.2812500	0.05
440.3983154	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1221.3733
Annotation	Unknow
Peak:m/z	Relative Intensity
355.0219727	0.13
485.2144775	0.43
503.6400452	0.05
513.2054443	0.13
527.2902222	0.81
528.4144287	0.25
541.4324951	0.31
542.4367065	0.07
545.2430420	1.82
546.3976440	0.04
559.0137329	0.04
643.2069702	0.27
661.2370605	0.77
662.0443115	0.32
675.0160522	0.62
679.2200928	1.51
680.3679199	0.40
693.1989136	0.08
695.1631470	0.17
703.2733154	3.93
704.1949463	0.20
721.2019653	26.29
722.3244019	4.73
735.3825073	1.85
736.6742554	0.14
801.4215088	0.08
838.2661133	0.04
855.2764893	2.52
856.1904297	0.82
883.3941650	0.84
887.1539307	0.05
897.1756592	100.00
898.3400879	33.39
913.6378174	0.15
979.1485596	0.39
1028.3225100	0.15
1035.4736330	0.09
1059.2657470	14.39
1060.2514650	3.54
1083.3927000	0.19
1161.4056400	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.1704
Annotation	Unknow
Peak:m/z	Relative Intensity
194.0946655	0.11
239.9687500	0.02
287.3305359	0.03
312.0543823	0.06
325.2571411	0.03
331.1598511	100.00
332.0214539	0.00
338.3866882	0.01
339.3663940	0.02
340.0701904	0.01
342.3815308	0.01
376.3004456	0.00
407.2731018	0.02
425.9049988	0.01
439.3917847	0.03
440.2199402	0.06
444.1413879	0.02
448.0247498	0.01
469.2842102	0.02
487.1073303	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.18
Annotation	Tanzawaic acid E
Peak:m/z	Relative Intensity
93.02474213	0.44
123.5382843	0.17
138.9385071	0.04
141.1365967	0.42
142.9634399	0.13
148.7231903	0.12
157.1321106	0.12
177.0761566	0.26
182.88591	0.23
185.0623169	0.19
187.1533356	0.10
193.1488037	0.43
195.0997009	0.19
198.9563293	0.08
201.2007141	0.11
203.2906189	0.53
204.8936462	0.18
205.8591614	0.29
206.9655762	0.08
209.0724182	0.31
217.104126	0.18
218.0995789	0.42
219.0546875	0.16
221.0249939	0.19
227.1891785	0.70
229.2191162	0.37
230.3947754	0.10
232.8920898	0.42
243.2258301	0.25
245.09552	2.89
246.0999756	0.30
251.0431519	0.15
252.4394836	0.50
253.2666626	0.16
253.9860229	0.16
255.3811035	0.36
259.0827026	0.64
260.1403198	0.27
261.1290283	0.95
262.074646	0.48
271.1766357	100.00
271.9267883	0.53
273.2293396	2.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.3481
Annotation	Nicandrose E
Peak:m/z	Relative Intensity
215.0591888	0.03
235.2185516	0.07
251.1673279	0.07
287.2082825	0.05
297.1860962	0.09
305.4431152	0.13
353.2835693	0.03
375.2163086	0.03
395.1629639	0.06
397.2493286	9.59
415.2908325	2.35
435.3414917	0.06
454.1455688	0.04
469.2339478	0.02
483.0878296	0.02
497.0040283	0.05
499.4252319	0.06
521.6336060	0.06
593.5020142	0.05
598.4889526	0.02
601.3339233	0.05
611.7100220	0.04
632.5640259	0.05
634.3673706	0.02
649.2064209	100.00
649.9686279	0.15
656.9532471	0.07
675.4679565	0.18
676.8939209	0.39
695.9177856	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.1185
Annotation	Unknow
Peak:m/z	Relative Intensity
160.2973022	0.09
161.3922424	0.03
168.9918213	0.30
172.7385559	0.05
176.9255066	0.11
180.6469727	0.18
183.1398315	0.20
184.9413605	0.24
192.6464233	0.09
194.8896790	0.40
197.1234589	0.24
198.9953461	0.26
202.7679749	0.38
205.0534515	0.22
206.9968567	0.07
212.9459076	0.96
215.3361206	0.03
222.5174866	0.03
224.9670715	0.62
229.0948181	0.37
230.0726166	0.04
230.8165131	0.14
232.5558777	0.13
239.0542603	0.33
242.9205627	0.17
245.0592041	1.36
248.9780731	0.24
253.0510101	0.27
257.0486145	0.67
258.7790833	0.35
260.6766968	0.15
262.9635010	0.43
269.0038452	0.27
271.1143799	4.91
273.0552368	1.07
274.9978638	17.54
278.9453735	0.18
287.0648499	3.67
289.0848389	1.04
292.6669312	0.21
297.0378418	0.90
299.2445068	0.37
302.2664185	0.11
302.8715210	0.05
304.9739685	13.89
310.8189087	0.11
315.0573730	2.61
315.6796875	0.06
317.0449829	2.28
322.9400024	0.85
329.1801758	0.32
333.1597290	1.52
335.0248413	20.16
341.0514526	8.42
347.0517578	0.95
350.1182251	0.07
355.3010864	0.04
359.0294800	25.21
360.7403564	0.04
362.2146606	0.20
365.0055542	5.34
366.6855469	0.09
377.0779419	80.06
377.6967773	0.71
379.9334717	0.04
383.1759033	0.11
385.2622070	0.18
386.7824097	0.14
393.2315674	0.75
395.0089722	100.00
395.6915283	0.29
397.0012817	0.03
404.1784668	0.12
407.1710815	0.06
409.2762451	0.06
412.7879028	0.15
419.1321411	0.21
422.9674683	0.18
424.5769043	0.09
427.1456909	0.16
428.3339844	0.36
437.0060425	1.41
449.0368652	0.36
451.3875122	0.04
453.3376465	0.19
467.2261963	3.62
479.1719360	0.11
491.8342896	0.12
518.3587036	0.07
521.1755981	6.59
526.8304443	0.10
539.1160889	51.61
539.9323730	0.39
568.6962891	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2621
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
153.1102448	0.06
179.2385559	0.02
196.0380859	0.14
214.1274414	1.93
233.1575317	0.47
241.4668884	0.02
259.4344177	0.11
275.2986145	0.36
277.2409058	100.00
277.8492737	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.18
Annotation	Tanzawaic acid E
Peak:m/z	Relative Intensity
92.87976074	0.13
110.0770721	0.13
113.0272369	0.11
130.8546295	0.13
142.894165	0.12
144.9957886	0.30
150.7664185	0.05
157.1495514	0.12
160.7996826	0.28
164.2738647	0.13
175.0385132	0.12
176.1173096	0.22
187.9677734	0.16
189.0957031	0.13
199.308197	0.06
201.2477417	0.06
203.2983093	0.14
205.0854187	0.13
215.4311218	0.09
217.2543335	0.57
218.0926819	0.11
218.9961548	0.07
227.0953064	0.05
228.2591248	0.10
229.0308838	0.72
231.1507874	0.46
242.7571411	0.15
243.4885559	0.08
245.0993347	1.09
246.0808105	0.08
247.269165	0.58
250.8062439	0.06
252.1377563	0.22
253.1157227	0.29
253.8216553	0.20
258.9060059	0.41
261.1025391	1.24
262.1036987	0.16
271.1785278	100.00
271.9511108	0.11
273.1614075	3.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2838
Annotation	Dehydrophytosphingosine
Peak:m/z	Relative Intensity
90.9878235	0.20
95.0196228	0.35
97.0758667	0.23
97.7442932	0.08
102.1667023	0.07
105.0125580	0.49
106.9695511	0.11
108.9173889	1.38
111.0043488	0.48
111.9936066	0.07
119.0271225	0.10
121.0417099	0.81
123.2008209	0.90
125.1526489	0.57
132.9862976	0.39
134.9949951	0.74
136.8893585	0.92
139.1628113	0.09
141.0169678	0.35
147.1354980	0.62
149.1207581	1.44
151.0354004	0.27
155.0469666	0.07
156.1277771	0.63
161.1262512	1.49
163.1430054	0.65
165.1180725	0.43
169.1208191	0.17
171.7676392	0.21
175.0114899	0.65
178.9328613	0.23
191.2730408	0.51
198.1406250	0.29
202.3472748	0.25
203.2989502	0.11
205.1287537	0.08
207.2509460	0.68
211.1681213	0.06
219.1835938	0.14
219.8601074	0.17
221.0443115	1.22
225.0473022	0.08
226.5591125	0.18
233.2403870	2.20
235.3037109	0.22
237.1010437	1.09
239.2490234	1.47
242.3387756	0.74
245.1945801	3.62
247.2047119	0.05
250.4207764	2.11
251.2138977	3.42
252.2018127	0.14
253.3100281	0.04
254.3291321	0.68
255.1840515	0.61
256.2205811	0.18
257.1001587	0.49
261.2122192	0.23
262.3585815	4.27
263.3164978	4.12
267.0692139	1.35
267.6834106	0.10
268.2875061	2.24
269.4385986	0.18
271.0859985	0.84
274.5220947	0.37
280.2326660	70.27
281.1492004	2.21
285.1143799	0.30
285.8122559	0.31
298.3082886	100.00
299.0353394	4.16
301.8814697	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.1
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
155.0691986	0.22
163.1095581	0.14
197.2373657	0.19
205.1508484	0.07
213.0508575	0.16
291.3453369	0.31
300.8879395	0.54
319.1599731	100.00
339.3787231	0.32
342.9171143	0.33
345.6311035	0.20
347.1617126	0.52
361.2487488	0.73
374.0220947	0.57
374.9022217	0.12
381.2309570	0.41
393.4057922	0.25
399.2966003	0.31
400.9837341	0.26
419.2930603	0.16
427.2684937	0.16
435.1045837	1.31
435.8297424	0.54
437.2829590	1.48
442.9110413	0.15
457.5048828	0.68
462.4756470	0.57
463.3256226	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.1802
Annotation	1-O-E-Cinnamoyl-(6-arabinosylglucose)
Peak:m/z	Relative Intensity
131.1457977	0.12
135.1100616	0.87
139.2728577	0.37
144.2026062	0.14
145.0692444	0.34
148.1561279	1.15
152.9737091	0.28
154.0747986	1.85
158.8997955	0.03
163.0948486	7.71
167.1046143	0.56
173.0366211	0.32
180.2627258	0.06
187.2087708	0.38
188.9741821	0.21
193.3358459	0.10
195.0008850	100.00
205.0707092	0.43
207.2158356	1.04
211.8179016	3.77
212.8403625	0.30
215.1704559	0.15
217.1596069	0.89
219.1164551	2.57
221.2153625	0.28
224.1856537	0.45
230.0028687	0.68
230.7444153	0.55
237.1484985	1.65
243.0075684	0.27
248.0456543	5.66
249.0296326	0.87
257.1304016	0.72
258.9537354	0.35
261.2115784	3.43
266.0725708	8.97
267.0727844	0.11
271.2239075	0.12
275.0058899	0.55
285.1194458	4.91
289.2501221	0.07
303.1798096	20.14
310.0101318	0.19
313.1181030	0.10
316.0516357	0.29
319.0819702	0.07
320.5591125	0.44
321.2135010	0.83
328.9241943	0.07
341.2758179	0.26
354.4518433	0.35
355.3434143	0.50
356.9244690	0.07
361.2570801	0.89
367.3746338	0.11
371.1336060	0.18
378.9262085	1.35
381.2495422	0.04
386.1054688	0.10
388.0117493	0.12
389.0839539	8.78
407.0732422	11.40
411.0970764	0.21
419.1615295	0.27
423.0882263	0.06
425.0063782	6.85
428.0811462	0.41
438.0610352	0.03
441.0653687	0.47
442.8852234	3.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.2475
Annotation	(1alpha,2beta,4abeta,5beta,8aalpha)-(+-)-decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-1,5-naphthalenediol diacetate
Peak:m/z	Relative Intensity
142.9105530	1.53
178.8639374	1.97
181.3462524	0.32
182.7870789	1.32
211.0267334	5.99
215.3324280	1.27
224.2163696	0.73
256.5380554	0.64
272.9902954	1.48
291.1136475	3.81
295.0563354	1.26
305.1981812	22.65
323.1424255	100.00
323.7568970	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0338
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
129.0857391	0.02
133.2310333	0.04
134.9411774	0.03
136.1880493	0.06
136.8387909	0.08
146.8664093	4.90
156.8097382	0.05
164.2518158	0.12
170.0791779	1.32
174.8170929	100.00
175.4273224	0.45
184.0658417	0.28
192.3882904	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1866
Annotation	Unknow
Peak:m/z	Relative Intensity
129.2165070	0.09
130.8183594	1.55
138.9519043	0.16
148.4898376	0.51
156.9365540	1.05
159.0947266	0.22
163.2821808	0.26
172.9781189	0.08
174.9588318	4.97
177.2695312	0.07
187.0656128	0.53
193.0634613	9.10
197.2244110	0.45
205.0843811	0.33
213.2684479	0.08
231.0866394	3.22
249.0362244	23.53
267.1203308	0.83
288.8522949	0.25
306.7854919	0.30
315.1983337	1.79
333.2155457	32.25
346.0762939	0.20
351.2640381	100.00
375.1244812	1.85
389.3628235	0.24
417.2609863	12.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.1638
Annotation	Unknow
Peak:m/z	Relative Intensity
294.1868286	0.59
295.1372681	0.45
306.0183716	0.23
340.0062256	0.43
341.0192261	0.86
353.2330933	0.76
367.1394653	0.83
369.9791870	0.26
371.3496094	0.20
385.1186523	100.00
385.7714233	0.37
460.5462036	0.16
475.1359253	0.25
504.0065308	0.63
506.3087769	0.52
521.3165894	0.74
533.2124634	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8642197	4.71
115.9510345	1.68
117.0016937	3.28
130.9716187	0.41
132.9364014	0.10
158.9276733	100.00
159.9031677	43.78
160.8928223	74.02
199.2288513	0.11
200.2719116	1.56
201.0076599	2.81
217.0486450	0.04
217.9817505	0.26
218.9408569	1.00
229.8793945	15.91
230.9966125	39.19
246.0200500	0.18
247.0513916	0.87
256.8546143	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2919
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
179.9719086	0.04
256.9489746	0.03
282.2625122	0.47
313.3093872	37.15
313.9252930	0.14
353.2634888	0.12
392.6998596	0.37
393.3365784	2.81
411.0378723	0.27
418.2806702	0.12
423.0195007	0.02
436.1813660	100.00
436.8574524	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	588.9
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1430054	0.23
229.1504822	0.20
245.0064697	0.11
255.2471619	0.14
273.0075378	1.65
273.8810120	0.27
386.8838501	0.86
387.8970947	0.20
389.3622437	0.09
402.7218018	0.14
426.9977417	1.22
428.1783447	1.74
429.0548706	3.25
472.8999634	2.57
473.9445190	0.94
474.9967651	2.14
493.4522095	0.15
501.5868530	0.20
516.0834961	0.18
541.8438110	68.52
542.8279419	100.00
543.7593994	0.05
544.9544067	0.25
557.0195923	0.10
559.9861450	0.30
560.6195679	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.221
Annotation	(plusmn)8-GINGEROL
Peak:m/z	Relative Intensity
90.77736664	0.32
96.91831207	0.14
109.0752182	0.36
110.6949997	0.19
112.8335114	0.26
115.0882111	0.15
120.8526993	0.23
123.0859222	0.38
124.9907532	1.57
126.708725	0.09
129.2160187	0.16
131.013916	0.64
133.1255646	0.48
135.0076599	1.43
143.0537109	0.13
148.9988098	0.93
150.1766968	0.17
153.1637573	0.16
154.7382202	0.42
157.1613464	0.37
159.2825928	0.12
161.125824	0.39
163.2609863	1.12
165.1403198	0.80
167.1979675	0.20
169.0454102	1.40
175.1863556	0.48
176.8425293	0.12
179.0908051	0.22
179.8421631	0.23
180.9013977	0.64
183.1421204	0.13
185.095459	9.39
187.080658	0.08
189.2838745	0.27
191.0131226	0.31
193.2618713	0.89
197.0654297	0.21
201.1455688	0.27
203.3509827	0.28
205.2419128	0.54
206.8764038	0.11
209.0662231	2.47
211.2710266	0.24
220.7783203	0.20
225.1233826	5.25
227.1245728	0.25
234.7221375	0.51
236.9577026	0.55
241.0898438	0.99
242.7774658	0.47
245.3990784	0.38
247.1345215	0.17
249.2658997	0.18
250.5907288	0.54
251.3713989	0.15
253.3554077	0.08
255.2970886	2.29
263.2171021	1.93
265.2225037	0.54
266.1590271	0.24
267.2982483	1.78
268.2420349	0.11
273.1279907	10.79
273.7286987	1.16
275.0968628	0.27
276.8997498	0.60
277.9763184	0.38
281.0322266	0.15
281.7106628	0.32
287.4837036	0.57
288.9972534	0.27
291.2578125	45.89
295.1132202	0.71
303.5632324	0.11
305.2157593	100.00
306.3409729	0.18
308.2514648	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9779510	4.47
130.9822845	0.24
142.9053040	0.13
158.9072723	100.00
198.9615479	2.52
201.0829163	0.05
216.9210815	0.49
228.9248352	24.08
244.9155273	0.52
255.0462341	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.4137
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
207.1731262	0.15
258.9176636	0.18
275.1903992	0.29
278.4334106	5.74
293.2349854	0.66
303.3022766	0.24
321.0719604	0.48
337.2825317	1.74
338.6672974	0.26
350.1608276	0.30
356.4046021	0.44
359.2622681	41.45
359.8908691	11.16
436.3814697	0.24
437.2564087	0.27
440.3215942	2.67
455.3146973	1.55
499.4621582	0.73
500.1616211	0.19
501.7217407	0.75
506.4487305	0.21
517.6980591	0.16
521.8344116	1.30
536.5560303	16.87
541.4986572	0.15
555.3349609	0.92
557.9615479	0.65
616.3002319	0.59
617.6024170	100.00
630.3433228	1.33
637.3112183	0.50
661.8408203	0.53
663.4750366	0.89
678.3977661	0.43
679.2096558	0.30
681.2797241	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.1925
Annotation	Paratunamide B
Peak:m/z	Relative Intensity
159.1142426	0.16
160.3337708	1.66
170.0505829	1.04
188.0949402	31.81
204.9924774	100.00
222.0616150	0.11
283.9514771	0.29
284.9379272	0.49
289.3686523	1.37
291.0700073	0.39
295.9418945	0.75
309.4592285	0.18
325.2187500	0.68
332.3589478	0.38
342.5661011	1.96
343.3960571	0.41
367.1439209	1.83
385.1398315	6.93
412.3787842	0.76
414.2003784	0.80
415.5773315	0.18
430.8187866	0.49
454.4066162	0.45
456.3926392	1.03
459.4832764	0.34
482.2986450	1.20
485.4108276	0.11
492.3977661	0.25
500.3356934	0.76
501.0917969	0.70
502.6694946	0.67
517.9927368	0.52
518.6281738	0.99
527.2896118	0.19
528.1087036	0.42
529.1983643	2.33
530.4052734	1.24
547.1050415	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.3519
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
221.2161865	0.18
223.3955383	0.08
232.6101532	0.09
235.0802155	4.20
245.0616455	0.27
253.1595764	0.30
262.9116821	0.30
269.0088501	0.14
277.0188904	0.05
279.4049377	1.74
280.2862549	0.22
287.1471252	2.77
288.2952576	0.57
305.1376953	5.19
306.2633667	0.04
313.1973877	0.13
321.2204285	0.15
323.1198730	1.14
332.9767456	0.17
341.4284058	0.07
360.8774414	0.14
379.1268921	0.25
397.2009888	100.00
398.2561646	10.04
415.2158203	31.28
416.2813110	3.13
432.9851074	0.08
669.9121704	0.10
677.2364502	43.09
678.2193604	6.87
678.8779297	0.20
695.4044189	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.1393
Annotation	Dalmaisione A
Peak:m/z	Relative Intensity
199.0974274	0.07
201.0021057	0.09
213.2125244	0.02
229.1069336	0.08
259.1667480	2.36
272.9864197	5.91
301.0681152	0.14
327.2333374	0.42
371.2638550	0.67
373.0770874	100.00
382.1674805	0.04
387.1133423	0.16
394.7092896	0.02
405.0598755	0.15
410.8964233	0.11
412.9191895	0.18
421.1093750	0.04
423.2120972	0.04
425.1012573	2.66
439.9358521	0.01
455.2317505	0.05
458.7975464	0.09
467.0513916	0.02
468.9718018	0.15
471.3873291	0.04
473.3219604	1.92
478.9146118	0.16
484.6372070	0.02
495.3571777	0.04
511.2650757	0.05
518.5360718	0.05
538.1111450	0.03
540.3712158	0.26
541.0244751	0.39
543.1846313	0.15
543.9754028	0.08
550.4090576	0.03
568.2355347	0.32
569.0215454	0.09
570.1013794	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	448.2465
Annotation	N-Acetyl-leu-leu-tyr
Peak:m/z	Relative Intensity
140.1787872	0.07
152.9633636	0.19
160.8614655	0.02
171.2788391	0.01
183.0093384	0.01
195.1821289	0.01
196.1261597	0.34
197.0785522	0.02
210.2256165	0.01
214.1445923	1.96
215.1713257	0.21
233.3425140	0.16
234.1126404	0.05
251.2360535	100.00
252.2234192	13.81
255.0654602	0.00
277.9665833	0.01
280.2898560	0.00
283.2476807	0.02
293.2011719	0.01
298.3782349	0.01
307.2882385	0.02
317.5405884	0.01
336.0645447	0.01
340.4463501	0.01
350.6006775	0.01
351.4854736	0.01
355.3887329	0.02
362.2568359	0.01
363.2197876	0.02
365.1916199	0.01
369.5372620	0.01
370.3136902	0.01
372.2392883	0.01
375.6109924	0.01
376.5354004	0.01
384.2699280	0.01
388.5550842	0.02
391.3741760	0.05
392.3746338	0.02
402.3210144	0.01
404.1253967	0.05
405.1643982	0.02
406.3071594	0.00
410.3069153	0.01
411.1925964	0.11
412.1234131	0.12
413.1546326	0.06
414.2718506	0.02
430.3089294	0.05
431.2734070	0.10
446.9509888	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1346
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.5615234	0.04
175.0763245	0.11
176.9850922	0.21
178.9226379	0.09
185.1596069	0.09
187.1001129	0.12
188.1817932	0.13
202.3685608	0.36
203.2293091	0.40
204.9329834	0.31
206.1347961	0.10
207.0837402	0.10
220.7901459	0.22
227.1675110	0.11
229.2314148	0.19
231.1893616	0.17
243.1186676	0.65
245.2148438	4.81
246.2775269	0.04
246.9788513	0.46
255.1159973	0.09
261.1113281	0.14
269.2133179	0.46
271.2255554	0.65
273.1401367	1.97
281.1809387	0.24
282.2026367	0.15
285.0730591	0.27
287.1130981	5.65
288.1782227	0.23
289.1210938	22.37
290.3898926	0.27
295.1425171	0.12
297.3508301	0.16
299.0263062	4.36
300.9706421	0.09
305.0917358	0.28
313.3714294	0.05
328.9784546	0.24
331.2111206	0.47
339.2586670	0.63
341.1765747	0.28
348.2453613	0.04
351.1083374	0.06
357.2393188	0.87
363.0427856	0.09
365.4225464	0.10
366.8565674	0.33
369.4739380	0.07
371.1293335	0.07
381.1739502	1.80
393.0739746	0.43
401.2502441	0.21
405.0891724	0.32
407.1539307	57.14
408.3544922	0.13
409.2572632	0.58
410.2933350	0.16
411.3996582	0.58
413.2322998	1.00
414.5452271	0.21
415.2416992	0.20
416.2136841	0.22
419.0180054	0.11
423.2025146	0.41
425.1458740	100.00
426.0167236	0.03
431.3297729	0.19
432.1794434	0.27
433.6585693	0.76
437.1839600	0.07
443.0765381	0.09
444.0549316	0.15
449.1555176	1.42
451.2260132	29.01
452.0647583	0.39
454.2719116	0.14
455.0863647	0.11
467.2836304	1.44
481.3409424	0.08
482.5736694	0.21
491.3128052	2.57
492.1979370	0.24
493.6664429	0.22
495.4622192	0.10
500.3330688	3.43
501.2956543	0.34
508.4561157	0.26
512.2108154	0.20
515.0109863	0.25
515.6561890	0.06
516.2756348	0.07
525.8988647	0.08
527.2041626	0.16
531.0451660	0.28
532.3350220	0.29
533.2962036	2.22
534.3679810	0.08
538.2053833	0.14
539.3037109	0.65
540.2374268	0.67
541.2227173	0.17
545.1074219	0.05
557.4523926	0.04
559.1697998	11.41
567.1266479	0.51
568.2113647	0.05
569.1704102	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	792.2502
Annotation	Unknow
Peak:m/z	Relative Intensity
242.1201172	0.11
288.0441895	0.12
306.3262634	0.45
340.1869507	0.04
341.1806641	0.23
348.0919800	0.27
356.0997925	0.07
378.3480225	0.10
390.3297119	0.13
423.4268799	0.25
434.3437500	0.15
447.1661987	0.13
450.0307617	0.51
468.2282715	2.74
472.2341919	0.10
505.1242676	0.23
532.0127563	0.06
553.5701904	0.06
568.9796753	0.06
571.0264282	0.37
575.4640503	0.12
578.2875366	0.49
596.3930054	0.58
606.5184937	0.41
609.1112061	0.10
610.5109863	0.17
612.3970337	0.52
627.2853394	0.04
630.2812500	100.00
643.2019653	0.31
671.2141113	0.06
676.3394775	0.11
701.3917847	0.12
730.5165405	0.17
748.5209351	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1287
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
88.7268524	0.05
95.1334915	0.19
111.0132599	2.50
112.9161377	0.07
123.1356201	0.31
125.0983887	0.12
131.7874451	0.07
133.1031647	0.26
134.8861084	0.11
137.1945953	0.07
138.1960754	0.08
138.9846039	0.08
150.9617767	0.12
153.0476532	100.00
158.8493805	0.07
161.0790863	0.78
165.0973358	0.19
172.7513580	0.19
176.5404968	0.12
177.2989044	0.25
178.9959106	0.05
185.2408295	0.17
189.3251038	0.36
190.9134827	0.28
191.8901520	0.26
201.1035614	1.59
203.1136932	0.27
204.2370148	1.67
205.2400055	0.27
217.1422424	0.27
219.1911469	28.58
220.9851990	0.78
233.2299042	0.34
234.0856323	0.10
234.9799042	0.04
243.2569733	0.19
244.1560516	0.98
245.1874390	1.15
247.2257080	0.15
261.0816650	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.3754
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
199.1327057	0.10
202.7539978	0.03
216.9967651	0.12
219.0671387	0.34
220.1557465	0.05
221.0996704	0.38
226.8532410	0.03
233.2728729	0.08
235.1598816	5.84
236.0364075	0.27
245.1359863	0.37
251.1063843	0.06
253.1437378	1.37
254.1845703	0.06
261.3069763	0.02
262.9311218	0.26
271.3551025	0.10
277.1064453	0.02
279.2631226	3.21
280.0641785	0.23
287.1753540	3.88
293.1303101	0.07
301.0595703	0.07
303.2027588	0.13
305.1354370	5.70
306.2211914	0.04
323.0932007	1.25
323.9296265	0.08
332.9705811	0.04
336.6939697	0.08
349.4625854	0.06
351.5097046	0.02
361.3405762	0.03
378.9791870	0.21
380.1141968	0.03
397.2453613	100.00
398.2658691	2.96
406.1030273	0.05
415.2730103	33.25
416.3312988	0.90
640.1445923	0.03
659.5415649	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	430.2019
Annotation	7-Benzylidenenaltrexone
Peak:m/z	Relative Intensity
137.0272980	0.08
144.9585266	0.08
160.8412018	0.40
172.9727783	0.12
175.1079102	0.21
183.1965332	0.14
195.1858978	0.08
198.1777802	0.06
199.3783264	0.12
201.0803070	0.12
202.2072449	0.06
233.0176392	5.40
235.7307434	0.09
247.1028442	0.05
248.6229553	0.05
250.2167358	0.24
251.0646667	0.27
267.4857483	0.18
268.3910522	0.23
271.0837097	0.34
271.9373779	0.17
283.1027527	6.00
285.1098328	0.21
300.1786804	100.00
301.3543396	0.07
309.1695557	0.35
310.3548279	0.07
330.1558838	0.23
331.6495056	0.17
353.3985291	0.06
366.9996338	0.08
371.0387878	0.10
376.7870483	0.18
381.2433777	0.08
383.2991943	0.15
384.0584412	0.17
385.0339966	0.17
390.7233582	0.04
392.4664612	0.16
393.5660400	0.61
394.3500061	0.37
395.0204163	0.29
398.8092957	0.15
402.1236572	0.10
411.1051025	0.44
412.2792053	10.35
413.3895264	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	357.2993
Annotation	Stearoyllactic acid
Peak:m/z	Relative Intensity
103.0033112	0.09
120.7284470	1.08
123.2410965	0.07
125.0129929	0.69
126.9478683	0.20
129.0596161	1.04
132.9505768	0.48
135.0181274	0.76
137.1864929	0.28
146.9544983	0.19
149.0280151	0.70
151.0093842	1.74
153.1355286	0.72
157.1621552	0.62
161.1086731	0.52
165.0942688	0.84
167.1116028	0.31
168.7880554	0.50
170.8875122	0.36
177.2729187	1.79
180.8926239	0.61
183.0657043	0.34
185.1336670	0.59
186.3323517	0.33
191.1029663	1.46
195.1217651	2.13
199.0757751	0.94
203.2113190	0.11
205.1865234	0.21
209.3018036	0.08
213.0397949	0.54
219.0649109	0.46
221.3455811	0.16
223.3516235	0.07
227.3253174	0.80
239.0565186	0.44
240.0646667	0.36
241.0845032	0.82
245.3908386	1.03
247.1803894	20.99
249.2572937	0.23
257.3629456	0.48
258.8111572	0.23
263.2800903	0.71
265.2532349	65.98
266.8255615	9.31
267.5208130	0.60
273.2547607	0.37
274.5174866	0.92
279.3163757	0.09
283.2050781	39.33
293.8411255	0.59
294.4912109	0.48
301.0939941	0.47
303.2628784	0.14
311.1776428	0.28
314.1623535	0.38
315.5004272	0.83
321.2070312	1.65
325.6972351	0.22
339.2495728	100.00
340.4159241	3.49
348.6891785	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.0667
Annotation	Unknow
Peak:m/z	Relative Intensity
113.0285187	0.07
134.2273560	0.06
140.8519287	8.89
148.7897949	0.17
152.0633240	0.03
156.2156067	0.04
159.2732697	0.07
168.9367676	0.12
173.3622131	0.08
174.8769836	0.04
177.0169373	0.06
178.4559479	0.21
184.8910370	100.00
188.6782837	0.06
191.1721649	0.09
193.1091614	3.94
199.1330261	0.04
203.0275574	4.62
217.0508575	0.93
222.8896179	0.17
223.5297241	0.04
225.3412781	0.03
226.0732117	0.03
231.8964539	0.07
232.9898682	0.17
234.8103027	0.06
237.0583191	0.09
238.6284790	0.06
244.1627502	0.04
249.1901245	0.32
257.6136169	0.10
260.1921387	0.06
267.1948547	0.06
273.2537537	0.15
276.8663940	0.17
278.3574524	0.08
280.6162415	0.10
281.3637390	0.13
283.0360107	0.18
289.0621948	0.22
291.3572693	0.30
297.3308105	0.05
299.1589966	0.27
306.4053955	0.06
307.2135010	0.12
311.0463257	1.16
319.2252502	0.06
320.9966125	0.14
324.2098389	0.23
332.2259827	0.52
333.2747192	1.14
334.1601562	0.60
335.1664429	0.15
336.3722534	0.11
341.1381836	3.00
342.1852112	2.04
343.2931824	0.68
346.4645386	0.08
350.0082703	0.18
351.3352356	0.49
359.0690918	0.08
359.9772644	0.33
361.1571960	0.99
364.3529358	0.24
375.1948242	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	592.2888
Annotation	Unknow
Peak:m/z	Relative Intensity
237.1332245	0.04
250.8538055	0.05
277.0712891	0.03
289.3713989	0.10
305.0906067	0.14
307.1010437	0.13
314.5567627	0.01
315.3688354	0.04
321.3678589	0.20
322.0170288	0.06
323.0182495	0.04
332.2585449	0.02
361.1300049	0.03
363.1004639	0.13
377.3832397	0.02
381.3668823	0.09
401.1527710	0.04
417.1851807	0.09
417.8984985	0.05
419.3314819	0.12
426.5570679	0.03
433.1189575	0.04
435.0009155	0.14
436.3356934	0.05
444.6151123	0.05
447.6855469	0.07
448.4417114	0.12
457.5552979	0.06
461.3025513	0.89
462.4199219	0.29
463.3209839	0.16
467.2079468	0.10
475.4196777	0.07
477.4364624	0.71
478.3453369	0.18
479.3033447	0.07
480.6369019	0.09
487.2391968	0.85
488.3138428	0.16
489.4496460	0.03
494.4284668	1.20
495.2661133	0.11
496.9138184	0.05
497.5972290	0.10
501.4797974	0.07
502.2469482	0.13
504.1432495	0.04
508.0159302	0.09
522.1468506	0.03
532.3005981	100.00
533.2917480	26.59
534.0634766	0.15
539.5302734	0.05
546.2664185	17.12
547.2473145	3.13
548.4314575	0.15
549.3582764	0.27
553.9484253	0.03
557.3129883	0.18
565.7344971	0.04
572.8356323	0.09
574.4589233	0.05
575.2190552	0.02
577.2347412	0.05
593.8559570	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3069
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
157.1522522	0.18
161.0709839	0.22
179.3333893	0.12
219.3728333	0.04
227.5008850	0.03
233.3982849	0.35
235.0934448	1.54
241.1425476	0.07
242.0679779	0.12
253.1998596	8.10
259.3739624	0.09
275.1801147	0.12
277.2763062	100.00
277.9173584	0.10
329.9448853	0.19
347.5887451	0.15
369.0034180	0.09
382.2238159	0.05
424.9989624	0.09
434.3054810	0.08
439.6505127	0.06
452.2943726	12.34
453.4170532	6.85
455.2227173	0.07
465.2024536	0.07
467.4846802	0.03
469.6849976	0.04
475.2773438	0.08
477.2546387	0.09
478.0353394	0.04
479.5411987	0.03
494.4642334	0.16
495.2896118	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.1327
Annotation	Glucoacetosyringone
Peak:m/z	Relative Intensity
125.0520859	3.79
127.9315491	0.33
128.9622803	0.33
164.2325134	0.38
178.809967	3.09
184.1117096	1.10
195.074585	1.25
197.0761414	100.00
211.0730591	0.79
212.1525116	0.61
217.3469238	1.49
223.1609497	1.01
228.0774841	5.01
242.2810364	0.90
243.2474976	0.50
247.1532593	2.61
251.0571289	0.78
257.1005249	2.38
258.8366699	0.54
272.8757324	0.93
280.6234741	1.84
295.1270142	2.99
312.8964844	1.68
314.2577515	0.40
314.9459229	2.98
327.1956787	2.61
328.6972046	2.42
330.3843994	1.18
331.1174316	2.36
332.5144043	0.43
336.5728455	3.60
340.5805359	2.49
341.405365	18.43
342.2052307	0.48
344.2889709	0.79
349.6697083	0.60
359.0141907	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1080.2325
Annotation	Unknow
Peak:m/z	Relative Intensity
422.2291260	0.66
504.2070923	0.51
527.1612549	0.15
564.2452393	0.27
591.1334229	0.49
626.4782715	0.79
699.1341553	2.32
708.2149658	0.89
741.4757080	0.84
744.3599243	0.48
789.3787231	0.75
799.4152832	0.62
808.1600342	0.49
835.4188232	0.49
844.4605713	1.11
849.8337402	0.22
873.4663086	0.89
899.4739990	0.23
905.5239258	0.58
922.4722900	0.58
925.6607666	1.31
927.7330322	0.85
929.5014648	0.73
930.6375732	1.15
944.9608154	1.51
945.5831299	0.51
959.1282959	2.84
962.5290527	2.79
966.5988770	0.49
974.7567139	0.28
984.0212402	1.27
986.3518066	0.55
987.3380127	0.92
1004.6002200	0.27
1007.7226560	0.57
1008.3737790	0.48
1011.2570800	2.18
1013.7312010	4.92
1019.8236080	2.37
1020.4272460	1.25
1021.7941890	0.45
1035.2700200	1.61
1036.4759520	0.52
1047.3918460	0.89
1098.5892330	1.26
1115.5600590	0.27
1135.1444090	0.53
1147.5842290	1.72
1158.6365970	4.28
1159.4885250	0.77
1161.3811040	0.94
1198.9211430	0.22
1199.7382810	0.58
1212.8670650	1.57
1216.1450200	0.76
1216.8073730	4.26
1222.7591550	0.30
1229.8942870	0.29
1235.0874020	0.96
1235.9760740	0.75
1260.2734380	0.42
1260.8862300	0.66
1277.3048100	0.56
1280.7777100	1.85
1318.3355710	0.35
1337.5377200	0.97
1338.2663570	3.34
1339.0527340	0.70
1365.8760990	1.02
1369.7250980	0.44
1371.4381100	0.37
1415.2362060	0.32
1416.1516110	0.51
1428.9238280	0.18
1437.6182860	0.71
1464.0040280	3.33
1479.7263180	0.75
1512.1160890	0.74
1516.2954100	1.04
1547.0374760	0.48
1623.5743410	2.29
1647.3919680	0.24
1651.8013920	0.96
1677.7281490	0.22
1683.1926270	0.49
1694.5448000	0.22
1738.9786380	0.40
1742.6999510	0.21
1809.2083740	1.26
1851.9744870	0.18
1858.2740480	0.69
1861.2858890	0.48
1870.8399660	0.16
1876.4705810	0.22
1899.8011470	2.20
1902.6042480	0.17
1905.8780520	1.01
1913.5451660	0.97
1915.1369630	0.12
1922.1477050	0.18
1926.7103270	0.16
1930.2136230	10.34
1931.1223140	0.46
1932.5589600	0.48
1936.2302250	3.90
1938.1208500	4.36
1943.8835450	1.40
1950.3732910	0.55
1952.3055420	0.11
1960.8406980	2.75
1965.3841550	0.61
1967.3941650	0.23
1969.8543700	0.24
1971.8231200	2.07
1972.6424560	0.18
1974.8609620	0.27
1980.4997560	0.85
1981.1698000	0.58
1982.5852050	0.36
1984.0762940	0.60
1992.4769290	100.00
1993.1961670	5.64
1995.6629640	10.55
1996.2878420	1.51
1997.0006100	0.89
1998.2600100	1.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2417
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
94.73098755	1.18
97.12507629	0.30
108.8049088	0.78
116.7087173	1.05
123.0667038	0.61
125.1417389	0.55
133.1089478	0.28
137.0794678	1.31
138.9836121	10.18
141.1105652	1.14
142.0342407	0.42
143.2532043	0.23
149.1204224	0.41
165.199234	0.80
169.2097473	0.13
170.0101318	0.36
171.2453003	0.21
178.9438782	1.05
183.1764526	1.20
185.2683105	0.33
188.9457397	0.30
191.1960602	0.22
191.9601288	0.20
192.9319153	0.50
197.0101929	13.19
201.2606201	1.15
203.2441406	0.96
205.3034973	0.48
207.1947021	1.08
209.1609497	0.52
211.2073364	2.16
219.5192566	0.36
221.1928406	2.39
226.2781067	0.84
226.9577332	0.59
232.744812	0.16
233.3887329	0.55
237.0940857	3.92
238.1190491	0.30
239.2670288	20.42
240.9957886	0.33
243.2812195	1.63
251.2578735	1.45
253.1225891	2.79
254.3810425	1.45
255.2615356	2.24
257.0806885	0.67
261.0477905	4.31
269.4067688	0.52
279.236145	100.00
280.2505493	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	893.2438
Annotation	Smilaside L
Peak:m/z	Relative Intensity
329.7210999	0.31
342.9049377	0.20
344.9365845	0.61
360.9852295	0.22
445.3609009	0.13
493.2146606	0.64
519.3137207	1.01
536.9555054	0.11
678.2709351	0.14
713.2310791	2.25
731.3214722	100.00
732.3193970	2.51
811.8141479	0.84
863.4470825	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	429.2982
Annotation	Kuguacin D
Peak:m/z	Relative Intensity
118.0026855	5.31
133.1677856	0.31
140.9979858	5.27
147.2090454	1.38
156.8447723	0.56
173.1259155	0.67
179.02948	14.55
202.9240112	0.51
227.1539917	1.44
229.1171265	1.88
253.7183228	3.03
267.2746277	4.08
269.1806335	0.72
271.5279846	1.85
289.5352783	1.47
299.2876587	0.76
304.9507446	0.44
315.2752075	2.14
319.379303	0.38
325.1719666	1.26
331.3866882	0.72
342.1822205	0.39
349.8920593	1.71
352.9387817	0.63
357.3443909	0.68
358.1608887	1.20
367.4657288	1.46
369.8066711	1.91
375.1460571	4.04
383.437439	3.96
393.4161682	18.24
400.3985901	2.25
409.1559448	0.64
411.2823792	100.00
411.8938904	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0966
Annotation	Ethotoin
Peak:m/z	Relative Intensity
118.0109711	0.04
132.1329498	0.07
139.1722870	0.03
159.0670471	0.20
161.1203461	0.08
162.2474518	0.03
163.1025238	0.08
173.0067902	0.02
187.9946747	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
97.11228943	0.18
106.9756165	0.46
109.2205505	0.22
116.8988953	0.40
121.0478897	2.47
123.0670471	1.36
124.1283417	0.16
129.2008362	0.10
130.6669617	0.20
133.0540771	0.40
135.0653076	1.73
136.5003662	0.18
137.2527008	0.12
140.1756287	0.18
143.1184235	0.49
145.1512756	0.30
146.8997498	0.30
148.9734497	1.55
151.0540771	1.33
157.010437	1.80
159.0021667	1.12
160.9579468	0.20
163.0534515	0.92
165.0722046	1.32
168.9555817	0.88
173.0505829	1.19
175.0154419	0.30
177.003479	0.44
179.1175232	0.48
180.7290039	0.19
183.0663147	0.85
183.7093506	0.14
185.0061646	0.69
187.1165466	1.11
188.8883514	0.29
191.147522	0.54
197.0949707	0.80
199.0629883	0.19
200.9458771	0.94
203.2310944	0.59
205.1243439	0.28
205.7315063	0.35
207.1135254	0.14
209.8283691	0.17
210.8262939	0.59
215.1672363	0.72
217.2390442	0.11
219.2310486	0.22
223.1331787	0.53
225.3183899	0.10
227.2269287	0.54
229.1882935	0.39
231.2447205	1.10
233.0039368	0.55
237.2478333	0.17
241.2459717	0.11
243.34021	0.66
244.1697083	0.13
245.1212463	1.62
247.2488708	9.13
248.8644409	0.10
251.3773804	0.60
253.3429565	0.28
258.5786743	0.54
259.2176514	1.40
260.121521	0.52
262.9278564	0.29
265.1689453	0.50
267.3457336	0.40
269.0985718	0.06
271.5643005	0.32
273.229248	0.27
277.4754639	0.52
279.2269897	0.20
283.0887146	0.38
287.2028809	0.71
291.0631409	0.21
295.2470398	0.93
297.1124878	0.34
299.2536621	3.11
305.2426758	1.81
313.1523438	1.81
317.0255737	0.15
323.2459717	100.00
323.9743042	0.62
328.1709595	0.32
341.1359863	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9196
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9848022	2.58
198.9750671	0.35
217.0416260	0.09
228.9544678	0.49
245.1621094	0.04
273.0385742	45.24
384.0900574	0.04
385.7672119	0.42
386.9508057	100.00
427.1252747	0.11
428.2524109	0.02
457.8880920	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1345
Annotation	Syringin
Peak:m/z	Relative Intensity
112.9876480	0.30
119.1938019	0.13
121.0620956	0.07
128.8813171	0.21
131.0326080	0.07
133.2666321	0.09
142.9949646	0.33
147.0576477	0.09
149.0160828	0.19
159.1646423	0.49
160.9672699	3.14
164.0787048	0.33
165.9570923	0.09
176.0359497	0.06
177.2087402	0.88
178.0689545	1.19
178.9735413	3.87
187.0680847	0.17
189.1031494	0.37
190.9517822	0.27
192.2766113	0.68
192.9909363	2.04
194.0921478	11.22
195.0011597	0.66
200.9403992	0.26
203.3170929	0.02
205.1026001	0.07
206.1057129	0.17
207.0794067	1.24
209.0512238	100.00
209.9906311	5.99
217.1330566	0.35
218.1750488	0.19
219.0989075	0.21
220.9229736	0.26
221.9712219	0.15
223.0927429	0.16
224.9488220	0.03
229.2363586	0.25
230.0509644	0.07
232.9987183	0.19
236.1028748	1.92
237.0838623	0.33
245.1932678	0.24
246.8838501	0.37
248.0634766	0.25
249.0433350	1.91
251.1316223	8.98
260.9712219	0.05
263.0810547	1.20
269.7891846	0.09
271.2078247	0.06
275.0298157	0.26
277.3518677	0.11
279.0081787	0.10
281.1828613	0.51
283.2770386	0.20
291.0044861	0.13
293.0350647	0.35
298.1986694	0.03
307.2464905	0.44
309.4010315	0.17
311.1573486	1.33
312.2524414	0.15
323.0817261	0.03
324.1850281	0.15
325.0414734	0.37
327.2384644	0.05
330.0979309	7.71
330.7087402	0.11
333.3746948	0.07
334.9793091	0.86
339.2561035	1.03
342.1857300	0.15
353.1336060	0.61
356.0185852	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.3226
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
161.0136871	0.08
171.0707550	0.03
179.0080566	0.10
185.0413513	0.02
198.7640076	0.02
216.9691315	0.02
235.1752319	0.87
245.2077789	0.05
253.1498413	6.44
261.3786621	0.06
268.9557800	0.03
279.2656860	100.00
285.2721558	0.04
322.3022461	0.02
339.5043945	0.03
355.5629883	0.04
357.2150879	0.01
363.3535156	0.03
369.4028320	0.05
399.5599976	0.05
403.1752930	0.05
425.1380615	0.03
427.5375977	0.03
428.6798706	0.01
430.0438843	0.01
439.5581055	0.07
443.4021606	0.03
452.5291138	0.03
453.5404663	0.06
455.3079834	0.06
478.7108154	0.13
479.3483276	0.01
480.2775269	0.06
497.1427002	0.13
498.3275757	0.07
500.2044067	0.03
514.4443359	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.3908
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
199.2674713	0.11
203.1505585	0.25
216.9998474	0.13
218.7951660	0.27
229.4081726	0.09
231.1904602	0.23
235.1885681	5.26
236.1810303	0.41
241.0856934	0.10
245.3107605	0.85
253.1699524	0.61
259.1506958	0.10
262.8775635	0.04
277.3589172	0.28
281.3136597	3.15
282.3087769	0.36
287.1928101	4.65
288.0738525	0.68
303.2411499	0.08
305.1419678	6.44
306.0777283	0.97
322.0736084	0.06
323.2086487	0.53
324.0414734	0.09
338.0663757	0.13
361.2227173	0.09
362.3490601	0.05
379.1600342	0.26
397.1843872	100.00
398.2844849	8.17
415.1816406	28.95
416.3361816	3.38
478.1876831	0.10
483.3620605	0.07
517.6731567	0.06
535.4096680	0.08
540.4645386	0.08
587.4221802	0.04
591.8231812	0.14
617.5588379	0.11
620.2448730	0.13
625.5710449	0.03
630.4628296	0.35
633.9375610	0.04
636.4353638	0.08
649.1157837	0.13
661.5034790	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1345
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0851898	0.17
164.6734924	0.09
169.1629333	0.09
171.0610199	0.15
175.0360870	0.11
176.9926147	0.25
178.1089783	0.13
188.0653534	0.04
197.1794281	0.08
200.0790405	0.17
201.2099304	0.08
202.9896698	0.56
205.1904144	0.15
209.9451294	0.19
227.1125183	0.27
229.1268005	0.06
230.8119507	0.12
243.2707062	0.55
245.1183777	2.85
246.1107788	0.50
246.9901886	0.16
254.0705872	0.06
255.3247070	0.16
261.2705078	0.08
267.3602905	0.09
269.2172852	0.25
270.2191162	0.14
271.0057068	0.06
272.5076294	0.19
273.1680908	1.84
273.9754333	0.35
281.2395630	0.21
285.0001221	0.12
287.0643311	10.23
288.2800598	1.72
289.1752014	22.67
290.1851807	4.05
299.1898804	6.68
300.0798340	0.70
301.3358154	0.23
303.3755493	0.50
305.2772827	1.09
306.2828369	0.20
311.1950073	0.09
315.2775269	0.33
327.3038940	0.05
329.1084595	0.74
330.2307739	0.05
331.1090698	0.85
332.4436646	0.23
339.3203735	0.48
340.3274536	0.04
341.2784424	0.44
342.3117676	0.35
345.2062988	0.27
350.4971924	0.13
353.2804565	0.37
357.2831421	0.15
360.2111816	0.18
361.2756348	0.06
365.4631958	0.08
379.0115967	0.08
381.1760864	1.30
382.2464600	0.28
389.4040527	0.05
393.4375610	0.08
394.1542969	0.21
407.1566772	51.81
408.2592773	15.03
409.2655640	1.25
410.2231445	0.48
411.6115112	0.25
412.2297363	0.07
414.0954590	0.20
415.2752686	0.10
416.2947998	0.40
423.2527466	0.42
425.1665039	100.00
426.0825195	23.28
427.1190796	0.18
432.2073364	0.07
433.3435059	0.43
436.1331177	0.17
437.1163330	0.22
443.8488159	0.06
449.2838745	1.31
451.1334839	37.31
452.1389160	10.02
452.7649536	0.10
455.4725952	0.49
467.1925049	1.83
468.3512573	0.22
483.2639160	0.21
487.0276489	0.22
489.6248169	0.05
491.5685425	0.10
493.1882935	0.21
496.7241211	0.33
500.9024658	0.54
502.3657837	0.14
515.3010864	0.34
516.1918335	0.21
530.8664551	0.05
532.8098755	0.79
533.6565552	0.78
534.4293823	0.39
535.2161865	0.17
541.2700806	0.12
542.2371826	0.09
555.6602173	0.39
559.2252808	13.30
560.3277588	5.28
561.2807007	0.05
568.3402710	0.72
578.1834717	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9963684	0.23
161.2679901	0.04
174.8460388	0.25
198.9123840	0.04
217.0807648	0.14
228.7066193	0.11
233.0628967	0.03
245.0173035	0.18
273.0518188	6.08
274.0743713	0.20
289.0332947	9.77
351.2918701	0.02
386.9576416	0.66
387.5725708	0.13
400.8677368	0.15
402.9061279	100.00
420.8870850	0.15
442.8619385	0.14
459.9754028	0.01
469.9393921	0.02
470.8975220	0.57
516.9216309	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	589.0676
Annotation	Unknow
Peak:m/z	Relative Intensity
168.8596497	0.23
186.8333130	0.24
199.2181702	0.08
216.8992615	0.78
228.4977722	0.08
243.0091858	0.12
246.7875519	0.25
255.0482788	0.45
257.8188477	0.43
260.9646301	0.16
265.0896606	0.21
268.8947754	0.14
274.1226807	0.40
277.0359497	7.60
289.1427612	2.10
295.0351562	0.70
303.0794678	1.19
305.1259155	0.91
306.9380188	18.26
319.0297852	0.98
324.7719116	0.60
328.9458008	0.43
330.8863525	0.57
336.9287720	6.95
343.0501099	0.08
347.1346436	0.31
348.9630737	1.05
353.1165771	0.13
353.8151855	0.19
354.7551880	0.77
361.0272217	2.65
364.8209839	1.25
366.9550781	23.44
373.0683594	2.77
377.7587891	0.40
382.1687012	2.56
383.1096191	2.46
391.0670166	9.15
395.0705566	0.16
397.0337524	24.33
407.1952515	0.43
408.9307861	58.20
426.0150146	8.26
427.1242676	100.00
441.9297485	0.25
456.4429321	0.20
469.1589355	1.35
499.0739746	2.44
507.8433228	0.37
529.2047119	0.16
544.0283203	4.16
545.1232910	8.63
570.0371704	0.65
570.9813843	6.17
585.0459595	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	246.0982
Annotation	Valinopine
Peak:m/z	Relative Intensity
81.0196762	0.06
93.0214996	0.05
103.0060425	0.03
107.9813538	0.65
111.0225525	0.04
114.8478851	0.04
123.0227966	2.59
130.0724487	2.54
134.1698151	0.06
135.1724701	0.02
144.0013885	0.03
146.2277374	0.05
147.0894012	0.09
149.1321106	0.89
154.0189667	0.02
159.4186859	0.02
166.0549164	0.03
167.0567322	0.05
171.2659454	0.04
175.1871490	0.03
176.9215546	0.48
184.1529694	0.25
199.1283264	0.14
201.1743317	0.02
202.1230469	0.60
203.0716095	0.33
204.2936859	0.06
210.1222992	16.35
212.9408722	0.07
215.9626617	0.03
217.0439148	0.10
218.1368103	0.43
228.0394440	100.00
231.0552979	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1714
Annotation	alpha-L-Rhamnopyranosyl-(1->3)-alpha-D-galactopyranosyl-(1->3)-L-fucose
Peak:m/z	Relative Intensity
133.9908600	0.10
143.3191986	0.03
179.1033325	0.09
193.0966339	1.14
209.1117249	0.08
209.9579926	0.06
220.9810486	0.06
225.1606598	0.03
231.8776398	0.12
245.1452942	0.11
246.2698669	0.09
247.1730347	0.04
256.0375671	0.04
257.0838013	0.02
262.8796692	0.21
273.0703430	0.35
282.2030640	0.04
290.0469666	0.38
290.9856567	0.32
295.1258850	0.01
303.2379761	0.02
305.2210388	0.08
309.2988281	0.01
310.9834900	0.04
315.1681519	0.08
317.2301941	0.07
323.2191162	1.24
335.1622620	0.06
341.1836548	4.08
355.0567627	0.22
357.3383179	0.10
361.1129150	0.03
375.3043213	0.37
381.1119385	0.19
383.2573242	0.05
384.0313721	0.07
385.8281250	0.06
387.1231384	0.16
393.3273010	0.04
398.1188049	0.17
399.2109070	0.09
409.5724487	0.39
410.9492493	0.10
423.2651672	0.08
425.0816956	100.00
425.7530518	0.11
426.4554138	0.06
427.1282043	0.39
429.2322998	0.09
435.1359253	0.10
436.0943909	0.07
443.1264343	0.03
449.0338745	0.29
452.0443726	0.09
452.9735413	0.70
453.8518982	0.13
456.0273743	0.05
456.7847290	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.14
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0844727	0.14
190.2153015	0.26
191.0492554	7.93
213.1449280	0.77
229.3764954	0.14
253.0384521	0.16
258.4844360	0.81
266.1425171	0.31
268.1911011	5.79
269.2130737	14.31
275.9354858	0.22
281.0333252	0.29
283.1334839	0.24
289.1604309	1.33
303.7133789	1.36
307.1762085	100.00
308.0642700	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.0965
Annotation	4-Hydroxyphenylacetylglutamine
Peak:m/z	Relative Intensity
92.9024353	0.14
109.0278320	0.08
115.9160995	0.54
120.1115570	0.22
123.5655670	0.16
133.0847473	0.14
146.9911346	0.17
161.1657867	0.11
162.9188843	0.05
166.0546265	3.85
167.6713715	0.04
170.0239563	0.10
178.0319824	0.15
178.9973145	0.03
204.5293884	0.05
211.5169678	0.23
217.9706726	0.50
224.3560181	0.10
226.0266113	0.27
232.1672058	0.19
236.0097961	75.27
237.1621704	0.25
238.2522278	0.36
239.2317200	0.24
241.1259155	0.18
246.0932922	3.09
247.2048340	0.08
249.8544312	0.04
253.7596130	0.19
254.3875732	0.11
259.9195251	0.16
263.9662170	100.00
265.0314331	0.59
267.1593933	0.32
273.0963440	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1033
Annotation	Juglanoside E
Peak:m/z	Relative Intensity
113.1686096	0.61
125.0205612	0.62
133.9862976	3.83
148.920929	0.83
158.0580292	0.53
158.9006042	1.48
160.0404663	3.81
167.0930481	0.65
175.0882568	39.32
177.8666687	0.42
191.2065887	0.98
193.0419617	100.00
199.0656891	0.44
203.1484833	1.27
207.0337219	1.24
217.0252686	61.48
221.0709229	0.31
233.0379028	0.27
235.1576843	14.50
244.995575	0.59
247.0119019	5.10
257.4346008	0.26
259.0147705	0.69
265.0374756	18.31
270.0231323	0.60
277.0329285	0.16
292.9526672	0.45
295.1837158	15.35
299.0661011	0.21
309.1590576	3.56
310.4328003	1.32
311.270752	0.99
317.9594116	0.30
319.026123	0.97
319.9069824	0.92
327.3548584	0.50
336.9875488	5.83
337.6885986	0.18
340.0605469	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.1325
Annotation	Glucoacetosyringone
Peak:m/z	Relative Intensity
125.1401215	1.24
142.0333405	0.70
146.9754486	1.19
177.2996216	0.42
178.8348694	2.59
191.2517548	0.65
197.0805664	100.00
212.3025055	1.28
215.3183289	0.19
226.9598694	4.93
228.1729126	0.25
239.3605957	1.95
240.1834106	0.62
241.7442932	1.69
244.1637878	0.64
245.2260132	5.10
260.8780518	0.39
262.2069092	0.70
274.125946	0.70
278.5317383	2.34
290.0176392	0.42
291.1165466	1.34
295.2432861	4.62
298.9619751	0.76
300.2181396	2.73
301.7868652	1.67
313.1844482	2.46
318.2468567	1.81
322.0860596	2.73
323.0769043	1.77
323.9641113	2.82
326.9867859	5.94
329.3713074	2.53
336.5605469	9.53
338.3330078	6.14
339.6446533	2.54
340.6789551	4.34
341.3965759	2.60
342.2596741	5.21
344.6482849	1.12
350.2720642	1.26
359.2893066	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	294.0981
Annotation	Indican
Peak:m/z	Relative Intensity
84.8858032	0.10
86.9310608	0.13
100.9337006	0.90
113.7574768	0.10
128.9270782	19.38
130.9082794	0.35
146.9664612	0.04
149.0288696	0.03
155.7068329	0.04
164.0695801	3.64
174.9930420	0.08
176.7992859	0.03
182.8740540	0.27
185.2376099	0.32
188.8084412	0.09
191.1623840	0.07
203.0696106	0.09
204.3139343	0.08
204.9803162	0.10
206.3558655	0.04
206.9745789	0.08
208.4775085	0.12
214.8168335	0.17
224.1825562	0.08
232.3417664	0.10
238.1158752	0.15
246.1888428	0.18
247.6283569	1.28
248.2363586	0.09
249.2548828	0.05
250.1253052	0.54
251.0636597	0.34
252.3281250	0.10
257.3294067	0.15
258.0206909	1.78
258.9049072	0.15
260.0885315	0.04
265.9993286	0.26
267.0593262	0.10
273.0727844	0.26
276.0978394	100.00
277.1166382	0.07
278.9292297	0.33
295.0824890	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0614
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1403351	0.17
182.3832397	0.56
194.1496277	0.36
200.9953156	0.12
204.8878174	0.59
216.9471588	1.37
228.9125977	0.07
235.0153809	0.49
244.9641724	1.00
255.2083893	0.12
275.2033691	0.58
276.9708862	7.69
280.5985718	0.31
289.0886841	1.62
292.8949585	0.11
294.9756470	0.17
303.1552124	1.62
304.6181946	0.96
307.0609436	12.20
319.0443726	2.53
325.1069946	0.36
329.2929077	0.86
330.8643799	0.98
336.9341431	10.25
343.3619385	1.52
347.0259399	0.85
349.0448608	0.49
349.8683472	0.19
355.0446167	0.27
360.7354126	0.79
364.9458618	0.46
366.0084229	1.89
367.0336304	24.28
372.9175415	2.25
379.2501831	1.14
382.1519165	1.05
390.9490356	8.36
395.9418945	1.79
396.9141846	22.89
407.9202271	1.11
409.0946655	58.82
424.9871216	0.12
427.0008545	100.00
456.8214111	0.79
459.2402344	0.45
469.0126953	0.56
498.9618530	1.51
507.4022827	0.32
544.2022095	3.00
545.1699829	6.12
552.2689819	0.66
570.9320679	8.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1558
Annotation	Nervilifordin C
Peak:m/z	Relative Intensity
192.0213470	0.12
193.0478210	0.11
197.1170349	0.17
204.1954041	0.17
214.0569153	0.13
215.0324707	0.06
221.2788696	0.05
226.3680725	0.08
228.2849731	0.06
229.7999573	0.06
231.9360504	0.23
241.0227966	0.14
242.0595398	0.28
243.0574493	0.07
244.2587738	0.09
244.8623199	0.08
259.1320190	0.24
269.1311035	0.04
270.3795166	0.59
271.0944519	2.66
271.9772644	0.17
285.1322021	0.21
287.0937500	3.07
288.1603394	0.49
296.2311401	0.20
298.0904846	0.08
299.2852173	0.02
303.2404785	0.35
311.3623657	0.08
312.1344604	0.12
313.1147461	0.27
316.0712280	80.59
317.2349854	0.25
328.0597534	0.33
329.1132202	0.82
330.0949707	8.24
331.1018372	100.00
332.2387695	0.38
340.1797485	0.11
342.8318481	0.21
345.3358765	0.03
355.2073364	0.13
358.3100586	0.04
373.1427002	1.17
374.2861328	0.24
377.4453125	0.10
385.0114136	0.11
389.0464478	0.07
402.1248779	0.04
403.1223145	0.12
404.4966431	0.09
425.0499878	0.05
431.2996826	0.04
457.5784912	0.07
459.2750854	0.15
462.2199707	0.09
463.2637329	0.05
464.0844116	0.03
475.1939697	0.06
477.5630493	0.77
478.3480225	0.03
479.1837158	0.45
480.1436768	0.31
493.0695190	0.46
509.6762085	0.03
513.4818115	0.23
542.7669067	0.23
565.3889771	0.07
575.7268677	0.03
579.2984619	0.12
587.6868286	0.08
589.0225220	0.11
607.3048096	1.23
611.2698364	0.19
620.3290405	0.13
621.2036133	0.80
624.2344971	3.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.123
Annotation	Eupalinilide A
Peak:m/z	Relative Intensity
119.8604889	1.55
126.0639496	0.13
127.0462341	0.04
127.9616699	16.34
141.0144806	0.04
152.9582977	0.50
159.0322876	0.13
160.5828552	0.17
167.0580139	0.06
171.1641235	0.20
179.0370789	0.32
185.1419678	0.13
186.9525452	0.09
195.1903992	0.23
197.2971802	0.20
201.8082275	0.18
203.0429840	0.03
213.1636353	0.95
215.0431519	1.07
216.0627289	0.16
220.9630737	0.08
224.9911499	0.03
227.1250305	0.11
231.0797119	8.18
240.7490845	0.12
249.1065369	100.00
252.0469360	0.05
258.8335571	0.43
262.9881897	0.22
272.8092041	0.10
281.1153564	0.12
282.0781860	1.47
283.9646912	0.04
291.3438721	0.71
294.3890991	0.07
305.3291626	0.62
312.4620361	0.03
315.0783997	0.06
323.2486267	0.06
325.1433716	0.22
331.0025940	0.04
333.7206726	0.13
349.1889954	0.09
355.3368835	0.06
360.3136597	0.30
365.2209473	3.32
366.8609924	0.73
373.3525085	0.18
374.9814453	0.47
377.2176208	0.15
380.5549316	0.17
383.0583801	0.04
392.9547729	1.71
393.6249695	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.1138
Annotation	Prodiamine
Peak:m/z	Relative Intensity
99.1510696	0.04
113.0035400	2.06
115.1395340	0.05
116.9451752	0.20
139.2170715	0.03
141.0898132	0.07
148.5716248	0.02
152.9808350	0.14
174.9834290	0.45
184.7480164	0.07
187.2978821	0.12
189.1045532	0.03
198.6735535	0.10
203.1531525	0.36
205.0247650	1.00
206.9225769	0.06
223.1053772	0.54
231.0690002	1.31
245.2600708	0.05
249.0723267	35.38
258.9793701	0.08
267.0865479	100.00
267.6948547	0.30
276.8807678	0.03
287.1634521	0.11
288.1305542	0.05
289.0130005	0.99
289.8444519	0.07
290.8692932	0.09
303.2134399	0.48
305.0307312	0.38
306.0295715	0.03
307.3796997	0.20
313.8486328	0.88
320.1092834	0.05
330.0459900	0.43
331.2201538	3.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2841
Annotation	Halisphingosine A
Peak:m/z	Relative Intensity
89.83060455	1.94
94.95713806	0.22
96.92193604	0.30
105.033371	1.07
107.0504532	0.80
108.869751	1.68
118.980278	1.83
120.949173	0.22
135.2532043	1.29
136.2002106	0.83
137.1705322	0.83
138.9468079	0.63
142.2859802	1.32
151.3527832	0.69
162.9838867	3.04
164.1906891	2.11
167.1436768	0.93
169.0868683	0.33
175.1633911	1.92
203.0251465	1.34
216.5579529	1.12
218.1645813	1.61
220.8289795	1.98
225.6463318	1.17
226.9794922	0.59
233.1317749	0.44
236.7695923	0.77
239.2061462	6.64
242.1930847	1.63
244.6483459	1.02
245.3513794	2.59
250.4917603	0.54
251.3981323	0.86
253.1236572	1.13
254.3399048	0.84
262.2424622	4.46
263.2047119	2.02
267.2485046	1.49
268.1850281	1.26
271.3164673	1.59
272.1918335	0.64
275.0788574	0.82
280.2976074	50.45
281.194458	0.60
285.2562866	2.29
298.2794495	100.00
299.1126404	13.00
316.892334	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2678
Annotation	[10]-Gingerdiol
Peak:m/z	Relative Intensity
109.2432480	1.51
117.1113968	0.17
121.0266876	0.51
123.0004425	1.17
131.0220032	0.26
132.7194061	0.89
134.9731750	1.63
137.0491333	1.92
145.0156708	0.33
146.9165344	1.18
149.1478577	2.31
151.0195618	1.99
157.2891846	0.18
159.0503845	0.12
161.1346130	3.45
163.0923157	8.36
164.8260498	5.87
165.8753052	0.24
167.0694580	0.34
169.2129211	0.15
173.0467377	1.39
176.9955444	4.19
179.1443481	2.28
183.0893402	0.89
187.1542969	1.01
195.0252991	0.19
200.9782562	0.53
205.1516113	1.51
209.0606995	0.17
215.0242615	1.31
217.4033813	2.61
219.2582397	1.06
229.2231750	0.35
233.2039490	0.51
243.1936340	34.64
245.2143860	3.04
251.2612000	0.40
253.2726746	0.44
257.1022949	0.74
259.2700195	1.19
261.2527161	100.00
263.2842712	4.78
267.0977173	0.47
269.2712402	0.54
271.3077393	0.83
272.8753662	0.63
275.0437317	0.97
277.6636353	0.45
279.2136841	14.33
291.4516602	0.80
292.9466248	0.42
295.4600220	1.13
297.1412964	1.23
305.0668945	0.23
307.5227051	0.63
308.2101440	0.63
311.5215454	0.77
312.6219482	1.34
317.3845215	4.84
323.4409790	0.31
334.5747070	1.55
335.2761536	65.21
335.9890442	2.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.88
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0990601	0.07
230.0643463	0.24
272.9067993	9.15
274.1265564	2.46
386.9060059	12.77
387.9919434	4.48
498.8483276	0.14
500.8878174	71.50
501.8754883	30.98
569.7225952	0.05
608.9347534	0.87
610.0208740	0.30
610.8948975	0.33
612.8312988	0.40
614.8042603	100.00
615.7866211	56.96
616.6011353	1.03
626.7783203	0.04
627.9323730	0.23
643.8131714	0.05
645.2103882	0.06
653.9378052	0.42
654.9233398	3.66
656.0491333	2.67
656.9022827	0.99
673.0050049	0.81
673.9902344	0.73
674.9766846	0.43
683.0029297	0.94
683.8903198	1.04
684.8173218	0.04
701.1028442	0.37
701.9457397	0.36
703.0473022	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.117
Annotation	Sissotrine
Peak:m/z	Relative Intensity
143.0138855	0.09
158.7061005	0.20
161.0552216	0.17
166.4611511	0.04
178.936554	0.04
190.0717773	0.13
195.3554382	0.03
223.3166809	0.20
224.1637573	0.04
239.1373901	0.26
242.3803406	0.12
249.1731262	0.65
249.8991394	0.42
257.4071045	0.14
