#DEFINITION	Reference Metabolome for Momordica charantia
#IDENTTFIER	RefMeta-Momordica charantia.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Momordica charantia
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Momordica charantia was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3849
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
348.4300537	14.00
509.6309204	47.05
513.5071411	49.48
555.4839478	62.78
583.2584839	6.06
719.6703491	76.38
743.4661865	49.46
803.3751221	100.00
804.6641235	76.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	838.3587
Annotation	Unknow
Peak:m/z	Relative Intensity
284.0444641	0.19
295.1479797	0.13
358.2162476	0.15
485.3193359	0.32
588.8848877	0.35
623.5283813	0.07
633.4541626	0.11
684.5499878	0.31
718.2192993	3.15
731.7324829	0.28
735.1127930	1.51
740.4224854	0.47
748.7228394	0.57
753.4719849	0.93
758.3676147	2.00
759.6392822	0.42
764.4730225	0.30
766.7800293	1.24
768.0258789	1.10
775.0831299	0.96
780.7145996	0.14
782.1203003	3.73
783.4641724	0.09
784.9009399	3.44
785.5783081	0.59
792.2030640	4.81
795.2670288	22.87
796.0028076	2.09
797.3674927	0.35
798.1020508	0.16
799.8181152	0.43
800.8340454	3.32
802.0560913	1.29
803.5576172	1.46
805.2886963	2.61
807.5319214	0.59
808.8836670	7.25
809.5127563	3.65
810.9104614	4.47
812.4225464	21.94
813.2678833	4.70
814.6849976	21.33
815.6954346	4.82
816.5164185	1.33
818.2172852	28.13
819.1400757	2.15
820.1426392	1.58
820.8477173	0.16
822.0658569	10.12
823.0972900	7.89
823.9019775	2.27
825.0074463	12.34
826.5088501	4.13
827.2614136	0.15
828.6774902	1.39
865.9767456	0.81
868.0748291	0.91
883.2037354	0.24
897.6645508	0.49
903.3246460	0.15
905.0444336	1.52
905.8537598	1.94
920.2883911	3.12
922.7094727	2.17
926.2164917	0.86
927.1751099	2.82
928.2420044	1.91
930.2109985	3.42
931.4959106	0.57
932.7314453	5.66
934.7393188	4.10
936.9631958	1.99
937.8065796	1.59
939.0808105	2.33
940.1738281	2.98
941.6010132	5.33
944.0073853	2.96
945.1349487	0.99
946.2031860	2.48
946.9437866	1.50
949.4658203	3.38
950.5173340	0.60
951.2190552	0.08
952.5969238	0.90
954.1765747	7.72
955.2267456	0.98
956.9661255	3.93
958.0927734	1.30
958.9416504	3.53
960.1010132	12.09
961.1544800	11.29
962.6528931	4.64
964.4894409	3.40
965.1271362	0.53
965.8009644	14.34
966.7558594	1.96
967.9133911	1.05
968.6393433	0.14
971.2024536	1.23
972.5244751	10.41
973.6845703	6.48
974.6860352	1.40
975.4348755	2.41
976.6689453	5.28
977.9116821	4.00
978.7296753	10.94
979.9634399	8.58
981.1106567	5.89
982.9547729	32.39
983.9115601	10.64
984.8296509	3.17
986.2268066	3.24
987.5604858	20.12
988.6903687	10.21
989.7858887	15.39
990.5361328	2.33
992.0480347	58.58
992.8537598	6.05
993.6433105	37.04
994.5524292	12.84
996.0902710	10.85
997.3200073	10.22
998.1027832	0.29
999.9519653	5.53
1000.5997920	100.00
1001.4561160	17.43
1002.2935180	0.44
1003.3137210	2.74
1004.4818730	1.39
1005.1539920	2.57
1005.7880860	0.88
1007.0605470	5.05
1007.9968260	2.89
1009.7564090	4.01
1010.8466800	10.20
1011.7203980	5.43
1012.3366700	0.88
1013.5844730	5.38
1014.2993770	3.13
1015.4087520	13.64
1016.4282840	1.26
1017.7671510	38.66
1018.5400390	23.41
1019.3158570	2.67
1020.2244260	8.16
1022.1289670	60.27
1022.7355960	71.23
1023.8566890	0.23
1024.9531250	0.62
1027.0109860	13.07
1028.1444090	1.39
1031.2355960	0.22
1035.2385250	0.07
1051.7740480	0.45
1069.4108890	1.83
1103.4914550	0.88
1119.7983400	0.71
1128.8125000	1.49
1131.9387210	0.33
1133.8999020	0.50
1135.8471680	0.39
1139.0170900	0.82
1141.7468260	2.31
1148.2851560	0.40
1149.1734620	1.00
1150.1965330	0.99
1153.0579830	1.02
1153.7412110	0.31
1155.6992190	0.36
1160.4465330	0.87
1165.3109130	2.20
1167.8331300	0.09
1172.1002200	1.28
1174.5067140	1.93
1178.7170410	1.70
1185.5717770	3.13
1189.1978760	0.13
1193.2896730	0.44
1194.3032230	0.85
1196.1086430	0.58
1197.5568850	0.52
1198.3852540	2.27
1199.6748050	2.45
1201.6241460	1.34
1203.3637700	1.62
1204.2954100	3.91
1205.3940430	1.29
1210.0136720	0.12
1210.9892580	2.43
1212.6478270	3.41
1213.4611820	0.72
1214.9578860	0.31
1216.1252440	2.44
1221.9011230	1.06
1224.5476070	0.90
1225.8752440	2.80
1227.3797610	0.40
1229.8845210	3.63
1231.1667480	0.93
1233.0393070	2.63
1233.7950440	1.37
1236.0969240	4.62
1237.6583250	0.85
1240.2730710	1.92
1241.4782710	2.89
1242.1086430	1.62
1243.0043950	4.22
1244.4213870	1.58
1245.9361570	1.85
1248.8585210	13.91
1250.0839840	1.99
1252.4610600	3.58
1255.4224850	2.24
1256.5668950	0.97
1258.1757810	36.51
1258.9821780	15.15
1259.8165280	4.38
1260.7489010	2.36
1262.1810300	3.52
1262.7998050	1.13
1263.4927980	2.10
1264.6557620	5.72
1265.7368160	1.04
1266.4385990	0.66
1267.5952150	2.80
1268.4532470	8.84
1269.1850590	0.57
1270.0059810	1.74
1272.2795410	5.06
1273.2601320	2.13
1273.9132080	0.93
1275.2062990	6.02
1276.1185300	1.73
1277.0314940	3.47
1278.2855220	1.40
1279.2509770	2.80
1280.2260740	1.33
1281.4251710	19.94
1282.2423100	10.88
1283.0621340	0.82
1287.3737790	65.95
1288.3768310	19.06
1289.2467040	1.26
1291.1715090	0.35
1293.5036620	0.41
1294.1834720	0.89
1295.8067630	4.45
1296.7884520	1.11
1299.0203860	1.49
1299.6342770	2.21
1305.8529050	1.87
1310.2579350	1.47
1312.1835940	0.89
1313.2330320	0.47
1317.1063230	0.18
1318.8392330	2.31
1320.1231690	2.13
1322.5194090	0.78
1325.1036380	3.56
1326.0335690	4.20
1328.4620360	1.03
1329.1434330	1.04
1331.3646240	2.05
1333.5926510	0.89
1334.3712160	0.50
1342.3331300	1.03
1382.3912350	0.59
1393.4107670	0.54
1412.8763430	0.28
1421.3654790	0.98
1423.1020510	0.48
1450.2977290	0.11
1466.5618900	0.51
1507.4910890	0.56
1540.1223140	0.57
1548.6823730	0.76
1556.9738770	0.46
1562.5780030	0.32
1566.6943360	0.17
1618.6781010	0.73
1633.7130130	0.16
1642.5856930	0.69
1660.4232180	0.59
1662.0891110	0.39
1663.4064940	0.90
1675.4221190	0.48
1684.0894780	0.46
1694.9948730	0.16
1701.5472410	0.27
1707.7800290	0.36
1718.5103760	0.19
1739.2985840	0.41
1743.2515870	0.36
1747.4185790	0.28
1776.6666260	1.03
1795.5428470	0.15
1811.5413820	2.00
1818.3054200	0.74
1829.3458250	0.42
1832.1632080	0.95
1842.1292720	1.84
1856.0695800	0.24
1860.5821530	0.68
1866.6043700	0.28
1887.8116460	0.55
1899.7854000	9.48
1936.8396000	0.22
1944.6768800	2.53
1960.8576660	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1034
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
114.7905884	0.08
133.8851318	3.70
146.9217682	2.01
147.5365906	0.18
149.0455780	2.19
153.0447083	0.07
160.4249573	0.14
173.9861755	0.43
178.0666962	2.66
179.0513306	0.09
193.0176849	100.00
201.2849426	0.11
217.1827087	0.30
225.8545227	0.24
233.0955505	0.33
234.9448547	0.41
257.4337769	0.27
259.2009583	0.14
260.7570496	0.14
265.0931091	0.23
275.3543091	0.04
280.1343994	0.10
281.0113525	0.08
285.3174438	0.15
290.1195679	0.12
291.2638245	0.12
293.2942505	1.43
296.4313965	0.14
307.9987793	0.25
309.0969238	1.68
311.2012939	1.25
312.1432800	0.22
313.0674438	0.22
319.1804504	2.72
334.2461243	0.30
335.3855896	0.05
336.9645081	2.31
340.1075439	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	375.093
Annotation	Furaneol 4-(6-malonylglucoside)
Peak:m/z	Relative Intensity
108.1853867	0.09
139.0778046	0.08
158.7774048	0.09
161.2534790	0.14
167.0492249	13.47
177.0646973	0.07
178.7435303	0.06
182.9587097	0.06
189.9772644	0.18
193.3841705	0.24
194.2500916	0.18
194.8763123	0.10
207.3021393	0.09
216.0609436	0.11
238.9280396	0.09
244.1708984	0.12
255.2975464	0.09
256.1032715	0.10
259.3607483	0.12
289.0794678	0.10
291.3851318	0.03
299.4339600	0.12
301.3434448	0.19
303.1780701	0.52
306.4784546	0.07
311.1259155	0.17
312.1795654	0.09
313.1552429	0.23
314.0214539	0.17
317.1673279	0.07
329.1044312	100.00
329.7056580	0.55
331.1658936	0.57
333.3783875	0.26
338.3627014	0.25
339.0084534	0.45
344.3053894	0.05
355.2277527	0.32
356.2568970	1.22
357.0023193	0.74
358.2694702	0.04
359.1990051	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	466.2191
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1070404	0.11
159.1566772	0.30
162.8848877	0.09
165.9711609	0.58
170.9265137	0.41
171.8328552	0.22
173.1135254	0.27
177.0275726	0.08
178.0095215	0.12
179.8838959	0.18
184.0225372	100.00
195.1114502	0.28
199.1260071	0.21
203.0919800	0.19
210.1329346	0.18
222.9304352	0.27
226.3409424	0.05
227.0569611	0.23
235.1579895	0.21
238.2398682	0.15
239.1023712	0.27
240.2181396	0.05
244.3136292	0.13
245.0320129	0.26
245.6556702	0.13
246.9422607	0.17
249.1449585	0.14
251.0645142	0.13
252.1661682	0.51
256.0773315	0.21
257.9999390	0.50
261.6717224	0.20
264.8997498	0.26
267.2622681	0.06
271.0003662	0.04
273.1695557	0.09
277.8751526	0.19
281.1736755	0.27
283.1827393	0.97
285.2582092	0.07
289.1817932	0.10
293.8832092	0.52
295.2335815	0.51
297.9176331	0.08
299.0829773	0.17
302.3088684	0.07
303.2135925	0.37
304.3728943	0.05
307.2321167	0.25
308.2232056	0.56
309.4757385	0.22
313.3455505	0.24
314.8495483	0.21
316.5097656	0.11
318.2335815	0.12
320.9346924	0.42
327.1957397	0.11
329.1204834	0.06
330.2480469	0.34
330.9020386	0.23
332.3029785	0.05
333.1397095	0.21
335.3073425	0.04
336.2381897	0.42
336.9164429	0.51
347.2675171	0.70
348.3186035	0.59
358.5406799	0.29
362.2722778	0.10
365.2893677	0.52
366.3182983	0.28
367.9301147	0.09
375.0407104	1.39
377.6722717	0.35
378.3782043	0.37
383.2933655	0.10
384.8457031	0.85
388.2149963	0.25
389.3198853	0.06
392.8043823	0.61
403.1357117	0.04
406.2140808	0.63
406.9201050	0.04
409.6865845	0.08
411.8505554	0.60
419.8397827	0.15
421.2715759	0.55
422.4839783	0.63
423.3097839	0.14
429.5684814	0.60
430.2483215	0.49
433.1909790	0.06
435.0624084	0.30
438.3675842	0.60
440.3316956	0.12
444.8049622	0.25
448.2460938	42.12
449.0945435	0.49
449.9081726	0.39
451.5485229	0.48
455.7493286	0.64
456.5311584	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	485.2109
Annotation	Unknow
Peak:m/z	Relative Intensity
139.9833984	1.75
148.9678192	0.02
157.9473877	100.00
165.9826050	9.04
167.1867218	0.14
179.2527618	0.06
205.2634888	0.03
221.1945190	0.05
231.2560730	0.13
235.1036530	0.20
238.0731354	0.03
257.0513000	0.04
262.2145386	0.06
266.2354126	0.06
283.1508179	0.03
301.1833801	0.09
302.0675049	0.13
310.0567932	0.02
311.0709229	0.04
318.4471741	0.78
319.3832703	4.50
320.1790771	10.89
322.0038757	0.19
323.0890198	0.87
326.6690063	0.05
328.0451660	0.63
338.4367065	0.16
359.4097290	0.15
369.3499146	0.02
372.9935913	0.11
376.6974182	0.03
382.7167053	0.11
387.1164856	0.09
412.2660217	0.06
435.2812805	0.11
438.0104370	0.12
439.9962158	0.06
449.6847534	0.21
467.3830872	0.64
468.4393616	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	394.16
Annotation	Waltherione A
Peak:m/z	Relative Intensity
126.9852829	0.40
129.9249115	1.49
139.1113281	0.23
143.9967346	1.67
144.9568024	0.83
158.9398651	0.22
161.9998474	9.26
167.0818481	0.34
172.0024414	0.38
190.1255188	2.18
192.0572510	0.14
230.0487976	12.32
245.2050171	0.88
246.1601562	1.24
247.0430298	8.19
248.1384888	41.53
253.1137695	0.14
256.7301636	0.91
260.2280884	0.53
261.1275635	0.25
263.0500488	0.54
265.0926514	100.00
270.6516418	0.20
290.1426392	0.12
304.1163330	0.30
304.9828491	0.27
319.2818604	9.01
341.7619019	1.12
349.4126587	0.54
352.6611328	0.29
354.1232605	1.17
376.2720032	1.93
377.1557922	1.05
383.6833496	0.40
384.7511902	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.5068
Annotation	Namonin E
Peak:m/z	Relative Intensity
861.8345947	0.06
939.7043457	1.86
957.5766602	1.01
982.4135742	0.14
983.4997559	0.29
999.6401367	12.32
1011.7504880	0.23
1012.4265140	0.16
1025.3303220	0.20
1026.0878910	0.17
1043.3081050	100.00
1044.4731450	3.71
1045.2709960	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2236
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1012573	0.17
177.0549927	0.29
179.8785095	0.22
189.3563843	0.14
193.2739258	0.09
229.2270508	0.06
253.3530273	0.05
272.2127686	0.13
297.1312256	0.03
298.3284302	0.05
302.8997192	0.20
304.0905151	0.05
313.0857544	0.08
317.2576294	0.12
320.0073853	0.10
331.1742554	0.08
333.0942383	0.08
334.3355713	0.18
342.2547607	0.10
347.2070923	1.04
361.3700562	0.05
362.1300659	0.18
363.3532715	0.25
367.4505005	0.06
369.2235718	0.08
373.3516235	0.37
377.4128418	0.47
380.3518677	0.59
406.2186890	0.16
410.6899414	0.08
419.2187500	0.66
421.1729126	0.20
434.9129639	0.09
441.4610596	0.16
447.1277466	0.08
448.2798462	0.06
449.1447754	0.31
455.3926392	0.15
463.3031616	100.00
463.9236450	0.41
465.2388916	0.76
473.3083496	0.12
474.4934692	0.20
477.1806030	0.29
488.3521729	0.11
489.0958862	0.81
490.5236816	0.06
491.2974854	0.42
492.3383179	0.21
510.6920776	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1041
Annotation	Unknow
Peak:m/z	Relative Intensity
112.7200012	0.05
119.2163696	0.07
128.8931122	0.16
136.8860931	0.07
145.1375427	0.13
153.1951294	0.74
158.9329224	0.04
161.0907288	1.26
170.9969940	0.45
173.9151459	0.10
181.1145935	0.13
194.9110107	0.05
197.1341248	0.08
199.1944122	0.06
203.2054749	0.10
223.0569153	0.10
225.3646545	0.08
226.3659668	0.05
231.1134338	0.16
250.2489624	0.10
254.9192810	0.09
257.2445068	0.09
259.0151672	0.05
267.2958679	0.05
270.1179810	0.02
272.3406372	0.09
273.1488037	0.10
275.2081299	0.06
280.1524048	0.10
281.2190247	0.04
286.3968201	0.04
290.9560547	0.07
295.3493958	0.22
298.8925476	0.23
302.1740723	0.10
304.2849121	0.16
313.2921448	0.05
315.1256714	5.44
317.1405334	100.00
317.7556152	0.11
320.1676636	0.06
321.4114685	0.03
322.4610291	0.06
324.2249756	0.22
325.1270752	1.59
331.2842712	0.07
333.1566162	0.06
341.0598755	0.19
342.2154846	0.15
343.0841675	0.59
345.1778870	0.13
347.2168274	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.5082
Annotation	Namonin E
Peak:m/z	Relative Intensity
789.1745605	0.04
817.5302734	0.03
837.3043213	0.09
914.4552002	0.15
939.6333008	1.79
957.7683105	0.69
963.5130615	0.07
999.5898438	11.13
1043.2814940	100.00
1044.5207520	3.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.2344
Annotation	Unknow
Peak:m/z	Relative Intensity
154.5395355	0.08
166.0341492	0.23
175.2908173	0.10
177.2541504	0.07
177.9258728	0.07
184.0181732	100.00
189.0032349	0.07
192.0546112	0.15
195.0555420	0.05
198.3922119	0.04
201.9004059	0.09
207.1557007	0.09
209.0983429	0.15
210.0150757	0.14
212.6969604	0.08
216.1476746	0.41
219.1688385	0.05
223.2362061	0.20
226.1179047	0.17
227.2049561	0.09
229.5065460	0.16
231.3628540	0.19
238.8384094	0.13
257.2286072	0.10
258.0976868	0.37
259.2271118	0.12
261.3565063	0.16
263.9400940	0.15
265.0379333	0.10
267.1670227	0.11
270.1951294	0.06
276.2022095	0.32
283.2929382	1.98
297.2817383	0.50
298.2192383	0.30
300.9334717	0.96
301.5486450	0.12
304.6113281	0.17
308.0535889	0.17
312.4428406	0.14
313.6096497	0.06
317.1816406	0.28
318.2469482	0.37
319.2140198	0.12
331.9507446	0.03
335.2501221	0.51
338.1739197	0.20
339.4470520	0.52
342.4092102	0.42
345.2638550	0.05
359.0098267	0.12
360.3538208	0.32
361.4227905	0.19
363.9489136	0.14
366.2822266	0.23
369.5908203	0.24
377.5889587	0.24
388.8264160	0.15
391.2624817	0.15
392.3930969	0.51
393.2430115	0.09
394.3638000	0.60
396.6662903	0.19
397.3415833	0.16
398.3834839	0.34
400.8877869	0.19
402.6486206	0.16
404.9088135	0.12
405.7902527	0.34
406.4361267	1.18
407.4929504	0.38
409.0781555	0.76
412.3058167	1.22
413.5229187	0.41
418.2487183	0.09
420.8067322	0.55
426.3128967	0.57
427.4627991	0.32
433.1736450	0.27
434.6125793	0.07
435.5293884	0.02
436.3957825	0.04
437.1868591	0.29
444.3190918	0.79
445.1435852	0.89
447.4292297	0.04
448.7529297	0.18
453.9596863	0.34
456.4909973	0.19
459.4837952	0.12
462.3493042	46.04
463.2788391	0.18
469.0619507	0.20
471.2477112	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.86
Annotation	Unknow
Peak:m/z	Relative Intensity
97.1269684	0.05
104.1142120	0.06
104.8050385	0.10
126.9544754	0.22
131.2112122	0.13
143.8761902	0.03
146.2185974	0.12
147.0902100	0.09
152.7756348	0.05
173.0529785	0.34
179.9352417	0.12
180.9131470	2.84
201.3916321	0.06
214.9873962	1.46
225.1223755	0.09
228.8891602	0.09
231.7287292	0.21
232.9071960	21.12
252.8701782	0.64
270.8346863	2.45
272.2263794	0.02
272.9279785	0.03
284.0694580	0.13
289.0396118	0.08
296.3406067	0.03
298.8928223	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.17
Annotation	Isatidine
Peak:m/z	Relative Intensity
105.8523483	7.41
116.0578003	0.25
117.1529160	0.08
122.1261520	0.04
123.0835266	0.19
129.9733887	0.35
130.8945770	0.14
136.8682251	0.04
138.2191620	0.17
142.8463440	0.09
146.8486328	0.10
157.1759033	0.11
157.8830566	0.27
159.2065582	0.36
160.2270813	0.30
161.0499573	0.18
170.4463959	0.48
171.1160736	0.20
172.0529480	0.18
173.0415344	0.31
175.1829529	0.06
177.2051697	0.05
179.9721069	0.05
181.0071716	0.12
182.8022003	0.20
183.4463501	0.02
184.1524353	0.36
187.1291809	0.06
188.8833313	0.43
192.3110962	0.35
194.0470734	0.07
197.3158875	0.06
198.1337280	0.36
199.0107422	0.38
201.0355835	7.45
204.9915314	0.26
207.0178680	0.05
208.1856995	0.06
211.1035461	0.07
217.2146912	1.25
219.0729065	0.64
220.3630066	0.13
227.0336609	1.66
233.1302185	0.16
235.3154907	0.09
245.1850891	100.00
247.3375854	0.07
248.2175903	0.04
251.3847046	0.03
256.2194214	0.03
257.4689941	0.12
260.4930115	0.12
261.1840820	0.25
263.0570984	10.86
266.8827515	0.17
268.0693359	0.07
270.0520630	0.05
275.0476074	0.25
279.6401978	0.08
284.8161316	0.12
286.2495728	0.41
287.1950684	0.07
288.5729980	0.24
291.1239014	0.18
292.2341003	0.83
296.3680115	0.15
297.1312561	0.13
303.7565002	0.18
304.3770142	0.45
305.2557068	0.26
306.2578735	0.16
307.1271057	0.04
308.0632629	0.31
309.1405640	0.16
310.3811951	0.12
312.0061646	0.08
313.2708740	0.05
314.1840820	0.14
315.1687927	0.11
319.2456055	0.11
322.0990601	1.06
323.0733032	0.08
324.1332397	0.23
325.3307495	0.26
327.2597656	3.09
328.5300903	0.50
331.6641541	0.39
332.3247986	4.91
333.2376099	0.75
333.9808350	0.42
335.8469849	0.34
337.1617432	0.17
342.6088257	1.70
343.4118042	0.28
345.3089905	0.30
347.2967834	0.19
350.1138306	49.23
350.9230957	1.42
351.9006042	0.43
353.6332703	0.40
355.2063293	0.19
358.2215271	0.69
359.3328857	0.52
361.7377930	0.12
376.4873657	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	881.4524
Annotation	Unknow
Peak:m/z	Relative Intensity
289.3420715	0.01
327.4053955	0.02
371.6440430	0.01
520.7386475	0.00
534.3225708	0.02
597.2556763	0.01
615.2817383	0.01
616.8023071	0.02
676.5086670	0.02
678.3159790	0.02
706.6294556	0.04
713.5592041	0.03
714.8828125	0.03
718.4147339	0.01
729.8321533	0.01
742.9655151	0.01
748.5361938	0.10
760.5549316	0.02
777.5715942	0.51
778.6070557	4.09
779.4731445	0.03
796.4795532	7.99
797.2539673	0.01
802.5502319	0.01
822.5562134	0.01
838.4682007	100.00
839.2007446	0.32
840.8535767	0.09
862.5425415	0.07
864.7659912	0.02
882.1195679	1.50
883.3651123	0.28
884.0134888	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8062286	20.48
212.8335571	0.03
245.7775879	0.08
254.7443848	0.05
290.7258606	100.00
291.3354492	0.20
296.8477173	0.29
315.1096802	0.10
338.7500305	1.15
352.8393860	0.16
368.8920288	0.08
374.0812988	1.63
374.7014465	24.63
375.5028381	0.03
398.8566284	1.63
412.8850098	0.31
428.6443481	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.12
Annotation	Unknow
Peak:m/z	Relative Intensity
137.1012268	0.09
150.9558716	0.36
164.0944519	0.35
164.9470520	0.32
195.9227905	0.13
211.1042786	0.08
221.1076965	0.04
235.4194946	0.07
242.0353394	0.11
278.0697937	6.21
279.2123108	3.80
280.0472107	5.88
281.5409851	0.23
283.0797119	0.19
286.2196960	0.43
287.1552734	0.24
308.3387451	0.20
326.3336792	0.23
330.5097656	0.07
332.7587891	0.15
335.5414124	0.05
346.0692139	0.06
353.1665649	21.32
353.7876587	0.21
356.3567200	0.08
360.1318054	0.15
381.2243347	0.36
383.3143616	0.05
397.3536987	0.56
399.0485229	100.00
399.6795349	1.08
400.9853821	0.14
409.2055054	0.10
417.2873840	0.08
424.0035400	0.36
427.6673889	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.17
Annotation	Spectinomycin
Peak:m/z	Relative Intensity
97.0290375	0.09
98.1046448	0.03
100.8876572	0.02
116.9029999	0.15
119.1015015	0.04
120.1390839	0.21
123.0170746	0.12
127.1151733	0.07
129.1660614	0.07
135.1329651	0.12
139.1658936	0.03
140.8706818	0.36
147.9038391	0.03
150.9292603	0.07
152.0253601	0.03
152.7373657	0.04
155.0440979	0.04
162.8882141	0.04
164.0707092	0.16
169.3139496	0.03
170.9891357	0.03
171.8852844	0.05
174.9081726	0.12
177.0102844	0.03
178.8765564	0.04
182.0277405	0.03
187.9764404	0.07
192.9775085	0.27
197.0327301	0.04
199.2550049	0.15
204.0780945	0.01
209.1608887	0.01
211.0198059	0.05
217.1885071	0.02
221.0910950	0.08
227.1433411	0.07
234.6701050	0.09
238.9328003	0.08
240.6698303	0.05
243.1014099	0.04
246.8233948	0.08
248.2165527	1.26
251.0367432	0.06
251.9600220	0.25
255.0409241	0.13
256.9982910	0.02
258.6262207	0.15
259.2544556	2.32
268.9880981	0.06
269.9819336	0.21
270.8525696	0.04
272.9985962	0.33
274.2522278	0.10
278.7619324	0.01
281.7659912	0.06
284.1600647	52.19
287.2397461	0.19
288.1797791	0.12
289.2619629	0.08
291.1900330	100.00
297.1061401	0.15
299.4394531	0.07
301.2224121	7.43
302.0947876	8.02
302.8656006	0.10
305.2485657	0.06
306.2743835	0.04
311.0571594	0.46
312.0311279	0.06
313.2770081	0.24
314.9943237	1.39
316.1289062	13.30
317.1125793	0.17
318.0145264	0.15
324.1188354	0.13
333.0775757	0.08
344.2241516	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Unknow
Peak:m/z	Relative Intensity
119.9059448	100.00
120.8806915	0.02
130.9234924	0.15
147.8457184	0.73
148.9833374	4.09
166.1200409	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	567.83
Annotation	Unknow
Peak:m/z	Relative Intensity
206.6914673	0.67
216.0648193	0.32
231.9326782	13.64
270.3004150	0.09
315.9159546	27.16
353.9375000	8.75
374.0418701	0.17
391.1333008	0.36
399.8406372	45.94
402.1557617	0.14
413.4449463	0.26
427.2882080	0.19
433.8697510	0.15
434.5675659	0.09
437.8126831	30.80
438.5114136	0.07
447.2832031	0.16
481.8248291	1.79
483.7337036	66.34
484.5143433	0.19
519.4960327	0.10
521.7161255	100.00
522.4518433	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1442
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
174.9812012	0.13
176.9674683	0.41
179.0561523	2.77
184.9063721	0.67
192.8949890	0.13
197.0395355	0.72
203.0147858	0.37
208.3015747	0.04
210.1737671	3.37
213.2773285	0.22
225.9575195	0.44
228.0711670	0.27
229.1218719	0.11
231.0605774	0.06
236.2937775	0.18
242.1945801	0.18
252.1832581	0.14
254.1736298	13.65
258.1465149	0.09
258.9521790	0.12
268.2355957	0.08
270.1393433	0.15
272.1836548	41.22
272.9196167	0.09
286.2015381	0.96
288.2231445	5.39
293.2296753	0.06
304.1378784	13.61
306.0570679	100.00
306.6679688	0.11
314.1416626	0.07
316.0838013	0.08
320.1354675	0.60
338.1176758	24.77
353.1138916	0.09
361.3216553	0.51
362.0940552	0.07
363.3407593	0.07
395.2354126	0.24
406.0626221	0.18
418.2455444	0.19
451.2792969	0.14
452.3232422	0.07
464.2254028	0.30
482.2792358	16.96
499.9327393	0.08
524.4567871	0.17
562.5222778	0.22
566.3029175	0.27
566.9418945	0.11
575.3010864	0.31
592.7413940	1.18
593.3469849	8.65
594.3063354	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.098
Annotation	Crotonoside
Peak:m/z	Relative Intensity
82.1545334	0.03
87.0137024	0.04
87.8590393	0.05
88.7715607	0.05
90.0830383	0.02
94.8881912	0.15
96.0417938	0.02
96.9617920	0.02
98.8494263	0.05
109.1239319	0.04
113.1442566	0.01
115.0848465	0.08
119.8314514	0.05
120.7175598	0.01
122.5853195	0.06
123.2458038	0.07
125.1067200	0.03
127.1826630	0.02
128.9702301	0.06
133.0804138	0.07
133.9165955	0.17
134.9001923	0.09
136.0376892	0.08
137.2665405	0.07
149.0030518	0.04
151.9313660	100.00
152.6781311	0.01
162.9880066	0.23
165.2087402	0.06
168.9545441	0.12
171.9230804	0.04
175.0803070	0.01
177.2114258	0.13
178.0383148	0.02
183.0430145	0.03
191.1139832	0.09
196.6857605	0.05
204.1444092	0.04
209.0513000	0.10
212.9865417	0.02
214.2562866	0.04
221.0982971	0.02
225.0938416	0.03
230.5534668	0.07
231.1623535	0.03
232.7437439	0.03
236.0689087	0.02
237.3546448	0.04
238.0129700	0.10
239.1231689	0.41
240.0668335	0.02
241.2901001	0.12
241.9956360	0.04
242.9484558	0.02
247.0858154	0.19
248.2122803	0.25
248.9852295	0.06
260.9186096	0.06
261.8034668	0.04
265.1678162	0.29
266.0937500	0.46
266.9835510	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7861328	4.55
219.0992126	0.20
290.8859253	1.12
296.8032532	29.47
303.0143127	1.01
335.0408936	0.20
345.0625610	0.54
350.6026001	0.61
374.8070679	0.20
378.2243652	0.93
380.6103516	77.62
381.3605347	1.29
382.8367310	1.77
386.8244019	7.97
408.1157227	0.44
412.8280029	0.94
424.8249512	12.45
428.7180786	3.77
442.6473389	1.41
454.7369995	0.28
458.1863403	0.16
462.0617065	2.00
463.1669922	1.90
464.6243286	100.00
465.3349609	0.37
466.7900391	21.42
470.7788086	15.32
485.0133667	0.78
488.7331543	0.30
496.6618652	14.96
497.2820435	1.18
508.4481812	0.49
512.8287964	5.25
524.1406860	0.63
526.6574097	3.79
530.9572144	0.23
538.6791382	0.91
545.8821411	0.61
547.1052246	0.39
548.1044312	22.99
548.7841187	53.43
556.4700317	1.29
568.7068481	1.41
572.6525269	3.77
586.6804199	5.26
632.3690186	1.71
633.0244141	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	701.39
Annotation	Cimiracemoside O
Peak:m/z	Relative Intensity
221.2703705	0.41
255.3391724	0.18
290.1299133	0.34
301.1130981	0.23
315.4443359	0.22
321.6889038	0.38
361.1693726	0.21
395.5262451	0.24
406.8345337	0.31
419.2722778	0.58
435.4409790	0.30
441.3902588	0.10
444.2697754	0.11
451.4524536	0.37
468.4348145	0.41
470.1977539	0.09
472.3613892	0.72
486.4071045	0.96
488.3081665	0.47
504.1322021	0.89
512.3116455	1.18
519.4107666	0.46
532.2338867	0.42
533.3366089	0.38
540.5841064	0.13
541.5341797	0.43
544.2944946	2.02
546.4660034	0.99
552.4488525	0.21
601.3515015	0.67
609.4358521	2.01
625.5023193	3.66
626.5582275	0.42
639.2265625	0.19
641.2593384	4.27
651.3501587	0.15
655.5274048	0.78
657.4307251	0.26
666.6087036	0.12
669.4130859	100.00
670.4442749	4.72
673.6675415	0.13
683.0040894	0.31
683.7030640	0.34
684.6132202	0.07
685.6632690	0.63
702.3129272	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1663
Annotation	Verbasoside
Peak:m/z	Relative Intensity
131.0155182	0.02
137.2867889	0.03
148.9743652	0.12
164.5595856	0.05
168.9248047	0.02
173.1975098	0.08
177.0518951	0.04
180.9443665	0.03
192.9340210	0.04
197.1304321	0.13
225.1877441	0.05
233.1905060	0.04
254.1175232	0.07
267.2781067	0.01
268.0506897	0.04
272.0590820	0.14
283.1279297	0.10
288.0509949	0.06
292.8125000	0.09
298.6044312	0.10
306.1618958	1.57
307.2520752	0.16
310.3293152	0.09
312.3119507	0.04
325.0122986	0.06
327.2520752	0.01
329.5104370	0.10
330.2950134	0.28
338.4947510	0.04
341.2555542	0.02
355.1193848	0.06
356.2689819	0.02
359.1713562	0.03
361.5928650	0.02
364.4608765	0.06
365.1015320	0.04
371.3800964	0.04
372.1785889	0.04
381.0830994	0.02
387.2514343	0.02
389.2027283	0.04
392.9503174	0.09
396.4659424	0.03
397.2936401	0.27
399.3759460	0.14
400.3716431	0.70
401.1032715	0.09
415.2388916	100.00
415.8739929	0.59
417.0010376	0.08
424.2438049	0.16
425.6089172	0.03
440.9971924	0.04
442.3954773	0.19
443.4517517	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	771.3926
Annotation	Hoiamide C
Peak:m/z	Relative Intensity
217.3091888	12.07
235.0073242	7.95
238.9453888	19.84
253.2715454	5.33
261.3709717	5.42
280.9470215	8.34
286.6671753	4.16
296.3352051	12.46
303.3712158	4.64
319.2010498	5.43
335.2182617	11.48
336.2981567	3.73
341.2906494	7.01
373.625	17.61
391.432312	6.53
393.4701538	3.05
395.4088135	18.48
405.1866455	3.90
417.3447876	11.37
419.5001831	17.32
452.9765015	4.89
461.5651855	6.65
473.0876465	8.09
481.4872437	4.80
509.4034424	30.61
527.4993286	12.05
545.6148682	12.61
581.3914795	7.11
631.4406128	36.60
637.2686768	10.21
639.4476929	33.71
649.5778198	5.86
667.5733032	45.23
684.5653687	11.98
685.5974731	7.82
711.7019043	4.90
727.5973511	15.76
735.003479	16.85
738.9227905	9.77
752.855896	29.04
771.3759155	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.44
Annotation	REBAUDIOSIDE A
Peak:m/z	Relative Intensity
569.6071777	0.53
874.296875	0.79
877.6086426	4.25
921.37146	21.71
964.6383667	28.53
965.397644	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2715
Annotation	Ansamitocin P 4
Peak:m/z	Relative Intensity
435.2823486	0.09
446.5313110	0.77
447.3427124	1.96
448.3330078	0.53
449.3553467	0.04
513.4299927	0.02
541.5168457	0.02
542.4179077	0.11
543.3034058	0.30
544.3895264	2.77
545.4884033	0.74
586.3340454	5.89
587.4836426	1.90
588.6770630	0.06
604.3370361	100.00
605.3567505	12.84
606.2425537	0.01
613.4148560	0.03
617.3569946	0.02
630.4577637	1.60
631.5101318	0.27
649.1841431	2.90
649.9086304	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.4681
Annotation	Cyclotheonamide E4
Peak:m/z	Relative Intensity
539.6021729	0.01
615.4689941	0.06
633.5210571	0.09
657.2892456	0.01
692.7211304	0.06
703.9984741	0.02
713.7149048	0.07
724.1426392	0.04
731.5908813	0.04
743.6763916	0.03
747.8617554	0.26
759.6168213	0.10
776.2556152	0.02
777.6254883	2.94
790.3530884	0.02
791.1824341	0.01
795.6932983	5.14
797.1182251	0.02
818.1898193	0.04
819.3231201	0.07
820.1278687	0.05
837.5083618	100.00
838.1764526	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1304.7897
Annotation	Unknow
Peak:m/z	Relative Intensity
970.0321045	0.63
972.1381836	0.06
1013.6806640	0.21
1106.4365230	0.20
1124.4282230	0.13
1171.6625980	0.18
1220.2642820	0.81
1230.4006350	0.67
1241.9923100	0.73
1280.6989750	1.05
1284.6984860	0.21
1303.3837890	0.14
1305.0395510	100.00
1305.8566890	32.95
1306.5422360	4.16
1307.2211910	1.04
1307.9680180	1.13
1308.8054200	0.52
1309.5653080	0.63
1310.4790040	0.65
1311.5350340	0.69
1315.1804200	0.47
1315.8974610	0.13
1316.7694090	0.20
1318.7298580	0.21
1323.2706300	1.19
1341.1534420	0.09
1352.4837650	0.47
1398.3289790	0.26
1408.4541020	0.04
1410.7615970	0.88
1415.3828120	1.25
1428.3358150	0.15
1454.6724850	0.20
1460.6735840	1.16
1521.8016360	0.45
1539.1768800	0.39
1548.1744380	0.26
1554.1169430	0.04
1560.9768070	0.77
1563.8122560	0.66
1606.0601810	0.56
1611.2675780	0.68
1613.3038330	0.31
1621.3817140	0.85
1655.5360110	0.51
1675.6569820	0.06
1706.2592770	0.57
1708.1704100	0.53
1736.5811770	0.07
1755.7481690	2.76
1824.6262210	0.16
1829.0250240	0.67
1840.5002440	0.20
1879.4694820	0.09
1886.4862060	0.36
1896.7664790	0.26
1898.4031980	0.51
1906.3864750	0.06
1928.3269040	0.47
1971.7806400	11.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
830.2522583	48.29
835.3491821	18.46
966.5103149	21.20
967.4424438	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	863.4427
Annotation	Unknow
Peak:m/z	Relative Intensity
303.1970215	0.05
568.4913940	0.06
746.8078003	0.13
765.1848145	0.12
788.8940430	0.09
818.6837769	0.21
820.6146851	0.06
821.6843262	0.14
863.5728149	100.00
864.3471069	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	832.406
Annotation	Unknow
Peak:m/z	Relative Intensity
327.5428467	0.02
446.4913330	0.02
568.7366943	0.03
596.6623535	0.03
672.5516357	0.29
678.2098999	0.01
686.3341675	0.05
714.9076538	0.05
796.6417236	0.09
833.5720825	100.00
834.2776489	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.23
Annotation	Unknow
Peak:m/z	Relative Intensity
133.0300903	0.12
135.2232971	0.24
141.9111176	0.22
145.4575195	0.24
146.0960693	0.17
147.0990295	0.09
155.8934631	0.92
158.1355591	0.20
159.3169861	0.21
160.1080933	0.08
161.1623230	0.10
162.1383362	0.14
168.9910278	0.12
169.9493103	0.71
171.0240784	0.18
173.0246429	0.31
174.2012329	0.11
184.0639648	0.32
185.1045380	0.17
187.1428528	0.17
188.7857056	0.11
198.0212250	1.50
199.0614014	0.47
202.8054047	0.04
208.2989655	0.13
209.1324463	0.16
211.9918213	1.58
213.4233093	0.14
215.1293945	0.07
217.1111755	0.07
224.0260925	0.76
226.0724487	1.69
227.2467346	0.14
230.3707581	0.15
236.1956482	0.06
238.0790710	3.74
239.9549561	1.39
241.0892639	0.12
241.8844604	0.65
248.5505981	0.14
252.0644836	3.52
254.1313782	0.75
255.4115295	0.30
256.9716492	0.15
261.4654236	0.23
266.0175171	0.52
268.1232910	0.41
277.2305908	0.20
280.1827698	0.59
282.0840759	0.63
283.1976318	0.51
286.1943359	0.41
292.3880920	0.35
294.1341553	0.38
297.2493286	0.63
299.3153687	0.11
303.2139893	0.15
304.0598145	0.20
305.7291565	0.39
307.3417358	0.35
308.2410278	0.53
309.6549377	0.30
310.8415222	0.18
311.4761047	0.52
314.1710815	0.48
321.1805115	0.12
324.6439209	0.07
332.1346741	0.40
333.0080872	0.13
334.2115784	3.01
336.1728210	100.00
337.3232422	17.68
338.2796326	37.36
339.0196533	0.42
339.9978027	0.09
350.7945557	0.11
352.2379761	0.42
353.8921814	1.28
354.8492737	2.39
355.7960510	11.56
359.1694641	1.09
359.9781494	0.30
364.3924255	0.17
365.5709534	0.14
367.0323486	0.09
367.8536072	0.22
368.9613342	0.06
372.4112244	0.13
373.6407776	5.20
375.0575256	2.45
376.1932678	1.34
377.1408997	0.29
378.0776062	1.62
378.6875000	0.12
381.1817627	1.75
382.1145935	0.53
384.1227722	0.46
384.9172058	0.21
387.1113892	1.44
390.5957336	0.71
395.9313049	1.40
398.8522339	0.09
406.0018005	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	603.2035
Annotation	Unknow
Peak:m/z	Relative Intensity
183.9945679	0.08
189.7761993	0.29
212.8718262	0.53
214.0991364	0.09
217.1826782	0.05
240.0941467	0.26
242.2810059	0.06
244.8686218	0.26
250.9375916	0.53
257.0678101	0.27
282.1883545	0.16
284.8445435	0.73
291.4436646	0.12
294.4522705	0.06
296.2276001	0.37
301.9684143	0.05
306.5401611	0.08
313.2942505	0.08
314.3069153	0.41
328.4582520	0.07
335.5000610	0.04
336.1959839	0.26
346.2529297	0.09
348.1044312	3.74
354.6104736	0.37
358.1325684	0.14
376.3378296	0.03
386.2723999	0.25
391.5676270	0.20
395.3267822	0.59
399.4388428	0.05
402.1557617	0.07
404.1671753	0.18
407.0028076	0.16
408.9780884	0.06
415.0483398	0.18
417.1122437	4.96
422.1673584	0.26
428.7505493	0.29
430.3329468	0.58
437.0892944	0.34
439.0442505	0.06
440.8630981	0.16
443.0867920	0.40
445.2102051	1.79
448.8533325	0.15
450.1825562	0.07
452.2755127	1.20
453.3811035	0.21
457.4319458	0.05
469.7601318	0.30
474.3851318	0.93
487.2834473	0.11
497.1036987	0.28
499.2951660	0.47
504.1161499	0.29
506.2163696	3.36
507.3549194	0.58
513.3505249	0.84
521.1032104	0.20
522.1823120	0.20
528.9415283	0.17
531.7472534	0.44
534.6714478	0.18
539.3841553	0.20
543.2669067	0.64
545.4624023	0.16
556.4052124	0.39
557.6911011	0.41
558.4574585	0.14
560.3272095	0.08
562.7734375	0.85
568.3641968	0.15
583.8688965	0.33
586.2836304	100.00
586.9528198	0.28
604.5762329	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9105072	0.39
270.2199097	0.07
302.9340210	10.87
374.8778687	0.06
378.2709351	0.97
379.2471313	0.31
380.1619873	1.44
381.3032227	0.04
386.8148804	50.61
394.7916260	0.06
417.9847412	0.08
441.8187866	0.20
443.0714111	0.10
443.9556274	0.21
470.7194824	100.00
471.4445801	0.09
477.6587524	0.15
483.8689575	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	431.03
Annotation	Unknow
Peak:m/z	Relative Intensity
121.0059967	0.12
142.0412903	0.04
145.0264587	0.14
145.9758606	0.11
148.1417542	0.21
149.0417480	0.34
156.9254150	0.06
168.0280457	0.11
170.1093750	0.04
172.8131104	0.05
178.9083557	0.19
187.0863647	0.14
197.0345764	0.12
201.0560913	0.11
202.1717072	0.17
210.9586182	0.46
216.3141632	0.13
218.3718567	0.09
230.9557343	0.08
235.0538635	0.18
237.3810120	0.19
243.2070007	0.27
248.1798096	0.10
249.4709473	0.09
250.2284851	0.10
253.5256958	0.09
255.3731384	0.12
261.2455750	0.37
263.1102600	0.12
268.8261414	0.12
271.1308899	0.06
272.3912659	0.10
274.1082458	0.04
276.4222412	0.44
283.1222534	0.77
286.2727051	0.10
295.1348877	0.43
299.3590698	0.35
301.5040894	0.17
305.1512451	0.31
307.1252136	0.95
310.4025574	0.04
313.9309692	0.31
316.0187378	0.22
319.2314453	0.34
320.6364746	0.52
323.3869629	0.07
325.0868530	0.33
326.3172302	0.09
327.0105896	0.06
329.9555054	0.43
333.2837524	0.30
334.0712891	0.36
335.7562866	0.58
336.8234863	0.29
339.3397217	0.19
342.0058594	0.09
345.0054321	0.24
348.9783630	2.15
353.3885498	0.04
355.9372559	0.22
364.9989014	0.05
367.0128479	0.21
369.2101135	0.32
371.4379272	0.03
372.1246643	0.13
385.0412292	100.00
385.6699524	0.19
389.2475281	0.06
390.0546875	0.31
393.5939331	0.04
394.5044861	0.62
395.5255432	1.01
401.5777893	0.10
402.3811951	0.12
408.0571289	0.29
411.0174255	0.09
412.2810669	0.81
413.2430115	2.90
415.0029602	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.4
Annotation	Vincristine
Peak:m/z	Relative Intensity
469.6234741	5.48
514.1987915	5.04
555.4205322	6.19
556.7054443	22.52
735.1154175	2.86
762.6591187	2.90
779.055603	10.37
805.1697998	2.55
822.4286499	11.87
823.4279785	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	354.0843
Annotation	Unknow
Peak:m/z	Relative Intensity
101.8541412	0.14
103.7721558	1.41
105.0074158	0.08
116.0136871	0.11
116.7345963	0.07
117.9923401	0.08
119.1176529	0.15
119.9131775	0.31
127.8684235	0.80
129.0201111	0.08
132.9219360	17.66
135.9657745	0.11
137.9526672	0.05
141.1436768	0.05
141.9118652	0.11
146.0397797	0.42
148.1192474	0.49
150.0221558	100.00
156.0304260	0.60
157.2312012	0.70
162.0130310	0.37
162.8757629	0.52
163.8435364	0.47
164.9786987	0.10
174.0133667	17.65
175.0553284	1.08
176.0132141	0.54
178.9810486	1.82
179.9810486	0.65
180.9333191	0.40
183.0284576	0.21
187.8774872	0.10
190.0714264	0.06
192.0421753	2.78
193.1282349	0.24
198.2176666	0.09
203.2205200	0.06
205.1076508	0.06
206.6475372	0.16
207.8808594	0.07
209.1458435	0.05
213.9639587	0.35
215.9570618	0.04
217.8426208	0.03
221.0226135	1.60
222.1910400	0.66
224.0196533	0.21
225.0229187	0.33
225.8718872	0.07
226.9705505	0.23
229.2710876	0.10
232.7457581	0.24
234.4729919	0.09
235.2514954	0.07
236.6377563	0.11
238.1518555	0.12
239.3168335	0.08
241.0097046	0.08
242.1040649	0.18
245.8455811	0.15
247.6702881	0.40
249.9934387	0.09
251.8648376	1.21
253.5980835	0.57
254.9456177	0.09
256.3307190	0.12
258.4582214	0.16
262.2525940	0.07
264.2223816	0.16
266.4508057	0.11
268.0675659	0.40
269.2894287	0.29
273.3636169	0.11
279.0219116	0.22
280.4081421	0.26
281.1875610	0.08
282.2493591	0.07
283.5588684	0.08
289.6885986	0.21
292.2462769	0.31
293.1673889	0.14
294.2615967	0.08
295.2833557	0.07
295.9257202	0.06
302.9403687	0.03
304.7902832	0.25
307.9937439	0.49
309.0748901	0.33
310.1640015	0.22
312.3338623	0.19
313.2898254	0.86
316.3126526	0.03
317.2064819	0.43
319.0552673	0.04
322.0700684	0.29
325.4151306	0.19
333.2833557	0.18
334.3219299	0.17
335.2480164	1.80
336.2610474	2.16
337.0930786	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9267502	5.66
130.8725586	0.29
156.8884277	0.06
158.9648285	100.00
161.2779236	0.01
198.9783020	2.21
200.4049988	0.06
201.0423889	0.10
217.0401611	1.28
228.9850464	25.16
244.9565125	0.46
246.9852295	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	282.0843
Annotation	Crotonoside
Peak:m/z	Relative Intensity
107.0360794	0.16
108.0746918	0.06
132.9712830	3.94
149.9833832	100.00
152.9203033	0.07
192.1269836	0.03
198.0577087	0.07
209.9152222	0.07
219.1592407	0.07
236.0205688	0.40
238.1656799	0.17
252.1508789	0.16
256.1718750	0.06
264.2050171	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	432.81
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9663086	0.63
131.0384979	0.04
156.0508270	0.04
173.1627350	0.11
174.0007935	0.25
181.3009338	0.04
218.7514954	0.12
252.9273071	0.04
289.1517944	0.06
302.8892822	8.73
303.5082092	0.03
312.5418701	0.11
331.3194275	0.05
347.1979980	0.30
348.4320374	0.87
349.2129822	0.95
370.8921204	0.02
372.9653625	0.03
385.0050354	0.03
386.7358704	100.00
387.5014954	0.15
398.0450745	0.02
414.7303772	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	158.08
Annotation	Tiglylglycine
Peak:m/z	Relative Intensity
69.8671570	1.90
101.1105042	0.07
101.9558563	0.21
106.8626251	1.77
111.8896332	89.83
112.9610138	0.11
114.0332184	0.25
116.0047302	2.07
116.8455048	7.72
129.9523621	0.03
137.6393280	0.18
139.8748322	100.00
148.6518250	0.23
157.7743073	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.07
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.9987793	0.47
176.9595490	0.42
191.9357605	0.17
193.0676422	0.19
211.0781860	0.38
213.0293732	0.04
216.8242035	0.58
222.0214386	0.92
222.9743652	0.06
240.1220703	0.53
241.1086578	0.35
246.1262817	0.75
255.2957458	0.07
257.0642700	0.55
259.0249023	0.10
261.0065918	3.24
261.9216919	0.13
264.1416016	2.02
269.0605469	0.39
273.0588684	20.15
280.1940002	1.17
282.0498352	31.48
291.0180969	0.56
300.1171875	6.67
305.0958252	6.93
311.1671143	0.15
323.0729370	25.53
323.9872437	0.62
325.0432434	1.71
326.2940063	0.09
330.7819824	0.24
331.4633179	0.15
333.0858154	0.20
334.2523193	0.22
342.1640015	0.40
344.0132446	2.01
346.0570679	0.08
352.2902222	0.14
359.1376343	0.09
360.2730103	0.28
360.9430542	0.44
362.0571899	20.59
362.6711426	0.08
367.1393433	0.04
372.2723389	0.11
376.9755859	0.20
377.8191528	0.24
379.3320923	0.44
380.1415405	0.12
385.0731812	100.00
385.7211304	0.09
393.1978760	0.49
396.1658325	0.20
398.0648804	0.20
403.0772705	46.17
407.1636353	0.09
418.2238159	0.18
420.9786987	0.15
422.1854248	0.05
424.1187744	0.11
425.1562500	0.07
426.8771973	0.86
430.8197632	0.16
433.2274170	0.11
433.9209595	0.15
438.1608276	0.09
441.2553101	0.53
441.9829102	1.23
443.1213379	2.99
444.1342773	0.11
449.0679932	0.04
450.6224365	0.42
461.2249756	0.09
464.1186523	0.24
464.7445068	0.05
465.3900757	0.18
469.5128174	0.12
470.5108643	0.57
471.5182495	0.88
472.2230835	1.84
483.1475220	0.38
484.0057983	0.07
485.0179443	2.55
486.1317749	0.57
489.4444580	0.06
492.8973999	0.33
494.1854858	1.49
507.6684570	0.27
508.3347778	6.31
518.1010132	0.10
521.0826416	1.37
521.9266968	1.73
523.0639038	0.22
526.2904663	0.58
527.1542969	0.05
541.6237793	0.14
544.0455933	0.04
558.9814453	3.86
560.2897949	0.09
562.1272583	5.89
563.2266846	1.35
584.9542847	0.06
587.0651855	2.23
589.0510864	0.31
607.5302734	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.75
Annotation	Unknow
Peak:m/z	Relative Intensity
145.0429077	0.40
162.8220978	0.12
176.6338654	0.04
184.0769043	0.82
189.0796814	0.14
194.9686890	0.31
197.1885376	0.16
198.9497375	0.09
201.2797546	0.09
202.9472961	0.20
208.9915924	0.10
215.1535492	0.34
231.0999146	0.19
257.1513367	4.30
271.1312866	0.08
281.3721313	0.08
283.3823853	1.19
288.0826416	1.54
288.8406372	0.89
290.2736816	0.28
297.1385498	0.14
298.8503418	0.22
300.2468872	0.07
308.2801514	0.04
309.2334595	0.35
311.2792358	0.26
312.1971436	0.37
313.3717041	0.42
315.3863525	0.23
317.1669312	0.18
318.8235474	0.12
321.7079468	5.60
327.3073730	0.09
330.8823242	0.40
334.2436523	0.37
335.2197876	0.30
336.6128540	0.24
343.3275757	0.15
353.1304932	0.03
354.2707520	0.08
361.3981323	5.75
364.0598755	0.10
368.4177856	0.35
370.3154297	7.21
372.0609741	0.25
376.9293213	0.23
382.9095459	0.33
385.3521729	0.47
386.2206421	0.07
390.0665894	0.16
397.3566895	2.91
399.5933228	0.07
402.0661011	0.24
403.8356934	0.12
406.1838989	0.23
417.1968384	1.28
425.8817749	6.97
428.2516479	0.16
434.7779541	100.00
435.3903198	7.19
436.1306763	0.52
437.1381836	0.49
438.4689331	0.10
439.8792114	0.12
440.5889282	0.31
448.5198364	0.30
455.0069580	0.32
456.5891113	0.28
457.4303589	0.31
462.9466553	0.12
466.9111328	0.20
491.3804321	0.29
497.2079468	0.49
498.2713013	0.37
498.9544678	0.67
499.7199707	0.15
513.5474243	0.14
529.3466797	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	967.4561
Annotation	Achyranthoside A
Peak:m/z	Relative Intensity
427.4445801	0.04
615.5274658	0.02
673.5967407	0.01
683.7918701	0.05
691.8378296	0.03
694.6752319	0.02
695.6592407	0.01
723.5194092	0.03
741.5844116	0.15
747.5223999	0.02
759.4718628	0.14
777.5621338	1.96
783.6836548	0.09
789.5986938	0.13
795.4876709	0.63
819.5421753	4.38
837.5471802	10.40
861.5236206	0.02
879.5249023	19.84
923.3145142	7.86
967.3017578	100.00
968.1522827	0.60
968.9249878	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.166
Annotation	Unknow
Peak:m/z	Relative Intensity
121.0728378	0.06
161.0183411	1.76
162.0917816	0.08
174.9043427	0.04
177.1171570	0.13
230.8260803	0.03
241.0865173	0.27
247.4474487	0.02
249.0694885	0.25
250.1258545	0.14
271.2722778	0.10
274.8318481	0.13
279.0654297	0.18
285.1406860	0.10
293.2062988	100.00
295.3002014	0.22
297.0711060	0.07
301.2025757	0.23
303.2122192	0.09
309.1129761	0.11
310.8107910	0.04
318.8950195	0.10
321.2674255	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.13
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
184.5771942	0.37
185.2051239	0.40
195.2499390	0.11
201.1786804	0.73
219.0723572	0.47
227.1432953	0.20
233.2667847	0.21
245.2109222	1.35
252.1802521	0.82
259.0787659	0.27
291.1625366	0.35
294.5795288	0.25
297.8880005	1.12
299.5380249	1.04
317.3051147	0.25
321.2822876	0.19
332.4998779	0.13
347.1596069	0.92
359.0610962	1.00
363.0858154	8.43
381.0945435	100.00
382.2514648	0.59
396.9599609	0.11
411.4138794	0.58
414.3174438	0.47
429.2573853	1.06
445.0825806	0.55
453.2993164	2.05
469.0800171	0.10
483.2164917	0.98
523.2933960	0.28
524.5330200	2.89
525.3449097	2.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.171
Annotation	Arphamenin B
Peak:m/z	Relative Intensity
100.8748016	0.65
111.1487732	0.13
111.8569336	0.08
112.9617233	0.85
119.0475388	0.11
125.0488052	1.18
127.0804596	0.74
129.0369873	0.12
138.2212982	0.14
139.1911316	0.08
141.0133362	0.27
142.1314087	0.09
143.0372620	0.65
151.2522583	0.06
153.2385254	0.51
155.1255493	0.58
157.0327454	0.39
158.8825684	0.10
164.1790161	0.53
169.1730499	0.54
171.1134949	0.43
173.0759277	78.95
185.1138916	0.64
185.9059143	0.04
187.1986694	3.48
189.0767822	0.11
193.3116455	0.08
195.0707397	0.22
197.2035828	0.51
199.1908569	1.62
203.0976562	0.40
207.2374573	0.31
209.2937317	0.16
211.1009827	0.09
213.1216125	0.68
215.0787659	1.83
221.0804138	0.07
227.2225952	0.62
232.9798584	0.11
235.2704773	0.12
239.4154663	0.55
243.2470703	0.26
245.0793762	0.13
245.7391357	0.10
248.2269897	0.16
251.3246460	0.11
253.4192810	0.17
255.2744141	0.16
257.4255981	0.08
259.2587280	0.24
263.2567139	0.10
273.1805725	0.31
277.1472168	0.32
287.2225342	0.51
289.1005249	1.06
290.2301025	0.15
291.2202759	0.07
293.3894653	0.16
299.2509766	2.13
305.0873718	0.73
315.1785278	0.16
317.2183228	100.00
317.8457947	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8862610	6.09
223.0309143	0.15
290.8304443	37.35
327.3443604	0.04
350.2291870	0.04
374.6338501	13.34
375.4224243	0.01
386.2697144	0.03
387.3572388	0.18
396.1181641	0.30
412.2482300	0.09
458.5931396	100.00
459.4241333	0.11
496.9523926	0.02
498.8821411	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	Stevioside
Peak:m/z	Relative Intensity
773.4180298	4.13
803.4032593	100.00
804.0603027	32.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	835.4495
Annotation	Lucyoside M
Peak:m/z	Relative Intensity
551.2377319	0.04
597.4666138	0.02
615.5216675	0.08
633.6333008	0.13
634.4548950	0.09
653.1327515	0.05
653.8008423	0.02
701.7545166	0.02
730.5087280	0.10
731.5405884	0.15
747.4219971	0.07
749.7479858	0.09
758.1869507	0.01
759.6129761	0.13
777.5952759	3.20
788.5160522	0.02
795.0181885	0.70
795.6925659	4.00
818.1210327	0.25
819.0570679	0.23
819.9138794	0.05
837.4636230	100.00
838.1051636	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
108.0237503	1.09
117.5163116	0.10
120.9148636	0.15
123.0807419	1.91
151.9903107	5.65
167.0367126	100.00
172.7726440	0.06
189.0722351	0.12
192.9835663	0.02
207.0478210	0.12
209.1321716	0.55
213.0178223	0.07
223.0684204	0.12
232.5918579	0.17
233.2479858	0.03
239.1431885	0.13
269.0836182	0.21
283.0112915	0.21
284.2619324	0.21
285.3337402	0.34
292.9706726	0.02
309.0812683	0.05
310.9937134	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.4072
Annotation	Beesioside D
Peak:m/z	Relative Intensity
443.2915649	0.21
453.7706299	1.01
471.1427002	0.41
531.2816162	0.12
587.6428833	0.12
615.0676880	0.29
633.4416504	100.00
634.5359497	7.65
635.6924438	0.70
679.7160034	1.96
680.3377075	7.45
681.0162964	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	863.44
Annotation	Unknow
Peak:m/z	Relative Intensity
608.6324463	0.03
718.8513184	0.02
742.2747192	0.01
758.7603149	0.01
800.5913696	0.05
801.3118286	0.04
802.6813965	0.08
815.4368286	0.03
818.3733521	0.07
820.4158325	0.08
821.1843872	0.05
822.0488892	0.02
863.5505371	100.00
864.2714844	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.145
Annotation	2-Phenylaminoadenosine
Peak:m/z	Relative Intensity
106.9544678	0.02
122.9187469	0.01
126.7373123	0.03
132.0571289	0.03
138.9891968	0.01
141.0898132	0.03
142.0173950	0.01
144.3162537	0.04
152.9616394	0.04
155.1003113	0.02
176.9310608	0.01
179.1344757	0.01
179.9728088	0.02
192.0370789	0.01
197.0971222	0.03
204.8813019	0.04
211.2030945	0.01
215.0357056	0.02
221.5081482	0.06
224.9029541	0.03
226.1091309	0.01
226.9263306	0.04
228.0429993	0.04
233.2567749	0.08
235.4210815	0.01
241.8947144	0.01
247.2023926	0.05
255.1101379	0.05
259.2401123	0.02
259.8565063	0.04
273.1284180	0.03
276.3139648	0.03
279.4472961	0.04
281.0151672	0.07
283.1927490	0.09
284.3580322	0.02
286.6703796	0.06
293.1564941	0.01
295.0979309	0.03
296.0951233	0.04
297.2543335	0.02
299.4911499	0.02
300.1076355	0.02
301.0996399	0.02
304.8036499	0.03
308.5350647	0.01
311.3237305	0.02
312.3872070	0.03
313.2752075	0.13
314.9095459	0.05
316.9241943	0.17
317.5716248	0.03
321.0194092	0.01
323.1982422	0.11
324.1713257	0.02
327.1371155	100.00
328.4843140	0.07
331.0797119	0.02
336.6432495	0.08
339.1595459	0.02
340.0753479	0.11
341.2236328	0.29
342.2109680	0.09
343.3879089	0.07
345.1518250	10.06
345.7542114	0.02
349.7185364	0.11
350.8041687	0.01
352.4439697	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
495.4048462	7.15
555.7390747	8.17
565.8080444	3.08
605.649292	11.02
717.4385986	3.21
758.7278442	11.82
759.5704956	4.00
784.4380493	9.20
803.3904419	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	534.2122
Annotation	Neoharringtonine
Peak:m/z	Relative Intensity
152.8276672	0.02
159.9708557	0.43
166.2909241	0.04
167.0670471	0.44
169.8395233	0.06
171.0837402	0.40
176.9545441	0.68
178.9915009	2.07
185.1650391	0.11
190.0391541	0.02
192.1241455	0.25
197.1583557	0.19
210.0825500	1.98
212.9075623	0.28
227.1511993	0.05
228.1834564	0.11
231.1683197	0.03
236.1525116	0.07
242.2013092	0.25
254.1729584	8.15
272.2105713	8.16
274.2484741	0.06
274.8624878	0.03
278.7990417	0.09
280.2624512	0.02
288.1112061	6.51
306.1061401	100.00
315.2758789	0.02
360.0043335	0.06
366.8642578	0.08
385.1296997	0.09
405.1994629	0.80
413.3929443	0.12
420.3919678	0.13
429.0111694	0.04
438.3879395	0.04
442.2601318	0.08
446.5426025	0.14
449.4680176	0.03
472.4332886	4.62
481.6867065	0.05
487.4470215	0.18
488.4248047	0.29
489.6138306	0.02
498.0368042	0.04
506.5201416	0.07
512.2777710	0.50
516.2117310	5.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.9
Annotation	Unknow
Peak:m/z	Relative Intensity
359.3801270	0.20
369.4862671	0.08
401.4694824	0.16
419.6263428	0.21
421.4924927	0.10
429.3638916	0.04
437.2822876	0.04
439.3674316	0.29
447.6732178	0.06
449.6571045	0.33
457.4663696	0.05
467.5361938	0.77
470.7945557	0.05
481.6303711	0.22
485.4091797	0.93
489.7147827	0.12
491.3062134	0.03
493.2919922	0.15
495.2816772	1.24
507.3188477	0.03
508.9967651	0.21
509.6350098	0.45
513.4168091	5.54
523.0866699	0.29
525.5789795	0.12
527.4536133	0.15
537.6922607	0.31
541.1767578	0.80
553.4331055	0.16
555.5103760	44.85
565.7269287	0.04
582.5833130	1.06
583.2470703	5.99
593.5753784	0.03
601.0345459	0.10
655.5796509	0.06
672.5789185	0.10
673.2384033	0.41
698.5862427	0.06
714.3499146	0.21
715.0891113	4.42
759.1338501	3.11
775.7427368	0.13
777.1779175	12.88
777.8505249	0.04
818.8510132	0.03
821.1354980	100.00
821.9213257	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	190.98
Annotation	Unknow
Peak:m/z	Relative Intensity
71.9944611	0.02
82.2231522	0.02
84.1397095	0.02
95.0080566	0.03
99.9877930	0.01
101.2384186	0.01
114.8819580	0.02
116.0588989	0.03
118.9879456	0.01
121.0533295	0.01
132.9099121	0.04
133.7260437	0.01
134.9360504	0.03
141.6278839	0.14
143.1533508	0.01
144.1531830	0.04
144.9308624	0.20
145.8726654	0.02
146.9438019	0.12
148.0053253	0.03
149.8360138	100.00
150.6483765	0.02
151.7280884	0.01
153.8691254	0.01
161.0501556	0.01
162.0768585	0.02
162.9082794	0.06
167.7350769	1.25
169.9669342	0.70
170.6392212	0.26
172.1768951	0.05
172.9444580	0.16
173.8934174	0.02
174.8859253	0.01
178.9080963	0.65
179.7425232	0.08
181.6901398	0.12
182.7149048	0.07
185.2969360	0.05
186.8051300	0.03
190.6223602	0.05
195.8784332	0.01
200.0569611	0.01
203.0693970	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2139
Annotation	Jasminoside I
Peak:m/z	Relative Intensity
148.9494934	0.12
171.0303955	0.03
191.2350464	0.02
202.8307495	0.09
220.3580475	0.08
221.0574951	0.07
237.3405609	0.05
251.1289368	0.10
262.3027039	0.06
274.2639771	0.09
275.1805420	0.05
277.2571716	0.03
285.3677979	0.69
286.1810913	1.05
287.2083435	0.13
290.3499146	0.07
292.2427673	0.07
293.0988464	0.29
299.2960815	0.10
311.0877686	0.14
312.2747498	0.24
313.2456665	0.08
323.1738892	0.06
327.0604553	0.14
329.4418640	0.05
343.2783203	0.04
355.5224304	0.06
360.3214417	0.03
365.1299744	0.03
371.2930298	0.04
383.5446167	0.04
390.4143372	0.12
393.3538818	0.12
398.5066833	0.10
399.4079590	0.12
401.6311951	0.04
403.2175293	0.04
418.6285400	0.05
419.3438416	0.10
429.0801697	0.03
431.4427185	0.20
433.5797119	0.13
445.2839661	100.00
446.1752625	0.04
447.2876587	0.33
448.3528748	0.20
449.4396362	0.12
460.3668518	0.08
463.5974731	0.04
471.3668518	0.31
473.2142639	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
97.59963989	0.26
98.85987854	0.32
112.696106	0.49
119.2083435	0.32
120.1819077	0.16
121.1654358	0.67
130.8859253	0.14
156.1477661	0.24
167.0472412	0.12
169.8675385	3.78
179.3024139	0.16
183.0062714	100.00
183.9605713	9.79
191.2986755	0.44
197.0138092	8.95
198.0429688	5.92
199.1215515	1.03
209.214386	0.16
211.0653076	2.30
212.209198	0.14
213.3147583	0.31
223.2661133	0.27
225.0196228	1.49
226.0545959	0.66
227.0989075	1.28
239.2837524	3.93
240.3074646	0.40
243.2112427	0.87
247.1882324	4.64
248.0064087	0.17
249.144043	1.40
250.9380493	0.77
253.2835083	0.96
254.4509888	0.30
261.1949158	0.14
263.1533203	0.34
265.2788696	2.09
267.300293	2.66
271.3377686	0.15
275.1306458	2.10
281.1057434	0.24
293.2594299	3.20
311.2844543	18.84
312.1682129	2.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0771
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.8876495	2.42
133.2289276	0.06
136.9272308	100.00
137.6738586	0.01
151.0199738	0.17
160.9161682	0.39
167.0890503	0.92
179.1684723	0.09
190.7834930	0.17
211.1470947	0.08
212.1020203	0.05
227.0484619	0.05
234.2315979	0.03
237.1496582	0.19
239.2190857	0.13
253.1141357	0.46
254.2459717	0.13
262.9125366	0.04
272.1796265	0.06
281.1603394	0.58
283.1071777	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	661.2881
Annotation	Briaranolide C
Peak:m/z	Relative Intensity
195.9978485	0.08
222.1150513	0.17
223.0817566	0.49
224.9897156	0.32
237.0808868	1.00
238.1223602	0.08
239.2816772	0.99
251.0453186	0.19
252.2739868	0.09
257.3300781	0.07
279.1648560	1.88
291.2549744	0.28
294.8246155	0.18
297.1204834	1.01
303.2016907	0.12
309.2919922	1.07
310.3026733	0.14
311.2872925	1.48
323.1271973	0.21
325.3908691	0.13
329.2684326	0.17
339.5130615	0.35
341.4592896	0.29
355.2409058	1.63
372.2451172	2.58
373.6366577	0.43
375.2444458	0.90
375.8966675	0.21
376.5355835	0.25
384.4198608	0.18
386.2688599	32.23
387.2949219	0.17
388.1836548	0.63
394.2800903	0.21
397.2579346	0.38
400.3333130	1.56
402.5759888	0.50
410.4198608	0.42
414.2442627	0.67
415.1892090	0.15
416.2020264	0.35
418.2999268	0.19
419.3449097	0.21
428.3959351	32.65
430.4169312	1.60
431.1773682	0.16
432.2739258	18.85
444.3823853	0.96
445.6077881	0.24
446.3897705	3.38
447.2652588	0.12
448.3892822	0.50
457.6313477	0.55
459.4307861	0.97
460.3842773	3.94
462.2220459	0.10
470.5974731	0.29
472.2433472	34.07
473.3369141	3.22
474.4335327	0.97
476.2329712	0.14
481.5999756	0.89
483.2718506	2.52
486.2691040	0.14
491.4503784	2.68
492.3285522	5.33
494.0465088	0.54
496.2854614	0.21
504.2893066	51.44
505.2280273	0.42
506.2791138	0.23
514.3173218	0.17
523.3325806	1.00
524.6287231	0.27
525.3021851	9.94
525.9299927	0.14
528.6192017	0.29
529.3978271	0.19
537.4354858	0.20
541.0979614	0.36
543.3140869	1.19
549.3080444	0.76
551.4947510	0.48
557.2493896	1.63
565.4338989	0.09
567.5028687	9.84
569.4214478	24.02
570.5204468	0.71
571.6533813	0.17
583.2527466	0.07
584.6824951	1.90
585.3408813	3.35
586.8927002	0.11
587.5320435	1.22
588.3162842	0.26
593.4930420	0.77
599.2902832	1.70
601.4007568	70.46
611.3392334	67.23
611.9490967	0.37
616.2067261	0.46
617.5037231	2.44
618.8034058	0.09
624.7811279	0.08
625.4425659	1.68
627.5453491	0.34
629.3684082	100.00
630.0989990	0.16
643.3358154	78.78
661.4476318	6.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	962.5099
Annotation	Unknow
Peak:m/z	Relative Intensity
441.0389404	0.59
962.7272949	100.00
963.4533691	5.60
964.2380981	2.03
964.8610840	2.07
966.5243530	5.69
967.2658081	0.92
968.9783325	0.48
969.6591187	0.67
973.4357300	1.27
974.6123047	0.35
991.4708862	4.36
1010.1916500	0.35
1013.3059080	0.95
1066.7702640	6.56
1143.3872070	8.24
1185.0480960	2.56
1232.4863280	1.92
1296.6350100	0.45
1321.9412840	3.14
1366.6895750	0.61
1369.2553710	0.95
1442.0214840	0.32
1651.8524170	4.09
1652.4903560	0.72
1727.8768310	0.59
1757.5174560	0.96
1763.8529050	0.41
1815.2386470	0.50
1830.6317140	0.95
1832.3641360	1.32
1849.7098390	0.80
1859.3555910	1.13
1882.8892820	0.83
1902.9548340	0.20
1926.1270750	4.37
1943.9498290	22.10
1946.4943850	0.55
1968.6477050	1.34
1975.8903810	16.71
1976.6018070	77.11
1987.3575440	0.38
1999.0650630	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1409.5494
Annotation	Unknow
Peak:m/z	Relative Intensity
526.3334961	0.01
994.2104492	0.01
1007.2529300	0.03
1011.9825440	0.02
1072.6361080	0.03
1111.7150880	0.03
1175.5760500	0.01
1262.3585210	0.02
1263.4593510	0.01
1265.4538570	0.01
1269.1647950	0.04
1279.6638180	0.05
1285.7362060	0.01
1302.6678470	0.01
1319.7418210	0.03
1328.4832760	0.10
1333.6085210	0.07
1334.3039550	0.04
1337.5019530	0.05
1342.7597660	0.14
1343.4206540	0.01
1350.2031250	0.02
1351.5750730	0.41
1353.2187500	0.02
1359.3974610	0.03
1360.3535160	0.02
1378.0708010	0.04
1383.1661380	0.03
1387.2387700	0.02
1392.1589360	0.06
1409.9244380	100.00
1410.9127200	1.54
1412.0753170	0.23
1412.8873290	0.09
1414.7246090	0.08
1415.5950930	0.08
1416.7447510	0.01
1417.9664310	0.07
1423.9534910	0.01
1425.5240480	0.03
1497.8295900	0.01
1577.6191410	0.01
1584.7043460	0.01
1607.3575440	0.02
1660.7916260	0.02
1667.7264400	0.01
1677.8615720	0.01
1686.7198490	0.01
1697.0332030	0.04
1752.4512940	0.03
1759.3299560	0.17
1764.8132320	0.05
1768.3626710	0.02
1771.9412840	0.02
1776.5930180	0.01
1788.8225100	0.01
1790.9046630	0.06
1823.1485600	0.03
1839.9151610	0.01
1878.9631350	0.03
1908.3859860	0.01
1923.9395750	0.45
1933.9254150	0.02
1939.8502200	1.56
1940.7225340	0.02
1951.2434080	0.08
1961.9490970	0.01
1965.0460210	1.99
1973.6419680	0.01
1975.8126220	0.08
1988.2872310	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	817.44
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
292.4749146	0.02
311.3087769	0.07
738.5621948	0.13
770.5747070	0.13
774.7072754	0.07
775.6652222	0.14
798.3938599	0.27
799.6627197	0.14
817.5430298	100.00
818.2935181	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1255
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1668701	0.03
160.0863800	0.07
166.0836639	0.06
176.0167084	0.04
178.9226532	0.10
180.5217285	0.03
181.1279449	1.04
181.9230194	0.64
183.0331421	0.02
185.0724945	0.12
190.8040924	0.05
193.1899719	0.05
197.0824432	0.05
199.0807037	0.62
208.9024353	0.02
210.9703979	0.07
219.4345856	0.16
231.0343475	11.42
235.1318054	0.29
241.7668304	0.09
242.9983673	0.04
246.9769897	0.09
254.8368073	0.06
260.1021118	0.10
262.9968567	1.16
265.0438232	0.18
270.1409302	0.02
271.2281494	0.32
272.1885071	0.13
280.2906494	0.11
283.3217773	0.09
288.4388733	0.35
289.1596680	0.83
290.0980225	0.14
304.2798462	0.06
306.0245972	19.04
306.6371460	0.24
308.2904663	0.06
309.9243164	0.08
316.2528076	0.20
317.0895386	7.13
319.1881104	0.04
322.1101074	0.10
326.3646851	0.08
328.3392334	0.06
332.3541870	0.13
334.0567017	100.00
339.1970825	0.02
341.1359253	0.02
342.5617065	0.07
345.7640381	0.03
347.0475464	0.11
347.9979858	0.15
352.3518677	0.06
357.4186401	0.08
358.3148193	0.03
361.1106567	0.32
362.3170776	0.06
363.3681030	0.03
364.0335083	0.07
371.9596558	0.15
374.0597534	0.04
381.0973511	0.22
385.9955444	0.05
391.1517944	1.06
392.1900635	0.47
400.1273804	0.35
404.9933472	0.31
409.1735840	49.34
416.1466064	0.17
418.2040405	0.07
432.2851562	0.07
436.2513428	0.46
436.9200439	0.11
440.2868652	0.15
443.6301270	0.05
445.1741333	0.51
449.4699097	0.11
458.3692017	0.03
463.1594238	0.40
464.6078491	0.04
465.4708862	0.52
473.6896973	0.81
475.1584473	0.62
476.1589966	0.04
484.0662231	0.02
493.4550781	0.16
500.6085815	0.20
501.9593506	0.25
520.1990356	10.83
521.1211548	0.29
523.6196289	0.19
525.0364380	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	512.2262
Annotation	N-Acetylpuromycin
Peak:m/z	Relative Intensity
166.8401184	0.03
178.9479980	0.09
180.2532043	0.09
207.2098083	0.10
209.2108002	0.04
224.2362061	0.09
226.7470703	0.11
238.2996826	0.12
241.2566376	0.12
253.2958984	0.16
254.2214508	0.19
260.2983398	0.06
269.9987793	0.06
271.9118042	0.08
283.0979004	0.17
288.4564209	0.05
305.5496826	0.21
306.1791382	0.19
310.8896484	0.18
312.5598145	0.04
314.2604980	0.12
327.0406494	0.04
363.0205078	0.17
381.2075195	1.48
384.7268677	0.06
404.4778442	0.07
407.2993164	1.15
415.3254395	0.10
416.5941162	0.18
434.4315796	0.18
436.6077271	0.03
444.0177612	0.04
448.2014771	0.08
449.0563965	0.07
450.2967529	0.14
452.3753662	100.00
453.3234863	0.67
455.2034302	0.03
462.3814697	0.07
466.3817139	4.09
467.3487549	0.40
468.6557007	0.34
474.1242676	0.09
475.5130005	0.02
480.4930420	0.11
485.1127319	0.11
492.4358521	0.16
494.1137085	0.33
495.4566040	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.3096
Annotation	Hyperibone A
Peak:m/z	Relative Intensity
144.9996796	0.50
147.1634827	0.74
151.9333191	1.20
153.0917816	1.45
154.9842224	0.66
156.1812439	0.12
157.0606384	1.42
157.9138489	0.07
159.1009674	2.26
161.0224152	1.12
162.8976135	0.84
165.9007263	0.82
166.9743652	0.83
168.0453491	0.52
169.0395508	1.47
171.1319275	2.18
172.1431274	0.47
173.0603943	2.08
175.1218414	0.45
178.1770172	0.38
178.9793396	0.89
180.0738068	0.21
181.1461792	0.86
183.0671082	1.38
185.1136475	2.47
187.1749725	1.99
189.2361603	1.60
191.0353699	0.94
192.5010834	0.10
193.2237854	0.26
195.1022034	0.64
197.0578918	3.29
199.0116882	3.34
201.0907440	2.32
203.1131287	3.99
205.1084595	0.86
207.1596375	1.34
209.1589813	3.14
210.0987854	0.20
211.0625916	4.28
213.0835571	1.05
214.0576477	0.45
215.1595764	1.46
217.1313782	2.77
217.9142456	0.32
219.0209656	0.95
220.1325989	0.29
221.0379639	1.83
223.1572876	1.47
225.2052917	1.53
227.3794098	1.60
229.2575836	4.20
231.0671082	0.96
233.0076294	0.77
235.2254944	2.50
236.5534515	0.28
237.1793060	3.04
239.1163330	4.09
241.3181000	1.88
243.0279999	1.97
245.1959686	3.86
247.0626831	0.95
249.2630310	3.55
250.4523315	0.29
251.2510986	2.81
253.1266632	2.04
255.2956238	2.81
257.1104126	2.44
258.6655884	1.06
259.4496460	0.27
261.1231384	3.37
263.1546631	2.15
265.3101807	1.21
267.2495117	3.20
268.1301270	1.96
269.1607666	2.80
271.1940918	0.29
272.3030396	0.65
273.0989380	4.63
275.1766357	1.35
277.1719666	5.07
278.7609863	0.74
279.4071655	2.24
280.3128052	0.39
281.1957397	3.85
283.1970825	3.77
285.2415771	18.85
287.1436768	1.87
289.0359497	0.33
291.2100220	2.63
293.2640991	4.10
295.2437134	4.27
297.1878357	0.79
299.2856445	1.41
301.1572876	1.44
303.3412476	4.66
305.0567017	1.74
305.7145386	0.29
307.3385620	2.52
309.1710815	0.90
311.3159180	1.62
313.2014771	4.59
315.3175049	2.13
317.4008179	3.40
319.2359619	3.79
321.2402954	2.86
323.1594238	3.49
325.2321777	1.11
327.1093750	0.92
329.2697144	2.08
330.1057129	0.17
331.5794067	0.85
333.2700195	2.16
335.2763062	2.46
337.1875610	1.40
341.2261963	0.98
343.4461060	1.10
345.2153320	1.53
347.3850098	1.94
349.3916016	22.46
350.4089355	0.59
351.3853149	2.31
352.8532715	0.50
353.5455933	2.23
355.2607422	1.76
357.4973755	0.32
359.2990112	7.32
360.3203125	1.10
361.3814087	0.22
363.2004395	3.80
365.2528687	1.61
367.2826538	2.50
369.1730957	5.46
371.4349976	1.41
373.2838745	4.09
375.3095093	7.30
377.3558350	18.80
378.9445801	4.00
379.6093140	0.15
381.2631226	5.00
383.3786621	3.12
385.5881348	1.20
387.3446655	16.89
389.2963867	1.35
391.3690186	5.24
392.4506226	0.33
393.3481445	1.81
395.3820801	2.11
397.2208252	2.95
399.3239746	1.42
401.3687744	5.17
403.2141724	2.97
403.8526611	0.10
405.2662354	1.51
407.2109985	2.46
407.8766479	0.43
409.2677612	6.10
411.3203125	1.13
413.4964600	1.91
414.3419189	0.13
415.4070435	1.70
416.2234497	0.42
417.4415894	3.52
419.2122192	3.30
421.2874146	4.65
423.2513428	3.35
425.2929077	0.67
427.4544067	6.48
429.4393921	6.60
431.4087524	0.63
433.3142700	1.34
435.4179688	12.35
437.3331299	7.80
439.3458252	3.78
440.1309204	0.44
441.5100708	0.71
445.3652954	15.77
447.3804321	3.01
449.3585815	6.78
451.1618042	0.15
455.4202881	8.17
456.4924927	0.22
457.4892578	18.77
459.3956909	1.13
461.4781494	2.65
463.2078857	43.66
465.4691162	3.81
473.4066772	22.71
475.4508057	11.67
477.3386841	5.29
483.4188843	18.87
487.2666626	1.23
489.4583130	1.70
491.4161987	46.99
501.3415527	100.00
502.0130005	0.41
519.1181641	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	921.4208
Annotation	Microginin 299B
Peak:m/z	Relative Intensity
277.0685425	0.02
304.8266602	0.01
320.2266235	0.03
322.3038330	0.02
331.2431335	0.02
362.6785889	0.02
388.0612793	0.03
445.5087891	0.03
446.4989014	0.02
474.4468384	0.02
477.9334106	0.05
491.3632202	0.02
552.3085327	0.04
562.1926270	0.02
596.2620850	0.04
610.4179688	0.09
620.8659058	0.01
636.8120728	0.09
637.4889526	0.14
652.4345703	0.02
653.5475464	0.08
654.4546509	0.63
655.1587524	0.16
655.7920532	0.08
656.5411987	0.02
657.3243408	0.14
664.8040771	0.03
672.1224365	0.02
673.5703735	0.08
688.3167114	0.04
696.7954102	0.06
697.5742188	0.30
698.5295410	0.08
699.6506958	0.08
704.9572144	0.01
714.2120972	0.11
723.1381226	0.06
723.7459106	0.07
726.0748901	0.05
738.7379761	0.06
741.6217041	0.71
757.7257690	0.04
758.8282471	0.09
760.7369385	0.02
774.4717407	0.19
810.2503662	0.05
812.2902222	0.04
822.2077637	0.01
828.2648315	0.10
830.3084106	0.09
834.2365112	0.01
835.7787476	0.13
841.9135132	0.06
859.4430542	0.36
860.1052856	0.01
860.8162231	0.03
876.4021606	0.07
877.6207886	1.67
886.4432983	0.01
891.5286255	0.06
902.4353638	0.16
903.5671997	0.96
921.5250854	100.00
922.1846924	0.46
922.9504395	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.46
Annotation	Pipalamycin
Peak:m/z	Relative Intensity
585.2684937	0.05
597.5752563	0.03
615.3480835	0.01
616.6107788	0.02
626.1088257	0.03
626.9170532	0.07
632.8766479	0.08
633.5462036	0.14
675.6357422	0.04
699.4811401	0.02
701.6778564	0.04
713.9971313	0.02
728.5856323	0.02
730.5982056	0.10
731.6275635	0.32
741.8992310	0.06
747.4382935	0.12
749.6177979	0.25
758.6256104	0.02
759.7977295	0.10
772.2186279	0.03
777.5117798	5.37
778.2680054	0.03
789.6900024	0.07
791.8486938	0.06
795.5110474	4.25
796.1815796	0.03
818.7871704	0.05
819.6127319	0.08
837.4503784	100.00
838.1057129	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	266.2
Annotation	Unknow
Peak:m/z	Relative Intensity
85.9376678	5.09
115.8705139	0.14
132.0046844	100.00
164.0654144	1.26
167.0690155	0.42
192.0502472	0.58
194.0961456	0.74
206.2118835	1.08
209.3979645	0.19
210.0717621	0.34
225.1141357	0.84
230.3409882	1.16
235.5186920	0.47
248.2569580	2.51
251.2734985	0.54
257.0390930	3.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.09
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
142.9675598	0.06
151.0186768	0.47
154.0970306	0.05
161.0256805	1.47
165.0303040	0.56
167.1080780	0.39
169.0202637	0.23
178.9930115	1.44
183.4806824	0.09
186.9463348	0.09
191.3228760	0.08
193.0689392	0.08
207.0659332	0.20
209.1042480	12.44
211.8782806	0.21
212.6512146	0.07
217.4539490	0.14
225.0382996	0.05
225.8372345	0.40
226.9940796	0.18
229.0188751	0.35
231.0903931	0.29
233.1013641	0.86
235.0266266	0.09
237.9282837	0.05
245.1896667	0.10
253.0632629	1.71
254.0479736	0.20
255.2915344	0.18
257.2381287	0.33
259.7202759	0.10
267.1359253	0.12
271.3093567	0.26
271.9881592	0.39
273.2399902	0.50
275.3437195	0.13
281.0532532	0.06
283.1518250	1.04
284.9062500	0.15
288.7847290	0.45
293.2395325	0.20
295.9740601	0.11
296.8999634	0.36
298.7664185	0.17
300.1290588	31.10
301.1628418	100.00
302.3578186	0.23
305.3954163	0.09
306.9779358	0.17
308.4114075	0.15
311.9798279	0.06
313.1432190	0.30
315.6140137	0.07
317.0109253	0.09
321.0336914	0.08
325.1665649	0.12
331.2940979	6.18
335.3548584	0.13
337.3269043	0.47
341.2249756	0.39
343.1833801	1.88
345.2644043	0.28
347.4626465	0.71
355.3826294	0.21
357.0387878	0.21
363.2094116	0.06
367.2357788	0.12
370.8229980	0.05
373.1459656	0.29
375.2126160	0.18
379.2723389	0.32
382.0424500	0.07
384.0980835	0.23
399.0618591	0.20
401.4757690	0.66
415.4603577	0.51
416.2893982	0.72
417.1775818	1.88
418.4779968	0.55
419.1824951	0.85
420.5503540	0.42
425.4121704	0.43
426.0679932	0.06
433.4513245	0.09
435.3373718	0.18
444.6201477	2.33
445.2615356	8.13
453.4080200	0.11
464.0463562	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.386
Annotation	Stevioside
Peak:m/z	Relative Intensity
325.6329041	1.99
513.3916016	1.73
555.3079224	2.29
564.4190063	2.47
687.2871704	1.41
693.2644043	1.94
758.5806274	34.22
759.5591431	14.36
784.6752319	2.87
803.4030151	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.1074
Annotation	Unknow
Peak:m/z	Relative Intensity
201.0121155	0.13
210.9845428	0.13
221.0527344	0.50
325.8582764	0.23
353.2879028	0.34
381.2276611	0.22
404.6247559	0.24
480.0907593	0.16
491.4937134	0.37
632.3793335	1.07
649.7237549	0.48
652.1877441	2.84
662.9707031	1.69
668.5333862	3.08
669.2957153	1.89
672.0277100	0.85
675.6302490	0.23
676.3090820	0.34
677.9391479	3.79
681.2031860	3.57
683.6044312	0.39
698.3303833	0.30
749.6190186	2.12
751.8953247	0.18
756.4780884	2.11
761.5393677	0.25
769.4631958	0.45
772.6600952	0.19
773.3571167	0.39
776.1732178	0.68
779.5993042	0.83
782.2151489	0.24
784.4046021	1.38
785.0698853	1.56
789.1604614	0.84
794.2295532	4.26
796.1863403	2.63
798.0418701	2.68
801.4063110	2.26
802.0971680	0.68
807.7519531	5.21
809.2637329	2.22
810.7361450	6.84
811.4793701	6.88
812.2368774	7.21
814.0947266	9.88
815.0131836	7.65
815.6546021	0.59
817.6099243	3.34
818.6204834	12.55
819.6390991	0.76
820.6945190	3.50
821.7003174	6.24
822.5231323	5.29
824.6264648	3.45
826.0346069	70.63
826.7161255	34.24
827.7500000	3.19
829.0302734	2.31
830.0090332	0.83
831.3723755	0.97
832.1400757	4.36
832.8822021	1.73
833.9881592	3.13
834.9794312	3.23
835.9039307	2.75
836.6925659	8.63
837.5980225	2.59
838.7356567	13.96
839.5138550	18.86
840.7197266	2.55
842.6188965	17.19
843.4572144	100.00
844.2792358	5.77
845.4751587	4.29
846.7732544	18.87
847.6343384	11.39
848.8232422	0.67
850.5833740	41.75
851.8312988	2.00
852.9612427	0.21
854.9448853	0.14
863.7421875	0.75
878.8085938	0.66
879.9752808	1.02
885.8291016	1.10
915.2072144	0.37
916.7439575	0.91
929.9135742	2.09
935.1705933	1.29
936.3495483	0.75
939.3920898	2.18
940.9550781	2.95
942.0280762	1.20
944.8204956	1.23
955.0717773	1.27
956.5336914	1.09
958.8208008	1.08
963.4131470	3.29
964.9271851	0.52
969.4560547	0.28
973.5166626	3.56
974.8064575	3.25
977.9672852	0.77
982.6560059	0.70
990.7324829	2.61
992.7587280	0.31
996.0554810	5.17
997.0072632	0.55
997.6849976	2.74
999.7207642	0.71
1000.9896850	0.48
1003.0050660	1.65
1004.9572140	0.61
1006.5043950	0.81
1011.0659790	1.37
1011.8151250	0.92
1012.7265620	8.49
1013.4609990	0.28
1014.3933110	2.11
1017.6290890	1.75
1018.5038450	0.89
1020.3132320	5.26
1021.1967770	1.26
1023.7314450	1.19
1025.1718750	1.77
1026.8378910	0.57
1028.7994380	4.58
1029.6079100	4.02
1030.4586180	4.13
1031.3353270	0.34
1032.0712890	0.24
1032.6964110	0.17
1033.3505860	0.67
1034.2863770	0.21
1035.0725100	3.82
1035.9053960	1.30
1036.7030030	0.45
1040.1479490	1.15
1045.0141600	5.96
1045.6237790	2.83
1046.3912350	2.25
1047.9970700	5.15
1051.4616700	0.45
1052.5565190	2.11
1053.2636720	5.24
1053.9177250	0.46
1054.7875980	0.87
1056.8211670	1.09
1057.8353270	5.86
1058.5085450	11.23
1059.4326170	1.02
1060.9648440	0.70
1062.3769530	2.78
1063.3858640	1.49
1064.6467290	0.46
1067.3090820	2.68
1068.1401370	7.31
1068.9426270	1.90
1069.9217530	0.20
1072.1376950	0.49
1072.9332280	3.73
1073.6940920	0.08
1074.3579100	0.94
1077.5686040	6.77
1078.4187010	1.43
1079.8310550	1.71
1081.1855470	3.65
1081.8256840	1.19
1085.5861820	4.33
1086.2502440	4.30
1087.0927730	1.62
1090.5961910	8.72
1091.3029790	13.87
1092.0791020	1.69
1095.6860350	2.62
1099.4082030	1.42
1100.8752440	4.76
1105.2368160	0.98
1108.8449710	1.18
1110.2745360	0.53
1128.7319340	0.55
1133.9753420	1.00
1134.8603520	0.38
1148.3737790	0.45
1189.6345210	0.24
1271.7677000	0.24
1298.4196780	0.37
1302.8004150	0.13
1304.5721440	0.21
1313.7156980	1.41
1319.2774660	1.28
1329.2977290	1.99
1342.6761470	0.55
1359.9315190	0.45
1375.0395510	0.30
1385.9586180	0.27
1402.7310790	0.15
1427.5284420	0.52
1433.6972660	0.70
1436.9069820	2.06
1437.9022220	0.37
1445.1722410	0.83
1451.0152590	0.65
1468.4559330	0.25
1504.3562010	0.37
1523.9807130	0.67
1568.7308350	0.60
1597.8646240	0.52
1640.8988040	0.39
1650.2437740	0.11
1790.8542480	3.55
1792.5876460	3.27
1843.8682860	0.35
1853.6580810	0.88
1862.8908690	0.21
1882.2110600	0.51
1892.6138920	0.54
1893.5213620	7.22
1903.4753420	4.82
1912.6024170	0.56
1939.8739010	0.12
1952.1228030	0.46
1952.8397220	0.28
1972.6989750	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.3298
Annotation	Petrosiacetylene D
Peak:m/z	Relative Intensity
118.9674149	1.40
120.7512970	1.65
123.1521759	0.71
125.1570740	0.23
127.1773529	0.13
128.0061035	0.55
129.0548096	0.36
130.9216614	2.98
132.9609680	3.38
135.0755920	0.95
137.0552826	1.37
140.9756165	0.91
142.0780029	0.51
143.0493774	1.61
144.3978577	0.61
145.0547180	5.66
146.1586761	0.27
146.9876099	4.44
149.1073303	3.45
151.0713348	0.35
155.0390167	1.89
156.9622040	6.33
159.0448914	8.81
161.1103516	5.36
163.1140747	4.25
164.5722351	0.18
165.2626343	0.41
166.0894470	0.12
167.2629700	0.90
167.8799896	0.25
169.1464233	2.44
171.0613403	5.83
173.0591736	7.25
175.0459290	2.97
177.1100769	3.31
179.1061401	0.83
181.0869904	3.00
181.8980713	0.34
183.0980072	11.40
184.0721130	0.47
185.1179657	6.24
187.1428680	5.35
189.1573181	6.46
191.1799164	2.80
192.2677917	0.17
193.0005951	1.66
195.0945892	4.77
196.1668243	0.28
197.0189362	5.02
198.3768311	1.12
199.1782837	8.41
201.1964569	8.95
203.1046143	7.35
205.1054688	5.87
207.2556915	2.84
209.1349487	4.56
211.1817780	8.10
213.1778564	9.94
215.1711121	11.20
217.1777954	6.52
219.0406189	2.85
219.7024536	0.26
221.1193848	1.66
221.9738312	0.24
223.0945740	6.87
225.1618500	6.68
227.2423706	8.04
229.2441101	6.40
231.1014404	1.65
233.1856689	1.34
233.9709167	0.20
235.1928101	2.78
236.2858887	0.80
237.2070312	7.00
238.1927795	0.22
239.2196960	8.95
241.1214600	12.63
243.1998291	8.71
245.0604553	0.83
246.0520630	0.10
247.2340088	3.50
248.0736694	0.06
249.2039185	4.51
251.2700806	6.26
253.1597290	9.51
255.1925049	9.25
257.1788940	4.59
259.1561279	1.17
260.3660889	0.59
261.2085266	1.40
263.2139893	4.83
265.2597351	5.60
267.2731628	14.72
269.2059326	11.14
271.3047180	3.78
273.3208923	0.29
275.1509399	3.04
277.1059875	5.83
277.8779602	1.03
279.2250977	7.26
281.1780396	18.28
281.9284973	0.16
283.3444824	7.24
284.1578979	0.12
285.2031860	0.16
289.2738647	4.80
291.3333740	3.83
293.2560425	8.86
295.2311401	13.50
296.2143555	0.93
297.3656006	7.29
299.3054810	0.58
303.2562561	2.96
305.3511047	3.32
306.2084351	0.16
307.3005981	21.12
308.3019714	0.90
309.3250427	11.92
311.2996826	8.95
312.5934753	0.61
313.4066772	0.86
317.2633057	3.65
318.3505859	0.29
319.3060913	6.10
321.3670044	16.50
323.3516235	3.10
325.2849121	2.47
326.5122681	0.29
329.5112915	0.28
331.2129211	5.56
331.9893494	0.32
332.7707520	0.93
333.4004517	1.93
334.2520142	0.67
335.3264465	16.44
336.6518555	1.46
337.3610840	15.09
339.3842163	0.09
341.3153381	0.26
345.3510132	8.09
346.3841553	0.40
347.3617249	2.19
349.2323608	7.30
350.2285156	1.84
351.4176941	1.87
355.2161865	0.33
355.9291992	0.28
358.8130798	1.41
359.4692383	5.14
361.3119202	8.84
363.2721863	24.45
364.8591919	0.11
369.4220276	0.18
370.3594055	0.08
372.3325195	0.41
373.3337402	1.85
375.3811951	4.85
376.7045288	3.08
377.4001160	8.58
386.4398499	0.48
387.2412415	0.26
389.4083252	3.00
391.3909912	100.00
392.0093079	0.45
401.3447266	84.84
402.1091919	0.36
403.5391846	0.17
404.4044495	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
129.1132507	0.15
136.0819397	0.04
137.9000397	0.15
143.0272827	0.91
147.1005554	0.09
153.0630341	4.66
159.0558167	0.44
160.9582214	5.05
165.0715027	0.06
178.9664307	0.72
187.0906067	0.65
205.0739136	7.53
223.0777893	9.77
233.1477661	0.05
269.3797302	0.08
307.1165771	0.09
321.0739746	0.09
339.3372803	0.07
371.0135193	0.04
385.2234497	100.00
387.3804016	0.08
395.6184387	0.04
411.1340637	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.3962
Annotation	Saundersioside D
Peak:m/z	Relative Intensity
256.2731018	0.57
265.2001343	0.20
421.5216675	0.53
426.4979248	0.08
451.4962158	0.28
481.5585327	0.97
507.4793701	0.19
555.6362915	0.22
565.2575684	0.67
575.8909912	0.10
583.7327881	0.86
585.3140259	0.54
601.4702759	0.83
603.1386108	0.11
603.7450562	0.49
613.4662476	27.55
614.5512085	1.23
625.4237671	0.48
631.5465088	11.18
643.3594971	0.35
645.0321655	0.10
649.4583130	7.51
650.9636230	0.24
661.3255005	1.38
671.0175171	0.44
673.4804688	48.24
674.9055176	0.69
677.5615845	0.77
686.7584839	0.19
691.4395142	100.00
692.4414673	1.97
693.5081177	0.11
708.8786011	0.26
717.6851196	0.77
736.3932495	17.48
737.3427734	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	348.85
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9222870	0.93
146.0653992	0.02
180.9505920	2.93
219.0124817	0.77
246.8021851	0.36
261.9631348	0.05
264.8307190	5.47
286.8602905	1.30
302.8414307	100.00
303.4452820	0.31
330.8671265	13.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	251.14
Annotation	Paucine
Peak:m/z	Relative Intensity
71.8728027	3.29
72.7363892	0.05
88.9643860	12.08
97.0964661	0.03
97.9809418	0.20
100.9316864	0.03
107.0623322	0.03
114.0010071	6.14
114.9745178	2.57
117.0118561	0.64
135.1028442	0.02
137.9698639	2.36
138.8347015	0.09
152.7733002	0.08
162.9856110	7.59
174.9413605	0.40
176.3031158	0.04
179.1638031	0.04
179.9564056	0.03
180.9321442	0.03
182.1941986	0.07
191.0519409	0.22
192.1397400	7.03
193.0242920	0.05
194.9403534	0.17
197.0907898	0.10
205.0198059	1.38
207.1789246	0.33
209.0641479	0.82
209.9634552	0.15
215.1471710	0.19
219.2017975	0.02
223.1837006	0.45
224.8116608	0.05
227.7995758	0.04
231.1271210	0.03
234.0941925	100.00
235.7923126	0.14
242.8775482	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2616
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
190.9882202	0.08
195.0796814	0.32
225.2638245	0.17
243.1484985	0.07
249.1775970	0.09
255.4826965	0.32
259.9771118	0.19
311.4793701	0.12
315.2388611	0.14
337.8372803	0.26
341.2404175	0.03
363.3146362	0.10
380.4514160	0.06
381.4588013	0.23
391.2360840	0.07
400.8262329	0.14
408.1745605	0.12
419.3958130	0.08
439.3104858	0.07
445.4306030	0.11
451.5657349	0.10
453.2979126	0.33
454.9377441	0.05
462.4975586	0.12
463.4082031	0.17
471.4304199	0.31
478.5700684	0.10
481.4063110	0.16
489.6683960	0.10
497.5850830	0.04
505.7844238	0.14
511.0426636	0.37
515.4354858	100.00
517.4946899	0.10
519.7152710	0.41
522.3815918	0.04
523.6720581	0.46
526.6382446	0.20
531.3404541	0.21
532.3091431	0.06
533.6835938	0.57
536.0128174	0.05
537.3434448	1.18
544.6967163	0.15
546.6719971	0.80
547.5402832	1.09
550.1068726	0.09
552.0552368	0.08
553.1167603	0.26
554.5303345	0.33
555.3038940	1.76
559.2689209	28.55
559.9319458	0.20
563.1498413	0.45
571.2468872	0.11
572.8706055	0.41
573.5618896	0.15
591.5256958	0.16
592.2039185	0.14
592.9138184	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3846
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
328.0765076	14.45
355.2582397	5.22
499.536377	5.27
525.1166382	5.87
555.4588013	80.02
621.5840454	11.52
687.546814	7.99
715.3049927	10.05
717.4564819	100.00
759.0464478	24.36
780.6997681	30.87
785.5704956	15.87
803.3817749	93.28
804.3949585	14.84
1371.968994	3.52
1397.579956	16.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.33
Annotation	Petrosiacetylene D
Peak:m/z	Relative Intensity
118.8568420	1.23
120.9489517	1.38
123.0768585	1.03
125.0553894	0.56
127.2777328	0.39
127.9626999	0.61
129.1509094	0.89
130.9688110	2.21
132.9954376	2.61
135.0196991	3.16
137.1317291	1.57
139.1536560	0.24
140.9269104	0.46
142.0278015	0.59
142.9943542	1.36
143.9263306	0.12
144.9960938	5.22
146.9893799	3.50
149.0659637	6.32
151.2722778	0.49
153.0732117	1.26
154.0316315	0.28
154.9467316	2.13
156.0670776	0.21
157.0333557	4.90
159.0769653	6.68
161.0810242	4.20
161.7245331	0.32
163.0532837	6.21
165.1936951	0.64
166.5928040	0.41
167.2924042	0.80
168.0783081	0.51
169.0123444	4.19
170.0274353	1.01
171.0331116	5.96
173.1216125	9.41
175.0292358	4.20
177.1033936	1.70
179.1075134	1.16
181.1109619	1.09
182.0845642	0.22
183.0474548	8.23
185.0892029	5.41
185.7793274	0.04
187.0817871	9.39
189.0973663	4.65
191.1335602	2.67
193.1342773	0.27
194.0502777	0.18
195.0689240	3.32
197.0735779	6.38
199.1042633	10.82
200.1332703	0.11
201.1637268	10.00
203.1466675	12.93
205.1569824	5.15
207.1968536	2.61
208.0476685	0.08
209.1249084	5.66
211.1033783	6.77
213.2536011	6.56
215.1587219	9.75
217.1267395	8.84
219.0463562	1.13
221.0489197	3.98
223.1038513	6.03
225.1625061	6.89
227.1835175	7.44
229.2170563	8.46
231.1490936	4.07
233.1102905	2.65
235.2105408	4.13
236.0673828	0.08
237.2124634	6.08
239.2051086	7.86
241.1667175	20.36
243.1893616	7.84
245.2352600	1.20
246.1712341	0.23
247.1200256	0.95
249.2021484	4.22
251.1909485	7.21
253.2617188	12.12
255.2489319	10.95
256.1839905	0.12
257.2661438	6.16
259.4111023	0.40
261.3168335	1.01
263.1659546	4.62
265.2373047	6.56
267.3145447	15.41
269.2502441	10.99
271.3159180	2.80
273.6286316	0.93
275.1807861	1.44
277.3433228	5.09
279.1896362	5.96
281.1665344	13.09
283.1679688	10.96
285.2147217	1.45
289.2528076	3.72
290.6047363	0.68
291.2572021	6.00
291.8805847	0.18
293.1997070	11.47
293.8393250	0.08
295.2537231	10.44
297.2052917	4.84
299.3914185	0.95
303.2786255	2.16
305.2440186	6.22
306.4414368	1.49
307.2669678	26.52
309.2626343	18.55
311.2878723	7.35
312.3332520	0.11
313.2293091	0.91
317.3629761	3.59
319.3078613	8.06
320.2978516	0.28
321.3696594	7.80
323.3007202	3.86
325.1506042	0.99
327.2793579	0.09
329.2720337	0.09
331.3103943	4.60
333.3410034	3.16
334.3162231	1.02
335.2980347	16.79
337.3208618	12.72
339.3082275	0.67
342.2963867	0.93
343.4670410	0.07
345.3740234	9.91
346.2247009	0.26
347.3148193	2.46
349.3143311	7.16
351.4393921	3.55
355.1315002	0.69
358.3854980	0.70
