#DEFINITION	Reference Metabolome for Eriobotrya japonica
#IDENTTFIER	RefMeta-Eriobotrya japonica.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Eriobotrya japonica
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Eriobotrya japonica was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1715
Annotation	Secologanin dimethyl acetal
Peak:m/z	Relative Intensity
129.1224670	0.05
131.2008667	0.07
132.9146729	0.10
139.1280975	0.51
143.3903809	0.16
147.3546753	0.14
151.0371857	0.08
157.0645142	0.50
158.8199921	0.06
160.8053894	0.26
165.0416718	0.32
167.1943512	0.09
169.0727081	0.06
175.1308136	1.87
179.0486145	0.26
180.8353271	0.16
183.0559998	21.29
188.2069550	0.05
189.0238342	0.65
205.2961426	0.48
223.0684204	0.55
231.1575317	10.76
241.0751038	0.09
249.0682068	100.00
253.0326233	0.25
257.3704529	0.20
261.1021729	0.18
267.1368103	7.90
271.2516479	3.21
273.1485901	0.36
277.0752563	0.13
279.2263184	0.09
281.4363708	0.08
283.3141479	0.08
302.2321167	0.32
309.1749878	0.17
313.2084351	2.16
322.9614868	0.11
325.2910156	0.11
327.2025757	0.14
328.8533630	0.10
336.9733276	0.07
343.1162415	0.42
344.4038086	0.34
346.7808228	0.25
355.0679626	0.13
356.7421570	0.24
357.3623657	0.21
358.6358032	0.09
359.2561646	0.21
363.2302856	0.14
365.4956055	0.46
368.4381409	0.08
373.2274475	3.81
383.2524414	0.10
387.0912476	0.53
388.3732300	0.39
389.2825623	2.90
397.2786560	1.97
401.3704834	0.15
405.5809631	0.10
412.5641785	0.06
413.1793518	0.13
414.2628479	0.07
415.3417053	23.60
416.9945984	0.04
418.2404480	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	837.3273
Annotation	Unknow
Peak:m/z	Relative Intensity
233.9490051	0.13
277.1348877	0.15
292.2044678	0.15
307.1649780	0.42
321.0447998	0.12
323.2086182	0.09
337.3496094	0.34
368.2233276	0.11
369.6302490	0.13
386.0957947	3.43
386.9399414	0.35
387.8756104	0.49
397.3632812	0.28
399.1984863	0.12
400.1064453	0.26
411.8690796	0.13
426.2454224	1.66
427.4074707	0.61
429.1920776	1.38
430.2669067	0.39
439.0335083	1.07
440.4666138	1.03
442.3836060	0.33
443.3919678	2.92
444.2577515	9.23
445.4140625	3.91
446.4828491	0.27
455.3770142	0.41
456.7230225	0.67
457.3492432	24.25
458.3248901	7.16
459.2877197	1.10
460.3934937	0.35
469.2811890	0.21
471.4490967	0.57
472.6002197	0.11
473.4133911	0.35
474.3144531	0.21
487.2379150	1.15
488.3211670	8.42
489.3956299	0.87
490.4260254	0.23
552.3473511	0.17
561.3457031	0.07
564.6581421	0.17
579.5394897	0.13
593.4033203	0.35
594.6663818	0.18
609.2676392	0.54
610.7508545	0.61
611.8323364	0.31
612.4909058	0.25
613.5090332	0.18
622.3154297	0.62
623.5287476	0.59
625.3672485	6.74
626.4570312	1.87
627.6122437	0.15
636.3206177	0.28
639.2712402	0.86
640.3795776	100.00
641.4114380	41.27
642.3666992	5.61
653.4539185	1.58
654.2875366	0.18
667.7052002	0.10
688.8261108	0.33
713.4713745	0.06
715.7841187	0.08
771.5383911	0.20
789.6175537	3.13
790.4231567	1.54
801.9902954	0.31
807.2150879	0.45
808.8084106	0.22
811.4839478	1.33
819.4711304	0.16
820.9080200	0.72
822.3528442	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	751.1385
Annotation	Unknow
Peak:m/z	Relative Intensity
224.9484253	0.07
229.4478912	0.08
230.5422363	0.10
231.3028259	0.06
233.2247620	0.04
235.3676300	0.05
239.4598999	0.04
244.3770294	0.09
246.4004822	0.06
253.2849121	0.05
254.3324585	0.29
255.5015259	0.03
256.2106934	0.11
261.1596985	0.02
262.2121582	0.11
263.2581177	0.03
268.9628296	0.02
270.0266418	0.02
270.9300537	0.05
272.1149902	0.03
278.1780701	0.16
279.3864746	0.02
281.0223694	0.07
284.1972961	0.40
285.3693542	0.11
288.2346191	0.79
289.2951660	0.03
295.9614868	0.05
306.2872314	1.15
307.1380005	0.05
309.2598877	0.03
322.0569763	0.53
323.0580444	0.06
325.2930298	0.03
326.4553223	0.05
330.2604370	0.05
333.3767700	0.04
338.2078552	0.10
340.2648926	0.05
341.1453552	0.36
348.3533325	0.18
351.0471802	0.12
357.1897888	0.55
358.2571716	0.27
359.0931396	0.11
360.2868042	0.06
362.2993469	0.02
363.3673096	0.09
363.9866943	0.12
364.9737549	0.04
366.2792969	0.82
367.2296143	0.15
370.3713379	0.04
374.0165405	0.31
375.2473755	2.79
376.3572998	0.11
378.3274536	0.13
382.2230225	0.10
383.3178101	0.15
384.6101074	0.09
385.5490112	0.15
391.2522583	0.13
392.1901855	0.06
393.2449341	0.03
398.1782227	0.07
400.1307373	0.45
401.3659668	0.30
403.3817749	0.10
408.0874634	0.09
409.2783813	3.53
410.1854248	3.74
411.2796021	0.41
417.1704102	0.23
424.4816284	0.27
425.1970825	0.03
426.2326660	0.42
427.5578003	0.08
428.4289551	0.07
429.2824097	0.20
434.4759521	0.18
435.3442993	0.02
436.2650146	0.03
442.2407227	0.19
443.5689087	0.34
444.3018188	0.92
445.4677124	0.10
450.2356567	0.13
452.2966309	0.18
459.3179321	0.12
460.3419800	0.25
462.2279053	0.17
467.1110229	0.06
468.0073853	0.53
468.6185913	0.04
469.6764526	0.17
470.7291260	0.23
474.3297729	0.07
476.2900391	0.03
486.3801270	4.79
487.3219604	0.93
489.4498291	0.09
492.2147827	0.04
495.6354980	0.03
499.2218018	0.05
501.1346436	0.31
502.5062256	0.17
504.2304077	4.21
505.3426514	0.57
508.1816406	0.06
511.5228271	0.06
516.6920776	0.15
518.0611572	0.03
520.2397461	4.95
521.3850708	0.39
522.4896851	0.11
523.3504639	0.09
524.3753052	0.12
525.5975952	0.02
527.3214111	0.04
529.3801270	0.02
533.1954956	0.04
534.2341919	0.08
536.9280396	0.08
538.2695312	50.45
539.2831421	8.62
539.9202271	0.03
540.5220337	0.03
545.2184448	0.05
547.6245728	0.08
548.5921631	0.05
555.2333374	0.26
559.3143921	0.05
564.3878174	0.09
568.1574707	0.08
570.4205933	0.18
571.1661377	0.18
573.2567749	1.27
574.4345093	0.45
577.2457886	0.48
578.4935303	0.20
580.4385376	0.10
585.3447876	0.11
586.1986694	0.30
587.2015991	0.06
589.1577148	0.25
591.1914062	0.08
592.3488770	0.07
593.5651855	0.10
595.4629517	0.06
596.4612427	0.33
597.6555786	0.18
598.4862671	0.25
599.5571899	0.08
601.5006104	0.07
603.4216919	0.20
606.2314453	0.04
607.2206421	0.57
608.3896484	0.10
611.3121948	0.87
612.3436279	0.33
613.2858276	0.21
619.4980469	0.09
620.4767456	0.04
621.4235229	0.38
622.3497925	0.23
624.2275391	0.07
625.4270020	0.24
626.3043823	0.04
629.5258179	0.35
630.3482056	1.54
631.5149536	0.35
632.5388184	0.14
633.3009644	0.26
634.2055054	0.05
637.2432251	1.93
638.3682251	0.36
639.4428101	0.61
640.4502563	0.04
642.3612671	1.66
643.3677979	1.13
646.4938354	0.24
647.5930786	0.16
648.3099976	0.17
649.4519653	0.11
651.2269897	0.11
653.4226685	0.09
655.2363892	7.04
656.3192749	3.00
657.2290649	0.05
658.0543213	0.34
659.2473145	0.05
663.2359619	0.15
664.3567505	0.08
665.4044189	0.92
666.3240356	0.41
667.5229492	0.49
668.3319702	0.26
669.1553345	0.61
670.5563354	0.14
671.3765259	0.84
672.5501709	0.44
673.3740845	6.50
674.4696655	2.17
676.3975220	0.97
677.3733521	0.23
681.2528076	4.73
682.2327881	2.55
683.4653931	0.40
684.4918823	0.24
687.1116333	0.63
688.5073242	0.53
689.4055176	3.07
690.2080078	0.60
690.8123169	0.08
697.2346802	0.02
699.2753296	31.80
700.2741089	8.53
705.6283569	0.08
707.3171387	27.46
708.2725220	6.78
708.9799194	0.05
715.2696533	3.73
716.5899048	2.70
717.3380737	19.00
718.4214478	5.02
719.6600952	0.19
731.3763428	0.32
733.2626343	100.00
734.2540283	32.71
734.9481812	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0814667	1.52
179.1289368	100.00
181.3347168	0.05
205.2973328	0.13
209.0510254	0.06
223.1360474	1.30
224.2982635	0.07
225.2994843	0.17
288.0234985	0.05
294.8712158	0.12
297.2835693	0.87
341.2559814	2.70
343.3533936	0.14
359.1798706	0.10
385.1933594	0.20
476.9235229	0.08
485.0908813	0.05
503.1712646	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1382
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0242767	0.88
196.7325134	0.08
221.2347107	0.16
232.5710449	0.05
234.0820923	0.24
241.0559692	0.07
245.6871033	0.15
250.6688843	0.05
259.0983582	7.29
260.1697693	0.37
280.6361084	0.09
310.6463013	0.05
323.1793823	0.99
341.0310669	1.54
342.1320801	0.03
379.1634521	0.26
383.3071289	0.94
384.1929321	0.18
403.2661743	0.32
404.4793701	0.08
421.1719971	4.18
422.1886597	0.37
439.2217407	32.36
440.2338867	2.71
442.9490356	0.13
503.3038330	100.00
504.2963257	19.09
556.3450317	0.15
583.3623657	24.78
584.3062134	4.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.177
Annotation	Lactucaside
Peak:m/z	Relative Intensity
161.1874237	0.06
165.0288849	1.43
166.9717712	0.05
175.1147003	0.06
177.9843140	1.77
191.0911713	1.27
193.1330261	25.46
195.0526733	3.99
210.1313934	0.05
215.3024902	0.05
223.0964966	0.14
225.1190186	0.20
235.0920105	0.24
243.0626831	0.07
262.0083923	0.04
265.1933594	0.04
270.4580078	0.08
285.2489014	0.28
288.1086426	0.04
326.9035645	0.11
338.9992676	0.29
341.2233887	14.85
343.0829468	0.07
345.0607910	0.27
351.4580078	0.08
353.2789307	0.03
354.3615112	0.08
356.3927612	0.06
358.2648315	0.09
371.0451660	0.64
371.6461792	0.12
375.9788818	0.04
377.3338013	0.26
383.6950073	0.13
385.3159790	0.48
387.2924194	0.43
389.1290283	100.00
389.7907715	0.32
394.3459473	0.04
397.2196045	0.19
406.9487305	0.05
420.9051514	0.12
421.5346680	0.04
431.1635132	0.64
441.1706543	0.34
442.4652710	0.14
444.7670898	0.38
447.2725830	0.11
448.1830444	0.03
455.2962646	0.07
461.2634888	0.05
464.3162231	0.07
471.8492432	0.16
476.3284302	0.04
486.6292725	0.07
491.2615356	0.26
503.7339478	0.19
504.4859009	0.11
505.1529541	0.17
505.9974365	0.16
507.3543091	0.04
514.4033813	0.13
519.8187866	0.05
520.6464233	0.09
525.5122070	0.10
528.4003906	0.49
532.2071533	0.17
533.2737427	0.04
534.7453003	0.33
536.2157593	0.09
541.2681274	0.45
542.1572266	0.23
545.9888306	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1198
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
131.1226196	0.04
142.9708099	0.05
160.9993591	0.16
179.0013733	1.76
250.8843079	0.03
269.3435059	0.06
277.1679993	0.19
293.0514526	0.08
295.1917419	0.23
341.1642151	100.00
361.2249451	0.13
362.0299072	0.09
439.2153625	3.84
439.8433533	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.1829
Annotation	Arabelline
Peak:m/z	Relative Intensity
223.2305145	0.02
251.3193665	0.03
281.1682129	0.05
320.1170044	0.02
327.4211121	0.02
335.2740479	0.03
338.2724609	0.01
351.3403625	0.03
353.2323608	0.80
355.1956787	0.03
372.5020142	0.02
453.7086792	0.02
455.5201416	0.01
463.3097534	0.01
474.3829346	0.02
478.8881836	0.02
483.4024658	0.01
491.1412354	0.01
501.3105469	0.06
505.5087280	0.01
506.1990967	0.02
507.1683960	0.02
508.2257080	0.02
509.1244507	0.11
512.7653809	0.04
525.4957275	0.14
527.2544556	100.00
527.8651733	0.69
537.1560059	0.01
542.9912720	0.01
544.3786011	0.03
545.4083252	0.05
555.1604614	0.06
556.4386597	0.03
585.4018555	0.04
611.3961792	0.04
620.9889526	0.02
623.1294556	0.01
632.3819580	0.03
643.0232544	0.01
667.1370239	0.02
672.4157104	0.10
673.8724976	0.02
674.5109253	0.03
675.1164551	0.01
677.5061646	0.03
683.3008423	0.05
686.4675903	0.01
698.2963257	0.01
700.7509766	0.16
701.5733032	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.1566
Annotation	Chitobiose
Peak:m/z	Relative Intensity
135.8229675	0.05
150.1103973	3.35
152.7974548	0.07
161.1798248	0.19
171.1204834	0.27
175.1314545	0.04
177.0387726	0.09
185.3056641	0.20
203.1855011	0.08
217.4206848	0.05
233.0849609	0.20
244.1970520	0.15
244.9230652	0.05
247.2094116	0.05
249.1212769	0.05
253.5651550	0.03
264.1872864	0.20
265.2417297	0.17
268.9681091	0.05
275.2098694	0.43
277.4055481	0.25
282.1129761	2.86
293.1526794	0.13
295.2173157	100.00
297.1961670	0.17
301.1300049	0.08
306.9695129	0.16
313.5329590	0.07
315.0763550	0.05
321.3146362	0.04
323.0625610	0.15
336.8394165	0.32
337.7553101	0.05
339.4050293	0.23
343.4271240	0.11
345.0455627	0.06
349.3659058	0.08
352.7752686	0.18
361.3948364	0.33
365.5862122	0.07
370.3764648	0.05
379.2481384	0.18
381.1854858	1.36
382.2886047	0.24
383.4460754	0.37
391.6452637	0.43
399.6667786	0.05
408.4526672	0.63
409.1909485	1.43
426.5713806	0.09
429.7476501	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.1541
Annotation	Pirbuterol
Peak:m/z	Relative Intensity
69.9399338	0.48
71.1072006	0.10
71.9602051	0.13
78.4811935	0.20
80.9311447	0.26
81.9568100	0.07
83.9676819	15.25
84.8797150	0.35
95.0298004	0.08
96.0274048	0.18
97.2169189	0.35
98.0343475	1.65
100.0865326	0.44
104.9996643	0.08
109.1387634	0.18
110.9122772	0.35
112.9146271	0.06
114.0692749	0.19
115.9908600	0.63
121.0657959	0.34
123.9511871	0.07
125.9560547	1.28
127.9838715	22.26
130.8986206	0.22
140.0351715	0.09
144.0910797	16.04
144.8992615	0.08
149.0182343	0.09
150.2081604	0.58
152.1024323	0.89
155.0699310	0.05
156.9284668	0.10
158.0551605	1.74
168.0140839	4.32
176.9676514	0.04
177.9803925	0.06
178.8813324	0.04
181.1133270	0.44
183.0193329	0.10
184.2936554	0.22
185.1243134	0.09
187.1287079	0.06
196.1307526	100.00
197.1862488	0.25
198.2447052	0.53
199.1156464	0.12
199.7751923	0.12
205.1073761	0.20
213.2029266	6.47
223.1454010	1.48
241.0680542	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2181
Annotation	Ficusesquilignan B
Peak:m/z	Relative Intensity
165.1242523	1.43
166.3294525	0.07
177.0995941	0.20
178.7185822	0.07
179.8441925	0.10
182.1617584	0.02
187.2199860	0.02
187.8835144	0.07
190.2798462	0.03
192.1274109	0.10
195.0302429	9.48
196.1843414	0.68
203.3025208	0.16
206.1867523	0.08
209.2985077	0.06
219.3069916	0.06
220.1442719	0.24
221.1500244	0.09
233.1745148	0.01
292.0014343	0.01
307.3281250	0.07
308.5011597	0.03
309.2768555	0.09
310.1624146	0.02
311.3449402	0.02
312.2270508	0.05
313.2756348	0.04
321.4065552	0.03
322.4476318	0.07
323.3381958	0.19
324.3121338	0.43
325.2849731	0.15
326.3233643	0.08
327.4258423	0.29
328.3693848	0.05
334.3248291	0.01
337.1458130	0.38
338.1938477	1.48
339.2427368	3.04
340.3101196	0.46
341.3813477	0.18
342.1762695	0.42
343.2256470	0.66
344.4972534	0.09
354.2768555	3.78
355.3419189	1.34
357.2877197	52.94
358.2788696	8.37
369.2851562	100.00
370.2594604	14.83
373.3464966	0.15
383.4517822	0.07
385.2484131	0.27
386.3291626	0.12
387.3037109	0.97
388.4569702	0.26
403.2948608	0.15
406.0986938	0.04
411.3275757	0.01
412.3845215	0.02
413.0371704	0.04
414.3780518	0.01
425.2774658	0.04
429.0891113	0.01
436.4863281	0.04
451.5245361	0.03
453.3261108	0.07
455.3729858	0.06
459.0547485	0.03
469.5664673	0.10
474.9869385	0.03
477.4431152	0.06
484.3583984	0.02
489.2261963	0.11
490.5197754	0.02
491.4499512	0.01
493.3922729	0.02
505.3458252	0.36
506.4483643	0.21
507.4276733	0.03
517.3310547	0.43
518.3781128	0.17
521.9537354	0.01
523.0050049	0.10
524.2907104	0.01
533.4648438	0.15
535.3152466	18.54
536.2946167	5.59
537.3905029	0.01
539.6079712	0.01
546.2170410	0.02
547.2506714	0.12
548.5396729	0.11
553.3214722	3.36
554.2801514	1.20
556.3740845	0.02
565.2476196	4.55
566.2955933	0.97
575.1936646	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	717.2755
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0815430	0.22
259.1410522	0.10
294.2235718	0.10
310.9743347	0.10
323.4712219	0.29
324.3019409	0.08
326.3549805	0.20
327.2910767	0.08
341.3599243	0.69
342.4172668	0.04
350.9681396	0.10
353.4406128	0.07
355.1845703	0.28
357.3862915	0.36
358.2855835	0.14
369.4643555	0.38
371.2991333	19.45
372.3684082	3.77
380.3916626	0.12
385.3302002	0.05
388.7849121	0.05
389.4096069	0.29
413.5689697	0.08
425.3140259	4.35
426.3885498	0.51
434.3439941	0.08
443.2031250	0.21
459.5733032	0.09
465.5441895	0.11
469.0036011	0.16
485.3516235	0.06
489.3854980	0.33
502.4581299	0.20
505.2046509	0.09
507.4098511	0.45
508.2059937	0.19
517.3341064	0.11
519.3731079	100.00
520.3740845	25.54
521.2625732	11.18
522.2725220	3.48
531.2802124	1.65
532.3921509	0.73
533.1887817	0.15
535.3115234	0.13
537.7955933	0.17
538.5715942	0.31
549.2784424	11.73
550.4134521	2.79
552.0551147	0.16
553.1955566	0.04
554.2785034	0.10
555.2163696	0.14
556.4559937	0.21
557.5451050	0.08
561.2450562	0.09
562.4572144	0.07
563.4020386	0.07
567.1577148	27.02
568.3381348	7.74
575.3165283	0.07
586.6490479	0.06
599.3308105	0.29
608.6324463	0.09
641.9689331	0.11
645.4671631	0.09
655.2717896	0.17
669.2471924	98.73
670.3689575	35.68
671.5941772	0.24
681.6987305	0.48
687.3302002	0.06
696.4005737	0.45
699.3862915	2.88
700.3905640	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.167
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
201.1610260	0.03
217.0504150	0.22
227.4879150	0.11
228.2139130	0.03
229.0031738	0.61
240.2635803	0.02
241.1481934	0.09
247.1208954	0.04
253.1611633	0.06
254.0606537	0.05
263.1288147	0.03
264.2449951	0.12
265.0090332	0.15
266.2513733	0.04
267.1623840	0.12
269.0439453	0.20
276.3087158	0.09
277.1677551	0.81
279.3764648	0.02
280.1646423	0.03
283.1208496	0.06
286.3306274	0.13
289.2116699	0.03
292.4747009	0.24
293.2649231	1.56
294.3038940	0.47
295.2106323	3.16
297.2028809	0.04
299.4287109	0.03
303.2797852	0.19
304.1320801	0.07
307.4947815	0.06
310.1145020	0.06
311.0591431	0.18
313.1741943	0.38
321.1774292	16.35
323.5911865	0.02
325.3450317	0.21
328.5005493	0.04
337.3578491	0.39
339.0888672	12.14
339.7664185	0.04
351.3129272	0.06
359.1923218	0.13
360.9488525	0.16
364.2825928	0.06
366.4182129	0.08
370.3754883	0.05
371.1922607	0.09
372.1656494	0.05
375.2865601	0.05
379.4783325	0.06
381.2216797	0.03
385.5177612	0.06
403.1265869	1.01
407.4359131	0.03
409.3648071	0.03
425.1897583	0.04
433.2993164	0.11
441.3581543	0.22
448.2243652	0.03
449.3322144	0.11
451.1072388	0.08
468.3201294	0.23
469.3165283	2.47
477.5078125	0.04
481.2706299	0.04
483.3611450	0.03
485.3273926	2.32
486.1899414	0.07
487.1959839	0.74
490.1663208	0.11
495.2681274	0.88
499.4627075	0.17
508.3475952	0.03
511.1598511	0.13
513.1901245	100.00
513.8717651	0.30
517.3198242	0.04
519.4636841	0.03
525.0341187	0.03
530.4789429	0.18
531.2444458	0.21
533.3922729	0.04
538.0363770	0.03
543.1974487	0.18
549.3811646	0.15
552.2216187	0.02
553.3569946	0.03
570.3396606	0.12
571.2625122	0.03
572.2421875	0.04
576.7211914	0.05
591.1063843	0.06
595.3433838	0.52
598.3457642	0.03
608.5144653	1.09
609.3051147	0.26
617.2906494	0.23
618.2613525	0.08
639.2747192	0.06
642.4873047	0.10
643.3363037	0.07
644.9744263	0.11
648.0607910	0.05
658.0577393	0.14
661.0855713	0.11
669.2232056	0.05
671.4837036	0.23
686.4847412	0.02
687.2332764	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1669
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
292.8852539	0.01
295.2986145	0.02
296.9540405	0.01
321.2244568	0.02
322.2166138	0.01
339.2332764	0.71
340.2960205	0.09
351.2209473	0.07
353.0908203	0.07
375.3306885	0.01
378.4196777	0.02
437.2031860	0.03
469.3997803	0.02
470.5003052	0.01
513.2461548	100.00
514.2987061	7.16
525.5997925	0.01
532.1164551	0.01
540.3693237	0.01
543.4150391	0.03
544.3666382	0.06
553.0360107	0.02
557.2752075	0.01
609.0420532	0.04
620.8439331	0.01
675.2036743	0.00
679.4277954	0.04
687.6706543	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	207.0299
Annotation	Isoochracinic acid
Peak:m/z	Relative Intensity
76.8181076	0.04
86.9028168	0.04
91.1743622	0.03
101.1726379	0.02
119.1052551	0.06
120.9701385	0.01
129.2558594	0.02
131.0454559	0.04
135.0254364	2.43
137.0266724	0.50
143.0753632	0.23
147.0072784	0.06
159.0496521	0.03
161.0710449	3.47
163.0474396	0.93
178.9917450	100.00
189.0458527	0.31
190.0370026	0.01
191.9155579	0.25
206.7560730	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1742
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
163.0425568	0.05
178.1275482	0.16
180.1388245	0.11
181.1530151	0.19
191.1709595	1.10
192.2315369	1.09
193.1845703	0.40
194.6739502	0.06
199.0251160	0.23
206.9899445	0.20
209.2275696	0.07
219.3078613	0.15
224.9762268	0.06
232.9089966	0.19
281.1544189	0.11
295.4173584	0.11
311.3099976	0.77
313.1807861	0.45
321.2248535	2.23
323.1320190	0.18
324.3597412	0.06
334.1054688	0.04
338.2889404	0.09
340.1925049	0.30
341.2197266	0.93
346.3749390	0.06
353.1926880	5.65
356.0412598	0.21
363.3092041	0.20
365.3790283	0.08
371.0883179	100.00
371.7703247	0.27
382.1308594	0.33
389.3170776	0.07
398.8662109	0.07
400.2664795	0.10
401.2769165	0.25
408.1401367	0.09
428.9974976	0.17
432.9763794	0.09
446.4888306	0.26
473.2349854	0.08
487.4782104	0.22
492.5548706	0.20
495.0370483	0.04
503.5101929	0.30
504.5386963	0.09
517.1650391	0.14
518.6925049	0.23
520.5920410	0.08
521.9414673	0.06
526.4478149	0.61
530.8504639	0.10
532.9125366	0.54
535.2372437	0.04
536.1686401	0.70
538.0877075	0.33
544.1836548	0.96
545.2825317	0.22
546.1347656	0.04
548.2981567	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.9471
Annotation	Unknow
Peak:m/z	Relative Intensity
97.0129852	0.03
128.1252441	0.06
133.0051880	0.05
141.9295044	0.03
145.1952820	0.06
154.9461517	0.04
183.9033508	0.06
185.9357910	7.64
187.9963379	0.97
191.1697540	0.16
198.8175964	0.03
203.9142151	0.64
213.8566284	5.25
215.8658752	0.04
227.0478210	0.03
227.9962463	0.02
229.8501587	11.80
231.9100342	1.90
246.3077087	0.06
247.9490356	1.21
255.6385498	0.03
257.3096313	1.32
257.9828186	13.73
259.0134277	0.85
260.0769043	0.73
273.9454346	0.23
275.9720154	100.00
276.7521362	0.01
289.1971130	0.03
301.1377869	0.15
301.8927612	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	530.0557
Annotation	Unknow
Peak:m/z	Relative Intensity
164.0285339	0.07
174.9060364	0.15
187.0121155	0.05
198.8070984	0.19
203.1482697	0.07
210.9898071	0.10
213.1143494	0.02
216.3047485	0.10
217.1375427	0.08
234.8031616	0.21
248.4032898	0.14
249.0374756	1.74
259.0736084	0.07
260.8636169	0.21
270.5626831	0.06
273.0596008	0.15
277.0556641	17.57
278.9577026	0.50
284.5916138	0.05
288.9600525	2.53
290.9697876	0.05
295.1104736	0.38
305.0160522	0.05
306.9438477	26.39
308.9971313	6.55
315.4490356	0.05
318.8584595	0.44
321.1506348	0.06
324.2877808	0.08
324.8892212	0.14
330.9040527	0.04
332.8880615	0.15
335.1472778	0.03
336.9119263	15.10
348.7720337	0.06
351.1069336	6.31
359.1887817	0.07
361.0266113	0.22
366.8565674	0.67
368.0295410	0.80
369.1121826	19.64
378.8587036	0.90
380.6825562	0.02
383.3681641	0.07
394.7932129	0.24
395.7131348	0.69
396.9437256	100.00
397.5903931	0.21
402.2437744	0.06
410.9356689	0.48
422.6946411	0.16
441.1180420	0.44
456.1719971	0.07
464.8223877	0.11
470.7396240	0.26
471.4174805	0.20
473.1524048	0.10
486.0874023	0.33
487.2564087	0.32
495.2525024	0.06
495.9747314	0.03
501.0269775	0.27
503.5786743	0.08
512.9502563	0.80
513.5924683	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.09
Annotation	Unknow
Peak:m/z	Relative Intensity
147.9655914	0.02
151.1576080	0.06
153.0719452	0.23
160.0482025	0.26
163.1913300	0.03
165.1401825	0.06
166.1835022	0.05
167.3387756	0.21
171.0333557	0.04
175.1322937	0.04
177.1930847	0.41
178.1028595	0.05
178.9938965	0.83
184.1606445	0.08
185.1135254	0.30
185.9496307	0.16
191.9172363	0.28
193.0107422	0.13
193.8423309	0.03
197.2894135	0.08
199.0302429	0.10
203.3551941	0.14
207.1938171	0.12
209.1052856	0.04
210.1543884	1.04
211.1853943	0.41
212.0980988	0.05
213.2234955	0.03
219.3125305	0.83
223.2409058	0.16
225.1223450	0.09
228.1548615	0.07
228.9764709	0.19
230.2372742	0.47
231.3833923	0.05
236.0382233	0.07
236.9127197	0.15
244.1213837	0.03
245.0787964	0.04
245.9752808	0.03
252.2564087	0.11
254.1600952	2.69
255.1661987	0.10
260.1510010	0.02
263.2003784	0.12
265.3798218	0.16
269.1604614	0.39
270.0736694	0.13
272.1865234	1.87
279.1524658	0.04
281.1339722	0.03
283.1636353	0.04
284.2343140	0.11
288.1574097	3.40
289.2326050	0.14
295.9644470	0.23
297.1639404	0.36
301.2915039	0.17
306.1354980	19.34
308.1826172	0.10
311.1788330	0.03
320.3741455	0.02
322.2058716	0.66
323.1836548	0.10
323.9772339	0.04
326.3911133	0.08
327.3765259	0.06
331.1061401	0.17
332.2606201	0.06
333.0888672	0.12
336.1805420	0.02
338.3596191	0.24
340.1870728	0.20
341.2247314	0.94
342.2202759	0.07
345.3421021	0.17
348.1355591	0.04
350.0517578	0.03
351.2998047	0.05
353.3922729	0.17
354.3565063	0.03
356.2201538	0.12
359.1691895	0.19
361.2114868	0.13
363.1445923	0.05
366.1413574	0.85
367.2320557	0.10
368.1898804	0.05
369.4226685	0.02
371.1998901	0.46
372.2912598	0.07
373.3145752	0.05
374.1876221	0.22
376.8256226	0.14
377.4256592	0.10
379.1578979	1.35
380.1903076	0.38
381.4440918	0.03
384.2565308	0.07
385.3897705	0.03
386.8236694	0.07
389.1162109	0.10
390.2477417	0.13
391.2979126	1.23
393.3734131	0.24
395.0695190	0.06
397.5769043	0.65
398.2994385	1.07
399.9885864	0.15
401.2295532	0.05
403.3583984	0.21
405.3659058	0.94
407.2127075	0.08
410.2326050	2.10
411.2855225	0.23
414.3411255	0.03
415.2116089	0.68
417.4335938	0.39
423.3184204	10.58
427.3011475	0.26
428.1536865	0.21
429.3207397	0.03
431.1000366	0.09
435.3640137	4.03
437.3175659	0.98
439.1824341	0.24
441.1983643	2.36
443.0308228	0.03
444.1531372	0.38
446.2387085	0.15
449.1898193	5.00
455.3022461	1.06
457.1675415	3.53
458.3983765	0.11
467.2937622	38.85
468.1282959	0.04
475.2620850	5.51
483.2507935	4.76
485.2365112	16.17
485.8468628	0.08
489.1956177	0.04
491.4263916	0.14
499.3132935	0.02
501.1989136	100.00
501.8519897	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2818
Annotation	2,2'-Disinomenine
Peak:m/z	Relative Intensity
224.9785614	0.03
269.3460693	0.07
299.2797852	0.02
325.3208618	0.05
355.4514771	0.06
402.3677368	0.05
403.3566284	0.02
432.3074951	0.06
444.2972412	0.25
445.2631836	0.07
446.2088623	0.04
447.3521118	0.03
448.1132202	0.06
449.4742432	0.06
462.6885376	0.13
463.4891968	0.13
469.3693237	0.04
476.9743652	0.15
488.4502563	2.57
489.3718872	0.43
497.5941772	0.08
505.5369873	0.03
508.4360962	0.18
520.3464966	23.27
521.3817749	5.44
541.4649048	2.34
542.6055298	0.87
544.2614136	0.05
573.3035278	0.13
574.0152588	0.16
583.4523926	1.06
585.3906860	15.98
586.4882202	6.43
588.5982056	0.02
589.4271851	0.07
599.1108398	0.08
601.4552612	1.02
602.4525757	0.44
604.3618164	0.03
617.4038696	88.16
618.4259033	26.91
627.3746948	18.42
628.4561157	7.97
634.2228394	0.08
645.3990479	100.00
646.4135742	37.14
647.1238403	0.13
650.6644287	0.11
654.1260376	0.05
659.3720093	45.67
660.4441528	14.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1975
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
243.1313782	2.43
245.0466003	3.01
246.3523407	0.31
250.2213440	0.17
257.1036987	0.22
259.3428040	0.16
261.3076782	0.67
267.2219849	0.08
269.0852051	0.25
271.1076050	0.14
273.1784973	0.57
279.1427612	0.28
281.2594604	0.10
283.2748413	0.29
285.2140808	0.17
287.1832886	15.59
288.1976929	1.05
289.1710205	5.61
290.3390808	1.10
297.1785889	0.10
299.2154541	2.25
300.1889038	0.23
302.2506714	0.18
303.4335327	0.62
304.5177917	0.07
307.2889404	0.42
311.3749390	0.20
315.1199646	0.06
316.1932983	0.06
325.1042480	0.53
327.0961304	0.24
328.2030029	0.25
331.2700500	0.44
333.2044678	0.22
337.2260132	0.63
339.1257324	0.21
340.1558838	0.08
341.3051758	0.89
355.5584412	0.12
363.2659912	5.75
364.1480103	0.11
365.2120361	0.28
366.9039917	0.51
369.5748291	0.10
371.1037598	0.56
372.4256287	0.28
373.1756592	0.43
377.2132568	0.32
379.1530151	0.44
381.1678772	1.04
382.3037109	0.19
383.1716309	0.87
387.7913818	0.37
391.4628296	0.59
393.3680420	0.55
395.2802734	4.13
395.9877930	0.09
396.5992432	0.34
397.3942871	0.18
405.2413940	7.14
406.3478394	1.58
407.2194824	29.24
408.2684937	2.83
409.3528442	1.03
413.2279053	8.41
414.2231445	0.72
415.4556885	0.10
417.0303955	1.19
417.6778564	0.04
419.4426270	0.18
423.2365723	4.47
425.1518555	19.71
426.2498779	2.25
431.4786377	0.46
433.3469238	1.10
434.3691406	0.36
435.1847534	1.79
436.4121094	0.14
437.2940674	0.79
447.2941895	1.24
449.2001953	17.85
450.4280396	3.97
451.2846069	14.19
452.2448730	2.11
453.4743652	0.21
454.1555176	0.59
455.1544189	0.08
465.2994995	0.61
466.4812622	0.48
467.4907227	1.04
468.3340454	0.16
473.2229004	0.10
475.2241211	0.16
476.4762573	0.06
478.3756104	0.24
481.5374146	0.12
489.6285400	0.37
491.5762939	0.18
493.3930664	0.30
494.4487305	0.08
498.8789673	0.11
509.4083252	0.30
512.1727295	0.46
515.2657471	1.71
517.3440552	0.64
519.1007080	0.54
520.2062378	0.06
525.4306641	2.81
526.5017090	0.27
527.9488525	0.35
529.2898560	0.08
531.6143188	0.70
533.2753296	7.11
534.3102417	1.64
535.3759155	0.94
536.4375000	0.28
543.2390747	12.84
544.2432251	2.05
545.1354370	0.08
546.3796997	0.18
549.2427368	0.19
555.6081543	0.13
557.3771362	6.61
558.2737427	1.68
559.2824707	4.88
560.4542236	1.35
561.2404785	2.86
562.3624878	0.59
569.3338623	6.44
570.3803711	2.17
575.2109985	32.48
576.4234619	6.25
577.2656250	58.44
578.2024536	9.06
584.8291626	0.41
586.5546265	1.71
587.3233032	20.72
588.1940918	2.37
598.9403687	0.27
600.4138184	0.10
602.8263550	0.15
606.4953613	0.11
611.2868652	0.83
612.5405273	0.08
613.7421265	0.12
616.5954590	0.37
617.3192139	0.99
618.0726929	0.13
619.1867065	4.22
620.1654663	0.44
625.0867310	0.79
629.3342285	1.26
630.5043335	1.56
633.4089966	0.08
651.5673218	0.49
652.4526367	0.07
669.2924805	3.99
670.4408569	0.33
677.3563843	4.97
678.4716187	1.14
683.5838013	0.08
693.3768311	0.24
695.2404175	100.00
696.3062744	18.49
697.4244385	0.58
698.1267700	0.42
703.1366577	0.40
713.2360840	39.64
714.3440552	5.73
720.1125488	0.37
721.3799438	1.64
722.4177856	0.10
723.8494873	0.12
725.3867798	0.12
726.2975464	0.15
737.6251831	0.62
739.2276611	59.51
740.2513428	12.22
746.5695190	0.26
755.3899536	0.94
780.9794922	0.19
785.4547729	0.06
789.3400269	1.11
797.4808960	0.16
803.4662476	0.17
804.2803345	0.63
821.3193970	1.90
829.5005493	0.06
830.7312622	0.38
832.7214355	0.17
847.2859497	17.67
848.2623901	7.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1147
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
148.9894104	0.06
163.9638824	0.30
179.1599426	0.18
208.1499329	1.55
209.1908569	0.10
210.8056946	0.20
223.0712585	100.00
265.2424927	1.09
289.1487732	0.17
294.9962463	0.09
321.3005981	0.07
337.9290466	0.05
339.2839661	0.29
340.5928650	0.26
367.4685974	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.98677063	0.65
96.79381561	0.21
109.1129379	0.91
118.205513	0.29
119.5473099	0.23
122.2460251	1.13
123.1653442	0.83
125.0202866	0.66
127.091568	0.60
128.8918457	0.97
130.8284607	0.59
133.0635834	0.62
135.1190948	0.25
137.0385132	0.57
139.0069733	3.06
140.8383331	0.69
143.1285706	2.03
152.6902771	0.32
154.9240417	1.00
162.9801331	1.51
166.9155273	0.84
168.9814606	1.44
170.9297333	0.35
178.8743286	0.53
181.1159058	2.47
184.2240601	0.89
185.2817688	1.09
195.1114807	4.48
197.0435791	2.89
199.0537567	0.92
207.1236267	1.29
209.1296082	0.21
211.0298462	2.96
212.6835938	1.22
213.3921204	0.68
214.9398193	0.37
217.1213684	0.70
219.2669373	0.43
221.007782	0.92
223.1777954	0.30
225.1933899	0.75
227.0066528	1.34
228.0142517	0.64
229.2028503	0.23
233.1861572	1.63
235.0290527	0.59
236.9752502	1.72
239.2359314	4.25
241.1550598	0.54
249.109314	0.23
251.2004089	2.76
253.1027527	9.03
253.9549561	0.27
257.6795044	0.23
263.2764893	0.32
265.0535889	4.43
267.4058533	3.60
268.3599854	0.21
270.1092529	1.09
275.1210327	14.61
275.7601318	0.17
279.5714722	0.27
283.3313599	5.55
287.7064209	1.43
290.7398987	0.62
293.2102661	100.00
294.4442139	0.27
296.3057251	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1362
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1587830	0.08
163.9294128	0.04
165.2074127	0.19
175.0744324	0.13
177.0915070	0.06
179.0840454	0.08
187.2535400	0.21
188.3343201	0.15
199.1284485	0.09
201.1728668	0.02
203.1821442	0.46
205.1435242	0.24
212.1611023	0.04
217.0503082	0.21
227.0813446	0.09
228.9934692	0.03
231.1495209	0.06
235.0753784	0.05
243.1246033	0.20
245.1683655	2.87
246.1205444	0.03
247.0802917	0.09
253.3995819	0.10
255.0829010	0.20
261.1542664	0.06
267.4136353	0.06
269.2743225	0.98
271.3098755	0.13
273.2003174	1.62
279.1140747	0.03
281.3154907	0.10
285.1531372	0.06
287.2569580	6.29
289.1821899	20.35
290.2293396	0.07
291.1362305	0.06
299.2379761	4.87
301.2971802	0.07
303.5414734	0.03
305.2137146	0.09
307.3015137	0.05
309.4071045	0.04
311.0961914	0.03
315.2581482	0.12
324.9605103	0.15
326.1343384	0.03
328.0951538	0.04
329.3280640	0.29
331.2229004	0.82
332.1820679	0.03
339.4997559	0.25
341.2113647	0.23
353.3853149	0.05
357.1975708	0.27
381.2337646	0.81
393.0938110	0.02
395.1665649	0.04
402.8799438	0.04
407.2108154	50.99
408.1206055	0.07
409.2917480	0.21
410.3401489	0.19
411.1802368	0.15
413.0977173	0.26
414.3279419	0.16
415.3130493	0.17
416.1759644	0.05
423.3389282	0.15
425.1902466	100.00
427.6742554	0.04
432.4978027	0.08
433.3834229	0.22
436.1979370	0.03
449.2617798	1.10
451.2136230	24.18
452.1942139	0.28
453.1215210	0.09
454.9650269	0.03
467.2996216	0.95
473.2551880	0.02
475.2423706	0.07
483.2667847	0.32
491.4438477	0.94
492.2451782	0.27
500.3472290	2.26
501.2020874	0.61
502.5889282	0.09
503.2359009	0.03
512.2893066	0.09
513.3014526	0.02
514.9030151	0.06
515.5228271	0.14
516.7171021	0.07
522.0466919	0.14
533.2313843	0.79
540.7916870	0.14
541.5682983	0.06
545.2253418	0.02
548.8170166	0.06
550.1354370	0.03
558.2493286	0.12
559.3767090	7.85
567.3775024	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
97.0146942	0.09
98.9369049	0.31
100.9633789	8.67
106.9258270	0.17
113.0537872	18.40
115.0172424	0.24
118.9178543	15.27
124.9940796	2.01
130.4097748	0.61
131.0329437	7.55
132.7805939	0.22
143.0157318	19.50
148.2614441	0.31
149.0148010	3.96
159.2438049	0.24
161.0335846	17.97
177.1037140	0.15
178.9380951	100.00
208.7063293	0.07
221.0118408	0.11
235.5300293	0.25
249.0757141	0.21
269.0644836	0.33
281.0770569	1.48
294.9992981	0.44
322.4107971	0.20
323.3141479	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0541534	0.04
212.9026337	1.54
218.9589844	0.02
290.9537964	0.04
296.7998657	23.87
297.5016479	0.02
302.8890381	0.25
344.8215942	0.11
356.8549805	0.06
378.0633850	0.05
380.6985168	100.00
381.5121155	0.15
404.8985596	0.03
419.1018982	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2021
Annotation	Rhusemialin A
Peak:m/z	Relative Intensity
165.1279297	1.74
166.1202698	0.20
175.0596771	2.28
176.0850830	0.90
177.1981201	0.07
178.0343475	0.08
180.0583344	0.14
180.9446869	0.14
190.1457520	5.01
191.2396240	0.49
192.2759705	0.05
193.0354919	0.20
195.1013031	2.00
196.0222321	0.17
203.1761017	0.13
204.1528778	0.63
207.0516968	0.07
208.0944214	0.14
216.1486206	0.05
218.1276550	6.99
219.1350708	3.34
220.2225037	0.29
223.2834015	0.05
231.2755432	0.19
234.5026855	0.02
239.0519257	0.05
245.1222229	0.03
251.2102509	0.08
261.2341614	0.04
271.1674805	0.03
283.3600464	0.02
293.3170166	0.04
297.9017334	0.06
308.2952271	0.11
310.3058472	0.15
311.3821411	0.04
313.4780884	0.07
318.9959106	0.08
321.3713379	0.09
322.2177734	1.16
323.0419922	0.27
326.1281738	0.10
335.6834717	1.12
336.3552856	1.84
337.2420044	2.77
338.3056030	0.43
341.1955566	3.14
342.2191162	0.37
343.3331909	0.27
352.1986084	3.44
353.1737671	3.33
355.2312012	23.36
356.2348022	4.23
357.2803345	1.72
358.4057617	0.16
359.2978516	0.07
364.2915039	0.02
367.2534180	100.00
368.2172241	20.19
369.1188965	2.27
370.3836060	0.95
371.2758179	1.40
372.2239990	0.05
373.0471802	0.23
374.3566895	0.10
379.2604980	0.03
383.0759277	0.88
384.4842529	1.47
385.1256104	5.08
386.1221924	1.01
393.2605591	0.03
399.5634766	0.23
401.2695312	0.18
405.3162231	0.09
407.2814331	0.08
408.8486328	0.11
411.2736206	0.07
415.1512451	0.04
419.0460815	0.08
427.4483032	0.08
428.9976196	0.04
437.4691162	0.05
439.2570190	0.09
457.2955322	0.88
458.2747803	0.59
467.3444214	0.03
473.2293701	0.33
474.5534668	0.03
481.9781494	0.08
483.2601318	0.06
485.2696533	0.07
486.1310425	0.02
490.4705200	0.09
497.4707642	0.08
501.4293823	0.16
503.4503174	2.93
504.4141235	1.55
505.4334717	1.39
506.4220581	0.12
507.4397583	0.04
513.3969727	0.36
514.3657837	0.28
515.2803345	8.31
516.2505493	3.17
517.4989014	0.15
518.8071289	0.09
519.5287476	0.27
520.5830688	0.10
522.3159790	0.03
524.3845825	0.04
533.2398071	57.91
534.2501221	17.25
535.0806274	0.10
536.0412598	0.08
537.3057861	0.51
538.4006958	0.68
539.4209595	0.03
544.6199341	0.04
545.4194946	0.10
546.4229126	0.09
547.4603271	0.11
549.4329224	0.09
551.3064575	14.04
552.2712402	5.75
553.3796997	4.81
554.4794312	1.07
558.0279541	0.08
563.0777588	12.78
564.2798462	2.61
566.3867798	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1671
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
230.2482300	0.02
266.8146667	0.02
278.2376404	0.01
294.9788513	0.01
305.6524048	0.01
312.3712769	0.01
319.3392944	0.01
321.3485413	0.05
339.1843262	1.24
340.1724243	0.23
351.9040527	0.06
353.2025757	0.06
377.3380737	0.02
424.5175171	0.02
469.5003662	0.01
470.4232788	0.02
478.4584961	0.01
485.2371826	0.01
486.2583008	0.02
487.4078369	0.02
513.2191162	100.00
514.2153931	12.40
514.8753662	0.07
521.4807739	0.01
531.2800903	0.03
539.2790527	0.01
543.3323975	0.07
544.5573120	0.04
590.6388550	0.01
594.5065308	0.02
609.5291748	0.01
610.2533569	0.02
616.4703979	0.02
643.1925659	0.01
687.0794678	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.05
Annotation	Unknow
Peak:m/z	Relative Intensity
72.9793854	0.04
82.7931824	0.04
84.9194488	9.99
87.1027527	0.05
101.0350800	0.28
110.9120178	8.55
124.9894562	0.06
128.9576569	1.91
133.0090790	0.07
143.0618134	0.15
147.1306763	0.10
159.1454926	0.25
161.0363922	0.61
163.2053986	0.05
173.0507660	0.42
177.0200806	1.85
179.3520050	0.03
186.9865112	2.30
190.7906036	0.05
205.0399933	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.27
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8591614	0.45
178.8988647	0.22
180.1425629	0.04
191.2571106	0.46
199.1757050	0.14
203.9794006	0.07
204.9441528	0.28
208.9452820	0.05
225.1453857	0.13
230.4273834	0.04
234.3189392	0.74
235.0451050	0.77
245.1394043	0.57
246.2754364	0.76
248.1794128	0.08
253.0901489	0.14
255.1385803	0.07
264.8616638	2.21
265.5990601	0.05
273.2301025	0.20
274.1176147	0.45
287.2165833	1.09
288.2922974	1.04
289.2180786	2.53
290.2685547	2.25
291.2873230	0.42
294.8110352	0.20
299.2040405	0.52
300.1575317	1.33
301.2458496	0.30
307.3292847	0.58
308.3561401	0.07
323.3123169	0.04
324.9674683	1.58
329.1626587	0.14
331.4268799	0.25
332.3158569	0.35
333.0301514	0.09
337.2645264	0.10
340.5328979	0.12
342.3962402	0.11
345.3452759	0.09
348.1654663	0.10
349.2448730	0.37
352.1107178	0.10
364.2261353	0.07
373.0831299	0.16
377.3681030	0.11
381.3545532	0.11
382.2530518	0.53
383.0240479	0.34
387.3821411	0.16
394.0751343	0.11
399.4743042	0.13
403.1723633	0.31
405.2370605	0.11
407.3468628	6.02
408.2265625	10.78
409.2307739	3.13
411.4261475	0.16
412.1833496	0.05
414.3119507	0.07
417.4227295	0.41
425.2306519	12.18
426.2477417	25.94
427.1760254	8.91
430.4500122	0.12
432.0596313	0.32
433.0696411	0.22
434.5077515	0.08
438.7171021	0.07
447.7916870	0.04
450.0549927	0.25
451.4089355	2.10
452.2671509	5.96
453.3526611	2.10
459.4295654	0.16
467.3680420	0.06
468.3187866	0.09
471.2794189	0.10
482.4089355	0.28
483.1439209	0.42
485.0598755	0.29
489.4424438	0.40
490.4997559	0.05
491.5743408	0.12
492.3114624	0.03
493.2233887	0.10
500.2151489	0.08
507.4506226	0.22
516.4408569	0.16
517.5347290	0.12
518.4249878	0.06
521.8931885	0.12
531.7298584	1.49
533.2556763	100.00
534.1430054	0.32
535.5535889	0.10
539.2684937	0.17
543.5896606	0.05
547.6188354	0.18
549.3877563	0.39
556.7025146	0.27
557.5781250	0.19
558.3660278	0.27
560.3325195	2.56
561.4301147	1.92
563.2278442	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.21
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0170135	0.08
176.1553345	0.02
177.3090210	0.09
179.0917358	3.40
189.1647339	0.02
191.1902161	0.06
193.2763214	0.01
197.4219055	0.03
203.2982788	0.15
205.1170044	0.09
221.0420227	0.13
223.1116943	13.15
241.1364746	0.16
245.3359528	0.04
247.0975037	0.06
265.2960205	0.29
277.3253479	0.11
283.1826782	0.03
287.5593872	0.03
295.2359619	0.26
305.3090210	0.05
307.4348145	0.05
311.1034241	0.04
323.5817261	0.06
325.2674561	0.30
329.1337280	0.06
337.2091675	0.10
341.0406494	0.02
351.1356812	0.02
353.3444824	0.03
355.1917725	0.02
359.3881836	1.15
367.1616211	0.09
372.0545654	0.06
375.2644043	0.04
385.3090210	9.82
387.2891235	0.04
389.0953369	0.31
390.1139526	0.07
391.2287598	0.04
397.0205078	0.03
403.2575684	100.00
405.0427856	0.02
407.3495483	0.03
412.3136597	0.06
444.7631836	0.02
445.3989868	0.23
457.1253052	0.05
458.8433228	0.01
464.7150269	0.02
473.1044922	0.02
475.5695190	0.09
503.0774536	0.07
505.2651978	1.02
519.2638550	0.28
520.6264648	0.06
547.3284912	0.25
548.0822754	0.04
548.7074585	0.16
552.3199463	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.76
Annotation	Unknow
Peak:m/z	Relative Intensity
199.8489532	0.24
296.7371826	10.83
297.3480835	0.60
298.4218750	3.76
299.0268555	11.36
323.4255981	1.55
324.2018433	2.57
380.6395264	43.28
382.1518555	25.82
382.9016724	47.47
463.4965210	0.75
464.5483398	38.09
465.9538574	51.51
466.6392212	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1455
Annotation	Polygalatenoside D
Peak:m/z	Relative Intensity
145.0260468	0.06
150.1014862	0.02
152.0375671	12.79
153.0661469	6.47
153.9131775	0.71
163.0501709	0.40
163.9154053	0.05
166.9972229	100.00
167.9504395	55.54
169.0565186	6.49
176.7803955	0.07
205.1762543	0.04
205.9773407	0.04
209.1665802	0.42
210.2173767	0.42
211.1478882	0.04
228.9610291	0.04
230.2356720	0.04
243.2512512	0.09
248.1342468	0.17
289.1144104	0.10
307.0726318	0.75
308.2431030	0.79
309.1940918	0.22
349.4020386	0.04
355.0981445	0.16
379.0782776	0.11
386.0266724	0.06
387.2917786	0.02
389.2357483	0.05
398.0312195	0.06
424.4376526	0.07
431.3697815	0.03
432.5221863	0.11
442.3443298	0.10
443.4372864	0.09
458.2704163	0.10
458.9295349	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.71404266	0.64
94.94549561	0.55
96.93502045	0.70
99.03676605	0.21
100.989624	0.21
105.7217865	0.47
112.0468521	0.41
121.1943665	0.66
123.1131592	2.94
124.8442993	0.51
129.0085754	0.84
133.0950928	1.45
135.1516724	0.47
137.0820618	1.75
139.1716003	3.66
141.0452881	0.40
142.8549805	0.91
146.9956665	0.29
147.9705658	0.42
148.8421326	0.80
151.1819458	1.66
152.3786316	0.19
153.1422119	0.29
155.0414124	1.32
157.0489349	0.17
162.9497986	0.69
165.0281677	0.25
165.8787079	0.65
167.1009521	1.69
177.0346375	0.60
178.9264069	0.17
181.2130432	1.56
183.0113525	2.52
184.6170197	0.85
186.182663	0.21
191.0070648	0.76
193.0465393	0.23
195.1006165	0.82
197.2427368	3.71
198.9586792	0.24
203.0978699	0.62
207.4577332	0.85
208.9016418	0.75
211.2245789	4.54
213.2010498	0.85
215.0378723	0.19
217.3816833	0.17
221.0960693	0.77
223.2001038	1.68
224.8510742	2.14
226.2993469	0.17
227.0285645	0.91
229.2795105	0.39
233.1924438	0.98
235.1342468	1.88
239.1694031	1.45
240.9358215	0.71
247.0861206	0.86
248.8119202	0.37
251.0531311	5.26
253.1352844	11.01
255.1042786	0.19
257.1726074	0.90
262.9656982	0.49
264.0216064	0.37
265.3990173	0.45
266.4309082	0.27
267.3787231	1.25
269.0957947	2.01
275.2363281	17.44
277.3773804	0.23
279.2993774	0.30
280.1196899	0.67
283.2011414	6.66
293.2084351	100.00
294.1246338	0.83
295.1335449	0.46
302.2529297	0.69
302.9645386	0.41
311.0978088	0.21
312.3157349	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0563
Annotation	Quinic acid
Peak:m/z	Relative Intensity
58.8649902	1.82
60.8741608	0.75
67.0213623	0.28
69.0888061	0.24
70.8548355	4.14
80.8394012	1.54
82.9428024	1.35
84.9050903	83.14
86.8584595	19.46
88.9536591	0.20
93.0117798	51.11
95.9880371	1.30
97.0045471	0.17
99.0723724	3.51
108.9675598	26.88
110.9788666	36.51
113.1523285	0.36
114.9939270	4.49
126.9385986	100.00
128.8736267	0.59
136.8823242	1.97
143.0799255	4.40
144.6365814	1.16
145.2830353	0.55
147.0842590	0.77
153.1072540	6.19
155.0301056	11.24
163.2927856	0.22
171.0440826	29.60
172.9888153	85.71
191.0864105	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2917
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
149.0616760	0.80
159.6105347	0.55
163.2990265	0.42
180.9083557	0.46
187.1170807	0.98
197.2767334	0.22
215.3256531	0.40
221.1930389	1.10
259.0516663	0.40
282.5726929	0.75
293.1977539	0.98
313.3540649	46.46
344.2877808	0.35
359.4022827	0.85
363.3076477	0.22
393.2126770	6.42
401.1576843	0.87
436.3032227	100.00
437.1756287	1.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.134
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
213.0844879	0.05
254.1158600	0.12
271.9400330	0.32
288.4589539	0.13
289.1969604	0.03
297.1983643	0.06
306.1992188	1.11
324.0694275	0.03
327.3226929	0.06
328.2712097	0.08
339.0127563	0.02
341.4143066	0.04
349.1784058	0.06
357.2242432	0.10
359.1604614	0.16
366.1483154	0.11
371.2132568	0.03
374.9506836	0.05
376.5625000	0.05
380.4763184	0.12
386.2622070	0.13
391.2178955	0.97
395.1700439	0.06
398.2798462	0.10
401.0609741	0.03
403.3551025	0.04
410.1287231	0.03
415.4095459	0.48
417.4525146	0.12
423.2591553	0.45
428.3338623	0.04
431.3541870	0.04
439.2467651	0.08
441.2673340	0.59
449.3471069	0.48
455.6069946	0.05
457.3156128	0.31
467.2974243	2.55
470.2952881	0.18
475.3737183	1.82
481.3552856	0.06
483.0741577	0.06
485.2619629	1.61
488.2327881	0.34
501.3012085	7.07
519.2526855	100.00
525.6326294	0.06
526.4202881	0.08
529.2359619	0.23
530.4552002	0.20
531.3450317	0.43
532.3128052	0.46
543.4102783	0.07
547.6274414	0.04
550.4032593	0.08
553.3236084	0.12
561.3904419	0.18
577.3481445	0.12
585.4976807	0.09
592.1344604	0.12
605.4894409	0.19
615.2648926	0.13
621.5369873	0.18
624.3506470	0.02
637.5925903	0.08
639.2604370	0.18
649.3563843	0.44
656.1924438	0.10
657.5733032	0.24
665.3106079	0.09
666.0414429	0.14
667.6128540	0.10
673.3523560	0.09
674.6359863	0.03
683.2620239	1.32
701.3792725	5.57
725.9660034	0.20
727.1725464	2.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.06121063	0.24
127.1401291	0.10
133.111969	0.38
146.3025818	0.37
154.9549561	0.18
156.2081299	0.12
169.988205	3.90
170.9876099	0.26
176.1022949	0.42
179.1800537	0.24
183.0081482	100.00
184.0782776	15.43
184.9942169	0.91
197.0112305	16.75
198.0906677	4.92
199.0549316	0.44
204.4031677	0.41
205.1157837	0.41
207.26297	0.13
210.0803223	0.55
211.1046143	1.68
211.9998779	3.17
212.7842407	0.80
215.2101746	0.08
225.1371155	2.57
226.0977478	2.26
227.1452332	0.35
231.157959	0.07
236.9550781	0.17
239.270813	3.19
240.2983704	0.29
241.0406494	0.37
246.2519531	0.13
247.2559814	7.30
248.1089478	0.44
249.2922058	1.51
251.2646484	0.70
253.2174683	0.63
254.2626038	0.13
255.2927856	0.46
257.0563354	0.48
264.9953003	0.25
267.3316345	4.77
267.9912109	0.62
269.3970947	0.08
271.0706482	0.15
273.1137085	0.35
275.1713867	0.52
281.3491211	0.66
283.1862793	0.22
292.2171021	0.27
293.3226318	6.71
295.1741333	0.52
296.1690369	0.19
311.3000793	9.74
312.2908325	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0904
Annotation	Glutathione
Peak:m/z	Relative Intensity
115.9629745	0.54
128.0260468	0.01
129.9634552	0.26
134.0407715	0.07
134.9741211	0.02
143.9659729	2.15
145.0744019	0.12
149.7278442	0.03
150.8320923	0.12
162.0433502	23.85
173.0148315	0.07
173.9882202	0.03
178.9825745	100.00
204.8766785	0.05
215.0890503	0.70
216.3099670	0.03
218.0780945	0.23
219.2415466	0.01
233.0377808	16.98
243.3885498	0.13
244.9899902	0.96
272.0798035	1.22
289.1006470	0.66
290.1168213	6.90
291.1351318	1.56
299.1564331	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.0989
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0765076	0.04
173.1555939	0.02
215.1236572	0.03
231.0839844	0.11
245.3278503	0.11
300.4828491	0.03
307.2723389	0.04
309.6383057	0.06
314.2821045	0.04
335.0826416	0.04
341.1179810	0.19
343.0578003	0.22
358.2271729	0.05
359.5067139	0.14
370.8118286	0.04
402.1970215	0.05
405.4385376	0.03
418.1143799	0.80
422.7766724	0.06
428.1774292	1.01
436.6035767	0.08
446.0930176	100.00
446.7587280	0.29
469.1787109	0.13
475.0125122	0.08
477.2749634	0.03
484.7116699	0.22
485.3145142	3.97
489.7525635	0.21
491.9808960	0.05
503.0725708	3.82
503.9638672	0.11
511.2515869	0.28
512.1791382	0.12
520.8593140	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.21
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1474609	0.05
281.0845337	0.05
311.2298889	0.06
323.0231934	0.10
333.1915894	0.05
341.0352173	0.34
413.0479126	0.04
443.1341553	0.23
473.4825439	0.03
503.2633057	100.00
504.1111450	0.05
505.3284302	0.08
518.4378662	0.03
519.5759888	0.08
537.2408447	0.03
549.2268677	0.04
550.0900269	0.15
585.9525757	0.02
587.1264038	0.03
588.2075195	0.64
588.9971924	0.64
617.0903931	0.03
617.7680054	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1617
Annotation	Maltotriose
Peak:m/z	Relative Intensity
159.0675964	0.91
161.0473938	100.00
178.880127	7.42
191.0518341	1.68
221.2787781	1.87
259.9549866	0.66
272.1018372	0.86
280.22229	0.72
290.2596436	1.01
323.0920105	13.16
341.1477661	5.82
351.1819458	1.25
433.1781311	2.00
451.0574036	0.86
457.4168396	4.46
485.3578491	11.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1492
Annotation	Lactulose
Peak:m/z	Relative Intensity
127.0577774	3.50
145.0018463	1.77
159.0379028	0.46
162.8210907	7.68
180.0663452	6.70
180.8935547	0.43
191.1211243	0.28
198.1024170	5.25
214.3225708	0.63
245.8518982	0.45
250.9161987	0.23
253.1176758	0.69
255.1583252	0.52
258.8393555	4.52
259.5765991	1.01
271.1323853	0.28
276.1586304	2.53
276.8359375	8.15
288.9803772	16.33
303.4273071	0.50
305.5730591	0.76
306.4877014	3.38
307.0887451	7.50
311.9177856	0.68
316.1202393	0.25
322.3010254	0.28
322.9846191	0.60
324.2307129	9.94
324.9646606	100.00
336.9087524	0.28
339.8573914	0.30
342.2279358	24.72
343.0036011	79.90
351.6012268	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
117.0816574	0.37
121.1042938	0.28
122.768631	0.55
130.8956299	0.39
132.904068	1.24
135.0153503	0.55
145.0087128	2.40
157.859314	0.33
163.0399628	100.00
173.1561432	0.55
182.1486969	0.30
195.9022064	0.35
198.1959686	0.60
203.0451355	0.95
204.9560242	0.19
206.2768707	1.25
210.0655975	0.21
215.9089355	0.21
219.1573486	0.45
221.1416626	0.36
224.947876	0.35
233.2431335	0.47
234.108429	0.37
234.9301453	0.76
237.2320862	0.55
239.2210388	0.71
243.2070007	0.41
245.2827454	0.30
247.1739807	0.33
249.3780212	0.33
253.3280029	1.67
264.2292786	0.47
265.1484985	0.66
273.1636353	0.94
275.1075134	3.46
277.0333252	1.11
278.2216492	0.71
284.1056519	0.44
291.9704285	0.85
293.0895386	1.98
294.7233582	0.74
295.3513184	0.22
297.2789001	1.91
306.8988647	0.47
309.1203613	1.14
311.1072998	0.48
313.1614075	1.25
313.8716431	2.49
319.1442261	0.80
324.7276306	0.66
325.4238281	0.36
326.7098694	0.90
327.3650818	1.82
332.006958	2.34
334.5608521	0.47
337.0926514	3.90
338.2150269	1.09
355.1306763	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1016
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
98.93701172	0.06
109.0519714	0.13
116.0252075	0.14
117.0212326	0.21
134.0669861	0.04
135.0034943	0.23
140.9179535	0.08
144.9616547	2.78
147.0318146	0.22
156.8755188	0.04
161.2181396	0.18
163.0340576	100.00
164.0393982	0.08
175.0576782	0.05
177.3639832	0.07
179.0393372	0.03
181.1077576	0.05
182.9145203	0.04
187.0577393	0.17
190.8236542	0.06
193.0276337	0.89
201.1233521	0.62
207.0560913	0.08
214.7668762	0.19
231.2860107	0.09
232.7886658	0.06
239.3184509	0.10
248.3095398	0.05
249.303894	0.03
253.3347168	0.08
269.2966919	0.06
277.1967163	0.10
279.0281677	0.09
287.0151978	0.06
288.5491943	0.13
290.4873657	0.06
294.1494141	0.10
295.4464722	0.05
297.0756836	0.41
301.2349243	0.07
308.1925049	0.04
309.3344116	0.44
310.2216492	0.06
311.2964478	0.20
313.7323914	0.10
319.1902466	0.29
322.303833	0.03
323.2321472	0.48
325.2484131	0.14
327.1970215	0.82
335.7957458	0.07
337.1025391	2.18
338.1046143	0.59
339.1424561	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1556
Annotation	Arborescoside
Peak:m/z	Relative Intensity
121.0135956	0.41
122.9076538	0.08
131.0224609	0.22
133.1160126	1.27
134.0547943	0.09
135.0650787	0.22
142.8764038	0.69
144.1253662	0.12
151.2465668	0.73
152.1294403	0.90
152.9676208	0.58
154.0227966	0.29
161.1897888	0.24
163.2052612	0.07
164.2162476	0.08
165.3409119	0.07
175.0918274	0.09
177.1539307	6.15
178.9483948	3.22
179.9559326	0.05
195.1776886	2.84
205.9817810	0.10
207.1294861	0.05
208.1068878	0.23
209.0927124	0.26
210.8919373	0.11
213.2886658	0.06
221.1437073	4.43
225.2546692	0.05
227.1947021	0.21
236.9404907	0.07
239.1709290	5.43
241.1504211	0.30
242.3048401	0.22
243.1040955	0.19
253.3146973	0.04
257.1438904	0.79
257.7638550	0.13
259.2891846	0.07
267.3090515	0.04
268.2065430	0.30
269.3548279	0.16
285.2919312	0.46
286.1114502	0.34
287.2768250	0.08
289.0682373	0.18
293.2530518	0.12
298.3006592	0.03
306.0981445	0.09
310.1762085	0.07
328.2362061	0.12
328.9841003	0.07
329.6282959	0.05
331.1357727	0.12
333.1081543	0.08
345.9753418	0.08
354.9515381	0.14
357.3332214	0.28
360.9341431	0.10
373.1693420	0.31
375.2018127	3.80
380.2419434	0.04
383.2839050	0.23
384.2072144	0.21
389.2720642	0.77
390.7883606	0.38
398.0134583	0.12
399.2381287	0.09
400.0022583	0.10
401.2744141	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.12
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.8779907	1.65
86.8936844	0.05
89.9688568	28.02
94.6472015	0.05
98.0243073	0.19
103.1250610	0.06
115.9709930	4.01
121.9888611	0.06
124.1451874	0.13
126.0560303	0.07
130.9330139	0.22
133.8774719	0.04
135.2190857	0.08
142.0236664	0.14
146.0405121	0.03
147.0635223	0.08
147.9113922	0.05
154.0373688	0.10
156.0350800	0.30
159.9763336	0.08
163.9149323	0.01
166.1006012	1.02
167.3707275	0.08
171.2377167	0.09
172.1075897	0.09
173.4025421	0.27
174.0332336	4.34
175.1552582	0.11
176.0290070	0.15
178.1482391	0.09
179.0379181	0.24
184.0158234	23.93
188.1482544	0.07
189.6652374	0.04
190.7128448	0.19
192.2359314	0.09
196.5483704	0.05
202.0481873	100.00
203.0646362	0.94
210.7546539	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.0862
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0244598	0.09
152.9139557	0.43
160.1210022	1.13
160.9905853	0.26
164.9478302	0.02
166.0684357	0.04
167.2417145	0.35
168.0612335	0.10
169.1645813	0.02
171.0457764	0.43
171.9194641	0.03
176.9940796	1.07
178.0746002	0.02
179.1128235	2.06
180.2137299	0.09
181.0985413	0.13
185.1391296	0.15
186.0749512	0.02
191.1601410	0.04
192.1508789	0.30
193.1351624	0.19
197.0539246	0.34
198.1572113	0.07
202.9493408	0.05
208.9919128	0.03
210.1270447	1.68
211.1262512	0.54
212.2074127	0.23
213.0753784	0.03
219.2657013	0.42
220.0629730	0.07
220.7708282	0.05
222.1916656	0.05
223.0703735	0.07
224.2203674	0.08
226.0401917	0.06
228.2732239	0.39
229.1726685	0.20
230.0402832	0.31
231.0684204	0.11
232.3755188	0.13
236.2263336	0.30
237.1744995	0.57
238.3239746	0.06
242.4477539	0.16
244.2351685	0.12
245.1797485	0.05
252.2386475	0.19
254.1360168	9.31
255.2419281	1.31
256.2413635	0.03
259.9467773	0.09
261.1567383	0.03
262.3176880	0.22
262.9447021	0.04
264.6222229	0.04
265.3140259	0.11
268.5799561	0.14
270.4006958	0.28
272.2120361	5.17
273.1445312	0.80
278.1060791	0.03
279.1653442	0.26
280.3082886	0.14
281.1846924	0.05
284.1879883	0.17
284.8831177	0.04
286.1827393	0.08
288.0967407	6.24
289.2170410	1.44
289.9059143	0.05
291.1723328	0.04
293.2533569	0.03
294.1570435	0.11
297.2877197	0.60
298.0250244	0.07
299.2401123	0.12
301.1679077	0.13
304.1788940	0.19
306.2169189	38.73
307.1671143	3.59
309.3406372	0.08
313.2863159	0.30
315.2435303	0.06
316.0488281	0.05
322.1807251	1.06
323.2128906	0.29
324.2191162	0.08
326.2022705	0.08
327.2622681	0.06
330.2467651	0.16
332.2553711	0.03
333.2009888	0.03
335.3065796	0.39
336.2334595	0.20
338.1283569	0.54
339.2514648	0.16
340.2068481	0.06
341.2800903	0.54
342.0730591	0.19
343.0518188	0.12
345.2911987	0.33
347.3230591	0.12
348.1681519	0.29
350.2838135	0.04
351.2631226	0.24
351.9939575	0.07
353.4041138	0.16
354.2767944	0.69
355.0568237	0.32
355.7430420	0.05
357.2833862	0.61
358.4874878	0.19
359.2009277	0.23
360.2637939	0.35
361.3849487	0.29
364.3792114	0.08
366.0885620	0.48
367.1496582	0.73
368.4284058	0.03
371.3986816	0.27
372.4147339	0.46
373.5376587	0.27
374.2882690	0.39
375.2261353	0.24
376.4019775	0.09
377.3617554	0.40
379.1959839	1.91
380.1840820	0.62
381.9810791	0.23
383.4267578	0.02
385.3002930	0.03
387.0946655	0.22
388.4696045	0.03
389.3018799	0.63
391.1977539	2.08
392.3212891	0.77
393.5536499	0.12
394.4541626	0.11
395.2835693	0.22
396.3312988	0.10
397.5018311	0.57
398.4219971	1.33
399.3410645	0.55
400.2468872	0.51
401.2204590	0.35
403.3764038	0.19
405.0743408	1.01
406.2066650	0.32
407.2211304	0.09
410.2015991	3.67
411.2229004	0.38
415.3140259	1.46
416.4404907	0.70
417.3043213	1.84
418.0148926	0.31
423.2362061	15.07
424.2645264	5.51
426.2861328	0.18
427.0512085	0.39
429.2037354	0.10
431.2415161	0.76
432.5498047	0.24
433.3266602	0.42
435.2246704	9.21
436.2623901	2.90
437.2776489	0.27
438.4577637	0.14
439.4028931	0.21
440.2554321	0.13
441.3167114	4.11
442.2960815	0.63
444.2607422	2.04
445.1152954	0.22
448.5899658	0.25
449.2091064	7.38
450.3069458	2.08
455.2110596	2.01
456.3333740	0.29
457.1851807	0.63
458.2215576	0.96
465.2716675	0.05
467.2406616	57.88
468.2614136	17.76
473.0776978	0.12
474.2788696	0.11
475.3203735	2.43
476.3119507	0.42
483.2744141	6.08
484.1588745	1.64
485.2316284	20.67
486.3565063	5.03
501.1920776	100.00
502.1980591	27.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1395
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
83.1689453	0.07
93.0808105	0.05
96.9694214	0.08
105.1583099	0.02
108.5289993	0.02
110.9575882	0.10
119.0807953	0.49
121.0906754	0.12
123.0976868	5.53
125.0091248	0.23
133.0399475	0.21
135.0929260	0.05
139.2104492	0.19
143.1300964	0.13
145.1184387	0.87
149.1788025	0.16
150.0964813	0.10
151.3151245	0.07
153.0129395	1.52
155.0607605	0.08
156.3086700	0.03
159.1434937	0.46
160.3353271	0.10
161.0641022	0.05
165.2299652	0.03
169.0478058	0.23
171.1730957	9.51
175.0533600	0.32
176.4613953	0.03
177.1672516	0.15
178.1535339	0.03
189.1863098	3.60
192.9780121	0.52
201.1121826	3.73
205.3172607	0.11
207.1990967	6.04
209.2218323	0.02
219.1605530	10.82
234.7214966	0.07
237.1445923	100.00
237.7501221	0.11
263.2151184	0.19
266.1287537	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1969
Annotation	8-Isobutanoylneosolaniol
Peak:m/z	Relative Intensity
128.9847717	0.06
137.0668182	0.08
142.9782410	0.46
146.1426086	0.07
159.1732941	0.10
160.8768768	0.21
179.0351562	0.28
183.1378479	0.06
187.2218475	0.06
197.2293396	0.08
205.1570129	0.20
213.3709106	0.03
215.2209167	0.97
216.3016968	0.04
217.2155914	0.10
222.2182922	0.05
225.1111755	1.00
227.2062531	4.95
229.2359467	3.55
231.1484222	0.16
236.8042603	0.16
243.2289124	0.08
245.2229309	8.94
247.1761475	0.05
254.1312256	0.08
257.2392883	0.47
265.1871948	0.03
271.2472229	3.75
273.2133484	9.09
287.2967529	0.07
288.3250122	0.26
289.2198792	4.14
299.3034668	0.08
301.2652588	1.11
303.1245117	0.10
315.3061523	0.18
329.3870850	0.10
341.1971741	0.72
349.1437378	0.04
361.2915039	0.05
365.2410278	0.13
375.3540955	0.06
389.4381714	0.76
393.4721069	0.08
405.2999268	0.44
407.3220215	100.00
407.9389038	0.45
413.0409851	0.04
414.4611511	0.23
432.7407532	0.19
433.4020081	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1034
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
100.8633118	0.02
114.1958618	0.02
116.0584488	0.04
119.7096100	0.04
123.1206512	0.10
138.0174561	0.40
153.1565704	0.58
165.0940552	0.05
167.0712738	0.15
179.2852020	0.02
180.0310822	0.11
182.1066132	4.96
197.0359497	100.00
209.1525879	0.03
217.1535645	0.02
225.1284180	0.03
226.2799072	0.05
237.5651550	0.02
251.2263489	0.03
263.4111328	0.01
270.9403687	0.02
284.3494873	0.02
289.1669006	0.01
298.0875244	0.16
298.6974792	0.04
299.3759766	0.07
311.2117920	0.03
313.5143433	0.07
315.4307861	0.02
324.5085754	0.02
325.3147583	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9198
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9175110	3.77
159.9655457	0.36
199.0944519	0.50
199.9563293	0.16
217.1388092	0.15
228.8870392	0.43
230.1468811	0.51
271.1388245	0.05
273.0082397	55.93
274.0246887	17.18
289.1426392	0.04
370.9915771	0.13
385.2260437	0.42
386.9740295	100.00
387.9826355	49.54
388.5918274	0.12
427.0938721	0.14
427.9042358	0.06
445.9893799	0.18
455.2152710	0.12
455.9786987	0.08
484.0627136	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.2349
Annotation	Unknow
Peak:m/z	Relative Intensity
204.9825745	0.63
209.0600128	0.52
215.1963959	0.40
219.2011719	1.99
221.2744446	0.72
229.2336731	0.23
232.9199829	0.58
242.9506836	0.42
245.1432495	14.12
246.1404877	0.57
247.2582703	2.84
248.1124268	1.01
262.8527527	1.19
265.0597534	17.94
266.1068726	1.66
269.0938110	0.37
271.1916809	0.35
275.1259155	0.60
277.2992859	0.39
283.1667480	6.35
284.1636658	0.90
287.1523743	1.65
289.2765808	3.46
290.3396301	0.24
293.7128906	0.49
294.7518311	0.52
295.4461365	0.19
305.1909180	27.89
306.2434082	2.00
309.3390808	0.25
311.1278687	0.29
317.3441772	1.58
319.4063110	0.82
321.2053528	1.38
322.1671753	0.70
323.4063110	0.82
329.3132324	1.16
337.1693726	10.01
338.3102417	0.78
341.3513184	0.66
347.3007812	0.41
349.1545105	1.19
350.5306396	0.29
351.5017090	0.42
358.1716919	0.13
359.1678162	0.13
360.8203125	0.08
361.4315186	0.31
362.3432007	0.32
371.1768188	0.17
371.8577271	0.78
374.9283447	0.12
377.1395264	2.75
377.8377075	1.08
378.6316528	0.37
383.0488281	0.89
391.0222778	0.49
395.2633057	0.57
397.3139038	19.09
398.2766724	2.73
401.1721191	0.70
403.0959473	0.95
404.5192261	0.27
409.2513428	0.95
415.2617798	10.27
416.4614868	0.37
419.4340820	0.22
433.5481567	0.47
436.6984863	0.43
437.3395996	1.75
449.2736206	13.98
450.2376099	1.67
451.1964111	0.53
453.5467529	1.62
454.2590942	1.08
455.1784668	0.81
455.9731445	0.31
457.3182983	0.37
460.9494019	0.11
468.0452271	1.05
469.2990112	1.05
473.2475586	1.78
479.1352539	0.57
481.2337646	6.82
482.4995117	0.65
485.3612061	3.94
491.2170410	4.48
492.5981445	0.12
494.3845825	0.14
495.0986938	0.16
507.3522339	0.24
509.3472290	3.62
510.6750488	1.10
511.3082275	5.59
512.4868164	1.24
523.2402344	0.18
526.3765259	0.09
527.4315186	0.34
529.3212891	10.97
530.4158325	3.18
537.3488159	0.69
538.3950806	0.32
543.4194336	0.61
545.5144043	0.22
555.2814331	3.57
556.3513794	0.59
561.1041870	2.54
562.3941650	1.59
573.2001343	0.32
574.3862915	0.23
575.3550415	0.92
576.2625122	0.38
587.3781128	0.67
603.4144287	0.42
605.3328857	9.15
606.0854492	0.28
607.5664673	0.21
627.1663208	0.31
646.2573853	0.51
658.3286133	0.31
659.3959351	1.28
661.3894043	39.43
662.3663330	10.61
675.2875366	0.18
677.2739868	10.20
678.3460693	1.56
687.0249634	0.17
693.3806763	7.46
694.2726440	0.76
705.3819580	100.00
706.3494873	22.87
719.4096069	5.07
720.1336060	1.73
720.8799438	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0927
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
108.8811798	0.03
110.7865067	0.02
119.0271759	5.85
129.0310974	0.03
155.0932617	0.69
163.0020752	100.00
173.0797119	3.79
191.1357727	8.16
216.9096069	0.03
273.2346802	0.02
291.3448486	0.04
292.0332642	0.01
293.0103760	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.0972
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0856476	0.03
158.9676819	0.04
160.0854492	0.60
167.1898193	0.05
168.0507507	0.06
169.1438904	0.05
169.8884277	0.03
171.0310059	0.17
179.1784821	0.70
185.1669312	0.66
188.1595001	0.02
192.1119995	0.12
192.8969421	0.03
196.0781860	0.37
197.0186005	0.19
202.3819580	0.11
203.0820923	0.03
210.2272339	0.75
212.0870209	0.09
219.1195068	0.06
227.2615967	0.05
228.0957031	0.08
230.0036469	0.48
231.3207397	0.09
234.3736725	0.04
236.1114197	0.30
237.1862335	0.14
239.2788239	0.05
242.0970764	0.20
244.5800781	0.10
252.2684021	0.12
254.0714722	4.06
255.3304443	0.27
259.3406372	0.06
260.4376221	0.05
262.3966980	0.21
263.3387451	0.11
270.5371399	0.12
271.1857300	0.15
272.1301880	0.76
273.0577393	0.04
279.0961914	0.03
280.2752686	0.36
281.0039673	0.49
288.2047729	5.08
288.9393311	0.15
294.1997375	0.05
295.0098267	0.03
296.9176025	0.38
306.1540527	11.53
310.1996460	0.22
315.1185303	0.46
316.2643433	0.07
319.3861694	0.04
320.2188721	0.03
322.3203735	0.07
323.4246826	0.07
331.0689087	0.05
332.4083252	0.18
335.4469604	0.04
336.1724854	0.03
337.8853760	0.08
340.2790527	0.16
345.2390747	0.27
348.1828003	0.10
350.1918945	0.05
351.4277954	0.06
354.1914062	0.72
356.3249512	0.15
357.3789062	0.06
358.2560425	0.04
359.1273804	0.11
361.3927002	0.06
363.3859863	0.33
366.3190918	0.91
367.4582520	0.04
371.1889038	0.05
372.3245850	0.03
374.5456543	0.18
375.2159424	0.52
377.2932129	0.28
379.1972656	1.52
380.2081299	0.12
381.2505493	0.32
382.4272461	0.10
389.2381592	2.40
391.5007935	0.06
392.1931763	0.10
397.3990479	0.48
405.3130493	0.46
407.2999268	1.65
409.4021606	0.73
410.2669067	0.05
411.3106689	0.18
413.2546387	0.16
415.1428833	0.26
416.2841187	0.21
417.2568359	0.08
418.2292480	0.04
423.2045898	13.80
423.8352051	0.01
425.3249512	0.07
426.4420776	0.04
428.1894531	0.81
429.4461670	0.21
431.3679810	0.14
433.2196045	2.75
434.9834595	0.05
437.3114014	0.04
439.3057861	1.08
441.1926270	23.20
441.8466797	0.13
450.1634521	0.07
451.3408813	2.65
455.2368164	0.07
457.3424683	7.09
459.2960205	1.72
462.1796265	0.35
467.2247925	3.86
469.2824097	0.31
473.1375732	0.72
473.7694702	0.03
475.2435303	86.00
483.8313599	0.06
485.2015991	100.00
485.8587036	0.48
491.2830200	8.29
492.2940063	0.13
493.3457642	3.85
501.3468018	1.38
503.2913208	44.01
507.8961792	0.06
509.0254517	0.08
519.2547607	26.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2339
Annotation	Dihydrobuddlenol B
Peak:m/z	Relative Intensity
165.1366119	0.24
174.3735046	0.03
177.0778656	0.11
179.1671295	0.46
181.1434021	0.19
187.8403015	0.10
190.0564880	0.06
191.2850494	0.02
193.9624329	0.13
195.0903168	1.41
203.1495056	0.06
209.4380798	0.03
212.0938721	0.04
222.1130676	0.32
223.0736084	0.06
227.0621948	0.08
233.0305023	0.03
263.2377319	0.02
295.2415161	0.21
311.3142700	0.25
317.9614868	0.02
325.4960938	0.20
326.2839966	0.33
327.3475952	1.08
330.3599854	0.03
341.3535767	0.05
343.2791748	0.07
345.2149048	5.84
354.4002075	0.04
355.8342285	0.08
357.1694946	5.57
358.5371704	1.76
359.2780151	16.75
369.1405029	0.96
370.1886597	0.88
371.1270752	0.11
373.9829712	0.02
375.2557373	1.32
377.3856201	0.02
381.3033447	0.04
385.0386963	0.06
387.2683105	1.63
388.1358032	0.73
389.1091309	1.54
401.1889038	0.04
405.0368652	0.05
423.5558472	0.02
424.4730225	0.08
429.5073242	0.04
431.3899536	0.10
433.2864990	0.04
442.0869141	0.07
447.4696045	0.03
451.2159424	0.06
475.5377808	0.06
476.4085693	0.03
489.7622681	0.08
507.1522827	1.66
507.7853394	0.09
517.3254395	0.08
522.4226074	0.09
535.6151123	0.80
537.2578735	100.00
537.9302368	0.32
538.9073486	0.07
540.3185425	0.16
546.7291870	0.08
547.4963989	0.05
548.4584351	0.03
549.5159302	0.26
553.4644775	0.24
554.7865601	0.21
555.4064331	0.49
563.7924194	0.04
566.0314331	0.71
566.6920776	0.14
567.3812866	2.90
570.3546753	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.2761
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0747070	0.10
214.2553406	0.11
229.0725250	0.13
231.4083252	0.05
249.0925598	0.24
252.2524109	0.02
262.4246521	0.03
264.9161987	0.10
272.4269409	0.02
279.4534912	0.09
321.3249512	0.07
322.0203247	0.04