261.2050476	0.05
264.0233765	0.04
269.3943176	0.10
271.2574768	0.05
275.2661743	0.08
283.0627136	100.00
284.0431519	31.27
286.1013184	0.26
295.1004028	0.12
297.2381592	0.35
313.2296753	0.13
314.2037659	0.20
315.9782104	0.33
317.258728	0.10
325.3453369	0.14
331.3139954	0.22
335.9559021	0.10
342.4608154	0.33
349.2292786	0.08
354.4677429	0.04
355.3238525	0.24
362.0044556	0.04
365.2675171	0.04
368.4945984	0.06
371.4346924	0.05
374.1827698	0.13
383.1283569	0.03
384.2606201	0.06
387.2441711	0.15
399.9901428	0.16
401.2669983	0.59
402.0327759	0.27
403.1984558	0.16
407.9372864	0.16
409.7455139	0.61
410.3907166	0.34
426.2249451	0.21
427.244812	0.57
428.3198547	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	662.2197
Annotation	3''-Adenylylspectinomycin
Peak:m/z	Relative Intensity
193.0366211	2.30
204.5723267	0.04
214.9648895	0.13
215.8745728	0.11
226.9504395	0.03
233.0994263	0.64
238.0209503	0.03
245.2654572	0.01
251.2942505	0.02
267.8910522	0.77
290.1647949	0.39
291.1943970	0.25
308.0652466	34.16
308.6705017	0.10
338.3294983	0.07
341.1185913	0.28
350.0120850	0.07
359.3584595	0.03
370.9204712	3.12
395.0216064	0.09
413.0850830	0.04
416.2366333	0.22
425.2155151	0.33
434.2336426	0.28
452.1187134	0.09
470.1922607	1.26
477.5731812	0.07
479.2780762	0.01
482.0800781	0.08
482.7548828	0.03
490.9746094	0.04
498.3141479	0.03
500.0593872	100.00
500.6983032	0.61
503.4605713	0.01
533.1765137	0.06
539.1976929	0.09
542.1204834	0.26
565.1813965	0.04
571.1928101	0.05
572.3310547	0.09
577.9160767	0.06
582.3753662	0.02
587.4126587	0.22
607.9558716	0.02
617.0922852	0.03
625.3186646	0.08
626.0776978	0.15
639.8765869	0.10
643.0968628	0.20
644.2545776	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.11
Annotation	Eupatolitin 3-glucoside
Peak:m/z	Relative Intensity
150.9434814	2.36
153.1105804	0.42
163.0932922	0.25
164.9346161	0.20
169.0743713	0.30
174.8661499	0.07
176.9259033	0.54
179.0913239	0.48
179.8362274	0.09
191.7732849	0.09
203.1350403	0.22
205.1422119	0.08
207.0843658	0.11
208.9528809	0.08
218.1583710	0.21
218.9705505	0.72
221.2637329	0.17
228.3131104	0.19
231.0393677	0.37
232.1458435	0.12
233.1183014	0.16
234.1442566	0.37
235.0779572	0.10
236.3200226	0.11
241.1039429	0.16
241.9281921	0.08
243.2801819	0.11
245.1981506	0.32
246.1800842	0.34
246.9921875	0.26
249.3357391	0.10
251.3034210	0.23
257.3001404	0.38
258.1536255	0.53
259.0487976	0.10
261.3054199	0.26
263.0320129	0.18
265.1008911	0.10
269.2585449	0.44
270.1404724	0.24
271.1789551	0.08
273.1201477	1.82
274.0032043	0.06
274.9288025	0.31
276.0926208	0.58
277.0938110	0.43
279.2284851	0.57
283.9490051	0.18
285.2486877	0.09
285.9621277	0.60
287.3369446	0.27
288.2081909	0.09
289.2453308	0.14
291.0565796	0.39
293.3188477	0.20
295.2128601	0.22
297.5543213	0.07
299.1105347	0.14
301.0753784	5.99
302.0364990	0.76
303.1744995	2.10
305.1043396	0.15
311.1853943	0.42
313.2249756	0.18
314.2133789	0.23
315.1563110	2.53
316.1905823	2.93
317.1774902	1.11
319.0871582	0.05
326.0998535	0.17
327.1912842	0.69
327.9725952	0.68
329.1107178	8.20
330.2101746	3.47
331.1140137	0.57
333.4545593	0.49
335.1293335	0.07
338.9288330	0.47
341.2952881	0.22
342.0745850	0.08
343.2477722	5.28
344.1417236	100.00
345.2131042	73.58
346.1595764	5.09
353.2857056	0.23
355.5039978	0.73
357.1550598	0.28
358.2304382	0.74
359.2308655	2.88
360.1878662	0.06
367.1676636	0.28
369.3860168	0.31
370.3427734	0.07
370.9662476	0.11
372.0987549	0.49
374.3831787	0.54
375.6144409	0.20
378.4774780	0.20
387.1885071	20.06
388.1537476	1.18
392.4468994	0.06
397.1395569	0.13
399.0391541	0.48
401.7903442	0.30
402.4098816	0.20
405.0746765	0.08
410.8844299	0.41
413.2352905	0.10
417.1610413	2.31
418.3680420	0.49
421.3565979	0.20
423.6414185	0.07
426.1324158	0.25
429.2846985	0.12
437.3550720	0.14
439.6572876	0.09
443.1541748	0.26
447.0606689	0.11
461.1343689	0.99
463.1892395	0.90
470.9699097	1.21
473.4649963	0.12
475.4101868	0.55
479.2854614	8.18
480.0922241	1.21
488.2976379	0.06
489.1618958	1.41
490.1065369	0.09
492.1737366	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.1548
Annotation	Unknow
Peak:m/z	Relative Intensity
104.0337830	0.27
114.9288254	0.08
122.0557404	0.28
137.0894470	0.76
144.4615173	0.18
157.1629791	0.17
164.0591431	0.21
169.0031128	0.08
181.1405182	0.22
183.9899445	38.12
185.0890961	0.35
195.1760101	0.09
197.2144012	0.32
198.9621277	0.36
225.5670471	0.48
227.0156250	0.21
228.3136902	0.80
230.3647461	0.25
239.0526733	0.70
241.0995483	0.13
252.0559692	0.11
253.0375366	0.12
256.6991882	0.59
258.1873779	0.81
260.6667480	0.55
261.3460693	0.06
267.0409546	0.15
271.0488892	0.17
273.3970947	0.08
274.1253662	2.96
275.2229614	0.26
278.5211792	0.09
283.0584106	0.09
284.4583130	6.42
285.0708008	3.72
286.7548523	0.32
293.4537659	100.00
294.2568054	2.41
295.7023926	0.15
301.3394165	0.10
319.7449646	0.07
339.0455933	0.34
352.3427429	0.42
364.2744141	0.37
377.1681213	0.33
403.2931824	0.78
404.3943176	0.08
408.3302002	0.05
420.3805237	84.03
421.4999390	3.18
432.0700073	0.25
450.3500366	0.88
464.8848572	0.09
471.1893005	0.66
473.8605347	0.14
500.2311707	1.73
590.8523560	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
100.9624329	0.34
105.2657089	0.06
107.1667709	0.12
107.9532547	0.48
109.0328217	0.03
112.9148865	1.32
119.0720215	0.06
122.3407898	0.28
123.0744781	3.46
126.9126968	0.07
130.9033203	0.05
135.0695648	0.07
137.1582642	0.06
142.9854584	0.25
145.2708740	0.10
147.0504761	0.08
150.0842590	0.35
151.0903015	0.28
152.0584564	2.47
160.8746643	0.40
164.9866638	0.36
166.0591736	2.31
166.9831848	93.24
179.1079102	0.14
181.1143188	11.15
193.1782227	0.50
194.1881714	1.19
197.1401215	0.07
207.1347351	0.18
209.0180664	100.00
210.2720337	0.11
221.1575928	0.56
223.0519104	0.25
232.0642700	0.07
232.8525696	0.23
235.2737427	0.08
239.0578613	13.16
241.4230042	0.07
245.0775757	0.19
250.8041992	0.52
252.7454224	0.31
263.1808472	0.68
265.3061218	0.09
269.0867615	36.99
292.9563293	0.08
294.2667236	0.10
299.3359070	0.07
311.3079834	0.39
314.2403870	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.117
Annotation	Sissotrine
Peak:m/z	Relative Intensity
143.1191711	0.01
148.7279205	0.04
161.145462	0.04
179.052002	0.10
191.1793823	0.04
199.0612183	0.04
201.9258118	0.01
204.3754578	0.07
210.6702881	0.07
231.0379639	0.04
243.3562317	0.03
247.0109253	0.07
249.1200256	1.15
265.3257751	0.02
281.1289062	0.05
283.0621033	100.00
289.1488953	0.01
297.1056824	0.03
298.1560669	0.02
326.0658264	0.02
327.039856	0.01
330.1237183	0.03
341.3783569	0.04
352.0610962	0.05
355.105957	0.04
357.1602173	0.17
359.2814941	0.26
365.230896	0.05
373.3930664	0.02
377.0627441	0.05
384.2277527	0.05
387.1106262	0.06
388.0321655	0.01
397.8059387	0.04
399.2183228	0.09
400.7485657	0.04
401.5092468	0.16
403.2054749	0.13
406.0080872	0.04
406.8560486	0.21
407.6493835	0.03
408.2794495	0.09
409.283844	0.34
415.1755371	0.03
417.1234741	0.06
424.1594849	0.03
426.6876526	0.08
427.2880249	0.16
428.2596436	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1193
Annotation	Unknow
Peak:m/z	Relative Intensity
105.0051422	0.06
123.1575012	0.36
129.9971924	0.83
130.8233490	0.03
136.9416199	0.03
151.8426208	0.23
152.8640137	0.21
154.1151428	0.09
167.2481995	0.02
178.9707947	0.02
183.1583252	0.03
188.6016235	0.07
191.1844330	0.08
193.0615234	0.07
209.9237366	0.20
211.9122009	0.07
213.1186523	0.03
215.3280334	0.11
217.7638245	0.04
219.8041077	0.10
224.2494812	0.09
231.0593872	0.11
237.0119324	0.07
240.6565247	0.16
253.0572510	0.61
261.6496887	10.03
265.4439697	0.04
267.9002075	0.09
269.1134338	0.30
280.1101074	0.38
284.9522095	0.03
288.6551208	1.99
289.3492432	0.07
290.1673584	0.10
294.8722534	1.02
301.6871033	1.62
304.0755615	0.02
308.1074219	1.33
309.2629089	0.14
311.8142090	0.05
317.6784363	100.00
319.0409546	0.40
320.0092773	0.22
320.6983337	0.02
324.3555908	0.05
328.2402344	0.08
350.9388123	0.06
351.6765137	0.06
353.1776428	0.20
368.9128723	0.29
370.2071533	0.14
371.2635193	0.17
376.1427307	0.23
419.1533508	0.17
441.2326355	0.09
442.3212280	0.20
443.1795959	0.06
466.2799683	0.05
467.9517212	0.05
483.0723267	0.15
500.0327759	1.79
505.2268677	0.42
506.3073120	0.02
522.2128296	3.68
523.0692749	0.43
558.9708862	0.02
576.2079468	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.1083
Annotation	Androsin
Peak:m/z	Relative Intensity
100.9561462	5.30
102.9803772	5.59
106.8694153	0.07
111.7101517	0.07
112.9379501	3.54
114.9113770	0.11
118.9015045	4.86
124.9641724	0.33
130.9956970	1.02
142.8549500	1.98
146.9333191	100.00
148.9296417	0.34
157.0130920	0.09
159.2723694	0.11
161.0006104	1.18
164.9863281	17.11
177.1163330	0.82
178.8885345	0.90
188.2987061	0.09
192.9774475	0.23
205.0768127	0.30
207.0086060	0.76
210.8921204	0.09
231.0841370	0.15
237.0975342	0.58
254.1683655	0.06
254.9170532	0.46
265.3471069	0.13
281.1027527	0.58
282.9180603	0.48
291.2078552	0.09
297.1549072	0.12
308.3389893	0.04
309.1020203	0.40
310.2023926	0.11
312.0616760	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
110.9445953	28.71
177.1649323	14.00
193.1098022	21.19
206.0298767	21.83
207.3708038	73.79
208.115509	8.78
215.0913239	42.33
223.1428986	52.02
233.0778351	21.81
251.067688	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	412.1247
Annotation	6-Amino-6-deoxyfutalosine
Peak:m/z	Relative Intensity
126.9366760	0.06
144.9789124	0.19
146.9483490	1.02
148.9258728	0.26
161.1505585	0.29
164.0381927	3.12
166.9495239	0.18
170.9525909	0.28
173.1801758	0.29
179.1420593	0.37
184.9359131	0.18
188.0352783	92.47
190.1035156	2.65
198.1457825	0.44
202.2831879	0.11
206.1040039	48.89
216.1104126	1.08
230.1050720	0.84
231.8713074	16.98
232.5296326	0.19
246.2092896	0.54
247.3293152	0.12
249.8793640	13.70
251.0282898	0.33
251.9985046	0.36
260.1514587	10.84
263.2436523	0.14
270.3592529	0.21
272.0831909	0.91
274.1437073	100.00
280.2169800	0.62
290.2283325	1.67
292.1282043	4.28
296.3438721	0.08
301.9640808	0.39
304.1094360	40.89
306.7459717	0.08
314.1873169	0.22
316.0438232	6.78
320.2015381	0.07
322.1265259	6.42
332.0955811	0.30
334.1999512	4.50
346.4371643	0.11
350.3352661	0.09
352.0941162	25.43
358.1695251	1.93
364.2317200	0.10
365.1232910	0.24
366.4097595	0.22
367.2354431	0.09
368.2041931	0.29
376.1653137	3.18
382.2431335	0.06
394.1350098	4.48
394.9616089	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	310.0017
Annotation	5-HYDROXY DICLOFENAC
Peak:m/z	Relative Intensity
128.2861328	18.18
147.1055298	4.45
264.100769	100.00
266.013855	90.86
282.0979004	6.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.156
Annotation	[3aR-[3aR*,4R*(2S*,3S*),6E,8S*,10E,11aR*]]-2,3,3a,4,5,8,9,11a-Octahydro-8-hydroxy-6,10-dimethyl-3-methylene-2-oxocyclodeca[b]furan-4-yl ester 2-hydroxy-2-(hydroxymethyl)-3-mercapto-butanoic acid
Peak:m/z	Relative Intensity
189.0729370	0.04
196.7463379	0.11
223.3448944	0.03
240.8475800	0.03
253.3217468	0.04
271.1462708	0.05
272.1652222	0.23
277.1972961	0.08
283.3507080	0.06
293.6893005	0.07
294.3894348	0.03
295.2644348	0.13
303.3057251	0.04
309.3642578	0.05
319.1709900	0.06
323.2601013	0.10
327.1145325	0.08
341.1405945	0.22
342.4567871	0.05
343.4235840	0.02
352.2273865	0.05
365.1601257	0.03
375.3981934	0.17
379.4267273	0.05
382.3672180	0.03
384.3999939	0.05
392.5462341	0.08
395.2117310	0.06
396.3033752	0.05
411.1775818	100.00
412.4331360	0.10
413.3317261	0.07
420.3907776	0.09
427.3835754	0.07
429.5544128	0.09
430.9526367	0.02
439.1494751	0.17
440.2161865	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	509.1281
Annotation	Eupatolitin 3-glucoside
Peak:m/z	Relative Intensity
195.3230591	0.11
242.2407227	0.18
275.0611267	0.58
281.0746460	0.22
293.0826416	0.09
330.8637085	0.09
336.8413696	0.34
344.7703857	0.17
347.1630859	100.00
349.3295898	0.17
359.3171997	0.57
362.1995239	0.26
371.2964478	0.20
389.4877930	0.19
396.0648804	0.15
408.8649292	0.21
411.2292480	0.51
413.3151855	0.34
434.6712036	0.23
442.1556396	0.18
447.7829590	0.43
450.8392944	0.57
454.3900757	0.63
462.9859619	0.83
467.6018677	0.38
471.3225708	0.14
473.0523071	0.20
482.7634888	0.43
490.1776733	0.64
491.3904419	3.20
492.1310425	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.24
Annotation	Unknow
Peak:m/z	Relative Intensity
130.4757538	0.15
134.9817810	0.06
147.0521851	0.13
170.8929443	0.12
201.1500854	0.37
209.1857758	0.08
215.1027374	0.30
216.7432098	0.18
246.0179443	0.43
265.0663452	0.21
275.1049805	0.10
278.1244507	0.44
284.3712158	0.25
294.0709229	0.34
296.6389771	0.20
306.2515564	0.25
309.1979370	0.53
310.2757568	0.35
315.0686340	0.52
332.3076172	0.12
334.1548767	28.38
334.8765869	0.27
343.0368347	0.32
350.1619263	0.29
352.0159302	0.09
353.6094360	0.35
355.0559692	1.02
361.2042542	0.44
365.2537537	0.85
366.1700134	0.10
378.2416077	100.00
378.9395142	0.14
382.7367554	0.11
388.0293274	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2251
Annotation	Citbismine C
Peak:m/z	Relative Intensity
225.0092468	0.03
338.9353027	0.20
341.1460571	100.00
503.3821411	0.03
511.5823364	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0379
Annotation	4-Hydroxy-5-(3'-hydroxyphenyl)-valeric acid-3'-O-sulphate
Peak:m/z	Relative Intensity
100.9097595	0.27
114.9040146	0.68
125.1713104	0.06
126.8862915	0.11
128.8652802	0.24
130.0025940	0.06
157.0931091	0.34
160.6526337	0.10
162.1232300	0.12
165.2156372	0.11
171.0912781	0.80
172.8982544	34.42
174.0307617	0.06
175.0827637	0.63
177.2309875	0.04
178.9992371	0.41
185.1669617	0.07
186.9449463	0.50
188.9353638	4.76
199.9128723	0.43
201.0563049	0.16
202.1205444	0.04
203.5229187	0.13
204.8664246	0.33
212.9551392	0.48
214.9631042	100.00
216.0673218	0.91
216.9309387	0.35
225.3654785	0.08
226.4593201	0.28
227.1270447	3.10
228.9407959	0.15
230.1749878	0.07
230.8782349	0.14
231.6075134	0.04
238.8074341	0.07
241.2788086	0.14
242.9830017	3.84
244.0159607	4.22
245.0878906	12.07
246.2189636	0.03
247.1499634	0.37
250.9580994	0.01
253.3511353	0.09
254.1436157	0.05
258.7575684	0.09
260.2021790	0.06
269.2030640	0.04
271.1135254	3.53
274.1892700	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2075
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1653442	0.05
162.2074585	0.10
178.8791809	0.33
207.1723022	0.18
210.9181366	0.16
212.1534576	0.13
222.3260345	0.10
223.2070007	0.16
235.3089905	0.16
241.1042480	0.23
262.2517395	0.14
268.6424255	0.07
270.1184082	0.70
271.2506409	0.99
273.8793335	0.13
288.1752930	0.19
300.9349670	0.66
317.2957764	0.26
318.2193909	0.30
341.3842163	0.10
345.1104736	0.34
345.7625732	0.06
351.1442261	0.25
352.2026062	0.12
353.1294556	0.18
378.1292725	0.16
385.9225159	3.92
387.3054810	100.00
388.3812561	1.03
389.1927185	0.33
390.0171814	0.21
396.8600159	0.38
398.4785461	0.17
403.1724548	0.37
404.6853943	0.06
415.0882263	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1031
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
101.2122726	0.04
107.8246155	0.05
112.9897385	0.03
121.0235596	0.06
126.9927673	0.04
128.9605408	0.11
132.0777588	0.09
134.0361633	4.56
142.9724426	0.15
149.0720367	2.20
157.9725952	0.07
160.0381165	5.33
160.9866028	0.08
165.2203674	0.04
173.0707397	0.22
175.0335999	38.89
176.1849670	0.12
178.0220032	0.82
178.8802185	0.02
180.3780823	0.07
187.9552155	0.13
189.0408173	0.14
191.1763000	1.24
193.0289764	100.00
201.0288544	0.17
202.0209045	0.66
203.0120544	0.25
207.1532593	0.79
213.1788025	0.14
217.1181946	61.90
219.0510864	0.30
221.0936584	0.22
232.9859924	0.27
235.1040039	11.38
244.9006042	0.06
247.0804749	2.92
259.0974731	2.67
265.0776978	5.59
275.2059937	0.11
277.1929626	0.56
289.0285950	0.25
295.1158752	6.48
309.1527710	0.09
310.9263916	0.03
319.0015869	0.12
321.4389038	0.09
327.1384583	0.11
337.0831604	2.20
340.3345947	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1136
Annotation	Robustaside B
Peak:m/z	Relative Intensity
130.7111816	0.07
144.9298706	0.05
149.0278320	0.19
151.0016174	1.66
152.8123779	0.29
165.3320923	0.09
169.0420990	0.19
177.0290833	0.14
178.2966919	0.22
192.8953552	0.29
195.0820618	0.10
207.1966858	0.04
214.9884033	0.26
218.2288818	0.05
226.2829590	0.12
246.2763062	0.24
251.0960693	0.23
253.3370972	0.43
271.1317444	100.00
275.0287476	0.07
278.9940491	0.17
284.2492676	0.16
285.1361389	0.10
287.4050598	0.08
291.0100098	0.23
295.2009888	0.42
297.2832642	0.06
307.2663574	0.08
311.0915222	0.38
313.2098389	11.89
315.0145264	0.31
334.6702881	0.07
343.1862488	0.26
345.6659851	0.08
347.1411743	0.27
352.6576843	0.32
377.0209351	0.70
385.3034973	0.09
386.2100525	0.07
387.2432861	0.45
389.4383545	0.06
395.0522766	0.05
397.3235779	0.37
398.2381897	0.08
414.2574463	0.16
415.1491394	1.19
416.0017395	0.07
417.3439026	0.26
433.0726013	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.3516
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
209.2469788	0.08
219.3671875	0.08
221.2664337	0.29
235.1112061	3.93
236.2835693	0.39
253.1851959	0.47
254.2950592	0.04
260.3556519	0.04
263.1630554	0.21
269.3432617	0.06
277.1895142	0.06
279.3173218	3.88
280.2795105	0.63
286.0193176	0.10
287.0520020	3.12
288.1304321	0.38
303.0215149	0.07
305.1557007	4.30
306.0361938	0.45
319.3312988	0.08
323.0454102	0.80
351.1464844	0.17
379.2025146	0.17
397.1716919	100.00
398.2923584	11.07
399.1707764	0.07
413.2664795	0.30
415.2351685	29.05
416.2657471	4.16
433.2762451	0.40
465.3430786	0.10
485.0601807	0.05
496.7827759	0.15
515.2842407	0.15
603.2814331	0.11
617.0714722	0.05
632.3574219	0.12
639.5183105	0.05
651.7213745	0.05
667.1398926	0.20
669.5156860	0.15
677.2224731	38.94
678.2756958	9.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1345
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0259857	0.27
174.3360291	0.08
175.0945740	0.10
177.2702484	0.02
178.9331360	0.09
187.1593628	0.06
187.9714508	0.05
189.0778503	0.02
199.3855591	0.03
201.2854919	0.28
203.0087738	0.51
205.1497192	0.36
213.3209381	0.03
215.2895508	0.13
217.3066254	0.12
225.1281433	0.05
227.2400818	0.08
228.0079193	0.08
229.1085205	0.07
230.0733337	0.16
241.0795135	0.05
243.1242523	0.15
245.1586609	2.57
246.2555084	0.10
247.3030396	0.05
254.8522949	0.23
257.1298523	0.13
259.2510681	0.04
260.7526855	0.06
262.1093750	0.08
269.0967407	0.44
271.0561218	0.18
273.1255493	1.16
285.1709595	0.47
287.1365356	5.02
289.1123657	16.98
290.0234375	0.31
293.1997681	0.03
299.1417847	4.02
301.4005127	0.11
303.1592407	0.75
303.9060059	0.06
305.3383179	0.02
328.1347046	0.02
329.1865845	0.64
331.0906372	0.49
339.2998047	0.39
341.3685913	0.22
342.4524536	0.07
343.2149048	0.04
345.0609741	0.09
357.1749268	0.20
367.3383179	0.10
381.3568115	0.65
383.4537964	0.03
395.1118774	0.07
397.4727783	0.08
407.1874390	46.96
408.2931519	0.17
409.2310181	0.18
410.9876709	0.21
413.2963867	0.13
414.2716064	0.13
415.4015503	0.14
423.1954346	0.20
425.1236572	100.00
425.9271240	0.32
433.3300781	0.34
437.1191406	0.23
449.3139038	0.93
451.2727661	23.35
455.2810669	0.08
466.5873413	0.15
467.3447266	0.70
469.2915039	0.04
470.6151123	0.04
475.2282104	0.04
478.8852539	0.16
482.8070679	0.03
483.6382446	0.26
491.2077637	0.80
492.1648560	0.41
493.4951782	0.08
497.3547974	0.02
500.2122803	0.77
501.3076172	0.22
513.0781860	0.32
514.1828613	0.03
515.2883911	0.49
516.4144287	0.17
532.3187866	0.04
533.4534302	0.60
536.3326416	0.04
540.3087769	0.12
541.5706787	0.02
559.1861572	9.79
567.2903442	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	490.26
Annotation	Zygosporin E
Peak:m/z	Relative Intensity
152.9946289	0.14
172.1453857	0.10
176.9102173	0.19
186.0962830	0.07
195.1057434	1.83
195.9806213	0.56
208.2145081	0.12
214.1189728	1.64
222.9299011	0.48
224.1482086	0.27
231.3818512	0.07
245.3677216	0.30
255.9637756	0.05
262.1239929	0.04
265.2152100	0.10
271.1212158	0.14
275.3384399	2.03
292.2457581	0.35
293.2661133	100.00
300.4464722	0.26
305.2204590	0.07
306.1362305	0.13
311.3165588	0.23
317.3414612	0.07
320.1214294	0.08
328.2544556	0.47
341.4372559	0.07
345.1912842	0.06
378.1086731	0.39
379.1831360	0.09
389.2015686	0.25
394.2738037	0.07
400.2884827	0.30
402.3237610	0.36
412.1009827	0.25
415.7673035	0.20
418.0919800	0.26
421.1999207	0.73
423.6109314	0.29
427.3079834	0.56
432.2387390	0.08
443.1673584	0.14
444.1320496	1.21
445.5975037	0.08
448.8566589	0.12
452.3397827	0.59
454.1883850	35.91
455.2857361	4.97
460.1618347	0.11
461.0693970	0.12
462.4830627	0.24
471.4919739	0.27
472.2726746	1.61
473.0476379	0.27
480.6729431	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.1642
Annotation	Orientin 2''-O-(2'''-methylbutyrate)
Peak:m/z	Relative Intensity
152.0261383	0.26
153.8096924	0.10
160.8908691	0.09
177.0535583	5.74
183.0231171	0.20
194.9649048	1.76
198.9658203	0.19
212.9730530	0.10
216.8691101	0.10
230.9569702	0.30
232.8655243	0.13
241.3695679	0.27
249.1475830	0.09
258.8942261	0.34
261.2609253	1.06
266.9811401	0.53
285.1114502	0.14
286.5350342	0.12
302.9458008	0.69
308.8931274	0.04
311.3257446	0.45
321.0084229	0.47
338.2218628	0.29
343.2512207	0.10
345.3801270	0.08
353.0560303	0.17
362.2251587	0.27
363.0546265	0.27
375.2667236	0.37
381.3489990	0.14
389.2482300	0.60
390.8693237	0.42
406.8721924	1.31
421.5077515	0.12
423.1596069	0.04
425.1696167	100.00
428.5114136	0.06
439.0847168	0.22
455.3324585	0.24
460.3890991	0.20
469.1150513	0.38
474.9779663	0.08
478.8493042	0.41
480.3432617	0.10
481.7931519	0.16
488.9970703	0.19
496.4291382	0.04
497.2538452	0.89
514.5415039	1.12
515.1664429	9.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.117
Annotation	Sissotrine
Peak:m/z	Relative Intensity
142.7383118	0.02
162.1431274	0.02
177.8146057	0.01
179.1693726	0.08
180.3928986	0.06
191.1583862	0.05
195.1251831	0.03
201.1826935	0.02
205.0888519	0.03
217.2121887	0.03
219.0813141	0.02
235.9176025	0.01
239.3919983	0.07
247.1435242	0.05
249.1234131	0.91
250.1455383	0.18
265.2641907	0.02
270.9879761	0.02
274.2697449	0.02
283.0681458	100.00
284.1372375	14.95
291.2713318	0.08
293.2580261	0.08
298.2136841	0.04
304.0552673	0.11
313.1271362	0.08
315.2794189	0.02
317.1147766	0.06
327.1481934	0.03
336.2472534	0.06
349.4115295	0.02
359.344574	0.08
373.4250183	0.03
381.4283752	0.02
384.9963074	0.02
399.209137	0.04
399.9923706	0.05
401.2155151	0.12
402.3216248	0.22
403.2832947	0.06
407.1168518	0.02
408.2805481	0.06
410.051239	0.13
413.8847961	0.05
425.098938	0.04
427.2218323	0.35
428.2538147	0.07
429.0502014	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9002
Annotation	Unknow
Peak:m/z	Relative Intensity
173.8965149	0.04
198.9196930	0.16
200.1292267	0.09
216.8574677	0.03
228.8582153	0.22
230.1782837	0.04
273.0711060	7.90
274.0407104	2.15
386.9242554	19.01
388.0704346	7.83
430.0639648	0.03
500.8733521	100.00
501.8842163	48.52
502.5057373	0.09
513.6182251	0.02
543.0565186	0.07
569.0661621	0.03
572.8165894	0.03
596.8744507	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1172
Annotation	Sissotrine
Peak:m/z	Relative Intensity
138.9639587	0.25
146.0170898	1.04
146.9460907	0.72
160.986496	0.32
164.0736084	1.54
165.2619629	0.19
179.0500793	6.22
180.0715027	3.08
182.7944183	0.14
192.8521576	0.22
194.9816895	100.00
195.7598877	0.07
199.0227356	0.23
221.1351624	0.25
223.2741241	0.40
237.111557	2.06
238.9413147	0.45
265.1628723	0.90
283.0580444	73.29
287.2944946	0.16
314.2779541	0.10
317.2759705	0.30
325.223053	0.13
326.1993103	0.12
329.1070557	0.23
331.2652893	0.21
339.7635193	0.51
341.3543396	0.27
345.2568054	0.35
347.0343628	0.16
354.9811401	0.80
357.1325989	26.37
359.9545898	1.03
365.1700439	0.17
371.1113586	0.22
373.6565247	0.79
383.6245422	0.62
384.3904114	0.39
385.4153442	0.45
398.1945496	0.10
399.3569031	0.29
400.2333679	0.17
401.3992615	0.29
413.5533142	0.27
414.9510193	0.39
425.4342651	0.31
426.558075	0.63
427.2342224	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.89434814	0.90
103.0370941	0.40
105.0280914	1.17
109.0413361	0.31
113.2482605	0.31
114.8476868	0.22
119.1171417	0.72
122.980072	1.19
124.8536987	0.60
128.8669739	0.65
130.8708496	1.35
133.1327515	0.59
135.1129608	1.11
137.3025818	0.33
139.1043854	0.53
140.9127655	0.50
142.9255981	1.26
146.696991	0.98
147.3891296	1.60
149.1460571	0.87
151.0448914	0.15
154.9244995	0.84
156.8182983	0.39
159.0251617	1.15
163.3847656	1.53
165.0247345	0.35
167.0478821	0.38
169.0358582	2.71
173.0295105	6.98
177.2406921	0.60
183.1127625	2.34
185.0464783	1.10
186.8168945	1.39
188.8256226	0.63
191.0037689	0.38
194.9251862	0.42
197.3053284	1.86
200.89711	1.63
203.2915955	0.54
205.195282	0.56
209.1231689	0.79
210.9810486	3.33
221.355072	0.28
223.0264282	1.19
228.0216675	0.38
233.2813416	0.29
240.9771729	0.20
243.0112305	0.54
247.3082886	3.41
251.3522339	2.77
265.2510986	0.45
269.4188232	1.40
271.2151489	1.02
277.3376465	2.17
279.1234131	2.06
281.1132202	1.95
283.2459106	1.01
285.0454712	1.84
287.5908813	0.27
295.2903442	3.48
297.1922302	0.97
298.6917725	1.22
299.3341064	0.43
305.2961426	8.08
310.4464111	0.49
311.2521362	0.63
323.2460938	100.00
324.2883911	0.64
325.1474915	2.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.2009
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
114.9829865	1.00
126.9753571	0.52
128.7753296	0.15
132.9117126	8.55
143.2389069	0.46
144.8742676	6.37
146.7972565	1.41
149.9826355	5.64
150.6116943	0.25
152.8744659	0.71
155.2457275	0.58
159.1323547	0.24
161.0436554	0.47
162.8988647	5.80
164.9152069	3.70
168.9649353	0.51
171.2639313	2.49
172.9082489	0.23
177.0262146	0.48
186.9146423	0.37
189.0896606	15.84
192.9616394	1.69
201.0647888	14.53
203.1843262	0.96
204.1503296	0.97
205.0891724	0.56
207.0553131	6.29
209.3279114	0.23
210.8465729	0.68
212.9412842	1.94
218.9676514	21.24
221.1772156	0.40
223.0674744	4.13
229.0157013	0.35
231.1185608	5.12
236.7309265	5.93
237.3969116	0.70
238.2871094	0.29
240.9505005	9.24
248.5337830	1.43
249.1350403	0.17
254.0575256	3.56
254.8214417	80.45
255.5957336	1.30
258.6889343	91.38
259.4224548	0.27
267.1276245	1.50
270.8072510	0.18
271.9517212	1.13
277.0833435	6.43
284.9684448	100.00
286.9776611	0.17
292.7803650	0.40
294.3275452	19.07
294.9529419	96.21
295.5870667	0.16
302.1031189	15.81
308.8582764	0.77
345.9290466	0.24
367.2656555	1.19
388.1433411	1.08
388.9479065	0.17
390.3538208	4.13
391.4010620	0.24
395.2245178	0.82
399.1037292	0.15
400.4085388	1.17
403.1969604	0.82
415.3453674	0.31
416.5286560	19.91
417.2553101	1.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.1248
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9167633	4.12
232.0412140	0.42
251.0705872	0.07
265.2781067	0.10
386.8922729	0.28
391.7590942	0.17
403.0436401	0.48
404.2578735	0.17
405.8637085	100.00
406.8290405	0.25
407.7692261	0.14
419.0796509	0.07
423.9125366	0.09
425.0642700	4.06
425.9888306	0.05
427.0058594	0.16
430.8582764	0.05
439.0746460	0.27
440.9649048	0.13
444.0565796	31.48
453.4240723	0.08
501.1479492	0.07
511.7857666	0.18
512.8521118	0.08
513.5098877	0.09
515.1460571	0.28
521.3383179	0.30
522.1129761	0.36
552.9088745	1.06
575.9801636	0.23
578.5345459	0.19
580.6121216	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3071
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
161.0695801	0.17
205.3239441	0.08
217.1691589	0.06
233.3952026	0.72
235.1671448	1.17
253.1283264	8.10
255.2292633	0.04
259.2246094	0.09
273.0177612	0.07
277.2733154	100.00
287.8332520	0.05
295.0704651	0.05
300.9374390	0.07
308.4226074	0.08
317.1235352	0.15
345.4072876	0.02
369.6239624	0.04
372.5587158	0.03
381.2362671	0.10
383.4534912	0.19
409.3800659	0.04
425.3944702	0.05
429.1102905	0.04
450.2013550	0.08
451.2460327	0.15
452.3651123	0.23
453.3824463	0.51
467.3932495	0.60
469.1380615	0.11
471.3722534	0.11
472.0380859	0.06
472.8063965	0.02
477.2521362	0.18
478.2233276	0.26
483.5101929	0.10
495.4273071	0.32
496.3978882	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
152.1275024	6.98
285.380188	12.56
307.2827148	2.90
379.741333	2.50
390.3861694	5.84
407.6138306	12.66
408.2683105	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.2069
Annotation	7S,8S-DiHOTrE
Peak:m/z	Relative Intensity
97.0345306	0.12
98.9785614	0.11
107.2402725	0.05
111.0836029	0.10
115.0005875	0.22
125.1530685	0.03
138.9677124	0.08
141.1120453	0.24
149.1298370	0.03
153.0980225	0.07
155.0981140	0.06
160.9008789	0.06
163.2001343	0.27
165.0812378	0.52
167.0811462	0.27
167.8438110	0.05
171.0301208	0.42
177.1206360	0.02
178.2726746	0.02
181.0561981	0.16
182.9290466	0.12
185.1342163	0.09
191.1289215	0.22
193.2589569	0.99
197.1259460	0.08
209.1696472	46.90
210.1022034	0.05
211.2091370	0.49
218.9389954	0.13
223.3724670	0.04
225.3290100	0.03
227.1520386	0.04
237.5359802	0.02
239.2469788	0.08
241.3417053	0.07
243.2117004	0.03
247.2402954	2.05
249.0676270	0.07
251.1275024	0.27
253.1466675	0.06
261.3599548	0.10
263.2343140	0.09
265.2657166	2.41
267.2787476	0.23
271.2187195	0.02
273.3149109	0.97
281.1545105	0.18
291.2439575	100.00
293.2564697	0.07
294.0620117	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.3016
Annotation	Cepafungin III
Peak:m/z	Relative Intensity
146.8003845	0.11
157.0283813	0.81
174.9576874	1.61
177.0940247	0.05
189.1060486	0.97
193.4954834	0.12
204.9614258	2.92
207.1203613	0.10
223.2444153	0.52
224.9528351	0.21
231.0499878	6.60
243.3566895	0.26
249.1579895	43.79
255.2623596	100.00
267.1481018	16.20
267.9063721	0.21
279.4192810	10.00
280.3029785	1.37
307.6386719	0.18
312.2918701	0.20
312.9067383	0.16
321.2994995	0.12
341.4110718	0.55
373.3521729	0.08
387.1617432	0.05
410.3436584	0.24
417.0256042	0.12
419.7618408	0.11
427.5922241	0.74
431.3489990	0.07
433.4389343	0.26
445.4773254	2.54
447.4768982	0.10
451.5624695	0.10
457.1824341	0.23
459.0469055	0.52
459.7635193	0.20
461.3516846	1.19
468.3159790	1.07
469.1969910	1.26
470.4419556	0.35
487.3188171	26.83
487.9327698	0.23
490.1192932	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.2172
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9666290	57.34
161.0637817	44.76
176.9673462	100.00
178.0668640	85.69
281.3988647	0.30
326.8111572	0.73
339.4216309	0.54
502.1648560	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1353
Annotation	Speranculatine A
Peak:m/z	Relative Intensity
130.0048676	0.19
131.9415436	0.41
143.1104736	0.07
159.0278015	0.09
161.0647278	0.22
173.0427551	13.86
174.1828918	1.63
177.9656372	0.09
194.9747009	0.07
200.0838013	0.32
201.1293182	0.10
211.1932526	0.04
211.8158875	0.02
214.1783142	0.07
215.0271301	0.14
225.4404602	0.02
227.4010468	0.02
231.0182190	0.07
232.7224121	0.02
233.8677673	0.02
239.1921692	0.03
243.1990662	0.20
245.2978516	0.05
251.2929077	0.02
257.3378296	0.14
258.0850525	0.04
262.1619873	0.05
264.4247742	0.03
265.1773682	0.11
267.0794983	0.10
269.2538757	0.04
271.4165344	0.07
272.1798096	0.03
274.8076477	0.03
275.7766724	0.06
289.2681885	0.57
290.0905151	0.05
292.1443176	19.53
293.2058411	4.35
300.2198792	0.06
301.0022888	0.02
305.2855530	0.03
318.3070374	0.24
319.5345764	0.09
323.4653320	0.03
325.2812500	0.03
326.0522461	0.02
335.2247620	64.06
336.1206665	100.00
337.1332703	14.27
340.1213379	0.05
340.8570251	0.06
343.5054932	0.03
345.1231079	0.02
354.0407715	0.02
361.2457886	0.03
362.1608582	0.03
382.0883484	0.01
389.3508911	0.35
390.4255981	0.05
391.0737610	0.03
405.9002075	0.03
407.2383118	3.82
408.3056641	1.34
413.8483887	0.15
415.1556091	0.29
416.1758118	0.24
420.1633606	0.25
424.1448669	0.03
424.9769592	0.04
433.1598511	80.16
434.1515808	18.59
434.9398499	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.2209
Annotation	(1alpha,2beta,4abeta,5beta,8aalpha)-(+-)-decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-1,5-naphthalenediol diacetate
Peak:m/z	Relative Intensity
119.2193298	0.08
121.2498550	0.10
127.1909332	0.09
132.1961670	0.56
134.0667114	0.12
135.1094513	0.10
142.0626221	0.16
149.1062317	0.33
149.8966980	0.26
151.3079529	0.18
157.1770935	0.15
175.2082214	0.31
176.3634949	0.25
179.2442780	0.38
180.2534180	0.86
181.0070496	0.13
183.9687195	1.02
190.0956116	0.29
205.3156738	0.09
205.9662170	0.17
208.1034546	0.37
210.9201050	0.49
212.1030273	5.08
216.4013672	0.12
217.0363464	0.68
222.3546143	0.08
224.5694275	0.11
231.2685547	0.11
232.2321472	0.34
236.3918457	0.15
240.1076050	0.18
246.3784790	0.42
250.0748291	0.50
252.1091309	0.14
255.3539734	0.57
264.1423340	0.35
268.1150513	100.00
269.2902832	0.53
273.0550537	0.58
274.1685791	1.42
280.1116333	0.17
284.2696838	0.05
286.8308716	0.77
287.5586853	0.16
289.0517578	0.66
291.7338867	3.25
292.3919373	10.04
293.0665894	0.43
294.3273926	0.07
296.5089111	0.17
297.3016357	0.05
305.3700867	1.09
306.2927246	7.84
306.9678345	0.26
308.3791504	0.15
323.2142944	0.34
324.3750610	0.27
325.0883179	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1771
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0067902	0.81
145.0917053	1.34
146.0690308	4.13
147.1281738	0.84
150.8919525	0.20
159.0337982	2.16
160.1023865	4.85
161.0141296	41.85
162.0777283	3.66
163.0065460	0.15
163.9857635	0.04
173.0585327	0.61
174.1144409	0.13
175.1107941	11.22
176.1139221	1.59
178.9151917	0.84
181.1828003	0.03
183.3276978	0.10
185.0792236	0.87
186.1706390	0.19
187.0902100	0.94
189.0404816	86.66
190.1466370	14.77
195.2336426	0.13
196.8594818	0.10
201.0430298	2.19
203.0342102	36.55
204.0790100	6.43
215.0100403	1.45
216.4749146	0.12
217.3681793	0.09
221.1071625	13.21
222.1159363	0.92
226.3648071	0.05
227.1789703	0.21
229.1758423	3.58
230.0841370	0.65
231.0982056	0.83
232.0104523	0.34
233.2013855	0.72
241.2447815	0.17
243.0207672	0.04
245.1518402	0.35
246.3892670	0.09
252.2200623	0.05
253.0545349	0.07
254.3414307	0.23
255.3134460	0.15
257.8157043	0.13
258.9989929	0.19
260.8876038	0.30
261.9526367	0.07
269.1596680	0.14
270.0814209	0.16
272.1747742	0.04
275.1892395	0.28
277.1727600	3.60
278.2650757	0.30
286.9865723	0.68
290.4354248	0.17
295.1652527	2.39
296.1574707	0.19
305.1419373	100.00
306.1941528	25.37
307.2125854	0.40
308.0750732	0.25
309.3245239	0.05
312.2775269	0.16
323.1504517	24.44
324.1861877	5.60
339.0922241	0.07
347.2929077	0.13
354.2584839	0.05
366.2916260	0.04
370.1908569	0.12
378.1221619	0.11
389.3876953	0.04
390.3360901	0.06
396.2753601	0.06
398.3074036	0.13
405.2038879	0.08
406.3455505	0.08
411.2879944	0.28
412.1433411	0.09
413.1429138	0.43
420.2558289	0.20
422.3090515	0.15
423.5609436	0.08
426.5235596	0.24
431.3906555	0.10
439.2942810	0.03
440.9173889	0.37
442.1937256	0.21
444.3915405	0.03
449.1069031	0.45
453.7304688	0.22
454.3322449	0.19
457.2995605	7.55
458.3263855	2.23
465.9755249	0.18
467.2186890	29.47
468.2835083	9.93
469.3690491	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.0411
Annotation	Unknow
Peak:m/z	Relative Intensity
208.9435730	100.00
223.0409241	41.10
249.9172058	0.39
319.0751343	1.01
337.1185303	0.47
343.0462952	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1345
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
175.2030182	0.25
179.0939331	0.05
185.0695190	0.06
189.1853638	0.06
198.8603058	0.04
201.2259216	0.10
203.1764832	0.13
205.0200653	0.37
210.8438263	0.14
215.2192383	0.02
217.3458099	0.08
219.1289978	0.08
224.7430267	0.06
229.2095642	0.03
230.1845551	0.07
232.0776062	0.13
243.0524139	0.26
244.0086670	0.04
245.2210236	3.30
246.0999146	0.06
246.9238281	0.04
255.1267090	0.51
259.1488647	0.15
261.4904175	0.08
262.1758118	0.03
263.0469666	0.02
269.0963440	0.38
271.1643677	0.04
273.0617676	1.40
275.3532715	0.10
281.1661377	0.11
283.4909668	0.04
285.1626587	0.86
286.4494019	0.24
287.1854248	6.28
288.0555420	0.04
289.1065063	16.57
290.1739502	0.43
291.5434875	0.21
299.1371460	4.75
300.1160889	0.03
301.1115112	0.03
303.1260986	0.75
304.1807556	0.21
305.1130981	0.06
311.1882935	0.25
325.1647339	0.03
328.2200317	0.06
329.1593018	0.51
330.3289795	0.10
331.2792358	0.43
341.0554199	0.20
345.5827026	0.03
352.9592896	0.04
357.2145386	0.46
359.1735840	0.02
361.4807129	0.04
363.1269531	0.03
364.3998413	0.05
369.1037598	0.05
371.3388672	0.02
380.0588989	0.03
381.2629395	1.24
383.3669434	0.10
385.3674927	0.13
395.4271851	0.10
397.4799805	0.06
405.1546021	0.33
407.1777954	51.82
408.5205078	0.54
409.2221069	0.50
410.2099609	0.17
411.2590332	0.44
413.2639160	0.78
414.2263184	0.03
415.3270874	0.52
416.1591797	0.09
417.2907104	0.04
423.1732178	0.53
425.1287842	100.00
433.1770630	0.46
434.1651611	0.04
436.5553589	0.13
437.2115479	0.38
447.2443237	0.10
448.3238525	0.03
449.2509766	0.93
451.1431274	24.05
451.8483887	0.22
453.0393677	0.08
455.2895508	0.15
467.2547607	0.42
471.2324829	0.04
475.3199463	0.12
482.3030396	0.20
483.2064819	0.24
488.4271240	0.07
489.1269531	0.09
491.2951050	4.79
492.1049194	0.40
493.0617676	0.12
500.2962036	4.93
501.2309570	0.64
501.9323120	0.11
515.2163086	0.10
521.1367188	0.18
526.3977661	0.10
531.1065674	0.29
532.0139771	0.30
533.2748413	1.34
534.3278198	0.07
539.3698120	0.08
540.1686401	0.10
541.4424438	0.09
548.9567261	0.13
557.7941895	0.11
559.2369995	6.73
560.2780151	0.51
561.1529541	0.06
567.2695923	0.32
568.4752808	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	263.09
Annotation	Ng-L-Glutamyl-L-aspartic acid
Peak:m/z	Relative Intensity
128.8714142	0.43
130.1080322	0.68
133.9699707	1.68
147.0514984	2.43
160.3008575	0.51
200.0427246	0.08
210.2149963	0.42
216.9886322	4.10
218.1485443	0.76
220.8813019	0.08
227.0271454	14.32
228.0294495	60.02
235.0615845	1.67
245.0280151	100.00
246.0846100	38.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	204.0862
Annotation	7a-Epialexaflorine
Peak:m/z	Relative Intensity
59.95546722	0.30
65.61846161	0.05
68.11856079	0.07
87.97764587	1.93
95.85636902	0.42
96.7530365	0.26
108.8638	0.18
110.1708832	0.18
113.9467926	1.77
115.8805389	2.25
122.0495911	0.19
125.8840637	1.57
133.9580536	100.00
137.8446808	1.05
144.0459442	0.72
145.0274811	0.59
148.0933075	0.12
149.9285736	0.17
156.0173798	1.47
157.7926788	0.41
162.9105377	2.76
163.7095032	0.08
167.9653931	6.30
173.7734222	0.17
175.7905579	0.06
180.7792053	0.60
186.0670319	68.26
187.2520752	0.06
203.8421783	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.1662
Annotation	Cypellocarpin A
Peak:m/z	Relative Intensity
152.8684998	0.09
179.0214539	0.12
184.4975739	0.33
242.8648529	0.25
245.3344421	0.08
253.2204590	0.18
269.3527527	0.31
283.2337341	0.42
285.3086853	0.05
287.7575989	0.11
317.0174561	0.08
326.9986267	0.08
327.9822998	0.19
346.3747864	0.04
349.3739929	0.33
365.4606934	0.08
373.1972961	0.15
409.4720764	0.20
411.2441711	5.67
411.8512573	0.11
422.7881775	0.20
425.1895447	0.06
428.8324890	0.10
434.2637634	0.12
437.2307434	0.34
451.1798706	0.83
453.2459412	100.00
454.1903076	0.14
458.3115540	0.07
459.3656921	0.13
460.0191650	0.08
461.2185364	0.44
462.3635559	0.09
467.1186829	0.14
478.9402466	0.95
480.1250610	0.26
496.6380005	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1035
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
177.0290222	1.46
179.1293182	0.08
218.7995148	0.25
220.4005890	0.05
231.2040100	0.06
232.1828308	0.05
240.2135468	0.12
242.6864166	0.12
249.2154846	0.09
259.2508545	0.18
266.9757080	0.17
269.0021667	0.23
275.0427246	0.14
285.1715393	23.43
300.1719360	0.13
303.0787354	100.00
303.7512207	0.20
311.0219116	0.17
318.1780090	0.08
327.0069580	0.40
332.8843079	0.11
334.1887817	3.33
337.5049133	0.11
341.1749268	1.19
343.0630493	0.11
352.8632812	0.03
356.9408875	0.16
360.2022095	0.41
368.9766235	0.09
371.1820374	0.43
378.2941589	1.89
381.0584717	0.12
394.2969360	0.08
404.3541565	0.04
405.3136597	0.03
406.0885620	0.20
417.6987000	0.04
419.0358582	0.06
421.0048523	1.29
421.9860535	0.21
428.5566101	0.26
437.2128296	0.58
446.1817932	0.13
447.2018738	2.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.11
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
112.9397430	0.73
118.7768021	0.11
123.1521988	0.27
124.9320068	0.06
138.0519257	0.82
142.9740295	0.58
146.8928528	0.09
149.0338135	0.40
151.1495819	0.08
152.9861145	17.29
158.9187164	0.53
160.9974060	4.90
161.8508606	0.05
164.0395050	2.55
173.9350128	0.10
177.0740967	0.71
179.0488739	1.29
185.0845490	0.04
186.9681549	0.04
190.0124512	2.95
192.8971100	0.19
201.1305847	0.07
203.1707764	0.43
205.0442963	60.69
206.1988525	0.09
207.9896088	1.56
219.1120605	0.16
221.1476135	1.52
223.0199127	100.00
223.6671753	0.59
231.9382019	1.59
233.1477661	1.53
237.0877075	1.12
240.8707275	0.12
247.0158386	46.04
248.8873596	0.15
250.0632019	0.59
251.1307983	1.30
252.1365051	0.45
254.9849548	0.11
263.1637573	0.47
265.1393127	9.03
277.1275024	1.30
280.1752930	0.11
285.1054077	0.13
289.1311646	1.15
293.3635254	0.17
295.1894226	4.43
299.3974915	0.17
307.0796509	0.32
323.0957031	0.42
325.2594299	5.42
333.0846863	0.10
337.0209045	0.07
338.2698364	0.23
339.2255249	0.81
340.4340210	0.06
341.7722473	0.15
342.4250488	0.19
349.1334534	0.44
356.9871216	0.25
365.3692932	0.18
367.1592712	2.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.1961
Annotation	Desacetyltetraneurin D 15-O-isobutyrate
Peak:m/z	Relative Intensity
132.3179016	0.12
149.1560669	0.07
159.9862976	26.94
160.9556274	0.45
177.0511475	100.00
204.9906158	0.11
207.9742126	0.04
263.0951233	0.14
299.2202148	0.05
307.0264893	0.15
335.2619629	0.36
336.3058472	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0874
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
100.8899612	0.86
112.9968491	1.30
115.0846100	0.13
118.9513702	0.72
125.1348801	0.13
131.0993958	0.44
131.9491119	0.03
133.1078644	0.23
135.0497589	5.35
142.9894714	0.89
148.7321777	0.23
161.0034180	23.48
175.1407471	0.07
177.7424622	0.05
178.9737091	100.00
189.2066498	0.19
203.0010986	5.79
207.0183258	0.16
211.0488586	0.04
221.1456909	0.57
226.2252808	0.06
231.1249695	0.08
233.0729065	0.29
245.2880249	0.08
251.0597839	2.56
268.9987488	0.05
279.2548828	0.07
281.1639099	3.22
285.1405029	0.04
293.2379150	0.07
295.0569458	2.37
297.0501099	0.52
312.7253418	0.17
323.0950317	0.57
326.4734192	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1403
Annotation	6-Caffeoylsucrose
Peak:m/z	Relative Intensity
160.9885559	1.94
172.7873993	0.02
179.0491791	9.34
203.0459900	1.15
205.1921387	0.05
219.1461792	0.04
221.1361847	0.02
232.2959442	0.30
233.2258759	0.13
243.0476990	0.08
245.0742798	0.05
251.2058411	0.48
272.3666992	0.06
273.1301575	0.24
281.2401733	0.83
282.4092712	0.20
295.1458435	0.16
303.9862366	0.13
306.3077393	0.03
311.1945801	0.08
315.4503174	0.07
323.1405640	0.72
325.5363770	0.02
329.1657715	0.12
341.1271362	100.00
353.2322998	0.02
357.2621460	0.03
365.2923279	0.07
381.2337036	0.08
393.3270874	0.04
400.0305481	0.13
405.0208740	0.16
415.0945740	0.10
441.2085266	0.05
443.2073669	0.60
456.2677002	0.20
457.0439148	0.33
467.1087952	0.09
475.2420349	0.03
484.1582336	0.20
485.4373169	0.05
493.7146912	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2622
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0818176	0.03
153.0426483	0.04
174.3251801	0.01
196.0707092	2.37
205.0859985	0.11
214.1383362	1.81
222.1387024	0.02
233.2420654	0.76
259.1787415	0.30
275.4225159	0.38
277.2517700	100.00
278.0936279	0.01
309.1004028	0.02
319.6331787	0.03
373.4320984	0.03
413.2386169	0.59
430.5946960	0.03
431.3884583	0.03
436.0746460	0.01
438.0970764	0.08
439.4015503	0.02
457.0447083	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.3591
Annotation	Denin
Peak:m/z	Relative Intensity
198.9587402	0.03
202.9479675	0.15
209.0342407	0.02
212.8433838	0.04
216.2758789	0.03
217.2229156	0.05
219.0363922	0.17
221.1567230	0.19
227.0870209	0.03
235.1131592	6.46
244.0601501	0.05
245.1263275	0.42
251.6025085	0.06
253.1316528	1.66
257.3323364	0.05
263.1470947	0.18
269.1553040	0.08
277.3148193	3.32
287.1350708	3.68
293.2265015	0.06
295.3490601	0.19
300.9666138	0.05
303.2098999	0.12
305.1214600	6.64
311.2370300	0.04
317.1958008	0.03
320.1441040	0.03
323.2059326	0.93
327.2213745	0.12
331.2704468	0.05
350.9707642	0.13
361.2075806	0.17
379.1017456	0.23
397.1527710	100.00
397.7659302	0.21
415.2698364	34.93
421.1244507	0.05
423.4354858	0.13
447.3038330	0.04
515.0266113	0.02
550.8927002	0.03
582.9856567	0.05
590.7901001	0.03
609.4666138	0.03
657.4337769	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	330.0923
Annotation	Unknow
Peak:m/z	Relative Intensity
95.0634613	0.13
109.9941406	11.26
137.9910278	0.11
156.0727539	86.11
156.9702148	0.22
160.0745544	0.09
166.0594940	0.12
187.0086823	0.21
205.3232422	0.08
240.1175842	0.97
248.0843201	0.06
250.1229248	0.59
252.2480774	0.04
261.0670776	0.19
266.1679077	0.50
267.9874268	0.25
270.0347595	1.01
276.2831116	0.28
284.1415710	31.71
294.1184692	2.38
295.0102234	1.00
312.1169128	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.0874
Annotation	Mannopine
Peak:m/z	Relative Intensity
108.1158600	0.28
108.9711304	0.19
110.1370392	0.18
118.0936661	0.14
131.1086884	0.04
135.9600372	1.41
137.0573120	2.15
153.9755554	100.00
173.1276550	0.24
192.1560974	0.03
210.0441589	0.11
286.9062805	0.06
303.2212524	0.02
329.2081909	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.2542
Annotation	9,12-dihydroxy stearic acid
Peak:m/z	Relative Intensity
96.7787170	0.11
130.1919098	0.11
143.0262146	0.05
169.0940857	0.15
170.2178650	0.06
177.2852478	0.22
179.3804626	0.06
182.9597778	0.10
186.0732880	0.08
187.1056213	0.37
193.2060852	0.12
198.4491730	0.08
201.1004639	0.17
211.3767395	0.06
221.2674866	0.12
225.1194153	0.18
235.2451477	0.06
237.2924500	0.13
239.0764771	0.07
241.0740967	0.51
242.1153259	0.12
245.0095215	0.08
248.3158875	0.05
253.2707825	100.00
254.1581116	0.20
255.1272278	0.21
268.4258423	0.56
269.3507385	0.44
271.1862793	0.64
273.0358887	0.10
275.3587036	0.03
278.0726318	0.06
281.2724915	0.56
283.4151611	0.23
287.2196655	0.03
297.3380737	70.28
299.9674072	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.3231
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
157.0380859	0.55
161.2327576	0.06
179.1192780	0.04
193.4053650	0.09
235.0226440	0.61
245.0845490	0.07
251.3016968	0.14
253.1520081	5.86
261.2485352	0.04
277.1633301	0.07
279.2554321	100.00
339.4337158	0.16
358.5127563	0.07
425.3574219	0.12
427.6690063	0.08
439.3288574	0.07
441.2089844	0.33
447.2323608	0.06
457.6135864	0.10
468.2117920	0.11
476.7801514	0.09
477.3875122	0.07
479.2946777	0.35
480.1329346	0.28
495.1339722	0.09
497.0393066	0.76
497.7053833	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1918
Annotation	Atticin
Peak:m/z	Relative Intensity
133.8679810	0.19
149.2528534	0.10
158.0001068	0.59
159.0711212	0.16
159.9625549	1.34
161.0825500	0.69
162.0039368	0.17
168.9842224	0.11
173.0714417	0.64
174.3934479	0.86
175.0852051	4.02
176.0467834	2.60
177.1871948	0.63
189.0288086	0.08
191.2182007	0.16
193.0542297	2.77
194.0499573	2.92
195.0776062	0.96
201.1229858	0.76
202.1097260	0.29
203.1848755	0.44
205.0524292	0.11
211.1941223	0.06
217.0946350	1.52
218.0621338	1.81
219.1253204	0.38
222.9583435	0.13
236.0792542	0.04
249.1099548	1.57
250.2318420	0.10
251.0262451	0.24
255.1354370	0.06
263.3214417	0.13
267.2468262	0.12
271.0717163	0.35
281.2333069	0.21
287.3883972	0.06
290.4149170	0.14
292.9961548	0.24
299.2553711	0.10
307.4874268	0.18
310.9218750	0.06
316.3898010	0.10
317.3220520	0.31
318.2372131	0.13
319.1862183	0.47
327.3137817	0.14
333.2932129	0.84
351.1507263	100.00
351.7625427	0.28
367.0024109	0.35
379.5948792	0.12
381.2063904	0.22
385.1856995	0.23
393.3707581	0.15
397.4968567	0.18
407.9828186	1.19
408.6375122	0.36
409.4226379	0.71
414.6180420	0.10
422.1373596	0.17
423.0852966	0.44
424.1802979	0.09
425.3672180	0.68
426.4698792	0.70
427.3030701	0.21
429.4739685	0.33
431.2992859	0.67
431.9996948	0.26
433.0408630	1.11
434.3981628	0.19
441.2096558	0.77
445.6483459	0.12
450.8929138	0.23
451.5110168	0.60
453.3550720	0.48
454.3232727	0.10
459.9055786	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.14
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
161.0250244	0.32
178.9494629	0.81
180.1587067	0.02
213.9270325	0.02
215.0778351	0.06
217.0240326	0.01
221.1286316	0.27
222.2023315	0.03
232.9361115	0.23
234.1297760	0.11
251.7962799	0.03
263.1065063	0.03
281.0766907	0.07
282.9712830	0.03
288.2418823	0.12
293.1287842	0.06
297.0595093	0.03
305.0507812	0.14
311.1333008	0.04
318.0914307	0.01
323.1460571	0.39
324.0986328	0.19
325.1927490	0.05
329.0418701	0.04
339.9095459	0.09
341.0215454	0.76
342.0669556	0.13
351.7102051	0.03
354.9388428	0.05
356.8029785	0.44
357.4967651	0.08
359.1051636	0.14
360.3090820	0.31
361.2233276	0.42
366.4471436	0.04
367.2224731	0.02
370.2208252	0.15
370.9424438	0.39
377.2828369	0.14
378.2102661	0.51
379.2376099	1.09
383.2297363	0.78
384.1200562	0.43
385.1485596	0.03
389.2209473	0.02
393.8046875	0.17
394.9878540	0.07
408.9542236	0.07
413.0185547	0.19
425.3194580	0.11
426.1640625	0.10
443.1592407	0.15
444.0166626	0.39
445.0309448	0.18
450.8553467	0.01
457.3716431	0.06
464.9483032	0.07
465.8112793	0.01
466.8427124	0.17
485.0742798	0.07
494.2556763	0.03
494.9254761	0.03
503.2821655	100.00
504.2339478	56.56
505.3367310	18.13
522.9974976	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.3148
Annotation	PS(20:1(11Z)/0:0)
Peak:m/z	Relative Intensity
160.8618469	0.13
201.8446350	0.57
218.0989380	0.14
219.8440094	2.88
220.8480377	0.24
242.3006592	0.10
244.2189941	0.08
250.0085907	0.07
251.7318878	0.12
258.0489197	0.32
265.3049316	3.58
270.9552612	0.32
280.0240479	0.26
328.0448608	0.14
333.1430054	0.16
341.9875488	0.16
343.6369629	0.31
379.7976685	0.11
385.7899170	0.19
407.2702026	0.13
420.1360474	0.09
439.1126709	0.35
445.4501953	0.06
446.5305176	0.12
451.3686523	0.10
454.2976074	4.42
460.2395630	0.65
462.0876465	0.13
475.6243896	0.10
476.3927612	0.64
483.6727295	0.07
490.3582764	100.00
491.4266357	0.18
496.0890503	0.12
504.1257935	0.08
506.4301147	0.13
512.3574219	1.14
514.1611938	1.51
515.3620605	0.09
527.5509644	0.05
531.9071655	0.70
533.4304199	0.34
535.2186890	0.41
536.4246216	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	526.31
Annotation	Unknow
Peak:m/z	Relative Intensity
181.8941345	0.12
219.9996643	0.04
228.1670837	0.08
239.0613251	0.06
241.3511047	0.70
256.9902039	0.24
272.7533569	0.07
281.8311768	0.09
297.6123047	0.14
298.9435730	0.05
355.6345215	0.05
377.9917603	0.05
445.8582764	0.08
452.4613647	0.33
454.1807861	0.19
455.1067505	0.16
466.3461304	100.00
467.3581543	0.52
469.7817383	0.04
472.1311035	0.14
480.3851929	0.46
483.3798828	0.24
488.4279175	0.71
490.2042236	0.16
495.6133423	0.04
507.6727905	0.37
508.4397583	0.38
509.3229370	0.78
511.3468018	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	206.0821
Annotation	2-Acetamido-4-methylphenyl acetate
Peak:m/z	Relative Intensity
69.9271088	0.33
91.0317078	0.06
102.9045410	0.03
132.1614380	0.04
146.9977875	10.62
148.6312103	0.01
149.6289368	0.03
159.9946594	0.05
162.1543427	0.55
162.7973633	0.06
163.9726105	100.00
176.1284485	0.10
178.0144806	0.05
186.9645844	0.02
188.1199799	0.99
190.8269806	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1241
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9576797	2.48
86.7810669	0.67
88.9455337	3.17
95.0373383	0.35
100.9825592	4.76
106.8197098	0.72
112.9226303	7.83
114.8924332	0.66
119.0176849	3.69
119.7879791	0.05
125.0029144	0.30
127.0205460	1.63
128.0025787	0.31
129.1202393	1.22
131.0255432	100.00
142.9734802	2.04
144.9943542	0.73
148.9644012	0.36
155.1296387	0.15
160.1317139	0.34
160.9561005	1.37
167.0809937	0.28
168.9417877	0.47
171.9400940	0.27
173.0067749	6.97
178.9639740	1.29
181.0279541	0.22
185.1407166	1.19
187.3628235	0.11
203.1080322	1.35
205.0051880	0.09
206.2538757	0.28
214.9124756	0.12
219.1183777	0.19
233.0850525	0.49
246.1403503	0.35
247.0524597	0.44
248.9306030	0.10
249.8922729	0.10
257.1334839	0.13
263.3951111	0.94
265.1419067	0.25
274.8732300	0.47
281.2771606	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2415
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
94.97741699	0.34
96.99357605	0.18
111.1019363	0.08
112.886795	0.13
122.7028809	0.20
124.883934	0.21
129.0121002	0.09
133.0456543	0.61
135.3421326	0.29
137.0637512	0.34
138.9512024	1.75
145.3919983	0.25
148.9373474	0.49
153.1427002	1.68
155.147522	0.40
156.9637451	0.19
159.0291595	0.34
169.0974884	0.55
173.0374603	0.20
175.2840576	0.75
176.9793243	0.22
179.3703613	0.06
181.2440338	0.27
183.2242126	0.23
184.6313782	0.11
185.2397003	0.24
190.9304504	0.10
196.9336243	8.09
197.5363159	0.23
198.8879395	0.53
203.1490173	0.14
208.2478333	0.16
211.0425415	2.57
213.3425293	0.24
215.3308411	0.10
221.1069336	2.33
225.2737427	0.80
227.2155762	0.88
233.2911377	0.76
235.1075745	0.06
237.3369446	1.79
239.185791	12.36
241.1991577	0.77
243.0526123	0.31
250.3585815	0.29
251.1432495	1.38
253.2181091	1.96
254.2261963	0.54
255.2008667	0.86
256.1685181	0.21
257.237793	0.58
261.1255798	3.40
261.8083496	0.29
264.8981323	0.33
269.4507446	0.09
270.215271	0.30
273.7171631	0.18
279.2376709	100.00
280.9723511	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.18
Annotation	Coniferinoside
Peak:m/z	Relative Intensity
143.0117188	1.12
144.8560486	0.22
148.0782013	0.12
154.9268494	0.05
159.1177673	0.09
160.9895325	9.05
163.9342651	2.82
166.9508362	0.28
179.0146484	9.39
201.9820557	0.08
202.9650269	0.80
205.0154572	0.28
206.3314667	0.22
207.1815491	0.28
207.9820862	0.39
211.0687866	0.07
220.9607086	2.36
227.1747742	0.23
233.0007019	0.06
239.2347412	0.21
245.1236725	0.12
247.1820374	0.07
249.9608154	0.41
251.0957489	0.15
263.0603638	0.09
281.0324097	0.17
290.3751831	0.44
294.9147034	0.13
323.1386414	100.00
324.1824341	0.12
340.2087402	0.08
340.9259033	0.32
341.5935364	0.52
343.3044128	0.17
367.4359741	0.15
369.1134338	0.15
371.2061768	0.24
374.4685364	0.11
387.0740662	0.19
399.3362427	0.20
407.4026184	0.06
429.0173035	0.26
433.4043579	0.15
435.0063171	0.08
436.5301208	0.06
443.1914368	0.23
445.3900452	0.18
457.2082825	0.63
458.3643188	0.15
459.3733215	0.88
467.3207397	0.76
472.1961365	0.11
472.9528198	0.08
478.4456482	0.13
482.3415833	0.28
484.6883240	0.96
485.3632507	0.19
486.1599426	0.12
487.1676331	0.13
488.3871460	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1188
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
129.1695557	0.08
133.0939941	0.10
136.2009277	0.38
151.3121033	0.05
153.1555481	0.11
157.0023499	0.16
159.2275696	0.19
171.9579468	0.06
187.2187042	0.13
194.9959412	100.00
209.2043610	0.23
216.8141479	0.22
219.1222229	0.52
224.1230774	0.10
237.1793213	0.71
240.8894043	0.12