359.3990479	7.71
361.3622131	6.18
363.3905334	26.37
370.2080078	0.15
372.5572205	0.32
373.4024963	0.87
374.5341797	0.08
375.4668884	4.15
376.3733215	1.75
377.4522095	9.60
378.1978149	0.11
383.9419861	0.42
386.4703369	0.09
389.3706055	3.52
391.3590393	95.68
392.0088501	0.25
399.5360413	0.08
401.3659668	100.00
402.0292664	0.40
404.3457947	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.06
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9115601	2.23
130.8686829	0.01
134.0663757	0.02
141.0472565	0.52
158.9893494	2.85
174.9178162	0.01
177.1027985	1.15
193.2691345	0.10
195.0288849	100.00
196.0895233	0.17
197.2241974	0.04
214.9729919	0.02
231.9861755	0.12
232.9502716	0.32
236.9201355	0.01
239.1616211	0.03
251.1708984	0.04
253.8325806	0.03
279.7750854	0.01
292.9293823	0.04
299.0702515	0.02
312.9677124	0.01
330.9266663	14.43
338.9329224	0.29
341.4327393	0.02
345.0653381	0.51
369.2075806	0.02
393.1376953	0.73
411.1213074	1.12
429.9479065	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	390.1337
Annotation	2-(Glutathion-S-yl)-2-methylbut-3-en-1-ol
Peak:m/z	Relative Intensity
127.8419266	0.14
143.0932312	0.28
159.8669739	0.18
176.9697266	0.72
179.0519409	0.30
210.0662994	0.94
212.7590485	0.34
230.1710205	0.32
231.0536499	0.11
242.1686401	0.13
251.6213684	0.56
254.0843201	5.15
272.1450195	8.36
288.0456238	7.11
289.5111694	0.18
295.3601379	0.05
306.1991272	100.00
313.0336914	0.08
327.9833679	0.13
343.8460999	0.90
345.1927490	0.20
346.3005066	0.23
354.2095032	0.58
372.1369324	2.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.4
Annotation	Vincristine
Peak:m/z	Relative Intensity
717.3334351	2.77
751.6853638	3.35
760.6860962	1.77
762.9003296	1.19
779.3776245	2.49
780.7490845	11.42
794.7617188	3.12
822.1469116	0.80
823.4130249	100.00
824.1270142	3.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	490.1422
Annotation	Unknow
Peak:m/z	Relative Intensity
149.9055481	0.06
210.1925659	0.23
223.0867004	0.29
232.9707336	0.22
241.1636963	0.10
298.3943481	0.22
306.2517090	0.20
309.4754333	0.56
322.9475403	0.09
340.3729858	0.26
355.3541870	0.19
384.4468384	0.17
393.3639221	0.08
397.1769714	0.13
399.9300232	0.06
402.4850769	0.05
407.1798706	0.10
444.2157288	100.00
444.8377380	0.21
460.3063660	0.07
469.1143494	0.21
472.2632751	0.34
473.0910034	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1503
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
116.8128433	0.20
122.9143906	0.07
131.1288300	0.06
148.9072571	0.04
150.9661255	0.06
153.0223694	0.24
157.1015472	0.09
159.1573181	0.05
161.2992859	0.11
164.8416138	0.25
167.0132141	0.11
169.0501099	0.15
171.0946198	0.08
177.1783752	0.58
183.0160217	0.07
187.1873474	0.15
193.5254669	0.14
195.0083008	0.17
199.3066864	0.12
201.1313934	0.29
205.2695618	0.05
207.0465088	0.10
210.8721619	0.49
213.1270142	0.09
215.0576172	0.15
217.1552734	11.78
219.2697449	0.90
224.8633423	0.23
227.3117676	0.13
229.0072632	0.06
231.0345764	0.46
233.1560974	0.17
235.1561584	6.49
237.1381226	0.40
243.3495178	0.10
245.1487732	1.59
249.1996765	0.88
255.1968384	1.30
261.2414551	1.36
263.1733093	0.19
267.6480408	0.06
271.2453613	0.34
273.2553101	7.91
280.8802795	0.21
282.6358643	0.14
283.4010315	0.14
286.9718018	0.15
289.2547607	2.38
291.2572327	16.35
299.2843018	0.23
301.2715759	0.07
305.0016174	0.12
305.6469727	0.11
307.3117371	1.60
309.2210388	100.00
317.0644531	1.03
324.1549377	0.15
335.1487427	2.93
338.2895508	0.05
351.0677185	0.53
353.2092590	48.45
359.4346619	0.27
379.3072205	1.97
382.2035217	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.3677
Annotation	Vincristine
Peak:m/z	Relative Intensity
311.0995483	0.27
463.3989258	0.11
469.8756714	0.09
479.4009399	0.04
506.6079102	0.10
536.4425659	0.94
598.217041	0.49
602.5756226	0.20
693.2560425	0.19
746.5360718	0.29
764.4447021	0.87
804.414978	0.25
823.4278564	100.00
824.0858765	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	989.439
Annotation	Aculeoside A
Peak:m/z	Relative Intensity
425.1567383	0.13
481.6566772	0.11
531.5148926	0.02
543.3658447	0.10
549.5660400	0.10
573.2015381	0.13
575.3702393	0.05
619.8706665	0.10
633.5591431	0.08
657.8217773	0.26
659.6697998	0.22
661.3730469	0.25
675.7578125	0.06
691.7135620	0.05
703.3400269	0.06
739.9133301	0.16
753.8677368	0.08
755.9631348	0.07
761.7454834	0.04
763.6475830	0.13
767.9680786	0.03
769.6955566	0.06
779.5970459	0.29
781.4467773	0.82
783.8294678	0.09
795.8153076	0.07
805.3397217	0.03
806.0544434	0.03
811.4830322	0.03
813.5166016	0.12
823.6025391	44.63
825.7860107	0.08
841.5632324	1.77
853.3889160	0.04
855.5078125	0.13
859.4233398	0.13
860.7218018	0.04
865.5878906	0.05
882.8658447	1.25
883.5333252	1.48
885.2137451	0.05
900.0625000	0.08
901.5214844	1.03
944.8916016	1.56
945.5334473	0.54
989.2282715	100.00
990.3156738	2.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.4588
Annotation	Aquilegioside F
Peak:m/z	Relative Intensity
398.2886963	0.05
439.3643799	0.07
576.8502808	0.04
636.1175537	0.32
654.0836792	0.07
664.4946899	0.29
674.5418091	0.05
678.5845337	0.07
680.7865601	0.11
682.2041626	0.10
698.6849976	0.09
707.1401367	0.44
717.6538086	0.09
724.7022705	0.89
725.8053589	0.29
747.9206543	0.28
754.5158081	0.44
764.6355591	0.15
767.6166992	0.15
778.7901001	0.18
781.1596069	0.45
782.7103882	2.65
792.5387573	0.09
796.4963379	100.00
797.2059937	0.33
798.9432983	0.06
800.0411987	0.29
800.7379150	2.92
810.8030396	0.08
812.7667847	0.05
822.5155640	0.74
823.7820435	0.06
824.5372925	0.10
843.4092407	3.07
844.2333984	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1193
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
149.9620514	0.08
150.9854431	0.47
152.0155487	0.82
153.0195618	4.97
154.0457458	0.47
160.4364929	0.13
163.0789032	0.08
165.0701752	0.07
166.9945984	7.57
168.0389709	0.75
174.9705200	0.06
177.0254364	0.72
178.2498779	0.03
181.0538025	0.52
190.8898010	0.05
191.8318329	0.05
193.2064819	0.12
195.0411987	1.16
199.3003845	0.24
200.2118530	0.04
203.1186218	0.15
206.9928741	0.14
208.9577637	0.06
219.1613770	0.15
220.2704773	0.06
221.2323914	0.22
225.0797424	0.57
229.1509399	0.02
237.0766754	1.47
237.7712402	0.04
239.0389557	0.20
240.3225098	0.16
246.9541931	0.16
269.1005859	0.51
270.3160400	0.21
279.0074768	0.10
281.3309021	0.08
291.4673767	0.05
297.0870667	100.00
298.2146912	15.16
307.1171265	0.21
311.1521606	54.53
312.2071838	10.74
317.3756104	0.12
359.1101685	0.04
379.2294312	0.03
393.0175476	0.04
405.3013306	0.07
420.2502747	0.23
421.3108521	0.13
433.1742859	0.08
435.3126526	0.58
446.8298645	0.20
447.4349365	0.14
450.1744690	0.10
451.4802551	0.15
459.4097595	0.17
461.7496948	0.28
464.3919067	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3847
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
307.6194763	16.61
462.3108521	11.11
742.7160034	12.82
784.836731	6.62
803.3428345	100.00
804.2442017	6.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	236.614
Annotation	Unknow
Peak:m/z	Relative Intensity
71.9519501	4.89
72.8414383	0.15
75.8598480	1.47
83.8880615	1.49
84.7875366	0.28
98.0550384	0.31
115.0358429	0.19
121.9376831	0.20
126.0281525	1.93
129.8750153	33.06
130.9916229	0.82
144.1369171	0.14
147.9745636	100.00
149.0183411	2.67
151.0485687	0.36
152.0818634	0.48
156.1697693	0.28
161.9880524	1.42
163.0034332	0.15
164.0076447	0.11
165.0944977	19.69
166.1121674	3.59
167.0210266	1.38
169.2632294	0.08
172.1542511	0.67
177.0016022	0.70
179.0126495	10.84
180.1599274	0.95
181.1055145	0.51
187.1737213	0.32
189.1556854	0.27
190.0213928	0.68
192.2921295	0.21
194.9986725	0.24
196.6141357	12.81
197.4274292	0.53
198.1998291	1.75
199.0673676	1.81
200.1973267	0.14
201.0593567	0.59
205.0121002	8.17
205.9680023	0.41
207.0069733	0.09
207.9590912	0.28
209.1456757	0.41
213.4115295	1.41
216.0833588	0.39
217.0738373	0.42
218.2107544	0.63
218.9658966	2.55
219.6581726	7.53
220.9323273	0.29
223.0013580	0.44
228.0677490	79.05
228.7058105	3.92
230.9862671	3.40
236.9166412	0.75
245.3788605	0.08
251.0071869	0.12
254.0078278	0.25
255.1338654	4.13
256.1092529	0.55
272.1036987	7.57
272.8729553	0.45
288.8772278	0.36
290.0552368	0.68
291.1325073	1.49
306.0371704	0.38
306.9962463	1.45
308.1521606	83.28
309.1726074	4.28
317.2787170	0.82
326.1247864	1.44
326.9885559	0.28
334.0551758	2.38
343.2377014	24.80
344.1672058	0.89
392.5548401	0.16
397.4100952	2.17
398.3317261	0.29
401.1861877	8.38
402.3360291	0.74
403.3133240	0.94
409.3124695	0.45
438.3669739	0.18
455.1035767	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.3724
Annotation	Unknow
Peak:m/z	Relative Intensity
202.2183075	0.11
243.1873322	0.53
259.0924988	0.89
260.1666260	0.05
261.1808472	0.39
292.2040405	0.07
297.5919800	0.13
301.1929932	0.28
315.2948608	100.00
329.3922729	0.36
332.8536987	0.51
359.3090820	0.87
360.5939941	1.42
361.3505859	1.93
374.5597534	0.10
391.7532349	0.31
392.3533325	0.12
393.1269531	0.12
461.2467651	46.02
475.1943359	0.08
479.5224609	0.08
543.5317993	0.08
560.9669189	0.29
561.5778198	0.37
571.1928711	0.07
576.2820435	0.24
608.2384644	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.07
Annotation	Deethylatrazine
Peak:m/z	Relative Intensity
117.9100342	0.56
142.0298462	0.45
144.0515594	10.58
145.9300995	100.00
160.0427094	0.65
164.9138489	0.06
170.0178528	3.30
187.9560242	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.4304
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
254.3197174	0.21
287.3624878	0.37
303.3026428	0.16
338.9832764	0.12
356.3952026	0.05
441.3880615	0.04
621.0770874	0.07
682.4385986	0.15
701.3685913	0.08
713.1686401	0.15
766.7908936	0.29
771.3497925	0.14
787.6450195	0.22
795.5707397	5.83
812.6276855	0.12
813.4229736	0.27
831.5264282	100.00
832.6380005	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.44
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
964.4411011	17.27
965.3893433	100.00
966.0266113	8.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.07
Annotation	Unknow
Peak:m/z	Relative Intensity
173.1466827	0.35
218.1842651	0.59
237.0595398	1.21
276.3004761	0.25
309.5008545	1.00
349.9738770	2.21
407.6625366	0.35
408.2734375	0.77
452.5975342	0.59
465.3072510	1.14
471.3788452	2.41
487.1461182	5.79
489.0097046	1.20
502.4252319	2.98
511.2913208	4.16
512.6345825	2.99
516.0674438	0.71
519.1511841	5.87
520.5837402	9.16
521.4981079	8.98
523.1102905	0.61
525.8911743	100.00
526.7092896	2.21
527.5024414	1.16
530.3103027	16.86
531.1682739	1.37
532.3054810	4.75
540.9342651	4.14
543.4453735	2.53
544.1659546	4.82
545.2879639	6.77
548.4284058	8.12
550.0000000	11.72
550.9224854	3.18
552.4652710	8.39
567.8281860	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2133
Annotation	7,7-O-Dihydroebuloside
Peak:m/z	Relative Intensity
148.8788757	0.06
153.0684814	0.01
159.1839600	0.03
185.0837860	0.02
191.1383362	0.03
273.3747253	0.09
278.2680969	0.02
281.0245361	0.05
283.2748108	0.03
293.3504639	0.13
297.4068909	0.05
308.9610596	0.01
311.2259521	0.01
312.3447266	0.01
313.3436890	0.48
314.1421509	0.12
315.3900452	0.02
327.9385681	0.03
329.3700562	0.01
330.5397339	0.02
335.3254395	0.03
338.0798340	0.05
360.2191162	0.01
396.0960083	0.09
401.2308655	0.06
405.4584656	0.02
413.4677124	0.03
419.1993713	0.02
420.2008057	0.02
428.8101807	0.01
429.7604675	0.05
431.2990417	0.36
432.3183594	0.11
445.3001099	100.00
446.2435608	16.86
447.1741333	0.02
448.4058228	0.05
449.5359192	0.21
450.3945007	0.05
454.1710510	0.04
455.2693787	0.03
456.0220947	0.05
470.8598328	0.01
473.4085083	0.05
474.5237732	0.01
475.5123901	0.02
493.6243591	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.129
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
82.9716949	0.11
93.0620270	0.01
135.2719879	0.02
139.0890808	0.02
146.8302307	0.04
157.0457764	0.08
162.9557190	0.05
165.1193390	0.29
181.3631287	0.12
183.1468506	1.07
183.8505402	0.05
191.1005096	0.03
197.0249176	0.04
199.1789246	0.39
207.0793152	0.13
209.0957947	100.00
210.8630676	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.4307
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
472.5961914	0.07
752.2339478	0.06
795.5266724	10.76
831.5686646	100.00
832.6814575	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.45
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
652.2987671	15.97
804.9195557	4.58
931.2046509	19.46
966.5728149	26.90
967.4143677	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	Stevioside
Peak:m/z	Relative Intensity
292.177002	0.84
325.5201416	1.22
454.6970215	0.84
472.234314	2.12
510.3950806	0.84
551.6444092	0.71
756.6452026	2.05
757.4453735	7.00
803.4098511	100.00
804.2269897	7.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1044.4429
Annotation	Unknow
Peak:m/z	Relative Intensity
306.0113831	0.11
307.2991638	0.80
332.5317993	0.15
669.4645996	0.34
719.4163818	0.37
822.9150391	0.21
876.0456543	0.16
922.4144287	0.10
940.2624512	0.06
946.7702637	0.13
950.7656250	0.07
969.5804443	0.12
980.1777344	0.15
982.3465576	0.21
983.1166992	0.06
1008.6585690	0.14
1009.6291500	0.20
1025.8887940	0.62
1026.4897460	0.99
1027.6562500	0.26
1044.4394530	100.00
1045.4697270	29.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
213.6135559	0.09
214.9591980	0.13
218.8737488	0.86
259.2760620	0.63
275.2841187	0.13
302.9124146	10.66
303.5192261	0.09
308.9488220	4.49
355.1298218	0.15
373.3786621	0.04
374.3635254	0.19
384.6450806	0.07
386.7929688	34.20
403.2647095	0.05
417.2755127	0.53
422.0307007	0.35
444.8762817	0.18
463.9874268	3.11
464.7818604	1.26
467.6634521	0.19
468.6784058	0.57
470.6798096	100.00
471.4309082	0.14
482.9160156	23.51
484.0282593	0.35
536.2462769	0.05
540.2370605	0.35
541.4853516	0.15
552.1412964	3.52
553.1724854	0.70
553.7972412	1.66
554.4702759	76.75
555.1406860	0.98
592.1261597	0.07
594.2182007	0.28
604.4723511	0.22
620.1397095	0.16
638.5054321	0.79
639.4177246	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.02
Annotation	Unknow
Peak:m/z	Relative Intensity
88.8625336	0.71
95.0290146	0.25
96.8673553	6.91
114.9724960	0.20
131.9900970	8.16
157.6645508	0.14
169.9055023	0.22
175.0126038	100.00
212.8833923	8.37
213.5016479	0.02
214.9865112	0.36
228.9823303	0.07
230.0216675	0.88
237.0750732	0.04
238.2660217	0.12
254.3732910	0.07
255.0564575	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3407
Annotation	Unknow
Peak:m/z	Relative Intensity
148.7163086	0.15
149.4223785	0.08
152.0869446	0.12
153.2414551	0.14
154.8541565	0.25
155.9707031	0.12
157.1163940	0.48
159.0272675	1.27
161.0704651	1.72
162.9780579	0.83
164.9736938	0.16
167.9964600	0.06
168.9622040	1.30
171.0975342	0.74
173.0484314	1.77
174.9612885	0.93
177.0494537	0.56
179.0312653	0.16
181.1567688	0.15
182.0526428	0.53
182.9380646	0.49
185.1059875	1.65
187.2054596	2.01
189.1917114	1.19
191.0532227	1.21
192.9882507	0.24
195.0247345	0.16
197.0831604	1.10
199.2365112	1.16
201.0914459	1.26
203.2166443	2.64
205.0679932	0.93
207.4457397	0.27
209.2276154	0.64
211.0749969	0.88
213.1581268	2.23
215.1473389	1.81
217.1562653	1.82
219.9419556	0.06
220.8753967	0.13
223.2228699	0.34
225.1651001	1.66
227.1885071	2.67
229.3385620	0.39
231.2312317	0.69
233.3362122	0.11
235.3972168	0.11
237.2581482	1.14
239.2998810	2.40
241.2139740	1.79
243.1617737	0.82
245.1394348	1.07
247.0296173	0.09
249.3100281	1.71
251.2229004	0.47
252.1858368	0.13
253.2126465	3.17
255.2798920	0.64
257.2819214	0.95
259.2060547	4.06
261.3452148	0.08
263.3367004	0.07
265.2660522	1.91
267.1834106	1.84
269.2581787	1.09
271.0572205	0.75
273.1787720	0.42
275.2631226	0.17
277.1958008	0.45
279.2109985	2.02
281.1705933	3.86
283.2085571	0.29
285.2634277	0.95
287.1592407	0.85
289.2334595	0.85
291.3207397	1.31
293.3137207	1.28
295.2377319	3.15
297.2748718	1.03
299.3096313	1.17
301.2322998	0.09
303.0428467	0.27
305.2590332	0.50
307.3899536	0.66
309.3444824	1.41
311.2826538	0.68
313.2885132	0.73
315.2151489	0.09
317.1862793	0.96
319.3894653	1.23
321.4040527	2.70
323.1380615	0.13
325.2658691	0.14
327.3489990	1.77
331.3190308	1.21
333.3574219	0.62
335.2789307	2.16
337.3132935	1.04
339.4692993	0.26
341.3695679	1.05
343.1378174	0.82
345.2206421	1.45
347.2576294	0.31
348.4611206	0.08
349.2975464	1.09
351.1363525	0.19
353.3166504	0.54
355.0718994	0.34
356.7039185	0.19
357.3405762	0.71
359.4595337	0.97
361.3186646	1.15
362.1071777	0.29
363.2889404	2.68
367.2880249	0.79
369.3413696	1.20
371.1559448	1.27
373.4796143	0.19
375.2882080	1.57
377.3033447	0.41
379.2079468	0.13
381.4407349	1.49
383.3618774	0.77
385.1441040	1.06
387.4933472	0.28
389.5251465	0.70
391.4681396	42.67
393.1911621	0.18
395.5649414	0.16
397.2092896	0.13
401.3917847	7.99
407.2388306	0.08
409.4600830	0.06
411.4782715	0.36
413.3889771	1.77
415.2585449	0.27
417.5548096	0.05
419.4963989	40.78
423.3792114	0.23
425.3154297	0.44
435.6119995	0.24
437.3209229	32.12
438.0131836	0.16
439.1655884	0.87
441.2927856	0.51
445.2097168	0.13
449.0103760	0.26
451.8814087	0.10
453.2974854	0.28
461.5482178	0.25
465.3818359	0.17
467.1906128	2.07
470.0598755	0.14
479.3450317	4.10
481.0508423	0.65
481.6552124	0.14
495.3070068	100.00
496.1443481	0.37
505.4791870	8.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.5067
Annotation	Namonin E
Peak:m/z	Relative Intensity
795.4891357	0.01
827.8299561	0.03
863.7060547	0.04
866.3614502	0.02
876.0698242	0.02
903.5115967	0.01
909.8035889	0.04
921.6269531	0.02
939.5537109	0.43
957.5743408	0.84
999.6307373	9.30
1043.2805180	100.00
1044.1119380	0.29
1044.8078610	0.45
1045.8449710	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3849
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
283.3103638	24.08
291.6672974	8.19
715.340271	20.11
749.3556519	28.13
758.7450562	26.34
785.5390625	41.88
787.772583	14.98
803.3601685	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.1558
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
112.9837265	0.88
113.9984207	0.05
116.0513611	0.45
117.0266800	0.10
118.0756454	0.05
119.1009674	0.72
124.0495911	0.04
124.9235382	0.13
126.1611328	0.13
128.1205902	0.76
129.0274963	0.50
137.0574036	0.14
142.0495911	0.05
143.0628052	0.71
143.9411621	0.08
146.0714417	69.09
147.0655212	3.83
149.0352783	0.29
151.1182861	0.06
158.9736023	0.10
160.9763489	2.06
161.6458893	0.07
168.2764587	0.15
170.0747375	0.03
171.0502319	0.03
173.0284882	0.72
174.1486511	1.01
175.1100159	0.18
179.1016235	0.13
181.8771362	0.17
188.1222382	0.18
189.0842590	0.03
191.7525024	0.06
200.0635223	4.30
201.1687317	0.75
202.9262390	0.04
216.0942688	0.05
218.1757812	5.95
219.3330688	0.03
242.2250671	0.20
245.0228882	0.09
246.5314636	0.03
248.0457458	0.06
249.4336548	0.10
254.1280212	0.05
260.1828918	0.99
263.0727539	3.23
263.9463196	0.21
265.2308655	0.14
272.0214844	0.23
290.1918335	16.66
291.2848206	1.38
292.2571411	0.08
303.2231140	0.08
308.2643433	63.70
309.2887878	6.52
314.4552307	0.13
315.5308533	0.04
327.2879028	0.06
332.5992432	0.05
335.2139282	0.64
337.0875854	0.07
337.7580566	0.10
344.3298645	0.44
345.2465820	0.07
350.3926697	0.08
353.3535156	0.03
360.4179382	0.19
362.2241516	100.00
363.2720032	13.48
364.0152893	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.2391
Annotation	Ethyl 3-hydroxyoctanoate O-[glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
161.1151276	0.11
178.9880219	0.06
185.1632233	0.09
189.0015106	0.18
203.1126099	0.05
204.9900513	0.06
209.0784302	0.10
227.0196686	0.04
229.0528259	0.23
247.1698914	0.19
269.3461304	0.13
278.4190063	0.10
281.1711426	0.15
283.4043579	0.08
293.0294189	0.21
297.0178833	0.09
306.1813354	0.04
329.2304688	1.90
335.3640137	0.11
343.1005249	0.11
345.4182739	0.06
347.2089233	62.92
348.1015625	0.09
349.3361816	0.40
352.1904907	0.04
353.3211670	0.11
360.2442017	0.09
364.1210938	0.19
365.3382568	0.56
367.1376953	0.14
372.4854126	0.08
394.0056763	0.53
395.2825928	0.04
396.3582153	0.41
397.3251343	0.07
404.1614990	0.09
406.1818237	0.11
415.0585938	0.06
421.2227783	0.15
423.3815918	0.03
437.0753174	0.06
446.3283691	0.10
448.5176392	0.06
450.1661987	0.20
451.5465698	0.43
461.0619507	0.07
465.3618164	1.63
467.1052856	0.19
475.4053955	0.87
482.3799438	0.03
493.3972778	100.00
512.2862549	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	881.96
Annotation	Unknow
Peak:m/z	Relative Intensity
615.4690552	0.16
633.5186768	0.12
635.8130493	0.09
657.3602905	0.06
675.4227905	0.05
676.9125366	0.04
705.0809937	0.08
731.6984253	0.08
741.3048096	0.10
749.5219727	0.10
777.5382080	3.63
791.4765625	0.21
795.5537720	8.42
796.1730347	0.06
809.8388062	0.12
819.4609375	0.14
837.4448853	100.00
838.2633057	0.11
839.2978516	0.16
881.2373657	73.41
882.0197144	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8612671	5.40
223.1348114	0.34
231.9306335	0.50
290.8646851	20.12
307.0769653	0.76
345.4938354	0.35
374.7247925	11.86
375.4325562	0.37
433.9987183	0.46
440.0249023	0.21
442.2741699	0.24
457.0585938	0.17
457.9603882	2.42
458.6828613	63.43
465.3272095	0.68
481.0581055	0.33
505.3081665	0.74
542.6748657	100.00
593.0856323	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.124
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9530640	3.32
87.1460266	0.18
88.9182739	3.24
95.0293961	0.34
100.8745956	4.80
106.6512451	0.45
112.9121780	6.07
114.9661407	0.79
117.0196533	0.26
118.8325500	4.15
124.7223053	0.39
127.3308411	1.82
128.0829468	0.97
129.2363892	0.68
131.0072327	100.00
138.5427551	0.21
143.0883636	1.82
144.8956909	0.98
146.9283142	0.13
148.7729797	0.30
159.0563354	0.18
160.9628601	2.23
173.0804291	6.08
178.8654175	1.39
185.2135925	0.42
191.2008820	0.05
203.1311340	0.53
233.0050049	0.11
239.0080872	0.34
247.1350098	0.09
247.7355957	0.20
256.8940735	0.40
275.0904541	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.4
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
509.1112061	2.93
715.1947632	3.87
820.3060913	1.09
821.397644	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.1565
Annotation	Nikkomycin Lz
Peak:m/z	Relative Intensity
137.8422241	0.04
154.2328186	0.14
160.1099548	0.11
166.8699951	0.10
169.0638885	0.09
178.7003937	0.30
195.0979919	0.06
214.9267731	0.10
221.1400299	0.19
253.4138184	0.37
254.2727661	0.21
256.1087341	0.09
258.2307739	0.17
269.2241821	0.10
270.3943787	0.18
287.3494568	0.04
293.0806885	0.62
298.9841309	0.96
300.2883301	0.64
323.2509766	0.18
345.3064575	0.10
357.6182861	0.06
400.3936462	0.24
405.5600891	0.11
406.2996216	0.05
410.2090759	0.10
412.5200500	0.15
414.0291748	0.12
426.9299316	0.11
432.2412415	100.00
434.1601868	0.35
442.4062195	0.16
447.7373352	0.20
448.5564270	0.37
457.6001282	0.10
459.2447815	0.48
459.9948425	0.60
461.4762573	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	652.25
Annotation	Unknow
Peak:m/z	Relative Intensity
185.1807098	0.05
188.9049225	1.51
196.1381836	0.64
197.1502686	0.05
204.9973450	0.65
206.1939697	0.23
212.0377045	0.11
213.3302917	0.05
215.0279541	1.13
227.9651947	0.12
233.2458496	0.55
244.8869171	0.35
255.3867340	0.14
256.9724731	0.48
265.4963074	0.36
268.1985474	0.15
282.2467041	0.15
287.0637512	0.07
288.0878601	0.50
291.1865234	0.36
296.0906982	0.36
299.1882324	0.52
300.1022949	0.63
301.9319458	0.24
304.7235718	0.42
307.0280151	0.18
308.2366333	0.81
309.5859985	0.30
311.4054565	0.26
312.5518799	0.34
313.2515869	0.39
318.2345581	0.34
319.4705811	0.17
320.9470825	0.06
333.1243286	0.35
336.4547729	0.12
341.3540039	0.51
343.4466553	0.08
346.1702881	0.06
355.3701782	0.06
358.0764771	0.15
362.2333374	0.90
368.2947388	0.50
369.2742920	0.04
372.8782959	0.35
377.4770508	0.06
379.4161987	0.37
381.2625122	2.21
382.1301880	2.50
384.9576416	0.13
386.2918091	0.04
389.7275391	0.34
395.1909180	10.28
395.8745117	5.92
402.8000488	0.21
406.3468628	0.21
407.1008301	0.46
415.3625488	2.34
417.1625977	1.82
423.9830322	5.05
424.8502808	0.36
425.4664307	0.09
432.9148560	20.15
433.8022461	2.66
436.5935059	0.22
442.3361206	0.38
443.3878174	0.44
445.7910767	0.88
446.5548706	1.11
448.2482300	0.14
450.6413574	1.39
451.3519287	0.60
452.5321045	0.38
454.2909546	3.47
455.1918945	0.21
458.3752441	0.26
459.5136108	0.09
460.3316650	0.58
461.2164917	0.41
468.3057251	0.97
471.8777466	0.50
475.2008057	0.06
476.4371948	0.71
478.4987183	1.45
480.0750122	1.06
482.6940308	0.65
483.9184570	0.08
484.6328125	0.09
486.8234253	0.59
487.5169067	0.93
488.8067017	2.94
489.4752808	0.26
492.8480835	0.14
496.1762085	0.38
496.8781738	2.55
497.7766724	12.90
500.4043579	0.05
501.2313232	0.61
503.2230225	0.09
504.4964600	0.98
505.9969482	77.72
506.8994751	10.92
508.3771362	0.20
509.9425049	0.27
511.4718018	0.16
514.1032104	1.04
514.8844604	0.80
518.4990845	2.93
522.0983887	0.32
524.0121460	1.87
524.7213135	0.59
525.9989624	0.20
527.0065918	3.27
527.8980103	0.62
530.4302979	0.41
532.0435791	0.29
532.8558960	6.42
533.6275024	4.40
534.4636841	0.37
535.3591919	0.15
538.9181519	0.39
539.9797974	0.33
545.5668335	0.31
548.1452026	0.95
556.7348633	0.21
561.9545288	7.92
562.7509766	0.63
567.6555786	0.28
569.0316772	0.40
570.5220947	100.00
571.3890991	18.33
572.0128784	0.09
573.2418823	0.48
575.6040649	0.30
577.8889771	0.11
578.8179321	3.91
580.0706177	0.13
585.5109863	0.38
587.0025024	13.94
587.8881836	6.82
588.9462280	0.63
589.5924683	0.29
590.3050537	0.10
591.6354370	0.95
597.5606689	0.22
600.4325562	0.06
601.4162598	0.80
602.9135132	0.23
605.3846436	0.18
606.3073120	0.28
608.0025024	0.33
608.6301270	0.07
610.6302490	0.47
613.9747925	3.63
614.8488159	2.30
615.4809570	2.60
620.7762451	0.29
622.3600464	0.51
623.6936035	0.19
625.3861694	0.80
626.8554077	0.76
631.7116089	0.17
633.2620850	1.01
634.4375610	2.13
635.4483643	0.45
636.1426392	0.50
638.1299438	0.12
640.4923096	0.20
641.4295044	0.07
643.6600342	0.11
653.3946533	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	147.11
Annotation	Lysine
Peak:m/z	Relative Intensity
72.8494263	0.05
76.8937149	0.01
83.8825684	1.97
85.9855347	0.25
100.9323425	0.18
105.8736877	0.09
111.8829651	0.02
114.8872833	0.03
129.0524597	11.26
129.9738922	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.09
Annotation	9-Riburonosylhypoxanthine
Peak:m/z	Relative Intensity
88.0346603	0.27
96.9336395	2.48
101.0427551	0.24
104.9181213	0.11
118.1879578	0.09
124.9443970	6.63
125.8388977	0.05
136.1746826	0.09
140.9759979	0.05
143.1515503	0.42
157.0860138	0.09
160.4484711	0.45
161.3564148	0.08
167.0867767	0.11
168.1157379	0.09
169.8954620	0.07
170.9755249	0.12
173.2230682	0.07
174.7574921	0.04
176.5642090	0.08
182.7185059	0.03
184.4043579	0.08
185.1998291	0.35
193.1831818	0.06
198.8562012	0.34
200.2805176	1.84
200.9295959	3.60
203.0934448	0.21
204.0828552	0.08
205.5515137	0.05
208.8985596	0.07
211.1136475	0.29
212.0638733	0.26
213.9788513	0.09
217.9315491	0.10
218.9799194	0.28
226.9541016	0.15
228.4221497	0.32
229.0339355	7.48
231.0444641	0.30
236.0375061	0.33
237.5263672	0.12
242.7615051	0.04
246.9767456	16.94
247.6596069	0.39
252.1288757	0.23
255.2341309	0.83
255.9103394	0.38
257.1586304	0.31
264.1727295	21.87
264.8676758	19.61
265.5141602	0.09
272.2436523	0.13
273.1403503	0.09
282.0172729	100.00
283.1266479	0.54
291.0568237	1.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	456.2003
Annotation	O-Demethylpuromycin
Peak:m/z	Relative Intensity
167.1080627	0.19
171.0900574	1.83
173.1471710	0.11
209.1099701	7.44
211.3149414	0.04
214.1821747	0.62
227.1430511	3.02
249.0737305	0.11
253.0682983	2.32
254.1046448	0.54
264.1956482	0.26
272.3678894	0.28
294.9037476	0.33
298.0677185	0.05
323.4337769	0.08
325.0426331	0.08
332.1004028	0.07
334.6144104	1.22
338.0989990	0.08
341.0050049	0.35
351.1975403	0.35
360.2323608	0.36
363.0749512	0.10
366.0545959	0.24
369.2951660	0.36
374.0184631	0.13
375.5356445	0.14
384.1816101	0.24
396.2349548	100.00
397.1563416	0.18
402.4886169	0.08
407.6605225	0.18
409.2492676	1.17
410.2454224	8.71
411.3480530	0.49
412.8870850	0.14
420.0991211	1.38
424.3034668	21.39
426.2177429	0.20
436.0402527	0.30
437.2761536	1.47
438.3154907	0.22
439.5627136	0.12
457.2527466	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1977
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9735565	0.13
135.2473297	0.08
136.9457855	0.88
139.2389832	0.03
142.7949219	0.10
146.7946320	0.17
149.0291443	0.03
149.9430084	0.06
151.2331390	0.45
151.9528656	0.03
155.0839539	0.06
156.9795380	0.13
159.0838013	0.29
160.7671967	0.10
163.1380005	0.06
165.1478577	0.04
167.0973511	0.06
172.8084412	0.03
174.2225952	0.09
175.1904144	0.16
178.3574219	0.35
179.1621399	0.79
183.0532990	0.26
183.9646912	0.06
189.0025635	0.92
193.1044312	0.70
196.9280548	0.04
199.2568359	0.32
200.1268311	0.10
201.2249298	0.21
202.1889191	0.29
204.9824524	0.36
207.1210785	0.21
208.2066345	0.24
213.3076782	0.15
215.1112671	0.58
217.1384583	6.67
219.1742096	0.35
220.2550354	0.08
224.1651611	0.03
225.0357513	0.07
233.2694092	0.04
235.1151886	0.73
243.4970398	0.20
261.3252869	1.49
263.0562134	0.59
267.0422668	0.05
271.3164673	0.08
275.2254333	0.10
277.8647156	0.05
279.2439575	0.91
281.8372192	0.08
292.3063354	0.18
297.0786743	0.04
300.9738770	0.11
303.2351990	0.32
309.2431030	0.14
321.2000122	0.21
330.0738831	0.20
330.8374329	0.19
345.0526428	0.03
351.5114441	0.12
368.9706421	0.13
370.9093018	0.11
376.3478699	0.05
379.9151917	0.05
381.1818542	0.17
383.5667419	0.05
385.2459717	0.12
391.0480652	0.04
395.2240295	100.00
395.8363647	0.24
397.3830261	0.39
403.3081970	0.07
405.2453918	0.06
421.3180237	0.23
422.4501343	0.64
423.2928772	0.17
441.2774353	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.465
Annotation	Pipalamycin
Peak:m/z	Relative Intensity
474.3660889	0.05
533.5545044	0.01
587.7229614	0.01
615.2855835	0.03
633.5444946	0.05
653.5197754	0.02
675.4376831	0.01
676.6829224	0.02
713.7484131	0.02
718.8400269	0.01
730.7901001	0.10
731.6869507	0.17
747.6022949	0.04
749.2788086	0.16
758.7079468	0.04
759.8777466	0.01
777.5494995	1.86
792.5078735	0.01
795.5242310	4.64
796.1428833	0.12
818.5402222	0.47
837.5134888	100.00
838.1988525	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0963
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0370026	1.59
136.0810547	0.05
159.1914978	0.04
161.9138489	0.04
163.0232544	4.10
166.8085632	0.10
179.9842987	52.93
180.6105652	0.37
195.0748749	0.34
202.0604401	0.11
203.0258331	0.59
218.0857849	100.00
219.0586853	0.26
219.7496338	0.36
221.0243225	0.16
238.9937439	0.10
245.1525574	0.14
251.4796753	0.03
266.8837585	0.10
278.3457031	0.06
279.1325073	0.04
284.3108215	0.11
291.2253113	0.90
292.9227295	0.04
308.9736633	0.05
315.0975952	0.04
323.2600403	0.11
337.3243408	0.18
338.2304993	0.11
339.1982422	0.08
353.1593018	1.90
354.4210510	0.23
369.2080994	0.24
379.3047791	0.06
380.3201294	0.11
381.2120667	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1017
Annotation	Penicilloic acid
Peak:m/z	Relative Intensity
113.9550476	0.20
114.9412384	0.23
132.0059662	23.92
158.0130005	1.03
171.1061249	0.11
174.9474030	100.00
184.9174805	0.05
200.9446869	0.04
223.0488892	0.22
231.7920227	0.04
233.1672363	0.04
242.2486877	0.08
247.7322083	0.13
261.2004395	0.03
268.7635498	0.14
273.1982117	0.03
290.9903259	2.35
307.9289551	0.18
313.2890930	0.09
332.6625977	0.10
333.3863220	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3846
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
291.1278687	6.80
309.12854	0.90
416.81604	1.75
458.1811523	1.72
555.5231323	0.67
642.8513794	1.61
752.659668	0.48
770.145813	0.33
784.4371948	3.69
802.6951294	3.11
803.3876343	100.00
804.0970459	2.57
847.3821411	2.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7701874	100.00
150.8754883	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3864
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
513.3647461	0.63
555.4631348	1.73
673.3562012	0.46
696.6620483	2.01
715.1445312	1.16
759.2214355	14.26
784.8751831	2.08
803.3816528	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3967
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
259.1181946	1.14
308.551178	1.14
555.2628784	0.48
648.3895264	0.78
717.3900146	3.49
732.9220581	0.52
760.6343384	1.17
777.1891479	5.19
785.5900269	0.71
820.7825928	16.59
821.3939819	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1815
Annotation	Unknow
Peak:m/z	Relative Intensity
198.7855988	0.03
200.8792114	0.03
212.9805908	0.16
259.0472412	0.06
272.3937988	0.06
282.0397339	0.06
284.0816345	0.88
286.1770020	0.02
302.3012085	0.09
315.9283142	0.03
328.2023315	0.07
329.1080322	0.14
330.1172485	2.34
331.9908447	0.08
344.2839966	0.02
347.9077759	0.03
357.4745483	0.05
375.5587158	0.03
377.4476318	0.06
388.2896729	0.11
392.4900513	0.13
417.2171021	0.21
422.2844849	0.02
431.3098755	0.58
432.2620850	0.35
442.4691162	0.08
443.4128418	0.03
459.2656860	1.20
461.1751099	100.00
461.9324341	0.40
462.5786743	0.26
463.3372192	0.09
504.4956055	0.07
518.9852295	0.04
533.4406128	0.29
538.5197144	0.11
544.4099731	0.03
562.7061768	0.07
572.9747314	0.06
592.1089478	0.12
600.3193359	0.09
619.2669067	0.15
646.4049072	0.04
647.2954102	0.15
665.2037354	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.4394
Annotation	Bryostatin 1
Peak:m/z	Relative Intensity
699.953186	6.43
859.2557373	43.34
902.4860229	12.86
903.4358521	100.00
904.1803589	4.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.4546
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
367.8062439	0.05
387.4699707	0.03
424.6208496	0.11
425.2400513	0.08
427.8004150	0.04
428.6863403	0.04
435.4592285	0.03
443.4678955	0.02
453.6084595	0.71
454.8179932	0.03
465.7650757	0.06
467.4902954	0.02
471.3889160	0.15
472.7016602	0.05
505.8309326	0.10
513.5637817	0.03
517.4817505	0.49
526.4743652	0.06
559.6119385	0.03
571.5320435	0.07
587.6177979	0.46
588.4729004	0.01
589.5999756	0.52
590.6181030	0.16
605.5874023	0.03
613.4767456	0.02
615.4885864	1.69
616.5791016	0.16
633.5942993	0.44
634.7308960	0.05
657.7705688	0.05
714.4673462	0.09
742.6656494	0.08
747.4922485	0.28
749.5785522	2.86
750.6793823	0.80
751.5955811	0.96
752.7211304	0.27
767.6654663	2.38
768.5532837	0.61
769.2047119	0.03
775.6541748	0.04
777.5151978	6.52
778.6251831	1.29
796.6170044	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	238.02
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0065308	100.00
191.9529724	0.15
193.9701691	0.26
209.9055023	0.02
210.8184052	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.2415
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
198.8404236	0.04
239.3349304	0.27
256.5902405	0.05
259.0808105	0.29
278.2365112	0.09
283.0299988	0.10
308.3075256	0.21
311.3398438	0.27
317.4535522	0.09
346.9262695	0.04
387.1530151	0.34
392.5824585	0.41
406.6495361	0.33
418.5614624	0.13
420.0492554	0.32
424.4428711	0.12
433.4522095	0.29
447.4312744	0.07
449.4439697	0.06
454.9682007	0.61
461.2888184	0.51
477.6183472	0.08
485.2919312	0.37
486.3816528	0.08
489.1511230	0.18
491.9212646	0.24
500.3273926	0.04
511.1284180	0.22
514.3628540	0.28
515.2647095	0.07
520.4806519	0.30
521.5885620	0.33
529.3860474	100.00
531.2813110	0.06
533.1652222	1.99
533.8721313	0.05
536.9979248	0.10
543.9485474	0.63
548.2620850	0.35
551.6333618	0.50
557.0403442	0.06
558.2523193	0.08
559.4445190	0.11
561.4193115	2.64
563.5649414	0.27
565.3453369	0.19
567.5516357	0.13
568.6629028	0.07
569.5967407	0.38
571.3796997	0.11
572.2081909	0.23
573.2108154	7.12
584.2797241	0.22
585.0895386	0.15
587.3901978	0.97
606.7887573	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3848
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
495.77771	32.64
583.1546021	16.18
584.8384399	100.00
803.3712769	50.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0829
Annotation	N-Malonyltryptophan
Peak:m/z	Relative Intensity
87.8903275	4.38
96.6738586	0.18
109.8883972	0.56
113.8535156	4.36
114.9366913	9.80
128.0449066	0.40
130.0118408	9.03
131.9954529	100.00
155.9928436	9.13
171.0919037	0.25
173.0175171	29.41
174.0138855	79.67
184.0670166	0.10
185.0310059	0.17
204.9852600	0.35
211.1346741	0.21
217.3420715	0.30
227.1645203	2.95
229.1139832	0.42
243.9193115	0.55
245.1007080	42.88
253.2795105	0.45
260.2398071	0.11
271.0447693	21.51
273.2534790	0.64
274.3647156	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.2166
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
119.0516968	0.55
120.9859772	0.21
122.9720612	0.29
124.8813171	0.96
126.8310471	6.55
129.1526947	0.36
131.0177002	0.41
131.9288483	0.19
132.9645081	2.04
135.0465088	0.88
139.0189972	2.54
141.0381622	1.49
141.9208527	0.09
142.9514465	0.12
144.8689117	11.77
146.1468048	0.21
147.0279541	0.52
148.9445496	0.72
149.9337311	1.01
150.9999847	1.41
153.0265656	1.19
155.0396729	0.60
157.0469818	0.61
159.0726318	0.36
162.8052368	14.72
165.0862732	0.05
166.9544678	0.94
169.0675507	1.71
170.9992981	0.46
174.9581299	0.53
175.6806488	0.20
177.3596802	0.07
179.1047058	2.41
180.8308411	1.35
184.0486755	37.78
185.1254272	0.53
187.0345917	1.43
191.2848663	1.26
193.3597717	0.06
195.0769348	0.07
196.9956360	5.12
198.9652863	4.07
203.4049225	0.50
204.4875641	0.07
207.3608246	0.17
209.1638184	4.92
213.1681976	0.27
214.9992676	9.69
215.7266235	0.23
216.9307251	13.50
219.1375885	0.34
220.0947876	0.10
222.9659424	6.32
227.1475067	4.91
229.0275574	0.64
230.0028687	0.04
230.9605713	0.05
231.6153564	0.13
233.0647888	16.75
235.2110291	0.19
239.0039062	0.29
240.9826660	13.86
243.2469177	0.29
244.1731567	0.18
245.1237488	12.02
246.8820496	0.53
249.1061096	0.50
250.1289368	0.61
253.4263916	0.30
255.8523560	0.08
258.9615479	57.45
260.5225220	0.35
262.9672546	61.72
263.5984497	0.28
265.3320618	0.27
267.5231934	0.10
271.3454895	0.30
272.7383423	0.14
275.2681274	0.27
276.9070129	17.64
277.5212402	0.45
279.9810486	4.02
280.5922852	0.04
281.5219421	0.19
283.1219482	0.20
285.0358276	0.09
286.4275513	0.38
292.3633728	0.05
294.9364929	100.00
299.4997253	0.56
300.2138672	0.36
304.2413940	0.14
310.0621948	0.44
312.1413574	0.22
323.1277466	0.58
327.2214355	0.49
328.1038818	0.05
338.4681702	0.50
340.7179565	0.15
341.6742554	0.26
346.7373047	0.11
350.9918823	0.78
354.4370117	0.82
355.2017212	0.36
356.0916443	0.23
356.9765320	0.42
357.6546936	0.28
358.4260864	0.76
359.1276245	1.11
365.7789612	0.08
367.2233887	0.28
369.7505798	0.09
376.7664185	1.38
377.5770264	0.14
378.7726135	0.86
389.7122192	0.59
393.3191223	1.71
394.3478699	14.32
395.1397705	1.58
398.3127136	0.21
400.5868530	1.07
403.0861511	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	175.0248
Annotation	2-Dehydro-D-glucono-1,5-lactone
Peak:m/z	Relative Intensity
57.0475845	0.13
58.9219284	2.71
68.9574432	0.07
70.9494324	6.88
72.9251938	1.85
74.8176956	0.11
82.5743256	0.11
83.1858673	0.05
84.9129181	4.84
86.8174439	1.74
94.8801117	0.20
99.0424957	0.16
100.9061432	2.69
112.9648590	6.36
114.9241943	100.00
126.9995728	2.05
128.7689056	0.85
130.9220428	2.53
131.9929657	0.23
145.0875702	0.33
146.9947815	0.25
157.0669098	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.06
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9581451	1.43
177.1107788	1.12
195.0738525	100.00
197.0887146	0.20
245.2982941	0.24
324.0858765	0.12
340.2356567	0.17
341.3188477	1.53
424.0843506	0.08
439.2169800	10.62
450.3978882	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	820.3641
Annotation	Unknow
Peak:m/z	Relative Intensity
253.9680939	0.10
425.2404175	0.03
634.3053589	0.03
691.4218750	0.88
787.7344360	0.19
802.6708374	0.52
820.5117798	100.00
821.1730957	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0090942	4.04
159.8473969	0.94
160.9849854	1.69
199.0401306	1.18
199.8975525	0.62
200.7756042	0.49
216.7644348	0.18
218.1795349	0.39
219.1389160	0.21
229.0016174	1.30
229.8302155	0.62
230.9340210	0.27
273.0046692	62.25
273.9943542	27.85
274.9635315	40.31
310.1954346	0.10
344.9090576	0.07
376.1284790	0.10
382.8809509	0.15
386.9349670	40.67
387.9773865	49.31
388.9340515	100.00
412.2622986	0.08
414.9606934	0.13
428.9445496	0.40
457.0329285	0.06
458.7152710	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.2681
Annotation	Unknow
Peak:m/z	Relative Intensity
177.1775208	0.23
188.0610657	57.06
189.0083160	3.07
191.9821472	0.07
205.0065002	100.00
206.1139526	9.36
237.0181885	0.18
257.9632263	0.31
259.1784058	0.47
259.9032898	0.11
264.9546509	0.10
266.1267090	2.25
294.8375854	0.91
306.3547363	0.09
307.3764038	0.33
310.2072144	0.30
319.2816772	0.09
331.8845215	0.07
337.1918335	0.51
338.3358154	0.05
359.0538940	0.12
360.4162598	0.29
371.1621704	0.17
372.0031128	0.18
386.6437378	0.30
389.5035400	0.30
395.2632446	0.28
426.6044312	0.39
428.0299683	0.60
434.1626587	0.11
442.7012329	0.35
449.6765747	0.14
463.3610840	0.23
468.5297852	0.12
492.4763794	0.48
494.8576050	0.09
499.3054199	0.58
500.4361572	0.57
502.1948853	0.44
504.0841064	0.40
519.5368652	0.14
545.9365234	0.46
587.3607788	0.37
599.2860718	0.10
601.5327759	0.56
602.8950806	0.20
613.1528931	0.50
614.1976929	0.49
617.5834961	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9543
Annotation	Unknow
Peak:m/z	Relative Intensity
140.9503479	0.03
156.5813141	0.02
163.1484680	0.02
182.9625549	0.08
183.5857544	0.01
195.9510498	0.02
202.8924103	0.01
212.9683075	0.03
223.8377380	0.07
247.3300476	0.04
250.1799622	0.02
257.4004517	0.01
264.4699097	0.02
266.0251160	0.01
267.0701599	0.01
270.2428284	0.04
270.8626709	0.02
283.2119446	0.22
292.8930359	0.02
294.2257996	0.01
296.0895996	0.02
307.2492371	0.11
309.0788879	1.16
310.0910645	0.74
311.0285339	0.26
313.3821411	0.01
323.3010254	0.06
327.0751648	0.23
327.9370422	0.17
329.2817993	0.11
331.3836975	0.03
335.1127930	0.02
337.1517029	0.08
340.1685791	0.04
341.7387695	0.02
343.6226807	0.09
347.4900513	0.03
348.6906433	0.01
349.5005493	0.02
351.0165405	0.01
354.7197571	0.09
356.7710266	0.07
365.2437439	0.04
366.1383362	0.04
367.3790588	0.03
369.2767029	0.03
372.5226135	0.04
376.3826599	0.02
377.1309509	0.18
378.2159119	0.25
379.7307739	0.24
380.9121704	0.19
382.9372559	100.00
387.9496765	0.10
392.5509338	0.02
395.1973877	0.11
396.1358948	0.13
396.7888489	0.18
397.7651672	0.16
399.1123047	0.64
399.8091736	2.59
400.6328125	18.76
403.4398499	0.06
405.4581604	0.15
406.4619446	0.06
408.4778748	0.14
411.6745300	0.07
414.1380920	0.03
415.0088806	0.09
418.2104187	0.04
419.9043884	0.01
423.7496643	0.05
434.1993103	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	193.04
Annotation	D-Tagaturonate
Peak:m/z	Relative Intensity
58.8674316	1.76
70.9331818	0.89
72.9596939	0.06
74.9971466	0.04
84.8643036	0.16
88.8390808	1.64
89.4400940	0.03
100.9901581	0.40
102.8780670	100.00
103.7838745	0.09
112.8902740	0.87
114.9754639	0.05
118.8021240	0.27
120.0630493	0.02
126.8998718	0.02
129.0224915	0.07
130.9624634	0.99
149.0076447	0.15
156.9565887	0.21
158.9275665	0.05
162.9502716	0.02
174.9569092	2.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1766
Annotation	Serruloside
Peak:m/z	Relative Intensity
131.0115662	0.25
136.1651306	0.19
136.8792419	0.43
143.0398712	1.11
144.9828949	0.15
146.9045258	0.49
149.0943146	0.28
149.9599915	0.09
151.0955811	4.15
152.0737305	0.08
152.8188782	0.13
155.4148254	0.07
157.8907471	0.39
158.9452057	0.15
161.0494385	0.94
163.0493164	0.17
164.1799774	0.12
165.1652527	0.05
167.0182037	0.99
171.0598450	0.19
173.0775146	0.17
174.1792908	0.22
175.1813202	0.36
177.0581665	0.32
179.0146027	4.26
180.1679688	0.10
184.0679016	1.70
187.0925598	2.19
187.9723053	0.21
189.0018311	4.05
189.6671295	0.52
190.9523926	0.25
193.1345825	0.41
197.1903992	0.31
199.1285095	1.65
201.0402679	0.40
202.0457916	2.24
203.1931000	0.19
205.0009003	3.42
206.9306335	0.14
208.0959625	0.22
215.0904236	2.62
217.0797424	39.97
219.4270477	0.10
220.0900879	0.17
225.3289795	0.17
231.0347900	0.13
232.9335938	0.06
235.0406952	2.67
241.9818726	0.20
243.1375732	0.68
245.2220764	0.12
245.9219666	0.06
248.4977722	0.15
253.4829712	0.16
261.1591797	4.79
263.1169739	2.13
264.9032898	0.19
275.1494141	0.47
279.1654663	3.21
283.2929688	0.12
289.9300537	0.07
291.3219604	0.15
301.3381958	0.10
303.1434326	0.37
305.0734863	0.17
313.1295776	0.06
317.4704285	0.09
319.2225952	0.14
330.2357788	0.48
345.0545349	1.27
348.3164062	0.54
361.0762939	0.12
367.2220764	0.04
379.3862000	0.35
390.5534668	0.16
395.2633057	100.00
396.9560242	0.06
405.1100159	0.40
406.4054260	0.30
411.1365051	0.15
421.0825500	0.81
422.3513184	2.23
423.1640930	1.81
424.3077087	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0826
Annotation	Ethotoin
Peak:m/z	Relative Intensity
64.9809418	0.04
71.7571793	0.08
73.7846527	1.10
96.9423828	0.07
115.9161682	33.09
116.8451843	0.04
123.1554260	0.15
125.1068878	0.11
128.0400696	0.38
129.0460358	0.27
130.0834808	1.82
132.1572266	0.07
140.8441315	0.16
141.9742126	14.36
142.9341125	0.15
145.9487305	0.19
156.8925171	0.61
159.0277557	100.00
162.1532288	0.04
172.9698944	1.72
176.1294098	0.07
184.9568024	0.76
186.0864105	11.95
188.0330505	0.08
203.0893707	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3851
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
467.6775513	13.06
513.0164795	15.89
555.3238525	12.32
723.4775391	18.30
785.8378296	11.64
803.3563843	93.41
804.7088013	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
538.9750977	35.82
938.0314941	48.27
967.4168091	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.12
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
68.8606720	0.14
71.9260330	2.25
73.8927460	0.09
86.7770233	0.03
87.8686752	0.02
89.8604126	43.44
94.9753723	0.08
97.8133850	0.30
100.0376892	0.07
101.0644226	0.03
101.9448547	0.10
102.9132690	0.08
108.1770325	0.04
108.8511505	0.08
113.0036621	0.25
115.8917542	5.06
119.9997864	0.03
120.9416809	0.13
124.0277252	0.17
130.0694580	0.05
130.9701843	0.19
131.9405823	0.03
134.0284729	0.09
134.9965363	0.03
136.0036011	0.08
140.0338593	0.07
141.7285919	0.06
147.9211121	0.05
151.8516998	0.02
154.3992767	0.22
156.1121826	1.08
157.0376740	0.06
159.9957581	0.19
165.9717255	0.84
171.9560699	0.34
172.8722687	0.02
174.0519562	4.35
176.0409241	0.25
176.9637604	0.04
178.0271149	0.13
179.1078644	0.20
184.0540924	28.98
184.8180847	0.02
189.8207397	0.11
191.9007111	0.36
197.2448730	0.09
199.5786285	0.18
202.0631866	100.00
203.0528717	0.59
204.2170105	0.18
204.8349609	0.27
210.7476654	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0512
Annotation	2-Caffeoylisocitrate
Peak:m/z	Relative Intensity
110.9345093	19.85
113.0462341	0.16
129.0433044	1.55
135.1645966	0.09
155.0020142	8.23
172.9819489	100.00
178.9547424	2.26
184.9762573	0.10
189.1586609	0.07
191.0145874	90.53
206.9927673	0.06
209.1297302	0.14
222.9572754	0.06
260.9593506	0.06
263.4726868	0.09
267.3845520	0.12
271.1262207	0.06
279.1613770	0.06
281.1192627	0.05
291.4118347	0.11
294.3565063	0.23
307.1100464	0.52
309.1950073	0.65
314.8782349	0.04
315.9602661	0.17
321.2804260	0.03
322.1802673	0.10
332.2286682	0.05
332.8923340	0.10
334.8698730	0.27
335.6252441	0.05
338.5051880	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.0915
Annotation	9-Riburonosylhypoxanthine
Peak:m/z	Relative Intensity
86.9157791	0.03
92.9993057	0.08
96.8979187	2.62
105.0022736	0.29
108.8263092	0.02
121.0022202	1.25
124.8987961	7.89
127.7034988	0.02
130.9747925	0.03
133.0666809	0.24
136.0260010	0.23
136.9826050	0.03
138.0608826	0.74
141.2308655	0.16
142.9830017	0.35
153.6127625	0.03
154.9095764	0.11
160.7667847	0.53
162.2312927	0.09
166.0477142	0.10
168.9237366	0.03
172.1216888	0.05
173.2530060	0.16
179.8502350	0.07
181.0720520	0.02
182.6935272	0.09
187.2424774	0.03
189.3959808	0.08
191.0491943	0.04
196.9454346	0.03
198.2084656	0.06
199.2558899	0.30
200.7392578	5.12
203.3096619	0.08
204.0413513	0.41
209.1044617	0.21
210.5494080	0.23
211.6148376	0.13
213.1314087	0.04
214.2061462	0.12
218.9162292	0.15
223.8056641	0.05
225.1245117	0.08
226.1667786	0.03
228.9321594	8.25
230.0801392	0.19
236.1839600	0.15
238.0060120	0.08
239.2218628	0.33
242.3016968	0.02
243.1349182	0.26
246.8749390	20.94
247.5128479	0.05
250.4696960	0.08
251.0720825	0.17
253.0187378	0.16
254.0585022	0.16
254.6643982	0.24
257.1087646	0.42
258.1697083	0.23
258.9882507	0.43
264.1365051	21.46
264.8632812	22.19
267.3627625	0.07
271.6765442	0.24
275.9922180	0.19
276.8806458	0.05
279.8372192	0.05
282.0210571	100.00
283.2072449	2.30
290.8519592	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.07
Annotation	Galactonolactone
Peak:m/z	Relative Intensity
68.7805405	0.64
70.8419189	0.65
73.0034561	0.09
82.7826386	1.49
84.9509049	11.09
86.9105682	14.87
88.9803085	2.29
96.8561401	4.44
98.9764862	6.29
101.1266174	0.15
110.8932343	11.74
112.8383942	0.63
114.8353119	10.06
117.0981140	0.27
117.7587585	0.27
127.0281830	0.19
129.0035706	100.00
130.5903015	0.32
132.9902649	0.25
137.0824127	0.22
140.9805908	8.63
142.8901825	0.66
144.8018646	0.51
145.9864960	0.42
147.1631165	0.22
158.9044952	46.00
162.8128815	2.13
165.0288391	1.13
172.9424896	0.13
176.8502350	1.85
190.9133606	2.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9195
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0281372	4.14
198.9507751	0.58
216.9474182	0.22
228.9335938	1.51
271.0206909	0.40
273.0576782	79.80
385.0502625	1.07
386.9977112	100.00
411.0585632	0.05
427.1047668	0.32
428.1241760	0.13
429.2905579	0.15
444.0485535	0.06
456.2829285	0.04
457.2100525	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
99.0937729	0.23
134.9370422	9.70
141.2848969	0.22
143.2718506	0.04
161.2406921	0.15
176.9378662	0.06
179.0322418	100.00
182.0549927	0.06
196.9839935	0.06
221.1181030	0.13
245.2165527	0.07
247.0236816	0.08
255.9371338	0.07
268.2885132	0.10
278.1529846	0.45
281.2045593	0.37
283.0409546	0.29
288.8442688	0.17
293.1935730	0.09
295.2633362	0.98
296.8898926	1.10
297.4940796	0.28
303.2919922	0.12
305.0738525	0.05
313.2432556	0.34
314.3485107	0.13
321.4398499	0.16
323.0994873	0.52
325.2843933	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3967
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
255.4856567	1.79
734.3720703	5.63
821.4022827	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	649.2847
Annotation	Tasumatrol E
Peak:m/z	Relative Intensity
189.9272614	0.11
191.9811096	0.09
193.9302063	0.06
218.2064819	0.09
235.2304688	0.07
236.1461334	0.22
246.0961914	0.61
247.3822784	0.03
252.9866943	0.05
255.2674713	0.38
257.3216553	0.13
262.1903992	0.24
269.1337280	0.02
271.5589905	0.09
280.1771851	0.07
281.2238770	0.14
283.2719727	1.39
285.0681458	0.14
287.2137146	1.57
293.3482056	0.06
295.1818237	0.09
296.2037964	0.05
299.1566162	8.58
303.1959839	0.09
304.2130737	0.10
305.2680664	0.22
311.2614136	0.94
312.0106812	0.03
313.1666260	0.94
320.1466064	0.16
323.1391602	0.77
325.1782227	0.11
327.4890137	0.07
331.1310425	0.12
337.1923218	1.06
338.7583008	0.29
339.4036255	0.25
341.1528320	0.23
343.4417114	0.06
351.1043701	0.02
355.1489258	0.12
357.0163574	0.13
365.2714233	0.09
373.1319580	0.11
375.3153076	0.31
383.1892090	0.92
401.1931152	4.89
408.2497559	0.02
419.1282959	0.95
420.7052612	0.18
422.3080444	0.02
425.2814941	0.02
432.4367065	0.92
433.2518921	0.06
434.3488770	0.42
436.3402710	0.21
438.3009644	0.64
446.2911377	0.28
448.2413330	40.33
448.8470459	0.42
450.2023315	1.63
456.2720337	0.89
458.2432251	0.19
460.5854492	0.11
462.4830933	0.05
464.4135742	0.04
466.2598877	1.08
468.2152100	1.63
474.2791138	6.85
476.3204956	0.90
478.5617065	0.04
482.0897827	0.64
492.0704956	12.58
492.6773071	0.12
494.2223511	1.10
496.1936646	0.20
500.2246704	0.36
503.2906494	0.11
510.4158936	0.04
512.3345337	0.44
526.8627319	0.06
527.4920654	0.05
543.7933350	0.08
545.3165894	1.55
551.7231445	0.04
559.3527222	0.29
567.6014404	0.02
568.7427979	1.53
569.3516235	17.09
571.2816772	0.90
585.5570068	0.36
587.2261353	9.65
587.8596191	0.05
588.5621338	0.29
589.3385620	0.99
594.9046021	0.63
595.5073853	2.23
603.1329956	0.12
605.2553101	34.05
605.9318848	0.14
613.3167725	14.29
614.6303711	0.07
631.3025513	100.00
632.1818237	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.1175
Annotation	Unknow
Peak:m/z	Relative Intensity
107.0051041	0.09
109.9418793	0.03
118.1351624	0.06
118.9176025	0.69
125.0292969	0.04
127.0894852	0.11
131.0596619	0.50
139.1864014	0.13
146.9253845	6.68
147.6036987	0.06
149.1255188	0.11
150.0539551	0.20
150.8765411	0.03
152.9807434	0.12
154.0869751	0.03
155.0759888	0.29
156.9801636	0.06
160.9340820	0.12
165.3294067	0.12
167.1091309	0.14
171.0457153	4.96
173.0769958	2.78
177.0438080	0.02
180.9075012	0.05
183.0806580	0.02
183.8699493	0.13
195.9328308	0.12
199.0703278	14.91
205.1681671	0.18
207.0522003	0.08
209.9697113	0.05
212.1109924	0.06
217.0355835	100.00
219.9590149	0.08
220.8759460	0.11
222.8890686	0.42
224.2225342	0.11
228.8165894	0.03
231.0578613	0.08
241.8325500	0.04
243.2261658	0.23
245.2432556	0.04
246.9047241	0.02
255.0691833	0.03
256.2651672	0.02
260.1764832	0.10
264.0838318	0.12
264.9200134	0.04
271.3062744	0.04
275.3635864	0.02
277.1730957	2.06
282.4985657	0.04
286.4457703	0.05
289.2875977	0.14
291.6694946	0.23
294.0916443	0.04
295.9719238	0.12
297.6481323	0.17
299.2638550	0.27
300.0665283	0.03
303.5514526	0.09
306.2574463	0.02
308.3286743	0.06
313.0311584	0.10
314.1963501	0.24
315.2688293	0.08
316.9932861	0.40
317.6235962	0.08
318.3268738	0.18
319.1473694	0.45
321.9895935	0.35
323.4244995	0.22
325.2169189	0.37
326.4557800	0.05
327.0950928	0.04
331.3222961	0.17
335.3934631	0.08
339.2688293	0.09
344.6242065	0.98
345.3216248	1.90
346.1938477	0.09
353.1020203	0.27
354.0038147	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.2632
Annotation	Mutangin
Peak:m/z	Relative Intensity
220.0615387	0.06
235.0422974	0.33
236.1885986	0.08
253.3701935	0.42
265.1248169	0.09
269.3937073	0.12
281.2143555	0.51
295.1132812	0.06
297.0645142	0.27
299.1379395	0.17
307.1316528	0.13
309.6112061	0.16
313.0358276	0.10
319.2771606	0.19
332.9989014	0.16
339.4466553	0.04
341.2836914	0.10
342.3427124	0.16
347.0765381	0.06
348.3575439	0.10
349.1525269	0.17
353.2334595	0.25
355.3549194	0.44
357.2413940	0.38
367.3247681	0.25
375.3907471	0.24
381.3649292	0.13
390.3454590	0.25
399.2670898	0.36
404.6348267	0.45
410.4641113	0.12
415.7083740	0.09
417.0347900	0.12
419.1580200	0.07
420.2278442	0.10
422.1884155	0.26
431.0108032	0.20
436.4262695	0.16
447.5278320	0.13
457.3526001	0.27
457.9846802	0.08
460.3945923	0.16
462.7518311	0.16
469.3671265	0.23
479.6435547	0.54
481.3690796	0.22
487.6643677	0.31
489.3341064	0.49
490.4764404	0.09
491.4900513	0.26
503.4743042	1.02
506.3496704	0.15
511.6524048	0.16
517.5941772	0.79
519.6867065	0.33
521.6226196	0.96
525.4326782	0.38
529.5925903	0.18
531.3947144	0.26
533.4950562	2.72
534.5350952	0.32
536.4559937	0.10
545.4865112	2.18
549.4191895	0.57
550.2352905	1.20
551.7081299	0.05
561.2876587	0.20
563.2846069	0.07
569.4170532	0.14
573.2212524	0.12
576.2699585	1.18
577.4112549	100.00
578.4843140	6.64
579.5971069	0.36
580.6950684	0.52
581.4205933	0.74
583.3073730	0.17
587.4760132	0.13
589.1374512	0.24
592.3871460	0.35
593.5094604	8.37
594.3831787	0.35
595.1212769	0.21
601.9906006	0.57
604.5134888	0.48
605.3951416	8.47
606.3650513	0.43
609.4107056	2.84
610.2777100	0.33
618.6366577	1.08
619.4516602	4.91
629.3171997	0.06
638.4437866	10.50
639.1671143	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	940.0309
Annotation	Unknow
Peak:m/z	Relative Intensity
260.9544067	0.32
269.9291077	0.15
287.1267395	0.16
288.1661072	0.52
299.4971008	0.28
316.1424866	0.14
317.9984131	0.47
327.0279541	0.09
328.0524902	0.14
348.1629333	0.10
350.2578125	0.13
350.8842773	0.24
354.5884094	0.15
358.6454468	0.23
366.3848877	0.24
368.2670593	0.23
377.2781982	0.12
387.2186890	0.06
405.1571045	1.26
416.1411743	0.10
419.6437988	0.16
428.1851807	0.13
430.7169189	0.15
432.0923462	0.08
436.8970947	0.16
437.5030518	0.16
439.9805298	0.09
446.2316284	0.25
447.3830566	0.15
448.2603760	0.36
450.3447876	0.07
457.3906250	0.09
462.5175781	0.26
467.2127075	0.17
474.1054688	0.96
475.0883179	0.10
475.9759521	0.54
476.6222534	1.00
477.4906006	0.53
485.7869263	0.30
494.6238403	0.28
506.2029419	0.11
514.0572510	0.08
515.4617310	0.06
516.3723755	0.23
531.3973389	0.18
533.4148560	0.33
534.8135376	0.19
544.3959351	0.28
564.1564941	0.50
565.1276855	0.24
575.5321655	0.63
586.2232056	0.18
588.3516235	0.27
605.4816284	0.19
614.3731079	1.37
615.4655151	0.06
618.1371460	0.16
618.8066406	0.11
629.3255005	0.35
632.3132935	1.85
633.6611938	0.22
634.5171509	0.19
635.5401001	0.18
637.4083862	0.19
638.5538940	0.17
646.9760132	0.08
651.3732300	0.54
668.1748657	0.24
688.2072754	0.12
688.8757324	0.22
699.2731934	0.47
712.4556274	0.45
713.3890991	0.10
723.4868774	0.08
725.6057739	0.59
731.5614624	0.12
743.7198486	0.29
750.0563965	0.06
756.0861206	0.55
766.4645386	0.52
773.6484985	0.53
774.7925415	0.55
780.5175171	0.10
784.2174072	0.47
795.8562012	0.45
801.2075806	0.11
805.5977173	0.10
810.4627075	0.21
816.4174194	1.19
818.6605835	1.04
820.1572266	0.53
821.1918335	0.22
827.5928955	0.60
828.3186646	0.54
830.8214111	0.06
831.4303589	0.97
833.9437866	0.68
836.9030151	2.60
839.3109741	0.75
840.7535400	0.66
842.9633179	0.70
843.7509155	0.38
845.3307495	0.90
846.1054077	0.50
848.0346069	0.09
848.8871460	0.54
850.5411377	0.69
852.4102173	1.92
853.2924194	2.45
854.3627930	2.17
855.1554565	0.38
857.2190552	0.55
858.0505981	0.90
858.9615479	2.46
860.2814941	0.47
861.2669067	0.69
862.1400146	2.00
862.9648438	0.23
863.8082886	0.95
864.8270874	1.79
865.9666138	1.24
866.6894531	0.27
867.7749634	1.41
868.9016113	2.59
869.6909790	0.83
870.8944702	1.92
871.7653198	0.62
872.6558228	1.12
873.3751831	0.23
874.8399048	0.21
876.1608276	1.66
876.8991699	2.95
878.1755981	0.93
878.9176636	4.95
879.7826538	0.08
880.4571533	0.19
881.4110718	1.84
882.3427124	1.20
883.3125000	0.77
884.0392456	4.29
885.5110474	3.51
886.3280640	1.77
887.2500000	2.70
888.4368286	3.47
889.2847290	1.74
889.9957886	1.73
891.8832397	5.19
892.7134399	8.89
893.6647949	3.70
895.8305664	14.65
896.7915039	1.99
898.4052734	7.20
899.5764771	0.26
901.4966431	15.80
902.1321411	18.66
903.0982056	5.17
903.9447021	0.37
904.9771118	2.70
907.7548218	26.49
908.6911621	1.00
909.4849243	0.56
910.5786743	2.12
911.3410034	4.14
912.9504395	3.04
913.8995972	1.41
914.5817261	0.26
916.0189209	1.79
916.7117310	5.06
917.3582153	6.84
918.3818970	0.73
919.5919189	15.13
920.5482788	3.07
921.5240479	0.69
922.5889282	2.48
924.7402954	1.54
925.6469727	10.88
926.6890259	0.47
929.7562866	0.46
941.5430298	4.62
945.7089844	0.22
951.8367310	0.06
959.3681030	0.30
961.3225098	0.65
964.3591309	0.07
977.2282715	0.11
979.7776489	0.32
980.6387329	0.57
990.1789551	0.97
990.8993530	0.28
992.4998169	1.15
993.5529175	0.16
994.3300171	0.35
995.6034546	0.18
996.9321899	1.60
1001.6574710	0.50
1002.9002080	0.31
1004.0207520	0.21
1004.6872560	0.67
1010.0505980	0.70
1011.0358280	0.50
1012.0983890	0.17
1015.3735960	0.06
1018.3996580	0.31
1020.0805660	0.88
1021.7783200	0.67
1025.7485350	0.65
1026.5876460	0.33
1028.6420900	0.96
1030.7188720	0.90
1031.3444820	0.16
1035.5820310	0.74
1036.7192380	0.75
1038.8769530	1.02
1040.3066410	0.11
1043.5300290	0.59
1044.5544430	0.59
1047.5964360	0.45
1048.6462400	0.19
1052.1431880	0.29
1057.7983400	1.36
1062.2701420	0.16
1064.0021970	0.79
1065.0034180	0.64
1067.4519040	0.20
1068.2967530	1.19
1068.9163820	0.72
1069.9536130	0.48
1070.7409670	0.09
1072.2463380	0.85
1076.9094240	0.66
1077.7744140	1.34
1080.1925050	2.40
1081.2916260	2.70
1082.7761230	0.93
1083.9677730	0.69
1085.4450680	1.84
1086.5025630	1.80
1088.1429440	0.20
1091.1567380	1.25
1091.9130860	0.79
1094.5933840	3.66
1095.2880860	0.48
1096.0284420	0.36
1099.6202390	1.46
1100.3599850	0.25
1101.1673580	0.73
1102.4221190	0.43
1104.0571290	0.09
1104.7949220	0.45
1106.5383300	0.42
1107.6430660	0.65
1108.5704350	0.25
1113.1618650	1.05
1113.9644780	0.37
1114.6086430	0.24
1116.0173340	1.14
1117.2185060	0.36
1119.6728520	0.53
1120.4863280	0.89
1122.8385010	0.82
1123.7949220	0.56
1128.6009520	0.59
1129.6492920	2.31
1131.2258300	0.76
1132.6091310	0.05
1134.0687260	1.69
1135.0372310	0.56
1135.8535160	0.50
1137.6755370	1.60
1138.6043700	0.75
1139.4573970	1.11
1140.3847660	1.45
1141.6987300	0.74
1144.1235350	0.36
1144.7668460	0.49
1145.9494630	0.09
1148.0637210	0.47
1149.1298830	0.64
1150.4106450	1.20
1151.2694090	1.24
1152.3625490	1.07
1153.0887450	1.20
1153.8337400	0.28
1155.2370610	0.88
1157.0229490	1.44
1158.3464360	5.87
1159.0831300	1.37
1159.6870120	1.24
1162.4646000	1.32
1163.8720700	0.96
1164.7712400	3.31
1165.7188720	0.51
1166.8957520	0.73
1169.3269040	0.73
1170.6757810	1.51
1172.1926270	1.53
1172.8409420	5.37
1173.7768550	7.91
1174.6418460	3.89
1175.4771730	0.72
1176.8408200	2.08
1178.8093260	0.77
1179.8939210	0.20
1182.1175540	1.58
1182.9702150	0.48
1184.9986570	0.13
1185.9300540	3.88
1187.3673100	2.02
1188.5588380	0.25
1189.9012450	1.29
1190.8267820	1.30
1193.5076900	1.19
1194.4481200	2.98
1195.2249760	0.91
1196.0816650	1.01
1196.7517090	0.32
1198.5253910	2.90
1199.4104000	1.91
1200.4084470	3.14
1201.2097170	0.41
1202.3372800	1.23
1203.6121830	1.24
1204.2805180	0.44
1205.4948730	0.65
1207.4492190	2.42
1208.3558350	9.47
1209.2438960	1.12
1210.3441160	1.17
1212.8156740	1.23
1214.0317380	0.61
1216.6685790	1.75
1217.9942630	0.74
1220.5271000	0.24
1221.6196290	1.50
1222.5263670	1.13
1223.3748780	2.59
1224.1865230	0.99
1225.5017090	2.34
1226.4616700	1.65
1227.6059570	0.24
1228.8864750	3.49
1229.7065430	1.08
1230.6291500	0.88
1231.7918700	1.37
1233.1948240	0.78
1234.4479980	2.89
1235.9626460	0.22
1236.6491700	0.06
1237.2563480	0.56
1238.2229000	5.20
1239.0977780	1.08
1239.7836910	0.57
1241.0278320	0.95
1242.6499020	5.17
1243.8643800	2.20
1245.2543950	2.90
1246.9582520	4.62
1247.6677250	7.03
1248.6214600	2.18
1249.6230470	0.87
1250.2451170	0.44
1251.2930910	2.64
1252.2246090	5.95
1253.2084960	2.39
1254.1193850	1.09
1257.4543460	3.87
1258.2561040	2.33
1259.5493160	0.56
1260.7540280	0.47
1261.5129390	0.14
1264.2818600	1.53
1265.3540040	1.60
1266.4359130	1.09
1267.6834720	1.52
1268.5333250	0.81
1269.3991700	0.79
1270.3341060	1.74
1271.3125000	2.65
1272.2614750	2.71
1273.0465090	0.28
1274.4095460	0.30
1275.4344480	0.17
1276.3731690	0.78
1277.1231690	0.19
1278.1488040	6.08
1278.9547120	5.22
1279.7690430	1.60
1280.6811520	1.44
1281.7047120	1.07
1282.3753660	0.45
1283.4200440	1.34
1287.1817630	11.95
1288.3409420	4.44
1289.3829350	1.17
1291.1390380	0.19
1292.0064700	1.27
1292.9796140	2.41
1293.7918700	2.09
1294.5247800	0.14
1295.5906980	6.18
1296.8406980	9.55
1297.7369380	1.85
1298.3443600	0.41
1300.2603760	1.30
1301.4390870	3.70
1302.4525150	9.97
1303.6190190	2.98
1304.7684330	4.43
1306.4495850	1.12
1307.8331300	0.73
1309.1561280	0.36
1311.1373290	1.92
1312.2701420	1.28
1314.4782710	1.12
1315.5744630	0.71
1316.6358640	3.85
1317.9062500	2.88
1319.2264400	2.16
1320.6866460	1.68
1321.4746090	0.53
1322.6043700	1.25
1323.5544430	1.47
1325.2877200	9.34
1326.1239010	2.44
1327.7229000	5.30
1328.5443120	3.20
1329.4176030	4.35
1330.0727540	1.77
1331.3548580	3.61
1332.2476810	3.58
1332.9296880	1.58
1333.8082280	1.39
1334.5072020	2.33
1335.3778080	1.03
1336.5679930	11.55
1337.2447510	4.86
1337.9031980	4.14
1338.7943120	1.06
1342.4769290	2.58
1343.1855470	8.14
1344.1270750	3.82
1344.9312740	4.27
1345.8035890	2.13
1346.7501220	1.78
1348.1621090	1.13
1350.5289310	0.74
1351.9370120	38.72
1352.7318120	9.54
1353.9283450	18.97
1354.8614500	3.22
1355.5169680	0.26
1356.7164310	0.99
1359.3309330	0.29
1360.8509520	100.00
1361.6723630	18.09
1362.3723140	1.07
1364.7188720	0.23
1365.8270260	3.62
1367.1263430	0.70
1370.3714600	0.09
1371.6771240	0.16
1374.9300540	7.38
1375.5405270	1.12
1376.8382570	0.51
1389.1436770	0.38
1412.6407470	0.14
1413.2542720	0.23
1427.8151860	0.25
1439.9398190	0.06
1444.6871340	0.33
1458.2918700	0.11
1468.8280030	0.30
1494.9188230	0.07
1523.8049320	0.29
1541.0983890	0.06
1586.1600340	0.17
1610.5313720	0.48
1633.6384280	0.27
1648.8626710	0.27
1661.8194580	0.18
1664.0515140	0.50
1677.2525630	0.10
1685.3039550	0.56
1688.0217290	0.08
1708.7932130	0.40
1731.6314700	0.23
1733.6300050	0.42
1765.3704830	0.16
1769.9198000	0.29
1773.8347170	0.27
1789.9768070	0.27
1795.0391850	0.14
1800.0373540	0.27
1806.0213620	0.33
1809.1356200	0.19
1816.5490720	0.15
1817.8692630	0.38
1840.5896000	0.68
1859.9045410	0.52
1864.0096440	0.14
1878.8726810	0.16
1882.7624510	0.21
1883.8131100	0.34
1884.4454350	0.20
1906.0125730	0.29
1908.4654540	0.07
1913.3209230	0.41
1923.2053220	0.91
1932.0373540	0.10
1934.4136960	0.51
1936.2955320	0.25
1940.3111570	0.11
1945.1770020	0.16
1949.1539310	0.29
1951.9337160	0.21
1962.6304930	0.25
1968.6009520	0.14
1980.2093510	0.38
1984.3884280	0.69
1986.7154540	0.07
1989.8138430	0.39
1991.5773930	4.83
1997.7481690	1.26
1999.7174070	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	312.1644
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
96.8631668	0.25
100.9522247	0.09
103.8844299	0.08
108.9455795	0.15
116.9021988	0.10
126.8592377	0.44
132.4267883	1.65
133.1051941	2.08
139.2419739	0.30
140.7446289	0.07
144.9285278	1.38
148.2445374	0.04
148.9398499	0.14
150.0796814	0.14
162.8862610	12.01
171.1177216	0.09
178.9905548	0.19
180.1693726	0.25
184.0804443	0.07
185.0345764	0.07
196.1201324	0.15
204.1624756	0.56
207.0493469	0.44
216.1454773	0.49
223.2219238	0.07
227.7302246	0.27
229.4163818	0.17
230.9072266	0.51
237.2958069	0.35
239.1281433	0.93
243.1002502	0.15
248.4891052	0.44
250.1302185	0.09
252.3422241	0.08
253.9715271	0.22
256.0610352	0.17
258.9466553	2.36
260.3573608	0.44
263.1595764	0.47
266.3394775	0.73
266.9544678	0.06
268.0162659	0.45
268.7725220	0.86
271.2638550	1.72
276.3693848	0.57
277.1231384	0.50
284.2346802	0.76
288.9579163	0.56
294.2406616	15.40
295.0052795	100.00
297.4135437	0.17
300.5587769	0.34
303.1464233	0.78
307.8016357	0.59
312.0844727	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	305.09
Annotation	Demonomethylchlorpromazine
Peak:m/z	Relative Intensity
96.8697052	1.24
98.6929626	0.10
107.0298462	0.53
115.0699844	0.33
115.9705811	0.12
119.2737579	0.07
124.9533844	21.15
130.9326630	0.14
131.9983521	0.46
133.1186218	0.11
133.8672791	0.06
136.1575623	0.04
137.0086060	0.25
138.8466187	0.04
140.9733887	0.17
142.9137115	100.00
147.1911011	0.06
149.3592529	0.10
154.0779419	0.05
154.8941956	0.10
157.0331726	0.03
159.1670227	0.06
162.1017609	0.19
164.9105835	1.07
168.9266968	0.20
170.9061279	0.22
172.1678314	0.03
173.9785461	0.12
175.3281555	0.10
183.1935120	0.10
184.9331970	0.21
188.8984985	0.23
193.0731354	0.14
199.0100098	0.06
201.0817871	0.33
203.0436096	0.04
207.0510254	0.05
215.8759155	2.89
217.0173645	0.14
226.9512024	0.07
229.1143799	0.09
232.7145081	0.77
235.0087585	0.13
235.7605896	0.06
238.6770935	0.41
240.8912659	0.03
241.5143738	0.04
245.1390991	0.60
246.0640259	0.28
247.2758179	0.35
249.1717224	0.08
259.2303467	0.57
260.1836548	0.11
261.2714233	0.22
262.2807007	0.03
263.3633728	0.33
264.0552979	0.56
268.2567749	0.09
269.0427856	0.64
271.5582886	0.04
273.1664124	0.62
274.5047607	0.19
275.1632690	0.38
277.1627808	0.30
281.5924988	0.11
284.4527588	0.18
286.1676941	6.42
287.1300354	5.31
288.2311096	0.53
296.2667236	0.12
304.7251587	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3964
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
618.7774048	15.79
733.3394165	11.46
821.4063721	100.00
822.6226196	21.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1111.7498
Annotation	Unknow
Peak:m/z	Relative Intensity
420.2102661	0.02
471.5140991	0.01
914.1473389	0.04
952.4383545	0.08
955.8018799	0.14
974.8651123	0.09
998.9555664	0.03
1001.1088870	0.14
1006.5493160	0.07
1007.7971190	0.11
1011.1574710	0.03
1012.9011230	0.10
1040.7147220	0.18
1050.6860350	0.08
1057.7083740	0.18
1058.5666500	0.12
1069.7973630	0.06
1073.5729980	0.02
1074.6591800	0.22
1086.5142820	0.07
1087.6726070	0.05
1091.4855960	0.10
1112.0312500	5.73
1112.6481930	100.00
1114.4423830	0.63
1115.0952150	0.21
1116.0515140	0.28
1117.2109380	0.18
1118.0935060	0.06
1118.8260500	0.03
1119.8892820	0.06
1122.4184570	0.12
1124.6374510	0.06
1125.7624510	0.03
1127.0853270	0.02
1134.7778320	0.06
1138.3142090	0.01
1145.9626460	0.02
1230.6696780	0.04
1248.2991940	0.03
1250.6296390	0.03
1295.9316410	0.06
1297.7164310	0.04
1305.5727540	0.04
1306.1972660	0.02
1314.5905760	0.01
1324.8635250	0.03
1351.7232670	0.03
1369.2208250	0.03
1370.7218020	0.07
1387.1467290	0.10
1438.8970950	0.13
1442.3570560	0.02
1444.2496340	0.01
1449.8536380	0.08
1457.7691650	0.20
1467.0512700	0.06
1475.2645260	0.02
1486.9495850	0.13
1506.2999270	0.04
1510.7014160	0.17
1511.3145750	0.06
1518.7027590	0.09
1535.1612550	0.04
1537.0588380	0.23
1543.6451420	0.06
1555.4010010	0.06
1566.5886230	0.02
1574.7659910	0.01
1582.8061520	0.01
1585.5906980	0.04
1589.6578370	0.12
1595.6557620	0.01
1596.2679440	0.10
1623.3099370	0.01
1652.2763670	0.02
1694.3923340	0.02
1765.8441160	0.02
1788.7791750	0.04
1794.1696780	0.03
1802.9737550	0.06
1804.6119380	0.01
1868.4395750	0.01
1897.9387210	0.06
1904.9969480	0.01
1917.4774170	0.05
1929.1292720	0.01
1940.1214600	0.02
1945.6820070	0.28
1975.0335690	0.04
1976.5531010	0.01
1982.4715580	6.15
1983.9869380	0.01
1992.9969480	0.01
1995.2586670	0.02
1995.8796390	0.01
1997.0084230	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1719
Annotation	Folinic acid
Peak:m/z	Relative Intensity
136.0628967	0.05
148.1688843	0.02
149.0444031	0.02
163.8937225	0.02
165.0110779	0.06
170.9498901	0.01
177.3993988	0.05
178.1130981	0.12
178.9590149	0.10
197.1178894	0.06
198.1744690	0.30
199.1061707	0.12
213.0402527	4.29
214.0554810	0.85
233.2846985	0.13
234.1357727	0.04
245.2775269	0.40
246.3612976	0.19
248.9230347	0.02
255.2873535	0.06
256.0937500	0.21
257.2001648	0.03
258.1586609	0.05
259.2295532	0.03
260.9870911	1.52
262.1105652	0.31
265.1078491	0.05
265.8699341	0.03
272.2438354	0.07
273.2230225	0.09
281.2360535	0.10
287.9331360	0.08
289.0889282	0.02
290.1205750	0.20
292.4258423	0.03
297.2642517	0.03
301.1869507	1.09
302.0353394	0.03
303.2232971	0.05
308.2268677	0.04
309.5711975	0.22
310.2312622	1.79
311.2301025	0.09
312.6276245	0.02
314.9235229	0.14
327.2296143	100.00
328.3516846	0.13
335.9548340	0.03
343.1840820	0.45
345.0466919	23.07
345.9276428	0.01
347.2263794	0.06
352.8644714	0.02
355.2310181	0.02
356.2296753	0.10
357.1803284	0.18
358.3123474	1.32
359.0950317	0.02
365.9393921	0.18
372.6080627	0.10
376.0535278	0.03
378.3513489	0.04
385.2977600	0.06
386.2240906	0.02
388.3117371	0.06
397.1243896	0.13
399.6110535	0.05
401.3315735	0.02
408.4289246	0.04
410.7876282	0.27
412.2947083	0.17
417.3496094	0.09
421.4166870	0.03
428.1476135	1.08
429.6464539	0.26
430.3291321	0.67
431.0963440	0.14
432.0771179	0.09
433.0288086	0.02
438.2889709	0.03
439.8892517	0.05
442.8203735	0.09
444.8883972	0.03
453.3753967	0.06
456.1917419	12.16
457.1813660	0.14
458.3556213	0.27
461.7022400	0.15
464.3160706	0.11
473.9924927	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	431.03
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0017548	0.14
148.6536102	0.07
161.2095642	0.04
170.1199646	0.14
185.9757385	0.16
187.9802246	0.04
189.1000977	0.20
198.9272766	0.16
214.2577515	0.12
217.1072998	0.16
218.1161804	0.22
221.0332947	0.08
223.8804321	0.37
248.0786438	0.04
262.9730530	0.17
268.0347290	0.24
271.5403748	0.11
274.1703186	0.18
283.1456604	0.34
284.9058838	0.16
290.4682312	0.42
294.9221497	0.57
300.1621704	0.33
302.3411255	0.26
307.2897034	0.05
310.1730957	0.75
310.8153076	0.33
312.8721313	0.57
315.8358154	0.19
317.7905273	0.05
318.9755859	0.35
320.0891418	0.27
320.6916809	0.56
324.3875122	0.44
325.1844788	0.37
333.4401245	0.18
348.9485779	1.63
355.1781921	0.32
365.1675110	0.32
373.3490295	0.18
377.3221741	0.22
383.0225525	0.16
385.0612183	100.00
385.6914062	0.48
387.9199524	0.12
389.5717773	0.35
394.8035583	0.23
396.2241821	0.20
402.2037964	0.50
413.2375793	2.71
413.8440857	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0787
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
96.6187897	0.06
113.0323639	0.05
125.9556732	0.04
130.7663422	0.10
139.9050751	1.72
145.0386963	3.18
145.9567108	0.04
158.1659393	0.08
167.1622925	0.04
169.0182953	0.05
178.9014130	0.05
187.0373688	0.26
194.8205109	0.08
196.0361328	6.45
202.1694641	0.09
211.1330261	0.25
213.0607300	100.00
214.0936737	1.21
215.0486603	0.40
228.5564575	0.03
231.0693817	27.17
232.0433350	0.02
233.0782013	0.06
241.0320892	0.83
242.0780487	0.25
243.2618256	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
456.9423828	7.83
458.2230835	6.55
459.5180054	10.54
474.7597046	16.94
475.3692017	26.62
483.0274048	7.26
483.6989746	6.20
501.1914673	100.00
501.9645386	14.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.4655
Annotation	Cyclotheonamide E4
Peak:m/z	Relative Intensity
406.4924316	0.01
556.6124878	0.02
585.5285034	0.03
628.2396851	0.03
661.4342041	0.02
674.7941284	0.07
692.6179199	0.02
700.8469849	0.05
703.8042603	0.01
713.8968506	0.02
729.6845703	0.04
741.6718750	0.10
746.9227905	0.01
747.6941528	0.12
749.4082031	0.03
759.6693726	0.14
762.0546265	0.01
777.5426636	3.89
778.1799316	0.05
792.1749878	0.01
795.6966553	3.65
798.2329712	0.03
800.7055664	0.13
801.7938843	0.03
806.2201538	0.06
818.8453369	0.05
837.4500122	100.00
838.1756592	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	404.1494
Annotation	N-Methyl-2,3,7,8-tetramethoxy-5,6-dihydrobenzophenathridine-6-ethanoic acid
Peak:m/z	Relative Intensity
128.0150604	0.14
129.8923340	0.03
142.9090118	0.28
145.2182007	0.04
145.9264069	0.03
153.1306763	0.02
159.8526764	0.22
163.1014099	0.02
167.0199127	0.16
171.0637207	0.05
177.0446320	0.33
179.0236053	0.36
185.0003815	0.01
192.0550232	0.02
196.9354248	0.06
206.2346191	0.03
210.0809326	0.17
212.8498535	0.14
223.1823273	0.02
227.9839783	0.03
231.1442871	0.02
242.1589966	0.04
247.1249390	0.01
254.1790466	2.94
266.0272217	0.04
270.5079346	0.03
272.1720276	4.15
276.5087891	0.07
283.4015503	0.04
284.1994019	0.04
285.2045898	0.01
288.1738281	4.20
306.1202087	100.00
308.2056274	0.03
319.2246704	0.06
319.8608704	0.05
324.3484802	0.06
326.3407593	0.08
328.0537109	0.01
332.2265625	0.02
336.8590088	0.09
341.3165588	0.07
342.5186157	0.03
358.1346741	0.08
359.2787476	0.07
360.0695496	0.14
367.3990173	0.02
368.4873962	0.04
373.4779663	0.03
385.1520081	0.11
386.0796204	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0197
Annotation	Daucic acid
Peak:m/z	Relative Intensity
60.9055061	0.62
68.8675919	35.23
69.6416779	0.32
70.9928131	1.54
72.8993225	11.23
75.0085831	0.67
78.9487686	5.11
82.9737244	1.68
84.8043137	2.46
86.9020691	14.07
95.2512054	0.26
96.8659210	100.00
98.9780273	3.30
110.4959259	1.09
111.1197815	0.15
112.9298859	4.20
114.8373718	40.13
116.9036255	3.26
122.9772644	4.51
126.8361816	0.20
129.0096130	9.67
130.8239899	1.73
140.8872528	67.64
158.8922119	9.96
166.7746124	0.31
184.9323578	11.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.0026
Annotation	Unknow
Peak:m/z	Relative Intensity
132.8906555	0.16
133.9966888	0.16
140.2811279	0.06
140.9669189	0.60
149.9790955	0.50
151.0171661	0.32
158.8316956	0.08
166.2713776	0.10
167.0145264	0.07
175.0148010	0.04
177.1921997	0.05
185.0067444	0.05
194.1223755	0.04
195.1509705	0.10
202.9848633	100.00
211.0903320	0.07
241.0800781	1.40
245.9584961	0.11
248.1813354	0.05
264.9208679	0.14
266.7124634	0.06
269.2642212	0.15
272.2948608	0.03
273.2042542	0.04
282.4658813	0.03
284.2477417	0.20
298.1478882	0.22
303.1948853	0.06
306.2056580	0.10
308.0326538	0.09
309.2055664	0.08
315.2479553	0.06
323.1337891	0.14
328.3107300	0.16
339.9388123	0.30
346.1828613	0.07
347.3113403	0.09
357.2856140	0.15
380.9635620	0.17
382.9170837	0.10
396.1894226	0.04
397.4345703	0.28
399.3150940	0.29
400.2880554	0.06
401.2868958	0.16
414.2749023	0.03
425.3516541	0.08
426.1315002	0.32
427.1102600	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.84606171	0.24
112.7948456	0.20
118.7782135	0.28
152.9970703	0.20
156.0437622	0.20
168.9469604	0.33
169.9857178	4.52
171.082016	0.32
177.28508	0.14
183.0063171	100.00
184.0540771	6.54
185.0230713	0.18
193.3229828	0.29
197.0225983	5.49
198.0873413	2.65
201.2998047	0.28
209.0002747	0.07
211.0436096	0.63
212.1416321	2.02
212.8248291	0.46
223.0698853	0.24
225.1656494	1.84
226.0909119	0.36
227.1822815	0.15
231.0739746	0.13
239.2323303	4.57
240.2074585	2.13
241.0478821	0.16
243.2145996	1.93
245.140625	0.28
247.2838745	4.57
248.1513672	0.19
249.380127	1.07
253.0734558	1.69
254.2585449	1.00
255.3099365	0.44
257.1505127	0.28
263.1245117	0.10
265.3969727	0.48
267.2907715	2.44
268.1190491	0.07
281.2426758	0.09
282.2725525	0.82
283.237915	0.22
284.242981	0.49
291.2508545	0.18
293.2775879	4.13
294.1994019	0.07
311.238678	14.19
312.3607788	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.4762
Annotation	Dioscin
Peak:m/z	Relative Intensity
728.7629395	4.91
764.56073	2.77
806.944519	1.19
824.6588745	12.79
867.4892578	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	671.4139
Annotation	Unknow
Peak:m/z	Relative Intensity
193.2657471	3.19
197.9641571	1.26
201.0621338	0.50
203.1394043	2.55
207.9021912	1.25
209.1137238	0.99
211.2772064	2.42
215.1414490	2.25
225.1276703	1.78
237.2911377	0.63
239.0813904	0.96
241.2636719	2.83
247.1749573	3.68
250.1137543	0.50
253.2727661	7.85
255.2608643	1.48
257.5280151	1.27
259.4252930	0.74
265.2695312	1.85
267.3975525	1.94
271.2702637	4.12
279.3641357	2.68
281.2326965	3.18
283.1360474	2.78
294.0649414	1.37
295.1565552	0.43
315.3600769	0.78
319.2965698	0.71
323.4982910	1.00
335.1595459	3.27
336.1718750	1.53
338.9991455	0.39
349.4879150	5.36
353.6269531	0.67
363.3649902	2.25
379.4330444	1.88
391.3691406	2.61
403.3792725	1.22
404.8387451	1.59
405.4740601	100.00
407.2937622	0.67
423.5449829	5.64
427.5016479	0.60
433.6318359	3.96
439.1265869	1.58
453.1913452	1.87
454.9691772	0.91
465.3432617	1.55
471.4667358	2.75
517.5371704	1.22
559.5801392	2.89
573.6300659	0.42
577.5714722	0.70
585.3336792	5.16
597.6318970	0.68
615.5901489	1.18
617.5950317	6.07
625.3543091	2.45
627.4582520	6.20
635.7349243	1.18
653.4570923	5.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	897.95
Annotation	Unknow
Peak:m/z	Relative Intensity
431.4888916	0.04
467.6469727	0.04
513.6210327	0.04
557.5290527	0.02
615.3995361	0.13
629.6252441	0.36
633.4541626	0.88
657.4057617	0.21
675.5905762	1.83
691.5343628	0.03
693.5076294	0.33
703.0536499	1.02
703.6755981	0.26
717.0061646	0.03
717.6156616	0.04
729.5170288	1.51
733.2893677	0.02
739.6730347	0.04
745.6997681	0.18
757.5082397	0.54
771.6149902	0.11
775.3234253	0.64
787.2974243	0.21
789.8513794	0.10
793.5436401	0.03
799.4732056	0.07
817.3212280	1.54
832.9374390	0.10
835.1640015	11.86
835.9368286	0.11
853.2722168	0.08
861.7120972	0.05
879.0858765	0.11
891.6777954	0.03
894.4170532	0.03
897.1749268	100.00
897.9321899	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2136
Annotation	Jasminoside I
Peak:m/z	Relative Intensity
143.0105896	0.03
148.9826660	0.06
155.1614685	0.05
157.0126038	0.07
167.0472260	0.07
195.2756653	0.04
199.0459900	0.05
205.1481781	0.06
231.9633179	0.03
235.2685242	0.03
251.1708069	0.05
253.0275726	0.05
263.0820618	0.07
273.2445984	0.05
275.0337219	0.02
281.1596069	0.55
283.4000244	0.02
293.1275024	0.16
297.2686157	0.02
302.7601624	0.04
305.9873657	0.20
310.5233459	0.19
311.2325439	0.05
313.3147278	0.09
315.3235474	0.02
317.4076233	0.10
323.1488647	0.04
329.2885437	0.55
332.2445068	0.06
343.1006470	0.08
359.4006348	0.05
365.3486328	0.02
374.2907715	0.03
375.2124634	0.11
376.9589844	0.04
385.0154114	0.06
387.4062805	0.05
395.3974304	0.26
400.7998352	0.04
404.0369568	0.03
405.3514709	0.08
407.4284668	0.05
417.2135620	0.10
419.4014893	0.18
431.3608093	0.44
445.2735291	100.00
445.9223938	0.13
447.1033630	0.43
449.6556702	0.09
455.2243347	0.12
456.2231140	0.02
470.1657410	0.12
471.3130188	0.10
472.5026550	0.04
473.2177124	0.31
474.1929016	0.02
493.2906189	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1012.6984
Annotation	Unknow
Peak:m/z	Relative Intensity
291.1986084	0.05
307.3125000	0.06
308.2636108	0.05
325.0250244	0.02
364.1650391	0.01
382.5870056	0.03
472.0737915	0.01
884.6092529	0.08
907.2032471	0.12
919.7313232	0.07
921.0736084	0.07
941.1022949	0.09
955.7243652	0.12
964.2564697	0.08
970.3170166	0.06
971.0350342	0.01
971.9655762	0.11
973.5987549	0.06
979.7720947	0.13
984.5270996	0.68
985.3316650	0.15
987.0808105	0.43
989.2071533	0.02
990.1965332	0.04
993.7319336	0.28
996.8253174	0.03
1013.3371580	100.00
1014.8094480	2.55
1015.8732910	1.25
1016.9588620	0.67
1017.9619140	0.14
1018.5708010	0.23
1019.2319340	0.23
1020.5015870	0.25
1021.4516600	0.04
1022.1950680	0.04
1023.3989260	0.11
1024.5552980	0.18
1027.5924070	0.05
1028.4355470	0.05
1029.3475340	0.05
1097.2595210	0.06
1124.6083980	0.09
1129.5639650	0.03
1147.7849120	0.14
1149.8281250	0.11
1152.1372070	0.11
1167.0029300	0.06
1168.9187010	0.21
1171.8416750	0.10
1175.9804690	0.08
1178.1304930	0.04
1182.1093750	0.08
1185.3427730	0.12
1188.7353520	0.24
1191.2884520	0.11
1197.0386960	0.04
1199.2880860	0.07
1200.9754640	0.11
1203.8841550	0.14
1206.3339840	0.09
1207.2993160	0.09
1208.5904540	0.04
1217.6140140	0.06
1218.2666020	0.02
1223.1711430	1.51
1224.0227050	0.03
1224.7495120	0.11
1232.3786620	0.03
1233.2094730	0.05
1235.3006590	0.10
1236.3271480	0.27
1242.1108400	2.30
1243.1892090	0.29
1245.3903810	0.05
1249.5950930	0.19
1251.4871830	0.22
1256.8699950	0.06
1258.7257080	0.03
1260.2580570	0.10
1261.5568850	0.16
1264.3415530	0.15
1265.6921390	0.19
1273.7640380	0.16
1274.6826170	0.14
1276.8286130	0.06
1279.0434570	0.01
1279.7097170	0.63
1280.8752440	0.22
1291.8941650	0.27
1292.5367430	0.07
1294.3873290	0.25
1296.7495120	0.04
1300.3406980	0.01
1312.7565920	0.13
1317.9837650	0.18
1344.8249510	0.01
1366.7733150	0.04
1389.1343990	0.03
1395.4884030	0.09
1399.9940190	0.04
1423.2349850	0.05
1424.0635990	0.03
1436.0960690	0.05
1472.3775630	0.05
1499.6573490	0.05
1505.4571530	0.03
1513.9849850	0.04
1516.7010500	0.09
1518.0610350	0.07
1525.2327880	0.02
1531.1568600	0.04
1538.0628660	0.04
1546.9801030	0.04
1556.4726560	0.02
1581.8856200	0.06
1600.5739750	0.06
1608.0050050	0.16
1611.7585450	0.07
1616.8477780	0.13
1643.1804200	0.06
1647.9774170	0.10
1656.2286380	0.10
1657.0740970	0.01
1668.5314940	0.06
1680.3596190	0.16
1685.6530760	0.08
1704.3248290	0.05
1704.9964600	0.17
1706.4699710	0.03
1715.1522220	0.07
1717.4407960	0.05
1720.7757570	0.02
1731.1070560	0.05
1732.6649170	0.05
1752.9735110	0.04
1761.3454590	0.10
1764.0548100	0.02
1784.9606930	0.02
1796.1180420	0.03
1799.9105220	0.01
1829.2845460	0.01
1841.2398680	0.05
1877.5230710	0.25
1911.5407710	5.45
1913.4719240	0.02
1928.4774170	0.13
1933.1009520	0.02
1948.5606690	0.03
1955.2581790	0.78
1986.0123290	0.03
1996.4294430	0.01
1997.6594240	0.13
1998.7408450	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3401
Annotation	Unknow
Peak:m/z	Relative Intensity
147.1189423	0.45
148.8904724	1.80
150.8523865	0.13
153.1177368	0.63
154.0040894	0.43
154.9758453	0.18
156.2363434	0.32
157.1265869	1.02
159.0232391	1.88
161.0986023	2.46
163.0299988	2.05
165.2388611	0.30
167.3059540	0.19
168.0516815	0.48
169.0743408	2.11
171.1127930	1.80
171.9701538	0.24
173.0609894	1.50
174.0672302	0.25
175.1493073	2.61
177.0929871	1.00
179.2421875	0.46
181.2686310	0.63
183.1286774	1.93
184.6736298	1.45
185.3476105	0.37
187.1020508	2.11