323.4095459	0.03
325.3827515	0.03
337.3024292	0.37
347.5243530	0.04
364.0474854	0.12
365.2583618	0.09
373.3687744	0.18
374.0942993	0.02
376.0165405	0.02
382.3549194	0.08
383.3278198	0.03
387.2839966	0.06
391.4379272	0.03
394.7322388	0.15
401.2364502	0.06
404.0637817	0.05
406.7635498	0.15
413.1011353	0.09
415.6633301	0.09
423.2105713	0.04
429.0973511	0.05
431.2701416	0.04
433.2970581	0.10
435.0009155	0.05
439.3059082	0.04
442.7537842	0.06
449.4744263	0.05
461.2288208	0.99
472.8578491	0.03
477.4529419	0.09
487.3458252	0.12
488.9375610	0.02
491.5181885	0.09
497.4481812	0.05
507.1353760	0.74
509.1329346	0.02
517.7491455	0.03
519.2785034	0.09
520.6270752	0.08
521.2271729	0.16
530.9852295	0.11
534.2083130	0.12
551.3419800	100.00
553.1694336	0.32
559.3204956	0.05
561.1605835	0.06
565.5623779	0.02
567.6721802	0.04
574.6596069	0.11
576.9420166	0.16
579.1265259	1.10
580.1336060	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	811.3166
Annotation	Unknow
Peak:m/z	Relative Intensity
251.2436829	0.07
264.2245483	0.08
301.6382751	0.05
313.1724243	0.06
325.7730408	0.08
339.4017944	0.04
340.1110229	0.14
343.3419800	0.27
344.2088623	0.29
357.4633789	0.19
358.3802490	0.12
370.5245361	0.11
371.1990356	0.06
373.0941772	0.60
374.3661499	0.22
375.2665100	0.66
385.2839966	0.09
386.5812988	0.59
387.2905273	0.81
388.2899170	1.36
389.3132935	1.52
390.3281250	0.53
398.2188110	0.32
399.5139160	0.14
401.3802490	0.39
403.3811035	0.36
404.3561401	0.15
417.1775513	0.16
418.1285400	1.11
419.2372437	0.20
421.1282959	0.17
422.0924683	0.26
422.8119507	0.06
423.6799316	0.04
429.3317261	0.23
430.4632568	0.23
431.2379761	0.20
442.8833618	0.37
443.5336914	0.35
444.3902588	0.30
458.1520386	0.12
459.4341431	0.19
461.4851074	0.10
462.3978271	0.08
471.1641846	0.12
473.0927124	0.11
473.9983521	0.33
491.1076660	0.14
523.6103516	0.19
537.3499756	3.72
538.3495483	0.66
548.4285278	0.17
549.2001953	0.13
550.7644043	0.10
551.4363403	0.07
553.3203735	0.32
556.9791260	0.16
564.0994263	0.11
565.5037231	2.08
566.6933594	1.62
567.4996948	6.66
568.4636841	2.11
571.5142822	0.22
575.4086304	0.08
582.0441895	0.11
583.3017578	1.43
585.2281494	4.04
586.1721802	0.76
595.3312988	2.92
596.3007812	2.01
597.4063110	3.22
598.6046753	0.80
599.4915161	0.21
601.3039551	0.29
602.4866333	0.10
609.4043579	0.34
610.6808472	0.21
613.4102173	8.81
614.2630615	8.78
615.3067627	11.94
616.3417358	0.86
621.3025513	4.30
622.3363647	0.70
629.5652466	0.20
639.5673218	0.59
640.6763916	0.05
641.8375854	0.07
651.3200073	1.36
652.7410278	0.04
657.1837769	0.24
658.1964722	0.03
669.2299805	14.19
670.3906250	3.09
685.4025879	0.10
686.5347290	0.09
687.2373047	6.83
688.4129639	0.71
697.6130981	0.29
698.7306519	0.20
715.3987427	12.74
716.5044556	3.25
727.3507690	0.57
728.3048706	0.62
731.5136108	0.22
743.3021851	0.09
745.3385620	43.72
746.4038696	11.48
747.0095215	0.06
757.3361206	0.93
758.4207153	0.37
761.3551636	0.11
763.3092651	58.11
764.3062134	14.63
764.9486694	0.19
775.3372192	38.52
776.4505005	10.62
781.3070679	1.04
782.5121460	0.11
793.3112793	100.00
794.2620239	30.08
794.9299316	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2915
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
141.8867035	0.06
149.0157776	0.19
154.8831635	0.37
163.4585266	0.16
175.0583954	0.12
179.0892181	0.06
183.0649414	0.30
184.9802246	0.15
187.1350555	0.16
189.2285767	0.18
191.1948547	0.10
195.2355042	0.17
198.1068726	0.44
207.2960510	0.36
215.9927063	0.13
231.9944763	0.10
235.2645264	0.47
245.3009033	1.51
249.3873901	0.23
256.1337891	0.13
262.9197998	2.25
263.5272217	1.64
279.3605652	0.10
288.4453125	0.13
306.4117737	0.77
313.3952026	0.06
319.3297729	0.65
321.2756958	0.11
324.6139832	0.09
328.7776794	0.20
330.5404053	0.27
332.9264832	0.08
333.9822998	0.10
335.0705566	0.17
337.2970276	67.08
337.9492493	0.11
347.3533630	0.10
351.2774658	0.08
361.1821899	0.09
364.6800232	0.21
375.4153748	0.22
380.5610657	0.37
407.0781860	0.19
415.1264343	0.12
417.2561340	4.45
418.9264832	0.09
419.5782776	0.18
422.1776123	0.13
432.7245789	0.06
435.1786499	0.69
441.4924011	0.22
445.8491821	0.09
446.4512024	0.17
447.4761353	0.23
450.9915466	0.09
455.5397949	0.14
460.3612366	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.169
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.94967651	0.42
96.89897156	1.24
98.97583008	0.45
119.0823212	0.33
132.0769806	0.09
168.9709625	0.15
169.9761658	3.81
171.030777	0.64
183.0044556	100.00
184.0900879	9.58
197.0587769	7.72
198.0583496	8.85
198.9981842	0.35
207.1326904	0.24
211.1681824	0.88
212.1465454	1.05
213.085907	0.09
223.3859863	0.09
225.0677185	1.56
226.0711365	2.22
226.9292603	0.26
239.3257141	4.47
240.1635437	1.05
241.0777588	0.34
247.3498535	5.29
248.3931274	0.67
249.334137	0.32
251.4656067	0.35
253.162384	1.85
254.0992126	0.70
254.987854	0.40
265.3470764	0.34
266.3205566	0.11
267.3417664	1.41
269.3518982	0.15
275.3661499	0.18
277.1870422	0.35
283.006897	0.09
283.616394	0.23
292.4656067	0.65
293.2154236	4.09
294.5133667	0.26
295.7045288	0.51
296.6053467	0.09
311.3223572	11.39
312.3544922	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368
Annotation	Unknow
Peak:m/z	Relative Intensity
144.6413879	0.16
146.0735321	0.09
155.0817871	0.06
156.0220947	0.33
158.0295715	0.13
174.9642639	0.42
180.9059448	0.13
187.0464325	0.13
196.1387177	0.06
198.5400696	0.20
202.0064545	0.28
206.0275421	0.20
213.5636597	0.14
216.0759735	0.19
218.1362610	0.34
226.1526489	0.14
234.0539856	3.24
236.0061951	0.07
239.8402405	0.35
243.9686584	0.27
247.1184082	0.73
247.9496765	1.88
252.0480652	0.10
254.1906738	0.08
259.1028137	0.49
262.0902100	0.71
269.8659363	0.15
277.0685120	3.04
278.0410156	13.94
279.1014709	0.08
287.2940979	0.18
288.0950317	0.13
292.4676514	0.05
301.9294128	0.30
305.3400879	0.38
306.1907654	0.49
307.1437683	0.26
307.9447327	0.72
309.0532227	0.05
310.0704346	0.27
319.2940674	0.52
321.1095581	0.10
322.2330933	0.62
324.0366821	100.00
332.1383667	0.37
333.5867615	0.18
341.9422607	0.06
349.1448059	0.50
350.0995178	2.26
359.3120422	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.1484
Annotation	Unknow
Peak:m/z	Relative Intensity
231.1116638	0.14
244.0940552	0.08
245.0664978	0.06
259.0812683	0.04
260.2143555	0.06
261.6493530	0.15
272.3328247	0.03
279.0708618	0.17
280.0160522	0.06
288.2000732	0.11
294.0031738	0.03
299.7802734	0.06
306.1813965	0.42
314.1581116	0.05
321.0886230	0.04
332.2017822	0.16
339.0972290	0.15
340.3201904	0.07
341.3375854	0.05
345.3685303	0.11
347.1438599	0.10
357.1013489	0.43
364.5866699	0.04
366.1078491	0.38
366.8329468	0.05
373.9227905	0.04
375.1691895	0.39
383.2229614	0.03
384.3717041	0.04
385.2902222	0.04
391.9569092	0.07
394.4364014	0.17
400.2938843	0.49
402.2269897	0.18
403.6516113	0.27
408.3935547	0.26
409.2415161	1.33
411.2893066	0.14
416.4002075	0.14
418.2218628	0.26
424.2288208	0.04
428.2529907	0.45
430.2875366	0.09
442.2559204	0.16
461.2070312	0.08
462.0839844	0.21
475.5180664	0.11
479.4280396	0.07
480.3715210	0.09
483.8624268	0.19
486.3440552	0.24
487.3597412	0.29
491.1478271	0.21
504.3894043	0.40
512.2467041	0.18
513.4394531	0.16
515.3751831	0.09
518.1680298	0.12
519.3704834	0.03
520.3522949	1.30
521.4368896	0.18
524.0168457	0.04
529.0960083	0.14
533.5859375	0.05
535.1834717	0.08
536.1651611	0.10
537.6360474	0.77
538.2444458	6.52
539.4082642	0.26
540.4799194	0.31
541.3453979	0.12
542.5142212	0.06
543.4738159	0.07
544.2708130	0.16
548.3778687	0.05
552.2784424	0.03
554.0873413	0.05
554.7620239	0.26
555.6943970	0.13
557.0680542	0.06
558.0868530	0.03
560.4700928	0.05
561.4045410	0.05
564.3709717	0.04
565.4078979	0.08
567.1196899	0.10
571.2069702	0.37
575.1167603	0.03
577.4156494	0.36
578.2980347	0.19
579.1566772	0.09
585.4904175	0.18
586.3389282	0.29
588.2994995	0.04
589.1261597	0.06
594.5272217	0.14
595.2875366	0.05
596.9927368	0.03
598.2365112	0.33
603.2354736	0.16
604.6104126	0.06
607.1933594	0.23
608.3652344	0.03
610.5943604	0.23
611.2600708	1.76
612.4558105	0.07
617.7341919	0.22
621.2877808	0.87
622.1252441	0.08
624.2797241	0.32
628.3994141	0.15
629.4389038	0.24
634.4459839	0.05
637.3522339	0.42
639.2423706	1.14
640.2688599	0.27
641.3232422	0.47
644.1517334	0.11
645.6895752	0.35
647.4016724	0.05
650.2299805	0.05
653.3046265	0.22
655.2947388	9.85
656.1941528	0.10
657.2399292	0.03
658.6123657	0.23
660.2418823	0.36
665.3966675	0.49
666.4459839	0.08
667.4510498	0.16
668.5134888	0.07
671.3078613	0.70
672.8554688	3.84
673.4588013	12.25
679.3704224	0.27
681.0490723	0.10
683.3721924	0.30
684.0493774	0.30
687.6697388	0.31
688.8393555	2.68
689.4672852	2.35
690.3960571	0.19
691.2493896	0.92
693.3114624	0.18
694.3157959	0.41
697.6983032	0.13
699.0649414	1.89
699.9039917	0.20
701.3992920	0.10
705.6154175	0.74
707.2372437	100.00
707.9206543	0.28
709.3505859	4.72
715.6129150	0.37
716.6972046	3.99
717.4077759	17.25
722.1983032	0.10
723.3416138	1.10
724.3377075	0.84
725.5317993	1.08
733.2288208	2.40
734.0438232	0.50
735.2973022	8.79
736.1975708	0.13
737.1470947	0.14
747.4266357	0.13
750.3759766	5.21
751.3536987	25.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.69
Annotation	Unknow
Peak:m/z	Relative Intensity
291.6575317	1.09
375.0549927	1.09
458.6585693	3.33
459.6089478	9.31
469.4057617	0.80
480.9042969	1.58
520.7675171	0.70
542.5770874	31.15
543.6826782	100.00
579.7244263	0.94
581.2877808	4.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	878.58
Annotation	Unknow
Peak:m/z	Relative Intensity
290.8628540	3.58
292.8685608	1.34
374.5622559	0.44
396.9351196	0.35
458.6281128	14.89
539.8606567	1.68
542.6430664	74.00
624.0633545	0.96
625.3481445	0.82
626.5811157	27.96
709.2473145	0.35
709.8800659	0.56
710.4812622	48.26
748.8939819	2.46
794.4207153	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9366
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8839569	0.44
130.9414673	1.94
147.0002441	0.91
158.8775635	7.66
174.9229431	100.00
175.6779480	0.02
198.8305054	0.07
215.3262329	0.23
232.9052124	0.48
243.1417236	0.07
244.9400024	27.72
261.0176392	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.21
Annotation	5-Megastigmen-7-yne-3,9-diol 3-glucoside
Peak:m/z	Relative Intensity
107.0316238	0.08
110.9417648	0.07
122.9859619	0.05
131.0802155	0.14
132.9636230	0.98
133.9622955	0.07
135.1928406	0.11
136.9361877	4.31
149.1835938	0.17
151.0726166	1.50
152.2078247	0.08
157.0088196	0.32
162.8208771	0.28
167.0242615	9.47
172.9857788	0.20
173.7824707	0.12
175.0739441	1.97
177.0758667	1.45
179.0773010	0.85
181.0392151	0.43
183.2605743	0.22
187.0559845	1.53
189.0321045	0.91
191.1156769	1.44
192.0595856	1.19
193.1734619	0.99
194.8636627	0.91
196.9643555	0.15
199.0775604	0.91
200.9703369	0.17
205.0702820	0.58
207.1779022	0.84
209.2636108	10.55
215.0406036	1.87
217.0580444	14.93
219.2809143	0.78
220.9868774	0.49
228.9603882	0.11
232.9753113	0.11
235.1494141	1.53
237.0421753	0.14
239.2755127	0.26
241.1753235	0.09
247.1147156	14.75
255.2503357	0.21
256.5139160	0.10
259.1658325	0.15
260.9313049	0.37
265.3063965	0.37
269.2679138	0.16
270.3531799	0.25
272.4997253	0.51
277.0002747	0.07
281.1231384	0.81
283.2705688	0.75
285.3563843	0.42
289.0979004	0.86
293.3065491	1.68
294.0413513	0.10
297.3200989	0.20
301.1726685	16.99
305.1121521	0.68
306.1661377	0.14
307.9064941	0.17
309.2528076	4.67
311.2423096	0.67
313.2387695	0.37
315.3880615	0.83
316.6816101	0.30
321.2353821	17.38
322.9504395	0.27
325.0302124	0.54
326.1714783	0.31
327.0793762	0.37
335.3588562	0.45
336.2606201	0.08
339.1332092	6.22
341.1171875	43.64
343.1208496	3.33
353.2612305	100.00
356.1389771	0.25
362.1899109	1.58
362.8127441	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.15
Annotation	Gerfelin
Peak:m/z	Relative Intensity
165.1132355	0.06
173.0032043	0.09
175.0848541	0.09
179.0783997	1.18
186.1000061	0.10
187.0215759	0.60
187.8708954	0.11
191.0832520	1.69
203.1670532	0.64
205.0446167	2.63
210.2099609	0.05
210.8860168	0.09
217.2176514	0.34
223.4610138	0.20
231.0452118	0.14
235.0798035	0.18
245.1809540	8.36
247.1335602	0.94
255.0012360	0.07
265.3052979	0.06
271.4496765	0.31
273.1162109	0.22
287.1611328	0.37
289.1278687	100.00
290.0032959	0.16
291.2202759	0.51
299.2208862	0.09
301.0831299	0.13
302.3178101	0.09
307.9248657	0.07
311.1507568	0.14
313.6524658	0.14
315.8918457	0.10
323.4246826	0.18
324.6838989	0.11
327.4716797	0.28
328.4465942	0.10
331.2230835	0.87
333.3457642	0.10
335.3988037	0.10
337.0289917	2.21
342.0889282	0.08
343.2041016	0.32
361.5056763	0.15
369.1118164	0.25
385.3889160	0.07
391.3588257	0.28
398.2122192	0.06
401.5205078	0.08
403.4066162	0.09
404.1147461	0.04
405.3859863	0.35
407.2299805	0.04
408.3668823	1.38
409.4446411	0.46
411.2443848	0.36
417.3404541	0.08
423.6426392	0.20
425.2510986	0.90
426.4151001	2.19
427.3608398	0.98
434.1755981	0.24
440.0554810	0.11
450.3495483	0.19
451.2786255	1.07
452.1577148	1.67
453.6207275	0.29
458.4143677	0.07
461.2004395	2.24
461.8023071	0.11
463.2379150	0.10
465.7764282	0.24
469.2238159	1.50
473.1975708	0.27
475.2678223	0.19
482.4820557	0.17
488.2764893	0.08
489.3185425	0.15
491.3550415	0.24
492.7089233	0.17
493.4722290	0.08
500.9962769	0.11
501.9277344	0.27
503.4649658	0.06
516.3355103	0.37
517.5736084	0.13
521.0920410	1.02
524.3645630	0.04
530.7626343	0.28
532.0702515	0.53
533.2650757	6.90
533.8894653	0.12
535.2515259	0.51
535.8730469	0.26
538.2526855	0.15
547.7592163	0.21
556.2530518	0.38
557.2926025	0.17
559.4195557	0.19
560.3460083	1.33
561.3430176	1.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.2136
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
178.9801025	0.10
199.1504211	0.25
207.2275696	0.14
214.2292328	0.12
217.0431519	0.14
234.9517670	0.11
341.2338257	0.10
346.6948242	0.07
353.4926147	0.17
355.3590088	0.08
369.0878296	0.11
372.3091431	0.17
381.8466797	0.29
387.3227539	0.57
389.1936646	0.11
402.4664917	0.12
411.9000854	0.13
417.2827759	100.00
420.0813599	0.08
423.3183594	0.18
424.3587646	0.12
428.1901855	1.03
429.4635620	0.75
431.1346436	0.14
432.4579468	0.42
433.2707520	0.25
437.4772949	0.10
441.1105957	0.27
443.3360596	0.12
457.3267822	0.11
459.6313477	0.05
461.3384399	0.10
462.0549927	0.37
463.4262695	0.51
471.6864624	0.19
477.4795532	0.08
479.5310059	0.16
480.7355347	0.31
500.5454102	0.08
517.2427368	0.08
529.7358398	0.09
534.8176880	0.08
550.5547485	0.14
551.5814209	0.13
553.3870850	0.06
563.4390259	0.19
565.2760620	0.30
578.7764893	51.89
579.7061157	0.52
580.4078979	0.09
593.5024414	0.14
594.9279175	0.12
605.2858276	0.05
606.9775391	0.68
607.6228638	0.77
608.5112305	0.24
610.3478394	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9321136	5.87
212.9541473	3.99
218.9360657	0.37
221.2208557	0.07
239.2287903	0.20
241.0997925	0.11
261.1479492	0.20
268.1060486	0.18
270.2248840	0.16
271.4220886	0.36
279.0576782	0.20
294.3959351	0.07
296.7587891	100.00
297.4260864	0.30
312.4305420	0.06
341.2812805	0.12
363.0567322	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0772
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.1464081	0.10
109.0541534	0.15
110.9854202	2.33
114.9078293	0.11
118.8272705	0.10
133.0223694	2.99
133.9657288	1.48
135.0117798	28.32
137.0361023	10.53
147.0869446	0.09
148.9767456	0.07
151.2865601	0.06
155.0539246	3.97
157.0652466	0.05
159.1419983	0.64
160.9931335	78.82
163.0570374	0.13
164.1371307	0.11
173.0483856	2.82
175.0722504	0.33
177.2970886	1.16
178.1028748	1.86
178.9976959	100.00
188.0045013	0.06
188.9751587	0.08
196.1234436	0.10
199.0382538	3.50
201.1730652	0.18
203.2637329	0.22
207.3171692	0.06
210.5583496	0.17
211.2008057	0.54
215.1960449	0.14
219.1943665	0.09
221.0166321	0.32
229.1503296	2.09
231.0735474	0.11
233.0157776	0.18
237.1958923	0.19
240.1607056	0.12
243.7960205	0.06
247.1945801	3.60
253.1572266	0.10
255.1974487	2.51
273.0881958	1.00
275.3422546	0.07
289.1140747	39.55
291.1705933	30.07
299.3144531	0.97
307.6128845	0.12
317.2214050	4.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1014
Annotation	Scopolin
Peak:m/z	Relative Intensity
107.0879059	0.02
117.0097809	0.36
135.0771179	0.46
145.0419922	3.05
146.8524170	0.01
156.9246368	0.02
162.9517975	100.00
180.2792664	0.02
181.1350250	0.04
192.0407867	0.01
192.9794159	0.24
221.2791138	0.02
297.3788452	0.01
300.9548950	0.03
326.2713013	0.09
327.4132690	0.02
337.1228027	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1871
Annotation	Isosyringinoside
Peak:m/z	Relative Intensity
160.8238068	0.24
162.9883270	13.04
164.4202271	0.05
179.1107788	3.55
187.2098999	0.05
205.0234680	0.73
211.2650757	0.09
228.8694458	0.08
234.3516846	0.05
247.1176910	1.29
249.1711121	0.03
289.0709229	2.31
289.9104919	0.19
298.6414795	0.05
307.1644897	100.00
353.0174561	0.54
471.2707520	0.09
481.4549561	0.06
486.8604126	41.81
487.6784058	0.09
499.1694336	0.07
512.9347534	0.38
515.0311890	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0754
Annotation	Sinapic acid
Peak:m/z	Relative Intensity
67.04176331	0.01
99.1522522	0.01
105.1115723	0.05
107.1512299	0.02
130.8667603	0.03
137.1639099	0.04
146.8247833	0.03
149.1426086	0.02
155.0983124	0.01
165.2412872	0.01
175.1408997	0.03
179.1051178	0.02
181.0146484	0.33
183.0583344	0.26
183.6863861	0.03
192.8966217	0.01
194.2447662	0.02
195.2144623	0.23
207.0587616	100.00
208.0084076	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.20442963	0.94
81.13894653	1.09
89.09912872	5.40
95.02124023	2.59
97.0135498	1.96
98.77682495	2.09
102.9802551	4.00
105.1641846	2.94
107.1621094	4.86
109.0197144	9.10
113.127655	1.47
114.8399048	3.19
121.0261841	4.05
123.1629486	4.03
125.2723846	1.88
128.8096771	8.57
133.0714569	10.31
134.9842682	1.63
137.0620575	4.30
139.1820679	2.27
140.8061218	8.70
142.6260071	2.18
149.1074371	3.50
151.0335541	88.14
153.1702728	4.94
154.9216461	4.11
157.1731873	2.18
161.2154541	7.16
162.2182922	4.87
165.1203918	1.49
167.1132965	2.01
169.1404877	0.71
171.1996002	2.49
174.9264832	4.44
177.2687836	4.27
178.2724762	4.93
179.2189941	6.81
181.3049774	1.89
183.0007782	7.47
189.3127899	2.54
193.0959473	3.56
195.0408173	17.26
197.1316223	9.64
199.2550507	1.87
207.072464	11.31
209.1893005	8.60
211.0440216	18.25
217.1297913	20.67
221.0522461	5.77
225.0941925	29.42
235.1877899	100.00
236.1977386	2.26
237.9496918	15.24
243.6609955	6.99
253.0818634	92.69
254.2032623	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.17
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
118.91185	1.20
123.3353729	0.52
125.3219147	1.08
131.1781464	1.82
134.0075684	0.86
151.4259338	1.72
161.1915131	0.83
162.6595764	0.84
169.966095	8.78
181.1074219	0.79
183.0114746	100.00
184.0267487	22.79
197.1583252	13.16
198.1338806	5.84
211.0870056	5.13
212.1398926	1.18
223.2904358	2.43
226.1444397	0.74
227.2236328	0.77
236.816864	1.22
239.2041321	3.45
240.1373901	1.54
246.2975769	0.89
247.2721252	8.23
248.5310059	2.27
249.3616943	9.66
251.2713623	1.95
253.32547	0.41
254.963562	0.80
262.3070679	4.32
267.2857666	18.19
268.1911621	1.00
269.4442139	5.93
271.4122314	1.02
275.1516113	0.40
281.602356	0.75
282.5187988	0.56
291.3484497	1.75
293.3420715	40.38
295.4187317	1.37
310.4665222	1.71
311.3149719	13.30
312.253479	5.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.203
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
151.2782288	0.10
171.1169891	0.58
203.1085815	0.14
236.5924377	0.19
287.9902954	0.34
311.1107178	0.46
311.9177246	0.42
313.3932495	0.19
315.1757812	30.09
329.2760010	39.19
341.3879395	0.08
342.1536865	0.41
346.0261230	0.47
352.4979248	0.45
359.0112915	20.26
359.7459106	0.37
371.2873535	4.38
375.4293823	0.16
387.3948975	0.07
389.3534546	11.39
400.8923340	0.17
408.1582031	0.44
477.3062744	100.00
489.3001099	0.29
491.2247314	0.51
503.1488647	0.11
506.1984253	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
129.1972046	0.03
146.0151215	0.02
160.7901917	0.18
179.0805206	0.48
239.1006470	0.07
251.1668396	0.15
263.1999817	0.03
280.8529663	0.05
288.1433716	0.04
322.5113525	0.07
323.2624512	0.11
341.1993408	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.1667
Annotation	Antimycin A5
Peak:m/z	Relative Intensity
151.1940613	1.25
152.1352997	0.03
163.0343781	5.04
163.8091125	0.05
166.0791626	22.53
167.1761322	0.21
181.0496368	100.00
182.1347961	5.21
191.2872925	0.06
204.9881897	0.11
234.2085419	0.03
235.5890808	0.18
247.0242920	1.20
250.1220703	0.17
271.2140503	0.06
289.1598816	0.87
290.3203735	0.10
307.1301880	64.38
308.2007446	3.80
314.0714111	0.19
323.1901245	0.21
324.4551392	0.14
325.3572388	0.22
325.9611816	0.17
337.1714478	0.05
339.9575195	0.10
343.3443604	1.10
344.4613037	0.24
353.1624146	5.70
354.4995117	0.48
355.2705688	8.92
356.3631592	2.03
365.0776367	0.07
366.3296509	0.06
367.3934937	0.13
373.2739868	1.74
374.3206787	0.18
381.3982544	0.11
385.3671265	0.04
386.1715698	0.08
387.3740845	0.08
389.3451538	0.36
403.3179932	0.18
408.2113647	0.06
439.5169067	0.18
453.3516846	0.22
470.1354980	0.23
474.3903198	0.20
476.5828247	0.13
486.2822876	0.05
488.9326782	83.73
490.0422974	7.96
491.3508911	0.38
492.1477051	0.24
503.4185791	0.05
504.6335449	0.40
505.3222046	1.77
506.2516479	0.48
517.2197876	4.09
518.3867798	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
135.0235748	0.40
145.0166321	1.77
150.6311646	0.52
152.1732483	0.36
156.821106	0.26
163.0435944	100.00
181.8481293	0.11
187.9508057	0.60
190.1392212	0.65
191.1759033	0.18
192.980896	1.22
203.2287292	0.13
205.2025146	0.41
215.0159607	0.08
229.1772461	0.48
239.2724304	0.64
240.334259	0.57
241.2714539	0.23
246.8529358	0.10
248.7915344	0.13
255.3999329	0.07
259.1233826	0.63
261.0615234	0.71
264.4510498	0.78
265.3567505	3.23
267.0023804	0.51
274.074646	0.87
277.3099365	0.60
281.1152954	0.24
281.9768066	0.66
283.2028809	0.89
284.6199951	0.18
289.0245361	0.70
295.3678284	1.10
297.2985535	0.67
298.204834	0.21
298.9560547	0.19
308.1467896	0.44
309.211731	1.36
310.1946411	0.38
313.8154602	2.68
319.0800781	1.72
319.6811523	0.09
325.1587524	0.26
327.2770386	0.66
331.1690674	0.38
332.6374512	0.57
334.462616	1.69
337.0827026	2.93
338.063385	1.31
346.0942688	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1186
Annotation	Gancaonin N
Peak:m/z	Relative Intensity
123.1424866	0.02
127.3207092	0.01
141.0097351	0.02
159.1351929	0.01
164.9905701	0.04
167.1391907	0.02
177.1137848	0.01
187.2811127	0.05
191.2196350	1.34
192.1529236	1.27
192.9397430	0.07
207.1415100	5.58
216.3931580	0.02
219.2643433	0.02
221.2284241	0.03
223.1094666	0.03
240.9310303	0.02
251.3683472	0.03
273.3760681	0.04
276.2518921	0.04
277.1436768	0.04
279.4114990	0.04
283.4694824	0.05
284.4495239	0.01
291.4870605	0.02
293.2065430	0.04
297.3571167	0.06
305.3138428	0.06
306.2298279	0.01
307.2210999	0.08
308.1255493	0.05
308.7482300	0.01
309.3740234	0.03
311.2600708	0.06
320.0161438	0.11
321.1299438	0.33
322.2081909	0.29
323.1679077	0.23
324.2442017	0.17
324.8909912	0.03
330.0946350	0.07
331.1283264	0.13
335.2268677	9.42
336.2452087	11.82
337.1916504	11.88
337.8468323	0.06
339.0802917	0.02
340.0517578	0.05
348.4259949	0.11
349.3700867	0.48
352.1790466	100.00
357.0665588	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1255
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0297852	0.05
170.9703369	0.77
172.0677032	0.35
173.0912170	1.68
174.8902588	0.09
176.8833923	0.07
178.9582520	0.94
189.2257385	0.18
193.1915894	0.09
220.8298492	0.02
230.5403137	0.04
232.1472473	0.03
233.0400391	0.20
295.2385864	0.06
302.2108765	0.03
309.5100708	0.05
322.2557983	0.03
323.3575439	0.10
335.1049805	0.13
341.1645508	100.00
342.3922119	0.10
352.0520020	0.08
387.1048584	0.05
397.1250610	0.02
417.3048096	0.04
424.1669922	0.06
443.0900269	0.15
455.3137207	0.12
469.0726929	0.07
470.3240967	0.04
471.4052124	0.04
479.0424805	0.09
487.3854370	0.08
496.2484741	0.34
497.1279297	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1676
Annotation	Unknow
Peak:m/z	Relative Intensity
168.0430145	0.76
176.8966827	0.06
195.9889526	0.04
212.0232544	0.55
212.7168579	0.03
226.2753754	0.04
243.2987823	0.05
245.2209625	0.46
246.1481476	0.10
247.0069122	0.04
250.2693787	0.04
269.4771729	0.05
279.2877197	0.05
287.1787720	0.78
288.0730591	0.36
289.1928101	1.31
290.2675171	0.14
292.3096313	1.02
293.3956299	0.05
299.3256836	0.78
300.3340149	0.13
307.3283081	0.07
330.3714600	0.03
355.4188232	0.04
357.3018188	0.35
358.5204468	0.05
364.1711426	100.00
365.1943359	1.81
367.6831055	0.08
370.1946411	0.09
386.8193359	0.04
407.2619629	4.33
408.3288574	0.99
409.3297119	0.16
417.6055908	0.04
425.1904907	6.09
426.1153564	1.47
427.1823120	0.02
430.4287720	0.03
444.9848022	0.06
449.4385986	0.07
451.3276367	1.92
452.1671143	0.24
461.8166504	0.14
462.5392456	0.03
467.3837891	0.13
468.2509766	0.05
470.8370972	0.10
472.0960693	0.03
499.9710083	0.04
508.4686890	0.02
513.1937866	0.05
515.4414062	0.22
532.1492920	0.06
533.4627075	0.14
534.3928223	0.20
541.9001465	0.03
543.4871216	0.25
557.4774170	0.04
558.1807861	0.13
559.2791138	1.59
560.2286987	0.30
561.1506958	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	497.2026
Annotation	Iridodial glucoside tetraacetate
Peak:m/z	Relative Intensity
142.9934387	0.03
164.8843384	0.09
215.1042938	0.11
227.1672058	0.03
239.1057434	0.08
243.1582642	0.18
259.2459412	2.14
261.1953430	3.94
273.3022156	0.65
285.4405823	0.10
291.2496338	1.67
299.3764038	0.35
303.3238220	1.47
317.2518921	0.66
330.1799316	0.06
335.2434998	100.00
336.0897522	0.01
349.6830750	0.04
359.3560181	0.40
377.1979370	3.26
377.8129883	0.12
380.1932983	0.08
390.5387878	0.04
399.3754578	0.07
407.4355469	0.08
408.9770203	0.03
419.2236023	0.06
434.4758301	0.06
437.2969666	0.32
443.3323975	0.02
450.3439026	0.04
451.3711243	0.09
453.3384094	0.23
461.1494446	0.32
467.3654480	0.06
475.2005920	0.31
477.1598511	0.04
479.3004761	0.16
482.1570740	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1194
Annotation	Unknow
Peak:m/z	Relative Intensity
108.3298187	0.01
126.8561630	0.01
155.0453186	0.04
173.0607605	0.10
191.0512695	100.00
192.1893005	1.53
193.0970764	1.53
327.2738647	0.18
340.2756042	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	636.1979
Annotation	Obtusadiene
Peak:m/z	Relative Intensity
221.1122437	0.28
322.4987183	0.04
323.2534790	0.03
324.2891846	0.04
340.3100586	0.10
341.1633301	0.54
342.1304321	0.10
383.2540894	0.08
443.2509766	0.26
473.4219360	0.10
503.2383423	100.00
504.3717041	16.34
551.1303101	0.03
588.3989868	0.03
589.1823730	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9767456	0.05
160.0262756	0.52
167.4290771	0.10
170.2343903	0.10
170.9979401	0.16
173.0513000	0.09
177.0269012	0.22
177.9899139	0.08
179.1789551	0.29
184.9189758	0.63
190.9150696	0.24
192.9983521	0.13
195.0291748	0.20
195.9725647	0.42
197.1964417	0.05
202.1332092	0.11
203.0369263	0.04
206.0053864	0.06
208.8576355	0.09
210.0172577	0.15
219.3063507	0.05
224.2000580	0.06
226.7691040	0.24
230.1266479	0.11
231.2341003	0.28
233.7884674	0.18
234.4243774	0.13
235.7138367	0.06
237.1771851	0.15
241.1304932	0.07
250.2999573	0.28
252.3536987	0.10
253.0830383	0.05
254.1915436	3.41
254.9813385	0.12
262.0691528	0.05
263.2329712	0.04
270.1050415	0.09
271.2202759	0.25
272.1983643	0.73
273.1773071	0.06
278.1022949	0.19
280.3302612	0.15
281.1110535	0.26
288.1883545	6.35
289.4269409	0.06
292.3711548	0.06
293.2443237	0.10
293.9297485	0.35
296.9797363	0.15
299.1894836	0.13
304.4159851	0.08
306.1581421	11.59
306.7791138	0.12
313.0151978	0.18
314.1911621	0.36
315.3068237	0.57
320.0973511	0.15
321.7315674	0.15
327.2911377	0.07
331.9344482	0.28
335.4251099	0.04
336.4730225	0.06
340.3698730	0.17
341.2612305	0.23
345.2589111	0.38
348.0460815	0.15
351.2684326	0.20
354.3052979	0.20
356.9871216	0.40
358.1038208	0.23
359.1538086	0.04
361.2662964	0.10
363.1330566	0.29
366.1433716	0.57
370.3864136	0.22
372.3117676	0.14
375.2192383	0.44
376.1809082	0.08
377.2702637	0.10
379.3418579	1.29
382.2224731	0.07
383.2931519	0.05
384.0057983	0.20
389.3150635	1.21
392.2329102	0.12
397.1017456	0.52
400.1724854	0.21
401.0186157	0.03
405.2154541	0.26
407.3529053	2.11
409.2528687	0.94
410.3820190	0.06
411.3540649	0.07
413.3170166	0.11
415.7253418	0.16
416.3375854	0.29
418.3078003	0.07
421.1378174	0.09
423.3085327	13.28
425.3330078	0.88
428.3090820	0.57
433.2636108	1.60
435.1724243	0.14
439.0712280	0.75
441.2560425	24.10
445.4160767	0.11
449.3779297	0.29
451.1475830	2.19
451.7933350	0.06
457.2340698	6.15
459.2330322	1.40
462.3135986	0.29
467.1807251	4.80
469.1134033	0.58
473.0802002	0.27
475.2258301	76.84
476.2664795	0.13
485.2558594	100.00
487.3505249	0.05
489.1004028	0.20
491.3174438	6.37
493.3179321	1.58
501.1841431	1.44
503.3247070	45.70
519.1809692	22.24
527.1353149	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1921
Annotation	Unknow
Peak:m/z	Relative Intensity
125.1843109	0.04
126.0780792	0.07
131.0361176	0.04
138.0588074	0.01
143.1315460	0.26
149.0817566	0.03
153.1727295	1.10
154.2696228	0.07
159.1458282	0.08
161.1378479	1.80
161.8170929	0.02
178.9588928	0.84
180.0279388	0.02
181.0580750	0.02
197.2609100	0.02
205.1678925	1.59
205.9428711	0.01
206.6283875	0.04
207.4498901	0.01
223.0535278	4.52
223.8738098	0.10
225.1452942	0.32
235.5497131	0.01
251.9903259	0.01
265.3238525	0.05
269.2223511	0.05
281.1625671	0.03
293.4245300	0.02
295.3172607	0.02
297.2032776	0.02
307.1772156	0.01
316.8921509	0.03
341.4342651	0.08
358.3461914	0.05
372.2261047	0.01
385.2205200	100.00
386.2622375	1.53
387.3156433	0.01
405.2175903	0.03
413.3149414	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.1772
Annotation	Lactucaside
Peak:m/z	Relative Intensity
160.8922882	0.26
165.0396423	1.87
176.2762146	0.06
178.0795135	2.60
179.9199219	0.07
180.9548340	0.06
191.0397339	2.08
193.0359955	47.16
194.0031891	0.05
195.0614014	7.78
196.2409973	0.11
199.7100220	0.10
210.9276733	0.05
215.1118774	0.07
223.3127747	0.20
235.0269623	0.41
243.1205139	0.11
255.2350159	0.14
285.2442932	0.70
307.0936890	0.08
313.1719971	0.07
324.6333008	0.19
327.1360474	0.22
337.4055176	0.19
339.0297852	0.37
341.1658325	8.21
341.7672729	0.10
343.3694458	0.14
345.4042969	0.69
351.2177124	0.22
357.7205200	0.68
358.4527588	0.18
363.9807129	0.09
371.1823730	1.16
375.4829102	0.09
376.1397095	0.08
381.2864990	0.07
383.1188965	0.22
385.2280273	0.80
389.1422729	100.00
389.7655029	0.25
392.1818848	0.29
409.2595215	0.12
410.4328003	0.10
419.2520142	0.31
431.0877686	0.73
435.2426147	0.27
436.3708496	0.12
442.4820557	0.06
457.3829956	0.13
461.3971558	0.05
464.4124146	0.10
473.5656738	0.15
476.4255981	0.11
485.2698975	0.04
486.1343384	0.05
488.2133179	0.19
489.4074097	0.13
491.0219116	1.27
499.2592163	0.31
504.3095093	1.29
505.3863525	2.20
513.2945557	0.04
514.4270020	0.63
515.5311890	0.32
518.3919678	0.07
519.4136963	0.56
520.5063477	0.09
521.4706421	0.22
525.2700195	0.27
528.0363159	0.32
529.3942261	0.28
533.4031982	0.39
534.2504272	0.47
541.3281860	0.48
542.1690063	0.77
542.7926025	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.2552
Annotation	5beta-cholestan-3alpha,4alpha,11beta,12beta,21-pentol-3,21-disulphate
Peak:m/z	Relative Intensity
179.0939789	0.08
185.1093750	0.09
187.1949768	0.06
189.1570892	0.88
191.0057831	0.28
205.2786713	0.05
207.1397247	3.21
209.2966614	0.08
225.2302704	0.04
233.1638031	0.46
245.9470520	0.05
251.1738892	39.38
251.8888245	0.08
269.2744141	1.98
277.3892517	0.07
293.2555847	0.03
311.1954041	0.11
336.3369141	0.07
351.3709106	0.21
353.0106812	0.02
365.3848267	0.04
371.3371582	0.08
373.3020020	0.06
374.9027710	0.13
380.3607178	0.23
385.2703857	0.06
387.3973389	0.27
393.0466919	0.06
403.3669434	0.14
413.3342896	0.16
431.3633423	100.00
439.4340210	0.03
447.5162354	0.12
449.3768921	4.45
452.2740479	0.04
467.2894287	0.19
478.4213867	0.14
483.2982788	0.15
485.1729126	0.28
486.1881104	0.05
491.0388794	0.07
515.4011841	0.81
519.3357544	0.13
521.2876587	0.17
526.7589111	0.02
532.5392456	0.05
533.3477173	0.06
537.3876343	0.15
538.2990112	0.06
545.3484497	0.29
549.3998413	0.03
551.5149536	0.13
557.4376831	0.03
564.3273315	0.06
565.2133179	0.09
567.4406128	0.07
576.2705688	0.08
577.0491333	0.02
580.8399048	0.10
593.3671265	0.29
594.5325317	0.06
596.2976685	0.06
602.8671265	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.2227
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9572906	0.25
177.2305603	0.67
199.2162170	0.20
205.4005737	0.37
216.1737213	1.29
217.1747131	0.85
223.0094604	1.04
241.2645264	0.17
246.5136566	0.65
249.0732422	0.54
251.9688721	0.79
252.9947662	2.85
258.8161621	2.35
265.3400269	0.55
268.7205811	0.49
270.9086609	6.75
276.1769409	1.17
277.0008850	0.40
288.3007202	5.36
288.9816284	15.62
301.0276489	0.60
304.4995117	0.27
306.3397522	1.82
307.1197205	4.45
324.3970947	18.25
325.0595703	100.00
328.8900757	0.65
334.5540161	0.30
339.3373413	0.16
340.5278931	0.35
342.4482422	34.09
343.0921631	48.18
420.8229370	0.57
432.1506348	19.30
433.3107910	0.29
438.4024658	0.30
450.8991699	0.35
461.3380737	0.62
462.0224609	0.97
485.8826294	1.28
486.8295898	5.12
487.5728149	0.66
504.9448853	3.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1406
Annotation	Racemosic acid
Peak:m/z	Relative Intensity
152.8669434	0.11
154.9488525	0.05
161.0740051	3.26
171.3040924	0.18
173.1921844	0.43
179.0358276	3.77
191.0603027	20.26
195.1549530	0.09
203.2622833	0.04
233.1279602	0.13
244.8204346	0.07
268.9531860	0.08
297.4743042	0.08
305.1674194	0.14
323.1759033	100.00
332.9488525	0.04
335.1918335	0.65
341.2166748	16.03
345.2274170	0.07
353.1235962	16.12
367.3668823	0.19
388.3920898	0.15
395.4073486	1.79
425.5618286	0.09
438.3032227	0.06
441.3522339	0.15
455.3248901	0.10
471.4761353	0.50
497.2910767	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.08
Annotation	Unknow
Peak:m/z	Relative Intensity
151.1834259	0.11
153.0765991	0.12
160.1075287	0.51
160.7780457	0.02
161.7451630	0.14
163.2638550	0.05
164.0641785	0.10
166.2159729	0.06
167.2806091	0.09
169.0450439	0.12
170.0547638	0.02
171.1044617	0.32
176.9832458	0.17
178.1183167	0.16
179.0104065	0.77
179.9892731	0.15
181.0891724	0.07
184.9259186	0.35
186.0992737	0.24
192.2282104	0.10
193.3002014	0.03
194.2807007	0.08
197.0773926	0.04
202.4048309	0.03
209.1711731	0.21
210.1486969	1.25
211.1456757	0.29
212.1330261	0.33
212.9873657	0.23
217.2814941	0.05
219.0355835	0.38
220.1861572	0.11
225.3062897	0.11
228.2831421	0.09
229.0656281	0.18
230.0868683	0.15
231.1594696	0.34
232.0080414	0.14
235.8629456	0.10
237.3156433	0.16
238.0350952	0.06
238.8421021	0.09
243.2282715	0.21
244.0999146	0.10
245.1735840	0.03
252.2551422	0.05
253.1435394	0.47
254.2374420	3.55
255.1278687	1.57
256.1284180	0.32
261.0372009	0.06
263.2911987	0.07
268.9420776	0.26
270.1638794	0.07
271.1348877	0.09
272.1854248	2.95
273.1606750	0.99
274.2615967	0.17
278.3442688	0.08
280.0399170	0.04
280.7528076	0.12
284.2497559	0.19
287.1776733	0.16
288.1575317	2.01
289.1443787	1.43
290.0968628	0.78
291.0670776	0.07
292.2394714	0.05
294.5859680	0.09
296.2477417	0.07
297.4241943	0.18
298.1508179	0.42
300.2478638	0.08
304.2457275	0.04
306.1437988	12.65
307.1763916	9.96
308.2504272	5.81
312.1320801	0.05
316.2180176	0.10
317.0541992	0.05
318.5983276	0.10
321.1309814	0.05
322.2980347	0.11
323.1470947	0.28
324.2183838	0.40
327.2571411	0.09
328.0648193	0.09
330.3775635	0.17
331.2002563	0.07
332.3135986	0.04
333.1209106	0.05
338.3787842	0.31
339.3339844	0.03
340.2761841	0.27
341.1075439	0.73
342.1176758	0.75
343.0872192	0.13
345.3535156	0.03
346.1699219	0.17
347.1351929	0.09
348.9741821	0.07
350.0434570	0.07
354.2860107	0.33
357.2813110	0.09
358.1899414	0.06
360.0223389	0.35
361.3730469	0.25
363.3073120	0.17
366.2686768	0.21
367.4277344	0.59
368.0978394	0.03
371.0778809	0.09
372.2830811	0.28
373.0688477	0.04
374.4000854	0.19
375.0447388	0.06
376.3858032	0.05
377.3402710	0.05
379.1951294	0.66
380.2274780	0.51
381.1941528	0.53
382.4140015	0.18
383.4218140	0.02
386.6163940	0.06
389.1467285	0.23
390.0911865	0.13
391.3901978	0.70
392.4497681	0.91
393.1804199	0.03
395.3405762	0.05
398.3320923	0.85
399.1134033	1.02
400.2680054	1.15
401.2916260	0.08
402.0941162	0.03
405.4181519	0.14
406.2751465	0.40
407.2643433	0.44
409.2946167	0.40
410.2263794	0.47
411.2638550	1.18
412.2347412	0.52
413.3086548	0.12
415.4479980	0.21
416.1528931	0.34
417.1908569	0.40
418.3002930	0.31
419.5167236	0.04
423.2920532	2.71
424.2172852	9.39
425.3070068	2.82
427.2362671	0.45
428.0654907	0.04
429.3112793	0.17
432.3261719	0.17
433.1719360	0.10
434.3823242	0.05
435.2324219	1.43
436.2191772	3.70
437.4936523	0.37
438.3820801	0.58
439.3629761	0.34
440.5100708	0.53
441.3181152	0.75
442.3094482	1.70
443.3059692	0.99
443.9176636	0.06
445.1968994	1.34
446.3697510	0.14
449.3124390	1.04
450.3161011	3.30
451.1767578	1.11
455.3070679	0.18
456.2962646	1.49
457.4699097	0.97
458.2225952	1.12
459.1749268	1.27
467.3443604	7.37
468.2088623	30.10
469.1998291	11.86
470.3298340	0.04
474.0044556	0.09
474.8897095	0.14
476.2337036	5.14
477.3336182	3.43
484.2074585	2.67
485.2380981	4.89
486.2478638	15.34
487.3670044	5.65
490.0137939	0.07
498.3406372	0.10
502.2236938	100.00
503.1989136	48.59
504.4573364	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	361.07
Annotation	Cyclocanaliculatin
Peak:m/z	Relative Intensity
101.7970886	0.07
125.0887756	0.09
127.6438904	0.11
130.0738831	0.62
145.9353943	0.12
153.2908173	0.10
161.0677185	0.04
162.6690063	0.18
164.0462646	0.16
169.2945557	0.11
186.0326538	2.84
186.9303741	0.18
197.9210510	0.23
207.7545624	0.10
213.9826355	16.96
230.3249207	0.08
232.0787659	2.27
254.9207458	0.05
258.9226379	0.03
261.3999939	0.09
270.6975098	0.30
271.9279785	0.15
279.0464783	0.58
279.6516113	0.41
288.6546631	0.16
289.9962769	0.47
297.1962280	4.90
300.1127014	0.11
303.2114258	0.11
306.7070618	0.55
308.0418396	0.21
313.0721436	0.18
315.1170654	15.35
320.6092834	0.19
323.5169067	0.14
324.9268188	3.51
325.9435425	1.87
329.7825928	0.19
333.6421204	0.12
341.2460938	0.25
343.0191650	100.00
343.9707642	1.80
350.7914734	0.21
352.0416565	0.09
360.6687927	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9442291	3.70
159.9036865	0.50
199.1228027	0.18
200.0071411	0.19
217.0377045	0.04
218.1864319	0.06
228.8901672	0.61
230.0746002	0.16
272.9549255	54.94
274.0985413	15.63
288.9612732	0.06
371.1481934	0.18
372.1956177	0.08
385.0539246	0.31
387.0001221	100.00
387.9607544	53.43
388.6256409	0.17
409.3898010	0.07
410.9649963	0.10
427.0491638	0.05
428.1419678	0.11
429.4233093	0.02
457.1529541	0.09
458.0920410	0.13
460.0715332	0.07
473.1771545	0.17
483.2279663	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1013
Annotation	Xestodecalactone B
Peak:m/z	Relative Intensity
89.1579361	0.01
94.8968964	0.02
99.8916702	0.04
102.8422546	0.01
106.8241730	0.02
113.2742462	0.01
117.1412506	0.03
119.1081238	0.05
122.9416885	0.02
127.0119781	0.03
129.0944061	0.01
131.8040466	0.01
132.9631958	0.02
134.3984985	0.02
137.2303772	0.02
140.8031921	0.02
145.1364899	0.02
146.5012665	0.02
147.1661072	0.07
148.0385132	0.01
149.1370544	0.05
151.2876892	0.03
153.3488159	0.02
156.9125366	0.01
163.1156616	0.03
164.9857941	0.01
169.2428894	0.05
171.3090668	0.02
175.2254028	0.01
177.1709900	0.03
181.2159271	0.05
185.2602539	0.05
187.1140137	0.04
189.2281036	0.03
191.2509308	0.04
193.3628540	0.05
200.2478333	0.04
201.2856445	0.02
202.3424377	0.03
203.2935486	0.05
204.1979675	0.01
205.3497009	0.02
206.1597290	0.05
207.1441040	0.13
208.2171326	0.03
209.2739868	0.03
211.0960999	0.02
213.1040649	0.03
217.3645325	0.07
218.3223572	0.02
219.2819519	0.07
221.0870667	0.10
223.0001831	0.02
227.1726379	0.01
230.9620972	0.03
233.6547852	0.02
235.1188354	0.21
237.2644958	0.06
239.3710022	0.07
244.3010254	0.02
245.3197632	0.12
249.1462402	0.17
250.0519104	0.02
251.1751709	0.03
253.1655273	0.11
256.1493530	0.03
258.1670532	0.04
263.0788574	100.00
263.6883545	0.36
264.9815979	0.03
265.9644470	0.01
271.9268799	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1483
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.8404694	0.05
165.1200256	0.36
165.8581238	0.10
169.0820312	0.16
170.1022644	0.07
179.1404114	0.08
183.0052185	0.28
184.0789642	0.11
185.1128693	0.08
186.2176971	0.21
186.8747864	0.14
188.9423981	0.20
190.9714966	0.25
201.0857544	0.57
203.2727814	0.23
204.9006653	0.68
213.5229492	0.18
214.9784851	0.06
215.6508179	0.07
225.0241089	0.18
227.3022766	0.06
229.0948486	1.63
230.2383575	0.13
231.0770874	0.04
232.9669189	0.19
239.2313080	0.06
241.2080231	0.14
243.1614685	1.01
244.9208221	0.11
247.1447144	18.76
248.0940704	1.78
255.3119202	0.10
256.1919861	0.11
257.2537231	0.23
259.0944824	3.30
259.9636841	0.35
261.2543335	0.77
269.0423279	0.23
271.1893311	9.19
272.2075195	0.90
273.0900879	1.83
275.0394287	5.58
276.1373291	1.88
283.2406006	1.07
285.1468506	0.81
287.2517090	1.24
289.0669556	20.01
290.3141479	4.91
291.1000366	42.72
292.1486816	7.08
299.5791626	0.10
301.0891418	12.35
302.0872192	2.00
303.1937866	7.42
304.1012573	1.29
307.1754761	0.35
308.2062073	0.08
310.1948853	0.21
311.0890503	0.05
312.7339478	0.38
313.3627625	0.15
314.3801880	0.17
315.1642456	0.31
316.4979858	0.03
318.1359863	0.16
321.2775269	0.05
325.6275024	0.18
333.2885742	0.96
334.0373535	0.49
341.5355225	0.04
355.4901733	0.15
358.8459473	0.06
391.4917603	0.12
393.2677002	0.11
394.6024170	0.06
401.3215332	0.32
402.1795044	0.41
405.0820923	0.08
407.4875488	0.07
409.1622925	48.67
410.1701050	11.11
411.3198853	10.20
412.2648926	2.26
418.3997192	0.10
421.1740723	2.51
422.2300415	0.58
423.2121582	0.47
425.2199707	0.09
427.1060791	100.00
428.1410522	17.10
429.0372314	0.06
433.2711792	0.04
435.1726074	3.70
435.9204102	0.28
437.2422485	0.20
439.1520996	3.01
440.2176514	1.12
441.4067993	0.10
447.1920776	0.94
448.0545654	0.18
449.4449463	0.07
453.1436768	4.11
454.1574707	1.42
459.7376099	0.16
465.5013428	0.05
469.2088623	0.15
477.7723999	0.32
484.2207642	0.40
492.3519287	0.13
532.0611572	0.05
533.1652832	0.33
538.7058105	0.24
543.0277710	1.25
544.1545410	0.92
545.3427124	0.05
561.1318970	4.22
562.3591919	3.92
563.1442871	0.08
571.1776123	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.1445
Annotation	alpha-CEHC
Peak:m/z	Relative Intensity
106.9951096	16.81
108.9976959	1.59
120.9566727	30.20
126.9890594	50.78
133.9526062	100.00
134.9434814	22.82
141.0793762	3.40
146.9866943	13.53
154.8928223	1.79
164.7920532	0.94
178.2663269	1.20
179.0492859	5.08
183.1787109	0.88
187.1791687	0.83
193.3273926	1.51
197.3110046	0.69
205.1583252	20.09
206.9801025	2.39
213.1644592	1.07
217.1304321	1.69
219.2279663	0.82
221.3986816	1.80
231.1682434	2.07
233.1503906	99.68
234.1721191	0.76
235.2832336	10.48
247.1485596	0.94
249.4197388	4.77
258.2499084	1.57
259.339386	4.47
277.2876587	2.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	235.0612
Annotation	7-Hydroxy-3-methoxypereflorin
Peak:m/z	Relative Intensity
72.9485092	0.21
90.9214020	0.22
99.1029358	0.02
117.1374512	0.10
119.0698090	0.02
129.0995789	0.49
147.2020111	0.09
151.2543945	0.01
157.0316010	0.06
161.1922455	0.21
163.4006805	0.10
173.0525055	29.68
177.0820618	0.03
187.1560669	0.03
189.1631622	0.55
191.1376038	20.30
199.1786499	0.03
201.8634491	0.01
203.2977448	0.09
205.1207123	0.08
206.2955170	0.02
206.9916840	0.92
207.5969086	0.00
217.0547485	100.00
219.4662933	0.09
220.1461639	0.33
235.0436859	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1607
Annotation	trans-p-Ferulyl alcohol 4-O-[6-(2-methyl-3-hydroxypropionyl)] glucopyranoside
Peak:m/z	Relative Intensity
120.1103363	0.18
149.3756409	0.06
160.8945312	0.07
163.1756439	0.11
164.0037842	0.61
171.0348816	0.08
171.9461975	0.14
180.1239929	0.19
184.7582397	0.10
207.2531738	1.13
211.2221527	0.06
215.3081818	0.07
217.1868591	0.06
219.1701050	100.00
220.2482452	0.05
221.2045746	0.06
230.0279846	0.07
244.9892273	0.19
249.1077881	0.03
255.1651306	0.11
257.3986206	0.05
264.9479675	0.06
267.1564331	0.06
272.1143494	0.04
305.2641602	0.03
311.3630981	0.22
323.3644409	0.24
327.5744019	0.05
335.5500488	0.08
339.1308594	0.10
346.3264771	0.09
347.3835449	0.10
352.9396362	0.06
355.3094788	0.40
356.3764343	0.05
366.4018860	0.03
367.2676697	0.03
368.1307068	0.05
369.4223938	0.06
371.2508240	0.06
380.7851257	4.87
383.4679871	0.18
385.6499329	0.07
387.4506531	0.08
390.5759583	0.19
391.2730408	0.26
409.0887756	0.97
410.3633118	0.11
411.1712646	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
88.9209290	0.29
101.0013428	3.74
106.9176559	0.13
112.9282227	19.22
114.9671478	0.42
118.8883972	11.95
125.0679016	2.59
130.9696045	9.31
143.0676575	17.05
148.9952545	2.75
160.4045715	1.08
161.0481873	13.21
179.0115509	100.00
182.8933411	0.54
184.9424744	0.21
221.0498352	0.25
237.2583923	0.18
245.2103577	0.11
251.0814819	0.17
281.0134277	1.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1401
Annotation	Racemosic acid
Peak:m/z	Relative Intensity
158.8966064	0.06
161.0393066	0.27
171.1248169	0.43
173.0925598	0.62
177.1691284	0.07
179.0739288	3.29
189.2141724	0.11
191.1117859	67.40
203.0651245	0.31
215.2224579	0.09
220.8242493	0.14
229.3287506	0.14
243.0452881	0.11
250.8845520	0.05
305.4465332	0.06
308.4301758	0.08
317.0473022	0.03
322.4489746	0.84
323.1890259	7.75
335.1492310	0.64
341.2427979	2.35
353.2381592	100.00
363.3782959	0.10
381.6618042	0.09
393.0609741	0.05
395.2141113	1.61
399.2279663	0.11
405.5274658	0.12
407.2142944	0.09
409.0708618	0.04
419.2321167	0.15
420.6867065	0.10
434.4253540	0.06
436.5173340	0.24
447.2839355	0.07
449.6486206	0.06
455.3725586	0.22
468.6453247	0.13
469.6197510	0.20
471.3447876	0.04
482.1222534	0.07
487.3970337	0.10
489.7703247	0.11
496.5584106	0.80
497.4602051	0.34
498.2240601	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9165344	1.15
84.9219818	0.01
100.0050201	0.06
101.9907227	18.09
102.6968994	0.01
129.9395447	100.00
130.8929291	1.00
147.4742126	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2207
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
101.0884552	0.17
106.9910431	0.16
109.1957855	0.14
113.0043335	0.40
119.035965	0.19
124.5780487	0.24
129.1007233	1.64
135.2507629	0.45
137.0624084	1.05
139.078949	0.56
141.0092163	0.39
143.1013947	1.05
149.1903992	0.49
151.1247253	1.33
153.0600281	0.35
155.1929169	1.67
157.0376587	1.83
159.9216614	0.25
160.9062805	0.58
163.1444855	0.47
165.066452	0.99
166.9806824	0.52
169.1343689	3.67
171.1174774	0.22
175.165802	0.17
177.0509033	2.44
183.2204285	1.13
185.2684479	0.53
187.0749359	1.31
190.8503418	0.42
193.0498047	1.57
195.1274414	4.49
197.1571655	1.23
198.1590576	0.73
199.1748047	0.99
200.1853027	0.61
201.2540588	0.62
204.9668579	0.59
207.1549072	1.13
209.1022949	0.94
211.2504883	4.82
213.3554382	0.14
215.2574768	0.25
217.5101929	0.33
219.3513489	0.15
221.2511597	0.19
223.056488	1.98
225.2131958	4.18
227.3031616	1.53
228.8808594	1.51
229.4880676	0.56
233.2779541	0.62
235.3259888	1.53
237.20224	1.01
239.124054	3.56
241.3040771	0.75
242.9238586	0.99
245.4925537	0.20
249.0506592	0.58
251.2293396	4.47
253.2008667	8.78
255.3309937	0.55
257.2359009	0.91
261.4699097	0.88
263.0492859	0.20
265.1652832	1.78
266.5571289	0.78
267.3787842	0.85
268.5815125	2.25
269.3151855	1.98
270.10849	0.70
275.0737	14.74
276.3444214	0.43
277.1936646	0.24
279.1094971	0.80
280.3503113	0.48
283.2296753	4.17
293.2067871	100.00
294.0477905	0.65
302.2715149	0.60
307.2731934	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.08
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
93.0263824	4.19
136.9970703	100.00
172.9436340	0.13
178.9722290	0.06
184.1014709	0.06
202.9635010	0.05
207.1066895	0.10
208.9767151	0.13
211.1845703	0.06
227.2543030	0.02
237.4387817	0.08
239.0000305	0.13
252.9938354	1.46
255.0877380	0.19
270.9683838	0.05
278.9096680	0.03
279.5581665	0.03
281.1970215	0.21
283.3162231	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.085
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.9229126	0.10
95.95739746	0.02
102.9516144	0.17
103.9950562	0.11
104.8549652	0.06
108.8337402	0.11
114.9326782	0.01
118.8403778	0.02
123.2039795	0.02
129.0168152	0.86
129.9882507	0.42
142.2419281	0.09
146.9373322	0.03
151.0400543	8.03
152.0311127	2.81
153.9719086	0.06
156.1327362	0.03
158.1912231	0.04
159.1442566	0.04
165.1951599	0.14
166.0752869	0.15
167.0616608	0.67
168.0966339	0.15
169.0993805	0.09
169.9872589	0.12
179.1480103	0.41
180.1452484	0.16
181.240921	0.08
182.131485	0.12
183.2722778	0.23
184.1094818	0.05
185.0018768	0.22
191.1581116	0.04
192.2549286	0.02
194.2767487	0.05
195.0641327	0.08
197.043869	0.37
198.2144775	0.31
198.9390411	0.09
200.2915955	0.02
208.1849213	0.03
209.8729553	0.11
211.1066132	0.02
212.2241364	0.04
223.2242737	0.02
225.1243134	0.75
226.0884857	0.57
235.0578156	0.07
238.2024384	1.08
239.2818756	0.88
240.21521	0.13
251.2069244	0.13
253.0909882	100.00
254.2208252	4.62
255.2800903	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
200.0648956	0.09
215.0710144	0.12
244.9254913	0.07
246.8001709	0.09
273.0708618	1.38
274.0764771	0.69
275.1352844	1.15
289.0140991	4.53
289.9712219	1.21
291.1175537	0.90
297.3725586	0.03
387.0747681	1.38
388.0334473	1.46
389.0354004	1.95
403.0200806	17.04
404.0009766	9.16
404.9650879	12.18
443.2946167	0.06
485.2992554	0.06
486.2713623	0.04
499.0214233	0.04
501.9052124	0.64
503.1028442	0.32
516.9321289	49.94
517.9672852	78.59
518.9177856	100.00
519.5939331	0.11
543.0794067	0.10
558.0755005	0.21
559.0380859	0.14
575.2327881	0.12
586.0615845	0.53
587.0714722	0.30
587.6993408	0.05
588.8485718	0.26
614.9066772	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1672
Annotation	Unknow
Peak:m/z	Relative Intensity
204.2538147	0.03
299.1234131	0.09
323.2783203	0.25
341.2532959	0.04
372.2628784	0.02
373.2954712	0.03
443.4724121	0.03
451.4073486	0.01
473.5185547	0.02
503.2531128	100.00
503.8555298	0.43
531.2923584	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.2238
Annotation	Alangilignoside C
Peak:m/z	Relative Intensity
174.0613251	0.13
175.0790100	0.12
177.5444031	0.14
178.9161682	4.95
187.1576233	0.39
187.9745789	0.30
193.1314697	1.84
201.7982178	0.05
203.2070007	0.17
205.0585938	0.27
207.0718994	0.15
208.8070374	0.38
217.0547638	0.27
221.1684723	0.42
222.2067719	0.12
223.0747375	0.09
232.4539490	0.17
235.1692200	1.30
272.9998169	0.09
274.1593628	0.07
309.1762695	0.08
314.2290039	0.06
322.1248779	0.16
323.3495483	0.14
325.2385254	0.40
328.2805786	0.10
329.3711548	0.04
339.3150024	0.12
342.3775024	0.19
343.2103271	0.20
353.2612915	0.17
354.0270996	0.11
355.3216553	0.61
356.3427124	1.14
357.3165894	0.03
359.4626465	0.20
365.0213013	0.08
365.7149048	0.08
368.6974487	0.45
369.3973389	0.84
371.2957764	2.27
372.3156738	0.74
373.1436157	5.33
375.0982666	0.15
383.3344116	0.33
385.2716064	0.58
386.2472534	0.68
387.2709961	0.97
388.3869629	0.14
389.3466797	1.49
390.2911377	0.20
391.3666382	0.11
397.6138916	0.09
401.3407593	100.00
403.3038940	1.17
405.2250366	0.18
406.5298462	0.18
409.0931396	0.11
412.6021729	0.12
415.6135254	0.10
417.2117310	0.32
418.8037720	4.24
419.4167480	1.86
420.9181519	0.27
431.4696655	0.09
432.5377197	0.15
433.1862793	0.17
437.1857910	0.06
444.4727783	0.17
448.3612671	0.46
457.3165283	0.09
461.3016357	0.33
464.5395508	0.05
491.0352173	0.13
493.4674683	0.16
495.5131836	0.08
497.2946777	0.64
503.4035034	0.16
507.4208374	0.09
511.2280273	0.20
515.0741577	0.27
517.4838867	0.08
520.5123291	0.06
521.3215942	0.10
532.9649658	0.11
534.3687134	1.60
535.2847290	5.81
537.1083984	0.45
539.2164307	0.11
540.1724243	0.04
548.9689941	0.20
549.6566162	0.09
551.2979126	0.29
556.6725464	0.18
558.3048706	0.11
562.2530518	0.31
563.3423462	0.47
566.2597046	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2084
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
166.1614990	0.01
181.2002563	0.09
190.8845673	0.01
193.1042480	0.04
196.1178284	0.02
206.2818451	0.01
207.4142151	0.00
208.9665527	0.01
225.5502930	0.02
261.1880798	0.01
278.9165649	0.01
309.2821045	0.06
310.3931274	0.03
311.3783569	0.02
327.4159546	0.01
336.4014893	0.02
346.2257080	0.01
370.3811646	0.02
371.4427490	0.02
373.1823120	0.01
375.3126221	0.03
384.4171753	0.01
385.3365479	0.01
388.2923584	0.00
403.2695923	0.02
411.2196045	0.01
417.2528076	100.00
418.2326660	1.23
459.3852539	0.13
462.6069336	0.03
485.0648193	0.01
499.4548340	0.01
501.5053101	0.01
518.2152710	0.01
519.2553101	0.03
520.3843384	0.02
533.3625488	0.01
540.1746826	0.01
547.0977173	0.01
561.2230835	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2
Annotation	Magnolenin C
Peak:m/z	Relative Intensity
181.1891327	0.04
205.4900513	0.03
208.3796692	0.03
222.5932617	0.02
223.3380737	0.05
236.2009277	0.04
243.1666718	0.02
260.3321228	0.02
275.0530396	0.02
293.0885010	0.06
345.3677368	0.04
346.4140625	0.03
364.5609131	0.03
369.1492310	0.05
373.2001343	0.30
374.4872437	0.02
377.4428711	0.02
383.2970581	0.07
387.1165161	0.36
389.2636719	100.00
397.0884399	0.06
397.7590332	0.02
399.3806152	0.01
401.0451660	0.02
403.3245850	0.58
407.6146851	0.03
415.2832031	0.17
421.1098022	0.07
422.2687988	0.02
431.1643677	0.08
432.7009277	0.44
433.3590088	8.63
441.4442139	0.03
442.4578247	0.05
470.4529419	0.01
506.2850952	0.02
509.1945801	0.02
510.1968384	0.03
514.2776489	0.08
517.1583252	0.07
519.4581299	0.11
520.1960449	0.02
521.3095093	0.02
524.5745239	0.02
525.5322876	0.02
531.5971680	0.03
533.2726440	0.02
535.3980103	0.02
548.2660522	0.32
549.2981567	0.25
551.1623535	31.18
551.7725830	0.26
557.1843872	0.02
559.4020996	1.11
562.4182739	0.13
563.3919678	0.30
575.5331421	0.05
577.0373535	0.27
580.3551636	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
105.0862122	0.50
114.8817444	3.44
121.1637726	0.69
123.1117172	1.74
127.0636597	1.02
127.9150467	0.62
131.0422058	0.32
132.9052124	0.58
134.7989502	0.33
137.0198669	0.34
138.9865112	1.29
141.0600281	0.23
142.9741974	0.30
149.2948914	0.81
151.1011658	1.16
156.9492188	1.88
160.9947052	0.42
162.1731415	0.48
163.2316284	1.39
165.1452789	0.23
167.1110382	1.40
168.2671204	0.40
168.9988556	2.20
171.1251221	2.05
176.786911	1.46
177.3937225	1.19
181.070282	0.80
183.1809692	1.39
184.9323273	0.60
187.163208	1.27
190.9824829	0.43
193.8266754	0.62
195.2679749	4.45
197.232666	3.24
200.3853455	0.54
204.7912903	0.80
208.2979431	0.58
208.9414978	0.37
210.9796143	2.37
213.252655	0.65
215.3274841	1.57
217.0801086	1.55
217.8553772	0.91
221.3499451	0.50
222.0710449	0.32
223.1216125	0.71
225.2540894	0.82
227.0384216	2.69
229.315094	0.79
230.9541016	1.34
231.7759705	0.26
233.0140381	0.23
234.0732422	3.49
234.9472961	0.42
236.032135	0.28
237.0429382	1.96
239.0711365	3.33
241.1151123	0.33
242.0347595	0.48
247.2167969	1.56
249.2336731	1.65
251.2586975	5.29
252.017395	0.19
253.1627197	9.42
255.3467407	0.60
257.4394226	0.23
261.7295532	0.29
265.2449646	3.58
267.2327576	2.17
268.8893433	0.54
275.2033081	12.79
275.8255005	0.67
277.1619263	0.41
279.1309509	1.12
282.1622314	0.44
283.1716919	4.54
285.442688	0.32
287.8982239	0.33
293.2057495	100.00
294.2614746	1.36
301.8343201	3.03
307.4399109	0.39
310.6634521	2.14
311.3771973	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.1877
Annotation	Rupestrin B
Peak:m/z	Relative Intensity
257.1877441	0.15
261.0542603	0.13
288.4205322	0.06
304.9375916	0.08
335.2764282	0.10
337.1538696	35.59
338.1245728	0.15
343.3446045	0.08
353.2082520	100.00
354.3377686	0.16
367.1145020	0.06
426.3045044	0.08
428.2391357	0.18
474.9948730	0.09
477.2730103	0.21
485.2221680	0.05
495.1497803	0.07
499.1027222	0.17
511.6587524	0.24
517.4696045	0.15
519.2502441	1.33
520.2386475	0.17
521.4637451	0.21
528.7344971	0.07
547.7684937	0.12
575.8047485	0.03
591.0523071	0.17
595.4155884	0.24
601.7485352	0.03
629.2329712	0.05
631.2937622	0.18
645.3771973	0.04
656.4828491	0.11
673.1390991	0.11
674.5801392	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
59.0421600	0.03
67.2490692	0.02
70.9955750	0.02
84.9230652	0.49
86.9835663	1.39
92.9499359	0.09
100.9586792	0.02
109.0482330	0.05
110.9613647	100.00
111.6780396	0.03
117.0281525	0.05
127.0472412	0.13
129.0306854	2.75
130.9253693	1.08
144.6527863	0.03
147.1143036	0.08
154.9613037	1.04
162.9722595	0.03
171.0080566	0.09
172.9640961	36.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2939
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9754028	0.08
164.8992920	0.04
196.0933685	0.35
214.0873718	1.56
224.3690338	0.02
241.3877258	0.02
281.3817139	100.00
293.3432922	0.08
325.3034058	0.04
332.3467407	0.03
334.2036743	0.03
340.3273315	0.05
360.5068970	0.03
372.6022949	0.03
398.8621216	0.03
404.2847595	0.04
407.4482727	0.03
434.3700256	0.09
446.5840149	0.06
459.3376770	0.07
460.1408691	0.13
461.5366516	0.13
462.3529358	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.1498
Annotation	Unknow
Peak:m/z	Relative Intensity
225.1851349	0.05
226.0813141	0.03
228.3388977	0.05
254.1544495	0.29
255.4038391	0.04
258.9981079	0.02
262.1943665	0.04
263.1705322	0.09
282.1335449	0.06
288.2033691	0.36
289.1930237	0.02
296.1030273	0.01
296.8664246	0.01
297.5462646	0.03
299.2564087	0.04
304.2500916	0.03
306.2236328	0.32
311.9238586	0.02
315.4095459	0.05
322.1572876	0.03
323.4879761	0.04
324.1212158	0.03
325.2088318	0.03
331.5234375	0.06
332.9193115	0.02
340.2683411	0.05
341.3448486	0.04
347.2210693	0.03
353.1969604	0.05
354.1578369	0.04
356.2439575	0.13
357.3630981	0.03
359.1474915	0.03
366.1761475	0.25
367.2684631	0.06
370.5642700	0.04
375.3065186	1.09
380.2107544	0.02
382.2288208	0.08
383.5700684	0.03
384.2348022	0.04
385.1880493	0.24
389.3780518	0.02
390.1937256	0.01
391.2239990	0.03
399.5772705	0.08
400.4081421	0.23
403.1114502	0.08
409.2584839	1.24
410.1853638	0.10
415.0397949	0.03
416.1024780	0.02
417.2959595	0.15
418.3624268	0.05
424.2410889	0.05
426.2972412	0.14
427.1087646	0.03
428.2893066	0.19
431.1410522	0.01
434.5549927	0.03
437.1422119	0.05
441.1675415	0.12
442.3200073	0.17
444.2949219	0.05
450.4260864	0.01
452.1129761	0.07
457.4036255	0.05
458.4283447	0.03
462.2203369	0.12
468.0610962	0.04
468.7079468	0.08
470.2066040	0.04
474.4672241	0.03
475.3169556	0.06
480.1837158	0.05
484.2899780	0.19
486.3323364	1.00
495.4307861	0.05
500.5918579	0.04
504.4359131	0.85
510.0441895	0.03
511.2708740	0.08
512.2925415	0.07
519.2012939	0.04
520.3538818	1.96
521.3482666	0.03
524.2199707	0.08
526.1852417	0.07
528.4230347	0.12
529.2520142	0.18
533.8983154	0.14
536.3330078	0.07
538.2938843	7.96
538.9251709	0.03
541.1298218	0.05
542.3905029	0.01
543.3824463	0.08
544.5437012	0.19
545.3940430	0.01
547.4690552	0.06
551.5651245	0.06
552.3488770	0.22
554.4219360	0.14
555.3895264	0.01
559.4272461	0.03
560.4209595	0.04
561.4666138	0.07
564.4290771	0.10
565.4414062	0.05
567.3489380	0.16
568.3471069	0.05
570.2511597	0.10
571.2500610	0.10
573.3272705	0.07
574.4447632	0.07
577.3013916	0.34
578.7308960	0.06
580.1788940	0.08
586.1812134	0.38
587.0198364	0.06
588.7514038	0.09
589.8613281	0.05
591.3859863	0.29
593.3049927	0.25
595.2708740	0.14
598.3927612	0.66
599.5103760	0.03
601.1497803	0.03
602.3360596	0.05
603.4796753	0.12
604.4961548	0.06
605.7009888	0.02
606.3710938	0.13
607.5806274	0.17
608.3753052	0.03
611.4602661	1.60
612.3937988	0.03
619.5256958	0.02
621.2510986	1.22
623.4954224	0.10
624.4007568	0.06
625.4866943	0.06
626.6062012	0.12
629.4933472	0.32
630.5802002	0.02
632.0586548	0.05
637.3231201	0.49
639.3268433	0.55
640.3975220	0.02
641.4319458	0.80
645.3279419	0.12
647.2211914	0.15
648.1524658	0.17
650.4144287	0.03
654.7720337	0.68
655.4338989	9.07
657.4699097	0.11
658.5938110	0.01
660.3229370	0.48
661.3647461	0.11
663.3616333	0.07
665.3063354	0.64
669.6849365	0.07
671.4368896	0.43
673.3032837	18.69
676.2369995	0.14
681.2809448	0.18
683.3565063	0.60
684.3833618	0.08
686.4135132	0.04
687.4080200	0.04
689.2454224	4.72
689.8551025	0.10
691.4274292	0.16
693.1715088	0.07
694.4863281	0.10
699.3297729	2.31
700.9600220	0.05
701.6082764	0.05
702.3468018	0.07
705.2113037	0.28
707.2895508	100.00
708.0689087	0.13
709.3965454	0.30
715.3438110	0.08
717.3583374	20.96
721.4547729	0.03
723.3360596	1.41
724.4053345	0.10
725.4162598	1.80
733.3064575	2.48
735.4051514	8.57
737.3289185	0.14
748.2861328	0.03
751.2332153	25.34
751.9204102	0.03
759.3802490	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.98
Annotation	Unknow
Peak:m/z	Relative Intensity
86.0765228	0.12
87.0677643	0.09
95.0989685	0.39
96.9860077	0.22
102.0057220	0.09
107.0211639	0.15
109.1585693	0.13
115.9605865	0.30
121.0489197	0.24
123.6770630	0.19
125.4142914	0.11
128.8764801	0.07
134.9853210	0.20
140.2637787	0.13
142.8957214	0.32
144.0475006	0.09
148.9519653	0.38
153.2109985	0.29
154.8911133	0.09
155.8707275	0.12
163.1723175	0.09
169.0281982	0.61
170.0038757	0.07
170.9654541	0.19
171.7410278	0.32
174.1703186	0.08
175.2829285	0.42
182.1794586	0.26
183.3732758	0.50
185.0956879	0.41
186.8856049	100.00
188.9423981	0.07
191.2243652	1.89
192.1342926	0.08
198.1595612	0.46
199.1110077	0.05
200.2370300	0.09
204.8359528	0.75
206.7894592	0.37
209.1378937	1.06
210.1764679	2.14
211.1539459	0.22
227.6107178	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	207.1012
Annotation	Ethyl trans-p-methoxycinnamate
Peak:m/z	Relative Intensity
70.8459015	0.10
73.2966003	0.02
75.0312958	0.08
88.9446106	0.28
91.0494843	0.17
101.0525360	0.07
104.8199921	0.07
107.0227203	0.04
108.9568787	0.03
115.0507812	0.14
117.0490112	0.12
118.9884033	0.10
120.9447174	0.16
123.2456207	0.10
128.9193420	0.08
131.0405426	0.05
132.0972595	0.04
133.0703430	1.59
134.1566010	0.02
136.0820770	0.10
136.9974976	0.39
138.0361328	0.27
138.8893585	0.09
141.3038177	0.04
142.0442810	0.02
143.0151825	0.06
145.0777435	0.55
146.9975128	2.09
149.0718536	0.21
151.0301208	6.41
152.9290009	0.09
158.1876984	0.10
159.2187500	0.19
160.3111267	0.52
161.1232452	0.58
161.9048462	0.10
163.1688232	0.25
164.0556183	0.66
165.0655823	0.58
171.1623993	0.06
174.1765137	0.52
175.0201721	15.12
176.0282898	100.00
177.0787659	13.19
179.0370636	8.41
189.0841217	1.57
192.0310822	14.35
194.7558594	0.05
205.2670135	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.2026
Annotation	Unknow
Peak:m/z	Relative Intensity
211.2329712	0.08
212.0845947	0.10
218.9244843	0.23
219.5280762	0.03
227.1945343	0.13
228.2472229	0.15
238.4731750	0.05
242.3011017	0.06
245.0993805	1.02
247.1292114	0.24
255.8222046	0.10
256.9686584	0.05
271.1993408	0.19
272.1531982	0.05
285.4167786	0.14
287.1176453	15.77
288.4847412	2.20
289.1493225	10.69
290.1546936	1.78
290.7835388	0.06
299.1102295	4.80
300.1578064	0.58
301.1239929	0.11
307.1820374	0.08
325.1736450	0.16
328.0203247	0.39
329.2201538	0.54
330.0860596	0.05
331.4208984	0.11
332.3247375	0.06
337.3048706	0.14
339.3792114	0.12
341.4948120	0.17
350.9356995	0.06
353.1630859	0.05
357.1753845	0.06
363.1298828	0.15
371.5459595	0.15
377.4409790	0.09
382.2824097	0.44
385.3361206	0.04
397.3430176	0.06
405.1923218	0.72
407.2991943	5.55
408.2782593	1.00
409.4476318	0.21
410.1619263	0.11
417.3607178	0.91
419.3530884	0.99
420.4034424	0.09
423.5260620	0.13
425.1703491	0.71
426.1854248	0.21
431.5670776	0.47
433.2546997	0.33
435.2541504	4.34
436.3535767	0.23
437.2145996	0.93
438.4648438	0.04
445.2398071	0.02
447.2880859	0.06
449.2075806	41.71
450.2652588	6.55
451.2265625	16.44
452.3063965	2.71
461.1548462	0.11
466.2314453	0.08
467.1275635	0.17
477.4248657	0.04
491.1704712	0.19
494.3805542	0.04
502.0618896	0.06
503.2946777	0.17
516.2598877	0.11
525.6082153	0.07
530.3665771	0.06
531.5856323	0.05
541.2446899	0.05
543.1981201	0.38
544.5298462	0.14
546.5664673	0.10
547.3254395	0.18
555.7174683	0.04
559.2992554	1.36
560.2824097	0.59
569.3147583	20.60
570.3878784	6.08
571.2794189	0.35
572.4100952	0.19
573.5876465	0.07
577.3966675	1.30
578.5354004	0.18
587.2672729	100.00
588.3101807	18.28
589.2987671	0.41
590.5319824	0.05
591.2174683	0.08
594.3609009	0.15
611.5027466	0.10
621.2730713	0.10
629.4517212	0.92
630.5494995	0.16
631.2822266	0.08
647.6461792	0.09
653.6270142	0.08
663.7056274	0.03
677.2810059	0.24
678.4256592	0.06
679.4597168	0.21
685.1654053	0.08
693.6509399	0.07
695.3915405	0.66
696.5070190	0.30
697.1205444	0.09
703.3792725	0.21
704.2910767	0.02
707.2020264	0.04
708.8507690	0.07
721.4396362	4.39
722.3793335	0.78
730.5482788	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3304
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9022675	0.09
191.9721069	0.22
243.2553864	0.05
270.2270508	0.14
279.3216553	2.15
297.2960815	0.09
347.5817261	0.06
409.2562256	0.09
420.5687256	0.10
431.9537964	0.17
467.4462891	0.06
468.5125122	0.05
504.4225464	100.00
505.3372192	0.30
507.5138550	0.12
509.6769409	0.12
518.2798462	0.37
519.2484741	0.27
520.4507446	0.15
525.3026733	0.34
528.5608521	0.81
532.8869629	0.14
545.7727661	0.59
546.5275269	0.10
564.7817993	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	839.3354
Annotation	Unknow
Peak:m/z	Relative Intensity
289.1967468	0.04
340.9671936	0.02
405.2658081	0.02
451.4138184	0.02
473.3305054	0.02
496.5533447	0.04
520.6458130	0.01
539.6264038	0.02
547.4210205	0.03
552.5118408	0.02
577.3540649	0.02
603.1872559	0.04
606.2926025	0.08
608.6571045	0.02
610.4853516	0.06
624.6864624	0.17
627.6464233	0.02
638.4620972	0.09
650.4869995	1.43
651.6538696	0.07
655.5885620	0.02
664.6631470	0.06
665.6890259	0.07
670.4007568	0.13
676.8829346	0.03
677.5736694	0.06
682.4301758	4.26
692.9301758	0.02
701.7207642	0.06
703.3654785	0.36
706.5272827	0.03
719.5910034	0.05
721.2284546	0.07
729.3181763	0.09
733.5601196	0.06
737.6298218	0.02
742.3951416	0.02
743.6609497	0.05
745.6200562	0.04
747.5487671	26.68
749.4308472	0.02
757.1879272	0.01
758.6813965	0.03
761.4403687	0.22
763.3834839	0.81
764.2744751	0.02
771.7758789	0.16
777.5975952	0.08
779.4229126	65.08
780.0846558	0.08
789.4351196	12.51
790.5249634	0.03
803.4714966	0.14
807.4456787	100.00
808.1218262	0.35
815.4757080	0.14
817.3763428	0.02
821.3538208	21.52
822.0492554	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.2707
Annotation	Kansuinin H
Peak:m/z	Relative Intensity
238.1613312	0.03
268.2060547	0.04
302.2811279	0.11
305.9827881	0.03
311.2850342	0.07
313.3051147	0.07
323.4637451	0.06
326.0505371	0.04
336.3014526	0.05
337.2768555	0.02
338.0708618	0.04
339.2431030	0.80
340.2236328	0.04
344.2001953	0.03
354.2966919	0.68
355.1607666	0.28
357.2485962	0.66
358.3766479	0.18
366.5736084	0.06
369.3143921	6.65
370.3480225	0.85
372.2197266	0.39
373.2615967	0.10
374.4181519	0.03
385.9995117	0.13
387.2721558	6.88
388.3735962	0.35
389.6401367	0.05
429.2665405	0.07
441.4184570	0.27
467.2618408	0.03
485.3604126	0.24
505.3526001	0.21
513.4833374	0.03
517.3534546	2.24
518.4265747	0.49
519.1558838	0.31
520.4130249	0.10
535.3623047	24.43
536.3956299	2.40
537.1127319	0.02
547.3768311	0.14
549.2454834	0.43
550.5693359	0.09
551.4582520	0.24
553.3657837	0.66
554.3651733	0.09