243.9851685	0.26
260.1600037	0.13
267.3031006	0.14
271.2485962	0.07
287.4529419	0.26
297.3836670	0.42
299.2402344	0.06
310.3854980	0.12
311.1543274	1.36
312.0884705	0.08
312.9907227	0.18
319.2931213	0.06
320.8141479	0.22
322.2095947	0.30
323.3277588	0.22
329.2590027	0.37
337.1892700	0.12
338.9976807	1.34
356.3809509	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1087
Annotation	Lactulose
Peak:m/z	Relative Intensity
89.0061188	0.44
101.0018997	7.78
106.6685791	0.51
112.8943939	15.60
114.9548492	0.61
118.9422302	11.82
125.0657349	0.50
130.9098206	8.37
143.0414124	18.53
148.9159851	2.69
160.9772949	22.51
178.9721222	100.00
221.1354370	0.49
250.7486572	0.13
269.2036438	0.30
280.7852173	4.25
281.5008545	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.11
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
112.7387543	0.09
127.2981873	0.04
134.9943695	0.15
165.3989563	0.03
172.8063354	0.03
180.1192017	0.02
185.0917969	0.06
221.0918579	0.03
223.0918274	0.14
225.2151489	0.05
231.0343628	0.03
233.1216736	0.04
238.9089355	0.04
245.1571045	0.09
249.0753784	9.74
255.1464539	0.03
263.2510071	0.05
267.0663452	100.00
267.8447876	0.03
268.9851379	0.03
272.7853088	0.06
281.2263184	0.03
289.2159119	0.09
294.9887695	0.07
297.4678040	0.04
298.4527588	0.03
299.9586182	0.06
303.3370361	0.11
304.8526306	0.03
306.1149902	0.03
322.0520630	0.02
323.2801514	0.21
325.1799927	6.01
326.8593750	0.02
338.5868530	0.20
339.2986450	0.18
340.0040894	0.03
341.3032837	0.13
342.2584229	0.08
343.2276306	0.73
347.2506104	0.30
349.3034058	0.13
350.2180481	0.10
355.6756897	0.09
367.2317200	0.70
368.5872498	0.03
369.3319397	0.21
370.2663269	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2253
Annotation	Citbismine C
Peak:m/z	Relative Intensity
281.1710205	0.12
339.0792236	0.03
341.2192993	100.00
555.4506226	0.03
637.1271973	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1287
Annotation	Epoxycantabronic acid
Peak:m/z	Relative Intensity
83.13426208	0.06
85.09506226	0.05
87.15209198	0.05
96.99751282	0.23
101.0588074	0.11
102.0320969	0.08
109.0167694	0.28
110.9935303	1.92
112.7743073	0.06
115.0457458	0.07
120.917572	0.06
123.0500183	0.08
134.919693	0.09
138.158844	0.32
138.7997131	0.24
143.0263214	0.24
144.3938599	0.10
148.9789276	0.06
151.131546	0.57
152.9916534	100.00
161.0147095	1.44
163.1543427	0.23
164.161026	0.04
164.9753265	0.11
173.2327271	0.05
175.9924622	0.08
177.2489929	0.29
184.9787903	0.08
187.4909821	0.05
189.2577667	0.20
191.1396179	0.06
192.9870605	0.24
201.138443	1.96
203.1144867	0.40
204.1335144	2.04
205.0528107	0.30
211.1074371	0.09
217.1017914	0.25
219.1387482	26.86
220.1026154	0.06
221.0167694	0.22
221.907135	0.07
224.9408722	0.03
226.9563141	0.10
232.9749756	0.14
235.2273712	0.31
244.1461334	1.55
245.1165924	2.35
245.8131714	0.05
247.4381561	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.27
Annotation	Unknow
Peak:m/z	Relative Intensity
159.2010040	0.74
170.1166534	0.44
188.0393372	39.41
204.9739532	100.00
206.0727234	0.51
251.2084656	0.40
346.5256348	0.61
367.1744995	1.37
378.6035156	0.78
380.0625610	0.39
533.2655640	0.68
542.0972900	0.62
551.4820557	2.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2725
Annotation	PI(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
170.8251343	0.54
204.9861145	0.44
223.0687561	22.06
224.0670471	2.42
241.0685883	56.53
242.0704651	3.23
253.1935120	13.87
254.2225037	4.15
259.1400452	2.13
315.1138000	100.00
316.1937866	6.96
333.1297607	10.00
334.1167603	0.36
389.4372559	2.51
390.1300049	0.29
390.7702637	0.42
397.2993774	0.13
405.1831055	0.18
407.2985229	0.76
477.6833496	0.50
524.2752686	0.38
532.3824463	0.14
534.3405151	0.21
552.1461792	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.2862
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
168.2403412	0.14
173.0350037	0.04
175.2387695	0.11
183.1536255	0.42
185.9308167	0.02
191.1771545	0.12
199.2879028	0.15
201.4003601	0.02
203.2159119	0.05
217.3746490	0.08
223.2003632	0.13
229.1581421	0.06
243.1572418	1.92
245.3632965	0.13
249.2941895	0.04
259.9639282	0.20
261.0411377	1.78
261.6956177	0.14
269.1589355	0.13
275.3757019	0.14
276.9099731	0.08
277.6325989	0.08
279.2211914	0.07
281.3478394	0.60
287.2974243	0.08
289.0545044	0.10
290.7901611	0.04
291.3924561	0.59
293.8050537	0.14
299.0255737	0.60
315.8303833	0.04
317.2624512	5.29
322.5233154	0.14
335.2944946	100.00
335.9531860	0.26
338.9434204	0.16
341.0627441	0.10
353.3812256	0.47
396.8977051	0.05
399.9547119	0.10
405.3634033	0.68
415.0847778	0.13
423.2897339	0.17
441.0443726	0.08
451.0949097	0.13
453.0481567	0.16
463.1846924	0.15
483.1263428	0.06
493.2368774	0.05
495.0517578	0.10
497.4863892	0.12
503.1997681	0.67
505.4006958	0.32
545.0380859	0.14
550.2823486	0.26
558.7349243	1.56
559.3847046	8.62
566.4765015	0.09
577.1985474	31.41
578.0027466	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.1689
Annotation	Laricitrin 3-rutinoside
Peak:m/z	Relative Intensity
219.4099121	0.15
221.033432	0.30
235.8341675	0.10
300.077301	0.21
302.2750244	0.12
318.1485291	1.69
330.1959229	0.37
333.0671387	100.00
357.3258057	0.29
366.1661987	0.09
369.1218872	0.19
375.1237183	0.98
424.968689	0.44
428.0388184	0.13
429.1168823	0.48
439.2156372	0.33
443.1915283	0.13
455.0699463	0.14
457.3607788	0.38
472.1463623	0.23
477.1965942	1.30
479.0941162	8.17
487.1754761	0.70
494.5263672	6.37
495.1622925	32.64
519.1997681	0.28
521.1630249	0.47
552.1343994	0.29
565.1069946	0.51
576.2008057	0.62
579.3283081	0.25
587.1963501	2.19
594.9421997	1.61
597.111145	0.44
599.0732422	0.21
599.8897095	0.34
605.2099609	2.43
623.1399536	3.25
623.7702026	0.17
632.0582886	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	462.2622
Annotation	PE(17:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9136047	0.06
152.6697845	0.05
168.1816559	0.03
173.9953308	0.03
196.0779419	0.16
213.9694672	1.32
225.2959595	0.07
231.8272095	0.07
247.1862793	0.24
265.2434998	100.00
266.0216370	0.08
267.0737305	0.02
301.9330750	0.08
344.5972900	0.04
348.9966736	0.21
362.0700073	0.09
374.3843384	0.04
378.1383362	0.10
381.4542847	0.16
387.3267822	0.18
388.1823730	0.13
390.1391602	0.16
399.9943848	0.03
414.1021729	0.16
416.2079468	0.03
417.5160522	0.06
418.3037415	0.18
424.3823547	0.15
426.0511169	1.14
427.3930359	0.05
434.3797302	0.03
444.1926575	0.07
444.9590149	0.03
446.5323486	0.08
447.2619629	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.2117119	0.03
71.1332245	0.05
84.9400940	0.49
86.8923950	0.50
100.9835052	0.02
110.9053650	100.00
111.6898956	0.01
128.9814911	2.97
130.8075562	1.31
146.8630371	0.23
154.9202423	0.30
172.9797821	26.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1762
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
112.9257355	0.68
124.9238052	0.97
129.0929871	0.33
130.0429993	0.05
131.0473480	0.27
141.4744415	0.06
143.1422729	0.56
144.8786621	0.05
148.5554352	0.09
149.1554718	0.43
151.0673065	0.06
153.0769806	0.07
159.0162659	1.16
161.0832367	9.40
175.2608643	0.16
185.1196594	0.12
186.2264099	0.02
186.8516388	0.08
191.1294861	0.47
194.1772003	0.03
215.0090027	0.35
217.8498993	0.02
220.7188721	0.05
231.1902466	0.12
233.0667419	1.64
237.2727356	0.07
249.1191406	100.00
251.0151367	0.05
261.5985413	0.08
274.8991394	0.06
283.2747192	0.06
291.3088684	0.55
293.1521606	1.32
295.3116455	0.05
314.1697693	0.03
317.1829834	0.03
318.0679321	0.06
335.4428711	0.07
345.1076050	0.25
351.6833191	0.19
362.4276123	0.12
363.2132874	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1082
Annotation	Hydroxytyrosol 1-O-glucoside
Peak:m/z	Relative Intensity
95.0668488	0.05
109.0313110	3.17
112.9606171	0.05
122.9746857	3.09
130.1513214	0.08
130.8023529	0.16
135.1089172	0.43
137.1208954	0.09
143.3132324	0.03
152.9485931	100.00
161.8825073	0.07
171.1474304	0.09
178.8943634	0.09
183.0153503	0.05
184.9706879	0.05
198.9318085	0.04
216.1309204	0.07
219.2631531	0.05
222.8426514	0.07
233.1169434	0.09
243.0306091	0.17
253.1094360	0.06
255.1619263	0.22
257.2241211	0.09
269.1735229	0.41
270.5053101	0.10
271.2465820	0.59
280.0469971	0.08
282.9422913	0.04
287.2269897	0.14
293.6066284	0.07
296.2487183	0.06
297.3011475	0.14
298.4084473	0.05
300.4771729	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.3019
Annotation	Unknow
Peak:m/z	Relative Intensity
177.8217468	0.13
205.0683289	0.05
223.9052887	0.38
253.1273499	0.04
279.3245239	0.78
280.2667236	0.12
316.4080811	0.05
319.0842285	0.02
337.3437500	0.05
440.4309692	0.05
458.3193359	0.22
466.1420898	0.05
468.4887695	0.13
476.3182983	0.05
493.8014526	0.05
504.3961792	100.00
511.5529175	0.07
516.1503296	0.19
517.9884644	0.73
535.0458374	0.17
536.5303345	0.32
553.4037476	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
84.88665771	0.34
87.88894653	0.34
99.04590607	0.60
109.1003571	0.38
111.7025604	1.25
116.936821	0.64
135.1083221	1.31
138.9944458	4.15
157.0368805	0.60
161.1097717	1.39
175.5492401	0.96
197.0905457	3.27
203.0415344	0.49
213.2902527	1.71
221.1676636	2.07
223.3716431	0.73
225.3209229	1.27
227.2401123	0.55
233.0327454	0.22
237.4062805	3.71
239.1737671	10.15
241.3223267	0.26
243.1254578	0.68
251.2427673	2.33
253.1937866	1.53
255.3278809	1.15
261.2191772	2.94
279.2240906	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	578.3094
Annotation	1-Epicrassicaudine
Peak:m/z	Relative Intensity
181.8138123	0.23
186.0905151	0.13
251.9506226	0.15
307.3623657	0.42
309.9501953	0.13
343.2020874	0.46
343.9342651	0.08
345.3442993	0.59
346.3303833	0.72
357.1944580	0.11
365.9270630	0.17
387.3673706	0.11
394.9708252	0.04
418.7271729	0.10
447.4377441	0.46
462.4091187	0.44
472.3884888	0.09
473.3187866	0.46
481.4904175	0.08
482.1390381	0.42
493.1852417	0.22
494.6043701	0.07
504.3823853	0.13
516.6962280	0.06
518.3923340	100.00
519.4468384	0.12
525.3336182	0.13
530.6454468	0.12
532.2496948	62.31
533.3042603	0.42
534.4069214	0.63
540.1268921	0.26
541.8855591	1.98
559.3786011	0.19
560.1270142	0.67
561.3388062	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0474
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
183.0857849	0.01
192.9951782	0.12
193.8880615	0.04
210.9850616	2.43
212.0304565	0.26
235.7335663	0.02
241.0606384	1.19
242.0439758	0.19
244.1158447	0.03
273.1769409	0.03
280.1447754	0.69
281.1373291	0.16
305.1248169	0.16
321.1090088	0.89
323.0569458	100.00
324.0782471	11.90
353.3109741	0.03
385.1361694	1.35
386.1511230	0.28
391.2876587	0.02
403.0468750	2.66
404.1793823	0.24
449.1727905	0.07
467.2008667	0.18
468.2321777	0.01
547.1977539	0.34
548.3593140	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
111.3630753	1.35
116.0009384	0.32
121.2576065	1.67
122.5908966	1.31
124.7264709	0.32
137.2676544	0.29
154.9911499	0.98
157.2802277	0.99
167.151886	0.62
169.0543823	5.63
171.0757446	1.45
176.8620911	5.68
182.8206024	1.29
189.1981049	0.44
192.9518127	0.36
194.9772644	6.41
205.1309204	1.70
209.0007019	6.82
211.1606445	2.83
214.5632324	0.72
217.3137207	0.77
219.130249	0.78
222.8394775	2.75
225.1500854	2.26
228.9322205	0.71
236.2130127	0.53
237.1429138	1.38
239.1566162	2.17
249.1986084	1.38
253.0206909	5.64
255.228363	2.55
264.2868652	2.16
265.056366	2.09
267.1564331	2.13
268.2947998	1.45
270.1613159	1.30
275.1844482	11.23
276.6610718	1.30
278.9056396	0.40
283.2055969	1.27
287.5351562	2.33
293.2089539	100.00
294.0587769	1.15
311.0641174	2.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	482.33
Annotation	PC(15:0/0:0)
Peak:m/z	Relative Intensity
155.9911804	0.24
166.1794739	0.21
170.7123566	0.03
183.9727783	15.72
197.8526611	0.10
199.0081024	0.13
214.9996033	0.08
258.2951355	0.33
266.3081055	0.04
269.1679993	0.12
269.9822083	0.03
277.2921753	0.04
287.2835693	0.05
292.0924683	0.04
299.4335938	0.40
301.3439941	0.06
304.6901855	0.14
309.5329285	0.15
310.6269836	0.21
322.3438110	0.03
324.2095642	0.06
339.3102417	3.43
340.3885498	10.84
341.3354187	6.24
345.3891296	0.16
392.3692932	0.22
403.3299561	0.09
405.4379578	0.13
415.4278259	0.07
419.2189941	0.71
420.1074829	1.64
421.2239990	1.61
422.4508972	0.20
433.4057922	0.09
436.1682434	0.05
437.9467163	0.20
441.2820740	0.04
462.4306335	2.35
463.2505798	22.69
464.3571472	100.00
465.0840454	1.02
481.2001648	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.16
Annotation	Gomisin R
Peak:m/z	Relative Intensity
137.0982361	0.29
146.8779297	0.14
167.1139832	3.49
180.8612976	0.13
182.8487854	0.11
190.9274445	0.37
204.9981995	0.97
206.9985809	0.73
209.1295776	0.92
217.0023346	2.34
219.1804352	0.30
223.4023438	0.09
235.3258057	0.17
239.3324585	0.08
247.0986938	3.16
255.1035156	0.40
267.4677734	0.07
269.1434326	0.15
271.0454102	0.34
279.1001282	0.27
291.346344	0.70
293.2846375	0.17
295.0588989	0.11
297.5567017	0.16
298.7052612	0.87
300.0808716	0.11
301.4735107	0.34
305.2938232	0.45
306.5998535	0.23
307.2631226	1.09
309.0045166	0.07
319.2487793	1.22
321.3700562	0.55
323.2649536	0.64
327.1508789	0.11
330.3591919	2.75
331.350647	2.58
337.3053284	0.10
339.0194092	0.68
340.2215271	0.52
340.9912109	0.17
342.0434265	0.22
345.4896851	0.47
347.4406738	0.46
351.3078308	3.66
355.2493286	0.24
356.3782043	0.39
359.0577087	0.48
360.0918884	0.07
365.4021606	0.51
366.1413269	0.17
367.3936157	0.15
369.1513672	4.22
371.1561584	9.13
373.3327026	1.14
383.1410217	100.00
383.8972473	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1968
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.1507416	1.72
244.2641296	0.24
245.1665039	1.82
253.2746277	0.05
255.1102753	0.67
256.3822632	0.54
257.1099243	0.20
261.1555176	1.26
263.3464966	0.10
269.1793518	0.56
271.2273865	0.12
273.0113525	0.45
282.3122559	0.07
283.1002197	0.23
285.0155640	1.03
287.1171265	14.14
288.5259399	0.40
289.1923523	3.69
290.2264404	0.20
295.1901855	0.07
297.1953125	0.09
298.0832825	0.04
299.1903076	1.69
301.0579224	0.51
305.2882690	0.29
307.3296509	0.05
313.1599121	0.30
315.3615112	0.23
317.3579712	0.24
321.0153809	0.12
325.0006714	0.10
326.0637207	0.31
327.2279663	0.17
328.9915161	0.98
331.4442749	0.58
335.1807556	0.07
337.1215820	0.50
339.2614746	0.37
340.9702759	0.86
344.7017517	0.18
346.5086670	0.08
347.2130127	0.62
349.0980225	0.26
363.1278076	4.82
365.1637268	0.29
367.2125549	0.34
369.3930664	0.28
370.9645996	0.19
379.1467285	0.62
381.2161865	1.44
383.1696167	0.20
387.1165466	0.34
388.3911743	0.19
389.4168701	0.28
391.2347412	0.22
392.9981689	0.10
395.1076965	3.09
399.2232666	0.19
403.2198486	0.12
405.2281494	7.47
407.2422485	20.45
409.2763062	1.43
411.2852783	0.30
413.0985718	8.94
414.2404785	0.38
417.1658936	1.91
423.0913086	5.66
425.2202759	19.36
431.1360474	0.18
433.1865845	0.24
435.2609253	3.05
437.0321045	0.28
447.2593994	0.28
449.1506348	12.82
451.1459351	13.88
452.1674194	0.59
453.4226074	0.20
455.2778931	0.08
459.2308350	0.10
465.1985474	0.53
467.1845093	1.34
473.2730103	0.15
477.1700439	0.06
481.3948975	0.07
483.4518433	0.25
491.3386230	0.29
493.2463989	0.56
499.5007935	0.32
501.2616577	0.26
502.1772461	0.06
505.3111572	0.05
513.3110962	0.18
515.2792358	0.83
517.5172119	0.41
519.2933960	0.55
523.9028320	0.13
525.2377319	2.34
531.3427734	0.69
533.2697754	5.73
535.2817993	0.65
539.1660767	0.28
541.1661987	0.60
543.2771606	14.03
545.2708740	0.26
551.1546631	0.11
557.1359253	5.41
559.2553101	4.07
560.1370239	0.07
561.2005615	2.53
567.4031982	0.22
569.2372437	4.11
575.2420044	25.95
577.1796265	45.30
578.1303101	0.26
580.3911743	0.51
585.4426880	0.79
586.4433594	1.53
587.2296753	14.68
590.2755737	0.11
591.5527954	0.56
599.5177002	0.26
601.2835083	1.00
603.3557739	0.11
611.1611938	0.37
616.2612915	0.10
617.2065430	0.66
619.1881104	3.05
629.3550415	1.46
630.3969727	0.20
634.8845215	0.33
636.1694946	0.06
641.3587646	0.16
643.3004761	0.05
644.2310181	0.70
645.4727173	0.13
651.0431519	0.44
653.3484497	0.13
656.1658325	0.06
657.0176392	0.50
659.6110229	0.10
665.0562134	0.23
669.2244873	1.07
670.9094849	0.35
677.1896362	4.01
679.4343872	0.55
680.7168579	0.22
684.2796631	0.27
685.0247803	0.21
690.3848267	0.17
693.4040527	0.04
695.1475830	100.00
696.0244751	0.08
697.2972412	1.17
699.3013306	0.07
701.3444214	0.77
702.2709351	0.21
703.1460571	0.50
711.3779907	0.31
713.1299438	32.44
716.8247681	0.15
719.1162720	1.83
719.7400513	0.12
721.0817871	3.33
721.7299805	0.11
723.0123291	0.15
724.3547363	0.21
725.0976562	0.13
727.4096680	0.20
737.3601685	0.94
739.1586914	39.75
740.0748901	0.26
746.0499878	0.20
749.2503662	0.16
755.3747559	0.75
756.2914429	0.23
761.4671021	0.13
763.3143921	0.31
770.2786255	0.57
777.5540161	0.16
779.0963745	1.10
779.8577271	0.71
781.2448120	0.28
785.0551147	0.07
788.8265991	1.88
789.7122192	0.14
793.1756592	0.16
800.6565552	0.29
801.2886353	0.21
802.4049683	0.90
803.3314819	0.10
806.8992310	0.94
818.7261353	0.10
819.9968872	0.13
821.0762329	0.95
823.2863770	0.10
827.2754517	0.10
829.1105347	1.46
842.4235840	0.08
844.9378662	0.11
847.1190186	19.34
847.7789307	0.15
849.4168701	0.17
875.3839111	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.1293
Annotation	Verproside
Peak:m/z	Relative Intensity
142.8978271	0.10
152.8781433	0.10
179.0629578	4.68
191.2050171	0.24
241.2005310	0.16
243.2487183	0.24
258.7350464	0.13
259.3866272	0.12
268.9117737	0.20
271.9437561	0.12
291.1962585	0.04
305.1068115	0.46
311.0581055	0.13
315.0361633	0.15
317.0480652	0.07
319.3500061	0.09
333.8668823	0.10
335.1395264	100.00
337.5180664	0.07
339.2221069	0.11
341.2950134	0.13
361.0453186	0.26
377.1864929	0.22
379.1069946	0.14
385.7590637	0.09
402.3780212	0.18
405.3743591	0.10
421.3852234	0.12
423.2517090	0.20
424.2921143	0.11
433.3050537	0.26
436.0939636	0.09
443.3730774	0.09
450.1463928	0.32
450.9137268	0.21
453.1406860	0.30
454.0622253	0.13
458.9771729	0.11
461.2187805	4.78
461.9161682	0.20
465.4900513	0.18
470.1293640	0.21
479.2413635	0.69
483.1037903	0.12
488.7207642	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.9
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1618805	0.08
199.0442505	0.02
248.3023834	0.04
255.1373596	0.12
273.0365601	1.23
274.0307312	0.29
275.2134705	0.18
276.1304016	0.16
277.3515625	0.07
359.0462646	0.10
360.1566162	0.04
361.0994873	0.21
361.9431763	0.16
387.1860962	0.12
388.7670288	0.03
416.0081177	0.05
427.0036621	0.49
427.9352417	0.49
429.0020752	2.59
430.2095947	0.47
443.3399048	0.02
444.0516968	0.07
445.1865234	0.09
473.1156616	0.26
473.9077148	0.66
474.9079590	2.29
475.9332886	0.36
486.9609985	0.11
497.2504272	0.05
498.9863892	0.03
503.9300537	0.05
515.1113892	0.02
516.0891113	0.12
516.8955688	0.05
520.9767456	0.02
541.1417847	0.42
542.8370972	100.00
543.8979492	18.03
545.0751953	0.15
549.8326416	0.03
560.5140381	0.29
561.8986206	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	309.2055
Annotation	Albocycline
Peak:m/z	Relative Intensity
95.13838196	0.11
97.09339905	0.04
108.5130539	0.04
111.0054321	0.05
116.5830002	0.08
120.9477463	0.10
123.1137085	0.26
125.0833435	0.06
131.1848145	0.05
133.2910767	0.13
139.1377258	0.08
140.0342102	0.03
141.1811981	0.04
143.2893982	0.03
145.0066528	0.22
147.080719	0.11
154.9815674	0.09
157.0454102	0.02
159.1815491	0.07
163.1214142	0.16
164.874939	0.22
169.0739441	0.06
171.0045166	0.94
173.0808563	0.12
174.6165314	0.14
175.3321533	0.33
180.9966125	0.04
183.1921387	0.10
185.1520996	0.11
186.7139282	0.13
189.2531128	0.14
191.1845398	0.24
193.2928772	0.06
197.2842407	0.11
205.0655518	0.08
207.0109558	0.24
208.8862	0.48
211.2536011	0.86
212.3377991	0.04
213.3585205	0.06
217.2656555	0.19
219.1641541	0.08
221.3933716	0.08
223.2861633	0.39
225.0435791	0.03
227.1584167	0.24
230.8766174	0.14
233.2904053	0.20
235.1339722	0.03
237.2256775	0.16
239.2258606	0.06
245.3095703	0.48
247.265686	0.07
249.3373413	0.48
251.2030334	0.35
254.6225281	0.07
255.296936	0.87
263.0675049	0.14
263.7443848	0.06
265.178833	0.49
267.321167	0.03
268.4508667	0.14
270.0401306	0.15
273.1535645	10.14
277.102478	0.27
279.2259521	0.08
281.148468	0.63
288.418457	0.03
291.1911011	100.00
291.8806152	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	280.0825
Annotation	4-Hydroxyphenylacetylglutamine
Peak:m/z	Relative Intensity
112.9674149	0.04
116.7145386	0.06
118.0189819	0.05
131.0024414	0.04
132.0920105	0.03
140.2117615	0.02
146.9646912	0.06
164.0160980	4.03
166.2568970	0.11
168.1941376	0.02
172.8251648	0.02
183.2734528	0.05
194.0172424	0.06
195.0281982	0.04
218.1901245	0.03
219.1691589	0.07
220.0330505	0.03
233.1560364	0.03
234.2117310	0.06
236.0791626	0.21
237.6580505	0.07
244.0859985	10.55
250.0014648	0.05
252.3914795	0.03
262.1131592	100.00
262.9982300	0.03
264.8518982	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1383
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0024414	0.12
184.1287231	0.33
201.1345673	0.10
220.7948914	0.10
232.8872070	0.63
250.9896851	0.11
252.9629364	0.30
258.0350647	3.81
259.1252136	7.61
287.0387573	0.17
323.1810303	1.59
324.2704163	0.25
325.4044800	0.21
329.2615967	0.10
341.2029419	0.79
354.9492798	0.14
383.2371826	0.75
394.9614868	0.44
402.5214844	0.56
403.2134399	1.63
413.5528564	0.17
418.1408691	0.32
419.8711548	0.19
421.1542358	9.45
425.0603027	0.27
439.0862427	4.22
442.7910156	0.25
444.2728882	0.21
455.1464844	0.68
464.9788818	0.21
468.9196167	0.48
480.7805786	0.12
503.3129883	100.00
504.3930664	0.34
526.2848511	0.14
538.0260620	0.10
542.1354370	0.07
564.7199097	0.42
566.2798462	0.12
583.2966919	16.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	470.1579
Annotation	Unknow
Peak:m/z	Relative Intensity
143.9685211	0.07
162.1388245	0.34
163.0196838	0.60
179.0301208	2.12
193.1425171	0.03
201.0137177	0.03
207.4589386	0.04
233.1110992	0.47
237.8616333	0.05
242.1177673	0.04
259.1744690	0.03
269.0327454	0.02
286.8749695	0.03
290.2177429	0.25
291.1917419	0.04
305.9782104	0.07
308.0639954	100.00
308.6693726	0.22
309.4754028	0.01
330.8659668	0.05
336.6965332	0.10
340.6611328	0.33
341.3833008	0.12
349.1032104	0.05
383.1414185	0.03
420.0331726	0.02
424.0122986	0.07
426.8860474	0.07
429.3305359	0.14
434.1255798	0.05
435.2687988	0.02
452.2548523	0.02
452.9109802	0.09
461.0866394	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1101.3083
Annotation	Unknow
Peak:m/z	Relative Intensity
362.3460693	0.13
495.2598267	1.60
512.9460449	0.21
627.1895752	0.66
730.8962402	0.45
747.7334595	0.65
807.4938965	0.23
837.4697266	1.24
903.3118896	0.23
909.2780762	3.36
909.9144287	0.76
921.4768066	2.20
939.3718262	0.99
951.3604736	0.19
969.3284912	100.00
970.1407471	0.42
981.4727783	2.86
1041.4025880	37.99
1042.3792720	0.69
1083.2943120	15.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	905.2249
Annotation	Smilaside L
Peak:m/z	Relative Intensity
372.4376221	0.19
478.4330444	0.06
540.5016479	0.10
644.1503296	0.11
645.1233521	0.09
672.1628418	0.19
706.9924927	0.08
711.4750366	0.06
739.4451294	0.26
803.1051636	0.03
818.2061768	0.05
819.3134155	0.33
829.7209473	0.07
850.9561157	0.06
854.2244263	0.18
869.1690063	100.00
869.8449707	0.52
875.6520996	0.04
911.7420044	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
95.04554749	0.09
97.11283112	0.65
98.82065582	0.28
109.3231964	0.29
113.0988617	0.49
115.1256866	0.34
120.9889755	0.28
123.0491486	0.08
124.8022614	0.23
127.0500793	0.14
132.8417206	0.08
139.0291748	4.07
140.8197937	0.74
142.9711914	0.37
146.9560547	0.04
149.2683411	0.47
150.8744354	0.36
152.8648071	1.20
155.0717163	0.14
159.0036774	0.18
161.0830688	0.21
163.0373688	0.21
164.9977112	0.33
167.2136993	0.39
169.0024261	0.51
173.0714417	0.08
179.2639465	0.08
181.0496216	0.11
182.8742828	1.19
183.5342712	0.12
184.9891968	0.57
191.1321564	0.10
193.2291565	0.65
195.0569	0.27
197.0743866	4.89
198.8780518	0.41
203.2729492	0.46
205.0801392	0.96
209.1222839	0.24
211.0307007	1.34
213.1328735	0.27
219.2789917	0.07
221.2029114	3.28
223.1726685	0.32
224.4485779	0.48
225.3144531	0.66
226.8935242	0.09
233.3662415	0.58
234.1622314	0.41
235.2936707	1.16
237.0724487	1.46
239.2145081	10.13
241.5435486	0.29
243.2398071	0.24
250.975708	0.72
253.1028748	1.32
255.1007385	1.32
256.0971069	0.34
257.0690918	1.45
261.1693115	3.21
262.8224182	0.25
277.1084595	0.11
279.2322998	100.00
280.0183716	0.47
281.3800659	0.22
297.2414551	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.9339
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0116730	0.15
368.8605347	0.07
382.9314575	0.30
402.3372192	0.10
411.1571045	0.08
423.2595215	1.71
424.1412354	1.61
425.0435181	3.69
426.1384888	6.28
427.0102539	5.99
429.0343628	0.12
440.4340210	0.48
441.2987671	0.33
442.5443115	1.64
443.9362183	1.03
464.8468628	0.46
465.7796021	2.28
467.2241821	1.10
483.2044067	0.08
492.3085327	4.24
492.9885864	64.94
493.9862061	100.00
495.0198975	6.49
496.0058594	0.12
508.7499390	0.15
510.8231812	27.09
511.8434448	32.06
513.0538940	3.01
513.9867554	0.14
516.9340210	1.87
519.0327759	0.44
522.0111694	0.49
525.2583618	0.36
526.5270386	0.99
527.3669434	0.34
528.1185303	0.49
529.4651489	1.29
530.9409790	0.26
534.2617798	0.31
539.0151978	0.60
539.9427490	0.80
547.7606812	0.33
549.1353760	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.1537
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
220.8787689	0.12
253.9082947	0.08
273.2064209	0.27
290.2236328	0.12
291.1785889	0.09
301.2311707	0.15
319.0833435	100.00
319.7007751	0.87
360.9517212	0.16
371.0975952	0.15
385.1257935	0.66
397.1008911	0.21
445.2686157	0.48
446.8291626	0.06
454.3928223	0.22
457.3555298	0.16
463.0374756	0.92
465.1705322	11.25
470.9089355	0.09
480.5103149	3.33
481.1107178	44.53
486.8360596	0.05
505.0752563	0.58
506.8313599	0.36
507.4896851	0.38
523.2673340	0.24
543.4689941	0.40
547.2605591	0.09
573.0042114	0.93
573.6880493	0.15
591.2847290	0.49
609.2747803	2.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	216.0876
Annotation	2,3-Dimethyl-3-hydroxyglutaric acid
Peak:m/z	Relative Intensity
70.0635605	0.51
70.8596649	0.81
87.9475098	12.15
96.9251862	0.46
100.0958405	5.74
100.9337311	62.34
113.9058533	33.18
114.8914642	20.20
132.0274506	6.13
154.0007172	11.74
172.1037750	100.00
173.0965881	0.08
198.1272736	76.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	901.2612
Annotation	Kaempferol 3-rhamnosyl-(1->2)[rhamnosyl-(1->6)-galactoside]-7-glucoside
Peak:m/z	Relative Intensity
403.1301575	0.16
445.3844604	0.10
493.4118652	0.19
535.3128052	0.30
567.0126953	0.03
569.3394165	0.30
575.5755005	0.10
639.4797974	0.05
665.5901489	0.23
682.1940308	0.03
696.3109741	0.06
697.2158813	0.11
698.5299683	0.07
712.1436157	0.03
739.2531738	100.00
739.9651489	0.61
745.1267700	0.03
770.8925171	0.18
780.9594116	0.06
871.1599731	0.13
882.8411255	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2208
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.966362	0.31
93.12017822	0.16
95.06784058	0.42
96.97434998	0.07
99.04347992	0.64
101.0132294	0.07
108.9873123	0.20
119.3325882	0.19
121.1678314	0.15
123.2603683	0.26
128.8640594	0.28
135.0819244	0.31
138.1284637	0.07
139.1358032	0.17
141.1260681	0.10
142.9088135	0.28
147.0749817	0.14
152.902771	0.06
155.0336914	0.50
156.9451599	0.25
161.0531158	0.10
163.0289459	0.10
164.973114	0.31
167.0835876	0.24
169.0313416	0.25
170.9379425	0.25
175.3226929	0.12
176.9957581	0.51
181.1608887	1.10
183.0645752	0.20
193.0050049	0.63
195.1387482	0.81
195.7484589	0.29
197.1117249	0.28
199.072876	0.21
206.0053101	0.21
207.5043335	0.25
209.129425	0.54
211.1546936	2.46
212.8933411	0.23
217.0826111	0.31
219.3039856	0.75
223.2279053	0.67
225.2518005	0.87
229.3831177	1.01
233.0383606	0.33
235.2781677	0.17
237.0140381	1.14
238.5686951	0.07
239.2255554	0.57
241.3424683	0.27
243.1687622	0.22
249.0637817	0.23
251.380249	0.99
253.0970154	1.42
255.1843872	0.74
257.1965332	1.57
264.0091248	0.19
265.175354	0.83
267.1602173	0.25
269.9472046	0.16
272.942627	0.33
275.2043152	6.64
283.2080078	0.46
284.2062073	0.09
287.7931519	0.20
291.3209534	0.85
293.2155762	100.00
293.9089966	1.59
295.2619324	0.18
302.1217651	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.1815
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0375366	0.22
130.0668030	1.39
147.0512390	21.08
155.9467010	100.00
163.1311798	1.53
172.8804321	0.37
180.7188110	1.06
188.1986084	0.23
215.1446838	0.54
239.6831665	0.33
243.0301514	0.65
246.9031982	0.29
257.0024414	0.21
260.1293030	0.54
260.9155579	0.58
265.9574890	0.37
267.2894287	1.34
269.3282471	0.15
270.0782776	0.34
273.1537170	22.72
278.7313843	1.22
280.8182068	0.34
283.9980164	8.78
285.2046814	12.45
292.6638184	0.91
300.4117737	0.40
302.1755371	0.13
308.1838684	1.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.2656
Annotation	Sinapoylspermine
Peak:m/z	Relative Intensity
135.0699310	0.04
138.2013550	0.01
142.1185760	0.01
151.0248413	0.01
152.9699402	0.03
154.9348602	0.02
187.2950897	0.01
213.1214294	0.01
245.1371460	0.01
267.2510986	0.03
282.0122070	0.00
298.3912354	0.01
309.4697266	0.02
313.9790649	0.01
320.4721680	0.00
323.4094849	0.04
326.3986206	0.03
330.1287231	0.03
333.6881714	0.03
346.3175354	0.04
359.6119690	0.01
361.4003906	0.01
362.3455200	0.01
363.4695435	0.01
364.5020142	0.08
365.3320312	0.01
371.4181824	0.06
375.9573975	0.03
379.6363525	0.02
387.3848572	0.00
389.3705750	100.00
390.3882751	57.07
391.3310852	0.35
392.4458008	0.10
393.3290710	0.01
394.2754211	0.01
409.2612610	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	349.0125
Annotation	Chloromonilicin
Peak:m/z	Relative Intensity
112.8817902	0.03
115.0231781	0.06
120.1927872	0.05
139.9468842	0.05
143.1161804	0.04
145.6203156	0.05
166.7129517	0.06
179.2874146	0.07
180.8753662	0.08
185.0109711	0.04
187.3200531	0.08
197.2227173	0.11
198.1738892	0.04
209.8454590	0.02
216.0797424	0.22
218.0350647	0.13
219.0433044	0.13
225.2632446	0.08
232.1549072	0.07
245.1535645	0.06
246.1049805	0.05
254.0606384	0.26
259.1583862	0.19
261.1355286	0.14
269.3542480	0.04
272.1036377	0.89
273.2337036	0.19
274.8108826	0.10
275.9768677	0.05
277.7020264	0.16
283.5615540	0.04
287.3534546	0.08
288.1492615	0.03
289.1427917	0.19
291.0272827	0.05
301.0793762	0.02
302.0271301	0.87
303.0820312	100.00
304.3242188	0.10
305.1729431	0.61
313.1542358	0.44
318.4590454	0.05
320.2050476	0.52
320.8828735	1.00
330.2313843	0.05
331.2561035	0.25
332.1916809	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
192.0152893	0.11
212.8791046	0.82
296.7927246	13.76
317.2213135	0.58
323.2440186	0.33
336.9665527	0.25
353.4175415	0.15
355.1127319	7.95
356.0296631	0.20
356.9211426	0.17
374.4815674	0.49
380.6787109	80.33
386.7561035	0.85
393.2125854	0.27
394.1281128	0.47
400.9068604	0.13
422.9035034	0.19
428.9477539	0.46
440.8744507	0.20
461.9442139	0.12
464.5200195	100.00
465.2249146	3.24
484.1300659	0.57
488.8636475	0.57
501.9475708	18.93
502.9805298	1.36
529.9207764	4.19
530.9983521	1.27
548.5436401	0.13
558.8410645	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.1404
Annotation	t(6)a
Peak:m/z	Relative Intensity
162.0074768	0.93
170.040741	0.19
191.0307617	0.13
194.1291504	0.11
205.0947876	0.57
208.3463898	0.39
212.7590637	0.15
215.0479736	0.30
220.1833344	0.10
240.3440247	0.26
246.036377	0.45
251.1292419	0.39
261.1251526	0.58
268.2436218	4.63
269.221405	0.38
281.0934448	100.00
291.3731079	0.49
293.9827881	0.78
309.0464478	0.48
323.3919678	0.14
336.2652588	0.13
339.2713013	0.66
351.4580994	0.62
367.7721252	0.45
369.346405	0.13
382.6456604	1.11
395.0022888	1.41
395.6515503	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0667
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
69.0040665	1.42
70.8981476	1.27
82.8290939	4.30
84.9159851	2.01
86.9644852	42.11
88.9716339	3.54
96.8764343	0.78
98.9229584	5.05
100.8646698	0.08
103.0202026	0.17
110.9584045	15.67
112.1250458	0.21
112.8965759	0.78
114.8562317	40.86
118.8871307	0.16
125.5042572	0.57
128.9766235	100.00
129.9892120	0.27
131.0609436	0.46
141.0090179	4.48
144.2643890	2.66
145.0527954	1.56
158.9333954	72.49
161.5867157	0.09
162.9070740	9.55
176.8702545	3.73
190.9113922	8.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.1323
Annotation	10-Deoxymelittoside
Peak:m/z	Relative Intensity
156.9906464	0.26
167.2724457	0.13
193.1855164	0.08
207.1286163	0.08
228.3068237	0.15
247.2954102	0.04
259.1437073	0.03
265.1304016	0.05
289.2640991	0.24
290.5952454	0.17
294.9053345	0.15
304.2323608	0.10
315.1972656	0.04
316.0169067	0.03
319.1837769	0.39
323.1359253	1.72
329.3378906	0.14
337.0864868	0.63
341.0546875	0.22
342.5186768	0.21
344.1458740	0.18
346.0617676	0.26
355.2501831	3.05
359.2366943	0.61
367.2238159	0.04
368.6331787	0.19
373.4509888	0.10
390.3457642	1.24
391.0292358	2.29
403.1621704	0.07
406.0238647	0.06
409.1947021	0.16
416.1251221	0.06
424.3815308	0.08
433.9772949	0.03
436.1618652	0.12
437.3474121	0.28
440.3110962	0.12
442.8739014	0.14
452.0494385	0.05
456.3762207	0.05
457.9184570	0.15
461.0031128	0.24
463.2012329	0.14
465.9603271	0.12
469.4452515	0.12
473.3236084	0.04
479.1379395	0.05
481.0385132	0.05
495.1168823	0.04
499.3672485	0.14
503.3883057	0.29
504.7774658	0.10
505.5057373	0.11
507.1918945	0.34
508.3795776	0.32
509.4168091	0.34
510.6727905	0.09
516.3966064	18.94
517.2103882	100.00
526.1138306	0.13
534.2288208	0.05
535.1582031	0.20
535.9899902	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.288
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.1806946	0.28
222.9630432	36.03
224.0681458	0.78
227.1108093	0.25
241.0624390	58.12
242.0909119	2.86
258.9990845	4.06
259.7941895	0.99
279.2712708	34.52
280.3179321	4.87
281.1921387	0.24
315.0990601	100.00
316.0808716	8.17
333.1259766	14.86
334.2310791	1.23
415.2759399	2.37
416.2147217	0.57
433.2365723	1.47
434.3145142	0.84
504.2146606	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.1837
Annotation	Unknow
Peak:m/z	Relative Intensity
179.9038239	0.14
205.0879822	0.27
207.0996246	0.12
207.8914032	0.12
210.9461212	0.05
212.0273132	0.11
221.0127563	1.87
221.9793396	1.18
238.5943146	0.28
249.0815277	0.15
250.3844147	0.10
250.9944458	0.92
251.9479065	0.22
259.2177734	0.07
265.1214600	0.61
267.0613403	14.97
268.0772705	3.85
269.0048218	1.06
270.8617554	0.33
274.2308960	0.12
281.1079712	7.59
282.1566772	1.68
284.7756958	1.17
285.9566650	0.14
294.9414062	0.43
297.2595215	0.06
298.6536865	0.53
299.7463379	0.10
301.3641968	0.14
307.7459106	0.07
308.9619141	0.28
314.9300537	0.04
321.9728088	0.30
326.5557861	0.04
328.3214722	0.09
331.3652954	0.07
338.9859619	0.69
340.2272949	0.25
352.5069580	0.15
355.0441284	100.00
356.0947876	33.42
369.2506104	0.23
371.0721436	5.81
372.1325684	0.97
373.0634766	0.23
389.4468994	0.20
391.6964722	0.10
395.4671021	0.14
401.3197021	0.16
402.0858154	0.14
407.6740112	0.17
413.3336792	0.21
415.2089233	1.05
415.8603516	0.44
431.4979858	0.32
433.4508057	0.17
435.0629883	0.11
449.6159058	0.28
454.3526001	0.04
473.1612549	0.24
485.1441650	0.04
488.9212036	1.52
490.1863403	0.97
491.5223389	0.11
504.9827271	0.03
517.6389160	0.10
519.0372925	0.07
524.9398193	0.03
525.8060303	0.04
529.3853149	0.30
532.8677979	0.18
540.3880005	0.16
544.3731079	0.21
546.2529297	0.10
558.2973022	0.16
561.4132080	0.10
565.0148315	0.09
565.7154541	0.09
568.1515503	0.07
574.6489868	0.11
575.5581055	0.05
576.9605713	2.54
577.9627075	2.16
583.2855835	0.11
592.5958252	5.80
593.6660767	0.85
611.6498413	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	327.34
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0383453	0.50
136.8243866	0.23
153.1622314	0.08
155.2185669	0.37
169.2642517	0.25
185.3541107	0.65
197.0670319	0.49
199.0095215	0.19
203.1430054	0.27
208.8188782	0.11
213.0394897	0.61
227.2031555	0.41
228.0880432	0.24
232.9780884	0.38
235.1711426	0.09
245.3672485	0.15
249.1500854	0.89
250.8227844	0.68
254.9515076	0.20
256.4534302	0.24
263.0975647	0.20
267.9142151	0.63
271.1733704	0.49
272.9580688	0.21
277.6465454	0.87
281.0909119	0.08
288.3135681	0.23
299.1876831	0.70
309.3140259	8.22
310.4307861	100.00
327.4101562	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.1071
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
119.0157623	0.39
123.0146332	0.26
136.0114899	3.90
137.1066284	0.29
147.0377960	1.04
151.9867554	0.16
152.6945190	0.30
154.0676575	0.94
156.1598358	0.15
157.0301361	0.13
161.1447144	0.07
165.0219421	9.75
166.2690277	0.46
175.9957275	0.20
180.2190552	0.23
181.9477234	100.00
193.1626587	0.11
195.2274170	0.06
209.0951691	0.10
210.7893372	0.64
212.0030975	0.59
221.3372498	0.23
222.1604309	0.31
223.3854065	0.28
226.1029053	0.23
229.1193237	0.05
230.2840881	0.04
242.1192322	0.05
242.9777527	0.25
244.1021423	0.12
245.0880737	0.18
248.1816101	0.98
253.8144531	0.12
256.1809082	0.48
268.0592041	0.09
269.2025757	0.08
271.0301208	0.19
273.1354980	0.11
274.0728760	0.20
292.2373047	0.23
297.9924927	0.17
299.1168213	1.09
300.7407227	0.06
303.2877502	0.14
308.0329590	0.41
309.1660156	0.27
310.1229248	0.14
311.4117737	0.13
314.1915283	0.20
326.1055298	1.71
327.2476807	2.17
328.3042297	1.52
329.1846924	0.21
335.9666138	0.14
337.1932678	0.57
338.1354675	0.49
352.0187073	0.26
355.3716431	2.13
356.2107544	4.36
357.2605286	0.41
366.1242371	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3957
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
220.6316833	0.04
235.1862640	0.05
253.3472290	0.16
287.1887512	0.14
305.0818787	0.12
365.2539062	0.04
379.2154541	0.13
380.9713745	0.03
388.5517578	0.08
397.2658691	7.69
407.4374390	0.04
409.1383057	0.03
415.3620605	0.85
464.4407349	0.02
472.3057251	0.10
480.5197754	0.04
503.2303467	0.12
595.8556519	0.05
635.3041992	0.08
641.3609009	0.04
652.4005737	0.08
670.0977783	0.02
679.2244873	100.00
680.1508789	0.16
681.7764893	0.08
686.4656982	0.07
687.6501465	0.07
689.1332397	0.12
694.3425293	0.08
704.8208008	0.06
707.6685791	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0578308	0.02
200.1271973	0.02
216.9729004	0.03
229.9920654	0.03
244.9534149	0.02
272.9805298	7.48
274.0720215	1.72
386.9475708	17.58
387.9912109	7.24
482.1049194	0.01
499.0059204	0.10
500.9348755	100.00
501.8761597	44.32
502.5346680	0.06
509.9640503	0.02
560.1359863	0.09
568.7492676	0.06
569.9312134	0.09
597.0388794	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0375824	0.16
218.0705719	0.06
228.9422913	0.07
230.1178589	0.07
273.0372620	9.97
274.1111450	3.91
275.0251160	3.05
386.9929199	15.61
387.9689331	13.79
389.0474243	10.57
472.8994751	0.05
475.0057983	0.15
482.8405762	0.03
500.9582520	40.24
501.9214478	90.37
502.8850708	100.00
503.5120850	0.38
527.9949951	0.03
543.1988525	0.02
544.8079224	0.02
552.2243652	0.03
571.0592651	0.13
589.7464600	0.17
598.1818237	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.2179
Annotation	Desacetylvindoline
Peak:m/z	Relative Intensity
179.0108032	0.18
185.7973175	0.24
193.1678467	0.38
209.407196	0.74
221.0550232	0.34
250.1202698	0.26
255.3575439	1.21
263.7190857	0.26
272.1197205	0.55
285.3401489	0.23
291.0534058	0.98
296.2127991	0.23
305.7354736	0.56
317.1399231	0.88
328.4396973	0.93
332.2829285	0.24
334.5004883	0.67
339.140625	0.43
341.1483459	0.98
351.2896729	0.38
353.1903381	100.00
355.2074585	0.83
367.0634155	2.04
368.9677124	1.83
369.9041138	0.84
371.3541565	2.14
372.1660767	0.54
375.1888123	0.64
377.1627808	2.28
378.1016846	3.27
385.063385	0.21
386.7104492	0.51
395.3780823	3.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
201.1298523	0.03
201.9840088	0.02
225.1740112	0.16
242.1826172	0.05
255.3133392	0.04
261.5499268	0.02
279.2777710	0.66
299.0894775	0.05
379.2891235	0.01
415.6193848	0.01
433.3223877	0.09
454.6595459	0.03
468.2129517	0.01
475.5154419	0.04
476.5037231	0.02
478.4683228	0.04
490.4998169	0.01
504.3593140	100.00
505.3965454	0.42
506.3093262	0.03
528.2116089	0.03
546.4008789	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.3229
Annotation	PE(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
165.9291687	0.43
183.9918060	80.65
238.5274963	0.04
311.4934692	0.25
328.0744629	0.33
425.3516235	0.05
472.1915588	0.14
476.3957825	100.00
477.0106812	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2587
Annotation	8''-Hydroxypactamycin
Peak:m/z	Relative Intensity
167.0463715	0.02
196.0973511	0.31
209.0119934	0.09
211.2828979	0.07
213.1191101	2.68
222.9363251	0.03
231.0631409	0.24
240.0948639	0.24
243.0218811	0.05
259.1489868	17.69
269.0919189	0.04
277.2471313	0.10
279.1630249	0.17
280.1593628	0.41
296.1253357	0.22
311.8764648	0.02
313.2677002	1.63
314.1988525	0.06
322.2196045	0.21
323.3611450	0.08
331.2669678	0.72
337.3624268	0.19
349.3065186	0.06
353.3293457	0.11
359.2179565	100.00
359.8639526	0.80
373.0294800	0.26
399.1801147	0.24
409.0909424	0.05
417.0225220	0.08
418.1179199	0.38
425.3297729	0.07
426.1951904	0.51
427.0770874	0.47
442.0467529	0.08
446.1550903	0.13
459.3950806	1.74
465.5050659	0.02
468.3038940	0.05
470.4013062	0.14
475.1093750	0.03
483.1463623	0.05
495.3989868	0.35
507.5285034	0.13
509.4197388	0.17
526.1586914	0.39
527.3287964	1.91
528.0636597	0.04
530.0126953	0.11
536.2727661	0.08
545.1604004	0.04
553.3828125	0.05
554.9436646	0.36
572.9077759	0.07
580.2149048	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.2236
Annotation	Unknow
Peak:m/z	Relative Intensity
150.0550842	0.11
160.3793945	0.22
165.0118408	0.66
183.2083435	0.06
203.1010132	0.08
223.0234833	0.09
253.1203003	1.39
272.9365845	0.21
287.2295532	0.14
289.1546631	0.16
303.2434082	0.46
313.1439209	0.06
318.2114258	0.11
327.1312866	0.09
344.9942017	0.29
346.9146423	0.41
365.2597046	0.05
367.2399292	0.25
386.7383423	0.25
395.1903381	0.14
406.3266907	0.56
409.4594421	0.05
410.0738831	0.20
411.1116638	0.46
412.1411438	0.09
423.3104248	0.72
425.2795410	0.19
437.0172424	0.35
439.1770935	0.07
451.2785339	100.00
454.2384033	0.20
458.4617004	0.11
459.2315979	0.43
460.7366333	1.28
461.6728821	1.59
474.8788452	0.12
478.3338013	0.18
479.2474060	0.67
494.7876892	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	315.95
Annotation	Unknow
Peak:m/z	Relative Intensity
164.6307220	0.01
187.5425415	0.02
203.3272705	0.05
231.9300537	100.00
232.7598572	0.02
270.0724182	0.11
270.9759521	0.03
296.8839722	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
118.9752960	0.04
142.8161316	0.02
161.0476685	0.13
179.0164795	0.74
180.1130066	0.07
181.0933533	0.11
196.9932861	0.19
198.0087433	0.05
198.8973846	0.48
215.0539856	1.99
216.0726471	1.67
217.0131683	8.17
280.9616699	0.06
341.1539917	100.00
342.1447754	26.69
343.2415161	8.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	513.1952
Annotation	6-O-(3,4-dimethoxybenzoyl)-ajugol
Peak:m/z	Relative Intensity
144.9497375	0.24
177.0723572	7.43
188.9794006	0.14
193.8458862	0.22
195.0394897	0.76
212.9461060	0.18
215.3867188	0.12
218.9904633	0.07
230.9271545	0.83
232.5441284	0.11
241.2787628	0.35
259.1476440	0.15
265.3275146	0.17
275.0509338	0.08
283.0281372	0.20
300.8610840	0.48
302.9587402	0.63
313.0874634	0.10
319.3435669	0.05
325.2069092	0.05
333.1434326	0.20
340.9926147	0.23
345.2746582	0.04
347.3967285	0.08
355.6262207	0.07
388.8778076	0.92
406.9163818	1.03
408.9916382	0.07
409.6029053	0.08
414.4102173	0.16
425.1033325	100.00
425.7507324	0.13
466.9766846	0.06
495.0675659	2.55
495.8828125	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	423.2231
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9261780	0.48
129.0343170	0.35
131.2601013	0.29
143.0281372	0.98
148.7436066	0.82
158.9451447	1.77
160.9904785	13.56
190.6798096	0.05
193.1911926	0.14
203.1046143	0.29
208.1561890	0.10
215.1736450	0.12
227.1785583	0.10
233.0814514	1.40
261.2488708	0.22
262.0618591	0.14
280.1392822	0.21
281.3975220	0.19
283.5065918	0.09
289.0686951	0.32
291.1784363	100.00
293.0922241	1.73
296.9814453	0.15
319.3914795	0.18
330.9378052	0.25
335.0591431	0.37
339.0843811	1.64
349.0516663	0.50
351.1778564	0.14
357.0692444	0.20
359.4158020	0.19
362.6661072	0.19
363.2715149	0.28
365.1790466	0.06
377.0482178	0.55
377.6814270	0.04
378.8717957	0.33
380.3452759	0.59
386.1938477	0.33
387.2132874	0.92
388.2974548	0.05
403.1658936	0.12
405.1969910	1.57
408.3532715	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.7
Annotation	Unknow
Peak:m/z	Relative Intensity
196.7541199	0.03
206.9299774	0.04
208.0832062	0.06
212.9947510	0.01
214.0778656	0.05
277.7904663	0.03
280.8081665	3.27
286.8470154	0.05
290.7105713	2.57
291.3364258	0.01
359.0332031	0.04
362.0473633	0.03
362.7997437	0.03
364.5834351	5.04
365.3641968	0.09
371.8065186	0.01
372.9340820	0.22
373.6029663	0.03
374.6575928	1.31
379.0290527	0.05
380.9697266	0.03
382.0760498	0.03
383.0203857	0.21
385.0490723	0.18
399.3415527	0.28
400.9378662	0.03
401.9196777	0.06
402.7913208	0.09
422.6877441	0.03
427.0126953	0.05
440.2523804	0.01
446.9523926	0.48
448.5800781	100.00
449.2703247	0.31
452.7774658	0.02
454.1339722	0.01
456.1122437	0.15
456.8779297	0.32
458.7533569	1.70
472.8497925	0.03
486.0736694	0.31
486.7250977	0.50
496.1439819	0.20
497.0908203	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393
Annotation	Unknow
Peak:m/z	Relative Intensity
135.1816864	0.03
162.8472290	0.05
191.2990265	0.50
192.0584106	1.12
205.1390686	0.29
208.9413910	67.29
222.9673462	100.00
259.5737915	0.11
260.2557678	0.12
261.1980896	0.04
263.2818604	0.21
271.1285400	0.15
278.0605469	0.03
312.1744995	0.06
313.1722412	0.06
374.9557190	1.01
375.9374695	2.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	676.9
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8980560	0.50
214.6788025	0.23
231.9620819	0.41
315.8122559	0.11
333.1614380	0.18
354.0456543	0.47
391.1429443	0.14
402.0166626	0.15
405.7640381	0.46
424.3804321	0.45
425.0346069	2.25
443.8103638	0.12
445.7873535	0.82
447.0026855	0.42
463.3907471	0.51
465.2695312	0.57
499.5231323	0.09
502.2742920	0.23
508.9062500	11.65
521.3165283	1.25
522.3389893	0.45
546.9063721	11.59
584.7953491	16.73
585.4378052	0.13
590.5520630	0.44
592.2358398	3.18
592.8409424	34.82
594.6030884	0.06
599.2074585	0.29
618.4904175	0.26
630.7401123	100.00
631.3618774	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	230.99
Annotation	Unknow
Peak:m/z	Relative Intensity
85.1522064	1.61
101.9884644	1.53
111.1213837	0.88
122.0267792	1.97
123.5178528	2.43
125.1091309	1.97
129.9252319	1.63
143.0523987	3.32
147.2126923	0.69
158.3183136	2.24
168.4516602	5.95
172.0953522	1.49
185.2404327	2.20
187.9953156	1.30
194.9216309	1.31
199.4080963	16.66
203.0063171	0.33
213.0901031	7.74
214.1396332	6.14
221.9195099	100.00
222.6583862	29.73
242.4806519	5.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	384.1136
Annotation	Succinyladenosine
Peak:m/z	Relative Intensity
160.8905334	0.11
166.1380463	0.20
173.555191	0.11
190.9020233	0.23
205.7620544	0.32
220.8730164	0.30
222.1038361	0.64
234.5401001	0.34
252.0672302	100.00
253.2313538	0.39
256.1366882	0.12
278.078186	0.18
281.7815247	0.10
293.7495728	0.19
338.2762756	0.15
366.223999	0.74
367.3789368	0.38
376.193634	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	246.0967
Annotation	Liarin
Peak:m/z	Relative Intensity
80.0134888	0.06
87.9149628	0.16
95.0728455	0.11
100.1309509	0.06
107.1389160	0.06
110.7132111	0.09
124.5612640	0.09
134.0265808	3.81
136.9035645	0.07
140.1049194	0.14
141.1306763	0.09
155.9130402	0.44
158.9320374	0.07
174.1453857	0.11
184.0335693	0.06
199.9041901	9.96
200.7911224	0.38
202.2559052	0.24
204.9798279	0.48
211.0189209	0.20
215.0125885	0.31
218.5491180	0.25
223.0884705	0.30
228.0178070	100.00
229.0570526	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.88
Annotation	Unknow
Peak:m/z	Relative Intensity
106.2016449	0.54
111.2157135	0.14
134.1471252	0.45
157.1396179	0.17
171.8686523	0.21
181.0460358	0.12
187.1808472	0.19
218.8558044	4.74
225.1415405	0.42
230.9372864	1.04
236.7894287	2.29
243.1628723	0.49
257.4031677	0.23
259.9400635	0.14
262.8078308	100.00
274.6608582	0.95
280.7762756	19.85
283.3025513	7.76
285.1227112	0.20
286.2877197	0.22
291.7564392	1.38
303.8017273	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.14
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9210205	1.92
180.8546906	1.04
198.8932648	1.01
247.1584167	0.66
258.0934448	0.67
259.1809082	2.33
271.0260010	1.58
280.4446106	1.04
289.0094604	30.52
290.5671997	1.31
293.7160645	0.48
294.9730530	1.08
300.0958557	3.12
305.1915283	1.00
307.0762939	0.81
324.5670166	8.11
325.3862915	0.65
354.9184570	0.41
370.0164795	90.96
370.7396851	7.34
381.0022583	0.35
396.9869995	7.53
450.9656372	2.67
451.6046143	3.36
456.5869141	1.79
486.8538208	6.77
516.7366943	4.55
517.9053955	1.07
530.2780762	0.24
559.2843628	3.83
577.0184937	30.30
578.1084595	0.44
619.0446167	1.98
737.1516724	2.39
738.9911499	100.00
740.0335083	4.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	578.3094
Annotation	Unknow
Peak:m/z	Relative Intensity
219.8526611	0.05
220.7846527	0.02
238.3954773	0.05
243.1348572	0.06
293.2700195	0.42
294.1853638	0.12
307.4502563	0.08
342.3949585	0.07
351.5540161	0.24
364.9020996	0.13
381.6875610	0.05
391.4887695	0.12
398.4401245	0.04
400.4033813	0.07
405.6636353	0.12
429.6135254	0.22
447.3909912	0.57
449.1582031	0.11
450.6029053	0.08
473.4296265	0.07
474.3430786	0.19
476.3038940	0.15
493.1407471	0.14
496.3792114	0.21
497.7125854	0.10
505.2905884	0.23
507.2073364	0.10
518.3262939	100.00
519.3153076	39.36
520.2445068	0.54
521.3101807	0.06
524.7080078	0.03
532.9789429	0.83
535.3355103	0.09
537.4215088	0.06
541.0478516	0.36
543.1434937	0.61
546.3662109	0.04
561.5028687	0.10
562.3003540	0.12
563.4344482	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1083
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
147.0209503	0.01
148.5241852	0.02
149.1281738	0.05
151.0562897	0.02
152.0874023	0.03
153.0800476	0.00
154.0870514	0.00
157.1559906	0.01
159.3123474	0.01
160.9184875	0.02
163.0073547	0.08
164.1855316	0.01
165.2390594	0.02
170.0998688	0.01
173.2531433	0.01
175.1414337	0.01
176.9489746	0.03
178.9832153	0.27
180.0803833	0.07
181.1515503	0.02
182.3976746	0.01
190.9813843	0.07
199.0858459	0.08
201.2479706	0.15
202.3540802	0.02
203.1062927	0.01
204.0532532	0.01
205.2024231	0.03
208.2433929	0.01
211.0409698	0.01
215.1349487	0.06
216.1638336	0.02
217.3283997	0.01
219.2955780	0.01
220.0756378	0.00
221.6846619	0.01
222.9993591	0.03
225.3486938	0.04
226.2456970	0.03
227.2261047	0.00
229.0925903	0.01
233.2229309	0.01
237.3907623	0.01
241.3636780	0.02
243.2154236	0.85
244.3013611	0.27
247.2423706	0.01
251.3587341	0.01
259.1739197	23.48
260.1695557	3.28
265.0311279	0.02
267.2046509	0.02
269.1449280	25.00
270.1701050	3.84
270.9406433	0.00
273.4277954	0.01
281.4089050	0.00
283.2609863	0.19
284.2214966	0.03
287.1204224	100.00
288.0872498	9.45
289.0928650	0.02
293.1613464	0.14
294.0363159	0.02
295.2933960	0.01
297.3726807	0.01
301.4632874	0.00
302.5184326	0.00
309.2062073	0.01
311.1419373	0.98
312.0444641	0.08
315.2773132	0.00
321.2474976	0.01
323.1354980	0.01
324.1890869	0.03
325.1224670	0.04
329.0932617	0.08
330.3972778	0.01
331.0869141	0.01
341.2483826	0.10
342.1527100	0.55
342.9741211	0.02
347.1734314	0.00
353.1110229	0.03
354.1311951	0.00
359.0184326	0.01
362.0076599	0.01
376.3302612	0.01
377.2780457	0.00
387.0082703	0.02
387.7857361	0.00
389.2334900	0.02
390.2013855	0.03
403.2780457	0.05
405.2208862	0.02
406.1544800	0.02
413.1607666	0.01
414.0528259	0.01
421.1402893	1.03
422.1876221	0.23
431.1453552	4.12
432.2297058	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	394.22
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0084534	0.07
190.2009125	0.12
207.0790100	0.15
226.9790649	0.06
235.8915710	0.06
238.0583496	0.19
257.0280151	0.09
267.6852417	0.07
274.1738892	0.58
290.6768799	0.43
292.2607422	0.13
294.3125000	0.07
296.3144226	0.37
298.9022217	0.22
304.1340637	0.43
306.0881958	0.21
316.2445679	0.07
318.3011780	0.11
318.9970703	0.09
320.3872681	0.08
331.1689148	0.10
332.3151855	0.15
334.2747498	0.08
336.0162354	0.13
341.8284302	0.11
344.2731628	0.57
347.6723022	0.24
348.3951416	0.21
350.0010986	0.74
351.0030823	0.30
352.3756714	0.18
355.8155823	0.31
357.9823303	1.36
359.0646057	0.16
361.0243225	0.06
362.5596619	0.16
364.3016052	0.27
366.0908813	0.08
367.3149719	0.07
376.2474670	100.00
380.3836365	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.0757
Annotation	Unknow
Peak:m/z	Relative Intensity
67.5981064	0.07
88.0085602	1.81
88.8041153	0.13
97.1902389	0.06
107.2022324	0.11
111.1835556	0.18
115.9445190	0.43
121.1601410	0.15
122.0053406	1.31
135.0112610	0.14
139.4930878	0.08
140.3763123	0.34
141.2531128	0.23
151.0052948	100.00
151.8689880	0.14
154.1672058	0.23
155.0825500	0.26
163.1055450	0.41
168.9807129	9.37
177.0849915	1.11
179.3962708	0.24
190.0352020	0.16
191.3668213	0.09
195.1450195	0.19
199.4306335	0.15
206.6588135	0.71
207.3255615	0.23
210.2248230	0.56
213.2931824	0.29
222.2033386	0.91
223.2005310	1.80
224.1346741	0.46
225.2066650	0.33
226.2486877	0.43
231.1868286	0.12
237.9961853	0.59
239.1317139	2.39
240.2946777	0.30
241.3388672	0.16
243.1008911	0.64
247.2060547	1.65
252.9945068	0.30
254.3110962	0.21
255.2810669	0.30
256.1318359	0.27
260.0231628	0.22
261.1970520	1.79
265.9756775	15.11
267.1296997	4.45
268.2260132	0.09
272.1669617	0.36
275.1312866	8.84
275.8186646	2.03
291.1125183	6.70
291.8651733	0.85
312.1251831	0.36
313.2205200	0.80
314.1945190	0.08
314.8030701	0.07
379.2843933	0.47
409.4341736	0.24
412.1097107	0.18
413.0004272	0.26
451.7622986	0.54
549.3427734	1.03
550.9476318	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.2941
Annotation	LysoPE(0:0/20:3(8Z,11Z,14Z))
Peak:m/z	Relative Intensity
146.9882050	0.03
151.1553345	0.13
153.1456146	0.10
168.1249695	0.10
171.1952209	0.02
183.3673706	0.08
203.0166016	0.03
218.0068054	0.11
220.0561066	0.02
224.0831451	2.58
226.3942566	0.02
233.2200012	0.55
237.0850677	0.04
242.1253357	1.92
248.2561646	0.11
257.4029541	0.01
259.2636108	0.28
261.4336548	0.01
265.1673584	0.04
269.2649841	0.02
270.2378845	0.02
271.9592590	0.06
275.3026733	0.40
277.2308350	100.00
277.8417053	0.20
304.5570374	0.06
311.9436646	0.04
328.9725952	0.02
340.1963806	0.09
343.4480591	0.03
344.3767090	0.08
346.6003418	0.02
354.2772827	0.01
410.1955872	0.03
413.2964478	0.26
422.1990662	0.04
431.3996277	0.08
438.2127075	0.02
441.4057922	0.02
442.7925415	0.04
452.4398193	0.81
458.3672180	0.04
464.1063843	0.14
466.3012085	0.50
475.4772644	0.11
483.5116882	0.16
484.2797241	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0724
