#DEFINITION	Reference Metabolome for Lactuca sativa Crispa Group
#IDENTTFIER	RefMeta-Lactuca sativa Crispa Group.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Lactuca sativa Crispa Group
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Lactuca sativa Crispa Group was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.1271
Annotation	Cadensin B
Peak:m/z	Relative Intensity
138.5375824	0.04
139.8826294	0.03
140.8803406	0.21
142.0824280	0.56
143.0443573	0.04
148.8585510	0.08
151.1365204	0.27
152.0402069	0.91
153.1492767	0.10
155.1342163	0.07
157.0133057	0.50
159.0927734	0.16
165.0957947	0.51
166.0593872	0.23
167.1008606	2.47
169.0602112	0.26
170.2298279	0.47
171.1091003	0.18
173.0564270	0.24
175.0466766	0.07
176.5837097	0.03
177.8975220	0.05
179.1475220	0.20
181.1985168	0.12
182.2210236	0.32
183.0055847	0.20
183.8160400	0.06
185.0945892	2.49
187.2462006	0.19
192.8386230	0.06
195.0046997	10.41
197.1473694	1.45
198.0473938	0.84
199.0805969	0.61
205.1147766	0.06
210.9431000	0.06
213.0303040	11.79
213.8453674	0.02
217.0704651	0.11
223.0649261	22.08
225.0823975	0.07
231.1808014	0.03
232.3567352	0.05
237.1693115	0.02
239.0804138	0.22
241.0663910	86.32
243.2126160	0.02
258.8446350	0.38
266.7759094	0.04
268.9374695	0.05
277.2163086	0.10
284.1705017	0.38
285.0024719	3.13
288.9545288	0.02
294.9124756	0.22
295.6547241	0.03
299.2774963	0.06
300.7160034	0.04
303.1728821	0.12
306.1426086	0.03
312.9706116	9.93
315.3316650	0.04
329.1112671	0.23
331.0437622	100.00
339.0008545	0.02
348.9352112	0.45
351.4206543	0.13
367.4625854	0.08
371.4350586	0.04
375.0983887	0.32
383.2020264	0.12
392.9395447	0.47
393.6462708	0.13
398.7005310	0.09
420.4940796	0.24
421.2198181	0.11
422.2100525	0.05
427.1546021	0.08
430.3999023	0.03
439.1672058	0.04
440.1552429	0.12
448.4404602	0.04
450.3811951	0.03
464.2686157	0.25
465.2450562	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.09
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
134.9634705	0.38
144.8754578	4.67
147.1493683	0.16
149.2556763	0.34
152.1405945	0.38
162.9161377	100.00
163.8659515	0.09
173.1370392	0.51
174.8989563	3.08
183.2265930	0.22
190.9885559	0.63
201.0617065	0.33
204.9525757	0.17
211.0531616	0.12
213.1002045	0.17
215.0893097	0.27
222.3386841	0.46
227.4323883	0.11
230.9723816	0.20
233.1378326	0.67
236.6493530	0.18
239.2853699	0.47
241.6780701	0.17
251.0727234	0.53
251.9502869	0.12
253.2748108	0.18
255.1320496	0.43
257.1394958	0.94
258.7902527	0.49
264.1706543	0.06
264.9981384	0.13
266.9357605	0.43
269.1283264	6.73
270.1492004	0.29
271.2204590	0.23
277.8871155	0.14
279.3141785	0.38
282.1156006	0.09
283.1085815	19.81
283.7164001	0.20
295.0899048	3.73
296.0755920	1.24
297.1871948	1.86
301.1470337	48.55
303.3323059	0.15
312.8803101	1.55
314.1683960	1.47
315.2161865	0.14
318.9681396	0.14
321.1787720	0.69
322.6440430	0.64
323.3511047	0.40
324.2384033	4.32
324.9751282	42.27
325.6757202	0.07
337.4530640	0.21
342.2276306	0.71
343.1422729	2.16
346.9089966	0.34
359.4826050	0.20
363.0929260	0.34
364.2722778	0.60
365.1333008	2.30
366.0851135	0.14
371.3925476	0.09
375.9341736	0.11
383.6937866	0.61
385.3825073	0.49
395.7197876	0.43
400.1732483	0.13
401.1514893	0.36
415.2711487	2.98
421.4629822	0.13
427.2303772	0.15
427.9696350	1.29
429.2123108	0.51
430.2422180	0.71
431.2346802	0.19
433.0306702	1.31
446.4471741	0.53
447.4847717	0.26
456.4171753	3.23
457.1679688	10.06
458.3465271	0.09
474.1319885	0.08
592.2199097	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.1072
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
106.9194107	0.14
116.0357437	0.41
118.7925110	2.57
121.0812836	0.58
123.0282898	1.75
125.9522781	0.07
129.0275116	1.23
135.8822327	5.51
136.8273315	0.13
138.7829590	0.06
146.9299316	3.70
148.1470337	0.37
155.2356873	0.28
155.9648438	0.26
164.9933472	15.69
165.8524933	0.13
168.0661621	0.16
169.0520630	0.22
171.1311340	0.14
175.0937195	0.83
176.9654388	0.06
177.8710327	0.08
181.9533997	100.00
187.1488647	0.09
189.0765991	0.27
193.0445709	0.32
194.0169067	1.24
196.7766266	0.22
203.1816559	0.24
205.2225037	0.71
206.9639282	0.16
210.1900330	0.61
211.0726318	0.34
212.0699768	1.19
216.2218933	0.10
227.2484741	0.64
234.6186829	0.72
240.1566772	0.15
244.2497559	0.07
254.9395752	0.16
257.8224182	1.37
259.0944824	0.17
260.7337952	0.67
267.9910278	0.32
269.1385193	0.17
276.3773193	0.15
286.1163330	0.14
287.1342163	0.84
294.2671204	0.08
295.3142395	0.29
298.4504395	0.49
299.2437439	1.68
303.1506958	0.08
307.7307129	0.19
312.0621338	0.26
312.7048950	0.24
326.2953186	0.49
327.2336731	0.12
328.0196228	0.34
330.0751343	0.46
337.8783264	1.10
339.1174316	0.12
342.6914368	0.44
344.2330017	0.07
345.8462524	0.17
355.2154236	3.28
356.1754761	7.28
356.9913635	0.26
373.6598206	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	642.831
Annotation	Unknow
Peak:m/z	Relative Intensity
207.1914215	0.21
222.9673615	10.90
290.7047729	1.25
306.8713379	12.41
321.0249939	0.15
323.0588989	1.20
336.3652954	0.37
383.0632324	0.09
390.3368530	2.75
390.9714966	65.27
396.0921021	0.33
400.9325562	0.32
407.0552368	1.83
422.6559448	0.59
423.2658691	0.50
426.0654297	0.07
450.2242432	0.12
451.0408325	0.16
458.9114990	0.15
461.2704468	0.14
471.2414551	0.59
472.3416138	0.41
474.1169434	2.92
474.7760010	32.12
480.8286133	1.26
488.6464844	0.67
490.4228516	1.23
491.1401367	1.83
497.3816528	0.75
510.7281494	0.78
550.7675171	0.27
556.8344116	0.10
558.6624146	100.00
559.5333252	0.23
573.6089478	0.27
595.9464111	0.84
599.1170654	0.33
612.6100464	0.23
621.8959351	0.43
624.6597290	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	213.1497
Annotation	5-Oxododecanoic acid
Peak:m/z	Relative Intensity
69.1695480	0.01
81.2436371	0.02
83.0083771	0.12
86.9222717	0.05
93.0239105	0.09
94.8442841	0.01
97.0765839	0.07
111.1249695	0.12
113.3839722	0.06
120.8602142	0.02
122.9903107	0.04
127.1664124	0.01
128.8334808	0.01
139.1579285	0.08
141.0500641	0.07
147.2507782	0.03
149.1966553	0.04
151.2743988	0.08
155.0502014	0.05
158.8405914	0.05
165.1384430	0.32
167.2211456	1.04
169.2740326	0.92
175.1912384	0.16
177.1219635	1.89
183.1249847	27.12
193.1303253	0.42
195.0887299	100.00
197.1790466	0.03
198.2223206	0.04
213.3131104	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1306
Annotation	Galactotriose
Peak:m/z	Relative Intensity
200.1625214	0.18
201.1062012	0.54
210.0701904	0.24
219.0066681	0.40
244.7945709	0.09
288.9443359	0.20
290.5974121	1.23
293.9914551	0.06
325.9177246	0.07
331.2112427	0.13
363.1243286	14.50
371.3485107	0.79
371.9801636	0.28
378.0300903	0.04
381.1304932	100.00
382.0346680	0.24
382.6434326	0.05
416.2000732	0.21
423.2998657	0.14
453.1823120	2.85
454.5556641	0.08
472.9808350	0.05
483.1542969	0.15
489.1034546	0.40
525.3458862	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	731.4312
Annotation	Spergulin B
Peak:m/z	Relative Intensity
205.4037781	0.54
225.3951416	0.07
228.1209106	0.23
231.2218933	0.17
235.3037720	0.37
243.0162811	1.19
265.0503235	0.10
267.3728333	0.09
269.2169189	0.14
271.3043213	0.24
291.1425781	0.77
301.0797119	0.12
317.3110352	0.14
331.7143250	0.07
335.1842041	0.87
351.6997681	0.19
355.3416748	0.49
361.1956177	0.27
377.3051147	0.34
395.2284546	0.13
397.0771484	0.23
409.3153076	0.10
417.3471069	0.22
419.3601074	0.27
436.9627686	0.15
453.2968750	64.35
455.4745483	0.12
456.1396484	0.12
468.5766602	0.51
471.4931030	0.19
483.2749634	0.26
497.3831787	0.43
505.5961304	0.81
509.5256348	0.06
519.4096680	100.00
520.2617188	0.11
551.4774170	0.18
557.4371948	0.37
569.4757690	1.40
570.7833862	0.06
646.3952026	0.16
657.4512329	0.13
669.5130005	0.20
675.1740723	0.17
714.0057983	0.11
714.6903687	0.22
731.6258545	16.17
732.5354004	7.28
733.2738647	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1925
Annotation	Creoside IV
Peak:m/z	Relative Intensity
113.0066376	0.24
114.8597946	0.13
137.2013855	0.12
142.9151306	0.09
158.7453003	0.60
160.0822449	0.08
161.0779877	2.52
171.1139221	0.06
177.1954956	0.31
186.9457092	0.43
190.8710938	0.13
215.1779785	0.10
231.1429443	0.23
233.2124329	0.06
235.1830139	0.06
245.1735535	0.05
247.4320068	0.10
248.1901550	0.13
251.1339111	0.10
261.1549683	1.18
262.1568604	2.30
262.9848938	0.33
277.1481934	2.23
297.1687317	0.05
305.1250916	100.00
311.1810913	0.16
314.9014282	0.65
322.8943787	0.38
331.2597351	51.87
332.8837891	0.06
341.2180786	0.15
343.5223999	0.09
348.8695068	13.80
349.6384583	0.24
350.3875122	0.07
351.1742554	1.22
359.3724060	0.14
367.2777405	0.08
377.1021423	0.51
378.2337036	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0879
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.9499817	0.03
111.0320129	0.07
117.1142426	0.02
127.0532074	0.17
128.0837097	0.14
133.7738495	0.39
135.0050964	6.77
136.0237274	0.68
137.2415771	0.01
144.0759888	0.01
144.7970886	0.04
153.2648926	0.02
154.9541931	0.17
161.0308838	0.61
161.9603577	0.10
171.1417847	0.05
173.0069275	2.17
174.1072388	0.30
179.0106354	40.06
180.0030823	5.12
189.1296997	0.01
191.0195618	100.00
192.0380707	8.71
217.0422058	0.03
260.3303528	0.03
266.1109619	0.04
307.4751282	0.03
308.9745483	0.04
309.7933960	0.03
336.2335205	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.0562
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
106.8969269	2.01
109.0536423	0.03
124.9307404	3.04
135.0567932	3.91
150.9143982	100.00
160.9730530	0.60
165.2040100	0.03
177.0941162	0.26
178.9225922	0.05
195.9931641	0.05
198.9906921	0.08
201.1777344	0.22
225.1980591	0.23
227.2881470	0.31
231.1239624	0.05
241.0351868	0.03
242.2774048	0.13
243.1319580	0.35
244.9845581	0.05
250.3750610	0.04
251.1370850	0.04
257.8384094	0.05
259.2344971	0.11
267.9785767	0.07
269.0825806	4.12
269.6842651	0.06
271.2238159	0.03
272.3594360	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.07348633	0.23
92.93525696	0.44
94.91947937	1.05
96.92897034	1.19
100.8564606	0.44
106.9073181	0.33
108.8612976	0.79
110.9477692	2.29
112.063324	0.33
116.8789673	0.73
118.9109421	0.55
120.9908371	2.01
124.9272995	1.09
127.1048203	0.97
128.9458771	1.16
135.0032654	1.79
136.8141022	0.85
139.1461792	1.66
140.9943848	2.08
142.0496216	0.84
142.87146	0.69
144.8020325	0.12
147.2340698	0.46
149.0752258	1.63
150.9586487	0.78
153.0310059	3.04
154.9865875	1.43
156.9692688	1.61
162.7998962	0.68
165.9972382	0.37
167.0500183	0.78
169.0923004	4.47
170.9969788	2.21
173.0350342	0.84
175.2896271	0.17
177.0716095	2.83
177.9485168	0.27
178.9869995	0.45
181.551239	0.78
183.0140076	2.13
187.1949768	0.61
191.1506958	0.48
193.1955261	2.10
195.000824	1.94
197.1811829	4.00
199.1173859	0.21
206.8902893	2.50
209.2866516	0.74
211.1063843	9.02
213.1542053	2.07
215.233429	3.75
216.1309814	0.90
221.1837769	1.39
223.3565369	2.37
225.1132202	5.03
227.3217773	0.99
229.0803833	0.91
233.2999573	0.98
235.3515015	0.94
237.2319946	2.35
239.0235291	8.91
241.1906128	1.30
247.0418091	1.94
249.2644653	0.82
251.2000122	3.32
253.084198	23.70
255.2175903	0.45
257.092041	1.29
265.1653442	1.12
266.0460815	1.42
267.1567078	1.78
269.2721252	2.66
270.2328491	0.54
275.2738037	15.34
277.3701477	0.78
283.2236328	1.17
293.2034912	100.00
314.998291	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	963.2361
Annotation	Quercetin 3-(6''''-ferulylsophorotrioside)
Peak:m/z	Relative Intensity
285.1325989	0.08
408.6700439	0.55
409.3646851	0.41
410.2880249	0.33
446.0286255	0.05
474.2512817	0.03
480.9836426	6.12
482.0392456	5.47
489.4736328	0.11
524.3084106	0.14
702.5818481	0.12
891.9593506	0.07
962.0383911	0.18
963.2426758	14.30
963.8555298	100.00
964.7559204	2.42
965.7081909	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8885
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9259491	0.08
147.1886139	0.22
158.8867798	5.63
160.0934448	0.06
174.9289398	0.52
175.9228516	0.12
198.8539429	0.14
217.1259308	0.24
228.8645935	1.24
230.9578247	0.05
249.0628662	0.05
260.9175720	0.06
263.0515747	0.05
270.8753662	0.04
271.9752502	0.63
273.0606079	100.00
274.0541687	1.91
275.0048218	2.21
277.0828857	0.09
284.1018372	0.05
286.0308838	0.14
289.0374146	6.52
296.8490295	0.16
302.9530029	0.04
305.0095825	26.18
329.7131042	0.11
330.9035645	0.11
345.0318604	1.18
347.1005859	0.20
371.9482727	0.62
373.1584167	1.78
373.8810120	0.61
374.9344482	2.56
375.9024048	0.12
388.0923462	0.47
389.0366821	0.24
390.9277649	0.70
393.0386353	0.26
400.1250305	0.17
401.0168762	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	REBAUDIOSIDE A
Peak:m/z	Relative Intensity
447.4992065	17.73
819.6939087	17.71
967.4595337	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.04
Annotation	Unknow
Peak:m/z	Relative Intensity
109.8436279	100.00
127.8439789	4.79
130.3824310	1.35
132.8754272	0.05
139.1704559	0.71
145.0443268	0.01
151.0361786	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.0827
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
101.8101196	0.59
129.9692535	95.57
130.9187775	2.33
143.1233215	0.11
143.9828491	0.14
148.8119812	0.08
161.8982697	1.93
176.9987946	1.00
179.0308533	2.77
185.1101227	0.89
187.2908325	0.08
188.9784851	0.17
196.0626526	0.11
198.9635010	0.52
200.9664917	0.08
210.8490295	1.27
219.4891968	0.26
227.3851013	0.13
231.1092529	3.81
233.0486450	1.45
234.0638733	0.32
235.0281067	0.88
242.6484985	32.75
243.7156372	0.36
245.0158081	0.20
246.5949707	0.55
255.5267639	0.64
257.1792603	0.72
260.5839233	1.70
261.2243652	0.31
264.1495361	0.13
265.1966553	0.11
266.6440430	0.37
269.6211853	38.65
271.1982422	0.53
272.1383667	0.20
274.0830688	0.63
275.6545105	53.50
276.9442749	0.23
278.5189819	1.27
288.1781006	0.22
289.2517700	0.23
290.0994263	0.99
298.5679016	88.21
299.2549438	10.26
300.2164917	0.14
308.1754150	0.58
309.1983948	0.34
321.9913330	1.03
325.9547119	0.07
337.1106873	0.49
338.7638855	0.22
340.2222595	0.77
347.1348572	0.06
355.1537781	100.00
356.1780701	5.83
363.9850769	0.78
365.2102966	0.17
379.2323914	0.07
381.0829163	5.96
382.1698303	0.81
391.2105408	0.20
400.2678833	0.75
409.1940308	14.14
410.1573792	1.47
421.1518860	0.36
466.2905884	2.82
467.3487854	0.60
484.2202759	52.74
485.2212219	8.73
520.2214966	0.74
521.4151611	0.32
538.2135620	15.88
539.3858032	2.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.1822
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8723450	0.03
177.0435028	0.04
191.0225830	0.09
210.9073334	0.05
225.0147705	0.06
229.0187683	0.37
231.2333679	37.02
232.2288513	0.04
253.3316040	0.09
255.1195679	0.53
258.3828125	0.07
261.0823975	0.17
261.8444214	0.19
265.8330688	0.23
273.3947144	0.39
275.3574524	0.08
292.3961182	0.11
293.1026001	0.34
295.6545105	0.21
297.3517456	0.08
299.1580505	0.10
307.0713806	0.19
317.3031311	0.84
319.5224609	0.07
323.5402222	0.04
333.3434753	0.17
336.4397278	0.09
342.2351990	0.04
349.2470703	0.08
369.0982361	0.04
373.2825623	0.15
374.2478943	0.05
379.1882629	0.24
391.0318604	0.32
393.2348328	100.00
394.2471008	0.11
395.3195496	0.22
403.1105347	0.13
411.0889587	0.20
418.3210449	0.12
421.0846863	0.48
422.1862488	0.04
430.4031677	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	400.18
Annotation	Unknow
Peak:m/z	Relative Intensity
117.9733582	42.31
135.9985657	4.74
136.6159973	0.18
139.0721130	0.28
147.9922943	0.09
151.0964813	0.13
162.9184265	0.33
176.1183777	0.09
178.1331787	0.13
180.9949341	0.09
190.4919281	0.11
192.1621857	0.32
201.8206177	0.31
203.0791779	0.36
204.0368652	0.08
205.2154388	0.07
208.0877686	4.54
218.1496735	0.44
218.8214111	0.25
220.1965332	3.50
231.9016113	0.22
238.0479126	100.00
239.1250000	0.26
244.0201721	0.19
246.9800720	0.35
249.0920715	0.06
258.2096558	0.19
264.9620667	1.76
267.3256226	0.11
268.1704712	0.43
269.8270569	0.27
276.1229248	0.27
279.2174377	0.15
280.2669373	0.66
282.2056580	0.43
283.1445618	1.79
285.1191406	0.10
286.1881714	0.66
288.1744690	1.18
292.2412109	0.09
295.0852661	1.35
300.0984497	0.29
301.0780945	0.66
301.8345947	0.41
303.2300720	0.70
304.0982056	4.69
306.9858093	0.16
308.0841675	0.13
310.0120544	1.77
324.1223145	0.16
327.5176392	0.69
328.1443481	0.55
334.3735657	0.37
340.2285767	0.28
344.0628967	0.15
346.3329468	0.11
352.2398071	10.64
354.0964661	0.41
355.5189819	0.54
364.2074585	5.73
370.4500732	0.27
371.8383179	0.21
378.3067322	0.07
382.2649536	2.66
383.1365356	0.07
385.6030579	0.62
390.3119812	0.33
409.0077820	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2452
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0767670	0.12
179.1064606	0.08
185.2240295	0.03
187.2258606	0.20
189.1479340	0.96
190.3604431	0.16
197.1043701	0.07
203.3891144	0.05
205.2671814	0.07
207.2617798	2.01
208.3153839	0.31
225.2889709	0.05
231.1820374	0.58
233.0631714	0.39
234.2992554	0.14
242.3608093	0.04
251.1169739	48.35
252.1926270	5.42
265.2208862	0.07
269.2602539	0.03
275.1312561	0.03
276.5337219	0.03
284.8128052	0.05
293.2414551	1.26
294.2180786	0.51
298.9689331	0.04
305.0607300	0.15
305.9188843	0.05
312.0966797	0.03
313.1823730	0.20
323.1185913	0.30
323.8309326	0.32
327.4003906	0.03
329.3586426	0.11
330.4049072	0.15
331.3385620	0.03
341.3291016	0.12
353.1582031	0.95
354.2290039	0.22
355.1469116	0.20
358.7401123	0.07
369.3620605	0.06
370.2994995	0.04
378.2893066	0.09
387.4057617	0.10
388.6856689	0.08
394.9656982	0.12
395.5657959	0.10
396.3160400	0.14
407.7937622	0.03
413.2179565	21.16
414.2904053	3.71
431.2451782	100.00
432.2604370	19.55
473.2104492	0.57
474.2772217	0.14
476.1737671	0.09
503.2875366	0.24
504.3617554	0.04
509.9110718	0.22
519.6459351	0.03
533.2664795	0.64
533.9931030	0.06
546.3609619	0.13
549.2265015	0.11
556.2073975	0.06
572.4052124	0.24
576.2893677	0.24
577.7211304	0.07
594.1665649	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1824
Annotation	Pyridinoline
Peak:m/z	Relative Intensity
148.8152161	0.10
161.0452576	0.10
170.9376831	0.06
172.9862366	0.05
176.8119812	0.07
185.1378479	0.09
187.3358459	0.08
190.9981689	0.07
201.3762207	0.43
210.9241486	0.04
214.9038086	0.05
221.0254974	0.12
247.0283508	0.15
265.1278381	0.10
279.2470093	0.04
283.2918701	0.07
286.1950684	0.06
291.9778748	0.06
318.9500122	0.14
337.2890625	0.35
340.5876770	0.21
346.6160278	0.20
353.1862793	0.19
355.1900024	0.10
359.1157837	0.05
361.5333557	0.05
364.1995850	0.05
368.3127747	0.11
381.2407837	100.00
381.9611511	0.29
383.2557678	1.39
389.1936340	0.11
391.1593933	0.30
407.3645325	0.10
408.0110168	0.10
409.3139648	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9099731	0.05
218.9271698	0.75
302.9253540	13.48
334.2879639	0.04
372.7378540	0.08
374.9846802	0.25
377.8753052	0.13
379.0917358	0.11
380.2872314	0.39
381.2109375	0.11
382.5755005	0.17
384.8244629	0.48
386.7398071	52.66
387.3493042	0.35
393.0728760	0.06
401.0447388	0.10
442.0910645	0.07
444.2960815	0.08
444.9213867	0.18
468.0268555	0.13
468.7556763	0.26
470.7017212	100.00
471.5971680	0.02
494.1314087	0.05
495.1312866	0.10
508.5983276	0.13
524.7937622	0.05
527.0195923	0.03
555.7300415	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.99
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7782822	100.00
140.3764648	0.54
141.0072632	4.40
144.9222412	0.14
147.0358887	0.13
159.7007294	0.21
187.2342224	0.29
188.3566589	0.09
203.2672424	0.49
204.2877502	0.15
205.7843628	0.28
211.0408936	0.12
215.1539307	0.34
216.9580688	0.32
219.0924988	0.10
220.1479187	0.11
225.3482056	0.39
228.9122620	0.36
241.2371826	0.07
254.8432617	0.07
256.9062500	0.46
267.2427368	0.21
268.1181641	0.18
271.5776672	0.54
272.9203796	0.49
281.6472778	0.24
285.1172180	1.50
294.6621094	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0982
Annotation	PD 169316
Peak:m/z	Relative Intensity
106.9180222	0.48
110.9873199	0.43
117.944046	0.28
127.9981842	1.01
150.9083862	5.50
153.0699768	0.30
174.8882446	0.74
178.0438843	0.30
181.8545837	0.75
187.1103363	0.59
190.842041	0.44
194.9877777	2.16
195.9599762	1.30
197.098877	2.30
222.9879761	0.39
257.1665039	0.72
263.0282593	0.87
265.0094604	0.60
266.5211792	1.50
270.8776245	1.22
272.022583	0.49
272.7926636	0.28
274.8361816	1.53
283.0390015	0.60
297.0974731	1.02
305.1276855	0.34
313.1066589	100.00
315.1986694	4.22
323.3535461	1.20
324.1712952	0.70
326.1853943	0.91
331.2213745	0.52
336.7187195	0.31
339.0240173	1.48
340.2610168	6.79
341.3335571	3.50
342.263092	0.25
344.1555481	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	362.997
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9560547	6.33
114.9973907	0.08
129.0757294	0.21
131.0015259	0.10
132.9073029	1.90
147.1501312	0.03
154.8005371	0.04
170.7229156	0.03
172.9829102	1.91
175.0715332	0.06
190.9683380	100.00
199.1061401	0.06
217.0911255	0.06
218.9682617	0.03
219.8714905	0.09
229.0951538	0.03
231.1098633	0.04
233.1032410	0.03
259.0736084	2.79
265.1536255	0.05
275.2050171	0.11
283.0515137	0.06
287.2217407	0.08
290.9206848	0.02
301.3612976	0.13
302.0572510	0.01
303.2726746	0.08
305.0568848	0.05
305.9194336	0.05
317.2602234	0.03
318.2041626	0.05
318.9484863	0.17
331.2850647	0.02
345.0433350	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9077301	4.47
116.0147705	1.27
130.9838257	0.37
132.0274963	0.10
143.1625671	0.01
158.9416504	100.00
159.9148560	21.53
198.9519958	1.65
199.9908142	1.08
201.0059509	0.01
216.9947815	0.79
218.0622864	0.51
219.5002136	0.01
228.9081726	21.02
229.9138489	10.02
245.0062256	0.26
246.0849609	0.23
247.0861206	0.02
273.7409058	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.1716
Annotation	Unknow
Peak:m/z	Relative Intensity
190.9036865	0.14
241.1037140	0.02
307.4095459	0.20
308.1180420	0.05
317.4569702	0.02
323.1592102	0.10
335.2197876	0.80
341.1293945	0.91
353.2263794	4.52
373.3588257	0.04
376.8907471	0.03
397.2255249	0.02
404.3517456	0.03
425.3253784	0.10
456.4774780	0.12
459.3966675	0.18
461.3408813	0.18
464.4030151	0.03
470.6096191	0.03
489.4779053	0.11
491.4458618	0.03
494.1284790	0.02
497.4385376	0.29
498.0443115	0.02
501.3941040	0.18
503.0857544	0.16
505.4352417	0.04
515.2958374	100.00
517.3625488	0.04
534.2560425	0.03
535.4148560	0.08
541.2194214	0.15
580.1546021	0.14
588.4506836	0.07
593.0924683	0.03
598.3513794	0.05
601.2371826	0.09
609.2802734	0.12
611.9240723	0.12
613.6769409	0.08
614.3877563	0.08
627.3740845	0.04
629.4009399	0.25
633.3948975	0.08
644.4234619	0.07
651.9708252	0.10
657.1757812	0.09
658.4066772	0.42
677.2259521	11.32
678.3554077	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2661
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9106750	0.15
233.2149200	0.08
236.2374268	0.05
259.2855530	0.06
265.1069641	0.14
271.2579346	0.41
283.2817383	0.03
284.2567139	0.08
291.0995178	0.12
293.2232361	0.15
326.9969788	0.06
330.2509155	0.12
340.2714844	0.10
343.8681030	0.19
353.0488281	0.07
367.2478638	0.13
379.4608154	0.12
399.3262939	20.37
409.9652100	0.09
413.2810669	0.22
415.2721558	0.34
416.4483032	0.21
417.1956787	0.12
431.3605957	0.22
432.4830933	0.10
435.3670044	0.35
441.3319702	0.31
457.2760620	0.43
458.5695190	0.12
459.3666992	0.23
460.0049438	0.82
462.4976196	0.04
468.9957275	0.44
471.5377808	0.06
473.3948364	0.83
479.5469971	0.09
487.1546631	0.16
488.5057373	0.05
489.2863159	0.12
490.5867920	0.36
500.2932739	0.17
503.2832642	0.88
505.5533447	0.12
509.5169067	0.39
517.3876953	0.45
519.4669189	0.12
533.1592407	1.29
535.6053467	0.13
559.0379639	0.09
577.1160889	0.24
579.2039795	0.20
580.1369629	0.21
581.3623047	0.14
583.6613159	1.23
584.4077759	0.13
593.4055786	0.19
595.3304443	0.26
597.3729858	0.77
605.1257935	0.29
607.3881226	0.40
617.2153931	0.08
621.4002686	100.00
629.2312622	0.06
630.3712769	1.12
633.5213013	0.11
642.3825684	0.29
645.3044434	0.07
646.6583252	1.63
647.3573608	0.32
664.6063843	0.13
665.2326660	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	759.2729
Annotation	Galalpha1-3Galbeta1-4[Fucalpha1-3]GlcNAcbeta-Sp
Peak:m/z	Relative Intensity
291.0676575	0.48
417.6564331	0.12
421.3491211	0.80
446.3952026	0.29
504.7141113	0.43
515.0484009	0.23
528.9623413	0.20
572.4151001	0.15
573.6102295	0.37
579.3536987	0.31
597.3539429	0.27
655.3213501	0.80
670.2909546	0.27
671.5217285	0.47
673.227356	1.21
683.9769897	0.69
685.0786743	0.22
686.3488159	0.74
695.2683716	0.16
713.5720215	4.85
714.8567505	24.16
715.5592651	100.00
721.6452026	0.62
722.6807861	1.95
740.5800171	0.18
741.2651367	0.11
759.2698975	85.01
760.1811523	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7549591	6.53
261.0386658	0.04
296.7787476	68.72
302.9014282	0.96
344.8246155	0.43
375.0904541	0.10
378.0879517	0.63
378.7109070	0.08
380.6082458	100.00
381.3746033	0.34
404.6524963	0.04
423.3623352	0.16
446.8039246	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	499.1247
Annotation	2',3'-di-O-Acetylfrangulin A
Peak:m/z	Relative Intensity
142.8846130	0.19
146.9697113	0.06
155.1987000	0.04
156.7819214	0.03
157.9424896	0.13
161.0936432	0.36
162.9882812	0.67
171.0433044	0.25
173.0261688	0.53
175.1271667	0.05
179.0712585	2.93
180.1878052	0.23
182.9954987	0.05
185.1168671	0.49
186.9805298	0.22
188.5503693	0.05
189.1560516	0.41
190.9610443	7.44
197.1584167	0.15
203.1969910	0.31
205.3765869	0.05
211.9608612	0.06
213.1861115	1.54
215.2208099	0.12
216.0468903	0.04
217.1308594	0.05
231.1507111	3.33
245.1302795	1.06
255.0466919	0.18
257.0975342	0.48
259.3146362	0.08
275.0579834	2.12
285.2441406	0.14
287.2026672	0.10
294.2034302	0.03
299.2237549	0.10
301.0610962	0.06
303.3552246	0.05
307.3578796	0.16
311.4423523	0.04
317.1711426	0.31
319.3825073	0.46
325.0550232	0.09
335.0952148	1.32
337.1904907	21.53
342.9693604	0.04
353.2514343	100.00
369.1447754	0.13
379.1801147	0.44
383.4664612	0.03
384.3908386	0.08
406.4452209	0.04
411.6033020	0.04
414.1586609	0.08
427.1349487	0.29
453.2287292	0.30
455.2821350	0.14
462.4898071	0.11
480.1867371	0.04
481.1057434	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	430.1849
Annotation	Romucosine G
Peak:m/z	Relative Intensity
120.9731369	12.87
121.9505005	0.24
128.0630035	1.04
128.9650421	0.10
130.0306396	0.08
132.8990021	1.84
134.9894104	2.32
136.0382385	0.92
138.8233185	0.37
141.0201111	1.64
142.8782349	1.55
144.9841766	1.86
146.8540955	0.64
148.2042236	0.65
149.9557190	30.72
151.6769867	0.13
152.7961426	0.79
155.1305237	0.12
156.7847900	0.26
158.0746460	0.27
158.9648743	2.55
160.0570221	0.44
161.4664764	0.14
162.9815674	2.56
164.9220276	0.96
165.8813477	0.17
167.5926361	1.06
169.0425568	0.59
170.9751892	6.35
171.8634338	0.12
173.0005798	0.38
175.2381287	0.27
178.9885254	0.08
180.9584656	0.78
183.0211182	8.92
184.4960175	0.83
185.1746826	1.86
186.2715454	0.45
187.1648865	1.84
188.0154572	0.56
189.0363617	2.14
191.2367706	0.13
195.1234589	10.73
196.0942993	0.83
197.3177490	0.19
199.1705322	4.12
200.3110504	1.24
201.0864258	3.00
202.9323120	0.15
204.1689758	0.10
207.9993896	0.16
209.0800781	0.11
210.0978394	3.40
211.0727844	2.54
212.0795441	5.40
213.0686646	13.21
214.2656403	2.33
215.1191864	0.71
216.1408081	1.17
217.1552124	1.76
220.1598816	0.07
220.9507141	0.14
222.1104431	0.21
224.0122070	9.38
225.3420868	0.06
226.0995483	0.66
227.0729980	3.16
227.9681091	0.97
229.0719299	2.00
230.0754852	3.53
231.1225891	20.78
232.1457214	4.00
238.0844727	6.44
239.1059265	3.07
241.1191406	4.31
242.1719055	0.82
242.9726562	0.15
244.3301392	1.22
245.2336426	3.09
248.0669861	1.00
250.0850830	6.32
250.9430542	0.24
252.0558472	0.22
253.8817444	0.57
256.1054688	6.86
257.1215515	4.56
258.2764587	0.22
259.1445923	1.12
260.1854553	0.89
261.2085571	0.29
263.0806274	9.20
263.9503784	0.55
266.1321411	0.49
268.0756836	0.53
268.9854431	0.13
270.2722473	0.36
272.2942505	0.12
274.1710815	8.65
275.1074829	0.37
278.0894165	1.80
281.8892822	0.21
284.8905029	0.07
286.0534363	0.27
291.1703491	0.34
292.1527100	19.05
294.5106201	0.35
299.2634888	0.05
300.0970459	0.40
302.4304810	0.36
304.2171936	1.01
306.1883850	1.18
310.1522217	100.00
311.1552734	0.99
313.2328796	0.76
316.2416687	0.37
317.2152710	0.06
320.0500793	0.82
322.2476196	1.04
330.1971741	1.14
332.2300415	11.07
334.3283386	0.84
335.1771545	0.05
340.0750122	0.23
341.3183899	0.12
342.2448120	0.35
346.5617371	0.89
348.3424988	3.21
349.1260376	0.42
350.2724304	3.75
352.4626465	0.21
354.4917603	0.10
358.2008667	10.55
358.9347839	0.23
364.2132874	1.01
366.3876038	3.02
368.3658447	0.79
372.9340515	0.08
374.4273987	0.40
376.1984558	10.65
382.4481201	0.54
384.2789001	4.13
394.3161621	26.15
402.2319641	7.95
405.3145447	0.29
410.5098572	0.38
412.2109680	49.14
412.9331665	0.66
413.6237183	0.15
420.7936096	0.74
429.9458923	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.1823
Annotation	Unknow
Peak:m/z	Relative Intensity
148.8930359	0.54
151.2113342	0.03
160.7357483	0.20
187.1749878	0.02
187.9498138	0.05
191.2460175	0.09
192.0669861	0.06
220.9205017	0.25
227.1265869	0.02
229.1807556	1.47
230.2491455	1.58
231.2250977	0.46
250.8461609	0.14
254.1901550	0.03
255.2642517	0.01
257.3753052	0.04
258.1037598	0.03
261.0242920	0.03
266.3935242	0.02
271.4606628	0.02
273.0697632	0.06
279.7593689	0.03
281.2152100	0.05
293.2721252	0.19
304.3005371	0.01
305.1796265	0.02
311.0443420	0.32
317.3471985	0.05
320.9995117	0.07
322.1622925	0.04
325.5550537	0.01
333.2368774	0.07
348.0583801	0.03
349.2326965	0.04
361.1569214	0.04
367.2901001	0.11
391.1243896	0.13
393.2702332	100.00
394.2422791	0.06
395.1853638	0.06
415.3371277	0.09
418.3865051	0.07
419.5234680	0.06
421.1499329	0.07
423.2953186	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	522.7548
Annotation	Unknow
Peak:m/z	Relative Intensity
161.2791443	0.61
162.1058655	0.95
162.9394989	0.53
179.5095673	2.43
197.0087738	2.53
210.8241272	0.21
214.9190674	2.60
221.1335297	1.83
229.1192932	12.80
244.7661743	1.07
272.0811157	0.75
273.0613098	2.01
285.9634705	0.95
290.2159424	0.41
293.9639282	1.18
308.2265625	0.70
313.0603638	0.75
325.0870972	0.26
340.3478394	0.52
341.4146118	0.73
345.3173218	0.58
347.1658325	0.47
358.3504028	2.09
375.4048462	2.38
376.2904053	1.13
381.3543701	0.43
386.8890381	0.37
390.3623047	1.07
393.2017212	20.36
394.3265991	2.91
399.2478027	27.10
411.3220825	1.33
416.1734619	0.23
417.4984741	0.36
447.1713257	2.49
448.2731323	1.28
464.2755737	1.54
485.1185303	0.71
486.4016113	0.71
491.3663940	0.52
503.1076660	0.61
504.3779907	0.91
505.3202515	0.86
629.1815796	0.43
646.3268433	100.00
646.9276733	0.48
647.7350464	0.52
677.8244019	0.40
686.3187256	0.50
771.6691284	0.78
779.5415039	0.69
796.5739136	7.71
797.6120605	0.52
816.6923218	1.52
874.6989746	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.01
Annotation	Unknow
Peak:m/z	Relative Intensity
95.1456299	0.05
101.0024261	0.11
109.0808945	0.07
116.1185989	0.02
116.9884491	0.11
119.8615799	0.06
121.0267258	0.13
126.0940094	0.07
129.6558228	0.03
130.8680420	0.10
132.0029602	0.12
132.9584656	0.06
138.0936127	0.03
144.7000732	0.03
147.1150970	0.07
149.1519775	0.09
151.1037598	0.03
155.0837555	0.16
157.0373840	0.16
160.9582672	0.04
162.1816101	0.08
163.3115234	0.07
174.8753662	0.14
176.8973999	16.46
177.5085449	0.05
178.4322357	0.05
179.0751038	0.17
181.0865479	0.04
184.9074402	0.36
188.0237579	0.08
190.8644409	0.03
193.3024597	0.05
194.7383728	0.10
195.8836517	0.07
199.6473389	0.21
201.0479431	3.04
202.8970032	49.50
203.5290527	0.13
204.1344604	0.09
207.0054626	0.12
212.1344604	0.06
212.8784180	0.09
215.0118103	0.15
219.1287537	0.19
221.0055237	0.05
226.0558472	0.32
228.9308167	0.81
229.9169312	0.12
230.9815369	2.23
233.2007446	0.28
234.0522156	0.03
237.0470276	0.41
242.4201355	0.03
243.8917847	0.09
244.9930420	0.46
246.8464966	100.00
248.9412842	0.32
251.1398315	0.25
251.9860840	0.04
256.0904846	0.20
256.9546509	1.10
261.5443726	0.11
262.8618164	0.13
264.9868469	0.34
270.4415283	0.05
274.8540039	28.42
275.5979309	0.16
284.1290894	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutin
Peak:m/z	Relative Intensity
201.1994019	0.05
215.0264587	0.28
224.8572235	0.29
235.1639709	0.21
241.2353973	0.26
245.0713654	0.46
245.827301	0.32
249.3079224	0.12
255.2898254	0.10
257.061615	0.25
270.1288452	0.31
281.3522339	0.17
285.0838013	0.40
287.1479492	5.50
297.2557983	0.11
303.059082	100.00
303.6776123	0.27
306.677002	0.67
309.1585083	0.16
325.3051758	0.14
326.9782715	0.66
334.4863892	0.15
344.387085	0.66
345.1017456	0.67
361.5379639	0.14
362.2525024	0.12
383.4863281	0.14
384.1158447	0.12
385.3676758	0.06
399.3057861	0.31
419.5003052	0.47
429.1845093	0.16
430.829895	0.48
434.2748413	0.33
447.1209106	0.98
448.4590454	1.51
449.1459351	6.61
456.1137695	0.22
459.3624878	0.06
460.3449707	0.13
465.0227661	15.78
465.6773071	0.20
473.3002319	0.07
492.9898682	0.08
497.8154907	0.12
511.4856567	0.36
536.3118286	0.22
537.3659058	0.04
539.296936	0.42
545.4483032	0.14
546.2315063	0.32
549.2174683	0.23
551.4898682	0.09
556.4307251	0.21
557.3324585	0.73
563.4596558	0.16
565.4021606	0.15
567.2355957	0.08
568.0401611	0.15
570.3146362	0.33
574.5776367	0.20
575.5248413	0.09
578.598938	0.29
581.4136353	0.73
585.1503296	0.90
592.4111328	0.96
593.0960083	0.28
613.0386963	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.1907
Annotation	WF 14865B
Peak:m/z	Relative Intensity
104.8928070	7.30
108.9540863	0.70
126.9483032	19.55
137.0536804	0.50
144.9904175	2.26
157.2694702	1.11
158.2587891	0.65
159.3274078	0.33
175.0547485	0.29
181.0041809	0.37
183.1330719	0.66
201.1419373	0.48
208.1109619	0.56
210.9927673	1.48
212.8448486	3.00
226.1628113	0.34
230.9335938	82.66
246.0124817	0.24
248.8758850	35.94
251.2140198	0.19
265.9749146	3.17
270.3889160	0.18
275.1897278	0.53
277.1530762	0.30
278.2338257	1.86
279.4648438	1.15
295.1182251	0.85
296.2243652	1.24
297.1375427	0.22
299.3828735	0.66
307.3405457	0.83
308.5180054	0.45
310.0692749	0.72
315.0113525	51.52
316.5778809	1.12
322.3370361	0.28
324.2249451	0.27
327.1352539	5.06
329.1022034	0.18
331.4143066	0.50
332.4137878	19.57
333.0658264	100.00
345.1082153	1.23
345.8464966	0.53
349.4343567	1.10
350.4587708	3.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2029
Annotation	Unknow
Peak:m/z	Relative Intensity
134.7302094	0.03
143.2386475	0.08
149.0806274	0.03
163.1329803	0.22
165.1689148	0.18
167.0180206	0.05
167.9433289	0.10
176.9248657	0.03
178.9103394	0.12
181.9098663	0.05
187.1487427	0.07
189.1213074	0.54
191.1447906	0.34
197.2250519	0.03
199.2308960	0.10
204.6846619	0.05
206.4865570	0.17
207.1034088	3.00
209.1598816	7.22
224.2803802	0.02
225.1850433	2.33
227.2821655	0.14
233.0753937	0.12
244.4888916	0.06
251.1598816	3.72
257.1999207	0.06
265.3701477	0.02
269.1386719	100.00
270.2572021	0.08
272.0902405	0.06
276.0536194	0.03
285.2596436	0.09
286.0993958	0.16
287.1645813	2.23
293.1942444	0.23
297.3735046	0.10
303.1253052	0.03
311.2021790	0.27
317.0203247	0.23
318.1614990	0.06
327.2841797	0.03
329.2607727	0.37
343.3279419	0.04
344.9715271	0.07
347.3127136	0.08
349.1574707	0.04
353.1410522	0.15
358.2166748	0.05
362.5059204	0.06
363.1585388	0.06
377.2064514	0.05
385.1838074	0.05
387.0942383	0.19
389.3961792	0.48
392.2099304	0.12
403.3607483	0.17
405.0904846	0.43
417.2290955	0.05
430.4261475	0.32
431.2903137	1.25
432.0870361	0.09
433.2290955	0.08
433.9492493	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.1754
Annotation	Unknow
Peak:m/z	Relative Intensity
147.9058075	100.00
268.4357300	0.23
296.5044556	0.27
309.7951660	1.98
311.0251770	0.46
324.8031616	0.88
328.0731201	0.48
355.3786621	0.53
435.5455627	0.13
472.6049500	1.11
473.5868835	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	4'-METHOXYFLAVONE
Peak:m/z	Relative Intensity
76.88605499	0.37
78.74565125	0.41
81.09507751	0.24
82.92685699	0.32
84.92355347	0.12
88.8722229	0.06
90.9127121	0.14
93.15879822	0.14
94.8470459	1.17
96.0088501	0.16
96.83781433	0.38
98.81074524	0.12
100.1672668	0.19
102.9658508	2.64
103.7445984	0.15
105.0335541	1.02
105.9586182	0.13
107.0971985	0.53
108.8912964	0.57
118.9000092	0.49
121.0612335	0.66
122.8434601	1.49
124.009552	0.15
125.0755157	0.34
126.7944489	0.10
128.9418182	9.91
129.9546814	2.39
130.8633881	0.11
132.9912872	0.47
135.0123596	0.31
135.702774	0.15
137.0269318	0.08
138.8837433	0.11
141.1541595	0.56
142.0302277	0.23
143.1410522	0.26
145.1121826	0.66
146.1127625	0.06
146.90979	0.15
147.8566589	0.48
149.1527405	0.62
151.0065918	100.00
152.0366364	13.41
152.882843	2.20
154.3018646	0.22
155.0706024	0.64
155.9776764	0.77
157.1391296	0.37
157.8779755	0.08
158.92276	0.13
160.084671	0.06
160.9684601	0.49
162.0322723	0.44
163.1913452	0.05
164.1216736	0.14
165.0366516	0.78
166.0818634	0.74
167.0600586	2.58
168.4392395	1.43
169.0725555	1.26
170.4193878	0.15
171.0835114	0.91
175.0674896	0.36
176.2419891	0.08
176.9042816	0.14
179.0614777	1.64
180.1322327	1.04
181.0828247	0.53
182.0004425	1.67
183.2381744	0.24
184.2154083	0.05
185.1430511	4.18
186.0431061	0.27
187.0504761	0.24
189.1355133	0.19
190.1049957	0.35
191.1423798	0.41
193.0208435	0.21
193.9984741	0.61
195.1908112	0.37
195.9080963	0.53
197.0841827	3.61
198.2958221	1.07
198.971756	0.23
206.3043671	0.37
207.131485	1.44
208.1274414	1.45
209.8401031	0.23
210.9211273	1.45
211.7356262	0.29
213.0604401	0.14
216.9951935	0.98
218.1210327	0.20
222.9534454	0.32
225.1125336	7.92
226.0000763	2.25
231.1006927	0.06
235.1914825	2.14
236.1210785	1.65
238.0612183	15.53
239.1047211	4.13
240.0596466	0.41
251.2095795	1.76
253.0899658	60.76
254.1569824	13.26
255.1412354	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8752
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0043945	0.19
174.9805145	1.74
199.0415344	0.07
215.0657196	0.13
229.1838837	0.03
231.0942535	0.04
245.0262909	0.38
260.7651672	0.16
273.0008545	1.66
273.9816589	0.13
288.9513550	20.14
303.8244629	0.04
304.9227905	14.54
387.0224609	0.55
387.9526367	0.12
403.0172729	8.62
416.9517822	0.07
418.9376831	100.00
442.8912964	0.06
444.0381470	0.04
457.9838257	0.04
459.1486206	0.25
486.9846802	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.07
Annotation	Luteolin 7-glucuronide
Peak:m/z	Relative Intensity
156.9452667	0.01
174.9990845	0.04
184.8917542	0.02
242.3883820	0.01
271.1391907	0.02
285.0584717	100.00
285.6770020	0.11
297.1314697	0.40
299.4530640	0.03
309.6862183	0.07
325.2061462	0.06
327.2662354	3.23
337.2237854	0.34
339.1103516	0.19
341.2825623	0.13
343.1777954	0.09
351.2380981	0.27
353.0788574	0.27
355.1270752	1.64
357.1661682	5.19
363.2347412	0.26
367.2893982	0.07
369.2047729	1.57
371.1000671	0.35
373.5070190	0.04
381.2021179	3.11
385.0414734	0.01
387.3529968	0.01
397.5321350	0.02
399.2127075	0.38
417.2289429	0.02
418.4807434	0.01
419.3339539	0.06
425.3616333	0.01
443.2682190	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.2029
Annotation	Ebracteatoside D
Peak:m/z	Relative Intensity
128.9614716	0.04
134.0890198	0.07
136.0577850	0.07
157.1482849	1.06
161.1601868	0.21
162.8843231	0.07
165.2743683	0.07
170.0369720	0.07
179.0702820	0.22
180.0143433	0.06
181.0851593	0.27
190.9621887	0.20
193.2682495	0.03
193.9107361	0.06
198.6020203	0.06
199.2309875	0.14
211.1013489	3.72
218.9501038	0.09
229.1110535	100.00
232.0808258	0.05
235.1073914	0.07
253.1349182	0.37
254.0708618	0.33
256.2223511	0.09
257.0708618	0.30
262.9678955	0.04
271.2089233	0.44
272.1802673	0.36
273.0775146	0.26
274.1444092	0.32
275.1044006	0.23
287.9369507	0.24
289.0996704	0.04
290.6530151	0.08
300.9705811	0.18
304.1915894	0.19
305.2034607	0.61
306.1048889	0.10
311.5646362	0.12
312.8795166	0.06
319.1259460	0.11
320.5564880	0.08
322.9611816	0.08
326.0046997	0.35
331.0546875	0.53
331.6950073	0.19
334.8552246	0.05
335.4879150	0.11
340.6251831	0.11
341.2725830	0.05
343.4336548	0.05
347.1695251	0.27
349.2304077	0.25
351.3460083	0.05
353.5600586	0.75
355.2999878	1.21
356.0811768	0.88
361.3764648	0.38
365.1099243	0.04
370.1714172	0.24
371.9768982	0.08
373.3431091	0.23
375.2375488	0.07
376.4582214	0.06
377.8452148	0.19
382.1291199	0.14
382.9301453	0.17
384.1820374	0.11
390.3593445	0.94
391.0776062	6.33
391.6858521	0.28
392.3287048	0.19
393.1647949	0.90
398.3554382	0.06
401.0722351	0.21
409.6559448	0.08
415.3226624	0.48
416.1143799	0.07
417.2011719	0.07
418.4526367	0.10
419.2314148	0.72
420.7658997	0.10
422.1854553	0.04
423.8931580	0.24
447.2882690	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	560.32
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0507202	0.20
216.7144470	0.26
219.1004028	0.12
328.9066772	0.66
330.0419312	0.72
331.0104980	1.51
332.1371460	0.53
333.0081787	0.48
344.8231812	0.10
346.3068848	0.13
347.7255859	0.14
348.4575806	0.12
413.9727783	0.60
427.4918823	0.82
428.6779785	0.31
429.9626465	5.38
431.0971680	1.62
443.0340576	6.58
444.0112305	52.61
444.9920654	100.00
445.9400635	76.18
446.9354858	51.85
448.8361206	1.02
453.2646484	0.21
455.2421875	0.48
456.0294189	0.09
459.0445557	0.75
459.8104248	0.59
460.5389404	2.57
461.5841064	1.78
462.4215088	1.68
463.2785034	1.63
464.7728271	0.06
474.8279419	0.16
483.7642822	0.21
492.2447510	0.11
514.2981567	0.46
514.9326172	0.44
532.1359253	0.22
533.1524048	0.78
536.6359253	0.34
541.0586548	0.45
541.7879028	1.06
543.2036743	0.41
545.8407593	0.62
546.9432373	0.27
550.9074707	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
111.1380615	0.02
113.9952087	0.02
127.0842438	0.06
127.9856949	0.01
133.0435028	0.05
133.9585266	0.30
134.9956055	8.58
136.0359802	0.69
137.0526276	0.03
143.2131348	0.02
155.0545349	0.11
156.0755157	0.05
161.0734253	0.82
161.9715576	0.03
173.1136475	2.27
174.0646057	0.19
178.9964752	41.67
180.0966492	4.84
189.1088715	0.02
191.0297241	100.00
192.1225891	7.56
199.6979980	0.01
219.1691284	0.01
223.0294495	0.01
225.0910339	0.02
231.0445251	0.04
240.9426575	0.05
243.1530151	0.07
245.3305664	0.05
248.3139648	0.05
252.1366882	0.02
254.2736206	0.02
265.3109131	0.02
266.2238464	0.05
267.4245605	0.02
272.1643677	0.02
289.1685486	0.02
291.0415649	0.38
292.1121216	0.07
297.1812134	0.02
307.2307739	0.03
307.9467163	0.08
309.3213501	0.04
310.1883545	0.14
325.6098022	0.05
331.9558105	0.08
335.1286621	0.37
352.9398499	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.0852
Annotation	2',5'-Dihydroxychalcone
Peak:m/z	Relative Intensity
76.9331436	0.06
78.9280548	0.03
80.8575821	0.02
82.8441773	0.01
84.8693390	0.04
93.0580597	0.04
94.8675690	0.10
96.9550781	0.07
104.8886261	0.04
106.9300079	0.07
109.0681152	0.11
110.9364624	0.04
112.8586426	0.13
115.0559235	0.09
119.1632385	0.02
120.9441223	0.11
122.9306946	0.32
124.9646606	0.03
126.8300781	0.06
127.8965912	0.06
128.9624786	0.02
130.9067535	0.06
133.1227112	0.01
134.9843750	0.14
136.7178192	0.01
138.9159546	0.09
141.0543365	0.27
142.8731842	0.17
145.1727448	0.09
147.0845337	0.20
149.2133026	0.08
150.9885406	0.04
152.9038849	0.20
153.9524841	0.07
154.9908600	0.53
157.0939789	0.48
158.3762054	0.03
159.3220978	0.06
163.2547150	0.08
165.1014709	0.13
167.2360382	0.19
169.0760651	0.38
171.0802917	0.41
173.1792145	0.08
175.6080170	0.07
176.9538422	0.03
179.0717468	0.03
181.0095215	0.25
183.1505585	0.63
185.0602722	1.44
187.2967072	0.26
194.1880341	0.02
195.0093384	0.32
197.0645294	0.73
198.2180328	0.04
199.2116699	0.17
199.9930267	0.04
201.1097260	0.06
202.8524933	0.06
205.1638641	0.61
208.9754791	0.03
211.0530243	0.21
213.0186615	100.00
214.1654510	0.14
218.8401947	0.02
220.2873535	0.06
223.1253204	3.10
226.8681183	0.07
232.3412018	0.05
239.0818939	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	4-O-Methyl-a-D-glucosyl-(1->2)-b-D-xylosyl-(1->4)-D-xylose
Peak:m/z	Relative Intensity
160.8576660	0.22
178.9857178	3.78
197.0509644	0.05
215.1079254	0.04
221.0931396	0.72
232.9883118	0.08
250.8929749	0.24
281.1051331	0.38
311.0938110	0.18
323.1890259	1.07
339.4292603	0.17
341.0932007	3.39
355.3269043	0.11
359.2044678	0.07
377.2283325	9.50
383.1961060	0.31
443.3513794	0.17
503.2773438	100.00
503.9223022	0.11
521.4852905	0.03
539.2590332	0.08
545.8223267	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.2409
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
210.8925323	0.09
311.2706604	0.12
351.1245728	0.09
382.4383545	0.11
421.2971191	0.45
422.4386597	0.36
447.5521240	0.10
459.6119385	0.08
485.3004150	0.27
491.5844116	0.06
514.5208740	0.22
515.3936768	0.40
519.5211792	0.10
525.3154907	0.14
529.3394775	100.00
530.0974121	0.34
531.2278442	0.35
533.3928223	1.33
536.1181030	0.20
540.8001099	0.27
550.2786865	0.12
551.3662720	0.78
558.2677612	0.15
559.4309692	0.35
560.7598877	1.63
561.5166626	1.51
567.7199707	0.42
569.1215210	0.44
573.1198120	3.30
586.2260742	0.08
587.4421997	1.45
597.1780396	0.13
605.2944336	0.23
606.7138062	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0889
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
191.0499725	0.01
218.8383942	0.01
264.0582275	0.02
300.1907654	0.04
301.1282349	0.38
317.2740479	0.07
344.2375488	0.01
411.1611328	0.02
423.2160645	0.02
453.3312378	0.01
461.5326538	0.05
463.2415161	1.38
467.2439575	0.07
471.4435425	0.01
472.2555542	0.01
485.1630249	0.14
503.4099731	0.28
505.2011108	100.00
505.8442383	0.22
507.8083496	0.02
516.3718872	0.01
517.3212280	0.02
549.3053589	0.01
550.4473267	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.57948303	0.43
94.57801819	1.33
102.7248077	2.04
105.0480194	1.87
106.9264984	0.26
118.8062286	0.92
119.9694977	0.46
122.8374634	0.16
128.9975281	18.70
129.9838257	2.67
141.0293121	0.82
141.7835541	0.24
147.1264496	0.24
150.9733276	100.00
152.0332031	25.88
153.1641693	2.29
154.2913666	0.41
154.9070892	0.97
157.2693939	1.18
166.414917	0.43
167.2909851	3.88
168.1470642	0.88
169.0328979	1.65
170.2225494	1.81
178.1005096	0.48
178.9478912	3.52
179.9199982	0.72
182.0224609	1.78
183.086319	0.59
185.0957794	2.22
185.9653473	1.26
194.2084656	0.17
197.0581818	5.49
209.0825958	0.81
210.1735992	0.19
211.2996826	1.14
212.174057	0.44
225.1501312	8.88
226.0759125	4.75
236.9538116	4.32
238.0288239	21.54
239.1615753	6.66
240.2058258	0.22
251.1750641	4.25
253.0883636	59.80
254.047287	13.78
255.0493164	2.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1293
Annotation	Cratoxyarborenone D
Peak:m/z	Relative Intensity
122.8596802	0.09
129.9126892	0.10
133.2066650	0.03
144.1448364	0.08
149.0270691	0.06
150.9747314	3.33
155.2501068	0.15
156.9745483	0.16
161.0560150	0.46
164.7988892	0.10
166.6929321	0.11
168.2434387	0.05
169.0245667	0.47
171.0679321	0.50
173.1328735	0.15
175.0651245	0.56
183.0202637	1.18
184.3835754	0.31
185.1873169	2.08
186.9408112	0.11
195.1449890	2.89
196.9897614	0.29
198.0188599	0.78
210.1854553	0.15
211.0293274	1.01
213.1670227	30.91
214.0259094	0.07
215.1360016	0.07
227.1072540	0.98
228.3192444	0.43
229.2600098	0.39
233.3835754	0.20
239.1879883	2.99
242.0066528	1.81
247.2271423	0.06
257.0859070	100.00
273.5996704	0.15
275.0475464	5.53
291.3296509	0.05
295.2987366	0.05
301.2031860	0.06
303.3479919	0.16
312.9848633	0.13
321.2440796	0.05
329.3665161	0.22
337.3832703	0.12
343.2422485	0.31
344.4445190	0.12
349.4092407	0.14
353.2957153	0.06
355.2742920	0.12
363.7237854	0.15
365.1302185	0.46
367.3876648	0.18
371.1006165	0.10
372.2033081	0.35
373.3231506	0.16
375.4064636	0.05
390.5403442	0.10
391.4472351	0.14
394.1139221	0.07
410.0684509	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1515
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
170.9328003	0.19
175.2716217	0.08
176.1893005	0.09
184.9898071	0.12
188.9895172	0.08
192.998642	0.19
198.2160492	0.07
199.1002808	0.57
201.0325775	0.27
206.8725586	0.17
213.0455322	0.22
214.882782	0.05
217.1205139	0.08
220.9356384	0.04
224.098053	0.17
229.1358032	0.26
236.8885498	0.14
241.2889862	0.13
243.2453156	1.00
248.9777527	0.07
251.2172852	4.57
257.034668	0.08
259.3067017	0.07
267.5212097	0.04
269.137146	3.76
273.2765503	0.07
281.3854675	0.03
285.0427856	100.00
286.3617554	0.06
293.5007324	0.37
297.1393433	0.15
297.9224243	0.11
299.2696533	0.05
301.1895447	0.04
302.3640747	0.04
306.2652588	0.08
313.164978	0.09
316.9720764	0.08
319.1021729	0.38
322.9407959	0.10
327.3197632	0.47
328.1882324	0.13
329.4537354	0.13
337.28302	0.28
341.3649902	0.08
343.133728	0.20
345.2802124	0.19
346.9592896	0.12
350.1878662	0.09
351.9540405	0.08
353.2897339	0.08
359.1725464	0.09
371.1832275	0.19
375.3782959	0.08
381.2444458	0.09
385.145813	0.06
388.3530273	0.21
397.0570679	0.05
398.1972656	0.09
403.3704834	0.09
404.2877808	0.27
406.3504028	0.31
407.3889771	0.12
412.121521	0.07
413.3076172	1.16
414.2364502	0.15
418.1833496	0.22
426.2780762	0.14
427.3330078	0.16
430.2126465	0.49
431.2739258	8.27
435.2358398	0.19
443.348938	0.05
447.2019043	1.58
449.3178711	0.13
457.0604248	0.08
461.3383789	0.48
462.9989014	0.05
468.8691406	0.27
472.2352295	0.13
473.1428833	0.21
476.0966187	0.16
483.3168945	0.23
486.8591309	0.24
488.2084961	0.05
494.7733765	0.24
500.1618042	0.29
501.4205933	0.10
505.0379639	0.16
511.0805664	0.30
512.9017334	0.08
516.9669189	0.05
523.6066284	0.14
527.3851929	0.09
534.0466309	0.20
543.0238647	0.26
546.2476196	0.04
547.1343384	0.29
548.3291626	0.39
549.3497925	0.23
557.2575684	0.16
562.3405762	0.05
565.1513062	0.52
572.5878296	0.17
574.5871582	0.36
575.2973022	0.39
576.4898071	0.14
578.3930664	0.35
593.2637329	0.29
594.3398438	2.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1031.2465
Annotation	2'',6''-Di-O-Acetyl isovitexin
Peak:m/z	Relative Intensity
341.3364868	0.01
353.2436523	0.98
515.1155396	1.65
677.5525513	0.01
689.3836060	0.03
707.5604248	0.01
849.8612061	0.02
851.1373291	0.07
869.3959961	0.23
908.9844971	0.01
1030.2561040	9.23
1030.9218750	100.00
1032.3250730	2.38
1033.1605220	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2679
Annotation	[10]-Gingerdiol
Peak:m/z	Relative Intensity
102.8447342	0.09
104.8506012	0.23
107.0233383	0.86
109.0026093	1.46
110.3345642	0.05
111.1917953	0.08
112.6933823	0.23
114.9788666	0.13
116.8990631	0.29
119.0282288	1.27
121.0882950	1.47
123.0851669	2.63
124.9181366	0.26
127.6099243	0.18
130.8897552	1.12
131.5451813	0.10
133.0072021	2.14
135.0094452	2.77
137.0584717	1.72
139.0413208	0.60
141.0644531	0.15
143.0565796	0.09
145.0272522	2.14
147.0958862	1.83
149.0690918	3.34
151.1122437	2.14
153.0604553	0.36
155.1347961	0.12
156.9734802	0.14
159.0233154	3.06
161.0821228	2.23
163.0209961	5.62
165.0141602	1.58
167.0513000	0.41
169.0456848	0.15
170.9609222	0.03
173.1165619	5.36
175.1035919	0.98
177.0903015	2.55
179.1201477	1.79
181.0177307	0.25
183.1556854	0.09
185.0759583	0.17
187.1301880	2.68
189.1323090	0.97
191.0046082	1.10
193.1203003	0.41
195.0569305	0.62
196.9863586	0.42
199.0782166	0.51
201.2287292	1.70
203.1637878	0.28
205.1217651	1.80
207.2677155	0.20
209.0802612	0.91
213.0716400	0.45
215.0579529	0.66
217.0314941	0.14
219.1036987	1.03
222.8990784	0.05
223.5404663	0.12
224.9974060	0.14
227.0817261	0.19
229.1536560	0.35
230.9546814	0.36
233.1414185	2.24
235.0929871	0.15
237.2777405	0.49
238.6778259	0.11
241.4170837	0.09
243.1753845	35.09
243.8025513	0.43
245.2230530	3.67
247.2808228	0.06
251.2195129	0.25
253.2142029	0.05
254.5487671	0.03
257.2528076	0.11
258.8838501	0.18
261.2178650	100.00
261.8772583	0.17
263.2700195	5.91
265.3992920	0.02
269.0319214	0.34
270.9142456	0.48
271.5380859	0.08
273.2060547	0.12
275.4818115	0.29
277.4733276	0.32
279.1998291	9.42
281.2491150	0.20
283.1375427	0.35
286.9820557	0.10
291.4226074	0.44
293.6679688	0.04
295.3372803	0.13
297.2060547	0.71
299.2994385	0.68
305.3520508	0.04
311.2242432	0.44
312.1855469	0.16
317.3643799	2.65
335.3870239	23.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.046
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
86.9378433	0.09
88.8936615	0.17
102.9353256	0.91
110.0147400	0.37
113.0055084	0.38
114.0063324	0.06
119.0478516	0.67
127.9031525	0.16
128.9606171	0.24
130.7438965	1.32
133.2141113	0.06
139.0462189	0.44
140.1290588	0.42
141.1441345	0.07
148.9187469	100.00
150.0281677	0.07
161.0729218	0.04
162.4929047	0.78
163.0981140	19.04
177.1120605	0.07
177.9478760	0.05
179.0504456	0.17
187.0479736	0.11
192.3111877	0.16
206.2034607	0.15
207.1372375	0.14
219.0352783	1.73
220.0407715	4.47
221.1013794	1.49
222.0373535	0.07
231.9823303	0.71
236.8922119	0.10
247.4109802	0.24
248.1415100	0.08
249.0085449	0.35
249.8368530	0.53
251.1226807	0.45
252.2272339	0.24
276.0494080	1.99
277.2944031	1.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1225
Annotation	Marein
Peak:m/z	Relative Intensity
133.1271667	0.44
135.0357056	0.15
137.1920929	0.24
149.2037659	0.05
151.9562073	0.08
152.9312134	0.06
162.9861755	0.24
172.9721069	0.19
176.1464844	0.09
177.2194214	0.09
179.0414124	0.39
189.2043762	0.17
194.862793	0.14
204.9920654	0.08
214.7850342	0.20
224.5065155	0.11
225.1395416	0.12
228.8033447	0.14
239.2446594	0.09
241.1976318	0.10
257.354126	0.13
258.1279297	0.08
261.1564026	0.34
267.381958	0.06
270.1723938	0.26
271.2246094	0.18
273.0205078	0.14
274.95401	0.13
286.1916504	0.09
287.24823	0.83
289.0655212	100.00
289.7514038	0.14
293.6062622	0.33
294.30896	0.25
296.411499	0.04
297.2419434	0.62
301.0132446	0.11
302.359436	0.05
308.4407349	0.18
313.1861877	0.47
317.1737061	0.06
319.061676	0.51
321.3002625	0.26
325.8027954	0.24
331.1572876	0.72
337.5870667	0.27
340.1074829	0.11
346.7145691	0.29
348.2987061	0.53
350.4247742	0.44
351.4012451	0.18
352.3251343	0.16
355.3951416	0.80
359.2686157	0.24
360.644989	0.40
361.2451782	0.74
366.2339172	0.16
367.2461243	0.08
368.813446	0.18
369.4677429	0.16
371.2672424	0.08
377.2062683	0.22
381.0594177	0.24
383.7047424	0.13
385.2659302	0.45
387.244873	0.15
388.363678	0.70
390.1077576	0.05
392.355072	0.19
397.3612366	1.75
400.1750793	0.07
400.8737488	0.48
405.3493958	0.43
406.4658508	0.69
407.5844421	0.30
408.4532166	0.25
409.8999634	1.09
410.5139771	0.10
415.3476257	0.41
419.0376282	0.32
420.356781	0.16
423.3140564	0.13
430.7072754	1.25
431.6018982	0.05
433.1483154	6.36
434.214447	0.38
442.1138916	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.0723
Annotation	Aesculin
Peak:m/z	Relative Intensity
109.0073471	2.96
120.9373016	0.24
130.0653992	0.04
133.1087646	0.34
135.0043030	13.62
139.1498718	0.13
148.9967651	0.21
152.9278870	100.00
159.1406860	0.13
160.9680328	0.35
162.9949188	0.07
172.9289551	0.13
175.0002594	0.18
180.9079285	0.09
183.0269775	0.13
185.1309052	0.10
186.9934235	0.29
188.9090576	0.45
191.0028229	0.22
193.2139587	0.49
197.1366425	0.14
199.1271973	0.07
201.0860443	0.06
204.9156494	0.14
206.9487762	0.27
209.1870117	0.35
210.8890686	0.12
215.4277039	0.32
219.2428284	0.30
232.9678650	0.13
235.0340881	0.24
236.9307556	0.11
239.0411987	0.45
253.3431091	0.08
255.1975403	0.15
259.2648315	0.11
261.6127930	0.10
264.0490723	0.05
274.4491577	0.23
275.5067139	0.06
277.3363037	0.21
279.1399841	8.45
281.1013794	0.19
293.1556396	1.10
294.9015198	2.45
297.0992432	6.13
300.1452637	0.10
303.2565613	0.23
311.3134155	0.55
319.3460693	0.05
320.1094666	0.40
321.1933594	3.12
340.1033936	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2915
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
141.9312897	0.01
144.9341888	0.01
147.1596985	0.06
149.0857239	0.05
151.3562164	0.05
154.6644440	0.01
160.7426758	0.09
163.2150116	0.02
165.0519409	0.01
173.0988007	0.01
175.2707367	0.05
180.2250061	0.04
187.1858521	0.01
197.9336548	0.15
200.1537170	0.04
203.1905518	0.09
207.2221680	0.01
208.9878998	0.04
215.9825134	0.14
225.0356750	0.03
226.2627563	0.01
245.3658752	0.27
249.1728516	0.02
263.1759644	0.23
266.9766541	0.05
268.7937012	0.02
271.1897888	0.02
273.3869934	0.01
288.5319519	0.03
301.3458252	0.03
306.3648071	0.31
307.1321411	0.02
313.1983643	0.02
319.6056519	0.01
324.4177551	0.03
326.7187805	0.06
337.3076782	100.00
337.9281921	0.34
380.4531555	0.01
401.1879272	0.01
416.9506531	0.09
417.6908264	0.01
435.3470154	0.08
446.2843323	0.05
460.2033997	3.34
460.8544312	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.09
Annotation	dTDP-L-dihydrostreptose
Peak:m/z	Relative Intensity
163.0105286	0.06
179.1233215	0.08
185.1964417	0.13
202.1264191	0.06
207.1710358	0.12
209.3814087	0.03
235.3737946	0.07
241.1903381	0.40
244.9579773	0.27
287.0648193	100.00
299.0838318	0.12
300.9675903	0.81
309.6024780	0.24
315.2312622	0.18
316.4541626	0.05
321.2320557	0.09
322.2627563	0.13
327.4122925	0.16
328.8439941	0.03
332.2698975	0.25
351.6361694	0.09
353.0020142	0.08
363.4425659	0.17
368.0508423	0.05
369.1378784	0.04
385.1776733	0.08
387.4034424	0.37
390.6008911	0.20
392.5053101	0.12
409.3444214	0.21
417.6398315	0.07
427.3074951	0.09
437.1937866	0.13
444.1474609	0.05
445.0466919	0.05
453.7738647	0.09
463.0168457	1.18
489.2030640	0.07
495.2160645	0.16
496.4626465	0.05
505.1945801	0.28
513.2223511	0.05
521.2610474	0.15
530.4825439	0.16
531.2271118	1.07
532.9324341	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.2137
Annotation	Salicifolioside A
Peak:m/z	Relative Intensity
178.9626160	0.07
219.7982178	0.04
229.2486267	0.10
243.2301636	0.30
250.5169525	0.06
256.4697876	0.03
257.1965942	0.06
265.0090942	0.05
281.2617188	0.06
287.1327209	0.19
289.4263916	0.05
291.7313843	0.19
293.4598389	0.06
299.6192627	0.08
300.2446899	0.15
301.0989990	2.57
302.1870728	1.25
305.4243164	0.04
324.2866821	0.10
327.1407166	0.06
330.9799194	0.05
337.1091919	0.07
361.4797974	0.03
369.2788086	0.09
373.1456299	0.03
374.2374268	0.28
385.3162842	0.17
393.8845825	0.09
395.3131714	0.07
401.1992188	0.06
402.4245605	0.20
445.2157593	0.12
446.6225586	0.17
450.4067993	0.05
463.1942139	0.65
464.4025269	0.12
465.1156616	0.26
471.2243652	0.09
474.3181152	0.02
477.4394531	0.11
491.4109497	0.32
492.5756226	0.03
493.1959839	0.04
505.2904663	0.13
509.6820679	0.38
510.4762573	0.11
518.1254272	0.08
521.3834839	0.72
522.5735474	0.15
533.3667603	1.51
534.3091431	0.24
537.2714844	0.19
537.8743286	0.06
539.2470093	0.22
540.2990723	0.28
550.3418579	0.09
554.2441406	0.15
556.2997437	0.13
563.3757935	0.29
566.4591675	0.08
575.3018799	0.19
579.4447632	0.05
581.2679443	100.00
582.2857056	8.13
583.6277466	0.08
603.8057861	0.22
605.2549438	0.09
606.2534180	0.23
607.2160645	0.25
607.9442749	0.31
608.6232300	0.05
610.3471069	0.11
626.1529541	0.28
627.1441650	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.2665
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0488129	0.40
211.0133057	1.12
213.0992584	0.22
223.1048126	0.19
234.7903900	0.18
241.1809387	0.19
248.8005981	0.06
255.2028961	0.11
265.1192017	0.12
287.1670227	0.53
295.2940979	0.30
313.1702881	3.44
329.1898193	0.03
331.1842346	0.30
340.3756104	0.14
357.4525146	0.77
375.3518677	9.30
377.1823730	0.08
405.4515991	0.04
411.1529541	0.20
417.2163696	0.23
422.3318481	0.04
436.8424072	0.05
439.2412720	0.12
441.4492188	0.07
450.3153687	0.06
451.4920654	0.10
464.3303833	0.18
471.4665527	0.16
480.3392334	0.50
481.4781494	0.12
482.3943481	0.04
491.3943481	0.31
502.3959351	0.51
503.7283936	0.08
509.2273560	0.91
526.3355103	0.98
527.3876343	3.17
531.4292603	0.09
550.4502563	0.06
555.5503540	0.28
563.7620850	0.21
569.4718628	0.05
581.4044800	4.15
584.4728394	0.30
595.4872437	0.11
601.4747314	0.16
602.3787842	0.48
603.1455688	0.08
609.7789307	0.11
611.4857788	0.40
613.2788086	0.26
617.6953125	0.27
627.4961548	0.32
628.4049683	0.23
635.6639404	0.35
643.6597290	0.97
644.3869019	8.10
645.4081421	0.56
652.6699829	0.06
653.3923340	0.60
657.4816895	1.30
671.3703003	30.69
672.3391113	0.41
689.4334106	100.00
690.3669434	14.91
691.0939331	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.8824
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8562164	100.00
183.0476379	0.11
212.7389832	42.58
213.4499207	0.04
228.1207581	0.23
250.1340027	0.10
251.1269531	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	488.3141
Annotation	Unknow
Peak:m/z	Relative Intensity
162.0459442	0.06
162.9317322	0.10
168.1700897	0.04
173.0736237	0.11
174.0902100	0.07
178.7461548	0.14
183.1209412	9.58
184.0775452	0.16
194.9292297	0.05
211.0543213	15.61
212.2337341	0.43
217.1374817	0.08
223.3614502	0.09
247.2669220	0.04
250.0303040	0.03
265.0131226	0.07
268.0967102	0.12
280.0001221	0.29
288.2358093	0.19
294.2587280	0.30
295.3310852	0.40
300.5756836	0.33
302.6136780	0.14
304.2734680	0.73
308.2476196	0.62
309.0308228	0.09
309.6832886	0.06
315.3854980	0.07
316.7313843	0.74
320.1934204	0.21
322.1875000	0.69
323.3574829	0.25
327.1940918	1.26
329.2656250	0.21
330.1191406	0.15
334.3005371	0.34
336.4891052	0.46
339.8040161	0.34
351.6137695	0.36
352.2817383	0.30
353.8352661	0.06
356.3047485	0.12
357.2221069	0.23
359.3026733	0.03
365.1510315	0.88
365.9211121	0.43
367.4845581	0.17
374.3889771	0.81
376.1192932	0.05
377.7243347	0.10
379.9581909	0.13
381.5068665	0.11
383.3241272	28.91
383.9582825	4.44
391.4519348	0.23
393.1607971	0.49
394.4992065	0.16
399.2335510	0.05
399.9925537	0.05
402.1770935	0.03
406.2004089	2.55
407.8511963	0.68
413.3979187	0.38
421.5622559	3.54
422.7019958	1.67
423.9970093	1.35
427.3035583	2.47
428.2908630	0.75
429.7349243	0.31
431.9333496	76.06
432.8898926	0.16
434.0741882	0.32
436.6238098	0.18
440.9423523	0.15
442.1315613	1.44
443.6286621	0.23
452.3613586	0.09
454.0935364	0.43
458.7428589	0.19
459.7203064	0.39
460.4358215	0.35
463.4488220	0.25
464.2707825	0.27
468.0956421	0.11
470.1173706	0.91
472.4678345	0.17
474.5001526	0.25
479.8043823	0.42
490.3388977	0.13
549.3447876	0.81
555.4475708	2.78
556.5032959	0.41
573.4432983	0.20
588.4348145	0.39
595.8259888	0.10
630.6931152	0.07
632.3117065	0.70
633.4216919	0.26
662.3958130	0.17
668.4682007	1.05
669.4662476	0.43
677.7139282	0.05
703.6508789	0.11
747.5211792	0.88
748.5077515	0.06
765.5529175	100.00
766.5411377	14.40
767.2814331	0.02
814.6261597	0.10
842.0708618	0.10
842.7186890	3.72
843.6250000	0.59
861.6972656	0.06
862.5168457	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.24
Annotation	Swietenin F
Peak:m/z	Relative Intensity
214.9369354	0.32
257.1069336	0.05
258.2249146	0.06
265.3922119	0.12
295.1135254	0.06
343.4658203	0.26
363.0162964	0.08
365.3328247	0.14
387.0272217	0.16
409.5470581	0.53
421.0554810	0.18
457.3577881	0.11
467.6068115	0.11
477.8475952	0.04
493.0441895	0.10
506.2413940	0.26
507.4779053	0.12
533.4949951	0.11
535.3984985	0.26
537.3638916	100.00
538.0530396	0.57
539.7172241	0.30
545.5546265	0.29
549.5555420	0.29
550.2534790	0.23
552.6450195	0.11
553.9691162	0.08
555.3489990	0.54
562.2805176	0.08
567.0302734	0.58
567.7334595	0.46
568.6199341	0.86
569.6160278	0.10
576.8025513	0.05
580.4747314	0.54
581.5174561	0.14
584.6667480	0.25
590.6194458	0.30
594.9918823	0.05
595.6126099	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.16
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
176.8395844	0.09
181.0377502	0.29
184.2654114	0.05
185.2873840	0.08
198.9140930	0.42
205.0894165	0.19
209.0190430	0.66
211.0390320	2.08
217.1661224	0.05
231.0074310	1.93
234.9917297	1.18
256.0834045	0.48
256.8475952	0.08
257.4900818	0.14
262.1885681	0.06
271.1432495	0.04
272.1611938	0.17
274.1239319	0.14
279.5715637	0.16
280.2019958	0.14
288.0485229	1.26
298.0456238	0.52
306.1238403	0.27
320.1256104	0.04
322.1384888	0.59
325.0045166	0.12
337.1558228	1.27
338.0338745	0.22
355.1442261	100.00
363.3861694	0.07
372.2513428	0.14
390.0737305	0.14
391.0874023	0.39
405.0487061	0.04
409.2551880	5.72
417.6196289	0.17
431.1979980	0.12
432.8537598	0.10
451.2202148	0.57
452.3134766	0.18
463.1436768	0.14
466.2159424	6.82
480.2572021	0.04
484.1732178	71.69
484.7835083	0.41
490.4837646	0.04
511.2805176	0.14
520.2178345	0.04
522.5127563	0.27
523.1560669	0.23
538.2482300	2.61
577.3114624	0.62
595.2622681	22.25
595.9196777	0.04
613.5485229	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.1531
Annotation	(-)-Acaterin
Peak:m/z	Relative Intensity
60.9662285	0.03
64.8935165	0.03
66.7651367	0.52
68.9275360	0.45
70.9091339	1.04
78.9701080	0.39
81.0279617	0.43
82.8504639	87.41
84.9054718	1.37
86.9838486	0.19
88.7647552	0.06
90.7581177	0.07
93.0415649	2.08
94.9095917	2.69
96.9632263	7.84
98.9152679	8.43
100.8850555	0.25
102.8363495	0.08
104.9372711	0.87
107.0097656	3.53
108.9918976	39.44
110.9006500	22.38
113.0061035	1.68
114.9118042	0.28
119.0446167	1.12
121.0400238	9.03
123.0011139	7.64
125.0422668	6.68
125.9491577	0.04
127.0359650	1.34
131.0261383	1.85
133.0645905	11.74
135.0263367	13.51
136.5037231	0.33
137.1203461	1.45
137.8822479	0.08
139.0191498	2.83
140.9531403	1.20
145.0115356	0.55
147.0545502	1.65
149.0748138	12.53
151.0762787	77.51
152.9799347	34.05
154.0872955	0.30
155.0759125	0.32
160.0134125	0.07
160.9092865	0.40
163.0728760	7.04
163.9637604	0.30
164.9152222	2.20
167.0391388	100.00
168.1183624	0.21
170.8424988	0.09
173.1245728	17.14
177.0734406	1.89
179.0075989	0.03
181.0482178	3.07
188.3664551	0.13
189.3070679	0.03
191.0947113	94.21
192.1599274	0.13
200.1221771	0.11
209.1409607	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1045
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0709686	0.31
189.4932709	0.17
191.2642059	0.03
219.0654602	3.40
231.0744171	0.62
237.3651276	0.18
239.9941101	0.21
249.0269928	0.12
253.2022247	0.12
255.1073914	0.99
271.3952637	0.19
272.4402466	0.13
275.1228638	1.05
281.1538086	3.89
293.1177368	17.02
297.1738281	3.84
323.1421204	0.25
333.3909302	0.08
336.0805054	0.09
341.1117554	74.38
345.1605225	0.11
360.1684570	0.08
368.9932861	0.23
373.2396240	0.07
375.2095337	0.10
411.1838989	0.06
429.0921631	0.39
430.1358643	0.05
437.2331543	0.12
455.2558594	0.66
459.0432129	0.84
459.7858276	0.35
467.2695923	0.24
471.3079834	0.15
473.1386719	100.00
477.3526001	0.06
480.3041382	0.20
502.0607300	0.06
503.0978394	0.32
530.1467896	0.13
538.4657593	0.13
546.7907104	0.85
547.4535522	0.82
557.1437378	0.10
559.4527588	0.11
574.1889038	0.21
588.0723267	0.24
589.0675659	0.07
590.6226807	0.09
591.8466187	0.10
599.3600464	0.40
603.3859863	0.24
616.4841919	0.38
617.5680542	0.06
635.2061768	4.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.2058
Annotation	Glochidacuminoside C
Peak:m/z	Relative Intensity
128.0767822	0.04
128.8836670	0.03
130.9306183	0.04
132.9587402	0.03
135.0092621	0.11
137.0142975	0.47
142.9036865	0.13
145.1237335	0.15
146.9956512	0.43
149.1097412	3.64
150.0641785	0.50
151.1034698	6.15
152.1581726	0.68
157.1018524	0.08
157.9730682	0.07
161.0208435	0.07
163.2319489	0.27
165.0408325	9.66
166.0509186	1.14
171.0624847	0.02
173.1478119	0.26
174.1515808	0.36
175.0697021	0.06
176.0459442	0.05
177.1227112	0.03
180.9707031	0.17
187.1671143	0.04
187.9635620	0.07
191.0171051	5.72
192.1889648	0.81
193.2590027	1.85
194.2333679	0.20
203.0234680	0.06
209.1241455	100.00
210.1726227	13.24
212.8372040	0.07
230.7449646	0.07
241.1146545	0.03
242.5018005	0.10
245.3052673	0.04
248.2200928	0.13
249.1218872	0.05
251.0687256	0.02
253.9707642	0.03
261.1263733	0.05
263.2735596	0.06
264.2034302	0.05
264.9931030	0.14
269.2392273	0.07
273.2008667	0.10
281.1520081	0.10
282.2381287	0.13
283.2781982	0.04
285.0681152	0.17
288.5839233	0.02
295.0988464	0.09
299.2740784	0.26
302.7103882	0.05
303.4563599	0.05
305.0681152	0.02
309.0509338	0.06
311.4063110	0.07
317.0992432	0.03
333.2321167	0.24
335.3263855	0.14
336.0052185	0.12
337.1595459	0.08
351.4768066	0.06
353.0885620	0.08
355.4412231	0.08
359.9435425	0.18
365.1736145	0.05
376.2085266	0.12
377.2487793	0.45
378.2359924	0.16
386.3521423	0.02
395.0887756	0.32
396.2380676	0.19
396.9678040	0.23
399.1423035	0.07
400.5755310	0.02
403.3583374	0.37
404.4198303	0.05
405.3206482	0.03
407.1793518	0.05
410.6281433	0.10
411.4598694	0.06
412.0920105	0.04
413.2796936	0.16
421.1490784	2.26
422.1714783	1.04
425.5411987	0.04
428.3522034	0.03
431.0238037	0.02
437.1806946	0.03
438.4917297	0.41
439.1613464	2.90
440.1899414	0.84
444.3091125	0.02
448.7715454	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2209
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.7464447	1.52
97.26955414	0.30
109.1733551	1.84
110.8349075	1.35
113.1175613	0.84
114.7987289	0.21
116.6139603	0.46
119.2137756	0.54
120.9058151	1.90
123.023407	1.08
125.2040253	0.53
126.7323151	1.27
129.0871277	0.91
133.045517	0.52
135.0832367	0.23
138.8415985	0.89
141.1732788	0.87
142.9439697	2.46
145.2258301	0.25
147.0992737	0.99
148.8557739	0.84
150.9207458	0.25
155.1444397	1.95
156.7252045	1.08
160.9504242	0.82
163.05896	1.06
167.1300049	1.45
168.9440918	0.56
171.0296478	2.81
172.7392426	0.80
176.975647	2.96
178.0796509	0.15
179.0685425	1.15
181.0948944	0.93
183.050415	3.92
185.2033081	0.54
187.1665802	1.39
189.2740784	0.47
191.1599731	1.81
193.0443726	1.28
195.09552	0.75
196.8138275	2.85
199.2436676	1.30
201.1429596	1.47
205.0713196	0.70
207.3919067	1.55
209.1329651	0.93
211.0266113	3.48
215.0940247	1.02
217.0294495	0.92
221.0015564	1.41
223.2481384	0.74
224.9671936	2.49
227.1386414	1.10
229.2503662	0.19
233.2020874	3.46
235.3802185	0.17
236.966217	1.00
238.9441528	1.56
241.2154236	0.25
246.7567749	0.34
247.4301758	0.30
248.568573	1.22
249.2050781	0.67
250.7114258	0.43
251.365448	4.74
253.1396484	4.62
255.0578613	0.35
257.089325	0.93
261.9862061	0.51
264.9283447	1.42
267.1332397	3.71
269.2685242	2.92
275.2165222	37.19
276.3219299	0.27
283.0587769	1.02
288.9110107	0.53
293.208313	100.00
293.8978882	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	368.0047
Annotation	Unknow
Peak:m/z	Relative Intensity
131.6965790	0.04
135.1159058	0.06
139.8160248	0.25
143.9264221	0.05
146.0806122	0.14
149.2205963	0.12
155.8354492	0.04
156.8685455	0.25
157.8252258	0.15
159.8108673	0.03
168.1417847	0.01
169.9900970	1.83
171.9094849	0.37
174.2796936	0.03
174.9760742	0.07
176.0462799	0.47
176.8767395	0.03
179.3236389	0.16
184.1237793	0.03
185.8647003	0.42
186.9599304	0.21
188.1187439	0.07
188.9875031	0.09
190.0613556	0.18
192.0684967	0.06
197.9758606	0.09
199.9093323	1.32
201.9254761	0.35
202.9453583	0.04
208.9677429	0.14
211.8983154	0.12
213.8723450	0.65
217.9904633	1.47
219.2858276	0.04
219.9775696	0.56
226.0832825	0.04
227.8821411	0.65
229.9132690	1.06
231.1663818	1.14
231.9795532	8.31
232.8172302	0.15
234.2723694	0.02
242.2292480	0.21
243.9569397	100.00
245.2401733	0.18
245.9092407	0.03
247.8799438	0.03
249.0965881	0.19
250.3280029	0.21
255.8341980	0.06
257.8533936	2.19
259.9812317	0.06
261.9973145	2.50
262.9652405	1.09
264.0407410	0.26
270.1225586	0.06
270.9363708	0.06
274.0039368	10.81
275.0662842	0.23
275.8989258	0.14
277.2227478	0.08
279.9692993	3.30
280.9922791	0.16
288.1115723	0.72
290.0535278	0.04
292.4364014	0.49
293.2152710	0.27
294.0861206	0.31
302.1209717	0.05
306.0691528	10.13
307.7266846	0.20
320.0699768	1.59
324.1170044	0.36
336.9592896	0.12
338.0088196	1.22
349.0958557	1.64
350.0489502	25.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	646.8554
Annotation	Unknow
Peak:m/z	Relative Intensity
214.8946838	0.19
245.0366516	0.29
260.9870300	0.08
273.0359802	0.85
289.0094299	9.83
290.7843628	0.05
304.9415283	4.10
312.5107422	0.13
325.0261230	0.06
346.7667847	0.16
386.9506226	0.34
403.0236206	12.11
415.0598145	0.10
418.9851074	25.36
444.0397949	0.35
498.3316040	0.13
500.9529419	0.25
502.1922607	0.25
515.7674561	0.10
516.9364624	3.32
531.1286621	0.99
532.8814087	100.00
533.5165405	0.36
549.6551514	0.08
550.9696045	0.07
572.1056519	0.16
572.8262329	0.28
589.9801636	0.08
590.9679565	0.34
599.7088623	0.88
600.5199585	0.19
601.1929932	0.16
601.8717651	0.12
610.5554810	0.08
646.8728638	4.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0777
Annotation	3-Galloylgallocatechin
Peak:m/z	Relative Intensity
134.9247131	0.58
136.9035339	0.04
139.1233215	0.07
145.2830505	0.09
147.0560303	0.13
148.8635101	1.59
155.0803528	0.06
159.9721680	0.13
160.8638611	0.38
163.0292206	16.86
170.9198151	0.28
175.1735840	0.11
177.2382202	0.09
179.0419922	5.07
187.1122131	0.04
189.1209412	0.15
190.2293243	0.16
191.0861206	0.48
203.0399780	3.88
205.1510315	0.51
215.2354889	1.16
219.1139526	8.75
221.2089386	0.20
231.1332092	0.77
233.1416931	1.66
249.2457581	0.13
259.1037598	1.27
269.4489136	0.16
275.1099548	1.56
277.1548157	47.84
293.1736450	69.64
295.0332947	100.00
310.4941406	0.31
311.1251831	3.00
325.0886230	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.052
Annotation	Unknow
Peak:m/z	Relative Intensity
142.0234833	0.07
155.4204712	0.07
157.8609924	0.51
169.7403717	0.21
182.0462341	0.06
183.8985291	0.21
185.9334717	0.80
187.0548401	0.16
187.8914490	0.21
189.0440369	0.04
197.8713684	0.08
199.9996643	0.04
200.9434357	0.05
201.8855286	0.44
203.8877563	0.05
209.1707916	0.23
210.9641724	0.06
211.9923096	4.04
214.1257019	0.04
215.1608276	0.05
217.1267548	0.33
218.0184326	0.33
223.9297485	1.24
225.8900146	0.15
228.0549622	0.14
228.8692169	0.02
229.8158264	0.15
232.8686829	0.26
234.0694580	0.15
241.2850342	0.06
242.1261292	0.41
244.0543213	0.09
245.9797058	0.04
249.1061707	0.14
253.0338135	0.03
254.0354004	0.88
255.0415344	0.06
255.9711304	0.13
258.2758789	0.07
258.9981689	0.04
260.2210693	0.03
261.9419556	5.48
263.0075989	1.41
264.1362000	0.87
268.9675903	0.04
269.9347839	0.03
271.8699951	0.35
272.8098450	0.11
274.0242615	0.10
278.1978760	0.17
279.9576416	9.64
280.8141174	0.35
287.9144897	0.02
289.8472595	0.45
294.0435791	2.09
298.9978943	0.04
300.0082397	0.52
304.1003418	0.08
305.0025635	0.10
306.0629883	1.18
307.1941833	0.48
308.8500366	0.03
310.1226807	0.04
317.8204956	0.36
318.4252319	0.33
322.1094971	2.22
322.9649353	0.25
324.0991211	0.08
330.1847534	3.70
331.1027832	0.16
333.4702454	0.13
334.2377014	0.74
335.1370850	0.88
336.0633240	2.45
337.1115417	0.26
339.3012085	0.17
344.2931213	0.05
346.2146912	0.21
348.0617676	100.00
349.1871338	0.46
350.4617004	0.12
352.0715332	0.15
360.0837708	0.59
361.9107666	2.45
362.5261536	0.02
365.1968994	0.11
366.0497437	0.63
367.1706543	0.09
372.1728821	0.02
374.1130981	0.10
378.2474670	2.80
379.2274780	1.52
384.9554749	0.04
392.3033752	0.04
393.1712036	0.14
397.9019470	0.04
398.9179993	0.07
411.2432251	0.71
412.2149353	0.02
413.9253235	0.04
421.9436646	0.04
428.1214600	0.17
435.2583313	0.08
436.1933899	0.86
441.6779785	0.15
442.3172913	0.06
454.1114197	42.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3079
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
165.0122070	0.04
179.0881348	0.16
216.9412231	0.15
227.2307587	0.19
233.3079224	0.61
235.1010437	0.83
253.1570435	9.43
255.1850891	0.06
275.4075317	0.61
277.2478333	100.00
310.2722168	0.56
333.3975220	0.12
351.2106934	0.13
385.1167603	0.17
409.2367554	0.09
423.3850708	0.13
425.2561646	0.06
437.7998657	0.04
451.1832275	0.10
453.4996948	0.35
458.8599243	0.06
467.4253540	0.67
469.4231567	0.10
493.6754761	0.11
495.3268433	0.35
515.0636597	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.0993
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