565.2034302	6.83
566.4137573	0.39
575.1666260	0.02
576.7571411	0.03
583.2321777	100.00
584.2067871	12.72
585.0180054	0.08
602.7927856	0.28
607.3496704	0.13
619.4069824	0.03
625.3607788	0.11
631.3425293	0.02
633.8115845	0.06
654.9605713	0.02
669.5621948	0.09
671.3318481	0.08
672.8361206	0.03
683.1878052	0.08
685.9105835	0.28
686.8397827	0.09
697.1106567	15.83
698.1026001	3.53
699.2852173	0.30
700.1122437	0.08
701.5570679	0.42
702.4466553	0.08
714.9611206	0.14
716.5162964	0.03
717.4907837	0.04
725.8184814	0.03
727.0992432	1.77
728.3399048	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	693.11
Annotation	Unknow
Peak:m/z	Relative Intensity
196.2527466	0.06
197.0062103	0.04
202.9545898	0.02
215.1568298	0.02
217.9192963	0.03
225.9032745	0.02
230.1437225	0.02
231.9198303	0.13
232.5524597	0.05
233.2034302	0.02
238.1458282	0.05
238.8958893	0.10
240.1883087	0.42
246.1317902	0.03
251.2765045	0.07
257.1255493	0.02
258.0638428	0.12
259.0980835	0.06
260.1510010	0.91
261.1205750	0.36
262.1866455	0.09
263.1858826	0.13
265.1573486	0.03
273.5069885	0.11
274.3229370	0.11
275.3129272	0.09
277.1517944	0.99
278.2041626	0.49
283.1722717	0.09
286.9394531	0.09
288.1114197	0.31
290.2970276	0.11
290.9997559	0.07
292.2307739	0.33
294.2916870	0.09
299.7745972	0.07
302.0180054	1.16
304.0578003	1.18
305.0894775	2.32
306.1072998	0.23
317.9252930	0.73
320.0504150	5.22
322.1183472	0.04
327.7991333	0.12
331.0578613	0.14
344.0675049	0.42
346.0833130	3.75
348.0353394	1.21
348.8546753	0.13
349.9343262	0.03
360.4002686	0.03
362.4780884	0.04
363.9376221	0.68
367.7050171	0.05
372.1511230	0.10
374.0309448	0.41
376.1098022	0.02
389.9794922	2.04
390.8787231	0.29
392.0592651	12.00
392.7432861	0.14
394.1287231	0.06
408.1242676	0.03
417.3021851	0.13
418.0931396	1.56
425.4862061	0.08
431.0728760	0.01
434.0056152	0.22
435.5099487	2.06
436.1938477	16.74
437.0347900	0.08
444.3753662	0.04
459.9636841	0.05
462.1042480	2.98
467.0516357	0.02
478.1329346	1.24
480.0897217	100.00
481.1433716	0.11
482.3127441	0.03
512.0349731	0.03
522.1987915	0.10
530.0195312	0.05
541.5765381	0.10
543.0852661	0.03
544.8233032	0.09
546.2316895	0.08
560.8351440	0.05
587.0385132	0.16
603.1390381	0.06
605.3605957	0.16
607.1266479	1.25
616.2362671	0.03
618.4367676	0.03
630.9834595	0.77
649.0440063	1.49
656.7586670	0.17
673.1859741	0.09
674.8297729	5.61
675.5899048	0.01
692.7891235	0.02
693.6875610	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.09
Annotation	Unknow
Peak:m/z	Relative Intensity
158.0056305	0.11
178.7409363	0.19
209.4248352	0.06
211.1200562	0.08
239.0810394	0.04
240.7281189	0.05
245.2947388	0.03
247.0658875	0.09
248.3871155	0.15
278.2130127	0.04
290.4920044	0.14
310.6746826	0.12
312.8634644	0.27
313.6430664	0.10
316.3229370	0.24
325.3002319	0.14
329.1991577	0.14
336.5119629	0.07
340.1726685	0.05
343.1139526	0.18
344.1885376	0.06
345.2666626	0.35
353.3010254	0.05
360.8540649	0.06
370.0363770	0.05
371.0730591	0.16
374.9380493	0.08
376.4755859	0.07
387.0395508	0.11
391.1627197	0.03
402.3515625	0.11
404.2128906	0.09
411.9795532	0.14
417.4754028	0.11
418.2646484	0.13
419.2028809	0.42
420.1112671	1.18
429.2546997	1.38
430.2234497	1.30
431.6879883	0.18
438.7322998	0.08
446.2637329	16.90
447.1668701	88.24
448.1077271	100.00
449.6274414	0.19
462.3238525	0.07
468.9784546	0.10
470.6319580	0.19
471.2707520	0.05
475.2881470	0.05
477.2827759	0.12
478.3307495	0.04
479.2400513	0.10
486.2949219	1.96
487.2273560	3.80
491.3814087	0.32
496.9285889	0.13
504.2183838	2.70
505.2080078	3.33
506.0736694	0.80
513.7200317	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
109.2068329	0.93
127.2191467	0.29
129.9047089	0.85
169.9642639	8.78
183.0061035	100.00
184.0609894	12.92
197.1063538	20.63
198.0439758	5.05
201.0151062	0.48
211.2888184	1.90
212.1728821	2.15
212.9623413	1.30
225.1842957	1.61
226.1828613	0.64
239.212616	2.21
240.1917419	2.64
241.2290955	0.48
246.2104492	0.45
247.246582	10.01
249.3262329	8.43
251.2674255	2.23
253.0986328	1.11
254.050415	0.97
255.3195801	0.63
257.3722229	1.00
265.2393188	0.62
266.5377197	2.23
267.4155579	13.58
268.4023438	0.69
269.2805176	1.10
293.2069702	15.64
311.4128418	11.04
312.3466492	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.278
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
195.9794464	2.11
214.2056885	1.08
236.9617004	0.03
249.1006470	0.03
255.2841187	100.00
256.2509155	0.03
277.9371948	0.03
309.1518555	0.05
340.7114868	0.07
391.3419189	0.42
406.0247498	0.31
407.4678955	0.15
408.4643250	0.02
434.2839966	0.03
437.7758179	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
163.1132355	6.36
268.5499268	4.85
281.366272	15.89
327.2432251	10.30
339.118042	15.36
362.8742676	35.16
372.2000732	6.36
375.2193604	7.00
384.8468018	15.86
400.1870117	28.96
444.3577271	19.45
483.3284912	26.14
501.2056274	100.00
502.2603149	21.86
502.8634644	13.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8943
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9774475	0.27
160.1319580	0.06
174.9179230	1.80
199.6980743	0.06
213.2244110	0.04
214.9336090	0.13
228.8263245	0.05
237.0374146	0.03
245.1115112	0.23
260.2049561	0.07
262.9166260	0.09
273.0730896	13.48
274.0660400	1.30
275.0249329	0.45
287.3306274	0.06
288.9808044	30.60
303.8239746	0.80
304.9701538	100.00
307.0190125	0.08
319.2218628	0.06
329.1322327	0.04
345.0569763	0.61
348.0377502	0.08
362.2217407	0.15
362.9422913	0.08
372.1519165	0.14
373.0478821	0.93
373.9988403	0.27
374.8792419	0.28
375.8365784	0.07
376.4695129	0.07
377.7662659	0.06
391.0560608	0.40
400.4344177	0.08
401.1473083	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1377
Annotation	Villosin B
Peak:m/z	Relative Intensity
81.0352325	0.05
85.1560516	0.02
86.1126404	0.10
86.9012909	0.02
95.0122223	0.10
96.9447021	0.31
104.7417755	0.06
106.9737701	0.04
108.9047623	0.41
109.8075409	0.07
110.9792633	0.59
112.9428940	0.14
119.0675735	0.16
121.3460541	0.09
123.0608368	0.09
125.1547394	0.29
126.9679260	0.12
130.9506531	0.18
133.0661926	0.20
135.0699158	0.78
137.0428162	0.26
139.2243347	0.03
143.0173340	0.14
144.9971008	0.48
146.2013245	0.08
147.0831604	0.84
147.9705811	0.03
149.0235596	0.18
151.0615387	0.18
152.9923248	0.23
155.0451050	0.16
157.1525574	0.69
159.0830688	0.78
161.1279297	0.62
163.0907898	0.37
164.2937012	0.04
165.1654510	0.19
166.2679443	0.07
166.8686829	0.03
169.2615814	0.05
171.1165924	3.93
173.1073608	3.60
175.0530701	0.95
177.2252045	0.19
178.9851990	0.07
181.1702271	0.54
183.0918274	0.33
185.1084747	1.06
187.1549683	0.65
188.9773712	0.99
191.0452423	1.00
193.1342468	1.38
199.2094116	2.29
201.1331177	9.01
203.1911621	2.27
205.0813904	0.52
207.0621033	100.00
209.1259766	0.50
211.0755920	0.05
215.1010437	5.98
217.2008972	1.89
218.9965820	11.36
219.6973877	0.05
221.0298767	0.50
222.6885986	0.05
225.2349548	0.06
227.1666565	4.71
230.1402893	0.04
231.3328857	0.12
233.1297913	4.32
235.1250916	1.94
236.5113525	0.18
237.4168701	0.20
238.9814453	0.14
240.1439209	0.30
245.1098328	30.81
245.7221375	0.33
249.1271057	0.29
251.1961975	1.16
252.2706604	0.14
253.3476562	0.07
260.5603333	0.06
261.2308044	0.02
263.1231079	29.83
272.1145020	3.02
273.2097778	0.10
280.7816772	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.2951
Annotation	Clerodendrin H
Peak:m/z	Relative Intensity
220.6755219	0.02
250.9906006	0.13
253.2071228	0.05
279.1342468	0.10
287.3319702	0.25
297.3746948	0.10
299.4218140	0.05
305.3388977	0.51
313.1826172	0.13
323.9213257	0.11
331.0144653	0.04
339.1260681	0.20
345.2489624	0.09
357.4548950	0.21
365.5158081	0.03
383.3688354	0.03
385.0928955	0.02
395.3100586	0.05
399.3669434	0.08
401.2502441	1.25
402.4188232	0.21
406.3234863	0.13
414.7902222	0.03
426.1389771	0.08
434.0405273	0.19
438.5969849	0.03
440.9816284	0.07
452.3479614	11.92
453.3296509	4.26
454.2487183	0.47
464.1895142	0.04
471.2483521	0.17
478.2863770	3.07
479.3917847	1.07
496.1214600	8.47
497.2366333	3.87
505.3373413	0.05
507.6771851	0.04
510.3218384	12.25
511.2875977	4.25
514.5475464	0.04
547.9525757	0.07
552.7070923	0.10
557.8204956	0.22
571.4188232	0.15
573.5545654	0.30
575.5234375	0.61
576.4813843	0.37
578.3181763	0.21
581.3018799	0.10
591.4215698	3.08
592.3798218	1.67
593.3596802	0.02
599.2669678	0.41
600.3583374	0.38
607.3382568	1.21
608.3432617	0.31
617.3622437	9.41
618.3657227	5.80
619.2990723	0.22
620.8904419	0.10
631.3621216	0.62
632.4573975	0.07
635.3771973	100.00
636.3663940	66.85
637.0263062	0.34
644.8587036	0.18
649.3449707	0.79
650.2462769	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.96195221	0.64
96.89483643	0.92
101.0003357	0.94
110.9175873	0.41
121.0284119	1.26
122.9042282	1.03
128.9809723	0.80
132.9958344	0.19
137.0477295	0.45
139.2447968	0.94
140.9004517	1.61
143.0421143	1.10
147.8793793	0.32
151.0113831	1.30
152.8411865	0.16
154.9838867	2.18
157.1951599	0.42
163.0831909	0.90
165.1224976	0.29
169.0840454	0.83
170.8277893	1.59
177.2173767	3.37
181.254364	0.76
183.328537	0.87
184.3220367	1.03
184.9979095	0.33
191.0657043	1.52
193.3283081	0.19
195.0232849	1.60
197.1903381	2.08
198.913269	2.44
204.9776306	0.65
209.2623596	1.03
211.2432861	3.57
211.9891663	0.53
213.2951355	0.52
221.0269165	2.43
225.3103333	0.99
227.1186218	2.53
231.3665771	0.37
233.3112488	2.21
235.083313	1.29
237.2359924	0.55
239.23703	1.51
240.0111084	0.23
241.2194824	1.49
246.2492065	1.15
249.269928	0.59
251.0375977	2.12
253.2333984	7.51
255.3955994	0.32
256.7130127	0.46
263.2442017	1.50
265.2133789	4.98
267.1500244	2.31
267.7650146	0.11
269.120697	2.44
275.3196106	13.54
275.9434204	0.22
279.2194519	0.37
281.2548218	0.41
283.2200623	6.14
287.8023071	0.18
293.2017212	100.00
294.1089478	0.74
296.3319397	0.35
302.2088318	1.71
307.5196838	0.65
310.4266357	3.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	556.13
Annotation	Unknow
Peak:m/z	Relative Intensity
297.9725952	0.05
306.6282959	0.05
362.3486328	0.45
371.5637817	0.24
376.2534790	0.19
377.2236328	0.25
387.8626099	0.07
393.3320923	0.12
395.1215820	100.00
404.1599731	0.05
409.2030029	0.03
436.2350464	0.16
451.2946167	0.06
471.8615112	0.33
475.8289185	0.19
492.0556030	0.34
493.3326416	0.19
500.7797852	0.12
509.6249390	0.38
510.7522583	0.20
511.4045410	0.17
520.6598511	0.09
537.8366089	1.01
538.9134521	0.19
557.1621704	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.161
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
160.0279694	0.06
161.0406494	0.28
163.2153320	0.04
168.0871124	0.07
171.0405121	0.04
173.0483856	1.03
174.1286316	0.04
176.9793396	3.40
178.0337524	0.26
179.2052307	0.24
180.0419312	0.29
191.0492096	10.73
191.9653625	0.31
194.1609192	0.17
195.1174011	0.98
196.1489716	0.11
197.0589142	0.05
198.7691803	0.21
202.2365723	0.13
203.1090698	0.36
206.9655609	0.06
207.8514252	0.03
209.1508179	0.43
211.0222168	0.04
215.0697021	18.61
216.1548157	1.21
219.0851440	0.08
221.0173950	0.05
223.0134277	0.05
227.1688843	0.16
234.6231689	0.06
243.4101868	0.06
245.1423340	0.31
261.1994629	0.24
265.3590698	0.06
267.2188721	0.04
269.0026245	0.06
270.8328247	0.02
286.0237427	0.12
289.1488037	0.05
290.1380005	0.13
294.9267578	0.14
296.5625610	0.03
297.2410583	0.13
307.1976929	1.31
308.2245483	1.24
310.4658203	0.15
311.2802734	0.16
312.4197998	0.25
313.1900635	0.09
324.4215088	0.24
325.2315063	0.10
326.3359985	0.05
334.3774414	0.05
335.2490845	0.06
337.3073120	0.03
338.2598267	0.13
339.0787354	0.43
341.4154053	0.14
343.2301025	0.71
344.6885986	0.13
349.3063354	0.18
351.1864014	100.00
352.1117554	13.95
353.1576538	1.56
354.4443970	0.04
356.1746826	0.48
357.3850098	0.81
358.3638916	0.06
363.4252319	0.06
365.2553101	0.03
366.2593994	1.64
367.2382812	13.50
368.4116211	3.32
369.2241211	30.71
370.2744751	6.09
371.3639526	0.04
373.2669678	1.49
374.3173218	0.32
381.3395386	0.31
385.3236694	0.10
387.1814575	4.65
388.3236694	0.62
391.4789429	0.12
397.1784058	0.07
398.4246826	0.06
399.3287964	0.50
400.2011719	0.16
407.6884766	0.04
409.4200439	0.09
414.0697632	0.03
417.3849487	0.17
420.8226318	0.03
439.2604370	0.03
446.0239868	0.04
448.1040039	0.07
465.1757812	0.03
469.2915039	0.04
472.2904663	0.11
475.4359741	0.04
486.4762573	0.17
511.4868774	0.19
512.2371216	0.03
513.3876343	0.10
515.3064575	0.26
517.1458130	0.35
523.3460693	0.10
524.2326050	0.03
526.0656128	0.07
528.7637329	0.25
529.4790649	0.17
531.1947632	0.59
532.2721558	0.32
538.1768799	0.07
539.4288940	0.16
543.1483765	1.57
544.2825317	1.23
562.6168213	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0752
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone
Peak:m/z	Relative Intensity
81.0410004	0.03
90.9311523	0.01
100.0430603	0.02
104.9853973	0.04
107.1489258	0.01
108.9400024	0.02
110.9782562	0.06
112.9392548	0.06
115.0705414	0.01
121.0572052	0.01
123.0003662	0.02
125.2567444	0.03
126.8836975	0.01
129.1853027	0.01
131.1484833	0.05
137.1042023	0.01
147.0245209	0.03
151.1009369	0.01
152.0568695	0.01
156.9891205	0.04
162.7674103	0.02
165.1555023	0.06
167.2840729	0.01
168.9843292	0.02
171.2417450	0.02
174.9774323	0.03
177.2167511	0.02
179.0800629	0.15
181.1624451	0.16
182.9049835	0.23
184.0585480	0.40
188.8768311	0.03
193.0097656	0.04
195.1344604	0.04
197.1360321	0.15
201.0581665	0.04
202.2017975	0.01
204.6423492	0.10
207.0566559	100.00
208.0710297	0.08
209.0111542	0.05
210.0438538	0.01
216.0346832	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	513.2061
Annotation	Unknow
Peak:m/z	Relative Intensity
146.0478210	0.31
146.9442749	0.10
168.2403107	0.12
169.1942444	0.03
170.1789246	0.27
173.3186035	0.05
180.0051117	0.09
185.1548309	0.03
185.8117371	0.03
188.1165466	4.89
189.1149902	0.42
191.3256683	0.03
202.2916718	0.24
203.0798340	0.11
205.0232849	17.17
206.1212158	3.38
208.2620087	0.02
209.1376648	0.08
215.1556854	0.03
216.6511841	0.10
218.1554565	0.14
229.1709290	1.90
230.1091461	0.61
231.2389832	0.10
240.3168030	0.18
242.2408295	1.59
243.0904541	0.05
247.1242218	3.40
248.1801758	0.77
249.2453156	0.07
254.1589355	0.61
255.3643341	0.23
258.2231445	0.16
259.2308960	0.25
260.2322388	0.26
260.9252319	0.19
270.5748291	0.14
271.1835327	1.11
272.0775757	0.23
276.1454468	0.37
277.2881470	0.10
278.3441772	0.31
283.2659912	0.05
284.2883301	0.04
285.2487793	0.08
289.2085876	0.44
290.2482910	0.07
291.2315674	0.12
292.0999756	1.27
293.1851196	0.63
294.1302795	0.80
295.0745239	0.35
296.0557861	0.04
297.3288879	0.72
298.4972534	0.09
300.6426392	0.09
305.2047119	0.37
307.3959351	0.23
310.5294800	0.10
313.2639160	0.45
315.1431885	6.44
316.1848755	3.00
316.8836060	0.07
321.1827393	0.11
323.5321655	0.06
324.2457275	0.02
328.9856567	0.13
329.9713745	0.03
331.3104858	1.15
332.1800537	0.57
333.2013550	8.28
334.2639160	2.38
337.1292725	0.12
339.2745972	0.13
340.1823730	0.15
343.1634521	0.20
344.2618408	0.08
346.4713135	0.14
348.1843262	0.07
349.2949829	3.66
350.3173218	2.95
351.1823120	15.55
352.3274536	4.35
353.2112427	0.21
355.1480713	0.18
357.2861938	0.26
361.2747803	0.05
363.9907227	0.12
365.3215332	0.23
367.1876831	100.00
368.1861572	31.98
368.8519897	0.07
369.5841064	0.21
371.0637817	0.04
373.4448242	0.47
375.2096558	0.97
376.3986816	0.22
377.5433960	0.07
378.3592529	0.14
379.3423462	0.39
380.1578979	0.04
381.2201538	0.05
386.1821289	0.21
387.3590088	0.19
391.2546387	5.57
392.3339844	2.06
393.3026123	2.13
394.4307251	0.25
397.3171997	0.05
399.2797241	0.14
404.1251831	0.18
405.3186646	0.38
406.4352417	0.03
409.2438354	2.36
410.3359375	0.87
413.5012817	0.08
415.5612793	0.44
416.3676758	0.04
416.9712524	0.04
417.8013916	0.07
421.0850220	0.19
422.4918823	0.50
423.3747559	0.17
429.2610474	0.10
433.2944946	9.09
434.2940063	3.31
440.0808105	0.07
441.4106445	0.67
442.4949341	0.07
443.1094360	0.07
449.5318604	0.08
451.3817749	1.08
452.4829102	0.15
459.2661743	4.35
460.3386230	2.02
461.6673584	0.03
462.7948608	0.16
467.4789429	0.35
468.5789185	0.09
469.3129883	0.10
477.2473755	18.05
478.3568115	7.84
492.0379028	0.05
495.2660522	58.92
496.3063965	18.70
497.3203125	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	300.18
Annotation	Indicine
Peak:m/z	Relative Intensity
109.1049194	0.04
126.9403992	0.05
156.0964050	0.04
163.2274780	0.11
168.0415039	0.05
202.2731323	0.11
211.2587891	0.13
215.2146912	0.05
219.1162720	0.07
220.1360779	0.14
221.2363586	0.06
229.2792969	0.05
239.1620789	0.08
240.1803284	0.33
247.0446167	1.08
250.7937622	0.04
254.1765747	0.18
255.1808472	0.31
258.4929504	0.15
259.1218262	0.07
265.0643311	100.00
265.6675110	0.22
279.0260315	0.21
282.0301514	33.52
283.1851807	2.61
285.4294128	0.05
290.8114624	0.12
300.0003662	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1614
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
114.2495193	0.05
117.0060425	0.03
118.9157562	1.08
125.0418701	0.29
131.0588684	0.86
135.0986481	1.04
136.1807861	0.03
143.1076660	2.37
144.1113586	0.10
149.0402222	0.71
159.2101746	0.11
161.0418549	2.93
161.9645386	0.27
179.0364075	24.03
180.1460876	3.30
181.1378174	0.07
197.0942688	0.11
198.0419159	0.15
205.2878723	0.23
223.1045837	100.00
224.1932220	15.55
241.1010437	1.06
242.1980896	0.22
250.9344788	0.02
255.2329712	0.06
265.2037659	0.03
283.7475281	0.05
326.1052246	0.10
343.2183228	0.02
359.2216492	3.86
360.1615295	0.77
385.2543335	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	720.158
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0912018	0.40
212.3658600	0.12
213.2444763	0.14
217.2459412	0.36
219.0865936	0.15
231.0804749	0.59
243.2094727	3.02
244.1418610	0.24
245.1712952	5.02
246.1236572	0.79
247.3594055	0.47
257.4447632	0.12
261.2066040	0.31
269.1222534	0.08
270.1554565	0.29
271.0051880	0.17
274.9133301	0.17
285.1350098	0.99
286.1478882	0.12
287.2573242	13.34
289.1055908	28.85
290.2129517	3.03
299.3941956	0.53
300.1769714	0.45
301.2503662	0.11
313.1000366	0.44
327.4275513	0.28
329.2723999	0.19
330.1372070	0.39
331.2319946	2.15
337.4616089	0.14
340.2631226	0.13
341.4992981	0.37
346.3459778	0.15
353.1584473	0.63
354.2885132	1.48
355.4086304	0.24
357.5573120	0.48
361.1736450	0.10
363.0950317	0.94
364.5761108	0.33
371.2839966	0.38
374.0145874	0.24
381.2361450	0.36
382.4147949	0.47
395.1044922	1.25
396.3498535	1.10
405.3574219	3.49
406.2655640	0.83
407.2477417	11.37
408.3316040	3.21
409.1225586	0.36
413.1669922	8.06
413.7988281	0.54
414.4157715	0.49
418.0712891	0.16
423.3732300	1.62
425.0801392	7.22
426.3271484	1.82
431.7053833	0.27
435.5336304	0.64
439.0339355	0.15
449.0982056	3.55
450.1591187	1.18
451.2240601	6.25
452.3267822	1.17
453.2186279	0.38
454.4394531	0.18
455.3956909	0.50
465.1452637	0.27
467.3809814	1.09
469.7271118	0.88
474.3931885	0.72
479.6247559	0.18
483.1649780	0.58
483.8600464	0.53
489.3853149	0.15
490.8415527	2.52
491.9382324	0.23
493.4119263	0.36
494.4619751	3.45
495.3711548	0.49
499.5151978	1.81
500.4718628	2.30
502.2062378	0.58
502.8424072	0.27
514.3732910	0.55
515.2946167	0.48
519.3430176	0.19
520.5100708	0.71
523.2329712	0.31
525.2606812	0.21
527.1961060	1.29
528.2879028	2.38
529.1461792	0.38
531.1831665	1.88
532.6893311	0.81
533.3663940	2.41
534.3344727	0.13
536.1739502	0.18
537.2257690	0.41
541.6063843	1.57
546.2469482	0.88
549.2716675	1.32
550.5990601	5.42
551.3282471	1.02
552.2052612	0.28
554.7894287	1.64
555.4650879	0.16
556.6636353	0.24
559.4198608	19.22
560.3384399	2.41
565.5723267	0.20
566.4415894	0.65
567.3234253	0.13
568.3235474	6.86
569.5235596	0.71
572.4728394	2.38
575.3230591	47.37
576.2507935	13.83
577.1955566	37.38
578.3268433	13.71
579.1353760	0.84
580.5562744	0.33
581.5154419	2.04
584.9732666	0.08
585.5772705	0.35
587.5620728	1.16
589.8310547	0.62
597.8881226	0.18
600.9176636	0.62
612.5549927	0.67
613.3452759	0.46
614.0079956	0.59
617.3536987	0.59
618.2268066	0.31
618.9644775	0.19
619.5646362	0.85
620.3999023	0.50
622.4507446	0.73
626.6862183	6.10
628.8381348	0.61
629.6421509	0.81
631.8740234	0.27
633.3912964	0.14
634.2036743	0.67
635.4387207	100.00
636.3455200	6.63
637.1018677	0.40
643.2853394	0.11
644.2747192	40.62
644.9531250	20.30
648.3278198	1.17
649.5989380	0.27
650.3212280	0.37
651.3131714	0.35
652.3735962	0.16
653.1162720	1.44
657.3696899	7.79
658.0626221	3.22
659.4818726	0.76
660.2119751	0.34
665.4077759	2.62
667.2870483	0.17
683.3015747	2.13
684.2149048	0.16
687.2257080	0.21
692.6057739	1.70
693.4523315	2.76
694.6541138	1.03
695.3388062	4.96
696.3161011	1.77
697.4715576	0.69
698.2827759	1.50
698.9824219	0.37
701.1567993	12.43
702.3711548	5.67
703.3821411	2.39
704.2956543	0.31
711.3403931	1.99
737.0466919	1.72
739.0686646	5.98
740.3820801	3.65
743.1281128	0.10
749.1007690	0.44
756.5382690	0.14
779.2506104	1.11
781.4133301	0.35
785.3516235	0.30
796.3474121	0.24
801.3072510	0.34
803.2534790	0.11
804.2127686	0.15
814.2170410	0.10
819.3356323	0.39
820.5885010	1.04
821.3859253	1.67
822.1771851	2.15
823.0484009	0.11
831.4503784	0.35
832.4569702	0.17
837.4286499	1.28
838.3629761	0.66
845.4065552	2.34
846.4942017	0.53
847.4722900	1.15
848.5248413	1.24
855.3143311	0.30
857.2136230	1.52
858.4433594	0.53
859.7196655	0.27
863.2643433	46.74
864.3322144	20.84
865.2980347	27.87
866.3186035	10.81
867.3004761	1.13
873.8970337	0.37
875.1787720	0.19
889.1305542	0.31
890.2534180	0.46
891.6154175	0.17
899.2606812	0.46
901.3449097	0.63
902.6504517	0.18
905.1530762	0.16
906.0720215	0.94
907.2080688	2.70
908.2316895	1.05
908.8959961	0.21
918.6520386	0.21
919.3209839	0.07
939.1152954	0.59
941.6052246	0.41
946.2910767	0.30
954.8778687	0.30
958.1061401	0.43
971.3430786	0.81
981.0054321	1.54
982.3257446	2.14
983.1845093	2.26
984.1701660	1.87
985.6032104	0.48
986.2933960	0.09
988.0895996	0.78
989.3179321	6.86
990.2593384	5.42
991.4047852	1.76
998.9091797	1.55
999.6538086	2.38
1000.5103150	0.34
1001.2669070	1.00
1002.2412720	0.64
1008.3488770	0.16
1009.3949580	1.16
1010.3295290	0.50
1025.4260250	2.48
1026.0446780	3.76
1027.2939450	9.93
1028.3894040	4.62
1029.4213870	2.09
1031.2762450	0.75
1043.7110600	1.11
1045.5979000	0.15
1083.3215330	0.22
1095.0709230	0.09
1107.4456790	0.12
1108.3071290	0.09
1109.4235840	1.74
1110.2485350	1.15
1111.0212400	0.54
1111.8553470	0.18
1112.6832280	0.25
1128.5871580	0.30
1133.0897220	0.34
1134.3016360	0.48
1135.1727290	1.00
1135.8881840	0.87
1136.7065430	0.58
1145.2581790	1.03
1146.3691410	1.10
1147.5362550	0.17
1150.7456050	6.79
1151.3601070	44.43
1152.5148930	26.69
1153.3666990	19.10
1154.2967530	7.94
1155.4343260	1.63
1163.3330080	1.24
1164.3425290	1.45
1165.1555180	0.33
1178.4077150	0.11
1193.6568600	0.29
1195.1434330	3.96
1196.2324220	3.52
1197.4937740	0.95
1270.8636470	0.14
1272.7482910	0.11
1274.4383540	0.19
1275.4044190	0.11
1289.2645260	0.30
1297.5152590	0.99
1298.5936280	0.25
1315.2626950	11.36
1316.2962650	12.43
1317.0345460	1.21
1317.7252200	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.1926
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
163.1434479	0.28
164.0404968	1.09
165.0045776	0.20
165.7913513	0.08
177.1733551	0.05
178.3178711	0.17
179.0629730	0.86
181.0517273	0.09
191.1017761	0.14
193.1772919	0.91
205.1274109	0.32
206.1778259	0.34
207.0101929	0.28
208.1729126	3.55
211.2616272	0.08
219.2031860	0.18
221.1422424	0.26
223.1331787	84.82
229.3602448	0.05
230.9511108	0.06
232.2069092	0.06
233.1647644	0.10
234.1484833	0.25
237.1353912	0.47
238.0910797	0.05
247.2645874	0.15
248.9852905	0.35
265.1118469	2.42
267.0986023	0.27
277.2180176	0.15
289.1836548	0.06
293.0600586	0.08
295.3782349	0.13
307.3569336	0.29
310.0950317	0.12
315.1622314	0.25
316.1525879	0.08
323.2384644	0.16
325.1795654	0.21
326.5410156	0.18
327.1641235	0.04
333.3401489	0.13
336.0735474	0.16
339.4197388	0.15
342.0942383	0.19
347.3726807	0.10
353.0407104	0.09
353.9619751	0.20
355.4825439	0.05
356.1860352	0.13
357.2779541	2.56
358.2383423	0.29
359.2008667	0.18
365.2872314	0.15
367.2573853	1.08
370.0688477	0.39
371.2139282	0.23
372.2286987	0.12
382.9104614	0.60
384.2231445	1.66
385.2888794	4.48
386.4321899	0.09
389.1964722	0.45
394.6500854	0.04
396.2086792	0.08
397.3819580	0.28
398.4485474	0.13
399.1047363	0.04
400.6260986	0.06
401.4578857	0.61
403.1263428	100.00
403.7827759	0.21
410.7632446	0.04
412.0563965	0.37
415.3599243	1.30
417.2819824	0.21
419.0728149	0.74
427.6618042	0.23
428.2903442	0.13
429.0111084	0.22
432.2132568	0.04
433.2017212	0.12
445.2105713	2.12
448.3540649	0.05
456.5543823	0.05
465.4387207	0.14
469.2924805	0.05
474.1647339	0.05
481.2937622	0.16
484.4497070	0.28
497.4080811	0.11
501.4097900	0.18
503.4175415	0.05
504.4218140	0.37
505.4955444	0.06
506.5128174	0.45
512.3265991	0.10
516.1032715	0.17
517.4909668	0.18
518.5283813	1.58
519.2377319	1.74
520.3723145	0.07
521.6208496	0.33
527.9030762	0.03
528.9091187	0.09
532.9306030	0.23
546.2409668	0.61
547.1854858	0.25
550.2022095	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9916
Annotation	Unknow
Peak:m/z	Relative Intensity
113.2068176	0.04
114.8843155	8.04
119.0352478	0.02
132.9445343	100.00
133.8872223	0.03
134.8533020	0.03
139.0823364	0.05
141.1878357	0.02
143.1003418	0.07
163.2489624	0.03
185.0655975	0.03
188.9293213	0.04
215.1882019	0.09
216.9177551	0.03
218.1430664	0.07
218.8816833	0.12
226.6401367	0.19
230.9451599	0.04
233.0813293	0.06
242.9410095	0.04
245.0523682	4.22
253.1754761	0.19
259.0854492	0.20
260.1361084	0.05
261.1877747	0.04
273.0511780	0.03
275.4742126	0.04
276.3394165	0.09
276.9989624	0.03
286.6195068	0.41
287.3229370	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
106.9924927	0.07
116.9098892	0.53
124.1025162	0.02
134.9933777	0.47
141.085022	0.07
144.9275665	2.98
161.0966034	0.03
163.0357361	100.00
163.7127686	0.03
192.946106	0.41
214.3009949	0.02
254.1539307	0.03
263.4700317	0.03
264.1913452	0.01
264.9086914	0.02
279.4400024	0.01
283.6626587	0.04
297.059967	0.03
309.1477661	0.03
310.5177612	0.02
313.0602417	0.09
314.0214233	0.04
319.4748535	0.01
326.3476257	0.01
337.1858521	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1118
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9553070	0.44
98.9491196	0.02
107.0645676	0.04
108.9378052	0.35
110.9989243	0.03
117.0895386	0.07
123.0054626	0.02
126.9189911	4.15
133.2717285	0.14
135.0519409	0.02
137.0273132	0.02
139.1256714	0.10
140.9425964	0.03
144.9958191	6.61
159.1434937	0.05
161.1453247	0.21
162.9604645	10.97
165.0372009	0.24
167.2807312	0.03
169.1608276	0.08
175.2394104	0.04
177.2860413	0.07
181.1414032	0.34
182.1689148	0.01
182.9850464	0.04
189.1620789	0.03
191.2139587	0.01
192.9122467	0.68
194.8529205	0.14
196.9993286	0.02
198.9590759	1.21
201.5555725	0.04
205.1684875	0.57
207.1914368	0.15
209.6694946	0.04
211.0965881	1.23
212.2902832	0.09
216.9235535	2.22
219.2454529	0.16
222.5124817	1.04
223.1828918	1.97
225.0308838	0.46
229.0746460	1.44
231.3105164	0.04
233.0656128	0.02
235.0457458	0.38
239.5810852	0.09
240.9343262	1.03
243.1294861	0.24
247.0435486	2.66
250.2894287	0.04
251.2615662	0.02
253.0016785	8.15
255.1070557	0.05
256.3299866	0.06
258.1776123	2.85
258.8904419	11.10
259.6734009	0.02
261.1322937	0.45
263.0297852	0.02
268.2376709	2.30
269.2019958	0.55
270.9865112	20.20
271.5963745	0.09
276.9612427	0.02
278.9913940	0.56
280.1614990	0.03
281.1671753	0.09
282.1733398	0.08
282.8299561	0.01
285.5646973	0.05
288.8393555	100.00
289.5964050	0.11
301.4550476	0.03
305.1744385	0.05
307.0562744	7.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1715
Annotation	10-Deoxymelittoside
Peak:m/z	Relative Intensity
144.9908600	0.97
146.0075531	0.05
160.2261658	0.11
162.9922638	11.47
163.9993744	0.72
187.1067200	0.10
188.0990906	0.18
205.1678009	0.15
229.1101379	0.09
234.7218323	0.22
247.0766907	0.56
248.1091919	0.30
289.1162109	0.93
290.2878418	0.13
307.1193848	100.00
308.2293091	16.41
327.5985718	0.11
353.2685547	0.25
354.1488342	0.19
371.4454956	0.06
400.2304382	0.05
405.2789917	0.33
436.1481018	0.09
444.8209534	0.18
449.4734802	0.09
460.9539185	35.20
461.9495544	4.98
462.6814880	0.10
464.2412415	0.41
490.1704407	0.20
498.7233582	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0773
Annotation	Gerfelin
Peak:m/z	Relative Intensity
108.8381653	0.11
110.9308395	2.94
116.9913940	0.15
120.8759766	0.06
122.0437164	0.09
124.9785614	0.12
131.0362701	0.18
132.1017761	0.06
132.9665070	3.00
134.1670990	1.63
135.0461731	27.44
136.9335022	13.16
144.2194672	0.14
149.1013489	0.06
154.9945374	4.84
157.2989197	0.11
159.1749268	0.23
161.0894623	79.93
162.9591370	0.05
173.0230408	3.84
174.3127441	0.05
175.0315552	0.10
177.0334167	0.94
179.0723877	100.00
182.8910828	0.09
189.0857697	0.18
191.1112366	0.10
195.1552429	0.26
199.1008301	3.45
201.2171021	0.17
203.0078125	0.85
205.1169434	0.09
207.1688538	0.32
211.1994019	1.65
215.2040710	0.22
217.1242676	0.19
219.0633240	0.32
221.2732239	0.73
229.1598816	3.87
231.2368164	0.13
232.5896606	0.05
233.3456421	0.04
236.9721069	0.04
247.1383972	4.82
255.1524353	1.76
257.0866089	0.29
263.1299438	0.10
267.2795410	0.13
273.2192383	0.62
289.1184692	15.89
291.1475525	30.42
291.7598877	0.11
299.2846069	0.69
317.1598816	4.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.27
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0720825	0.08
191.0534668	0.04
192.9188232	0.02
195.0371399	0.04
205.0755310	0.30
232.9798431	0.06
234.5842590	0.63
235.2323151	0.26
247.1408386	0.05
252.4172058	0.02
264.2734375	0.26
264.9418640	2.04
265.6529846	0.03
277.1896973	0.05
287.3433533	0.02
288.3843384	0.07
289.1395874	0.42
290.5643311	0.07
291.2190552	0.03
295.0754395	0.05
299.9055176	0.06
307.2407837	0.82
324.5998535	0.33
325.2645264	1.20
330.2307739	0.03
337.1027222	0.06
355.2990112	0.07
369.3608398	0.10
382.5952148	0.02
385.3420410	0.05
387.3428345	0.74
389.5140381	0.01
397.2706909	0.01
403.1358032	0.05
407.4060059	0.09
408.4217529	0.10
409.5699463	0.01
410.4677734	0.02
412.1412354	0.02
417.4361572	0.15
425.4307861	0.41
426.3380737	0.46
427.3639526	0.19
428.3961792	0.04
431.2817383	0.04
433.4430542	0.04
451.3451538	0.08
452.2710571	0.20
453.3658447	0.11
461.6806030	0.02
469.4776611	0.03
470.1080933	0.03
481.4024048	0.03
483.8096313	0.07
484.4604492	0.03
491.3912354	0.03
495.3231201	0.03
516.2666626	0.02
521.3384399	0.03
531.3030396	0.11
533.3181152	100.00
534.0035400	0.04
539.5012817	0.02
543.2800293	0.02
545.5088501	0.15
549.5242920	0.02
551.2831421	0.02
560.5333862	0.09
561.2901001	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1879
Annotation	Dimethoxyscytonemin
Peak:m/z	Relative Intensity
180.9823914	0.04
205.2169952	0.05
237.3151093	0.11
250.9382019	0.06
251.5526276	0.05
264.8176270	0.03
269.2344360	0.06
278.9122925	0.11
289.2897949	0.03
323.0804443	0.41
326.6961670	0.16
339.1322632	0.43
357.2951660	0.06
369.4796143	0.08
381.2214355	0.15
399.0363770	0.24
403.3663940	0.08
407.2611084	0.12
415.4091797	0.03
417.5210571	0.06
427.2587891	0.24
444.0162964	0.06
445.5215454	0.41
477.1641235	0.07
488.7421265	0.03
494.3024292	0.07
501.2352905	0.08
510.6633301	0.05
516.4859009	0.12
517.6353149	0.08
521.3723145	0.17
532.7108765	0.05
533.3319092	0.03
543.5745239	0.03
545.2658081	0.10
546.5657349	0.08
547.4312744	0.15
553.3088989	0.06
559.3680420	0.13
561.1670532	100.00
561.8356934	0.19
563.2597046	0.28
564.4393921	0.09
575.2472534	0.10
576.4642334	0.05
577.6748047	0.06
580.5921631	0.10
587.3213501	0.31
588.1567383	0.26
590.8612671	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.15
Annotation	6'-Hydroxygaruganin V
Peak:m/z	Relative Intensity
104.8179169	0.71
111.0776596	0.39
117.4386902	0.36
119.1215973	1.39
128.0125122	0.36
131.0898743	0.27
131.9419250	0.22
132.9249420	1.10
140.9554749	0.74
145.1494598	0.80
147.0612183	3.72
154.9636230	0.50
160.2989807	1.04
161.0701904	6.59
163.0136719	32.16
165.3432617	0.20
167.1127319	8.99
168.0462341	0.44
175.0143433	100.00
181.0891418	0.94
186.2730713	0.56
187.1265106	2.75
191.1130981	3.38
193.0669708	98.44
195.1126404	0.89
201.1518555	5.31
215.2059021	0.29
233.0958557	0.53
253.1847839	0.42
257.2854004	0.27
259.1850891	0.24
261.1622009	0.29
263.0021667	1.56
281.2219849	3.31
290.2310486	1.52
291.1792297	3.22
294.0844116	0.24
295.0443726	3.95
306.4817200	0.89
312.2601013	0.22
313.2651672	1.36
314.0016785	1.64
317.1735229	0.16
318.6079407	1.00
319.4826355	1.07
323.2739868	20.08
326.4317932	0.24
327.2872314	3.97
331.5870361	1.59
336.4276123	0.33
337.1558838	6.99
338.3822937	0.25
340.2747192	4.40
349.9385376	0.15
355.0576477	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9383087	2.83
87.0512238	0.11
88.9500656	3.24
94.8827057	0.40
96.9979401	0.15
99.1333847	0.17
100.9222794	4.66
105.0755310	0.07
111.2021027	0.05
113.0070190	7.51
115.0556183	1.19
118.9934082	4.13
125.0732269	0.34
127.0717621	0.64
129.0968933	0.60
130.9709625	100.00
136.1708679	0.07
142.9667358	1.52
144.9806824	0.33
148.7920380	0.34
154.9521179	0.12
158.9573212	0.16
160.8947754	0.71
173.0681152	6.41
179.0182800	1.50
183.4058533	0.13
185.0191193	1.01
191.0839081	0.18
202.9826355	1.19
205.1614075	0.27
219.1203918	0.23
220.0472412	0.05
229.0761719	0.03
231.1001587	0.11
233.0997314	0.26
245.1953430	0.10
247.0927124	0.41
249.2433472	0.37
263.1853638	0.12
275.2540894	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9676056	5.48
115.9688110	1.20
131.0132446	0.34
131.9325867	0.06
158.9912720	100.00
159.9678955	26.38
161.2269592	0.02
173.0659637	0.01
184.9986115	0.02
198.9936218	1.76
200.0074463	1.36
201.9872131	0.01
217.0038147	0.66
218.0783997	0.46
228.9792175	18.82
230.0411682	11.67
237.6210327	0.00
245.0712280	0.29
246.0285950	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1033
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.8659210	0.62
87.9034424	100.00
120.0005188	0.08
136.9481049	0.14
146.0415955	11.49
149.2274780	0.11
168.9130707	0.19
173.9095459	0.18
176.1944122	0.04
179.1122131	0.06
199.2530060	0.20
200.4528503	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.0856
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9000549	0.06
148.9216309	0.05
151.9326782	0.06
159.9623260	0.23
166.3104401	0.04
167.1725616	0.06
168.0331421	0.05
171.1729126	0.04
177.0460815	0.34
178.9867401	0.64
181.0104675	0.09
184.9059448	0.10
191.1791992	0.05
192.1579285	0.09
193.2863464	0.11
195.0410156	0.03
197.1347961	0.18
204.9786530	0.03
209.3019104	0.06
210.2015839	0.61
210.9627991	0.15
212.0914154	0.25
213.0177917	0.04
219.0713806	0.35
223.1410980	0.12
226.2107849	0.03
228.2548981	0.14
229.2062378	0.09
230.1638794	0.11
230.9716187	0.21
234.0145874	0.04
236.4675293	0.06
237.2338104	0.19
243.2304382	0.15
246.2248535	0.03
249.7355194	0.04
253.2003632	0.30
254.1596680	2.99
255.2735596	0.10
258.1950073	0.03
262.6930847	0.06
265.2484131	0.02
267.0233765	0.07
267.9104004	0.04
269.0256042	0.42
270.1156616	0.11
272.1726990	2.09
278.3948364	0.03
280.9761963	0.14
281.9517822	0.06
283.1625366	0.04
285.1558228	0.08
288.1544800	2.62
289.2490234	0.11
293.9540405	0.10
295.2745361	0.13
296.1733398	0.13
297.1442871	0.15
299.2406006	0.02
301.2617798	0.04
306.2224731	19.41
310.4551392	0.01
313.9623413	0.16
315.3672485	0.25
321.0877075	0.08
322.3562622	0.26
326.2349243	0.03
327.1762695	0.05
330.1816406	0.08
332.1555176	0.11
333.1115112	0.08
335.1145630	0.21
336.1731567	0.06
338.1724243	0.27
340.3226318	0.28
341.2000122	1.08
345.3142090	0.39
347.2462769	0.08
348.2241211	0.13
350.2658691	0.04
351.2677002	0.03
354.3653564	0.10
356.4301758	0.03
358.0595703	0.10
359.1723633	0.27
361.2833252	0.16
362.2498779	0.05
366.3150024	0.42
368.3585815	0.05
371.4465332	0.20
372.2010498	0.05
373.2386475	0.19
374.2329102	0.14
377.2711792	0.04
379.3315430	1.19
380.2440796	0.54
382.2527466	0.02
387.1291504	0.08
389.2504883	0.27
391.3649902	0.86
392.2323608	0.16
393.3502808	0.04
395.3184204	0.10
397.2793579	0.53
398.3121338	1.48
399.3359985	0.05
400.2400513	0.06
402.8469849	0.05
403.4491577	0.03
405.2570801	0.39
407.6058350	0.05
410.2172241	2.21
411.2191162	0.14
413.7177734	0.03
415.1227417	0.77
417.4113770	0.73
422.2825928	0.06
423.3482056	9.32
426.2395630	0.24
427.3743896	0.11
431.2150879	0.08
433.4940186	0.03
435.3101196	3.80
435.9213257	0.02
436.9265137	0.20
439.2989502	0.09
441.2456665	2.67
444.2524414	1.28
449.2427368	4.04
453.2220459	0.05
455.2687378	1.06
457.2930908	1.98
465.1576538	0.12
467.2301025	33.31
468.0617676	0.17
473.2360840	0.16
475.2977905	4.65
483.2745361	3.39
485.3080444	13.63
489.1952515	0.05
501.1754150	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.0961
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9972687	0.03
160.0522461	0.58
164.8517303	0.04
165.9547729	0.06
167.2420349	0.07
169.0614319	0.11
170.0046692	0.10
171.0261536	0.07
172.9444580	0.07
176.9819031	0.13
177.8496552	0.06
179.0140381	0.31
185.0006866	0.40
185.8727417	0.02
191.1122284	0.14
192.8305359	0.03
194.9755554	0.12
196.1474304	0.26
197.2313232	0.19
201.0433044	0.36
202.0214996	0.44
206.4531097	0.05
210.4064941	0.34
211.0374451	0.06
214.1625977	0.03
223.7494202	0.03
227.2244415	0.05
228.5007172	0.05
230.1163940	0.56
231.0200500	0.09
235.5153656	0.03
236.1530151	0.38
237.0897217	0.30
242.0187531	0.12
243.2544098	0.12
250.2623901	0.11
254.1596680	2.12
255.1427307	0.19
261.2664490	0.04
263.2152710	0.25
272.1738892	1.04
277.9822693	0.06
280.2278442	0.23
281.3525085	0.15
282.3083801	0.03
284.0993347	0.14
286.2689819	0.14
288.1843262	5.00
292.2723999	0.14
294.1905518	0.13
295.4575500	0.07
296.2482300	0.07
297.2194519	0.09
306.1528320	10.62
306.9691772	0.14
308.4124756	0.11
309.1690674	0.16
315.2788086	0.51
319.1886597	0.06
320.2929688	0.04
322.1768799	0.20
324.3325806	0.05
326.4064331	0.04
328.2298584	0.14
332.1516724	0.03
338.2059937	0.13
340.1520386	0.12
345.2896118	0.43
354.1742554	0.91
356.3728638	0.18
357.1571655	0.29
359.2587891	0.06
363.3313599	0.28
364.3396606	0.04
366.2078247	0.67
372.3630981	0.02
374.4329224	0.08
375.4447021	0.10
377.5505981	0.02
379.2545776	1.15
382.3433228	0.05
384.4257202	0.18
389.3294678	2.21
392.4483643	0.12
393.5800781	0.13
395.2114868	0.30
397.1245728	0.09
398.0825806	0.17
400.1453857	0.03
405.3192749	0.72
407.2590942	1.31
409.3185425	0.83
410.3342285	0.10
411.2797241	0.43
413.4932251	0.06
415.1779785	0.22
416.1903076	0.05
417.0874023	0.15
419.3503418	0.05
423.2944336	13.41
423.9570312	0.10
425.2109375	0.06
428.2428589	0.66
431.3641968	0.05
433.2229004	2.38
435.3728027	0.13
439.3026123	1.32
441.2362671	23.13
441.8443604	0.05
449.0473633	0.29
451.2109985	2.50
455.1685791	0.23
457.2413940	7.84
459.2988892	3.01
462.0895996	0.07
467.3209229	4.35
469.3145142	0.46
470.5795288	0.04
473.1565552	0.55
475.2362061	74.91
475.8408813	0.23
483.3226929	0.15
485.2116089	100.00
485.8407593	0.30
491.2352905	8.01
493.4199829	2.46
501.2245483	2.10
503.3115234	40.64
508.9536743	0.05
519.2655029	24.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.0858
Annotation	Gerfelin
Peak:m/z	Relative Intensity
90.9429321	0.06
94.9166794	0.04
104.9933395	0.10
105.9780197	0.06
111.0842896	0.17
119.0769501	0.27
122.8953857	94.96
124.0068054	0.06
125.3501892	0.08
126.8856201	1.01
136.9421997	1.19
138.9336853	100.00
146.9875183	8.94
149.9264832	0.08
151.0264893	25.20
153.0491028	0.60
162.9593506	0.45
165.0604858	56.47
169.0083466	3.52
181.0253906	0.27
200.5628052	0.24
205.3370972	0.18
212.9946594	0.06
227.1783447	0.24
228.9937439	0.06
231.1220398	0.87
244.9869385	0.16
249.1995850	0.61
255.2167053	0.21
266.2047119	0.07
273.0713501	29.70
275.9967651	0.04
277.1862183	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.183
Annotation	Patuletin 3-rhamnoside-7-(3''',4'''-diacetylrhamnoside)
Peak:m/z	Relative Intensity
230.2921295	0.04
267.9062500	0.01
271.5582275	0.03
276.7248535	0.02
295.1054688	0.09
314.3348999	0.06
315.4176025	0.07
322.0909424	0.02
323.1429443	0.23
341.3072815	0.06
353.2261963	100.00
354.4060669	0.12
359.1936646	0.06
422.3225098	0.06
436.3639526	0.03
463.1381836	0.19
464.3593140	0.03
481.3596191	0.04
494.2286377	0.02
499.3703613	0.04
513.2292480	0.21
514.3362427	0.46
515.3275146	1.18
516.2722778	0.15
519.3643799	0.03
528.3490601	0.03
532.5264282	0.05
533.4391479	0.01
537.3148804	0.58
551.3911743	0.05
573.2800293	0.03
591.4440308	0.03
592.4204712	0.03
597.5022583	0.07
609.1942749	0.02
629.3356323	0.08
646.4371948	0.05
655.6113281	0.04
663.3818359	0.04
671.5870972	0.04
688.9639893	0.08
689.6069946	0.12
690.4415894	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1354
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
173.9478912	0.18
177.0900116	0.12
184.9933014	0.13
187.1234436	0.22
200.9476013	0.06
203.2817383	0.20
205.0350189	0.61
207.1037750	0.10
213.1269684	0.06
215.4541473	0.08
222.1943512	0.12
225.1697388	0.25
227.3119812	0.14
229.1137848	0.03
231.2655945	0.10
237.1078796	2.19
243.2071228	0.29
245.1823120	3.32
247.2881317	0.14
255.0211792	0.50
257.0883179	0.04
258.2289124	0.05
261.2130737	0.04
269.2008362	0.58
271.2041931	0.19
273.1852417	1.82
275.0095215	0.09
283.1339722	0.07
287.1961060	8.49
289.1817017	18.43
290.1829834	0.16
292.9918213	0.10
295.1650391	0.10
297.3759155	0.07
299.1651001	5.89
301.4982910	0.05
303.2800598	0.06
319.1212769	0.27
325.3229370	0.08
329.2472534	0.42
331.3036499	0.61
339.2142334	0.20
341.1002197	0.23
349.0385742	0.05
357.1482544	0.64
363.2894897	0.06
370.4270020	0.06
371.2062988	0.14
381.3501587	0.83
385.3656616	0.06
389.3698120	0.14
392.2907715	0.04
393.4919434	0.03
396.3278198	0.05
397.1041870	0.18
402.1897583	0.07
405.2340088	0.10
407.2503052	46.84
408.2185669	0.11
409.2295532	0.58
410.1974487	0.33
413.1611938	0.34
414.2670898	0.39
415.1296997	0.68
415.8457031	0.09
423.3811035	0.25
425.2003784	100.00
426.2811279	0.04
433.2327881	0.92
437.1566772	0.09
449.2705688	1.11
451.3177490	30.42
452.1680298	0.25
453.5415649	0.05
456.3359375	0.08
461.4842529	0.10
467.2966919	1.29
469.3570557	0.29
471.2681885	0.07
475.3383179	0.08
482.7864990	0.15
483.9243774	0.07
485.9208984	0.08
487.9362183	0.07
491.3473511	3.43
492.1086426	0.91
493.4054565	0.21
497.2363892	0.05
500.3781128	9.95
501.2726440	0.97
513.1885376	0.24
515.4524536	0.19
521.1156616	0.15
527.8995972	0.09
530.6809692	0.24
531.4247437	0.94
532.2577515	0.06
533.2274780	1.80
534.6665039	0.10
546.2254028	0.08
556.5320435	0.15
559.2320557	7.76
560.1655273	0.33
567.5460815	0.17
569.5993652	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.0981
Annotation	Unknow
Peak:m/z	Relative Intensity
138.2907410	0.09
142.9201660	0.24
146.9423065	0.41
148.8103638	0.03
161.1116943	6.55
163.0246887	1.82
178.9104309	0.03
181.8798065	0.03
187.0854492	0.67
197.1523132	0.09
198.0742950	0.14
213.4335022	0.09
215.0505371	0.07
217.1653137	0.03
218.2453308	0.03
226.1156006	0.12
230.9559021	0.57
232.5941162	0.09
233.2553711	0.21
249.1427917	100.00
251.1236877	11.94
259.1589355	0.07
279.4964600	0.07
281.3486633	0.02
283.2191467	0.08
289.2873840	0.05
291.3768921	0.05
293.2326660	0.25
294.5189514	0.05
298.6951904	0.25
304.1770020	0.04
305.4131775	0.09
307.1364136	0.18
312.1993103	0.07
314.2460327	0.04
316.0689087	0.07
319.2814941	0.10
323.2047729	0.03
331.0556946	0.08
332.9312744	0.35
349.2696838	0.08
350.5759277	0.23
351.2167358	0.04
353.2927246	0.11
358.1083069	0.07
359.3030701	0.22
366.5391846	0.09
372.4141846	0.19
376.2967224	0.18
377.2868347	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
97.29564667	1.49
104.9717102	0.56
111.1035156	0.55
114.7665863	1.18
116.8099823	1.77
139.9451752	2.12
142.8479767	0.68
163.4796753	1.13
167.03508	0.99
169.067627	2.10
177.0778656	1.77
179.1403656	1.32
180.1776428	0.62
183.3313599	0.55
195.2770844	3.84
196.8904724	2.32
204.9720764	0.80
206.0328064	0.99
207.2948608	8.38
208.2738037	9.25
209.1238403	5.85
222.2102203	3.96
223.2413483	12.86
233.2031097	6.06
234.3045654	1.18
251.069931	100.00
252.15625	14.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1015
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
102.8096313	0.10
106.9695587	0.10
117.0355682	0.41
135.1035614	0.37
140.0258789	0.08
145.0029907	3.06
147.1768188	0.14
151.257782	0.16
154.7484131	0.12
163.0330353	100.00
165.0916443	0.34
175.0911102	0.54
177.1351929	0.10
190.9368591	0.12
193.0178223	0.57
200.2095947	0.16
201.2415466	0.55
205.1930237	0.15
215.8861084	0.27
217.1208191	0.14
218.1109924	0.09
223.434967	0.09
225.3907166	0.15
227.2825928	0.28
231.169281	0.28
239.1492615	0.44
240.031311	0.09
249.1235352	0.33
251.369751	0.16
261.2085571	0.09
264.9509888	0.28
271.3284912	0.17
273.1111145	0.17
275.2940674	0.21
277.4364014	0.15
280.133728	0.13
281.2424622	0.08
285.0532227	0.28
289.7979736	0.30
290.7919312	0.31
293.3811035	0.08
294.993103	0.42
297.0994568	0.42
309.2485962	1.00
313.8212891	0.80
319.3378601	0.28
323.0458374	0.91
324.3495483	0.11
325.4257202	0.09
327.2989197	1.58
331.8483276	0.13
337.1109009	6.08
338.2349243	0.13
340.1178589	0.47
344.8467407	0.14
354.2749634	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
120.9699097	0.06
123.0273514	0.05
126.1231461	0.36
128.0672607	0.12
137.9789429	0.49
153.0747070	0.58
166.9710083	0.22
168.0177307	1.07
179.0952454	0.22
182.0279694	3.46
183.1719055	0.05
196.9921722	100.00
201.1005707	0.03
229.1814880	0.04
234.0872498	0.08
239.0890503	0.38
242.0162048	0.03
268.9466248	0.03
271.2530823	0.04
286.3127441	0.05
287.0362549	0.01
287.6639099	0.03
312.4390259	0.03
313.1737671	0.08
315.2387695	0.12
317.2453003	0.28
340.3262329	0.05
341.2590637	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.169
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
97.00104523	1.15
99.01353455	0.58
101.0721741	0.11
118.9603043	0.47
122.9431763	0.07
129.039444	0.11
141.3269958	0.14
155.9234009	0.19
162.2339783	0.07
169.975647	2.83
179.1890106	0.09
183.0055237	100.00
184.072113	11.21
185.146637	0.32
197.1019592	8.95
198.1400146	5.34
199.0973358	0.87
205.1185303	0.08
205.8921204	0.13
209.9250488	0.29
211.147522	0.27
212.1667175	1.12
213.293335	0.24
223.2555237	0.48
225.1564026	1.51
226.131897	2.37
227.2573242	0.36
234.9962463	0.05
237.2078857	0.12
238.0154419	0.10
239.2965088	3.52
240.1951904	0.71
243.229248	0.36
247.2346802	5.80
248.4215088	0.71
249.4614563	0.98
251.0097656	0.07
253.1825562	1.63
254.1060791	1.15
255.4661865	0.06
265.3659668	0.12
267.2226257	0.96
268.2866821	0.50
269.4174194	0.27
273.4011536	0.25
274.9708557	0.08
283.2637329	0.12
293.4016418	2.14
311.3233643	12.96
312.2855225	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1097
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
112.9653320	0.11
131.0001526	0.04
132.9088745	0.06
151.0928955	1.89
156.9862061	0.15
175.0006714	0.37
177.1509705	0.04
189.0431213	0.08
205.1129303	0.76
207.3246155	0.09
219.8001404	0.06
221.5978394	0.04
223.1194611	0.14
225.1170959	0.20
226.1593933	0.02
230.1011963	0.15
231.1084900	0.93
239.1828613	0.08
249.1231689	19.21
251.9385681	0.06
255.4223022	0.06
263.2256470	0.02
264.8154907	0.05
267.1381531	100.00
281.1399536	0.04
307.2280273	0.09
311.2501831	0.06
312.2357788	0.15
313.2648621	0.19
333.7088623	0.11
339.2838135	0.36
340.2047729	0.05
341.2011108	0.59
349.3962097	0.03
355.1118164	0.22
356.3540955	0.08
357.3980408	0.02
359.1978760	0.03
364.9812927	0.06
367.3995667	0.02
368.6527710	0.05
373.1455383	0.13
382.2387695	0.30
383.2774658	5.43
384.2762146	0.06
392.3216858	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.2972
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0599213	0.08
223.2413025	0.05
225.1174469	0.16
239.2046509	0.06
251.9580536	0.05
258.9099426	0.04
286.3268433	0.06
287.0651245	0.11
289.2473145	0.23
290.4240112	0.24
299.4036255	0.16
321.2973938	0.18
332.3511963	0.04
337.4025269	0.12
340.4151611	0.12
342.5690308	7.50
343.2100220	100.00
345.3394775	0.06
357.4671936	0.07
361.1287842	0.04
365.4801636	0.12
371.3901367	0.06
372.4627075	0.10
374.5966797	0.14
375.3208008	0.45
381.1927490	0.05
384.3022461	0.17
385.2512207	1.09
387.2474976	0.22
392.5968628	0.06
395.0984497	0.05
399.1853638	0.24
402.2171631	0.07
404.4617310	0.21
409.3978882	0.28
411.4133911	0.12
423.2545166	0.07
425.1940918	0.13
431.7649536	0.07
446.3215942	0.13
449.9700928	0.05
461.2830811	0.34
465.1546631	0.12
466.2271729	0.11
467.0848999	0.11
472.8777466	0.14
493.2857666	0.15
494.3059082	0.24
501.5348511	0.17
504.5632935	0.10
507.6448364	0.38
511.2044678	10.41
512.4185791	0.99
513.4223022	0.50
514.2603149	0.18
519.0768433	0.30
521.5748291	0.21
534.1391602	0.43
535.4332275	1.27
536.2049561	4.43
537.2373657	2.05
538.3154907	0.17
549.3408813	0.32
555.3117065	0.29
560.5172729	0.08
566.0893555	0.27
567.3948364	0.81
573.2852173	0.40
575.0210571	0.41
575.9396973	0.29
577.2351685	0.21
578.3638306	0.25
583.4605103	0.32
584.1876221	0.23
585.1054688	0.07
592.3764038	0.04
599.3001099	0.16
602.2295532	0.35
603.0413208	0.42
611.2312622	0.33
612.6372070	0.46
615.5757446	0.12
620.4533081	0.11
622.3234253	0.31
623.2578125	0.32
630.2401123	0.20
631.7244873	0.21
632.5580444	0.04
635.3920288	0.21
639.7614136	0.28
640.3650513	0.19
643.6202393	0.63
649.7322388	0.10
652.2832642	1.80
653.0278320	0.61
655.5816040	0.29
656.3208618	0.28
657.3635254	0.04
660.4173584	0.40
662.1035767	0.48
666.4852905	0.96
667.7337646	0.37
681.1449585	0.48
682.3990479	4.72
683.1040649	0.83
684.4041138	1.13
685.5800781	1.11
686.4563599	0.34
693.1173706	0.16
702.2494507	0.13
703.2900391	0.48
705.4114990	0.15
707.1426392	0.88
709.6539307	0.23
710.4938965	0.34
711.6255493	0.59
714.9951782	0.16
718.0756226	0.18
720.7390747	0.25
738.4481812	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1351
Annotation	Tetrahydropentoxyline
Peak:m/z	Relative Intensity
111.9887848	0.03
112.9503784	0.23
116.0293427	2.79
125.1585159	0.04
127.9339066	0.11
129.1439819	0.16
130.0685730	0.26
132.1249084	0.04
137.1096039	0.09
141.7811737	1.16
142.4715576	0.05
143.0932007	0.31
157.2405701	0.05
159.0885315	6.18
161.1698761	0.04
169.2062683	0.03
170.3482056	0.07
173.0285645	0.04
176.9716187	0.04
181.0360718	0.04
183.4846802	0.14
184.1129761	0.04
185.1406860	3.44
186.1651154	1.06
193.1703033	0.04
195.1264191	0.03
197.1000671	0.04
203.0491638	100.00
206.9591675	0.03
211.0991974	0.17
212.9436646	0.09
214.0703735	0.04
217.3491669	0.03
224.9743042	0.09
229.1428833	1.34
243.1474304	0.08
245.1429443	1.04
249.2220764	0.04
255.4630737	0.11
257.1906433	0.14
259.1763000	0.03
267.0769043	0.59
273.0894165	0.46
275.1989136	0.16
279.0066833	0.16
281.2431946	0.09
285.0361938	0.09
287.2131653	3.38
291.3832703	0.09
305.3759460	0.09
311.1006470	0.03
318.9387817	0.35
321.2301636	0.83
323.3547974	0.12
334.1342773	0.03
335.5231323	0.03
337.7266541	0.03
343.4854431	0.07
346.5339050	0.15
347.1973572	2.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.1085
Annotation	Androsin
Peak:m/z	Relative Intensity
95.0565109	0.14
100.9785004	3.09
103.0117645	3.67
105.6888580	0.15
113.0005035	6.09
115.0254211	0.22
118.8926926	6.24
119.5302429	0.27
124.8386230	0.71
130.8360596	1.64
142.9708252	2.09
146.9705963	100.00
148.3253174	0.23
149.1044617	1.15
161.0744934	1.01
163.0604248	0.32
165.0378113	15.28
179.0208130	1.56
207.1392517	0.92
213.2490234	0.21
261.7201538	0.13
267.4948425	0.15
283.2328491	0.10
285.1523132	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.1143
Annotation	Tetraphenylphosphonium
Peak:m/z	Relative Intensity
98.9484711	0.42
100.8078003	0.04
102.9350510	0.59
111.1096420	0.07
112.9370117	9.42
117.0726013	0.14
118.9969711	0.07
129.0906372	0.68
131.0461884	0.19
139.0800629	0.12
144.9462433	0.07
149.1765747	0.05
157.0709839	0.79
162.8238373	0.07
175.0258484	2.86
176.0551147	0.04
189.0311584	0.74
191.2925110	0.12
192.9858398	0.23
201.1314545	0.06
205.0426483	1.28
217.0528564	0.10
223.2120972	0.81
231.0446167	8.97
234.2603455	0.14
249.1768799	100.00
261.1539001	0.26
263.1298523	0.09
267.1275940	19.18
277.2150879	2.24
291.2438965	0.12
292.2806396	0.05
293.2965088	0.33
301.1255798	0.98
318.0458984	0.21
319.2313232	25.03
322.2264404	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2137
Annotation	Nudiposide
Peak:m/z	Relative Intensity
159.0910645	0.59
162.9476166	0.13
179.9964142	0.01
186.9699554	1.77
188.0560913	0.71
189.1856079	0.10
193.1981812	0.03
202.1229858	2.97
203.1487732	4.25
204.9017792	0.15
218.0327759	1.28
219.2433777	0.02
220.2012634	0.02
221.2969666	0.03
233.1344299	10.21
235.1587830	0.09
247.1988525	0.29
249.4044800	0.03
250.2492828	0.02
252.3142242	0.12
253.1951447	0.04
264.7673950	0.04
270.2249146	0.01
275.2083130	0.04
301.4116211	0.04
307.1303711	0.17
320.3441162	0.04
325.0228271	0.12
337.1218262	0.02
339.3465576	0.14
340.1112671	0.02
341.4250488	0.01
342.0487671	0.04
345.2622681	0.09
352.0925903	0.02
352.8303223	0.02
354.2000122	0.07
355.1364746	0.03
356.4037476	0.37
357.3052368	0.17
358.0338745	0.02
359.3806763	0.13
367.1331177	0.09
369.2670288	0.12
371.1605225	0.58
372.3961182	0.23
373.2037964	0.33
375.2132568	0.03
379.2911377	0.09
380.0236206	0.01
382.4403687	0.04
383.3243408	0.04
386.2689819	1.87
387.3769531	0.42
388.1632080	0.10
389.2466431	0.22
390.3787842	0.05
391.4063721	0.20
396.3350830	0.02
397.4296875	0.54
399.4604492	0.04
401.3674316	14.80
404.2852173	2.88
405.3458252	0.65
419.2710571	100.00
419.9390869	0.23
431.1199951	0.03
433.2343140	0.06
475.4014282	0.01
487.3868408	0.10
502.0856934	0.02
503.8607788	0.02
505.1597290	0.69
505.7615356	0.02
507.1751709	1.00
517.4337158	0.06
519.3459473	0.25
521.2880249	0.31
523.4362183	0.03
533.4166870	0.03
536.3099976	10.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.7592163	1.50
374.5315247	0.50
458.5991211	9.33
459.7384644	0.97
542.5415649	66.79
543.7747192	3.34
586.6370239	0.72
594.8710938	0.11
625.8515015	3.34
626.4829712	43.31
627.3807373	3.85
628.7045288	2.29
650.8157349	0.24
658.4985962	0.16
687.8901367	0.52
688.5868530	4.88
689.7752686	0.10
709.0050659	0.92
710.4536743	100.00
711.4462280	5.70
734.8220215	0.24
735.5957642	0.12
748.0635376	0.89
748.8107910	5.21
749.9140015	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0928
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
98.7947235	0.04
111.2014771	0.02
119.0634613	0.53
127.0495148	0.02
135.1182098	0.03
136.1221619	0.07
142.8416138	0.03
144.9588623	0.19
154.8374023	0.04
163.0254822	5.05
173.0903931	0.63
179.1234741	0.24
180.0575867	0.27
181.0261230	0.05
191.0156403	100.00
292.3230591	0.03
293.2077026	0.11
309.3583679	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.1011
Annotation	(3S,4R)-6-Acetyl-3,4-dihydroxy-2,2-dimethylchromane
Peak:m/z	Relative Intensity
94.9877930	0.02
103.0599518	0.03
107.0903625	0.03
111.0951691	0.01
117.4058685	0.01
120.9915161	0.04
129.1814728	0.15
131.1050720	2.60
133.1739960	0.09
137.0172882	0.17
139.0041962	0.01
141.0652161	0.40
142.9625702	0.24
144.3306122	0.12
145.1247253	0.10
147.1082764	0.02
148.9470978	0.06
151.1286926	0.09
153.2434235	0.06
155.2227936	0.02
157.0248871	3.39
159.0041656	13.83
160.0317383	0.26
161.0088196	0.11
163.1166229	0.54
169.1046906	3.10
170.0125732	0.38
171.1790619	0.19
171.9660492	0.02
173.0425415	0.24
174.0432739	5.25
175.1214142	4.50
176.0808716	0.15
177.1017914	0.34
183.1789246	0.14
184.8089752	0.05
186.1882019	0.72
187.1302338	1.04
189.0525665	100.00
191.1369171	18.26
199.0810852	0.01
201.0574951	30.04
203.0758057	0.02
204.2616272	0.05
205.1937103	0.02
209.9693298	0.07
213.0502625	0.03
225.6340485	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0982
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
113.1008911	0.02
123.1211090	0.04
128.0650024	0.07
131.1472626	0.02
138.0278931	0.25
143.2742920	0.06
153.0746460	0.61
167.2472839	0.06
179.1183167	0.89
182.0842743	3.72
186.9344482	0.04
192.1210785	0.03
193.9725800	0.02
195.1460876	0.06
197.0373840	100.00
197.9245911	0.02
225.0968628	0.03
239.0504150	0.69
240.2378235	0.03
257.1651306	0.04
268.2359314	0.09
269.1189270	0.08
271.0846863	0.16
279.2407837	0.10
285.3592834	0.01
287.3116150	0.06
288.1574707	0.03
297.2842407	0.03
299.0410156	0.03
300.1645203	0.05
312.0285034	0.04
313.0288696	0.05
314.2285461	0.06
315.0637207	0.05
330.0527344	0.03
336.2497253	0.05
340.0626221	0.09
341.2341003	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	703.2665
Annotation	Unknow
Peak:m/z	Relative Intensity
249.1775208	0.08
267.1818237	0.07
278.8942261	0.19
287.3663635	0.08
300.9930420	0.10
313.9246216	0.08
319.2204285	0.13
329.4272461	0.19
333.2482605	0.11
335.1919556	0.12
336.1521606	0.67
337.0825195	1.56
339.2383423	0.19
351.2551270	14.13
365.3295898	0.23
367.4552612	0.17
373.0986328	0.33
374.2617188	0.06
405.3709717	0.13
415.1849365	0.23
423.3609619	0.05
435.1170044	0.09
449.4180298	0.03
453.2330933	0.12
465.3095093	0.20
485.3332520	0.45
493.2359009	0.26
494.7108765	0.24
498.3623047	0.08
501.2468262	0.06
504.4671021	0.08
505.2648926	0.09
509.5070801	0.32
511.1970215	100.00
517.2308350	0.10
523.6414185	0.10
527.3897095	0.31
529.1953735	1.17
539.6651611	0.11
540.8132935	0.28
547.3991089	0.13
550.3759155	0.08
573.4833374	0.05
578.2075806	0.07
581.6404419	0.10
593.8823853	0.23
595.8806763	0.15
601.2812500	0.16
607.4461670	0.15
613.2418823	0.09
615.6981812	0.46
616.4213257	0.22
617.3277588	0.05
618.1919556	0.11
630.4891968	0.18
641.4852905	0.04
655.0855103	0.07
657.3448486	0.78
659.1972046	0.07
660.9862671	0.42
667.4259644	0.13
670.0711670	0.11
671.5451050	0.10
673.4568481	0.05
679.3132935	0.29
680.5565796	0.28
682.3543701	0.48
683.3598633	0.19
684.8842163	0.66
685.8664551	0.64
694.3118286	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9394
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0085449	0.53
229.0657654	0.05
245.1658020	0.02
272.9898376	100.00
309.3331909	0.02
313.1117859	0.01
329.1658020	0.06
341.1901550	0.99
342.8771362	0.02
357.3042297	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.0561
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
54.9442596	0.27
58.9589653	3.14
65.1064453	0.09
70.9700470	6.01
73.0279922	0.70
74.9057159	0.10
80.7993240	0.22
83.0569458	0.18
84.0000305	0.06
84.9726868	3.71
86.9276428	2.46
88.9863052	25.57
91.0051422	1.63
96.9318848	0.92
97.7349091	0.07
99.0153351	1.08
100.9938812	15.22
102.9118958	1.39
106.8497772	0.64
112.9368896	5.94
115.0059052	1.35
118.9495850	18.72
121.2209930	0.09
125.0320892	1.50
127.0613403	0.60
131.0317688	31.27
132.9806213	0.24
137.1525879	0.07
143.0073242	9.61
145.0512238	1.48
148.9831390	38.44
161.0587921	4.50
163.0899048	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0754
Annotation	Sinapic acid
Peak:m/z	Relative Intensity
84.99703979	0.06
104.8565521	0.02
107.8821259	0.04
108.7954865	0.03
120.8889313	0.01
146.8942566	0.08
165.2123566	0.08
179.0275269	0.09
181.1105804	0.19
183.1147919	0.19
183.8537598	0.02
189.1232452	0.08
193.134964	0.11
195.1564331	0.23
196.112854	0.02
197.4305573	0.02
204.3033295	0.03
207.07164	100.00
208.4356842	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.1872
Annotation	Gnetifolin K
Peak:m/z	Relative Intensity
163.9884796	0.06
165.1087646	0.30
177.2248077	0.06
179.0449829	0.38
193.0288544	0.51
195.1457977	4.98
196.1183777	0.68
201.8989258	0.12
203.3789368	0.21
204.1513824	0.04
208.1022644	2.14
209.2107849	0.19
211.2184448	0.02
218.1301727	0.03
219.2971191	0.05
221.1672974	0.54
223.1165009	28.71
224.1188049	3.35
224.7768097	0.05
237.1328735	0.05
249.2433167	0.05
265.1380920	1.01
266.4565125	0.16
272.4156799	0.02
282.4450073	0.06
290.6930542	0.02
296.1837769	0.05
297.2816467	0.06
315.1644592	0.26
325.3770142	0.08
345.4212646	0.02
355.3034058	0.32
359.4281616	0.06
371.3021240	3.69
372.2120361	0.45
373.3396606	1.66
375.4313354	0.04
385.1663818	0.12
387.1330566	0.06
389.3423462	0.07
391.9395752	0.04
400.6624756	0.13
401.2678833	0.51
402.3176880	0.19
404.4185791	0.06
405.4045410	0.06
413.2962036	0.08
417.3374023	0.10
419.1580200	100.00
420.1633301	15.35
433.1138916	0.09
435.4524536	0.04
446.3187256	0.11
461.2081909	0.88
462.2536621	0.49
463.4475708	0.06
465.2216187	0.10
472.9537354	0.10
476.2169800	0.12
485.5223999	0.09
490.9347534	0.04
492.3963623	0.07
502.9616089	0.16
521.0083008	0.42
522.0756226	0.07
535.1000366	2.68
536.2476196	0.18
545.3564453	0.10
547.3672485	0.02
553.4430542	0.06
563.4566040	0.06
564.1763306	0.03
566.4509277	0.08
567.1605835	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0752
Annotation	Sinapic acid
Peak:m/z	Relative Intensity
69.11148071	0.01
81.05256653	0.03
83.07170105	0.05
93.02436829	0.01
99.99871826	0.12
104.8214722	0.08
106.7335663	0.04
108.8959808	0.02
119.1143799	0.02
121.0518494	0.01
123.2103577	0.01
126.951828	0.02
135.0348969	0.01
136.9532928	0.02
139.0171356	0.03
140.0490723	0.01
141.0548401	0.03
143.0875549	0.05
145.0469818	0.03
147.215271	0.07
149.0155334	0.04
151.0707703	0.03
151.9198151	0.01
153.1877136	0.02
155.0339508	0.08
162.8867035	0.02
165.0359192	0.15
166.9533234	0.01
170.9835968	0.05
174.0187225	0.03
178.1359253	0.01
179.2262115	0.05
181.080658	0.21
183.1147614	0.20
183.9782562	0.22
189.1351776	0.20
193.0870209	0.03
194.9958801	0.02
197.083786	0.04
201.8308258	0.07
204.6322174	0.09
207.0658417	100.00
208.2297211	0.11
209.080307	0.13
210.1740265	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2825
Annotation	Clerodendrin H
Peak:m/z	Relative Intensity
222.2274780	0.20
237.2089539	0.39
273.0148315	0.10
275.2027283	0.05
297.1583252	0.08
309.2192383	0.16
319.5726013	0.04
328.4101562	0.05
343.3479614	0.38
359.0982056	0.04
365.2377319	0.09
372.2820435	0.25
378.4140015	0.09
390.3381348	1.48
406.2286377	0.09
413.5185547	0.32
416.4620972	0.07
418.4326782	0.08
432.3906250	1.60
433.3117676	0.06
434.2895508	0.05
436.3355713	0.28
440.4692383	0.24
450.4675293	1.17
464.3433838	0.11
467.3986206	0.11
471.3010864	0.10
476.2590332	11.00
476.9694214	0.22
483.3730469	0.05
484.8014526	0.23
485.4240112	1.02
487.3225098	0.16
490.3411255	0.18
491.5562744	0.23
496.4985352	0.42
501.1257935	0.05
503.4746704	0.38
508.3022461	58.84
508.9282837	0.45
509.5285034	0.18
511.1823730	0.31
515.5762939	0.17
517.0004272	0.13
519.2905273	0.06
524.4055176	0.08
527.8056030	0.06
529.4169922	2.85
533.0562744	0.53
545.4935913	0.08
546.2252197	0.12
547.2570190	0.76
553.5493774	0.27
555.4610596	0.10
561.6607056	0.35
571.4688110	3.65
573.4721069	13.84
574.3530273	0.11
586.8530884	0.27
587.5586548	0.63
588.7913208	0.98
589.3979492	4.07
591.6910400	0.11
597.6629028	0.25
603.2651367	0.44
605.3476562	52.50
606.0325317	0.24
615.4185791	20.01
616.1906128	0.15
619.3040161	0.69
621.3182983	0.31
629.4779663	0.66
633.4780273	100.00
647.3636475	56.01
650.1244507	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	368.11
Annotation	Unknow
Peak:m/z	Relative Intensity
108.1413193	0.02
109.0654449	0.01
111.1074677	0.03
117.1044846	0.01
127.0391083	0.13
128.0232849	0.02
134.1354370	0.29
135.1766663	0.02
143.0608215	0.14
144.0541687	0.01
144.9458923	0.01
149.1517487	0.06
155.0505676	0.07
159.9911194	0.01
161.1161957	0.01
171.0495911	0.07
173.0808716	1.67
174.0767212	0.18
175.1316223	0.09
177.9262543	0.02
179.0542603	0.04
188.8966217	0.03
191.0410004	100.00
192.0694885	6.09
193.0500793	5.70
194.0778503	0.36
279.0978394	0.02
323.2298584	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	249.1116
Annotation	Pterosin U
Peak:m/z	Relative Intensity
90.7329102	0.13
94.9603043	0.05
96.9255981	0.26
100.9900970	0.07
104.9528961	0.14
106.8983307	0.36
109.0679016	0.09
114.9393921	0.63
117.0226440	1.16
119.0293427	0.06
129.0192108	5.29
130.9909668	13.15
133.0558777	2.97
137.0817871	0.06
141.0794678	5.05
143.0539703	2.71
144.0232849	0.18
145.0248413	3.16
146.1587219	0.46
146.9750061	1.78
147.9632416	0.07
148.9495087	0.10
152.9909515	2.08
155.2795258	0.12
156.9571381	10.40
159.0158234	46.95
159.8067322	0.08
161.0568542	14.33
161.8365631	0.08
163.2044373	0.16
164.9936066	0.07
167.1282806	0.95
169.1920929	0.22
169.9925995	0.19
171.0313721	9.21
173.0543518	10.11
174.0299225	1.60
175.1179504	3.67
178.0524597	0.54
178.9936676	0.19
181.0138245	0.82
184.2113953	0.26
185.1539307	0.75
187.0110626	100.00
189.0725708	54.10
190.0087433	1.57
191.1442871	0.28
192.0866547	0.12
193.0053711	1.39
197.1172485	0.21
199.0466156	12.36
200.0404968	0.51
201.1583405	0.51
204.0601349	25.09
205.1614227	2.15
206.2355347	3.22
207.1856842	0.24
213.2938538	0.40
216.0586395	4.52
217.0797882	5.66
218.9964447	13.09
221.1689301	47.48
222.2530975	0.14
231.1473999	44.82
234.0253754	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1481
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.8750153	0.28
165.1347656	0.24
166.9067383	0.06
169.4655914	0.09
171.0075531	0.20
178.0853424	0.05
178.9004211	0.42
180.8323669	0.29
183.0445251	0.05
185.1557922	0.18
187.1593628	0.12
191.0574951	0.19
193.1171570	0.05
194.1243286	0.06
196.8688965	0.19
200.9902649	0.36
201.9711304	0.08
203.1781921	0.07
207.0757599	0.46
217.0072021	0.05
218.0537415	0.07
219.1730499	0.05
226.0952148	0.12
229.0944977	2.58
231.3603210	0.20
233.2963562	0.04
234.0756531	0.24
243.0681763	0.60
244.0586853	0.09
247.0544739	21.73
248.1082764	1.86
249.2052612	0.13
253.1322632	0.16
255.3464050	0.36
256.3753052	0.13
257.1076050	0.40
259.1156921	3.61
260.0635986	0.67
261.2216797	0.60
267.1157837	0.13
271.1134644	10.05
272.0662537	1.04
273.2385254	1.71
275.1224976	5.27
276.1175537	0.75
283.1498108	1.51
283.9603577	0.32
285.1466980	0.93
287.1653137	1.22
289.0838013	24.56
291.0874634	54.00
292.1458130	6.38
295.4027710	0.04
297.1241760	0.21
298.9985046	0.85
299.6144409	0.07
301.0969849	15.18
302.1351318	2.17
303.1353760	7.11
304.2172852	1.36
308.1597900	0.11
312.3456421	0.05
313.1627808	0.56
314.3904419	0.06
315.0683899	1.04
316.2094116	0.21
317.3467407	0.26
328.9259033	0.03
330.3679810	0.20
332.9149780	1.39
334.0015259	0.20
343.3087158	0.17
344.5500488	0.27
350.4464722	0.13
363.0974121	0.08
365.3236694	0.06
378.7828979	0.29
382.4468384	0.30
385.3690796	0.15
387.2479858	0.46
391.3105469	0.13
393.7293091	0.07
394.3718262	0.18
399.2946167	0.36
404.8004761	0.18
406.7571411	0.12
409.1471558	57.30
410.1492920	11.57
411.2089233	12.85
412.2548218	2.70
414.8062134	0.22
416.4247437	0.07
417.2866211	0.23
417.9549561	0.05
421.0700684	2.94
422.1059570	0.82
423.1474609	0.49
424.4236450	0.28
427.1170044	100.00
428.0459595	19.89
428.6674194	0.06
431.6981201	0.05
434.3471680	0.31
435.2506104	2.83
436.1781616	0.56
439.1953735	3.74
440.2028198	0.61
441.1616821	0.05
444.0343018	0.41
446.0663452	0.73
447.4893799	0.29
448.4984741	0.16
450.9118652	0.16
453.0618896	5.15
454.1930542	0.72
455.5803223	0.37
458.0897217	0.13
476.4741821	0.07
484.0086670	0.45
490.3189697	0.12
494.2221069	0.05
495.0571899	0.09
515.9821777	0.18
517.4570923	0.10
520.9786987	0.24
525.4122925	0.07
527.4654541	0.10
532.4130249	0.09
533.3239136	0.05
534.9620361	0.20
535.7501221	0.39
538.6806030	0.10
540.3805542	0.22
543.1851807	2.13
544.2706299	0.70
548.4513550	0.06
549.2342529	0.39
552.0036621	0.21
561.1837158	7.77
562.2125244	3.04
563.6823120	0.12
571.2736206	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2878
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