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9224625	55.71
155.0200195	0.46
171.0121613	0.10
172.9402618	100.00
179.1041870	0.18
206.1216736	0.09
255.0776978	0.29
309.2038574	0.06
334.4490662	0.29
335.1413879	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2207
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
99.03736877	0.45
109.0296478	0.25
110.2778625	1.19
124.8956833	0.45
127.0602112	1.33
130.9754028	0.45
138.9365234	0.21
141.1981659	0.36
142.210083	0.37
142.8861084	0.24
148.8904114	0.58
151.3329163	0.48
155.0854187	0.11
165.1484375	0.33
166.7323914	1.04
171.0816956	0.31
181.1500854	1.08
182.618927	1.44
183.2941742	0.40
191.006546	0.19
193.276001	0.26
195.1069641	1.36
197.1640625	0.53
198.0358582	0.37
204.9194641	0.42
211.1002808	0.54
213.2008057	0.38
219.3258972	0.25
225.2565918	1.13
229.1715088	0.19
233.2241211	1.64
237.0282898	2.36
239.0632935	1.02
241.1551208	0.53
241.8407898	0.83
243.1540222	0.50
249.0893555	0.63
250.9729919	0.42
251.5740662	0.49
253.1107178	5.45
255.2857666	0.59
265.2969666	0.47
267.3442078	0.86
268.1710205	0.60
269.3084717	1.85
270.0765991	0.41
273.2849121	0.72
275.2852783	10.13
278.3557739	0.24
279.2527466	1.02
280.4492188	0.59
282.9694214	2.93
291.4338379	0.27
293.2063293	100.00
293.8391724	0.16
296.1665649	0.57
302.2822266	3.30
310.6070557	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1662
Annotation	Butrin
Peak:m/z	Relative Intensity
168.8435059	0.15
172.0466614	0.04
172.8365173	0.03
179.1580048	0.12
179.9899902	0.10
181.0561218	0.16
181.9987946	0.09
183.0060272	0.12
185.0065308	0.07
192.0458984	0.01
195.0283813	0.08
196.1113739	0.25
196.9234009	0.17
199.1280975	0.03
201.0083618	0.34
205.0463257	0.02
205.8880615	0.03
207.4135590	0.02
223.0096741	0.04
224.0627441	0.12
225.1318665	1.17
226.1276855	0.08
228.2042999	0.05
243.2035675	0.21
244.0733948	0.03
245.9208984	0.03
259.1753540	1.81
260.2215576	0.41
267.0404053	0.04
269.0695801	100.00
270.0728455	13.15
270.8298950	0.09
282.1755981	0.05
287.0685425	1.36
288.3567200	0.14
311.2860107	0.06
312.1793213	0.11
323.1484375	0.05
346.3435059	0.04
369.5938721	0.06
393.2653809	0.03
394.8083496	0.02
405.9636841	0.03
409.6779175	0.05
415.3887939	0.05
431.1511230	0.07
433.3157349	0.06
443.0216675	0.04
444.4488525	0.09
449.3271484	0.10
450.2506714	0.16
461.5684814	0.02
467.4661255	0.13
469.2519531	1.17
470.4179077	0.16
471.4334717	0.20
475.1235962	0.04
477.0003662	0.03
483.2116699	0.02
489.3682251	0.89
490.3483887	0.04
492.3045044	0.08
500.4096069	0.06
510.9892578	0.02
516.3235474	0.15
528.3336792	0.08
533.1343384	0.22
549.3194580	0.37
551.3721313	0.47
552.2575073	0.10
558.0538330	0.03
559.3139038	0.23
568.0443726	0.03
577.1593628	0.17
578.1481323	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.1404
Annotation	t(6)a
Peak:m/z	Relative Intensity
161.8881378	1.15
267.0513	0.13
268.1210327	2.09
281.0894775	100.00
294.1113281	0.70
325.1455383	0.34
369.0027161	0.91
395.5172424	0.91
396.2606201	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.2285
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9019470	0.10
179.9228363	0.09
185.0934143	0.05
219.0406799	0.02
271.2298584	0.04
291.2160950	0.06
307.1611023	0.13
318.2825317	0.07
336.9384155	0.03
339.0952759	0.14
343.5127258	0.21
347.3394165	0.04
354.1462708	0.12
361.2035522	0.11
362.7907410	0.11
375.2022095	0.03
379.0422668	0.05
380.3815002	0.09
382.0943298	0.07
383.1386414	0.03
385.1416626	0.04
388.1094666	0.06
397.3200378	0.04
400.0177612	0.07
406.2430115	0.08
407.1802673	0.04
409.3502197	0.12
411.2633362	0.05
413.4826965	0.13
423.2970581	100.00
425.4231873	0.13
430.1284790	0.09
431.0948181	0.31
433.1827087	0.80
434.2504578	0.49
435.2471924	0.07
446.9886780	0.41
450.1136475	0.02
451.2743225	0.46
460.9427185	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.2365
Annotation	Unknow
Peak:m/z	Relative Intensity
145.1866302	0.08
147.1450348	0.11
150.1619110	0.07
153.1395264	0.58
158.8856506	0.22
160.9963074	0.34
163.0917816	4.17
164.2725220	0.24
165.2006683	0.96
167.1327362	0.18
171.2662506	0.04
172.9302368	0.71
175.4738159	0.11
177.0092468	0.35
178.9516602	0.29
181.2051849	0.93
183.4133301	0.18
185.0559082	1.06
187.1460876	0.11
188.9800720	0.21
191.0653076	24.57
196.0901947	0.61
197.1425171	0.05
201.1469116	0.30
203.2185211	0.45
205.2408905	0.14
207.0874786	0.45
209.0569458	56.32
211.1212921	0.10
214.0148315	6.88
215.3927917	0.12
217.3246765	1.03
218.2158356	0.21
219.2318726	0.09
219.9429474	0.11
221.2798767	0.11
223.3264160	0.17
225.1497192	0.96
225.9625397	0.27
227.3348694	1.55
228.2302704	0.05
229.3142548	0.41
233.3133392	0.33
234.9193420	0.48
237.3877716	0.29
238.2847595	0.05
243.1976624	1.42
245.2585907	43.82
247.1887512	0.79
249.2455292	0.33
252.3525391	0.12
259.1977539	0.27
261.2661743	0.94
263.1545715	1.50
265.2144165	0.73
271.2559509	5.55
273.1954346	1.25
276.0835571	0.33
279.2846985	0.60
284.3257446	0.20
284.9540710	0.13
287.2597961	1.44
289.2538757	100.00
307.2621765	54.44
314.1024475	0.47
331.0606689	0.09
341.3120728	0.06
342.2035522	0.23
359.2149048	0.36
363.3067932	0.15
364.0449829	0.19
389.6991882	0.05
392.0674744	0.24
396.2929382	0.05
401.0344849	0.10
406.2474670	1.62
423.4424133	0.07
430.0437927	0.06
432.1970215	0.27
435.8562622	0.24
441.6755066	0.21
443.1557312	1.13
443.9556580	0.07
449.7272644	0.14
457.9292297	0.25
459.3406677	0.23
460.2755737	0.22
461.3029480	0.25
466.2004089	0.93
468.2563171	9.77
469.0448914	0.18
485.1727905	0.66
486.1966248	1.00
487.3687134	0.25
488.3419800	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2682
Annotation	Unknow
Peak:m/z	Relative Intensity
164.9465485	3.15
177.1100159	0.35
177.9272766	0.15
178.9380798	0.80
182.9828796	4.78
188.9904327	1.30
189.7839355	0.42
207.0197754	5.70
208.0602722	1.11
208.9704285	0.23
212.9430389	0.59
224.9773560	100.00
225.9695435	13.85
227.2207642	2.57
240.8412476	0.10
243.1145782	16.97
244.0593872	0.71
261.8142090	0.29
268.1336060	0.78
275.2223511	3.07
277.2990417	21.43
278.2349243	2.16
279.2261353	0.58
285.6347656	0.19
299.1464844	42.47
300.1123047	3.83
301.0087280	0.59
305.1994629	0.13
317.1549683	7.12
318.0213623	0.38
320.9456787	0.28
338.9450684	0.29
346.3842773	0.82
386.3885498	0.21
436.3446045	0.15
469.2571411	0.79
470.2763062	1.50
482.0817871	0.34
494.1223755	0.41
509.4178467	0.51
519.4113770	0.37
521.4166870	0.80
522.5023804	1.58
532.3848877	2.06
533.7913208	1.23
534.5034790	6.59
536.0054932	0.21
541.5065918	0.25
542.3850098	0.97
548.5418091	0.38
550.1702271	0.19
560.9431763	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.14
Annotation	Acremoauxin A
Peak:m/z	Relative Intensity
98.1865845	0.07
121.1025848	0.09
142.9496765	0.07
144.1528015	0.22
149.3304138	0.11
155.2286987	0.06
155.9001160	0.05
160.2212524	0.05
162.0280151	1.45
166.8878326	0.04
180.3037567	0.16
183.9714355	0.44
193.0258331	0.14
194.3864441	0.06
204.0596619	4.64
212.0951538	2.55
223.9452515	0.03
228.0191956	0.04
234.9306946	0.07
236.2365112	0.11
239.1729431	0.26
240.1990662	0.07
241.2276001	0.05
258.0647278	0.06
259.7118835	0.08
263.2022095	0.05
264.3294678	0.11
265.1358032	0.31
268.1617126	100.00
270.1948853	0.24
279.1474609	0.25
280.0533447	0.08
283.1719666	0.17
288.1651611	0.53
289.2895508	0.22
292.8885193	0.07
296.4864807	0.26
306.1383362	10.62
307.1315308	0.70
308.3289795	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.157486	1.76
121.2180939	1.49
123.1379089	1.16
125.0482178	1.04
131.0955811	0.35
134.9764404	1.45
137.1608276	0.93
141.0019379	0.54
147.1047363	3.16
154.8357391	0.19
156.8642883	0.13
158.7646637	0.35
160.9524078	1.62
168.9992981	0.82
173.2636108	0.23
175.1888885	1.44
176.9823303	0.47
184.8096924	0.21
189.208313	1.29
191.1516876	0.37
192.8202515	0.68
194.9835205	0.37
197.2627258	1.41
202.9195557	3.23
205.0058289	0.89
209.3184814	0.43
210.851532	1.59
213.0440674	1.70
216.8157043	0.85
219.2513428	0.45
223.1906738	1.57
223.9870911	0.70
225.0442505	0.31
227.0987244	0.67
228.8747559	2.74
231.0550537	0.36
235.2426758	3.27
237.2397461	0.40
238.8377991	0.36
241.2149048	0.89
242.3235168	2.79
243.3111572	1.96
245.4244995	0.80
247.2072144	6.52
249.2723389	0.21
251.2313232	0.36
258.4010925	0.74
259.2225952	0.52
267.2288818	1.98
268.1962891	0.46
268.8066406	0.24
269.4203796	1.16
270.2958069	0.25
271.4700317	0.63
279.1662903	1.27
281.1848755	2.80
282.0799561	0.57
283.2207031	5.72
284.836731	1.23
285.4502563	1.54
287.3059692	2.46
288.0653381	0.17
295.2579956	1.30
296.2351379	1.47
297.1802979	0.36
299.1003723	1.99
304.3345947	0.58
305.1547546	3.96
307.1878357	0.67
309.4053955	0.30
313.2058105	2.57
323.2400513	100.00
324.1920166	1.08
332.2296143	4.45
341.0746155	2.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.91
Annotation	Unknow
Peak:m/z	Relative Intensity
193.8005524	0.11
232.0588074	3.24
252.7584229	0.06
315.8438721	100.00
316.5063477	0.22
353.9647827	19.17
382.1777039	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1035
Annotation	LMPK12140454
Peak:m/z	Relative Intensity
176.9427795	2.70
193.1746826	0.03
203.1333618	0.05
206.5065002	0.06
215.2266846	0.21
217.0132751	0.26
240.2105865	0.04
241.1925964	0.08
257.3741455	0.15
258.974823	0.19
266.3048401	0.03
268.6187744	0.27
272.1238403	0.10
279.0624084	0.10
283.1096191	0.15
285.0883789	24.11
295.0939026	0.10
303.0419922	100.00
303.6744995	0.29
310.975769	0.13
312.177887	0.03
327.2904968	0.30
328.1834717	0.14
329.145874	0.09
332.345459	0.05
334.2746887	1.41
338.9289551	0.03
340.1574097	0.10
341.0606689	0.87
343.2698975	0.04
346.1379395	0.24
362.3022461	0.21
366.1381836	0.07
376.6593018	0.12
377.2741699	0.04
378.2782898	1.90
380.6226196	0.11
381.3586731	0.03
390.4931641	0.04
394.1933899	0.14
403.4627686	0.30
419.2723694	0.14
420.3746338	0.31
421.2427063	0.39
428.9483032	0.09
430.0996094	0.03
431.1595154	0.03
437.2416077	0.50
447.1343384	2.74
448.2074585	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.07
Annotation	Unknow
Peak:m/z	Relative Intensity
187.9927521	0.03
259.0356140	0.04
270.3207092	0.02
271.0717163	0.13
295.2175293	0.04
315.0004272	0.21
355.1320190	0.51
366.9345093	0.02
368.9423218	0.10
376.8388062	0.05
384.9049683	0.05
394.9998779	0.23
404.9129639	0.08
415.1854248	0.09
428.0543823	0.32
429.1036987	0.66
440.7497559	0.08
442.7965698	0.58
453.2520752	0.03
454.9941406	0.13
456.9720459	0.06
463.1763916	0.06
464.2525024	0.05
465.1953735	0.13
466.8359985	2.57
476.8147583	0.09
478.8255615	0.03
479.6904297	0.03
493.2938232	0.02
503.3342896	1.67
516.8295288	0.02
522.8981934	0.20
529.1531372	0.08
537.0886841	0.04
539.1791382	100.00
553.2139282	0.07
566.8945312	0.21
574.9739380	0.23
577.1007080	10.01
577.7784424	0.10
595.0119019	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
84.91036987	0.30
90.82422638	0.27
94.96739197	1.02
105.0676727	0.53
111.0261688	0.43
112.9125519	0.11
114.7084122	0.18
116.8214417	0.10
120.593399	0.12
122.9739304	1.50
125.3043213	0.30
126.0659714	0.20
128.9662781	0.15
133.0016174	0.42
134.921051	0.30
137.0497742	0.52
138.8965454	2.07
141.1109009	0.28
146.8838196	0.22
149.2535706	0.11
151.2119141	0.70
153.0013123	1.87
154.7939758	0.26
157.224823	0.27
159.1048889	0.19
161.1227112	0.53
162.9297791	0.32
165.2947388	0.43
166.868103	0.31
169.0382843	0.61
171.3121643	0.61
177.0014496	0.26
183.0602417	2.48
185.171463	2.09
187.1793823	0.46
191.0346985	0.30
192.996582	2.05
195.2718201	1.10
197.033844	7.85
199.0162354	1.78
203.2599182	0.18
206.9556274	0.74
209.1812744	1.18
211.1747131	4.14
213.2203674	1.63
217.5410767	0.20
219.1318054	1.11
221.2375488	3.34
223.3114014	1.67
224.1830139	0.90
225.0543823	2.41
227.26474	1.15
233.1871643	2.09
237.1789856	6.47
239.1696777	13.23
243.2721252	0.88
248.1181641	0.19
251.2735596	3.95
253.0290833	0.54
254.3597412	0.28
255.3361206	0.70
255.9756165	0.20
257.1297607	0.71
261.1534119	3.25
267.1746826	0.08
269.0579224	0.50
279.2223816	100.00
280.8320923	0.45
287.9931641	1.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1696
Annotation	Glu Pro His
Peak:m/z	Relative Intensity
115.8884125	0.10
150.4441223	0.50
159.8633423	0.47
176.9518738	3.41
178.1317444	1.04
219.9585266	1.43
251.9966125	0.19
291.7192078	0.33
300.7393799	0.15
323.0135193	0.18
328.1967773	7.62
336.290802	0.34
338.2694092	0.63
340.9807434	0.78
346.046875	9.05
358.5900879	0.22
364.1607361	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.12
Annotation	Methylinoscavin B
Peak:m/z	Relative Intensity
131.0917816	0.08
152.0687408	0.16
154.2013550	0.16
161.0469360	0.14
177.0850372	0.11
178.9154358	1.19
184.2855835	0.07
198.5375061	0.14
214.9646149	0.67
216.0744781	0.07
217.1038208	1.74
243.3369751	0.24
248.8526917	0.12
251.1525574	0.38
253.0528564	0.19
259.2242126	2.31
269.1317444	3.74
272.8904419	0.16
283.2220154	0.06
284.9752808	0.09
287.1301270	5.27
301.9598389	0.12
303.0458069	0.14
311.1160278	0.48
323.2155762	5.78
324.0859375	1.45
325.1505737	0.23
341.2184448	8.98
342.2495728	1.38
343.1481934	0.96
345.3054810	0.23
352.7815857	0.21
361.1901855	0.48
372.3724365	0.08
393.0378723	0.07
403.0712585	0.85
404.7987976	0.18
405.4371033	0.26
411.1530457	100.00
412.1752930	49.92
413.1567993	9.91
413.7582703	0.07
415.2122803	0.30
417.3966675	0.08
426.6677551	0.15
429.2243958	0.19
431.3507080	0.73
439.4559631	0.29
440.2676086	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	608.2831
Annotation	Unknow
Peak:m/z	Relative Intensity
197.0684967	0.34
263.1899414	0.53
322.3521729	0.82
348.0907593	100.00
360.6848145	0.42
366.8158569	0.36
376.2763672	0.87
415.2593994	0.52
461.2677612	0.22
503.0263062	0.64
541.1442261	0.60
557.9890747	0.20
558.9621582	1.35
573.1517944	0.65
589.2354126	0.17
591.0358276	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9594727	0.08
157.0593262	0.08
158.9520569	5.37
159.9679565	0.46
160.9527588	0.97
198.9834595	0.59
199.9198303	0.20
201.7164612	0.05
217.2174988	0.02
228.9186096	0.99
230.1851501	0.44
231.0536194	0.29
272.9664917	49.60
274.0102539	30.57
275.0422974	27.93
386.9864197	56.16
388.0124817	82.44
388.9414368	100.00
459.0830383	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.3013
Annotation	L-Oleandrosyl-oleandolide
Peak:m/z	Relative Intensity
161.0648193	0.18
174.9359894	2.07
186.9980164	0.29
188.9352112	0.34
193.1184998	0.58
205.0167847	1.94
216.8864136	0.12
223.0749664	1.01
225.3624268	0.09
231.0817871	3.38
241.8073425	0.13
249.0934448	22.37
261.2842712	0.19
267.1780396	24.40
277.3313599	0.57
279.2687073	100.00
286.2853394	0.08
337.3928833	0.09
357.2674561	0.15
367.3690186	0.51
409.3920288	0.39
453.6997681	0.15
469.3220825	2.10
475.7404175	0.12
479.2015381	1.05
485.4860840	0.33
486.1569824	0.17
491.5553589	0.11
493.6098633	0.46
494.6008911	0.42
511.3300171	19.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	801.2072
Annotation	Brassicoside
Peak:m/z	Relative Intensity
314.9518738	0.28
330.7454834	0.70
331.3463745	0.44
423.4458618	0.13
448.5208740	0.06
450.3867798	0.08
477.1947632	0.18
492.3361816	0.05
493.3312988	0.09
495.9036865	0.20
504.3565674	0.11
562.0717773	0.12
602.2728882	0.10
624.0051270	0.40
639.3270264	100.00
641.6141968	0.30
655.3189697	0.05
671.2009888	0.20
681.5255737	0.26
703.0964966	0.30
724.7951660	0.13
747.2008057	0.12
756.5263062	0.16
778.8883667	0.15
780.2683105	0.15
782.6106567	0.82
783.3869629	0.30
784.2817993	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	917.2565
Annotation	Luteolin 7-neohesperidoside-4'-sophoroside
Peak:m/z	Relative Intensity
272.9509583	0.23
299.1113281	0.05
300.0185547	0.10
301.1441956	0.30
333.2521973	0.10
355.3570557	0.11
373.1710815	0.07
462.2077026	0.46
463.2208252	0.19
479.4137573	0.03
489.2766724	0.30
498.8710327	0.06
555.2213135	0.06
564.8143311	0.04
591.1746216	0.30
608.2234497	0.07
609.3020630	0.37
635.2310791	0.07
637.3591919	0.04
685.2273560	0.04
691.1741333	0.06
737.4646606	0.19
753.2947388	0.15
755.2059937	100.00
755.8507080	0.72
771.5819702	0.02
779.3217163	0.05
783.3538208	0.03
797.2792358	0.46
827.6244507	0.12
857.3422852	0.05
908.5443726	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	993.5978
Annotation	Unknow
Peak:m/z	Relative Intensity
279.3158264	12.87
476.2707825	100.00
477.2310791	0.59
494.4739685	0.03
502.2457275	0.26
796.6888428	0.01
866.4221191	0.02
934.8453369	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1915
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1855927	0.16
176.1051941	0.12
177.0729370	0.37
179.2059784	0.11
181.1544800	0.19
182.9649963	0.32
190.1374207	0.66
191.1203766	0.13
192.1954956	0.67
193.1097565	0.73
195.6760101	0.07
203.0100098	0.50
203.9652100	0.21
205.0868988	2.71
207.1096497	8.24
209.1249695	5.39
221.0010223	0.26
223.2456055	0.29
235.0792236	0.15
245.0072021	0.53
247.2488403	0.16
249.1660767	1.19
271.1784058	0.06
277.1277466	0.13
279.1138306	0.44
283.3667297	0.18
285.3271790	0.09
287.0306396	0.22
289.1898193	0.58
297.9144897	0.74
299.0357056	0.05
307.1662598	0.10
308.8676758	0.33
314.9940491	2.47
320.9816284	0.11
323.0310669	0.10
326.2289429	0.16
327.1171265	0.31
334.4346313	0.24
339.2936401	0.42
345.1630249	0.29
353.2425537	0.12
356.3244629	0.37
357.3419189	0.05
358.2312012	0.23
365.3748169	1.18
366.2117920	0.38
367.3791504	0.30
368.2103882	0.09
369.0841675	0.51
371.1878052	0.10
384.2421875	1.41
396.9697876	0.05
399.1588745	100.00
401.1817017	0.11
416.4473877	0.33
417.3502808	0.41
424.0679932	0.10
425.3704224	0.36
428.9760742	0.22
430.3721924	0.07
436.6717529	0.06
443.1558838	1.74
449.2343140	0.12
459.2843018	0.20
461.1339722	0.76
468.9672852	0.18
470.3201294	0.09
478.8685913	0.56
485.3016968	0.15
488.8002930	0.06
492.2529907	0.29
501.2849731	0.44
503.3165283	1.66
504.3679810	0.53
507.0596313	0.94
515.3287964	0.08
517.3039551	0.09
533.4274902	0.28
535.3200684	0.35
536.3291016	0.30
547.2761230	0.14
552.1281128	1.02
562.2073364	0.08
577.1099243	1.98
579.2067871	16.59
580.2606812	0.16
583.3181763	0.19
585.3704224	0.08
590.4568481	0.19
591.2474365	0.44
595.0658569	0.09
605.2907104	0.23
606.7725830	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2873
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
120.9861221	3.36
135.1454926	2.63
147.0338593	3.41
158.9985962	1.24
172.9371338	3.55
180.7620697	1.06
183.164444	1.24
197.0552673	0.86
203.1031494	0.96
205.1078796	1.35
208.053833	2.66
229.2663727	5.50
232.6781464	2.67
245.3634644	8.91
259.455719	3.32
281.1394043	3.52
281.8294373	1.34
286.0971069	1.72
287.030426	1.15
332.3867798	3.89
334.0867004	2.94
335.3406372	6.43
337.4187927	7.10
357.2896729	7.10
367.3852539	2.09
374.6512146	1.07
377.2848511	2.67
380.077301	8.17
380.6957703	8.47
381.4196777	3.47
384.955658	4.46
388.5149536	0.86
389.9182434	7.85
391.0187683	9.43
393.6114197	2.76
394.550415	4.64
397.5440979	1.99
400.1488953	3.48
407.4309387	5.41
408.2852478	100.00
409.0140686	0.91
411.046814	3.04
414.918396	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	524.2257
Annotation	Scoparasin A
Peak:m/z	Relative Intensity
180.0636902	0.23
199.1366119	0.16
201.0862579	0.16
213.9721069	0.14
233.1872559	0.21
239.1629333	1.32
276.0141602	0.06
291.2892761	0.13
310.4375610	0.81
312.9889526	0.06
327.1909180	1.95
328.1021729	1.23
335.1382446	0.12
344.0314941	1.00
362.2848511	9.63
395.4979248	0.11
418.2404785	0.39
436.6223755	0.71
439.7478638	0.33
450.0946655	0.13
464.2167969	100.00
464.9144897	1.22
465.6597290	0.35
475.6134644	0.24
478.3519897	1.67
484.2811890	0.88
485.5964966	0.46
488.2135010	0.75
503.6127319	0.07
506.5247803	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	444.1143
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9700623	0.02
133.9325867	0.03
135.1561279	0.25
136.1676483	0.04
148.0807037	0.09
151.0383301	3.45
151.9344635	10.01
153.0261993	0.78
158.2774811	0.02
160.2624054	0.10
161.1162720	0.23
162.2118530	0.02
164.7866211	0.02
166.0692596	9.18
166.9962616	100.00
167.9540405	11.02
168.5648193	0.05
174.2203979	0.04
176.2007446	0.02
177.1572571	0.32
188.0793762	0.08
190.0113220	0.30
190.8114624	0.12
195.0576782	0.23
204.2077026	0.19
205.1670990	0.24
206.2219391	0.02
208.0063782	0.02
209.1550140	0.54
213.2570190	0.17
218.1372375	0.27
219.0312805	0.15
220.0691071	17.00
221.1510773	2.44
230.1759949	0.03
232.1407166	0.08
233.2441711	0.29
234.1574097	1.10
235.2646790	0.10
238.0594482	20.28
239.1487732	4.08
242.1748962	0.10
245.3297119	0.03
260.1321716	0.09
262.0687256	5.30
263.0131226	1.04
264.1358337	1.08
265.1347046	0.14
267.1795349	0.05
272.4419250	0.04
273.0433655	0.03
273.9205933	0.07
277.7784729	0.08
279.0318298	0.03
280.1274414	0.36
282.1094360	17.69
283.1605835	2.52
287.1369629	0.10
292.1091003	0.31
293.2035217	0.12
304.1978149	0.08
305.1441040	0.08
306.0046387	0.03
311.2901306	0.03
322.3796997	0.02
324.1625366	0.07
328.1867676	0.74
329.1098633	43.09
330.1102295	7.06
341.2965393	0.11
352.9839783	0.09
354.2302246	0.06
355.1344604	0.06
357.1921387	0.11
361.1149292	0.18
371.6090393	0.03
373.3096313	0.03
381.4491577	0.11
382.1362000	0.37
383.1022034	0.11
387.3872375	0.04
397.3975220	0.13
399.1153564	0.72
400.2759705	0.66
401.2606812	0.03
426.1127625	3.01
427.1998596	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
98.92323303	0.77
120.9057541	2.17
127.0506516	0.92
128.9450226	3.54
137.2693481	1.05
140.9055939	7.82
142.9399414	0.90
154.8516388	0.90
158.9399414	2.97
164.9391785	2.27
166.9332275	3.41
169.060318	7.87
181.151062	3.12
194.9195251	1.69
197.4741669	2.51
203.9819946	3.07
211.2689819	0.77
213.1418152	2.17
225.1843872	1.43
227.0649719	0.95
229.1752319	4.04
232.9829102	11.63
234.9090881	0.94
239.324646	3.48
247.2467957	2.61
250.9298706	2.79
257.2587585	3.21
264.9855652	5.90
269.3492126	3.65
275.0923462	5.91
283.1066589	5.06
286.8127136	3.07
288.5762634	4.81
293.2083435	100.00
305.4833679	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2499
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.85359192	0.04
102.9289627	0.08
106.7736816	0.62
108.9196625	0.35
116.8730316	0.31
121.0068283	2.27
124.8733063	0.19
130.3889465	0.17
133.1774139	0.24
135.0798492	2.54
143.0328522	0.80
144.9361877	0.16
146.97612	1.00
149.0355225	1.92
151.2438965	0.32
152.5682373	0.20
155.1142273	0.15
156.8797607	0.65
158.0953674	0.22
159.0905762	0.15
160.9356232	2.77
163.1712341	0.79
167.2830353	0.24
168.8074341	0.10
171.0509949	0.09
173.0676422	1.15
174.9514618	1.22
177.214325	0.64
183.0574951	0.64
187.2184448	1.30
188.9810486	1.59
191.1182556	0.20
193.0326385	0.22
197.2125702	0.39
198.9790802	0.46
200.3832092	0.21
205.2248077	0.50
206.9934692	0.06
211.1420593	1.04
213.1615906	0.34
217.1111145	2.35
223.0679932	2.08
225.1072693	0.56
227.285675	0.93
231.4516907	0.68
232.2936401	0.04
235.058197	0.06
239.065979	0.04
243.3998718	0.13
244.8539124	1.38
247.3135071	5.33
249.3170776	0.20
253.0121765	0.14
255.7373657	0.22
257.1529541	0.59
259.244751	0.11
262.7333069	0.94
267.1057739	0.06
271.0355225	0.07
273.1501465	0.18
277.4691162	0.09
279.0964355	0.30
281.194519	0.14
285.2867126	0.29
287.3894653	1.29
291.2608643	0.32
292.1394043	0.66
292.9431763	0.27
295.3542786	2.08
297.1217651	0.09
299.2644958	0.84
305.3208923	3.85
310.3015442	0.41
311.3359375	0.46
313.0220337	0.07
323.2445984	100.00
327.8027344	0.18
341.341156	2.34
354.212738	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.1534
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1039734	0.04
186.1440430	0.06
190.0251160	0.05
210.0648651	0.02
244.3852539	0.02
256.2401428	0.29
273.4470825	0.05
274.2437439	0.04
278.2526855	0.05
285.1122437	0.08
295.9901733	0.31
305.2607422	0.03
306.0305481	0.01
312.3087158	0.09
313.1930542	0.66
327.9850769	0.05
330.1630249	100.00
330.7670288	0.20
362.6554871	0.06
366.1358643	0.10
368.4188538	0.11
384.1912537	0.16
404.0940247	0.02
441.3091736	16.96
442.2014465	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	628.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7102051	0.14
208.9926453	0.11
290.7659912	1.00
292.8554077	1.43
369.1966553	0.25
372.5859375	0.04
375.0571289	0.01
376.6818237	3.69
377.3567505	0.05
378.7485962	0.02
384.9909058	0.07
393.0491333	0.03
415.0089111	0.20
418.7069092	0.08
420.5941772	0.07
444.0274048	0.12
452.9204102	0.22
458.6043091	2.31
460.0908813	5.11
460.7554932	18.46
462.2624512	0.10
463.0428467	0.08
466.7438965	0.04
468.9805298	0.15
470.7452393	0.14
475.6416626	0.06
491.0553589	0.11
498.6629639	2.18
500.9739380	0.10
503.9712524	0.11
520.7255859	0.19
538.0797119	0.12
542.5023804	10.08
544.5666504	100.00
545.3372803	0.07
552.9075317	0.07
554.6644287	0.05
555.8875732	0.11
563.4437866	0.03
581.0117188	0.19
582.0121460	1.19
582.7067871	15.16
586.1111450	0.11
592.1178589	0.08
592.8886719	0.10
599.1409302	0.03
605.2888794	0.42
606.4164429	0.04
608.8743286	0.06
610.8461914	0.10
635.7992554	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1784
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0103455	0.06
127.1290588	0.04
139.9964294	0.43
145.0507355	13.09
146.2455292	0.21
150.2026520	0.08
154.0471649	0.06
157.9934692	0.08
158.8847961	0.44
167.0536194	0.04
185.1472931	0.06
194.3172913	0.05
196.1720734	0.11
211.4221649	0.03
213.0835266	2.28
213.7636108	0.09
223.0315857	1.42
224.0709839	0.05
227.1686096	0.17
231.0523071	0.57
240.0351562	4.50
240.9473572	0.17
245.0456543	0.31
258.0855713	0.28
262.0605164	0.31
263.1997681	0.34
267.2893372	0.73
275.4345093	0.04
277.0303345	0.24
279.1632690	2.05
280.2793579	1.11
281.3995361	0.05
285.1380920	0.03
294.1952820	1.59
296.1750488	10.77
297.2785034	1.18
298.4109497	0.33
313.2080078	100.00
314.2614136	3.59
315.3507385	0.04
329.1762390	0.09
331.1643066	22.55
332.0443115	0.92
341.2338562	0.05
359.3859558	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.99
Annotation	Unknow
Peak:m/z	Relative Intensity
92.8700104	0.08
96.8190384	29.90
108.0377502	0.12
136.0761719	0.22
137.0319214	0.49
153.9373627	100.00
208.1115417	0.07
230.1442871	0.19
247.1411743	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.23
Annotation	Salviamalvin
Peak:m/z	Relative Intensity
273.1172791	0.13
300.8461914	0.73
363.0016785	1.56
381.4011841	2.13
507.2607422	0.18
525.2316284	15.82
543.2802124	24.17
669.3021851	0.22
687.2681274	28.01
705.3750610	100.00
706.2180786	0.21
807.4783325	0.65
849.4684448	0.42
858.6403198	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.1346
Annotation	N2-(2-Carboxymethyl-2-hydroxysuccinoyl)arginine
Peak:m/z	Relative Intensity
111.9359818	0.24
113.0474243	0.15
114.0134583	0.05
115.9778442	1.22
130.0153503	0.97
139.7422943	0.23
156.9475708	2.23
158.1361694	2.99
175.0277252	100.00
176.0557709	0.04
214.1719666	0.10
214.9998474	0.05
270.9762268	0.13
277.7668457	0.10
289.2184448	0.32
295.7823486	0.10
297.2252502	0.09
303.8249512	0.24
314.2230835	0.37
319.1478577	0.10
331.2314758	1.00
331.9567871	0.47
333.0409546	0.19
333.8469849	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.2372
Annotation	Unknow
Peak:m/z	Relative Intensity
132.8929901	0.19
179.0323639	0.18
251.7620544	0.17
269.7747192	0.15
294.1666870	0.18
302.1848755	0.06
307.0559692	0.21
329.6680298	0.29
334.2621155	63.46
334.8759155	0.86
347.8887329	0.09
361.1547546	0.55
368.0989380	0.14
378.3666992	100.00
379.4376221	0.57
387.6556702	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1815
Annotation	Unknow
Peak:m/z	Relative Intensity
129.0843964	0.06
149.0419312	0.05
155.0235443	0.03
156.9459991	0.24
161.0804749	0.03
175.0642090	1.29
176.1459808	0.03
179.0828247	0.09
188.1612549	0.11
193.0513611	4.40
193.8758545	0.33
204.9934998	0.24
213.0540771	0.19
220.8814697	0.04
222.9458008	0.09
231.1286011	1.39
232.2078705	0.10
232.9935303	0.23
234.2101440	0.03
241.2080078	0.08
244.9498596	0.08
247.0533752	0.12
249.1774597	15.99
250.2388916	1.87
259.8899841	0.09
265.2377014	0.40
267.2107239	0.19
268.2643433	0.12
283.9544373	0.07
289.2428589	1.28
291.0823975	2.62
292.3219910	0.57
305.0528564	0.14
308.0805664	0.05
309.1949768	6.34
310.3253784	1.14
315.4741821	0.29
328.4404297	0.10
331.0975647	0.30
332.0830688	0.10
333.2593689	17.92
334.2752075	2.96
349.2522278	4.57
351.2017212	48.33
352.2672729	7.95
356.6540222	0.05
360.0694580	0.09
367.2909851	22.03
368.1804199	4.79
372.5447998	0.05
375.1612244	2.36
376.3679504	0.92
384.1348572	0.13
391.0541077	0.46
393.2138977	100.00
394.3182373	20.03
395.3174744	0.05
406.0972595	0.49
408.2828674	0.17
414.3448792	0.16
415.3093262	0.58
416.2282715	0.60
433.2293701	69.88
434.2778625	18.86
435.2751160	0.05
436.1617126	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2994
Annotation	4-Hydroxysphinganine
Peak:m/z	Relative Intensity
88.79156494	0.02
92.83877563	0.02
96.82527161	0.04
109.1134338	0.11
111.1715393	0.04
121.1462097	0.16
122.8339081	0.09
134.9560547	0.28
137.0177765	0.05
139.2286682	0.13
149.1997681	0.17
172.2285919	0.04
177.1470032	0.04
179.1607971	0.04
193.049057	0.02
197.0096588	0.12
210.8926697	0.43
235.1134949	0.18
238.9549255	0.16
241.4708252	0.03
247.2044067	0.16
252.3250122	0.62
253.1047058	0.67
254.4687195	0.09
256.3869019	0.13
264.5765991	1.09
265.3380737	2.23
270.296814	0.74
282.3197632	37.42
283.1046448	0.29
300.2813721	100.00
300.9276733	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	481.0986
Annotation	Myrciaphenone B
Peak:m/z	Relative Intensity
151.0392761	0.21
178.9387970	0.54
180.8859863	0.04
181.7000580	0.06
191.1054382	0.55
193.0781555	7.23
200.1325989	0.07
210.0506592	0.07
215.1250153	0.13
221.1703186	0.32
226.5272827	0.06
237.0503540	0.06
239.2222900	0.10
240.8094635	0.40
255.1437683	0.23
257.2091980	0.13
259.2457886	0.10
275.0743713	0.16
283.1291809	11.52
301.0437622	3.40
315.0708618	0.07
318.4949646	0.34
319.1786804	1.25
319.9155273	0.09
328.8347168	0.06
335.0476685	0.13
337.2232666	0.64
340.6696167	0.06
345.2298584	0.15
349.2397461	0.44
353.3210449	0.32
355.2009888	22.68
356.0066833	0.04
377.3251648	0.10
379.2951050	0.32
384.8052368	0.26
390.9626770	0.05
391.9985657	0.11
395.5079956	0.34
397.3116760	0.13
399.0850525	0.07
405.3594666	0.14
407.0560608	0.18
409.2964478	0.12
416.3306580	0.11
419.3497925	0.20
423.1983643	0.38
425.3337097	0.05
426.7506104	0.09
435.1385193	1.02
436.4664612	0.33
437.2184143	1.94
439.0835266	0.10
441.6883545	0.06
443.0018616	0.03
444.4097290	0.24
445.2272644	0.19
453.1291809	2.27
463.1458435	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	362.1588
Annotation	3-Acetylnerbowdine
Peak:m/z	Relative Intensity
115.1696930	0.02
121.8114014	0.01
123.0384903	0.03
161.0280914	0.12
165.1080017	0.01
167.2849731	0.04
175.2087097	0.03
181.0985870	0.04
191.0342102	0.21
191.8825073	0.03
193.1276398	0.55
205.3561859	0.02
208.0501709	0.05
209.0525055	0.14
210.2491760	0.04
237.7772827	0.00
263.0101318	0.03
265.1784363	0.01
271.4346924	0.02
277.9252930	0.02
280.8931274	0.02
283.2590942	0.01
285.2217102	0.01
295.4126587	0.01
297.3136292	0.03
298.1299744	0.02
299.1958923	0.06
313.2295532	0.07
315.1164551	0.34
316.4649658	0.01
327.0989075	2.68
327.7040405	0.06
331.3840942	0.09
345.0788574	100.00
345.6811829	0.48
347.6537170	0.08
350.4939880	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.2314
Annotation	Thiersinine B
Peak:m/z	Relative Intensity
170.9521484	0.15
181.0884705	0.07
204.9814453	0.04
219.3316040	0.04
223.1765900	0.29
237.1642914	0.30
261.9708862	0.05
268.0800476	0.09
279.2959595	0.22
283.2507324	0.29
292.3005981	0.07
296.8545532	0.04
310.1326294	0.04
311.0968628	0.10
338.8242493	0.06
343.9672852	0.14
345.3340149	0.18
366.1903381	0.05
377.2135010	0.15
377.9443970	0.17
379.2906799	0.06
387.5526428	0.09
388.1987000	0.03
391.9330750	0.09
403.0743713	0.11
418.2887878	0.05
420.9804077	0.30
422.1001282	0.04
435.9102478	0.02
437.1121216	0.12
444.1529846	0.05
445.2178040	0.12
448.2456055	100.00
449.2255249	1.54
462.2071533	11.81
462.8475037	0.16
464.1157532	0.21
470.1819458	1.06
471.3827515	0.06
472.2369995	0.48
473.0936584	0.16
476.4085083	0.16
489.1621399	0.11
490.1510620	0.15
491.3591614	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.1332
Annotation	Unknow
Peak:m/z	Relative Intensity
95.7557907	0.11
107.1492615	0.03
110.0147171	0.62
112.0978699	0.12
113.6417847	0.15
118.8304977	0.33
122.1332321	0.13
124.0494537	0.09
130.0729675	0.10
134.0805817	1.66
135.1595917	0.64
136.9950867	2.44
138.1737823	0.08
140.0842590	26.30
149.8114014	2.07
152.0433197	20.70
153.9532776	4.21
158.2011414	0.07
160.9925842	0.22
162.1015930	1.74
163.9961700	100.00
164.6050415	0.27
166.1950073	0.15
167.2103271	0.08
180.2426453	0.13
181.1737366	0.17
196.9049072	0.07
201.2555237	0.10
213.0201416	0.30
226.0417786	0.10
242.2193298	0.32
250.2321167	0.15
256.1453857	1.79
256.9865112	0.50
267.2449341	0.97
268.2042236	1.74
272.2982178	0.21
274.1109009	0.40
285.1467285	81.90
286.2462158	20.75
294.2244873	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
130.8894501	2.33
150.9532318	2.32
152.1595306	2.33
159.0207367	1.60
168.8719177	1.46
172.9921875	5.11
177.4186401	2.34
178.0238953	4.83
181.3028564	2.48
186.8891296	1.45
196.8542633	5.73
224.9530945	2.62
245.2302856	6.95
254.309906	3.93
263.2631531	6.56
272.2337646	11.80
275.2240906	2.04
280.1856384	2.77
281.2839966	2.76
282.0506287	14.54
288.1439209	1.85
295.3367004	10.78
309.0626831	2.76
328.4813232	2.40
332.3560181	2.34
333.5305176	3.22
339.2124634	3.80
342.3197327	5.74
343.5292664	2.47
354.2008057	2.04
356.199646	8.62
357.1401367	3.64
359.232605	5.44
366.3951721	1.75
367.6323242	5.96
372.1428223	8.74
377.2225342	52.79
379.0779724	4.31
380.3904114	5.76
382.0787354	7.94
383.4906921	2.32
385.3918152	1.89
390.4224548	9.68
391.025238	34.44
395.1744995	2.04
397.3712463	9.62
407.542572	28.14
408.2810974	100.00
409.8365784	16.20
423.8217163	8.47
427.3858032	1.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.3907
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
198.9384460	0.13
209.1068115	0.06
218.9433594	0.05
221.1150818	0.31
235.0970612	6.20
240.8772430	0.07
245.2775879	0.19
253.0154724	0.99
262.8402710	0.08
269.1825562	0.10
281.3253174	3.92
287.1709290	3.38
293.0456543	0.04
295.1709290	0.26
305.1864624	4.44
323.1254272	1.39
339.4754639	0.06
351.1787720	0.18
361.1257324	0.04
379.4328613	0.22
397.1658936	100.00
415.3262329	31.79
480.5526733	0.15
605.1860962	0.10
607.0478516	0.10
619.3665161	0.13
620.6986084	0.06
621.9533081	0.41
623.5340576	0.13
625.8914185	0.09
642.5537720	0.05
643.3520508	0.19
660.9951782	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.4792
Annotation	Strychnohexamine
Peak:m/z	Relative Intensity
323.3035889	0.01
445.4888916	0.01
471.2049561	0.01
581.8727417	0.01
609.5551147	0.02
615.8442993	0.01
631.4190063	0.03
721.7100220	0.04
808.5400391	0.01
841.8062134	0.01
867.4152222	100.00
868.1039429	0.38
870.6063843	0.01
871.4014282	0.02
895.8319702	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.23
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0890350	0.15
233.0139160	0.19
251.0940552	0.07
252.9778595	0.02
281.5160522	0.02
306.2009888	0.20
306.9751587	0.09
323.1747437	0.14
325.0584717	0.05
329.0544434	0.06
341.2118530	0.55
383.5074463	0.03
412.6902466	0.07
424.8630371	0.03
425.9613647	0.05
443.1561890	0.36
450.8645020	0.18
466.1385498	0.03
468.8224487	0.15
477.1891479	0.05
478.7470703	0.03
486.6151733	0.08
493.0549316	0.14
501.3040771	0.06
503.2901001	100.00
508.9929810	0.04
512.9035645	0.11
513.7026367	0.02
517.2523804	0.04
546.2407837	0.06
561.3594971	0.09
602.9004517	0.03
613.1627808	0.34
630.9226074	0.26
632.2153931	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1401
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
177.0975494	0.20
178.0475006	0.06
178.9115906	2.69
180.0832672	0.10
185.1268005	0.21
187.2077942	0.10
189.1145477	0.21
190.8770294	0.05
192.0731659	0.45
193.1629028	0.06
197.1614075	0.20
199.1288147	0.05
201.8854065	0.07
202.8731995	0.06
204.3596344	0.06
205.1085815	0.60
206.0494690	0.42
206.9831848	0.43
209.0305176	0.16
214.1267853	0.43
215.3918304	0.24
216.8873444	0.11
219.0764008	0.33
223.1795654	0.20
225.0540619	0.04
227.0997620	0.80
228.8994904	0.10
231.0150146	0.14
232.2921753	0.04
233.0121765	0.46
237.0570068	0.07
241.9631042	0.82
243.0792389	1.12
245.2225800	0.38
246.2216339	0.09
248.0534821	0.22
249.1946411	0.42
250.1909180	0.10
251.1894836	0.09
252.9698029	0.13
254.6385956	0.10
259.1030273	1.37
263.0597839	0.17
265.1522827	0.05
268.9649353	0.22
269.9933167	2.20
271.0861206	12.36
272.2782288	0.72
273.4064941	0.10
279.4544678	0.08
283.0868225	0.04
285.0157471	0.39
287.0249023	6.23
288.1589355	0.87
289.0942993	1.30
291.1871033	0.08
295.1253662	0.22
297.1436768	0.71
299.1432495	0.53
300.9214478	0.60
303.0182495	0.20
307.0494385	0.23
311.2224121	0.20
313.2255554	0.50
315.4287109	6.18
316.0462036	100.00
317.1613770	60.54
318.0554810	1.30
325.4037476	0.09
326.9810791	0.43
328.0974121	0.06
329.1545715	3.60
341.1301880	0.60
343.0244141	0.15
353.0255127	0.03
357.2020264	0.10
359.1630859	2.79
360.1314087	0.27
365.2996216	0.15
369.3372192	0.06
371.0241089	0.08
372.1854248	0.09
379.1112061	0.06
383.0081787	0.03
387.3110352	0.05
389.2367554	2.03
403.3641968	0.15
413.2966309	0.77
425.3386230	0.22
430.6951904	0.09
431.3250732	0.40
437.4985962	0.20
443.3601074	0.61
461.3289795	0.66
462.4569702	0.23
463.3290405	0.05
473.1566772	1.36
478.9981689	1.11
481.0787354	0.75
482.2695312	0.07
485.5986938	0.03
497.4378662	0.09
499.2543335	1.17
509.7797241	0.04
515.3442383	0.35
521.2742920	0.08
531.2564087	0.19
535.1721802	0.15
563.1185913	0.11
571.1653442	0.06
579.1131592	0.29
581.1456299	0.14
589.1996460	0.25
607.1757202	12.12
608.1569214	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.163
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9839935	1.06
221.2171478	0.08
235.0952148	0.10
281.0102539	0.22
287.7868042	0.15
354.1466675	0.19
366.0648804	0.06
379.2145386	0.33
380.1892700	0.14
381.1151733	0.42
383.1053467	0.06
415.0678711	0.13
421.2890625	0.18
441.2266235	0.20
454.7506104	0.10
456.8853760	0.21
464.8411255	0.18
465.6516113	0.05
468.8893433	0.67
475.9104004	0.17
477.2148438	0.30
487.3488159	0.07
499.1162109	0.15
503.2046509	4.16
509.3841553	0.45
513.1298828	0.26
535.2885132	0.12
539.1987915	100.00
540.3690186	1.36
541.3434448	0.31
553.1876221	0.49
559.9315186	0.61
572.9442749	0.28
574.2135010	0.05
575.8655396	0.20
576.4907837	0.20
577.1683960	9.94
586.0552979	0.42
586.9467773	0.06
587.8385620	0.18
595.2033691	0.10
625.3770142	0.11
634.9575195	0.22
638.5924683	0.21
646.0855103	0.23
647.8474731	0.09
649.0983276	0.27
672.2702637	0.32
672.9828491	0.30
677.2286987	1.48
684.6716919	0.16
687.0354614	1.32
703.9421997	0.74
704.9889526	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.323
Annotation	PE(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
166.0383148	0.12
184.0494080	18.01
226.2481232	0.06
242.9249115	0.10
252.6566162	0.09
258.1354980	0.74
311.2490540	0.71
313.0144043	0.07
326.0312805	0.08
327.2783203	0.07
353.4513550	0.18
368.0808716	0.28
384.3966675	0.11
385.0672302	0.14
389.8134766	0.13
403.3323059	0.07
409.6258240	0.16
416.9900818	0.09
460.6608887	0.03
476.3830872	100.00
477.1554871	0.39
485.0013733	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	500.1685
Annotation	Unknow
Peak:m/z	Relative Intensity
159.4727478	0.28
160.9924316	0.36
162.0514984	1.12
162.9483490	0.11
178.9377747	3.71
187.2268982	0.14
193.1056519	1.57
195.8898315	0.12
233.0830383	0.42
236.1298828	0.06
240.4297485	0.15
245.0289154	0.30
267.2180481	0.03
273.7668152	0.10
274.7518311	0.05
290.2414856	0.24
295.6375732	0.05
308.1103821	100.00
310.3244629	0.14
322.9143677	0.09
328.3305664	0.06
353.0457764	0.13
366.9784546	0.33
369.1163940	0.21
370.8661194	0.10
383.0908813	0.04
411.8808899	0.07
418.2078552	0.15
424.3456116	0.13
425.2015076	0.10
440.6820068	0.11
462.1231995	0.18
464.1404724	0.14
465.3273621	0.12
481.4150085	0.02
482.4293518	0.71
483.9872131	0.55
492.1702271	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1807
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1196899	0.02
210.3508606	0.01
213.0997467	0.02
220.9851379	0.03
228.0626526	0.02
229.1731262	0.01
232.6740570	0.01
252.3066711	0.01
253.9734192	0.09
261.4322510	0.01
266.1787415	0.00
272.0937805	0.13
273.1675110	0.01
274.9307251	0.02
284.1940308	0.01
314.9650269	0.02
323.0817871	0.05
330.0975952	0.41
331.0899658	0.04
332.2578125	0.06
342.0780029	0.01
348.0779419	0.00
349.0772705	0.02
351.3233643	0.01
368.9623413	0.01
372.1534424	0.02
381.0736694	0.01
392.4733276	0.05
393.5138550	0.01
408.3427124	0.03
412.0570679	0.03
417.2591553	0.02
431.2562256	0.03
432.3736572	0.09
433.4294434	0.06
439.1472168	0.09
443.3026123	0.03
444.4935913	0.04
455.7821045	0.04
459.3486938	0.13
461.2140503	100.00
462.1929932	26.43
463.2523193	0.04
472.5958252	0.02
477.0677490	0.01
485.4623413	0.03
486.2949219	0.01
503.3858032	0.03
504.3200073	0.01
517.3059692	0.02
524.9702759	0.01
536.2030640	0.03
547.0411987	0.01
550.4583740	0.01
562.8628540	0.02
575.3446655	0.02
585.8810425	0.01
602.2709351	0.06
603.2034302	0.01
615.9984741	0.02
620.2086792	0.05
622.3302612	0.05
647.4771118	0.02
648.2252808	0.04
668.1132812	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	608.3281
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0050201	0.07
300.0730591	0.08
310.0705566	0.06
312.1185913	0.25
313.2623596	0.33
328.2549438	0.32
330.4263916	6.14
331.2726440	1.29
384.5408936	0.13
433.4362183	0.13
447.5650024	0.04
449.1753540	0.03
450.2503052	0.40
475.3199463	0.80
476.3836060	0.11
477.3662720	0.09
491.2026367	0.28
492.5657349	16.08
493.4135742	100.00
494.4929199	0.13
509.2666626	0.09
518.6163940	0.08
522.2113647	0.24
536.2971802	0.15
544.1664429	0.10
546.4323120	0.09
549.8790894	0.13
550.5303345	0.12
562.3464355	0.57
564.4939575	4.66
565.4918823	0.06
572.2714233	0.13
584.7330933	0.12
589.4806519	0.45
590.4496460	7.64
591.5989380	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2779
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
139.9985809	0.07
141.7789154	0.06
153.1205902	0.29
196.1396790	0.25
199.0438690	0.37
200.9522095	0.07
214.0832520	0.84
227.1648254	0.06
253.3552551	0.13
255.2448425	100.00
255.8572083	0.63
268.0521240	0.04
272.3764648	0.17
306.2006226	0.15
307.8818359	0.23
322.5547485	0.07
362.5290833	0.07
376.4403381	0.25
378.1780701	0.05
389.0420227	0.08
390.9469299	0.19
393.2262878	0.18
395.0709534	0.10
405.6788330	0.09
406.4535828	0.27
414.1167603	0.27
416.0087891	0.29
417.3414001	0.07
423.6056213	0.10
433.9126282	0.37
435.2579346	0.10
436.6917114	0.08
452.9512024	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.97
Annotation	Unknow
Peak:m/z	Relative Intensity
182.8763123	1.13
201.0121765	0.54
235.2169495	0.16
236.7144470	0.06
247.5427551	0.22
249.1850586	0.04
249.9271240	0.35
251.9684753	0.11
252.8775024	0.04
254.8201599	100.00
255.6741028	0.03
266.9754639	0.38
271.2988892	0.16
272.1070862	0.50
272.7553101	5.19
275.2734680	0.41
276.8042603	0.12
278.1418762	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.2
Annotation	(-)-11-nor-9-carboxy-Delta9-THC
Peak:m/z	Relative Intensity
120.9685059	0.42
123.0914307	0.29
131.9958496	0.38
138.8180542	1.49
156.9749146	0.65
165.2518921	0.99
167.0177155	0.33
169.273468	0.22
173.2260284	0.24
175.0319824	0.47
190.0163879	0.53
196.0112152	0.65
196.6570129	0.52
204.9571381	0.20
207.2516022	0.40
213.1263123	1.61
214.8016052	0.59
216.2664795	0.53
221.0958252	0.22
222.9605408	0.58
230.4727783	0.83
237.3500671	0.29
245.1068115	0.24
248.8989868	0.33
253.1853638	1.20
257.1315002	1.11
258.1130066	0.65
263.392334	0.18
271.1025391	0.20
273.2279968	0.24
275.2871094	3.63
276.3041382	1.39
281.3710938	0.67
282.769165	0.24
286.2835999	2.01
301.0474854	1.21
303.3996582	0.44
304.88974	0.76
309.2412109	12.89
314.1399841	1.31
327.1859741	100.00
328.0589294	0.37
330.3340454	0.34
345.230896	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	612.31
Annotation	Oleficin
Peak:m/z	Relative Intensity
236.1086121	0.13
242.2518768	0.11
275.7896729	0.19
299.0264282	0.07
321.8360596	0.11
327.3323975	0.13
348.8405151	0.08
380.0297852	0.37
405.4291992	0.16
414.5708618	0.15
419.3407593	0.23
434.0010376	0.07
436.1456299	0.06
437.9880371	0.08
468.1691895	0.15
478.0845947	0.46
481.3025513	7.26
488.2951050	0.11
494.2640381	0.17
495.3790283	0.15
507.2178345	0.29
510.2270508	0.25
516.2326660	0.10
522.2875366	1.17
531.4298096	0.08
532.0575562	0.24
533.2168579	0.22
539.2080688	0.20
540.1823120	1.96
550.2374268	0.23
552.3315430	100.00
553.4130249	1.87
566.2743530	2.97
568.2180176	0.09
569.6467896	0.11
574.2525024	0.49
576.2411499	3.97
584.0574341	0.47
593.7142334	0.23
594.3804321	0.36
597.7664185	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.2195
Annotation	Unknow
Peak:m/z	Relative Intensity
297.9819336	0.09
306.2635498	0.04
324.2677307	100.00
333.1461792	89.45
333.7706909	0.36
339.9665833	0.16
389.4688416	0.04
405.8310852	1.86
412.6858521	0.69
431.7410278	0.11
433.9512024	0.07
435.0438232	0.50
450.0371094	0.08
452.3724670	0.14
455.8343811	0.27
461.1363220	0.29
462.2717590	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.32
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
177.9363251	0.03
184.0079498	19.87
240.0981750	0.13
243.0516357	0.22
258.1389160	0.87
289.1574097	0.12
332.8528442	0.09
377.6060181	0.14
441.2442017	0.26
483.0675659	0.05
486.8557739	0.12
500.3757935	100.00
501.2783203	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.3019
Annotation	PI(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
175.3092194	0.25
176.9771881	0.22
203.1493988	0.59
206.9917450	0.14
245.2934570	0.48
247.3444214	0.13
261.0142212	0.67
263.3648376	0.30
266.5881348	0.25
277.5380859	0.55
291.0573120	0.15
299.2584839	0.58
317.2477417	1.12
319.3025513	0.57
335.1162109	4.41
337.2521973	100.00
342.8311157	0.58
355.2513428	0.20
362.0076904	0.07
401.4284058	0.06
403.6174316	0.09
415.3077393	0.13
416.1843262	0.75
417.4444580	0.50
425.3637695	0.09
439.5162964	0.40
443.2014771	0.39
449.5352783	0.08
498.8600464	0.31
500.4642944	0.34
505.3236084	0.69
521.1464233	0.08
539.3667603	0.08
547.3636475	0.07
551.3233032	0.20
555.2453613	0.35
561.2141724	15.56
561.8352661	0.06
563.8508301	0.32
565.4049683	1.18
567.2920532	2.13
568.4211426	0.54
569.6469116	0.54
570.4625854	0.19
578.6280518	2.23
579.2426147	27.90
580.4159546	0.07
582.3666382	3.03
583.7941895	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.3237
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1256409	0.05
255.3039856	0.06
269.1368103	0.05
289.2432251	0.14
293.0879517	0.18
295.3380127	0.08
297.1516724	0.32
301.9472046	0.14
313.1757812	0.06
319.4060669	0.10
341.3995361	0.08
343.3837891	0.05
344.6256104	0.05
351.2919922	0.14
353.2991943	0.07
362.2122192	0.11
387.1718140	0.38
389.3583984	0.06
407.4743652	0.06
413.2319336	0.07
417.9321289	0.22
420.3275757	0.35
423.5790405	0.20
443.2635498	0.08
445.4001465	0.06
469.6561890	0.11
471.3517456	0.13
482.5669556	0.20
489.2061768	0.21
493.5945435	0.37
499.2388306	0.05
501.2197876	0.13
504.2219238	0.14
509.7476196	0.16
510.9915161	0.09
511.6255493	0.41
512.5470581	0.22
514.3342896	0.60
515.2030029	0.17
517.4376831	0.18
519.4459229	100.00
520.2064819	0.31
527.2551270	1.20
528.1876221	0.15
529.5557861	0.33
534.4788818	0.18
535.3440552	0.81
536.6689453	1.62
537.4683838	1.80
554.8936768	0.95
555.6542358	1.37
558.6633301	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1276
Annotation	Unknow
Peak:m/z	Relative Intensity
134.9351501	0.13
138.0167999	0.33
138.8710327	0.13
145.9979401	0.05
153.1180573	4.16
154.0385132	0.34
159.1239166	0.03
161.0221558	0.37
162.0065613	0.30
163.0270233	0.82
174.9216461	0.05
176.0668640	0.17
177.0074158	2.38
177.9395294	0.42
179.1264954	0.32
180.0686493	0.03
181.9048462	0.06
182.7283020	0.09
193.0209045	0.10
194.1466064	0.07
195.1298981	0.26
198.8463898	0.04
205.0258179	0.06
209.0582886	0.57
210.1573181	2.58
211.1550598	1.16
217.9954376	0.02
223.1430206	0.27
225.0581818	75.77
226.1168213	13.59
237.2831879	0.04
251.2110291	0.13
252.2569580	0.14
252.9981995	0.11
254.2137146	0.03
261.0082092	0.18
267.1073608	2.05
268.0451965	0.60
269.3069458	0.05
270.2323914	0.07
279.2493286	0.05
281.1962585	0.47
282.0155029	0.06
283.0513000	0.46
295.2409363	1.28
296.2248230	0.04
308.2866211	0.14
309.2637634	0.11
313.1124268	100.00
314.1369629	18.46
323.5060425	0.02
327.0580139	0.17
329.4779053	0.04
337.3390808	0.04
339.2900696	0.49
340.2047729	0.04
345.8610840	0.07
349.2896423	0.02
355.1155701	4.35
356.1087646	1.21
360.2554321	0.13
361.0562134	0.02
370.5079651	0.07
373.2018433	0.55
379.0679626	0.07
385.1031494	0.36
387.1499939	28.86
388.2072144	8.05
398.2734985	0.07
409.3150940	0.06
413.3207092	0.29
414.9266968	0.40
416.1135559	0.05
434.8635559	0.08
437.0821838	0.06
441.0665588	0.04
443.2864075	0.72
444.4197083	0.30
445.5679626	0.12
457.1359863	0.64
458.0790405	0.32
475.1026306	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.19
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
113.0689163	0.61
121.2878723	0.11
122.3487091	0.17
124.8992386	0.21
128.9700623	0.38
132.0772858	0.05
136.0037994	0.15
138.1228027	0.24
143.1897125	0.22
149.0233765	0.55
151.1280518	0.06
152.9732208	16.98
154.1697388	0.05
159.0895996	0.49
161.0696716	3.53
163.9613037	4.66
173.1805573	0.15
175.1906433	0.42
177.0523682	0.85
178.9757080	1.88
185.1276550	0.48
186.7608490	0.33
188.3332672	0.04
190.0273438	3.00
193.1250153	0.07
195.0171509	0.18
203.0663147	0.41
205.0288849	64.50
207.0274506	0.16
207.9584961	1.18
217.8211670	0.41
221.1393738	0.88
223.0438690	100.00
232.1831665	0.70
233.2168579	1.24
237.0634155	1.15
247.1391296	52.28
248.4653320	0.08
250.2540894	0.05
251.0657043	0.54
252.1426697	0.94
263.0738525	0.95
265.0801086	8.16
275.3900146	0.11
277.1091614	1.91
279.3762207	0.29
286.4102783	0.14
289.2017822	1.25
292.2315063	0.15
295.1881714	4.52
305.1912537	0.23
307.1856384	0.34
311.3151855	0.11
317.4265442	0.07
325.1737366	5.29
339.2752380	0.50
341.2649841	0.22
350.2708740	0.06
351.4722595	0.07
355.2344666	0.47
356.9634705	0.39
367.1338196	2.25
368.3466492	0.12
369.1639709	0.08
370.2738342	0.06
385.5751953	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1614
Annotation	10-Deoxymelittoside
Peak:m/z	Relative Intensity
184.8898621	0.08
198.7755127	0.06
203.0950165	0.23
210.9108582	0.09
238.2784119	0.03
255.2124786	0.04
269.2487183	0.04
272.9046021	0.08
275.2671204	0.06
281.0793457	0.04
297.2699280	0.06
298.2257080	0.03
318.6677856	0.08
323.2542725	0.10
331.4028931	0.13
332.2086182	0.36
333.3651733	0.11
352.2922974	0.07
366.5108032	0.14
370.4473267	0.16
399.5759277	0.22
403.2189941	0.07
411.1560059	0.16
413.9130249	0.03
415.1638794	0.05
416.3086548	0.08
437.1149902	0.08
438.5900269	0.06
447.4330444	0.25
448.8231812	0.08
458.2242432	0.11
459.3588257	0.05
473.1915283	0.25
489.2995605	0.07
491.1779175	0.12
495.2935791	0.03
517.2550049	100.00
518.1067505	0.03
520.4000854	0.12
526.3016968	0.05
531.3519897	0.15
533.4357300	0.16
544.1386108	0.23
563.4384766	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
126.1768188	0.72
149.076828	0.59
164.87117	0.51
174.0415192	1.09
195.194458	1.30
205.0401917	1.27
206.54216	4.24
207.6574097	14.98
208.6005859	0.98
210.101059	0.45
214.9880981	0.72
222.2427063	10.69
223.1909943	16.19
224.0447845	1.32
236.1384125	1.59
251.0827179	100.00
252.0648651	16.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.1238
Annotation	Methyl helianthenoate F glucoside
Peak:m/z	Relative Intensity
107.9168396	0.37
108.8206787	0.19
119.1977310	0.14
127.5258636	0.17
129.0530396	0.18
130.0992432	0.07
131.0984192	0.11
138.7586823	0.07
146.8478088	0.59
149.0418701	100.00
153.7332764	0.10
169.1235352	0.11
173.0198517	0.20
174.2580872	0.09
190.8285828	0.11
194.9538574	0.37
203.2015839	0.15
210.3213806	0.03
211.0097656	0.08
221.1128235	0.12
235.1419678	0.12
241.2680969	0.05
259.0751953	0.14
263.0026855	0.36
265.1229553	0.25
266.9009094	0.19
271.1904297	0.40
273.3735046	0.09
281.9785767	0.36
291.9805908	0.04
293.2942200	0.56
294.9313660	0.21
299.0392456	0.09
307.0219727	0.69
308.1743774	0.08
309.3270264	0.08
311.2633667	0.44
312.1224976	0.10
314.9968872	0.39
315.8844604	0.36
317.2178955	0.71
318.0810547	0.36
322.3086548	0.07
323.2359619	0.19
324.8448486	0.03
333.0183105	0.23
335.1510620	2.43
336.2193298	0.24
337.5462952	0.29
343.6300964	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.6114
Annotation	Unknow
Peak:m/z	Relative Intensity
451.0039062	0.12
452.3118896	100.00
452.9213257	0.35
504.3943481	0.19
634.0056763	0.06
774.7144165	0.08
926.4589844	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.1856
Annotation	Vernoflexuoside
Peak:m/z	Relative Intensity
142.2332611	0.14
146.0238800	0.63
188.0818481	23.53
205.0706482	100.00
247.1283875	0.19
275.2957153	0.18
299.5113831	0.36
355.3216248	0.19
357.6318970	0.26
391.2165833	0.78
392.4024658	0.46
400.8849487	0.27
410.3277893	0.11
415.1145935	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
109.0811768	1.74
110.9995499	0.32
127.2429657	0.40
130.9914246	0.94
132.6295471	0.35
135.0841675	1.31
143.0499268	2.47
147.3187866	0.37
149.1556091	1.68
151.0825806	0.57
158.9753723	0.38
162.9627228	0.35
171.127594	0.88
173.1277161	2.21
175.0436096	1.95
189.0238037	0.60
196.670578	1.14
199.2164612	1.50
201.0440979	0.97
202.9768066	1.50
217.219696	1.75
222.9310913	0.32
230.3097229	0.81
235.2555542	1.34
239.2642822	0.89
243.1274109	0.35
247.1561584	4.23
252.3101807	0.41
255.1437988	1.14
259.8709717	1.39
269.4417725	1.90
279.262146	1.30
280.352417	0.66
285.1239624	1.33
287.2320251	0.85
295.0268555	1.85
297.2825012	1.23
299.9624634	1.25
305.2908325	5.95
307.4196777	2.06
309.3674927	2.13
311.282196	0.55
312.3868103	0.50
323.2376099	100.00
323.8438416	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1294
Annotation	Unknow
Peak:m/z	Relative Intensity
101.0844727	14.74
102.8936920	0.49
112.9943924	14.79
117.0400696	0.28
118.8448334	0.32
127.0443420	0.62
128.9714966	1.03
130.9025116	1.13
142.9058380	2.75
149.0979004	1.31
152.9157715	0.48
157.1286469	2.49
160.7417297	0.45
169.0941467	0.20
170.9793396	0.24
173.2095184	0.22
174.9934692	9.30
178.9981079	16.81
186.9405823	0.68
189.1469574	2.11
193.2457886	0.44
205.1103668	4.03
223.0895386	4.01
230.9914246	8.91
244.0838318	0.66
249.0109558	100.00
267.1371765	77.05