178.9757690	28.43
243.2693939	0.12
249.2150574	0.21
253.2384491	0.05
267.1338501	0.07
277.1203613	0.32
295.0179443	100.00
296.2163086	0.09
307.0767212	0.24
355.2233276	0.15
367.4509888	0.07
387.4476318	0.09
404.7718506	0.02
411.4211426	0.32
429.0882568	1.54
430.1163330	0.10
435.2976074	0.05
456.8447876	0.47
474.4086304	0.08
475.2177124	0.03
534.6285400	0.07
536.1497192	0.14
555.2091675	0.13
571.6567993	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1492
Annotation	Luteolin 7-sambubioside
Peak:m/z	Relative Intensity
193.2026062	0.07
204.0389404	0.11
234.0142059	0.03
249.0260925	0.09
252.1906128	0.18
255.7948914	0.09
264.9936523	0.16
269.1878662	0.16
274.6250916	0.27
279.1766357	0.15
283.0521851	0.04
287.1070251	34.20
296.3283691	0.27
297.0498657	0.17
298.0039673	0.11
298.9328003	0.17
303.2798462	0.04
308.1692810	0.10
313.2138367	0.09
314.3441162	0.69
315.4017944	0.23
316.5447388	0.04
322.4703979	0.03
329.1745605	1.23
332.2346191	0.07
333.2704468	0.04
341.0186157	0.08
353.3955688	0.12
365.1205444	0.24
370.3591919	0.10
371.3539429	0.08
373.2044067	0.69
373.8630371	0.09
379.0183716	0.03
381.2343750	0.08
383.0510254	0.33
389.0443726	0.13
395.1467896	0.11
399.1370850	0.26
401.2177734	0.93
413.9077148	0.21
415.2015381	0.14
417.2698975	0.08
418.1632690	0.43
419.2146606	4.30
428.3971558	0.07
432.2194824	0.18
437.2144165	0.09
449.1668701	100.00
455.0112305	0.08
478.5414429	0.10
489.1672363	0.08
491.2427368	0.21
492.6596069	0.36
494.3716431	0.08
495.0682983	0.03
499.7964478	0.18
500.4690552	0.18
515.3573608	0.18
521.3084717	0.10
530.6517334	0.12
536.5408325	0.09
549.3181763	0.59
552.5612183	0.32
555.4984741	0.10
556.2062378	0.13
558.2357788	0.27
559.0428467	0.48
562.2531128	0.26
563.2556763	0.43
568.4788818	0.20
571.7050781	0.59
581.3956909	0.16
582.2061157	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1925
Annotation	Unknow
Peak:m/z	Relative Intensity
120.9411850	0.08
143.0425415	0.10
145.0513611	0.07
163.0507965	1.26
169.0085754	0.07
171.1914978	0.10
173.0923767	0.06
178.9893188	0.26
189.1197357	2.91
205.1227112	0.09
207.0637665	8.64
207.7904510	0.10
208.9261932	0.17
232.9558716	1.58
251.1193237	100.00
253.3690796	0.05
269.2369995	2.05
278.4046326	0.04
293.1373291	0.12
329.3696289	0.29
341.5000305	0.08
342.1880188	0.06
343.2152405	0.06
353.5268555	0.33
371.4163818	0.20
385.2213440	0.17
387.1145935	0.12
388.2741089	0.13
395.1117859	0.09
412.9668274	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.96162415	0.25
94.78839111	0.60
96.91751862	1.97
98.83102417	0.45
104.9184647	0.21
107.0117798	0.57
110.9602356	0.47
113.1560211	0.86
120.8185577	0.65
125.0940399	0.80
127.0692291	0.72
129.2182007	0.13
135.1638184	0.84
135.8851318	0.21
137.1146545	1.13
139.1066589	1.10
140.9810791	2.08
142.9068451	1.37
147.0279541	0.63
148.9654388	1.01
151.2006531	0.18
153.0860291	1.01
155.0341492	4.13
156.9898376	1.59
162.8830261	0.82
164.6542816	0.85
167.2118683	0.44
169.0896606	1.34
170.9526978	0.15
173.0527802	0.99
174.177948	0.79
175.0362854	0.42
177.1385956	1.69
179.0892029	2.05
180.9285126	0.65
183.0207977	1.61
185.1441345	0.60
187.1128845	1.23
189.2576904	0.34
190.9710236	2.21
193.0565643	0.56
194.9963837	0.62
197.0163879	3.39
199.2204437	0.58
203.0956421	0.34
205.0015564	0.34
206.0703735	0.26
209.1873474	2.12
211.1088562	1.79
212.165802	0.29
213.146698	3.09
215.2159729	1.49
217.0040588	1.22
220.4407959	0.93
221.094574	0.26
221.7910767	0.31
223.1273804	0.84
224.9602356	1.09
227.055542	2.31
230.9142456	1.45
233.1721497	0.13
235.7481995	0.71
237.0680847	10.32
238.0677795	0.28
239.2614746	2.60
241.4011841	2.16
243.0609741	0.37
245.259613	0.26
247.2422485	2.15
249.1316528	1.18
250.0526123	0.26
251.328949	1.90
253.0638733	5.80
253.6802673	0.21
255.099823	3.13
257.3850708	2.00
265.2320557	0.54
266.437439	0.62
267.223053	0.66
270.1092834	0.31
274.2337952	1.27
275.2626343	20.05
280.3557129	0.64
283.4806824	0.89
287.5294189	0.81
293.2039185	100.00
294.46698	1.26
296.2664795	0.25
299.8583374	0.79
301.7406921	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1017
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
134.9938354	0.04
136.9905090	0.04
151.2349243	0.02
152.9449005	1.36
158.3966064	0.03
160.0196991	0.03
162.9206848	0.64
179.0370026	1.00
195.1101074	0.10
203.0619202	0.07
219.1305237	0.02
229.2683258	0.02
243.1884155	0.09
247.0697327	0.22
249.1856079	0.05
253.2641907	0.02
264.5202026	0.06
271.2124023	0.32
274.4832764	0.02
283.0567627	0.01
285.2880859	0.04
286.7082520	0.02
289.0406799	100.00
293.0422058	0.06
296.9443665	0.04
301.1262512	0.64
303.0577087	4.09
303.7734375	0.05
308.3363647	0.05
311.1087952	0.94
313.0441895	1.10
329.3493042	0.12
331.0981445	0.42
343.0190735	0.06
344.3439941	0.03
354.2600098	0.35
355.2426147	1.36
367.0321350	0.12
383.2402649	0.17
385.1373596	0.29
391.0793152	0.09
393.2209167	0.02
401.1520386	0.09
411.0225525	0.36
429.1166077	3.68
447.1356201	4.51
448.4383240	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.1664
Annotation	Unknow
Peak:m/z	Relative Intensity
127.6604309	0.13
149.1213684	0.05
160.9494934	0.18
177.2903442	0.08
179.0690308	0.06
191.0439453	0.10
192.9141083	0.21
201.1165619	0.51
207.0882111	0.22
223.1784668	0.16
225.0378876	0.08
246.1963806	0.17
250.9267578	0.08
272.3869934	0.24
278.0852966	0.07
281.0387878	0.22
295.1566772	0.15
298.3903809	0.07
306.7682495	0.07
317.3418884	0.04
325.2535400	0.08
348.7611084	0.16
353.2778931	0.06
363.2796326	0.38
367.2969360	100.00
369.1975403	0.63
370.5612793	0.15
376.2565613	0.10
383.5897217	0.15
393.0837097	0.40
394.7596741	0.12
395.4523010	0.30
404.2588806	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0721
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
93.0353088	0.59
94.9403229	0.07
100.9960861	0.40
107.9341125	5.95
108.9356689	7.99
112.9675751	1.22
119.0460052	0.31
120.9029922	1.47
122.2519836	0.47
123.0807877	1.35
133.0869446	0.13
134.0600891	0.51
134.9555054	1.73
135.9513855	0.48
137.0230408	0.48
145.1029968	0.23
147.2410583	0.52
150.9662170	5.35
151.9698486	39.51
152.9559631	100.00
158.9208679	0.10
161.0844116	0.82
163.0228882	9.70
165.0262299	12.52
167.2071228	0.17
175.1407471	0.41
176.9280548	1.88
178.9966125	2.76
181.1275330	2.84
182.9779053	0.44
189.0530853	0.17
191.1355896	0.11
193.0618744	0.95
195.0508881	3.93
199.0384827	0.49
205.0430603	0.50
207.0432434	2.31
214.2212524	0.10
217.2364807	0.98
219.0828247	1.04
221.3463745	0.06
223.0668335	0.31
225.1121216	7.33
226.9763184	0.07
237.1053467	1.90
239.2711792	0.18
248.4971008	0.31
249.3486023	0.06
261.3584595	0.10
297.0984497	0.43
298.8918762	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
84.88148499	0.29
104.7482758	3.11
117.25737	1.05
148.8712616	2.20
152.9553375	1.49
179.0064545	3.97
183.2741241	1.05
189.0835724	0.42
191.901886	0.47
195.0410919	0.85
206.2436066	4.57
207.0556335	13.16
208.1524506	7.26
209.1338806	2.88
214.8805695	1.07
222.0088654	11.59
223.1329498	6.26
223.9812927	1.29
233.241272	3.45
234.9816284	0.31
251.0767212	100.00
252.213974	13.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.2681
Annotation	PS(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
150.9250641	0.13
152.9278412	12.16
171.0189056	1.57
240.0050659	0.35
255.5454102	0.20
258.2379761	0.18
279.3096313	0.06
314.6741333	0.36
327.2302246	0.12
341.1602783	0.27
390.6817017	0.39
418.3093262	0.09
426.8968506	0.09
433.2722778	100.00
439.6787109	0.08
442.4435425	0.06
446.3627930	0.48
448.1356201	0.08
465.5941162	0.07
474.0339355	0.55
477.1223755	0.08
482.2730103	0.08
484.2522583	0.14
501.6422729	0.25
502.5161743	0.08
503.5004272	0.15
504.6698608	0.26
520.4997559	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
98.8873596	0.16
101.0046005	0.39
111.0130005	0.50
112.9165878	1.00
114.9464264	1.14
117.1207275	0.03
125.0807343	0.26
126.9043579	0.57
129.0075989	0.70
130.9976654	0.25
136.8480835	0.07
138.9814758	0.22
140.7416687	0.07
142.9500122	0.03
144.8785400	0.07
148.9603882	4.09
151.0377197	0.12
153.1151428	0.04
156.9919128	2.26
167.0484467	0.02
168.9356689	1.27
170.8568420	0.14
173.9779358	1.22
174.9700317	1.09
187.0264893	0.02
190.9039307	0.20
193.1205444	2.56
199.1835785	0.04
209.0679321	0.26
219.1697083	0.06
231.0506897	0.04
238.9655457	0.04
249.2957458	0.07
258.8914795	0.08
260.9420166	0.02
263.0946045	0.04
264.9537048	0.06
275.1700745	0.06
277.1000977	100.00
279.1080933	0.09
287.0776367	0.10
289.1789551	0.15
308.0332031	0.07
319.1063538	1.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.05
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9223785	2.94
115.8549194	0.44
132.9152527	59.66
133.9941711	3.54
135.0621490	4.75
136.0171967	0.81
163.0934906	0.26
163.9070435	0.07
179.0000305	100.00
180.0656891	14.37
187.2262115	0.12
189.0407715	0.14
205.2134399	0.12
215.1180115	0.04
219.9740295	0.02
220.9775085	0.17
224.1645508	0.05
224.9665222	0.07
231.2907715	0.09
234.1150513	0.03
247.0414124	0.04
251.2661133	0.23
252.3463135	0.05
253.1585999	0.23
267.0074463	0.18
268.0643921	0.03
277.2442932	1.02
278.0464172	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0879
Annotation	Scopolin
Peak:m/z	Relative Intensity
109.1247025	0.03
126.7733994	0.30
135.0952454	0.32
145.0013428	0.03
153.0424500	0.01
155.0533752	0.03
161.1028442	0.64
170.7677612	0.01
173.0988464	0.28
174.1780396	0.04
179.0550842	2.99
191.0089417	100.00
220.9309998	0.03
267.2915649	0.05
307.5675659	0.03
309.1715393	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0966
Annotation	Bikoeniquinone A
Peak:m/z	Relative Intensity
128.8806915	0.52
130.7927399	0.03
159.0753479	1.44
162.9460144	0.03
171.1385803	0.14
172.0357971	0.19
178.7037964	0.03
186.5534668	0.07
190.9208984	0.23
209.0367126	100.00
210.1761475	0.03
218.0234833	0.38
219.9548340	0.15
227.1970825	0.03
228.9041138	0.06
230.7740021	0.04
231.8162231	0.02
235.6718445	0.03
248.1752930	0.02
251.4136658	0.02
260.2851257	0.04
262.9742432	0.43
264.0973206	0.13
265.1345520	0.09
266.0971375	0.02
273.0513916	0.08
276.1558228	0.04
277.1423340	0.05
282.8363647	0.03
286.5789185	0.03
290.1708984	0.02
293.0937805	0.04
294.0013428	0.36
295.1311035	0.20
307.4176331	0.06
310.5215454	0.02
318.4398193	0.05
320.0290222	0.09
323.0603638	0.03
330.3314209	0.24
331.1848145	0.06
332.2127075	0.34
334.1923828	0.09
335.0979919	0.10
336.0321045	0.02
339.1917725	0.11
341.0815430	0.44
346.0282593	0.09
348.8981018	0.02
350.2229614	1.04
351.2174072	3.35
352.3579407	0.08
353.0880127	0.13
354.1035767	0.05
358.9493103	0.30
364.2342224	0.03
366.0325623	0.08
368.1804810	0.16
377.0010986	0.21
378.1618958	0.03
379.1710815	0.47
380.9835510	0.03
383.1609802	0.05
392.2299194	0.06
394.1579590	0.27
395.2249451	0.07
397.1172791	0.09
404.0198669	0.08
406.2611389	0.05
407.0850525	0.20
410.0545959	0.22
410.9218140	0.09
412.6853333	0.26
413.3175659	0.16
427.0632019	0.11
430.3163757	0.02
437.1425171	0.05
438.1611023	0.91
439.1719666	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.0675
Annotation	Quercetin 7-glucuronide
Peak:m/z	Relative Intensity
150.9887085	0.79
170.9867859	0.07
178.9813843	1.17
192.9356384	0.17
212.4034729	0.03
215.1355743	0.06
228.9125977	0.03
232.8742371	0.05
257.2252808	0.27
273.0975647	0.07
283.1541138	0.02
299.1773682	0.12
301.1792908	100.00
314.0200500	0.04
433.1393127	0.03
433.9955139	0.09
459.3496399	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0514
Annotation	2-Caffeoylisocitrate
Peak:m/z	Relative Intensity
110.9620819	9.07
115.0699463	0.09
123.9837875	0.36
128.9390259	0.45
135.0762939	1.13
145.0126343	0.04
154.9016418	4.07
160.8562012	0.09
173.0124054	46.64
179.0283051	5.02
182.9946594	0.05
190.9786530	100.00
197.1370697	0.09
200.9768677	0.11
220.1194458	0.24
221.1705933	0.09
233.2725220	0.03
257.4002686	0.08
263.2605896	0.03
264.1130371	0.13
265.2714539	0.10
273.4685669	0.21
274.3112793	0.06
285.3430176	0.09
290.8346558	0.25
295.0137634	0.06
305.9919434	0.05
306.9994202	0.37
309.1258545	0.91
310.0871887	0.06
316.3186035	0.06
317.5222473	0.04
326.3491821	0.06
335.2444458	0.71
336.3188477	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1199
Annotation	Quercetin 3-glucosyl-(1->2)-glucuronide
Peak:m/z	Relative Intensity
193.1448975	0.03
202.9258728	0.05
212.3604279	0.02
228.9627686	0.01
247.2392120	0.02
255.2534637	0.03
265.1670227	0.01
271.0657043	0.03
273.2431335	0.03
285.1340027	0.12
297.3164062	0.09
300.0186157	0.82
301.1103516	23.70
301.7231445	0.21
302.4863281	0.11
310.1784668	0.02
311.4833069	0.04
313.2933960	0.02
314.3506165	0.04
315.2002869	0.17
318.7159424	0.02
325.3385010	0.04
326.1082153	0.04
331.1019897	0.03
337.4755249	0.03
340.9863892	0.07
342.5609131	0.24
343.2734985	1.39
353.1616211	0.02
355.3911743	0.09
365.8944702	0.06
368.0379028	0.01
369.2548218	0.05
371.1307373	0.10
372.1177368	0.02
373.2369995	0.33
379.3113403	0.15
396.3276978	0.02
397.2539062	0.08
409.2315674	0.02
415.4388428	0.03
441.1827393	0.01
444.9424438	0.05
459.5036621	0.06
463.1927490	100.00
474.9334106	0.06
475.5435791	0.04
477.2942505	0.86
478.0300903	0.10
505.3141479	1.77
509.5351562	0.03
517.2965698	0.15
518.1486206	0.02
518.9677734	0.03
522.3292847	0.05
529.2048950	0.22
531.2984619	0.28
533.1489868	0.90
533.7756348	0.03
535.3062744	2.81
541.1375732	0.03
547.2994995	0.68
549.2273560	0.11
559.3006592	1.29
577.0853882	0.09
625.0027466	0.04
639.2855835	3.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1665
Annotation	Unknow
Peak:m/z	Relative Intensity
144.0644531	0.49
149.0170746	0.12
156.9134064	0.04
160.9172058	0.14
175.7777100	0.10
191.0944214	0.14
203.0282745	0.12
204.8694153	0.13
219.9683380	0.12
220.8775940	0.31
242.6820679	0.21
244.0197449	0.77
245.2843323	0.09
251.0678711	0.11
255.0896606	0.04
259.0379028	0.14
262.0991211	0.05
263.0773926	0.70
275.5158691	0.15
286.2485046	0.06
289.2311401	0.12
293.0717163	0.16
303.1495056	0.17
304.2121582	0.14
309.2545166	0.07
310.9002075	0.14
327.1642456	0.62
334.9869995	0.21
346.2255249	0.05
349.2663574	0.07
353.1205139	0.16
354.9669800	0.22
357.3493652	0.09
365.0880432	0.06
367.8824768	0.04
369.5168762	0.05
375.4239807	0.06
379.2950134	100.00
380.2601929	0.08
389.2087097	0.09
396.1396484	0.05
397.3499146	0.20
405.2720032	0.12
407.2119446	0.23
409.0485229	0.10
415.7570801	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1818
Annotation	(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside
Peak:m/z	Relative Intensity
112.8236008	0.20
143.0875092	0.16
148.9334717	0.08
159.2881775	0.06
161.0130615	0.52
165.0780945	7.45
166.9608765	0.03
169.2717285	0.04
173.0909424	0.03
183.1864319	7.64
194.0444336	0.05
207.1236267	0.08
209.1053162	0.64
217.0689087	0.04
221.3398132	0.04
225.3505249	0.16
227.0847778	100.00
229.1713257	0.06
234.0746765	0.11
239.3063965	0.03
241.3055725	0.05
245.5948486	0.15
247.5097351	0.05
251.2141113	2.69
255.2504883	0.05
261.0940247	0.02
263.1523743	0.38
267.4360962	0.03
269.1395264	0.91
271.5634155	0.03
272.1830444	0.42
279.0915222	0.11
281.2150879	0.41
289.0578918	0.06
291.2531433	0.46
293.2094727	0.74
299.2189026	1.06
303.0868835	0.07
304.2055054	0.12
307.5504150	0.46
311.1387024	0.08
314.6155396	0.13
317.1135254	0.15
323.3104858	1.03
327.3365173	0.26
329.1129761	1.55
335.3080139	0.95
343.1074829	0.32
345.2420654	0.05
346.9636230	0.08
351.4978943	0.07
352.6033936	0.30
353.3137512	0.90
354.8461609	0.04
357.1774902	0.17
359.6296997	0.16
360.3763123	0.05
361.1298218	0.12
370.6142273	0.09
371.3486023	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.1719
Annotation	Apigenin 7-(4'',6''-diacetylalloside)-4'-alloside
Peak:m/z	Relative Intensity
191.1666107	0.13
203.1163025	0.87
204.1439209	0.18
213.3300629	0.03
221.0085754	0.02
227.0178986	0.04
229.3049164	0.02
252.9378662	0.07
255.0959320	1.06
256.0687256	0.12
286.0851440	0.04
291.2703552	0.01
299.1437378	1.36
300.0096436	0.22
312.7125244	0.01
317.1464539	1.02
318.3029785	0.12
323.1582642	0.21
331.2546997	0.02
335.1758118	0.94
336.0941162	0.15
337.1801453	0.04
338.0483398	0.07
339.2455750	0.03
341.1633606	0.73
342.2473755	0.15
353.1512451	12.24
354.1837158	1.62
379.1522827	0.14
383.0100708	0.07
384.3073120	0.06
395.0523682	0.09
427.3082275	0.02
462.0872803	0.01
469.1875610	0.11
471.1234131	0.12
473.2952881	0.07
479.2437744	0.07
481.4938354	0.05
496.1569214	0.02
497.3385010	1.06
498.2431030	0.06
503.3671875	0.18
504.1819458	0.02
505.2789307	0.04
506.4194946	0.03
515.1750488	100.00
516.1517334	13.23
516.8125000	0.13
518.4290771	0.03
530.3347168	0.05
531.4609985	0.05
541.3630371	0.03
545.3794556	0.08
546.6705933	0.09
555.4002075	0.03
557.4904175	0.07
558.3841553	0.13
562.5682373	0.05
573.5669556	0.02
579.3773193	0.06
590.6750488	0.03
591.3132935	0.04
593.3286743	0.66
601.1681519	0.11
629.3121948	0.04
631.1245117	0.12
633.6503296	0.06
634.4920044	0.01
635.7457886	0.01
643.3146362	0.02
659.5343018	0.12
678.1969604	6.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	376.2321
Annotation	Bacithrocin B1
Peak:m/z	Relative Intensity
106.9376831	0.04
114.8034821	0.06
116.9489288	0.17
118.9724274	0.64
121.2035141	0.48
123.1014252	0.11
129.0921478	0.04
133.0071259	1.14
135.0327606	0.18
137.1997681	0.18
140.9976501	0.22
149.0066528	0.03
150.9531555	0.20
153.9378815	0.06
155.1369934	0.04
155.8985138	0.07
158.7569275	0.02
160.9247131	3.54
167.9017639	0.03
169.2529449	0.11
177.0904541	0.06
178.4660797	0.19
179.1187592	1.95
196.1304474	2.32
196.9417419	0.07
206.1130676	0.07
208.1028137	0.09
214.1541290	100.00
222.3197632	0.15
224.1824036	0.34
226.3313293	0.18
230.2384644	0.12
241.0861816	0.03
243.1320190	0.29
255.2397461	0.13
256.1719971	0.58
259.2212830	0.24
261.1633301	0.16
262.1350708	0.24
265.2131958	0.05
269.4321899	0.11
274.8880615	0.09
275.9470825	0.19
279.1235962	0.10
280.2828674	0.27
286.1818237	0.27
287.0662231	0.04
288.0505371	0.03
292.2529297	0.84
293.1356201	0.04
295.0491333	0.35
300.8529053	0.08
302.1900330	0.12
304.4085999	0.85
309.7022705	0.15
310.3408203	0.35
313.7274780	0.20
317.5061646	0.07
322.3513184	1.39
329.5309448	0.29
331.0542297	0.14
332.3939209	0.03
340.1429443	2.84
340.8188782	0.20
341.4336243	0.16
345.1280212	0.09
346.2299805	0.09
347.2590332	0.04
353.2562561	0.11
356.5226746	0.04
358.3736267	5.49
359.2057800	0.13
360.5136414	0.08
361.3108215	0.36
365.3908386	0.09
367.0329590	0.19
379.2189636	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1298
Annotation	Hesperetin 7-O-rhamnoside
Peak:m/z	Relative Intensity
135.0234528	0.27
137.0747223	0.03
151.9692078	0.34
153.2207642	0.11
162.8721008	0.12
164.8768616	0.03
179.1976776	0.04
190.0484161	0.07
195.0361023	0.16
197.0461426	0.64
198.0970917	0.09
209.0917358	0.06
213.1420746	0.09
215.4215088	0.08
217.0138397	0.07
225.2038422	0.12
227.2459717	0.05
229.0263062	0.15
241.1739197	0.16
243.0568848	100.00
245.0493164	0.04
253.0466919	0.04
284.0969849	0.16
285.1766357	3.58
289.4163818	0.22
299.9654541	0.26
301.1692505	0.06
312.1984558	0.03
324.1614075	0.08
329.1617432	0.17
335.3575745	0.12
339.4042358	0.19
341.2177124	0.35
351.0012817	0.25
354.5169373	0.22
355.1325989	0.28
357.5975342	0.10
358.2583008	0.19
359.1434937	0.27
362.4324341	0.14
369.0229797	0.09
371.2212219	0.07
373.3948364	0.03
374.9808655	0.06
375.9719543	0.09
380.0574036	0.02
381.4884949	0.12
387.4119263	0.29
393.4117737	0.18
400.2773132	0.13
401.4345093	0.06
403.4498291	0.17
404.4828796	0.63
405.0909119	0.02
407.8129578	0.04
409.3188171	0.10
411.2161560	0.05
411.9446106	0.13
415.0810242	0.07
418.9283752	0.20
425.2445984	0.17
426.9798889	0.05
429.0284119	0.38
429.7499695	0.17
431.3135071	0.06
432.5344849	0.09
448.3249817	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.0177
Annotation	Unknow
Peak:m/z	Relative Intensity
84.9324951	0.30
87.9153290	0.50
112.8833313	0.37
114.6008911	0.40
137.8858337	0.23
149.3144684	1.02
150.9968719	0.44
153.0133514	1.41
154.8784637	1.63
157.3111877	0.11
166.2485809	6.66
166.8731232	100.00
169.0459442	0.40
169.7072296	1.25
171.7192841	15.71
177.2181854	0.69
179.9214325	0.14
182.9830475	2.53
184.4653778	2.19
189.6610718	1.18
195.1573334	2.64
198.6623993	0.46
201.3819733	1.41
202.9559479	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.2189
Annotation	Kunzeaphlogin D
Peak:m/z	Relative Intensity
182.1179810	0.04
184.9390106	19.41
185.9732819	0.81
195.0507202	0.16
196.1319580	0.04
203.0165405	0.06
213.1620178	0.09
247.2112274	0.02
286.0975952	0.04
297.3620605	0.03
353.0684814	0.04
357.4787598	0.30
358.3769531	0.31
373.5720215	0.03
375.2940674	100.00
376.2905273	17.31
396.5694580	0.03
443.3251953	0.04
447.5938721	0.04
476.2948608	0.10
480.5969238	0.06
487.4586792	0.25
489.4712524	0.17
515.7514038	0.09
517.3423462	0.41
518.4086304	0.17
519.4096069	0.03
520.5770264	0.11
526.1480103	0.10
543.6035767	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1034
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.9639282	0.56
87.9219055	100.00
128.1052704	0.17
128.8200531	0.28
146.0734711	11.66
173.8979340	0.67
174.7523193	0.31
200.3014069	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1696
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
214.25354	0.04
229.290741	0.11
233.1285858	0.06
235.1863861	0.03
271.0542908	28.23
271.9115295	0.20
295.0845337	0.05
313.4326782	0.38
330.0708008	0.12
330.8596802	0.10
332.9202881	0.05
337.0957031	0.12
348.7401123	0.06
355.3286743	0.10
363.2637329	0.13
372.3493652	0.08
387.1963501	0.26
397.4075317	0.20
398.9344482	0.25
400.390564	0.16
402.411377	0.02
403.3838501	0.15
414.8377686	0.10
417.3087769	1.41
424.2088623	0.04
429.2832642	0.07
433.1028442	100.00
433.7697754	0.25
442.1895752	0.03
449.0212402	0.08
461.3891602	0.06
470.7376709	0.06
480.6389771	0.11
488.625	0.05
489.9574585	0.17
499.3775024	0.06
503.4453735	0.07
520.973999	0.23
543.0332642	0.04
547.4772339	0.09
549.0460205	0.11
551.2147217	0.11
560.4347534	0.22
561.2059326	0.31
564.2160034	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	656.2349
Annotation	Unknow
Peak:m/z	Relative Intensity
183.7860413	0.18
186.2651978	0.09
187.1160736	0.06
187.9380493	0.09
188.9806976	0.15
192.0315552	0.21
195.1302948	0.39
197.9991302	0.50
200.0901489	0.04
201.1177521	0.47
201.8847809	0.05
203.2431030	0.05
204.9755707	0.13
205.9860077	0.16
207.0374146	0.15
209.0380402	0.73
210.1728210	0.38
211.9909058	0.27
214.8183289	0.10
217.9799194	0.14
219.2014313	0.46
221.1227264	0.13
222.0513916	0.44
223.3326111	0.08
224.1572876	0.23
225.0397186	0.52
226.0716248	0.25
227.1757355	0.11
229.1062012	0.08
231.1302185	0.14
232.1378479	0.31
232.8500824	0.04
234.1526642	0.34
235.1470184	0.18
237.2262421	0.03
238.2235413	0.22
239.2504883	0.17
241.2512817	0.05
242.3268738	0.14
243.2934875	0.33
243.9513550	0.43
246.3929749	0.03
248.1398468	0.19
249.1608276	0.06
250.0124359	0.50
251.3055115	0.41
252.0758514	0.86
253.2740173	0.08
256.6319275	0.05
258.1547241	0.10
259.1279297	0.06
260.2554626	0.15
261.3342285	0.33
262.2131958	0.26
263.2396545	0.07
264.2013855	0.32
265.2379150	0.07
265.9010010	0.07
267.1914673	0.19
268.2686157	0.30
269.2534180	0.50
272.1361084	0.24
273.0943604	0.09
274.0797729	0.35
275.0717773	0.15
276.2636108	0.49
277.3259277	0.54
279.6836853	0.26
281.9639587	0.06
283.2269287	0.39
284.1301270	0.17
285.4311218	0.32
286.1563721	0.25
287.1839600	0.43
288.3214722	0.06
289.2388000	0.31
290.5843201	0.11
292.1273804	0.11
293.3170776	0.36
294.4242859	0.14
295.3884277	0.14
296.1662903	0.28
298.0062256	0.12
299.1461792	0.37
300.1861572	0.40
301.2690125	0.34
302.3732300	0.02
303.3026733	0.15
304.1783447	0.44
305.3105469	0.47
308.2084351	0.18
309.2376099	0.43
310.0292664	0.18
312.2556763	0.34
313.2582397	0.13
314.2991943	0.07
316.0712891	0.15
317.1916504	0.37
318.2573242	0.51
319.4178467	0.11
320.1373291	0.51
321.0646362	0.16
322.2934875	0.22
323.4031067	0.05
326.5431519	0.56
327.4140015	0.20
328.9174805	0.19
329.5660400	0.21
330.3998413	0.89
332.3313599	0.05
333.0478516	0.28
334.3294983	0.08
335.3651733	0.09
336.2947388	0.90
338.1613159	0.13
342.1442261	0.11
343.2171021	0.18
344.2820435	1.30
345.5385132	1.18
346.3461304	7.59
347.1926270	2.44
348.2546387	3.38
349.3980713	0.99
350.2674561	0.05
353.5304565	0.16
354.4176636	0.77
355.4243774	0.62
362.4292603	1.08
363.3143311	1.50
364.3493652	0.34
365.3914795	0.16
366.2393799	0.45
367.4082642	0.07
368.4180298	0.10
370.2770386	0.54
370.9263916	0.13
372.2830811	5.08
373.2739258	1.66
374.2931519	0.05
375.1224976	0.21
376.1709595	0.05
377.3405151	0.21
378.2377930	0.16
379.0061646	0.08
380.1907349	0.21
384.4276123	0.22
386.3049927	0.06
387.4014282	0.23
388.3172607	1.74
389.4962158	0.71
390.2896729	2.74
391.3283081	1.10
392.6331177	0.27
393.3335571	0.41
394.5021973	0.19
396.1546021	0.20
397.3098755	0.18
398.1046143	0.36
400.2716675	0.10
402.6147461	0.03
403.5244751	0.22
404.8175659	0.08
405.4931641	0.87
406.5448608	0.18
408.2631836	100.00
409.2885742	25.67
410.3687134	0.53
411.3283081	0.08
413.4181519	0.41
414.2921143	1.24
415.2399292	0.44
416.5404053	0.08
418.6574707	0.19
420.4703369	0.22
421.4824219	0.04
422.3734131	0.06
424.5926514	0.11
426.7968140	0.17
430.4097290	0.23
431.6385498	0.50
432.2753906	2.43
433.3491211	1.44
434.4374390	0.28
435.3924561	0.06
437.2190552	0.07
438.1295166	0.39
440.1939697	0.16
444.3778687	0.04
448.6251221	0.53
450.3464355	6.46
451.3133545	1.86
452.3858643	0.19
454.3491211	0.26
455.5106812	0.17
456.5578613	0.49
457.2189941	0.07
462.3740845	0.57
468.2615356	0.06
468.9060669	0.12
470.6825562	0.10
472.4797363	0.64
473.3264771	0.10
474.3415527	1.77
475.3840942	0.65
480.2495117	0.91
481.3218994	0.81
484.5429688	0.06
488.5942383	0.17
490.5847778	0.25
491.3351440	0.05
492.5063477	0.50
493.6266479	0.21
494.9281006	0.42
498.2189941	2.45
499.4558105	0.83
504.4801636	0.04
505.3259888	0.16
508.3276978	0.18
514.0338745	0.38
514.6409302	0.09
515.3390503	0.27
516.2915649	0.46
517.2842407	0.33
525.0972290	0.45
530.2621460	0.03
532.3540649	1.33
533.4636841	0.86
534.3919067	0.51
535.1170654	0.06
540.4056396	0.19
545.0736084	0.06
547.0594482	0.04
550.3638306	0.25
551.6133423	0.21
552.3966064	1.76
553.3037720	0.43
558.2993774	1.13
559.3782959	0.56
566.5081177	0.30
570.2142334	5.46
571.3270874	2.66
574.6683960	0.25
576.3317261	3.67
577.4108887	1.59
584.4487915	0.16
589.1312866	0.06
592.4500122	0.06
594.3461304	3.55
595.3919067	1.83
602.3098755	1.43
603.0193481	0.34
607.4476929	0.39
612.4987183	2.85
613.4948730	0.49
618.3937378	0.09
620.3332520	3.43
621.3192749	1.23
628.2975464	0.09
630.5354004	0.22
636.5487671	0.15
638.3312378	6.58
639.4788208	3.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1255
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
187.0053711	0.02
197.1328125	0.09
197.9910736	0.03
198.9805298	0.16
213.3149719	0.12
215.1732025	0.06
238.8454590	0.07
240.2818909	0.03
241.1029053	0.15
243.1539612	0.09
251.2634277	0.07
254.1517792	0.16
256.8371887	0.06
260.8261719	0.08
272.1307983	0.04
278.9860229	0.04
281.0358582	0.07
285.0913696	100.00
297.1998291	0.22
299.0923462	0.34
311.4502563	0.05
314.5104980	0.06
315.1694031	0.05
319.1331177	0.02
325.2772217	0.34
327.2022705	11.54
335.1514282	0.12
339.2402954	0.38
343.3403931	0.03
349.1257935	0.03
351.2521362	0.10
351.9556885	0.07
353.3206177	0.48
355.1622925	1.82
357.1748657	5.61
357.7788086	0.01
363.2160034	0.33
367.3493652	0.07
369.2856445	2.85
371.1513672	0.68
375.0202637	0.06
378.2402954	0.15
379.2925415	0.10
381.1994019	4.52
383.2083130	0.06
384.3444824	0.03
393.3095703	1.39
395.2005615	0.06
397.2075806	0.33
399.2968750	1.43
411.2344971	0.35
413.4751587	0.07
417.5767822	0.18
418.9846191	0.12
423.3461914	0.28
425.1724854	0.15
426.0203857	0.04
429.2053223	0.50
436.1837769	0.03
441.3139038	0.07
443.2218628	1.82
444.0619507	0.13
447.2337036	22.60
461.2159424	88.78
462.1081543	0.04
463.5051880	0.01
475.3471069	0.15
477.4366455	0.03
483.5255737	0.04
485.1137085	0.05
489.2196655	0.54
491.2702026	0.28
501.1213989	0.06
503.2677002	26.45
505.1394653	0.34
508.2013550	0.11
513.3156738	0.04
515.2586060	0.55
517.3270264	0.61
519.1251221	0.60
526.8330688	0.28
527.6387329	0.04
531.3269043	0.07
533.2700806	5.23
534.4075317	0.08
542.4904175	0.32
543.3190308	0.59
545.2705688	0.82
548.4471436	0.03
556.9848022	0.28
559.0722046	0.14
561.2393188	0.17
563.0771484	0.05
569.1658325	0.79
575.0884399	0.18
576.3146362	0.03
577.2550049	0.14
578.7747192	0.38
587.1834106	0.90
602.2509155	0.33
603.5608521	0.09
605.2131958	0.41
608.0073853	0.16
609.2424927	0.02
623.3137207	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.11
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
107.9971771	0.43
108.9331818	5.41
121.9897385	0.07
122.9651337	4.20
126.9801407	0.05
134.9692841	0.11
142.7424316	0.07
150.9823761	0.45
151.9611206	1.73
152.9205017	100.00
164.9369202	0.16
170.9606476	0.04
175.1977234	0.02
177.0677490	0.11
183.0730286	0.09
195.0075989	0.47
197.8286133	0.03
205.1880188	0.04
207.0005188	0.07
211.2828674	0.06
219.8253174	0.03
222.8479919	0.27
225.2569275	0.02
237.1047974	0.06
239.2271118	0.07
255.6292725	0.11
269.3618164	0.03
271.0247192	0.22
287.0093384	0.02
296.7210083	0.07
297.3362427	0.20
298.6015320	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	342.18
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
99.0131683	0.12
108.9156342	0.14
116.9213181	3.90
125.8055725	0.09
126.8807068	1.55
129.0193329	0.59
131.0791016	0.05
132.1224823	0.55
135.0663147	0.04
136.0588379	0.08
137.1335449	0.05
147.4367981	0.03
151.0952148	0.18
151.9095459	0.15
156.1713257	0.05
162.8328552	18.99
165.4425049	0.13
167.1293488	0.06
169.1346741	0.05
175.0542908	0.08
178.9727783	72.65
179.9551392	100.00
186.3416901	0.74
193.0961304	0.12
197.1230316	0.19
200.2658234	0.66
201.2640381	0.09
210.0874329	0.11
211.1085205	0.17
214.9110718	0.03
219.4541626	0.07
221.1464844	0.09
224.7228088	0.04
229.3415833	0.31
231.2116089	0.13
236.2002563	0.13
236.9910278	0.19
245.2740479	0.09
248.1276245	0.04
252.5001221	0.40
254.1920166	0.07
256.5325623	0.10
263.9715271	0.06
265.8923645	0.04
268.3725586	0.07
275.1851807	0.16
278.9795532	0.19
283.0851440	0.07
284.6292114	0.35
288.8830566	0.12
291.3035583	0.05
292.0084229	0.07
295.9985046	0.07
297.1742554	0.31
298.6930542	0.04
300.5889282	0.12
301.1956482	0.03
304.2514343	0.07
306.7423706	0.36
308.2221680	0.04
309.1725464	0.05
310.0803223	0.37
311.2451172	0.16
312.1431885	0.13
313.9497070	0.08
318.8416138	0.04
322.6202698	0.48
324.2285767	7.40
324.8394775	13.10
325.4518738	0.09
333.0934753	0.22
333.9818726	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.0886
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
178.9694977	15.24
267.1968079	0.24
293.2682495	0.24
299.3171387	0.10
311.0127563	100.00
359.0983276	0.04
442.8175659	0.09
460.3961792	0.21
461.1072998	0.60
473.1794434	0.11
491.1061401	0.06
549.3341675	0.03
622.9142456	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.98
Annotation	Unknow
Peak:m/z	Relative Intensity
99.8598251	0.03
105.8393097	0.28
107.0885315	0.29
108.1170959	1.82
108.9090424	0.24
114.1046829	0.09
122.9311371	5.53
124.0384293	0.68
127.0330887	0.06
128.9712219	0.18
130.6799316	0.05
133.9080505	1.25
134.8464203	0.12
135.9506378	2.91
137.0561523	0.29
139.1127625	0.07
144.8005219	0.13
147.2215271	0.14
151.9918213	7.79
152.9372864	0.33
154.1457214	0.09
163.9569092	0.10
166.0758667	0.07
169.9739685	10.93
171.0804596	1.55
175.0734558	0.09
177.3746643	0.13
182.2041321	0.42
185.2203064	0.52
191.1062164	0.05
194.7437592	0.05
197.6399536	0.10
202.1037140	0.13
203.2939453	0.03
204.0103455	0.05
210.7690735	0.15
213.0536804	0.25
214.0613708	0.15
219.9406128	0.24
230.0583191	0.23
231.1410217	0.06
231.8507996	0.19
232.8223267	0.07
235.0104980	0.04
242.8786316	1.21
245.3146057	0.36
254.9346313	0.17
259.1878967	0.08
260.0433960	0.05
267.4461975	0.08
270.4216614	0.08
271.0361023	0.05
272.8550415	0.67
273.9776611	0.04
278.4337463	0.11
280.5694275	0.58
286.6908569	0.61
288.1026001	0.05
289.0748291	0.10
291.8543091	12.13
294.1484070	0.25
296.1889343	0.17
297.3759766	0.18
302.3119507	0.07
303.2233887	0.06
304.7448730	0.27
312.0512085	0.08
314.1404419	100.00
315.2028809	18.51
317.3884277	0.21
328.3309937	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1534
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
94.8952560	0.11
102.9736023	0.03
104.9537048	0.06
108.0923309	0.04
111.2960739	0.02
118.9220581	1.41
121.0782318	0.10
123.1923828	0.05
125.2568665	0.05
128.7908173	0.44
130.9276276	0.17
132.8883667	0.18
135.4485931	0.27
136.9324951	2.36
139.0562744	0.15
145.0033875	0.04
147.1351318	0.02
149.0407410	0.85
150.9794617	37.95
156.9176025	0.82
161.1199646	0.91
163.0279236	1.71
164.8478241	0.41
169.0838928	0.23
172.6328278	0.13
174.3021240	0.31
175.0263367	0.57
177.1094666	0.40
179.1751251	0.04
181.0005951	0.11
189.0080566	24.28
189.7016144	0.24
191.2646332	0.28
197.1233063	0.06
198.0259552	0.14
207.0505981	5.58
213.1809998	0.14
217.0206604	0.04
218.2614746	0.08
221.1153564	0.22
223.0465393	0.12
227.0846558	0.27
231.0546875	0.02
232.4347229	0.25
234.3556213	0.03
235.3693542	0.15
237.1841125	0.55
241.2463074	0.02
243.5241089	0.08
245.1682129	0.38
247.4458618	0.10
249.2362366	2.95
251.2584534	0.03
253.0795898	1.86
255.1602173	5.40
257.2314758	0.03
259.0172729	0.15
263.1840820	0.33
264.0791016	0.04
265.0626831	0.18
269.1494751	0.56
272.9157104	0.14
274.9635620	0.49
281.1723938	4.59
283.1176758	0.06
285.1336975	16.37
287.1796875	59.44
288.1088867	0.13
290.0902100	0.08
295.1072998	1.27
299.1628418	1.43
299.8272400	0.03
301.2589722	3.12
303.1557922	0.19
313.1698914	100.00
314.1416626	0.09
316.5691223	0.09
321.9083252	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	295.0443
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
88.8964920	0.02
98.9796600	0.02
101.2119064	0.01
106.8898315	0.01
108.9667358	0.01
114.9316711	0.04
117.1118164	0.10
123.5948029	0.02
135.0022278	0.06
144.9169312	0.59
154.0641785	0.01
162.9027557	100.00
163.6791229	0.00
171.1911774	0.02
175.0898590	0.03
179.0874634	0.01
181.0238342	0.03
230.8502502	0.01
233.1907959	0.01
241.3758850	0.01
249.1229248	0.12
249.9959412	0.03
258.3598328	0.01
259.0360107	0.04
266.4867554	0.07
267.1268921	0.18
276.1585083	0.01
277.1194763	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Scopolin
Peak:m/z	Relative Intensity
110.9670105	0.04
112.8057861	0.06
127.0723877	0.15
134.0264282	0.06
135.0601349	0.50
143.0530701	0.02
144.8603210	0.03
161.0807495	0.48
173.0489197	0.19
179.0582428	2.98
190.9959564	100.00
309.2656250	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2785
Annotation	L 697318
Peak:m/z	Relative Intensity
139.9319763	0.08
147.0190582	0.02
152.9843445	0.03
157.0817261	0.05
162.7697754	0.04
196.0629120	2.04
197.1613007	0.08
214.1530609	1.61
243.1538391	0.10
259.3624878	0.07
261.3702087	0.32
262.2162170	0.02
272.3551636	0.01
279.2581177	100.00
280.2860107	18.73
301.0435791	0.50
390.4214783	0.01
393.1402893	0.17
395.1158142	0.01
415.4385376	0.24
416.2974548	0.19
433.5688171	0.02
458.8728333	0.03
459.5722961	0.04
461.2767334	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1813
Annotation	Lychnose
Peak:m/z	Relative Intensity
363.1866455	13.32
381.2003784	7.35
453.3424072	0.25
467.1785889	0.06
525.2184448	71.22
526.0398560	0.03
543.2778931	100.00
552.9646606	0.12
571.2926636	0.04
606.9016724	0.33
629.6232910	0.06
685.0433350	0.08
706.4268188	1.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.086
Annotation	Luteolin 7-glucuronide
Peak:m/z	Relative Intensity
257.0490112	0.04
287.0806885	100.00
288.0357666	0.04
299.1095276	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
193.1064148	0.55
196.9315491	0.16
205.0650177	0.17
210.9691315	4.54
213.0915833	0.18
215.0083008	2.52
219.1346741	0.09
222.8660736	0.13
232.8319397	0.56
240.9826813	6.21
256.9472961	2.61
259.1960449	1.01
262.1434937	0.62
268.9815063	0.21
280.0784302	0.77
283.0463257	0.30
287.1271362	0.12
292.1161499	0.08
298.9157715	0.67
300.1904297	0.44
305.2518921	0.41
309.1246948	0.07
311.1407471	0.92
318.1388550	0.99
321.1461182	0.06
323.1350403	100.00
324.2916260	0.21
326.1224365	0.33
329.0396729	8.60
334.0691528	2.95
335.9583740	0.21
341.0728760	0.47
342.0003662	0.04
343.0291138	0.19
352.1071167	0.63
359.1109619	4.46
361.3579102	0.81
364.2173462	0.22
370.0799561	0.22
371.0100708	1.07
371.9677734	0.53
377.1179199	13.66
380.0650635	0.91
381.0158081	0.07
382.2137451	0.27
384.6396484	0.32
388.0772095	0.11
390.0172119	0.09
391.1657104	0.13
392.6953125	0.15
396.3218994	0.17
398.0983887	1.63
401.9374390	0.13
406.3813477	0.17
413.1639404	0.05
414.3263550	0.15
416.1200562	0.14
419.0769043	3.68
423.0762329	5.63
424.2064819	2.28
426.0112305	0.29
428.8696289	1.78
429.6702271	0.48
431.2306519	0.36
440.4215088	8.91
441.1588135	44.20
444.1199341	0.30
446.3446045	0.64
446.9561768	0.61
449.1238403	2.05
452.2073364	1.09
453.1771240	0.28
462.2429199	0.74
464.1188965	0.15
465.1220093	0.38
466.8222656	72.29
467.8642578	0.71
470.1324463	16.07
473.1234741	0.24
483.0639648	36.20
483.6796875	0.17
484.9072876	0.17
486.0249634	0.08
488.1832886	3.68
490.5541382	0.25
491.1931763	3.04
494.9521484	0.07
500.3041382	0.22
506.0681152	0.34
507.2005615	0.20
516.1183472	0.08
518.8587036	0.04
524.2281494	2.10
542.1385498	3.35
556.0431519	0.15
560.0788574	69.53
560.7031860	0.66
585.1432495	21.46
603.0183716	2.13
603.8157349	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	718.2247
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0682831	0.09
212.9169922	0.20
214.1265869	0.03
214.9135895	0.08
216.9156647	0.11
217.8889465	0.08
223.0428619	0.56
224.0721283	0.18
224.9610748	0.05
226.2572174	0.03
227.1666565	0.09
229.2321167	0.02
231.1314392	0.04
233.1106873	0.17
234.0403442	0.36
235.2606201	0.08
238.7646484	0.17
241.1093750	10.69
242.2209167	2.04
245.0661621	0.36
246.2060547	0.15
247.3104248	0.09
250.1419678	0.14
253.1504059	0.22
253.7960358	0.03
255.1950378	0.37
256.2404480	0.13
257.1320496	0.07
259.1104126	0.83
259.7984619	0.06
261.0770264	0.22
270.2885132	0.12
272.3242798	0.26
273.1166077	0.29
274.0531616	0.62
275.2862854	0.10
280.2290649	0.21
281.1425781	0.07
283.1406250	0.11
286.1300354	0.03
287.1586609	0.12
288.0200195	0.11
291.3074341	0.10
291.9202881	0.02
293.1635437	0.43
294.1232605	0.12
296.4607239	0.22
297.8604126	0.15
298.9956970	0.40
300.1452026	0.07
302.9737549	0.10
308.0027161	0.03
312.0283508	0.07
313.3924255	0.04
314.0349731	0.13
316.1310730	0.59
317.0250854	0.09
328.2928162	0.09
329.3339233	0.34
331.1891479	0.05
334.2125854	0.49
335.0262451	0.05
344.2323914	0.33
344.8541870	0.06
348.3372803	0.03
350.2803955	0.07
352.5340881	0.07
356.3438721	0.13
373.2811890	0.36
374.1602783	0.60
375.1260986	3.39
376.1371460	0.54
376.9434814	0.24
383.2109985	0.10
384.2846680	0.88
385.1336670	0.09
389.1741333	0.11
390.1055908	0.44
391.2343750	0.17
392.3179932	0.04
393.3793335	0.04
402.1325073	10.61
403.1990356	2.50
405.1235352	0.45
407.2241821	0.09
411.2992554	0.04
414.1708984	0.03
415.4417725	0.02
419.1427612	4.97
420.1810303	7.19
421.2672729	1.45
425.3246460	0.10
426.3996582	0.05
429.0345459	0.08
430.1644897	0.13
433.0682373	0.18
437.2170410	2.98
438.2835083	0.95
443.2330322	0.07
444.1527100	0.09
445.3631592	0.05
447.5394897	0.12
451.2331543	0.05
452.2985229	0.08
455.0761108	0.07
463.2348022	0.06
467.6929932	0.06
468.5164185	0.22
474.2217407	0.02
475.2606812	0.17
479.1354980	0.06
480.0506592	0.24
486.1687012	9.21
487.2182617	3.18
491.3251343	0.81
492.2117310	0.06
493.3983765	0.02
495.8114014	0.02
497.0550537	0.38
498.3183594	0.34
503.3849487	0.40
504.3207397	0.60
505.4696655	0.21
508.3405762	0.26
513.9273682	0.29
515.0452881	0.09
521.5279541	0.04
522.3303223	0.06
525.3223877	0.13
526.1407471	1.57
527.2396851	0.09
536.1414795	0.23
537.3652954	0.02
538.4492798	0.12
545.2965698	0.13
548.2991333	1.45
549.2442017	0.38
550.2957153	0.13
553.3880615	0.43
554.1730347	1.45
555.1427002	0.52
566.2200928	1.91
567.5537720	0.34
571.2189331	6.87
572.2039185	14.69
573.1567383	4.95
573.9360962	0.12
583.0061646	0.04
589.2205200	100.00
590.2307739	30.21
590.9227295	0.03
597.5481567	0.05
598.5350952	0.09
603.5285645	0.22
607.3016357	0.04
625.3348999	0.76
626.4931641	0.40
637.0932007	0.11
643.3071899	5.01
644.3618164	2.71
652.4724121	0.20
654.9884644	0.32
656.0470581	0.16
657.1511841	0.13
671.5016479	0.16
673.2222290	0.07
675.6448364	0.54
683.3208618	0.06
684.5701294	0.08
700.3623047	3.70
701.2827759	2.46
702.4264526	0.27
705.5244751	0.31
719.3352051	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	560.68
Annotation	Unknow
Peak:m/z	Relative Intensity
216.8493042	0.24
268.8882751	0.39
292.8313904	0.08
304.4224243	0.17
308.9157410	1.24
359.1545410	0.24
377.1525879	0.59
392.8272705	21.72
419.2308960	0.14
424.0123901	0.04
461.7060547	0.11
463.0425415	0.87
470.1384277	0.15
473.5833740	0.21
476.1967163	9.06
476.8200684	100.00
486.8632202	0.10
488.4862671	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.21
Annotation	Atalanine
Peak:m/z	Relative Intensity
220.8782501	0.34
222.2414398	0.02
233.1363525	0.03
250.6164246	0.10
281.0143738	0.04
310.4606323	0.15
323.0732422	0.40
341.0793457	1.03
383.2542725	0.09
469.2549438	0.08
484.9771118	0.02
503.2542114	100.00
504.3000488	11.64
510.2731934	0.10
517.1251831	0.06
632.0601196	0.22
650.2507935	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	267.0512
Annotation	Unknow
Peak:m/z	Relative Intensity
87.1376953	0.06
96.9581833	0.02
102.6176605	0.04
104.9365845	58.77
117.1483002	0.07
130.8755951	0.11
135.0568085	4.06
142.9413757	0.06
148.9934540	0.06
161.0215607	100.00
161.7349701	0.03
175.0788879	0.04
179.0546875	24.87
183.3556976	0.06
187.0161438	0.05
191.9980316	0.07
193.1230621	0.31
195.4734955	0.22
202.9745026	0.07
205.0834961	0.24
207.0345612	0.06
219.1481018	0.04
221.0019989	0.34
223.0577698	1.51
224.2081757	0.07
229.3002930	0.03
239.3546600	0.15
244.8380127	0.10
249.1512451	0.41
251.1177368	0.06
252.2798920	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.19
Annotation	4,2'-Dihydroxy-4',6'-dimethoxychalcone 4-apiosyl-(1->2)-glucoside
Peak:m/z	Relative Intensity
178.9692535	1.55
180.0180969	0.33
180.9512329	0.26
188.2440796	0.31
204.2066345	0.10
205.2095947	0.64
206.1175232	0.65
206.9612427	0.07
211.8908997	0.11
216.1150055	0.06
220.3752441	0.28
224.2439270	0.05
228.9550171	0.25
231.2169952	0.21
247.3504333	0.12
249.1951904	3.86
250.2621460	2.50
251.1317596	0.45
253.1360168	0.07
254.2173920	0.21
255.2017059	0.19
260.2777100	0.07
266.1395874	0.14
269.1652832	0.48
270.4896851	0.20
272.0497742	0.18
273.0817871	0.12
278.2526855	0.30
281.3647461	0.34
285.3214111	0.05
287.2685547	0.85
290.0128479	0.19
291.5728149	0.28
292.4168091	0.05
293.1813354	0.24
294.0651245	0.17
295.0275269	1.63
296.0693054	2.12
297.2385864	0.50
298.1918335	1.12
299.0646362	0.34
309.2999268	0.67
310.4196167	1.13
311.3062744	2.30
312.2871704	0.16
313.2136841	0.08
314.2034302	6.67
314.8434753	0.07
325.4819336	0.50
326.1845093	6.57
327.1029053	0.37
329.2208862	100.00
330.0014648	0.29
337.3969116	0.15
339.1835938	0.89
341.2128296	95.46
342.1342773	0.41
343.1253662	0.12
345.2646484	0.08
347.2578125	0.09
352.2505493	0.22
354.1129761	1.28
355.1287842	0.07
357.2642212	53.77
358.9696045	9.20
359.6437378	0.16
363.1530151	0.22
369.1971436	53.09
371.3133545	0.12
375.3883667	0.06
376.2878418	0.06
381.2968140	0.09
383.3541870	0.11
385.6340942	0.72
386.6410522	1.13
387.4090576	0.37
389.3326416	0.34
392.4316406	0.05
393.9608765	0.07
403.0646973	0.32
406.5812378	0.12
411.1540527	0.93
412.3140869	2.54
413.2213135	0.79
415.3728027	0.36
416.9208374	0.31
419.6481934	0.32
422.8767700	0.49
429.2036743	5.96
430.2645874	15.77
431.1494141	2.79
442.8468628	0.05
445.4335327	0.27
446.4079590	0.30
451.9046021	0.11
455.2075195	0.17
460.7273560	0.06
462.3747559	0.14
472.9183960	0.13
474.1840210	0.06
475.1775513	0.18
477.8956299	0.15
481.7689209	0.64
487.1273193	0.41
489.3402710	0.13
491.2825928	0.53
502.4210205	0.15
506.0761719	0.12
509.2797852	0.32
511.4137573	0.15
512.1621094	0.16
519.2501831	0.63
520.8649902	0.58
525.7501221	0.32
528.4277954	0.29
531.0723267	0.19
532.7747192	0.22
533.4006958	0.64
545.4721680	0.32
546.6506958	0.70
547.2930298	0.85
548.7916870	0.50
549.5905762	0.51
551.5228271	0.10
560.2684326	0.12
561.1505737	0.73
562.5225830	0.09
563.2045288	0.36
570.7855835	0.13
573.4019165	0.15
574.9159546	0.75
575.5592651	0.32
593.1664429	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.2771
Annotation	Granaxylocarpin A
Peak:m/z	Relative Intensity
195.1727295	0.11
221.2495117	0.09
222.3123779	0.18
223.9591675	0.15
235.1253662	0.07
245.1592102	0.28
251.2508240	0.06
265.1537476	0.11
268.2062683	0.07
271.3598022	0.27
277.1097412	0.21
279.3325806	0.36
291.2083435	0.09
295.2814941	0.66
297.5187683	0.31
310.1538086	0.14
313.2982178	0.81
325.3808899	0.90
332.3461304	0.07
334.2718811	0.09
345.3491211	0.15
354.9266968	0.32
355.6563721	0.05
360.3499756	0.45
372.5507202	0.09
373.4708862	0.23
389.4355469	0.09
391.0327148	0.30
400.9498291	0.06
402.2556152	3.76
404.3101807	0.13
413.5049438	0.10
414.4977417	0.39
416.5177002	0.14
422.1861572	0.07
425.2659302	0.09
426.0051880	0.10
430.4735107	0.95
432.0866089	0.11
442.3052368	0.06
444.3066406	5.95
445.3309937	0.55
446.1864624	0.21
448.3766479	2.05
454.4011230	0.09
456.5802612	0.16
458.1122437	0.51
460.5223389	0.47
462.5718384	0.34
463.3478394	0.58
464.0178223	0.05
475.1834106	0.95
476.4238281	0.61
478.5026245	0.06
488.3531494	9.54
489.3375244	2.50
493.0852661	0.37
494.2202759	0.05
495.3436890	1.83
496.2181396	0.11
499.3709106	0.15
503.5108032	0.28
507.3180542	1.03
508.4079590	1.12
511.2304077	0.70
511.9067993	0.29
518.3164062	0.11
520.3541260	25.82
521.4483032	0.60
523.5272217	1.17
525.2785034	6.36
525.9070435	0.16
526.6168823	0.18
547.9637451	0.73
549.4302979	0.22
555.8988037	0.07
558.4643555	0.16
565.2538452	0.72
567.4400024	35.04
569.0905151	0.18
570.4062500	1.80
580.2736816	0.26
581.4484863	0.05
583.3613281	1.80
593.2938232	0.17
597.2333374	0.43
598.4666138	2.39
599.3414307	1.58
600.6842651	0.25
605.4312744	0.41
610.7603149	10.73
611.4833374	100.00
614.3096313	0.34
615.5288086	0.94
617.4636841	0.09
624.7149658	0.61
625.6221313	0.71
643.4426270	16.72
644.3550415	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.046
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
87.0285034	0.31
102.8914871	0.73
112.9226837	5.54
114.0046310	0.05
118.9731598	3.08
130.7902374	1.27
133.1276245	0.23
136.8685608	0.06
138.0354614	0.19
138.9358826	0.07
140.0990295	0.16
149.0371399	38.43
161.4635468	0.04
162.9360962	100.00
178.9945679	0.43
183.0445862	0.04
188.2249298	0.25
189.1872559	0.07
190.0198059	0.05
195.0661621	0.04
202.9741211	0.15
218.9906921	0.83
220.0857544	2.90
221.0705566	0.60
222.2109375	0.15
222.9637146	0.07
232.1503296	0.50
233.0506592	0.11
234.2415466	0.03
235.1178894	0.04
249.1042175	0.10
250.0092163	0.03
250.9879761	0.18
262.2057495	0.03
276.1465454	0.68
277.1145935	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1116.25
Annotation	Unknow
Peak:m/z	Relative Intensity
519.0685425	0.13
523.1569824	0.09
594.2293701	0.37
807.8220215	0.38
922.6992188	0.52
1082.8796390	0.34
1083.6723630	0.24
1116.1613770	100.00
1117.2060550	3.63
1118.0070800	6.61
1118.7542720	2.31
1119.7985840	1.44
1120.6729740	1.49
1121.3925780	0.58
1122.6755370	1.92
1123.5208740	0.21
1124.4744870	0.66
1125.6962890	0.19
1260.8718260	0.66
1264.8621830	0.17
1279.0444340	0.28
1282.8516850	0.47
1283.9172360	0.24
1309.1209720	0.06
1314.5396730	0.20
1332.9277340	1.57
1369.2799070	1.21
1377.4466550	0.89
1407.9499510	0.30
1410.7821040	0.45
1414.6088870	0.76
1438.7153320	0.84
1546.0693360	0.29
1615.2308350	0.91
1623.3843990	0.48
1628.2943120	0.29
1648.8887940	0.17
1650.4647220	0.11
1651.3841550	0.40
1689.9899900	1.20
1748.9294430	0.84
1764.9454350	0.48
1792.1531980	0.39
1802.5328370	0.22
1834.7203370	0.78
1862.8303220	0.46
1868.3485110	0.43
1870.7115480	0.63
1892.3542480	21.94
1970.8294680	0.08
1979.0384520	8.95
1984.7644040	0.10
1989.2609860	2.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	778.1399
Annotation	Unknow
Peak:m/z	Relative Intensity
251.1273804	0.02
254.1782532	0.29
272.0876770	1.33
272.7484741	0.09
296.4107361	0.01
305.9594727	0.01
311.1377869	0.14
319.0942993	0.02
324.2870789	0.02
325.0288696	0.03
355.1235962	0.05
368.0366821	0.02
386.1322632	0.04
404.2874756	0.01
422.2949219	0.06
434.2053223	0.04
440.2620850	2.32
448.3408203	0.06
466.2001953	0.49
483.5109253	0.14
484.2116089	0.78
486.8908081	0.03
505.1090698	0.48
567.7872925	0.04
580.2358398	0.11
597.3585205	0.04
598.2849731	0.29
614.7803345	0.04
616.1348877	2.30
646.5067749	0.03
649.3068237	0.13
760.2232666	0.16
778.1572266	100.00
778.8488159	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9434814	0.09
158.9391937	6.25
160.0054779	1.43
161.0076904	1.24
199.0255432	1.42
199.9973450	0.66
201.0095215	0.90
216.8464203	0.24
218.0050354	0.26
229.1339417	0.60
229.9009247	0.70
231.0492401	1.40
244.8397827	0.24
272.9195862	76.77
273.9818420	33.55
274.9845581	45.97
341.0672607	0.09
357.1406860	0.09
369.1506958	0.05
372.8960876	0.04
386.9616394	47.06
388.0168152	79.94
388.9599915	100.00
412.1593018	0.09
429.0690613	0.04
434.8201599	0.04
446.7097168	0.08
456.3451233	0.20
457.0733948	0.29
458.7772522	0.44
475.8628845	0.07
485.1163025	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1768
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
130.9905701	1.57
135.1188354	0.06
143.0348816	3.46
145.0505219	0.51
147.1548615	0.16
149.1092682	0.74
161.0161438	18.18
161.6253357	0.04
171.0264893	0.15
173.1463013	0.13
178.9470825	11.39
182.9509277	0.20
185.0371704	1.60
187.1578674	4.98
203.0726318	0.35
205.0829468	48.37
205.7094269	0.14
223.3285522	0.76
228.9835815	0.17
231.1816711	0.85
241.2209167	0.20
243.4736023	0.23
247.1246033	0.13
249.0973511	100.00
267.0235901	2.22
271.3666992	0.16
280.3561401	0.17
295.1106567	0.59
297.4775696	0.30
299.1124878	0.51
306.8988647	0.10
309.3323975	0.09
311.3964844	0.16
325.1582336	0.38
351.2775879	0.36
358.8099365	0.17
369.3384705	1.29
375.2825012	0.05
383.3699646	1.36
385.2962341	8.63
411.1184998	2.09
414.3865051	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.05
Annotation	IAA-94
Peak:m/z	Relative Intensity
107.8678436	0.01
109.8899078	0.03
126.8313141	0.07
127.9343109	0.03
129.0544434	0.05
131.1664124	0.20
133.2624359	0.04
134.3668213	0.03
135.1117554	0.61
136.0168457	0.34
138.2120972	0.08
143.0073547	0.01
149.0612793	0.04
150.0468750	0.02
150.8717651	0.05
155.1091614	0.02
161.0826721	0.67
162.0594482	0.24
162.8880005	0.03
171.1602478	0.03
172.0235748	0.02
173.0162659	0.68
174.1700287	0.41
175.0553436	0.93
176.8482666	0.02
179.0480652	3.33
180.0145416	4.28
181.1070404	0.51
191.0769958	100.00
192.0553741	80.39
193.0458832	21.72
215.1464233	0.06
216.1671753	0.08
217.0437927	0.02
218.0862122	0.05
219.1089478	0.04
222.8403625	0.05
233.1353149	0.02
237.5024109	0.03
248.3066711	0.02
265.1085815	0.02
279.0088501	0.02
283.3724976	0.01
292.1416931	0.11
293.3417969	0.09
295.0220337	0.05
299.2204590	0.06
308.1179199	0.04
309.0872498	0.14
310.1152344	0.21
311.1964417	0.17
318.4143066	0.15
319.2637329	0.10
329.1969604	0.02
336.2299194	0.02
337.0728149	0.89
345.0126038	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	939.1476
Annotation	Unknow
Peak:m/z	Relative Intensity
266.2528076	0.07
271.3568420	0.02
273.1123657	0.19
283.1657715	0.11
285.0891113	1.52
294.8841858	0.02
299.7929688	0.02
301.0453186	26.43
315.3138123	0.05
327.0882263	0.14
353.0999146	0.11
357.1389465	0.16
363.2471924	0.04
381.2596436	0.02
459.5780640	0.06
461.1768188	4.73
463.1709595	0.10
477.1500854	100.00
477.7632446	0.24
503.2098999	0.04
585.2225952	0.04
601.1643677	0.02
829.3870850	0.01
921.4067383	0.06
938.8398438	14.09
939.5402832	0.14
940.4011841	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.2125
Annotation	Unknow
Peak:m/z	Relative Intensity
210.1002960	1.00
211.0912476	0.02
213.1436920	0.17
228.2607422	0.08
231.0316162	0.13
235.9426575	0.10
237.0021973	0.03
242.0775757	0.31
244.0456238	0.08
247.1401062	0.03
254.1234131	7.56
255.2101746	0.28
256.9234924	0.08
258.2835083	0.03
272.1870117	8.21
273.0792542	0.23
288.1314697	5.89
289.0078125	0.20
293.1661377	0.16
306.1151733	100.00
307.2160034	5.32
329.0167847	0.03
367.1956177	0.04
372.9218750	0.03
378.9820557	0.02
392.6233521	0.08
409.6847534	0.02
414.7183228	0.04
423.3126221	0.09
435.2213745	0.25
440.2123413	0.12
441.5155640	0.04
492.3883667	0.18
493.4731445	0.03
495.1166992	0.04
502.2972412	0.07
512.5720215	0.09
520.2465820	0.38
521.2963867	0.03
524.1345825	0.04
525.2651978	0.19
546.3926392	0.27
549.1885376	0.04
554.5134888	0.05
555.4338989	0.17
564.2691040	4.58
565.1981812	0.43
570.1134033	0.07
582.3630981	0.75
583.3541260	0.06
587.1597900	0.37
588.1082153	0.06
598.8065186	0.16
606.4107666	0.04
608.5852661	0.10
635.0891113	0.06
640.5501099	0.01
643.5435181	0.07
654.3073120	0.25
672.3063354	0.19
684.2941895	0.50
685.5967407	0.09
698.2673340	2.16
699.3354492	0.43
703.4868164	0.08
717.2785645	8.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1403
Annotation	Secologanoside dimethyl ester
Peak:m/z	Relative Intensity
119.1375198	0.14
124.9135666	0.12
137.0953064	0.15
143.0561218	0.45
146.2063599	0.47
150.9329529	0.70
159.0075989	0.18
160.9735718	3.61
163.1188965	0.22
166.1261292	0.21
168.0425110	0.15
168.9767456	0.18
175.9867249	1.10
177.1734619	0.13
178.9959717	0.91
181.1838989	0.42
190.3914185	0.19
191.1905670	1.36
192.2045593	0.08
193.9518890	11.46
195.0001068	0.65
207.0971375	15.18
209.1037598	100.00
219.3539124	0.15
235.2056580	0.13
236.1054993	2.55
237.1647339	0.06
253.0116272	0.78
254.0446777	0.84
255.0469055	0.24
296.5150452	0.14
300.9693604	0.21
309.4047241	0.34
313.3505859	1.13
325.9813843	0.26
331.4244385	0.16
337.2827148	0.44
341.2543335	0.59
355.0337219	0.14
357.2089233	0.36
370.9596863	3.06
372.5752258	0.77
381.1342773	0.17
398.3244324	0.50
399.4293823	0.63
402.9717407	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0882
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
135.0896912	0.47
146.9210510	0.09
150.9978485	8.08
152.0159912	0.32
157.0269470	0.17
160.8584137	0.03
166.2115479	0.02
168.0827637	0.05
174.9870911	6.17
176.0604248	0.27
177.0912018	0.06
179.1011505	0.17
193.1365356	0.13
197.3046112	0.03
201.2835236	0.05
208.9767914	0.04
212.2380219	0.02
231.0628357	0.09
237.2401733	0.03
243.3910828	0.06
244.9791870	0.01
247.0280762	0.03
266.1423340	0.02
269.1394348	0.44
283.1694031	0.03
287.0780029	100.00
288.0766602	13.34
301.0384827	8.66
302.0360718	1.24
309.1531677	0.07
313.3429565	0.02
329.0138550	0.54
330.1094971	0.11
331.3135071	0.10
341.2457886	0.66
342.1587524	0.06
343.1989441	0.66
345.2068787	0.05
347.1602783	0.15
353.3162231	0.01
354.2767639	0.07
357.2687073	0.10
359.1687927	0.40
360.2824707	0.04
368.2402344	0.03
371.1320190	0.19
372.3329163	0.05
383.1119690	0.05
384.3377991	0.08
387.1085510	0.05
389.3309937	0.04
401.3301697	0.05
403.1286621	0.05
404.4444580	0.02
417.1938782	0.21
419.4161377	0.06
421.2023621	0.08
445.1814270	0.82
446.1389465	0.27
447.1507874	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	947.66
Annotation	PI(20:1(11Z)/22:0)
Peak:m/z	Relative Intensity
293.2658081	0.02
311.1258240	0.08
472.9132690	0.19
946.8552856	100.00
947.6191406	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.0777
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
128.0589600	0.03
149.0776978	0.03
156.9290924	0.22
159.0038757	0.05
161.0220184	0.03
174.9762268	5.82
179.1563110	0.03
220.3667908	0.03
221.1869507	0.11
254.7271729	0.02
263.1010437	0.05
269.0787354	100.00
269.6820068	0.24
286.2553711	0.02
294.9313049	0.04
299.1263733	0.03
300.1114502	0.34
301.3561096	0.21
302.9572144	0.10
309.1731567	0.07
311.0566406	0.38
313.4645691	0.10
337.3242188	0.05
339.2628174	0.28
341.0163879	0.39
347.3757935	0.04
348.0689087	0.02
353.4383240	0.08
355.1021423	0.02
359.1342773	0.16
364.9939575	0.31
372.4405823	0.04
381.0369568	0.09
383.3539734	0.05
398.2424316	0.03
399.2258911	0.16
400.4421082	0.17
401.1944580	0.21
403.3995361	0.24
409.3602600	0.03
415.3286438	0.10
427.2501526	0.63
429.0816956	0.05
430.2591858	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1411
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
175.1611633	0.08
210.2815704	0.14
220.0764465	0.04
222.9369659	0.10
225.0736694	0.31
241.0844879	0.08
252.0324097	0.09
255.2512512	0.09
261.1571960	0.08
269.0302429	0.38
274.0517578	0.08
279.0650940	0.26
283.0939331	0.05
287.1641846	60.77
287.9947510	0.07
293.2043457	0.15
301.1560059	4.11
306.0815430	0.12
307.0377808	0.04
310.8933716	0.16
329.0964355	0.17
355.1865234	0.08
358.9274292	0.09
369.1227417	0.26
371.3829346	0.04
373.1256104	0.06
383.3065186	0.15
397.0955811	0.15
403.5656738	0.17
404.4938354	0.05
407.0543823	0.11
413.2673950	0.23
431.1812134	0.38
439.5589600	0.22
443.2360229	0.07
445.2038574	2.03
449.1446533	100.00
463.1858521	25.14
485.6399536	0.15
486.3169556	0.13
491.3209839	0.21
492.8087769	0.06
494.7742310	0.05
505.3403931	0.63
509.9396362	0.27
519.4922485	0.28
529.4301147	0.10
533.2973022	0.15
534.2827759	0.15
537.1366577	0.40
538.4166870	0.16
539.3187866	0.19
543.1427612	0.06
545.0319824	0.05
562.2760620	0.18
564.3878174	0.15
565.3836060	0.41
578.5678101	0.65
580.2113037	0.49
604.0740356	0.09
605.8086548	0.07
607.2128296	0.84
625.3551025	1.34
626.3309937	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	375.2024
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
112.9870834	10.58
113.8660126	0.34
116.9688110	0.19
118.9521255	19.67
119.9261780	0.12
124.8195648	1.73
130.9144745	5.51
142.9828491	4.46
144.0630798	0.62
147.9703369	0.34
148.8951874	1.90
161.1411438	1.53
162.2669067	0.25
177.0774841	1.15
179.0750275	1.73
179.7965393	0.18
181.3952179	0.52
183.2389526	0.94
191.1457214	0.34
195.1884155	100.00
196.1060181	12.84
197.2060852	0.70
209.2176361	6.95
210.7216492	0.47
211.3571014	0.11
213.1772919	59.32
214.2857208	5.18
227.1637878	0.69
228.1384277	0.18
229.9155273	0.45
237.0838623	1.27
245.3095398	0.39
249.1529236	0.84
250.0146484	0.28
255.2189636	1.01
267.0811768	0.90
274.6039429	0.30
283.1420288	0.28
312.4868164	0.45
327.4754028	0.12
333.6136475	0.09
339.3069458	0.13
345.4311523	0.84
357.2886963	86.78
358.3805847	14.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	618.86
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9022675	0.07
219.1763306	0.08
232.7644653	0.10
245.0486755	0.04
273.2089844	1.42
274.0535278	0.82
275.1155701	2.31
275.9104004	0.85
277.1437378	0.29
288.8696899	0.33
374.8491211	0.05
386.9400635	1.33
388.0230713	1.69
389.0173950	4.61
389.9842529	2.89
391.0004272	0.56
403.7307739	0.07
415.1281738	0.16
418.8928833	0.23
421.0316162	0.08
428.1033325	0.06
434.8135986	0.04
443.0494995	3.08
444.4033203	0.10
459.0631104	8.30
459.8121948	0.13
461.1605835	0.14
489.1954956	0.07
501.2594604	1.10
502.0319214	4.71
502.9404297	9.01
503.9512939	16.09
504.9200439	8.84
517.1054077	0.11
544.0634155	0.16
545.0567017	0.23
546.2152710	0.09
559.8265991	0.06
572.9223633	100.00
574.0461426	0.25
574.8604126	0.15
600.1008301	0.15
618.7573853	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.2136
Annotation	Briaexcavatin S
Peak:m/z	Relative Intensity
149.9554138	0.03
162.1646881	0.02
164.8500671	0.11
166.9561615	0.01
175.0666962	0.02
177.0466614	0.08
179.0849762	0.02
181.1579590	0.12
190.2478943	0.02
193.0518646	0.02
194.9694366	0.29
196.0993805	0.02
239.2360840	0.01
253.2742920	0.04
253.9193268	0.02
266.2691040	0.01
266.8963623	0.01
287.2005615	0.01
288.3470459	0.02
291.2837524	0.01
300.3090820	0.01
311.3038330	0.06
326.1887207	0.02
327.1716919	0.03
328.4629517	0.21
329.2760620	0.70
341.4099731	0.03
343.2011108	4.24
348.7568970	0.03
357.3801270	0.19
358.1281738	0.04
359.4585571	0.04
369.2795410	0.02
376.1428223	0.01
377.1101074	0.07
381.5806274	0.02
383.2474365	0.02
384.8094482	0.03
385.4696655	0.02
397.3237305	0.29
401.3712769	0.01
406.2612915	0.02
408.9622803	0.01
410.3756714	0.01
423.3647461	0.01
437.1771240	0.02
438.7498779	0.01
443.4672852	0.08
444.5615234	0.01
445.3809204	0.00
449.4225464	0.01
453.3378296	0.02
467.2782593	0.01
471.5138550	0.05
476.3977051	0.09
485.4323730	0.04
488.4625854	0.02
491.3005371	100.00
492.3424683	0.01
493.5875244	0.03
495.9448242	0.05
503.2897339	0.28
507.5165405	0.03
511.3838501	0.02
519.2147827	0.01
521.3023071	0.62
522.2879639	0.02
524.4413452	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
966.7756958	52.36
967.4213257	100.00
974.7866211	21.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.2054
Annotation	5-Megastigmen-7-yne-3,9-diol 3-glucoside
Peak:m/z	Relative Intensity
105.1124802	0.13
106.9792938	0.63
108.9404755	0.59
110.9495239	0.15
116.7751160	0.11
118.9759064	0.21
120.9806671	2.89
122.9242249	0.11
125.1345367	0.25
131.0075378	0.12
132.9978333	2.11
134.9843445	3.19
137.0690460	0.24
139.0974731	0.72
144.9848633	0.27
147.0432281	3.92
148.9870148	2.50
149.6257782	0.19
151.0638580	5.42
153.0594177	0.28
158.1264343	0.38
160.1272278	0.17
163.0846863	5.15
165.0965576	0.33
167.0886078	0.14
173.0878296	4.21
175.1273651	0.11
176.9378967	0.03
187.0846558	0.03
191.1160126	46.65
193.1461639	0.08
196.7857361	0.25
203.0951385	0.08
205.1319733	0.20
209.0218506	100.00
213.2315369	0.04
215.3006134	0.02
217.3528595	0.28
220.0922546	0.04
227.0317688	0.07
231.1210022	0.08
240.1400146	0.14
241.6140747	0.07
248.0615845	0.04
251.0182800	0.15
257.2219849	0.12
258.3812256	0.07
261.1840515	0.24
265.3572998	0.12
267.2888794	0.08
268.1873779	0.06
274.9785156	0.10
278.1807251	0.19
283.8692017	0.12
285.2469177	0.07
287.0288391	0.50
289.0403748	0.23
297.0903931	0.16
299.0427246	0.27
301.2732849	0.04
303.2025146	0.05
306.2880554	0.03
307.3276672	0.17
311.1008301	0.04
312.4196167	0.10
317.2204895	0.06
321.2147217	0.12
323.1467285	0.12
325.3302002	0.09
327.2796021	0.09
329.1499939	0.50
333.8782959	0.29
335.1313477	0.92
337.0439148	0.09
339.2404175	0.23
341.2292480	0.16
343.2727661	0.05
344.2890930	0.14
352.1600647	0.72
353.2575989	3.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1068
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
108.0364227	0.02
118.9707489	3.34
124.9514618	0.03
126.1865768	0.02
140.8873596	0.04
146.9131775	100.00
147.6896667	0.04
152.9227295	0.01
157.2019348	0.02
158.2085876	0.03
159.0384216	0.01
162.9878693	0.11
164.0516052	0.02
165.1142883	0.03
165.7838593	0.05
168.9228210	0.05
173.1091614	0.04
175.0788727	0.03
177.1552887	0.17
178.0350952	0.06
179.7854309	0.04
182.8876038	0.03
189.1198730	0.01
190.0877838	0.01
218.2514038	0.03
220.1468201	0.04
220.9775391	0.03
222.1954346	0.07
224.3704224	0.01
244.9810486	0.06
245.8860168	0.07
247.0892639	0.08
251.1015015	0.06
253.2837219	0.03
255.0654297	0.04
256.6193848	0.04
265.0410767	0.01
267.2758789	0.02
269.3280029	0.06
271.3867188	0.01
275.2002563	0.08
279.1965027	0.08
280.0877686	0.03
289.1702271	0.02
291.2079468	0.03
293.0452576	0.16
293.9941406	0.03
295.2144775	0.03
296.9708557	0.07
298.0657349	0.05
301.9746094	0.01
303.2275391	0.33
304.3343506	0.03
307.1636963	0.31
308.1900330	0.09
309.8452759	0.02
310.5535889	0.04
311.3067932	0.16
315.9636841	0.02
320.4212036	0.16
321.3134155	1.00
322.2676697	0.05
323.4015198	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
157.1292572	0.02
157.8255005	0.03
158.9591675	4.09
160.0404663	0.97
160.9666443	1.31
198.8302765	0.27
200.0440521	0.47
201.0590363	0.74
202.0603333	0.10
217.0987396	0.06
217.8015900	0.06
218.9647522	0.07
220.1357422	0.04
228.9781799	1.03
230.2902527	0.13
231.0214539	0.70
232.0622559	0.14
273.0062866	47.02
273.9941101	20.84
274.9657593	43.79
276.0256348	8.59
301.8127441	0.17
345.9754639	0.07
371.0843506	0.06
373.1085815	0.18
373.9851990	0.02
386.9643250	22.17
387.9786072	26.81
388.9410095	100.00
389.9438782	31.48
429.1148682	0.37
429.9730530	0.14
447.4125061	0.14
457.1866455	0.06
458.1736755	0.30
458.9869080	0.73
475.7293396	0.07
486.3296814	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1821
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9806519	0.05
186.2557983	0.10
221.1336060	0.03
237.2277832	0.04
246.6536255	0.11
250.2574463	0.07
254.0777283	0.15
257.2733154	0.02
265.2958069	0.06
271.2066956	0.55
287.1015015	0.06
299.0469971	0.12
300.1833496	0.62
301.1294861	1.53
302.3107300	0.02
303.4081116	0.09
312.1951904	0.18
315.1203308	0.06
316.8627625	0.12
319.3650818	0.06
323.0243225	0.08
331.3558655	0.07
332.1457520	0.03
341.3631287	0.09
343.2903748	26.21
348.2138977	0.05
355.0097656	0.04
363.1881714	0.02
364.3835144	0.04
365.2424011	0.05
367.3776855	0.04
373.1534729	0.20
375.1514893	0.09
377.2629700	0.14
381.1391907	0.19
388.5372620	0.19
395.2370911	0.03
401.0017090	0.02
403.2076721	0.06
415.4888306	0.17
417.2075806	100.00
418.1320496	0.02
419.4356995	0.03
442.4710388	0.08
443.1149292	0.02
444.6591492	0.10
445.3453674	0.29
464.4955750	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.0863
Annotation	3'-Methoxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
134.9034576	0.19
136.7556458	0.26
145.0310364	0.23
147.0021057	0.88
161.1975555	0.09
163.0248108	5.35
170.9847412	0.07
172.9447174	0.05
174.9632721	8.66
181.2613373	0.15
191.0781555	1.81
195.0866394	0.04
227.2655334	0.05
231.2442474	0.23
233.0545502	0.12
238.7403870	0.28
239.3759155	0.18
241.1854858	0.22
242.0281677	0.07
243.8498840	0.08
251.0207214	0.13
252.3189697	0.05
255.1258545	2.79
257.0920105	3.02
265.1380920	0.51
269.0266113	15.01
269.6361694	0.32
273.0455933	0.18
275.8403931	0.07
277.0127869	0.03
279.2035522	0.08
280.2519836	0.03
283.1871338	35.48
293.5671997	0.13
294.8826294	1.55
295.5092773	0.01
297.1881714	0.70
299.1078491	0.27
301.0783997	100.00
302.1006470	0.03
307.0976257	0.10
310.9921570	0.06
312.5875244	0.46
313.4627075	0.16
314.1862793	0.06
315.4281311	0.03
316.5341187	0.09
321.0277710	1.33
323.0985107	0.03
325.0958557	49.68
327.0982056	0.09
330.0804443	0.06
331.2210693	0.16
337.0802307	0.05
343.1261902	8.56
346.1851196	0.12
347.1299438	0.28
365.1232300	7.76
381.1296692	0.13
385.0189209	0.05
394.2357788	0.12
403.2694397	0.04
404.5017395	0.12
415.2050476	5.53
417.5178528	0.04
420.3193665	0.07
428.9283447	0.68
431.1925354	0.47
433.0622864	0.74
439.1035156	0.45
442.1759949	0.07
446.4906921	0.08
447.3219604	0.15
457.2053223	8.82
461.6143188	0.28
466.1933289	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.2307
Annotation	Chlorophyll c
Peak:m/z	Relative Intensity
243.0676575	0.29
255.5590057	0.05
377.0098877	0.03
471.2882690	0.11
511.3484497	34.22
512.3671265	18.42
512.9706421	0.12
514.2868042	0.10
519.5169678	0.59
520.7201538	0.10
523.4702148	0.09
526.6734619	0.25
531.5256958	0.24
533.4020386	0.32
541.5015869	0.14
543.3754272	100.00
544.3361206	46.96
545.2465210	0.10
552.2897339	0.11
555.3790283	0.23
556.2190552	0.05
569.3231201	0.24
581.6914673	0.08
588.1318970	0.21
589.6353760	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.1104
Annotation	Flavin Mononucleotide
Peak:m/z	Relative Intensity
145.0226440	0.02
148.2635956	0.02
203.2003479	0.11
207.9854584	0.04
211.3452301	0.02
213.2075806	0.07
218.3055573	0.10
229.0593262	0.02
236.8936157	0.02
243.0255432	0.38
245.2554626	0.03
257.0111694	0.06
261.2267151	0.02
262.3281555	0.07
273.0953369	0.03
276.1572571	0.07
277.3038025	0.02
286.2274780	0.12
295.1106262	0.18
298.7189636	0.03
304.2615051	0.56
309.0925293	0.13
310.2241821	0.02
321.0116272	0.02
323.4085693	0.04
325.1791992	0.05
327.1924744	0.15
334.3533936	0.03
335.2890625	0.06
336.0397949	0.05
341.1962280	0.10
342.1373291	0.05
353.0415955	0.05
357.3831787	0.05
359.2919312	4.76
361.5671997	0.02
365.9874268	0.02
368.1837769	0.07
368.9288330	0.20
371.1546326	0.13
375.1070862	0.06
377.0770569	0.05
377.7201233	0.02
381.2079163	0.01
383.1443481	0.15
394.0345459	0.05
396.3120728	0.08
397.2221069	0.08
399.0489502	0.02
402.1090393	0.01
411.0918884	0.61
412.4179688	0.04
413.0713806	0.06
414.2394714	1.74
414.8941345	0.02
420.2468262	0.02
421.3324890	0.26
425.5754089	0.03
426.9974060	0.09
429.1901550	0.10
431.6192017	0.05
432.5339050	0.13
439.1708374	100.00
440.2845459	0.79
447.9382629	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0983
Annotation	PD 169316
Peak:m/z	Relative Intensity
125.096077	1.03
151.0475159	3.04
153.0870667	0.16
156.8307495	0.33
160.9866028	0.76
164.9936523	0.28
178.1694489	0.16
178.8981018	0.47
184.9286346	0.32
191.0722351	0.51
195.0374756	1.46
196.0073242	0.91
197.0717621	1.68
202.2219391	0.17
203.2009277	1.07
209.1012726	1.22
223.0827026	0.13
226.8117065	0.67
228.2930908	0.16
230.124939	0.17
242.9825745	1.22
256.9277954	0.50
265.1276245	0.17
267.184021	0.25
269.9639893	0.31
286.4862671	0.17
303.1775513	0.98
310.8878784	0.56
313.0969543	100.00
314.267395	1.06
315.0925598	1.27
337.9310913	0.15
340.1671143	3.79
341.301239	5.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.2672
Annotation	GalNAcbeta1-3Galalpha1-4Lacbeta-Sp
Peak:m/z	Relative Intensity
223.3770447	0.09
234.2837677	0.13
250.4410248	0.11
294.480072	0.20
308.9396973	0.35
320.1774292	0.05
338.3302612	0.27
339.0916748	0.27
358.7432251	0.14
370.4432373	0.24
371.289856	0.10
371.9016113	0.31
385.8988037	0.15
389.4699097	0.04
401.4283447	0.06
402.256958	0.17
403.4575806	0.22
413.2330322	0.15
414.4403687	0.06
427.3543701	0.11
440.5756836	0.21
442.2710571	0.18
443.6403198	0.24
445.390625	0.12
446.5717773	0.72
447.4996338	0.60
454.2651367	0.15
459.3255005	0.81
460.4536743	0.30
461.3423462	0.26
462.0245972	0.06
472.4090576	0.53
473.3546143	0.66
474.7589111	0.57
477.5236816	0.05
488.3533936	0.33
489.0571289	0.52
490.6221924	1.80
491.5356445	1.30
504.3898315	0.24
516.2089233	0.10
518.2682495	0.13
519.2282104	0.17
524.0411377	0.12
527.0895386	0.15
530.6229248	0.17
533.7341309	0.11
534.4667358	0.11
540.4420166	0.20
547.2010498	0.06
548.8296509	0.30
551.527832	0.04
555.0371704	0.18
558.1184692	0.08
561.2990112	0.07
563.7597046	0.11
565.3311768	0.15
566.3039551	0.81
567.2974243	0.18
575.8331909	0.29
577.2913818	0.24
584.6110229	0.56
593.1306763	0.21
594.4956665	2.10
595.4488525	0.06
602.5481567	0.32
603.2131958	0.45
606.2098999	0.29
608.7037964	0.15
611.5283203	0.14
612.5401611	0.49
613.5269165	0.19
622.6958618	0.06
624.2880859	3.27
633.546814	0.34
634.4498901	2.01
635.5917358	0.58
638.430542	0.12
639.6245728	0.25
644.2474365	0.17
651.3513794	3.54
652.3858032	12.03
653.4876709	0.11
654.5701294	0.04
667.2519531	0.05
686.3816528	0.51
689.5033569	2.07
692.5063477	0.09
697.159729	0.05
701.4663696	0.08
706.5119629	0.14
709.6276245	0.06
710.4100342	0.42
728.4945679	4.27
730.1940308	0.58
731.5036621	39.04
732.3430786	0.13
738.5321045	0.36
739.3335571	0.40
746.383728	15.93
747.0703735	0.52
756.5062256	9.85
757.5063477	1.04
775.2835083	100.00
776.0169067	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	283.07
Annotation	Xanthosine
Peak:m/z	Relative Intensity
100.8625793	0.53
104.9923782	0.44
151.0289612	100.00
154.858551	0.52
160.8507385	0.92
167.3993225	0.43
179.1984253	0.39
182.9990387	1.02
190.9703369	1.02
198.8616333	1.31
207.0891724	0.25
209.0476379	0.40
210.9131775	0.35
235.6528625	0.45
237.0395813	4.28
239.1409302	0.68
265.0016174	1.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0837402	0.20
128.9553833	0.21
142.9683685	0.33
158.8013000	0.08
159.8977661	0.06
161.0027771	5.48
162.9355774	0.09
164.7302704	0.19
179.0686951	1.30
181.2962036	0.06
186.9735107	0.10
189.0964050	0.37
192.9997864	0.10
195.0878143	0.18
205.3070374	0.08
219.1480865	0.06
222.8619843	0.07
225.3751373	0.55
228.1816101	0.09
234.8626099	0.28
241.8012390	0.29
243.2329102	0.31
253.0860901	4.23
264.4653931	0.07
269.0028381	0.16
292.9464417	0.19
309.9921875	0.12
312.3829346	0.08
314.0404358	0.19
316.9965820	0.10
323.4057617	0.10
330.2216187	0.22
335.8665771	0.09
347.5443115	0.24
359.1126709	0.18
366.8479004	0.41
369.0765076	0.30
371.2149658	0.16
373.2557983	0.33
379.9870911	0.24
384.3797302	0.11
387.2904968	100.00
388.2918701	0.25
389.2356873	0.31
391.2373962	0.62
397.2904053	0.06
404.8555603	0.07
413.4779358	0.07
415.3824768	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
95.1504364	1.18
96.95698547	1.45
149.1853333	0.88
152.1190338	0.71
153.0843658	0.94
155.1704712	0.95
162.9734192	2.95
165.1011047	3.93
169.332962	2.48
179.376358	4.58
182.1044464	2.86
183.0859985	1.74
189.3040924	2.34
193.0281677	5.54
194.1026764	1.75
195.1707153	4.21
197.2936401	0.86
207.2162628	22.41
208.2258148	7.54
209.1593475	10.06
215.156189	3.48
221.4985809	3.25
222.2519379	2.40
223.184082	12.65
233.257431	14.82
235.8586578	1.29
251.0700836	100.00
252.1993866	17.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.0548
Annotation	15-Deoxylactucin-8-sulfate
Peak:m/z	Relative Intensity
96.8103256	100.00
134.9226227	0.28
160.9215698	0.38
251.1630554	0.42
319.2465210	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.0181
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9917297	0.06
136.8958435	0.02
172.2065125	0.03
174.6884460	0.04
187.0125885	0.02
188.9187469	0.15
202.4481201	0.06
203.0661621	0.49
204.9612427	0.05
206.9021912	0.03
212.8967438	0.28
215.2403870	0.04
216.0990143	0.02
217.0019531	0.40
219.1000824	0.19
229.2141724	0.14
229.8892517	0.02
230.9446106	0.27
234.9006042	1.25
237.1493835	0.01
237.9582520	0.02
244.0172424	0.03
244.9362183	0.01
247.1718750	0.03
248.2586365	0.02
255.2437744	0.03
257.1130981	0.67
259.2208862	0.04
261.1712646	0.43
262.1963501	0.18
267.0851135	0.03
271.8562012	0.04
272.8809814	0.06
273.9363098	0.03
274.9462891	3.68
276.9701843	0.23
279.0145874	0.12
284.8914185	0.04
287.2254944	0.02
288.2651978	0.03
289.7960510	0.05
291.1010132	0.04
292.9887085	0.13
300.9477539	1.42
301.8836365	0.08
302.9880066	0.15
305.0686646	0.13
307.3127136	0.15
312.5454102	0.10
313.1874695	0.07
316.2048950	0.03
318.9865723	13.76
319.8018188	0.06
321.0327759	0.07
323.0213013	0.21
325.8822632	0.03
326.9715576	0.06
328.9739380	0.95
332.9280396	0.12
336.8497314	0.06
338.1765137	0.01
340.0362854	0.05
344.9673462	2.52
347.0897217	8.45
348.0203857	0.09
349.0553589	0.98
349.6829834	0.03
351.8864746	0.06
353.2196960	0.07
355.0507507	0.14
359.7343445	0.12
362.9637146	9.06
363.9087219	0.12
364.7967834	0.23
367.3871765	0.05
370.7571411	0.07
373.0008545	6.26
378.9700317	0.12