132.8862305	10.21
139.2111206	5.84
147.1186523	8.14
159.1091156	1.85
161.4174042	2.54
165.0954437	2.54
189.1044159	5.76
197.2132874	2.70
205.2209778	1.84
213.4363098	2.77
224.9971924	8.50
227.1955566	5.76
231.3145752	5.07
237.2408447	8.60
249.2358093	5.76
263.3168945	5.76
269.2060547	2.99
270.2922974	8.13
271.2466431	5.45
272.4603271	6.31
278.1299744	12.51
281.5217896	8.81
284.3746643	2.31
299.4088745	7.03
301.4022522	12.59
309.5880432	2.80
310.3796082	12.69
326.2235413	9.78
334.1994629	5.07
335.3583374	9.43
337.4111328	11.60
339.4332581	22.54
341.1094971	5.30
342.5782166	4.38
349.3489685	2.55
350.1426697	3.00
352.1546631	9.78
355.4335632	8.68
357.0801392	13.37
361.0211487	3.80
364.4067383	12.67
366.2471619	14.61
373.1771545	3.01
377.0785217	8.40
378.3805847	2.54
380.321991	7.14
381.1800842	12.32
383.6083984	7.02
391.1862183	22.28
395.4797058	37.82
398.914093	4.38
407.4067688	24.46
408.2702942	100.00
409.3876648	5.17
410.309967	6.78
424.6183777	7.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.2001
Annotation	Hymenoside A
Peak:m/z	Relative Intensity
151.0476227	0.13
152.9147339	0.09
159.2623749	0.18
159.9391632	0.14
161.1358795	0.66
163.1733093	0.23
167.1191559	11.58
168.9860840	1.24
172.0055237	0.14
173.0768738	0.11
175.1337891	8.36
176.0586395	0.06
177.0993195	0.36
178.1276855	0.04
181.1571655	0.09
183.9980469	0.05
186.0760345	0.05
187.1748199	1.85
191.0564270	3.40
193.0970001	11.04
199.0580139	3.13
201.1736298	7.79
209.0434113	2.16
215.4725952	0.27
217.1087036	1.80
226.2638550	0.19
252.1481018	0.17
253.1856232	0.16
257.3197632	0.07
281.3305054	0.22
287.3243408	0.22
289.0794067	0.47
291.2321167	0.20
293.2205811	0.15
295.2692261	0.14
301.3338623	0.07
306.0745850	0.09
307.4356689	0.17
309.2432251	0.17
321.2221680	4.55
322.8602905	0.21
323.4990234	0.51
325.3526001	0.36
326.2522583	0.45
329.3545532	0.12
335.4331665	0.05
337.1812134	0.07
341.2879028	21.85
343.4114380	0.11
351.1914673	0.14
353.2113037	100.00
354.1531372	0.21
355.2325439	46.07
355.8343506	0.06
357.2122192	0.07
361.3128052	0.10
362.3562622	0.10
363.0707397	0.23
365.3944702	0.61
367.3067017	0.32
370.4232788	0.96
371.0657959	8.23
375.3507690	0.06
377.3994751	0.34
379.1119385	0.33
395.1116333	1.02
399.1279907	0.11
401.5491943	0.07
403.1110229	0.13
407.2200317	0.21
409.3515015	0.09
413.3005981	0.10
436.7356567	0.06
446.1321411	0.15
449.5682373	0.14
479.2925415	0.23
485.4016724	0.21
497.5082397	0.37
502.7384644	0.26
503.4143677	0.17
513.6076660	0.03
515.3543091	0.89
516.3001709	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8767090	1.75
215.0433655	0.56
296.7723999	14.12
297.4309998	0.07
298.8452148	22.81
378.3773804	0.17
380.0714722	1.51
380.7196960	19.48
382.6391296	100.00
383.4234924	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1298
Annotation	N5-Dinitrophenyl-L-ornithine methyl ester
Peak:m/z	Relative Intensity
112.9692688	0.62
130.9718018	0.13
135.0480804	0.13
137.0259399	9.67
143.2835693	0.18
146.0332947	0.22
157.0613098	0.19
161.1490173	1.06
164.1580200	0.42
165.1104126	0.11
165.7405090	0.21
175.0432434	0.40
179.0374451	38.83
187.1514282	0.06
189.0540009	0.10
191.0390625	0.19
191.8952332	0.16
193.1054382	0.14
205.2547607	0.07
206.4297638	0.29
207.1033325	3.23
211.0922852	5.49
221.1795959	0.10
231.1306763	2.17
243.1145020	0.24
249.1064453	67.35
267.0961914	100.00
281.1571350	0.10
283.2291870	0.37
295.1543884	0.12
296.3173218	0.10
300.6003418	0.17
307.3527222	0.05
311.2910461	0.10
315.2415771	0.32
325.3027344	1.44
327.1717834	0.35
341.0684509	35.07
341.6934204	0.34
342.4288330	0.05
343.1943359	1.01
354.8291016	0.06
360.3240356	0.12
367.8904114	0.32
369.1513062	6.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
102.9633789	2.45
105.0150909	0.27
106.8717499	1.66
122.950592	1.17
129.0368042	10.93
130.0807343	0.22
145.0307007	0.61
146.036026	0.50
151.0638885	100.00
151.894104	3.50
155.3090363	1.00
157.1233215	0.82
164.8484955	0.99
166.0603943	1.06
167.1059418	3.28
168.0302429	1.63
169.0865631	0.43
178.2303772	0.82
179.1696472	3.45
182.0077667	1.93
185.0144501	6.23
194.0614777	2.63
197.0690155	1.92
198.2849884	1.56
206.9846039	1.00
208.1178131	0.74
211.1042938	0.92
221.18367	6.03
225.1174774	9.30
226.1580963	1.21
235.1060333	1.55
236.2349243	2.11
238.1099243	26.02
239.1897736	3.03
251.2323761	1.78
253.0815887	86.16
254.1512909	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
118.8028870	0.09
137.3168182	0.04
141.1408234	0.07
159.0211334	0.11
160.9479675	0.87
165.3078613	0.03
174.1224060	0.05
176.2830200	0.04
177.2867737	0.22
179.0779266	0.47
181.1704712	0.45
197.1105652	12.99
202.9965973	0.04
205.1197662	0.06
221.3727417	0.06
222.0740204	0.03
223.2706451	0.30
225.2320404	0.04
229.0742493	0.20
237.2799377	0.03
241.1232605	100.00
243.1669617	0.03
247.2470093	0.26
250.1724548	0.06
255.3806458	0.04
265.2426453	0.22
267.1692200	0.06
271.1661377	0.08
273.4230957	0.03
277.0705261	0.06
283.1326294	1.15
289.2648315	0.05
295.1119385	0.17
305.0301514	0.23
307.3067627	0.05
313.0750732	0.49
327.3582153	0.03
328.4821472	0.06
336.3324280	0.10
338.1248779	0.15
341.3261719	0.23
343.2236938	3.26
355.2183838	0.25
357.2000427	5.96
359.1737976	0.26
367.2897339	0.32
373.3289490	0.17
374.4002380	0.11
385.0387878	1.05
385.6602173	0.26
387.4569092	0.17
388.1798401	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	865.1981
Annotation	Mesquitol-(5->6)-catechin-(8->5)-mesquitol
Peak:m/z	Relative Intensity
241.4155731	0.15
243.1408081	0.99
245.2213135	2.64
246.3390656	0.18
255.2239227	0.38
257.0525513	0.19
261.2190857	1.26
262.1485291	0.13
267.2125244	0.08
269.1506042	0.76
271.2817383	0.36
273.2079163	0.71
274.3703918	0.36
277.1372070	0.23
278.2395630	0.05
281.2048645	0.07
282.2467651	0.16
283.7520447	0.09
285.1807861	0.29
287.2316589	19.40
288.9617310	7.51
290.1235046	0.50
291.1059570	0.20
295.2210999	0.45
299.2089844	3.47
300.0819397	0.43
301.2826233	0.09
303.3568420	0.52
309.5422974	0.10
311.1304016	0.45
319.1206055	0.07
320.3614807	0.08
327.3659668	0.38
328.5956421	0.29
329.3020630	0.26
331.4839478	0.15
337.1042786	0.89
338.2597351	0.14
339.2296143	0.46
341.2095032	0.61
345.3264160	0.07
347.3900146	0.09
353.3940430	0.24
357.4846802	0.15
361.3569336	0.51
363.2465820	4.05
364.0549316	0.42
365.3830566	0.36
366.0261536	0.39
367.1766968	0.38
369.3085938	0.14
370.2216187	0.17
371.5564270	0.19
373.0957947	0.14
377.4770508	0.17
379.2092896	0.50
380.2803955	0.32
381.1370850	1.90
382.4023438	0.24
383.3980408	0.39
384.4174194	0.16
385.4118042	0.42
387.0986023	0.26
388.2902222	0.08
391.3374634	0.16
393.4821167	0.36
395.2590637	3.23
396.2666016	0.52
397.5664673	0.34
398.4415283	0.30
405.2420044	9.09
407.2177124	25.30
408.3560181	1.38
409.1068115	0.37
413.2212524	8.60
414.5170288	0.30
416.3079224	0.10
417.2365112	2.04
419.3647461	0.24
421.4171753	0.13
423.1804810	7.82
424.6308594	3.85
425.2481079	23.12
426.1629028	1.35
431.0750732	0.31
435.1811523	2.09
436.9890747	0.91
439.2778931	0.05
449.2415161	20.48
450.3264160	4.10
451.3177490	13.75
452.3274536	2.08
453.2825317	0.50
459.1560669	0.18
465.3175049	1.09
466.2775879	0.35
467.3013916	2.28
468.3046875	0.05
473.2837524	0.08
477.2824097	0.39
478.3624268	0.12
479.6051025	0.10
491.2854004	0.14
493.3392944	1.06
494.4978027	0.28
499.2269287	0.52
501.4579468	0.14
502.3097534	0.26
507.2719727	0.11
509.5095215	0.37
513.2985229	0.53
515.3589478	1.88
517.2382202	1.81
518.3629761	0.13
519.3322144	0.67
525.3121338	2.77
526.2536621	0.51
531.2383423	0.33
533.2167358	7.81
534.3792725	0.93
535.5009766	1.37
536.1364746	0.18
539.2906494	0.94
541.7480469	0.15
543.2832642	13.58
544.3169556	1.77
545.2811890	0.62
546.4329834	0.63
551.3589478	0.16
557.3237305	4.49
558.2575684	0.35
559.3787842	5.12
561.0528564	4.10
562.3908081	0.47
563.4075928	0.23
567.6073608	0.64
569.3092041	5.18
570.3234253	1.50
572.4896240	0.28
575.1732788	32.80
576.2331543	4.67
577.2849731	58.41
578.2968750	4.96
585.1824341	0.97
587.1718750	21.95
588.2431030	3.65
604.2221069	0.38
617.3867188	0.73
618.3045654	0.18
619.2623291	3.43
620.3289185	0.28
625.6101074	0.18
626.3386841	0.60
629.1801758	2.04
630.2653198	0.33
651.2837524	0.60
651.9672241	0.09
653.5173950	0.11
669.3803101	2.04
670.2515259	0.44
677.3253174	7.71
678.4677124	0.71
684.9196167	0.18
693.4118652	0.16
695.2200317	100.00
696.3544922	19.85
697.3692017	0.43
698.3709717	0.04
704.9296875	0.27
711.5390015	0.09
713.2478638	37.35
714.3932495	6.85
721.2579956	1.78
722.3377075	0.61
723.1973877	0.06
725.6065674	0.15
727.3112793	0.08
737.3477173	0.88
739.2257690	56.27
740.3956299	11.54
755.3708496	2.36
756.4127197	0.84
757.3168335	0.41
761.1663208	0.21
779.7809448	0.32
780.5978394	0.34
783.6235962	0.14
789.2853394	0.52
790.1613159	0.16
801.3764648	0.20
802.9824219	0.24
804.0559692	0.39
821.1968994	2.47
822.6584473	0.41
829.5235596	0.64
830.3330688	0.64
844.0679321	0.42
847.2459106	17.68
848.4152222	5.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3298
Annotation	Unknow
Peak:m/z	Relative Intensity
292.1047363	0.08
331.0429077	0.05
345.9352417	0.03
354.3038940	0.03
415.1818848	0.18
431.3117676	0.09
447.3484497	0.14
461.2662354	0.03
475.4456177	0.10
505.5130005	0.09
522.2192383	0.11
541.4595337	0.05
552.5028076	0.08
568.2838745	0.08
586.3642578	0.10
591.1978149	0.05
592.3463745	0.42
593.2536011	0.04
593.8771362	0.08
597.2731934	0.04
606.6342773	0.64
610.0820312	0.18
611.5155640	0.12
637.0523682	0.05
643.5312500	0.28
650.2911987	1.71
651.4302979	1.30
659.4035645	0.03
661.0396118	0.14
669.4345703	0.03
682.4276733	3.50
683.3961792	0.17
685.7668457	0.03
687.3742065	0.10
688.0960693	0.07
705.5741577	0.03
706.6187134	0.13
711.4916382	0.14
718.2918091	0.26
723.7485352	0.34
727.4779663	0.21
729.4010010	1.81
740.9000244	0.09
745.2786255	0.65
755.4656372	0.54
756.9501343	0.13
759.3076782	0.36
761.0894165	0.04
769.6438599	0.18
773.4188232	100.00
774.0983276	0.35
777.5142822	0.23
787.4580078	0.26
802.8910522	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2136
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
159.0183868	0.04
167.9647522	0.04
175.0969849	0.06
177.1307068	0.03
186.8941040	0.05
190.2693634	0.15
191.1851044	0.10
192.7700958	0.06
201.0325775	0.13
202.1248779	0.19
203.1051941	0.18
205.0452118	0.24
207.0539703	0.04
208.3087769	0.04
218.0046692	0.07
220.2753296	0.29
221.1936035	0.21
224.6020966	0.03
233.1282501	0.20
235.1370850	0.28
238.4123535	0.10
243.2332458	0.04
247.2332306	0.06
254.0425720	0.15
291.2854004	0.09
295.0610352	0.15
295.9760132	0.05
309.1953125	0.21
310.1932983	0.05
311.1374512	0.16
315.2396851	0.67
321.3246460	0.04
326.2197876	0.05
327.0165405	0.06
338.2536011	0.04
339.4915771	0.07
341.0617065	0.27
342.3331909	0.03
343.3578491	0.30
345.2900391	0.07
346.2619629	0.04
349.3229980	0.05
351.4571533	0.07
356.4407349	0.28
357.3303833	0.32
358.2376099	0.02
359.3519287	0.20
368.2321777	0.16
369.2741089	0.46
370.6038818	0.40
371.2938843	3.05
372.3848267	0.24
373.2742920	0.04
377.2979736	0.03
385.4196167	0.35
386.5028687	0.21
387.2572632	0.97
388.4201660	2.49
389.4133911	0.88
391.1844482	0.16
397.4447632	0.26
399.4714355	0.28
401.2850952	100.00
403.4872437	0.03
404.8447266	0.12
405.5468140	0.04
413.2929688	0.13
415.6039429	0.12
419.3792114	12.91
420.7666016	0.06
429.2580566	1.23
430.1510620	0.06
432.9876709	0.06
441.7382202	0.13
443.2917480	0.17
455.3791504	0.10
460.2922974	0.04
461.2086792	0.03
463.2442627	0.34
467.6704102	0.43
468.3653564	0.22
469.2656860	0.08
471.2423096	0.06
472.9115601	0.82
473.5493164	0.25
477.8316650	0.08
485.5022583	0.22
489.3845215	0.24
490.1773071	0.20
491.4108276	0.22
499.1912231	0.06
500.5991821	0.13
504.5059204	0.90
505.2829590	1.23
507.2608032	0.22
514.1848755	0.35
515.3900757	0.27
516.0767212	0.58
517.3246460	0.14
519.3264771	0.64
521.4092407	0.43
528.5869751	0.07
532.0213013	0.20
533.2501221	0.50
535.5130005	0.06
536.5913696	0.50
541.3088989	0.05
542.0796509	0.55
543.9276123	0.11
551.5979614	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2245
Annotation	Citbismine C
Peak:m/z	Relative Intensity
281.0909119	0.17
323.1427002	0.10
339.2140503	0.61
341.2015076	100.00
502.8850098	0.09
665.5172729	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1691
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
118.9328308	0.22
127.1302795	0.07
132.9400177	0.10
148.01474	0.13
151.1770325	0.30
155.9484863	0.07
170.0113678	4.16
170.9147034	0.53
183.0067444	100.00
184.0986633	6.56
184.8790741	0.15
196.9743958	4.44
198.0038147	1.53
206.9237671	0.08
210.9504395	1.31
212.0756836	2.89
213.2494202	0.04
214.2220154	0.07
225.0578308	1.89
226.0731506	2.56
226.9910889	0.07
237.0550842	0.11
239.1233521	2.60
240.1068115	1.28
241.0966797	0.08
243.0805664	0.22
247.27005	2.85
248.5028076	0.49
249.3086243	0.55
253.1017151	0.45
254.1217651	0.65
255.3168945	0.06
265.2061768	0.18
266.6647949	0.51
267.4908447	0.44
268.3154602	0.10
269.3074951	0.07
283.0097656	0.10
293.3320312	1.32
311.3308411	13.81
312.1894836	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
88.87038422	0.13
96.81382751	0.08
119.0034027	0.31
155.9158936	0.06
157.0699768	0.20
169.9811096	7.54
171.0978241	0.42
177.1116333	0.06
183.0074768	100.00
184.0333862	8.61
184.986908	0.60
191.1136169	0.10
197.0194855	7.85
198.1104279	5.98
199.3193054	0.19
208.8606873	0.16
211.0533142	2.18
212.0169678	2.22
224.5227966	0.46
225.2061462	2.70
226.097168	2.99
226.9263306	0.11
239.1787109	2.38
240.0496826	0.88
240.6895447	0.23
241.2914734	0.10
247.307251	5.23
248.3096924	0.19
249.3167725	0.52
250.0157471	0.19
253.081543	0.61
254.1035767	0.49
265.3996277	0.27
267.3701782	1.82
268.5141296	0.12
273.0119629	0.07
283.4107666	0.11
293.1992798	2.22
293.8497925	0.06
311.2832642	12.94
312.3938599	1.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
108.9503326	0.06
110.3657684	0.02
110.9764404	0.15
127.2229919	0.04
134.0638275	0.27
137.1724854	0.05
142.9544983	0.07
148.9734650	0.05
155.0373840	0.10
160.1803894	0.15
171.3144989	0.03
173.0648499	1.64
174.9014893	0.16
191.0254974	100.00
193.0906830	4.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.218
Annotation	Ficusesquilignan B
Peak:m/z	Relative Intensity
163.8224945	0.12
165.1533051	0.76
166.1965332	0.10
175.2173462	0.15
175.8522797	0.05
177.0345459	1.29
178.1432800	0.59
179.1053619	0.39
181.0354767	0.38
182.2788391	0.07
191.1484222	0.90
192.0534515	0.07
193.3129730	0.07
195.0070190	5.32
196.2322235	0.54
206.2790527	0.24
207.1085205	0.09
218.3110046	0.02
219.2361450	0.23
220.1909027	0.15
221.2313843	0.46
222.1626587	0.08
225.1188812	0.06
233.7987366	0.08
239.5497589	0.04
251.2507019	0.03
285.0673218	0.20
303.2187500	0.13
309.1171875	0.04
310.5868530	0.08
313.5341187	0.11
323.9786377	0.11
325.1422119	0.28
325.9757080	0.18
328.2054443	0.07
336.2203979	0.05
337.3261108	0.51
339.5200806	0.04
341.2119751	0.21
342.1725464	0.24
343.2850342	3.56
344.1834106	0.72
346.0017090	0.06
348.1688843	0.25
349.3939209	0.06
354.2868042	0.25
355.2680664	1.37
356.2777710	2.71
357.2634277	16.35
358.3433228	3.16
359.4899292	0.12
367.4645386	0.90
368.3261719	1.94
369.2326050	7.81
370.3613281	2.07
371.2059326	0.20
373.2410278	9.40
374.4014893	2.13
381.4143677	0.04
385.1350098	4.65
386.2632446	2.95
387.2747803	41.61
388.3083496	6.06
396.2536621	0.09
403.1489868	0.05
412.3255615	0.09
423.3421631	0.11
424.2911987	0.05
425.0068359	0.03
429.2460938	0.53
430.1607056	0.04
441.2940674	0.58
442.2117920	0.12
459.2986450	0.03
460.4396362	0.09
461.3754272	0.03
485.2574463	0.04
489.3292847	0.04
493.4362183	0.05
502.3565674	0.22
505.3815918	3.47
506.3634644	1.05
511.3504028	0.08
517.2435303	2.94
518.3354492	0.71
520.3297729	0.15
521.5109253	0.32
523.2166748	0.13
533.3869629	0.26
535.3039551	100.00
536.3197632	32.31
537.2971191	0.04
538.4295044	0.03
539.2858276	0.14
540.5178833	0.09
545.2580566	0.13
546.2158813	0.06
547.2739868	0.86
548.2824097	0.50
551.3087769	0.11
553.2113037	11.20
554.3172607	2.44
565.1616211	25.82
566.2562256	5.59
567.1937866	0.09
567.9136353	0.06
568.7449951	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.9821
Annotation	Unknow
Peak:m/z	Relative Intensity
66.9247971	0.10
82.7808075	0.09
95.0558624	0.23
97.1543579	0.04
107.0539093	0.15
108.8565826	0.24
115.2091217	0.04
121.1499329	0.09
126.2182007	0.08
134.8780823	0.18
136.2830963	0.07
137.0156403	0.05
139.0863190	0.07
142.0025940	0.04
149.3040314	0.06
169.0226898	0.45
170.2094879	0.21
171.2326660	0.03
172.1167908	0.06
172.9189606	0.11
173.8831329	0.04
175.3276062	0.04
181.3585358	0.17
182.2714081	0.05
183.1584015	0.15
186.8887939	100.00
188.0509796	0.05
191.1820221	0.18
192.1707611	0.10
199.2129364	0.06
204.7955475	0.78
207.6296844	0.04
209.0360107	0.55
209.9627533	0.55
211.1519470	0.14
227.9640656	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1296
Annotation	Arborescoside
Peak:m/z	Relative Intensity
113.0060730	0.76
118.9800797	0.04
127.1771698	0.06
131.0659943	0.15
132.9426727	0.02
135.1959839	0.08
136.9521942	9.53
138.0312347	0.60
138.9307556	0.10
142.8160400	0.09
146.0689087	0.21
153.9987183	0.03
157.0033112	0.25
161.0819092	0.23
162.1308289	0.04
164.0903320	0.26
175.0925293	0.52
176.1226501	0.03
179.0407104	9.24
180.1734772	0.98
192.1679077	0.04
193.2007294	0.32
202.8905029	0.13
204.8676147	0.08
207.1801147	1.73
211.0692749	5.29
212.0388184	0.65
217.9173584	0.03
218.8490295	0.07
223.1641846	0.02
225.2771606	0.12
231.1329041	2.32
232.1046753	0.53
249.0861511	60.81
250.1091919	7.71
251.1051636	0.07
253.1241760	0.07
253.8923340	0.03
267.1196899	100.00
268.1172485	11.47
281.3010864	0.03
291.1986694	0.02
294.9925537	0.03
295.9093018	0.11
297.2761841	0.13
299.4086304	0.06
307.2388306	0.07
311.0534973	0.14
325.2397766	1.20
326.3197937	0.34
327.0927429	0.14
329.2512207	0.16
339.1907349	0.05
340.4906921	0.86
341.1316833	5.43
341.9191284	0.34
343.3336792	0.79
344.4796143	0.10
351.1524048	0.11
352.2245178	0.13
358.2259216	0.08
359.5021362	0.04
369.2468567	5.49
370.2217712	1.00
378.6664124	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	599.2126
Annotation	Tasumatrol V
Peak:m/z	Relative Intensity
173.4140320	0.12
174.1564484	0.06
174.9930725	0.11
176.1083069	0.09
177.1228333	0.11
178.0899811	0.57
179.1558533	0.13
181.0882263	3.66
189.3871460	0.09
190.0190277	1.00
191.2063904	0.13
193.0654755	5.48
195.1825562	1.90
202.1325073	0.14
203.2096252	0.10
204.0963898	0.10
205.0764923	0.17
206.2990112	0.13
207.0445709	0.19
208.1437988	1.49
209.2871552	0.29
214.2278900	0.06
216.8862000	0.06
221.1821594	0.54
222.0216064	0.37
223.2602539	1.46
231.2816467	0.04
232.1627197	0.18
233.2343750	0.09
238.2315674	0.58
251.1483765	0.05
265.2273254	0.15
271.2151794	0.21
284.3378906	0.08
286.1914673	0.19
297.1531372	0.16
299.2790527	0.09
300.6588440	0.14
301.3845825	0.26
311.0983276	0.06
312.3291626	0.58
313.0852051	0.37
314.0846558	1.26
315.2085571	0.24
325.0460815	0.09
326.2570801	0.26
327.2399902	1.39
328.2580566	3.15
329.3036499	7.04
339.2569580	0.04
341.2182007	1.24
343.2597046	0.31
344.2517090	2.00
345.3371582	0.62
351.5545654	0.21
353.3637695	0.29
354.7084961	0.21
355.3446655	0.22
357.2457275	2.05
357.9932251	0.06
359.2569580	35.29
361.2480469	0.09
367.3033447	0.23
369.3240356	0.10
371.1492920	0.55
372.4026489	0.38
373.2878418	0.25
374.5819092	0.41
379.1616821	0.04
382.3125610	0.09
383.4055176	1.86
384.3574219	0.80
385.2702637	4.18
386.3665771	0.10
387.6259155	0.09
389.3511353	0.04
397.4945068	0.22
401.1541748	1.69
402.0239258	2.99
403.2359619	10.19
405.5018921	0.09
417.3055420	10.99
419.4258423	0.04
433.2893066	0.06
436.6848755	0.06
439.4781494	0.13
445.0906982	0.28
451.9629517	0.20
457.2880249	4.28
459.2589722	0.27
469.2523804	0.05
471.3933716	0.26
473.2523804	0.09
475.3502808	1.66
477.3056641	14.92
478.5085449	0.19
487.4015503	0.20
489.2604980	2.10
493.3988647	0.16
497.1194458	0.19
501.4804077	0.05
503.1914062	0.52
505.5106812	0.72
507.3526611	6.00
508.2237549	0.10
519.3356934	4.56
523.7704468	0.05
525.1309204	0.50
533.3712769	0.29
534.4351807	0.13
537.3303223	0.11
538.2328491	0.16
549.3408813	0.28
551.2951660	100.00
551.9636230	0.67
553.4158936	0.92
554.4121704	0.71
555.4226074	0.83
561.4701538	0.12
562.3507690	0.09
563.1681519	0.72
567.3437500	3.08
568.2560425	0.05
569.4893188	0.05
579.5231323	0.18
581.3154907	17.05
584.4016724	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.1429
Annotation	Isosamidin
Peak:m/z	Relative Intensity
111.0801544	0.10
117.9845200	0.12
119.2922363	0.08
120.9716568	0.20
123.1365128	0.21
126.8759155	0.26
134.0548706	0.16
137.0053711	0.04
143.0711975	0.16
146.9088440	0.07
148.0129700	0.19
148.9814148	0.18
152.9447021	0.45
155.1523438	0.09
157.0839691	0.12
159.1357117	0.11
164.9514771	0.51
167.1452026	1.45
171.3688354	0.10
172.9592590	0.52
175.3411255	0.17
181.0866089	0.18
183.2657623	0.12
185.3110352	0.75
186.1330261	0.31
187.2378845	0.58
191.0572510	1.06
194.0200806	0.08
195.3515625	0.46
196.9692688	0.27
199.0592194	0.21
200.8070831	0.18
203.0394287	1.18
204.9610901	0.46
208.3163147	0.16
209.2640381	0.23
212.6708984	0.05
215.2227783	1.03
217.2470398	0.08
218.9545288	0.58
223.1269226	0.23
228.2983398	0.08
232.7800598	0.16
234.7077637	0.07
235.3441162	1.04
239.1344299	0.10
241.2207031	0.06
247.0372925	0.11
251.1998291	0.19
252.9699097	0.40
255.2378845	0.35
263.1277466	0.10
264.0787659	0.07
268.5956421	0.21
271.0047607	0.08
273.1301880	0.12
274.2856750	0.28
283.2620544	0.21
284.2718201	0.20
289.1844482	0.35
291.0780945	0.85
294.2640686	0.10
295.1653442	0.06
295.9476929	0.40
296.5672607	0.14
298.1899414	0.07
299.4436035	0.23
301.0706787	0.09
306.1922913	0.04
307.3448486	0.07
309.3406982	0.63
312.2167664	0.25
313.2326965	0.62
315.2415161	0.13
317.0843506	0.14
319.2466431	2.91
323.2470093	0.85
325.1873779	0.85
326.3423157	0.10
327.1055603	0.26
328.2418823	0.42
334.3612671	0.18
337.2089233	2.72
339.3413086	4.04
341.1880188	0.69
343.2840576	0.26
349.6135864	0.96
351.2118225	71.30
355.4349670	1.13
357.1988220	37.10
363.2269287	0.59
367.0879211	0.18
369.0671082	100.00
370.1037903	1.13
377.7340393	1.30
386.4627686	0.23
387.2982483	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1503
Annotation	Orientin 2''-O-(2'''-methylbutyrate)
Peak:m/z	Relative Intensity
148.7718658	0.08
155.0594635	0.03
160.0458984	0.41
161.0848694	1.56
161.9745331	0.11
162.9584808	0.10
165.1838837	0.61
170.9067078	0.24
173.1071167	2.75
174.0064392	0.04
174.9619446	0.04
177.0902405	2.88
179.1062622	1.59
191.1106262	23.05
193.2998810	0.21
194.9131165	0.40
200.9938965	0.15
202.3148804	0.38
203.1108704	0.27
215.0672150	16.17
223.1049194	0.04
227.1545868	0.16
261.2646179	0.11
263.2220764	0.08
264.4709473	0.08
265.2071533	0.04
271.2905884	0.23
279.2114258	0.06
280.3156738	0.31
281.2796631	0.36
283.2017822	0.15
288.9684448	0.46
293.1651611	0.04
294.0777588	0.14
295.2176819	0.44
299.0445557	0.35
307.2174683	2.06
308.3214722	0.11
309.1724243	0.48
311.1995850	0.47
313.1950073	1.82
321.3395386	0.04
327.2552490	0.94
337.0259399	0.19
339.1818237	76.82
343.2163086	3.67
351.1595459	100.00
352.1813354	0.30
353.0222168	0.61
357.2351074	11.71
365.2240601	0.31
366.4709473	2.29
367.2369995	8.39
391.2094116	0.25
415.2623901	0.04
468.3072510	0.04
481.2269897	0.07
487.5077515	0.13
494.4397583	0.05
498.8967285	0.32
499.5009155	0.28
501.1832886	0.93
513.2915039	5.68
516.6068115	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2779
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0940552	0.17
144.0453186	0.04
153.0048218	0.08
178.1778259	0.02
196.0258484	1.94
214.1755676	1.46
222.0709534	0.02
224.0523987	0.04
227.2372589	0.03
261.2937012	0.32
270.6181335	0.03
279.2770691	100.00
288.1115417	0.01
327.2962036	0.05
328.2874146	0.04
393.6641541	0.06
401.5632019	0.10
413.5014343	0.02
415.3713989	0.41
420.2535400	0.02
421.1528320	0.01
430.7117615	0.08
440.3238831	0.03
457.6738586	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.25
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0306091	0.33
191.1874847	0.05
193.0940857	0.04
199.4455566	0.15
203.2312622	0.34
205.3689575	0.27
217.4962769	0.06
227.0668335	0.04
234.0273743	0.03
235.2504272	0.09
245.1840057	1.13
247.2691803	0.24
255.2139587	0.05
260.3063354	0.12
261.1023254	0.16
269.1977234	0.31
270.9895325	0.07
273.1089172	0.97
285.1925049	0.08
287.2783813	1.66
288.4978638	0.64
289.2363281	6.98
290.1928711	0.13
293.4533691	0.13
299.1754761	1.79
303.2958679	0.04
324.8435669	0.04
329.1083374	0.32
331.2129517	0.26
339.1903076	0.39
341.3115845	0.20
344.2102051	0.11
349.0968628	0.05
352.1380005	0.11
353.4907837	0.10
368.2905884	0.38
372.2148438	0.06
375.3974609	0.14
377.1752319	0.16
381.2921143	0.63
383.8631592	0.20
395.3511353	0.34
397.1552734	0.32
403.4531250	0.06
405.2412720	0.14
407.3013916	17.04
408.0522461	0.11
409.5914307	0.07
411.2189941	0.05
413.1303711	0.28
414.5500488	0.06
415.2428589	0.15
415.8610840	0.13
423.3236084	0.49
425.2544556	36.86
430.5051270	0.10
433.2930908	0.41
436.5903931	0.10
437.2281494	0.14
438.4027710	0.11
440.9817505	0.06
448.5312500	0.20
449.1801758	0.25
450.6024170	0.88
451.2734375	7.16
452.4589233	0.09
453.2743530	0.08
455.8867798	0.13
465.2258911	0.11
467.3922729	0.05
468.1153564	0.05
471.2825317	0.08
478.4147949	0.23
479.4660645	0.25
480.1709595	0.10
480.9741821	0.30
482.5641479	0.14
486.1546021	0.18
486.9523315	0.06
490.2526245	0.35
491.2330322	1.66
491.9120483	1.46
493.4832153	0.07
499.4287720	0.20
500.5487671	3.42
501.3849487	0.60
502.5553589	0.14
505.3181763	0.08
510.4920654	0.07
518.5258789	0.14
520.1473389	0.04
521.3815308	0.28
524.0740356	0.09
527.3444214	0.07
529.3909912	0.05
531.2861328	100.00
531.9295044	0.36
533.4179688	0.64
539.2830200	0.05
540.0442505	0.22
541.3518677	0.36
554.2227173	0.07
555.3854980	0.24
558.2619019	0.32
559.3793335	5.00
561.2244873	0.27
567.3722534	0.11
588.4000244	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
98.90548706	0.11
114.9416275	0.36
123.3284454	0.13
156.0409546	0.26
168.2532959	0.17
169.1428528	0.55
170.151947	4.65
183.0139923	100.00
184.0877686	13.89
184.9723816	0.35
197.0514221	20.98
198.06633	7.48
208.8852539	0.20
211.1272278	3.68
212.0891724	3.72
225.2239685	3.61
226.2113342	3.22
227.1766052	0.74
235.2852173	0.41
239.2902527	3.48
240.2356262	1.84
240.9372253	0.12
243.3123169	0.63
246.7346802	1.25
247.3584595	8.61
248.3632812	0.76
249.0709839	1.25
253.0943909	1.17
254.1310425	0.86
255.1520386	0.21
263.2817383	0.75
265.4150391	0.23
266.3720093	0.45
267.2815247	4.62
268.4542847	0.57
273.1211548	0.16
275.3743896	0.82
283.2644043	0.47
292.2001953	0.77
293.1883545	6.32
295.1782227	0.11
303.1980896	0.19
310.4193726	0.15
311.3353882	11.42
312.3251343	2.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	339.1241
Annotation	Sophoraflavanone B
Peak:m/z	Relative Intensity
96.2133026	0.04
119.1237488	0.02
134.8046875	0.03
146.2264404	0.07
159.9186707	0.04
161.1732788	0.22
164.0008240	0.13
179.1155090	1.66
183.0385590	0.02
197.1461487	0.05
203.1673889	0.02
220.1860352	0.01
240.3618469	0.04
247.1998291	0.01
255.2662659	0.03
267.0493774	0.01
276.1356201	0.06
277.3340454	0.07
278.3669434	0.04
280.2613831	0.14
291.4803772	0.22
292.1820679	0.17
293.3322754	0.09
294.2385864	0.11
295.2602539	0.16
296.3129578	0.03
297.2482300	0.09
306.2572632	0.32
307.1925964	5.19
308.2351685	3.85
309.2473755	5.50
311.1167603	0.03
318.3347168	0.01
319.1330872	0.02
321.2030029	0.60
322.4913330	0.07
324.2231445	100.00
325.1607666	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	664.1542
Annotation	Unknow
Peak:m/z	Relative Intensity
215.9650879	0.02
267.2296143	0.01
299.3784485	0.02
334.9337769	0.03
335.5695801	0.03
350.0803833	0.02
361.2095337	0.13
363.2537842	0.18
365.2157593	0.06
370.8836670	0.02
379.2120361	0.04
389.1987915	0.13
402.7460938	0.01
405.2939453	0.27
407.2305908	1.63
414.8697510	0.02
433.2197266	0.73
449.6354980	0.39
451.1956787	100.00
451.8387451	0.11
458.1818237	0.02
467.2008057	0.01
468.6901245	0.03
469.3584595	0.04
481.0450439	0.02
483.4524536	0.01
502.2142334	0.01
516.3747559	0.04
533.9376221	0.01
547.3220825	0.01
549.0549316	0.01
574.2515259	0.01
576.8914795	0.05
578.1076660	0.07
587.3309937	0.01
588.3385620	0.05
602.2884521	0.05
605.7056885	0.01
607.4700317	0.02
608.5159302	0.02
620.0858765	0.15
646.0106812	0.66
646.6383667	0.04
647.6146240	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	753.1487
Annotation	Unknow
Peak:m/z	Relative Intensity
199.7371521	0.05
215.1710052	0.08
216.4097900	0.09
233.0248108	8.41
234.1845856	0.74
237.1615906	0.08
245.2375183	0.08
247.0548248	0.20
255.0490112	0.09
288.2515259	0.11
290.9186096	0.08
308.1794434	24.79
309.3223877	0.96
336.0351562	0.09
367.9212036	0.04
399.9705200	0.37
410.5284424	0.18
411.3629761	0.12
417.9348755	0.23
429.0187988	0.38
446.1776123	4.59
447.2739258	0.16
462.8799438	0.03
475.2163696	0.14
478.4404297	0.07
527.2351685	0.13
531.3176270	0.16
540.4942627	0.24
543.0583496	0.07
545.2593994	0.06
556.4408569	0.05
557.1533203	0.22
575.3933716	0.05
596.3380737	0.13
601.3123779	0.14
608.1128540	0.25
644.2148438	0.19
650.1083984	0.79
651.1151733	0.06
660.2999268	2.33
661.3016968	0.36
668.7301636	0.05
678.1273804	100.00
679.2160034	12.10
688.2286987	0.08
691.6087036	0.19
692.3276367	0.33
699.3016968	0.11
708.4002075	0.06
717.2401733	1.73
718.4058228	0.15
735.2350464	29.11
736.2575073	2.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1974
Annotation	Paeonidanin A
Peak:m/z	Relative Intensity
175.2113800	0.02
177.1104889	0.42
178.1792908	0.02
179.1738129	0.17
181.0395050	0.35
182.0861206	0.09
190.1443481	0.42
191.1504364	0.97
192.2291565	0.23
195.0058899	2.70
196.2256317	0.29
207.2870789	0.10
220.3168793	0.07
235.1370239	0.03
249.2756348	0.09
251.3093567	0.05
273.5462036	0.02
288.5996704	0.03
293.3046875	0.08
295.3225098	0.18
308.2514954	0.08
309.2203369	0.48
310.4914551	0.04
312.3739624	0.06
313.3125000	0.53
314.2889709	0.10
319.1478271	0.03
323.2348022	0.11
324.3027344	0.61
325.0911255	0.03
326.6679688	0.28
327.3694458	1.28
328.2071533	0.14
328.8094482	0.08
329.4304810	0.03
330.2097168	0.14
331.6337280	0.02
336.1131592	0.05
337.2467041	0.12
338.4658203	0.95
339.2449951	4.64
340.2843628	1.19
342.8945923	0.15
344.2567139	0.12
348.4578857	0.03
351.3601074	0.61
352.2170410	1.92
353.3219604	1.94
354.4561157	0.26
355.2846680	0.78
356.2279663	0.77
357.2001953	7.34
358.3663940	1.57
359.1599121	0.03
360.6889648	0.03
366.9771729	0.03
368.3165283	2.77
369.2639160	3.73
370.3125000	1.95
371.2637939	25.78
372.3098755	4.22
374.3347778	0.04
379.3057861	0.02
381.2489014	0.14
383.2255249	100.00
384.2343140	20.35
384.8612061	0.08
385.5288086	0.02
387.0504761	1.19
388.2143555	0.09
397.2540283	0.31
398.0961304	0.14
399.2656860	1.32
400.3967285	2.03
401.1491699	3.02
402.1895752	0.67
409.0817261	0.08
411.3935547	0.05
417.3237305	0.17
418.3589478	0.05
425.3331299	0.08
429.3577881	0.35
430.3753052	0.03
435.3131714	0.13
437.2093506	0.10
444.3445435	0.07
455.2760620	0.32
456.4078369	0.02
469.2271729	0.03
473.2934570	0.40
475.4476929	0.18
476.3432617	0.07
477.5382080	0.23
478.3966064	0.22
484.1848145	0.02
487.3707275	1.07
488.4495850	0.45
493.2637329	0.06
505.3319702	8.20
506.3668823	1.74
510.2102661	0.02
512.3851929	0.04
515.2230835	0.09
517.5485229	0.05
519.3251343	1.52
520.3305664	0.37
523.2962646	5.49
524.4145508	0.78
531.3102417	6.45
532.3754883	1.60
535.2490845	3.93
536.3074341	0.96
539.5001221	0.03
549.2830200	71.52
550.3051758	22.91
551.1570435	0.09
553.3110352	61.19
554.3247681	15.14
554.9351807	0.10
559.3148193	0.06
560.9316406	0.14
561.5352173	0.10
562.4592285	0.17
565.7758179	0.05
567.2338257	7.34
568.3124390	2.75
579.1275635	22.17
580.2110596	4.49
583.2340698	0.11
597.9338989	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.276
Annotation	Unknow
Peak:m/z	Relative Intensity
191.2401123	0.11
205.3366394	0.08
210.8168945	0.11
230.1029663	0.03
243.9950867	0.10
261.1507263	0.06
280.0357666	0.06
286.2788086	0.03
351.5196533	0.08
352.1698608	0.02
354.3279419	0.04
359.5848389	0.08
361.0358276	0.09
366.4932861	0.07
383.0674438	0.23
384.2142334	0.16
385.2542725	0.07
386.5929565	0.11
393.3471680	0.11
405.3262939	0.13
419.4220581	0.03
451.5177002	0.09
481.2132568	0.05
498.2120361	0.08
507.3225708	0.07
509.5187378	0.05
533.3979492	0.04
534.1453247	0.14
544.3849487	0.05
548.9605103	0.20
551.3179321	100.00
552.0220337	0.28
552.7003784	0.08
553.4531860	0.04
574.5811157	0.40
579.0363159	0.79
582.4227295	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1016
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
116.9980316	0.32
123.2488403	0.16
133.0841675	0.17
133.992981	0.26
135.0300293	0.17
145.0118256	2.40
145.9588318	0.04
147.1871643	0.11
157.0392761	0.17
161.032074	0.08
163.0357208	100.00
174.7482605	0.04
179.0551758	0.45
180.8617554	0.22
188.9165344	0.05
193.0305176	0.23
200.9643555	1.63
206.18367	0.15
206.9262085	0.12
211.2218323	0.08
219.1412048	0.09
221.0809021	0.32
231.0789185	0.32
233.8502808	0.07
237.1450195	0.24
239.2870483	0.14
247.1338501	0.03
248.8183594	0.07
255.4170532	0.15
258.2745972	0.03
261.1830444	0.40
262.2228394	0.07
262.9810181	0.06
264.0697937	0.08
265.244873	0.11
270.1716309	0.08
274.2649231	0.23
277.0128784	0.04
277.9559326	0.08
282.6339417	0.09
286.1560364	0.10
287.3438721	0.08
288.3101807	0.09
290.1092529	0.14
293.0349121	0.14
295.1967773	0.18
296.5456543	0.14
297.3048706	0.07
299.2475281	0.07
301.2466125	0.12
305.0820618	0.35
309.0290527	0.72
311.2003784	0.17
318.244751	0.17
319.1954651	0.05
323.105835	3.02
326.4543152	0.37
327.3410645	1.14
331.3384399	0.11
332.0769958	0.03
336.3155518	0.04
337.2216797	1.69
338.196228	0.97
339.4833679	0.16
340.3864746	0.11
345.3465881	0.43
346.3591003	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1743
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
167.0822449	0.05
176.8652954	0.05
186.8713226	0.15
191.1768188	2.53
192.1352539	3.30
193.1959686	0.09
193.8928223	0.07
197.2798767	0.03
199.1321411	0.03
233.3407593	0.05
245.2717896	0.12
246.0828857	0.07
248.0629578	0.11
279.0823059	0.05
295.1271973	0.36
298.3375549	0.07
307.2724915	0.23
310.2222900	0.11
311.3798828	0.05
312.9204712	0.14
315.1378174	0.05
321.2296143	0.14
323.1425781	0.04
324.1965332	0.09
325.2611694	0.38
329.0149536	0.07
341.2858276	0.63
353.2081299	3.23
357.3084717	0.11
362.9177856	0.09
368.3425293	0.16
369.4938354	0.13
371.1812744	100.00
379.3560791	0.09
381.4586792	0.08
393.8709717	0.03
395.3456421	0.14
400.3277588	0.05
401.1478271	0.07
406.4818115	0.20
409.2185669	0.33
415.3054199	0.05
417.0766602	0.26
419.3079834	0.05
423.0614624	0.03
424.2780151	0.04
427.5735474	0.08
437.2850342	0.07
438.0128174	0.07
452.9455566	0.07
457.8470459	0.33
468.9760132	0.21
471.4566650	0.29
472.2391357	0.04
474.0232544	0.14
481.0732422	0.09
483.0496826	0.05
499.0839233	0.05
504.4573364	0.13
524.6586304	0.15
526.1163940	0.06
532.5914917	0.17
533.2037354	0.17
535.1835327	0.09
544.1978149	0.61
545.3958130	0.69
546.3809204	0.05
547.4123535	0.08
548.1331787	0.16
560.7581787	0.05
562.2346191	0.07
573.6769409	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1065
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
104.1396179	0.03
119.0232239	2.44
124.1044006	0.03
146.9250183	100.00
151.5169067	0.01
164.9403381	0.08
169.9463501	0.07
175.1346741	0.01
176.9710083	0.03
223.2755127	0.04
224.9867249	0.01
231.2278748	0.05
239.1246643	0.03
248.6191406	0.07
261.3642578	0.02
267.4516296	0.02
273.3154907	0.03
291.9528809	0.11
292.9296265	0.01
293.7593384	0.07
295.2518921	0.04
302.7583618	0.04
310.9109802	0.20
319.1994324	0.03
321.2005920	0.53
322.2334900	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2034
Annotation	Magnolenin C
Peak:m/z	Relative Intensity
173.0331116	0.03
175.0474396	0.09
177.4018250	0.01
179.0674133	0.02
188.1817322	0.06
190.1576385	0.17
191.0366211	0.21
192.0372620	0.01
193.1066132	0.06
195.2013550	0.07
203.3726349	0.13
204.3227844	0.03
205.2036438	0.14
207.2515259	0.05
208.1538391	1.01
221.3525848	0.08
222.0895996	0.49
223.2335205	0.16
225.2829285	0.02
247.3735504	0.01
251.0328369	0.20
252.2263336	0.05
252.9821625	0.07
267.3419189	0.20
298.3010864	0.06
311.2412109	0.01
323.5928345	0.08
326.5018311	0.02
327.2638550	0.08
341.1598511	0.13
342.1591187	0.04
343.3101807	0.10
344.2775879	0.28
345.2861328	0.01
354.4318848	0.02
357.1654053	0.31
359.2706909	0.94
365.4658813	0.01
369.2606201	0.34
370.0526733	0.07
371.4452515	0.10
372.4583130	0.03
374.2813110	1.46
377.4584961	0.01
383.5501709	0.03
384.8656006	0.06
386.6988525	0.07
387.4312744	0.02
389.2766724	100.00
399.1041870	0.18
402.3007812	0.09
403.3160400	0.09
407.3649292	0.07
413.3552246	0.16
415.3570557	0.08
421.1840820	0.07
429.5579834	0.02
431.3650513	0.03
433.2252808	48.31
433.8519897	0.12
437.2153931	0.10
441.0960083	0.01
449.1983032	0.02
475.3267822	0.03
487.4135132	0.01
493.4088745	0.06
518.9389038	0.04
519.5576172	0.28
521.2841187	0.16
532.4092407	0.01
533.0285645	0.02
543.6429443	0.02
546.2542725	0.02
547.5598145	0.02
549.2695312	0.18
551.6582642	0.07
557.4316406	0.07
562.1677856	0.08
563.1085205	0.09
577.2442017	0.10
578.4683838	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
108.1463699	0.02
108.9247208	0.05
111.0686417	0.04
127.1982498	0.09
133.0129395	0.03
135.0975037	7.00
137.0709381	0.03
145.2935791	0.02
155.0537415	0.16
161.0953827	1.12
165.286499	0.05
173.1211395	2.20
179.1152649	40.70
191.0505981	100.00
216.9563599	0.02
233.1981201	0.07
307.3778992	0.03
308.9584351	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.21
Annotation	Lysergic acid diethylamide
Peak:m/z	Relative Intensity
94.8048096	0.03
129.0245972	0.02
140.8178101	0.02
144.0011444	0.04
146.1314392	0.08
149.0817566	0.15
153.0809021	0.05
156.0599060	0.02
166.1282959	0.01
167.2354431	0.03
170.9739990	0.02
178.1869659	0.02
181.4070435	0.03
184.1514587	0.25
196.1668549	0.04
210.2327271	0.02
212.0701294	2.55
221.4123535	0.03
222.2562256	0.06
224.2200623	0.31
237.1236877	0.04
239.3268738	0.05
240.3020630	0.16
247.2877197	0.02
251.9327393	0.14
253.3190002	0.05
255.1420288	0.13
257.3882446	0.03
259.3262024	0.06
261.3438110	0.04
264.7498779	0.11
268.1716919	100.00
269.3330078	0.14
271.4346619	0.06
275.1903381	0.15
277.1251221	0.07
278.1645508	0.12
279.1163330	0.25
280.1548462	0.09
281.0360107	0.03
282.9806824	0.37
288.2073975	0.03
289.4720154	0.05
296.4783020	0.06
297.1831970	0.04
300.9606934	0.08
303.1218872	0.19
303.9074707	0.21
305.9741211	0.46
307.1804199	0.18
308.1129456	0.24
309.3618469	0.12
312.4493103	0.24
314.4194946	0.15
315.7509155	0.33
318.4998779	0.15
324.0623779	0.09
325.1000671	0.04
329.0883484	0.04
334.3196106	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.156
Annotation	Gonocaryoside B
Peak:m/z	Relative Intensity
145.1536560	0.22
151.0039978	59.94
163.0054016	1.60
205.0111694	0.25
234.8078613	0.07
246.7320251	0.18
289.2297363	0.24
307.1287842	27.51
308.2369690	0.12
309.1165771	0.19
323.3011475	0.06
324.7145386	0.09
325.5228271	0.07
341.3666382	0.38
353.1653442	1.35
415.2449646	0.27
443.2594910	0.42
459.0367432	100.00
487.3760681	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1301
Annotation	Galactotriose
Peak:m/z	Relative Intensity
200.9062195	0.16
247.0742035	0.07
272.9364014	0.12
289.9030151	0.10
291.1724854	0.20
325.3302612	0.22
363.2052002	20.26
366.3399658	0.05
367.8828735	0.08
370.1581421	0.34
370.9918213	0.12
371.7169800	0.46
381.2162476	100.00
382.1318970	0.07
427.3023682	0.18
453.2421875	0.05
483.3812256	0.41
484.4955444	0.06
485.4125366	0.08
525.2165527	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
108.9942017	0.02
113.0974731	0.04
118.9272614	0.07
126.9141998	0.03
143.0310211	0.09
160.8888245	0.14
178.9639587	0.92
180.1327972	0.16
197.0053558	0.28
198.1114655	0.17
199.0688171	0.77
215.0156860	2.25
216.0849152	2.55
217.1170349	9.36
263.0408325	0.06
341.1640015	100.00
342.1527100	39.71
343.1742554	10.61
346.0094604	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
96.09366608	0.28
97.0292511	0.54
98.86488342	0.24
109.1164093	0.39
121.037674	0.57
127.0947647	0.94
129.083252	0.30
134.9691925	0.43
137.9408875	0.94
139.0883484	0.43
141.031311	0.72
143.0999756	0.45
145.1884155	0.41
149.0340118	0.34
151.0372009	1.31
153.0428772	0.59
154.9321899	2.59
156.9945068	0.93
162.9616699	1.05
165.0690918	0.57
169.1179199	1.47
170.1672668	0.21
171.0776978	1.98
174.926712	1.17
177.2613831	1.12
178.828125	0.72
181.1503906	0.68
183.11409	2.24
184.2406311	0.72
184.9335022	0.50
187.1074524	1.26
189.1687622	0.21
191.1374817	0.25
193.0958252	2.71
195.0198669	0.97
197.0255432	3.67
199.1546021	0.93
201.5474548	0.46
203.2557678	0.24
205.3911133	0.60
206.357605	0.26
207.5609436	0.62
209.2031555	2.65
211.2424927	2.27
212.8969116	0.30
215.0593262	1.17
221.290802	2.82
223.0549316	2.30
225.263916	2.64
226.7763672	1.96
229.2101746	0.88
233.3555603	0.82
235.1285095	1.35
237.4648438	0.87
238.2598267	0.72
239.2515564	2.76
247.0430908	0.79
247.9471436	0.55
248.9961548	0.33
251.2661743	1.56
253.1579895	7.95
255.1401978	1.00
261.0386047	0.12
264.0986328	0.47
265.2122498	4.69
269.505249	1.30
270.2829285	0.16
275.2286072	16.69
279.1061401	0.51
280.2339478	0.95
281.2603149	0.26
282.3135071	0.13
283.2155762	4.52
284.0275574	0.84
293.2141724	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
179.3000183	0.01
236.8442383	0.01
341.2077637	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1611
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
160.1395264	0.09
161.1534424	0.20
161.9723511	0.09
173.1064148	1.92
174.3146210	0.09
175.0295410	0.05
177.0684052	2.87
178.0373535	0.35
179.0086670	0.36
180.2333069	0.05
191.1448364	10.89
192.0737610	0.40
192.8034058	0.14
193.8995819	0.03
195.1581726	0.99
196.1441956	0.05
197.1782074	0.07
198.1179352	0.05
203.0495300	0.30
207.0864258	0.23
209.0692139	0.88
210.1071320	0.04
211.2230072	0.03
215.0789490	17.11
216.2070160	1.01
217.2913208	0.05
219.1231842	0.09
227.1867065	0.18
233.1437225	0.05
243.1294861	0.03
244.0331421	0.03
245.1729126	0.06
246.3370667	0.05
252.9300537	0.06
261.1270142	0.13
267.5322571	0.07
271.1350098	0.03
273.0744629	0.06
278.4368896	0.02
279.2113037	0.02
281.9632568	0.08
290.3654785	0.02
290.9998169	0.01
294.9099121	0.08
297.4001770	0.02
307.2219238	1.87
308.2599487	0.86
309.4469604	0.02
310.3567505	0.12
311.3795776	0.17
312.3698730	0.13
313.0270996	0.02
314.3447876	0.05
320.3228760	0.04
323.4503174	0.02
324.3215332	0.03
325.3612061	0.09
326.4061890	0.08
329.4913330	0.02
336.4915161	0.09
338.3178711	0.08
339.3281860	0.13
340.3860474	0.11
342.2249146	0.03
343.1969604	0.97
344.3259277	0.29
351.1717529	100.00
352.2075806	8.94
353.1811523	0.56
354.4523926	0.03
355.1274414	0.07
357.2940674	0.12
361.3953857	0.02
365.1525879	0.03
366.1701050	1.30
367.2186890	9.32
369.1828003	43.09
370.2479858	5.52
371.3120117	0.05
373.2879028	2.70
374.1983643	0.87
377.2951050	0.14
381.5051880	0.03
387.2426147	7.83
388.3004761	1.05
391.1824341	0.02
395.3588867	0.05
399.2811279	0.03
404.1849365	0.03
409.3935547	0.22
416.4453125	0.11
430.1055298	0.06
437.0717773	0.03
447.4124146	0.06
453.4193726	0.14
469.0738525	0.03
471.3491211	0.08
472.4254761	0.02
484.8671875	0.07
488.9912720	0.05
499.4660034	0.03
514.6599731	0.19
515.3648071	0.33
517.1036377	0.03
518.5315552	0.18
523.2062378	0.03
529.3378296	0.77
530.2211914	0.12
531.3056030	0.41
532.2264404	0.05
533.3958130	0.02
541.4692383	0.02
543.2050171	3.89
544.2859497	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0766
Annotation	Glutathione
Peak:m/z	Relative Intensity
108.9800568	0.06
111.1629562	0.05
120.0444794	0.15
125.0270462	0.12
125.9064560	0.33
128.0003510	10.05
130.1054230	0.09
140.7980042	0.27
143.0469055	9.96
143.9430084	0.06
145.3223267	0.19
146.0645599	1.25
155.0049896	0.16
160.0486755	9.51
166.1068268	0.25
167.1251221	0.68
169.1952820	0.42
171.0824127	0.72
177.0138245	8.42
179.0940094	8.08
184.2443542	0.07
185.0648041	0.38
192.7033539	0.09
197.0210571	1.58
203.4897461	0.10
206.1340942	0.09
208.0166931	0.10
210.1189575	3.82
213.0919189	1.71
219.3642883	0.05
226.2054443	0.12
228.3391113	0.79
229.0716553	0.08
231.1525879	1.32
233.0967102	0.08
236.2724609	0.80
242.2230835	0.98
244.0383606	0.16
245.0119019	0.08
246.0927124	0.17
254.1108398	98.21
261.6264343	0.77
262.3498230	0.07
264.2749329	0.06
270.1188965	0.04
272.1548767	100.00
278.2945251	0.16
288.1048584	68.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.15
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
163.1668091	0.56
165.0840912	0.56
167.0498047	0.46
169.1832733	0.07
173.1054077	0.36
179.0987091	0.15
181.0888977	0.15
187.2608032	0.37
189.0433960	0.10
191.0284576	0.10
193.1601257	0.17
199.0006714	0.14
201.2093201	0.14
212.8739319	0.39
220.8274841	0.07
225.2324677	0.16
228.9530945	1.66
231.2184448	0.21
243.2359924	0.40
245.1860657	0.30
247.0981598	13.99
247.7668457	0.12
249.2714386	1.09
250.7508850	0.09
253.1690216	0.74
257.2211304	0.28
259.0668335	2.10
261.2296143	0.20
267.2215881	0.15
269.4097290	0.27
271.0891113	6.32
271.6984253	0.15
273.1456604	8.69
275.1218872	7.14
283.2216492	1.73
285.0835266	1.80
287.1967163	7.41
288.5710754	1.12
289.1836548	12.26
291.1489868	39.14
292.7658997	0.20
295.1890869	0.26
296.9968262	0.07
299.1502075	3.19
301.1688232	21.78
303.1637878	2.55
309.1447144	0.11
311.2515259	0.61
313.1475220	4.80
313.9294739	0.11
315.2121582	0.15
325.1591797	2.59
331.0640259	0.96
333.2351074	3.08
338.9143066	0.05
343.2766113	0.73
350.5811768	0.10
355.2992554	0.11
363.3393555	0.10
365.5117188	0.28
367.0684204	0.23
386.7711792	1.10
393.4141846	0.54
397.1848145	0.32
398.3057861	0.11
405.1217651	0.07
406.9749146	0.97
409.1813965	100.00
410.1905518	0.41
411.2888794	13.05
414.0778809	0.07
415.3027954	0.54
417.1116333	2.46
421.0913696	8.68
421.7597656	0.06
423.1614380	3.22
425.3112183	0.75
427.1520996	88.77
433.1123047	1.27
434.0566406	0.38
435.2941895	36.42
436.1551514	0.16
438.5805664	1.38
439.3148193	12.68
441.3994141	0.24
445.1972656	0.16
446.2501221	0.34
451.2330322	1.23
453.1468506	70.87
453.8978882	0.23
455.0145264	0.21
457.5303955	0.21
481.1259155	0.18
487.3364258	0.11
489.1931152	0.18
490.5957642	0.19
498.0702515	0.78
500.9425659	0.08
502.1948853	0.18
512.1159058	1.08
513.3245239	0.74
515.3413696	0.12
516.9135742	0.19
517.9434814	0.29
518.8235474	0.48
520.5181885	0.26
529.3148193	0.05
533.4762573	0.12
534.5449829	0.15
538.8278198	0.20
542.3034668	0.06
543.3264160	2.93
545.4128418	0.15
548.0537720	0.06
551.8316040	0.37
554.0828247	0.73
560.0269775	0.96
561.1747437	58.87
561.7853394	0.17
562.6824341	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
119.3338318	1.24
157.1288452	0.08
162.1031647	0.18
170.0174408	4.02
171.0544128	0.20
183.0128937	100.00
184.0201874	19.13
185.0445404	5.16
197.1348877	5.77
198.1275635	3.51
199.0557861	0.73
211.0362854	0.84
212.1910706	2.89
213.3757629	0.23
225.1387634	1.87
226.1598816	3.15
226.8736877	0.13
228.1593018	0.50
237.3946228	0.06
239.1690063	1.97
240.0721436	1.04
240.7516785	0.47
244.7778015	0.29
247.2079773	4.10
248.2738342	2.66
249.3301392	0.14
250.1206055	0.42
253.2933044	0.31
254.1584473	0.89
267.2738342	0.87
268.3354492	0.20
269.480011	0.12
282.4785767	0.39
284.2325134	0.07
293.3273926	1.15
294.2497864	0.86
295.2594604	0.18
296.2047119	0.36
297.2941284	0.12
311.2706299	9.64
312.3927612	3.80
313.3637085	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
100.9567719	0.53
105.2281952	0.49
113.1213226	2.10
117.0752258	1.31
133.1477051	0.73
148.9951782	1.57
151.2209625	1.51
163.1998138	1.42
164.8689423	0.67
171.2711639	0.76
176.9893646	0.49
179.1260376	1.95
179.9541473	2.61
183.1363983	0.66
191.1009674	0.41
193.3016968	0.57
195.0060577	0.57
202.6448212	0.63
205.0488281	1.86
206.0522308	0.64
207.1161346	13.54
208.0724335	6.95
209.0672607	2.69
209.7645569	0.17
221.3736115	1.51
222.1689301	2.69
223.1470795	8.95
224.3492737	1.21
232.4755707	2.34
233.1814423	7.80
235.1035309	0.66
236.1706696	0.76
251.0745392	100.00
252.2234955	14.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0985
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
109.1315384	0.03
112.9741516	2.04
117.0501099	0.03
120.9361420	2.49
123.1209259	0.40
125.0848312	0.07
127.9385300	0.10
129.1036377	0.04
145.9126434	0.11
146.9263306	0.06
148.9762878	0.06
156.8823547	0.17
164.9314880	0.06
167.0088654	4.45
172.1484528	0.03
173.2023621	0.02
174.9945068	0.47
176.2517700	0.04
179.3436584	0.07
180.0760193	0.07
187.2844543	0.02
189.1012573	0.21
190.9487305	0.03
192.9439087	0.18
197.0243530	0.03
209.2800598	0.01
220.2136536	0.07
221.1650696	0.03
223.1589661	0.59
224.1842346	0.47
225.1055908	0.05
227.3948364	0.05
231.0516968	5.24
249.0992737	100.00
254.2503662	0.03
255.1304932	0.08
256.6357727	0.03
265.1962280	0.01
266.3507690	0.03
267.1845093	0.02
272.1553650	0.08
283.2068787	0.04
285.6828003	0.04
291.4343262	0.06
295.1445312	0.09
297.3874512	0.04
307.1418152	0.05
307.7642212	0.02
309.4155273	0.14
310.1627197	0.04
311.3151550	0.40
313.0692749	0.03
323.3540039	0.14
324.3229675	0.41
325.4332275	0.61
326.1715088	0.10
327.1659851	0.49
335.1915894	0.40
341.0788574	0.13
341.9382629	0.02
353.2340698	2.81
355.4195251	0.11
356.1819763	0.10
356.9220276	0.11
359.3138123	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.214
Annotation	Unknow
Peak:m/z	Relative Intensity
282.0777283	0.08
305.9272461	0.54
307.0927124	0.50
323.0122681	0.22
340.8713989	0.22
343.4864502	0.12
383.2796021	0.21
395.3869019	0.29
442.2557983	0.29
443.1314697	0.35
470.3551636	0.15
503.3579712	100.00
504.2808838	3.55
632.3589478	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1143
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
113.0522995	0.17
114.2390060	0.00
115.1635284	0.00
119.1604462	0.00
126.9957962	0.00
135.2368164	0.04
136.1345825	0.02
139.2213898	0.01
148.6298828	0.01
149.2894897	0.01
156.9995422	0.00
173.1846008	0.00
174.9346313	0.07
176.3848267	0.01
179.3233032	0.01
189.0445557	0.01
191.1794891	0.01
205.0332947	0.05
206.0573120	0.00
207.2475433	0.02
214.4028168	0.00
223.2190552	0.04
224.1568909	0.01
231.2412720	0.09
232.3624878	0.01
234.1205444	0.01
249.1560364	8.13
250.1686707	0.66
267.1193848	100.00
268.1155396	7.92
268.8476562	0.01
308.5971985	0.01
325.2539978	0.01
336.8951416	0.03
338.2723389	0.03
339.2280884	0.01
342.2356873	0.01
343.9788208	0.01
355.2527161	0.02
367.0229797	0.15
370.1309204	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.1714
Annotation	Cannabin
Peak:m/z	Relative Intensity
179.0770569	0.24
217.3002472	0.28
289.0540161	0.23
314.0170288	0.11
323.1452026	0.13
327.2770386	0.13
341.2353516	4.22
363.2989502	0.06
367.3015747	0.08
397.2902832	2.88
416.1410522	0.18
417.5115967	0.10
428.9289551	0.17
444.4412842	0.06
469.2684326	0.15
495.3630371	0.26
499.2772217	0.07
499.9349976	0.06
501.5117188	0.16
514.6397095	0.42
515.2658691	0.07
534.9322510	0.07
545.3685913	0.49
547.0516357	0.29
547.7112427	0.41
553.3036499	0.21
554.2161865	0.03
555.6137085	0.24
559.2318115	100.00
559.8454590	0.73
561.2754517	0.43
573.4271851	0.28
575.4065552	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.1901
Annotation	Limonexic acid
Peak:m/z	Relative Intensity
146.0567932	0.39
147.0504608	0.98
153.1636200	0.09
157.2872009	0.24
158.8733521	0.05
159.9921265	0.76
161.0921936	5.82
162.9821320	9.54
169.0422058	0.10
171.2701111	0.23
175.0955811	23.68
177.0314026	0.05
178.4877930	0.12
179.1431885	1.34
184.9622498	0.53
186.1099548	0.06
187.0458832	1.54
199.1262512	1.28
200.9859619	4.97
201.5960999	0.15
209.3207397	0.22
217.0806427	3.90
229.1358948	0.08
233.2353210	0.15
237.2364044	0.06
241.2599335	0.24
245.3914948	0.04
247.1873169	0.10
250.9137878	0.22
253.2578735	0.10
261.2036133	0.10
262.3504944	0.06
263.2532349	0.22
265.0744629	0.08
279.1187134	0.43
289.5316772	0.10
291.2395020	6.13
292.2709351	0.34
293.2340088	0.82
295.1494446	1.15
296.2669067	0.13
297.2191772	0.27
303.3620300	0.05
308.0103455	0.17
309.2115784	0.14
311.1723938	26.31
313.4228821	0.21
315.2348938	0.18
323.2750854	100.00
325.2836914	35.74
327.1588135	0.26
333.8513489	0.34
335.2115479	0.34
337.2400208	0.32
339.1484680	0.05
341.1216431	20.10
346.9430237	0.04
349.2160034	0.09
351.4820251	0.26
358.9704285	0.24
363.1868896	0.10
365.1753540	0.71
372.3190918	0.15
373.9537354	0.09
383.2241516	0.19
384.1796265	0.11
389.3188782	0.10
395.2816467	0.11
401.2174377	0.12
437.6584473	0.04
439.3649597	0.12
443.1707764	0.06
449.4953003	0.17
455.3478699	0.75
461.2446289	0.14
466.7162781	0.06
467.3936157	0.48
473.0485229	0.37
475.0618286	0.05
485.3416138	3.27
486.5707703	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2075
Annotation	threo-Carolignan K
Peak:m/z	Relative Intensity
162.7593231	0.20
165.1284790	0.32
191.9958038	0.05
195.1499634	0.81
238.9870148	0.09
292.0925903	0.05
294.6647949	0.25
295.2874451	0.08
297.0039062	0.11
307.1694946	0.22
309.3096924	0.19
313.1850586	0.35
315.4621582	0.05
324.2503052	0.49
325.2033691	0.51
327.3012085	5.94
333.0898438	0.05
337.5866089	0.09
339.2873535	8.24
343.1902466	0.03
345.3053589	0.08
353.2086182	0.11
357.1389771	0.03
365.2962036	0.03
371.4910889	0.04
372.1024780	0.07
373.3095093	0.28
374.4725342	0.16
389.8223877	0.12
391.4000244	0.06
398.7079468	0.06
401.2280884	0.06
402.4302368	0.08
403.3143311	0.61
406.4916382	0.16
408.2315674	0.08
411.3683472	0.10
419.2955933	0.03
420.1088257	0.05
421.6083984	0.04
440.0525513	0.05
445.3938599	0.18
457.3352661	0.09
462.5771484	0.09
464.4288940	0.04
469.1330566	0.03
475.3035278	0.97
487.3307495	3.31
491.2300415	0.05
494.4957275	0.06
498.3457642	0.07
505.2752075	100.00
506.1823120	0.05
506.8972168	0.04
509.3269043	0.19
516.4177246	0.46
517.3964844	1.94
521.2918091	0.33
522.0624390	0.08
523.3347168	2.17
533.3449097	0.28
534.0779419	0.05
534.6969604	0.33
535.3161011	3.84
538.2467651	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9727936	1.05
110.0893707	0.02
122.9369202	1.15
152.0285339	3.55
167.0337067	100.00
177.0677490	0.10
209.0374756	0.56
233.1956177	0.04
251.2710571	0.07
267.8693542	0.04
269.1574402	0.09
283.1005859	0.31
285.2995605	0.20
293.2056274	0.11
301.4723511	0.02
309.2096558	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1296
Annotation	Arborescoside
Peak:m/z	Relative Intensity
113.0421753	2.07
118.9164658	3.32
125.0265656	0.32
130.9526672	1.82
136.0835266	0.26
142.9607239	4.54
145.7190857	0.09
148.8276672	1.00
150.9104919	0.84
160.8920593	4.54
162.5940247	0.06
177.6269989	0.47
178.9365540	100.00
181.0923767	2.21
191.1050110	0.13
194.5739136	0.14
212.8608398	0.08
224.5797424	0.54
225.1868896	3.99
234.9689636	0.04
278.3186646	0.06
279.4412842	0.07
296.2851562	0.11
341.2630005	13.45
342.1472778	0.14
343.2957153	0.13
357.4712219	0.15
369.1468811	0.65
372.2719421	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.1084
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9636688	12.86
164.0364532	0.31
193.1498108	0.11
243.7606659	0.03
302.1128845	0.05
308.1463013	0.13
336.9599609	0.21
338.1945190	0.11
353.2349243	0.04
354.9726562	14.13
356.0471191	0.67
356.8484497	0.02
363.0791016	0.04
379.2433472	0.19
382.2553711	0.04
383.0731201	0.05
384.5983276	0.13
408.1008911	0.06
409.2153931	0.07
427.5354004	0.08
447.2797241	0.11
453.9711914	0.05
462.7269897	0.06
477.7745361	0.02
497.3458252	0.05
498.8877563	0.13
522.8813477	0.10
526.0858154	0.03
540.9691772	0.81
542.1236572	0.13
569.1810913	0.17
571.0328369	5.16
571.9989624	0.20
583.0806274	0.14
589.0592651	0.17
590.5183105	0.11
600.0623169	0.14
601.1785278	0.36
619.6204834	0.05
717.3131714	0.32
718.1829834	0.21
745.1046753	0.16
746.3855591	0.04
760.0531616	0.13
761.1625366	11.07
762.3599854	19.19
763.1536255	100.00
764.2670288	2.02
779.7941284	0.04
792.1781006	0.12
803.4161987	0.02
808.5592041	0.05
953.2536011	1.37
954.6450195	6.21
955.4431152	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.1573
Annotation	Piperacillin
Peak:m/z	Relative Intensity
149.0427704	0.21
157.1186218	0.91
159.0576172	0.13
160.1670227	0.04
161.1952515	0.66
164.1030426	0.08
179.1692352	1.02
197.1764984	0.04
211.0597382	0.26
221.0580139	0.07
231.1566010	0.12
247.1941833	0.18
249.0621490	0.42
257.1083679	0.07
275.2507324	0.29
293.2276001	69.84
319.0630493	0.11
337.2333374	100.00
432.1339722	0.02
434.5407715	0.11
469.7469482	0.03
472.3953247	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	214.0704
Annotation	N,N-Dihydroxy-L-tyrosine
Peak:m/z	Relative Intensity
128.0845795	0.21
167.9672394	40.97
168.7679596	0.02
178.1294708	0.13
185.6358185	0.02
195.8975677	100.00
214.1112213	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1669
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
219.2220764	0.03
225.0952301	0.01
229.2205353	0.03
240.2798157	0.05
241.5061035	0.01
269.1411133	0.05
277.2269287	0.04
289.3058777	0.01
292.2720947	0.01
293.3261719	0.01
295.1297607	0.04
296.5510864	0.01
303.2434082	0.01
310.8390503	0.01
313.2387695	0.04
313.9444885	0.02
321.1273193	0.45
322.2787476	0.04
339.2017212	4.47
340.2857666	0.64
351.3153076	0.06
355.5654907	0.04
359.3491821	0.05
367.3086548	0.06
370.9100342	0.01
403.3726196	0.03
404.2392578	0.01
421.2437744	0.02
469.3305664	0.49
470.4479980	0.03
480.4123535	0.03
483.7343140	0.01
485.0806274	0.02
487.3217773	0.20
492.4565430	0.02
495.3898926	0.53
496.2612915	0.19
507.4390259	0.03
509.3628540	0.01
511.4335938	0.01
513.2687378	100.00
514.2747192	12.75
515.0938110	0.01
529.9389648	0.01
531.1480713	0.11
532.2999268	0.01
537.4723511	0.04
549.2460938	0.22
550.3998413	0.06
560.5345459	0.02
568.6997681	0.02
577.1568604	0.01
595.2734985	0.05
609.0827637	0.10
618.4089966	0.01
620.3162231	0.07
639.1291504	0.03
643.3062134	0.01
659.6999512	0.01
661.1690674	0.05
662.4917603	0.00
664.8198853	0.01
672.6760864	0.03
674.8087769	0.01
687.5326538	0.02
688.1790161	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	Unknow
Peak:m/z	Relative Intensity
160.6937103	0.08
179.0292206	1.53
214.8841248	0.02
221.2313538	0.16
233.0967407	0.13
250.8164978	0.26
268.1427917	0.06
269.1141357	0.04
281.0524292	0.10
323.2052002	0.28
341.0303955	1.89
359.2173462	0.36
377.2636719	10.06
383.2328491	0.04
412.8920288	0.02
503.3425293	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2939
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9217987	0.14
153.9969025	0.12
179.9943237	0.02
196.0260620	1.62
210.9938965	0.04
214.1670532	1.51
231.0395813	0.02
248.9589233	0.08
267.0632935	0.09
281.3898926	100.00
284.3690186	0.02
287.9469299	0.05
320.3314209	0.03
321.1638184	0.08
330.2696533	0.02
347.5170288	0.03
415.6169128	0.09
417.5560608	0.13
418.8914185	0.04
433.4536743	0.07
436.4172363	0.07
441.3946228	0.02
459.1376038	0.06
460.2545471	0.11
461.5259399	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1871
Annotation	Isosyringinoside
Peak:m/z	Relative Intensity
161.2744904	0.31
162.9477386	10.47
164.1085663	0.37
167.1244507	0.06
179.1171112	3.32
205.0430756	0.40
234.8107452	0.44
247.1816254	1.50
289.2325439	1.85
305.8420410	0.18
307.1057129	100.00
307.9220581	0.02
332.5100708	0.05
352.1174316	0.18
352.7522583	0.14
353.3652344	0.34
453.2741699	0.17
470.9028931	0.08
471.5523682	0.26
481.4551392	0.18
486.2430420	2.08
486.9362183	31.82
487.6693726	0.04
497.3320923	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	404.1544
Annotation	Scopolin
Peak:m/z	Relative Intensity
146.8901367	0.06
155.0995789	0.21
167.0167236	0.21
179.9875793	4.19
185.1321716	0.08
197.1990204	0.15
207.0150604	12.58
221.1580200	0.30
223.4497986	0.30
225.0124512	100.00
225.6816711	0.14
231.1098328	0.05
241.8845215	2.16
253.0674438	0.12
262.3258362	0.13
263.0438843	0.22
264.3129272	0.21
269.4606628	0.18
271.8699341	0.10
305.2362061	0.30
313.2029419	0.08
316.5231934	0.08
319.2078552	0.15
327.2331543	0.23
328.9614258	0.25
329.7722473	0.10
331.4982300	0.10
342.1563721	0.30
343.1632690	0.09
351.1806641	0.22
358.0414734	0.11
359.2416687	0.20
369.0681152	0.28
372.9878845	0.06
373.7380676	0.16
375.5384827	0.15
376.3221741	0.21
381.7967834	0.40
383.1413879	0.75
384.4385986	0.49
385.8952332	2.77
386.5259705	6.33
387.1464844	2.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.1541
Annotation	Pirbuterol
Peak:m/z	Relative Intensity
69.9023056	1.23
71.0510941	0.06
80.9482422	0.24
82.0252762	0.10
83.9465027	15.16
84.9141235	0.30
95.9162064	0.06
98.0576477	2.63
100.0114746	0.77
114.0389252	0.20
115.9263000	1.40
126.0186005	1.62
128.0897217	28.01
134.8763428	0.10
137.4522247	0.06
140.2749481	0.34
144.0341187	14.78
144.6351166	0.11
150.1536713	0.34
152.1698151	2.03
154.1668396	0.19
158.0174713	2.45
165.1061707	0.12
166.0948334	0.09
168.0858765	5.12
170.2189789	0.13
173.0022125	0.22
177.9143219	0.13
179.1828461	0.12
183.0468445	0.45
184.1076202	0.51
196.0574341	100.00
197.1869965	0.58
198.1094055	0.77
199.2185516	0.16
205.3004913	0.20
207.2796021	0.11
211.3176880	0.14
213.2035980	5.96
213.8125153	0.07
220.3177338	0.24
223.2559967	1.66
224.2175751	0.16
226.3503265	0.10
241.1212616	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	764.3336
Annotation	Unknow
Peak:m/z	Relative Intensity
230.2606354	0.02
230.9845428	0.01
237.2935181	0.02
253.9774323	0.11
263.1504211	0.01
272.1411743	0.05
280.2436829	0.02
282.3649902	0.04
288.2311096	0.11
289.2821045	0.13
298.2500000	0.06
306.1619568	0.43
307.1735229	0.02
320.1572876	0.02
325.1890869	0.07
339.4216614	0.02
354.3540039	0.04
360.1633606	0.02
363.3167725	0.05
364.1518555	0.02
365.1978149	0.03
375.0332642	0.05
380.0702515	0.02
384.8895264	0.03
389.4412842	0.25
390.3716431	0.03
407.1220093	0.10
408.1107788	0.03
409.2837524	0.06
410.0344238	0.02
413.4990234	0.03
421.3377686	0.02
423.1954956	0.48
424.0358276	0.04
428.4671021	0.05
433.4012451	0.08
434.2244873	0.05
439.4904175	0.09
441.2556763	1.57
442.4095459	0.66
446.0144653	0.02
451.4266357	0.14
457.2376099	0.23
458.6076660	0.04
459.3998413	0.12
462.2630615	0.07
467.1195679	0.22
468.5126343	0.04
475.2080688	8.90
476.3337402	1.90
480.3066406	0.02
485.2597656	3.12
486.2759399	0.80
487.9984131	0.02
491.1278076	0.21
491.7410889	0.12
492.3693848	0.03
493.3936157	0.19
494.3899536	0.10
501.4702148	0.01
503.3649292	1.10
504.3793335	0.44
509.4623413	0.02
519.2356567	2.63
520.3298340	0.47
527.3133545	0.01
528.1670532	0.01
531.9974976	0.18
533.6495972	0.02
537.2456665	100.00
538.2224121	19.33
538.8581543	0.05
549.4822998	0.15
550.5842896	0.07
553.4381104	0.07
554.2219849	0.03
568.3915405	0.03
574.2791748	0.07
579.0908813	0.14
580.0275269	0.02
595.3090210	0.01
596.0488892	0.02
605.1064453	0.02
613.5111084	0.08
617.6091919	0.02
621.1967163	0.05
623.3724365	0.04
630.6791382	0.10
631.3987427	0.01
640.4791870	0.02
647.6696167	0.05
649.4464722	0.07
657.2175903	0.47
658.3299561	0.15
667.2651978	0.31
668.3659058	0.13
672.2333374	0.02
673.6726685	0.06
675.1863403	0.16
676.4498291	0.11
677.7424927	0.02
682.9734497	0.08
685.2548218	0.12
686.3231201	0.02
687.6542358	0.07
701.2014771	5.28
702.2401733	0.95
711.3676147	0.43
719.3236694	0.82
720.6156006	0.17
728.0452881	0.05
729.3186646	0.24
730.4887085	0.18
742.9702759	0.04
745.2754517	1.16
746.3835449	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	566.1514
Annotation	Unknow
Peak:m/z	Relative Intensity
168.1109772	0.12
173.1588745	0.14
179.0777588	0.47
191.1202240	2.20
205.2149200	0.10
207.1515808	0.06
336.3112183	0.05
339.3807373	0.20
349.2549438	0.04
353.1302490	100.00
353.7545776	0.22
379.9854126	0.06
392.1793823	0.07
397.2559814	0.81
404.3469238	0.04
413.2249146	0.07
437.2736206	0.11
447.2897949	0.03
474.8795776	0.07
475.5193481	0.06
494.2384033	0.10
503.2439575	0.34
505.1861572	0.25
515.2746582	0.07
519.3670044	0.17
524.5552368	0.24
535.2600708	0.05
548.2568359	0.10
549.3153076	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	529.1566
Annotation	Antimycin A5
Peak:m/z	Relative Intensity
157.0650940	0.87
175.1157227	100.00
179.0516510	0.08
190.9270020	0.53
303.9557495	0.06
315.1883545	0.21
332.2152100	0.06
335.3164062	0.17
343.0059814	0.05
353.1461792	10.86
355.4122314	0.06
397.3261719	0.12
433.3074951	0.04
437.2232666	0.02
439.2970581	0.03
483.3265991	0.63
488.1998901	0.04
511.1592407	0.25
512.2669067	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	753.1491
Annotation	Unknow
Peak:m/z	Relative Intensity
215.0897369	0.01
216.0762024	0.05
233.1455994	7.60
234.1568909	0.14
244.9913940	0.03
267.4480591	0.03
272.1924438	0.10
284.1465149	0.02
290.1858521	0.06
291.2570496	0.11
296.8488770	0.20
308.1167297	19.25
309.1492310	0.29
336.0822144	0.08
343.0913086	0.03
365.1416626	0.03
373.1118774	0.07
374.2532349	0.03
383.8717651	0.03
400.1010742	0.10
402.2803955	0.03
411.3113403	0.13
412.0783081	0.07
418.2543945	0.23
420.0437012	0.04
428.2339478	0.35
446.1762695	4.78
459.2123413	0.07
463.0186768	0.22
477.3810425	0.10
478.1890259	0.05
522.5484619	0.13
529.1723022	0.03
540.0791016	0.22
556.4702759	0.02
557.4430542	0.05
561.8546143	0.02
573.3843384	0.16
575.1464233	0.22
642.3107300	0.07
650.1328735	1.33
651.0940552	0.04
655.0862427	0.05
660.3190918	2.36
661.3868408	0.04
673.1073608	0.06
678.1379395	100.00
679.2426758	4.41
691.3286743	0.15
701.4275513	0.04
707.4628296	0.04
717.2443237	0.92
718.1020508	0.16
733.1177979	0.22
735.2207031	26.99
736.2315063	1.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1826
Annotation	Scopolin
Peak:m/z	Relative Intensity
291.9506531	0.04
308.2818604	0.04
308.9534302	0.03
321.2537231	0.03
322.3493042	0.14
351.3596802	0.03
353.0980225	100.00
513.3519287	0.12
514.0497437	0.41
515.1983643	0.22
544.9558716	0.17
595.4046021	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	350.09
Annotation	Loracarbef
Peak:m/z	Relative Intensity
117.0078506	0.03
128.0113983	0.06
130.0491638	0.02
131.0231628	0.10
132.8451843	0.03
140.8865509	0.02
144.0551758	0.16
145.0772858	0.10
145.9728851	0.05
147.2169495	0.03
148.2040405	0.03
148.9960632	0.02
151.0365906	0.32
152.0345459	0.11
157.0322723	0.09
170.0549927	11.81
174.1436615	0.03
179.0670166	0.06
188.0043335	100.00
189.3888702	0.08
195.2037506	0.09
199.0064697	0.03
200.9880371	0.76
202.1023560	0.07
209.2048492	0.72
215.0123901	0.11
216.0962830	0.03
217.1406555	0.04
218.9340820	0.11
228.8711853	0.60
233.0422974	0.13
234.0439758	0.03
235.3179016	0.04
248.0049133	0.06
250.7511902	0.02
260.3736572	0.16
262.2065125	0.13
269.0845947	0.16
273.3701172	0.03
274.3057861	0.12
278.3015442	0.04
281.9639893	0.14
282.9803162	0.66
286.2103577	0.06
290.0258179	0.12
291.1356201	0.04
295.4032898	0.13
302.0156250	0.03
303.0699158	0.19
304.2138672	0.13
305.9603882	0.67
309.0601196	0.03
313.7527466	0.23
314.3750000	0.06
315.0677185	0.05
320.1811829	0.02
331.4335938	0.35
332.0815735	1.51
332.7595520	0.01
333.5792847	0.03
335.5110168	0.02