267.9078369	0.47
271.1893005	0.48
273.8529053	0.52
275.2577515	0.96
289.0642700	0.72
291.1129456	7.18
305.1876221	0.75
307.1569214	0.24
315.1609802	1.21
319.2365112	0.21
322.9045410	0.34
333.2111816	36.27
333.9610596	0.27
335.4000244	2.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.1475
Annotation	Bocconoline
Peak:m/z	Relative Intensity
115.6974640	0.03
129.9543152	1.04
130.9526062	0.15
136.9643707	0.08
143.9598236	0.05
147.8332825	0.03
160.1666870	0.03
162.0380249	0.26
167.8484802	0.09
177.9340210	0.12
180.0636292	0.13
188.0252075	0.16
191.0399475	0.07
212.0798035	0.07
215.0009460	0.19
216.0624542	0.51
218.1580811	0.04
234.0176697	42.51
249.2362061	0.03
251.0034790	100.00
251.6062622	0.51
273.8381653	0.04
276.8700562	0.22
287.0845337	0.86
305.1874390	7.91
317.2207031	0.39
335.0972290	0.06
344.2374878	0.37
345.0794678	0.18
362.2124329	3.47
363.1106567	0.24
371.2832336	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9192505	4.89
208.9537506	5.09
212.8918762	1.20
232.1612854	0.88
247.9482422	0.72
248.6999512	0.45
250.9725647	0.87
282.2682800	0.37
286.8088684	1.50
288.2614441	0.33
290.8380432	40.07
291.9517517	9.36
292.8464355	100.00
374.4882812	6.04
375.9936218	20.40
376.8005676	53.61
386.7609253	6.27
387.6147461	1.28
396.6789551	0.87
414.8399658	5.49
416.9331970	0.61
417.9391479	1.03
424.9949951	7.36
441.9318237	1.22
442.7875061	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.3596
Annotation	Denin
Peak:m/z	Relative Intensity
191.0554810	0.03
193.2746735	0.05
198.8928375	0.06
203.0292664	0.24
217.0908203	0.10
219.0003967	0.21
221.1273651	0.17
227.0565186	0.20
233.1412811	0.09
235.1521301	7.42
245.0765686	0.49
248.5892487	0.15
253.0519714	1.15
259.0354004	0.07
262.9014282	0.39
276.7269897	0.22
277.3547363	3.37
287.0988159	3.78
290.9952393	0.09
295.2162170	0.02
303.2573853	0.04
305.1618652	5.77
323.1048584	0.71
329.2867432	0.02
349.0625610	0.10
351.3970947	0.04
361.2631226	0.39
373.3656616	0.06
379.2891235	0.24
397.2191162	100.00
415.2619019	36.38
459.4264526	0.02
494.9816895	0.17
602.1541138	0.04
616.3792114	0.03
629.6510620	0.06
630.7956543	0.14
637.5149536	0.14
639.1173706	0.06
657.0274658	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.12
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
131.0458069	0.04
143.2347412	0.02
148.0949707	0.02
161.0750732	0.05
179.0333862	1.55
197.1455688	0.02
254.1422729	0.09
271.1234436	0.03
272.0387573	0.11
274.1452026	0.03
277.0018921	0.03
280.6319275	0.03
286.1159058	0.03
293.0316162	0.03
295.0658569	0.24
306.0922852	0.09
341.1398315	100.00
342.0557861	0.04
358.1040649	0.04
370.2174683	0.06
373.1492310	0.01
377.1574097	0.03
383.0704041	0.07
384.2193909	0.18
385.2766724	0.06
410.2527771	0.02
438.3594666	0.06
439.2360535	2.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
122.8760147	1.45
125.1165237	0.50
141.1481934	0.16
151.2245483	0.15
162.9792786	0.20
167.039856	100.00
172.9480438	0.08
190.9187469	0.64
197.0997009	0.30
203.0785522	0.36
205.240921	0.18
209.1620178	0.43
213.2345276	0.04
220.9415894	0.52
237.091095	0.38
241.1153564	0.30
243.0557556	0.09
245.3352356	0.10
249.2211609	0.05
269.2662048	0.20
271.1057739	0.14
281.2458191	0.19
282.0906982	0.37
283.1069641	0.41
284.9807129	0.99
286.0739441	0.17
287.051178	0.12
288.4141846	0.08
292.9176636	0.05
294.9549561	0.06
299.9130249	0.07
308.8580322	0.09
310.9056396	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.3067
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0415039	0.07
152.9615173	0.22
160.7128296	0.06
162.9974365	0.03
196.1466675	0.02
200.8842316	0.07
209.1314087	0.04
220.7765503	0.06
227.2828522	0.31
235.0903168	2.04
239.1024628	0.16
247.0997467	0.05
251.0753784	0.05
253.2294617	100.00
260.9727173	0.13
269.3328857	0.04
296.0103760	0.04
301.1841125	0.11
305.0070801	0.13
329.1325378	0.24
341.0792236	0.20
342.5908813	0.03
357.1261292	0.62
361.0693054	0.09
363.1817627	0.03
365.4543762	0.07
376.1885071	0.12
383.0611877	0.16
389.4590454	0.03
394.4776306	0.07
398.6210632	0.09
399.2811584	0.06
400.6131897	0.03
412.9079285	0.11
414.0500793	0.08
415.1392517	0.03
419.8567505	0.17
421.8893127	0.02
428.0024719	0.14
432.2751160	0.07
443.2388306	0.68
444.2710571	0.10
445.4821167	0.18
446.1383057	0.19
451.5422363	0.33
452.3149414	0.74
453.5230408	1.77
454.3096619	32.70
455.4075012	0.06
459.5246887	0.06
469.1111755	0.06
470.1160583	0.07
471.4068909	0.30
472.0837097	0.18
473.0706177	0.05
473.7013245	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2653
Annotation	Blumenol C 9-O-(4'-O-glucosyl-beta-glucoside)
Peak:m/z	Relative Intensity
190.8709106	0.04
221.0740662	0.12
246.2884674	0.08
257.3383179	0.04
285.0263672	0.09
287.9923096	0.07
290.1581726	0.21
291.1746826	0.08
329.0709839	0.06
330.7447510	0.11
331.4107056	0.16
371.4384766	0.13
372.6130981	0.13
382.0010986	0.13
397.4346313	0.06
399.3511353	0.04
400.2639160	0.09
408.3824463	0.48
409.2416992	0.86
410.0725708	0.21
417.4932861	0.28
425.1943970	0.43
426.0860596	0.17
427.2495117	0.91
428.2821655	0.65
435.3887939	0.16
443.2284546	0.08
449.9099121	0.05
451.1586914	0.15
453.0888062	0.59
454.1563721	0.37
459.2734985	0.09
463.2641602	0.15
465.6627197	0.50
478.4194336	0.06
482.2802124	0.09
490.3015747	0.03
491.2492676	0.04
494.2075806	0.23
495.6581421	0.12
500.8765259	0.20
515.8416748	0.06
516.9770508	0.09
533.3006592	100.00
534.3630981	40.67
535.2860718	0.43
536.9436646	0.35
542.1513672	0.13
544.0734253	0.33
547.4042969	0.17
553.4003906	0.29
556.7184448	0.21
557.7651978	0.09
561.1871948	0.12
562.2383423	0.68
563.0365601	0.11
576.3676758	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1169
Annotation	Unknow
Peak:m/z	Relative Intensity
142.7234497	0.03
160.2038879	0.04
161.0446777	0.05
163.9726257	0.03
178.9988403	0.19
179.9064941	0.03
195.3445129	0.09
239.2034912	0.03
249.1465454	1.13
283.0485840	100.00
286.4033813	0.04
311.1681824	0.04
329.2933044	0.03
331.4578857	0.03
367.1264343	0.04
369.2135315	0.04
374.1255188	0.01
383.4443665	0.04
399.2132263	0.10
401.3162842	0.04
407.9518433	0.03
422.7342529	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.77
Annotation	Unknow
Peak:m/z	Relative Intensity
138.5308533	0.09
212.8555603	8.00
294.6627808	0.10
296.7279968	100.00
297.3483276	0.32
311.7528992	0.08
334.7220459	36.25
335.3354797	0.06
362.0068054	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	567.2569
Annotation	Methylene-bismehranine
Peak:m/z	Relative Intensity
171.0191498	1.92
178.1503601	0.15
200.8030701	0.21
223.0193481	24.30
224.1176147	1.70
241.0258026	58.87
242.0662537	3.09
251.3179474	18.97
252.2664795	2.50
258.9637451	2.16
260.3807373	0.36
288.3103027	0.21
315.0989990	100.00
316.2016602	6.97
333.1152344	10.53
334.0590820	0.39
387.3434448	4.15
388.2896118	0.59
405.4453735	1.26
461.8998413	0.36
475.6607056	0.28
477.2297974	0.38
477.9400635	0.20
480.2811279	0.13
493.8604736	0.19
499.5856934	0.13
508.2882690	0.62
514.2705688	0.22
523.1479492	0.15
529.3853149	0.12
530.5021362	0.70
531.8383789	0.59
532.5241699	0.64
536.1004639	0.33
548.7787476	0.12
549.4700317	0.35
550.6107788	0.54
552.0277100	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1663
Annotation	Butrin
Peak:m/z	Relative Intensity
171.9803314	0.08
172.9678040	0.04
179.1864166	0.05
180.8996277	0.48
181.9284058	0.13
184.8948517	0.06
195.2378540	0.10
197.3221741	0.33
201.1079102	0.21
202.9967194	0.08
220.9407349	0.17
223.0726013	0.14
225.0457458	0.93
225.8857727	0.12
227.0502930	0.20
240.9698792	0.11
243.0703430	0.75
259.2074890	2.27
269.0679321	100.00
270.2762451	0.23
271.9298096	0.16
287.0021362	2.29
301.1925659	0.05
314.9538574	0.04
353.2847290	0.10
357.3282471	0.27
363.6625977	0.33
377.9173584	0.19
380.8416138	0.17
389.2503052	0.28
402.3148804	0.11
407.2420044	0.11
408.9842529	0.09
411.3148193	0.07
418.1285400	0.16
433.2650757	1.23
443.4125366	0.08
461.4479980	0.12
466.1488647	0.04
469.2993774	1.98
471.4832764	0.10
477.6257324	0.18
479.4272461	0.35
482.3417358	0.39
489.4336548	1.10
491.2230835	0.15
494.0838013	0.06
501.1489258	0.26
504.4107666	0.49
514.4345093	0.34
546.3338013	0.07
548.9695435	1.03
549.6233521	0.26
551.2340698	0.90
552.3120117	0.13
556.5610962	0.24
557.9293213	0.09
558.9256592	0.74
560.2300415	0.18
567.2901001	0.23
570.4005737	0.39
571.7426147	0.09
576.7232056	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1818
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
131.0175781	0.74
162.8000488	0.05
166.8719635	0.09
180.1084290	0.42
185.1548462	0.30
188.9558411	0.40
193.0708466	0.15
203.0876923	0.11
209.2423096	0.30
219.0679016	0.11
229.5328674	0.12
235.1752319	0.36
243.0097961	0.18
249.1065979	1.56
262.6407776	0.15
264.5042419	0.16
265.1211243	0.10
268.1191101	0.20
271.5408936	0.36
275.9081421	0.08
277.9473267	0.12
291.1999207	0.10
295.5278015	0.16
303.2571411	0.08
305.4006958	0.16
310.9411316	0.08
312.9545288	0.15
315.3106689	0.07
324.1268921	0.18
341.0297241	0.57
342.2847900	0.15
343.1036987	0.35
354.9220276	0.32
365.1843567	0.10
366.2337646	0.06
367.2005310	0.58
381.1488037	100.00
382.0361023	0.91
383.1629028	0.79
383.9861755	0.51
391.9985046	0.16
393.0277710	0.87
394.3252563	0.34
397.0291138	0.21
398.0791321	0.21
406.1771545	0.06
408.5270386	0.20
409.3038635	1.00
418.8960266	0.20
427.2790833	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.3799
Annotation	Gingerglycolipid B
Peak:m/z	Relative Intensity
218.9534912	0.02
235.1935272	0.02
245.3302002	0.02
262.7132568	0.01
279.1011047	0.08
287.0375061	0.07
305.0417480	0.14
321.1448364	0.04
323.5070801	0.05
379.2720947	0.05
397.2514038	8.07
400.0394897	0.09
415.2460938	1.70
452.4537354	0.02
471.4086914	0.05
580.6631470	0.03
649.6589966	0.04
664.0598145	0.03
677.2662964	100.00
678.7482300	0.02
679.4308472	0.03
686.4133301	0.04
687.2028198	0.03
708.3351440	0.02
723.0897827	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.1559
Annotation	10-Deoxymelittoside
Peak:m/z	Relative Intensity
149.1809998	2.77
151.2208862	0.41
153.1180878	5.42
154.1418610	0.52
154.7880707	0.14
156.7541199	0.14
158.0505676	0.85
158.9932556	0.28
160.0163879	8.47
160.9971619	1.28
171.0898438	0.47
173.0701447	0.86
175.0615997	34.05
176.0164490	3.75
177.2681122	0.66
177.9855804	3.23
178.9579926	1.00
186.3561859	0.08
188.1376648	1.44
190.9192505	3.46
193.0115051	100.00
200.1460724	0.55
201.3954773	0.32
202.0912018	0.13
203.0646973	1.88
207.1246643	1.63
214.1383667	0.16
214.9761963	0.69
217.0653381	13.60
218.2673187	3.06
219.2198486	0.14
220.0272675	0.17
220.9791870	0.67
229.2528687	0.24
231.2829437	0.83
232.1759644	0.18
233.3084106	0.81
235.1221619	35.38
244.1366577	0.82
244.7845459	0.09
247.0633545	8.75
249.3093872	0.43
254.2027283	0.24
257.1116638	1.09
259.0430298	34.99
265.1493835	27.45
270.8660889	0.13
275.0670471	0.90
277.0009766	1.03
287.0015564	0.06
289.1519470	0.50
289.9608765	0.26
292.7086182	0.56
293.3815918	0.12
295.0679321	30.59
297.1909790	0.16
298.2291260	0.34
301.2672729	0.38
306.2534180	0.73
307.2066650	1.76
308.0825806	2.05
309.0230103	0.57
312.7206421	0.17
315.1924438	15.45
316.1116943	5.84
319.1164551	34.61
323.1598511	26.44
325.1224976	0.21
337.1856689	59.94
340.2302856	0.17
341.2830200	5.65
355.0659790	31.59
355.7108765	0.16
358.2599487	0.43
362.3402710	1.31
363.3323364	0.64
366.8861694	0.12
369.2509766	4.76
372.9481812	0.10
387.1895752	0.85
427.0974731	0.40
442.1478271	0.63
457.4086304	0.22
469.2962036	0.39
470.2467651	2.06
471.1730347	1.87
473.2003784	0.43
478.8857422	0.20
480.7388916	0.39
485.0260010	0.82
499.1166382	6.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.838089	0.54
108.9958878	0.79
121.0128479	2.13
123.0407867	0.45
124.9667435	0.19
130.9229584	1.16
135.0584259	1.62
135.9255066	0.30
137.1454468	0.41
144.9766846	0.15
147.028595	0.37
149.2808228	0.66
151.3458099	0.19
152.4516907	0.15
156.8711243	0.62
159.06604	1.55
160.995636	0.77
163.0975342	0.60
164.748291	0.82
170.9694061	0.40
172.9914856	1.34
174.4404144	0.31
175.3144531	1.31
181.109375	0.29
183.1505737	1.45
185.1434174	0.29
188.0543518	0.18
189.0898132	0.66
191.2289886	0.26
193.1912537	1.35
194.9279175	0.17
196.9875183	0.50
199.0164032	0.39
201.0181885	0.41
203.057373	0.76
205.1032715	0.15
207.0987396	0.87
209.0584106	0.76
211.0816345	1.48
212.2355347	0.32
213.2346802	1.02
215.0847778	0.97
217.197937	2.44
218.8650513	0.83
223.481781	0.35
224.3144531	0.20
225.1852417	0.87
227.1665344	0.16
229.1597595	0.70
231.2267456	1.51
234.8579102	0.27
241.0739441	1.27
245.4228821	1.02
247.3492432	4.81
249.0865479	1.15
250.631012	0.52
252.9836426	0.32
254.8319702	0.41
257.0007324	0.39
259.3323364	0.31
260.1675415	1.32
260.9351501	0.09
267.3630371	0.58
269.052063	0.18
271.2980652	0.38
275.2337952	0.47
276.503479	0.15
281.3276367	0.29
284.987854	0.28
290.9505005	0.16
294.4678345	0.66
295.2962646	0.58
298.7373657	0.33
299.4793091	0.92
303.0916748	0.45
305.3411865	6.57
317.0080872	0.35
319.0520935	0.86
323.2384644	100.00
324.3569336	0.58
331.8864136	0.99
341.23526	2.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.276
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
144.8061676	0.17
149.3117523	0.11
154.7889709	0.05
161.1988983	0.09
162.7536621	0.05
166.9565887	0.17
173.0462036	0.08
176.7656555	0.09
185.2320251	0.17
191.1965942	0.21
197.8621826	0.07
205.4298553	0.09
216.2397308	0.05
219.1936188	0.34
225.4003296	0.12
235.2451172	0.05
243.2316132	1.65
245.2049408	0.05
252.7530518	0.05
261.1838379	5.22
277.2043762	0.06
281.2283325	0.04
304.3098145	0.93
317.4907532	0.74
319.0979004	0.19
331.2601318	0.13
333.0696411	0.09
335.3595581	53.09
336.1254272	0.12
362.3150635	0.08
375.5669250	0.17
378.5489197	0.29
414.7019043	0.20
415.3125000	6.87
426.8753357	0.06
429.5323181	0.14
433.1806335	1.09
440.8323669	0.13
445.6093140	0.18
458.2759094	100.00
459.1939697	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	566.1572
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0016632	0.22
211.2636719	0.04
220.6513367	0.02
221.9203491	0.18
223.1347656	1.83
224.1636200	0.15
241.1089630	0.02
322.6313477	0.05
323.2531128	0.82
340.9110107	0.03
379.0861206	0.06
383.3356323	0.05
384.8258667	0.03
386.3640747	0.04
403.0159302	0.14
404.1007690	0.09
434.3050537	0.05
475.1410522	0.05
503.2470703	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.315
Annotation	PS(19:0/0:0)
Peak:m/z	Relative Intensity
153.0188293	0.02
185.0085297	0.04
202.9174194	0.02
242.2205963	0.04
253.2701721	0.54
257.9158630	0.04
258.9869995	0.02
260.1339111	0.01
273.8825073	0.02
281.6703491	0.19
284.2042847	0.01
323.0564575	0.02
348.0939941	0.04
363.3311768	0.03
379.0209961	0.03
389.1143188	0.01
394.1854248	0.02
406.2866821	0.05
407.0855103	0.06
412.4271240	0.02
421.0717163	0.06
436.1356812	0.01
439.4860840	0.10
442.4247437	0.04
446.5398560	0.04
448.5932617	0.01
450.0831909	0.09
464.1162109	0.04
466.2415161	0.03
476.4071045	0.04
478.3388062	100.00
479.4125366	0.22
482.2314453	0.08
490.2471313	0.06
491.4938354	0.15
493.6771240	0.01
495.0556030	0.09
500.1415405	0.28
502.0761719	1.07
519.6655273	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	202.072
Annotation	7a-Epialexaflorine
Peak:m/z	Relative Intensity
58.9720230	0.39
69.9973297	0.75
70.9334564	0.93
72.0452957	0.97
86.8990479	64.57
87.9076157	12.21
95.9090424	0.15
96.9591217	0.48
113.9034271	100.00
114.8846741	20.20
132.0180206	6.97
140.1152191	6.12
143.5986786	0.33
145.9117889	0.11
154.3961639	0.23
158.0449982	97.85
169.8337402	0.26
173.9037933	0.23
183.9875641	92.46
184.8061066	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.18
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9956970	0.74
177.1537781	0.14
188.8270264	0.04
190.7200623	0.16
207.0084686	0.10
209.0179749	100.00
341.4014282	0.07
503.2243042	0.19
504.2871094	0.33
505.2461548	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	272.0871
Annotation	Unknow
Peak:m/z	Relative Intensity
83.1031876	0.13
92.9571228	0.24
95.0422516	0.17
98.1607208	0.03
100.0114746	0.04
110.0110779	7.63
112.1225281	0.10
122.0892639	0.05
123.0244293	0.09
123.7535553	0.19
128.0995178	0.19
130.0661774	0.21
137.8879242	1.05
145.2101746	0.08
146.0511322	0.09
147.9020233	0.19
156.0062714	82.21
162.8590546	0.15
164.0411530	0.06
166.2833862	0.07
192.1979675	0.19
193.0858765	0.08
198.3289948	0.14
207.9234161	0.89
210.2951813	0.22
212.2084961	0.22
214.9885712	0.10
223.8907623	0.26
226.0395203	70.87
236.1325684	2.84
242.1581421	0.43
244.2043915	0.10
254.0578766	100.00
254.7807007	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.28
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
170.8162537	0.02
196.028717	0.26
197.2078552	0.03
202.1120605	0.05
214.09021	1.49
229.2658997	0.03
235.0676575	0.03
239.0693054	0.03
242.1994019	0.03
251.3363647	0.14
261.3778992	0.15
277.4451904	0.05
279.2355957	100.00
279.8497009	0.34
288.8102417	0.03
303.2358398	0.05
314.0446472	0.01
319.0455322	0.04
320.1683044	0.02
348.9615479	0.01
360.2727051	0.04
363.2159424	0.04
378.2868958	0.03
404.2619934	0.08
415.3466492	0.02
416.5125427	0.04
417.2336731	0.06
428.9631653	0.06
431.4047546	0.14
432.2546692	0.06
434.144928	0.06
437.0949402	0.04
439.8656311	0.28
440.5444641	0.07
446.2027588	0.02
457.7689514	0.28
459.0995178	0.07
460.4307556	0.07
461.1772461	0.03
462.2375793	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1346
Annotation	Grevilloside C
Peak:m/z	Relative Intensity
111.0085297	0.10
113.0695953	0.44
118.9094696	0.30
128.7930298	0.19
131.0137787	0.14
142.9405823	0.36
148.2503052	0.07
149.0050049	0.08
157.1570435	0.10
158.7217102	0.09
161.0484314	1.94
163.3221741	0.13
164.1238403	0.06
174.3899231	0.26
176.2364807	0.16
177.0088196	0.77
178.1248016	1.11
178.9885864	3.45
180.2102051	0.61
183.1122437	0.18
185.1243134	0.14
186.8736267	0.26
188.8014221	0.14
191.1144257	0.57
192.1036377	0.53
193.1453857	2.02
194.1076508	12.96
195.1534424	0.94
203.1537476	0.06
205.1174469	0.12
206.4677734	0.34
207.2630005	1.35
208.1335754	3.72
209.0794983	100.00
210.1099548	8.59
213.5005646	0.09
217.1704102	1.25
218.9955444	0.05
221.1523132	0.44
222.1134338	0.26
222.9885559	0.16
229.1433716	0.38
230.244812	0.06
231.283905	0.03
233.0115051	0.46
233.9503479	0.05
236.1289978	1.90
237.1940918	0.11
239.4788208	0.07
245.3640137	0.31
248.1817627	0.19
249.1306458	2.56
251.1129456	6.02
253.1392822	0.06
255.3408508	0.05
260.9258423	0.04
263.1212463	1.78
272.1013184	0.16
275.2647705	0.11
281.0581055	0.24
282.9197693	0.26
289.1347656	0.05
292.9580383	0.40
295.0256042	0.08
296.5367432	0.08
297.4441528	0.06
305.2788696	0.15
307.1856384	0.51
309.1794739	0.10
311.0626831	0.91
323.3544312	0.06
324.252594	0.05
325.2418213	0.74
326.395874	0.11
327.1372681	0.24
330.0956726	10.21
333.0548706	0.08
335.0870667	3.77
339.2326965	0.63
353.0758972	0.66
354.1000671	0.09
356.4128723	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8879700	5.30
115.9636078	1.50
130.9114685	0.12
133.2209473	0.03
158.9523621	100.00
159.9381714	34.73
198.9343567	1.35
200.0118103	1.11
201.8630981	0.05
216.9909363	0.51
217.9503174	0.66
228.9155579	18.71
229.9721375	16.67
245.0595703	0.29
246.0167847	0.14
248.0731506	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.91
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9000549	0.05
272.9546509	1.25
274.2173767	0.07
359.2452393	0.04
387.0455933	0.25
388.9276123	0.09
405.1864014	0.06
426.9558716	3.44
428.0775757	2.07
454.0520020	0.08
456.9761963	0.28
458.0691528	0.12
472.3306885	0.51
472.9461670	2.36
473.8989868	2.65
483.8885498	0.07
497.9439087	0.07
501.9856567	0.05
503.0100708	0.23
503.9143677	0.08
512.6477661	0.20
513.7489014	0.15
515.0416870	0.31
530.9259644	0.28
540.8686523	100.00
541.8347168	58.20
542.9169312	0.17
543.8833618	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1967
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
241.0169067	0.21
242.6563568	0.51
243.3113251	0.37
245.0836029	1.16
252.6665344	0.30
254.1078186	0.13
255.1258240	0.58
256.1602783	0.20
258.8951721	0.10
261.0673828	0.94
269.1914062	0.75
271.2152710	0.33
273.0292358	0.18
274.2601929	0.22
280.9042969	0.07
283.0222778	0.60
285.1223755	0.83
287.1441650	21.36
289.1681213	4.52
295.2848511	0.20
296.2003784	0.39
297.1035156	0.52
299.1914062	4.34
303.1319580	0.12
309.4252319	0.19
311.3195190	0.20
319.3380127	0.29
321.1517029	0.46
327.4034424	0.18
328.1177979	0.19
329.0798950	0.61
331.0920105	0.54
335.1981812	0.38
337.1583557	0.59
341.3291626	0.63
345.3381653	0.24
353.1804199	0.15
360.1527710	0.32
361.3284912	0.18
363.2138977	4.19
365.0966797	0.90
369.3227539	0.47
371.1032104	0.58
375.0216675	0.17
377.1835632	0.12
378.1180420	0.12
379.1416016	0.47
381.3063354	2.15
383.3626709	1.19
387.1907349	1.63
391.1197510	0.16
395.2050781	3.02
397.1119995	0.40
405.1735840	11.16
407.1856079	32.08
409.1468506	0.77
411.3096924	0.45
413.1632690	8.80
417.2485352	1.54
423.2786255	7.14
425.1924438	30.21
427.4871826	0.23
431.1306152	0.29
435.2335205	2.96
436.0701904	0.14
437.1562500	1.01
445.5095825	0.34
447.1943970	0.88
449.1966553	18.68
451.1448364	18.88
452.1225586	0.11
453.0510254	0.34
464.3616943	0.45
467.2976685	1.58
469.2277222	0.13
473.3301392	0.14
475.0546265	0.23
477.1955566	0.20
484.7929688	0.19
489.1376953	0.15
493.1881104	0.31
501.0781860	0.10
515.2753296	1.21
517.1464844	0.85
519.3978271	0.21
525.0630493	3.24
531.1819458	2.46
533.1226807	7.35
533.8511963	0.25
535.2974243	1.94
543.1173096	19.27
545.0794067	0.40
545.7501831	0.17
557.2760010	5.62
559.1085205	5.79
561.2117920	4.32
569.3339233	5.39
573.3604126	0.11
575.1344604	34.54
577.1782837	57.76
578.0000000	1.00
585.3770752	0.93
587.2597046	20.13
599.0532227	0.31
616.2470703	0.15
617.3546753	0.98
619.2717285	4.18
629.3755493	2.25
651.2002563	1.35
656.7851562	0.18
667.2960815	0.11
669.3278198	1.51
677.1926880	4.32
679.1076050	0.36
681.2553711	0.58
683.1591797	0.28
693.8427734	0.45
695.1729126	100.00
695.8505249	0.45
697.3175049	0.10
702.3687134	0.50
703.2529907	0.88
709.4711304	0.11
711.0751343	1.19
713.1975098	39.32
715.0321655	0.57
719.3271484	1.77
720.3152466	0.68
721.1840210	0.88
724.9865112	0.17
725.6872559	0.37
737.4553223	1.02
738.6517944	3.76
739.2597656	41.97
743.8987427	0.36
755.1637573	1.13
778.9622192	0.69
780.0058594	0.90
781.3909302	0.39
788.2348633	0.09
797.1982422	0.39
801.2033081	1.13
802.4039917	0.35
803.3889771	0.12
808.1283569	0.12
821.4136353	1.98
829.1782227	0.91
846.7365112	8.33
847.3558350	15.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.31
Annotation	Unknow
Peak:m/z	Relative Intensity
181.0231781	0.01
235.3018188	0.08
236.1101227	0.06
237.2577972	0.03
253.2436981	0.05
254.2076721	0.07
255.1312561	0.19
269.9528809	0.02
277.2758789	1.94
278.3006592	1.65
279.3549805	1.06
280.4550171	0.09
345.1083984	0.03
413.0291748	0.07
431.6216431	0.09
449.5938110	0.01
502.3329468	100.00
503.2977905	0.17
507.9124146	0.05
513.3517456	0.35
514.3471069	0.16
515.1301880	4.64
516.2554321	0.32
525.3110352	0.13
544.0703735	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	909.486
Annotation	Ardisiamamilloside H
Peak:m/z	Relative Intensity
289.0974731	0.22
391.4524231	0.14
438.5558472	0.72
521.6597900	0.08
575.3169556	0.21
667.9025879	0.07
669.6862183	0.14
703.3391724	1.61
714.0684814	0.23
721.4604492	18.92
745.4756470	0.05
750.1693726	0.08
763.1554565	2.00
792.5704956	0.17
805.4646606	0.20
813.1146851	0.20
831.1256714	0.56
848.6721802	1.22
849.3352661	14.49
855.3910522	0.25
867.4251709	100.00
868.0920410	0.28
889.8856812	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.13
Annotation	Glu Val
Peak:m/z	Relative Intensity
65.66184235	0.38
83.02945709	0.41
118.8729095	0.12
121.0246277	1.56
121.9494781	0.09
133.1623993	0.38
134.9919281	0.60
136.7968597	0.39
137.457489	0.25
141.0388336	0.25
143.1545715	0.38
144.2404785	0.12
145.0909729	1.02
147.0522919	1.83
149.1629944	1.32
150.2181244	0.39
153.0305328	0.88
156.9098816	1.21
158.9929352	0.52
160.0760651	0.61
161.0311127	0.26
163.0517426	3.54
165.0141449	0.21
169.1956635	0.20
172.0619659	0.17
173.1936188	1.24
175.1139526	0.09
183.0888672	2.58
185.010437	1.11
187.1380615	14.48
189.1858673	0.70
190.974823	11.02
191.5856781	0.04
201.1152802	9.44
203.2287445	4.96
204.99617	1.36
209.2098846	0.19
211.0585175	5.30
212.0109711	0.09
219.0551605	1.15
225.4841461	0.79
229.1082153	100.00
229.9273224	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.1505
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9162598	0.12
131.0229187	0.25
140.9093018	0.09
142.9548950	1.45
151.0054321	0.09
159.0930786	0.44
161.0330963	2.36
167.0015869	0.24
171.0039368	0.07
179.1134644	0.90
183.0275879	0.55
184.9509888	0.14
189.0148621	0.18
199.8193054	0.15
203.1640320	0.13
212.9660339	0.21
215.0067596	0.13
231.0443420	0.14
233.0122681	0.12
242.1064758	0.12
243.1441345	0.21
244.8293457	0.67
247.1425476	0.19
248.7362366	0.60
257.8927307	0.17
274.9805298	0.09
278.9855957	0.08
285.0472412	0.16
300.1104126	0.10
305.0498352	0.14
313.2770081	0.12
321.1114502	0.13
321.9501343	0.28
323.0986938	48.40
327.2024841	0.43
329.3339233	0.34
331.1893921	0.31
341.1560059	100.00
347.1277161	0.25
363.1133728	0.07
365.1872864	4.33
375.2355652	0.31
384.3426819	0.19
393.0907288	0.88
394.3207703	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.17
Annotation	Piperacillin
Peak:m/z	Relative Intensity
161.9882202	100.00
162.6283875	0.25
181.2645111	0.98
208.9518890	0.69
228.2730713	0.68
273.9083862	0.39
318.1921387	0.82
323.9365234	0.24
338.1841431	2.41
339.3445435	0.50
341.1042480	0.54
349.3475952	0.71
355.2991943	0.60
363.2198486	7.95
372.3219604	0.14
402.2630615	0.16
416.6092529	0.68
419.1482544	2.31
420.0117188	4.00
440.2857666	3.09
471.7354126	0.65
499.5150146	0.96
500.1555786	1.00
509.8390503	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.12
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
71.90325928	1.03
89.90710449	21.67
98.15649414	0.18
115.9455414	1.91
122.0785828	0.33
130.8869171	0.82
133.9319763	0.12
141.8427429	0.15
145.7496338	0.37
149.9737091	0.29
157.1044922	0.70
160.8439484	0.43
162.1030121	0.43
163.0491333	0.29
166.099884	2.90
172.0344543	0.87
174.0821075	4.13
176.1552887	0.40
179.1629791	1.05
184.1127625	26.97
184.8500671	0.14
189.0980072	0.23
192.2989349	0.37
199.0493469	0.75
199.7800903	0.22
202.1035919	100.00
202.9456024	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1221
Annotation	Marein
Peak:m/z	Relative Intensity
144.9197693	0.52
188.2344971	0.54
205.1334229	3.40
206.1558228	2.20
222.0198975	0.29
243.1628113	1.24
255.9280701	0.83
270.9746094	37.52
289.0715637	100.00
298.2144775	0.54
300.9891968	0.33
313.1673889	3.74
328.7576904	0.86
330.9119873	14.02
341.4459229	1.59
355.1887207	2.90
369.6601868	6.39
370.271637	3.68
387.0310974	0.74
388.4859314	1.00
392.4797668	0.97
397.200592	0.22
401.2254028	0.55
405.2600098	1.13
406.032135	0.60
407.469635	0.83
410.1087952	2.22
415.0558167	10.63
416.2307434	0.75
432.6109619	14.43
433.2236328	12.09
441.7217712	3.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.2935
Annotation	1-heptadecanoyl-glycero-3-phosphoethanolamine
Peak:m/z	Relative Intensity
184.1623383	0.55
187.1089172	0.59
196.0015564	2.06
213.076355	0.14
214.0992126	1.20
269.2428589	100.00
269.8447571	0.63
270.5005798	0.33
301.2184448	0.13
314.5529175	0.14
318.2925415	0.39
329.1896973	0.16
339.3502197	0.47
376.2157898	0.27
381.322937	0.19
387.1694031	0.19
392.6436157	0.11
395.5376587	0.14
405.4295044	0.14
420.0868835	1.15
421.060791	0.36
422.5055237	0.91
423.2429199	0.86
424.216217	0.42
430.0635071	0.39
436.2697449	0.17
439.2206116	0.19
440.8123474	0.08
447.6166687	1.20
448.4055481	4.56
449.3688965	34.09
450.2920532	1.03
451.4302368	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	748.2051
Annotation	Unknow
Peak:m/z	Relative Intensity
297.2581482	0.05
321.2537231	0.19
339.6629333	0.07
350.8580322	0.05
353.2065430	0.07
377.1996460	0.63
387.4114380	0.19
395.1539307	0.29
399.7467041	0.15
404.3252563	0.14
405.1815186	1.68
408.9932251	0.27
411.2754517	0.09
418.1532593	0.20
421.0436401	0.55
423.1138916	18.28
440.1420898	48.95
441.6709595	0.03
452.1045532	0.47
474.1872559	0.18
482.2196655	1.47
504.0030518	0.27
506.1262207	1.81
512.2686768	0.10
514.1318970	0.47
518.3845215	0.64
524.1176147	0.10
530.2197876	0.15
532.1940308	18.22
533.2476196	0.22
536.4811401	0.13
539.9286499	0.10
548.1361084	3.76
550.2752075	44.11
562.2565308	0.58
566.1994629	7.76
568.1127930	9.85
569.0775757	0.41
574.5323486	0.05
584.2846069	3.50
586.3235474	10.99
596.0377808	0.28
602.0993652	100.00
602.7529907	0.19
606.9701538	0.48
608.3434448	0.11
628.8604736	0.06
643.7897949	0.46
644.4200439	0.17
650.2145386	0.08
658.3529663	0.12
659.8518677	0.36
668.0668945	0.04
676.5357056	0.26
694.1908569	9.46
711.4002686	0.38
712.1483154	3.90
712.7556763	0.02
730.0765991	6.80
730.7053833	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1452
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
173.0093689	0.15
174.9533691	0.09
176.9737244	0.08
178.9899902	2.45
180.1269989	0.22
182.0776520	0.07
184.0268555	0.13
184.9097443	0.05
187.0926666	0.11
189.2373047	0.06
189.9262695	0.26
191.0367584	0.34
192.0416565	0.06
193.0172119	0.53
196.2398682	0.11
197.1207733	0.08
197.7918396	0.12
200.3062592	0.05
201.2047119	0.02
201.9272308	0.11
202.9520874	0.25
204.1644592	0.13
205.0113831	0.06
207.0653381	0.13
208.9431152	0.09
211.1035767	0.16
211.9906921	0.11
213.1342773	0.26
214.0948944	0.27
215.0267181	0.10
216.1970367	0.07
217.1875916	0.41
218.2451477	0.10
219.2217712	0.04
220.6890564	0.16
222.1289062	0.05
226.5298157	0.37
227.2181091	0.64
228.2597656	0.42
229.0617065	0.56
231.3168335	0.18
232.2341309	0.05
233.0407410	0.03
234.8923340	0.03
237.2223206	0.09
239.0862274	0.04
241.2166595	0.06
242.3934021	0.38
243.2092133	0.20
244.3121643	0.13
245.1684113	0.22
247.1861420	0.09
250.9496460	0.13
254.3014069	0.41
255.0342712	5.04
256.1320801	1.62
257.0377197	0.79
258.0793152	0.05
259.2387695	0.15
264.2227173	0.08
266.2674561	0.04
267.2191467	0.09
268.7992249	0.11
271.1063843	8.93
272.1137085	2.04
273.0386353	1.41
274.1490173	0.50
275.0331116	0.33
279.0706177	0.16
281.9428711	0.08
283.0785217	0.77
285.2781372	0.27
289.2729492	0.10
291.2506104	0.03
296.0503540	0.17
297.1306152	1.84
298.0130615	0.02
300.0693054	55.40
301.0709534	100.00
302.0495605	14.12
303.3588257	0.22
304.4028931	0.06
305.3595581	0.03
307.1663818	0.18
311.3863831	0.13
313.1862793	1.00
314.0573120	0.26
315.1976929	0.09
323.2249146	0.03
325.2286987	0.50
326.0886841	0.10
330.2473145	0.07
337.1962891	0.09
338.2876587	0.06
341.0735474	0.15
343.1213379	12.82
344.1666260	1.08
349.3214722	0.06
353.3314819	0.05
355.2742920	0.87
356.0124512	0.04
367.2337036	0.32
372.1312256	0.17
373.2167969	1.92
374.0930176	0.10
381.2133789	0.14
385.3493042	0.24
386.3024902	0.12
403.0874634	0.05
409.3272705	0.09
410.3381958	0.08
417.2720947	0.22
420.1204224	0.02
421.3241577	0.16
427.2124023	0.21
428.7760620	0.03
429.4364624	0.07
439.5441284	0.06
445.2180786	1.01
446.6468506	0.14
447.2731934	0.14
448.1372070	0.05
453.6783447	0.04
455.4221802	0.17
457.1208496	0.23
461.3002930	0.07
463.2699585	1.12
464.3289795	0.48
465.1914062	0.27
473.3681030	0.13
481.3104248	0.10
483.0689697	0.06
493.9470825	0.03
495.2100220	0.04
500.2131958	0.25
501.0775757	0.04
505.0765381	0.12
523.2592773	0.11
527.1923218	0.04
529.2842407	0.07
531.3779297	0.18
541.0876465	0.09
547.4737549	0.05
549.3300781	0.09
549.9362183	0.04
564.0809326	0.16
565.2847900	0.12
567.0079346	0.04
573.4644165	0.09
581.0325317	0.07
591.2947388	3.44
592.2788086	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0763
Annotation	Glutathione
Peak:m/z	Relative Intensity
99.0699310	0.16
113.1712570	0.23
116.1600189	0.10
125.0941696	0.05
127.4414597	1.05
128.0516510	7.95
143.0681610	10.34
145.0892029	0.40
146.1030426	0.11
153.0833130	0.18
159.9449768	9.03
166.0816650	0.18
166.9782562	0.20
169.1082458	0.15
170.0907288	0.11
171.0843506	0.46
177.0856018	8.22
179.0921936	10.89
185.1165466	1.26
192.1412354	0.20
193.2102203	0.19
197.1502686	0.77
203.1896973	0.11
204.2199402	0.23
210.0606079	2.91
213.0502625	1.27
215.9100037	0.37
217.0865479	0.22
224.1740723	0.16
228.1398010	0.61
230.1010132	0.12
231.0792236	0.59
236.4082031	0.06
242.1657104	2.12
244.3188171	0.10
245.2075500	0.08
246.1670532	0.20
249.3895874	0.09
254.0740051	86.06
260.3245239	0.17
262.1701050	0.31
263.1838379	0.07
269.9035339	0.12
272.1951904	100.00
276.2638245	0.09
278.1495361	0.19
288.1457214	71.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.075
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0072174	0.04
171.8162842	0.07
172.9950867	0.09
190.9783173	0.11
197.1151886	0.07
210.1454315	0.15
217.8348694	0.10
220.0485687	1.84
221.8864136	0.18
223.3710022	0.05
227.1542511	0.18
229.3020020	0.04
248.7849731	0.09
254.4243774	0.12
262.7982483	0.10
263.9685974	8.60
265.0078125	0.33
266.2377319	0.16
266.9815063	0.08
268.0079346	0.13
273.0405273	0.06
280.8768311	0.19
282.0137939	0.08
290.1132202	0.14
291.2111206	0.39
298.2215576	0.12
309.2402344	0.05
314.2864990	0.05
331.1793823	0.34
339.3530273	0.09
341.3485107	0.52
345.0695496	0.03
365.8749695	0.19
375.0514832	0.03
383.0793762	100.00
383.7154541	0.88
385.1089478	17.87
385.8879700	0.12
388.1961060	0.05
392.9822998	0.32
400.2576294	0.99
401.0251465	6.94
411.2600708	0.53
412.6051636	0.04
428.7027588	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2779
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
139.7979584	0.06
153.1094818	0.11
177.1910706	0.04
195.9903412	2.00
198.9621124	0.02
214.1558228	1.64
255.2239685	100.00
255.8803101	0.26
324.1703796	0.08
391.2301941	0.35
406.1300354	0.04
409.2711487	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.9
Annotation	Unknow
Peak:m/z	Relative Intensity
190.0196533	0.04
199.0774536	0.07
230.0267181	0.05
232.0446625	0.02
272.9727783	5.05
274.0139771	2.01
275.0309448	3.30
276.0451050	0.41
386.9512939	7.98
387.9522095	6.67
388.9336548	15.64
389.9879150	4.53
427.3235474	0.10
486.7638550	0.03
489.2291870	0.04
500.9440918	18.77
501.9179688	24.75
502.9258423	100.00
503.8976440	38.72
504.5056763	0.10
514.8864746	0.02
570.8334961	0.12
571.7394409	1.09
574.0053711	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	947.2361
Annotation	Unknow
Peak:m/z	Relative Intensity
572.3665771	0.13
625.1062012	0.29
673.1000366	0.18
735.2866821	0.20
818.1198120	0.12
899.0895996	0.05
900.3997192	1.13
902.5663452	0.50
911.2294312	100.00
928.6877441	0.12
950.7907715	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.13
Annotation	Galactotriose
Peak:m/z	Relative Intensity
162.8129578	0.20
219.1905518	0.17
281.0108643	0.04
281.9987793	0.06
290.3067322	0.91
291.0897217	0.08
295.9538269	0.22
318.8688965	0.14
323.0525513	0.14
325.0726318	0.09
326.4454956	0.16
332.1647339	0.21
363.1034546	8.04
368.0818481	0.12
370.2759399	0.74
371.2947388	4.22
372.3144531	1.22
381.1024170	100.00
382.2396240	0.30
390.9271851	0.14
396.9473267	0.08
398.8274536	0.28
399.4806519	0.13
410.4061279	0.31
452.2792969	0.96
458.8970947	0.34
487.1314087	0.20
488.5175171	0.10
502.2150269	0.35
519.0606079	0.34
520.0519409	0.07
524.1138306	0.33
552.8856812	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.3942
Annotation	Unknow
Peak:m/z	Relative Intensity
125.2149887	0.52
136.9619141	0.39
154.1040192	30.52
171.1601257	93.14
234.2465820	0.70
251.3449707	2.10
265.0851135	1.04
280.1553040	1.96
292.1788940	0.47
301.2810364	0.73
333.4240723	1.74
334.4503784	0.57
368.4018860	1.02
382.6030579	0.63
383.4022827	0.57
394.1112976	3.42
398.9527893	0.78
400.3386536	1.68
401.4018555	0.70
417.5224915	10.49
418.4801636	100.00
435.4433899	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.2167
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9060211	5.75
162.7663269	6.78
163.4747009	0.16
178.9401245	0.31
180.6334381	1.01
198.8851624	0.27
204.0055695	0.20
210.7437134	0.20
245.5937042	0.22
246.9216309	0.97
253.2622070	2.00
258.5542603	6.02
259.1797791	0.16
271.0604553	0.64
276.2087402	1.10
277.0469360	0.40
284.3894043	0.77
285.8690186	0.59
288.8243103	15.94
289.4326477	0.17
292.0188904	1.03
293.2155151	4.24
294.0325928	62.38
306.8445129	5.73
311.8088379	100.00
312.5014954	0.16
324.3182983	4.02
324.9510498	28.07
342.8574524	4.82
454.8568115	0.14
456.2793884	2.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.11
Annotation	Phenylalanyl-Aspartate
Peak:m/z	Relative Intensity
87.8870773	0.19
93.8334961	0.13
120.0196228	0.90
122.8956680	0.05
127.0018997	0.39
149.3553467	0.06
162.0634155	0.12
163.0287018	0.21
165.9685059	9.87
174.9311371	0.14
181.8990784	0.29
187.1138916	0.09
189.8216095	0.32
192.8890839	0.45
194.9626465	0.21
197.1763306	0.15
199.2061157	0.19
200.0948792	0.17
203.1355591	0.04
205.8854980	0.17
206.9496155	0.24
214.0784302	0.57
216.9068298	0.16
217.7403564	0.23
219.2317505	0.15
221.0184326	2.21
222.0452881	0.52
223.3922729	0.06
228.1289978	0.34
229.8810120	0.32
232.7847595	0.23
233.4361877	0.14
235.0685730	67.92
236.1889343	0.77
239.3605957	0.23
240.1604004	0.38
245.1125488	11.04
246.1085815	13.06
249.0576782	0.30
251.0128784	0.06
252.6692200	0.69
253.3180542	0.57
257.1376648	0.09
261.1604309	3.31
262.9877014	100.00
263.9545288	2.82
265.0267029	0.24
271.4589844	0.06
272.1612549	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	424.2469
Annotation	PC(11:0/0:0)
Peak:m/z	Relative Intensity
139.9617004	0.34
162.9557190	0.05
177.9469147	0.04
193.9803772	0.01
196.1294403	3.23
214.1596527	1.56
227.1800537	100.00
257.2275391	0.04
267.0991211	0.04
271.2497864	0.14
281.4692993	0.04
297.0922546	0.08
308.1030273	0.03
344.4684753	0.08
351.1470032	0.02
360.3430786	0.01
361.3398132	0.03
363.1946106	0.76
366.3524475	0.10
373.1440735	0.03
378.2931519	0.06
379.1823425	0.06
380.2599792	0.20
381.0251770	0.03
386.2737427	0.15
387.0407410	0.03
388.1529541	0.13
389.6001892	0.02
392.1730957	0.08
405.3037415	0.10
406.4559631	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.809021	0.07
100.9857635	0.32
103.0231934	0.23
121.0784149	0.31
123.1282043	0.47
128.9286652	0.71
134.8842163	0.31
137.9738159	0.15
138.6105957	0.10
140.8445282	0.23
143.9454803	0.18
146.0007172	0.84
150.8890686	11.25
151.8930206	4.34
152.7922516	0.07
154.2569122	0.16
155.1625824	0.61
157.2703705	0.27
161.888031	0.52
167.0602722	1.02
168.0195618	0.28
168.9988861	0.56
169.6403656	0.06
170.7691803	0.07
172.2342834	0.22
174.8256989	0.18
175.4493103	0.15
176.1339874	0.07
179.0684509	1.04
185.1943817	1.58
186.2995605	0.18
190.008667	0.19
191.339798	0.72
195.135849	0.12
197.124649	1.92
200.125824	0.32
205.9732666	4.58
211.1006622	0.12
216.8490143	0.18
217.5063324	0.33
218.1460419	2.17
219.2264709	0.14
225.2370148	1.42
226.1030121	0.56
236.0013275	12.00
237.0822754	0.27
238.1264038	1.98
239.0667725	1.00
245.1977539	0.78
253.0786743	100.00
254.1874847	8.02
255.2914276	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.2858
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0617676	0.04
156.7961273	0.16
170.0296936	0.04
175.0106659	2.21
176.1138611	0.09
187.1625977	0.03
189.1754761	0.18
193.1672058	0.65
194.1775818	0.13
202.2890625	0.04
205.1376343	1.10
206.0635071	0.09
207.1127777	0.03
213.1688080	0.02
219.7919922	0.03
223.0178680	0.56
224.2760010	0.03
231.0751495	4.55
232.0102234	0.71
233.2493134	0.41
234.2870178	0.05
249.0606537	30.57
250.0755615	2.21
250.6779327	0.01
259.4233398	0.46
261.3644714	0.04
267.1240234	35.78
268.1712036	3.05
275.2550659	0.37
277.2688599	100.00
278.2490234	16.59
280.2324829	0.07
293.0043945	0.07
318.2227783	0.04
331.2242432	0.07
347.0162964	0.06
348.0596924	0.04
355.4580078	0.08
360.4622803	0.08
373.2096558	0.10
379.3786621	0.08
383.4378052	0.05
385.3624268	0.15
409.4365234	0.03
426.2241821	0.04
439.2640381	0.05
450.2580566	0.04
451.4972534	0.11
452.4874268	0.13
453.6859741	0.09
464.3645630	0.05
467.3165283	2.20
468.3540039	0.81
477.2512817	0.04
486.1552124	0.03
490.6614380	0.24
491.3035278	1.14
492.5828247	0.07
509.2769775	24.12
510.4031372	6.18
513.5595703	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.8445702	18.04
69.8581543	1.56
71.9554138	0.50
96.8340149	0.25
111.9599762	5.32
112.9192047	0.98
114.0188751	3.30
114.9519043	1.09
115.9352264	44.01
130.0484924	33.44
133.0289154	1.24
138.7696381	0.06
140.0209198	5.23
141.0043793	0.07
144.6786499	0.09
153.4287567	0.22
157.0198517	79.13
157.9896393	100.00
158.6145630	0.22
175.6063232	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1059.3187
Annotation	Unknow
Peak:m/z	Relative Intensity
319.1863403	0.62
337.2323608	0.94
355.4753723	0.17
361.5792847	0.04
365.3049011	0.07
421.2680664	0.03
425.3216858	0.03
457.2795715	0.09
481.3020935	0.17
499.2643433	3.86
503.1759338	0.15
513.3166504	1.14
517.2498779	2.16
527.1466064	0.21
531.1502686	0.53
541.2696533	6.40
559.3061523	15.88
671.3720093	0.28
675.3154297	4.36
693.2912598	7.59
735.2617798	100.00
737.2568359	0.19
777.1349487	0.13
792.4321289	0.14
794.4060059	0.07
795.2835693	0.05
801.4813232	0.18
826.6391602	0.13
835.4401855	0.07
883.1560059	0.29
896.1885986	0.27
897.4465332	0.74
919.6033936	0.12
997.8447266	0.28
999.5977783	0.15
1000.7756350	0.12
1017.3847660	1.20
1041.4401860	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1
Annotation	Bidensyneoside C
Peak:m/z	Relative Intensity
130.8684082	0.11
160.8736267	0.09
168.5645752	0.04
171.2183533	0.08
173.1802368	0.03
179.0163879	0.39
183.7931824	0.07
187.0818481	0.08
197.0659332	0.09
198.0335999	0.03
207.4140625	0.03
215.1125031	0.59
221.0883789	0.13
229.7658997	0.06
230.8132935	0.11
235.1093750	0.03
236.1543274	0.08
239.2186584	0.06
244.2175903	0.04
249.2402954	0.16
256.7381287	0.16
258.9853210	0.25
263.4636536	0.16
265.3349304	0.05
267.0075073	0.11
279.5022583	0.17
281.2387085	0.08
283.1327820	0.05
287.2484741	0.11
288.4965210	0.07
297.2506104	0.11
300.1644287	0.09
307.3264160	0.21
308.4511719	0.10
314.9571533	0.05
320.4776001	0.06
322.5732422	0.06
330.0050354	0.05
331.2028198	1.35
332.3048401	0.34
334.1214600	0.05
335.4414062	0.17
341.2342529	100.00
343.1899414	0.15
344.4254150	0.35
345.3816223	0.11
347.2208862	0.13
358.4178772	0.19
359.2030945	0.67
360.1381531	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1507
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
167.1282349	0.04
169.0227509	0.20
170.4573517	0.11
171.0632324	0.07
172.2891998	0.06
173.1813507	0.05
174.2961731	0.05
175.1427460	0.06
177.0242615	0.18
177.9003754	0.05
178.9521179	1.13
180.0353241	0.13
180.8679047	0.03
182.2834320	0.06
183.0030823	0.08
184.1099548	0.14
185.0335693	0.45
186.9600677	0.47
188.0914154	0.18
189.3189240	0.04
192.0291595	0.13
193.1181641	0.41
195.0353241	0.84
195.6416779	0.05
196.2855835	0.16
197.2489777	0.16
197.8726807	0.06
199.2126160	0.16
200.3408813	0.03
201.0781555	0.19
202.0841675	0.17
202.9705353	0.23
205.0272827	0.23
206.1098022	0.11
207.2405396	0.26
208.3146973	0.04
209.0992432	0.12
210.1220398	0.09
211.0770721	0.92
212.1090698	0.31
213.1065674	1.12
214.1792908	0.08
215.0661926	0.13
217.1864319	0.23
218.1398010	0.20
219.2655640	0.07
221.2187347	0.12
223.0747833	0.13
224.1091003	0.05
225.9729309	0.07
227.0326691	1.73
228.1410828	0.67
229.1848297	2.12
230.2692413	0.30
231.0961304	0.20
232.1673889	0.11
233.2606506	0.04
237.2726288	0.09
238.4811249	0.19
239.1353912	1.05
240.1283264	0.88
241.1158447	1.73
242.0675659	0.31
243.1084290	0.34
244.9583435	0.09
247.2501068	0.02
251.1365051	0.10
253.1250610	0.10
255.0878296	11.62
256.0567017	2.02
257.1215210	7.38
258.1247559	0.99
259.0861206	0.20
261.4910889	0.05
265.1311035	0.06
267.0602722	1.24
268.0405579	0.28
269.0932312	1.56
270.0681152	0.10
271.1371460	0.45
271.8066406	0.06
274.9653015	0.02
276.8117065	0.17
277.9759216	0.05
279.1512146	0.08
281.1364746	0.06
282.0832520	0.07
283.1985474	5.14
284.0549622	43.71
285.0737305	100.00
286.0723572	14.61
287.0783081	0.69
295.1593018	0.05
297.1184082	0.34
298.1269531	1.06
299.1137085	2.08
300.1799927	0.44
301.3334351	0.11
306.1383362	0.06
307.1660767	0.54
309.2243958	0.20
311.3075562	0.12
313.1010437	0.36
314.1286011	0.16
321.9929199	0.05
323.0765991	0.10
325.0512695	0.10
327.0784912	21.25
328.1719360	3.26
329.2238770	0.26
330.1069946	0.05
336.9171753	0.05
339.1091309	1.05
341.2498779	0.14
342.3160400	0.05
348.8246460	0.03
351.1566162	0.31
357.1480103	5.27
358.1715088	0.57
359.0588379	0.06
365.5201416	0.21
367.3615723	0.17
369.2809448	0.44
370.0768433	0.14
375.1799316	0.04
381.3526611	0.09
383.0133057	0.03
387.3156738	0.07
393.1183472	0.78
394.2764282	0.25
395.3323975	0.03
411.2590942	0.18
412.4542236	0.03
421.9871826	0.07
429.1309204	0.14
430.0834351	0.08
431.2487793	0.19
432.2654419	0.17
439.5136108	0.12
440.9790039	0.05
443.4138184	0.13
447.1128540	2.29
448.1127930	0.39
450.4138794	0.07
455.2518921	0.17
457.3906250	0.18
459.9418335	0.04
461.4451294	0.14
462.1353149	0.04
467.2142334	0.08
476.3056641	0.12
498.1470337	0.04
501.3474731	0.07
503.4114990	0.28
504.8059692	0.06
506.5324097	0.10
510.0196533	0.07
513.3679199	0.02
522.0621338	0.24
525.4628906	0.03
531.2548218	0.12
533.7240601	0.03
534.9091797	0.07
547.4884644	0.22
548.4660034	0.37
549.2235718	0.25
550.1682739	0.33
557.3305054	0.64
563.3276978	0.05
565.2332764	1.77
566.1861572	0.24
567.6466064	0.09
575.2944946	0.29
576.3087158	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	697.364
Annotation	Unknow
Peak:m/z	Relative Intensity
235.0155945	0.01
253.1397400	0.22
287.2311096	0.06
305.3840332	0.10
314.1407471	0.04
355.4044189	0.04
396.6166992	0.28
397.2770996	7.22
415.1879272	1.19
426.4176636	0.07
444.3047485	0.09
445.3314209	0.05
450.5601196	0.12
524.1638184	0.06
619.6092529	0.04
651.2645264	100.00
651.9223633	0.28
653.8811646	0.07
661.3945923	0.06
678.4330444	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3124
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
161.1737671	0.07
179.1363373	0.06
235.1753998	1.80
253.1151886	11.82
253.7551575	0.04
259.0540161	0.10
274.9915771	0.07
277.2380371	100.00
277.8480835	0.38
397.5354004	0.19
424.2326050	0.07
429.3699951	0.04
438.1542969	0.08
457.3184814	0.02
473.4747925	0.07
481.0383301	0.03
513.0892944	99.62
513.7702637	0.61
524.4423218	0.03
541.5428467	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.31
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
184.1197815	0.08
197.9563904	0.42
215.9632111	0.32
273.0950317	0.43
308.4626465	0.40
339.2877197	100.00
339.9406738	0.68
407.4751282	0.13
419.4549561	0.28
431.0296021	0.11
462.2206726	7.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	979
Annotation	Unknow
Peak:m/z	Relative Intensity
305.2802124	0.84
414.9175415	1.71
476.1514282	0.55
477.8992310	0.23
618.2350464	0.53
763.9108276	0.68
914.1896973	0.28
1479.9891360	3.45
1480.6505130	3.05
1503.3607180	0.14
1522.6914060	1.65
1657.1519780	1.43
1687.5540770	0.38
1688.2712400	0.22
1689.5484620	9.57
1694.6387940	0.60
1696.4890140	0.50
1716.9796140	0.13
1722.9328610	0.10
1747.8348390	0.41
1752.4779050	2.11
1761.4606930	5.54
1770.7447510	0.21
1773.7620850	0.15
1780.7933350	0.17
1786.5416260	2.90
1788.0277100	0.18
1797.2838130	0.38
1801.5609130	0.21
1804.6947020	0.97
1807.2673340	0.48
1812.9337160	8.77
1816.3597410	2.62
1836.6174320	4.34
1854.1483150	2.62
1857.0172120	0.19
1868.4777830	0.59
1869.3840330	0.14
1873.4139400	0.61
1875.5225830	0.17
1880.4387210	12.74
1886.6413570	0.28
1891.4561770	2.58
1893.3826900	8.23
1894.5100100	0.24
1897.1605220	0.23
1899.6018070	0.11
1900.6804200	0.26
1905.5946040	15.81
1906.4847410	0.62
1907.1912840	1.03
1907.8690190	0.19
1908.6037600	0.20
1913.3059080	0.13
1916.0921630	0.22
1917.8927000	5.74
1919.8692630	0.96
1920.7525630	7.26
1924.8298340	0.45
1927.5782470	0.41
1929.3502200	0.13
1931.3238530	13.70
1932.6138920	13.17
1933.5661620	1.38
1937.7122800	0.53
1941.0853270	25.12
1942.4088130	0.27
1945.0211180	4.81
1946.1427000	55.42
1947.1242680	1.78
1949.1041260	35.69
1949.8907470	0.45
1951.2742920	1.12
1953.3109130	1.32
1955.4870610	24.62
1956.8809810	100.00
1957.6527100	20.19
1959.0236820	2.85
1960.3072510	1.64
1962.2579350	4.13
1963.1804200	0.36
1963.8171390	0.85
1964.8488770	7.90
1965.6146240	1.91
1968.1271970	1.45
1969.9260250	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	453.2711
Annotation	Sinapoylspermine
Peak:m/z	Relative Intensity
150.2396851	0.02
151.0241089	0.01
153.0589294	0.03
170.8852844	0.02
171.5635529	0.05
181.1289673	0.03
193.0744476	0.01
195.1191711	0.04
198.9282074	0.03
200.9785461	0.10
207.1422272	0.00
209.8908386	0.03
211.3090210	0.01
212.6316833	0.02
241.4592285	0.01
253.4058838	0.05
255.1622620	0.04
257.1449890	0.02
269.4767456	0.01
279.1106873	0.04
285.3032227	0.07
289.9626160	0.01
295.1921997	0.01
311.4985352	0.01
313.3894043	0.01
317.1144409	0.02
334.3867188	0.01
340.6456299	0.02
350.8634033	0.00
359.7125854	0.02
361.2464600	0.02
362.4837036	0.02
363.0960083	0.03
364.3764648	0.02
365.4546814	0.03
366.4574890	0.02
369.0598450	0.02
373.2811584	0.04
373.8934631	0.03
381.6955261	0.01
385.4313354	0.02
390.3917542	0.03
391.4651184	0.17
393.3065186	0.10
395.4142456	0.13
396.2461548	0.03
397.0564270	0.02
407.3405457	100.00
408.2328796	0.08
409.4161377	0.19
415.0112000	0.04
416.2604675	0.01
417.3037415	0.10
418.6174622	0.02
423.1280823	0.04
424.5555725	0.05
425.4179688	0.03
434.4183655	0.40
435.2035522	3.78
436.0984802	0.02
436.9676514	0.02
439.1913147	0.02
450.6960754	0.02
453.6573181	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.3123
Annotation	Unknow
Peak:m/z	Relative Intensity
166.7534485	0.06
235.1385803	1.00
243.8763428	0.25
244.8609009	0.09
246.0458984	0.08
253.2779236	49.49
255.2706299	0.15
260.4105835	0.31
271.5579834	0.12
287.0355225	0.14
303.0906372	0.05
307.3404541	0.06
309.3326416	0.06
317.6972656	0.19
338.2770996	0.09
343.3271484	0.28
351.2261963	0.17
372.9504395	0.04
375.0968018	0.18
404.0825195	0.13
434.2646484	0.17
443.9479370	0.12
449.4219360	0.33
454.2390747	0.36
455.4570923	0.13
461.1755981	0.13
462.3286743	0.36
473.4786377	0.07
475.3253174	0.08
476.6316528	0.16
483.0026245	0.07
489.1327515	100.00
489.7886963	1.42
491.0680542	0.79
491.6779175	0.06
496.2344360	0.47
497.3351440	0.34
498.2340698	0.49
499.1909790	1.20
500.2255859	0.30
516.6200562	0.30
517.2886353	1.05
518.2681885	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.91
Annotation	Unknow
Peak:m/z	Relative Intensity
111.1631927	1.50
114.0283737	0.42
128.9380798	0.44
133.0247498	0.30
135.1112366	0.52
136.8648071	0.40
156.1590271	0.35
166.9433594	1.74
169.1676636	1.55
177.0254669	0.86
183.0858612	0.28
189.1136475	0.44
200.8009949	1.03
206.8981934	1.15
211.1902466	0.82
212.1506653	0.74
218.5231018	0.20
221.0596619	0.16
222.8780518	4.24
226.1228943	0.60
230.3714905	0.58
236.8401489	6.74
237.9830627	0.28
239.0541992	2.10
241.8707275	100.00
243.0106201	0.38
247.3186035	11.44
248.2022095	1.56
253.1325073	0.18
253.9270020	2.11
254.7855835	1.44
256.0237427	0.74
259.4402466	8.11
260.3911438	1.66
261.9350281	19.82
262.8638000	12.42
265.0161133	28.16
266.2016602	2.09
269.2506714	4.40
269.8608398	0.51
270.8264771	6.21
271.9600830	1.00
273.5663147	1.99
282.9385681	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.1512
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9513397	0.12
161.0122681	0.46
179.0446167	1.35
246.1612244	0.08
289.9979858	0.37
308.1245728	0.74
318.9680176	0.07
341.1462402	100.00
372.1453247	0.09
424.2279053	0.41
452.1716614	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1818
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
151.2356720	0.06
153.1967621	0.09
160.9475708	0.04
162.9556580	6.62
165.0474854	0.09
179.0651245	0.19
205.0554199	0.07
214.8605347	0.08
225.1346741	1.14
227.1813354	0.05
230.7509155	0.01
233.2184448	0.10
234.5926514	1.86
235.3455811	0.02
252.6215515	0.24
255.2210999	0.05
264.2687988	0.71
264.9017334	2.95
269.0529175	0.09
271.3627625	0.12
276.8578186	0.10
278.5907593	0.22
281.1626282	0.22
288.9969788	0.22
294.9866943	0.31
305.7605286	0.12
307.1746826	1.72
313.1120911	1.68
318.8671875	0.16
322.8914185	0.07
324.8791504	4.16
325.5075378	0.02
341.2900696	0.55
342.2810974	0.21
344.9768982	0.06
346.2319946	0.06
355.5872192	0.13
374.2881470	0.09
379.1792603	0.19
383.4494934	0.05
385.2506409	0.04
386.7437744	0.59
387.3541565	0.09
389.1731567	0.06
391.2593689	0.16
397.2834167	0.23
401.6498718	0.06
406.7305603	0.19
429.0735779	100.00
429.7817993	0.36
431.2007751	0.51
437.0763550	0.52
438.8391418	0.44
440.2723694	0.14
446.2553406	0.09
448.0024109	0.06
453.2276001	0.11
455.3899231	0.06
456.3539734	0.10
457.0267639	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	376.2126
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1164246	0.14
188.3306122	0.11
190.3094635	0.07
196.9582520	0.10
219.1335449	0.53
220.8800354	0.03
228.3662720	0.07
243.3439941	0.06
249.1510620	0.13
260.4154968	0.24
270.4174805	0.06
277.9073486	0.52
279.0371094	0.12
280.1448975	0.13
284.1355591	0.05
289.1310730	0.05
292.2521362	0.14
295.9973450	0.06
298.3656616	0.12
300.2093811	3.74
303.0531616	0.12
314.5617676	0.28
315.2542114	0.07
316.2902832	0.41
317.9212341	0.09
321.2137756	0.08
326.3280334	1.25
327.2797241	0.06
328.0609741	0.27
330.3551025	0.16
331.0844727	0.04
332.2156982	15.39
332.9850464	0.21
334.1401672	0.04
338.0820923	0.04
340.0134277	0.36
340.9660645	0.17
342.1795654	0.11
344.2252808	100.00
344.8399048	0.23
349.2068176	0.40
358.2056274	2.89
359.4526672	0.16
362.0693359	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.07
Annotation	Deethylatrazine
Peak:m/z	Relative Intensity
72.7592316	0.10
118.1129456	0.13
142.1176300	0.57
144.0352478	10.16
145.9418182	100.00
160.1587524	0.80
170.0374298	3.24
170.9275665	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1
Annotation	Syringic acid beta-glucopyranosyl ester
Peak:m/z	Relative Intensity
123.17659	0.38
125.1331024	0.30
129.7866058	0.49
137.9941711	0.45
142.9074707	0.34
153.0722656	0.87
161.1138	0.13
166.7864227	0.14
179.2561646	0.21
182.0612488	1.67
194.9269257	0.36
195.6300659	0.30
197.0413055	100.00
199.7732239	0.11
203.1972809	0.13
205.1369934	0.37
210.3542633	0.09
212.4218292	0.53
224.1593628	0.17
229.2459106	0.16
239.2450867	0.88
267.0885315	0.20
268.9483643	0.35
274.8325806	0.43
280.8214111	0.35