380.7894287	0.08
389.0387268	0.08
391.0338745	100.00
391.9135742	0.04
399.3446350	0.23
399.9933167	0.17
401.5349426	0.02
409.1324768	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
824.7366333	55.05
966.5921021	100.00
967.4067383	99.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.131
Annotation	Delphinidin 3-(6''-malonylsambubioside)
Peak:m/z	Relative Intensity
216.9289551	0.05
220.7521820	0.02
254.0402679	0.01
255.1971130	0.02
259.2952271	0.04
271.1948242	0.14
290.2680664	0.03
294.8665466	0.09
300.0770874	0.78
301.1335754	1.74
314.0274353	0.05
324.3391113	0.03
325.1596680	0.06
326.8548584	0.03
343.1413574	0.17
352.3078003	0.11
354.2949219	0.04
355.2946777	0.10
357.1934204	0.09
369.1713257	0.05
370.3624878	0.02
371.1472778	0.11
373.1312866	0.03
395.3353882	0.02
396.1303711	0.07
397.2584839	0.11
407.8798828	0.06
415.2283325	0.02
445.2951660	0.02
463.2627563	0.54
477.2135620	0.23
499.2053223	0.06
503.1740112	0.14
505.2151489	100.00
506.4159546	0.13
515.0125732	0.14
517.0678711	0.24
518.4141235	0.15
519.1720581	0.05
535.5476685	0.03
545.4152832	0.13
547.2061157	3.45
557.1283569	0.05
559.1133423	0.08
560.9624634	0.05
562.8594360	0.03
571.1932983	0.46
573.3408813	0.08
575.2948608	1.31
577.2499390	3.46
577.9448853	0.05
583.3101196	0.16
589.3373413	1.39
591.1226807	0.41
601.2114258	2.60
605.4310913	0.18
619.3610229	0.49
636.2814941	0.04
637.3049927	0.09
645.5075684	0.02
647.4087524	0.03
653.1794434	0.01
663.0803833	0.12
681.2599487	14.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0883
Annotation	Spiraeoside
Peak:m/z	Relative Intensity
149.1022034	0.02
151.0187378	1.78
153.166687	0.01
163.1105957	0.11
169.0384216	0.42
170.0774841	0.06
179.0122375	2.35
182.2687836	0.02
183.1372681	0.04
185.2487488	0.06
187.1197815	0.02
190.1468811	0.03
190.8258362	0.01
191.8203888	0.03
193.0493622	0.31
199.1055908	0.08
201.1616211	0.01
205.1197357	0.03
210.9703827	0.39
213.0398254	0.02
214.1426239	0.04
215.1704102	0.04
218.933609	0.02
220.9262695	0.02
225.1008453	0.04
227.2518921	0.04
228.1427002	0.04
229.1002045	0.48
229.9241333	0.04
231.1617126	0.01
239.0158234	0.17
240.1530762	0.02
243.2170715	0.03
244.9758606	0.31
255.0479736	0.68
257.1235962	0.37
259.2979126	0.05
266.0584717	0.06
267.22995	0.03
269.1153564	0.23
271.3003235	0.03
272.6281738	0.16
273.2466736	0.80
283.2082825	1.00
284.0273132	0.03
285.3577881	0.04
286.3886414	0.07
297.1963501	0.82
299.3009949	0.74
301.0342407	100.00
302.2427063	0.49
311.2893982	0.07
312.2396851	0.06
313.2925415	1.33
315.3324585	0.20
319.0933533	0.04
323.0941467	0.07
325.2523804	0.60
326.0973816	0.03
329.1235352	0.02
331.5933533	0.01
341.1195679	9.00
342.1043701	0.06
343.1830444	6.02
344.2763062	0.03
352.1132202	0.02
354.15979	0.05
355.2294312	0.08
367.3775635	0.38
372.3103027	0.01
374.1342468	0.02
377.195343	0.05
385.1734924	0.04
403.3215637	0.23
426.8805542	0.04
427.5673828	0.02
445.2936096	1.06
464.2666626	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	264.88
Annotation	Unknow
Peak:m/z	Relative Intensity
96.8279724	7.73
112.9088135	0.13
180.8348846	100.00
218.9143219	47.54
220.2056274	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.0995
Annotation	Quercetin 3-(2''-caffeylglucuronide)
Peak:m/z	Relative Intensity
179.0867004	0.08
184.7139893	0.10
187.2412720	0.05
188.1813965	0.10
191.0410156	0.26
203.0151367	1.86
204.9795685	0.07
217.1734161	0.73
219.0823975	0.86
231.0602875	0.15
233.1195679	0.10
245.1427307	5.19
247.1752930	0.10
255.1280823	0.70
257.2640076	0.65
259.3008728	0.08
260.0988159	0.25
261.2547607	0.19
270.3402710	0.07
271.3077698	0.31
272.2395020	0.18
277.2375183	0.19
282.3058777	0.26
283.3020630	0.32
289.4434509	0.24
293.1772461	0.20
294.0564270	0.08
299.2913818	0.66
300.1050415	3.13
301.1966553	38.37
306.4559326	0.09
308.3219604	0.11
319.2659302	0.13
323.3743896	0.43
324.4836426	0.19
325.1541138	0.20
327.5895081	0.25
336.1776123	0.53
337.1121826	42.24
342.2363892	0.12
342.9816895	0.10
353.3569336	0.15
355.0419922	0.15
367.4255371	0.06
379.3375244	0.07
383.3937378	0.23
395.2910767	0.14
396.5237427	0.12
397.1350708	0.06
400.3853149	0.14
427.3307495	0.05
428.6303711	0.09
441.4946289	0.25
447.4837036	0.14
451.5004883	0.11
457.2882080	0.08
459.1421509	100.00
460.0326538	0.49
461.4125977	0.06
463.2153931	0.40
465.3972778	0.12
473.2143555	0.12
477.2642212	16.86
490.2737427	0.05
495.2060547	0.15
506.3397217	0.04
507.6814575	0.51
516.8361816	0.24
525.2349243	0.08
534.6261597	0.45
542.1391602	0.11
543.3175659	0.52
550.4990845	0.48
551.8350830	0.27
553.1126099	0.13
562.2012939	0.36
566.1469116	0.09
567.2821045	0.17
569.6059570	0.39
577.0377808	0.24
583.4760742	0.23
591.5225830	0.23
593.0532227	0.15
594.5121460	1.39
595.5263062	0.25
598.9102783	0.31
602.2515869	0.19
603.6193237	0.10
606.3888550	0.17
618.3042603	0.28
619.4522095	0.05
620.1911011	0.05
621.2207642	4.36
624.3532104	0.15
639.2720337	10.08
640.5507202	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3292
Annotation	Unknow
Peak:m/z	Relative Intensity
275.1764526	0.03
280.1861572	0.01
326.2901611	0.06
337.3571777	0.01
343.1252747	0.03
346.1762085	0.01
360.4039917	0.05
371.2749023	0.08
395.2869263	0.03
402.3873901	0.11
425.9804688	0.02
429.5419312	0.03
431.3343506	0.03
445.2720337	0.03
459.5443726	0.01
466.3912354	0.08
473.5131836	0.01
475.4656372	0.14
487.0813599	0.11
497.2289429	0.04
513.4790649	0.02
522.3892212	0.02
533.7556763	0.04
536.3258057	0.04
547.3935547	0.01
551.4345093	0.19
552.4880981	0.06
564.3734741	0.06
565.3019409	0.03
593.1444702	0.20
606.3478394	0.37
607.1000366	0.04
608.5578003	0.03
610.4685669	0.25
623.1187744	0.03
633.5939941	0.01
637.4558105	0.10
638.4666138	0.10
642.8604736	0.04
650.4225464	0.98
651.4273071	0.76
659.8203125	0.02
661.4907227	0.07
669.4200439	0.15
670.2303467	0.04
682.1903687	0.30
682.9544067	0.18
683.8229370	0.02
685.4850464	0.02
687.4186401	0.13
688.2844238	0.01
701.6869507	0.07
717.4911499	0.01
727.5455933	0.03
728.8183594	0.14
729.6159668	0.50
731.8776245	0.02
732.7615967	0.04
733.5553589	0.01
737.4841309	0.05
745.6558228	0.41
755.3921509	0.24
760.4539795	0.08
761.4348755	0.05
768.9838257	0.01
773.4949341	12.18
787.0850220	0.07
805.3906860	100.00
806.0919800	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.05
Annotation	Unknow
Peak:m/z	Relative Intensity
109.7040405	0.07
127.9708252	0.09
129.1185913	0.05
130.1528931	0.07
133.9718933	0.24
134.9351807	0.59
142.8099823	0.10
147.9813690	0.17
151.9233704	6.81
155.7306213	0.06
156.8546753	0.07
160.9223022	0.46
170.3874817	0.17
171.0267639	0.23
174.0497131	0.06
176.9089661	0.07
179.0597382	0.11
188.9342194	5.19
190.0470428	0.36
196.1386414	0.19
197.2052917	0.05
198.1863403	0.26
198.9779816	0.04
199.6379395	0.03
200.3200073	0.29
202.0011292	0.26
205.4233704	0.19
206.6408844	0.95
213.0545349	0.11
217.1954041	0.15
218.1301880	0.22
224.0986633	0.11
225.0195007	0.10
228.0160522	0.32
228.8438110	0.15
230.0037537	0.21
231.1624146	0.14
232.0963440	0.33
233.0010376	0.17
234.0120239	0.67
235.0558167	0.09
242.9753418	5.17
244.1771545	0.05
252.0505371	11.94
256.3312683	0.22
257.0128174	0.70
257.6784973	1.27
258.3325500	0.21
259.1512146	0.45
259.9725342	0.17
261.0526123	0.25
264.4598389	0.17
265.9817810	0.52
268.0484009	0.26
273.1279602	0.62
274.1511230	1.30
276.0985718	0.62
281.0392456	0.18
283.6430054	0.31
285.2561646	0.13
285.9235840	0.09
288.0101318	0.19
288.9613647	0.08
290.0009766	0.10
291.6264343	0.20
292.2495117	0.40
300.2908325	0.21
301.1550598	0.12
302.0324097	0.56
302.9664307	0.21
304.1912842	0.54
307.2468872	0.05
311.0867920	0.36
318.1096802	0.27
319.0831909	0.36
325.5287781	0.22
327.3125000	0.24
328.2059326	0.31
331.0606079	0.22
332.0449219	0.21
334.0945435	6.87
334.7172546	0.33
335.7365112	0.11
336.9889526	19.77
337.7606201	0.85
339.2642212	0.97
345.9226074	100.00
346.8276062	1.20
347.9366455	1.24
348.8962708	0.32
351.6187439	0.31
354.8259277	0.67
355.9495544	0.26
359.5896912	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	213.1498
Annotation	5-Oxododecanoic acid
Peak:m/z	Relative Intensity
96.9446411	0.13
106.0856018	0.05
109.1006775	0.09
111.0022583	0.06
123.2644958	0.02
124.9517670	0.03
132.9583740	0.02
139.0608063	0.11
141.0571289	0.13
143.2087860	0.02
149.1450806	0.10
151.0413513	0.17
157.1721649	0.04
163.2151337	0.02
165.1697540	0.80
167.1000824	1.28
169.0995331	0.41
171.0585022	0.03
172.0624847	0.02
173.1923981	0.03
175.0668030	0.06
177.1562347	1.78
179.8590393	0.03
183.0797272	26.56
185.0976715	0.99
193.2225494	0.51
195.1778412	100.00
196.2413788	0.03
198.0666656	0.45
213.1302338	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.84
Annotation	Unknow
Peak:m/z	Relative Intensity
97.0111923	0.19
172.3591614	0.10
212.8681641	0.10
219.0966797	0.03
232.8771973	23.32
248.7105103	0.11
270.8305054	100.00
299.1155090	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	657.1096
Annotation	Delphinidin 3-O-(2''-O-galloyl-6''-O-acetyl-beta-galactopyranoside)
Peak:m/z	Relative Intensity
199.1202850	0.10
205.0693665	0.07
211.3603821	0.12
238.0839996	0.04
245.1945953	0.05
252.2812958	0.06
255.1854553	0.07
259.2649536	0.06
273.0081177	0.09
283.2879028	0.05
296.2069397	0.06
299.1401978	0.22
301.0854492	41.18
312.1547546	0.10
315.1427002	0.15
327.1658325	3.85
330.3760986	0.22
357.1715698	0.04
358.2377930	0.08
359.0986328	0.27
361.4476929	0.10
372.2205811	0.04
378.3079224	0.07
395.3633423	0.04
396.9697266	0.11
402.0099487	0.11
409.0222778	0.04
418.3190918	0.20
419.2274170	0.21
437.3043823	0.15
445.2587891	0.14
453.4225464	0.34
459.2579956	0.08
463.3233643	0.04
464.0397949	0.16
477.1536865	100.00
477.7619019	0.52
481.0338135	0.81
494.2053833	0.32
495.0316162	0.11
503.2167969	9.41
510.2932129	0.36
535.2874756	0.37
541.4423218	0.18
559.4622192	0.12
566.3202515	0.09
569.3865356	0.17
575.4896851	0.23
586.9198608	0.15
592.6637573	0.05
597.6806030	0.07
610.2117310	0.22
612.3386230	0.08
613.2656860	0.37
615.1339722	0.17
620.6191406	0.22
625.2973022	0.06
634.2114868	0.04
635.0184326	0.05
636.3850708	1.63
637.4241333	0.11
638.5313110	0.56
639.1933594	0.50
639.8355103	0.02
657.2591553	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	842.2976
Annotation	Majusimine A
Peak:m/z	Relative Intensity
233.2611542	0.20
237.9091949	0.15
241.1692505	0.40
243.0490112	0.21
247.1103973	0.18
250.8756714	0.43
256.0081177	0.23
258.1373291	0.20
259.2419434	0.14
261.1129456	0.22
263.2298889	0.36
264.1071777	0.13
264.9222717	0.18
267.0959778	0.20
268.0899353	0.42
273.2442627	0.20
274.3661194	0.14
277.4288330	1.20
278.5653076	0.51
279.2588501	0.30
280.1708984	0.15
283.2292480	0.15
284.4001770	0.13
285.3182373	0.10
286.1711426	0.19
288.9147339	0.13
291.2645874	0.21
292.4011536	0.13
293.9844360	0.10
296.0874023	0.46
299.4047241	0.24
300.1915894	0.59
300.9319153	0.19
302.2155151	0.40
303.2676392	0.38
304.0223694	0.71
309.2507324	0.68
314.3731079	0.05
316.3756104	0.31
317.9294434	0.32
319.3499146	1.02
321.3991699	0.03
324.3555908	0.16
325.4600830	0.29
326.4262085	0.16
327.3404236	0.19
328.3591614	0.50
329.2534790	0.17
330.2771301	0.46
331.4448547	0.14
335.0617981	0.08
336.4368896	0.67
337.4287109	0.16
339.0891724	0.20
340.3989258	0.61
341.9619751	0.06
344.4815979	0.30
345.2774963	0.35
346.2014160	0.20
349.2409973	1.30
352.1429749	0.52
353.3695679	0.35
354.1658325	0.11
354.9005127	0.49
357.3789673	0.05
358.2638550	0.14
359.4179993	0.12
360.0511475	0.68
362.3645935	3.55
363.2239380	0.85
365.2892456	0.23
366.4318848	0.16
367.4096069	0.27
368.2757568	0.27
369.2780151	1.00
370.3454590	0.16
372.2689819	0.30
373.2031555	0.22
374.2966003	0.36
375.6694946	0.37
377.0627441	0.10
380.2187500	0.40
384.0717773	0.92
385.6068115	0.33
386.2186584	0.07
387.2638550	0.79
388.3760986	0.40
389.2480469	0.10
390.3486328	0.59
391.7579346	0.50
392.4185791	0.64
394.0562134	0.52
394.9591064	0.85
396.1711426	0.06
397.4901123	0.10
401.2056274	0.54
402.2203979	0.17
403.2797241	2.92
404.3804932	0.40
405.2996216	1.99
406.2847900	0.28
408.4553223	0.07
410.2345581	0.90
411.3248291	0.30
412.4228516	0.29
413.4339600	0.08
415.2003784	0.13
416.1226196	0.26
417.0580444	0.18
419.3430786	0.22
421.2617798	0.20
424.0913696	0.11
426.4692993	0.06
428.3907471	0.26
429.0912476	0.39
430.3940430	0.76
433.5996094	0.06
434.5091553	0.17
437.1041870	0.15
439.3484497	0.42
439.9853516	0.22
445.6576538	0.30
447.4032593	1.49
448.3850708	1.21
449.6721802	0.62
450.5078125	1.11
451.3666382	0.17
452.4349365	0.77
453.9696655	0.72
455.4931030	0.54
456.2894897	0.82
457.4241943	0.76
460.6085815	0.37
465.2445068	83.46
466.2448120	17.54
466.8515015	0.21
467.4648438	0.23
468.3988037	0.27
469.4653320	0.06
472.1655884	0.28
473.3371582	0.14
474.3640137	0.30
475.5368652	0.41
481.3973999	0.10
482.2308960	0.65
483.4729004	0.60
485.3464355	0.33
486.5906372	0.12
488.1978149	0.21
489.2880859	0.63
491.5251465	0.46
492.4023438	0.48
494.2612305	0.22
495.1182251	0.33
500.0142212	0.26
501.4297485	1.25
502.5518188	0.35
505.2882690	0.56
507.2055054	4.18
508.3347168	1.36
509.4866333	0.12
511.0556030	0.06
513.3737793	0.34
514.4533691	0.38
517.2847290	0.19
518.5195312	0.31
519.4536133	8.98
520.3879395	1.21
525.4866333	0.61
530.3875122	0.22
531.2402344	1.07
532.1964111	1.38
533.5952759	0.70
537.4360352	0.56
538.2889404	0.15
542.3084106	0.27
549.3605957	1.01
550.3085938	0.27
552.2387695	0.07
554.1318359	0.13
555.6482544	0.85
556.5005493	0.46
557.4108276	0.78
558.7703857	0.64
561.3248291	0.48
563.1505127	0.05
565.3219604	0.03
566.3920288	0.89
567.3664551	0.89
569.4317017	0.15
570.0358276	0.27
573.5586548	0.39
574.2416992	0.35
575.2749634	2.72
576.5006714	2.43
577.4197388	1.55
578.3146362	0.36
579.6427612	0.08
584.3673706	0.19
585.4380493	0.05
591.4167480	0.62
592.0865479	0.43
594.3218994	100.00
595.3112183	22.91
595.9130249	1.19
597.7788696	0.42
598.4641724	0.16
601.6560669	0.25
609.7852173	2.85
610.4714966	1.70
611.2546997	0.77
615.4399414	0.75
618.3605347	0.20
619.9558716	0.26
625.6851807	0.04
627.2804565	1.29
628.3344116	0.57
631.3021851	0.12
633.5530396	0.95
634.4691772	0.18
636.4443359	2.05
637.5475464	0.36
642.3344116	0.09
644.5614014	0.13
648.9261475	0.29
651.5149536	0.11
654.1995239	0.15
656.2371216	0.41
657.6514282	0.21
659.4349976	0.97
660.4445801	0.43
661.4734497	0.23
662.4064331	0.25
666.7173462	0.31
669.3530884	3.91
670.5263062	0.26
674.3372192	0.10
677.1050415	2.80
677.9064331	0.65
678.6518555	0.10
679.8027344	0.22
681.5049438	0.39
684.3401489	0.42
685.3325806	0.47
687.5072632	0.08
695.3375244	1.56
696.4150391	0.98
698.6743774	0.38
699.4885254	0.25
703.8353882	0.07
713.2940674	40.29
714.3753662	8.23
723.4037476	0.67
726.0934448	0.50
731.4918213	0.07
738.4099731	0.13
744.7620239	0.38
745.5695190	0.14
749.7501831	0.19
750.3730469	0.15
756.3051147	9.16
757.3229370	2.45
762.2507935	0.30
762.8588867	0.15
767.4038696	6.49
768.4896851	2.44
770.3834839	0.05
774.8739624	0.23
779.5197144	0.05
780.3754272	0.98
781.4672241	0.66
788.4076538	2.06
789.2642212	1.75
798.3842163	3.44
799.4302368	0.89
806.2568359	1.59
807.5685425	0.35
810.1889038	0.14
824.3586426	2.91
825.4363403	2.94
826.1087036	0.15
843.3713989	38.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.0961
Annotation	5'-Methylthioadenosine
Peak:m/z	Relative Intensity
96.9303131	1.05
103.0034256	0.05
107.0936890	0.03
115.1286621	0.10
115.7876282	0.06
118.9487915	0.03
121.9956207	0.05
123.1873474	0.05
128.8990326	0.03
130.2496185	0.02
134.1644287	0.02
135.8972168	100.00
138.8385315	0.05
144.9754639	2.34
162.8934937	5.13
166.0776520	0.04
170.8315735	0.05
178.1350250	0.07
181.9924316	0.08
183.0847931	0.10
187.1827545	0.04
192.0998993	0.01
199.0118408	0.03
203.1867981	0.10
207.9386292	0.04
209.0132751	0.02
213.2672729	0.12
215.2507324	0.03
216.8739319	0.09
221.1484985	0.09
227.3150940	0.02
228.0538635	0.06
232.0472107	0.04
237.1207581	0.03
238.0431824	0.41
238.9519043	0.08
251.9089966	0.71
252.8719177	0.05
254.3164062	0.06
256.9427490	0.26
261.2717285	0.04
266.1540833	0.02
267.4091492	0.03
269.8764343	0.04
279.8385010	0.90
280.6443481	0.16
282.1049500	0.03
288.4304504	0.09
289.1336975	0.08
290.1391602	0.01
291.5401306	0.12
307.1399841	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
112.9355774	0.37
118.7822418	0.16
122.8595428	0.18
130.0764771	0.07
136.9572754	0.06
138.0841827	0.32
143.0435028	0.13
149.2429810	0.06
151.0544281	2.05
153.0451050	1.84
161.0779724	0.73
164.9533997	0.23
167.0415649	0.31
173.1813202	0.11
175.0750732	4.25
179.1620331	0.09
181.0897827	0.15
182.0819397	7.12
193.0859680	0.51
194.9863281	0.38
196.9846954	100.00
205.1234589	0.86
206.9517212	0.20
217.1723938	0.60
222.9674988	1.68
225.0195007	0.16
225.6233215	0.08
227.2050476	0.06
229.3387756	0.02
234.7956238	0.09
239.0426636	0.83
240.7184448	0.17
242.8802490	0.16
252.9496155	7.55
271.0206604	0.19
272.2173157	0.05
286.1210938	0.04
287.2988892	0.11
291.2822266	0.03
294.3883972	0.21
295.0570068	0.15
297.1478882	0.05
299.3350830	0.16
313.0596924	12.85
314.3322144	0.08
315.2227783	0.60
316.9034424	0.08
321.2796326	0.11
322.9573669	0.09
327.2115479	0.07
330.8715820	0.06
338.7911987	0.04
340.5249939	0.30
341.1694641	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1198
Annotation	1,3-Dicaffeoylquinic acid
Peak:m/z	Relative Intensity
154.7946625	0.12
157.16008	0.08
170.7686462	0.20
173.034729	2.26
178.9764252	3.22
184.6379852	0.06
191.0890808	5.45
203.0720062	1.53
210.005127	0.04
211.3582916	0.06
211.9935608	0.19
214.3217163	0.20
220.273056	0.31
220.8930206	0.04
225.1233368	0.25
226.0492096	0.23
227.0961609	0.22
249.0516357	0.05
253.2272949	0.07
255.280899	0.73
266.8336792	0.05
273.1529541	0.18
281.1897583	0.07
282.2054138	0.30
285.1569214	0.18
291.211731	0.09
293.496521	0.27
294.239624	0.03
295.0291748	0.03
297.0737915	0.10
299.1913452	2.27
301.2424316	0.23
312.8381348	0.02
315.4624023	0.05
317.0526123	0.62
317.9764404	0.02
327.4129028	0.07
329.2957153	0.23
334.0680542	0.17
335.0512085	1.23
339.3496094	0.18
341.2318115	0.43
351.4429932	0.25
353.0953369	100.00
357.2019653	0.24
359.1942749	0.11
379.2183228	0.14
393.375	0.18
394.4514771	0.22
398.168396	0.19
417.2094727	0.12
427.2575684	0.19
429.0774536	0.09
434.3766479	1.55
441.3355103	0.10
446.2407227	0.04
452.2020264	0.04
453.1203613	0.05
455.574646	0.08
460.6550903	0.18
467.7498779	0.10
469.1209106	0.70
470.7692261	0.22
471.4091797	0.24
473.4733276	0.50
479.3834839	0.32
483.321228	0.22
484.2727661	0.13
486.6557007	0.23
490.9193726	0.25
493.3860474	0.07
497.4141235	0.17
500.4585571	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0904
Annotation	Glutathione
Peak:m/z	Relative Intensity
115.8769302	1.55
127.0479584	0.01
129.9165039	0.50
143.9363403	3.06
145.0102539	0.07
145.7316284	0.03
149.9781342	0.01
151.0334473	0.11
161.9071655	31.59
178.9361420	100.00
192.0698547	0.03
204.9956360	0.02
214.9418945	0.82
222.0903625	0.03
233.0980225	19.23
233.8591919	0.02
241.1336670	0.02
244.0100098	0.06
245.0897827	0.65
272.0626221	1.77
273.0829773	0.01
274.0922852	0.13
290.1163940	6.37
291.1063843	2.08
293.8646851	0.09
303.2467651	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.0832
Annotation	3'-Methoxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
136.9832611	1.28
138.1994019	0.10
139.8216858	0.14
148.9568024	0.81
151.3116455	0.04
153.0928345	0.43
154.0899963	0.03
158.8945923	0.16
161.0149231	0.26
162.0131226	0.17
162.9649658	0.29
167.0169678	0.18
177.1726837	0.09
178.1365662	0.31
178.9935150	2.59
180.2778931	0.08
181.0470734	0.04
191.0959473	0.25
197.0776367	12.08
198.0495911	1.06
203.9250488	0.04
205.0807495	1.15
209.0403442	0.51
213.1091309	0.04
219.0338745	6.95
220.0103455	0.73
221.0617065	2.51
222.1660156	0.11
230.9456940	0.78
232.1348267	0.17
234.5626221	0.11
242.2777710	0.08
243.3334351	0.11
249.0928650	1.08
250.0770264	0.03
256.8448792	0.02
262.8002319	0.07
267.0545044	0.42
268.0359192	0.04
271.0123291	1.57
272.2083130	0.37
275.1287842	1.48
275.7515259	0.38
279.2257996	0.03
280.9640198	0.90
286.2300720	0.07
293.0861206	66.47
294.1260376	6.01
297.1926880	0.24
305.1694641	0.12
307.6851807	0.12
310.9405518	2.79
312.0883179	0.41
314.2093201	0.07
315.0990295	1.58
316.2819214	0.17
317.2989502	0.04
327.2048950	0.03
329.0999146	100.00
330.1849976	9.36
330.9882202	0.03
341.2414856	0.03
344.2944336	0.09
345.2470703	0.11
353.3370361	0.23
357.1085205	0.07
359.1177368	11.55
360.2100830	2.23
363.6544189	0.22
365.4483948	0.15
371.2886963	0.12
377.2619629	0.05
388.3143616	0.09
390.3204041	0.15
395.2968140	0.06
402.1109924	0.09
403.1058044	0.10
406.9073181	0.08
408.2505798	0.06
411.1440735	0.15
412.0514221	0.02
420.5531921	0.12
429.1383362	0.37
431.3025208	0.06
445.1792908	0.14
446.4545288	0.21
447.3821106	0.16
454.8606262	0.19
464.1598816	0.04
473.1402893	0.57
473.9562073	0.24
476.3905945	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.0827
Annotation	3,5,8,3'-Tetramethoxy-6,7:4',5'-bis(methylenedioxy)flavone
Peak:m/z	Relative Intensity
132.0661011	0.11
132.9777374	0.34
134.0395203	0.15
135.0395966	0.45
135.8980103	0.03
160.9579926	7.49
162.0624084	1.00
167.9996338	0.05
168.9718475	0.06
176.0462036	0.02
177.0948486	0.10
179.0690918	1.36
180.0596008	0.29
184.9372559	0.09
187.3925476	0.02
193.0096130	0.08
194.1159821	0.06
196.9799500	0.02
203.1873779	0.04
205.0893402	1.54
206.1487274	0.06
211.2011414	0.02
219.2077332	0.02
220.1561127	0.04
221.0898132	0.11
223.3597107	0.10
249.0638123	2.27
250.1499023	0.44
253.1136169	0.02
261.2577515	0.05
267.0787659	100.00
268.0392151	14.01
285.2468567	0.11
286.3104553	0.11
291.3218079	0.07
293.0398560	0.12
299.4309998	0.03
306.3355103	0.04
313.3179016	0.05
316.1227112	0.06
318.7062378	0.02
323.5828857	0.02
330.0875244	0.07
333.3006897	0.03
339.6382141	0.03
340.9744263	0.07
344.1792908	0.03
346.2122498	0.10
349.3303528	0.11
355.4711304	0.05
357.1898804	0.06
365.1822510	0.02
369.3312073	0.02
370.4256897	0.04
371.2332153	0.07
380.1007385	0.02
383.1803284	0.25
384.2852783	0.11
387.1320190	0.04
391.4251709	0.27
392.2421875	0.27
393.2699280	0.05
394.2235413	0.35
411.2753601	0.40
412.0329590	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
96.87223816	1.94
99.2102356	0.44
146.0624847	0.59
149.0347443	3.05
150.0474701	0.44
160.9980469	2.33
165.0537415	0.44
173.9833527	1.47
182.1753235	1.13
189.2084808	0.75
193.2043457	0.67
195.1687317	3.35
206.333847	1.49
207.1733093	20.62
208.0618744	9.31
209.0934601	7.58
210.3850555	0.63
221.0786743	0.83
222.6013336	4.54
223.2199554	2.43
224.0935822	0.91
225.1782227	0.48
233.195816	6.12
235.2248535	1.19
236.0052032	1.10
237.1562958	1.15
251.0839996	100.00
252.1869507	29.74
252.928299	1.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.00019836	1.30
122.0997162	0.95
139.3855438	4.15
143.1754303	1.41
150.9302063	0.58
167.0425568	4.15
169.9024963	1.21
179.248703	1.58
180.0469818	1.77
180.9431	1.73
182.9009857	0.85
193.1853485	0.63
194.2073364	1.68
195.3188629	5.59
197.7273102	1.47
205.3437042	1.04
206.0571747	1.74
207.1914215	14.37
208.0641937	8.76
209.0701752	10.07
210.2945099	3.46
215.9396667	0.83
216.988678	1.29
221.0892334	1.67
222.5128021	4.11
223.2778625	15.58
224.032486	2.90
233.2000122	4.99
234.0228882	1.26
235.1423492	1.42
236.9174194	2.16
251.0749664	100.00
252.1583405	34.52
253.3031616	4.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1099
Annotation	Unknow
Peak:m/z	Relative Intensity
168.9765320	0.09
177.1455078	0.26
178.0125580	0.03
178.6305237	0.08
190.7926636	0.15
198.9099274	0.06
204.8082886	0.03
210.9962921	0.08
228.9715576	0.45
231.2875671	0.10
235.0898438	0.12
243.3670502	0.04
245.0327148	0.05
253.3292847	0.07
254.3976898	0.17
255.1311493	0.04
262.1333313	0.13
268.3353271	0.11
271.0942993	0.16
273.0427246	4.63
283.1969604	0.04
285.2109985	0.03
287.0587463	0.06
293.2393188	0.06
296.2561646	0.09
299.1099854	1.40
300.2011108	0.30
301.1340332	0.11
313.0386353	0.04
317.1015625	0.94
325.3071899	0.35
329.1160278	0.07
331.1797485	9.27
349.1742554	2.94
355.0593262	0.53
357.0686646	0.10
361.5638428	0.05
367.0627441	0.04
373.2557983	2.10
374.4606323	0.07
383.2792969	1.58
385.2442017	0.07
387.2925415	0.17
394.2442627	0.06
399.1046753	0.03
410.7736206	0.09
416.4195557	0.36
417.4223633	0.28
423.2442627	0.03
429.3253784	0.03
435.1836548	0.33
459.2957153	0.28
473.1766968	0.05
475.2324829	0.09
477.2276611	1.58
481.1439819	0.12
487.3091431	0.11
491.3225098	0.13
493.1986084	0.04
500.0958862	0.07
503.2994385	6.27
504.2726440	0.04
505.1942139	0.07
506.3383789	0.04
507.4374390	0.06
508.1671753	0.11
508.9591675	0.02
511.2100220	2.81
516.1580811	0.13
517.3894043	0.04
520.6291504	0.04
521.3961792	0.22
535.1886597	54.34
550.1397095	0.41
551.3778076	0.14
553.1006470	100.00
553.7573853	0.35
554.6852417	0.15
561.5336304	0.12
564.0830688	0.08
569.4656372	0.03
577.1683960	0.15
578.6690063	0.25
579.2847290	0.57
597.2240601	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0966
Annotation	Indoleacrylic acid
Peak:m/z	Relative Intensity
80.8490143	0.02
95.2909241	0.01
96.9730682	0.02
108.8695984	0.01
118.0591278	0.04
120.8082886	0.03
122.7805328	0.03
130.6009827	0.01
131.9102020	0.02
133.1088104	0.01
138.9973602	0.03
144.8648834	0.02
157.2214203	0.02
159.1268463	0.21
161.1357117	0.02
163.8103333	0.02
176.5106964	0.01
188.0086670	100.00
188.8522339	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.8847046	0.91
259.1112976	0.03
297.2728271	0.09
302.8995972	6.65
303.5212097	0.14
322.1827393	0.09
348.9941406	0.07
382.6785278	0.14
384.9725952	0.10
386.8224487	33.83
392.8832397	0.03
464.9451904	0.55
467.7460938	0.13
468.8700562	0.19
470.6457520	100.00
471.3367920	0.15
482.8945312	0.67
502.0391235	0.10
550.9696655	0.11
552.5953979	0.97
554.5419922	57.87
555.2565308	0.13
582.8671875	0.06
592.0629883	0.25
596.4017944	0.10
638.4791870	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7500153	100.00
123.5231476	0.02
133.1280212	0.05
145.1957855	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
642.4703979	19.46
676.9466553	3.05
967.4313354	100.00
969.0957031	7.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.0461
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
86.9256134	0.27
102.9150085	0.86
108.9257507	0.03
111.0869446	0.07
112.9327087	5.66
113.8108292	0.06
119.0253448	2.62
127.0150833	0.08
130.9170380	1.04
133.1041718	0.01
135.5833740	0.07
138.1919861	0.06
138.9699402	0.20
140.0761871	0.16
148.9546814	4.25
161.0272217	0.07
162.9494476	100.00
163.7694702	0.02
177.1614075	0.02
178.9825439	0.08
181.3590088	0.05
189.2105408	0.07
192.1296692	0.03
204.9184570	0.08
205.8002319	0.05
219.0678711	1.76
220.0281067	6.59
220.9973145	0.97
222.1058655	0.08
222.9721985	0.02
231.0749817	0.06
232.0619507	0.51
233.1832275	0.06
247.0185547	0.02
247.8590698	0.06
248.9818726	0.06
250.1233826	0.03
251.2100830	0.09
257.9055786	0.02
276.0703430	2.96
277.1466980	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.3065
Annotation	Unknow
Peak:m/z	Relative Intensity
145.2598267	0.09
153.5476685	0.03
156.1454163	0.13
167.1193542	0.63
168.1729736	0.08
177.0503082	0.17
179.0590210	0.04
183.0791016	7.80
184.1378632	0.71
189.0984192	0.12
198.2401733	0.07
211.0411377	19.14
212.0514221	2.10
216.8067322	0.10
223.1336975	0.15
238.1499329	0.13
238.9951019	0.08
257.2239990	0.14
260.3306274	0.15
261.4639893	0.04
267.3536377	0.05
284.9922180	0.23
291.3088989	0.07
300.0299072	0.47
301.0672607	0.43
302.0701904	0.09
302.9585571	0.23
304.1986084	0.03
305.2901611	0.46
308.0319824	0.59
309.5541077	0.21
310.3075562	0.22
315.0805359	0.07
316.7762146	0.83
318.5007935	0.35
319.1803894	0.99
324.4520569	0.04
332.2421265	0.06
338.3893433	0.10
341.2745667	0.17
346.4483032	0.09
349.4080200	0.10
352.4477539	0.19
358.9693909	0.28
361.4307861	0.07
365.7040100	0.70
366.3989258	0.15
367.3471069	0.29
368.1474609	0.25
372.2815552	0.19
373.1934509	0.25
376.4284973	40.84
377.4257202	1.63
379.3251648	0.37
381.3520508	0.17
391.7726440	0.03
401.2444763	0.45
404.6983032	0.20
407.5239563	1.03
408.3617249	0.37
413.3113708	2.03
414.6329041	0.80
415.7689819	0.40
416.4061584	0.36
417.5861511	0.22
418.6580811	0.04
421.6748657	5.08
422.4325256	1.92
423.4216003	0.12
425.0249939	80.51
425.9095459	1.93
427.3646240	1.14
428.4932251	0.21
429.5734558	0.08
431.9148254	0.04
434.9302673	0.29
436.5081787	0.26
444.2208557	0.15
446.1905823	0.15
449.4280090	0.15
451.2901917	0.28
451.8921204	0.21
460.5628967	0.36
463.2350769	1.31
464.4509888	0.08
465.7131653	0.11
472.8751526	0.41
475.8832703	0.09
532.8422241	0.15
535.4889526	0.61
541.4946289	2.26
542.5595703	0.45
543.3528442	0.15
549.3931274	0.17
550.2728882	0.30
555.5039673	1.56
556.7892456	0.06
558.3858643	0.20
564.4896240	0.07
604.5140991	0.18
619.6020508	0.35
632.5850220	0.25
633.3777466	0.15
654.4470825	0.96
655.5859985	0.69
665.7217407	0.11
668.8748169	0.23
689.4351807	0.06
714.5705566	0.04
716.6366577	0.19
719.4014282	0.13
733.6892090	1.50
734.5645752	0.11
735.6308594	0.27
742.6805420	0.29
743.5778198	0.05
744.5027466	0.17
751.5745239	100.00
752.5797729	33.37
753.6830444	0.98
778.6812744	0.11
800.3367310	0.08
810.6342773	0.21
815.3268433	0.05
828.7362671	1.78
829.7715454	0.23
842.6134644	2.06
843.5446777	0.71
848.5327759	0.32
850.4282227	0.14
861.6210938	0.14
877.0673828	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.0356
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
87.0158005	0.02
110.7812958	0.21
112.9110413	0.31
119.0336533	0.51
121.1912079	0.03
122.9509583	0.02
127.0299530	0.18
130.9178162	0.11
132.9928284	0.04
143.1905975	0.15
145.0273438	1.37
145.8876038	0.04
146.4900818	0.03
147.3132629	0.04
154.8417816	0.43
161.1312408	1.68
163.0607605	0.32
165.0062714	0.02
171.0159912	2.59
173.9204102	0.02
175.1941833	0.12
187.0947266	0.05
189.0664215	1.87
197.0202332	0.05
198.9773560	0.25
203.0253296	100.00
205.1033630	2.48
209.0806580	0.03
215.0773621	3.65
231.1977844	0.45
233.0259705	27.31
240.3290100	0.20
241.2852783	0.03
242.0578918	0.14
243.2625122	0.05
259.0126038	26.74
277.2728271	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	462.08
Annotation	L 735821
Peak:m/z	Relative Intensity
175.0616760	0.09
191.0021210	0.03
217.1793671	0.03
235.0912476	0.01
285.0673828	100.00
286.0570068	15.98
286.6679993	0.02
293.0021362	0.05
297.1578674	0.37
298.1167603	0.06
299.6415405	0.02
300.3085327	0.01
301.3569336	0.03
309.1173096	0.01
325.2906799	0.16
327.0744629	3.61
328.1205139	0.56
336.6189270	0.06
337.2582397	0.37
338.2978821	0.05
339.2177734	0.25
340.4710083	0.02
341.3519592	0.05
343.2408447	0.14
351.1230469	0.13
352.1014404	0.06
353.1157837	0.57
354.5961609	0.29
355.2281494	1.93
356.4800110	0.85
357.1427612	4.01
358.1332092	1.00
363.2115479	0.22
364.3487244	0.08
367.4182739	0.03
369.1095581	1.96
370.2741699	0.31
371.2742615	0.54
372.1401672	0.11
381.1958313	2.95
382.2760315	0.64
397.4378967	0.03
398.3999939	0.04
399.2890320	0.21
400.0758972	0.01
424.6582031	0.01
425.3992004	0.05
433.2720032	0.02
443.1552429	0.07
444.1898193	0.05
463.1925659	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8438110	5.19
208.8320312	2.83
290.8191528	20.04
292.7200928	26.12
293.3380127	0.12
336.5256348	0.03
340.9316406	0.09
374.5990601	4.25
375.7811890	0.87
376.5908813	9.71
382.8189087	0.35
391.1185913	0.04
398.6427002	0.10
401.0125122	0.13
424.9597778	0.25
438.6912842	0.53
453.3670654	0.16
454.8245239	0.07
456.7741089	0.08
458.6232910	15.70
460.6127930	100.00
475.8817749	0.12
482.4828491	0.08
483.9136963	0.04
484.8923950	0.45
498.0982056	0.24
498.8312378	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	414.0445
Annotation	Unknow
Peak:m/z	Relative Intensity
116.0701447	0.02
123.0429535	0.01
214.8919525	0.02
233.9645996	0.28
240.2383423	0.01
243.1905518	0.04
251.3272400	0.07
255.1469116	0.01
257.0656128	0.02
259.1600647	0.03
260.0308228	0.03
263.8188477	0.08
267.3363953	0.07
271.0997925	0.01
276.0097351	0.27
277.1466675	0.01
280.1499023	0.12
281.2614441	0.04
287.9716797	0.55
289.0427856	0.03
290.0014038	0.10
294.0484619	4.49
297.0873108	0.03
297.9563293	0.01
306.0864258	3.75
307.9513245	0.39
310.2142334	0.02
315.1943970	0.04
316.2017212	0.03
318.1079102	0.03
318.7293091	0.14
319.7303467	0.05
322.3039551	0.15
324.0098572	100.00
325.1239319	0.29
329.8900146	0.04
332.0817261	0.02
333.9917603	0.05
335.9832153	0.18
338.2449341	0.09
339.2093811	0.07
340.1743774	0.01
347.8936157	0.12
352.0457153	0.07
353.0233765	0.03
354.0995483	0.12
354.9597168	0.02
360.1004639	0.31
361.0443115	0.12
365.8542175	0.59
366.5486145	0.04
367.8367310	0.09
369.7130432	0.02
371.3450623	0.14
377.9281921	1.60
378.8261108	0.01
384.0077209	1.09
395.9085083	7.36
396.5456238	0.16
404.3479919	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	789.3298
Annotation	Correolide
Peak:m/z	Relative Intensity
241.4170837	0.12
295.2266846	0.05
311.3457031	0.16
330.1427612	0.08
363.0172119	0.05
367.2138672	0.03
394.7570801	0.05
400.6467285	0.02
412.1601562	0.20
419.3213501	0.15
430.3447876	0.16
457.4182129	0.16
459.5075684	0.09
461.3790894	0.15
472.2340088	0.08
475.3435059	0.09
490.3966675	0.20
509.3587646	0.05
514.4841309	0.07
525.7117920	0.10
542.3552246	0.04
556.4188232	0.05
557.5233765	0.14
560.5048218	0.14
562.1317139	0.10
572.2306519	0.11
574.4186401	0.39
577.3244019	0.13
580.5373535	0.61
584.4045410	0.13
587.2622070	0.07
588.5377808	0.04
590.6126709	0.19
592.5486450	0.34
593.5261230	2.61
594.5003052	1.73
595.4717407	0.04
598.0628662	0.02
602.8075562	0.15
604.3356323	0.47
606.4302368	0.26
617.0388794	0.27
620.4156494	1.94
621.2606812	2.04
622.4470215	0.99
624.2991333	0.14
627.0910645	0.25
627.6914673	0.19
630.0781250	0.17
632.6901855	0.15
634.2649536	7.68
635.4843140	0.24
636.6300659	0.11
646.2061157	0.11
648.6977539	0.13
650.5274048	0.09
651.3697510	0.18
655.2777710	0.50
666.3112183	10.44
667.3114624	0.11
673.3513184	0.07
675.3225098	0.07
677.0250854	0.04
685.3379517	0.08
693.4494629	0.22
696.3484497	0.07
703.3927002	0.70
711.3037109	0.33
711.9173584	0.04
713.5073242	0.28
715.5208130	0.60
716.2262573	0.04
721.3818970	1.38
725.6116333	0.05
729.3430786	1.23
739.4948730	6.73
753.2377930	0.52
757.4673462	100.00
761.3739624	0.12
771.4667358	1.65
789.4213257	2.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.1331
Annotation	5'-O-beta-D-Glucosylpyridoxine
Peak:m/z	Relative Intensity
92.7361984	0.03
105.9203262	0.09
107.9867783	2.50
110.0872192	0.01
115.8931122	0.49
122.8943634	0.04
123.9880371	0.15
124.7563782	0.04
128.8478088	0.05
129.4980316	0.02
130.3927460	0.03
133.9846497	0.82
135.9660797	2.84
137.6213837	0.09
144.0236359	0.05
147.1007385	0.02
151.9330750	11.07
154.0052490	0.07
157.9586182	0.04
169.9971924	9.91
170.9486847	0.07
175.2223358	0.03
185.1544495	0.10
198.4205017	0.03
201.9594421	0.07
202.6333923	0.02
207.9253845	0.06
209.0246887	0.02
212.2958679	0.10
215.8606262	0.03
216.9747314	0.08
235.2606201	0.10
236.0080872	0.14
241.2040710	0.02
243.1167603	0.05
245.2794495	0.06
246.3515930	0.02
247.0378418	0.04
248.1379089	0.04
253.2232056	0.02
258.3026428	0.01
260.1334229	0.04
269.0819092	0.02
273.8772583	0.19
276.7012329	0.07
278.1363525	0.05
284.2632141	0.01
286.0507202	0.07
288.1022949	0.01
289.7998047	0.06
291.3037109	0.12
292.0042419	0.08
296.1931458	0.42
297.1174927	0.01
299.7349243	0.14
314.1721191	100.00
316.5344849	0.09
323.3502502	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.1083
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9696350	20.49
164.0028992	0.41
165.1234283	0.02
205.1602325	0.08
213.2459106	0.06
311.0989380	0.03
312.2836914	0.06
332.2802734	0.10
337.3744507	0.45
355.0789795	14.77
356.1177979	0.23
357.0316772	0.18
362.9785156	0.04
374.2076416	0.24
377.2147827	0.07
378.1262207	0.16
379.0518188	0.08
381.4956665	0.05
397.2249756	0.04
407.3908691	0.06
409.1199341	1.02
457.1423950	0.14
462.7066040	0.24
476.8173218	0.18
478.1545410	0.30
484.6303101	0.05
489.6660767	0.18
494.9345093	0.06
499.1567993	0.03
501.5085449	0.11
517.9227905	0.11
523.1865845	0.10
541.1922607	0.32
543.6309204	0.13
563.1526489	0.12
568.9752808	0.16
571.0617065	5.60
572.0979614	0.13
583.0330200	0.09
589.1201782	0.12
601.2000732	0.45
601.8354492	0.05
690.9790039	0.04
718.4181519	0.12
719.4918213	0.04
744.1060791	0.06
745.2649536	0.37
759.5339355	0.06
761.1083374	7.77
762.2357788	19.49
763.1156616	100.00
764.0131226	3.09
767.2868652	0.07
779.0414429	0.18
805.5252075	0.04
808.2617798	0.05
952.7391968	1.14
953.8928833	1.42
954.7998047	2.33
985.5363159	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9018
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9329987	0.24
261.1141357	0.08
273.2071533	3.14
274.0662842	1.45
275.0616455	2.04
276.1417847	0.42
277.1384888	0.17
288.9010620	0.79
290.0387573	0.20
290.9988403	0.08
304.8759460	0.43
359.0369263	0.04
387.0695801	1.40
388.1289062	1.74
389.0125732	3.06
390.0476074	1.87
391.1248169	0.50
394.5834961	0.08
402.6879272	0.18
403.8258667	0.37
418.9028931	0.10
420.1535645	0.11
426.1980591	0.08
426.9954834	0.11
443.1108398	3.69
445.0823364	0.09
459.0587769	8.06
461.0609131	0.31
473.1102295	0.10
488.3158569	0.27
489.0760498	0.62
500.7045288	0.06
502.1013794	3.37
502.9442139	7.85
503.9190674	14.23
505.0424194	6.81
516.0023804	0.59
516.9255981	0.09
519.0161133	0.19
527.0354614	0.04
533.8317871	0.48
543.9495850	0.07
544.9837646	0.50
555.4648438	0.06
560.8685913	0.16
563.2443848	0.11
572.8601685	100.00
574.0442505	1.31
575.0005493	1.41
578.0581055	0.23
588.8886108	0.04
590.9802856	0.18
598.1325684	0.10
599.8298950	0.18
600.8973389	1.78
618.9281006	0.21
619.5411987	0.28
620.3229980	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1253
Annotation	Unknow
Peak:m/z	Relative Intensity
166.1185150	0.11
181.0766602	1.71
183.9186401	0.15
185.0764771	0.04
199.0834503	1.07
211.0913086	0.30
219.3901978	0.06
220.6494141	0.07
230.9781799	12.45
256.3017883	0.44
260.1274719	0.17
262.9894409	1.11
265.1527710	0.30
271.0446167	0.14
272.2861328	0.11
281.0955505	0.07
288.0372925	0.76
289.0656128	0.60
290.2777710	0.25
299.0939331	0.09
306.1201172	20.65
308.4489136	0.24
316.0945435	0.11
317.1516724	9.82
321.9444580	0.45
334.0539551	100.00
334.6710815	0.13
342.2477417	0.04
354.9707031	0.18
360.3283691	0.29
372.9617310	0.35
381.3898926	0.32
386.8814087	0.09
391.2567749	0.78
392.1104126	0.31
400.1759644	0.13
406.0502930	0.06
409.1810303	55.27
420.2802124	0.14
421.7001343	0.05
424.7193604	0.30
435.1333008	0.04
445.1229858	0.96
446.5316162	0.11
449.8391113	0.32
457.1710815	0.16
460.9779663	0.11
463.2402344	0.96
475.2102661	0.26
484.7543335	0.07
498.9287109	0.29
520.2375488	9.58
521.3272705	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.1289
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
74.8847961	0.05
86.7786255	0.06
95.1817932	0.03
96.9763947	0.03
109.0949249	0.10
110.7997589	0.13
125.0979614	0.08
126.8792877	0.12
140.0547943	0.10
141.2837067	0.05
155.1412506	0.19
165.0861664	100.00
166.8983612	0.06
169.2281036	0.03
180.8885498	0.04
183.1477661	72.89
185.1786194	0.03
191.1368408	0.12
197.5501556	0.16
199.3249969	0.07
207.1236725	0.86
209.1840057	6.28
211.0660400	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1724
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9910278	0.10
170.8878784	0.13
172.9634857	0.33
186.9437714	0.04
190.9650574	100.00
223.2602081	0.06
277.0098877	0.07
323.1154785	0.11
335.1690674	0.11
339.3944092	0.01
341.3015747	0.14
353.0610352	0.27
359.1134644	0.08
361.0422363	0.07
362.8741455	0.02
397.2716675	0.11
413.1297607	0.06
428.3078613	0.05
443.4586182	0.05
445.1227417	0.08
454.4996948	0.11
484.1019897	0.19
514.4972534	0.12
534.8762817	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9085
Annotation	4-Hydroxy-2',3,5,5'-tetrachlorobiphenyl
Peak:m/z	Relative Intensity
114.9501953	2.21
130.9193420	0.52
145.9473572	0.08
146.9314270	0.61
153.0822144	0.09
158.9601898	33.33
160.0837250	0.20
161.1466827	0.19
170.9841003	0.22
174.9454956	14.91
189.1712036	0.24
190.8744202	4.66
203.1162415	0.14
214.1156311	0.10
217.1596375	0.10
228.9071655	0.11
229.9060974	0.64
230.9490662	23.74
248.9625854	10.69
249.9847412	0.36
257.9168091	0.38
258.9707031	1.31
259.9284363	6.20
260.8670654	100.00
268.8005066	0.13
276.1392212	0.31
276.9772949	0.60
285.2285461	0.07
287.0143738	0.16
304.9370728	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	518.2524
Annotation	PS(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
151.0582123	0.30
152.9789276	16.78
170.8406982	1.55
187.0557556	0.03
213.9682922	0.03
239.9778748	0.50
257.8957520	0.04
277.3958130	0.07
285.1685181	0.04
322.4213257	0.05
345.0370483	0.04
350.2242432	0.03
355.1744995	0.28
383.1043701	0.07
385.4616089	0.12
387.6571655	0.12
413.0286255	0.05
419.4499512	0.07
425.7823486	0.05
427.7089844	0.08
431.2875977	100.00
431.9180298	0.11
446.3284912	0.12
450.3562012	0.09
453.1879883	0.18
458.0198975	0.03
464.7414551	0.09
480.7733765	0.04
482.2119751	0.45
500.4441528	0.22
501.2073364	0.09
503.1678467	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
401.2642822	2.77
794.8521118	1.00
949.7628784	13.18
966.623291	4.92
967.4067993	100.00
968.8755493	1.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9456558	0.56
128.9013214	0.02
130.9103394	1.91
146.9008179	0.72
158.8853149	8.35
174.8879242	100.00
215.0045166	0.07
216.8548584	0.27
233.0273132	0.21
244.9715576	24.91
260.9758606	0.50
270.2533264	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1099.1847
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
505.4096985	0.27
506.2557983	0.22
1055.7475590	0.56
1099.8713380	100.00
1100.7019040	0.23
1101.3198240	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1923
Annotation	Unknow
Peak:m/z	Relative Intensity
135.2189178	0.08
142.8556519	0.21
156.2080536	0.23
158.2197113	0.06
161.1276550	0.05
162.0851135	0.09
163.1051941	0.28
171.0785828	0.07
178.9114380	0.06
185.3480835	0.10
186.0379944	0.03
189.1447601	4.39
200.9111938	0.04
205.8851929	0.11
207.1812286	11.46
209.1988678	0.46
231.2126770	0.19
233.0935974	0.50
245.4046021	0.03
249.2273560	0.19
251.1340637	100.00
253.2250671	0.09
268.1541748	2.06
269.1655884	14.67
270.1213379	0.58
272.1949158	0.08
273.2820740	0.09
275.2054443	0.18
283.3202209	0.12
293.2840576	0.03
304.8157654	0.04
311.1308594	0.75
312.3304443	0.05
323.1957397	0.13
325.9215698	0.03
327.8484497	0.04
334.1900024	0.14
335.3564148	0.12
341.2359009	0.34
351.5772095	0.18
353.2859192	0.15
364.2335205	0.03
371.5559387	0.12
383.2570801	0.17
385.0871277	0.31
387.3265991	0.18
389.2492371	0.05
395.6214905	0.03
404.5611877	0.04
411.1509094	0.08
413.1351013	0.78
414.8722229	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.08
Annotation	Unknow
Peak:m/z	Relative Intensity
133.8990326	0.03
135.0984039	1.22
136.8319397	0.10
139.0015869	0.13
149.0541534	15.31
150.1245270	0.25
155.2204895	0.08
158.2223816	0.03
161.1616821	0.28
162.7530518	0.03
177.0214844	0.08
179.0874939	12.08
180.1088562	0.98
187.1663361	0.04
191.2080994	0.16
201.0422058	0.03
205.0816956	0.63
213.2370300	0.02
219.0324402	5.23
220.1406403	0.62
221.1576996	0.30
231.0990753	0.39
232.0807190	0.13
249.2538147	0.17
250.2100525	0.03
267.1830444	0.39
275.0868530	1.28
293.1045532	91.73
294.2005920	4.84
295.0450745	0.04
297.2259521	0.08
309.5102539	0.17
311.0608826	100.00
312.1278076	5.98
341.1821289	1.23
342.1300354	0.11
392.2238464	0.07
429.4156189	0.06
454.9438782	0.19
456.1882935	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9395
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9917145	0.04
158.9603577	1.87
199.1171722	0.06
217.0139160	0.06
229.0259399	0.20
245.2190857	0.04
246.2720642	0.02
257.1434631	0.03
272.9416504	100.00
313.7407227	0.05
331.0838013	0.10
356.7500916	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
146.9714813	0.08
149.0016785	0.05
151.0286560	2.18
155.0953369	0.05
158.9353638	0.04
162.8553162	0.10
169.0751038	0.14
173.9413147	0.01
178.9476776	3.22
185.0415344	0.04
186.8924866	0.06
188.9892578	0.03
191.1350403	0.11
193.0198975	0.34
195.1317139	0.03
199.1890869	0.04
200.3756104	0.12
204.9607239	0.13
211.0466919	0.50
213.0611572	0.05
214.7779694	0.16
215.4109955	0.02
216.9281311	0.03
220.8733063	0.08
222.1767273	0.03
224.7505798	0.02
226.9096680	0.24
228.0729370	0.09
229.1258392	0.78
233.2442322	0.04
237.0426178	0.02
239.0433960	0.20
240.2820435	0.10
242.0018616	0.01
245.0960541	0.38
249.0212097	0.07
253.2333374	0.03
253.8525085	0.08
255.0484619	1.41
256.1777039	0.12
257.1571350	0.56
259.0382690	0.03
263.1012268	0.05
265.1220703	0.20
266.0242920	0.15
269.2644653	0.24
271.1786499	0.21
273.1909485	1.10
274.1615601	0.02
283.2285461	2.14
284.0365906	0.05
285.1985779	0.07
287.1773987	0.02
288.5620422	0.02
293.2615967	0.08
294.9954834	0.13
297.2431030	1.09
298.9245605	0.43
301.0454712	100.00
301.6952515	0.22
313.1252441	0.14
315.1898804	0.38
324.4963989	0.10
325.1948242	1.36
325.9692383	0.03
328.9726562	0.07
331.0220947	0.05
339.4021301	0.04
341.2532959	0.25
341.9031982	0.07
343.1072083	7.09
343.8122253	0.01
353.0369568	0.01
355.1242065	0.88
358.9377441	0.02
367.2593079	0.31
369.1929016	0.07
371.1241455	0.01
373.3857117	0.36
381.3388672	0.08
383.2470703	1.73
384.2150574	0.10
385.2322083	0.11
392.9461975	0.04
396.3504028	0.03
402.0476379	0.03
406.4011536	0.06
427.1805725	0.25
437.1057129	0.04
441.0246582	0.01
445.1528015	1.23
458.4741516	0.02
459.2065125	0.15
460.2637329	0.10
463.1779480	1.64
468.3495789	0.04
469.4224243	0.04
473.0872498	0.02
474.2081604	0.02
487.1981506	1.46
487.9551697	0.07
495.1625671	0.08
505.4953918	0.06
506.2593079	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3137
Annotation	Phyllanthoside
Peak:m/z	Relative Intensity
384.4758911	0.06
401.4696655	0.33
413.5270386	0.07
517.3129272	0.14
539.4749756	0.18
557.5991211	0.14
560.2901611	0.14
575.2611694	0.14
624.7315674	0.09
642.2048340	0.30
668.2805786	0.07
686.6790161	0.05
687.8398438	0.13
706.3818970	0.09
726.4156494	0.09
727.7684326	0.64
728.4866943	2.53
729.5315552	0.06
744.8026123	0.25
754.4619141	0.24
760.2656860	0.51
771.5020752	3.22
772.4598389	100.00
773.4585571	10.34
774.1778564	0.05
786.0699463	0.38
787.2222290	0.44
805.4251099	60.12
806.0859985	0.10
807.2567749	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.0654
Annotation	Unknow
Peak:m/z	Relative Intensity
135.8946991	0.04
141.8328552	0.09
150.1417542	0.06
157.9114838	0.20
169.8251953	0.60
171.9766235	0.08
184.1290894	0.04
185.6553345	0.13
187.8519135	0.65
197.0338440	0.04
202.0449829	0.32
203.9690704	0.19
206.0137024	0.08
211.8597870	0.09
213.2651215	0.32
213.9460602	1.28
217.9378662	0.41
219.8849487	2.93
226.0298157	0.19
228.0074768	0.10
229.1444244	0.05
231.5084686	0.08
234.2460938	0.04
235.8869171	0.99
236.8040619	0.07
237.9124756	0.55
241.5584717	0.19
243.9284973	0.06
246.0373993	0.22
249.2397156	0.14
250.0812378	0.10
257.2618408	0.03
259.8908081	0.03
262.0281372	0.02
263.8820801	12.73
276.0001221	0.09
277.6572266	0.13
280.0571594	0.20
281.9564209	67.51
283.6491089	0.04
287.0081177	0.03
290.0437622	0.25
293.6581726	6.74
294.3572998	0.13
296.1141357	0.13
300.3116455	0.03
304.7691040	0.04
306.0787354	1.13
318.0778503	0.47
319.0695190	0.16
324.1248169	7.34
332.1029053	6.03
332.9301453	0.05
336.2303772	0.08
337.0967712	0.18
340.3282471	0.04
343.9887695	2.96
347.8338013	0.27
348.6624146	0.22
350.0413208	100.00
350.6757202	0.32
354.1613770	0.16
354.8078308	0.02
357.8012085	0.49
361.8073120	1.61
364.1291809	0.26
366.2255249	0.04
368.1960144	0.24
370.9451294	0.03
374.1427002	0.26
375.9414978	0.13
377.3036194	0.11
379.8513794	0.71
382.2978821	0.10
384.0213318	0.07
385.0856934	0.06
393.9523621	0.05
394.8737183	0.07
405.8908386	0.09
407.3576965	0.11
409.2958374	0.05
410.1118774	0.17
411.9155884	0.24
412.6567688	0.06
414.4575500	0.17
415.7654114	0.08
421.3431091	0.04
424.3831177	0.12
428.1859131	0.03
429.5437317	0.10
437.9472961	20.59
438.7796021	0.22
441.2014771	0.26
443.5658875	0.05
453.8684998	0.07
455.9775085	45.83
456.8274231	0.23
459.8936462	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0808
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
122.9418335	0.03
135.9622955	25.23
141.0956879	0.01
165.0462341	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	388.5668
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8744583	0.94
127.0131760	0.37
127.9044876	2.57
130.8985596	0.35
131.8927307	0.18
133.0853729	0.95
134.8817139	4.92
138.7481232	0.32
142.9498596	0.86
145.0962524	0.20
145.9699707	0.18
148.9182739	21.00
161.0031433	19.44
167.0375977	3.38
176.9256592	0.35
179.0691833	26.95
192.9267731	1.60
203.2824249	0.17
205.1384277	0.60
207.0986023	0.17
208.1438141	0.21
210.0257874	0.86
210.9791870	6.08
219.1792297	2.67
225.8792725	0.31
228.1436462	0.28
241.6799927	2.85
252.2129211	2.14
254.0432434	9.84
268.0864868	0.20
272.1379700	65.92
285.7439270	4.52
288.3178101	0.61
289.7900391	0.29
293.0705566	55.58
298.6154480	0.32
300.6276855	13.06
306.1705322	0.75
307.5793457	100.00
308.3290710	1.39
309.1056824	0.26
311.1108398	23.97
322.6081543	18.27
324.3174438	0.21
325.1645508	1.30
339.1988831	0.71
342.5045776	1.02
343.1503296	13.33
343.8149719	0.91
347.1611938	1.00
355.0928650	0.17
359.3874207	0.14
370.0814209	1.44
372.2215271	0.58
379.2554016	0.18
404.2949219	0.47
416.1825867	3.15
422.1051636	0.77
434.2382507	49.16
435.4626770	0.58
440.2082825	26.57
466.2023010	34.78
466.8435974	0.30
484.1508179	22.83
487.3535767	1.03
505.0093079	32.53
535.9650269	0.44
554.1030273	0.57
580.3259277	3.05
592.2252808	0.38
598.1948242	27.17
602.6186523	0.32
616.2054443	24.87
617.0730591	0.74
628.2230225	4.52
629.5383301	1.73
649.2523804	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.11
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
134.1665955	0.02
135.0753937	0.14
141.1299591	0.10
149.3037720	0.06
151.0086975	4.69
161.0275879	0.06
161.9426575	0.14
163.2345428	0.03
164.9462280	0.48
168.1651154	0.02
190.7012939	0.17
195.1122437	1.12
209.1649475	0.14
214.6388397	0.11
228.9487610	0.06
238.3711243	0.14
241.0086060	0.10
244.3403015	0.04
245.3318787	0.05
252.9853210	0.03
265.2726746	0.09
267.2426453	0.12
269.1153564	0.71
270.3113098	0.04
271.2638855	0.02
272.0089111	0.06
282.2684937	0.08
283.9471741	0.07
285.1611328	0.12
287.0753479	100.00
287.6867676	0.37
288.6687622	0.03
297.3341064	0.08
298.2734070	0.08
301.0759888	0.13
303.1189880	0.06
305.1954346	0.17
310.9127197	0.04
316.9331055	0.11
318.6969299	0.10
320.1159363	0.11
321.1615601	0.04
326.9234619	0.03
329.1873779	1.50
332.1105347	0.05
343.0734863	0.21
343.9843750	0.04
346.2996216	0.04
355.3531189	0.11
357.4591675	0.05
359.2284241	0.13
365.3892822	0.11
367.3392944	0.13
370.3077698	0.12
374.2816772	0.05
377.1113586	1.48
382.7044983	0.10
384.6165466	0.18
385.4398499	0.03
386.3528442	0.05
387.3764954	0.08
389.3949280	0.02
391.3587341	0.06
401.2283936	0.10
402.2158813	0.03
403.2588806	0.23
404.4584045	0.27
405.1863098	0.40
407.3467712	0.04
411.9275208	0.09
413.3755188	0.11
418.2693176	0.03
419.0469666	0.06
425.3049011	0.15
426.2706299	0.07
430.5138245	0.85
431.3663635	0.65
434.0921021	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2758
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
135.0586243	0.21
137.1873932	0.05
142.7144470	0.38
145.0614929	0.31
147.0154266	0.41
148.9067535	0.70
152.9703979	0.14
154.8604279	1.32
157.0142517	0.18
159.0927277	0.07
161.0923462	0.40
162.9161987	0.74
165.0258179	0.38
173.0814209	1.20
175.0165405	0.33
177.0464478	0.75
179.0522614	0.15
180.0331726	0.11
185.0561829	0.17
187.0929413	0.66
189.1815948	0.17
193.0776978	0.23
195.3312378	0.05
198.0183105	0.87
201.0255432	0.29
205.1645813	0.23
209.4082031	0.04
211.3518677	0.11
213.4391785	0.27
216.1979675	0.19
219.1321106	0.05
224.2500610	0.14
225.2253113	0.22
230.9799194	0.05
233.3279724	0.08
235.1640320	0.23
243.2529755	2.92
244.9889679	0.04
247.1804657	0.13
257.1796570	0.34
259.1243591	0.24
261.3309937	8.46
266.1378479	0.06
273.2700806	0.24
275.5222473	0.14
279.4428711	0.45
294.3323975	0.08
297.2188110	0.04
299.0390320	0.59
304.2510986	3.33
305.4260559	0.29
307.0392761	0.22
317.3105774	1.57
321.4030151	0.39
330.4191895	0.11
331.0697632	0.39
333.4435425	0.49
335.2984009	86.39
337.1724243	0.17
342.1168518	0.10
345.1916504	0.10
353.3747864	0.12
356.7751465	0.08
358.3530884	0.05
359.3542480	0.05
362.4974365	0.10
367.8196411	0.13
378.4763489	0.50
380.3886414	0.05
384.1713562	0.04
385.6073914	0.08
388.1889343	0.07
415.2763367	11.21
421.4075012	0.08
423.2308960	0.23
429.4474792	0.48
430.3724365	0.19
432.9612732	0.99
433.5778809	0.25
434.3502502	0.13
440.3513489	0.05
444.2507935	0.22
458.1915588	100.00
459.0885010	0.98
476.0459900	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1102
Annotation	Unknow
Peak:m/z	Relative Intensity
176.8927765	0.05
178.8608093	0.04
209.0425262	0.04
229.3178101	0.12
230.1053314	0.04
255.1469116	0.17
271.1751709	0.80
273.0922546	4.79
274.3549194	0.06
285.3116455	0.04
287.3678589	0.07
296.9510803	0.06
299.1315308	1.90
300.4761963	0.59
301.3479614	0.02
302.7792664	0.38
303.4469299	0.21
317.2268677	0.42
324.3388672	0.06
331.0628662	9.17
331.7048950	0.06
337.2114868	0.13
341.1890259	0.12
343.0172729	0.27
347.2923584	0.17
349.0831909	5.13
352.1286621	0.07
352.9790039	0.16
355.1950073	1.00
357.2440186	0.12
365.3182373	0.18
373.1600342	2.32
376.9943237	0.15
383.1528320	2.16
392.9981079	0.05
401.4121704	0.08
405.4307861	0.20
406.1716919	0.08
411.2315674	0.17
417.3198853	0.10
425.6815796	0.05
434.8264160	0.28
446.2302856	0.28
475.2793579	0.07
477.1930542	2.53
478.2157593	0.06
481.2495728	0.10
482.6867676	0.08
491.1459351	0.21
493.3041382	0.09
493.9071045	0.06
503.2575684	6.05
507.2400513	0.17
509.1383057	0.12
511.1657715	3.05
516.0170898	0.13
520.9991455	0.31
533.0553589	0.23
535.1880493	53.40
547.1408081	0.08
549.3616333	0.21
553.1137695	100.00
553.7874756	0.51
555.2099609	0.11
561.1409302	0.21
565.4058228	1.00
574.8316650	0.05
578.7504272	0.47
579.4327393	0.48
597.1121216	0.11
597.8146362	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	354.1286
Annotation	Boc-Asn-OPhNO2
Peak:m/z	Relative Intensity
106.8925171	0.02
130.8590698	0.05
134.1474762	0.02
135.0525208	0.04
145.9951477	0.12
159.9280243	8.35
166.0748138	0.06
169.1679993	0.03
173.1594086	0.03
173.9519348	0.02
175.1306305	0.15
177.1020508	0.11
179.1131134	0.14
182.9598083	0.01
186.5061493	0.02
192.0177307	100.00
196.0510101	0.02
198.9846344	0.07
199.8562317	0.02
206.1579132	0.02
207.3416595	0.02
210.2174988	0.02
222.0364685	0.09
231.1173096	0.06
232.1146240	0.10
234.0003967	0.07
235.1062012	0.05
242.2424622	0.01
243.2213440	0.03
244.3509521	0.05
250.1370544	0.02
252.0073547	0.21
253.0488586	0.03
256.0973816	0.01
258.0972900	0.09
262.0728760	0.04
263.0415649	0.09
263.8619690	0.08
267.1397705	0.01
268.3065491	0.01
269.6183777	0.10
271.9197998	0.04
274.1705322	0.02
274.7992859	0.07
276.0947266	0.02
277.9308167	0.02
280.0318604	0.07
288.1199036	0.15
293.3330383	0.04
294.6163330	0.07
297.9346924	0.02
306.1901550	0.05
307.4223633	0.01
308.4697571	0.06
309.7931213	0.16
312.9808960	0.20
313.6878052	0.02
317.7522278	0.24
318.8227844	0.15
322.1234741	3.59
324.0246582	0.02
325.1762085	0.03
326.2586365	0.21
327.2826233	0.04
331.3271790	0.11
335.4552307	0.36
336.1900635	0.81
337.1411438	0.38
345.6567078	0.27
354.3125305	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.0861
Annotation	Kaempferol-3-Glucuronide
Peak:m/z	Relative Intensity
152.9162445	0.03
209.1971436	0.00
213.076416	0.02
285.1095886	0.02
287.0637817	100.00
287.9333801	0.01
299.0395813	0.02
300.3200684	0.01
301.3262024	0.03
311.1365662	0.01
317.1496277	0.01
319.7781677	0.01
371.5249939	0.01
375.1781006	0.01
403.0341492	0.01
444.3435364	0.01
445.160553	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2247
Annotation	Gilvusmycin
Peak:m/z	Relative Intensity
221.4464264	0.57
341.1707153	100.00
502.7594604	0.24
683.0108643	15.12
683.7727051	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.05
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
86.8688507	0.09
114.9447479	2.85
132.9374084	67.87
135.0428162	4.60
178.9969788	100.00
206.8056030	0.05
219.2253113	0.03
230.9220581	0.08
249.2310181	0.03
264.9817505	0.06
277.0859985	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
137.0102844	0.07
140.9105988	0.22
149.0100708	0.12
150.9544067	2.35
152.9725952	0.17
158.9005737	0.06
160.9739685	1.27
164.7863464	0.14
171.0674591	0.04
175.2544556	0.06
178.9700928	0.11
181.1256866	0.10
185.0503845	0.07
189.1751709	0.10
193.1578827	0.38
194.9574280	0.13
196.0279999	0.09
197.0629425	0.39
212.9755707	0.14
222.9315491	0.15
225.0279846	0.19
227.1403503	0.14
228.9723816	0.05
237.1379089	0.24
248.9713745	0.07
252.8926086	1.00
263.2268677	0.15
265.1236572	0.10
267.2372742	0.16
269.0108032	0.14
271.2427979	0.19
273.2759094	0.18
279.4269714	0.66
286.8267822	0.07
293.3051147	0.19
299.1604614	0.25
299.8631592	0.20
311.0173340	0.13
313.1308594	100.00
314.2749023	0.15
315.1682129	0.52
322.9961853	0.07
331.3639526	0.05
339.1022339	0.22
340.1498413	0.58
341.1358337	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0931
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
130.1419983	0.06
130.8831940	0.04
136.8364105	0.03
151.0863495	0.06
152.8750153	0.02
161.1239624	0.09
165.3584747	0.05
175.0721741	0.12
189.1284180	0.01
195.1618347	0.03
211.2007141	0.02
211.9811401	0.01
217.1638794	0.21
219.3387299	0.04
222.3246460	0.02
223.0981293	0.04
229.3531494	0.07
236.9871216	0.02
238.8612061	0.03
243.1350708	0.03
250.8779602	0.02
253.3729248	0.03
257.2547302	0.05
267.0382996	0.08
269.1404419	0.20
271.2067261	0.07
277.1511536	0.03
282.9213562	0.02
284.1059570	6.99
285.0859985	100.00
286.1706543	0.74
288.9214478	0.03
292.8854980	0.07
297.1843567	0.07
298.1859131	0.02
299.1014404	0.09
302.1371460	0.09
303.2813110	0.07
308.9788818	0.02
314.3414917	0.02
316.0250244	0.02
325.1409302	0.01
327.1646423	2.71
328.2826538	0.08
330.4438782	0.04
337.1093140	0.02
343.3553162	0.02
346.8215637	0.06
348.3358154	0.10
350.3414001	0.04
351.1921082	0.03
355.4528198	0.04
357.5143433	0.02
359.4164429	0.03
361.1189575	0.03
363.3785400	0.03
369.2172852	0.13
375.3283386	0.12
383.5564880	0.02
385.2528992	0.14
387.0832214	0.26
401.2497253	0.66
403.3183594	0.06
404.2029419	0.03
405.1430969	0.06
405.7525635	0.02
411.1529541	0.03
415.0746765	0.06
417.3084106	0.07
428.9524536	0.22
430.2434387	0.07
432.1065979	0.02
445.0702209	0.13
448.4031067	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.02
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9539719	0.04
137.9029541	0.11
139.9517822	0.06
141.7377625	0.13
144.9267120	0.11
147.2603149	0.06
150.0939026	0.06
157.1443939	0.03
157.8252869	0.08
158.9093933	0.08
168.7911682	0.18
169.9370422	0.10
171.8015137	0.09
174.1207275	0.27
184.8779144	0.10
186.0047607	1.59
186.9984741	0.11
188.9901733	0.08
195.9404907	0.25
198.0572662	0.77
199.4873199	0.31
200.1087952	1.02
201.8845673	0.40
204.0556488	0.05
206.0660706	0.18
208.0390320	1.27
209.9084930	0.09
212.1862183	0.04
213.9472961	0.22
215.9113159	2.40
217.9398499	1.17
218.8832703	0.08
223.8011017	0.21
225.7324066	0.85
227.1680298	0.17
227.8454895	0.66
230.0606689	5.87
232.0907288	0.18
233.4017029	0.77
234.0205383	9.96
236.0602264	0.07
236.9742126	0.15
237.9338226	0.28
239.9622803	0.93
242.1139526	0.88
242.8066101	0.04
243.8320923	0.59
245.0041504	0.81
245.9670105	1.44
247.7968445	1.63
248.4215393	0.02
250.2147217	0.12
251.9949341	3.69
255.9822083	0.20
256.9781494	0.11
257.8129578	1.20
259.9807434	1.14
262.0617065	0.43
265.9942932	2.83
267.3103333	0.22
270.0844116	0.49
271.8240967	0.83
273.8952026	0.22
276.0045166	0.78
277.2732544	0.53
277.9416809	0.97
282.2018127	0.16
283.7496948	0.07
286.0406494	0.83
287.0675964	0.15
288.0443115	1.25
289.9046936	1.79
291.2034912	0.42
291.9394226	0.14
292.7578735	0.34
293.9991150	1.87
297.9111938	0.03
299.9009399	6.15
301.7287598	0.56
303.7260132	1.02
304.4963989	0.19
305.4761353	0.24
306.1040039	0.93
307.0544434	8.73
308.0686646	2.39
310.0238647	0.09
311.0297852	0.12
311.9538269	0.40
314.0878296	0.32
315.5583801	0.50
316.7309265	0.03
317.9723511	14.18
319.9459839	26.86
321.0524292	1.86
322.2661133	0.18
323.8889465	0.95
324.9980164	0.09
326.7590942	0.09
328.0941772	0.74
328.8426819	0.45
330.0410156	0.92
331.9018250	7.64
333.1099854	0.21
334.1713867	0.53
336.1351318	4.61
336.9296265	6.75
338.0325928	4.26
339.2196655	0.27
340.0286865	0.11
340.9423523	0.30
342.1025391	0.62
343.9334106	1.87
345.2828064	0.37
346.0510254	1.20
347.0214233	0.05
348.0550537	1.67
349.8966064	100.00
350.9741821	1.10
352.0350952	0.73
353.0228882	0.20
356.0506592	2.53
358.1326294	0.86
359.0902100	0.74
360.1157532	1.17
361.9248352	13.22
363.4121704	0.42
364.1849060	0.44
365.0700684	0.37
366.1407166	0.37
368.1893005	0.28
371.6567078	0.95
372.7237244	0.61
373.8597412	3.03
376.1016541	0.50
378.0490417	0.55
379.8993225	57.97
380.7624207	0.59
381.3918152	0.15
386.1470337	5.06
387.0783691	1.07
387.9797058	0.07
390.0191345	4.50
391.2816162	2.81
391.9179993	7.28
392.7724915	0.14
394.0361023	1.26
396.4770508	0.04
398.5317688	0.15
399.8885193	0.17
403.8437805	5.00
404.4942322	0.18
407.9745789	22.19
409.1608887	1.59
410.0421143	2.50
410.9293518	0.08
421.2091370	13.06
422.0727844	36.87
423.2618713	0.73
424.3086243	0.26
443.0035095	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	780.1517
Annotation	Unknow
Peak:m/z	Relative Intensity
218.0409241	0.21
219.3846283	0.26
220.1726990	0.06
221.1397858	0.05
228.2761230	0.11
231.1245575	0.24
232.0240936	1.67
236.0520020	3.70
237.1112213	1.37
238.3211060	0.06
238.9319611	0.02
241.3101196	0.08
244.8380432	0.20
248.0174103	0.10
251.1456909	0.08
251.9464722	0.09
256.0359802	1.06
257.0245972	0.17
260.0315552	0.05
260.9953308	0.11
261.9906311	0.22
264.0042419	26.26
265.0592041	5.11
266.1488647	0.06
274.0583191	1.14
275.1316223	0.33
276.0847168	0.11
277.2105713	0.54
278.1669922	0.15
280.2171021	0.27
287.0734863	0.03
288.1995239	0.21
289.1329956	0.65
290.2128296	0.36
295.0776367	0.16
297.1261902	1.54
298.1316833	0.12
301.9533386	0.03
303.0414429	0.31
303.7968750	0.07
307.1887817	6.32
308.1972046	1.63
314.8666382	0.06
319.1426697	0.16
320.8440552	2.23
321.5413208	0.39
322.3075256	1.32
323.1445007	0.30
327.0273438	0.54
328.0343018	0.05
330.0501099	0.11
336.4319153	0.17
339.0102844	4.47
340.1487427	1.78
341.1988525	0.11
342.9983521	0.09
347.1690063	1.78
348.1527100	1.35
349.2354126	0.17
350.0995483	0.05
351.1947632	0.09
352.2432251	0.07
356.0542603	0.05
357.4897156	0.47
360.9541626	0.17
363.1350098	0.10
365.0827332	1.22
366.1038208	0.33
369.0849609	4.17
370.0740356	0.78
374.4902954	0.27
375.1797791	0.77
376.4486694	0.28
386.1336060	3.88
387.2236938	1.93
390.3203125	0.11
391.3150635	0.04
393.1668701	15.90
394.1580811	4.75
398.4475708	0.05
399.0982056	0.43
400.1218262	0.57
401.0364380	0.06
404.9573975	1.86
406.1463013	0.71
410.2677612	0.03
418.1953125	4.76
419.2115479	1.11
423.0769043	0.55
424.0651245	1.31
426.0838013	1.14
427.0487671	0.32
436.1192017	0.89
437.2045898	0.29
440.2368164	0.07
449.5926514	0.17
450.3262329	0.86
451.1683350	0.24
453.1525269	0.06
454.0481567	0.12
468.2344360	12.56
469.3010864	2.49
471.1123047	1.79
472.1981812	1.22
472.9317017	0.20
482.9720459	0.08
486.2437744	0.07
489.1546021	28.32
490.1027222	10.83
490.7545776	0.04
497.2837524	0.15
501.0317993	0.12
508.0678101	0.04
512.0010986	0.07
515.2289429	0.13
516.1112671	0.03
519.2501831	0.06
523.2165527	0.11
525.2229004	0.68
526.1801147	0.31
527.0351562	0.08
527.9367676	0.34
529.2568359	0.09
537.1654053	0.59
538.4081421	0.49
543.2582397	11.27
544.2622681	6.53
544.9250488	0.03
548.0358276	6.75
548.9727173	3.58
555.1112671	1.83
556.1752930	0.60
558.2918091	0.27
559.0733032	0.30
573.6367188	0.17
576.1599731	15.73
577.2355347	8.86
582.5165405	0.26
583.3777466	0.08
595.0607910	0.22
599.5211792	0.06
600.3248901	5.94
601.2780151	3.20
602.1024170	0.17
612.0140991	0.65
612.8862305	0.06
613.5736694	0.10
618.1867676	100.00
619.2307739	52.26
619.8406982	0.20
621.3117065	0.10
630.1948853	1.49
631.3702393	0.59
633.2440796	0.18
635.3204346	0.10
651.0928955	18.47
652.1923218	11.72
678.2335205	0.30
687.2797241	0.64
688.2669067	0.09
705.1977539	13.82
706.2896118	11.18
717.1926880	0.18
762.2427368	1.22
763.3270264	1.39
764.2986450	0.36
781.1870117	47.40
781.9091187	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.05
Annotation	Unknow
Peak:m/z	Relative Intensity
101.0038528	0.02
104.9342041	0.83
110.9458923	0.14
115.0672913	0.02
128.9626160	1.64
141.0704956	0.23
158.8978882	1.05
172.0847778	0.10
173.1434021	0.11
176.6819153	0.07
179.0225525	0.13
187.1417236	0.06
190.9152069	0.10
198.0174866	0.02
203.0910339	0.03
209.0501709	100.00
216.9670105	0.08
217.9753723	0.02
228.0555420	0.12
229.0236206	0.03
233.8422241	0.02
242.1531067	0.01
243.1031189	0.07
245.8836975	0.03
247.2516785	0.05
247.9482727	0.04
249.9189148	0.03
255.1276245	0.07
262.1180115	0.06
262.9992981	0.08
264.0796509	0.70
265.0436707	0.24
266.2359314	0.01
271.0412598	0.08
272.4756165	0.05
275.0473633	0.20
276.9560242	0.25
279.2356567	0.07
290.1022644	0.02
291.1266479	0.03
292.0663452	0.06
293.0946350	0.07
303.0758057	0.32
304.3222656	0.02
306.0985107	0.01
307.3225708	0.11
307.9463806	0.05
308.8473511	0.08
309.8843689	0.01
313.2752686	0.01
321.1175232	0.01
323.1950073	0.08
334.1389771	0.22
335.1859131	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0764
Annotation	Glutathione
Peak:m/z	Relative Intensity
90.0015717	0.06
99.0532227	0.48
116.0466003	0.34
120.0199738	0.15
126.0753174	0.19
127.9911041	9.71
129.9052429	0.13
133.1013184	0.51
134.0652771	0.04
135.1059875	0.28
138.7866211	0.08
141.0618896	0.03
143.0303040	9.96
144.0728455	0.22
145.0244751	0.11
145.9304504	1.35
149.0148315	0.02
153.1298523	0.31
155.0964355	0.14
159.9870605	11.63
165.9331360	0.06
167.0549927	1.11
169.1065369	0.07
170.1573792	0.42
170.9962769	2.12
177.0649261	7.20
179.0608521	13.92
180.9349670	0.03
183.2652893	0.28
184.1298370	0.14
185.0381012	1.07
188.0705414	0.04
195.0392914	0.02
197.1107788	1.63
200.9115906	0.05
202.3316956	0.05
203.1333008	0.07
204.9904175	0.09
210.0991211	8.84
211.2375793	0.06
213.0752563	2.14
216.0256348	0.06
228.0969238	0.61
230.9676514	0.33
233.1437073	0.06
236.1034851	1.56
242.0993652	1.69
243.0833740	0.05
243.9910278	0.36
245.0523682	0.03
245.9427490	0.12
247.0431824	0.03
254.0749512	100.00
257.2683411	0.04
258.8435364	0.08
260.0627441	0.05
261.1509094	0.05
261.9995422	0.17
262.9246216	0.02
270.0633240	0.14
272.1258545	87.60
286.7995911	0.02
288.0770264	46.09
288.6777954	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.2448
Annotation	Dictamnoside D
Peak:m/z	Relative Intensity
142.9482574	0.26
161.1507111	0.37
178.9664917	0.45
183.4121704	0.05
191.0897827	0.09
195.1188965	0.24
213.1106873	6.03
214.8455048	0.08
219.2292786	0.10
243.1858368	0.51
245.2512512	0.17
253.1950684	100.00
255.0857239	0.20
257.1791687	0.39
258.4142761	0.16
263.0474243	0.14
274.9411316	0.15
279.2141113	0.07
288.9405518	0.29
293.2686157	0.64
294.3457642	0.10
297.1398010	0.09
299.3379517	0.46
313.3068542	0.10
315.3120728	0.38
318.3804321	0.13
327.5290527	0.50
332.2908020	0.55
333.1239319	0.38
337.1286621	0.12
340.9700928	0.12
342.1194458	0.13
345.3266907	1.89
347.3078003	0.23
353.0873718	0.08
355.2768555	0.11
363.2019348	0.06
364.2844238	0.07
368.3145142	0.11
371.2730103	0.22
372.3038330	0.39
381.2717285	0.66
386.2461243	0.18
399.0886841	0.44
403.2759705	0.06
405.0898743	0.62
406.2443237	0.15
413.6888428	4.94
431.4499817	0.45
432.1021423	0.22
433.2398682	0.32
435.4244080	0.12
444.1811218	0.10
449.2042236	23.17
450.4144592	1.29
451.3491516	0.87
456.4701538	0.18
458.2843933	0.42
459.6717224	0.45
466.5559387	0.18
467.3724670	0.42
472.9310608	0.20
474.5776978	0.97
476.3306274	2.05
477.3063354	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.151
Annotation	Unknow
Peak:m/z	Relative Intensity
176.1482239	0.06
203.2098999	0.02
209.1464386	0.03
219.0345154	0.01
220.9621582	0.02
227.0721893	0.03
229.0201111	0.03
235.2850342	0.06
238.3354187	0.05
241.9613037	0.02
245.9853210	0.02
253.0973816	0.04
259.1338196	0.04
274.1107483	0.04
279.3562622	0.04
280.5465393	0.06
281.1827393	0.23
284.2100525	0.05
287.3995361	0.06
289.1380005	0.03
289.8126831	0.02
290.6855164	0.17
293.2850647	0.03
295.0473633	0.03
313.2776794	0.05
315.2872314	0.09
317.4649658	0.01
318.7928772	0.06
320.9246826	0.01
324.5120239	0.04
325.3069153	0.19
340.6331787	0.11
341.3713989	0.03
342.2714844	0.03
354.9811401	0.06
356.0827026	0.07
362.1492615	0.04
371.1407471	0.09
376.2145691	0.02
377.0718384	0.57
387.1466370	0.02
397.9263000	0.02
400.3973694	0.06
415.2746887	100.00
423.0334778	0.03
424.9774170	0.11
442.2129517	0.06
443.3607788	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	554.64
Annotation	Unknow
Peak:m/z	Relative Intensity
206.7730713	0.07
208.9017029	0.03
212.8513489	0.73
214.7182617	0.03
234.0144806	0.02
250.8820801	0.04
290.5814209	0.08
296.7093506	0.16
302.7072144	0.02
362.3652954	0.02
370.8938599	0.19
380.6068726	0.25
382.5947876	0.12
384.9375000	0.16
385.6752319	0.04
386.8712158	5.06
400.1917725	0.02
401.2227173	0.02
410.7590332	0.04
418.1063843	3.28
419.2427979	0.39
429.0922852	0.32
468.7738037	0.16
470.7000122	100.00
471.4532471	0.28
472.5096436	0.02
512.7288208	4.92
513.3747559	0.12
514.2818604	0.06
516.2601929	0.06
522.0136719	0.02
531.6370850	0.05
536.0376587	2.14
537.1385498	0.21
561.0122681	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.1095
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0330811	0.07
158.5840759	0.17
163.0527649	0.28
164.8874817	0.04
167.0664062	0.04
168.9410400	0.35
177.0821228	0.10
179.0528870	0.52
184.9494019	0.15
197.0192566	0.07
202.0243530	0.10
203.0549316	0.16
205.0009155	0.36
220.8650818	0.08
227.0676880	0.11
229.1261292	1.01
231.4051361	0.09
243.1478729	0.24
255.2262115	0.19
256.1155396	0.09
257.3410950	0.17
259.2151184	0.10
261.3175964	0.24
265.1072998	0.10
268.2548523	0.28
271.1656799	1.30
273.1438904	15.16
281.1161499	0.07
283.2426758	0.04
287.4655151	0.18
288.4175720	0.13
293.3071899	0.15
297.3042603	0.25
299.1564636	9.37
300.2297974	2.66
301.1344604	0.94
302.2389526	0.03
303.1978149	0.30
304.0841675	0.10
305.1510620	0.05
313.1602783	1.60
314.1442871	0.11
315.1970215	0.11
316.1693115	0.05
317.1325073	1.65
319.3611450	0.07
325.1029053	0.12
327.2019653	0.27
329.4752808	0.08
331.1616821	78.41
335.2943726	0.42
341.2232056	3.65
344.2287598	0.12
345.2999878	0.12
347.1879272	0.09
349.0485840	22.20
351.0173950	0.16
352.2668457	0.63
353.1709595	0.23
355.1306152	0.37
362.2088623	0.08
364.2553101	0.12
375.2813721	0.04
376.2706299	0.09
377.2223511	0.21
378.5225220	0.76
379.4400024	0.62
388.2391357	0.05
389.3989258	0.17
391.2263184	0.10
395.0429077	0.59
409.3218994	0.19
417.3388672	1.01
419.0800171	0.04
421.1859131	0.49
429.4423828	0.08
433.1151733	0.81
435.2385864	4.29
443.2553711	0.12
445.2484131	0.10
449.3035278	0.09
450.1184082	0.17
451.3353882	0.31
461.2406006	25.29
461.9789429	0.16
463.6685791	0.09
464.4061279	0.24
465.2570190	1.22
467.2351685	1.02
479.3040161	0.04
480.4616699	0.31
483.2920532	0.05
493.2192383	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
85.01983643	0.79
95.0640564	0.76
100.8915405	0.95
108.8554993	1.21
110.8354492	1.78
119.0023346	0.50
121.1631165	0.72
129.0034637	0.31
149.141037	0.78
151.0829926	0.91
157.1376648	1.43
167.2765656	0.63
167.9728699	0.69
169.072525	2.10
179.2801361	1.11
189.0543365	0.60
193.12883	1.82
195.2606354	2.46
202.9505157	0.41
207.0462646	10.91
207.9251556	4.70
209.064682	4.46
210.0773468	0.50
215.1585083	0.82
221.9206543	0.69
223.2108307	11.77
224.1820221	1.11
232.2451019	0.79
233.0698853	3.49
235.2702026	1.27
251.0835419	100.00
252.1793976	10.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
126.9108734	0.77
145.4575195	0.33
151.0498962	0.24
162.1065979	0.29
166.7786255	0.31
169.151001	0.89
171.1911163	0.49
177.0452576	0.42
183.2552338	0.48
185.2394714	1.09
197.0660248	1.19
199.0882111	0.73
200.2233582	0.36
200.9847107	0.18
205.0971985	1.07
215.0993042	1.46
217.1087952	0.34
225.0801697	0.31
227.2585754	1.09
229.2798157	2.26
230.2049255	0.29
231.1805115	0.37
235.0935364	0.47
241.2364197	1.27
243.157135	4.13
245.053772	0.18
254.1257935	0.40
255.3685608	3.08
257.1547852	5.36
261.6594238	0.33
262.4121704	0.35
263.3955078	3.47
269.1019897	2.21
271.135498	1.66
273.1862183	2.87
283.3713379	2.18
285.2348022	6.41
287.4265137	0.13
293.121521	0.54
295.4780884	3.21
297.2615967	3.43
298.3478088	1.14
299.3046265	3.82
301.458252	0.47
303.0650635	0.56
305.1845703	0.24
305.9143982	0.49
309.137146	0.51
311.3232422	5.01
313.2716675	6.13
314.2085571	0.58
315.5028076	0.56
321.2354431	1.99
322.1246033	0.29
323.3222656	10.81
325.6072388	1.87
326.8696899	0.60
329.3684692	1.62
337.3435059	0.66
339.2409668	100.00
340.2301941	0.86
341.3860474	19.00
342.433075	0.71
359.1842346	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.3643
Annotation	Denin
Peak:m/z	Relative Intensity
217.0564728	0.03
219.2228394	0.06
221.1204071	0.09
227.2106781	0.02
235.2614441	3.37
236.3025513	0.11
237.1063232	0.02
245.2005615	0.14
253.2626495	0.43
259.2271729	0.05
263.2453003	0.15
265.3016968	0.03
269.2413635	0.03
275.6546021	0.02
277.3812866	3.04
278.4860229	0.15
286.0695801	0.02
287.2315063	2.49
288.3142090	0.21
291.3111267	0.02
301.2181702	0.03
303.3683777	0.05
305.2931213	4.67
306.2788391	0.19
307.3360291	0.04
315.3832397	0.01
318.8887329	0.01
319.6165466	0.05
323.1677246	0.59
324.3605347	0.04
331.3779297	0.01
346.3298340	0.04
349.3425903	0.01
361.2691650	0.15
362.5809326	0.03
364.4309082	0.01
379.3076172	0.11
380.3126831	0.03
397.3082275	100.00
398.3740234	6.79
415.2927856	29.55
416.2905273	2.13
439.2202759	0.02
511.3248291	0.01
531.0259399	0.01
631.9664917	0.01
659.2357788	0.01
675.3218384	96.11
676.2585449	43.74
677.0369263	0.06
678.6080933	0.02
685.6760254	0.04
704.8192749	0.02
722.1784668	31.76
723.3861694	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	780.07
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9983826	1.25
228.3213501	0.12
231.0567932	0.04
232.0949249	0.70
236.0653687	1.99
237.0630798	0.37
238.1030579	0.15
244.1721802	0.05
246.0373535	0.16
251.6346741	0.05
253.6795807	0.08
256.0914001	0.69
257.2745056	0.29
257.9672241	0.24