340.8341064	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
96.72822571	0.33
100.8584976	0.26
104.906929	0.31
109.0177917	0.16
111.1246185	0.53
113.0295029	0.51
120.0700226	0.25
123.4266739	0.31
124.9592743	0.68
126.8111191	0.19
128.7513428	0.87
135.0169678	0.40
137.0536499	0.48
139.068634	0.79
140.8886719	0.86
142.9964905	0.41
145.2003174	0.38
149.2815094	0.26
151.125885	0.96
153.0744629	0.74
154.8499451	0.46
161.1955872	2.42
163.2528992	0.22
165.1470032	0.46
166.9517975	0.75
169.1313629	1.82
171.1931763	1.13
173.2698212	0.77
174.9788513	0.21
177.1532745	0.70
179.1675873	0.36
180.8659973	1.51
183.5217896	0.64
185.3023071	0.51
187.1346741	0.50
189.2678375	0.97
190.9984436	0.95
195.13974	1.96
197.1030273	1.91
199.1007843	0.43
200.6581726	1.08
204.8197632	0.21
207.2277832	0.77
209.1091614	0.26
211.0109863	1.95
215.1952515	0.17
216.1628113	0.19
217.3706055	0.62
219.2663574	0.17
221.1827698	2.06
223.1052551	0.86
225.0481262	1.90
225.9703369	1.27
227.1181641	0.58
233.1931458	1.08
235.1663818	2.05
237.1758423	3.07
238.1459656	1.47
239.0310974	1.79
241.1929626	0.14
247.3676758	0.10
250.083374	1.15
251.1454163	1.63
253.1645508	6.25
255.4516296	0.10
265.3646545	1.41
266.4344482	0.36
267.2919922	3.04
268.3928223	0.37
269.4448547	0.38
270.4808044	1.17
275.2328491	9.85
277.1044312	0.86
279.1627197	0.49
281.2806396	1.50
283.210968	4.21
284.0753784	0.49
287.8088379	0.67
292.1334534	4.59
293.211853	100.00
294.4961243	0.21
302.7036743	2.16
311.4693604	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.1345
Annotation	Pseudoanisatin
Peak:m/z	Relative Intensity
87.2494812	0.22
92.9547272	0.24
94.9801865	8.11
97.0938492	1.70
98.0434723	0.35
98.9277420	0.46
101.0655060	0.07
107.0468140	0.16
109.0879364	0.44
111.0971451	0.95
113.0459518	100.00
114.9916992	0.18
121.1014481	2.97
123.0958176	4.23
135.2188873	0.93
135.8424988	0.13
136.9627686	2.02
139.0608826	29.66
141.0285339	1.24
147.0834045	1.13
149.1275024	0.50
152.9498291	0.22
155.0170898	2.17
157.1829681	0.60
157.8808594	0.20
159.2223206	0.54
161.0344238	1.77
165.1613007	0.66
166.2411194	1.07
167.1230316	0.57
169.0231323	4.83
170.8944702	0.62
172.9967499	0.84
174.0037384	2.08
175.1010132	2.25
177.1154633	1.16
178.0919800	0.13
179.0232239	1.96
181.1344910	0.68
184.1631775	0.17
185.1262512	0.44
187.0770111	8.82
189.1191406	2.47
191.1951904	3.18
192.2354279	0.90
193.1487732	2.44
194.9384003	1.23
196.9711761	0.79
199.2130127	13.83
202.1459045	0.27
205.2013855	19.75
207.2186890	1.46
215.1332397	1.42
217.1648560	64.01
223.1285095	2.18
235.2003479	22.74
238.9683533	0.49
251.1311951	2.55
253.1146545	23.57
279.2490845	2.05
282.2825623	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9767227	0.79
123.0756073	1.55
139.9164124	0.02
151.8809509	3.30
167.0009460	100.00
167.8419189	0.16
175.0498047	0.05
180.1204834	0.03
193.2162018	0.11
209.2307434	0.21
239.4064941	0.17
241.0827637	0.07
283.1353149	0.38
284.2648926	0.11
285.1861267	0.23
293.0552979	0.08
311.1759949	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
161.1017456	0.31
169.9630127	7.29
179.008606	0.38
183.0125427	100.00
184.0884247	8.73
184.9813843	0.35
194.9683075	0.21
197.1034851	22.57
198.1009827	9.57
199.2046051	0.38
211.1256409	0.68
212.0897827	3.11
217.1072388	0.59
224.1999817	1.03
225.1939697	2.13
226.1405945	1.45
239.2014465	6.44
240.3032227	2.11
241.3099976	1.57
242.9792786	0.27
247.2488403	7.04
248.2648315	1.11
249.1837769	3.36
249.7840576	0.79
253.0421753	1.56
254.2036743	2.45
265.3784485	0.55
266.616333	0.97
267.4778442	3.04
268.0803833	0.34
281.4250793	0.18
283.1096802	0.31
293.2738037	7.27
311.2670288	15.87
312.2988892	3.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.15
Annotation	Chalconaringenin 2'-rhamnosyl-(1->4)-xyloside
Peak:m/z	Relative Intensity
151.2553101	0.07
160.1177216	0.41
160.9639587	0.95
162.0133667	0.10
163.1625214	0.07
165.0900879	0.52
171.1807861	0.10
173.0713196	1.90
177.0375671	3.33
178.0388947	0.05
179.1928406	1.54
191.1471558	20.58
193.1100006	0.11
195.0269165	0.44
199.1658783	0.05
202.1142273	0.09
202.9793091	0.29
215.0393066	17.92
223.2758484	0.45
233.3461914	0.11
242.5366974	0.14
245.3037872	0.09
262.2977600	0.04
271.3872070	0.09
280.2300110	0.29
281.2698364	0.63
283.2236938	0.37
294.5285645	0.41
295.2307739	0.35
307.2091675	3.35
308.1707764	0.09
309.2686768	0.55
310.9942627	0.10
313.1390991	0.47
321.3255615	0.29
325.2088013	0.37
327.3710938	0.46
335.5503540	0.04
337.2186279	0.10
339.2539673	58.73
343.3104858	1.32
351.2088013	100.00
352.1569824	0.34
353.1891479	1.81
357.2421265	8.00
365.2340698	0.42
366.3990479	2.11
367.2215576	16.72
391.2399902	0.29
421.2925415	0.04
435.5051880	0.04
438.4163818	0.19
446.9584961	0.28
453.2081299	0.14
457.1282959	0.12
468.4649048	0.04
471.3687134	0.19
472.4280396	0.10
481.1921997	0.05
483.0989380	0.15
484.2641602	0.27
485.1831665	0.04
486.2697144	0.04
487.3732910	0.25
499.2237549	0.22
501.2183838	1.99
501.9270630	0.04
513.3112183	4.40
513.9698486	0.09
516.2838745	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	488.1206
Annotation	Unknow
Peak:m/z	Relative Intensity
148.8089600	0.09
164.1840820	0.04
165.9949951	0.33
176.0221863	0.19
181.0531921	0.34
193.9849243	4.59
194.8843689	0.05
207.1640778	0.68
209.1049347	100.00
219.0926666	0.06
226.9407043	0.03
239.2019501	0.17
244.4918671	0.29
254.1537170	12.48
262.1237793	0.07
281.1127014	0.05
296.0226440	19.68
297.0726929	0.50
313.1864624	0.05
314.1724243	0.27
315.0127563	0.27
316.2922363	0.17
318.5100098	0.22
325.0660400	0.05
339.9042969	0.13
341.2887573	0.08
342.6117554	0.05
358.4805298	0.04
371.2831421	0.06
379.7814636	0.15
381.2037048	0.06
383.3218079	0.14
391.8072815	0.18
398.1572266	0.08
398.8222656	0.24
400.7321472	0.04
417.3075256	0.09
427.5881042	0.11
429.4195251	0.17
430.1623840	0.08
442.0962830	0.72
451.4596863	0.14
453.0249634	0.43
458.4403381	0.13
467.8700867	0.22
470.2007446	18.97
471.1648560	0.98
479.0368042	0.19
487.4064331	0.17
488.1564026	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.0754
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone
Peak:m/z	Relative Intensity
81.0846634	0.04
137.1660461	0.03
181.0718231	0.08
183.1560822	0.18
189.2938080	0.00
193.2203827	0.03
195.2092285	0.17
207.0525818	100.00
211.2217560	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.1325
Annotation	Unknow
Peak:m/z	Relative Intensity
217.4501648	0.06
219.2822571	0.06
229.0227356	0.06
231.1215820	0.07
234.2347107	0.03
235.3222809	0.03
254.2107849	0.44
266.0821838	0.02
270.4252319	0.08
272.4373779	0.02
278.1323242	0.05
279.1888123	0.06
280.4885559	0.17
282.0240479	0.02
286.3129272	0.15
288.2213135	0.48
292.3361816	0.07
293.3298340	0.07
296.2706909	0.06
303.4297180	0.07
304.3435974	0.11
306.1995850	0.38
312.5261841	0.02
315.3948975	0.03
320.1588135	0.39
323.1934814	0.69
325.0614929	0.03
332.2395630	0.26
334.3803101	0.04
337.2689209	0.09
338.0523071	0.36
341.2471924	0.21
345.1203918	0.03
347.4869385	0.06
350.3706055	0.20
352.5283508	0.04
353.1452637	0.04
354.0819092	0.13
355.2556152	0.02
356.5449829	0.05
357.2806702	0.11
358.3828735	0.03
361.6055908	0.03
362.7343140	0.02
364.1730347	0.07
366.1243591	0.52
371.2568359	0.03
372.0770874	0.04
373.4270630	0.17
375.1547241	0.76
382.2525024	0.07
384.0011597	0.08
389.1601562	0.26
390.1226807	0.04
391.0226440	0.07
393.3432617	0.06
394.3923950	0.05
397.4233398	0.10
398.2260132	0.23
400.2802124	0.27
400.8968506	0.02
402.5866089	0.06
407.2385254	0.96
408.4013062	0.03
409.3649902	0.19
410.0888672	0.02
414.3083496	0.08
415.9719849	0.07
417.3253784	0.29
424.2441406	0.11
427.3796997	0.04
428.1562500	0.06
432.3880615	0.05
434.1884155	0.02
435.4099731	0.03
437.9374390	0.13
439.2763672	0.03
440.9312744	0.21
441.9500122	0.07
443.3437500	0.11
445.1062622	0.05
449.0491333	0.08
452.3300781	0.26
455.3403931	0.08
458.2787476	0.03
459.4725952	0.15
460.6110840	0.20
466.3750610	0.07
468.1405640	0.10
470.3632202	0.31
473.9967651	0.11
476.4085083	0.10
477.4965210	0.16
478.2285767	0.14
479.9227905	0.17
481.2910767	0.08
482.4766235	0.08
484.6665039	0.07
485.4237061	0.14
486.3256226	0.41
488.2514038	0.24
489.7398682	0.07
492.2134399	0.16
493.8639526	0.07
497.2032471	0.02
499.6801758	0.10
500.3750000	0.06
502.2951050	0.19
504.3813477	1.05
506.4023438	0.14
507.0590820	0.04
508.2839355	0.15
511.3344727	0.04
516.5453491	0.09
517.5702515	0.30
518.3878174	1.22
520.4191895	0.49
522.2585449	0.11
523.1454468	0.09
524.3237915	0.02
528.1859131	0.04
529.3114624	0.08
531.5178223	0.05
533.4398804	0.02
536.3248291	6.32
537.2735596	0.35
538.2922363	0.85
539.2540894	1.63
540.2532349	1.85
541.3766479	0.67
542.2269287	0.04
543.3477173	0.12
545.3196411	0.14
546.4503174	0.11
547.3147583	0.12
548.2761841	0.17
549.7445679	0.02
552.2597046	0.39
553.3957520	0.09
557.5594482	0.08
558.4890137	0.03
559.3934937	0.07
561.7683716	0.26
562.8673706	0.04
563.5108643	0.37
564.1434326	0.45
565.4898071	0.03
566.3413696	0.07
568.2546387	0.15
570.2675171	2.36
573.2659302	0.04
574.1900024	0.11
575.3740845	0.15
576.4088135	0.04
577.5105591	0.21
578.2992554	0.06
578.9830322	0.06
580.4943237	0.08
584.2063599	0.16
586.3550415	0.14
587.3303223	0.81
588.3100586	0.09
591.4463501	0.34
593.4656372	0.19
595.3494873	0.69
596.2788086	0.19
600.9760132	0.04
602.4510498	0.13
603.2930908	0.33
604.4432983	0.56
605.4701538	1.67
606.2864990	0.18
607.7899170	0.12
608.4186401	0.10
609.3522339	0.80
610.4801636	0.14
611.4984741	0.05
612.2706909	0.05
613.5230103	0.24
615.3947144	0.02
617.4592896	0.03
618.2972412	0.07
619.2502441	0.60
620.0813599	0.46
621.4024048	2.94
622.3239136	0.16
624.2310181	0.05
625.3514404	0.13
626.7416382	0.37
627.7554932	0.11
630.1618042	0.47
631.2421265	0.05
635.1316528	0.47
637.2783203	0.55
639.3263550	8.20
640.3502808	0.08
641.3433838	0.04
643.2158203	0.25
645.3418579	0.19
647.1535034	0.10
648.3322144	0.13
649.4328613	0.10
653.2528687	3.48
653.8805542	0.17
655.4682007	0.22
657.3469238	0.54
659.9631348	0.11
661.1511841	0.29
664.2052002	0.22
665.3220215	0.65
666.2454834	0.05
667.4896851	0.08
669.2789307	0.64
671.3479614	23.16
674.4409180	0.14
677.8037109	0.03
679.3593140	0.40
680.1243286	0.08
681.1542969	0.11
682.7207642	0.16
683.4140015	3.92
684.7789917	0.02
687.2799683	7.54
689.3649292	0.75
692.3555298	0.71
697.3054810	1.12
701.2873535	1.15
703.2672729	0.43
705.2741089	100.00
705.9260864	0.20
712.8621216	0.11
715.2585449	13.67
716.0110474	0.03
721.3391113	1.40
722.5558472	0.41
723.3671875	1.24
731.2251587	2.64
731.8793945	0.02
733.3305054	6.49
739.4244385	0.15
749.2379761	51.69
749.8497314	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
100.8298340	0.06
113.1144409	0.10
119.0325775	0.14
120.1348190	0.10
122.2167664	0.09
124.8048477	0.02
130.8988342	0.15
133.8703613	0.11
134.9779510	5.48
135.5878296	0.02
143.1418457	0.13
160.9333496	0.24
163.0429993	0.75
164.0377502	0.94
165.0606842	0.51
166.1291199	0.49
167.3495483	0.04
171.2321014	0.03
175.1029205	0.10
176.1481171	0.04
177.2320099	0.04
179.0174561	100.00
184.9702759	0.08
191.2184296	0.05
192.9869080	0.13
194.0787201	0.06
195.0862885	0.22
217.1924744	0.03
219.1227112	0.03
242.9219971	0.03
250.0240784	0.02
251.2241211	0.07
262.9866943	0.03
269.1074219	0.02
278.0446167	0.05
279.4494629	0.02
280.9924622	0.10
285.2505798	0.03
294.7286072	0.34
295.6527710	0.13
296.5142822	0.15
299.2321167	0.03
309.5206604	0.03
310.1843872	0.09
313.2374878	0.03
321.1696167	0.02
322.4227600	0.01
323.4918823	0.18
326.5303650	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1038
Annotation	Mollugoside
Peak:m/z	Relative Intensity
123.1049118	0.47
129.0082703	0.18
131.2882690	0.05
138.9789734	0.21
142.9939270	0.12
151.9290619	0.16
153.0049133	2.71
156.9791565	1.39
167.1164551	11.96
171.0275726	0.42
173.9212341	0.05
174.5467529	0.08
175.1972198	0.67
181.1911926	0.07
187.3015442	0.07
188.9936218	0.20
191.3053741	0.04
193.2063599	0.06
207.0872498	0.07
209.1801453	1.73
223.2214966	0.24
225.0991364	0.12
227.0777588	52.64
227.6808167	0.18
229.3750000	0.11
231.0904541	4.36
237.0338135	0.28
241.1323547	9.86
249.0911865	75.29
255.2021484	8.64
258.2647705	0.06
262.8665466	0.14
267.1264038	46.74
269.1889648	1.17
280.9956055	0.23
284.9976807	0.23
297.1322632	0.04
299.1202698	0.14
309.2388306	2.27
311.2781372	0.68
316.0961609	0.06
321.1481628	0.28
323.2814026	0.17
327.0989990	0.26
337.0345154	0.15
339.3024292	0.66
341.2608948	1.72
342.3405151	0.41
349.1682434	0.15
353.0156555	0.15
354.1296387	0.13
355.2607422	6.50
357.2108459	11.10
359.2009888	0.05
367.1616821	0.79
370.1842957	0.04
371.1630554	0.10
373.1525574	1.93
379.2757568	0.11
381.0838623	0.21
385.1960449	55.55
397.1875305	0.13
399.2771301	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2028
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
148.9425354	0.08
177.6137695	0.09
190.0993042	0.04
202.2858887	0.07
205.0324860	0.11
220.2351532	0.24
221.0129089	0.26
235.0694275	0.98
270.2806396	0.04
271.3920898	0.07
283.0540466	0.05
285.0488892	0.61
309.1348267	0.05
311.1489258	0.13
312.0892944	0.23
341.3126831	0.81
343.2328491	0.42
345.6242676	0.12
357.3190918	0.61
359.1111450	1.01
360.1513672	0.08
371.2330933	100.00
371.8388062	0.20
374.1971436	0.27
385.2675781	0.21
391.1498413	0.18
394.1691284	0.20
414.4010620	0.09
441.2351685	0.04
442.6704102	0.04
445.3878784	0.08
461.2167969	0.21
474.6509399	0.05
475.3277588	0.29
477.5175171	0.23
478.6107178	0.06
485.3259277	0.11
486.3298950	0.25
489.2972412	0.15
491.5053711	0.07
501.3076782	0.07
502.4539185	0.40
503.3749390	0.49
505.4009399	0.06
506.3721313	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	452.1576
Annotation	Unknow
Peak:m/z	Relative Intensity
143.9517975	3.69
152.1159668	0.16
175.3107605	0.15
182.1795044	0.12
195.0527039	0.06
199.2447205	0.16
231.3183441	0.11
235.2303467	0.09
253.1389465	0.10
260.3109741	0.08
264.2669678	0.15
272.2053223	0.37
273.1437683	0.38
293.3124390	0.21
294.9855347	0.07
306.1262512	100.00
311.3203430	0.19
356.0455933	0.07
366.2531738	0.29
409.4883728	0.12
411.1139221	0.33
417.5794983	0.29
429.1582947	0.09
433.9436951	0.22
435.4237671	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1353
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.1231079	0.06
162.0748749	0.03
165.1909943	0.07
168.1402740	0.10
175.1327972	0.18
178.9584351	0.06
187.2690735	0.06
188.1256561	0.09
191.0721741	0.03
199.8610229	0.10
201.2345581	0.02
201.8642883	0.02
203.2978821	0.20
204.2194519	0.10
205.0765076	0.63
206.8431396	0.04
209.3381042	0.02
210.9415283	0.06
215.0137939	0.07
227.2663269	0.05
228.1040955	0.08
229.1369324	0.08
230.2477722	0.12
231.0937805	0.05
243.1167908	0.07
244.1106110	0.03
245.1877899	2.68
246.2660217	0.42
247.0986481	0.28
255.1030579	0.03
256.2347412	0.03
257.2147827	0.04
261.3083191	0.02
269.1171265	0.43
270.2257690	0.06
271.1977539	0.22
273.1188965	1.51
274.1669922	0.29
275.0703735	0.03
287.2427979	8.19
288.2836914	1.39
289.2902222	18.33
290.2167969	3.43
291.0770874	0.08
299.2219238	4.93
300.1833496	0.93
305.3945007	0.15
310.2273560	0.05
324.3263550	0.02
327.1776733	0.18
329.1790771	0.30
330.7478638	0.17
331.4195557	0.33
332.3107300	0.08
337.3410645	0.03
339.4378662	0.28
341.0186768	0.18
342.5030518	0.03
345.6417847	0.05
347.5968628	0.05
357.2228394	0.38
358.5888062	0.03
364.2150269	5.33
365.4719849	0.17
366.4182739	0.11
370.9756470	0.08
378.2487793	0.06
381.3171997	1.02
382.5062256	0.34
385.2315063	0.05
386.7271729	0.12
388.3648682	0.06
393.3681030	0.12
404.1773682	0.03
407.2357178	46.45
408.2153320	9.57
409.2947998	0.27
410.6257935	0.19
411.3015747	0.14
413.4017944	0.03
415.4375610	0.14
416.3435059	0.07
423.1737671	0.36
425.2451172	100.00
426.2111816	15.76
427.2914429	0.03
433.2843018	0.23
434.3332520	0.14
437.2521973	0.44
438.3862305	0.12
441.2803955	0.06
449.2744141	0.65
451.2319946	28.36
452.2692871	6.66
454.3009033	0.02
462.2372437	0.13
467.2278442	1.12
468.4140015	0.15
473.1796875	0.04
475.3518677	0.09
483.2723999	0.13
486.6873779	0.14
488.0381470	0.04
489.8709717	0.13
491.4932251	0.52
492.3528442	0.17
493.3776245	0.06
497.2334595	0.18
499.3561401	0.09
500.0055542	0.04
501.0310669	0.03
501.7042847	0.09
502.8616333	0.03
504.2861938	0.05
505.2039185	0.11
515.2163086	0.58
516.2168579	0.04
519.4334106	0.08
521.0687866	0.04
525.0755005	0.11
532.0937500	0.08
533.3751221	1.99
534.2861938	0.34
536.2589111	0.03
541.4346313	0.21
545.3707886	0.08
548.4821167	0.05
559.3038940	11.46
560.3028564	2.44
561.2434692	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9026031	100.00
212.7442627	40.46
213.4221497	0.13
253.4299011	0.10
279.7319946	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.0549
Annotation	2-(Acetamidomethylene)succinate
Peak:m/z	Relative Intensity
75.8769073	0.02
84.0755615	0.03
102.0800476	0.14
110.8544769	0.01
115.9703064	0.02
125.9380646	0.01
127.8835907	0.01
142.0882111	0.11
143.8637238	0.02
144.6974945	0.05
146.1468811	0.04
160.0267487	0.01
167.1696014	0.02
169.9813080	100.00
170.9000702	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.2632
Annotation	Linoleamide
Peak:m/z	Relative Intensity
80.9244690	0.69
83.2180405	0.04
94.9443054	1.37
95.9959412	0.06
96.9717712	0.59
98.9756851	0.10
100.0573502	0.32
104.9330444	0.23
109.1711121	1.25
110.9600067	0.37
113.0809021	0.19
114.0567169	0.68
118.9322357	0.13
121.0882721	1.61
123.1255341	1.08
124.9689255	0.38
125.8675842	0.08
128.0651703	2.08
133.0126343	1.12
135.0561829	1.67
137.1199646	0.92
139.1124115	0.54
140.1416626	0.24
142.0310364	1.60
147.0783691	1.76
149.1048889	2.93
151.2273865	2.05
153.1025085	1.27
153.9930725	0.24
154.9844360	0.11
156.0132751	3.17
161.0430298	1.12
163.1233368	1.71
165.0211487	2.46
167.1752472	1.28
168.1123657	0.26
170.1772003	2.67
173.2115784	0.11
175.1206360	2.46
177.1469269	0.43
179.1658630	2.64
181.1930542	0.69
182.2918701	1.80
183.4766998	0.24
184.0848389	3.04
184.7101746	0.18
189.1865234	2.44
190.9830627	0.77
193.2557373	0.34
196.2200317	2.10
198.1978760	2.50
203.1465454	0.85
205.2642212	0.28
207.1805115	0.30
209.5934753	0.17
210.2052002	2.29
212.3793335	0.64
217.0660095	0.62
219.0292053	0.32
221.2061462	0.94
222.0764160	0.14
224.0945435	1.92
231.1507263	0.06
234.2794495	0.07
234.9369202	0.05
238.3038940	0.50
245.2060242	46.27
249.0502319	3.92
250.0640259	0.09
263.1657104	100.00
279.3492126	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.2283
Annotation	Buddlenol C
Peak:m/z	Relative Intensity
177.3031158	0.15
180.1289368	0.56
190.1123962	0.15
195.0337982	2.68
196.0512695	0.34
203.2151489	0.09
204.2087860	0.08
209.1030884	0.06
210.0723114	0.39
220.0839844	0.08
223.3768463	0.16
225.0711060	6.96
226.0879517	0.67
234.2700806	0.05
243.1399536	0.05
283.1689148	0.05
299.2286377	0.10
308.4053345	0.11
312.1838989	0.23
313.3013916	0.04
322.1130676	0.08
323.2893066	0.23
324.1890259	0.32
325.2973633	0.37
326.7268677	0.25
328.0754395	0.05
337.2688599	0.86
338.2516479	0.81
339.2146606	2.25
340.3311157	0.73
341.1893921	0.04
342.1312256	0.45
343.3238525	0.36
354.1810303	2.56
355.2659302	1.80
357.2288208	26.03
358.2661133	6.51
359.3433228	0.03
365.4579468	0.10
369.2727051	48.30
370.3378906	11.63
371.3116455	0.04
372.6013794	0.09
373.4260254	0.21
383.6585693	0.08
385.1166992	0.34
386.5388794	1.40
387.2893066	0.92
387.9348145	0.40
389.3587036	0.09
395.3589478	0.02
397.2952881	0.26
398.3668213	0.25
433.3347778	0.14
434.2272949	0.15
442.1670532	0.06
444.2059937	0.13
465.1633911	0.04
478.3652954	0.03
481.0317993	0.06
495.4618530	0.04
506.5671387	0.03
516.4061890	0.04
519.5717773	0.08
535.3826294	0.84
536.5509033	0.35
539.4606323	0.08
547.3500977	1.67
548.4387817	0.59
551.7191772	0.17
565.2919922	100.00
566.3973999	39.23
567.5844116	0.15
568.4082031	0.04
569.8112183	0.07
570.5277100	0.15
576.3225098	0.14
583.3682251	2.24
584.4830933	0.69
593.5952148	0.05
595.1727905	9.16
596.2501831	1.59
604.7810059	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1663
Annotation	Verbasoside
Peak:m/z	Relative Intensity
135.1338959	2.90
136.0517578	0.23
139.0514526	0.31
143.0970764	0.29
145.1706543	0.08
153.0498657	12.99
154.1333771	0.95
156.9427185	0.44
161.1761932	0.21
163.2111969	0.07
167.0133667	1.31
168.0615234	0.21
170.9396973	0.55
174.9149170	0.88
175.9927979	0.19
179.1251221	0.48
180.2175446	0.12
186.9999847	0.07
189.1168060	0.11
191.2950134	0.04
193.0609131	0.72
194.2228088	0.12
197.0387878	0.42
205.1310730	2.33
206.2835083	0.23
207.1513672	0.24
211.2143250	6.70
212.1964417	0.86
223.1313629	0.41
224.1723633	0.12
227.2625732	0.11
231.1076202	5.66
232.1604919	1.11
249.1235657	100.00
250.2024231	9.66
253.1013794	0.10
257.4322510	0.08
267.1347351	63.21
268.1144714	7.38
271.2592468	1.23
272.2286682	0.26
274.0042725	0.04
275.0788574	0.11
281.4066467	0.12
285.3607788	0.04
289.1846313	0.09
293.2886963	0.19
299.3743286	0.14
310.2818909	0.05
313.3137817	0.32
321.3190613	0.04
324.7878723	0.05
325.7963867	0.04
327.0876770	0.08
340.8045044	0.39
341.7416382	0.17
347.0059204	0.10
349.4199829	0.28
367.1658630	0.64
368.2644043	0.28
381.2663879	0.07
385.2672729	14.00
386.3507080	2.77
401.2683105	0.53
402.3450012	0.44
411.1741333	1.05
412.1101685	0.35
415.3137512	0.03
416.3776550	0.04
417.2881470	0.45
418.0349426	0.03
425.3206482	0.10
429.2850952	28.74
430.3244324	5.89
443.2163391	8.98
444.3331909	2.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	573.2184
Annotation	16,17-Dihydro-16a,17-dihydroxygibberellin A4 17-glucoside
Peak:m/z	Relative Intensity
160.4291229	0.02
163.0117645	0.03
164.1579437	1.07
166.3054504	0.03
167.0421906	0.11
177.9091797	0.06
179.4285126	0.04
181.1424561	0.20
182.0616302	0.02
187.0653076	0.03
191.4429016	0.03
194.1599121	0.08
202.2286987	0.03
204.1889343	0.20
210.2572632	0.04
217.1621857	0.16
219.0849457	100.00
220.1484375	3.27
234.1422424	0.02
303.1995239	0.01
307.0956421	1.39
317.2457886	0.03
325.1998291	0.02
337.5347900	0.03
339.4876709	0.02
343.4588013	0.07
349.1011963	0.11
353.2506104	0.14
355.1011353	0.02
367.4867554	0.06
376.1813965	0.01
377.3908081	0.15
379.2564697	0.02
393.4542236	0.08
395.3435669	0.02
405.1066895	0.04
431.1450195	0.27
431.7662354	0.04
432.4200439	0.04
449.2908936	0.21
450.5499268	0.02
455.1711426	0.04
477.5314941	0.02
481.3479004	0.03
484.2738037	0.08
497.6070557	0.03
506.0833130	0.03
508.0003052	0.03
515.4562378	0.02
525.4717407	0.80
526.9714966	39.29
528.0872803	1.61
529.2604370	0.07
537.3918457	0.08
541.3395996	0.06
544.1934814	0.06
546.0475464	0.03
553.3186646	0.02
555.4085083	0.51
556.4485474	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.1826
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9000854	0.07
223.9090881	0.03
281.1765747	0.02
309.2065735	0.02
311.1749268	0.06
312.5361328	0.03
320.4323120	0.10
328.2716980	0.07
329.1008911	0.22
330.4245605	0.03
367.4016724	0.07
382.2334595	0.08
386.4026489	0.08
389.0828857	0.04
408.3317871	0.23
410.2496948	0.02
415.4663696	0.04
417.2659912	0.03
422.9633789	0.03
426.3893433	0.16
434.2915649	0.11
437.4028931	0.09
438.5215454	0.04
442.2288208	0.04
452.2863770	0.34
454.2410278	0.09
469.8140869	0.22
479.0527344	0.06
480.2912598	1.22
489.2436523	0.03
490.3680420	0.07
494.3491211	0.14
495.3493652	0.02
497.3724976	0.07
498.3145142	0.34
501.3466187	0.11
503.3250732	0.05
506.2354126	100.00
506.9401245	0.25
513.9280396	0.02
519.3939209	0.11
521.3923340	0.02
522.9580688	0.05
524.3355713	7.18
526.4700317	0.05
527.1208496	0.06
531.3416138	0.04
535.5171509	0.02
536.2329102	0.13
542.2378540	0.11
554.3852539	0.02
559.5314331	0.08
568.0476685	0.07
571.1788940	0.09
588.2979126	0.06
589.3424072	0.09
596.7279663	0.05
599.5368042	0.12
600.5739136	0.09
619.5872192	0.23
627.3975830	0.19
629.6631470	0.08
638.2326050	0.06
644.4626465	0.25
653.1481323	0.06
654.3727417	1.96
656.4525757	0.02
669.1384888	0.19
671.0077515	0.25
672.3688965	10.22
687.6835938	0.04
695.3750000	0.15
697.2969360	0.41
698.3016968	1.38
700.5690308	0.03
701.3384399	0.10
706.5441284	0.11
707.3843994	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1153.2628
Annotation	Unknow
Peak:m/z	Relative Intensity
327.0185242	0.16
329.2538452	0.23
331.2064819	0.12
335.2176208	0.38
339.3040466	0.24
341.0478516	0.99
343.5050354	0.15
345.2962036	0.10
346.3373718	0.13
351.3472290	0.67
363.4308472	0.37
369.1138000	0.36
371.3020935	0.32
374.1865540	0.14
376.9801636	0.12
379.0586243	1.16
381.2229614	0.97
383.1356201	0.19
387.0812683	1.23
389.2738037	0.13
390.9231567	0.42
395.1405029	1.52
396.4480896	0.53
397.2455750	0.10
399.1235657	0.21
403.2236938	0.18
405.1965027	6.24
407.3490295	15.77
408.6354980	0.68
409.6094055	0.08
413.1368713	9.84
415.5318604	1.04
417.2765503	0.90
421.4490967	0.33
422.5933228	0.44
423.3040771	4.91
425.1777039	9.52
433.2748108	0.76
435.3073120	0.49
437.1866455	1.19
443.2284851	0.23
445.0625916	0.12
447.2717285	2.10
449.2419434	14.11
451.2029114	8.11
452.4166565	0.32
453.4057617	0.25
455.2894592	0.94
459.2676392	0.46
461.5505981	0.08
465.1072083	0.72
467.1177979	0.43
472.9929199	0.41
476.5750122	0.17
485.3026733	0.08
487.2443542	0.14
489.2257690	0.38
491.2372437	0.81
493.4522095	0.11
501.2955933	0.45
503.2607727	0.28
505.1516418	0.95
507.3107300	0.20
513.2982178	0.53
515.2244873	0.70
519.1719360	0.22
523.0788574	0.27
525.4558105	0.56
531.2360229	5.03
532.8775635	0.96
533.5022583	2.98
535.4515381	1.43
537.5388794	0.18
539.4354858	0.29
541.3400879	1.21
543.2049561	3.24
545.0175781	0.18
549.1751099	4.57
555.4516602	0.46
557.2153320	8.02
559.3320312	4.47
564.3345947	0.13
565.6234131	0.27
567.2027588	0.71
569.2591553	2.38
575.3228149	45.91
577.2332153	36.21
578.3041992	1.03
579.0651855	0.38
581.3959961	0.51
583.5783691	0.31
585.3637085	1.08
587.2659912	7.51
588.3057861	0.40
589.3201904	0.47
591.2125244	0.88
599.3480225	0.89
601.0746460	0.28
607.4029541	0.14
609.4222412	0.20
611.2243652	2.20
614.2993164	0.23
617.1884766	3.27
619.3878174	1.91
625.1518555	0.12
627.6491699	0.12
629.3997803	3.50
633.1368408	0.35
635.5770874	0.35
639.3704834	0.14
641.3555908	0.46
643.6340332	0.17
644.5901489	0.29
647.2005615	0.34
649.6602173	0.24
651.1840820	0.90
657.1154785	1.03
659.7355957	0.23
660.6275635	0.49
661.6988525	0.36
664.1942139	0.16
665.6314697	0.27
667.2879028	1.30
669.4091187	0.37
670.0478516	0.12
671.4132080	0.40
675.4107666	0.12
677.2062378	0.70
683.3327637	6.61
685.1479492	0.23
693.2722778	7.50
695.2806396	17.30
696.4859009	0.37
701.2375488	23.38
702.4541016	0.49
703.0902100	0.10
705.3521118	1.03
709.5606079	0.25
711.2608032	3.37
713.2526245	5.27
719.3044434	0.27
722.1613770	0.17
723.2843018	0.20
724.0603027	0.11
727.0067139	0.29
737.2377930	15.74
739.2575684	46.38
740.2305908	0.49
741.2841797	0.22
743.5367432	0.21
746.3489380	0.17
747.4601440	0.56
753.5067749	0.46
755.3377686	1.36
756.3908081	0.16
759.4014282	0.44
761.4827881	0.27
763.3811035	0.12
769.6323853	0.19
777.1889648	0.26
779.5184326	0.20
781.5249023	1.54
787.5059814	1.03
789.4718628	0.15
797.5390015	0.83
799.4129639	0.14
803.1801758	0.65
805.3935547	0.99
806.9815674	1.50
813.1955566	5.37
821.3334961	6.89
823.0660400	0.76
824.5173340	0.23
830.6005859	0.10
831.2258301	7.33
832.2143555	0.23
833.4812012	0.52
843.4421387	0.11
845.2781982	6.27
846.6070557	0.40
847.2780762	10.93
849.3212891	2.06
857.2883301	6.24
858.2810059	0.17
863.2409668	58.76
865.2825928	99.18
866.2161865	1.32
867.0043945	0.07
873.4129639	0.49
874.4335938	0.38
875.2233887	4.09
876.2393799	0.17
889.3244629	1.83
899.2574463	0.53
901.3422852	0.13
905.4458008	1.24
906.6024170	0.84
907.3398438	20.37
917.2110596	1.28
918.1922607	0.14
927.2872314	1.25
933.0043945	0.49
939.1746826	1.10
947.1716309	0.36
957.2886963	3.13
965.3049316	8.88
966.4147949	0.27
967.2993164	0.89
978.5430908	0.14
983.3311768	100.00
984.4232178	0.72
985.3648682	2.16
986.3656006	0.29
991.0993652	0.24
997.2496338	0.48
999.4890137	0.14
1001.1784670	42.55
1001.7995610	1.74
1002.5330810	0.26
1009.1152340	4.63
1009.7406010	0.67
1010.3520510	0.14
1025.5434570	1.28
1027.2004390	65.34
1028.3142090	0.94
1043.2089840	2.04
1044.5212400	0.15
1059.7227780	0.77
1069.3603520	0.55
1073.5629880	0.07
1090.5498050	1.15
1091.3654790	0.11
1109.3660890	5.33
1117.4963380	0.51
1118.3151860	0.18
1135.2309570	42.14
1135.8569340	0.70
1136.4951170	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0981
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
126.9447479	0.09
135.1421204	0.33
136.9326935	0.17
151.2044373	0.07
161.1273804	0.25
171.2073059	0.19
173.0611725	0.98
179.0827179	2.15
191.0846863	92.90
203.1149597	0.08
227.1740112	0.62
233.2377014	0.39
234.8841248	0.41
243.0835571	0.05
247.3137817	0.14
251.8211365	0.07
256.2853394	0.24
261.0134888	0.09
265.1486816	0.31
267.0667114	0.04
279.1546021	0.16
281.6585083	0.23
295.0097656	0.43
308.2823486	0.22
309.2076416	0.32
311.2061157	0.07
323.3385315	0.16
324.5738525	0.49
325.2308960	1.32
327.1613159	0.38
335.3138123	0.13
342.2175293	0.13
343.3504028	0.14
353.1184387	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	337.0909
Annotation	Altersolanol A
Peak:m/z	Relative Intensity
100.0105591	0.02
110.9669037	0.18
117.0276871	0.02
120.9952393	0.24
123.1278839	0.09
130.0561829	0.02
134.9197388	0.10
136.9632568	0.11
138.9154968	5.01
139.5428314	0.02
144.8994141	1.77
156.9909058	12.28
162.9732056	100.00
174.0113525	0.13
180.9786224	17.20
182.3438568	0.05
188.2583008	0.04
193.0733032	0.03
195.0658722	0.06
201.1004028	0.09
201.9602966	0.04
203.0265808	0.03
209.8894348	0.03
211.1368103	0.60
213.1234436	0.11
223.0597229	0.14
226.9899292	0.44
229.0845337	0.19
229.8905945	0.09
230.8414612	0.01
237.2377625	0.04
238.1080627	0.07
239.3490906	0.11
245.2933044	0.08
247.1697998	0.61
248.0377197	0.16
254.4413147	0.13
255.1604919	1.27
257.0975647	0.52
258.3352356	0.02
259.0802917	0.13
265.3026123	0.11
273.1080322	0.91
274.7783813	0.02
277.1930237	0.05
278.9660645	0.03
283.0640869	1.46
291.0032959	0.02
291.9677734	0.05
301.2060242	2.64
305.2114868	0.06
309.0650330	0.14
319.2167053	5.13
321.2419434	0.04
322.3179016	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.1087
Annotation	Androsin
Peak:m/z	Relative Intensity
93.1729279	0.02
101.2416077	0.06
113.0746002	0.06
121.0784912	0.24
129.0073090	1.02
130.2522583	0.03
135.1676636	0.02
137.1609192	0.10
139.2536926	0.04
144.9619141	0.01
146.9642029	7.14
158.9547424	0.06
161.0685425	0.04
163.1270142	0.09
165.0168915	100.00
179.1074524	0.03
189.0599518	0.05
191.1674194	0.06
207.1767273	0.19
217.0192566	0.02
218.9446106	0.05
231.2348633	0.07
237.3273621	0.02
240.1433716	0.02
243.2238464	0.10
245.2874451	0.04
254.9655151	0.01
265.2801514	0.04
267.2686157	0.02
269.0901794	0.03
280.9497681	0.02
283.3183594	0.02
291.2971802	0.04
294.2751770	0.02
309.1694336	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	553.2291
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
159.1606445	0.18
162.5121460	0.02
166.1553192	0.01
171.9349518	0.02
173.2849274	0.03
174.9775085	0.04
178.2609711	0.02
180.0345612	0.05
181.0682983	0.28
188.3384705	0.01
189.3025818	0.03
190.1383667	0.02
191.1331482	0.03
192.2608948	0.04
192.8768311	0.01
194.1230927	0.04
195.0842285	0.35
203.0622864	0.01
204.1125031	0.03
204.8312988	0.02
207.0929260	0.06
209.3678589	0.02
217.2218781	0.03
221.1292419	0.04
222.3033142	0.01
223.2176208	0.01
225.2016907	0.04
232.2105255	0.01
235.3188477	0.02
237.5408020	0.01
245.1996155	0.01
247.2155762	0.02
249.9562988	0.02
280.5601501	0.02
297.2622070	0.05
300.3264160	0.01
303.1117554	0.02
311.0820312	0.06
312.1723633	0.01
313.0404053	0.01
323.5631104	0.02
325.2052612	0.02
326.2007446	0.18
327.2676392	0.57
339.0782471	0.03
341.3157959	0.63
342.3510742	0.06
343.1505127	0.02
346.2584839	0.01
347.4115601	0.01
352.3403931	0.01
353.5178223	0.06
355.5490723	0.02
357.3766479	0.32
358.2714844	0.15
359.3913574	0.02
371.2699585	0.48
372.1354980	0.03
373.3468628	0.95
374.3374634	0.76
376.0480957	0.01
377.4753418	0.01
381.2687378	0.08
385.2780151	0.08
387.0173950	0.01
388.3173218	4.65
389.3976440	0.99
390.6293335	0.03
391.4500122	0.10
393.3699951	0.12
396.1005859	0.01
400.4826050	0.01
401.4415894	0.02
403.3129272	9.08
404.1058350	0.03
406.2944946	2.28
407.4281006	0.41
408.5023804	0.04
419.4140015	0.03
421.2841187	100.00
422.3029175	0.03
430.6176758	0.01
435.5933838	0.04
445.7809448	0.02
449.4890137	0.02
460.4472656	0.01
463.5690918	0.02
474.9356079	0.02
476.1322021	0.01
479.2567749	0.01
489.0575562	0.03
491.3639526	0.32
505.4379272	0.06
506.3612671	0.06
507.3759766	0.11
508.3895264	0.11
514.1183472	0.03
515.3562622	0.03
517.5798950	0.01
521.3582153	0.31
523.2929077	0.26
524.3671875	0.01
529.7993774	0.03
535.4286499	0.52
538.3789062	8.74
539.0687866	0.07
543.6104126	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	183.0858
Annotation	Allitol
Peak:m/z	Relative Intensity
66.6297455	0.04
68.9284363	2.16
71.0749512	0.05
80.9609909	0.32
82.9372406	0.51
85.0061493	0.07
87.0106506	0.37
90.9495010	0.43
98.9987946	0.22
100.8835144	0.05
103.0186157	0.05
110.9747162	1.79
116.8578644	0.03
123.1323700	0.08
127.6871643	0.03
128.9464111	12.38
138.9527130	0.01
142.8875580	0.10
144.0018921	0.04
145.4332581	0.12
146.9098511	48.89
164.9070587	100.00
165.8972931	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8254547	100.00
187.9976501	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.14
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
161.1022797	0.12
162.2286987	0.04
179.0559082	1.43
180.0515137	0.36
181.2179565	0.06
221.1575928	0.72
222.3192749	0.04
234.0594177	0.05
245.5128479	0.03
250.6821289	0.17
262.9145203	0.10
268.7168579	0.03
279.7600098	0.04
281.0374146	0.17
281.7933960	0.09
289.4138184	0.03
304.9039917	0.12
323.2046509	0.62
324.1744995	0.08
325.0562744	0.17
341.0204468	2.83
342.1394043	0.82
343.0946655	0.22
359.9161987	0.08
361.0399780	0.19
377.2827148	2.68
378.2125854	5.41
379.1831055	10.60
379.7881470	0.05
383.4846802	0.07
384.5007324	0.04
385.6367188	0.03
503.2915039	100.00
504.3154297	63.59
505.2827759	17.31
524.9569702	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.14
Annotation	Fast green FCF
Peak:m/z	Relative Intensity
229.9458923	0.04
231.1420135	0.04
254.0415649	0.02
256.3270264	0.03
272.1296997	0.03
288.3165588	0.25
289.1500854	0.02
294.3913574	0.05
306.1820068	0.49
313.2316895	0.04
314.8117676	0.02
345.1465454	0.16
353.3763428	0.04
354.1101074	0.02
363.3875427	0.02
366.2461243	0.06
375.5571899	0.05
376.4634399	0.02
387.3859863	0.12
389.2012329	0.23
402.3066406	0.03
405.1408081	0.04
407.4249878	0.10
423.2890015	0.80
431.0535278	0.02
431.8079834	0.02
433.2868652	0.20
438.9619751	0.04
441.3314819	1.90
451.1029663	0.09
455.5552368	0.02
457.2742920	0.36
459.1141357	0.09
467.1740723	0.19
473.1797485	0.04
475.2200928	10.70
475.8909302	0.09
478.3322754	0.04
480.4047241	0.06
485.2127075	5.70
485.8403320	0.03
488.4320679	0.03
491.3038940	0.18
493.4087524	0.42
501.2153320	0.17
503.2456665	3.01
513.2133179	0.09
519.2042236	2.99
519.8130493	0.03
527.6646118	0.03
531.1624146	0.10
531.8184814	0.06
535.2286377	0.12
537.2029419	100.00
545.0280151	0.03
547.1828003	0.02
549.3287354	0.63
551.5025635	0.03
571.4755859	0.04
594.2345581	0.02
605.2044678	0.10
618.1698608	0.06
623.4236450	0.05
625.5338745	0.03
631.2273560	0.09
639.4331055	0.06
646.9877319	0.13
657.2138672	0.61
662.4540405	0.02
666.2280884	0.09
667.2409058	0.26
673.8237915	0.03
675.2437134	0.20
676.3456421	0.16
682.7751465	0.02
683.3964844	0.08
685.2043457	0.02
691.2971191	0.02
693.1669922	0.05
698.0518799	0.09
700.2514038	0.26
701.3218384	4.93
710.7282715	0.14
711.3508911	0.36
718.2196045	2.80
719.1919556	1.10
720.4409180	0.02
728.3118286	0.09
729.1753540	0.54
742.5654907	0.02
743.6897583	0.08
744.3256836	0.15
745.2790527	1.52
746.3369751	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1875
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
151.1390533	0.06
157.2276917	0.01
158.9107513	0.02
161.1559296	0.31
168.9293976	0.02
176.9088440	0.10
178.0045776	0.01
179.1776733	0.03
198.9174805	0.01
203.2088928	0.01
254.6314087	0.01
262.9755859	0.01
265.2644348	0.01
267.2190857	0.04
275.1734619	0.02
279.1054077	0.01
280.2735596	0.01
283.2630920	0.42
287.3967896	0.03
288.9923096	0.01
291.4088135	0.01
295.3070068	0.03
306.3024902	0.01
310.4765625	0.02
311.2948608	0.11
313.0950317	0.16
319.2343750	0.01
325.2661133	0.01
327.3442993	0.10
329.4080811	0.01
338.1858521	0.02
339.5367432	0.02
340.3147583	0.04
341.4025879	0.01
343.1647949	0.01
355.5858154	0.02
357.1960449	100.00
358.0083618	0.01
361.4462280	0.03
363.0430908	0.01
369.2755737	0.05
374.0297852	0.02
385.5123291	0.01
387.3139038	0.01
389.2807007	0.01
398.4589233	0.06
399.2156372	0.30
399.9712524	0.02
409.7301025	0.03
413.3867798	0.01
416.2814941	0.01
421.3638306	0.01
422.7789307	0.03
423.4463501	0.03
431.3989868	0.02
440.9840088	0.01
443.6737671	0.02
445.1973267	0.01
449.0538330	0.01
455.2304688	0.01
457.1929932	0.04
458.0578613	0.01
467.2650757	0.08
472.7246704	0.16
473.3344116	0.60
475.1377563	0.36
483.0904541	0.02
485.4232788	0.03
499.3305054	0.05
500.3044434	0.03
501.3177490	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.2026
Annotation	Gigasol
Peak:m/z	Relative Intensity
161.4569855	0.23
162.0843353	0.21
165.1464844	0.37
175.9022064	0.15
177.0457458	2.12
177.8805542	0.05
179.3040771	0.06
181.0735779	1.00
187.1025085	0.05
188.0819550	0.22
189.3226166	0.14
195.0880890	3.00
203.0293274	0.05
203.9238739	0.03
206.0065613	0.08
206.9766693	0.09
237.5003662	0.05
241.2208862	0.12
279.1822815	0.08
280.2852783	0.02
281.2952271	0.02
285.1123047	0.10
286.3873291	0.04
287.9450684	0.05
291.1401978	0.04
293.5484009	0.14
294.2725830	0.08
295.1540833	0.19
305.1901855	0.16
306.4074097	0.11
308.1715698	0.13
309.2203369	0.51
310.2693481	1.56
313.2241211	2.10
316.2904053	0.05
319.0916138	0.04
323.2628174	1.10
324.3679810	6.04
325.2088623	19.50
326.3488159	0.20
327.4147949	0.06
328.1337280	0.04
334.2823486	0.09
337.3381958	0.46
338.5202637	0.14
340.2588501	2.90
341.1912842	3.31
342.0255737	0.10
343.2278442	46.49
345.3256836	0.44
353.2361450	0.81
355.2139282	44.78
356.0010986	0.01
357.3395996	0.37
360.4341431	0.04
361.2874146	0.13
362.4202271	0.16
369.1079712	0.36
370.2885132	0.06
371.4519653	0.43
373.2282104	22.16
376.3715820	0.11
377.4538574	0.09
381.4146729	0.03
386.4266357	0.03
387.1820679	0.05
388.1932983	0.09
389.2415161	0.11
390.1703491	0.16
391.1743164	0.21
394.3753052	0.09
397.2533569	0.04
403.1851807	0.04
405.5416870	0.10
406.2084961	0.04
409.3824463	0.24
417.8091431	0.03
418.4756470	0.13
419.3020020	0.45
427.3591309	0.41
433.0748291	0.05
437.3341064	0.17
439.6915283	0.09
445.2999268	0.24
453.5354614	0.04
459.9076538	0.04
461.0109863	0.19
463.2113037	0.02
466.1436768	0.09
467.4567871	0.06
472.7810669	0.31
473.5552368	0.07
479.3779907	0.09
485.4672241	0.11
490.1701660	0.07
491.3840942	0.99
503.4384766	2.09
505.2554932	0.05
506.9918823	0.09
509.3804321	0.06
521.3493042	100.00
522.8748169	0.45
524.6751099	0.09
525.4545288	0.03
531.4343262	0.21
532.5573120	0.31
533.1937256	0.73
537.4630737	0.05
539.2969360	4.78
546.8988647	0.10
551.2112427	14.34
552.1228638	0.07
553.7517090	0.25
559.8923950	0.19
575.2500000	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	361.07
Annotation	Cyclocanaliculatin
Peak:m/z	Relative Intensity
119.0905609	0.14
130.0329895	0.61
131.2117615	0.06
132.7272491	0.20
154.0039673	0.11
155.0191345	0.29
157.7691040	0.17
171.2367401	0.13
183.1049805	0.08
185.8609924	0.55
191.4362183	0.06
196.9711304	0.07
203.2158966	0.07
209.2147369	0.21
213.2447815	0.49
214.0366821	5.86
228.4112549	0.15
229.3455811	0.08
230.8500977	0.35
231.9605103	0.38
241.2009583	0.16
244.8798218	0.11
245.9986267	0.17
248.1748352	0.09
255.1103516	0.06
256.0640564	0.11
257.1373901	0.06
259.3331299	0.09
261.9605103	0.17
271.3518066	0.05
273.2746582	0.04
277.2183228	0.08
280.1320801	2.25
287.2772522	0.22
290.2210693	0.19
297.2056580	4.43
301.1159668	0.22
303.0787354	0.08
306.0162964	0.04
315.1194153	24.19
325.0726318	0.19
338.4956970	0.09
341.4111328	0.05
343.0036316	100.00
344.1276245	0.22
352.0960693	1.07
360.8756714	0.11
366.7938843	0.10
369.4782410	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	599.2134
Annotation	Tasumatrol V
Peak:m/z	Relative Intensity
177.0483398	0.17
178.2678375	1.31
179.1293640	0.31
181.0506134	0.06
191.9620514	0.36
193.0363159	16.07
195.0324402	0.97
196.2999420	0.11
204.9748535	0.05
206.0217285	0.09
207.1063843	1.66
208.2962036	0.25
208.9459839	0.21
221.1717377	0.07
223.2286377	0.27
237.1439209	0.08
239.2084503	0.18
240.9686737	0.10
261.1942749	0.06
283.4421387	0.11
309.4038086	0.15
341.1405640	0.09
343.1363525	0.40
356.2844849	0.09
357.4544678	0.17
367.5227051	0.11
369.4741821	0.18
373.4790649	0.63
374.2909546	0.24
389.0834351	0.15
391.2437134	0.30
397.4079590	0.14
399.3855591	0.06
400.1198120	0.06
401.1978149	0.08
403.1885376	8.48
407.3240356	0.05
416.7992554	0.19
419.3135986	0.50
421.5404053	0.05
422.5789185	0.07
425.5504150	0.05
436.6286011	0.29
437.2301636	0.42
440.2981567	0.05
441.4846191	0.08
445.3836060	1.15
457.3552856	19.95
461.3400269	0.18
475.0369873	0.34
477.1210327	0.20
489.4879761	0.07
491.4114990	0.16
495.9614868	0.07
503.5005493	0.14
509.5832520	0.13
513.1610107	0.16
514.3728638	0.12
519.5317993	0.19
537.4877930	0.17
539.4539185	0.12
541.6811523	0.13
551.3732300	100.00
553.3022461	0.41
554.3873901	0.19
555.3627930	0.94
563.4063110	0.83
567.5863647	0.24
569.1264648	0.20
570.2813110	0.12
580.8762817	3.45
581.4763794	7.70
584.3698730	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.1334
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
254.2492981	0.06
288.1217957	0.07
298.9775696	0.02
306.3078003	0.25
311.2343750	0.02
316.2327271	0.04
322.0932617	0.02
327.3452759	0.04
329.0371094	0.03
345.3203125	0.06
349.1856384	0.02
377.2629395	0.02
379.1229858	0.02
389.6248779	0.05
391.3646851	0.09
394.4510498	0.05
399.0256958	0.04
403.0167236	0.06
405.3529053	0.02
410.1622314	0.13
415.2413940	0.08
417.6812744	0.03
419.3577881	0.04
423.4331055	0.18
435.5520020	0.03
438.0636597	0.05
441.3577881	0.08
444.7206421	0.02
449.2001343	0.04
450.1756592	0.03
457.3738403	0.08
467.2233887	0.90
472.2958374	0.06
475.1353760	0.04
483.3951416	0.07
485.3206177	0.92
488.4272461	0.10
499.4026489	0.01
501.2840576	2.54
503.3035889	0.04
514.2535400	0.04
517.4619141	0.04
519.2523193	100.00
520.1047363	0.06
524.3916016	0.03
531.0635986	0.02
532.1674805	0.22
536.1789551	0.14
537.5073853	0.04
543.4879150	0.04
544.9829712	0.03
551.4458618	0.20
552.0966187	0.26
553.2665405	0.26
557.4053345	0.02
561.2402344	0.17
564.4119263	0.07
565.4188232	0.04
567.2426147	0.03
571.3895264	0.06
575.3954468	0.01
582.0265503	0.06
595.2075806	0.08
604.4013672	0.01
611.1448364	0.04
613.4873047	0.04
616.2192383	0.10
619.9511108	0.02
621.4218140	0.04
622.1412964	0.03
623.2929077	0.05
637.4310913	0.06
639.1114502	0.08
647.3307495	0.04
648.7527466	0.02
657.2670288	0.12
659.0991211	0.01
667.2135010	0.03
668.6478882	0.10
671.4178467	0.03
678.2064819	0.01
682.7105103	0.07
683.3382568	0.60
698.0899048	0.72
699.0364380	0.06
700.1493530	0.05
701.4121704	1.91
708.2293091	0.07
709.6267090	0.01
711.2103882	0.04
712.3099365	0.06
713.2476807	0.10
714.7537231	0.05
720.5120239	0.01
726.5025024	0.42
727.4287109	0.30
730.3552856	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.205
Annotation	Rabdokunmin D
Peak:m/z	Relative Intensity
100.1105499	0.05
117.0534973	0.21
128.0642548	0.14
133.0151672	0.20
139.0805817	0.18
140.8521881	0.60
151.1453247	0.12
159.2377014	0.06
162.6159973	0.06
165.1011353	0.05
173.1458740	0.18
175.0252533	0.28
177.1551819	0.05
179.0090942	0.11
182.9035034	0.13
185.1743469	0.17
192.9332275	0.31
197.1312561	0.40
205.1779022	0.13
207.3974304	0.24
217.2498779	0.28
218.8646545	0.13
221.4861450	0.08
223.1207581	0.06
226.6582947	0.13
231.1881409	0.44
239.2062073	0.09
241.3186951	0.14
249.2970276	0.22
251.3147888	0.20
254.7674866	0.19
256.2113953	0.29
257.2048340	0.56
259.1703491	0.44
265.2412720	0.20
269.2450867	5.13
271.4639893	0.24
272.1434021	0.08
273.4068604	0.23
284.2706909	0.14
287.1972046	52.32
288.1912231	0.08
289.1061096	1.28
291.3156738	0.17
297.2221375	0.95
303.5216675	0.78
305.0848694	0.58
306.2950439	0.06
309.8561401	0.75
312.2263184	0.06
315.2181091	100.00
316.0996094	0.21
333.3193359	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1825
Annotation	Scopolin
Peak:m/z	Relative Intensity
272.2107544	0.02
321.5115356	0.11
322.4543152	0.06
340.3149719	0.02
341.4841003	0.03
351.2708130	0.13
353.0844727	100.00
353.6912231	0.26
469.5512695	0.03
513.2832031	0.23
514.3637695	1.21
515.2160645	0.58
544.8111572	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.1542
Annotation	Leucyl-Proline
Peak:m/z	Relative Intensity
68.0512543	0.06
69.9712982	13.41
81.1271668	0.09
95.9522705	0.09
98.0938568	0.11
113.9697113	3.02
115.1764069	0.15
116.1871948	0.23
124.0415344	8.71
126.0965424	4.50
126.7112732	0.04
132.1366119	0.61
135.1677551	0.06
141.9935150	100.00
156.7249603	0.06
158.0886230	0.23
165.9218292	0.11
167.0915680	0.36
169.8876801	10.27
173.1987610	0.04
182.7821503	0.20
183.9933319	0.11
184.9897156	0.13
187.5394745	0.13
201.1526184	0.21
210.5382843	0.22
211.2407074	1.10
212.2754822	0.29
229.3246613	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
99.0051651	0.14
101.0485687	6.68
106.8115540	0.45
112.9581985	17.04
115.0014648	0.64
116.9286804	0.33
118.9906998	15.92
124.9992142	2.69
130.9963074	7.40
142.9378662	20.86
149.0886230	3.51
159.0556335	0.58
160.9988708	19.97
178.9508362	100.00
182.9989929	0.65
184.0636902	0.13
185.2976074	0.23
198.1396027	0.25
213.1954956	0.24
220.3681946	0.43
221.2365112	0.57
242.0755310	0.10
261.4226379	0.47
262.9370117	0.32
275.6145325	0.15
280.5272827	0.40
281.1602783	3.32
340.5574646	0.22
341.5576782	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.2342
Annotation	Xyloccensin P
Peak:m/z	Relative Intensity
215.0627899	3.64
216.3819733	0.16
234.1620483	1.01
244.2465973	0.19
247.1309509	0.38
249.1267395	5.15
250.2402039	0.20
257.0218811	0.45
261.1100159	0.22
263.2629089	0.41
281.0820007	0.58
282.9458923	0.32
294.1805420	0.53
296.2911987	0.37
300.9907837	0.21
307.1130981	0.22
308.2383423	1.14
309.0808411	0.16
313.2068176	1.42
320.0853577	0.39
325.1047363	0.39
327.1534424	0.31
328.4738159	0.22
329.2673950	0.20
337.2399902	0.18
339.0913086	0.61
341.3037720	3.73
342.5298462	0.89
343.3023071	1.27
344.3277588	0.29
351.1760254	54.21
352.1452026	7.22
353.3765564	0.66
354.2304077	0.29
355.3091736	2.49
356.0755005	1.02
365.2700500	2.31
366.1740112	8.63
367.2194214	100.00
368.2797241	14.24
369.2685547	5.31
370.1738281	1.40
371.1158447	0.68
372.0985718	0.29
373.2938232	18.63
374.2319336	2.08
387.1636963	0.24
388.1255493	0.18
391.4337769	0.22
395.2107544	0.12
409.6554565	0.18
421.3292236	0.77
423.2468872	0.26
492.4274902	0.53
500.1720581	0.22
503.4363403	0.25
504.4393311	0.35
507.4217529	0.24
512.4647217	0.32
515.2213135	0.46
521.1490479	0.13
522.8837891	0.37
525.3000488	0.19
527.3711548	0.37
529.3038940	23.28
530.2780762	6.69
531.1264038	0.38
532.9564209	0.91
534.3082886	1.03
535.1945801	1.33
536.3854980	0.63
539.3090210	0.26
540.3582764	0.61
541.5390015	1.44
543.4133911	0.74
544.5531006	0.18
545.2460327	0.32
547.5505371	0.35
551.1353149	0.14
559.3118896	15.77
560.2019653	16.07
561.3190308	10.07
562.3391724	0.91
565.1864014	0.24
566.6205444	0.25
569.3609619	0.41
571.2464600	0.56
575.3319702	2.45
576.4627075	0.27
583.4608765	2.34
585.3087769	1.00
586.4736938	0.21
595.5274048	0.18
597.4966431	0.33
598.4551392	0.35
603.8356934	1.72
609.5905151	0.21
615.2249756	7.06
616.1902466	2.54
621.3681641	0.15
633.2999268	3.92
634.4771729	0.13
660.1821289	0.21
671.4008789	0.57
672.2677612	0.36
677.1126099	0.25
678.2717896	0.60
689.8640747	0.18
691.3944702	1.03
695.4350586	0.37
703.4807129	0.32
709.2963257	4.04
710.3717651	2.53
713.9054565	0.13
721.2980347	1.42
722.1696167	0.22
725.5997925	0.49
735.9845581	0.17
739.2445679	9.36
740.4926758	2.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	431.026
Annotation	Unknow
Peak:m/z	Relative Intensity
148.0370789	0.10
156.8220520	0.07
165.1732025	0.22
176.9843140	0.04
179.1243591	0.15
182.8934937	0.13
187.0720520	0.19
191.0438690	0.17
196.0971069	0.62
198.1152954	0.09
203.2764130	0.13
203.8959045	0.12
218.0657349	0.16
221.1027222	0.06
224.0628662	0.15
238.1079407	0.10
239.0995789	0.11
239.9091187	0.28
241.3297729	0.15
245.1617126	0.21
260.3602600	0.23
261.2988586	0.06
263.0226746	0.06
266.3783875	0.07
267.9698486	0.16
268.9726562	0.28
280.0899353	0.16
281.2760925	0.08
281.9817810	0.10
283.0472412	0.44
283.8354492	0.23
290.0952759	0.13
291.0938110	0.15
298.5695190	0.45
300.0196533	0.05
301.4059143	0.15
302.3081665	0.12
307.1694031	0.53
314.1724854	0.18
314.9425659	0.06
318.9028625	0.66
321.4674377	0.17
323.1427612	0.26
326.1958313	0.33
341.1834106	0.07
347.0222778	0.24
348.0197144	0.05
348.9502258	1.92
352.3251648	0.10
364.9376526	0.21
365.5876465	0.13
366.5106201	0.38
368.2786560	0.29
369.1918640	0.08
370.7567444	0.10
371.4103699	0.12
376.9632263	0.12
385.0450134	100.00
385.7931824	0.33
389.1971741	0.37
394.4622803	0.62
395.1808167	0.03
399.1519775	0.17
401.6034851	0.24
402.4531555	0.12
411.1069641	0.16
412.4163513	0.89
413.3765564	0.71
414.2235107	0.26
421.5494080	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	720.158
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9031830	0.54
205.4522095	0.18
217.6427155	0.27
218.3454742	0.20
223.2684326	0.62
227.0890961	0.71
231.1754150	0.18
243.1348572	1.69
245.2045593	2.12
246.2386169	0.77
261.1386108	1.31
262.2397461	0.66
273.0895081	0.29
281.3706970	0.04
285.1383667	0.53
287.1786499	6.73
289.1416016	25.31
290.2073059	2.31
297.4118652	0.12
299.2146301	1.09
300.3118286	0.10
301.3012085	0.18
303.0412598	0.18
311.5198364	0.35
313.2683716	0.32
315.1654663	0.54
327.2796631	0.09
328.3828125	0.17
329.5072632	0.19
331.3059082	2.42
332.3140259	0.99
340.4766846	0.20
341.2760620	0.41
342.2236938	0.55
354.3101501	0.06
358.2188721	0.07
363.1591797	0.85
364.5917969	0.08
378.4931030	0.12
381.2846069	0.08
383.4022827	0.50
385.1373291	0.14
390.5631104	0.28
395.2232666	1.16
396.0946655	0.51
405.2832642	1.31
406.1132812	0.99
407.2414551	6.32
408.2496338	0.65
409.2401123	1.21
409.9525146	0.06
413.1632080	3.75
414.1624756	0.47
415.2403564	0.40
418.3183594	0.40
419.0965576	0.39
423.1196289	2.91
425.2283325	5.91
426.2091064	0.98
431.2239990	0.48
433.6018066	0.25
437.0148926	0.26
449.3101807	5.76
450.3670044	0.44
451.2390747	6.37
452.3527832	0.81
453.3906250	0.65
454.2844849	0.16
455.2854004	0.66
456.6898193	0.11
465.2750854	0.64
467.0734863	1.15
468.4841919	0.13
469.2462158	0.56
474.3588257	0.71
478.8535767	1.01
481.2927856	0.33
482.2551880	0.96
483.0123291	0.19
486.9841309	0.84
490.5875854	4.64
492.0380859	1.11
492.7910156	0.55
494.5310059	2.82
499.4062500	2.83
500.5570068	2.14
502.7762451	0.15
503.8442993	0.57
507.3374023	0.35
512.9246216	0.28
514.1519775	0.99
515.3883057	0.35
519.8754272	0.62
525.3452148	0.50
527.3872681	1.79
528.3775635	1.64
529.2362061	0.65
531.3043823	0.99
532.6143188	1.98
533.4065552	2.12
535.2380371	0.42
541.5856323	1.59
542.2631226	0.09
543.2289429	0.07
546.3125610	1.12
549.2444458	0.99
550.2364502	5.61
550.9656372	6.56
554.5260010	3.24
555.3290405	0.66
556.2808228	0.11
557.3377686	1.35
559.4019165	17.72
560.5162964	1.19
561.2377319	0.42
561.9236450	0.58
562.9462891	0.21
564.2547607	0.92
566.3937378	2.40
567.2554321	1.27
568.4479370	6.57
569.3014526	1.28
571.4738159	0.27
572.6209106	2.89
573.3623657	0.47
575.2987671	45.69
576.4373169	10.65
577.2339478	37.03
578.2669067	7.36
581.4915771	1.37
582.3538208	0.82
584.1119995	0.12
587.3814697	1.56
588.2458496	0.47
589.2462769	1.39
591.2274170	0.18
592.2523193	1.40
594.3214722	0.11
596.4428101	0.15
599.0550537	0.09
601.7151489	0.50
602.3364868	0.09
603.4891357	0.14
606.3234253	0.33
612.0204468	0.19
613.4716797	0.22
617.3001099	0.54
618.3880005	0.12
619.2670288	1.12
620.1629028	0.27
622.3063354	1.86
623.3234863	0.45
626.5090942	4.75
627.3534546	0.54
634.5804443	2.16
635.4418945	100.00
636.3454590	5.35
637.1552124	0.62
637.7846680	0.09
639.9208984	0.37
641.5605469	0.24
644.4272461	65.91
645.3750610	4.73
646.3607788	0.50
648.1940308	1.04
649.1544800	0.79
651.2863159	1.13
652.8406372	0.09
656.3297729	0.27
657.3793945	8.18
658.3795166	0.32
665.9631958	1.76
667.0513916	0.34
669.2058716	0.19
670.6089478	0.13
677.2133789	0.60
677.9429932	0.29
683.9824219	0.83
690.2161865	0.32
693.3021851	2.18
694.2673950	1.60
695.3007202	2.01
696.4484253	2.15
697.5094604	0.56
698.8078003	2.10
699.5486450	0.51
701.1481323	6.58
702.4338989	6.14
706.3128662	0.19
711.4003906	1.23
712.5725708	0.17
713.4548950	0.34
725.3854980	0.31
737.2932739	1.52
738.0540161	0.55
739.2212524	9.34
740.2630005	2.40
741.3775024	0.54
743.3705444	1.17
751.1629028	0.25
754.5401001	0.18
780.3081665	0.28
802.3424072	0.24
803.0441284	0.08
819.2833862	1.93
820.2991333	0.57
821.2445068	2.21
822.1588745	0.15
837.5615845	0.49
838.5300903	0.24
845.3355103	1.44
846.3491821	0.22
847.5711060	0.88
848.4223633	0.52
857.4157104	1.35
858.1842041	0.44
861.3223267	0.06
863.2951660	54.66
864.2500000	18.35
865.2870483	22.70
866.3428345	7.08
867.2339478	0.22
876.5700684	0.70
880.3131714	0.15
889.5519409	0.08
905.4416504	0.41
907.1386108	0.96
908.4197388	1.65
930.3395996	0.11
936.3964844	0.30
940.2930298	0.11
946.6691284	0.37
947.4897461	0.07
957.4067383	0.50
959.3716431	0.20
968.2666626	0.08
971.2202148	0.23
972.3538208	0.75
973.2727051	0.54
975.4464722	0.15
981.1849976	1.16
982.3579102	0.63
983.1211548	0.99
984.4429321	0.46
985.2780762	0.24
986.2525024	0.10
989.2666016	9.37
990.4085083	5.96
991.2893066	0.90
993.4125366	0.40
994.0554199	0.10
999.2937622	1.51
1001.1671750	1.25
1002.0692750	1.00
1009.7640990	0.61
1010.6044310	0.07
1025.2978520	3.60
1026.4857180	2.66
1027.2609860	7.86
1028.3583980	3.47
1029.4614260	1.32
1031.2224120	0.23
1043.3471680	0.77
1044.5568850	0.79
1091.5290530	0.08
1101.5356450	0.32
1109.3880620	1.43
1110.8657230	0.42
1133.1494140	0.72
1134.4647220	0.53
1135.7302250	0.66
1146.1085210	0.40
1151.2297360	38.96
1152.2165530	15.37
1153.1840820	15.13
1154.2933350	9.18
1155.3118900	0.28
1163.5321040	0.19
1164.3571780	0.54
1177.4781490	0.70
1195.1533200	2.85
1196.1774900	1.14
1197.4980470	0.32
1249.8253170	0.21
1256.0487060	0.80
1274.5648190	0.28
1289.1727290	0.14
1290.3643800	0.66
1297.3653560	0.53
1298.2835690	0.48
1299.5762940	0.55
1315.2788090	9.22
1316.3084720	8.56
1317.5045170	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.1346
Annotation	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
Peak:m/z	Relative Intensity
133.9860535	0.05
172.9971313	0.02
177.1672058	0.01
191.1429138	0.34
192.1043396	0.11
193.2460938	0.08
207.1661987	0.04
213.8728638	0.02
223.2420959	0.05
225.0197449	0.02
229.3787231	0.02
233.0491028	0.02
237.5565186	0.03
272.9805908	0.01
278.3130798	0.04
279.0616455	0.03
285.2296143	0.03
293.1104126	0.03
294.3073425	0.02
295.3543701	0.03
301.1274719	0.02
306.1336670	0.09
307.3327332	0.14
308.2354736	0.40
309.1139221	0.17
309.8634033	0.01
322.1753845	0.56
323.1900635	1.09
324.3014832	2.99
325.3049927	0.14
337.2398071	13.27
338.2384644	15.68
339.3258057	19.24
341.1685791	0.06
349.1878052	0.03
350.1672058	0.04
351.2909546	0.23
354.1985779	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1821
Annotation	Kanokoside A
Peak:m/z	Relative Intensity
143.9336243	0.07
145.0946960	0.09
146.1178284	0.04
161.4649048	0.06
163.0134430	5.72
164.1169128	0.53
169.2958527	0.06
174.3193054	0.01
205.1112671	0.31
217.1389465	0.02
230.7929688	0.03
234.7663574	1.86
235.9258575	0.19
252.8047485	0.12
264.4238586	0.49
265.0458984	2.43
266.1159058	0.18
269.0847473	0.04
277.0952759	0.06
289.0845642	0.30
290.1028748	0.04
295.1624756	0.08
296.3270264	0.03
299.8936768	0.04
307.1327820	0.76
308.2994995	0.12
314.2273865	0.04
323.3642578	0.04
324.3796692	0.46
325.1072998	4.95
326.0783691	0.30
334.1592407	0.05
361.4074097	0.09
381.3001404	0.11
397.9427490	0.03
408.4656677	0.06
429.1666565	100.00
430.1829529	14.06
430.9238281	0.01
447.1147156	0.02
457.3294373	0.06
458.3213196	0.23
459.5471497	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1976
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
161.2509766	0.04
163.1928864	0.01
176.9763794	0.13
179.1440887	0.02
181.2546082	0.04
191.2780914	0.02
206.9711609	0.02
209.3229675	0.02
230.1186523	0.02
231.3911133	0.01
235.1955414	0.02
247.3164825	0.01
262.1200562	0.01
271.3059082	0.01
274.2494812	0.04
287.3491211	0.01
289.9982910	0.02
297.3897705	0.01
299.4733276	0.01
303.4779053	0.01
313.2786255	0.03
319.8239746	0.01
325.1774292	0.02
329.0584717	0.01
331.4760132	0.01
339.0671387	0.05
340.3574219	0.08
341.0122070	0.02
343.3853760	0.04
345.2772217	0.00
357.2312012	0.07
367.1131592	0.03
369.3184204	0.01
370.2525024	0.01
373.4443970	0.04
375.4010620	0.02
378.8847046	0.01
385.2627563	0.04
387.2705078	100.00
388.3582764	1.21
399.3078613	0.05
403.4930420	0.03
411.4204102	0.00
417.0551147	0.02
418.4680176	0.01
427.5546265	0.00
429.4282227	0.12
430.7470703	0.00
432.1250610	0.02
453.2463989	0.03
454.2546997	0.02
463.2872314	0.02
470.9950562	0.03
475.6255493	0.01
477.3126831	0.01
478.2595825	0.01
494.9358521	0.01
497.5153809	0.01
502.2378540	0.01
503.4164429	0.72
504.2401733	0.06
505.0632935	0.02
506.1339111	0.02
512.2494507	0.01
513.7276001	0.02
514.5701294	0.01
519.4338989	0.01
526.4788208	0.04
529.4287720	0.02
531.3075562	0.09
532.9992676	0.01
539.1037598	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1172
Annotation	3-O-Feruloylquinic acid
Peak:m/z	Relative Intensity
112.8220215	0.01
116.9616928	0.42
136.8752136	0.05
141.0870667	0.02
145.0303955	4.45
146.0817566	0.03
158.0874939	0.02
162.1409912	0.04
169.1203003	0.03
176.9967499	100.00
177.8536530	0.01
193.0336609	0.40
194.1156311	0.06
195.1986084	0.04
197.1232300	0.01
207.2868042	0.02
215.0227966	0.02
235.0221863	0.08
237.2476807	0.03
261.3372803	0.03
275.3192139	0.03
277.2971802	0.07
305.4420166	0.01
315.2420959	0.03
322.8482056	0.01
333.0364990	0.08
339.3686523	0.03
341.0467529	0.01
350.6548767	0.08
351.2827759	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.21
Annotation	Glycobismine-D
Peak:m/z	Relative Intensity
199.3267822	0.21
204.9895325	0.92
211.2809296	0.55
229.2557831	0.19
241.1217957	0.58
252.9988098	1.46
255.3447418	1.02
258.6803894	1.20
270.9258728	7.41
277.9938965	0.40
288.0905151	1.76
288.8381348	11.71
290.2605286	0.17
294.5844116	2.15
295.1895142	8.95
306.8612671	7.06
311.6832275	0.58
312.6882019	0.38
324.8769531	100.00
325.8626709	1.47
337.1855469	0.28
341.4794312	1.08
342.7534180	62.62
343.6136475	0.79
419.8353882	1.48
432.7208862	0.21
438.9384155	0.38
450.7406616	2.18
456.9005737	6.37
457.9216309	1.93
474.9864502	63.24
476.1387329	7.04
486.3250732	1.69
486.9479980	8.10
503.8630371	0.99
504.8975220	2.42
518.5250854	0.45
619.3640747	0.84
620.3021851	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.7260742	0.06
201.0092163	0.06
218.2196198	0.12
219.1603699	0.05
228.9434662	0.15
230.0142670	0.10
231.1875305	0.05
273.0671692	9.42
274.0880737	3.63
275.1146851	3.06
373.2113037	0.03
387.0379639	14.73
388.0557251	14.02
389.1042480	11.28
391.2517700	0.07
403.1524658	0.09
405.0953979	0.09
425.5065308	0.08
429.4003906	0.38
437.9585571	0.06
469.1670532	0.05
485.9242554	0.05
487.0859375	0.07
500.9866333	40.48
502.0119019	93.33
502.9605103	100.00
503.8781738	0.02
514.2484741	0.03
515.2570801	0.21
517.1386719	0.04
526.2230835	0.11
526.8504639	0.05
533.0543213	0.08
542.8567505	0.34
559.9970093	0.03
561.2312012	0.10
570.0247803	0.38
570.9145508	0.61
571.5338135	0.10
572.1802368	0.07
573.0533447	0.05
585.3068848	0.10
587.4074097	0.03
599.0228882	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	585.2336
Annotation	Dihydrobuddlenol B
Peak:m/z	Relative Intensity
164.9755707	0.15
178.2089539	0.02
179.1256104	0.06
180.0789795	0.08
181.1449585	0.07
195.0583496	0.85
196.0759735	0.09
198.9334564	0.04
222.0054016	0.03
249.2172089	0.03
261.0760803	0.03
313.0787964	0.06
319.9757385	0.02
326.0476685	0.02
340.3502197	0.02
341.3090210	0.13
342.4356689	0.07
344.2424927	0.12
345.5379028	0.12
356.2585449	0.08
357.3329468	0.88
358.1948242	0.48
359.2946777	2.07
360.1997070	0.67
367.3381958	2.52
368.3098755	0.62
369.2452393	0.34
370.2434692	0.57
371.1992798	0.86
372.3274536	0.30
377.3162842	0.55
378.4203491	0.13
382.3627319	0.10
387.8211060	0.24
389.3140259	0.61
389.9387817	0.04
402.7216797	0.06
413.5501099	0.02
414.4998779	0.02
425.4701538	0.18
426.3610840	0.04
431.9089966	0.08
437.1793213	0.03
443.4808960	0.03
444.3141479	0.04
453.4020386	0.05
460.3993530	0.13
461.2523193	0.04
462.3124390	0.03
472.7891235	0.03
489.4354858	0.04
503.5818481	0.09
507.3792725	7.31
508.4711304	3.02
519.3197632	1.52
520.4491577	0.33
531.3076782	0.05
532.3720093	0.10
535.3736572	0.05
537.2258301	7.96
538.3871460	2.70
539.5873413	0.14
548.2961426	0.12
549.1978760	0.27
550.4304199	0.28
555.2713623	100.00
556.2519531	26.86
556.9178467	0.02
558.5338745	0.03
565.3684692	0.06
567.2703247	1.98
568.2678833	0.56
570.3344116	0.03
571.5335083	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1403
Annotation	Racemosic acid
Peak:m/z	Relative Intensity
161.0496368	2.76
162.2335510	0.26
171.0757446	0.02
173.2296448	0.07
179.0256958	3.14
179.8984375	0.38
191.0822601	21.78
192.1727905	1.16
203.2661896	0.06
209.2334442	0.08
215.3201141	0.03
232.8554382	0.17
251.1945038	0.06
287.2231445	0.03
290.2615356	0.04
295.2655640	0.03
296.8076782	0.02
297.4872437	0.02
298.2850952	0.10
309.3035889	0.06
323.1607666	100.00
324.1859131	21.10
324.8293457	0.02
334.4547119	0.08
335.2632446	0.95
336.3226929	0.08
341.1480713	18.59
342.1828613	3.57
353.1166382	18.56
354.2450562	4.70
355.1390381	0.10
367.4620361	0.06
377.2545166	0.13
395.2433472	1.64
396.2904663	0.56
407.2244873	0.08
408.0158081	0.09
425.0267944	0.03
425.9859009	0.04
435.3690796	0.08
437.3153687	0.04
438.5251465	0.05
455.3372192	0.10
469.6428223	0.04
471.2777100	0.25
472.2655029	0.02
479.2021484	0.05
497.3231812	1.25
498.4061890	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1699
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
201.2149963	0.06
205.2220764	0.11
215.2702026	0.18
218.9273987	0.08
233.0403137	0.18
247.1199951	1.31
249.1604919	0.11
251.2266998	0.11
259.0977173	0.29
261.0418091	0.20
271.1875610	1.25
271.8300476	0.52
273.1443481	0.17
275.2487183	0.93
282.6516418	0.06
283.3975220	0.12
285.2922363	0.52
287.1637573	0.29
289.0349731	2.68
291.1371460	3.73
292.1862488	0.35
301.1275024	2.32
303.1903076	1.43
309.4378052	0.13
313.2213745	0.43
321.2351685	0.07
333.0584106	0.64
339.3451538	0.57
346.4116821	0.24
350.8696899	0.13
364.3978882	0.07
371.9268799	0.06
375.2563477	0.15
383.9552002	0.27
385.4771118	0.18
387.1979980	0.09
393.2159424	1.21
397.3156738	0.31
399.0885010	0.65
405.2333374	1.63
409.1445312	6.29
411.0053101	1.58
417.2664795	1.19
421.0845947	0.32
423.1877441	1.18
425.3128662	0.27
427.1662598	8.54
429.2486572	0.15
429.9165039	0.26
431.2564087	0.46
432.0505371	0.21
433.2861328	0.39
435.2994385	1.46
439.2385254	0.67
441.2068481	36.77
444.1566162	0.17
446.2262573	0.44
451.2709351	0.98
453.0662231	7.29
453.6813354	0.22
454.2972412	0.09
459.2578125	9.85
465.2353516	3.30
474.1696167	0.21
475.3756104	0.13
477.2070312	0.31
483.2885132	3.63
493.2941895	0.16
495.2503052	11.21
499.2454834	0.25
502.5757446	0.33
507.2415161	4.68
513.2777710	15.17
516.4351196	0.08
518.3088379	0.09
525.2755737	8.64
534.5449219	0.64
537.9906006	0.17
542.0872803	0.22
543.2874756	33.09
547.1731567	0.27
554.9038696	0.37
557.1960449	0.39
558.9360352	0.25
561.2065430	100.00
568.4441528	0.26
569.4655762	0.71
571.7221680	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1013
Annotation	Xestodecalactone B
Peak:m/z	Relative Intensity
81.9118195	0.08
89.1361160	0.02
109.1159134	0.13
117.1243820	0.04
118.1818085	0.04
120.8711548	0.03
122.1211700	0.05
128.0561829	0.06
133.1253967	0.03
137.1749268	0.02
137.9664307	0.03
147.0038605	0.13
148.9984741	0.11
152.1902008	0.06
152.9745178	0.05
155.2130280	0.14
157.0598297	0.03
159.3135071	0.07
165.2154541	0.16
167.9059753	0.03
169.0532532	0.10
174.9332275	0.07
178.9647369	0.12
180.8666687	0.04
183.1854706	0.04
185.0946960	0.01
187.2545929	0.08
188.2807922	0.11
189.0820007	0.17
191.0926514	0.36
200.1203613	0.39
205.2105713	0.17
207.1228027	0.19
209.3288269	0.14
211.0729065	0.03
214.1945801	0.03
216.9638367	0.06
219.0741272	0.05
221.1105347	0.32
222.8758850	0.14
224.9477539	0.11
227.2101746	0.03
231.0040894	0.09
234.4159851	0.09
235.1175842	0.68
237.2935791	0.07
239.1169434	0.05
245.3231812	0.12
246.0013428	0.04
249.1031494	0.24
249.9766235	0.01
251.1411133	0.02
252.3514404	0.04
253.2537537	0.20
256.7871399	0.06
258.1232300	0.04
259.0687866	0.16
263.0888367	100.00
264.2355347	0.13
266.0513916	0.44
272.3029785	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2027
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
149.0489197	0.12
176.1523438	0.06
203.1958923	0.04
205.2261353	0.55
207.1336823	0.05
217.1975555	0.06
220.0040588	0.30
233.2377777	0.12
235.0166016	0.13
247.3231201	0.07
275.2193604	0.19
283.4152832	0.06
285.1238403	0.30
288.9280396	0.07
295.3397217	0.05
297.3269653	0.08
307.3214111	0.03
309.3838501	0.09
315.3206177	0.23
324.2519531	0.03
326.2731323	0.21
327.6662598	0.24
332.0009155	0.12
341.2337036	2.10
341.9387817	0.03
353.3022461	0.04
356.0372314	0.13
357.4218140	0.29
358.1071777	0.24
359.3185425	0.27
371.2610474	100.00
389.2505493	0.54
390.9677734	0.05
395.1851196	0.06
401.2220459	0.04
403.2293091	0.07
412.3943481	0.12
431.4685669	0.41
433.3449097	0.06
461.1469727	0.23
473.5192871	0.05
475.0122681	0.14
475.8565063	0.21
477.5579224	0.06
478.7811279	0.06
485.1205444	0.07
485.7551880	0.08
487.2549438	0.09
489.1557007	0.10
501.2931519	0.05
502.4033813	0.07
503.2230835	0.36
505.6207886	0.08
506.5408936	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.3247986	0.10
212.9584351	1.26
296.8838501	15.33
302.9835815	0.11
323.1340942	0.16
333.4436035	0.02
374.5515747	0.07
380.6580811	69.36
381.4354248	0.16
386.9829712	0.15
428.8884888	0.25
442.8738403	0.04
458.9152832	0.08
462.1857300	0.19
464.5158081	100.00
465.2681274	0.50
484.4049683	0.03
489.0407715	0.02
503.1721802	0.02
518.9841919	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	488.1208
Annotation	Unknow
Peak:m/z	Relative Intensity
164.0565338	0.07
179.0191040	0.20
181.0878906	0.28
194.0075989	4.80
206.9854279	0.30
209.0907135	100.00
221.1270752	0.18
229.3554077	0.05
250.1666260	0.22
254.0576782	10.79
260.3589783	0.07
269.0322571	0.13
278.2834167	0.10
287.0447998	0.13
296.0130005	20.77