189.1974792	2.84
190.9779358	0.93
193.0105286	1.02
197.1098633	2.05
199.2027130	2.33
201.1647644	4.09
203.1455536	3.70
205.1567688	0.68
207.0765533	0.71
209.0567627	0.71
211.1400757	3.23
213.0129395	3.65
214.1234436	0.64
215.1547546	5.46
217.1543579	2.77
220.9888000	0.55
223.2414551	0.86
225.0619965	3.43
227.1598358	2.72
229.0969238	5.64
231.0095520	0.46
234.9674530	0.74
237.1642303	0.65
239.2468719	2.51
241.2221985	3.38
243.2528992	1.82
245.0266724	0.17
247.2500610	2.37
249.2584839	2.05
250.0986633	0.12
251.1438904	0.48
253.2576294	2.60
255.2307434	3.32
256.2210083	0.40
257.1802063	0.88
258.6916504	0.26
259.2973022	3.55
261.2888794	0.62
263.0025024	0.56
265.2741089	2.84
267.3145752	4.28
268.3403931	0.30
269.2758179	2.96
271.3059082	1.10
273.1156006	1.10
275.4182739	0.79
277.3013916	0.42
279.2111816	1.30
281.1627808	1.73
283.1436768	1.60
285.2756348	1.23
287.1834106	0.72
289.4222412	1.12
290.9751587	0.47
293.3536987	2.74
295.3080444	5.98
297.3014526	1.47
299.1444092	0.81
301.2805786	0.08
303.1398926	0.29
305.1438599	0.64
307.3811035	1.35
309.3904419	3.46
311.3231812	1.22
313.2227783	1.78
314.9855347	0.53
316.6698608	1.14
317.4865112	0.30
318.7634277	0.08
319.3773193	2.33
321.3761597	1.36
323.0351562	0.72
325.2936401	1.22
327.2555542	1.50
329.3286133	0.25
331.3989258	1.13
333.2549438	0.45
335.4381714	3.39
337.2900391	2.89
339.2281494	0.82
341.2168579	0.39
343.1150513	0.16
345.4414062	3.63
347.5553589	0.13
349.5093994	0.69
351.3096313	0.09
353.0723877	0.24
355.1796875	1.34
357.3407593	0.10
359.1743774	1.40
359.7866821	0.16
361.1990356	3.63
363.3576660	6.50
367.4291382	0.60
369.5458984	0.33
371.1201782	1.11
373.2574463	0.42
375.2151489	0.62
377.4757080	1.63
381.3565063	3.42
383.5587158	0.98
385.3698120	0.60
387.2761841	0.57
389.1117554	0.09
391.3789673	63.06
392.0086060	0.20
393.4425659	1.32
396.7766724	0.10
399.4096680	1.27
401.4415283	13.78
404.5806274	0.43
409.7650146	0.07
411.1868286	1.13
413.5551758	0.79
419.4617310	73.61
421.2705688	0.27
423.3638916	0.62
425.4531860	0.27
427.5164185	0.62
435.2640381	0.37
437.3577881	56.22
439.4056396	0.90
441.1931763	0.62
443.1395264	0.30
452.4586792	0.16
453.4442749	0.31
459.5678101	0.46
463.4174805	0.69
465.5040283	0.50
466.1618652	0.13
467.4020386	4.27
477.3956299	0.23
479.3805542	9.15
480.5034790	0.08
481.5198975	0.18
492.4329224	0.15
495.3333130	100.00
496.0142212	0.56
502.6182251	0.23
505.3109741	17.32
506.1448364	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.4222
Annotation	Kurilensoside J
Peak:m/z	Relative Intensity
225.0800781	0.04
249.2619629	0.03
251.0478210	0.05
255.3325195	0.45
297.4186401	0.12
375.3793945	0.02
381.1567993	0.05
393.6153564	0.04
431.3358765	0.21
457.3847046	0.28
468.4114380	0.12
487.4815063	0.20
505.3162842	0.42
526.5917969	0.21
531.4122925	0.03
586.6078491	0.03
595.5361328	0.08
598.2053223	0.02
616.5663452	0.16
625.1545410	0.21
643.7363892	0.25
651.7143555	0.06
669.6939087	0.05
673.5465698	0.38
674.8636475	0.07
685.0781860	0.05
687.5156860	3.19
695.6603394	0.72
703.4751587	0.03
711.1998901	0.30
713.5192871	32.88
714.3125610	0.98
714.9622192	0.10
730.1710205	0.72
731.3945923	100.00
732.1150513	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.26
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
173.0460815	0.20
174.5493774	0.20
183.1659241	0.11
188.2623749	0.22
191.0946350	0.10
195.0923157	0.21
197.3691864	0.05
206.3710022	0.12
220.9892273	0.03
222.5211639	0.15
234.7005310	0.06
245.0213318	0.14
247.0093842	0.36
255.2528992	0.07
259.2604675	0.13
261.3345337	0.08
294.9487305	0.05
296.0504150	0.42
303.3934937	0.11
307.6440125	0.21
309.3259583	0.20
313.2990723	0.10
315.1081238	0.30
318.0370789	0.15
322.9469604	0.59
328.1805420	0.08
329.2042236	0.22
332.6994019	0.12
335.4632568	0.13
343.5317993	0.20
347.2379761	0.22
348.9038696	0.06
352.1687012	0.25
360.9387207	0.06
365.3903809	0.75
366.7349243	0.57
369.5081787	0.21
377.7536011	0.23
383.2545166	0.38
391.5127563	0.16
406.3464966	0.10
408.3654785	0.22
412.3975830	0.35
415.4506226	0.05
416.2555542	0.27
417.0484009	0.05
419.5997925	0.18
424.6364136	0.05
426.6441040	0.26
433.6928101	0.09
441.1544189	0.07
443.4830322	0.24
444.8291016	0.20
455.5257568	0.15
457.3746338	0.05
465.2330322	0.05
466.3466187	0.11
484.4674683	0.08
486.0646362	0.32
502.8641357	0.07
505.0535889	0.17
506.6450195	0.32
510.7885132	0.56
515.5446167	0.15
521.1121216	0.08
527.5391235	0.50
528.2405396	0.15
539.4453125	100.00
540.4801025	0.07
543.8192749	0.04
547.2227173	0.06
550.1625977	0.19
551.4561157	0.12
552.2114868	0.11
556.2339478	0.27
565.1751099	0.08
566.6265259	0.12
568.1892700	0.24
569.4732666	0.59
572.4749146	0.09
579.6112061	0.23
583.1802368	1.45
586.4725952	0.29
596.7440796	0.27
597.4218750	1.33
598.0349731	0.47
616.6843872	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1402
Annotation	6-Caffeoylsucrose
Peak:m/z	Relative Intensity
145.0141602	0.30
149.0469971	0.11
153.0564117	0.14
158.5584106	0.21
160.9915924	0.32
162.9512177	3.09
169.2362061	0.15
177.0608215	0.53
179.0168457	0.69
187.0516357	3.48
190.8150330	0.29
193.1838989	0.16
194.2552032	0.08
201.1085663	0.06
205.0119324	1.98
213.1534424	0.15
216.9528503	0.43
222.8992310	0.42
235.0965576	7.74
241.1341095	2.02
243.1747589	0.18
247.0298920	0.13
251.0286255	0.52
254.2076416	0.19
259.1755371	0.07
263.2983093	0.08
265.0856323	14.04
293.0999451	0.25
303.3024902	2.63
307.2072144	4.08
314.9063110	0.31
321.2297974	3.25
323.1200256	0.11
325.2926636	3.23
333.1538696	0.90
339.3170166	1.32
340.2586060	0.06
341.5697021	0.19
343.2413940	0.17
354.8153687	0.36
357.2434082	100.00
363.4468689	0.24
364.2147522	0.05
367.2622681	3.84
370.2008057	0.45
371.3554688	0.19
373.5915527	0.09
381.5586243	0.30
387.3895874	0.05
395.1810608	0.08
397.1503906	0.07
405.2867737	1.76
407.2126160	0.58
415.3768005	0.38
416.2985535	0.16
417.2938232	0.04
423.4302368	0.29
427.4909668	0.15
430.5359497	0.16
440.5993347	0.18
449.2837830	0.73
454.3123779	0.19
455.2741699	0.42
456.1594238	1.02
457.2189026	2.89
457.8922729	0.50
458.9319763	0.37
467.2993469	10.39
471.1887817	0.13
472.1059265	0.32
482.8790894	0.75
483.5079651	0.15
485.1981812	17.33
504.3921204	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2395
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9219666	0.10
185.2260590	0.32
191.3046265	0.10
196.0271912	0.04
205.1106873	0.04
209.2275696	0.34
211.2824860	0.08
219.3646698	0.14
234.8534241	0.16
249.2168579	0.06
251.2031708	0.07
253.0511322	0.23
263.3383179	0.14
271.3264771	0.18
280.8703613	0.08
289.2183838	0.29
293.4592285	0.10
298.9052124	0.03
299.5077515	0.19
303.1853638	0.05
305.4092407	0.05
307.2301636	0.22
313.4874268	0.03
315.2807617	0.14
316.9384766	0.10
325.2746582	0.38
327.1260376	0.15
333.4537964	0.06
343.3532715	0.07
360.2346191	0.22
361.0218506	0.03
368.4942017	0.05
370.1912231	0.08
375.2175293	0.06
377.9907837	0.04
385.0906372	0.11
398.2799683	0.02
421.3613892	0.23
422.5197754	0.06
427.1438599	0.13
431.0712280	0.06
433.3836670	0.05
437.2209473	0.18
438.1632690	0.03
439.4005737	0.07
447.5789185	0.05
451.3732300	0.12
459.2789917	0.23
461.1525879	0.10
462.3471680	0.11
463.3987427	0.22
465.0773315	0.17
475.5598145	0.17
477.3071289	100.00
477.9872437	0.40
479.5010376	0.51
481.5203247	0.11
485.2723999	0.07
486.5350342	0.15
491.2833862	0.05
492.2963257	0.05
494.5083618	0.10
503.6034546	0.25
504.4700317	0.55
505.2497559	0.58
507.2528076	0.04
524.7190552	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.067
Annotation	Decarbamoylgonyautoxin 1
Peak:m/z	Relative Intensity
110.9060745	18.68
128.9183350	0.60
145.8204041	0.05
152.8671570	0.04
155.0226440	10.29
157.0510864	0.13
158.9147644	0.03
159.7991028	0.03
161.0551605	0.04
171.0112152	0.03
172.9075012	100.00
173.9112854	0.05
191.0662384	0.68
193.0409546	0.35
194.8934937	0.22
200.0156250	0.11
201.1772003	0.24
202.1669922	0.56
203.1666565	1.01
204.1344910	0.37
213.0223999	0.05
213.9364014	0.17
215.1798401	0.13
218.2793579	0.24
228.0192261	0.26
229.3122864	0.08
230.1918640	0.10
230.9364319	0.06
232.0200806	0.11
236.9888916	0.10
244.2023926	0.14
246.0286255	0.26
247.1170959	0.07
249.0798340	0.16
259.1829224	0.06
260.0754395	0.02
263.1408081	0.03
271.2515259	0.03
274.8902283	0.08
276.1670227	0.48
279.0702209	0.11
281.3987427	0.02
287.1925964	0.06
289.2236328	0.08
292.8687744	0.06
303.3607788	0.05
304.4947815	0.10
312.4459534	0.10
320.4248047	0.06
321.3208618	0.38
331.2978516	0.15
336.1379089	0.05
339.1368408	0.05
346.0894470	0.03
347.1615295	0.38
348.3037720	0.05
349.1971436	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.44
Annotation	Isorebaudioside A
Peak:m/z	Relative Intensity
946.552002	1.87
964.6353149	56.06
965.4555664	100.00
966.2814331	6.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.9247
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8344727	0.07
200.8507538	0.01
217.1242981	0.03
244.8645477	0.39
245.5024109	0.02
267.1366272	0.01
270.0780334	0.02
273.0743103	0.42
304.1369019	0.08
311.1989441	0.05
312.0754395	0.02
313.1440430	0.02
314.1510620	0.01
337.2680664	0.01
349.2661438	0.01
353.0032959	0.01
357.2834473	0.10
358.5031128	0.21
359.1081238	0.22
366.7674255	0.04
373.9083862	0.03
381.6377563	0.04
383.1125183	0.05
398.1416321	0.05
398.9990845	0.01
400.8730164	0.05
402.2098083	0.06
404.1035156	0.01
405.6259766	0.03
419.1771240	0.01
425.0598755	0.01
426.9848633	100.00
427.9660034	0.45
429.0587158	0.89
429.9901428	0.02
434.9816589	0.02
444.9587097	0.06
462.9270630	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.154
Annotation	Unknow
Peak:m/z	Relative Intensity
119.0164795	0.75
122.9930420	1.42
124.9427490	0.08
130.1710815	0.14
132.1180725	0.42
135.9768829	5.27
142.2059937	0.06
144.9026184	0.05
146.9264374	1.37
148.2135468	0.62
154.8232117	0.04
158.3544922	0.21
159.1110535	0.14
161.7757874	0.10
165.0384064	14.62
171.1602020	0.22
182.0379486	100.00
183.0136566	1.01
186.9628143	0.04
189.2930603	0.06
191.4113464	0.12
205.3477478	0.33
223.1152649	0.67
232.0340271	0.27
248.3074036	0.19
260.9558105	0.07
266.3640137	0.32
270.2857971	0.16
273.2222900	0.19
276.1479492	0.26
293.6618652	0.19
301.0679016	0.09
315.1827698	0.28
316.2516479	3.19
317.2597656	1.47
317.9882507	0.05
322.1907349	0.46
326.2542419	0.17
334.7849426	0.08
340.7303772	0.26
343.0550842	0.25
344.0776978	0.22
345.1098633	1.51
346.2348328	0.16
353.5773315	0.34
354.6755676	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.3769
Annotation	Methylanhydrovilangin
Peak:m/z	Relative Intensity
167.9380035	1.08
169.1532288	0.47
170.1640625	0.26
171.1678467	3.95
173.1465454	0.87
175.2137756	1.02
176.9742432	0.89
179.2239227	0.47
181.0911865	1.77
183.0539703	4.55
185.1640015	2.77
186.3647003	0.61
187.1123657	1.95
189.1147156	2.73
191.0310974	0.92
192.2732849	0.63
193.0906372	0.65
193.8223419	0.17
195.1432343	3.53
196.9060974	4.05
199.1275482	2.11
201.1737518	3.54
203.1793518	4.67
205.1527710	1.82
206.0301361	0.75
207.1529541	0.42
208.0393829	0.16
209.1171417	3.80
211.1127472	2.71
213.2259674	14.33
215.0595245	4.95
217.2266235	4.19
219.1534424	2.16
221.4191132	0.20
223.1987915	3.53
225.1640930	4.63
227.2302704	2.94
229.1522369	2.89
231.2992249	2.87
232.9717865	1.42
235.3913879	0.44
236.3239441	0.49
237.0965881	4.11
239.2100372	7.51
241.2461853	4.95
243.2213135	1.88
245.0393677	2.39
247.2637939	1.16
249.2655182	3.16
251.0898590	2.40
253.1748962	12.57
255.1749878	6.10
257.1345825	1.90
259.1767883	11.79
260.2412415	0.55
261.2435303	1.61
263.2487183	1.22
265.0865479	2.69
267.1381226	5.06
267.7618103	0.16
269.2995605	4.94
271.2187500	8.56
273.2303772	3.01
275.2613831	1.41
277.1794434	1.46
279.0419922	7.75
281.3161621	10.90
283.2323608	5.82
285.3325195	3.80
287.3689575	3.83
289.1846313	0.49
290.8610840	0.45
291.5349121	0.44
293.3746948	2.61
295.2935791	14.29
297.2725830	5.33
299.1601562	14.36
301.1947937	0.45
302.2065430	0.57
303.2780762	0.73
305.3070068	0.95
307.1211548	6.62
309.2495728	6.71
311.2769775	6.15
313.3227539	4.18
317.3125000	0.86
319.2634277	3.52
321.2393188	6.49
323.2960815	2.59
325.2239990	8.71
327.3382568	12.64
329.5045166	0.65
331.2606812	0.71
333.2489014	0.82
335.3267212	5.79
337.2713013	4.11
339.3078003	1.32
341.2383423	1.60
345.4158936	2.44
347.3276367	0.63
349.3886719	1.43
351.7100830	0.33
353.4117432	4.00
355.2443237	5.89
357.1570435	0.66
359.3308105	1.50
361.2318115	1.00
362.8397217	2.00
363.5038452	3.66
367.4677124	2.60
369.5242310	1.93
373.1450806	0.37
375.2631226	2.42
375.9168701	0.97
377.3505859	1.92
379.3000488	1.02
381.3118896	10.93
385.1577148	0.52
389.3142700	1.20
391.4451294	93.00
393.2792358	2.07
395.3562012	2.84
397.0571289	0.12
401.4685669	21.08
403.2081909	0.56
404.6594238	0.79
407.2758179	0.30
409.4066162	17.96
411.3327637	0.78
413.1162720	0.12
414.6168213	0.28
417.3129272	0.18
419.3565674	85.57
421.3995972	0.40
431.3840332	0.99
435.1892700	0.12
437.3949585	84.62
441.2097778	0.13
443.5974121	0.63
445.2770996	1.01
447.3634644	1.53
455.4368286	0.09
459.5614014	2.39
465.5245972	0.78
469.4927979	0.24
471.2634277	1.57
473.4702148	0.36
477.8201294	1.04
483.4403687	0.28
485.4774780	0.58
487.2366943	2.15
489.5037231	0.41
496.8653564	0.60
497.7675171	0.73
499.6162720	0.45
501.4317017	0.31
513.2092896	1.56
515.2872925	1.16
523.4943237	0.14
533.6030884	0.75
537.2492065	0.92
541.3557129	4.42
543.1586304	0.71
543.7954102	0.20
551.4278564	3.30
553.3145142	0.91
561.4885864	1.11
569.3241577	100.00
570.0181274	0.80
579.5234375	10.96
580.4906616	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2822
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
219.0479279	0.05
281.3822327	0.07
285.3174438	0.03
303.1748047	0.11
306.4349976	0.05
309.4244385	0.05
313.3258057	0.12
325.2754517	0.11
355.2886963	0.17
372.3347168	0.02
376.9725952	0.14
380.3131104	0.03
399.9533691	0.08
402.4400024	0.13
406.1461792	0.03
414.5892944	0.14
421.0598755	0.07
426.2363892	0.26
430.2968140	0.30
432.4329834	0.97
444.2941895	1.20
446.3097534	0.18
448.2731323	0.07
458.2418213	0.48
462.3076782	0.32
463.6159058	0.15
470.3195190	0.91
471.4322510	0.18
472.5053711	0.18
474.3334961	0.03
478.0401611	0.06
480.2169800	0.07
488.3639526	2.00
490.2321167	1.57
492.5756226	0.03
498.3469849	0.21
499.2595215	0.11
502.3038940	0.67
503.2395630	0.05
507.0776978	0.05
508.2260132	0.26
511.5375366	0.02
514.6541748	0.19
515.6526489	0.24
520.3384399	6.73
521.2362671	0.08
523.4665527	1.10
537.0748901	0.02
539.3075562	0.49
541.5421753	0.41
553.5396118	0.79
555.3511353	0.37
563.1761475	0.03
565.4723511	3.12
567.2628784	1.69
569.9529419	0.03
571.3316040	1.33
573.4849243	0.29
575.3307495	0.04
579.5975952	0.11
583.4510498	18.37
585.3444214	5.50
587.3816528	1.18
591.3479004	0.09
597.3596802	3.58
599.3118896	1.86
600.6564331	0.63
601.4963989	2.25
605.2559204	0.10
609.3467407	3.50
615.3483276	16.67
617.3838501	6.66
622.4977417	0.08
623.4959106	0.04
627.4505615	46.92
629.4025269	2.10
630.6277466	0.09
631.4209595	0.08
633.3764038	0.06
641.4371948	2.34
645.3878174	100.00
646.1088257	0.04
647.3241577	5.73
647.9522095	0.02
656.5698242	0.08
657.6024780	0.09
659.3426514	18.66
660.0168457	0.06
677.3758545	24.19
678.0267944	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.15
Annotation	4-Hydroxy duloxetine glucuronide
Peak:m/z	Relative Intensity
141.9803772	0.03
145.0425110	0.60
146.9268188	4.36
148.9550018	0.04
152.3378296	0.05
164.9812164	14.93
172.9847107	0.13
181.9761505	100.00
184.0205994	0.04
189.0513916	0.03
192.9202576	0.03
194.0798645	0.04
196.1484070	0.08
198.9185486	0.07
203.3389893	0.03
213.1221008	0.07
217.1778107	0.20
218.1929474	0.06
220.0589142	0.03
222.8393555	0.30
223.6535645	0.10
229.0128479	0.09
231.2696228	0.02
240.0116272	0.05
241.1074219	0.13
242.0654602	0.12
243.2529449	0.21
244.0734253	0.15
245.1776123	0.08
247.9676971	0.08
251.6045837	0.07
255.1105042	0.03
258.3801575	0.28
259.0539856	0.64
260.0677185	0.41
261.9401855	0.25
263.1286316	0.03
264.1900635	0.08
265.8123474	0.21
267.1660767	0.15
268.1154175	0.27
273.0112610	0.11
277.1970825	0.07
278.0576477	0.03
279.1710205	0.10
281.0714111	0.06
283.9817505	0.02
285.9885864	0.22
289.1108398	0.09
290.1397095	0.22
291.1997986	0.12
297.2255554	0.28
299.2631226	0.11
300.3616333	0.07
302.1879883	0.21
304.1864624	0.03
306.9426880	0.18
307.7382507	0.32
309.3058167	0.11
310.3937988	0.07
313.2355652	6.11
314.2169800	3.21
315.2250977	0.25
317.3477783	0.19
321.9767151	0.39
325.2370300	0.39
327.3377075	0.34
328.2361755	0.75
329.3092346	0.19
330.3838196	0.04
331.2441406	0.08
332.2624512	0.19
337.8432617	0.22
339.3545532	0.08
342.2370300	0.30
342.9640198	0.27
343.5870361	0.21
345.3869629	0.07
354.4493713	0.03
355.3412781	0.05
356.9291382	0.41
357.6791382	0.21
358.3147583	0.61
359.2730713	0.46
360.1759949	0.11
361.1875000	1.50
362.1807861	0.06
370.5244751	0.16
375.5681763	0.29
376.1996155	0.05
377.2531433	0.81
383.1363220	0.21
384.4081726	0.12
388.1557312	0.36
393.2755127	0.35
397.4475098	0.34
399.2229004	0.06
401.9182129	0.15
406.2191467	0.08
407.2527771	0.27
410.3386841	0.24
415.1048279	0.59
415.7179260	0.25
417.0629578	0.06
418.1000061	0.11
423.4739685	0.11
425.2160339	0.13
427.3154602	0.31
429.2035217	0.03
429.8166504	0.03
436.0656433	0.04
442.6414490	0.34
443.4590454	0.09
444.4329529	0.12
445.2348938	0.14
453.1603699	0.22
454.3954773	0.53
471.4961853	3.82
472.3246460	5.55
473.2633667	0.13
480.3926697	1.25
481.3832092	0.24
500.4700317	0.12
504.3031311	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.17
Annotation	Trans-Zeatin-9-glucoside
Peak:m/z	Relative Intensity
116.0294724	1.12
141.9278259	0.17
144.9876099	0.09
147.0350342	0.43
166.1552124	0.39
168.9916382	5.80
173.9072571	0.43
184.0386963	2.54
185.3018341	0.14
187.1636047	0.45
187.9675293	0.47
202.123291	3.12
208.9825287	0.33
210.2316742	0.14
213.1226501	84.56
214.1067505	6.53
217.4220276	0.07
220.1173859	100.00
227.1461487	0.37
232.3016663	0.17
233.1073303	0.60
244.1475525	0.18
250.3026733	0.07
251.7982788	0.17
266.0847168	8.42
267.2395325	0.39
275.386322	0.19
276.3276978	0.64
281.0593567	0.39
283.9687195	5.98
287.4728699	0.64
290.055603	0.38
293.7715454	0.15
308.6065979	1.96
310.1481628	11.90
311.2245483	3.06
313.4110107	0.15
316.0219116	0.16
318.173584	0.59
319.7303467	0.14
322.0377197	0.53
328.3778076	1.00
335.2704468	0.98
336.0872803	0.78
337.0637207	0.44
338.0236816	0.13
340.6898499	1.29
344.3230591	1.83
350.4043579	0.19
353.4892273	0.53
359.3068237	0.25
361.80896	0.16
363.4828186	6.27
364.2804871	1.53
365.0833435	0.47
373.5806274	2.36
382.8221741	0.49
390.5664062	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.4758
Annotation	Dioscin
Peak:m/z	Relative Intensity
365.6011353	1.41
487.4420776	8.71
659.5827026	3.14
710.5446167	7.11
763.3875122	16.04
764.5662231	2.80
806.5761108	17.27
822.3435059	10.94
823.7005615	4.68
824.6068115	35.94
831.8800049	4.34
867.477478	100.00
868.1915894	4.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	644.3238
Annotation	Unknow
Peak:m/z	Relative Intensity
181.7373199	0.81
197.9765320	0.20
199.0431824	0.24
199.9079132	0.39
205.8938141	0.28
206.9048004	0.67
213.6870422	0.17
217.1027069	3.16
222.1809692	0.18
223.0817261	0.05
226.9172821	0.73
228.0435486	0.30
239.2244263	0.78
240.2128296	0.20
245.1221161	0.75
246.0171204	0.15
257.8394165	0.07
274.4288940	0.37
276.8524475	0.53
282.2623901	0.31
283.3771973	0.54
285.7286682	0.15
294.1524658	0.19
296.5590210	0.42
299.7249451	0.42
301.2648315	1.02
311.4583740	0.51
312.0680237	0.16
319.3895264	0.24
327.3351440	0.35
328.3811646	0.12
331.2113037	0.12
331.8564453	0.69
336.8327637	0.16
346.4201660	0.12
359.4212036	0.14
363.4637451	0.34
367.8541260	0.36
369.1257935	0.09
372.5101929	0.29
380.4210815	0.14
382.4617310	0.24
385.5968018	0.99
389.5244751	0.32
394.5896606	2.40
399.4426880	2.12
400.3477173	0.10
403.3062744	0.41
409.8484497	0.19
412.3598633	1.43
419.3638306	0.34
421.6027832	0.89
422.4465942	1.31
423.0500488	0.13
424.2756958	0.65
425.9758911	0.31
427.2974854	0.50
429.6926270	0.41
431.7078247	4.81
437.0999146	0.56
441.5499878	0.62
442.8903809	0.86
443.9794922	0.49
449.4636841	0.92
454.8203125	0.57
455.5939331	0.32
456.5866699	0.21
459.2983398	0.29
460.7269287	0.08
463.5742798	3.54
464.8258057	1.49
466.9287109	2.51
468.4119263	0.14
469.2832031	0.08
470.4101562	6.69
471.6679077	1.03
472.7226562	1.76
473.8361206	0.69
474.5358887	0.10
476.2943115	7.75
476.8978882	1.77
478.2943115	0.73
479.1187134	0.94
480.4721069	2.57
482.5866699	0.21
486.2876587	1.54
497.5312500	1.26
498.3463745	0.17
500.5882568	0.23
501.6375732	0.87
504.5035400	0.50
510.3679810	1.65
511.1376953	1.79
511.9727783	0.07
512.8679810	0.07
513.4779663	0.87
515.5163574	0.06
517.6503296	0.24
518.7681274	6.01
519.4470215	0.58
520.3690796	0.95
521.4909668	1.60
524.4158325	1.39
525.3803711	1.14
527.6651611	2.96
528.6876831	2.37
530.4012451	1.41
531.1669922	1.13
533.0597534	0.64
539.1436157	0.60
541.9203491	0.13
543.2741699	0.35
544.5961914	0.57
548.1521606	2.01
554.3334351	0.18
555.5485229	0.17
559.6732788	1.23
567.1489868	0.19
569.8291626	0.67
573.5293579	2.21
575.0780640	1.97
576.6613159	1.45
580.3110962	0.81
583.3621826	4.21
585.6655273	1.69
586.5926514	2.23
587.8951416	0.34
589.5172119	2.34
591.4833984	1.79
592.0999146	2.73
592.7587891	13.00
593.6309204	0.28
595.1000366	2.93
596.0711060	23.80
596.9334717	0.73
597.7738037	1.49
598.3945923	0.38
600.5490112	0.05
602.7341309	1.71
607.3153687	0.21
608.5895386	0.43
609.8203125	2.06
610.9027100	1.30
611.6661377	1.09
613.6936646	1.07
614.8678589	31.78
615.6771851	3.23
618.2506714	57.87
619.1798706	3.98
621.1445312	0.14
622.2122803	6.89
624.1560669	0.54
625.1375122	0.66
626.0117798	2.29
627.3528442	3.24
628.9342041	3.00
629.5489502	1.63
631.2598877	2.52
632.3094482	2.15
633.1956177	0.94
634.1068115	6.80
634.7467041	1.70
636.5563354	0.22
645.5404053	0.54
647.1129761	0.20
649.3740845	0.81
654.4763794	0.16
661.3103027	0.26
664.4877930	2.04
665.1864014	0.07
672.8217163	5.90
674.0830688	1.10
675.4440308	0.14
678.2731934	6.74
679.0889282	1.42
680.1070557	0.25
682.2578735	1.30
683.2630615	0.27
684.1507568	1.54
686.7002563	0.70
687.5817261	0.50
689.0538940	3.78
692.2596436	0.48
700.4644775	0.91
703.9392700	0.99
705.0712280	1.07
707.5805054	0.77
708.6314087	4.20
710.0366821	0.55
711.6640015	1.03
712.6583252	0.79
713.5968628	0.85
714.2460327	0.12
715.3208618	1.97
716.2374268	4.11
716.9456787	2.10
720.2597046	1.77
720.8722534	0.72
722.9236450	1.06
723.6585693	0.42
724.5850830	2.46
726.6558228	3.68
727.6605835	0.96
728.5473022	0.89
729.7841187	1.93
731.1843262	0.50
733.1925659	1.41
734.4073486	1.91
735.4985352	0.46
736.5470581	4.45
737.6261597	0.86
739.1492310	1.73
740.4970093	38.47
741.4085693	0.95
742.2353516	0.82
743.2355957	0.18
744.6738892	100.00
745.6782837	16.67
747.0466309	0.91
748.1568604	1.23
748.7811890	6.23
750.1817017	5.65
751.0457153	4.27
751.9313354	1.27
752.6903687	0.22
753.4594116	0.57
756.0792847	7.04
756.9675903	1.01
759.6441040	34.54
760.5205078	0.44
761.6077881	1.45
762.8889771	0.07
763.9297485	1.73
768.6438599	1.32
771.6500854	6.08
772.4963989	1.07
773.6279907	0.45
780.2769165	16.35
781.2363892	5.74
782.0628662	1.88
787.9320068	2.01
790.8706665	0.45
793.9642944	1.78
797.5640869	1.59
798.8900757	0.54
804.1126709	0.28
806.3668823	0.36
807.6705933	2.33
808.6437378	1.29
810.5156250	0.41
811.3878784	0.53
814.7280884	0.23
815.8682861	14.60
816.9565430	7.32
817.8032837	0.41
818.4443970	0.53
820.4209595	0.25
824.2229614	0.29
826.7343140	0.09
828.0354614	0.23
830.6919556	0.42
832.4456177	1.07
837.5203857	0.37
838.7754517	0.17
840.0487061	1.79
840.6947021	1.70
849.0578613	2.06
853.0403442	1.16
859.0537109	0.67
865.1000977	0.31
866.1450806	1.52
871.4204102	7.07
873.6010742	0.13
880.5443726	0.77
888.4695435	6.00
889.3866577	6.38
890.1923218	1.37
891.5212402	1.29
892.6705933	0.19
894.8020020	0.19
895.9078979	11.17
896.9695435	18.77
897.7538452	13.22
898.3715820	12.75
899.1353149	2.11
904.2750854	0.74
905.7691040	0.93
906.6218262	1.58
907.9504395	0.49
908.6918335	0.38
910.2000122	1.84
911.1750488	0.92
914.7434692	0.13
921.0998535	4.45
921.8972778	0.97
923.2200317	0.55
924.6887207	0.07
925.6577148	0.92
926.8504028	0.07
942.3378906	0.30
943.9497070	0.84
944.7148438	0.36
948.4191284	0.44
949.6804199	0.73
953.4538574	1.36
954.5222168	2.05
957.2770386	0.26
961.5042114	5.27
962.3208008	1.06
982.6914062	0.31
1005.7995610	0.16
1008.2277830	0.60
1009.0776980	1.18
1013.7446290	0.10
1014.4635620	0.27
1016.1737670	1.59
1017.6422730	1.37
1018.3606570	0.79
1019.9196170	0.09
1023.5516970	0.44
1024.6716310	0.31
1025.5538330	0.84
1026.8115230	1.02
1036.9313960	0.37
1038.9012450	0.25
1041.7314450	0.20
1055.6193850	1.27
1061.8487550	0.77
1075.7392580	0.27
1076.8874510	0.25
1079.9321290	0.74
1081.6457520	1.87
1082.7354740	0.41
1089.0013430	0.27
1097.4440920	0.29
1107.0549320	0.30
1126.9017330	1.63
1161.5869140	0.18
1169.4267580	0.55
1170.5947270	0.23
1187.6376950	0.26
1210.8443600	1.03
1243.9354250	0.31
1253.6367190	0.07
1276.0018310	0.09
1328.7874760	0.16
1332.7106930	0.21
1357.0098880	0.37
1407.0069580	0.27
1474.3531490	0.19
1488.7623290	0.18
1501.0097660	0.33
1504.0628660	0.78
1632.1052250	0.21
1654.9246830	0.26
1714.9802250	0.33
1746.1256100	0.22
1760.8995360	0.10
1764.4763180	0.09
1768.3031010	0.46
1776.2019040	0.98
1824.4442140	0.63
1882.3787840	0.26
1914.9455570	0.17
1951.1270750	0.36
1979.2659910	0.15
1996.6126710	32.53
1998.1722410	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
616.0720825	12.28
755.4851685	4.55
798.2550659	2.48
833.5567017	7.72
835.6444702	11.82
874.8403931	1.52
913.475647	6.48
917.5779419	10.48
942.4706421	3.56
967.4021606	100.00
968.2167358	7.59
969.562561	5.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	840.45
Annotation	Carbomycin
Peak:m/z	Relative Intensity
459.5587158	2.16
609.5050049	3.42
616.4487915	2.24
617.3851929	0.84
633.6192017	0.71
635.5390625	1.42
636.574585	0.65
677.5042114	2.92
684.9020386	0.85
708.0524292	0.90
733.4801025	1.73
744.4441528	0.44
775.1226807	3.10
779.5262451	32.52
780.6343384	0.54
793.4185181	5.58
796.4897461	4.07
797.6801147	48.24
798.6895142	3.72
801.7526245	0.44
803.7026367	3.62
808.1628418	1.05
819.4608154	32.28
821.6471558	1.79
840.4405518	100.00
841.2159424	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.2067
Annotation	Physalin L
Peak:m/z	Relative Intensity
141.4759216	0.03
149.9429321	0.12
169.0899963	0.29
169.7587280	0.12
173.8742523	0.21
179.1213074	0.15
185.3089294	0.04
191.2835999	0.10
196.9787903	0.04
207.2997131	0.08
215.1178436	0.07
234.9009094	0.09
237.1097717	0.22
239.0737915	0.08
240.0879059	0.22
244.0174408	0.25
252.0551453	0.90
252.8976288	0.04
254.3734436	0.19
256.1044312	0.09
269.2438965	5.96
270.2335205	3.22
280.0510864	0.08
280.9842834	0.31
286.1235352	0.17
296.4007568	0.04
298.1643066	1.19
315.1762695	61.84
316.0914917	0.04
334.1722412	0.03
341.0173340	0.21
353.2506714	0.24
354.9359131	0.64
355.6050415	0.24
360.0863037	0.19
360.7260742	0.03
365.9465942	0.03
367.3974609	0.16
370.1850586	2.01
372.4970703	0.26
380.9110107	0.05
382.1392822	0.37
383.5860596	0.58
384.2592773	0.07
395.4440308	0.15
398.3911743	0.24
400.2424316	1.27
411.4596558	0.09
422.2908325	0.26
423.3054810	0.42
427.1472778	0.05
438.0944824	0.04
439.8156128	1.09
440.5054932	0.65
444.6801147	0.03
446.8150635	0.09
447.6174927	0.49
449.2644653	0.39
455.3146973	0.95
456.3483276	0.93
457.2945557	0.12
465.1341553	0.06
466.3770752	2.26
467.3066406	8.03
468.4469604	0.29
477.1461792	0.03
484.2443237	100.00
485.1421509	0.60
485.7792969	0.07
492.0750732	0.09
494.2817383	1.80
495.4389038	0.12
501.3549194	15.46
511.2633667	12.10
512.3076782	16.53
513.5121460	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.109
Annotation	Chiriquitoxin
Peak:m/z	Relative Intensity
110.8370743	0.01
128.9498901	1.77
132.9211578	0.02
140.7444458	0.05
149.1132355	0.07
158.9893494	1.86
177.1025696	0.65
195.0168457	100.00
196.1208801	0.04
197.1729584	0.14
210.7561951	0.01
292.6197510	0.08
293.3175049	0.09
300.9262695	0.06
303.0864258	0.11
355.0407104	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	951.4614
Annotation	Licoricesaponin F3
Peak:m/z	Relative Intensity
695.5545044	0.44
743.5639038	1.61
761.6209106	2.60
769.7994995	0.23
779.3004761	0.55
779.9735718	0.10
803.4774780	10.18
820.8417358	0.41
821.4978027	14.71
863.4158325	27.00
864.0990601	0.33
865.1716309	0.27
906.7382812	4.88
907.4157104	13.98
923.4830933	0.19
951.3099976	100.00
952.3830566	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	536.2255
Annotation	Neoharringtonine
Peak:m/z	Relative Intensity
156.9840240	0.21
161.9543457	0.93
174.8966370	0.23
179.0115356	5.44
187.1751862	0.15
201.9464722	0.08
205.0440369	0.04
213.3141632	0.22
215.0682983	0.27
221.9049988	0.10
223.0844269	0.05
229.2496033	0.13
232.9152527	1.05
246.9802246	0.07
264.1920166	0.18
266.0335083	0.13
272.1482544	0.30
272.9462280	0.29
282.4126587	0.18
283.2141724	0.04
285.3700867	0.10
287.3038940	0.16
290.9489746	0.14
298.2452698	0.14
301.4495239	0.05
303.3646240	0.16
304.4793091	0.22
308.1412964	66.57
309.5980225	0.03
310.4069824	0.15
313.1471558	0.17
314.0075073	0.11
333.7990112	0.07
342.2283936	0.06
350.4011230	0.25
356.2409668	0.14
357.7515869	0.99
368.5219727	0.11
370.1801758	0.24
373.5190430	0.27
375.3903198	0.04
378.2724609	0.11
379.8536377	0.06
386.1237183	0.12
389.1159668	2.41
406.2411499	1.89
407.1979370	0.11
407.8082886	0.22
420.5437622	0.06
423.5873413	0.27
425.5928955	0.04
427.6152344	0.25
428.8972778	0.17
430.9608154	0.26
432.7817383	1.07
435.4829102	0.34
440.2186279	0.14
443.3410034	0.21
446.7483521	0.42
447.7119751	0.06
454.1931152	0.62
454.8544312	0.87
461.2667847	0.05
465.2857666	0.10
482.1184082	0.48
483.3162231	1.11
487.2687378	0.47
488.2403564	0.12
491.3940430	0.05
492.1344604	0.13
500.2924194	0.28
502.9428101	0.12
504.4002075	0.36
506.2243042	0.06
518.1472168	100.00
519.1464233	1.12
520.3316650	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.692
Annotation	Unknow
Peak:m/z	Relative Intensity
124.0879135	0.06
126.9093323	0.59
130.0513000	0.20
137.2586060	0.05
140.9972687	0.03
142.9034119	0.04
144.1247559	0.06
144.9260559	0.58
146.8936768	0.33
148.1334839	0.07
149.0657349	0.22
151.4035645	0.10
159.0693665	0.10
160.6541443	0.03
162.9648743	0.75
166.9839478	0.04
171.1287537	0.21
173.1685791	0.15
174.2828674	0.03
175.1891479	0.16
177.2594604	0.12
184.1041870	0.03
187.1358795	0.20
199.2798462	0.19
200.7171631	0.02
203.1165619	0.98
204.3554230	0.03
213.1238098	0.07
214.9058380	0.22
217.1819153	0.07
224.1251526	0.07
228.9859619	0.22
231.0891724	0.13
239.0944214	0.47
242.8523865	0.10
249.0756531	0.29
253.1453247	0.04
256.0256042	0.04
257.0916443	0.25
260.7760925	0.04
263.0182495	0.14
265.0657654	0.03
266.1587219	2.42
270.9399109	0.08
271.5860596	0.02
273.6125488	0.04
274.6498718	0.14
276.2802734	0.11
278.0714722	0.02
279.2934570	0.05
280.0590515	0.16
283.4078369	0.12
287.3411865	0.02
291.1511841	0.05
293.3887329	0.30
295.3031006	0.14
299.2091064	0.05
301.2047119	0.15
302.0604858	0.06
305.7747192	0.10
307.1343994	0.13
308.3239136	0.25
309.1214294	0.05
311.2985840	0.22
312.4474792	0.39
321.7304077	2.04
322.3417664	0.23
327.3103638	0.03
328.9362793	0.09
330.7120972	100.00
331.8242798	0.57
332.6789551	0.09
334.1383362	0.06
335.0341187	0.13
337.0297852	0.06
341.6860352	0.12
348.3719788	0.04
351.1939087	0.23
352.2437134	0.27
353.3041992	0.31
355.3246765	0.06
356.8793640	0.21
360.8041687	0.10
363.1985168	0.09
364.7128296	0.21
365.3365784	0.34
366.1498718	0.31
366.7810364	0.08
367.5007629	0.23
369.5289307	0.27
370.4378357	0.36
371.6285095	0.04
375.1813660	0.36
376.3427734	0.08
377.0018005	0.09
381.2293701	0.21
383.3843689	0.32
384.7504272	0.45
385.5191040	0.52
387.5379639	0.18
388.2158508	0.03
393.0895996	0.82
393.9078979	0.67
394.5934143	0.15
395.2508850	0.20
401.8562622	0.19
402.9176941	0.46
405.6844177	0.13
411.4509583	0.07
420.8290100	0.13
428.4252014	0.08
459.2323914	0.06
468.3010559	0.02
475.2691040	0.08
485.2904968	0.14
496.1757202	0.10
500.1492615	0.27
500.9374084	0.14
503.3775940	0.11
513.0567017	0.11
515.0346069	0.05
515.6779785	0.06
527.5133667	0.12
531.4637451	3.16
534.9963989	0.14
541.5930176	0.17
544.5318604	0.16
548.4432983	0.05
552.9533081	0.18
558.2858887	0.07
572.5316772	0.19
595.6858521	0.06
603.4526978	0.09
608.5379639	0.09
617.5080566	0.16
622.3452148	0.15
642.5469971	0.37
660.4147339	32.68
661.3967896	0.51
675.3291626	0.10
686.4473267	0.10
688.7046509	0.10
693.7542114	0.20
694.4981689	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.4399
Annotation	Isorebaudioside A
Peak:m/z	Relative Intensity
921.0663452	12.41
964.5762329	17.57
965.3996582	100.00
966.0488281	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.0031
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
176.7022552	0.07
196.8413391	0.33
211.0149689	3.46
214.8803101	2.13
218.0985718	0.10
223.8915405	0.26
227.8961945	0.10
232.9206543	0.33
241.0713959	7.53
248.1882324	0.11
256.9513245	2.17
259.0827942	0.13
262.0390015	0.68
269.1892090	0.23
280.0468140	1.32
290.1822510	0.15
299.1286621	1.20
305.1510925	0.19
308.2232666	0.13
310.5093689	0.52
311.1500244	1.06
317.0058594	0.36
318.2332153	0.57
321.0370483	0.16
323.0696716	100.00
323.6823120	0.14
329.0303345	8.64
334.1195679	3.04
340.9375610	0.35
342.0699463	0.29
347.1250610	0.21
352.1257324	0.81
353.5621948	0.26
354.3291016	0.06
359.1036377	6.27
361.1222534	0.07
363.1674805	0.07
364.1231079	0.35
367.9052734	0.06
371.0120239	0.26
372.0043335	0.55
377.0952759	10.56
378.1533813	0.13
380.1206055	2.01
382.1596680	0.48
384.2094116	0.09
388.4292603	0.29
391.0604248	0.07
393.1915894	0.16
395.2736816	0.10
398.0923462	1.51
400.9444580	0.20
406.3151245	0.35
411.1954956	0.11
413.8143921	0.17
419.1482544	4.00
423.1099854	3.16
424.1138916	1.42
425.9979248	0.26
427.9624634	0.13
430.7294312	0.41
431.3804321	0.13
433.1019897	0.63
434.7866211	0.58
440.1469727	6.18
441.1242065	37.35
443.2706299	0.07
443.8952637	0.11
446.4512329	0.17
447.2512817	0.32
448.0791016	0.05
449.1638184	0.50
452.0966797	0.58
453.4735718	0.19
458.0206909	1.50
462.1178589	0.24
466.8315430	0.10
470.1250610	16.65
472.9802246	0.54
483.0284424	39.42
485.0086060	0.07
488.1906128	3.73
489.2581177	0.12
491.1811523	1.82
500.0974731	0.28
501.8052979	0.09
502.7074585	0.09
505.7016602	0.24
516.2669678	0.35
517.0208130	0.04
518.0166016	0.73
518.9244995	0.73
524.0910034	2.50
525.4855957	0.10
542.1643677	4.11
556.2975464	0.39
557.1661377	0.05
557.9840698	0.17
560.0954590	68.49
585.1972046	19.48
603.1768188	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.065
Annotation	Chiriquitoxin
Peak:m/z	Relative Intensity
128.9355316	2.64
141.1101379	0.36
158.9546204	2.35
177.0577393	1.18
195.0722961	100.00
196.0836182	0.13
197.0192719	0.08
223.1720734	0.08
231.8958130	0.16
248.5405884	0.04
259.2434082	0.02
293.0279541	0.04
299.2641907	0.03
312.8649902	0.19
328.0199280	0.05
330.3136597	0.25
331.0459595	3.21
338.0889893	0.08
338.9281921	0.08
344.8645020	0.71
368.3788147	0.04
374.6761475	0.03
384.9311523	0.03
393.1385803	0.76
411.1386414	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.4698
Annotation	Thalicoside A1
Peak:m/z	Relative Intensity
261.2648926	0.05
268.0989075	0.03
271.2866821	0.05
275.3928833	0.04
307.2329407	0.10
335.0861206	0.02
342.9708252	0.04
391.2572632	0.03
417.2609253	0.05
423.4819336	0.04
434.2727051	0.11
455.5040894	0.03
459.4271240	0.10
464.9447632	0.05
466.5452881	0.06
486.2223511	0.02
488.3189087	0.06
489.4721069	0.31
490.6765747	0.03
505.3524780	0.08
522.3952637	0.11
523.3469849	0.14
524.4682007	0.02
552.3192139	0.02
561.6803589	0.16
586.6290283	0.02
590.4303589	0.09
591.5559082	0.05
616.1939087	0.04
617.4181519	0.07
635.4882202	0.08
639.5481567	0.09
656.4362183	0.13
662.3798218	0.03
667.2117310	0.28
677.4503784	0.07
707.1530151	0.13
711.1228027	0.14
717.5527954	0.11
723.9488525	0.12
735.2670288	0.03
738.3636475	0.32
752.7894897	0.05
778.5816040	0.41
779.5620728	0.08
797.5128784	100.00
798.2070923	0.29
798.9086304	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	839.3354
Annotation	Unknow
Peak:m/z	Relative Intensity
239.3016052	0.03
254.2461090	0.02
270.3397522	0.03
280.4143677	0.06
286.4750671	0.06
311.2679443	0.11
321.4552612	0.02
323.4880676	0.07
355.3659668	0.03
358.3831177	0.04
359.2227783	0.01
361.4379272	0.01
375.2480164	0.07
377.3453979	0.07
400.2610474	0.13
401.3151245	0.12
404.4456787	0.06
418.2850342	0.13
419.4133911	0.37
429.5719604	0.03
432.6882324	0.14
433.6503906	0.14
444.3023682	0.33
445.4108887	0.33
446.5809326	0.44
447.4180908	0.07
476.4976196	1.53
477.3161011	1.91
478.2521362	0.03
488.5921631	0.04
496.2323608	0.02
497.5487671	0.17
498.4091187	0.31
499.4351807	0.02
500.3251953	0.01
502.5156250	0.08
505.3072510	0.04
513.8430176	0.08
514.5282593	0.02
521.1229248	0.01
523.5416870	0.16
524.5608521	0.20
528.7194824	0.04
530.2289429	0.03
539.3868408	0.07
540.2806396	0.32
541.6228638	3.01
542.3983154	5.85
543.4746704	0.54
544.8027954	0.03
557.9035034	0.79
558.6879883	0.10
559.4199829	0.03
560.1322632	0.07
563.2266235	0.03
566.2560425	0.33
567.5216675	0.45
568.4187012	0.90
569.3756714	0.13
570.1894531	0.07
573.4050903	2.51
574.3509521	8.37
575.4262085	0.46
583.4336548	1.97
584.4163208	7.57
585.5009155	0.82
586.2991333	1.37
587.3300171	0.05
588.3755493	0.07
598.0886230	0.12
599.4371948	0.34
600.4454956	1.04
601.4181519	9.83
602.3886108	38.17
603.3118286	1.46
604.0075684	0.01
609.1783447	0.22
610.4600220	0.62
611.3449707	0.05
615.5249023	1.72
616.2849731	5.21
617.3009033	2.84
618.3971558	7.28
619.4740601	0.07
627.2986450	0.76
628.4264526	3.83
629.3162842	0.25
633.3505249	6.00
634.4253540	27.23
635.4373169	0.32
640.5334473	0.04
642.3652954	0.38
643.5214233	0.01
645.4094849	1.86
646.4409180	9.40
647.4428711	0.48
650.5657349	0.08
651.4669800	0.33
652.6084595	0.18
656.3132935	0.10
657.3635254	0.05
658.4598999	0.30
659.3506470	1.41
660.3616333	5.21
667.6619263	0.03
668.5426636	0.02
669.1981201	0.03
670.4979858	0.30
672.3005981	0.05
677.5307617	5.49
678.3463745	17.76
679.5008545	0.36
682.0974121	0.07
682.7383423	0.22
683.4542847	1.23
687.3886108	0.11
688.4077759	0.72
702.2457275	0.31
712.3858643	0.04
714.1489868	0.12
720.3891602	0.12
726.4977417	0.18
730.6644287	0.03
736.7261353	0.03
747.2878418	1.64
748.3925171	14.21
749.5419312	0.61
762.8267822	0.11
764.5289307	0.38
780.2914429	36.81
781.5227661	1.27
782.4265747	0.03
789.3602905	0.32
790.4509888	6.75
791.5780640	0.46
796.6896362	0.26
798.4697266	0.25
804.7026978	0.07
806.3045654	0.03
808.3699951	100.00
809.4993286	3.04
820.6111450	1.02
822.2975464	9.41
823.5684814	0.33
841.4570923	40.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1036
Annotation	Mollugoside
Peak:m/z	Relative Intensity
119.0435028	0.12
120.9931641	0.68
122.0602264	1.80
122.9772949	2.77
124.1961746	1.00
130.8007202	0.30
133.0361328	3.27
134.0710144	1.17
135.0744171	1.62
135.9498596	1.03
137.0838623	0.32
138.9775085	0.34
144.8984375	0.50
146.9928284	0.78
149.0312195	1.46
150.9418640	24.20
151.9699097	52.52
152.9957275	12.38
154.0558167	0.57
156.6704712	0.08
159.1896667	0.25
160.0942841	0.29
161.0788422	1.08
162.4169312	1.25
163.1095276	20.20
164.0637207	1.97
164.9681549	0.67
165.9201355	0.04
174.0212097	0.88
174.9880981	4.77
177.0072784	8.40
179.0045471	16.58
180.0057068	1.90
181.1147766	0.52
182.1296387	0.09
183.1078339	0.14
186.9274597	1.68
189.0881958	0.80
191.2835083	0.14
193.0708008	2.00
193.9532166	0.71
195.0697937	0.45
201.1522522	0.24
202.6242981	0.40
205.1063843	2.38
207.0330658	7.76
208.0390778	0.63
209.2476959	0.06
219.0962830	5.53
220.2303009	0.31
220.9578247	0.04
223.0627747	2.96
224.2637329	1.35
225.1142731	2.81
226.1065979	0.07
231.9891968	0.06
233.2170410	0.05
235.3636169	0.13
237.1623230	0.09
238.0506592	0.23
241.0835571	100.00
242.1278687	9.58
243.1872559	0.13
249.2609253	0.27
254.1380310	0.12
254.9347534	0.15
261.1720581	0.30
262.9124451	0.16
267.0986633	10.17
268.1663208	0.58
268.9225464	0.06
281.2169495	0.70
282.0925293	0.20
282.8773804	0.57
285.0932617	36.50
286.1654053	6.02
287.0644226	0.21
288.1647339	0.12
294.6399231	0.09
300.2266846	0.10
300.8281860	0.09
303.0016479	0.13
327.1557617	0.92
328.0850830	0.07
329.1900024	0.66
346.4288025	0.15
353.2573547	0.13
357.4465332	0.34
361.9430237	0.11
369.4140930	0.38
371.4317932	0.08
372.1374512	0.36
373.2037659	3.89
374.6164856	0.26
380.1210632	0.48
382.2651062	0.29
387.4636841	0.32
388.2152405	0.07
397.4133606	0.21
399.1452942	8.48
400.2804871	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	173.13
Annotation	3-Aminocaproic acid
Peak:m/z	Relative Intensity
66.9927368	0.07
70.0128250	0.06
76.8425140	0.08
78.8138123	0.09
80.9760818	0.13
82.8234558	0.09
85.9763641	0.12
95.0927429	0.13
95.8929596	0.12
97.0602875	0.08
97.8665771	0.02
98.9390717	0.08
100.7104340	0.07
106.9447632	0.04
109.2474976	0.03
111.8529205	0.03
112.4758148	0.11
113.9810944	0.17
115.0636597	0.17
116.3886566	0.19
117.0641022	0.23
119.0087738	0.13
122.0138550	0.03
126.1219025	0.16
126.9204865	1.56
128.0075836	0.85
129.1049347	0.68
130.2328796	0.37
131.8132782	100.00
137.0361176	0.11
142.6282196	0.87
144.9357300	1.77
147.9786530	0.08
149.8363190	3.95
152.2413025	0.73
153.4751892	0.03
154.9079742	5.81
155.9774170	0.20
157.0500946	0.15
160.9534607	0.35
163.9032440	0.78
173.0257568	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9306030	5.81
115.9869461	1.45
116.9689789	2.73
130.8366852	0.34
132.9104919	0.14
158.9307709	100.00
159.9400940	48.30
160.9068298	64.30
173.9383240	0.06
190.0347748	0.06
198.9504089	0.29
199.9989014	1.19
201.0130310	3.31
203.1060791	0.12
217.0376282	0.09
217.9757080	0.73
219.0109863	1.64
229.1007690	2.33
229.9614258	20.76
230.9065552	31.85
245.9471436	0.56
247.0034790	0.46
255.9788513	0.04
257.1499634	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.11
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8606567	0.19
118.9795685	0.24
123.0165787	0.44
124.8711472	0.07
129.0116272	4.13
130.9932251	0.28
134.0942688	0.27
140.9245148	2.08
143.0289612	0.14
148.8999176	0.14
158.9449768	2.16
161.0808258	0.77
162.9682312	0.89
175.0932007	2.97
176.8808746	1.58
177.9508362	0.11
179.0782928	0.72
183.0901337	0.11
193.0635529	0.87
194.9622498	100.00
196.8944855	0.05
213.1635284	0.86
221.0883179	0.18
234.9878540	0.37
237.1262817	0.10
272.9492188	16.47
275.0220947	0.15
280.1007080	0.06
291.1329346	1.00
303.0495605	2.81
321.2693176	5.64
325.1191406	1.07
328.0580444	0.16
339.0788574	0.73
351.0158997	0.21
352.9890442	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8917084	4.13
296.1611938	2.72
296.8521118	45.79
302.7688599	0.08
324.9401245	0.15
344.9341431	0.09
374.6806641	0.11
378.4736938	0.20
380.6400146	100.00
381.4647827	0.38
386.8917236	1.49
404.2877197	0.17
424.7312012	0.10
429.0891724	0.55
441.1488037	0.16
458.5546265	0.57
461.7937012	0.11
464.0674438	12.49
464.7176514	48.70
488.5858765	0.30
514.8347168	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	879.44
Annotation	Saundersioside C
Peak:m/z	Relative Intensity
513.4515381	0.03
717.9657593	0.03
742.4052734	0.02
817.4609985	0.06
819.6889038	0.05
834.5509033	0.04
835.3252563	0.04
836.6001587	0.08
837.5993042	0.07
842.4124756	0.04
861.4188843	0.08
879.5776367	100.00
880.2590332	0.17
884.2500610	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.385
Annotation	Stevioside
Peak:m/z	Relative Intensity
292.1826782	5.12
308.2151794	3.10
495.3168945	18.63
559.5998535	11.45
561.7530518	6.76
606.6178589	4.10
742.5891724	11.73
774.5308228	6.77
784.4697876	1.88
803.4063721	100.00
804.4746704	6.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2342
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9534149	0.04
163.0267487	0.14
164.1496887	0.08
165.0561829	0.11
166.9097748	0.08
177.0792236	0.06
181.1208496	2.41
182.3200989	0.73
183.0544891	2.89
184.2629395	0.06
192.2718811	0.07
195.0395966	0.06
197.0207062	0.06
199.2149353	3.59
200.0153351	0.53
200.6389771	0.03
205.1933594	0.17
207.2524872	0.74
210.2119141	0.03
213.1152191	0.05
223.0579987	0.10
225.0745544	2.58
226.0205078	0.43
228.0511932	0.28
239.1728973	0.29
240.3527069	0.14
243.0936584	100.00
244.1256866	14.57
249.1628265	0.52
251.2780304	0.08
255.2086029	0.17
267.0134277	0.38
279.0784912	0.17
285.0672607	2.11
289.1721802	0.23
290.2278442	0.18
291.0528564	0.06
296.1336060	0.05
300.8365784	0.08
307.2647705	0.10
315.3434448	0.12
327.1083374	0.25
331.4667969	0.07
344.2454834	0.19
367.5968628	0.18
369.0791016	0.15
372.2005005	0.07
373.1185303	0.12
385.2003784	0.21
389.1954956	0.29
390.2785645	0.12
401.0544434	0.17
412.5643311	0.06
423.2161255	0.21
429.7450562	0.20
432.3599854	0.05
434.1795654	0.07
441.5727539	0.17
448.9990234	0.06
461.5789185	0.06
462.4323730	0.04
470.5023804	0.19
471.2006836	0.08
472.5257568	0.13
478.1401978	0.11
488.1124268	0.42
491.1803589	0.98
492.0235596	0.78
504.0034790	0.23
506.1895752	0.05
507.3978271	0.90
508.2551880	1.10
514.3453979	0.05
515.0908813	0.27
516.2716675	0.78
529.3889160	0.25
530.4321899	0.42
532.2670288	0.10
533.3078613	0.77
534.2875366	1.18
537.5638428	0.11
552.5952759	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	215.02
Annotation	Allantoic acid
Peak:m/z	Relative Intensity
83.7993622	0.03
98.7802734	100.00
154.8823090	18.06
157.8628998	0.15
168.8415527	0.08
170.1937561	0.09
171.8819122	2.78
182.7966309	0.08
197.0480957	0.10
198.1880951	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	831.4304
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
281.5128784	0.06
443.5195312	0.15
633.1450195	0.08
769.6654053	0.06
777.7962646	0.76
795.5338135	100.00
796.5208130	1.20
813.6411743	0.19
831.4780884	2.11
832.5075073	25.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Galactonolactone
Peak:m/z	Relative Intensity
70.9112854	0.03
85.1179199	0.06
86.8866272	0.02
90.0460968	0.02
99.0350037	0.02
111.0009308	0.34
117.1413269	0.02
124.9993134	0.25
128.9586792	1.75
133.7989655	0.02
134.9453430	0.03
140.9664764	0.07
142.9430389	0.03
147.1231842	0.07
158.9479218	17.61
160.2609711	0.04
174.8114929	0.04
176.9341278	100.00
184.6991730	0.01
194.1508331	0.01
204.9786224	1.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2758
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
142.0849304	0.12
142.8112183	0.08
144.9943848	0.14
146.9847565	0.58
149.0364532	0.49
153.2782288	0.04
154.9691772	1.56
156.9258118	0.13
158.0888672	0.17
159.0521240	1.06
160.9876404	1.09
162.1198730	0.18
162.9438477	0.31
165.2400513	0.16
167.1558838	0.38
173.0508728	1.04
176.8239899	0.45
177.4383545	0.04
179.2616272	0.12
181.0211182	0.05
186.9457703	0.99
188.2555542	0.44
189.2302856	0.22
197.8563232	0.50
201.0144043	0.36
208.2729645	0.14
209.0675659	0.14
210.9335327	0.06
216.0129700	0.36
216.9935913	0.09
229.1122131	0.10
229.9291687	0.21
231.1486511	0.04
233.2056122	0.46
236.1705322	0.38
237.2290497	0.22
239.2662354	0.08
240.8612213	0.70
243.2832642	2.68
249.2961121	0.34
261.2304077	7.32
269.2112427	0.21
271.1822510	0.07
275.3571472	0.24
277.0591125	0.14
278.0232239	0.11
284.9140930	0.20
289.3537598	0.08
292.9365845	0.23
298.1495056	0.09
299.2360840	0.09
300.0571594	0.14
302.1855774	0.12
303.6885986	1.02
304.4331665	2.68
305.3164062	0.10
307.4349976	0.20
312.6290588	0.41
313.5680237	0.13
314.4316406	0.15
317.4708862	0.95
319.2495117	0.18
330.9876099	0.40
335.2794189	82.23
335.9219971	0.19
341.3085938	0.13
355.3906250	0.19
356.4430237	0.32
357.6286316	0.12
359.2992554	0.09
371.4979248	0.37
375.3520508	0.38
378.5216370	1.04
383.6256409	0.50
386.4450989	0.13
387.4422302	0.41
388.9185181	0.13
395.0071716	0.26
401.7723389	0.07
402.4479675	0.05
415.2621460	17.06
416.0909729	0.26
417.8729248	0.17
426.3475342	0.27
429.5184021	0.08
431.4816284	0.14
433.0988464	1.30
435.5171814	0.08
440.3055115	0.58
444.8276062	0.13
447.3638306	0.20
448.4891663	0.31
458.2056580	100.00
458.9836731	0.94
459.6813660	0.05
474.1946106	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9099426	2.93
232.0253143	0.11
251.0200043	0.31
290.8259277	19.18
338.8585205	0.07
368.8951416	0.14
373.9097900	0.29
374.7117920	6.29
375.4284058	0.11
418.8289185	0.88
434.2086792	0.06
436.7410278	0.48
451.9509277	0.04
456.7526855	0.13
458.6265869	62.69
460.7714844	3.19
478.7793579	0.10
482.7420654	0.56
490.5687866	1.01
491.1842651	0.07
496.7331543	0.20
506.9015503	0.06
518.4131470	0.16
519.4859619	0.04
520.6753540	4.89
542.5663452	100.00
543.2996216	0.79
567.1491089	0.98
573.3602905	0.18
580.5368652	1.07
584.6931763	0.23
585.4262085	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.133
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
105.9300690	0.01
108.0142136	2.85
121.8719177	0.01
122.8136597	0.07
123.9349899	0.19
127.1206818	0.05
133.9580994	0.51
135.9480591	2.20
137.9107819	0.04
152.0172729	7.84
153.0523071	0.03
153.9647827	0.28
161.9640808	0.05
164.0369263	0.02
169.9744568	7.50
194.0456238	0.02
216.3446045	0.03
218.1379089	0.03
230.1527100	0.04
236.3020020	0.03
241.7918701	0.01
242.9385376	0.08
245.9299316	0.03
247.9804077	0.04
254.9774170	0.05
270.1594238	0.03
296.0476685	0.20
296.6950378	0.03
314.2232056	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	484.2293
Annotation	Unknow
Peak:m/z	Relative Intensity
145.2102966	0.09
146.9680328	0.03
161.8713531	0.05
163.1781769	0.36
166.0823364	0.58
167.8959656	0.08
171.0208588	0.04
173.1700745	0.05
175.0939484	0.09
177.0839386	0.19
183.9504089	75.73
185.0712585	4.93
191.1298523	0.08
196.9969482	0.07
199.0477295	0.06
209.1244812	0.11
209.9571838	0.30
211.1938324	0.17
222.0464935	0.87
224.1751404	0.03
225.8699188	0.71
227.0212402	0.17
231.4533844	0.08
235.9771729	0.08
238.1083679	0.52
239.1262360	0.43
240.0900421	0.26
247.0176849	0.02
252.9853516	0.09
256.3350220	0.17
258.0722961	1.66
259.1930542	0.08
264.4844971	0.04
266.1160583	0.08
267.1224976	0.18
271.1948853	0.07
275.3515625	0.05
280.1819763	0.03
281.0426941	0.89
282.0201111	0.11
282.9539185	0.06
284.0568542	0.04
286.1871643	0.03
287.2636414	0.05
294.1984253	0.45
295.1473389	0.15
296.2164307	0.04
297.2627563	0.04
299.1562500	4.73
300.0593567	0.36
301.3046570	0.43
302.2094727	0.02
308.2307129	0.33
309.3105469	0.43
310.3289490	0.06
312.2225647	2.47
313.2843018	0.73
319.1072693	0.06
321.0475159	0.12
322.0342712	0.05
323.0420837	0.60
324.0751953	0.06
325.5123901	0.05
326.1835327	0.69
327.1338196	0.32
328.1017151	0.17
331.2192383	0.11
333.1760254	0.09
335.3033447	0.06
336.8558655	0.13
337.9667358	0.06
340.4068909	0.92
341.2351685	0.21
350.4505005	0.05
351.2276611	0.06
352.3986511	0.10
353.0539551	0.06
354.2626038	0.11
363.0762634	0.08
365.1220703	0.87
366.2971497	0.58
367.3712158	0.16
368.2828979	0.51
369.0792236	0.08
370.1196289	0.04
377.3435364	0.07
379.8932800	0.08
380.5071411	0.16
382.4816589	1.13
383.2530823	1.85
384.2113342	0.82
385.4675598	0.13
389.4162903	0.07
390.3652039	0.42
391.2169800	0.09
393.8380432	0.57
394.6889038	0.14
395.3474426	0.20
396.2988281	0.16
398.2039490	0.05
403.2406616	1.00
404.4200439	0.62
405.2288208	0.18
406.1425781	1.46
407.2528992	0.87
408.2699280	0.74
409.3271179	0.06
411.9732666	0.36
420.2032166	0.42
421.3742676	1.57
422.3975525	0.68
424.3043518	0.30
427.3704224	0.03
431.1222839	0.33
431.7657166	0.03
432.4630432	0.07
438.4412231	0.22
439.3977661	0.06
445.9905396	0.04
449.2871704	3.06
450.3572693	1.27
453.4978943	0.04
457.4461975	0.03
461.4039612	0.02
462.9104919	0.10
464.6637268	0.17
466.2688599	100.00
467.2897034	28.46
468.3067017	0.41
473.0244446	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.76
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9208527	1.29
257.0191650	0.01
277.4145203	0.04
290.1264343	0.03
299.0287170	0.07
300.8402100	0.23
302.9057922	33.86
308.7811890	0.29
310.8200684	0.21
333.3110657	0.02
335.4512939	0.02
350.0294800	0.02
372.5585938	0.01
373.2666016	0.03
380.3783264	0.08
381.1731262	0.14
383.4573059	0.02
384.1884460	0.03
386.8045044	100.00
393.4653320	0.02
424.9734192	0.07
435.3163147	0.01
452.3975525	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.1917
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
113.0276794	0.14
136.9475403	0.47
139.0554199	0.02
147.8946228	0.02
153.1098022	0.02
155.0145264	0.04
173.0871582	0.03
179.0618896	0.02
191.2699890	0.15
219.2389832	0.08
221.3429565	0.02
223.3378296	0.05
229.3573303	0.12
231.0339050	0.03
233.2391357	0.21
235.3359070	0.17
239.2654114	0.02
241.2279968	0.06
243.0377197	0.11
245.3228760	0.42
247.2274170	0.07
255.2287903	0.11
257.2914124	0.74
259.2008972	0.21
261.3086243	0.16
263.2031250	0.29
273.1604919	0.61
275.2343140	1.32
279.3350830	0.08
283.2789917	0.03
285.0634766	0.02
289.2816162	0.15
291.2786560	1.09
293.2490845	0.75
301.1682739	0.09
303.3502502	0.05
305.1900024	0.08
307.4739990	0.02
309.2882385	0.78
315.3718262	0.02
317.1266785	0.08
319.2941284	0.99
335.2929993	1.92
337.2430420	100.00
338.4257202	0.07
339.2025757	0.09
345.1368408	0.17
363.3451843	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3973
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
330.8535461	5.61
692.8765869	16.63
821.3960571	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8544388	0.28
206.7864227	5.01
212.7928162	1.84
254.9742737	1.28
266.8801880	0.54
284.9679871	0.55
290.7504578	100.00
301.1170044	0.02
310.8120117	0.06
314.8892822	1.21
328.9636230	0.03
338.7190247	0.12
356.9196472	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.99
Annotation	Unknow
Peak:m/z	Relative Intensity
104.8442230	0.15
122.8470001	100.00
139.9931335	0.33
140.8915100	0.38
147.0484619	0.18
151.7467346	0.71
156.1117249	0.29
159.0173798	0.43
172.0113220	0.55
174.9104767	2.50
179.1910095	0.28
179.9723511	0.35
186.8895111	0.12
199.2001343	0.38
204.8296814	0.21
208.7882690	0.18
212.8334961	46.89
214.6795654	2.43
217.1713257	1.89
217.9712219	0.29
219.0401917	0.21
238.3594971	0.53
257.1331787	0.15
258.8396606	0.49
273.0868530	0.31
284.9187622	1.86
296.8508301	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.03
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9128876	1.35
159.1823730	0.24
176.9832153	0.35
192.8348389	0.05
194.9931335	100.00
195.7572632	0.03
242.2029114	0.34
243.2792053	0.17
258.3302612	0.07
274.8470459	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	275.0173
Annotation	6-Phospho-D-gluconate
Peak:m/z	Relative Intensity
78.8236618	8.41
96.8860855	100.00
97.6431274	0.10
102.0744019	0.03
115.3302155	0.23
119.8708420	0.11
128.0370789	1.28
128.8606262	0.04
131.0841980	0.05
140.1557159	0.09
144.9313660	0.11
145.9644470	2.07
157.9649506	0.04
172.9168854	0.32
173.8458405	0.14
177.0727081	0.06
203.2619019	0.08
206.9996338	0.07
213.1436768	0.06
231.3031311	0.14
239.0756836	1.46
244.2965698	0.10
257.1449280	4.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.2053
Annotation	Cinncassiol A
Peak:m/z	Relative Intensity
132.1698303	0.02
134.9941406	0.01
137.1240540	0.01
146.9053345	0.09
149.1576843	0.03
153.0379028	0.05
162.9140930	0.09
164.0095673	0.02
165.0368805	0.24
167.0629578	0.05
182.8377380	0.07
190.4657593	0.03
208.8438416	0.03
210.9199829	0.32
219.0092010	0.02
227.2875671	0.02
235.2351074	0.02
239.1696167	0.17
249.2857666	0.04
255.2517700	0.08
257.1363831	0.29
258.1775208	0.01
261.2078552	1.02
264.9839478	0.08
268.9578552	0.04
273.3140564	0.04
279.4348145	0.02
283.2747192	0.73
285.3233643	0.26
291.3904114	0.05
293.2145386	0.12
295.2576294	0.07
301.2364807	0.90
303.4159546	0.08
311.1888428	4.78
313.0962524	0.02
317.2291565	0.11
319.2220459	3.59
323.0761108	0.05
325.4765625	0.03
326.8737183	0.04
329.1982422	6.43
334.3734131	0.09
337.2243347	5.41
338.1378479	0.27
340.2352905	0.02
342.0090332	0.04
347.1385193	28.15
347.7660217	0.07
352.6199951	0.04
363.1690674	0.04
365.1358337	100.00
366.0732117	0.02
373.8252869	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
339.5394897	1.19
435.2025146	2.45
501.0565796	0.34
507.5935669	1.27
555.3947144	7.74
689.434082	0.73
715.3781128	1.46
759.1924438	6.64
802.6369019	5.86
803.3433228	100.00
804.1931763	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	574.2438
Annotation	Unknow
Peak:m/z	Relative Intensity
166.8857880	0.39
168.1388855	0.40
170.9084473	0.32
171.8755646	0.06
177.1103821	0.87
178.9441681	2.06
179.9428101	0.12
185.0879822	0.10
185.9928894	0.28
192.2245636	0.27
196.8431091	0.13
205.2767334	0.10
209.9663391	2.29
211.2132416	0.10
212.8206482	0.29
228.3085938	0.06
235.9801636	0.16
239.1298218	0.16
242.2194519	0.29
244.3802490	0.24
249.4942627	0.22
254.1342468	7.53
255.2485352	1.56
262.1786499	0.05
272.0858765	8.81
273.1244507	1.01
288.1058960	4.69
289.2099609	0.73
295.2812500	0.37
306.1236572	100.00
307.1713257	12.94
325.2716675	0.11
337.3228760	0.14
340.0456543	0.14
341.2677612	0.07
342.0347290	0.12
348.2463379	0.24
350.9472046	0.41
353.2070312	0.71
361.1301880	0.30
371.1842651	0.18
381.0885620	0.13
382.1507568	0.09
383.2911987	0.17
385.2631836	0.06
389.2734985	0.12
393.0836182	0.25
397.3624878	0.10
407.3770752	0.04
409.1115723	0.09
413.1010742	0.28
417.3099365	0.13
431.6016235	0.09
445.1213379	0.12
446.2990723	0.28
455.4157715	0.03
457.6710205	0.22
460.4724121	0.17
471.5642090	0.21
478.2687988	0.19
484.7794800	0.13
489.2899170	0.10
499.3769531	0.21
502.4179077	0.10
505.4087524	0.14
507.5359497	0.25
512.3789062	6.31
513.4397583	1.53
515.6447754	0.26
525.2798462	0.20
528.1068115	0.28
528.9957275	0.13
531.1997681	1.04
541.9314575	0.10
546.8678589	0.18
552.6903076	0.42
555.5915527	1.70
556.2915649	4.19
557.2756348	3.94
559.4290161	0.27
576.5270386	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	562.28
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0711060	0.11
161.8759613	1.19
167.2717133	0.13
172.9798279	0.21
174.9336548	0.15
179.3715210	0.35
180.8963318	0.48
191.2605591	0.08
195.0284576	0.03
199.3574524	0.24
201.1032410	1.53
203.1845551	0.21
219.1509705	1.78
222.2377930	0.24
225.1416931	0.13
229.2892456	0.31
235.1104279	0.17
237.1848907	5.82
243.1408539	0.05
251.1655884	0.79
253.4570312	0.07
255.1108398	3.17
256.4458618	0.76
257.1121826	0.43
265.5610962	0.28
267.1922302	0.44
269.1583862	4.57
271.0739746	1.20
274.2785034	0.07
279.3587646	0.19
287.2221985	3.48
289.1674805	0.41
295.0769653	0.11
301.5392456	0.12
305.3344116	0.05
309.2109985	0.49
310.2243042	0.22
312.5134277	1.31
313.2815552	7.04
317.1462402	0.04
321.8814087	0.32
323.1272583	0.11
330.3452759	1.18
340.3395996	2.88
341.2753906	0.04
345.7992554	0.15
358.1186523	0.09
359.4088745	0.19
367.2847290	0.06
372.2595215	0.27
379.3997192	0.24
380.2579346	0.81
386.1298218	0.15
389.0635986	0.25
396.5000610	0.06
398.3232422	10.57
400.3807373	0.14
401.3801880	0.10
402.5739746	0.18
407.5003052	0.11
412.1206055	0.24
414.1129761	0.22
416.1907959	36.98
416.8598022	0.32
422.1219482	0.16
424.5746460	0.05
433.2611694	100.00
440.7802734	0.26
441.5191040	0.47
446.4985962	0.11
448.5612793	0.09
451.4127808	0.38
452.2170410	0.13
469.3668213	0.16
474.5659790	0.08
479.4973145	0.23
481.3269043	0.05
483.9698486	0.14
487.3266602	15.03
499.1405640	0.38
511.7416992	0.33
515.2938843	0.29
516.2585449	0.09
517.3595581	0.99
519.7366333	0.23
522.6782227	0.11
525.6232300	0.18
526.2476196	0.47
544.3936157	5.73
545.2035522	0.18
564.4970093	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0764
Annotation	Glutathione
Peak:m/z	Relative Intensity
86.9537430	0.04
98.9234314	0.27
99.9452210	0.07
115.9284515	0.14
119.9439697	0.09
124.8850861	0.13
125.9561005	0.20
126.9221878	0.37
127.9229507	11.67
130.1129150	0.31
141.0175781	0.39
142.9750977	14.13
145.8073425	1.37
149.2494507	0.08
153.0617676	0.27
154.9568481	0.13
160.0060425	13.02
165.0573730	0.05
166.1414795	0.47
167.1199188	1.54
169.0101471	0.12
170.9741974	2.41
176.9695435	6.32
179.0726318	14.25
182.0758057	0.04
183.1502075	0.04
185.0628967	1.63
192.1884155	0.15
195.1784210	0.13
197.0566101	1.71
199.6173401	0.04
203.2614136	0.08
210.0875549	9.49
213.0432434	2.46
214.9309692	0.03
218.0395813	0.08
224.0247498	0.16
226.2262878	0.10
228.1577148	1.29
231.0822449	1.61
236.1101990	0.87
242.1816406	1.26
244.2204285	0.13
249.1938782	0.20
254.1481628	100.00
260.1222229	0.13
263.0982056	0.06
272.1099548	83.84
285.9118042	0.12
288.0773315	45.52
288.9613647	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	879.44
Annotation	Neoviridogrisein I
Peak:m/z	Relative Intensity
633.4356079	0.14
634.6314697	0.05
673.6200562	0.02
676.7184448	0.22
714.6452026	0.03
717.7341919	0.05
718.7272339	0.22
729.6376343	0.07
732.5292358	0.02
758.4579468	0.02
763.0253296	0.06
770.3293457	0.06
774.5751953	0.02
782.5776367	0.15
784.6217041	0.02
792.7552490	0.15
794.5905762	0.03
800.6671753	0.21
812.6311646	0.04
818.3845825	0.08
819.6513062	0.02
824.9954834	0.07
834.8137817	0.14
836.6529541	0.20
837.7522583	0.05
842.2619629	0.01
843.0750732	0.03
861.0454102	0.10
862.1029053	0.03
878.4002075	1.69
879.6135864	100.00
880.2926025	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.278
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
134.9697723	0.02
139.9588776	0.12
141.1359863	0.02
153.0211182	0.18
166.1138153	0.04
171.0625153	0.00
196.0741577	2.26
197.1365662	0.08
214.1085968	1.66
215.1591187	0.03
237.1540222	0.01
255.2315674	100.00
256.2350159	16.22
284.2721558	0.01
391.2800598	0.41
392.0231628	0.04
407.3465271	0.15
409.4795837	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3848
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
311.5071411	3.57
555.4267578	17.17
575.5009155	8.17
803.3754272	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1505
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
149.0845184	0.04
161.2625275	0.07
187.2676086	0.01
217.1904297	0.04
219.2419128	0.01
239.2261658	0.01
251.3552246	0.02
267.2086182	0.03
268.2538452	0.03
269.1734314	0.15
275.3909912	0.04
277.0781555	0.02
305.9191895	0.02
326.1397705	0.06
401.2165222	100.00
401.8514099	0.19
428.3907776	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.4584
Annotation	Aquilegioside F
Peak:m/z	Relative Intensity
340.2539368	0.02
426.7753296	0.12
483.5040283	0.16
525.7814941	0.04
580.4899902	0.11
584.6588135	0.06
616.7594604	0.10
619.5480347	0.05
634.7879028	0.10
635.6074829	0.02
636.5964966	0.22
638.7377930	0.40
647.5173950	0.09
664.8287354	0.04
670.2469482	0.04
681.6887817	0.13
698.5199585	0.29
722.7462769	0.18
750.5925903	0.09
766.5297852	0.03
770.5526123	0.02
778.4700317	0.09
780.5380249	0.08
782.6766968	2.24
796.4768677	100.00
797.2548828	0.38
800.5987549	2.84
801.7666626	0.02
821.5106201	0.04
822.6768799	0.54
842.2150269	0.82
843.5957642	1.90
844.4780884	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
177.1548157	0.19
184.1233826	0.05
185.3819122	0.15
189.1374359	0.07
199.2127533	0.12
201.0505066	0.12
204.9788666	0.28
207.0476685	0.10
209.0232544	0.91
211.0135193	1.83
211.8790894	0.40
215.0768433	0.08
225.0931396	0.20
228.2981262	0.06
230.9853668	2.00
235.0814972	1.55
262.0913696	0.30
269.3402100	0.07
271.7131958	0.11
273.9179077	0.03
288.2137451	0.09
290.2538757	0.16
298.2205200	0.56
303.0272827	0.09
305.1008301	0.05
320.2264099	0.43
322.1296387	0.32
326.4824829	0.22
327.5351562	0.17
337.0375366	1.05
338.3465576	0.09
340.2100220	0.37
343.2362671	0.08
344.1622314	0.07
345.9913940	0.06
348.2432251	0.18
355.1195068	100.00
366.0809326	0.16
380.8631592	0.05
382.2833252	0.14
390.9278564	0.04
409.1533813	4.85
409.7679443	0.08
411.2917480	0.08
417.1680298	0.07
421.1062622	0.12
423.3863525	0.11
430.9280396	0.07
432.2031860	0.11
439.5847778	0.07
444.2064819	0.13
452.8638916	0.14
459.1148682	0.04
462.7765503	0.21
466.2707520	7.09
467.0871582	0.02
476.2680054	0.27
479.8082886	0.39
480.4128418	1.93
481.4736938	0.46
484.2344360	69.75
489.8281860	0.47
509.1845703	0.12
520.1569214	0.04
522.3338623	0.32
523.1596069	0.06
538.2641602	4.92
558.4002075	0.16
569.0687866	0.25
577.3759155	0.33
593.4473267	0.05
594.1106567	0.41
595.2371216	20.86
596.4722900	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	260.0234
Annotation	2-methoxyacetaminophen sulfate
Peak:m/z	Relative Intensity
78.9000244	0.16
79.8719788	0.72
80.8205719	0.18
96.9962463	0.65
119.0832214	2.03
126.9066925	0.06
130.7546082	0.20
133.9121399	0.21
136.2003021	0.10
163.2195282	0.43
168.9615479	0.33
171.9312134	0.08
174.1161652	0.07
177.9286652	0.09
180.0966034	13.17
184.9684601	0.07
185.9835205	3.10
187.1451569	0.97
197.0797424	0.16
199.0363007	100.00
200.1001129	0.34
213.1940002	0.07
214.9318695	27.37
216.0093231	0.30
229.1117554	0.15
232.1470490	0.48
239.2777252	0.15
240.0252838	0.05
240.9690704	0.32
242.8945160	6.14
243.5095978	0.04
260.2086792	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.4136
Annotation	Mezzettiaside 2
Peak:m/z	Relative Intensity
415.4703979	0.02
425.6224976	0.10
513.7319336	0.22
633.4983521	0.04
663.8723145	0.04
672.5422974	0.05
715.7805786	0.07
729.6509399	0.09
745.5656738	0.14
755.5737915	0.12
756.2307739	0.08
773.5805054	2.37
774.6906128	0.04
789.4677734	0.05
791.5203247	1.15
815.5219727	0.15
816.4353027	0.07
834.5438843	100.00
835.2592163	0.19
835.8848877	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	850.1273
Annotation	Unknow
Peak:m/z	Relative Intensity
254.3558655	0.71
303.3291626	1.45
307.0028992	1.06
310.0101013	0.71
325.4283447	0.84
339.0205078	0.14
342.2090759	0.20
363.1818237	0.28
368.7938843	0.11
390.3245850	0.36
400.2484741	7.28
401.3316650	0.65
407.2349243	0.43
416.2286987	0.17
425.4857788	0.42
427.2567139	0.37
428.3080444	0.19
438.4827881	0.55
442.2965698	0.34
455.4868164	0.96
472.2743530	0.41
500.4650269	0.23
501.2554321	0.12
505.6437378	0.16
513.4415894	3.82
514.3619385	0.39
515.7278442	0.43
519.1143188	0.27
520.7014160	1.16
525.9020996	0.53
538.6046753	0.38
539.8186035	0.48
541.1701660	0.72
550.5180054	0.57
561.7131348	0.12
567.1172485	0.14
569.1359253	2.08
578.5374756	0.17
587.1329346	0.61
597.4775391	0.37
602.1212769	0.49
611.9409180	0.15
623.3870850	0.33
624.5106812	1.49
626.6853638	1.05
627.4971313	0.42
635.4878540	0.59
637.3722534	0.18
642.4468994	3.45
643.6715698	0.58
655.1044922	0.59
665.1723022	0.34
674.6030884	0.30
682.5067749	0.80
683.1113892	3.19
688.4523926	0.15
691.2466431	0.97
695.5142822	0.27
696.8991089	2.26
710.6459351	0.08
711.3216553	0.36
727.6442871	0.14
738.1737061	0.39
741.6418457	2.90
742.5613403	1.92
747.2239380	0.60
748.8059082	0.16
750.6524048	0.12
759.9122925	0.60
765.7769165	0.56
769.1163940	0.18
769.7510376	0.08
778.6110229	0.18
786.3340454	0.10
792.8218384	0.13
796.1019287	0.61
797.5600586	0.94
799.9614258	0.13
802.7507935	0.82
804.7235718	1.43
805.6497803	0.44
806.5230103	0.28
809.3825073	0.74
810.3562012	0.45
811.8023071	0.75
813.1995850	0.35
814.1098633	0.19
816.5761108	1.15
818.6375122	0.25
819.4602661	0.44
824.9765625	3.29
825.9069214	4.36
827.8412476	0.50
828.9094849	0.40
832.7046509	2.25
833.7313843	0.87
835.1965332	0.68
837.5421753	0.43
851.5356445	0.94
856.2755127	0.31
869.0126343	0.56
874.7658081	0.87
882.0624390	0.57
887.4655151	0.20
888.8830566	0.08
893.6930542	0.17
895.5909424	1.60
896.4028320	3.21
897.6954346	0.84
898.3551025	0.29
900.3130493	0.32
901.2990723	0.39
904.5459595	2.66
905.2722778	3.93
908.5563354	0.09
909.6265259	0.09
911.9989624	0.11
923.5747070	0.28
924.6571655	0.38
925.6270142	0.34
932.0436401	0.31
933.8281250	0.18
935.0499878	1.23
935.7872925	0.07
936.4657593	1.22
937.2980957	0.91
937.9516602	0.16
938.6375122	0.25
940.9974976	0.51
941.6425781	0.52
942.6729126	0.59
945.2883301	1.38
946.6765137	1.29
954.2751465	7.22
954.9324341	1.08
959.7013550	0.27
961.7712402	0.70
962.4421997	0.95
963.3593140	0.97
968.7173462	1.28
969.6298218	0.31
972.7166138	0.17
979.7258911	0.17
982.0098267	0.21
985.7954102	0.69
996.6677856	0.48
1000.3884890	0.53
1001.2739260	0.74
1005.4251100	1.19
1010.2564090	1.88
1010.9089970	1.42
1018.9539180	9.58
1019.7183230	1.17
1021.1448360	0.37
1022.6399540	0.21
1024.0466310	0.61
1024.8452150	0.28
1025.6898190	0.12
1026.4785160	0.11
1037.5740970	0.32
1044.9058840	0.26
1052.7368160	0.82
1056.8056640	0.46
1057.7868650	0.14
1058.7071530	1.05
1061.4844970	2.26
1062.6997070	0.23
1064.6280520	0.37
1066.4389650	4.66
1067.3913570	4.32
1068.3410640	0.18
1075.5583500	36.86
1076.3367920	5.55
1077.1055910	0.17
1078.0139160	0.18
1081.2666020	0.09
1081.9667970	0.12
1082.8656010	0.37
1093.8380130	0.99
1095.1271970	0.30
1110.7148440	0.15
1117.4692380	0.30
1118.3087160	0.34
1124.4312740	0.15
1126.9140620	0.68
1131.2156980	1.16
1136.3966060	0.44
1137.0888670	0.62
1137.6958010	0.33
1157.8269040	0.46
1161.6997070	1.86
1162.6748050	1.36
1165.9044190	0.38
1167.8924560	0.16
1182.4948730	0.33
1185.8026120	0.34
1186.6391600	0.32
1187.8767090	0.97
1188.5949710	1.81
1189.2023930	0.70
1194.5656740	0.46
1197.0622560	0.30
1223.1303710	0.42
1223.7879640	0.09
1228.6237790	1.10
1237.0510250	0.29
1237.9893800	0.41
1249.2651370	0.07
1250.4245610	0.29
1265.6486820	0.10
1299.5805660	0.30
1337.6917720	0.37
1366.5736080	0.21
1380.8820800	0.33
1382.9815670	0.22
1400.6629640	0.38
1403.0633540	0.32
1414.3016360	0.54
1418.2283940	0.12
1452.9270020	0.20
1453.5723880	0.08
1454.8446040	0.96
1467.2303470	0.16
1493.1375730	0.32
1494.9279790	0.12
1505.8955080	0.46
1523.9189450	0.43
1563.3892820	0.57
1576.6882320	0.59
1579.0915530	0.20
1595.4644780	0.15
1676.3889160	3.23
1680.6325680	0.61
1681.4315190	0.62
1706.1197510	0.34
1708.1428220	0.26
1794.1746830	0.31
1809.9564210	0.12
1834.5227050	0.30
1862.3201900	4.30
1865.5338130	0.12
1903.2467040	7.89
1908.7716060	0.17
1923.0002440	0.52
1933.3742680	2.22
1936.7458500	0.28
1952.4588620	100.00
1968.2757570	0.21
1981.2264400	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	983.45
Annotation	Licoricesaponin A3
Peak:m/z	Relative Intensity
454.8214722	0.03
471.2103882	0.09
472.3950806	0.03
495.5482483	0.05
513.8619385	0.08
514.6114502	0.02
537.4410400	0.07
538.5992432	0.17
555.6143188	0.02
561.6260376	0.02
568.3654785	0.02
584.4801025	0.07
591.4451904	0.02
592.2120361	0.03
619.2368164	0.03
626.5781250	0.03
644.3458862	0.49
657.7724609	0.95
658.5842285	0.97
674.3428955	0.03
675.2492676	0.10
676.2694092	0.19
684.4550781	0.05
699.5665894	0.40
700.5444336	1.45
711.5011597	0.02
712.5463257	0.07
717.6962891	0.56
718.5986328	2.12
728.8191528	0.30
730.7567139	0.31
734.5728760	0.13
735.4981689	0.09
736.5167847	0.21
741.4768066	0.27
742.5755005	0.07
745.2811279	0.16
746.3863525	0.77
754.5931396	0.04
756.3709106	0.04
758.0357666	0.05
758.7059326	0.14
764.1006470	0.07
770.0405273	0.05
771.3712158	0.03
772.7015381	0.14
787.1306152	0.04
788.4134521	0.33
794.1600342	0.04
794.8751221	0.02
796.4851074	0.10
800.5827637	0.14
806.7385254	0.03
817.8043213	0.33
818.4527588	0.88
830.4572754	0.25
836.3574219	0.14
841.7824707	0.02
860.3022461	0.46
877.5397949	0.39
878.3378906	2.58
879.0256348	0.05
896.8734131	0.02
898.4869385	0.04
904.4804688	0.08
921.7205811	1.28
922.4061279	1.66
939.7403564	2.13
940.4221191	1.73
942.4664307	0.34
952.6208496	0.03
963.5009766	0.08
966.4288330	0.36
982.6651611	0.06
984.2241211	100.00
985.3261719	0.87
985.9396973	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.4529
Annotation	Neoviridogrisein I
Peak:m/z	Relative Intensity
416.4700928	0.08
417.5184937	0.07
460.0584106	0.06
460.9702759	0.44
476.2468262	0.04
486.4756470	0.03
518.1175537	0.03
530.2095337	0.02
632.3021851	0.12
666.3600464	0.21
667.5232544	0.51
676.3815308	0.03
698.4081421	0.26
699.2789917	1.27
699.9276733	0.02
762.2728271	0.16
778.4724121	0.05
792.1769409	0.13
796.7849731	0.13
806.4078979	0.11
810.9586792	2.80
811.5647583	8.76
814.6317749	0.14
836.5513916	0.65
838.5121460	0.12
857.3706665	100.00
858.0952148	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1206.1184
Annotation	Unknow
Peak:m/z	Relative Intensity
790.7470703	0.03
850.6146240	0.11
891.8908691	0.01
965.3031006	0.06
985.9339600	0.06
988.3353271	0.02
994.0571289	0.04
1020.0607910	0.05
1037.5020750	0.12
1049.1960450	0.09
1051.9281010	0.02
1064.0314940	0.11
1071.3203120	0.07
1075.0932620	0.07
1077.3779300	0.01
1090.3718260	0.04
1091.7404790	0.17
1097.7597660	0.26
1100.8930660	0.03
1103.7856450	0.01
1109.6059570	0.28
1112.9528810	0.13
1118.7431640	0.16
1120.1958010	0.14
1121.3530270	0.12
1126.1674800	0.01
1131.3529050	0.04
1134.1175540	0.07
1135.7636720	0.08
1144.5363770	0.26
1146.1572270	0.01
1152.9542240	0.14
1161.7272950	0.17
1162.4086910	0.08
1172.5698240	0.06
1175.7211910	0.09
1179.9895020	0.07
1181.7294920	0.06
1183.0718990	0.08
1185.1474610	0.14
1186.2866210	0.09
1205.5837400	0.17
1206.5845950	8.75
1207.2368160	100.00
1208.3031010	1.09
1209.2678220	0.23
1210.2214360	0.25
1211.8165280	0.12
1213.9342040	0.06
1215.2562260	0.10
1216.3881840	0.05
1217.7062990	0.08
1220.8671880	0.05
1226.5422360	0.03
1252.3978270	0.08
1268.7978520	0.06
1283.1397710	0.02
1306.6087650	0.01
1307.8552250	0.05
1315.7294920	0.15
1331.5966800	0.11
1337.7332760	0.03
1355.7819820	0.02
1375.7323000	0.04
1399.5703120	0.09
1409.3829350	0.05
1444.8812260	0.01
1463.5151370	0.08
1482.2655030	0.02
1488.8565670	0.07
1546.5416260	0.01
1556.6527100	0.07
1564.8067630	0.03
1574.9882810	0.03
1575.5919190	0.07
1580.1192630	0.05
1582.1112060	0.01
1583.2039790	0.07
1584.3944090	0.07
1587.3509520	0.02
1590.1013180	0.05
1591.2642820	0.09
1592.8093260	0.11
1599.2984620	0.10
1605.3505860	0.03
1611.9364010	0.03
1624.6903080	0.02
1628.9561770	0.02
1655.3929440	0.04
1665.0925290	0.10
1668.9407960	0.02
1677.4281010	0.12
1679.2015380	0.03
1720.9808350	0.05
1746.6975100	0.04
1831.4499510	0.03
1852.9993900	0.09
1901.2775880	0.01
1913.2458500	0.02
1951.8791500	0.02
1977.8079830	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1632
Annotation	Unknow
Peak:m/z	Relative Intensity
133.9839783	0.76
135.9596710	0.20
139.1232605	0.11
156.0380096	0.05
162.9236145	6.23
180.0779572	100.00
191.1871033	0.36
195.2852020	0.09
208.9057617	0.07
221.1202393	0.16
243.4666138	0.14
245.1397705	0.18
260.3392944	0.47
264.9259644	1.15
266.0581970	0.42
280.6417847	0.07
283.2321777	0.14
303.5497437	0.04
309.2248230	0.06
310.2489624	0.31
313.4152222	0.16
316.1091614	0.65
324.2701416	0.12
330.0637207	0.08
331.0984497	0.07
335.3357544	0.28
343.8174744	0.20
351.0513916	0.05
372.1318665	0.27
384.1575012	0.25
385.1329041	0.07
389.3735046	0.67
400.2479248	1.25
401.1221313	1.70
402.9638977	0.21
428.3002014	0.11
429.1689758	1.00
430.1565247	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1932
Annotation	Physalin L
Peak:m/z	Relative Intensity
150.8012848	0.05
154.8429871	0.07
168.0450745	0.08
179.8677368	0.10
198.2331848	0.08
202.0620117	0.04
209.9806519	0.06
219.2747345	0.11
224.2413025	0.03
225.1691895	0.49
226.1249847	0.15
237.0915833	0.32
238.1794434	0.06
240.2724304	0.08
243.0994568	0.17
245.3365631	0.09
252.2763062	0.22
254.0546265	0.37
255.1929016	0.37
257.4067993	0.08
260.3592224	0.08
267.2639160	0.11
268.2954407	0.52
272.2261353	0.28
273.3990479	0.18
279.3408203	0.08
280.2035522	0.35
281.2413330	0.13
284.1327515	0.25
285.3055420	0.41
286.4357300	0.52
287.1218872	0.11
293.3200684	1.12
294.3408203	0.75
295.4891968	0.11
296.1810913	0.13
297.2980347	0.27
299.3769531	0.38
304.1411743	0.14
304.9625244	0.09
309.2444458	0.50
310.2396851	1.23
311.3104858	1.52
312.2686768	0.22
313.1781006	0.58
314.3618164	0.04
315.4685059	0.07
317.2000122	0.38
319.2783813	0.27
320.2029419	0.47
321.2919312	0.37
323.3171387	0.72
324.2542725	0.11
325.0739136	0.09
326.8874512	1.44
328.2799072	0.75
337.1430664	4.08
338.2853394	1.36
340.2061768	6.51
341.2888184	2.95
342.1660767	0.20
343.4978027	0.05
348.1605835	0.20
350.2579346	0.24
352.1514893	0.05
354.2080078	100.00
355.2074585	35.07
356.4799194	0.47
358.2499390	0.10
360.4769287	0.04
363.2390747	0.05
364.2435303	0.06
366.2436523	2.47
367.2918701	1.11
370.4555054	0.15
380.4687500	0.53
381.1287231	4.68
382.2655029	1.71
383.3139038	0.08
394.3449097	0.39
395.2754517	0.10
396.4821777	0.16
398.2222290	64.73
399.3304443	20.59
400.1932983	0.11
403.3805542	0.15
409.1495361	0.05
410.2698364	3.26
411.1784668	0.84
412.4875488	0.06
415.6934814	0.09
422.4155884	0.06
424.3067627	0.18
439.6135254	0.73
440.3764038	0.29
448.3947754	0.14
455.9700317	0.95
457.0483398	0.76
457.6947632	0.09
464.1829834	0.13
465.4457397	0.82
466.3434448	1.07
467.4725952	0.43
468.3545532	1.09
469.3594360	0.10
480.2253418	0.21
481.6618042	0.42
483.3121948	30.23
484.3607178	12.89
496.9205933	0.23
499.3571167	0.52
500.3777466	0.70
510.3179321	6.68
511.3736572	5.59
529.1416016	0.34
529.7928467	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1047.9495
Annotation	Unknow
Peak:m/z	Relative Intensity
807.4108887	0.16
918.0256348	0.23
961.1563721	0.17
964.7785645	0.18
969.5683594	0.02
971.3532715	0.44
973.2668457	0.14
977.9265137	0.50
984.3681641	0.38
993.9514160	0.31
995.4414062	0.41
1000.1279300	0.42
1000.7972410	0.03
1010.7779540	0.52
1013.1791990	0.91
1017.4458010	0.42
1018.8641360	0.61
1021.5728760	0.11
1027.6647950	0.40
1029.8133540	0.62
1048.5916750	100.00
1049.5070800	0.71
1050.4279790	0.16
1052.4372560	1.06
1053.9062500	0.14
1055.7448730	0.10
1057.6007080	0.04
1059.1193850	0.25
1081.2221680	0.07
1100.9162600	0.59
1105.2587890	0.18
1184.5485840	0.14
1197.7064210	0.31
1202.9671630	0.35
1207.5352780	0.18
1212.5878910	0.22
1233.5424800	0.66
1239.1677250	0.34
1240.0306400	0.46
1251.3535160	0.81
1257.6535640	1.03
1259.3996580	0.17
1264.0402830	0.42
1264.7321780	0.47
1266.8947750	0.12
1275.7449950	0.47
1278.8067630	0.17
1280.5234380	0.76
1285.5297850	0.22
1286.9714360	1.36
1290.6602780	0.85
1292.8759770	0.27
1296.8869630	0.24
1301.1451420	0.21
1302.9952390	0.96
1303.9251710	0.45
1305.0460210	0.20
1306.1379390	0.08
1309.7779540	1.05
1310.9605710	0.12
1312.4156490	0.43
1315.7189940	4.65
1317.0496830	0.42
1321.6651610	6.61
1322.7037350	0.27
1323.8531490	0.35
1324.5244140	0.51
1327.3635250	0.67
1333.0147710	0.79
1333.6196290	0.21
1334.3726810	0.20
1346.6160890	0.13
1347.6171880	0.19
1350.1774900	0.16
1351.4428710	0.59
1352.4063720	0.29
1353.4187010	0.47
1356.1375730	0.27
1359.4799800	0.45
1362.4434810	0.17
1387.4747310	0.15
1460.6949460	0.12
1492.7834470	0.10
1519.0898440	0.14
1549.7457280	0.11
1633.3016360	0.02
1708.0181880	0.04
1728.7396240	0.03
1747.8651120	0.07
1768.9704590	0.14
1771.7747800	0.12
1840.5692140	0.08
1859.6824950	0.07
1925.6213380	0.39
1930.8824460	0.04
1960.1776120	0.17
1974.8162840	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	512.2263
Annotation	N-Acetylpuromycin
Peak:m/z	Relative Intensity
152.9340820	0.02
165.4777222	0.18
186.1073914	0.06
195.0031586	0.05
209.1926270	0.80
210.2930908	0.02
217.9427338	0.07
223.2413483	0.13
227.1918488	0.39
241.1901855	0.57
242.2400818	0.04
243.2540283	0.12
263.2608032	0.07
279.3471680	0.07
291.0621033	0.07
294.2303467	0.10
302.1607666	0.07
309.8510132	0.08
311.2477417	0.08
315.3290405	0.14
319.4490356	0.07
333.0031738	0.04
337.2500610	0.05
350.3768921	0.02
353.3109741	0.08
358.2404175	0.03
363.3085938	0.16
376.3925781	0.09
381.2126465	0.96
396.0320435	0.11
397.3034058	0.59
407.2907104	0.33
415.3692017	0.16
420.1951294	0.03
422.6115112	0.09
434.3786011	0.04
436.6986084	0.11
437.7864990	0.09
448.1824951	0.23
449.4597168	0.18
452.2919922	100.00
453.2247925	0.96
464.3582764	0.10
465.2397461	0.26
466.3146973	5.35
467.5556030	0.03
477.3337402	0.03
480.4367065	0.03
482.0014038	0.11
491.4517212	0.02
493.3389893	0.25
494.2911987	0.12
495.4865723	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1819
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
125.6585236	0.03
131.0090637	0.01
134.1361084	0.05
135.1868439	0.02
136.2250214	0.03
149.9796448	0.01
161.1860199	0.03
167.0626984	0.04
180.2096863	0.02
183.3390045	0.02
185.1984558	0.03
193.0324249	0.09
194.2933350	0.03
196.7899933	0.03
204.2556610	0.03
213.1202087	0.08
230.2923126	0.03
240.8966370	0.06
246.9524841	0.03
249.1987000	0.21
250.1365051	0.04
255.1188354	0.05
265.3261719	0.12
267.2488403	0.03
267.9760742	0.01
285.1659851	0.02
293.3211670	0.02
306.2826233	0.02
313.4573364	0.01
314.5654907	0.02
325.5692139	0.01
330.2879333	0.05
332.1816711	0.03
335.3268738	0.01
336.2514343	0.02
337.4506531	0.05
340.1642456	0.01
347.4491577	0.02
349.2725220	0.06
355.2869873	0.02
366.1997375	0.08
367.3779602	0.01
370.3119507	0.06
381.2291565	100.00
382.2240295	14.16
383.3612671	0.06
387.3255005	0.01
388.7499695	0.02
391.4731140	0.09
392.2332153	0.01
394.5878296	0.06
398.2449951	0.06
399.8794250	0.01
401.3455505	0.02
407.4926758	0.03
408.3631897	0.02
410.2574158	1.02
411.4185181	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1394
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
82.9164734	0.16
85.2043381	0.01
93.2303162	0.03
95.0361176	0.05
96.9832382	0.07
100.8738098	0.06
104.9256439	0.26
111.0517731	0.44
113.0778351	0.02
119.0821381	0.43
120.2317505	0.03
121.0285950	0.32
123.0894165	9.56
124.0247269	0.02
124.8418732	0.08
133.0827026	0.16
135.1214600	0.06
137.0630188	0.18
137.9810791	0.04
139.0093689	0.29
142.9720154	0.11
145.1312561	1.21
149.0903015	0.04
150.0603333	0.09
151.1209869	0.31
152.5089417	0.32
153.1248932	2.02
155.2395172	0.01
156.1432495	0.02
157.1966248	0.06
159.1614532	0.58
161.2003326	0.10
163.0855713	0.03
165.0065460	0.17
169.0615845	0.32
171.1012268	17.36
173.1993866	0.11
175.1589203	0.76
175.9048615	0.02
177.1849976	0.07
179.1839600	0.07
180.2559204	0.05
183.1934509	0.03
189.1214294	6.20
191.1996613	0.32
193.0455017	0.10
199.3284607	0.09
201.1490173	7.90
205.2768555	0.08
207.1114502	9.97
209.2572937	0.04
213.2894287	0.05
217.1970520	0.06
218.5537109	0.97
219.1690979	11.30
225.1276550	0.02
233.1701355	0.02
235.1224365	0.62
237.1592407	100.00
238.0064087	0.01
243.2794189	0.01
245.1901855	0.08
251.1244202	0.15
253.0515747	0.02
261.1420593	0.08
262.1462708	0.02
263.1736755	0.66
281.1797791	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1695
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
130.0954590	1.31
142.1153259	0.35
167.0256653	0.76
173.0223999	0.14
174.0561218	0.27
184.0767365	2.04
202.0729675	9.90
213.1508026	0.80
220.0597229	100.00
237.2513733	0.26
251.1213379	0.91
308.3502502	0.20
309.6927490	0.38
318.2529602	2.27
331.6106567	1.20
353.4225464	0.35
363.9672241	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.4091
Annotation	Argentinic acid C
Peak:m/z	Relative Intensity
170.1682434	0.77
173.2640228	4.20
174.1773987	0.33
175.1779785	1.14
177.3067932	0.52
179.1051788	1.14
185.0917664	0.19
186.7711792	0.99
188.4371643	0.25
191.1074677	2.03
198.7367096	0.38
201.0287628	3.02
203.5094910	3.95
209.4041595	1.43
213.0842896	2.70
214.2832947	3.37
217.0691071	4.51
223.2988892	0.49
225.3024902	2.31
226.2886963	0.21
227.1205139	1.32
229.0200195	0.32
231.2424622	0.85
232.1487274	1.20
237.1690521	0.27
243.3957825	0.76
245.1124268	4.36
251.1263580	0.44
255.1315002	0.33
265.2481079	0.53
269.1928101	0.60
281.7294922	0.69
283.4472656	1.19
293.3746338	1.48
295.3720703	0.63
298.6457214	0.34
302.2466125	0.53
307.4118652	2.95
308.5065613	0.91
310.3670044	0.67
311.4918823	1.03
321.5891724	1.36
322.2883301	0.83
327.2447510	0.90
330.4059448	0.57
333.3407593	0.74
335.3751221	8.15
336.2597656	2.79
337.4271240	1.61
338.9021606	1.99
339.6499634	0.60