285.9503784	0.22
287.0236511	0.27
291.2919922	0.28
298.339386	0.71
310.0606689	0.46
311.2952881	0.21
313.0777588	3.28
314.9325256	0.84
315.7480469	0.51
319.2660522	0.44
321.2070312	0.09
329.3120117	0.21
339.1120911	0.30
341.0653687	1.35
344.0673523	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0716
Annotation	Corynether A
Peak:m/z	Relative Intensity
83.06674194	0.07
84.94868469	0.03
92.88096619	0.02
94.12874603	0.01
97.00261688	0.33
98.89762878	0.06
106.7342987	0.09
109.0327759	1.17
110.0077515	0.20
120.4383392	0.09
121.0498581	0.14
122.9516754	0.96
124.8677521	3.33
126.0489349	0.37
127.9977341	0.01
131.9417419	0.03
133.1588593	0.03
135.1739197	0.65
136.4742432	0.44
137.1082458	3.00
138.0779724	0.34
139.0842133	0.59
139.9694214	0.07
143.1062012	0.15
144.9963531	0.10
146.1988068	0.08
146.8739014	0.08
148.9403992	0.21
151.0314636	1.98
152.1080017	0.15
157.1399841	0.03
159.1112366	0.45
160.4781494	0.21
161.1118317	1.91
161.9934235	0.81
163.2892914	0.42
164.0297852	0.66
165.1247406	3.56
166.1099701	0.91
167.0638733	2.24
168.0122375	0.35
173.0907593	0.20
174.1679688	0.03
175.1687927	0.64
176.003418	0.48
177.1496124	0.19
178.9989624	13.70
180.0073547	3.58
182.2643127	0.07
183.9627533	0.04
185.1110077	0.21
186.0231934	0.26
187.1006012	1.47
188.1439514	1.68
188.9845581	0.23
190.9587402	0.21
198.9454651	0.13
200.0497437	0.10
201.058136	0.26
202.1498718	0.62
203.103241	7.14
204.0777283	4.42
205.0577087	43.74
206.1160889	11.00
212.0382385	0.06
215.0549011	0.02
217.1877136	1.25
218.0629272	0.22
220.1291809	0.04
221.2267151	0.08
222.2653503	0.03
227.0505676	1.77
228.2549438	0.50
229.3161316	0.25
230.2543335	0.37
231.0602112	8.70
232.0910339	1.75
233.9188232	0.05
245.0728149	100.00
246.1277771	46.81
247.0674744	6.34
248.0871582	3.48
253.1199951	0.13
254.0930786	0.28
260.1210632	0.03
261.2108154	0.11
261.8623352	0.04
267.9916077	0.04
271.1109924	5.38
272.13797	2.13
273.8763428	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	286.0816
Annotation	Unknow
Peak:m/z	Relative Intensity
141.2084351	0.53
174.0736084	0.52
186.2478943	0.49
189.2878876	0.19
196.9540710	0.20
203.0735779	1.88
205.0047302	0.50
213.1413879	1.56
213.9816284	2.37
215.0061951	1.64
216.0471191	0.18
225.0349121	0.40
226.0172119	0.81
229.2429810	0.15
230.0984497	2.02
231.0601196	6.03
231.8646851	0.12
241.0682983	8.67
242.1546021	0.43
243.1742554	0.79
249.3109436	0.33
255.0616150	0.13
258.0809326	100.00
259.3272400	2.11
267.3317566	0.32
268.2309570	2.37
269.1310730	1.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
207.3482666	0.13
208.7820435	0.73
232.0973663	0.11
290.8255615	3.98
292.0942993	0.73
292.8606567	4.58
340.5878296	0.11
350.9780884	0.04
352.1989746	0.63
355.0449219	0.45
368.9456787	0.33
370.3393555	0.76
370.9398804	0.79
374.5693970	2.50
376.0410767	1.14
376.7424316	4.10
380.6735229	0.35
382.7003174	0.23
388.7316284	1.42
389.4533081	0.06
390.0708618	0.38
406.8604126	0.12
407.8563232	0.04
422.4288940	0.12
424.3400269	0.32
452.9382935	0.12
458.6280518	17.27
459.8610840	14.35
460.6934204	100.00
480.6692505	0.32
483.4616089	0.12
484.5628662	0.11
488.5390625	0.11
498.7318115	0.94
520.8638916	0.04
521.5755005	0.12
525.9759521	1.51
527.0192261	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	536.2988
Annotation	PS(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
160.9782104	0.03
177.8646240	0.01
193.0052490	0.01
200.8700562	0.02
224.1350555	0.04
231.9753113	0.02
242.1687317	0.16
243.9612427	0.07
251.2721405	1.95
257.0526733	0.05
271.0882263	0.03
272.0159912	0.04
299.8235474	0.02
302.0792847	0.02
305.4977112	0.02
341.0946655	0.05
345.4182739	0.03
361.3633423	0.03
371.0944824	0.03
378.3222046	0.02
405.2992554	0.05
407.9412231	0.06
415.4247437	0.01
424.7952271	0.03
441.1601562	0.04
446.1822510	0.03
455.4682007	0.04
474.2487183	0.04
476.2642822	100.00
477.0214233	0.71
477.7614136	0.01
482.0262451	0.07
490.2301025	0.07
497.3763428	0.01
498.2706909	0.14
500.0647583	1.00
501.0002441	0.03
507.5069580	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.0965
Annotation	4-Hydroxyphenylacetylglutamine
Peak:m/z	Relative Intensity
139.0438232	0.04
148.9573669	0.09
166.1140900	0.33
176.0958862	0.09
180.2697296	0.18
194.7849731	0.02
200.4559326	0.18
218.0632935	0.34
220.7174377	0.22
236.0874023	39.42
240.4721069	0.22
241.1721802	0.04
246.1141357	1.01
251.2184448	0.03
253.6159363	0.13
257.2416992	0.24
264.0252075	100.00
265.0214844	0.15
272.8837280	0.62
273.6446228	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	5-O-(alpha-Mannosyl)-myo-inositol
Peak:m/z	Relative Intensity
100.9051971	16.57
112.9749985	36.54
118.9044647	19.15
130.9769287	5.93
142.9482117	23.68
148.7341919	8.05
160.9798584	31.85
165.2061615	0.78
179.0617981	100.00
182.9138947	4.19
248.8862	5.95
280.9967041	3.53
294.9009705	12.55
296.9077759	29.68
297.9458008	2.55
305.1673584	1.66
312.8508301	1.91
322.8548584	24.83
323.9755249	4.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9799194	0.10
155.0342865	0.02
170.9455566	0.11
173.0296631	0.23
190.9835358	100.00
323.5433350	0.06
515.5053101	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3047
Annotation	Sphinganine
Peak:m/z	Relative Intensity
94.94710541	0.12
96.96309662	0.30
110.7127991	0.10
122.8412781	0.08
125.0149307	0.50
135.0916748	0.06
150.9872437	0.20
153.0209656	0.17
166.9404297	0.10
227.2194519	0.14
230.1314392	0.13
240.4298706	0.66
242.0544739	0.25
249.138092	0.39
253.3669128	0.16
254.578064	0.89
256.230072	0.12
259.4437256	0.18
266.3770142	4.71
267.2943115	0.66
273.3894043	0.08
284.300293	100.00
285.2530212	0.36
287.5148315	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1066
Annotation	4-Hydroxy-5-methylcoumarin 4-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
145.006424	3.26
166.2455597	0.56
177.0510559	100.00
195.0892944	3.63
203.973114	0.33
215.0949707	0.19
257.0690002	0.30
258.2974854	0.27
272.8725586	0.65
275.2150879	0.27
279.1338501	0.97
284.9736938	0.57
290.0041504	0.30
297.3803101	0.33
303.5282898	1.00
307.8508301	1.05
310.3719177	1.04
312.0292664	0.54
321.2246704	11.84
322.0951538	1.07
330.2998352	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1716
Annotation	alpha-L-Rhamnopyranosyl-(1->3)-alpha-D-galactopyranosyl-(1->3)-L-fucose
Peak:m/z	Relative Intensity
148.8769531	0.09
179.0664673	0.05
185.2210693	0.12
208.1932220	0.17
212.7699585	0.21
216.2694702	0.35
219.0009766	0.20
228.2704620	0.11
231.9176178	0.21
247.2548218	0.61
260.1903992	0.10
269.0277100	0.34
273.2518616	0.12
289.9203796	0.47
291.0015564	0.92
293.4038086	0.09
311.1068115	0.15
323.0434570	0.19
341.3110046	0.65
355.4193726	0.05
385.3529968	0.20
387.1581726	0.40
395.1588440	0.16
397.2528992	0.16
398.1210022	0.03
403.1764526	0.31
410.1434631	0.37
425.1792297	100.00
426.2286377	0.91
427.2881470	0.85
433.1170959	0.18
435.0599365	0.34
443.2875977	0.04
452.4193726	0.23
453.3813782	0.30
454.1427307	0.06
455.2113953	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0874
Annotation	1-Caffeoyl-beta-D-glucose
Peak:m/z	Relative Intensity
101.0407333	0.41
106.7741852	0.05
112.990303	0.88
116.901062	0.24
119.0435181	0.64
131.0220642	0.24
132.036438	0.05
132.9677124	0.48
135.0064392	4.35
142.9941406	0.83
149.2168579	0.07
161.0184326	29.41
177.1203918	0.10
179.0578461	100.00
187.1799011	0.08
189.0464478	0.51
198.125885	0.09
203.0430298	5.45
209.0234375	0.13
220.9049683	0.68
233.1394348	0.54
240.9994507	0.07
245.3609924	0.13
251.1611633	2.50
261.1169739	0.08
281.1730957	3.94
293.0244141	0.04
295.0673218	0.98
297.1437683	0.76
298.2179565	0.06
305.3369751	0.09
313.052948	0.04
322.9355469	1.47
326.0983276	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1066.1318
Annotation	Unknow
Peak:m/z	Relative Intensity
417.1370544	0.31
471.2522583	0.35
502.4891357	0.56
520.5189209	1.08
521.6875000	1.29
534.0729980	0.19
535.7337646	0.44
546.8991089	2.32
574.1197510	1.33
676.9545898	0.46
677.5659180	1.99
678.4794312	0.84
697.3796387	0.55
758.4645386	0.99
813.3758545	1.02
1039.6965330	4.79
1040.3681640	6.17
1041.0135500	0.16
1092.5501710	6.62
1093.7531740	6.83
1107.4549560	1.49
1108.7020260	0.69
1137.5275880	0.79
1182.3747560	0.81
1276.7866210	1.02
1277.4447020	0.49
1509.5787350	0.95
1510.5389400	1.10
1536.3577880	0.47
1599.5795900	1.60
1612.5664060	4.24
1613.6694340	2.34
1614.7996830	1.59
1692.7912600	1.40
1781.8345950	0.71
1786.2689210	1.12
1792.3776860	0.16
1796.2098390	0.28
1814.8428960	0.16
1817.1094970	3.42
1827.4830320	0.23
1836.4234620	0.95
1844.4869380	0.21
1851.1306150	0.60
1852.1781010	0.47
1862.6837160	0.65
1885.1071780	0.26
1889.1617430	0.35
1895.9211430	1.79
1897.3441160	7.57
1902.9221190	0.22
1904.2326660	0.67
1907.8728030	4.15
1911.4436040	0.16
1912.6175540	0.26
1914.9337160	6.27
1916.7025150	0.16
1918.0941160	0.82
1919.7365720	0.28
1921.5368650	0.19
1925.3552250	0.29
1929.5789790	0.23
1930.6867680	0.14
1933.7117920	2.33
1934.6345210	2.32
1937.2113040	0.14
1938.9884030	1.97
1939.6429440	0.59
1946.0819090	0.52
1957.0969240	20.85
1959.1820070	0.89
1963.0562740	3.30
1964.5964360	41.90
1965.4361570	0.84
1966.5316160	0.44
1970.3924560	0.46
1971.6749270	7.78
1972.4069820	0.17
1973.9154050	1.32
1974.8746340	6.24
1975.9454350	18.53
1976.7725830	0.41
1978.9987790	40.05
1980.2745360	0.14
1981.6097410	65.27
1985.5140380	0.70
1986.1634520	0.14
1987.1507570	1.14
1990.2640380	15.62
1991.1892090	34.83
1993.7720950	100.00
1994.5269780	0.46
1996.3845210	2.51
1997.9470210	1.06
1999.7933350	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.166
Annotation	3-Methyl-3-butenyl apiosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
127.0207138	0.06
141.1101685	0.11
143.1559753	0.05
144.0536194	0.97
151.1192474	0.05
157.2738647	0.10
161.8735962	0.08
177.1545715	1.93
177.9145203	0.06
179.2864075	0.06
186.9680328	0.14
187.9329834	0.26
195.0985107	0.08
196.8648987	0.05
231.1653290	0.17
241.2877502	0.09
244.9069824	0.58
263.0207825	0.09
272.9858398	0.12
293.6828003	0.15
305.1685791	0.08
306.8079224	0.10
323.4194946	0.13
324.3273315	0.04
328.0649414	0.09
329.2301941	0.13
331.4455566	0.04
333.4200439	0.05
334.3019104	0.13
341.2999573	0.33
350.2607422	0.11
350.9185181	0.17
352.1032104	0.02
356.3132629	0.21
357.2765503	1.36
361.1520386	0.07
362.1448059	0.11
363.3430481	0.27
365.1817322	0.38
367.2616882	0.12
368.4736023	0.06
373.0993958	0.05
379.1688232	100.00
379.7771301	0.70
383.1973572	0.05
391.0475769	0.12
392.0970459	0.38
393.0657959	0.13
395.0158386	0.64
396.1506042	0.31
397.0655212	0.06
406.3117676	0.09
407.2626343	0.98
409.2958069	0.07
410.0390015	0.03
425.6849670	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	Unknow
Peak:m/z	Relative Intensity
108.9440918	2.45
120.9546585	0.51
122.6791534	0.60
135.0186005	5.05
142.9793854	1.03
151.1298523	1.65
156.9938965	0.64
159.1373749	1.51
167.1424408	1.56
173.2780151	2.70
176.7843933	0.38
182.9303131	1.48
187.3426056	1.55
189.1556244	2.79
190.7387390	0.69
193.2017365	0.63
201.2849579	1.09
203.5207825	0.26
214.9696655	0.37
223.3610840	0.60
232.8368530	2.25
241.3320923	1.91
247.2371216	3.92
249.3498535	0.76
251.2540283	3.81
265.2910156	1.11
273.0504761	2.75
279.0086060	0.35
291.1513977	1.41
294.8718567	0.60
301.1780396	0.45
305.0757751	2.68
309.1789246	0.61
313.2429810	3.36
323.2133179	100.00
324.0903320	2.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	539.1965
Annotation	6'-O-alpha-D-glucopyranosylloganic acid
Peak:m/z	Relative Intensity
283.2373047	0.05
292.5105591	0.07
326.2887573	0.31
343.7299805	0.02
359.2385254	0.29
362.0779419	0.08
365.9238281	0.13
377.2087402	100.00
377.8448486	0.18
379.8643799	0.04
383.4733276	0.10
386.2808228	0.20
387.3334961	0.21
408.2354736	0.85
410.3124390	0.04
443.2037354	0.42
448.8162231	0.35
458.3457642	0.24
475.7882080	0.12
477.2229614	0.09
485.1257935	0.22
502.0445557	0.03
502.7576904	0.17
511.1375122	0.27
521.0253296	1.87
522.3630981	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.086
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
116.8547363	0.05
123.0789185	0.04
147.9691772	0.11
151.1279449	0.13
155.9106903	0.03
181.9849091	0.07
195.0311432	0.14
206.0134277	63.20
206.8948822	0.02
216.1870270	0.05
217.3380585	0.03
223.9351501	0.08
233.9338989	100.00
235.0894775	0.18
238.0908813	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	612.64
Annotation	Unknow
Peak:m/z	Relative Intensity
199.1237640	0.27
214.9987335	0.61
400.9063110	0.40
472.2942505	0.26
496.2489624	0.54
496.9467163	2.37
497.9674683	3.61
499.1972046	0.51
508.4120483	0.44
512.9515991	0.28
517.1640015	0.33
520.3663940	0.23
537.9423218	4.64
539.1309204	2.45
539.8627930	0.72
555.1647339	0.36
555.8303833	0.29
556.8399048	0.61
557.9786987	0.12
565.3092041	6.09
565.9367065	57.60
566.9594727	100.00
583.0469360	17.70
583.9457397	16.04
584.6647949	13.64
585.2976074	0.82
586.1380615	0.45
588.6455688	0.17
593.7191772	0.10
606.3953247	0.62
612.3255005	1.17
613.0170288	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1456
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9971466	0.03
147.0130463	8.98
160.9122620	0.38
179.0706177	1.15
241.1622772	0.24
274.0701904	0.39
281.2483215	0.23
290.9648438	0.20
297.1537476	0.17
302.8747559	0.11
309.2433472	0.23
326.2681274	0.08
341.1499329	100.00
342.2778931	0.96
343.0179138	0.07
369.0138245	0.10
383.9872742	0.17
385.3386536	0.29
438.8628845	0.05
443.0013428	1.22
457.1990662	4.91
469.8937683	0.08
470.9961853	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.12
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
160.5086060	0.17
179.0071106	0.06
193.1818848	0.61
206.9243164	0.34
235.1257019	0.03
244.2639465	0.23
253.2014160	0.32
266.7329712	0.61
280.9443970	0.12
300.8865967	0.03
305.1963806	0.22
314.9679871	0.42
315.5856018	0.09
322.4406433	0.03
354.5120239	0.13
359.3388672	0.13
366.8402100	0.27
374.8417969	0.13
376.7595520	0.74
378.9374084	0.13
397.4923401	0.07
404.9028931	0.27
406.5576782	0.12
413.0854187	0.03
415.2060852	100.00
415.8708496	0.20
421.3603210	0.11
433.0984497	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1643
Annotation	Bidensyneoside C
Peak:m/z	Relative Intensity
103.1513824	0.10
107.1668015	0.05
119.2071609	0.10
120.9978638	0.58
130.8824615	0.05
134.9553070	0.05
140.0001221	0.05
148.9334106	1.72
153.0047302	1.12
162.0988312	0.03
163.1116028	0.24
181.0094910	100.00
192.9648895	0.14
197.6280060	0.16
203.2568665	0.13
214.9476624	0.08
225.1774597	0.22
235.2003174	0.07
240.9196777	0.11
257.4517822	0.10
259.0753479	0.02
267.8049316	0.12
270.9757996	0.08
277.1876221	0.08
288.5305786	0.06
289.2266541	0.05
293.0257263	0.07
297.2885437	0.29
298.7258911	0.04
300.9990234	0.09
306.3601990	0.07
307.1778564	0.20
310.9352417	0.34
314.9425354	0.26
316.1331787	0.20
317.2095947	0.02
324.8490295	1.82
329.1470032	0.50
331.9255066	0.05
336.7358704	0.12
339.3987122	0.04
341.5269165	0.37
342.2355347	2.23
342.9774475	6.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	526.2704
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9808502	0.16
162.9830322	0.15
181.8548431	0.13
236.1332092	0.05
242.2970123	0.15
245.8374023	0.22
251.5424194	0.66
277.1888123	0.04
294.2285156	0.22
340.0625610	0.15
400.7371826	0.15
434.3970947	0.19
436.0104980	0.07
448.0326538	0.26
452.7467041	0.06
460.2048340	0.06
463.3358154	0.24
465.7872314	0.30
466.4343262	0.05
467.3286743	0.12
470.2243652	0.20
471.8334351	0.31
472.4800415	0.17
476.3044434	100.00
476.9561157	0.28
480.0601196	0.58
488.3037109	1.42
489.3363647	0.33
490.2201538	0.98
490.8366089	0.08
496.3876343	0.16
497.7819214	0.11
499.2664185	0.31
507.3695679	0.44
508.7619019	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	216.98
Annotation	3-hydroxybenzoic acid-3-O-sulphate
Peak:m/z	Relative Intensity
74.7936249	0.06
86.8513184	0.08
88.8910675	0.05
94.7552338	0.04
96.9320374	0.19
99.1347198	0.04
110.7128296	0.12
113.2148895	0.09
117.0921478	0.07
124.0839539	0.04
125.8426971	0.16
127.0637665	0.19
127.8218994	0.04
133.1734772	0.03
136.9879608	0.27
139.0082092	0.09
142.7548981	0.03
144.8477936	0.02
146.1060638	0.02
148.1566620	0.08
153.2115631	0.09
154.9737396	0.16
171.0390625	0.27
172.9075165	100.00
174.0768890	0.07
174.9716339	0.10
179.0676422	1.15
179.8760681	0.05
181.3945465	0.10
189.2372589	0.07
198.9888153	0.42
201.8046112	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0475
Annotation	UDP-glucose
Peak:m/z	Relative Intensity
163.9499664	0.07
175.2004547	0.01
182.0745544	0.04
192.96698	0.03
204.6022644	0.04
210.9437256	2.80
222.6788788	0.07
241.0301514	1.01
273.0894165	0.13
280.1299438	1.21
291.2279663	0.02
305.099762	0.25
321.0657959	0.50
323.0290527	100.00
372.1413574	0.02
385.0647583	1.52
396.0339966	0.02
397.0230103	0.23
403.0759277	2.95
409.8051147	0.05
445.2753906	0.06
467.2485352	0.31
478.7140503	0.02
480.7301025	0.39
483.6998291	0.04
485.1464233	0.05
518.9136353	0.10
519.7770386	0.09
521.9854126	0.02
529.1385498	0.03
547.1720581	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1663
Annotation	Butrin
Peak:m/z	Relative Intensity
169.1925812	0.14
170.1519165	0.01
173.0282135	0.02
175.2439270	0.01
179.1736450	0.12
180.0721893	0.04
180.9879303	0.29
182.1632996	0.03
182.9835205	0.16
185.1985474	0.07
187.3210449	0.02
190.9285431	0.03
195.2229614	0.06
196.0654297	0.03
197.0259094	0.31
197.9684448	0.08
199.1339111	0.07
201.0296478	0.21
201.7174072	0.04
205.0768738	0.06
207.0688171	0.02
210.8900452	0.05
215.0190735	0.10
224.1174316	0.29
225.0817719	1.27
226.0179291	0.24
227.2427063	0.10
232.1142426	0.10
233.0877533	0.06
234.1117859	0.01
240.0491791	0.03
240.9111786	0.06
243.2866516	0.28
244.0005798	0.01
252.0715637	0.02
252.8746338	0.01
257.3021240	0.01
259.1026611	1.23
260.3112793	0.09
269.0390930	100.00
270.0661011	13.53
270.9481506	0.10
273.1588135	0.06
287.0717468	1.69
288.1866455	0.17
289.2954712	0.11
295.8064575	0.05
297.2187195	0.02
299.3909912	0.02
311.0430298	0.06
312.1519165	0.04
315.1952515	0.03
323.1633911	0.04
326.0825806	0.02
347.1034546	0.06
354.3763428	0.03
357.0241089	0.02
363.0961914	0.02
364.0693359	0.01
373.1585693	0.05
397.0249634	0.02
400.9772949	0.12
404.1069946	0.02
408.9924316	0.05
410.3090210	0.02
415.4720459	0.02
433.4467773	0.03
443.3718262	0.26
452.1763916	0.03
462.2190552	0.09
465.1985474	0.24
466.2052612	0.02
469.1824341	1.05
470.2108154	0.13
473.5406494	0.07
478.5425415	0.35
479.2957153	1.31
480.1754150	0.83
481.4326172	0.01
483.7927856	0.04
489.3029175	0.83
490.2271118	0.21
501.0873413	0.13
509.2185059	0.03
519.0839233	0.08
524.1411743	0.02
527.2195435	0.01
533.3317261	0.34
534.3821411	0.01
539.7964478	0.03
549.4243164	0.31
550.5112915	0.08
551.2549438	0.08
552.0364380	0.01
555.9775391	0.05
557.9826050	0.02
559.4251709	0.09
560.3079224	0.06
567.2081909	0.09
572.9147339	0.03
577.3855591	0.36
578.0277100	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1439
Annotation	Leucyl-Glutamate
Peak:m/z	Relative Intensity
86.0007172	14.56
129.9892273	0.52
131.9713287	100.00
132.9716187	0.75
135.0339661	0.10
148.0529633	1.50
155.1363983	0.47
163.1511841	0.10
188.7622681	0.66
194.1977081	0.63
197.5852203	0.41
198.1992188	6.58
214.9820709	1.00
225.2068329	1.10
229.1960754	0.17
232.8896332	0.29
243.0701447	10.27
244.1620941	45.84
252.0441437	2.28
252.9672394	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
135.1428833	4.80
160.0127411	1.96
175.3022308	4.56
177.4586487	0.97
219.5562439	2.58
251.2835693	3.67
253.3455811	4.62
267.1370239	5.06
269.2077637	5.75
282.0569458	1.32
282.9732971	1.01
293.2081299	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	228.0876
Annotation	Unknow
Peak:m/z	Relative Intensity
70.1007538	0.07
70.8648376	0.06
87.9334106	1.69
100.0766449	0.04
112.8909760	5.88
113.9319305	2.82
114.9954529	1.12
131.9676819	100.00
138.1371918	0.03
147.8661346	0.01
151.2390594	0.04
162.1139069	0.17
164.8920441	0.11
166.2222443	0.28
172.2463074	0.07
184.0858459	2.15
184.8236237	0.03
189.8114471	0.05
200.0325775	0.16
208.4252014	0.02
210.0062103	3.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.284
Annotation	Unknow
Peak:m/z	Relative Intensity
165.0191345	5.37
166.9319153	0.44
179.8835297	0.45
182.9631042	3.51
184.1549225	0.30
189.0394592	1.70
207.0433502	7.86
207.9108276	0.88
213.1031494	0.45
225.0707550	100.00
225.9767609	5.75
227.0183411	2.94
242.9822235	11.44
244.0829010	0.93
244.9105530	0.32
256.0565796	0.31
259.3072510	0.34
261.8165283	1.44
279.2927246	33.32
280.2008057	5.18
281.5736389	0.25
299.0808716	56.89
300.2445068	6.65
301.2968140	1.82
317.0196533	6.90
318.3202515	1.65
319.3281250	0.26
325.0864258	0.23
326.0937500	0.66
327.0140991	0.48
327.8085327	0.23
329.2198486	0.28
359.5867310	0.20
447.6747437	0.14
469.3240967	0.22
484.4424438	0.27
489.1492920	0.27
494.4331665	0.51
496.5363159	0.39
505.5652466	0.54
507.1742554	0.58
522.2053833	0.42
534.4138794	1.54
535.3552856	1.80
536.3251343	1.96
537.2456055	0.27
543.2477417	0.30
546.6134644	0.15
550.6972046	0.21
551.4371338	0.14
561.3049316	0.10
562.4650879	0.11
575.4068604	0.30
579.5169678	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.2752
Annotation	Virescenoside N
Peak:m/z	Relative Intensity
175.1134186	0.33
179.0393066	0.04
192.9318848	0.04
217.1849976	0.06
237.3672333	0.03
269.5103455	0.05
279.1470642	0.08
281.2563171	0.05
283.4315796	0.04
303.3782959	0.06
317.3132324	22.17
329.3486328	0.70
335.2518921	100.00
347.3238220	0.11
349.3222961	0.05
356.1109314	0.06
359.0201111	0.32
369.3761902	0.25
375.2528687	0.19
379.3227844	0.15
383.3153381	0.28
388.0863953	0.04
399.3177795	0.10
401.4618225	0.04
404.1218567	0.21
406.8860168	0.08
409.2801208	0.34
412.8761902	0.11
417.3422546	0.21
431.5494080	0.16
435.1297607	0.15
437.5361633	0.37
438.2430725	0.06
451.5047607	0.07
453.5115051	0.87
454.1401672	0.17
459.3935242	0.03
460.1297913	0.06
461.3176880	0.52
462.1650696	0.24
470.9125366	0.18
479.0267029	0.57
480.1285095	0.17
482.2304382	0.15
497.9716187	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.3099
Annotation	Rapisterone D
Peak:m/z	Relative Intensity
142.9277344	1.10
144.8470306	0.89
146.9252777	1.75
149.0472717	1.43
151.3368225	2.10
154.9393311	0.96
157.04776	3.62
161.1503296	0.87
163.069397	3.16
165.1052399	1.18
170.1292877	2.30
171.1402283	2.88
173.0524597	5.37
177.1373901	0.78
179.1897278	9.97
181.434433	0.89
183.121048	2.18
185.1138611	7.79
187.0537872	0.65
189.213501	1.14
193.0898438	2.28
197.0687714	2.61
199.1022949	4.15
201.11026	8.15
203.2496948	0.84
211.1828766	4.34
213.1696167	1.85
215.1048584	1.92
219.1942139	0.38
223.139801	6.98
225.2780762	1.71
229.0598755	0.70
231.0750122	1.76
233.1898804	0.71
237.0735474	0.69
239.4126282	1.15
241.0267792	4.15
243.2241821	6.87
250.7984314	0.65
253.2166748	3.05
256.9288025	1.70
259.3292847	9.54
261.2407837	22.10
263.7084045	1.27
264.9480591	0.47
267.3132629	4.99
269.6051331	1.06
271.2206116	7.54
273.2815552	1.37
274.9691162	4.18
277.3466187	6.86
278.2866211	1.29
285.3603516	5.08
287.1583557	2.21
289.2930298	1.54
291.4645386	1.32
293.2037659	2.42
297.2636108	2.58
299.4038086	5.33
301.2304993	2.45
303.2988892	5.13
307.2077026	0.29
309.2272339	0.49
311.4019775	0.69
313.4038696	2.13
315.213562	9.98
316.9959106	1.48
319.3114319	2.99
321.3007507	2.45
322.3666687	2.17
323.3110962	7.07
327.0542603	0.56
327.6579285	1.69
329.6803589	1.77
331.3141479	1.24
333.113739	13.28
335.3318481	100.00
341.2918091	10.14
343.241272	1.56
345.0734863	5.54
345.6767578	0.24
351.2406616	16.92
353.2439575	0.89
357.1152344	1.09
359.4016113	4.41
363.1942139	1.68
365.494751	1.84
369.3583069	27.19
375.3179321	4.85
377.3352051	4.95
379.6412048	1.34
381.4266663	6.30
383.4813843	0.85
385.5960999	3.42
387.2690735	14.27
389.3682556	6.68
393.4954529	0.38
399.1754456	1.01
401.1408997	2.15
403.9227905	1.80
405.1717834	6.34
405.9471436	1.10
407.6743469	1.59
415.5360413	4.66
417.3482361	2.08
418.98172	2.87
419.6229553	1.54
423.3433228	3.06
425.2877502	5.17
431.303009	2.57
434.8864136	1.03
440.7643738	1.55
443.4586182	35.01
449.3217773	1.43
455.863678	1.05
461.2963562	41.62
479.2913208	72.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.66
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1238861	0.13
280.8511963	0.18
282.2943420	0.09
290.4031372	0.22
291.1233826	0.04
292.9114990	0.25
324.9867859	0.41
335.5757446	0.13
362.7444458	0.18
364.6201172	0.15
369.7099609	0.18
404.5834351	0.12
412.7822876	0.19
443.7462158	0.12
445.6387939	0.28
446.3799438	0.56
447.6423950	0.82
448.6385498	5.03
455.0053711	0.17
456.1583252	0.40
456.8505249	0.20
458.6232300	0.69
461.0697021	0.20
462.3255005	0.05
467.0461426	0.21
472.9603271	0.02
484.6240234	0.22
486.8308105	0.83
503.6331177	0.06
525.9368286	0.14
530.2895508	1.67
532.4770508	100.00
533.1983032	1.09
540.8148193	0.46
542.9348755	0.95
545.7067261	0.71
556.0315552	0.05
568.9066772	0.13
569.8908081	0.94
570.6354370	7.27
572.9050293	0.07
579.9607544	0.77
593.0585938	0.09
596.8358765	0.06
597.8333130	0.42
598.7976074	0.15
617.7817993	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	175.0611
Annotation	2,3-Dimethyl-3-hydroxyglutaric acid
Peak:m/z	Relative Intensity
84.9175873	61.54
85.5282593	0.49
88.8408966	0.21
92.8723450	0.16
99.1026916	0.15
112.9372101	53.88
114.9050140	100.00
126.1636200	0.16
128.7575226	15.57
130.9781952	9.75
156.9593048	53.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.1513
Annotation	Unknow
Peak:m/z	Relative Intensity
160.7994080	0.07
178.9302063	1.41
193.0727997	0.27
308.3150024	0.75
341.1977539	100.00
366.0403748	0.26
412.4099121	0.08
434.9938354	0.11
452.0039978	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
122.8951111	1.31
125.066185	0.69
163.3152466	0.13
167.0254517	100.00
181.21521	0.10
182.9931335	0.14
185.1183167	0.30
191.1081085	0.20
205.0137939	0.18
209.175415	0.66
222.9799194	0.17
229.264679	0.18
233.0732117	0.31
249.0370178	0.12
251.0772705	0.24
267.4173584	0.60
268.2518616	0.28
271.1558838	0.41
273.0078735	0.25
285.1389771	0.79
293.3195801	0.23
298.3011169	0.74
311.293335	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	832.6245
Annotation	Unknow
Peak:m/z	Relative Intensity
336.3958130	0.94
419.3233643	8.93
478.4415894	2.01
495.1774292	0.43
496.3939209	100.00
520.0837402	0.78
538.4690552	1.02
551.5451050	0.63
838.1539917	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3962
Annotation	Gingerglycolipid C
Peak:m/z	Relative Intensity
232.3814697	0.03
235.3189392	0.11
253.2556152	0.01
281.3923035	0.07
297.6010742	0.01
305.0460815	0.12
379.3877563	0.10
391.3937378	0.08
397.2078247	8.12
415.2718506	1.68
455.0473022	0.07
478.5811157	0.06
479.5918579	0.02
480.1945801	0.07
572.3955078	0.12
586.2295532	0.04
621.3867798	0.03
624.4067383	0.02
651.3436890	0.03
665.3419800	0.05
679.2332764	100.00
679.9270630	0.26
707.3713379	0.03
719.4423218	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3385
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
165.9279480	0.64
184.0495453	21.06
185.1086731	0.04
222.4296722	0.03
243.2046814	0.10
257.9410095	0.33
337.3730469	0.25
348.2689209	0.21
443.2144775	0.13
502.4229126	100.00
503.0274048	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	522.1825
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
161.1030121	0.15
178.9415741	1.61
180.0318298	0.44
209.0953674	0.02
248.2488403	0.06
253.1142731	0.03
281.2693787	0.04
288.2108154	0.04
341.1704712	100.00
383.9906616	0.04
475.3377686	0.05
477.2424316	0.03
477.8615112	0.03
485.2361450	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.3057
Annotation	Unknow
Peak:m/z	Relative Intensity
240.0167084	0.18
320.4122314	0.62
357.3291626	2.82
389.3013916	0.10
391.6875000	0.11
450.8586426	0.74
456.3866577	0.20
481.3478394	100.00
482.7656860	0.70
506.5714722	0.94
509.5165405	0.10
511.1697388	0.13
523.4525757	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1135
Annotation	2',4',6',beta-Tetrahydroxychalcone 4'-glucoside
Peak:m/z	Relative Intensity
151.0661011	0.28
152.9419098	0.07
168.963562	0.04
180.8217163	0.21
181.7917175	0.08
219.2379456	0.10
224.957016	0.13
250.3326721	0.07
253.4293823	0.10
259.1714783	0.41
271.0543823	100.00
271.6691895	0.11
273.467804	0.75
274.0935974	0.34
286.1412964	0.20
287.1856079	0.28
288.2001343	0.76
295.1195068	1.29
299.2146301	0.22
317.5351562	0.32
318.1940918	0.05
327.1494751	0.16
331.948761	0.19
335.5254517	0.28
343.2541809	0.41
345.1664429	0.39
349.2843018	0.26
351.1141968	0.14
354.1438293	0.17
359.1588745	0.89
360.1972656	0.72
364.132782	0.11
369.2170105	0.09
371.8814087	0.49
373.1229858	0.73
386.8371582	2.15
388.4221497	1.79
389.2184753	0.71
390.0014648	0.45
391.2552795	0.68
394.8789368	1.16
397.0939026	0.90
402.1181946	0.16
404.1922302	0.67
415.0147705	1.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1719
Annotation	Malvin
Peak:m/z	Relative Intensity
199.2211304	0.14
203.0399170	0.06
214.9780884	0.12
219.0746002	0.03
229.0382385	0.04
231.1996460	0.05
235.1993256	0.06
237.0715637	0.18
243.2119598	0.36
258.1843262	0.17
259.0183105	0.73
260.2135620	0.08
270.9290771	1.62
272.3745422	0.10
282.0900879	0.06
285.2261963	0.34
287.1624451	2.47
287.9579468	0.10
291.0189514	0.13
292.6280212	0.04
297.8482666	0.12
301.1675415	0.56
302.2195435	0.38
313.1849670	0.06
315.0712891	19.47
316.1138916	0.49
327.1341553	0.14
329.4796753	7.27
330.1184692	64.11
331.0302124	0.73
341.2886353	0.19
342.3422852	0.05
343.0516968	0.08
345.1089478	100.00
346.1801758	0.93
354.1577759	0.40
356.9753418	0.06
359.0824585	0.12
361.1236572	0.11
365.2028809	0.30
372.1190796	0.41
387.1713257	1.39
399.1707153	0.16
403.2980347	0.02
404.9857178	0.05
408.1367188	0.17
409.1365356	0.03
417.1683350	0.15
429.1210938	0.15
467.1882324	0.05
474.3001709	0.14
478.2252808	0.07
481.0708618	0.26
482.8615723	0.09
491.3739624	0.64
493.3294678	0.38
499.0684814	0.06
506.1057739	0.13
507.1073608	0.26
509.2648315	0.05
520.7283936	0.04
521.5360718	0.05
538.2045288	0.04
557.0370483	0.25
562.7515869	0.04
569.3633423	0.05
573.2357788	0.06
579.1600952	0.07
592.7505493	0.60
603.2281494	0.22
606.3345337	0.26
607.3943481	0.67
608.2446899	0.44
616.9608154	0.14
617.6417847	0.09
620.2803345	0.04
622.8682251	0.03
625.3672485	2.31
629.4467773	0.47
634.1899414	0.04
634.9936523	0.27
635.6292725	0.30
638.2238159	2.28
639.2282104	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.2109
Annotation	Consiculine
Peak:m/z	Relative Intensity
118.9694519	0.08
122.9133453	0.26
135.2929382	0.29
137.0100098	2.45
141.0810547	0.24
145.3855896	0.18
146.8632355	0.40
148.9576416	0.19
154.0025940	0.47
159.4651031	0.27
160.9792786	0.91
162.7398682	0.13
165.0279846	1.25
169.3328400	0.06
171.0754700	0.23
174.8914185	1.21
176.9396362	0.38
179.3056030	0.34
179.9319458	0.05
186.9540405	0.10
193.1905212	0.60
195.1796570	0.34
197.1409912	0.20
199.0476685	0.38
201.1797638	0.19
202.9118347	0.29
205.1694946	0.31
209.0678864	0.23
211.0714569	1.88
212.2694397	0.44
215.1010437	0.42
221.1485291	0.06
225.1725159	0.04
227.1336975	0.15
229.3278503	0.15
235.1965942	0.08
265.1875000	0.65
269.2387085	0.27
272.8083191	0.59
283.1434937	0.45
285.3614197	0.12
289.0784302	0.09
293.1536865	1.00
297.1236572	0.29
299.2789917	0.22
301.5245361	0.81
307.7767639	0.08
311.2417908	9.03
315.0362244	0.38
317.0601501	0.68
318.8851929	0.30
320.0909729	0.44
322.6217651	0.13
329.2557983	54.55
332.8793335	0.38
335.2036133	0.41
346.2086792	100.00
347.0996399	14.69
347.7363586	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9393
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0041962	0.57
228.9482422	0.15
271.0575562	0.05
272.9582214	100.00
313.1097412	0.03
314.9735718	0.03
341.2527161	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	460.2466
Annotation	Antibiotic DC 102
Peak:m/z	Relative Intensity
152.7452393	0.14
168.9440918	0.81
170.6945038	0.10
183.1593781	0.24
184.9491119	0.13
190.9549255	0.07
195.9020081	0.15
196.7582397	0.09
213.6071320	0.90
214.2692413	2.21
215.3553772	0.14
219.3091736	0.82
220.1344604	0.34
227.2055054	0.12
243.4128418	0.29
255.3433533	0.07
258.9456482	0.26
261.0621033	0.19
263.2387695	100.00
264.2050476	35.35
264.8097229	0.33
277.1320801	0.07
295.3760376	0.19
304.3094482	0.21
305.9818115	0.17
307.6786804	0.07
317.3814697	0.09
319.6133423	0.07
327.4017334	0.17
349.2131958	0.22
353.4806213	0.11
361.5548096	0.54
365.1977844	0.13
373.5612488	0.26
377.0409546	0.09
385.2626038	0.19
387.3281555	0.06
389.3629456	0.17
397.4846802	0.28
398.5685730	0.12
399.4761658	0.81
401.3376770	0.17
403.3143005	0.43
415.1386414	0.46
416.6785583	0.76
417.3733215	0.11
418.6524353	0.25
423.3163147	0.15
424.2104492	0.15
425.3346863	0.64
426.0408020	1.14
431.2691040	0.10
432.2180481	0.40
434.2794800	0.38
443.2908020	1.32
445.1675110	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	483.0104
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0810852	5.58
257.1335144	0.05
262.1521912	0.06
272.3077393	0.09
273.1670227	0.19
289.9871826	100.00
308.9851685	11.82
322.9570312	0.06
328.0555115	11.62
345.0960693	0.04
347.1568298	11.60
398.8650818	0.12
434.5442200	0.18
437.3257751	0.19
439.9086304	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.18
Annotation	Tanzawaic acid E
Peak:m/z	Relative Intensity
114.9334564	0.12
125.7241592	0.09
127.0604935	0.22
130.9880371	0.08
162.9954376	0.11
171.2587891	0.06
175.1407928	0.43
177.2094574	0.07
186.9556885	0.08
188.0361938	0.09
191.1172638	0.12
192.2161102	0.08
199.0706482	0.14
203.263916	0.26
212.4180908	0.21
214.9141846	0.09
216.2765808	0.11
217.3080139	0.18
217.9361572	0.11
220.2031555	0.15
221.0666199	0.31
222.0483093	0.15
227.1752014	0.18
229.1188965	0.39
231.1806641	0.30
240.9659729	0.11
243.9353638	0.38
245.1613464	0.97
246.000061	0.62
247.1436768	0.09
250.5750427	0.11
253.4129639	0.41
255.2567749	0.09
259.5073242	0.13
260.9816589	0.83
261.9902954	0.72
269.2759705	0.43
271.1722717	100.00
271.9103699	0.15
273.2290039	3.27
274.1877136	0.06
283.1034851	0.07
285.0021973	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.3364
Annotation	Denin
Peak:m/z	Relative Intensity
216.7682648	0.20
219.2787628	0.13
235.1987000	4.33
244.7771759	0.18
253.3008270	0.58
259.1224365	0.19
277.3961182	3.48
281.1214905	0.06
287.0816650	3.54
305.1434326	4.05
319.5053711	0.18
323.2927856	0.66
361.5113525	0.12
379.1379395	0.16
397.1480103	100.00
415.2677612	39.46
433.4108276	0.07
439.4445190	0.14
454.2322388	0.33
499.4262085	0.13
600.6642456	0.19
659.0329590	0.06
672.4802246	0.24
673.7967529	0.57
675.2095947	30.43
675.8419800	0.14
693.6585083	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.1943
Annotation	Maculalactone K
Peak:m/z	Relative Intensity
163.6291504	0.40
211.3714447	0.12
223.0692139	0.22
238.1299896	0.64
251.5663147	0.26
253.0348816	0.79
263.2969360	0.10
279.2630005	0.08
290.9450073	0.76
307.1414795	0.43
314.2404175	0.11
326.4308472	0.21
362.1953125	1.73
363.1461182	0.19
378.9747314	2.35
396.9783325	0.18
405.3922119	0.22
428.0778809	0.65
433.9296875	0.12
441.8208618	0.18
442.6393433	0.59
445.1249390	1.73
448.0461426	0.45
483.1002808	0.14
486.7098999	0.17
488.3335571	0.82
489.3861084	0.26
497.4899902	0.41
501.4981079	0.44
516.2672729	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2938
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
152.9493408	0.16
196.0377045	1.83
214.1153259	1.01
223.1942902	0.04
225.7895813	0.03
239.3854675	0.02
247.8934174	0.02
253.3423462	0.78
267.0428467	0.02
280.1488953	0.14
281.2452087	100.00
281.8605652	0.42
309.3376465	0.02
315.7022705	0.03
332.1531372	0.01
337.4874268	0.01
340.4281616	0.05
346.0390015	0.02
351.2214355	0.02
365.0814514	0.02
371.4062805	0.02
395.4211121	0.04
402.2116394	0.03
410.2772522	0.07
411.002594	0.02
413.7882996	0.01
415.4812317	0.11
417.2171936	0.45
432.4356995	0.07
435.2652893	0.05
440.2216187	0.03
441.9404297	0.20
442.6592102	0.09
449.2687073	0.05
459.4014893	0.08
460.116272	0.15
462.5638733	0.07
463.2275085	0.01
474.9420776	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.12
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
71.88539124	0.77
89.94675446	17.82
97.8478241	0.58
115.9512482	6.15
134.0753937	0.29
142.017807	0.50
147.7671967	0.38
156.081131	0.92
157.0778198	0.51
160.0570526	0.30
166.0839386	0.75
170.8632965	0.23
171.7815094	0.28
174.0554657	7.81
176.9877472	0.44
178.2350922	0.55
182.4512177	0.23
183.9882965	15.96
184.698288	0.47
187.9736176	0.54
190.3315582	0.19
192.024353	0.21
202.1034546	100.00
203.0166931	1.09
204.5009308	0.27
210.6144257	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	308.0773
Annotation	Inodxyl glucuronide
Peak:m/z	Relative Intensity
88.1223450	0.07
107.9182129	0.10
113.9828339	5.89
114.9642563	3.96
119.0671387	0.10
123.0321960	0.61
132.0006409	20.02
134.0465393	3.69
136.1456299	0.08
145.0309753	0.84
145.9700623	0.04
149.0170441	6.66
158.0177612	0.11
160.8607635	0.05
162.0907135	0.38
175.0344849	0.78
177.1856079	0.54
178.1784363	0.24
179.0480957	0.05
181.1587067	0.03
184.0182343	0.06
187.1473999	0.04
193.0893402	100.00
194.0164490	0.06
204.3617249	0.23
204.9804077	0.26
206.1859741	0.12
210.1371765	0.55
218.1452637	1.12
219.0806274	0.08
220.1527710	1.48
232.0271606	0.26
246.1534424	26.39
247.1325989	0.61
248.0583496	0.42
254.1920776	0.20
255.0846558	0.30
256.3916016	0.07
264.0408325	21.46
264.6473999	0.33
266.0062256	0.22
269.9352112	0.21
272.0221558	0.27
273.1171875	0.05
289.5378418	1.05
290.1567383	4.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2764
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
139.0080566	0.02
145.2361298	0.10
197.7641449	0.04
213.2395935	0.03
216.0576172	0.04
249.4121399	0.09
261.2848816	0.10
276.3225098	0.03
304.3417358	0.31
307.1918030	0.07
317.2187805	0.09
322.4665527	0.04
335.3075256	100.00
336.1812744	0.02
349.3204956	0.06
378.2403259	0.10
415.2186584	0.49
433.0707092	0.04
458.3050232	5.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.2938
Annotation	1-heptadecanoyl-glycero-3-phosphoethanolamine
Peak:m/z	Relative Intensity
195.5381165	1.06
196.1595001	3.73
213.0032654	0.99
214.0309753	2.97
252.5611572	0.22
259.9617615	0.18
269.2566223	100.00
298.2020264	0.29
309.145874	0.10
326.2450256	0.21
355.5962524	0.71
377.5148926	0.29
378.221405	0.46
384.8871155	0.41
404.2650452	0.57
407.3730774	0.10
419.7333374	0.59
420.7380981	0.12
422.4115295	0.75
423.2090759	0.96
430.2926636	0.76
431.1302185	1.19
447.3092346	3.12
448.1264954	2.34
449.3959656	55.55
451.3471375	0.88
465.2551575	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	897.2654
Annotation	Unknow
Peak:m/z	Relative Intensity
337.0940247	0.15
481.3771973	0.06
517.1691284	0.44
541.4783325	0.24
559.2769165	2.39
573.6251221	0.20
602.3643188	0.11
635.5045776	0.05
653.0538940	0.09
675.1313477	0.34
693.1835327	1.12
693.8165894	0.32
721.0776367	0.06
732.5742798	0.04
735.2455444	100.00
775.6438599	0.08
777.4354248	1.35
788.3307495	0.17
803.6710815	0.15
816.3921509	0.17
818.4567261	0.06
838.2557983	0.14
851.1514282	0.05
851.7781372	0.10
852.7694092	0.16
863.1719971	0.26
878.6052246	0.14
879.3356323	0.22
897.6651001	0.04
898.9738159	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	154.0859
Annotation	Vanillylamine
Peak:m/z	Relative Intensity
120.8073425	0.03
125.9600830	0.01
137.0330658	100.00
137.9924469	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
113.1224365	0.07
119.0119324	0.04
125.0649109	0.07
142.9193726	0.12
161.0905151	0.05
178.9541779	0.60
197.0215302	0.41
205.0986786	0.03
215.0777435	8.09
281.2612915	0.07
331.3371887	0.02
341.2473145	100.00
359.1135559	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	450.2603
Annotation	N-Acetyl-leu-leu-tyr
Peak:m/z	Relative Intensity
148.8597870	0.11
193.0848999	0.14
198.1179199	0.05
198.7332001	0.06
217.0048828	0.15
256.2795410	0.02
278.2557678	0.18
290.3869629	0.10
291.5166016	0.22
309.2968750	100.00
327.3882141	0.09
392.4921570	0.14
394.4827881	0.14
407.2142029	0.61
426.7441711	0.04
432.2210693	4.51
433.4279480	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	734.38
Annotation	Unknow
Peak:m/z	Relative Intensity
211.9095306	0.10
226.6881866	0.10
228.0500336	0.12
230.0756989	0.12
231.9905243	0.20
240.9375000	0.25
241.8548889	0.19
243.0525208	0.33
255.9681396	0.20
257.1060181	0.18
258.7369690	0.06
267.1000977	0.03
267.7189026	0.06
269.0204468	0.42
275.1564941	0.15
281.2296143	0.05
290.0773926	0.15
297.4667969	0.30
312.9626770	0.07
325.5385132	0.15
339.2302856	0.24
342.0124207	0.14
353.1474304	0.08
367.2844849	0.30
368.2963867	0.21
371.2471313	0.48
376.2081299	0.27
385.3867798	0.05
386.0238647	0.32
390.1279297	0.11
393.3585815	0.07
395.3016357	0.09
397.3479004	0.05
401.4370728	0.08
403.6082764	0.05
405.8997803	0.07
408.9111328	0.25
418.1121216	0.12
419.4367065	0.50
421.3540039	0.20
422.3152466	0.31
423.2016602	0.13
433.2032471	0.06
435.2320557	0.26
436.6804810	0.26
438.3387451	0.16
439.3457642	0.46
440.0531006	0.19
441.0424805	0.29
443.1563110	0.14
445.9091797	0.28
446.5509644	0.10
449.1819458	0.46
451.2110596	0.13
452.3971558	0.04
454.2368164	35.87
455.2299805	59.18
456.2360840	100.00
457.1572876	1.93
457.7633667	0.09
458.4896240	0.26
461.2387695	0.04
465.2409058	0.12
475.6878662	0.07
477.2970581	0.59
478.2947388	0.22
479.3382568	3.62
480.2252197	3.14
481.3004761	8.92
482.3508301	1.08
483.2295532	0.46
495.4148560	0.22
504.1785889	0.32
505.3299561	0.10
507.0844116	0.51
509.2373657	0.52
521.1296997	0.28
522.6596069	0.57
523.5968018	0.06
536.3302002	0.14
537.2468262	0.07
548.2330933	0.13
549.4119263	0.54
550.4258423	0.27
565.2823486	0.62
572.0291748	0.08
576.1397095	0.31
579.8204956	0.04
580.6216431	0.16
587.1697998	0.44
588.0719604	0.22
591.4321899	0.20
592.5790405	0.10
599.4856567	0.45
606.0615845	0.06
616.4273071	0.14
620.2704468	0.12
621.6120605	0.77
625.4151611	0.42
632.1454468	0.37
634.4380493	0.16
643.6433716	0.05
649.5775757	0.49
650.3301392	0.04
669.9227905	0.08
670.6580200	0.04
672.6720581	0.05
674.5240479	0.13
675.4685059	0.22
676.8605347	0.12
682.7612305	0.12
687.7747192	0.57
688.8265991	0.44
689.8783569	0.48
691.2917480	0.09
693.7048950	0.40
695.9732666	1.49
696.7583618	0.14
697.8432617	0.66
699.0352173	0.04
700.0239868	0.50
704.1594849	0.05
715.2621460	1.02
716.2650757	1.92
717.6891479	4.08
718.7145386	5.09
719.6685181	4.38
731.5891724	0.43
732.9206543	3.17
733.6229248	25.74
734.5847778	11.58
735.5308228	3.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.28
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.0153198	0.07
152.9046936	0.16
180.8239746	0.06
196.1066742	0.17
214.0934753	0.95
224.1326599	0.02
233.4690552	0.02
241.9867096	0.07
251.3778076	0.02
258.0810547	0.02
261.3648987	0.26
264.091095	0.04
277.3199158	0.08
279.2372437	100.00
279.8536682	0.37
283.2255859	0.01
306.6647339	0.05
307.4599609	0.03
310.1809082	0.02
331.4093018	0.02
358.5412292	0.04
362.6204834	0.05
373.151123	0.02
384.2745667	0.03
395.0582886	0.03
403.8104553	0.09
405.089325	0.06
413.0151672	0.04
430.0433044	0.04
431.5138245	0.13
432.1439819	0.14
435.4494324	0.03
438.4084473	0.02
439.348114	0.05
440.2105408	0.41
442.4580688	0.02
457.0760193	0.22
457.9703064	0.22
458.919342	0.31
462.0672302	0.03
475.9801636	0.07
477.5004578	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
123.0853195	2.58
143.0028992	2.74
160.0362091	2.56
166.821167	4.83
172.9372864	3.56
183.1085052	4.68
187.3112183	5.77
197.3535461	2.10
221.0935211	1.62
239.9154663	2.72
241.1558838	4.25
244.0171509	1.45
253.6089783	9.01
267.2618713	2.41
281.2533569	8.47
295.0503845	4.32
303.3412781	9.14
305.0414124	8.82
319.1932983	4.01
321.2670898	8.16
326.3442993	2.41
339.3147583	19.44
341.2483215	5.70
347.1047363	4.65
351.2521362	8.84
355.1040039	4.17
357.0817566	13.12
358.7710876	4.66
365.4213562	4.60
366.5394897	1.92
374.8503418	9.46
377.116333	4.01
390.2447815	14.93
391.4709778	8.33
394.0362244	11.51
407.5310059	32.21
408.2780457	100.00
409.3664551	24.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8526764	0.07
206.3806152	0.34
213.0034027	2.01
254.9746094	0.72
259.2795410	0.21
266.8811035	0.78
284.9704895	1.52
290.7248840	100.00
291.3356934	0.33
314.9077454	2.21
357.0109863	2.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.0828
Annotation	6-Hydroxytricetin 5-glucoside
Peak:m/z	Relative Intensity
150.9488525	0.53
179.0764008	1.13
192.0504456	0.16
193.0018005	0.17
198.1216125	0.03
207.8923950	0.09
222.2046967	0.05
232.8144226	0.03
236.0357361	0.04
253.3734741	0.25
255.1192627	0.07
263.1453552	0.09
275.2923584	0.05
283.4849243	0.04
289.1681213	0.29
293.0428467	0.08
297.3406677	0.05
299.0907898	0.56
301.3415527	0.04
309.1713257	0.05
315.2262573	0.24
317.0414734	100.00
318.1094360	2.59
329.1663513	0.04
341.1101685	0.35
348.1422729	0.21
350.6660156	0.07
359.2032776	0.17
360.1257629	0.07
364.3519897	0.15
370.3331299	0.18
383.1643372	0.05
385.1081238	0.06
389.1155701	0.05
391.1264038	0.05
392.3282776	0.10
393.3123169	0.05
395.4396057	0.03
417.2316895	0.06
418.9181519	0.20
421.1600037	0.11
424.4043884	0.03
433.0711670	0.19
433.7786560	0.14
435.1107178	0.35
440.9225159	0.12
443.4032898	0.41
444.2686157	0.04
451.0360107	0.07
460.1411438	0.07
461.1683044	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.2413
Annotation	PS(17:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.0578461	0.05
152.7517090	0.06
162.9148254	0.05
169.0644989	0.07
177.1477356	0.20
179.1415405	0.22
192.9108429	0.33
195.0550537	0.09
196.1567688	0.30
204.6778870	0.03
205.3375549	0.15
214.1197662	1.67
214.8634033	0.05
219.7770386	0.09
235.1752319	0.03
236.0018005	0.06
237.3311157	0.09
247.2751312	0.96
273.2523499	1.10
284.1421204	0.03
291.2424316	100.00
303.3569946	0.05
311.2649231	0.20
333.0695801	0.23
338.3331299	0.11
346.2253723	0.06
357.8071289	0.08
369.8823242	0.02
373.4841919	0.04
376.4338379	0.13
385.1744080	0.14
391.8147888	0.39
394.1823425	0.04
397.7186584	0.02
400.5405579	0.09
403.6009216	0.15
407.8093567	0.03
414.0116577	0.05
417.3643494	0.06
419.4547119	0.11
424.6676025	0.05
428.7385254	0.09
431.3132935	0.12
432.4837952	0.06
442.1744995	0.06
443.5367126	0.24
444.9671631	0.14
449.0530090	0.03
450.1839905	0.46
451.5279846	0.46
452.3535461	1.54
453.2903137	0.17
456.3698730	0.39
461.1328125	0.15
469.0435486	0.08
469.9953918	0.08
471.6684265	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.2329
Annotation	chaulmoogric acid
Peak:m/z	Relative Intensity
82.92129517	0.71
97.01931763	1.01
99.91464996	0.38
126.9504623	0.23
133.0662537	0.59
161.044342	0.79
181.2893982	0.24
195.7988281	0.19
204.97052	1.34
232.4392395	0.43
233.2961731	0.91
234.2342834	0.98
235.1847229	0.54
243.3683777	4.63
259.2104187	5.30
259.8186035	1.45
261.229248	100.00
262.972168	1.26
264.0294189	0.58
279.3806152	4.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.07
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0005798	0.03
219.0992432	0.06
242.0487061	0.10
245.9211426	0.19
269.1912231	0.16
270.7635498	0.14
273.0238647	0.30
281.0335083	0.12
282.2019653	0.16
285.1679688	0.14
292.5355225	0.15
297.0666504	0.14
315.0618896	0.15
323.2027283	0.08
341.3609619	0.17
356.7019043	0.37
357.3046875	0.54
366.9283447	0.08
368.2446289	0.08
368.9814453	0.06
399.2018433	0.07
415.8523560	0.17
416.9019165	0.15
427.8741455	0.08
428.9121094	0.38
430.0676270	0.91
430.9652100	1.14
434.8964233	0.08
440.5021362	0.12
441.1768799	0.14
443.2772827	0.16
444.6595459	0.54
459.2269287	0.08
466.7067261	0.11
467.8682251	0.24
469.0214844	2.92
475.9973145	0.40
481.7568970	0.06
503.2473755	2.68
504.4973755	0.27
505.2788696	0.39
517.1986694	0.12
527.2478638	0.38
530.8023071	0.13
539.2083130	99.32
540.2363281	40.08
541.1853027	100.00
554.1269531	0.11
577.0748291	7.91
578.1926270	7.38
579.1788940	10.76
596.2844849	0.25
596.9415283	0.50
597.6562500	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.156
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1815796	0.05
177.9045105	0.03
179.0235291	0.15
187.8868866	0.11
203.1018982	0.14
205.0948029	0.06
208.2987671	0.04
220.8512268	0.03
221.9169617	0.03
223.1081543	0.02
248.9542542	0.09
251.0309448	0.12
264.9944153	0.20
271.1347046	0.07
272.1720886	0.24
275.1384277	0.04
276.2286987	0.04
283.1775208	0.04
287.3590698	0.05
288.8594055	0.05
290.2424011	0.11
290.9993286	0.06
294.2962952	0.51
295.1998596	0.43
303.6152954	0.06
309.3464355	0.03
318.9824219	0.17
324.2349854	0.05
325.3179626	0.06
326.9170837	0.18
329.1668091	0.28
341.2766724	0.45
342.2437134	0.13
343.0812988	0.13
365.0365601	0.06
367.3142090	0.05
373.1069031	0.54
376.3730774	0.09
379.2872009	0.03
383.0704346	0.13
385.1930237	0.10
389.1323853	0.12
395.5006104	0.36
396.9481506	0.08
399.2654114	0.02
411.1790161	100.00
412.1159363	0.14
413.0542908	0.17
413.8840332	0.08
422.1857910	0.10
428.9799805	0.07
430.4266663	0.33
438.2144470	0.16
439.3273010	0.58
440.1542358	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	2-C-Methyl-D-erythritol 4-phosphate
Peak:m/z	Relative Intensity
70.9544373	2.08
78.7631683	3.18
88.9179993	3.38
100.9771881	0.71
106.3883820	0.43
118.8944550	2.32
126.1090851	2.30
131.0053101	1.72
139.7897186	1.45
142.7708282	4.57
152.8845978	3.05
158.7108002	0.80
161.0957489	9.38
171.1623077	0.92
172.0083008	1.11
178.9867401	100.00
196.6828613	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.3804
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
235.1224976	0.04
253.1246338	0.05
287.2619629	0.16
304.8471069	0.27
397.1760254	6.52
415.2197266	0.91
445.5184937	0.11
561.2546997	0.01
594.2903442	0.02
639.7723999	0.06
653.2158813	100.00
653.9322510	0.17
667.2380981	0.05
681.4763794	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	330.26
Annotation	Undecanoylcarnitine
Peak:m/z	Relative Intensity
94.0045700	0.16
102.2184677	0.25
116.1172791	0.18
121.1982574	0.30
144.9175110	0.13
150.9247437	0.31
155.3879700	0.25
167.0211182	0.41
188.7731934	0.46
210.5410767	0.17
211.2851257	0.61
225.1490173	0.75
236.3400269	0.28
237.2550964	0.35
242.9159851	0.80
255.0096741	0.15
256.0404663	0.52
257.6553650	0.13
266.9841919	0.34
277.3878174	1.31
278.7673340	0.10
281.1409912	2.71
283.4846497	0.35
284.9182739	1.29
289.1110840	0.05
295.1419678	100.00
296.4496460	0.30
298.4843140	0.26
299.0971985	0.50
302.2150269	0.33
312.2825317	8.64
313.1320190	0.45
315.7817078	0.34
330.2304688	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.2205
Annotation	PA(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
150.8412933	0.64
152.9222107	100.00
158.7477417	0.13
170.9186401	8.96
180.8488159	0.10
217.2058868	0.09
224.2101135	0.07
234.0473328	0.12
254.9148865	0.12
257.2556763	0.22
269.4597473	0.28
271.3095703	0.17
273.3202820	0.14
274.2544556	0.05
277.3812866	0.33
283.0381165	0.26
284.3215332	0.13
299.2667236	0.05
303.2215576	0.21
321.2905884	0.15
322.4513550	0.58
327.1020813	0.39
340.0548096	0.64
341.2078247	0.52
342.1439819	0.06
343.9252930	0.25
357.5081482	0.23
358.6167297	0.18
360.3631592	0.35
369.4706726	0.60
371.3933411	0.11
384.3334351	0.19
385.0428467	0.24
386.8587341	0.74
387.5980530	0.44
392.9096985	0.36
394.7574158	0.27
398.9468689	0.34
400.9470520	0.14
403.2805481	0.11
412.0423279	0.85
413.1421509	0.95
415.3092346	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.4758
Annotation	Dioscin
Peak:m/z	Relative Intensity
289.1641846	0.90
325.0690918	0.52
493.6760864	0.14
509.6403809	2.27
510.7283936	0.57
522.1004639	0.23
525.9736328	0.20
539.2949829	0.49
575.4310913	0.69
576.4138184	0.56
600.4362183	0.12
667.4625854	0.26
687.3830566	0.28
703.2400513	1.17
704.6665649	0.38
721.3950806	100.00
722.3956909	56.21
723.0321655	0.67
764.6610718	0.26
781.3764038	0.13
800.5014648	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.33
Annotation	Unknow
Peak:m/z	Relative Intensity
279.3529053	2.23
308.2481689	0.02
459.7098999	0.03
504.3605347	100.00
505.3798218	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.877
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0427246	0.03
228.8438873	0.06
245.0566711	0.30
247.0373840	0.14
248.9239044	0.03
273.0394287	1.54
274.0087891	0.01
275.0665894	0.10
289.0442505	3.42
387.0394897	2.33
399.1242065	0.05
401.0441284	0.07
402.9368286	18.57
484.9649658	0.06
485.7540894	0.06
500.8704834	0.27
515.1323853	1.01
516.8360596	100.00
517.5106201	0.20
527.8488159	0.05
557.0418091	0.22
558.8225098	0.06
561.2116089	0.09
573.6875000	0.03
583.8335571	0.75
585.0131226	0.62
585.9181519	0.10
588.2316895	0.06
589.0105591	0.07
592.9535522	0.04
603.0557861	0.07
611.9452515	0.09
612.8292847	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0436783	2.23
116.9156494	2.00
121.019928	6.05
123.2236786	0.62
133.1035767	0.69
135.1426392	0.23
136.4737854	0.85
137.40448	0.41
143.0075989	4.98
151.0279236	0.47
154.8979797	0.86
156.853775	0.65
159.1445007	2.44
163.3007507	3.82
168.9842529	6.20
172.8728333	4.41
182.7471924	1.61
187.0696716	3.62
191.3776855	3.31
192.6677246	0.90
197.1228943	1.80
201.4606323	1.13
210.9880066	6.44
215.3313904	0.32
228.8764954	1.33
231.1685791	1.61
233.0909729	0.36
237.2590027	0.51
242.9210205	1.91
245.4645691	1.37
247.2087708	2.46
255.4692383	0.36
263.3469238	1.05
267.335968	0.74
269.1057739	0.89
271.1300354	1.15
277.5663452	2.86
279.4431458	0.83
280.3244934	1.65
295.2571411	2.79
297.117218	1.18
299.3992004	1.40
305.5144043	0.85
306.9711609	1.48
323.2311707	100.00
341.6231995	4.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.3755
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
185.2461548	0.04
187.1774445	0.04
196.8787231	0.02
203.3112793	0.04
209.1364594	0.16
217.1170502	0.13
219.2636871	0.04
221.0358276	0.18
235.1689911	6.22
245.1116333	0.43
249.1598511	0.05
253.1492615	1.14
255.1791840	0.95
259.4647827	0.06
263.2261963	0.24
269.0538025	0.10
277.2204895	0.14
283.0431824	0.07
287.1624756	3.78
296.9606323	0.04
301.2751465	0.10
305.1341553	7.03
311.3514404	0.17
314.8792419	0.07
323.1662598	0.85
329.4321289	0.02
340.6802979	0.02
349.3529053	0.04
351.4421387	0.27
360.9075317	0.35
373.0853271	0.04
379.2673950	0.49
387.6021118	0.06
397.2063599	100.00
415.2244263	32.67
451.3594360	0.05
490.4996338	0.04
491.4613647	0.09
521.2636108	0.02
593.5394897	0.61
594.5230713	0.05
595.2556763	0.21
599.5333862	0.04
609.3576050	0.07
617.4046631	0.02
634.5200806	0.07
635.3661499	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	869.2505