297.2837830	0.18
310.0302124	0.04
314.1281738	0.51
318.1980591	0.43
325.0991211	0.10
339.7291870	0.19
357.1798401	0.21
370.9760742	0.17
385.1722412	0.14
398.9633484	0.04
413.3967285	0.07
414.4381714	0.08
416.5460205	0.10
417.2266541	0.06
422.3286743	0.37
432.5637207	0.22
434.9026794	0.07
441.8987122	0.59
442.5752258	0.14
453.0783081	1.72
470.2114563	17.38
471.1458130	0.33
475.8927612	0.42
478.4897156	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2915
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
180.9094543	0.09
195.1204834	0.05
197.8711853	0.15
213.3141937	0.29
221.2019958	0.06
241.1578827	0.17
245.1512451	0.06
247.4259186	0.04
251.4900208	0.07
255.6634521	0.04
263.2216187	0.10
279.4156494	0.10
283.1691589	0.20
293.3548584	0.07
306.3809204	0.59
314.4575806	0.05
319.2294922	0.13
323.3654480	0.02
324.4662476	0.06
329.1942139	0.03
337.3441772	100.00
341.1855164	0.05
358.7940369	0.08
364.4028015	0.08
373.0209045	0.05
378.6183167	0.10
380.6684265	0.09
403.3069458	0.05
407.6094971	0.12
414.6738892	0.11
417.1090698	0.10
418.3723450	0.16
422.0653687	0.03
429.4328613	0.02
436.2811584	0.02
442.3417358	0.02
442.9648438	0.06
447.2825623	0.26
459.6857300	0.51
460.3056335	4.03
461.0817566	0.17
463.7228394	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.9612
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0834351	0.02
177.9772644	0.01
183.9710693	0.01
188.0379028	0.07
205.1492004	0.02
206.1599426	0.06
219.1623535	0.03
230.1201782	0.01
231.2600708	0.13
232.0989685	0.61
240.0648499	0.02
243.9887085	0.01
256.1244812	0.05
257.3408508	0.01
259.0845032	0.19
259.9454346	0.66
262.2011719	0.03
275.1541138	0.05
276.2153931	0.11
277.9862671	100.00
284.8497925	0.02
302.9987183	0.17
304.0118103	0.13
309.3874512	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	775.2812
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1592712	0.08
307.4496460	0.07
309.0307922	0.06
310.1610107	0.13
350.3215332	0.04
355.3710327	0.12
385.4105225	0.30
386.4838257	0.08
387.2633667	0.99
403.3157959	0.22
409.4553223	0.11
415.1923828	0.04
416.1163940	0.18
417.2790527	6.21
426.3916016	0.12
429.3624268	0.03
453.4874878	0.08
466.2636719	0.03
467.5693970	0.13
469.0359497	0.25
471.3961182	0.10
487.0813599	0.07
495.2322998	0.08
517.4267578	0.10
519.6247559	0.14
523.3679199	0.11
535.5198975	0.05
537.7956543	0.03
547.6553345	0.20
555.3922729	0.22
565.4221802	17.76
567.3140869	0.28
582.3770752	0.17
583.3536987	0.80
592.5908813	0.07
595.1229858	3.16
599.5259399	0.14
607.2555542	0.04
608.4624634	0.03
613.2234497	100.00
613.9254150	0.28
625.7361450	0.12
633.7194214	0.08
639.2855835	0.05
658.2913818	0.04
670.0021362	0.14
685.6016235	0.24
691.3262939	0.08
700.3612671	3.34
712.5270386	0.11
716.6983032	0.33
717.4255981	0.12
727.1875610	4.52
729.2903442	0.48
729.9042358	0.24
731.2631226	0.07
742.0104370	0.12
747.4487305	0.08
756.1845093	0.26
757.0869751	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
98.9363327	1.00
100.8616104	0.81
107.1399765	0.72
114.9507828	0.77
117.0744324	0.54
121.0697708	0.23
122.9082794	0.51
124.6483078	0.63
127.0742645	0.29
128.9668579	0.61
132.980545	0.73
134.9943237	1.10
138.2385712	0.27
138.9175262	0.53
143.1535339	3.08
149.0944672	0.51
153.0872803	1.81
155.1669617	0.22
157.1990967	0.34
158.7192383	1.02
161.0476532	0.24
167.130249	0.88
169.2431641	1.68
170.1259613	0.32
171.0643158	0.90
173.103653	1.01
175.208725	0.92
177.1962128	1.37
179.0564575	1.12
183.1127472	1.40
185.1523438	2.66
187.249054	0.24
191.0804749	0.40
192.3396606	0.70
193.1385803	0.54
194.7879028	0.51
197.0918579	2.72
198.951355	0.29
202.0003967	1.63
207.2485657	1.83
208.9189453	0.81
211.1564636	1.71
212.1175537	0.24
213.1395569	1.42
215.1844788	0.81
219.3936157	0.95
221.2022095	0.58
222.0114746	1.23
223.2183838	3.15
225.0413208	0.26
227.119751	0.59
229.4999084	0.91
231.1804199	0.96
233.2925415	3.62
235.3556213	3.04
236.2895813	0.85
237.087677	0.26
239.1494141	1.59
241.1074219	0.65
247.1605835	0.85
249.0925903	0.38
251.1801758	6.06
252.342041	0.42
253.160614	6.05
255.2461853	0.68
257.4675598	1.72
262.0483398	0.26
265.1303711	6.67
267.3436279	0.62
268.8909912	0.57
272.666687	1.03
275.2302551	13.79
279.4047852	0.41
280.4023438	0.41
281.1507874	0.63
282.1395874	0.44
283.1770325	6.06
287.6024475	0.66
293.2179871	100.00
296.0703125	0.29
302.3464966	2.99
304.1304016	0.38
310.6756897	1.63
311.5407104	1.31
313.0144653	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1141
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
113.0719147	0.12
128.9928741	0.03
131.1239166	0.04
135.0350800	0.14
139.0686188	0.07
191.0510254	0.06
192.0252686	0.05
193.1419220	0.33
207.0961456	0.14
209.1495056	0.05
210.2273865	0.01
211.0008545	0.08
217.1582947	0.05
223.1959534	0.37
230.9866943	0.06
232.8384094	0.04
247.2775269	0.06
249.1828308	3.35
265.1472473	1.77
267.1348267	100.00
290.9082642	0.06
294.2709656	0.03
295.1397400	1.22
295.9306030	0.02
309.2978516	0.09
313.4069824	0.08
323.0766602	0.15
325.2114563	0.87
327.4460449	0.11
338.4274292	0.16
339.2200317	0.62
341.3576660	0.36
342.4776001	0.05
354.3377991	0.16
355.0347595	0.27
358.3185730	0.02
361.7230225	0.14
365.9644470	0.03
367.1922302	0.48
368.0635986	0.03
370.2306213	0.15
376.2618103	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
127.0186005	0.33
135.1221924	1.67
157.0573425	0.62
160.9716034	1.92
173.1639252	2.05
174.8146515	0.55
178.9772491	9.71
182.7977142	0.65
187.9499817	0.33
191.0535583	100.00
197.0684204	1.35
213.0466461	0.93
220.4258118	0.52
227.1368408	0.47
251.3682251	0.36
255.2781372	0.71
257.1276855	0.39
258.2951965	0.26
259.2874146	3.55
265.1422729	1.04
273.7520447	0.33
277.1647034	1.19
281.1384888	2.57
291.3522339	1.90
293.2414246	1.54
294.24823	0.26
295.296814	0.61
306.9434509	1.31
309.1364136	0.23
309.8167114	1.02
310.4970703	0.55
312.4242554	0.33
316.0971985	0.46
317.2687988	2.13
335.2694092	39.15
337.2869263	8.06
338.1773071	1.10
339.3497314	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	354.09
Annotation	Unknow
Peak:m/z	Relative Intensity
107.1080551	0.04
108.1043015	0.03
109.1000366	0.06
111.3256607	0.05
112.0475159	0.02
117.1371307	0.04
127.0575180	0.15
135.0180664	7.24
136.0711060	0.58
137.0336914	0.01
144.1871643	0.06
153.4406738	0.01
154.9244843	0.35
156.3450623	0.02
161.1168213	0.79
162.0762329	0.05
171.0581055	0.02
171.9430695	0.02
173.1444550	2.60
174.1024475	0.27
179.0636902	43.02
180.0488892	4.42
189.2910767	0.02
191.0467224	100.00
192.1160278	7.32
316.9670410	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.0671
Annotation	Unknow
Peak:m/z	Relative Intensity
86.8331604	0.79
89.0062332	3.60
98.9438477	0.08
101.0369110	3.28
103.8258514	0.09
105.8126221	0.13
106.7813110	0.43
113.0626297	4.71
114.8610611	55.07
119.0114594	5.30
125.0704041	1.11
129.1156311	0.21
130.1432800	0.26
131.0211639	2.01
132.9409180	93.04
134.0624542	0.13
142.8991394	8.42
145.0168152	0.13
147.1882629	0.30
149.0342712	1.98
161.0401306	7.73
175.0650330	1.80
177.2168274	0.08
179.0170593	100.00
187.0244446	0.26
190.3127289	0.16
197.3616180	0.13
204.9798889	33.94
207.3355713	0.07
209.1975403	0.06
217.1680298	0.25
230.9571533	0.18
235.1166382	19.61
251.4192505	0.67
259.1844177	0.43
265.0891724	0.47
277.0690002	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	684.0797
Annotation	Unknow
Peak:m/z	Relative Intensity
337.3691406	0.20
346.5813599	0.03
360.3173828	0.05
421.0155029	0.16
459.2291260	0.11
513.9801025	0.09
516.2344971	13.82
516.9244995	0.11
518.6326904	0.05
536.3527832	0.25
538.3189087	0.06
554.3582153	5.98
579.0832520	0.08
592.3494263	0.15
596.3178101	0.05
597.0305176	0.03
598.5512085	0.03
600.1016235	100.00
600.7571411	0.32
602.6192627	0.93
616.9700317	0.03
624.5675659	0.26
626.8583374	0.03
630.3413696	0.04
638.1243896	70.67
638.8703003	0.69
639.5597534	0.27
642.1550903	0.04
653.6294556	0.88
665.5011597	0.35
675.5703735	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1036
Annotation	Zidovudine
Peak:m/z	Relative Intensity
109.8153381	0.13
119.2902374	0.06
135.9241028	100.00
138.2027435	0.06
141.8251801	0.02
150.0074921	0.16
150.8077698	0.10
168.0547638	0.03
170.0970154	0.02
178.1902008	0.03
179.0851898	0.07
183.1782532	0.01
192.0798645	0.04
201.1034546	0.09
203.5909119	0.02
206.4924011	0.04
214.1914062	0.02
222.1913147	0.14
224.1025543	0.01
231.4627686	0.03
232.1993256	0.03
233.0991364	0.01
249.9319916	0.17
250.9823608	0.08
254.7554321	0.02
258.1804199	0.08
258.7821655	0.09
272.9794312	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.2351
Annotation	Unknow
Peak:m/z	Relative Intensity
204.9858704	0.26
219.1308136	1.08
221.1140137	0.53
228.9018860	0.22
233.4601135	0.13
243.3369141	0.34
245.1205444	5.04
246.2108612	0.27
247.1174164	0.71
248.1952209	0.19
260.9226074	0.11
263.1757507	1.62
265.2108765	10.68
271.1449890	0.16
275.2951660	0.25
277.2073059	0.54
280.9658508	0.41
283.2079468	4.33
286.9346313	0.40
289.1301880	2.11
294.7743835	0.24
296.1886597	0.59
305.1625366	16.25
306.0914001	0.14
306.9358521	0.24
311.3526611	0.25
317.1162109	0.61
319.2115479	0.16
321.1357422	1.27
322.2354126	0.64
323.1722412	0.14
329.2091064	1.66
335.2426758	0.17
337.2679749	6.41
338.3250732	0.45
339.2633667	1.19
340.2089539	0.41
341.5357056	0.25
342.2806702	0.41
343.1920471	0.17
347.0258179	0.27
349.2283325	0.69
350.0398560	0.12
351.3901062	0.15
361.2387085	1.12
365.4711914	0.11
367.0612793	0.41
371.1739502	1.51
377.1606445	2.83
379.1876831	0.16
381.3618164	1.85
382.2354126	1.02
383.2561035	0.81
388.7481079	0.09
393.3622437	0.43
397.2788696	9.80
401.2324219	2.81
402.3767700	0.20
403.2965698	0.21
405.9005127	0.64
409.1704102	0.69
415.3827515	4.90
420.3800659	0.11
421.1386719	0.68
422.3986816	0.35
423.1281738	0.10
433.2265625	1.44
434.1817017	0.13
437.1273193	0.54
439.8205566	0.20
449.3135376	11.16
451.3013916	0.22
453.1063843	0.72
454.2968750	3.58
455.4504395	0.18
457.2770386	0.30
461.0321045	0.26
462.3628540	0.59
469.3952026	0.19
471.3119507	0.97
472.3178711	1.88
473.4095459	0.53
480.7731323	0.35
481.4133301	8.25
482.2700806	1.37
485.3984375	1.62
491.2396851	1.84
493.4076538	1.03
494.2643433	0.89
495.3968506	0.27
509.2844849	1.27
511.3124390	4.16
512.3789062	0.53
514.3027344	0.16
515.1963501	0.41
519.3069458	0.24
523.4116211	0.66
525.3018188	2.08
526.2208252	4.10
527.3378906	1.18
529.3389282	9.33
537.4373169	0.88
543.6367188	7.62
544.3495483	11.75
545.4112549	1.37
554.6346436	0.46
555.3854370	1.23
556.5937500	0.38
561.3502808	3.62
562.5327759	0.30
571.2246094	0.36
572.6299438	0.52
573.4223633	0.74
585.1253662	0.56
587.4166870	1.09
588.2199097	0.11
603.3851929	15.76
604.3455811	42.01
605.4849243	10.69
606.5723267	0.44
626.3224487	3.00
627.2393799	0.98
640.3019409	0.54
643.4308472	0.44
644.5995483	0.85
645.3618164	0.10
646.4364624	1.28
657.3834229	3.18
658.3663940	34.14
659.4414673	9.17
661.3199463	22.59
675.3473511	13.61
676.3623657	100.00
677.4171143	23.09
678.1270142	0.40
688.7234497	0.93
693.4793091	4.74
705.2479248	61.63
705.8533325	0.95
706.5178833	0.42
718.8843384	1.24
719.6306763	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.08
Annotation	Unknow
Peak:m/z	Relative Intensity
151.2086792	0.06
151.8822632	0.04
153.1239319	0.06
160.0130768	0.60
161.0939636	0.18
161.9884338	0.04
164.0959015	0.03
165.2137146	0.04
167.1357422	0.34
167.9065399	0.05
169.0455322	0.13
170.0097351	0.03
171.0896606	0.09
172.2256470	0.04
175.1499023	0.11
177.1841125	0.13
179.0256653	0.74
180.1908264	0.22
183.1490479	0.02
185.1764526	0.27
185.9426880	0.29
187.0873260	0.05
187.8132019	0.12
191.2668762	0.06
193.2050171	0.07
195.2967987	0.06
197.2242432	0.27
199.1316681	0.02
204.0413513	0.07
207.3056641	0.05
208.1282654	0.23
210.1428528	0.48
211.1599731	0.37
212.2378387	0.16
213.1107178	0.21
213.9640808	0.10
215.1665192	0.02
219.0818329	0.22
220.2355194	0.24
223.1643372	0.03
224.2550507	0.05
226.1003113	0.05
228.0357056	0.10
229.2356873	0.16
229.8972168	0.11
231.1432190	0.31
232.0771332	0.21
234.2401123	0.02
235.3602753	0.07
236.1142120	0.02
237.1623688	0.19
238.0871582	0.25
239.0463867	0.11
242.7830505	0.19
243.4905090	0.03
244.2763214	0.20
245.3556366	0.10
246.0964050	0.03
248.2431335	0.08
252.3459625	0.03
253.5393982	0.57
254.2459106	2.95
255.2436218	1.42
256.1456299	0.24
256.9571228	0.05
258.2009888	0.07
259.2075195	0.03
261.2214661	0.02
262.1106567	0.06
263.1033325	0.02
264.2024231	0.03
265.1234741	0.04
269.1646118	0.15
270.2361450	0.31
272.1773682	1.78
273.2265320	1.01
274.2714539	0.08
280.1616211	0.07
281.4501953	0.16
282.1822510	0.05
283.3224487	0.05
284.7034912	0.13
287.1887207	0.09
288.1790161	1.89
289.2174072	1.69
290.1744995	1.14
291.3120422	0.13
293.1523438	0.07
295.4268188	0.10
297.3250122	0.17
298.1993408	0.22
299.0313110	0.03
301.7493896	0.13
306.1535645	12.23
307.2164917	12.68
308.3013916	5.14
310.2286987	0.03
313.1011963	0.02
314.2776489	0.03
316.2852173	0.33
319.5428467	0.09
321.9577637	0.25
322.5966797	0.01
323.3305054	0.18
324.1655273	0.21
325.1206665	0.03
328.2346802	0.14
329.3407593	0.07
331.0364990	0.10
333.4278564	0.02
334.2579956	0.02
335.2303467	0.07
336.1634521	0.33
337.3638916	0.24
338.2328491	0.14
339.1132202	0.09
340.3412476	0.13
341.2048950	0.43
342.1431885	1.62
343.2795410	0.21
344.1601562	0.06
345.2803955	0.06
346.4043579	0.15
347.4740601	0.15
349.2643433	0.02
350.2951050	0.04
351.3486938	0.25
352.4096680	0.28
353.2076416	0.03
354.2368774	0.13
355.1554565	0.22
356.3961182	0.09
358.3028564	0.05
359.1086426	0.04
360.1423950	0.38
361.3167114	0.18
362.3377686	0.14
364.9786987	0.02
366.3655396	0.13
367.3301392	0.29
368.2653198	0.29
371.2460327	0.09
372.1459961	0.03
373.7401123	0.15
375.2733765	0.10
376.3842163	0.02
378.1718750	0.14
379.1862793	0.46
380.2462158	1.18
381.2421875	0.51
382.3834229	0.04
383.5585938	0.05
384.3729858	0.13
387.3174438	0.02
388.2509766	0.02
389.3168945	0.03
390.2283936	0.21
391.2844238	0.58
392.3298340	1.21
393.3305054	0.50
394.2363281	0.07
395.2401123	0.09
396.8784790	0.03
398.2750244	0.63
399.2409058	1.04
400.1462402	0.61
401.1157227	0.18
402.2850342	0.31
403.2731323	0.18
404.3227539	0.16
405.1556396	0.18
406.1288452	0.27
407.3574829	0.45
408.7458496	0.22
410.1891479	0.73
411.2072754	1.29
412.2672119	0.65
413.4998169	0.08
415.2468872	0.28
416.1701660	0.67
417.3444214	0.25
418.2266846	0.56
419.2150879	0.27
420.3379517	0.09
421.3146362	0.10
423.2451172	2.78
424.2584839	7.50
425.2736206	4.12
426.4240723	0.15
428.3246460	0.11
429.3421631	0.09
430.4007568	0.04
431.3372192	0.04
432.3353271	0.20
433.4392090	0.14
434.1492310	0.06
435.2971191	1.52
436.2457275	3.24
437.0972900	0.73
438.2109375	0.72
439.2913818	0.30
440.1573486	0.31
441.3213501	0.59
442.3118286	2.24
443.2707520	1.10
444.0512695	0.03
445.2378540	0.73
446.1364136	0.44
449.1882935	1.05
450.2199707	2.61
451.3658447	1.55
453.5550537	0.03
455.2680664	0.34
456.2747192	0.49
457.4481201	0.44
458.3178711	1.79
459.2605591	1.28
467.1829834	8.36
468.2106323	27.76
469.3123779	13.78
474.1087036	0.14
476.2077026	4.87
477.2864380	3.20
479.0751343	0.03
480.8878784	0.03
484.2213135	4.07
485.2351685	5.84
486.2572632	15.56
487.3234863	5.83
502.2034912	100.00
503.1943970	52.87
503.8497925	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1603
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
134.0508270	0.42
135.1081085	0.10
136.1527252	0.16
146.8860168	4.60
148.1107330	0.06
163.0107727	0.12
164.9345856	8.60
168.1560669	0.08
182.9727783	100.00
193.2699280	0.03
254.7278442	0.04
257.2461243	0.07
260.7481689	0.02
288.9240723	0.15
290.0006714	0.08
291.0083313	0.05
295.8419189	0.26
296.8747559	0.20
298.0422058	0.02
313.2548218	0.04
314.0809021	0.11
315.1508789	0.20
316.0144653	0.28
323.1648560	0.07
325.1267090	0.62
326.0162048	0.35
327.0143738	0.82
338.0507812	0.02
341.2651367	0.02
343.1743469	0.20
344.8291016	27.13
345.5746460	0.08
357.9331665	0.02
359.0164490	0.04
389.3932190	0.04
416.5159302	0.06
440.2824402	0.07
442.3543701	0.03
447.2760925	0.03
459.0660706	0.28
460.1827698	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.295
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
204.0517731	0.14
217.9088593	0.11
236.1550598	0.11
245.9263763	0.05
249.9102020	0.05
262.0307007	0.03
273.2838135	0.22
276.1611328	0.21
287.3108215	0.22
294.1597290	0.24
299.2019653	1.35
305.3027344	0.36
313.4898071	0.02
315.2901611	0.52
323.3012085	0.40
325.3015747	0.25
337.1961060	1.00
341.2694702	0.20
343.2491760	0.16
357.1813354	0.60
359.1798096	0.50
365.0737915	0.15
369.1822510	0.20
369.8401489	0.05
371.2454834	0.75
373.0900879	0.36
383.4337158	0.59
389.3623047	0.03
401.2501831	3.18
402.7337646	0.08
415.2615356	0.13
422.2244263	0.07
429.0789795	0.07
433.2302246	1.72
438.2636719	0.17
446.3396606	0.37
449.1764526	0.04
450.3729248	0.41
452.2695312	0.26
464.4039307	10.37
465.3386841	0.10
466.3005981	0.33
467.0430298	0.15
471.4167480	0.05
472.2119141	0.07
476.1919556	0.63
478.3544312	0.34
482.3582153	0.59
483.2580566	0.09
487.1367798	0.11
490.3204956	9.32
494.4243164	0.27
504.7697144	0.10
506.7270508	0.04
508.1403809	7.69
508.8475952	0.02
514.3248291	1.02
516.9047852	0.06
522.2646484	31.05
523.2081909	0.06
525.5384521	0.38
526.3597412	0.82
533.0397949	0.12
539.5547485	0.05
540.5605469	0.11
554.3373413	0.15
564.7235718	0.08
567.2016602	0.09
583.4208374	0.57
585.3335571	0.54
587.4202881	1.94
593.1934204	0.05
601.4223633	0.06
603.4404297	3.90
604.8015137	0.15
609.1873779	0.09
611.3065796	3.23
611.9301758	0.06
613.2033691	0.16
619.3472290	2.40
629.4096069	12.98
630.9497681	0.25
633.3924561	0.20
643.3422241	8.13
647.3541870	100.00
648.1311646	0.07
651.1372681	0.40
661.2526245	4.33
662.5341797	0.30
663.4544678	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	229.1541
Annotation	Leucyl-Proline
Peak:m/z	Relative Intensity
67.8470993	0.10
69.9721375	14.37
71.8521500	0.08
81.8488007	0.12
82.9456253	0.05
84.0739136	0.04
86.0474243	0.12
88.0899963	0.12
97.7122650	0.05
113.0302734	0.36
113.9364319	3.19
114.5781860	0.07
116.0652313	0.39
123.9339752	6.34
124.9658661	0.04
125.9915466	2.68
126.7878418	0.08
129.0015259	0.82
132.1138306	0.70
136.0321198	0.14
142.0426178	100.00
146.7192841	1.78
151.0653076	0.04
152.6565247	0.11
154.1569366	0.10
155.1644135	0.40
157.9524384	0.29
167.3285675	0.04
169.9739380	13.08
171.0566406	0.19
181.9272003	0.07
183.1094208	0.05
187.7543945	0.05
193.3507843	0.18
198.7631989	0.15
201.2678528	0.74
202.1013184	0.07
208.0936432	0.12
210.4373474	0.30
211.1851501	3.64
214.2175903	0.05
220.1513062	0.12
221.0237579	0.13
228.7117920	0.29
229.3565521	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.22
Annotation	Unknow
Peak:m/z	Relative Intensity
220.9349976	0.04
227.0541382	0.07
233.1452026	0.08
245.0230865	0.25
262.6636047	0.08
277.0940552	0.06
289.2532654	0.43
294.3500061	0.22
303.0325928	0.13
305.1377563	1.29
307.1898804	0.08
317.2991028	0.02
319.2531738	0.20
321.1617737	1.10
329.1589966	0.07
335.3200989	0.30
337.1349487	0.23
339.1682129	1.57
349.3217163	0.06
361.4568481	0.04
363.2030640	0.11
373.8686523	0.25
377.2470093	0.24
381.3065186	3.07
390.8466187	0.08
395.1970825	0.06
401.1385498	0.15
403.4847412	0.03
408.9193726	0.04
420.6222534	0.08
421.2395630	0.70
433.0736084	0.09
437.1547852	0.06
439.3691406	0.27
441.1881714	0.11
449.3425903	1.21
452.1406250	0.08
453.2463989	5.28
471.2967529	1.57
473.3088379	0.04
481.3555298	0.86
491.4382324	0.23
493.3378296	1.46
507.1762695	0.15
509.2668457	0.64
511.2630005	0.37
513.2683105	0.28
523.5856934	0.07
525.2835083	7.10
525.9462280	0.05
535.2849121	0.09
543.3270264	14.75
553.4550171	0.40
567.3314819	0.04
571.3696899	2.35
574.4324341	0.06
581.2130737	0.06
584.8569336	0.04
585.4581909	1.46
601.2484741	0.06
603.3085327	50.14
603.9213257	0.15
605.2477417	0.06
613.1421509	0.13
625.3602905	3.30
639.4895630	0.07
643.3005981	0.72
645.3731689	1.61
646.4806519	0.08
657.3191528	38.03
657.9194946	0.11
667.6149292	0.07
673.2355347	0.04
675.3596191	100.00
676.0168457	0.30
699.4092407	0.28
703.3120728	1.16
705.4246826	0.14
716.3175049	0.10
717.3270264	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
89.1331711	0.12
97.1880798	0.41
101.0069580	6.95
106.7395096	0.29
112.9945679	13.65
118.9445572	13.15
124.9474945	2.20
131.0164185	5.44
143.0221252	15.75
149.0239563	4.93
158.8652344	0.30
161.0090027	16.37
179.0145569	100.00
220.9233398	0.39
232.3958130	0.13
235.3203125	0.17
267.1366882	0.15
279.3119812	0.36
281.0837402	1.40
305.1909790	0.12
309.2287598	0.14
320.9644470	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
137.0414581	3.06
168.3872681	0.03
183.1678467	0.05
206.9097137	0.04
240.3085327	0.02
250.7208862	0.02
282.8975220	0.09
299.0941467	100.00
301.2533875	0.02
301.8948059	0.01
309.1420898	0.04
327.0646362	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1344
Annotation	Davidioside
Peak:m/z	Relative Intensity
120.9481125	0.15
121.9840622	0.11
122.9822006	0.05
132.8617706	0.04
135.1466217	0.11
146.9235840	0.05
149.0180359	1.09
150.0607300	1.24
151.1377258	0.14
152.1075134	0.02
163.1873779	0.24
164.0743256	2.36
165.0737610	5.48
166.0884399	0.24
173.2209778	0.01
176.9227905	0.01
179.1573792	1.96
179.9577484	0.12
181.1071625	0.19
193.1819000	0.07
195.0830383	17.09
196.1342926	0.57
208.1833344	6.92
209.1318054	0.26
220.1955566	0.01
223.0547333	100.00
224.1356049	3.40
237.1078796	0.02
239.2652283	0.03
240.4275208	0.01
246.3618164	0.01
255.3193665	0.02
256.0334778	0.02
257.5328979	0.03
285.4850159	0.01
294.9347229	0.02
299.3712158	0.03
301.6604919	0.03
315.5349121	0.01
316.2698975	0.02
323.1626282	0.02
332.4013672	0.05
333.3735046	0.02
339.4640503	0.01
347.9027405	0.03
355.5018311	0.07
357.3964233	0.02
358.4430542	0.02
359.2674255	0.01
371.1957092	10.56
372.2620544	0.90
373.2875671	0.08
374.2962341	0.03
375.4082947	0.03
382.0742798	0.02
384.2582397	0.05
387.3743591	0.04
391.1480103	0.02
392.4975281	0.02
401.0769653	1.89
402.1613770	0.20
403.2424622	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.1035
Annotation	Gerfelin
Peak:m/z	Relative Intensity
110.9999771	0.11
113.9221802	0.03
117.2462158	0.05
133.9856262	5.61
135.1883545	0.03
137.0513763	0.12
148.9080505	0.95
155.0702820	0.68
160.0293884	0.07
160.9412537	0.16
161.8975830	0.10
164.2160950	0.09
173.1441956	2.98
177.0595703	0.07
178.2494354	0.03
187.1148682	0.03
191.1839294	3.26
193.0164795	100.00
205.1498413	0.13
215.3723450	0.06
239.2160339	0.03
241.2438660	0.05
263.0797119	0.37
267.4417419	0.04
280.1664429	0.10
285.4031982	0.10
289.2650757	0.09
293.3411255	0.08
294.2236328	0.18
303.5264893	0.10
321.1958008	0.30
323.2058411	0.45
334.4703369	0.06
339.3121338	0.08
349.3815918	0.18
352.1732788	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1326
Annotation	Gancaonin N
Peak:m/z	Relative Intensity
132.9772949	3.78
134.9024048	1.28
137.2615662	1.52
155.2157288	0.37
160.0615234	0.69
161.0753021	1.15
163.0787354	1.15
167.1407776	20.92
175.0483093	4.87
185.3839417	0.72
186.9362488	0.37
189.0430908	2.76
191.2120819	3.02
195.9577026	1.21
199.1336670	1.76
203.3582153	0.55
209.1059875	5.45
211.1092529	1.32
217.0676422	7.22
221.2755127	0.37
231.1800232	0.43
264.0947266	1.25
265.0676270	1.43
269.2726746	0.52
277.5898438	0.87
281.1177368	0.86
283.1768799	0.31
290.5760498	0.63
293.2846375	2.79
297.3225708	1.68
307.3395386	1.44
309.2028503	1.18
311.1202087	0.63
312.3361511	0.69
315.3969116	0.86
321.5901794	2.08
323.4074707	0.55
325.2472229	2.26
326.4481201	0.78
327.1538086	0.82
334.3788147	0.69
335.4211731	3.62
339.1305237	9.93
341.2536011	39.40
343.3953552	3.19
352.0275269	0.40
353.3063354	100.00
371.3281555	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1035
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
111.8857956	0.01
113.2299347	0.03
120.1300125	0.04
126.6872940	0.01
134.9893951	0.05
149.0578308	1.40
159.2860107	0.02
164.0525208	5.32
173.2357788	0.05
175.0857239	0.06
179.0257416	12.56
179.9499207	0.15
189.0897522	0.13
190.0016479	0.07
191.0424652	3.60
192.0612793	3.71
193.0768738	1.53
205.3270416	0.04
206.1626740	0.27
208.0870361	5.08
209.1052246	0.33
217.0870667	0.05
221.1907959	0.54
223.0652161	100.00
230.2344971	0.07
233.0221252	1.15
234.9797363	0.05
237.2966614	0.12
245.3074341	0.05
249.0549011	0.06
250.2096863	0.16
251.1451721	0.22
252.2642517	0.16
259.2378540	0.04
262.9747314	0.03
265.1600342	2.25
274.2702332	0.04
282.9422607	0.04
289.0706787	0.03
291.3770142	0.02
295.1935425	0.21
308.1691284	0.38
309.2906189	0.33
311.4484558	0.02
323.1954346	0.28
324.2044067	0.20
325.2827759	0.17
336.1130676	0.10
337.1685791	0.18
338.9788208	0.03
340.1920776	0.28
348.4645081	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1299
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
146.9876099	0.06
150.7618103	0.07
152.0421753	0.66
153.1323700	0.38
163.2478943	0.03
165.1301575	0.05
177.0282745	0.41
177.8202209	0.12
179.0979156	0.37
180.9054871	0.14
185.1950073	0.02
187.0013733	0.21
192.9428558	0.14
195.3244629	0.06
204.9558411	0.06
207.0750732	0.17
217.0362396	0.04
219.2310638	0.04
221.2132568	0.04
223.1332245	0.11
228.9274292	0.06
230.6342010	0.05
235.2063904	0.11
237.2384949	0.10
241.2537842	0.07
247.1433716	0.10
253.3086243	0.05
255.0997009	0.16
259.5171509	0.09
267.1608276	1.19
271.3231812	0.53
273.1560669	0.16
276.0935059	0.08
277.1711731	0.12
285.1146240	1.00
296.9384155	0.03
327.0651855	0.55
329.1557007	0.11
340.8917847	0.82
341.8171997	0.05
353.1481934	0.08
357.3283691	0.03
359.5031128	0.06
361.3000488	0.04
368.2657471	0.04
369.3109741	0.03
371.2333984	0.18
380.6429443	0.14
381.3507080	1.05
382.8001099	0.05
387.5128784	0.08
389.3455200	0.03
399.2047729	100.00
400.1766357	0.53
424.3474731	0.21
425.1680298	0.16
428.3204346	0.06
429.2915649	0.04
431.0015259	0.03
433.6570435	0.04
444.4349976	0.11
459.0222778	0.05
460.4656372	0.09
461.5558472	0.04
470.6363525	0.05
472.5908813	0.15
473.4160767	0.05
475.4080200	0.09
477.2518921	1.14
483.0458374	0.13
485.5531616	0.04
488.2754517	1.62
489.3845825	0.95
491.4146729	0.08
492.6821289	0.04
498.7299805	0.02
502.4467163	0.51
503.3484497	0.27
504.0608521	0.05
506.2483521	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	168.0666
Annotation	5-Hydroxydopamine
Peak:m/z	Relative Intensity
124.1284180	0.04
125.9683533	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.08235931	0.17
94.98754883	0.39
97.92481995	0.17
100.0403595	0.29
100.8983765	0.32
103.1221619	0.73
105.1680145	0.17
114.0366821	0.20
120.0478821	0.17
122.9634857	0.46
128.9520721	1.70
130.0249329	1.00
133.1422577	0.18
134.0990753	0.32
137.2450867	0.14
139.0059814	0.57
142.0705109	0.50
150.9764862	19.36
151.993576	12.40
153.0493927	0.96
155.1744843	0.18
161.8495941	0.43
164.9870758	0.30
168.9580231	1.68
170.1128235	1.21
171.0419769	0.77
171.8743134	0.28
172.6185608	0.17
174.0041962	0.41
176.7888336	0.57
178.2840118	1.13
180.1075439	0.97
183.1237946	0.89
186.1067657	0.82
190.4468536	0.48
193.8134766	0.21
195.0352936	0.70
198.2690887	2.12
202.4388428	0.99
208.0961304	0.37
211.1521606	0.35
217.4326477	0.18
218.2286682	1.11
219.1478119	0.08
224.1989288	0.10
225.1131592	1.23
226.1459808	2.85
235.7532349	1.94
236.4364014	0.18
237.0980988	1.02
238.2658844	1.88
239.1626587	3.84
240.2175293	0.70
244.7473602	0.38
251.2285919	0.26
251.9900055	0.35
253.0939484	100.00
254.1165161	21.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9699402	3.93
131.0448914	0.41
158.9169006	100.00
199.0187073	1.86
217.0489502	1.09
225.8929749	0.04
227.0450439	0.10
229.0382080	23.66
244.9349670	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.2141
Annotation	Helonioside B
Peak:m/z	Relative Intensity
367.1705933	100.00
368.0313721	0.00
453.2165527	0.02
543.0928345	0.07
546.1047974	0.01
561.4797974	0.02
613.6084595	0.05
667.3576050	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.09
Annotation	N(beta)-Epoxysuccinamoyl-DAP-Val
Peak:m/z	Relative Intensity
106.9023743	0.04
109.0407715	0.04
111.0113831	0.10
127.0324707	0.18
135.0292053	7.89
145.1546631	0.03
154.9835358	0.06
161.0673523	0.86
171.1212311	0.03
173.0690918	2.15
179.0978088	44.12
191.0094757	100.00
306.4221191	0.03
334.9863892	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.08
Annotation	Altersolanol A
Peak:m/z	Relative Intensity
106.0213776	0.01
106.8910980	0.04
109.0793381	0.03
111.0179672	0.71
120.7679443	0.04
125.2372742	0.03
133.1868896	0.13
135.0108032	20.51
136.9846802	0.41
151.0951996	0.04
155.0131531	0.76
161.0116730	2.68
173.0531158	0.65
178.9713287	100.00
179.7626190	0.02
199.2277527	0.04
202.5030212	0.04
205.4739380	0.06
209.2937012	0.04
211.1567078	0.07
214.1238098	0.19
217.2997131	0.09
229.1264954	0.31
237.0259705	0.04
245.2847595	0.03
247.0692444	0.28
254.1127014	0.05
255.2676392	0.14
261.2133179	0.04
262.2185974	0.19
272.3629456	0.03
273.2085571	0.56
281.1902161	0.07
287.9055481	0.04
289.3578796	0.18
291.1756592	3.31
299.2835693	0.10
307.1740723	0.02
316.5788879	0.22
317.1849976	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.08
Annotation	Lactulose
Peak:m/z	Relative Intensity
205.1652832	0.05
208.9823151	0.17
211.0187988	0.22
212.8955688	11.28
214.9477081	0.10
234.1959839	0.04
280.2882080	0.04
292.9205933	0.04
295.0494995	0.19
296.8431396	100.00
321.0986938	0.06
334.8038940	39.71
336.6356201	0.08
362.2022400	1.24
363.1298523	0.40
380.9437866	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	209.08
Annotation	Sinapinaldehyde
Peak:m/z	Relative Intensity
64.9131241	0.25
74.9833832	0.23
76.9378815	0.09
84.9425964	0.19
89.0644836	1.74
90.9708862	0.02
92.8516693	11.04
94.8402100	0.03
97.0023346	0.10
98.7595367	0.04
100.8937378	0.01
102.9201355	0.16
105.0545349	1.10
105.9648132	0.39
107.1719513	0.02
109.1007080	0.11
111.1887970	0.09
112.9297028	0.03
117.1573181	0.06
119.1407013	0.06
121.0597687	2.81
122.9249725	0.10
125.0315857	3.18
130.9551544	0.02
132.9281769	2.03
135.0540466	0.26
137.1741791	0.06
139.1342926	0.18
145.0394440	2.26
147.1798553	0.21
148.9678345	24.77
150.0800018	0.06
151.0482330	2.10
152.9994354	8.98
158.9654541	0.06
163.1171570	0.77
164.0402527	0.07
164.9205627	0.20
166.1767731	0.06
167.0705261	0.84
168.6411285	0.03
177.0100708	56.88
178.9218292	0.22
181.0200043	100.00
191.1269379	2.92
192.0751038	0.08
193.2606201	0.04
194.2441101	0.18
199.5375214	0.19
200.1574554	0.08
209.1379089	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
97.17595673	0.34
98.81268311	0.50
106.7981033	0.34
109.2060394	1.10
113.0140076	1.09
114.2915955	0.35
121.1150665	0.46
123.016861	1.31
124.2945251	0.25
125.1371078	1.31
130.958725	0.31
133.2046814	1.20
135.243866	0.57
137.2305908	0.41
138.9752197	1.28
140.9806824	1.22
143.0041199	1.04
145.1254272	0.58
146.3682251	0.35
148.68927	0.50
149.6049347	0.56
153.0628052	0.59
155.0246277	1.81
157.1799774	0.28
161.0384064	0.23
162.9763794	0.91
165.3960419	0.73
167.1253204	1.27
169.3174744	0.41
175.4363556	1.81
179.1052094	0.29
183.1480408	2.40
184.2378693	1.15
185.1925354	0.43
187.031601	0.74
189.1315002	0.27
191.1804657	1.65
193.3628387	2.88
195.1373901	5.99
197.3481445	0.89
198.5061035	1.69
201.2311096	0.45
203.2538452	0.84
205.2940674	0.53
206.1889038	0.50
207.2351074	0.95
209.1069336	2.47
211.1348267	1.85
212.5151672	1.98
213.2117615	5.66
215.2168274	0.72
219.4648438	0.66
221.2086792	1.68
223.3430481	1.00
225.2250366	2.26
226.1367493	1.29
227.1595459	2.43
229.0204468	0.34
231.3392029	0.54
233.3857422	0.98
235.4503479	2.14
237.1671753	2.93
239.1615601	1.39
241.1275024	0.49
247.3419189	1.42
251.2506104	4.58
253.164856	8.00
255.2005005	2.16
257.2851868	1.28
265.2067261	3.48
267.4860229	0.33
269.096344	0.84
270.1759033	2.56
275.2734985	18.30
279.1027832	1.38
282.5999756	0.66
283.2278137	6.57
284.1291504	0.95
285.2824707	0.70
293.2051697	100.00
294.1323853	1.01
302.0269775	1.25
302.8955383	2.25
309.3053589	0.24
310.274353	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1921
Annotation	Plantamajoside
Peak:m/z	Relative Intensity
179.0216675	0.27
191.2147980	0.18
194.1388550	1.05
207.0882874	3.10
208.0889587	0.65
209.1734772	12.14
221.9513855	3.19
223.1271820	2.21
291.3487549	0.06
338.0154419	0.10
369.3378906	0.07
383.2330322	0.06
401.2254028	5.00
413.1256104	3.26
431.1231079	100.00
431.7695312	0.37
447.4768066	0.08
459.4259644	0.21
476.4044800	0.08
481.2234497	0.11
485.2799072	0.09
486.1204834	0.04
488.7044067	0.07
491.6541138	0.11
492.5825195	0.21
499.4102783	0.21
533.4024048	0.10
541.7131958	0.14
545.7268677	0.14
549.4357910	0.05
550.1914062	0.07
555.2916870	0.10
579.1500244	3.66
579.7548218	0.03
590.0916138	0.25
591.9646606	0.24
592.8456421	1.93
593.5570679	0.48
595.2426147	0.29
603.4584961	0.19
607.2765503	0.11
621.4745483	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	4'-METHOXYFLAVONE
Peak:m/z	Relative Intensity
76.85962677	1.50
78.84464264	0.67
94.78948212	0.44
96.73179626	1.76
98.80412292	1.16
103.0772705	3.04
105.0278625	2.41
106.9127502	3.73
109.0582581	1.01
111.0184326	1.33
112.5487213	0.45
121.1161041	1.82
123.0513611	1.29
128.9818268	7.46
130.0135498	0.38
132.864151	0.47
136.1603546	0.66
141.0613556	0.47
143.2184296	1.22
145.0926514	1.51
146.5977325	1.99
148.9786987	0.66
150.9380341	77.42
151.8842316	9.70
152.9549713	1.57
155.096817	2.26
158.805481	1.23
161.1535034	0.82
165.2012787	2.41
165.9836426	1.45
167.179657	2.40
169.1377869	2.79
169.8144379	0.45
173.3565216	0.47
175.403656	1.38
179.1773529	2.55
179.8664398	0.88
182.2389069	6.00
183.067215	0.75
185.1834869	5.71
189.1674042	3.85
193.1162262	0.50
195.9626923	0.38
197.1078796	4.67
198.3995667	2.54
199.4503784	1.07
207.307312	2.04
208.1731415	1.07
209.3030701	0.44
211.3018646	0.44
212.1890564	0.63
217.1650848	14.80
221.1626587	3.14
225.1828766	9.68
226.227478	0.83
234.3471832	0.48
235.2242584	29.06
238.0574951	21.46
239.239151	1.82
253.0802612	100.00
254.0652313	2.96
257.1660156	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.17
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
229.0556030	0.07
245.0750122	0.02
248.3421783	0.01
252.1278992	0.01
253.1107178	0.02
265.0609741	0.05
272.9536438	0.01
277.4233704	0.04
279.1304321	0.02
281.2523804	0.01
289.3576050	0.01
292.2933350	0.04
293.2105103	0.01
294.2908325	0.04
294.9517822	0.05
305.1585083	0.01
313.1266479	0.11
319.0208130	0.05
321.1816711	1.04
335.1818848	0.01
337.0470581	0.08
338.1552124	0.12
339.3091431	0.54
347.2191772	0.09
351.1289673	0.15
353.1440430	0.13
355.1616211	0.01
357.0908813	0.05
358.0542603	0.01
366.2509155	0.03
373.0498047	0.02
403.3098145	0.04
407.8584595	0.02
425.4699707	0.01
431.1922607	0.02
435.6473999	0.04
441.2432861	0.17
451.2061157	0.04
469.3484497	0.38
477.4337769	0.03
483.5692749	0.01
485.3453979	0.10
487.0797119	0.10
495.3174438	0.04
498.3524170	0.03
511.1735229	0.50
513.2509155	100.00
518.4474487	0.02
523.1890869	0.02
525.1227417	0.05
530.2470703	0.02
531.3389893	0.14
533.3292847	0.01
534.3690796	0.02
535.1065674	0.03
537.3936157	0.08
543.1768799	0.02
549.2435913	0.24
552.2092896	0.03
553.3594971	0.01
560.4856567	0.08
561.3140869	0.05
575.4851685	0.02
590.7711792	0.08
595.3041382	0.01
603.3786011	0.02
606.4332886	0.03
608.2318726	0.55
608.9515381	0.43
609.5917358	0.15
614.8729858	0.02
615.5552979	0.05
617.2484741	0.02
621.6467896	0.02
624.4057617	0.03
625.8849487	0.03
629.4689331	0.07
631.2995605	0.07
639.2416382	0.01
647.6744995	0.06
657.4205322	0.02
661.1923218	0.05
677.4188843	0.04
680.5758667	0.01
685.4931030	0.05
686.3228149	0.03
687.2819214	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.09
Annotation	Cordyformamide
Peak:m/z	Relative Intensity
108.0948334	0.14
109.2079315	0.16
111.1352386	0.16
117.9952698	0.09
127.0058136	0.14
129.1268921	0.05
134.0537109	0.25
135.0308228	9.34
136.0008240	5.95
137.0960083	1.76
139.1212006	0.03
143.0381165	0.03
154.9820557	0.22
156.1660156	0.20
157.0698547	0.30
161.1199951	0.86
162.1300354	0.62
162.9382935	0.21
173.1075745	3.11
174.0853424	1.87
175.1496582	1.32
179.0548553	39.51
180.0340424	36.43
181.1399841	17.73
191.0920105	100.00
192.0894165	73.54
193.0623627	43.55
231.1952515	0.03
249.0729675	0.08
254.1643066	0.03
283.2973022	0.06
307.1076355	0.04
309.5394287	0.11
310.4177246	0.04
311.2349548	0.11
319.3525391	0.20
336.1741943	0.04
337.3210449	0.05
337.9432983	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	717.2752
Annotation	Unknow
Peak:m/z	Relative Intensity
221.3319855	0.04
235.2416534	0.48
260.1719360	0.04
299.3769531	0.07
309.3494873	0.05
311.2343750	0.07
327.1588135	0.10
328.9985352	0.03
341.4533386	0.03
355.1342773	0.04
357.3834839	0.54
369.1771240	0.40
370.2377319	0.27
371.3262329	3.38
376.2305298	0.06
383.3395996	0.03
392.8001709	0.09
443.2309570	0.25
443.8786011	0.02
460.6400146	0.04
491.4492188	0.09
507.4100952	1.03
515.1540527	0.04
518.5246582	0.17
519.4064331	0.87
520.5936279	0.43
521.4075928	1.89
525.6155396	0.06
534.3494263	0.07
537.5245972	1.77
544.5338745	0.06
554.2965698	0.05
555.3604126	0.03
563.0820312	0.11
564.2803345	0.04
565.4976196	0.19
567.4187012	0.23
574.0723877	0.06
575.2805176	0.79
583.0518799	0.16
584.5155029	0.16
585.3062744	0.35
611.1419067	0.04
622.6695557	0.15
641.5308228	0.05
645.5310059	0.07
669.3660278	100.00
670.0108643	0.36
671.2982788	0.08
672.4877319	0.04
673.3579712	0.31
680.9487915	0.52
681.5645142	0.22
685.3365479	0.16
686.5333252	0.03
697.8023682	0.04
698.9751587	0.35
699.6171875	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.1141
Annotation	Unknow
Peak:m/z	Relative Intensity
194.8111877	0.05
202.1351318	0.07
204.9127502	0.03
209.8536377	0.07
217.1731567	0.07
218.0447083	0.12
230.1511536	0.03
232.0779266	0.18
233.2200623	0.03
235.0335083	0.09
239.0095062	0.03
240.0937958	0.38
256.9303589	0.09
257.5334473	0.02
258.3132629	0.09
260.1804504	0.61
261.1372986	0.15
262.1374817	0.08
263.1025085	0.06
265.2019348	0.03
269.1680908	0.15
277.1154175	0.41
277.9880066	0.27
286.0882263	0.03
287.0415039	0.11
288.2534180	0.17
289.8450317	0.02
292.0157471	0.13
292.8468018	0.07
295.0040588	0.11
301.1561890	0.05
302.1118469	0.86
303.3967285	0.20
304.3342896	0.66
305.1045532	1.14
306.2363281	0.39
307.1742554	0.19
315.1290894	0.05
316.8789673	0.03
317.9818420	0.66
318.7486572	0.23
320.0120239	3.76
321.0797729	0.74
322.2040405	0.02
328.2184448	0.05
331.1148071	0.04
332.9012146	0.10
336.7907410	0.06
343.8409424	0.57
345.0072021	0.25
346.0627441	4.05
346.9316406	0.34
348.0466309	1.10
349.2368164	0.23
363.9105225	0.67
364.6005859	0.10
371.9124756	0.25
374.0107422	0.28
389.9819336	2.36
392.0144043	10.10
393.0722656	0.98
413.1486206	0.03
416.7564087	0.04
417.8919067	1.97
418.9444580	0.36
433.9959717	0.15
436.0358276	19.85
437.1004028	3.04
451.2160645	0.07
461.9926147	2.99
463.0739746	0.23
468.1450195	0.02
478.1201172	0.17
480.0745239	100.00
481.0579224	15.34
482.0989990	0.32
560.8604736	0.05
561.9254150	0.14
567.1177368	0.02
584.8887329	0.07
586.9583130	0.24
589.1607666	0.07
605.0685425	0.11
607.1132812	0.77
613.0185547	0.12
618.3261108	0.12
630.1776123	0.04
631.0509033	0.66
631.9210815	0.52
646.8480225	0.05
648.4013672	0.15
649.0022583	1.64
650.1464844	0.27
660.2817383	0.04
666.1754761	0.03
674.2885132	0.10
674.9534302	5.27
676.0460205	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	813.3328
Annotation	Unknow
Peak:m/z	Relative Intensity
356.1961670	0.06
375.3150635	0.73
389.4697266	0.92
405.3974609	0.11
406.3197021	0.29
407.1266479	0.52
408.1559448	0.05
419.3217773	0.20
420.3413086	0.20
421.3411865	6.20
422.3421021	0.67
433.4188843	0.95
434.3664551	0.09
435.3483887	0.11
444.6333618	0.09
456.1296387	0.16
461.3065186	0.36
464.4209595	0.04
475.4083862	3.18
476.2661133	0.22
493.3142700	0.12
494.7532349	0.31
537.1475830	0.10
551.4620972	0.05
552.4379272	0.31
553.5341797	0.16
555.3101807	0.26
557.9804688	0.08
566.4750977	0.07
567.3648071	0.57
568.2922974	0.52
569.4451294	6.00
570.3482056	2.83
581.6314087	1.22
582.4483032	0.76
585.4130249	8.00
586.4010010	2.03
596.9348755	0.26
598.1605835	1.52
599.3258667	7.09
600.4623413	3.20
602.4553833	0.22
603.7693481	0.24
606.4739380	0.09
608.3723145	0.26
611.4872437	0.16
616.1333618	4.85
617.3092651	17.10
618.3110352	4.16
623.5633545	2.22
624.6814575	0.93
632.3214111	0.05
636.3447876	0.11
641.3272095	0.47
642.3229370	0.23
653.4658813	1.99
654.2929077	0.25
655.3217163	0.07
659.1076050	0.50
659.8049316	0.34
671.3201904	12.26
672.3935547	2.59
689.3497925	6.00
690.3582153	1.83
703.3839722	0.18
717.4154663	14.47
718.4211426	8.60
719.0975952	0.09
725.1760254	0.23
727.5603638	0.31
729.2494507	0.32
730.2025757	0.06
735.5355835	0.08
744.7720337	0.14
747.4099121	33.29
748.3680420	12.23
749.0398560	0.10
759.2323608	1.00
760.4219360	0.14
765.2554321	66.19
766.4262085	15.57
768.4366455	0.12
777.3419189	30.00
778.4713745	10.32
795.3137817	100.00
796.4387817	30.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8697205	0.32
175.0611267	0.75
199.0597229	0.13
202.7650452	0.02
215.1461945	0.01
216.8215942	0.02
229.0380554	0.10
245.0517578	0.29
272.9720459	5.96
289.0934448	10.73
387.0110474	0.83
401.5417480	0.48
402.9551392	100.00
403.5857544	0.09
441.9879150	0.03
443.0755615	0.43
443.9693604	0.03
446.3623657	0.02
460.1218872	0.08
461.3358154	0.09
469.9736328	0.08
471.0794678	0.08
472.6477051	0.10
489.1718750	0.13
516.9855347	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
92.78936005	0.44
97.14585876	1.53
98.90408325	4.66
109.1596756	0.87
111.0705872	0.34
112.9673233	2.17
116.9533768	0.43
119.2145538	0.30
120.7055511	0.84
123.1386795	0.56
137.0085449	0.52
138.5980682	0.86
141.2841187	0.90
142.1066284	0.55
147.1463623	0.31
151.1901855	0.67
157.1755066	0.41
160.8957062	0.73
162.9156036	1.73
165.0740967	1.76
174.9511719	1.02
177.0327301	0.27
179.290863	0.37
181.0270996	3.38
183.1974792	1.88
184.9696503	0.99
191.1872101	0.99
195.2168884	5.56
198.8768311	2.52
200.0553131	0.96
201.0955963	0.78
203.0539703	0.38
205.3816223	0.50
206.9084778	0.37
209.0733337	2.44
211.0131836	2.61
215.2734375	1.40
217.1221313	0.52
219.2307434	1.17
223.0245361	0.99
225.1761169	0.25
227.0704651	0.86
229.4298706	2.37
230.1225586	3.29
230.9581909	0.27
233.0045166	0.85
235.1351624	1.28
236.2197876	0.90
237.1864929	0.94
239.21521	2.93
241.2919922	2.11
242.421936	0.51
246.9124756	0.87
248.3477783	0.35
249.3039551	1.33
251.1782837	7.94
252.1868591	0.75
253.1873779	14.25
263.3612061	0.88
264.2938232	0.56
265.2311096	5.41
267.1776733	5.06
268.5619507	0.56
269.3450928	1.38
270.1938171	0.93
275.1814575	22.75
276.2561646	0.53
277.2609253	0.44
279.3633423	1.33
280.0571289	2.64
281.6329651	0.49
283.2817688	4.55
288.0194397	0.91
292.5480957	9.61
293.2074585	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.2184
Annotation	Fraxiresinol 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
181.1152039	0.02
194.5285187	0.02
205.1860962	0.02
208.0862579	0.04
208.9346924	0.01
245.3588867	0.02
251.0677490	0.03
255.1557770	0.01
289.4895630	0.02
305.1436768	0.04
325.2073364	0.05
341.0357056	0.02
358.4217529	0.18
359.2875366	0.06
360.3350830	0.02
366.8909302	0.01
371.0884399	0.07
387.2566528	0.01
389.3816528	0.15
391.2549438	0.47
392.2347412	0.04
399.5358276	0.02
403.2854614	0.25
404.3547363	0.03
417.3248901	0.22
418.3135986	0.01
419.2324219	0.02
428.0725098	0.02
429.5273438	0.05
433.2602539	0.01
434.4527588	0.10
435.2782593	0.12
436.1105957	0.01
441.0833130	0.02
459.3906860	0.01
464.9447021	0.02
477.2604370	0.07
478.2548218	0.02
483.2112427	0.02
489.0109863	0.01
501.3352661	0.02
506.2789307	0.01
512.0965576	0.03
519.3624878	0.11
521.2629395	0.43
523.0541382	0.02
536.5924072	0.01
551.3264771	100.00
552.3471069	1.27
553.3692017	0.12
559.4207764	0.02
562.5311890	0.04
563.9792480	0.01
565.2451782	0.12
567.2963257	0.02
579.5358887	0.20
580.4598389	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.218
Annotation	Ficusesquilignan B
Peak:m/z	Relative Intensity
165.0591125	0.61
175.4950562	0.02
177.0593567	0.05
180.0017700	0.10
191.2310486	0.01
195.1321259	3.07
196.0408783	0.10
202.8372498	0.02
249.1147461	0.01
251.2362671	0.02
279.2203979	0.06
295.1026611	0.02
309.2006226	0.13
311.2388306	0.03
313.3152466	0.04
323.3016968	0.13
324.3190918	0.17
325.3142700	0.29
326.2039795	0.05
327.3515625	0.01
328.4325562	0.03
337.2030640	0.19
338.2893677	0.22
339.1617432	1.09
340.3361816	0.33
341.9816284	0.53
343.3461914	0.95
344.0563965	0.08
351.4290771	0.02
354.2229004	1.85
355.3959961	1.11
357.2864380	29.28
358.3582153	4.87
367.2838135	0.33
369.2879028	53.96
370.2864380	8.87
373.4002686	0.20
374.5043335	0.01
381.0149536	0.04
382.0996704	0.03
383.2411499	0.02
385.3250732	0.20
386.3579102	0.18
387.0241089	1.62
388.2587891	0.29
389.5009155	0.02
401.2958984	0.03
412.4764404	0.05
429.2133789	0.02
432.1909180	0.01
441.4236450	0.28
442.1854248	0.02
444.7288818	0.01
459.0711060	0.14
459.9731445	0.05
475.2583008	0.03
488.3552856	0.03
489.4062500	0.06
491.6005249	0.01
494.2081909	0.05
505.4116821	0.80
506.4204712	0.32
509.3817749	0.02
517.3386841	3.17
518.4612427	1.20
519.6128540	0.02
523.4921875	0.04
535.3297729	100.00
536.3273926	31.78
537.3753052	0.10
539.2269287	0.04
547.5428467	0.07
548.4782104	0.01
553.3563843	2.51
554.3208618	0.42
565.0990601	7.46
566.2405396	2.05
582.1889038	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
101.0056305	6.39
106.9123993	0.12
112.9285355	20.31
115.2112122	0.91
119.0142975	16.62
125.0484543	2.99
130.9833221	8.82
143.0284119	23.31
148.9805603	3.52
160.3851624	0.91
161.0461121	22.80
178.9814453	100.00
220.6083679	0.31
242.9741821	0.36
244.8931274	0.15
278.2120361	0.35
281.1442566	0.72
298.9029541	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1558
Annotation	Ferupennin M
Peak:m/z	Relative Intensity
122.9885559	1.07
123.9036560	0.05
131.1037140	0.20
133.2877197	0.04
136.0897522	0.06
137.1466980	0.20
138.0105896	0.16
139.1343994	0.04
143.2669525	0.08
144.1281128	0.09
146.9218140	0.05
150.9828796	11.72
152.0045929	0.93
152.9693909	0.12
153.9946594	0.04
159.1520081	0.36
160.1268921	0.37
161.0987244	0.16
165.9377136	33.61
167.1147461	2.32
175.1522217	1.32
177.2736206	0.28
178.1135254	0.04
179.1435394	0.32
181.0952148	100.00
181.7945862	0.09
187.9946136	0.29
189.0223389	0.27
190.1091919	2.87
191.1249542	0.39
192.1316528	0.61
202.9771423	0.35
205.0787659	6.77
206.1227570	0.66
206.9614563	0.10
215.2131653	0.08
216.8959656	0.15
218.2436981	0.08
220.2272491	0.11
221.0776825	0.31
225.1261292	0.08
232.2991028	0.08
233.2436218	0.16
235.9171143	1.14
237.1380615	0.05
247.8514404	0.23
249.1615295	0.07
249.8922424	0.05
251.3981323	0.16
275.2791138	0.17
314.3984680	0.05
320.2157593	0.17
321.3129578	0.11
323.3175049	0.07
324.1535339	0.05
339.5804443	0.12
340.5067139	0.03
341.3072205	0.09
343.2739258	0.22
354.0850830	0.37
356.3155518	1.86
357.4849548	0.79
369.1943665	0.24
371.1858215	12.78
372.2187195	0.26
373.3582764	0.59
378.0031128	0.17
381.6152649	0.07
387.2438049	4.71
387.9126892	0.08
397.0848083	0.24
399.1313171	0.36
402.2200928	59.47
402.8534851	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	361.1274
Annotation	Heteroflavanone A
Peak:m/z	Relative Intensity
103.0081558	0.12
106.9121628	0.32
118.9577560	0.54
121.9605560	1.77
133.0116882	0.61
134.9449310	0.22
137.0006256	38.99
140.9566650	0.22
144.0853729	0.31
147.0502472	1.46
150.2662964	0.16
151.0873718	1.60
153.1224670	0.26
161.0231934	2.83
162.0584412	2.51
162.9948883	0.39
167.2161407	0.25
169.2109375	0.19
173.4347534	0.16
175.0868530	2.56
179.0784607	2.59
182.9253387	0.63
193.1143799	0.57
194.9134521	1.53
205.1892090	0.68
207.0986328	53.41
209.0740509	0.68
211.2389221	0.25
214.2526855	0.10
219.3207703	1.43
220.8238525	0.12
222.2434387	0.23
229.2633667	0.07
237.0410461	19.78
240.9639587	0.12
243.1326904	0.10
247.3061829	0.24
254.6161804	0.30
257.2320557	0.98
262.2749329	0.09
267.1765442	0.37
271.3351135	0.72
275.4309692	0.09
277.0761108	0.29
279.2811279	0.49
281.3585815	0.39
283.7272339	0.34
284.4198608	0.18
285.2872009	1.24
286.1444702	0.16
287.4854736	0.06
289.0076904	0.40
293.1621704	0.18
294.3352661	0.30
299.2114868	26.81
301.0156860	0.10
302.8966980	0.17
306.5141296	0.07
307.4160767	0.26
311.2619629	26.06
313.4541016	0.71
315.1109619	0.40
316.2187805	0.06
317.3400879	0.75
319.8240356	0.10
324.8627930	0.95
329.2124634	100.00
331.1314087	74.56
332.1925659	0.82
333.0675659	0.20
338.9360657	0.09
342.6300964	3.06
343.2354736	20.24
346.3070984	0.31
360.3537903	0.36
361.3694153	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.2825
Annotation	Clerodendrin H
Peak:m/z	Relative Intensity
205.3279724	0.05
237.3236389	0.14
285.1581726	0.07
289.3906860	0.14
290.2536011	0.08
301.1168823	0.11
311.2317505	0.19
319.1841125	0.18
343.3537598	0.16
346.0285034	0.04
364.1037598	0.28
365.3275146	0.07
372.0606689	0.26
379.2899780	0.32
381.2255249	0.08
390.4088745	0.98
392.4531250	0.04
408.2754517	0.07
414.5454102	0.03
423.4481812	0.42
432.3333130	1.22
434.4401855	0.10
436.4227905	0.44
446.4951172	0.17
450.3184204	0.87
464.2124023	0.31
476.4395752	11.95
478.5773926	0.11
481.9321899	0.33
485.4993896	0.20
487.1304932	0.04
490.2798462	0.19
496.6365356	0.22
508.3104858	66.30
508.9285278	0.44
509.5900879	0.15
511.1776123	0.15
515.1957397	0.07
525.2709351	0.04
527.5886841	0.08
529.5082397	3.56
546.5527344	0.16
547.2995605	0.05
549.2361450	0.08
553.4884644	0.23
555.3523560	0.07
559.4476929	0.17
561.5103149	0.25
563.3389282	0.21
569.1926270	0.18
570.5712891	0.15
571.5214844	1.83
573.4411011	13.50
579.8036499	0.04
587.4167480	1.30
588.6954956	0.70
589.4621582	5.35
591.4064331	0.41
597.5362549	0.64
601.5945435	0.07
603.2960815	0.51
605.3817139	52.21
606.0098267	0.12
615.3950806	17.83
616.0057983	0.08
617.5056152	0.10
619.2519531	0.82
621.3588867	0.37
629.4903564	0.34
630.3477173	0.28
633.3777466	100.00
634.1546021	0.19
635.5505371	0.15
639.6937866	0.04
645.3361816	0.14
647.3523560	58.14
648.0150146	0.22
650.3880005	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1394
Annotation	Nitidanin
Peak:m/z	Relative Intensity
134.9392242	0.13
147.6181793	0.16
160.2537231	0.08
171.2366943	0.11
173.2680054	0.18
185.1725159	0.10
187.5713348	0.21
197.0903015	0.09
199.2206879	0.06
201.3648376	0.08
209.0605469	0.27
215.1151886	0.11
223.0654144	0.48
224.4580994	0.05
227.3264771	0.13
231.1616821	0.04
243.3374634	0.15
244.2543640	0.07
266.5386353	0.10
273.9364624	0.15
275.1838379	0.07
287.0846252	0.32
289.1942749	0.11
291.1441650	0.30
298.2665405	0.15
303.0966187	0.08
313.2807922	0.06
315.2178955	0.19
323.5304565	0.11
329.3010254	0.41
333.4492493	0.06
334.8178711	0.05
339.4785156	0.30
341.3898010	1.19
343.3048706	0.25
344.3346252	0.16
347.3836670	0.12
353.3341064	0.37
357.2467957	0.70
359.2959290	100.00
361.5328674	0.16
364.3158875	0.07
365.3823547	0.05
367.0615540	0.19
367.7115784	0.21
368.3317871	0.10
369.9194946	0.35
371.3632507	0.40
373.1266174	0.10
383.4963074	0.04
384.2981873	0.21
385.3819885	2.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.1086
Annotation	Androsin
Peak:m/z	Relative Intensity
92.8692322	0.04
96.8914566	0.08
101.0267639	0.09
113.1998138	0.03
118.8951111	0.04
121.1292419	0.13
123.1102524	0.04
129.0318756	0.87
130.2317505	0.17
144.9239502	0.06
146.9985962	8.02
161.1596985	0.03
165.0204773	100.00
166.0748596	0.17
178.0789337	0.06
179.0923309	0.06
181.1024628	0.06
184.1566467	0.07
190.7953186	0.04
199.2171783	0.06
207.1619568	0.04
211.1090088	0.05
213.1600037	0.10
225.3493347	0.04
229.2606812	0.04
231.2397766	0.05
232.9891357	0.06
243.1489563	0.04
251.1444702	0.07
259.4659729	0.04
280.9649353	0.19
283.2274780	0.22
285.0021973	0.05
296.4716187	0.05
308.3796387	0.27
309.3330688	0.16
311.9827881	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
132.8972931	2.43
139.117157	1.44
143.0947418	2.00
183.230011	3.95
194.9618835	11.25
207.3759918	5.41
211.0978699	1.16
213.4249878	2.36
216.6737518	2.95
253.1853943	4.23
263.3432312	5.23
281.3540344	4.74
283.258728	4.77
283.9242554	5.20
295.2221069	9.54
307.350708	2.97
324.6514282	2.83
327.379364	4.56
328.8109436	2.48
330.3692627	1.58
336.3161621	11.47
341.1157227	4.09
343.2623291	2.36
354.602356	3.05
360.9179077	1.58
365.9978333	8.94
367.2301025	3.51
372.4845581	9.04
377.3845825	5.95
379.1072083	1.30
391.4263916	1.30
392.5235901	3.32
395.6809387	7.12
396.5709534	1.16
398.6128235	5.29
407.1489868	2.25
408.271759	100.00
409.1901855	15.89
411.5068665	6.56
426.1882324	7.12
430.9407654	3.19
438.332489	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
128.0213013	10.19
132.9330292	12.07
141.0445251	7.08
142.3499756	2.18
149.0632935	12.22
153.0205078	9.29
154.9908752	11.54
164.1236877	10.36
173.0472717	29.94
176.973587	20.05
179.1145325	2.91
208.2436829	9.15
209.5106506	13.42
220.1040955	17.49
233.7895508	3.28
247.426239	6.40
252.1762085	4.03
267.4347534	9.33
274.883606	4.00
281.2397156	10.63
283.8128357	3.08
308.3858032	6.97
328.56427	6.96
334.4421692	3.67
335.3929443	22.43
340.3557434	14.87
353.1079712	17.37
357.2629395	44.55
363.4098816	9.38
368.4165955	9.88
371.1941528	3.29
377.2657471	13.73
379.2964172	6.20
384.53125	6.34
394.4445496	2.92
404.401947	5.06
407.4946594	24.19
408.2736816	100.00
409.2129822	25.23
411.4035034	11.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.99835205	0.68
81.02248383	1.12
94.98529816	0.99
98.75170898	0.89
102.9456635	2.11
105.2038879	0.62
106.9686279	1.45
109.1038666	3.21
110.8995819	1.12
120.9043579	0.54
122.9083252	0.80
126.9292908	0.41
128.9949951	5.71
132.9914246	0.97
135.1494904	3.19
136.9007874	2.08
146.9024506	3.39
150.9937439	100.00
151.8629761	6.46
152.5139771	0.33
153.9388123	1.08
155.0007172	1.78
162.9235077	5.30
165.1839142	0.66
165.9869232	1.50
167.1398163	5.44
169.2419739	2.66
174.9108124	3.22
177.1600647	1.78
179.1095734	7.63
181.3710632	1.37
184.16716	1.56
184.9501495	1.70
186.0831604	2.33
188.9118347	2.19
192.7302704	0.50
193.9738617	1.08
195.1129456	1.73
197.005722	1.75
198.1726227	0.51
199.2086334	1.49
204.9208221	0.58
207.1994171	4.10
211.3435822	4.55
217.2505951	18.29
220.0861359	0.55
221.1282196	7.47
222.1352997	0.51
225.151535	7.11
226.3348999	0.63
235.1909637	49.64
238.1058807	17.53
239.2205353	1.95
243.9343719	3.32
253.0928345	92.24
254.1877289	4.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.1382
Annotation	Unknow
Peak:m/z	Relative Intensity
216.9069519	0.03
225.1947174	0.08
243.1834717	0.05
245.0673523	0.06
263.1847534	0.14
272.2749634	0.11
305.6004028	0.05
306.3467102	0.54
327.0530090	0.08
339.3975830	0.11
345.2596436	0.04
354.2215576	0.22
360.5717163	0.09
367.1761475	0.07
379.1270142	0.08
386.1810303	0.08
398.4711914	0.05
423.2804565	0.17
433.3691406	0.30
441.2720337	3.11
441.8781738	0.10
451.2921753	0.67
456.9460449	0.03
457.6145020	0.05
459.2546387	0.03
462.1651001	0.65
466.1829224	0.13
467.3914185	0.37
475.3005371	12.62
482.8804321	0.07
485.1323242	7.18
485.7600098	0.05
491.2160645	0.40
499.1764526	0.04
501.3052979	0.58
503.3334351	3.69
505.4049683	0.17
518.5371094	0.28
519.2194824	5.42
520.9594727	0.32
521.8912354	0.10
531.2053833	0.05
535.2583618	0.52
537.1896362	100.00
537.8366089	0.19
546.0711060	0.16
547.5601196	0.05
565.0647583	0.11
577.4473267	0.18
579.2789917	0.13
587.3767700	0.38
595.1120605	0.18
596.2413330	0.18
597.2441406	0.42
617.5383911	0.09
618.3344116	0.03
631.1477661	3.74
641.2706909	1.15
647.1249390	0.34
648.9679565	0.19
657.2692261	0.23
659.2966919	0.20
673.1624756	0.03
674.7144775	1.00
675.3531494	1.00
676.5314331	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1194
Annotation	Quinic acid
Peak:m/z	Relative Intensity
123.3803864	0.02
126.9883499	0.06
144.6845398	0.05
155.0694122	0.08
161.0983887	0.03
171.0621948	0.02
173.0493469	0.13
189.0839539	0.04
191.0389099	100.00
191.8626556	0.02
202.9752502	0.01
207.1767578	0.02
208.3302307	0.05
218.1655731	0.01
263.1767578	0.02
293.2747498	0.04
323.0593262	0.08
337.1860962	0.02
341.1798096	0.19
345.4300232	0.05
365.2855530	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1557
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
173.0725098	0.22
173.7033539	0.02
179.0372009	10.01
180.1499481	0.69
189.0245819	0.08
191.1889648	0.17
217.2465057	0.73
217.9373627	0.05
235.1882172	3.80
236.1714478	0.52
253.2214203	0.89
254.0090942	0.02
265.0590820	0.01
299.3871460	0.06
319.1712646	0.03
341.1690063	100.00
342.2206421	14.19
363.1733398	0.04
365.3934937	0.02
369.7490845	0.03
373.2816772	0.09
385.1223145	0.03
386.6250610	0.08
397.1470337	0.72
398.3399048	0.48
410.0725708	0.11
415.1941528	0.25
425.1797485	0.19
482.1752319	0.02
487.0922241	0.05
531.6055298	0.20
533.4323120	0.22
559.2626953	40.27
560.3002319	10.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1668
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
229.3531342	0.01
241.2070007	0.01
251.4531860	0.04
253.0680695	0.01
269.1194458	0.10
277.4133301	0.01
278.0935059	0.01
287.3392334	0.01
290.4527588	0.01
293.2515259	0.02
295.1590576	0.04
296.1902466	0.05
297.2124023	0.05
307.4666138	0.01
309.3175659	0.01
313.1072998	0.09
314.0541992	0.01
321.2312012	0.22
322.1018677	0.06
337.4877319	0.05
339.1775513	5.45
340.2068481	0.58
351.2567139	0.13
353.1110229	0.09
367.2663574	0.04
391.6787109	0.01
403.0089111	0.02
417.3665771	0.02
418.2625732	0.01
433.4568481	0.02
453.2307739	0.04
467.0872803	0.02
469.2811279	0.52
470.3578491	0.11
485.3883667	0.05
487.3214111	0.01
488.4863281	0.01
495.3177490	0.40
496.3430176	0.03
501.4289551	0.02
511.3478394	0.01
513.2258301	100.00
514.1824951	13.25
515.0191040	0.01
519.1754150	0.04
529.6201172	0.01
531.2573853	0.07
534.6378784	0.01
537.1178589	0.01
543.2680664	0.03
549.1325684	0.04
550.4827271	0.05
562.0553589	0.05
587.3545532	0.01
595.5990601	0.02
602.3450928	0.01
608.7929688	0.03
610.2996216	0.01
629.6301880	0.01
643.2716675	0.02
661.3032837	0.02
662.3886108	0.04
687.5344849	0.02
688.2821655	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9927216	0.04
199.2268372	0.04
216.9567261	0.02
229.0789490	0.11
272.9966431	5.81
275.3453369	0.02
289.0316772	0.11
289.8819580	0.05
387.0808105	19.21
484.0479126	0.04
485.1929321	0.04
497.9605103	0.11
499.2425537	1.20
500.9572754	100.00
501.5905151	0.20
503.1418457	0.04
549.9058838	0.04
559.1291504	0.12
568.0947876	0.15
568.9918823	0.24
570.4563599	0.12
587.2025146	0.04
587.9029541	0.03
596.9830322	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1719
Annotation	Unknow
Peak:m/z	Relative Intensity
153.2808838	0.01
155.0462952	0.03
171.1840515	0.21
173.0785828	0.43
189.1836395	0.03
191.0421143	100.00
192.0009460	0.05
305.2081909	0.01
341.3190918	0.03
419.5901489	0.01
471.1842651	0.02
534.7346191	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.8782
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1503143	0.07
244.7687378	0.06
247.0344543	0.16
249.4152069	0.01
272.9506531	1.38
274.1054993	0.03
289.0693970	2.77
305.9379272	0.02
311.3034058	0.03
387.0195312	1.70
402.9838867	17.04
430.3004150	0.03
497.4545898	0.06
500.9718018	0.58
501.9774780	0.03
515.0261841	0.70
516.8762817	100.00
517.5226440	0.56
546.2911987	0.02
554.1245117	0.06
560.0001221	0.02
562.0356445	0.03
566.3033447	0.03
576.3781128	0.05
584.0352173	0.34
585.0182495	0.38
586.0735474	0.02
586.9342041	0.02
589.3198853	0.02
600.2761841	0.05
602.6708374	0.02
607.6549683	0.04
620.2479248	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	871.1647
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9995117	0.07
249.0313263	0.17
250.4163513	0.07
254.0990601	0.42
254.8534546	0.07
258.0676880	0.23
268.0767822	0.57
269.1174011	0.10
272.2915649	0.68
276.2701111	0.04
279.9031982	0.05
283.2475586	0.22
284.1123352	0.13
285.0788879	0.09
288.3840332	0.05
289.3300781	0.18
290.2913208	0.31
292.9259949	0.30
297.2424927	0.11
300.1510925	0.23
304.0875854	0.07
306.3175049	0.26
307.1078491	0.16
308.5988770	0.24
309.2418823	0.26
315.1756287	0.50
316.2184448	0.12
317.0949402	0.14
319.0028076	0.41
320.3459473	0.19
321.0332947	0.03
322.2028198	0.28
323.0217896	0.52
326.9772339	0.10
328.2493286	0.32
333.1340027	0.05
333.9776917	0.09
335.1755981	0.51
336.1359253	0.83
337.0834656	0.50
340.0364075	0.24
341.1821289	0.38
345.3705750	0.15
350.9417725	0.03
354.3284302	0.14
359.3429565	0.62
360.3433228	0.11
361.3439026	0.12
363.2399902	0.52
364.0225830	0.08
366.1333618	0.45
367.2459717	0.06
371.2491455	0.49
372.2716675	0.09
373.8701172	0.27
375.0041504	0.10
378.2714539	0.15
379.0677490	0.61
380.1984253	1.37
381.1040649	0.31
385.2045898	6.61
386.2323608	0.56
389.0601807	0.33
392.5169678	0.07
397.2152100	0.05
398.3668213	1.58
399.3054810	0.32
403.2697144	0.09
404.8999023	0.48
405.5147705	0.04
407.1981201	0.11
410.0726318	1.37
410.9495850	0.14
415.1615601	1.97
416.0840454	0.16
423.2302856	5.78
424.2275391	1.25
428.4028931	0.14
429.3770142	0.05
433.6978760	0.39
434.3374634	0.35
441.2014160	2.69
442.3706055	0.17
449.1645508	5.04
450.5241699	0.32
451.3622437	0.35
456.2933960	0.28
466.6527710	5.89
467.3353882	27.82
468.1967163	4.51
476.2714844	0.05
485.2414551	100.00
486.2307129	15.50
493.4626465	0.04
499.1937866	0.09
501.2725220	0.26
502.3883057	0.04
503.1492920	0.15
504.2208252	0.05
512.3774414	0.29
513.4051514	0.30
517.1793823	0.13
518.6523438	0.16
519.3656616	4.01
520.3101807	0.87
529.1596680	1.46
530.1282959	0.25
539.5601807	0.07
547.3023682	0.26
549.4056396	0.07
557.5626831	0.07
573.4495239	0.18
576.5678101	0.20
587.3748169	0.11
591.1513672	0.91
592.1294556	0.36
617.3273315	0.57
621.3992310	0.50
635.2098999	2.98
636.3233032	1.09
640.1522827	0.11
641.3540649	0.23
643.9453735	0.10
653.3665161	0.45
654.2039185	0.05
658.2212524	8.15
659.3547974	1.82
661.2723999	1.50
662.4963989	0.08
679.2383423	6.69
680.1718140	1.87
697.1098022	0.37
697.9287109	0.07
709.3458862	0.13
711.3827515	0.11
727.4275513	0.10
739.8528442	0.23
751.4027100	0.40
757.4395142	0.16
786.5525513	0.51
787.2916870	0.07
788.2161255	0.05
793.2946167	0.21
795.3723755	0.22
803.6561279	0.10
807.3824463	0.17
808.3944702	0.20
809.5391235	0.18
810.5044556	0.14
827.1711426	0.26
828.7708740	0.05
835.4052734	0.68
836.4429932	0.63
837.3475952	0.31
838.3905640	0.05
851.6751099	0.08
853.2531738	12.67
854.2725830	4.35
854.9271240	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
97.02410889	0.93
105.058197	0.79
107.1011429	0.52
109.1626053	0.16
110.9243011	0.33
112.8064346	0.20
117.0040207	0.32
120.47435	0.40
122.9842834	0.73
125.1045837	0.85
129.1254272	0.52
132.9301453	1.76
135.0632629	0.51
136.9917603	1.33
139.0574188	0.69
141.0671997	0.41
142.8760986	0.47
145.1244507	1.35
148.95401	1.66
152.9477997	1.30
155.1537781	1.07
159.0728455	0.20
163.1069641	0.97
166.9411621	1.16
169.2468872	0.23
171.0500336	1.52
173.0485535	0.36
175.2036438	0.62
177.2612	0.26
181.0187073	2.43
182.7964172	1.06
186.9309387	0.30
191.0756836	0.58
192.9538269	0.67
194.9262695	3.42
195.7855835	0.72
197.0650024	1.92
198.0762024	1.01
198.9941101	0.47
205.0969543	0.80
211.2114258	2.16
212.9756165	2.30
215.192688	0.84
219.5153198	0.40
221.1411438	1.43
221.8159485	0.12
223.2601318	0.25
225.0441589	1.22
231.0426636	0.92
233.4154663	1.21
235.4381714	0.78
237.1460876	2.04
241.0490723	0.92
247.1783447	1.84
251.0320129	2.66
253.1531677	2.91
254.8799438	2.88
257.4790039	0.32
262.1965637	0.73
265.017395	6.59
267.1827393	4.23
267.8620911	1.04
269.0791626	0.91
269.9624023	0.47
275.2540894	11.90
275.9283142	0.13
280.0787354	0.33
281.8471069	0.53
283.236145	7.48
289.9886169	0.73
293.2028503	100.00
294.2906799	0.87
296.0761414	0.87
302.2420349	1.70
310.7110596	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	521.0988
Annotation	Unknow
Peak:m/z	Relative Intensity
161.9333344	0.07
245.0201569	0.02
255.2359009	0.07
256.3428955	0.02
290.3142090	0.05
297.1212769	0.10
313.3765259	0.07
317.1329956	0.02
328.3295288	0.06
342.9724121	0.26
371.2215576	0.03
400.5078735	0.17
405.0068970	0.01
418.2015991	1.25
428.2235107	0.74
446.0928955	100.00
446.7595215	0.14
459.3254395	0.09
464.3670044	0.04
467.1373291	0.02
469.1031494	0.02
474.7174683	0.04
485.2361450	0.71
503.1572266	18.60
503.7602539	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9903412	0.32
98.9895020	0.38
100.9886551	8.71
106.6502609	0.39
112.9423294	14.52
114.8984833	0.44
117.0643768	0.27
119.0603409	15.27
125.0309219	2.96
129.9157257	0.15
130.9646912	8.25
136.3449707	0.10
142.9984589	19.46
148.9678040	2.63
158.9242554	0.08
161.0309448	19.28
178.9439545	100.00
203.2632904	0.26
207.2548370	0.08
221.1991882	0.76
232.9420776	0.34
241.8571472	0.17
242.8481140	0.40
281.1173706	0.63
323.2301941	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	309.1327
Annotation	Lasiopulide
Peak:m/z	Relative Intensity
90.8628006	0.24
96.9187012	0.46
98.9517059	0.39
100.9111176	0.20
102.8775558	0.16
108.8728180	0.13
110.8732910	0.76
117.0404282	1.38
118.2165146	0.06
126.9109344	1.14
128.9135132	16.98
135.0713654	0.09
143.2637024	0.08
144.8750610	1.40
146.4106598	3.96
147.0156250	9.91
150.1435547	0.23
162.4921265	0.47
163.1398315	5.23
164.2164001	1.05
164.9746094	5.10
171.0523376	0.53
173.0217743	0.12
175.0124207	8.66
177.1561890	1.82
179.0273895	0.59
180.2086487	0.16
183.8744354	0.07
187.1429291	1.59
188.8800659	0.71
191.2296753	0.21
193.0986023	7.32
197.3677063	0.15
199.0182495	0.14
201.1475372	0.73
203.0371704	0.62
205.1116638	4.73
207.1841125	0.20
209.6823730	0.16
211.2988586	0.36
213.0367432	0.45
214.9642334	0.25
216.1034851	0.10
217.1447754	5.34
218.8769531	0.90
221.0574646	0.34
222.2276917	0.29
223.0469971	0.82
223.9684753	0.08
224.9295959	0.71
227.1761169	0.42
229.0448914	3.86
231.0936890	1.07
233.0238647	0.57
235.0729065	1.69
236.2830811	0.18
237.0101624	0.61
238.9008179	0.11
241.1989746	0.05
243.1058960	3.18
245.1098328	4.86
245.7114258	0.06
247.0476074	9.90
249.0067749	0.74
251.2136841	1.36
251.8931580	0.16
252.6557617	0.39
253.6136475	0.59
254.3181152	3.62
254.9841919	6.99
260.6135254	0.09
263.2223511	1.63
264.1201782	1.16
265.0002747	1.03
267.7930298	0.08
273.0897217	45.54
276.9855347	2.07
279.0478516	0.07
281.2960205	0.56
291.0971069	100.00
293.9737244	0.43
300.3079529	0.47
302.1605835	0.60
303.2200012	0.09
304.6621399	0.23
309.4351807	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.0615
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
86.8717194	0.08
88.9618530	0.14
100.9567413	0.05
106.6446381	0.10
110.9642487	0.21
112.9654541	0.20
114.8558655	0.05
118.9085236	0.57
124.9093475	0.05
129.1025543	0.14
143.0764771	0.90
161.0453186	2.01
179.0430145	100.00
188.9992676	0.03
207.1536865	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
101.0667725	0.29
106.6541061	0.93
108.8942566	0.55
118.803566	0.31
121.1996918	1.43
122.833931	0.20
125.0907135	0.80
128.8588867	0.89
131.892334	0.25
133.147583	0.42
134.9555817	0.38
139.0074158	1.64
141.0986328	0.23
146.9662628	0.24
153.1056824	0.73
157.1644897	0.29
159.2766418	0.29