342.3858032	0.73
343.2407227	0.61
347.3930054	0.45
348.4753418	0.39
349.3527832	0.58
355.2228394	0.21
357.3798218	1.72
365.3954468	0.74
378.4887695	0.68
391.4520874	9.50
392.3756104	9.09
393.4543457	2.32
394.4407959	1.68
403.4050293	3.14
404.4210205	2.03
406.3987427	1.09
409.3345337	14.42
410.3612671	8.34
411.5100098	0.64
421.3477173	13.62
422.3462524	4.11
423.3276367	2.96
424.7280273	0.61
425.4520264	1.00
433.4102173	1.12
437.2021484	0.38
439.1544800	100.00
440.2359009	38.14
441.2529297	1.25
462.0147095	0.25
490.3170776	0.97
527.3832397	0.40
532.3091431	0.21
570.6221313	1.34
571.4847412	1.24
573.4382935	1.18
583.3460693	1.72
584.0123901	2.15
603.4599609	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	664.1133
Annotation	Nicotinamide_dinucleotide
Peak:m/z	Relative Intensity
193.1051788	0.31
214.0875854	0.78
215.6738281	0.18
232.1752014	10.07
250.2126465	0.45
272.9981079	0.31
311.8667603	0.17
330.3356323	0.20
348.2186279	0.58
358.3808594	0.10
370.9129028	0.25
388.8746338	0.16
410.1477051	0.89
428.0502319	8.90
444.1535645	1.85
511.0533447	0.14
524.0618896	100.00
529.2485352	0.71
542.1491089	89.85
551.3637085	0.31
554.0593872	0.12
627.7058105	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.0882
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8953781	0.25
130.8500977	0.08
139.0352325	0.04
143.0040894	0.19
146.7088013	0.05
149.0016785	1.02
158.7872009	0.07
160.9368439	2.56
174.9792480	100.00
175.9956055	0.07
177.0436401	0.40
190.9809875	0.11
202.8483124	0.04
214.1796875	0.05
220.9229736	4.29
227.1405029	0.25
232.8454742	0.09
264.2550354	0.71
265.0100403	8.79
306.1904297	0.06
352.0182495	0.13
380.8613281	0.13
397.4139709	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
759.5145874	64.35
846.7367554	96.41
967.434082	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.3982
Annotation	Unknow
Peak:m/z	Relative Intensity
184.9946899	3.16
187.1353302	0.84
189.1604004	0.63
190.9361572	0.40
197.2066040	1.65
199.2727051	1.59
203.1054993	1.58
206.9418945	0.50
209.1991119	2.36
211.0390167	4.13
213.3054199	0.42
215.1203308	2.89
217.1958923	4.19
218.1672974	0.47
219.3171082	2.36
225.2038116	3.40
227.3094177	1.34
229.0211639	0.69
231.0707397	1.08
239.1468811	2.68
241.2388916	0.76
243.1835022	0.91
253.0891876	3.31
255.0939941	0.31
257.2434082	1.30
261.2326050	1.48
265.1719971	0.85
267.2659302	2.28
269.2728882	1.72
273.0678711	1.29
277.2881470	1.15
279.1640320	1.97
281.0011597	0.65
291.4994507	0.34
293.3376465	2.14
295.3176575	0.24
301.0806580	0.18
307.2985229	1.17
319.5874023	0.77
334.2413330	1.13
335.3469849	9.92
346.9453735	1.84
348.1784058	2.68
349.2034912	2.85
353.3543091	0.36
360.7415161	0.69
373.2160645	0.18
381.3970337	0.53
387.3735962	0.79
389.3060913	5.48
391.3833008	100.00
393.4815674	1.56
403.4531860	0.78
404.4058838	0.48
405.5302734	0.91
407.4471436	1.61
409.2493896	8.50
413.5161133	0.53
415.5935669	0.61
417.3423462	0.62
419.3591919	1.03
421.4316406	0.87
422.9894409	1.22
433.4813843	0.59
447.2649536	1.20
455.2103271	0.54
460.5225830	1.02
469.6554565	0.65
476.6616821	1.89
477.4771118	1.44
485.4309692	1.30
494.7310181	13.92
495.5170898	0.37
517.1990356	0.56
519.5312500	0.44
521.4754028	0.72
531.5388184	0.44
535.6513062	0.99
537.4345093	0.35
547.1211548	0.58
569.7052612	0.28
575.6709595	1.21
580.2525024	0.63
585.5958252	0.50
595.6530151	1.16
601.3764648	1.00
611.6079712	1.49
612.7330933	0.22
613.5679321	2.76
621.4677124	2.58
637.6093140	0.88
639.5499878	12.19
640.3963013	0.97
658.7213745	3.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	967.4559
Annotation	Unknow
Peak:m/z	Relative Intensity
759.4334106	0.39
760.5214233	1.78
777.5466919	0.25
778.5996704	1.19
796.5160522	0.30
801.8626099	0.11
819.6867676	0.59
820.4680786	4.04
821.0842896	0.02
837.7196045	1.91
838.5587158	4.07
840.7066040	0.04
861.7033081	0.05
880.3722534	13.07
881.0922852	0.07
922.6578979	0.07
923.5433350	0.67
924.4058228	6.52
968.3088989	100.00
969.2963257	0.76
970.1391602	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	528.22
Annotation	Unknow
Peak:m/z	Relative Intensity
177.2328491	0.52
182.2070312	0.18
195.2078552	0.08
203.1408386	0.23
211.1840210	0.13
212.1478119	0.15
225.1462097	1.06
226.1734619	0.43
237.2156677	0.55
239.4758301	0.12
242.2103424	0.27
250.3534851	0.20
252.4436646	0.14
256.3735962	0.14
259.0109253	0.08
263.4697876	0.42
266.3245544	0.09
268.2014771	0.37
269.3666992	0.05
270.4206543	0.06
272.5367126	0.32
276.2041016	0.11
280.3000793	0.10
281.2406311	0.20
284.1461182	0.93
287.4144287	0.04
293.2072754	1.82
294.4353333	0.47
296.7373657	0.43
297.3425903	0.41
298.3019714	0.26
300.1998901	0.06
304.4648743	0.23
306.6159668	0.12
307.5245972	0.24
309.8256836	1.07
311.2254639	1.87
312.2304688	0.61
313.2032471	0.67
314.6405640	0.09
317.1473999	0.13
319.2066040	0.30
320.2401123	0.60
321.2973633	0.10
323.3065186	0.55
324.2228394	0.12
325.3227539	0.09
326.9870605	0.24
328.3473511	0.19
334.9082031	0.92
335.7318115	0.09
337.1795044	3.43
338.2465210	0.88
339.0193481	0.15
340.2375488	8.78
341.2918091	1.70
346.3057251	0.11
349.2779541	0.07
350.8318481	0.32
352.2196045	0.12
354.2373657	100.00
355.3309326	34.19
357.4530640	0.08
366.3342285	2.18
367.3569336	0.55
368.1338501	0.05
381.1890259	4.46
382.2195435	2.55
383.2637329	0.42
384.2476196	0.23
393.2374878	0.17
394.0244141	0.14
396.0268555	0.09
398.2490845	72.75
399.3134766	23.50
400.4463501	0.34
401.1315308	0.09
404.2564087	0.15
410.3702393	2.60
411.3260498	0.17
424.4638062	0.13
436.2414551	0.10
438.3684082	0.07
439.3914185	0.15
440.4012451	0.15
448.2233887	0.10
448.9890137	0.12
456.4071045	1.11
457.3027954	0.27
464.4210205	0.15
465.5087891	0.87
466.5510254	0.81
467.4265747	1.02
468.3585205	3.12
473.3377686	0.05
481.7852173	0.12
483.2743530	34.18
484.4154663	14.68
485.1629028	0.16
490.9800415	0.05
491.9375610	0.36
494.5286255	0.09
498.7305298	0.26
500.3733521	0.59
504.8544922	0.08
508.4867554	0.07
510.1825562	8.74
511.1474609	4.74
529.4188843	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9172211	100.00
210.9414978	0.74
212.7767029	40.95
282.3231812	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	897.95
Annotation	Unknow
Peak:m/z	Relative Intensity
477.6007690	0.59
611.6424561	0.08
633.5170288	1.61
634.1895142	0.31
643.4053345	0.20
661.6602783	0.23
675.6459351	1.51
685.6227417	0.15
717.6115112	0.11
727.2203979	0.09
729.5342407	4.74
730.1873779	0.14
731.9418335	0.18
745.8948364	0.12
757.5861206	2.08
775.2673340	1.01
787.2427368	0.38
799.6042480	0.15
807.5203857	0.15
817.2562866	2.88
817.8966675	1.06
835.2424927	13.37
836.0112915	0.07
879.0942993	0.54
879.8533325	0.33
897.1694946	100.00
897.9582520	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3857
Annotation	Stevioside
Peak:m/z	Relative Intensity
457.7721558	0.18
459.4078369	0.91
471.0846558	1.72
513.5686646	2.11
517.4014282	0.83
549.3892822	0.37
555.3815918	1.28
627.6970215	0.39
673.7334595	1.09
715.4351196	0.44
721.7991333	1.91
724.2930298	0.28
727.0609131	0.74
756.53125	2.53
757.475769	0.75
759.1969604	2.70
767.5192871	0.24
781.0112915	1.02
785.4730835	3.61
802.6885986	5.30
803.413208	100.00
804.5103149	7.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8740082	12.99
207.8770599	0.20
208.8984375	19.21
290.7492676	37.63
292.8134155	100.00
341.0053101	0.65
358.0532227	1.22
370.8474731	0.92
374.7429810	7.09
375.9471436	2.48
376.7566528	25.36
384.9658813	0.30
400.8916931	2.09
430.8247986	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0877
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
135.0016022	10.97
141.0180054	0.04
151.1569366	0.04
163.0888519	0.05
178.9767151	100.00
179.7727203	0.03
189.8829956	0.04
192.2585144	0.05
195.0192261	0.05
216.9214783	0.02
221.0148315	0.11
232.9579773	0.04
236.1583862	0.05
251.1822205	0.12
255.2183228	0.03
261.0814209	0.14
267.0609131	0.04
270.5168457	0.09
277.9508057	0.05
279.2614746	0.13
281.0250854	0.09
295.0897827	0.40
295.7052002	0.05
296.3400269	0.08
297.3884277	0.26
303.2454224	0.20
309.1501465	0.08
310.8761902	0.02
321.2189941	0.15
323.1434326	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	742.3234
Annotation	Unknow
Peak:m/z	Relative Intensity
224.9512177	0.10
243.6455078	0.44
255.1339722	0.13
271.5770874	0.08
279.3750305	0.08
281.2020569	0.04
283.0485229	0.07
288.0451050	0.31
311.1875000	0.33
327.3104858	0.08
329.3490601	0.10
347.4039307	0.07
350.1822510	0.08
403.4061890	0.37
404.4058838	0.08
406.9785156	0.03
408.3077393	0.23
418.7053223	0.13
442.9222412	0.14
454.4220581	0.39
469.4147949	0.05
489.5360718	0.16
493.4957886	0.05
498.2971802	0.02
506.1711426	0.03
509.0362549	0.11
516.8603516	0.17
519.4176636	0.14
545.7628174	0.48
550.0027466	0.11
562.7854614	0.31
568.0109863	0.10
580.7227783	0.52
581.4708252	0.03
595.8646851	0.17
610.3588257	0.06
613.2279053	0.05
614.6830444	0.09
619.0252075	0.22
619.6707153	0.23
622.6119995	0.08
636.6350098	0.09
645.2898560	0.16
646.6227417	0.13
648.7402344	0.06
650.2388306	0.07
651.5857544	0.03
653.1870117	0.04
656.7169800	0.45
657.3804932	0.56
664.8514404	0.06
679.3532104	0.04
682.4083862	0.04
685.1876831	0.37
685.9523315	0.70
688.7785645	0.77
689.5124512	0.43
690.4567261	0.42
691.7351685	0.86
692.3551636	0.12
693.9735107	1.74
696.4176636	2.48
697.0962524	0.71
699.0696411	0.99
701.5167236	0.06
702.5673828	0.26
703.3854980	1.65
705.5520020	1.22
706.3927612	1.39
707.2747192	0.18
709.5959473	1.22
710.5801392	2.48
711.2975464	0.07
713.0314331	1.23
713.7879028	1.27
714.7501831	0.81
715.7501221	0.65
717.5223999	1.49
718.2085571	0.41
720.1053467	2.11
720.8270874	1.74
722.5083008	1.02
723.8252563	1.79
724.7799072	12.86
725.4785767	2.50
727.2607422	12.37
728.9932251	2.75
729.9707031	0.41
730.9899292	1.72
731.6034546	14.07
733.3440552	0.93
735.6082153	0.28
738.5061035	0.06
743.1842651	0.29
743.7986450	0.08
748.6912842	0.12
760.7265015	0.27
766.3208618	0.27
774.4747925	0.26
788.9398804	0.42
808.8683472	0.42
813.6112671	0.38
815.6443481	0.12
817.3305054	0.70
818.6610718	0.37
823.3144531	0.07
824.5155640	0.43
825.2521362	0.23
828.5099487	0.13
829.2233887	0.07
829.8897095	0.05
833.2719116	0.11
835.5046387	0.19
836.9380493	0.67
837.7037964	0.10
840.3847046	0.38
846.5968628	0.20
847.7403564	0.25
848.8314209	0.39
850.4216919	1.41
854.7979126	0.39
855.7421265	0.40
861.1134644	1.84
862.0169067	0.90
862.9533081	0.84
865.2563477	0.40
865.8743896	0.69
866.7075195	1.05
867.4821167	1.63
869.9038696	0.56
870.5763550	0.27
871.8016968	0.35
872.8554077	0.36
874.4196167	1.05
875.6593628	0.96
876.5280151	0.91
878.5441284	0.96
879.4446411	1.19
881.0886230	0.06
882.4973755	0.36
883.7256470	0.70
884.9253540	5.71
885.7379761	1.54
887.0000000	0.12
888.3527222	1.44
889.4609985	0.78
890.1345825	0.31
890.8708496	0.26
893.0708008	0.14
894.2997437	18.88
895.2018433	5.61
896.5497437	0.28
898.3491211	0.50
900.3823242	3.37
901.0709839	0.58
901.6721191	0.14
902.3202515	0.17
903.3344116	0.45
904.1564941	0.27
905.0671387	0.42
906.1775513	0.83
907.5678711	0.82
908.2937012	1.09
909.9460449	0.36
911.6400757	0.39
913.4004517	7.95
914.4957886	2.74
916.3281860	1.81
917.7413940	4.03
918.5062866	2.36
919.1950073	2.15
919.9246216	0.40
921.9762573	22.13
922.8870239	7.98
923.7373657	2.70
924.5373535	1.21
925.2861938	0.09
926.5631714	2.46
927.2013550	1.17
928.1375122	100.00
929.5236816	2.21
930.6523438	0.41
931.8222046	1.90
933.0848999	2.18
933.9193726	1.44
935.2308960	0.70
936.3950806	0.81
937.4968262	0.96
938.5375977	0.70
940.6384277	3.21
941.4687500	5.53
942.0999146	2.64
943.1940308	0.07
944.8551636	1.27
945.7965698	2.35
946.8424683	3.95
947.7465820	4.71
948.7117310	0.09
950.5979004	3.17
951.5283203	4.42
952.8201294	0.70
956.2276001	7.57
956.9984741	7.06
957.7587280	3.62
959.2026978	0.08
960.4335938	1.10
961.1795044	0.10
962.4417114	0.65
963.0819702	0.32
964.5207520	0.48
969.8624878	0.18
975.7551270	0.39
1001.8244630	0.10
1002.7294310	0.22
1005.2478640	0.42
1024.3735350	0.10
1052.1008300	0.10
1055.7824710	0.14
1075.0107420	0.21
1077.8265380	0.03
1078.6472170	0.04
1084.4892580	0.09
1087.2211910	0.05
1091.1019290	0.56
1096.3759770	0.32
1097.4764400	0.11
1112.7073970	0.20
1119.0573730	0.27
1119.7124020	0.06
1124.1879880	1.21
1139.2736820	0.26
1146.3229980	0.11
1148.7965090	0.24
1154.5000000	0.19
1157.5601810	0.07
1158.3571780	0.17
1182.6600340	0.21
1193.6749270	0.10
1199.9200440	0.13
1201.8408200	0.08
1203.8807370	0.12
1207.2919920	0.04
1208.7670900	0.09
1212.9329830	0.26
1214.0544430	0.19
1216.6390380	0.20
1236.0499270	0.08
1236.7910160	0.45
1237.6285400	0.06
1241.5738530	0.11
1253.8656010	0.20
1255.1212160	0.19
1256.0714110	0.24
1256.7100830	0.19
1260.5279540	0.22
1263.6663820	0.69
1266.1124270	0.39
1276.7447510	0.16
1278.5787350	0.18
1281.4937740	0.07
1296.0072020	0.18
1297.4678960	0.20
1304.6307370	0.14
1317.7840580	0.14
1327.9407960	0.45
1332.7039790	1.04
1333.8123780	0.23
1336.9552000	0.17
1341.7656250	0.09
1370.2269290	0.08
1371.1419680	0.08
1379.1480710	0.10
1422.0241700	0.08
1426.0253910	0.13
1446.0727540	0.10
1550.6960450	0.04
1556.1580810	0.15
1574.7740480	0.05
1583.1999510	0.05
1607.5305180	0.29
1624.8289790	0.07
1672.7401120	0.02
1688.8190920	0.09
1770.8707280	0.05
1783.0217290	0.24
1792.5789790	0.05
1810.1179200	0.17
1822.9490970	0.10
1847.3952640	0.09
1859.5218510	0.04
1864.3396000	0.06
1869.6286620	0.04
1874.2967530	0.08
1897.8172610	0.15
1900.3488770	2.20
1937.0198970	0.04
1947.5988770	0.16
1964.9361570	0.20
1968.2243650	0.51
1975.4844970	0.05
1986.3944090	0.08
1990.3845210	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.2681
Annotation	Unknow
Peak:m/z	Relative Intensity
188.0015869	46.90
189.0167847	3.08
198.9502106	0.53
204.9972687	100.00
206.0790863	7.51
208.2458801	0.12
246.5355835	0.07
264.6556396	0.25
266.2582397	0.51
268.1557312	0.19
273.1321716	0.13
277.0848083	0.06
294.9386597	0.55
300.3651733	0.09
310.2381592	0.11
320.0855408	0.11
324.3139648	0.18
326.4479065	0.12
333.0693970	0.16
337.1649170	0.46
378.3934326	0.05
390.5103149	0.14
408.2070923	0.26
412.2020874	0.04
425.7010498	0.12
427.3057251	0.62
428.1698608	0.24
452.9894409	0.11
471.7941895	0.20
476.4108276	0.11
498.9917603	0.08
499.6102295	0.69
501.5783081	0.05
505.3515015	0.10
517.3707886	0.10
554.7136841	1.30
561.4895630	0.07
570.7340088	0.47
599.5168457	0.31
608.3416748	0.34
613.4365845	1.23
614.2887573	0.49
618.5522461	0.35
633.5844116	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	847.4255
Annotation	Randiasaponin VII
Peak:m/z	Relative Intensity
400.2988281	0.11
476.5089111	0.35
506.4255371	0.05
511.6557007	0.09
524.5738525	0.10
549.5621338	0.22
585.3640747	0.07
595.0499878	0.05
607.3953247	0.22
619.5576172	0.23
631.2544556	0.09
666.4219360	0.11
683.1593628	0.14
695.5022583	0.09
715.7175903	0.10
759.4240723	0.08
786.6406860	0.14
787.3059692	0.28
802.5984497	0.19
811.5343018	3.54
828.4203491	0.49
847.5675049	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.1172
Annotation	3-O-beta-D-Galactopyranuronosyl-D-galactose
Peak:m/z	Relative Intensity
110.8892822	0.32
112.9945374	0.31
114.9349976	2.65
118.0801392	0.03
124.9271622	0.70
126.9593277	0.43
128.9467468	2.90
132.8602905	15.86
134.2319489	0.08
138.8641052	1.66
142.9204407	0.51
144.9057159	0.11
146.9345093	14.34
150.9799500	0.30
154.8710632	0.12
156.9869080	2.56
159.0229492	0.10
160.9840393	4.30
163.0786438	0.13
164.7976685	1.09
166.9316101	0.12
171.0573425	0.12
173.2115784	0.12
174.9731140	5.87
177.0982056	0.46
178.8269196	0.36
181.2312927	0.03
184.4975891	0.08
186.8149719	0.03
192.9659424	100.00
196.6127625	0.17
198.0804443	0.06
203.0098724	0.20
204.2566376	0.09
207.1151123	0.04
211.0318298	0.89
212.4297333	0.40
219.0455933	0.06
221.1040649	0.10
230.0360107	5.45
230.6391907	0.24
232.2908020	0.07
233.0235901	0.63
236.1172180	0.04
236.8250122	0.04
238.1810913	0.49
239.0837097	0.11
248.0288696	0.29
249.1024170	1.01
251.1561584	0.05
253.3150024	0.04
254.9356995	0.05
256.0803833	0.04
257.0623779	1.42
265.0739136	0.59
266.0538330	14.10
267.2860413	0.04
269.0552979	0.47
271.0486145	0.03
272.2559509	0.31
273.0149536	0.15
280.7291870	0.02
283.1074829	0.21
284.0782471	0.05
285.0123901	0.16
287.3216248	0.08
292.5097351	0.13
293.2471313	0.18
298.9580078	1.41
305.0791016	0.02
307.0640564	0.43
309.3011780	0.19
311.0622559	0.06
314.2690735	0.05
316.8350830	0.22
321.1972656	0.68
324.9820251	0.31
327.2529602	0.02
335.1174927	7.89
337.0751343	0.56
339.1610718	1.14
342.3980103	0.05
350.5709534	0.04
353.0692444	44.25
353.6772156	0.19
355.1040955	0.17
362.1091309	0.47
379.1544495	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	307.1397
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0938644	0.11
88.9811554	0.70
95.1686401	0.11
96.0525971	0.27
96.8062820	0.30
98.9654541	4.87
100.9297333	3.21
112.9202499	3.47
118.9036865	3.10
125.1570969	0.26
127.0398026	1.80
127.9640350	0.75
128.9472046	1.10
130.9062805	1.67
140.9699707	1.48
142.9668427	3.34
143.9439087	0.49
145.0637207	100.00
145.9857178	0.20
148.7861328	0.30
155.1037140	0.44
157.0702820	0.35
158.8205261	0.48
160.0221405	0.23
161.0125732	0.92
167.1543121	0.08
170.8176727	0.16
177.0012054	0.62
178.9975891	1.72
180.0081329	0.68
180.7793579	0.14
183.3242798	0.10
185.0417175	0.07
187.1097717	5.19
193.2573242	0.07
196.9597473	0.47
198.9961853	0.46
201.1619873	0.13
207.1117554	0.07
209.0902710	0.15
209.8584595	0.15
210.8933716	0.17
213.1835632	0.10
214.1222534	0.18
217.1831055	0.39
219.1585999	0.45
220.0550232	0.13
226.1278992	0.05
231.2525024	0.06
232.1779175	0.26
233.1236877	0.13
235.2011108	0.87
236.1044312	0.56
241.2075195	0.07
243.0831909	0.40
246.5086365	0.27
247.2810669	0.17
249.1678467	0.10
251.2786865	0.07
253.2354736	1.50
254.2078552	4.49
255.1536255	1.78
261.1319275	2.99
263.1876221	0.62
269.0925293	0.33
270.0178833	0.29
271.0379639	0.46
272.0754395	6.38
273.0729370	2.42
274.9036255	0.25
276.2789917	0.13
287.0981445	0.91
288.2545471	3.30
289.1503906	3.23
290.7832031	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1786
Annotation	Unknow
Peak:m/z	Relative Intensity
112.0181885	0.08
114.9656372	0.13
127.3379822	0.08
129.0393066	0.04
139.9909668	0.35
145.0179291	16.43
159.2893066	0.05
167.1181641	0.23
174.8650818	0.10
184.0774384	0.08
185.1305542	0.13
193.9314270	0.43
196.0847626	0.36
210.3380280	0.06
211.2644348	0.17
213.1225586	1.63
214.0782166	0.20
221.0040588	0.09
222.1263428	0.05
222.9639282	1.02
227.1376953	0.12
228.1785889	0.09
230.9483032	0.20
240.0531616	6.65
241.0726013	0.93
244.9986877	0.47
246.1754761	0.04
250.1448975	0.12
258.0493469	2.14
262.2363281	0.50
263.0983582	0.29
267.1245728	0.71
277.4012451	0.19
279.1164551	2.28
280.2041016	1.71
286.9184570	0.09
291.0530701	0.42
294.2801514	4.44
295.4383545	1.25
296.2059937	11.56
297.3006287	1.72
298.1975708	0.45
298.8887939	0.05
302.1035156	0.14
311.9432678	0.48
313.2503662	100.00
314.1403198	3.57
315.1645813	0.20
316.3923645	0.05
321.7203064	0.18
331.1116638	37.54
332.2229614	0.62
339.2113037	0.73
341.3442383	0.56
344.4419250	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	984.19
Annotation	Unknow
Peak:m/z	Relative Intensity
470.3154602	0.03
565.6051636	0.03
579.2675781	0.05
712.6632690	0.02
784.8784180	0.08
832.3911133	0.02
887.7109375	0.07
922.3259277	0.14
947.6329346	0.02
951.7249756	0.07
962.2312012	0.14
984.5291748	100.00
985.4411621	2.73
986.4921875	0.75
987.3417969	0.52
988.4829102	0.38
989.5520020	0.59
990.3212891	0.08
991.0358887	0.04
992.4890137	0.09
993.1318359	0.14
994.2072754	0.13
995.0065918	0.19
995.7884521	0.02
996.4396973	0.01
1003.9617920	0.01
1029.2225340	0.16
1036.2208250	0.08
1055.5638430	0.15
1074.1430660	0.08
1086.3635250	0.07
1100.5529790	0.03
1106.5629880	0.02
1109.4276120	0.01
1113.7880860	0.08
1121.5991210	0.12
1131.0834960	0.06
1131.8581540	0.14
1134.3671880	0.13
1150.6870120	0.05
1152.3760990	0.15
1153.1606450	0.09
1159.3640140	0.12
1160.5498050	0.26
1167.8498540	0.18
1168.7623290	0.14
1169.4011230	0.15
1171.1069340	0.02
1177.7666020	0.09
1190.7878420	0.03
1197.0915530	0.10
1197.8033450	0.21
1201.1268310	0.19
1201.7531740	0.05
1203.6417240	0.10
1212.9692380	0.10
1223.1621090	0.32
1224.9821780	0.03
1228.6580810	0.01
1229.5504150	0.02
1230.6740720	0.02
1235.7728270	0.18
1236.4094240	0.09
1238.8110350	0.15
1240.8137210	0.04
1242.0480960	1.08
1242.9016110	0.09
1250.1065670	0.02
1258.4846190	0.11
1262.1466060	0.34
1265.1562500	0.01
1267.9114990	0.12
1274.2094730	0.19
1279.5611570	0.21
1281.6729740	0.03
1284.8771970	0.10
1313.7362060	0.01
1319.7767330	0.01
1340.7835690	0.05
1345.5734860	0.03
1368.3406980	0.03
1375.8424070	0.01
1395.1629640	0.02
1396.6668700	0.02
1400.3811040	0.04
1401.6407470	0.04
1407.1607670	0.08
1424.7086180	0.03
1434.2242430	0.02
1436.0247800	0.04
1462.9896240	0.10
1484.8966060	0.07
1529.0582280	0.05
1533.8494870	0.11
1534.5888670	0.05
1536.3795170	0.01
1610.1232910	0.06
1623.1112060	0.02
1628.3897710	0.03
1664.6676030	0.05
1685.8084720	0.04
1709.1281740	0.02
1725.7452390	0.05
1727.7335210	0.10
1742.4910890	0.06
1752.4318850	0.19
1753.1346440	0.10
1784.7806400	0.02
1786.0167240	0.03
1795.1698000	0.03
1814.8194580	0.03
1825.6472170	0.10
1832.7694090	0.03
1866.8293460	0.02
1869.8156740	0.02
1874.4764400	0.01
1882.4354250	0.02
1885.4344480	0.02
1913.8599850	0.03
1939.7453610	0.01
1943.8543700	0.01
1944.9017330	2.32
1955.6246340	0.04
1960.4124760	0.09
1968.9783940	0.13
1974.5203860	0.01
1982.0357670	0.26
1987.1124270	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1224.4442
Annotation	Unknow
Peak:m/z	Relative Intensity
376.3557129	0.00
432.3104553	0.03
585.1843872	0.01
596.5262451	0.01
724.5257568	0.01
792.0911255	0.01
838.5783691	0.05
910.0985107	0.02
922.4456787	0.00
934.5041504	0.02
946.4040527	0.01
962.4598389	0.03
978.4068604	0.02
983.9327393	0.02
991.7093506	0.01
1013.3673100	0.01
1027.9249270	0.07
1028.8681640	0.04
1032.4946290	0.02
1036.1473390	0.04
1045.1547850	0.01
1079.8999020	0.01
1082.6180420	0.02
1086.1755370	0.01
1092.9921880	0.01
1094.5588380	0.01
1097.9543460	0.02
1100.1870120	0.00
1101.6618650	0.02
1105.7895510	0.01
1106.9510500	0.01
1109.1561280	0.02
1111.4014890	0.01
1113.8853760	0.06
1116.5280760	0.01
1123.5710450	0.02
1133.9311520	0.02
1138.6236570	0.05
1139.5100100	0.01
1144.1099850	0.03
1145.0163570	0.01
1147.3161620	0.38
1148.1164550	0.08
1149.5341800	0.01
1155.6832280	0.02
1157.8881840	0.11
1159.0756840	0.03
1159.7814940	0.01
1163.6828610	0.13
1164.3029790	0.06
1165.1363530	0.03
1166.8994140	0.27
1167.6843260	0.01
1168.6337890	0.03
1172.9360350	1.01
1173.6817630	0.21
1182.6698000	0.03
1183.4249270	0.01
1199.8438720	0.04
1203.1606450	0.02
1203.7617190	0.01
1225.3981930	100.00
1227.4859620	0.20
1228.3819580	0.18
1229.4575200	0.06
1230.5609130	0.02
1231.2337650	0.05
1232.1983640	0.03
1234.8029790	0.02
1235.8133540	0.03
1236.6981200	0.01
1244.6947020	0.03
1257.4748540	0.01
1320.9143070	0.02
1406.7662350	0.02
1411.5993650	0.01
1414.9534910	0.01
1420.2932130	0.03
1444.5584720	0.02
1449.6641850	0.02
1496.9476320	0.02
1514.1253660	0.02
1533.7974850	0.01
1558.4187010	0.02
1575.7508540	0.02
1577.1343990	0.00
1580.2139890	0.03
1581.2413330	0.02
1602.2202150	0.02
1631.6491700	0.01
1638.6617430	0.02
1649.2310790	0.01
1656.3502200	0.01
1684.1433110	0.01
1687.5662840	0.00
1691.7025150	0.03
1703.8884280	0.01
1704.6724850	0.01
1718.4906010	0.01
1722.0262450	0.03
1723.4571530	0.01
1733.7752690	0.02
1749.3817140	0.02
1758.8768310	0.03
1763.8674320	0.02
1780.6617430	0.02
1808.9793700	0.03
1829.6979980	0.02
1831.4100340	0.01
1835.4854740	0.01
1837.1575930	0.01
1841.6658940	0.00
1850.2180180	0.01
1863.0194090	0.01
1871.8243410	0.08
1895.8760990	0.01
1897.8375240	0.02
1900.0393070	0.05
1926.8684080	0.00
1931.0544430	0.02
1945.4564210	0.01
1946.9957280	0.01
1967.1735840	0.02
1969.9002690	0.03
1972.5563960	0.01
1976.2293700	0.03
1978.0456540	0.01
1978.8917240	0.17
1989.0189210	0.01
1990.6950680	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	489.17
Annotation	Dracorubin
Peak:m/z	Relative Intensity
177.0068207	100.00
258.8948975	1.78
275.0562744	1.14
295.2627563	3.37
390.4593201	3.23
471.0385132	1.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.2667
Annotation	2',7-Dihydroxy-4'-methoxy-8-prenylflavan 2',7-diglucoside
Peak:m/z	Relative Intensity
260.1579285	0.07
303.2777100	0.05
306.3536987	0.17
319.1655884	0.04
331.5702820	0.05
341.6057739	0.03
366.5750122	0.06
387.5802612	0.11
400.2274170	0.16
407.1677856	0.05
418.2355957	0.18
423.2513428	0.12
429.3507080	0.11
432.3524170	0.51
433.3544922	0.10
444.5033569	0.07
445.3692627	0.04
450.3660889	0.09
462.3503418	1.34
467.5258789	0.05
473.3142090	0.04
475.2734985	0.06
483.3270874	0.10
514.6950073	0.12
515.3665771	0.31
528.9343872	0.24
529.5748291	0.13
533.4821777	0.03
541.3566895	1.39
543.7081909	0.08
557.0492554	0.11
559.3399048	5.04
565.4484863	0.03
571.4808960	1.06
573.9505005	0.02
575.4801636	0.67
583.4179077	2.57
585.1879883	0.02
589.4346924	3.59
591.1777344	0.02
594.3224487	0.04
601.4660034	14.33
602.2663574	0.04
608.4671631	0.03
615.2089233	0.02
617.0991821	0.32
619.3926392	100.00
620.0079346	0.27
626.6183472	0.04
627.4232178	0.15
630.5731201	0.09
633.4064331	0.11
634.6832275	0.02
643.8753662	0.07
645.3150635	2.48
646.6168823	0.04
663.2388306	1.81
664.1987915	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.1782
Annotation	Ugonin P
Peak:m/z	Relative Intensity
128.9829712	0.08
135.9968262	0.28
141.9414978	0.10
148.1946411	0.08
149.0830536	0.24
152.9082642	0.17
153.9308624	0.28
174.9259644	0.38
178.9647217	0.13
180.1223145	0.27
181.1702728	0.35
181.9809570	0.14
186.2093201	0.17
186.9838867	0.06
189.0639038	0.11
189.9333191	0.36
191.0119019	0.10
195.2732086	0.15
197.0448761	0.05
203.0188599	0.20
204.6580658	0.16
211.1549377	0.47
213.2069092	0.47
218.9778748	0.34
226.0205688	0.06
231.2339783	0.23
232.9278412	0.57
233.5948792	0.57
235.0968323	0.08
243.0722046	0.12
251.2373962	0.36
253.0801697	0.21
261.1318665	0.74
271.2584534	0.41
275.0200806	0.29
278.9048767	1.30
283.2734985	0.90
284.1357727	0.84
293.2180786	100.00
295.2187500	0.10
308.1469421	0.76
312.9627686	0.31
314.7287598	0.19
316.7064819	0.08
324.2461243	0.16
326.3203125	0.08
341.4842529	0.24
344.4121704	0.30
346.7957153	0.13
349.1929321	0.18
350.5610046	0.28
352.5234985	0.20
355.7483521	0.63
358.5695190	0.45
360.2706909	0.22
360.9923096	0.21
376.5687561	0.97
377.3480225	0.69
378.4189758	0.60
379.3117676	0.13
380.2630920	0.21
381.4862976	0.40
382.1264954	0.20
385.3990784	0.53
386.2870178	0.20
387.1677856	0.30
387.8837585	0.83
390.3613892	0.38
391.2027283	0.98
393.2201538	0.22
401.5861206	0.59
402.9406128	0.36
404.6237488	1.00
405.3604736	24.86
406.3000793	0.36
408.1603088	0.24
410.4345703	1.16
412.6119080	0.09
413.7647095	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	911.3199
Annotation	Unknow
Peak:m/z	Relative Intensity
306.2954712	0.09
341.2520447	0.05
374.5291443	0.21
388.2759399	0.07
400.5969238	0.06
406.6177979	0.06
418.3047485	1.50
433.3688965	0.02
444.4586792	0.04
462.5335693	0.02
469.3132935	0.17
475.7692871	0.04
485.7138672	0.05
511.5881958	0.03
513.7779541	0.07
515.4042358	2.76
539.3434448	0.03
541.5452881	0.65
557.4312134	2.87
559.3691406	1.73
565.2000122	0.09
575.4973145	7.24
583.3875732	0.24
599.4757690	0.10
601.3954468	1.90
604.2539673	0.03
607.4555664	0.02
613.5128784	0.02
619.4248657	10.23
620.1365356	0.02
627.5981445	0.03
635.3219604	0.04
643.1301880	0.07
661.0158691	0.11
666.5860596	0.26
668.9158936	0.06
703.2033081	0.13
721.7722168	0.14
727.0748901	0.11
733.7586670	0.04
743.7265015	0.07
745.1351318	0.06
749.3795776	0.10
763.3711548	30.94
764.0092773	0.13
765.1194458	0.14
781.4585571	0.53
789.3661499	0.06
796.4888306	0.06
797.8148804	0.03
805.4818726	9.00
807.4909668	0.04
813.6156616	0.05
821.2089233	0.05
823.3880005	100.00
824.1044312	0.19
825.3934326	0.03
832.3416748	0.02
849.4193115	2.77
851.5516357	0.06
867.2437744	9.32
867.8565063	0.23
875.3152466	0.07
883.3233643	0.07
893.2704468	0.31
893.8884888	0.32
911.1790771	33.70
912.0676880	1.35
912.8380737	0.22
913.4773560	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	506.549
Annotation	Unknow
Peak:m/z	Relative Intensity
144.4520111	0.08
145.0545044	0.21
146.0934143	0.09
161.9161835	0.10
163.0375061	1.57
163.6868286	0.18
168.8637390	0.17
178.2056732	0.10
179.1385651	0.40
181.0773163	0.09
189.0039368	1.52
190.2969208	0.27
194.1935577	0.20
198.8520660	0.16
201.5138855	0.25
205.1101379	1.06
215.0925446	1.79
224.1316528	0.29
229.3118286	0.49
231.1834259	0.34
232.8911133	0.27
233.9648285	0.25
238.1996460	0.21
240.0886078	0.13
243.2808838	0.20
254.9125671	0.64
257.3648376	2.94
258.7209778	0.18
261.7945557	0.30
264.7141113	0.13
266.0568542	0.24
267.0834961	0.11
272.8301392	0.54
288.1238098	0.11
296.1463623	0.51
299.2578735	0.18
300.0215149	0.19
304.8704224	5.24
305.7932739	0.29
308.1439209	0.18
310.1887207	0.45
311.5181274	0.51
313.0495605	0.11
314.1466064	0.40
317.1071777	0.32
322.1538696	0.33
324.5806580	0.13
325.2701721	0.98
327.3239441	0.46
331.0108032	0.10
334.3973999	1.52
335.3981323	0.12
339.4085083	0.29
341.0000000	0.16
343.3949280	0.35
344.5192261	0.22
345.1707458	0.16
345.9935913	0.23
349.7086487	9.55
350.5211792	0.14
355.5291138	0.88
358.2532349	0.13
359.1683655	0.42
360.0840759	0.32
361.3292236	1.71
362.2411499	0.58
367.7253113	0.62
369.7355042	0.25
371.2262573	0.08
372.4990234	0.18
373.5907898	1.13
377.2708740	0.81
378.5676880	0.31
392.5295715	2.59
393.2885437	1.14
394.2319641	0.33
398.6612244	100.00
399.4046326	2.07
400.1351624	1.13
401.4246826	0.17
403.8697815	2.23
405.1667480	0.57
407.9889832	4.43
409.3143005	2.25
423.9654846	0.39
425.8067322	0.96
426.8587952	0.63
431.7324829	0.16
432.3491821	0.42
435.7530518	0.95
440.4230347	0.38
442.3569031	0.46
443.6859741	0.15
444.4111633	0.43
449.4075012	0.24
452.6256104	42.50
453.5911560	3.83
454.7373962	0.89
455.9043579	1.08
457.4786987	1.28
458.4929504	0.34
460.3731689	0.43
461.1332703	0.69
463.7133179	0.86
469.3998718	0.08
470.3303528	0.41
471.2895813	0.21
474.7114868	0.34
478.1045837	0.44
480.0238953	0.24
488.4049377	2.12
489.3295288	2.46
495.8211365	0.94
496.7836304	0.15
512.3706055	0.16
515.0885620	0.82
516.2772217	0.10
523.8189087	5.14
524.5552368	1.95
531.4214478	0.21
533.0357666	13.36
533.7966919	0.42
534.5170288	0.29
539.4533081	0.10
540.5297241	0.78
546.8067627	0.26
549.5877075	0.57
552.4235840	0.97
556.5631714	0.84
560.3295898	2.15
566.3225098	0.49
570.6742554	0.35
575.5629272	0.24
579.3966675	0.09
586.2438354	0.43
587.4054565	0.78
588.5759888	10.37
597.5484619	96.43
598.5901489	2.72
599.4389648	1.21
600.1701660	0.22
606.6644897	0.61
614.0033569	4.38
618.4491577	0.43
619.3378296	0.05
621.9413452	0.18
632.4375000	0.29
636.7050171	0.93
650.3867798	0.09
660.6036987	0.55
665.0264282	0.16
667.5078735	3.34
668.4985352	0.60
669.7108154	2.31
670.5286255	0.07
671.2553711	0.32
678.5711670	18.07
679.8314819	0.24
683.8903198	0.39
685.8779907	0.45
705.7849731	0.33
723.5158081	0.37
724.5018921	0.17
740.5052490	0.37
741.6267700	0.41
764.4248657	0.17
778.2362671	0.06
796.7304077	2.73
797.8095093	0.21
802.5007935	0.10
814.6246948	0.25
830.5512695	0.18
838.6147461	0.44
842.4807739	0.20
852.5848999	0.52
868.6127319	0.38
869.7383423	0.16
870.9905396	0.66
879.4415894	0.09
946.4226074	0.11
958.6918335	1.52
1074.1669920	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.2317
Annotation	Thiersinine B
Peak:m/z	Relative Intensity
147.0343170	0.02
152.7129517	0.04
166.9395905	0.18
193.2167664	0.09
205.2218781	0.34
216.2730560	0.14
223.1994934	4.69
237.1502686	1.06
242.0344849	0.61
261.4693909	0.08
274.1032410	0.04
309.2658691	0.31
332.9561768	0.02
342.4708252	0.08
359.1140747	0.12
374.0628662	0.11
377.4920654	0.10
379.1278992	0.13
383.1897278	0.08
390.6618652	0.10
391.4747620	0.21
392.4866638	0.15
403.1655579	0.42
432.3678589	0.13
433.3270569	0.07
446.1109619	0.13
448.2764587	100.00
449.2060852	0.77
460.3902893	0.07
462.2701416	6.35
463.2615967	0.13
464.3186951	0.50
470.2757874	0.03
472.3646851	0.13
478.3002014	0.02
480.8784790	0.24
486.5612488	0.12
488.3790588	0.17
489.9353943	0.02
490.5945435	0.18
493.1134644	0.06
509.2969666	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.17
Annotation	Trans-Zeatin-9-glucoside
Peak:m/z	Relative Intensity
115.8277206	2.85
119.961441	0.18
130.5330353	0.13
138.7604675	0.30
140.8768158	1.45
147.9888763	0.17
158.0729828	0.36
165.8901215	0.60
169.1110535	1.36
169.9604187	0.76
184.0942688	0.70
186.9946899	0.38
188.0404663	0.11
195.1016846	1.23
197.0454407	0.35
198.8503418	0.18
201.3104858	0.51
202.1317902	6.67
208.0764313	0.36
211.8616333	0.65
213.0140533	65.22
214.1936035	8.06
215.0969086	0.49
220.1252136	100.00
233.2120972	0.92
238.2536316	1.00
241.2061768	0.53
243.2748718	0.36
245.1946411	0.32
251.1408386	0.71
266.1908569	10.56
267.1086121	1.48
284.0558167	6.53
284.9496155	0.78
287.0967407	0.31
291.9225464	0.81
293.0723267	0.11
300.2853699	0.87
305.5932312	0.22
310.1427307	8.73
311.2388916	1.28
313.8407898	0.08
317.835968	0.25
321.8127747	0.60
333.3375244	0.13
335.8671265	0.86
337.2332153	1.34
341.232605	0.53
342.1889954	0.35
346.8228149	0.28
352.3218079	1.28
353.3979187	1.17
359.2972412	0.11
363.0594788	1.31
364.0018616	0.83
364.7658081	0.44
369.8824158	0.99
372.5421753	1.36
373.3278809	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	363.1176
Annotation	Unknow
Peak:m/z	Relative Intensity
109.0862045	0.02
109.9676361	0.15
111.0814896	0.02
111.9902496	0.04
113.9058685	0.03
116.9877319	0.04
118.9177475	0.34
122.0268250	0.02
126.9477692	0.29
129.7921753	0.02
130.9617920	1.06
133.0679321	0.05
142.0119324	0.01
144.0749664	0.02
144.9006958	0.02
146.9201965	6.95
147.8016663	0.05
149.0049133	0.02
152.2281189	0.01
153.0334473	0.05
155.0047607	0.54
165.0116882	0.08
170.9367371	5.74
173.0484314	2.54
181.1853638	0.02
185.4357910	0.01
195.1567230	0.06
198.9953308	12.15
205.0975800	0.01
209.2223816	0.05
217.0992432	100.00
218.9580688	0.05
222.8279419	0.27
223.4294434	0.01
225.0796814	0.06
230.6469421	0.11
237.3106995	0.03
238.1129150	0.07
240.9389343	0.07
242.4652710	0.10
243.1298828	0.13
249.0629578	0.11
262.0629883	0.01
271.0422363	0.01
273.1588135	0.03
275.1540527	0.06
277.1806030	2.26
281.6873779	0.06
283.6880798	0.03
287.7941895	0.08
289.3966370	0.03
294.1752319	0.02
299.0698242	0.09
299.9757080	0.09
301.2080078	0.08
303.2120361	0.05
304.0476379	0.01
312.2335815	0.04
313.1141968	0.02
314.6907959	0.07
316.2484131	0.32
317.1318359	0.35
318.2415161	0.12
319.1445618	0.37
321.2286682	0.04
322.2718201	0.17
327.4427795	0.07
330.6900024	0.10
331.5013733	0.05
333.1907349	0.03
335.2967224	0.03
336.0791321	0.02
343.6569519	0.03
344.5279236	0.17
345.1726379	1.31
346.0820007	0.12
348.2077026	0.04
353.7967224	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2029
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
151.9278870	0.04
153.0804749	0.08
159.1564484	0.22
160.2028046	0.05
160.9453888	0.36
178.0670929	0.15
185.2904358	0.16
187.1581116	0.10
193.0617065	0.14
202.9905243	0.14
209.0569458	0.06
213.2697296	0.20
215.0257874	0.12
233.2161102	0.04
283.2924500	0.22
284.1087952	0.17
289.0880737	0.18
296.4700928	0.13
302.2454834	0.09
304.3065796	0.18
311.1972046	0.47
317.1904907	0.08
319.0686646	0.08
329.2666626	100.00
333.2290649	0.06
334.2824097	0.19
335.3341064	0.04
343.4356079	0.06
347.0025635	0.13
348.9730225	0.15
356.2205200	0.06
356.8899536	0.17
357.5642700	0.10
359.0702515	25.44
361.4143677	0.03
371.2122803	0.10
372.9047241	0.15
377.2681274	0.09
382.0831909	0.08
386.2258301	0.05
389.3978882	0.05
390.0850220	0.10
391.1570435	0.09
401.3292236	0.31
413.3175659	0.62
417.2775269	0.22
423.0227661	0.07
431.3684692	0.32
434.5200195	0.22
435.3878784	0.51
449.2004395	0.24
459.3277588	0.16
461.2850952	0.74
470.6069946	0.05
471.2551880	0.15
473.1931763	1.92
474.2907104	0.16
475.3416138	0.73
476.1119385	0.06
477.3098755	0.31
479.4104614	1.65
485.4528809	0.11
486.3771973	0.04
490.4196167	0.09
491.3618774	0.35
494.2300415	0.05
500.3311157	0.21
501.4750366	0.59
502.2708130	0.07
503.2798462	0.36
522.2053833	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	251.14
Annotation	Paucine
Peak:m/z	Relative Intensity
71.9961014	4.97
87.0389862	0.06
88.9758148	20.67
90.9431610	0.07
98.0100098	0.67
98.7263947	0.12
100.9139099	0.52
106.8850098	0.06
113.9382629	5.84
114.9519348	3.95
116.8851013	2.21
117.9203644	0.13
119.9744873	0.12
125.0794983	0.03
126.9987640	0.04
130.0242157	0.10
132.9243317	0.36
135.1227875	0.34
137.0791931	0.23
137.9856567	2.63
141.1926880	0.17
160.8893585	0.17
162.9960938	9.49
167.2633820	0.11
175.0531464	0.68
177.0173492	0.58
177.7468719	0.04
178.9868774	0.41
179.9161835	0.17
191.0907745	0.45
192.1192474	7.80
193.0462646	0.60
194.9647064	1.16
199.2013245	0.17
202.9049530	0.06
204.9599609	2.12
206.0223541	0.13
207.1735687	0.20
208.8561707	1.41
209.9441833	2.02
210.7625885	0.20
212.0537109	0.07
215.1138763	0.08
218.6967621	0.15
220.2689362	0.08
220.9434967	0.23
223.1065979	0.98
224.8760223	0.27
227.8030396	0.62
231.1556244	0.30
234.0963745	100.00
235.0641479	0.24
241.0661774	0.11
248.5697174	0.17
251.1577759	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.4163
Annotation	Unknow
Peak:m/z	Relative Intensity
814.7819824	0.02
833.5544434	100.00
834.5421753	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3965
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
591.4956055	1.30
821.3898315	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	840.45
Annotation	Carbomycin
Peak:m/z	Relative Intensity
473.7173462	3.28
581.6203003	1.53
585.3113403	0.91
604.4778442	2.36
611.0115356	1.64
617.7015381	0.56
631.3308716	3.23
633.3606567	0.96
661.585083	1.19
688.3307495	2.88
690.9995728	3.44
713.5715942	0.75
715.6314087	1.76
719.6281128	1.03
755.4550171	3.62
761.5236206	1.64
778.1270142	1.52
779.5371704	66.50
780.472229	3.34
793.3436279	6.68
794.7411499	1.82
797.5735474	69.34
798.5957031	2.79
801.4593506	2.09
804.5066528	1.08
808.7251587	4.47
819.4376221	46.88
820.5979614	6.36
823.164978	0.80
840.4640503	100.00
841.3442993	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.4589
Annotation	Unknow
Peak:m/z	Relative Intensity
418.0064087	0.05
618.5332642	0.26
679.5930176	0.05
722.6624146	0.02
733.8109741	0.07
734.4829712	0.03
744.7547607	0.06
750.4661865	0.06
752.4452515	0.21
778.4940186	0.07
779.6505737	1.05
780.5525513	1.97
781.5819702	3.26
788.0476074	0.12
794.9666138	0.06
796.0888672	0.21
797.9044800	0.65
798.6730347	3.30
799.6853638	5.25
820.6386108	2.05
821.5525513	0.12
822.5741577	0.08
841.5075073	100.00
842.1275635	0.67
842.7927856	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
116.852005	0.10
118.8060074	0.22
169.0925446	0.17
170.0561218	2.82
179.0683289	0.50
183.0115662	100.00
184.0821991	8.54
185.1159668	0.47
189.0330811	0.14
191.1853638	0.18
195.0855408	0.17
197.1020203	8.39
198.0871887	3.34
199.25	0.34
206.2202759	0.28
211.1531677	1.79
212.0801392	1.12
225.0773315	2.80
225.9273376	1.13
234.9532776	0.21
237.3674316	0.19
239.0796204	2.07
240.0204163	0.94
243.0926514	2.12
247.1967468	6.23
248.0373535	0.22
249.2353516	2.01
253.2469177	2.29
254.3859253	0.51
255.1112061	0.10
263.3051147	0.39
265.184906	0.58
267.1046753	4.45
268.0691528	0.28
270.9467773	0.21
275.2709351	0.07
279.1891174	0.28
281.9265137	0.53
283.3291321	0.18
290.0980225	0.37
293.25177	5.45
295.4534912	0.38
311.2985535	13.35
312.4174194	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.3301
Annotation	Petrosiacetylene D
Peak:m/z	Relative Intensity
119.0415192	1.99
120.8704071	1.58
122.8612976	1.55
125.0950775	0.71
128.2007904	0.60
129.0105286	2.31
130.1524811	0.84
131.0524597	2.02
133.0363007	1.85
135.0475464	2.64
137.2105560	1.33
141.1371765	1.76
141.9175873	0.38
142.9529724	2.91
144.9411926	4.92
146.9711151	4.80
148.1035461	0.46
149.0450134	3.56
150.8332977	2.42
152.9371033	0.22
153.9059143	0.44
155.0231628	2.19
156.1187439	1.16
156.9487457	5.52
158.0901031	0.09
159.0274658	5.50
161.1220245	3.88
163.0163574	2.22
164.7033386	0.39
167.0749207	0.90
168.0116882	0.44
169.0988159	4.63
171.0257263	5.55
173.0642395	4.94
175.0803833	2.00
177.1384888	3.24
179.1372986	1.34
180.6646118	0.08
181.2656860	0.86
182.3487244	0.66
183.0828400	11.68
184.0549316	0.42
185.0887909	5.72
187.1144409	5.82
189.0712738	6.12
191.0986481	2.22
192.1479797	0.36
193.0755310	0.97
195.2716827	2.74
197.1083984	3.90
199.0384369	8.02
201.0701447	9.41
203.1168823	6.56
205.2125549	6.52
206.2131653	0.21
207.2535248	0.91
209.2153931	4.91
211.2408295	5.22
213.1621399	7.47
215.1399994	9.36
217.2081299	3.88
218.7662964	0.21
219.3676910	0.39
221.2471466	2.57
223.2510529	8.51
225.1501770	5.02
227.1893005	7.04
229.0877533	3.98
231.1080933	2.58
233.2131348	2.47
235.1990662	3.43
237.2195740	4.45
238.2685547	0.13
239.1836548	6.61
241.1837158	26.04
243.2026978	5.97
247.3163757	1.52
248.1164246	0.72
249.1012573	4.84
250.1040649	0.62
251.2127380	7.87
253.1898193	12.88
255.1687622	9.25
257.2114258	3.39
259.3032227	1.05
261.3075867	1.13
262.2147522	0.11
263.3464355	6.11
265.2610779	6.99
267.2657166	17.72
269.2350769	14.78
271.1875916	2.30
272.7379150	0.25
275.2364197	4.04
276.0791016	0.26
277.3519592	6.79
279.0805664	7.53
279.6846619	0.08
281.2691040	13.10
283.2577820	8.00
285.3911133	2.18
287.0228271	0.65
289.2731628	5.86
290.1788940	0.50
291.2883301	4.58
293.1722717	12.09
295.3533325	12.03
297.2854919	6.33
299.4734497	0.29
303.3289490	1.38
305.2218628	5.42
307.2224426	32.61
309.2516479	29.40
310.2302246	0.52
311.3725586	7.66
313.2504272	1.42
317.3694458	3.27
319.3447266	6.22
320.3115234	1.49
321.2840576	10.02
322.0972900	0.78
323.2915955	7.02
325.3849487	2.74
329.4245605	0.13
330.1805115	0.42
331.3033447	5.09
333.2456665	3.78
334.5693359	0.73
335.4429932	12.51
336.2585144	0.21
337.3359680	13.06
339.4220581	1.20
342.9992676	0.14
345.3375549	13.07
346.6150208	0.62
347.3836670	3.28
349.2681274	7.99
350.2860107	1.05
351.3930054	1.70
356.1215210	0.16
359.1899414	2.91
361.4656372	8.14
362.6747131	2.09
363.4148865	20.86
365.1024170	0.16
373.3385315	2.72
375.5408325	2.77
376.3583679	0.75
377.5008850	11.88
378.6212769	0.63
386.6251526	0.18
389.4797363	1.74
391.4924011	63.24
401.4669189	100.00
404.4857788	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2205
Annotation	Unknow
Peak:m/z	Relative Intensity
210.2558594	0.45
210.9101105	0.14
227.8770142	0.04
235.9475098	0.11
237.3189392	0.28
253.0867615	0.06
254.1971436	2.19
255.1949463	1.27
272.1934814	0.27
273.1811829	0.25
279.1056824	0.19
284.3100586	2.91
285.3512878	0.89
293.2247009	0.33
308.4242249	0.12
321.3671265	0.07
326.1555786	0.23
341.4592590	0.07
342.4356689	0.09
346.2901611	0.40
364.3300171	0.14
390.3295898	0.11
395.0441895	0.29
408.3883667	0.14
410.1273193	0.33
412.3996582	0.86
418.1600342	0.41
420.2463989	90.56
421.2359619	14.44
433.7461548	0.09
437.2182617	0.25
438.1188965	0.77
439.5263062	0.13
446.4879150	0.19
449.4346313	0.45
452.4411011	0.08
453.3328857	0.12
461.2188110	0.26
462.4124146	0.18
465.2654419	0.05
468.2009277	0.12
479.2297363	0.19
490.1767578	0.14
493.1228638	0.05
495.4583130	0.28
497.5519409	0.03
507.2849121	2.99
508.2231445	1.09
513.7776489	1.13
517.2266846	0.23
520.3936157	0.75
521.3024292	1.08
522.5440063	0.38
526.0058594	0.09
529.3966675	0.28
531.1719360	0.70
532.5421143	0.31
539.4035034	3.96
540.3833008	1.21
544.1730347	0.11
549.4726562	0.17
552.5105591	0.52
560.2065430	0.15
564.3261108	37.79
565.4683838	5.34
572.5383911	0.15
573.3798218	0.30
574.6218872	0.85
575.5920410	0.17
577.5700073	0.37
578.6648560	0.28
587.5551758	0.29
588.6269531	0.05
594.9869995	0.21
600.3117676	6.59
601.0573120	1.60
601.8390503	0.12
603.1763916	0.54
606.3128662	0.12
614.4028320	1.16
615.5518188	0.10
618.0485229	1.14
620.1372681	0.25
625.3892212	0.07
631.4498901	2.82
632.4491577	1.27
633.3924561	0.09
635.5816650	0.29
637.6296387	0.22
647.5527954	0.33
648.3103638	0.07
649.4025269	2.99
650.3986816	0.33
651.4371948	0.19
657.1647339	0.69
658.1271973	0.51
663.4503784	0.39
672.0929565	0.26
673.2593994	0.10
675.3516846	100.00
676.4804077	16.92
694.4367065	38.92
695.4112549	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1014.4276
Annotation	Unknow
Peak:m/z	Relative Intensity
325.0115662	0.15
329.2341309	0.22
333.9689026	1.03
336.2442932	0.35
362.0807495	0.60
364.8279114	0.15
374.2632446	0.53
387.1648560	0.59
391.5087891	0.09
398.1188049	0.71
416.1098022	0.35
455.3433533	0.21
462.6013489	0.23
466.6403809	0.15
468.2289429	0.28
473.4520874	0.31
475.6099854	0.40
492.9460144	0.25
504.3461914	0.35
527.5577393	0.07
540.5438232	1.06
573.5410156	0.32
597.7248535	0.13
601.6381836	0.41
612.1022949	0.14
614.5286865	0.16
635.5436401	0.53
652.9935303	0.47
669.4906616	0.16
687.2604980	0.42
688.3248291	0.20
702.5882568	0.47
705.3607788	5.35
723.4599609	1.61
728.6211548	0.13
731.6858521	0.61
741.3446655	0.29
764.4263916	0.36
770.5468750	0.93
777.2137451	0.17
780.8712158	0.09
782.2806396	0.37
788.2509766	0.36
790.5395508	0.50
815.3884277	0.21
816.4512939	2.92
817.4570312	0.29
834.4779053	9.07
835.3642578	0.36
847.6193848	0.50
849.6661377	0.46
852.4786377	10.63
862.6345215	0.27
867.5645752	1.47
885.1567383	0.20
916.6760254	0.29
921.3760986	0.66
930.1450195	0.17
939.6655273	0.14
960.3747559	0.51
978.5937500	1.95
979.6782227	0.53
995.8753662	0.33
996.4982910	10.37
997.7669678	0.79
1014.5473630	65.99
1015.4692380	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.3152
Annotation	Neoabieslactone D
Peak:m/z	Relative Intensity
131.0200653	0.14
132.9842072	0.31
135.1191101	0.27
137.1830139	0.16
139.0301056	0.07
141.0365753	0.15
142.2286072	0.23
143.0164642	0.40
144.9760895	0.85
146.9711609	0.95
149.0904846	0.74
150.9365845	0.28
151.9101257	0.16
153.2493286	0.15
155.0050201	0.46
156.9232788	1.47
158.9525604	1.36
160.9098358	0.41
162.0198669	0.21
163.1516418	1.52
165.0691223	0.48
165.8292542	0.32
167.1455078	0.06
167.9790649	0.33
168.9936829	0.90
171.0290985	1.32
173.0603790	2.17
174.9719543	0.07
177.1576233	2.27
179.2008667	0.24
181.0729523	0.70
183.0584412	1.00
185.0109711	1.62
187.0873718	1.32
189.1104431	2.96
191.0909729	1.55
193.0898743	0.20
195.1363525	1.02
197.2348938	1.01
199.2067566	1.25
201.1110840	3.40
203.1350555	4.18
205.2116089	0.68
209.1567078	1.07
211.0632324	1.69
213.0941467	2.27
215.1831970	2.47
217.1645813	1.40
219.2365723	0.32
221.1690674	0.90
223.1315918	1.17
225.2229614	2.10
227.1869812	2.69
228.1733093	0.06
229.1470795	1.12
231.0644379	0.85
233.0749207	0.35
235.0908203	0.49
237.1522827	0.73
239.2183228	1.81
241.2796936	2.63
243.2385864	1.63
245.1831970	1.06
246.9697266	1.67
249.2389832	1.16
250.5223389	0.17
251.1937561	0.54
253.2430420	2.16
255.3343506	1.01
257.2198486	1.73
259.1597900	1.60
259.9141846	0.31
261.1003113	1.66
263.2346191	0.82
265.1711731	1.54
267.1856995	1.34
269.1002502	2.60
271.3006287	0.99
272.0882263	0.06
273.0128479	1.38
275.3344727	0.60
277.2003174	2.31
278.6358032	0.34
279.2495422	1.41
281.2138062	1.96
282.3622131	0.07
283.2764893	1.52
285.3035583	1.16
287.1251831	0.84
289.2311401	1.26
291.2596436	0.75
292.5295715	0.29
293.3290100	1.19
295.2155762	1.92
297.2015991	1.89
298.6817627	0.30
299.3041992	1.32
301.2013245	2.86
303.1699524	2.47
303.7721558	0.12
305.1730652	1.35
307.2370605	2.04
309.3421631	0.50
311.2972412	1.67
312.1588135	0.17
313.3784790	0.70
315.1634827	1.90
316.6223145	0.10
317.2590942	1.08
319.1567078	1.28
321.1849670	1.51
321.8668213	0.40
323.2222290	0.79
324.2238770	0.06
325.3536987	5.21
327.2112427	1.74
328.3026733	0.17
329.3933716	3.69
331.2729187	1.23
333.1981812	0.68
334.5903320	0.19
335.3312988	0.57
336.8822632	0.60
337.4944458	0.75
339.2698975	4.90
341.2774963	1.15
343.2582703	7.40
345.3435059	0.98
347.2492676	1.86
349.3452759	1.27
351.1250610	2.84
353.1864014	1.90
355.2832031	1.43
357.3497925	17.04
359.3011475	0.77
361.5290222	1.08
363.3963318	6.82
365.3363647	5.30
367.2507935	1.82
369.1994934	4.41
371.2839050	1.74
373.2860718	0.52
375.4321289	20.62
377.4430542	1.88
378.9334412	0.52
379.5459900	1.30
381.3526306	0.38
383.2928162	3.86
385.3618164	9.83
387.4561462	5.34
389.2178040	0.79
391.3795471	0.39
393.3428650	9.71
395.2679749	0.14
397.3588257	2.63
398.2044373	0.19
399.6159973	0.22
403.2939758	17.57
404.1080627	0.04
405.4345398	4.32
406.7042236	0.34
407.3519287	2.31
409.5150452	0.50
411.2652893	10.24
413.3879089	0.67
414.5174255	0.06
416.3623657	0.08
419.1241760	0.60
419.9586487	0.17
421.3901978	17.75
423.3674927	2.19
425.4481812	1.87
431.3497009	18.28
431.9859619	0.10
435.5246582	0.08
437.3420105	0.62
439.4198914	14.44
441.6568298	0.06
447.6915588	0.53
449.3130798	100.00
450.3711243	0.60
466.5097351	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0771
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
87.2546234	0.05
88.9126434	0.18
92.0299988	0.12
92.9682922	3.28
93.9063721	0.42
94.9658203	0.45
97.0430985	0.03
100.9029312	0.31
102.0053177	0.02
107.0263977	0.09
108.1068878	0.11
112.9166870	5.36
113.9125366	0.31
115.0089417	0.12
116.9620667	0.04
118.8628845	0.29
121.0916290	0.10
124.9656677	0.07
125.9565277	0.03
130.8830566	0.19
133.0522308	0.06
134.8824768	0.36
136.9587402	100.00
137.9284668	8.44
142.9296875	0.74
145.0933533	0.14
146.9767761	0.11
148.2485962	0.09
148.9282074	0.11
150.9839325	7.14
152.0057220	0.50
153.8984985	0.12
158.8405609	0.09
160.9600372	0.23
163.1737061	0.06
175.0160828	0.18
175.8351746	0.06
177.2174530	0.05
178.9810181	79.62
179.9869385	9.67
189.2471313	0.05
190.8979492	0.52
192.2059174	0.09
193.2330780	0.15
195.7278442	0.06
199.0130615	0.11
202.0339966	0.04
203.2796631	0.08
205.2195129	0.03
206.1387634	0.08
206.8359680	0.07
209.0234375	19.88
210.0480957	3.89
213.0275879	0.11
213.8949280	0.07
217.0115051	0.03
221.0660706	0.70
227.0935059	0.08
228.0455933	0.07
232.9923401	0.60
237.2007751	0.14
239.0383606	89.89
240.1296082	15.21
253.0256042	0.24
254.1554565	0.12
255.0195007	0.18
256.1502991	0.21
263.1126099	0.11
264.2572632	0.09
269.0838318	0.06
270.2857666	0.13
272.1885071	0.02
279.0115967	0.13
281.0165100	1.24
282.0438843	0.16
283.3101501	0.02
286.0408630	0.08
299.4296265	0.03
300.4090271	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	237.0598
Annotation	8-Dehydro-3-deoxy-D-manno-octulosonate
Peak:m/z	Relative Intensity
86.8438110	0.13
98.6316376	0.22
102.8837738	0.48
107.8820496	1.25
108.9937286	0.41
112.8987885	5.03
119.9686127	0.10
121.9583588	0.26
129.8212128	0.30
131.0176697	0.10
135.7472229	0.26
140.7233429	0.18
142.9987640	0.70
146.0112152	0.07
149.8359528	0.32
152.9526978	0.62
159.0963135	0.40
160.6357880	0.32
163.9611359	0.31
166.2051544	0.34
167.1710052	0.47
168.9939728	4.88
175.1632538	0.81
177.3051910	0.47
178.7844391	0.45
179.5038910	0.51
180.9109497	0.87
186.0498810	5.84
186.8601532	38.46
188.3356628	0.62
189.8703156	0.57
191.0308228	1.89
191.8512115	0.77
192.9168854	0.54
196.0587921	0.63
196.7201996	0.14
199.1217346	0.18
201.2621613	0.67
204.6476898	100.00
205.3433533	0.44
205.9801178	0.26
209.1381378	1.07
219.1396790	2.93
220.1451416	1.85
221.3957062	0.41
236.9457397	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	967.4561
Annotation	Unknow
Peak:m/z	Relative Intensity
588.4818726	0.01
616.4163208	0.08
634.4867554	0.01
715.1005859	0.01
724.5385742	0.01
730.8171997	0.02
732.4321289	0.10
742.6907349	0.04
748.6418457	0.04
750.8125610	0.02
759.5303345	0.02
760.3699341	0.09
774.6133423	0.01
778.1333008	0.61
778.8231812	0.44
792.3148193	0.04
795.5474243	0.09
796.6544189	0.22
802.4276123	0.12
819.5118408	0.44
820.5740356	2.47
834.6119995	0.03
837.8473511	1.30
838.5322266	6.40
839.1841431	0.02
879.8792114	2.72
880.5445557	14.87
881.1765137	0.06
906.6869507	0.03
923.7697144	1.49
924.4381104	5.35
966.0517578	0.01
968.3049316	100.00
969.0767212	0.50
969.7681274	0.29
970.7129517	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.2397
Annotation	Rosellichalasin
Peak:m/z	Relative Intensity
145.0056152	0.22
155.1512756	0.39
162.8044739	0.74
165.1212769	0.85
170.9243469	0.28
175.1627808	0.10
184.0010071	51.70
189.3455811	0.55
223.1956329	0.55
244.4132080	0.27
251.0849915	0.43
255.1636963	0.49
258.1788025	0.35
275.1051025	0.07
281.2138672	0.40
282.8370667	0.13
283.4371948	0.49
285.0227966	0.43
303.2338257	0.12
312.2802124	0.08
313.3895874	0.19
323.2619629	0.46
327.3652344	0.08
333.1798401	0.60
341.1250610	0.19
345.3410339	0.21
354.3044128	0.21
358.2751160	0.16
365.1763916	0.16
366.5263062	0.57
382.2773132	0.13
383.3475647	0.64
387.2049255	0.69
389.7111511	0.16
393.3352051	0.95
401.2155457	0.25
402.2979736	0.16
403.5883484	0.50
410.3524170	0.13
419.3814087	1.38
429.3672485	0.14
446.3114624	100.00
447.4516907	0.51
448.7645569	0.57
454.7887573	0.16
455.3977966	0.33
465.4061584	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	571.3982
Annotation	Hericenone F
Peak:m/z	Relative Intensity
167.1041260	4.82
169.0367432	0.72
170.2602539	1.70
171.2641296	2.59
173.7341614	2.38
179.0781250	0.52
180.9678650	4.50
183.0835724	3.14
185.1503296	0.56
187.1050262	2.78
189.1369934	0.81
193.1080933	2.11
195.1831360	1.53
199.1531677	2.74
201.1262512	7.07
203.0956726	3.86
207.2953186	0.47
213.1828308	12.81
214.9387512	1.63
217.2759399	2.50
219.3805847	0.56
225.1595154	5.37
227.1405792	5.60
229.3385773	0.93
230.9626160	2.30
237.2535095	4.96
239.1818237	2.88
241.2524261	2.30
243.4142151	0.64
245.2749634	1.00
253.2386780	3.33
255.1847992	1.24
257.3547058	5.46
258.9045410	1.00
264.9888916	0.93
267.2105103	9.30
279.2405090	1.83
280.3760986	0.37
281.2186890	5.29
283.3698425	3.04
285.5254822	2.40
289.4575806	1.06
293.0809326	4.50
299.3419800	3.47
301.3752441	1.16
305.3711548	0.42
307.2619629	6.59
309.3078003	10.96
311.4902344	0.83
323.0813599	3.31
325.4400635	3.50
327.4732666	3.17
328.8012695	5.09
333.4715576	0.33
335.3659668	8.23
341.5034180	1.07
347.2311401	0.95
348.2900391	1.78
349.7142334	0.79
353.3192139	1.00
367.3973999	0.95
381.2404785	4.48
389.2388306	3.82
391.4790649	100.00
393.7047729	2.29
403.6088867	2.80
405.5955811	0.64
409.4602661	28.78
411.3790894	0.57
417.1428833	2.20
421.2736816	6.71
423.5955811	1.17
434.0617676	0.49
443.4048462	3.03
471.4845581	1.56
487.3802490	1.25
511.6316528	3.02
515.5841675	1.96
517.1337891	7.07
528.3389282	2.55
529.7063599	1.54
535.4002075	19.41
551.9003296	2.13
553.4917603	33.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.2208
Annotation	Astin I
Peak:m/z	Relative Intensity
156.0173492	0.74
157.0062103	0.13
157.8531494	0.13
158.9782715	1.07
160.8059540	1.19
162.1010742	1.65
162.8537445	0.12
167.9270477	0.16
169.0090637	1.59
170.0160217	0.44
170.8502502	4.63
172.2281799	0.24
172.9743042	0.35
175.2033081	1.94
176.0094910	0.26
176.8983917	8.38
177.8478851	0.74
178.8913422	3.93
180.6718445	2.02
181.5227051	1.24
182.2486877	0.96
182.8996429	0.41
184.0937042	0.95
185.1408691	0.64
185.9961853	0.25
187.0478363	1.62
188.3918762	5.92
189.0001526	68.37
191.0703583	0.13
193.1275635	1.13
195.1033020	0.18
196.1014709	1.94
196.9198303	0.87
199.0879822	0.22
201.2416382	0.27
204.9268341	12.20
207.0228882	0.28
207.9162750	1.09
209.2332611	0.36
210.4746246	0.92
211.1778259	4.80
212.2711182	0.65
213.1608276	0.71
214.9594421	32.55
216.2048035	0.25
217.0951843	2.63
220.0203552	0.25
220.9897766	0.52
223.0877228	1.60
224.1753540	2.01
225.1809235	0.08
226.9434052	2.25
228.0444794	1.11
229.1170197	0.54
230.1079559	0.62
231.1395721	2.35
233.0972748	10.19
238.0146790	1.26
238.7758789	0.54
239.4062195	0.56
240.9983368	1.02
241.8865967	0.61
243.0289612	1.49
245.1095276	3.04
247.6953125	0.81
249.1400757	0.31
250.3200226	0.61
254.1645813	0.44
256.4918823	0.20
257.2133789	1.17
258.0744629	0.19
259.1309814	3.53
266.0711060	4.89
267.2251282	0.51
268.1659546	1.64
269.2215576	6.15
271.3127747	0.18
274.0733948	1.09
277.4252319	0.16
278.1763916	0.58
279.2804260	0.17
280.5841370	0.59
284.2896118	4.11
285.3367004	1.15
286.4113770	1.97
287.1419678	10.16
288.1964722	3.00
289.0754395	0.69
290.0419922	0.12
291.1193848	1.03
294.1760864	4.44
295.1881409	1.25
299.2556152	1.31
301.9964600	2.93
303.9901123	0.19
305.1671143	1.12
306.4441223	4.59
308.1317749	2.03
312.2453613	2.84
313.0752563	0.53
314.2657471	0.26
315.3309937	0.19
320.1027832	5.26
321.3247070	0.26
323.2037964	2.98
324.1892700	0.51
325.0435791	0.27
326.1761475	1.08
327.1494141	0.31
328.2235718	0.36
330.2152710	0.96
334.0531616	7.10
335.3423462	0.37
339.0827637	0.61
341.2671509	5.66
342.4097900	0.78
343.3306274	0.56
344.2579956	0.69
345.1710205	5.90
350.4416504	0.29
351.4085083	0.49
353.1724854	0.71
356.1328125	0.55
359.1975098	0.16
362.2265015	20.23
369.1707764	1.79
370.2647705	1.77
371.2155762	12.97
371.9638062	0.93
376.7359619	0.62
378.0200806	1.11
387.2716675	8.70
388.2068481	1.17
392.2686768	0.86
396.4185181	2.08
397.3894653	0.22
401.4758911	0.61
405.2872925	100.00
406.4301758	0.32
416.9506226	0.67
423.1781006	37.16
423.8510132	0.19
425.2489624	1.35
431.5362549	0.30
432.3685303	0.50
434.3687134	0.45
441.5761719	0.34
443.4536743	1.17
453.9537964	0.27
459.2829590	3.06
460.2378540	0.40
461.9427490	3.41
467.6361694	0.52
469.9378662	4.49
471.0744019	3.50
477.4578247	1.68
479.8286743	0.47
482.2724609	0.42
487.4240723	0.65
488.2563477	0.27
498.3143921	1.24
506.6661987	0.11
517.2155151	0.35
534.2557373	58.45
535.3798218	1.76
540.3775024	0.53
543.3041382	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3868
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
759.6712036	8.26
803.364624	100.00
804.6586304	15.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	508.2319
Annotation	Thiersinine B
Peak:m/z	Relative Intensity
152.9468536	0.03
160.7782288	0.06
168.0758057	0.05
176.1748047	0.02
176.8348083	0.04
191.1520996	0.10
204.1047058	0.04
205.2702637	0.06
223.1791534	1.01
225.3114929	0.02
237.1284332	0.34
262.2062988	0.05
267.4948425	0.03
275.0732117	0.09
279.4385681	0.12
283.4097595	0.04
292.5426636	0.15
311.6112976	0.06
342.4312134	0.19
345.5126648	0.16
350.4474182	0.05
358.2589722	0.05
359.1952209	0.28
365.1724243	0.04
372.3364258	0.07
375.3283386	0.06
377.4077454	0.02
379.3597412	0.17
386.1343689	0.03
403.1718750	0.25
412.1157837	0.05
414.6327209	0.20
419.7845154	0.06
425.3912659	0.05
432.2317200	0.10
433.1341858	0.07
436.4505005	0.07
448.2438049	100.00
449.3405457	0.25
462.4066162	7.38
463.4363708	0.08
464.2869568	0.19
465.5830383	0.08
470.2906189	0.06
472.3836365	0.18
477.5219421	0.03
487.9749146	0.05
489.4657593	0.05
490.3559875	0.20
493.5409241	0.12
509.4425659	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Unknow
Peak:m/z	Relative Intensity
72.8809967	0.37
75.1490173	0.09
80.8847275	0.94
84.9171295	0.11
86.9452286	0.23
88.9449310	0.05
98.9774475	0.87
103.0679321	0.04
112.8671417	0.85
116.8622284	1.25
124.9860229	24.06
128.9744568	1.51
131.0326080	0.04
142.9959564	7.79
145.1110840	0.04
146.9771271	5.89
159.0413055	0.40
161.0716095	1.02
168.9342957	1.29
177.0729828	2.18
186.9918518	0.34
203.0084534	0.07
205.0005646	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	484.2293
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0019989	0.27
163.1038208	0.09
166.0088348	0.21
181.2444153	0.01
184.0081177	100.00
185.0739746	7.07
208.9787903	0.04
210.1136627	0.14
221.1068573	0.01
222.1417847	0.07
223.0885925	0.08
233.1741333	0.02
237.9251099	0.04
238.9780884	0.38
240.1126404	0.13
258.1750793	0.21
259.2668152	0.03
276.1645813	0.03
280.2955627	0.04
281.1319275	0.07
287.3783264	0.06
288.2715149	0.05
291.0771484	0.07
293.9802246	0.02
299.1752014	0.30
301.2114563	0.13
304.4422607	0.02
310.0339050	0.05
312.0815430	0.13
313.3469849	0.02
320.0832214	0.16
322.1924438	0.04
323.3649597	0.02
327.4013062	0.14
340.2878723	0.09
343.4231262	0.06
350.1109009	0.06
352.3625793	0.10
355.3973999	0.13
356.2599487	0.04
357.2319336	0.10
359.3771057	0.09
364.1391296	0.04
365.1349487	0.16
368.0706482	0.09
368.9886475	0.04
371.1298828	0.05
383.1847534	0.16
385.8393860	0.01
388.4658508	0.07
391.0783997	0.05
394.8589783	0.15
395.4998169	0.03
396.3242798	0.02
397.7290649	0.02
399.1854858	0.06
401.7614441	0.02
404.4506531	0.12
406.2187195	0.08
408.2012024	0.02
412.0423279	0.19
413.5049133	0.03
420.1791077	0.06
421.3208313	0.05
422.1759949	0.02
423.2843933	0.03
430.6189270	0.30
431.5489197	0.05
432.4686584	0.03
438.4775696	0.23
441.1711121	0.05
443.9093933	0.02
448.2220459	0.04
449.2567444	0.65
450.3155518	0.23
451.6963196	0.06
452.6455383	0.04
457.1955566	0.04
466.2773743	36.21
467.3584900	9.83
468.3448792	0.05
475.4612122	0.05
487.3645935	0.02
493.4588928	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0902
Annotation	Glutathione
Peak:m/z	Relative Intensity
115.9529266	1.49
130.1011658	0.21
132.7984314	0.02
143.9570312	3.82
145.0709534	0.04
150.4012756	0.07
155.3727112	0.01
161.8763123	30.01
178.9492645	100.00
179.7714233	0.02
185.9632111	0.04
205.0372620	0.10
215.0852966	0.93
218.0691528	0.03
232.9968262	18.31
245.1509399	1.55
252.1568604	0.02
261.9389648	0.05
272.2058716	1.23
290.0885315	5.61
291.1571655	2.27
298.5015259	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.0874
Annotation	Unknow
Peak:m/z	Relative Intensity
107.8934021	0.09
109.0474701	0.18
110.0877686	0.14
118.1495895	0.05
131.0530396	0.18
135.8643646	0.86
136.9300537	2.48
142.9403992	0.03
145.1824036	0.02
154.0589905	100.00
173.0856323	0.98
176.0248413	0.04
192.1314850	0.07
201.1712952	0.02
210.0506897	0.12
257.4817810	0.02
263.0223389	0.12
283.2422180	0.03
284.0695496	0.05
287.1029663	0.04
301.2503662	0.03
303.9833984	0.02
312.0178223	0.08
316.2968445	0.09
320.2148438	0.10
329.2228394	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.267
Annotation	2',7-Dihydroxy-4'-methoxy-8-prenylflavan 2',7-diglucoside
Peak:m/z	Relative Intensity
209.2398682	0.07
211.2886963	0.02
222.1086121	0.06
225.4858704	0.02
240.3864441	0.05
243.1320953	0.03
249.2662811	0.02
253.4204102	0.06
254.2044373	0.06
255.1824951	0.09
256.2832031	0.05
266.3506775	0.02
268.2963257	0.02
272.2789917	0.12
274.0578003	0.04
281.3119507	0.82
295.2083435	0.04
304.8914185	0.08
306.1547852	0.05
312.3902283	0.03
313.0009155	0.07
317.2574463	0.16
318.0708008	0.08
319.0640869	0.05
324.9396973	0.02
329.4437561	0.03
335.1027222	0.62
336.2175903	0.52
337.2025146	0.08
345.2998657	0.10
355.0162964	0.02
363.1762085	0.03
366.0575562	0.03
388.2634888	0.27
389.3395386	0.48
390.3668213	0.08
396.2297363	0.12
402.4241333	0.05
403.2826538	0.11
406.5557251	0.02
409.3973999	0.04
416.4232178	0.06
418.3648682	0.15
434.3538818	1.98
444.3132935	0.38
447.5872192	0.02
448.2729492	0.05
457.4067993	0.12
462.2915649	100.00
462.9484863	0.22
464.3643799	0.04
466.5379028	0.04
475.4249878	0.07
476.4727173	0.05
488.3294678	0.48
489.4078369	0.18
497.1483765	0.02
499.8268433	0.10
501.3900757	0.05
506.0982056	2.16
514.4148560	0.02
515.4485474	0.10
516.4946899	0.07
529.5535278	0.04
533.3240356	0.92
534.2713013	0.38
543.4451294	0.09
558.3930054	0.07
560.5903931	0.06
566.8233032	0.05
570.3640747	0.02
577.1712646	0.04
579.0358276	0.02
587.4749146	0.08
588.3695679	0.02
600.3021240	0.34
601.3153687	0.15
602.3981323	0.02
603.2935791	0.03
616.1444702	0.07
618.5580444	1.66
619.3054199	3.99
626.5388794	0.21
627.2046509	0.02
630.4594727	0.04
631.4302979	0.03
643.2578735	0.02
644.7305298	0.77
645.5556030	0.75
663.1353760	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8084717	5.08
290.7422791	30.79
291.3490906	0.14
296.6270142	0.12
338.7502441	0.44
369.0844116	0.43
374.6796875	13.49
375.4478760	0.15
376.9990845	0.26
380.7548218	1.12
398.8627930	1.35
406.7368774	0.50
413.0888672	0.16
422.7855225	1.87
436.7434082	2.30
452.4310303	0.12
458.6490479	100.00
466.1891479	0.29
466.9721069	0.23
478.8163452	0.63
482.8212891	4.86
496.7021484	1.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	832.407
Annotation	Unknow
Peak:m/z	Relative Intensity
685.5251465	0.04
704.4806519	0.05
746.4017944	0.14
752.9500732	0.08
768.9592896	0.11
773.4238892	0.04
786.6058960	0.04
789.3280029	0.02
814.7792358	0.25
833.5419312	100.00
834.2583618	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
467.2276001	5.70
700.2918091	3.95
803.3685913	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.73
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8751068	0.04
193.9909668	0.02
206.9014130	0.11
209.0561523	0.06
210.0120392	0.02
210.9878845	0.06
212.8164062	0.12
232.0102234	0.20
232.9786835	0.01
251.1171875	0.35
252.1145325	0.27
253.0113525	0.27
268.2261658	0.02
272.0461731	0.02
290.9293823	0.07
292.8677063	0.02
293.9398499	0.09
294.6969299	0.26
296.7243042	3.75
367.0952148	0.10
378.2787781	0.03
378.8993835	0.04
380.7287903	100.00
381.3472595	0.21
398.8966675	0.05
418.1469421	0.01
419.0444031	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3409
Annotation	Unknow
Peak:m/z	Relative Intensity
148.1217957	1.14
149.1999664	1.20
151.3936310	0.72
157.1375122	0.79
159.0141602	4.64
171.2343903	1.30
172.1634064	1.02
173.0446014	5.20
179.3800354	0.59
182.2292480	3.14
183.1915283	3.30
184.0023499	0.95
185.0133362	7.43
187.1308899	8.36
189.1075134	2.33
191.1985168	1.27
193.0699615	1.05
194.9303284	0.66
197.0851288	1.92
199.2182617	1.97
200.1429596	3.25
201.0265808	11.48
202.4311829	5.55
203.2725220	8.33
207.1558838	4.66
209.3701935	1.30
210.1770020	3.34
210.9970398	2.80
213.0673523	4.89
214.0954285	2.30
215.1309662	3.00
216.2904663	2.23
217.1887970	0.47
218.0403900	9.43
225.0729370	4.37
226.1188049	4.97
227.8119659	4.50
229.3932037	0.79
232.2239075	1.78
235.9525452	2.23
239.3068695	2.73
241.2616730	4.92
246.3014221	0.72
249.2543335	5.51
252.0788574	3.59
253.1363525	4.75
254.4423676	5.80
255.1528015	4.27
256.4378052	4.07
257.3979492	3.43
258.5710449	9.08
260.1653442	3.07
266.3201904	0.92
267.1880493	4.09
268.0956116	1.27
270.4481201	4.60
271.2402344	2.46
275.1572266	1.11
277.5632019	3.83
280.0242920	1.72
281.1062622	3.85
282.4231873	2.69
283.2379761	1.69
284.2879639	1.50
287.5281372	3.83
293.4665527	2.94
295.2312012	8.22
296.1853027	6.69
297.6528931	2.41
308.5178833	5.69
310.2714844	4.48
317.3106079	5.03
319.3642578	1.17
320.4464111	4.38
322.4370728	7.26
325.1735229	2.36
327.4712524	1.92
330.7099609	1.34
331.3101807	1.36
332.4197388	2.30
336.4620972	3.32
343.2158203	2.23
345.1823730	6.43
346.2805176	1.50
352.3156738	4.71
358.2770386	2.50
359.6359863	4.01
360.5632324	3.39
361.2030640	2.24
362.5777588	8.27
363.3884888	1.91
364.2851562	2.17
371.2687378	1.01
376.3874512	2.26
381.5775757	1.11
382.4526978	3.74
389.2495728	2.97
390.4847412	5.17
391.5003662	14.78
392.3856812	50.06
396.2130737	0.53
400.2600708	5.39
401.3617554	13.93
402.4342041	12.60
412.1764526	0.66
413.3292236	2.54
414.3449097	2.31
419.4741211	40.12
420.4848633	87.35
424.4139404	2.06
425.5712280	1.29
437.4262695	18.61
438.3814697	44.81
439.3031006	10.14
440.5922241	4.87
441.3730469	1.95
451.0590210	2.66
453.7922974	2.14
467.6184082	5.49
468.3583984	4.17
471.5720825	1.65
479.5686646	13.83
480.5049438	13.08
481.1342163	4.88
482.4279175	1.40
495.6707153	32.77
496.3570557	100.00
505.2994995	23.15
506.4871216	34.37
507.3689575	2.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.4073
Annotation	Beesioside D
Peak:m/z	Relative Intensity
368.2504883	0.14
443.8225708	0.30
453.2328491	0.23
454.0761108	0.25
471.4472656	0.58
487.3170776	0.13
518.2343750	0.09
587.5344849	0.45
615.3864136	0.65
633.4567261	100.00
634.5368652	5.46
635.7280884	0.13
661.5084839	0.27
680.4329834	5.70
681.2857056	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	951.4597
Annotation	Licoricesaponin F3
Peak:m/z	Relative Intensity
282.2093811	0.02
600.5534058	0.04
617.6309204	0.06
618.4484253	0.09
662.6415405	0.07
687.5801392	0.05
708.6250000	0.24
726.5579224	0.14
756.7372437	0.11
762.4176636	6.64
763.1095581	0.15
774.7443237	0.14
779.9221191	0.30
780.7749023	0.87
803.9387817	5.23
804.6178589	13.83
821.6508789	3.46
822.5042114	19.63
838.4454956	0.04
847.9656372	0.04
863.8994751	10.80
864.5023804	38.64
865.1102295	0.14
907.6195679	0.68
908.2947998	6.81
908.9529419	0.08
952.2461548	100.00
953.1669922	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.14
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
137.0477753	0.12
141.7089081	0.16
142.7982483	0.61
144.9772797	0.07
146.1419373	0.06
156.9727478	1.90
165.2651367	0.14
172.9973450	1.85
174.9680786	1.64
177.0084991	0.07
185.0340118	0.13
186.0951233	0.07
186.8020935	0.09
188.9198914	2.56
195.1139984	2.79
201.1055145	1.07
205.0984650	0.38
207.0331879	2.63
209.1556854	0.14
215.0587616	0.75
217.0233765	0.68
219.1134491	0.07
223.1302490	0.16
234.7128296	0.08
236.5110779	0.71
237.1611328	1.49
244.0414734	0.10
245.2066956	1.83
249.1612244	12.43
252.3066101	0.11
255.1734619	0.39
259.6136169	0.14
261.2596130	0.25
261.9338074	0.03
265.1323853	0.16
267.1699524	0.82
275.1939697	0.05
277.2688904	0.25
289.1261292	4.52
290.7839661	0.32
292.2485962	0.08
293.1163940	0.11
293.8784790	0.10
294.9940491	2.04
304.9990540	0.06
307.1276245	1.08
309.2408447	0.39
317.0632935	4.37
321.1280823	18.73
322.3366699	0.05
323.3402100	0.17
328.5574646	0.06
330.3746338	0.06
333.6602173	0.16
334.3591919	0.03
335.1881104	0.18
337.3070068	0.17
339.2385559	5.11
341.1823120	0.85
342.2226868	0.98
343.2902222	0.17
349.1802673	1.23
351.3757324	0.09
355.4115295	0.43
356.0207214	0.25
361.2189331	8.99
363.1139832	0.24
368.1150513	0.22
368.9664307	0.06
372.9761047	1.45
373.5929871	0.03
379.2497864	4.38
380.1647034	0.47
381.2127991	2.12
383.2651062	0.14
389.2739563	0.04
393.2746887	35.00
399.2488098	0.06
407.2648010	0.22
408.1889648	0.15
409.1905212	0.30
411.2080383	100.00
420.1225281	0.09
421.2180481	0.22
425.1408997	0.11
427.1141663	0.07
428.0483093	0.58
439.2120361	0.93
441.0718689	0.11
443.4700623	0.13
452.0216064	0.07
453.1015320	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0680542	0.41
216.8593750	0.02
228.9988403	0.29
262.6933289	0.05
271.1932678	0.08
272.9591064	16.98
275.2413330	0.04
290.1240234	0.06
371.2047729	0.04
385.2734375	0.13
387.0164185	30.34
423.0916748	0.03
427.0437012	0.16
429.1298218	0.03
459.3071899	0.03
460.8270264	0.03
467.9830322	0.04
480.2706909	0.21
480.9833984	0.07
484.8215942	0.06
492.6354980	0.05
499.0186157	1.96
500.8604736	100.00
501.5127563	0.61
507.9399414	0.06
523.2058716	0.02
525.0009155	0.02
526.0506592	0.07
528.0947876	0.04
529.1612549	0.03
540.9166870	0.35
541.9452515	0.12
543.0870361	0.05
557.9951172	0.09
559.0921021	0.23
567.9773560	0.27
569.1162109	0.47
569.9027100	0.21
570.8675537	0.23
572.5090942	0.08
581.9264526	0.09
582.9492798	0.04
585.5732422	0.12
586.4591064	0.33
597.1722412	0.03
615.0786743	0.06
615.9578857	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.4597
Annotation	Malonylsaikosaponin A
Peak:m/z	Relative Intensity
599.4654541	0.19
624.3648071	0.05
699.0462036	0.06
726.5438232	0.07
732.6055298	0.32
743.3958740	0.06
744.6069946	0.16
761.5220337	2.05
762.5997925	21.28
773.5552979	0.34
774.3673096	0.14
779.2835693	0.36
780.5314331	5.48
781.1832886	0.04
786.7615967	0.13
804.4891968	22.70
805.3688354	1.01
822.4491577	41.80
823.3391724	0.65
846.4995117	0.14
865.3899536	100.00
866.1878662	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.386
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
405.3855591	0.37
643.4324341	0.27
687.5476074	0.44
714.977417	0.19
717.7263184	3.72
743.2931519	0.16
759.5762329	17.42
803.3769531	100.00
804.0084839	0.51
804.7802734	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.187
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9653320	0.02
148.8849792	0.06
162.0076599	0.04
164.0472717	0.32
179.0744171	0.08
181.0017090	0.04
185.2085876	0.05
187.4844055	0.03
189.0899353	0.15
202.1842651	0.02
205.1637573	0.05
206.2940369	0.02
221.1777649	0.12
223.2885742	0.02
226.9711304	0.04
232.1084595	0.27
235.1303406	0.03
246.0783386	0.03
248.1446838	0.10
253.3144226	0.08
255.5390625	0.09
257.1524048	0.10
258.4671021	0.03
259.9041748	0.07
271.6795959	0.06
275.1718750	11.19
279.0143127	0.02
282.1238708	9.80
283.3156433	0.31
290.9088135	0.11
293.4974060	0.11
295.3068237	0.11
297.7091064	0.04
300.1420898	12.49
306.9134827	0.03
308.3261108	0.19
309.0926514	0.09
310.3809204	0.12
311.0492859	0.02
314.2464600	0.07
317.1940308	100.00
318.2724609	0.16
323.3576965	0.06
325.3073425	0.05
327.3480530	0.05
329.4057922	0.04
331.2460022	0.06
332.2756348	0.06
342.3506165	0.33
343.2718506	0.02
346.3087769	0.03
347.1290283	0.03
365.4038086	0.24
367.8639526	0.17
371.0687256	0.12
375.0730591	0.05
381.6380920	0.10
382.3419495	0.02
384.4208679	0.03
396.8645325	0.09
404.3924255	0.06
405.3963318	0.22
407.4600525	0.04
418.9228516	0.02
420.8484802	0.05
422.0258179	0.07
429.8807373	0.17
431.7741394	0.13
433.4140015	0.16
437.2734680	6.74
443.3620911	0.09
444.2144470	0.13
446.9304504	0.03
449.5050354	0.29
455.3472595	0.04
456.9142761	0.11
460.0062561	0.42
461.1238708	0.99
462.2526245	0.26
468.2286987	0.16
478.6918335	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0965
Annotation	Ethotoin
Peak:m/z	Relative Intensity
132.0228424	0.09
158.8142090	0.08
188.0176544	100.00
188.8394775	0.01
196.1828461	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1385
Annotation	Unknow
Peak:m/z	Relative Intensity
116.0486755	0.15
116.8382874	0.23
118.9142075	1.58
121.8966370	0.62
122.7667618	1.90
123.8987732	0.47
124.9447174	0.50
129.1017761	0.71
133.0395966	0.06
136.0271606	8.31
137.0947876	0.18
139.1443176	0.27
144.1352539	0.26
145.0769958	0.07
146.9704590	3.50
147.8871460	0.57
149.9375916	1.16
151.7486420	0.30
153.0123596	0.12
156.3676147	0.22
157.0476685	0.12
160.1726074	0.14
164.9960632	18.17
166.1138916	0.54
167.7811890	0.35
170.0935059	0.12
171.1343842	0.33
172.1324158	0.20
175.1233826	0.70
181.9558716	100.00
182.9523468	0.51
183.9833069	1.16
185.1297607	0.19
185.7888794	0.57
187.9655304	0.15
190.0546570	0.42
191.9969635	3.21
195.5690765	0.25
201.0860901	1.76
202.1260986	0.19
204.3187866	0.44
205.1694031	1.07
207.0066986	0.19
209.3757019	1.56
210.0017242	8.77
211.1139526	0.19
212.2253113	1.04
215.0724182	0.67
216.0266418	0.25
218.7391052	0.87
219.3580322	0.59
220.0280609	0.14
221.9812927	0.21
225.7042847	0.07
227.0590820	0.73
228.0350952	9.85
229.0299377	0.61
230.1795959	0.30
232.1128540	0.17
237.0951233	0.34
240.0026855	0.48
241.3667297	0.15
242.9741516	2.14
244.0406799	0.86
247.0885315	0.36
249.1953125	0.14
253.1536865	0.24
255.2129822	0.79
256.1395569	0.36
257.0968628	0.38
257.8980713	0.10
259.7469788	0.89
261.2873840	0.33
262.3523560	0.30
265.0801086	0.55
265.7661133	0.07
268.0523071	1.61
271.0146484	0.13
271.9962158	0.26
274.1539917	1.07
275.3928833	0.71
276.1456299	0.18
277.2372437	0.25
280.8934326	0.08
284.1476440	3.08
284.9353638	0.97
294.2269897	0.04
297.9337769	0.09
299.9925537	0.09
301.2691650	0.85
302.3623047	0.51
304.0202332	0.09
308.0202942	0.23
308.6537781	0.31
310.2209167	0.30
312.0508728	0.24
313.1839294	0.96
315.2910767	0.55
317.4062195	0.12
324.1387634	0.16
325.0508728	0.38
325.9869995	0.17
326.7086792	0.13
327.3488159	0.28
328.2977295	1.54
329.4666443	0.10
330.2034912	0.34
331.2697144	0.69
332.5996399	0.52
334.5157471	0.42
335.1411438	0.68
336.3124695	0.74
340.6535950	0.48
341.2776489	0.27
343.0535889	0.46
344.0729980	0.20
345.0989380	0.55
346.0589294	0.39
347.3562622	0.22
348.3120117	0.77
353.3649292	0.54
354.3373108	1.55
356.5828857	0.90
358.1618042	0.21
359.8317261	0.19
367.0230408	0.14
371.1562195	3.88
372.2832031	34.99
373.1929016	0.15
380.3630066	2.03
381.1158142	0.59
381.9270935	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.03
Annotation	Unknow
Peak:m/z	Relative Intensity
126.7746429	0.03
132.0352478	0.13
133.9772339	0.86
139.8983459	1.00
141.7975769	0.26
144.9968872	0.06
152.9279480	0.03
157.8432007	0.90
165.0665894	0.29
169.8069611	1.68
174.5853424	0.04
184.0072632	0.02
185.9144287	0.91
187.8574524	0.84
190.0011902	0.13
193.9492798	0.21
195.3930359	0.04
196.0244446	0.03
201.9975281	0.11
203.8983459	1.60
205.9737549	7.56
209.0191193	0.13
211.9748535	0.34
213.8696594	4.51
215.0813599	0.25
217.9533844	0.05
219.8603363	0.11
221.9484253	3.74
223.8291931	0.82
225.0239563	0.05
226.0460968	0.17
230.0208740	0.10
231.8007202	0.59
235.9764252	0.65
237.9971619	0.56
241.3820801	0.19
245.1278076	1.10
246.1286011	0.56
247.4548950	0.11
248.0907593	0.05
249.9072266	17.92
252.0090942	0.05
254.9882812	0.07
259.0484314	0.07
261.9455566	0.29
264.1592407	0.49
265.8792725	0.54
267.8610840	100.00
270.0994263	0.04
272.1001282	0.03
275.7431946	0.04
279.8675232	7.88
284.4980469	0.08
286.0504150	0.03
290.2427368	0.43
291.0077515	0.16
292.0625610	0.26
294.1411133	0.13
295.1895447	0.39
297.4818115	0.06
302.0528259	0.09
304.0930786	0.04
305.9440613	0.13
307.9668884	0.31
310.0386353	7.14
311.0892639	0.63
312.1350708	0.05
312.8239136	0.09
314.0859375	0.31
318.1506958	1.64
320.0102539	0.12
321.6136780	0.16
322.9537048	0.84
323.9964600	0.07
325.9818115	57.61
327.1243896	0.04
329.8041992	0.64
334.1405029	0.03
336.0990295	66.81
337.9953003	0.35
341.0711060	0.05
344.1920166	0.05
347.4042969	0.57
348.0587769	2.52
350.1107178	0.04
356.4587402	0.09
361.6345825	0.13
363.8253479	0.19
365.1539917	0.19
365.8373413	0.18
367.9365540	0.11
370.9547119	0.37
375.3916321	0.03
382.1267700	0.79
383.8596497	0.29
398.1642151	0.04
400.0871277	2.42
409.3522339	1.75
410.0481873	4.75
428.0464478	28.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1932
Annotation	Unknow
Peak:m/z	Relative Intensity
172.9573364	2.92
173.9925232	1.11
175.2266846	0.29
178.8945465	0.15
185.0064850	0.99
186.2595062	0.12
191.3016663	0.43
201.1806335	0.83
203.1528015	0.23
204.9393921	4.08
215.0065613	4.87
216.8812408	0.59
221.2965546	1.51
233.1330109	1.90
245.0770569	2.70
247.1656799	2.77
263.2707214	1.88
265.1357422	24.28
266.1752930	2.51
281.9105225	0.28
283.1809692	12.04
303.1071167	0.40
315.3740845	0.66
317.1517334	14.73
318.1742554	3.42
329.2029419	4.57
330.1014404	1.55
344.3905029	0.50
347.2777710	0.26
349.1774292	0.59
350.2531738	0.83
359.0127563	0.52
361.3256836	2.39
362.5014648	0.33
377.1121826	3.70
378.2667847	0.51
385.2984619	1.92
397.2657471	8.76
398.2034302	0.55
399.9489136	0.38
403.3035278	0.75
411.2133789	0.40
415.3031006	23.86
416.3146973	1.11
440.3405151	0.76
444.1945801	0.78
485.3039551	0.98
486.2492676	0.15
511.3796997	3.57
512.0972290	0.32
529.4640503	1.65
538.4788818	0.52
545.3353271	1.15
555.2106934	1.44
560.3828125	0.18
561.3594971	0.92
562.7933960	0.35
573.2789917	100.00
574.3854370	17.78
587.3884888	4.93
588.3386841	1.55
607.3948364	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
140.0462341	0.08
145.4008942	0.07
167.8994751	0.04
184.1318970	0.03
194.1826477	0.10
212.7816010	9.48
227.3761902	0.09
253.8018188	0.03
294.5907593	0.08
296.2738953	8.82
296.8829956	66.53
349.8014221	0.18
378.8707581	0.03
380.5817261	100.00
381.3356323	0.14
384.1801758	0.14
417.9947205	0.08
418.8851013	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.651
Annotation	Unknow
Peak:m/z	Relative Intensity
111.8583069	0.17
119.8655396	0.03
123.0081635	0.10
129.9783630	10.46
131.0643921	0.09
132.0627747	0.13
135.1770477	0.05
136.8964539	0.09
138.1308289	0.07
146.0226135	0.03
146.6324310	0.02
150.2104340	0.02
152.8535156	0.11
160.4602814	0.02
170.0947266	0.05
177.0800934	0.33
178.9800720	0.09
181.0160522	0.02
185.0709381	0.03
191.1278992	0.05
192.0458832	0.43
195.1856079	0.07
196.2875977	0.10
197.1244507	0.08
203.1156616	0.02
210.1134949	0.03
217.1507568	0.10
221.0779724	0.10
226.3208313	0.12
227.3413391	0.06
231.0110474	0.29
235.1558533	0.49
239.8051147	0.90
241.1437683	0.07
244.2335205	0.08
247.9771729	0.10
249.1798706	0.69
249.7952881	0.03
250.7857971	0.16
253.3970032	0.76
255.2050171	0.36
256.1014099	0.11
258.1336670	2.19
259.1726074	0.62
260.4680786	0.04
262.1423950	0.56
263.0828552	0.02
266.2438965	0.16
267.3431396	0.32
268.9947510	0.03
273.1437988	0.22
274.2851868	0.03
276.0884705	1.74
277.0742188	0.23
278.2640991	0.03
279.4310913	0.05
280.2349243	0.05
281.2200928	0.14
282.3245850	0.61
284.2623291	0.15
285.1846313	1.72
285.8453674	0.08
287.2261658	0.09
291.0688782	66.25
291.7086182	1.59
292.5396729	0.25
293.6125793	0.11
294.9541016	0.09
299.7781982	0.27
300.3892822	0.09
301.2922974	0.18
302.2809448	0.20
304.6686096	6.96
305.3608398	1.21
306.3453674	0.09
307.2495422	0.35
308.1922607	1.14
313.7370605	100.00
314.7912903	0.10
315.4824219	0.02
317.2558594	0.02
321.4632874	0.03
333.2933655	0.05
337.3214111	1.41
338.5968323	0.19
339.2848206	0.69
342.0057068	0.05
351.3630371	1.33
352.5338745	0.17
360.1737061	0.04
366.3962097	0.02
369.3465576	5.55
370.2583923	0.12
371.5767822	0.08
376.8749084	0.26
392.2001648	0.04
394.2736511	0.11
395.2644653	0.55
422.2274475	0.28
426.2979431	0.04
427.1856079	0.02
440.0893250	0.09
443.2689514	0.07
444.7286682	0.03
449.4545593	0.06
451.6246643	0.18
452.4429016	0.22
457.6118469	0.08
458.5139465	0.03
460.1040955	0.02
461.4646301	0.06
478.3716125	0.12
479.3478088	0.10
480.5076599	0.13
488.1278687	0.09
497.4294739	2.03
498.5527649	0.13
505.3975525	0.04
506.2572327	0.31
515.3401489	14.04
516.4492798	0.82
523.5813599	0.03
533.3853149	0.13
534.6522827	0.03
543.9970703	0.02
547.2272949	0.04
551.4214478	0.89
563.1459351	0.07
569.4458008	0.66
581.3147583	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.0983
Annotation	5-(3',5'-Dihydroxyphenyl)-gamma-valerolactone 3-O-glucuronide
Peak:m/z	Relative Intensity
133.8820496	0.15
135.0715332	7.86
144.9968262	0.05
152.8948364	0.30
163.1597137	0.18
166.1102142	0.24
173.2185059	0.09
175.0657654	0.36
176.9082642	0.63
179.0535889	39.47
190.1481476	0.47
198.7332611	0.19
205.1871948	0.33
217.2325439	0.12
221.0493011	2.14
232.1568909	0.11
234.8108826	0.42
241.2181396	0.17
244.9688110	0.45
247.4171143	0.16
263.4606323	0.18
279.1337585	0.08
281.3615417	0.17
287.1665039	0.37
289.2020569	0.05
293.2926025	0.18
305.2095337	0.12
311.1672974	0.10
315.1744995	0.17
319.5458984	0.09
321.1475220	0.16
323.1459045	100.00
324.8883667	0.15
336.5917969	0.34
337.4481506	0.86
338.4287415	2.10
339.2492371	1.67
339.9138794	0.31
341.2098999	68.48
347.3722229	0.22
354.5684509	0.16
355.3928223	0.11
363.1341858	0.21
365.1578979	1.42
367.9560547	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	888.582
Annotation	Unknow
Peak:m/z	Relative Intensity
260.9956055	0.06
320.2510071	0.07
407.3101807	0.11
478.0510864	0.06
610.6540527	0.30
614.2352295	0.09
618.3947754	0.26
624.6511841	0.07
670.6561890	0.07
687.6465454	0.05
737.5745239	0.13
756.6716919	0.15
772.8485718	0.11
805.4790039	0.12
836.5694580	0.44
854.9614258	9.16
856.5828857	0.15
858.2572021	0.33
860.7868652	0.17
861.6525269	0.59
870.4374390	0.23
871.3390503	0.29
872.2271118	0.12
873.3764648	0.52
889.6464233	0.23
891.0328979	0.06
916.1081543	0.44
927.7008667	0.31
944.1587524	0.53
967.0139771	0.25
995.7709961	1.66
1013.5261230	0.92
1014.2807620	0.09
1027.5521240	14.30
1028.5837400	0.87
1030.5968020	0.10
1032.6691890	0.41
1035.6230470	0.19
1036.7416990	0.12
1038.8861080	0.06
1063.8220210	1.13
1068.3592530	100.00
1069.5266110	6.17
1070.5581050	2.09
1071.4404300	1.00
1072.4746090	0.53
1073.3018800	0.63
1074.1601560	0.47
1074.9553220	0.26
1077.2097170	0.81
1080.1672360	0.59
1084.0639650	0.52
1085.3059080	0.04
1092.9694820	0.50