Annotation	Smilaside L
Peak:m/z	Relative Intensity
243.1978607	0.02
245.0181580	0.03
247.2239227	0.04
251.3600159	0.08
257.1911621	0.21
261.1272278	0.03
265.2083130	0.67
266.0451660	0.06
270.4298401	0.04
286.6813354	0.03
292.2418213	0.07
295.3171997	0.05
299.3688965	0.08
301.3863831	0.08
319.2444153	0.45
323.1032410	0.51
331.1591492	0.05
337.2242432	1.11
342.2061768	0.07
355.4321899	0.15
383.2413940	0.27
395.3600464	0.04
418.0916138	0.06
421.1351318	0.10
423.2544556	0.04
441.2926636	0.07
451.3734131	0.05
467.4055176	0.39
469.3727417	0.06
471.3663330	0.10
481.2451172	1.01
482.1398926	0.05
485.2564697	1.05
494.8988647	0.03
496.2130737	0.44
499.2119751	8.93
500.3323975	1.99
513.1453857	2.44
514.2348633	0.92
517.2296753	7.16
518.2568359	1.14
525.1746826	0.06
527.2403564	0.10
531.2340088	0.03
532.3447266	0.03
545.0970459	0.06
585.1640015	0.09
595.5281372	0.10
597.4688110	0.05
657.2428589	0.04
658.5325317	0.11
661.3226929	2.03
662.3562622	0.98
675.2563477	47.45
676.3690796	14.37
680.2442017	0.05
689.4336548	0.55
690.1586914	0.14
693.2092285	100.00
694.2546997	33.65
694.9262085	0.09
707.1658325	3.26
708.3793335	0.73
720.4317017	0.12
784.0106201	0.30
820.7632446	0.18
824.0612793	0.15
825.4015503	0.04
843.8452148	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.0511
Annotation	Phosphoribosyl-formamido-carboxamide
Peak:m/z	Relative Intensity
129.1807861	0.17
133.9020081	0.14
134.9795227	0.96
140.7981262	3.04
156.8783112	0.24
179.0712433	19.09
180.0519409	0.29
185.0157166	35.47
189.2117920	0.17
197.0801086	0.12
198.2186279	0.07
203.0518799	100.00
205.2064362	0.11
207.2441101	0.09
215.0043030	0.10
217.0618286	0.07
219.1967773	0.11
221.9943542	0.08
229.1791687	0.11
232.9962158	0.07
235.0025635	0.54
236.1770325	0.06
245.2161255	0.17
249.2259827	0.19
261.2294922	0.09
265.2835083	0.47
267.4102783	0.20
269.2574463	0.33
275.1345215	0.30
276.3222656	0.17
279.0351562	0.09
290.3015747	0.19
291.3515015	0.12
293.0650024	0.08
303.5020752	0.31
305.3881226	0.09
312.1584473	0.18
317.1544800	0.03
318.2333679	0.46
319.1173096	0.77
321.0524597	1.14
323.3181763	0.79
324.9552002	0.09
328.9353027	0.20
334.8268127	0.08
346.1544800	0.47
347.1927795	1.69
349.0505676	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0195
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
84.9957428	0.38
86.9451447	0.74
100.9562683	0.06
110.8437805	100.00
128.9439240	1.79
130.8357086	1.58
147.0978241	0.02
154.9938202	0.26
172.9656677	27.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2942
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9197693	0.05
152.9784241	0.08
162.9482880	0.04
196.1030273	0.10
201.8205872	0.05
214.0644836	1.35
224.4330292	0.04
225.3107452	0.03
253.2475281	0.47
281.2662659	100.00
381.8809814	0.02
404.1282959	0.07
415.7259216	0.04
442.2575378	0.04
461.0421753	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1193
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8733063	0.66
130.0113831	0.93
137.2345886	0.02
147.8486938	0.04
152.0839844	0.11
152.9067078	0.01
154.1722717	0.09
162.0847626	0.01
164.0676880	0.05
178.9420929	0.06
181.0259094	0.10
188.5464783	0.03
191.0080872	0.25
192.3811798	0.07
193.2168121	0.21
200.2584534	0.03
210.1358032	0.15
211.1973572	0.09
212.3027954	0.03
214.9581604	0.02
223.1150818	0.08
229.1919861	0.03
233.1751099	0.02
240.6958923	0.10
245.2955322	0.03
249.9632568	0.17
252.9859924	0.84
255.0380859	0.05
261.6288147	8.66
262.8148804	0.11
263.7443848	0.03
264.9993286	0.04
266.0039978	0.05
267.4239502	0.01
269.1109619	0.14
270.1106262	0.10
277.0725708	0.10
280.1076660	0.45
280.8037109	0.11
285.0211487	0.09
288.6774597	3.03
289.5835266	0.02
290.4385071	0.03
294.9260559	0.77
296.1131287	0.18
301.7598572	2.71
303.0307007	0.11
308.2534180	1.52
309.1784058	0.44
309.8684998	0.09
317.6743469	100.00
318.9652710	0.76
320.1752930	0.08
321.6138306	0.04
324.6401062	0.05
326.2145996	0.07
336.7763977	0.01
339.2818604	0.04
344.3059387	0.10
354.2183533	0.05
358.8419495	0.09
366.2043457	0.11
369.1262207	0.22
369.8276672	0.10
370.5150757	0.07
371.3542786	0.05
376.0873108	0.42
403.1360779	0.03
419.2416077	0.54
436.1342163	0.06
442.1639709	0.03
444.4343567	0.04
454.2366638	0.03
480.3214722	0.08
487.3070679	0.10
498.6823425	0.03
500.1707153	2.17
501.3566284	0.08
505.2708130	0.39
506.0627747	0.08
522.2097168	5.81
523.1468506	0.51
572.2970581	0.14
576.4966431	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1
Annotation	Farnesyl triphosphate
Peak:m/z	Relative Intensity
183.1770935	0.02
185.9873352	0.05
195.2487793	0.01
203.1057587	0.05
208.1678772	0.01
226.3568573	0.01
228.9518280	0.02
244.2035980	0.01
246.2400818	0.01
259.1006775	0.13
270.0355530	0.01
298.0477905	0.01
299.3417358	0.05
302.0858154	0.11
303.1463623	0.85
304.1356201	0.30
305.2870483	0.07
319.4157715	0.00
321.5669556	0.02
327.1556396	0.02
330.3506165	0.01
330.9903564	0.02
332.2285767	0.01
340.1112366	0.01
344.1552124	0.04
345.0642395	0.02
350.2985840	0.01
360.8214722	0.01
368.3039551	0.06
372.0609741	0.01
374.2720337	0.02
384.9737244	0.04
385.7862854	0.02
395.2996521	0.01
404.3856812	0.01
417.0788269	0.03
418.3761292	0.04
420.3376770	0.01
427.2519531	0.02
431.2796936	0.01
434.0517273	0.01
435.6401367	0.01
443.5311890	0.04
444.6786499	0.03
447.2867737	0.02
459.5742493	0.10
461.1477661	100.00
462.2880554	0.12
463.2862854	0.02
471.1349487	0.03
484.7482300	0.01
488.6681519	0.12
519.9930420	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	498.1546
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9501038	0.61
146.1198730	0.09
160.0538025	1.23
165.2015686	0.03
167.1221313	0.36
169.0687408	0.07
170.3616333	0.23
171.1156464	0.31
177.0716248	1.35
179.0284271	2.61
182.1299591	0.11
185.0390930	0.17
192.1212921	0.36
197.1231537	0.33
210.1403503	1.49
212.9678345	0.19
228.3016815	0.02
231.1386108	0.03
236.0582886	0.12
242.2445679	0.18
249.1348572	0.03
254.0935364	10.60
272.1126099	10.94
288.1549072	12.68
306.1215820	100.00
319.7973633	0.06
369.0677185	0.30
451.8761292	0.02
479.9881897	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2207
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.89627075	0.69
97.07538605	0.19
109.112915	0.31
114.6228638	0.16
120.9118729	0.51
122.6266937	0.79
128.7397156	0.32
133.1614075	0.55
135.1745911	2.29
136.9263611	1.55
138.6984253	0.60
148.9327393	0.72
151.1012268	0.33
153.2327271	0.28
155.0748596	1.43
157.0885925	1.04
164.8442993	0.41
169.1645966	0.92
172.9949646	0.65
177.2063751	1.54
181.2546692	2.78
185.0016479	1.08
187.1860046	0.69
189.1364594	0.47
191.1595306	1.34
193.2810822	0.31
194.8330688	2.59
197.3247223	0.43
199.063324	0.36
204.1086731	0.41
204.9661865	0.19
209.0872803	1.25
210.5258789	0.82
211.137085	1.80
213.2235413	0.41
215.1497192	1.16
218.8825378	0.27
221.1647339	0.23
223.0975647	1.90
225.2891235	0.71
226.9490662	0.59
229.1255493	2.89
231.3668518	0.85
233.3280029	1.30
235.1058044	0.44
237.0800781	1.98
239.2706299	2.42
241.1880798	0.30
247.229248	2.52
249.0996094	0.92
251.3179932	0.37
253.0637207	9.23
255.2328491	1.75
265.4386292	2.32
267.1136475	1.66
269.4857178	0.80
270.2993164	0.31
275.1403198	16.45
277.2203979	1.78
279.2243042	1.55
280.2402954	0.38
281.151825	0.81
282.9381104	1.13
290.8005371	0.14
293.2086182	100.00
302.2126465	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1643
Annotation	Kaempferol-3-Glucoside-3''-Rhamnoside
Peak:m/z	Relative Intensity
287.0535889	100.00
288.1798096	44.34
385.3267212	5.08
403.1420898	3.16
405.1195679	3.37
449.1027222	26.58
450.0870972	90.39
533.1177368	4.06
551.4241943	4.66
577.9889526	11.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.077
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
84.9670410	0.09
87.0245438	0.12
88.8612823	0.41
92.9890518	2.89
95.0367432	0.07
96.9311523	0.24
99.1360169	0.08
100.9221725	0.56
104.8318405	0.05
106.8020172	0.04
112.9824295	2.91
115.0057907	0.08
119.1920776	0.07
121.0312500	0.08
131.0899811	0.18
134.8659821	0.10
136.9868469	100.00
142.9973450	0.46
151.0093994	6.69
158.0402679	0.04
161.0318604	0.15
162.9367981	0.07
172.9046936	0.10
177.1436005	0.08
179.0252380	78.70
181.0330200	0.04
183.9682007	0.05
187.1577454	0.25
190.9918060	0.28
195.1181488	0.08
203.1415100	0.39
203.9390869	0.08
205.1502686	0.48
207.2138977	0.05
209.1028442	22.78
209.9520264	0.13
211.0501709	0.05
213.2850342	0.38
221.1231689	0.33
223.0493164	0.13
227.1960144	0.24
233.2098083	0.94
237.2728882	0.12
239.0382080	89.88
241.1470337	0.12
251.3522034	0.07
253.1214294	2.19
253.8400879	0.38
255.2255859	1.08
263.1866455	0.32
266.1316223	0.85
268.9824829	0.14
270.1468811	0.06
271.3875427	0.29
279.7045898	0.20
280.6472473	0.41
281.2619629	1.18
284.4711914	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	552.2859
Annotation	Unknow
Peak:m/z	Relative Intensity
178.0492249	0.04
201.8553314	0.20
202.9178772	0.05
209.0873871	0.05
217.7210236	0.05
220.0928192	0.23
221.8554688	1.00
245.9150543	0.43
249.2557373	0.12
267.2440491	0.13
277.3300781	0.78
295.2659302	0.09
296.2440796	0.10
310.1080933	0.04
367.4370728	0.07
380.0460205	0.08
384.5538940	0.12
387.0751343	0.09
390.4456177	0.26
406.1077271	0.11
407.3240356	0.09
416.3014526	0.06
431.3867798	0.11
436.0133667	0.03
439.2641602	0.09
449.1868286	0.03
456.2702637	2.52
462.2562866	0.06
480.5513306	0.07
484.3901978	0.13
490.2568970	0.08
493.4316406	0.05
502.3014526	100.00
502.9223022	0.37
508.2989502	0.35
510.3187866	0.10
514.2479858	0.78
516.1082153	1.08
533.4371948	0.04
534.3184204	0.34
535.2016602	0.12
555.0769043	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2936
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9382477	0.09
153.0737610	0.07
171.0492706	0.02
196.0354919	1.64
213.9451599	0.77
253.2174988	0.04
279.2456360	0.01
281.2735596	100.00
282.3614197	0.01
337.0748291	0.08
341.3964844	0.02
397.4753723	0.02
417.3392944	0.22
442.4942932	0.04
443.2771606	0.04
450.3117981	0.04
460.2309875	0.07
461.7465515	0.01
475.4497986	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.0783
Annotation	Lactulose
Peak:m/z	Relative Intensity
111.7545471	1.75
116.3186569	3.69
132.2213440	3.88
147.9591370	1.02
160.1580963	1.58
174.0285645	4.80
176.8693085	9.09
201.0254211	43.66
218.9627380	49.62
232.7577515	1.18
234.0387573	17.94
234.8997803	1.42
249.0798950	8.86
251.1045837	100.00
252.2722778	24.73
275.0177612	3.97
305.1816101	2.39
334.8806763	1.89
336.0262756	1.27
362.7601624	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	492.3071
Annotation	Unknow
Peak:m/z	Relative Intensity
166.1427765	0.64
184.0685883	100.00
309.0639954	0.18
376.3511353	0.07
432.3647461	0.52
474.4297791	98.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2359
Annotation	LPA(0:0/18:2(9Z,12Z))
Peak:m/z	Relative Intensity
151.0784912	1.41
152.9695587	100.00
170.9615173	8.10
207.0901489	0.80
257.4530029	0.26
271.2943115	0.58
279.3173523	0.27
291.4819641	0.17
332.9504395	0.32
337.3495483	0.32
340.2943115	0.25
342.6349792	0.28
371.3325195	0.25
376.0393677	0.54
386.2242432	0.21
387.2095032	0.22
389.2268982	0.65
395.0031128	1.36
396.4288025	0.14
397.1404724	0.24
405.3760071	1.05
414.4589844	0.51
415.3806763	0.78
416.0639648	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	314.1049
Annotation	Amoxapine
Peak:m/z	Relative Intensity
133.0161438	0.05
159.9360352	0.20
161.0808716	3.15
174.0785217	0.02
179.2350311	0.02
181.2920227	0.04
187.1111450	0.12
192.9995270	100.00
205.2124023	0.07
225.2977600	0.01
227.1130981	2.34
252.0218506	0.01
263.4803467	0.14
265.1035156	0.07
267.6922607	0.13
269.2011414	0.02
269.8515930	0.01
295.0159912	0.02
295.8908691	0.25
305.5665894	0.07
318.9716797	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2782
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.1235504	0.09
153.1204834	0.06
196.0972290	1.66
205.1089478	0.05
214.0310364	1.40
239.2441559	0.39
240.5122070	0.03
251.6626892	0.02
259.2043457	0.01
261.3729248	0.28
271.2351379	0.05
277.2028503	0.02
279.2535400	100.00
279.8585510	0.36
349.3895874	0.07
369.2575073	0.01
376.3758240	0.01
387.4394836	0.02
401.4258728	0.06
415.3190918	0.24
421.3862915	0.04
422.3773499	0.02
431.0899658	0.10
431.8703918	0.04
433.5595398	0.03
437.6886902	0.02
440.1317749	0.07
441.1558533	0.03
475.2854919	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.28
Annotation	Terragine D
Peak:m/z	Relative Intensity
244.1749878	0.39
281.2962341	0.12
283.2406311	0.22
305.5494385	0.52
307.2596436	0.41
323.2865295	0.48
335.4140015	5.99
336.3618774	68.91
337.3239441	25.73
338.3269348	100.00
363.8546143	0.64
374.8626709	1.11
387.5518494	0.10
397.4405823	0.25
404.7835999	0.36
419.5684509	0.28
433.3495178	0.11
435.1118774	0.45
443.3931274	0.29
459.3022766	0.98
460.1117249	0.20
461.2002258	10.54
462.4538879	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	699.3536
Annotation	Denin
Peak:m/z	Relative Intensity
245.2181244	0.29
343.2529907	0.21
347.0012207	2.26
348.0475769	0.93
357.1062622	0.27
365.0623779	3.21
366.3251343	0.62
375.3622437	0.57
379.0479736	0.49
421.1445923	2.20
509.2003174	0.16
537.4016113	100.00
538.5457764	19.78
546.0089722	0.93
607.9264526	0.20
616.2348022	0.36
681.4789429	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	594.304
Annotation	alpha-MAPI
Peak:m/z	Relative Intensity
248.1185760	0.09
249.8985901	0.11
252.2263641	0.11
257.4720154	0.06
261.2315674	0.07
291.2451782	0.11
292.9386597	0.07
299.3586731	0.13
309.2041626	0.75
310.1923218	0.15
323.2993164	0.04
334.3613892	0.09
387.4691772	0.21
419.3728638	0.43
435.3970337	0.64
445.6026611	0.10
446.2343750	0.16
447.2733154	0.23
448.0916748	0.15
459.0849609	0.11
463.2205811	1.33
464.2304688	0.18
465.2821045	0.14
466.3220825	0.11
478.9608154	0.05
480.1560669	0.18
489.4782104	0.33
490.6188354	0.32
494.1244507	0.23
495.2734985	0.45
499.2913818	0.20
506.9857788	0.18
508.1563721	0.35
517.3582153	0.10
530.9348755	0.16
532.3693848	0.11
534.3090210	100.00
535.2762451	42.00
536.2708740	0.97
548.2896118	15.71
549.3084106	6.47
549.9204712	0.03
551.3063965	0.43
557.2455444	0.16
558.1185303	0.41
559.2805176	0.19
563.7450562	0.39
576.4044800	0.08
577.3689575	0.32
581.0103149	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.4506
Annotation	Astragaloside I
Peak:m/z	Relative Intensity
367.0474854	0.03
464.2831421	0.17
518.4257202	0.08
556.3300171	0.04
635.2764282	0.05
703.4473267	0.29
715.7214355	0.03
721.3334961	3.08
721.9537964	0.33
815.5703735	0.05
825.3889771	0.04
867.4283447	100.00
868.2567139	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2498
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
133.0585327	0.92
135.9368286	0.82
145.1454315	1.51
149.2192383	0.26
151.1748047	0.34
157.2358398	1.15
158.9608765	0.31
165.2894287	0.58
168.9305115	1.07
170.938324	0.74
181.1363525	0.76
189.132843	0.50
205.2896881	0.37
211.2227783	0.46
215.9817505	0.49
223.334137	0.67
225.20047	0.55
245.2830505	0.46
247.325592	5.78
277.2101135	0.46
285.0348511	0.59
295.5436401	1.66
299.3600464	1.80
305.065918	0.89
313.0749207	0.72
323.2410278	100.00
323.8414917	0.51
341.258667	2.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.3636
Annotation	Denin
Peak:m/z	Relative Intensity
205.3446503	0.08
235.1120605	0.03
271.3900757	0.03
277.2369995	0.04
305.0000000	0.05
322.9597168	0.01
361.2813110	0.07
373.1547852	0.12
391.4686890	0.09
397.2110596	5.91
400.8863525	0.02
415.3287354	0.81
427.1945190	0.01
467.2686157	0.01
469.2425537	0.41
470.4150391	0.26
471.2803955	0.03
527.4151001	0.03
563.3147583	0.03
569.8436890	0.04
617.0158081	0.02
626.1332397	0.05
659.4336548	0.09
675.2183228	100.00
675.8481445	0.71
677.3656616	0.03
684.4310303	0.03
685.7536621	0.17
686.4741211	0.03
702.7389526	0.04
703.6774902	0.02
721.5240479	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.145
Annotation	Hymenoside K
Peak:m/z	Relative Intensity
133.1241150	0.30
135.0981293	0.09
142.5832520	0.07
145.2810059	0.10
150.9812317	0.46
151.8550110	0.03
153.1687012	0.11
161.0513000	0.43
163.7635956	0.05
168.8632507	0.15
170.9843750	0.06
172.9517212	0.06
175.1811218	0.05
175.9855652	0.22
177.0837708	0.46
178.0198669	0.45
179.0390930	13.19
180.0391388	0.27
180.7972717	0.08
189.0200500	0.27
190.9025879	0.23
191.9661255	0.63
193.0177765	4.60
194.0150757	24.44
194.9759674	1.01
201.0394897	0.08
202.8928986	0.18
204.2429810	0.60
205.1643524	0.21
207.1046295	2.38
208.0348511	7.26
209.0260620	100.00
210.1073151	2.83
213.1601257	0.14
217.0927582	0.36
218.9383392	1.58
220.1928101	0.12
221.1850586	1.32
222.2431641	0.17
222.9743500	0.22
229.0091858	0.52
230.5025940	0.10
233.0116272	0.55
234.0509033	0.09
236.0551758	3.86
242.3476257	0.08
245.2158203	0.38
247.2232971	0.09
247.9831543	0.05
249.0903625	0.56
251.1316833	12.94
263.0433960	1.66
271.1790161	0.21
277.9373779	0.08
279.2690430	0.31
281.4357910	0.30
289.2444763	0.11
291.2198486	0.04
293.1256714	0.91
295.1791992	0.14
309.2019348	0.05
316.9045410	0.10
321.2477417	0.91
323.0202637	0.09
325.1707153	0.11
329.2174377	0.54
339.0454102	0.27
349.4354858	0.59
351.9685669	0.14
353.2670898	2.39
354.4961853	0.11
365.3607483	0.08
367.2253113	0.85
368.8563232	0.71
369.5337830	0.05
371.1666565	1.33
372.2481079	6.56
375.0691223	0.07
377.1990662	0.56
378.2807312	0.40
394.0070190	0.09
395.2284241	2.27
398.2898254	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2784
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.2016296	0.08
153.0365906	0.12
170.7729187	0.04
196.0523376	1.32
209.9489136	0.04
214.1473083	1.21
235.2540588	0.02
239.1970978	0.52
240.5210419	0.03
243.2228394	0.05
251.2132263	0.02
259.3781738	0.02
261.3214111	0.17
279.2381287	100.00
279.8511658	0.40
334.7994995	0.03
360.0223999	0.01
361.9164429	0.01
365.5054321	0.02
380.2119446	0.06
383.2856445	0.03
399.1905823	0.01
404.5643616	0.01
413.527771	0.06
415.2703247	0.22
418.0253296	0.02
430.1618958	0.05
432.400177	0.08
440.3251648	0.07
458.1238098	0.04
460.5323181	0.01
461.1513367	0.03
475.5857544	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1383.4253
Annotation	Unknow
Peak:m/z	Relative Intensity
629.4174805	0.06
679.1279297	0.13
689.3058472	0.44
703.3122559	0.08
705.3186646	0.09
707.1566162	1.42
721.2481079	0.49
841.2406006	0.76
865.4970703	0.35
883.3984375	18.12
897.3785400	1.00
999.5037842	0.25
1017.2679440	1.95
1021.4438480	0.14
1059.2391360	100.00
1059.9682620	0.51
1207.4836430	0.12
1212.0864260	0.23
1221.1986080	0.61
1341.6414790	0.14
1355.7498780	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	323.2209
Annotation	(1alpha,2beta,4abeta,5beta,8aalpha)-(+-)-decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-1,5-naphthalenediol diacetate
Peak:m/z	Relative Intensity
93.2157898	0.02
94.0012512	0.11
106.9188614	0.19
108.9625626	0.14
113.0582428	0.04
119.1961060	0.03
121.1472015	0.09
125.1170044	0.17
132.8887939	0.06
135.0473785	0.46
141.0063171	0.03
145.2696686	0.05
147.1490784	0.11
153.0520935	0.23
157.0865479	0.09
160.9939575	0.03
163.1351318	0.11
165.1757507	0.24
167.2337341	0.08
169.1826172	0.06
175.0740967	0.19
177.0977783	0.06
179.0737152	0.11
185.0697174	2.76
186.9181213	0.12
189.2227478	0.38
194.9149475	0.23
199.2943115	0.03
201.5220947	0.09
202.8823547	0.12
209.1146545	0.05
211.1016235	0.10
217.1245728	0.21
219.5304260	0.15
223.2868652	0.11
227.0838013	0.17
231.2851868	0.13
235.2737732	0.05
237.1489258	0.08
241.0698853	0.15
245.3428040	0.08
249.1253967	0.19
251.2412720	0.20
253.1343994	0.17
255.2695618	0.93
256.4588623	0.02
263.4959412	0.13
264.8280334	0.02
273.2138367	4.65
278.3054504	0.06
279.1318359	0.29
281.1186523	0.05
283.1657104	0.08
287.1929321	0.27
291.2749023	22.37
305.2348328	100.00
305.9436035	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1492
Annotation	Lactulose
Peak:m/z	Relative Intensity
112.3575897	0.27
126.9677429	0.43
131.9363708	0.11
144.9092407	1.50
153.9683228	1.61
162.7521667	2.77
166.9894104	0.22
174.9677734	0.29
179.8949585	3.64
180.8183746	0.66
182.0473633	0.62
183.2238770	0.07
187.8300934	0.39
197.9608154	2.24
213.2430420	0.29
223.0010376	0.35
227.9375305	0.09
241.0670471	0.60
253.1811218	0.05
258.3212280	2.17
259.0217285	3.61
270.9379578	0.20
275.9586792	1.29
276.9322205	3.10
287.8730469	0.45
288.9232178	8.88
296.2649536	0.22
303.3246155	0.29
305.8894348	0.74
306.5486450	8.95
307.2113342	3.19
315.9974365	0.67
319.9661865	0.21
322.9635620	1.86
324.7838440	100.00
325.5862732	0.10
327.0815125	0.19
330.1224976	0.38
332.1466675	0.17
338.4062195	0.15
342.2342224	10.59
342.8934326	62.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1657
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
149.2687683	0.07
160.8553314	0.04
192.9999390	0.34
203.1652527	0.11
203.9815369	0.09
215.3608093	0.06
242.8936768	0.17
249.1606140	2.90
255.2251892	0.13
256.3847046	0.27
267.3519287	0.21
291.0389099	0.29
296.2840576	0.11
299.2457275	0.07
305.2176514	0.30
309.2225037	2.55
311.0830078	0.22
325.1025696	0.39
329.1777344	0.07
334.1464539	0.12
339.0671387	0.13
341.2944946	0.08
343.0974731	0.28
349.2610474	2.62
350.0538330	0.19
352.6157837	0.16
367.2706299	100.00
369.5513000	0.13
372.1264648	0.40
373.3080444	0.16
383.3652039	0.07
384.9445190	0.51
387.4026184	0.14
395.1457825	0.49
399.2553406	0.23
413.2364807	0.27
416.7015686	0.18
427.1106873	0.43
438.6237488	0.40
439.4890137	0.15
440.7915344	0.46
446.4352722	0.26
448.2177124	0.20
449.1581421	0.47
450.1824036	0.29
455.2333069	0.14
458.8108826	0.15
463.3891907	0.15
467.3288269	2.52
468.3276978	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	415.32
Annotation	DIOSGENIN
Peak:m/z	Relative Intensity
128.9132385	0.41
139.3963623	0.27
151.0168762	0.21
154.9374695	0.27
156.8904877	0.38
159.089859	0.22
166.6188049	0.45
170.8556366	1.00
173.2190247	0.51
196.9780426	0.38
211.0876465	0.73
212.9808044	0.35
222.8667908	0.34
226.9544067	0.34
229.2622986	0.53
241.2850647	1.52
242.1773682	0.41
243.2214966	1.48
251.1692505	0.38
253.2265625	21.46
255.1773987	0.99
271.1983032	100.00
273.5737915	0.98
283.2354126	4.00
285.2422485	0.99
287.0913696	1.80
293.2294312	0.35
297.0167542	0.56
301.2027893	0.99
315.2986755	0.66
326.0120239	0.43
327.1233826	1.83
327.9171448	0.59
328.9864807	1.13
337.2963867	0.38
355.4624023	0.36
364.2415466	0.68
369.0523376	0.99
379.500946	0.40
397.4071655	8.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2779
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
139.7393646	0.17
153.0017242	0.19
171.0638123	0.04
196.0988312	2.00
214.0911255	0.96
255.2250061	100.00
255.8359985	0.20
350.1981506	0.07
391.3812256	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.9993
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9493713	10.42
195.9860382	3.70
196.9923553	0.69
200.7648468	4.50
213.9074097	0.96
223.9181061	100.00
231.4893188	0.26
241.8714752	9.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.1541
Annotation	Tetraphenylphosphonium
Peak:m/z	Relative Intensity
112.7992172	2.58
130.8728333	22.87
158.7820740	9.98
165.6931458	0.61
176.8939362	100.00
179.9913940	13.11
180.7855835	0.61
186.8591919	0.39
193.9042053	81.38
194.6369019	0.19
197.7280426	0.88
226.9239502	1.42
265.6300659	1.42
267.0853577	0.75
289.0658875	0.20
310.3462830	1.12
314.2952271	0.22
320.7145386	0.57
328.0192261	0.65
332.7380371	0.19
337.0437012	0.43
338.1119385	4.56
338.7286377	8.50
339.3357849	2.00
348.3443909	0.91
349.3209229	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.9742966	0.57
109.2841339	1.30
117.023674	0.50
121.2926331	0.50
122.8459091	0.38
135.024231	1.93
137.0188599	0.25
138.9066467	0.54
142.8835144	0.32
145.0041504	0.24
149.0641174	3.00
150.9195557	0.29
153.2598572	1.13
154.217514	0.23
156.932373	0.77
159.0814514	0.25
161.1676636	0.31
162.908783	1.51
171.1073761	1.65
173.1293335	0.17
174.6210327	1.94
177.0115662	0.49
183.0373077	0.57
184.9653015	1.83
187.0370941	0.67
188.9568787	1.03
191.1323853	0.34
196.8492126	2.16
202.7001495	0.69
211.04245	0.34
217.419281	0.48
218.353241	0.38
226.8123169	0.85
229.1042786	1.55
231.0749207	1.50
239.0066223	0.27
242.9966736	0.63
245.2043457	0.90
247.1270752	4.08
255.2826538	0.40
257.2003479	1.24
258.9414978	1.02
267.3685303	0.67
268.9267883	0.58
279.2349854	1.07
281.2191772	0.50
285.1902466	1.09
291.4508362	0.86
292.4005737	0.34
295.1289673	0.92
296.2849731	0.23
298.6685181	0.35
305.2929382	2.41
323.2304077	100.00
323.9544067	0.91
340.9103088	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.9247
Annotation	Unknow
Peak:m/z	Relative Intensity
245.0167084	0.12
273.1457214	0.10
357.0998230	0.06
358.0982056	0.11
359.0528564	0.18
426.9901428	100.00
427.5954285	0.24
428.7886658	0.28
462.7588196	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.0394
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9083252	5.66
198.9536743	0.89
216.8447113	0.33
228.9273987	1.92
245.3152161	0.02
269.6307983	0.04
271.1313477	0.21
272.9367065	100.00
310.0706787	0.02
322.3080139	0.06
332.9187927	0.02
340.1487427	0.08
341.2222900	0.02
343.3395081	0.06
371.0392456	0.07
373.1513672	4.39
387.3514404	0.04
395.3156738	0.03
408.8361206	0.06
413.0742493	0.05
414.7021790	0.10
426.4506531	0.05
439.8372498	0.07
441.1469116	0.30
443.0174866	0.05
451.2432861	0.02
468.2222290	0.20
469.0704651	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1187
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
107.0026398	0.02
113.0390320	0.72
114.8171310	0.19
118.9380798	0.51
124.9306641	0.33
130.9847412	0.40
133.2018433	0.02
134.1656342	0.03
135.8851929	0.02
143.0115051	0.77
149.1445007	0.11
151.1436768	0.04
161.0911255	0.37
161.9776611	8.88
176.9940643	100.00
178.9439392	4.29
180.3732758	0.08
193.1237030	0.04
195.0753479	8.20
199.3532715	0.08
234.8978577	0.02
237.1859131	0.06
251.0969849	0.02
263.2638245	0.03
266.8910522	0.06
285.9704590	0.04
293.9573669	0.07
301.1746216	0.04
311.1751709	0.12
315.1059875	0.08
323.4913330	0.10
337.3084412	0.05
338.5191650	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.2179
Annotation	Desacetylvindoline
Peak:m/z	Relative Intensity
151.84729	0.10
194.1969452	0.62
201.846756	0.36
209.4121246	1.03
215.9340973	0.40
227.2686768	0.17
251.1390381	0.38
253.2813721	0.32
272.8984985	0.66
289.9109497	0.93
293.1916504	0.30
299.3712158	1.55
310.9161072	0.35
319.0148926	0.66
329.2189941	0.71
334.1976013	0.37
339.3023071	0.24
353.187439	100.00
353.8455811	0.19
355.3815918	0.59
367.2118835	1.98
367.8636475	1.08
369.0655518	3.50
370.0144043	1.11
371.4841003	0.86
376.1018982	0.33
377.3338928	2.25
378.1451111	2.57
383.1000671	0.60
384.2537537	0.54
395.2972107	3.78
396.3063049	0.20
398.9751587	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	558.2637
Annotation	Unknow
Peak:m/z	Relative Intensity
160.0398560	6.05
172.6409454	0.11
174.0211945	0.25
176.9964905	16.21
184.2209167	1.08
202.1066132	3.38
220.0600586	100.00
234.1855011	0.27
325.0814209	0.06
328.1463013	1.83
346.1461182	1.93
364.1174316	7.68
380.8024292	0.70
382.0156860	65.93
395.5054932	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.31
Annotation	Unknow
Peak:m/z	Relative Intensity
242.1622772	0.13
277.3318481	2.40
431.2742920	0.07
457.4866943	0.09
502.3163452	100.00
503.4185181	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.99
Annotation	Unknow
Peak:m/z	Relative Intensity
232.5083771	0.01
308.9896240	0.09
346.9774170	0.20
366.0547485	1.87
403.2380981	0.08
407.1492310	0.08
423.3630981	0.01
482.8056030	2.23
483.7966919	0.04
501.9431152	0.54
521.0230103	3.92
524.7819214	0.02
539.8596802	1.61
540.7179565	0.02
543.3115234	0.07
544.8428345	0.02
558.9426880	100.00
559.5867310	0.13
578.8379517	0.14
581.0604858	0.04
605.0259399	0.03
615.0488892	0.07
621.1163940	0.02
625.0148926	0.03
628.9181519	0.02
629.5629883	0.11
667.6149292	0.07
671.9763794	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.292
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
184.2905426	0.11
198.1498871	0.19
207.9248199	0.06
228.3429565	0.02
243.2544250	0.04
245.4212952	0.10
263.1900635	0.02
306.3725586	0.38
337.2911987	100.00
337.9385071	0.34
417.0533447	0.12
435.0126648	0.04
460.2037659	5.52
460.8444214	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	452.2763
Annotation	PE(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
197.8744965	0.14
215.0514526	0.07
252.6690674	0.03
280.2562866	0.43
311.2508240	100.00
311.8619995	0.62
332.5557861	0.03
353.2544556	0.10
388.3641052	0.09
391.0321960	0.09
409.3872986	0.03
417.0398865	0.11
433.6922607	0.33
434.3160706	5.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1815
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1897888	0.12
139.1211395	0.02
148.7591553	0.03
157.0134888	0.36
158.0845337	0.14
164.0908966	0.08
168.8657227	0.09
175.0946045	1.28
176.0735779	0.13
193.0771179	3.73
194.1477661	0.19
197.8270111	0.02
204.9325714	0.10
213.2554169	0.04
223.1886292	0.04
224.0117950	0.01
231.1604614	0.51
232.0812531	0.14
247.2426758	0.05
249.1127625	7.24
250.1663208	0.57
267.3290710	0.04
268.3730164	0.07
272.7680664	0.03
288.0582275	0.02
289.2952881	0.14
291.0944214	1.76
292.1668396	0.28
305.5193481	0.02
306.8063965	0.02
309.1985779	1.39
310.0432739	0.12
315.1400757	0.24
317.5879517	0.02
319.5574341	0.01
321.3615112	0.05
322.0413818	0.03
333.2173462	10.01
334.2083740	1.24
349.2942810	1.76
351.2251587	66.51
352.1822510	11.21
356.1059570	0.18
357.2443848	0.02
358.4205017	0.08
360.1130676	0.03
360.8971558	0.01
364.0497437	0.05
365.1901245	0.01
367.1854553	2.15
368.1736145	0.64
373.1640320	0.11
375.2585754	1.94
376.3384094	0.13
389.4200745	0.02
390.1632385	0.11
391.2433167	0.12
393.1960449	100.00
394.2067566	16.15
404.5232239	0.21
405.3794250	0.07
406.2755737	0.11
407.0879822	0.13
408.2298279	0.08
409.3811646	0.07
410.4173584	0.04
414.1380310	0.27
415.0210266	0.17
416.2023010	0.18
431.3103943	0.02
433.2128601	42.84
434.2045593	10.05
434.8360291	0.01
436.2372742	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.3098
Annotation	PE(20:2(11Z,14Z)/0:0)
Peak:m/z	Relative Intensity
151.0466614	0.02
153.0321198	0.07
168.1068573	0.03
223.9334869	0.16
242.1885376	1.92
243.3844910	0.04
261.3084106	0.24
279.2585449	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	701.9995
Annotation	Unknow
Peak:m/z	Relative Intensity
231.8693542	0.98
317.9624634	0.26
415.9758911	0.23
425.1209106	8.55
427.1638184	0.20
463.3421021	0.12
470.7638550	0.31
489.5861816	0.44
508.8709717	0.39
545.9784546	0.78
547.2006226	0.11
564.7718506	0.09
600.9536743	0.18
608.9607544	0.44
610.7195435	0.09
615.8726807	0.19
617.9174194	30.70
618.5491333	0.87
619.1923218	0.15
627.9765625	0.09
655.9774780	100.00
656.6125488	0.94
678.9617920	0.29
682.9926147	0.08
701.4156494	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1491
Annotation	Lactulose
Peak:m/z	Relative Intensity
103.9629288	0.16
127.0305710	0.24
144.5188904	1.30
145.1352234	1.47
162.3973236	0.58
163.1947632	0.55
179.4274750	0.13
180.0283203	4.39
197.9978333	5.72
205.1479340	0.31
240.8943176	0.10
246.5631409	0.26
258.5609741	3.21
259.2200317	0.79
270.7264404	0.30
271.9897461	0.50
275.1115112	0.48
276.5973206	4.40
277.2532959	0.71
280.4197998	0.14
287.3319702	0.27
288.7944031	17.70
300.0227356	0.19
305.1570740	0.54
306.7262878	15.60
307.4177856	0.07
315.9057007	0.11
324.2693481	21.41
324.8954468	97.31
325.5338440	0.38
327.8996887	0.45
336.8748169	0.28
340.6938477	0.14
342.7908325	100.00
343.5997009	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2939
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
152.8227081	0.06
167.8931580	0.07
195.9808044	0.04
209.0082397	0.03
214.1432190	0.10
217.4585571	0.03
223.1171722	0.03
224.1691284	0.18
227.8470459	0.02
231.1675110	0.01
235.1348572	0.06
242.1717224	2.70
253.2443542	100.00
279.2291565	0.35
280.3152771	1.60
281.1837463	0.09
295.2325439	0.04
307.1927795	0.08
327.6000977	0.22
345.9560242	0.03
347.2937927	0.03
364.2181702	0.01
393.3476257	0.05
398.2287903	0.02
404.4812622	0.02
409.2202454	0.07
414.2111511	0.10
417.2748108	0.04
418.5636292	0.03
432.4877930	0.03
433.3403320	0.03
435.2196960	0.06
436.1630554	0.09
440.3414612	0.08
442.2811584	0.08
443.3228149	0.05
460.1597290	0.03
462.7373962	0.03
477.4446106	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	309.2418
Annotation	Yaretol
Peak:m/z	Relative Intensity
96.82634735	0.35
106.8239441	0.42
117.1114044	0.40
121.1434326	0.53
123.1046982	0.54
124.9935837	2.12
134.74617	1.78
140.9784241	1.09
152.8909302	6.05
157.0960693	3.78
161.0402222	2.36
165.1108704	0.45
170.9008026	1.09
172.9241638	0.84
175.0275421	2.61
184.9944916	29.87
193.01297	3.80
195.0722351	0.84
198.9097595	0.54
202.5176697	2.97
203.20401	3.49
206.8461304	2.96
209.2335815	0.65
219.2549438	0.52
221.2818909	0.78
225.1175232	22.94
237.2012024	1.46
239.1478577	5.47
241.1015015	8.96
247.0560303	0.38
251.241333	1.17
259.2420349	4.83
264.3870544	0.84
266.5011292	0.96
273.2067261	1.67
277.1717529	100.00
277.9953003	0.37
281.4694214	1.40
288.9446716	1.18
291.2315674	89.89
292.0155029	3.51
293.2859802	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	732.38
Annotation	Unknow
Peak:m/z	Relative Intensity
215.9919739	0.16
226.8556061	0.06
227.8429260	0.11
228.9012299	0.09
240.9654846	0.38
242.9931946	0.14
252.8874969	0.09
256.1566162	0.12
256.9571228	0.21
260.9685364	0.04
265.2683105	0.08
277.0161133	0.08
280.4283447	0.04
281.0430298	0.21
283.7751160	0.07
310.7929077	0.03
317.3055115	0.08
337.1218872	0.30
339.2259521	0.18
340.2722168	0.04
343.1801758	0.11
346.4331665	0.03
351.6177368	0.08
365.2398682	0.04
381.2087402	0.05
384.7149658	0.07
401.2382202	0.20
409.2924194	0.17
415.4395752	0.04
435.2337646	0.10
436.8785400	0.12
439.2296143	0.84
444.6946411	0.03
450.3314209	0.24
451.5169678	0.17
452.2958374	1.17
454.1699829	100.00
456.9216309	0.30
461.2329102	0.05
463.6651001	0.04
465.0491943	0.21
468.0782471	0.09
468.6856689	0.21
477.2612305	1.33
478.2443237	0.07
479.2953491	5.04
480.5496216	0.19
481.3782959	0.55
482.6990356	0.20
488.2282104	0.20
490.1793823	0.17
493.3338623	0.09
497.0986938	0.35
498.4510498	0.08
503.5603027	0.09
507.4453125	0.24
520.3247681	0.06
521.5573730	0.27
522.7984619	0.17
523.5046387	0.07
529.0368042	0.13
531.2295532	0.18
535.5911255	0.25
547.2756958	0.36
549.5137939	0.19
550.5829468	0.07
554.3286133	0.10
569.5442505	0.05
577.4801636	0.09
579.6364746	0.13
580.3228149	0.09
581.3439941	0.06
583.1519165	0.07
589.3674927	0.05
600.2491455	0.06
603.7702026	0.13
619.5155029	0.27
625.5120850	0.06
628.9573364	0.03
633.7320557	0.12
639.4230957	0.26
642.5797729	0.06
644.5986938	0.05
645.5872192	0.06
647.9856567	0.32
650.7471924	0.06
668.2296143	0.07
669.7354126	0.16
671.2470703	0.47
673.5311890	0.03
674.3541260	0.06
678.4332886	0.13
685.6315308	1.86
686.4413452	1.31
687.3807983	0.20
688.5982056	0.87
695.5994263	1.17
696.4094238	0.57
697.7092896	0.05
699.6820679	0.05
713.5191650	1.03
714.5505981	0.84
715.4833374	0.77
716.8521118	1.02
717.6306152	4.16
722.3776855	0.06
729.5736694	0.13
731.4180908	4.12
732.6559448	0.98
733.5786743	3.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.1194763	0.02
196.052887	0.15
214.1078949	1.19
261.171936	0.03
279.2272644	100.00
279.8608704	0.34
413.0321655	0.01
415.3855896	0.03
457.7601624	0.04
458.5796814	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	2,4,6,4'-Tetrahydroxy-2-benzylcoumaranone 6-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
171.0749969	0.15
177.9913025	0.08
178.9179382	1.12
180.1549072	0.18
193.1930542	0.31
196.9453125	0.18
199.1862488	0.27
201.2363129	0.39
206.8480682	0.61
210.9030457	0.21
215.1319122	0.46
222.9326172	0.18
241.0314331	0.40
243.3027344	1.18
251.1289368	0.37
256.0454407	0.31
259.0845642	37.97
259.6980896	0.12
269.1151428	58.61
273.0509644	0.16
283.1381531	0.19
285.1694031	0.20
285.8022461	0.34
287.0527954	100.00
289.0072021	0.63
291.2872314	0.09
292.303894	0.12
295.0786133	0.13
304.3398132	0.11
306.121521	0.25
309.0155029	0.17
311.1961365	1.87
323.1820068	1.77
324.1661987	0.78
325.389801	0.12
329.1897278	0.53
331.2253723	0.32
332.3126831	0.19
339.136261	0.14
341.949646	0.20
347.2857666	0.18
361.1939087	0.53
363.2371826	0.44
369.4375305	0.15
371.2956543	0.16
374.4683838	0.09
377.3611755	0.91
378.3925781	0.34
382.393219	0.16
387.3960571	0.56
389.4342041	0.43
402.2393494	0.11
402.9796448	0.48
404.428772	0.58
405.3831482	0.67
407.6143188	0.35
411.182312	6.09
412.1687927	2.41
413.2319641	1.18
420.4182434	0.67
421.3493958	7.81
431.1305847	14.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1345
Annotation	Syringin
Peak:m/z	Relative Intensity
109.0789948	0.05
112.9689560	0.71
114.6661377	0.08
125.0462189	0.06
132.9445343	0.08
134.0444031	0.24
143.0510101	0.05
147.7929382	0.09
149.0936432	0.11
149.9111328	0.06
154.7466431	0.14
159.0079651	0.52
160.9654236	2.90
163.2646484	0.06
165.2193604	0.12
169.0742798	0.02
173.0804138	0.08
174.9610596	0.04
175.9649048	0.44
177.0496826	0.79
178.2983398	1.57
179.1194458	3.87
180.1247253	0.42
181.2114410	0.07
185.1158142	0.07
187.2405090	0.33
189.1038208	0.16
190.9711914	0.64
192.0793152	1.62
193.0525970	4.16
193.9893036	18.34
195.0428314	2.28
196.2436218	0.11
200.3488312	0.06
203.1586151	0.21
204.0323792	0.18
205.0788116	0.84
206.1327515	0.09
206.9712219	2.77
208.1906891	14.57
209.0557556	100.00
210.0612488	9.68
213.0979919	0.11
215.1120911	0.05
217.1531067	0.53
217.9823914	0.58
218.9365540	2.37
219.5706482	0.29
221.0689697	1.92
221.8175659	0.17
223.0073853	0.59
225.2115784	0.12
228.9787903	0.39
231.2460022	0.26
233.0499573	1.61
234.2409668	0.11
235.9901733	8.86
239.7194519	0.25
243.0538635	0.08
245.1293640	0.62
247.1661072	0.56
248.0333862	0.41
249.0428162	1.00
251.0369568	34.29
251.8009949	0.03
261.5737610	0.14
262.5690002	0.50
263.1869507	4.40
266.1127625	0.07
268.0887451	0.08
269.3215332	0.10
278.9310913	0.10
280.2727661	0.33
281.2245178	0.78
287.3063965	0.06
290.5287170	0.11
291.5088501	0.19
292.2854919	0.18
293.2064514	0.66
297.0471191	0.05
298.1861267	0.11
305.0908813	0.03
307.1114197	0.41
309.3848267	0.04
311.3312378	0.32
312.1006775	0.17
312.9807129	0.16
324.2427979	0.10
325.1044922	0.48
326.3318481	0.17
327.2406006	0.18
327.8599854	0.06
330.2264404	14.56
335.1442261	0.39
336.0792847	0.53
339.2432251	1.34
341.3551331	0.40
343.1832886	0.38
351.1086426	0.17
353.2659302	0.74
356.1141968	1.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	376.16
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
136.9748383	1.73
178.8742523	0.76
179.9070435	0.17
183.2223206	0.20
192.9547119	0.51
196.8045959	9.33
199.0956421	0.24
223.1083069	0.79
224.0783081	2.54
251.1666870	1.90
253.2189331	0.24
291.2364502	1.51
299.6692505	4.19
303.4914246	0.29
305.1320801	2.29
308.1320190	0.82
312.1626892	7.21
318.0953979	0.60
320.1815186	1.14
322.9949951	1.06
324.2786255	0.65
329.9689636	0.60
331.5017395	0.74
333.1018066	0.42
339.7241821	2.79
344.3358765	2.04
345.0271606	0.17
353.3216858	0.38
357.5879822	0.15
358.8753967	1.31
368.1306458	100.00
368.8739929	0.64
369.5951538	0.77
370.3688354	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.21007538	0.48
99.14746094	0.23
111.0059967	1.32
121.0830917	1.16
122.9661789	0.31
125.0117645	1.29
127.0234833	0.86
128.8887329	0.66
136.8873749	0.21
139.1181335	1.74
149.1604309	0.63
152.9776611	3.30
163.2332153	0.62
164.2146606	0.64
166.7010803	1.79
168.9672699	4.36
177.2191772	1.59
178.2136841	0.56
181.9771729	0.24
188.7968292	0.23
193.2037354	1.11
194.9941406	2.62
197.039093	0.18
202.9210968	1.96
204.5736389	1.23
207.0488281	3.09
211.3029175	1.31
212.8912354	0.64
221.1561584	2.81
223.2731018	0.54
231.3576355	0.49
236.968811	2.39
239.1499023	0.74
241.3348694	1.34
247.3009949	0.87
251.1312561	3.82
253.2241211	4.17
265.2835693	0.49
267.8646851	1.02
268.9906006	1.42
275.3736572	16.46
283.1882324	2.19
293.2059326	100.00
294.0774231	0.80
302.270874	1.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.3629
Annotation	Unknow
Peak:m/z	Relative Intensity
156.2176056	0.12
161.4322510	0.18
163.3251953	0.25
164.9209900	0.29
193.0704651	0.25
239.2765503	0.11
245.2415161	2.72
263.2971802	10.54
267.0951538	0.37
273.1052856	0.21
281.5473633	0.48
299.2543335	0.68
337.2429810	6.02
355.1255493	67.47
355.7573853	0.37
366.9054565	0.42
393.3760376	0.24
448.8104858	0.26
459.3393555	0.07
463.6030884	0.22
466.6098633	0.11
473.0545044	0.18
481.2515259	1.51
489.5394897	0.36
499.3562622	100.00
501.4257202	0.52
515.4600220	4.81
516.3052979	16.59
516.9953003	37.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	811.0623
Annotation	Unknow
Peak:m/z	Relative Intensity
231.9086609	0.99
240.2646637	0.22
251.9523773	0.50
310.2730713	0.08
386.6937866	0.80
425.0624390	35.31
444.0256958	0.13
462.9556274	4.18
539.3007202	0.80
579.8924561	0.38
594.0297852	0.12
598.5786133	0.26
599.1790161	0.73
617.8966675	100.00
618.5999146	0.81
642.6022339	0.74
656.0770874	61.69
732.9245605	1.27
764.2993774	0.23
787.4776611	0.80
790.5213623	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	619.2163
Annotation	Briaexcavatolide K
Peak:m/z	Relative Intensity
179.1783905	0.14
232.1382141	0.12
269.2588806	0.31
277.2998047	0.11
319.2576904	0.30
329.3610840	0.12
333.5258179	0.05
341.2905884	0.59
369.3682861	0.04
401.3308105	0.32
431.5523071	0.33
433.6740723	0.18
456.2640991	0.25
467.0479126	0.30
476.3259888	0.11
481.2080078	0.11
493.2055054	0.07
495.4012451	0.26
498.2597046	0.41
499.3817139	0.70
502.2073975	0.29
503.3627319	0.17
507.5049438	0.07
523.1930542	0.30
531.2509766	0.11
535.1503906	0.20
544.0673828	0.19
547.9237671	0.20
558.2803955	0.19
558.9196167	0.09
561.1091919	0.18
566.4760742	0.47
569.4537964	1.08
572.4425659	0.29
573.1060791	0.50
574.7782593	0.71
580.9937134	0.13
583.3929443	100.00
584.1728516	0.14
586.3297729	1.03
587.3121948	0.40
587.9265747	0.22
589.9671021	0.39
600.0783691	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1064
Annotation	Unknow
Peak:m/z	Relative Intensity
154.2550812	0.23
161.0134888	0.08
213.8317108	0.04
215.1739502	0.04
220.9673767	0.06
222.0512085	0.46
231.0890503	0.09
240.3957214	0.17
241.1216431	0.08
253.0447083	0.05
287.3784180	0.07
299.2240601	0.03
305.5577087	0.13
326.1396790	0.02
329.6765747	0.03
331.1815186	100.00
333.4876709	0.09
341.1754150	0.22
346.5970764	0.14
349.1059875	0.08
357.0339050	0.05
358.3649902	0.07
359.0695190	0.28
359.9364319	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.3981
Annotation	Denin
Peak:m/z	Relative Intensity
260.8712158	1.82
277.2374878	5.04
292.9080505	0.24
294.6916809	2.45
317.3846130	0.45
321.0157471	0.69
335.3307495	0.92
349.1364746	1.05
353.3383789	0.49
354.4941406	0.24
358.3090210	72.35
359.1893921	0.58
376.6980591	0.69
391.1811523	1.45
455.4487305	0.78
456.4408569	0.53
493.6690674	0.60
497.6860352	2.07
498.3671875	0.80
499.3324585	2.53
514.4011230	0.42
520.3613281	4.43
534.5307617	16.35
537.6361084	0.42
553.3630371	4.00
615.4978638	100.00
659.3019409	0.80
660.1843872	0.62
661.3200073	1.15
665.5697632	2.03
678.0164185	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.5623
Annotation	Unknow
Peak:m/z	Relative Intensity
275.4390869	0.16
277.3330383	11.75
278.3201599	1.06
474.2695312	100.00
475.3277588	12.81
476.4177246	0.09
477.5381470	0.22
651.4320679	0.12
688.4365234	0.23
805.9423218	0.07
894.8103638	0.22
946.4251099	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.2545
Annotation	Unknow
Peak:m/z	Relative Intensity
229.2847748	0.23
251.1247711	0.14
268.0702209	0.24
291.1361084	0.82
336.0805969	0.85
337.2503052	0.51
354.1936035	8.51
395.2199097	1.20
411.0755615	0.69
413.0304565	1.22
465.3471069	0.17
483.2499390	14.47
494.9374390	0.14
516.1176147	15.38
553.5001221	0.10
581.2608032	0.27
627.0863647	0.26
645.1911011	100.00
646.8368530	0.23
678.1221924	7.31
709.2136230	0.07
762.5916138	0.22
775.9121094	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
130.9704742	0.09
179.0163422	0.62
197.1314087	0.77
215.0018768	7.27
341.2220459	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.2838
Annotation	Ceriporic acid B
Peak:m/z	Relative Intensity
105.2015533	0.27
107.0831604	0.19
108.9667206	1.01
118.8487244	0.58
121.0512848	0.37
123.2802963	1.22
129.0521240	1.04
133.1568756	0.50
135.0714722	2.73
137.0209045	0.08
139.1406860	0.70
140.7825928	0.82
142.9999695	0.34
146.8821106	0.17
149.1073914	3.67
151.0746613	1.59
152.7985687	0.24
157.1623840	0.70
161.1462402	1.46
163.1549683	1.95
164.9858398	1.47
167.2005615	1.38
169.0101929	0.82
170.7337341	0.91
171.5060272	0.42
175.0560760	1.67
177.0255585	1.15
179.1064148	1.70
180.9832458	1.33
185.1697845	0.44
189.3072205	1.07
190.7406311	0.22
197.0722351	0.16
198.9959259	0.47
203.1303711	0.67
207.2148132	0.68
209.2550659	0.31
210.7621765	0.84
217.1216736	0.72
221.3930664	0.25
223.1856689	1.15
225.2255554	0.38
231.1688232	0.14
233.1737671	0.57
239.1723938	0.28
245.2716675	35.20
247.2655945	4.16
251.2583618	0.23
253.0746460	0.36
257.0663452	0.59
259.3616028	0.13
263.2711182	90.04
265.2192383	13.51
267.3005981	0.21
271.0736084	0.41
273.5391541	0.47
281.1910400	11.65
283.3786621	1.59
285.0908203	0.82
287.1705933	0.13
298.8233032	0.48
299.4425354	0.38
305.2385864	0.28
308.9016418	0.23
313.0319214	1.40
313.8144531	3.14
314.5504150	0.71
315.6481323	0.15
319.3958130	2.23
326.3471069	0.52
337.2901611	100.00
337.9225464	0.35
353.7298584	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2654
Annotation	Blumenol C 9-O-(4'-O-glucosyl-beta-glucoside)
Peak:m/z	Relative Intensity
179.0254822	0.04
188.2004395	0.03
219.3010254	0.07
221.0020905	0.06
236.9033813	0.13
239.9744568	0.04
245.3007507	0.03
270.9822998	0.05
290.0568237	0.12
305.3769531	0.03
315.4571533	0.07
324.1925049	0.13
337.1175537	0.10
341.7761230	0.22
342.5390625	0.38
343.2716064	0.03
345.1502686	0.06
371.1893921	0.06
373.3011475	0.04
379.9909058	0.06
385.9376221	0.04
393.6072388	0.04
399.1380005	0.02
403.2647705	0.04
408.3535156	0.12
416.1085205	0.36
417.3475342	0.19
422.3686523	0.03
426.6179810	0.06
449.4172974	0.04
451.0739136	0.08
461.0390625	0.06
463.4743652	0.05
480.8611450	0.25
488.6893311	0.02
491.1463013	0.27
494.9199219	0.06
521.3777466	0.07
533.2853394	100.00
535.3964233	0.15
543.0684204	0.15
548.4882202	0.08
551.8596802	0.17
560.3359985	0.12
561.1502686	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.2454
Annotation	S-Decyl GSH
Peak:m/z	Relative Intensity
136.9191895	0.09
151.8530579	0.06
153.0817566	0.07
155.1303406	0.05
179.0963135	0.04
189.0163116	0.04
193.9455719	0.28
212.0909424	0.07
215.0777283	0.45
216.1295319	0.13
218.9048767	0.04
231.2936707	0.24
236.3668213	0.14
245.0852051	0.18
255.3638916	0.19
259.4984131	0.10
273.3583679	0.09
275.0808105	0.13
276.1939087	0.45
288.9887695	0.26
294.1656799	0.05
303.2288208	0.16
307.2460327	100.00
307.8854065	0.16
324.0140991	0.10
347.3237305	0.08
358.1486511	0.14
366.8541870	0.20
368.2179871	0.19
370.4479980	0.18
380.9529114	0.27
387.4048157	0.12
388.2760925	0.10
391.3057861	0.14
395.1685181	0.26
401.4504395	0.10
405.0933533	0.12
406.5787048	0.10
412.3843994	0.24
413.0055847	0.13
417.5075073	0.10
429.3074646	0.41
430.3142395	7.86
431.1872253	0.09
448.6386414	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1768
Annotation	Crosatoside B
Peak:m/z	Relative Intensity
149.9885559	0.14
150.9624634	0.11
161.1496277	0.13
175.1041718	0.49
176.0607605	0.53
178.9379578	0.30
192.1335449	0.31
193.1066589	1.20
193.9665527	1.13
195.1374817	0.26
197.9228821	0.05
203.1522217	0.14
235.1211548	0.98
236.1496277	0.17
236.8419647	0.06
261.3646851	0.09
265.1591797	0.39
266.2059021	0.52
287.0415039	0.31
295.2439270	0.22
296.2202148	0.24
307.0983887	0.08
310.2730408	0.21
314.0444336	0.06
316.4180908	0.12
323.3403015	0.09
327.1409912	0.09
329.4138794	0.54
332.9222412	0.06
337.3091125	0.46
341.1221924	0.43
351.0415649	0.29
355.2220459	0.34
357.3053284	0.19
370.2597961	0.05
373.2860718	0.12
387.3004761	0.10
395.2844543	0.86
396.0821228	0.32
401.1192017	0.19
415.3395996	0.14
432.4599915	0.08
445.1592712	100.00
445.8252869	1.24
446.7970276	0.39
448.1439819	0.22
452.9628601	0.37
454.8589172	0.44
463.2729797	0.06
472.4288940	0.29
473.1882935	0.81
474.2793274	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	154.0859
Annotation	Vanillylamine
Peak:m/z	Relative Intensity
130.9504395	0.03
136.9658966	100.00
137.8074188	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	310.0913
Annotation	Inodxyl glucuronide
Peak:m/z	Relative Intensity
115.8034592	0.05
117.1246796	0.15
144.9789429	0.58
148.9260254	0.09
176.9792938	100.00
181.2217407	0.03
194.9970703	0.17
250.1181641	0.06
280.1741943	0.04
291.3618774	0.05
292.3600464	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	911.2597
Annotation	Unknow
Peak:m/z	Relative Intensity
257.2846985	0.12
259.1566772	0.04
265.2026367	0.13
275.3737488	0.03
277.2346802	0.07
278.0489807	0.06
283.5682373	0.06
287.2687683	0.29
289.3263245	0.11
307.3626099	0.04
319.0488281	0.38
320.1776428	0.05
322.9454041	0.11
337.3445435	0.34
353.3177185	0.13
361.0264587	0.18
365.2639160	0.38
366.2357788	0.06
367.3788147	0.10
369.3232422	0.07
370.4263306	0.15
372.2886353	0.03
377.2020569	0.03
379.3090210	0.11
397.2395020	0.18
398.2427979	0.03
409.1966858	0.11
423.2587280	0.04
435.4606323	0.19
441.2866821	0.05
451.6167603	0.10
452.3894653	0.18
455.2977295	0.10
472.3929443	0.11
481.2895508	0.17
482.2481079	0.08
486.5273438	0.09
495.2645264	0.63
499.1860352	0.98
500.4746094	0.38
510.4660645	0.10
513.2714844	4.37
514.2595825	1.25
517.4499512	0.37
518.2431030	0.12
523.2898560	1.14
524.2538452	0.28
527.3402100	1.16
528.3155518	0.28
531.2839355	0.02
532.1956787	0.02
541.2351685	6.43
542.2768555	3.19
545.1889038	0.08
546.3425903	0.04
559.2217407	8.32
560.3025513	3.22
580.3870850	0.12
598.2998657	0.17
613.1889038	0.08
631.8577271	0.16
643.2097778	0.08
657.4193726	1.13
658.5136108	0.48
659.3334351	0.03
661.2435913	0.12
662.2005005	0.05
675.2192993	2.51
676.2525024	1.46
689.1198120	0.69
690.5289917	0.06
693.2830200	1.14
694.2493896	0.89
703.2418823	1.79
704.3367310	0.60
707.2974243	0.25
717.2705078	38.76
718.3729858	15.16
721.2354126	0.12
731.1808472	0.54
732.3292236	0.10
735.2735596	100.00
736.2238159	44.00
736.9197388	0.05
745.3907471	0.20
749.3357544	2.16
750.3196411	0.88
761.5327759	0.10
762.3400879	0.06
767.2073364	0.03
812.8418579	0.06
819.9015503	0.07
834.8605957	0.15
851.1876221	3.28
852.2266235	1.70
867.4304810	0.06
869.2195435	2.32
870.2766724	1.52
875.5432129	0.05
893.2260132	0.05
894.3887329	0.07
897.2860718	0.05
912.0516357	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	193.0506
Annotation	Speciosin D
Peak:m/z	Relative Intensity
96.9121552	0.02
106.9274597	0.23
107.9470978	0.03
117.0032501	3.11
121.0004272	0.06
122.0507050	0.06
123.2081451	0.09
129.0436096	0.06
131.0427551	0.02
133.9369049	100.00
135.0489502	0.05
136.9965668	0.12
145.2408905	0.08
146.8892975	0.21
148.9929199	34.31
151.2382965	0.10
158.9493713	0.08
163.0781403	0.07
163.8327484	0.03
165.0552979	0.23
174.9105682	0.31
178.0225983	2.92
192.4323883	0.03
193.1780853	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.1285
Annotation	Unknow
Peak:m/z	Relative Intensity
150.9311523	13.81
152.0613251	0.17
168.9972534	1.55
183.3761292	0.33
263.1378479	0.25
266.0848389	1.66
273.1725464	0.81
276.9766541	0.43
281.1911926	0.23
284.0283813	100.00
296.0171204	0.66
313.1691284	0.48
328.9837036	2.57
399.9776001	0.23
415.9015808	0.48
427.5538330	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
72.8589325	1.22
92.9422226	0.64
117.798996	0.52
124.0371552	0.29
137.0309296	2.65
139.1510315	0.50
142.7086334	0.76
146.060791	1.13
147.9208679	0.80
149.8699493	0.38
150.7635345	1.43
152.9758453	1.39
159.1280365	0.31
161.0267029	1.15
166.9814606	0.63
168.3330231	0.65
177.1689148	0.43
178.3168945	0.46
179.2545624	1.42
180.1333313	2.28
181.2335663	0.72
183.0641937	1.69
185.0817566	1.09
187.0141449	2.23
188.9841461	1.74
190.9642181	0.26
191.9528656	1.80
195.2046967	1.77
206.0062408	2.70
207.1837006	17.18
208.2274475	2.56
209.2538605	8.61
214.9090424	14.14
221.3515472	1.56
222.1892548	4.32
223.1079865	16.16
224.1014862	3.04
232.2436981	1.22
233.188797	11.38
236.0917816	4.65
251.0800629	100.00
252.1864014	9.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1086
Annotation	2,4,6,4'-Tetrahydroxy-2-benzylcoumaranone 6-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
146.921936	0.09
149.1634064	0.16
152.0927429	0.03
152.976593	0.06
158.1685486	0.02
161.1837158	0.05
162.8177948	0.10
163.7589264	0.04
165.0037689	0.08
174.3677368	0.03
175.0375671	0.08
176.2131653	0.03
177.0674438	0.09
179.1199341	0.41
180.1307983	0.22
199.0319519	0.03
201.282135	0.10
202.0414734	0.07
204.9589539	0.13
207.9575653	0.01
214.998291	0.08
225.183075	0.05
226.0719452	0.03
241.2051392	0.04
243.2087708	1.05
244.2202148	0.20
248.9441528	0.03
258.0110474	0.10
259.0996399	27.84
260.1135864	5.15
261.1667175	0.01
267.3044434	0.04
269.1112061	28.06
270.1947632	5.99
276.4739075	0.02
283.0598755	0.55
284.0596924	0.20
285.1737366	0.11
287.0653381	100.00
288.0697632	21.33
289.3622742	0.03
292.1595154	0.11
293.1123962	0.15
295.2938538	0.05
301.0672607	0.08
311.1915894	1.54
312.0322571	0.43
314.4592285	0.11
323.2292786	0.04
325.7909546	0.11
329.1795654	0.24
329.8487244	0.05
331.1212769	0.02
333.0725708	0.03
334.0014038	0.03
341.1691589	0.08
342.0275879	0.62
343.1951904	0.21
348.1467285	0.03
353.2923279	0.02
354.3062134	0.06
356.1712036	0.04
357.2707214	0.15
361.0198975	0.13
368.7944031	0.06
381.7237244	0.02
384.2494202	0.02
385.2366333	0.15
389.4952087	0.14
393.2173157	0.07
403.2793274	0.23
404.079834	0.15
405.1532593	0.04
406.2171631	0.03
409.2420044	0.02
412.319519	0.06
413.6083984	0.18
414.2367859	0.21
415.4668274	0.03
417.3721924	0.03
421.1385193	3.61
422.1799622	1.89
431.1393127	5.11
432.241333	1.80
433.039093	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9169
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9755402	0.72
245.0324707	0.24
249.1595764	0.02
271.9771729	0.10
272.9695129	3.87
286.0788574	0.03
287.1437378	0.10
288.9155884	100.00
328.9761963	0.12
347.2087097	0.04
356.1522522	0.10
357.0621948	0.15
357.8230591	0.06
358.7127380	0.09
385.0504761	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
232.0009155	0.51
244.2160950	0.26
290.7126465	2.57
316.3983765	0.10