259.0360107	0.12
264.0579834	18.30
265.1095581	0.38
274.1605225	1.21
275.2862244	0.13
276.0304565	0.09
280.2098389	0.12
289.0852356	0.08
290.2368164	0.25
292.1237488	0.06
293.0855103	0.04
294.1029663	0.05
295.1565247	0.11
297.0984497	1.44
302.2276611	0.22
303.0848083	0.08
304.1335449	0.03
307.2143860	3.71
309.1643677	0.58
311.1791687	0.12
319.2973938	0.25
320.1983948	0.42
320.9800720	2.94
322.0218201	1.14
326.8968506	0.26
330.1576538	0.07
337.1853943	0.12
338.9943237	4.06
347.2056274	2.81
348.2215271	0.74
349.4418335	0.11
351.0187988	0.25
357.2920532	0.27
365.1991577	1.18
365.9246826	0.13
367.8715210	0.17
369.0460815	3.09
372.2274780	0.18
375.1317139	0.47
386.2111816	2.85
387.0699463	0.34
390.2731323	0.07
393.0921631	16.17
394.1239624	0.15
396.1483154	0.24
398.4780884	0.15
400.2161865	0.64
404.9268799	1.47
406.1113281	0.22
411.3292847	0.31
418.2169189	3.47
422.6557007	0.73
423.3649902	0.13
426.1296387	1.14
436.1358032	0.35
440.0428467	0.10
450.0003052	0.59
450.7775269	0.43
451.5233765	0.17
453.6766357	0.10
457.2158813	0.03
468.2149658	13.68
471.0349731	1.20
471.9552002	0.24
480.0145264	0.06
481.3357544	0.06
486.3861084	0.14
489.1437988	26.61
496.7293091	0.26
515.3082886	0.13
519.0436401	0.07
525.2873535	0.89
530.1282959	0.05
537.1642456	0.53
543.2985229	9.72
548.0170288	4.11
555.0341187	1.58
555.7557983	0.05
558.2151489	0.11
576.1132202	15.93
576.7537231	0.05
582.2365723	0.29
594.1643066	0.38
600.2385864	5.15
601.2137451	0.86
612.0484619	0.09
616.0086060	0.13
618.1829224	90.99
618.9279785	0.09
629.3792114	0.07
630.5160522	0.24
633.2319336	0.17
634.2869873	0.25
638.5620728	0.05
642.5403442	0.11
651.1083374	11.72
651.7575073	0.05
658.6485596	0.13
687.2616577	0.08
704.6502075	0.97
705.2803955	10.89
716.9474487	0.34
762.0227051	1.39
762.6331177	0.22
763.2858276	0.69
780.1229858	100.00
780.8424683	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.26
Annotation	Beilschmieflavonoid A
Peak:m/z	Relative Intensity
236.8841553	0.05
248.4555359	0.08
273.5880737	0.04
274.2742310	0.06
323.4699097	0.07
328.2836914	0.11
335.2761841	0.14
340.0086060	0.03
345.4392700	0.08
349.2721558	0.16
363.3668213	0.07
368.6339722	0.29
370.9169922	0.10
393.4301758	0.14
400.8286133	0.05
453.1355591	0.03
464.2351685	0.04
466.1912842	0.08
470.1495361	0.14
484.2945557	0.21
486.3874512	0.03
497.3317261	0.23
507.4281616	0.10
509.1453857	0.07
513.2904053	0.06
529.5218506	0.05
533.3118286	0.08
536.2721558	0.12
537.8339233	0.99
539.3339233	100.00
540.0161743	0.44
541.3960571	0.48
550.9872437	0.05
553.4926758	0.04
554.5724487	0.10
561.9926758	0.11
565.6030273	0.24
570.2005005	0.52
571.6212158	0.09
579.1744995	0.08
582.2959595	0.65
583.0027466	0.86
583.6735229	0.24
585.4277954	0.07
598.2148438	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.2027
Annotation	Patrinoside
Peak:m/z	Relative Intensity
136.9182892	0.08
150.8961792	0.27
177.0608826	0.08
186.0774536	0.04
200.1256256	0.09
213.1768341	2.56
214.9797058	0.11
220.9182587	0.07
223.2138367	0.19
224.2266998	0.18
257.2206726	0.09
261.0718079	0.05
271.1038208	0.05
283.2534485	0.08
285.1926880	31.91
286.1911621	0.14
292.9463806	0.03
295.8941650	0.08
297.2922974	0.11
301.2087402	0.08
308.4296265	0.07
312.5250244	0.07
313.6009827	0.07
315.2060547	0.13
316.7298889	0.08
325.0729370	0.04
327.2025757	1.06
334.2328491	0.03
339.1516724	0.20
343.0459290	0.03
345.1931458	0.16
351.1548462	0.09
353.3674316	0.12
355.2124329	0.93
357.2467346	2.45
358.4237061	0.07
365.2560120	0.09
368.4336548	0.03
369.2105103	0.73
371.4338074	0.04
373.3365173	0.08
375.2323303	0.58
381.2602844	0.76
394.4115601	0.29
399.2823181	0.42
400.3827820	0.07
401.5188599	0.35
404.7225952	0.04
413.4723816	0.09
415.2561340	0.75
417.3180237	100.00
417.9242859	0.19
424.5012207	0.19
425.1527710	0.04
431.3376770	0.08
443.0533447	0.64
443.6743164	0.02
446.7629700	0.43
462.1472473	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2784
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
140.0698395	0.07
152.9193573	0.20
153.9105225	0.07
196.0030518	2.02
214.0899048	1.23
237.3242950	0.08
255.2247009	100.00
255.8377380	0.16
271.1154785	0.01
283.2274780	0.07
320.5794678	0.04
381.0672302	0.05
391.2744446	0.39
405.3453979	0.10
406.2696838	0.07
407.6510620	0.07
408.7107239	0.02
414.1663513	0.02
415.9633484	0.01
421.2246399	0.03
433.4169617	0.07
434.4418030	0.04
437.4239807	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0855
Annotation	cis-1,2-Dihydroxy-1,2-dihydro-7-hydroxymethylnaphthalene
Peak:m/z	Relative Intensity
79.0908051	0.01
81.0331879	0.01
92.9736023	0.03
104.9704437	0.15
114.8677979	0.03
116.8603516	0.03
119.2261200	0.02
123.3084717	0.01
132.9079285	0.99
135.0708618	0.07
142.9556885	0.02
145.7877502	0.04
147.0921021	0.01
150.9141693	0.03
151.8801270	0.01
160.9835663	100.00
161.7766418	0.01
165.1267700	0.25
170.1589508	0.03
172.6083679	0.07
174.9488373	0.10
176.8142700	0.02
177.9902039	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.0408
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
102.9373322	0.60
105.1036682	0.11
112.9684448	0.23
123.0877838	0.02
130.9053192	0.45
135.0328674	3.99
148.8840942	100.00
178.9744568	54.79
188.9451447	0.03
205.2381287	0.10
211.1036072	0.05
211.9858704	0.10
219.1181335	0.10
221.1647034	0.37
228.9789124	0.03
249.3221741	0.06
262.8211975	0.03
265.2271118	0.08
267.0994873	0.46
293.1213989	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.0727
Annotation	Luteolin 7-glucuronide
Peak:m/z	Relative Intensity
137.0120392	0.05
143.1320496	0.02
175.0375061	0.41
179.1156616	0.03
187.3283844	0.07
188.8399811	0.01
197.2995453	0.06
206.3017731	0.01
209.1346588	0.04
212.9939575	0.01
214.0564880	0.03
222.2466888	0.03
227.0513153	0.04
229.2209473	0.14
235.1594543	0.02
240.2098236	0.01
240.8299561	0.01
249.1798706	0.02
257.1445312	0.30
267.1246643	0.12
271.2249756	0.24
272.6918030	0.02
274.1437988	0.01
281.2926025	0.01
285.0791016	100.00
285.8749390	0.01
297.1374512	0.26
299.0032349	0.31
300.0372620	0.02
302.4421997	0.02
313.3603210	0.01
314.7737122	0.02
323.1884766	0.05
325.1754150	0.26
327.2271118	1.25
335.0876465	0.01
337.3280945	0.17
339.2166138	0.13
345.3226318	0.02
351.2061768	0.13
353.2089233	0.24
355.0988770	0.55
357.1380310	1.55
363.1278076	0.11
369.1900940	0.68
371.1673279	0.29
380.3729858	0.04
381.1138000	1.28
389.4676819	0.05
397.0006714	0.01
399.1882019	0.10
400.3343201	0.03
404.4043884	0.04
414.0303040	0.02
415.3688354	0.11
416.4029846	0.17
417.2817078	0.62
418.5324402	0.03
419.5569153	0.02
433.1545715	1.06
434.5057373	0.04
443.3202820	0.25
447.3794861	0.03
451.6977844	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.14
Annotation	16-iodo-hexadecanoic acid
Peak:m/z	Relative Intensity
130.1319885	0.29
132.0658264	0.08
144.0511475	0.62
145.0549316	4.73
156.1091614	0.06
157.0254517	1.34
158.1604919	0.46
160.1075439	0.14
166.0956421	0.07
171.1360321	0.15
172.1527405	0.09
173.8037567	0.05
175.0955505	2.92
183.1138153	0.18
186.0212250	0.35
186.9592590	0.08
189.7848511	0.16
199.6094513	0.25
200.4494934	0.22
201.2859955	0.28
203.0290222	14.22
204.1136780	0.40
209.0289612	0.75
214.9859772	0.31
215.8304596	0.38
217.0438843	10.46
219.1591644	0.38
220.2433472	0.66
221.1215515	12.65
227.0001221	7.32
228.2352295	0.56
231.0567627	0.70
242.1899109	0.24
245.1717529	15.60
246.0184326	0.08
246.8856201	0.23
249.0203857	0.30
256.2047119	0.09
257.2829895	0.43
261.2110901	0.28
263.0420532	69.88
265.0173340	0.44
267.0778503	0.16
269.2087402	0.59
271.1685791	0.12
273.8354797	0.03
275.1722107	1.14
281.3046265	0.10
285.4224243	0.06
286.6988831	0.41
288.1935120	0.21
292.8502197	0.16
296.1601562	0.19
299.1464844	3.16
300.2052002	0.16
301.1228638	0.45
303.2462158	0.14
307.0297546	0.04
309.7505493	0.08
311.1584473	1.36
317.3699341	0.50
318.9622192	0.25
321.5181885	0.23
323.0245056	0.24
329.1854858	3.50
330.3629456	0.18
336.9205933	0.30
338.7198181	0.28
339.3542175	0.03
341.9612427	0.32
342.9895020	0.16
345.3889771	0.13
347.2081299	14.95
348.1412964	7.99
360.0205383	0.11
365.1806946	100.00
374.4101257	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1029.2859
Annotation	Unknow
Peak:m/z	Relative Intensity
381.2398682	0.05
453.4421387	0.02
513.0314941	0.02
524.4090576	0.07
525.2871094	0.28
543.2148438	0.05
687.4099121	0.37
695.4706421	0.00
705.3082275	0.29
775.8824463	0.03
849.4255371	0.71
867.4438477	0.78
1029.4492190	100.00
1030.1076660	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.9656219	0.17
108.8666992	0.06
111.0108719	0.07
116.9314041	0.13
122.0656891	0.07
126.9559479	0.06
131.9286499	0.06
134.1599579	0.50
135.0306091	7.34
137.0024719	0.09
146.1819305	0.02
146.8615112	0.05
155.1367950	0.13
161.0436859	1.02
172.9996185	1.58
178.9995728	39.56
190.9915009	100.00
193.3628845	0.05
199.1380005	0.03
206.1582031	0.02
220.2311096	0.03
223.0684814	0.02
225.1202698	0.05
232.9798584	0.02
234.9019165	0.06
239.1198425	0.04
242.0331726	0.06
242.9349060	0.14
248.0823669	0.07
259.0979309	0.13
264.9681396	0.19
267.0637207	0.11
271.3927002	0.06
285.2088318	0.03
291.1779785	1.52
292.2229919	0.02
306.0840149	0.11
307.1829834	0.16
308.0535278	0.05
309.4644470	0.06
323.3762817	0.07
324.0840454	0.04
333.1755676	0.05
334.1910400	0.08
335.1421204	0.90
336.4044189	0.05
353.2901001	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1016
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
165.8513336	0.02
201.2618713	0.01
212.8922729	0.02
228.8366699	0.01
231.0578308	0.03
247.0512848	0.04
249.0968628	0.03
255.0168457	0.01
273.9895630	0.03
285.1907959	0.03
303.0733643	100.00
303.6794434	0.25
315.3682251	0.03
327.2958984	0.06
345.0639648	0.44
369.2256470	0.01
381.1798706	0.03
399.2775879	0.07
411.1131592	0.14
429.2534790	0.05
447.5819702	0.05
455.0817261	0.03
489.2611694	0.07
490.3248901	0.01
515.0017700	0.04
518.0994873	0.03
533.0825806	0.22
533.7029419	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1221
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
152.9268646	0.88
163.0311890	0.43
170.9562683	0.41
210.1598969	0.30
215.1598816	0.20
257.0252991	0.32
263.2206116	0.83
271.1726379	1.08
281.1998291	0.28
285.1490784	0.81
289.1560974	100.00
304.2841492	0.52
308.9616394	0.22
325.9340210	0.30
331.1330872	1.85
333.3350220	0.52
377.4293823	0.29
380.0028381	0.20
385.2386169	1.71
391.4662170	1.11
397.4382019	0.20
398.1834717	0.29
404.9784851	0.69
409.1798706	1.14
410.1283264	1.69
414.4882507	1.36
415.3120422	0.44
424.2839050	0.40
431.9837952	1.70
433.1242676	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.0821
Annotation	Cochinolide
Peak:m/z	Relative Intensity
81.0078735	0.05
92.9277191	0.06
96.6291351	0.02
108.0097656	0.06
108.9084473	0.07
111.2354736	0.02
114.9912262	0.04
116.9578705	0.02
121.0743408	0.04
122.2135162	0.02
122.9936371	0.03
129.0481567	0.02
130.2949524	0.01
133.1261444	0.01
135.0307007	0.13
143.0048370	0.08
145.0640106	0.11
148.2087097	0.01
149.0929108	0.02
153.0290375	0.08
154.0428467	0.03
155.1053009	0.11
156.1298065	0.05
157.0410309	0.19
158.8832703	0.03
161.0379333	0.83
167.1502228	0.26
168.1145782	0.01
169.2010651	1.58
170.0637360	0.18
171.0525970	0.25
172.0424957	0.01
173.0668488	0.20
174.9705963	0.45
177.3026276	0.05
180.3068542	0.08
183.0610199	1.82
184.0578918	0.36
185.1030121	3.29
187.1128082	0.09
195.0533600	3.09
196.1071014	0.03
197.5149231	0.52
198.2141571	2.09
199.3455963	0.03
201.0572815	0.22
203.2760315	0.01
210.3477936	0.34
211.2114716	0.78
213.0738983	100.00
214.3109894	0.09
215.1716309	0.05
219.3280640	0.01
220.0038452	0.03
221.1358185	0.11
224.3964691	0.02
225.9693909	0.06
227.1162567	1.56
228.1693420	0.26
229.1582794	1.96
237.2806549	0.03
239.1557159	5.60
242.0641327	78.45
242.6746216	0.08
257.0363159	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.87576294	0.50
78.6488266	0.13
82.87922668	0.95
91.25631714	0.18
94.90585327	1.05
103.0723419	2.26
103.9105682	0.39
104.9166565	1.10
106.9934235	1.41
108.914032	0.37
117.1348114	0.10
118.891922	0.62
122.2044373	0.24
122.9445038	0.26
128.9011078	9.10
129.9332123	1.50
132.9302673	0.44
140.9560699	1.28
142.0391998	0.10
145.3517303	0.05
146.9648895	0.15
148.8815765	0.23
150.9404449	100.00
151.9232635	14.96
153.0016174	2.29
154.1668854	0.96
155.2689514	0.76
157.0366058	0.78
158.0535889	0.45
162.1082611	0.12
164.8028259	0.44
165.9740295	0.46
167.0907745	3.78
168.2621307	0.36
169.0945587	0.59
169.8735809	0.32
171.0590973	1.11
171.9444275	0.34
178.1048279	0.43
179.0549927	3.69
180.2266083	0.22
181.2282257	0.24
182.0580444	0.83
183.0717316	1.66
184.9757843	2.48
186.1849213	0.29
189.1566315	0.20
190.0075531	0.95
191.1877899	0.42
193.8587341	1.07
195.0645905	0.31
196.9853363	3.52
198.111145	1.35
199.2032471	0.16
207.0101166	1.36
209.9187164	0.76
211.1154022	0.86
212.2507019	0.11
213.0842438	0.23
217.1547394	0.05
223.2159729	0.09
225.2517548	7.49
226.2536774	1.91
235.1856689	0.40
236.093338	0.31
237.0380096	0.26
238.050293	15.60
239.0634613	2.09
240.1082153	0.38
251.1677246	1.99
253.0794525	60.73
254.2218475	14.81
255.2239532	1.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.093
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
107.9198227	0.03
108.8959579	0.06
111.0300903	0.12
118.9918365	0.28
127.2734833	0.04
129.0785217	0.03
135.0116119	0.15
136.0726929	0.06
136.9063721	0.01
142.8391571	0.11
145.0297089	0.01
154.9617310	0.04
161.0148621	0.04
162.0111084	0.08
163.0763245	3.65
169.3960571	0.04
171.3099060	0.01
173.0695953	0.81
175.2235107	0.03
179.0814056	0.14
180.1338043	0.22
181.0851593	0.05
190.9853668	100.00
191.6027374	0.14
196.0249023	0.03
203.2659454	0.04
211.1324158	0.01
227.3826294	0.02
233.0534363	0.11
264.9545288	0.05
265.9681396	0.02
276.8232422	0.02
278.0868530	0.02
290.2397766	0.09
291.1874695	0.02
293.1693115	0.13
294.2142029	0.05
295.2330933	0.03
300.2279053	0.03
309.1108398	0.07
318.3878174	0.09
319.0395508	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
698.0010986	6.07
757.461853	18.81
786.6030884	13.83
882.175354	48.40
958.4227905	42.57
967.4462891	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.0831
Annotation	3'-Methoxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
139.1371918	0.13
149.0137634	1.59
152.9202576	0.91
154.9994965	0.13
159.0566559	0.06
161.0902710	0.04
161.9778442	0.20
163.0540924	0.22
166.9457550	0.30
173.1583710	0.16
175.0531464	0.07
176.9249420	0.47
177.9089813	0.09
179.0531006	3.90
186.9212036	0.05
190.0055847	0.19
191.1368256	0.43
197.0233459	12.81
203.0997925	0.03
205.0059204	0.47
209.0800781	0.44
219.0580444	8.01
221.0424957	0.26
223.0373077	0.08
231.0674438	1.27
241.2721252	0.10
249.1191406	2.98
256.0362549	0.14
262.0069275	0.05
267.1133423	0.93
271.4511108	0.17
274.9860535	1.10
281.0494690	1.29
287.0991516	0.04
293.1050110	65.68
294.1466370	0.22
297.0556030	0.07
309.0177917	0.04
311.0327759	3.55
313.2875977	0.17
314.0804138	0.14
315.2509766	0.36
327.1520996	0.03
329.0753174	100.00
341.1389160	0.09
353.4801636	0.03
356.1359253	0.10
357.1498413	0.05
359.0376587	2.59
361.2540283	0.10
388.2445984	0.11
413.4545593	0.07
428.4234924	0.10
447.4210510	0.04
448.1190796	0.08
473.0422668	1.20
476.3786316	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1462
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
173.0966492	0.06
174.9163208	0.17
177.1509247	0.05
178.9368896	2.66
180.1840057	0.03
183.2850800	0.18
185.0388794	0.08
187.2418213	0.19
188.9971161	0.24
190.0969391	0.26
190.9324341	0.05
191.9744263	0.04
193.1746674	0.16
198.1651764	0.05
199.2146301	0.14
201.1003723	0.31
203.1021729	0.23
204.8977661	0.07
206.9927826	0.16
211.1422272	1.05
212.1201019	0.11
212.9382935	0.26
216.2571564	0.10
217.0500793	0.12
220.9007568	0.19
225.4206238	0.26
227.0074768	0.55
228.1009827	0.38
229.2179413	0.90
230.9281769	0.20
233.1811218	0.26
239.0490265	0.14
240.1436920	0.20
243.2290039	0.86
244.9243927	0.09
247.0692749	0.28
252.8176117	0.10
253.9117279	0.38
255.0463562	3.88
256.1366272	0.20
257.1293640	0.69
265.2013550	0.09
266.2432251	0.21
271.1007690	9.24
271.9550781	0.19
273.1605835	1.93
281.1392822	0.12
282.4387207	0.12
283.0801697	0.94
285.2058716	3.23
287.3222046	0.06
295.1538086	0.15
296.0988770	0.12
297.2086792	1.85
300.0791321	49.53
301.0668030	100.00
311.1570435	0.37
313.0259399	0.69
315.1118774	0.19
321.2168579	0.12
324.1171570	0.07
325.2382202	0.71
327.2894897	0.07
328.3340454	0.13
329.0667114	0.21
331.2568970	0.09
337.2193604	0.23
341.3785400	0.15
343.1607056	8.51
345.9772949	0.14
353.3571777	0.07
355.1472168	0.31
357.4475708	0.22
360.1372070	0.07
363.0512085	0.32
367.0578003	0.09
369.2122803	0.11
373.2988892	0.66
375.2493896	0.14
378.9875488	0.11
385.3442993	0.20
390.9839478	0.09
395.0217896	0.08
397.4815674	0.13
402.5500488	0.13
409.2290649	0.32
418.9788818	0.15
423.1081543	0.05
429.3799438	0.32
433.4603882	0.21
443.2460327	0.07
445.0618286	0.17
446.2536621	0.07
447.2439575	0.54
457.1975708	0.34
463.2791748	0.74
465.3076172	0.67
471.3923950	0.03
481.2453003	0.03
483.3605347	0.35
493.4304810	0.12
497.3431396	0.22
500.2371216	0.22
516.7660522	0.91
517.9661255	0.46
519.1619263	0.12
523.2021484	0.07
529.4871216	0.04
530.5817261	0.37
535.8325806	0.57
536.4480591	0.19
537.3055420	0.12
541.5260010	0.05
545.5537109	0.09
546.8364258	0.21
551.4562378	0.07
560.9806519	0.11
562.3937378	1.21
563.0678101	5.05
564.2473755	0.98
565.5864258	0.23
572.3806763	0.09
573.3308105	0.14
574.2494507	0.26
576.3068237	0.34
578.5761108	0.07
586.6369019	0.09
588.1350098	0.19
590.0952759	0.10
591.3602295	2.46
609.5297241	0.61
610.4011230	4.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.958
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0368652	0.25
141.8352966	0.69
143.9575806	0.08
147.9690552	0.17
153.9257507	0.20
155.8750916	2.69
156.8489380	0.27
161.9278107	0.20
169.9792938	5.74
171.7773590	0.65
173.0977325	0.35
183.9426880	2.30
196.0654144	0.18
199.9640198	33.57
200.9756470	5.00
201.8861084	0.16
213.9750824	8.85
217.9757233	2.18
225.2790527	0.31
226.9748535	0.88
227.9521027	0.53
240.0744324	0.13
241.4931641	0.37
242.1407471	0.50
243.8634338	10.00
244.8968506	0.28
245.9067993	1.82
253.3483582	0.28
254.0343628	0.06
255.4720764	0.06
257.9205017	100.00
260.1273193	0.36
261.9771423	3.00
267.9522095	0.46
272.2752075	0.21
273.0708313	0.06
283.9702148	5.36
285.8090515	6.43
286.7891235	0.23
287.9979248	9.71
289.6655884	2.31
301.8207397	43.72
302.5121460	0.26
303.9453125	1.57
313.9152222	2.04
327.7311096	3.29
329.6691895	6.02
331.3690796	8.76
332.0157166	87.85
333.0896301	0.59
343.2436218	0.15
344.5110474	0.26
345.8854675	21.43
347.9855347	1.80
355.1343689	0.11
357.8953247	1.26
372.9722290	1.22
373.8075562	0.71
375.7711792	0.23
392.0292969	25.30
399.9147034	3.35
417.9162903	54.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.1532
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
202.4777679	0.06
212.9614868	0.22
229.2160187	0.09
241.8369293	0.08
255.1320801	0.12
257.0795898	0.10
265.8942871	0.13
275.0783386	0.12
293.0717468	0.10
303.0727234	62.92
303.6876221	0.33
306.0527954	0.20
308.1067505	0.30
314.8859863	0.07
338.3542480	0.08
340.0655518	0.03
345.2317505	0.89
357.1172485	0.22
359.0258789	0.30
360.5489502	0.07
369.1784668	0.30
378.8419800	0.12
398.0877686	0.07
399.2309570	0.28
411.0660400	0.37
417.4798584	0.23
419.0664062	0.28
424.0025024	0.12
425.8063965	0.25
427.3364258	0.11
429.0455322	0.12
435.2034302	0.17
442.0198364	0.38
446.1482544	0.67
447.1851196	1.47
451.1186523	0.04
452.2926025	0.74
457.3485718	0.39
460.9343262	0.29
463.1295776	0.03
465.0442505	100.00
465.6719971	0.32
479.4675903	0.14
480.1265259	0.18
510.1353149	0.27
511.1956177	0.16
511.8829346	0.09
514.3513184	0.06
521.4309692	0.08
522.5484619	0.14
525.4324951	0.08
545.4481201	0.12
559.1306763	0.05
560.6096191	0.37
566.6287231	0.22
579.4981079	0.13
583.5537720	0.25
591.3910522	0.19
592.2427979	0.06
605.2578735	0.14
606.6221313	0.19
607.9808960	1.25
609.1539917	1.06
628.2363892	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
85.0101318	0.40
87.0174713	1.04
110.9466095	100.00
111.7506104	0.05
128.9766388	1.72
130.7634277	1.16
147.2335205	0.06
155.0649719	0.08
172.8567963	19.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.7471
Annotation	Unknow
Peak:m/z	Relative Intensity
161.1212311	0.09
169.2937469	0.08
170.9739075	0.85
185.7716675	0.04
187.1370544	0.08
197.2787933	0.63
199.1612091	0.04
225.9776154	0.07
227.0599060	0.16
241.2791138	0.05
244.0176392	0.15
249.2137146	0.24
257.3502197	0.06
262.1715088	0.68
270.4597778	0.18
272.0808716	0.06
283.1297607	0.28
287.1696167	0.06
294.9979858	0.24
299.1326904	0.08
300.2328796	1.70
301.0867920	0.13
325.8377686	0.21
326.8599854	0.19
329.0588989	0.19
333.2394409	0.09
334.3262329	0.15
337.3905640	0.10
340.0278931	0.20
341.0094604	0.19
345.5622559	0.11
347.0158081	0.11
349.0201416	0.08
354.2797852	0.37
355.2260132	0.09
359.2310791	0.25
365.3073120	0.21
367.3553467	0.21
370.2740479	0.13
373.4002075	0.05
377.2867432	0.04
397.0568237	0.18
398.2814941	0.16
407.4752197	0.16
413.1821899	0.25
415.0954590	0.35
426.3684082	0.10
427.3989868	0.14
430.5740967	0.14
433.5324707	0.08
436.2041016	0.19
436.8349609	0.31
442.7072754	0.41
448.4058838	0.70
450.3228149	0.57
451.3576050	0.07
456.3240967	0.09
465.2350464	0.06
468.2341309	4.79
469.1798706	0.23
475.8140869	0.12
478.1829224	0.97
479.1046753	0.02
480.0521240	0.17
484.4255371	0.12
485.3046265	0.24
496.2463989	67.12
497.3350830	8.90
498.8078613	0.37
500.3414917	0.09
502.3696899	0.24
503.1418457	0.17
503.9188232	0.16
506.2708130	0.10
527.2941284	0.52
528.2624512	0.43
529.4473267	0.03
534.0965576	0.30
545.3125610	100.00
546.3454590	11.32
548.0697021	0.22
566.2265015	0.08
589.2901001	0.12
593.4247437	0.89
596.2773438	0.22
619.0979004	0.27
630.5789795	0.20
644.4241333	0.85
645.2745972	0.06
650.5694580	0.62
666.6199341	0.58
688.3096313	0.10
725.5949097	0.21
738.3389893	0.10
739.8355103	0.25
741.4167480	4.20
742.4766235	0.35
754.6449585	0.06
779.3718872	0.96
780.3302002	0.33
797.6133423	0.08
828.8023071	0.05
865.3923340	0.05
869.6704712	0.12
883.5542603	0.21
908.1049805	0.53
908.8842163	0.50
909.6958618	0.09
1053.5705570	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.04
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
102.9275970	0.45
104.9450378	0.02
112.9821930	0.40
130.7889404	0.60
135.0502014	3.30
148.8918152	100.00
177.1245880	0.03
178.9540558	58.68
179.9673462	0.02
194.7158966	0.03
267.0261230	0.34
293.0557251	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8354950	2.74
124.8212891	0.02
145.0170593	0.02
206.7642517	100.00
223.0726013	0.86
254.1601562	0.01
255.1798401	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2188
Annotation	Unknow
Peak:m/z	Relative Intensity
185.0287476	3.51
186.2557373	0.80
271.3067932	0.23
273.2990417	0.15
309.9967651	0.09
341.0656738	0.21
357.5218506	0.37
375.2849731	1.11
376.4906006	0.58
385.3114624	0.09
399.3088989	0.09
417.2891235	67.04
418.3204956	11.08
418.9698486	0.07
419.6483154	0.16
443.4237061	0.19
461.0827026	0.42
462.0344238	0.14
472.8382568	0.09
489.3496094	0.16
516.2868652	0.24
537.4852905	0.15
541.5539551	0.13
543.8749390	0.31
553.1065063	0.06
553.8801880	0.16
557.5386963	0.16
559.3452759	0.22
561.4429321	5.22
562.4278564	0.79
567.4524536	0.39
588.4776611	0.09
597.7496948	0.09
603.2908325	100.00
604.3363647	14.08
611.0750122	0.17
622.3583374	0.08
627.3721924	0.28
629.3358765	3.50
630.6025391	0.84
632.3393555	0.17
648.2819214	13.91
649.9133301	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1043.5135
Annotation	Unknow
Peak:m/z	Relative Intensity
324.2460327	0.34
342.1347046	0.08
377.2593384	0.04
395.2603455	0.03
425.5185547	0.25
427.2442017	0.25
453.2861938	0.30
484.5629272	0.10
496.4381714	0.04
503.3995361	0.18
524.5057373	0.25
525.5273438	0.03
581.3417969	0.03
599.3448486	9.58
600.4164429	0.72
659.3971558	0.15
679.3239746	0.08
698.2040405	0.10
708.2590942	0.17
719.1530762	0.11
755.9478760	0.06
757.7517090	0.06
777.2421875	0.06
787.5362549	0.26
848.5606689	0.16
849.2489014	0.03
852.5482178	3.32
853.4654541	0.19
857.1252441	0.27
863.4595947	0.18
877.4223633	0.49
926.4680176	0.23
927.2976074	0.27
962.4193115	0.13
963.7772217	0.04
976.2963867	1.04
980.7923584	0.37
983.0098877	0.08
984.3170166	0.09
987.7259521	1.25
995.5374756	0.32
1002.6385500	0.05
1004.6900630	0.12
1013.1899410	0.31
1018.7178960	0.49
1026.7946780	7.54
1036.2937010	0.08
1044.0986330	100.00
1045.3673100	6.37
1046.3325200	1.53
1047.1628420	1.19
1048.2767330	1.42
1049.7369380	0.82
1050.4281010	0.03
1051.0672610	0.06
1051.8966060	0.24
1053.4489750	0.26
1054.6251220	0.23
1057.2965090	0.04
1060.4082030	0.07
1072.2102050	0.07
1075.2819820	0.30
1076.8249510	0.32
1077.7735600	2.13
1078.8176270	0.14
1079.7299800	0.08
1098.8483890	0.53
1116.9465330	0.18
1130.4514160	0.05
1132.1396480	0.21
1139.3138430	6.78
1140.0699460	0.50
1170.7658690	0.03
1178.7257080	0.66
1179.8258060	0.07
1180.7124020	0.13
1193.0568850	0.10
1202.8964840	0.26
1212.9416500	0.10
1214.1064450	0.03
1216.4001460	0.49
1218.4089360	0.13
1229.7412110	0.24
1239.1942140	0.14
1251.8563230	0.45
1252.6049800	0.27
1253.3842770	0.12
1256.8466800	1.56
1265.8657230	38.04
1266.9754640	2.17
1268.8115230	0.18
1270.3084720	0.18
1277.5858150	0.28
1279.3193360	0.27
1294.0708010	0.06
1313.9417720	0.05
1316.7128910	0.12
1318.6705320	0.05
1322.9443360	0.02
1350.9964600	0.12
1370.9099120	0.07
1380.7874760	0.09
1406.0479740	0.14
1427.5505370	0.30
1428.2076420	0.34
1428.8204350	0.28
1433.6890870	0.47
1467.1225590	0.07
1549.3460690	0.13
1551.0233150	0.06
1558.2436520	0.16
1611.0240480	0.09
1622.2545170	0.17
1630.8416750	0.09
1653.0656740	0.09
1655.2863770	0.07
1669.1214600	0.08
1682.2448730	0.34
1712.1042480	0.04
1713.8651120	0.17
1725.5208740	0.15
1738.8216550	0.04
1740.2933350	0.13
1747.2235110	0.07
1766.2047120	0.32
1773.5726320	0.09
1776.3258060	0.10
1784.3192140	0.03
1807.2388920	0.03
1810.3132320	0.07
1811.9235840	0.03
1813.5618900	0.09
1819.9373780	0.11
1824.3157960	0.26
1837.7410890	0.04
1846.6947020	0.12
1866.4029540	0.04
1873.2249760	0.12
1884.5653080	0.09
1895.2950440	0.10
1908.3078610	1.44
1917.1214600	0.07
1962.7579350	22.21
1963.4996340	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408
Annotation	Unknow
Peak:m/z	Relative Intensity
127.7817383	0.08
128.8016052	0.07
132.0587463	0.09
132.8278046	0.10
145.7790222	0.12
164.8684082	0.26
165.9415741	0.35
189.9228363	3.19
200.0812378	0.14
206.9739380	0.06
207.8878174	0.36
212.9589081	0.26
213.7192383	0.08
217.0195007	0.20
233.3158569	0.18
243.1015320	0.08
245.6981812	0.16
246.7912903	0.42
257.8273010	0.19
261.0151978	1.03
263.6337280	0.06
272.0784912	0.69
274.9743958	0.12
278.0067139	0.04
287.1729126	0.17
287.9743042	0.05
289.9181213	100.00
299.2651367	0.11
307.1864624	2.11
307.8581238	15.51
317.0112915	0.44
319.8327942	0.20
329.9052734	0.28
347.1241760	0.17
352.0561523	0.05
353.5317383	0.43
360.2261353	0.07
367.1392822	0.11
371.0571289	0.18
371.9812927	0.09
372.5938721	0.15
385.8417053	0.08
388.4190674	0.28
389.6001892	8.28
390.3148804	0.83
407.4812927	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.26
Annotation	Unknow
Peak:m/z	Relative Intensity
345.2672729	0.10
361.2188110	0.23
364.2326050	0.06
379.5299072	0.23
387.0260010	0.29
402.3046875	0.07
409.1336670	0.20
415.0043335	0.14
419.5180664	0.11
423.5048218	0.19
443.0415649	0.05
445.3053589	0.18
447.5345459	0.10
452.6950073	0.03
456.0821533	0.19
459.2792969	0.14
461.1658325	0.08
463.4472046	0.29
468.3700562	1.13
471.8109131	0.04
477.3197632	0.17
489.3582764	0.75
496.0120239	0.13
503.3879395	0.75
505.2946167	100.00
505.9173584	0.29
507.4879761	0.19
513.1423950	0.50
518.7411499	0.26
521.5615845	0.06
529.2916260	0.20
530.4242554	0.22
531.3424072	0.10
550.4075317	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.2079
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
137.2285614	0.03
143.0943298	0.06
147.0075073	0.02
153.0071259	0.13
158.9255066	0.02
160.8914642	0.39
179.2502136	0.09
181.1903076	0.01
183.0170288	0.49
188.8930969	0.02
193.2567444	0.09
195.1861115	1.46
197.0337677	0.04
207.1152039	0.51
211.3491821	0.02
213.1110077	100.00
223.0917206	0.31
226.9964600	0.21
237.1755981	0.02
241.2752991	0.03
249.2774963	0.16
255.2448120	1.15
258.5317078	0.02
267.2067566	0.53
279.0300598	0.06
285.0914307	0.60
285.7704163	0.01
302.3750000	0.05
309.3542480	0.02
315.2954102	0.09
344.9293823	0.05
345.5813599	0.07
356.8242798	0.03
357.4395447	0.02
375.0729065	5.69
393.3499451	0.04
403.7038574	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.0884
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
178.9557495	11.11
218.9441681	0.06
266.9674072	0.25
271.3092346	0.09
293.1872559	0.27
311.0169678	100.00
311.9267578	0.04
359.3381958	0.07
442.3229370	0.20
443.0754395	0.08
460.7287598	0.12
473.0689697	1.52
491.2276611	0.20
494.3928833	0.22
605.4386597	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1023.1689
Annotation	Chlorocyclinone B
Peak:m/z	Relative Intensity
293.0751343	0.45
300.1072693	0.10
301.1157227	0.09
307.3545837	0.01
311.0765991	0.45
341.1194153	0.03
343.3812256	0.02
463.3305359	0.02
473.0503235	2.86
473.7194214	0.03
487.6535645	0.02
505.2217407	2.38
505.8347778	0.01
530.8852539	0.01
549.1299438	0.17
817.1947021	0.00
860.9331055	0.01
978.3889160	0.05
1022.8375240	100.00
1023.6048580	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.8753166	0.18
58.8544159	3.64
60.9561386	0.76
66.9174805	0.42
70.7606049	5.01
72.9330978	0.89
80.8901901	0.23
82.9516907	1.77
83.8707428	0.14
84.9048309	100.00
86.9326172	23.14
92.9064026	47.96
95.9400635	0.30
99.0589905	3.95
108.8798370	19.05
110.9517365	34.75
112.8661041	0.81
114.8472748	0.74
126.9670105	82.86
129.0230255	3.16
137.0059052	2.08
142.8936768	5.00
144.8408813	1.25
146.9067993	2.45
153.0561523	6.33
154.9588165	7.66
171.0062408	30.40
173.0029602	86.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Rehmaionoside C
Peak:m/z	Relative Intensity
125.1374359	0.13
131.0250549	0.56
133.0268402	0.18
134.9934845	0.13
136.8355103	0.07
143.0258789	1.55
143.9178162	0.15
148.9755859	0.30
155.0383606	0.04
158.8276062	0.23
160.9932251	10.37
162.0788269	0.32
163.1950531	0.31
164.0959778	0.06
172.9952698	0.22
175.0592651	0.19
177.1721344	0.15
179.0083008	13.06
179.9318237	0.30
181.1510010	0.56
185.0010376	0.54
190.1674805	0.04
191.1581116	0.36
197.1253815	0.12
199.1513977	0.17
205.3169098	0.28
206.2412415	0.13
207.2014160	0.45
217.2209167	0.15
219.1018677	0.24
225.2037354	9.33
226.1944885	0.65
229.1657104	0.03
229.9640808	0.06
231.3308411	0.12
232.1514893	0.08
234.9863586	0.08
237.0390625	0.20
243.1525574	0.62
244.1032104	0.04
247.0585632	0.39
249.2162781	1.12
253.2117920	0.59
261.2512207	0.62
263.2580872	0.23
265.0257874	0.45
266.6774902	0.13
267.9525452	0.13
271.1127930	0.69
272.2427063	0.12
278.1436157	0.04
279.2611084	1.86
280.2831421	0.21
285.1045532	0.12
288.1958008	0.14
291.2151489	0.81
292.3541870	0.04
295.1779785	0.05
297.0356445	0.59
300.9962769	0.05
305.3189392	0.06
307.3209229	0.16
309.3096924	5.65
310.1483765	0.64
314.2703857	0.04
321.3856201	0.14
325.3192749	0.74
335.3538208	0.25
343.2396851	1.94
344.2882690	0.54
345.2218628	0.18
346.3843994	0.11
348.1956177	0.09
349.2257690	0.07
351.0356445	0.13
353.2062378	16.43
366.3907166	0.17
368.9772339	0.84
373.3212585	0.07
374.3041992	0.09
377.3532104	0.08
378.3312073	0.11
387.1741638	100.00
388.1594849	5.09
389.2234802	0.19
389.8714905	0.05
391.5644836	0.42
392.3887634	0.12
403.1343994	0.07
405.5485535	0.09
415.0741882	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0933
Annotation	Scopolin
Peak:m/z	Relative Intensity
115.0129242	0.39
122.8725967	0.07
126.9652405	0.07
128.9778595	27.41
134.2794495	0.69
135.1236267	1.51
140.9475555	0.86
150.9923401	0.07
154.7687378	0.14
159.0176392	0.47
160.6745300	0.09
167.0143433	0.16
173.9755859	0.17
175.1317444	0.21
179.0029907	14.02
183.3126221	0.21
186.3756866	0.09
191.0897064	1.20
200.8693237	0.74
203.0584412	3.64
217.0950012	6.88
219.1003113	51.62
227.0583191	0.49
228.9588928	0.26
231.0038757	2.72
233.1412659	0.80
237.0889587	27.83
245.4928589	0.10
247.1250305	2.13
249.3524475	0.05
251.2216187	0.41
253.2119141	0.08
259.0834351	0.71
260.7887878	0.17
265.2107544	0.32
267.2413940	0.12
273.3790588	0.05
275.0670776	1.23
277.2557373	1.15
293.1560059	11.18
293.7950439	0.09
297.3032532	0.06
300.9707336	0.14
311.2390137	2.06
313.2116394	0.05
319.2178040	0.18
337.0633545	12.48
338.9625854	0.15
341.5344238	0.05
343.2524414	0.08
352.2122192	0.66
353.2360229	0.41
354.4331970	0.04
355.1827393	0.95
356.5935364	0.07
357.4112854	0.12
363.1734314	0.34
367.3058167	0.21
371.2772522	0.11
377.2125549	0.02
381.0832214	100.00
381.7028809	0.56
389.5146790	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3152
Annotation	Unknow
Peak:m/z	Relative Intensity
168.1199646	0.02
233.5642548	0.04
235.4312897	0.04
237.2215881	0.05
241.9989471	0.21
252.9927216	0.01
254.4301147	0.40
255.3044434	0.15
256.1469727	0.05
275.1237793	0.03
277.2707520	16.85
278.3111572	2.73
279.3197021	2.61
280.4349976	0.11
283.3238525	0.06
414.2269287	0.04
431.6055298	0.11
448.2478638	0.05
502.4260864	100.00
503.3779907	0.41
513.0921631	0.03
514.5437622	0.47
515.2733765	1.63
516.2074585	0.12
517.9042358	0.04
543.4943237	0.23
544.2122803	0.43
563.2864380	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.0959
Annotation	2-(6'-Methylthio)hexylmalic acid
Peak:m/z	Relative Intensity
80.9143753	0.03
86.9046631	4.13
106.6290741	0.05
115.1091309	0.20
125.0669708	0.02
128.7095490	0.04
131.0023804	0.04
132.9495544	44.54
139.2147522	0.04
149.0239716	0.09
157.3158264	0.08
159.0274811	0.19
160.9720001	0.17
174.9877777	0.37
179.0200348	0.14
185.0655212	0.07
201.0939941	0.18
203.0611420	41.96
209.0020599	0.24
218.9752655	0.38
221.0553131	100.00
226.9782562	0.02
229.2060394	0.04
234.9658051	0.16
244.3510284	0.88
245.2019196	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	493.1353
Annotation	Hesperetin 7-O-rhamnoside
Peak:m/z	Relative Intensity
162.8996277	0.10
165.2945862	0.11
180.2757416	0.14
218.8023682	0.03
222.6428223	0.05
243.0610352	0.87
250.7720490	0.07
271.8315125	0.17
293.1368103	0.15
312.8138123	0.32
313.4945374	0.18
321.4261169	0.08
332.1952515	0.05
335.1218872	0.08
361.2890625	0.17
385.9074097	0.07
387.2485046	0.21
390.8736267	0.08
403.3792419	0.38
407.2187195	0.08
411.3404236	0.04
411.9442444	0.14
414.4149170	0.04
418.5332336	0.04
430.4358521	0.05
435.1347046	0.19
447.1805115	100.00
447.7948303	0.81
449.2329407	0.26
450.6470032	0.08
454.1990051	1.07
455.1665344	0.11
456.1860962	1.91
457.2181396	0.54
460.2255554	0.37
461.2310486	0.14
462.6860657	0.29
474.2915649	0.14
477.3225708	0.12
494.2816772	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1405
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8948059	2.11
141.0394592	0.15
159.0597839	0.81
179.1288452	0.05
191.0203094	0.11
191.8574677	0.08
209.0257874	100.00
210.2182465	0.23
228.8812866	0.07
236.9855042	0.03
245.1631775	0.12
261.0951843	0.07
270.8602905	0.16
272.3577881	0.06
274.1541138	0.06
283.3589172	0.09
291.0076904	0.08
295.0358276	0.19
296.0849609	0.16
305.1687927	0.13
310.0274658	0.13
312.0725098	0.14
313.0697632	0.47
322.3299561	0.03
325.9006042	0.06
328.1133118	0.06
329.2441406	0.31
339.0038452	0.13
341.6525269	0.11
342.4796753	0.06
344.7171631	0.36
347.0905151	0.03
355.0026855	0.08
357.1586914	0.33
358.2734375	0.04
359.1293945	0.51
374.9073181	0.52
382.9991455	0.08
400.0289612	0.05
401.0968323	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8738937	5.31
115.9277267	2.45
116.9137573	3.03
130.9187317	0.15
131.8467407	0.21
133.0722046	0.14
134.9053650	0.08
158.9417419	100.00
159.9265594	48.36
160.9087219	60.97
198.8288879	0.03
200.0139160	1.73
200.9145508	3.36
217.0867004	0.07
218.0143433	0.75
219.0539551	1.62
229.2385559	1.84
229.9324036	17.74
230.9805908	32.94
245.9371643	0.32
246.8022156	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.27
Annotation	Galb1-4GlcNAcb1-3Galb1-4Glcb-Sp
Peak:m/z	Relative Intensity
222.0900879	0.10
266.3817139	0.06
277.5804443	0.12
280.1429443	0.07
281.4627075	0.06
307.3598328	0.06
308.3414612	0.14
317.0481873	0.29
327.1253967	0.10
373.1951294	0.08
402.4172974	0.13
403.3793335	0.25
410.8925781	0.26
414.4244995	0.13
415.3378296	0.42
426.8920898	0.07
428.5127563	0.20
432.5802612	0.10
437.1155396	0.13
441.361084	0.12
444.6049805	0.10
445.4802246	0.37
447.4004517	0.08
459.1177979	0.18
460.5459595	0.11
462.3609619	0.27
471.5853882	0.33
472.2608643	0.21
473.4107056	0.78
474.4421387	0.34
488.321228	0.12
489.2877197	0.25
490.2675171	0.61
491.3283081	2.62
505.4920044	0.08
517.3291626	0.18
518.6871338	0.19
519.4653931	0.09
532.4632568	0.10
543.0715942	0.06
547.414856	0.19
566.3357544	0.36
576.3490601	0.63
585.4624023	0.06
588.463501	0.40
593.4555054	0.23
594.5057983	0.60
603.2224121	0.10
612.3605347	0.11
613.1636963	0.09
615.4145508	0.29
618.2564087	0.06
624.3970947	0.57
625.3418579	0.35
626.5739746	0.24
634.8671265	0.15
636.4068604	0.13
638.3904419	0.91
650.0864868	0.33
651.3878784	1.22
652.4255371	6.95
653.3855591	0.10
654.7279663	0.13
669.3939209	0.16
672.8720093	0.34
682.4996948	0.11
686.3679199	0.59
689.50354	1.67
695.7346802	0.20
703.5018921	0.25
710.8473511	0.26
713.6305542	0.14
728.4969482	3.45
729.7173462	0.05
731.3838501	36.98
732.0152588	0.46
739.1809082	0.23
746.461792	13.59
747.4022827	0.23
753.9537354	0.10
756.4073486	5.97
757.4476318	1.19
775.2503662	100.00
775.9502563	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1252
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
199.3770752	0.20
201.1838837	0.16
203.1974487	0.09
216.9916229	0.10
241.1009216	0.15
253.9570312	0.11
285.1434326	67.96
297.0970459	0.27
299.1310425	0.06
302.2173462	0.14
305.3530273	0.38
310.8174438	0.21
325.4888916	0.09
326.2035522	0.04
327.1811523	2.78
329.2164917	0.04
337.3193359	0.45
339.0091553	0.05
353.0704956	0.30
355.3450317	0.44
357.2977905	3.33
359.2164307	0.08
363.3318481	0.37
369.2759399	1.42
370.2317505	0.09
371.2572632	0.69
375.2300415	0.46
377.3066406	0.58
381.2927246	1.55
385.2955322	0.64
386.2387085	0.14
393.2142944	0.09
399.0402222	0.43
399.7700806	0.99
409.9982300	0.22
415.3624268	0.09
417.0300903	0.21
419.2400513	0.13
423.1788940	0.07
425.3295898	0.37
433.5980835	0.16
437.1330566	0.56
441.5325928	0.40
442.3837280	0.88
443.2703247	1.82
445.3556519	0.10
447.1570435	37.23
447.8077393	0.38
457.5137939	0.15
461.1937256	100.00
473.4052124	0.20
475.2666626	0.07
482.3801270	0.09
484.9406128	0.17
487.9970093	0.14
489.0682373	0.07
491.3472900	0.08
503.2120361	14.80
508.6860962	0.14
511.5988159	0.17
512.5621338	0.07
515.2551880	1.67
519.1898804	0.40
526.1636963	0.10
527.2844849	0.14
529.0351562	0.22
530.3018799	0.10
531.6009521	0.07
534.7708130	0.22
544.9732056	0.21
551.3969116	0.28
561.3207397	0.70
562.3801880	0.05
563.2267456	1.68
575.3209229	0.77
576.4623413	1.31
577.5997314	0.18
578.3034058	0.52
579.4713745	0.31
587.1809082	0.24
590.4208374	0.07
600.0451660	0.21
605.2216187	4.28
610.4613647	0.17
614.5546265	0.11
623.1824341	1.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	591.2582
Annotation	Swietenin F
Peak:m/z	Relative Intensity
179.8980255	0.15
221.4746704	0.09
252.7331696	0.05
311.4001160	0.08
356.2681885	0.06
358.0522461	0.04
418.3070068	0.11
445.4332886	0.23
446.4742432	0.07
447.5373535	0.13
448.3994141	0.61
458.5620117	0.04
459.5325928	0.56
460.3764648	0.72
461.4345703	0.30
467.4476318	0.10
472.2880249	0.75
473.3966064	1.40
474.3901978	1.65
475.4074707	1.52
476.3276367	0.41
484.6882935	0.36
485.4264526	0.96
486.7008057	1.72
487.4069824	6.37
488.4615479	1.24
489.4323730	0.74
490.5644531	0.46
491.6447144	0.03
492.4213867	0.03
497.5690918	0.09
498.3882446	0.04
500.6694946	0.11
501.4486694	0.07
502.3334351	0.66
503.3815308	2.30
504.3762207	1.23
505.3424683	0.32
512.4343872	0.03
513.4198608	0.15
514.4100342	0.75
515.3726196	6.79
516.4226685	0.85
517.7155151	0.96
518.4088745	1.71
519.4023438	1.37
520.4036255	0.10
526.3355103	0.08
531.3859253	100.00
532.3815308	35.02
533.3867798	3.03
537.6597290	0.06
541.4692993	0.39
542.4500122	0.09
545.7838745	0.16
546.7562866	0.26
547.4345093	1.01
548.4463501	0.40
549.3995361	0.72
558.3340454	0.11
559.3838501	2.01
560.5867310	0.25
562.4711914	0.19
563.4082642	1.42
564.2130127	0.95
564.8549194	0.05
572.5083618	0.08
576.3410034	0.35
577.1649170	0.05
577.9394531	0.02
592.4312134	19.44
593.2327271	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2241
Annotation	Alangilignoside C
Peak:m/z	Relative Intensity
165.0208893	0.07
167.1701355	0.08
177.4911652	0.07
181.1430359	0.31
190.8433380	0.17
195.0126038	0.90
201.3671112	0.05
207.1133728	0.07
216.9162292	0.04
218.3047943	0.08
223.0557251	0.28
243.0287781	0.11
253.1777802	0.19
265.4194336	0.10
268.4176636	0.11
269.1454163	0.04
273.0848083	0.04
279.4448853	0.03
285.0991516	4.88
286.0822449	5.33
287.0396729	0.80
288.0957642	0.06
289.1859131	0.32
299.3439941	0.06
308.2695312	0.06
311.1908264	0.21
313.1771240	0.15
314.9815674	0.15
323.2208862	0.04
325.1768799	6.29
326.1794434	0.05
327.2157593	0.38
328.1984863	0.41
329.3091431	0.24
341.4035034	0.16
343.3347168	4.62
345.1744995	0.31
357.2719116	0.07
359.2327271	0.35
365.4356689	0.07
371.3905640	0.04
373.3923950	0.57
375.3242188	0.10
382.4981079	0.13
383.3976440	0.10
385.3270874	0.54
394.3220215	0.15
397.3399048	0.05
399.2742310	0.66
400.4363403	2.07
401.4828491	0.68
411.0817261	0.03
413.1371460	0.05
417.2521362	0.26
419.3402710	0.46
425.2659912	0.41
427.4520874	0.05
429.2278442	0.06
436.3071899	0.16
443.2427979	0.04
444.9833374	0.41
449.1162720	0.07
455.4450073	0.17
463.3898926	0.47
465.3400269	0.07
468.5092773	0.16
473.2618408	100.00
474.5552979	0.20
484.9160156	0.37
485.9701538	0.61
487.5902100	0.13
488.4018555	0.43
489.4808350	0.03
491.3928833	25.93
492.6598511	0.03
493.5216675	0.50
495.1696167	0.22
497.4686890	0.04
503.2985229	1.69
517.3512573	0.03
519.3084717	0.18
521.2195435	14.05
522.2645874	0.15
527.5156860	0.15
531.5249634	0.06
533.3218994	83.10
534.3281250	0.17
535.3047485	0.24
536.2001953	0.40
537.1521606	0.53
538.6865845	1.54
539.3162231	20.21
543.2983398	0.12
545.4291382	1.40
547.1257935	0.06
548.2444458	0.23
549.2621460	0.15
551.3359985	0.17
558.5592651	0.04
561.6162720	0.04
563.1996460	1.97
563.9446411	0.05
566.1111450	0.29
582.4140015	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.16601562	0.73
94.94934845	0.95
96.89907074	0.47
100.1065369	1.03
103.1024323	0.34
109.0165176	0.43
122.7984009	0.70
124.8518448	1.78
126.9673615	0.87
128.8496094	4.68
130.6307373	0.30
133.0187378	0.48
134.9470062	0.71
139.0632019	1.97
141.0510406	1.59
143.0891266	3.01
145.1417694	0.48
149.2236023	0.43
150.9864655	0.78
152.9873962	4.19
154.986908	5.98
157.0669861	0.81
163.0768433	1.27
164.8134155	0.46
166.9477539	0.46
169.0327454	3.16
175.0909882	0.75
177.1139832	1.85
179.0197754	1.91
181.0231781	0.34
183.1866455	5.59
185.0280457	0.89
188.8628845	0.47
191.0089111	0.78
193.0377502	0.50
197.0212097	3.25
198.9960327	0.58
203.1369324	1.02
209.0588989	0.93
211.2351074	3.99
213.0348206	3.82
215.2506104	2.29
217.0284119	2.98
219.1637573	0.95
221.4562683	0.65
225.0517883	6.92
227.1469727	1.01
229.0575256	0.31
231.019165	0.52
233.0670166	3.95
235.2897949	0.93
237.1546021	3.77
239.309082	0.44
241.075531	0.21
247.1616211	2.80
249.155365	2.80
251.2461548	3.30
253.0068054	7.83
253.6111755	2.02
255.1190186	1.88
262.7924805	0.30
264.0683594	0.47
265.1401367	1.69
266.9805908	0.65
269.1766357	1.60
270.1398315	0.39
275.2009583	34.46
281.0717773	0.93
282.9713135	1.26
284.1529541	2.36
287.8188782	1.17
293.2039795	100.00
293.8656006	1.87
302.35495	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1786
Annotation	Unknow
Peak:m/z	Relative Intensity
139.9448242	0.45
144.9683075	14.79
153.9318848	0.07
158.9833527	0.07
166.8526459	0.38
184.9842072	0.04
196.0148315	0.64
206.0315094	0.10
211.1039429	0.09
212.0965118	0.07
213.1592712	1.43
221.9711304	0.12
223.1686401	1.95
227.0880432	0.10
229.2143555	0.10
231.0372925	0.21
240.1297302	5.53
241.1433411	0.55
242.9238281	0.07
244.0318298	0.02
244.8002319	0.06
256.9734192	0.04
258.1282349	1.30
259.1341248	0.07
263.1817017	0.43
265.2712402	0.13
267.1735840	0.33
270.7864685	0.07
271.9771729	0.07
273.1958008	0.08
275.1578369	0.28
277.2055359	0.22
279.1463928	1.81
280.1344299	1.01
285.0477905	0.14
287.8481140	0.05
291.1087036	0.05
293.1348267	0.02
294.2064819	3.35
295.4256592	1.29
296.1911011	12.21
297.3220215	1.01
299.5211792	0.13
300.8599548	0.16
311.8040161	0.93
313.2186890	100.00
314.1217651	3.85
315.2089844	0.26
331.1823730	26.65
332.0843506	0.13
333.1478882	0.23
339.2019043	0.28
341.2469177	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2625
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
139.9448242	0.18
144.9152222	0.05
153.0843048	0.27
154.0693512	0.02
159.0237427	0.02
162.9854736	0.02
167.2278137	0.04
169.2139282	0.02
174.2060699	0.05
177.1366425	0.02
179.0875702	0.01
183.0793457	0.07
193.2510834	0.02
196.1178589	2.79
197.1201782	0.18
204.8465881	0.06
206.0666199	0.02
214.1648254	1.73
215.0561981	0.03
227.4934235	0.06
233.2986755	0.55
234.4642792	0.11
236.9450378	0.06
237.5719604	0.02
247.3614044	0.03
257.4990845	0.02
259.3477173	0.56
260.2974243	0.01
261.1716919	0.03
275.1945801	0.55
277.2593384	100.00
278.2695923	14.60
294.2358398	0.06
305.1338501	0.01
313.1774597	0.10
319.1072083	0.01
346.2292480	0.02
374.5033569	0.06
378.2737732	0.02
386.4735413	0.04
393.3233948	0.05
394.2477722	0.07
413.4880066	0.20
414.4999695	0.05
428.7309570	0.04
430.5686340	0.11
431.3740540	0.04
437.5474243	0.02
457.2187500	0.06
474.8974915	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0777
Annotation	3-Galloylgallocatechin
Peak:m/z	Relative Intensity
129.9572144	0.22
130.8797760	0.36
136.8951721	0.37
139.0775452	0.31
145.0356903	0.21
148.9901428	5.73
155.0865784	0.19
160.0708313	0.10
161.0047302	1.32
163.0188751	16.21
167.8052826	0.08
174.9511871	0.23
179.0516815	6.50
189.0138092	0.07
191.2788696	0.37
203.0894928	3.77
203.9654083	0.17
205.0997925	1.16
209.4907532	0.23
218.9970856	7.40
221.1352692	0.27
227.1254120	0.40
231.0781708	0.76
233.1183014	1.47
235.2087402	0.22
239.1559448	0.07
246.9400940	0.59
249.1115417	1.05
253.2643127	0.08
257.2044983	0.22
259.1091919	0.68
267.1388550	0.26
271.0491943	0.14
272.4846191	0.46
277.1230164	41.69
281.2945557	0.24
284.0953064	0.51
291.2122192	0.30
293.1178589	71.10
295.0738525	100.00
311.0937805	5.22
315.5001831	0.22
324.9966431	0.18
333.5574951	0.08
340.6985779	0.33
354.3770752	0.07
358.4636230	0.10
361.0749512	0.12
368.3244629	0.34
369.4983521	0.10
384.1630859	0.07
394.0873718	0.13
398.4074402	0.40
399.3171997	0.13
402.4674988	0.15
409.4429016	0.23
410.3058472	0.57
411.6213074	0.71
413.1666565	0.64
414.3247681	0.07
415.3182068	0.25
420.0619202	0.80
435.1363220	0.36
438.2812805	2.22
439.4463196	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.0808
Annotation	Quercetin 7-glucuronide
Peak:m/z	Relative Intensity
137.1146851	0.01
146.8075714	0.01
163.1042938	0.01
166.6807098	0.02
175.0441284	0.01
201.2865295	0.02
204.9468079	0.01
221.0236511	0.01
231.0943756	0.04
237.2568359	0.02
264.7642822	0.03
271.1488953	0.02
273.1969910	0.01
276.6387024	0.01
281.3789673	0.03
288.3152771	0.01
292.2296143	0.02
294.4089661	0.01
295.1412354	0.01
298.0687561	0.02
303.1139832	100.00
315.1239624	0.08
316.2529297	0.20
327.1408081	0.02
330.8182373	0.04
345.1351318	0.02
355.2633057	0.01
360.1343689	0.01
368.2340698	0.05
373.2056885	0.01
385.2513123	0.05
387.2107239	0.01
396.2783508	0.02
397.6386719	0.03
399.2197876	0.01
407.2235718	0.02
419.2443542	0.02
425.1711121	0.04
431.2086792	0.01
433.0987854	0.23
433.7220764	0.02
441.4237976	0.03
443.4211731	0.06
447.3533630	0.12
451.0866394	0.05
452.2026367	0.03
456.2801819	0.01
460.0670166	0.14
461.1198425	0.29
462.0397034	0.04
469.3158264	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.3641
Annotation	Denin
Peak:m/z	Relative Intensity
217.1698914	0.03
218.5614166	0.02
219.3346405	0.04
220.0498352	0.00
221.3192139	0.17
222.5902710	0.01
223.4074402	0.01
227.3599243	0.02
231.3522644	0.01
233.1907196	0.01
235.2751312	4.26
236.3622131	0.38
237.3664246	0.02
245.2817230	0.14
246.4656372	0.03
253.3879852	0.75
254.3455811	0.05
259.2680054	0.03
260.6912231	0.03
261.3249512	0.01
263.4219360	0.14
264.2511902	0.03
268.8185425	0.02
275.6445923	0.01
277.4393921	3.53
278.5096436	0.50
283.0112610	0.02
287.3479919	2.90
288.3584595	0.34
291.4592285	0.05
292.6722412	0.00
295.2119751	0.02
301.5330811	0.05
303.4385376	0.08
305.4042664	4.41
306.4370422	0.55
317.2200317	0.01
319.5722656	0.05
321.3021545	0.00
323.3665771	0.68
324.4816895	0.08
325.6005859	0.00
337.5114136	0.01
341.7184448	0.00
349.4963989	0.02
350.5631104	0.01
351.4991150	0.04
361.5444946	0.15
362.6758423	0.07
369.9508667	0.01
373.3902588	0.02
378.4171753	0.01
379.4379272	0.33
380.5277710	0.05
391.1471558	0.05
397.3867188	100.00
398.3626099	17.05
399.3587646	0.04
415.4130859	30.42
416.4086304	5.17
417.4732666	0.01
421.2064819	0.02
432.3707275	0.01
434.6168213	0.02
449.5431519	0.02
455.5256958	0.01
460.1691895	0.01
461.3084106	0.01
468.0795898	0.01
469.2492676	0.07
470.3217773	0.03
471.5137939	0.01
495.5379639	0.00
514.5438843	0.01
523.1616211	0.02
568.6067505	0.01
582.9447632	0.01
585.2700195	0.02
601.4013672	0.01
625.6853638	0.01
626.8552856	0.01
631.5349731	0.01
657.5883179	0.03
658.5665894	0.02
675.4006348	83.03
676.2478638	60.65
677.2371216	1.10
678.3667603	0.01
684.4293823	0.01
686.4982300	0.01
701.3189697	0.01
703.5471802	0.02
722.1462402	27.25
723.1630859	1.76
723.8465576	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8667908	26.51
184.1004791	0.37
199.0260620	0.48
212.7434540	19.73
269.9727478	2.54
296.1091003	23.03
296.8588257	100.00
334.6694336	0.16
352.3778076	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.3284
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
160.9778748	0.22
173.0119019	0.15
235.0426636	1.29
239.0684509	0.13
253.1195679	6.79
261.2207031	0.20
277.1348877	0.62
278.2109070	0.83
279.2444458	100.00
279.8472900	0.38
283.3159790	0.10
310.4929810	0.27
389.4772949	0.06
413.3859863	0.07
441.6828613	0.05
449.3743896	0.04
462.3873291	0.21
499.2547607	0.19
503.6427612	0.14
515.1585083	23.66
515.7921143	0.17
525.3253784	0.53
538.9712524	0.11
543.2373047	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.07
Annotation	SC-1271
Peak:m/z	Relative Intensity
108.1321716	0.53
109.1277466	0.33
111.9887009	0.54
123.0390091	15.21
134.9942932	0.14
135.9368286	1.38
142.9541473	1.77
151.0113220	0.84
151.8526001	2.23
153.0451660	100.00
159.1367645	0.65
163.0202942	0.89
165.0744019	1.51
174.8774872	0.67
177.2964478	1.55
179.9662781	0.22
181.0790100	0.19
191.0391541	1.67
192.1444092	0.51
193.1445923	0.34
195.0480042	39.77
207.1061401	0.77
223.1166077	0.25
227.9374084	1.41
229.1839600	0.11
246.9662170	0.40
269.2294617	1.33
277.2274780	0.58
295.3032227	0.61
297.1528015	2.01
299.7269592	0.53
305.8853455	0.23
312.9996338	1.06
315.1652832	1.94
339.4241943	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8976
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0065002	0.52
174.9919128	1.00
198.9195557	0.17
215.2450867	0.14
216.8474579	0.05
229.1367035	0.08
244.8944702	0.14
261.3400269	0.07
273.0308838	9.33
288.9483643	25.20
386.9390259	0.51
402.9229126	100.00
427.0470581	0.09
429.0391235	0.02
443.0502930	0.09
470.9599609	0.05
497.9919434	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9974365	0.31
130.8402405	0.57
133.1183472	0.14
134.1500854	0.15
135.1863098	0.10
143.0022125	4.65
148.9973450	0.68
159.1517639	0.07
160.9026184	4.80
164.9920349	0.35
171.0824432	0.17
179.0133362	13.45
189.3151245	0.10
192.9651184	0.08
204.8756104	0.27
206.8497162	0.07
209.1836243	0.15
223.1437378	0.63
225.2754517	0.09
232.2728577	0.07
241.2774658	0.04
247.2080688	0.22
251.0350037	0.63
259.2392883	0.32
260.8739014	0.09
269.1550598	0.37
293.3390198	0.09
295.1242065	0.80
296.0720825	0.18
307.1809387	0.14
312.2521973	0.07
315.1923218	0.23
339.3156433	0.11
341.2027588	0.20
343.3077393	0.24
347.2973633	0.09
357.2467651	0.10
367.2793274	0.57
371.2164307	0.52
385.2021790	100.00
385.8497314	0.20
387.4790344	0.12
391.1936951	0.34
393.2223816	0.78
394.3575134	0.63
399.4582825	0.24
402.2187195	0.25
410.8366089	0.07
411.5187683	0.04
412.9705505	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1514
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
170.9418335	0.08
175.1097870	0.37
175.9010620	0.08
178.9791870	0.05
182.0140076	0.01
185.1177826	0.10
187.1535034	0.03
189.2191925	0.16
194.9124298	0.05
196.7763977	0.03
198.0564728	0.05
199.0909424	0.58
200.1050720	0.06
201.2233887	0.02
205.1515808	0.08
207.2973328	0.02
208.1488953	0.06
211.0937805	0.06
213.0675659	0.02
215.1244507	0.18
216.0981598	0.07
217.0023499	0.43
223.0204468	0.04
226.4986725	0.07
229.1892242	0.06
239.0554199	0.02
240.0449219	0.05
241.1486511	0.32
242.3875122	0.05
243.0651703	0.45
251.1646881	3.39
252.2839050	0.20
254.2012329	0.11
256.9841614	0.09
266.9458313	0.15
269.2819824	0.13
270.4013977	0.05
272.2283936	0.22
285.0857544	100.00
286.0889282	12.83
293.2000732	0.03
297.1105347	0.07
298.2448120	0.10
299.0516968	0.04
323.0816040	0.04
327.1210938	0.73
328.0842285	0.17
341.1918945	0.14
353.1521606	0.07
357.0747681	0.09
386.4387207	0.02
401.3142090	0.03
407.2650146	0.21
413.0889893	0.95
414.2689819	0.16
417.0470581	0.02
427.8663330	0.08
431.2611084	7.26
432.3030396	1.25
447.3712769	0.97
448.3031616	0.13
465.4439087	0.10
497.5641479	0.08
511.8703613	0.06
533.4329834	0.05
539.3414917	0.04
547.1696167	0.20
550.1611938	0.05
576.2803955	0.25
594.2545166	0.38
595.3200073	0.34
595.9276733	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.3809
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1878967	1.94
245.0813293	0.09
253.1856689	0.21
255.2777100	0.33
281.0840149	0.03
287.0836182	1.08
305.1299133	1.21
323.1915588	0.28
361.2416992	0.33
379.2230225	0.61
397.1976318	52.51
397.8090820	0.49
405.6406250	0.07
415.3005981	18.65
492.8429565	0.10
518.9758301	0.11
638.5172729	0.24
649.4653931	0.21
653.2565308	100.00
653.9573364	0.60
658.3601685	0.25
666.5275269	0.13
680.5122681	0.16
683.6599121	0.35
699.1202393	58.73
699.9234009	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.233
Annotation	Unknow
Peak:m/z	Relative Intensity
363.2447510	0.90
370.2194214	0.11
381.1904297	0.17
437.5457153	0.01
453.4913330	0.05
523.6773071	0.01
525.2379150	6.59
525.9276123	0.02
533.0797119	0.14
543.2189331	4.66
613.7514648	0.17
614.4788208	0.05
615.4542847	0.06
687.4218140	14.49
705.3184814	18.65
705.9271851	0.07
723.1296997	0.06
777.4016724	0.03
867.4014893	100.00
868.0614624	0.27
868.7473755	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1219
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
131.2391052	0.09
179.0970459	0.19
235.4474335	0.03
250.1382141	0.07
253.1325684	0.24
259.2201538	0.10
267.9871216	0.08
281.3388062	0.03
302.0614624	0.09
304.8690796	0.23
311.0131531	0.12
312.0514526	0.04
317.3018188	0.10
323.2874146	0.29
341.0223389	0.04
374.3296204	0.02
404.5469360	0.08
415.3127136	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.8781738	0.44
239.7685852	0.05
259.3291016	0.19
286.8281555	0.07
299.6403809	0.07
302.9054871	8.22
308.9544678	0.27
381.7483521	0.34
382.8792725	0.16
383.7551270	0.24
386.7898560	30.31
464.8562012	0.66
466.3056030	0.06
467.9985962	0.23
468.7175903	0.08
470.7486572	100.00
482.9063110	1.52
522.9589844	0.16
550.6629639	0.23
551.9213257	1.08
552.5549927	0.91
554.5244141	56.22
555.3199463	0.05
570.6548462	0.03
591.6591797	0.04
592.7068481	0.21
619.8645630	0.14
638.6957397	1.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1753
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9880676	1.20
137.1522064	0.05
148.2353973	0.26
161.0180511	23.26
163.0012817	0.80
163.9589539	0.47
171.0705872	0.14
174.0291443	0.21
174.8317108	0.07
177.8598785	0.10
188.0930786	0.27
192.9823608	100.00
195.0563965	0.09
197.2662048	0.35
207.2207336	0.15
211.0803833	0.29
212.1896362	0.08
215.0355682	0.28
216.0277252	0.15
224.9482117	0.21
229.2858276	0.24
230.0909576	0.22
234.9025574	0.19
243.1725616	0.05
247.1567230	0.04
248.0366669	0.62
251.9140015	0.14
261.2287903	0.23
264.0876465	0.22
265.3331299	0.49
266.1350403	0.73
268.8488770	0.11
270.1513672	0.08
278.9767456	0.33
279.8412170	0.06
283.3195190	0.16
284.1102905	0.49
286.0838013	0.18
295.2370605	0.18
296.2685852	0.23
296.9905396	0.12
298.1386414	0.15
299.0638123	0.17
301.1349182	0.44
302.2326660	1.47
307.4858398	0.08
308.3745117	0.46
314.1040649	0.06
321.4326172	0.28
325.5045166	0.90
326.2222595	2.68
329.4488525	0.07
333.7823486	0.16
342.2919617	0.29
343.0639648	0.58
344.1105042	1.51
345.0799866	0.14
354.0126953	0.42
359.4138184	0.15
360.3471680	0.16
364.9329529	0.12
366.1310425	0.62
379.2081604	0.32
382.0054626	0.11
385.5082092	0.25
387.4642639	0.07
394.6675415	0.84
400.7346802	0.05
401.6389771	0.49
405.3430786	0.17
414.9697571	0.04
416.1407471	0.17
422.3741760	0.60
423.3422241	0.22
426.8936462	0.46
430.2000122	0.59
431.3097229	0.20
432.5837097	1.11
440.4296570	1.07
441.1150208	0.36
447.1421204	0.62
457.2589417	0.66
458.1776428	1.52
466.4822388	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1456
Annotation	luteolin-3',7-di-O-glucoside 
Peak:m/z	Relative Intensity
174.9250183	0.06
182.1755676	0.08
185.1412354	0.03
189.0777893	0.05
197.1420898	0.10
197.8701935	0.18
198.9991455	0.42
201.0691071	0.20
207.2430115	0.07
212.969635	0.15
217.0938416	0.19
225.1489563	0.50
225.8617249	0.17
227.0068054	0.08
233.5835571	0.05
239.1377563	0.05
240.2149353	0.16
241.132843	0.60
241.98703	0.12
243.2168579	0.26
249.2669373	0.11
257.0769043	0.22
267.2501831	0.25
281.0684509	0.24
283.1595154	0.07
285.0421753	100.00
285.6772461	0.17
293.2456055	0.04
295.1279907	0.03
297.1603394	0.08
301.1998901	7.15
303.2228394	0.07
313.7421265	0.10
314.3513794	0.07
321.5473022	0.02
323.2623291	0.04
327.1968384	0.49
337.1584473	0.16
341.2661133	0.08
353.4158325	0.03
357.1020508	0.24
359.3768311	0.03
360.8461304	0.04
373.1865234	0.11
387.2332153	0.05
397.3040771	0.02
398.9807129	0.10
405.234314	0.65
420.3341675	0.12
423.3078613	0.41
428.1894531	0.13
429.2644653	0.30
445.0465698	0.15
447.2357178	23.61
453.3961792	0.25
475.2472534	0.29
491.180481	0.28
500.4946899	0.08
502.9832764	0.04
512.3619995	0.10
513.3261719	0.03
518.9597168	0.03
521.1358032	0.09
523.3364258	0.05
531.5814819	0.05
536.1381836	0.16
540.340271	0.03
541.4325562	0.04
543.1956177	0.32
545.1968384	0.40
551.2776489	0.04
555.3272095	0.03
563.2180176	0.84
564.1556396	0.24
565.2806396	0.38
570.4261475	0.28
571.1060181	0.03
573.2147217	0.32
582.319397	0.05
586.6948853	0.04
588.361084	0.08
589.1694336	0.26
591.3604126	0.31
610.3862915	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	634.65
Annotation	Cer(m18:0/24:1(15Z))
Peak:m/z	Relative Intensity
206.6732788	0.41
212.7900543	1.83
213.6846466	0.23
222.9113464	0.29
272.9332886	0.39
290.7531738	1.11
292.8510437	0.30
296.8097534	1.49
298.6315002	2.13
312.9435425	0.83
337.0772705	0.41
367.1423950	0.99
370.6873169	0.12
373.2460327	0.08
380.7328491	10.91
381.7910156	2.87
382.8461914	18.38
385.2070923	1.05
387.0091553	0.54
411.0163574	0.38
411.9694824	0.54
413.0256348	0.19
423.2376709	0.40
441.4688721	0.16
442.7578735	0.42
450.9661865	1.16
454.9375000	3.64
462.6325684	0.19
464.5473022	26.80
465.6434326	15.99
466.6165161	51.80
470.9230957	0.89
480.8065186	0.24
485.1358032	0.55
503.0685425	0.80
529.7229614	1.56
545.0479736	0.23
547.8353882	1.96
548.5821533	14.49
549.7061768	67.10
550.6959229	100.00
557.8629761	0.86
560.9874878	0.31
562.7014160	0.32
565.8699951	0.55
572.9972534	0.14
574.4296875	0.94
578.5397339	0.31
580.5792236	0.62
590.9915161	1.61
592.0558472	3.49
592.8546143	1.74
596.9882812	0.95
604.9041138	0.25
617.0783691	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.18
Annotation	Cyclocalopin D
Peak:m/z	Relative Intensity
155.0772552	0.06
161.0049438	0.10
173.0913544	2.79
175.0189819	0.06
179.0072937	4.50
180.0445557	0.08
185.0784302	0.02
187.5449219	0.03
191.0782471	3.92
200.8184662	0.01
203.1365662	2.46
205.0173340	0.12
207.0386963	0.09
210.3354492	0.01
211.1841125	0.03
213.2608032	0.03
217.0130157	0.03
219.1620178	0.05
220.4633179	0.08
221.2516937	0.07
225.2097778	0.02
227.1551361	0.16
237.1460876	0.04
249.2078400	0.64
253.2432861	0.02
255.1755219	1.45
267.2371826	0.03
271.0722046	0.01
273.1080933	0.10
289.0832214	0.01
293.0254517	0.10
294.1310425	0.12
299.2282715	2.23
303.0048218	0.07
309.2709351	0.27
310.6547852	0.24
314.4815674	0.06
317.0956421	0.70
328.2731323	0.12
329.3072510	0.03
331.1159668	0.04
335.2420654	1.32
336.0885620	0.04
341.1326294	0.49
351.0585327	0.04
353.1803589	100.00
358.7963867	0.02
364.1165771	0.03
379.2571411	0.05
393.3068848	0.04
395.2293701	0.10
397.2286987	0.07
398.4047241	0.14
399.4501343	0.05
411.3851929	0.01
412.3056030	0.24
418.4571533	0.04
421.5452271	0.09
423.3952026	0.04
427.1867065	0.21
429.2812500	0.08
432.5453491	0.02
434.2084961	0.85
436.4309082	0.02
439.3386230	0.11
443.1051636	0.22
447.1188354	0.17
451.2186890	0.02
452.4402466	0.03
453.3155518	0.04
455.2930908	0.03
469.2733765	0.24
471.1749268	3.59
471.7812500	0.12
484.2966309	0.04
497.3236084	0.26
500.3648682	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	230.99
Annotation	Unknow
Peak:m/z	Relative Intensity
69.8327942	4.68
113.8951569	12.00
114.8842468	2.89
115.9149475	13.78
125.9951019	2.63
132.0062103	3.03
135.2178650	2.44
139.0907593	1.39
141.8862000	17.80
142.8685760	23.55
157.1106415	3.40
160.9370270	5.84
168.1630096	6.71
169.1213226	6.51
171.0565338	6.58
183.8130035	2.45
184.4156647	3.35
185.1665649	15.70
189.1689301	2.56
195.0842133	6.44
196.0928802	11.00
202.0623322	1.61
212.0315399	4.92
213.0297546	100.00
214.1350555	11.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	915.1625
Annotation	Unknow
Peak:m/z	Relative Intensity
258.6274719	0.05
275.1184082	0.30
277.1426697	10.38
292.2127686	0.04
293.1003418	13.87
295.0242615	17.71
311.0847778	0.26
337.5245361	0.08
397.2411194	0.03
399.2464600	0.03
435.2188721	0.07
438.9789429	0.06
455.4190063	0.12
457.0089722	30.30
457.6702881	0.04
482.1937256	0.04
494.3708496	0.04
545.2369385	0.10
547.0883789	0.05
579.3625488	0.03
608.4121094	0.11
637.1165771	0.04
650.4328003	0.08
712.4645386	0.07
750.6046753	0.11
752.8652954	0.28
783.4939575	0.12
811.5770874	0.24
829.5894775	0.09
853.4346924	0.04
871.4710083	2.64
887.6296387	0.13
897.7975464	0.22
914.8054199	100.00
916.1983643	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9142
Annotation	Unknow
Peak:m/z	Relative Intensity
102.8234558	0.07
112.6431961	0.16
115.0437317	0.54
130.9497070	4.48
144.6138763	0.08
146.9657898	2.13
158.9934998	6.83
174.8733826	100.00
189.9619751	0.32
190.9112396	0.55
206.9939270	0.11
219.9727478	0.09
230.7174683	4.26
231.4042664	0.11
242.0698242	0.16
247.1178284	0.07
248.9743652	2.19
257.9777527	0.90
259.1182251	1.25
260.7756348	21.83
268.8188477	0.11
272.1476440	0.04
276.1152649	0.13
276.9919434	2.71
287.1081238	0.40
289.3837891	0.05
294.1233826	0.23
294.8562012	0.03
305.0252075	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1016
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
146.9539337	0.01
153.0161133	0.02
163.2177277	0.02
191.2087708	0.02
199.0873413	0.04
208.3362427	0.00
214.3622284	0.01
215.3136902	0.02
216.0166931	0.01
243.2770081	0.02
264.2394409	0.01
285.1500244	0.04
287.9433289	0.02
289.3246155	0.04
295.2564392	0.03
296.0473633	0.01
297.2050781	0.25
300.0278625	0.02
303.0833740	100.00
303.9362183	0.00
309.0398560	0.00
315.1369019	0.04
327.0939331	0.03
331.1224976	0.03
345.1176758	0.71
361.0269775	0.01
368.2625122	0.00
369.2587891	0.16
379.1579285	0.09
384.3175964	0.03
390.1468811	0.03
399.1273193	0.35
400.6762390	0.02
401.4661560	0.02
404.5384521	0.01
411.0826111	0.38
419.1084290	0.01
420.4454041	0.02
422.1039124	0.01
428.3030396	0.03
429.1686096	0.13
432.3265991	0.02
437.2890015	0.01
445.4531250	0.03
447.1036682	0.95
448.2645569	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	354.09
Annotation	Unknow
Peak:m/z	Relative Intensity
111.0340424	0.02
126.9483795	0.05
127.7973938	0.03
135.0534973	0.79
136.1077576	0.06
143.0561371	0.03
155.1043243	0.02
160.9510193	0.43
161.9871216	0.11
173.0411987	0.38
174.1426544	0.07
179.0196838	4.54
180.1332397	0.64
191.0080261	100.00
192.0481262	15.11
193.2061768	0.02
309.2270508	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	947.66
Annotation	PI(20:1(11Z)/22:0)
Peak:m/z	Relative Intensity
293.2527466	0.07
311.1350098	0.01
472.9678345	0.11
946.8396606	100.00
947.6090698	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.0864
Annotation	3,3',5,5'-Tetrahydroxy-6,7-methyleneoxy-4'-methoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
159.1603088	0.14
163.1820526	0.23
165.0004120	0.04
173.0411072	0.08
181.1861572	0.10
188.0671997	0.06
192.2539673	0.03
194.8753357	0.03
197.1289368	0.12
201.0564423	0.03
212.9865570	0.22
221.3824768	0.12
229.0259399	0.09
231.3273315	0.16
242.2750549	0.03
243.0695801	0.07
244.3927002	0.04
267.1070557	0.14
271.2814941	0.17
283.1968689	0.09
286.3392639	0.05
289.0177307	0.14
297.3837280	0.21
298.2202759	0.03
303.0846558	100.00
303.7034302	0.68
312.0325928	0.07
316.1814575	0.05
317.0167236	0.08
327.2074585	0.18
329.3158569	0.03
331.1586304	0.08
339.2807617	0.03
343.3022461	0.22
344.1247559	0.68
345.1897583	0.81
351.2755127	0.07
352.4682007	0.07
354.9828491	0.15
363.4650879	0.15
364.0936279	0.11
370.2208252	0.11
374.4394531	0.18
381.3875732	0.10
390.2741089	0.10
392.7604980	0.20
394.0826416	0.16
395.3377686	0.02
397.3346558	0.09
398.1936035	0.02
401.4029541	0.11
403.4588013	0.06
405.1594238	0.03
407.3715210	0.06
412.9730835	0.09
417.0820312	0.13
418.0922241	0.09
425.2513428	0.03
433.4798584	0.05
436.3613281	0.08
437.2493286	0.08
439.4941406	0.27
443.6829834	0.23
446.8754272	0.12
449.7426758	0.08
451.2356567	0.94
455.9338379	0.17
465.5917358	0.06
475.2845459	0.67
477.2935181	0.02
483.2434692	0.06
487.7765503	0.04
491.0878296	0.09
492.5144653	0.05
493.2017212	0.04
497.3290405	0.08
498.6442871	0.20
501.0602417	0.76
503.5394897	0.06
505.4443970	0.18
509.3272095	0.15
518.3715210	0.35
519.1356812	1.92
523.3268433	0.03
528.7962036	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.12
Annotation	O-Acetylgeniposidic acid
Peak:m/z	Relative Intensity
125.2095947	0.04
127.6841278	0.05
129.9447937	0.05
131.9921875	0.03
132.9434204	0.38
134.9270782	0.23
143.1099548	0.08
148.9590759	0.06
160.9559784	0.47
162.0854187	0.23
163.2212219	0.07
166.9490051	0.03
177.0464783	2.20
179.0568542	0.73
180.1312561	0.73
186.0973816	0.08
187.1365662	0.16
190.9653015	0.28
192.0710449	14.20
193.0481262	0.07
205.0756226	0.13
207.0630188	100.00
219.0120239	0.18
224.9915161	0.07
235.1207581	0.05
236.2697754	0.21
244.8115234	0.25
245.8879089	0.07
266.7496643	0.09
272.3580933	0.04
275.3510742	0.06
277.0879517	0.03
283.1723633	0.23
285.1618347	0.03
293.1083069	1.66
294.0719604	1.17
295.0356750	0.62
296.2061157	0.06
299.2630310	0.04
299.9297485	0.03
306.8498535	0.14
310.9039612	0.26
315.5775146	0.06
323.3432007	0.04
327.1400146	1.20
329.2158203	0.53
332.9658203	7.54
333.8007812	1.84
336.3567505	0.14
341.0923462	0.26
343.9944763	0.14
347.4581299	1.68
348.2289734	2.28
349.5700684	0.46
350.6062012	0.24
351.5057373	0.10
353.4358521	0.03
354.1779480	0.03
355.1851196	0.38
358.8410950	0.06
366.8719177	0.07
368.9430542	1.20
371.4066162	1.00
373.3556519	0.04
376.1439209	0.03
380.2290344	0.08
385.3511047	0.05
386.3800659	0.06
392.2046509	0.51
393.2307434	0.05
397.2238770	0.18
398.2075195	0.09
400.4089966	0.10
405.2701721	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.2057
Annotation	5-Megastigmen-7-yne-3,9-diol 3-glucoside
Peak:m/z	Relative Intensity
104.9803467	0.13
106.9466324	0.48
108.7411957	0.26
112.9119110	0.10
114.9565964	0.07
117.0218964	0.03
118.9159088	0.36
121.0192719	0.81
123.0340729	0.54
125.1910477	0.05
131.1225891	0.29
133.0180206	4.58
135.0852051	0.14
135.9665985	0.06
136.9726257	0.45
146.4640808	0.07
147.0832214	0.09
149.0971680	2.53
151.0512695	4.34
158.0678101	0.12
161.2428284	0.24
163.0683594	0.17
165.0390015	5.42
166.2207184	0.09
170.9548950	0.04
173.1391602	0.65
174.7795715	0.13
177.0021973	0.06
188.2687988	0.03
191.0239868	7.14
193.2362671	1.83
199.0301819	0.03
200.1508179	0.18
209.0951233	100.00
209.8449707	0.07
213.2338409	0.03
217.1234436	0.03
219.0313110	0.16
220.5709534	0.06
221.9430542	0.09
227.0374146	0.26
231.3313599	0.16
232.1189880	0.28
235.0328064	0.09
236.9970703	0.09
253.4672241	0.13
257.2879333	0.11
261.2121582	0.11
274.4069824	0.03
281.2459106	0.07
283.0680237	0.04
287.1699219	0.04
294.0272827	0.03
296.1957703	0.06
302.8146362	0.10
309.4258728	0.03
311.2727051	0.09
311.9571228	0.16
317.5180359	0.04
318.9434814	0.05
327.1444397	0.08
328.6252441	0.05
334.5343018	0.21
335.2785645	0.09
336.0389099	0.11
342.2547607	0.32
343.2737122	0.11
344.1330261	0.06
348.0439148	0.09
353.2173157	1.57
354.4209595	0.47
370.0514221	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.221
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
95.00200653	0.46
96.89173126	1.34
99.0037384	1.10
100.9966888	0.60
106.9511108	1.51
109.0453796	0.47
118.9381485	0.20
120.9169617	0.37
122.9070206	2.48
124.9325867	0.73
129.0174713	0.61
132.7657471	0.85
134.9532166	2.34
135.6227264	0.35
136.989502	0.38
138.9584961	1.72
141.0862122	2.68
143.0208282	2.25
147.1330872	0.17
149.0101929	1.89
152.9608459	1.19
155.0501709	1.60
156.7286682	0.57
160.9203491	0.75
163.0027161	1.50
166.8045349	0.51
169.0638275	3.15
170.9966431	0.95
179.1959076	0.59
180.9210052	2.04
182.1310272	0.27
182.9770203	1.75
184.9936676	1.30
189.4399567	1.16
193.0743713	0.44
194.9150543	1.20
197.1989746	3.17
205.0874634	0.33
207.0227051	0.63
210.225647	0.32
211.152832	3.86
212.9125366	1.03
215.1105042	1.10
219.2060242	0.96
222.1135254	0.64
223.164032	2.00
225.2680054	0.90
227.1266479	0.94
228.7729797	1.06
231.2347107	0.23
233.0966797	1.02
235.163208	1.69
237.3006897	0.50
239.2239685	2.71
241.315094	0.86
244.8445129	0.28
247.2623901	0.24
249.1505127	0.98
251.1959534	3.05
253.2203979	6.60
255.1739502	0.34
257.2789307	0.18
263.3518982	0.74
264.2577515	0.18
265.2819214	0.77
267.242981	1.62
269.4075317	1.33
270.0827637	0.62
275.2975464	27.08
277.2825012	0.74
279.3501892	0.43
283.1404419	0.29
293.203125	100.00
294.3514709	0.99
301.7948303	3.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.0464
Annotation	Nitrofurantoin
Peak:m/z	Relative Intensity
98.8995819	0.32
104.8644791	100.00
110.5546570	0.43
112.9366150	0.13
114.9013748	0.24
118.9930267	0.22
128.9928589	0.81
131.0584106	0.11
134.7553558	0.20
135.4680176	0.16
142.9007416	1.79
149.0863953	0.65
150.0329895	0.46
151.0340118	0.37
153.1603699	0.14
160.7329712	0.14
173.0113068	20.80
174.9896393	0.52
177.3086853	0.07
178.8015747	1.08
186.8872070	0.08
189.7564545	0.30
191.0295715	1.89
203.9925537	0.27
205.9065552	0.15
221.0813293	0.12
234.2302856	0.16
235.2283325	0.15
250.1000977	0.20
250.9011230	0.54
253.2646484	0.14
254.0097961	0.15
261.2218628	0.12
273.3595581	0.11
278.9748535	83.23
282.5921021	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.07
Annotation	Quinic acid
Peak:m/z	Relative Intensity
58.7879410	0.54
80.9795837	0.24
82.9334946	0.34
86.9848938	3.74
92.9962158	0.17
96.9929810	0.44
100.8528900	1.92
105.1788635	0.19
118.9160156	0.71
127.4931488	0.10
128.9038391	13.42
132.9963684	0.23
135.2822571	0.25
137.0625000	0.43
142.9472656	1.03
144.5667572	0.37
146.8258820	100.00
148.9685516	0.27
156.8508453	4.35
162.9332428	0.18
163.9183350	1.15
164.7170868	5.39
168.1481476	0.49
174.9962311	6.59
176.5274811	0.28
177.9651031	0.49
184.0500946	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1021
Annotation	Quercetin-3-(6''-malonyl)-Glucoside
Peak:m/z	Relative Intensity
176.7868347	0.15
190.7928467	0.07
196.8302917	0.04
208.9759521	0.21
216.1547852	0.10
218.9041748	0.11
235.2148285	0.25
257.0975342	0.03
267.089386	0.04
271.06427	0.06
273.1797485	0.19
285.510437	0.04
287.3091431	0.21
288.0141602	0.11
289.2384033	0.11
291.3832397	0.04
295.0977783	0.09
297.257019	0.31
303.0560303	100.00
303.7084961	0.21
305.5098267	0.02
306.9755249	0.40
327.2155762	0.55
345.0814209	2.04
359.0827026	0.08
363.5393066	0.10
369.1824341	0.22
376.2663574	0.17
386.2833862	0.08
393.152771	0.17
398.7891846	0.15
411.0805054	0.51
429.0654297	0.33
438.9689331	0.14
463.1113892	0.09
465.0634155	0.08
469.3687134	0.09
470.5264282	0.11
477.0107422	0.13
493.3052368	0.24
505.3347778	0.11
514.4575806	0.15
515.3256836	0.49
522.1575928	0.08
525.4195557	0.41
526.5269165	0.04
531.3031616	0.04
533.1898193	3.63
534.152832	0.04
536.0383301	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.072
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
92.8617401	0.24
94.9280930	0.14
98.8171463	0.50
100.9707336	0.39
107.8718567	4.83
108.9671173	9.29
112.9558487	0.83
120.9500809	1.07
123.0495529	0.72
132.9511108	0.99
134.0070648	0.12
135.0169373	0.80
136.0722351	0.35
145.1311035	0.22
151.1275024	7.36
151.9060211	41.99
152.9127808	100.00
159.2785797	0.44
161.0379181	0.95
161.6629639	0.30
163.0276794	8.45
165.0100555	9.98
167.1155090	0.11
177.0888977	1.10
179.1072998	3.86
181.0406799	2.19
183.1595764	0.42
189.0596619	0.22
191.1092072	0.78
193.0724792	1.14
194.9855499	4.05
202.8917389	0.10
207.0236511	2.37
208.9558411	0.43
219.1394958	1.54
222.8837280	0.52
225.1025085	7.00
229.1531677	0.29
237.0093079	1.18
243.0883484	0.14
269.0522766	0.50
269.9865723	0.40
324.2844543	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.31
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
179.1473389	0.04
187.2631836	0.02
211.4513092	0.01
231.2073975	0.04
233.5227509	0.16
235.1212769	0.94
253.0885010	9.56
257.3821106	0.03
259.5942078	0.14
275.3993530	0.19
277.2656860	100.00
421.4833984	0.06
513.1178589	18.50
513.9259644	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1023.77
Annotation	TG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))
Peak:m/z	Relative Intensity