1095.6135250	0.24
1123.6473390	0.38
1138.4482420	0.08
1148.7239990	0.11
1154.6633300	0.50
1161.0068360	0.39
1188.6171880	0.49
1194.7680660	0.15
1246.0339360	0.68
1255.2458500	0.60
1259.1761470	0.52
1265.0389400	3.00
1282.9456790	0.51
1296.1700440	0.53
1305.3831790	0.23
1314.0546880	0.55
1321.0732420	0.15
1327.2243650	2.13
1334.2615970	0.09
1345.1081540	0.20
1350.9398190	1.94
1363.5417480	0.52
1369.5745850	0.47
1376.6412350	0.57
1395.6937260	0.51
1482.8712160	0.15
1544.8651120	0.15
1643.2037350	0.12
1645.9881590	0.07
1649.7567140	0.07
1652.5413820	0.41
1669.7435300	0.05
1682.5064700	0.35
1693.5510250	0.45
1694.9064940	0.39
1775.4964600	4.96
1844.0744630	1.00
1852.0889890	0.06
1884.0150150	0.07
1915.4937740	12.89
1969.6314700	0.59
1995.0977780	0.04
1999.4041750	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2174
Annotation	Unknow
Peak:m/z	Relative Intensity
83.9153442	1.73
100.9395523	1.16
128.2422485	0.46
129.1631775	3.18
130.0225220	11.84
130.9811401	0.31
135.0244141	0.54
145.1791534	0.27
146.9547119	100.00
148.9186401	0.40
151.1349030	0.59
155.2251282	0.13
156.8379669	0.12
161.0676880	0.47
172.9812775	1.11
191.3479004	0.08
197.1284790	0.65
210.8460083	0.13
219.0530396	1.01
220.7259521	0.67
229.3975830	0.16
232.1997070	0.08
234.7765503	0.40
237.1806030	2.91
240.4292603	1.32
245.7052612	0.56
246.9556885	5.79
247.8990479	0.13
250.1050110	0.16
251.9109802	0.97
252.8168335	0.94
254.2593689	2.37
257.0536499	0.97
264.4965820	0.68
266.3059692	0.36
270.2289124	0.68
274.8444824	4.10
275.4635010	2.38
276.1059570	0.12
277.7829895	0.23
279.1321106	0.20
284.6902466	1.48
285.3649902	1.22
286.2700806	1.22
293.1632080	0.55
301.3984680	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.0208
Annotation	9-Riburonosylhypoxanthine
Peak:m/z	Relative Intensity
117.0113678	0.77
140.9617615	1.41
230.6927795	2.18
235.1153870	1.05
259.0362549	0.65
265.1275940	1.14
277.0813293	80.50
302.9422302	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.2881
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9643860	0.30
176.9452820	0.41
179.0222015	1.84
179.9536591	0.09
183.0954132	0.13
184.0543213	0.05
187.1794128	0.17
188.2464294	0.12
189.2835388	0.18
191.0000610	0.15
193.0067749	0.11
198.7436523	0.08
201.0561676	0.31
203.0915680	0.69
208.0963745	0.13
210.9394531	0.37
215.1588440	0.08
220.8343048	0.12
221.4498138	0.03
225.1937103	0.06
226.3634186	0.04
229.3807068	0.42
230.9736633	0.06
232.0520325	0.07
233.0744781	0.79
237.2780457	0.04
238.8142700	0.25
240.9847717	0.22
243.0014801	0.22
245.2758026	0.14
247.1123657	0.11
249.2420349	0.03
254.2146454	0.13
255.3039398	0.06
256.2767944	0.17
257.1654053	2.12
259.1249390	0.53
265.0662231	0.33
267.2006531	0.27
268.2127075	0.74
269.2357178	0.58
270.2192688	0.07
271.0946045	0.14
272.1318970	0.04
273.0298767	1.35
274.1163025	2.08
277.0690918	0.12
279.1286621	0.16
281.3981323	0.20
282.0454712	0.06
283.3770752	0.46
284.2587280	0.07
288.2875366	0.18
289.4569092	0.47
290.2429810	0.79
291.2327881	1.87
292.2983093	0.08
293.3657227	0.04
294.2154541	0.18
297.1050110	0.16
299.2454834	0.11
301.2861938	0.29
303.3648376	0.64
304.2648315	0.07
305.0660400	0.20
306.1871948	0.15
307.0593872	0.19
308.1799316	4.37
309.1170654	1.00
310.1344604	0.30
311.3143921	0.02
312.4122620	0.18
314.3629150	0.21
315.3604126	0.31
316.4534912	0.40
318.2704468	0.33
319.2670898	0.42
320.2256165	0.13
321.1033936	0.35
323.4682312	0.07
325.1644897	0.57
326.2738037	0.40
327.4031982	0.16
328.5562134	0.21
329.2513428	0.13
329.9271851	0.20
331.3914795	0.28
332.0636597	0.08
333.8314819	0.11
335.2611694	0.09
336.4608154	0.14
337.4152222	0.25
338.5756836	0.04
339.4766846	0.06
340.5230713	0.25
341.2197266	0.09
342.5231934	0.12
344.3035278	0.09
345.4750366	0.09
347.5874634	0.58
348.2299194	1.87
349.3214722	1.47
350.4810791	0.05
351.2962646	0.29
352.2441406	0.09
354.4327393	0.11
355.4120483	0.34
356.1695557	0.37
358.0357666	0.15
360.4733276	0.07
365.3657837	0.85
366.3447876	5.09
367.6434326	0.21
369.2308960	0.30
371.1281128	1.45
373.0922241	0.39
376.1828613	0.99
379.3261719	0.50
383.5057983	0.48
384.2429199	5.91
385.5668335	0.12
386.2402344	0.06
388.3704224	0.09
389.9846802	0.21
391.5573730	0.34
393.3348999	0.91
394.4639282	1.10
395.3966675	0.25
397.3347778	10.69
398.2737427	0.34
403.2639160	0.05
404.2642212	0.28
405.2276611	0.59
407.3326416	0.58
408.3552856	0.05
409.2715454	0.21
410.7349854	1.67
411.3746338	16.10
412.3140259	0.87
415.6877441	0.08
417.4865112	0.26
418.5828247	0.14
419.1845093	0.17
420.4893188	0.11
421.3298340	0.10
423.1240845	0.10
425.0532227	0.39
427.3872070	0.04
429.4290161	0.46
433.3543091	0.79
434.0629883	0.10
435.4522705	0.37
437.1196289	0.19
440.3900146	0.04
442.5509644	0.08
449.3648682	0.41
450.3110962	1.11
451.3516846	34.25
452.2280273	0.75
453.1560669	0.22
454.1648560	0.52
455.4338379	0.31
457.8286743	0.32
463.1727295	0.08
466.1564331	0.06
467.4547729	0.12
469.2833862	100.00
470.2673950	1.02
472.4967651	0.12
477.1372681	0.14
481.5456543	0.17
487.2507935	14.92
501.6455688	0.05
505.3558960	0.29
507.5118408	0.21
508.7919922	0.19
512.3577271	0.11
517.4749146	0.30
522.8825684	0.26
523.5881348	0.40
525.8333740	0.13
526.4367065	0.58
528.1829224	0.10
530.3601685	0.04
533.4804077	0.33
534.5979614	1.09
536.3131104	0.11
537.3707275	0.46
540.5386353	0.33
541.4558105	2.01
543.4304199	0.10
550.9486694	0.27
551.5961914	0.17
553.4273071	0.65
554.1359253	0.12
557.4570923	0.15
558.3550415	0.06
561.3108521	0.12
569.7888794	0.19
571.7063599	0.40
577.4951782	0.04
579.4751587	0.27
580.4201660	0.77
581.2561646	0.29
585.4768677	0.27
586.2525635	0.06
588.6181641	0.05
597.4317017	1.74
598.4254761	5.36
599.3328247	0.31
626.2079468	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.32
Annotation	Yunnanxane
Peak:m/z	Relative Intensity
173.0261383	0.38
185.0692291	0.34
194.9202271	0.12
208.2687531	0.30
209.1843567	0.13
211.4656982	0.07
225.0343018	0.05
226.0638123	1.12
227.0399170	0.33
228.9436646	0.33
233.0701294	0.05
243.2992249	0.22
255.3197937	0.18
260.8145142	0.35
297.7492676	0.69
303.4382935	0.25
309.8286743	0.15
310.5454712	0.12
313.3405151	0.44
314.0398560	0.14
317.6147461	0.33
319.3743896	0.76
320.0043335	0.13
321.4569702	0.05
332.4917603	0.18
334.7624512	0.89
337.4131470	0.13
349.7177734	4.49
350.8500366	0.06
365.5540771	0.26
367.6865845	0.09
382.7080688	0.48
383.6324463	0.16
389.4019775	0.15
397.3082275	0.17
405.8970947	0.10
408.3215332	0.32
411.3880005	0.14
413.9336548	0.22
414.6020508	0.17
417.5547485	0.06
420.8876953	0.08
422.1441650	0.15
430.9434814	0.08
448.0601196	0.08
449.9707642	0.11
453.3609009	0.07
454.3280640	0.35
455.5419312	0.37
462.2327881	1.71
462.9228516	1.07
465.5286255	0.32
466.1536255	0.12
468.3744507	1.41
472.3127441	1.06
473.2076416	0.32
483.6340942	0.13
487.6162109	2.82
488.6052246	2.93
489.4520264	1.34
492.4311523	0.37
493.3562622	0.62
494.5874634	0.24
496.4075928	0.73
502.3922729	0.16
507.1844482	0.90
509.6362305	0.18
510.6854858	0.47
512.9395142	0.09
515.0444946	5.06
515.6913452	0.62
519.1843262	6.56
520.3265991	11.28
521.5620728	7.87
522.7672729	0.91
523.8538208	0.80
525.9857788	100.00
526.7397461	1.75
527.8765259	1.49
528.6824951	0.73
530.4476929	12.82
531.7097778	4.19
532.6977539	7.00
533.4671021	0.34
534.6189575	1.07
536.3847656	1.61
537.5906372	0.61
538.5891113	0.71
541.0133057	5.39
542.2512207	1.14
543.5947876	3.30
544.6972046	1.60
545.3582764	9.75
546.1631470	1.04
548.2842407	10.31
550.0718994	7.81
551.2017822	0.29
552.0338745	1.99
552.8228760	0.35
554.2588501	0.95
567.5932007	0.24
568.6409912	0.99
571.6026611	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.4534
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
249.2916718	0.01
308.2128296	0.04
343.6469727	0.01
359.4651489	0.02
433.2808838	0.05
449.7299194	0.03
455.5016479	0.02
471.1198730	0.06
493.3182373	0.02
495.6713257	0.07
501.4262085	0.06
578.6431885	0.02
615.5968628	0.14
618.9638062	0.04
622.9867554	0.04
633.6743774	0.32
638.3031616	0.03
675.8103027	0.06
679.5006714	0.04
687.2492065	0.05
706.4815063	0.06
707.5978394	0.05
711.3366089	0.03
713.3204346	0.03
735.6607666	0.03
746.3712769	0.01
749.6340942	0.14
750.7763062	0.02
767.8765259	0.08
775.5120239	0.02
776.6251221	0.16
777.5228882	0.06
795.5301514	100.00
796.4779053	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	645.2569
Annotation	Cineracipadesin E
Peak:m/z	Relative Intensity
275.4698486	0.03
290.3273926	0.05
319.2520752	0.60
320.1764526	0.39
333.4178467	0.03
346.4052734	0.01
385.7377319	0.13
443.3861084	0.03
451.3876343	0.02
462.6189575	0.07
497.6151123	0.21
498.4110107	0.02
528.5255737	0.10
530.7970581	0.03
539.2938843	0.06
541.2542114	0.12
542.4503784	0.08
557.3791504	2.12
558.4019775	0.37
565.6666870	0.06
572.4932861	0.03
583.4191284	0.42
584.6475830	0.10
589.7388306	0.03
595.5120850	0.09
601.3560181	100.00
602.3999634	22.47
603.0845337	0.04
609.2152100	0.07
616.6025391	0.04
627.4183960	1.92
628.2659302	0.10
646.2421875	3.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	905.4505
Annotation	Unknow
Peak:m/z	Relative Intensity
289.9565430	0.96
305.1018982	0.91
591.4445190	1.60
621.4359741	3.04
622.9639282	1.25
623.8176270	4.16
637.4425049	0.63
638.7290649	0.60
639.7714233	0.36
676.1199341	0.53
725.7125244	1.18
842.2971191	2.06
860.7654419	10.79
861.7277832	11.40
885.1116333	3.88
886.5193481	5.97
887.3980103	1.56
905.5881348	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	400.83
Annotation	Unknow
Peak:m/z	Relative Intensity
180.7252197	0.20
215.1649933	0.10
232.8670654	0.52
253.0334778	0.03
256.0625305	0.02
271.0085144	0.01
273.0101318	0.02
298.9750061	6.03
302.1286316	0.28
308.9289551	5.21
312.0073853	0.13
312.8283386	0.04
316.8218384	7.84
317.4303284	0.05
336.9208374	44.02
354.7516785	100.00
355.3553772	0.46
382.7476807	19.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.1605
Annotation	Unknow
Peak:m/z	Relative Intensity
233.1763458	0.30
248.1522827	0.08
284.1582336	0.39
301.3362732	0.54
338.1769409	0.29
359.0545044	0.35
377.3497925	0.68
380.1145325	0.45
395.1626587	0.19
413.1721802	0.09
480.4114380	0.17
633.2879639	0.35
711.1293335	0.79
738.5559692	0.76
758.0147705	0.24
759.0757446	0.42
770.7792969	1.89
771.6716919	1.73
775.1942139	0.57
776.1494141	0.23
776.8041382	4.53
780.8531494	0.64
784.7992554	2.21
788.5150757	7.75
791.1950073	3.91
792.0903931	18.69
793.0738525	3.18
794.1264038	2.84
795.0825195	0.58
796.3785400	0.25
797.1168823	8.90
798.0728149	4.28
798.9480591	1.90
800.2423706	1.91
801.3250122	3.06
802.6597290	2.79
805.7376099	12.31
806.4375000	1.53
807.6732788	8.61
808.2749634	0.56
809.4522095	18.18
810.4370728	3.24
811.3020630	15.15
811.9160156	8.20
812.8373413	4.20
813.9767456	4.36
814.7711792	13.54
815.3884888	14.80
816.2366333	0.41
818.1568604	3.05
819.0830688	7.45
820.0975342	7.23
820.9542847	0.99
821.9133301	6.00
822.7503052	2.26
823.5408325	3.32
825.0902710	1.64
828.5518799	0.36
844.4871216	1.47
912.9431152	1.39
921.7841797	0.61
922.7082520	1.08
923.7894897	1.09
925.0102539	0.73
926.0329590	0.07
928.2418823	1.40
929.7106323	5.49
930.8471069	2.02
931.4775391	1.03
932.4111938	4.24
933.2817993	0.88
933.9436646	1.60
935.3173218	1.74
937.3498535	10.48
939.1956177	2.34
940.4528198	1.31
941.6809082	6.48
942.5598145	0.09
944.3961792	4.03
945.0531616	3.74
947.0713501	1.99
947.8579712	1.09
949.9044800	5.08
950.6956177	2.65
951.6962891	5.72
953.8778687	4.46
955.4284668	7.74
956.1601562	2.83
957.2589722	3.81
958.0417480	2.30
959.0065918	5.93
961.3983765	17.76
962.3696289	0.99
963.8342896	8.56
964.5666504	7.67
965.8713379	17.12
967.1134644	4.99
967.9191895	3.06
969.7023315	0.94
970.6954956	3.15
972.0044556	10.52
973.1875000	7.28
974.1472778	4.17
975.4233398	2.34
976.1833496	3.93
977.2248535	2.06
978.4957886	13.93
979.2263794	6.66
980.2736816	10.84
981.2546997	2.39
981.8609009	2.93
983.3266602	26.83
985.2543335	13.10
986.2561646	6.82
987.5163574	32.76
988.3456421	4.46
989.7092285	32.32
990.6557617	1.62
991.7229004	7.68
992.3764648	94.46
994.1523438	5.41
994.8792114	1.00
996.1381226	7.74
996.7777710	100.00
997.5515137	22.65
998.5516968	1.97
999.1762695	1.82
1000.9331670	1.39
1002.2042850	1.88
1003.3566890	3.18
1004.7456670	3.93
1005.6563110	1.96
1006.8103030	15.37
1007.6243290	8.97
1009.3474730	10.26
1010.0076290	0.20
1011.3716430	13.73
1012.1725460	0.09
1012.9463500	1.11
1014.0187380	61.10
1014.8251950	7.56
1015.6477660	2.55
1016.3325810	1.09
1017.2538450	1.17
1018.4470830	93.43
1019.1100460	33.34
1020.3768920	18.43
1021.1738890	15.11
1022.8434450	21.29
1023.7212520	1.99
1024.9482420	0.15
1027.6643070	0.86
1029.0910640	1.40
1032.0815430	1.05
1033.1669920	0.34
1045.6479490	0.45
1065.4598390	0.39
1092.2425540	0.91
1095.4774170	0.15
1099.1860350	0.75
1105.8037110	1.67
1124.3741460	1.48
1127.1773680	0.32
1128.0975340	0.70
1129.3452150	1.53
1141.0010990	0.93
1142.7940670	0.33
1145.3801270	1.45
1147.0700680	1.08
1148.4669190	0.34
1163.0666500	1.17
1167.5789790	0.57
1173.5456540	1.10
1175.7580570	0.91
1178.1427000	0.74
1180.0583500	1.22
1185.1691890	1.44
1186.2019040	1.11
1190.1384280	0.55
1191.0458980	0.75
1193.0932620	1.60
1194.2220460	0.84
1197.0058590	2.36
1198.6323240	1.40
1200.0229490	0.81
1202.0314940	0.10
1203.9169920	4.94
1204.7526860	2.93
1206.7757570	3.87
1207.6062010	0.92
1210.5892330	1.29
1212.9959720	0.96
1214.7675780	0.76
1216.0828860	1.41
1223.1649170	2.09
1224.6711430	4.49
1225.6289060	1.47
1227.0952150	1.59
1227.9466550	0.47
1228.9556880	1.92
1230.3566890	3.20
1231.3215330	0.45
1232.3648680	1.93
1233.4560550	0.93
1234.2989500	1.26
1236.2585450	1.32
1237.3422850	0.78
1238.8044430	3.77
1239.5673830	4.28
1240.7565920	2.11
1242.3515620	7.21
1243.7133790	4.16
1246.5601810	1.22
1247.4973140	2.32
1248.7789310	3.49
1249.6964110	4.83
1251.0917970	1.61
1252.4278560	5.01
1253.3656010	6.99
1254.4871830	3.33
1255.2814940	1.60
1256.2862550	0.88
1257.6458740	2.76
1258.3070070	34.87
1259.0035400	36.42
1259.8209230	1.66
1260.4582520	1.18
1262.0177000	0.75
1263.0621340	2.33
1264.1800540	4.68
1265.3614500	0.85
1266.2679440	1.07
1267.5166020	3.42
1268.4450680	5.54
1269.3970950	4.68
1270.6110840	3.99
1271.9530030	6.28
1273.8435060	3.90
1275.0084230	4.51
1275.9512940	2.67
1276.6098630	0.40
1277.5870360	5.54
1278.4399410	7.59
1280.4761960	2.48
1281.5140380	26.18
1282.2167970	11.16
1283.2655030	3.65
1284.7138670	1.80
1285.3992920	1.11
1287.0623780	24.74
1287.7252200	61.16
1288.9337160	4.26
1290.2066650	2.45
1291.1435550	2.72
1293.1352540	3.57
1294.0681150	3.97
1296.1014400	12.67
1296.8597410	8.87
1297.5909420	1.03
1300.2603760	1.46
1301.6235350	1.79
1302.6173100	0.18
1304.4659420	1.05
1306.2659910	1.01
1308.2069090	0.67
1309.3947750	0.23
1310.4620360	1.33
1311.5489500	1.75
1312.2731930	0.24
1314.0827640	4.05
1314.7828370	0.22
1318.8798830	3.09
1319.5391850	3.74
1322.2762450	2.35
1323.0745850	1.38
1325.1699220	10.60
1325.9923100	8.37
1328.6182860	4.06
1329.6951900	2.25
1331.5545650	0.79
1333.9932860	0.37
1340.6727290	0.18
1350.1263430	0.19
1353.9244380	0.45
1357.3156740	0.97
1359.4954830	0.62
1368.8986820	0.18
1384.9066160	0.74
1387.8778080	0.11
1391.5523680	0.24
1432.9534910	0.18
1466.5311280	0.65
1467.1553960	1.06
1477.5578610	0.17
1487.8442380	0.70
1497.5551760	0.11
1498.7961430	0.41
1522.0472410	0.36
1541.0057370	0.08
1551.9897460	0.70
1561.2467040	0.53
1562.4959720	0.86
1574.3939210	1.06
1612.7481690	0.29
1613.4992680	0.57
1621.7113040	0.90
1629.8165280	0.26
1696.1676030	0.24
1699.1346440	0.14
1703.4823000	0.82
1728.2708740	0.71
1777.5040280	0.59
1780.2213130	1.29
1783.1998290	0.35
1817.2398680	0.12
1828.1158450	1.09
1842.2935790	0.23
1845.5518800	0.68
1846.2761230	0.49
1854.5457760	0.46
1901.1673580	0.13
1901.9727780	0.47
1919.6911620	0.21
1959.8029790	0.21
1973.1885990	2.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1089.4254
Annotation	Unknow
Peak:m/z	Relative Intensity
376.5982361	0.35
912.3023682	0.31
930.4804688	0.34
939.2808838	0.11
1004.4974370	0.61
1005.4732670	0.25
1007.6105960	0.25
1010.6206050	0.50
1023.3332520	1.05
1031.1103520	0.93
1044.8393550	0.74
1046.8811040	0.19
1052.6973880	1.31
1056.5671390	0.91
1059.0166020	1.07
1067.8504640	0.45
1068.4553220	0.38
1070.7241210	0.19
1071.6752930	1.02
1074.6434330	0.08
1090.0756840	100.00
1090.9271240	5.85
1092.1000980	0.24
1092.8201900	0.36
1093.5869140	1.14
1097.8181150	0.27
1098.7260740	0.13
1216.3385010	0.27
1260.6462400	0.22
1312.2645260	0.32
1324.6527100	0.18
1341.8900150	0.37
1349.7551270	0.75
1390.6105960	0.67
1420.2049560	0.13
1438.6597900	0.13
1442.7495120	0.06
1467.8239750	0.55
1495.6119380	0.55
1514.7810060	0.35
1534.3879390	0.40
1558.1807860	0.43
1786.1160890	0.12
1840.3096920	1.27
1859.2835690	0.24
1865.6721190	0.06
1904.4914550	0.13
1915.9431150	0.22
1972.4483640	0.69
1985.4722900	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.44
Annotation	Bryostatin 1
Peak:m/z	Relative Intensity
833.8173218	7.88
858.7368774	0.78
903.4231567	100.00
904.2617798	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	707.4086
Annotation	Unknow
Peak:m/z	Relative Intensity
198.1666412	0.18
213.2777710	0.08
224.3421021	0.10
241.1912079	0.15
243.0352478	0.12
244.2307739	0.16
247.4622803	0.40
249.2883759	0.41
261.3584290	0.11
271.0773926	0.07
278.5823364	0.12
279.2177734	0.46
282.4082642	0.31
291.3349304	0.19
293.2783508	0.05
305.5523071	0.64
308.4645386	0.31
309.6671753	0.04
315.4774170	0.08
317.3105774	0.87
318.0441895	0.22
331.4929199	0.13
335.2039795	0.70
352.1881714	0.07
353.4084473	0.24
359.4715576	0.52
361.0871582	0.21
364.9799194	0.16
382.3137817	0.53
392.2163086	0.11
419.2227173	0.06
423.2372437	0.15
426.6652222	0.09
431.4187622	0.11
435.4274902	0.29
436.3896484	0.29
437.5665894	0.23
438.7057495	0.32
439.3789673	0.23
443.6083984	0.09
448.5088501	0.22
453.4253540	0.66
456.3409424	0.19
459.2911377	0.19
461.6791992	0.05
465.3923340	0.25
471.6033325	0.33
472.8110352	0.46
474.5123291	0.27
485.6141968	0.05
488.9157104	0.29
489.6720581	2.40
494.6980591	0.19
495.6777344	0.14
497.4062500	0.40
498.5084229	0.14
499.4296265	0.24
501.5001221	0.45
507.1363525	0.06
515.3747559	0.46
516.5894165	1.44
522.6173706	0.38
527.5614624	5.54
528.6210938	1.88
529.3919067	1.38
532.3394775	0.30
533.2656860	0.13
535.4945068	1.19
539.3880615	0.13
540.5697021	0.19
543.6489868	0.61
545.4633179	100.00
546.4879150	3.01
547.5744019	0.14
551.7007446	0.13
553.5034790	0.26
557.6611938	1.04
569.5678711	1.76
570.6564331	0.39
572.1217041	0.11
581.4623413	0.34
587.4252319	3.61
588.8536377	0.17
589.7324219	0.20
593.6514282	0.35
598.0056763	0.24
599.7479248	0.59
603.3247070	0.17
605.7528687	0.23
610.4730835	0.12
611.7176514	0.68
615.6314087	0.25
617.6149902	5.01
618.6143188	0.69
625.5932007	0.39
629.9564209	0.53
630.5905151	0.04
633.6627808	1.53
647.7097778	0.89
648.3944702	0.17
649.3752441	0.31
651.0684204	0.44
653.5625000	0.34
657.5689697	0.48
661.5686646	0.18
665.6067505	0.10
671.5104370	1.24
677.5816040	0.30
678.6941528	0.22
679.5413818	0.73
689.5703735	16.31
690.6851196	1.28
707.4021606	0.32
708.6931763	19.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.0616
Annotation	Uralenneoside
Peak:m/z	Relative Intensity
92.8373413	0.14
106.8653870	0.58
107.9468460	4.51
108.9918594	7.82
111.1576843	0.04
114.0278320	0.08
120.8581390	0.56
122.1385651	0.09
123.0327454	0.44
130.0112305	1.06
131.9999695	0.07
133.0921783	0.34
135.0115356	0.59
136.8522644	0.37
146.9630737	0.11
148.8558044	0.07
150.3997345	0.26
151.0072632	2.07
151.9371796	26.06
153.0379333	100.00
161.1759186	0.25
163.0854034	2.40
165.0673523	4.03
173.1019440	0.16
176.9835815	0.45
179.0645447	1.82
181.1428070	0.85
189.0711823	0.20
189.9430237	0.14
191.1501923	0.46
193.2550659	0.23
195.1057434	0.97
198.9934692	0.09
201.1749878	0.18
205.0756531	0.62
206.9945374	0.78
219.2318420	0.39
222.2194519	0.22
223.1275024	0.61
225.1126404	2.89
227.0221252	0.09
228.9110718	0.13
230.1890869	0.21
237.2048950	0.58
240.2402649	0.17
241.2510376	0.82
249.3046570	0.24
255.2572021	0.17
256.0018921	0.17
264.9726562	0.05
267.1661987	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	370.16
Annotation	PC(3:0/3:0)
Peak:m/z	Relative Intensity
108.9234161	0.07
119.2132950	0.06
120.8890152	0.26
122.0392761	0.04
124.9914932	0.10
132.8305359	0.03
136.9418945	0.04
141.9307251	0.08
145.9105835	0.03
150.2344055	0.04
150.8597107	0.09
155.0487976	1.07
162.8453064	0.12
164.9234009	0.03
165.8540649	0.05
175.9243774	0.03
178.8971252	0.47
180.0059052	0.04
184.2734528	0.14
191.2849121	0.11
191.9431610	0.02
197.1009979	0.09
198.7780304	0.02
204.2876892	0.08
206.0988464	0.05
207.1485291	0.06
208.3082581	0.06
210.9332581	0.23
212.8931122	0.03
222.8394470	0.18
226.5544434	0.08
229.1015015	21.09
239.2803345	0.07
240.2510376	0.10
256.3134460	0.17
259.0221863	0.07
261.5908203	0.03
264.3120728	0.04
267.2230835	0.08
272.1370544	0.12
277.0566406	0.06
278.1352539	0.03
280.2339478	0.15
282.5537415	0.15
283.2509766	0.19
288.1972046	0.17
289.2019653	0.21
295.0507202	0.48
296.5119934	0.20
303.7916870	0.08
307.8046265	0.07
309.1362915	0.07
310.1576843	0.07
313.1521606	0.17
316.0258789	0.03
320.7239075	0.05
325.1145935	1.01
326.9500732	0.98
328.1367188	0.31
329.3442383	0.08
334.2517700	3.16
335.0874634	0.08
340.5383301	0.30
342.2954712	0.57
346.7425842	0.24
349.1631165	0.16
352.1792908	100.00
353.3914490	0.32
358.2110291	0.12
360.4762573	0.38
361.9254761	0.07
370.2945251	0.05
381.2215881	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	855.873
Annotation	Unknow
Peak:m/z	Relative Intensity
254.1204834	0.09
288.3660583	0.06
308.3584595	0.09
455.5607300	0.03
476.8447266	0.26
532.6524658	0.15
543.7552490	0.09
570.5415649	0.08
597.4699707	0.09
694.6963501	0.07
797.2612915	0.29
800.0415649	0.78
805.9965210	0.26
817.3390503	0.19
821.5027466	0.90
824.2783813	0.38
828.3999634	41.08
829.6583862	1.26
830.7576294	0.18
832.3070068	0.04
837.2792969	0.31
838.5874023	0.08
839.9401245	0.04
840.9986572	0.47
857.8560791	0.89
866.6731567	0.05
878.6144409	0.51
967.4558716	0.15
973.7293091	0.02
990.2509155	1.15
995.4461060	0.23
997.0111694	0.16
1006.4348750	0.16
1007.2778320	0.23
1008.4099730	0.53
1009.5565800	0.38
1012.4248660	0.06
1014.1583860	0.19
1023.2504270	0.82
1027.3820800	1.26
1029.1088870	0.49
1033.3312990	8.49
1034.0983890	1.85
1036.2883300	0.73
1036.9194340	0.16
1039.7900390	0.07
1040.5490720	0.09
1042.4803470	0.25
1046.0773930	0.32
1047.1347660	0.09
1052.8497310	0.19
1055.3469240	0.12
1057.3724370	0.88
1060.8286130	0.70
1065.4865720	0.47
1066.1564940	0.56
1066.8293460	0.04
1067.9901120	0.05
1071.5227050	12.43
1072.2675780	15.24
1073.2207030	1.08
1074.0681150	0.18
1074.7111820	0.47
1077.2526860	0.63
1079.6818850	0.80
1080.4506840	0.23
1084.3713380	0.54
1089.3918460	0.37
1090.1950680	0.50
1092.2072750	0.49
1093.4152830	0.04
1094.3767090	0.69
1098.2773440	3.01
1098.9097900	0.71
1099.6013180	0.22
1104.1208500	100.00
1105.0163570	17.65
1105.8447270	0.63
1108.2528080	0.13
1109.1621090	0.34
1110.0039060	0.37
1113.4584960	0.08
1115.3663330	0.21
1142.0681150	0.40
1165.7893070	0.22
1184.4743650	0.07
1222.6533200	0.32
1265.8348390	0.30
1269.1970210	0.18
1284.3118900	0.46
1335.9581300	0.10
1340.4672850	0.20
1390.6319580	0.12
1427.0091550	0.54
1462.7072750	0.19
1475.6698000	0.11
1504.5629880	0.28
1505.3359380	0.30
1512.0130620	0.32
1530.9577640	0.23
1557.1275630	0.12
1560.9843750	0.18
1575.3573000	0.34
1717.8192140	0.18
1737.0577390	0.07
1787.1657710	0.03
1791.3546140	0.23
1812.5104980	1.88
1813.3952640	0.02
1822.0745850	0.11
1835.0614010	0.14
1839.7951660	0.05
1862.6431880	0.15
1925.2747800	0.14
1931.1636960	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3402
Annotation	Unknow
Peak:m/z	Relative Intensity
147.0198669	0.42
149.1283417	0.20
151.4243317	0.38
153.1901093	0.13
155.0299683	0.33
156.1741180	0.32
157.1417236	0.23
159.0632477	1.99
161.0746307	0.95
163.1449432	0.93
165.9565125	0.28
169.0341644	0.95
171.1508026	2.41
172.4792328	0.08
173.0937042	0.61
175.0206909	0.45
176.3117371	0.04
177.1768951	0.49
179.0198364	0.42
181.0341492	0.27
183.0285645	0.54
184.0992126	0.32
185.1344299	0.71
187.0928650	1.23
189.1224060	1.23
191.0723267	1.24
193.0676880	0.21
195.1773376	0.12
197.1388245	0.79
199.1617737	1.27
201.0626831	2.05
203.1645508	2.36
205.2221222	0.59
207.2158661	0.12
209.2434845	0.19
211.1313477	0.63
213.1060181	2.37
215.1687927	2.07
217.0511017	1.02
219.0728149	0.07
221.1200256	0.47
223.2529297	0.55
225.2055206	2.19
227.3272552	1.76
229.2403717	3.00
231.1748657	1.26
235.3703766	0.56
237.2280426	2.82
239.0804138	2.27
241.2514343	1.28
243.2867126	1.02
245.3008728	2.52
247.2643433	0.14
249.3171692	0.21
251.1623535	0.47
252.1354828	0.09
253.2741547	4.08
255.0301971	0.46
257.2495117	0.75
259.2043457	2.25
261.3900146	0.35
263.2223511	0.94
265.3035278	0.90
267.2838135	2.43
269.1342773	1.72
271.0800781	1.09
273.2903748	1.34
275.2807617	0.14
277.3206787	0.75
279.2991943	0.56
281.2396851	2.34
283.2828979	0.47
285.1692505	1.34
287.3023682	1.06
289.2357178	0.58
290.0691833	0.14
291.3861694	0.57
293.2545166	0.88
295.2314453	3.62
297.2655640	1.66
299.1915283	0.43
301.0947876	0.48
303.4374390	0.09
305.3079224	0.95
307.3186646	2.28
308.0728149	0.27
309.3049927	1.81
310.0894165	0.06
311.3240356	0.21
313.2921143	1.71
315.4214478	0.26
317.4428101	0.47
319.1398926	1.95
321.3370361	3.12
323.4890747	0.45
324.9795532	0.30
327.3736572	0.57
329.0560913	0.22
331.3124390	0.54
333.4116211	0.98
335.4771118	1.46
337.3988037	1.27
339.5698853	0.03
341.3375854	0.60
343.3177490	0.98
345.3340454	1.38
347.1966553	0.09
348.3820801	0.05
349.4285278	1.12
350.2451782	0.08
351.2818604	0.10
353.4013062	0.28
355.3267212	1.10
357.3723755	0.10
359.2437134	0.70
361.4215088	1.09
363.3069458	2.72
367.3018188	0.42
368.9781494	0.11
371.2827148	0.74
373.2299805	0.10
375.4518433	1.27
377.4526978	0.66
381.3521729	2.22
383.2666016	0.17
385.1931763	0.67
386.4801025	0.05
387.4541016	0.27
389.2460327	1.06
389.9136963	0.43
391.4788208	48.21
393.5948486	0.32
395.4583740	0.68
397.3660278	0.40
399.4624634	0.08
401.4277954	9.71
402.1196289	0.24
405.6853027	0.06
409.5590820	0.16
411.4566040	1.14
413.4259644	1.88
415.1254272	0.34
417.5114136	0.21
419.4730225	39.29
421.4609985	0.30
423.4095459	0.88
425.3925171	0.65
429.2491455	0.14
433.2112427	0.16
437.4288330	33.62
439.3087769	0.52
441.0404663	0.77
441.6525269	0.41
443.6949463	0.09
449.5297241	0.10
451.6200562	0.51
453.2982178	0.15
461.2957764	0.21
463.5641479	0.51
467.3898315	2.17
479.5292358	4.36
480.4530029	0.07
481.4714966	0.45
486.8366699	0.07
495.3300171	100.00
496.0002441	0.13
505.4631958	7.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	871.1312
Annotation	Unknow
Peak:m/z	Relative Intensity
265.2145691	0.19
268.4202881	0.07
280.2502441	0.11
353.3933105	0.18
381.3192139	0.19
403.7268066	0.11
452.1889038	0.08
465.9913330	0.07
499.3907471	0.08
505.1057739	0.09
538.5944214	0.09
570.4161987	0.09
604.1913452	0.34
622.2412720	0.31
667.1026001	0.09
690.2122803	0.08
718.5708618	0.38
728.1964111	0.51
734.9744263	0.61
738.4800415	0.14
753.1738892	0.52
768.1828003	0.78
777.5701294	0.08
782.5903931	0.07
787.2767944	0.29
793.4477539	0.55
797.7604370	0.89
799.3048706	0.19
800.4268188	0.23
803.8391724	0.10
807.5192261	0.08
810.1802368	0.96
811.0410156	0.70
813.7525635	0.26
817.1305542	1.11
817.7343750	0.41
818.5593872	1.69
819.4173584	1.07
822.0366211	0.88
824.1421509	0.53
825.9202271	12.39
826.7255249	0.70
828.0825806	0.16
830.3392334	0.26
831.1176758	0.98
832.5112305	0.32
834.7703247	1.40
835.4842529	0.73
838.9265747	2.86
840.9241333	0.10
842.3707275	0.65
843.4877319	1.07
845.6504517	0.23
846.9165039	4.31
847.9305420	0.12
850.3218384	4.88
851.1895752	1.25
852.7427368	1.85
854.8020630	0.18
855.9887085	0.31
856.7094116	0.28
857.5161743	0.26
858.2412109	0.36
859.1352539	0.40
863.6575928	0.16
871.9676514	100.00
873.0999146	3.24
874.4647217	1.45
875.2371826	0.23
876.9808960	0.85
878.2401733	0.33
879.2167969	0.20
880.7568970	0.65
882.5965576	0.07
887.6051025	0.58
899.3705444	0.59
904.7269897	0.29
918.8254395	0.08
927.2545776	0.12
934.2128296	0.30
941.2421265	0.38
949.7097168	0.46
953.2511597	0.36
953.9357300	0.67
958.5007935	0.19
962.0571899	0.47
973.9843750	0.96
974.8164062	0.52
978.0420532	0.11
979.6532593	1.07
984.3496094	0.39
986.5458374	0.10
991.4445190	0.60
992.0880737	0.57
993.2905884	0.16
995.6896973	1.13
996.2968140	0.56
997.0573730	0.05
998.8669434	0.30
999.7777710	0.23
1001.8088990	0.87
1002.9993290	0.99
1005.6121220	0.27
1006.3728030	0.32
1007.2782590	0.38
1010.7414550	0.38
1012.0866700	1.41
1013.7907710	0.26
1015.1110840	0.50
1020.2158200	2.36
1022.3527220	0.36
1023.6664430	0.28
1025.0771480	0.72
1029.0256350	2.17
1029.9128420	0.30
1030.6422120	3.32
1031.5461430	0.11
1032.8095700	0.81
1035.1989750	1.93
1038.3271480	0.78
1039.9294430	0.30
1041.4196780	0.24
1042.6162110	0.30
1043.6016850	0.15
1044.8264160	3.00
1045.8090820	0.31
1046.8928220	0.77
1048.1873780	1.10
1051.7069090	0.25
1052.4868160	1.68
1053.5893550	0.65
1055.1591800	0.23
1056.2319340	0.32
1057.1723630	0.10
1057.9069820	0.34
1060.5070800	0.49
1062.6815190	0.81
1064.4482420	0.51
1065.4194340	0.20
1066.9924320	1.11
1068.0714110	3.22
1069.0844730	0.85
1072.6457520	1.09
1074.7890620	1.62
1076.3813480	0.47
1077.0395510	0.24
1078.4505620	0.12
1079.4368900	1.25
1081.4117430	2.80
1082.1267090	0.76
1082.8146970	0.13
1084.5539550	1.15
1085.4846190	3.78
1086.5346680	0.78
1087.3491210	0.76
1088.7154540	0.45
1089.4262700	0.36
1090.9227290	10.84
1091.7808840	0.20
1093.1479490	0.19
1094.2768550	1.21
1095.3041990	1.16
1097.2585450	0.33
1099.3549800	3.26
1100.2652590	4.56
1101.0291750	11.12
1101.7186280	1.13
1102.7309570	0.41
1103.7919920	0.72
1104.4218750	0.54
1105.6567380	3.76
1106.2890620	0.28
1107.0439450	0.36
1107.6483150	0.18
1108.9685060	0.42
1109.6562500	0.61
1111.5605470	0.53
1114.6323240	0.62
1115.8773190	0.18
1116.7197270	0.78
1118.4174800	2.63
1119.1998290	1.82
1119.8013920	0.69
1122.3168950	0.80
1123.8461910	16.15
1124.6149900	3.54
1125.2678220	0.27
1126.4155270	0.24
1128.3148190	7.66
1129.0400390	10.68
1130.2204590	0.25
1131.2797850	0.76
1133.3106690	5.43
1134.1029050	0.12
1136.3977050	0.49
1138.3796390	0.26
1139.9350590	0.10
1142.7873540	0.16
1163.4268800	0.41
1172.9973140	0.28
1183.2512210	1.13
1192.8774410	0.22
1198.3291020	0.17
1205.2513430	0.04
1208.3270260	0.30
1213.9088130	0.10
1216.5953370	0.24
1223.4863280	0.21
1227.0999760	0.76
1234.9530030	0.12
1249.2221680	0.18
1251.0001220	0.15
1266.0146480	0.10
1274.7364500	0.24
1284.8024900	0.13
1287.4344480	0.24
1288.7495120	0.21
1294.8399660	0.83
1300.2576900	0.31
1317.9338380	0.93
1322.8377690	0.24
1326.2347410	0.08
1332.3730470	0.40
1337.1190190	0.83
1344.2811280	0.40
1345.3504640	0.48
1347.4495850	0.45
1352.5794680	0.20
1366.7111820	0.52
1382.2873540	0.37
1388.1027830	0.20
1390.0538330	0.13
1391.5758060	0.27
1401.8895260	0.13
1409.5345460	0.07
1411.0875240	1.21
1412.3800050	0.33
1415.0424800	0.57
1422.0563960	0.48
1426.6048580	0.40
1429.0234380	0.31
1436.8620610	0.34
1438.2854000	0.19
1444.7879640	0.16
1446.5748290	0.09
1449.8338620	0.49
1459.7188720	1.06
1460.5384520	0.17
1462.5687260	0.15
1464.0324710	0.20
1469.1285400	0.05
1472.4058840	0.54
1475.9553220	0.33
1478.1448970	0.40
1479.6647950	0.22
1487.6409910	0.22
1493.3551030	0.13
1494.5565190	0.48
1499.3485110	0.13
1502.3884280	0.75
1503.0069580	0.37
1510.2108150	0.31
1517.9796140	0.10
1535.0595700	0.33
1543.8032230	0.97
1548.8220210	0.18
1550.7314450	0.27
1551.5557860	0.26
1552.5550540	0.59
1556.0968020	0.28
1559.0009770	0.34
1560.4846190	0.29
1561.2785640	0.17
1566.7528080	0.17
1592.9674070	0.64
1597.9871830	0.44
1600.0568850	0.05
1629.2388920	0.12
1636.4788820	0.36
1686.9593510	0.10
1698.2814940	0.19
1720.7137450	0.06
1750.8869630	0.17
1769.2298580	0.10
1777.4772950	1.42
1794.3552250	0.14
1823.6428220	1.32
1833.1271970	0.28
1841.1496580	0.24
1858.5357670	0.07
1865.2742920	0.04
1868.6755370	0.18
1876.9543460	0.08
1882.2183840	1.11
1902.2487790	3.27
1908.9698490	0.04
1937.0939940	0.16
1950.2559810	0.25
1961.8658450	0.41
1972.3024900	0.05
1981.5135500	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.0963
Annotation	Griselinoside
Peak:m/z	Relative Intensity
141.0392456	0.10
143.2649231	0.26
160.8814087	0.13
165.0970001	0.22
186.9844971	0.21
190.0998535	0.32
253.0221252	0.06
269.3118896	0.15
274.2086792	0.09
277.1346130	0.11
287.1939392	0.28
291.2881775	0.11
293.1966858	0.80
297.0777893	0.12
299.3135986	0.24
300.1417847	0.11
305.3556213	0.11
306.2899170	0.09
309.1408691	0.18
311.0682678	0.11
329.2906494	0.07
330.1875610	0.15
341.2182617	0.10
354.2221985	0.12
369.1880798	0.09
374.1047668	0.60
374.9468994	0.14
378.4070435	0.09
381.2940979	0.23
393.2851257	0.10
395.2419739	0.06
399.3396912	0.20
400.5178833	0.19
403.7998962	0.05
420.3063965	0.66
421.1445007	2.76
423.3493958	0.32
431.2498169	100.00
436.3580627	0.07
446.9401245	0.23
449.3067322	0.45
452.3384399	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.0646
Annotation	Unknow
Peak:m/z	Relative Intensity
177.1240692	0.06
179.1031189	0.06
183.9806824	0.04
199.9174347	0.04
202.0196075	0.02
207.9921265	0.02
230.0661316	0.14
233.8110657	0.02
246.2094116	0.04
248.0020905	0.19
251.2753906	0.01
258.1250000	0.02
263.7953796	0.11
265.0494080	0.03
269.8125000	0.01
272.0207214	0.06
273.6915894	0.02
281.9587402	0.23
287.4726562	0.04
288.2010193	0.08
289.7477722	0.12
293.9534302	0.14
297.8049927	0.02
302.2796631	0.06
305.8861694	0.10
311.3348389	0.04
312.1866150	0.06
318.2531128	0.11
319.9274902	0.10
322.0844421	0.27
324.1002197	0.58
325.1116028	0.06
329.9288330	0.05
332.2954712	0.12
333.3804321	0.03
334.0125122	0.01
336.0996094	0.14
338.8822327	0.03
346.1853638	0.01
347.6549072	0.06
350.0254517	0.06
352.0403442	0.19
354.0421753	100.00
357.7914429	0.01
359.8737793	0.03
362.0720825	0.01
366.0641174	0.37
367.8255005	0.06
369.0862427	0.02
376.0358582	0.02
377.9091797	0.22
381.9465027	0.14
386.0339661	0.02
394.0115051	0.05
396.1231995	0.08
397.4778137	0.01
398.5756226	0.05
405.9721069	0.04
408.0158997	0.26
410.1500549	0.10
414.0570679	0.72
415.1163940	0.03
419.4359131	0.01
420.1762085	0.06
421.3027649	0.06
423.9001160	0.25
437.8856201	0.19
441.9913025	3.40
456.1208801	0.60
457.1367188	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2236
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2977753	0.14
167.0401001	0.04
180.0248718	0.14
183.3295135	0.11
190.9102173	0.10
192.2138367	0.08
200.8322601	0.34
202.1243591	0.12
210.3719788	0.05
213.3627014	0.22
220.3270264	0.11
243.3096924	0.17
254.0908203	0.09
262.1940918	0.21
267.1334534	0.04
275.1705322	0.04
281.2877808	0.30
289.3305969	0.09
293.1896973	0.35
293.9406128	0.09
295.2740479	0.04
303.6693115	0.30
304.3871460	0.48
305.1935425	0.08
307.0296021	0.19
310.9772339	0.11
312.4701538	0.06
313.1606445	0.11
319.5000610	0.04
320.1511230	0.24
325.2652588	0.16
328.3134766	0.45
331.4630737	0.10
332.3038330	0.25
347.3139038	0.43
348.0142822	0.12
348.6903687	0.28
359.5535278	0.11
404.3096924	0.18
418.1970825	0.18
421.5128174	0.07
422.4710693	0.17
428.4357300	0.15
446.2990112	0.44
450.5179443	0.21
463.3322144	47.02
464.2889404	100.00
466.2765503	0.78
471.7899780	0.17
474.3068237	0.73
478.4794312	0.27
484.3195190	0.15
489.3945312	0.06
490.3267822	0.32
491.7708740	0.32
492.5034180	0.24
511.0228271	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	245.0762
Annotation	Pseudouridine
Peak:m/z	Relative Intensity
69.6781387	0.02
73.8005447	0.18
82.7694397	0.07
83.8580933	0.14
84.9530640	0.05
85.7854233	0.05
87.0460892	0.03
88.0458221	0.23
95.6343460	0.09
96.9069061	0.66
97.8684998	0.37
102.8362885	0.02
112.9276428	100.00
114.9025116	0.34
115.8965912	4.75
117.7536163	0.02
123.9879761	0.13
125.1945801	0.08
128.1158752	0.11
129.9990082	3.40
132.8592072	0.68
134.0054779	0.24
140.9179077	0.05
142.0493317	0.02
143.8148041	0.02
146.9508820	0.02
150.0545349	0.14
151.0954895	0.10
151.8210297	0.05
153.1635132	0.03
154.9645081	0.11
158.9937744	0.07
161.0262604	0.04
161.9844818	0.03
166.3201294	0.11
169.0309753	0.09
169.7751617	0.08
172.8525238	0.07
175.0853882	0.09
177.8347015	0.05
180.1587067	0.04
182.0659943	3.43
183.0582123	0.09
185.0015717	0.04
187.2018890	0.09
188.9146881	0.05
194.9253693	0.02
196.8571014	0.04
198.9983978	1.92
200.2619171	0.02
201.1426849	0.08
201.7546692	0.03
202.7861176	0.04
205.8595276	0.04
209.0683136	0.22
209.6951141	0.02
213.1082153	0.13
215.2978210	0.12
217.0577545	3.12
227.0400543	2.91
228.1611786	1.87
229.0119171	0.05
233.2966919	0.14
235.9523315	0.89
236.6641083	0.28
244.7142792	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1767
Annotation	Lactucaside
Peak:m/z	Relative Intensity
158.9889832	0.04
163.0856323	0.07
163.9656982	0.02
164.9289856	0.22
172.9560089	0.06
173.8363037	0.02
175.1050720	0.30
176.0539246	0.35
177.8923187	0.45
178.7245178	0.11
181.0893250	3.93
189.1230164	0.08
190.9775696	1.36
193.0264282	8.91
194.9907532	0.77
195.5921936	0.01
207.1236115	0.18
217.2043762	0.07
221.2940979	0.03
223.1642914	0.12
225.1072388	0.34
234.0069122	0.02
235.1150818	3.43
237.1256714	0.04
243.1604767	0.24
248.0066223	0.05
250.1681061	0.15
264.0299072	0.02
264.9735107	0.10
265.5932617	0.04
272.3498535	0.03
272.9900208	0.08
278.2783813	0.03
279.2396240	0.03
282.2001648	0.25
283.0328979	0.11
288.0966797	0.02
297.0877380	0.47
298.3755493	0.08
301.1031494	0.02
304.1571045	0.10
304.9314575	0.03
306.2171326	0.53
309.2584229	0.02
310.0979614	0.06
311.3851929	0.04
321.2645874	0.08
322.4987183	0.18
324.9548340	0.04
326.0119019	0.02
327.1096191	0.09
334.6234741	0.18
337.4367676	0.04
341.2428589	17.95
346.4237671	0.04
353.1425171	0.24
355.2875366	0.79
357.3659668	0.05
367.3980713	0.03
371.1837158	1.11
373.4687500	0.19
375.2977295	0.03
377.2613525	0.09
381.1262817	0.07
382.6046143	0.28
383.2429199	2.27
385.1027832	0.05
387.0114746	0.06
389.1217651	100.00
395.2711792	0.03
397.3917236	0.06
403.2687988	0.94
413.2716675	1.03
421.1697998	0.04
424.6084595	0.11
429.2193604	0.05
431.2693481	8.90
442.8710327	0.02
444.9002075	0.05
455.2843018	0.07
459.2699585	0.07
460.7513428	0.20
461.5062866	0.24
465.2418823	0.02
473.2167358	0.07
477.1663818	0.02
485.3352051	0.03
491.1015015	1.31
497.6911011	0.04
505.1573486	0.23
506.5272217	0.02
507.8428345	0.09
513.3831177	0.03
519.2977905	0.06
521.5962524	0.02
530.8190308	0.08
533.3482666	0.41
551.4610596	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.229
Annotation	L-Linalool 3-[xylosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
149.1134949	0.08
151.9824371	0.05
167.0358734	0.50
245.3165131	0.07
249.4026794	0.09
250.2238007	0.02
271.1350098	0.02
293.2414246	0.20
295.0906067	0.02
297.1912842	0.05
311.4930725	0.02
312.9034729	0.03
314.2522278	0.05
315.3560791	0.18
324.3685608	0.03
331.1134033	0.02
344.2905884	0.14
345.3933105	0.24
349.3901672	0.09
375.1671448	0.26
379.3047485	0.17
385.2241211	0.11
388.4750061	0.03
399.0306396	0.03
404.9981384	0.05
407.3509827	0.07
425.4586792	0.04
433.2725525	0.20
447.3305969	100.00
448.3670349	0.02
449.2614441	0.05
450.2869568	0.01
451.6004944	0.01
474.7792358	0.07
475.6224060	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8549957	22.20
161.0399170	0.14
212.8182373	15.53
215.0593872	0.53
219.0114441	1.16
268.1647339	1.15
268.9556274	0.27
270.1407471	1.77
271.3957825	0.15
296.7312927	100.00
297.4233398	0.24
308.9572754	0.24
320.9240723	0.14
331.8916016	0.31
350.9322510	0.14
362.9746399	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	235.0209
Annotation	2-Carboxy-D-arabinitol
Peak:m/z	Relative Intensity
70.8728943	1.41
87.7958298	5.28
90.3841248	0.40
105.9579926	18.83
129.1909637	1.72
129.9266663	0.23
144.9244843	0.23
172.1325531	16.10
179.0820618	9.40
188.9411163	6.42
206.8753510	0.41
217.1086273	100.00
218.1250458	1.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
194.1686096	0.03
206.8017578	22.69
223.1174316	0.05
225.0729980	0.06
232.9022827	0.02
246.0550537	0.10
274.1673584	0.02
290.7161865	100.00
291.3480835	0.12
306.3146667	0.05
330.1827393	0.04
346.0700073	0.02
347.0446167	0.03
348.0996704	0.32
349.0641174	0.06
374.5699463	22.74
375.3528442	0.04
412.1120911	0.03
420.2754517	0.02
441.9608459	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	584.2752
Annotation	Amikacin
Peak:m/z	Relative Intensity
165.8833618	0.16
166.9151306	1.73
170.0739288	0.17
171.0531006	1.08
179.0690308	22.85
179.9457397	1.13
183.1458740	0.87
192.1942749	2.60
197.0352936	1.22
210.0407410	20.47
211.1083984	1.31
228.2742920	0.54
236.2934723	0.37
237.0719299	0.88
254.0539856	86.26
255.1022339	9.17
272.1821289	100.00
273.0783081	2.72
301.3376465	0.78
311.2889709	8.76
312.2977905	0.65
322.0993042	0.27
337.3107300	1.05
368.0993042	0.63
380.1931763	0.35
398.4074707	4.57
399.4432373	0.61
406.4458008	0.46
409.2855835	0.35
412.4566040	0.69
437.2319336	0.37
451.4064331	0.11
455.3349609	72.92
456.3762817	17.06
463.0081177	0.96
465.4879761	0.13
479.1495972	0.15
491.0775146	0.35
509.6052856	0.72
513.4388428	0.57
539.2700195	0.11
549.3278809	2.07
566.3112183	50.71
567.3772583	17.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1187.11
Annotation	Unknow
Peak:m/z	Relative Intensity
523.6909180	0.01
619.2121582	0.01
878.7430420	0.06
1012.7053220	0.03
1061.5986330	0.16
1063.4586180	0.05
1072.1130370	0.20
1093.9006350	0.20
1094.6549070	0.19
1095.6791990	0.21
1096.7733150	0.15
1100.2850340	0.08
1105.0644530	0.22
1106.1671140	0.15
1114.4412840	0.19
1120.1574710	0.19
1124.0683590	0.06
1129.5750730	0.10
1133.4851070	0.39
1134.5916750	0.10
1136.4840090	0.04
1142.9000240	0.31
1153.7426760	0.05
1154.7272950	0.04
1162.4626460	0.03
1166.2580570	0.01
1188.1574710	100.00
1189.6074220	0.64
1190.7637940	0.13
1191.9448240	0.22
1193.2731930	0.17
1194.4770510	0.02
1195.4646000	0.09
1202.0676270	0.04
1212.6807860	0.02
1221.5910640	0.03
1248.6234130	0.04
1281.6657710	0.04
1306.2939450	0.14
1348.3103030	0.04
1391.8598630	0.05
1425.8377690	0.01
1483.7418210	0.04
1493.5815430	0.07
1496.0924070	0.03
1514.3322750	0.05
1516.7276610	0.10
1518.8104250	0.07
1528.3549800	0.08
1545.1585690	0.04
1553.0834960	0.22
1556.7147220	0.03
1562.1340330	0.01
1578.3457030	0.09
1580.3812260	0.02
1585.8426510	0.02
1603.1088870	0.02
1608.8143310	0.09
1610.4354250	0.08
1614.4920650	0.07
1616.3431400	0.04
1640.1026610	0.06
1641.1993410	0.13
1649.7286380	0.04
1652.1441650	0.09
1658.1280520	0.12
1661.4045410	0.04
1671.9591060	0.02
1675.5369870	0.06
1682.6353760	0.07
1685.9613040	0.05
1704.3468020	0.02
1791.8834230	0.53
1849.7469480	0.50
1934.9058840	0.02
1955.0557860	0.02
1966.7664790	0.16
1972.0773930	0.03
1975.1276860	0.20
1985.0511470	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9084473	0.12
199.8170013	0.14
216.9951172	0.11
219.2136688	0.18
229.0179901	0.29
229.7000732	0.07
272.9774170	22.07
274.0073853	8.74
275.0736694	6.73
386.9602051	23.57
387.9995117	20.93
389.0312500	20.15
431.9430542	0.05
434.0466919	0.08
449.2843018	0.19
460.0445557	0.07
469.9199829	0.11
487.0787964	0.04
499.1318359	0.10
500.9708862	41.72
501.9740601	100.00
502.9379883	82.89
519.2307739	0.06
525.8862915	0.17
530.3289795	0.12
542.1121216	0.20
543.1632690	0.12
543.8880615	0.12
549.0732422	0.06
560.5334473	0.23
569.7821045	0.22
571.0146484	0.37
571.9132690	0.09
572.9981689	0.28
584.1256714	0.11
586.5984497	0.10
588.4262085	0.23
589.0555420	0.19
599.3423462	0.06
618.2617798	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2448
Annotation	Agnucastoside B
Peak:m/z	Relative Intensity
161.1000824	0.03
163.6681671	0.09
165.0868378	0.06
173.3090210	0.04
179.1152039	0.12
181.1266479	0.13
182.2161255	0.07
191.1513672	0.14
203.3216095	0.04
206.7534332	0.03
209.2847443	0.19
211.1984406	0.06
217.1470337	0.23
225.0495758	0.14
227.2271729	0.13
229.3247528	0.31
241.2598572	0.15
242.1761627	0.10
243.3013306	0.12
244.4559174	0.07
245.3270264	0.05
248.4423218	0.07
255.2358704	0.30
256.2667236	0.20
257.2601013	1.02
264.3278198	0.03
271.4244995	0.29
273.2354126	4.14
274.3293457	1.01
275.2758484	0.83
275.9926147	0.08
282.0979004	0.05
283.2418823	0.43
284.0791016	0.07
285.1608887	0.14
289.3460083	1.11
290.2793579	0.40
291.3443604	0.22
301.3097534	3.43
302.2100525	0.29
309.4460449	0.12
315.4986572	0.18
317.2402344	2.08
319.2454224	100.00
320.3154907	22.30
337.3195801	6.80
338.2777710	1.30
345.3048096	0.46
346.2837524	0.24
363.2299194	3.16
364.3039551	0.96
371.2948608	0.33
379.0721436	0.04
384.2856445	0.04
385.4681396	0.07
389.5201416	0.16
390.2672729	0.05
395.0762939	0.17
412.3944702	0.18
421.4229126	0.20
442.3687134	0.07
457.2897339	0.07
472.2662354	0.09
481.6851807	0.20
483.6312866	0.10
484.4243164	0.07
497.5723267	0.48
498.1729736	0.23
499.4295654	7.97
500.3779907	3.09
501.0039062	0.09
506.2401733	0.06
508.1259155	0.61
513.4449463	0.18
514.4370117	0.12
526.0761108	0.63
545.4803467	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.0752
Annotation	Unknow
Peak:m/z	Relative Intensity
165.0699768	0.09
172.8858032	0.15
194.9145050	0.03
219.1765594	0.03
220.0365753	1.26
225.4245453	0.35
245.3439941	0.10
247.9085999	0.05
249.3415222	0.04
251.2199402	0.10
257.2599792	0.07
264.0683899	8.02
264.8469543	0.49
266.0822449	1.16
273.1456909	0.09
281.9451599	0.13
290.0705872	0.43
291.0723877	1.06
292.1416016	0.22
298.2487183	0.04
300.1245117	0.04
303.5388794	0.07
309.1371460	0.04
331.3080750	0.17
334.7888184	0.15
341.2761536	0.04
342.1748047	0.06
366.2475586	0.25
368.9761353	0.11
383.2153625	100.00
385.0674438	12.33
385.6769104	0.09
387.4762573	0.10
391.3877258	0.17
398.6016846	0.07
400.3401794	1.06
401.0783997	9.37
402.9749146	0.11
410.8968506	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.5607
Annotation	Unknow
Peak:m/z	Relative Intensity
105.8509598	2.12
122.9484558	71.12
124.0537415	2.62
135.9867859	4.19
232.1574707	6.10
260.8572388	3.02
427.9939575	2.18
444.3843689	1.63
524.1775513	41.88
525.2337036	2.81
542.0624390	100.00
542.6732178	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	456.2005
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0370178	0.20
152.9805603	0.23
167.9246521	0.10
170.2011261	0.52
171.0929260	4.44
185.0559692	0.25
190.9209290	0.11
199.2216339	0.08
207.2803040	0.07
232.4436340	0.34
242.1559753	0.56
257.1222534	0.07
259.3138733	0.80
271.4790649	0.19
274.7175293	0.43
285.1514893	0.14
293.1766357	0.04
294.1552124	0.03
297.3635254	0.28
308.2622986	0.17
317.2089233	0.10
318.4522095	0.09
323.6838684	0.06
325.2287598	0.16
329.2110291	0.05
332.1669922	0.09
339.2182617	0.11
341.3459778	0.17
346.9981384	0.13
349.1736450	0.10
350.0316162	0.27
351.2259216	0.77
356.1101990	0.07
367.4793091	0.07
369.3409119	21.03
372.0342712	0.11
383.2460327	0.05
393.4660339	0.14
394.3658142	0.22
396.2386169	100.00
397.2065125	0.75
399.2047119	0.06
409.1643982	2.93
410.2352905	5.73
411.3681335	0.49
411.9700623	0.32
414.2268982	0.04
418.3029785	0.04
420.3217468	0.07
423.4759827	0.34
425.4638977	0.36
435.9459229	0.07
437.1463318	0.44
438.2942505	1.31
439.1468201	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	951.46
Annotation	REBAUDIOSIDE C
Peak:m/z	Relative Intensity
564.7385864	4.09
613.7318726	0.93
654.0888672	5.00
674.5903931	0.95
688.3676147	1.34
702.5291748	1.53
703.6103516	3.52
742.0303955	2.30
751.9915771	1.03
788.7352295	2.52
802.7175903	3.28
904.1410522	2.41
905.0834351	10.95
906.605896	14.38
910.6616211	3.85
932.5029907	6.20
933.916748	1.62
951.4645996	100.00
952.8114624	8.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1662
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8904419	0.08
139.1542969	0.02
142.9040375	0.08
148.9512024	1.07
181.1272278	0.05
191.1294403	0.13
216.8237457	0.17
218.1461792	0.12
218.9398041	0.11
220.8522949	0.21
227.2247314	0.06
229.0954895	0.07
243.1677246	0.13
245.0680847	0.22
247.0659180	0.07
251.0638428	0.12
259.9668274	0.02
263.1618347	0.09
274.8965149	0.05
281.1830444	0.09
282.1152954	0.17
293.1870422	0.17
294.6617432	0.08
297.0198975	0.04
302.9455566	0.10
304.1599731	0.09
305.0009460	0.06
311.0286865	0.41
329.0963135	0.52
335.0705261	0.14
337.1348877	0.03
338.3835144	0.03
348.1840820	0.02
353.2709961	0.06
361.1141968	0.11
364.4769592	0.08
365.2419434	0.13
367.1128845	0.11
371.3926392	0.02
379.1979370	100.00
380.3037720	0.16
389.1009827	0.04
394.8949890	0.05
404.4928284	0.15
406.4891052	0.06
407.3662109	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.245
Annotation	Acetylpringleine
Peak:m/z	Relative Intensity
190.1501617	0.16
193.3912659	0.07
194.3282013	0.27
197.1820374	0.08
208.3070679	0.07
210.1046295	0.61
211.0594482	0.28
215.3455658	0.10
222.1673737	0.94
223.3024139	0.45
225.5838165	0.17
232.3541412	0.05
236.1484680	0.31
240.1510620	4.31
241.1454468	0.31
254.1165161	3.70
255.2214661	1.39
256.1317749	0.57
265.8194580	0.09
272.0939026	3.94
273.3674927	0.23
276.0458374	0.05
280.0562744	0.08
282.4494019	0.78
284.3036804	0.13
288.0707703	0.08
292.9474182	0.14
298.0341797	0.20
300.2013550	0.89
301.2148438	0.20
307.2121582	0.27
311.2826538	0.08
316.3516846	2.00
317.0930176	0.63
326.3050537	0.23
328.9855957	0.12
334.2988892	17.56
335.4098816	3.43
357.3914795	0.10
359.1573486	0.24
360.2631836	2.35
361.3002319	0.79
367.0753784	0.10
371.3466187	0.23
378.2357178	100.00
379.2454834	17.84
416.3870850	0.05
419.4205933	0.14
430.9694214	0.16
432.3925781	0.04
435.2673340	0.65
445.3162231	0.10
447.2979736	0.13
463.2520142	0.69
465.3111572	3.57
466.1508179	0.70
470.2421265	0.05
478.4075317	1.03
479.2432251	0.30
494.3345337	0.06
498.4534302	0.20
501.7161255	0.05
502.4149170	0.11
503.5853271	0.14
504.4267578	0.60
505.5851440	0.61
522.3541870	30.33
523.3917847	5.37
532.5265503	0.10
533.4354858	0.20
545.4335938	0.09
554.2863159	0.11
555.2526855	0.06
558.1567383	1.16
559.3955078	0.12
561.5296021	0.13
567.5169067	0.23
571.3558350	1.39
572.3838501	0.95
576.4067993	0.05
578.1799927	0.07
587.6284790	0.06
589.3348999	0.65
591.2682495	0.20
594.5662231	0.08
597.2322388	0.05
606.2881470	0.41
607.4151001	2.08
608.5100708	1.00
615.4826050	4.65
616.4882202	1.17
617.3136597	0.12
621.8013916	0.14
631.3991089	0.13
633.3543091	40.12
634.4431763	10.53
652.4766235	0.27
653.0798340	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.1122
Annotation	S-Glutaryldihydrolipoamide
Peak:m/z	Relative Intensity
98.2212067	0.13
106.6490479	0.05
112.1839066	0.06
117.9753189	100.00
128.2160034	0.02
129.0153503	0.17
129.9184723	0.95
137.0247955	0.11
141.9718018	0.59
157.3108826	0.08
158.8850708	0.28
159.8652802	0.74
162.0332794	0.13
173.1256714	0.05
175.9121857	12.32
179.0049133	0.20
183.1234589	0.18
187.9576416	0.21
189.1059265	0.02
189.8864899	0.72
192.9834290	14.17
200.1210938	0.09
201.2181702	0.20
202.0935364	0.16
205.1281433	0.05
206.2284851	0.09
210.0476990	0.15
210.9271851	0.32
214.2803955	0.06
216.3420715	0.18
218.2189331	0.53
220.1683044	0.26
224.1542358	0.16
229.3193359	0.15
232.8904419	0.07
246.3399658	0.14
247.1116638	1.00
248.0444641	0.18
257.2478027	0.25
259.0948486	0.13
260.2186890	0.34
266.1938477	0.13
269.3880615	0.04
272.2529907	0.39
274.1734314	0.24
276.0677490	0.08
278.1905823	0.57
279.2344971	0.03
280.4914551	0.07
285.2169495	0.10
286.2690430	0.78
289.9111633	0.14
294.2864990	0.16
299.7815552	0.16
303.1660156	0.86
304.1188965	1.45
305.1895752	1.03
312.6383362	0.24
313.7190857	0.03
329.4389648	0.10
331.3510742	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.1935
Annotation	Unknow
Peak:m/z	Relative Intensity
209.1496124	0.21
225.1960449	0.10
240.0146179	0.09
260.0698853	0.12
274.9677429	0.05
305.8831787	0.06
306.5349731	0.06
334.2494507	0.14
335.2661133	0.44
353.2750854	5.10
357.1047363	0.11
368.2877197	0.05
373.1833496	100.00
375.2057495	0.10
381.1430664	0.04
417.9368286	0.07
442.8305054	0.05
469.7704468	0.04
494.2100830	0.15
504.2651367	0.07
508.1713257	0.18
518.1278687	0.30
519.4848022	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3847
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
344.0508423	6.06
452.7302856	9.40
540.8046265	14.21
641.508728	4.01
704.4907227	8.63
742.2223511	5.41
742.9332275	4.23
766.4685059	18.18
803.3757935	100.00
804.164978	11.38
827.1956177	2.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
176.9626007	0.04
178.9945831	0.10
180.9415436	0.20
182.0298157	0.10
185.1387329	0.19
188.8505249	0.08
192.9987183	0.13
199.0889893	0.41
204.9911041	0.02
209.0223083	1.25
210.9263000	1.03
217.0457001	0.18
226.7492523	0.06
231.0316772	1.49
234.9734192	1.35
256.0718384	0.57
257.4681091	0.07
261.9452515	0.03
271.2783813	0.02
274.1503601	0.03
279.8680420	0.11
288.1800537	1.12
290.2674561	0.09
297.9838257	0.21
306.1607971	0.09
320.2371216	0.02
322.1412659	0.25
337.1127930	0.67
338.1556396	0.15
340.2359619	0.11
348.2601318	0.18
349.3470459	0.04
355.1375122	100.00
355.7517090	0.15
372.2889404	0.12
381.2709961	0.07
391.3199463	0.22
409.1389771	6.36
421.2122803	0.24
451.9711914	0.02
466.2188721	8.26
467.3820190	0.16
473.4657593	0.06
480.5005493	0.05
481.3400879	0.08
484.1776733	69.55
514.1725464	0.03
520.1828613	0.66
538.1940308	3.73
550.2274780	0.05
570.1174927	0.04
577.0996704	0.30
595.2525024	20.58
595.9508057	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	661.2881
Annotation	Briaranolide C
Peak:m/z	Relative Intensity
237.2873230	0.02
257.1176147	0.01
269.2409363	0.04
280.0693359	0.04
297.2106628	0.09
298.0968323	0.04
310.7442017	0.06
339.9398804	0.10
386.3957520	0.25
387.1228638	0.22
402.3511963	0.06
416.5307007	0.12
417.2703247	0.02
420.5793457	0.08
428.2976685	0.65
429.1983032	0.21
430.1890869	0.06
434.3645630	0.19
435.0107422	0.05
436.1488647	0.02
444.0570679	0.06
446.4270020	1.35
447.3760376	0.53
449.0584106	0.05
460.4251099	0.35
461.4483643	0.38
472.4353638	2.49
473.3608398	1.97
474.2976685	0.27
477.3318481	0.15
480.4221191	0.03
481.1469116	0.02
483.5477905	0.06
492.3107300	0.25
493.4262695	0.05
499.2717285	0.02
504.3538818	6.91
505.4418335	1.99
525.4155884	0.59
526.4285889	0.47
567.3580933	2.14
568.5797119	1.81
569.3585815	3.66
570.3640747	1.62
583.2545776	0.10
585.3937378	4.10
586.4287720	1.94
587.6432495	0.04
594.1644897	0.17
601.3432007	4.32
602.4527588	1.80
611.3572998	14.98
612.4522705	5.88
625.3305664	0.04
629.3838501	100.00
630.3860474	44.45
631.0090942	0.15
643.3598022	6.23
644.4051514	1.79
662.3833008	2.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	351.1976
Annotation	Unknow
Peak:m/z	Relative Intensity
113.0211639	0.98
113.9787140	0.29
114.9657974	1.58
115.8287354	0.15
130.1991119	0.03
130.9187164	0.03
133.0328064	0.08
133.9292603	0.02
141.0354767	0.24
142.0833282	0.08
158.9779816	21.86
173.8888092	0.03
175.9923096	100.00
189.0394592	0.03
190.8081818	0.03
215.0653687	0.13
219.1233521	0.02
223.2719421	0.08
231.0820923	0.05
235.0423889	0.05
252.9601440	0.11
261.1839294	0.05
291.3694153	0.01
307.3876953	0.04
308.0580139	0.09
333.2391968	0.15
334.2113037	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.13
Annotation	SN-38
Peak:m/z	Relative Intensity
146.9040222	0.08
160.8500977	0.09
174.9475708	0.31
176.1130676	0.12
196.3660278	0.02
199.0789032	0.45
201.0606232	1.14
227.1125183	0.10
232.1013184	0.03
234.7649231	0.07
241.2415466	0.14
245.0574646	9.05
246.3094788	0.12
247.0376587	0.12
259.2493286	0.15
263.1403198	0.07
274.0239258	0.03
275.1864014	0.07
277.2340393	0.06
287.2992859	0.12
290.1027832	0.10
294.0578003	0.04
301.2557373	0.15
308.5494995	0.07
310.2521973	0.07
316.6732178	0.08
322.6582031	0.27
327.4425964	0.09
329.2933350	0.10
331.1289673	0.18
335.0972595	0.31
342.0804138	0.11
343.2362671	0.22
345.1651611	100.00
346.6154175	0.48
347.2916870	11.90
354.3664551	0.37
355.2505188	0.11
356.0497742	0.10
360.2489624	0.08
362.4922180	0.92
363.2295532	0.60
372.3316040	1.45
373.4506531	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	834.4207
Annotation	Unknow
Peak:m/z	Relative Intensity
503.6132812	0.05
525.6607056	0.17
539.6430054	0.09
633.8843384	0.15
671.4962158	0.10
672.7443848	0.13
701.5055542	0.07
745.8383179	0.26
773.3549194	2.30
774.0222168	0.05
791.6645508	0.67
833.9111938	9.93
834.6548462	100.00
835.9235229	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1538
Annotation	Vaccinine A
Peak:m/z	Relative Intensity
80.8872528	0.04
88.9813461	6.21
97.8784103	2.19
100.8651505	0.03
103.1317291	0.05
107.0956116	0.05
108.7759857	0.09
109.8746948	0.13
111.1982422	0.04
113.9311829	13.13
114.9195862	8.73
117.0807800	0.05
120.8477478	0.11
125.1905518	0.35
127.9205780	0.04
129.9741364	0.16
132.1906891	0.07
133.0639343	0.12
136.9566956	0.66
138.1133728	0.18
138.9406281	0.07
140.9425507	0.08
144.8260498	0.09
149.2046814	0.14
152.0023499	8.16
161.2229919	0.05
167.0982208	0.04
176.9852142	69.70
188.3202972	0.05
188.9772491	0.05
191.1203156	0.42
192.2013245	0.15
192.9549713	0.18
194.1440735	0.13
199.4205475	0.06
206.1401062	16.43
207.0906677	0.05
208.9080963	0.20
211.1475372	0.04
217.0372925	0.02
220.1972351	0.09
221.0929413	0.14
223.1885529	1.58
224.0121307	0.04
233.1334991	0.02
236.4299316	0.30
237.2498932	0.26
243.6567383	0.16
245.4983673	0.10
248.0740814	100.00
248.6823273	0.30
255.1578217	0.22
256.3260498	0.60
265.3554993	0.07
277.2393494	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.2882
Annotation	Amikacin
Peak:m/z	Relative Intensity
177.0605621	0.09
181.0606537	0.17
182.2001953	0.09
191.2176361	0.07
201.1945190	0.21
213.1847839	0.11
231.1963501	0.25
232.8501892	0.20
244.4875946	0.33
245.3495789	0.33
256.2614746	0.17
259.2105103	0.37
262.2715759	4.73
264.1023560	0.16
278.3468018	0.62
279.2353821	3.19
280.1151123	0.36
281.4829102	0.19
286.5411377	0.11
288.1597290	5.84
290.3077393	0.17
294.1793213	0.09
311.2446289	19.15
312.2002563	0.14
313.2283936	0.97
317.2720337	0.12
323.2230225	0.15
327.1065674	0.10
327.8140869	0.44
334.9249268	0.11
337.6867065	0.17
344.3405151	0.44
345.1599731	0.21
349.8287964	0.31
351.2655640	0.23
352.9517212	0.11
369.2904663	4.14
373.8605347	0.18
378.2925415	0.07
379.3589478	0.05
382.2229004	0.13
388.8989868	0.13
406.5563354	0.16
411.5720215	0.13
412.3070679	0.36
421.5191650	0.47
422.3076782	0.22
423.9267578	0.69
430.8978271	0.31
432.0494385	0.36
439.4291992	1.78
440.3821411	0.34
452.3828125	0.04
454.0269165	0.06
455.4417114	0.23
457.3054810	100.00
457.9355469	0.55
465.2689819	0.64
467.5667725	0.15
471.4688110	0.10
503.7681885	0.09
504.6813965	0.32
506.3856201	0.67
511.3753052	0.15
512.3420410	0.32
521.4002075	0.05
522.2037964	0.22
527.7217407	0.12
540.0033569	0.40
541.4879761	0.35
549.9398804	0.14
554.3720093	0.20
557.7938843	0.22
566.0786743	0.17
568.4583130	28.48
569.8571167	0.17
575.0532837	0.23
587.9743042	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1723
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0192261	0.03
176.1695862	0.21
177.2326050	0.12
186.5955658	0.05
191.1116486	0.29
201.0546570	0.05
205.0985718	1.68
219.1535187	3.94
227.2654266	0.03
228.2166443	0.04
231.1083069	0.01
258.1519165	0.05
261.0883789	0.02
277.1251526	0.02
291.2705383	0.04
293.2555847	0.05
297.2232666	0.07
311.3031921	0.04
319.0409241	0.03
321.3093262	1.68
323.4022217	0.04
335.1510620	0.03
339.1945801	100.00
353.2769775	0.02
357.2303162	0.45
357.8423157	0.02
367.3555908	0.03
385.2055664	0.05
411.1629028	0.12
414.0487366	0.22
436.2057495	0.06
436.8437805	0.03
438.2715759	0.03
439.2796936	0.03
440.8597717	0.03
455.1953430	0.21
456.6676941	0.07
457.2955017	0.03
461.9111938	0.08
481.4252014	0.14
482.9277039	0.36
483.6775513	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.4168
Annotation	Capsicoside B2
Peak:m/z	Relative Intensity
207.0591431	2.47
221.1139221	0.06
225.2268677	1.53
235.0833588	0.19
243.2005920	0.07
249.2832336	0.08
253.0298920	0.14
271.1007690	0.06
277.3402405	1.47
281.0889282	0.30
291.1892090	0.06
299.3665771	0.93
309.5854187	0.07
316.5507202	0.16
341.0339966	0.05
387.4265137	0.03
394.2462158	0.11
441.5463257	0.09
443.3709717	5.68
457.6097412	0.49
461.3043213	21.46
461.9188843	0.05
467.5617065	0.16
485.6192017	0.08
493.4721680	0.05
512.8118286	0.03
555.4224243	0.03
559.5969849	1.50
613.2424927	0.26
623.7406006	0.03
625.7930298	0.10
629.4818726	0.05
702.3735352	0.17
703.5621948	0.08
721.5194702	100.00
722.5298462	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.91
Annotation	Unknow
Peak:m/z	Relative Intensity
409.6461182	0.14
503.6106567	0.04
589.1749268	0.03
633.4769897	0.03
671.4773560	0.08
737.8096313	0.14
761.2291870	0.04
773.6218872	1.18
774.7302856	0.06
791.5990601	0.25
815.6752930	0.33
833.5795288	100.00
834.5477905	82.05
835.2511597	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.4073
Annotation	Beesioside D
Peak:m/z	Relative Intensity
471.2671509	0.07
524.9403687	0.06
587.6748657	0.23
615.1488647	0.14
616.3998413	0.07
633.5173340	100.00
634.4839478	24.53
635.7310791	0.13
680.3881226	17.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.0149
Annotation	Unknow
Peak:m/z	Relative Intensity
111.0025635	0.02
161.3524017	0.01
183.0609894	0.04
212.3919525	0.03
219.1519928	0.01
221.0506592	0.08
221.6858368	0.02
223.8952789	100.00
224.7548981	0.01
241.8072510	17.83
242.6421051	0.01
243.8607635	0.08
253.1328278	0.01
265.0111084	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1442
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
174.9167633	0.52
177.1708832	0.08
177.8418884	0.11
178.9826965	2.10
180.0247040	0.17
185.1181946	0.71
192.1265564	0.13
196.8949585	0.09
201.2028961	0.06
202.9807129	0.12
209.0287018	0.10
210.1054993	2.62
211.1447754	0.63
212.1974182	0.13
213.1334534	0.14
214.0944366	0.27
215.5225677	0.38
226.3007202	0.23
236.2041931	0.19
242.0243683	0.09
252.1904144	0.33
254.0370026	12.24
255.0872040	0.90
260.1190186	0.12
262.6989136	0.23
270.2829590	0.05
272.1800537	31.53
273.1908875	3.38
286.1634521	0.72
288.0980835	3.32
289.0811157	1.20
304.1138916	15.15
306.1459961	100.00
307.1662292	10.41
320.2142944	0.36
338.0321655	30.77
339.1328735	3.19
362.3796387	0.26
371.0917358	0.27
436.4345093	0.16
463.3486328	0.07
464.3590088	0.51
482.1870117	18.40
483.3229980	1.74
505.0386353	0.06
509.2973022	0.08
575.7291870	0.04
593.2269897	6.45
594.3171387	2.53
595.4313965	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1120.8414
Annotation	Unknow
Peak:m/z	Relative Intensity
328.0905762	0.30
341.2186584	0.03
414.6244507	0.05
435.5667114	0.08
474.2900085	0.06
482.5020752	0.15
495.3312683	0.04
535.4371338	0.02
565.4119873	0.08
645.5180664	0.11
657.3392334	0.33
702.2332764	0.10
728.6223145	0.05
748.9760742	0.11
773.5692139	0.07
828.5610352	0.06
834.5120850	0.04
836.5657959	0.07
854.7276611	0.20
871.3596191	0.11
887.5920410	0.18
897.2117920	0.38
899.8945312	0.07
922.4272461	0.13
935.1494141	0.27
936.9947510	0.22
956.9394531	0.16
983.6611328	0.09
985.2460938	0.13
1001.8009030	0.44
1008.0089110	0.08
1017.0649410	0.26
1018.8410640	0.56
1023.7194820	0.09
1025.4935300	0.08
1030.6665040	0.12
1036.6688230	0.24
1042.3793950	0.17
1043.5718990	0.30
1049.6005860	1.43
1058.6633300	0.97
1087.3143310	0.21
1121.5360110	100.00
1123.3189700	0.56
1124.1722410	0.30
1125.1037600	0.40
1125.8453370	0.11
1126.8059080	0.21
1135.5805660	0.23
1142.0808110	0.16
1151.3431400	0.17
1155.8786620	0.16
1157.7631840	0.06
1170.9268800	0.25
1171.6259770	0.12
1172.8325200	0.50
1179.3383790	0.38
1180.0415040	0.06
1208.2756350	0.20
1214.1303710	0.04
1228.9447020	0.09
1237.0344240	0.19
1271.3879390	0.12
1275.1425780	0.05
1288.0197750	0.09
1328.6514890	0.35
1331.9505620	0.12
1343.7818600	0.21
1348.8270260	0.15
1358.3105470	0.14
1367.1805420	0.25
1395.9395750	0.82
1413.9134520	0.10
1414.8676760	0.21
1422.5006100	0.45
1431.2867430	0.39
1432.1031490	0.14
1442.9805910	0.05
1471.8685300	0.11
1488.3088380	0.18
1489.2989500	0.44
1498.8001710	0.16
1516.8154300	0.42
1537.3673100	0.09
1546.4748540	0.04
1561.7329100	0.04
1563.8824460	0.18
1566.4298100	0.22
1572.7966310	0.20
1573.9930420	0.47
1585.8560790	0.07
1613.1282960	0.18
1694.4232180	0.02
1761.7025150	0.06
1790.3907470	0.05
1846.9696040	0.04
1878.8020020	0.06
1883.9925540	0.07
1887.8333740	0.59
1912.0552980	1.88
1913.7092290	0.52
1942.8859860	0.22
1948.4808350	0.70
1973.4166260	0.03
1993.0072020	6.34
1997.5423580	6.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.0982
Annotation	5,7,4'-Trihydroxy-3,6,8,3',5'-pentamethoxyflavone
Peak:m/z	Relative Intensity
136.9349060	6.75
142.9613953	0.06
146.8668823	0.09
150.9432220	0.13
158.8014526	0.13
179.0856018	0.58
191.3711853	0.02
192.9879456	0.03
197.0599060	0.08
203.1682739	0.30
208.9445038	0.36
211.1463928	0.13
216.2282104	0.02
217.3729858	0.12
220.9662476	0.04
223.0872650	0.07
229.2000732	0.12
233.2207031	0.03
239.0483093	0.15
254.9157715	0.07
257.0663147	0.08
261.2505798	0.06
270.1108093	0.10
279.0438843	0.04
281.1617126	100.00
281.9467773	0.03
297.1473999	0.15
299.1589050	0.13
300.5781250	0.04
302.2593994	0.06
311.4657288	0.07
317.1967163	0.10
318.9029846	0.07
321.1439209	0.13
323.2572021	0.18
325.0156250	0.07
329.4159851	0.28
331.1183777	0.08
332.3430176	0.11
337.3537903	0.03
339.4349060	0.12
343.3057861	0.08
345.2534180	0.07
346.9425049	0.16
351.3267822	0.24
354.6484070	0.06
357.2334595	0.25
372.2874756	0.28
373.2348328	0.75
374.3501892	0.28
375.3006897	0.27
375.9683533	0.09
377.3097534	0.03
383.0798035	0.07
387.4462585	0.39
389.4757996	0.05
390.9854431	0.13
399.1447449	0.44
401.1702576	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	211.0807
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
75.8675003	0.13
84.7525482	0.05
87.8848114	0.08
94.8763275	0.19
100.0769958	0.02
102.8601837	0.20
104.7975769	0.07
107.7949829	0.15
109.0550690	0.12
113.8222351	0.11
116.0094452	0.04
122.9581146	0.47
129.6585541	0.49
132.9629974	10.79
135.8394012	0.10
137.0835114	0.22
137.9003601	0.11
139.0356140	0.06
141.0371094	0.05
142.1630554	0.06
142.9841156	0.24
146.8403778	0.32
148.9475708	0.28
150.7763214	19.83
153.0139008	0.41
153.7560120	0.26
156.9773560	0.25
161.1236420	0.06
164.9106140	2.44
166.1479645	0.12
168.0696411	0.06
169.1017914	0.65
171.3329620	0.02
172.0664215	0.24
173.9368134	0.18
175.0907288	0.35
176.0625458	0.08
178.2864532	11.79
178.9114685	59.28
183.1548309	0.95
188.5422516	0.33
193.0078125	100.00
193.9791718	0.47
195.4318695	0.09
196.0990295	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.0829
Annotation	Zeanoside B
Peak:m/z	Relative Intensity
107.8543625	0.58
112.9390564	0.15
115.9324799	0.82
143.0571594	0.28
151.9336700	0.49
157.1035461	0.15
159.9433899	100.00
161.0263519	0.06
166.9287109	4.42
168.0745850	0.93
178.0341187	0.08
184.9662018	0.11
202.0050201	0.16
204.0724792	37.76
208.0221252	0.60
208.9979553	0.27
229.2091370	0.27
264.1110229	0.19
274.9530334	0.19
281.8231812	0.16
288.0267334	0.63
302.1823730	0.09
307.1335144	0.27
316.9655457	0.15
318.5733032	0.12
319.2609253	0.59
320.0642090	0.81
321.1480713	0.63
322.2375793	0.25
329.0529175	7.65
330.1384583	2.90
331.0692749	0.70
335.2488708	0.68
347.3811340	0.44
348.2630920	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	953.4692
Annotation	Angiotensin (1-7)
Peak:m/z	Relative Intensity
338.0888672	0.13
361.2163086	0.16
391.6774902	0.09
417.3527832	0.07
444.9727173	0.09
445.8256226	0.03
493.4850464	0.23
504.3538208	0.16
529.3724976	0.10
561.6323242	0.03
575.5965576	0.05
616.8497314	0.10
652.6332397	0.31
684.3504028	0.20
702.3441162	0.22
729.4147339	0.05
746.4371338	0.29
749.5150757	0.22
767.1798706	0.29
769.7702026	0.82
778.7127075	0.89
783.1211548	0.43
790.2611694	0.15
801.3792114	0.40
809.6071777	0.32
810.8668823	0.31
811.8256226	0.07
820.7178955	0.34
822.0399170	0.29
823.2969971	0.27
827.8923950	0.41
830.3049927	0.16
833.3281250	0.44
836.1465454	0.40
836.8465576	0.38
837.9384155	0.13
844.5321045	0.38
846.8250122	0.94
848.8238525	0.16
850.7898560	0.73
852.7345581	1.71
858.5446167	0.26
860.9004517	1.03
861.6688843	0.09
862.5111694	0.40
863.5373535	1.02
864.6621704	0.39
865.3402710	0.17
866.0100098	0.09
868.1729126	0.78
868.9689941	0.25
870.9645386	0.55
871.8099976	0.49
873.4778442	0.84
875.2444458	1.83
876.3304443	0.77
878.5299683	0.38
880.6470337	1.30
881.4649048	1.31
882.4812622	0.08
883.5420532	0.97
885.1235962	0.36
886.9241943	0.97
889.2196045	0.32
890.6293335	1.87
891.6348267	0.44
892.5770874	0.88
894.3485718	1.26
896.4855957	1.49
897.4989624	0.17
898.6577148	1.14
900.1080933	0.67
901.1090698	0.99
903.2151489	0.45
904.5559692	5.11
905.5645752	3.81
908.0484009	0.57
909.0515747	0.21
910.7616577	0.53
914.1147461	2.27
915.3656616	2.38
916.1343384	0.25
917.6497803	0.54
920.0338745	4.95
920.9227905	0.50
921.6348267	0.07
922.4479980	0.34
923.4714966	2.02
928.3471680	0.35
929.4352417	3.22
930.5267944	0.54
932.2780762	1.68
933.9797974	1.62
934.8137207	2.06
935.7204590	1.49
936.4467773	0.15
938.2277832	3.13
939.0144043	0.05
940.3873901	0.07
953.6907349	100.00
954.4496460	4.28
955.1120605	0.93
955.7440796	0.58
956.4445190	0.15
957.7355957	1.12
958.3373413	0.58
959.1348267	0.61
960.8643188	0.46
962.5211792	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	731.88
Annotation	Unknow
Peak:m/z	Relative Intensity
229.0994110	0.16
231.0765076	0.24
272.9823608	20.56
273.9652100	7.16
275.0609436	5.24
276.0120239	1.51
387.0235596	13.58
387.9940796	10.03
389.0401001	17.81
390.0484619	4.43
499.6107178	0.16
500.9152222	41.24
501.9205933	32.89
502.9365234	84.94
503.9108276	20.35
598.0049438	0.16
610.1014404	0.22
611.0701904	0.53
612.0031128	0.65
614.9143677	15.88
616.0156250	28.49
616.9021606	100.00
617.8675537	33.48
628.9007568	0.92
629.8711548	1.36
643.9157104	0.12
645.8995972	0.19
646.8882446	1.80
647.8974609	0.33
655.9904175	0.51
657.1079102	4.52
658.0023804	2.43
673.9300537	0.20
674.9793701	2.57
676.0115356	1.82
685.1254272	1.96
686.2105103	0.29
703.3767700	0.38
704.2128296	0.43
714.0592651	0.10
731.8364868	62.69
733.0660400	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.0569725	0.02
84.9259186	0.51
86.8703613	0.98
110.8648682	100.00
111.8984222	0.03
128.9680481	2.53
130.9234314	0.94
144.7260132	0.23
146.9579163	0.28
154.8963470	0.24
160.2250519	0.12
160.8381348	0.09
171.0088959	0.15
172.9594574	22.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.4
Annotation	Vincristine
Peak:m/z	Relative Intensity
379.4882812	0.36
424.7172241	0.39
478.5443115	0.68
485.7800293	0.27
495.5369873	0.62
496.2746582	0.89
514.2297363	1.89
515.5913086	0.38
538.4452515	0.44
542.2648315	1.01
555.817749	3.88
556.5119629	8.32
557.3984375	0.72
582.5493774	0.85
583.8239746	1.36
584.5099487	0.43
585.3411255	0.53
655.3956299	1.06
673.7605591	0.10
715.9143066	1.31
717.0534058	0.41
759.3268433	0.39
760.300293	4.75
761.5859375	1.63
762.6417236	0.92
778.2385864	3.10
779.2982178	4.94
781.137146	0.30
786.4674072	0.17
804.2869263	0.88
804.977356	0.84
822.6417236	3.96
823.4025269	100.00
824.3569946	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	928.1617
Annotation	Unknow
Peak:m/z	Relative Intensity
297.2752075	0.40
299.3705139	0.11
313.6465454	0.10
314.2885437	0.31
342.2806396	0.06
351.4884644	0.15
380.8867188	0.19
450.2462158	0.10
496.3430786	0.45
522.3108521	0.21
562.0137329	0.10
569.5654907	0.25
667.6373291	0.44
668.2985229	0.12
684.3181763	0.17
728.3393555	0.10
802.7810669	0.32
821.2869263	0.14
826.2213745	3.46
827.7542114	0.42
836.7479858	0.47
839.5679321	0.14
843.1076050	0.53
843.8538208	0.50
845.1636963	0.83
845.8882446	0.17
847.0984497	1.27
849.8041382	0.90
852.9292603	3.12
860.0960083	1.06
862.6632080	0.86
864.5833740	0.65
865.4865112	0.71
867.5105591	1.70
871.2305298	5.46
872.1206665	18.23
873.6281128	0.44
885.2968140	0.81
888.1884155	0.23
889.6793823	0.59
890.3946533	0.11
893.0029907	0.50
896.9619751	1.29
900.3076172	2.85
900.9998169	0.29
904.3815918	0.75
904.9857788	1.70
905.7732544	0.25
908.8692627	1.15
910.7282715	1.98
911.7359009	0.45
914.8216553	0.13
917.5465698	0.29
929.6359863	10.15
930.5590210	1.42
942.5728149	0.04
948.6209106	0.23
951.6560059	0.79
952.5886841	0.36
955.7683716	0.14
956.4914551	0.31
962.4126587	0.49
963.8855591	0.42
968.2170410	1.10
996.6638184	0.38
997.2962036	0.55
1002.7355350	0.81
1012.1499020	0.66
1013.1286010	0.38
1021.4651490	0.74
1024.0023190	0.19
1024.7800290	1.19
1026.0979000	0.58
1030.7277830	0.49
1033.9453120	0.30
1035.6680910	1.03
1042.2171630	0.85
1044.7596440	0.61
1046.0852050	0.24
1048.4753420	0.21
1050.2226560	0.67
1056.7060550	0.10
1057.7468260	0.23
1058.4711910	0.59
1065.3142090	0.64
1068.5004880	0.77
1072.1206050	0.48
1073.1402590	0.42
1073.7990720	0.60
1075.5095210	0.54
1077.1027830	0.66
1081.6187740	1.48
1082.6550290	0.14
1085.7382810	2.27
1086.3662110	0.46
1087.9804690	0.55
1089.9454350	1.71
1091.6245120	6.94
1092.6267090	1.49
1095.2281490	2.54
1096.1359860	1.12
1100.0190430	3.81
1100.8551030	4.95
1101.6497800	11.39
1102.3820800	1.07
1103.9267580	1.45
1104.8864750	0.93
1105.6433110	1.51
1108.6276860	0.43
1112.1843260	1.98
1112.9567870	1.42
1114.0395510	1.47
1114.6729740	1.75
1116.3071290	0.26
1117.9686280	4.90
1119.0993650	0.92
1120.1724850	0.42
1120.8210450	0.15
1121.9461670	0.37
1123.9746090	15.81
1124.6158450	25.88
1125.4577640	0.46
1127.0163570	0.61
1128.9422610	3.71
1129.7575680	1.03
1130.4637450	1.91
1134.1623540	1.58
1137.0552980	0.87
1138.6595460	0.46
1139.5695800	0.98
1140.7036130	0.16
1142.1064450	2.45
1143.0386960	1.27
1145.0114750	0.20
1145.8940430	0.08
1146.7644040	1.16
1149.8613280	2.55
1151.1424560	0.35
1152.7991940	2.02
1155.7988280	5.32
1156.5126950	1.28
1157.2143550	1.77
1158.3657230	1.98
1161.2729490	13.37
1162.1223140	100.00
1163.1506350	6.45
1163.9157710	0.59
1164.6656490	0.58
1165.4224850	0.65
1166.6752930	3.29
1167.5751950	5.14
1168.2014160	1.75
1169.6101070	0.61
1170.6234130	1.01
1171.6770020	0.96
1174.1376950	0.21
1175.7927250	1.13
1176.5639650	1.13
1177.3215330	0.55
1179.4987790	0.45
1180.6921390	1.02
1181.4027100	1.89
1182.0823970	0.29
1183.1691890	0.26
1183.8125000	1.22
1184.9780270	0.81
1185.9857180	2.02
1188.9005130	2.65
1190.5208740	0.34
1191.6203610	1.07
1194.0893550	9.99
1195.0197750	6.42
1195.9282230	1.20
1196.6424560	0.79
1197.7751460	0.81
1198.7777100	0.67
1200.2042240	67.86
1200.9965820	31.29
1202.1098630	0.80
1203.7163090	0.53
1204.9394530	6.71
1205.8640140	1.33
1207.0213620	0.38
1208.6708980	0.30
1209.8728030	0.89
1214.7080080	0.93
1222.5378420	0.62
1233.4918210	0.70
1267.2829590	0.52
1284.8209230	0.08
1285.8101810	0.10
1293.5999760	1.77
1297.7850340	0.73
1313.5605470	0.58
1328.1585690	0.52
1331.5163570	0.57
1334.8563230	0.61
1335.5610350	0.46
1341.6069340	0.41
1346.9473880	0.16
1355.2321780	0.29
1387.9630130	0.50
1395.1448970	0.34
1408.4243160	0.33
1409.4559330	0.41
1410.7633060	0.85
1412.7403560	0.77
1413.4473880	0.22
1430.0209960	0.27
1435.7904050	0.40
1438.7449950	0.35
1439.9307860	0.33
1445.6434330	0.57
1448.4381100	0.13
1449.3010250	0.33
1454.2763670	0.87
1480.1094970	1.15
1483.9947510	0.23
1486.3201900	0.48
1496.2166750	0.48
1501.4659420	0.35
1502.6246340	0.30
1503.9835210	0.20
1505.0874020	0.66
1508.7875980	1.06
1514.5250240	0.40
1517.6942140	0.37
1518.6597900	0.28
1520.3204350	0.49
1523.9681400	0.64
1538.0902100	0.06
1542.5225830	0.24
1543.8895260	0.15
1544.8951420	0.62
1546.1140140	0.30
1548.7368160	0.10
1552.0703120	0.57
1559.3148190	0.21
1560.6824950	1.27
1561.4410400	0.07
1565.9205320	0.89
1567.9857180	1.16
1572.5634770	0.31
1586.5264890	0.11
1587.3582760	0.23
1594.8006590	0.79
1601.7457280	0.66
1608.9293210	0.21
1616.4906010	0.34
1617.8636470	0.26
1619.8607180	0.14
1621.4909670	0.12
1628.3343510	1.44
1636.9387210	0.81
1652.2819820	0.16
1665.6193850	0.16
1666.4459230	0.25
1669.4124760	0.30
1670.4405520	0.57
1671.5280760	0.11
1678.2219240	0.09
1694.4234620	0.61
1708.1986080	0.19
1720.2620850	0.37
1801.8527830	0.06
1842.2652590	0.15
1861.9173580	0.34
1886.6168210	0.22
1894.4128420	0.22
1952.9240720	15.36
1974.2518310	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.09
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9828415	9.77
134.8892365	0.14
140.7348785	0.12
144.8758850	5.23
149.1488495	0.15
150.1395874	0.05
157.0239868	0.04
162.8414001	4.24
165.0294189	0.10
171.9789734	0.07
172.8019714	0.27
177.1333160	0.10
182.3712158	0.12
187.0448914	0.08
192.7131653	0.58
193.4087372	0.40
194.3447266	1.34
194.9699097	9.20
198.9215088	0.46
201.1250000	0.58
203.0167694	0.30
207.4627838	0.07
209.2022858	0.05
210.9729309	0.40
216.8883362	0.50
223.0255127	1.77
224.1784668	0.70
224.8866882	6.01
228.9728546	0.76
231.1259003	0.10
235.0493469	0.25
240.9179688	0.42
242.8028564	5.12
244.8755798	0.07
246.9107666	0.84
247.5544128	0.04
252.0969238	0.55
253.0063171	4.04
255.0470886	0.23
257.9374695	0.82
258.8731689	6.17
260.3576965	6.21
260.9753418	46.84
264.3097839	0.12
265.0191956	0.04
267.3747253	0.61
268.5101624	0.11
269.5492554	0.37
271.0252991	9.24
272.1428833	0.34
279.1471558	0.35
283.1340332	0.29
287.3688965	0.83
288.8861084	35.94
290.2177734	2.38
291.3422241	0.20
294.3012085	0.40
296.7270508	0.12
297.4682617	0.35
304.5796509	0.51
306.8541260	3.51
308.2556763	0.13
314.1428223	0.92
315.1679993	0.09
318.3034058	0.06
324.9527588	100.00
325.5892944	0.21
333.1715088	0.35
334.5740967	0.50
335.6656494	0.09
337.0422974	0.20
341.6349792	0.35
344.8915100	0.05
353.8715210	0.22
356.4783630	0.34
357.1404724	0.29
361.9929504	0.33
364.9503784	0.22
369.0200500	0.11
376.3118896	0.05
386.3579712	0.09
387.0890808	0.45
402.1734924	0.14
403.1318970	0.40
404.2159119	1.21
405.2722778	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.4143
Annotation	Mezzettiaside 2
Peak:m/z	Relative Intensity
355.4677734	0.02
507.3256226	0.05
513.5687866	0.04
514.7020264	0.10
626.5049438	0.03
628.4489746	0.08
629.7058716	0.04
671.4450684	0.04
672.5219116	0.33
730.9269409	0.03
746.2263794	0.04
814.6229858	0.41
833.5714722	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	305.1082
Annotation	Vicine
Peak:m/z	Relative Intensity
86.8834839	0.18
126.0929108	0.03
142.9142303	100.00
143.6724243	0.02
160.9838562	0.02
184.7656708	0.02
189.1570435	0.02
212.9716187	0.24
222.8115540	0.07
240.9409790	0.11
248.2872314	0.22
253.0401001	0.19
258.1886292	0.06
263.9616699	0.09
267.2212524	0.19
285.8864136	0.08
287.2329407	0.18
287.8705750	0.03
293.6151123	0.13
295.1770935	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1766
Annotation	Lactucaside
Peak:m/z	Relative Intensity
165.0414734	1.69
177.9088745	2.38
180.2664795	0.14
193.0979309	31.56
195.1079712	5.98
220.9140015	0.04
223.1595154	0.20
233.1160431	0.37
235.1247864	0.95
236.0127869	0.08
241.1617432	0.09
242.2939606	0.20
243.2492981	0.40
249.2532349	0.19
250.1843872	0.44
254.0525665	0.08
257.1896057	0.14
265.2147217	0.43
282.2284546	0.25
287.9254761	0.08
290.9799500	0.13
296.7335205	0.20
297.3426514	0.26
304.2639160	0.15
305.0490112	0.08
306.2938232	0.05
309.2271118	0.28
310.9063721	0.11
327.0380859	0.51
341.2549438	43.65
342.2969360	0.34
344.3407593	0.03
359.1007080	0.27
371.1985474	0.72
377.1273193	0.24
380.1926270	0.08
383.1452026	0.32
387.4508057	0.10
389.1183472	100.00
395.0967407	0.15
431.0366821	0.48
455.2584839	0.08
460.4269409	0.18
465.1983643	0.07
479.5449219	0.11
488.3706665	0.37
505.2341919	0.49
506.4274292	0.53
507.4387817	0.07
515.3320923	0.25
531.3544312	0.38
532.0822144	0.30
552.3352661	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	322.0932
Annotation	Indole-3-carboxylic acid beta-D-glucopyranosyl ester
Peak:m/z	Relative Intensity
93.9954071	0.04
96.9978790	0.05
101.2229462	0.13
106.5790482	0.11
112.9882050	1.34
114.9482727	0.15
115.9721222	8.32
118.9945068	0.57
125.1849976	0.40
127.8955078	0.33
129.2052612	0.26
130.6613159	0.27
142.8438110	0.85
144.0649414	0.26
144.8731689	0.20
148.3918152	0.07
149.1387634	0.06
158.0592651	0.14
159.9592285	75.93
160.9648743	0.19
170.2405548	0.10
171.9955750	0.25
174.0320740	0.83
179.1421967	0.37
184.0270233	0.36
186.1627502	0.17
199.7662659	0.17
202.0545959	29.71
208.2410583	0.05
212.1310425	0.65
226.1488342	0.17
232.1271057	9.18
235.3032227	0.09
244.0363159	0.16
250.1785889	0.23
256.1322632	0.49
260.0909729	0.09
262.0767822	100.00
264.2662964	0.08
265.9981689	0.15
276.0895691	1.41
278.2813416	0.30
292.1733398	0.50
293.3380432	0.10
301.1713867	0.16
303.0429077	0.17
304.2328796	2.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
116.7983704	2.99
145.1244812	0.39
149.1590881	0.45
169.243103	1.86
174.207016	0.74
179.0224152	0.80
192.9677277	0.33
194.925354	0.57
205.9922943	2.66
207.0597992	12.84
208.2233734	3.73
209.3480835	0.77
222.0740356	7.51
223.2202759	8.13
224.359787	2.84
233.1036987	0.50
236.5394287	1.30
251.0715485	100.00
252.0853424	8.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	500.2148
Annotation	Unknow
Peak:m/z	Relative Intensity
143.1900635	0.12
146.9244995	0.13
153.1699677	0.12
154.8596344	0.23
156.9121399	0.38
159.9917297	0.24
166.1056366	0.39
169.9890442	0.11
177.0331726	0.87
178.0730286	0.19
178.9230957	0.06
180.8471375	0.81
182.4400635	0.13
183.9662170	41.52
184.8253479	0.50
185.7319641	0.27
188.7595215	0.21
192.3162231	0.11
199.1043091	0.20
202.0180359	0.09
207.3813782	0.30
209.2292480	0.05
210.0219574	0.19
221.1022034	0.12
222.3054810	0.07
225.5067596	0.53
227.1647797	0.10
229.3194275	0.20
231.8366089	0.57
234.2082520	0.18
245.2128601	0.29
247.1664429	0.17
249.2825928	0.24
252.8904266	0.18
256.0716553	0.37
256.9960938	0.40
261.9669800	0.21
263.2518005	0.28
266.0216064	0.42
269.2167969	0.10
278.7890320	0.53
279.8881836	0.06
281.2678833	0.08
281.9963684	0.06
284.2643433	0.55
285.1231079	0.23
288.3001709	0.06
290.3062744	0.11
293.3062439	0.18
295.3948669	0.11
297.1886597	0.36
299.1439209	0.31
301.2477417	1.71
303.2144775	0.43
303.9260254	0.29
304.7827148	0.29
306.1448364	1.20
307.0026550	0.06
308.0732727	0.19
310.1947021	0.46
311.0577393	0.27
314.5189209	0.11
320.7812500	0.39
322.1832886	1.05
323.4176025	0.54
326.3746338	0.11
327.7546997	0.43
330.1935425	0.18
332.1300659	0.17
333.0817871	1.37
334.2359619	0.80
335.2710876	0.30
338.4263306	0.84
339.1783752	1.00
340.0598755	0.11
342.4003296	0.21
345.7411499	0.63
351.2091980	0.42
352.3759766	0.84
358.4170227	1.55
361.3777161	0.42
362.5632324	0.39
364.3390808	0.17
366.5906372	0.86
367.3198853	0.31
368.8033447	1.08
369.5967407	0.19
371.0464478	0.12
375.2574158	3.31
375.9292603	0.30
376.8544922	0.39
378.0688171	0.19
381.0556641	0.92
381.8471069	0.23
384.2395630	0.50
387.9547119	0.26
389.5646362	0.51
390.7557373	2.42
391.9636536	0.31
393.1982727	0.13
394.6332703	0.35
396.9981995	0.08
399.1736145	0.37
401.3960266	0.41
402.0709229	0.50
404.1039124	0.37
405.1592102	0.71
405.9098511	0.25
407.4506531	0.27
408.9538269	1.80
410.1035156	0.23
413.8978271	1.11
415.3027039	0.39
416.6612244	1.41
417.8661194	11.30
418.9558411	1.61
420.7013855	0.65
423.6249390	0.50
425.3998108	0.45
426.7635498	100.00
427.3867493	3.42
428.4056702	0.05
432.9728088	0.18
435.7301636	1.95
436.9711304	0.81
439.8291626	1.02
442.2486877	0.24
443.2922974	0.68
444.6011353	1.01
447.0138855	0.12
448.2751465	0.31
450.9780273	1.41
453.7527466	2.94
455.3508606	1.09
456.0315247	0.28
458.6337891	0.23
459.2366638	0.30
460.2967224	0.20
462.7434387	2.97
464.7834167	0.53
466.2348938	0.33
467.7153625	0.07
468.9204712	0.24
473.3830261	1.23
476.5442810	0.51
477.4630432	0.39
478.9850464	0.33
482.1353455	3.92
482.7929993	2.68