164.8677216	1.39
167.0445099	1.12
169.190155	3.59
170.1035919	0.43
175.0499268	0.78
178.2054443	0.59
180.9088593	0.44
182.920929	3.30
193.2533417	0.63
195.237854	3.17
197.1420898	1.85
199.3881531	0.43
201.2326508	1.07
205.0260315	0.55
209.257019	1.24
211.1931458	3.18
213.0131836	2.02
215.1901855	1.30
216.2303162	0.96
219.0787354	0.22
221.1995544	0.47
223.2183838	0.87
225.1518555	7.76
227.1905518	0.27
229.4524231	0.35
231.4318848	0.48
233.5191345	0.20
234.9379272	0.22
235.9241333	1.07
237.4788513	1.13
239.2478333	3.13
241.1291809	0.84
247.182251	0.67
249.2719116	0.46
251.3886719	2.84
253.1245117	12.86
255.1375427	1.30
257.1942139	2.27
261.3256226	1.38
265.2104797	3.16
266.4118652	1.22
267.2137451	1.59
269.1895447	0.69
270.2740479	0.22
275.2597351	17.24
283.1502686	5.48
290.9699097	0.51
292.142395	3.63
293.2052612	100.00
294.3652344	1.57
295.0908203	0.45
301.8513184	1.83
302.8708801	0.52
310.4863892	3.47
311.2351685	0.49
321.0321655	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8640289	8.28
212.9559784	0.09
290.7589111	100.00
296.9003296	0.26
338.9919128	0.07
374.5606384	29.79
375.3263550	0.50
398.9480896	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	D-Galactofuranose
Peak:m/z	Relative Intensity
113.1667175	0.02
131.1869202	0.04
161.0258331	0.18
179.0006561	1.35
197.1196289	0.50
215.1182556	8.42
250.1378174	0.03
251.2137451	0.03
280.1823120	0.01
281.3149719	0.02
322.9304810	0.04
341.2315063	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.225
Annotation	Citbismine C
Peak:m/z	Relative Intensity
251.2372742	0.07
338.9532471	0.28
341.2294312	100.00
497.4334717	0.06
500.9408569	0.11
503.0632324	0.07
511.2587891	0.04
521.0902100	0.17
537.4372559	0.11
538.2802734	0.10
637.0000610	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1688
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
97.00737	0.43
99.16374207	0.10
123.1265564	0.28
134.8778076	0.17
138.2723389	0.18
156.1280212	0.72
161.9785004	0.20
163.0515442	0.08
170.0771027	3.56
171.0714722	0.56
183.0068359	100.00
184.0745544	13.76
185.1509857	0.26
191.3135986	0.56
197.0629425	17.21
198.0066833	10.41
199.0941162	0.10
203.3375244	0.22
209.1828918	0.15
211.1873779	2.16
212.0979309	2.83
212.9588928	0.12
217.1713867	0.60
225.2123413	2.29
226.0619202	1.48
227.263855	0.24
231.1492004	0.41
235.1589661	0.38
239.2014465	3.44
240.1153564	2.31
243.0955505	0.14
247.2623291	6.30
248.311554	2.61
249.4454041	1.97
250.3943481	0.26
253.1671143	2.53
254.1531982	0.87
255.203125	0.28
257.2158203	0.57
265.4127808	0.58
267.1087341	2.91
269.0059204	0.45
273.0462646	0.13
275.5366211	0.32
276.3445435	0.10
282.1334229	0.13
283.9177856	0.38
291.3899536	0.31
292.2568665	0.77
293.2341919	6.52
311.2036743	16.36
312.493988	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.1931
Annotation	Crepidiaside C
Peak:m/z	Relative Intensity
156.0811462	0.09
163.0133514	10.02
163.9018250	0.44
187.4732666	0.11
205.3136597	0.11
206.0696411	0.05
216.1684875	0.05
233.1629944	0.03
234.7516174	0.35
237.2864075	0.06
247.0507050	1.11
248.2089081	0.18
249.3978729	0.08
260.7682495	0.07
273.2667847	0.07
279.3162842	0.04
289.2563477	1.21
290.2937622	0.05
303.2097778	0.06
305.6349487	0.39
307.1012573	100.00
308.1319580	12.97
308.7589722	0.07
343.2592773	0.05
347.2493286	0.05
351.1370239	0.35
353.0426025	0.13
354.2468872	0.05
355.3350830	0.12
357.2982788	0.14
375.5187378	0.14
382.1008301	0.07
407.2687988	0.09
421.6989136	0.04
428.3134766	0.04
444.2470093	0.03
459.2960815	0.04
468.7491455	0.02
470.1940308	2.95
470.9512329	20.10
472.0545044	2.66
474.0033569	0.03
499.6884766	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2037
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
193.1748810	0.75
197.1386719	0.14
200.9809113	0.04
209.2481079	0.23
215.1093750	6.23
220.0245514	0.46
221.2093964	0.22
222.3041687	0.06
227.3688660	0.15
238.2611694	0.04
250.9164734	0.13
256.6643066	0.06
262.4214172	0.13
263.3304443	0.10
265.1635742	0.17
267.1944275	0.04
269.1753540	0.07
271.1122131	0.21
276.3017578	0.09
279.2282410	0.40
280.3686218	0.43
281.0820618	0.29
282.1026306	0.28
293.2224121	0.10
295.1974487	1.08
297.3428345	0.12
299.2120056	0.07
307.2825928	0.59
308.1510010	0.06
309.3456421	0.11
311.2601929	0.34
321.1255493	0.76
321.9898071	0.19
323.1182251	0.82
325.1775513	0.88
335.0772705	0.11
337.2387695	0.35
339.1259766	23.58
339.7790527	0.59
341.2647095	0.10
351.1624756	23.40
353.1863403	1.49
355.3623657	0.58
363.1967773	0.26
366.0890503	0.68
367.3429565	24.35
377.1899414	0.20
379.1575317	0.19
381.2332153	17.28
399.4458618	0.10
411.0280762	0.85
414.3938599	0.11
415.1600342	0.05
423.3387451	0.18
425.0186768	0.07
428.1755981	0.23
441.1761475	1.58
449.4326172	0.06
452.6807251	0.10
455.5221558	0.14
457.0774536	0.54
466.6834717	0.04
470.1167603	0.40
475.4687500	0.61
479.6952515	0.15
481.4795532	0.25
485.2977295	0.12
499.3575439	0.53
500.2224731	0.57
501.2628174	33.20
504.0996704	0.06
505.0807495	0.07
506.0952759	0.10
513.3180542	100.00
515.3610840	0.14
516.5881958	0.05
517.4315796	0.09
519.2307739	9.89
519.8428955	0.06
520.4903564	0.14
524.4651489	0.14
530.3753052	0.20
531.5827026	0.20
537.1929932	1.60
543.4514160	0.35
553.5734253	0.06
555.0640869	0.25
557.9653931	0.06
591.2756958	0.04
594.0301514	0.05
597.4198608	0.83
601.2302246	0.18
607.2753296	0.14
612.4693604	0.08
614.4494629	0.07
617.6215820	0.10
625.2421265	0.06
631.0390015	0.06
633.3887329	0.64
643.3061523	0.16
646.6376343	0.34
649.1703491	0.12
655.3656006	0.06
656.2704468	0.24
661.3246460	0.13
662.9497681	0.12
670.6162109	0.12
675.4376831	1.23
677.9750366	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.1069
Annotation	Unknow
Peak:m/z	Relative Intensity
179.2725830	0.05
197.1135254	0.68
198.1077271	0.31
201.2689362	0.29
213.2800903	0.17
215.1524048	0.64
219.1895905	0.10
220.8851013	0.06
229.0069275	0.08
230.9837952	1.48
232.0536804	0.45
235.1264648	0.07
238.1796875	0.36
239.0776672	0.18
244.5319061	0.07
249.2218475	1.01
251.1976166	0.05
253.1348724	0.24
257.0793762	0.18
257.9685059	0.07
269.3758545	0.06
271.4566040	0.05
272.8485107	0.06
276.5052490	0.16
278.0774231	0.17
282.3101807	0.06
284.1590576	0.52
288.3604736	0.26
297.4548340	0.17
305.6161499	0.16
308.2345886	0.28
311.9631348	0.22
313.9184265	0.09
315.1055908	0.10
315.9628906	0.35
320.1088257	0.06
322.3172607	1.54
323.1255493	0.25
326.1900635	0.81
329.5372925	0.18
330.3735962	0.14
332.5574341	0.08
334.2592773	0.14
340.1378174	0.57
341.0149536	1.64
342.1712036	0.83
344.2534180	1.90
348.1759033	0.26
350.3936768	0.06
358.0725708	0.21
359.2625122	1.12
360.2460938	2.24
361.2396240	0.18
363.2565918	0.14
364.1810913	0.16
366.2555542	3.08
368.2357788	0.08
369.1304932	0.08
374.0130005	1.20
376.3416138	0.13
378.2017212	23.13
381.2005615	0.06
382.1493530	0.44
383.0971680	0.05
384.1641235	0.95
388.4550781	0.05
392.2679443	0.30
398.1256714	0.08
400.0717163	1.90
402.1792603	0.10
404.0178223	0.19
410.1405640	7.43
412.5193481	0.50
413.4180298	0.03
414.3164062	0.09
415.4783936	0.06
418.2291260	0.47
421.9462891	0.06
423.4983521	0.30
426.1318359	1.51
428.2366943	3.35
438.2049561	0.11
439.0416260	0.18
444.2339478	6.43
447.1975708	0.16
449.3177490	0.06
450.2248535	0.22
451.5022583	0.23
453.0003052	0.11
455.2064819	0.06
462.2655640	11.62
463.3807983	0.14
464.4567871	0.14
465.2540283	0.12
467.1782837	0.09
469.3701172	0.37
470.2696533	0.83
471.1881714	0.11
475.2821655	0.22
477.2031860	0.35
479.5200806	0.08
483.2514648	0.40
485.2490234	0.10
487.3796997	0.51
488.2025146	0.48
489.2690430	0.27
490.6184692	0.06
495.2779541	6.33
497.9699097	0.19
499.2254028	0.05
501.3695068	0.31
502.2044067	0.69
503.2695923	0.14
505.5706177	0.06
507.3013306	3.31
513.2556763	3.99
516.2890015	2.27
518.1327515	1.16
519.2516479	4.65
521.1882935	2.10
524.7528687	0.18
527.3938599	0.26
529.2005615	5.00
531.3866577	0.14
539.2844849	15.24
544.0673218	0.06
545.2893066	1.21
547.3558960	11.34
555.1751709	4.66
557.2955322	13.64
560.4496460	0.11
562.9649048	0.10
573.2160034	100.00
573.8576660	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.9897919	0.30
99.0381622	0.09
100.9711914	6.02
105.8296356	0.67
106.8744354	0.61
112.9231720	18.83
114.9410629	1.31
118.8789291	14.88
124.9479218	2.46
129.2593689	0.07
130.9794922	6.69
143.0850677	16.96
149.0436096	3.09
161.0283203	21.41
171.5285187	0.42
172.9174347	0.29
179.0101929	100.00
184.8032837	0.25
190.8734741	0.14
221.0594788	0.24
241.1206055	0.08
242.0474854	0.11
255.2238770	0.13
281.0375977	3.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1288
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
95.9190674	0.05
96.5460815	0.02
97.1855087	0.12
107.1382141	0.03
108.9127808	0.19
111.0473480	1.93
120.8649597	0.03
123.3870392	0.03
125.1399994	0.02
127.1391449	0.06
135.1183319	0.06
136.9163818	0.01
138.2116699	0.39
139.0799713	0.15
147.2406006	0.22
151.0482025	0.29
153.0255890	100.00
153.9980927	0.06
155.3621368	0.05
161.0783386	0.86
167.1399994	0.05
173.1787872	0.05
175.2378235	0.13
176.1467133	0.07
177.1515198	0.16
179.3354340	0.04
186.0903931	0.13
191.0651093	0.03
199.2697449	0.08
201.1683197	2.15
203.1589050	0.41
204.1940613	1.30
209.0185089	0.03
217.2687836	0.10
219.2211456	28.27
220.9689789	0.03
226.1505280	0.03
227.2125549	0.09
229.9337006	0.02
233.0694122	0.11
235.0608368	0.06
244.0842743	1.23
245.1533051	1.25
246.4544525	0.05
248.7885742	0.05
250.9096069	0.03
263.3110657	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	225.0617
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
84.9413605	0.22
85.9766846	0.13
87.0028076	0.04
88.8208313	0.14
101.1070251	0.09
111.0296478	0.19
112.6167755	0.21
113.2749481	0.02
119.0437775	0.42
128.0327148	0.09
130.8824921	0.15
143.0754700	0.35
148.9700012	0.04
151.1094360	0.07
153.0429230	0.15
156.8769684	0.02
161.0577087	1.17
162.3507080	0.03
163.1783752	0.10
165.1467896	0.05
176.7782745	0.04
179.0285187	100.00
180.4687958	0.06
181.1202850	0.07
188.8167114	0.13
205.0255890	0.79
206.0061798	0.59
206.9941864	6.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2
Annotation	Kunzeaphlogin F
Peak:m/z	Relative Intensity
157.9416656	0.04
162.9323273	8.80
167.1712341	0.14
185.3219757	0.05
187.0222931	0.26
191.0045471	0.04
193.0514221	0.06
205.0445862	0.25
210.9781799	0.08
223.2044678	0.09
229.1983490	0.18
233.1553802	0.11
234.8944092	0.16
239.0567017	0.28
247.1901550	1.82
259.3197327	0.03
284.1142578	0.19
289.1703796	1.31
293.2658691	0.15
299.1680298	0.04
307.1293945	100.00
322.9667969	0.20
325.3023682	0.05
334.9747314	0.05
341.3750610	0.13
349.4296875	0.12
351.3161621	0.26
353.2058716	0.62
354.3116455	0.05
366.2492676	0.02
367.2026978	0.07
382.3026733	0.07
383.2501221	0.05
384.3143921	0.07
385.5557251	0.23
401.4157715	0.04
431.5791016	0.21
440.5736694	0.08
448.5226440	0.09
449.4392090	0.06
455.1926270	0.03
457.0928345	0.59
459.1255493	0.16
463.0755615	0.11
463.7459717	0.02
474.9617920	0.07
487.6066895	0.10
489.5232544	0.10
498.3176880	0.05
500.5879517	7.19
501.2315063	3.95
502.7025757	0.11
503.6394653	0.09
504.2407837	0.06
506.4567261	0.03
510.1805420	0.03
514.3765869	0.18
515.1909790	0.03
519.3886108	0.04
529.1419067	0.47
530.1748657	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
92.88664246	0.33
94.91616821	0.22
97.0354538	0.45
98.70930481	0.57
109.1199188	0.11
111.144104	0.24
119.1441956	0.18
123.1166916	0.13
131.0344543	0.42
162.2315826	0.39
169.0948639	0.42
170.0212097	7.38
170.7809296	0.24
183.0064087	100.00
184.0477142	16.20
184.8643646	0.67
195.2077332	0.48
197.0750122	37.83
198.0929565	10.29
199.2044983	0.37
211.1398621	1.63
212.1538086	2.99
223.5101929	0.45
225.0606689	2.26
226.1008606	3.39
233.2672424	0.18
239.281189	5.16
240.5314941	1.29
241.3779297	0.20
243.1669617	0.67
247.3500061	9.00
248.2075806	1.68
249.3297729	1.58
251.4389648	0.56
253.347168	1.26
254.236908	2.23
257.1505432	0.45
263.4816895	0.28
265.059021	0.53
267.2530823	4.56
268.1489868	0.27
269.4482117	0.30
275.1896973	0.70
281.2203674	0.78
283.3074951	0.57
292.730072	1.17
293.416626	12.09
311.294342	19.40
312.1273804	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1243
Annotation	Samaderolactone A
Peak:m/z	Relative Intensity
121.2483749	0.04
122.0234070	0.34
123.0505219	0.21
127.3399811	0.10
128.3053131	0.06
133.9496765	4.12
135.0304260	0.11
136.1238861	0.03
142.8444061	0.15
145.1841125	0.10
149.0141296	4.04
150.0944824	1.93
151.0649414	0.43
153.2032318	0.03
156.8523560	0.04
161.0770111	0.05
165.1024170	7.50
174.2316589	0.06
176.5732727	0.10
178.0661926	6.17
180.0245056	0.08
181.0474854	0.36
190.2170410	0.18
191.0101318	0.11
193.0334930	100.00
195.0311279	17.28
199.1230469	0.10
204.9872894	0.06
206.9053040	0.11
208.1448364	0.69
211.2208557	0.06
213.0195923	0.13
222.1853638	0.54
222.9358215	0.10
236.0955811	0.11
238.9868469	0.09
243.8427124	0.30
249.1043091	0.05
257.0923462	0.04
265.1172180	0.03
269.4519653	0.19
270.1204529	0.07
273.2939758	0.05
283.5108032	0.03
287.1626892	0.06
289.1234436	0.05
297.1754150	0.09
299.1965027	0.07
300.2299805	0.10
301.3913574	0.15
302.3107300	0.04
303.3884583	0.03
310.4234924	0.07
315.2498779	0.09
325.5819397	0.13
327.1156006	0.41
331.1105652	0.11
341.1948853	20.79
342.1932068	1.02
343.2931519	0.34
345.2551880	8.21
350.0772705	0.03
351.5079041	0.11
352.2106628	0.13
353.0662231	0.21
355.7815857	0.07
357.3790283	0.38
358.1153259	0.09
359.2284851	0.65
360.5159607	0.09
369.3415527	0.09
371.2082214	1.19
372.0266724	0.15
374.3380737	2.70
379.7873535	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	397.1291
Annotation	Isorhynchospermin
Peak:m/z	Relative Intensity
126.8339233	0.03
154.0383759	0.02
161.1415100	0.10
163.2405396	0.02
172.0728149	0.07
173.0122070	0.01
174.1858368	0.08
174.7963257	0.02
178.0070190	0.06
185.0597992	0.02
187.9718628	0.19
189.1500549	0.04
193.1654510	0.17
214.1367950	0.11
216.4469910	0.03
217.2176514	0.06
234.2886658	0.58
235.1538696	0.26
241.2149658	0.06
259.9122925	0.14
263.4063721	0.02
265.2982483	0.08
275.1362305	0.03
278.9707336	0.03
291.3299561	0.03
308.1877136	0.12
323.0902100	0.05
334.0627136	0.18
335.3156738	0.21
336.4697266	0.02
337.1301270	0.22
338.4367065	0.03
339.6137085	0.08
342.0527344	0.02
350.2122192	0.75
351.1823120	0.92
352.2922058	3.95
353.1924133	0.24
354.0938721	0.02
358.4670715	0.03
360.3590393	0.04
361.5875549	0.10
365.2152405	17.28
366.2363586	43.18
367.3017273	34.51
376.1395264	0.02
378.4748230	0.38
379.2504578	0.21
380.0831299	0.11
382.1959839	100.00
382.9742126	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1173
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
68.9676743	0.08
71.3002930	0.02
71.9320221	1.58
84.9721527	0.03
86.7924652	0.11
89.9762421	30.74
95.0484161	0.02
97.9137726	0.37
99.9343262	0.03
103.2157440	0.06
113.0463257	0.05
115.9429626	3.61
117.8957977	0.11
120.1147156	0.07
124.1437225	0.15
128.2266846	0.05
130.7694244	0.52
141.9030914	0.16
145.9881134	0.09
152.0616302	0.02
154.6811523	0.17
156.0734406	0.43
157.9613037	0.14
159.4390869	0.10
160.1900482	0.04
166.0830536	0.88
171.9163208	0.17
173.9932404	3.62
175.2056122	0.08
176.3263092	0.03
178.1018982	0.08
178.8656769	0.09
184.1144867	25.40
188.8338776	0.11
192.1659393	0.11
197.3874359	0.04
202.0316620	100.00
203.0579071	0.37
204.0440521	0.09
206.4191895	0.08
210.3920593	0.12
211.1612091	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	791.2537
Annotation	Unknow
Peak:m/z	Relative Intensity
226.2081909	0.05
229.2416534	0.19
229.9385986	0.07
231.0194702	0.09
239.2243500	0.13
244.9174500	0.18
255.2098999	0.04
256.0863037	0.05
257.2181396	0.41
259.1731873	0.05
278.9852600	0.09
280.0555420	0.06
280.8572693	0.18
283.4124451	0.09
289.1177063	1.03
295.1339111	0.11
297.1754761	0.06
301.1249390	1.66
302.6962280	0.32
308.1976929	0.22
313.5658875	0.07
315.2678833	2.35
317.0156860	0.09
327.2665100	0.05
329.0578613	0.24
351.0311890	0.07
362.8215942	0.07
365.3940430	0.06
369.8020020	0.23
387.1121826	0.17
388.3078003	0.09
390.3726807	0.06
403.1972656	0.12
405.2194824	0.11
412.5615845	0.07
417.3236084	0.56
429.5048828	0.39
431.5512695	0.18
435.5132446	0.25
447.3186646	0.77
449.2224121	0.19
459.3323364	0.86
467.3784180	0.11
475.4044189	0.14
477.2788086	0.37
483.3305054	0.12
487.3541260	2.15
489.4219360	0.15
491.3576050	0.09
493.4011230	0.09
501.3488770	1.19
510.7395630	0.07
521.4669800	0.29
525.3629150	1.41
533.2363892	0.11
536.5419922	0.08
543.5533447	0.10
549.5530396	0.75
552.5134888	0.07
564.5352173	0.04
567.3739624	8.95
569.6428833	0.11
575.5978394	0.20
581.1747437	0.14
584.5070190	0.10
585.4642334	0.20
593.4247437	1.75
595.7039185	0.08
596.6196899	0.52
601.2103271	0.22
609.6679077	0.10
611.2920532	100.00
611.9369507	0.41
617.3347778	0.06
627.3387451	0.40
628.4100342	0.13
629.2318726	0.18
639.3694458	6.56
641.8013306	0.18
643.9508667	0.14
645.5103760	0.29
659.1113281	0.06
662.1989136	0.07
667.1613770	0.25
671.2234497	0.10
681.4363403	0.36
709.5443726	0.04
714.8254395	0.34
718.5325317	0.07
719.3002319	0.07
732.5148315	0.06
743.5267334	0.26
744.5119019	0.05
745.5337524	0.19
746.4147339	0.32
747.3059082	0.14
757.5484009	0.05
759.4379883	0.43
760.5379639	0.16
773.2440186	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	183.0858
Annotation	Unknow
Peak:m/z	Relative Intensity
56.8959389	0.01
68.9411087	0.37
80.8955231	0.45
82.8152161	0.15
86.9953232	0.41
90.9437256	0.13
98.9361267	5.20
106.9138641	0.02
110.9799805	0.47
116.9542847	3.09
123.0502014	0.01
128.9447632	13.52
134.0256348	0.04
146.9492188	32.48
164.9757233	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.2957
Annotation	Clerodendrin H
Peak:m/z	Relative Intensity
337.0474854	7.26
401.0266113	6.24
433.1961060	3.43
452.4095459	14.92
478.3757935	13.59
496.4401245	7.10
510.3185425	57.32
556.3766479	10.02
617.2340698	10.03
631.4683228	4.91
635.4814453	100.00
648.0629272	8.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.2184
Annotation	Unknow
Peak:m/z	Relative Intensity
181.1539917	0.39
205.2280884	0.08
207.2168274	0.04
222.2327271	0.14
235.1889191	0.06
267.3761597	0.03
304.2994385	0.04
309.0836792	0.10
315.3385620	0.07
340.2109375	0.06
355.1141968	0.02
356.1995239	0.06
364.0934448	0.12
369.1810913	0.10
371.2663574	0.89
373.4735718	0.03
374.5203857	0.06
383.2584229	0.03
399.2098389	0.03
405.2054443	0.07
415.2572632	0.03
432.2694702	0.25
433.2448730	0.09
445.7399902	0.09
447.2332153	100.00
447.8390503	0.28
489.3622437	0.13
511.4317017	0.15
533.3395996	0.23
537.4317017	0.04
553.2221069	0.03
562.5604858	0.09
563.3974609	0.15
564.2222290	0.06
565.4458618	0.13
572.1145630	0.09
573.7582397	0.23
575.5181885	0.11
577.1387329	0.23
590.1660156	0.10
591.2385254	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
80.94764709	0.71
92.94239807	0.50
94.91665649	1.84
103.0085754	2.21
104.9220428	0.37
106.8816528	0.42
108.9774475	0.63
119.0824738	1.25
121.0413055	0.51
124.2228088	0.56
128.9689789	6.95
130.0288544	1.34
132.8479309	0.64
134.8325348	1.87
145.082901	0.51
146.777298	1.52
148.7888947	0.65
151.022049	100.00
152.0930634	4.33
155.0870819	0.35
157.2108612	1.73
160.9715729	0.41
164.8004608	0.54
166.2111511	1.32
167.0751495	0.29
168.9218903	2.26
177.009079	0.94
179.1323242	1.53
181.0413208	0.75
182.2977142	0.54
183.2695923	1.09
185.1369934	2.41
190.0219574	1.46
193.0811615	0.78
195.0366364	0.95
197.1633759	11.34
198.3279572	0.84
207.0977783	1.83
209.9996185	0.44
211.2098541	2.05
217.0929718	1.84
221.1877747	2.48
225.0918274	14.98
235.2036133	9.43
238.178772	25.16
239.2060547	2.74
243.7075195	0.99
249.0848389	0.69
251.0554657	3.96
253.0919189	99.96
254.1698761	3.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1666
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
210.9766235	0.01
215.1563873	0.02
219.1066742	0.04
224.1488037	0.02
229.0813446	0.37
239.2218475	0.02
246.8091736	0.02
248.0521088	0.02
251.1005554	0.03
265.1058044	0.07
267.1247253	0.03
269.0376282	0.08
271.0755005	0.03
277.1059570	0.02
292.2516785	0.01
293.0908813	0.22
295.1026611	0.17
306.1530457	0.04
307.2409363	0.04
311.1762085	0.04
313.2789612	0.10
319.1649170	0.03
321.2151489	4.63
337.2276001	0.17
338.1559753	0.20
339.1893921	5.82
351.2702026	0.05
352.3381958	0.03
353.1442261	0.03
355.0065918	0.01
357.0900269	0.14
359.3243408	0.14
367.4919434	0.07
368.3710327	0.01
374.4194946	0.03
375.3224487	0.12
376.1881104	0.01
392.3551636	0.03
397.3539429	0.02
403.2729492	0.24
411.2584229	0.01
417.2117310	0.02
423.1779175	0.05
433.1782837	0.02
439.4931030	0.14
441.3121338	0.04
442.3472900	0.01
463.5712891	0.02
469.1535645	0.67
479.3198853	0.01
484.4996338	0.01
485.5867310	0.13
487.2322998	0.22
488.7035522	0.02
495.2412109	0.35
496.1044922	0.02
504.4682007	0.03
505.3539429	0.09
508.6276245	0.04
511.5175781	0.22
513.2192383	100.00
513.8421021	0.33
520.2200317	0.02
521.1878662	0.02
524.5907593	0.03
527.3762817	0.03
529.0979004	0.02
530.0627441	0.12
531.1353760	0.50
534.9553833	0.05
537.3662720	0.03
543.4512329	0.01
549.2050171	0.68
550.8430786	0.19
557.1207275	0.05
565.2832031	0.01
567.5360107	0.08
571.3247681	0.06
575.3700562	0.03
585.8633423	0.07
590.3190918	0.01
595.3219604	0.20
608.4600220	0.86
609.2596436	0.07
615.2271118	0.10
617.2322388	0.18
624.5564575	0.05
627.5211792	0.01
639.1408081	0.06
642.4168091	0.01
645.2218628	0.03
647.4562988	0.03
660.4106445	0.02
661.2363892	0.09
662.0797729	0.02
670.3251343	0.03
671.3615723	0.14
675.2641602	0.02
682.9155884	0.02
687.2489624	0.29
688.8517456	0.03
696.3714600	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.1928
Annotation	Sucrose octaacetate
Peak:m/z	Relative Intensity
191.1938324	1.54
203.0623016	0.13
227.2274323	0.10
230.2791901	0.04
233.2204285	0.04
273.3316956	0.09
306.0374146	0.11
308.3612061	0.08
321.4341431	0.05
323.3280029	2.01
337.4618530	0.07
341.1665955	0.37
353.2133789	12.66
369.2763672	0.15
377.1347046	0.30
380.1913452	0.05
390.2411499	0.03
392.5436401	0.04
395.2214966	1.19
405.2327271	0.11
407.4424438	0.07
421.2914429	0.03
425.2580566	0.22
437.4613647	0.10
440.2369995	0.12
441.2398682	0.22
442.2297974	0.10
453.1881104	0.12
455.0125122	0.24
458.5274658	0.10
461.4766235	0.06
467.4258423	0.15
468.3269653	0.63
469.0615234	0.09
469.6923218	0.06
476.4963379	0.16
477.2451172	0.29
479.2673340	0.05
485.2823486	0.88
486.2375488	1.20
487.2956543	0.30
496.2285156	0.17
497.4146118	0.54
501.1783447	0.76
502.2847290	1.46
503.3115234	0.43
515.3372192	100.00
519.3397827	6.55
520.2356567	16.15
521.2090454	13.22
521.9046021	0.09
523.1533813	0.15
526.8019409	0.05
539.2797852	0.05
547.3903198	0.24
554.6903687	0.04
557.3063354	2.27
569.2401733	0.21
587.2177734	0.52
597.5573730	0.17
598.3047485	0.05
602.3987427	0.09
617.1331177	0.25
631.1373901	0.04
632.3012085	0.48
633.2582397	0.70
640.3908081	0.17
644.6588745	0.09
658.3953247	1.32
659.4575806	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	751.1372
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1686707	0.13
227.9858704	0.02
229.1989899	0.04
231.0915222	0.08
235.2620544	0.05
238.4412231	0.10
244.0567627	0.16
245.3696136	0.20
251.3855438	0.06
254.2390594	0.39
255.4768829	0.05
265.7255859	0.04
269.3091431	0.03
272.0649414	0.03
276.3309631	0.04
278.2966614	0.05
281.1890259	0.07
283.9541321	0.21
285.3496704	0.04
286.3386841	0.07
288.3316956	0.51
296.1720581	0.03
300.0541687	0.04
305.0305786	0.05
306.2214966	0.53
307.1784058	0.27
322.2929382	0.58
323.3302917	0.52
327.9235229	0.05
331.4558716	0.19
339.3612366	0.04
340.1512451	0.13
341.1394043	0.44
342.2916260	0.09
346.0297241	0.06
347.9077148	0.07
351.2968140	0.20
354.2670898	0.19
356.2816162	0.03
357.1272278	0.64
358.3280029	0.07
359.1799316	0.08
360.2329102	0.11
361.4703369	0.05
365.3705750	0.20
366.2473145	0.75
367.3319092	0.06
374.0238037	0.04
375.2427368	2.08
376.3833008	0.19
378.4484253	0.20
379.2833252	0.17
382.4561157	0.05
383.4721069	0.12
385.3538818	0.22
386.4235840	0.04
390.2333984	0.12
391.3021851	0.03
392.3435059	0.08
399.4354248	0.03
400.1224976	0.30
407.1365356	0.08
409.1843262	2.90
410.1480713	3.54
411.1135864	0.56
412.0977783	0.05
417.3255615	0.12
418.1979370	0.13
420.2666016	0.03
424.2268066	0.05
425.4012451	0.24
426.1741943	0.37
427.2326050	0.03
428.1376343	0.11
429.2445679	0.05
430.2099609	0.04
442.3505249	0.52
443.3996582	0.28
444.2927856	1.49
445.1633301	0.12
447.4306030	0.03
451.4706421	0.03
452.4714355	0.12
457.5177002	0.14
458.4323730	0.18
462.3873901	0.33
464.5789185	0.03
467.3681641	0.03
468.2669678	0.39
470.4102783	0.21
471.4295044	0.05
486.3269653	4.02
487.3677979	1.07
488.5335083	0.03
493.0715332	0.03
501.2291260	0.21
502.3612061	0.25
504.2932129	6.10
505.2160034	1.42
512.4451904	0.08
520.3289185	4.99
521.2847900	1.03
522.3065796	0.13
523.6906738	0.05
524.6126709	0.21
526.3198242	0.03
529.3609619	0.24
538.3128662	46.09
539.3181152	8.38
540.4179688	0.06
542.3269653	0.06
543.9860229	0.04
544.7813110	0.09
546.4438477	0.26
552.4376831	0.26
553.1705322	0.05
554.3270874	0.18
555.2265015	0.03
559.6336670	0.13
560.4512939	0.10
561.3425293	0.09
564.5695190	0.04
566.3627319	0.07
568.7060547	0.04
569.5518799	0.06
571.4559937	0.05
573.2102661	1.74
574.1039429	0.70
577.4307861	0.17
578.4163208	0.21
580.3638916	0.35
586.4956665	0.17
588.5967407	0.09
589.2979126	0.11
591.2373657	0.03
592.3850098	0.09
593.3311157	0.16
596.3746948	0.11
597.3756714	0.03
598.3485718	0.08
599.2878418	0.27
603.2023926	0.34
604.3217163	0.41
607.3804321	0.16
608.3148193	0.07
611.2540283	0.24
612.4359741	0.64
614.0242920	0.19
621.3147583	0.50
622.5970459	0.10
623.6652222	0.18
624.3794556	0.05
625.4827271	0.33
629.1884766	0.23
630.2871704	1.44
631.2149048	0.69
632.3049927	0.14
633.2991333	0.14
637.2016602	1.71
638.3777466	0.26
639.5212402	0.37
640.2739258	0.25
642.3667603	1.68
643.3482056	0.30
645.4357300	0.10
646.3403931	0.09
647.1624146	0.44
649.1738281	0.13
650.2259521	0.08
653.2445679	0.03
655.3200684	7.02
656.3701172	1.94
658.9440918	0.06
659.5952759	0.05
663.1954956	0.29
664.6652832	0.20
665.4454956	0.79
666.0850220	0.14
666.8643188	0.07
668.1691284	0.12
669.2002563	0.49
670.4652100	0.06
671.4406738	0.26
673.2944336	4.14
674.3741455	1.66
676.2448120	0.49
681.2858887	6.30
682.3942261	2.20
683.4067993	0.55
687.1891479	0.69
688.5050659	0.40
689.3837280	2.49
690.2557983	1.40
697.6448364	0.20
699.2763062	22.03
700.3054810	7.79
700.9218750	0.03
705.4857788	0.05
707.2995605	24.16
708.2798462	6.15
708.9243164	0.02
715.2171631	3.34
716.1930542	1.21
717.3069458	18.87
718.3917847	5.10
720.2352905	0.12
723.1091919	0.02
731.0921631	0.03
733.2357788	100.00
734.2754517	25.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
97.06529236	2.28
105.1605988	1.69
132.9699707	2.04
145.1139069	1.56
149.0527191	2.76
150.2719879	4.23
157.2330322	3.56
163.0950928	8.87
163.8135681	1.44
167.2263184	1.80
168.8549347	1.32
173.0175323	1.46
177.1356659	1.32
179.3852386	1.32
180.0346069	1.08
181.3119965	2.52
183.1282196	4.43
191.1177216	1.44
193.0952911	4.59
194.2125244	4.80
195.2762451	0.96
197.1588287	2.29
202.8672028	2.40
205.1843567	2.04
207.1267395	38.51
208.4707947	10.65
209.173172	16.07
221.9469757	9.92
223.1634827	22.02
231.0345459	6.24
233.2815094	11.61
251.0799561	100.00
252.1518707	16.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
85.0049744	2.56
86.9891052	1.28
88.8774567	3.23
95.0239258	0.30
99.0254288	0.14
100.9180450	5.26
104.8991699	0.14
113.0076218	5.43
114.9906540	0.22
118.9895172	3.97
124.9893265	1.47
126.9017334	2.41
128.9880981	1.17
130.9790344	100.00
143.0860901	2.10
144.8811646	0.67
148.8281250	1.01
155.1526184	0.20
157.0322418	0.14
159.1544495	0.38
160.9390869	1.53
163.8230286	0.25
168.9268494	0.06
173.1242065	8.18
178.9550781	1.60
185.0244141	1.06
203.1460266	1.28
215.3146667	0.20
226.7257996	0.09
229.1641235	0.14
233.0714111	1.05
247.2153625	0.06
249.2966309	0.09
274.3282776	0.05
275.3058472	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	948.2407
Annotation	Unknow
Peak:m/z	Relative Intensity
385.1554565	0.05
489.3812866	0.13
635.1544189	0.04
756.5377808	0.05
860.1401978	0.09
892.8396606	0.05
893.5621948	0.08
913.2319336	0.10
947.8640747	0.05
1867.8621830	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
156.9339905	0.10
158.9270172	3.71
160.0317688	1.44
160.9580994	1.44
170.9803772	0.15
199.0381927	0.26
200.2194366	0.04
217.1439972	0.46
217.9860687	0.21
219.2082367	0.05
229.1189880	0.75
230.1160583	0.27
230.9953613	0.22
273.0074158	49.46
274.0175781	33.62
275.0866394	26.08
344.1807251	0.27
386.9773560	55.54
388.0151978	100.00
389.0212097	95.36
428.0662537	0.59
429.3850403	0.06
447.1403503	0.10
456.4843445	0.21
458.8707886	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	384.1141
Annotation	Succinyladenosine
Peak:m/z	Relative Intensity
122.7994308	0.03
128.9249878	0.02
130.1892853	0.07
135.9591675	0.17
144.1413574	0.04
148.3271332	0.08
158.9989929	0.05
162.0796509	0.15
170.1446381	0.07
178.9147339	0.16
188.0166931	0.06
204.3052216	0.04
209.0856476	0.11
210.2713318	0.07
211.2751617	0.04
216.0451050	0.12
220.1977692	0.08
221.2834015	0.03
222.0647430	0.28
226.1940308	0.04
233.0519104	0.06
233.9654236	0.42
235.0538940	0.19
243.2856445	0.08
249.0266113	0.07
252.1642761	100.00
253.1302185	0.16
276.2384033	0.05
279.2018433	0.08
280.6688232	0.19
281.9561157	0.14
286.1414490	0.06
288.2464905	0.14
293.9667053	0.48
294.8336182	0.12
296.2903442	0.03
297.1152649	0.33
302.8152466	0.21
306.1124878	0.04
322.2947388	0.06
323.1831360	0.17
324.4340210	0.07
325.2520142	0.23
331.1705627	0.14
336.1281128	0.15
338.1790161	0.03
339.2871094	0.25
342.4436951	0.09
343.3109436	0.13
347.1782837	0.15
348.4961548	0.05
349.4262085	0.09
354.1541138	0.06
355.1676941	0.04
356.2994080	0.04
365.3935852	0.23
366.2830811	0.85
367.3963928	0.06
374.3390503	0.20
375.1321411	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	707.1822
Annotation	Patuletin 3-rhamnoside-7-(3''',4'''-diacetylrhamnoside)
Peak:m/z	Relative Intensity
204.0232391	0.01
212.1573029	0.00
226.3309479	0.00
229.1675415	0.01
230.4432678	0.00
231.2798157	0.02
236.1684265	0.00
270.3823547	0.00
271.4147949	0.00
277.4506226	0.01
295.5202332	0.00
297.2297974	0.01
311.3337402	0.00
313.3449097	0.01
314.2369385	0.01
316.4788208	0.00
321.4977417	0.01
322.4779053	0.01
323.3363647	0.01
324.5699463	0.01
336.7393188	0.00
339.3463745	0.03
340.3628540	0.06
341.2743530	0.04
342.1325073	0.00
351.7097778	0.01
353.2548218	100.00
354.1409912	14.57
355.2260742	0.09
356.3740234	0.00
360.3131104	0.02
402.9884033	0.01
404.1993408	0.02
405.1160278	0.01
454.6833496	0.01
463.1156616	0.00
468.6205444	0.00
469.8417358	0.01
471.2694702	0.00
472.4669189	0.01
475.0294800	0.00
482.1308594	0.01
486.1538696	0.01
488.1265259	0.01
489.3723145	0.01
494.3024292	0.01
495.0780029	0.01
497.4748535	0.00
503.1799316	0.00
513.2343140	0.07
514.2490845	0.18
515.2598267	0.23
516.1647949	0.02
517.3296509	0.00
526.0044556	0.00
527.4276123	0.01
533.0657349	0.01
533.6658936	0.01
537.1828003	0.03
538.6292114	0.00
551.3333740	0.05
551.9668579	0.01
589.5448608	0.00
597.1867065	0.03
603.1820068	0.00
623.8745728	0.00
626.5193481	0.01
627.5146484	0.00
631.2230835	0.00
640.5330811	0.00
645.4170532	0.00
655.3889771	0.01
656.2392578	0.00
662.0982056	0.00
663.4026489	0.01
671.1586304	0.01
673.3405151	0.01
681.4693604	0.01
685.8132324	0.02
689.2467651	0.02
698.9177856	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2213
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
105.1828461	0.33
109.1829529	0.94
112.9260712	0.35
115.1510239	0.79
121.1698456	0.68
123.2680206	0.29
125.0514374	0.19
127.0154572	0.15
129.043869	0.86
132.881958	0.78
136.8953552	1.01
138.9495087	1.18
143.0861206	0.32
147.0571594	0.64
149.1277313	0.22
152.9752808	0.54
163.1102295	1.77
167.1596985	0.19
168.9642334	1.17
171.1293793	0.84
177.2759399	0.25
179.4596863	0.33
181.1897888	4.09
183.141098	0.63
184.1984253	0.66
184.9347382	1.00
190.1267395	0.20
191.1053619	0.50
193.122345	0.65
195.3126221	1.75
197.0955505	3.12
199.199234	1.21
200.9651337	0.38
205.1158142	0.80
209.1973877	0.82
211.2100525	1.20
213.2279663	1.15
215.0080566	1.30
219.2976074	0.37
221.1270142	0.19
223.1855774	0.87
225.2527771	2.03
227.1105347	2.57
233.4373474	0.91
235.2627563	1.85
236.1273499	0.44
237.1951904	1.78
239.223877	2.57
243.1437378	0.45
247.4133911	2.02
248.2261658	1.12
249.2088318	1.38
251.1293945	3.38
253.1144409	8.25
255.2033997	1.40
257.2214355	0.21
265.2536011	1.65
267.110199	1.37
268.0128479	0.37
269.28479	3.15
269.9660339	0.19
275.2357178	12.86
276.2158813	0.76
277.130249	1.08
281.2243652	0.39
283.3326111	3.56
293.2017212	100.00
293.9692993	1.21
300.9724731	0.57
302.2946777	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	443.1562
Annotation	Sibiricaphenone
Peak:m/z	Relative Intensity
133.8202057	0.07
162.0760651	0.09
187.2021790	0.04
217.0531921	0.37
235.2093506	100.00
259.0375671	0.16
281.4201355	0.10
284.9832153	0.04
289.0911560	0.06
295.3132629	0.04
300.1650085	0.03
315.2848816	0.11
351.2191772	0.12
360.8247070	0.08
367.0606384	0.13
369.3419495	0.24
381.3299561	0.06
383.2877502	0.14
396.6647034	2.68
397.2892761	3.82
399.4023132	0.17
401.0919189	0.12
404.1626282	0.11
407.2538452	0.08
423.2243958	0.11
425.4606628	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	751.1339
Annotation	Unknow
Peak:m/z	Relative Intensity
223.0716858	0.25
231.0844421	0.70
235.1334991	0.06
253.8815918	0.11
260.3074036	0.21
265.1644897	3.75
288.2296143	0.04
289.0833740	0.31
290.1701050	0.12
291.8373413	0.08
306.0072327	0.10
315.1231995	0.08
316.2467651	0.09
317.0751343	0.24
334.0803833	0.32
339.6889038	0.21
340.3525391	3.56
343.1340332	0.44
346.3783569	0.07
354.2028198	0.39
355.9727783	0.14
359.7127075	0.24
364.0411377	0.17
372.2283325	0.46
379.1220093	0.07
394.3137207	1.16
400.1446533	2.00
402.1983032	0.35
409.1597290	1.12
412.2770386	1.61
418.2858887	0.08
419.8587036	0.12
443.0858765	0.47
445.3641357	0.08
446.3217163	0.30
457.2047729	0.29
461.1036987	0.16
462.1947632	0.28
463.1189575	0.75
471.0969238	0.37
475.0999756	2.59
485.3634644	0.27
492.1688843	0.07
493.0764771	0.11
501.2032471	0.24
502.3260498	0.16
503.3742065	0.49
517.5621338	0.06
519.2196045	1.68
520.2982788	4.66
521.3304443	0.28
527.2315063	0.13
528.9404907	0.18
529.5747681	0.82
538.3306885	2.43
539.2775879	0.17
545.4552002	0.08
547.2088013	7.24
553.7257080	0.30
560.5088501	0.27
572.9059448	0.40
575.3228149	0.86
577.3851929	0.32
580.5182495	0.15
583.5526733	0.36
586.2911987	0.49
594.3100586	0.09
596.1827393	0.21
602.4208374	0.16
603.4774780	0.49
604.3748169	1.33
614.3206787	0.43
622.2556763	5.27
629.3753052	0.17
630.2085571	2.35
631.3458252	0.15
632.1573486	0.80
640.4044800	0.36
643.2028198	0.32
648.1063843	9.39
658.1694336	17.25
660.2709351	0.40
671.1940308	0.38
674.0516968	0.14
676.1997070	57.73
676.8356323	0.21
687.1640015	0.72
688.1757812	0.50
689.2440796	7.86
705.1332397	3.12
706.2497559	1.92
707.3981934	0.10
715.3271484	2.26
723.2857666	2.38
731.1998901	0.44
733.2140503	100.00
733.9766846	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	710.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.5616608	0.19
290.7906494	2.86
374.6516724	1.43
426.8726196	0.06
458.0490112	0.96
458.6885376	15.56
489.5619507	0.11
517.0494995	0.12
526.8686523	0.05
542.5447388	100.00
543.2568970	0.24
544.6687622	0.04
548.3001099	0.09
558.9929810	0.06
590.7448120	0.07
600.4392700	0.32
610.6915894	0.04
623.7859497	0.06
626.0049438	4.37
626.6162720	18.92
640.6899414	0.05
641.6710205	0.07
664.0187378	0.78
664.7398071	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
76.85462952	0.89
80.95702362	0.72
90.94795227	1.61
92.99326324	1.31
95.08640289	6.39
97.20927429	1.68
99.24275208	2.26
105.1189575	3.45
108.9837036	8.14
110.9890137	3.30
118.8296967	1.63
121.0482788	3.36
123.0763245	4.31
126.973587	2.80
129.1587677	4.34
135.0169983	9.09
135.9054413	1.21
137.0625	13.08
141.0493622	3.46
143.2734833	2.67
147.1712341	5.63
149.2586823	1.69
151.0648956	90.22
152.1261749	5.54
152.8453217	6.83
154.2835388	5.16
155.1995697	5.15
159.0409393	2.01
161.3623962	3.37
165.2402954	10.02
167.1705933	2.16
169.1374207	5.52
170.9229736	6.82
175.1900482	7.91
177.1079865	8.61
177.9760437	3.78
179.029892	3.19
182.1979065	2.91
183.0961914	2.72
184.3770905	0.72
185.072525	1.37
193.2414703	4.85
193.8970337	2.25
195.0750122	17.46
196.9419708	3.92
198.0035553	0.82
203.0921783	2.69
206.9605865	7.38
209.2625885	2.52
211.1989594	7.28
211.8536072	0.38
217.2502899	21.19
220.9990692	7.85
222.7298126	1.98
225.1618805	17.86
234.58638	10.56
235.2249298	61.15
237.1004181	2.59
238.186203	18.06
239.3596039	1.68
244.5231781	6.34
253.0967865	100.00
254.3003998	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9426575	0.47
296.8107910	7.60
380.6346436	29.16
381.3341675	0.05
396.6940308	0.16
424.4337158	0.08
461.5261230	0.08
462.8571777	0.17
464.6150513	54.75
491.4207153	0.24
540.9246826	0.05
548.5913086	100.00
586.0987549	0.23
613.7036133	0.11
614.9417725	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	716.1827
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9326324	0.03
258.1066284	0.04
264.3464661	0.03
277.2136841	0.05
278.3549805	0.05
290.1110229	0.04
305.3095703	0.10
311.2060547	0.19
328.1482239	0.10
329.2439880	0.11
347.3786316	0.03
349.1030273	0.04
359.2185669	0.03
360.2734985	0.06
370.7934570	0.08
371.5051270	0.07
373.7370605	0.11
374.3574219	0.08
403.2052612	0.29
404.5509644	0.03
408.0249634	0.17
421.3413696	0.12
422.3905029	0.02
423.4697876	0.05
426.4024048	0.66
437.2642212	0.05
451.3397217	0.03
452.2989502	1.18
452.9763794	0.04
454.2174683	0.38
464.2734375	0.02
470.2023926	0.11
479.4456177	0.06
480.4089966	1.74
495.2710571	0.15
496.2072144	0.09
497.2454834	0.07
498.2926025	0.59
501.3425293	0.05
502.3480225	0.08
503.4035034	0.12
506.2650757	100.00
509.4547119	0.06
512.0562744	0.03
513.4841919	0.10
519.3412476	0.28
524.2362671	9.33
524.9268799	0.02
535.3432617	0.17
537.9998169	0.07
542.2474976	0.38
546.9201050	0.10
551.2828979	0.04
553.1687622	0.34
554.3958130	0.08
559.4995117	0.06
563.4851074	0.02
565.2374878	0.03
569.0941772	0.08
580.9216309	0.05
585.3025513	0.05
587.5302734	0.16
589.1796875	0.15
598.1223145	0.03
598.7887573	0.06
600.3930664	0.07
602.2789307	0.12
610.7098999	0.09
628.5270996	0.05
641.9230957	0.07
644.4525146	0.30
651.2327271	0.07
653.2456665	0.09
654.4420776	2.46
656.2575073	0.05
667.5474854	0.11
669.0394897	0.04
669.9039307	0.28
672.4332275	10.13
679.3550415	0.08
687.4940796	0.17
697.6704102	0.70
698.3764038	1.68
700.4895630	0.06
701.3407593	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1487
Annotation	Tetrahydropentoxyline
Peak:m/z	Relative Intensity
115.1029968	0.04
115.9339218	0.06
117.0371475	0.08
126.0559540	0.02
127.0749969	0.02
129.9617310	0.02
132.1264801	0.06
144.0832214	0.78
145.0987549	0.17
146.0921021	0.39
156.1967621	0.18
159.0303955	0.10
169.9406281	0.07
170.9604492	0.06
172.1280518	0.03
173.0825348	0.15
174.0248413	0.02
174.9406433	0.05
176.6922913	0.02
180.1899567	0.04
184.0835266	0.02
185.1567688	0.18
188.1118774	24.33
191.9259644	0.04
201.0184631	0.28
202.1743774	1.16
203.0613098	0.08
205.0463867	100.00
206.1284485	0.03
207.0762329	0.10
215.1436157	1.46
217.1655273	1.55
219.1268311	0.17
221.9803467	0.02
229.1540222	11.20
230.2012329	3.39
231.1134644	0.03
233.1575012	0.14
240.1526489	0.08
242.0455933	0.04
244.0677185	0.05
247.0669861	27.70
247.6762390	0.11
249.3290100	0.03
251.3542786	0.14
254.1840820	1.12
257.1592712	0.10
258.0392151	0.63
259.0760193	0.21
266.1141663	0.03
267.1926575	0.02
268.1923828	0.08
271.1924438	4.86
276.0336609	3.46
277.1647034	0.21
283.1871948	1.21
284.0661011	0.44
285.2169495	0.30
294.1744690	0.72
295.1647034	0.27
296.2132568	1.41
301.0416565	1.82
303.3286133	0.06
304.0896301	0.02
306.9115601	0.12
308.7494507	0.08
313.1765442	3.76
314.2302856	1.14
321.2524414	0.68
322.1243896	0.03
323.1566772	0.19
325.3619995	0.02
327.4799805	0.10
331.1855469	10.38
332.1929321	2.89
337.3466797	0.08
339.0913696	0.11
349.1939392	29.78
350.1826477	9.44
350.8468933	0.02
366.4737854	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1718
Annotation	Unknow
Peak:m/z	Relative Intensity
107.9627991	0.06
109.1233521	0.15
113.0650787	0.18
113.9786377	0.72
124.9379349	0.09
131.1531677	0.22
134.1728058	0.22
136.0382080	0.13
137.9349060	0.13
143.1187592	0.10
144.1865845	0.05
150.2403412	0.09
151.1455383	0.05
151.7725677	0.10
153.1122284	0.29
163.2793274	0.05
165.0607452	0.53
169.2175446	0.12
170.0417175	0.22
173.0869751	0.07
176.0962067	0.04
177.1719818	0.07
180.0502930	0.09
181.1101837	0.29
184.1434479	0.09
186.1848907	0.39
189.2987366	0.11
190.9723816	0.09
197.1356812	0.24
201.1045837	2.78
203.1700287	1.14
204.2464752	0.03
205.1090546	2.10
215.0564117	0.51
218.3319702	0.26
219.2447815	4.23
227.2969360	0.18
229.1411133	0.47
244.1109924	10.25
245.1990051	1.54
247.1564026	0.27
262.3123169	8.32
267.2952576	0.05
275.1813049	0.32
280.3022461	0.23
281.3891602	0.13
287.1578369	0.26
290.3790588	0.22
291.4097290	0.24
297.9775696	0.25
299.2865295	0.19
315.3001709	0.81
316.3585510	0.28
317.1877441	0.15
318.2520447	1.99
330.9956665	0.35
331.6013794	0.09
333.3186951	4.71
341.2470398	1.05
342.6167297	0.47
344.1752014	0.05
345.1929321	0.21
347.2855530	0.15
354.3432312	0.18
359.2160034	100.00
368.0060730	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1671
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
228.9568787	0.03
251.3647919	0.02
267.3517151	0.01
295.1924438	0.01
313.3407593	0.02
321.2238770	0.01
323.7028198	0.01
339.2444153	0.75
351.2109375	0.02
353.3441162	0.01
367.4577637	0.00
376.1124268	0.01
383.5046387	0.01
421.9163818	0.01
449.5246582	0.01
469.1549072	0.04
487.2647705	0.01
495.5038452	0.07
503.4872437	0.01
504.2856445	0.02
508.2907104	0.02
511.6156616	0.09
513.2261963	100.00
514.0965576	0.02
519.3372803	0.02
525.3928833	0.01
531.2891846	0.12
535.1985474	0.02
549.1134644	0.03
562.2973022	0.01
590.3343506	0.04
591.8622437	0.06
608.2801514	0.06
609.2457886	0.01
660.2676392	0.01
661.5900879	0.01
665.4469604	0.02
670.5088501	0.01
674.0724487	0.02
675.6911011	0.01
688.1425171	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	364.1036
Annotation	4-Hydroxyvoriconazole
Peak:m/z	Relative Intensity
110.7608948	0.04
112.9456787	1.62
115.8807831	0.06
125.0681152	0.19
128.1485901	0.07
128.9804382	0.40
129.9793091	6.75
131.0814819	0.04
134.9066772	0.05
141.1165619	0.09
142.9969482	1.60
144.3714447	0.12
154.2760315	0.07
156.3178406	0.02
156.9712830	0.05
158.0586853	1.42
158.9931641	0.83
161.0100250	3.21
163.0945435	0.12
164.9728088	0.05
172.1452332	0.34
180.9009247	0.04
184.1179657	0.52
186.5703125	0.05
188.2847900	0.32
189.4190521	0.13
200.1489258	7.92
201.8863525	0.13
210.3225403	0.04
214.0886841	1.03
217.1935272	0.10
222.9845276	0.12
226.1989441	0.14
228.0743103	0.10
230.3255005	0.14
232.1666870	0.11
235.2363586	0.14
244.1145630	0.61
254.1936951	0.08
257.4197693	0.09
274.2342834	0.03
292.2006836	100.00
302.2376099	0.18
319.1668701	0.18
320.4732666	0.34
327.1825562	0.03
328.2220459	0.14
336.2981567	0.15
345.8796692	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1351
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0530243	0.03
162.1085205	0.06
164.0013123	0.02
165.0078735	0.05
175.0483551	0.01
179.0694580	0.21
182.0024109	0.01
183.3269043	0.01
186.9810791	0.07
188.2194977	0.14
199.1167603	0.05
200.8596497	0.08
203.1164246	0.15
204.0947571	0.02
205.0657196	0.32
206.2494507	0.03
212.1552124	0.01
219.4059143	0.10
225.1377869	0.02
227.1913605	0.12
229.5147705	0.04
230.2165680	0.04
242.1833191	0.03
243.1837158	0.36
244.2645569	0.02
245.2413025	2.15
246.1263123	0.28
247.0726624	0.03
248.2508240	0.02
253.1334839	0.03
255.2940979	0.08
257.2221985	0.06
259.3007202	0.04
261.1163330	0.03
263.2615356	0.01
267.1908875	0.04
269.1375122	0.25
270.9436951	0.03
273.1726074	0.85
274.1751099	0.18
274.7938232	0.02
275.4847412	0.06
281.1621704	0.10
285.1451416	0.10
287.2330322	6.18
288.4443359	0.95
289.1796265	12.38
290.1788330	1.80
299.1160278	4.91
300.0872192	0.69
301.3106079	0.10
305.3513184	0.01
311.3390808	0.03
314.9221802	0.04
327.3801270	0.04
329.2351685	0.32
330.2914429	0.08
331.2506714	0.37
332.3291016	0.09
339.1688843	0.21
340.2592163	0.11
341.3020630	0.17
357.2317505	0.39
358.5508423	0.06
361.9455566	0.02
369.3251953	0.03
371.1481934	0.05
377.5745239	0.07
379.3515015	0.03
380.0133667	0.02
381.3264160	0.78
382.3612061	0.03
383.5311890	0.03
393.5260010	0.04
395.4750977	0.06
405.2830811	0.05
407.2055054	38.83
408.2419434	6.08
409.3654175	0.35
410.2686768	0.06
411.2145996	0.20
413.2116089	0.02
420.7038574	0.04
423.3060913	0.16
425.1760864	100.00
426.2538452	12.15
430.6063843	0.01
433.3300171	0.38
434.2177734	0.07
437.1005249	0.09
438.3610840	0.05
446.5497437	0.02
449.3629761	0.48
451.2137451	21.21
452.3145142	4.37
453.4274902	0.03
459.6831055	0.02
462.2321167	0.03
467.3078613	1.12
468.1011353	0.25
471.3134155	0.05
472.2317505	0.03
473.5532837	0.04
475.6317749	0.04
483.3113403	0.01
489.4909058	0.04
490.2210083	0.06
491.8965454	0.07
492.6495972	0.02
493.2584839	0.08
497.3715210	0.03
498.3698730	0.04
499.2802124	0.14
515.3446655	0.35
516.3560181	0.12
533.1864624	0.70
534.2105103	0.32
534.8428345	0.01
538.4346924	0.02
542.3884888	0.02
551.3888550	0.01
555.8403931	0.03
559.2410278	6.52
560.3226318	1.23
568.3894653	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
113.0470276	0.03
136.0508423	0.31
151.0512695	21.52
161.0549622	0.02
165.0431824	0.03
166.4644165	0.04
167.2952881	0.03
182.0525665	9.33
191.0030670	0.05
197.0309906	100.00
206.9396057	0.64
223.1596375	0.22
224.1262817	0.27
225.2152710	0.07
226.1404419	0.12
234.2680359	0.07
235.3164368	0.04
238.1801758	0.02
267.4894714	0.04
271.2797546	0.17
282.9882812	0.05
312.9594116	5.19
315.2951050	0.24
317.2844849	0.04
327.1291199	0.04
328.3729858	0.02
329.3607178	0.04
341.2462463	0.27
342.2893372	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.91
Annotation	Unknow
Peak:m/z	Relative Intensity
198.9735565	0.13
202.9053345	0.20
245.1419983	0.08
273.0711060	0.68
341.1516113	0.11
357.3732910	0.19
387.1242065	0.15
405.1408081	0.28
427.0617676	6.10
427.8048096	0.12
429.2280273	0.43
432.1231079	0.12
456.9079590	0.36
469.7343750	0.05
471.1203613	0.43
472.3609009	0.84
473.0578613	2.57
481.0739136	0.19
485.4539795	0.15
486.0651245	0.12
493.7970581	0.09
495.3256226	0.09
500.8569946	0.07
503.2140503	0.12
512.9500122	0.94
517.9072266	0.34
518.8533936	0.36
529.1893921	0.46
529.9039917	0.16
532.1490479	0.09
534.5209961	0.12
540.9506226	100.00
542.0122681	0.41
543.0353394	0.21
556.0125122	0.18
559.2268066	0.64
568.8781128	0.23
570.3817139	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1035
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
107.9355621	0.10
109.0814590	0.41
119.0816345	0.60
121.0354385	0.02
121.9262390	0.04
130.8713837	0.07
132.1651001	0.04
135.0951233	0.62
137.0381470	4.36
143.1483612	0.04
161.0538940	0.05
162.0477905	0.10
162.9084778	0.15
169.0553741	0.18
177.3032837	0.03
179.1753998	1.91
181.0120087	100.00
182.0315247	0.07
191.1253357	0.15
205.2595215	0.03
211.1142883	0.06
213.5153198	0.02
217.8578796	0.04
219.3746338	0.02
223.1251831	0.09
227.2078552	0.08
239.3141174	0.03
241.2005310	0.02
247.0559998	0.06
253.0484314	0.02
270.1800232	0.06
277.5707703	0.13
281.3793945	0.16
283.3530273	0.06
295.2108154	0.12
297.1191406	0.93
299.0995789	0.17
324.2658691	0.10
325.1180115	0.15
326.7631531	0.03
328.3699036	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.1414
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9940338	0.11
161.9872131	0.45
167.1491089	0.04
170.0335388	0.05
179.0304260	1.29
187.0548401	0.10
189.1575623	0.03
206.9575806	0.29
213.9209290	0.03
215.0708313	0.36
216.3607635	0.04
226.9276428	0.03
231.0455322	0.09
233.1169739	3.73
233.7671051	0.03
240.2034607	0.02
241.2877655	0.07
243.0231476	0.08
245.0541534	0.14
250.1212463	0.03
251.0760345	0.05
262.1397705	0.04
272.0583496	0.06
273.2277832	0.03
274.4602051	0.05
283.8652954	0.19
290.1444092	0.33
291.1553955	0.39
296.2114258	0.11
298.3411255	0.02
300.4299316	0.09
301.1615601	0.24
302.0815735	0.10
306.2891235	0.09
308.1946411	8.34
309.8319092	0.08
316.1787720	0.06
318.1074219	2.69
319.0632324	1.34
326.0798950	0.04
334.0757446	0.95
335.1706543	2.50
336.1269531	27.54
339.1676636	0.04
340.6499634	0.20
341.2610474	0.09
344.2164917	0.90
347.1912842	0.05
348.3489990	0.03
349.0609131	0.13
349.9031372	0.04
353.7901611	0.08
356.9833984	0.05
361.5274658	0.09
362.2928467	0.47
366.1770630	0.04
369.1031494	0.03
374.1630249	0.03
375.1387939	0.60
376.1954956	0.20
378.3372192	0.14
379.0093994	0.10
384.1118164	0.07
385.3491821	0.02
390.5002441	0.08
392.2125244	0.19
393.1710815	3.15
394.1540527	0.12
395.4067383	0.05
401.0440063	0.07
402.1301270	0.82
409.1646118	1.20
411.1490479	100.00
411.7643433	0.43
413.1109619	0.87
420.2001343	0.26
424.2926025	0.06
429.1559448	0.18
430.0598755	0.02
431.2695312	0.18
435.1878662	0.06
436.7845459	0.09
437.3959961	0.05
438.3223877	0.06
441.3650513	0.19
446.3480835	0.14
447.2458496	1.81
448.3471680	0.13
449.9683838	0.04
459.4483643	0.14
465.1402588	14.50
465.8350830	0.03
475.5236206	0.11
477.1968384	0.20
483.1187744	0.03
494.4468384	0.09
504.3114014	0.65
505.2136841	0.07
506.2108765	0.12
507.0147705	0.05
516.3756104	0.08
521.2877808	0.71
522.2415161	8.39
523.2119141	0.58
530.3673706	0.19
531.5278931	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0562
Annotation	2-O-(Z-p-Hydroxycinnamoyl)-(x)-glyceric acid
Peak:m/z	Relative Intensity
86.8305130	0.03
104.9028473	21.08
105.7243500	0.05
119.0081482	0.79
131.0734711	0.11
145.0903473	3.57
149.3022308	0.04
162.9824066	100.00
163.7588501	0.02
177.1122284	0.03
180.3209076	0.04
190.9023285	0.05
204.9997559	0.03
207.1060638	0.37
208.0300446	0.06
232.2953644	0.11
233.0837555	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.02
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0460052	0.12
219.8378143	0.07
221.1264801	0.14
223.8719788	100.00
236.8043213	0.02
241.8138428	22.16
244.2141571	0.01
264.7988281	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	460.77
Annotation	Unknow
Peak:m/z	Relative Intensity
149.0050812	0.03
206.9327087	9.51
208.9721069	8.14
232.8794403	0.09
257.1425476	0.06
281.2876892	0.06
290.8132629	48.44
292.8014526	100.00
293.4212952	0.12
299.0513306	0.13
301.0087891	0.06
323.2299194	0.07
325.1866455	0.16
340.5446777	0.12
368.7628174	0.03
370.9772034	0.04
374.1010742	0.38
374.7171631	6.28
376.6395264	37.46
377.5452881	0.20
400.8641052	0.28
413.9584656	0.08
414.7057495	0.10
431.0629883	0.06
443.1244507	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	279.1237
Annotation	Villosin B
Peak:m/z	Relative Intensity
88.6724243	0.08
95.0039368	0.03
97.0191803	0.39
107.0254822	0.07
109.0352325	0.18
116.8389282	0.11
119.1721039	0.05
120.9122772	0.14
122.1172333	0.24
124.0444336	0.93
124.9387741	0.05
137.0527039	0.54
139.0964050	100.00
147.0809631	0.69
149.0567322	0.10
151.0562134	0.99
158.9876251	0.16
161.3140411	0.10
164.9146423	0.13
168.1582184	5.64
169.0743408	12.27
171.0665588	0.04
172.0195465	0.08
173.1137543	0.10
177.1012878	0.37
187.1887970	3.63
189.0751038	0.33
191.2411499	0.45
195.2228699	0.06
199.1840820	0.26
202.8520813	0.06
205.1651306	27.07
207.2306213	0.29
217.1649170	3.99
218.6501160	0.07
219.3532104	0.03
221.9171448	0.06
231.1652527	0.53
233.0765991	0.42
235.0695801	19.75
235.7845154	0.08
241.2911072	0.06
243.1198120	0.10
247.6802368	0.09
249.0650330	23.79
249.6876526	0.30
260.2268066	0.37
261.1418762	2.12
264.1495361	0.09
280.1642761	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.1116
Annotation	5,6-Dihydroxy-7,8,4'-trimethoxyflavanone
Peak:m/z	Relative Intensity
105.0580597	0.20
107.0370483	0.10
110.2106018	0.07
114.9148102	0.31
119.1475220	0.12
121.1074677	0.05
121.9626160	0.24
124.8545837	0.05
127.0855255	0.03
133.0267487	0.61
136.9580536	21.83
139.8826447	0.04
146.9937744	1.32
149.0081787	2.27
151.0196533	0.44
152.9726257	0.06
161.0603333	3.44
162.1398010	2.07
165.0799713	0.15
165.9454651	0.14
167.9945221	0.08
168.9760742	0.25
171.1740417	0.05
175.1132507	0.44
177.1962280	0.62
179.0423431	1.99
180.3112793	0.23
181.0487671	0.17
184.5419159	0.09
189.3049011	0.06
192.9997864	24.25
194.9805145	0.09
197.1276550	0.14
198.6249542	0.02
201.0104828	0.17
205.0739441	0.93
207.2551575	0.18
209.2314148	0.06
213.5457458	0.11
216.0487061	0.03
221.1987610	0.05
222.9164429	9.07
225.0058899	0.03
227.3957520	0.08
241.2211304	0.04
243.1376038	0.37
248.4348145	0.08
253.1728516	0.58
258.3249512	0.07
262.1170959	0.05
264.9418945	0.12
267.2136841	0.08
268.3433533	0.10
270.0703125	0.12
271.4270020	0.15
273.1104126	3.02
274.9589844	0.03
277.1434021	0.10
279.0188904	0.06
282.0452881	0.06
283.1009521	0.52
284.1784058	0.04
285.2717285	1.54
287.1409607	0.06
291.2802734	0.43
293.0969849	0.04
297.1882324	7.00
299.1343994	13.55
299.7628174	0.05
301.0436707	0.33
301.7006836	0.11
302.6310425	0.76
303.4350281	0.17
306.0244446	0.03
307.0019836	0.13
311.1371460	2.09
311.8532104	0.07
315.1452026	0.60
317.2374268	45.06
318.0278320	0.13
319.2058105	0.17
327.0284424	0.07
329.1690674	100.00
330.2979736	0.09
337.8950500	0.06
358.8869324	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	694.1135
Annotation	Unknow
Peak:m/z	Relative Intensity
196.1942139	0.02
197.8788147	0.04
232.2007141	0.12
239.1663666	0.09
240.1625977	0.60
241.2103424	0.06
256.9975281	0.03
259.0906677	0.11
260.1015015	0.48
261.3891602	0.20
263.0211792	0.08
269.3911438	0.07
273.9707642	0.14
275.0166931	0.04
276.1563110	0.04
277.1048584	0.74
278.1533813	0.28
278.9756165	0.11
283.2602539	0.04
286.2874756	0.04
287.0427246	0.03
288.0137329	0.08
290.5461426	0.21
291.8617554	0.26
293.1103210	0.10
301.9942932	0.49
303.1486206	0.16
304.2985840	0.49
305.0787048	2.66
306.1723938	0.39
307.1362305	0.03
309.3966675	0.06
311.4220886	0.02
317.9252014	0.72
320.1203003	4.61
321.0770874	0.39
327.0769043	0.04
330.3918457	0.07
342.1424561	0.04
344.0810547	0.14
346.0513306	2.87
347.1306763	0.67
348.1777954	1.21
349.0843811	0.48
349.9649353	0.21
352.3650513	0.04
364.0658569	0.29
364.9353638	0.09
372.3159790	0.04
373.1688232	0.03
374.1610718	0.13
375.9507446	0.05
376.9569702	0.05
381.9758301	0.02
389.1329346	0.15
390.0466919	0.94
391.0415649	0.24
392.0769043	9.69
393.2046509	1.21
401.9456177	0.02
403.5443115	0.11
412.1605835	0.14
417.9971924	1.76
419.1083374	0.44
434.1701660	0.02
435.9749756	20.39
437.0581055	1.95
454.8204346	0.06
456.2534180	0.06
462.0780640	2.12
463.1110229	0.18
464.3249512	0.06
469.0984497	0.02
474.2764282	0.08
474.9310913	0.11
477.9444580	0.13
479.9786377	100.00
481.0377808	12.38
481.6786499	0.06
485.2137451	0.05
486.8973999	0.04
492.3109131	0.05
519.2674561	0.03
544.1062622	0.07
563.2027588	0.04
564.2731323	0.08
577.8166504	0.11
587.3460083	0.19
605.0491943	0.21
606.0864258	0.07
607.0964966	0.49
608.0529785	0.27
613.1582031	0.05
618.3512573	0.15
630.9990845	0.75
632.2904663	0.45
646.9517212	0.06
648.9548950	1.51
649.7081299	0.02
650.4557495	0.03
657.2759399	0.13
660.3109131	0.19
674.9268799	6.56
676.0082397	1.26
676.6740112	0.01
684.9688110	0.10
685.9058838	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.1078
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9865112	14.29
164.1217651	0.20
168.1903381	0.06
177.0540466	0.05
181.0924988	0.04
197.3543396	0.05
211.4226990	0.04
272.1203613	0.12
285.5458984	0.08
309.0874023	0.04
311.4440308	0.12
333.4730835	0.04
337.2559814	0.30
353.0844727	0.08
355.0138550	23.33
356.1913452	1.03
357.3803101	0.08
358.2189331	0.03
359.5283203	0.10
361.2356567	0.05
364.9591064	0.06
366.0018921	0.12
379.0656128	0.13
380.9708862	0.06
381.8193359	0.30
382.6437988	0.05
383.4390259	0.14
384.5629883	0.05
389.5775757	0.12
391.4874268	0.04
407.3660278	0.04
408.1815796	0.13
409.1859741	0.54
409.9614258	0.09
412.4609375	0.09
427.7305908	0.03
428.7969360	0.03
463.0687866	0.04
468.6399536	0.13
471.2739258	0.11
477.8779907	0.05
478.4824829	0.02
484.5711060	0.09
495.2363892	0.03
499.4102173	0.06
501.6853027	0.06
512.2186890	0.13
514.5084839	0.04
521.3829956	0.02
526.1537476	0.05
539.2332764	0.09
541.1200562	1.66
569.4415283	0.28
571.0989380	4.58
571.9918823	0.02
582.2591553	0.07
583.2583618	0.03
589.3329468	0.11
599.3379517	0.09
600.4464722	0.23
601.1957397	0.65
603.3521118	0.10
718.0592651	1.05
719.0426636	0.07
744.6333008	0.05
745.5161743	0.05
761.2698364	17.23
762.2675171	46.81
763.1193848	100.00
764.0952759	0.56
767.2716064	0.09
779.5588989	0.19
780.9851685	0.08
783.5537720	0.03
800.7705688	0.03
854.8510132	0.06
951.6303711	0.08
952.7642212	1.68
953.8051758	4.19
954.8521118	6.80
956.2136841	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.1588
Annotation	Ferupennin M
Peak:m/z	Relative Intensity
114.9895630	0.05
117.0467224	0.01
123.0371017	0.01
123.8473587	0.07
127.0427322	0.03
129.3342590	0.03
131.0544281	0.07
132.9330444	0.03
135.1909027	0.06
136.9858704	0.06
139.1464844	0.03
141.1762848	0.03
144.0859375	0.03
145.0338440	0.04
146.4164429	0.01
147.1033325	0.01
149.2761536	0.05
151.0950470	0.07
151.9432678	0.08
152.9717712	0.08
155.1444397	0.05
158.0949402	0.02
159.1073303	0.10
161.0867310	0.03
163.0462189	0.06
164.1321106	0.01
167.0505066	6.89
169.1573486	0.05
173.1192322	0.16
175.1083984	0.05
177.3569641	0.02
179.0691223	0.08
181.1850281	0.24
183.1361084	0.06
187.1269989	0.45
190.0702209	0.02
190.8818665	0.05
191.6724548	0.03
193.1729126	0.10
195.1157684	0.33
197.0948792	0.17
203.1794434	0.04
205.0331268	2.28
206.0139771	0.01
207.1581421	1.03
209.1581421	0.38
215.1277771	0.12
217.1582489	4.18
219.1026306	1.21
220.4528198	0.01
221.1772461	0.06
227.4207764	0.03
229.1096802	0.16
229.7313538	0.01
231.1321106	0.66
233.2198792	0.09
235.1748962	0.48
237.1199951	0.04
239.4404907	0.02
240.9215698	0.01
242.2480469	0.03
243.3323364	0.01
245.0063782	0.03
247.1907959	3.47
251.6435242	0.02
252.2646179	0.02
255.9433289	0.01
259.4372559	0.03
261.2360229	0.03
269.4719543	0.09
278.3300781	0.03
279.2142944	0.07
281.1109009	0.01
284.5777588	0.01
287.2568359	0.05
289.3075562	0.03
291.2568970	0.60
293.1245728	0.03
295.1511536	0.04
295.9405823	0.02
297.2326355	0.06
298.8137817	0.05
299.4698181	0.07
300.3584595	0.05
301.2887573	0.06
305.2028809	0.04
307.2149658	0.24
309.2243347	0.15
310.2799072	3.13
311.2449951	0.25
311.9441528	0.00
315.3024902	0.24
316.4322510	0.01
318.3078613	0.14
319.1971130	0.66
320.4836121	0.16
321.3562012	0.05
323.2816467	1.78
324.3261414	0.04
325.2687988	0.01
327.4126282	0.05
328.3150024	0.01
330.2244263	5.56
331.3092041	2.92
333.1986084	0.04
336.3279419	0.06
337.2716675	0.06
339.1632080	1.37
340.3552856	0.79
341.2874756	0.71
342.1121521	0.05
343.1953125	0.79
346.1547241	0.34
346.8400269	0.05
347.6660156	0.01
351.2316589	8.61
352.3662109	0.08
355.2583008	0.17
356.3188171	0.13
357.2989807	0.11
359.2240295	0.02
359.9465942	0.04
365.3874207	0.12
368.5256653	1.07
369.2618103	13.31
371.3023376	5.53
373.2504578	3.32
383.2427673	100.00
384.3883362	0.17
385.3556824	0.05
386.2308044	0.16
389.5519714	0.02
391.2707214	0.46
392.7627869	0.19
411.1089478	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1355
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0649109	0.07
163.0261688	0.12
174.2451172	0.02
175.1072693	0.15
177.0961609	0.07
179.1148834	0.09
183.0355835	0.04
187.1880951	0.01
187.9670410	0.01
190.0293427	0.02
199.0683136	0.09
200.9894409	0.11
202.0838165	0.23
203.3277740	0.13
205.2193909	0.08
217.3064117	0.04
226.8399200	0.07
228.2075195	0.12
229.1383209	0.13
230.2171631	0.08
231.0330658	0.08
232.5620728	0.06
241.3612671	0.12
242.9685669	0.53
245.1800842	4.02
246.2761841	0.17
247.0916748	0.23
255.2231598	0.07
257.2349243	0.11
259.0168152	0.05
261.2489624	0.04
263.2079163	0.02
267.2955322	0.03
269.1824341	0.56
270.3304443	0.04
271.1849976	0.18
273.1503296	1.89
274.2280884	0.32
275.4237061	0.02
281.3380127	0.07
285.3006592	0.13
287.1489258	9.12
288.2001953	0.99
289.1593018	19.00
290.2401123	2.75
297.4344482	0.04
299.2093506	6.33
300.1615601	1.03
301.1278381	0.07
303.3676147	0.10
309.3865967	0.06
313.2156982	0.02
315.2650146	0.07
327.1469116	0.11
328.7088623	0.21
329.3325806	0.39
330.4761353	0.22
331.2762451	0.70
332.3794556	0.21
339.1645508	0.24
341.1343384	0.26
347.1102905	0.04
349.2305908	0.05
351.6909180	0.17
356.7891235	0.24
357.4395752	0.41
358.3648071	0.12
364.2869263	0.14
366.2643433	0.04
367.2350464	0.07
371.2676392	0.03
372.4802246	0.04
378.9230957	0.11
381.2551880	0.83
382.3046875	0.24
383.4683228	0.06
385.4074097	0.11
386.8735352	0.01
391.0975342	0.04
393.1393433	0.02
395.7203369	0.09
397.2636108	0.09
400.2012939	0.02
401.4541016	0.02
403.2567749	0.13
405.2550659	0.03
407.1721191	46.66
408.2493896	10.10
409.3997192	0.61
410.2225952	0.24
411.1086426	0.21
412.4151001	0.17
413.2176514	0.02
415.5327148	0.07
416.4265137	0.04
421.3662109	0.02
422.3508301	0.03
423.3577881	0.38
425.1759033	100.00
426.2880249	17.27
427.3927002	0.04
428.3719482	0.03
429.1463623	0.04
431.3564453	0.20
432.3850708	0.09
433.1549072	0.71
434.3341064	0.11
435.4708252	0.11
437.0278931	0.03
437.8728027	0.07
441.9961548	0.11
444.1860352	0.11
445.1942139	0.02
446.3430786	0.08
449.3554077	1.01
451.2103271	28.97
452.2313843	6.29
453.3070679	0.03
461.3487549	0.06
462.3540649	0.36
463.1559448	0.03
467.2935791	1.94
468.2815552	0.17
471.4505615	0.02
473.5464478	0.04
474.1880493	0.04
475.6525879	0.05
479.6139526	0.08
481.3104858	0.14
482.6461182	0.13
483.3828125	0.11
487.3133545	0.02
489.3761597	0.10
491.3457031	0.07
492.2572632	0.28
493.2860718	0.11
499.2924805	0.44
500.2686157	0.25
502.0440063	0.18
505.2565308	0.06
515.2620239	0.40
516.4839478	0.09
517.2243042	0.04
525.4077148	0.13
526.3936157	0.02
529.7412109	0.08
531.3446045	1.66
532.2770996	0.10
533.2714233	1.60
534.3268433	0.58
539.6079712	0.08
541.5814209	0.02
542.4494019	0.15
545.5851440	0.03
546.4237671	0.15
547.3581543	0.08
555.4186401	0.29
559.2175903	13.20
560.2271118	3.97
561.1151123	0.09
569.2023926	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.2346
Annotation	Unknow
Peak:m/z	Relative Intensity
191.1225739	0.05
221.1817932	0.02
257.0147095	0.12
289.2785645	0.06
293.1832275	0.06
327.5284424	0.02
353.5683594	0.03
370.9805908	0.03
379.2070923	0.07
383.2722778	0.14
400.3571777	0.02
401.1891479	0.33
427.1184692	0.05
449.3435669	0.10
458.7857666	0.03
465.3220215	0.03
470.2882690	0.03
507.2179565	0.03
515.4130249	0.03
517.3199463	100.00
517.9240112	0.27
540.9659424	0.02
542.3947144	0.05
544.9415894	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1815
Annotation	(1R*,2R*,4R*,8S*)-p-Menthane-1,2,8,9-tetrol 9-glucoside
Peak:m/z	Relative Intensity
105.0538635	0.08
112.9508820	0.47
118.7194366	0.18
125.2229843	0.07
127.1742020	0.05
130.8741760	0.18
139.3074493	0.14
140.8895874	0.05
143.0351562	0.88
149.0854492	0.11
153.1033325	0.12
155.1561279	0.76
156.1020508	0.44
157.1274719	5.68
161.0704041	0.34
163.9677582	0.13
171.2168274	1.05
179.1587219	0.49
181.1080475	0.08
185.0725098	2.43
187.1731262	1.04
199.2362518	6.22
201.2676697	0.91
203.1111145	100.00
215.1353607	0.24
217.2208557	0.08
227.1919556	0.43
245.2440796	6.23
254.9857178	0.10
257.4278259	0.36
258.0546875	0.10
259.3303528	0.10
275.2945251	0.08
276.3888550	0.06
277.3614197	0.09
287.3466187	0.15
289.1085815	0.24
303.0888672	0.70
305.4129944	0.16
319.3171082	0.51
321.2550354	0.57
323.3615723	0.24
347.3088074	2.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	745.1339
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
217.0067139	0.08
230.0348816	0.09
253.9534912	0.15
265.4500732	0.07
268.1364136	0.05
269.2251587	0.15
272.1128845	0.39
287.5503540	0.05
288.4460449	0.10
306.1484375	0.87
313.0534058	0.18
319.5128174	0.05
335.3366089	0.04
338.0972900	0.17
338.9082336	0.04
341.2976685	0.07
345.3097534	0.04
351.2637329	0.05
353.2061768	0.34
359.2247314	0.03
361.0434570	0.04
369.5721436	0.05
372.1553955	0.03
374.2628784	0.06
379.1483765	0.09
389.3822632	0.13
391.1644897	14.27
391.8759155	0.10
393.1411133	0.04
398.2668457	0.25
407.1669312	0.59
410.0783081	0.13
415.3057251	0.05
417.2999268	0.19
423.2898560	0.69
426.0834351	0.07
435.3495483	0.04
437.3943481	0.02
439.4140625	0.05
441.3226929	0.29
449.2185669	0.51
450.1514282	0.05
457.2041016	0.24
467.3150635	3.31
472.1065674	0.20
475.3753052	2.79
476.8064575	0.03
483.2319946	0.37
485.3348389	1.34
488.3623047	0.26
496.2163086	0.03
498.4476318	0.04
501.2010498	7.43
513.3400269	0.05
514.0585938	0.14
519.2177124	100.00
520.1707153	0.04
527.3892212	0.17
532.1404419	0.83
535.4320068	0.10
537.3692017	0.04
544.3663940	0.14
553.0637817	0.96
554.5171509	0.17
561.2069702	0.20
565.2391968	0.62
569.2825317	0.13
571.3129272	0.27
572.3333130	0.05
573.1378784	0.06
577.3650513	0.19
582.1887817	0.16
583.3830566	0.30
595.4184570	0.04
601.3375854	0.23
611.7015991	0.04
620.6581421	0.10
639.6461792	0.35
649.4129028	0.19
657.1562500	0.60
665.3263550	0.12
667.1735229	0.13
675.2616577	0.08
681.4966431	0.04
683.1560669	0.95
690.2312622	0.03
693.1885376	0.17
701.1860352	6.78
708.2743530	0.03
709.5230103	0.02
710.3822021	0.07
711.5723267	0.04
717.4500122	0.10
726.2603149	0.60
727.2557373	5.02
733.6523438	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0876
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
106.9290771	0.07
108.1465759	0.06
110.9958038	0.07
118.1507797	0.03
127.0850296	0.02
133.0023041	0.04
134.999054	6.59
136.0911713	0.61
137.2388611	0.01
155.129715	0.16
161.0898743	0.68
173.0248566	2.58
174.1113434	0.09
179.0729523	39.79
180.1338043	3.49
188.1002197	0.02
191.0517273	100.00
192.1329956	7.40
217.0808105	0.04
308.9007874	0.06
310.0863342	0.01
331.0826416	0.03
335.4183044	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.1322
Annotation	Glu Val
Peak:m/z	Relative Intensity
82.8981781	0.34
84.9861145	0.03
90.78449249	0.05
94.76982117	0.03
96.98799133	0.17
105.1507416	0.18
108.9489136	0.49
110.9991302	0.42
115.2943726	0.03
119.0321655	0.19
120.9481354	1.99
123.0426941	0.41
127.0600586	0.03
129.2577667	0.07
133.1010132	0.08
135.0110474	0.47
137.0614624	0.57
139.2119598	0.16
141.0665894	0.16
142.9086761	0.21
145.0908813	1.07
147.0360565	1.12
149.095108	1.82
150.0471954	0.46
150.9833527	0.18
153.086441	0.22
157.1093445	0.29
159.1121674	1.11
160.1297455	1.16
161.2037201	0.52
163.0776367	2.84
165.1824493	0.15
169.554184	0.40
170.303299	0.18
171.187912	0.33
173.0043182	2.66
173.6108093	0.03
174.954422	0.14
177.0648956	0.07
183.1845093	3.05
185.1215973	1.67
187.1524506	15.22
188.1292725	0.04
189.0758209	1.14
191.1018219	18.59
196.1624298	0.05
201.0922241	12.03
203.208313	3.79
204.0014496	0.10
205.1486053	2.22
206.0794373	0.19