522.5536499	1.11
852.612915	1.23
861.1456299	10.05
869.1186523	2.19
889.7331543	3.27
946.2091064	9.97
968.1668701	10.23
979.6376953	12.57
982.5507812	4.90
1002.827393	5.13
1023.730469	100.00
1090.12915	1.48
1108.839478	12.40
1120.91333	4.30
1150.355591	12.20
1163.199463	7.06
1190.422241	8.56
1198.573608	1.74
1275.496338	2.23
1299.612671	7.31
1312.781616	8.47
1346.572754	6.38
1378.270386	7.39
1386.741577	15.84
1387.360229	2.24
1409.384888	6.62
1418.937866	14.23
1459.656738	2.77
1460.484741	4.04
1469.185425	6.21
1490.301758	2.32
1561.78894	1.74
1590.30603	5.57
1652.809448	13.25
1788.822021	1.36
1849.105103	3.28
1879.705933	4.10
1890.436768	79.04
1899.076538	4.42
1941.898804	6.41
1944.062622	4.04
1949.389893	3.40
1958.018677	44.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
70.9410248	0.32
84.7180099	0.25
86.9296417	0.50
88.9262085	2.33
100.9572144	0.47
105.5099182	0.09
106.5026245	0.52
107.1151733	0.04
112.9686737	1.53
118.8887634	2.90
125.0410614	0.44
130.9633484	1.11
141.6369476	0.07
142.8911896	3.41
149.0174408	0.88
160.9702911	7.36
179.0386200	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.13
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
160.9079437	0.45
162.0777893	0.03
174.1900177	0.03
174.9820557	0.10
178.4510040	0.37
179.0681152	3.59
180.1699677	0.23
181.0483398	0.04
203.0235596	0.03
221.0296631	1.82
222.1301880	0.34
223.1464691	0.06
232.8074646	0.03
245.2648621	0.05
249.1317444	0.06
250.0621948	0.04
250.7429352	0.09
259.0099182	0.07
263.1182861	0.10
280.4866943	0.11
281.3969727	0.20
282.1650696	0.10
311.0985107	0.05
313.3041382	0.06
319.1255493	0.03
323.1511841	1.10
324.0957642	0.43
341.0105591	3.00
342.0952148	1.75
342.7942505	0.63
355.5097046	0.07
356.2662354	0.06
361.1402588	0.18
377.1259155	1.50
378.1841431	4.60
379.1356812	9.71
379.7612305	0.12
383.3521729	0.25
384.4461060	0.28
400.3115845	0.04
413.0847168	0.19
443.0068359	0.30
485.3447876	0.09
503.2549438	100.00
504.2825317	56.17
505.2453003	13.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1014
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.0369034	0.02
110.9712524	0.23
116.9235229	0.50
120.6806183	0.01
124.3810883	0.04
128.9550629	0.65
133.7770386	0.02
134.9171753	0.47
135.9971619	0.06
137.1755829	0.01
139.0016632	0.22
139.9085388	0.01
144.9130249	2.37
146.9253693	1.09
156.9615173	0.73
162.9249573	100.00
164.6355286	0.09
166.8800659	0.02
174.9559326	0.17
178.9347534	0.06
181.0031738	0.04
183.7408142	0.01
192.9480286	9.40
199.0330811	0.03
203.1288910	0.01
204.1861877	0.01
204.8471069	0.04
207.0384064	0.04
218.1281433	0.02
219.2351379	0.02
222.1027222	0.05
223.0819397	0.02
233.0191956	0.01
234.1686096	0.01
249.1329651	0.03
264.0892639	0.01
279.9409790	0.08
281.2388916	0.05
282.9000854	0.01
288.2571411	0.01
291.2128906	0.01
295.0857544	0.04
302.0972900	0.03
309.1408691	0.07
311.1708374	0.02
313.3134766	0.06
314.0271606	0.04
318.3186951	0.07
319.2793579	0.01
322.1200562	0.01
323.2100830	0.05
326.0480957	0.01
327.3316040	0.06
332.3860474	0.01
336.5184631	0.13
337.2160034	0.25
338.1157227	0.04
346.1882019	0.06
354.9532166	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
58.9670143	3.93
60.7317352	2.28
67.0182800	0.84
68.7862701	0.21
71.0530701	3.06
80.9734039	0.61
82.9284210	0.52
84.9564056	85.41
86.9400635	18.01
92.9559021	44.99
95.0394745	0.15
95.9649200	0.31
96.9081268	0.31
98.9810333	2.77
101.1300507	0.48
108.9834442	18.88
110.8896790	34.96
112.8803101	1.19
115.0488586	4.68
126.8863373	100.00
129.1542664	0.61
137.0417633	2.18
142.9864960	2.21
145.1018829	0.13
147.2689362	0.19
153.0393219	4.28
154.9653931	6.65
162.9827271	0.28
171.0498657	23.73
173.0441132	85.91
190.9592743	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.2653
Annotation	5'''-epi-Lividomycin B
Peak:m/z	Relative Intensity
188.1997986	0.04
202.8564148	0.18
209.9722290	0.08
216.9182892	0.07
226.9747620	0.09
231.0372009	0.54
233.0389404	0.88
235.1513062	0.11
245.4086914	0.18
261.1972656	7.00
262.3676758	0.20
263.1378174	0.38
271.4164429	0.07
283.3345947	0.14
296.6206055	0.15
297.9864502	0.06
302.2692261	0.08
308.1491089	0.08
311.5515747	0.43
331.2221069	0.15
331.8374634	0.21
333.2617798	0.30
342.1799927	0.34
344.1087646	0.18
349.9365845	0.99
356.0806885	0.14
359.8983154	0.58
376.1356201	0.51
378.0738525	40.62
378.6773071	0.16
382.1896973	0.09
390.0293579	0.38
396.2467041	0.10
404.2819214	0.10
408.2448730	2.80
416.4771118	0.05
427.3073120	0.46
444.0755615	0.08
445.2189941	5.92
446.3879395	0.21
451.2155151	0.20
455.0868530	0.14
457.2345581	0.08
458.5538330	0.20
459.3227539	0.13
463.1207275	14.87
463.7677612	0.11
465.3404541	0.07
473.1976929	7.21
476.2434082	0.51
482.5008545	0.29
486.2657471	0.31
487.0635986	0.09
488.5394897	0.08
491.1304932	100.00
491.8387451	0.14
495.0915527	0.12
497.3688965	0.19
502.0429077	0.04
504.3118896	0.87
505.1174927	0.11
516.4119873	0.09
522.2007446	0.14
540.1583862	0.08
545.9545288	0.19
547.4802856	0.25
551.4136353	0.13
557.5191650	0.31
562.3567505	0.10
563.4039917	0.16
566.2235718	0.06
574.2830200	0.17
575.3975830	0.24
576.2015991	0.08
591.1397095	0.08
592.1984253	0.83
594.7315063	0.05
602.3135376	0.54
605.2745361	0.43
608.4436035	0.17
613.4614258	0.46
614.9151001	0.34
615.9652710	0.05
620.2286377	5.17
621.1807251	0.61
624.1250000	0.23
628.9877319	0.27
639.5789795	0.05
646.4606323	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.083
Annotation	3'-Methoxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
139.0792236	0.09
145.2496796	0.15
147.0708771	0.10
148.9703369	2.61
152.9347382	0.58
155.0133667	0.05
160.9842987	0.55
163.0751038	0.20
175.0669250	0.43
177.1152344	0.21
179.0239410	1.40
179.7704620	0.03
187.1202850	0.21
190.2314911	0.15
191.0711365	0.56
196.9956055	2.53
204.9700928	1.21
209.0641479	0.40
219.1453552	6.49
221.0190735	0.33
231.1878967	1.00
249.1426697	2.56
267.2557678	0.65
271.2092590	0.10
275.0880432	2.49
277.2038269	0.06
280.8743591	0.63
293.0691223	70.50
294.1565247	0.20
296.8099976	0.06
298.2770386	0.04
311.0493774	4.26
329.1640625	100.00
356.9324036	0.17
359.1755981	2.45
384.6022644	0.08
447.2928162	0.04
460.4451599	0.08
472.4458618	1.08
473.2240295	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0929
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
119.0903549	0.31
126.8956070	0.09
142.9523315	0.02
155.1361237	0.03
163.0043945	4.17
171.2475891	0.02
173.0413208	0.83
191.0174713	100.00
192.1611786	0.06
241.3912964	0.03
256.1091003	0.08
261.1658630	0.07
274.9448547	0.13
293.2175598	0.08
319.3499146	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.8479538	6.39
121.0937653	0.05
130.8977661	0.39
145.1320190	0.05
153.4819031	0.03
158.8551025	100.00
163.8133850	0.09
198.9608459	2.23
201.0204163	0.06
205.1857605	0.03
210.2159729	0.17
217.0274048	1.27
219.0064087	0.07
226.0246277	0.16
227.0281982	0.69
228.9616699	27.42
232.0762024	0.14
244.9962158	0.88
254.9117432	0.26
255.5867004	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1031.75
Annotation	Unknow
Peak:m/z	Relative Intensity
353.2131042	0.01
515.1687012	0.01
1030.8735350	100.00
1031.7113040	0.46
1032.4844970	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.81974792	0.71
97.11993408	0.37
105.3425522	2.45
111.037323	0.82
116.8563232	0.57
118.7611618	1.47
120.9464417	0.70
124.9889832	0.67
129.0821686	2.27
134.9616699	1.02
142.8190918	1.11
145.0680847	1.28
154.7684021	2.96
156.3924255	0.34
157.0887299	2.38
161.1291046	0.30
162.7114563	0.50
165.3283386	0.61
169.0122833	2.15
171.0467072	0.53
173.1364288	3.69
175.1724548	2.99
178.9521637	0.24
180.1226349	0.50
181.0831146	1.41
183.0134125	1.02
184.7979736	1.14
187.0789032	1.12
190.9861755	1.09
192.9465179	1.96
195.1451416	1.39
197.112381	2.31
205.1280518	0.94
210.0137024	0.66
211.1947021	6.25
212.848053	2.23
213.4976196	0.67
215.1782227	0.87
219.1625977	1.44
221.1233521	0.79
227.1148376	0.31
235.2361755	3.00
239.0614319	1.99
241.2368164	1.68
249.0841064	0.44
252.9835205	9.63
255.2457275	0.79
257.1627502	0.79
265.0885315	6.99
266.8945312	2.80
268.9942322	5.84
270.0527954	2.07
275.2035522	48.33
280.6864624	3.16
283.2179871	4.19
288.1369019	1.61
289.2663574	0.34
291.3515625	0.66
293.2099915	100.00
294.0655518	1.88
301.744873	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.1413
Annotation	Delphinidin 3-(6-malonylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
229.1264038	0.02
286.9229736	0.02
299.3529053	0.01
301.2848511	0.17
462.2800293	0.03
463.2982788	0.28
477.2951050	0.04
505.2687988	1.23
547.1456299	0.17
607.1498413	0.04
625.3786011	0.23
649.2953491	0.11
667.2734375	100.00
667.9231567	0.18
693.4243774	0.05
711.0378418	15.28
711.6950073	0.12
712.8862305	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.167
Annotation	Unknow
Peak:m/z	Relative Intensity
323.0643311	0.57
341.3418579	0.11
383.4929810	0.07
503.2351685	100.00
503.8460083	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.0911
Annotation	Baicalin
Peak:m/z	Relative Intensity
136.6839447	0.05
147.0724792	0.02
163.2733917	0.05
168.6784058	0.01
175.0118103	0.02
188.8283386	0.02
211.000061	0.03
214.8109283	0.05
247.2166138	0.02
255.9163818	0.02
257.2427368	0.04
263.3008118	0.02
266.2709656	0.02
267.0951538	0.11
268.2871399	0.01
271.0704651	100.00
272.08255	22.30
275.1826172	0.02
285.0827637	0.13
303.1592102	0.07
322.2477722	0.04
324.2431641	0.04
336.2597351	0.07
337.2817993	0.01
348.3188171	0.05
349.177063	0.01
351.3604431	0.01
366.7221375	0.04
367.4065857	0.03
369.1171265	0.02
376.1793518	0.05
381.2938232	0.02
382.2951355	0.03
385.2897034	0.03
391.3707581	0.07
393.5898132	0.06
399.87323	0.02
402.1221008	0.02
405.1222534	0.02
429.3072205	0.13
430.0445251	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1
Annotation	Quercetin-3-(6''-malonyl)-Glucoside
Peak:m/z	Relative Intensity
225.4587097	0.49
239.286377	0.14
252.2694397	0.08
257.0874329	0.16
258.1939697	0.72
284.1900635	0.24
292.936676	0.06
303.0535889	100.00
313.3990479	0.74
345.0424805	1.65
349.2224121	0.36
359.1743774	0.25
365.6777954	0.19
369.1153564	0.73
371.1941528	0.10
383.1921997	0.72
389.2546387	0.20
399.2941284	0.49
402.3550415	0.56
407.151062	1.79
411.4047241	0.20
421.2820435	0.20
433.2084351	0.33
452.3370361	0.79
461.8847656	0.73
463.0301514	0.46
464.0098267	0.30
470.3423462	0.62
477.3726807	0.16
478.2458496	0.43
480.2415771	0.79
488.3930664	0.24
489.2987671	0.63
491.2805786	0.12
506.045105	1.10
508.0644531	0.64
509.8330078	0.19
518.3922729	0.33
522.2929077	0.18
532.1990356	1.74
533.2279663	4.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.1075
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
152.8516998	0.15
163.1310730	0.05
219.0790710	0.09
221.1622009	0.04
241.2225952	0.03
270.1093750	0.12
283.4708862	0.06
287.0987854	100.00
288.4772949	0.05
329.3492432	0.09
331.4270630	0.21
353.3104858	0.08
355.3583374	0.10
372.3364868	0.02
395.4727783	0.17
449.0925293	13.30
491.2269287	2.62
498.9635620	0.18
517.1325073	2.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.0832
Annotation	3'-Methoxytricetin 7-glucuronide
Peak:m/z	Relative Intensity
136.8711853	0.05
146.6619110	0.12
148.9526672	4.11
154.8588867	0.07
160.2974396	0.19
160.9981689	0.39
163.2305603	0.06
174.8892212	0.08
176.8405304	0.05
179.0370941	1.13
186.8094788	0.03
189.0540161	0.03
190.9853210	0.23
196.8723755	0.89
205.1770020	0.60
219.0292358	8.51
220.9560089	0.38
223.2364960	0.06
231.0579529	1.21
239.0203552	0.11
249.1296844	0.32
275.0377808	2.06
287.2309875	0.13
293.1421814	66.57
294.2808838	0.09
311.0307617	3.81
312.8421021	0.09
314.1332092	0.18
329.1238708	100.00
339.0976562	0.15
353.3889160	0.43
359.1378479	3.12
375.3221741	0.06
403.0965881	0.07
413.2257080	0.15
445.5347595	0.03
447.6263123	0.11
454.0160217	0.11
473.1510925	1.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	778.14
Annotation	Unknow
Peak:m/z	Relative Intensity
254.0324402	0.26
272.2091980	1.76
311.1207886	0.06
324.2113342	0.01
343.2464600	0.04
355.3292847	0.03
368.2256775	0.04
386.2249146	0.16
404.2307129	0.07
434.0309448	0.05
440.2024536	1.50
466.3242798	0.36
484.1883545	1.14
487.2437744	0.14
505.1150513	0.18
536.2221069	0.07
554.3770752	0.01
580.2907715	0.15
598.3418579	0.40
616.2657471	2.15
646.6206665	0.08
648.9967651	0.18
760.0839233	0.12
778.1588745	100.00
778.8660889	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.082
Annotation	Cochinolide
Peak:m/z	Relative Intensity
92.7939987	0.07
97.1337585	0.07
98.7588501	0.14
101.0628662	0.06
107.9759369	0.11
113.0564270	0.08
122.8905792	0.25
129.0954437	0.05
139.1515045	0.04
144.8954620	0.19
146.9044495	0.04
151.1421967	0.08
154.2904205	0.12
157.0749969	0.72
158.0528259	0.03
161.0547333	0.67
167.1789093	0.84
169.0315094	2.28
171.1516266	0.21
172.0427246	0.02
173.0554352	0.48
175.0904083	0.20
177.0905304	0.06
183.0839691	1.64
184.1239777	0.23
185.1359406	1.68
187.3989410	0.04
188.3852386	0.03
191.3168182	0.05
193.1624908	0.34
195.0708008	4.61
195.9446259	0.14
197.0361786	0.37
198.1155548	1.68
200.9939575	0.13
210.0498352	0.25
211.1412506	2.14
213.1034241	100.00
214.0740662	0.19
215.1987457	0.03
217.1689911	0.13
219.7422333	0.16
221.1309052	0.32
221.8351593	0.29
225.1460114	0.04
227.1334686	2.76
228.0328827	0.76
229.1776886	2.39
237.1629181	0.31
239.0634155	7.04
241.0866699	1.24
242.0464935	40.57
247.9943695	0.06
257.1231995	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	481.1139
Annotation	Cadensin B
Peak:m/z	Relative Intensity
140.6322174	0.05
143.1361389	0.11
151.0075836	1.95
157.1744080	0.10
161.0784149	0.56
165.2887268	0.14
167.1929169	0.24
167.9542389	0.07
169.4741974	0.39
170.1100464	0.21
171.0966187	0.31
172.9955902	0.28
174.9347534	0.22
177.2260132	0.10
182.0046387	0.03
183.0829468	1.20
184.0343933	0.38
185.0892334	1.51
185.6991119	0.03
187.1031189	0.04
193.8582458	0.06
195.1088867	4.20
196.1371155	0.12
197.0103760	0.57
198.0719604	1.13
209.9324951	0.20
211.1772156	0.74
213.0318298	37.09
224.1525269	0.34
226.1448669	0.37
227.1580505	0.63
227.8605652	0.03
229.2172699	0.60
231.2379303	0.19
239.0294800	4.19
241.1053925	1.15
242.0434265	6.86
257.0698853	100.00
259.1259766	0.08
275.0509033	2.83
275.6869812	0.17
285.2792053	0.35
319.1761780	0.08
329.0850525	0.29
347.1220703	0.05
365.4234009	0.38
392.9306946	0.03
404.0663757	0.14
409.0859070	18.16
409.7723083	0.09
435.9197998	0.04
437.2236633	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.35
Annotation	Unknow
Peak:m/z	Relative Intensity
194.9060822	0.05
201.0493622	0.10
207.2687988	0.09
210.0548096	0.19
213.2196350	0.21
214.8584900	0.06
219.0051575	0.23
220.8643036	0.13
228.0453644	0.77
230.9106598	0.12
235.0864563	0.17
237.3732758	0.09
243.4327545	0.07
244.3130035	0.18
261.0744019	1.40
262.3459473	0.16
268.1758728	0.16
275.1779785	0.28
277.1821594	10.53
277.8118896	0.99
279.1563110	0.11
283.1344910	0.11
286.0369873	0.04
291.0442810	0.08
293.2638550	1.29
296.0490112	0.07
297.2445679	0.15
299.4186707	0.08
301.3584290	0.06
302.9472351	0.32
307.2710571	0.15
313.3318481	0.54
317.2862244	1.08
318.4824829	0.13
320.9282227	1.82
322.2033691	0.04
328.2727356	0.07
333.4064941	0.05
335.2531738	1.10
345.3330688	0.17
349.6986084	0.12
354.4349976	0.09
358.2333984	100.00
358.8366699	21.47
361.2705078	0.03
363.1252441	0.09
367.3270874	0.05
377.0854492	0.38
391.1603394	0.04
404.3459473	0.26
420.3555298	0.15
439.2147827	2.13
439.8291626	0.33
452.1992188	0.05
453.4235840	0.25
455.1875610	2.18
456.4735107	0.12
461.5591431	0.08
488.8829956	0.30
497.2892456	0.04
498.3679810	0.09
499.4267578	0.24
516.0272217	0.12
520.4496460	0.56
525.5930786	0.15
534.5993042	32.38
539.3910522	0.47
550.9313354	0.10
553.3712158	1.20
554.7198486	0.11
595.5198975	0.12
599.6216431	0.23
606.5159912	0.55
615.5357056	86.29
634.2925415	0.12
636.7149048	0.35
659.1967773	0.03
660.4513550	0.74
677.5363159	0.29
697.0172729	5.97
715.4338379	3.56
716.4102173	0.71
774.8696899	0.09
978.7267456	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3126
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
161.0628815	0.01
179.2194672	0.06
191.2339020	0.04
195.3624268	0.02
205.2600708	0.10
217.2722778	0.02
233.3222046	0.16
235.1600342	1.57
241.1398621	0.06
253.1313934	10.74
257.2901917	0.07
259.2828369	0.14
261.3787842	0.03
275.3767090	0.15
277.2680359	100.00
513.1370850	15.55
513.8450317	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.2985
Annotation	Unknow
Peak:m/z	Relative Intensity
154.7769012	0.12
167.1089783	0.73
169.1328735	0.12
183.0676575	6.44
183.9244080	0.46
192.0112000	0.08
194.1221924	0.06
196.9306030	0.37
199.8016052	0.19
211.0559998	15.58
212.0682678	0.79
212.9642944	0.06
228.1015930	0.12
229.2524109	0.08
238.2651978	0.32
243.0624695	0.14
243.9653320	0.31
258.1075134	0.07
263.9696045	0.33
265.4137268	0.25
269.3062134	0.16
271.0126343	0.07
279.9115601	0.16
288.5762024	0.20
293.0549316	0.12
294.2026367	0.24
295.1379700	0.15
295.9193420	1.04
298.1800537	0.06
301.2311401	0.23
303.1257935	0.57
304.0122986	0.25
307.0291443	0.09
308.1819153	1.07
310.0634155	1.22
311.3476257	0.08
312.2728271	0.73
315.7947388	0.05
324.1318359	0.43
325.2504272	0.31
331.8447266	0.23
341.0517578	0.59
342.3361816	1.28
343.0877686	0.47
345.1910400	0.30
357.8729858	0.23
358.4876709	0.89
360.3427734	0.20
363.6413879	0.09
365.3252258	0.06
367.9645996	0.15
369.2855530	30.73
369.9107056	4.81
372.4527588	0.19
373.9703979	0.15
374.9778748	0.15
376.3896484	0.49
377.4849243	0.30
379.4061584	0.37
385.6200256	2.62
386.7095337	0.40
389.6444397	0.13
392.1376648	0.26
393.1709595	0.13
394.3690491	0.08
397.8330078	0.24
401.2800293	0.63
406.3992004	0.21
407.3087769	2.04
408.8649902	1.12
410.1756287	3.54
413.3096619	3.75
414.8769531	6.51
416.2367554	0.06
417.9607239	78.38
418.9691467	0.51
420.0093384	0.38
422.6701965	0.13
424.0961914	0.24
427.9856873	3.66
430.0613098	0.24
432.1520996	0.34
435.7729187	0.13
438.8295593	0.07
442.6041870	0.28
446.0708313	0.22
451.2764587	0.09
452.3957214	0.07
455.3291016	0.94
456.3462219	2.88
457.1564636	0.84
493.0354309	0.08
520.3792725	0.05
521.6011353	0.25
522.4164429	0.35
526.8281860	0.08
535.4972534	0.68
541.4381714	2.51
542.6733398	0.91
547.4900513	0.25
574.6160889	0.12
596.2265625	0.22
602.8286133	0.07
605.7957153	0.16
618.5485229	0.87
639.3616333	0.22
640.4933472	1.57
641.8635864	0.23
670.6008911	0.07
692.6768188	0.22
700.6043091	0.28
702.5803833	0.13
719.2656860	0.84
731.7361450	0.12
737.5352173	100.00
738.5590210	22.79
739.1719360	0.13
764.5683594	0.13
767.2852173	0.15
768.0745850	0.12
782.5555420	0.07
784.7100220	0.38
809.3293457	0.14
828.6620483	1.92
829.7415161	0.74
834.7946777	0.14
835.6668091	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	Unknow
Peak:m/z	Relative Intensity
135.9410553	24.49
137.9030914	0.01
140.9601593	0.01
146.8257294	0.03
164.9131622	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.15
Annotation	Hymenoside K
Peak:m/z	Relative Intensity
133.0645905	0.13
133.8968811	0.38
134.9906006	1.88
160.9950562	1.19
165.0229492	0.29
175.9378967	0.55
177.0919647	0.12
178.1025085	0.12
179.0894775	7.01
190.9784851	0.84
194.0896912	0.89
209.0348511	10.42
219.0823059	1.49
231.1005554	0.05
232.0540771	0.05
245.9658508	0.04
248.9597778	0.47
251.1882629	0.10
257.2545166	0.07
266.1978149	1.18
268.1203613	0.05
275.0566711	0.10
276.1098938	0.04
280.3986206	0.09
286.1439209	0.08
291.1526489	0.10
293.0695496	15.46
293.9150696	0.22
300.7350159	0.47
307.1210938	0.13
311.1969604	0.48
316.8843079	0.14
323.1615601	0.17
324.2464905	0.15
325.7368774	0.48
326.4638062	0.17
331.0669556	0.81
332.1987305	100.00
333.3113403	0.58
334.5047607	0.44
335.1509399	0.13
336.1090088	0.11
339.0325317	0.29
341.3371277	0.15
346.2275085	0.10
347.2335815	4.98
353.1903076	0.93
355.2351685	0.05
357.3069153	0.24
359.4486389	0.20
367.6997986	0.19
368.3795471	0.18
369.2748108	0.05
370.4546204	0.26
375.3344116	0.14
376.1474609	0.05
376.9834290	0.57
381.4411621	0.12
390.3345032	0.20
395.1019592	0.80
404.3659058	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.9472
Annotation	Unknow
Peak:m/z	Relative Intensity
141.8724518	0.53
159.9092407	0.12
184.1412201	0.04
185.8846130	15.72
187.9623718	1.75
203.2109070	0.07
203.9230652	0.52
213.8381958	7.57
227.7188416	0.02
229.8863220	16.56
231.9606018	2.67
245.7714539	0.04
246.6361389	0.11
247.9483337	1.30
256.4223022	0.23
257.7860107	21.21
259.3898926	0.13
260.0502930	0.81
276.0162964	100.00
301.8741455	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3083
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
156.6968994	0.02
160.9733582	0.08
171.2439270	0.07
178.9717712	0.21
217.3868408	0.03
233.2608337	0.72
235.1158752	1.40
253.1915894	8.12
255.2620239	0.05
259.2668152	0.23
273.3262939	0.03
275.1849365	0.44
277.2506104	100.00
291.4993896	0.03
298.9204102	0.04
328.4968262	0.04
381.4512329	0.07
425.2570801	0.05
450.0806885	0.10
452.5518188	0.30
453.5178223	0.08
455.4471436	0.03
467.3535156	0.25
469.2154541	0.06
477.4765015	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	470.0346
Annotation	Unknow
Peak:m/z	Relative Intensity
139.8237305	0.05
141.0997772	0.02
144.0500793	0.18
145.9887543	0.09
156.9246674	0.07
157.8372192	0.10
159.8620911	0.06
162.0766602	0.04
169.8834839	0.10
171.8452148	0.03
180.6849060	0.07
182.0196228	0.05
188.1630859	0.48
189.1316223	0.02
191.8959351	0.05
195.1116333	0.14
199.9959412	0.04
202.1835632	0.09
203.9023438	0.04
206.3616943	0.13
210.7220459	0.02
214.0766907	0.06
215.7809601	0.05
217.9726257	0.73
218.9778137	0.24
220.0911407	0.42
222.3521423	0.11
223.9773254	1.05
227.1315613	0.10
227.9242706	0.19
229.1191711	0.08
230.0419617	0.10
231.7470703	0.09
235.8225555	0.11
236.6294556	0.03
240.1298218	0.04
241.1269531	0.08
242.0274506	0.58
243.1474915	0.03
245.2601318	0.08
246.0002136	0.20
247.0341187	0.28
249.9412842	0.41
251.1579285	0.14
251.8495483	0.25
255.9307251	0.16
257.9624329	0.85
259.6002197	0.26
263.8325500	0.88
264.7899475	0.06
265.9671021	1.13
267.2152405	0.02
268.0455627	0.08
270.0692139	0.03
271.9325867	0.16
274.1252441	0.07
275.5923767	0.11
277.9053345	5.86
279.0588379	0.22
282.0239258	1.26
284.4032593	0.11
285.9908142	1.41
287.2955933	0.49
288.0754089	0.48
289.9338379	0.31
291.4588928	0.03
294.3708496	0.07
296.0483093	1.62
296.8898315	0.21
300.1377563	0.03
301.2950439	0.13
302.0156860	0.24
303.9161987	1.40
305.0522156	0.08
306.1031494	2.00
307.0067139	0.09
308.0076904	0.97
309.1322021	0.03
312.0094299	0.02
317.1438293	0.22
318.0675049	0.58
320.0463257	0.76
321.7836304	0.36
323.2255249	0.06
324.2514038	0.40
327.8994446	0.06
329.9189453	1.37
331.9337158	0.48
334.0570374	0.37
335.9598083	1.32
336.9143066	0.08
339.3311157	0.64
339.9867249	0.23
341.3759766	0.14
343.9911194	0.08
346.1076355	1.78
347.1488037	0.12
348.2397156	1.41
349.9328003	4.95
350.9553223	0.04
354.1178284	0.82
357.9534607	3.46
358.6849976	0.10
360.0945435	0.47
361.8883667	4.31
363.0742188	0.28
364.0385437	1.14
364.9293518	0.48
366.2126770	0.77
367.9225464	3.00
369.0154419	1.41
370.9696045	0.81
372.0578613	3.39
374.2157898	0.23
375.8805542	0.33
376.7229919	0.12
377.8970337	1.42
380.0801697	1.37
382.0202637	0.53
385.2068176	0.52
385.8871460	0.04
388.2580872	0.27
390.0148621	1.79
391.9738770	3.84
393.3433838	0.32
394.6973877	1.40
395.8717346	0.46
398.0243835	0.04
406.1963196	0.41
408.0776062	0.42
410.0084534	8.10
410.6364136	0.11
412.0030212	0.12
414.9001770	0.13
418.5413513	0.26
420.0373230	13.97
421.2590942	0.45
422.0638733	0.82
422.9230042	0.24
423.9169922	3.78
425.1242981	0.08
426.1183167	0.32
428.1153259	0.11
429.0116577	0.05
433.1466064	0.27
434.0711975	0.20
435.6524963	0.03
436.9330139	0.34
438.0467834	5.80
439.2312927	0.11
440.0888672	0.52
445.7303467	0.14
449.9736633	0.08
452.0438843	100.00
453.3367310	0.07
454.4316711	0.11
455.1018372	0.13
457.0173950	0.11
460.9265747	0.15
461.6179504	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3297
Annotation	Unknow
Peak:m/z	Relative Intensity
266.5087585	0.03
287.2738037	0.03
311.4763489	0.02
323.2502441	0.04
402.3463745	0.05
404.1811523	0.01
435.2114258	0.02
444.3355713	0.05
446.2400513	0.01
471.3560181	0.05
472.1081543	0.09
475.2615356	0.04
481.7438354	0.05
487.6373901	0.05
490.4175415	0.04
495.5416260	0.02
507.6408691	0.04
513.3487549	0.04
517.5202637	0.07
518.1879272	0.01
523.0338745	0.02
532.5573730	0.01
562.0057983	0.03
564.4380493	0.06
592.6478882	0.01
593.5360718	0.08
597.1369019	0.04
606.2771606	0.38
607.4369507	0.06
610.4664917	0.04
611.3332520	0.02
619.4549561	0.05
624.5198364	0.05
625.3729858	0.04
626.5003052	0.02
633.1534424	0.04
634.2171021	0.02
638.4080811	0.26
639.7260132	0.02
650.4122925	1.46
651.4473267	2.18
652.4700928	0.29
657.4149780	0.03
661.1414185	0.03
669.3484497	0.10
670.6381226	0.10
674.1793823	0.02
675.8115845	0.01
682.3651123	1.23
683.4487915	0.27
687.8452759	0.04
689.5747681	0.09
701.6919556	0.03
707.5692749	0.02
711.2949829	0.05
718.3181763	0.03
719.6050415	0.01
727.4719849	0.15
729.5776978	0.79
730.7672729	0.05
731.4942017	0.04
732.5191650	0.06
733.4059448	0.03
734.8576050	0.01
737.6170044	0.03
745.1344604	0.27
745.7668457	0.35
746.7011108	0.02
755.5300903	0.53
756.5962524	0.05
757.2638550	0.02
761.8292847	0.09
762.4391479	0.05
771.5714722	0.02
773.4349976	100.00
774.4691772	8.08
787.4723511	0.28
806.3929443	46.86
807.1213989	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
157.2117004	0.55
167.9817505	0.52
172.9693298	0.73
175.06604	0.44
186.9768066	2.09
197.0907288	0.29
199.190506	0.72
213.1537781	0.32
215.1372375	0.25
217.0301819	0.51
227.0221863	0.47
229.1956482	0.93
233.230011	0.17
239.2749634	0.61
241.246582	0.64
243.0732422	0.14
245.25	0.22
251.3879395	0.12
253.2950745	2.04
255.2925415	0.25
257.1783447	3.92
262.2835693	0.23
263.3414307	1.38
269.2791443	1.00
271.1505127	4.30
272.8191528	0.56
273.5407104	0.22
277.9852295	0.43
283.1738281	0.45
285.2472534	2.97
287.2425842	0.50
295.3317871	1.07
297.4227295	2.41
299.3374939	1.74
301.3287354	0.27
303.3253784	0.56
311.3287354	3.19
312.3136597	1.07
313.3371582	3.51
314.3831787	0.65
315.2286377	1.53
320.8513489	0.96
321.4804688	1.22
323.1873779	9.37
325.4196167	0.58
329.1190796	0.65
337.248291	0.57
339.2539978	100.00
340.3809814	0.57
341.2642517	15.53
356.7138977	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.1428
Annotation	Cratoxyarborenone D
Peak:m/z	Relative Intensity
116.3007202	0.04
116.9809799	0.03
119.1458817	0.03
121.0633698	0.03
122.8211288	0.04
124.8312378	0.01
126.0715790	0.02
126.9463043	0.02
127.9348068	0.15
128.9953156	0.21
130.9718170	0.10
132.9138184	0.10
138.9773254	0.02
140.9351807	0.06
142.0190125	0.31
143.0026550	0.31
147.0334778	0.15
148.0061493	0.02
148.9317627	0.03
152.0091400	0.12
154.1042938	0.01
155.0567017	0.24
157.0558929	1.93
158.9489594	0.19
161.0343170	0.10
163.0044403	0.07
165.3607788	0.04
167.0359039	1.34
169.2319641	0.27
170.1431580	0.07
171.0644226	0.23
172.9503174	0.09
175.0861816	1.31
176.9958801	0.02
179.0887756	0.10
181.1820984	0.03
182.0164490	0.06
183.0632019	0.37
185.0051880	5.47
187.1532593	0.24
189.0598907	0.18
194.9869232	1.02
197.1392365	0.33
198.1172180	0.15
199.0866394	0.23
200.4504395	0.01
201.1513062	0.02
203.2092133	0.87
207.9710999	0.02
211.0911560	0.57
213.0151978	8.70
215.1959534	0.14
217.2654114	0.03
223.1472473	0.75
226.1000824	0.21
229.0913696	0.09
231.1481934	1.38
232.9755554	0.01
235.2576599	0.01
237.9064026	0.02
241.1359558	5.81
247.1425476	0.01
249.0758362	0.06
251.4026184	0.03
255.7512512	0.04
259.0687256	100.00
259.6697693	0.09
267.0816956	0.03
269.2040405	0.09
270.6438293	0.04
283.5231323	0.02
291.2564697	0.02
295.9398804	0.01
297.0600891	0.03
304.8413696	0.02
306.2985229	0.03
309.1348267	0.03
311.1942139	0.01
317.2980347	0.10
322.0907288	0.01
325.2051392	0.04
331.0323486	0.03
333.1804199	0.02
341.1808472	0.01
347.2482300	0.02
349.2133789	0.02
352.9964294	0.04
362.2615356	0.02
365.1057129	0.11
367.4765320	0.04
370.4501648	0.12
375.1842346	0.12
392.2178955	0.42
393.3406067	0.91
410.5922546	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.08
Annotation	Unknow
Peak:m/z	Relative Intensity
133.1835632	0.01
135.1045227	1.45
137.0846558	0.23
138.9772949	0.15
148.9481354	15.03
149.9884491	0.44
154.9385071	0.04
160.9268494	0.21
163.1106415	0.07
173.1536255	0.05
175.0141449	0.03
177.0776367	0.06
179.0641479	13.51
180.0810242	0.42
187.2065277	0.02
188.1777344	0.03
190.9222107	0.20
201.0523071	0.06
205.0189209	0.72
219.1185608	4.64
220.0970154	0.24
221.1821289	0.45
231.1727753	0.40
246.9973755	0.06
249.1858826	0.39
267.1748657	0.29
275.1249084	1.39
276.1082153	0.07
293.1022339	80.78
294.2396851	4.40
297.1262817	0.10
311.0283203	100.00
312.0512390	4.43
337.2816162	0.10
341.0426941	1.79
342.0697327	0.13
392.3448181	0.08
393.4086914	0.07
429.1018372	0.11
455.2638550	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.2705
Annotation	9-Hydroxy-10-O-D-glucuronoside-12Z-octadecenoate
Peak:m/z	Relative Intensity
142.9832916	0.12
148.7381897	0.14
161.0675354	0.35
161.8318176	0.05
163.1336060	0.74
164.1193542	0.06
165.1400452	3.93
166.1401978	0.06
167.0778046	0.48
171.0429077	0.48
175.1934509	0.25
177.1775818	0.53
178.9412537	1.36
179.5960388	0.03
181.2214966	0.05
183.2204895	0.69
185.2062988	0.24
189.2213745	1.08
190.0439606	0.11
191.1815491	0.44
193.1216125	3.96
194.1827240	0.31
197.0668945	0.21
198.1370239	0.06
199.2613525	0.04
201.2646179	0.15
202.1797638	0.21
205.3250732	0.46
207.1175995	0.07
209.1389923	2.64
209.9755402	0.15
211.2256012	0.14
217.3190308	0.40
220.7940674	0.45
223.1180115	1.29
224.3977051	0.10
227.2007599	4.11
228.2072296	0.37
229.0963287	1.36
230.0154572	0.04
245.2075806	0.47
247.2242737	10.11
248.3160400	2.17
251.9447632	0.08
253.0978699	0.06
255.1091919	0.21
256.2976074	0.41
258.2208252	0.07
263.3059387	0.05
265.3393250	0.36
266.1553040	0.12
268.4625854	0.10
269.0773010	0.16
270.3311768	0.06
271.2669067	0.37
273.2262268	6.55
274.3385620	1.09
275.1404419	0.06
277.6937256	0.04
284.9200134	0.46
287.1399841	0.29
289.1855774	0.13
289.9887085	0.12
291.2713318	100.00
292.2782593	16.07
292.9226379	0.02
293.6206360	0.11
299.5425415	0.13
300.3957520	0.06
305.4232483	0.16
307.4217529	0.29
309.2602844	33.48
310.3021545	3.62
311.2973633	0.12
313.9454956	0.08
315.2314148	0.37
316.4728088	0.04
317.2948914	0.04
327.2552490	20.95
328.4388428	4.02
333.2915344	0.92
334.2861938	0.16
349.4604492	0.16
351.4026489	0.78
352.5104370	0.17
358.0827637	0.21
369.0988464	0.25
372.6002502	0.18
375.9769287	0.10
381.0889893	0.15
382.1047363	0.08
391.3673706	0.10
392.6454773	0.04
402.2766724	0.25
418.3837891	0.29
424.3233337	0.19
429.0961914	0.03
430.2561951	0.10
436.1835022	0.09
443.5142517	0.23
444.2937927	0.07
445.2171021	0.13
447.5959778	0.23
451.8153992	0.10
454.0218811	0.84
457.2254028	0.24
462.3382874	0.21
471.4415588	6.18
472.4990540	2.32
473.4723511	0.15
491.2481079	1.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0772
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
104.8225098	0.08
107.0375519	0.05
109.0097198	0.08
113.0167694	0.06
130.1898499	0.06
131.1757812	0.06
136.9301453	100.00
143.0780029	0.31
161.0821075	0.12
174.9540558	0.07
178.9449921	0.19
193.0510559	0.36
198.2345581	0.08
202.9872742	0.72
207.0987549	0.08
227.1948547	0.13
236.1051636	0.06
237.1352234	0.08
241.1007385	0.08
253.3383179	0.11
255.0437012	0.36
263.2402344	0.39
269.0501404	0.16
271.1373291	0.58
280.0777893	0.08
281.2896118	0.30
299.3092651	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.17
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
363.1985474	10.13
525.2150269	100.00
525.8496094	0.42
613.0439453	0.07
687.5080566	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
56.8779716	0.02
84.8802109	0.49
86.8722687	1.27
100.9287872	0.08
110.8826447	100.00
128.9959259	2.35
130.9165649	1.01
147.1882477	0.03
148.9587555	0.05
154.9051361	0.13
172.9372101	17.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	447.091
Annotation	Baicalin
Peak:m/z	Relative Intensity
164.177063	0.01
174.9432373	0.01
181.0898438	0.01
182.2105713	0.08
187.3285828	0.01
222.9940186	0.01
227.002533	0.02
231.1885071	0.03
271.0539856	100.00
272.5426025	0.02
282.2151489	0.01
285.5006714	0.03
293.0560608	0.02
311.1238403	0.04
312.9855042	0.01
322.2950439	0.01
331.5930481	0.02
341.0144043	0.02
347.3563538	0.03
348.1127319	0.03
349.2194214	0.02
353.2582397	0.12
365.404541	0.03
366.2225342	0.03
367.0065002	0.01
372.3235779	0.02
385.893158	0.01
398.1479187	0.01
399.3286438	0.05
402.1491394	0.04
403.2081604	0.08
403.9583435	0.07
411.9425659	0.07
415.7045898	0.02
418.3574829	0.02
428.184845	0.03
429.1529236	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	602.1268
Annotation	Unknow
Peak:m/z	Relative Intensity
169.2905731	0.19
175.0281677	0.14
178.7371979	0.55
181.0011902	0.19
187.1441956	0.11
189.0751343	1.26
190.1802368	0.34
190.8165894	0.13
192.8938141	1.42
193.9919128	0.91
195.0036163	1.80
199.0718842	2.41
200.9516602	0.23
206.9272156	6.89
208.1345673	4.13
209.0887756	1.60
211.0393982	0.60
218.1466675	0.25
219.0177917	2.40
220.8913269	0.10
224.9619751	0.52
227.1786499	0.09
227.8273926	0.52
234.1793365	0.08
236.0103149	8.33
237.1530304	0.49
243.2528229	0.13
244.2905273	0.12
247.2283325	0.10
250.0756531	0.10
254.1941833	0.14
256.0816040	0.84
257.0251770	0.38
261.8658447	0.23
264.0954285	100.00
274.1053162	3.25
275.9273682	0.30
276.5458374	0.15
289.2228394	0.08
294.1869507	0.07
297.2286377	3.95
303.1339111	0.10
308.0470581	0.04
320.9938354	7.42
322.0785828	5.99
325.0292969	0.31
339.0091553	9.66
340.0021973	0.27
347.1534424	2.59
348.1719360	1.20
353.0379028	3.37
357.3856812	0.46
358.4454956	0.05
365.1834717	2.54
370.1245728	16.57
377.1347046	0.31
386.5543213	0.32
393.1557617	27.56
404.9520874	2.56
407.2475586	0.17
411.1845093	0.64
423.0528564	1.86
424.4364014	0.31
434.5478516	0.11
437.9541626	0.04
440.3673096	0.21
450.3082275	1.39
451.1234741	0.93
455.2940674	1.16
456.1577759	0.57
464.1445312	0.16
468.2593384	15.03
473.1609497	75.69
486.1972656	0.67
488.3259888	0.10
491.0101929	0.12
497.3469238	0.41
498.0355225	0.17
499.2312622	0.69
502.3171997	0.17
509.3048706	0.37
512.4238892	0.13
520.2857056	0.17
527.2401733	43.56
539.1526489	0.62
548.7124634	0.59
566.1810913	0.22
579.5177612	0.32
584.1452026	4.80
585.3198853	4.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0518
Annotation	5-Hydroxydantrolene
Peak:m/z	Relative Intensity
102.9819641	0.29
105.0717697	0.06
106.7413712	0.03
108.9591522	0.37
112.9401093	1.71
116.9406815	0.05
118.8468018	0.11
131.0356750	1.09
133.8564301	0.25
134.9479065	100.00
135.7702332	0.04
146.0437317	0.14
148.9215698	50.25
150.9349976	0.08
152.8788300	0.14
164.9045868	0.06
167.1217346	0.03
172.8446960	0.05
175.1558990	0.05
179.0648651	5.17
180.2226257	0.05
183.0759888	0.07
184.5873566	0.05
195.1766052	0.17
196.7091370	6.57
197.4883575	0.10
207.1203461	0.06
209.9436951	0.15
219.2565918	0.04
229.0005493	0.10
238.0524902	0.17
242.8827820	0.05
256.2376709	0.14
267.0392151	1.91
267.6464233	0.04
278.3473206	0.07
283.2487793	0.03
285.3524170	0.31
293.2956543	0.08
311.0680237	18.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
641.7016602	7.92
908.8532715	10.13
967.434082	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	780.1516
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0419006	0.32
228.2916107	0.11
230.9744110	0.34
231.9946899	1.07
236.0396118	3.52
237.0026550	0.26
250.3798523	0.08
256.1523743	1.08
257.1669922	0.25
261.1100769	0.06
264.0672913	18.96
274.1150513	1.78
275.0885010	0.24
277.0681458	0.08
279.0758362	0.12
280.3305664	0.17
288.9844666	0.09
290.3098450	0.19
297.1034241	1.35
302.1513062	0.09
303.0201416	0.30
307.1610107	4.70
307.9694824	0.32
311.1315918	0.13
318.6832275	0.04
320.4525757	0.89
321.1876831	3.66
322.0898132	1.00
327.0760498	0.34
339.0674133	4.13
341.2434692	0.16
347.0198975	1.39
348.0608521	0.76
361.2892456	0.19
365.1447144	1.74
368.4796753	0.42
369.1639404	2.84
374.9345703	1.26
376.0948486	0.08
377.2553711	0.04
386.0866699	3.60
386.9873047	0.22
393.1063232	16.08
393.9901733	0.11
398.3091431	0.07
400.0338745	0.43
405.1743164	1.53
406.1609497	0.06
411.1192627	0.31
412.1427612	0.23
418.1638794	3.28
419.2863159	0.06
422.9044800	1.59
423.5364990	0.22
426.2445068	1.09
436.2281494	0.33
440.1760254	0.25
448.1673584	0.08
450.2398071	0.93
451.2683105	0.41
455.2392578	0.23
468.2371826	11.96
471.2138672	1.09
479.1032104	0.20
486.2261353	0.35
489.1175537	30.78
508.9592896	0.50
511.2557373	0.19
515.3709717	0.09
523.4613647	0.18
525.2847900	0.80
527.1209106	0.21
537.3594360	0.34
543.2625732	10.36
547.4658813	0.63
548.1044312	5.93
554.8278809	0.96
555.4376831	0.66
558.0328979	0.05
558.6443481	0.09
561.3132935	0.06
576.1670532	18.64
581.8759155	0.31
586.3989868	0.20
600.2363892	7.28
601.3903809	0.60
612.2028809	1.13
618.2067261	100.00
618.9275513	0.16
630.1599731	1.00
631.0670166	0.19
633.9727173	0.28
651.1603394	15.23
677.2411499	0.08
687.1295166	0.23
705.2019653	13.20
717.2760620	0.27
762.2258301	1.30
762.9247437	0.83
763.5260620	0.49
780.1546021	56.24
780.8410645	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.0859
Annotation	Unknow
Peak:m/z	Relative Intensity
119.9665985	0.05
122.9829407	0.63
126.8811493	0.57
129.1314087	0.01
132.9717407	3.06
134.9190216	0.34
139.0256500	0.01
144.9240417	0.29
149.1634827	0.04
149.8723145	0.01
150.9938507	0.74
162.3406372	0.02
162.9748383	0.06
164.8287659	0.07
167.1825256	0.08
174.2337036	0.03
176.8380432	0.02
179.0218964	100.00
184.9310303	0.02
187.1066589	0.08
189.0273743	0.03
194.0133362	0.03
195.0853882	0.05
197.0567169	0.07
198.0376892	0.03
200.8470459	0.04
211.5094299	0.05
212.9450073	0.66
215.1636505	0.03
219.7907715	0.11
227.3527222	0.08
230.9718933	2.20
233.1359253	0.03
233.8037109	0.04
239.1193542	0.07
241.1244812	0.02
245.2134705	0.02
247.1452942	0.09
247.8857422	0.02
249.3386230	0.01
257.3263550	0.02
263.2740173	0.07
264.9223938	0.13
272.1116943	0.05
273.4271851	0.12
275.9928284	0.06
277.1104126	0.07
287.2870483	0.03
288.2826538	0.02
288.9422607	0.03
294.4092102	0.01
295.2526550	0.02
303.2129822	0.03
306.9997559	0.20
309.2279053	0.06
311.0479126	0.03
311.9281616	0.01
319.3412476	0.03
320.9710083	0.18
326.8887329	0.02
328.2340393	0.02
336.3853760	0.28
337.0552063	0.12
338.0881042	0.05
339.1856079	0.02
341.1925354	0.22
345.0310669	0.28
346.1218872	0.74
347.2966003	0.02
352.3549500	0.03
353.2240601	0.03
357.3143005	0.03
360.2594604	0.04
362.8816223	0.04
365.3804932	0.04
367.0279846	0.09
369.3366394	0.02
379.5975342	0.06
382.4862366	0.05
383.5196533	0.10
390.9653625	0.39
397.6135254	0.31
408.0894775	0.49
408.9224243	2.16
409.8017883	0.23
412.3350830	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	442.1028
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9794083	2.66
128.0717468	1.63
144.7619324	3.01
162.8595276	3.39
211.1076660	1.56
234.7894745	0.85
250.4331360	1.08
271.0101013	22.56
277.7062683	0.85
280.0912170	13.72
289.0139160	0.90
291.3036499	0.59
308.0161133	0.39
310.1842651	1.27
318.9922485	0.43
328.5657959	0.66
331.0754700	0.87
335.9873657	0.70
336.8561401	1.20
343.2181091	1.45
352.1601562	100.00
353.3275146	0.29
355.4106750	0.60
360.5386353	5.50
361.1752930	21.62
379.0366211	9.75
380.0155640	1.00
395.8883972	1.17
396.7960510	1.29
539.2336426	0.67
541.1607056	6.94
542.1365967	2.05
559.0740356	5.16
721.0566406	5.91
721.9280396	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.06
Annotation	Calcium Gluceptate
Peak:m/z	Relative Intensity
137.1038055	0.03
140.0185089	0.05
141.0047455	0.11
173.2549896	0.02
178.9735260	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	731.1422
Annotation	4-Deoxy-4-thio-alpha-D-digitoxosyl-calicheamicin T0
Peak:m/z	Relative Intensity
205.3320465	0.40
229.0625000	0.07
230.7185669	0.13
249.0914917	0.05
255.0433350	0.21
259.3576660	0.21
271.2412415	0.12
298.5730286	0.24
303.1571655	21.66
315.1377563	0.09
327.5595093	0.24
330.2362671	0.08
343.3535767	0.12
345.2028809	3.08
355.3356323	0.23
361.1480103	0.13
365.2298584	0.15
369.3841553	0.49
370.4472656	0.24
372.0897827	0.25
373.1946411	0.99
387.1096191	0.25
393.2153931	0.23
395.2169800	0.13
403.2271118	0.12
411.1015625	2.02
420.2274780	0.06
421.4320068	0.26
428.3044434	0.06
429.1964111	0.06
437.2249756	0.16
447.2628174	0.16
453.0186157	0.56
454.1359253	0.04
465.0856323	1.74
471.3047485	0.18
481.3019409	0.21
483.2085571	100.00
483.8426514	0.30
489.2814941	0.11
506.0636597	0.07
507.2555542	0.74
515.1410522	1.72
520.1941528	0.11
525.3853149	0.91
533.2322388	5.55
541.0682983	0.08
551.2100830	13.28
573.1057739	0.25
574.3904419	0.10
597.4253540	0.18
598.7039185	0.32
599.6189575	0.10
612.9547729	0.09
655.9710693	0.04
658.6030884	0.29
667.2585449	0.07
691.1109619	0.84
694.6013184	0.28
695.2830200	0.40
704.6329956	0.11
712.6642456	0.65
713.4072876	1.11
714.1394653	0.05
731.0593262	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	167.09
Annotation	3-(4-Methyl-3-pentenyl)thiophene
Peak:m/z	Relative Intensity
70.9365540	0.02
80.8105316	0.01
96.6329040	0.02
103.0274963	0.03
119.9576874	15.10
120.9237671	100.00
121.6703491	0.01
125.9162903	0.09
131.9076538	0.26
138.2451935	0.03
140.8703003	0.01
146.4724731	0.02
148.9096222	1.06
149.9706726	5.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	279.0494
Annotation	Nepenthone A
Peak:m/z	Relative Intensity
84.9142151	0.04
90.9706421	0.02
92.9286804	0.03
93.8891296	0.04
94.9811706	0.05
98.8783112	0.02
101.0257416	0.03
104.5710068	0.02
107.0747070	0.04
108.9594040	0.02
110.6490173	0.01
118.8604813	0.17
119.8955231	0.04
125.0647736	0.02
129.1562195	0.05
133.1334534	0.06
134.9333191	0.02
137.0600281	0.02
138.9404297	0.02
145.0607910	0.02
146.8859558	100.00
148.9222717	0.63
152.1164398	0.06
160.8338013	0.04
162.8834229	0.02
167.0514832	0.15
169.1175385	0.02
177.2744446	0.02
178.9486237	0.04
183.1806030	0.02
188.9289398	0.02
196.3451538	0.01
197.0900574	0.06
199.2037048	0.02
200.0226440	0.11
201.0199890	0.13
201.9616089	0.01
204.3758240	0.29
204.9792175	1.05
208.1963806	0.05
215.1580200	0.08
219.0617371	0.46
220.1111450	0.01
220.8823547	0.04
223.1644287	0.11
225.2781372	0.01
229.1805725	0.02
233.0318604	0.20
234.9580078	0.10
236.2156982	0.24
237.0153809	0.01
238.1229553	0.03
243.5106506	0.02
247.1702271	0.05
251.1150513	0.30
252.9585266	0.05
256.5549622	0.10
259.6518555	0.02
260.3118591	0.14
261.1515503	0.55
263.1666870	0.02
266.7322388	0.02
269.9049683	0.10
279.1179199	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.8776
Annotation	Unknow
Peak:m/z	Relative Intensity
186.9925385	0.08
200.1310425	0.03
214.9626770	0.10
215.9468384	0.05
228.9252014	0.03
245.0144653	0.20
245.9548035	0.11
246.8762207	0.17
273.0572205	4.07
274.0642700	1.19
274.8432617	0.07
289.0068054	9.62
290.0620728	1.43
305.4479980	0.02
346.7560425	0.02
387.0037842	1.98
388.0673218	0.87
402.9582520	33.61
403.9784546	8.73
444.1096191	0.04
469.9371948	0.05
484.5692749	0.03
485.5065918	0.07
501.0338135	0.53
501.9174194	0.29
515.1473999	0.25
516.9124756	100.00
517.8648071	34.07
518.5062866	0.09
519.1627808	0.07
520.0438843	0.03
539.0897217	0.14
542.4765625	0.04
576.1195679	0.04
584.8540039	0.54
585.9771729	0.05
588.9808350	0.04
598.7439575	0.02
613.8478394	0.04
631.9439697	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.27
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0476685	0.04
168.8241119	0.08
183.0172424	0.03
184.2732849	0.03
201.0991821	0.06
207.0980225	0.07
211.2021942	0.07
223.0579071	16.64
235.0843201	4.29
240.8873291	1.80
249.1850586	0.04
251.0626221	0.09
253.0717163	100.00
267.1957703	0.06
269.0146179	0.13
269.9579773	0.99
270.7765503	3.96
271.4579468	0.10
276.0428772	0.07
281.1490173	0.65
293.9512329	0.19
295.1264648	0.11
301.0229797	0.13
307.3858337	0.05
320.0942383	0.06
327.1552734	0.02
335.0898132	0.11
336.1433105	0.03
337.1289062	0.10
338.1646423	0.11
347.3771362	0.08
352.2565308	0.04
353.3774414	0.11
357.3258362	0.02
378.3837891	0.14
379.1551819	0.04
383.2152100	0.09
389.4641418	0.07
399.6239319	0.02
403.7323608	0.07
407.2897339	0.15
420.4679871	0.04
421.2024841	0.09
423.2894287	0.09
425.0517883	0.11
431.2825928	0.33
432.1553040	0.03
437.0947571	0.22
449.2870789	1.18
450.2495728	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.8
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0236511	0.06
218.8423004	2.09
259.1048584	0.10
274.0127258	0.02
295.3554077	0.02
302.8652344	100.00
310.7859192	0.03
340.2981567	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9713
Annotation	Unknow
Peak:m/z	Relative Intensity
129.1689758	0.01
137.2710419	0.03
155.2445374	0.01
158.8820953	0.02
172.7835846	0.03
179.8064575	0.02
198.8832397	0.08
201.2136841	0.12
202.1404724	0.23
203.0321350	0.16
226.9939270	0.23
228.9117737	0.05
243.0232239	0.24
245.0133362	0.18
247.0434265	0.10
253.1168823	0.03
254.8032227	0.04
259.9412231	0.06
260.9373169	0.04
262.9153137	0.03
264.8936157	0.05
269.0421448	0.03
269.8022461	0.04
271.0220947	0.88
272.9669800	0.06
277.2326050	0.01
286.4997559	0.11
287.1458435	0.45
296.9995117	0.05
303.1710510	0.01
304.0870667	0.84
305.0572205	3.07
307.1134644	0.46
310.4788208	0.01
314.1541748	0.04
314.9423523	1.50
315.5948486	0.01
317.1037598	0.02
318.8096619	0.03
320.7161865	0.04
329.1516724	0.02
329.8263550	0.14
330.5629578	0.03
331.1639404	0.13
332.0005188	0.48
333.0367432	4.73
333.7752380	0.03
335.0914001	0.78
340.9416504	0.04
342.3170471	0.03
347.9492798	1.41
348.9710388	0.84
353.0925293	0.17
357.6747742	0.02
359.0685730	1.05
361.0538330	0.04
374.9703674	0.01
376.3307800	0.35
377.1326599	1.87
379.1717224	0.07
385.1039124	0.21
394.0265808	100.00
395.0378723	19.03
401.9245911	0.14
403.0244446	5.63
420.9668274	47.37
421.5902405	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.0933
Annotation	Taxifolin 3-apioside
Peak:m/z	Relative Intensity
123.0429382	0.04
129.0936584	0.05
135.0659943	0.18
137.0067596	5.40
138.0658875	0.57
142.8017883	0.03
145.1493683	0.09
147.0076599	0.05
149.0295258	0.02
150.8824463	0.14
151.8916473	2.78
152.9235687	6.42
154.0443115	0.35
161.0332184	0.18
162.0561371	0.05
162.9955292	0.55
165.0576477	0.15
167.0861664	0.05
172.0987244	0.02
175.0604858	0.12
176.9877777	0.08
179.0671997	1.14
180.1544952	0.07
180.8831635	0.08
189.1809998	0.18
191.0733032	0.01
191.9354095	0.02
193.1424561	0.10
195.0815430	0.09
203.0225525	0.06
204.9313049	0.06
207.1563110	0.41
208.2497101	0.12
209.1379395	0.53
211.1936798	0.04
213.0356750	0.08
218.9141235	0.20
220.0979156	0.02
221.4326782	0.24
223.2251282	0.02
224.9684448	0.21
230.6338196	0.03
237.0594788	0.29
238.0230255	0.05
239.1437073	0.15
253.0659790	0.09
255.0327759	0.05
262.4263306	0.05
267.1458130	0.19
269.0928650	0.04
270.9655762	0.13
277.2225952	0.06
279.1258545	0.45
281.2809143	0.15
282.3530884	0.10
291.3931274	0.12
293.2348633	0.05
295.1161804	0.17
297.1121216	100.00
298.1190796	10.97
303.0779114	0.07
304.1334229	0.10
309.3316956	0.02
315.1223145	25.13
316.1835327	3.47
320.0406494	0.03
326.4860840	0.06
328.9718018	0.19
330.0706787	0.02
331.3955383	0.03
332.9444580	0.06
335.1068726	0.04
339.3153076	0.06
343.3110352	0.06
347.2994995	0.09
349.0330811	0.04
353.1997681	0.07
360.2355042	0.05
361.1184692	0.04
362.2772217	0.10
364.0793457	0.04
364.8686523	0.10
373.4125061	0.04
375.5104675	0.15
390.1292725	0.05
391.5210876	0.19
393.3392639	0.03
395.0318909	0.02
398.0672913	0.13
399.2104797	0.02
399.9774780	0.10
405.5354309	0.01
415.3142700	0.10
417.2315979	0.20
418.1984558	0.24
437.3358765	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.0863
Annotation	Kaempferol-3-Glucuronide
Peak:m/z	Relative Intensity
141.9295654	0.01
269.3063965	0.02
283.1169128	0.03
287.0513306	100.00
298.9355164	0.01
303.2302551	0.03
311.1227112	0.03
315.4841309	0.02
375.1159973	0.03
381.0540466	0.04
427.4476929	0.02
446.1114197	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	822.198
Annotation	Unknow
Peak:m/z	Relative Intensity
229.3188477	0.22
230.9920502	0.30
232.0388184	0.21
236.0616455	1.48
237.0742493	0.21
238.1244354	0.10
241.9581909	0.06
244.2008362	0.19
247.1193542	0.07
248.1258850	0.08
251.0767212	0.16
254.0733643	0.06
256.2385864	0.98
257.0202332	0.41
261.0087280	0.18
264.0088806	26.38
265.0854492	2.02
268.0199890	0.14
274.1002502	1.81
275.2428589	0.23
276.4748535	0.11
277.2985840	0.10
281.2336426	0.09
283.1540833	0.13
286.0830383	0.04
290.2266235	0.35
292.9363403	0.14
297.3054504	2.88
298.0788574	0.09
302.1046753	0.07
307.2168274	8.64
308.2006531	0.79
310.3239136	0.05
311.0032959	0.04
319.1508179	0.96
320.0574341	0.53
321.1264954	2.02
322.1871948	1.03
323.2136841	0.10
324.1541443	0.09
335.2231750	0.12
337.1760254	2.24
337.8847046	0.07
339.1725464	5.20
340.0761414	0.77
342.9412231	0.05
344.2968445	0.13
347.2000732	3.06
348.2832031	1.79
349.3866577	0.12
352.3908081	0.12
357.2241821	0.54
364.9951172	1.83
366.0363159	0.39
367.4559937	0.06
369.2026978	0.05
372.5252686	0.18
375.2313232	0.95
379.1554565	0.30
386.7423706	0.06
391.0886230	0.16
393.1090698	22.27
394.1471558	3.28
399.3632812	0.25
400.0855713	0.27
401.1801758	0.13
405.1371460	2.28
406.0564575	0.67
411.1256714	0.70
416.0026245	0.47
418.2254028	4.42
419.2757568	0.91
420.0933838	0.11
423.0180664	1.11
424.1452026	0.48
426.2435303	1.95
427.1218262	0.26
428.1952515	0.18
428.9086304	0.15
435.1309204	0.05
436.1950684	0.54
437.1951904	0.09
450.0894165	0.91
451.1734009	1.24
456.3158569	0.13
468.2474365	18.71
469.2976685	1.42
471.0371094	0.19
478.2617798	0.14
480.5095825	0.16
481.5348511	0.12
484.1034546	0.43
486.4150391	0.18
487.2968750	0.29
496.4998779	0.10
499.2563477	0.17
501.0285645	0.09
509.2921753	0.15
511.2389526	0.10
513.1737671	1.92
514.0728760	0.34
515.0474854	0.26
516.0626831	0.15
519.1652832	0.19
529.0701294	0.31
531.1591797	14.01
532.1506958	1.59
537.0909424	0.34
550.2244263	0.04
555.0563354	0.76
562.2241821	0.22
567.4208984	0.53
568.3245239	0.29
572.2890015	1.41
573.2579956	0.12
575.2650757	0.19
577.1004639	0.08
579.4710693	0.18
580.4873657	0.12
585.2239380	4.74
586.1930542	1.05
590.1449585	3.47
591.1478882	0.61
596.3605347	0.28
597.4036255	0.25
598.4708862	0.05
600.2028809	1.11
601.3450928	0.08
604.1544800	0.06
605.7284546	0.05
612.4967651	0.12
613.1942749	0.29
618.1741333	11.30
619.2836304	2.57
624.4171753	0.34
625.1770630	0.10
630.1831665	1.29
631.2530518	0.03
642.2601929	6.34
643.2648926	1.90
644.2584839	0.27
655.3793945	0.07
658.2423706	2.31
660.2456665	75.24
661.2307129	15.41
661.8410034	0.08
675.2129517	25.02
676.2136841	6.42
676.8433228	0.03
683.0021362	0.12
690.5689087	0.13
693.1787720	62.01
694.2053833	13.20
694.8413696	0.11
696.8181152	0.43
711.1854858	0.09
713.6214600	0.05
719.3775024	0.20
729.3389893	12.52
730.4842529	2.14
737.8742065	0.24
741.0692749	1.05
747.3639526	51.13
748.4232178	14.22
772.6841431	0.21
776.1894531	0.17
778.0617065	0.45
779.4091187	0.34
786.7035522	0.37
787.4940796	0.80
804.2708130	59.85
805.3124390	20.86
823.2594604	100.00
824.0646973	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	406.1653
Annotation	O-Methyl-waltherione A
Peak:m/z	Relative Intensity
124.0403137	0.09
126.1879272	0.13
127.0458069	0.69
127.9880066	5.66
134.9272156	1.37
143.0000916	10.78
145.5286713	1.40
146.1890564	0.82
147.7768860	0.11
153.1419220	0.13
154.8253021	0.27
166.1288452	0.19
167.0525818	2.85
170.0936279	1.13
170.9414062	2.83
174.9958801	0.71
176.0266113	0.52
179.0248413	20.18
181.0513306	0.20
182.8714294	0.05
185.0860596	0.46
192.1080933	1.53
193.0779419	0.30
197.0275879	1.00
210.0814056	14.12
220.1242828	0.17
226.2070160	0.35
228.1314697	0.49
234.9954224	0.51
236.1408691	1.58
237.0918579	0.06
244.1055603	0.31
247.2477112	0.11
248.8947754	0.87
251.1813049	0.30
254.0659485	100.00
254.7022705	0.40
256.5710754	0.12
258.9530945	0.08
260.2222595	0.49
272.1586609	57.40
273.2256165	0.48
275.2504578	0.26
277.2309570	10.82
289.0678101	0.14
290.3344421	0.20
306.1564331	3.23
307.1021729	4.12
308.0468750	4.80
309.8569946	0.17
320.9786682	0.41
327.5574646	0.14
331.0153503	0.21
333.3706055	0.14
341.3176270	0.22
344.1539307	0.14
345.0195312	0.31
346.1281128	0.20
346.7987366	0.05
351.3359375	0.12
357.1701355	0.29
358.1488342	0.06
360.1718445	0.67
362.2549133	0.07
363.0461121	0.50
369.1194763	0.11
378.2025452	0.15
385.4074402	0.16
388.1996155	33.05
389.1094971	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	658.1555
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0542603	22.21
192.9942932	22.93
194.0676270	1.82
196.9684143	0.16
206.0835266	0.19
210.0199432	1.61
210.9848328	2.63
212.0672607	0.42
213.0469666	0.06
220.2522278	0.17
228.1062012	0.09
234.2654114	0.41
235.9757996	0.30
237.2150421	0.06
239.9382324	0.04
245.0668793	0.59
250.2187500	0.29
254.1619720	8.03
255.4051361	0.27
258.1465759	0.07
260.2197266	0.13
260.9231567	0.11
268.4533081	0.15
272.1307373	29.58
273.1489258	2.35
275.5085754	0.29
276.1405334	0.08
288.1518555	0.13
293.1911621	1.77
294.1698608	0.40
296.1798706	0.07
302.2118530	0.06
303.1940918	0.93
306.1545410	1.56
307.4023438	0.15
309.1074829	0.05
312.2537842	0.05
319.2453613	0.87
320.0873718	0.47
321.3933105	0.08
322.1472168	1.55
323.3185425	0.10
337.1116943	4.67
338.3582764	0.48
340.0863953	2.00
340.9111938	0.13
351.1312866	0.07
353.1748657	0.08
360.5355225	0.16
361.4317017	0.28
366.2197266	0.05
371.2832031	0.16
373.2391357	0.33
379.1047363	4.61
380.2951660	0.91
385.1103516	100.00
386.2273560	13.66
391.1779785	0.61
404.1537476	0.85
405.1088257	0.39
421.9429321	1.61
422.5982666	0.24
434.2119141	0.27
437.4547729	0.26
440.1355591	0.27
446.3858032	0.15
448.2105103	5.54
449.2376709	0.72
457.6303101	0.19
461.5994263	0.05
466.2016602	56.37
467.2297363	11.50
467.8408203	0.09
483.2567139	0.06
484.4318237	0.17
494.3656616	0.11
495.8894043	0.23
529.1843872	13.73
530.3063354	1.64
554.6509399	0.17
563.3575439	0.18
574.6751099	0.16
612.4807129	0.41
615.2360229	0.26
640.2218628	4.60
641.3801880	0.87
659.2854004	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9753418	3.99
171.1791382	0.05
175.0667877	0.05
198.9819641	0.82
216.9934845	0.14
228.9814148	1.49
246.9600830	0.02
273.0357361	72.36
274.0135803	0.06
288.9797363	0.07
385.0560608	0.30
386.9148560	100.00
426.1717224	0.27
426.9708252	0.08
429.2428284	0.13
440.2763672	0.03
452.0136719	0.05
454.9611511	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1017
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
147.0227661	0.01
153.0682678	0.01
166.1544189	0.01
176.8421478	0.01
209.1527557	0.00
216.1332703	0.01
217.0594635	0.02
222.9050598	0.01
231.0995789	0.01
261.0443115	0.00
267.2509766	0.01
280.4265442	0.00
285.3437195	0.05
288.3641968	0.02
295.2038269	0.00
300.0873413	0.01
303.1076965	100.00
304.1390991	17.59
305.0266724	0.01
325.3315735	0.01
327.8644714	0.01
329.0394897	0.00
331.2489014	0.00
333.2112427	0.02
337.1628723	0.09
355.1571045	0.01
357.2672119	0.01
363.1242065	0.03
365.1134644	0.01
366.3650513	0.00
384.2907410	0.03
385.1547852	0.01
391.1217041	0.02
392.4671936	0.01
396.9515381	0.01
398.5281982	0.00
399.1815491	0.02
403.5227356	0.01
404.3982849	0.02
405.0912476	0.01
406.0978088	0.01
418.5803528	0.01
422.2441406	0.00
429.2456055	0.01
430.3110352	0.02
430.9649963	0.02
437.9565125	0.01
447.2524109	0.12
448.2672424	0.05
450.8308105	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.2058
Annotation	Glochidacuminoside C
Peak:m/z	Relative Intensity
130.9755859	0.55
134.9791565	2.80
138.8698883	1.82
144.8611298	0.71
147.1440735	4.17
149.0440063	8.51
151.0826721	6.77
158.0248718	0.73
163.1263428	4.21
173.1063843	7.95
191.1130066	41.92
209.0909729	100.00
231.0991211	1.22
233.0352936	1.32
282.9860535	2.17
295.2521057	0.51
312.7615051	1.15
325.5237427	1.32
326.9293213	0.37
369.2832336	1.06
396.3766174	1.32
403.1647339	4.80
411.4587097	0.77
420.3332214	1.54
421.1802673	12.65
437.3576355	1.27
438.4608154	2.96
439.1581116	12.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	444.2006
Annotation	Unknow
Peak:m/z	Relative Intensity
125.5408325	0.08
128.0398865	0.06
129.2583618	0.14
130.0950623	0.18
132.0306244	0.15
133.0358887	0.24
134.9602051	100.00
136.0211182	10.50
137.1204224	0.18
140.9514618	0.11
141.9061890	0.03
142.8438416	0.16
145.0034180	0.80
146.9208069	0.92
147.8727417	0.32
149.2230225	0.28
149.9774628	1.35
151.0126190	0.30
151.8639679	0.35
154.0438995	0.43
154.9407654	0.63
157.0880127	0.12
158.1248169	1.31
159.0776978	1.58
159.9490204	0.19
162.0359802	0.94
163.9727631	26.17
165.0378418	3.55
167.2495728	0.57
167.9713440	0.78
169.1520996	0.09
170.0890808	0.62
171.0334167	4.74
172.2065582	0.06
173.0164185	0.18
175.1022034	0.08
176.9840698	0.11
179.0983887	0.33
180.1039886	0.05
181.1971741	0.10
183.0607147	3.22
184.0859985	1.20
185.1751709	1.47
188.6198273	0.82
189.7309875	1.34
192.3055115	0.13
193.0978394	0.06
195.0351562	6.18
196.0665588	1.10
197.2181396	0.50
198.3163452	0.61
199.1264343	1.12
200.0531464	0.55
200.9885406	1.47
202.1730194	0.31
202.9814758	0.60
204.0370026	0.05
205.3613281	0.27
206.0419922	0.07
208.9707031	0.23
210.4032898	0.40
211.1877136	0.50
213.0610199	8.70
214.1318970	2.00
215.1083679	0.66
216.0610809	0.15
217.2102356	0.80
218.1817474	1.03
218.9918518	0.17
221.1494446	0.32
222.9048920	0.10
224.2500000	0.32
227.2606506	1.68
228.1956787	3.73
229.2241974	2.21
230.4484253	1.75
231.1826477	14.54
232.1187439	1.21
234.9611206	0.11
236.1532288	0.15
237.2803040	0.82
237.9701843	4.42
239.2290344	0.09
241.1814270	0.70
241.9769592	0.30
242.9938049	0.10
244.0017090	0.80
244.9844971	0.98
246.0978088	2.01
247.0744019	0.15
251.0682068	0.14
252.0778503	0.37
253.7893982	0.38
255.3574829	0.13
256.2180481	0.43
257.2854614	0.83
258.1514587	0.43
259.1250916	1.09
259.7966003	0.06
263.1019592	2.19
264.0849609	4.53
265.1590576	0.63
266.2710876	0.08
268.3220825	0.48
269.1609192	0.59
270.1892700	0.55
273.3165588	0.28
274.0699158	0.46
275.1180420	0.35
276.1072388	0.29
277.2160950	0.13
280.1367188	0.10
281.2627869	0.38
282.1851196	0.36
283.0595093	0.11
286.9133606	0.08
292.2582703	1.68
293.0413818	0.61
303.5233459	0.22
305.2162476	0.12
309.6342163	0.11
313.1629333	0.03
315.4547729	0.39
317.4194641	0.15
318.3428040	0.29
319.5086365	0.18
323.3988647	0.11
325.2438354	0.28
326.2801514	0.27
327.2777100	0.71
329.3452759	0.05
330.2580566	0.26
332.3798218	0.16
333.2117004	0.08
334.3453979	0.52
343.1724243	0.06
344.3113403	0.73
345.3927002	1.55
346.3529968	4.49
347.2497559	0.77
350.2033691	0.23
354.7474670	0.18
355.4195557	0.18
357.4198914	0.16
360.4204102	0.49
362.1392822	0.80
363.1625977	0.40
364.3352356	4.79
365.1924133	0.99
371.1462097	0.11
372.3172607	6.40
373.2367859	1.09
373.8575745	0.33
374.4705505	0.09
378.2021790	0.85
380.2751770	0.74
381.2506409	0.26
382.3887939	0.53
383.3144531	0.07
383.9959717	0.51
385.5264282	0.23
386.4374390	0.28
389.0645447	0.06
390.2205505	6.36
391.2107239	2.65
394.3200684	0.29
396.4171143	0.28
397.1054993	0.18
398.2944336	1.69
399.3342896	0.96
408.3317261	14.91
409.4019470	4.07
416.3228455	5.91
417.3534241	0.71
426.2436829	35.19
427.3997803	8.89
429.2171021	0.15
455.3052673	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	699.3541
Annotation	Hirsutatin A
Peak:m/z	Relative Intensity
203.0290527	0.29
245.0763702	0.04
259.0913086	0.31
261.2725525	0.12
275.1690674	0.26
279.2035522	0.11
293.2237854	0.13
304.8057861	0.32
305.6123047	0.08
320.7330933	0.04
325.1722717	0.21
328.9132690	0.08
335.3397827	0.12
345.3817749	0.14
347.1660767	2.02
354.9627686	0.03
358.9296265	0.70
360.0454102	2.35
360.8871460	0.72
362.7901611	0.05
365.1384277	5.18
365.7642212	0.06
366.4463501	0.03
375.3123169	0.33
396.2673340	0.07
407.2891846	0.06
421.3438110	1.63
422.3563232	0.05
428.1720581	0.05
440.0439453	0.11
441.8193359	0.27
511.2395020	0.03
524.6123657	0.14
535.6365356	0.14
537.3843384	100.00
538.4566650	2.78
555.4733276	0.08
556.3903198	0.06
557.0646362	0.08
579.3479614	0.10
589.6414795	0.27
591.7866821	0.05
603.6314697	0.13
609.4865112	0.13
617.1820068	2.20
618.1123047	1.52
625.2383423	0.03
643.5518799	0.24
653.2961426	0.17
680.7342529	0.17
681.3599243	0.06
700.5314331	19.94
701.2963867	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.1066
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
164.8561249	0.02
188.7401123	0.04
191.8865662	0.01
213.2002716	0.01
230.9803162	0.08
241.3467102	0.02
245.4342957	0.04
253.2720795	0.03
258.1015015	0.02
274.9826660	0.02
287.0471191	100.00
287.7026978	0.16
311.2208252	0.34
313.2759399	0.01
327.0629883	0.02
329.0981445	1.92
335.1314087	0.02
353.2464600	0.31
360.5117798	0.02
365.3422241	0.06
375.1760864	0.01
383.1401367	0.01
390.1155396	0.04
395.3192749	0.50
413.1497803	0.06
431.2340088	0.06
436.6949463	0.02
448.9998779	0.03
455.3485718	0.03
473.3210449	0.06
480.8295288	0.02
491.2236328	0.06
499.2028198	0.70
517.2096558	1.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2732086	0.12
158.9343567	5.27
160.0423889	1.50
198.8948669	1.36
200.0569153	0.29
217.2959137	0.05
228.9623718	1.55
230.1363373	0.25
270.9579163	0.09
272.9762268	71.76
273.9499817	30.63
275.1245117	0.16
371.1075745	0.08
385.9416199	1.26
386.9618835	100.00
388.0158997	64.88
428.1143494	0.07
444.8819580	0.11
448.1020508	0.04
456.2526245	0.04
457.0549011	0.14
472.7682800	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1019
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
159.0495605	0.03
165.0156555	0.03
230.9779053	0.09
252.3701477	0.03
256.9975586	0.03
275.3088074	0.01
285.2861938	0.03
301.1479187	0.05
303.0984497	100.00
304.3020020	0.06
321.0865479	0.05
327.1229858	0.34
340.1663208	0.02
345.1442261	2.89
369.1654663	0.60
370.4395752	0.03
373.9877319	0.02
387.1674805	0.03
393.2626343	0.04
399.3614502	0.01
411.2235718	0.81
418.9158325	0.04
420.4424438	0.03
447.1168823	0.09
453.3961792	0.06
465.1582642	0.11
467.8768921	0.03
471.1629028	0.05
489.1546021	0.14
496.0256348	0.03
497.2352905	0.07
503.6693115	0.02
515.1593628	0.78
532.5851440	0.11
533.2388916	2.82
561.6436157	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1038.4767
Annotation	Unknow
Peak:m/z	Relative Intensity
601.1165771	0.07
920.7757568	0.20
1001.7061770	0.08
1020.3751220	0.13
1038.6035160	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.1832
Annotation	Cyanidin 3-(6''-p-coumarylglucoside)-5-4''',6'''-dimalonylglucoside)
Peak:m/z	Relative Intensity
254.6880188	0.05
269.0772705	0.05
271.0170898	0.29
297.3871155	0.02
300.1642151	0.10
301.0640259	7.80
313.0870972	0.02
315.4741211	0.02
317.2540894	0.02
322.3179321	0.06
324.9804077	0.07
341.1810913	1.21
343.0964355	0.79
355.2547607	0.11
367.4321594	0.08
369.2167053	0.02
373.1447449	0.10
403.4777832	0.03
445.1875000	0.21
463.1452637	100.00
463.7685547	0.77
473.5390015	0.03
523.0833740	0.09
556.2173462	0.17
569.4381714	0.05
583.3306885	0.02
597.4091797	0.04
632.6320801	0.04
633.4104614	0.18
681.4108276	0.06
693.4865723	0.08
700.2699585	0.04
703.2797852	0.08
729.2739868	0.07
731.5553589	0.07
747.4563599	0.08
765.3052368	0.35
775.4358521	0.04
798.4630737	0.02
806.2778931	0.07
812.3532715	0.27
839.3900146	0.03
851.4834595	0.04
865.2052612	0.10
879.6832886	0.14
883.4765015	0.02
895.4668579	0.03
908.7940674	0.11
909.4280396	0.07
926.9181519	8.61
928.0929565	2.10
928.8002319	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.2941
Annotation	Unknow
Peak:m/z	Relative Intensity
223.3146210	0.11
237.3548279	0.08
239.1180115	0.02
241.0364075	0.02
253.2754059	0.15
255.4594879	0.19
257.2180176	0.01
258.7236023	0.03
267.2152100	0.57
279.0414124	0.02
281.1680908	0.03
292.9641418	0.28
299.2081604	0.06
300.1018677	0.01
311.3963318	0.09
312.2029114	0.05
327.2328796	0.57
328.1526489	0.07
329.2532043	0.26
331.2452698	0.05
355.1234131	0.04
367.2862549	0.08
376.3916016	0.03
378.3345947	0.08
392.0604858	0.03
394.3865356	0.46
406.3759766	0.11
414.3720093	0.04
418.4124756	0.03
419.2305298	0.05
435.2609863	0.15
436.3489990	0.06
438.3245239	0.02
459.2589111	0.02
463.3361206	0.05
467.4523315	0.04
476.6508179	0.05
478.3193359	0.06
481.3218384	0.87
481.9400635	0.02
489.0039673	0.11
490.0172119	0.04
491.7932739	0.03
492.5337524	0.07
495.4920044	0.07
499.3222656	0.66
499.9349976	0.05
505.3247681	0.17
509.3631592	0.71
522.3246460	0.05
523.6337280	0.18
525.3164673	0.27
526.9050903	0.10
533.6659546	0.13
535.6782227	0.03
536.6370850	0.04
541.4777222	0.02
543.3356323	0.20
549.4695435	0.04
551.6027222	0.04
553.2935181	6.79
553.9215698	0.01
569.3947144	0.01
571.3430176	6.89
572.0344238	0.15
575.4623413	0.04
577.4863281	0.12
580.3536987	0.03
581.5213013	0.18
585.5305176	0.02
592.1623535	0.04
595.3048096	0.02
597.1697998	0.15
598.3793945	2.46
601.7092896	0.05
603.3126831	0.05
606.4501343	0.17
612.4990234	0.06
613.1591187	0.03
614.5076294	0.01
615.8114624	0.11
616.4418335	0.55
618.5404663	0.02
630.4893799	0.11
637.4921875	0.03
652.4431763	0.02
654.4669800	0.16
676.5200806	0.14
685.4774780	0.68
687.0848999	0.03
703.4385376	0.47
705.7027588	0.01
712.6207886	0.02
713.3955078	0.36
721.5358887	0.05
729.5372925	0.06
730.2221069	0.06
731.3818970	0.43
739.5553589	0.20
747.5735474	0.16
748.6907349	0.12
749.5537720	0.13
750.4159546	0.03
756.8740234	0.15
757.4884644	3.54
761.2401733	0.40
762.3922729	0.02
765.3650513	0.30
775.4753418	18.16
793.4011230	100.00
794.1043701	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	454.98
Annotation	Unknow
Peak:m/z	Relative Intensity
156.0652771	0.12
186.9567566	0.17
189.0459595	0.06
199.9501038	0.12
204.3257294	0.28
205.1031952	0.28
218.0513306	0.13
229.1331024	0.06
230.3043213	0.12
247.0548096	0.39
248.0528259	0.06
248.9293213	0.08
259.8810730	0.11
261.0097351	8.06
261.8922729	0.28
264.0859070	0.70
265.1048584	0.14
275.9717712	0.62
279.0989685	0.08
293.0576782	0.22
295.4836426	0.07
303.1001282	0.61
307.7519531	0.11
319.9344482	14.89
320.9687195	100.00
322.0242310	0.08
324.8397217	0.06
325.9945374	0.34
327.7926636	0.12
329.8709412	0.15
331.0614624	0.65
344.9561462	0.08
347.6960449	0.16
350.1804504	0.51
351.2866821	0.18
354.1599121	0.49
356.0115662	0.40
357.0864868	1.30
358.8001709	0.09
359.9261475	0.16
366.1062622	0.40
366.9972229	1.14
368.1791077	0.13
374.8444519	0.30
385.1143494	0.24
387.2183533	1.29
388.4120789	0.50
389.0833435	1.32
393.7628479	0.33
394.8068848	0.34
397.8283081	0.25
399.6638184	0.07
408.2342224	0.06
409.9445496	1.29
411.0259705	0.37
412.1443481	0.22
421.9699402	0.18
424.6349487	0.51
426.0547180	0.33
427.1159363	0.05
432.3585510	0.53
436.3356018	0.40
437.0295105	0.12
439.2361755	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1459
Annotation	luteolin-3',7-di-O-glucoside 
Peak:m/z	Relative Intensity
175.1145325	0.31
182.2798462	0.02
183.0543823	0.02
184.9836121	0.21
187.1555176	0.02
189.1597595	0.03
197.0098724	0.18
197.9950867	0.20
199.0974731	0.26
201.1022949	0.05
211.3728943	0.05
213.1464386	0.07
214.9684448	0.10
217.0787659	0.33
223.071228	0.30
225.1711731	0.07
226.1465912	0.04
239.0472107	0.14
240.138916	0.15
241.1428223	0.34
242.0957642	0.18
243.2102661	0.41
252.9344482	0.02
257.1860962	0.12
263.1523132	0.02
266.9017944	0.05
268.0615845	0.19
269.977356	0.02
285.0463562	100.00
285.8924561	0.04
296.9757996	0.06
299.2871704	0.07
301.0674133	0.49
311.3413696	0.12
313.1575317	0.10
314.9599609	0.15
327.0929565	0.42
335.1585693	0.04
337.2929688	0.07
343.2186279	0.04
350.3147583	0.04
373.0714111	0.05
374.2963257	0.04
383.4001465	0.03
385.3768921	0.03
388.2692261	0.26
393.2759399	0.20
397.286499	0.03
405.2803345	0.02
411.4376831	0.10
416.2294312	0.03
427.8025513	0.07
429.2767944	0.13
430.0930176	0.04
443.5663452	0.07
446.6690674	0.38
447.2843018	2.78
451.4177246	0.03
456.1998901	0.05
460.2145386	0.11
463.7805786	0.09
478.7061768	0.03
479.5014038	0.05
489.5513306	0.05
493.3672485	0.06
503.4227905	0.09
517.3403931	0.02
520.199585	0.04
523.3258667	0.11
524.1044312	0.05
531.6699829	0.10
532.5379639	0.03
537.0499878	0.09
547.4058838	0.06
548.4180298	0.07
549.5475464	0.21
561.5879517	0.05
563.4638062	0.14
564.4857788	0.11
565.3839111	0.28
574.7243042	0.02
588.8060913	0.08
591.37677	0.18
592.2114868	0.23
609.2802734	0.08
610.3345337	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.84
Annotation	Unknow
Peak:m/z	Relative Intensity
83.9737473	0.10
101.1462555	0.02
101.9375687	0.02
117.8739014	0.16
119.2166748	0.01
122.8404770	1.80
123.8462830	0.01
124.8493271	1.32
128.9826355	0.08
129.9822998	0.05
147.0620728	0.40
163.9439240	0.06
164.8793793	0.02
178.8122253	0.04
206.8294983	26.29
208.7959900	100.00
215.1030884	0.05
218.1986694	0.03
218.8882141	0.08
229.2328796	0.14
231.0227661	0.26
237.1400146	0.02
244.2013550	0.09
245.2602234	0.12
249.1470642	0.01
261.9814148	0.08
274.1396179	0.45
275.3025513	0.12
277.2560425	0.09
283.5890198	0.06
286.2603760	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.104
Annotation	Isoscutellarein 8,4'-dimethyl ether 7-glucuronide
Peak:m/z	Relative Intensity
148.9567261	0.04
150.9592590	0.17
152.9148102	0.01
154.2577820	0.03
155.1824646	0.02
157.0945892	0.01
158.9483643	0.01
161.0119934	0.01
163.0534821	0.12
164.0217285	0.05
169.3768921	0.03
171.0042114	0.06
172.1368408	0.02
173.7016144	0.02
175.1560974	0.13
178.9145355	0.10
182.2292786	0.03
184.2458801	0.06
184.9606018	0.01
187.0733032	0.06
188.2055969	0.02
189.2326355	0.02
191.0141907	0.01
192.7790375	0.01
195.0607910	0.25
197.1062622	0.24
198.5722046	0.06
199.1738586	0.10
207.0293732	0.01
208.1860657	0.01
209.8772888	0.01
211.0003510	0.11
212.8547363	0.26
214.1085968	0.06
217.0162048	0.04
219.8882904	0.02
222.9780579	0.03
224.1333618	0.03
225.1805573	0.07
227.1589966	0.22
228.0307770	0.01
229.1694946	0.57
230.2233887	0.03
239.0162201	0.39
240.0161743	0.19
241.1360168	0.60
242.2202759	0.06
243.1586609	0.11
252.0119019	0.02
253.1567993	0.05
255.1441345	0.74
256.2778015	0.43
257.1867676	1.26
258.0806885	0.30
259.2122498	0.03
265.5687561	0.04
267.0939636	0.52
268.0050659	0.04
269.3316345	0.02
272.0894470	0.03
273.0821533	0.08
275.2929382	0.02
277.0189819	0.02
279.2177429	0.02
281.1591492	0.07
283.3229065	1.44
284.1093140	6.17
285.0933838	100.00
286.1631470	14.20
291.0619812	0.03
293.4543152	0.02
297.3021240	0.03
298.3308411	0.05
299.2785950	0.09
309.0574646	0.08
310.4063416	0.06
311.2522278	0.03
312.0418396	0.05
313.2341309	0.07
315.0997009	0.01
325.3959351	0.02
327.1066284	1.49
328.2165222	0.08
329.3119507	0.04
339.4266357	0.13
340.2553711	0.02
342.1052856	0.02
343.0820923	0.03
345.0672302	0.02
351.2355957	0.03
353.1708069	0.05
357.2025757	0.17
358.1361084	0.07
367.4075012	0.03
369.3878174	0.05
373.4466553	0.01
381.0158081	0.05
382.0828247	0.03
383.4068298	0.03
391.2614441	0.03
393.2278748	0.13
394.2655945	0.01
394.9958801	0.11
403.3795166	0.02
405.5376892	0.04
408.5608521	0.05
411.6979065	0.01
412.4337769	0.06
417.5024414	0.04
418.4305725	0.03
427.5697021	0.05
429.2256775	0.48
430.4365540	0.13
443.0787048	0.05
444.0559387	0.04
446.3450928	0.01
447.1594849	0.31
448.3977661	0.05
454.2320862	0.01
461.3330383	0.05
471.1271057	0.21
472.3229675	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
761.0916748	2.60
873.4164429	7.80
903.0545654	6.48
967.4390259	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.8524
Annotation	Unknow
Peak:m/z	Relative Intensity
158.7997437	0.07
170.9510498	0.03
174.9173279	2.66
214.8811035	0.27
231.1377258	0.26
244.8946686	0.35
260.9632263	0.21
272.8489990	0.33
274.1125183	0.15
275.1756592	0.03
277.1022949	0.33
288.9645081	12.73
290.0532227	0.16
291.0657349	0.19
304.9972534	29.62
388.3742676	0.08
393.1214600	0.15
403.0300293	4.86
403.9703369	1.41
418.9545898	31.51
433.6137085	0.21
434.8581543	100.00
458.9057007	0.03
475.0241699	1.00
489.9261475	0.07
493.1196899	0.04
501.9318237	0.46
503.1925659	0.34
504.0351562	0.02
511.1550903	0.04
517.9295654	0.03
520.9785767	0.24
522.1087036	0.03
547.8267212	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	644.64
Annotation	Unknow
Peak:m/z	Relative Intensity
232.9148560	0.08
235.0346985	0.11
241.1704407	0.07
256.9863892	0.20
272.0706787	0.32
281.9772034	0.14
292.8946533	0.77
294.6783447	0.28
297.0790405	0.03
297.8626709	0.07
300.1365967	0.08
304.6383667	0.27
308.9418335	0.69
314.8825989	0.11
317.0932007	0.13
322.8923950	0.25
369.0944214	0.06
384.4747925	0.04
391.6558228	0.29
392.9161377	7.87
400.3941650	0.04
418.1458740	0.58
429.9750366	0.17
441.0772705	0.42
447.1220703	0.14
450.8191528	0.21
454.3522949	0.04
460.2105713	0.42
465.2390137	0.28
466.7878418	0.26
468.7977905	4.13
470.0896606	0.45
470.8737793	6.16
471.8942871	0.21
472.7244263	0.62
473.6703491	0.61
474.5911865	0.21
476.7521973	74.63
482.9910278	0.30
484.5770874	0.55
486.8023071	0.28
488.9171143	0.42
494.3808594	0.27
498.9319458	0.05
506.7466431	0.10
507.7547607	0.42
508.9365845	0.32
511.2881470	0.59
544.6216431	0.17
546.9002075	0.08
557.6461182	0.24
558.8793945	0.23
560.7377930	100.00
597.4538574	0.11
598.1210938	0.09
601.1635132	2.95
602.3477173	0.06
624.5782471	0.09
644.5908203	0.33
645.5582886	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1145
Annotation	Unknow
Peak:m/z	Relative Intensity
191.3758850	0.07
193.0827484	1.53
204.1602325	0.15
206.1390381	0.06
219.1161194	2.18
227.2080078	0.08
231.2668304	0.06
237.1440430	0.84
238.0640259	0.05
240.5746918	0.06
241.1884155	0.12
242.1358337	0.41
245.0734100	0.04
246.0939026	0.27
247.3356628	0.11
253.1653290	0.67
269.1807861	0.30
271.1604004	16.42
272.1643982	0.16
276.0352783	0.08
277.2711487	0.11
279.2358398	0.42
283.1933899	0.06
284.3366699	0.15
293.1567383	4.54
295.4364014	0.11
297.1688843	6.47
299.1272583	0.14
305.9890137	0.18
311.0528564	5.80
315.1191406	35.96
317.0560303	0.42
323.4827576	0.16
325.8013916	0.16
330.1509399	0.05
337.0520020	0.06
339.3351440	0.15
341.2023315	9.55
347.3598633	0.30
349.5797729	0.06
351.1912842	0.27
355.2318726	0.39
357.2595825	0.61
359.0889893	100.00
375.3103638	0.08
381.1923218	0.06
383.3605347	0.22
397.4703369	0.28
399.1423340	0.68
401.4099731	0.14
403.4317017	0.11
407.5175781	0.24
411.2413330	0.10
414.9660645	0.18
417.3344727	0.21
447.1219482	0.67
451.0485840	0.25
455.1880493	0.36
459.5415649	0.10
466.1630859	0.06
471.1697388	0.08
473.1229248	15.48
473.9489136	0.07
477.0732422	0.51
479.4080811	0.14
480.1446533	0.07
489.3664551	1.22
490.5097656	3.94
491.2390137	16.60
494.8187866	0.17
496.9849854	0.08
503.4409180	0.28
507.5200195	0.10
517.9485474	0.09
520.0985107	0.37