483.4424133	0.73
484.3204956	0.12
485.5251770	0.13
486.7298889	0.36
490.2345581	0.16
491.3845520	0.69
492.4602661	0.37
507.5063171	0.46
520.4578247	0.31
530.5205078	0.27
531.3856812	0.26
535.6446533	0.14
540.8316040	0.15
541.4595337	0.26
543.3005981	0.44
545.5604858	0.21
548.3413086	0.09
552.1576538	0.13
556.8770142	0.06
559.5228271	0.12
566.3517456	0.96
567.3197632	0.14
568.2368774	0.04
569.3558350	0.52
571.3446655	0.16
572.6408081	0.16
575.2886963	0.47
576.5392456	0.38
579.2906494	0.09
584.3956299	0.29
588.6347046	0.17
590.1438599	0.14
592.4271851	0.32
594.6348267	0.38
596.2631836	1.09
597.2406006	1.82
597.9428101	0.14
598.5671997	0.28
600.0618286	0.12
604.4514160	0.07
605.5914917	1.31
608.6596069	0.42
616.6550903	0.15
619.2339478	0.25
620.4275513	0.79
623.3256226	0.64
629.3011475	0.07
633.3847656	0.98
634.9622192	1.78
641.1403198	0.34
647.1699829	0.07
649.2569580	0.06
651.3769531	7.10
652.0727539	0.48
652.6743164	0.45
654.2924805	0.14
657.6091919	0.50
658.3593140	1.51
662.6797485	0.07
669.4475708	10.11
670.2780762	0.46
676.3406372	0.92
677.3705444	0.78
678.5946655	0.32
679.6840210	0.09
680.6516724	0.29
685.3385620	0.20
687.6878662	0.81
690.3052368	0.13
692.4276123	0.58
695.6338501	0.13
696.5227051	0.96
700.5056763	0.25
702.3700562	0.19
705.9052124	0.35
708.3923950	0.77
709.4213257	0.28
716.4640503	0.39
717.8511963	0.40
720.4366455	0.13
723.4086914	1.84
724.6057739	0.20
726.4744263	0.86
728.1232300	0.14
732.2711792	0.07
736.6737671	0.63
737.8043823	0.21
741.3124390	2.45
742.0972290	0.10
744.4640503	1.28
745.4143677	0.16
746.8180542	1.21
752.6430054	0.42
759.5949097	0.35
762.5628052	1.49
763.5803223	0.90
780.4283447	4.02
781.6733398	0.62
796.2904053	0.23
798.4415894	22.07
799.3146362	1.53
816.4207153	17.35
817.4953003	1.45
836.6833496	0.28
849.5287476	0.07
896.6041870	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	590.2391
Annotation	Unknow
Peak:m/z	Relative Intensity
166.8518066	0.15
177.0143127	0.51
179.0214386	4.38
183.1661377	0.30
184.9426880	0.13
192.1065369	0.25
192.9519043	0.36
197.2337189	0.14
210.0995941	2.65
211.2455750	0.56
227.2576294	0.36
228.3070374	0.52
230.9569092	0.06
236.2026672	0.19
236.9970703	0.22
242.2780914	0.36
249.2101135	0.11
254.0751495	11.79
260.2374268	0.07
262.1622620	0.13
272.2186279	11.59
283.4681396	0.31
288.0848389	7.56
304.1172180	0.13
306.1730957	100.00
314.1026001	0.33
319.2922974	0.28
322.2560425	0.11
325.1239624	0.10
332.1582642	2.38
342.3023071	0.33
351.4236450	0.33
353.2995605	0.17
359.3244629	0.25
371.3339233	0.07
377.2835083	0.26
382.3059692	0.34
388.3444824	0.13
406.9452515	0.15
412.2175293	0.06
429.0480347	0.86
430.2025146	0.19
432.4754639	0.52
443.5259399	1.58
444.3861694	0.21
454.2029419	0.14
457.3032837	0.21
461.1185303	0.21
470.4645996	0.05
472.5818481	0.46
476.3354492	0.13
492.3504028	0.13
503.3914795	0.46
504.3753662	0.24
511.3630981	0.25
527.3085327	0.10
528.3784790	1.58
529.2110596	0.09
544.3923950	0.61
545.7368774	0.33
546.4470215	0.64
547.4396362	0.23
553.2474976	0.20
554.2078857	0.17
558.5524902	0.08
559.6635132	0.05
570.1687622	0.28
571.4254761	0.98
572.2205811	2.29
572.9332275	0.05
574.0857544	0.32
575.2175903	0.68
590.9618530	0.97
591.6256714	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2205
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2711792	0.20
210.3020782	0.32
237.0425110	0.11
239.2397461	0.31
250.3579712	0.06
254.0195770	0.83
255.2091827	0.74
265.9004822	0.29
267.1932373	0.12
272.2117004	0.87
284.2402344	3.98
285.2433472	0.40
323.1301270	0.19
329.3769531	0.07
342.6450806	0.55
346.0143127	0.04
365.3544312	0.09
374.5974731	0.15
410.3175659	0.25
412.3350830	0.08
420.2490845	98.78
421.3494873	17.58
437.8847046	1.18
439.0513306	0.52
461.1402588	0.35
462.3801880	0.34
469.2965088	0.11
478.5626221	0.09
488.6702881	0.06
490.4349365	0.04
492.1673584	0.23
495.1934204	0.79
503.4772949	0.14
506.3640747	0.06
507.3734131	2.30
508.3513794	0.69
515.2899780	0.15
520.4514160	0.72
521.2875977	0.20
525.2326050	0.06
539.3848267	2.01
540.3063965	0.49
546.5259399	0.33
549.3115234	0.24
551.9520874	0.11
554.6307983	0.47
564.3654785	47.54
565.3430786	7.60
572.4434204	0.06
574.3662109	0.85
575.3150024	0.07
587.4364014	0.45
595.4521484	0.17
600.3351440	7.07
601.4020386	1.47
602.6207275	0.25
605.5753174	0.09
610.1840210	0.44
614.4475708	1.88
616.5429077	0.12
618.2798462	1.03
619.6190796	0.27
627.6994019	0.30
631.3489380	5.41
632.4626465	1.28
633.3394165	0.22
634.6167603	0.35
635.3464966	0.06
647.1720581	0.41
647.9835815	0.05
649.5640259	0.26
650.2340698	0.15
653.4304199	0.40
657.4938354	1.72
658.2586060	0.20
659.4258423	0.22
661.3309937	1.03
663.3876343	0.09
664.0341187	0.29
665.9562378	0.19
673.2459106	0.10
675.3521118	100.00
676.3850708	29.08
677.2866211	0.20
694.3480225	54.09
695.3461304	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.21
Annotation	6-O-Oleuropeoylsucrose
Peak:m/z	Relative Intensity
149.0642242	0.17
161.0276184	0.08
167.1056213	0.07
178.9629364	0.03
188.1761169	0.07
193.3001099	0.14
220.4005432	0.09
221.0559387	0.08
231.0728149	0.09
233.1168671	0.54
240.9722595	0.19
254.2234802	0.04
264.5661316	0.11
293.2091675	2.85
311.0663452	0.64
316.0912476	0.41
329.2006836	0.34
344.2423096	0.21
345.2155762	0.29
374.2531433	0.26
384.0571594	0.21
393.2733459	0.65
410.7721863	0.50
415.4194336	0.19
417.3834534	0.45
419.2912292	0.12
429.2374573	0.24
433.4079285	0.07
440.1571350	0.11
444.6791687	0.05
461.2670898	100.00
462.0178528	0.13
463.3262329	0.20
470.2833862	0.04
471.0783386	1.45
477.1900024	0.13
486.8987732	0.58
487.5779419	0.54
488.2786255	3.02
489.3000183	2.39
490.2926331	0.09
508.1604309	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	524.7523
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1356506	0.05
153.0283661	0.24
155.2681580	0.04
156.0826874	0.13
157.0411072	0.03
163.1050415	0.46
170.7963562	0.18
173.0153809	0.31
175.4060059	0.03
177.0825653	0.15
178.1526184	0.05
178.9509277	0.10
180.9144592	0.61
184.0408936	0.42
188.0436096	0.15
190.7814636	0.19
193.0554657	0.48
199.2323303	0.21
200.4019165	0.05
206.1291199	0.33
209.1172485	1.36
209.9925537	0.17
211.0806732	0.08
212.1808167	0.08
213.1663361	0.19
221.0540771	0.07
226.1270142	0.04
229.4116516	0.03
233.0588989	0.13
234.8402710	0.27
235.8372345	0.23
237.0671082	0.14
238.1230164	0.25
239.8979492	0.22
252.6180115	0.25
254.9456787	0.21
256.2741089	0.83
257.1441040	5.16
257.8002930	0.74
265.2822266	0.09
266.3538818	0.13
267.0825195	0.23
271.1608887	0.30
273.9717407	1.13
275.0197754	0.60
278.1821899	0.19
281.5782471	0.29
282.5600586	0.05
283.1889648	0.16
284.5718384	0.78
285.1890259	0.08
288.4547729	2.09
290.3639526	0.19
291.1081543	0.16
292.0255737	0.34
292.7550659	0.34
293.9873657	0.05
295.3537598	0.08
297.0918579	1.73
297.9129028	0.29
301.1263428	0.68
303.6944580	0.19
305.9684448	0.09
308.1979370	0.20
308.8944702	0.41
309.7788086	0.13
310.6840820	0.29
311.3687134	0.27
312.6624756	1.75
317.2488403	0.18
318.7931519	0.32
319.9129639	0.09
321.8281250	9.45
322.9344482	0.28
323.7951660	0.10
325.0553589	0.29
327.5848389	0.52
328.3677979	0.50
329.7693481	0.43
330.4082642	0.19
332.1875610	0.02
333.3937988	0.03
337.1826782	0.10
338.7721558	0.23
340.3068848	0.08
342.1856079	0.09
348.8716431	0.23
350.1845703	0.15
351.0869751	0.19
352.0188599	0.64
352.9023438	0.12
353.7603760	0.28
354.8463745	0.65
355.8929443	0.14
358.2980957	0.19
361.3001099	4.25
362.0866089	0.38
362.8753662	0.13
364.3902588	0.50
365.4295044	0.04
367.4382324	0.70
368.9351807	0.33
370.3186035	7.21
371.3238525	0.21
376.4392090	0.15
379.1346436	2.66
379.8136597	0.69
382.4625244	0.09
383.5026855	0.67
385.1451416	1.87
386.1661377	0.29
387.1057129	0.07
388.4333496	0.72
389.1453247	0.46
392.8845215	1.32
393.6564941	0.12
394.6533813	0.26
395.8431396	0.36
397.3191528	1.16
398.5887451	0.41
399.6732788	0.24
401.5375977	0.03
402.2830811	0.54
403.1182251	0.31
406.2896729	1.01
406.9072876	0.14
408.2983398	0.32
409.5709229	0.16
411.1856079	0.02
412.2359009	0.25
415.0061035	0.11
417.2069092	0.71
418.2525024	0.37
418.9265747	0.08
420.2337036	0.18
421.4199219	0.18
425.9569092	5.52
427.0866089	0.62
428.4818115	0.20
434.9393311	30.26
435.7706299	1.06
437.2185669	0.55
437.8859253	0.22
443.9215698	100.00
445.1505127	1.53
446.9486084	0.50
448.0191650	0.34
451.3582153	1.87
456.3594360	0.08
457.3701172	0.84
458.5554199	0.23
460.7243652	0.02
463.3804932	0.02
467.9086914	0.24
470.3676147	0.22
473.1155396	0.28
478.2841187	0.07
482.2469482	0.14
485.1595459	0.19
487.4511108	0.08
488.4284058	0.22
489.1644897	0.21
491.6099243	0.18
495.1670532	0.18
498.7895508	0.81
504.8442993	0.12
506.2366333	0.53
507.2679443	1.56
508.0984497	0.43
509.5181885	0.24
510.3912964	0.06
511.4688110	0.61
513.5591431	0.33
514.7113647	0.13
516.3270264	0.04
531.4262085	4.97
532.5274048	1.16
534.6141357	0.33
543.6699829	0.06
545.3849487	0.05
547.5524292	1.20
548.7957153	0.52
549.5292969	0.20
551.6125488	0.05
553.4381714	0.06
561.0066528	0.18
561.9038086	0.04
562.6138916	0.03
563.5523682	0.23
565.4904785	0.69
566.4064941	0.06
567.5347290	0.05
568.3953857	0.03
569.5602417	0.09
577.4752808	1.77
581.6317139	0.06
584.2374878	0.12
585.2197266	0.19
586.4612427	0.79
587.4378662	0.20
589.1047974	0.25
593.3224487	1.15
593.9717407	0.38
595.5181274	2.85
596.4636230	0.99
597.2391968	0.31
598.5112915	0.13
602.4920044	0.09
603.3833618	0.09
608.3305054	0.05
611.6863403	0.27
612.6654053	0.03
613.6546021	0.03
615.5617065	0.19
628.5271606	0.37
632.5591431	0.10
633.7271118	0.03
637.4201050	0.03
642.6173096	0.61
651.7977905	0.07
653.7485962	0.20
655.3417358	0.51
656.3410034	0.22
658.8743896	0.25
660.4150391	5.37
661.5383301	0.70
662.6793823	0.10
667.5451050	0.17
670.9147949	0.10
673.5372925	0.25
674.3842163	0.05
676.4490967	0.89
677.3978271	0.24
691.2966919	0.16
697.5737915	0.26
705.3657227	0.04
708.4010010	0.11
710.6347656	0.17
714.1682129	0.10
714.7951050	0.06
715.6472168	0.32
716.5551147	0.07
721.5222168	0.92
722.9000854	0.22
726.6151733	0.54
727.6745605	0.29
728.2905884	0.08
739.4731445	1.95
740.5684814	0.49
741.3601074	0.09
743.6022339	0.28
751.6478882	0.06
754.7797241	0.13
757.4943848	1.36
758.3616333	0.19
763.4646606	0.13
772.5650024	0.07
778.8480225	0.11
784.5178833	0.11
785.6729126	0.18
789.0736694	0.49
789.6757202	0.19
796.6589355	0.30
798.1015015	0.14
802.7217407	0.03
806.4666138	0.21
808.5859985	0.10
814.2785034	0.07
824.6563110	0.53
825.8568726	0.16
832.8085327	0.16
833.5524292	0.11
850.6403809	1.01
851.6760864	0.29
866.5380249	0.13
868.5285645	5.38
869.4874878	1.94
886.5021973	2.73
887.4614258	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.06
Annotation	Calcium Gluceptate
Peak:m/z	Relative Intensity
88.9410477	5.26
96.8632507	0.05
125.7640533	0.03
132.9871521	0.06
134.8186188	0.67
140.8834991	0.08
152.1586151	0.25
152.7754059	1.20
160.9172516	0.03
179.0807800	100.00
180.2850342	0.06
181.1072235	0.19
186.9743195	0.03
196.8493652	1.26
207.3872070	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.1998
Annotation	Unknow
Peak:m/z	Relative Intensity
137.0786438	0.48
161.9096222	2.30
169.0234070	0.67
174.8513184	1.57
178.1330261	1.06
179.0006409	2.90
180.2302551	0.36
193.3076477	0.33
198.9656372	0.23
204.6527710	0.18
215.0702515	0.16
217.1232300	0.58
227.2601013	0.41
231.2639008	0.18
232.9584656	1.99
255.1063538	1.85
257.2955017	2.88
263.1001892	0.98
275.1179504	1.27
277.9936829	0.42
285.2876587	3.89
308.0485535	26.85
309.2013245	6.29
309.9817810	0.61
317.3212280	0.91
321.5602722	1.88
334.2610474	0.77
336.4304504	0.20
338.9740295	1.71
340.4515076	1.21
344.0744629	2.53
353.8681641	1.17
362.3519287	2.09
366.1092834	1.29
375.0683594	0.29
379.4734497	1.91
382.3948059	0.46
384.3741150	2.55
387.3601990	100.00
389.0261536	2.55
390.1368713	3.22
391.0674438	0.83
393.3806152	20.88
394.3088074	0.40
395.8056030	0.87
399.1709290	1.04
401.1416931	1.81
402.5982361	1.30
404.0753479	0.21
405.5221252	0.77
406.2971802	0.73
411.7322693	1.90
413.3206787	0.33
420.0683899	0.23
425.2518311	2.58
426.8861694	20.74
427.7698059	1.35
429.0284119	5.04
430.3009949	1.42
432.5258789	3.47
435.3343811	2.78
435.9736633	0.39
466.3188782	0.55
470.3515930	0.87
473.8912659	0.66
498.9773560	1.46
507.9253540	53.62
508.9624939	2.47
510.1108093	0.39
512.3197632	0.19
531.2437744	3.30
537.1592407	0.26
548.5015869	1.11
568.5275879	0.41
571.4190674	1.90
580.5413208	16.14
581.6187134	1.64
582.4277954	0.50
586.4404907	0.52
589.1117554	3.19
589.9660034	1.07
593.9600830	0.63
660.5603027	0.84
723.4512939	3.19
724.5161743	0.31
777.6750488	0.74
834.5256348	1.21
852.6530762	5.08
853.6520386	2.90
854.7822876	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1612
Annotation	1-(3-Methylbutanoyl)-6-apiosylglucose
Peak:m/z	Relative Intensity
124.9601822	0.47
131.0098572	1.74
139.1231384	0.25
143.2352295	0.09
148.9582062	4.31
156.8572693	0.05
167.1161041	0.21
172.7829742	0.18
178.9199982	0.05
181.0805054	0.02
191.0885315	0.73
201.0892334	0.03
204.1241302	0.07
206.8507690	0.02
214.9429016	0.08
220.1561127	0.04
222.1033173	0.03
225.2113037	0.12
233.0745850	0.20
251.0974426	0.17
259.2106323	0.02
275.0106812	0.19
278.0572815	0.05
279.2236938	0.16
280.1150513	0.04
293.1372070	47.73
298.2716980	0.05
311.3134766	0.03
315.1477661	0.04
318.8839111	0.06
322.1772461	0.06
323.0612183	0.11
334.8050232	0.17
339.1343079	1.30
345.2058716	0.15
349.9681091	0.15
363.2667236	0.04
379.0793762	0.05
383.9790649	0.08
395.0766296	100.00
395.7531128	0.14
396.4656372	0.06
397.4477539	0.22
422.2330017	0.14
423.1996155	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.8
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9803772	0.03
173.2480469	0.03
193.9039764	0.02
218.9499512	2.67
259.1605225	0.05
273.2025757	0.06
300.7178650	0.14
302.8940735	100.00
330.8758850	0.01
368.1187439	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9219666	2.13
150.1376953	0.35
164.7145081	0.36
165.8203735	0.16
167.9905853	0.07
191.0541382	0.78
192.0742798	0.43
193.0197449	0.16
207.1635132	0.34
220.5322571	0.40
221.3239441	0.07
225.4093933	0.21
226.9869080	0.11
233.0117950	0.57
236.9688110	0.65
248.8523102	0.13
270.0865173	0.08
275.1647644	0.60
279.3094788	0.19
293.0886841	33.28
294.0815735	11.52
297.0056152	2.42
311.1743469	2.62
312.2163391	0.54
324.1907349	0.24
337.2253723	0.35
338.3224792	0.25
339.0850220	0.82
340.0716553	0.54
343.0715332	0.36
353.1376953	0.40
355.2584229	0.07
358.3676453	0.15
368.1563721	0.36
375.8963623	0.08
387.2278137	0.08
388.2880249	0.16
399.1796265	0.54
420.1019897	0.24
426.3235779	0.16
442.7715149	0.06
446.1037903	0.13
448.2589111	0.11
459.1755676	100.00
460.1733704	59.90
461.3098450	0.68
463.4323120	0.78
470.1728210	0.42
477.1842651	0.39
485.1936951	0.28
487.5283508	0.29
488.1968079	0.33
507.1155701	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3968
Annotation	Rifampin
Peak:m/z	Relative Intensity
387.6722412	0.20
425.4633179	0.14
514.5508423	0.08
556.5780029	0.10
621.1326904	0.13
639.3444824	0.18
662.7537231	0.17
736.7164307	0.19
737.7095337	0.12
753.4666138	0.19
762.7865601	0.33
763.5085449	0.04
777.4406738	0.09
778.4002686	0.49
779.7901611	0.24
780.6856689	2.90
791.5274658	0.53
804.4433594	0.16
822.0145874	0.05
823.5585327	100.00
824.4278564	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1013.1078
Annotation	Unknow
Peak:m/z	Relative Intensity
296.5621338	0.03
324.4703979	0.01
341.4854736	0.07
353.5969543	0.03
354.3056946	0.05
358.9336243	0.11
367.3381958	0.11
369.1763916	0.10
393.4603882	0.02
410.1711426	0.05
412.6848145	0.05
438.5017090	0.04
469.6639404	0.06
492.2396545	0.02
529.3385010	0.06
537.1805420	0.10
595.3784180	0.05
628.2280884	0.09
663.1116943	0.07
693.6433105	0.09
697.8139648	0.15
700.2854004	0.06
703.7167358	0.02
711.6215820	0.02
715.9143066	0.04
725.2154541	0.11
756.5172119	0.02
762.5903320	0.02
766.5461426	0.04
784.9993896	0.05
793.1926270	0.07
796.7241211	0.05
807.1188965	0.05
816.2869873	0.15
818.4031982	0.05
824.0152588	0.15
839.0721436	0.08
846.3690186	0.10
852.0336914	0.03
857.3978271	0.09
860.6917725	0.33
861.3706055	0.07
862.5201416	0.09
869.5229492	0.24
879.8188477	0.10
883.0856934	0.10
883.7340088	0.05
884.8312988	0.12
888.3577881	0.19
889.0343018	0.01
890.6560059	0.17
893.4354248	0.42
894.1875000	0.51
897.4816895	0.17
898.9930420	0.22
903.1650391	0.20
903.9788818	0.15
906.0883789	0.07
907.1795654	0.51
907.9897461	0.06
915.1612549	0.29
916.0758057	0.17
917.8249512	0.53
919.5992432	0.09
921.0704346	0.19
922.5296631	0.03
923.3625488	0.07
924.9713135	0.24
925.8696289	0.17
926.8919678	0.31
928.6656494	0.13
929.5805664	0.12
930.6456299	0.20
931.5037842	0.12
936.7016602	0.40
938.2919922	0.06
940.6425781	0.15
941.5620117	0.04
948.0424805	0.09
950.5969238	0.31
953.0389404	0.20
956.5819092	0.33
957.4123535	0.08
958.5590820	0.20
959.9060059	0.47
960.7448730	0.28
963.3221436	0.28
963.9896240	0.13
964.9628906	0.38
966.4865723	0.10
969.0676270	0.31
969.6893311	1.36
970.8328857	0.28
974.5249023	0.89
975.5684814	0.67
977.1998291	0.18
980.0871582	3.29
980.7258301	0.52
981.9624023	0.29
982.5921631	0.28
983.2135010	0.09
984.0524902	0.21
988.3659668	0.27
989.4946289	0.24
992.2596436	0.13
992.9212646	0.06
994.7489014	0.04
996.1845703	0.28
998.2598877	0.66
1003.2570800	0.02
1013.7034910	100.00
1015.0527340	1.68
1016.0056150	0.67
1017.1945800	0.32
1019.4112550	0.10
1020.6508790	0.02
1021.3640140	0.04
1022.3044430	0.10
1023.8253170	0.13
1025.1646730	0.11
1033.8659670	0.08
1072.1716310	0.13
1089.9398190	0.12
1092.3642580	0.11
1106.9067380	0.04
1112.3432620	0.06
1121.4840090	0.12
1132.1204830	0.06
1139.7687990	0.12
1140.4279790	0.02
1147.5168460	0.14
1150.9107670	0.06
1158.2382810	0.09
1160.7778320	0.14
1162.1864010	0.11
1164.2272950	0.04
1171.5983890	0.02
1173.7277830	0.09
1179.1928710	0.04
1182.2038570	0.12
1185.0944820	0.03
1196.2050780	0.17
1197.0052490	0.03
1198.1944580	0.15
1200.4626460	0.05
1202.2470700	0.08
1206.6469730	0.09
1207.3261720	0.13
1212.1367190	0.10
1213.1903080	0.15
1213.8328860	0.17
1215.6690670	0.05
1217.6245120	0.18
1218.8045650	0.08
1223.3216550	0.02
1226.6429440	0.11
1228.2177730	0.16
1229.2144780	0.07
1230.2551270	0.04
1233.7517090	0.08
1237.1492920	0.03
1240.7608640	0.24
1242.1342770	0.27
1243.0717770	0.04
1247.3735350	0.28
1248.7496340	0.21
1251.3843990	0.28
1252.0302730	0.13
1253.7690430	0.31
1255.4019780	0.27
1257.1452640	0.31
1258.9564210	0.07
1260.7578120	0.23
1261.7282710	0.03
1262.7402340	0.08
1263.6599120	0.05
1265.7097170	0.13
1268.9899900	0.12
1270.3671880	0.19
1271.3984380	0.21
1273.2377930	0.04
1274.1611330	0.13
1275.6857910	0.05
1277.7766110	0.08
1278.4099120	0.31
1279.3673100	0.02
1281.8474120	0.40
1283.7416990	0.21
1287.1907960	0.42
1287.8126220	0.12
1289.2719730	0.09
1290.4964600	0.34
1291.1883540	0.02
1292.4259030	0.41
1293.2137450	0.09
1294.9058840	0.21
1297.2004390	0.16
1298.9454350	0.31
1299.6810300	0.05
1302.7398680	0.55
1308.7297360	0.07
1309.9995120	0.10
1311.6649170	0.05
1313.4490970	0.05
1314.3289790	0.08
1323.3696290	0.11
1323.9791260	0.06
1325.5638430	0.13
1326.4554440	0.57
1332.3265380	0.22
1340.1834720	0.61
1340.9791260	0.18
1343.5354000	0.24
1346.3527830	0.07
1347.4399410	0.43
1348.4510500	0.08
1349.6259770	0.22
1355.5360110	0.15
1357.3836670	0.10
1361.2298580	0.06
1363.7989500	0.04
1364.7263180	0.27
1368.8349610	0.14
1377.9132080	0.11
1381.6373290	0.10
1382.2766110	0.29
1383.2069090	0.17
1384.5908200	0.47
1385.4495850	0.17
1386.2615970	0.08
1389.6859130	0.24
1390.4290770	0.23
1394.8389890	0.45
1396.6872560	0.17
1401.1085210	0.15
1403.4183350	0.37
1404.0903320	0.05
1405.2271730	0.12
1407.9981690	0.02
1412.3822020	0.61
1413.3377690	0.39
1416.0418700	0.04
1417.2749020	0.06
1421.1632080	0.19
1422.0173340	0.32
1423.0333250	0.06
1424.0794680	0.05
1424.8262940	0.21
1425.7408450	0.07
1432.2528080	0.12
1434.8918460	0.03
1440.1983640	0.12
1441.9997560	0.05
1444.2728270	0.02
1448.4793700	0.07
1453.0482180	0.03
1454.3504640	0.17
1459.9548340	0.03
1460.6075440	0.11
1461.2148440	0.19
1462.8621830	0.35
1463.5303960	0.19
1467.8920900	0.04
1469.9437260	0.90
1470.6910400	0.08
1478.5285640	0.03
1482.9561770	0.03
1496.7181400	0.03
1515.6097410	0.01
1516.8985600	0.06
1526.0235600	0.02
1534.7427980	0.04
1552.5170900	0.07
1561.2977290	0.03
1563.7550050	0.03
1589.0480960	0.05
1602.9091800	0.01
1605.6086430	0.09
1620.7999270	0.05
1631.2302250	0.06
1640.9837650	0.03
1643.4964600	0.02
1673.8128660	0.03
1691.8708500	0.14
1697.6705320	0.05
1704.9583740	0.01
1712.9094240	0.12
1725.1011960	0.03
1735.6414790	0.03
1746.6573490	0.02
1810.0134280	0.03
1812.8831790	0.08
1813.8391110	0.09
1821.0612790	0.05
1857.4410400	0.08
1872.3609620	0.04
1875.8249510	0.06
1891.3791500	0.02
1897.6253660	0.06
1906.1706540	0.27
1913.1292720	0.04
1916.2427980	0.03
1926.9841310	0.02
1930.0438230	0.05
1941.2435300	0.04
1950.0968020	0.02
1953.9436040	1.12
1959.5500490	0.05
1963.0989990	0.11
1972.9011230	0.25
1983.2149660	0.18
1990.5555420	0.05
1996.3341060	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.4119
Annotation	Cyclopassifloside VII
Peak:m/z	Relative Intensity
249.3013306	0.09
278.8856201	0.17
282.1436768	0.13
294.1605835	0.22
297.3948975	0.21
309.1338806	0.49
323.0121155	0.37
326.1251831	0.38
327.1070557	0.14
338.2451782	1.12
339.1301270	0.09
341.2189636	1.00
348.2420959	0.06
353.2697449	4.72
357.1079102	0.09
369.3361206	0.34
371.1528931	2.37
395.2817383	0.09
405.4815674	0.11
429.3370361	0.11
439.2969971	0.10
457.3085938	0.14
459.5796509	0.08
480.9708862	0.10
487.8555908	0.14
491.1346436	0.18
492.3785400	0.39
505.5134888	9.35
515.1114502	0.13
523.7371216	0.31
533.1164551	0.57
533.8265381	0.04
551.6395264	0.21
573.6378784	0.09
610.6189575	0.09
615.8851929	0.09
620.5934448	0.49
621.4820557	3.35
623.4311523	0.04
625.4345703	0.20
637.3552856	0.20
639.3630981	0.24
648.4818726	0.17
649.5145874	0.56
656.5797729	0.10
665.5563354	0.06
667.4977417	100.00
668.1498413	1.12
669.3836670	1.51
670.2741699	0.05
685.6603394	0.45
693.3226929	0.06
694.5184937	0.28
695.5513306	0.43
713.4631348	40.20
714.7011108	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3919
Annotation	Isonuatigenin 3-[rhamnosyl-(1->2)-glucoside]
Peak:m/z	Relative Intensity
198.8431091	0.37
211.1961060	0.36
217.0799713	0.06
227.1865540	0.09
242.9076538	0.71
256.8601074	0.24
278.2232971	0.14
285.3052063	0.21
319.4700928	0.22
321.5130005	0.72
327.2376099	2.18
337.3540955	0.30
345.1873169	0.78
352.9665527	0.54
375.4456177	0.20
381.3833008	0.44
391.3541870	1.07
418.6361694	0.25
419.4990845	0.42
426.0556030	0.11
452.4208374	0.34
470.2777710	3.76
491.8128662	0.07
502.2913208	0.68
503.3086548	0.78
504.5471802	0.17
516.5001831	0.33
530.1018066	0.30
548.1192017	0.14
553.4216309	0.10
595.0574341	0.10
599.4107056	0.50
609.4404907	4.05
625.2889404	0.30
629.5178833	0.30
631.1725464	0.52
634.5668335	0.36
635.4257202	0.08
639.3121948	0.10
641.3839722	1.57
642.4810181	0.15
653.3857422	100.00
655.1674194	0.08
664.6231079	0.06
665.4480591	0.33
667.0893555	1.59
667.7144775	0.11
669.0642700	0.75
686.4859619	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1819
Annotation	Pyridinoline
Peak:m/z	Relative Intensity
134.1849213	0.22
149.0625610	0.81
150.1875610	0.06
161.1240387	0.09
193.2255096	0.05
201.1867371	0.12
203.2227020	0.08
209.1110840	0.15
233.2982483	0.10
249.2049561	0.15
252.8020630	0.11
263.1008911	0.04
268.0970459	0.03
274.0653687	0.04
279.0524902	0.07
280.2600708	0.08
293.2467041	0.09
295.2974854	0.07
329.2364502	0.19
331.3252563	0.18
333.2166748	0.10
337.1629333	0.12
339.0317383	0.12
339.9257202	0.09
341.2789612	0.22
342.2437134	0.05
342.9541016	0.19
353.0117493	0.06
355.1464539	0.15
363.2284241	0.15
367.3084717	0.05
379.0864563	0.09
381.2242126	100.00
382.0356750	0.39
383.2388000	0.23
384.5088501	0.09
389.0925598	0.16
391.3507996	0.05
399.4308167	0.05
409.1917725	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0477
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
158.7517395	0.12
164.1399078	0.10
182.2043304	0.02
193.0753784	0.05
211.0692444	3.31
236.3220520	0.02
241.0542145	1.77
259.0550537	0.02
273.1557007	0.12
280.0364380	1.64
305.2013855	0.22
321.1228027	0.96
323.0617065	100.00
323.9653931	0.14
385.1876831	2.90
390.8905640	0.03
394.8967896	0.01
396.7388306	0.05
403.2136230	3.39
445.2120361	0.02
451.7476807	0.06
453.1594849	0.03
467.1919556	0.36
478.8273926	0.16
480.7975464	0.79
522.3554688	0.04
547.1449585	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.0466
Annotation	Unknow
Peak:m/z	Relative Intensity
114.7918549	0.06
122.8956299	0.06
128.9672852	0.04
140.9807434	0.48
152.0583191	0.16
158.8938446	0.17
166.0756836	0.02
174.7514343	0.03
177.1969604	0.08
181.0232849	0.05
182.0101624	0.03
186.8989563	0.04
190.9546051	0.30
191.8891449	0.08
192.8424225	0.02
194.8177185	0.05
200.6917419	0.07
203.0084839	100.00
203.7644653	0.03
225.3088989	0.05
227.1218262	0.07
228.0929565	0.09
231.0041809	0.11
233.1208801	0.09
243.6354065	0.03
251.1292114	0.06
252.0468750	0.02
254.0507202	0.02
254.9570312	0.02
271.5390320	0.06
272.2389832	0.02
273.1484985	0.06
277.1239624	0.03
285.2252502	0.10
287.0710144	0.08
293.2649841	0.03
302.9572754	0.23
304.6375732	0.17
306.0433044	0.38
307.1009827	0.13
308.0720520	0.28
309.2207336	1.08
315.0854797	0.02
317.0067139	0.02
320.2208862	0.02
321.0859985	0.05
329.3027954	0.03
331.2011719	0.06
335.0469971	0.02
341.3095093	0.04
343.9576111	0.03
346.9941101	0.03
357.0555725	0.02
358.0856628	0.03
362.9918518	0.35
364.2283936	0.02
374.3822632	0.03
388.3916626	0.33
389.1920471	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.207
Annotation	Astin I
Peak:m/z	Relative Intensity
160.0441589	0.72
163.0511322	0.15
165.8591766	0.03
167.0148926	1.00
169.0722656	0.10
170.1123962	0.03
171.0249329	0.27
172.3415222	0.05
177.0148163	0.73
177.7568817	0.03
179.0086517	4.31
180.1601562	0.64
181.1236877	0.34
182.1185913	0.15
184.9073792	0.47
187.1239471	0.09
192.1249542	0.33
193.1243286	0.10
197.0853271	0.29
199.2268066	0.06
203.0802307	0.11
207.1254425	0.34
210.0743103	2.61
211.1459351	0.75
212.8875732	0.44
214.0719147	0.04
225.2272797	1.20
226.0115814	0.27
228.1343842	0.08
229.0312805	0.04
230.8539734	0.17
233.1440125	0.08
236.2263794	0.51
237.1455078	0.04
242.1167755	0.08
243.1933289	9.23
254.0938416	13.81
255.1713257	1.61
264.1145630	0.07
272.1419373	13.00
273.2252197	2.30
279.4252014	0.04
282.3406372	0.08
285.3220215	0.14
286.1800842	0.04
288.1528625	8.77
289.0952759	1.38
299.2555542	0.04
304.2877197	0.05
306.1058350	100.00
307.1281128	16.51
310.3192749	0.12
313.7440796	0.14
314.3850708	0.11
327.1465454	0.05
332.2368164	3.44
333.1239014	0.67
335.2166748	0.10
339.1357422	0.04
350.6685181	0.04
351.4010010	0.10
353.2023926	0.02
354.1386719	0.04
359.3350830	0.06
362.2727051	0.02
371.3988037	0.04
376.3059692	0.08
389.5651245	0.13
415.2761230	0.07
418.3167114	0.03
421.2492065	0.76
422.2532959	0.21
436.1293335	0.07
436.7635498	0.14
443.3596191	0.08
447.0255127	0.02
447.9626465	0.07
455.2832642	0.03
461.3949585	0.14
462.1128540	0.03
463.4283447	0.02
465.2288208	0.02
477.3355713	0.03
485.0341187	0.08
486.1592407	0.17
487.1979980	0.07
488.3555298	0.95
489.3402710	0.23
491.4998169	0.07
493.4543457	0.08
502.1724243	0.10
504.7817993	0.22
505.3986206	0.82
507.3761597	0.22
515.4836426	0.11
516.2306519	0.16
520.2342529	0.03
529.3595581	0.32
532.2202759	2.39
533.2933350	0.59
534.2078247	0.06
535.9131470	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	591.26
Annotation	Swietenin F
Peak:m/z	Relative Intensity
180.7404327	0.14
194.0600281	0.06
195.1116028	0.07
196.9161987	0.13
201.2389221	0.25
202.9928131	0.09
209.2948761	0.06
211.1503143	0.29
215.2063599	0.12
227.1825867	0.31
229.0635681	0.14
238.9472351	0.08
249.9070282	0.05
251.1058350	0.14
253.2218170	0.12
256.0791016	0.11
256.9235229	0.05
260.9964905	0.08
263.0618591	0.07
265.1294556	0.06
267.3352966	0.07
268.2335815	0.04
269.3894653	0.06
274.5586548	0.10
279.2925415	0.17
281.1563110	0.15
283.2717285	0.05
291.4046021	0.15
293.4833984	0.45
294.1239014	0.08
297.4804077	0.22
301.2374268	0.10
307.3444214	0.05
311.3197021	0.15
312.9982300	0.24
319.0816650	0.08
326.3325806	0.09
327.2823486	0.23
330.7872925	0.18
337.3092651	0.05
339.1112671	0.08
341.0399780	0.14
343.2914429	0.32
346.3925171	0.14
347.3512573	0.14
349.3857422	0.20
359.3263550	0.14
363.5698242	0.12
367.1962280	0.19
369.3126221	0.05
371.8910522	0.04
379.3657837	0.05
381.4368896	0.04
383.3611450	0.28
387.2392578	0.09
390.3949585	0.17
394.4422607	0.10
401.0618896	0.30
411.3468628	0.40
412.9574585	0.21
415.0778809	0.08
419.9262695	0.18
427.2597656	0.07
430.0088501	0.45
431.5938110	0.10
433.2017212	0.19
443.6306763	0.13
445.6007690	0.37
446.2651367	0.02
448.5470581	1.12
453.9183960	0.13
457.3849487	0.39
458.5021973	0.14
459.2120972	0.68
460.0645752	0.19
460.9697876	0.19
461.9768066	0.11
469.4264526	0.37
470.1110229	0.15
471.0590820	0.20
471.7860718	0.10
472.4810791	0.04
473.5586548	1.09
474.4486694	1.44
475.5004883	1.52
476.3825684	0.44
483.1998901	0.06
484.1154175	0.18
485.4658203	1.51
486.7291870	1.49
487.5092773	5.14
488.3710938	1.80
489.3261108	1.42
490.4107666	0.19
491.3909302	0.59
492.5581665	0.45
493.6136475	0.05
495.0664673	0.24
498.4376221	0.27
499.6780396	0.27
501.3705444	0.21
502.4052124	1.02
503.3988647	3.07
504.3792114	0.98
505.3803101	0.52
506.1740723	0.32
512.3109131	0.18
513.4119263	0.19
514.5299072	0.41
515.4035034	5.51
516.3295288	1.09
517.2114868	0.56
518.4130249	1.85
519.5012817	1.27
520.1682739	0.24
520.8109741	0.33
521.5760498	0.04
524.5921631	0.03
526.3728027	0.07
527.5327759	0.04
529.2512817	0.14
531.3982544	100.00
532.3283081	44.71
533.3289185	3.55
537.2804565	0.34
541.4897461	1.18
542.4157104	0.53
543.5941772	0.19
544.3391724	0.30
545.5280762	0.34
546.1743774	0.34
547.4304810	2.51
548.1364136	0.56
549.2050171	1.61
550.5480347	0.05
555.2741089	0.35
559.4816284	3.68
560.6376343	0.41
562.2292480	0.52
563.4407959	1.84
564.3198242	0.57
572.1495361	0.43
573.0795288	0.42
573.6962891	0.88
576.4016724	0.10
592.4497070	18.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	642.2809
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0356750	0.55
179.9751892	0.06
192.0675201	0.18
192.9876404	0.18
197.0570984	0.09
210.1040955	5.05
210.9637451	0.75
213.3799591	0.26
215.2734833	0.04
222.0088501	0.07
223.0349426	0.07
236.1522827	0.34
239.2098846	0.25
254.0762482	22.14
255.1285400	1.43
270.9302063	0.15
272.1394043	16.37
273.1032104	1.08
288.1212158	0.19
306.0478516	0.21
307.2664185	0.87
308.6352539	0.13
309.3009338	0.08
323.0936890	0.44
324.3987427	0.07
325.1782227	0.15
335.6375427	0.06
351.3340454	0.81
369.3068848	39.92
370.2972412	8.74
371.0252075	0.06
375.2745972	0.07
408.8544312	0.05
410.3176880	0.06
420.2229004	0.08
426.5476685	0.33
427.3405151	0.13
433.6259155	0.19
438.3411865	0.56
448.3040161	0.13
450.3615723	0.24
456.4381104	0.56
469.8477783	0.68
478.2411499	0.09
479.9940796	0.05
483.2910156	0.11
493.2899170	0.07
495.5175781	2.47
496.3873291	1.18
497.3424683	0.19
499.2385254	0.05
503.2092896	0.04
513.3339233	100.00
514.3692017	14.91
520.4649048	0.12
521.4865723	0.19
523.4487915	0.26
524.3934937	0.32
528.5971069	0.12
529.8439331	0.10
532.5369873	0.19
537.4254761	0.21
545.6585083	0.05
548.1113281	0.10
549.2272339	0.29
550.6774292	0.20
552.1056519	0.11
555.3356323	0.25
557.6374512	0.23
560.1390991	0.61
562.0660400	0.27
563.5704346	0.10
564.3009644	0.25
567.4258423	0.13
568.4600830	0.19
570.2695923	0.60
576.2243652	0.09
578.9839478	0.20
582.2897339	0.26
583.2142944	0.14
588.3468018	0.34
589.3701782	0.42
590.2808838	0.13
595.3552856	0.60
596.6597900	0.46
597.6696167	0.73
598.7031250	0.24
604.3001709	0.07
606.2814941	1.98
606.9734497	0.63
607.6395264	0.57
608.4681396	0.10
610.9712524	0.13
611.6616821	0.69
616.3690796	0.10
619.1691284	0.90
620.2566528	0.11
624.3954468	42.45
625.4306030	12.18
626.5989990	0.04
643.4197998	10.60
644.3206177	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.0961
Annotation	Zeanoside B
Peak:m/z	Relative Intensity
104.9442673	0.03
116.7567596	0.06
120.9121552	0.04
130.0778656	0.04
131.8919373	0.18
134.9386597	0.09
152.9176483	0.08
157.0251465	0.10
160.0254822	0.73
162.8493958	0.01
169.0730896	0.14
170.0902252	0.02
171.1918335	0.06
173.1182556	0.05
174.9259186	0.27
178.0848236	0.64
184.0203247	0.08
187.3847046	0.11
187.9999847	2.24
188.9490967	0.04
191.3226929	0.05
192.9604187	0.01
201.0625305	0.07
205.9925385	100.00
206.5925446	0.08
214.9475555	0.02
225.2012939	0.01
232.9754944	0.04
234.0059204	0.03
234.9691772	0.05
238.1437378	0.04
252.0548096	0.18
253.1543274	0.09
258.2765198	0.05
263.1320496	0.06
269.2440796	0.11
279.1311951	0.12
283.2256470	0.06
284.7252502	0.05
286.5708618	0.25
292.0982666	0.02
293.1146851	0.03
293.7973633	0.07
296.0101624	0.11
297.1664429	0.13
301.9244690	0.02
303.6560059	0.07
304.8534851	0.02
307.0777893	0.07
307.8234558	0.18
308.8474426	0.11
311.0005188	0.28
313.1457520	0.02
313.9031372	0.05
314.7714844	0.03
321.3095703	0.15
322.2615967	0.02
323.2859497	0.05
325.1838989	0.02
326.7460022	0.02
327.3659668	0.67
329.9277039	0.02
332.0063477	0.04
333.2413635	0.02
335.3187256	0.33
336.1170959	0.02
339.1011963	0.07
340.5543518	0.11
345.0999451	0.37
345.7355652	0.20
347.1774597	0.05
349.1532898	0.21
350.1032410	0.60
350.9998474	0.45
353.3475037	0.01
358.9673767	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	837.3216
Annotation	Unknow
Peak:m/z	Relative Intensity
319.2735291	0.02
374.1865845	0.16
456.5066528	0.15
513.3140869	0.03
537.2941284	0.13
555.3931885	0.61
556.0904541	0.01
581.3822632	0.29
588.2736206	0.04
591.5302124	0.05
593.6456909	0.12
599.4772339	3.42
613.1141968	0.02
625.3115845	0.97
631.4395142	0.81
638.3100586	0.04
643.3324585	0.20
644.4594727	0.11
649.0855103	0.14
655.2314453	0.03
657.2637329	0.02
667.5219727	0.09
675.3127441	0.25
681.6867065	0.06
686.3698120	0.07
699.4385376	0.03
717.0499878	0.04
717.7162476	0.03
725.7173462	0.15
729.4590454	0.05
751.8539429	0.11
752.6996460	0.05
758.4718018	0.05
776.4146729	0.05
777.7613525	0.12
782.5304565	0.04
787.4738159	0.05
790.6101685	0.03
792.5383301	0.09
794.7002563	0.07
800.4837036	0.20
804.8989868	1.72
805.5277100	9.11
816.6469116	0.07
818.5700684	0.69
819.4697876	0.12
837.3621216	100.00
838.0131226	0.51
839.6928101	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2079
Annotation	6-O-Oleuropeoylsucrose
Peak:m/z	Relative Intensity
148.8998413	0.09
167.0219727	0.07
191.1536255	0.19
233.0943909	0.11
270.3035278	0.07
277.2877197	0.19
293.0981750	2.33
294.3046875	0.04
297.1802368	0.30
308.4091492	0.14
310.8872681	0.14
313.1615601	0.13
314.7304382	0.15
324.2919922	0.06
327.3807373	0.04
329.1213989	0.25
341.0971680	0.19
342.0771484	0.05
345.4035645	0.12
347.2934570	0.03
349.3259888	0.08
357.1663818	0.06
361.1069336	0.07
362.4619141	0.12
364.3725281	0.10
374.4758911	0.08
381.1630554	0.08
385.3411865	0.05
390.3364258	0.06
391.5500183	0.06
405.2359924	0.05
411.3019409	0.50
415.8915710	0.04
417.1745300	0.05
431.6132812	0.06
433.4906921	0.03
434.6389771	0.23
439.2793274	0.06
459.0148926	0.03
461.3327332	100.00
463.4440002	0.22
471.3899231	0.15
486.0443726	0.02
488.2920837	1.68
489.2985535	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.267
Annotation	2',7-Dihydroxy-4'-methoxy-8-prenylflavan 2',7-diglucoside
Peak:m/z	Relative Intensity
193.1629944	0.08
209.3702698	0.09
229.2133179	0.17
241.0688934	0.36
242.0263824	0.07
256.1645508	0.09
257.0608521	0.32
266.2508545	0.23
281.2296143	0.75
293.5500488	0.07
295.1959229	0.10
301.2709961	0.10
305.1387939	0.12
312.3143921	0.23
315.1365356	0.03
325.1641235	0.62
327.2314453	0.20
328.5063782	0.36
329.3432312	0.14
331.2017822	0.10
335.0641479	0.40
336.1571045	0.34
337.5010986	0.45
344.0014038	0.13
344.9351196	0.39
370.4514771	0.04
375.3442993	0.07
390.4004517	0.04
402.0375977	0.04
406.4309082	0.21
407.5148315	0.31
416.5615234	0.04
418.6699829	0.08
425.1992188	0.09
426.3834229	0.09
429.4818726	0.14
432.9892578	0.17
434.2447510	2.41
434.9642944	0.13
435.6972656	0.14
444.3297729	0.22
447.3035278	0.43
448.9353027	0.08
450.3095703	0.75
456.2563477	0.11
457.1654663	0.09
460.2212524	0.21
462.3323975	100.00
477.1886597	0.12
478.2769165	0.20
479.6334839	0.07
487.8397217	1.05
488.5077515	0.39
489.4670410	0.11
490.4386597	0.16
505.5589600	1.04
506.1629028	6.81
507.0609741	0.07
514.1913452	0.03
518.7263794	0.12
539.6038208	0.17
541.6160889	0.31
542.4985962	0.18
544.3430786	0.05
557.5172119	0.11
559.2655640	2.24
565.2228394	0.08
573.5189819	0.08
583.5808716	0.26
584.4616089	0.56
591.5128784	0.22
599.1616821	0.35
601.5520630	1.28
613.8059692	0.12
615.6382446	0.06
617.3100586	0.09
618.5643921	1.79
619.2301636	7.36
634.7133179	0.26
642.3287964	0.69
644.4078979	1.27
645.2730103	0.98
646.0396118	0.18
663.1097412	1.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8963089	4.55
115.9523010	1.42
130.9108429	0.24
131.9622192	0.03
158.9244995	100.00
159.9657135	34.68
173.9125061	0.03
198.9442139	1.44
199.9500427	1.73
201.8787842	0.07
205.8356628	0.08
216.9250793	0.50
218.0758057	0.86
219.0131531	0.03
219.7421570	0.04
228.9277649	18.41
229.9388733	18.41
243.7470703	0.03
245.0009766	0.28
246.0786743	0.44
254.9608459	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.1819
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
125.0175247	0.04
131.0134430	0.34
131.9183502	0.05
143.1374817	0.02
145.1653137	0.01
148.9943542	1.00
150.1459198	0.05
151.8904419	0.02
153.0218506	0.08
161.0136719	0.35
162.2575989	0.02
167.0816956	0.08
172.1766968	0.10
178.9851685	0.28
181.1716614	0.07
191.1855774	0.40
195.2855072	0.02
207.1181030	0.13
214.0480194	0.01
215.0919952	0.02
220.3582611	0.16
220.9769440	0.30
225.2210083	0.40
233.0628357	0.01
238.4505005	0.04
239.1735535	0.13
243.2685242	0.32
251.1273499	0.24
260.5665588	0.31
261.3168335	0.10
262.0780640	0.05
263.4811707	0.09
281.1307373	0.13
290.7084351	0.03
293.1898193	0.11
294.3392334	0.03
302.8827515	0.09
307.2904053	0.08
310.9721680	0.77
312.2506104	0.06
320.3125305	0.02
334.1704407	0.05
344.1511841	0.02
345.1378174	0.04
346.5621338	0.02
348.0974731	0.06
352.0945435	0.09
365.3500061	0.01
366.2396545	0.07
367.2310486	0.03
368.3754578	0.04
373.5045166	0.04
375.8632507	0.01
377.5193787	0.06
379.3548889	0.09
380.4062195	0.03
393.2085876	100.00
394.2367859	9.29
395.1094666	0.03
396.0054626	0.12
397.1476440	0.02
404.2427673	0.18
407.1224060	0.01
419.2974548	0.01
422.1550903	2.40
423.2124329	0.15
430.9869690	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.1772
Annotation	Unknow
Peak:m/z	Relative Intensity
146.1319733	0.11
160.9841919	0.05
174.1527405	0.06
178.9136047	0.04
197.0899658	0.02
202.0989075	0.02
208.4300232	0.02
218.1083374	0.03
239.3859100	0.02
246.0649719	0.03
263.1163635	0.04
265.1860046	0.03
281.2111206	0.15
289.9933167	0.47
306.2247314	0.02
308.2581787	0.93
319.5038147	0.01
335.2062378	0.04
344.3513184	0.01
347.4399719	0.12
362.2875061	6.59
364.2597046	0.02
366.1551208	0.03
380.2363892	100.00
380.8454285	0.39
383.4834900	0.03
389.2707214	0.07
396.2867432	0.02
398.1934509	0.09
403.3940125	0.04
405.2606812	0.07
410.3002625	0.46
411.3767700	0.16
428.3095093	8.16
438.1020203	0.15
439.3668518	0.02
446.2289734	0.03
452.9915466	0.17
454.1216431	0.24
456.3384094	0.13
457.6005859	0.07
462.2439270	0.04
463.6235657	0.04
464.3323669	0.16
470.6892700	0.10
479.1514282	0.02
482.2568665	3.41
482.9342957	0.02
501.4930115	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.41
Annotation	Mezzettiaside 2
Peak:m/z	Relative Intensity
538.4595337	0.08
553.5534668	0.11
564.5243530	0.05
576.2435913	0.16
597.4906616	0.17
632.4701538	0.22
676.6252441	0.19
746.5179443	0.18
788.7395630	0.33
790.9349976	0.06
814.4681396	0.19
833.6196899	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	258.86
Annotation	Unknow
Peak:m/z	Relative Intensity
83.8032150	0.19
96.0699921	0.37
106.9730530	0.06
110.0797729	0.27
147.1230774	0.15
169.9803314	0.11
170.7919312	0.05
175.0309753	0.11
187.2826233	0.22
196.1211700	0.23
197.3046112	0.14
203.0740662	0.11
212.8037109	100.00
215.1081390	0.16
231.1717529	0.15
241.1303253	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.23
Annotation	Unknow
Peak:m/z	Relative Intensity
161.9287415	0.35
169.0941467	0.06
170.8937683	0.06
172.9280090	0.07
175.3790436	0.02
177.0859375	0.11
179.0489655	1.25
180.1482391	0.16
188.0053711	0.08
188.9674683	0.14
191.0273132	0.03
195.0515900	0.53
197.2226105	0.04
203.0334167	0.18
207.1865234	0.24
212.1852722	0.09
213.0797729	0.23
215.2164307	0.05
217.1054382	0.17
218.1884155	0.11
219.2619629	0.02
224.9881744	0.04
225.7805634	0.05
227.1323547	0.02
233.1251984	0.03
235.1656036	0.27
236.1313477	0.10
238.1976929	0.17
244.2467041	0.11
245.1700592	0.19
252.2830658	0.65
253.2833252	0.12
254.3245697	0.09
257.2205200	0.03
270.2124939	2.12
271.1610107	0.03
272.1629639	0.03
273.8491821	0.02
279.9266968	0.30
281.4275513	0.06
283.6306763	0.12
288.1559448	4.74
291.2094116	0.06
294.1072998	0.04
298.2132568	0.28
299.1820679	0.04
301.4384766	0.03
308.1791992	0.72
309.9219360	0.13
312.1928711	0.39
324.3248901	0.98
327.2105713	0.26
328.4132690	0.09
338.2235718	0.36
341.3250122	0.08
345.2058716	0.20
346.2969971	0.09
347.3274536	0.11
355.2178955	1.39
356.2205811	0.29
357.4756470	0.14
358.2653809	0.18
373.2444458	100.00
374.3577271	0.08
379.6522217	0.04
385.3080444	0.02
391.2772217	9.08
399.3688965	0.29
401.2835693	0.06
416.8658447	0.08
427.3434448	0.18
429.8311768	0.18
432.1923218	0.20
438.9423828	0.52
439.8944092	0.10
440.9971924	0.08
444.3852539	0.02
445.2985229	0.84
447.3223267	0.10
449.4156494	0.29
451.3961182	0.03
457.4360962	0.07
464.4351196	0.05
466.0695190	0.03
470.5325317	0.20
475.1107788	0.16
476.4329224	0.03
477.2343140	0.06
480.1147461	0.13
481.3356323	0.18
484.2114258	0.42
485.3633423	0.20
490.6520386	0.03
496.4501953	0.02
502.2927856	7.52
503.3779297	0.22
505.1665039	0.26
510.5314941	0.12
511.4069214	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.4
Annotation	Vincristine
Peak:m/z	Relative Intensity
366.3352661	0.18
467.6539307	0.54
496.6605835	0.29
510.378479	0.45
513.3796387	0.23
514.3539429	0.62
555.4517822	4.23
556.4900513	6.27
557.5459595	1.57
583.3271484	0.36
584.1930542	1.69
715.4961548	0.79
716.369873	0.74
717.260437	1.87
718.4418335	0.89
753.6010742	0.81
759.585144	0.96
760.4701538	1.80
761.1586914	1.59
777.8156128	3.13
778.6127319	6.12
779.3738403	4.31
780.8688354	0.35
787.5705566	0.36
804.78302	0.60
805.4683228	0.28
823.4121094	100.00
824.366333	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.18
Annotation	Indicine
Peak:m/z	Relative Intensity
109.7518539	0.06
119.9626160	6.06
137.9695740	0.12
145.1496582	0.10
148.9470520	0.29
152.8651428	0.32
153.8468628	0.25
166.0503845	100.00
167.1819305	0.06
170.4267273	0.39
173.1130676	0.04
180.9167175	0.17
185.1996918	0.21
189.0602264	0.25
190.7355347	0.17
199.9802551	0.06
228.0123596	2.08
229.0000305	0.27
230.1209412	0.10
239.9412842	0.20
243.1683960	0.12
246.7653809	0.16
255.1079407	0.37
256.8875122	0.62
258.6717224	0.05
264.1906738	0.30
270.0887451	0.34
273.2203064	0.17
276.2676392	0.34
278.5635986	0.52
279.6978760	0.07
281.4367676	0.74
282.1163940	1.33
283.2419434	1.48
291.2714233	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	304.96
Annotation	Unknow
Peak:m/z	Relative Intensity
89.0553360	0.12
141.0322876	0.05
143.0128174	0.04
164.9849548	0.09
184.9290619	0.07
189.2802277	0.04
211.1500549	0.08
221.2022400	0.14
223.1967163	0.03
224.9483032	0.07
235.1690674	0.17
240.9205322	0.11
242.9572754	0.20
245.2292480	0.03
256.3028564	0.05
258.8284302	1.69
261.2670593	0.17
263.8598938	100.00
268.0489502	0.04
275.0003967	0.34
276.8933105	0.16
279.3911438	0.08
280.7385864	1.20
281.6734314	5.03
283.9107056	0.70
287.0831299	0.54
292.0492249	0.31
292.6723022	1.76
294.8592529	0.07
295.6436157	0.11
298.3509827	0.07
301.2944031	0.06
305.0377808	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.0865
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1909485	0.08
188.9481354	0.05
218.9797363	0.10
230.7996368	0.16
248.0953827	0.46
249.0326691	4.60
249.9965973	0.27
250.9602966	0.07
267.1044922	0.21
290.8804932	0.06
292.2253418	0.44
297.0369873	0.33
298.0776978	0.55
306.1248169	0.04
307.1504517	0.16
309.1571045	0.28
310.2259521	0.34
321.0841064	0.28
325.0599060	0.13
326.3806763	0.15
328.9735718	0.08
342.1461182	0.14
345.2023315	0.06
345.9963989	0.57
347.0725098	0.46
353.4201050	0.49
354.1252441	0.14
355.0426025	0.05
408.6667480	0.90
409.3152466	2.83
424.9851074	0.12
426.1538696	3.53
427.2326050	30.65
435.5114136	0.22
443.1372070	2.02
444.0763550	15.77
445.1376953	100.00
445.7640381	0.28
446.4357300	0.52
464.3316040	0.09
485.2654419	0.11
495.2347412	0.10
503.2290039	0.12
519.8639526	0.07
525.3917847	0.09
541.4055176	0.06
542.2041626	0.28
543.2274780	0.27
558.5117798	0.07
571.0388184	0.06
604.1546021	0.07
605.0248413	0.07
623.2843018	0.65
641.0318604	1.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9679184	1.19
120.9683685	0.10
122.9703369	2.07
151.9846497	5.21
167.0219116	100.00
208.9218140	0.42
233.1613464	0.02
237.2550964	0.08
239.1389160	0.04
251.3089600	0.11
253.1824951	0.09
271.0086975	0.13
283.1724854	0.41
284.2299500	0.33
285.2644653	0.19
293.3532410	0.08
309.2550659	0.22
311.1061401	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	835.36
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1697845	0.17
259.0777588	0.33
268.2567749	0.40
269.3477173	0.13
277.3208618	0.56
308.1955261	0.23
363.1611328	0.66
413.0543213	1.18
434.3126831	0.15
462.2807007	0.41
523.1444702	0.15
567.6157837	0.22
754.0119019	1.04
756.7500610	1.34
762.0693359	0.21
764.6027222	5.30
768.0564575	0.25
776.0548706	0.41
783.4765625	1.21
784.6466675	0.09
786.4712524	0.64
787.9664917	3.95
789.1336670	0.80
791.6635132	19.03
793.5725098	1.49
794.6506958	0.71
796.0622559	3.01
797.1797485	7.06
798.5041504	0.63
799.5831909	1.38
800.2828979	4.19
800.9306030	0.71
802.2810669	5.89
803.5652466	3.54
805.6390991	13.05
806.5857544	1.14
807.8832397	1.21
809.0560303	21.36
810.9410400	26.94
811.7253418	0.73
812.4197388	0.80
813.1375122	0.37
814.6439209	9.26
816.0823364	3.92
817.8793945	4.17
819.4474487	8.48
820.3260498	1.19
821.4087524	2.83
822.0739136	0.65
824.1065674	0.63
824.7499390	0.36
825.4397583	1.60
829.9177246	0.13
835.9962158	0.07
845.4892578	1.30
853.7276611	0.34
867.5548706	1.98
878.6333618	0.76
891.9674072	0.39
893.6734009	1.88
895.0850830	0.81
897.6611938	2.00
903.1779785	0.25
904.2714233	0.53
905.3449707	0.39
908.5305176	0.27
913.7579956	1.58
916.0714722	0.80
920.3755493	0.67
927.2374878	1.74
927.9656372	1.25
929.1923218	4.18
930.3291016	1.12
931.9635620	3.23
932.6315308	1.89
933.6203613	0.73
936.5388794	15.22
937.2313843	2.02
938.2854614	1.04
941.2302246	5.83
942.1494751	1.42
943.5134277	4.33
944.5227051	3.48
946.3468628	0.91
946.9717407	1.72
948.4406128	1.36
949.6170044	5.12
951.1140137	2.97
951.8760376	0.54
953.6311646	4.15
954.6028442	5.86
955.6377563	6.49
956.4779663	9.24
957.1358032	3.38
958.5776367	3.13
959.8236694	4.33
960.9861450	7.45
962.1539917	3.94
963.4233398	1.96
964.4917603	5.22
965.3925171	22.52
966.3816528	3.26
967.7925415	2.40
968.8641968	2.93
970.1766968	2.07
970.9536743	2.91
971.7434082	2.62
973.1418457	6.93
974.5066528	1.75
975.7228394	2.47
976.8078003	2.95
977.7177124	4.90
978.3373413	4.30
979.2407837	1.53
980.4252319	13.07
981.2620239	1.19
981.9806519	2.50
982.9409180	17.03
984.6938477	18.48
985.5017700	7.64
986.6482544	8.91
987.3015137	29.38
987.9880371	0.67
989.2448730	48.33
990.3427734	1.49
991.7600708	61.89
992.9915161	2.88
993.8403320	1.77
995.7556763	24.28
996.4003906	64.77
997.1664429	2.04
997.8320312	0.30
998.7333984	1.98
999.3428345	1.45
1000.4223630	1.17
1001.6902470	4.80
1002.4853520	3.51
1004.3718260	2.87
1005.5131230	1.59
1006.1736450	2.83
1006.8840940	5.73
1007.5493160	1.77
1008.9528200	10.24
1009.9013060	8.78
1011.0784300	14.04
1011.9905400	0.19
1013.4649050	28.39
1014.4832150	1.80
1015.3239140	7.72
1015.9451290	2.74
1018.0122070	100.00
1019.5519410	8.21
1020.1604610	25.99
1021.1030880	1.99
1022.3352660	18.34
1023.0202030	0.82
1023.7467650	1.39
1028.1274410	0.15
1034.2205810	0.64
1038.9621580	0.16
1040.3128660	0.88
1056.6525880	0.72
1076.4277340	0.42
1088.7758790	0.81
1090.8504640	0.75
1095.0147710	0.42
1099.5179440	2.24
1100.7949220	0.32
1109.1763920	0.26
1111.1484380	1.38
1116.1367190	0.95
1117.9764400	0.43
1119.3137210	1.29
1123.4294430	0.80
1129.7414550	1.13
1130.5683590	0.15
1137.5909420	0.98
1138.3872070	0.79
1147.7148440	1.13
1151.7177730	0.33
1159.8997800	0.69
1161.8858640	0.25
1162.7524410	0.86
1166.2116700	1.43
1169.3972170	2.60
1172.2226560	0.12
1173.1865230	0.25
1173.9246830	0.63
1177.8347170	0.81
1183.2041020	2.96
1184.9050290	3.11
1188.8228760	1.28
1189.4753420	0.48
1190.4746090	1.17
1192.6579590	1.06
1194.2104490	0.86
1194.8272710	0.40
1196.0098880	1.65
1197.0297850	1.20
1197.7032470	0.31
1203.4345700	2.67
1204.1063230	2.27
1204.7414550	0.24
1209.2655030	0.61
1211.7839360	0.86
1212.7659910	1.56
1213.4980470	0.91
1214.5207520	0.75
1215.2274170	1.73
1218.3861080	0.84
1221.8599850	0.95
1222.5566410	1.50
1223.4655760	0.76
1225.8703610	1.75
1226.4797360	1.67
1227.3281250	0.49
1229.0156250	1.03
1229.9495850	3.39
1230.9997560	2.21
1232.7216800	2.57
1233.3439940	2.13
1234.1716310	0.42
1235.4028320	2.14
1236.0891110	2.37
1237.0334470	1.45
1238.5694580	3.06
1239.5507810	0.77
1240.3963620	1.95
1241.5097660	0.90
1242.9105220	3.05
1243.7973630	3.42
1244.6265870	1.05
1245.7757570	2.76
1246.5488280	2.68
1248.5843510	9.12
1249.2396240	5.19
1251.8033450	12.78
1252.8187260	3.39
1253.6210940	1.52
1257.6470950	38.70
1258.3602290	47.60
1260.2932130	3.43
1261.6590580	7.20
1262.2762450	0.23
1263.6064450	4.75
1264.4571530	2.37
1265.3806150	0.34
1266.0892330	4.28
1267.6137700	12.17
1268.6370850	4.11
1269.5550540	2.71
1270.4500730	1.92
1271.6141360	4.50
1272.2257080	1.28
1273.1965330	1.94
1274.0032960	4.23
1274.9233400	4.33
1275.6248780	4.41
1276.6075440	2.55
1277.4396970	2.23
1278.7084960	0.46
1279.5587160	2.23
1281.0045170	30.13
1282.1129150	1.56
1284.9302980	2.54
1286.9256590	71.47
1287.7955320	1.65
1289.5159910	2.15
1290.1590580	2.90
1293.0723880	5.09
1294.3895260	0.96
1295.7342530	13.16
1298.7188720	0.88
1301.9339600	1.12
1302.5725100	2.16
1303.1799320	2.21
1304.1691890	2.15
1305.1007080	2.01
1308.4942630	1.92
1310.0942380	2.65
1312.3691410	3.75
1313.1844480	1.57
1315.7286380	1.08
1318.9036870	5.61
1320.2199710	1.09
1322.1397710	3.52
1324.5976560	11.78
1325.3387450	2.47
1326.4620360	0.46
1327.8814700	5.84
1330.8345950	1.14
1334.5065920	0.94
1346.4752200	0.41
1347.6164550	1.04
1397.0052490	1.47
1411.4493410	0.17
1422.9931640	0.33
1425.9643550	0.59
1427.4815670	0.84
1428.9777830	0.27
1429.8179930	0.13
1431.7397460	0.11
1492.7095950	0.45
1499.9084470	0.43
1500.9263920	0.73
1505.3248290	0.38
1521.4007570	0.99
1539.5147710	0.26
1554.2963870	0.55
1622.5144040	0.36
1643.5379640	1.03
1647.5740970	0.50
1648.6307370	0.36
1660.8391110	0.18
1667.6905520	0.48
1668.7608640	0.12
1676.0797120	2.44
1685.6170650	0.85
1702.8039550	0.10
1709.4655760	0.84
1730.4431150	0.71
1737.8148190	0.81
1748.2268070	0.20
1752.0411380	2.91
1766.0338130	0.37
1770.0369870	0.99
1774.9305420	0.70
1796.0611570	0.61
1797.1007080	0.39
1800.6590580	0.36
1804.3835450	0.22
1807.0599370	0.36
1810.8592530	0.27
1817.9382320	0.28
1856.3841550	0.49
1857.4344480	1.35
1870.2393800	0.44
1910.9359130	14.08
1923.7146000	0.34
1942.0866700	5.53
1945.5709230	0.54
1965.6960450	5.82
1966.4605710	0.85
1979.5684810	2.52
1981.4416500	0.12
1996.0858150	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.17
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9979858	2.28
177.0037842	0.70
195.0907898	100.00
196.0834961	0.28
251.1767273	0.19
323.1727295	0.30
325.2518921	0.16
329.1354980	0.36
339.3258667	0.46
340.6365967	0.19
341.3096313	2.10
356.9187012	0.11
362.2086182	0.12
375.4848633	0.28
408.1585083	0.06
439.1760254	16.13
493.3771362	0.10
501.5301514	0.08
519.0665894	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.2029
Annotation	Cellulose triacetate
Peak:m/z	Relative Intensity
161.0137024	0.09
166.8931732	0.04
191.1004791	0.12
249.4298401	0.05
250.1040344	0.19
259.0250854	0.12
266.1355591	0.18
284.8604736	0.12
289.0834351	0.08
293.1519775	0.68
305.1100464	0.07
306.0838623	0.07
317.0885620	0.15
323.2681885	0.23
329.2084961	1.85
336.2088013	0.13
338.2126465	0.29
340.8233032	0.28
355.1115112	0.29
357.2733765	0.08
358.4955444	0.66
359.2915649	1.44
380.1319580	0.06
389.3931885	0.18
402.8274536	0.14
411.7315063	0.06
415.4804688	0.10
428.8943481	0.18
439.1370850	0.08
442.0367432	0.61
445.1068726	0.12
447.7611084	0.19
449.3770142	0.16
461.0404053	0.17
475.3438110	0.17
476.9566650	0.14
487.6090698	0.09
489.2633057	100.00
490.8317261	0.27
491.4443359	0.33
497.3410034	0.25
498.6630859	0.55
501.3630981	0.36
516.8139038	1.25
517.4605103	0.07
537.3362427	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.3964
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
775.2540894	2.13
821.3947754	100.00
822.1018066	3.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.39
Annotation	Stevioside
Peak:m/z	Relative Intensity
715.2800293	3.48
759.1129761	3.67
803.4037476	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.17
Annotation	Trans-Zeatin-9-glucoside
Peak:m/z	Relative Intensity
108.9967346	0.21
131.1276703	0.37
132.666748	0.15
141.9590454	0.14
159.0041199	0.43
160.0317078	1.59
168.9825134	0.88
170.3165741	0.50
171.106781	0.24
183.7324371	0.59
193.2182007	0.43
199.3659821	1.40
201.0323792	0.51
202.1694489	4.53
213.0606995	20.65
213.8891907	1.26
216.2505341	0.59
218.9200745	1.25
220.1204529	100.00
225.2268677	0.34
238.0220947	0.69
243.2668762	0.18
246.3894043	0.38
249.0991211	1.06
251.1155701	0.89
255.7926025	1.08
262.0331726	0.14
266.4598999	1.09
269.2786865	0.13
275.9521484	0.92
277.2288513	0.19
283.9915771	0.86
285.0933533	0.74
286.027832	0.95
292.0029297	2.14
303.3769226	0.50
306.0396729	0.68
307.461792	0.94
308.428772	2.83
310.2808228	1.26
311.3843994	0.23
320.2486572	0.85
322.0650635	0.62
323.2524414	0.57
326.8492432	2.74
336.3669434	4.59
337.0649719	0.42
338.2442627	3.13
340.7510071	1.30
341.3681335	0.47
346.4806213	1.79
347.3801575	0.24
348.1126099	0.90
353.6573486	1.20
361.14328	1.03
362.0552063	0.13
363.3798523	0.78
364.2127686	3.33
365.3098755	0.79
367.1307068	1.93
367.9143982	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1089.7523
Annotation	Unknow
Peak:m/z	Relative Intensity
853.1324463	0.45
866.5625000	0.14
923.5456543	0.10
957.1329346	0.63
998.8530273	0.54
1002.8063960	0.06
1020.1738280	0.55
1025.6418460	0.22
1026.9959720	0.43
1031.2722170	0.48
1040.2778320	1.13
1048.3638920	0.36
1049.9285890	0.80
1058.9843750	0.86
1062.8686520	0.33
1063.7087400	0.41
1066.3065190	0.96
1070.0260010	0.13
1072.6259770	0.46
1090.3159180	100.00
1091.1839600	2.51
1091.8829350	0.76
1093.6088870	0.85
1094.5559080	0.36
1096.4653320	0.73
1097.6472170	0.55
1184.9252930	0.46
1222.7199710	0.31
1248.8375240	0.04
1278.1970210	0.65
1298.0964360	0.19
1360.1585690	0.89
1361.1480710	0.32
1363.3541260	0.70
1366.2579350	0.26
1375.7318120	0.10
1378.8161620	0.59
1396.8670650	0.79
1420.8916020	0.26
1435.3452150	0.50
1439.5363770	0.39
1440.4023440	0.45
1448.0831300	1.14
1455.8609620	0.16
1458.9954830	0.25
1482.8299560	0.29
1486.4400630	0.16
1504.2075200	0.30
1505.0297850	0.52
1514.7421880	0.23
1515.7689210	0.43
1527.0043950	0.51
1534.4202880	0.42
1560.4351810	0.64
1577.8012700	0.52
1589.5635990	0.33
1612.3590090	2.20
1663.3143310	0.07
1749.5681150	0.05
1759.9440920	0.12
1778.8747560	0.27
1811.6580810	2.23
1825.5905760	35.74
1848.0618900	0.35
1852.1516110	0.21
1868.9729000	0.06
1892.6802980	3.97
1895.9857180	7.86
1913.8366700	2.66
1948.3629150	6.57
1976.2658690	24.16
1983.8928220	0.13
1995.0548100	2.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	184.07
Annotation	4-Amino-2-hydroxylamino-6-nitrotoluene
Peak:m/z	Relative Intensity
55.7451935	0.36
59.8497925	15.61
60.5162239	0.13
70.8482056	2.63
85.8727035	100.00
98.8688812	0.03
104.0312653	1.53
124.9345398	25.41
166.0753326	3.40
184.1079865	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3926
Annotation	Isonuatigenin 3-[rhamnosyl-(1->2)-glucoside]
Peak:m/z	Relative Intensity
202.2230530	0.16
203.3381348	0.52
205.1575317	0.44
207.9150085	0.63
215.0118256	0.41
220.2928009	0.30
221.3482666	0.28
224.8353271	0.36
231.0500488	0.61
233.0348816	0.63
239.1477203	0.23
241.3623199	1.75
255.3573914	0.88
263.3796387	0.33
265.2500610	0.90
277.2515564	1.24
283.1491394	0.13
294.9523621	0.38
301.2487793	0.61
307.5448608	0.40
309.0831299	0.25
319.3583069	0.29
327.5652771	0.79
335.0089111	0.17
335.6362915	0.14
337.4388733	1.85
343.0956421	0.64
355.5100098	0.40
369.0298462	0.45
371.0663452	0.99
381.1846924	0.71
391.3700562	4.99
395.3491211	0.43
399.5571899	0.34
401.4409790	1.91
407.1785889	1.40
409.3450928	1.01
413.0018921	0.55
419.4595947	7.28
421.5142822	0.11
426.2270508	0.54
429.5196533	0.36
435.3685913	1.01
437.3464355	4.36
447.1060181	0.76
452.4451294	2.49
470.3198853	4.77
472.1226196	0.29
496.3912964	1.51
498.3715210	0.43
505.2825317	1.12
507.7778931	1.28
509.6150513	0.49
528.5432129	2.02
537.6575317	0.21
546.2192383	1.64
581.3168335	0.88
584.8391724	0.73
609.3819580	3.12
625.5899048	3.65
629.3554688	0.17
639.7660522	0.43
641.6627808	1.37
649.3356323	1.03
653.3432007	100.00
653.9527588	4.74
654.6239014	1.25
657.6753540	0.36
667.1343994	5.65
667.8469849	0.50
685.3872070	0.24
686.4448853	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.1449
Annotation	Unknow
Peak:m/z	Relative Intensity
84.0257111	0.12
100.9498978	0.11
122.8225555	0.23
129.9419708	11.84
147.0131073	100.00
147.9376831	0.40
159.0721893	0.14
164.0013428	0.09
177.3657837	0.17
179.0854797	0.06
198.9931030	0.10
203.0585632	0.19
207.0838318	0.64
216.2494202	0.06
221.0603027	0.25
222.2760010	0.08
224.0862427	0.13
228.3648376	0.19
231.0771790	0.17
233.3254089	0.13
234.8044739	0.15
237.0752258	0.60
246.9689331	0.30
248.0770264	0.76
249.1289978	1.31
250.9592285	0.36
257.0290222	0.90
260.9854431	0.25
262.2482910	0.48
263.0202637	2.38
266.6516113	0.05
274.1794434	0.37
275.0931396	2.95
276.1194458	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	452.5321
Annotation	Unknow
Peak:m/z	Relative Intensity
129.9203949	0.68
143.0117035	0.26
144.8702698	0.92
154.7447052	0.05
163.0669403	0.16
169.0785217	0.08
186.9999695	0.10
189.0537109	2.21
193.1178284	0.13
205.1706696	0.29
207.2782593	0.17
211.1497192	0.09
215.1088562	0.61
216.0115356	0.26
231.1140289	0.20
232.9932709	0.57
249.1145935	0.44
253.0007324	0.10
257.0783386	1.33
258.3927002	0.17
261.0182190	0.14
268.8382874	0.05
272.8326416	0.05
274.1891785	0.23
283.0916748	0.10
285.2169800	0.39
287.2158813	0.29
288.1163025	0.18
289.1774292	0.07
290.1733398	0.25
293.2391052	0.29
296.4796753	0.06
301.2549438	0.44
304.7348328	3.75
305.5068359	0.03
307.3300781	0.34
310.1430359	0.05
312.7300720	0.31
321.7976685	2.86
323.9541321	0.03
326.1113281	0.10
330.9582520	0.68
334.2399292	0.13
343.1844482	0.03
345.1370239	0.23
348.6842651	0.12
349.8646545	3.80
351.2704468	0.11
354.3643799	0.09
356.2441406	0.07
358.0418091	0.23
362.0729370	1.58
363.2218018	0.62
364.0411987	0.30
366.0513306	0.10
372.7140198	0.05
373.7928162	0.12
377.2536926	0.17
379.4238892	0.17
380.7721252	0.08
384.8671875	0.39
385.8122559	0.37
388.9914551	0.45
391.1417236	0.10
391.8948669	0.36
392.8538513	1.85
394.3033447	0.11
398.7086487	100.00
399.7845764	1.06
400.6371765	0.43
402.5746155	0.07
403.7673950	2.62
404.4455261	0.06
407.9455261	5.09
409.2946777	1.70
410.0332947	0.33
416.3125916	0.04
420.4720764	0.35
423.0704956	0.06
424.5346069	0.09
426.7099609	0.08
428.0051270	0.15
428.8557739	0.20
434.4651184	1.11
435.2698669	0.96
436.0736389	0.15
440.2251892	0.73
457.2569885	0.45
458.3110046	0.52
459.3002014	0.53
460.0375061	0.66
463.6055603	0.21
468.2128601	0.07
469.4510803	0.05
479.7448120	0.17
481.1553040	0.20
486.1845398	0.12
487.0598755	0.29
488.7075806	0.87
489.5510559	0.29
495.5035095	0.11
497.4293518	0.17
513.0706787	0.11
515.6428833	0.86
516.6709595	0.12
523.8004150	2.06
524.4822388	1.99
531.4077148	0.43
532.9395752	11.81
533.8682251	1.04
534.7572021	0.18
540.5266113	0.23
541.6885376	0.50
547.1350708	0.32
552.4781494	0.76
553.3294067	0.10
554.3976440	0.34
560.0888062	0.08
565.5787964	0.21
571.9363403	0.13
579.2738647	0.62
585.4204712	0.54
586.3814087	0.95
587.2778931	0.48
588.3012695	3.63
589.0002441	3.16
592.5785522	0.22
597.5584106	51.18
598.5113525	6.17
599.4891968	0.18
600.3650513	0.05
601.4976196	0.11
602.5896606	0.37
614.4838867	0.07
626.4534912	0.16
652.8844604	0.29
660.5695801	0.10
667.6560669	0.77
668.5696411	0.69
703.6987305	0.20
721.4333496	0.05
724.4414673	0.39
736.3917847	0.06
745.6575317	0.12
778.4249268	0.33
779.7384644	0.11
796.5185547	1.59
798.8867188	0.24
803.3746948	0.12
814.3427734	0.31
829.7963257	0.18
832.3480835	0.05
842.6935425	0.11
850.6192017	0.11
853.7976074	0.30
854.9370117	0.31
868.7377930	0.12
869.3471069	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1193
Annotation	Griselinoside
Peak:m/z	Relative Intensity
125.0509491	0.32
127.8780746	0.04
130.9043579	0.14
132.0397949	0.22
135.1018372	0.32
136.9038849	100.00
137.9877472	7.90
142.9258728	0.62
148.9739380	0.55
150.8983154	1.55
151.8621826	0.47
159.0758514	0.24
159.8950500	0.30
160.9457092	1.27
161.7340698	0.20
163.0795898	0.10
176.7650452	0.33
178.9781799	8.72
180.0504150	1.35
181.1560974	0.04
189.9654541	0.15
191.0384369	2.71
192.1044617	0.15
193.0781250	0.12
203.0032043	0.36
207.2172852	0.09
208.2177734	0.15
209.0953979	0.66
221.1623230	0.42
226.8854828	0.06
231.8251190	0.08
239.0364685	0.33
250.9227600	0.57
255.0587769	0.46
256.0697021	0.03
258.2496033	0.12
262.2484741	0.31
263.0253906	0.07
269.0102539	0.70
273.4116211	0.18
275.1157227	0.12
281.1065979	2.75
282.1792603	0.11
283.2281494	0.25
286.0909424	0.13
293.2033386	5.21
294.2677612	0.37
299.2189331	18.02
300.2034912	1.89
306.1508789	0.39
307.9698486	0.24
309.2806396	0.19
311.0548401	2.80
312.2524414	0.29
318.2708435	0.16
329.0777588	0.66
338.0523987	0.17
341.1540527	0.17
356.0629272	0.06
364.6416931	0.58
371.5806580	0.17
385.3683167	0.31
386.3683167	0.39
387.2541199	1.66
388.3327942	0.48
395.5021973	0.04
399.3343201	0.27
411.0201416	0.22
413.2218323	0.74
414.0842896	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	534.2122
Annotation	Neoharringtonine
Peak:m/z	Relative Intensity
159.8947449	0.65
166.0491943	0.10
167.0439148	0.11
168.1157837	0.06
171.1701355	0.27
176.9640198	1.39
179.0591583	3.67
180.0337219	0.32
185.1108856	0.06
193.1898499	0.28
210.1687317	0.58
211.0050964	0.63
213.1427917	0.20
221.1501312	0.10
225.1384125	0.25
226.1404724	0.07
229.1183929	0.10
232.2552948	0.06
237.1538391	0.12
242.2169800	0.37
244.3710327	0.06
254.2125092	8.20
255.0920105	2.78
272.1030884	9.80
273.2042236	2.59
277.3113403	0.14
279.1379395	0.06
288.1513672	5.20
289.2182312	2.16
306.0959473	100.00
307.2009277	23.44
309.3861694	0.19
332.3865967	0.25
362.2305908	0.17
373.3834839	0.31
377.4741821	0.24
383.3046875	0.05
385.0058594	0.16
387.2543335	0.15
389.3106079	0.07
405.6774292	0.25
406.4102173	0.42
408.3764038	0.23
420.3255005	0.08
420.9729614	0.51
431.2921143	0.10
438.3279419	0.38
441.3540039	0.43
445.6169434	0.14
454.4262695	0.15
471.4857178	0.45
472.2271729	1.09
473.3390503	1.09
481.3867798	0.29
483.6953735	0.71
488.4110107	0.17
489.3217163	0.33
490.4645386	0.85
491.4071655	0.61
493.2893677	0.09
499.1925659	0.06
516.2401733	1.86
517.4508057	1.37
535.1028442	0.15
536.3037109	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2658
Annotation	Unknow
Peak:m/z	Relative Intensity
250.0017548	0.15
262.0516357	2.14
262.8117065	0.56
263.8872681	0.04
268.8663330	0.08
286.8483276	0.15
353.1203003	100.00
354.2633667	26.35
381.0712891	0.06
397.1663208	0.10
419.0908203	0.15
481.1383667	0.17
493.5642700	0.18
503.0838623	0.13
506.3913574	0.20
518.1478271	91.70
519.1439819	14.31
525.3815308	0.10
532.4455566	0.30
533.7178345	0.04
536.3159790	0.14
538.3733521	0.15
592.3652954	0.14
600.1058960	0.38
606.3036499	0.07
621.3131104	0.11
637.2531738	0.43
638.2066040	0.17
648.5575562	0.12
666.2296753	0.19
684.0932617	28.63
684.8593140	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3403
Annotation	Unknow
Peak:m/z	Relative Intensity
146.8465118	0.44
148.9041748	0.07
151.5855713	0.22
153.1057892	0.40
154.9666901	0.81
155.9980927	0.28
157.1698761	0.23
158.1822968	0.29
159.1062927	1.39
161.0679932	1.16
163.0845184	0.98
165.0017242	0.42
169.1098328	0.85
171.1302490	0.65
173.1907654	1.93
175.1130676	0.48
181.0885468	0.34
182.9044189	0.27
185.0598145	2.98
186.9887085	1.18
189.1199646	2.37
193.3242340	0.35
194.2131195	0.20
195.2615356	0.66
197.1576080	0.26
199.0581818	1.51
201.1265717	2.47
203.2315674	2.00
205.2346497	0.43
209.0773926	0.30
210.9391632	0.57
213.2376556	2.94
215.0874329	4.44
217.2268219	3.50
219.2939453	0.14
221.3558044	0.08
223.2672119	0.49
225.2261200	1.35
227.2292480	1.25
229.0236359	2.21
231.2273407	0.29
233.1859741	0.16
235.1892090	0.63
236.3295898	0.11
237.1061401	0.81
239.2983246	1.89
241.2707520	3.29
243.2288513	0.44
245.3259430	0.58
247.3224487	0.48
249.1775055	0.35
251.2516327	0.35
253.2656555	2.22
255.1727448	1.72
257.2899475	0.75
259.1841736	1.65
265.2423096	0.99
266.2221680	0.20
267.2835999	2.66
269.2958984	1.57
273.1834106	1.36
275.1507874	0.48
277.1959839	0.89
279.2142944	3.06
281.5571594	0.99
283.2852173	2.08
284.7247925	0.27
287.1694336	0.39
289.4056396	0.62
291.2800598	0.38
293.4663086	0.44
295.2377930	6.14
299.3283691	0.46
303.0698853	0.51
305.0318604	1.23
307.3957520	1.07
309.3720703	0.94
311.4222412	0.47
313.2601929	0.74
313.9382935	0.15
315.2890015	0.35
316.9151001	0.23
319.2744751	1.87
321.1162720	2.08
323.2949219	0.42
325.3341064	0.90
327.2786865	1.21
328.9983521	1.02
331.1931763	0.87
333.4288330	1.24
335.3115845	3.36
337.3416748	1.27
339.2691650	0.27
343.3260498	0.92
345.3991089	2.30
347.2496948	0.63
349.4574585	0.65
353.1380615	0.35
355.4671021	0.33
356.9968262	0.98
359.4560547	1.19
361.4232788	4.45
363.4462280	2.74
367.6451416	0.26
369.5452881	0.39
371.4035645	0.58
375.4004517	1.04
376.4218140	0.32
377.5664673	0.63
379.1580811	0.15
381.4249268	2.16
383.2219238	0.50
385.2941284	0.90
389.4013672	0.50
391.3764038	45.78
392.0028076	0.07
393.4490356	0.57
395.3428955	0.27
399.1782837	0.09
401.4252930	8.96
409.4038696	0.07
411.2551880	0.94
413.4111938	0.85
415.3629761	0.53
419.4702759	39.23
423.3868408	1.16
437.4700317	41.33
438.4111328	0.13
439.1820679	0.36
441.3007812	0.85
445.6956787	0.13
449.4421387	0.17
451.5634766	0.40
453.6291504	0.17
461.3725586	0.15
467.3894653	3.20
474.4822388	0.07
477.4070435	0.33
479.3718872	3.72
480.2534790	0.11
481.3076782	0.33
487.5657349	0.66
493.3273315	0.35
495.3080444	100.00
496.0101318	0.50
505.4939575	10.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.44
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
337.2986145	9.14
673.6731567	2.08
716.1599731	2.52
794.8529053	7.66
922.9345703	2.34
966.3510132	1.96
967.4430542	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.386
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
303.3087463	3.79
686.1984253	6.01
759.2454834	7.55
803.3834839	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1036
Annotation	Mollugoside
Peak:m/z	Relative Intensity
119.1138763	0.19
120.9297562	0.37
122.0315552	1.28
123.0275726	3.44
124.1387482	0.21
129.0247650	0.14
130.2060394	0.10
130.9601898	0.24
131.8753967	0.13
132.9911499	3.21
134.0811310	1.31
135.0568848	2.20
135.9030914	0.97
137.0133057	0.41
138.0773926	0.09
139.2783356	0.06
143.1105957	0.25
145.0594025	0.35
146.1111755	0.21
147.0097656	0.48
148.0870667	0.17
148.9868774	0.62
151.0293579	21.36
151.9214478	50.32
152.9751892	11.84
154.0760498	0.59
157.1079102	0.06
157.8520813	0.03
159.0347748	0.19
159.8362579	0.23
161.0906372	1.20
161.9445190	0.27
163.0021057	20.62
164.0733032	1.55
164.9610138	1.00
166.0467987	0.04
173.6933594	0.07
175.0221252	5.02
176.1177979	0.54
176.9913635	9.20
177.8696289	0.55
179.0150604	17.19
180.1042480	1.39
181.0296173	1.09
182.1566620	0.11
182.9304810	0.15
185.2113037	0.10
187.1462708	0.84
188.1416321	0.23
189.0101624	0.38
189.9704895	0.20
190.8328094	0.19
192.0317078	0.03
193.1107788	3.07
194.1238098	0.24
195.0747223	0.82
196.9040222	0.03
201.1109161	0.11
203.1780396	0.02
205.0254517	2.11
205.9704895	0.39
207.1076202	6.21
208.0583191	0.61
208.9826660	0.13
213.0654449	0.06
219.0444946	6.78
220.1436310	0.44
221.1136322	0.08
223.1404114	5.49
224.0920715	0.63
225.1148682	2.74
226.1752014	0.36
231.1083984	0.55
232.2993469	0.17
237.1486206	1.42
238.0288086	0.12
239.2232666	0.13
241.0727234	100.00
242.0508423	9.68
248.8991089	0.37
252.1811829	0.04
263.2845154	0.10
267.1731873	9.81
268.1248779	0.70
275.0071106	0.03
278.1904907	0.08
281.1098633	0.10
285.0946350	40.20
286.2143250	4.78
300.3690796	0.07
304.1041565	0.23
313.4159851	0.08
316.1560364	0.03
318.8459473	0.17
321.1415100	0.20
325.1044006	0.05
327.1293945	0.72
329.1812134	0.03
343.1782837	0.02
371.4295044	0.12
372.1738892	0.18
373.1928406	2.84
374.2182922	0.56
381.3300781	0.23
382.0354004	0.51
387.3910217	0.03
397.0943604	0.13
399.2124939	8.92
400.2457581	2.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	955.4916
Annotation	Tuberoside A (Ullucus tuberosus)
Peak:m/z	Relative Intensity
466.5106812	0.04
806.4845581	0.17
824.5983276	0.53
865.4364624	0.13
866.5089722	1.39
868.0625610	0.01
908.4990234	0.06
909.6063843	0.02
910.5178223	0.20
922.7681885	0.12
954.3279419	8.95
955.5139771	100.00
956.2611694	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	158.98
Annotation	Unknow
Peak:m/z	Relative Intensity
58.6629524	0.25
70.9736252	0.14
84.9024811	0.07
86.9880829	0.13
96.9289093	0.12
98.8034973	0.04
100.8448181	0.05
110.8530273	0.08
114.8390656	100.00
129.0000458	0.33
130.8266602	7.22
140.8958893	0.17
158.9760742	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.6654968	0.19
211.1749268	0.05
212.7639465	3.16
214.8145905	0.60
232.5108948	0.27
290.6691284	0.48
293.1402588	0.21
296.2956543	0.55
296.9316406	3.63
378.8587036	0.09
380.8183594	28.81
402.4714966	0.34
416.9393921	0.33
419.8585205	0.36
437.1099243	0.25
439.0678711	0.44
439.9213257	0.08
456.2122192	0.25
458.2033081	1.56
461.0206299	0.27
462.6520386	0.15
464.1466675	10.54
464.7537842	63.55
470.1109009	0.17
502.8028564	0.05
542.4355469	0.16
545.3122559	0.55
546.1399536	0.44
547.8082275	6.33
548.5979614	100.00
549.2675171	0.56
581.8070679	0.09
586.2245483	0.33
586.9213257	0.44
590.3046875	0.28
611.9022217	0.29
615.4205933	0.09
633.7314453	0.54
634.7124634	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.1853
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1584778	0.06
155.9069977	0.01
157.3506775	0.02
158.0624847	0.04
160.9903259	0.09
172.8207703	0.03
175.2180328	0.11
184.9113159	0.03
203.0982361	0.06
205.0492859	0.02
207.0884705	1.46
212.1598358	0.05
215.1885376	0.08
226.1233826	0.02
239.1266785	0.06
253.3796387	0.08
261.1154480	0.07
271.0439148	0.10
272.1794739	0.06
282.2559814	0.05
284.2125244	0.03
285.2223816	0.05
287.2441101	0.04
289.9210205	0.05
295.2088318	0.07
295.9616089	0.08
301.3909912	0.03
302.2662964	0.06
303.2712708	0.02
305.2702637	0.41
309.4899902	0.11
310.5021362	0.06
311.2116089	0.05
315.1432800	0.04
323.1245117	10.50
324.1350708	0.16
327.0914307	0.03
328.2862244	0.14
330.1978455	0.12
333.0993652	0.06
337.4616699	0.14
338.7458496	0.15
341.1463013	100.00
343.4662476	0.07
348.3085327	0.04
356.4267578	0.02
359.3293457	0.02
372.0834961	0.15
387.1414795	0.10
388.7098999	0.09
405.3647766	0.18
416.2503967	0.06
422.3988647	0.12
429.3746033	0.02
433.9218750	0.03
435.2183533	0.03
438.9627380	0.01
441.2702942	0.05
447.0449219	0.02
456.3772278	0.01
458.2940979	0.06
464.4368591	0.07
465.5923462	0.14
466.2569275	0.05
467.1611633	0.05
468.4034119	0.06
482.1412964	0.11
483.3168640	0.03
484.4216919	0.20
485.1925354	0.55
486.8882141	0.05
494.2551575	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	732.3029
Annotation	Unknow
Peak:m/z	Relative Intensity
231.1936951	0.49
271.0194702	0.47
273.8814392	0.14
288.3141174	0.07
321.4699707	0.46
322.5142212	0.43
359.4406128	0.81
368.3742065	1.87
387.4804077	0.68
395.6174927	0.15
403.9037476	0.05
407.7180786	0.06
416.2718506	1.13
417.3251953	0.78
422.3049927	0.28
423.6049194	0.85
424.8723145	0.45
427.3932495	0.52
432.9711304	12.41
433.7551270	0.05
435.0366821	0.26
441.3716431	5.35
445.9891968	1.04
451.1835938	0.25
453.6281128	1.24
454.3535156	0.76
462.3114014	1.32
468.5709229	1.63
469.2543335	0.13
469.9744263	0.20
472.3039551	0.14
474.3234863	0.14
477.5258789	0.75
478.5330811	0.34
480.4681396	0.12
487.9508667	0.63
488.7438965	0.79
489.5407715	0.64
496.8869629	0.76
498.0130005	1.11
500.1878052	0.15
501.2642822	0.46
502.0171509	0.74
505.9548340	42.35
506.7593384	0.14
508.4719849	0.15
513.7624512	0.06
520.3314209	0.12
522.3882446	1.54
523.7116089	0.72
524.4969482	0.20
526.6638184	1.00
527.2975464	1.22
529.9514771	0.27
532.7914429	5.65
533.4429321	0.28
535.0985718	1.10
536.0781860	0.12
538.7642212	0.35
544.8757935	0.42
546.9100952	0.34
551.5265503	0.07
556.1570435	0.20
557.9490967	0.95
558.5520630	0.48
561.1482544	2.45
561.8475952	0.22
570.2988281	47.92
570.9702148	19.09
577.7683105	1.60
585.4895020	0.37
586.9812622	35.37
587.7745361	0.63
588.5242310	0.08
591.2300415	0.86
591.8798218	0.28
595.2026978	0.17
603.7328491	0.23
608.1195068	0.18
609.8169556	1.17
614.1486206	3.71
615.1667480	0.07
618.4023438	0.29
623.0966187	0.36
624.9363403	0.62
628.6442871	0.27
634.0498657	0.37
642.3911743	1.80
643.0678101	0.60
646.7520142	1.19
651.5442505	100.00
652.6139526	1.06
655.2307739	0.37
656.3550415	0.15
668.1234741	11.48
670.3330688	0.31
672.5454102	2.55
673.6581421	0.23
681.5195923	0.28
687.2387085	0.19
690.2831421	1.13
691.1207886	0.18
694.8258667	0.42
696.3103638	0.55
700.4976807	0.58
702.5666504	1.58
703.8344116	0.13
704.5238037	0.25
705.6516724	0.46
706.7572021	0.72
714.5781250	0.39
715.6417847	0.42
717.7429199	0.89
719.4151001	0.22
733.6797485	0.40
735.3930054	0.26
736.4368896	0.21
742.5370483	0.33
772.6394653	0.23
795.2216187	0.20
806.2789917	0.28
807.5457153	0.17
808.5961914	0.86
815.7558594	1.20
821.3787842	0.64
834.7180786	0.55
843.0957642	0.30
846.2911987	0.62
867.6516724	0.14
881.6926270	2.91
882.6289062	1.87
910.5604858	1.03
935.5365601	0.23
936.8012695	0.07
943.6022339	1.11
947.5005493	0.18
952.2544556	0.36
973.9489746	0.19
993.6511230	0.73
996.8574829	0.98
997.9551392	0.13
1000.7162480	0.14
1010.6843870	5.17
1011.7225950	3.19
1012.9767460	0.33
1044.4785160	0.19
1076.5473630	0.53
1120.5733640	0.10
1121.8065190	0.87
1122.7373050	0.07
1139.5717770	5.12
1140.7326660	3.56
1161.3937990	0.13
1172.4799800	0.32
1226.2312010	0.15
1244.6755370	0.08
1258.8872070	0.05
1262.7249760	0.32
1266.1766360	0.27
1283.2370610	0.15
1301.7938230	1.91
1302.8178710	1.00
1424.9790040	0.18
1446.4781490	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.18
Annotation	Indicine
Peak:m/z	Relative Intensity
102.9237518	0.15
109.1674652	0.37
120.0217361	4.71
124.9102859	1.56
136.1346741	0.18
137.8966217	0.12
141.1137085	0.45
156.0007935	0.96
161.8934784	0.15
165.9319763	100.00
169.1383057	0.28
176.2543030	0.20
177.2494812	0.18
200.9315796	0.16
203.0667419	0.87
208.1307373	0.21
211.0719910	0.34
213.1929016	0.11
219.3332520	0.25
223.1585388	0.59
227.9734802	1.89
228.9765625	1.53
246.9000244	2.70
253.0209961	0.68
254.3078003	0.22
255.1737061	3.43
256.7954712	0.71
258.9231262	2.77
264.3341675	1.60
264.9860840	0.44
269.2353821	0.17
271.9116821	0.12
273.1562500	0.48
276.7582092	0.13
278.8861084	0.59
280.3690796	0.35
282.2130127	6.01
283.1900024	3.05
284.5951538	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	464.2397
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9417114	0.04
150.0247650	0.32
151.3019409	0.04
162.9592896	0.10
165.9990082	0.59
176.7135315	0.07
183.9678040	100.00
185.1193542	0.05
190.9430847	0.16
192.9755249	0.04
201.1488495	0.05
207.2576599	0.42
213.2271271	0.09
231.1792908	0.30
233.1689301	0.08
239.2236328	0.12
240.3787537	0.17
241.2460327	0.10
247.0932007	0.06
248.9971619	0.10
255.3068237	0.20
257.5540466	0.05
258.3847961	0.06
259.0485840	0.14
275.3899231	0.22
281.1421509	0.25
283.2358093	0.50
299.0549927	0.04
301.2669678	0.10
302.4920654	0.24
305.3838196	0.12
307.1216125	0.26
309.3973083	0.08
312.3785400	0.03
315.2352600	0.10
325.2384949	0.13
327.3867493	0.29
328.3886108	0.07
347.0139771	0.44
355.3445435	0.05
356.9086914	0.20
357.9754333	0.37
360.3006592	0.31
365.5998535	0.24
376.1014709	0.09
381.4312134	0.13
383.0840454	0.22
387.3106384	0.08
392.9871521	0.15
403.2814636	0.11
404.8088684	0.17
410.2592468	0.50
417.7372131	0.07
419.4067383	0.08
429.0320740	0.16
432.3827820	0.06
433.6051331	0.25
436.7054443	0.14
443.3952332	0.03
444.4586487	0.17
446.2888489	46.58
447.0345154	0.37
455.0939636	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1036
Annotation	Cellobionate
Peak:m/z	Relative Intensity
100.8531342	1.63
111.0951920	0.53
112.9432068	14.78
113.9824905	1.00
115.0385971	1.89
115.9799805	0.24
118.9752502	11.29
119.9827118	0.59
121.1258774	0.54
122.9405823	13.37
124.0018387	1.44
125.0332336	2.29
126.0035706	0.38
127.0470505	0.12
128.9740448	1.16
130.8822479	6.84
132.2815094	0.14
134.1603699	0.15
138.9895325	1.11
140.9578552	32.79
141.9258270	4.62
142.9957275	12.33
144.0191040	1.46
148.9496307	2.47
150.6867676	1.56
155.2425385	0.38
158.9053192	8.79
160.3206177	0.72
161.0358887	25.89
161.9395294	0.94
163.0257568	0.85
164.8858185	0.93
174.1835327	0.42
177.0675201	8.61
177.8828430	0.98
178.9256134	39.32
179.8360138	3.03
182.8780518	1.50
188.0768890	0.23
195.1215820	1.68
196.0420685	0.76
197.2666779	0.28
200.7223358	0.12
210.6346130	0.18
213.0794067	0.95
219.1530457	0.24
221.0816650	8.96
222.0502625	0.35
225.0403748	0.71
232.8802185	0.44
235.0480347	4.00
236.3611450	0.42
237.0285645	1.37
238.2513123	0.44
243.0979309	0.32
248.6744690	0.17
250.4432983	0.21
251.0876770	0.28
259.2782593	0.72
259.9683838	3.80
261.1561584	2.55
267.2256775	0.36
268.0249634	1.07
268.9750977	0.19
285.0067749	0.40
285.9299622	0.85
291.2138367	6.56
292.3756714	0.69
297.0761719	0.22
303.1559448	26.00
304.1102295	7.95
309.0404968	1.48
310.1277466	0.15
313.8274536	0.25
321.1068115	53.65
322.1693420	7.27
339.1400757	100.00
340.2380371	15.03
340.8937378	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.95
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9573059	0.10
132.0320587	0.07
137.0610352	0.30
154.0680084	11.39
155.3987732	0.12
173.0389404	0.44
173.7866821	0.29
192.0424194	0.91
193.0586548	0.22
193.9980164	0.18
230.1184692	0.04
236.0484924	0.08
237.9980774	13.93
254.0280457	0.05
273.0720215	0.06
275.9751587	20.59
282.0629272	0.04
321.3409424	0.91
321.9975281	5.91
359.8321838	100.00
364.3316956	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.16
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0694122	0.06
140.3007202	0.26
144.0729065	0.20
149.0668335	0.21
151.0241089	2.59
162.0196075	1.17
165.8653259	0.06
166.8582611	0.18
172.8235626	0.19
175.0943146	0.10
176.0932007	0.31
179.0283508	10.37
180.2750549	0.35
197.0158844	0.14
201.2978668	0.12
216.8566437	0.19
225.3793182	0.09
229.2136383	0.63
231.3057861	0.28
233.0278931	1.44
242.3196716	0.08
245.3474121	0.27
247.3191528	0.09
250.2443542	0.11
253.2096558	0.64
259.4328613	0.29
270.1145020	0.45
271.1483765	0.09
272.3265076	0.56
275.3461609	0.16
276.3220215	0.08
277.2919922	0.22
283.3277893	0.21
284.4688416	0.42
287.2125854	0.19
290.0232544	0.52
294.2476196	0.31
295.1816406	0.20
298.3830566	0.10
306.9792786	0.17
308.0884399	100.00
308.6990967	0.64
311.2756042	1.69
313.2622681	0.13
324.3021240	0.09
325.0787354	0.09
328.9737244	9.03
337.8143311	0.48
342.8298950	0.29
345.2889709	0.22
351.5771484	0.27
353.3989868	0.23
355.3091736	1.05
357.6310425	0.16
362.4508972	0.57
365.0198364	0.14
375.8388672	0.16
378.1242676	0.05
383.1664124	1.68
391.3027344	0.17
393.6327209	0.50
396.3858337	0.16
399.4953613	0.08
400.3077698	1.04
403.7712708	0.32
405.7500305	0.88
407.7209778	0.62
410.3160095	0.27
411.5490723	0.70
412.4560242	0.58
417.2238770	0.24
420.6539612	0.16
422.1886902	0.08
423.6687317	0.41
425.3899231	0.69
426.2843933	0.33
429.5736389	0.19
431.4201965	0.45
437.0101624	0.70
439.0114441	0.48
440.1898499	1.48
441.2575684	1.33
442.2340698	0.25
443.6079102	0.23
448.3294373	0.58
449.8254395	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.3755
Annotation	Quadranoside V
Peak:m/z	Relative Intensity
419.5148315	0.33
421.4380493	1.72
439.4516602	1.94
440.4768677	0.74
453.5537109	0.24
481.4515991	0.53
495.5858154	0.13
517.3427734	3.00
518.4015503	1.01
523.6516724	0.29
545.7074585	0.30
546.6786499	0.21
573.4317017	6.68
574.5928955	2.89
575.6688843	0.04
581.6199951	0.94
583.5137939	9.25
584.4518433	2.80
591.4542236	0.11
599.6283569	0.36
601.4591064	100.00
602.4568481	28.47
603.2639771	0.24
613.6028442	0.28
619.5097046	7.91
620.4576416	1.64
630.5053101	0.25
635.6725464	0.22
645.7526245	0.10
646.4756470	0.18
664.4570312	9.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.4546
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
556.0892334	0.01
606.0305786	0.01
615.7905273	0.00
633.6927490	0.00
749.9879150	0.02
750.9635620	0.03
751.7097778	0.00
756.8479614	0.00
762.9328003	0.01
769.1351929	0.01
777.8587646	0.03
779.0154419	0.01
795.5606079	100.00
796.5654907	0.15
797.5330200	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	526.1929
Annotation	Unknow
Peak:m/z	Relative Intensity
152.0607605	0.07
152.9272003	0.22
154.2458191	0.01
162.9087067	0.20
167.2957001	0.01
171.1182098	0.02
186.2582550	0.02
195.3308411	0.01
205.2540741	0.03
214.1885071	0.03
218.0274353	0.07
231.0145569	0.03
267.0543213	0.04
269.1072388	0.02
271.9963074	0.02
274.1589966	0.03
278.8818970	0.06
281.2582397	0.01
289.9614868	0.03
301.4268188	0.03
302.0925293	0.05
306.0389404	0.03
308.2978516	0.58
320.2352905	0.03
321.2489624	0.02
328.3001709	0.06
329.7219849	0.04
334.2109375	0.15
336.1831055	0.11
362.2192993	2.99
364.2084961	0.10
372.0007935	0.03
380.2562256	100.00
404.5524292	0.03
409.4318237	0.08
411.1111450	0.05
427.4586792	0.02
428.7016602	0.03
436.3331909	0.13
438.0053711	0.02
439.2706299	0.05
449.2312012	0.02
450.5571289	0.07
451.3239746	0.44
452.2843628	0.11
454.2454834	1.17
455.1988525	0.04
460.9457397	0.06
463.4749146	0.08
464.4470825	0.03
465.3375854	0.04
466.2438354	0.02
472.1163940	0.09
479.0337524	0.21
480.3858032	0.02
481.2336426	0.08
482.3229370	0.39
487.2382202	0.03
489.3753052	0.07
490.1748657	0.11
498.3610229	0.06
502.1930542	0.02
505.4974365	0.03
506.3796997	0.02
507.4673462	0.06
508.2606812	1.13
509.1757202	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	925.3355
Annotation	Unknow
Peak:m/z	Relative Intensity
355.0106506	0.03
400.4980469	0.08
418.3096313	0.04
444.1798096	0.07
476.1562500	0.27