374.8602295	0.43
399.9248657	0.32
434.0314331	0.25
451.4735718	0.22
458.6230469	15.02
490.6885986	0.41
520.2951050	2.45
542.5200195	100.00
543.2717896	0.52
566.7339478	0.49
567.5667114	0.24
579.8760376	1.53
580.9435425	0.16
584.2502441	1.19
603.2940674	1.12
604.0121460	0.05
608.9150391	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.1961
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
146.8427582	0.41
161.0390320	0.05
162.9372711	0.07
164.9742126	14.54
182.0680542	100.00
259.0202332	0.23
288.7222900	0.15
316.1508179	0.09
324.9525146	0.43
332.3343506	0.29
342.9445190	0.10
343.9054565	3.21
344.5103760	0.03
360.6843872	0.45
361.8147583	4.37
370.3305054	0.98
395.1726685	0.15
408.0938110	0.05
428.3838501	0.08
506.2841797	0.18
507.0076904	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1717
Annotation	Malvin
Peak:m/z	Relative Intensity
188.3334351	0.07
190.2002869	0.02
198.2440796	0.06
199.1325989	0.04
203.2528687	0.08
205.1696930	0.04
206.9322968	0.13
209.1428375	0.08
211.1520996	0.19
213.1489563	0.03
214.6152344	0.30
215.2511597	0.06
219.0165558	0.06
220.1039581	0.09
225.4271240	0.06
226.0615845	0.02
227.0508118	0.08
230.0435486	0.06
231.3128967	0.02
232.3847046	0.15
234.1323547	0.37
234.9443665	0.15
241.2896576	0.06
242.1974030	0.35
243.1216125	0.54
244.0473633	0.11
246.0895081	0.04
249.0568237	0.09
250.0830383	0.08
253.1795349	0.18
255.0638733	0.14
256.2464294	0.08
257.1055603	0.11
258.1223145	0.27
259.0419312	1.11
260.2149048	0.17
262.9664001	0.02
265.1636963	0.23
267.2518616	0.03
269.0257874	0.82
270.0692444	0.87
271.1128540	1.87
272.0881653	0.18
273.1293945	0.40
274.2878723	0.15
275.0743408	0.08
277.0932922	0.03
282.2344360	0.06
283.1736755	0.15
284.0926514	0.28
285.0720215	0.48
286.0220032	0.64
287.1589355	3.43
288.1996460	0.63
289.2683105	0.08
293.3511963	0.08
296.1604919	0.08
297.2503357	0.04
298.2780762	0.39
299.1061096	0.33
300.0894775	0.71
301.1157227	1.43
302.2911377	1.02
303.2460022	0.35
304.3690186	0.02
306.2691650	0.06
311.4345703	0.06
312.3663330	0.04
313.3306274	0.31
315.0859985	13.10
316.1007996	3.11
317.2431030	2.34
318.1580505	0.52
319.0862427	0.19
320.1365662	0.03
327.0210571	0.42
328.1181641	0.98
329.1051331	7.44
330.1196289	18.89
331.1760864	3.42
332.4210205	0.15
339.3209229	0.07
340.1077881	0.07
341.2954102	0.24
342.1763916	0.51
343.1715088	6.75
344.1041260	19.90
345.1159058	100.00
346.1241455	26.44
347.1458740	0.21
351.7280884	0.03
355.1177368	0.70
356.0505371	0.18
357.3177490	0.51
359.2900391	0.93
360.1311035	0.75
361.1267700	0.04
366.3629150	0.10
368.3346558	0.09
369.1278687	0.13
372.3063354	0.37
373.1768188	0.09
374.3889771	0.04
381.0245361	0.06
382.3394165	0.18
383.3838501	0.22
384.9842529	0.10
387.1813965	5.12
388.1743774	1.08
393.2193604	0.30
397.5156250	0.11
409.5253296	0.08
415.4075928	0.04
417.1628418	0.50
418.1578979	0.41
427.4442749	0.05
429.1769409	0.17
430.0794678	0.11
446.4719238	0.02
458.7061157	0.07
459.4145508	0.03
471.3067627	0.06
473.4959717	0.04
478.2703857	0.19
480.8872681	0.18
482.3421021	0.02
485.0919800	0.04
491.3828735	0.05
492.2977905	0.08
493.3917236	0.46
499.4407349	0.09
500.3148193	0.11
501.1926270	0.02
507.3123779	0.53
508.1855469	0.23
533.4438477	0.12
558.2732544	0.07
588.7849731	0.05
590.1511841	0.10
592.4658203	0.13
593.2658081	0.05
607.9343872	0.16
608.5540161	0.08
610.4761353	0.05
621.3009644	4.06
622.1786499	1.82
623.5623169	0.08
625.2450562	1.72
626.2842407	0.85
626.8953247	0.05
635.2864380	0.54
636.1519165	0.21
638.1115112	0.74
639.4057007	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.2037
Annotation	Unknow
Peak:m/z	Relative Intensity
179.2877960	0.17
191.1515350	0.19
192.8076324	0.12
204.0544739	0.14
207.0656891	0.06
209.0739746	0.33
218.2146912	0.11
221.9792633	0.35
223.9327240	0.20
234.0611572	0.43
235.8553162	0.13
251.0179443	0.22
252.9801636	0.74
260.9807129	0.38
264.4540405	0.25
265.0643005	0.19
277.0883789	0.48
283.0503845	2.49
292.1557617	0.82
301.2089539	0.30
309.1759644	1.52
330.1317749	0.34
350.4182739	0.46
356.1860962	0.26
362.1475830	0.40
369.6195679	0.26
373.3159790	0.47
374.4122925	0.43
376.9580078	0.54
384.0500488	0.50
386.4411621	0.13
400.9786377	0.64
402.3638306	0.06
415.2332764	0.51
417.2687988	0.50
418.1002808	0.38
421.3106689	0.25
427.3171997	0.30
428.3142090	1.38
430.4495850	0.57
432.5782471	0.46
433.1957397	0.03
444.8295898	1.61
446.2218018	42.63
447.3959961	0.11
454.5056763	0.34
456.3335571	0.44
463.1400146	100.00
463.8025513	0.74
469.4447632	0.18
471.2564697	2.17
474.2604370	0.46
475.0188599	0.11
487.2592163	0.64
488.0249634	0.10
492.1557007	2.60
493.3935547	0.22
494.2222900	0.33
504.1441650	0.27
505.2112427	0.51
541.1378784	0.97
543.7656860	0.63
553.2517090	0.70
563.5216675	0.19
566.2376099	0.08
568.8948975	0.31
571.3222046	1.17
577.3561401	0.19
579.0016479	0.13
581.2377319	0.32
589.2583618	10.57
605.9884644	1.05
607.4344482	20.18
608.3880005	50.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.166
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
130.9643707	0.03
143.1176147	0.04
149.2354584	0.02
160.8969421	0.02
181.9940948	0.04
209.2571716	0.01
210.9924469	0.04
218.2867889	0.03
220.8363037	0.03
239.1615295	0.01
243.9691162	0.06
248.1542053	0.04
251.4416504	0.04
256.1762695	0.02
262.9571228	0.01
278.2674561	0.04
287.0890503	0.02
293.0290222	0.02
295.2213135	0.02
299.2969360	0.02
301.3551636	0.03
303.9325562	0.03
304.9689331	0.06
311.1083374	0.27
315.0695801	0.04
317.2216187	0.05
329.3401489	0.02
343.0487061	0.04
345.5664978	0.03
353.0443420	0.02
370.1284790	0.01
375.5038147	0.08
383.2277222	0.02
401.3286133	0.07
415.2027893	100.00
415.8517761	0.14
417.0285645	0.07
424.0851135	0.23
425.0012512	0.15
426.1116333	0.32
430.3878479	0.01
432.3280945	0.03
443.4873352	0.09
461.2519836	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1918
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
135.1852264	0.03
138.0307007	0.11
142.9793243	0.33
151.4020844	0.04
153.0476685	2.16
159.0777588	0.25
161.0323486	2.50
178.9852295	0.29
205.1460419	2.08
207.9956970	0.03
208.9803772	0.03
215.1977234	0.02
218.9723053	0.03
223.0395508	7.53
223.6705627	0.02
232.0437775	0.03
247.0054321	0.03
251.1358337	0.05
269.1188049	0.57
271.2675476	0.06
284.7855225	0.04
299.1781006	0.03
304.9517822	0.11
307.0557251	0.04
311.0870361	0.05
341.1404114	0.04
343.2597961	0.02
355.3191833	0.08
367.0909729	0.03
370.3506775	0.07
372.3268738	0.03
385.2342834	100.00
386.4744568	0.08
387.3034363	0.54
394.6805420	0.19
395.3913269	0.42
396.0167542	0.04
403.9418030	0.02
413.1493835	0.11
422.3010864	0.32
431.5550537	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	446.2308
Annotation	S-Decyl GSH
Peak:m/z	Relative Intensity
139.9150085	0.17
141.0465851	0.01
151.1912842	0.06
152.3059692	0.02
152.9626465	0.22
158.9497681	0.02
171.0712280	0.02
176.0687103	0.02
177.1509857	0.05
184.0946198	0.04
186.9729004	0.03
188.3626099	0.02
195.9899597	0.42
205.2394714	0.66
206.2653503	0.21
214.0304871	2.63
215.0183105	0.16
218.8436279	0.02
231.0571289	0.28
232.3151398	0.05
241.9196472	0.03
247.2637329	0.69
249.1878967	100.00
250.2231445	18.77
252.1289368	0.05
267.5883179	0.01
269.2665100	0.02
278.3318176	0.02
279.4223938	0.10
292.8522034	0.04
310.9250488	0.03
318.8255005	0.02
327.0950928	0.04
331.2384644	0.03
337.4778442	0.03
346.9812622	0.02
353.2260437	0.02
360.3956299	0.16
362.9984741	0.01
367.6039429	0.06
371.2185669	0.04
374.1651917	0.03
375.4170837	0.02
384.6879883	0.03
388.1194153	0.03
389.4128723	0.05
391.0035706	0.11
400.9933472	0.20
403.1533508	0.06
405.3428650	0.01
407.4100647	0.01
409.1107483	0.02
410.1782837	0.02
411.3563232	0.07
412.2371521	0.33
429.1531067	0.11
430.1902466	0.03
431.1933289	0.08
439.4214478	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.14
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
98.9365616	0.19
126.9281616	1.94
144.7550049	2.72
162.2632446	0.10
162.9084167	5.50
180.0439301	7.72
191.2074280	0.67
216.8398438	0.64
223.0041504	0.35
228.8365479	0.70
235.2279663	0.16
240.3805847	0.59
247.0957642	2.01
252.9999390	1.32
258.3466187	2.76
259.0708008	4.53
271.1144104	8.80
276.6812744	1.17
284.3231506	0.68
288.2482605	9.06
288.9900513	38.97
306.6653748	2.27
307.3097839	0.91
324.9874268	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.3281
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
185.1227570	0.09
202.8818665	0.05
235.1788788	1.17
245.9376984	0.08
253.1659546	6.24
254.1845703	0.77
277.3093872	0.12
279.2926636	52.43
280.3864136	13.94
299.2435303	0.17
366.1641846	0.08
382.6696777	0.06
426.0864868	0.08
433.3408203	0.04
450.2022705	0.07
466.5630493	0.05
472.2809448	0.06
477.2927856	0.07
502.2869263	3.67
515.1776733	100.00
516.1608276	28.72
525.2123413	0.06
526.8073120	0.11
544.2166138	0.07
568.3960571	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0967
Annotation	(2S)-2-azaniumyl-3-(1H-indol-3-yl)propanoate
Peak:m/z	Relative Intensity
86.89306641	0.10
126.0509644	0.10
132.1977844	0.04
132.9330902	0.04
139.1067657	0.05
149.2890472	0.14
150.3306885	0.13
158.6838531	0.03
161.0604095	0.13
168.8227081	0.21
177.1357574	0.12
188.0779724	100.00
196.6647186	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.3643
Annotation	Denin
Peak:m/z	Relative Intensity
219.2109985	0.01
221.2407990	0.00
231.2312927	0.02
235.2070618	0.19
239.0785522	0.01
245.1265717	0.01
277.2544556	0.08
287.2396851	0.07
305.1917725	0.19
351.4317932	0.01
379.4750977	0.01
392.4401245	0.01
397.2036133	7.61
397.8344727	0.01
415.3149414	1.29
452.2984009	0.01
545.3903198	0.02
571.3611450	0.02
622.4586182	0.03
625.8433838	0.01
657.7091675	0.03
675.2240601	100.00
675.9461670	0.34
686.0139771	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.1137
Annotation	Tetraphenylphosphonium
Peak:m/z	Relative Intensity
99.0088806	0.39
100.9068604	3.64
106.2283936	0.25
107.0134659	0.06
113.0139923	7.04
114.9780426	0.79
116.8744354	0.12
118.9482956	6.85
124.9831467	1.27
130.9306030	3.51
133.2497559	0.04
139.0972290	1.18
142.9591827	11.33
148.9309387	1.64
156.9749146	1.61
161.0130310	11.10
172.7153931	0.16
175.0927124	3.31
178.9251404	100.00
181.1883240	0.21
187.0628815	0.19
191.0356598	0.04
198.9937897	0.17
203.3940277	0.07
220.5970764	0.11
228.9767456	0.11
230.5593567	0.07
231.2704773	0.15
245.2478333	0.04
246.9210510	0.34
249.2491760	0.16
258.7010803	0.06
259.3739014	0.04
275.3034668	0.11
277.0377197	12.23
279.1561890	0.28
289.3103638	0.06
291.1710205	0.09
293.2714233	0.14
299.2578735	0.75
301.0392761	0.22
318.9824829	4.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	506.1833
Annotation	Unknow
Peak:m/z	Relative Intensity
163.7504578	0.37
191.3114624	1.68
240.9157257	0.37
249.1774597	0.64
266.4143677	0.71
270.5734863	1.04
272.2875366	1.59
312.0966187	100.00
353.2738953	0.58
379.5340881	1.04
385.0395813	3.44
456.5315857	1.40
464.9688416	0.24
474.5077820	8.55
475.1290894	0.61
488.2127991	6.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.17
Annotation	Glu Pro His
Peak:m/z	Relative Intensity
111.0348663	0.41
151.1615601	0.45
160.0956421	3.17
176.8604431	6.42
192.0454254	1.82
202.0612488	2.77
202.8384705	0.80
213.1893311	2.43
220.057373	17.06
231.2386169	1.58
235.1633911	1.31
251.8108521	2.77
253.2976074	0.69
263.34375	0.70
277.1176758	0.91
287.3119507	1.84
291.7684326	0.42
296.3453674	1.15
300.8327942	0.98
309.1331177	5.51
328.181488	3.89
336.3871765	0.37
337.211792	2.54
341.2106628	1.25
346.1132507	6.75
353.1891174	0.85
364.152832	100.00
364.870575	1.65
373.7944641	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1868
Annotation	Unknow
Peak:m/z	Relative Intensity
134.6112976	0.09
143.1997986	0.20
151.0555267	0.15
153.3582306	0.18
161.0681305	0.27
163.2400055	0.35
178.9110260	0.13
188.8590698	0.13
195.2785339	0.10
201.1854553	0.44
203.2233734	0.10
204.1066589	1.16
206.9605713	1.35
219.1407471	2.63
221.2073364	0.11
225.1855774	0.15
254.2736816	0.28
261.7438660	0.13
263.1003723	100.00
278.0610046	0.68
285.1227722	0.26
287.2476807	2.54
299.2746277	0.12
305.0816650	5.32
309.0160522	1.83
315.2196655	0.31
317.1076660	1.25
318.4793091	0.04
327.4467163	0.05
329.2113037	0.25
335.0128174	0.72
339.3110962	2.44
340.2917175	2.54
341.1769409	0.07
346.8765869	0.47
356.2582397	0.31
364.9105225	1.15
366.3804016	0.07
367.6266479	0.26
370.3879395	0.12
371.7351074	0.21
381.2515564	0.11
383.2921143	0.96
384.9059753	0.17
387.1398926	0.45
394.7504883	0.08
395.3606873	0.20
399.3002014	0.37
406.7191467	0.32
407.3588867	0.26
409.1930847	0.16
412.1076965	0.04
413.4064636	0.04
424.9833374	31.99
426.2681580	0.35
427.0832825	0.09
427.9107361	0.18
433.2917175	0.08
434.2024231	0.23
435.3079529	0.49
436.3987732	0.15
449.1727905	0.29
451.9667664	0.16
452.8270264	0.24
454.3282776	0.11
456.4594421	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3alpha,5beta,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.989418	1.31
109.1091003	0.56
123.2241058	0.58
135.1139832	3.34
136.8217316	1.25
144.8817444	0.23
147.0838928	1.89
149.2542114	2.64
151.286972	1.67
154.921524	0.81
157.0694275	0.51
158.7859497	1.15
161.0391083	1.00
162.8803406	0.50
165.1741486	0.50
167.8785858	1.54
170.7651367	0.40
173.1398773	0.39
175.0002441	0.20
176.9706421	0.62
178.2298584	0.85
179.9394989	0.28
180.6545105	0.29
183.0092773	0.68
185.2952576	0.68
187.1603699	0.53
189.1775665	1.56
191.1708069	2.86
191.9794159	0.18
197.0712891	0.79
205.1651459	0.39
206.0657196	0.43
211.0458984	0.53
215.1797485	0.62
217.0872498	0.35
219.0121155	0.20
220.4239502	0.70
223.1061401	1.29
227.0060425	0.28
229.1707764	0.78
231.1647034	0.33
237.295105	0.77
238.6663208	0.61
243.3665161	1.25
245.1006775	2.50
247.2142334	4.71
249.5237427	0.32
253.3293762	1.84
255.2698669	0.93
259.2277222	0.24
263.255188	0.93
264.1973267	0.24
265.3161316	1.94
270.9656372	1.68
275.1714478	0.85
277.3331909	2.39
279.1539307	1.18
280.2620239	0.92
281.2041321	2.13
283.0421143	1.57
295.082489	3.96
296.1385498	0.18
296.9055786	0.74
297.9544678	0.41
299.3582764	0.24
300.0089417	0.51
305.2911072	3.77
309.1916504	0.30
310.1836853	0.47
311.3960876	0.32
313.3577881	2.12
323.2347412	100.00
327.2752686	1.00
333.1127319	2.51
340.9266052	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1722412	0.02
156.0675964	0.06
158.9965210	3.33
160.0081635	0.24
199.0146484	0.39
200.0216064	0.21
217.0389404	0.18
218.1600037	0.03
228.9709625	0.79
229.9021301	0.27
245.1033020	0.02
246.0821686	0.03
273.0079346	51.66
273.9880066	12.82
274.7841797	0.03
332.1396790	0.02
384.0485535	0.03
384.9881287	0.17
386.9516907	100.00
387.9241638	40.69
411.2970886	0.02
426.9950867	0.08
429.8429260	0.02
456.6496887	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.2836
Annotation	CHEBI:75563
Peak:m/z	Relative Intensity
110.9244461	0.36
112.988678	0.25
120.9807053	1.69
123.1099854	0.12
130.8881836	0.34
131.9682312	0.41
135.0096436	0.35
136.962326	1.08
139.0012207	0.39
144.9678192	0.32
149.0971069	0.67
151.1677551	0.72
152.9536133	0.53
157.0646057	0.70
161.1838684	0.14
162.9544067	2.28
165.1218262	1.23
166.7779236	0.14
168.7846375	0.24
171.0739441	0.41
172.9085999	0.18
175.2704468	0.47
177.0684204	0.24
178.5147247	0.26
179.1951904	1.91
181.0497589	0.52
183.2369385	0.29
185.2783661	0.32
188.9916077	1.52
190.8960266	0.31
194.7366638	2.09
197.2283936	1.10
203.0860291	1.18
207.4976654	0.45
208.6699829	0.30
211.241745	0.96
213.1042175	0.43
214.3935852	0.54
220.3288574	0.53
221.2657471	0.97
223.2232666	0.28
224.433197	0.90
225.231781	2.49
227.138031	1.33
235.0069885	0.48
235.9750671	0.47
237.282135	0.27
237.9376221	0.45
239.188446	0.33
245.2399902	20.15
247.1444397	3.29
254.1944275	0.14
255.374176	0.73
263.2462463	56.54
265.277771	18.94
267.4377747	0.22
271.0701904	0.84
273.2611694	0.30
278.1231079	0.62
279.2622986	0.28
280.2944946	1.29
281.2037048	8.61
283.6684875	0.74
297.3216858	0.24
299.2879028	2.44
309.036377	0.19
311.5430908	0.25
313.8392944	6.65
319.2630005	3.16
327.072113	1.10
331.3545532	0.40
332.0873413	0.23
337.2740479	100.00
338.0991821	0.48
346.7358093	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	234.1
Annotation	Hirsutin
Peak:m/z	Relative Intensity
115.8548889	0.03
119.9531860	0.05
128.8408966	0.02
148.0722809	0.09
159.1441956	0.05
161.0464630	0.09
169.9735718	0.25
172.2948151	0.12
184.9135742	0.09
188.0286102	21.96
190.0375061	0.42
190.8763733	0.04
195.5912628	0.11
198.9405365	0.25
203.8013916	0.17
205.1004486	0.05
210.6574402	0.19
212.7845306	0.07
215.9293976	100.00
217.0397797	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Lactulose
Peak:m/z	Relative Intensity
341.1389465	100.00
342.0068054	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	346.1123
Annotation	Unknow
Peak:m/z	Relative Intensity
115.8592453	0.25
118.9263382	0.20
120.8941498	0.22
123.0903397	0.20
135.2527313	0.21
136.8825073	25.57
137.9934998	1.45
144.0060730	0.08
144.9414673	0.04
152.0852966	0.53
153.9906921	100.00
160.0236816	0.20
174.0653534	0.35
183.0123291	0.44
184.0220947	2.00
185.0957947	0.09
190.7781982	0.40
193.1860657	0.22
195.2900238	0.16
196.0701599	0.15
197.9139404	0.10
200.1781769	0.26
226.8831787	0.18
229.4948120	0.09
239.3765564	0.24
248.5586853	0.14
250.0613098	0.38
255.8648071	0.19
269.1582336	0.29
270.1473389	2.95
271.2114258	1.30
282.2399597	0.61
284.5028076	0.30
296.2339783	0.17
297.8975830	0.09
299.0095825	0.48
300.1652832	0.23
302.3201294	0.24
314.5796509	0.31
316.3540039	0.49
318.4124756	0.07
327.2651978	6.68
328.2257385	9.23
329.2602844	0.33
337.4616089	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1289
Annotation	Arborescoside
Peak:m/z	Relative Intensity
119.0138550	0.18
143.0427856	0.12
148.9136200	0.13
163.2451782	0.25
177.0490417	0.37
178.9787598	0.96
184.7450256	0.17
192.0268402	4.93
196.8684082	0.16
207.0528564	92.92
225.0655518	0.40
241.0662231	0.17
272.1614380	0.49
273.0779419	0.44
279.1436768	0.05
280.3235474	0.11
286.2745972	0.07
288.2400513	0.04
296.2862244	0.13
297.1331787	0.12
298.3617249	0.10
301.0131836	0.24
312.8142700	0.16
313.5749207	0.62
314.2580872	0.89
315.1100464	0.36
323.3164978	0.19
325.0479736	0.37
326.3488770	0.25
327.0736084	0.08
341.1441345	100.00
342.2177734	1.21
343.0717773	2.82
343.9498291	0.18
344.8906555	0.14
345.7346802	0.10
349.1820679	0.11
351.1296692	0.39
359.2878418	0.26
368.1783752	0.62
369.0519714	0.39
372.2358093	0.08
378.1999817	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.2329
Annotation	chaulmoogric acid
Peak:m/z	Relative Intensity
80.87614441	0.95
83.14206696	1.46
92.73153687	0.18
96.8194046	1.62
107.247551	0.56
111.3727112	0.34
127.2002487	0.26
165.269043	0.24
168.2176819	0.46
182.1238556	0.35
195.9339905	0.50
198.2447205	0.89
205.2498169	0.84
207.4221497	0.87
208.222229	0.30
219.2093506	0.73
224.1804504	0.54
232.467865	0.54
233.1024475	0.36
234.0125732	0.36
234.8129883	1.62
236.1290283	1.40
237.0568237	2.33
243.2731628	5.83
244.4242554	0.61
259.2857971	4.58
261.2254639	100.00
262.2470093	45.71
262.9804382	0.68
264.1852112	0.38
265.2696838	0.43
280.4059448	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	730.88
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0486145	0.32
273.0539246	13.68
274.0405884	4.81
275.0477905	4.58
346.8493042	0.44
387.0043945	11.41
387.9547119	8.31
389.0304565	7.27
428.8491821	0.15
486.1281738	0.11
486.9432983	0.05
498.9798584	0.13
500.9384155	49.83
501.9124756	53.57
502.9621582	49.57
503.7113037	0.13
558.7466431	0.20
582.9774170	0.04
585.8589478	0.06
609.7945557	0.54
611.0144653	0.44
611.7066650	0.21
614.8204956	31.10
615.8483887	92.05
616.8690796	100.00
618.0819702	0.38
626.8245239	0.20
628.1132202	0.33
628.9522705	0.14
630.1356201	0.25
640.9020386	0.10
642.6566772	0.04
645.0282593	0.13
655.9575806	3.53
656.9987793	1.70
658.1218872	0.71
672.9671021	0.09
674.0773315	0.44
675.1283569	0.59
675.8430786	0.08
684.0051270	1.06
684.9190063	0.34
700.7661743	0.12
703.1986694	0.18
704.1625366	0.12
711.8389282	0.17
731.0788574	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Tricaine
Peak:m/z	Relative Intensity
116.1750641	0.05
120.0388641	100.00
120.9914246	0.02
124.6544952	0.04
131.0483856	0.16
137.0236511	0.11
138.0181274	0.03
147.8497009	1.28
148.8729401	10.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.1941
Annotation	Maculalactone K
Peak:m/z	Relative Intensity
158.1289368	0.18
178.0293274	0.26
192.1649170	0.04
209.1408691	0.31
217.1578064	0.12
224.0299835	4.63
227.8591919	0.12
235.8858032	0.58
252.9630737	2.36
262.1477661	0.91
265.2199097	0.10
279.0307617	0.09
286.9547729	0.08
291.1831055	1.20
303.0759888	0.14
306.3697510	0.07
310.6293335	0.20
314.9097900	0.28
336.7198486	0.19
349.2371826	1.87
350.4464722	0.36
373.1844482	0.09
383.7931519	0.29
396.0971680	0.47
406.9160767	0.35
418.2852783	0.21
426.5121460	0.75
428.1613770	7.59
431.5045166	0.05
446.0330811	0.30
450.0137329	0.05
451.1730957	0.46
453.6310425	0.08
463.1157227	0.33
473.0503540	0.14
475.1604614	0.54
483.0548706	0.09
488.3083496	0.32
492.9171753	0.08
496.9990234	0.25
497.9061890	0.07
500.3864136	0.92
501.6473999	0.30
503.1415405	0.44
516.2539673	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2803
Annotation	Polysorbate 60
Peak:m/z	Relative Intensity
125.0680923	0.03
130.9720459	0.19
143.0770111	0.21
143.8363953	0.01
153.1746521	0.04
157.1165161	0.01
161.2036743	0.09
178.4517212	0.11
179.2154846	0.11
179.9609680	0.02
197.1668701	0.02
208.8975677	0.07
222.2775116	0.02
223.2863770	0.04
225.2446289	3.82
226.2817535	1.01
236.8992615	0.10
239.5342407	0.09
240.6162415	0.09
241.2872620	0.05
253.3218689	3.12
254.4277039	0.98
255.3422546	0.93
256.1455078	0.31
262.9877930	0.01
265.9404297	0.02
267.2774658	3.59
268.2929382	0.57
269.2835388	0.21
271.2912903	100.00
272.2824402	18.16
279.1089478	0.05
280.2529907	0.01
282.2296143	0.05
283.2113037	0.15
284.8379211	0.23
285.8550415	0.14
295.3526001	0.38
296.3824463	0.03
297.3245544	0.10
303.2890930	0.07
305.1821594	0.03
309.5420837	0.03
313.2291260	3.35
314.2745056	0.83
325.2550659	0.72
326.4396362	0.12
341.6320190	0.04
342.5804138	0.05
343.3087769	0.10
344.1449280	0.07
361.4917297	0.02
363.2248840	0.05
364.2453918	0.10
367.2550659	0.14
368.1753235	0.02
371.5514526	0.02
376.8579407	0.02
387.7222290	0.05
388.4888000	0.02
389.6395874	0.17
390.5621338	0.04
391.4261475	0.04
395.1440125	0.04
396.3395081	0.06
397.2328796	0.04
398.1632690	0.28
399.4641418	0.04
405.2987061	0.07
415.3108521	0.37
416.3023376	0.18
418.0857849	0.03
419.3928223	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	536.2994
Annotation	PS(19:1(9Z)/0:0)
Peak:m/z	Relative Intensity
160.9113922	0.01
164.8820038	0.05
171.8347626	0.05
183.0423737	0.06
200.7369537	0.02
202.8445892	0.17
218.0061035	0.06
219.9671021	0.09
220.9664612	0.07
224.0611877	0.08
229.8810272	0.03
235.8286438	0.32
242.1305389	0.08
243.9734497	0.16
245.0858002	0.03
247.1545715	0.07
251.0597839	0.85
251.7063141	0.05
253.1206360	0.13
257.1384277	0.08
262.8219604	0.13
272.0875854	0.05
279.8053589	0.10
285.0941772	0.05
286.0415649	0.03
294.0866699	0.03
299.2701111	0.04
302.1670532	0.03
307.7469482	0.05
309.5183716	0.06
310.4884644	0.09
338.3447876	0.06
340.7313843	0.02
347.9931641	0.10
349.9490356	0.06
350.6065063	0.09
356.2191772	0.04
357.3834839	0.09
365.2222900	0.03
370.1176758	0.07
377.1477051	0.03
384.1538696	0.08
387.3128662	0.54
398.3405762	0.13
400.1407471	0.05
413.3388062	0.04
430.0747681	0.07
433.9703979	0.04
435.2583618	0.09
440.3646240	0.17
442.1893921	0.07
443.4166870	0.06
446.4024048	0.90
448.2578125	0.10
450.5245361	0.14
452.1592407	0.06
460.2316284	0.02
462.0048828	0.03
463.2058716	0.04
466.1469727	0.12
467.8209229	0.07
474.3894043	0.05
476.3168335	100.00
477.2592773	0.56
482.2384644	0.18
490.1279297	0.03
491.7221069	0.07
493.0944214	0.03
498.2211304	0.39
499.9430542	2.39
501.5247192	0.04
503.3874512	0.04
505.9397583	0.06
517.6266479	0.11
518.3980713	0.20
519.6519775	0.05
535.9716797	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2725
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.2501831	0.38
205.0685730	0.45
223.0292511	25.04
224.0425415	0.30
233.5196381	0.20
241.1046448	51.84
242.1187744	1.08
259.0571289	2.33
260.1893311	0.44
277.3005371	25.14
278.2771606	3.13
315.0907593	100.00
316.1303711	6.66
333.1970825	10.17
334.0482178	0.63
413.2188110	2.85
414.5086060	0.22
431.2375488	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1086
Annotation	fagopyritol B1
Peak:m/z	Relative Intensity
100.9274139	1.39
112.9684906	2.99
118.8474426	2.96
121.1244278	0.07
125.0546951	0.99
130.9026489	0.91
135.0939636	4.32
143.1062317	3.32
148.8474121	0.47
151.0938416	0.19
156.7875061	0.10
161.0203552	4.39
177.0331726	0.42
179.046814	100.00
193.1530609	0.07
194.8243866	0.23
196.8756104	0.05
203.0478516	0.46
210.1069031	0.50
212.222229	0.08
213.0035095	0.29
219.3257141	0.11
221.1063538	10.60
227.4588013	0.08
231.1165466	0.40
232.9864807	0.52
239.1988831	0.32
243.1432495	0.38
245.0784302	0.17
246.9878845	0.40
249.0011597	0.12
251.0854187	34.45
261.0658569	0.32
262.9838867	0.11
267.2989502	0.35
277.1110535	1.08
279.1253052	0.25
281.163208	60.47
282.1754456	0.22
293.3227234	0.06
294.1940308	0.18
295.1304932	1.71
296.1044922	0.08
297.0140686	0.32
298.1966858	0.11
305.0900269	1.48
311.1755981	2.09
313.2198486	0.63
320.922821	0.18
323.1524658	4.90
324.1287231	0.13
325.9950256	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1173
Annotation	Sissotrine
Peak:m/z	Relative Intensity
178.9473572	14.39
180.0339355	8.59
195.2719116	31.20
197.2110138	4.97
237.4061432	16.72
283.0651855	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.0406
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9128876	0.35
98.9420624	0.81
113.0062256	0.40
115.9250412	0.41
117.1283493	0.32
118.9866486	0.14
124.6976013	0.41
136.9343872	0.52
139.0292358	0.07
140.8136292	8.19
141.5074463	0.03
142.9616394	0.10
150.9889526	0.09
154.9648590	0.12
159.0992737	0.12
160.1048584	1.96
161.0742493	1.41
174.9356689	0.11
178.9524536	0.36
184.9353790	100.00
185.6778564	0.06
192.7736206	0.14
202.0640259	0.71
203.0667114	12.08
210.8695068	0.30
225.2294312	0.24
232.2148438	1.09
233.5297241	0.14
244.9774780	0.13
247.1829834	0.31
249.1036987	0.40
253.2535400	0.15
260.9228516	0.17
262.0604248	2.07
263.1696167	0.18
275.1149597	0.24
277.2084351	0.55
279.1812744	1.36
280.0581970	0.28
285.1739502	0.39
286.0992737	0.08
287.0609436	0.20
292.1369629	0.15
293.0659790	0.75
295.0717163	0.36
304.1734619	0.87
305.1082764	1.01
308.0858154	0.06
309.3366699	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.144
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8228302	0.39
191.7493286	0.07
218.8246765	0.02
248.8074799	0.05
264.0925293	0.01
269.0809937	0.01
292.9406128	0.05
334.9321899	0.03
341.4306641	0.03
385.1400757	0.03
398.2343750	0.03
413.1959839	0.03
429.2615967	1.64
430.3040161	0.50
442.9652100	0.05
452.8068848	0.10
455.5073242	0.05
457.1970215	2.18
458.2824097	1.27
462.1234131	0.03
471.9486084	0.04
475.2915039	0.47
476.3627319	0.51
484.7664185	0.06
485.7777100	0.12
486.9829102	2.42
488.1236572	0.79
488.9378052	0.07
489.9081421	0.04
501.1908569	15.33
502.2403564	5.40
502.9309692	0.28
505.6649780	0.02
513.7785645	0.03
514.4342041	0.02
519.1565552	3.29
520.2295532	1.49
523.1812134	0.01
529.2268677	0.33
531.1493530	100.00
532.1071777	30.19
532.9188843	0.62
533.8363647	0.07
534.4428101	0.01
540.0157471	0.06
545.1267700	0.07
545.8229370	0.15
547.1039429	0.07
548.0156250	0.15
549.0950317	0.04
549.9691772	0.06
550.9403687	0.25
552.9458618	0.19
554.3721924	0.02
555.1420288	0.04
557.4074707	0.11
561.4622192	0.03
563.2333984	0.07
576.4338379	0.02
577.0366211	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.4563
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0210571	0.13
172.8796539	0.08
178.1380768	0.43
183.3089600	0.08
193.1886292	0.16
194.9165039	0.39
197.2246552	0.13
201.2000275	0.45
211.9493713	0.07
223.0791473	0.66
223.9798737	0.11
224.9995422	0.36
246.1534424	0.14
274.0994263	0.08
274.8940430	0.12
292.1255493	0.11
303.5076294	0.04
325.6768188	0.31
345.6211243	0.24
354.2860413	0.50
364.2830505	0.29
375.1356201	0.42
378.0870056	0.31
380.3394470	0.15
381.1593628	0.17
383.3270569	0.11
398.1091614	0.20
418.0779724	0.26
436.5140686	1.55
440.7980042	0.74
443.3693542	0.08
448.2897339	0.70
452.1604614	0.25
458.3709106	1.10
460.5958557	0.67
461.3681641	0.06
463.4357605	0.38
465.1609802	0.36
468.2108765	0.07
469.8936157	0.51
474.2056274	0.36
480.2383728	0.14
489.1938171	0.04
490.4663696	0.43
491.7366638	0.96
493.2208557	0.17
494.8845825	0.92
499.1075745	0.32
527.0894775	0.20
533.4641113	0.39
535.8621826	0.59
537.6418457	0.71
543.8247681	0.44
552.7665405	0.71
553.3835449	0.26
561.7022095	0.42
564.8704224	1.92
566.7856445	0.56
567.4058228	1.75
568.5292358	0.25
569.5815430	1.47
573.6958618	2.67
574.9364624	0.98
576.3886108	1.53
579.3940430	0.12
580.6483765	0.26
581.4957886	4.02
584.7185669	1.58
585.4096069	0.64
587.1994629	0.92
587.8024292	0.63
590.4653931	4.44
591.2803345	5.86
592.0935669	0.06
592.9636841	0.63
595.3342896	0.83
596.4022217	3.05
597.0195312	6.45
598.6182251	0.45
599.3153687	0.35
600.5470581	0.06
602.6134644	24.34
603.9568481	2.16
606.0646362	0.20
607.3911743	2.43
608.3268433	13.10
609.8433838	14.40
610.8195801	2.95
613.4242554	0.67
614.5108032	1.67
615.4041138	0.41
616.0777588	1.63
616.8127441	0.61
618.5046997	0.42
619.6654053	3.37
624.0606079	1.06
625.4959106	4.01
626.1097412	1.07
626.7838135	1.41
627.4485474	0.56
629.2536621	1.10
630.1455688	0.94
630.8690186	0.11
632.8082886	2.49
633.7020874	0.40
636.7831421	0.77
638.9544678	100.00
639.7230835	8.62
640.4938354	1.24
642.2091675	11.34
643.0685425	0.25
651.9732056	0.48
653.7271118	0.18
660.4866943	0.10
661.5197144	0.36
665.3247070	0.25
695.5092163	0.90
701.9174194	0.13
716.8136597	0.27
720.8880005	0.16
724.8615723	0.22
730.1149902	0.49
731.8754272	0.23
733.4138794	0.22
752.7518311	0.04
755.4415894	0.32
760.6404419	0.18
772.4697266	0.41
779.5266724	0.07
781.1577759	0.43
785.1032104	0.63
794.3380737	0.63
799.5480347	0.06
803.0079956	1.29
803.7976074	2.15
815.3593140	0.65
820.2468262	0.88
822.0966797	0.19
825.7863770	0.54
828.4213867	0.27
829.2402344	0.37
834.5385132	0.50
837.6378784	0.37
838.2434082	0.22
842.0795898	0.68
842.8961792	0.13
846.4844360	1.20
847.1436157	0.59
850.1774292	0.08
851.2991333	0.89
855.1377563	0.56
859.9390259	0.24
873.0745239	0.06
877.2947388	1.50
881.2111816	0.26
881.9331665	0.52
885.3269653	0.34
910.2392578	0.11
925.9536133	0.05
1041.6154790	0.26
1072.6108400	0.20
1082.2451170	0.10
1095.4864500	0.20
1107.8034670	0.66
1136.6760250	0.21
1146.2756350	0.31
1202.9566650	0.47
1220.9735110	0.37
1238.1510010	0.21
1275.0583500	0.08
1291.3853760	0.07
1294.5588380	0.15
1316.5155030	0.18
1344.8671880	0.05
1367.6566160	0.15
1485.7983400	0.06
1540.5467530	0.17
1630.6348880	0.15
1682.2960210	0.56
1726.9681400	0.04
1736.0159910	0.04
1738.8514400	0.05
1780.3631590	0.03
1797.2399900	0.04
1845.0357670	0.11
1858.6439210	0.05
1862.9488530	0.56
1867.6724850	0.13
1871.3831790	0.03
1880.5228270	0.29
1886.2879640	0.25
1891.0915530	0.22
1893.6585690	1.67
1899.2093510	0.08
1902.5876460	0.32
1903.8670650	0.93
1906.4338380	0.17
1917.0360110	0.13
1918.6400150	0.22
1919.2879640	0.08
1920.3421630	0.27
1923.5098880	0.55
1927.6569820	0.08
1931.0870360	0.22
1934.0769040	0.14
1937.7066650	0.37
1940.3479000	2.34
1946.9713130	0.24
1949.4442140	5.69
1958.9436040	0.09
1961.7043460	1.31
1963.3039550	3.45
1966.8939210	2.68
1969.7474370	10.35
1970.6722410	0.04
1971.3908690	0.14
1972.9198000	1.87
1978.1353760	0.65
1978.7821040	17.12
1980.8953860	0.11
1982.3013920	6.35
1983.5173340	0.55
1985.0925290	0.14
1988.9426270	0.63
1991.9298100	1.37
1992.6429440	0.93
1994.3475340	1.19
1995.3673100	0.46
1997.1290280	0.13
1999.2424320	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.1328
Annotation	Glucoacetosyringone
Peak:m/z	Relative Intensity
124.983551	1.42
145.5720215	0.24
151.1468811	0.56
155.0640564	0.17
173.1803284	0.08
179.1382446	1.05
181.3848267	0.15
197.0796204	100.00
224.2092285	0.12
243.2435303	0.19
249.4360962	0.78
253.1893005	0.32
266.0067749	0.22
267.3080444	0.28
268.4618225	0.22
275.1776733	0.24
277.5023193	0.48
290.993042	0.30
294.1048584	0.60
295.809021	0.12
323.468811	0.24
324.1011658	0.24
329.0514526	0.16
331.5049133	0.04
340.131073	0.80
341.0218506	1.01
342.3506165	0.32
349.933075	0.46
358.3855286	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.0032
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.9186859	0.09
192.9546814	0.70
195.1721497	0.10
208.2211456	0.12
211.0021820	3.19
214.9000549	0.94
223.1960449	0.12
232.9575806	0.20
235.9116364	0.20
241.1140137	4.55
256.9834595	2.53
259.1490173	0.91
262.0839844	0.38
272.8254395	0.07
280.0090027	1.87
287.1779785	0.10
293.0134277	0.13
298.8602295	0.31
308.1681519	0.20
309.9887695	0.16
310.8645325	0.56
317.7761230	0.30
319.8946533	0.07
323.0933838	100.00
323.8393555	0.03
329.0223389	3.71
334.2296143	1.90
335.9147949	0.16
339.2107544	0.05
341.1594238	0.05
352.1059570	0.36
353.8880005	0.16
356.2323608	0.05
359.0292969	4.76
361.0773926	0.27
369.5253906	0.06
370.9547729	0.48
372.2779541	0.17
377.0609741	6.34
380.0824585	0.56
388.4046021	0.04
390.3338623	0.16
396.0578613	0.12
397.8256836	0.36
402.0227051	0.07
406.3498535	0.41
410.9391479	0.14
419.1638184	1.67
420.9290161	0.08
422.9878540	2.32
424.2410889	1.64
425.1232300	0.19
427.9179077	0.85
428.9772949	1.33
431.1064453	0.25
440.9940186	29.47
441.6730957	0.11
444.0010986	0.18
444.8155518	0.06
446.9087524	3.26
447.5222168	0.70
448.1350098	4.81
449.0167847	0.20
451.8163452	0.30
452.9280396	0.42
458.1822510	0.24
461.9140015	0.04
465.2062378	0.11
467.4398804	0.23
470.0964966	7.87
471.3677979	0.32
472.1437378	0.09
483.1306763	28.39
486.0396729	0.11
488.1119385	3.01
491.0400391	3.65
500.1416626	0.20
504.7742310	0.33
506.1898804	0.19
511.9868774	0.26
516.1819458	1.40
517.5769653	0.56
518.3745117	0.65
524.2402954	0.87
542.1333618	1.50
556.0552368	0.38
557.1287231	0.06
560.0946655	48.58
561.0436401	0.28
585.1297607	18.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	512.2993
Annotation	(-)-Bisparthenolidine
Peak:m/z	Relative Intensity
199.9138794	0.10
227.2880859	0.36
284.1741943	0.08
341.4709473	0.06
357.3353271	0.06
358.0927734	0.11
374.3931885	0.13
381.5282593	0.07
392.1251831	0.03
409.5062866	0.07
424.5623779	0.13
452.3872070	100.00
453.4136353	0.03
456.2005615	0.03
465.9838867	0.18
467.5799561	0.04
474.1145630	0.53
476.4431763	0.37
477.3151245	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.1505
Annotation	Unknow
Peak:m/z	Relative Intensity
119.1224976	0.17
125.0470505	0.29
128.8737030	0.13
130.9497528	0.10
139.0498199	0.07
141.1026764	0.30
143.0004272	1.63
146.7815094	0.05
148.5485840	0.11
150.9823914	0.03
155.0501251	0.03
158.8995056	0.31
161.0135345	2.73
166.7709808	0.11
177.0044098	0.22
179.0330811	2.53
183.2262878	0.09
184.9375000	0.04
188.9691772	0.10
197.1560669	0.11
199.2072449	0.02
200.9049072	0.14
203.1168976	0.07
213.0588837	0.13
214.8421631	0.14
216.9971008	0.06
219.1878204	0.02
221.0717621	0.04
223.1679993	0.11
230.7880554	0.05
233.2388611	0.19
245.0586243	0.96
248.5751953	0.35
249.2088623	0.52
261.2222595	0.04
275.3098145	0.05
278.9590149	0.09
288.0506287	0.10
290.7635498	0.07
291.5839539	0.03
305.1494751	0.07
323.1184998	47.88
339.3564453	0.05
341.1301880	100.00
343.1309204	0.09
350.8989563	0.38
362.1805420	0.08
365.0514221	1.00
366.8061218	0.09
374.9202576	0.06
377.4172974	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.2942
Annotation	LysoPE(0:0/20:3(8Z,11Z,14Z))
Peak:m/z	Relative Intensity
153.0581512	0.09
159.3056488	0.05
162.6402283	0.01
168.0079041	0.07
171.2279663	0.01
224.1071930	0.34
231.2949371	0.02
233.2521820	0.51
242.1786804	2.59
250.0724792	0.03
257.2586365	0.05
259.3341064	0.21
275.2134399	0.37
277.2309265	100.00
277.8502197	0.32
303.2145386	0.02
371.3457642	0.01
431.2263489	0.04
441.4723816	0.01
464.1871338	0.08
465.8502197	0.02
473.5648804	0.01
483.4223328	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
76.9178009	0.45
105.0239716	0.26
118.0252228	0.30
130.2225952	0.36
145.9319	0.41
149.058075	2.11
150.0324707	0.29
165.0836945	0.22
169.1234589	0.86
174.0855713	0.53
177.1405945	0.70
178.8991241	0.89
180.0059509	1.25
181.2636719	1.18
182.5297699	0.33
184.0664215	0.38
190.0425415	0.24
193.1387787	0.64
194.1403198	0.20
195.2150726	1.17
195.980484	0.27
204.9182892	0.22
206.2600403	1.19
207.1303253	8.45
208.0870972	14.25
209.1258087	3.45
210.3521729	0.69
221.1013031	1.21
222.0373993	8.67
223.1889038	11.87
224.1702118	4.42
232.9791107	0.31
234.9546661	0.77
236.1035919	0.38
236.8170776	0.29
249.1082001	0.64
251.0766602	100.00
252.1371613	34.77
253.0914154	2.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	618.66
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0260620	0.04
208.8987579	0.30
251.2540588	0.11
272.4194641	0.02
280.6602478	0.13
282.8217163	0.53
290.7489014	0.24
292.8937988	0.50
294.8199463	0.04
317.8249512	0.14
337.5776367	0.07
353.8899536	0.03
364.7101440	0.07
366.8867188	2.26
374.7332153	0.06
376.9432983	0.55
404.8171387	0.07
444.9481201	0.04
448.5846558	1.26
450.6301270	14.30
451.2584229	0.10
458.1654663	0.20
458.9688721	0.16
460.7121582	1.63
462.9830933	0.02
469.0084229	0.14
476.3563843	0.02
482.7641602	0.06
486.8379517	0.05
488.6728516	0.96
521.2774048	0.05
527.9991455	0.01
532.4871216	8.12
534.5481567	100.00
535.2882690	0.39
544.3353271	0.22
562.5720825	0.10
572.6155396	12.17
573.2670288	0.12
580.1031494	0.04
595.8088379	0.31
599.9097290	0.03
601.3359985	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	316.2838
Annotation	Halisphingosine A
Peak:m/z	Relative Intensity
93.09503174	0.13
94.85395813	1.03
97.22706604	0.27
107.3191757	0.33
108.9563141	0.10
110.8600464	0.17
112.8611679	0.08
118.9301071	0.17
123.0113983	0.99
125.0786514	0.67
129.9080963	0.16
133.0496521	0.18
135.1793213	0.42
136.8227386	1.79
139.0938721	0.48
141.2049255	0.34
149.4257507	0.35
150.9989929	1.88
154.3440552	0.76
155.08461	0.13
156.052002	0.32
161.0158081	0.56
163.0862427	0.19
164.736969	0.07
169.0870056	0.17
170.2928467	0.21
175.2299347	0.79
176.9772644	0.29
179.2330017	0.06
182.1868896	0.18
185.0795593	0.21
188.2771149	0.69
189.1175232	0.25
197.26297	0.15
199.0786743	0.30
203.2789001	0.59
205.0619202	0.21
214.2836914	0.91
216.1646729	0.15
219.2596741	0.65
221.1742859	1.74
225.4229736	0.41
227.9448242	0.04
232.1729736	0.28
233.2219849	2.03
235.676178	0.16
237.4056702	0.42
238.8048706	0.79
239.459259	0.85
242.3030701	3.03
245.4432373	0.68
250.39328	0.83
251.0667725	2.07
252.3097534	0.20
254.4706116	1.01
255.2321167	0.18
257.1943359	0.69
260.3833618	0.96
262.2124329	2.75
263.2475586	4.54
267.0140381	3.09
268.4596558	2.16
270.3401794	0.09
271.0368652	0.62
274.1871948	0.15
280.2572021	67.48
281.1281738	2.15
284.9193115	1.92
293.0664062	0.08
298.2765503	100.00
299.0893555	9.76
301.2714844	0.51
304.0545044	0.07
306.8328247	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	177.1017
Annotation	N-Hydroxy-1-aminonaphthalene
Peak:m/z	Relative Intensity
159.9994354	100.00
161.0809784	0.06
163.7858124	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8109131	11.54
207.4849091	0.10
290.7781982	100.00
296.7699585	0.29
353.1964417	0.06
356.9521179	0.28
368.9004211	0.13
374.6023865	29.16
375.5065002	0.41
398.7861938	3.46
412.7480164	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	486.1527
Annotation	Unknow
Peak:m/z	Relative Intensity
177.2305298	1.47
277.0212402	0.71
288.1169739	1.28
306.0119324	19.48
324.0364380	100.00
356.2708130	0.55
371.3480530	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1186
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
135.0940552	0.08
136.9829407	0.04
151.1976624	0.13
152.7988892	0.03
154.0682068	0.17
161.9459686	1.28
177.0688629	0.72
180.0774536	5.41
183.9106750	0.25
194.9894714	100.00
203.0563354	0.11
215.0161438	0.10
224.3475952	0.05
229.2739868	0.05
237.1389160	0.06
257.0556030	0.21
259.2194824	0.25
261.1793518	0.08
265.0220642	0.07
267.1674194	0.11
269.3837891	0.11
270.0012207	0.11
277.8979492	0.03
278.9891968	0.15
280.0605469	0.05
289.1418152	0.16
293.9902039	0.26
295.1317139	0.11
297.1829834	1.29
302.6606140	0.18
311.1265869	0.36
312.3985291	0.05
313.1864014	1.24
315.1255188	0.92
318.9946594	0.21
321.0589600	0.67
323.1243896	0.20
329.1957703	0.17
339.1722107	0.25
343.2131653	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.2311
Annotation	Unknow
Peak:m/z	Relative Intensity
310.1412964	0.66
327.3435059	0.29
344.3416748	0.19
368.9628296	0.38
377.7041016	0.14
446.9007568	0.26
487.9235229	0.33
488.7530518	0.37
494.4996338	0.21
500.3300781	0.29
504.8092651	1.19
505.5666504	0.15
511.1519165	0.19
512.1730347	0.15
522.2067261	100.00
522.9252319	0.11
535.4963379	1.17
547.2972412	0.15
558.4966431	0.43
560.7264404	1.18
568.0112915	0.28
576.1646118	0.26
583.9827271	0.08
584.8726196	0.08
621.4630737	0.10
633.3696289	29.62
634.2705688	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2253
Annotation	Lactulose
Peak:m/z	Relative Intensity
232.8184814	0.04
304.0468140	0.02
329.2292480	0.05
339.9579468	0.13
341.1483154	100.00
347.2268677	0.02
386.2559814	0.05
472.6925659	0.02
508.5609741	0.02
636.2713013	0.17
637.3479614	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
125.2738037	2.13
131.2636108	4.60
139.0264893	4.90
151.2312927	6.30
161.0161438	1.31
167.212738	5.69
168.9543304	3.35
173.132843	2.83
179.1008301	4.18
185.118927	2.74
189.2588501	3.97
197.1758728	1.82
209.407074	9.30
239.9868164	1.14
245.3184204	3.22
265.3795166	4.06
269.0031433	1.82
273.3132935	4.56
281.484375	11.09
282.992218	12.18
285.7807312	2.84
288.297821	1.91
289.1639404	4.24
293.573822	3.64
297.3344727	2.58
307.1579285	2.39
309.0112915	3.15
314.4747314	7.21
326.9346924	4.16
331.0436707	2.22
332.0808105	5.19
335.7244263	3.04
337.439209	3.66
338.9468994	15.84
340.9418945	3.96
342.397583	11.29
361.1465454	2.84
376.9705811	5.31
390.3267517	5.60
391.1459045	5.68
395.3896179	22.12
398.5362549	3.42
408.2739563	100.00
409.4317932	5.72
415.773468	7.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1309
Annotation	Galactotriose
Peak:m/z	Relative Intensity
201.0220795	0.45
218.9496155	0.14
290.1072998	0.78
363.1886597	21.59
381.1000977	100.00
382.1323242	0.41
483.1475220	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	676.2727
Annotation	Unknow
Peak:m/z	Relative Intensity
293.1785278	0.35
318.1007080	0.40
367.1552124	3.03
482.4037476	0.71
500.8807983	0.52
529.7190552	4.39
532.3392334	0.47
540.2387695	0.57
552.3117676	0.80
557.7326660	0.70
573.9069824	4.82
575.2411499	4.45
576.3655396	2.61
585.0686035	1.42
586.3490601	1.86
590.2200317	2.87
610.1470337	2.12
618.8200684	5.62
627.3577271	1.68
629.1686401	0.86
632.1694946	0.71
632.9381104	2.24
637.0040894	3.69
638.0938110	0.20
639.0821533	20.76
643.6043091	0.54
650.4326172	2.23
653.4126587	0.98
654.8067017	2.52
656.6608276	2.72
657.3016968	2.50
659.2605591	1.22
664.6105347	4.04
665.3302612	0.97
667.6976929	3.03
671.2987671	1.28
715.2086182	0.73
722.5030518	0.51
785.6940918	1.52
799.4116821	4.82
803.4745483	2.46
804.2301636	1.85
812.1056519	1.26
820.1810303	1.63
825.2478638	1.03
840.6852417	0.75
847.0244751	3.11
848.3947144	1.49
849.9536743	2.75
850.8907471	5.07
852.1270142	5.31
856.0621948	0.24
863.1356812	1.71
871.4472656	0.71
877.9738770	0.18
881.1552124	3.68
890.0780640	1.67
893.0812378	2.91
894.9214478	3.11
903.7879028	4.22
905.7343140	5.25
912.5372925	0.80
913.9047852	13.34
914.5392456	6.75
915.1578979	5.45
922.9323120	2.33
929.0720825	3.02
930.2717896	2.40
931.6652222	1.38
938.0939331	1.12
939.8975220	2.68
950.0403442	1.30
957.7149048	13.01
959.0820312	15.10
959.8527832	0.42
1641.7225340	0.25
1661.0999760	1.34
1686.3909910	0.59
1743.8659670	0.70
1761.4073490	0.39
1767.6414790	0.36
1796.6300050	2.21
1807.4929200	0.64
1826.6195070	0.73
1830.3292240	3.28
1835.7847900	1.38
1837.2022710	15.27
1856.7962650	1.02
1859.2380370	0.18
1864.8005370	0.49
1867.1993410	0.20
1871.4998780	0.51
1872.8231200	9.19
1875.5845950	13.82
1886.1776120	2.86
1895.7834470	11.82
1900.6060790	0.95
1902.8751220	3.28
1911.3604740	1.69
1912.2985840	18.51
1914.6115720	0.95
1916.3846440	0.23
1925.7972410	0.92
1927.0072020	0.60
1930.4934080	0.31
1931.0964360	3.55
1935.6463620	2.22
1938.8958740	0.23
1940.3868410	0.35
1942.5374760	4.15
1944.3220210	0.25
1945.4068600	1.87
1947.9294430	0.56
1950.7169190	0.27
1953.8864750	0.65
1954.9871830	0.14
1957.6392820	2.57
1958.3937990	5.66
1961.7546390	100.00
1964.6329350	0.18
1966.4764400	0.27
1967.3189700	5.83
1972.0823970	0.25
1973.8093260	50.31
1976.3826900	6.48
1978.5191650	6.00
1979.7824710	15.97
1980.5540770	0.78
1982.9993900	2.55
1987.7977290	20.76
1989.1296390	53.00
1990.9530030	0.30
1991.9104000	43.01
1993.0847170	8.95
1994.3165280	44.34
1995.2156980	1.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.84
Annotation	Unknow
Peak:m/z	Relative Intensity
105.3492737	0.09
122.8139114	0.25
124.7832718	0.47
138.2157288	0.12
206.8233337	25.40
208.8415222	100.00
209.4463806	0.46
218.0512390	0.02
230.9977112	2.33
232.1540527	0.02
248.2751465	0.04
274.2634583	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0515442	0.06
152.8857269	0.03
196.0848999	0.38
214.1210022	1.41
235.2350922	0.10
240.3820190	0.03
261.2548218	0.14
279.2551575	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.1175
Annotation	Hydroxybupropion
Peak:m/z	Relative Intensity
80.97908783	1.46
87.99604034	5.27
93.2069397	0.90
94.95635986	18.34
122.9648743	100.00
128.1070099	2.99
130.2436066	2.75
133.8443909	1.54
140.6854706	11.92
141.4546051	1.65
148.9910431	1.27
153.950058	2.13
156.869812	1.97
163.1759949	0.84
188.3835907	1.77
192.2049713	1.98
193.1678009	0.96
207.8751221	3.04
210.2940521	0.76
213.0979156	2.76
220.0623932	2.17
226.312439	2.66
228.0076141	9.04
235.1937714	3.25
237.0112152	2.66
238.0974579	72.40
238.8322296	3.63
239.4842377	3.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.17
Annotation	Trans-Zeatin-9-glucoside
Peak:m/z	Relative Intensity
168.5833282	0.33
184.1571808	1.69
220.1177521	100.00
226.8231812	0.93
248.6484985	1.84
253.3043213	0.77
289.664978	1.31
292.2009583	1.39
306.7476807	3.19
310.8274536	1.02
316.151062	0.74
322.9846802	2.67
336.2867432	0.56
345.6067505	0.51
346.4915161	0.93
364.0890808	9.88
365.2475891	1.48
373.7124329	4.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2119
Annotation	Unknow
Peak:m/z	Relative Intensity
232.8806763	0.02
261.3344421	0.03
307.2594604	0.11
308.1978760	0.40
323.0643921	0.50
324.0874023	0.05
341.1439819	0.21
342.0561523	0.05
383.1527710	0.12
412.9387817	0.02
415.1795044	0.03
424.7141113	0.08
442.6630859	0.09
467.2204590	0.07
486.3755493	0.02
503.2373657	100.00
504.2977295	13.39
513.4957886	0.03
543.3256226	0.04
549.0904541	0.06
631.5378418	0.04
632.4779663	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.12885284	0.14
92.93510437	0.24
94.99478149	0.37
97.27383423	0.10
98.36412048	0.14
105.0080261	0.14
107.1189728	0.08
110.7229309	0.27
121.2062378	0.79
123.0446548	0.29
125.0827789	0.51
129.1045685	0.05
133.2378387	0.44
135.0710907	1.19
136.9438171	0.94
138.9622192	0.05
140.6505127	0.06
141.9797974	0.44
143.0926056	0.30
149.0377197	0.83
151.1282196	0.31
152.1249084	0.76
152.9688721	0.52
157.2713928	0.18
159.0474854	0.28
163.0392609	0.47
165.0181122	0.07
167.1011658	0.14
169.1491394	0.73
171.1732483	0.20
173.0551758	0.25
175.4942627	0.78
176.9730225	0.97
181.0853577	0.54
183.2890015	0.42
185.5885773	0.07
186.566803	0.05
189.2259979	0.43
190.9723511	0.17
195.2601776	0.77
197.1817017	0.87
199.0857849	0.20
204.9567261	0.26
207.2545471	0.05
209.1038208	0.34
210.6072693	0.48
211.2722473	0.30
213.1958008	0.11
215.0367432	0.07
217.1582642	0.55
219.2396851	4.13
220.5211182	0.24
225.321228	0.69
227.155426	0.21
229.2879333	0.21
233.2514343	0.56
237.1972351	8.01
239.1030884	1.15
241.1439209	0.28
247.243927	0.27
249.3081665	0.21
251.2269287	0.38
251.9407349	0.16
253.1292114	3.12
255.1418762	1.16
257.24646	2.08
265.2503662	1.36
267.2952881	0.62
269.3100281	0.95
275.1634521	7.42
279.4394836	0.12
291.1851196	0.23
293.2178955	100.00
293.9273987	0.18
310.1699219	1.10
310.7792969	0.88
311.5116577	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	728.8802
Annotation	Unknow
Peak:m/z	Relative Intensity
228.8692780	0.14
230.2987366	0.13
247.9785461	0.16
270.8036499	0.06
273.0365295	11.69
274.0049438	2.44
305.0982056	0.10
346.7357178	0.03
385.1648560	0.04
386.9235229	15.30
388.0161743	4.74
485.8477783	0.19
494.8925171	0.10
499.3510742	0.06
500.8645020	71.25
501.9844360	33.88
542.5097656	0.03
550.9562988	0.08
570.8434448	0.12
583.9302979	0.06
608.8630371	0.31
609.9810791	0.39
610.9300537	0.17
613.0408936	0.10
614.8298950	100.00
615.7998657	64.02
616.5322266	0.43
626.7616577	0.14
628.2177124	0.13
629.0056763	0.11
654.9902954	1.30
655.9256592	1.09
656.8300171	0.37
672.9867554	0.42
673.9547119	0.16
675.1247559	0.47
683.0070190	0.56
684.9415283	0.40
696.5980835	0.39
700.8136597	0.04
702.0134888	0.10
710.6738281	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.315
Annotation	PS(19:0/0:0)
Peak:m/z	Relative Intensity
242.2470856	0.02
253.2989502	1.96
294.0201416	0.01
299.0834961	0.06
369.2324829	0.03
377.4197388	0.01
394.2725220	0.02
407.5241699	0.05
415.4238281	0.03
422.2970581	0.03
433.4374390	0.05
436.2750854	0.01
446.3706665	0.03
478.3154297	100.00
479.2691040	0.58
482.3052368	0.02
499.9572144	0.15
501.6784058	0.02
502.3335571	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1461
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9709778	0.86
146.9005432	15.42
147.5329742	0.11
161.1511078	0.09
179.0032043	1.24
213.9877625	0.13
273.9452820	0.09
277.2612610	0.11
280.9131165	0.17
308.9816284	0.18
326.1030273	0.10
341.1758423	100.00
342.2310791	1.06
343.0874634	0.54
357.2239380	0.26
368.3143921	0.08
385.1339417	0.21
426.8210144	0.17
428.3191223	0.23
439.1567383	0.11
444.5548096	0.04
446.1492310	0.14
453.1736145	0.29
457.1626282	3.17
471.1388245	0.44
472.3806458	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.0784
Annotation	Lactulose
Peak:m/z	Relative Intensity
200.9782715	100.00
211.2136536	2.33
218.9456787	80.73
335.3438110	2.97
364.1867371	3.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2253
Annotation	Citbismine C
Peak:m/z	Relative Intensity
208.7321167	0.08
293.4014282	0.03
323.1091309	0.06
338.9362793	0.04
341.1519470	100.00
357.5668945	0.03
460.8636475	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.23
Annotation	9-OxoODE
Peak:m/z	Relative Intensity
109.9066238	0.67
116.8881607	0.43
124.9238815	0.27
151.2056885	0.44
159.1331329	0.41
165.139679	0.55
167.2172699	0.57
170.6498566	0.30
179.1678772	3.87
181.2911682	0.83
195.2978821	0.34
211.2669373	0.21
219.3328552	0.93
234.9478455	0.61
237.4240723	1.03
249.2331543	0.31
253.1889954	0.23
259.3405457	2.20
267.5950623	0.46
277.2215881	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.2371
Annotation	Unknow
Peak:m/z	Relative Intensity
145.7922516	0.07
213.2443848	0.12
224.9376221	0.10
234.9478760	0.17
293.3740234	0.56
310.5563354	0.05
311.3068542	0.41
329.1304626	0.29
343.3046265	0.78
355.4779968	0.45
361.2413940	2.58
378.2489929	100.00
379.2745361	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.3177
Annotation	Unknow
Peak:m/z	Relative Intensity
167.3074951	0.11
169.0350342	0.33
177.2781830	0.12
183.9622192	0.71
197.1894226	0.11
201.1622925	0.30
209.1154938	0.18
213.0675354	0.12
215.9945526	0.24
219.1909485	0.06
225.1166229	0.09
226.8487244	0.05
238.4392242	0.29
265.0844116	0.35
272.1239624	0.13
273.0940857	0.61
286.6561279	0.09
318.6519165	0.17
319.9063110	0.07
323.5757446	0.42
326.2137451	0.40
327.3572998	0.14
328.5642090	0.27
341.2261963	0.06
349.2948608	3.42
351.0848999	0.16
369.0632935	0.17
385.0896606	0.09
411.0142822	0.08
425.3598022	0.10
426.7944946	0.09
429.2603149	0.33
444.2772827	0.26
445.0208130	0.26
447.4583130	0.55
448.3696289	0.07
453.5674438	0.31
463.2393799	0.54
468.0581665	0.12
474.2407227	0.19
481.0469971	0.11
485.0905762	0.27
494.1179810	0.06
496.3865967	0.18
498.3810425	3.92
499.3064575	0.64
502.6243286	0.35
516.2437134	100.00
517.0692139	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1293
Annotation	Unknow
Peak:m/z	Relative Intensity
100.9799423	3.97
103.1350098	0.04
107.0695343	0.15
112.9586868	8.79
115.1674652	0.05
117.0307159	0.11
125.0418854	0.09
127.0173035	0.05
129.0639343	0.25
130.8380432	0.13
139.0339966	0.13
149.1576233	0.07
157.0017700	0.54
174.4215393	0.19
175.0373230	2.99
188.9279785	0.23
197.1572876	0.15
205.1033020	2.03
223.0353394	0.95
231.0926514	6.42
249.0685425	100.00
267.0969238	22.97
291.0727539	2.95
305.1447754	0.08
314.1818848	0.32
315.1443176	0.67
318.3065796	0.06
333.1375732	21.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.2539
Annotation	3,18-dihydroxystearic acid
Peak:m/z	Relative Intensity
96.98526001	0.36
127.0671616	0.61
130.1439972	0.23
151.223053	0.88
153.12677	1.07
155.2569275	0.23
157.1425171	0.17
159.9856567	0.79
166.1482849	0.32
167.1386871	0.18
179.1571045	0.18
196.0681305	0.14
197.3390045	0.21
200.1968079	0.38
201.367981	0.63
211.1867981	0.78
217.197937	0.47
221.0566406	0.89
225.27005	1.80
231.0032959	0.34
233.6842651	0.29
235.4736328	0.23
238.2123413	0.09
243.9606934	0.10
245.9906921	0.26
251.3989258	1.00
253.2585144	100.00
255.166626	2.81
261.0374146	0.23
269.2493286	0.17
270.3360596	0.65
271.1458435	4.31
273.0582275	0.37
279.242981	0.89
280.2456665	0.40
281.4026184	1.17
283.3536377	1.31
285.137207	0.25
288.1000977	0.18
295.1662598	0.62
297.2383423	82.12
298.3788147	0.47
299.1602173	1.54
300.1447754	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0825
Annotation	Ethotoin
Peak:m/z	Relative Intensity
68.8955765	0.45
72.0185852	0.55
73.9640350	1.38
96.9438171	0.50
99.0701447	0.06
113.0681000	0.05
114.0414276	0.10
115.9813995	36.45
128.0149689	0.89
129.0452881	1.06
130.0824890	1.10
130.9939270	0.13
131.9976501	0.27
141.9916840	17.40
157.1736908	0.31
159.0249786	100.00
159.6386871	0.41
173.0067291	2.35
175.0953217	0.18
184.9538422	1.61
186.1035614	11.36
202.9010468	0.05
END