521.1146240	5.60
535.3196411	0.22
536.3674927	0.06
539.2661743	0.40
553.2098999	0.12
572.1616821	0.31
573.2500610	0.05
581.9094849	0.08
606.2361450	0.04
607.1730347	0.11
608.2113647	0.31
609.2465210	0.63
616.8020630	0.13
620.2297363	0.14
634.5883179	0.80
635.2680664	1.88
653.3528442	1.24
654.1677856	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	652.2266
Annotation	Unknow
Peak:m/z	Relative Intensity
216.9249573	0.56
222.8349152	0.74
229.0184784	0.36
235.1660156	0.21
240.4935455	0.31
241.2809143	0.78
246.8475647	0.97
252.7592163	1.09
258.4485474	2.77
270.8839417	8.95
276.7266541	1.35
288.7871704	10.18
289.4240723	2.51
292.1623230	0.73
301.8831177	0.84
303.3474121	0.91
304.5897217	0.26
306.6941528	6.47
309.8834534	3.91
324.1994629	7.66
324.8653564	100.00
325.6803589	0.11
328.8646851	0.22
339.0571899	0.89
340.4982300	0.87
342.2877808	19.92
342.9005127	45.13
343.5434570	0.46
450.6387329	1.56
451.4891357	0.52
468.7491455	0.95
471.9575806	0.99
486.7973633	1.83
490.0525513	16.84
503.7992554	0.67
504.8447266	1.44
561.1080322	1.03
634.3577881	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	242.09
Annotation	Unknow
Peak:m/z	Relative Intensity
73.6693878	0.23
86.9330750	0.14
99.9297485	0.53
109.9920349	0.66
110.9694824	0.13
112.9245148	0.17
119.6831818	0.12
129.9213104	0.42
133.9069214	0.07
137.8510132	0.65
141.9068298	0.21
155.9976807	0.74
162.9430389	0.20
167.9225006	0.82
178.0067596	0.29
188.8121796	16.45
190.8715057	0.46
193.9433594	0.70
196.0106049	2.84
197.6493835	0.16
199.7428741	0.79
200.9656525	0.75
203.1676788	0.54
203.8716431	0.20
205.0165863	0.72
206.3093719	7.40
206.9940186	7.39
209.9793243	4.53
211.9742126	0.79
213.8848419	1.15
218.7172852	0.33
220.7976227	0.99
224.0144348	100.00
224.8945770	34.83
230.5106201	0.84
232.9201202	1.98
234.5197296	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3144
Annotation	Phyllanthoside
Peak:m/z	Relative Intensity
232.9582214	0.02
292.1792297	0.03
327.5572510	0.03
349.2553711	0.02
400.3292236	0.02
412.3713379	0.07
424.8145142	0.03
432.3326416	0.03
459.1610107	0.01
485.4036865	0.05
489.4699707	0.02
491.3078003	0.06
499.2203369	0.03
500.1727905	0.02
503.3856812	0.02
547.3364868	0.07
550.9583130	0.03
560.3618774	0.04
563.5966187	0.02
567.5972290	0.01
591.2363892	0.05
604.4428101	0.10
605.6036377	0.25
616.5497437	0.02
629.6466675	0.03
636.3271484	0.15
649.3511353	0.73
650.7992554	0.02
658.2798462	0.01
659.6902466	0.03
667.5806274	0.01
672.4067993	0.03
673.2168579	0.01
674.4776001	0.01
680.2650146	0.05
681.3410034	0.01
683.4608765	0.06
685.0844727	0.10
698.4924927	0.01
723.5152588	0.04
727.4215698	2.58
728.0898438	0.01
743.7785645	0.02
753.4318848	0.07
758.3833618	0.10
759.5069580	0.13
767.2948608	0.01
771.4229126	5.99
785.1090698	0.04
803.3811646	100.00
804.0281372	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
146.8924103	0.78
148.9530182	0.82
164.86586	0.38
166.0523224	0.53
179.3543091	1.61
180.1357269	0.28
181.1522064	1.30
182.2138824	0.10
189.2827911	0.27
192.780899	0.25
194.2152252	0.21
196.0980072	0.33
207.1395264	7.64
208.0251312	8.68
209.0770416	3.34
221.028183	0.12
222.1187897	8.66
223.1314392	11.92
224.2165985	1.41
233.0814972	0.80
234.1807861	0.28
235.2752228	0.20
251.0800323	100.00
252.0517731	40.49
253.1961823	2.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.1411
Annotation	2'',6''-Di-O-acetylononin
Peak:m/z	Relative Intensity
150.9389954	1.19
157.1590729	0.42
161.1208496	0.77
163.1138000	0.05
166.8738251	0.49
169.0183868	0.30
170.1645966	0.16
171.0783539	0.36
172.9467316	0.19
182.9221649	1.12
185.0919189	2.04
186.0417786	0.04
194.0357361	0.08
195.2008057	1.52
197.0033264	0.98
198.1552429	0.67
201.1546021	2.01
202.8404236	0.29
205.2343750	0.14
210.8714600	0.29
213.0845490	26.89
213.7999573	0.27
215.2357483	0.12
217.2687683	0.05
219.2373505	0.22
227.1363525	0.27
228.1994019	0.10
229.1763611	0.44
232.7369537	0.12
239.0179443	1.44
242.1156921	9.97
243.0063171	0.14
245.2261047	0.07
257.0674438	100.00
257.6780701	0.18
259.2745972	0.21
261.3385010	0.36
265.4916382	0.07
267.0144653	0.03
271.1365967	0.31
275.0763855	2.49
286.9733887	0.04
289.1177979	2.21
291.2386475	0.29
293.2059326	0.14
295.1927185	0.04
298.9969177	0.04
302.9075317	0.23
303.5450439	0.10
305.4244385	0.05
308.2347412	0.07
312.1382446	0.07
321.2739868	3.90
324.9716797	0.27
326.8602295	0.63
327.5574951	0.06
341.0992432	0.06
347.1250610	0.06
349.2990112	0.09
351.5119019	0.20
365.2321167	1.92
367.1520996	0.11
391.1626587	0.14
397.4212646	0.08
399.3684082	0.12
404.7881470	0.10
409.1614380	52.46
417.2754517	0.03
419.4006958	0.74
420.2029419	0.16
421.0131836	0.23
423.2220459	0.26
425.0839844	0.05
427.3452759	0.50
429.2669067	0.09
432.2100830	0.17
433.4396973	0.07
434.1112061	0.13
436.3523560	0.23
440.3964844	1.77
441.1307373	9.42
453.1564331	0.06
467.1207886	0.44
468.4642334	0.12
469.2465820	0.06
471.1747437	0.08
474.9064331	0.17
476.3346558	0.13
480.5264893	0.19
493.2144165	0.09
494.4096069	0.16
495.2053833	0.09
495.8206177	0.26
497.9088745	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1040.4836
Annotation	Unknow
Peak:m/z	Relative Intensity
545.3420410	0.20
702.1971436	0.21
909.1617432	0.75
993.8865967	0.22
1040.5255130	100.00
1041.4271240	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.09
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
135.0364380	0.60
144.9675903	4.27
146.7898865	0.52
151.1881866	0.06
162.9160767	100.00
163.8550873	0.09
165.0551758	0.05
174.9698486	2.92
177.1646423	0.28
180.8092651	0.29
186.0036621	0.24
191.1586914	1.08
209.1177673	0.09
215.1013794	0.06
224.0174713	0.30
226.1892090	0.11
227.1689148	1.30
231.9526825	0.23
233.0766296	0.48
237.3430023	0.28
238.6548615	0.05
240.1817017	0.11
244.0625763	0.23
245.3433533	0.12
250.1778564	0.04
252.1385193	0.17
255.1547546	1.08
257.1400452	0.78
259.1757202	0.19
265.1831055	0.04
267.0369873	0.06
269.1220093	3.38
270.1095886	0.23
271.1033630	0.06
280.4206848	0.13
281.0842590	0.11
283.0910950	13.47
295.0057068	2.68
295.8905334	0.89
297.1713562	1.39
298.2168274	0.05
301.1457825	30.72
302.3051758	0.10
312.3800354	0.28
313.0810547	0.23
314.1730957	2.18
315.1168213	0.12
317.1436768	0.15
321.1560059	0.03
322.1428223	0.04
323.1313782	0.69
324.2770386	6.91
325.0136108	31.13
326.0400696	0.13
337.0237732	0.11
341.3768005	0.08
343.1152039	2.52
345.3275452	0.30
346.0078430	0.13
347.3219604	0.08
349.1745911	0.12
351.2593384	0.11
352.1553040	0.20
355.4509888	0.11
360.1472778	0.24
365.0790100	2.09
365.7547607	0.12
370.0827332	0.25
371.3413086	0.07
384.2582703	0.15
385.0481873	0.12
387.1841736	0.16
411.9546814	0.12
412.8150940	0.63
415.3212891	0.88
417.2638245	0.07
428.2106628	0.58
429.1461487	0.55
429.7640686	0.11
431.0416565	0.10
433.3358459	0.13
433.9899597	0.03
439.1219788	0.10
446.1339417	0.36
446.9071045	0.07
456.3148499	2.12
457.1741638	6.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7560577	100.00
123.8776855	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2782
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.8303528	0.07
152.9278564	0.02
195.9875031	0.21
214.0162659	1.13
214.6458740	0.03
217.7391052	0.02
233.3413391	0.02
239.4421387	0.04
259.4628906	0.05
261.3625488	0.21
279.2555237	100.00
351.8138428	0.02
375.4271240	0.02
386.7384033	0.02
401.5409241	0.03
416.2529602	0.06
422.3081055	0.05
429.2742920	0.01
431.5031433	0.03
432.2073364	0.02
438.7003479	0.05
457.6537476	0.02
458.2854309	0.01
461.5402222	0.01
462.3692017	0.05
477.5092468	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.8
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8534546	0.13
152.9261169	0.05
212.8298187	6.66
214.4235687	4.02
215.0363007	2.14
245.0936279	0.16
246.3019104	0.41
253.0537415	0.84
296.7395630	52.40
298.2147217	25.72
298.9425049	49.45
330.0830688	0.21
346.7431946	0.09
380.0990295	4.01
380.7101746	28.60
381.8461914	27.60
382.6573181	100.00
383.5238342	0.07
403.1921082	0.50
419.9660950	1.25
421.0660095	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1409
Annotation	AN-7
Peak:m/z	Relative Intensity
130.9598236	1.83
160.6914062	0.46
161.3154602	0.47
178.9453735	7.56
181.0557861	0.89
223.0727539	1.14
238.7037354	1.30
269.1813354	2.17
271.2641296	1.15
287.2257996	10.88
299.221283	1.81
305.1456299	3.22
306.116394	0.68
307.3847351	0.47
309.1385193	0.98
329.4225769	0.57
351.3438416	1.68
352.9574585	3.96
357.4647217	0.55
368.9970398	0.68
391.0870667	1.67
403.1402588	100.00
404.2010193	0.46
405.3346558	0.52
406.3027039	1.94
413.157074	2.26
420.9975281	2.15
426.9758301	2.84
431.0071716	8.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	736.2348
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1793213	0.43
219.3706665	0.24
234.0787048	0.09
241.0537109	4.25
245.3191376	0.22
249.2934265	0.06
252.2840118	0.11
253.1165161	0.08
259.2879028	0.34
261.9036865	0.06
263.3675842	0.32
273.2259521	0.05
280.0694275	0.20
281.2897339	0.20
290.9956665	0.15
293.2893066	0.19
298.3699341	0.11
300.1778870	0.23
302.1747131	0.10
312.4876099	0.25
314.2025146	0.65
316.3506470	0.49
326.9819946	0.48
328.0939941	0.03
333.1940002	0.04
334.2578735	0.63
336.1445312	0.18
337.3969421	0.15
341.1459351	0.16
362.3756714	0.04
371.2014771	0.14
373.2518921	0.17
374.4988403	0.32
375.2363892	0.61
382.1944580	0.28
384.0199585	0.20
388.0548706	0.30
402.2908936	4.70
407.2674561	0.30
419.6432495	1.99
420.3652344	4.54
423.3594971	0.12
427.4544678	0.12
436.8066406	0.43
437.5674438	2.17
438.3472290	2.30
450.1638794	0.11
454.8276978	0.32
455.4790649	0.53
463.3066406	0.15
468.2498169	0.78
469.3449097	0.26
479.2041016	0.47
485.3428345	0.11
486.4812622	0.57
487.6828613	0.06
491.2730103	0.53
497.0139771	0.11
502.3047485	0.08
504.2078857	10.29
508.2488403	0.58
512.0582275	0.07
514.1231079	0.29
515.1781006	0.19
526.2971191	3.42
532.1060791	0.06
536.3998413	0.09
542.2013550	0.33
544.1773682	0.37
547.3651123	0.23
548.3165283	0.45
549.0932617	0.10
554.3652954	1.52
558.6497192	0.61
566.5599365	0.14
567.1831665	0.09
568.3333130	0.03
572.1718140	19.11
572.8522949	0.20
584.4498291	0.17
589.2891235	19.77
590.1854858	4.05
597.5274658	0.12
605.5477905	0.22
607.2326050	100.00
607.8430786	0.33
626.5149536	0.39
634.8961792	0.12
637.5682983	0.06
643.6111450	0.41
645.9281616	0.11
654.4053955	0.60
661.3491211	3.99
662.0153809	0.19
673.3302612	0.56
699.0407104	0.11
700.3148804	1.76
709.6690063	1.12
711.3400879	0.09
718.3435669	9.68
719.4187622	0.90
736.2866821	6.94
737.5883789	0.15
749.4171753	1.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	517.1323
Annotation	2'',6''-Di-O-Acetyl isovitexin
Peak:m/z	Relative Intensity
162.9551697	1.00
164.0604553	0.10
165.1887970	0.02
171.0386047	0.02
180.8984375	0.09
191.0438538	0.03
205.2128754	0.03
216.9611816	0.24
232.8935852	0.23
236.1490631	0.06
252.9787140	0.09
270.3613281	0.09
279.0570068	0.03
281.1196899	0.07
283.2935791	0.06
283.9547729	0.02
293.3844604	0.06
297.0183105	0.44
301.0673218	0.06
302.2035522	0.10
308.5091553	0.10
321.0724487	0.02
325.0551758	0.28
333.1128540	0.08
337.0712891	0.57
342.9882202	0.04
354.4683838	0.11
355.2519531	0.08
361.4141846	0.05
363.1796875	0.14
365.6327515	0.06
369.0267944	0.02
393.6069946	0.02
407.3294678	0.06
408.5082397	0.11
409.3892822	0.02
416.3723145	0.10
435.4473267	0.05
439.2266235	0.15
445.2142334	0.18
449.8108521	0.17
463.5049438	0.17
470.9100952	0.14
472.2379761	0.06
473.3566284	0.04
481.4567261	0.05
485.0654907	0.02
486.7318115	0.05
489.5620728	0.11
492.3120728	0.17
497.1514282	0.03
499.1879883	100.00
500.2551270	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2916
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
151.1684570	0.05
154.8952942	0.02
157.1889954	0.05
159.0602722	0.07
161.2196350	0.06
167.0726013	0.05
169.3177185	0.05
173.2759094	0.09
178.3916779	0.03
179.8906860	0.09
181.0280609	0.19
198.0147552	0.69
199.0596924	0.05
201.2866669	0.06
211.0154724	0.19
211.9767303	0.03
215.9859314	0.13
229.2276001	0.08
238.9449310	0.09
257.5279236	0.15
263.1159668	0.04
269.3141174	0.07
282.3121948	1.38
283.2936707	0.02
286.2571716	0.08
297.5902710	0.05
300.3795471	0.20
311.0946045	0.15
313.3106689	88.71
313.9217529	0.20
323.2128296	0.04
335.0733032	0.22
349.3060913	0.05
352.2153320	0.24
354.2451782	0.02
356.5276794	0.13
365.3970032	0.07
368.2050171	0.02
384.7959595	0.05
388.0954895	0.18
392.6111755	0.67
393.2364197	7.48
394.8259583	0.03
395.5431213	0.02
401.1658325	0.07
405.1707458	0.04
408.6372070	0.03
411.0903015	0.10
418.0983582	0.11
419.0250549	0.33
436.1869812	100.00
436.9323425	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	REBAUDIOSIDE A
Peak:m/z	Relative Intensity
657.4527588	19.31
967.4537964	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.0728
Annotation	Kaempferol-3-Glucuronide
Peak:m/z	Relative Intensity
160.8209534	0.02
169.1020355	0.05
175.0961456	0.03
190.7495117	0.02
230.2639771	0.01
271.459259	0.02
283.2990417	0.04
285.0473633	100.00
285.6789551	0.21
295.2338867	0.05
297.0773926	0.48
309.1091003	0.04
311.1642456	0.02
319.3092041	0.03
325.1873474	0.21
327.1550293	4.13
328.4401855	0.04
337.1087036	0.41
339.1270752	0.12
341.401886	0.03
343.3534546	0.04
351.2062378	0.19
353.1811523	0.38
355.1556396	1.88
357.1919556	4.48
363.2072754	0.19
369.1345825	1.52
371.1536865	0.58
381.2062683	3.25
385.4026184	0.03
399.2125854	0.30
417.0586548	0.04
425.405304	0.08
443.2276306	0.14
462.2550964	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2759
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
135.0855560	0.06
138.2439575	0.01
143.1043549	0.02
144.9625244	0.02
155.0476990	0.05
159.0223999	0.08
161.1987762	0.04
173.0878906	0.28
177.2011719	0.03
185.2824097	0.04
187.0783081	0.08
191.2624512	0.08
197.1404724	0.01
198.0009155	0.18
200.2277527	0.07
201.3403320	0.03
215.9635925	0.18
217.2542267	0.14
219.1277771	0.05
221.1673889	0.02
223.3069153	0.02
237.2931824	0.01
243.3900146	0.11
249.2962952	0.03
256.9779968	0.02
261.1788025	0.18
270.8683472	0.04
277.2648315	0.03
279.2930603	0.08
283.1015625	0.02
297.7003174	0.02
299.4252625	0.10
304.3917236	0.40
309.4000549	0.06
317.3366089	0.09
322.5142822	0.16
327.2544556	0.03
335.2772827	100.00
335.9180908	0.17
348.3672791	0.11
364.1889038	0.25
372.1549683	0.04
378.3594055	0.07
379.3187256	0.02
385.8542175	0.15
386.5773926	0.09
387.9472046	0.06
388.8489685	0.07
390.2722473	0.05
394.7436523	0.05
402.4282532	0.04
409.4645691	0.05
413.6927795	0.05
415.2524109	0.11
428.9481201	0.05
430.3435059	0.03
440.4899597	0.17
442.6315002	0.06
444.2647400	0.09
448.3965149	0.07
452.5840149	0.03
457.2561646	0.15
458.3318176	3.38
459.2141113	0.03
460.7276917	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	641.1323
Annotation	Quercetin 3-glucosyl-(1->2)-glucuronide
Peak:m/z	Relative Intensity
195.0351715	0.01
201.2048340	0.02
219.0469971	0.03
227.1684570	0.05
229.0322723	0.33
230.6080475	0.05
235.1757507	0.03
247.0496216	0.09
257.1508484	0.12
267.1683350	0.07
273.9432373	0.18
282.1801453	0.03
285.0669861	0.22
300.2503662	0.01
300.8863525	0.03
303.0883179	100.00
303.9287720	0.03
315.1635742	0.33
327.1737366	0.49
342.2487793	0.05
345.0750732	0.94
345.6785278	0.03
352.9614258	0.02
368.1658325	0.25
369.2285767	0.35
375.3887329	0.03
381.4904785	0.04
392.3715210	0.14
399.1618652	0.34
410.8414917	0.02
425.0968018	0.62
429.1981201	0.10
435.2714233	0.07
443.0738525	0.50
443.7374878	0.03
447.2729492	0.23
450.2215576	0.01
461.2071533	1.62
465.0803223	57.30
479.0960083	47.64
479.7601929	0.07
488.9594116	0.04
490.4537964	0.01
503.4100342	0.01
519.2187500	0.03
520.9820557	0.09
521.5884399	0.01
523.5648193	0.10
531.0209351	0.05
545.4522705	0.02
559.3049927	0.04
561.6394653	0.01
577.3696899	0.03
587.2045898	0.05
599.4314575	0.19
600.4247437	0.07
601.4924927	0.02
605.0949707	0.06
623.0269775	0.18
641.0480957	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.3592
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0447235	0.19
212.9790192	0.28
221.0813751	0.07
255.3412628	0.09
259.0114746	0.30
269.0629272	0.05
299.4166870	0.07
313.0945435	0.11
343.2746582	0.23
345.4390869	2.02
347.3718262	0.97
351.1900635	0.15
359.2841187	0.14
373.1105957	0.17
384.7589722	0.31
391.1143188	0.83
427.1382446	0.42
466.3663940	0.74
467.2966919	2.53
471.6119995	0.10
493.3862915	0.07
500.7326050	0.46
505.5681152	0.57
507.4417725	100.00
508.1176758	0.19
509.1801147	0.85
515.2144165	0.19
531.1068726	0.60
533.1904907	0.19
535.1490479	0.82
554.2000122	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2619
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
185.0603638	0.04
224.1430359	0.12
235.1759644	0.12
253.1353455	0.06
301.9978027	0.15
311.3685913	0.06
317.4834595	0.09
399.4846802	0.09
406.5203247	0.06
415.5794678	0.08
438.2561035	0.12
459.4185791	0.03
463.8068848	0.12
471.4318848	0.21
488.9986572	0.04
491.3062134	0.09
510.4096069	0.16
513.4456177	0.53
514.4803467	9.48
515.3622437	100.00
517.4734497	0.03
519.4258423	0.34
521.5358276	0.02
530.6707153	0.04
531.4601440	0.05
534.3386230	0.13
535.3056641	0.05
536.5032349	0.09
537.5578003	1.15
544.8004761	0.17
546.3592529	21.76
547.3501587	5.28
547.9811401	0.23
555.2102661	0.03
559.2762451	21.63
573.4865112	0.19
574.7924805	0.06
591.4879761	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.11
Annotation	Herbacetin 8-(2'',3''-diacetylxyloside)
Peak:m/z	Relative Intensity
144.6980133	0.15
187.2246552	0.33
203.1124573	0.17
207.4892426	0.02
213.2643280	0.03
224.0387115	0.13
225.1968536	0.13
233.2017212	0.07
235.0612183	0.06
254.6410980	0.04
259.3421631	0.13
261.2360840	0.06
271.0692139	100.00
271.6793213	0.28
274.3223267	0.14
275.3136597	0.04
278.9465942	0.06
298.2670288	0.03
303.1109009	0.05
329.1904907	0.19
337.2514038	0.04
340.2648315	0.04
343.3768921	0.05
355.1177368	0.10
356.6139526	0.17
357.2216187	0.25
382.4406128	0.10
385.0397949	0.07
396.4256592	0.07
399.1746826	0.10
405.5662231	0.09
411.2320557	0.10
433.2099609	17.42
440.7440186	0.08
450.7730713	0.10
456.9349365	0.03
468.5335083	0.06
475.2239380	2.49
480.8899536	0.22
483.4895630	0.33
491.4973755	0.08
501.0850220	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.0723
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
117.2526703	0.07
120.0669250	0.13
129.0381165	2.46
132.9411926	0.02
133.9353638	0.06
135.0590210	1.22
136.0793762	0.06
146.8742676	1.24
149.0821228	0.06
162.9576721	0.80
164.9592590	100.00
178.9680939	11.91
195.0918121	0.02
197.2360229	0.06
210.7682800	0.10
225.4650269	0.05
227.2218933	0.02
231.0557556	0.04
250.0056763	0.02
253.2171631	0.07
266.2188110	0.07
280.8972778	0.04
282.7053528	0.10
283.4283142	0.21
299.2233276	0.13
309.2119751	3.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	209.0667
Annotation	Sedoheptulose
Peak:m/z	Relative Intensity
68.9830017	0.06
70.9143448	1.57
72.7666702	0.08
78.9778061	0.11
82.9777832	1.13
84.8572388	11.18
85.9040680	0.05
86.9008179	14.17
88.9066009	1.44
96.2828064	0.13
96.9489288	2.49
97.7615356	0.04
98.9289856	5.73
100.9014130	0.83
110.8692474	11.54
112.9678192	0.31
114.7492371	4.26
128.9218445	100.00
130.9836731	0.14
133.1735687	0.12
137.0050201	0.06
140.9523621	9.78
142.9309845	0.07
144.7292633	0.26
147.1966705	0.14
149.1175079	0.13
159.0059814	45.46
162.8293304	0.47
165.1353912	0.77
172.9235687	0.03
177.0915833	0.55
190.8560944	1.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0764
Annotation	Glutathione
Peak:m/z	Relative Intensity
99.0005493	0.16
111.0369720	0.14
116.0358505	0.34
120.0650177	0.07
125.0932312	0.23
126.0307159	0.11
127.9494629	11.54
130.1076050	0.06
132.9378357	1.29
133.8819580	0.03
134.8452148	0.10
143.0362549	12.17
145.0021973	0.34
145.9204102	1.06
152.9581604	0.34
160.0001831	14.46
167.0428772	1.46
168.9231262	0.19
170.1328430	0.26
171.0431976	2.61
177.0540314	8.80
179.0344696	14.22
183.1731110	0.06
185.0859528	1.81
192.1521301	0.31
197.0828094	1.60
198.9743958	0.11
202.5130310	0.14
203.1537476	0.20
210.0511169	10.01
211.0567017	0.13
213.0778503	2.21
217.3134460	0.02
224.2106323	0.09
228.1369019	1.03
230.9090576	0.59
233.8015137	0.08
236.1290283	1.01
242.1289673	2.20
243.2331543	0.08
244.1926880	0.13
245.1691589	0.17
245.8929749	0.10
254.0682983	100.00
260.1040344	0.18
262.0802612	0.08
266.9156494	0.19
270.1277161	0.05
270.9688721	0.13
272.1065063	94.07
272.7075195	0.19
284.1753540	0.18
288.0593872	49.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.1115
Annotation	Pelargoniin B
Peak:m/z	Relative Intensity
207.1470337	0.03
228.9520264	0.06
257.0559998	0.14
258.9605103	0.02
266.9650879	0.07
274.0111694	0.08
275.3797607	0.14
285.1357727	0.12
303.1009521	42.54
304.1385498	6.12
315.3212280	0.09
327.1566772	0.35
332.8925781	0.10
343.0601196	0.04
344.7770996	0.24
345.4795532	0.19
346.2521973	0.23
368.0818481	0.03
369.2464600	0.29
369.9260864	0.05
383.6345215	0.07
399.3955078	0.05
400.2102661	0.11
405.0462646	0.10
408.4815063	0.25
413.4389038	0.03
422.3193970	0.07
425.2066650	0.24
435.5742188	0.13
443.2285767	0.63
444.0347900	0.24
450.1104736	0.05
455.2961426	0.08
457.2515869	0.09
461.1931763	0.89
462.0684204	0.09
475.9953003	0.05
479.0908813	100.00
480.2273560	18.23
483.6536865	0.05
485.5388184	0.05
488.8764038	0.09
493.4179077	0.10
495.0048828	0.07
499.5652466	0.09
519.9459839	0.06
520.9695435	0.56
521.8280640	0.32
532.9683228	0.03
539.0381470	0.25
540.0479736	0.11
546.3285522	0.05
548.5261841	0.23
565.4309692	0.03
566.4105835	0.02
571.6738892	0.06
574.5625000	0.02
575.8958130	0.12
601.3994141	0.18
619.2823486	0.05
628.4525757	0.02
633.4609985	0.28
635.4808960	0.08
637.2183228	0.54
638.2177124	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	841.3474
Annotation	Unknow
Peak:m/z	Relative Intensity
235.9280396	0.27
246.1782837	0.13
250.0439911	0.42
253.3707275	0.07
255.3042450	0.12
262.2697449	0.16
263.3784790	0.11
264.2869873	0.07
266.4970703	0.16
271.2424011	0.09
273.3726501	0.11
277.1074524	0.12
279.3993530	0.24
280.9365540	0.24
285.1095581	0.05
287.1709290	0.41
290.8169861	0.09
293.2096863	0.40
296.0500793	0.09
297.0369263	0.44
299.1869812	1.85
305.3356628	0.18
309.1151123	0.20
311.3607178	0.10
312.3643188	0.23
313.0780029	0.28
315.3087463	4.01
321.1233826	0.12
323.1580200	0.52
325.0834351	0.56
327.2188721	0.26
331.4132690	0.24
337.2521362	2.37
338.1959534	0.13
339.2113037	0.51
343.1292114	0.08
355.1777649	0.34
357.0895386	0.91
361.2013550	0.10
369.2521362	0.56
371.3369141	0.50
373.1142578	0.44
384.0743408	0.23
385.5159912	0.16
387.0960693	0.06
396.7846680	0.05
401.2438965	7.77
418.5461426	0.54
422.5165405	0.13
424.3881226	0.19
433.4561768	0.40
434.4124146	0.07
435.4690552	0.52
436.5384521	0.12
438.3107910	0.13
446.4238281	1.74
448.3512573	0.66
450.2604370	1.11
458.2930908	0.16
461.2201538	0.20
462.0972290	0.41
464.2929688	11.34
465.2746582	0.45
466.0073853	0.11
470.2809448	0.21
472.1796265	0.89
476.0929565	0.67
477.0263672	0.56
478.4167480	0.06
480.2141113	0.24
480.9005737	0.11
482.2963257	0.69
490.3150635	12.20
492.1767578	0.39
493.6184082	0.09
494.2933960	0.97
504.5450439	0.52
508.0148315	1.67
508.6301880	0.44
510.4379272	0.36
514.4138184	0.20
519.5062256	0.30
522.3213501	9.07
526.3023071	0.07
530.2576294	0.08
532.2012329	0.26
535.3088379	0.22
538.1331177	0.08
540.2726440	0.15
552.4393921	0.14
554.5150757	0.14
555.4348145	0.14
565.7265625	0.09
566.3883667	0.05
583.5147705	0.84
585.6091309	0.07
587.3204956	0.71
589.9409790	0.05
593.4623413	0.21
598.2857056	0.37
603.3693237	7.74
608.4671631	0.13
611.3689575	4.49
616.4702759	0.05
619.4532471	0.55
624.2172241	0.19
626.3342285	29.58
627.3983765	0.67
629.4008789	10.16
630.4295654	0.15
631.2755127	0.04
634.5280151	2.53
640.6473999	0.50
641.5729370	0.36
643.2856445	5.51
643.9263916	0.05
647.3862305	57.34
652.4097290	51.05
654.5996094	0.30
656.4014282	0.08
658.5337524	0.12
659.7272339	0.24
661.1664429	1.16
662.0773315	0.23
665.6592407	0.13
666.3565674	0.09
669.6185913	1.66
670.2433472	5.50
672.4922485	0.14
678.7772827	0.56
679.3990479	21.20
684.3425903	28.01
685.1705933	0.54
700.6750488	0.21
702.1531372	0.27
705.6842651	0.16
717.4017944	0.40
728.5690308	0.35
747.5432129	0.47
749.6827393	0.61
755.5164795	0.10
763.4201050	0.54
764.2830200	0.76
765.4542236	2.87
773.4929810	3.40
781.3446655	1.37
782.0060425	0.09
791.4151001	13.27
795.2468872	0.18
805.3406982	2.31
806.0125122	0.17
809.3414917	93.66
810.0009155	0.19
823.6774292	2.58
841.4061890	100.00
842.0898438	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.9528
Annotation	Unknow
Peak:m/z	Relative Intensity
116.1006241	0.12
156.0132599	0.16
159.8236694	0.20
169.8868408	0.12
170.9573212	0.11
173.0405273	0.06
181.9603271	0.11
183.7700806	0.08
185.9540710	0.41
188.1269684	0.14
199.9608002	2.14
202.0904236	0.03
203.9151306	0.71
204.9437866	0.11
208.8591766	0.02
217.2096558	0.03
218.0975342	0.06
225.8314209	0.24
227.9919739	0.91
230.0948792	0.12
240.2014160	0.07
241.4340515	0.08
242.2738647	0.49
243.9422302	43.75
245.0876770	0.04
246.0781555	0.34
253.4405212	0.05
258.8576660	0.29
261.2243042	0.14
262.0726929	0.84
269.8663330	1.30
271.9218445	21.41
273.9040527	4.39
274.5100708	0.02
275.3471069	0.04
277.0720520	0.11
277.9676819	0.15
281.5890503	0.08
286.1785278	0.15
287.9046021	7.05
289.2270203	1.31
289.9865112	0.65
292.1665039	0.13
298.8249817	0.15
299.8988342	1.75
302.6878052	0.08
303.8834839	0.32
305.0194092	0.07
306.2250671	0.05
311.4862366	0.14
315.8168640	2.06
317.1296387	0.53
318.1462402	0.05
326.1047363	0.06
327.4431152	0.13
330.0845337	0.05
331.0577393	0.13
332.9742432	2.76
334.0698853	24.54
335.0759888	0.25
341.2735291	0.31
347.2992859	0.03
356.6134033	0.06
359.9727478	100.00
360.5928040	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	414.2
Annotation	Unknow
Peak:m/z	Relative Intensity
116.9945145	0.09
117.9591599	8.66
125.0961075	0.09
130.0863495	0.13
133.1107483	0.07
145.1098938	0.62
162.4008331	0.10
163.1572723	0.09
166.0211945	0.16
170.8412781	0.05
179.2413940	0.11
183.0442200	0.18
183.8287811	0.12
188.9469910	0.10
190.0843506	0.26
195.1230469	0.05
195.9509277	0.10
205.9043884	0.05
210.1260681	0.11
214.7747803	0.11
215.7307739	0.23
217.9995575	0.09
221.3216705	0.16
228.1202698	0.09
230.0542603	0.16
234.0502625	0.47
237.3310852	0.06
238.4432983	0.07
248.2003479	0.15
251.1187134	0.18
251.8617554	0.27
256.0023193	0.23
260.4539490	0.12
261.0840759	0.68
263.7893982	0.35
267.8258362	0.04
275.9734497	0.74
276.7220459	0.08
277.6440125	0.29
278.4532166	1.04
279.0754089	6.65
280.0117798	1.18
282.5346985	0.54
287.9824829	0.11
294.0072632	11.39
296.1272583	0.10
297.2387695	0.97
298.0563660	1.06
306.1312561	2.74
307.8994141	0.21
311.4219360	0.84
315.2699890	0.34
316.1854858	0.21
318.0848694	2.23
319.1369629	0.39
321.9943848	1.41
324.0588684	100.00
324.9374695	0.87
325.8484497	0.24
326.9526367	0.21
332.8757935	0.73
333.6163025	0.18
335.9656372	3.44
337.9649048	0.54
340.1318970	0.16
341.3839722	0.29
345.0000305	0.36
346.7281799	0.51
347.9182739	0.15
352.0053101	0.71
354.1561584	0.09
355.1459961	0.04
358.7959290	0.22
359.9915466	0.85
360.6410828	0.36
361.2956238	0.97
362.4245300	0.11
363.9691772	0.37
365.1001892	0.62
366.2272034	0.74
367.9780884	0.29
369.2615356	0.62
370.0570679	1.92
373.0333557	0.48
377.1894836	0.55
377.9100037	2.22
378.6335754	0.31
383.8168030	1.59
386.4873352	0.14
392.1344299	0.90
393.4559631	0.10
394.6399841	0.21
395.4355164	4.19
396.1228027	32.99
398.7284851	0.08
399.5239258	0.30
404.9459534	0.48
413.8222961	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
99.0364990	1.50
100.9307632	12.23
107.2148743	0.26
112.9795990	21.61
115.2200775	0.44
118.8661957	22.95
124.8667145	2.80
125.9109955	0.63
129.0287933	0.12
130.8509979	7.25
142.9790649	26.30
148.2496643	0.40
149.0221558	4.88
161.0314941	20.91
178.9422760	100.00
183.0552216	0.42
183.9458618	0.16
220.7597961	0.19
280.5415039	0.84
281.2267761	0.57
340.2185974	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0988
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
149.0179138	0.08
150.9473267	0.83
151.9410248	0.11
152.8617706	0.15
163.3004150	0.13
165.0578003	0.07
166.9183655	0.03
169.1636963	0.08
170.0242462	0.07
173.0335693	0.03
178.9690094	2.35
179.9608917	0.24
185.0618286	0.03
185.8800659	0.03
187.0601959	0.03
188.9945526	0.32
191.1175842	0.07
192.3205261	0.11
193.1647644	0.02
196.0230103	0.02
201.0144958	0.03
203.0148315	0.15
207.2000275	0.25
208.9270630	0.02
210.9401245	0.40
212.2210236	0.05
213.1175385	0.22
215.0781860	0.04
216.9406891	0.09
218.0525208	0.02
222.5451202	0.07
226.1560059	0.11
227.4190063	0.13
228.1152496	0.04
229.0844421	0.14
230.3949280	0.17
231.1889038	0.06
233.0992432	0.12
243.0983276	0.18
244.0989685	0.13
245.1150208	0.15
246.1706696	0.12
249.0803375	0.02
254.0675354	0.08
255.0732727	2.67
256.1321106	0.69
257.0815430	0.50
261.4211121	0.03
263.3089600	0.05
266.3621216	0.05
269.0687866	0.07
271.1583557	4.22
272.1117859	1.00
273.1338501	0.82
274.1801453	0.11
275.0998535	0.08
281.1044617	0.14
283.0578918	0.78
285.0092468	0.17
287.0425415	0.04
292.1636658	0.15
293.8777466	0.02
296.0670166	0.09
297.1768188	0.30
298.4577026	0.57
300.0741577	79.21
301.0683899	100.00
302.0929565	15.44
302.7044678	0.14
309.0629578	0.06
311.1483459	0.22
313.1415710	0.29
314.1132507	0.10
315.3808594	0.06
319.2654419	0.06
320.1861267	0.07
323.0825500	0.03
324.1732178	0.02
325.3066406	0.59
326.1673889	0.11
328.6299438	0.02
331.0885925	0.16
335.4006958	0.08
337.2866516	0.03
339.1279907	0.05
340.2421265	0.04
342.0899963	0.06
343.1845703	2.08
344.3581238	0.28
347.9241943	0.03
349.0140991	0.17
351.2995300	0.02
353.3892822	0.05
355.1779480	0.10
356.3326416	0.08
359.1372681	0.09
360.1491699	0.07
361.1386719	0.09
367.0950928	0.24
368.9666138	0.15
370.1472473	0.03
373.3293762	0.15
379.2159424	0.31
381.2846375	0.12
385.7190857	0.25
395.0677795	0.33
396.6763000	0.11
398.1158752	0.02
400.1354065	0.04
401.4920959	0.07
409.3066101	0.22
417.2221985	0.06
420.4096375	0.06
425.1294250	0.08
427.1855164	0.32
428.3871155	0.03
438.2662659	0.07
445.1708374	76.52
446.2012329	20.03
461.2841187	0.19
463.1564636	15.32
464.3130188	2.41
470.3223572	0.05
487.3228149	0.34
488.2998962	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0776
Annotation	3-Galloylgallocatechin
Peak:m/z	Relative Intensity
131.0773163	0.11
134.7540436	0.40
137.0320892	0.12
139.1556854	0.13
146.9449921	0.68
149.0673523	0.84
150.7550201	0.05
161.0538788	0.47
163.0373993	19.24
170.7834930	0.05
177.0911865	0.24
179.0648804	5.00
186.8864441	0.11
189.1432495	0.23
191.0486145	0.16
201.1205139	0.10
203.0870972	4.31
205.0180511	0.84
215.0957489	0.74
219.0599976	6.76
221.2096252	0.10
231.2143860	0.37
232.9289246	1.03
249.1034546	0.15
259.1589661	1.07
267.1850891	0.03
275.1302490	1.51
277.1645203	48.04
291.2058411	0.06
293.0765991	70.46
295.0457153	100.00
311.0334778	4.21
325.2699890	0.29
352.2617798	0.17
396.6367798	0.12
441.3251953	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	790.2092
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1079712	0.19
224.1988983	0.08
227.1419678	0.24
229.6945648	0.18
235.3766479	0.11
237.0957794	0.16
241.1039886	8.50
242.1044922	1.81
246.1865692	0.12
246.8308411	0.06
252.5508270	0.29
253.2615814	0.10
255.1502686	0.33
256.1280518	0.58
259.1549377	0.11
265.9621277	0.22
267.9089661	0.09
268.9725342	0.02
270.2680664	0.08
272.9312439	0.45
274.0321045	0.49
275.1834412	0.23
280.0843506	0.03
280.9506531	0.06
281.9624023	0.09
287.0455017	0.46
288.3716125	0.07
293.1315918	0.03
294.2966309	0.04
295.9692383	0.09
298.0377502	0.05
298.8958435	0.13
300.2695923	0.47
302.2956543	0.10
312.0029907	0.02
315.1042480	0.25
316.1430054	0.31
317.0935974	0.03
318.1255493	0.06
325.2653503	0.05
326.0570679	0.05
327.1715088	0.15
328.1068726	0.21
329.2722778	0.17
329.8754883	0.05
331.1697388	0.12
344.3478394	0.04
346.0945435	0.22
346.8195496	0.13
348.3168640	0.12
351.2050171	0.16
356.3739014	0.05
357.4238281	0.15
358.4011841	0.07
361.2545776	0.05
363.9556885	0.11
365.0007629	0.06
371.4741821	0.04
372.1250610	0.07
374.2656860	0.67
375.2373047	1.26
376.2250366	0.28
382.1989136	0.03
384.1811523	0.72
385.0510864	0.44
390.2884521	0.09
402.1101074	14.05
403.2598877	4.14
405.1444702	0.10
415.4815674	0.19
416.3223267	0.03
419.1150513	2.16
420.2096558	2.10
421.2100830	0.63
423.3194580	0.15
425.2457275	0.37
433.0554199	0.14
437.2939453	0.23
438.2210083	0.06
443.2976074	0.24
444.3549194	0.13
448.0465088	2.04
449.2697144	0.65
450.8441162	0.08
452.1696167	0.05
462.2743530	0.02
464.8331299	0.71
466.1235352	0.66
467.4186401	0.18
468.2114868	0.63
469.2454224	0.10
473.3716431	0.24
478.7433472	0.12
479.4423828	0.38
480.6109009	0.11
485.2218628	0.37
486.1474609	0.89
487.0595703	0.34
489.1571655	0.02
491.4853516	0.25
492.1852417	1.62
493.0217285	0.96
495.1609497	0.09
497.5548096	0.05
505.5413208	0.08
508.3474731	0.09
509.3676147	0.58
510.1984863	0.77
511.3765259	0.04
512.3427734	0.05
514.2680664	1.83
515.3353271	1.14
518.2758789	0.09
519.2747803	0.14
524.3874512	0.14
525.3941040	0.18
526.1638794	0.09
527.2177734	0.52
528.6148682	0.03
530.5078125	0.20
531.3171997	0.05
536.3895874	0.28
537.2978516	0.15
539.8659058	0.29
543.4016113	0.15
548.3140259	0.23
549.2379761	0.18
553.6199341	0.61
554.2669067	2.30
555.1302490	1.15
555.7764282	0.12
558.1690063	9.50
559.3010864	4.95
564.2056885	0.14
566.0796509	0.39
567.2854614	0.33
568.9629517	0.38
571.2725220	14.12
572.3089600	9.31
573.2981567	0.84
575.3598022	0.07
576.0513306	0.22
581.1819458	0.17
582.2700195	0.53
583.4144897	0.09
589.2534180	15.36
590.3648682	7.16
598.1508179	2.06
599.3180542	2.10
600.1643677	3.07
601.2813721	0.96
617.2477417	12.91
618.2496948	6.83
618.9500122	0.04
625.3070068	0.99
626.2757568	1.10
627.1708374	0.23
628.5055542	0.33
630.2632446	0.05
631.3813477	0.16
638.2047729	0.61
639.4872437	0.33
643.2339478	2.27
644.1157837	5.05
645.2197876	2.78
653.5414429	0.23
654.5764771	0.19
656.1191406	0.07
661.2378540	100.00
662.2186890	43.61
662.8544922	0.32
669.0419312	0.04
669.6916504	0.07
671.3463745	2.50
672.4472046	1.99
682.3738403	0.03
689.3963013	0.21
697.1978760	0.18
700.2969360	5.06
701.4003906	1.85
702.2780151	0.13
703.8214722	0.13
715.3154907	9.70
716.3247070	3.85
718.2330933	7.11
719.2812500	3.18
726.8987427	0.40
728.3157349	0.72
729.3474731	0.20
730.4042969	0.25
741.8293457	0.05
745.7909546	1.37
746.4478760	2.44
747.3886719	1.35
754.5354004	0.08
755.3806152	0.08
772.2059937	1.19
773.2901611	1.36
774.3054810	0.35
791.3046265	5.70
795.6221313	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1149
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1276245	0.10
189.0663910	0.07
191.0468445	0.18
205.0440063	7.75
218.9002228	1.03
219.5199738	0.06
221.1268768	0.04
227.1636047	0.21
229.3114929	0.06
231.0385742	0.67
235.4347687	0.08
243.1865997	0.31
244.9738464	0.17
246.3065948	0.06
249.1578064	1.62
251.2925720	0.07
269.1698608	0.82
269.8003540	0.29
271.3409424	0.84
273.1529236	0.07
275.0360718	0.59
277.3582764	0.12
281.1828918	0.08
289.2720642	0.05
293.1757202	9.31
294.2782288	0.08
297.1760864	0.83
299.2523804	0.22
306.2190552	0.28
311.0481567	5.29
312.4371033	0.06
314.1245728	0.53
315.1488342	5.57
317.1827393	0.27
319.2306519	0.22
325.4253845	0.06
329.3995361	0.06
339.3171387	0.08
341.0662231	5.40
343.2208252	0.16
354.8527832	0.22
356.2258301	0.06
357.1838989	0.66
359.2009277	100.00
376.8659668	0.26
378.2062988	0.33
383.5704346	0.36
399.1877441	0.61
401.3517456	0.41
411.2414551	1.37
413.6770020	0.08
417.2722778	0.09
433.2959595	0.11
443.6346436	0.19
445.2133789	0.53
446.1542358	0.05
448.2399902	0.32
455.0783691	1.41
459.8009644	0.14
460.9601440	0.12
473.1198730	18.32
474.1719971	0.24
476.1020508	0.07
477.1489868	2.66
479.3355713	0.22
486.5767822	0.15
489.0015869	0.70
490.3693848	1.96
491.2457275	15.53
492.3718262	0.59
495.1090698	0.40
503.3464966	1.49
519.5205688	0.10
520.2611694	0.71
521.1390991	8.73
522.4456177	0.39
537.0596924	0.71
538.1387329	0.06
539.3461914	1.34
540.9884644	0.14
560.5455933	0.09
564.2056274	0.35
565.2944336	0.06
566.3743896	0.34
567.2666626	0.73
576.3176270	0.43
578.9364624	0.19
606.1461182	0.37
607.0874023	0.70
608.8665161	2.20
609.5229492	0.05
617.4046631	0.28
620.3681030	1.23
624.2377319	0.19
632.4663696	0.15
634.9603882	3.97
635.6945190	0.21
653.1195679	0.73
653.7531128	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.0861
Annotation	Kaempferol-3-Glucuronide
Peak:m/z	Relative Intensity
165.2209473	0.03
243.2157288	0.01
258.164093	0.02
259.1463623	0.04
284.8900757	0.09
287.0573425	100.00
287.9229431	0.00
299.0172424	0.01
315.2543335	0.08
317.1005249	0.02
319.1119385	0.05
331.0994873	0.01
339.0803833	0.01
353.2944031	0.03
360.430481	0.04
368.7355042	0.02
371.3042297	0.01
398.0731506	0.05
422.2097473	0.03
445.2124939	0.12
446.6059265	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	655.3699
Annotation	Russelioside A
Peak:m/z	Relative Intensity
245.2030487	0.03
263.2610779	0.09
279.2446594	0.11
281.1516418	0.08
282.3764954	0.09
307.2639465	0.04
327.3833008	2.61
328.3424683	0.43
337.4922485	0.06
375.5887451	0.03
396.4237061	0.03
399.7824097	0.12
401.4078369	1.19
402.4866333	0.16
406.1467896	0.24
412.6729736	0.10
423.5985718	0.11
429.2818604	0.31
431.4017334	0.09
432.3883057	0.10
439.3452759	0.10
441.4388428	0.05
447.3949585	15.57
448.3712158	3.90
449.5952759	1.99
450.7131348	0.26
453.4295044	0.22
454.6198730	0.04
457.3819580	0.26
458.0626831	0.07
461.5385742	0.16
471.6842041	0.34
472.6365967	0.04
473.4293823	1.25
474.4368896	0.69
475.4645386	3.51
476.5731812	0.78
477.4277344	0.24
487.3171997	0.02
488.5162354	0.10
491.4020996	1.28
492.4415894	5.98
493.4552002	100.00
494.5455933	24.26
503.6842041	0.04
505.4817505	0.09
507.1006470	0.13
512.0011597	0.07
517.4474487	0.54
518.5494385	0.38
519.5581055	0.07
529.7069702	0.20
534.2459717	0.28
535.2964478	0.87
536.4107056	0.44
547.5671387	0.06
548.2621460	0.12
551.5251465	0.11
556.7593384	0.08
560.2940674	0.13
565.6283569	0.31
568.3969727	0.22
570.5278931	0.05
580.3820801	0.14
582.8936157	0.05
584.2752075	0.06
596.6577148	0.16
603.5530396	0.05
611.6016235	0.04
612.3835449	0.11
620.3010254	0.34
622.3760376	0.09
623.2659302	0.08
624.3936768	0.08
634.7302246	0.41
637.4794922	1.65
638.6456909	1.09
656.4507446	2.48
657.5018311	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8946
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9594727	0.17
146.8862915	0.19
158.9497833	0.13
175.0014648	3.08
215.0408325	0.03
228.9086609	0.04
245.0321045	0.21
259.9528809	0.05
261.0401001	0.09
273.0469971	2.25
274.0454407	0.34
275.8647766	0.03
277.0506287	0.09
288.9513550	30.65
290.1452637	0.02
304.9385681	100.00
329.1650085	0.05
345.0075073	0.56
346.8379822	0.01
348.0348816	0.04
362.8098755	0.10
371.9748840	0.10
373.1713257	0.03
374.1414490	0.11
389.8760071	0.07
391.0295105	0.01
401.0782166	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0721
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
90.9739609	0.04
106.7078323	0.04
107.9325104	0.22
108.9937134	6.85
114.7244720	0.04
123.0573196	0.23
125.0850906	0.08
135.0525970	0.07
138.9884796	0.09
149.1929321	0.13
151.7536316	1.57
152.8967590	100.00
162.9826965	0.15
168.8429108	0.03
175.0859985	0.02
176.9489441	0.16
180.0764923	0.06
181.0520935	0.13
182.9762268	0.17
184.1606140	0.05
185.1372223	0.05
193.5113068	0.02
195.0114899	0.45
199.1977234	0.05
206.9424438	0.05
217.2163391	0.21
217.9280701	0.03
219.2368164	0.02
221.0045776	0.03
224.8446045	0.03
227.1366577	0.03
228.2351074	0.17
237.3031006	0.06
241.0239258	0.06
253.0520935	0.03
255.4384155	0.15
257.2177429	0.04
267.1871643	0.03
269.1261292	0.27
271.1036987	0.38
272.2362671	0.05
285.8557129	0.05
292.2110901	0.14
297.0142212	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	366.1752
Annotation	Deutziol
Peak:m/z	Relative Intensity
104.8273087	4.09
107.8348618	0.32
108.9277344	0.87
110.9556808	0.81
112.9668121	0.63
114.9395065	0.06
116.7845459	0.06
118.7465820	0.06
120.8331146	0.34
122.9092026	0.26
126.9259186	5.38
130.9982300	0.49
132.9538422	0.53
135.0095062	0.89
136.9831848	0.29
139.0343933	0.75
141.0266113	1.30
142.8572388	0.09
144.9472656	1.94
146.9728394	0.18
149.0855408	0.56
151.0564270	2.82
152.0127869	0.09
153.0730743	0.26
155.1397400	0.59
158.8382111	0.27
163.1805115	0.33
167.0028839	0.94
168.5439148	0.24
169.1595154	0.17
170.7909088	0.04
172.8429260	0.47
177.0056305	0.15
179.1835632	0.59
181.0779572	0.42
182.9556885	0.29
184.3940430	0.16
185.2263031	0.24
189.1064911	0.08
191.0915833	3.13
195.3798218	0.09
196.6834106	0.32
201.0748901	0.09
203.2390442	0.06
209.0677795	15.35
212.3601990	0.61
213.1426849	0.14
218.9950562	0.20
227.1079712	5.22
230.8899231	20.07
245.1753845	1.98
248.1485596	7.56
248.9985962	19.22
249.6015320	0.07
251.3697510	0.14
252.8606262	0.09
254.9072571	0.06
257.1743164	0.06
262.5442810	0.07
265.9721985	5.72
267.3027344	0.23
269.1563721	44.90
277.0733643	0.18
285.2238159	0.65
287.2843018	0.55
295.1158447	80.94
301.4502258	0.12
305.1810303	0.07
313.0364380	100.00
313.6773682	0.43
325.1330566	0.49
328.8777466	0.18
330.5126953	8.36
331.1293335	48.44
343.1936951	0.08
347.1787109	0.08
348.2376709	0.40
349.0715027	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.2538
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
188.7819214	0.15
210.0352325	0.03
212.8711548	0.11
215.1610413	0.14
223.1912537	0.04
253.0925751	0.07
263.2792969	0.06
265.1189575	0.08
266.4531250	0.06
280.0607300	0.07
307.2433472	0.11
312.4682617	0.14
327.1526489	0.11
331.0861816	0.12
349.4576416	0.07
356.1649170	0.11
357.4088745	0.04
361.0869751	0.05
362.0949097	0.03
363.3157959	0.16
364.6671143	0.05
365.3383789	0.08
386.2449951	0.14
393.6370239	0.03
395.4600220	1.60
396.4275513	0.23
404.3348389	0.05
408.5563354	0.06
411.4337158	0.08
416.4458008	0.09
424.5947876	0.10
425.4431763	0.07
427.1312256	0.07
434.4759521	0.11
440.4462891	0.07
442.2144775	0.31
446.8734741	0.11
447.6475220	0.19
448.4645386	0.27
452.4521484	0.10
454.4940796	0.38
459.3669434	0.24
461.4376831	0.11
462.6170654	0.09
467.4509277	0.07
473.4945679	0.45
474.3074341	0.78
475.5062256	1.18
476.4418335	0.41
477.3412476	0.17
478.7241821	0.14
479.3963013	0.03
483.3063354	0.03
487.3355103	4.34
488.2958984	1.92
489.4342651	0.24
490.5402222	0.04
491.6069336	0.03
492.5556030	0.18
493.5935669	0.16
501.5906372	1.66
502.4689331	0.42
503.3669434	0.39
506.0184326	0.43
507.3869019	0.12
508.6058960	0.21
513.5513306	0.50
514.4552612	0.11
515.2936401	0.58
516.4732056	0.03
517.4610596	0.58
519.3886719	20.83
520.3912354	6.94
521.6088257	0.86
523.5688477	0.03
529.3103027	2.36
530.3829956	1.30
531.4503784	0.57
532.1705933	0.25
533.3237915	0.42
534.4205322	0.45
535.3585815	0.42
536.2509155	0.13
537.3860474	0.03
541.7794800	0.11
545.5089722	0.11
547.4219971	100.00
548.3950806	36.33
549.4539185	2.50
550.1379395	0.03
551.4109497	0.74
552.4656372	0.06
553.8099365	0.06
557.4237671	0.29
561.4495850	3.13
562.3997803	2.07
563.5344849	0.40
564.3503418	0.11
565.5593262	0.04
566.4939575	0.03
567.4240112	0.09
571.3074341	0.14
573.3887939	0.03
574.7518921	0.39
575.4132690	2.65
576.5579834	1.52
577.4766235	0.56
579.4103394	93.58
580.4080811	36.23
581.3538208	2.91
589.3656006	5.54
590.4147949	2.35
591.5854492	0.11
592.5260010	0.25
609.4680786	3.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	212.92
Annotation	Unknow
Peak:m/z	Relative Intensity
87.2009735	0.03
123.7975311	0.11
124.9380493	0.03
127.0552979	0.15
128.8586578	100.00
129.8359680	0.04
139.9875031	0.10
145.0290375	6.79
154.0489197	0.17
155.1951447	0.20
165.0011902	0.12
169.0829315	0.06
195.2016144	0.10
195.8704224	0.06
196.8647003	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	210.06
Annotation	Unknow
Peak:m/z	Relative Intensity
73.8017883	0.04
82.8733444	0.02
83.9417114	0.02
85.9812012	0.03
89.7308350	0.08
102.1091614	0.08
103.8772430	0.09
105.8337708	0.03
109.9874878	0.04
114.1050415	0.05
120.0906525	0.02
124.9854736	0.06
128.1021729	0.03
132.1045990	0.05
134.0042267	0.05
136.1946564	0.03
139.9834747	0.04
142.0708618	0.02
146.8426971	0.32
147.8058014	0.04
149.1055603	0.08
149.8939819	0.41
150.9548798	0.51
152.3190460	0.08
153.9337769	0.02
162.1115570	0.06
164.0032501	0.09
165.1111603	0.03
167.8383942	0.53
168.8267517	0.56
174.9351807	7.15
179.9832611	0.08
182.1242828	0.17
186.5766907	0.39
187.9884186	0.06
192.8091125	100.00
193.4360352	0.30
200.3783417	0.26
201.2163239	0.02
218.4620972	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	815.1508
Annotation	Unknow
Peak:m/z	Relative Intensity
253.3526459	0.06
323.3101501	0.06
341.1229248	100.00
342.0267944	0.24
343.2230835	0.03
353.1473999	0.14
358.2796021	0.07
410.2172241	0.03
433.1846313	0.02
460.9746704	0.04
473.1570435	0.03
477.0480957	0.13
493.0251465	0.05
494.8502808	0.31
515.4409790	0.05
521.2599487	0.41
533.5058594	0.05
602.6484985	0.10
613.6095581	0.03
635.3612671	0.15
641.4328003	0.21
643.5236816	0.19
653.2099609	0.10
665.1580200	0.11
683.4323120	0.07
701.0939941	0.06
725.4837036	0.01
771.1661987	0.12
773.6539307	0.02
783.4769897	0.03
797.1511841	0.04
800.0325317	0.06
814.8803711	0.20
816.0009766	3.07
816.6911621	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1812
Annotation	Lactulose
Peak:m/z	Relative Intensity
350.6980591	0.22
363.0955200	13.88
381.2192383	8.08
451.2888794	0.17
453.3956909	0.07
483.4212036	0.08
525.3020020	66.34
543.3098145	100.00
614.9822388	0.17
645.1835327	0.14
687.2418823	0.11
706.4390259	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.09
Annotation	Cordyformamide
Peak:m/z	Relative Intensity
108.9910660	0.03
109.8286743	0.04
110.8363647	0.05
112.2609177	0.02
127.0402222	0.11
127.9166107	0.12
128.8226624	0.04
134.4284973	0.04
135.1293182	0.47
136.0383148	0.67
137.0000000	0.03
143.7668762	0.04
145.1103821	0.03
147.1171417	0.08
154.1295166	0.03
155.3086243	0.01
156.0440369	0.09
161.0744781	0.37
162.0014954	0.38
163.0491028	0.10
171.9889069	0.03
172.9918976	0.37
174.0709686	0.26
175.0438995	0.10
179.0379333	3.27
180.1030579	3.51
181.0371246	0.41
191.0556946	100.00
192.0459900	76.89
193.0287476	15.39
216.0433044	0.06
244.1642151	0.05
245.1018982	0.02
251.1304016	0.03
290.9897461	0.05
295.1796265	0.15
296.2352295	0.01
310.2492371	0.10
336.7279663	0.02
337.3580322	0.15
340.3069458	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.9102
Annotation	Unknow
Peak:m/z	Relative Intensity
83.0390778	0.02
114.1099777	0.07
123.0879822	0.18
129.9096985	0.02
135.9250183	0.10
141.8808136	0.02
163.1828613	0.08
163.9915466	0.08
166.0082397	0.09
168.0440063	0.03
173.0851440	0.03
178.9333649	0.05
181.0752258	0.08
197.0441589	0.20
198.1224060	0.14
205.0879822	0.07
211.2211914	0.05
221.2924194	0.02
222.6911621	0.18
225.2881470	0.06
226.3372192	0.07
227.0793457	0.06
231.3186340	0.18
232.3379517	0.11
233.5290222	0.08
237.8788757	0.17
239.0643005	0.34
240.1735840	0.20
241.1006165	0.39
242.0057068	0.29
243.8093567	100.00
245.0084534	0.26
248.4183960	0.27
249.3226929	0.06
255.0131836	0.17
256.7745667	0.52
257.7876282	0.18
258.8449097	0.22
261.5655212	4.03
262.3092651	0.11
262.9985962	0.47
263.9131470	3.60
266.4357300	1.15
267.0436401	1.40
267.7282715	0.24
269.1840820	0.19
270.2413330	0.66
271.0374756	0.73
272.6696777	1.23
273.3468018	0.29
275.5051270	0.51
276.2036133	0.47
278.3372803	0.03
279.1891174	0.24
280.1979675	0.21
280.9276123	0.04
281.5586243	0.04
284.4023438	0.12
285.0478210	0.28
288.6929016	0.24
293.4650269	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8807983	1.26
290.8095703	7.35
374.6867065	2.53
455.3018188	0.03
458.5935059	31.86
459.3328247	0.30
460.0691528	0.21
461.1921997	0.28
496.8814697	0.18
520.3475952	0.13
540.5641479	0.04
542.4880371	100.00
543.6630249	0.82
580.8041382	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.0682
Annotation	15-Deoxylactucin-8-sulfate
Peak:m/z	Relative Intensity
100.9264984	0.01
105.1693954	0.03
107.1288452	0.01
109.1071320	0.01
116.6494446	0.02
121.0827408	0.01
128.0358276	0.03
135.0932159	0.02
136.8464355	0.04
141.0339966	0.03
142.9782715	0.11
145.2000427	0.08
147.0112305	0.04
154.0546417	0.04
154.9329529	0.01
156.3564453	0.06
157.1069031	0.11
157.9145203	0.03
159.0951538	0.19
161.0114899	0.08
163.0080566	0.01
164.8060608	0.03
166.4093628	0.02
167.1107635	0.07
169.1570587	0.47
171.1783905	0.14
172.9894104	0.32
175.0414734	0.23
178.8122711	0.13
179.4373169	0.01
182.0428772	0.11
183.1047821	0.04
185.0357056	0.12
186.9863129	0.50
189.0644073	0.04
195.1798401	0.01
197.1099091	3.60
198.9467773	0.20
201.0151215	0.55
210.0275269	0.01
211.0406799	0.04
213.4050903	0.04
215.1479797	1.54
217.2082520	0.01
225.0634460	1.24
228.0785828	0.01
233.3165894	0.01
243.0599976	100.00
253.1785278	0.05
256.9393921	0.01
261.1331482	7.59
265.1257629	0.03
271.5196533	0.03
274.0643921	0.01
280.1517944	0.03
282.1192017	0.01
282.9487915	0.02
284.1668701	0.05
285.2639465	0.05
293.1159058	0.02
294.0995483	0.02
295.2744751	0.04
298.4561157	0.04
299.4347839	0.05
303.2225647	0.02
304.1955566	0.01
305.0912476	0.07
306.0537720	0.01
309.2043457	0.09
312.8973083	0.03
322.2013855	0.05
323.1928101	0.51
323.8465271	0.01
326.2362671	0.01
340.2308655	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	923.15
Annotation	Luteolin 7-glucuronide
Peak:m/z	Relative Intensity
462.5354004	0.04
474.4398804	0.03
922.9957886	100.00
923.6799316	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
96.94459534	1.06
99.07937622	1.02
116.8900299	0.46
126.1538391	1.15
148.9237518	0.84
149.9929047	0.91
155.0795135	1.58
157.1073303	0.68
163.0635529	0.52
165.0871887	2.54
178.2243652	1.51
179.0324249	0.73
180.0607758	2.57
180.999527	3.20
193.2276001	1.89
195.0216522	1.76
206.1676788	0.98
207.1360168	8.59
208.1472321	11.46
209.2102814	13.71
215.6127777	1.09
216.9945984	1.59
222.0803223	12.32
223.1612091	20.83
224.0005341	4.99
233.3087921	4.66
234.1992188	0.53
236.0697784	0.42
251.072403	100.00
252.1919708	33.65
253.0832367	8.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
90.97785187	0.47
93.11562347	0.99
95.00942993	1.38
96.90185547	2.75
98.57133484	0.19
100.9466858	0.25
102.9666367	0.70
107.2645416	1.15
111.0952301	1.74
112.9764557	0.21
121.1127625	0.69
123.1390228	0.94
125.0548935	1.58
126.9255753	0.39
128.9865112	1.27
131.0570984	0.29
135.2943115	0.33
138.9432983	2.15
140.9446106	1.40
143.2125549	0.69
144.8941345	0.33
147.2087097	1.21
149.1076965	1.61
151.2756042	0.32
152.2254639	0.37
153.1157227	0.17
154.9008789	2.29
156.9534607	2.85
160.9244843	0.68
165.0571747	0.60
167.0019226	1.28
169.0813599	1.99
171.3402252	1.07
175.0445251	1.01
179.0325317	1.44
180.988678	2.21
183.064209	4.00
184.7876587	0.50
187.0033722	0.35
189.3339844	1.31
191.0796967	0.21
193.248764	1.83
195.2348328	0.58
197.0027466	0.85
198.997345	1.98
201.2591095	0.17
203.0102844	1.28
209.2294006	2.61
211.0334473	4.06
212.9876099	1.52
215.2680969	0.88
217.1115723	0.92
222.5811157	0.49
225.1680298	3.45
227.3254395	0.55
229.4253845	0.72
237.1421814	2.11
238.1003418	0.96
239.3357849	4.29
241.0774231	1.11
242.8713074	0.69
247.2377319	3.20
249.3025513	0.36
251.1265869	4.13
253.2080383	9.24
254.9849243	1.55
257.1403198	3.13
265.0836792	2.96
269.0184937	1.16
270.128479	0.66
275.1755371	32.40
275.8571777	0.35
280.9593201	0.50
283.1920471	1.27
284.4734497	0.35
287.9900208	0.67
293.208252	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2678
Annotation	[10]-Gingerdiol
Peak:m/z	Relative Intensity
104.8254700	0.66
106.8208771	0.61
108.9716873	2.09
111.0646439	0.74
112.9956665	0.39
117.0034637	0.43
119.0627899	1.42
121.0700607	1.96
123.0063095	3.84
124.9748077	0.77
126.8203430	0.17
127.8188782	0.11
128.9753571	0.35
130.9081116	1.38
133.0890350	1.47
135.0460358	3.08
136.9845276	2.23
138.9579315	0.26
141.0997162	0.16
145.0545959	2.49
147.0179749	3.08
149.1165161	4.29
151.0264435	1.35
153.0747375	0.50
155.2745972	0.30
157.2266235	0.19
159.0330200	4.81
161.1594238	4.73
163.0710144	7.64
165.1041260	2.01
167.0965118	0.32
169.1443176	0.09
173.0839233	7.54
175.0818481	2.06
177.0939941	5.79
179.0487823	1.07
181.1045685	0.26
183.0173492	0.16
185.2698822	0.49
187.1729736	5.23
188.8692932	0.78
191.0664062	1.80
193.2020111	0.52
195.1884155	1.54
197.2013245	0.30
198.9157410	0.24
201.1726379	2.91
203.1479492	1.35
205.0607910	0.93
209.0453186	0.76
213.2514954	0.40
215.1254578	1.07
217.2110596	0.15
219.2024231	1.36
220.9843445	0.10
223.1568298	0.44
225.2732544	0.18
229.0562439	0.37
231.1156311	0.24
233.1860657	3.06
237.4711609	0.14
239.2261353	0.41
240.3987732	0.03
241.2425842	0.25
243.1380005	37.07
243.7535706	0.08
245.2557983	2.31
251.4908142	0.16
253.2267151	0.53
257.0718079	0.48
259.0148010	0.41
261.1966858	100.00
263.2707214	4.25
265.1061707	0.84
267.1875000	0.24
269.4107056	0.24
270.2686462	0.12
271.1282043	0.20
273.1289673	0.12
275.1713257	0.03
277.3583984	0.19
279.2577515	11.44
281.3999634	0.26
283.4015503	0.16
287.4170532	0.05
291.2086182	0.48
293.3916321	0.29
297.1719971	1.29
299.2689209	1.00
305.1089478	0.27
307.2424927	0.17
309.6603394	0.51
311.1145325	0.18
312.0155945	0.05
317.1315918	5.27
328.9511108	0.10
330.0184326	0.32
335.3727417	49.89
344.2105408	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1196
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1190643	0.14
109.1169281	0.11
111.0947952	0.13
112.8328781	0.07
127.0013428	0.18
140.9849548	0.15
143.0117798	0.18
151.1137085	0.13
155.1529846	0.06
161.1122131	0.09
171.9278259	0.07
173.2674866	0.39
179.0190887	0.13
187.1290131	0.03
191.0860291	100.00
195.5526733	0.06
197.2351685	0.05
207.3473206	0.07
211.0002747	0.15
220.8891602	0.12
238.7401123	0.09
251.9382019	0.10
253.0972290	0.06
258.8717651	0.04
268.2334595	0.03
270.9797974	0.06
279.0065308	0.06
280.2717896	0.03
281.0030518	0.07
283.0138550	0.07
303.0614319	0.06
305.0001221	0.13
308.2799377	0.26
309.1337280	0.07
314.8760986	0.04
321.1027222	0.05
325.0147705	0.23
327.2467041	0.10
339.4972229	0.31
351.0818176	0.32
353.5564270	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.1647
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9340515	0.10
131.8975067	0.17
133.9886169	0.53
143.0002136	0.12
145.9516907	0.06
150.1405029	0.24
158.0896759	0.06
159.0544891	0.10
177.1441345	0.16
179.1709290	0.18
186.6261597	0.10
201.1668396	0.13
218.0503845	1.48
233.1942749	0.09
234.0833130	0.28
236.1116943	0.52
247.1344604	0.47
248.3495483	0.22
254.1306763	1.12
255.4872437	0.03
264.1137390	0.05
268.9743652	0.24
272.1084595	100.00
273.0594177	0.09
282.2348633	0.10
283.6335754	0.18
300.1645203	0.03
302.1150208	0.42
303.1089783	0.17
308.1764221	0.77
312.8231812	0.28
314.1894836	0.54
316.8380432	0.12
325.7794189	0.03
352.4906616	0.27
353.2662048	0.28
354.3052673	0.07
360.4786072	0.12
362.0550232	0.12
369.3852234	0.44
370.4542847	0.10
374.1719055	0.13
380.3999939	0.14
381.5964050	0.09
387.3922119	0.10
389.2727966	0.13
389.9248047	0.31
393.0667114	0.27
396.3609924	0.33
398.8352966	0.32
402.0824890	0.05
403.8745422	0.41
407.0455017	0.07
410.0318604	0.06
412.3093567	0.06
414.9435425	0.16
416.1112366	0.51
417.0737915	0.12
424.3572693	0.35
425.0766296	0.10
434.6430054	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0025
Annotation	SC-58125
Peak:m/z	Relative Intensity
129.0249176	0.02
173.0736542	1.51
184.9026794	0.03
190.9595337	100.00
219.0464935	0.03
255.0911255	0.06
272.9239502	0.28
289.1865234	0.13
297.2799377	0.08
299.2136841	0.03
317.1432495	0.89
318.8181763	0.07
322.9795532	0.06
332.0101318	0.21
340.8079224	0.04
359.0679932	0.14
368.1251831	0.15
384.7457886	0.21
403.1588440	2.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1387
Annotation	Luteolin 7-galacturonide-4'-glucoside
Peak:m/z	Relative Intensity
230.9648895	0.10
245.8971405	0.05
252.1724243	0.06
263.1244507	0.21
265.1657410	0.17
273.1347351	0.15
287.1511536	23.66
299.2469482	0.16
303.1780701	0.25
308.2710571	0.04
311.1705933	0.04
329.0541687	0.27
330.3565674	0.03
389.1181030	0.06
411.7252808	0.35
428.4862061	0.05
433.2393188	0.36
437.4550171	0.19
445.3763428	0.10
449.1738281	100.00
454.2819214	0.10
462.9084473	1.39
463.5177612	0.80
471.0637207	0.03
475.2846680	0.04
477.3186646	0.05
478.1413574	0.22
491.4407959	0.06
495.1705322	0.08
529.2911987	0.04
532.1406250	0.09
534.4967041	0.19
538.5391235	0.11
539.3362427	0.11
552.4445190	0.07
563.4885864	0.11
566.5895386	0.04
577.3302002	0.32
588.2150879	0.12
592.4933472	0.31
606.4140015	0.48
607.2600708	1.33
635.8165894	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.19
Annotation	Apiosylepirhododendrin
Peak:m/z	Relative Intensity
130.7978668	0.04
133.9114990	0.09
149.0593262	0.29
150.1493530	0.31
151.0935364	0.06
155.0285187	0.16
162.8802185	0.97
163.9207001	0.79
164.9618530	0.04
175.2714996	0.24
176.3824768	0.06
179.0407867	0.41
179.9474335	0.09
180.7884827	0.11
190.1959839	0.21
203.1232910	0.29
204.1316376	0.26
205.0347290	0.06
206.1015167	0.12
209.1383362	0.09
219.1260681	0.15
220.0629120	0.37
221.1130524	0.33
227.1918640	0.07
232.8981323	0.15
234.1279602	0.05
234.9180603	0.09
259.2325439	0.08
260.2079468	0.22
263.2409363	0.03
264.2191162	0.13
267.0621643	0.16
271.2575378	0.05
275.0974731	0.17
277.0773315	2.61
278.0530396	2.50
279.1349487	1.75
287.2723999	0.08
293.1821594	5.30
294.0712280	5.60
295.0455017	7.84
296.0718994	8.77
297.1364136	3.90
300.4431152	0.09
301.1822510	0.16
307.2084045	0.04
311.2349243	0.55
311.9874268	0.11
313.2080688	0.34
315.2149963	0.07
319.2948303	0.07
323.1411743	0.22
325.0250854	0.04
327.0601501	0.06
341.3748779	0.13
343.3915710	0.13
345.3083801	0.09
355.3590088	0.41
356.3111267	0.14
361.0496216	0.05
362.5758057	0.14
363.2286987	0.24
369.3908997	0.04
371.3523865	0.12
372.3522034	0.07
373.2616577	0.54
377.9572449	0.50
380.7310181	0.05
386.0610657	0.35
391.1905823	0.09
394.3779602	0.11
396.4590759	0.16
398.3251953	0.27
399.2827759	0.36
401.3666687	0.09
409.2862854	0.28
412.7121887	0.40
413.3525085	0.73
415.2782898	100.00
417.3281555	1.19
426.7226257	0.03
429.2012634	0.07
433.5230713	0.29
438.2822876	0.49
439.2301941	0.17
440.4107361	0.31
441.3699036	0.51
444.2657471	0.24
445.3174133	0.49
447.4584351	0.09
461.0808411	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	817.0756
Annotation	Unknow
Peak:m/z	Relative Intensity
251.2866821	0.10
265.1859741	0.04
268.3763123	0.16
283.2413025	0.30
284.2210388	0.09
287.1868896	0.74
301.3128357	0.18
336.8819580	0.14
345.0891724	0.07
375.6131592	0.06
380.0486450	0.05
381.2189941	0.26
395.1544189	0.14
397.3897705	0.43
398.3686523	7.42
399.3952026	0.82
424.5444946	0.09
436.2716064	0.24
451.2055054	0.34
462.7439575	0.39
466.0069580	0.11
478.2966919	0.60
479.2844238	0.05
499.3388672	2.86
509.5056763	0.25
551.1721191	0.10
570.3739014	0.11
580.0718384	0.10
582.5253296	0.23
597.1000366	0.27
598.2312012	0.49
599.2858276	0.05
610.8256226	0.28
615.0529175	0.20
621.5494995	0.06
634.9320068	0.30
637.3421021	0.14
641.3645020	0.05
646.3430786	0.05
647.8746948	0.37
653.4571533	0.35
665.4951172	0.42
676.3334961	0.16
679.2655029	0.49
682.7478027	0.41
686.5919800	0.12
694.7542114	0.14
703.9223022	1.26
708.1624756	0.37
709.6578369	0.23
718.5806274	0.60
719.3041992	0.10
720.6027222	0.15
730.9850464	0.12
739.9301147	0.96
744.3515015	0.43
746.2915649	0.24
748.3363647	0.61
751.0447998	0.06
752.5283203	0.36
754.2002563	2.67
755.2839966	0.67
755.9512329	0.30
756.7103271	0.21
759.3323975	0.87
765.9846191	0.40
771.0437622	0.32
772.9375610	0.29
774.9717407	1.44
775.6072998	0.72
781.4513550	0.12
785.0014038	0.21
792.5670166	0.39
793.6725464	0.21
799.1831665	0.67
800.8178711	0.05
818.6896362	0.28
825.5115356	0.11
835.0286865	0.27
848.4373779	0.61
849.1657104	0.10
871.8466797	0.24
872.7205200	0.29
883.7946167	0.23
901.7321167	1.35
902.6857300	0.75
905.2096558	0.26
914.9414062	1.13
918.8536987	0.18
927.0209961	3.08
927.7263794	0.30
938.6288452	0.55
960.3537598	0.53
962.5373535	0.24
967.4729004	0.70
968.7568359	0.15
972.5839844	0.82
973.7966309	0.32
976.3187866	15.70
977.3181152	1.16
977.9273071	0.04
984.5942383	0.18
1004.8017580	0.46
1018.1364140	2.21
1018.9492190	0.16
1026.8770750	100.00
1027.7255860	10.33
1028.7241210	0.50
1030.7712400	0.36
1038.2114260	0.06
1043.4057620	0.38
1044.9646000	0.33
1053.5600590	0.20
1066.2791750	0.40
1066.9847410	0.91
1075.4793700	0.06
1077.5310060	0.14
1079.0395510	0.19
1098.8891600	0.36
1118.0412600	0.06
1122.0426030	0.49
1126.7382810	0.20
1130.1862790	1.74
1131.0012210	1.28
1131.8488770	0.30
1133.6623540	0.27
1137.6231690	0.20
1139.5372310	59.48
1140.3220210	3.51
1141.3623050	0.59
1142.2851560	0.79
1143.9006350	0.23
1151.6965330	0.31
1160.2944340	0.24
1181.0538330	0.11
1245.0965580	0.09
1251.7642820	0.23
1266.0357670	0.18
1288.1107180	0.25
1294.6202390	0.05
1332.8216550	0.05
1343.8126220	0.09
1345.7806400	0.21
1347.1253660	0.06
1350.9379880	0.14
1414.5195310	0.18
1429.1907960	0.05
1432.9464110	0.16
1478.6163330	0.47
1486.1284180	0.19
1522.5556640	0.17
1531.0526120	0.23
1561.7912600	0.53
1612.0692140	0.26
1628.5513920	0.24
1658.0272220	0.44
1660.6644290	0.20
1707.0833740	0.17
1725.4909670	0.10
1769.3768310	0.14
1827.4816890	0.27
1855.1296390	0.20
1903.1008300	0.08
1909.4019780	0.09
1962.2116700	0.05
1984.9016110	0.90
1995.9998780	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.0884
Annotation	Unknow
Peak:m/z	Relative Intensity
135.0545959	0.16
136.8845215	1.93
139.0854492	0.08
148.9623413	0.38
150.0004120	1.57
151.0013885	1.19
151.8572998	0.08
155.0520325	0.07
158.9901581	0.19
160.0598755	0.08
161.1231995	0.05
163.0896301	0.53
164.7575073	0.03
166.0090332	0.15
167.1279297	1.71
167.9389954	7.30
169.0140076	3.91
169.7499695	0.02
172.7897186	0.09
175.1842041	0.15
176.7867126	0.12
178.9595032	0.87
181.1247864	0.42
188.3849487	0.14
191.0897522	0.16
192.0062866	0.13
192.9704590	0.16
195.0444031	0.63
198.9935455	0.12
201.2713013	0.04
207.0504456	0.06
209.0883636	0.30
210.0757599	0.09
211.1691132	0.73
221.1646576	0.36
222.9474182	0.27
226.5451508	0.14
227.1600189	0.07
230.9860077	0.05
233.2225342	0.10
239.1261902	0.53
241.0639343	0.16
242.9661255	0.20
244.9857788	0.04
247.2886963	0.07
251.0252380	0.07
253.0552979	0.23
254.1716919	0.03
257.1550903	0.06
269.1479797	1.01
270.3482971	0.10
271.1672058	1.18
273.2826538	0.04
275.0283813	0.06
276.8264160	0.03
281.1552124	10.88
283.2868042	0.51
287.0531006	4.43
288.1648254	8.43
289.1844177	2.57
295.0812073	0.47
298.3259888	0.08
299.1712036	0.11
303.2732239	0.27
309.2337341	0.27
313.2160339	18.00
314.0499878	0.29
315.2494507	0.09
319.0524902	0.03
320.0835571	0.03
325.3129578	0.04
326.9726868	0.06
329.2227173	0.38
331.1375122	100.00
332.2179260	1.60
335.2119751	0.04
341.0645142	0.05
342.9500427	0.04
345.4000854	0.11
346.4800110	0.04
349.7293091	0.12
355.1765442	0.24
356.1250916	0.13
358.2825317	0.07
359.2313232	0.13
360.1541138	0.36
361.1142883	0.17
362.0342407	0.11
363.2545166	0.27
367.1485901	0.04
369.6734009	0.44
373.2215881	0.47
378.1583252	0.75
387.2848206	0.06
389.2959290	0.19
390.3832703	0.27
391.2897949	0.13
397.4567261	0.03
402.3089294	0.03
404.2016602	0.33
405.2197876	1.07
406.2318115	0.46
407.3180847	0.87
409.0738220	0.04
412.2178955	0.04
413.0873108	0.03
415.2108154	0.82
427.0652161	0.15
428.6770935	0.13
431.3163757	0.24
432.6519775	1.31
433.2846375	21.96
434.2536316	1.24
436.2810364	0.06
452.2449036	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	325.0929
Annotation	6-O-p-Coumaroyl-D-glucose
Peak:m/z	Relative Intensity
92.9533691	0.11
111.0115967	0.03
118.9525909	9.46
122.0594025	0.07
133.2045898	0.02
142.6880951	0.02
144.9735413	0.15
149.1575928	0.15
161.1895142	0.02
162.9377747	100.00
171.9121704	0.09
173.0320435	0.02
175.2070007	0.04
178.9447479	0.02
180.0961151	0.05
182.9777832	0.17
186.9625397	0.14
188.9104309	0.09
192.9981842	0.03
203.1390991	0.02
205.0422363	0.43
207.0624084	0.09
208.9271240	0.05
215.0822449	0.02
217.0907593	0.04
219.2554321	0.03
232.8669128	0.05
235.1908264	0.03
239.5121460	0.03
251.0328674	0.19
252.9020386	0.05
262.0656128	0.13
264.9995728	0.24
265.9921875	0.10
266.9002380	0.07
269.1881714	0.04
278.0155945	0.04
279.1044312	0.66
281.1958618	0.34
293.1352539	0.02
296.1672058	0.05
297.2090759	0.08
304.9632874	0.09
306.8662109	0.47
309.5859375	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	212.92
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8351440	100.00
144.7437744	0.05
169.2745972	0.02
185.0116882	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8103333	18.04
207.8769836	0.99
208.8542480	23.69
209.5885773	0.02
212.8148651	0.07
251.0115356	0.10
290.7396240	61.21
292.1804504	24.68
292.8074341	100.00
293.7298584	0.05
325.2837219	0.32
330.7092285	0.05
346.2422485	0.11
353.8176270	0.12
356.0255737	0.05
366.0812378	0.12
373.2726135	0.03
373.9783020	0.18
374.5866699	6.43
376.1642761	11.91
376.8359680	35.64
400.8037720	0.03
413.8508301	0.21
414.8379211	0.45
443.0110779	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.3099
Annotation	Unknow
Peak:m/z	Relative Intensity
227.1421661	0.03
251.1600342	0.04
257.3322144	0.10
269.2077026	0.33
276.9636841	0.07
296.3656006	0.28
298.0647888	0.13
311.2761230	0.07
313.3774414	0.22
315.1562500	0.06
333.0014648	0.04
339.2955322	0.03
348.4085083	0.03
353.3322754	0.20
371.2937622	0.04
382.3621826	0.23
387.3880615	0.05
394.5161133	0.06
429.2998657	0.04
440.1721802	0.29
447.5731812	0.25
463.3042603	0.25
473.5653687	0.03
477.3483887	0.07
481.4841919	0.04
501.2217407	0.28
504.4621582	0.08
508.3741455	0.22
511.2316895	1.64
521.3117065	0.52
523.1154785	0.11
534.4243164	0.08
545.6563721	0.16
549.7080078	0.05
552.3731689	0.14
553.3275757	0.28
555.4393311	1.24
564.4343872	0.25
567.1050415	0.06
569.1278687	0.19
573.2003784	0.22
575.0503540	0.10
579.3828735	0.09
586.6199341	0.12
591.0404663	0.11
595.3347778	0.36
597.4635010	0.13
598.5032349	0.62
600.3406982	0.57
609.2677002	0.04
609.8978882	0.13
614.4844360	0.26
616.3664551	0.80
617.0158081	0.06
618.4607544	1.33
619.1594849	0.11
639.0819702	0.10
662.5958252	0.07
705.5006104	0.07
709.4981079	0.10
715.4088745	4.59
716.5307617	0.13
731.5656128	0.11
733.4636230	8.58
738.2045288	0.15
749.6784058	0.16
759.4441528	3.34
761.4254761	0.09
764.9794312	0.39
766.5543823	0.14
775.4155884	0.05
777.3582153	16.69
778.0930176	0.04
795.4462891	100.00
796.8559570	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.13
Annotation	Traumatic Acid
Peak:m/z	Relative Intensity
92.80569458	1.03
96.88601685	0.55
99.05924988	0.49
110.9684906	0.31
112.8706665	0.39
124.6551056	0.62
125.2943878	0.89
128.9789429	1.05
136.8744965	0.15
139.2908478	0.15
139.8947754	0.72
153.0698853	0.74
155.1656036	0.68
159.0784454	1.03
165.1398621	100.00
170.7863007	0.26
172.0346832	0.62
179.155304	0.59
181.0806732	0.99
183.1425629	85.36
190.9002228	0.74
199.1376343	0.80
207.0066376	8.17
209.156601	26.23
211.2881165	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
81.79216766	0.46
149.2302704	0.38
160.7475128	0.53
178.989212	3.27
180.1526642	1.83
181.3402863	1.48
182.0289764	1.05
183.1785126	0.81
192.8801575	1.27
194.7448425	0.97
195.3795624	0.99
206.1424713	2.69
207.1700134	10.43
208.0804901	5.11
208.9773712	0.94
222.2880249	2.09
223.0563202	8.28
224.108902	1.95
233.030899	3.88
251.0667725	100.00
252.0135956	6.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.0723
Annotation	Aesculin
Peak:m/z	Relative Intensity
104.9788513	0.02
133.0616608	0.10
162.0699463	0.02
176.9877014	100.00
178.0649719	0.04
207.2145538	0.04
219.1158142	0.06
227.2668762	0.05
229.2961731	0.01
231.1081543	0.02
247.1234436	0.02
251.0014038	0.01
260.2660828	0.02
278.1492310	0.02
293.5065613	0.04
295.0809937	0.06
321.3877563	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.142
Annotation	Delphinidin 3-(6-malonylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
219.0324402	0.03
247.1718750	0.11
268.9867554	0.05
297.4028931	0.08
301.1356812	1.22
314.1981812	0.11
353.4063721	0.04
369.3347778	0.05
406.0552368	0.08
410.0114136	0.15
431.3920898	0.07
433.4539795	0.06
484.2473755	0.10
505.3247070	0.16
531.3522339	0.25
535.2819214	0.10
536.2892456	0.11
547.4606934	0.16
548.2627563	0.64
549.4198608	0.12
563.1575928	0.07
573.3387451	0.28
577.1866455	0.09
587.1693115	0.10
609.0347290	0.13
619.2940063	0.07
623.4577026	0.12
624.3519287	0.13
625.2520752	0.46
633.4098511	0.22
644.4007568	0.15
648.9738159	0.54
664.5530396	0.47
667.2952271	100.00
667.9425659	0.52
678.4822998	0.17
690.2207642	1.01
691.0588989	0.12
692.8125610	0.23
693.5967407	0.05
711.1674194	14.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.2557
Annotation	Kanokoside D
Peak:m/z	Relative Intensity
188.7635345	0.02
190.7831573	0.10
195.1037598	0.11
221.1304474	0.04
237.2103119	0.06
254.9112244	0.02
266.8942261	0.04
285.1346130	0.02
293.0419922	0.06
338.5300903	0.01
357.2878418	0.84
358.1962280	0.04
375.2905884	12.69
376.3645020	0.05
391.2238770	0.02
395.2513428	0.12
399.3616333	0.76
408.6558228	0.02
413.3263550	0.05
417.2881470	100.00
418.3298950	0.19
419.2303467	0.06
420.4718628	0.03
431.4306030	0.09
441.0770874	0.09
442.8227539	0.06
444.0725708	0.02
445.3970337	0.03
447.1548462	0.56
448.1813965	0.13
459.2012329	1.21
460.8038330	0.02
461.7756958	0.06
465.6506348	0.03
483.4394531	0.05
485.4876099	0.07
488.5639038	0.08
489.1949463	0.31
491.7416992	0.03
501.2684937	0.26
503.5001831	0.09
519.1119995	0.95
519.7632446	0.05
521.4291382	0.05
531.3777466	0.03
534.0349731	0.05
537.2631226	0.04
538.2053833	0.02
543.5261841	0.02
545.5275269	0.02
561.1898804	0.21
564.6437378	0.04
576.9199829	0.07
578.4735718	0.29
579.1007080	1.77
580.0515747	0.09
586.2600708	0.08
587.0380859	0.06
593.4079590	0.10
594.2955933	0.03
604.0675049	0.04
605.9915771	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.09
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
181.2119141	0.07
225.4662476	0.04
229.3406372	0.05
253.0447235	0.03
262.7370911	0.11
269.0088501	0.03
271.2921143	0.06
287.2709961	0.05
291.5143433	0.10
293.4642029	0.02
299.3964844	0.08
301.0907593	0.19
311.4620361	0.13
319.6181641	0.14
322.2874146	0.02
323.5198975	0.05
325.2130127	0.02
336.2615356	0.03
346.0767212	0.02
353.3470459	0.09
357.1954956	0.14
359.6791992	0.02
362.5185547	0.06
369.4119263	0.10
376.1300659	0.08
383.4387817	0.09
387.0512085	0.19
405.9486694	0.02
417.4012451	0.24
423.2210083	0.06
425.5898438	0.09
432.1243286	0.22
451.3012085	0.06
462.4482422	0.02
463.3059082	0.83
471.2323608	0.13
475.4482422	0.05
476.1492310	0.02
485.2495728	0.12
488.4421997	0.14
489.5215454	0.40
502.5431519	0.37
503.4777222	0.54
505.1996460	100.00
505.8404541	0.12
506.5989380	0.11
507.2576904	0.04
513.3615112	0.05
514.4381104	0.02
518.6764526	0.08
523.1275024	0.23
528.9765015	0.65
529.7451172	0.03
530.5466919	0.19
531.2371826	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.91838074	0.46
95.14299011	0.59
104.9222717	0.35
106.6921005	0.23
109.069519	1.36
111.0923996	1.15
119.1411285	0.88
123.0835266	0.66
125.1102905	1.14
126.6560822	0.60
129.0726013	1.08
130.8707886	1.79
133.0123444	1.48
135.1652985	0.64
136.9129944	0.78
139.0076904	2.19
140.8976135	0.92
143.0202026	1.58
145.1522827	0.42
148.9516602	1.38
152.0570679	0.23
152.989151	0.73
155.1271362	1.30
156.8681335	0.96
158.9798889	0.70
160.9779205	0.73
163.0593567	0.69
165.1448669	1.18
167.0407715	1.20
168.8762512	0.39
171.3561096	0.20
174.9765625	0.34
176.8549805	0.18
177.6238556	1.73
181.0144043	2.73
183.2783966	0.25
185.1707458	0.65
187.2310944	0.17
193.1424408	0.77
195.1163788	0.25
196.1712952	0.26
197.115509	3.27
201.2458496	0.30
203.2976074	0.50
204.880188	0.99
207.2420349	1.82
208.9570312	0.97
211.1499329	5.57
213.2894287	1.60
215.2822266	0.22
219.1828918	0.90
222.96521	1.79
225.2037659	0.60
227.1585083	0.89
229.2412109	1.11
231.3043213	0.45
233.1972656	1.11
235.1925049	1.38
237.1860046	2.69
239.2196655	0.73
241.1915894	2.00
247.4294434	1.08
251.1972656	2.38
253.2293396	7.64
265.1982727	0.99
267.3126831	1.52
269.0124207	1.71
275.2641296	16.65
277.2374878	0.19
283.0405273	0.30
289.1084595	0.36
293.2162476	100.00
293.842926	0.31
296.209198	0.22
301.7478333	1.52
302.775116	1.13
312.2730713	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.0616
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
70.7600098	0.10
86.8980713	0.18
88.9288635	0.75
98.9512024	0.02
101.0042572	0.13
102.9594727	0.04
105.3779602	0.03
106.8394928	0.30
112.9141083	0.79
118.9298706	2.42
124.8507996	0.10
130.8610535	0.20
143.0503082	1.96
148.9981232	0.29
160.9655914	3.40
164.9340363	0.13
170.1675568	0.02
178.9936066	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
105.0491638	0.49
117.088974	0.15
142.9116974	0.28
146.0508881	0.20
149.0289307	1.61
149.8704224	0.47
165.0778656	0.23
167.2976379	0.08
169.0867462	0.86
179.2337494	0.63
180.0339813	1.71
181.1992188	0.34
183.1322784	0.12
191.2971191	0.09
193.2353516	0.55
194.2318268	0.56
195.0851288	0.86
196.2489777	0.34
205.0807037	0.11
206.0940857	1.28
207.0396881	10.27
208.1062469	8.54
209.013855	3.51
209.9703827	0.32
222.0713348	5.97
223.0441742	9.03
223.9589691	0.99
236.2647705	0.82
251.0771027	100.00
252.1870117	22.75
253.1884766	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1511
Annotation	Barlerin
Peak:m/z	Relative Intensity
139.0042419	0.01
155.1109161	0.04
159.2044067	0.01
164.9712830	0.01
179.3465881	0.03
185.0739441	0.03
191.0482788	0.03
221.3520966	0.04
239.1270752	0.02
255.1300659	0.03
267.1729431	0.06
269.1398621	0.04
271.0845642	0.13
284.2321472	0.02
285.2093811	0.21
294.0299072	0.01
314.2658691	0.02
315.1071472	0.02
319.1177368	0.06
349.3027954	0.03
352.9951782	0.02
357.0534058	0.02
366.2006531	0.06
373.1778564	0.05
401.1940918	100.00
402.1186523	0.02
403.3269348	0.03
406.8350220	0.04
408.4498901	0.06
411.2020874	0.04
413.3054504	0.04
419.0633850	0.06
428.1290588	0.22
429.6355591	0.03
437.1306458	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	331.0669
Annotation	2-Galloylglucose
Peak:m/z	Relative Intensity
94.8866577	0.45
97.2021561	0.07
104.8918076	0.04
106.8869324	0.21
107.9810257	0.38
108.9419479	0.20
110.9765854	0.20
117.0038452	0.07
120.8613510	0.36
122.1700211	0.23
122.9708557	1.45
124.8908997	15.41
135.2398071	0.05
135.8648529	0.08
136.9983521	1.52
138.9727173	1.43
146.8786011	0.09
148.8069458	0.22
149.9907227	4.11
151.0638733	3.07
155.0723877	0.08
161.0521545	0.13
163.0598145	0.47
165.0194397	0.29
167.0770264	12.31