497.3857422	0.05
527.0062256	0.07
541.2992554	0.48
557.1520996	0.11
567.2778931	0.06
573.2835693	0.56
583.3562012	0.26
585.1715088	0.11
599.5025635	0.05
601.4269409	2.01
609.6350098	0.05
615.3952637	1.10
617.2563477	1.37
627.4767456	0.61
633.4315796	2.59
643.7435913	0.08
645.3074341	0.67
646.0391846	0.04
657.2552490	0.13
659.4142456	0.32
677.3609009	3.81
680.1741333	0.10
687.5015259	0.12
692.1691284	0.10
693.1521606	0.17
724.3345947	0.12
725.2803345	0.05
747.4510498	0.02
748.2490845	0.04
749.5356445	0.03
789.3774414	4.09
790.0058594	0.03
803.1084595	0.02
803.7454224	0.17
805.5393677	0.03
807.5587158	0.11
821.3640747	15.59
822.0172729	0.20
831.4544067	1.29
833.5916138	0.03
839.4310303	0.62
849.3827515	28.34
850.0964966	0.07
853.5828247	0.02
863.3504028	4.19
864.0173950	0.06
881.3560181	59.27
882.0991211	0.06
885.3826294	0.03
893.0344849	0.04
902.6149292	0.11
905.4629517	0.07
907.5535278	0.16
925.1614380	100.00
926.3283081	1.31
926.9686279	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	173.13
Annotation	3-Aminocaproic acid
Peak:m/z	Relative Intensity
68.7450104	0.06
72.8454895	0.11
76.7129135	0.04
78.8731842	0.10
80.7823410	0.09
82.7843170	0.21
84.9765549	0.14
85.9550934	0.31
86.9626923	0.03
93.1316528	0.07
94.8557587	0.17
97.1269226	0.27
98.7427216	0.15
100.9928589	0.07
104.8676147	0.03
106.9276123	0.07
108.8338623	0.11
111.0112000	0.03
111.9441071	0.05
112.9906921	0.13
114.0019989	0.17
115.2025452	0.03
120.0826721	0.07
126.9746399	1.30
127.9360352	0.22
129.0193634	0.75
129.9617462	0.18
131.8542023	100.00
133.1901703	0.03
136.9224701	0.04
140.9794769	0.13
142.8852997	0.02
145.0799866	1.45
149.8631439	3.83
151.8378143	0.63
152.4459534	0.53
154.9053955	6.72
156.0510712	0.10
156.9343414	0.17
161.1906891	0.19
164.0058899	0.71
173.1728668	0.05
182.0339813	0.06
183.8993988	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.2102
Annotation	Astin I
Peak:m/z	Relative Intensity
162.0963135	0.34
163.1990356	0.04
171.0472412	0.02
173.1832275	0.04
176.9183197	0.15
178.9767761	0.04
179.9393921	0.05
191.1633606	0.04
209.1417236	0.19
213.0659180	0.03
223.0164795	0.60
225.0714111	0.03
230.4688110	0.02
232.9603729	0.31
240.1366730	0.07
241.0745087	0.72
243.6564331	0.08
248.2720642	0.04
249.2311249	0.08
257.1410522	0.10
258.2919006	0.03
266.1680908	2.01
267.0985718	0.18
274.2652588	0.05
278.0403748	0.14
284.1117554	5.20
294.0028076	1.23
302.1831055	2.08
308.0142822	0.32
312.2656250	0.90
313.2760010	0.03
318.4413452	0.03
320.1578979	0.14
323.0963745	0.55
325.2259521	0.07
330.2967529	0.08
332.4167480	0.07
335.3000488	0.09
338.2807007	0.44
341.2356567	1.63
350.3088379	0.05
351.6414795	0.11
352.2650146	1.17
353.3097534	0.14
369.2554932	4.98
370.3126221	0.58
371.9799805	0.09
372.8916016	0.07
377.1826782	0.07
378.3246460	0.06
387.2092285	100.00
387.8430176	0.37
395.5895386	0.07
397.4319458	0.04
405.1914062	1.21
409.1436157	0.05
423.1632080	0.45
423.8537598	0.07
435.6064453	0.30
440.2895508	0.02
441.2637329	0.39
441.9347534	0.02
453.3118286	0.53
455.0395508	0.02
459.2677002	1.01
461.4353027	0.13
463.0042114	0.04
464.4082031	0.04
471.3165894	0.21
480.2603149	0.46
488.0830078	0.09
498.3419800	0.38
499.3992920	0.03
502.5062866	0.17
516.3208618	9.02
517.2324829	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0965
Annotation	Ethotoin
Peak:m/z	Relative Intensity
86.8100052	0.01
97.2375031	0.00
107.7238312	0.01
109.0283966	0.01
132.0428314	0.10
134.8540497	0.02
145.1347504	0.07
159.1405182	0.22
161.1027985	0.02
162.0322723	0.02
162.9883728	0.01
163.7544403	0.01
169.0354309	0.05
178.3941498	0.02
179.0839539	0.05
181.7065277	0.01
187.9978180	100.00
189.0022430	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3876
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
393.8270874	5.78
394.8007202	3.18
676.6420288	2.65
742.7885132	8.36
803.374939	100.00
804.1139526	8.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	481.2288
Annotation	Unknow
Peak:m/z	Relative Intensity
140.0624542	0.08
144.7701569	0.26
148.5275879	0.03
152.8645630	0.08
155.1081848	0.06
157.3330688	0.10
169.1760712	0.05
173.0950165	9.61
174.1196899	0.08
185.2677612	0.12
187.2116089	1.36
197.2736816	0.27
199.0401459	0.19
201.9736328	0.04
203.2471008	0.22
204.9750214	0.11
207.3509369	0.08
209.0764313	0.16
214.8956146	0.05
217.4279175	0.05
221.0670166	0.49
225.0584717	0.13
226.1400452	0.19
227.2625427	0.20
237.3634186	0.09
239.2736053	0.11
241.0777435	0.11
245.0673981	0.10
247.1262512	0.13
251.2107544	0.09
257.2904968	0.16
263.1813049	0.14
265.3339539	0.11
267.2475891	0.13
269.0226135	0.03
273.5550537	0.10
275.2460938	0.11
277.1035767	0.07
278.1820374	0.17
281.1541138	0.20
285.3110046	0.05
287.2088013	0.07
291.0865784	0.10
299.1939697	0.05
305.3987427	0.25
312.2423706	0.23
313.3226318	0.41
317.2824707	14.94
318.2711487	1.17
331.1516113	0.16
335.2619629	100.00
336.3318176	2.90
337.1068115	0.04
341.4570923	0.46
343.5296021	0.17
349.1954346	0.08
359.4139404	1.12
361.4068604	0.04
377.1397095	0.78
378.2611084	0.18
383.3138123	0.02
390.9833069	0.54
403.4468384	0.11
407.4403076	0.12
413.1072388	0.09
415.0801392	0.04
416.8501892	0.16
418.4045105	0.23
420.3173218	0.13
421.2829285	0.31
434.4060364	0.13
435.3685913	0.96
436.2985229	2.07
437.2434387	1.02
439.6225586	0.09
443.2210388	0.05
445.4265442	0.80
448.3599854	0.20
449.2037354	0.65
459.4103088	0.18
460.7574768	0.35
461.4563904	0.06
463.3928528	32.15
464.3677673	1.36
471.0420532	0.21
482.3472595	3.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	659.2281
Annotation	Sorocein B
Peak:m/z	Relative Intensity
216.0091858	2.89
232.9658356	0.18
261.2761841	0.20
282.3324280	0.19
285.3081360	0.21
316.0059509	0.22
326.9615479	0.37
329.2860107	0.67
335.0278931	0.41
377.8022461	1.29
378.4392700	3.99
385.4303589	0.16
388.4714966	0.87
401.2584839	0.22
407.3090210	0.31
460.6102295	0.41
461.5118408	0.09
491.3316650	0.84
508.2500610	0.24
519.1364746	0.23
522.3787231	0.24
526.3080444	0.12
528.0291138	0.15
530.6397095	0.14
532.1727905	0.11
546.3466797	100.00
556.4176636	1.10
588.6297607	0.38
615.6140137	0.60
618.3484497	0.28
622.3579712	0.56
623.0523071	0.16
628.1112671	1.06
631.1682739	0.31
639.7439575	0.70
641.3754883	4.31
642.1896973	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.377
Annotation	Methylanhydrovilangin
Peak:m/z	Relative Intensity
169.1536865	1.38
169.8939514	0.12
171.0892792	0.56
173.0487823	0.81
175.1549377	0.28
176.9030762	0.65
178.9537506	0.44
181.1436920	0.87
182.2823639	0.10
183.2024689	1.35
185.1828766	1.13
187.0533447	2.66
188.9568176	3.90
190.9801636	0.51
193.7555237	0.25
195.2042999	2.70
199.1349487	3.22
200.3577423	0.32
201.1159973	4.76
203.1538696	2.11
205.1735687	2.83
207.2308807	1.29
209.2355957	1.79
211.1597748	5.35
213.0731506	9.95
215.2088318	3.25
217.1051331	5.00
219.3157959	0.31
221.0905457	0.48
223.2246857	1.42
225.1955872	6.21
227.1937866	2.58
229.3301849	2.16
231.2243652	2.57
232.8070984	0.18
235.0643616	2.29
237.2467041	2.83
239.2178802	5.09
241.0674591	5.99
243.1118469	1.74
245.2562866	4.70
247.1693420	1.57
249.2530212	1.73
251.1693420	1.11
253.2002106	9.27
255.2198181	5.79
257.2953491	2.43
259.1724243	9.19
261.0809937	0.88
263.1752930	1.27
265.2583008	2.23
267.3017273	5.10
269.1635437	3.08
271.1767883	7.65
273.2086792	5.91
277.3139648	0.59
279.1523438	4.51
281.1303711	6.97
283.1786499	4.20
285.0704956	7.59
286.5534058	0.27
287.3457336	3.80
289.1636353	1.33
291.0552979	0.28
293.3738403	1.50
295.2052002	9.63
297.2546997	3.93
299.2510376	12.22
301.4058228	1.24
303.2210083	0.42
305.2778320	0.20
307.2357178	3.76
309.4198608	5.06
311.2998962	3.45
313.2593994	4.83
315.3512268	0.28
317.4740295	1.20
319.5937195	1.16
321.3318481	3.86
323.4161377	2.32
324.0168457	0.15
325.2201538	2.80
327.3306274	10.62
329.4420776	0.94
331.6306763	0.38
333.3798828	1.02
335.3120728	3.88
337.2424316	5.20
339.3878784	0.78
341.2440796	1.49
345.3892822	5.56
347.4732056	1.00
349.2313232	4.79
350.4390259	0.12
353.3330078	2.48
355.1301270	3.06
355.7402954	0.09
357.2587891	0.19
361.3693237	2.34
363.4224243	5.50
367.4042969	1.74
369.2415161	1.53
372.1700439	0.20
373.3851318	0.50
375.6334229	2.26
377.1916504	1.40
379.0756836	0.25
381.3078613	9.87
386.4277954	0.24
388.2006836	0.15
389.2298584	1.66
391.4661255	79.02
393.3919678	2.51
395.3692017	0.68
401.4216919	17.95
403.3171387	0.75
407.5565186	0.41
409.4235229	12.45
416.2963257	0.41
417.4815674	1.13
419.3416748	74.68
423.4983521	0.11
431.3463135	0.57
433.1986694	0.57
437.3740234	87.59
445.2774048	0.56
447.4620972	1.41
451.3044434	0.39
465.2208862	0.28
469.2109985	0.12
475.3154297	0.50
479.5972290	0.27
485.4110718	0.41
487.4908447	1.66
489.3117065	0.71
499.4537964	0.39
501.4407349	0.29
507.6830444	0.20
513.0267334	2.16
517.7028198	0.63
519.6591187	0.41
525.5239258	0.24
527.3707886	0.52
531.5064087	0.19
533.5253296	1.82
537.8088379	0.31
541.3635864	4.49
543.5996704	0.48
551.4031372	1.86
553.5305786	1.92
561.5036011	0.46
567.9151001	0.45
569.3674316	100.00
579.4143066	13.71
580.2720337	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.18
Annotation	Unknow
Peak:m/z	Relative Intensity
134.9411926	0.42
137.0409088	0.72
144.9040833	0.07
147.1458130	0.05
162.0404816	1.03
163.1491394	0.07
166.0104370	2.79
167.1979523	0.16
168.1485443	0.11
173.2230225	0.10
174.1015472	0.12
176.9409180	0.14
179.9686890	100.00
181.0425720	0.28
191.0527344	0.04
224.3458252	0.04
230.9652710	0.03
244.3341980	0.09
276.3671875	0.51
283.0787048	0.13
289.7005615	0.04
291.0717163	0.14
293.7149658	0.05
307.5275269	0.13
309.3146362	0.47
312.1521606	0.09
323.6023560	0.05
324.3211670	0.08
328.0995178	0.04
344.2655029	0.08
345.2218628	0.14
356.7029724	0.16
360.4060974	0.07
384.2184448	0.03
386.0005188	0.03
402.5096741	0.03
414.4981384	0.03
424.3108826	0.13
429.2298279	0.06
432.7919617	0.37
438.0817871	0.07
446.1482849	0.07
447.5105896	0.10
454.4486694	0.07
456.3324890	0.27
457.2835693	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.476
Annotation	Dioscin
Peak:m/z	Relative Intensity
343.209259	2.95
763.4324341	3.15
764.7141724	19.66
846.8595581	12.01
866.6624756	11.24
867.4768066	100.00
868.5375366	5.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.2113
Annotation	Cucurbitoside K
Peak:m/z	Relative Intensity
159.1306610	0.64
164.8766479	3.56
168.3924866	1.52
177.1455231	3.06
181.0976715	18.17
183.1071167	100.00
191.3668213	0.28
219.1277161	0.36
231.0534668	0.31
237.1150208	83.86
237.7256470	0.61
248.7070770	1.21
255.0995178	82.01
283.0458374	0.84
307.1253662	0.50
313.6385803	1.82
322.3468018	1.45
326.3882446	0.34
333.3146973	0.66
341.1696167	0.60
345.2416992	2.63
377.3011169	0.70
402.1867981	0.73
422.9574890	0.66
431.1568298	18.94
441.3980408	0.98
449.4496155	0.57
459.2649841	3.25
467.3490601	8.51
485.3111267	35.94
486.3598328	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.2272
Annotation	Unknow
Peak:m/z	Relative Intensity
203.4942627	0.03
209.9113159	0.11
260.2050171	0.23
285.0201721	0.08
302.0967712	0.07
306.1217041	0.20
322.1921997	0.26
334.1206055	0.10
352.9763184	0.05
354.2601318	0.17
361.0541992	0.04
364.2244263	0.09
383.1944580	0.03
394.3169556	0.06
404.3840332	0.40
405.0786133	0.08
421.2144165	0.06
427.3032227	0.21
431.3198242	5.71
449.2975464	0.20
450.0614014	0.57
451.2874756	100.00
452.0520630	0.09
477.5685425	0.09
493.4411011	0.11
496.4266968	0.46
503.6888428	0.09
526.3168945	0.22
532.4735718	0.12
538.4891357	0.10
539.7409668	0.11
549.5123291	0.04
552.5881958	0.03
566.6174927	0.45
567.3737183	0.16
593.3977661	0.06
608.1878052	0.33
610.3142700	0.17
611.3748169	0.10
625.7247314	0.04
635.2339478	1.29
636.2908325	0.04
637.5416870	0.08
655.2891235	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1086
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
130.8719788	0.05
136.1028137	0.05
137.0034485	4.96
138.0647430	0.42
147.4442596	0.03
150.9045715	0.19
152.0300293	0.94
153.0811462	0.08
159.2722168	0.04
161.2965698	0.04
162.7710114	0.02
166.9777679	5.90
168.0296631	0.45
174.0263672	0.01
179.0749207	0.39
180.0437012	0.01
180.9893494	0.03
185.2436523	0.11
189.1546631	0.09
190.9967957	0.43
192.0304413	0.06
203.1617432	0.05
207.0732117	0.42
209.0101013	0.27
210.1926117	0.03
221.0964508	0.61
222.1088257	0.05
224.6236877	0.04
225.2682037	0.07
235.0829163	0.12
237.0314331	0.03
239.1593323	0.35
240.1231995	0.06
242.0716553	0.09
253.1714478	0.04
263.2308044	0.04
264.0277405	0.02
265.6389465	0.11
269.2780762	0.02
281.0861206	100.00
282.2035522	10.29
297.1600952	1.33
298.2128296	0.44
311.2322998	0.95
312.1834106	0.08
336.1300049	0.01
353.1464844	0.08
361.2986450	0.02
376.1547852	0.07
403.2486877	0.09
405.0240784	0.56
406.4653320	0.12
412.4761353	0.07
413.9584961	0.22
431.3644104	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.1664
Annotation	Syringopicroside B
Peak:m/z	Relative Intensity
144.9889221	0.77
148.7907257	0.69
151.3218079	2.03
152.0453186	15.78
153.0122986	3.31
159.2252350	0.46
161.0622406	2.14
163.1645508	0.48
164.2639313	0.29
166.9833679	100.00
168.2190399	0.56
174.0407410	0.20
175.0927734	4.54
177.1055603	5.03
178.1396027	0.73
179.0359192	3.39
187.0168457	0.48
189.1697998	0.51
191.1529999	1.69
193.0601044	3.88
194.9870605	3.42
196.9899445	11.06
201.1296082	0.63
202.6935425	0.47
207.0041199	1.49
209.2486115	1.05
211.2056427	0.94
219.1921844	1.67
220.9743958	11.20
221.6460266	0.18
225.1187744	0.28
233.0680847	0.24
235.1625061	1.71
237.1124268	1.32
239.1348267	20.91
251.0494385	2.85
252.9847870	3.06
257.3477173	0.53
262.9035645	2.35
269.1902466	0.85
281.1670532	16.56
283.1667480	0.15
293.3033447	0.42
296.7741699	0.30
301.2435913	0.31
311.0512695	0.48
323.3058472	0.50
328.9739990	1.15
341.2171021	35.67
359.4420776	0.63
361.0270996	0.76
365.3807983	0.32
389.2426147	0.22
415.2396851	0.63
462.3698730	0.91
465.2760010	1.63
489.3650513	0.21
491.4442749	0.99
510.0567017	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9392
Annotation	Unknow
Peak:m/z	Relative Intensity
115.1323395	0.06
116.0400543	0.02
158.9739532	1.20
160.0494690	0.21
176.0125122	0.01
186.9333344	0.01
198.8652344	0.08
200.1314087	0.01
217.0713196	0.02
217.9188843	0.02
229.0961914	0.24
230.1429138	0.17
244.9871521	0.01
257.2706299	0.01
271.2628784	0.15
273.0062866	100.00
273.9659729	20.69
275.1423035	0.02
289.7761230	0.00
292.2114868	0.01
294.8892822	0.00
298.2593994	0.01
300.0165405	0.03
313.2008057	0.01
314.2994690	0.01
314.9074097	0.00
322.8146362	0.01
330.9512329	0.00
332.2493286	0.01
339.1716309	0.01
341.1148071	0.05
342.9402466	0.05
343.9145508	0.08
357.2035522	0.00
358.9796448	0.02
362.0834961	0.00
369.0246887	0.03
369.9703369	0.01
376.8793640	0.02
386.9192810	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.3931
Annotation	Unknow
Peak:m/z	Relative Intensity
168.9647675	0.32
171.1114807	0.66
171.8997803	0.21
173.1420898	2.30
175.0824585	0.85
177.1494598	0.46
179.1638641	0.09
180.9596100	0.32
183.2015381	2.50
185.0314484	3.91
186.9996948	2.72
188.5678101	0.28
189.2030334	1.55
190.9145203	2.03
193.1026306	0.15
196.1843719	0.17
197.2731628	1.33
199.0427704	1.72
201.0949402	3.38
203.0975494	2.95
205.0216675	1.04
206.8719177	0.33
209.0045776	0.36
211.1060486	2.43
213.1077118	2.64
215.1630249	5.56
217.0530243	3.02
217.6950073	0.05
219.2269287	1.48
220.9668884	0.19
223.0750275	0.82
225.1263428	1.72
227.2419128	2.86
228.6842651	0.47
229.2917175	2.44
231.2172241	0.68
233.2103271	0.57
235.0134888	0.27
237.1100922	1.17
239.2244263	3.73
241.1596832	3.11
243.3169098	2.14
245.0834656	1.94
247.1134033	0.41
249.3393707	0.16
251.1876831	1.63
253.2017975	1.61
254.7647095	0.28
255.3833008	2.55
256.1274719	0.21
257.2171021	0.58
261.1956482	0.31
263.1445312	0.10
265.2792358	1.19
265.9328613	0.24
267.2999878	4.73
269.1491699	2.44
271.4289551	0.60
272.8764648	0.49
275.3272705	0.13
277.3876343	0.17
279.0504456	0.75
281.2935486	3.32
283.3430786	2.71
284.5047913	0.28
285.3935547	0.35
287.2396240	1.80
291.3967285	1.09
293.1925659	1.88
295.3795776	5.45
297.1328125	0.80
299.3392334	2.84
300.2302246	0.29
303.1453857	0.15
304.0578308	0.61
305.3489990	0.87
307.2596436	2.07
309.2547302	7.36
311.3320923	1.15
313.2568359	1.58
315.2626343	0.21
319.3115234	0.20
321.2426758	2.26
323.5180359	1.52
324.8302917	0.78
327.3286743	3.84
331.6499634	0.61
333.5039673	0.50
335.3580933	9.67
337.2788696	6.60
339.2366943	0.24
341.3576660	0.73
343.1972656	0.77
345.1945801	1.89
347.2044678	0.38
349.4238281	1.31
351.3682251	0.90
353.3309326	1.74
355.3104248	2.65
357.2854004	0.06
359.4655151	0.63
361.4092407	0.41
363.3545532	3.86
365.0221558	0.15
369.3972778	0.14
371.5787354	0.17
375.2077637	0.46
376.0629272	0.36
377.2136230	0.70
379.2288818	0.88
381.3322754	25.12
382.4804688	0.32
387.3532104	0.37
389.4013672	10.64
391.3601685	100.00
392.1594849	0.22
393.4760742	9.21
394.9993896	0.31
395.7306519	0.22
397.5190430	0.28
399.5103760	0.29
401.4044189	4.99
402.5017700	0.38
403.5971069	0.48
404.4667969	0.13
405.3566284	0.22
407.4483643	5.61
409.3521118	25.62
411.5037231	0.26
413.6984863	0.42
417.4210205	0.62
419.3198853	31.84
420.3449097	0.75
425.3826904	0.09
429.3766479	0.66
431.4772949	0.16
433.1415405	0.18
435.3722534	2.27
436.2883301	0.68
437.3629761	35.06
439.3585815	0.61
447.3128662	0.16
448.6805420	0.16
449.6427612	0.60
455.3664551	1.08
457.1316528	0.48
459.5820923	0.42
460.4161377	0.37
461.4066162	0.07
463.4107056	0.10
471.4660034	0.72
475.2320557	1.53
478.0744019	0.06
479.1823120	0.25
483.2911377	0.23
485.5952148	0.21
487.5383911	0.25
489.2918701	0.41
491.2938232	0.16
494.3681030	0.24
497.0136108	0.14
497.6644287	0.41
499.3432007	0.57
506.3939819	1.03
507.2218628	0.59
510.3086548	0.09
513.5329590	0.12
515.4507446	1.43
516.9431763	0.43
517.6840820	0.69
525.4108276	1.75
527.4284058	0.58
535.3668823	2.55
536.5723267	0.14
539.4338989	0.14
543.3972778	6.27
545.5803833	1.60
553.4419556	7.14
555.2509155	0.19
563.2330322	5.84
563.8510132	0.14
570.6082153	1.88
571.4981079	6.51
581.3664551	43.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	612.32
Annotation	Oleficin
Peak:m/z	Relative Intensity
179.0910645	0.04
214.1284790	0.11
236.1315765	0.03
252.9985657	0.07
269.2852783	0.18
286.1621094	0.07
291.2586670	0.02
300.0281067	0.08
303.7825928	0.04
307.4099731	0.11
323.0017090	0.10
327.3134155	0.76
363.3763428	0.23
367.1750488	0.05
371.3696899	0.03
384.2490234	0.06
397.5814209	0.10
399.0000000	0.14
403.4655151	0.04
407.4716797	0.17
415.3336792	0.45
416.0430908	0.14
417.0437622	0.17
430.3580933	0.04
431.4794922	0.16
432.2947388	0.14
434.3652344	0.15
438.7032471	0.07
440.5996704	0.04
445.3730469	0.08
449.4296265	0.14
450.3872681	0.04
461.0970459	0.04
463.5662842	0.09
465.2390137	0.09
474.4586792	0.11
478.4742432	0.04
481.4244995	6.99
495.5537720	0.06
499.3457642	0.19
507.3052368	0.48
511.6729736	0.16
515.3324585	0.17
521.6794434	0.13
523.1381226	0.04
524.2834473	0.06
526.1054077	0.03
529.5943604	0.02
531.6129150	0.11
538.2864990	0.05
544.2598267	0.12
547.6223755	0.51
552.3947754	100.00
553.5202026	1.11
565.3864136	0.10
566.4655151	1.52
567.2348633	0.21
568.4658203	0.02
575.0545044	0.10
591.4944458	0.36
593.1940308	0.54
594.3880005	0.23
612.5487671	0.26
613.5767822	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	504.91
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9203339	5.59
159.8977051	2.00
161.0752869	3.25
161.9942932	0.79
199.2753296	0.07
199.9205933	0.47
201.0320129	0.22
217.1156464	0.20
218.2745209	0.26
221.2490845	0.06
228.6938477	0.84
230.0382385	0.20
231.0327148	0.87
233.0805054	0.21
247.7670288	0.30
272.9986267	28.18
274.0119324	40.31
274.9873962	86.26
275.9320984	31.48
277.0439758	13.07
318.7770081	0.17
346.0804138	0.36
385.9399719	0.07
387.9145203	44.06
388.9764099	99.08
389.9963684	100.00
390.9422302	56.82
391.5548096	0.20
414.1404419	0.21
420.0863647	0.20
430.2370911	0.16
431.1726990	0.17
458.2783508	3.73
459.1147156	2.01
460.0419617	1.65
476.7932434	1.00
487.0499878	6.90
504.9030457	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1663
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9829407	0.20
129.0011597	0.24
130.9937897	11.91
143.1212921	0.07
149.0637665	1.02
152.9642334	0.12
167.0725555	0.25
173.2071075	0.24
185.3680725	0.22
190.1368713	0.10
191.0227203	3.10
208.9825745	0.18
221.0170898	1.22
275.1986389	0.18
279.3083496	0.08
291.8353271	0.23
293.3534546	0.92
306.2732849	0.16
309.0210571	0.10
347.3182983	0.08
367.2348938	0.17
379.2061462	100.00
381.1630554	0.18
382.0111084	0.07
405.4293823	0.44
407.4062195	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	839.44
Annotation	Unknow
Peak:m/z	Relative Intensity
310.2855835	0.02
401.4871216	0.11
471.2340698	0.01
560.3535156	0.11
568.4140015	0.03
569.1994629	0.07
570.5808105	0.11
586.5231323	0.02
597.8209839	0.02
598.5535278	0.03
615.9342041	0.18
616.7963257	0.20
624.6084595	0.02
631.9249878	0.10
632.7095337	0.26
633.5630493	0.11
634.6088257	0.18
657.7645264	0.02
658.6822510	0.05
662.4007568	0.03
669.3329468	0.21
678.3805542	0.09
680.7905884	0.10
686.5515137	0.04
687.7263794	0.06
688.5536499	0.05
690.4429932	0.04
700.6979370	0.02
704.7702026	0.23
714.5711060	0.18
716.5220337	0.19
720.6594238	0.15
730.7482300	0.15
732.4641724	0.26
733.3837891	0.22
734.6226807	0.13
742.7050171	0.45
747.5615845	0.22
748.5966797	1.54
750.4013062	0.13
752.8381958	0.07
760.5093384	0.88
767.4663696	0.05
777.8018188	2.51
778.5917969	24.92
779.7012329	2.45
792.4480591	0.07
793.7151489	0.02
794.5039673	0.03
796.5496216	55.67
797.6448975	4.68
800.6569214	0.39
802.9139404	0.14
814.3709106	0.05
818.6973267	0.19
819.8527222	1.06
820.7550659	0.29
838.0034790	0.02
839.4945679	100.00
840.1886597	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391
Annotation	beta-D-3-[5-Deoxy-5-(dimethylarsinyl)ribofuranosyloxy]-2-hydroxy-1-propanesulfonic acid
Peak:m/z	Relative Intensity
111.0495911	0.10
128.9739075	1.78
146.8235474	0.02
149.0434570	0.04
158.9671021	2.45
177.0735168	0.43
192.9794312	0.07
194.9972076	100.00
196.0861359	0.07
197.1573486	0.14
248.9964600	0.06
283.0069580	0.05
292.7094116	0.35
293.3477783	0.10
329.2494812	0.03
373.2537842	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3401
Annotation	Antibiotic CI 940
Peak:m/z	Relative Intensity
147.0077972	0.37
152.1686096	0.41
153.1607361	0.08
154.6970520	0.44
155.2998505	0.30
157.0092163	0.99
159.0930481	1.21
161.0761719	0.61
163.1200409	1.59
164.9572754	0.52
167.1738586	0.22
168.0811768	0.36
169.0167847	0.41
169.9147339	0.09
171.1600647	1.92
173.0678406	1.91
175.0013428	0.65
177.1273651	0.31
179.2238159	0.13
182.0798187	0.06
183.0966187	1.00
185.1411133	1.47
187.1461487	1.49
189.2128296	1.57
190.4525757	0.15
191.1093445	1.32
194.9008026	0.57
197.1871643	1.12
199.2781067	0.56
200.3131561	0.18
201.1454468	3.87
203.1308594	2.11
204.9442749	0.27
207.2033234	0.66
207.9122772	0.05
208.9093018	0.70
209.5443420	0.04
211.2073517	1.74
213.1413269	5.85
214.5914612	0.47
215.2102051	4.60
217.1973877	2.75
219.2535248	0.53
221.0948792	0.83
223.1523132	0.57
225.2365570	1.86
227.2086182	0.61
229.0557556	1.71
231.2500916	2.08
233.3618927	0.12
235.0050812	1.38
237.1529083	0.80
239.1271667	2.72
241.1700287	2.40
242.2685242	0.30
243.2050781	1.23
245.0577240	0.84
247.0798645	0.15
249.1831665	1.60
251.2504120	1.87
253.2274780	3.84
255.3585510	1.64
257.3457642	0.86
259.2777710	2.14
263.1413574	0.75
265.3007812	2.05
267.1895142	2.93
269.4353027	0.57
271.3197632	1.45
273.2987061	0.76
275.2953796	0.16
277.1347656	1.05
279.2722778	2.40
281.3469849	3.17
283.3954773	0.98
285.2126160	1.10
287.2888794	1.39
289.3302917	0.96
290.3894653	0.24
291.3228149	0.31
293.1159668	2.15
295.3432007	2.47
297.2072144	0.82
299.0697021	0.47
301.3342285	0.62
303.3930054	0.22
305.1434937	1.44
307.1871338	1.81
308.3442993	0.09
309.3975830	2.23
310.2568970	0.15
311.3739624	0.92
313.3054199	1.87
315.4041138	0.07
317.2593384	0.70
319.2790527	1.93
321.3596191	2.47
323.3615723	0.78
325.1998291	0.65
327.1836548	1.08
329.2940674	0.05
331.1711426	0.36
333.2475586	0.55
335.3619995	1.60
337.2650146	2.79
338.4921875	0.08
341.4078979	0.05
343.3186035	0.81
345.2851562	1.42
347.4208984	0.28
349.3422241	1.14
351.3809204	0.13
352.9340210	0.20
355.2587280	1.48
357.3720093	0.58
359.4598389	0.42
361.3845215	0.92
363.4334106	2.99
367.4589844	0.60
369.2545776	0.48
371.1084595	0.09
373.7183838	0.18
375.3058472	2.70
377.4349365	1.00
381.3887329	3.33
383.5404663	0.11
385.3104248	1.27
389.3358765	0.44
391.3690796	54.54
392.0098877	0.17
393.4940186	0.67
395.4306641	0.06
397.4797974	0.08
399.4192505	0.37
401.3557739	11.27
405.4929199	0.24
409.3201294	0.14
411.0039062	0.50
411.6176758	0.51
413.4247437	1.05
415.2581177	0.72
419.4531860	52.60
421.4260864	0.06
423.6640015	0.25
427.4294434	0.16
429.3449707	0.06
435.4663696	0.17
437.3565063	37.79
437.9608154	0.91
439.6835327	0.14
441.2153931	0.83
443.6916504	0.04
445.4407349	0.06
451.4387207	0.45
453.2984009	0.90
454.2838135	0.08
455.4452515	0.30
461.4687500	0.19
463.3833618	0.29
465.7084351	0.25
467.3829346	2.78
477.2753296	0.10
478.8735352	0.28
479.5390015	6.37
480.6996460	0.15
481.5762329	0.57
487.5211182	0.08
493.2193604	0.06
495.3222656	100.00
496.0019531	0.19
503.6275024	0.19
505.3215942	11.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	506.22
Annotation	Hernandaline
Peak:m/z	Relative Intensity
144.0855408	0.07
147.9945679	0.05
155.9025269	0.05
162.2233887	0.59
163.0831909	0.12
165.0918274	0.06
171.2309723	0.09
172.9014587	0.08
179.0205841	1.17
181.1107788	0.29
182.9356842	0.10
184.1970215	0.43
186.3590393	0.26
187.8681793	0.05
193.2765656	0.42
197.1209106	0.26
199.0578613	1.34
209.3669586	0.31
210.0965271	0.42
210.7391815	0.07
211.3552856	0.20
212.8818359	0.18
224.1306000	0.25
231.1957703	0.61
232.9578247	0.32
238.1452332	0.63
239.2251587	0.17
246.2383728	0.26
251.1546631	0.10
252.8361969	0.12
255.1254272	0.26
256.1767578	1.28
257.3888245	0.08
261.3910217	0.19
263.2504883	0.07
266.1714783	0.05
272.0743408	0.16
274.1989136	9.03
278.0711975	0.32
282.9474487	0.44
284.0557861	1.21
293.2732849	0.23
295.1248779	0.13
298.2388916	0.48
299.8094788	0.20
306.0088501	0.09
308.1503906	0.44
312.5314026	0.56
313.4993896	0.31
314.5568542	0.19
317.2453003	0.05
324.1703491	0.18
325.3724060	0.29
329.3026733	0.25
334.4396973	0.11
341.4755249	0.17
342.1248169	0.72
356.8529053	0.11
359.2262573	100.00
360.2912598	0.27
367.2871704	0.10
370.2350464	0.36
371.0913391	0.14
372.2998047	0.14
373.3020020	0.13
374.2088928	0.40
377.3016357	39.61
385.4499207	0.11
386.4374084	0.13
387.3569031	0.15
392.4705505	0.05
397.4298096	0.15
408.3890076	0.44
413.0228882	0.15
417.3856506	0.34
420.1674805	0.05
424.2195129	0.38
425.3188171	1.32
431.2367249	1.44
434.5804138	0.06
441.4234924	0.37
443.1654358	0.39
447.1266479	0.16
448.4151001	0.11
456.0454407	0.67
459.4851379	0.30
461.2052307	0.22
463.1305237	0.07
464.9228210	0.17
469.4584656	0.18
470.2635193	0.04
474.1733704	0.14
487.3570862	1.16
488.3523865	5.16
489.1399536	0.16
489.8417358	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0806
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
119.0329742	0.01
123.0272369	0.07
123.8620453	0.02
135.9085083	24.54
136.5088654	0.06
140.9312897	0.04
146.8417206	0.10
164.9292145	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9282532	100.00
143.2858887	0.16
161.1167603	0.24
211.0943604	0.06
212.7705078	36.43
225.2109680	0.21
236.2915344	0.12
237.0672607	0.03
268.3687744	0.08
282.2118530	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0833
Annotation	Unknow
Peak:m/z	Relative Intensity
130.7754211	0.48
152.9195251	0.09
155.2387390	0.05
159.0164948	3.76
161.0025940	0.38
173.1101990	0.30
174.9511414	45.61
177.0755768	0.20
178.9946594	0.07
191.2372742	0.32
194.9528503	0.13
201.1972809	0.09
217.0150604	0.09
218.9847565	9.64
220.9598236	1.33
224.2386169	0.07
235.1674805	0.03
237.0450745	0.25
262.8276367	41.55
263.5950623	0.31
265.0408936	3.16
271.7389832	0.10
279.2071533	0.13
280.9314575	31.83
291.8475342	0.07
293.3706360	0.11
297.9641113	0.05
307.4333496	0.16
311.0782166	0.05
321.0232849	0.03
325.1085205	0.19
326.1584473	0.15
341.3425903	0.18
352.8708801	0.05
359.1440430	0.07
368.2136230	0.23
369.0668945	0.07
377.2521973	0.05
394.5439758	0.21
395.1584167	0.09
411.1162415	0.32
413.0401001	0.10
438.8966980	100.00
439.7378845	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.1501
Annotation	Unknow
Peak:m/z	Relative Intensity
134.9130554	7.57
136.0282745	0.87
151.9541626	100.00
152.9368286	10.90
188.8542786	0.15
192.1550446	0.07
200.2440338	0.03
213.0849304	0.24
226.1366425	0.05
232.0588837	0.03
235.1389313	0.08
248.0995178	0.03
255.0136414	0.21
260.9890442	0.14
266.2894897	0.03
268.1520386	0.10
284.9039307	0.17
291.3088684	0.17
293.0339661	0.05
300.3020630	0.02
301.3561707	0.11
310.3676758	0.06
313.0894165	0.22
314.1625977	0.25
315.0133667	0.16
326.2563782	0.06
327.0396118	0.05
329.0505066	0.06
331.0825195	0.09
337.2235718	0.04
349.1557617	0.49
373.4599609	0.06
374.4770508	0.09
380.4873047	0.07
387.1929016	0.05
394.2709961	0.04
400.4206238	0.20
401.4283752	0.33
406.0680237	0.04
411.1609497	3.22
426.9763489	0.14
428.3419495	0.89
429.3089905	2.86
447.0242615	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.21
Annotation	6-O-Oleuropeoylsucrose
Peak:m/z	Relative Intensity
158.9076996	0.07
161.3007050	0.05
167.2515259	0.11
178.9616852	0.30
206.6671753	0.16
208.9154663	0.34
212.9389648	0.03
240.9697266	0.07
244.3195496	0.09
255.1321716	0.05
259.1289368	0.16
269.0416565	0.79
270.3245544	0.16
273.2848206	0.24
285.1078491	0.09
288.1390686	0.16
292.9513855	0.17
303.1433716	1.45
304.0279541	0.17
305.2367554	0.05
306.1747437	0.42
310.3514709	0.03
311.4611816	0.03
315.4644165	0.11
316.5940247	0.07
321.3464355	0.14
326.2564392	0.21
327.2810974	0.14
328.9961853	0.28
345.2858582	0.19
348.8463135	0.10
357.2533569	0.13
362.9887695	0.06
371.2736206	0.22
372.1492615	0.05
376.3650818	0.16
405.3687439	0.09
406.0991821	0.04
409.5428772	0.05
415.2011414	0.17
421.1973877	0.09
422.6496887	0.10
429.4504395	0.35
443.4171448	0.23
445.2616272	0.04
457.0850830	0.21
461.2298279	100.00
461.8448792	0.46
463.3482971	0.66
468.3990173	0.06
471.0903625	0.33
475.4483032	0.14
477.1828308	0.27
479.7424011	0.06
487.3880920	0.34
489.1914978	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	570.2102
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0990601	0.39
175.8689880	0.15
176.8437805	0.06
184.2310638	0.46
202.1716614	0.07
208.2332153	0.14
220.0200653	0.22
223.3045197	0.09
245.2940674	0.12
271.1876831	0.16
276.2531738	0.15
277.3397217	0.09
284.7241211	0.34
285.3871155	0.23
290.1828613	0.25
300.8816528	0.20
302.0458984	1.54
303.2290649	1.12
304.9957275	0.13
308.0546265	0.22
311.0965576	3.78
313.3598022	0.70
320.2009888	1.09
324.2001343	0.26
327.0220947	0.06
328.1729126	0.04
330.0881348	0.52
338.0765991	2.82
340.2180786	0.18
344.1761475	0.10
345.1957397	0.17
348.0263062	0.28
352.9773560	0.29
355.2108154	0.25
357.2062988	0.21
359.3607788	0.17
367.6355591	0.15
373.1132812	0.61
376.9277344	0.46
385.4639282	0.04
386.7500000	0.24
387.4347534	0.19
388.3138428	0.31
389.4741821	0.20
391.6807251	0.11
393.2287598	0.11
394.9293823	0.09
405.1785889	18.44
406.2751465	0.09
411.3529053	0.08
415.9679565	0.42
423.3043213	100.00
433.7534180	0.21
437.1582642	0.22
441.1422729	30.19
441.7716675	0.18
444.7788696	0.15
449.1137695	0.10
461.3665771	0.54
477.4299316	0.33
479.7915039	0.51
489.0743408	0.58
490.1832275	0.29
495.4571533	0.65
505.3916626	0.40
509.7234497	0.08
516.0312500	0.21
517.5197754	0.38
522.5421753	0.16
528.4423828	0.11
531.9228516	0.25
533.6271362	0.32
535.6724854	0.32
537.3085327	0.45
543.0154419	0.31
551.1036377	0.73
552.2789917	5.34
553.2069702	0.59
554.5903320	0.31
555.2293091	0.05
557.2844849	0.55
559.6091919	1.02
561.1340332	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1315308	0.12
186.9037323	0.09
192.7805634	0.05
198.7454987	0.07
201.2145233	0.23
202.3272247	0.07
237.1063538	0.13
241.0974426	0.03
261.0743408	0.47
262.0844421	0.28
263.7003784	0.19
265.0478210	0.06
275.4355774	0.05
278.2464600	0.09
289.1575012	0.07
290.0438232	0.05
291.2903137	0.17
310.8078613	0.03
311.4211731	0.05
320.0884094	0.05
322.4509583	0.17
337.3652039	0.16
340.2396240	0.07
381.9885254	0.15
383.4201355	0.07
385.5505371	0.11
392.3854370	0.05
407.3096619	0.03
409.4266357	0.13
410.1948242	0.04
411.4144592	0.10
414.1233826	0.06
423.2429504	100.00
424.2577820	31.83
425.0976562	0.26
426.1719055	0.19
434.1741028	0.47
449.2963257	0.13
450.3201599	0.17
451.5281677	0.26
452.2380066	0.32
453.1992493	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.1
Annotation	Crotonoside
Peak:m/z	Relative Intensity
81.1616974	0.02
82.9309387	0.09
84.9424973	0.16
89.0059052	0.14
89.9017563	0.04
90.8584137	0.05
93.1197739	0.02
94.8804016	0.26
104.9747238	0.39
107.0841904	0.05
108.8980560	0.18
110.9272156	0.06
112.8834763	0.07
114.9114456	0.07
115.9939117	0.05
117.8193512	0.07
121.1164780	0.33
124.9795914	0.04
126.6966248	0.23
132.8339539	0.57
133.9716644	0.38
135.0850525	0.28
136.8037109	0.25
140.9497986	0.42
141.9709167	0.06
144.0557404	0.08
145.0263519	0.48
149.2223511	0.23
151.9142456	100.00
152.6776886	0.02
154.9871063	0.07
157.1052551	0.25
162.9791870	0.18
166.8063049	0.36
168.9827881	0.21
172.0453339	0.05
177.0692139	0.61
178.0863647	0.26
180.8022461	0.03
183.1021423	0.03
187.1789551	0.29
197.0446167	0.04
200.0192566	0.03
204.0154419	0.02
205.2685852	0.04
209.1029053	0.11
213.1329346	0.20
221.3112793	0.11
222.0673218	0.06
224.3470459	0.07
225.1492920	0.13
227.0642395	0.15
230.1698303	0.45
231.0597534	1.29
238.0405273	0.54
239.0895996	0.48
240.0173340	0.32
241.3878784	0.10
247.4524536	0.52
248.3096924	2.44
248.9274292	3.48
253.1328735	0.05
254.2091370	0.06
261.0657959	0.08
265.2448730	1.26
266.2247925	4.22
267.0607910	0.70
269.1056519	0.04
275.2163696	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.1965
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9798126	0.32
167.0341187	0.19
170.9887695	0.05
176.8901672	0.68
179.0678864	1.88
180.0278931	0.05
185.0783539	0.06
196.9928589	0.16
205.1184998	0.08
210.1289368	2.00
213.0676575	0.10
228.2518158	0.05
233.1191711	0.13
235.9974976	0.34
240.1376648	0.05
242.2026672	0.17
254.1254272	4.54
272.0845947	7.22
278.1520996	0.15
281.2849121	0.12
288.0491028	4.91
306.1211548	100.00
311.0681763	0.06
313.2235107	0.03
327.7065430	0.05
344.5433960	0.06
346.2581177	0.12
351.5972290	0.10
356.6496582	0.03
357.3052979	0.12
358.3482056	0.13
361.4502563	0.09
363.1560059	0.13
367.5096436	0.08
370.3748169	0.03
372.2648315	0.21
388.5220947	0.04
401.3986816	0.05
402.5441895	0.04
409.8711548	0.08
413.2049561	0.10
426.1726074	0.04
436.4608154	0.03
438.4277344	0.04
444.3025513	0.10
445.2856445	0.07
451.3028564	0.03
457.2242432	0.04
462.9569092	0.01
463.9093628	0.02
465.3297729	0.26
470.4036865	3.22
486.2969360	0.12
487.2431641	0.38
488.4356689	0.17
496.3735962	0.29
501.3743896	0.05
502.3505249	0.05
514.1350098	3.73
514.7632446	0.06
533.2883301	0.11
534.0398560	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	154.0622
Annotation	L-Histidine
Peak:m/z	Relative Intensity
66.9468689	0.08
71.9640503	1.71
80.9630966	1.11
92.9686432	7.26
94.2257080	0.10
107.8471985	5.38
108.9417114	9.73
109.9511566	7.73
117.9739838	5.58
135.9093170	76.04
137.0304718	100.00
154.0585938	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2236
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
166.9848633	0.24
201.1817474	0.16
202.8590393	0.22
209.0400391	0.87
235.2739868	0.13
243.1254120	0.05
244.0550690	0.04
247.2532654	0.05
253.2855988	0.33
265.2271729	0.11
278.0520020	0.03
284.0247803	0.09
287.1579590	0.08
293.0571289	0.20
301.1164551	0.12
304.8202515	0.13
315.4527588	0.04
331.2943726	0.57
347.3002930	0.23
355.3995972	0.11
368.2055664	0.11
377.6660767	0.05
385.5686646	0.12
395.3484497	0.10
403.2800903	0.09
412.9348145	0.05
418.9459229	0.25
431.2354126	0.03
445.3831177	0.50
447.3254395	0.09
449.2869873	0.72
461.5977173	0.07
463.3656616	100.00
466.5361328	0.08
467.5901489	0.24
470.3917236	0.08
471.2324219	0.08
472.0641479	0.04
482.6187134	0.10
488.0422974	0.07
489.3894653	0.55
490.3998413	0.04
491.2490845	0.94
508.2266235	0.03
510.0285034	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1815
Annotation	(1R*,2R*,4R*,8S*)-p-Menthane-1,2,8,9-tetrol 9-glucoside
Peak:m/z	Relative Intensity
110.9555511	0.06
112.8819656	0.50
123.7709427	0.07
143.1572571	0.06
155.9971619	0.06
158.4672852	0.03
159.1534729	0.23
161.0859222	0.56
163.1422729	0.02
178.0429382	0.03
178.7766418	0.06
183.1341705	0.22
184.0005493	0.10
185.1216125	0.97
190.8795013	0.19
199.3320007	0.04
203.1166077	0.80
209.2225037	0.11
211.0955658	0.08
212.0803223	0.03
215.1679077	0.08
221.1570435	0.03
228.2270508	0.06
229.1336365	0.08
235.1960144	0.08
243.0299988	0.07
247.2153320	0.03
254.8827209	0.03
258.3206482	0.02
259.1528015	0.08
269.0299377	0.28
270.0958862	0.06
276.1878662	0.45
277.1458435	0.21
281.1777039	0.56
285.2772217	0.07
289.1745605	0.03
303.2193298	0.23
305.3883972	0.03
318.5864258	0.80
319.4223328	0.22
320.4216309	0.28
321.2238159	0.55
329.2656860	4.45
331.2770996	0.04
336.6578064	0.08
343.9423218	0.06
345.2677612	0.25
346.0170593	0.04
347.2398071	100.00
348.3016052	0.71
348.9611511	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.0567
Annotation	4-(4-Deoxy-beta-D-gluc-4-enuronosyl)-D-galacturonate
Peak:m/z	Relative Intensity
113.0770416	0.15
114.9231873	2.77
126.9608612	0.04
129.3653107	0.04
130.8343506	0.07
132.6950989	0.10
144.0571289	0.11
145.1688080	0.07
173.0712891	0.07
174.9755859	100.00
175.7655640	0.01
177.1777954	0.03
225.2225952	0.03
231.1767883	0.02
235.9885254	0.16
253.1542053	0.08
254.0644836	0.03
264.0034180	0.06
271.0412292	0.06
272.3824463	0.01
278.2919922	0.03
278.9706421	0.04
306.1744385	0.08
307.2088623	0.04
332.2866821	0.08
332.9428101	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	740.6529
Annotation	Unknow
Peak:m/z	Relative Intensity
220.8406067	0.04
247.2471619	0.05
280.0462036	0.01
289.1582642	0.05
290.2006836	0.08
292.1647949	0.07
298.3233643	0.03
316.2219543	0.09
356.2490234	0.03
357.0792236	0.10
362.0093384	0.12
389.3474731	0.02
390.2352905	0.03
391.1108398	0.10
399.4313354	0.03
403.3169556	0.08
407.2275391	0.08
408.2533569	0.07
417.4456177	0.03
434.1926270	0.03
446.0419312	0.04
451.3579712	0.03
457.5593872	0.02
460.8608398	0.12
462.4114990	0.12
475.3773193	0.09
484.8395996	0.02
488.4932861	0.13
526.7781372	0.02
533.3230591	0.10
541.6165161	0.09
559.0288086	0.08
575.5449219	0.08
577.4238281	0.07
590.2887573	0.03
592.3383179	0.06
593.6064453	0.05
595.8624268	0.24
644.6447144	0.01
645.4808960	0.02
649.2012939	0.03
650.1198120	0.04
651.2542114	0.07
662.2821655	0.06
674.0581665	0.07
691.1217651	0.02
698.7141113	0.10
700.8006592	0.04
701.4579468	0.08
710.7681274	0.09
712.9340820	3.21
714.1704712	0.05
715.1276245	0.03
716.6074829	0.14
717.9124756	0.08
719.5383911	0.05
720.4517822	0.10
722.3873291	0.01
723.6685791	0.10
724.3956909	0.03
741.4956665	0.12
750.4212036	0.22
759.6102905	0.76
764.3595581	0.03
770.3154297	0.03
773.8613281	1.58
788.7263794	0.03
797.0715942	0.18
800.5031128	0.06
807.3381348	0.04
808.0834351	0.28
811.0256348	0.49
815.7626343	0.17
818.5867310	0.65
819.4735107	0.34
820.8432617	0.03
822.4224243	1.66
823.6002808	0.39
825.2656860	0.11
826.4647827	0.22
828.7874756	0.18
831.2039185	0.02
833.0150757	0.08
833.9692993	0.20
837.4954224	0.04
848.0207520	0.53
849.4572144	0.13
851.7572632	6.91
852.6929932	0.25
853.4861450	0.06
855.1782837	100.00
856.6253052	2.70
857.7362061	1.93
858.7382812	1.35
859.6605835	0.50
860.8081665	0.80
862.1762085	0.30
864.3298340	0.34
865.4576416	0.39
866.6950073	0.16
868.0825195	0.35
869.4791870	0.03
871.0165405	0.86
872.6332397	0.02
873.3038940	0.02
875.1326294	0.44
878.0097656	0.04
883.2112427	0.09
887.4848633	0.22
889.6696167	0.02
891.9428711	0.33
896.0164185	1.17
896.6828613	0.28
911.1093750	0.25
920.6066895	0.33
921.6043091	0.03
925.3198853	0.14
935.3201294	1.57
937.1591797	0.10
940.3773804	0.03
941.4812622	0.44
945.8278809	0.19
946.7086792	0.07
947.6975708	0.03
949.3012085	11.60
950.1087036	0.33
951.2924194	0.10
951.9077148	0.04
953.2440796	0.04
956.2601929	0.09
961.9016113	0.18
967.0711060	5.59
968.2225952	0.02
969.7352905	0.09
970.9135132	0.01
971.6240234	0.18
986.9133911	0.13
991.1426392	0.20
993.5764771	0.25
995.7553101	11.78
996.4765625	1.81
998.7145996	0.26
999.4328613	0.12
1000.2661740	0.20
1001.0045780	0.05
1002.3416140	0.12
1009.0539550	0.64
1010.1499020	0.24
1013.5938110	8.63
1014.7260740	0.27
1016.1190800	0.18
1017.0348510	0.12
1018.7441410	0.12
1019.4475100	0.05
1020.5915530	0.07
1023.4948730	1.17
1027.7740480	10.12
1029.0178220	0.08
1030.9163820	0.18
1031.7247310	0.13
1032.4831540	0.11
1037.7409670	0.08
1040.2463380	0.41
1041.6866460	0.02
1045.3994140	0.15
1048.4971920	0.05
1078.5334470	0.07
1081.6164550	0.05
1085.5559080	0.15
1094.3750000	0.10
1099.8857420	0.07
1105.8666990	0.15
1107.7827150	0.02
1117.7845460	0.15
1125.1419680	0.16
1129.6235350	0.09
1134.5733640	0.08
1142.0063480	0.14
1146.7803960	0.07
1148.7558590	0.15
1149.6776120	0.10
1150.5544430	0.34
1155.6708980	0.28
1156.7542720	0.20
1160.9433590	0.56
1161.7839360	0.86
1182.8756100	0.10
1186.3574220	0.13
1188.1550290	0.08
1188.8220210	0.27
1191.8177490	0.11
1194.0606690	0.82
1194.8154300	0.76
1199.8570560	0.16
1202.5245360	0.04
1209.4348140	0.11
1216.6475830	0.17
1217.5076900	0.06
1226.2315670	0.24
1238.2860110	0.31
1239.2611080	0.11
1249.6252440	0.05
1253.8647460	0.03
1256.1663820	0.30
1256.7786870	0.04
1260.5437010	0.29
1261.8541260	0.02
1265.6137700	0.76
1266.2158200	0.16
1268.9359130	0.03
1276.7069090	0.19
1277.8006590	0.17
1279.7279050	0.13
1283.0067140	0.49
1283.9210210	0.08
1288.7418210	0.07
1289.7237550	0.17
1292.4010010	0.02
1302.7553710	0.06
1306.8092040	0.10
1311.7386470	0.07
1319.3402100	0.20
1321.1052250	0.12
1322.2603760	0.06
1326.1422120	0.15
1327.3565670	0.51
1328.3323970	0.25
1329.4730220	0.11
1335.6334230	0.04
1338.0579830	0.08
1340.7707520	0.04
1346.9405520	0.04
1350.5101320	0.04
1355.8879390	0.06
1376.3157960	0.10
1386.6101070	0.06
1392.4086910	0.07
1404.9759520	0.12
1407.0004880	0.03
1414.8172610	0.30
1423.6475830	0.08
1454.0106200	0.07
1459.9566650	0.16
1462.5161130	0.01
1468.4816890	0.05
1469.5267330	0.05
1482.3901370	0.01
1484.5081790	0.02
1490.1221920	0.08
1517.2633060	0.07
1519.6367190	0.02
1531.4289550	0.06
1532.8519290	0.23
1566.8455810	0.11
1582.8079830	0.14
1587.2800290	0.03
1591.0147710	0.42
1597.3817140	0.05
1598.0374760	0.03
1606.0186770	0.08
1616.2272950	0.01
1622.4678960	0.04
1634.5496830	0.03
1635.4427490	0.02
1637.0372310	0.06
1652.9957280	0.11
1654.9685060	0.01
1673.0875240	0.04
1686.6168210	0.10
1689.9661870	0.03
1698.8142090	0.08
1700.2359620	0.04
1704.4180910	0.13
1711.0924070	0.06
1714.4410400	0.19
1732.3651120	0.16
1736.8621830	0.08
1740.1135250	0.05
1746.8558350	0.04
1751.0511470	0.05
1774.3756100	0.09
1778.1082760	0.02
1807.0032960	0.28
1822.9475100	0.02
1833.0588380	0.07
1854.4826660	0.43
1855.3850100	0.05
1876.9719240	0.09
1877.5794680	0.03
1884.4783940	0.06
1891.7259520	0.42
1894.3527830	0.02
1934.5560300	0.07
1943.1242680	0.03
1948.9421390	0.02
1959.5965580	0.01
1966.6989750	2.23
1975.0323490	0.05
1994.9044190	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	952.12
Annotation	Unknow
Peak:m/z	Relative Intensity
306.2792969	0.21
316.0703125	0.12
317.8775940	0.47
332.0152283	0.26
352.5710144	0.18
360.2751770	0.74
385.0982666	0.19
391.2368164	0.78
411.1962280	0.08
419.2152100	0.54
428.2672729	0.15
436.5440063	0.12
450.6426392	0.18
459.3484497	0.07
480.1616211	0.26
482.0939941	0.42
496.3223267	0.12
497.1870117	0.07
498.1099854	0.12
503.2721558	0.11
511.6382446	0.08
528.5521240	0.40
540.4283447	0.13
591.7529297	0.15
596.8784790	0.42
609.3695068	0.39
610.7548828	0.48
627.1461792	0.65
630.3383789	0.15
652.7694702	0.11
656.4781494	0.14
658.3935547	0.30
678.5193481	0.16
679.5418091	0.31
686.4952393	0.16
701.8696899	0.44
718.6069946	0.07
723.2929688	0.12
732.6596680	0.31
734.6190796	0.10
740.0110474	0.37
768.5739136	0.11
771.2742310	0.17
789.3512573	0.94
792.0840454	1.35
822.5255737	0.26
825.6527710	0.23
843.8041382	0.18
851.5510864	0.33
852.4509888	0.43
859.8215332	0.90
860.5486450	1.12
863.4893188	0.27
867.2169189	0.09
870.7523193	0.52
871.9058228	0.31
877.5533447	0.73
882.1729736	1.73
886.0557251	1.64
886.8834229	0.23
889.8790283	3.59
894.7246094	0.24
896.9958496	1.16
898.6933594	1.22
902.5950317	0.61
905.8887939	0.26
906.6937866	1.86
907.5178833	0.88
908.8524780	1.03
911.4990845	0.79
913.8923950	1.80
914.4959717	0.74
915.8457031	5.09
916.8180542	0.58
918.2424927	4.88
919.2883911	0.24
922.4376831	0.88
924.4505615	0.61
925.3717651	0.34
927.8006592	0.06
928.6303711	0.17
929.9631958	1.88
933.2541504	0.51
934.5447388	0.21
936.2963867	3.82
952.3673706	100.00
953.4199829	3.15
954.3903809	0.23
956.6817017	0.44
960.9115601	0.13
978.9912720	0.58
989.6384888	0.35
1007.0810550	0.17
1007.9006350	0.57
1017.9205930	0.41
1020.7084960	1.00
1024.5551760	0.06
1025.2393800	0.98
1027.1601560	0.54
1035.4726560	0.71
1036.9348140	0.13
1037.5675050	0.68
1043.9902340	0.71
1047.7196040	0.06
1050.4333500	0.34
1051.7851560	0.19
1052.7431640	0.79
1054.4942630	0.55
1055.2031250	0.84
1060.2192380	2.10
1061.4536130	0.47
1062.7380370	0.76
1064.6577150	0.53
1065.8936770	0.22
1074.0145260	0.44
1075.2580570	0.89
1079.4761960	0.17
1080.1604000	0.19
1080.9962160	0.38
1083.9718020	0.59
1092.9567870	1.68
1095.0703120	1.59
1097.3884280	0.41
1099.6872560	0.76
1102.4396970	0.05
1103.4912110	2.40
1105.1105960	0.36
1106.1765140	0.85
1107.8757320	0.37
1110.1704100	0.33
1113.1608890	0.48
1115.0734860	0.57
1115.9558110	0.27
1121.2207030	0.62
1121.8496090	0.52
1123.4366460	1.30
1124.0454100	1.13
1125.6524660	0.35
1126.6003420	0.78
1130.5587160	0.08
1136.9976810	1.16
1138.2938230	1.57
1139.9222410	1.23
1143.3035890	0.53
1145.8996580	0.91
1148.3371580	1.12
1149.8081050	0.77
1150.7219240	0.21
1151.6068120	1.15
1154.5554200	0.36
1157.2995610	0.30
1159.3807370	1.35
1162.1103520	0.46
1165.0551760	1.05
1168.8602290	3.44
1169.8016360	1.41
1172.2626950	0.45
1174.8623050	3.30
1176.2658690	0.44
1178.0843510	0.94
1180.9289550	21.05
1181.6715090	0.11
1182.4556880	0.40
1185.9821780	0.56
1191.7792970	3.20
1192.7453610	0.70
1196.4746090	0.30
1197.9257810	0.42
1198.7425540	0.78
1202.7565920	0.55
1203.3800050	0.44
1207.2316890	2.08
1208.3742680	0.11
1210.7596440	1.65
1212.0198970	1.16
1213.2543950	0.47
1214.4969480	2.22
1218.0018310	1.23
1218.7532960	1.76
1220.5432130	1.60
1222.3879390	0.34
1223.9805910	4.68
1224.7901610	1.71
1226.4201660	4.92
1229.8190920	9.44
1230.5185550	4.85
1231.2768550	0.78
1233.6884770	0.16
1245.8936770	0.48
1257.6228030	0.45
1264.8171390	0.23
1268.8465580	0.54
1279.3889160	0.42
1290.3837890	0.68
1296.7600100	0.36
1306.0421140	0.79
1306.8784180	0.37
1326.2371830	0.64
1332.4781490	0.20
1339.7851560	0.39
1352.5831300	0.85
1367.1092530	0.21
1382.3465580	0.46
1396.6634520	0.67
1414.4121090	0.39
1449.3155520	0.28
1457.5059810	0.43
1465.0686040	0.61
1487.2486570	0.36
1491.6910400	0.13
1504.8616940	0.19
1516.8218990	0.41
1522.1453860	0.46
1531.2611080	0.33
1541.0775150	0.25
1562.8436280	0.46
1566.9808350	0.21
1567.6387940	0.48
1574.6972660	0.17
1580.8541260	0.80
1581.8300780	0.32
1589.3614500	1.69
1590.1846920	3.39
1609.9147950	0.37
1615.0511470	0.12
1630.2767330	0.17
1659.4910890	0.07
1677.0191650	0.25
1718.5773930	0.08
1721.7707520	5.55
1751.9753420	0.48
1764.9846190	0.54
1774.6008300	0.08
1820.5692140	0.56
1822.1999510	0.53
1824.8223880	0.06
1831.1804200	0.09
1876.0296630	11.19
1926.6978760	0.41
1933.8507080	0.16
1934.5954590	39.31
1941.5811770	2.36
1961.9979250	0.14
1997.6778560	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.4397
Annotation	Isorebaudioside A
Peak:m/z	Relative Intensity
871.5241699	0.44
920.7566528	5.69
921.4360962	4.06
964.7946167	37.28
965.4041138	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
119.8985443	100.00
120.6988831	0.01
130.9937439	0.12
148.8388214	4.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	309.06
Annotation	6-Phospho-D-gluconate
Peak:m/z	Relative Intensity
100.6827240	0.13
106.7921906	0.49
108.9799652	0.36
111.0398483	0.59
116.5464554	0.09
117.1942444	0.48
129.8751526	96.25
131.0446930	9.48
132.0393066	7.57
132.9041443	1.02
138.8987122	0.17
142.9723663	0.64
144.0830688	0.78
145.0004272	1.45
146.0540466	0.78
149.2738342	0.56
151.0227203	1.44
156.9698486	0.64
159.8946838	0.78
160.9661560	0.19
162.0511932	0.88
169.0057831	0.38
171.1176147	0.18
175.0014191	0.63
175.9433136	0.17
177.0270386	0.66
178.8159180	7.78
179.4612427	0.46
180.1568451	0.62
180.9955139	1.67
192.9488831	13.98
195.0625763	1.24
198.7009888	0.08
208.8683167	0.19
210.9935913	21.28
213.1092224	0.18
214.9320679	0.24
216.3257751	0.38
217.1760254	0.44
219.6350403	0.24
221.4402161	0.17
225.4297180	0.77
226.2108459	0.65
230.8269348	0.51
232.0838928	0.44
233.1600037	1.32
234.4426575	0.62
235.2024536	0.49
236.9380188	0.24
243.3901978	31.17
244.2772827	6.50
245.1020813	1.01
245.9436646	0.26
246.7512207	0.09
248.0905762	0.69
249.3408813	0.33
251.0392456	0.55
252.3043213	0.14
253.1723633	0.22
254.1147461	0.09
255.1275940	0.14
257.1691895	0.42
261.0109253	0.66
261.6984558	1.22
263.0626831	1.61
264.1997070	0.20
266.1639404	0.41
267.4470215	2.45
268.0747375	0.31
269.5031128	2.31
270.7338257	35.64
271.8783569	3.69
273.2190552	0.91
274.0892334	0.22
276.6712646	63.85
277.8489990	4.31
279.0075684	0.49
279.7955627	0.42
280.8635864	0.52
283.8247681	0.21
286.3578491	0.10
288.1835327	0.72
289.1813049	0.67
290.2263184	4.38
291.1622314	4.87
292.1442871	0.11
294.4161682	0.48
296.8788452	1.23
299.6653442	100.00
300.7232056	6.05
306.1471558	0.49
308.1604309	0.49
310.1240234	0.28
311.1960449	0.14
312.0827942	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	816.6307
Annotation	Unknow
Peak:m/z	Relative Intensity
261.0795288	0.06
285.3266296	0.18
288.0458374	0.11
297.9894409	0.08
301.2473755	0.06
304.0938416	0.21
316.2286987	0.11
318.2027588	0.07
326.0707397	0.05
333.5937500	0.18
357.2852173	0.14
374.9601440	0.09
395.5311890	0.48
402.3523560	0.20
431.5317993	0.27
446.3079834	0.08
448.1076050	0.24
460.3728638	0.10
462.2328491	0.10
467.1362305	0.11
472.2932739	0.88
496.4215698	0.10
523.9591064	0.08
536.0975952	0.05
542.0538940	0.05
565.7337036	0.39
569.5482178	0.12
586.9286499	0.16
590.1720581	0.05
596.5097046	0.28
600.7000122	0.13
603.4172974	0.06
609.6358032	0.22
613.6233521	0.34
616.8248901	0.26
624.2781982	0.05
626.9973755	0.78
633.7767944	0.04
636.1345215	0.14
638.5835571	0.20
644.9069214	0.12
647.0345459	0.21
648.2487183	0.16
650.3832397	0.17
652.7059937	0.12
655.5802612	0.06
656.2506104	0.12
659.3677979	0.03
662.4829712	0.08
664.5147705	0.55
668.2682495	0.06
671.8398438	0.43
674.2619019	0.55
675.2034302	0.07
679.9666138	0.31
680.6648560	0.39
684.1852417	0.53
685.4965210	0.08
688.2980347	0.18
689.6498413	0.16
693.9252319	0.37
698.4550171	0.43
700.9098511	0.33
704.1754761	0.47
704.9971313	0.04
713.2587280	0.22
713.8783569	0.41
715.2642212	0.84
717.1585083	0.28
717.7894897	0.22
720.7802124	0.65
723.3662109	0.58
724.2866211	0.75
726.4124146	0.88
729.1670532	0.94
730.8436890	0.65
731.4911499	0.28
733.8074951	0.80
734.7962036	1.08
737.4295654	0.70
738.6301880	0.07
739.6773071	0.90
740.5804443	0.19
742.9735107	2.82
744.4598999	0.76
749.1831055	1.75
751.1501465	0.33
752.1926270	1.27
753.0459595	0.88
761.1582031	0.49
762.5705566	1.01
763.9071045	2.68
765.0153198	1.95
766.6878052	3.16
767.5708618	1.40
768.4805298	1.58
770.3307495	1.55
771.9708252	0.14
772.8244019	12.20
773.9676514	1.34
775.0739136	1.02
776.4489746	2.69
777.6609497	2.84
778.5509033	1.98
779.4648438	1.25
780.0884399	0.59
781.8498535	5.62
782.4825439	2.60
783.2164917	0.70
784.2041626	1.62
785.3817749	0.58
787.8188477	0.19
789.3634033	0.61
790.2763672	0.80
791.3201904	0.61
792.8235474	2.08
794.8289185	0.30
795.8152466	1.86
796.6401978	1.29
797.9790649	0.21
799.3081665	0.68
801.3956299	3.20
802.1151733	7.60
803.2569580	0.90
805.0465698	0.13
807.9948120	0.31
818.0787964	0.23
828.9948730	0.09
832.9436035	0.22
839.0576172	0.34
843.1119995	0.41
844.0626221	0.16
845.8250122	0.33
848.6758423	0.18
851.4390259	0.25
854.7605591	0.12
855.7473145	0.49
861.6771851	0.30
862.6545410	0.19
864.4030151	0.22
870.4598999	0.07
874.2537231	0.76
882.3695679	0.19
886.7770996	0.35
889.6794434	0.06
891.3755493	0.04
892.2445679	0.72
894.9641724	0.32
901.6065063	0.22
905.3543091	0.85
906.6737671	0.17
909.6430664	0.26
911.5488892	0.24
915.6408081	0.05
916.9655762	0.22
919.5320435	0.27
920.3471069	0.28
921.0830078	0.49
922.5125122	0.04
923.5440063	0.21
926.4704590	0.07
929.0025024	0.39
932.2053833	0.08
935.1186523	0.14
936.0553589	1.06
939.2316284	0.11
948.9423218	0.16
953.1464844	0.14
953.9184570	0.45
955.3875122	0.55
956.7576294	0.54
958.4946899	0.30
962.5980835	0.12
963.3892212	0.46
966.8727417	0.70
967.5532227	0.69
974.6848145	0.64
977.3864136	0.11
978.1441040	0.49
979.1896973	0.55
981.5147095	0.27
982.2209473	0.37
983.4525757	1.32
984.4235840	0.25
985.5636597	0.42
988.4511108	0.35
989.6465454	0.58
990.5787964	0.54
993.1887207	0.07
995.6145020	0.58
996.6195679	0.47
998.8822632	0.26
1001.4130250	0.18
1002.5886840	1.75
1003.6548460	0.89
1004.4967650	0.04
1005.6441040	0.78
1006.3605350	0.16
1008.0759890	0.32
1008.7982790	0.38
1013.7949220	0.26
1016.6804810	0.08
1017.6810910	0.06
1019.7459110	0.52
1020.9030150	0.32
1022.4965820	0.31
1023.6945800	0.15
1025.2917480	0.16
1026.5456540	0.32
1027.7429200	1.06
1028.5163570	0.41
1029.4581300	0.32
1030.6026610	0.41
1036.7430420	1.76
1038.0437010	0.61
1039.3593750	0.22
1040.6479490	0.71
1041.5748290	0.13
1042.5009770	0.31
1043.2932130	0.48
1044.3061520	1.34
1045.7612300	0.47
1046.9541020	0.19
1048.1038820	0.15
1049.4816890	0.72
1050.9077150	1.70
1052.1975100	0.83
1053.7764890	1.31
1054.4781490	0.39
1055.5271000	0.17
1056.3656010	0.98
1058.0839840	1.09
1058.9887700	0.76
1059.5947270	1.40
1060.5578610	0.96
1062.2749020	0.18
1063.5474850	1.59
1064.6156010	9.28
1065.6760250	0.24
1066.6080320	0.69
1068.1823730	0.30
1069.6787110	0.71
1071.0856930	0.16
1073.2796630	1.27
1073.9097900	0.43
1075.6562500	0.56
1076.4187010	0.67
1077.3518070	0.56
1078.3767090	0.57
1079.6107180	0.24
1083.1717530	1.84
1085.5793460	3.18
1086.4799800	1.53
1087.4040530	0.07
1088.3488770	0.73
1089.5994870	0.11
1090.5598140	1.03
1091.4785160	0.49
1092.3995360	2.18
1093.1040040	0.08
1093.9624020	1.01
1095.2607420	6.21
1096.3859860	0.72
1097.8431400	0.46
1099.1513670	1.66
1100.2044680	3.92
1101.0512700	1.85
1102.2416990	1.13
1103.4760740	0.20
1105.0825200	3.64
1106.1568600	2.55
1107.3314210	2.05
1108.2457280	0.82
1109.4079590	1.39
1110.2442630	0.49
1112.0136720	1.07
1112.6560060	0.41
1113.4304200	5.52
1114.1199950	15.80
1114.8988040	4.41
1115.9454350	1.95
1116.5646970	1.65
1117.3140870	0.86
1117.9582520	0.59
1118.9316410	0.23
1122.4948730	12.19
1123.1258540	26.80
1124.2041020	2.45
1125.8122560	0.32
1127.3901370	0.32
1128.2127690	0.45
1129.2912600	0.76
1129.9324950	0.87
1131.6678470	0.29
1132.7265620	2.08
1133.6137700	0.50
1134.7209470	1.78
1135.3530270	0.11
1137.9621580	1.28
1138.8300780	1.34
1140.8374020	0.40
1141.4494630	0.20
1142.9299320	3.75
1144.1019290	2.47
1146.3908690	2.52
1147.2431640	4.52
1148.1990970	1.11
1149.4063720	2.85
1150.2324220	0.79
1151.4543460	2.47
1152.4128420	0.33
1153.1773680	0.85
1154.4350590	0.67
1155.7570800	1.28
1157.8796390	3.40
1158.8504640	1.65
1160.0582280	3.62
1161.7498780	0.28
1163.4451900	11.00
1164.0734860	9.98
1164.7135010	0.68
1166.1169430	2.21
1166.7513430	9.29
1168.4067380	17.63
1169.2796630	5.56
1170.6984860	0.12
1172.4676510	100.00
1173.1848140	27.99
1174.0212400	0.20
1175.2658690	2.16
1176.1955570	2.46
1176.8226320	0.70
1177.4276120	0.11
1179.0728760	0.10
1180.1713870	0.08
1181.3386230	0.30
1189.6936040	0.38
1211.6893310	0.09
1212.4847410	0.22
1213.9182130	0.30
1216.4829100	0.36
1217.1678470	0.19
1227.5484620	0.25
1231.4482420	0.16
1240.8375240	0.11
1245.0970460	0.10
1253.5606690	0.30
1262.3137210	0.24
1290.6477050	0.12
1319.6453860	0.08
1334.4696040	0.11
1344.7313230	0.14
1353.6126710	0.09
1361.7703860	0.25
1376.9691160	0.17
1379.4642330	0.27
1397.1031490	0.13
1406.1926270	0.16
1429.7596440	0.24
1451.4354250	0.06
1473.1434330	0.09
1484.9713130	0.28
1497.4024660	0.09
1520.5076900	0.16
1532.5549320	0.11
1544.1373290	0.06
1579.4027100	0.19
1585.4674070	0.19
1587.5858150	0.23
1605.6021730	0.23
1623.8581540	0.16
1658.3420410	0.11
1676.6290280	0.08
1691.7170410	0.18
1697.3607180	0.13
1736.6661380	0.10
1744.6584470	0.08
1746.8121340	0.18
1751.5274660	0.15
1753.0460210	0.30
1764.9840090	0.35
1770.2071530	0.21
1772.7971190	0.25
1779.2844240	0.10
1781.3966060	0.09
1792.9561770	0.37
1798.7576900	0.07
1806.0080570	0.12
1808.7181400	0.23
1823.3941650	0.23
1827.6036380	0.10
1858.5782470	1.67
1860.9593510	0.06
1895.6881100	6.32
1898.8854980	0.04
1914.8343510	5.73
1927.1585690	0.15
1928.0437010	0.16
1941.2366940	0.43
1955.0202640	0.04
1992.6043700	0.21
1993.8101810	0.71
1995.1058350	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.4591
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
311.2494507	0.24
351.2610474	0.13
436.2564087	0.31
518.4935303	1.23
543.2544556	0.19
545.5765991	0.16
551.4043579	0.12
556.5054932	0.09
577.7085571	0.17
602.3665161	0.75
615.4845581	1.22
617.4841919	0.12
633.2787476	1.29
635.6481323	0.31
649.4622192	0.14
713.4348145	0.38
717.4237061	0.35
735.5347290	0.12
749.4036255	0.80
753.5558472	0.12
782.5458374	0.19
791.1766968	0.25
795.2874146	100.00
796.1884766	0.66
797.8852539	0.42
805.6319580	0.48
807.4348145	0.07
809.6206665	0.77
810.4414673	0.16
821.5401611	1.23
824.3146362	0.56
824.9699707	0.49
841.3023071	1.14
842.3638916	3.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3401
Annotation	Antibiotic CI 940
Peak:m/z	Relative Intensity
148.9841919	0.49
152.0463104	0.98
156.9686432	2.41
158.9344330	0.95
161.1961670	2.98
163.2284851	6.96
167.2260590	1.04
169.1843719	3.84
171.4267578	2.06
177.1003876	4.59
185.2912903	2.63
189.1656494	1.50
199.0709686	2.82
201.1724854	2.85
207.2118378	0.98
213.3373871	3.95
215.3043213	3.92
225.4515533	2.54
227.2146759	4.13
229.1781464	0.80
237.2077179	4.87
239.4053955	0.98
241.1164093	7.79
242.8543243	2.06
249.0599823	2.81
253.3818665	2.04
255.5252686	4.31
263.1995544	1.10
265.2088623	4.18
269.3265991	1.35
271.2693481	2.49
277.3917847	0.93
278.9246826	1.85
281.1023560	7.86
288.8961792	0.63
295.3067627	2.32
296.3858643	0.92
297.1449585	0.78
301.2772217	0.49
305.3009033	2.97
309.2741089	15.82
313.2885132	1.74
317.2051392	2.11
318.9974976	5.52
321.2028198	0.62
327.3015137	4.54
345.2401123	1.91
357.4511108	0.80
361.0339355	1.11
363.4653931	2.45
375.8561401	2.60
377.4541626	2.35
381.7744141	0.92
385.3785400	2.29
391.4230347	52.75
399.4307861	2.09
401.4759521	8.45
413.5881958	3.21
415.1694946	4.78
419.4282227	53.00
425.1704102	1.27
437.4747314	49.60
441.3572388	5.24
453.2716675	0.62
463.5668335	1.17
467.4223022	4.11
479.4108276	1.29
481.2316284	4.63
495.3685913	100.00
496.1115112	2.05
505.3794556	7.60
506.3813477	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.4066
Annotation	Beesioside D
Peak:m/z	Relative Intensity
425.4061279	0.30
437.3997803	0.22
443.6733398	0.07
453.4281006	0.11
470.8397827	0.13
487.4376831	0.51
517.3757935	0.48
530.9951172	0.54
547.2368774	0.14
584.5129395	0.14
587.5820923	1.23
615.4866943	1.33
633.4966431	100.00
634.4657593	4.04
635.1284180	0.34
660.7362061	0.57
661.5657959	0.74
680.4238892	6.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.4755
Annotation	Dioscin
Peak:m/z	Relative Intensity
782.6522827	7.45
806.4425659	21.73
823.6376953	14.37
824.6610718	28.31
867.4629517	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.407
Annotation	Beesioside D
Peak:m/z	Relative Intensity
307.2462769	0.07
424.1869507	0.04
425.3079224	0.09
443.6505127	0.09
453.3715820	0.05
473.7332153	0.15
501.6575928	0.21
587.4926758	0.86
605.0503540	0.07
614.8936768	0.24
615.5040283	0.36
633.4945068	100.00
634.3844604	6.52
635.0109253	0.07
643.2149048	0.04
661.2315674	0.23
662.3283081	0.07
680.3990479	4.52
681.2631836	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1032.1118
Annotation	Unknow
Peak:m/z	Relative Intensity
330.3128052	0.04
339.1912231	0.05
359.2185669	0.06
367.7432251	0.11
398.3782349	0.01
452.4774170	0.14
465.2016602	0.02
466.4109192	0.04
495.2711792	0.04
497.6775818	0.06
508.7165222	0.03
513.2623901	0.04
549.3725586	0.05
576.3084717	0.06
594.6101074	0.06
596.0374756	0.02
597.4981689	0.09
598.3079834	0.06
600.7286987	0.02
623.2082520	0.02
629.9156494	0.02
648.7973633	0.08
650.4074097	0.03
664.9844360	0.02
677.1168213	0.04
685.0344849	0.12
693.6016235	0.01
719.3635254	0.02
721.2319336	0.05
725.4769897	0.13
747.1736450	0.03
756.3422241	0.01
772.4047241	0.05
779.3695068	0.02
795.8455811	0.01
796.7091064	0.05
804.2757568	0.29
808.1593018	0.02
813.5588379	0.09
829.2307129	0.02
842.2723389	0.13
847.8594971	0.11
851.9604492	0.01
859.6192627	0.03
860.6839600	0.01
862.4899902	0.15
865.0341797	0.09
869.2113037	0.18
874.5598145	0.15
875.4968262	0.10
881.4378662	0.03
882.6931152	0.05
883.8587646	0.09
886.8140869	0.23
887.8629150	0.02
889.1876221	0.38
890.2786865	0.02
893.2985840	0.12
894.9505615	0.05
899.0908203	0.07
902.5289307	0.30
903.9414062	0.43
907.7366943	0.03
912.5465088	0.14
913.3984375	0.29
916.1544189	0.05
917.9378662	0.06
920.9401855	0.09
922.6763916	0.42
924.0139160	0.05
925.3745117	0.07
926.0310059	0.11
928.0751953	0.05
930.1512451	0.03
931.2418213	0.16
932.0372314	0.05
934.2615967	0.12
934.9520264	0.09
936.2099609	0.13
937.4969482	0.58
938.4409180	0.13
940.6135254	0.04
942.2545166	0.23
943.3275146	0.23
945.2908936	0.16
946.2122803	0.60
946.8572998	0.03
948.0367432	0.55
949.5894775	0.25
951.0447998	0.08
955.2541504	0.55
956.3159180	0.18
958.3476562	0.38
961.6976318	0.28
964.0196533	0.09
966.7764893	0.56
969.6499023	0.38
973.4062500	0.34
974.3081055	0.35
975.4866943	0.37
976.6513672	0.19
979.0377197	0.47
979.6452637	0.11
982.0280762	0.32
982.7661133	0.53
983.3854980	0.13
984.5615234	0.76
985.4610596	0.36
987.0708008	0.14
988.5844727	1.00
989.7951660	0.22
992.3947754	0.14
993.5808105	0.61
994.7493896	0.31
995.3706055	0.11
996.4453125	0.04
998.0446777	0.36
999.4903564	1.78
1001.6390380	0.14
1002.6905520	0.16
1005.5610350	0.07
1007.8195800	0.38
1008.7524410	0.44
1011.4675290	0.51
1014.4163820	0.47
1016.2805180	0.21
1016.9018550	0.29
1017.5842290	0.08
1032.7641600	100.00
1033.4693600	4.42
1034.3974610	1.77
1035.5881350	0.85
1036.5605470	0.21
1037.9116210	0.31
1038.7868650	0.23
1041.4365230	0.05
1044.4597170	0.20
1045.6047360	0.03
1047.2197270	0.05
1048.2778320	0.02
1049.1103520	0.11
1057.6768800	0.10
1072.0319820	0.09
1079.1439210	0.05
1081.6569820	0.11
1086.2014160	0.02
1088.9277340	0.08
1091.1890870	0.09
1092.7413330	0.10
1110.6125490	0.04
1114.4918210	0.01
1117.0059810	0.05
1119.0144040	0.08
1122.4803470	0.05
1123.5458980	0.08
1138.5932620	0.12
1139.5628660	0.11
1140.4581300	0.07
1143.3339840	0.10
1145.7366940	0.17
1146.8218990	0.04
1150.0097660	0.14
1158.3593750	0.10
1170.0218510	0.05
1171.0588380	0.04
1173.8011470	0.15
1176.5233150	0.12
1177.3769530	0.16
1182.7622070	0.02
1184.5590820	0.08
1185.7138670	0.18
1190.4244380	0.03
1191.5014650	0.25
1193.1629640	0.25
1193.8750000	0.01
1201.5401610	0.28
1202.2177730	0.07
1210.0173340	0.03
1214.0483400	0.08
1215.0816650	0.05
1219.4736330	0.04
1221.6638180	0.08
1223.1173100	0.19
1223.8424070	0.11
1225.9085690	0.15
1226.7205810	0.05
1230.0604250	0.03
1232.3720700	0.02
1234.0455320	0.01
1235.3356930	0.20
1238.0762940	0.12
1242.3161620	0.07
1243.2514650	0.06
1246.0225830	0.11
1246.9790040	0.04
1248.2493900	0.30
1249.2750240	0.13
1251.1934810	0.33
1252.2449950	0.09
1253.2838130	0.15
1255.4176030	0.15
1258.9625240	0.41
1262.8579100	0.11
1264.4519040	0.11
1266.2164310	0.12
1270.5793460	0.07
1271.5773930	0.03
1274.2476810	0.02
1275.8968510	0.18
1277.4692380	0.19
1278.4506840	0.15
1279.7003170	0.36
1280.9091800	0.07
1284.1812740	0.06
1284.9213870	0.14
1285.8081050	0.02
1287.6187740	0.08
1290.5413820	0.13
1291.7805180	0.04
1292.8537600	0.07
1294.0405270	0.12
1294.8168950	0.25
1297.3192140	0.07
1299.6419680	0.63
1300.3032230	0.15
1301.0540770	0.04
1302.5733640	0.07
1303.6802980	0.03
1306.0816650	0.04
1307.2550050	0.16
1308.7653810	0.11
1312.7197270	0.24
1314.9798580	0.35
1315.6949460	0.11
1317.2059330	0.06
1318.3021240	0.02
1319.6829830	0.09
1320.2983400	0.04
1322.4383540	0.19
1325.2323000	0.08
1330.1203610	0.08
1331.4478760	0.07
1335.3411870	0.09
1337.2585450	0.04
1341.5246580	0.04
1343.4486080	0.14
1345.3991700	0.05
1346.2738040	0.11
1347.3458250	0.09
1349.2164310	0.09
1350.5915530	0.08
1351.8238530	0.43
1354.7901610	0.23
1355.9636230	0.14
1358.3262940	0.04
1360.6693120	0.10
1361.8397220	0.02
1363.6540530	0.26
1364.8679200	0.25
1367.3309330	0.06
1368.8502200	1.53
1369.6601560	0.21
1370.3452150	0.16
1372.8826900	0.14
1375.3446040	0.20
1376.8216550	0.17
1377.5787350	0.15
1378.3377690	0.13
1379.3763430	0.13
1382.7915040	0.15
1383.7347410	0.15
1384.8780520	0.11
1385.7314450	0.07
1387.4085690	0.05
1388.6840820	0.08
1390.1744380	0.19
1392.3685300	0.10
1393.3933110	0.12
1397.2584230	0.11
1399.4656980	0.13
1400.4375000	0.09
1402.1722410	0.15
1402.9003910	0.01
1404.2277830	0.27
1405.3056640	0.02
1412.7382810	0.03
1413.6688230	0.14
1415.3031010	0.07
1417.9376220	0.14
1418.7669680	0.10
1419.7535400	0.11
1420.4436040	0.17
1421.2797850	0.09
1422.9676510	0.16
1423.7778320	0.28
1425.2890620	0.15
1425.9395750	0.16
1427.1699220	0.04
1428.9997560	0.08
1432.5108640	0.94
1433.3498540	0.09
1434.6206050	0.19
1435.8970950	0.05
1440.7246090	0.34
1442.8366700	0.18
1448.8507080	0.42
1449.8421630	0.31
1450.4871830	0.24
1452.2622070	0.08
1453.7816160	0.10
1454.7401120	0.03
1460.6851810	0.02
1461.4129640	0.13
1463.2117920	0.18
1466.9005130	0.13
1468.1406250	0.09
1470.8131100	0.02
1475.1248780	0.05
1475.8526610	0.26
1476.5816650	0.32
1477.5249020	0.18
1480.3662110	0.07
1481.1121830	0.23
1482.4392090	0.44
1483.6629640	0.14
1489.6978760	0.23
1490.3605960	0.07
1491.0371090	0.17
1492.0012210	0.10
1498.4046630	1.60
1499.3695070	0.62
1501.9830320	0.03
1503.2708740	0.07
1512.1475830	0.02
1523.2000730	0.03
1527.8262940	0.09
1535.0949710	0.03
1559.4720460	0.03
1582.4483640	0.06
1586.1386720	0.03
1597.7966310	0.08
1603.7719730	0.05
1626.6414790	0.02
1647.0096440	0.01
1667.5852050	0.02
1668.9481200	0.02
1677.6424560	0.06
1782.0534670	0.05
1790.8907470	0.04
1794.8044430	0.02
1854.9918210	0.01
1862.6854250	0.06
1882.7932130	0.07
1887.2117920	0.01
1890.5286870	0.08
1903.6517330	0.07
1906.1859130	0.03
1926.6389160	0.03
1929.0767820	0.06
1929.7780760	0.01
1939.8533940	0.01
1959.3438720	0.04
1967.7528080	0.18
1989.3043210	0.08
1996.9035640	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1694
Annotation	Thr Phe Asp
Peak:m/z	Relative Intensity
122.1780701	0.12
123.8199387	0.40
124.7426529	0.40
132.0072327	0.56
133.2147522	0.24
147.1025696	1.54
149.140564	1.11
150.1231384	0.15
151.0126801	0.18
161.2389069	0.26
165.1496887	0.23
175.0329895	0.35
184.9990845	3.08
202.1839294	3.69
203.0657043	8.08
207.2269592	0.14
213.0089264	0.75
217.0168304	0.39
220.0820465	54.66
221.1241302	100.00
227.2708435	0.14
228.259552	0.29
237.2229004	0.94
238.2528381	1.06
240.1062927	0.34
241.2459717	0.70
257.1968689	0.12
262.0518188	0.67
266.9918213	0.69
271.444519	0.39
283.72052	0.19
293.9362793	0.61
297.2981567	0.88
299.228241	0.53
301.322937	0.75
309.2549438	0.08
314.0690613	0.17
329.2728271	0.29
331.071106	0.77
334.080719	0.75
337.2216187	1.30
338.1986084	0.77
342.2651672	1.10
343.2644043	1.74
347.463562	1.44
351.1869812	0.43
354.3042908	1.37
355.1572266	0.17
359.7892761	1.09
361.041687	0.56
363.1916809	0.18
365.3051453	1.98
374.6781921	3.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.3302
Annotation	Petrosiacetylene D
Peak:m/z	Relative Intensity
116.9256210	0.16
118.9274292	1.00
121.0289383	1.66
123.0229034	1.72
126.8292694	0.34
128.1526337	0.79
128.9774628	1.40
131.1199493	1.57
133.1123810	3.12
135.1210938	2.52
136.9828491	1.14
139.0933838	0.35
140.9849243	1.87
142.1401367	2.65
143.0957336	1.60
144.0327911	0.31
145.0618744	3.83
147.0885315	5.30
149.0435638	3.23
151.0613251	1.73
151.8990021	0.12
153.2117615	0.41
154.0326233	0.65
155.0645599	1.80
156.0296783	0.49
157.0396729	4.69
157.7575226	0.65
159.1294708	8.40
161.0814819	4.21
163.0858612	3.64
165.0950623	1.05
166.7291870	1.27
168.3756714	0.66
169.1336975	3.59
170.1545105	0.56
171.1224976	7.71
172.1804047	0.27
173.0599060	8.60
175.1565857	4.25
177.1374207	2.03
179.0875854	1.14
181.1099701	1.66
182.3597412	0.59
183.1417847	8.59
185.1129456	8.31
186.0802307	0.06
187.0951080	5.80
189.1782074	4.73
191.1564026	1.82
192.3280182	1.08
193.2560272	2.07
195.1493683	6.79
197.0500793	6.69
198.0982361	0.11
199.1477051	9.30
201.1282654	9.81
203.1405029	5.78
205.1247864	7.11
207.1049194	1.51
209.1895752	5.37
211.0715637	6.47
212.1328735	0.08
213.1452026	9.77
215.1455536	11.23
217.0969543	4.77
219.3194580	0.42
220.0399475	0.39
221.0687561	4.04
223.0944519	6.68
225.1671448	3.59
227.2467346	8.12
229.2388000	7.06
231.2393036	3.23
233.0044861	0.62
235.1786499	4.76
237.2344666	9.06
238.1554260	0.21
239.2095642	6.13
241.1770630	26.43
243.2090759	4.57
245.1403809	0.85
247.0881958	1.54
248.0876160	0.08
249.2497864	4.96
251.1184082	8.39
253.2568665	11.62
255.2638550	9.60
257.2380676	1.87
259.3518677	1.14
261.0411987	1.67
263.1989441	5.18
265.2958984	10.52
267.1958008	14.75
268.6606140	0.58
269.3060913	10.68
270.2470703	0.12
271.4393616	3.11
273.3006897	0.55
274.2719116	0.09
275.2661743	2.76
277.3171692	5.95
279.2520142	6.90
281.1949463	11.27
283.2614441	10.94
285.3133850	1.50
286.1822510	0.61
287.4349670	0.30
289.1965942	8.50
290.3950195	0.64
291.2238159	5.83
293.2605591	11.39
295.1856079	10.31
296.3569641	0.33
297.1919861	4.14
299.4400940	0.30
303.1345825	3.46
305.3262329	3.99
306.6903076	1.59
307.3093567	31.10
309.2713318	20.65
310.4850159	0.82
311.2822266	5.54
313.2806396	1.02
315.3016968	0.29
316.4426270	0.51
317.3245239	3.58
319.3569641	5.69
321.1905823	13.22
321.8457947	0.11
323.2887573	7.42
323.9225159	0.04
325.2066345	2.82
331.3675537	4.02
333.1519165	3.43
333.7615967	0.04
335.2599487	14.35
336.4707642	0.67
337.3794861	11.84
338.2034912	0.74
339.2316895	1.36
345.4093323	9.62
347.3211670	3.19
348.3542480	0.31
349.3898926	7.21
350.1974487	0.70
351.3127747	3.39
356.4169617	0.61
357.5100708	0.08
359.3311768	6.58
361.4001160	7.09
363.3193359	25.51
364.2462158	0.35
370.0992126	0.06
371.0717468	0.24
372.1822205	0.44
373.3021240	1.19
375.4150391	2.83
376.3695068	1.35
377.4660034	4.77
384.2321167	0.34
386.6705627	0.27
387.8434753	0.46
389.1477051	2.37
390.8058777	5.75
391.4773865	61.60
399.3894958	0.26
401.3598938	100.00
402.3516541	0.21
404.3877563	0.31
409.6319275	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.14
Annotation	Jadomycin A
Peak:m/z	Relative Intensity
120.0407104	0.24
126.8652496	0.96
127.9585876	0.17
130.0937042	0.25
136.1454163	0.17
143.9093933	0.19
148.9510040	0.81
149.9120178	0.23
158.9645996	0.04
161.9770660	0.78
166.2274170	0.06
170.0168762	3.72
170.9454498	0.07
174.9159851	0.19
176.9648132	0.38
179.0036621	0.58
179.8393555	0.22
188.2143555	0.16
195.0792084	0.11
202.0782471	0.05
208.9564209	0.07
219.0588379	0.22
224.0016785	1.23
227.0693512	0.55
230.1176453	0.04
245.3813171	0.14
253.1936035	0.17
255.0736084	1.74
256.1001282	1.06
258.3148193	0.06
260.9039307	0.07
266.2645569	0.10
273.1742554	100.00
275.1931152	0.47
284.2542725	0.28
287.0713501	0.04
289.2582397	0.22
290.7020569	0.23
298.3996582	0.11
299.1168823	1.10
303.0651550	4.62
308.2214355	0.78
309.0276184	0.40
311.4588013	0.09
313.2148743	0.28
316.8404236	0.31
322.1554260	0.24
327.1515503	1.26
330.2253723	0.06
331.0137024	0.28
332.6116028	0.19
342.2916260	0.08
345.3078918	0.94
346.2356262	0.06
357.0654297	0.28
374.1174622	0.24
375.2394409	0.25
378.2644043	0.73
380.2170715	0.60
384.0085144	1.16
385.2417603	0.06
389.4172974	0.08
390.6132202	0.44
391.6625061	0.44
392.3217468	2.30
393.2358398	0.26
396.1293030	0.45
399.3169556	0.27
401.3459167	1.73
402.2549438	10.25
403.4405518	0.16
411.1510620	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.204
Annotation	Quercetin-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside
Peak:m/z	Relative Intensity
231.0148315	0.08
258.9263916	0.07
288.0628662	0.20
303.2408142	0.63
306.0546875	1.27
324.3444214	0.23
327.0412903	0.23
386.9811401	0.11
405.2770386	0.18
433.055542	0.43
442.986145	0.08
451.2732544	0.47
463.2717285	0.25
493.3885498	0.96
547.2136841	0.16
555.0310669	0.15
572.234436	0.21
587.5254517	0.22
647.1164551	0.38
663.1065063	0.36
665.2165527	0.12
691.1624146	0.16
709.8789673	0.53
725.4362183	0.40
732.5856323	0.35
737.3117065	0.31
738.4859009	0.42
751.2301636	0.95
769.1964722	100.00
770.1452026	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
157.8554382	0.03
158.9557190	4.04
160.0160522	0.82
161.0564270	1.96
161.8690186	0.02
174.8032379	0.04
199.0689392	0.49
200.1031647	0.26
201.1331177	0.36
202.1381378	0.10
217.0473938	0.09
218.1326294	0.06
219.1399231	0.36
228.9940338	0.40
229.8362732	0.22
231.0112457	0.80
232.0997620	0.21
245.1810913	0.05
246.1168976	0.04
273.0253906	42.71
274.1011047	23.40
275.0100708	44.57
276.1294556	6.01
327.8806763	0.03
345.9866943	0.27
363.0795898	0.02
387.0037537	28.12
388.1874695	35.31
388.9880066	100.00
390.0453796	24.37
393.1181030	0.12
402.2145691	0.04
406.1022034	0.14
412.8551025	0.03
415.1141052	0.05
418.1531982	0.04
428.9017639	0.15
430.2584534	0.14
437.2553406	0.03
442.0746765	0.10
447.3004456	0.03
456.9709778	0.31
459.0559387	1.24
460.3500061	0.03
474.9971619	0.12
477.1118469	0.07
478.1150818	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.17
Annotation	Loliolide beta-D-glucopyranoside
Peak:m/z	Relative Intensity
105.0365601	0.16
124.8129120	0.26
128.9624939	0.15
132.0392151	0.05
171.1645508	0.10
174.7502441	0.11
175.4203644	0.29
183.9561157	100.00
185.1320648	1.45
186.9603882	0.12
189.1500854	0.50
195.0216370	0.12
195.9716034	0.32
196.9842224	0.08
222.0372009	0.06
222.9835205	0.75
225.7186584	0.06
228.9430542	0.18
230.3329468	0.31
242.0021973	0.15
244.2145996	0.08
261.1915894	0.13
268.9932251	0.40
271.1384888	0.07
283.3018494	0.11
286.2257080	0.72
287.3248901	0.29
288.0059204	0.05
298.0129395	0.23
312.5382690	0.05
313.3348694	0.34
314.1135864	0.20
314.8103638	0.51
318.9818115	0.23
322.2748108	0.18
340.8470764	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.4395
Annotation	Bryostatin 1
Peak:m/z	Relative Intensity
717.1016235	0.92
769.2734375	0.71
805.7289429	2.53
818.6428833	1.17
901.8162842	0.85
903.4490356	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0825
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
119.9509888	0.22
137.0336609	14.41
161.0464783	0.07
162.2207642	0.33
164.1027985	0.21
170.2160950	0.09
201.0870514	0.13
223.3690796	0.15
225.1210938	0.46
229.1446228	0.42
241.0472107	0.22
257.1636963	0.06
281.0878601	0.43
299.0446777	100.00
300.0950317	1.51
301.0767822	1.05
306.9899902	0.30
309.2385254	0.17
309.9872742	0.15
317.0642700	0.16
325.1172485	0.23
326.3311157	0.21
327.3123169	0.59
328.0113831	0.27
329.2533569	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	524.2266
Annotation	Scoparasin A
Peak:m/z	Relative Intensity
152.8641357	0.27
165.0851135	0.06
167.0485229	0.06
171.1040649	0.70
181.0778961	0.16
183.0985718	1.05
193.3204651	0.12
196.1698608	0.32
197.1034393	0.14
201.4076080	0.13
211.1015930	0.48
214.1558685	0.31
216.4573364	0.11
220.0115204	0.07
221.1584778	0.27
223.9480896	0.06
228.1252289	0.06
229.1491089	0.07
233.2884979	0.45
237.2138062	0.18
239.1896515	3.65
240.9747467	0.08
242.0058899	0.19
251.2394409	0.27
253.0723572	0.10
255.1726379	0.15
263.1895447	0.10
269.3508301	0.37
283.1570129	0.06
291.4193115	0.85
304.2825928	0.10
306.1740723	0.10
309.5511475	0.03
316.5007935	0.16
327.3120117	29.44
341.2250366	0.06
344.3505859	0.07
351.3615112	0.19
358.3190308	0.07
359.6230469	0.02
361.4191284	7.10
362.3889160	0.46
368.1386108	0.03
373.3630371	0.17
377.3671265	0.25
381.0153809	0.05
382.4233398	0.05
383.4614258	0.24
388.5747681	0.09
395.2388306	0.30
396.2873535	0.07
399.5958862	0.10
401.4593506	0.06
405.2304688	0.11
410.2572021	0.06
417.4229126	0.04
420.2518921	0.22
428.3561401	0.07
430.3098755	0.07
431.0366211	0.14
437.4188843	0.36
438.2340088	0.27
440.0199585	0.12
446.4311523	0.24
450.2913208	0.26
451.6787109	0.04
461.2282104	0.30
464.2312622	100.00
465.3386230	0.80
470.5924683	0.23
477.3932495	0.75
478.4035645	0.73
479.4768677	0.11
480.4443970	0.25
481.8552856	0.33
488.4382324	0.07
493.3806152	0.07
496.4066772	0.23
504.5763550	0.31
506.3097534	0.71
525.3588257	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2136
Annotation	Jasminoside I
Peak:m/z	Relative Intensity
142.8947449	0.28
148.9787903	1.95
160.8329926	0.44
167.2043762	0.17
169.2294922	0.09
170.0622253	0.14
172.3759918	0.19
180.0169373	0.37
184.9985352	0.10
188.1410065	0.14
191.0997009	0.56
195.1335602	0.31
198.1452942	0.58
207.3426361	0.16
209.9528961	0.31
211.1862488	0.12
220.8181000	0.15
223.2717590	0.07
239.3635254	0.08
241.2095947	2.76
249.3465118	0.12
250.2772064	0.06
260.9667664	0.19
262.0872192	0.09
263.0725708	0.43
267.1834412	0.51
274.9838257	0.08
276.3216858	0.29
277.2196045	0.06
278.2272949	0.15
279.9046021	0.10
281.1516113	0.40
282.0933228	0.09
285.2488098	1.16
287.0606689	0.13
291.3812256	0.68
292.7746277	0.16
293.3933411	0.61
304.2669067	0.20
306.0783386	0.39
307.8209229	0.45
309.6053467	0.50
310.6170654	0.31
311.2525330	1.42
312.4299316	0.28
313.3424988	0.56
323.3489990	0.44
325.3681335	0.05
327.2152710	0.63
328.2141113	0.70
329.1937561	8.76
335.5152588	0.18
343.3384399	0.30
345.3300171	0.15
347.1692505	0.08
352.4107056	0.25
357.9411316	0.15
371.2780457	1.07
380.9110107	0.32
383.5979309	0.20
390.2975769	0.45
391.3442078	0.22
392.6464539	0.13
395.3512268	1.29
397.4838562	0.09
403.3019104	0.06
408.9846497	0.15
411.1792297	0.21
413.0261230	0.07
416.2112122	0.44
417.0990295	0.53
419.2658691	0.12
426.4615173	0.11
429.5101624	0.13
431.4033203	0.84
435.9800110	0.11
445.2969971	100.00
446.0757446	0.22
447.4399109	0.57
449.5044861	0.05
453.3087158	0.15
454.5054321	0.20
455.4560547	0.17
461.4862671	0.21
463.5736389	0.45
469.9503784	1.62
470.9212952	0.24
471.5504456	0.09
472.3485718	0.50
473.2158813	1.50
474.8809509	0.41
492.2344666	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8493652	5.14
207.8932648	0.66
208.7910614	2.40
232.1618805	0.09
251.2637482	0.15
290.8413696	15.50
292.7743530	32.76
293.4190063	0.07
294.3807983	0.75
352.0577393	0.10
370.7044067	1.33
371.3215942	0.71
374.7014160	3.86
376.1851807	3.93
376.8967285	10.37
388.8233643	6.05
392.8925781	0.50
417.3473511	0.24
431.0858154	0.23
446.8286743	0.49
456.2971191	0.20
458.6815186	17.63
460.6140747	100.00
498.7086182	0.16
502.5850220	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	646.67
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7142029	0.15
253.3191223	0.11
337.5197754	0.09
352.9734497	0.22
368.6781006	0.04
370.9809570	0.05
477.6891479	0.37
482.0487061	0.03
488.9029541	0.30
499.6697998	0.21
528.7485962	0.09
542.9467163	0.29
544.9616089	1.02
560.7990112	11.96
562.6978149	100.00
580.8251953	0.61
583.0180054	0.20
584.6393433	0.06
585.9016724	0.17
586.9149780	0.47
598.8209229	0.14
600.7155151	5.68
603.0168457	0.75
603.9197388	0.34
604.8556519	0.85
618.6608276	0.14
619.8250122	0.15
622.8124390	2.22
623.7778931	3.42
628.3176270	0.73
628.9213867	1.08
647.6122437	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3876
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
231.1430054	2.82
619.5405884	8.97
633.5780029	7.96
785.7230835	10.68
803.3633423	100.00
804.0628052	15.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603.2824
Annotation	Irinotecan carboxylate
Peak:m/z	Relative Intensity
192.1894684	0.06
197.2962799	0.07
215.1138611	0.04
217.0057068	0.06
240.9192810	0.02
253.2214813	0.40
261.2084961	0.17
265.2397461	0.34
266.2757568	0.07
281.0945435	1.39
282.1903687	0.08
285.2368774	0.10
295.1645508	0.04
302.1019287	0.16
303.2617188	0.41
309.2542725	0.03
319.5251770	0.19
320.3664551	0.20
374.2467651	0.22
376.3703003	0.08
386.2907104	0.08
402.2880249	2.34
405.6729126	0.16
406.4179077	0.13
411.3307495	0.24
418.4279175	0.97
419.4811401	0.02
426.4584351	0.07
428.4400024	0.55
434.3714600	6.24
436.2595825	0.04
441.5064087	0.10
446.3073120	100.00
447.4365234	1.12
452.3281250	0.07
453.5316772	0.07
471.3226318	0.20
483.0757446	0.03
483.7520142	0.09
499.4557495	0.11
508.6262817	0.23
512.3017578	0.12
513.3161011	0.35
515.3950806	0.12
517.2956543	0.13
523.5551758	0.18
540.5231323	0.12
541.4802246	0.11
543.3903198	54.85
544.0042725	0.12
557.5725098	0.20
559.3393555	0.40
560.5631714	0.12
567.4758911	0.53
574.6161499	0.06
575.7700806	0.03
583.3589478	0.33
585.4363403	74.86
603.4275513	1.05
604.1162720	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	7-Hydroxy-6-methyl-8-ribityl lumazine
Peak:m/z	Relative Intensity
95.0477295	0.02
97.2734375	0.03
98.8190384	0.32
100.9073105	0.47
102.8584824	0.04
108.1296692	0.02
110.8892136	0.53
112.9410629	1.07
113.9147415	0.18
114.9778748	1.65
116.9433289	0.05
118.9141541	0.02
122.9994431	0.02
124.9975433	0.06
127.0167542	0.88
128.9046021	0.73
130.9532318	0.22
138.9068604	0.29
141.0688019	0.23
143.1483612	0.10
145.0315857	0.03
149.0890503	0.10
153.0966949	0.07
155.0245056	0.03
155.9256897	0.04
157.0086365	2.16
159.0489807	0.15
160.8356323	0.14
169.0336761	1.49
170.7569275	0.03
172.8628845	0.09
173.9585114	1.16
175.0376129	1.05
178.8816528	0.04
181.2135620	0.05
201.1092834	0.08
207.1741791	0.07
209.1393433	0.02
215.1051636	0.02
219.1223755	0.05
221.1238403	0.07
229.1315002	0.05
233.0895081	0.06
235.2717285	0.04
236.7639160	0.09
238.9347534	0.13
251.2437744	0.07
259.1513672	0.17
277.0919800	100.00
278.1926270	0.11
289.2834167	0.05
291.1945496	0.08
304.9362488	0.05
319.0316162	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.2667
Annotation	12-Ethyl-8-propylbacteriochlorophyllide d
Peak:m/z	Relative Intensity
223.3979187	0.10
237.1370850	0.08
240.0478210	0.10
240.9775391	0.33
242.3780365	0.37
251.2126770	1.00
251.9912109	0.43
253.2375031	1.17
256.9757690	0.11
259.2980957	0.59
279.1693726	0.51
281.0498657	0.70
283.3322754	0.22
289.3332520	0.14
295.1854248	0.10
297.2835693	0.11
301.0844727	0.51
309.3421021	0.14
314.8265381	0.20
319.2119141	2.11
323.5214539	0.40
325.0546570	0.13
328.4564209	0.13
333.3283691	0.20
346.3779297	0.39
348.2194824	4.01
349.3428345	0.57
360.2934570	1.42
371.0034180	0.12
372.2885742	1.26
374.2003174	0.09
384.2877808	0.49
386.4689331	0.87
388.2676392	0.23
389.3727417	0.05
390.2489014	2.21
398.4014282	0.14
400.3301392	44.43
401.2945557	16.22
402.4014893	20.65
404.2086182	0.48
418.2978516	0.20
426.4096680	0.20