211.0722809	6.24
215.0570526	0.32
217.1794281	0.06
219.1226044	2.07
219.9463959	0.05
226.0384979	0.14
227.0127106	0.10
229.1214447	100.00
230.0212402	0.19
238.0671997	0.73
238.7716827	0.11
247.170578	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1155
Annotation	N,N-Dihydroxy-L-tyrosine
Peak:m/z	Relative Intensity
129.2143250	0.15
140.7682800	0.07
142.1549072	0.06
192.0668640	7.23
198.0073090	0.14
207.1828613	0.04
214.1746521	0.03
215.9911346	0.14
218.3766937	0.12
231.2212067	0.11
233.2015076	0.13
236.0336304	100.00
238.3882446	0.14
256.0899353	0.54
257.7250061	0.25
259.3131104	0.08
273.4727783	0.06
279.0277710	0.09
284.0990906	0.08
284.9869690	0.08
294.8358765	0.03
296.2404480	0.10
298.4527588	0.14
301.2015381	0.03
314.0263977	0.49
314.6594238	0.19
317.1746826	0.06
319.2548218	0.10
320.3297119	0.14
321.0138550	0.28
322.9672241	0.05
326.9677734	0.10
327.9531250	0.42
329.0153198	0.15
332.5259705	0.06
340.1090088	0.10
344.0186157	0.20
346.0881958	0.11
358.0363464	0.79
359.1145630	0.28
361.2796021	3.83
363.1441650	0.13
364.3281250	0.07
385.0890503	0.23
389.4287109	0.12
403.5060730	0.14
405.1190491	0.73
413.2323608	0.10
428.9790955	0.10
430.1920471	1.04
430.9986877	0.91
431.8921814	0.05
434.1562805	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9171
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9606323	0.02
158.9934692	0.09
160.1087036	0.02
175.0194092	0.69
176.0639343	0.01
230.1252747	0.03
241.2251587	0.03
244.9628601	0.15
246.0690002	0.01
273.0469360	3.65
274.0940857	0.78
287.0969238	0.01
288.9755249	100.00
290.0208130	12.26
305.3042603	0.01
328.9607544	0.16
330.9590454	0.01
346.8992310	0.01
357.0221863	0.05
358.0910034	0.03
358.9834900	0.06
360.1218262	0.05
375.2584534	0.05
376.1699219	0.01
385.1666565	0.03
385.9565430	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1038
Annotation	Mollugoside
Peak:m/z	Relative Intensity
122.1378098	0.09
122.9565735	0.29
128.9442444	0.04
139.0387878	0.09
147.1629333	0.08
151.0373230	0.16
152.0809326	0.66
153.0582275	2.47
156.8834839	0.64
163.0379486	0.17
166.9684448	15.01
169.0810852	0.30
171.1069641	0.19
175.0367279	1.38
177.2042542	0.14
179.0912476	0.12
187.0686340	0.11
193.1372528	0.21
194.0522461	0.26
207.1202698	0.20
209.2124634	2.43
217.0195312	0.06
219.4582214	0.21
223.2781067	0.36
224.9520264	0.18
226.1333771	0.84
227.0814819	47.01
231.1144714	3.76
239.3304443	0.09
241.1615906	13.16
245.3638916	0.15
249.1781616	75.72
255.0863953	9.17
265.3523254	0.18
267.1076965	43.39
269.2720642	1.87
279.1259766	0.10
281.1335754	0.20
285.2888184	1.13
288.8785706	0.06
296.3663330	0.13
309.1221008	1.52
311.0396729	0.14
323.2436523	0.29
327.1582642	0.44
332.2023010	0.05
333.3408508	0.22
335.2393494	0.04
339.1080933	0.27
341.1350708	1.22
345.7979736	0.23
349.1011353	0.18
353.0617981	0.24
355.3057251	4.92
357.2331848	12.82
358.9898682	0.08
367.1746216	0.35
369.8815308	0.31
371.1668091	0.36
373.2666321	2.27
378.2525330	0.05
379.3149719	0.89
380.5100708	0.13
381.4153748	0.38
385.1769714	53.50
397.3753357	0.06
399.2503662	100.00
399.8603821	0.18
407.5692139	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	528.0418
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0091858	0.24
157.8633423	0.29
169.7519226	0.35
171.9426880	1.13
173.9411926	0.35
184.2427063	0.14
184.9691925	0.08
187.9166718	0.07
200.1116180	0.44
200.9342957	0.07
201.9623108	5.24
204.1142426	1.16
214.1309052	0.15
217.0430756	0.19
231.0053711	0.16
232.0497131	1.13
234.1068878	0.08
242.0413818	0.19
244.0676575	0.59
245.9398956	76.17
247.1546326	0.27
249.9989929	0.71
256.2751465	0.10
258.0956116	2.92
260.0280151	1.34
261.2071228	0.88
262.1528931	0.38
270.0935059	0.13
274.1559448	0.48
275.9986572	3.99
277.1108093	0.53
278.1989746	0.19
285.9620972	1.00
288.1379395	1.37
291.7768555	0.46
293.8885193	0.10
300.3391724	0.33
301.9189453	0.17
302.9685974	0.06
304.0468750	1.01
305.9998779	7.13
318.0205688	0.79
320.1024780	0.11
320.9669189	0.43
322.0061035	4.12
330.1556396	0.32
333.9432373	0.40
343.5445557	0.22
348.0445557	11.32
349.3419800	0.41
363.8552856	0.15
366.0758057	16.00
376.3212280	0.14
378.1970825	3.95
394.2841187	1.58
396.0685425	100.00
408.1554565	0.17
412.2312622	6.14
418.2318726	0.10
420.3327026	0.19
438.2796021	5.44
440.0708008	0.07
454.1704712	2.18
466.1348267	0.23
468.1492920	4.13
482.2015991	3.69
484.1772461	96.04
510.1760864	3.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2779
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.0309448	0.01
152.9287567	0.10
196.0567017	0.23
197.3439941	0.02
214.1698303	2.16
214.9461365	0.06
242.2035217	0.06
243.1932068	0.07
261.4196472	0.17
262.2610168	0.04
273.2048035	0.07
279.2954102	100.00
280.3082275	23.64
297.2941895	0.04
319.4396973	0.09
327.1458130	0.02
388.9848938	0.04
409.1073914	0.03
413.1403198	0.10
421.0860901	0.02
431.1302795	0.03
433.4853821	0.02
449.4366150	0.06
457.1680603	0.03
458.9552917	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2135
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
175.2288208	0.07
190.4213409	0.04
191.3203430	0.03
202.3264160	0.01
205.1098785	0.11
206.8215942	0.03
207.4401245	0.02
208.3127289	0.03
209.2054749	0.01
209.8486481	0.02
216.8683167	0.02
219.1840820	0.04
220.0655518	0.06
221.1917572	0.04
222.7694855	0.03
225.3301086	0.01
233.2133026	0.04
234.0205383	0.05
235.3759613	0.48
247.1168518	0.03
287.1188965	0.03
315.0158691	0.03
324.2348022	0.01
325.0004883	0.04
339.1275024	0.11
341.2966919	0.04
343.0212402	0.04
356.3033447	0.18
357.3427734	0.02
368.3035278	0.01
369.2721558	0.26
370.6567383	0.12
371.3067017	1.02
375.1078491	0.02
383.4625244	0.08
386.4370728	0.34
387.2736816	0.26
389.1330566	0.36
399.4346313	0.01
401.2188110	100.00
401.8628540	0.31
404.5946045	0.05
419.3406372	0.41
421.5197754	0.01
429.3711548	0.28
431.3494873	0.02
460.9675903	0.05
473.5588379	0.02
475.3175659	0.05
476.2253418	0.09
491.2074585	0.03
504.1227417	0.03
505.2196655	0.03
515.2012939	0.01
521.4826050	0.07
533.2904663	0.08
536.4507446	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0877
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
109.0900421	0.06
111.1360092	0.05
126.9516907	0.10
134.0709076	0.26
135.0476074	7.59
155.1101379	0.20
161.1119995	0.75
164.3689423	0.02
173.0139008	2.69
178.9859009	45.21
191.0498047	100.00
308.8390503	0.12
309.459137	0.08
324.0614319	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1031
Annotation	Cinchonain Ic
Peak:m/z	Relative Intensity
176.9662476	0.09
189.1087952	0.60
197.2731934	0.08
211.1887360	0.07
216.3943481	0.10
217.1049805	0.85
218.9246521	0.04
223.2154541	0.13
225.2683105	0.05
229.1968079	0.09
231.0762939	0.36
245.2820740	0.09
254.8688354	0.05
258.9630127	0.07
271.2105103	0.09
285.2527161	0.14
286.8805847	0.22
287.6734619	0.15
289.1177368	0.65
299.2172852	0.74
313.2260132	0.04
315.0101013	0.08
323.1249390	0.05
327.2630920	0.29
341.1734924	100.00
348.2340698	0.02
355.6970215	0.03
372.2511292	0.07
377.2306213	0.16
392.2833557	0.02
405.4733887	0.17
406.2680664	0.08
406.9263916	0.04
415.2814941	0.05
423.0549011	0.06
433.2996216	0.19
436.5526123	0.07
437.3391724	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
154.6659241	0.05
159.0629120	2.96
159.9295959	0.78
161.0314636	0.69
198.9151917	0.09
200.1295471	0.18
201.0591736	0.48
217.3001404	0.11
218.9314117	0.28
220.0927582	0.05
229.0402527	0.37
230.2107849	0.36
231.0803833	0.55
246.1031799	0.02
273.0113525	32.73
274.0746155	16.47
275.0422668	33.94
276.0759583	3.80
307.0843201	0.05
346.0273438	0.09
374.1036377	0.03
387.0020142	30.48
388.2035828	38.22
388.9976807	100.00
389.9814758	24.61
390.6072998	0.03
413.3574219	0.02
414.0606995	0.08
429.0758362	0.41
441.9137878	0.03
457.2815857	0.16
458.9925232	0.94
460.9396057	0.02
474.7189331	0.10
477.1065369	0.06
485.1759338	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
107.1675262	0.04
107.9239502	0.02
109.0891647	0.07
110.4848938	0.04
111.23423	0.03
115.9676666	0.02
127.1082306	0.08
128.0917664	0.02
129.0561676	0.01
133.1159058	0.01
135.0207825	7.63
136.065155	0.48
137.2007751	0.01
143.1172333	0.01
155.1246948	0.28
156.0238647	0.02
161.1424866	1.13
162.1437988	0.06
171.0502167	0.07
173.1633606	2.42
174.2462769	0.26
179.0265045	43.37
180.1405487	3.01
191.0492401	100.00
192.0411682	5.58
217.0300903	0.01
309.3409424	0.05
310.4608154	0.02
335.3683167	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2877
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
125.1781845	6.25
135.015564	13.49
136.9562836	2.96
140.9792633	2.96
145.0076752	5.31
146.9699097	2.27
155.0369263	8.28
157.0003967	5.46
163.3717041	2.27
175.0200653	6.26
185.3776703	4.32
187.0798035	3.18
187.9807739	15.44
201.064209	3.32
212.9921417	9.06
223.2368011	6.42
236.2223816	6.02
242.1760254	3.19
244.4752197	9.83
253.7063599	3.19
256.1644897	4.33
272.3629456	3.50
280.4401245	6.00
281.2045898	15.78
292.3799744	5.00
324.1595154	3.97
327.3659668	2.81
339.4021912	19.62
350.0939331	7.03
351.6293335	5.45
355.0081177	9.73
357.131073	5.34
359.2344971	9.74
361.1905823	2.50
363.6253052	5.98
364.5518494	6.21
366.6647034	4.49
367.5437927	7.58
372.3190918	4.49
377.3916931	13.34
379.5759277	4.23
381.4582825	9.54
382.4031982	3.80
389.4775696	9.76
390.6105347	13.88
391.5409241	16.00
395.4645691	3.18
408.27005	100.00
409.4432983	17.60
410.085022	4.48
422.8734131	5.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1689
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
127.8046188	0.08
130.6794891	0.08
143.0670471	0.11
162.1372833	0.06
167.2132721	0.12
170.0529633	4.06
183.0049438	100.00
184.0158691	9.47
185.3424988	0.16
197.2093964	7.18
198.1334534	5.90
209.2610168	0.08
211.052948	1.78
212.1273499	1.08
213.1388855	0.26
225.1639099	2.55
226.017334	2.23
227.0157776	0.16
231.3053894	0.33
235.1968994	0.14
237.0541077	0.14
239.1828613	3.07
240.0438538	0.79
241.2791138	0.18
243.5610657	0.35
247.2780151	5.04
248.2170105	0.56
249.2940063	1.85
251.3568726	0.23
251.9585266	0.07
253.2427368	0.92
253.9935608	0.91
257.0565186	0.16
265.1862183	0.69
267.3955383	0.49
268.1834412	0.36
269.289856	0.38
275.2576294	0.46
285.0835571	0.05
293.3450317	1.86
295.4769287	0.50
296.1818848	0.33
311.282074	12.93
312.3913574	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3072
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
138.1377258	0.03
151.2513580	0.04
197.9806366	0.15
216.0491180	0.02
229.2494812	0.04
232.3535614	0.04
264.6924133	0.04
299.1911011	0.06
301.2248535	0.02
308.6670227	0.30
318.2756042	0.05
319.5535889	0.02
339.3101807	100.00
340.1748962	0.01
373.4396362	0.03
376.4077454	0.03
399.2835999	0.03
406.6179810	0.06
414.3720398	0.06
419.6069641	0.07
421.0527039	0.06
430.7274475	0.06
443.3776245	0.06
448.1998596	0.05
449.4779663	0.05
462.2466431	4.81
463.2703247	0.16
480.9396057	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.1455
Annotation	Polygalatenoside D
Peak:m/z	Relative Intensity
144.7674561	0.19
152.0040131	13.67
162.9726105	1.00
167.0772095	100.00
208.9850006	0.34
220.8659973	0.12
280.0068054	0.08
293.2582092	0.09
307.2431335	0.77
341.6855469	0.10
359.4147949	0.32
382.1740417	0.12
384.9071960	0.17
388.4867554	0.15
415.1017761	0.28
423.1420898	0.07
429.3016663	0.72
431.4225464	0.10
441.2074890	0.13
443.1590881	0.07
445.3699646	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	719.182
Annotation	Arabelline
Peak:m/z	Relative Intensity
215.2557983	0.08
225.9023743	0.03
264.1867981	0.09
281.0745544	0.03
292.2296143	0.03
294.3561707	0.03
297.4073486	0.01
306.6668701	0.08
307.3757629	0.03
309.3500977	0.19
315.1577759	0.09
325.2072144	0.02
327.4279785	0.08
331.3700562	0.04
335.3370056	0.56
339.3198242	0.16
351.1633911	0.60
353.1316223	1.68
354.2037354	0.02
357.3820190	0.07
359.4149170	0.01
367.3196411	0.28
371.4205322	0.08
384.8348999	0.13
387.2769165	0.04
405.0042725	0.02
407.4625854	0.03
408.4871826	0.03
425.1806641	0.03
431.1822510	0.04
432.6082764	0.05
434.3153687	0.04
441.1754761	0.04
445.1072998	0.02
449.1776733	0.02
451.5083008	0.06
462.1926270	0.04
473.0626221	0.02
477.1752319	0.04
479.3905029	0.02
483.3500977	0.29
495.2816772	0.34
497.3071289	0.02
498.3829956	0.05
501.3871460	0.10
506.3371582	0.02
508.1995850	0.05
509.0732422	0.03
519.2288818	0.04
520.5296021	0.02
521.1909180	0.02
522.3515625	0.02
523.2233887	0.01
525.3560181	0.12
527.2764893	100.00
527.9310303	0.19
538.6884155	0.04
539.3837280	0.16
540.1893311	0.04
544.0009766	0.02
545.2554321	0.42
549.3643188	0.07
553.1305542	0.02
556.4260864	0.02
557.1931152	0.04
565.1965332	0.02
573.2387085	0.09
574.0225220	0.11
575.4883423	0.07
577.6166382	0.02
579.4971924	0.06
580.2671509	0.04
591.5574341	0.08
600.3062134	0.01
605.4642944	0.16
606.2835693	0.06
611.8806152	0.02
623.3518677	0.14
625.6853638	0.02
630.8528442	0.03
633.3908081	0.15
634.3627319	0.18
643.2536011	0.03
651.2109985	0.18
667.2313232	0.01
670.0726318	0.09
670.7935181	0.14
672.5108032	0.06
674.2612915	0.16
675.3038330	0.09
681.5895386	0.06
682.2706909	0.09
686.0283813	0.01
687.7331543	0.11
693.5426636	0.04
696.6963501	0.15
697.5762939	0.11
700.0438843	0.16
701.1311646	0.08
710.3717651	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0717
Annotation	Gerfelin
Peak:m/z	Relative Intensity
93.1812897	0.04
96.9046478	0.21
101.1007538	0.06
109.0561218	0.79
121.0488129	0.33
123.0720520	0.31
124.9683685	3.04
127.0414429	0.04
134.9956970	0.58
137.0409241	1.64
138.0956421	0.02
138.9966888	0.53
149.0435791	0.05
151.0509338	1.64
155.0555878	0.05
159.0301819	0.63
159.7142487	0.06
161.1101685	2.84
162.1132507	0.08
162.9839172	0.22
163.9778290	0.60
165.0781860	2.97
167.0128326	1.54
173.1693115	0.07
174.2322388	0.03
175.1300659	0.62
177.0516357	0.04
179.0858459	11.55
179.9676056	0.05
180.8995667	0.05
183.1451569	0.05
184.9639282	0.11
185.9804993	0.83
187.1540527	0.86
188.0396729	0.61
199.0830688	0.11
201.0487976	0.63
203.0567627	8.92
205.0427551	32.22
209.1473999	0.02
212.0603943	0.05
215.3051758	0.06
216.0932617	0.02
217.1952820	0.28
220.9697266	0.26
227.0956116	1.75
229.1202087	0.25
230.0204773	0.42
230.9928894	7.30
231.6247253	0.04
243.2363586	0.06
245.1163330	100.00
247.1967163	5.02
253.1145020	0.04
271.0602112	4.56
289.1903381	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.1501
Annotation	Scorzodihydrostilbene C
Peak:m/z	Relative Intensity
143.1127014	0.14
151.0871735	0.04
181.2273560	0.29
188.1750183	0.14
197.2675323	0.18
205.2169800	0.06
219.3004150	0.10
223.3834839	0.10
224.2062683	0.05
227.1246033	0.03
240.2410278	0.09
243.0690308	0.21
281.3270874	0.08
300.3728943	0.17
318.8839722	0.07
324.0076904	0.04
327.3985596	0.14
331.0610962	0.06
336.8384094	0.04
341.0501709	0.03
342.1821289	0.06
346.2998047	0.04
351.2562256	0.09
357.4554138	0.06
359.1909790	0.09
368.3867798	0.04
369.4036560	0.08
370.2775574	0.03
373.2455750	0.13
374.3390503	0.10
385.3861084	0.15
386.4192505	0.08
387.1136780	0.73
389.2437439	100.00
390.4294739	0.05
397.1876526	0.05
401.1763000	0.18
402.4376831	0.04
413.3787537	0.10
414.8431091	0.42
415.5097961	0.21
416.2789612	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	237.1117
Annotation	DIHYDRO-beta-TUBAIC ACID
Peak:m/z	Relative Intensity
87.10435486	3.80
103.0545197	2.13
106.7924805	1.30
109.1933441	4.15
110.8802795	1.78
121.1222839	0.91
124.8835297	2.38
134.9480133	3.27
139.0181427	1.91
141.2127838	1.91
145.2205048	4.44
148.924118	3.49
160.9039917	3.19
163.0848541	2.91
164.9864655	4.80
166.1795807	1.01
166.8850555	6.62
169.0888519	7.42
174.8343353	3.61
177.1188049	6.03
178.2476349	2.28
179.1356049	4.88
180.8282318	26.54
182.7318268	0.87
187.1089325	1.40
188.991745	3.53
190.4760895	2.64
191.2067108	3.06
195.8697357	7.86
201.2180634	17.62
205.2349396	2.24
208.9309998	4.34
210.956192	2.39
214.0328827	2.30
219.0988159	100.00
220.1580811	2.08
221.0690918	9.07
221.7844238	2.48
227.758728	22.21
237.0279541	8.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2078
Annotation	Unknow
Peak:m/z	Relative Intensity
125.2830734	0.11
129.1560364	0.08
130.8938293	0.06
136.1939850	0.03
137.0225830	0.07
143.1123352	0.39
153.3162231	0.04
158.8746338	0.79
161.0669556	5.55
169.3649597	0.07
174.9713745	0.05
178.9910278	0.75
183.1060791	0.32
197.2608185	0.03
205.1863098	0.03
206.9640656	0.05
209.3648529	0.16
225.1753387	11.78
231.1615753	0.04
247.1679077	0.07
249.3163147	0.16
252.3745728	0.02
253.4156799	0.13
267.0630798	0.32
270.0424194	0.02
271.3299561	0.09
289.2286072	0.05
291.1596680	0.10
297.1566772	0.09
309.3034668	0.43
315.0995483	0.04
325.3248901	0.05
334.5189209	0.17
337.3026428	0.09
339.0809937	0.04
343.2527466	0.04
357.6047974	0.08
369.1539612	0.07
373.5572205	0.13
375.5843811	0.07
385.9960938	0.30
387.2388000	100.00
400.4646912	0.03
401.2988586	0.09
403.2871399	0.09
415.3154297	0.08
418.6531982	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1296
Annotation	2,3-Dimethyl-3-hydroxyglutaric acid
Peak:m/z	Relative Intensity
101.0236130	3.45
101.9688034	0.09
102.9764099	0.22
108.8506012	0.05
113.0190811	9.48
114.0157318	0.88
114.9162750	0.14
123.0276184	0.04
124.8042450	0.02
128.9453278	0.28
130.0850372	0.01
131.1095428	0.05
139.1639709	0.07
141.0953827	0.02
144.2027893	0.23
145.1314087	0.03
147.0855408	0.01
157.0224915	0.60
163.1319885	0.02
169.0296783	0.10
171.0712280	0.02
172.9919128	0.06
175.0286102	3.83
176.0723419	0.42
186.9677124	0.10
189.1529236	0.10
191.0764313	0.80
192.2817078	0.03
193.1236877	0.12
205.2100372	0.40
207.0881042	0.06
215.2905273	0.05
223.2693481	0.16
224.4700317	0.03
231.1647644	9.52
232.1365356	1.11
233.0593872	0.07
243.2322998	0.39
249.1004639	100.00
250.1177368	11.83
258.0535278	0.04
263.8613281	0.07
265.1116028	0.03
267.1601562	2.76
268.1481323	0.33
275.1502991	0.31
291.2117004	2.00
292.1642456	0.40
306.2039185	4.26
307.1688232	0.02
308.2808533	0.01
315.2436829	0.53
316.3148499	0.23
333.2192993	17.44
334.2536011	3.39
339.2666016	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	705.1666
Annotation	Kaempferol 3-[2''',3''',5'''-triacetyl-alpha-L-arabinofuranosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
215.0839233	0.13
264.9664917	0.02
293.9311218	0.02
295.0267944	0.03
297.2692566	0.01
307.1755371	0.04
311.3746338	0.06
321.3275757	0.18
322.2875366	0.02
333.1482544	0.01
339.2249146	1.24
340.2318115	0.24
351.1563110	1.60
352.2686157	0.15
353.2090454	0.32
357.4380493	0.01
369.2336426	0.06
371.1005249	0.04
403.3815308	0.05
404.1346436	0.01
417.4251709	0.01
419.2001343	0.01
425.6060791	0.06
441.1711426	0.02
449.2801514	0.01
469.2738647	0.08
470.4383545	0.01
471.5645752	0.02
473.2486572	0.01
485.5477295	0.05
487.4558716	0.18
495.5486450	0.05
496.5620117	0.03
511.8435059	0.04
513.2685547	100.00
514.2508545	14.70
514.8803101	0.06
519.3494873	0.01
522.8182373	0.04
524.5991211	0.08
530.4116821	0.04
531.7517700	0.06
543.4025269	0.07
552.2276001	0.01
553.3737183	0.04
558.6004028	0.01
566.6392212	0.02
611.5031738	0.01
615.7846680	0.02
617.3795776	0.08
618.3546753	0.01
621.5892944	0.02
625.2661133	0.02
659.1801758	0.01
661.3078003	0.04
673.0824585	0.08
676.2734375	0.02
687.2107544	0.20
696.5708008	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1818
Annotation	Lactulose
Peak:m/z	Relative Intensity
218.7514648	0.12
281.3251648	0.37
309.4278564	0.03
338.7536011	0.18
362.2375488	5.89
363.0812378	7.48
381.1711426	9.80
412.2077637	0.05
420.0485229	0.02
453.5065308	0.11
495.4967651	0.06
525.2341919	26.94
525.8763428	0.26
533.1632690	11.89
533.8001709	3.05
543.2658081	100.00
572.2532959	0.15
573.6643677	0.04
585.2889404	0.06
615.1247559	0.31
645.3401489	0.10
687.2660522	0.10
688.2809448	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	247.13
Annotation	Glu Val
Peak:m/z	Relative Intensity
83.00558472	0.80
93.05288696	0.06
94.98976135	0.25
96.99015808	0.28
105.0886078	0.06
106.0798645	0.22
107.0374756	0.26
111.061142	0.17
115.1141663	0.25
118.9803009	0.20
121.0480957	1.55
122.9226532	0.26
125.061142	0.06
127.1116333	0.23
130.3279266	0.39
131.0311584	0.18
133.0921936	0.33
135.1083527	0.56
137.0652161	0.42
138.9110107	0.22
141.3083801	0.08
142.9907684	0.26
145.0530548	0.60
147.1051788	1.46
149.0409698	1.74
150.0077057	0.50
151.4396973	0.09
152.9596863	1.26
157.2402649	0.21
159.1029053	1.63
160.1126862	1.11
161.2550049	0.43
163.0052338	2.96
165.0695343	0.33
170.2166443	0.18
171.0757751	0.10
173.0695038	3.67
175.1146698	0.40
176.1421051	0.06
177.1117249	0.33
181.38974	0.18
183.1305695	3.35
185.1891327	2.07
187.1603546	17.54
189.085144	0.42
190.0462799	0.25
191.0618896	17.96
193.2249603	0.49
196.0007782	0.23
201.1345062	14.38
202.2650909	0.09
203.1024933	3.03
203.7587433	0.23
205.1864929	1.78
211.136734	5.50
214.0007019	0.28
215.2700348	0.20
217.0535126	0.07
219.0656433	1.62
227.3759003	0.05
229.11763	100.00
230.108017	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.1873
Annotation	Rupestrin B
Peak:m/z	Relative Intensity
195.0526123	0.09
215.2690735	0.04
251.2176361	0.15
261.2042236	0.02
280.2951050	0.04
295.2673340	0.05
307.0083923	0.45
308.3456421	0.11
337.2376099	11.44
339.0921631	0.04
342.3020630	0.06
343.4705811	0.03
353.1513672	100.00
354.1177979	0.21
367.1577148	0.11
396.1162720	0.02
410.2251587	0.09
449.0504761	0.05
452.0297241	0.04
456.4104004	0.04
459.3546753	0.02
473.1538086	0.02
477.2392578	0.08
478.2612305	0.19
486.1683350	0.04
489.2764282	0.03
493.4327393	0.08
499.3294678	0.78
500.3181152	0.06
502.2315674	0.03
504.2920532	0.15
511.5070190	0.07
512.1427002	0.03
517.4497681	0.06
519.2089233	3.18
520.3099365	0.32
521.1832886	0.09
522.6485596	0.15
528.5404663	0.05
530.3710327	0.09
531.4404297	0.03
539.2005005	0.35
542.3049927	0.04
547.5263062	0.04
557.2150269	0.04
560.0171509	0.09
566.1502075	0.05
574.8178711	0.06
583.4497070	0.10
591.3224487	0.03
606.2980347	0.06
609.2780151	0.03
610.8857422	0.09
613.3040771	0.04
615.3574829	0.10
619.3995972	0.03
626.1026001	0.03
629.2876587	0.24
631.5288696	0.09
632.2479858	0.02
634.4396973	0.02
639.4011841	0.07
642.1628418	0.06
647.2678223	0.23
648.3165894	0.22
660.4786987	0.12
663.8707886	0.03
672.9801636	0.43
674.2098389	0.38
677.0970459	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.1754
Annotation	Raltitrexed
Peak:m/z	Relative Intensity
148.0418549	100.00
148.9514771	2.55
149.9352417	0.87
160.8221741	0.07
165.0504303	0.86
179.0204163	4.23
183.0195923	11.03
186.6682129	0.18
195.6131897	0.04
196.8705444	2.83
222.9906006	0.19
239.3371735	0.14
240.4715881	0.12
242.3412476	0.07
252.1927185	0.12
255.2947083	0.06
255.9347534	0.10
268.5785522	0.16
276.9992065	0.18
294.9599304	0.07
296.3721619	0.49
297.3582153	0.06
304.8564453	0.29
310.1070251	0.10
312.3888550	0.28
323.0117798	0.36
326.0222778	0.07
327.0229492	0.04
330.2437744	0.06
341.1148071	4.01
344.8429565	3.98
352.9931641	0.05
355.1324158	0.09
358.9330444	3.11
363.1934814	0.12
372.1040344	0.21
374.9310303	0.03
400.0595398	0.09
400.9201355	0.17
403.2953186	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.282
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
196.0640564	0.09
227.0483704	0.07
244.8850708	0.06
257.2794800	0.04
309.2451172	0.03
311.6608887	0.03
333.1162720	0.14
334.1911011	0.14
343.3502197	0.12
350.3305054	0.03
355.3977051	0.13
384.3139038	0.08
390.2332153	0.14
393.0004272	0.05
402.3967896	2.49
405.1030884	0.05
413.4337158	0.03
416.4308472	0.19
418.4057617	0.16
425.2644043	0.04
444.3426514	2.30
445.8271484	0.38
446.5485229	0.17
448.3943481	1.27
459.4258423	0.09
460.5626831	0.20
462.1890869	0.03
474.7116699	0.07
476.4462280	0.41
480.1956787	0.04
488.4221802	3.11
490.2917480	0.10
495.4838257	0.04
496.2998047	0.05
497.3641968	0.02
499.5270386	0.51
502.1740112	0.12
507.5499268	0.07
508.6216431	1.52
520.3234253	10.26
521.2827759	0.04
532.4351196	0.03
539.7112427	0.05
541.4091797	1.24
543.7935791	0.25
555.2975464	0.07
557.4885864	0.27
559.3552246	0.55
572.4181519	0.06
573.4588013	0.71
578.5664062	0.04
579.4841919	0.22
582.3132324	0.08
583.4757080	0.66
585.3865356	9.16
586.3654175	0.04
589.6091309	0.12
599.4313354	0.34
600.4915771	1.37
601.4612427	1.86
603.1075439	0.05
604.3050537	0.02
609.2495728	0.11
615.3496704	0.06
617.3787231	100.00
618.0056152	0.32
627.4044189	12.45
629.0747070	0.16
631.4870605	0.26
632.5073853	0.21
633.6309204	0.22
641.3786011	0.30
644.5018921	2.51
645.3900757	28.77
646.0038452	0.05
649.6189575	0.04
659.3492432	54.70
660.0772705	0.24
662.0877075	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2879
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
123.0910263	15.16
133.1389618	2.61
135.1731567	8.50
148.8962555	9.25
151.1992798	16.19
156.9976501	5.36
168.853714	5.90
175.0432434	17.99
181.2539673	4.54
188.8182678	10.40
190.9698486	4.29
194.2158661	3.15
203.2761078	6.99
214.256958	16.16
228.9132538	11.97
252.0239258	8.21
256.2077942	7.25
264.0610046	6.56
266.3195801	2.34
267.6181946	4.25
281.2594604	10.65
285.7265015	3.49
291.885498	8.97
303.4431763	3.99
323.6040649	18.06
332.4663086	9.54
336.026825	15.91
337.5257568	11.16
339.2582397	30.05
341.0630493	9.20
348.6517334	8.99
352.201355	2.34
357.2364502	9.58
363.2830505	9.40
366.3008728	21.49
371.3939514	11.13
373.1863403	14.07
377.3251648	4.72
380.7966919	10.67
385.63797	3.46
390.5658264	16.28
391.2560425	7.54
396.4402771	3.98
398.5055542	24.42
408.2874146	100.00
409.1807861	10.97
409.8530579	10.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0561
Annotation	Quinic acid
Peak:m/z	Relative Intensity
58.8907471	2.46
61.0144844	0.91
66.8462677	0.14
70.9266205	6.00
80.9641342	2.22
83.0546799	1.82
84.9546814	81.36
86.9824905	14.82
92.9244843	49.09
96.0989227	0.48
96.9861908	0.21
98.9934082	5.29
101.0976257	0.33
109.0341034	18.31
110.9622803	38.05
112.9484100	0.27
114.8407593	1.13
118.9223785	0.16
126.9245453	100.00
128.9607849	2.50
137.0205078	2.18
143.0137787	2.71
144.8041687	1.39
146.9816437	0.33
153.0388641	4.49
154.9509888	8.61
171.0578766	26.03
172.9901581	75.94
190.9299164	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1354
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
160.8525543	0.11
167.1194305	0.04
174.9648590	0.09
177.8213348	0.05
179.0464783	0.19
186.9782562	0.12
188.0583191	0.07
201.1491699	0.09
202.0635071	0.09
203.0307617	0.77
205.0933075	0.87
207.0586243	0.14
219.2535706	0.05
221.8448486	0.12
227.2040405	0.15
229.0626526	0.11
237.1007843	1.33
243.1798401	0.08
245.2232819	2.13
247.2576752	0.10
249.2183228	0.08
255.0051575	0.34
261.0841064	0.48
268.2980957	0.05
269.1931763	0.53
271.1843872	0.19
273.0751953	2.14
275.4899292	0.15
285.2588501	0.13
287.0858154	7.54
289.1897888	19.68
290.4296265	0.14
292.9763489	0.09
299.1120605	4.38
305.1093750	0.16
309.1968994	0.07
313.3735962	0.09
315.2516479	0.07
324.7801514	0.09
327.1918945	0.08
329.2297363	0.55
330.0303345	0.03
331.0945435	1.04
339.1682739	0.51
340.5830078	0.16
349.0419312	0.14
352.2198486	0.05
353.4129639	0.23
357.9804077	0.10
363.1996460	0.09
364.3616943	0.04
367.2816162	0.35
375.9337769	0.06
377.1474609	0.08
381.2152710	1.34
389.2512207	0.13
395.3734131	0.08
396.6376953	0.05
397.3164062	0.07
403.2409668	0.22
405.3767090	0.15
407.1774902	51.85
408.4014282	0.14
409.3118286	0.82
410.4513550	0.10
411.4201660	0.18
413.1055298	0.12
414.4756470	0.08
415.2872925	0.40
415.8930664	0.06
417.3914795	0.06
419.3660278	0.04
423.1167603	0.30
425.1758423	100.00
426.4979248	0.19
428.1953735	0.15
429.3710327	0.32
430.2277832	0.07
431.2906494	0.12
433.1861572	0.53
436.1594238	0.25
437.1931763	0.10
447.3536987	0.05
449.2988281	1.03
451.2684326	26.23
452.2812500	0.10
454.1491699	0.08
455.4185791	0.34
457.5213623	0.04
466.4246826	0.15
467.2550049	1.38
471.2871094	0.14
478.7851562	0.12
479.8496094	0.33
481.1551514	0.26
483.3268433	0.10
491.3745728	1.02
493.1608276	0.05
494.4905396	0.22
498.3059692	0.14
500.4251099	1.99
501.3344116	0.40
501.9727173	0.05
504.9193726	0.09
508.5429077	0.04
511.6359253	0.03
515.1942139	0.04
515.8109131	0.04
521.2920532	0.19
531.1071777	2.14
533.1309204	0.93
535.4083252	0.06
541.4618530	0.30
543.3958740	0.27
544.7150269	0.33
546.2438354	0.13
548.9744263	0.03
557.4664917	0.25
558.2630005	0.17
559.3363037	8.07
567.3515625	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.1067
Annotation	1-Caffeoyl-4-deoxyquinic acid
Peak:m/z	Relative Intensity
117.8941727	0.16
119.0161896	2.27
146.9970703	100.00
155.9895020	0.05
157.3664856	0.26
157.9998779	0.26
162.9588928	0.33
164.1138000	0.34
165.0605774	0.10
183.2611847	0.08
197.5202332	0.07
215.0889282	0.12
222.2839966	0.15
233.6574707	0.03
264.9336853	0.05
308.2019653	0.07
321.2572937	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.2196
Annotation	Unknow
Peak:m/z	Relative Intensity
205.4225616	0.03
245.2664948	0.08
249.0597382	0.08
262.3568115	0.07
263.0428772	0.19
276.9550171	0.20
289.2336731	0.57
303.1642151	0.05
305.1850586	1.22
307.3666077	0.08
319.2502136	0.07
320.1780396	0.04
321.2416382	0.83
331.2919312	0.02
337.2169189	0.83
339.1936646	1.19
341.5553589	0.04
343.1352539	0.11
349.1048889	0.21
351.1968994	0.06
361.2160645	0.15
363.2943726	0.02
365.1877441	0.02
376.7395020	0.02
377.4884644	0.02
381.2890625	3.23
392.1884766	0.13
393.3416138	0.28
401.3432007	0.17
404.8629761	0.05
409.1613159	0.17
421.2597656	0.85
422.9510498	0.07
439.3153076	0.42
449.3978271	1.04
452.2409058	0.30
453.3074341	4.93
461.3397827	0.05
470.8073120	0.14
471.4618530	1.39
481.2998047	0.53
491.3645020	0.13
493.3011475	1.16
495.7661743	0.02
507.3691406	0.20
509.3427124	0.79
511.2709351	0.62
513.3195801	0.23
525.3507690	7.66
541.3237915	0.48
543.3622437	13.23
553.3878174	0.38
554.1212769	0.36
567.2412109	0.32
571.3423462	1.78
572.2814331	0.23
573.3191528	0.04
585.4168091	0.95
603.3993530	47.05
613.4988403	0.28
619.0393677	0.03
625.2831421	2.87
627.4707642	0.15
639.0825806	0.25
643.3742676	1.04
645.3809204	1.37
657.4168091	40.52
675.4102783	100.00
687.7680664	0.09
699.4375000	0.19
703.4703979	1.36
705.7086792	0.07
716.2836304	0.12
717.2913208	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.2663
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
190.1256866	0.12
200.8933716	0.10
208.9525604	0.06
219.0322418	0.09
244.9759369	0.25
285.3585815	0.07
294.1221008	0.03
297.3766174	0.11
313.2732849	0.12
319.2875366	0.60
320.2890015	0.34
323.1374512	0.21
355.5181885	0.37
366.3699341	0.09
367.5301514	0.10
374.2543945	0.05
403.1109619	0.14
431.3251343	0.04
451.2121582	0.07
452.2004395	0.08
463.2237549	0.20
467.2290039	0.05
475.0530396	0.07
476.3633423	0.13
478.5711060	0.05
485.3781738	0.14
488.7069702	0.06
513.2818604	0.09
531.3768921	0.40
532.1116333	0.26
535.4537354	0.03
539.4784546	0.27
540.6182861	0.12
549.4015503	0.06
552.2593384	0.57
557.3336792	1.17
558.2745972	0.42
563.8666992	0.05
564.6698608	0.06
569.6930542	0.04
571.1711426	0.19
581.4794312	0.54
582.6873169	0.30
583.4448853	0.33
584.4264526	0.27
585.5000610	0.07
597.4317017	0.16
599.3680420	43.94
600.3812866	19.73
601.6210327	0.13
602.4031982	0.29
603.3045044	0.03
607.6920166	0.05
615.9235229	0.08
619.1434937	0.03
625.5491333	0.51
626.4566040	0.14
627.3562012	0.15
629.2165527	0.08
630.5277100	0.23
631.6772461	0.58
632.5601196	0.28
640.4321899	0.25
643.3008423	100.00
644.3463745	40.97
645.0737915	0.24
646.1931763	0.07
658.0860596	0.05
658.8061523	0.05
660.2955933	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.2212
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
91.2224884	0.19
93.0925293	0.88
95.15727234	0.37
108.9144592	0.68
111.1591263	0.19
113.348732	0.10
115.0370178	0.19
122.8919525	0.61
125.0078278	0.63
127.0132828	1.38
129.2233582	1.22
133.0629883	0.60
135.1460876	0.91
135.9719543	0.13
136.8884277	1.74
138.9812622	2.65
140.7020111	0.56
142.9763489	3.73
149.0666351	1.46
151.1150055	1.30
152.9092712	0.44
155.0083923	0.48
157.0270996	0.18
162.0344696	0.81
163.1751709	0.33
163.9035034	0.19
165.2102051	0.58
168.6922913	1.31
171.0366516	0.50
173.009201	1.14
174.9742432	1.25
178.9908447	0.99
181.0693665	0.74
183.2476654	1.20
184.1373901	1.01
185.1562195	0.64
186.739563	0.34
188.0486145	0.32
192.8157806	2.00
195.0481262	2.93
197.0549927	1.84
199.2102356	0.83
201.2017365	1.25
203.2156067	0.21
205.0518188	1.07
209.2731934	0.27
211.1684875	4.07
213.1457825	2.00
215.1309509	1.22
216.9344788	0.20
221.3590088	0.74
223.2540283	1.73
225.1729431	1.21
227.1217346	0.50
229.2384949	0.41
231.2407532	2.31
233.2572632	1.33
235.2706909	2.27
237.1021423	0.49
239.2366028	4.35
240.8966675	1.18
247.0763855	2.20
249.4516296	0.25
251.2763672	1.27
253.2052307	8.96
254.2151489	1.14
255.225708	2.11
257.1772156	0.49
263.9761047	0.43
265.2691345	3.28
266.3154297	0.47
267.2935486	0.50
268.1120605	0.16
269.1936646	0.81
275.2611084	14.38
277.3528442	0.56
278.9954834	0.40
283.2221375	4.63
287.7909851	0.15
290.0447998	1.25
292.2026367	3.06
293.2143555	100.00
294.1343994	0.59
295.1167297	0.74
299.5705566	0.30
301.7561035	1.09
311.3694458	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.225
Annotation	Citbismine C
Peak:m/z	Relative Intensity
280.8773193	0.21
336.9845276	0.06
338.1209717	0.07
339.4901123	0.15
341.1675415	100.00
378.1317749	0.07
419.3294067	0.05
457.2933350	0.11
503.0690308	0.04
567.2808838	0.07
636.7304688	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.27
Annotation	Unknow
Peak:m/z	Relative Intensity
162.9699707	8.82
164.1390839	0.12
205.1697388	0.71
232.9830933	0.07
234.2912598	1.23
235.0091248	4.74
248.0415802	0.17
252.7463226	0.21
264.9240112	8.98
281.4814453	0.11
289.1321411	0.39
294.8222656	0.22
301.3698425	0.16
307.1530762	2.26
324.3731689	1.25
325.1741333	10.48
326.0916138	0.19
337.3207397	0.11
339.3090820	0.25
340.2814331	0.30
357.2091675	0.40
358.1032104	0.04
371.3024292	0.46
383.2900391	0.93
399.5186157	0.08
401.1614380	1.09
441.3448486	0.26
446.5266724	0.07
457.6232300	0.08
461.2354126	0.24
466.1205444	0.11
500.5108643	0.09
504.8604126	0.17
517.1928711	100.00
517.9408569	0.14
519.3552856	0.32
533.2460938	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2708
Annotation	Ixerisoside J
Peak:m/z	Relative Intensity
175.1216736	0.04
178.9887238	8.61
179.9239044	0.13
191.2108917	0.02
220.0814819	0.01
225.1100922	0.60
226.0285645	0.03
230.1844788	0.02
243.1689453	0.02
245.3264465	0.10
287.1864624	0.40
289.1615601	0.08
302.3529663	0.05
311.0469971	0.06
330.4791870	0.03
331.3271484	0.02
338.9822388	0.05
349.2280884	0.42
350.4298706	0.08
355.0475464	0.04
358.5164795	0.02
367.3805542	100.00
368.3073730	5.19
381.3853760	0.04
395.3079834	0.33
401.2737427	0.09
405.6125488	0.02
406.4065552	0.05
407.2930298	0.03
409.1249390	0.91
410.3106079	0.08
412.0021973	0.04
412.9255371	0.02
415.3225708	0.04
418.6902466	0.17
423.4748535	0.14
424.2351685	0.06
436.0598755	0.07
438.8188477	0.26
449.0106201	0.04
450.9754639	0.12
465.6970215	0.05
469.1293335	0.66
470.2135620	0.03
482.3370972	0.02
491.2973633	0.30
493.3943481	0.02
499.4392090	0.14
500.2937622	0.08
511.3441772	0.05
515.4390259	0.02
521.3836060	0.05
527.8945923	0.20
529.0632324	5.85
529.9557495	0.78
530.6154785	0.03
532.6595459	0.11
537.5011597	0.05
539.6085815	0.02
555.7877197	0.02
557.4013062	0.13
558.4118042	0.05
559.4601440	0.10
564.1515503	0.04
567.1869507	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	353.0878
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
106.9898529	0.06
109.1326447	0.06
111.2115021	0.02
115.1266022	0.03
127.0418243	0.16
134.0822144	0.29
135.0400391	7.58
155.0345154	0.20
160.9978943	1.16
171.041153	0.04
173.0149536	2.43
179.0211182	44.52
179.7764282	0.03
191.0508881	100.00
309.2581177	0.11
335.1740112	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1478
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.9770355	0.26
164.1105347	0.05
164.9377289	0.58
166.0351562	0.10
167.0001526	0.03
169.2090149	0.11
173.1615601	0.18
174.2026367	0.03
175.1152649	0.13
182.9392395	0.15
188.2491455	0.05
193.1973877	0.07
197.1342316	0.18
199.0063629	0.04
200.0747986	0.05
201.0996857	0.65
204.2291107	0.02
214.9728546	0.05
224.9515991	0.04
229.2520599	1.22
230.1315613	0.41
231.1575928	0.09
232.1632080	0.11
233.2767944	0.13
234.3530273	0.03
241.0227051	0.20
243.1953278	0.18
244.0088654	0.06
245.3678131	0.11
247.0923309	16.74
248.1071014	1.87
249.2469940	0.20
253.0833893	0.11
254.1613464	0.15
255.4228363	0.07
257.1575317	0.06
259.1628113	2.51
260.2749634	0.42
261.0961914	0.30
271.1878662	3.84
272.0395813	0.31
273.0817261	1.62
275.0947266	3.02
276.1903076	0.31
283.1006775	1.35
284.0875854	0.14
285.2264404	0.48
287.0092163	1.05
289.0689697	15.57
291.1007080	49.32
292.2102966	4.33
299.2139282	0.68
301.0683899	15.76
302.0112305	2.47
303.2476196	4.31
304.2825928	0.60
313.0980225	0.70
314.3453064	0.05
315.0031128	0.22
315.8254395	0.06
316.5829468	0.05
325.1383057	0.20
331.4580078	0.11
333.1784668	1.75
334.1307373	0.10
343.6232910	0.03
350.3202515	0.08
369.3366089	0.10
387.1997070	0.21
392.9406738	0.03
394.3125000	0.05
402.8250732	0.29
407.4935303	0.24
409.2043457	40.51
410.2309570	9.79
411.2227783	10.65
412.2735596	1.85
417.5916748	0.35
421.2481079	1.60
422.3358765	0.87
423.1514282	0.37
424.2766113	0.05
425.3894653	0.21
427.1134644	100.00
428.1713867	15.29
433.9415283	0.02
435.1295166	3.15
435.7337646	0.10
436.3479004	0.55
439.2105103	4.59
440.2495728	0.77
440.9735107	0.05
451.3058472	0.08
453.1091919	7.11
454.2182007	1.44
469.2394409	0.06
483.8819580	0.03
513.7318726	0.07
517.3703003	0.11
534.9497070	0.09
543.1654053	1.25
544.0134888	0.28
561.1320801	5.22
562.1928101	1.61
563.4293213	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	519.21
Annotation	Gossypol
Peak:m/z	Relative Intensity
174.1126251	3.07
211.1653595	10.53
237.0969391	10.43
239.4164581	9.07
286.2636719	3.07
293.1644287	5.30
306.1902466	11.01
321.8594971	8.84
323.1990356	15.49
332.0467529	7.09
335.3190308	4.51
337.3182373	15.29
339.2295532	6.52
378.2407227	13.12
381.5979004	17.00
385.4182129	4.89
386.0919189	3.92
399.0407715	3.42
421.1314087	4.14
426.8206177	14.26
427.7238159	8.90
431.2684326	3.46
456.6098022	8.24
458.0840454	2.72
469.9821167	17.20
471.3483887	6.35
473.9066772	7.29
478.5912476	5.61
482.9799194	19.06
484.2096558	3.78
486.0199585	11.12
501.177063	100.00
502.5206909	13.66
511.2754517	6.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	335.0771
Annotation	Altersolanol A
Peak:m/z	Relative Intensity
106.8812180	0.02
109.1336136	0.11
111.0375824	1.70
117.0892868	0.03
120.9461975	0.04
125.0234451	0.09
134.4332275	0.38
135.0810852	5.87
137.0505219	0.42
151.2489014	0.20
155.0760193	7.22
161.1146851	0.74
168.9983826	0.13
173.0076447	6.57
175.2850037	0.37
177.3049164	0.17
178.9794617	100.00
179.7612610	0.03
181.0217285	0.14
185.0895386	0.05
189.1492920	0.41
201.1738892	0.20
202.9213409	0.09
209.2758789	0.05
211.1569214	0.88
216.8902893	0.07
219.1631470	0.44
227.2495422	0.25
229.1932068	3.35
231.1507263	0.23
245.1958313	0.15
247.2123718	7.14
255.2608948	1.00
263.2714844	0.07
273.1473999	4.29
281.4371643	0.04
291.2150269	26.41
299.1538086	0.60
317.1863098	7.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.1429
Annotation	Isosamidin
Peak:m/z	Relative Intensity
114.9413300	0.12
123.0841141	0.09
125.0501709	0.03
137.0220032	0.27
139.0601807	0.10
140.8618011	0.10
149.0464172	0.19
157.1232605	0.08
167.0463257	0.03
169.1392212	0.05
172.0612488	0.05
173.2769165	0.07
175.0350647	0.03
187.0237732	0.15
189.1156616	0.02
191.1833191	0.19
197.0793152	0.12
198.0731506	0.10
201.0702209	2.65
202.9305573	0.04
205.1604309	0.11
207.1923370	0.14
209.1396027	0.19
211.4458923	0.09
212.9233856	0.46
215.4055481	0.08
217.1525574	0.17
221.0425262	0.32
225.0977173	0.21
227.4517517	0.13
230.7911682	0.06
232.9975281	5.39
235.1220093	0.10
243.1380920	0.37
245.0951538	0.44
249.2012024	0.06
255.0993347	0.16
263.1934509	0.28
265.1210632	0.10
266.9267883	0.13
271.2596130	0.48
275.0322876	0.05
278.5248413	0.16
279.3034058	0.41
283.2088013	0.20
284.7620850	0.21
288.1649170	0.30
289.2459412	0.21
291.0966797	0.11
292.3396301	0.17
293.3582153	0.21
295.2036133	0.06
296.8542786	0.91
297.8672791	0.23
299.0645142	0.15
300.2908325	0.07
303.0534668	0.10
306.2122803	0.19
307.1980591	0.16
308.4672852	0.03
309.2305298	0.15
311.2046509	0.17
313.3759155	0.17
315.5812378	0.18
318.6960449	0.17
319.4533386	0.09
323.2018127	0.27
324.6776428	1.12
325.3156738	6.08
326.1647949	0.16
327.2537537	1.78
328.3414307	0.18
332.8301697	0.20
334.2102356	0.05
337.1286621	1.64
338.2629395	0.10
339.1147766	0.05
341.0858459	0.78
342.4473572	0.40
345.2639771	1.33
351.2422791	2.59
352.2741699	0.04
355.1756897	100.00
357.0536499	27.35
357.6795349	0.29
363.3063660	0.15
367.0025330	0.17
368.6586609	2.02
369.3063660	10.49
371.9281006	0.05
374.9580994	0.12
378.1724854	0.08
386.0984192	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	747.1454
Annotation	Bisisodiospyrin
Peak:m/z	Relative Intensity
215.1827087	0.07
286.8789062	0.04
288.0692749	0.02
297.2144775	0.05
301.2305908	0.11
302.1855774	0.12
315.4917908	0.12
372.2955322	0.04
393.1262817	0.28
400.2061768	0.24
401.0137329	0.03
402.4505005	0.04
405.1363525	0.20
406.2534790	0.13
420.4132080	0.04
421.0730591	0.05
425.4548950	0.07
428.3842163	0.05
440.9418335	0.03
446.1260986	0.09
450.8101807	0.05
453.1088867	0.10
462.1155396	0.06
463.9906616	0.02
469.2363892	0.26
470.4261475	0.12
471.7355957	0.04
474.2825928	0.02
485.2630615	0.05
487.3427124	3.89
488.3038330	0.51
494.0203247	0.07
513.4124756	0.11
519.1635132	0.61
520.2428589	0.06
529.0236816	0.04
531.4482422	0.13
538.3652954	0.04
539.4292603	0.09
555.1686401	0.15
556.1670532	0.50
556.9439697	0.03
557.6211548	0.05
559.0667725	0.11
561.0149536	0.08
566.0972290	0.16
567.2424316	0.16
570.3098755	0.05
571.2687988	0.04
573.4473267	0.07
582.1317749	0.04
584.1619873	3.97
585.2040405	0.51
608.5963745	0.15
623.1907349	0.06
626.3132935	0.59
627.3012695	0.27
628.2340698	0.12
629.2326050	0.11
641.1002808	0.45
642.1787720	0.18
643.4361572	0.12
644.1333008	3.77
645.2503662	1.26
654.2180176	0.68
655.3156738	0.40
659.2963257	0.76
660.1502075	0.29
667.2344360	0.11
672.1340942	100.00
673.2066040	16.26
685.6736450	0.11
687.0424194	0.04
703.4931030	0.14
710.5392456	0.17
711.5792236	0.04
717.0205688	0.05
721.4414673	0.23
722.5756226	0.11
729.2453003	12.66
730.2252808	1.90
731.7062378	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	580.1318
Annotation	Unknow
Peak:m/z	Relative Intensity
167.1376343	0.37
172.8709106	0.25
177.0717163	19.89
178.0114441	0.57
180.9662933	0.10
191.3042908	0.07
201.0658722	0.14
214.3055420	0.10
215.1914520	0.12
227.7168427	0.05
233.1705017	0.39
235.2106934	0.14
243.2075195	0.02
249.0776978	0.13
251.1462402	0.24
255.1951141	0.28
255.8053741	0.02
275.1919556	0.22
289.0538940	0.11
291.2824097	0.31
301.0859375	0.10
302.0861511	0.10
307.4110413	0.37
313.2727661	0.23
313.9194946	0.13
325.0529785	0.06
342.1118774	0.06
351.5455933	0.11
355.3206787	0.59
359.3552856	0.10
365.3804321	0.03
369.0178833	15.17
369.9929199	0.07
378.1074829	0.03
383.0537109	0.03
385.3309326	0.20
387.2450562	1.64
388.2646484	0.45
392.4782715	0.04
399.4551392	0.03
405.0961304	0.03
409.4827881	0.60
411.2332153	0.27
417.4011841	2.98
418.2839966	0.97
427.0613403	0.38
428.2017822	0.16
433.5265503	0.09
435.3265381	0.16
439.1553345	0.15
441.1882324	0.25
442.4700928	0.10
445.6152954	0.09
453.2161865	0.17
475.0487061	0.10
483.6453857	0.04
486.6166382	0.10
490.1718750	0.08
509.3832397	0.04
513.5230713	0.08
514.8589478	0.04
535.2194214	0.06
536.2491455	0.21
543.3072510	0.18
544.3294067	0.10
547.3200073	0.04
561.3423462	0.44
562.1486206	0.28
563.5624390	0.14
571.9509888	0.09
599.0983887	0.20
602.2677612	0.09
614.3772583	0.17
615.1705322	0.04
616.3949585	0.12
725.0064697	0.21
746.0390015	0.27
747.3661499	0.13
759.3829956	0.06
773.0048828	0.11
789.1630249	9.09
790.1550293	30.13
791.1259766	100.00
792.1764526	0.65
813.1064453	0.09
819.1105347	0.04
828.5154419	0.04
830.9240723	0.12
849.5934448	0.13
923.8129883	0.06
937.9657593	0.22
980.9096069	0.50
981.6600952	1.67
982.6937866	7.08
983.3457031	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	354.09
Annotation	Unknow
Peak:m/z	Relative Intensity
106.7131958	0.01
107.4043427	0.05
108.9723282	0.03
111.0644302	0.07
117.0639420	0.02
126.9375610	0.10
133.2042236	0.08
135.0265961	6.48
136.1165466	0.26
137.2023621	0.02
143.2438354	0.02
155.0828400	0.13
156.2881165	0.01
161.1429749	0.73
162.1115723	0.02
173.0796967	2.53
174.1014557	0.10
179.0506439	42.01
180.1622467	1.48
191.0465393	100.00
192.1291504	3.11
309.4448853	0.01
310.2290955	0.02
335.2692871	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.0859
Annotation	Unknow
Peak:m/z	Relative Intensity
151.2055664	0.03
153.0298309	0.13
160.0071869	0.83
163.1860657	0.09
164.9120178	0.15
166.1296539	0.04
166.9016724	0.50
168.1453705	0.24
168.9224396	0.31
171.1946411	0.23
175.1304932	0.19
177.1726074	0.36
179.0671997	2.10
180.1535034	0.13
183.1784058	0.08
184.9437714	0.59
186.0434265	0.07
187.3396301	0.04
191.3983154	0.06
192.2954407	0.04
193.0221558	0.67
197.1281433	0.52
198.1400452	0.04
209.2264099	0.14
210.1781158	1.46
211.0757294	0.48
212.0932007	0.66
213.1120758	0.35
216.1995087	0.06
218.1553497	0.15
219.1460724	0.19
221.9674377	0.04
225.9784393	0.03
228.2135315	0.08
229.2205505	0.17
230.2128906	0.23
231.1340027	0.03
234.9474487	0.05
236.0940247	0.27
237.1486053	0.67
243.1256561	0.10
244.1460114	0.12
252.0421295	0.03
253.0543823	0.04
254.1253967	8.99
255.1860962	1.19
258.4097290	0.03
262.2641602	0.17
263.2438965	0.14
265.2667542	0.14
267.3137207	0.06
268.1734009	0.05
268.9909058	0.29
270.0390930	0.14
272.2657776	5.59
273.1873169	1.29
273.8999634	0.03
277.9425049	0.04
278.8095398	0.05
281.2144470	0.02
282.3407288	0.10
283.2755432	0.20
284.1183472	0.12
285.3295593	0.04
286.1511230	0.06
288.2020874	5.93
289.1649170	0.98
290.3651733	0.06
291.0397034	0.14
292.2229614	0.04
293.1823120	0.20
294.1929932	0.32
296.7126465	0.38
297.3417969	0.23
298.2599182	0.15
299.2307129	0.03
304.1916504	0.11
306.1525879	40.09
307.1442261	3.83
307.8011475	0.03
309.0648804	0.11
311.0513306	0.06
312.0643311	0.08
314.4932251	0.04
315.2086182	0.13
319.9007568	0.06
322.2097168	1.03
323.1644897	0.46
327.1788940	0.20
329.8399658	0.10
331.2733765	0.05
332.3036499	0.11
333.2654419	0.03
335.3656006	0.24
336.3641357	0.28
338.3485107	0.55
339.1179810	0.11
340.3355103	0.28
341.2034912	0.63
341.8684082	0.05
343.3508911	0.04
344.1260986	0.06
345.3163452	0.39
347.4620972	0.04
348.2948608	0.03
349.4576416	0.13
353.8336182	0.20
354.5082397	0.05
355.1833496	0.13
356.1279297	0.07
357.1900635	0.41
358.2270508	0.10
359.2838745	0.08
360.2297363	0.05
361.4080200	0.26
362.4300537	0.10
363.2853394	0.04
364.1469727	0.30
365.9710693	0.61
366.7382202	0.20
367.4024048	0.09
370.6173706	0.14
371.3631592	0.63
372.4017334	0.15
373.4998779	0.46
374.4044800	0.16
375.2493286	0.21
376.3195190	0.12
377.1588745	0.04
379.3741455	1.98
380.3220825	0.50
381.3389893	0.13
382.2390747	0.22
383.3586426	0.03
384.3324585	0.03
389.3009033	0.61
390.2818604	0.13
391.3204346	1.35
392.2786865	1.16
393.3634644	0.10
394.0596313	0.04
395.3776855	0.14
396.4569092	0.11
397.3039551	0.25
398.2543335	1.00
399.2972412	0.39
400.2677002	0.94
401.3224487	0.22
402.4136963	0.07
403.3400879	0.07
405.2954102	0.95
406.2865601	0.31
407.4398193	0.12
408.2532959	0.06
410.2584839	3.94
411.2958984	1.13
413.4859619	0.06
415.1614380	1.87
416.2290039	0.46
417.2477417	1.00
418.3498535	0.54
419.2203979	0.04
421.1516113	0.15
423.2647705	18.35
424.2788086	4.81
426.2056274	0.43
427.2274780	0.09
431.2877197	0.19
432.2420654	0.19
433.3260498	0.63
435.2293701	8.67
436.2232056	1.86
437.3329468	0.41
438.3626709	0.06
439.2349243	0.54
441.2628174	2.21
442.1311646	0.56
444.2489624	2.21
445.1404419	0.68
448.5583496	0.42
449.3008423	7.75
450.2826538	1.89
455.2338867	0.82
456.3400269	0.11
457.3254395	0.76
458.2980347	0.55
460.3759155	0.06
465.1808472	0.34
467.2408447	53.67
468.2911377	13.15
469.4500122	0.04
472.9803467	0.37
473.6473999	0.04
475.2244873	3.47
476.2417603	0.76
483.1455688	4.23
485.1431274	21.35
486.2649536	5.65
491.3812866	0.12
497.1851807	0.04
501.2023315	100.00
502.1780396	21.73
503.0617676	0.06
510.5255127	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	600.1185
Annotation	Unknow
Peak:m/z	Relative Intensity
259.3500977	0.05
261.0511475	0.07
292.8245239	0.16
293.4679260	0.03
337.1394043	1.91
375.2833862	0.10
377.0837402	0.03
404.1959229	0.06
421.2123413	0.21
429.5855713	0.10
507.9797363	0.06
516.2304688	100.00
516.8364868	0.22
538.3178101	0.03
554.3086548	17.99
581.9489136	0.05
584.8646851	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0721
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
90.9525452	0.04
106.9650803	0.17
108.3192673	0.51
109.1005402	8.00
119.3100281	0.03
123.1058502	0.16
135.2091064	0.05
146.1603088	0.05
151.1482849	0.47
153.0311890	100.00
155.2305603	0.07
159.0029907	0.05
162.1003876	0.12
175.8223114	0.07
192.9533691	0.04
212.8800659	0.03
219.2387085	0.03
242.9717102	0.04
247.2996826	0.05
257.3113403	0.08
268.1373596	0.04
269.1653137	0.12
271.0567627	0.25
280.3983765	0.06
281.3850098	0.04
288.1351929	0.03
296.3343506	0.16
297.1596680	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	747.2863
Annotation	Alangisesquin C
Peak:m/z	Relative Intensity
217.7326813	0.04
220.3309784	0.11
234.0840607	0.17
235.3435516	0.11
267.4010620	0.06
278.2580872	0.05
300.9954224	0.04
308.4694214	0.12
323.3743286	0.04
340.3317871	0.18
341.1402588	0.20
353.5883179	0.09
355.5501099	0.29
356.2728271	0.27
367.2985840	0.02
368.9993896	0.18
370.9786987	1.14
371.6389160	0.10
385.2284546	0.04
386.2262573	0.35
387.3230591	0.86
388.3446045	0.23
395.4852905	0.08
399.3187866	0.75
401.2260742	24.12
401.8377075	0.04
404.4743652	0.06
410.1174927	0.09
415.1733398	0.04
416.9770508	0.06
418.7908936	0.22
425.2219849	0.07
443.3370361	0.15
445.4691772	0.07
452.1351929	0.04
455.3036499	2.38
460.9152222	0.10
467.4031372	0.03
487.1944580	0.05
509.4017944	0.16
510.3175049	0.06
517.6106567	0.09
519.2536011	0.09
520.3987427	0.41
529.3617554	0.09
531.2780151	0.06
535.5584106	0.07
536.4391479	0.48
537.4400024	0.31
549.3153687	100.00
551.3787231	8.21
561.2934570	1.29
561.9299927	0.04
564.0578613	0.09
565.2873535	0.17
567.4156494	0.32
568.2175903	0.12
569.4364624	0.27
571.3331909	0.04
579.2989502	10.19
582.9062500	0.31
584.2747192	0.98
585.1481323	0.14
589.5076294	0.08
593.0524902	0.02
597.3020630	23.67
600.3632812	0.07
605.3025513	0.31
608.8402100	0.27
609.4770508	0.12
612.0523682	0.05
617.1041870	0.18
629.1168823	0.15
650.4757080	0.09
651.3627930	0.59
658.6587524	0.04
659.3707886	0.07
667.2576294	0.10
673.7403564	0.03
684.1287231	0.06
697.4674072	0.03
699.3515015	67.60
702.6372070	0.21
703.8506470	0.19
710.0857544	0.04
711.0972290	0.58
716.7784424	0.18
728.3256226	0.31
729.3168945	2.57
751.6199341	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
93.09715271	0.27
94.72666931	0.26
101.4367676	0.28
103.8863831	0.13
106.8787155	0.36
108.9662933	3.15
110.8358994	0.56
112.990921	0.84
119.0132217	0.70
122.8543625	0.97
125.0549927	1.04
126.9216461	1.60
129.1093292	0.36
132.9305725	0.20
139.0308838	0.82
143.0368042	0.48
145.1696625	0.16
147.1803284	0.45
149.2479553	0.36
151.0458527	0.22
153.0257568	0.46
155.1856384	0.47
157.0296936	0.26
162.9192352	2.01
166.1535339	0.20
169.0587158	2.80
171.1978149	0.78
173.0427094	0.14
175.2109222	0.34
177.0006714	0.78
179.0279083	0.42
180.1100464	0.24
181.1529999	1.73
183.1535645	1.22
185.0082092	0.50
187.175705	0.40
191.1712646	0.10
194.0926514	0.34
195.1387634	2.13
197.1245728	3.38
203.1175842	1.20
205.0604553	0.45
207.0726013	1.12
209.2174377	0.68
211.19104	1.61
212.8840942	1.20
215.152832	0.55
218.9859924	0.52
223.3683167	0.86
225.1481934	0.50
227.101593	0.64
229.0391846	0.36
233.256958	1.13
235.215271	1.47
237.2852173	0.70
239.0523071	0.88
242.59198	0.22
247.3133545	0.36
250.4939575	0.86
251.3087158	1.50
253.1867065	10.60
257.4752197	1.18
263.2086792	0.80
264.4957275	0.36
265.3909302	0.37
266.5030823	0.30
267.3032227	1.65
268.0841675	1.70
269.1919556	0.73
270.2126465	0.56
271.182312	0.34
275.273468	20.51
279.2041016	0.42
283.1983643	3.71
289.0380249	0.33
289.8045044	1.41
293.2178345	100.00
307.3531189	0.58
310.4917603	0.48
312.0932007	0.26
321.136261	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.19
Annotation	Fraxiresinol 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
163.0571136	0.08
164.0862427	0.01
173.2072449	0.01
175.1710358	0.40
176.1046600	0.02
178.0073853	0.04
179.9507446	0.01
189.1421814	0.03
190.2238464	0.32
191.1686707	1.12
192.1394958	0.11
193.2253113	0.76
195.1500397	0.22
203.1131287	0.05
204.0554199	0.03
205.1964874	0.53
206.4433746	0.01
207.5785370	0.21
208.2619781	0.96
208.9794312	0.08
216.3260040	0.01
221.9715881	0.80
222.7178040	0.01
223.3414154	0.05
229.1467896	0.06
231.3056183	0.02
235.2323608	0.03
236.5470123	0.03
237.3413391	0.04
239.3287201	0.03
247.5932465	0.02
263.2758179	0.01
264.8762207	0.02
266.1253662	0.01
267.0429688	0.05
268.6583862	0.01
270.3146362	0.04
282.2648926	0.01
287.4389038	0.01
290.2940674	0.01
291.2813110	0.02
293.2423096	0.02
297.3575134	0.04
298.2036743	0.01
307.3159485	0.01
309.4710083	0.04
311.2202148	0.02
313.1640625	0.25
314.3761597	0.42
315.1707764	0.04
323.2657471	0.37
324.3397217	0.43
325.4467163	0.08
326.2048340	0.08
327.2719727	0.24
328.4480591	0.48
329.3766479	1.09
332.2019653	0.09
337.5877075	0.04
338.7051392	0.04
339.4883423	0.17
340.4016724	0.19
341.2221069	0.31
344.3670044	1.45
345.4620361	0.03
346.1877441	0.01
347.2377930	0.07
349.2301025	0.01
353.3894653	0.36
357.3112183	1.30
359.2609863	100.00
363.2990723	0.01
368.8677979	0.13
369.8023682	0.10
371.4010620	0.35
372.3466797	0.91
373.3791504	0.29
377.2073975	0.03
383.3028564	0.53
384.2463379	1.57
385.2302856	3.77
385.8459473	0.02
390.2521362	0.02
391.3827515	0.03
399.0986938	0.05
400.3840942	0.16
401.3264771	0.36
403.2291260	64.08
403.8337402	0.12
405.4683228	0.01
411.2717285	0.02
427.4153442	0.02
429.4383545	0.02
433.3237305	0.70
445.4551392	0.09
459.2050171	0.08
468.1808472	0.12
475.0167236	0.10
480.4141846	0.07
488.0670776	0.02
489.3484497	0.15
491.5264893	0.14
501.0598755	0.08
502.1498413	0.11
503.4949341	0.06
504.3673096	0.02
505.4494019	0.41
517.0954590	0.03
518.2551270	0.29
519.3772583	0.70
520.2627563	0.18
521.3052368	0.56
529.5943604	0.02
532.2045288	0.26
533.0686646	0.01
534.2508545	0.02
535.3428345	0.03
536.5582886	0.05
546.3068237	0.10
547.2199707	0.41
549.4917603	0.10
550.5598755	0.03
551.5292358	0.02
555.3444824	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9797363	6.31
116.0271683	3.20
116.9708862	2.53
130.8955994	0.38
132.0945740	0.04
133.0922852	0.16
158.9427643	100.00
159.9550171	56.26
160.9183960	65.69
198.8457336	0.15
200.0606995	1.34
201.0834656	1.38
202.1167908	0.04
202.9859619	0.04
217.3160706	0.17
218.0356445	0.83
218.9818726	1.35
229.8786011	23.26
230.9239807	34.80
245.1006470	0.07
246.1141357	0.19
247.0798950	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	311.22
Annotation	trans-EKODE-(E)-Ib
Peak:m/z	Relative Intensity
94.96594238	0.46
104.9581146	0.39
107.0339584	0.40
108.9915771	0.56
112.6277924	0.33
114.9731064	0.82
120.476593	0.74
123.0675354	0.33
124.97789	2.10
128.9869385	1.55
135.2040863	1.79
137.1565094	1.28
138.6764984	0.81
141.0834045	0.66
142.8313751	0.26
151.0569763	0.52
153.1188965	1.12
154.9799957	1.78
156.7578125	0.34
160.8944397	0.43
162.9053955	3.91
165.1271362	0.46
167.0059204	0.35
169.1217651	0.59
171.2687531	0.52
173.1248627	1.52
175.1240082	1.14
177.3205109	2.01
178.9478455	0.85
181.2928467	1.12
183.2322388	0.98
184.1893311	0.99
187.1890869	0.35
193.0254822	2.16
195.1713867	1.61
197.0661011	1.93
201.0763702	0.42
202.0163879	0.18
203.1455383	1.15
207.2988586	0.45
208.9380493	1.23
211.1059265	2.77
213.2086182	1.05
215.2408752	0.99
219.0353699	1.53
220.5594482	2.85
221.1883545	0.10
222.2419128	0.32
223.2684326	1.22
224.0265503	0.22
225.2226562	7.55
227.3147278	0.20
229.1482239	0.18
232.7678833	1.55
235.2154236	0.79
236.3709717	0.37
237.1571045	3.47
239.3135376	0.72
240.3699341	0.46
241.6655579	0.73
242.315094	0.74
248.2990723	0.44
251.2939453	2.55
253.1733704	4.66
255.2789307	3.17
257.2269897	1.09
263.4050598	1.75
265.0909424	10.39
266.594635	0.88
267.2866211	0.84
268.5393982	0.48
269.5388184	2.16
270.3474731	1.14
275.1295776	14.05
279.21698	1.09
283.0650024	6.71
284.0138245	0.29
293.2140503	100.00
294.0198975	0.80
295.3858948	0.53
296.2240601	1.36
302.1264343	1.33
310.4185486	0.31
311.1316833	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3299
Annotation	Unknow
Peak:m/z	Relative Intensity
245.3403320	0.03
300.1586609	0.03
361.2952271	0.05
363.2562866	0.08
391.5358276	0.03
399.1869507	0.03
402.1957397	0.03
417.3624268	0.03
425.3926392	0.03
475.4822998	0.08
487.4251709	0.06
518.6011963	0.07
564.3339233	0.17
577.5729370	0.03
592.7479858	0.09
595.4771118	0.11
606.6178589	0.25
608.4426880	0.05
610.5772095	0.03
611.6323853	0.07
625.0558472	0.05
638.3137817	0.04
642.5537109	0.20
643.4051514	0.89
650.4819946	0.94
651.4781494	0.69
655.7523804	0.06
658.1869507	0.02
669.5003052	0.05
670.6163940	0.17
673.0908813	0.02
682.4287720	1.65
683.5551758	0.07
687.0405884	0.09
687.7926636	0.03
690.4443970	0.12
721.0543823	0.02
727.5243530	0.07
729.4664917	0.30
732.2230225	0.08
745.6072388	0.57
751.5335083	0.04
755.5711060	0.36
756.6006470	0.03
757.2265625	0.04
771.7805786	0.16
773.4612427	100.00
774.1024780	0.43
775.6883545	0.05
787.4074097	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0902
Annotation	Glutathione
Peak:m/z	Relative Intensity
115.9971466	1.03
129.7946625	0.16
133.8326111	0.03
143.9193115	2.42
145.2464600	0.12
145.9060669	0.16
149.8220825	0.17
150.8225555	0.16
158.1520386	0.03
162.0449829	23.71
178.9700470	100.00
195.0831299	0.02
204.9661255	0.17
205.9908142	0.08
208.2446594	0.02
208.9775391	0.02
215.0796204	0.74
215.9840698	0.05
233.0046082	17.96
243.3840942	0.01
244.9339600	1.05
247.4820251	0.06
253.9172974	0.01
264.1863403	0.06
269.1469116	0.05
271.1936035	0.04
272.0623169	1.30
272.9736938	0.05
290.1302185	6.01
291.1465149	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1013
Annotation	Chlorogenic Acid
Peak:m/z	Relative Intensity
116.8407745	0.20
134.9061279	0.14
136.2477264	0.17
143.0833435	0.32
145.0133209	1.31
146.0302124	3.70
151.1296997	0.23
156.8330383	0.37
163.0400696	68.70
163.9457092	100.00
164.5525208	0.74
169.8486481	0.48
181.0771484	0.50
185.1439514	0.15
193.0244751	0.26
193.9287109	0.50
195.2619934	0.62
205.0773315	0.38
214.140686	0.45
238.1159058	0.26
239.2728882	0.58
245.0251465	0.42
246.3310852	0.44
290.2265625	0.14
291.1418457	0.61
293.4427795	0.44
294.3252563	0.63
297.2562561	0.74
310.2120361	0.30
311.1157227	0.17
315.0649719	0.80
320.3798828	0.56
321.2704163	0.57
327.3635254	0.33
337.1278687	0.87
338.1835327	0.96
339.0170593	0.95
347.6051331	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.2655
Annotation	Unknow
Peak:m/z	Relative Intensity
203.0644836	0.16
204.0015411	0.08
217.0160522	0.14
218.0338593	0.36
219.3962708	0.09
223.1782532	0.19
233.1793823	1.77
235.1192780	0.08
239.0447083	0.04
243.2291107	0.11
245.1716614	0.03
247.1918030	0.11
249.3811951	0.12
253.1641235	0.14
255.9665985	0.04
270.0499878	0.06
275.2095642	0.05
276.8015137	0.04
286.1804810	0.05
287.0496216	0.16
288.1348267	0.27
289.1871948	0.90
303.3918762	0.05
307.2187500	0.06
309.1645508	0.38
314.4317017	0.04
315.1793823	0.02
323.2653198	0.03
325.1887817	0.07
327.1635132	0.07
331.2253418	0.09
339.4042969	0.20
341.3669434	0.27
343.0794067	0.08
345.8830566	0.04
354.2001038	0.08
355.2933350	0.43
356.4359741	0.25
357.3891602	0.53
358.2308350	0.82
359.1279297	0.26
364.0192871	0.08
366.3571777	0.09
369.2213745	0.09
370.4226074	0.06
371.3113403	0.45
372.3314819	0.13
373.2335815	0.92
375.4104004	0.13
379.2218628	0.04
383.5096436	0.12
385.4788818	0.04
386.4029541	1.10
388.0944214	1.07
389.1790771	0.24
390.5599976	0.30
393.4996338	0.11
395.9719849	0.05
397.2336426	0.35
398.0587158	0.04
401.3270874	4.36
404.3447876	3.37
405.3533936	4.03
406.9932251	0.42
408.4209595	0.24
411.4240112	0.08
413.2937012	0.11
419.2800903	24.94
419.9543457	0.16
425.0653076	0.27
426.2871704	0.09
427.5750122	0.19
433.5055542	0.16
435.2167969	0.09
436.0690918	0.09
437.1741333	0.07
439.2942505	0.04
440.1997070	0.02
449.3052368	0.25
451.1867065	0.15
452.1378174	0.03
457.1864014	0.04
461.3905029	0.23
467.2086182	0.31
469.4487915	0.15
485.4647827	0.25
488.3949585	0.06
500.2802734	0.33
503.3903198	0.06
505.2353516	0.04
513.2780762	0.38
517.3091431	0.28
518.3871460	1.02
519.4491577	1.65
521.2286377	0.04
523.2147217	0.13
525.6112671	0.05
526.3572388	0.04
528.2239380	0.07
533.4328003	10.17
534.6401978	0.06
536.2053833	0.70
537.3265991	2.47
538.4207153	0.11
539.4816895	0.05
541.4451294	0.37
542.1181641	0.59
543.6315918	0.05
546.8558960	0.18
547.5076294	0.10
549.2005005	0.15
550.2013550	0.08
551.4395752	100.00
552.4861450	0.05
559.2645874	0.90
560.6376343	1.21
561.6175537	0.25
562.5612793	0.14
567.5007935	0.75
568.5407104	0.07
571.2272949	0.16
575.1710815	0.06
577.1500854	2.11
578.7958374	0.30
583.5467529	0.12
592.3115234	0.12
605.2476807	0.06
606.4553833	0.32
614.1843872	0.29
615.5097656	0.12
616.9892578	0.34
618.4739990	0.14
621.5083008	0.09
627.6714478	2.69
628.7770996	0.21
630.6630249	0.18
635.1233521	0.04
636.4599609	2.17
637.4110718	0.46
639.4094849	0.05
644.7344360	0.07
649.2537842	0.06
650.8851929	0.15
660.4118042	0.05
665.2598267	0.10
667.4558105	0.55
669.0331421	0.20
676.0923462	0.08
677.3690796	0.15
678.5979614	0.08
679.4252319	0.04
682.7022095	0.05
683.4356079	0.04
685.0883179	0.05
694.1339722	0.55
695.1530151	1.01
696.6665039	0.07
698.3871460	8.38
701.4833374	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.8328
Annotation	Unknow
Peak:m/z	Relative Intensity
299.1685791	0.04
304.9848022	0.07
408.0628662	0.15
426.7370605	0.06
439.0958252	0.04
441.2797241	0.12
444.7520752	0.41
446.8698120	0.10
447.8015747	0.02
462.9765625	1.28
463.9044189	0.07
471.3576660	0.18
479.3162842	0.21
488.8430786	0.03
490.8712769	50.81
491.5077515	0.13
493.1171875	0.14
495.4927368	0.12
507.2093506	0.19
508.8905640	11.11
510.4997559	0.03
523.9779663	0.12
525.8958130	0.02
527.1384277	0.14
535.0762939	0.24
536.9162598	100.00
545.5828247	0.04
555.0186768	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	245.0432
Annotation	Glycerophosphoglycerol
Peak:m/z	Relative Intensity
78.9341888	1.02
96.8616638	0.31
99.0178070	0.02
136.8615723	0.02
144.9256592	0.02
150.9927979	0.41
152.9636383	100.00
160.8802185	0.02
171.0666046	8.35
200.8515472	0.06
208.9174042	0.03
211.2225494	0.04
227.1058502	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.098
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
129.0555420	0.16
130.9211731	0.11
134.9376221	0.45
136.2851868	0.08
146.9897461	0.11
151.1520996	0.89
158.8208313	0.09
161.0794983	0.49
162.2449646	0.54
165.0882874	0.06
173.0335083	0.57
173.8563843	0.15
176.0362854	0.13
176.9284973	0.21
179.0735626	2.23
189.2291107	0.22
191.0559998	100.00
191.9867249	0.20
197.0109711	0.24
205.0968170	0.13
207.1272583	0.55
219.2806091	0.12
227.1278381	0.05
231.1615601	0.31
233.1601257	0.48
234.1385803	0.11
235.0237122	0.47
239.3320618	0.14
246.9858704	0.16
248.3669739	0.09
249.0975647	0.80
252.9581299	0.12
261.2174377	0.65
263.0241394	0.10
265.1440125	2.40
268.9370117	0.22
277.2036438	0.10
279.1937256	0.43
283.2718506	0.43
284.1036987	0.05
293.5158081	0.11
295.1918945	0.43
299.2966309	0.06
303.0354309	0.05
308.4171753	0.19
309.1508484	0.26
313.1992188	0.07
324.1138916	1.96
325.0348206	2.03
327.1334229	0.29
342.6254883	0.05
353.1095276	96.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.1245
Annotation	Samaderolactone A
Peak:m/z	Relative Intensity
123.2585754	0.08
134.0386658	3.45
136.0109558	0.14
149.0496063	3.44
150.0463257	2.56
150.9936981	0.22
152.1379242	0.05
165.0291138	6.29
166.1244049	0.09
166.9609070	0.18
178.0993042	3.61
179.9548645	0.14
181.0838165	0.34
188.8390198	0.04
190.1081543	0.05
193.1295776	63.47
195.1461487	14.14
206.9728699	0.08
219.1189575	0.17
245.2904053	0.06
265.2651062	0.03
274.1525269	0.06
309.4675598	0.03
315.3169556	0.08
327.0924377	0.05
341.1769104	100.00
342.1443787	0.93
344.5455322	0.05
345.2841187	0.07
346.2695618	0.03
359.6940002	0.06
371.0739136	1.72
372.2944641	0.14
373.3466492	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	763.1906
Annotation	Pelargonidin 3-(6''-p-coumarylglucoside)-5-(6'''-acetylglucoside)
Peak:m/z	Relative Intensity
221.0748291	0.17
245.1586914	0.02
251.0525208	0.03
259.1777344	1.47
260.1784973	0.03
263.9646606	0.03
280.8679504	0.36
303.0935669	0.06
305.0389099	0.07
310.2155762	0.02
323.1981506	0.36
324.1784363	0.03
339.8686523	0.03
341.0981445	4.15
342.1265259	0.71
346.9495544	0.03
383.2208862	4.74
384.1871338	0.46
389.2384644	0.02
403.3968506	0.03
411.2753906	0.03
412.8570557	1.55
413.7180176	0.08
439.1897583	0.04
442.9763184	4.88
444.1263428	0.56
467.4369507	0.10
473.1820068	0.28
473.9038086	0.09
485.2569580	3.20
486.3946533	0.64
502.5759277	0.13
503.1985474	2.32
504.2111206	0.47
517.2807007	0.14
541.4574585	0.05
545.4204712	0.23
546.4688110	0.10
547.3549194	0.10
565.2131958	0.17
566.6917114	0.13
583.3457031	1.04
584.4006958	0.34
588.2614136	0.05
601.2653198	13.70
602.3532104	1.56
627.1400146	0.06
665.3370361	100.00
666.3676147	21.44
745.3169556	15.71
746.4243164	3.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	511.1932
Annotation	Unknow
Peak:m/z	Relative Intensity
157.1049042	0.11
158.1152039	0.40
159.1361389	2.25
163.0646973	0.12
167.0848694	0.31
169.2552643	0.10
170.0202026	0.04
172.1761169	0.09
173.0810089	0.08
181.0630798	0.28
185.0504456	1.92
186.0327148	0.29
194.7956085	0.10
199.0437927	0.20
200.2042084	0.29
201.1644287	0.13
203.1037140	34.78
204.0868225	0.89
207.1739197	0.04
208.1677551	0.10
211.0827484	0.20
216.9398499	0.67
225.2882080	0.07
227.1507111	0.60
229.2241516	0.72
241.4989624	0.13
245.1835938	2.36
247.2603760	0.04
247.9579315	0.09
270.0330505	0.06
272.0986023	0.27
273.3283386	0.44
275.0393066	0.28
287.1825562	2.55
289.2893982	0.23
294.2178955	0.13
299.3311157	0.16
301.3307495	0.07
305.1680908	0.04
307.3761597	0.05
310.8496704	0.10
319.0775146	0.13
321.2755737	1.04
329.2642822	1.67
331.3148193	0.13
347.2996216	7.52
348.1250610	1.00
362.4973145	0.13
365.2775879	100.00
366.3549194	3.83
367.7266235	0.62
373.2512207	0.07
379.2811890	0.31
385.5482788	0.08
389.2946167	0.19
391.1502686	0.22
395.1860352	0.09
403.0833740	0.05
407.1544189	0.31
433.7592773	0.58
437.2389526	0.13
451.3465576	1.66
465.4754639	0.80
467.0159912	0.04
475.2412720	1.39
482.6006470	0.06
493.3040771	14.48
494.3129883	1.36
END