167.9357605	60.64
169.0155029	19.32
173.1604767	0.07
175.0723572	0.16
177.1661072	0.06
178.9574890	0.94
180.1459351	0.62
180.9647522	3.14
190.8556213	0.10
191.9268341	0.14
193.0473022	3.05
197.0949097	0.12
199.1343689	0.06
203.1435242	0.27
204.7815857	0.22
209.0752869	0.07
209.8337708	0.08
211.1234741	6.63
215.0696106	0.09
217.0906372	0.30
219.0002747	0.05
223.1554260	1.90
223.8881531	0.09
229.0380249	0.05
234.9543152	0.31
235.8987122	0.17
241.1415710	1.67
242.8317871	0.11
244.1175232	0.04
247.0073853	0.06
253.1324158	0.78
255.1943054	0.05
269.1893616	0.94
271.1101990	0.16
276.7603149	0.05
284.9842224	1.67
287.2452698	2.92
290.9838257	0.06
295.0196533	0.31
313.1082764	100.00
314.1923218	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.917
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1294861	0.02
158.9705200	0.22
160.0292053	0.03
175.0196991	1.49
176.0824280	0.08
198.8627777	0.01
228.8554077	0.02
230.0062561	0.01
244.9588928	0.26
245.9256897	0.11
261.1996765	0.01
273.0321655	3.52
274.0465698	1.17
288.9598999	100.00
289.9606323	15.62
290.7559204	0.00
300.9434814	0.00
313.8522034	0.01
328.9293823	0.05
330.0687561	0.05
346.8313904	0.10
347.9310303	0.02
358.6752014	0.02
359.6567078	0.02
374.6929932	0.01
384.9597473	0.01
385.9096985	0.02
391.1422729	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	517.14
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9045715	0.21
167.0974731	0.11
186.0615540	0.30
234.1288757	0.16
251.2159882	4.35
258.9378662	0.17
267.3258972	0.68
268.1247559	0.12
269.1338501	15.75
285.2155762	1.10
296.7668457	0.22
301.3851929	0.19
303.3495483	1.09
311.0803833	5.49
319.3238525	0.53
329.1887817	0.28
335.0502319	0.09
341.0694580	3.36
342.9378662	0.13
346.9641724	0.11
349.2207031	0.18
353.1458130	1.27
355.1558228	0.77
372.4035645	0.58
373.1437378	0.24
376.5521851	0.60
377.2216797	1.71
394.9804077	0.55
413.2932739	1.10
419.4293213	0.14
431.1881104	100.00
434.2093506	0.28
435.2283325	0.89
437.2994995	3.20
445.1174927	0.41
451.3508301	0.41
453.0659180	0.34
455.2992554	10.13
457.2742920	0.92
472.5361938	6.08
473.3056030	94.37
481.2597656	1.41
498.3736572	0.92
499.2246704	2.35
500.0663452	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.121
Annotation	Luteolin 3'-methyl ether 7-glucuronosyl-(1->2)-glucuronide
Peak:m/z	Relative Intensity
191.1489716	0.07
191.9522400	0.03
196.9992676	0.02
197.9979858	0.02
201.1625824	0.14
210.8244934	0.03
217.1418762	0.06
227.4412842	0.11
228.0413818	0.03
229.0099792	0.27
232.8960876	0.21
245.2754059	0.07
245.8811798	0.05
247.2953796	0.03
251.0594940	0.09
253.8188477	0.04
255.1925659	0.09
257.2857361	0.15
267.1146240	0.05
273.1412048	0.22
277.1951904	0.24
281.2831116	0.18
283.0594482	0.12
284.3538513	0.08
290.9954224	0.05
291.9663391	0.03
293.0581055	0.18
299.2031860	0.19
301.0895996	100.00
306.3292236	0.03
311.1518555	0.94
312.2524414	0.09
313.2485962	0.29
315.1170044	0.11
319.8594971	0.13
321.2817993	0.03
325.0222778	0.19
328.2102356	0.11
341.0868530	0.92
341.8572388	0.02
343.1076050	3.27
351.3879395	0.11
353.2822266	0.08
355.1434326	0.21
357.1383057	0.04
360.0813599	0.15
363.0133667	0.04
367.1955566	0.28
369.1779785	0.34
371.2698364	1.51
373.2651367	3.67
379.0904541	0.10
379.9238281	0.32
380.8997803	0.19
385.2644653	1.16
390.2363892	0.11
392.2633057	0.09
394.5437622	0.03
397.2339478	2.93
403.2752686	0.05
406.6809082	0.16
415.0872192	0.26
422.1889038	0.10
423.3611450	0.05
431.1328735	0.28
431.9815674	0.07
443.6552124	0.03
446.7119141	0.05
459.1125488	0.41
464.5534058	0.03
474.9987793	0.08
477.1390381	81.39
477.7838135	0.21
480.3143311	0.04
488.8850098	0.05
490.0665283	0.09
491.1879272	0.32
493.3422852	0.09
500.8780518	0.09
503.3992920	0.20
519.2135620	1.95
520.3919067	0.11
524.1168823	0.34
531.0557251	0.02
533.3610229	0.03
535.5781250	0.07
536.2328491	0.15
537.1959229	0.73
543.0342407	0.11
547.3904419	0.24
549.2644653	0.87
561.1278687	0.32
565.3167114	0.20
573.3063965	0.67
585.0686646	0.22
589.5291138	0.12
591.2991333	0.10
599.1807251	0.10
606.2670288	0.11
607.1831665	0.06
609.2976685	0.18
621.0726929	0.10
634.1954956	0.24
635.3528442	0.19
653.1428833	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.2103
Annotation	Unknow
Peak:m/z	Relative Intensity
179.7718811	0.16
193.0715942	0.37
206.8581696	0.17
216.6447754	0.21
222.0203400	16.70
229.1051636	0.54
235.0865784	0.21
241.1402283	1.09
242.9732361	0.27
253.2198334	0.61
259.1465759	0.28
271.0028687	3.87
287.9033203	3.06
288.8661804	12.52
294.8669434	0.34
296.1481323	1.58
306.2296753	1.68
306.8999634	6.23
324.9465332	100.00
342.1688232	9.07
342.9432373	45.73
343.9886475	0.26
402.6215820	0.29
412.1894531	0.32
433.3100586	1.12
450.6566162	2.46
458.2005005	1.66
475.4158325	10.43
476.1837158	19.92
486.4520874	1.21
487.1774902	0.76
496.0881348	0.47
504.7133179	1.87
531.9643555	0.26
540.1999512	0.32
545.0294800	0.24
573.7167358	1.23
620.2751465	1.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9211884	23.51
213.0234833	0.06
254.9390259	0.15
290.7652588	100.00
296.8663635	0.05
306.8332520	0.02
314.6960144	0.02
338.8890991	0.64
346.0104980	0.06
352.9096680	0.09
368.8965454	0.05
373.2601013	0.05
374.6358948	20.65
375.3363342	0.04
394.8355408	0.13
398.8708801	1.10
412.7462463	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.164
Annotation	Crispine C
Peak:m/z	Relative Intensity
95.0085907	0.55
110.7841263	0.03
113.0413055	0.01
125.3186722	0.02
127.0092468	0.04
133.2130737	0.02
134.0373230	0.03
138.9969482	0.13
143.0426178	0.15
143.8418884	0.03
144.9102936	0.02
146.1584473	0.01
147.9088745	0.01
149.0001526	0.01
152.8722382	1.49
157.0151825	0.59
158.9372559	0.22
162.9529114	0.24
165.2894592	0.03
166.8209839	0.02
171.0870972	0.07
173.1139526	0.08
176.9242249	0.02
179.0497131	0.09
181.1404419	0.04
185.1159058	0.02
187.3614197	0.03
189.0438995	0.10
191.0170135	0.08
193.2655029	0.08
195.0568542	0.37
197.3266907	0.01
199.3457642	0.05
207.0496521	0.35
209.1065063	0.08
211.0682983	0.49
212.4630432	0.05
215.1269836	0.04
217.2718201	0.42
223.2101135	0.10
224.9207458	0.10
227.1312561	0.04
229.1928406	1.41
231.1930237	0.03
233.3602600	0.02
235.1086731	13.33
238.2779541	0.02
243.1347656	1.31
245.1116028	0.03
245.9797363	0.05
247.1453247	0.08
248.0899963	0.07
249.2059631	0.01
253.1143188	100.00
260.0605774	0.06
261.2264709	0.05
266.1790466	0.07
268.9382935	0.15
270.9989014	35.72
272.1671448	0.02
280.0024414	0.09
285.8007812	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7787781	2.69
296.6950073	41.81
297.3359375	0.17
302.9592285	0.20
323.2491455	0.19
356.7068481	0.33
369.2725220	0.07
380.6473999	100.00
381.3437500	0.26
382.8740845	0.27
386.9126587	0.89
446.3909302	0.20
454.7767334	0.30
462.2164307	0.78
463.9119263	6.56
464.6070557	48.77
485.1541748	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.0895
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
301.0735168	0.14
463.0953979	0.40
505.1885376	100.00
531.4794312	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.0785
Annotation	Lactulose
Peak:m/z	Relative Intensity
201.0210876	53.33
218.9753723	100.00
290.5128174	16.96
291.1357727	38.74
363.2027283	1.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	525.1204
Annotation	Unknow
Peak:m/z	Relative Intensity
152.8741150	1.55
191.0079651	3.80
192.0003967	2.93
264.0617676	2.90
273.0917358	5.81
300.1635742	0.44
353.3283081	3.04
354.2383423	9.72
363.1579590	100.00
364.2857056	0.84
381.2540894	0.50
423.6038208	1.24
527.0852661	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1641
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
174.8572235	0.02
179.1510620	0.03
195.2345581	0.03
218.0388184	0.04
230.4463654	0.03
249.0115662	0.02
250.4333496	0.05
253.3486786	0.01
254.1190491	0.01
255.1116028	0.04
271.1149292	0.06
287.1091309	24.77
288.1192627	4.84
295.2454834	0.03
300.1839600	0.01
312.3316956	0.05
329.3204956	0.08
330.2257690	0.06
340.1527710	0.11
342.2998047	0.04
346.3245239	0.05
347.1747437	0.05
348.2561646	0.09
353.2125854	0.08
367.2125854	0.02
370.0755005	0.01
379.9578247	0.03
382.3947144	0.01
383.3516235	0.09
389.4004517	0.05
397.1436768	0.28
398.1965332	0.02
400.2223511	0.04
402.1126099	0.03
404.4215698	0.02
413.3275757	0.04
414.3599854	0.04
415.0662842	0.23
419.4531250	0.02
420.5671387	0.02
423.2715454	0.05
428.4028931	0.07
431.2158813	0.08
432.1850586	0.10
433.2924194	3.36
434.3795776	0.69
449.0627441	100.00
450.1908569	20.66
457.3699341	0.03
460.0834961	0.02
465.0931396	0.17
467.3875122	0.35
468.2211914	0.03
470.8018188	0.11
473.4604492	0.02
475.3204346	0.16
481.2664795	0.02
484.0708618	0.01
486.3200073	0.02
489.3427124	0.07
498.7356567	0.01
502.3961792	0.01
503.4060059	0.23
504.2681274	0.02
507.4831543	0.03
515.0570679	0.12
520.2971191	0.02
520.9376831	0.01
521.6921387	0.08
522.3007202	0.03
522.9259644	0.07
530.9503784	0.07
532.0509644	0.05
533.1119385	0.05
534.2622070	0.02
536.3158569	0.02
543.3727417	0.04
545.3452759	0.01
551.5078125	0.02
552.2935181	0.02
559.2373657	0.12
560.2916870	0.06
561.6417847	0.09
566.1431274	0.03
577.5137329	0.21
578.3955688	0.56
606.2529907	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0356
Annotation	Bracteatin
Peak:m/z	Relative Intensity
93.3032455	0.04
106.9933472	3.41
108.9738464	0.13
120.9533539	2.01
124.9438324	0.91
147.0994110	0.20
148.7671509	0.48
150.9468536	60.86
151.9922180	0.24
154.8025208	0.11
158.7687073	0.23
161.0242310	0.17
162.9738007	0.53
163.9497375	0.11
164.9597168	0.35
167.0971375	0.13
171.0908813	0.08
175.1532745	0.64
178.9235840	100.00
180.0096588	0.30
183.0353394	0.39
186.9105530	0.34
188.1090851	0.05
189.0940247	0.55
191.0200653	0.71
191.8850555	1.63
193.0330505	5.88
201.0564575	0.53
206.1722412	0.08
211.0799866	2.30
212.1200256	0.10
213.0720215	1.11
214.4689026	0.56
215.1400757	0.56
226.0048828	0.03
227.1852722	0.41
228.0969543	0.59
228.9917297	5.00
230.2469788	0.12
231.1916504	0.04
239.0324097	3.30
240.1920166	1.03
241.3665161	0.28
243.0236206	0.57
244.0274658	0.14
245.0969849	0.61
254.9971313	4.24
255.9441528	0.66
257.0554199	13.70
258.0706482	0.12
258.7733459	0.08
265.0014648	0.15
266.1862488	0.16
270.1599121	0.08
271.1317139	3.06
272.0823975	1.37
273.1270142	21.29
274.2561035	0.07
283.1647949	8.82
301.0454407	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1067
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
100.3691864	0.02
118.9104691	2.82
120.0631104	0.06
121.0398407	0.04
126.9939728	0.09
133.1446991	0.12
134.9049377	0.03
143.9034424	0.04
146.9134216	100.00
148.8886719	0.04
159.3244934	0.03
160.2023010	0.02
163.6265717	0.13
165.1348572	0.19
177.0772705	0.09
182.8475952	0.05
185.9682007	0.02
190.8469238	0.03
195.1724548	0.02
205.1464081	0.02
207.1877594	0.02
215.4698181	0.14
223.3179626	0.12
225.9732666	0.02
227.2992859	0.04
241.1748657	0.02
249.0832825	0.16
253.3206787	0.07
257.3032227	0.03
265.1913452	0.14
269.0803223	0.03
270.8594055	0.03
273.9680176	0.09
277.0660400	0.03
278.0747070	0.12
279.0645752	0.13
283.2686768	0.08
289.2607422	0.01
292.3375854	0.05
293.0988770	0.22
294.1539917	0.10
295.3261719	0.05
296.2106628	0.03
297.1492004	0.25
298.1859131	0.05
302.4660034	0.10
303.2471619	0.36
305.1068420	0.03
307.3471069	0.21
309.2024231	0.13
310.5319824	0.10
320.3935547	0.27
321.2811890	0.87
322.1622314	0.15
324.4924316	0.06
329.9581909	0.12
331.0924072	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.329
Annotation	Unknow
Peak:m/z	Relative Intensity
279.0538635	0.02
337.8887329	0.02
373.3858032	0.01
472.5842896	0.03
473.3482666	0.03
474.0427856	0.03
483.2409668	0.01
486.9622192	0.02
487.8062134	0.01
489.6014404	0.12
504.2164917	0.01
505.4844360	0.01
533.4873047	0.06
551.4573975	0.01
592.4181519	0.01
593.5494995	0.07
594.4471436	0.02
606.5890503	0.32
610.7714844	0.02
637.4362183	0.05
638.4235840	0.07
643.7101440	0.08
650.4695435	0.43
651.5233765	0.33
670.4776001	0.03
682.3981323	0.57
683.5546265	0.04
685.4629517	0.05
701.3368530	0.02
727.3466797	0.03
729.5040283	0.08
731.3198242	0.01
745.5724487	0.23
755.4197998	0.10
761.4517212	0.06
769.6829834	0.07
773.4498291	12.73
774.0859985	0.03
805.3773193	100.00
806.0958862	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1068
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
287.0864563	100.00
288.1134033	16.98
329.2426758	0.02
330.2565308	0.01
369.2329407	0.01
380.0149841	0.02
383.6491394	0.02
406.8621521	0.01
413.4176941	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
112.7857819	0.07
115.0426712	0.03
118.9128647	0.28
125.1158295	0.10
131.1412048	0.19
143.0628662	0.19
149.2229767	0.11
160.9845886	0.68
178.9978943	4.92
196.9255219	0.40
215.0019684	6.37
221.0823975	0.15
250.7605591	0.03
262.4711914	0.05
280.8419495	0.04
323.1412354	0.02
341.1519470	100.00
341.7532959	0.14
358.9850159	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
144.9368286	0.08
212.7856445	6.33
229.1383972	0.21
296.7192078	69.03
297.3652039	0.65
378.9728088	0.15
380.6229553	100.00
381.3505859	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1826
Annotation	Scopolin
Peak:m/z	Relative Intensity
216.9921570	0.06
219.0646973	0.15
237.0344086	0.10
239.3755493	0.05
271.2960815	0.03
309.0189209	0.03
323.1755981	0.22
339.5721436	0.06
348.9828491	0.06
353.0893555	100.00
354.2400513	0.36
375.4886475	0.03
393.4074707	0.02
463.3305054	0.01
470.0830688	0.06
497.5176392	0.05
513.1524658	0.03
515.2468872	1.34
516.3253174	0.26
533.3012695	0.01
545.2119751	0.10
663.5747070	0.09
708.0420532	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
701.0714111	52.88
967.4005737	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0885
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
143.0967865	0.02
148.9073181	0.03
162.9448242	0.02
167.1450348	0.01
173.0091705	0.02
185.1966858	0.04
186.3695068	0.02
190.9386292	0.02
191.9658813	0.01
203.2685547	0.03
204.9349365	0.01
211.1878357	0.04
212.1738586	0.01
213.1255951	0.04
217.2470245	0.02
221.2496490	0.02
229.1583710	0.03
235.1443481	0.03
239.3899689	0.01
241.1154022	0.05
244.9321289	0.02
253.2275391	0.03
253.9015503	0.03
257.2857056	0.02
265.2911377	0.08
271.0926208	0.02
273.3088989	0.01
283.0296326	0.12
285.0545654	0.04
286.2409363	0.04
288.9441833	0.01
293.1195679	0.01
295.2929382	0.03
299.0538940	0.05
301.0959167	100.00
302.1797791	0.13
306.1394653	0.01
309.0906372	0.03
313.3435669	0.04
317.1737671	0.05
319.3042603	0.03
325.2470703	0.08
327.2454224	0.03
331.2471313	0.01
341.2136841	0.01
343.1394348	0.50
346.9095459	0.01
351.3558960	0.02
352.9431152	0.03
355.3013916	0.02
373.2752991	0.02
382.3370667	0.02
384.1987305	0.01
389.5308533	0.02
399.3472900	0.01
400.2097168	0.02
403.2188110	0.05
416.3246765	0.02
417.0231018	0.01
419.3604431	0.01
421.3123169	0.05
444.3923035	0.11
445.2261353	0.69
464.3853149	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.34
Annotation	Unknow
Peak:m/z	Relative Intensity
166.0685425	0.11
184.0403748	56.48
184.9639587	4.89
236.9503784	0.19
240.1063538	0.15
241.0906677	0.47
258.2228088	1.20
280.5740356	0.27
291.0912781	0.29
293.1204224	0.25
297.1258240	0.21
299.3093262	0.11
337.4880981	0.11
338.4809570	0.36
349.1298218	0.06
351.1657104	0.10
365.0620728	0.04
396.7340698	0.19
427.3455811	0.06
433.0726318	0.08
435.4509277	0.19
443.5420532	0.44
444.2205811	0.24
447.3639526	0.28
449.4458618	0.26
460.2721558	0.07
461.2045288	0.42
463.5820312	0.26
477.7282104	0.24
485.5263062	0.40
491.9750366	0.21
502.4489746	100.00
503.4722900	71.84
504.3568115	0.07
506.4913940	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	727.1315
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7535706	0.20
229.0837097	0.15
231.0206299	0.16
238.9757385	0.06
249.0159912	0.08
274.1060181	0.16
303.0603638	55.24
326.9826965	0.33
345.1543579	6.86
369.0627441	0.87
387.2535400	0.38
393.1819458	0.28
411.3269653	0.68
419.2432251	0.20
433.4628296	0.50
438.2275391	0.24
453.4362183	0.24
457.3402710	0.13
461.4300537	0.30
471.5034790	0.94
473.3726196	0.09
474.2811890	0.14
479.1945801	100.00
488.3056641	0.11
515.3580933	0.72
521.3487549	0.43
527.3074341	0.43
533.3652954	3.59
539.6604614	0.56
543.1557007	0.44
545.2848511	0.56
551.2976685	2.21
557.3413696	0.28
567.7858887	0.31
581.1967163	0.36
584.4197998	0.11
587.0253296	1.18
612.2716675	0.44
621.7781372	0.53
629.3367920	0.27
641.2781372	0.14
660.7905273	0.39
683.3598022	0.29
691.4977417	0.13
692.7150269	0.14
709.2689819	1.27
710.2260132	0.92
727.2094727	1.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	249.2055
Annotation	alpha-Butyl-omega-hydroxypoly(oxyethylene) poly(oxypropylene)
Peak:m/z	Relative Intensity
58.5050278	0.02
74.9065094	0.10
81.2424316	0.07
87.0871429	0.09
94.9958496	0.02
96.8705063	0.98
98.9952698	0.42
100.8356934	6.43
110.9425201	0.02
114.8293915	37.36
115.6074066	0.32
116.9205017	12.28
123.0523071	0.06
130.9866486	0.05
133.0151978	1.66
134.7937622	0.48
151.3100739	0.22
155.8675385	0.19
156.8610687	0.04
159.0114136	0.63
162.9413452	0.08
164.8881073	0.10
172.8883820	100.00
173.5027618	0.29
174.9618835	5.24
177.0855560	0.04
189.0378265	0.24
190.9581757	0.34
193.0428314	0.59
202.9033813	0.06
204.7745819	0.46
207.1617584	0.15
213.0463409	0.91
218.1244049	0.05
228.4620361	0.08
229.1305695	0.05
231.0799713	5.51
234.4602661	0.13
239.5691071	0.27
240.2845306	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1535
Annotation	Anisocoumarin C
Peak:m/z	Relative Intensity
94.8377686	0.29
105.0363007	0.05
107.0623932	0.07
108.6049500	0.21
113.1435928	0.04
116.8869629	0.08
118.9183350	1.23
121.0225525	0.16
122.9685364	0.02
125.0458221	0.10
127.7317810	0.07
133.1467590	0.06
137.0108948	1.14
139.0040741	0.09
141.0930481	0.03
143.0834198	0.27
145.0687561	0.28
146.9764862	0.06
147.7592316	0.07
148.9573669	0.58
151.0794830	25.69
157.0969543	0.67
161.1027527	0.33
163.0227966	0.80
167.1045837	0.17
169.3943481	0.07
173.9682922	0.10
174.9368591	0.58
176.1217957	0.04
176.9691620	0.29
181.2960968	0.31
189.0572052	13.23
191.1895905	0.16
193.0590210	0.04
196.4982910	0.03
197.1095734	0.14
198.9018402	0.03
202.1361389	0.05
203.0440674	0.04
206.9640198	3.75
210.0267029	0.06
213.0378723	0.06
219.0817261	0.03
222.0158691	0.08
225.0579834	0.14
227.1632385	0.21
228.7727661	0.05
231.1462708	0.12
235.1679077	0.14
237.1326904	0.14
240.1714478	0.03
241.2598877	0.25
241.9407959	0.03
243.0841675	0.20
243.9566650	0.06
249.0850220	0.75
250.3851013	0.02
252.9959106	0.45
254.9648438	2.65
257.3172913	0.16
258.1369934	0.06
259.0573730	0.37
263.2095947	0.24
264.4891357	0.02
267.2850037	0.29
269.2115173	0.23
271.3166809	0.25
274.7951355	0.20
275.4382019	0.02
279.3755798	0.07
281.1844177	4.76
281.8465881	0.08
285.2319641	10.28
287.1883850	45.35
288.3041992	0.09
288.9859009	0.03
289.8904724	0.08
295.0530396	0.67
296.1559143	0.15
299.2155151	1.52
301.2485657	1.43
302.6239624	0.12
310.6174622	0.08
313.1557312	100.00
314.1189270	0.11
315.9897766	0.22
322.1728210	0.33
330.5216675	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.76
Annotation	Unknow
Peak:m/z	Relative Intensity
216.5593567	0.03
218.9564209	1.20
229.3758545	0.04
287.0534668	0.05
293.1570435	0.02
294.8459167	0.17
296.9717712	0.04
299.0407715	0.02
299.9628601	0.04
302.9033508	34.20
303.6936035	0.01
309.0139465	0.01
383.3114624	0.04
384.2769470	0.02
384.9978333	0.03
386.7194824	100.00
387.3462830	0.48
425.1188049	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1146
Annotation	Unknow
Peak:m/z	Relative Intensity
191.2540741	0.38
201.0178680	0.06
203.0789185	0.02
205.0230255	0.12
219.1325073	2.92
220.1350403	0.15
221.3946075	0.06
231.1823578	0.27
232.2767029	0.13
241.7771606	0.04
257.0906982	0.08
271.1914673	0.11
274.0164795	0.04
275.1323242	0.90
276.2273560	0.03
279.2733765	0.09
293.1599426	17.03
294.1511841	1.73
297.2075500	0.26
297.8861084	0.04
315.2089233	0.74
316.2949219	0.05
338.7911072	0.12
341.1586914	33.88
342.2442017	5.79
359.1034546	96.31
360.1392822	11.75
365.2438965	0.86
375.5326538	0.06
383.5229492	0.09
393.2262573	0.60
401.3561401	0.09
411.1398926	0.11
417.2976685	0.10
427.4458618	0.27
432.3950195	0.03
437.2295532	0.47
444.4144287	0.07
455.1959229	2.25
456.0645142	0.09
471.1571045	0.05
473.0895996	42.07
474.0843506	9.14
491.0968628	100.00
492.2262573	10.36
494.3501587	0.07
503.0924072	0.49
507.1072388	0.27
518.6992798	0.09
521.1854248	1.12
522.1625977	0.63
535.4520264	0.09
538.3433228	0.09
549.5117188	0.13
557.1954346	0.13
607.6315308	0.12
609.4567261	0.32
621.5587769	0.14
635.0418091	7.37
635.9970703	1.53
636.6503296	0.20
638.4071045	0.15
654.2199097	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.1767
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9269714	0.03
130.9586334	0.04
134.0958557	0.06
143.0651550	0.32
145.3506470	0.08
148.8662720	0.02
161.2502136	0.09
163.0611725	2.12
179.0373535	0.02
181.0826416	12.29
183.1699524	0.15
197.2919617	0.14
198.1976471	0.05
199.3055420	0.11
203.1261139	0.03
207.0925903	4.81
223.2716370	0.10
225.1102600	100.00
239.3049316	0.02
242.0649719	0.15
243.0560303	3.91
243.6874390	0.03
248.8945618	0.17
275.2514038	0.02
284.2954712	0.34
285.1851501	0.19
293.3132629	0.06
299.2431641	0.12
307.3727417	0.06
314.0297241	0.05
317.2585449	0.10
328.8121948	0.08
329.4603882	0.04
339.3336182	0.10
341.4465332	0.04
345.4383850	0.13
346.1898499	0.08
347.2716675	0.50
355.3961182	0.04
357.5037537	0.05
360.2899475	0.45
361.4629822	0.11
370.5742798	0.03
372.2644348	0.03
386.0653992	0.10
387.2210999	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.6
Annotation	Cer(d16:1(4E)/24:0(2OH))
Peak:m/z	Relative Intensity
206.9186401	0.28
208.7144318	0.01
212.7665558	0.04
214.9042053	0.04
215.9181519	0.03
216.7774048	0.03
232.2707825	0.03
290.6531372	0.14
292.8077087	0.15
296.9313354	0.07
298.8828735	0.09
300.6090698	0.09
356.6400146	0.02
362.1690674	0.02
380.8618164	0.10
382.6447754	0.27
383.8056030	0.06
384.8975830	0.30
386.3623047	0.12
386.9696045	0.89
388.6809082	0.01
466.5253296	0.09
468.2872314	0.29
468.9058228	0.15
470.6369629	18.20
471.2721558	0.11
474.7861938	0.02
483.3578491	0.08
493.1356201	0.07
502.0379028	0.05
506.1517334	0.05
524.6453247	0.01
540.1757202	0.03
552.4038696	0.26
554.6245117	100.00
555.3586426	0.09
558.5575562	0.04
560.7802734	0.10
562.8800659	0.01
567.1031494	0.01
591.9420166	0.01
595.7156982	3.99
596.6959839	2.29
599.2975464	0.02
600.2668457	0.04
604.7712402	0.04
615.0883179	0.40
616.0269165	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.073
Annotation	3,3',5,5'-Tetrahydroxy-6,7-methyleneoxy-4'-methoxyflavone 3-glucuronide
Peak:m/z	Relative Intensity
150.9031525	0.03
163.3044281	0.03
171.9053040	0.06
174.1213379	0.07
174.9418945	0.10
179.4102783	0.03
180.0676575	0.04
184.8790131	0.03
191.0182495	3.62
192.1030121	1.62
193.1577759	0.26
197.1309509	0.07
198.2792969	0.02
219.1754456	0.03
220.0654144	0.15
227.9870911	0.03
230.9140015	0.19
231.9962463	0.04
239.4134216	0.05
241.2102356	0.08
243.2936554	0.10
249.0730743	0.08
254.0825500	0.07
269.0416870	0.04
271.2098389	0.02
271.8723755	0.11
273.2584839	0.07
287.1821289	1.67
289.3936768	0.10
292.8807068	0.06
297.2436523	0.17
298.3009949	0.13
301.1486816	1.69
301.7593994	0.02
309.1555176	0.08
313.1520996	0.17
322.0778809	0.01
322.9849243	0.02
327.2523804	0.10
329.2125244	22.51
330.1403809	0.15
331.1256714	0.06
333.1923218	0.03
337.1793823	0.07
341.2011108	0.18
342.1994629	0.11
347.2866821	0.55
348.2291870	0.41
350.4711914	0.03
353.0254517	1.96
354.1938477	2.43
355.2161865	0.60
357.1060181	0.02
360.2351074	0.05
361.0382690	0.03
371.1073608	0.25
372.1778564	0.99
373.2300415	1.14
375.0917358	0.22
381.1940918	0.07
400.2033691	0.10
402.4201660	0.02
415.4199219	0.04
418.2824707	0.04
423.5836182	0.11
427.2121582	0.78
428.1733398	0.07
429.3720703	0.04
443.1096191	0.17
445.4041748	0.24
448.5159302	0.05
449.2864990	0.18
454.4603271	0.17
456.1627197	0.07
460.7136230	0.06
461.3895264	0.19
463.1804810	100.00
470.4696655	0.14
473.7721558	0.51
474.4225464	1.68
475.2749634	0.41
484.1994019	0.03
485.0530396	0.03
488.3199463	0.05
489.1955566	0.41
491.2373047	11.11
492.3450317	0.70
493.4603271	0.06
499.5581055	0.03
503.2886353	0.63
505.1796875	0.35
512.3251343	0.14
513.0341187	0.04
515.2940063	0.15
516.2084351	0.60
517.2668457	1.02
519.6224976	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1256
Annotation	Pyriftalid
Peak:m/z	Relative Intensity
179.0624237	5.95
191.0831604	0.36
204.9571838	0.21
219.0346985	4.57
221.3265686	0.08
231.1446838	0.61
249.0095520	0.31
269.3395386	0.14
275.1322937	0.80
281.2466736	0.12
293.1406250	28.49
297.1170654	0.44
311.1759033	3.71
312.9216309	0.21
317.2960205	0.11
341.0896606	53.39
341.8657227	0.05
343.2698975	0.15
381.1743164	1.14
383.2062378	0.75
388.1331177	0.13
392.2890625	0.05
448.0559082	0.27
449.5834961	0.13
455.2475586	37.55
471.2846069	0.10
473.1497803	100.00
473.8159790	0.54
475.4240723	0.09
495.6225586	0.46
499.6947632	0.12
501.0944214	0.07
503.1861572	0.65
517.1697388	0.19
518.3886108	1.74
519.4927979	0.64
520.3319702	0.08
529.2360229	0.45
531.5878906	0.29
537.3782349	0.40
547.2414551	1.24
548.3119507	0.08
563.2908936	0.21
572.1625366	0.20
587.2086792	0.17
588.1676025	0.43
590.3038330	0.25
591.6343994	0.29
592.2379761	0.10
596.5457153	0.08
599.6434937	0.09
615.5384521	0.10
617.3619995	0.52
635.2388916	5.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.2559
Annotation	Unknow
Peak:m/z	Relative Intensity
213.0739746	0.07
235.0718079	0.03
237.1741486	0.25
323.2611694	0.08
357.2672119	3.68
375.2899170	9.96
376.3502197	0.25
381.1524658	0.42
392.2661743	0.08
399.3481445	0.63
417.2911987	100.00
418.2736206	2.07
427.0579834	0.08
441.3298340	0.12
459.3374023	4.40
467.3603516	0.05
471.4503784	0.10
473.3977051	0.08
479.4780273	0.19
483.5419922	0.06
489.0025024	0.16
501.3458252	0.51
505.3455811	0.51
518.2463989	0.06
520.3526611	0.17
522.0914917	0.20
523.3004761	2.07
524.4144287	0.45
525.5734253	0.09
532.3382568	0.15
533.5616455	0.11
547.2508545	0.10
561.3710327	0.24
577.5964966	0.05
578.3037109	0.19
581.5349731	0.08
589.4381104	0.04
631.7410278	0.23
649.5715942	0.17
651.5875854	0.05
658.1677246	0.09
665.1055298	6.12
666.3460693	0.32
667.5398560	0.43
671.3535767	0.06
673.4579468	0.14
677.3386841	0.81
678.6151733	0.24
691.3855591	0.62
692.4071045	0.17
710.2431030	1.76
710.9285278	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	782.2671
Annotation	Unknow
Peak:m/z	Relative Intensity
227.2738953	0.18
271.0402832	0.35
273.0050659	0.27
299.3020325	0.58
300.3684082	0.62
315.0953369	1.88
329.0456543	0.11
330.3231201	0.13
331.8886414	0.11
333.0656738	7.17
353.3145142	0.16
470.6162109	0.32
477.2295532	0.30
486.6334839	0.36
487.3159180	0.36
488.1292725	0.17
509.2238159	24.45
521.2566528	0.23
533.3645630	0.43
536.4356079	0.04
575.6347656	0.24
589.5375977	0.12
600.3639526	0.04
601.2304688	0.18
606.4274292	0.08
633.8267212	0.06
652.6375732	0.39
653.3715210	0.38
665.1721802	0.08
693.4108276	0.06
728.1971436	0.21
737.1416016	0.11
763.2337646	0.50
764.4818726	0.12
782.1702881	100.00
782.8682861	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1664
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
143.0972137	0.14
144.9482880	0.09
156.9837341	0.04
157.9221802	0.03
158.9864349	0.04
161.0701752	0.19
164.1154175	0.02
170.2949524	0.03
172.3612976	0.01
173.1621399	0.06
178.9874725	1.37
180.2166443	0.06
182.1584625	0.07
184.9839478	0.03
187.1851807	0.17
191.1185303	0.02
195.0464172	0.02
197.1822052	0.99
198.0384521	0.18
199.2140503	0.09
200.0797119	0.06
203.1358643	0.02
211.1094055	0.04
213.3606262	0.12
214.5499420	0.60
215.1944885	13.30
216.2300415	3.31
223.1554260	0.03
224.7127380	0.03
226.1300659	0.03
227.1923370	0.04
229.3479614	0.11
239.1068115	0.10
241.1170197	1.34
242.1403351	0.19
250.3098755	0.03
257.1448669	0.91
258.1930542	0.13
259.1193237	9.15
260.1568298	1.64
269.1828918	0.08
272.2006836	0.04
275.1665955	0.08
277.2733154	0.68
278.3512878	0.12
287.3377686	0.11
297.2251587	0.05
299.2738037	0.03
306.2944031	0.03
316.5856323	0.03
318.6218567	0.04
323.1751709	0.18
332.3468933	0.11
341.2607422	0.02
355.2384033	0.01
366.9822998	0.03
375.9051819	0.03
377.0416870	1.00
378.0870667	0.06
380.1460266	0.03
389.9523010	0.05
394.1550903	0.06
395.3722839	0.05
396.3831177	0.06
419.3170471	0.21
421.1945496	23.73
422.2002563	5.66
423.2593384	0.08
426.3058777	0.02
439.1901550	100.00
440.2171326	24.27
441.1689453	0.19
442.3326111	0.07
450.2932434	0.02
451.6572266	0.08
457.3806458	0.07
467.3799744	0.07
468.3902283	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1067
Annotation	Luteolin-7-glucoside
Peak:m/z	Relative Intensity
134.9838715	0.01
177.1930847	0.01
223.1682434	0.01
228.6519165	0.08
233.0286865	0.01
239.0546875	0.02
241.0757141	0.08
243.3161621	0.01
247.5149841	0.01
248.6928711	0.04
251.2139587	0.03
254.1031494	0.02
258.0875549	0.01
268.3673706	0.04
269.2317505	0.06
269.9639893	0.06
271.0128479	0.02
280.0059509	0.04
283.9960938	0.06
285.3545227	0.02
287.0566406	100.00
287.9281616	0.01
291.3695984	0.02
292.2716064	0.04
299.2950439	0.01
301.0577087	0.02
302.2272949	0.06
303.2052002	0.02
304.605835	0.02
307.2063904	0.04
311.1329956	0.02
313.1766663	0.02
319.4796143	0.01
325.4655457	0.08
329.3039856	0.01
333.1167297	0.01
334.2480164	0.09
339.3356018	0.02
348.2727661	0.06
350.1255798	0.03
358.2107849	0.11
364.4973755	0.03
367.3353271	0.11
368.4183655	0.01
379.4076843	0.05
383.525116	0.09
385.0542297	0.02
386.3708801	0.03
388.6761475	0.06
390.4064026	0.03
392.3091125	0.01
393.2463074	0.03
395.2484436	0.03
396.3802795	0.03
401.0471802	0.04
403.2006836	0.02
409.2976685	0.02
412.3713074	0.08
413.3323364	0.06
417.0084839	0.07
419.3218994	0.04
420.9749756	0.08
425.4132996	0.01
429.3291626	0.03
430.4025574	0.28
431.3439331	0.26
433.2570801	0.02
439.2952881	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1922
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9304199	0.06
130.4801025	0.03
138.0234222	0.11
142.9532013	0.23
147.0111694	0.06
151.1078796	0.01
153.0261536	5.67
154.0960846	0.24
158.8334808	0.49
161.0584717	3.69
162.0775146	0.10
165.2720642	0.03
173.1480408	0.02
179.1029968	0.74
180.0055695	0.04
184.8536987	0.02
187.1253357	0.04
203.2597809	0.03
205.1621704	5.55
206.1136017	0.45
223.0643768	10.10
224.0114136	0.18
224.9818115	0.09
233.1661987	0.05
247.0770874	0.03
251.2382507	0.03
265.3153381	0.06
269.4837036	0.10
278.0317383	0.03
295.1997375	0.01
300.1484070	0.01
313.0960083	0.05
314.4349060	0.01
315.0356445	0.02
341.0189819	0.01
345.0368958	0.08
346.2019653	0.01
355.3753052	0.04
365.3177490	0.01
367.1457214	0.31
368.5438538	0.05
370.1399841	0.02
375.3334045	0.03
385.1824036	100.00
386.1719666	4.43
386.8450928	0.03
387.6612549	0.02
390.9668884	0.05
412.1402893	0.02
413.3239441	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	947.1517
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
267.1816406	0.04
275.1936951	0.66
293.1033936	16.11
296.9274902	0.04
308.4860840	0.04
311.1466064	14.50
341.1903992	0.20
411.1950073	0.07
455.3250732	0.08
473.0844727	59.23
477.4941406	0.15
766.5827637	0.13
784.7328491	0.12
785.3931885	0.15
946.8695679	100.00
947.5996704	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.1984
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
126.8861847	0.12
128.8383636	0.23
134.8388062	0.17
145.2410583	0.23
160.8081055	0.23
163.2220154	0.11
169.1810913	0.11
180.9039612	0.12
185.0092163	7.13
195.2503052	0.51
198.8743591	0.12
200.3452454	0.45
201.3002472	0.07
209.8477020	0.13
213.0577850	0.05
219.2729950	0.11
225.3471985	0.08
227.2799988	0.35
228.1013794	0.43
228.8912048	0.31
234.9323730	0.08
237.0984497	100.00
237.9465027	0.51
239.2391052	0.18
241.3389893	0.10
243.0975037	0.18
249.8840027	0.09
253.1871643	0.27
255.1385193	0.33
258.1099548	0.39
264.8443298	0.16
280.9754028	0.10
283.3541870	0.26
295.1782837	0.11
296.6772766	0.07
309.1400146	0.35
311.4008789	0.41
312.3730774	0.34
313.0600281	0.22
321.5291748	0.07
324.2850342	0.14
325.3160400	0.78
328.9989319	0.37
336.6204834	0.39
337.2945251	0.10
339.2547607	0.30
342.4578857	0.27
345.9205322	0.22
346.7012024	0.24
353.2436523	0.71
355.1047668	0.08
357.3594666	0.36
358.8439636	0.14
361.9031067	0.58
363.1600647	0.79
369.2677307	0.55
371.2471619	0.36
379.4336853	0.23
380.2214050	0.42
381.2471619	0.54
390.1678772	0.20
399.3398132	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.0991
Annotation	Chicoric acid
Peak:m/z	Relative Intensity
150.8952332	1.61
151.5051575	0.05
160.9809570	0.07
163.0408020	0.11
169.0048218	0.16
174.1577606	0.05
175.0632935	0.07
179.0454254	2.40
183.0956116	0.07
189.0263367	0.41
190.1269836	0.20
191.2713470	0.03
192.0669556	0.05
193.1767273	0.28
195.0113831	0.03
198.1250153	0.03
200.9474182	0.13
203.3800964	0.11
206.9608765	0.28
209.1242981	0.16
211.0863037	0.12
213.0027313	0.09
214.8751984	0.14
215.9984741	0.04
216.9746704	0.13
225.9822388	0.03
227.3193817	0.05
229.2688446	0.29
231.1983795	0.03
233.2839813	0.02
237.1588135	0.14
239.1881104	0.08
240.2284851	0.04
243.1561279	0.07
245.1354980	0.03
253.2385254	0.05
253.9349670	0.06
255.1746826	2.09
256.3141479	0.11
257.1564331	0.28
259.3684998	0.05
263.1572876	0.25
266.2279053	0.13
269.1312866	0.19
271.1190491	2.81
272.3941040	0.18
273.2152710	1.24
281.4154663	0.03
283.1486511	1.03
285.0200806	0.08
297.2829590	0.24
300.0697632	56.09
301.0575256	100.00
301.6869202	0.25
312.9755249	0.03
315.3515625	0.05
323.1825867	0.12
324.5872803	0.11
325.2085571	0.26
327.2595825	0.04
331.2262268	0.09
335.1823730	0.05
338.9871826	0.16
341.4225159	0.06
343.0820312	1.97
352.0008545	0.11
353.2467957	0.10
355.0899963	0.60
357.3036804	0.03
361.4142151	0.06
367.4830933	0.10
373.2196045	0.15
379.1675415	0.21
385.0979614	0.03
394.9123840	0.11
397.1705933	0.06
399.2515259	0.12
401.1991272	0.07
426.9906311	0.03
445.2182312	3.67
446.5778503	0.14
459.2399902	0.04
463.2564392	24.59
472.9242554	0.07
487.2062073	0.66
506.4018250	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1194
Annotation	Oenin
Peak:m/z	Relative Intensity
148.6197815	0.12
203.0913696	0.06
223.9821167	0.11
243.0710449	1.56
244.0277252	0.29
269.4256897	0.17
272.0688782	0.13
286.0419922	0.08
289.2506104	0.32
293.3570557	0.12
299.4379578	0.05
301.0504456	0.06
303.0233154	0.13
329.1075439	0.12
330.2919922	0.29
331.4689636	0.29
337.0303955	0.13
357.3108521	0.58
360.3185730	0.20
385.2877197	0.06
393.9977722	0.05
404.2339172	0.20
406.9043274	0.14
416.4813538	0.09
427.2034607	0.45
431.6364441	0.07
432.3611145	0.11
446.0279541	0.23
447.1869202	100.00
448.0141602	0.02
449.2504272	0.59
454.3744202	0.76
455.4315796	0.84
456.2573547	2.18
457.3970947	1.08
458.1712036	0.04
464.0521240	0.07
474.2839661	0.04
475.4469910	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.0882
Annotation	Unknow
Peak:m/z	Relative Intensity
136.8873444	0.05
139.1889954	0.08
146.9571838	0.15
148.8757019	2.13
151.2016602	0.06
160.9967041	0.19
162.3100739	0.21
163.0028687	0.18
175.0545959	0.25
177.1357727	0.58
178.0440369	0.69
178.9685364	10.49
187.0283203	0.08
189.1875000	0.21
189.9748840	0.11
190.9228058	0.76
192.9943848	29.36
201.2411804	0.21
202.1950684	0.11
202.9898376	0.05
205.0331421	0.99
219.0994873	14.68
221.2370453	0.17
230.8579712	1.18
233.1237335	6.05
235.2501678	0.15
243.3314514	0.05
245.0362244	0.66
249.1791382	0.32
257.2568359	0.07
262.9534912	1.49
275.1338806	2.73
277.1572266	0.05
289.2174988	1.21
293.0650635	83.36
298.9759827	0.15
307.2038574	42.56
311.0416565	1.90
323.3395081	0.10
325.1588745	100.00
353.2559204	0.08
354.2293701	0.11
355.3930664	0.21
369.2649841	0.08
393.4049988	0.19
401.2199097	0.11
409.5678406	0.14
413.3543701	0.99
420.6196289	0.12
423.1866760	0.06
427.3002319	0.58
437.2774048	0.09
439.2421570	0.26
440.2540588	0.22
441.3829651	0.19
445.3612366	0.25
451.4253845	0.09
453.1114807	0.19
456.8037415	0.08
469.3510132	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	645.2895
Annotation	Granaxylocarpin A
Peak:m/z	Relative Intensity
203.9177551	0.28
240.0503540	0.06
251.3488312	0.24
256.2138672	0.11
261.0493469	0.06
271.2036133	0.28
273.3926392	0.26
283.3634033	0.40
289.0780945	0.14
297.3345337	0.10
298.3552856	0.10
299.1953735	0.55
302.3463135	0.11
309.3395081	0.16
310.8569336	0.04
312.9372559	0.16
319.9520874	0.40
324.2320557	0.04
325.2581177	0.59
327.1555176	0.96
333.2109375	0.05
337.3551636	0.12
340.0607910	0.05
341.0643921	0.16
357.1961060	0.20
358.9545288	0.45
366.5789795	0.56
367.3079224	0.22
369.2172241	0.63
370.6831665	0.30
372.1504517	0.07
373.0643311	0.43
379.4270020	0.05
394.1841431	0.26
395.2227783	0.06
396.3487549	0.23
397.6358643	0.13
399.2713623	0.77
404.2418213	0.45
416.2258301	1.83
419.3433228	0.05
420.5682983	0.24
423.1749268	0.06
430.2225952	1.00
432.2785034	0.39
436.6831665	0.70
448.2435913	5.80
449.3905029	1.37
450.4013062	1.05
453.4547729	0.08
460.2745361	6.05
462.2009888	0.46
466.8675537	0.16
472.3154907	0.16
473.7036743	0.68
474.4508057	0.11
476.6099243	1.54
477.4129028	1.06
478.4379883	0.39
480.2875366	4.27
490.3373413	5.27
492.3062744	21.98
493.0990601	0.03
508.2252808	0.48
522.2291870	6.56
523.2271118	0.75
524.3470459	0.25
528.3549194	0.33
535.2846069	0.04
539.5173950	0.12
546.4177856	2.13
551.3685303	0.18
558.3954468	0.15
559.2918091	0.06
567.3755493	0.06
569.2670288	0.79
577.5276489	0.14
585.2919312	1.01
592.2607422	0.46
595.3295288	6.03
600.4259644	0.27
603.7937012	0.20
608.7155151	0.06
610.4554443	0.08
613.2962036	100.00
614.0088501	0.14
624.2195435	0.69
625.9407959	0.63
626.7333374	0.25
627.4420776	2.29
628.8726807	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1588
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
179.0232697	0.02
219.1154175	0.03
232.2482452	0.03
256.0252686	0.08
275.3871765	0.02
287.1030884	60.97
288.1147461	9.93
298.1228638	0.01
303.0683594	1.05
304.2142944	0.07
308.3588867	0.08
315.0272217	0.08
329.1489258	0.09
330.1384888	0.09
334.3431396	0.03
351.1502075	0.06
353.2099609	0.22
363.9883423	0.03
365.2741089	0.13
383.3009644	0.03
384.2256470	0.09
395.3285522	0.18
396.2814941	0.16
411.5295410	0.09
413.2758179	0.19
413.9170532	0.13
415.3323364	0.07
420.9983521	0.04
431.3038330	0.82
432.1818848	0.10
432.8214111	0.03
449.0987549	100.00
450.1088257	19.46
465.0165405	0.74
466.0452881	0.17
471.4014893	0.02
477.3770752	0.05
478.1245728	0.14
482.2601318	0.02
495.8135986	0.06
500.8158569	0.07
514.9588623	0.10
516.4418945	0.06
522.8092041	0.10
524.4288940	0.06
545.3466797	0.11
557.2958374	0.23
566.2816162	0.02
575.1744995	0.02
580.0471802	0.05
591.1658936	0.05
593.1665649	0.43
594.4027710	0.15
613.1563721	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	673.2713
Annotation	Unknow
Peak:m/z	Relative Intensity
191.1953735	0.23
195.0889282	0.52
207.0447693	0.43
209.2986145	0.32
213.1891937	0.67
214.1264038	0.67
216.9338074	0.17
217.9025269	0.12
219.1061096	0.23
225.1118164	1.91
227.2954407	0.36
235.4244843	0.41
236.8446960	0.62
237.6018066	0.55
250.9982300	0.23
267.3971252	0.37
270.3935547	0.47
271.1733398	0.43
279.3367004	0.83
297.2339478	4.89
298.1734009	0.33
304.0397034	0.14
315.1222534	12.50
316.1872559	1.67
357.2873535	5.19
358.2272339	1.92
362.4445801	1.78
375.3059082	100.00
376.3990479	15.01
399.2042236	2.26
400.1696777	0.21
405.2462158	0.41
411.4852295	0.35
417.5158691	0.53
423.2116089	0.09
440.9788208	0.45
450.4446411	0.09
459.2869873	0.90
467.2042236	0.38
468.1531982	0.25
471.5497437	0.54
487.3382568	0.86
488.6641846	0.30
493.4023438	5.59
494.5119019	0.81
496.4451904	0.49
509.3558960	0.24
511.3588257	8.30
512.2841797	1.79
521.1795654	1.10
522.4247437	0.34
535.7099609	0.40
553.7211304	0.63
554.4901733	0.46
565.4190063	0.43
570.6005249	0.17
575.4439697	0.39
578.0669556	0.15
587.3218994	0.19
588.2969360	1.04
601.2202759	0.57
621.3266602	0.22
629.4890747	1.13
630.5410767	0.54
644.4487305	0.31
655.3990479	27.93
656.2645874	2.21
674.3859253	63.83
675.4678955	6.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.0881
Annotation	Unknow
Peak:m/z	Relative Intensity
129.2535706	0.06
131.1004639	0.09
134.2064514	0.06
136.9048157	5.17
139.2012634	0.03
150.1248627	0.63
151.0706482	0.50
161.0890503	0.16
162.0020447	0.04
163.0380249	0.13
164.0359650	0.09
165.0311127	0.10
166.9460449	0.84
167.9536591	3.44
169.0326843	5.06
172.8076630	0.06
175.1656799	0.03
179.0206299	0.37
180.1181488	0.05
181.0172424	0.25
183.0099792	0.18
189.0416565	0.06
191.0866394	0.21
193.0076904	0.22
195.2760925	0.08
196.2486572	0.18
197.0655212	0.12
203.0477600	0.05
205.9123840	0.03
206.9355164	0.06
208.8621216	0.18
211.0940857	0.59
214.0193176	0.07
214.8150330	0.06
219.1163330	0.06
223.1644287	0.04
224.9297485	0.33
227.1279907	4.72
228.0366211	0.15
229.3801422	0.05
234.2476044	0.14
241.0403442	0.03
247.1565247	0.76
250.9926758	0.04
253.2889404	0.07
257.5960999	0.09
258.9996033	0.02
269.1839905	2.43
271.0867920	0.02
277.1967773	0.18
283.3279419	0.16
288.3185120	0.21
289.2862549	0.22
292.2223206	0.13
293.2311096	0.17
295.0812988	1.17
299.4950867	0.14
303.4102173	0.06
313.0969849	92.61
314.3873291	0.31
315.2906494	0.29
317.2851257	0.13
321.2185059	0.57
326.2675476	0.30
327.1648254	0.05
331.1320190	100.00
332.3015747	0.86
343.3011475	0.18
345.1508789	0.03
349.4835205	0.09
354.2616577	0.04
355.2980957	0.17
362.7847595	0.19
364.1758118	0.15
364.8921509	0.04
368.2990417	0.15
370.2690735	0.18
375.6574402	0.16
377.1886597	0.14
379.0722046	0.16
381.3915710	0.12
387.5207825	0.06
389.1004333	0.24
391.3208923	1.24
392.7739258	0.29
404.4300842	0.08
405.2922668	0.37
406.3641052	0.36
407.3390503	0.14
408.2606812	0.03
409.4391479	1.16
413.1648254	0.02
413.8103027	0.05
415.2215271	0.61
417.2415466	0.09
420.8090210	0.10
430.3746338	0.41
432.0457458	0.40
433.2215271	1.94
452.0819702	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1445
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
177.2115936	0.07
178.9697723	2.98
180.0437469	0.13
185.0614319	0.36
192.0948944	0.72
197.0482178	1.29
210.1512604	1.82
211.3249512	0.83
212.9665527	0.35
226.0729523	0.38
229.2651825	0.14
231.2507935	0.14
242.1611786	0.84
252.1256714	0.09
253.0324554	0.05
254.1339874	14.27
255.0266418	1.28
256.1677246	0.06
262.3533630	0.28
266.0211182	0.04
269.1234741	0.47
270.1288452	0.17
272.1656799	32.57
273.1516113	5.05
279.1059875	0.09
286.1685181	1.55
288.1070557	4.81
289.1378784	0.94
304.1096191	13.69
306.1047974	100.00
307.1339111	9.82
311.1356201	0.26
320.1000061	0.46
338.0425415	32.68
338.9925537	3.23
353.2084351	0.30
354.1041870	0.06
361.2522583	0.13
363.2197876	0.17
386.1560669	0.06
394.1171875	0.17
415.7097168	0.25
421.4910278	0.21
463.7877808	0.09
465.1804810	0.08
467.3923340	0.15
474.2964478	0.05
482.1633911	18.56
483.2485962	3.15
504.2235718	0.04
505.2241821	1.63
506.3485718	0.43
512.5531616	0.14
524.3914795	0.12
574.9301147	0.16
593.2363892	6.96
594.1918335	1.66
594.9947510	0.08
612.1611938	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2658
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0735168	0.02
195.0202637	0.09
197.1713257	0.02
233.9090424	0.02
238.3155670	0.07
285.1317444	0.67
286.1693115	0.56
320.3385620	0.04
321.2673340	0.02
327.2841797	0.34
328.3122559	0.14
339.3878784	0.02
343.4036255	0.03
381.1623535	0.12
382.4653931	0.02
393.4036865	0.06
399.3192139	100.00
400.2882080	22.58
400.9415283	0.04
417.2139893	0.07
435.1090088	0.02
447.2202148	0.09
447.9796143	0.05
463.1653442	0.03
464.1178589	0.03
471.5508423	0.18
518.8159790	0.08
519.6141968	0.07
531.3865967	0.05
532.1305542	0.09
534.1106567	0.05
536.3500977	0.18
537.3147583	0.22
538.2870483	0.06
561.1758423	0.03
562.5899048	0.04
581.2788696	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	359.1694
Annotation	Loliolide beta-D-glucopyranoside
Peak:m/z	Relative Intensity
104.9685211	0.70
106.9961853	1.28
109.0771103	0.19
115.8470688	0.03
119.0773315	0.17
119.8417816	0.07
122.9980392	0.16
130.9518738	0.07
132.9284058	1.61
134.1116943	0.06
135.0699768	0.04
137.1871338	0.17
137.9976044	0.06
144.3276520	0.04
148.9674377	0.80
151.0151825	1.43
152.9847717	0.17
160.9847412	0.66
162.6625824	0.11
167.0508118	3.52
169.1517792	0.05
175.0642395	0.03
179.0931091	2.74
186.2044220	0.33
195.2153778	0.06
197.0412292	100.00
204.9264526	0.02
207.2552948	0.26
212.9746094	0.09
214.3247375	0.07
223.1781006	0.06
224.8916931	0.05
227.9502869	0.18
228.8999939	0.10
235.1036987	0.21
236.9875183	0.08
243.2063599	0.18
247.1369934	0.03
249.0329285	0.24
253.4459229	0.05
255.0759277	0.54
262.1359253	0.04
263.9396057	0.06
267.0867310	0.22
269.0325317	0.19
277.5297546	0.26
280.7109985	0.21
281.3126831	0.14
283.0684204	0.07
285.3219604	0.16
295.2474365	0.10
295.8623047	0.13
299.1031189	0.18
301.1719666	0.08
303.3528442	0.08
307.1245117	0.37
308.9447632	0.17
310.0462341	0.04
312.4240723	0.09
313.2637329	1.95
314.1639404	0.08
315.2315979	0.19
316.3276062	0.14
317.1913452	0.18
318.3015747	0.06
323.2385254	0.12
324.0800781	0.06
326.2662964	0.13
327.3714294	0.75
328.1936035	0.04
331.1996765	0.48
336.0983887	0.12
340.5027466	0.46
341.2328186	2.46
349.9046326	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
57.9719467	0.01
66.9823456	0.01
67.8653107	0.01
69.5944367	0.04
70.8197479	0.01
72.0352631	0.03
73.8033447	0.07
74.9705353	0.00
79.0159683	0.01
79.9806595	0.01
80.9267426	0.07
82.0239563	0.04
83.0217285	0.14
83.9515533	0.03
84.8750000	0.04
86.0077667	0.03
92.8894043	0.02
93.7467651	0.01
94.9313507	0.00
96.0355835	0.03
96.9816284	0.14
98.0904999	0.08
100.0123749	0.12
100.7707977	0.03
105.0834503	0.01
107.1242676	0.04
108.1079559	0.05
108.8020172	0.04
110.0400543	0.05
111.0291138	0.16
111.9550323	0.09
113.1990967	0.02
115.1392517	0.04
117.1264954	0.03
117.9836731	0.01
121.5169525	0.08
122.1455841	0.03
125.0026550	0.07
125.9017029	0.02
128.2120514	0.02
128.9643707	0.01
135.8841705	0.02
137.0886383	0.03
138.1350098	0.01
139.0418549	0.03
140.0431671	0.02
143.1348877	0.04
151.2671814	0.01
153.9670868	0.11
155.1563568	0.05
156.0286865	0.02
158.8427582	100.00
159.8020935	0.01
161.8631897	0.00
163.3561859	0.19
164.1777496	0.01
169.9627686	0.01
171.2075653	0.01
172.1293640	0.03
176.6952515	0.94
179.1248016	0.14
181.0592804	0.19
181.9998627	0.59
183.1682587	0.01
183.9384155	0.00
199.2047577	0.02
199.8366547	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9715
Annotation	Unknow
Peak:m/z	Relative Intensity
125.7504578	0.02
143.8217010	0.04
147.9993896	0.01
155.8586426	0.02
166.1844025	0.02
185.1518250	0.04
191.0328369	0.01
197.9210510	0.02
201.9829102	0.52
213.8136139	0.01
217.9094696	0.02
227.0511780	0.02
230.3069153	0.02
231.9485474	0.04
233.1308289	0.03
237.2668457	0.01
241.8722229	0.08
244.0692139	0.04
249.0220032	0.03
257.8444824	0.03
260.0807190	0.10
263.7882080	0.06
268.9988098	0.03
270.1143799	0.02
272.2224731	0.03
281.2711487	0.03
284.7430420	0.02
285.9505615	0.19
290.0429688	0.01
290.8170166	0.01
295.2155151	0.03
304.0039368	0.90
305.3935547	0.01
308.1856384	0.13
308.9264526	0.05
314.0757446	0.02
321.8876953	0.04
325.5062256	0.01
330.0879517	0.57
331.3852234	0.24
332.1170654	0.58
333.2707520	0.04
334.1605225	0.24
334.9656067	0.15
347.9677734	2.67
350.1489868	0.01
357.5037842	0.20
358.3317566	0.05
362.8540344	0.12
366.5276794	0.05
370.2442627	0.03
375.1207275	0.04
376.0953064	0.29
378.3486938	0.05
380.4131165	0.03
384.8479919	0.01
393.9667053	100.00
394.5927429	0.30
397.7615356	0.03
401.1359863	0.26
401.9637146	0.05
419.0400391	1.74
420.0210876	0.76
420.7144470	0.01
421.4125061	0.06
428.8453064	0.02
429.5310974	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.0858
Annotation	Aesculin
Peak:m/z	Relative Intensity
100.8862000	0.04
104.8447571	0.04
115.7281189	0.03
121.0233612	0.03
123.0435181	0.05
125.1171112	0.01
129.1633606	0.05
131.1819153	0.01
132.9538269	0.05
135.0839844	0.05
137.0038605	0.15
146.9746399	0.01
151.0944824	0.07
155.0099335	0.06
163.0507202	0.07
165.1731567	0.02
165.9843292	0.01
173.8231659	0.08
175.1951141	0.02
178.9217682	100.00
179.7615204	0.00
182.2720642	0.01
182.9754639	0.04
184.2482147	0.06
185.2001953	0.02
186.2525482	0.03
187.3306427	0.03
188.9348297	0.03
190.9946594	0.01
201.0552063	0.24
201.9981384	0.14
202.8459930	0.02
208.9823303	0.03
211.0718994	0.11
211.9057922	0.03
217.1340942	0.04
227.7709045	0.08
230.8679810	0.01
233.2754211	0.03
235.3646545	0.08
240.0455017	0.02
241.1856384	0.04
243.1171570	0.03
247.1138611	0.04
251.0595398	0.03
263.3818054	0.10
265.1674805	0.05
267.2680359	0.02
271.2664795	0.01
272.0552063	0.03
272.9499512	0.06
276.3840027	0.02
279.2642822	0.03
280.9282837	0.03
283.1356201	0.02
284.2866211	0.26
286.7583008	0.01
287.4898682	0.04
291.1897583	0.19
293.1416931	0.09
294.8818054	0.03
296.3814087	0.05
299.3645935	0.09
300.1802368	0.03
303.3143311	0.08
309.1967773	0.13
310.4205322	0.03
311.2584839	0.11
312.3044128	0.03
313.2329712	0.08
315.7736816	0.06
322.9957581	0.89
323.6056519	0.01
325.7389526	0.01
331.7858582	0.09
332.8367310	0.05
340.8573914	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.21
Annotation	Suspensolide F
Peak:m/z	Relative Intensity
147.2160797	0.07
150.8109436	0.05
163.0315857	0.25
169.1266632	0.06
195.2061157	0.07
213.0757904	0.34
231.0606384	0.48
245.1871033	0.07
253.1888733	0.03
281.4061279	0.16
285.3088989	0.08
289.2138672	0.08
296.1101074	0.04
303.0807800	100.00
304.0122681	0.06
308.1945190	0.04
315.0162354	0.18
316.3763733	0.04
317.1889038	0.11
330.1427612	0.04
344.5608521	0.03
345.3540649	0.04
357.3305359	0.13
362.1411743	0.11
369.4630127	0.13
380.6679688	0.05
390.3392639	0.15
399.2236023	0.14
425.1253967	0.67
429.4846497	0.26
431.0966797	0.07
443.1596375	1.20
451.3873901	0.09
459.9515686	0.24
461.1031189	2.99
469.8967896	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3151
Annotation	Unknow
Peak:m/z	Relative Intensity
224.1836853	0.04
242.1668091	0.16
253.1358185	0.04
254.0603027	0.13
255.1571045	0.13
277.3134155	5.73
278.4076538	0.55
279.4282532	0.42
280.3225098	0.04
324.2946777	0.06
365.4058228	0.04
375.3503418	0.02
413.2850952	0.10
502.3698730	100.00
503.3477783	0.15
505.4796753	0.05
513.0410767	0.02
515.1913452	0.57
516.3051147	0.05
521.4039307	0.03
544.6024780	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2463
Annotation	Swietenin F
Peak:m/z	Relative Intensity
181.1461334	0.04
217.1107025	0.14
236.9779205	0.08
251.2273560	0.14
271.4355469	0.14
295.2413940	0.05
335.2952881	0.05
365.6419678	0.05
428.1751099	0.12
477.7013550	0.12
493.4003296	0.23
494.6636353	0.08
496.3388062	0.13
499.4459229	0.24
513.3745117	44.92
514.4194946	22.60
521.3634644	0.34
530.3817749	0.17
531.5226440	0.21
534.6883545	0.24
535.4918213	0.59
536.7051392	0.12
538.1874390	0.09
545.3864136	100.00
546.4423218	51.79
553.0880737	0.10
554.5415039	0.31
555.3958740	0.17
557.3821411	1.00
558.2035522	0.23
571.8739014	0.74
572.7811279	0.07
589.7971191	0.51
590.8093872	0.04
591.4540405	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	336.9815
Annotation	Unknow
Peak:m/z	Relative Intensity
98.8446808	0.07
102.9975433	0.33
112.6382751	0.15
130.9490356	0.68
148.9766693	100.00
151.0184021	0.02
156.9869385	0.04
175.0406494	0.19
187.1180573	0.11
190.9635925	0.23
191.5975647	0.03
192.2557678	0.35
204.0878906	0.08
205.0015869	0.43
209.1681213	0.03
211.1145325	0.07
218.8667297	0.04
231.2106323	0.04
232.8400269	0.18
236.0516052	0.27
245.7104187	0.26
247.3234863	0.71
261.0568848	0.70
262.9187927	0.17
275.0851135	0.64
277.1085510	0.85
289.9380798	0.04
307.0479126	0.13
318.2602539	0.03
319.0764771	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2206
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.06530762	0.54
92.91471863	0.44
94.88847351	0.70
107.9412231	0.24
109.3099365	0.33
110.9143295	0.72
121.1996918	0.98
122.9267197	0.90
125.0217438	2.10
127.0577698	2.95
128.800766	0.26
130.9878235	0.95
132.9828033	0.25
137.1279449	0.97
139.0351562	1.45
141.2653198	0.82
143.0642242	5.71
147.1875153	0.33
149.003479	1.03
151.137085	1.72
154.7974548	0.32
163.1583405	1.74
167.1131592	1.43
169.0301208	2.13
171.1044464	0.80
173.0466919	0.47
175.0717773	0.32
176.946228	0.78
180.969635	0.50
183.0990143	3.02
185.3017731	0.95
187.269928	1.16
189.1508179	1.08
191.1661835	0.32
193.2436218	0.19
193.9722595	0.29
195.208252	1.31
196.2745972	0.42
197.1339417	1.56
198.9108734	2.07
203.194519	0.40
205.9223938	0.32
207.3132324	0.39
209.1253052	2.27
211.1010132	3.09
213.1108093	1.23
215.0941467	1.35
217.0713501	0.28
222.1963806	0.21
223.1505432	0.37
223.9788818	1.15
224.9967346	0.81
226.4337769	1.36
227.3263855	0.43
228.9396057	0.78
230.2681274	0.56
233.1081848	0.23
235.1079712	2.04
237.1847534	3.74
239.1329041	4.45
240.990387	1.43
247.2546692	1.01
248.040863	0.77
249.37146	0.72
250.2164917	1.12
251.2081909	1.75
253.3510132	3.83
254.8013306	0.38
265.1066895	3.05
267.2202454	3.69
269.0474854	1.95
270.1012268	0.73
275.1716919	23.65
279.1658325	0.32
283.1445312	1.33
285.1141968	1.07
291.2718506	0.37
293.2027588	100.00
295.1548462	0.57
297.1431885	0.35
302.3045044	0.43
311.169342	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.8822
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8256226	100.00
208.9757996	0.23
212.7799377	39.79
254.9921875	0.05
279.2090454	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	215.1636
Annotation	5-Oxododecanoic acid
Peak:m/z	Relative Intensity
67.1329651	0.01
76.7058411	0.12
78.9009018	0.05
80.9287567	0.04
85.0904388	0.02
88.2369080	0.05
93.0170441	0.02
94.9505920	0.30
96.9344788	1.22
99.0199432	0.56
107.0743561	0.08
113.0972290	0.39
114.8350372	0.10
116.7927399	0.01
119.1184998	0.07
121.1069031	0.20
123.0297394	0.69
124.7998199	0.12
126.9219513	0.08
128.0537262	0.24
130.9320526	0.02
133.2061462	0.26
135.2202454	0.03
137.0285187	0.10
137.8591156	0.03
139.0953369	0.04
143.1165009	0.10
152.9463654	0.02
155.1015015	0.21
157.0987244	0.04
158.9050903	0.08
161.1001129	3.52
162.1659698	0.03
163.2577057	0.03
168.9345856	0.06
171.1606293	0.07
173.0655670	0.11
179.0941772	18.15
180.2217865	0.06
181.1074371	0.18
187.0316467	0.06
197.0189056	100.00
198.0543060	0.07
214.9676361	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
613.8342896	88.19
967.4208984	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2917
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
134.9622803	0.16
136.8980560	0.08
145.1632080	0.43
147.1427917	0.07
151.3021545	0.08
153.0655975	0.33
155.0297546	0.68
161.1004028	0.07
163.1034546	0.29
164.8787842	0.22
167.1205139	0.17
168.1383667	0.08
173.0316010	0.09
177.1123199	0.12
189.2377014	0.03
191.0785522	0.31
192.9680023	0.21
194.9622803	0.17
198.0788879	0.19
199.2283325	0.11
211.1239319	0.04
213.1098480	0.11
215.6060638	0.26
216.2200775	0.64
225.9302368	0.13
227.2317200	0.12
232.3177185	0.22
239.0213623	0.08
245.3148651	3.09
247.1610107	0.11
249.2344055	0.05
251.2667847	0.21
261.2513733	0.21
263.2346497	6.65
267.2507019	0.11
277.3551636	0.30
278.9211426	0.09
284.0958862	0.05
293.4050293	0.24
301.0812378	0.06
302.2025452	0.09
306.3355103	3.31
307.0284729	0.03
319.3524170	0.60
321.1467285	0.18
324.3347778	0.22
329.2863159	0.13
333.1816406	0.36
335.0555725	0.06
337.3643799	87.26
346.9988098	0.09
349.2029419	0.11
355.4678955	0.10
371.6181335	0.29
375.1676941	0.04
376.1898499	0.10
380.3359375	0.59
389.0690002	0.03
411.2218933	0.07
417.1247253	4.68
429.3487854	0.10
433.5105286	0.18
435.4307556	0.29
436.5664978	0.04
437.2378235	0.14
441.9525757	0.13
443.6253357	0.19
460.2352905	100.00
460.9260559	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	411.1793
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
149.1100006	0.16
152.9978333	0.05
161.1102142	0.10
162.8432159	0.14
169.0238495	0.30
179.0576630	0.14
183.2386169	1.67
195.2043152	3.21
197.0662537	2.18
202.7610321	0.12
210.9784698	0.41
213.1807861	100.00
214.1441345	0.03
229.3915710	0.13
249.2564087	0.46
255.1673889	0.06
265.2254944	0.14
295.3413086	0.38
307.2132568	0.18
316.2297363	0.11
322.8884277	0.07
353.2359619	0.19
360.8153687	0.08
364.3637085	0.12
365.4802246	0.26
375.4870300	1.01
381.4567566	0.08
383.3596802	0.30
393.3727112	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1149
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1894531	0.10
206.4587708	0.10
213.3240509	0.12
219.0082703	2.32
219.9992828	0.04
220.8690491	0.05
231.1151428	0.67
232.2010803	0.36
237.1871033	0.08
271.2503052	0.25
274.8247986	1.69
293.1272888	20.30
294.1654968	1.72
297.0204468	0.38
298.3144531	0.06
310.9524536	0.38
315.2229309	8.72
316.1320496	1.31
324.5833740	0.08
329.2897034	0.11
341.1538086	32.61
342.2003174	6.11
359.1163940	88.37
360.2293701	13.33
365.1884766	0.29
366.1389771	0.10
377.3764648	0.08
383.4022827	0.07
393.2410278	0.74
411.2756958	0.31
427.0550537	0.16
428.9937134	0.37
437.1477661	0.41
445.2551880	0.16
455.0357056	2.17
455.8528442	0.02
456.4704590	0.04
461.4231567	0.06
473.0459595	36.57
474.1450806	4.53
477.3612671	0.63
478.9838257	0.15
489.3878174	0.42
491.1046753	100.00
492.1018677	15.47
503.2888794	0.74
521.1377563	3.42
522.0806274	0.50
529.8267822	0.29
535.5630493	0.21
567.2594604	0.21
568.2240601	0.49
573.1132202	0.38
609.4798584	0.83
615.2286987	0.29
617.4578857	0.14
621.3095093	0.11
627.4456177	0.06
635.0730591	6.27
636.1455688	1.32
654.3060303	1.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1013
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.7965393	0.03
116.5588150	0.43
117.1688004	0.37
126.8995361	0.26
128.9359131	0.05
134.9339905	0.37
144.9618530	5.22
145.8680267	0.15
156.9641418	0.09
163.0193481	100.00
163.6957092	0.05
172.9172211	0.15
173.9476929	0.38
175.1360474	0.26
181.0199585	0.85
182.1562653	0.08
192.0629272	1.83
192.9359589	0.56
222.1409912	0.08
225.1316833	0.23
235.1314697	0.05
235.9169617	0.14
237.6388550	0.21
249.0726929	0.07
265.1654053	0.17
267.0744019	0.15
268.7892456	0.11
273.1919556	0.21
276.2584839	0.11
284.2138367	0.51
309.1901245	0.13
313.6397400	0.29
314.3376465	0.21
323.2391357	0.08
336.2329712	0.78
337.2904663	1.97
338.3752441	0.22
346.1121521	0.55
346.9127502	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.25
Annotation	Unknow
Peak:m/z	Relative Intensity
171.0301056	0.07
172.9995422	0.06
175.2203674	0.28
178.9566498	0.09
181.1804047	0.01
182.2016144	0.10
184.9184875	0.09
186.9601898	0.03
187.9434814	0.07
189.0337677	0.15
195.4013672	0.02
197.1228027	0.04
197.9815979	0.12
199.0054626	0.99
200.1909180	0.06
201.0845032	0.15
207.2648926	0.14
208.0796814	0.02
211.0859070	0.08
213.2310486	0.16
215.2636108	0.19
217.1921692	0.66
223.1987305	0.20
225.1890259	0.05
226.3179169	0.08
226.9275970	0.04
229.0506897	0.12
231.2101746	0.05
239.1993408	0.06
240.2008057	0.02
241.2122192	0.35
243.1559143	0.31
251.1791077	3.19
253.9462738	0.04
257.0667114	0.31
267.2125854	0.17
269.2992554	0.03
271.2525024	0.04
275.2592773	0.07
285.0723267	100.00
286.2729492	0.17
292.9708862	0.05
305.4147339	0.07
317.0974731	0.08
327.1301270	0.82
335.1558228	0.04
341.2208862	0.02
343.3394775	0.05
353.2672119	0.05
356.0980835	0.02
357.5663452	0.02
360.3217773	0.03
385.0766602	0.38
393.2340088	0.06
395.4423218	0.13
405.5925293	0.19
406.4975586	0.23
407.3108521	0.24
413.1764526	1.09
427.3789673	0.06
431.3107910	9.67
447.2636719	1.09
461.2753296	0.01
463.4733887	0.04
473.4362793	0.13
495.2661743	0.07
503.3781128	0.12
507.0204468	0.08
533.2661133	0.53
546.4335327	0.06
547.2372437	0.19
574.1613159	0.15
575.3793335	0.18
594.3869019	9.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.2333
Annotation	5,8,12-TriHOME(9)
Peak:m/z	Relative Intensity
94.9907608	0.30
96.9685135	0.38
98.9415283	0.34
110.8337555	0.10
114.8312149	0.16
123.0231094	0.09
124.9918060	0.90
127.0074692	0.55
129.0809784	0.09
139.2193604	0.62
141.0919189	0.14
143.1462402	0.09
153.1997375	0.22
155.1681366	1.24
165.0232544	0.53
167.1333923	1.40
168.9772034	0.20
171.0909882	2.57
173.1667175	0.29
177.0422211	0.41
179.1025543	0.10
181.1984253	0.43
183.1838989	6.10
185.1502380	2.16
193.2039795	3.09
195.2031250	0.62
197.0575104	1.46
199.1585236	2.33
201.3679047	0.18
202.0507507	0.05
209.0917358	4.84
211.1765137	63.29
213.3692932	0.08
215.1326904	0.09
218.1835022	0.04
219.5129089	0.09
227.2116699	0.45
229.1541138	100.00
231.0617981	0.58
235.1689758	0.17
239.4634705	0.17
241.2042542	0.11
242.3824463	0.16
243.4026184	0.21
247.5563049	0.13
249.2883301	0.88
257.2210999	0.28
258.5170593	0.13
261.5278320	0.09
265.2423401	0.21
267.1722107	0.63
269.3832703	0.56
271.2135620	0.06
273.2843628	0.16
281.2635193	0.08
283.2264709	1.61
285.2887878	0.46
287.2395325	0.14
291.3430786	2.18
292.2039185	0.09
293.3221436	20.93
299.2208252	0.61
307.0985107	0.09
309.3100891	5.20
311.2761536	30.65
312.3374329	0.07
313.3920288	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	325.0567
Annotation	Tricrozarin A
Peak:m/z	Relative Intensity
102.9185181	0.46
112.9966125	3.37
121.2326813	0.09
130.8287659	0.74
132.9761810	0.21
134.0004883	0.72
146.9581604	0.06
148.9128418	7.44
153.4492493	0.05
158.0802002	0.14
160.9234161	0.07
178.0557556	1.19
179.0974579	0.32
183.0512695	0.09
193.0216370	100.00
202.1361084	0.09
205.0082092	0.09
218.8655396	0.10
221.2550659	0.03
224.7675171	0.22
228.0412292	0.05
241.3004150	0.08
242.3526611	0.21
245.1218872	0.15
246.9829102	0.15
250.1006470	0.06
252.9980164	0.07
263.2196045	0.33
269.3302612	0.24
279.0423584	0.30
280.5692749	0.29
281.2535706	0.40
284.7647095	0.13
293.1573792	0.77
297.3948975	0.13
303.2451477	0.10
305.3886414	0.23
307.1113892	0.91
307.7587585	0.02
309.4517212	0.16
310.1875000	0.32
313.1550293	0.08
325.2211304	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	600.114
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0130463	0.30
167.9200439	0.16
177.1289825	0.32
177.9076385	0.05
179.0461426	3.08
180.0409088	0.86
185.1261444	0.54
193.1744385	0.33
195.2236023	0.16
196.1004791	0.28
197.0171814	0.06
210.0599670	2.19
210.9306641	3.01
212.0502777	0.07
228.2916565	0.06
237.0779877	0.13
254.1668243	8.94
255.0861511	0.63
268.2581482	0.11
272.1067505	100.00
273.1001892	11.02
290.9257812	0.06
306.0551147	1.08
307.3018188	0.41
309.2694702	0.13
311.1156616	0.94
312.2214966	0.05
322.2421265	0.12
323.1862183	0.20
326.0902710	0.23
327.0424194	0.83
328.3725586	0.15
340.2167358	0.47
344.2639771	0.05
355.0716553	1.11
356.3356323	0.20
362.0523071	0.06
365.2643433	0.10
373.1305542	0.22
374.2237549	0.45
379.1736450	0.34
380.4398804	0.13
391.0977173	0.41
392.0185547	0.21
421.8320312	0.64
424.8048706	0.11
440.1641846	91.96
441.2742920	13.01
448.0770264	0.57
449.2264404	0.39
461.0747070	0.07
466.1705322	11.98
467.3139648	2.11
468.2155762	0.06
471.0657349	1.01
472.2186279	0.13
484.1222534	32.71
485.1595459	4.54
503.2554321	0.08
526.9694824	0.14
535.5224609	0.22
553.0940552	0.13
555.9683838	0.13
563.7316284	0.13
581.8662109	0.84
582.5535889	1.60
583.5505981	0.13
601.2876587	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
171.0241394	13.97
184.0512543	6.23
187.2232666	5.79
251.3242798	20.85
255.0510254	18.81
259.3414307	21.08
269.3433228	18.89
297.2485962	12.02
325.2001343	8.65
331.2438354	5.36
347.3162842	17.21
363.1199341	16.63
379.4059448	4.92
385.6068115	26.84
404.4083252	15.48
415.1639404	31.53
417.434021	28.15
419.3630981	7.75
420.8336182	6.69
429.201355	13.50
432.9716797	25.47
437.2852783	6.42
445.6333008	28.26
461.1113281	12.19
475.3701782	10.30
477.211853	7.28
486.4707642	9.35
487.3688354	5.80
491.5541992	20.27
501.190979	100.00
502.0942993	17.27
506.909729	13.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9917
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9422607	8.52
133.0015259	100.00
172.3708801	0.06
189.0723724	0.03
231.1537476	0.22
233.3806763	0.08
243.1498108	0.11
245.0398560	6.00
261.0731812	0.05
262.1341553	0.03
286.1669312	0.29
287.1693726	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3225
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
165.8625488	0.06
183.9542999	42.27
184.5970154	0.10
240.2074280	0.04
246.6775818	0.20
258.2723389	0.99
311.2194824	0.06
335.2864380	0.50
401.4461670	0.30
407.5602417	0.06
441.2155762	0.65
446.7417603	0.55
464.6319580	0.13
468.0038452	0.33
471.4100952	0.07
500.4804688	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9104309	31.01
145.2028198	0.12
194.0594940	0.11
212.7747650	23.72
213.5194092	0.37
226.9094238	0.18
229.1650391	0.21
296.2398682	19.20
296.8717346	100.00
334.2660522	0.27
335.1971436	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.94081879	0.58
95.03083038	0.18
100.8056488	0.38
106.9350357	0.23
108.9475403	2.97
110.9355316	0.81
114.9360809	1.17
118.9333801	0.80
121.0291748	1.48
122.8887482	0.25
126.7314301	1.51
133.0477142	1.49
135.1660461	2.52
136.7663879	0.86
137.4937134	0.55
139.0132294	1.74
140.8430176	0.86
144.9543762	2.35
148.9563599	0.53
150.9281921	0.58
153.0361023	1.01
155.0786743	1.82
157.0741882	0.77
163.0409241	2.82
166.9894104	1.17
169.15448	1.93
171.23172	1.52
173.0826721	0.94
175.0638733	0.85
177.1063232	0.30
178.1940765	0.85
179.1316376	0.72
181.1710968	1.05
182.9723053	0.41
187.8542328	0.86
189.1635895	0.38
193.4680328	1.84
194.8375397	1.38
197.0804443	2.32
198.184021	0.21
201.0493927	1.81
207.1828613	1.21
209.038269	1.75
210.9039307	4.29
213.0363159	0.91
217.3405151	4.11
219.0107727	0.73
221.0850525	2.06
223.2564697	3.28
225.0556946	1.55
226.2953796	1.23
227.2740173	1.56
230.0716553	0.21
232.8885193	2.03
235.1128235	1.94
236.1074219	0.80
237.0959167	3.61
239.1489258	3.28
241.4841919	1.54
247.2431641	2.87
249.2254639	1.11
251.3306885	1.96
253.1494751	7.91
254.2822266	0.91
255.3039551	3.59
257.2288208	1.07
260.3156128	1.43
265.0864258	3.49
266.1810608	0.53
267.4680786	0.92
269.0334473	0.75
269.9804993	0.83
275.2147827	17.35
279.0635071	0.37
283.1143188	1.04
293.2183228	100.00
294.1549072	1.37
295.159668	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.97
Annotation	Unknow
Peak:m/z	Relative Intensity
88.7507629	0.13
114.9671860	0.72
116.9821014	1.09
132.8687897	8.50
143.3569336	0.26
144.1160583	0.62
144.9769287	3.20
148.9335938	0.24
162.9888000	0.16
171.9359436	6.76
172.9825592	0.90
187.9919434	1.17
188.8847809	100.00
189.8215027	0.23
190.9320374	0.55
199.8626099	7.15
200.9798279	3.32
215.9595032	2.11
216.8060303	0.26
229.0242004	2.58
242.0757141	0.14
243.7236328	3.35
245.1169434	3.46
247.2218018	0.67
270.2256470	1.29
270.9699707	3.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.0149
Annotation	Myricatin
Peak:m/z	Relative Intensity
170.9106140	0.20
180.1120758	0.09
182.9577332	0.04
185.7496033	0.03
187.8670654	0.42
188.9360046	0.01
195.9183502	0.07
199.8472748	0.01
200.8494263	0.07
209.0806427	0.07
212.1674347	0.07
214.0074768	0.12
214.9251709	0.31
215.8653717	0.04
227.0944824	0.05
229.0729370	0.83
230.0101013	0.40
231.0643158	0.51
232.1849060	0.02
235.9345703	0.03
237.1248779	0.41
240.8522949	0.04
242.9598846	0.02
254.0202026	0.10
257.0989380	0.16
258.0195618	0.08
266.1018677	0.06
268.3178101	0.03
271.0554199	0.74
273.0289917	0.06
281.1119385	0.59
283.0523071	0.27
283.8083191	0.02
285.6676636	0.02
288.2920532	0.06
298.1301880	0.05
309.0752563	0.03
310.1699219	0.12
315.0950928	6.91
325.1665039	0.16
327.0214233	4.29
332.9586792	0.37
341.1133423	0.36
357.0559692	0.42
359.0817261	100.00
360.0963135	2.96
361.0161133	0.51
361.9619751	0.04
372.9946289	0.05
408.9239502	0.03
416.9651489	0.10
421.7432861	0.06
446.7756348	0.14
448.0156250	0.03
461.1614380	0.27
462.9641113	0.16
466.6221313	0.02
476.0384521	0.02
488.8824463	0.08
504.2440796	1.52
505.1218872	0.27
506.9372559	2.57
515.5011597	0.21
533.0802612	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.0861
Annotation	Kaempferol-3-Glucuronide
Peak:m/z	Relative Intensity
256.9960022	0.02
285.3516235	0.03
287.0507202	100.00
287.6845703	0.22
299.2733765	0.02
300.7584839	0.03
427.3514709	0.04
444.9354248	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2177
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
94.0481873	0.14
95.1067886	0.22
96.9862289	0.32
98.5795746	0.05
109.0482254	0.10
111.0076523	0.54
115.1083069	0.21
122.0978775	0.08
123.0001678	0.82
124.1263809	0.17
124.9745483	0.55
126.0816727	0.21
126.9884567	1.00
128.1779938	0.07
129.2255249	0.06
133.2106934	0.04
135.1321411	0.05
136.0156250	0.08
137.1055756	0.42
141.8245544	0.04
149.2889099	0.14
149.9286804	0.23
151.1618347	0.07
152.9727936	0.11
155.1408691	2.34
155.9534607	0.33
159.1466370	0.28
161.6583862	0.11
163.0402832	0.98
165.0664062	4.36
166.1376953	0.95
167.1762695	0.44
168.2160339	0.35
171.0621033	21.92
172.1742859	2.49
175.1945343	0.11
177.1441650	2.77
178.1458893	0.44
179.4296112	0.42
181.1129913	0.26
182.2143402	0.21
183.1212311	5.27
184.1739655	0.98
185.1496582	2.76
186.2902985	0.33
189.1934509	0.10
190.1550293	0.07
191.1837158	0.34
193.2180939	4.29
194.1977844	0.72
195.0822296	0.11
197.1451263	1.81
198.2337189	0.43
199.1713562	1.27
200.2283173	0.30
201.2058868	0.39
202.1844635	0.17
203.1825867	2.40
204.2402496	0.07
205.2569122	0.19
207.4357300	0.19
209.1205750	14.37
210.1271667	3.31
211.1365051	56.11
212.2265320	8.10
217.1856384	0.24
219.1924438	0.30
221.1097107	18.88
222.1590576	3.22
223.1934509	0.87
224.3270874	0.07
225.2379761	0.09
226.5884705	0.17
227.2535706	2.86
229.1480103	100.00
230.2387085	17.98
233.1755066	0.34
233.8706360	0.06
237.5456848	0.06
239.1142578	13.34
240.2604980	3.19
241.3678589	0.04
245.2057190	0.36
247.1716919	6.01
248.3092957	1.66
251.2927856	0.19
252.2271118	0.07
253.9889221	0.17
257.1865234	0.33
258.1950378	0.89
259.2224121	0.29
263.0932617	0.50
265.2707520	0.27
266.1051636	0.10
267.4297485	0.13
268.0929565	0.05
269.2974243	0.96
270.2892151	0.05
273.1722107	3.89
274.2662659	1.70
276.0885925	0.04
279.3235474	0.54
280.5205078	0.10
281.4285889	0.80
282.3597717	0.25
284.1679382	0.51
285.1358643	0.06
289.3514404	0.30
291.2483521	47.40
292.2800293	14.65
299.4254150	0.68
307.2128296	2.40
309.2414551	17.09
310.1574097	3.06
310.8195801	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	522.2472
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9377747	0.03
151.3100128	0.08
153.0089417	0.11
159.0416565	0.06
161.1045532	2.44
162.0068359	11.65
179.0989380	3.61
181.1193695	0.40
197.0922852	7.93
211.0911102	0.30
213.1154175	0.10
214.9900208	5.82
219.1159058	0.08
221.1419830	0.09
227.1294861	0.02
229.0938873	0.26
237.2056274	0.37
238.2578888	0.03
245.2241516	0.03
248.0507660	0.05
255.0321350	1.48
257.1733704	0.62
269.1571655	0.03
272.2423706	1.89
273.1373291	9.58
273.9546509	0.14
280.9779663	0.03
283.2788696	0.30
290.0780945	2.01
294.4244385	0.03
300.1031799	1.58
306.2416382	0.07
312.1192017	0.03
318.2662354	0.22
324.4990234	0.34
330.0750122	0.26
340.2737427	3.79
358.2161865	8.36
360.4020386	0.19
374.1119385	0.06
375.6096191	1.91
376.2934570	15.21
383.4339600	0.04
387.9133911	0.03
393.2391968	100.00
393.8476562	0.46
401.3903198	0.45
404.0558472	0.10
410.8988037	0.37
423.3541870	0.54
424.4424438	0.06
429.3239746	0.20
440.6721802	0.08
446.1821289	0.10
447.3604736	2.87
455.4594116	0.11
458.6245728	0.27
459.4403076	0.80
465.4909058	0.09
468.3374634	0.05
474.0978394	0.30
476.4149170	0.10
481.7402954	0.08
486.1583862	0.22
495.3736572	0.12
503.3505249	0.02
504.3179321	5.20
505.2601929	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1013
Annotation	Scopolin
Peak:m/z	Relative Intensity
106.8350677	0.03
116.9489288	0.54
135.0619812	0.64
144.9152069	3.99
156.9795074	0.02
162.9022827	100.00
180.0571594	0.03
181.0201111	0.08
192.9838104	0.08
313.8762512	0.01
326.7413330	0.04
337.2414551	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.376
Annotation	all-trans-Heptaprenyl diphosphate
Peak:m/z	Relative Intensity
182.9888916	0.12
187.1715698	0.14
199.0781708	0.16
202.8169403	0.05
217.2561798	0.16
219.0881348	0.47
220.1050720	0.06
221.1491241	0.21
234.9864655	9.41
236.0095673	0.27
245.0536041	0.97
253.0797272	2.06
255.3018494	1.68
256.2597656	0.06
259.2432861	0.09
263.1397095	0.44
264.3294067	0.09
269.2812195	0.36
277.0703125	0.35
287.1777954	5.73
305.0965576	7.40
306.3430786	0.32
316.1043701	0.12
323.0931396	1.03
349.3698120	0.21
354.8887939	0.15
361.2318115	0.62
379.2304077	0.38
392.3016968	0.25
397.2020874	100.00
398.2114868	5.43
398.8502197	0.05
415.2416382	40.62
416.1575317	3.95
417.3695679	0.06
433.3099976	0.15
566.4772339	0.31
591.4293213	0.12
607.1304321	0.33
608.6223755	0.08
609.7572021	0.06
617.9934692	0.21
623.0482788	0.06
631.5336914	0.32
635.4006958	0.14
636.2781372	0.11
654.3178711	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2192
Annotation	Laciniatoside V
Peak:m/z	Relative Intensity
165.0893707	0.24
165.9166260	0.08
179.9001007	0.08
194.9929657	1.13
195.6814575	0.03
207.0339661	0.03
227.2114258	0.10
242.7088013	0.07
263.1827393	0.05
283.2949219	0.16
284.1697998	0.04
284.9874268	0.10
297.9863892	0.03
308.0668335	0.07
314.3352356	1.42
327.1665039	0.10
329.2683716	68.65
343.5560303	0.09
351.3313599	0.05
358.9909668	0.55
374.9641113	0.14
377.0944824	100.00
379.3955688	0.08
403.4466553	0.04
422.4035645	0.18
423.3598022	0.15
461.2969971	0.05
463.3311157	0.14
467.9714355	0.13
475.6710205	0.14
483.0534058	0.10
493.6085815	0.16
498.2944946	0.06
505.6174316	0.04
510.5241699	0.23
525.2813110	0.17
538.3840332	0.90
539.0977173	0.58
540.2693481	0.99
541.2401123	0.73
550.3284912	0.05
554.4691162	0.04
563.0437622	0.35
564.1028442	0.10
566.1393433	0.34
567.2488403	0.39
570.4612427	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	867.232
Annotation	Ormocarpin
Peak:m/z	Relative Intensity
291.0274048	0.09
363.1851807	5.12
364.0095520	0.32
381.2769165	1.47
382.2419434	0.22
453.1958008	0.20
525.2257690	40.78
526.3219604	1.57
543.2374878	19.46
544.2932739	4.05
613.2230835	0.31
615.2745972	0.57
687.3183594	84.36
688.2587891	8.61
705.2958984	100.00
706.3365479	15.23
868.3358154	62.89
869.0003662	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.1201
Annotation	Unknow
Peak:m/z	Relative Intensity
297.2203979	0.07
300.0563354	0.08
323.1206665	0.16
354.2627563	0.06
369.1647339	0.09
379.4677124	0.30
407.5592041	0.12
421.4354248	0.14
441.3698120	0.14
453.0761719	0.04
468.2932129	0.15
475.4571533	0.03
478.3357544	0.05
488.3247681	0.13
505.2171631	21.85
506.3104858	5.29
508.3530884	0.06
526.5236206	0.07
531.4212036	0.18
532.2145386	0.11
533.2730103	0.19
547.4048462	0.47
548.4069824	0.04
549.3800049	0.06
552.4337769	0.05
575.2039795	0.73