428.3748169	0.16
430.2043457	0.07
437.5740356	0.07
438.3684082	0.44
439.4395142	0.47
444.2431641	19.10
445.3037109	9.99
446.4484253	30.02
451.1903687	0.07
452.1953125	0.86
457.3117065	0.09
461.3992920	0.34
464.0957031	0.20
469.5590210	0.50
472.4546509	0.08
477.3768311	0.07
478.3927002	0.13
480.3839722	0.16
481.4211426	0.13
482.1932983	0.19
487.2092285	0.07
493.3370361	0.21
495.3743286	4.14
497.3316040	100.00
498.0459595	0.40
502.5478516	0.24
505.7129517	0.06
509.3142090	3.13
511.4291382	1.03
515.5623779	0.09
521.3585815	10.59
524.2441406	0.07
528.1588135	0.40
529.5405884	0.16
532.8779907	0.13
539.3389282	87.10
540.0239868	0.25
541.4118042	66.42
550.5092163	1.45
554.2804565	0.27
555.2930298	0.37
557.3794556	40.83
565.4141846	0.77
573.3078003	0.11
579.9919434	0.56
583.4204712	42.68
586.1073608	0.11
601.3543091	13.36
602.5921021	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.2534
Annotation	Ligurobustoside A
Peak:m/z	Relative Intensity
133.7854767	0.13
136.0311127	0.58
141.2080688	0.44
145.0864868	0.07
153.2354279	0.32
155.1417694	0.60
156.6996765	0.46
159.0370941	0.13
159.9544983	0.28
161.0159302	0.22
164.9947205	0.53
167.3796692	0.16
168.1507263	0.21
168.9470215	0.78
170.9621277	0.84
174.5449677	0.49
177.3036499	0.36
179.1455383	1.23
180.0432739	1.61
181.9881439	3.54
183.8007202	0.29
187.2420044	0.32
189.0083618	2.54
189.6840210	0.14
193.1492615	0.54
194.7303162	0.08
197.0780640	1.92
200.0621033	0.23
202.1548309	7.36
203.8710327	0.54
206.0449982	0.82
207.0303955	0.25
208.1735535	2.53
209.3594360	1.48
210.1002502	9.42
211.2855988	0.55
212.1334076	0.85
213.1391449	0.67
214.1952515	0.52
215.0491486	0.30
217.0533447	0.09
219.1566772	1.02
220.1770325	0.61
221.0189514	0.16
223.0741272	0.14
225.1243591	7.44
225.9028168	0.06
230.1044312	4.50
231.0168762	5.34
231.9730225	0.37
235.1705627	0.16
236.1942749	0.77
237.1607208	1.07
239.0858154	7.64
239.7097626	0.35
242.0025635	0.56
243.0732117	0.14
248.0875854	56.04
253.2511902	0.19
254.3131104	0.11
255.0424500	0.11
259.2386169	9.78
260.3387756	0.20
261.2377014	0.13
265.0261841	30.60
265.8456726	0.10
267.2091370	0.23
270.2732239	1.13
271.4863892	0.28
276.2123413	0.91
277.2064209	0.90
278.2291565	0.70
278.9741211	0.30
282.2277222	24.06
287.2354126	10.72
288.3970337	0.82
293.5807495	0.49
299.6873474	0.09
305.0927429	100.00
307.3414612	0.11
308.1928101	1.26
310.4019165	0.20
311.3004150	0.48
313.1947021	0.80
315.1452942	1.02
317.0932312	0.68
320.1719055	0.29
322.0148010	15.28
322.6582031	0.25
332.2723999	2.05
333.2789307	0.55
334.1951294	0.12
335.2305298	0.40
343.5479736	3.70
344.3623962	5.86
346.5438538	0.08
348.3135681	0.11
350.1167603	0.57
352.2302856	1.13
354.3743286	0.23
357.3858643	0.27
360.2245483	5.11
361.1037598	0.33
362.3173523	2.05
364.2159729	0.32
365.1818848	0.51
371.3753967	0.21
372.1269226	0.58
373.2239685	1.93
374.0158386	1.50
374.9065247	0.62
378.2973328	6.29
381.2982483	0.37
382.4570312	0.14
389.3626099	1.08
390.2526245	5.90
391.3081970	4.08
399.7657166	1.29
400.4960632	1.61
401.2455750	0.64
402.2602234	0.57
405.2489319	0.43
406.2366028	0.80
410.3956909	0.37
415.0125427	0.29
417.2639465	18.91
418.3324280	54.10
419.2693176	0.93
421.8025818	0.36
426.2262878	0.09
427.6343689	0.97
428.4830017	3.02
432.3625183	0.66
435.3904724	38.07
439.6422424	0.57
440.9481812	0.76
443.6959534	0.07
445.2296143	23.00
446.2880249	22.61
448.4999084	0.28
453.1449890	0.18
454.2596436	3.52
455.3169250	0.09
464.8916321	0.35
472.4093323	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1247
Annotation	(S)-1-[4-[(Aminocarbonyl)imino]-3,4-dihydro-3-methyl-2-oxo-1(2H)-pyrimidinyl]-6-[(2-amino-3-hydroxy-1-oxopropyl)amino]-1,6-dideoxy-4-thio-L-glycero-alpha-L-ido-heptofuranuronic acid
Peak:m/z	Relative Intensity
133.8830261	0.14
136.8131561	0.10
144.9822083	4.28
146.1755066	0.34
147.0529022	0.16
151.9494934	0.77
156.9923553	0.33
157.8674164	0.07
158.8917542	0.10
161.0914001	0.17
161.8844299	0.35
162.9998474	1.61
165.1317749	0.14
167.0849609	4.04
174.9439392	0.21
181.1284180	0.06
187.1103516	1.42
191.2211914	0.31
192.8206177	0.56
193.5098877	0.14
196.9355469	0.09
202.1588745	0.05
203.1062012	0.68
205.1762695	0.61
207.1112671	0.37
209.1649780	3.66
211.0985718	0.08
213.2817078	0.07
216.7541809	0.05
217.9338531	0.09
219.0777893	1.18
221.2818604	0.05
222.7973022	0.05
229.1158752	0.08
233.1257477	0.04
235.2816620	0.17
245.1374207	0.19
247.1243896	1.49
249.0603638	1.00
250.1879883	0.06
251.2834473	0.45
253.2327881	0.10
254.0402527	0.21
259.0983582	0.08
263.3956909	0.10
265.2583008	0.06
267.1642761	7.82
269.0743408	0.06
272.3448181	0.04
279.1352539	0.09
281.1901550	0.21
287.2531738	0.10
289.0867615	0.29
294.3461914	0.23
295.3317871	0.03
299.1574707	0.10
307.1798401	100.00
309.2142944	0.39
312.0551147	0.08
313.2232971	2.00
315.1680908	0.06
323.0357056	0.20
323.8041382	0.06
331.0678101	0.29
337.2478027	0.14
339.0639038	0.33
347.3997498	0.06
354.2242126	0.18
358.1617432	0.11
369.2231140	0.13
377.1862488	0.04
386.5254517	0.17
411.3147278	0.10
413.4094849	0.05
415.3965759	0.07
421.4350586	0.07
422.3183899	0.05
423.3833313	0.05
427.2146912	0.21
428.7948608	1.59
429.4304504	1.30
431.4039612	0.41
432.3917847	0.14
439.2149963	0.03
446.4501038	0.04
447.4939880	0.15
455.2595825	0.07
456.2049866	0.30
457.3837891	0.30
475.8044128	0.04
476.5130005	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.1693
Annotation	Erlangerin A
Peak:m/z	Relative Intensity
173.0277252	0.65
199.2789001	0.72
204.9605103	3.44
221.0003204	3.04
249.0858612	8.06
251.0431671	11.97
252.9581909	3.49
261.1323242	0.53
262.1827393	2.03
263.0292358	7.11
265.2806396	1.21
275.2723999	18.90
281.2268066	1.98
287.2050781	4.79
293.1877441	3.52
305.2743225	1.84
317.2124634	20.45
330.9945068	1.77
345.8933105	3.95
352.3555908	1.74
355.8951416	1.35
359.2754517	18.12
368.2949219	1.28
371.3191528	12.12
375.5075073	2.59
377.1940918	0.79
387.3239746	1.70
389.1824341	1.04
391.0016479	2.01
395.0686035	1.90
420.0803833	0.58
425.4404297	2.93
445.3032837	10.01
463.3294678	10.20
465.4189453	3.39
467.6909180	1.59
474.6491699	1.64
481.2282104	3.35
484.4379883	1.67
499.2356567	100.00
511.2529297	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.01
Annotation	Unknow
Peak:m/z	Relative Intensity
267.8264771	17.55
326.0341797	3.67
330.1680298	0.55
336.2326050	0.79
380.9483643	3.18
382.1102905	2.40
400.0129395	1.11
428.0050049	67.05
446.0718384	100.00
507.9800415	14.34
525.7961426	85.34
526.5933228	8.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3225
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
166.0398712	0.12
181.2957001	0.07
184.0635681	39.48
186.9926147	0.05
214.9993896	0.28
255.0703583	0.09
258.1259155	1.26
277.2724609	0.04
296.2929688	0.08
328.0282593	0.04
335.2206421	0.12
365.6235962	0.08
391.6066284	0.05
396.9870605	0.05
397.7102051	0.36
407.2716064	0.05
413.9215698	0.04
441.2949219	0.61
444.8300781	0.08
457.3842163	0.09
459.8008423	0.28
461.7551270	0.07
472.3859253	0.23
482.4786987	0.05
500.4083862	100.00
501.2633667	0.06
509.0410156	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.1648
Annotation	Ugonin P
Peak:m/z	Relative Intensity
128.1513519	0.21
129.9552612	0.15
146.0736542	0.76
147.0566101	0.25
169.0971527	0.02
173.1774902	0.02
178.8576965	0.12
183.2577515	0.05
188.2500305	0.03
189.0956879	0.03
199.2615204	0.05
203.2862244	0.02
217.1333160	1.81
218.0428619	0.03
229.0713806	0.02
237.9017639	0.06
243.2541809	0.03
257.2354431	0.04
259.2278137	0.37
261.0800781	0.05
272.1668091	0.03
277.1504517	100.00
277.8306885	0.07
291.3031921	0.09
301.3691101	0.06
316.2290649	0.05
317.1882935	0.06
319.2254028	1.66
331.9578247	0.05
333.2997742	0.11
336.9481812	0.10
343.2371216	0.06
345.1346130	0.04
346.3031616	0.03
359.1996460	0.13
361.3038635	0.07
374.0679932	0.11
375.2764282	0.15
376.2883911	0.04
377.4145203	0.62
378.6415405	0.05
379.6257019	0.04
390.1217957	0.05
391.4332886	0.04
403.0240784	0.12
406.0141907	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1719
Annotation	Folinic acid
Peak:m/z	Relative Intensity
136.9266052	0.13
146.9948425	0.09
148.9587708	0.16
157.0823822	0.12
161.9669952	0.22
163.1029663	0.08
165.0232849	0.08
167.0493774	0.26
176.9642181	0.10
178.1516724	0.05
179.0515747	0.63
181.0957947	0.64
184.2250671	0.12
189.4868164	0.29
197.2998657	0.11
204.2481995	0.16
213.0984497	3.36
214.4506836	0.20
227.1909485	0.05
233.3540192	0.06
234.3458557	0.04
241.068573	0.16
244.2866821	0.06
245.0144958	0.35
261.1347351	0.47
273.0457153	0.31
275.5018311	0.13
280.9371033	0.13
283.1019592	0.06
285.1785889	0.18
295.3027954	0.11
295.962616	0.04
301.348175	0.20
302.2004395	0.23
308.2798462	0.32
309.1387329	0.18
310.1652527	0.90
311.165802	0.21
323.1626892	0.08
325.9837036	0.19
327.1096191	100.00
328.0916443	0.51
330.1733704	0.06
339.4534607	0.10
342.2677002	0.11
345.2034302	19.15
357.0679932	0.04
358.1515198	0.10
359.2456055	0.31
362.277771	0.10
366.4792786	0.39
370.9492188	0.07
377.257019	0.09
381.245697	0.08
382.8050537	0.47
383.7536926	0.18
384.9078064	0.56
401.4404907	0.57
404.1964417	0.03
409.6954651	0.20
411.0816956	0.37
412.4405823	0.51
413.3963318	0.08
414.2857971	0.09
420.1230164	0.19
420.8085632	0.50
422.9134216	0.22
427.6081238	0.31
428.2633362	1.11
430.3423157	0.93
430.9506226	0.04
438.2893982	0.20
441.7540894	0.26
446.0883179	0.07
447.3839722	0.06
456.1802673	12.70
456.8900757	0.26
457.9109192	0.26
464.4467468	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	842.46
Annotation	Unknow
Peak:m/z	Relative Intensity
235.9945068	0.15
241.5835876	0.05
307.5780640	0.19
312.2877808	0.09
325.2269897	0.09
357.7567749	0.04
375.5538330	0.07
386.2243042	0.06
400.2836914	0.43
401.2634277	0.05
402.5458984	0.16
414.9575806	0.06
417.9896851	0.17
420.5282593	0.48
434.3810425	0.06
444.4441528	0.22
445.4581909	0.22
446.4931030	0.22
447.3535767	0.25
457.6213989	0.04
473.5297241	0.09
476.2041626	0.23
477.6130981	1.13
478.5567017	0.29
479.2465820	0.19
488.2202759	0.24
497.4185181	0.11
498.3885498	0.27
499.3354492	0.11
504.3103638	0.08
524.4578857	0.21
525.5219116	0.05
529.3308716	0.16
541.4318848	1.57
542.4134521	3.19
543.4697876	3.90
544.5789185	0.55
545.5446777	0.05
546.2495728	0.16
555.4041748	0.07
557.4084473	0.21
558.5365601	0.52
559.5468140	0.30
565.7034302	0.05
566.4733276	0.06
567.5006714	0.25
568.4151001	0.88
569.4374390	0.55
572.2704468	0.18
573.3865356	1.26
574.3215942	2.92
575.3276978	6.03
576.3821411	0.81
583.3905029	1.93
584.4944458	1.80
585.3706665	3.01
586.4604492	1.32
587.4366455	0.60
590.1704102	0.09
597.2591553	0.17
600.7012329	0.75
601.4094849	5.76
602.4444580	13.10
603.4028931	25.00
604.4794312	2.41
608.6367188	0.21
609.5553589	0.13
610.6414795	0.03
611.3049927	0.16
615.3771362	1.26
616.3778687	1.14
617.3693237	4.43
618.5577393	2.17
619.3370361	5.61
620.3287354	0.06
625.7022095	0.05
627.4750366	0.47
628.4299316	0.38
629.3065796	2.61
633.2498169	3.67
634.4102783	7.14
635.3499146	21.18
636.3814697	1.03
640.5020752	0.28
643.5278931	0.04
645.0393677	0.42
646.2512207	1.72
647.3875732	7.15
648.3721313	0.75
651.1075439	0.33
652.2445679	0.93
653.3831177	0.05
659.7009888	0.62
660.4415894	0.50
661.3828125	3.85
677.3505249	0.83
678.4537964	4.33
679.3544922	15.81
680.4467163	0.82
683.3431396	0.23
684.3532715	0.37
685.3206177	0.21
687.3228149	0.11
689.0718384	0.06
703.2183838	0.36
705.4763794	0.05
712.7552490	0.12
720.0462646	0.20
721.1104736	0.27
722.0098267	0.35
744.6151733	0.22
746.8499756	0.58
747.6276245	1.40
749.3475342	14.14
750.3267212	0.69
755.7825928	0.11
764.1958008	0.43
765.4219971	0.07
773.8606567	0.23
775.4773560	0.13
777.4985352	0.61
779.0764160	1.70
779.7979736	1.49
781.2959595	38.88
782.4221802	1.36
789.5094604	0.14
791.4231567	6.82
792.6601562	0.15
795.2919312	3.43
796.0946045	0.28
797.3448486	0.21
799.6935425	1.36
805.3364258	0.05
807.3701172	1.11
809.3547363	100.00
810.4942017	3.88
811.4210815	0.26
821.5380859	1.45
823.3891602	12.39
824.3350830	0.14
842.3579102	87.45
843.1392212	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	455.08
Annotation	Bismurrayaquinone A
Peak:m/z	Relative Intensity
131.9914551	0.02
141.1971588	0.02
144.7839203	0.01
167.2380676	0.03
173.0555725	0.06
174.1877289	0.18
176.1163788	0.06
179.2528687	0.02
184.9385681	0.03
193.2996216	0.01
193.9416809	0.03
194.9951172	0.08
234.9993286	0.04
246.9685364	0.02
253.0666809	0.06
259.0515747	0.76
260.0583801	0.04
261.1167297	0.19
267.9644470	0.03
269.2160339	0.02
271.0420227	0.13
272.1165161	0.83
274.0969543	0.02
278.9263916	0.04
279.6374817	0.04
280.2440186	0.06
286.9541626	0.04
291.3124084	0.02
293.0779419	0.04
305.2012024	0.08
308.4072876	0.20
309.1007080	0.75
315.0578613	0.03
318.2545776	0.01
319.0389099	0.23
321.1022034	0.03
322.0465698	0.07
326.0918884	0.14
327.2690430	0.23
335.2317200	0.10
339.1056519	0.08
343.2818909	0.16
357.1922607	100.00
358.4224548	0.07
365.0845642	0.26
365.9787598	0.28
366.9223328	0.21
379.1758728	0.25
380.1217346	0.02
381.2662659	0.03
382.0619507	0.02
383.1023865	0.14
392.1872864	0.04
393.2685547	0.01
393.9193420	0.02
395.1675720	0.04
395.9651794	0.08
416.0260620	0.13
416.9751892	0.42
417.8406677	0.02
419.0768127	0.27
436.1506653	0.08
437.0563965	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	881.4523
Annotation	Unknow
Peak:m/z	Relative Intensity
313.5690613	0.05
435.2107544	0.04
459.5984497	0.03
522.5316772	0.01
598.5303955	0.04
600.9492798	0.01
616.7709351	0.02
624.2499390	0.02
629.6024170	0.03
630.5612183	0.01
676.5305786	0.06
678.5164185	0.02
688.4601440	0.02
700.7035522	0.01
706.5759888	0.02
720.6705322	0.02
727.1213379	0.04
730.8029785	0.01
732.7365112	0.02
742.5585327	0.09
747.8847656	0.07
748.7324829	0.02
759.5535889	0.02
777.7835083	1.67
778.5884399	12.45
780.9014282	0.01
795.6900635	0.88
796.6122437	7.50
798.8632202	0.01
820.2651367	0.08
828.8550415	0.06
832.6826782	0.02
838.4564819	100.00
839.2738647	0.22
840.7257690	0.08
850.4170532	0.09
862.5902710	0.02
882.2415161	1.63
883.4616089	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1043.7019
Annotation	Unknow
Peak:m/z	Relative Intensity
515.6274414	0.02
955.0885010	0.27
982.2719727	0.10
989.1856689	0.12
989.8969727	0.04
991.4256592	0.18
996.0688477	0.08
1004.3361820	0.18
1006.1907960	0.54
1009.3100590	0.25
1013.1759030	0.20
1015.6785890	0.21
1019.8378910	0.11
1023.4827880	0.09
1030.6179200	0.30
1044.3907470	100.00
1045.2727050	2.67
1046.3447270	1.06
1047.4831540	0.28
1048.3924560	0.09
1049.7324220	0.26
1050.5273440	0.04
1051.8840330	0.11
1053.9071040	0.05
1054.7039790	0.03
1055.6347660	0.11
1056.3394780	0.10
1058.4145510	0.05
1086.5347900	0.14
1097.9230960	0.10
1133.5534670	0.05
1171.4062500	0.20
1216.9357910	0.02
1228.9118650	0.13
1232.1682130	0.03
1243.8288570	0.12
1257.8396000	0.21
1261.7581790	0.12
1274.3000490	0.15
1275.6248780	0.17
1280.5488280	0.38
1284.3302000	0.05
1286.4635010	0.42
1294.4394530	0.05
1295.1440430	0.04
1301.8338620	0.21
1302.4477540	0.36
1306.8958740	0.13
1309.5748290	0.88
1310.5185550	0.02
1312.8723140	0.30
1315.7110600	1.34
1316.4859620	0.25
1321.6330570	3.04
1324.1829830	0.20
1325.3559570	0.22
1327.8465580	0.04
1328.7756350	0.02
1330.4088130	0.01
1331.1177980	0.06
1332.4686280	0.11
1336.3048100	0.16
1338.8469240	0.28
1345.1101070	0.10
1347.3289790	0.25
1350.2846680	0.13
1352.5280760	0.03
1353.4371340	0.39
1355.4272460	0.10
1356.7393800	0.52
1357.4295650	0.05
1359.3013920	0.88
1362.8879390	0.11
1377.6496580	0.03
1441.6134030	0.09
1458.8342290	0.01
1486.9298100	0.04
1515.5344240	0.09
1519.3870850	0.01
1534.6473390	0.14
1543.6422120	0.22
1545.9577640	0.01
1547.3825680	0.06
1554.1776120	0.02
1560.8845210	0.03
1569.7237550	0.06
1596.4078370	0.01
1653.9442140	0.10
1667.9205320	0.04
1695.6706540	0.03
1707.8319090	0.09
1723.6136470	0.21
1730.1380620	0.03
1731.5402830	0.09
1732.6525880	0.03
1761.8381350	0.05
1767.0543210	0.03
1791.0072020	0.08
1792.5010990	0.03
1796.2313230	0.02
1860.2897950	0.15
1863.9290770	0.04
1884.8348390	0.11
1886.1854250	0.08
1895.8948970	0.06
1907.1604000	0.01
1913.5197750	0.32
1948.6488040	0.08
1970.8524170	0.14
1998.0123290	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0826
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
102.9434509	0.56
129.9263000	100.00
130.9672394	4.76
132.0611267	0.09
143.9881287	0.04
145.0571899	0.24
149.1443787	0.08
155.0252686	0.19
161.8638916	0.70
169.2251129	0.28
176.9973755	0.53
179.0923462	4.28
182.7805634	0.09
184.7913818	0.37
191.1038971	0.12
199.0569153	0.08
209.0497437	1.01
211.0036011	1.04
215.0868530	0.36
219.4665222	0.83
224.3504333	0.13
231.0177917	1.62
233.3909912	0.52
234.2685547	0.49
235.1688232	1.91
238.0462341	0.68
242.5592957	23.02
243.1925354	7.13
244.6420288	0.63
245.7121887	0.25
246.7739563	1.55
252.1248474	0.52
256.0099487	0.63
257.1851196	0.62
260.5459595	2.09
261.2745972	2.07
264.2787170	0.18
265.2071533	0.28
267.0588379	0.61
269.6518555	42.25
271.0176086	0.78
271.8244324	0.21
275.6974487	57.03
276.6087646	1.90
278.7404175	0.24
288.2098999	0.25
289.1519165	1.11
290.2213440	1.60
298.6862488	92.38
299.6995850	2.47
307.9305420	0.76
308.9846191	0.10
322.1728821	0.22
323.1884766	0.07
336.3383484	0.19
338.0607605	0.36
338.8822937	0.16
340.3669739	0.12
355.1296082	93.38
356.1547852	8.31
357.2250671	5.55
364.1750183	1.35
380.4260559	0.08
381.1676941	4.51
382.0585022	0.87
391.2159424	0.14
409.1706848	16.00
409.9685669	1.33
411.2150879	0.66
421.4809875	0.22
466.2448425	2.40
467.3363953	0.99
468.0434265	0.09
476.4173279	0.07
484.1730347	58.28
485.3169861	8.98
486.2987366	2.67
494.2217102	0.09
520.1377563	1.88
538.2854614	15.75
539.2510376	2.77
540.2782593	0.67
551.3471069	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.3928
Annotation	Isonuatigenin 3-[rhamnosyl-(1->2)-glucoside]
Peak:m/z	Relative Intensity
214.5025177	0.24
236.2231140	0.44
251.1993408	0.48
268.8215332	0.12
281.4603271	0.27
309.3427734	0.35
310.2508545	0.17
315.3598022	0.36
321.2053223	0.28
327.0267334	0.20
345.0721130	0.42
378.9028320	0.11
391.4572144	0.48
419.3504639	0.15
422.3366089	0.24
455.0020142	0.19
460.3364868	0.19
470.3087769	1.15
473.4334717	0.23
485.2483521	0.44
496.5072632	0.08
502.3038330	2.48
503.3446655	0.17
504.4116821	0.30
505.4011230	0.22
510.5245361	0.94
516.2178955	0.55
520.4236450	0.26
527.2945557	0.43
528.4085083	1.38
530.1217651	0.33
548.2910156	0.89
581.4735718	0.49
592.0834351	0.52
609.6597900	0.94
610.5588989	0.55
613.3519897	0.43
621.6918335	1.00
623.2540894	0.31
625.3928223	1.06
639.5256348	0.42
641.6398315	1.51
649.4057007	0.17
653.4532471	100.00
654.5778809	0.89
667.3607788	1.17
686.6056519	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1084.0837
Annotation	Unknow
Peak:m/z	Relative Intensity
312.2583008	0.12
509.4924927	0.36
530.2991943	0.19
627.5721436	0.03
745.9584961	0.08
791.5701904	0.11
842.2603760	0.45
873.9046631	0.13
886.1824951	0.16
896.6937256	0.37
948.5902100	0.19
954.5122070	0.22
975.2044678	0.30
980.3015137	0.53
981.4509277	0.29
988.5651855	0.53
990.2805176	0.84
993.0634766	0.19
996.9044189	0.41
999.0705566	1.11
999.7929688	0.10
1001.9010010	0.34
1005.8195800	0.17
1014.2902830	0.28
1022.2586670	0.12
1024.7355960	0.11
1025.5466310	0.29
1026.5587160	0.37
1029.6137700	0.34
1030.2236330	0.11
1031.3040770	0.51
1032.6971440	0.35
1041.3244630	0.74
1054.6843260	0.69
1061.2739260	0.14
1063.6776120	0.39
1064.4509280	0.42
1066.9244380	1.11
1084.6992190	100.00
1086.1827390	1.07
1087.1524660	0.19
1087.8126220	0.04
1088.6225590	0.13
1089.4448240	0.11
1090.9066160	0.16
1092.1718750	0.07
1098.3757320	0.14
1134.8751220	0.17
1155.0330810	0.23
1167.3405760	0.37
1178.2795410	0.45
1212.7193600	0.07
1213.6352540	0.38
1218.2255860	0.14
1230.3526610	0.27
1231.5540770	0.11
1233.3840330	0.18
1240.0954590	0.22
1242.7731930	0.24
1243.8015140	0.26
1278.0197750	0.22
1287.2402340	0.20
1302.3105470	0.12
1305.7595210	0.12
1328.3941650	0.31
1329.8585210	0.06
1351.8952640	0.25
1353.2435300	0.33
1354.8834230	0.17
1362.9979250	0.32
1372.8217770	0.28
1379.8978270	0.16
1383.7894290	0.25
1388.8645020	0.10
1392.5762940	0.04
1396.5866700	0.23
1398.1953120	0.34
1412.4046630	0.36
1423.7310790	0.45
1425.1441650	0.20
1430.6761470	0.22
1432.4530030	0.07
1439.9832760	0.73
1440.7695310	0.07
1446.2623290	0.13
1450.8159180	0.23
1456.9842530	0.20
1461.0220950	0.16
1465.3134770	0.30
1468.3111570	0.05
1472.0039060	0.35
1474.3809810	0.73
1475.6660160	0.17
1479.3143310	0.11
1485.0688480	0.46
1487.0317380	0.13
1489.7760010	0.54
1494.6113280	0.39
1496.2889400	0.47
1496.9881590	0.18
1499.2125240	0.16
1502.7259520	0.09
1507.3028560	0.24
1509.7373050	0.51
1511.7220460	0.25
1517.1375730	0.30
1518.0611570	0.23
1519.6899410	0.38
1535.6806640	1.11
1541.2836910	0.20
1547.9749760	0.55
1551.5858150	0.27
1757.7266850	0.04
1767.0085450	0.03
1777.2410890	0.20
1805.2132570	0.08
1871.8034670	1.18
1878.7336430	1.05
1886.8948970	0.06
1894.1895750	0.10
1913.4407960	0.09
1914.0443120	0.38
1921.4622800	0.03
1934.6262210	2.16
1953.3990480	0.06
1974.9193120	0.18
1982.9395750	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	617.9
Annotation	Unknow
Peak:m/z	Relative Intensity
200.3158417	0.05
217.0346069	0.05
219.1002045	0.05
228.9867249	0.27
230.3432159	0.10
273.0190735	12.06
273.9538574	6.72
275.0071411	9.56
276.0543823	1.71
356.8703613	0.07
373.2373657	0.06
386.9945068	10.78
387.9387207	10.38
388.9426270	23.36
390.0006714	4.69
427.1375122	0.14
459.2369995	0.04
473.9974365	0.06
483.1502075	0.18
499.2048950	0.07
500.9403687	18.17
502.1416016	30.58
502.9512329	100.00
503.9662476	24.23
515.9434204	0.08
527.0592651	0.08
527.9194946	0.16
543.0701294	0.29
561.9293823	0.22
564.9053345	0.11
570.9415894	0.39
572.6773071	0.05
585.0370483	0.31
588.7651367	0.15
600.0177002	0.15
617.9788818	0.04
619.7684326	0.14
624.9191895	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	825.3196
Annotation	Unknow
Peak:m/z	Relative Intensity
241.3467255	0.01
284.9166260	0.04
373.9984131	0.03
400.5750122	0.02
406.4276733	0.17
418.3164062	0.48
419.4826660	0.01
435.7084961	0.04
450.3192749	0.02
461.9678955	0.01
462.5921021	0.05
469.6262207	0.02
498.4591675	0.02
503.6384277	0.06
511.2910156	0.02
513.0236816	0.03
515.4837036	2.63
541.5101318	0.32
557.4749146	1.70
559.3733521	2.92
562.4971924	0.02
575.4986572	11.66
583.5141602	0.08
599.2109375	0.07
601.4424438	2.11
617.6589355	0.07
619.3096924	21.91
620.1177979	0.11
624.4004517	0.49
629.7110596	0.05
631.4066162	0.03
635.5481567	0.01
643.2556152	0.08
645.5723877	0.02
659.6477661	0.04
661.0953369	0.12
661.7695923	0.02
663.3046265	0.19
671.6655273	0.01
672.8795166	0.03
691.1900635	0.04
703.2049561	0.05
703.8445435	0.02
721.4487915	19.38
735.6419067	0.04
737.5385132	0.13
743.3994141	0.02
745.5243530	0.03
747.2974854	0.05
763.4525146	6.02
765.2512817	0.11
777.6438599	0.06
781.4021606	100.00
782.2923584	0.60
795.6279907	0.01
800.0333862	0.06
802.0833130	0.04
805.6725464	0.03
807.4386597	2.16
825.2754517	1.02
826.2901001	2.54
827.0136108	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1034
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.0293198	0.56
87.9590607	100.00
93.6731567	0.38
116.1189117	0.21
126.1069031	0.09
146.0377655	12.14
146.8353119	0.31
157.8886719	0.14
172.2050934	0.17
173.9740753	0.47
174.7787018	0.08
181.8629608	0.51
190.0079956	0.10
191.0760803	0.07
199.0680084	0.12
200.0768280	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8589935	3.24
134.2683716	0.03
156.0929413	0.02
173.0557404	0.05
201.2041321	0.01
204.8791199	0.03
206.7766113	100.00
207.5195923	0.01
213.1047363	0.01
223.0480957	0.21
233.0291138	0.01
245.2037354	0.02
273.1952820	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.1825
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0495453	0.05
135.0783234	0.87
137.0512695	0.32
143.0301361	0.03
145.1283722	0.66
149.2594910	0.13
153.1722717	0.07
155.0196838	0.89
157.0764160	0.04
161.2436523	0.05
162.3486633	0.06
163.0437622	1.36
164.1347809	0.07
165.1929474	0.12
171.2405396	0.08
173.1899567	0.08
175.1508942	0.05
175.9564209	0.03
177.0973511	0.15
179.0233765	0.03
180.1614075	0.07
181.1140137	0.38
183.8672028	0.07
189.0692749	0.06
190.0675049	0.23
191.0071106	0.46
193.1564941	0.31
195.6728210	0.04
197.9008484	0.05
201.3383789	0.05
202.3453979	0.08
208.9624329	4.53
209.6137695	0.03
210.8677063	0.46
212.8829956	0.07
214.3709106	0.06
216.0509644	0.38
219.2159119	0.07
220.8097992	0.07
224.1097717	0.16
227.0419617	1.83
229.1779480	5.57
230.0595093	0.05
231.0442963	0.04
234.1750488	0.04
235.0373993	0.03
239.3182068	0.05
241.1027527	0.06
244.9097290	0.12
247.4541931	0.04
252.3302002	1.21
255.1619263	0.09
256.1636353	0.09
257.1439819	0.09
259.2238770	0.10
262.2699890	0.04
265.1119995	0.19
266.3094788	0.06
267.3542175	0.21
270.2628174	0.84
281.3704224	0.23
283.1544189	4.34
284.2737427	0.04
287.3093872	0.07
288.6025696	0.39
291.3723755	0.03
292.2770996	0.19
293.1614990	0.05
295.1082153	0.14
296.4387207	0.03
299.1485291	0.14
301.2468262	37.77
302.6660156	0.02
308.1588440	0.29
309.0692139	0.35
310.6217041	0.32
311.4613037	0.22
312.2283325	0.19
315.0099487	0.44
316.2019043	0.15
318.0068970	0.03
319.2623596	0.06
321.8141479	0.46
325.6852417	0.45
326.3677979	0.75
328.4320679	0.07
330.3617554	0.14
331.2549133	0.05
333.1255493	0.04
334.2813721	1.16
344.4506836	0.15
346.0661011	0.10
350.5700378	0.13
351.7340088	0.22
352.5765381	0.08
356.3570251	0.13
357.0696411	0.17
360.7320862	0.18
361.4935303	0.63
362.3463440	0.17
363.0676270	0.35
363.8889160	0.11
368.2327881	0.15
369.1482544	0.22
375.5624084	0.24
379.4977417	0.10
381.2801819	0.43
382.2613220	0.26
383.0854797	0.42
384.5299377	0.19
385.7986145	0.40
386.9190674	0.10
388.0353699	2.85
388.7016296	0.89
389.4844055	0.16
390.3667297	0.54
392.2548218	0.18
393.5436707	0.13
396.3573914	0.06
397.3043213	0.03
398.3727112	0.27
399.0379333	0.34
399.7114563	0.26
406.1671448	6.75
407.2151794	1.14
411.4719543	0.25
412.5248718	0.06
420.5248108	0.43
424.2680664	100.00
425.2419128	0.14
426.5240479	0.37
427.6407166	0.11
430.6770020	0.36
432.2320862	0.07
434.0712585	0.21
441.3871765	0.10
452.4723206	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1241
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9669571	1.92
86.9786377	0.68
88.9557648	4.30
94.9031677	0.30
99.0430756	0.16
99.8027878	0.06
100.9262924	4.44
104.9514313	0.10
107.9783554	0.04
112.9847794	6.00
114.9578247	1.88
118.9353485	4.84
124.9747696	0.35
127.0959778	1.99
129.0441589	0.91
130.9395905	100.00
142.9480896	2.43
144.9834595	0.18
148.8997192	0.38
155.1404419	0.18
157.1331482	0.09
161.0288391	0.64
162.8889008	0.13
168.0762634	0.12
169.0357971	0.12
172.9742889	5.96
178.9607849	0.73
185.0496674	0.82
190.7599792	0.03
192.1909485	0.03
192.9582214	0.13
195.0551910	0.27
197.0869141	0.11
203.1990967	0.87
220.8751221	0.22
227.0222778	0.53
233.0702209	0.14
235.0010681	0.21
239.2098999	0.45
240.9713135	0.12
246.8838806	0.80
248.1088257	0.13
249.0296936	0.57
254.7800598	0.13
256.9808350	0.25
258.0625916	0.04
263.2162781	0.23
265.2695312	0.18
273.3958435	0.46
275.2148438	1.19
276.9824829	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.18
Annotation	Unknow
Peak:m/z	Relative Intensity
102.9590302	0.04
105.2164001	0.07
110.1095734	0.07
119.9100342	4.93
120.7965393	0.07
124.7339401	0.03
130.9028015	0.08
135.9671936	0.18
137.9675293	0.22
146.9768372	0.07
149.2830505	0.15
160.0727234	0.07
161.1337280	0.16
165.9931641	100.00
180.9916687	0.06
186.8396912	0.06
188.1541901	0.29
195.9285126	0.05
201.6715393	0.51
208.3043518	0.04
210.9866943	0.05
213.2356873	0.02
214.2682800	0.07
223.1531372	0.06
226.0721741	0.08
228.0510864	1.08
229.2543640	0.48
230.1326904	0.08
234.2135315	0.03
238.3543701	0.15
239.1504211	0.07
240.3692627	0.06
241.3846436	0.05
242.2052307	0.05
243.2883606	0.06
246.1752319	0.04
246.9895020	0.09
253.1516113	0.09
254.0006104	0.10
254.7861023	0.04
256.2701416	0.11
257.1541748	0.42
258.9956055	0.37
259.8520508	0.04
263.3363342	0.13
264.2498779	0.04
270.3613281	0.08
271.8042603	0.05
273.1302490	0.03
277.4069824	0.16
281.3026123	1.21
282.0794678	1.10
283.1459045	0.67
285.1055908	0.05
290.8635254	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	628.3102
Annotation	Indaconitine
Peak:m/z	Relative Intensity
177.1048431	0.09
185.0570679	1.94
191.2905121	0.23
194.0297546	0.11
199.2717896	0.14
207.2876587	0.15
209.2015381	16.03
213.1890259	0.32
215.0754089	0.21
219.1968231	0.23
223.0861816	0.74
224.1533508	0.75
226.3244019	0.28
227.2417297	1.11
236.2754211	0.32
238.2465973	0.21
239.3048096	0.04
240.0825195	0.10
241.1237183	3.68
242.0956421	1.33
243.0267334	0.08
245.2440338	0.25
249.2714233	0.06
251.2360992	0.22
252.8793793	0.39
263.2497253	0.19
264.2277527	0.32
266.2023926	0.07
271.4657593	0.07
272.1087036	0.18
283.2723999	0.06
289.3106689	1.56
291.5064697	0.74
293.3670654	0.16
299.3580322	0.12
303.1303101	0.11
307.1949158	18.28
307.8403931	0.11
311.1831360	0.09
321.3200073	0.67
323.1215210	0.07
325.2823486	9.64
327.1947021	1.76
334.8990479	0.06
339.4108887	0.62
342.9016113	0.23
344.1787109	1.51
351.2858887	0.15
352.4807129	0.13
357.0791626	0.10
363.1903076	0.39
367.2197266	1.02
369.3342285	0.08
373.2575073	0.12
379.2854614	0.10
379.9393921	0.32
381.3205566	1.90
395.2514648	0.45
396.1400757	0.18
405.3164062	0.06
407.4141235	0.70
410.2505493	3.15
418.9359741	0.19
421.3115234	0.37
422.2916260	0.27
423.0301514	0.16
436.9601440	0.05
452.3001709	3.03
453.7873535	0.30
461.6922607	0.27
464.3395386	0.87
465.3400879	0.07
466.3705444	0.70
479.2764893	3.16
481.4272461	6.46
482.5283813	0.45
483.2680664	0.08
489.4645996	0.32
490.5870972	0.49
493.5001221	0.42
495.2001343	0.14
497.3685303	19.35
501.6124878	0.59
504.3786621	0.09
505.3015747	1.02
506.2476807	0.20
511.3557739	0.35
514.1808472	0.19
515.4873047	0.42
521.3536377	0.27
523.3108521	0.60
531.4515991	0.30
532.3680420	0.39
540.3047485	0.20
549.1116333	0.09
550.3698120	27.66
552.3975220	0.41
564.4109497	2.87
565.1457520	0.30
566.2624512	0.17
568.3065186	100.00
569.1696167	1.59
571.2815552	0.16
579.2913208	0.12
581.4411011	1.25
582.3056030	6.71
584.2827148	0.17
591.7501831	0.07
609.4503784	1.79
610.3674927	0.55
617.6077271	0.99
628.3173828	7.11
629.4372559	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.0724
Annotation	Tamarixetin 3-glucoside-7-sulfate
Peak:m/z	Relative Intensity
172.0463715	0.12
173.1302795	0.10
184.3397064	0.16
195.2478027	0.14
196.9988403	0.21
199.0958405	0.31
209.3635559	0.09
226.0782166	1.79
228.2234497	0.16
229.1523590	0.31
284.5503540	0.12
289.0833740	0.24
291.2921753	0.19
309.7357788	0.25
316.0139771	0.36
317.3958130	0.25
328.2096558	0.67
332.3472900	0.20
344.2943115	0.84
349.8687134	3.65
358.9309692	0.09
363.6115112	0.28
368.7556152	0.58
373.3570557	0.17
386.9182129	0.22
394.2685547	0.11
397.2319946	0.18
412.2066650	0.32
413.7766724	1.70
414.4117432	0.16
422.4163208	0.13
425.9453125	0.10
427.4503174	0.06
430.2176514	0.07
439.8130493	0.56
444.2977905	0.29
446.1044312	0.31
447.6032104	0.13
454.8137817	0.24
460.2645874	0.14
462.3128662	0.56
463.4507446	0.81
467.1535034	0.60
469.9462280	0.27
472.4715576	0.62
475.4033203	0.08
476.5072021	0.09
478.1029663	0.60
480.7974243	0.61
483.1520386	3.40
483.8187256	0.87
488.6088257	2.82
489.4212036	1.02
491.0922241	0.07
493.5437622	1.14
495.0784302	0.95
495.7229004	0.21
496.4621582	0.43
500.5337524	1.45
506.6979370	1.17
508.9315796	0.66
511.3228760	3.07
514.5462646	0.53
515.3397827	2.83
516.5084839	11.39
517.4365845	7.93
518.3130493	0.89
518.9718628	2.91
519.6373291	3.17
521.9024048	100.00
522.9699707	0.28
524.3888550	3.94
525.1639404	1.97
526.6047974	6.27
527.9229736	3.36
529.7919922	0.24
531.0596313	1.24
531.8015137	0.41
533.1232300	2.33
533.7875366	0.93
535.4259033	1.51
537.1541138	4.20
538.2849731	0.55
538.8923950	1.98
540.1284180	1.54
541.5132446	20.04
543.6420288	0.84
544.2510986	12.03
545.9844360	10.20
546.8820190	0.96
547.6853027	0.29
548.5466309	1.77
549.7772217	0.17
551.1958618	0.09
567.4241333	0.41
571.8721313	0.31
572.6121826	2.49
581.0601196	1.99
582.2615356	0.20
585.2901611	1.25
586.4573364	0.74
590.3889160	0.68
593.1328735	0.67
598.1359253	0.41
602.8173218	0.09
607.9872437	0.20
616.2949829	0.65
620.6901245	1.09
621.4906616	0.88
626.6635742	0.22
632.5123901	0.45
634.5603638	0.42
636.1704712	0.09
640.4007568	0.75
644.0220947	3.37
644.7179565	2.00
645.6512451	0.05
649.4657593	0.17
650.6586914	0.29
651.7223511	0.75
652.4928589	1.17
656.0709229	0.54
660.5848999	0.05
664.3743896	0.59
666.7233276	0.23
670.1261597	1.43
675.3656616	0.92
676.5592041	0.31
681.4669800	1.01
682.5690918	0.17
683.7935791	0.41
684.6475830	0.30
688.1177368	9.64
689.2199097	2.00
689.9189453	1.81
691.0292358	0.15
691.7692261	1.54
693.6019287	1.07
694.9153442	2.86
695.6289673	12.34
696.3969116	1.54
697.2028198	0.09
698.5477295	2.54
699.4115601	1.23
701.3109741	4.75
702.0371094	2.49
705.2922974	1.04
706.6187744	0.12
720.7804565	0.29
725.1050415	0.48
732.3663940	1.11
733.4691772	1.25
739.3721924	0.20
741.0314331	0.38
742.3023071	0.72
748.4144287	0.23
759.3551636	2.70
760.3112793	0.27
793.6873169	0.49
796.7152100	0.52
798.1180420	0.98
803.6268921	0.20
805.5524292	0.09
811.9467163	0.09
823.4660034	0.21
862.0432739	0.26
863.3253784	0.47
905.9123535	0.25
906.6655884	0.12
909.5277710	0.19
915.4011841	0.16
923.9136353	0.71
925.8206177	0.06
935.1269531	0.23
946.9602051	0.38
962.8386841	0.29
976.7758789	0.42
980.5497437	0.45
990.7666016	0.25
1006.9370730	0.19
1014.5563350	0.27
1036.8808590	0.32
1037.8404540	0.21
1038.6032710	0.08
1057.1840820	0.14
1119.0974120	0.18
1143.1154790	0.07
1161.8009030	0.11
1226.7933350	0.15
1278.8602290	0.12
1293.8488770	0.40
1782.4361570	0.05
1805.2691650	44.26
1838.3045650	0.24
1848.6307370	0.82
1872.5941160	0.09
1907.9520260	0.34
1916.1053470	0.08
1955.3981930	0.32
1957.3753660	0.04
1960.7535400	0.06
1966.0827640	0.77
1968.8405760	1.53
1969.5642090	0.11
1970.6037600	0.20
1973.6260990	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1251
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9480438	0.03
159.8649139	0.04
171.1273193	0.05
173.7920837	0.02
176.8532104	0.02
181.0829010	1.02
183.8010559	0.03
184.9660950	0.13
199.1116028	0.52
204.7254639	0.04
208.8454590	0.05
211.0916748	0.43
231.0084076	13.65
232.9547424	0.10
235.3031921	0.15
247.0894928	0.02
251.1498871	0.05
260.9027405	0.13
262.1100464	0.03
262.9804382	1.31
265.0567627	0.35
271.3405151	0.22
277.0101318	0.04
279.3867798	0.02
280.0906372	0.06
282.1279907	0.07
288.2043457	0.49
288.9785461	0.58
306.1199951	16.26
307.9637451	0.03
311.4172974	0.09
313.9976196	0.11
315.8579712	0.04
317.1201782	9.60
321.9846191	0.37
327.5076294	0.02
334.0189209	100.00
334.6731567	0.15
339.9017944	0.02
343.0751343	0.06
348.9039917	0.03
352.0771484	0.04
363.1974487	0.16
363.8516846	0.05
370.9327393	0.06
373.8798828	0.15
378.2055054	0.10
381.1182861	0.24
391.1311646	1.12
392.1933594	0.38
399.5835571	0.08
400.2062988	0.13
405.0088501	0.07
409.0909424	45.88
409.6981812	0.35
413.9737549	0.07
417.0847168	0.17
424.9995117	0.29
435.2714233	0.02
445.0634766	0.73
463.2332153	0.78
465.0068970	0.30
465.6500244	0.25
475.1334839	0.42
491.9032593	0.09
492.5708618	0.12
494.1291504	0.03
496.9938354	0.08
502.1732178	0.08
508.4879150	0.02
518.7655640	0.24
520.1915894	10.00
521.2752075	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	255.0722
Annotation	Galactonolactone
Peak:m/z	Relative Intensity
98.7849197	0.15
110.9336548	0.29
112.9768372	0.08
128.8687439	1.12
141.0096283	0.09
144.9794769	0.04
153.9119720	0.02
158.9383392	10.57
167.2997437	0.06
176.9237823	100.00
199.0417023	0.04
208.7311859	0.22
222.9496613	40.73
223.6048126	0.26
227.2529602	0.14
236.5729218	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	410.013
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0943756	0.15
141.9585114	0.02
161.8579712	0.09
171.3809357	0.05
173.5065613	0.09
177.4956055	0.02
187.1128540	0.07
203.1756592	0.19
203.9729614	0.08
212.0184784	0.20
213.8479156	0.08
214.9288330	0.11
222.0999146	0.14
228.1610413	0.06
231.8661194	0.30
235.9106140	0.04
239.1202393	0.02
246.0201416	0.18
249.9592896	0.26
262.1816406	0.11
264.0655212	2.85
265.2209473	0.06
269.2069092	0.03
270.0848389	0.02
275.9061890	0.31
276.8484497	0.20
277.9021912	0.58
288.0093384	0.09
290.0977783	0.39
292.0780029	29.42
295.7709961	0.19
298.9586182	0.08
300.2555542	0.05
303.7346497	0.34
305.1805115	0.27
305.9730835	0.03
311.0597839	0.08
312.1370850	0.05
315.8781738	0.49
317.9553833	2.15
318.9305725	0.07
320.0398254	0.14
321.0631409	0.25
322.0736389	0.54
323.4011841	0.22
329.8661499	0.05
333.7417603	0.73
335.8297119	1.29
336.4638367	0.19
345.7491455	0.28
353.9903564	5.76
356.1415710	0.20
357.0636902	0.07
362.0090027	0.07
363.9217224	17.31
364.5289917	0.21
368.3564758	0.06
373.3439026	0.12
374.1103821	0.36
375.2850647	0.04
379.9257507	0.14
381.9602356	100.00
382.5889587	0.22
391.3062439	0.59
392.2277527	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	222.06
Annotation	Unknow
Peak:m/z	Relative Intensity
70.0201569	0.12
73.5692215	0.06
83.0138397	0.04
87.9647293	0.09
88.8923187	0.04
89.9550781	0.11
91.6243286	0.04
112.9152222	9.71
115.9597321	0.04
117.8830414	0.16
121.0338593	0.04
121.8033142	0.35
123.0792694	0.23
123.7860107	0.07
124.8564148	0.02
129.7294769	0.56
132.0094147	0.35
134.0767059	0.11
136.7815857	0.04
143.1120758	1.21
147.0084991	0.05
149.9357452	0.06
150.9357910	0.35
152.1662750	0.78
153.0764618	0.12
158.0480957	0.04
160.1829834	0.04
162.0773926	0.06
163.9304962	0.08
164.7520752	0.05
166.0709839	0.03
168.9272308	10.61
174.1091919	0.25
175.6769562	0.51
177.9817505	0.22
179.8685455	0.18
180.8476105	0.37
183.9745636	0.13
186.1977386	12.59
186.8161011	100.00
187.4331818	0.34
192.9066162	0.10
194.1936188	0.03
197.6714783	0.08
198.7896271	0.04
201.7186737	1.12
203.9385223	13.24
204.7126617	16.04
205.3391266	0.07
213.1939850	0.33
221.1154327	0.05
228.0034637	0.05
229.5196533	0.12
230.2803192	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8820953	3.20
206.7614136	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
135.9149017	25.22
147.0280762	0.10
165.0012970	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	258.11
Annotation	Glycerophosphocholine
Peak:m/z	Relative Intensity
85.7852402	0.02
86.9413528	0.02
95.8475037	0.01
103.9380493	100.00
114.2686768	0.02
142.1253357	0.03
161.0832672	0.10
181.1343079	0.02
184.0562897	0.41
198.9696960	0.23
218.2131500	0.10
240.0929565	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.6481
Annotation	Unknow
Peak:m/z	Relative Intensity
83.9009247	2.97
85.0379105	0.26
102.1330795	0.23
111.9825058	1.50
114.8561325	0.08
129.9205933	97.94
131.0037079	5.52
132.0567017	0.25
144.8913574	0.20
146.8439789	0.41
161.9216003	0.30
175.0258331	0.19
176.9696655	8.47
178.0306549	1.68
179.0324097	1.27
181.0278931	0.33
187.1190033	0.07
210.6592407	2.28
211.7744141	1.53
220.7792358	1.00
222.1252441	0.35
224.8644104	1.21
229.0862732	32.79
229.7483826	2.69
230.9958191	4.29
232.4278870	0.30
234.3631287	0.12
235.1722107	0.14
238.7842712	1.42
241.1395264	0.20
242.3079224	0.20
244.7943420	0.60
247.3316040	5.68
248.3792114	0.57
249.1315308	0.87
253.1100159	2.12
253.8914795	0.86
256.2309265	28.49
257.2232971	3.22
259.2269287	0.07
261.2239380	0.69
262.3409729	15.37
263.3253784	2.39
264.0869141	0.14
265.2107544	0.25
266.1489868	0.18
267.2782593	0.60
271.8510437	0.12
276.0513306	3.17
276.7735291	0.90
277.3948975	0.46
278.2818604	1.03
279.2966003	4.27
281.2948608	11.86
282.0638733	1.73
283.3187256	0.06
284.8813171	71.57
285.7926025	9.87
287.1210022	0.09
306.1253052	0.37
308.1733704	9.17
309.0448914	0.16
310.0677795	0.27
311.3042603	63.99
312.3044434	13.54
313.3761597	2.76
314.2979736	0.06
320.0115356	0.48
337.2776184	11.45
338.2013550	1.61
339.2654114	0.17
364.2217102	1.26
365.2179565	0.09
369.3102112	4.87
370.3420410	0.82
371.3497620	0.05
382.2637634	0.59
386.3708496	0.37
394.2577820	0.48
420.3468628	2.31
421.0817261	0.75
430.2230530	0.37
438.9604187	0.67
439.5903625	0.80
440.5708313	0.60
441.2991333	0.09
442.3096313	0.34
447.5728149	0.74
448.2451782	4.76
449.4169006	0.64
450.3312073	0.21
457.2872620	100.00
458.3356323	22.98
459.3687439	3.47
465.2933960	0.20
468.2516174	0.23
476.4395447	0.27
493.3231506	2.44
494.2659607	0.35
498.0887756	0.11
506.2211304	0.06
511.2439880	6.14
512.2595825	1.53
513.2936401	0.45
515.0816040	1.05
517.3966064	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0949
Annotation	Flumioxazin
Peak:m/z	Relative Intensity
101.0889435	0.15
110.9822311	2.47
117.0323181	0.25
128.9746094	17.78
131.9269714	0.76
133.0768890	0.32
135.0578918	0.15
137.8466797	0.04
141.0556641	1.58
158.8963623	26.31
174.8578033	1.25
177.0119324	100.00
179.1312561	0.09
183.2648926	0.05
191.0557098	0.07
211.1840515	0.06
219.1861572	0.23
225.3404236	0.16
237.1250916	0.72
239.3257751	0.03
242.2522888	0.51
252.8366699	0.07
253.8251648	0.06
265.0525513	0.22
282.7611694	0.22
288.9439087	0.22
292.0813599	0.12
294.8518066	0.16
300.1817017	0.04
300.8306274	0.05
309.1662292	1.42
310.1047363	0.07
315.9091797	0.06
324.3830566	0.08
325.5556946	0.14
326.2557373	0.10
327.5195923	0.08
336.4140625	0.64
337.2010193	2.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.15
Annotation	2-(Glutathion-S-yl)-2-methylbut-3-en-1-ol
Peak:m/z	Relative Intensity
120.9047318	0.11
123.0152740	0.02
134.2391357	0.08
140.2012634	0.07
141.2792816	0.09
142.0334625	0.21
143.8340149	0.21
144.8487854	0.11
148.9653625	8.25
149.9481354	1.21
156.1317444	0.04
159.9343262	0.75
161.9776306	0.67
166.9434509	2.47
167.8796692	0.32
171.1560211	0.03
174.8827209	0.12
178.9617615	0.80
187.9858246	0.10
192.8240509	0.12
196.0589600	0.05
201.0746155	0.03
212.0054321	0.03
213.0599060	0.06
227.9049683	0.28
229.2790222	0.07
230.1709290	0.20
232.9997864	0.05
243.0542908	0.05
245.0582886	100.00
246.0702209	0.14
251.0881958	0.04
253.3749695	0.14
253.9776917	0.12
256.2711792	0.04
256.9483337	0.07
260.2663574	0.14
261.0296936	0.08
263.1056213	11.20
266.3712463	0.05
267.0077820	0.17
270.0314941	0.05
271.1543884	0.46
272.0391235	0.02
272.8760376	0.02
279.0171509	2.11
279.8885498	0.18
286.1535034	0.15
289.3594360	0.06
290.3558350	0.08
299.0247803	1.09
306.2728882	0.10
308.1759033	0.92
309.2617798	0.27
314.4556580	0.04
315.3789673	0.04
317.1420593	6.91
320.1522522	0.04
321.7425232	0.23
329.1126099	0.26
332.1127319	0.15
334.4693298	0.32
338.0437622	0.11
346.1482239	0.13
346.8421021	0.06
348.8759766	0.05
351.2796326	0.28
353.8625793	0.03
354.7724609	0.32
356.0005493	0.23
356.7878723	0.27
363.3741150	0.02
365.0407410	0.34
369.9190063	0.23
374.2093201	3.76
375.2035522	0.53
383.2111511	1.08
385.9962769	0.05
401.1023865	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	386.1072
Annotation	Zeanoside C
Peak:m/z	Relative Intensity
114.7100372	0.02
118.9246140	1.83
122.8790131	1.36
132.1359558	0.03
132.8993988	0.07
134.3589172	0.09
135.9774475	7.19
146.9653778	3.03
163.2447052	0.05
165.0055847	18.42
173.0326538	0.22
175.1988220	0.08
182.0774231	100.00
185.3602448	0.10
186.1404266	0.07
203.3818665	0.04
204.9775085	0.16
213.2303314	0.09
224.0562134	0.54
231.0585022	0.05
245.3270264	0.05
250.0379333	0.21
276.9979858	0.05
279.8213501	0.08
282.1091614	0.05
292.1932373	0.02
297.0859985	0.02
312.1364136	0.07
321.2967224	0.07
327.2715149	0.14
333.4049683	0.09
338.1257935	0.08
340.2126465	0.07
341.3810425	0.03
343.9058838	0.07
345.1611023	0.01
348.4208679	0.19
350.2613525	0.18
351.0545959	0.06
364.1536560	0.22
367.9648132	0.54
368.6735535	0.12
369.3021545	0.06
376.3705139	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3858
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
477.1887207	0.93
485.5489502	1.24
509.3242188	4.50
515.5777588	0.85
555.5411987	8.58
630.6054077	0.86
677.5452881	3.16
712.7091675	1.78
714.892334	2.24
742.5321045	1.01
758.3778076	4.77
759.1567993	5.48
802.7138062	25.86
803.3554077	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	468.2348
Annotation	PS(14:1(9Z)/0:0)
Peak:m/z	Relative Intensity
154.1930084	0.05
157.1461487	0.10
162.9780121	0.27
166.2282715	0.08
177.1409302	0.28
183.9712830	40.52
187.2796326	0.28
193.4563904	0.12
211.3817749	0.10
218.9682312	0.15
227.7914734	0.07
256.6875916	0.14
258.2467041	0.41
267.1435547	0.21
271.4557190	0.49
283.0788574	0.21
285.2117004	0.30
287.1633911	0.26
289.1774292	0.07
298.2501221	0.19
311.2707214	0.14
318.3814087	0.10
324.3575439	0.11
327.4653320	0.04
332.4116821	0.11
335.2313843	0.38
343.1443176	0.10
347.1999512	0.14
352.0212097	0.14
355.3116455	0.10
369.0913696	0.14
371.3476868	0.12
373.1225281	0.05
379.2673035	0.04
385.3243103	0.15
387.4933777	0.25
393.3858337	0.22
411.3159790	0.15
413.4858704	1.32
414.2733765	0.85
417.0324402	0.18
423.3153992	0.17
423.9193115	0.31
432.3938293	2.87
438.3504333	0.05
447.6214905	0.21
450.3249817	100.00
451.1109619	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.4022
Annotation	Quadranoside V
Peak:m/z	Relative Intensity
423.4763794	0.09
453.6708374	0.24
469.3639526	1.59
472.7687988	0.27
487.3267212	0.95
488.7219238	0.86
517.1450806	0.47
533.5717773	0.09
542.3855591	0.51
569.1884155	0.11
603.5037231	0.06
620.4216919	0.28
631.3742065	0.29
635.3806152	0.12
647.6761475	0.13
649.5410767	100.00
650.5313110	13.13
667.7951050	0.13
677.7259521	0.64
696.2976074	1.94
696.9185181	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	612.32
Annotation	Oleficin
Peak:m/z	Relative Intensity
193.3169861	0.05
221.3408813	0.04
226.2029419	0.08
227.9122314	0.03
271.5186768	0.12
295.2079468	0.06
301.2345581	0.03
305.2590332	0.05
305.9730835	0.07
315.1186523	0.03
327.3488770	1.10
343.3497925	0.06
344.1564331	0.24
348.1599731	0.09
415.1851196	0.05
432.6182861	0.05
440.7239380	0.06
481.3081055	8.11
482.0302734	0.14
483.4536133	0.04
495.5390015	0.18
496.4288940	0.08
497.6380615	0.05
500.1787109	0.21
507.5910034	0.49
522.4004517	0.14
534.3528442	0.04
538.4456177	0.13
552.3804321	100.00
553.3572998	0.70
564.1327515	0.06
565.5863647	0.46
566.4253540	1.56
568.3283081	0.10
575.3283691	0.08
576.5333252	0.37
581.0829468	0.24
593.3581543	0.40
594.2005005	0.42
612.4403687	0.35
613.4876099	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1664
Annotation	Fibraurinoside
Peak:m/z	Relative Intensity
161.0961609	0.09
161.9930420	0.12
162.8011169	0.24
163.9102173	0.14
176.1390991	0.19
179.0278625	0.48
179.8955383	0.56
181.1039886	0.04
182.0812225	0.04
187.1368713	0.03
191.0959778	2.08
193.3165894	0.04
200.4205933	0.05
203.1124268	0.53
204.2452545	0.17
206.0516357	0.07
216.2847290	0.03
221.2689514	0.11
222.1540222	0.16
223.0162964	1.48
224.1430054	2.63
225.0621948	0.09
226.4888611	0.05
230.0989990	0.07
233.8473053	0.14
235.2028656	0.35
245.0411377	0.08
250.9947968	0.04
252.0523682	0.23
253.1083679	0.10
254.2864685	0.11
257.1883545	0.07
260.9677429	0.26
264.9110718	0.13
266.4224243	0.07
267.1823730	0.17
272.1730347	0.04
277.1798096	0.11
279.1356506	0.06
282.1875000	0.33
283.0627747	0.06
288.2293701	0.08
290.1773682	0.24
294.1638184	1.79
297.0893860	0.07
299.3417969	0.44
306.1863403	0.16
308.1981201	0.34
309.2199707	12.55
320.4542236	0.35
321.3057251	0.38
322.0588989	0.49
323.0439453	0.42
324.1464233	0.05
327.2769775	3.41
328.9313965	0.14
335.2255859	0.24
338.1979980	8.27
341.2214966	55.06
351.1688843	0.27
353.1634521	100.00
355.2045288	0.16
357.2453613	0.16
358.9248047	0.28
365.3007812	2.38
367.3012695	0.29
371.1488037	91.49
371.7531738	0.20
377.3848877	0.09
379.4016113	0.03
383.1602173	0.91
393.3397217	0.17
395.1787720	3.30
397.5095215	0.09
401.6388550	0.06
403.6320190	0.06
407.1697388	0.91
408.3455200	0.14
411.4624634	0.36
413.2044067	0.13
425.4064331	0.08
434.4840698	0.12
436.2210083	0.34
436.9790649	0.03
439.5948486	0.12
443.2394409	0.24
451.6000977	0.20
457.2229004	0.06
467.5065918	0.69
468.2167358	0.50
471.0915527	0.05
472.2321777	0.16
473.3113403	0.54
477.4104004	0.27
487.3000488	1.73
488.3125000	0.04
489.1759644	0.06
497.0153809	0.19
497.6340332	0.16
503.2827759	1.80
509.6499634	0.45
514.2645874	1.82
515.1933594	1.31
535.9634399	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.2855
Annotation	Taxezopidine J
Peak:m/z	Relative Intensity
207.0715332	0.64
249.2364502	0.16
250.0307159	0.81
253.1994019	0.27
327.2761230	0.26
328.3516235	0.34
335.5206299	0.79
339.1378784	0.43
358.1198730	0.80
391.4707031	1.24
407.5374146	0.54
427.5144043	0.57
433.1141968	0.27
445.1983643	0.31
449.4128418	0.57
459.2062378	0.32
471.0366211	0.60
475.1610718	0.23
477.5156250	0.64
478.6077881	0.36
499.5706787	0.54
504.4057617	0.15
509.4157104	0.46
521.5939331	1.86
525.7510376	0.95
531.3145142	2.85
532.2531738	0.72
533.4420166	8.39
535.3636475	1.75
545.5032349	0.53
547.2687988	0.41
550.5039062	0.18
555.6646118	0.38
563.3495483	100.00
564.5385742	15.76
565.2253418	0.68
567.2258911	0.25
569.4798584	0.71
576.5661011	0.21
577.3339233	0.34
578.9182129	0.68
590.3775024	0.26
591.4237671	4.96
592.4043579	2.94
593.4905396	36.25
594.5195312	7.10
595.4224243	1.44
605.3457031	15.17
606.5270386	1.58
607.7103882	0.42
622.9000854	0.36
624.4104614	13.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	419.3303
Annotation	Petrosiacetylene D
Peak:m/z	Relative Intensity
118.9748383	1.23
120.9307098	1.66
123.0610123	1.19
124.9451599	0.28
127.7411652	0.21
129.0416412	2.02
131.0384521	2.33
133.0527954	0.95
135.0324707	2.23
137.0475006	0.18
139.1073151	0.26
142.1126099	1.43
143.0082550	0.92
144.9136658	4.31
147.0781555	2.73
148.9736328	0.96
151.0613708	0.44
153.1351776	0.50
155.1433411	1.00
156.0995331	0.59
157.0932465	5.04
159.1204529	4.19
161.1871948	2.43
163.0564880	1.92
166.5821686	0.76
168.2980652	0.08
169.0576935	2.36
170.1724548	0.18
171.1215973	5.13
173.0054626	7.02
175.0678101	2.21
177.1365662	1.25
179.2518005	0.76
180.9829559	1.15
182.4658051	1.02
183.1819153	6.24
185.1820068	4.79
186.2605896	0.21
187.1350708	4.97
189.0714569	3.62
191.2473450	1.97
192.3297424	0.43
193.0378723	0.50
195.0102234	1.89
196.0501862	0.28
197.1629944	4.21
199.0911102	6.50
201.1265869	9.83
203.0746307	3.80
203.7169037	0.43
205.1848297	2.62
207.3554382	0.87
209.2334900	2.48
211.0894623	4.34
213.1418762	6.76
215.0694580	7.51
217.0796509	3.19
219.3088074	0.08
219.9221497	0.14
221.1018677	1.66
222.1389465	0.13
223.1629333	4.13
225.0918732	5.26
227.1704712	4.88
229.1133270	3.75
231.0521240	2.25
233.1423340	0.47
235.1418457	1.92
237.1473694	5.42
237.7579956	0.05
239.1496887	5.74
241.0938721	5.44
243.1598511	10.84
245.3561401	0.56
247.1825256	1.57
249.1985474	3.11
251.1922302	4.84
251.7982788	0.20
253.1830444	9.34
255.2207947	5.18
257.1479187	3.62
259.1955261	0.99
261.1312561	1.08
263.1929932	4.41
265.1485291	3.07
267.1851501	11.43
269.2278442	5.10
271.2450562	5.16
273.4750671	0.22
275.1454163	2.19
277.3361816	7.31
279.3179626	5.23
281.2424316	11.09
283.3470459	4.44
285.2252808	0.11
289.2084961	1.80
290.1240845	0.09
291.3617859	4.18
293.3086853	5.62
294.0479126	0.32
295.2474365	11.38
297.4495850	2.94
298.6839905	0.20
299.4002380	1.01
301.4387512	0.06
302.1401062	0.83
303.3416138	2.73
305.1997681	1.99
306.2626038	0.87
307.3471375	9.26
309.1737671	8.35
311.3186646	3.69
313.1607666	0.90
317.2297058	2.02
319.2834778	3.71
321.2888184	18.19
322.6722717	0.59
323.3530884	1.43
325.5203247	1.30
331.2999573	3.68
332.2008972	0.82
333.2058716	1.34
335.3136902	12.09
337.2310181	11.07
338.5836792	1.25
345.2670593	6.02
347.3869324	1.64
348.8061523	2.22
349.4075928	7.46
351.3225708	1.72
355.5831909	0.88
359.3475342	5.04
361.3027039	5.46
361.9301147	0.16
363.2315979	14.41
364.2174683	0.27
372.3392639	0.05
373.5638733	1.58
374.2031555	0.34
375.3817139	3.35
376.3521423	1.00
377.4530945	9.28
378.5272522	0.23
387.5155334	0.35
389.3024597	3.03
391.3740540	100.00
392.0859680	0.06
401.4114685	62.30
404.5047607	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9651184	0.25
208.7849426	0.05
210.9430389	0.25
212.7791595	1.23
251.0047302	0.35
290.7110596	0.30
292.6301270	0.32
293.9791565	0.06
294.8035278	0.71
296.1642151	0.24
296.7843323	5.69
297.4089661	0.18
298.6306763	0.34
310.3580017	0.17
352.8583374	0.05
368.6226807	0.06
369.5267334	0.07
374.1911011	0.11
375.0974731	0.60
376.9004517	0.17
378.7597656	0.37
380.7630615	46.78
393.1033936	0.06
412.6905518	0.37
413.5495605	0.13
422.1088867	0.37
461.6450195	0.21
462.6153564	1.30
464.6516724	100.00
465.5039673	0.02
501.8409424	0.14
531.0139160	0.74
549.8577881	0.52
555.0823364	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	715.4273
Annotation	Mediasteroside M2
Peak:m/z	Relative Intensity
205.1341095	0.24
208.2651825	0.04
209.1353912	2.36
226.0621033	0.08
226.9103699	0.99
231.1804810	0.11
249.0601807	2.74
253.3436432	0.16
255.2501068	12.18
256.1870728	0.40
257.6322632	0.09
261.2661133	0.07
267.3598022	0.31
268.0210571	0.18
269.3408508	0.05
279.1400146	0.15
281.3216858	0.15
294.2001648	0.03
298.4089355	0.08
323.0940552	0.25
413.3889771	0.65
414.2683716	0.09
415.4943237	0.11
419.3117065	0.17
436.3173218	0.03
441.3121948	0.08
445.4591675	0.06
457.2774048	0.41
459.4486694	1.53
461.3063354	0.14
468.6087036	0.04
469.3413696	0.19
475.3662720	0.59
476.4978638	0.19
477.3428955	2.23
487.5906982	1.45
488.2492676	0.24
494.6958618	0.06
505.3815918	10.61
506.3003540	1.27
507.5192871	0.56
538.8276367	0.30
539.6571655	0.27
564.3975220	0.10
608.7213745	0.08
621.7152710	0.11
633.3235474	0.11
637.4270630	0.13
652.5161133	0.50
653.1929321	0.18
655.3801880	0.11
656.4025879	0.16
658.8696899	0.22
659.5870972	0.05
669.5591431	0.07
671.5861206	0.14
672.6537476	0.14
696.8150635	1.84
697.7870483	1.19
715.5115356	100.00
716.3381958	1.44
717.0438843	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.3926
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0511627	0.37
173.0766602	4.26
174.9746399	1.62
177.0873260	0.32
179.1846161	0.33
181.8470459	0.09
183.0955505	1.79
184.9305420	3.57
187.0842285	4.86
188.9343872	2.20
191.0890503	2.27
195.1344757	0.62
197.0867920	1.97
199.1124268	2.97
201.0949707	2.04
203.1114960	1.38
204.6184082	0.54
205.2784424	1.04
205.9174652	0.13
207.4015045	0.27
208.9882965	2.85
211.1570892	2.70
213.2934265	3.64
215.0245667	0.80
217.1328430	2.96
219.2182922	0.12
221.2064667	0.88
223.2948914	0.55
225.1148529	1.72
227.2127075	1.83
229.1793518	1.52
230.9189758	1.54
233.1473846	1.34
235.1481628	0.13
236.2450867	0.42
237.2954712	0.96
239.2906189	2.89
241.1830750	1.46
243.0738220	1.69
245.1138916	1.50
247.1173706	1.65
249.1444855	0.19
251.0846100	2.08
253.1955414	4.28
255.2416687	2.52
257.2221069	1.88
259.1900330	1.91
261.5310364	0.27
263.3796997	0.09
265.3943481	0.86
267.2152405	4.02
269.2878113	2.02
270.9440613	0.99
273.0306396	0.21
277.1878662	0.24
279.1046753	1.86
281.3660583	2.90
283.2165527	2.37
285.0950928	0.28
287.3673706	0.43
289.0965271	0.41
291.3131104	0.52
293.3692932	1.25
295.2605591	5.56
297.4266357	1.41
301.3042603	0.55
307.4311218	0.99
309.2459717	6.16
311.1229553	1.08
311.8977051	0.20
313.1893616	1.54
315.2559204	0.67
316.4485474	0.92
317.4037476	0.27
319.5327148	0.62
321.5514526	1.52
323.4216919	0.27
325.1273499	1.12
327.2028198	5.00
329.3663330	0.50
331.2135010	0.59
333.3593140	1.13
335.3230591	8.05
337.3687744	6.88
339.2231445	0.30
345.4150391	1.08
348.3952637	0.42
349.3243408	0.77
351.5438232	0.47
353.4718018	1.81
355.3187866	2.57
361.3449097	0.29
362.2586670	0.45
363.2865601	3.35
367.4864502	0.19
369.3663330	0.70
371.4380493	0.78
379.2183228	1.21
381.2670288	39.20
387.2843628	0.40
389.3597412	18.91
391.3293457	100.00
393.4011841	8.50
395.1546021	0.44
399.6024780	0.87
401.4512329	6.06
403.4865723	0.54
407.3338623	7.30
409.4429321	19.97
411.3643799	0.11
413.7949829	0.16
415.3717041	0.22
417.3986206	1.93
419.4108887	31.97
420.2768555	0.09
424.9599609	0.31
427.3249512	0.62
429.1374512	0.12
431.4766846	0.06
432.6536865	0.59
433.6986084	0.14
435.5275879	1.49
437.3512573	36.12
438.7309570	0.09
445.9537964	0.22
449.3836060	0.13
453.2245483	0.31
455.1621094	1.12
457.4436646	0.58
461.5064697	0.74
469.6148682	0.11
471.3038940	0.06
473.3381348	0.48
475.4299927	3.07
476.7731934	0.15
479.1778564	0.14
481.3011475	0.46
485.3096924	0.28
487.4313965	0.36
489.2832031	1.09
497.6203613	1.40
499.7071533	0.97
503.4208374	0.30
507.2484741	3.62
515.2987671	1.02
517.4304810	1.61
518.3546753	0.90
521.3658447	0.17
525.2902832	0.98
534.6272583	0.33
535.2852173	0.21
543.4433594	2.42
545.5723267	1.96
553.5242310	5.14
555.5602417	0.18
557.4245605	0.25
562.7064209	1.86
563.4028931	15.86
570.6909790	2.18
571.5380859	5.66
581.3233032	41.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	761.3769
Annotation	Unknow
Peak:m/z	Relative Intensity
385.5214844	0.08
569.2715454	0.13
609.5188599	0.03
625.5560913	2.26
635.2736206	0.04
650.6459961	0.04
653.5892944	1.36
669.2315063	0.08
671.5249634	1.54
697.0002441	0.38
697.6159058	1.48
715.4910278	100.00
716.1187134	0.94
716.8468628	0.21
717.5092163	0.06
742.5222168	0.03
761.2620239	92.96
762.0042725	0.14
762.9973755	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.38
Annotation	Methylanhydrovilangin
Peak:m/z	Relative Intensity
168.5268402	0.47
169.2023315	0.28
170.1910706	0.42
170.8994904	1.23
172.9118347	0.94
173.9075012	0.26
175.0098877	0.66
177.1044159	1.19
177.9542084	0.39
180.0058899	0.34
181.1862640	1.25
183.0622253	1.89
183.9694519	0.57
184.9865570	2.73
187.2079163	1.80
189.1093445	1.01
191.1432800	1.06
193.0472717	0.43
195.0165253	1.69
196.5960846	1.20
197.2193298	2.59
198.0701294	0.47
199.1119690	1.74
201.1738129	3.19
203.1167603	5.22
205.2835388	1.62
206.0350800	0.20
207.1057587	0.60
209.1331635	2.72
210.0901337	0.19
211.1631470	4.18
213.0887756	6.99
215.2184143	3.27
216.2189941	0.34
217.2479553	2.58
218.9308472	0.65
220.2213898	0.10
223.1358795	1.60
223.7915649	0.34
225.2457275	4.97
227.1072998	2.73
229.2453461	2.68
231.1856079	1.92
233.0624084	0.82
235.2590790	1.86
237.2009430	3.67
239.1674194	7.23
241.2037354	7.80
243.2418976	3.61
245.2481232	3.33
247.1636047	0.30
248.2130432	0.30
249.1589508	1.20
251.1397552	3.80
253.1707458	7.34
255.1755219	7.40
257.1522217	2.29
259.2498474	4.92
263.2466736	0.16
264.6892090	0.51
265.3746948	3.63
267.2336121	9.07
269.2844543	5.83
271.1462402	5.47
273.1217651	2.56
277.2176819	2.81
279.2041016	6.96
281.2023926	6.68
281.9777832	0.52
283.3110352	3.35
285.1521606	3.27
287.3446655	1.94
289.1448364	1.41
290.2069092	0.16
291.2614441	1.28
293.1100464	3.29
295.2940063	7.64
297.2345581	5.17
299.2868652	7.24
301.3630371	0.18
302.8476257	0.49
304.2822571	0.15
305.3527832	0.75
307.2912292	4.86
309.2915649	8.43
309.9276733	0.17
311.3538818	0.72
313.2904053	3.04
315.3741455	0.24
317.2695007	0.87
319.4218445	1.10
321.2095337	4.48
323.0534058	0.96
325.2446899	3.22
327.2084961	4.08
331.2413940	0.89
335.2711792	6.04
337.3633423	6.14
339.3887939	0.46
341.3682251	1.27
343.5046387	0.25
345.3606567	2.37
346.1920166	0.11
347.1219482	0.39
349.3950806	0.38
353.4310913	1.44
355.3256836	2.59
357.0574951	0.48
359.1280518	2.12
361.4581909	1.37
363.3589478	6.92
364.3068237	0.36
365.1831055	0.17
367.3001709	2.98
369.1267700	0.33
373.4530640	0.32
375.2974243	3.20
376.2028198	0.23
377.4593506	1.35
381.2467041	20.76
383.1543579	0.32
389.4495239	1.77
391.3759766	100.00
392.0131226	0.81
393.4338989	3.19
395.2839966	0.85
399.3634033	0.45
401.4631958	23.12
403.0724487	0.75
405.3873901	0.24
407.4193726	0.25
409.5142822	10.49
417.2374268	1.08
419.3481445	68.27
421.7731323	0.08
422.4879761	0.55
428.9951782	0.17
429.7172852	0.43
431.0870361	1.31
434.5118408	0.49
435.6036987	0.48
437.3951416	73.80
443.3242798	0.13
445.1740112	0.27
447.1219482	0.78
448.7042847	0.30
449.4098511	0.69
453.3140869	0.24
457.0467529	0.69
459.2786865	0.95
461.4467773	0.48
465.4180298	0.58
469.4226685	0.48
471.2748413	0.29
473.5940552	1.19
477.5014038	0.12
479.5236206	0.22
483.4492798	0.25
485.6657104	0.22
487.4634399	1.48
489.3998413	0.15
491.4678955	0.18
495.1070557	0.44
497.4896851	1.49
499.6695557	0.50
501.5266724	0.24
505.5286255	0.24
509.7235718	0.43
513.3538208	2.46
515.4472046	2.85
516.9885254	0.23
527.3611450	0.29
533.5035400	1.78
535.2582397	0.20
537.8363037	0.36
539.4006958	0.35
541.4567261	4.71
543.5836792	0.91
549.3901978	0.22
550.7279053	0.29
551.3908081	2.84
553.3554077	1.09
557.3797607	0.64
561.4506226	2.36
565.2205200	0.35
569.3569336	71.13
579.4893188	9.68
580.6852417	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3871
Annotation	Stevioside
Peak:m/z	Relative Intensity
300.5401001	0.20
326.5058899	0.28
341.5133667	0.11
364.0778198	0.78
384.0227051	0.22
434.2768555	0.15
436.7677002	0.30
439.416626	0.42
457.3668213	0.13
470.5167847	0.18
472.3251343	0.38
493.49646	0.15
507.3286743	0.86
512.7040405	0.25
519.3999023	0.46
548.4456177	0.98
561.661377	0.40
577.1575928	0.15
588.3275757	0.28
639.0845947	0.19
655.18396	0.42
675.0443726	0.12
677.0829468	0.40
695.0811768	0.13
699.2491455	0.43
702.5204468	0.53
712.6016846	0.25
756.0077515	0.79
756.750061	0.55
757.6159058	0.36
759.2093506	0.55
766.9558105	0.66
770.3447266	0.11
783.3685913	0.70
785.484314	12.73
786.09552	0.41
803.4126587	100.00
804.2363281	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.408
Annotation	Conyaegyptin
Peak:m/z	Relative Intensity
170.1391144	1.11
171.1386108	1.81
173.0141907	0.70
174.1731567	0.41
175.1775208	1.39
177.0655975	0.98
178.7824249	0.20
182.5308533	0.44
183.1519470	0.74
184.3403778	0.31
185.1549988	1.28
185.9555664	0.45
187.2021790	4.63
189.0819550	5.46
190.0880585	1.06
191.1581268	0.30
191.9163818	0.10
193.0474854	0.35
194.0275574	0.78
195.2623596	0.55
196.9229431	3.51
199.2347870	1.85
200.0341644	0.43
201.2448730	3.71
202.4892578	1.25
203.2560577	1.14
204.2886353	0.32
204.9961548	1.80
207.0027771	1.31
208.2915039	0.33
209.1315765	0.45
210.5192108	0.58
211.1213531	4.78
212.2821350	0.12
213.2115479	4.06
215.1549072	3.70
216.1679993	0.27
217.2718658	0.30
218.4823151	0.61
219.1861267	1.52
221.0829010	0.16
221.9545593	0.20
223.1903381	0.85
225.1951599	2.46
226.0240479	0.85
227.2381744	1.56
229.1324463	3.83
231.2316132	2.19
232.2086487	0.80
233.1778870	1.74
235.0816498	0.39
236.2720947	0.51
237.2798309	0.52
238.2342682	0.50
239.3499451	1.93
241.0435333	0.86
242.1390839	0.14
243.2174225	1.16
244.0124512	0.11
246.9925537	1.32
249.2003326	2.05
250.2932434	0.31
251.1716309	1.55
252.7730103	2.04
253.4602661	1.27
254.7036743	0.38
255.3242950	1.00
257.2005005	0.35
259.2836304	2.08
260.3287964	0.45
265.3197021	1.64
267.1514282	1.22
269.2692871	0.47
270.2255859	0.48
271.3192749	1.05
273.2679138	1.37
274.4019775	1.08
275.2298279	0.25
277.4332886	0.46
278.3394165	0.14
281.1705933	1.39
283.2435913	0.29
285.3592834	1.88
286.0936279	0.32
287.2728271	0.31
287.9428711	0.47
288.9906006	0.49
291.2685547	1.24
292.1821289	0.58
293.3256226	3.20
295.2173462	63.56
296.2907104	7.06
297.2508545	1.69
299.0254517	0.73
303.2299805	0.64
305.0659790	0.24
306.3851318	0.43
307.1372070	1.34
308.7600708	0.78
309.4598389	0.34
311.3258057	2.31
313.2219849	54.62
314.2823486	5.28
317.2951050	0.44
318.1879272	0.36
320.5523682	0.22
321.5447388	0.07
323.1907959	2.90
324.3073120	0.53
325.2951660	5.36
331.3090210	0.72
333.3297729	0.78
334.4252930	1.15
335.1044312	0.25
337.4347534	0.39
339.5086670	0.87
341.3903198	1.69
343.4327393	0.28
347.2235107	4.03
348.0820312	0.21
349.0859985	0.79
350.5654297	0.21
351.4526978	2.43
353.1940918	1.16
357.6080933	0.22
359.0953979	1.20
362.6126099	0.42
363.3225098	0.40
365.3099976	1.94
366.0138550	0.09
366.9181519	0.93
367.5515747	0.14
368.1976929	0.30
369.1102905	0.28
374.0592041	0.29
375.3222046	0.29
377.5498047	0.18
379.2893066	1.69
380.1586304	0.48
381.1280518	1.09
387.3342896	0.21
391.5298462	0.27
393.2816162	1.76
397.5701904	0.37
403.4431763	12.33
404.4042358	3.51
405.2525024	0.44
410.3816528	0.44
419.5276489	0.26
421.3265381	63.54
422.3894653	13.37
425.4486084	0.14
429.7818604	0.19
430.4617920	0.41
434.5220337	0.30
437.2735596	1.14
439.2937622	100.00
440.3687744	17.06
445.4645996	0.15
449.3389282	0.10
450.4781494	0.74
451.7057495	0.33
457.2433472	4.41
458.2863159	2.75
463.4211426	0.81
469.5390625	0.27
470.3590088	1.03
472.3939819	0.65
473.2764282	0.30
475.3076782	16.48
476.4282227	1.70
477.4036255	0.59
480.3031616	0.30
481.5635376	1.10
487.5526733	1.49
489.5952759	0.64
490.2752075	0.17
491.5595093	0.89
499.5605469	1.52
501.4429932	0.67
502.0573730	0.22
503.5021362	1.28
507.4840088	0.82
509.5181885	1.54
511.5657959	0.24
513.2536011	0.44
521.6549072	0.96
527.6962280	0.40
529.1458740	1.56
529.7518311	0.32
530.3754272	0.62
532.5772095	0.11
536.4107056	0.19
541.2855835	0.32
542.0269165	1.38
543.2937622	0.43
545.8402710	0.26
547.4332275	1.25
548.5216064	0.23
555.5272827	0.21
558.2994995	0.17
559.6217651	0.08
565.3867798	3.07
566.1970825	0.83
568.6740112	0.19
583.3300171	17.44
584.2625122	3.61
587.7606812	0.43
603.7730103	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.15
Annotation	4-Hydroxy duloxetine glucuronide
Peak:m/z	Relative Intensity
144.9984741	0.45
146.9918213	3.10
161.9488525	0.05
164.9906464	18.31
182.0702972	100.00
182.8657074	0.22
199.0416870	0.17
207.0518188	0.12
213.1468964	0.07
230.9592590	0.19
235.2209473	0.25
240.0472717	0.07
246.0566559	0.51
246.6666565	0.11
256.4729614	0.07
268.5975952	0.38
270.7863770	0.15
273.1838989	0.55
274.4384155	0.26
291.1194458	0.71
307.2676392	0.13
308.0075989	0.71
309.0086060	0.20
309.9844360	0.19
325.0014648	0.11
327.2436523	0.35
328.3086548	0.85
333.2901001	0.22
339.2477417	0.28
340.0745544	0.30
341.2642822	0.37
342.3742065	0.10
343.2307129	0.07
357.3717346	0.54
358.1010742	0.09
359.2330322	0.12
372.0713806	0.40
374.3845215	0.10
375.1129150	0.20
390.5785828	0.09
393.8800659	0.13
400.3335876	2.13
407.2135620	0.26
408.0222473	0.04
426.3576965	0.31
427.5288391	0.50
430.1012878	0.24
433.5239868	0.14
444.3771057	0.45
445.5799255	0.30
454.5277710	0.42
455.3883362	0.33
459.2425842	0.21
461.0782471	0.19
462.6278381	0.70
471.5296936	3.10
472.1851501	2.18
472.9699402	0.18
487.2360229	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.07
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9997711	1.35
141.0161591	0.43
156.8179626	0.06
158.9354553	2.49
161.0650482	0.13
177.1134338	0.52
185.9213257	0.16
189.9376221	0.11
193.1380005	0.04
195.0087128	100.00
195.8917389	0.05
203.1688843	0.12
204.9742279	0.08
207.0397644	0.32
209.2697601	1.42
210.0965576	1.05
218.1425171	0.05
221.1625061	0.05
230.9468384	0.04
232.8182068	0.27
248.0488281	0.11
250.1977234	0.32
253.3069458	0.24
262.5218201	0.32
265.9412231	0.12
267.8969727	0.05
269.2201538	0.18
274.6658936	0.13
283.9915466	0.08
285.1695862	0.23
291.2903442	0.22
292.1856689	0.37
303.2213135	0.11
309.0102539	0.24
326.0718689	0.07
326.7259216	0.06
327.5448608	0.48
328.3283386	0.13
329.4630127	0.47
330.3316650	0.54
330.9605103	1.48
338.0663452	0.21
339.0465393	0.40
340.1252441	0.12
344.7851868	0.63
348.6577148	0.18
353.1912537	0.30
365.4491272	0.29
366.2516479	0.13
369.3515930	0.10
378.2564392	0.22
385.0191956	0.06
392.5838623	0.22
393.2553406	0.35
397.1093140	0.20
411.2421875	8.71
412.1705933	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.4538
Annotation	Mabiogenin 3-[rhamnosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
291.4060059	0.03
307.4135437	0.06
343.1491089	0.03
422.5191040	0.06
443.5333252	0.06
509.5310669	0.09
526.3968506	0.09
567.3873291	0.14
585.6528320	0.05
605.4751587	0.06
606.2457886	0.06
623.4321899	0.10
625.4000854	0.03
633.6284180	0.10
636.3950806	0.03
641.7070923	0.06
664.5369873	0.05
702.5065308	0.15
707.7661133	0.06
716.4216919	0.05
718.6306763	0.02
726.8012085	0.10
749.9611206	0.08
750.6137695	0.06
753.4137573	0.03
759.3440552	0.02
766.5196533	0.07
776.3371582	0.09
777.6677856	0.26
795.5440063	100.00
796.4478149	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.19
Annotation	Desacetyltetraneurin D 15-O-isobutyrate
Peak:m/z	Relative Intensity
103.0114441	0.05
104.9532776	0.58
106.8969498	1.20
108.9257431	0.22
110.9496307	0.95
114.9984589	0.19
117.0510406	0.43
118.9221191	1.85
120.9530334	0.72
122.9398651	0.80
126.9199829	0.27
128.9363708	0.40
131.0130463	2.07
133.0481873	2.98
134.4060822	0.57
135.0392456	3.89
136.0494995	0.13
142.9661255	0.07
145.0900574	0.81
147.0206757	2.40
148.1026917	0.46
149.0256653	1.02
154.8988342	0.05
157.1878357	0.20
157.8988037	0.66
159.0022278	0.39
161.0620422	0.06
162.1296997	0.13
163.0636139	1.86
169.0504761	0.11
170.1837769	0.03
170.9233246	0.07
173.0357208	9.83
175.1716461	2.72
179.9234924	0.18
182.9315491	0.24
185.2560730	0.03
188.9128113	0.07
191.0934601	100.00
200.2207947	0.05
203.2321777	0.13
204.8892059	0.07
206.0962524	0.12
209.2028503	0.18
210.3655090	0.08
212.9431915	0.05
215.1968689	0.31
219.1373901	0.08
220.0043030	1.22
221.0805969	0.87
222.0140076	0.11
223.0459595	0.20
229.3907471	0.05
231.0801697	0.39
232.1323547	0.17
235.2682495	0.31
236.9678650	0.09
238.9278870	0.22
246.8732910	0.23
248.2805481	0.11
250.0446777	0.09
251.9956970	0.04
253.2702942	0.22
254.1122437	0.06
267.0938721	0.45
275.2991943	0.02
279.1527710	0.19
279.8696899	0.09
281.8659363	0.06
286.2794189	0.14
288.0557251	0.11
289.3861084	0.08
290.1728210	0.06
293.2615356	0.02
294.9656067	0.18
296.2432861	0.08
297.2952576	0.88
298.2943115	0.15
299.2195435	0.19
303.1897888	0.30
304.9231873	0.15
306.9248352	0.57
307.7866211	0.05
308.5311279	0.22
309.1980286	0.11
311.3598633	0.28
312.1002808	0.20
313.0559692	0.29
317.2756958	0.31
322.4496765	0.47
326.2308655	0.02
327.2284546	0.31
329.7059937	0.06
333.2576904	0.31
335.1537170	3.73
336.1939087	0.83
336.8947754	0.22
339.0053101	0.28
339.7623291	0.21
344.0463562	1.40
345.1880798	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	674.49
Annotation	Unknow
Peak:m/z	Relative Intensity
212.4779663	0.33
213.2915955	0.21
270.2488708	0.23
271.1592712	0.24
286.3083496	0.32
324.2343140	0.19
341.5579224	1.61
357.3281250	0.35
369.1120605	0.22
375.4987183	0.93
398.3364258	0.45
436.4118652	0.12
441.2551880	0.30
444.4048462	0.40
481.0885620	0.09
504.3948975	0.12
512.6226196	0.77
519.2554321	0.19
569.2388306	0.26
570.8532104	0.12
582.7900391	0.57
584.2957153	0.63
585.1305542	0.44
608.0676270	0.13
612.2651978	0.21
630.9390259	0.47
640.7699585	2.57
642.5082397	0.49
654.9055786	5.12
655.9605103	1.25
657.1176147	0.29
701.7053223	1.86
706.5441895	0.31
741.2764282	1.00
747.9750977	1.18
760.3338013	2.41
761.4606323	1.42
765.5305176	4.87
771.5835571	2.82
772.5536499	4.85
774.6119995	0.10
779.3634644	3.65
782.5614624	1.93
783.4825439	2.82
786.2182007	8.74
790.3828735	31.94
791.2324829	2.20
792.7496948	0.38
793.9589233	2.79
795.1174927	1.74
796.0312500	0.14
800.6914673	4.38
801.7272339	0.71
803.9530640	2.40
807.2332153	0.41
808.3858643	2.47
811.2871704	6.47
811.9912109	2.88
814.0769653	16.74
815.1163940	31.96
816.1768799	3.50
818.6823120	100.00
819.9482422	2.72
821.0696411	0.51
821.7721558	0.54
823.9375610	3.45
825.0632935	0.68
826.0086060	2.18
832.0821533	3.10
845.2472534	0.53
849.6133423	1.56
907.9912109	1.52
916.5197754	0.59
919.3876343	0.89
925.6977539	0.67
930.6184082	0.86
931.4270020	1.50
935.3535156	3.90
939.2265625	1.32
940.5768433	0.17
941.3159790	3.26
942.0789185	2.35
946.6731567	1.53
947.8705444	1.18
958.2554321	4.47
960.7824097	3.95
963.6296387	1.00
964.4089355	0.81
967.5004883	0.61
971.5517578	0.12
972.7265015	1.55
980.7053833	0.76
985.0654297	3.19
989.3833008	0.17
991.1637573	2.18
991.9854126	0.25
994.0798950	0.87
996.8261719	8.11
997.5114746	0.11
1000.4390260	1.68
1001.4891970	2.85
1010.9547730	0.66
1011.6958620	0.71
1012.3186650	3.43
1014.1255490	4.65
1014.9628910	4.29
1017.4561160	1.13
1020.4370730	25.81
1022.8271480	0.85
1024.5887450	0.95
1029.3190920	7.37
1030.1613770	4.41
1031.4458010	0.76
1035.3388670	0.70
1047.4916990	4.14
1048.2675780	0.78
1051.7043460	0.23
1053.2780760	9.08
1054.2119140	0.93
1056.7050780	0.49
1060.8101810	0.61
1061.9587400	1.84
1067.6174320	1.10
1143.7596440	1.33
1175.8276370	0.30
1177.5704350	0.90
1245.3790280	0.21
1317.3349610	0.62
1327.9171140	1.66
1371.8710940	0.14
1395.7283940	2.31
1411.6638180	1.89
1431.7938230	0.22
1444.8057860	0.40
1503.2331540	0.48
1541.7889400	0.94
1570.7174070	0.33
1666.8314210	0.35
1791.3990480	0.40
1817.8840330	0.20
1856.0230710	0.22
1876.8416750	15.18
1878.5378420	49.70
1932.8970950	0.76
1952.5162350	10.23
1967.3684080	6.31
1979.3289790	73.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.0197
Annotation	Daucic acid
Peak:m/z	Relative Intensity
60.9559402	0.57
68.9513931	47.32
69.6107254	0.04
70.9318390	2.47
72.9236298	8.80
74.8678589	0.08
78.8496552	3.72
82.9736023	0.21
84.9692993	3.22
86.9458008	11.41
94.9753571	0.34
96.9752808	100.00
98.8949432	4.16
101.0041656	0.20
110.8973846	3.64
112.9396667	4.07
114.9007111	36.97
117.0399780	3.72
123.0046539	3.47
126.7835846	0.14
128.9018250	7.88
130.7404022	0.54
139.1331482	0.12
140.9139557	79.82
158.9740448	11.51
166.9998932	1.44
173.1340179	0.87
184.9615021	13.88
203.3592834	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	988.44
Annotation	Unknow
Peak:m/z	Relative Intensity
297.2219543	0.01
329.3057251	0.01
411.2413025	0.04
422.9722900	0.02
470.2868652	0.09
587.1734619	0.01
638.4718018	0.01
721.5494995	0.02
742.5057373	0.02
784.1416016	0.03
788.6413574	0.02
803.7583008	0.03
811.8189697	0.06
840.5958252	0.10
855.7414551	0.02
889.2532959	0.09
922.7374268	0.13
927.9560547	0.06
930.5877686	0.05
933.5562744	0.02
941.0827637	0.15
948.3432617	0.18
950.6320801	0.04
952.5147705	0.01
953.1643066	0.14
955.6291504	0.07
957.4169922	0.04
958.8637695	0.07
960.0323486	0.60
962.7248535	0.06
968.0556641	0.05
972.6060791	0.20
988.7434082	100.00
989.5527344	2.93
990.3225098	1.67
991.2662354	0.83
992.1700439	0.40
993.2026367	0.30
993.8747559	0.17
995.4006348	0.12
996.5175781	0.07
998.2583008	0.08
999.1586914	0.04
1000.2331540	0.08
1001.9562990	0.06
1002.7946780	0.07
1004.0655520	0.01
1005.1361080	0.03
1006.5866700	0.05
1007.7176510	0.07
1028.1204830	0.10
1030.7969970	0.01
1031.4454350	0.02
1032.4179690	0.06
1040.3806150	0.01
1043.4310300	0.01
1048.5200200	0.04
1052.6519780	0.10
1061.3939210	0.18
1062.6889650	0.05
1064.0897220	0.03
1083.7644040	0.05
1086.0754390	0.03
1093.8913570	0.03
1096.9227290	0.04
1101.7755130	0.02
1107.2985840	0.02
1109.1379390	0.04
1119.1179200	0.02
1125.9780270	0.11
1140.5745850	0.04
1144.1252440	0.04
1145.2089840	0.14
1147.3238530	0.07
1148.3005370	0.07
1148.9204100	0.03
1149.8909910	0.07
1152.3935550	0.04
1153.6280520	0.02
1159.5185550	0.14
1160.3704830	0.04
1164.0322270	0.06
1168.8237300	0.54
1169.7968750	0.02
1171.3422850	0.20
1172.9287110	0.17
1173.7564700	0.09
1177.1103520	0.11
1179.2050780	0.15
1183.5925290	0.06
1185.8533940	0.13
1188.4729000	0.04
1189.1406250	0.09
1190.0280760	0.04
1190.9459230	0.11
1192.2290040	0.22
1194.2109380	0.11
1197.0882570	0.08
1197.8431400	0.23
1200.0859380	0.07
1201.2559810	0.13
1204.4860840	0.12
1205.4562990	0.03
1206.5008540	0.11
1207.8673100	0.03
1210.5653080	0.03
1211.5432130	0.05
1212.4606930	0.04
1217.6215820	0.04
1218.7722170	0.05
1220.7733150	0.01
1223.2536620	0.33
1224.4411620	0.04
1226.8405760	0.09
1228.2896730	0.01
1230.3170170	0.18
1230.9355470	0.09
1232.9912110	0.13
1236.2171630	0.67
1236.8453370	0.01
1238.2005620	0.24
1240.1262210	0.04
1242.1674800	3.93
1242.9328610	0.16
1244.1889650	0.96
1245.1047360	0.12
1246.9128420	0.01
1248.3187260	0.14
1250.5449220	0.05
1253.4777830	0.04
1257.7014160	0.09
1263.0570070	0.08
1263.6734620	0.03
1265.1625980	0.09
1267.3232420	0.15
1270.2032470	0.07
1273.3117680	0.13
1274.4396970	0.06
1279.2725830	0.11
1280.1313480	0.33
1283.2937010	0.18
1288.5720210	0.02
1299.2239990	0.07
1326.3712160	0.08
1328.8665770	0.03
1344.7316890	0.04
1350.1843260	0.09
1360.8353270	0.01
1366.7012940	0.09
1367.5117190	0.05
1368.1446530	0.08
1369.8236080	0.02
1371.0865480	0.03
1378.0410160	0.04
1384.7174070	0.03
1390.9737550	0.06
1397.6799320	0.05
1404.8779300	0.01
1408.8430180	0.05
1410.0142820	0.02
1417.4803470	0.01
1418.4063720	0.10
1426.3522950	0.04
1429.8430180	0.03
1438.3741460	0.06
1444.8636470	0.06
1468.6958010	0.16
1477.3731690	0.02
1481.2510990	0.05
1493.6169430	0.02
1497.9183350	0.06
1504.3809810	0.05
1507.7537840	0.06
1511.4957280	0.01
1512.5703120	0.05
1516.6512450	0.10
1521.4488530	0.10
1523.6208500	0.01
1525.2919920	0.13
1533.0495610	0.04
1550.0465090	0.02
1561.0093990	0.04
1562.9030760	0.05
1564.4610600	0.03
1572.7005620	0.06
1581.5324710	0.09
1584.4114990	0.03
1589.1324460	0.02
1594.1229250	0.01
1597.1883540	0.05
1598.9654540	0.01
1605.8841550	0.04
1607.7130130	0.02
1611.6871340	0.03
1612.3574220	0.03
1614.5979000	0.04
1631.1978760	0.09
1638.7930910	0.03
1642.8922120	0.07
1671.5583500	0.03
1673.8736570	0.08
1675.5357670	0.10
1683.4559330	0.07
1697.4451900	0.01
1702.7678220	0.21
1705.7584230	0.57
1729.8985600	0.06
1731.4470210	0.02
1740.9816890	0.02
1751.9051510	0.02
1752.5579830	0.09
1753.2896730	0.06
1756.7390140	0.09
1767.1102290	0.08
1770.5225830	0.06
1777.0228270	0.03
1778.7989500	0.03
1795.7813720	0.03
1847.3616940	0.20
1862.9377440	0.04
1871.7869870	0.01
1876.4938960	0.06
1888.3874510	0.01
1889.7355960	0.07
1892.3299560	0.01
1903.2067870	0.03
1906.3187260	0.01
1907.3957520	0.08
1928.9381100	0.04
1933.1300050	0.06
1935.5886230	0.02
1938.2282710	0.04
1961.7772220	0.02
1982.1223140	0.06
1985.5965580	4.95
1987.2878420	0.01
1988.2521970	0.01
1996.1405030	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.2291
Annotation	Ustiloxin D
Peak:m/z	Relative Intensity
161.2005615	0.06
185.0684662	0.04
191.1808167	0.02
232.8224945	0.18
237.2304077	0.04
239.2398071	0.02
254.3120117	0.06
255.1110840	0.03
262.9928284	0.04
277.3482361	0.08
278.2455139	0.02
291.1280823	0.04
293.2363892	0.10
311.3488770	0.03
314.1092529	0.03
315.2116089	0.74
317.3913574	0.04
330.2033386	0.03
331.4296265	0.08
335.6068726	0.02
345.3452454	0.01
346.5134277	0.02
350.2258301	0.03
351.2092590	0.04
376.3117676	0.02
379.5100708	0.02
385.3023682	0.05
386.2754822	0.01
396.1483459	0.04
397.3502502	0.20
400.2663269	0.02
401.7195740	0.06
407.3711853	0.03
413.7900391	0.03
416.4512634	0.06
420.1934509	0.05
421.5221863	0.04
429.3521118	0.03
430.8079529	0.04
431.5528259	0.05
443.3171082	0.06
447.2475586	100.00
449.3840942	0.11
451.2849426	0.02
455.3908386	0.05
461.4041748	0.16
465.4666748	0.02
473.2366028	0.05
474.2109680	0.08
475.3461609	0.17
478.3829956	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0512
Annotation	2-Caffeoylisocitrate
Peak:m/z	Relative Intensity
110.8451767	20.47
111.7207336	0.05
119.1484146	0.02
129.0087433	0.42
134.9596558	0.44
149.2195282	0.05
154.9276886	7.86
172.9112396	100.00
175.0963745	0.05
178.9686737	1.39
190.9791565	80.04
195.9190063	0.07
205.0606995	0.03
211.2532806	0.16
220.4835510	0.05
231.9488220	0.06
235.1596985	0.05
237.2886047	0.20
244.9805908	0.06
246.2869873	0.27
249.2229919	0.06
250.3070679	0.37
261.1808167	0.07
269.0015564	0.09
277.0819397	0.03
281.4451599	0.10
291.1628723	0.12
293.1626892	0.04
297.2857666	0.08
305.0283813	0.11
306.1776123	0.04
307.2289124	1.19
308.4769897	0.42
309.2407227	0.41
314.4462585	0.10
315.1984558	0.18
317.0687866	0.24
318.2826538	0.11
326.9508057	0.08
333.3093567	0.04
334.2597046	0.19
335.3012695	0.66
337.3395386	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3853
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
234.9674377	9.27
309.2627258	6.68
627.4077759	7.55
744.1295166	10.97
775.4034424	3.86
785.635498	3.84
803.4019165	100.00
804.6226807	47.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.21
Annotation	Unknow
Peak:m/z	Relative Intensity
120.0748978	0.23
129.2440491	0.14
143.0650024	0.41
144.9421234	4.14
148.9058228	0.11
149.8895569	0.06
153.1554260	0.14
160.2027130	0.08
163.0744019	0.29
164.7528229	0.04
165.9460907	0.60
171.8005981	0.09
173.0173340	0.27
176.9988403	28.49
185.2496490	0.26
191.2680054	0.10
194.0021210	0.07
197.0081329	0.39
198.1782532	0.63
203.0837708	0.47
205.1635742	0.09
213.1754303	0.05
214.1774445	0.09
215.1185913	1.22
223.1357117	0.12
230.9704285	0.25
241.1093140	0.22
245.9951782	0.61
248.1221619	17.50
261.1379700	0.25
265.2243042	100.00
267.4561462	0.11
268.7648926	0.23
271.3059692	0.16
287.2916260	0.52
293.4161682	0.09
295.5141602	0.05
297.3480530	0.49
299.2170105	0.08
301.8002014	0.23
306.0737305	0.20
307.3052063	1.52
311.3921814	0.08
314.9740295	0.39
321.2201538	0.35
332.9146729	0.09
333.5961304	0.08
341.4916992	0.14
343.2930603	1.06
345.6921692	0.19
346.4096375	0.10
349.5033569	0.18
353.6826172	0.27
355.0649414	0.27
361.1118469	0.48
363.2730103	0.60
364.2087097	0.24
367.5853271	0.11
373.2560120	1.85
378.9650574	0.25
380.9605103	0.35
386.0347900	0.10
386.9703369	0.17
391.2946777	1.40
399.5063171	0.09
400.4680481	0.11
408.4999084	0.81
409.6414490	2.10
410.3737488	0.67
415.1047363	0.16
418.1678467	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8507385	8.01
219.0313263	0.11
243.2268982	0.04
273.0325623	0.06
290.1190796	0.06
291.1959229	0.10
296.7636719	70.67
302.8469543	1.49
320.9554138	0.04
344.8871155	0.89
348.5873413	0.16
356.9299316	0.82
360.7969360	0.12
374.7114258	0.08
378.6914978	0.76
380.5842896	100.00
381.3341064	0.15
383.0270691	0.12
389.0064087	0.17
404.6259460	0.38
409.1248779	0.03
418.9784241	0.20
430.1969604	0.03
434.9333191	0.03
445.6760559	0.04
447.0873108	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.14
Annotation	Luteolin 7-sambubioside
Peak:m/z	Relative Intensity
167.0525818	0.23
169.1912231	0.09
173.0839996	0.30
175.0604858	0.15
178.9610901	0.07
182.2329102	0.13
182.9707489	0.09
184.0674133	0.20
185.0105438	0.16
187.0214233	0.16
193.2970581	0.23
195.0192261	0.90
197.1696320	0.99
197.9155579	0.16
199.2446594	0.18
201.3068237	0.14
205.1289062	0.10
209.8131409	1.51
210.9666443	0.59
211.9776001	0.18
213.2966309	0.87
215.2734985	0.04
220.7375641	0.10
223.3871155	0.08
224.1550751	0.11
226.3986969	0.68
227.1363678	0.35
229.1079712	2.18
232.0765686	0.27
234.6392975	0.24
238.1619263	0.20
239.0681763	0.55
240.2449036	0.26
241.0761719	0.52
243.0523987	0.10
244.9024353	0.11
247.3153381	0.31
252.1980286	0.16
255.0868378	1.21
256.1693115	0.26
257.0098877	4.10
259.3402405	0.07
266.1979980	0.11
267.1135559	1.96
268.7346191	0.16
271.1590271	0.12
272.2426758	0.12
276.2271118	0.06
281.2310486	0.06
283.2026367	1.25
284.0603027	4.07
285.0723267	100.00
288.3504639	0.07
289.1732178	0.64
290.2250366	0.17
293.8965454	0.26
295.1287842	0.18
296.1002808	0.09
299.0198975	0.58
301.0576477	0.07
306.1217651	0.89
307.3127441	0.79
317.1026001	0.33
323.8068237	0.09
327.2340088	1.81
329.2870483	0.24
337.3306274	0.20
343.2980957	0.21
351.2700806	0.22
357.1966553	0.87
383.0349121	0.49
393.1972046	0.30
410.5107422	0.24
411.2589722	0.05
417.3903198	0.17
421.1138916	0.07
437.2365112	0.12
439.0799561	0.35
447.0121460	0.38
450.5435791	0.11
473.4641724	0.40
480.7581177	0.24
487.6152954	0.09
491.1681519	0.09
493.1907959	0.50
497.6563110	0.64
500.6360474	0.37
506.4931030	0.19
516.3841553	0.25
519.5837402	0.06
521.3576050	0.16
523.3993530	0.07
525.2302856	0.32
532.0852661	0.74
533.3333130	3.96
534.7036133	0.27
535.3092651	0.17
543.5633545	0.10
558.8316650	0.13
560.3536987	0.99
561.3430786	0.63
580.3495483	0.87
END