576.1383667	0.18
577.2265625	0.93
578.4606323	0.51
587.2819824	0.10
589.4663696	0.25
591.4040527	0.06
601.2725220	0.65
602.1500244	0.14
602.7694702	0.14
604.7506714	0.14
619.3357544	0.91
621.3634644	0.11
628.6603394	0.06
639.3274536	1.45
640.4714355	0.10
663.0045776	0.17
679.4627075	0.18
681.2285767	100.00
682.2053223	22.05
682.8449097	0.27
692.3622437	0.03
694.9813843	0.08
695.8677979	0.12
707.2262573	1.49
708.2877197	0.57
726.0446167	21.40
726.6928101	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.0805
Annotation	Quercetin 7-glucuronide
Peak:m/z	Relative Intensity
285.1826477	0.02
303.0924683	100.00
304.0945435	0.02
314.2728271	0.01
327.0234070	0.13
332.3371277	0.02
345.1027222	0.18
357.0693359	0.01
369.1420288	0.08
399.2247620	0.05
425.3360291	0.03
443.2460022	0.14
461.2155762	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1973
Annotation	Unknow
Peak:m/z	Relative Intensity
113.0426025	1.52
118.9001083	1.09
125.0551605	0.09
130.7806702	0.76
142.9582825	0.84
148.8017426	0.07
152.9091644	0.09
155.2329254	0.42
160.9734802	0.74
177.1142273	0.09
178.7277832	0.47
182.9480591	0.37
193.2401276	0.46
199.1689148	0.27
207.1907349	0.07
209.4284363	0.14
211.1316986	5.55
223.2014160	0.16
225.0027161	0.11
227.2132263	0.10
229.1531677	9.74
243.1385498	0.14
246.0195007	0.19
253.0774841	0.31
258.7919922	0.06
271.2201233	0.12
275.1980591	0.10
281.2106934	0.50
295.0020447	0.14
301.0346985	0.04
303.2227783	0.12
305.2359619	0.07
310.8794556	0.49
325.3105774	0.14
328.3113098	0.07
329.3982849	0.08
330.1788635	0.14
331.2808533	0.78
343.3534241	0.23
345.0135498	0.16
347.1858521	0.11
349.4388428	0.22
354.5265808	0.34
355.3562927	2.00
359.2756348	0.07
371.1488037	0.10
373.2441101	100.00
376.1711121	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2624
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
138.7973938	0.02
139.9889984	0.05
151.0411072	0.01
152.8671570	0.10
179.4656982	0.13
180.2026672	0.01
191.3807678	0.07
195.4577332	0.01
196.1353760	0.14
201.2585449	0.02
206.1415710	0.17
214.1464996	1.59
215.0999451	0.22
219.2432251	0.03
233.2841187	0.81
234.2542114	0.13
235.3456726	0.04
255.1397400	0.01
257.2550964	0.04
259.4037476	0.26
260.3717651	0.01
275.2478027	0.54
277.2377014	100.00
278.2349548	18.67
278.8712158	0.13
293.0057068	0.02
294.1405640	0.08
294.9978943	0.11
299.2751465	0.05
309.2679443	0.01
311.4551392	0.02
312.4721985	0.08
313.3193054	0.03
341.3779907	0.01
358.9739380	0.02
367.4276733	0.02
373.3830872	0.02
374.9916992	0.05
383.5364685	0.02
384.5077515	0.02
385.1389771	0.01
386.3965149	0.02
387.5521545	0.07
388.1634521	0.04
391.3918762	0.01
392.4959412	0.11
393.6131897	0.02
395.0668335	0.01
402.1195679	0.09
404.7254333	0.01
412.1961975	0.02
417.5060730	0.07
419.0074768	0.01
421.2743835	0.02
423.5937805	0.05
428.1304626	0.04
429.3224792	0.13
430.1121521	0.09
431.0976257	0.01
437.6254883	0.02
447.1485901	0.02
456.5276489	0.09
459.2208557	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1196
Annotation	Quinic acid
Peak:m/z	Relative Intensity
110.9088135	0.32
127.0516510	0.25
149.0457458	0.11
149.9959717	0.06
150.9499969	0.04
154.9521027	0.05
171.0319824	0.18
173.1323242	0.38
191.0352173	100.00
192.3488464	0.05
193.1328430	0.06
195.0702820	0.17
203.1033783	0.01
207.1723022	0.09
208.7861023	0.09
232.9146729	0.04
245.1354980	0.12
247.0387573	0.05
262.0406494	0.14
262.8788757	0.17
285.0953369	0.08
292.0074768	0.24
293.1252747	0.94
304.9374390	0.04
323.3366394	0.03
344.9474487	0.07
353.4062195	0.08
354.8623962	0.07
365.1510315	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	667.1517
Annotation	Sinocrassoside D3
Peak:m/z	Relative Intensity
194.0250244	0.04
197.0480804	0.03
199.2848206	0.03
213.0633545	0.12
217.2574158	0.04
221.0793762	0.12
227.1939697	0.24
231.2191467	0.07
233.9964752	0.03
235.2327423	0.04
241.0950012	0.04
242.1629028	0.02
243.1394958	0.10
244.0329437	0.04
255.2007751	0.51
257.1541748	0.25
264.9575806	0.05
271.1601868	0.74
272.0754089	0.04
272.9636230	0.05
279.0558167	0.05
282.0132446	0.07
285.1990356	0.25
286.2207031	0.15
294.1343994	0.06
295.3241577	0.08
297.0993042	0.13
299.0453491	5.86
300.0658569	3.41
301.1122131	41.80
302.1149292	6.32
312.2038574	0.07
313.2040710	0.34
314.1394958	0.25
314.9996338	0.41
321.7899170	0.25
325.1155396	0.85
326.3274231	0.07
327.3408203	0.12
341.2127686	0.97
342.1514282	0.67
343.1896973	3.31
344.2890625	0.67
356.0897217	0.10
357.2119751	0.05
359.3862305	0.05
367.0359497	0.45
368.3009644	0.88
370.4027710	0.02
371.2719727	0.21
373.2327271	0.21
374.1704712	0.06
379.2976074	0.09
385.3002930	0.13
396.3039551	0.10
403.5319214	0.16
410.1997070	0.10
445.5118408	0.16
446.2418823	0.08
459.1080933	0.03
462.2189941	38.90
463.2216797	38.64
464.2711792	8.13
475.3233032	0.05
478.4325562	0.05
479.5342407	0.06
487.4210815	0.13
489.3292236	0.14
492.3395996	0.17
500.4039917	0.05
501.1475830	0.13
505.1965942	100.00
506.2170410	27.95
518.3347778	0.14
519.4564819	0.46
529.4234009	0.14
534.3487549	0.04
535.3726807	0.10
537.0645142	0.06
547.2307739	5.97
548.2922974	2.96
550.6501465	0.18
551.4011230	0.08
552.2726440	0.06
553.4401245	0.21
571.1630249	0.14
572.3558960	0.07
577.2355347	0.12
584.1699829	0.06
589.4313354	0.21
595.0340576	0.06
605.1356201	0.21
607.2507324	1.19
608.3375854	0.19
615.1482544	0.15
622.1154175	0.09
625.2224121	8.48
626.3328247	4.18
631.4749756	0.21
648.7373657	0.09
649.3697510	0.80
650.2076416	0.29
668.2862549	10.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.09
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
92.8135147	0.12
96.9689102	0.31
100.8817673	1.06
106.9197922	3.21
113.0243835	1.23
128.7714844	0.43
132.9611359	0.07
134.9565887	0.59
137.1952820	0.28
142.9167175	0.12
148.9216919	0.36
151.0432739	100.00
153.0421143	0.34
159.1061859	0.54
160.9583740	6.22
165.1147461	0.22
175.1061096	1.47
179.0101624	0.10
184.1287537	0.11
184.8356323	0.06
188.8462830	0.14
193.0692749	1.40
197.0936890	5.75
204.9195557	0.23
212.7767029	0.09
217.0897522	0.37
230.3353271	0.13
233.1211243	0.34
235.0498352	0.35
251.2745056	0.35
252.4269409	0.32
253.0761108	0.59
255.1122131	0.18
267.2488708	0.38
269.2263184	1.00
283.3665466	0.11
288.0650635	0.19
295.1101685	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1457
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
171.0806122	0.01
173.0075836	0.03
174.0464783	0.03
175.0871429	0.37
179.9412842	0.05
195.2223053	0.02
196.9535980	0.11
197.9199371	0.22
199.1040039	0.26
199.9365234	0.08
201.0740051	0.15
202.0903015	0.06
211.2189636	0.09
213.1036072	0.05
215.0343170	0.11
217.1148682	0.35
218.0251770	0.03
223.1984863	0.11
225.0885468	0.23
225.9379730	0.04
229.2936401	0.05
239.0366669	0.03
239.8278503	0.02
241.2053833	0.29
242.2049561	0.15
242.9369507	0.31
249.1824188	0.02
256.2548523	0.06
258.1917114	0.05
267.0491333	0.09
269.0191345	0.08
270.7999878	0.03
285.0598145	100.00
286.1414795	14.34
293.1851807	0.01
300.0715942	0.03
301.1345825	0.48
302.2377930	0.02
313.0666504	0.03
327.2593994	0.56
328.2408447	0.03
337.4378052	0.07
355.1845093	0.05
357.0234985	0.02
385.3668823	0.07
387.1409302	0.04
405.2412720	0.16
406.1433105	0.07
429.4960327	0.02
434.3038330	0.05
447.2131348	4.07
448.2538452	1.16
477.1056519	0.03
488.5878906	0.05
492.4556274	0.04
513.1405640	0.09
515.2057495	0.02
523.2980957	0.07
563.2940674	0.19
564.4724731	0.10
565.2954712	0.03
582.6714478	0.05
610.3016968	0.06
611.3120728	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9753265	0.55
268.0811768	0.08
286.7687378	0.03
298.6759033	0.11
302.9415894	12.36
378.3387451	0.09
379.1419067	0.03
380.2585449	0.24
381.0827026	0.09
382.7014771	0.05
384.5729370	0.15
386.7458496	58.24
387.4256592	0.20
410.8203125	0.05
442.2708740	0.05
466.3390503	0.06
467.6101685	0.12
468.5530396	0.21
470.6766968	100.00
471.3425903	0.13
487.3363647	0.14
495.4866333	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.4175
Annotation	GLYCYRRHIZIC ACID
Peak:m/z	Relative Intensity
267.1508484	1.82
314.1254272	2.86
350.7890015	0.63
398.4104004	0.89
473.1401367	2.21
515.2197266	1.33
530.1918945	1.34
547.3240356	7.07
548.1334839	1.79
551.6934814	2.33
639.6833496	4.80
659.428894	2.03
692.3952026	1.95
740.4464722	1.73
800.6802368	16.66
803.6749878	1.16
820.7832031	4.88
821.3869019	100.00
823.1416626	4.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	731.1418
Annotation	Unknow
Peak:m/z	Relative Intensity
239.2691193	0.12
257.1661987	0.15
301.0146484	0.28
302.5100708	0.47
303.2035522	0.62
304.4807129	0.15
326.9200439	0.14
327.6485901	0.15
345.3687134	0.23
367.9553833	0.22
369.9910278	0.19
377.2861938	0.12
397.2670288	0.24
406.6287231	0.05
434.9731445	0.08
437.3103638	0.38
454.2055054	0.14
464.5165405	0.31
465.7436523	0.08
481.0827026	0.62
483.1414795	100.00
483.7785034	0.78
506.2647705	0.19
507.0148315	0.54
525.2892456	3.93
541.1183472	0.07
549.3493652	0.97
550.4851685	0.19
558.9586792	0.25
563.1117554	0.31
568.3467407	0.06
573.0513916	0.14
579.1582642	0.06
590.3917847	0.24
591.4368286	0.12
596.2824707	0.68
633.4566650	0.22
639.7060547	1.53
654.4978027	0.16
655.3266602	0.42
666.3934326	0.19
669.4494019	1.02
673.3897095	0.10
687.2838745	0.32
694.2785645	0.12
695.2797852	2.01
697.7265015	0.18
712.3783569	0.10
713.1891479	3.43
724.8191528	0.17
731.1129150	1.65
731.7492065	0.26
734.4529419	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	784.2772
Annotation	Unknow
Peak:m/z	Relative Intensity
223.0258331	0.12
247.1317444	0.30
258.5785217	0.11
266.1400146	0.23
277.2879639	0.24
278.3573608	0.31
288.1721802	0.06
303.5746765	0.18
305.0505371	0.79
333.0717163	6.84
335.1193237	0.77
341.1178589	0.11
356.0349731	0.06
359.2841492	0.51
376.4096069	0.13
416.4030151	0.24
437.9145508	0.09
442.3856201	0.13
443.6315918	0.23
444.2396240	0.26
461.2352295	1.29
462.2540894	13.61
473.3510742	0.06
479.1051025	34.52
479.7891235	0.12
493.6306152	0.19
520.9873657	0.39
533.2382812	10.43
543.0905762	0.23
545.0380859	0.48
588.4572144	0.22
590.1934814	0.70
604.6041870	0.18
606.2813110	0.09
608.2226562	100.00
619.1762695	0.55
620.4309082	0.12
621.5087891	0.72
622.3135376	0.39
654.3218384	0.28
655.0865479	1.11
693.8381958	0.06
709.1588135	1.39
739.7072144	0.15
755.2620850	0.38
766.3322144	0.23
783.7276001	0.59
784.3331909	13.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
162.7969666	6.49
217.2201691	12.53
252.3205566	14.50
283.170166	14.69
326.9432373	13.74
331.1303711	5.90
355.9536743	11.92
361.1890869	18.86
367.0968018	6.59
385.7397461	10.13
394.5066528	21.91
397.4074097	10.74
413.555603	11.57
415.4275513	16.42
418.3429565	7.15
421.2299194	19.53
427.4976807	16.77
430.0541382	17.51
433.3922119	49.17
448.7822266	18.56
464.4100342	7.70
473.0077515	26.62
475.0653076	40.93
477.3971558	8.50
487.8442383	26.60
499.4466553	18.19
501.1836548	100.00
502.8131714	16.68
504.5577393	9.70
520.3814087	11.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.213
Annotation	Zeatin riboside-O-glucoside
Peak:m/z	Relative Intensity
163.0596466	0.17
164.9130859	0.07
184.0831299	0.34
187.3340454	0.04
202.0445251	1.56
211.1950378	0.15
213.0616455	0.42
220.1637268	15.44
224.1285095	0.07
228.0121765	0.05
242.3769226	0.25
262.0929565	0.08
293.2694092	0.36
294.2799072	0.48
296.2223511	0.22
307.2280273	0.34
319.1328735	0.30
343.3234863	0.17
345.6524048	0.05
351.5419312	0.83
352.2282715	2.11
357.5524292	0.84
364.0482788	0.48
382.2081909	100.00
384.9804077	0.11
388.0622559	0.05
391.0546265	0.06
400.0958252	0.25
406.4035645	0.20
411.0982056	0.32
426.1380615	0.23
428.1776123	0.13
446.7719116	0.25
459.0630493	0.22
460.4962158	0.26
462.9851685	0.07
483.7864380	0.12
494.2077637	0.15
496.1288452	0.71
497.1657104	0.73
580.2578125	0.28
585.3627319	0.63
635.0006714	0.05
670.4277954	0.61
674.0775757	0.62
679.5500488	0.14
685.0281372	0.17
714.1564331	1.94
715.1076050	1.13
762.8651123	0.15
790.6010132	0.66
863.4519653	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.09
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
133.7914124	0.05
150.9123840	0.70
157.0164490	0.07
159.0653229	0.04
169.0446625	0.13
176.1596985	0.04
177.0326843	0.05
178.9305878	0.81
186.9865723	0.05
188.9696960	0.08
190.1562500	0.07
203.1085205	0.03
206.7807312	0.02
209.0358887	0.02
231.0286713	0.13
233.1139221	0.11
236.2079468	0.21
242.0707397	0.10
243.0151062	0.03
245.1314087	0.03
251.2591248	0.03
255.2040405	0.23
257.3322449	0.13
259.1015930	0.04
269.1721191	0.02
271.3073730	0.35
272.1995850	0.02
273.2455139	0.19
281.0951538	0.07
283.1938171	0.36
285.0950928	52.19
286.0953979	100.00
287.2088013	14.04
297.2791443	0.10
298.2871094	0.54
300.1102905	15.95
301.0880432	47.84
301.9284363	0.03
307.1870728	0.04
311.3299255	0.03
313.1377563	0.03
319.2299500	0.05
325.1867065	0.34
327.0588684	1.54
328.1713867	3.68
329.1714478	0.39
332.2044067	0.08
338.1736145	0.32
340.2081909	0.33
341.3229370	0.03
343.2769775	0.94
344.0960388	0.10
351.1327820	0.04
352.1765137	0.64
353.4854736	0.08
354.3276978	0.35
355.0800171	0.69
356.2202148	2.19
357.3833618	1.38
358.1438904	6.74
359.2001953	1.06
363.0533447	0.02
364.2259521	0.48
365.3391113	0.17
369.1798401	0.27
370.1504517	2.44
371.1268005	0.59
372.2747192	0.29
373.3049622	0.03
380.2401123	0.03
381.1040344	0.06
382.1494751	3.73
383.0634460	0.30
399.0444641	0.04
400.1105652	0.24
401.3426819	0.03
403.2875061	0.09
409.4591980	0.07
417.1832581	0.04
418.6172791	0.17
419.4894104	0.02
433.5547180	0.07
444.1922302	0.21
445.1226501	0.07
464.1221008	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
149.0412292	0.82
162.9100189	1.11
165.2765961	0.95
178.866684	0.83
188.957962	0.99
206.8729553	100.00
207.9482422	8.03
209.2267609	1.51
214.6370239	2.45
220.1918488	3.21
222.5608521	6.11
223.2046051	1.21
224.0986633	1.28
224.9846649	4.22
232.930481	5.33
250.1745758	1.70
251.068222	53.88
252.0952759	2.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.04
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
86.9733353	0.07
102.9440460	0.40
104.7662582	0.16
112.9198303	0.27
131.0390167	0.28
135.0241089	3.10
148.9346924	100.00
149.6921234	0.11
179.0624847	57.71
238.8931580	0.04
267.0133972	1.00
292.9465942	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.2129
Annotation	Maryal
Peak:m/z	Relative Intensity
124.8781128	0.05
131.0606995	0.11
132.1813049	0.01
142.9943390	0.15
144.2668152	0.02
146.7696533	0.02
150.0751953	0.03
154.9913025	0.02
160.9511871	0.37
178.2265320	0.03
179.0724792	0.04
180.1384277	0.02
182.8068848	0.02
191.3334045	0.04
193.1399994	0.02
195.1298828	3.01
196.1952209	0.43
203.0197144	0.01
209.2694702	0.62
210.1791534	0.08
213.2282562	1.48
214.4096375	0.17
219.0177002	0.15
220.5321655	0.03
226.6734772	0.01
227.4998932	0.02
228.3766174	0.03
236.2974243	0.02
237.0820618	0.67
238.2478027	0.05
249.3317261	0.09
250.0998230	0.01
255.3782349	0.08
259.2544861	0.02
260.4209290	0.01
267.1405640	0.12
268.2076111	0.08
269.1180725	0.01
275.2716980	0.03
278.5932617	0.03
279.3770142	0.09
283.3751526	0.02
284.3843689	0.09
291.3457031	0.04
293.2900085	0.07
295.4851685	0.04
297.2789001	0.03
298.1528320	0.01
313.4245605	0.02
319.2412720	0.02
321.3226318	0.06
327.5514526	0.01
331.0643311	0.03
339.3530579	0.07
340.1170654	0.01
357.2963257	44.30
358.3724060	11.70
359.2989502	0.02
375.3190002	100.00
376.2734985	30.92
376.9173279	0.04
380.0324402	0.02
381.6311646	0.04
399.3308411	0.56
400.3053894	0.17
426.1815796	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.2941437	0.70
212.9033203	1.83
280.8742676	0.43
296.1865845	4.60
296.8397827	43.24
380.5796509	100.00
381.3379517	0.19
417.9254761	0.21
464.5241699	50.28
465.2532959	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	819.3452
Annotation	Unknow
Peak:m/z	Relative Intensity
323.3063965	0.05
337.2560425	0.66
377.1939697	0.12
428.3881836	0.03
565.7495117	0.07
571.4239502	0.23
607.4743042	0.21
639.2272339	0.06
650.2555542	0.05
656.4933472	0.38
664.2928467	0.20
665.3178101	0.50
669.2525024	0.13
673.0677490	0.27
676.1150513	0.15
697.4544067	0.14
709.6626587	0.09
714.6923218	0.07
733.7427368	0.10
742.5579224	0.06
743.3520508	0.26
745.4411621	1.07
750.4248657	0.20
755.4334717	1.40
757.6994629	0.21
759.5806274	0.13
768.4351807	0.06
773.3922119	0.19
775.7748413	0.48
786.5847778	0.12
787.4088745	2.48
819.5006714	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.0808
Annotation	Quercetin-3-Glucuronide
Peak:m/z	Relative Intensity
146.0287476	0.01
163.0350647	0.03
179.1393433	0.03
195.1385803	0.03
211.062561	0.01
215.1732788	0.01
220.2391052	0.02
224.9234009	0.03
231.0500183	0.02
235.1257324	0.06
238.1037445	0.01
245.0897064	0.04
253.1492615	0.01
263.0935364	0.01
271.0815125	0.03
277.2011719	0.02
281.3545837	0.03
286.3065491	0.02
294.9794006	0.03
297.1665955	0.04
299.2634888	0.02
303.0557251	100.00
304.0412903	0.09
309.0726929	0.03
311.0343323	0.03
312.1978149	0.02
313.1246338	0.02
315.3135376	0.23
316.1058044	0.19
317.175415	0.04
319.1435852	0.06
333.1145325	0.04
335.0348816	0.01
342.0787964	0.01
347.5437927	0.03
359.2980347	0.06
361.3961487	0.02
363.1161499	0.04
368.3462524	0.02
375.0151062	0.01
387.6014099	0.06
388.3658142	0.05
391.1247864	0.05
399.3635864	0.07
405.1238098	0.05
419.2418823	0.04
420.0213623	0.01
433.1937561	0.26
434.0205078	0.06
438.2125549	0.04
442.0126343	0.14
443.1261902	0.06
448.2466736	0.08
451.0914307	0.12
458.085907	0.06
460.2110596	0.19
461.2987366	0.34
462.320343	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.1307
Annotation	4-Deoxy-4-thio-alpha-D-digitoxosyl-calicheamicin T0
Peak:m/z	Relative Intensity
255.1395111	0.05
269.3936462	0.29
278.9631348	0.15
300.1754456	0.43
301.1838989	1.21
326.2763672	0.13
339.3475952	0.04
341.3084412	0.04
342.0545044	0.08
353.5033875	0.06
370.9559937	0.07
416.4814453	0.04
434.4104614	0.05
463.2130737	0.40
488.9644775	0.06
505.2937622	91.44
531.3030396	16.43
535.3833008	0.10
549.3701782	0.23
552.2108154	0.22
553.2886963	0.10
563.2763672	0.09
567.2543335	0.22
575.2760620	0.19
575.9931030	0.33
578.9634399	0.10
630.3780518	0.09
631.1806641	0.34
633.4335327	0.10
640.9316406	0.26
641.7628784	0.04
643.3345947	0.26
665.3772583	0.10
666.4998779	0.38
667.4423218	0.25
682.7548218	0.28
683.9658203	0.46
685.2731323	46.97
693.6755371	0.04
710.1312256	0.74
711.1726074	0.41
729.1264038	100.00
729.7666626	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.2555
Annotation	5beta-cholestan-3alpha,4alpha,11beta,12beta,21-pentol-3,21-disulphate
Peak:m/z	Relative Intensity
178.9278259	0.09
189.1582947	3.52
207.0912018	5.81
208.1147461	0.99
210.1653442	0.61
215.3291016	0.28
218.5996704	0.15
232.9898987	1.81
234.0432281	0.08
251.1306763	91.78
252.1920013	9.97
269.1988525	3.89
270.0741272	0.09
276.3287048	0.19
292.7140503	0.28
293.9160156	0.12
311.0501099	0.20
330.4660645	0.09
354.1632690	0.11
372.3850098	0.24
373.1188965	0.47
387.2648926	0.40
413.3723145	0.68
431.2125244	100.00
432.3564453	18.02
445.0763550	0.27
449.2917480	8.35
450.2662354	1.05
479.5485840	0.33
491.3098145	0.32
503.4231567	0.07
551.3923950	0.10
563.1950073	0.22
591.3925171	0.17
593.4844360	0.29
612.5809326	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.0803
Annotation	Unknow
Peak:m/z	Relative Intensity
127.1635056	0.07
130.9335480	0.24
132.0369110	0.13
133.0788879	1.23
134.3980713	0.36
135.1324158	1.87
137.0016022	0.34
140.8265686	0.43
145.1532288	0.11
149.2104034	0.11
161.0251007	2.29
162.0600128	0.05
162.9322510	0.04
165.4286499	0.10
173.0772705	0.19
179.0540161	9.05
185.2814941	0.12
186.2707520	0.05
191.0050812	11.15
191.9845123	0.29
203.2150116	0.15
205.2312469	0.16
208.9625549	0.22
214.1869507	0.11
219.0881042	2.50
221.1193085	0.41
221.9261322	0.05
227.3304443	0.19
231.1304932	0.36
232.1955872	0.11
236.1888123	0.08
243.1206970	2.17
244.1734009	0.14
249.1616821	0.04
250.4166260	0.06
254.2563171	0.02
255.2966309	0.04
257.1485291	0.12
266.3165283	1.03
267.1643677	0.07
270.0061951	0.06
275.1167603	0.30
278.9139099	0.02
279.7226562	0.03
283.2935791	0.21
289.0474854	0.06
293.1728210	35.83
294.3235168	0.08
311.1115723	0.44
314.9369507	0.12
317.1181030	0.12
322.0242004	0.21
322.9517822	0.10
324.2700195	0.21
325.2577820	0.48
326.1071167	0.30
332.1604919	100.00
332.9853516	0.11
334.3552856	0.04
335.0703125	0.13
339.0142517	0.21
340.0143738	0.21
340.9855652	0.97
347.1098022	4.42
347.8656616	0.33
352.0939331	0.17
353.2907715	1.61
357.0193176	0.12
358.0332336	0.06
360.5223694	0.47
366.0327454	0.04
367.2077637	1.37
368.4073486	0.19
369.1189270	0.43
370.3750305	0.14
374.9273376	0.41
391.0431213	0.36
392.1961670	0.05
395.1506042	0.36
399.1180115	0.15
404.2088928	0.63
473.1418762	0.21
474.3204041	0.32
487.2344360	0.10
489.4745178	0.14
490.4839478	0.07
501.1404419	0.14
503.2684021	1.93
504.1773376	0.05
513.3682251	0.17
515.2322388	1.17
516.1863403	0.09
531.2639771	0.19
533.1736450	43.16
534.2674561	2.15
559.0618286	0.04
575.3518677	0.77
603.1993408	0.72
623.3502197	0.05
628.6173096	0.10
647.2216187	7.60
648.1970825	0.78
650.3865967	0.03
663.5109253	0.05
665.2585449	6.01
666.4390869	0.68
667.9859619	0.20
669.3178711	0.15
711.2573853	0.37
712.8240356	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1194
Annotation	2'',6''-Di-O-Acetyl isovitexin
Peak:m/z	Relative Intensity
155.0788116	0.06
160.9622192	0.12
171.1455231	0.02
173.1058502	0.34
179.0823975	2.12
191.0181732	5.01
203.0787354	0.09
227.2035217	0.03
255.2015228	0.02
298.9998779	0.07
335.1328735	0.47
353.1282349	100.00
379.3062134	0.08
434.3047485	0.24
469.3567505	0.05
496.3774414	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1035
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
109.0070190	0.58
120.9738998	9.59
122.7910233	0.06
124.0151520	0.15
134.8933105	1.24
135.9674072	0.34
138.9565430	100.00
139.7307739	0.06
148.9807739	0.55
152.9801941	0.05
162.8672485	0.08
166.2279968	0.11
167.1266632	0.05
179.0573273	0.52
180.1176910	0.27
181.0624390	1.49
190.3463745	0.09
192.7926788	0.17
203.2385712	0.22
206.8090210	0.06
210.2967224	0.40
211.0057983	0.35
222.6541138	0.08
226.0700378	0.06
227.0879517	0.22
232.7789001	0.06
234.1345520	0.96
235.1612244	0.19
239.0525818	0.23
251.1556396	0.06
252.2237549	0.12
253.1778259	1.13
254.2359314	0.25
257.2095642	0.51
270.1637268	2.48
271.2401428	0.85
278.9413147	0.14
280.0952148	0.11
283.2288208	0.32
296.9082031	0.34
298.1433716	0.19
299.1439819	0.06
301.3030396	0.52
307.0139465	0.52
311.1685181	0.39
314.4215088	0.44
315.0234375	0.24
325.0000305	0.19
326.3080750	0.08
327.3423157	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0726
Annotation	Unknow
Peak:m/z	Relative Intensity
99.0315018	0.07
100.9467773	0.65
103.0456238	0.43
112.9732513	2.30
115.0632324	0.06
118.8366318	1.94
124.9242477	0.27
128.0673065	0.13
129.0382385	0.05
130.9546509	3.72
137.0669556	0.05
141.0296021	0.24
142.9923401	1.24
148.9501038	100.00
160.9785767	1.34
167.1383209	0.15
168.8274231	0.12
172.9884644	0.15
179.0415039	7.58
183.1665802	0.09
189.4075317	0.23
191.2468262	0.03
195.2529907	0.28
196.1757812	0.06
199.1005402	0.16
204.9690857	0.06
208.2779541	0.09
208.9756470	0.11
211.1709595	0.15
220.1399231	0.04
221.1062317	0.13
228.9712219	0.15
233.4320984	0.27
234.1309814	0.90
235.0940552	1.32
241.2534485	0.22
242.9110107	0.07
250.2746582	0.08
255.0797119	0.11
263.1173706	0.07
265.0860291	0.07
276.6576843	0.09
279.9581299	0.65
281.2049561	0.31
284.8763428	0.42
294.9064636	0.37
303.2282104	0.08
311.2428894	0.16
312.3129272	0.07
313.0883789	0.18
322.6605225	3.44
323.2888794	1.41
331.0984192	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.0145
Annotation	Myricatin
Peak:m/z	Relative Intensity
154.9760284	0.02
168.2661896	0.02
168.9669495	0.01
169.9706879	0.03
171.0065613	0.21
174.0204926	0.01
187.9697266	0.41
191.0396881	0.02
199.7931061	0.03
201.9749146	0.01
211.9513550	0.03
212.7733765	0.10
214.9330292	0.72
216.1182861	0.14
217.0486450	0.03
224.9823456	0.07
227.0243988	0.03
228.0360718	0.07
228.9906616	0.58
229.9082336	0.12
231.0621338	0.34
232.8952179	0.01
235.9772339	0.01
237.1483765	0.66
239.9666595	0.05
253.0157166	0.06
254.0416718	0.11
255.9933624	0.03
257.0168152	0.22
258.0686646	0.35
266.0252075	0.07
266.9840393	0.02
271.0834961	0.72
281.0431519	0.42
283.1248779	0.16
283.9630737	0.03
286.3976135	0.02
287.1849365	0.09
297.0759888	0.12
298.0890808	0.10
302.8995972	0.01
306.4068604	0.08
309.9144897	0.18
313.2392578	0.04
315.1197510	7.66
315.9526978	0.03
324.9917603	0.21
327.0677490	3.17
332.1938477	0.04
333.2374878	0.34
339.0109253	0.02
341.1680908	0.32
342.9664307	0.07
346.6563110	0.16
357.1231079	0.27
358.9988403	100.00
360.0633545	2.96
360.9588013	0.57
367.8405762	0.04
370.1646118	0.02
373.2110596	0.02
378.5112915	0.05
401.2107544	0.04
404.4630737	0.02
416.7227783	0.11
419.3189697	0.06
422.2354736	0.03
428.8125000	0.03
445.2072754	0.02
446.1833496	0.01
447.1088867	0.16
461.1213989	0.08
463.0835571	0.04
479.2941284	0.04
483.5507202	0.08
488.9232788	0.10
496.4175415	0.02
507.1278076	2.55
515.1829834	0.03
528.9643555	0.07
532.1483765	0.16
533.0441284	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.1086
Annotation	Unknow
Peak:m/z	Relative Intensity
176.9328918	0.17
179.1160278	3.12
179.8611450	0.12
183.3624420	0.08
185.0962372	0.15
187.2618103	0.08
192.6274109	0.51
193.2866211	0.43
197.0546265	0.40
197.8412323	0.19
210.1123047	1.77
211.0742188	2.23
228.0860596	0.43
236.4971466	0.09
249.2290649	0.08
254.1301575	9.71
255.1673584	0.64
260.2467651	0.14
268.3003235	0.45
272.0977173	100.00
273.1994019	8.23
278.2315063	0.14
284.4537354	0.07
306.0064087	0.49
310.9764099	0.82
321.9574585	0.07
341.1751709	0.71
343.2445679	0.68
355.1843262	0.74
356.2958374	0.15
368.2576294	0.21
379.2350464	0.60
380.2034302	0.19
421.9417725	0.63
426.1027832	0.17
431.1965332	0.06
440.1705322	86.04
441.2183228	14.38
447.9846802	0.56
451.3321533	0.07
466.2598877	14.12
467.3063965	2.92
484.1290283	42.82
485.0903931	2.83
487.2193604	0.87
488.2432251	0.42
527.3806763	0.30
543.4699097	0.07
554.4193115	0.25
572.5440674	0.06
580.4647827	0.21
597.9531860	1.25
598.6835938	0.23
599.3087769	0.07
617.4794312	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0477
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
158.7422028	0.06
164.0709686	0.03
193.2592773	0.11
211.0375061	3.33
241.0940552	2.01
273.0954590	0.28
280.1080933	1.46
286.9160156	0.02
292.8936462	0.13
304.9801025	0.58
312.8606567	0.03
321.0477295	0.91
323.0944824	100.00
385.0475464	2.77
390.7957153	0.21
392.8746338	0.05
394.9041138	0.36
396.9807129	0.28
403.1146851	2.75
428.8196411	2.84
429.9983521	0.16
467.2274170	0.96
476.9111938	0.08
478.7879028	1.14
480.7840576	2.90
547.3077393	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.2
Annotation	Unknow
Peak:m/z	Relative Intensity
136.0308685	0.04
138.0072632	0.36
146.8034821	0.06
148.8294678	0.12
155.9592438	0.37
161.0496521	0.19
162.8030701	0.12
166.1265869	4.20
179.9969482	0.38
182.0268250	0.07
188.8074341	0.06
198.0372314	0.29
206.1661987	0.24
214.0890045	0.11
224.0235596	0.08
226.6288300	0.12
228.6922607	0.10
239.1774902	0.40
251.3025208	0.21
258.3223267	0.33
260.1982727	0.23
262.3420105	0.54
267.1767578	1.00
270.4664307	0.37
271.1708069	0.19
272.2830200	0.40
276.2212830	1.33
281.3885498	0.28
285.1573792	6.11
286.1621399	0.21
290.1704407	0.33
291.0632324	0.32
297.0717163	0.17
303.1459351	15.44
304.1216736	4.93
308.3198853	0.15
314.2165527	0.17
321.1170654	100.00
321.7612915	0.32
322.7200928	0.64
324.4271851	0.49
325.8786011	0.47
327.7455750	0.14
335.0427246	0.17
336.4216309	0.14
338.9164124	0.18
341.9823608	0.16
354.3513794	0.21
367.1220703	0.14
371.0244751	0.22
377.3193054	0.05
385.0494080	0.18
387.3047180	0.16
392.8525696	0.07
402.2430115	0.30
403.0635681	0.10
408.0802917	0.11
409.9653320	0.59
411.2220154	0.08
414.4808044	0.15
418.3330994	1.89
419.0088196	0.63
422.7594299	0.57
423.4450989	0.50
424.3852539	0.22
428.3061829	0.06
437.2585144	0.09
445.8935242	0.86
446.5168152	0.28
447.7487488	0.26
456.1683350	0.50
462.9928894	0.06
465.2328491	1.64
466.5748596	0.25
473.6153870	0.29
474.4231873	0.40
477.9983826	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.78152466	1.63
97.00540924	0.66
107.0129547	0.31
112.9798965	0.29
114.8287888	0.29
121.0036316	0.67
122.9563675	2.33
124.9884567	2.28
126.8651886	1.10
129.1056366	0.74
130.977356	1.07
133.0021057	0.38
134.898468	1.39
137.0863647	0.81
138.9449463	6.41
141.1574097	1.23
142.8826294	1.41
145.1466064	1.86
148.9564209	1.24
150.8309326	1.05
153.090744	0.93
154.9593811	2.05
165.0485382	0.36
167.1400757	1.30
169.2877655	2.27
171.1019897	0.45
173.1404266	0.27
177.2161102	0.98
179.2564392	0.20
180.8895264	1.12
183.0460358	3.41
184.8730621	0.55
187.2028961	1.80
189.1612396	0.92
191.2454834	1.55
193.1018372	1.62
194.8780518	0.42
197.0592651	2.11
199.2335968	1.52
203.4196777	0.48
205.2198486	0.85
207.0341797	0.78
209.0597839	0.25
211.0211792	5.18
212.7207947	0.31
215.1409302	1.48
217.0292969	0.41
218.9827271	0.34
223.302124	4.39
225.3179932	0.83
227.0555725	1.76
233.1519775	1.33
234.8575745	0.76
235.765564	1.11
237.2149963	2.35
241.2077637	0.88
243.1234436	1.37
247.0147705	0.34
251.258667	1.85
252.532196	1.26
253.1412964	4.18
254.9726562	1.13
257.1323853	4.28
265.3061218	0.40
267.1184692	1.62
269.2537842	3.05
271.2774048	0.47
275.1368408	22.38
276.5756836	1.48
281.0448303	0.44
289.8345337	1.45
293.2134399	100.00
299.9729614	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1019
Annotation	Delphinidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
165.2344360	0.06
183.2545013	0.02
212.9847107	0.02
219.0465088	0.03
229.1430359	0.03
231.1233368	0.09
247.1830597	0.01
249.0682220	0.02
257.0618286	0.03
285.1658325	0.10
298.3257446	0.04
303.1244202	100.00
303.9703979	0.01
305.6487427	0.02
327.2097778	0.27
343.0423584	0.06
345.1840820	1.53
369.2661743	0.32
393.3068237	0.06
411.2783813	0.38
429.3695068	0.04
447.1107788	0.14
453.2805786	0.00
465.2283936	0.11
471.1553955	0.03
485.3305054	0.00
489.2722778	0.10
497.3610840	0.06
507.3068848	0.03
515.1782227	0.41
533.1715698	2.09
533.8390503	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1404
Annotation	Racemosic acid
Peak:m/z	Relative Intensity
161.0240784	0.30
162.1212006	0.13
171.0356750	0.50
173.0261688	1.49
174.0750885	0.06
179.0859680	3.90
180.0067291	0.23
191.0415344	100.00
192.0735626	11.03
203.1593628	0.31
213.0375366	0.26
214.9971313	0.06
216.0535583	0.18
228.0940857	0.15
233.2152100	0.05
254.1485138	0.15
267.0503845	0.09
272.2117310	0.17
277.3895874	0.08
282.2514648	0.16
288.1423340	0.07
301.3351440	0.06
306.2937012	1.24
307.3718262	0.15
308.4205322	0.06
315.1840210	0.07
323.1641235	6.65
324.2588501	1.54
333.0938721	0.43
337.0863647	0.23
338.2568970	0.09
341.1430664	0.96
342.0883789	0.07
353.1068726	76.56
354.1880493	11.70
367.8795776	0.06
378.3700562	0.07
384.4306641	0.10
387.7205200	0.04
389.3331909	0.08
394.2852783	0.12
395.2371216	1.99
396.2558594	0.51
400.2780151	0.19
420.2622681	0.11
421.2045288	0.05
425.2793579	0.08
443.4846191	0.11
454.1253662	0.41
455.0291138	0.13
455.6823120	0.61
470.1990967	0.65
471.4190063	0.48
472.1896362	0.13
476.1179199	0.05
480.3969116	0.46
481.4492798	0.39
485.4909058	0.41
497.4445190	0.22
498.4091797	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9102631	0.07
206.8007660	4.83
216.0820618	0.05
223.0182190	3.63
228.8841553	0.06
268.0357666	0.04
289.2947998	0.12
290.7410583	100.00
291.3595886	0.81
307.0535889	0.32
339.9626770	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	406.1655
Annotation	O-Methyl-waltherione A
Peak:m/z	Relative Intensity
124.1134644	0.13
125.3108673	0.27
125.9705124	0.17
126.8640518	0.66
127.9850769	6.46
130.5444489	0.15
133.0356750	0.36
134.9681854	0.97
141.0992889	0.04
143.0479736	10.90
144.3087463	0.08
145.0970612	1.04
146.0105591	1.01
153.0921936	0.27
155.1935425	0.19
160.9619141	0.05
165.1430969	0.09
166.1820679	0.86
167.1111450	3.44
170.0686951	0.76
171.0765381	2.04
175.0805206	0.54
176.1772156	0.06
178.9988708	22.74
179.7808075	0.03
184.9620361	0.40
185.9701996	0.07
192.0978699	1.10
193.0084229	0.07
195.1840210	0.06
197.0468750	1.41
210.0933533	13.30
219.9692993	0.11
225.3590393	0.08
228.0986023	0.75
236.0668945	2.47
242.7983398	0.28
250.9692688	0.13
254.0770569	100.00
260.3054504	0.09
272.1604004	54.57
275.2217407	0.05
277.2189331	11.63
289.1094360	0.25
306.0346985	1.25
307.1382446	1.53
308.0919495	2.31
313.3867188	0.13
320.8015442	0.20
324.1900024	0.17
330.8432007	0.04
341.3488464	0.05
343.2665405	0.16
344.2139587	0.16
346.6150513	0.08
356.3959045	0.20
357.2826233	0.14
358.4284668	0.18
359.4255066	0.07
361.0563354	0.23
362.1871643	0.08
363.0458984	0.10
369.2938843	0.06
370.3937683	0.05
374.3768005	0.09
376.5804443	0.29
388.2030945	37.69
389.2494507	0.14
391.1074829	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	951.17
Annotation	Unknow
Peak:m/z	Relative Intensity
275.0019836	0.19
276.1083984	0.12
293.2644653	0.29
294.2292480	0.35
295.2700195	0.45
311.3402405	2.08
313.1041870	0.22
314.0709229	0.25
473.0428467	2.24
474.1029663	4.90
475.0581665	6.69
476.1326904	2.34
594.3554688	0.12
606.0964966	0.16
768.4895630	0.65
787.0722046	0.30
949.8283691	100.00
950.8016968	4.70
951.4223633	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0786
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
113.0121613	0.02
139.9392242	1.38
145.1201324	2.46
158.0925751	0.08
167.0138245	0.16
169.1276855	0.08
175.0992584	0.03
185.1657562	0.05
187.0403137	0.05
194.1481781	0.04
196.0084229	7.10
202.1389618	0.02
205.0992432	0.09
211.1388245	0.26
211.8655396	0.05
213.0337067	100.00
214.0014038	1.58
215.1788940	0.13
215.9538116	0.02
230.9585114	24.29
231.6291656	0.06
232.9393158	0.07
241.1348419	0.39
241.9478607	0.09
258.6692810	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1143
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
142.9649200	0.02
179.0418091	0.38
225.1853027	0.02
251.0761719	0.09
268.4304199	0.02
281.1062622	0.03
323.2756348	0.05
341.1644592	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1975
Annotation	Ethyl 7-epi-12-hydroxyjasmonate glucoside
Peak:m/z	Relative Intensity
118.8144226	0.03
130.6465759	0.04
136.7442017	0.06
140.9790039	0.10
143.0131226	0.33
151.1171570	0.05
154.8105469	0.23
161.1145477	0.22
173.0851440	0.16
177.1118164	0.26
178.8998718	0.08
179.5699158	0.05
184.5770721	0.03
185.3838806	0.10
191.2282715	0.34
193.2267456	0.01
195.3076477	0.09
201.2261963	0.07
203.4043884	0.02
209.6896667	0.12
211.1539917	0.49
223.2100830	0.10
225.3406982	0.03
235.1595764	0.24
253.1532593	0.24
263.6068420	0.11
265.2680054	0.10
272.1247559	0.09
275.2664490	0.05
279.3794250	0.04
282.4728699	0.09
287.1014099	0.05
295.3336792	0.05
300.0925598	0.07
301.4696350	0.05
308.2996826	0.03
311.3574829	0.44
315.4888306	0.07
319.1902771	0.15
323.7152710	0.03
325.5134888	0.11
329.3162842	0.63
335.5177612	0.23
337.3806152	0.10
350.8525391	0.02
353.4885559	0.08
355.2935181	31.04
365.4245911	0.05
369.1228333	0.37
371.2141418	0.11
373.3374023	100.00
378.2088928	0.25
379.2191467	0.22
380.3708496	0.04
383.3612366	0.08
386.9855347	0.02
389.1744690	0.04
396.3326721	0.15
397.3829041	0.46
405.1912231	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.0306
Annotation	Caftaric acid
Peak:m/z	Relative Intensity
87.0094986	0.07
94.9252853	0.09
99.0089569	0.16
108.9708405	0.77
110.8659363	0.29
112.9626846	2.92
126.8471985	0.73
130.9143829	0.12
135.0260315	1.36
136.9849548	0.74
138.9145203	5.43
154.9182739	0.43
160.9868011	1.01
163.1634216	0.02
177.1182098	0.89
179.0105133	0.25
187.1051331	0.48
190.1324921	0.02
190.8789978	0.03
201.3533020	0.08
205.0589600	1.69
219.0864563	100.00
221.0058289	1.85
231.0679016	7.92
246.9346619	0.02
249.0140381	1.65
249.6154785	0.05
264.7958984	0.02
275.0834656	24.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	657.3854
Annotation	Unknow
Peak:m/z	Relative Intensity
231.2182007	0.07
253.1058044	0.10
271.1302490	0.15
273.4519043	0.14
281.5435791	0.07
311.3544312	0.28
329.4094849	3.22
338.1557922	0.08
363.2395020	0.26
373.1169434	0.13
399.4557495	0.14
408.6303101	0.22
431.5155640	0.07
434.2498779	0.07
447.7696533	0.16
449.4235840	17.56
455.5145874	0.12
463.5969849	0.68
465.7825317	0.12
471.4032593	0.71
475.3884888	1.18
476.8309326	1.22
477.5935669	3.89
479.7165527	0.37
491.5493164	1.70
493.5358276	0.98
494.3914185	7.91
495.4478149	100.00
496.0964966	0.50
501.1442871	0.08
502.2974243	0.67
509.0190430	0.29
519.7014771	0.31
522.3737183	0.11
531.0962524	0.29
534.3948364	0.15
535.4548340	0.18
537.2421265	1.30
559.4658813	0.11
561.0746460	0.16
569.4461670	0.06
573.2294312	0.14
581.2614746	0.27
593.2941895	0.29
597.2510376	0.73
597.8522949	0.10
602.6601562	0.07
607.1543579	0.05
611.2978516	0.53
613.5058594	1.01
614.5782471	0.32
621.8629761	0.10
625.2645264	0.63
627.0387573	0.14
639.3582153	1.86
641.7641602	0.38
657.4971313	2.19
658.5646973	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.5607
Annotation	Unknow
Peak:m/z	Relative Intensity
95.9805756	0.12
105.9610748	0.86
111.1457977	0.11
122.8704224	100.00
124.0957794	0.14
135.9041138	4.02
150.9593048	0.10
162.8059692	0.09
164.3359070	0.11
170.1541748	0.23
180.9041290	0.27
181.7632446	0.12
182.8685913	0.36
193.1690674	0.26
195.1069336	0.09
201.2289886	0.12
214.2236938	0.15
215.8490906	0.05
227.0739441	0.10
230.2416992	0.05
231.9754944	6.55
233.8342285	0.04
234.8915710	0.09
237.2578430	0.41
239.0882568	0.10
240.1256409	0.04
254.8549194	0.06
258.8702698	0.31
264.2976685	0.06
271.2130127	0.12
272.0687866	0.07
273.0617676	0.18
286.0556641	0.51
286.9769287	0.38
287.9759216	0.25
289.1352539	0.44
291.1893311	0.31
291.9565430	0.34
296.1305542	0.16
301.6481323	0.25
304.0622253	0.27
311.2090759	0.50
312.1775818	0.60
313.7846069	0.73
314.8840027	1.18
316.5746460	0.14
348.0045471	0.11
389.1257019	0.12
410.2427673	0.91
419.1349792	0.27
423.0446167	0.38
427.5804749	0.11
428.1924438	4.77
444.2836609	0.72
472.3572693	0.28
524.0967407	52.84
525.1996460	0.43
529.3946533	0.61
542.0924683	74.41
543.0835571	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1145
Annotation	Unknow
Peak:m/z	Relative Intensity
163.2691650	0.05
173.0087738	0.14
178.9770355	0.33
192.2246552	0.05
194.1931610	0.25
195.1422119	0.49
213.1310425	0.16
217.0484924	0.05
221.2322998	0.15
223.0771790	0.06
243.0895081	1.33
246.2330322	0.08
251.0681152	0.04
253.1485596	0.05
255.6186829	0.08
263.1647339	0.06
265.0801086	0.05
267.0663452	0.05
268.1949158	0.04
269.9057617	0.02
278.9960327	0.19
281.0469055	0.27
296.9877319	0.18
298.9397583	0.26
302.8490601	0.04
307.1065369	0.08
322.9089355	0.39
324.8973694	0.13
329.5475464	0.05
339.7482910	0.19
341.1650391	100.00
343.1741333	0.04
359.2492065	0.33
369.2443542	0.52
395.0381775	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.221
Annotation	Unknow
Peak:m/z	Relative Intensity
192.0738525	0.67
203.9282227	1.02
206.0630798	0.14
222.1647644	0.24
223.9724731	0.31
228.1939545	0.88
240.0609436	0.63
246.0788269	0.08
252.2719879	0.82
257.0995483	0.21
258.8367615	0.43
270.2185669	0.65
285.0485840	0.59
288.1348267	6.33
306.1600342	6.97
324.1352844	100.00
353.0415039	0.27
459.5928955	0.38
465.3503418	0.28
482.2321777	0.52
499.8805542	0.33
518.2640991	4.27
532.5542603	0.23
590.9723511	0.21
602.0092163	0.36
662.4641113	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1007
Annotation	Tricetin 7,3'-diglucuronide
Peak:m/z	Relative Intensity
184.1060333	0.11
190.9978943	0.07
192.8213348	0.06
212.9373322	0.17
223.1943207	0.07
227.1049957	0.06
229.1356201	0.10
240.1976013	0.06
247.1985779	0.12
248.7188416	0.16
255.1010742	0.11
256.1565247	0.06
257.0133057	0.25
259.1188965	0.09
264.0222168	0.05
273.1939697	0.46
275.0127563	0.07
276.8152771	0.10
281.2045898	0.07
283.1770020	0.26
284.2243652	0.05
290.2738037	0.16
293.2478027	0.27
298.9456787	0.08
301.0913696	100.00
301.6953735	0.46
310.9913330	1.61
312.1220703	0.54
313.1060791	0.33
315.3720093	0.18
319.1457520	0.15
325.2044678	0.14
336.2068481	0.05
341.8897705	0.04
343.2101440	3.47
346.1729126	0.07
348.9971313	0.08
355.0973511	0.16
357.2261353	0.07
359.0900269	0.10
361.2113037	0.07
367.2484741	0.44
369.0664673	0.55
371.2080078	1.91
373.1716919	4.36
379.1647949	0.35
385.2231445	0.81
389.1132202	0.04
390.0473022	0.11
392.2869263	0.10
397.2334595	2.59
405.1185913	0.13
408.2010498	0.04
415.0919189	0.45
428.8547974	0.02
429.4869995	0.08
431.3806763	0.07
433.0647583	0.04
454.6752930	0.11
463.1260376	0.10
465.4496460	0.05
473.1595459	0.19
475.1530151	0.12
477.1478271	85.83
477.7542725	0.27
489.2879028	0.06
491.1962280	0.25
492.0920410	0.09
500.9464111	0.09
508.6361694	0.13
513.7182007	0.11
516.8897095	0.23
518.2001953	0.19
519.2244263	1.14
520.2791748	0.15
521.1692505	0.37
524.1304932	0.15
534.2364502	0.09
535.8836060	0.26
537.0537720	0.72
547.2595825	0.97
549.2290649	0.49
555.4754028	0.07
561.2334595	0.09
564.1959839	0.06
573.3639526	0.52
583.6959839	0.04
606.2349854	0.04
607.4574585	0.02
608.7156372	0.09
609.4198608	0.12
616.1701050	0.17
617.5104370	0.04
622.4662476	0.09
623.2911987	0.07
625.3745728	0.06
634.1776123	0.16
635.3129272	0.04
636.5432739	0.12
653.0585938	0.68
653.6931763	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1012
Annotation	Scopolin
Peak:m/z	Relative Intensity
102.9135132	0.01
107.0232086	0.04
108.9112854	0.01
110.7945251	0.02
116.8953857	0.67
129.0358276	0.02
132.9969635	0.01
134.9625702	0.63
135.8123474	0.02
144.9073944	3.98
147.1557922	0.04
148.0090179	0.02
156.8625488	0.01
157.9706421	0.03
160.0430908	0.21
160.9939575	0.05
162.9222717	100.00
164.0319214	0.07
165.1839752	0.01
165.9876709	0.02
171.1855774	0.04
172.7968903	0.04
174.7514648	0.02
180.9309387	0.18
186.0404663	0.05
189.0814667	0.01
192.0036163	3.00
193.0567169	0.61
196.2875061	0.03
203.2687836	0.02
204.0191650	0.02
217.0214233	0.01
223.3309631	0.03
225.2168274	0.03
227.9708557	0.02
230.1769714	0.01
233.2091675	0.02
233.9148254	0.02
235.0985107	0.02
236.3443298	0.01
237.9113770	0.03
247.2576904	0.01
251.2667542	0.03
252.0785217	0.03
253.1683350	0.01
259.0346680	0.02
260.9856567	0.01
262.0872498	0.01
263.2297974	0.04
265.3120728	0.02
267.1175842	0.05
270.1358643	0.02
271.2221680	0.01
274.0354309	0.02
276.5620117	0.02
280.1857910	0.02
281.0663452	0.03
283.0590820	0.19
286.2679443	0.02
293.0469666	0.03
305.9068909	0.01
308.6408997	0.06
309.3024902	0.18
313.9139099	0.14
322.2183228	0.05
322.9914551	0.13
324.0772400	0.04
325.8338318	0.01
327.0428467	0.09
332.8581848	0.04
336.1492920	0.07
337.1961670	1.14
338.1709595	0.04
339.0370178	0.01
345.8353271	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1292
Annotation	Cratoxyarborenone D
Peak:m/z	Relative Intensity
120.9539948	0.23
129.0385437	0.03
143.1595459	0.03
144.1192017	0.04
145.1141968	0.06
147.0296021	0.06
150.9851227	5.33
153.0490112	0.06
157.1539001	0.30
159.2526398	0.03
161.0371399	0.50
162.5097656	0.12
163.1469421	0.10
167.0945435	0.32
169.0525360	0.56
170.0355377	0.18
171.2407532	0.42
173.3415527	0.05
175.1903381	0.27
183.2163544	0.73
184.0191650	0.24
185.0470886	1.49
186.9555969	0.06
193.1958160	0.18
193.9417419	0.02
195.0022888	2.50
197.1239929	0.23
198.1691742	0.83
201.0591736	0.43
207.0783081	0.05
209.3764954	0.04
210.4031067	0.42
211.1382751	0.97
213.0701752	31.16
214.2070312	0.08
215.0625458	0.57
218.0572968	0.10
224.0568542	0.18
227.1864624	0.95
228.2941284	0.03
229.2823792	0.22
231.2004089	0.10
237.3185425	0.02
239.1406250	2.64
242.1641235	1.61
255.1408691	0.10
257.0683899	100.00
257.8443298	0.03
259.3889160	0.14
265.3545837	0.26
269.3615112	0.09
274.0946045	0.09
275.0921021	5.23
276.9659424	0.04
279.2609558	0.18
289.0001831	0.09
291.3255310	0.14
293.3729248	0.06
296.2362366	0.09
302.9853516	0.18
311.0315247	0.09
321.1728516	0.79
321.7985840	0.08
324.4574890	0.13
325.3508606	0.05
328.2866821	0.07
330.1542358	0.21
335.0663147	0.04
336.1853027	0.05
340.3796082	0.05
343.2752075	0.17
344.4062500	0.30
347.1785889	0.17
354.9776611	0.11
363.0740967	0.39
364.3516235	0.26
365.2252197	0.93
367.2724304	0.05
370.3945007	0.06
372.2196960	0.71
373.3848877	0.94
376.8419495	0.11
381.2845154	0.09
389.0180664	0.14
391.2409668	1.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	499.1248
Annotation	2',3'-di-O-Acetylfrangulin A
Peak:m/z	Relative Intensity
154.9156647	0.04
161.1526489	0.19
163.1087036	0.11
173.0386658	0.51
174.9872131	0.11
178.9555359	2.94
189.2163391	0.04
191.0952148	7.83
203.0375977	0.37
207.3445740	0.02
213.2275238	0.13
215.0785522	0.09
215.9778137	0.02
219.0181122	0.05
224.0732269	0.07
227.2918854	0.02
228.3512726	0.06
231.0979614	0.33
253.3254700	0.10
254.0668030	0.08
255.1137085	0.29
256.1460571	0.08
275.1924133	0.20
282.9201355	0.04
285.4551697	0.08
291.3125610	0.21
293.1422729	0.01
294.0554810	0.02
299.0678101	0.29
301.1183472	0.20
313.2297974	0.03
319.2258301	0.68
323.1360168	0.02
335.2273560	1.25
337.1391907	15.46
337.7562866	0.03
351.2728882	0.06
353.2162781	100.00
355.4090271	0.05
369.4968567	0.05
379.2299805	0.05
382.3071899	0.05
385.5781555	0.08
403.2904358	0.04
412.1014404	0.11
419.0622559	0.01
424.9299927	0.06
427.4657288	0.05
439.4393005	0.02
450.5507202	0.03
452.2403259	0.15
452.8881531	0.07
454.1295471	0.10
455.3268738	0.31
456.1673889	0.02
471.3900452	0.12
478.1629333	0.07
480.5937805	0.09
481.3566284	0.14
500.3202209	0.04
506.4801636	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	149.0092
Annotation	Tartaric acid
Peak:m/z	Relative Intensity
58.9224472	24.68
72.9821320	1.77
74.8561325	0.16
86.8407211	94.93
88.7668762	0.15
102.9202271	100.00
104.8819885	1.28
130.9006958	51.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.8
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9958954	0.02
158.9126740	0.02
173.2521362	0.01
218.9674225	2.50
250.8648987	0.02
273.2560730	0.01
298.0599060	0.01
302.8815308	100.00
344.4248962	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.0992
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
179.0342865	39.35
191.1892700	0.13
229.3913574	0.09
249.1460724	0.20
276.9446411	0.07
295.0795898	100.00
392.4586792	0.14
427.5820312	0.11
429.2643433	2.22
449.3763428	0.17
456.0175781	0.20
457.3140259	0.12
473.8710938	0.49
474.8975220	0.15
509.6028442	0.58
543.4620972	0.04
591.0137939	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0027
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9336548	0.26
131.1189270	0.23
169.0505829	0.08
172.8214417	1.20
184.8986816	0.11
191.0148010	100.00
198.9736176	0.34
212.9365845	1.43
233.0875854	0.06
241.3733826	0.09
254.9820557	0.13
266.0426941	0.29
270.1883545	0.03
272.1972351	0.09
273.0973206	0.94
278.8938293	0.12
285.0411377	0.17
299.0027466	1.32
302.7197266	0.10
306.3583374	0.16
313.0859985	0.36
315.2147217	0.08
316.9672241	3.65
319.2727966	0.07
330.9653320	0.13
335.1532288	0.11
340.9475098	0.30
346.8876343	0.11
348.9278564	0.11
359.1372375	0.50
375.1153259	0.07
376.2718506	0.10
377.1228333	0.08
384.7784424	1.05
385.4282532	0.29
403.0012207	5.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1411
Annotation	Myricetin 3-neohesperidoside
Peak:m/z	Relative Intensity
176.2698517	0.01
179.0127869	0.02
188.9932404	0.06
190.0444183	0.05
191.2527466	0.01
192.1130676	0.03
193.0798187	0.03
197.0792389	0.01
201.1145020	0.07
202.8730164	0.04
205.1060486	0.11
209.0831909	0.03
211.3258667	0.03
213.3920593	0.03
215.1768799	0.05
217.0756226	0.05
218.0972900	0.03
221.2287750	0.14
227.6870422	0.09
229.1276550	0.01
233.1002960	0.04
240.4052429	0.04
242.2600861	0.04
250.8367615	0.03
253.1610413	0.02
255.0037994	0.28
256.0748596	0.13
257.0261230	0.03
259.1652832	0.01
262.9281006	0.03
264.9093628	0.04
271.1199951	0.43
272.3143921	0.18
273.0934448	0.03
277.1971436	0.03
279.4133301	0.02
281.1779480	0.09
285.1880493	0.29
296.1794434	0.06
297.2268677	0.10
299.0681763	1.62
300.1200562	2.13
301.0675659	37.57
302.0873108	7.39
309.2094116	0.03
312.6191406	0.22
313.5427246	0.10
314.3025513	0.14
315.1683350	0.26
322.2153320	0.03
323.4747620	0.04
325.2016602	0.16
325.9553833	0.05
327.0364990	0.02
329.0610962	0.03
331.1162720	0.06
339.4168091	0.04
341.0342407	0.22
342.2281494	0.43
343.1913452	3.31
344.2148438	0.68
355.3445435	0.03
361.1808472	0.03
367.2063599	0.09
369.5999146	0.01
373.1336060	0.14
374.2946167	0.11
385.2277832	0.02
386.2546997	0.08
395.2125244	0.01
396.9818726	0.02
403.3191528	0.21
404.1696167	0.02
413.9926758	0.03
415.3953857	0.05
416.4700928	0.02
430.1574707	0.06
435.2369385	0.08
444.2655029	0.02
445.3077393	0.39
446.0725098	0.01
450.2209473	0.10
459.3649292	0.06
462.2142334	23.57
463.1945801	100.00
464.2082520	20.18
464.8336182	0.02
467.3646851	0.04
475.6477661	0.09
476.2854614	0.13
477.0918579	0.08
486.1657715	0.01
487.3953247	0.13
490.2828979	0.13
491.3414917	0.04
492.5343018	0.03
494.4688110	0.04
505.2522583	4.46
506.2765503	0.76
509.6135254	0.07
511.2639771	0.03
527.3389282	0.02
529.2202759	0.06
535.3198853	0.17
539.4060669	0.05
545.1928711	0.02
547.4635620	0.07
562.4864502	0.02
563.2235718	0.02
565.6102905	0.05
579.0062866	0.04
580.2183838	0.01
581.4036255	0.04
591.4746704	0.04
607.2426147	0.34
608.1155396	0.24
608.8624268	0.06
626.3474731	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.0592
Annotation	alpha-D-Galactosyl-(1,1')-sn-glycerol 3-phosphate
Peak:m/z	Relative Intensity
96.9263992	0.92
150.8973541	0.84
152.9901428	96.89
153.8526459	0.06
171.0406952	3.29
222.9806213	0.48
241.0279846	100.00
259.0734558	0.63
315.0000610	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1035
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
108.9144669	0.29
112.9161987	0.02
119.0159378	0.90
121.0238800	0.07
135.0427246	0.82
135.9962463	0.28
137.0357666	6.95
150.8775330	0.09
161.9231567	0.21
163.1237183	0.06
170.1367645	0.09
177.3775787	0.17
178.3386841	0.09
178.9659424	1.20
179.9901886	3.03
180.9887543	100.00
218.8368225	0.05
223.2519836	0.05
226.2509155	0.12
233.9743042	0.48
234.8890076	0.03
238.9534607	0.03
253.2825623	0.03
269.9292908	0.08
293.8739014	0.16
297.0532532	0.18
298.2406311	0.41
299.1040039	0.27
308.3522949	0.25
309.1758728	0.10
313.3568726	0.03
324.9209900	0.05
328.1491089	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.3095
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
140.7917938	0.67
141.9954071	0.41
143.0856171	0.42
145.0048523	3.93
147.0570068	2.66
149.1002197	1.79
150.9676819	0.22
152.3188477	0.34
152.9729919	0.59
154.9159698	1.63
156.2631836	0.38
157.0804901	3.19
159.0626068	6.53
161.1094666	3.80
162.9780731	2.70
164.0494995	0.08
165.1853638	0.66
166.7190552	0.83
167.3582458	0.06
168.0855255	0.94
169.0332947	1.82
170.9687805	4.56
173.0444946	9.62
175.0503235	5.14
177.2346039	1.12
178.2516632	0.23
179.1341858	1.07
180.5510254	0.08
181.2102203	1.77
182.9637451	6.67
183.5722961	0.24
185.1140442	5.13
187.1294556	4.43
187.9268494	0.12
189.1640625	2.71
191.1405945	1.30
193.0555115	1.06
194.9499664	1.80
197.2136536	2.87
198.0345154	0.07
199.1112366	4.88
201.0487366	2.52
203.0885315	0.40
205.1233215	0.95
207.0381470	0.67
209.0589905	1.90
211.1513367	4.76
213.2471619	3.89
215.1589966	1.98
217.0900421	1.38
219.1205444	0.94
221.1447449	1.72
222.0125427	0.59
223.2159729	3.28
225.0877380	3.15
227.1797180	2.50
229.1374512	1.49
231.2010956	0.93
232.5550842	0.49
233.2145386	2.45
235.3298798	2.01
237.2249756	2.16
239.2178955	2.11
241.2702942	4.11
243.2776184	9.62
245.0780792	2.19
247.0959167	1.15
249.0981140	0.91
251.2506256	2.05
253.2188721	3.31
255.2637329	2.76
256.7362976	0.67
257.3644714	0.76
259.2091980	4.81
261.2710876	21.61
262.3795776	0.09
263.1543579	1.54
264.3702698	0.32
265.1249084	2.12
267.3074646	1.43
269.1587219	1.77
271.1515808	3.41
273.1933899	1.26
275.1994934	1.47
277.2448730	4.92
279.1441650	2.36
281.3099365	1.76
283.2626648	1.62
285.3134155	3.54
287.1932983	1.95
289.2255249	2.86
291.2933044	1.72
293.3357239	0.89
295.2840271	1.87
297.2583618	3.11
299.2828979	1.44
301.2177124	3.21
303.2619934	6.25
305.1714478	3.01
307.2561340	0.16
309.2848816	2.97
311.1761780	0.46
313.2541199	2.14
314.0944214	0.20
315.3536377	6.01
317.2244873	4.73
317.8352966	0.05
319.3241882	1.38
321.2356873	1.09
323.3409729	3.56
325.2739258	0.76
327.3072510	6.06
329.3509521	1.11
331.3303833	1.50
333.2289429	6.61
333.8676453	0.08
335.2574158	100.00
337.3166199	0.91
339.2681885	1.56
340.3806152	0.88
341.3933105	4.34
343.3042603	0.99
345.3400574	4.12
347.4650269	0.59
349.2498169	1.32
351.3249512	14.03
353.3624268	2.48
355.2436523	0.26
357.4439087	0.50
359.3475952	1.11
361.3268433	1.77
363.3530884	3.96
365.4361572	2.80
367.3124390	0.35
368.2811890	0.05
369.3854980	15.04
371.3217163	0.91
373.1063232	0.39
374.0009155	0.07
375.4486084	2.47
377.3463745	6.20
379.4498596	0.78
381.4055176	0.49
383.2994080	0.45
385.3823242	0.23
387.4075623	10.10
388.3170776	0.40
389.3135986	1.09
391.2546692	0.86
391.8601074	0.43
393.4534302	1.50
395.4646606	0.16
397.4470215	0.96
399.3233948	0.55
401.2877502	2.15
403.4207458	0.99
405.3804016	4.40
407.2751770	0.96
411.0123596	0.10
413.3439026	0.51
415.3652649	0.72
417.4709778	0.32
419.4319763	3.15
423.4269104	1.62
425.4945068	4.32
431.5195923	2.90
433.4602356	0.07
437.2591248	0.37
441.3132629	0.31
443.4461975	21.83
451.3724365	0.70
461.3662109	17.02
479.3216858	26.09
480.2169800	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.76
Annotation	Unknow
Peak:m/z	Relative Intensity
184.9012604	0.01
212.8136902	3.71
214.7249908	0.02
223.1229248	0.06
261.0919800	0.02
290.1053772	0.09
293.8614502	0.03
296.7561646	100.00
308.0069885	0.02
334.1508789	0.06
334.8807678	0.20
352.3260193	0.03
362.1377869	3.28
363.1817627	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.1198
Annotation	Unknow
Peak:m/z	Relative Intensity
271.1881104	0.05
300.0021057	0.06
301.2371826	0.70
343.4270020	0.05
369.4422607	0.03
397.5732422	0.06
463.2646484	0.59
477.3225098	0.07
505.2188110	57.80
505.8520508	0.21
516.8388062	0.09
531.1950073	0.39
533.5094604	0.05
547.2941895	1.55
548.9260864	0.14
559.4580688	0.11
573.2634277	0.23
575.3079224	0.98
577.3113403	2.23
589.3899536	0.45
591.4666138	0.15
601.3297729	1.67
619.2144775	0.77
638.0955200	0.10
639.3253784	1.77
645.3545532	0.03
663.1303711	0.44
681.2608032	86.62
707.1960449	1.60
725.1027222	100.00
725.7626343	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	759.1417
Annotation	Unknow
Peak:m/z	Relative Intensity
237.2939758	0.17
255.3051300	0.28
256.1084290	0.15
269.0477600	0.04
295.1875305	1.51
297.1575317	0.12
301.1126709	13.40
340.4484253	0.19
342.9570312	0.06
349.2587891	0.17
378.9520264	0.17
386.2239990	0.11
461.4599609	0.23
463.2170410	91.33
472.0988770	0.04
506.4353638	0.14
509.4616699	0.09
523.4384766	0.05
530.3792725	0.20
533.5815430	0.10
534.2925415	0.09
551.0903931	0.09
579.2207031	0.14
596.4671021	0.26
629.3334351	0.18
641.1015015	0.13
642.5856934	0.15
643.2163696	0.12
644.2981567	0.08
653.1916504	0.07
663.4498901	0.15
699.1205444	0.16
713.5585327	0.20
722.1077271	0.05
740.7981567	0.48
758.9143677	100.00
759.7022095	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	344.1332
Annotation	N-(1-Deoxy-1-fructosyl)tyrosine
Peak:m/z	Relative Intensity
116.0143967	0.46
118.9171753	1.41
119.6840820	0.05
120.8985443	0.20
123.0215607	0.55
129.8889465	0.17
135.0917358	0.06
135.7945557	0.16
141.8458710	0.09
142.7145081	0.05
143.9125366	0.26
145.0227203	0.24
146.9018860	72.46
147.8964539	0.24
154.2803040	0.03
155.0358124	0.07
162.1756134	0.43
163.0943146	0.42
165.0147095	100.00
172.2684937	0.03
174.2077332	0.05
180.0149078	8.87
181.9288940	9.16
183.7704468	0.19
189.0015869	0.13
196.9602356	0.10
198.1820679	0.15
199.9285889	0.05
202.2681732	0.39
204.8579407	0.04
210.9989319	0.09
214.1017761	0.09
218.2459106	0.13
220.1428223	0.11
228.9778442	0.17
230.1464539	0.21
235.9410400	0.17
239.0784912	0.12
241.3595886	0.27
245.1042786	0.21
250.2279358	0.13
251.0343628	0.07
254.2721558	0.12
255.8600159	0.09
261.1960449	0.15
267.6999512	0.06
269.5221252	0.08
273.3235474	0.06
277.9481812	0.03
280.4238281	0.04
281.2923584	0.64
283.2695618	0.06
284.3081970	0.27
294.1148987	0.08
296.2659607	0.19
298.2589111	1.13
298.9905090	0.14
300.5581970	0.25
303.0673828	0.41
304.0928955	0.28
308.3326416	2.92
308.9615784	9.86
309.6385498	0.18
313.3411865	0.05
314.0656433	0.13
315.4454956	0.20
321.1752930	0.21
324.2266846	0.06
326.1828308	2.07
327.2563171	10.56
330.3580627	0.30
335.0442200	1.14
335.6900024	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3403
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1041870	0.03
246.0292969	0.02
250.1092072	0.10
253.4081268	0.07
273.1659241	0.01
282.9616089	0.02
283.9844360	0.03
285.2081299	0.26
289.2335205	0.07
294.1387939	0.03
295.1341553	0.03
296.4698792	0.12
297.2155151	0.04
299.1018982	0.35
309.0567017	0.06
311.1702881	0.18
312.1828003	0.11
317.3200989	0.05
319.2526550	0.01
323.3390808	0.19
325.0768738	0.32
327.1749268	0.03
337.2434082	0.42
338.4718018	0.08
339.2230835	0.13
341.3304443	0.24
355.4228516	0.01
357.1524658	0.17
359.4399109	0.14
367.0217896	0.11
370.3729248	0.17
371.3312378	0.10
373.1901855	0.11
385.0385742	0.05
395.0496826	0.03
399.3573608	0.50
412.3562012	0.03
415.2423096	0.04
416.0600586	0.04
420.5483398	0.02
424.4784546	0.12
428.2894897	0.02
430.3832397	0.60
431.5132446	0.02
432.2415161	0.17
436.3654175	0.06
443.1852417	0.02
444.2758179	0.04
446.1896973	0.08
448.2720337	1.95
449.3526611	0.90
450.2374268	0.46
460.3297729	1.82
461.3742065	0.67
462.1197510	0.06
472.3916626	0.06
474.3637695	0.07
476.4839478	0.96
477.4100342	0.67
478.4456177	0.66
480.0478516	0.11
480.6564331	0.04
487.4490356	0.29
488.4852295	0.06
490.3616943	3.28
491.3219604	0.05
492.2918701	1.12
501.3029785	0.03
504.4291382	0.01
505.4871826	0.16
506.3359985	0.31
508.2817383	0.04
510.6011353	0.10
522.2903442	1.52
523.1768188	0.06
534.7584229	0.12
549.3966675	0.01
567.4402466	0.03
569.6026611	0.16
570.8002930	0.04
574.2429810	0.06
577.3151855	0.06
578.4204102	0.07
584.2817993	0.03
585.2852783	0.19
586.4132690	0.06
587.4649048	0.07
590.5970459	0.04
592.1484985	0.07
595.4282837	2.37
597.5696411	0.03
604.0957642	0.04
608.3958130	0.21
610.3583984	0.13
611.5670776	0.27
613.3272095	45.56
614.0173950	0.20
616.5005493	0.20
630.9141846	0.10
634.3384399	0.24
635.7239380	0.04
636.3894653	0.09
638.4042358	0.03
639.7587280	0.17
645.3928223	12.63
649.4766235	0.03
652.3147583	6.73
653.6088257	0.48
654.5130615	0.16
655.7467651	0.12
656.4119263	0.01
659.6741333	0.03
667.4112549	0.02
673.0820923	0.01
678.7721558	0.02
684.3104858	5.95
685.3162842	0.59
686.4069214	0.06
695.2411499	0.03
697.3463745	0.05
711.4204712	0.07
721.1915283	0.04
731.5183716	0.78
739.3873901	1.24
747.7236938	0.08
757.5527954	2.36
771.1196899	0.01
775.3812866	100.00
776.0916138	0.20
788.8182373	0.14
789.8723755	0.07
807.3662720	24.76
808.1055908	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1349
Annotation	Spicatolide G
Peak:m/z	Relative Intensity
118.7923355	0.04
134.9642334	0.11
145.0488281	0.05
148.9665070	0.04
162.9439545	0.17
164.0388031	32.76
167.1108704	0.04
178.9946594	100.00
185.0879517	0.05
193.0460205	0.08
203.0411377	0.05
208.7345734	0.08
221.2937927	0.25
222.9226532	0.06
245.1962891	0.11
250.7777100	0.06
253.1709595	0.29
269.1083679	0.03
273.1179199	0.03
281.3392944	0.06
285.3471985	0.10
287.0755005	0.18
293.1433716	0.26
296.9754944	0.51
301.5476074	0.04
303.4937439	0.07
322.3313904	0.07
323.1490784	0.36
325.2253723	0.07
335.8566284	0.16
337.2974243	0.67
338.3447571	0.11
339.4368286	0.03
341.1730652	0.94
347.2497559	0.20
353.3327637	0.10
363.1504517	0.18
365.3381653	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	805.3248
Annotation	Phyllanthoside
Peak:m/z	Relative Intensity
235.1788483	0.33
249.3447113	0.12
263.0949707	0.20
269.1824646	0.39
293.3398438	0.17
323.1643677	0.16
337.0037842	2.75
352.9890747	0.09
357.2438354	1.63
368.3145752	0.29
369.3543701	0.73
435.2539673	0.15
448.4234619	0.11
461.2864990	0.64
462.5696411	0.34
464.3159790	0.20
472.6806641	0.40
478.3349609	2.07
490.2519531	5.83
494.3333740	0.18
502.3858032	0.92
504.5914307	0.14
508.2254028	0.22
520.1200562	1.90
522.3294678	100.00
523.0143433	0.48
530.3023682	0.33
553.9622192	0.09
559.6022339	0.20
564.4710083	0.19
580.5062866	0.15
585.5167236	0.25
593.5256958	0.81
595.3740845	0.37
598.5443115	0.55
601.3876343	0.42
602.1322021	0.06
609.3076172	0.11
611.3247681	5.90
614.3478394	0.83
625.4146729	2.25
626.3942261	0.24
635.0108032	0.10
643.3177490	34.84
650.2872925	0.77
651.1060181	0.37
652.5416870	8.72
653.5300903	0.27
666.4676514	0.21
670.3868408	0.45
673.4474487	0.41
675.4626465	0.54
682.2656860	0.37
684.3388672	70.46
701.5624390	0.76
737.4244995	3.81
751.4592896	0.12
755.1831665	2.80
773.3973999	24.37
787.3950195	0.09
805.4283447	22.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0879
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
106.7165146	0.01
112.7687683	0.04
117.0186462	0.02
121.0426407	0.05
134.9398804	10.27
137.1593323	0.02
147.1239929	0.02
149.1065674	0.03
150.8159790	0.10
160.1679688	0.03
161.0221252	0.07
164.9331360	0.08
167.0794067	0.04
168.8847046	0.07
175.0270996	0.04
178.9572906	100.00
181.0329285	0.03
189.3264771	0.06
191.1521759	0.02
192.8562469	0.06
203.0709686	0.14
205.2482452	0.06
207.1052094	0.06
209.0045776	0.09
210.8778381	0.09
220.9737549	0.28
223.1161194	0.02
225.9911194	0.02
233.0907593	0.85
251.1489868	0.61
251.9071350	0.12
265.0633545	0.03
269.1118469	0.12
277.3635254	0.02
281.1115417	0.18
283.3153687	0.01
293.1869812	0.20
295.1298828	0.11
296.5112915	0.07
297.1218262	0.04
299.3879395	0.04
305.0212097	0.01
310.2365723	0.03
311.3214111	0.06
313.6567993	0.02
319.2044067	0.07
323.2704773	0.11
328.9711914	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.9611
Annotation	Unknow
Peak:m/z	Relative Intensity
118.0345230	0.01
188.0234375	0.29
197.8801880	0.04
205.8147888	0.22
214.2011414	0.01
223.7550049	0.02
226.0060730	0.01
232.0125122	1.20
256.0966187	0.01
258.6658325	0.10
259.8425903	0.92
276.3016968	0.02
277.9435425	100.00
285.1328430	0.03
304.0169067	0.07
317.5302124	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.166
Annotation	Corchoionoside B
Peak:m/z	Relative Intensity
140.8538818	8.52
141.9563904	0.72
184.9250183	100.00
185.9461670	7.52
201.1558228	0.15
203.0033264	1.39
209.1431274	0.04
213.2012634	1.94
214.2949219	0.12
216.8173676	0.08
239.4971313	0.25
243.8417053	0.16
258.0883179	0.13
293.0815125	0.06
295.2739258	0.15
319.2764282	0.04
325.4741516	0.18
327.3120728	0.56
337.5658264	0.08
340.4816895	0.06
341.2283936	0.12
353.1678467	0.26
354.1081238	0.10
355.2531738	0.44
356.2733765	0.41
357.3695984	0.52
358.7259827	0.12
362.0655212	0.11
363.9877625	2.62
369.3373413	0.11
372.3888245	0.09
381.2403870	0.62
382.3470154	0.59
391.1891174	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1828
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0612640	0.84
191.3819580	0.07
209.0495758	100.00
252.9982605	0.07
324.3893433	0.10
325.2963867	0.04
338.2512207	0.05
340.0822754	0.06
358.5635376	0.09
397.1700439	0.03
407.1112671	0.33
413.1901245	0.25
445.0665283	0.18
475.1356812	0.05
478.8602905	0.06
488.1413574	0.06
504.9535522	0.08
508.8574829	0.38
520.4039917	0.11
531.2389526	0.11
532.0974731	0.11
533.0132446	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	635.4025
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9744415	0.71
187.2328186	0.52
195.0608063	0.31
197.1647339	0.13
211.1064911	5.09
212.1347046	0.30
218.1257782	0.50
220.8897705	0.41
227.1066742	0.08
235.1793976	0.07
241.8818054	0.23
260.4069214	0.24
267.6775818	0.92
269.3790283	0.10
270.2837219	0.10
282.1078491	0.44
294.4215088	0.91
295.9315796	0.83
297.3602600	0.27
308.0160522	0.24
312.5562134	0.14
316.8203735	1.44
319.0233154	0.07
322.5300293	0.19
323.2296143	0.27
339.5422363	0.74
344.4616089	0.09
351.3554077	1.27
352.4412231	1.32
354.4790649	0.26
357.3329468	0.49
359.4431763	0.07
364.6167603	0.32
365.2810059	5.05
366.1213989	0.84
367.6498413	0.48
369.4363403	0.22
370.0925903	0.08
371.2883301	0.48
375.0134888	0.09
376.3953857	3.37
377.3264160	0.34
378.0763550	0.10
379.9805908	0.33
383.5588989	0.56
388.1073608	0.23
392.9070435	0.59
393.5290527	0.22
398.8004761	1.21
400.8584595	0.42
401.9147339	0.10
402.6911621	0.11
407.3881226	1.17
408.5578003	0.76
411.2495117	0.50
413.3687134	1.29
414.0905762	0.11
416.6404419	2.30
421.3476562	0.51
422.7311401	2.20
423.7610474	1.21
425.0402222	85.53
425.9866943	3.04
427.2079468	1.21
428.4187622	0.08
430.2836914	0.62
432.0178223	29.77
433.1905518	2.35
436.4271240	1.04
437.3064575	0.20
439.2827759	0.23
450.5249634	0.63
451.4662476	0.55
452.1507568	0.24
454.7511597	0.38
455.5580444	0.19
456.4751587	1.18
461.1719971	0.43
461.9470215	0.33
463.6907349	2.45
464.4276123	1.46
465.2160034	0.86
465.9075317	0.54
470.4786987	0.60
471.6082764	0.67
472.3120117	3.51
472.9993896	0.71
478.3634644	0.10
479.4376831	0.29
480.4416504	1.02
481.4577026	1.51
482.2015381	0.28
486.3654785	0.55
488.4429932	2.82
489.7004395	0.67
490.4374390	0.09
491.7905273	0.23
493.3612671	0.60
497.2954712	0.55
498.3151245	0.89
498.9251709	0.39
500.4998169	0.72
502.9682617	0.10
505.0108643	0.21
505.8594971	0.10
507.7167969	0.27
508.5995483	1.81
509.5460815	0.23
512.2559204	0.80
513.0634155	4.50
513.8676147	0.73
515.0878906	1.70
518.4887085	0.29
519.8727417	5.34
520.5739746	2.85
521.2274170	1.78
522.0475464	14.23
522.8720093	4.58
526.0935669	1.22
529.0932617	44.89
530.0405884	5.65
530.7639771	0.23
531.4091187	0.10
532.5946655	0.35
535.5702515	0.65
540.3050537	0.32
541.1856079	0.22
542.0347900	0.65
543.4067993	0.13
545.0524292	0.39
549.4329224	0.48
550.3956299	0.20
554.3284912	0.75
555.2800903	0.54
556.5997925	0.47
557.3469849	0.42
561.2025757	0.17
561.8664551	0.69
563.3754883	0.76
564.6147461	0.85
565.7696533	4.59
566.6771240	1.62
568.4166870	3.40
569.0455933	1.93
570.3059692	1.91
571.0938110	1.45
572.1841431	0.09
573.3214722	0.63
574.9541626	0.27
577.7081909	8.29
578.5798950	1.06
583.1710205	0.68
590.2804565	0.66
591.4136963	3.54
592.1546021	0.42
594.3140869	0.13
595.5050049	0.58
596.4882202	0.95
597.8417969	19.40
598.5451660	6.37
599.3644409	0.31
600.6361694	0.70
601.2479248	0.34
604.6253052	0.61
606.2759399	0.19
610.9398193	0.12
614.8652344	0.17
616.5894165	1.23
617.4578247	0.88
618.4625854	1.09
619.4780273	0.88
621.3869019	0.83
622.5245972	0.33
626.8333740	0.36
630.3002319	0.46
636.6564331	0.27
646.2468872	0.24
650.5259399	0.55
653.5787964	0.11
654.7354126	0.15
655.6677856	1.06
661.7620239	0.13
668.4225464	0.40
678.9527588	0.72
683.5548706	1.37
686.1951294	0.84
687.6776733	0.68
698.6043091	1.18
701.5535278	0.25
708.2525024	0.15
715.7054443	0.44
717.5851440	0.73
718.4481812	0.23
720.9991455	0.19
729.5165405	1.60
733.7687988	0.56
734.7837524	0.61
739.6719360	1.68
742.9542847	1.02
743.8578491	1.38
745.4998169	0.30
746.7274170	0.51
749.4259033	0.16
751.4594116	9.77
752.4026489	2.58
753.6731567	0.77
756.3796387	0.15
760.1675415	1.09
763.3545532	0.28
764.5430298	0.18
765.6597900	1.45
766.5156250	0.72
777.6835938	0.33
781.4827271	0.96
784.6671753	0.26
788.3131104	2.05
789.0526123	0.51
789.9136963	0.29
796.4299927	0.35
799.6334839	0.72
800.6766357	0.16
802.7559204	0.10
803.7968140	0.08
814.7147827	0.13
815.4808960	0.81
818.0794067	1.07
819.0720825	0.67
828.6926880	1.54
829.6975708	0.68
831.5258789	0.14
832.6860352	1.52
833.5532227	1.31
838.9611206	0.36
839.7564087	0.24
842.7606812	0.63
843.8059082	0.37
845.7103882	0.24
846.9673462	8.92
847.9191895	100.00
848.7106934	50.64
849.6035767	14.91
850.7821655	2.76
853.2395630	0.29
857.7109985	0.11
860.9011841	0.18
862.6484985	8.18
863.8986206	3.18
864.6213379	0.59
873.7440796	0.09
886.3632812	14.60
887.2178345	2.43
888.8073730	0.12
889.9877319	0.33
890.8436890	0.40
892.2644653	0.49
893.2556152	2.45
893.9354858	1.07
897.3018188	0.55
901.8054810	0.15
911.4855347	0.31
913.9739380	0.51
925.9729004	0.46
928.5476685	0.13
929.5961914	2.04
931.0520630	0.09
931.8090820	0.11
933.1726074	0.08
940.0858765	0.13
943.7230835	0.91
944.7185669	1.97
945.7189941	0.58
961.2168579	0.38
962.1305542	0.32
975.6765137	0.23
1021.7160030	0.13
1025.7447510	1.09
1028.4038090	0.27
1040.1848140	0.68
1042.8248290	11.92
1043.6540530	6.25
1044.8771970	2.48
1056.7963870	21.51
1057.7805180	14.45
1058.6984860	2.71
1062.7045900	0.08
1084.5694580	0.93
1138.9501950	0.36
1269.0816650	0.58
1282.2163090	0.18
1283.1960450	0.29
1355.8023680	0.24
1357.0759280	0.14
1563.1815190	0.20
1577.3400880	0.33
1673.1848140	0.08
1808.5701900	0.29
1899.6033940	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
125.2204285	0.06
134.6945953	0.04
136.9718323	0.04
142.9818115	0.10
159.0956421	0.03
160.9963989	0.70
162.1801605	0.03
167.7150574	0.02
179.1038513	0.35
189.2332153	0.01
191.1584930	0.13
217.2672729	0.02
220.0782013	0.02
225.0379791	0.17
226.0034180	0.01
231.0745239	0.02
243.9051208	0.06
251.3647461	0.03
253.2441711	1.00
254.1626892	0.04
270.3157654	0.01
271.3308411	0.03
277.0157471	0.03
289.1922607	0.02
295.0739441	0.02
319.2903442	0.04
322.1997681	0.02
335.1337891	0.04
343.3583374	0.04
345.5513916	0.02
347.2444153	0.01
352.3194580	0.03
353.3310242	0.48
356.4642944	0.01
369.2369385	0.08
373.3293762	0.04
374.5014343	0.01
383.8070068	0.03
387.2470703	100.00
388.3274231	0.88
389.2794800	0.01
391.5191956	0.03
396.5484619	0.04
398.2276306	0.05
412.3446350	0.02
415.5013733	0.04
416.2806702	0.02
425.1051331	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3308
Annotation	Unknow
Peak:m/z	Relative Intensity
224.1416168	0.05
261.2387085	0.09
279.2496948	4.83
281.3681335	0.56
282.3385010	0.17
298.9935913	0.07
415.3829346	0.03
438.2765503	0.15
501.7372437	0.20
502.6395874	0.10
504.3750000	100.00
505.5144653	0.30
517.3323364	0.10
528.3416138	0.16
532.1682129	0.04
545.3374634	0.19
546.4960327	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.0936
Annotation	5,4'-Dihydroxy-3,3'-dimethoxy-6,7-methylenedioxyflavone 4'-glucuronide
Peak:m/z	Relative Intensity
172.6877747	0.03
173.3570557	0.01
191.1448059	0.01
210.9305420	0.01
271.3968506	0.01
285.1292114	0.28
292.9684448	0.01
297.1488647	0.02
311.4293213	0.04
328.1222534	0.01
329.5609131	0.02
331.4050293	0.02
339.5750732	0.06
352.3265381	0.01
353.3698120	0.02
355.2414551	0.03
356.9499512	0.03
369.0591431	0.02
371.0775757	0.02
436.8635864	0.05
443.2799683	0.01
447.2734375	1.37
451.6982422	0.05
454.2724609	0.01
473.3792725	0.11
487.0779419	0.06
489.1961060	100.00
489.8493652	0.21
491.4210815	0.13
496.4957886	0.06
501.2459106	0.04
505.1360474	0.04
515.1338501	0.06
515.8087769	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.9662
Annotation	Unknow
Peak:m/z	Relative Intensity
109.9154739	0.04
115.9311523	0.04
128.8851471	0.06
144.0462494	0.12
145.8556519	0.03
148.0956726	0.06
156.0557556	0.03
162.0508728	0.16
173.2218628	0.07
178.0221405	0.03
179.0220184	0.44
184.0695801	0.05
201.9797668	0.31
205.0700378	0.04
217.0073853	0.07
217.9415741	0.06
219.2110901	0.03
219.8952637	0.08
226.8475952	0.03
228.1134949	0.05
230.1933899	0.04
231.0638733	0.02
233.1174927	0.33
234.1344299	0.01
240.2579041	0.03
244.9943848	0.16
246.0671997	0.12
247.0952454	0.10
248.0609131	0.14
250.2950134	0.18
251.1049500	0.75
255.4573364	0.04
257.1146545	0.03
259.0006409	0.02
260.1689148	0.02
264.0952454	0.20
272.0027466	0.02
272.9787903	0.02
275.6874390	0.18
277.2269897	0.02
281.0782471	0.02
282.4419861	0.06
286.0422974	0.08
287.1258850	0.02
289.9958801	1.88
291.0533142	0.03
292.3022461	0.03
292.9946289	0.01
304.7626038	0.14
307.1859131	0.07
308.2401733	0.23
312.1369324	0.02
315.8916321	0.03
317.6307983	0.73
318.3191528	0.31
320.3957214	0.05
323.6468506	0.07
329.4985046	0.10
334.1065674	0.35
336.0490112	100.00
341.7784424	0.15
343.1370850	0.18
344.0793762	0.06
347.0384216	0.18
359.4646301	0.09
361.0760803	1.11
362.1958008	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	660.1674
Annotation	Unknow
Peak:m/z	Relative Intensity
188.8848114	0.77
190.0661469	0.51
191.0987396	0.25
192.9996033	1.27
194.0405426	2.29
195.0614777	0.82
196.6832275	0.23
199.0711060	1.87
201.0979614	0.31
205.9505463	0.31
207.0555115	10.11
208.0552673	4.64
209.0325623	0.75
211.0984802	2.70
216.8954010	0.17
218.1143188	0.94
219.0448151	2.86
220.1567993	0.09
224.9595032	0.11
228.2657928	0.17
230.9909515	0.10
234.0552063	0.08
235.1021881	0.38
236.0867615	11.46
236.9622498	0.86
238.0486450	0.03
238.9209290	0.28
245.2606812	0.13
247.2518768	0.09
250.6941681	0.12
253.9162292	0.13
256.0922241	0.78
257.1518860	0.50
261.3677368	0.12
263.9672852	100.00
265.2349854	0.13
274.1054993	5.05
274.9114380	0.47
289.0871277	0.18
292.0030518	0.28
293.3280029	0.13
296.1461792	0.18
297.1803894	7.17
302.2610474	0.32
303.2378845	0.22
319.2445984	0.14
320.1165161	0.40
321.0957336	8.67
322.1290894	3.66
325.1893921	0.09
336.3888550	0.31
337.0661011	0.26
337.9757385	0.10
338.9568481	8.87
340.0339050	0.35
341.2376099	0.44
344.2985840	0.05
347.0266113	5.16
348.1208496	1.77
349.2727661	0.28
357.3259277	0.60
365.1469116	5.91
369.3851929	0.24
373.4150391	0.12
375.2207642	0.80
381.2651367	0.11
387.2120972	0.23
391.2904053	0.20
393.0668335	33.97
393.6798706	0.15
396.1607056	0.20
399.4205322	0.14
404.9509277	2.91
410.8076782	0.66
411.5487061	0.04
414.1289062	0.38
415.4469604	0.09
423.0930786	3.06
426.3489380	0.06
428.1233521	2.80
432.0046997	0.12
439.1137695	0.26
440.1157837	0.29
450.2008057	1.72
451.1791992	1.89
452.2283325	0.12
468.2317505	19.88
479.1467285	0.05
480.3113403	0.16
483.8815308	0.03
485.1697998	0.22
486.3200073	0.10
496.4616699	0.30
503.4641113	0.12
513.1246338	4.26
514.0658569	0.16
521.8757935	0.04
527.3648682	0.21
531.2203979	37.14
532.2797241	0.11
539.2875366	0.43
544.3830566	0.04
554.6533813	0.37
567.1622925	1.65
567.7816162	0.38
569.7651978	0.08
575.5713501	0.57
579.1992798	0.85
581.6557007	0.15
583.3829956	0.07
585.2709351	55.31
588.2606201	0.16
593.8654175	0.38
597.0366821	0.59
613.4080811	0.12
614.2156372	0.51
624.3194580	0.23
626.7762451	0.55
641.4600220	0.43
642.2498169	6.73
643.3403320	3.54
646.0695801	0.58
655.1779175	0.18
665.5418091	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8373413	0.28
206.8953857	3.68
212.8338165	1.14
254.9348145	0.85
266.9478760	0.17
284.7592163	0.25
286.8692932	0.35
290.7590027	100.00
297.0274048	0.19
314.9078369	0.87
357.1734314	0.39
END