#DEFINITION	Reference Metabolome for Dioscorea polystachya
#IDENTTFIER	RefMeta-Dioscorea polystachya.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Dioscorea polystachya
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Dioscorea polystachya was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.27
Annotation	Unknow
Peak:m/z	Relative Intensity
163.8445740	0.08
189.9356537	0.11
191.2158661	0.09
210.0891724	0.06
217.2417908	0.05
221.2418060	0.04
233.1514587	0.54
238.2115479	0.05
239.3415833	0.03
243.0921326	0.11
246.1203003	0.07
253.1804504	0.04
258.8329468	0.04
260.8038330	0.11
262.9901733	0.12
267.2847290	0.24
268.0690308	0.21
269.1838989	1.10
270.1979370	0.13
277.4532166	0.18
279.0822754	0.31
280.1524353	0.06
281.1540527	0.44
282.1266479	2.74
283.2037354	3.37
284.2307739	0.57
287.3134766	0.39
288.1665039	0.10
289.2593994	0.20
290.0910645	0.06
291.2133179	0.04
293.1437378	0.39
293.9201660	0.05
295.2262573	0.61
297.0962524	6.82
298.1022644	0.52
299.2817383	0.16
307.2567139	0.25
309.4656372	0.19
311.1139526	66.07
312.2126770	5.37
319.5090942	0.15
323.1140137	3.39
324.2150879	0.51
325.1305542	0.47
326.0568237	0.15
328.2652588	0.06
335.1475830	0.30
336.2825317	0.21
337.2308960	0.39
338.2291260	0.17
339.5046997	0.18
341.1762085	25.80
342.2550659	1.21
349.2871704	0.21
351.2613525	0.13
353.2281494	4.70
354.2463989	0.78
355.1485596	0.33
356.3057251	0.11
359.4536133	0.05
361.1606445	0.35
362.0362549	0.04
363.3856812	0.03
365.6616821	0.11
366.3239746	0.11
367.1239624	0.03
369.0722046	0.27
371.2920532	0.47
378.2702026	0.05
379.4072876	0.75
380.3467407	0.15
381.2973022	0.16
383.2302246	2.07
384.3375854	0.24
385.1375732	0.04
393.2642822	0.03
397.1637573	3.08
398.1585083	0.59
398.9765625	0.13
401.5190430	0.11
407.1489258	0.70
411.2246094	0.21
413.1315918	0.49
415.1831055	100.00
416.1981201	7.99
425.2501831	1.93
429.1541748	0.59
430.2487183	0.10
439.3599243	0.41
449.1481323	0.15
450.1804199	0.03
451.0958252	0.49
455.2658691	0.08
457.2050171	2.50
458.2083130	0.42
467.2599487	0.05
469.5266724	0.07
473.2540894	18.69
474.3323975	2.04
486.2507324	0.03
487.1863403	0.17
488.1063232	0.04
489.4636841	0.23
491.3506470	0.48
492.1405640	0.08
497.3542480	0.19
500.2058716	0.10
501.2778320	0.16
503.2290649	5.52
504.3187866	0.39
515.2874146	0.51
516.3848877	3.13
517.4434204	0.21
522.3395386	0.83
523.3631592	0.04
531.1824341	2.74
532.1338501	0.19
533.2709351	1.70
534.2800293	0.07
535.3499146	0.08
539.2443237	12.68
540.3433228	0.05
541.2971802	0.59
542.1983032	0.07
545.2604980	2.05
547.2013550	0.05
548.2422485	0.07
549.6729126	0.03
552.8951416	0.38
554.0665283	10.85
555.3573608	0.02
556.4525757	0.07
557.8698120	0.71
559.2494507	1.30
560.4144897	0.24
562.8871460	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.07
Annotation	Unknow
Peak:m/z	Relative Intensity
269.8887634	0.15
341.9628296	0.07
355.2447510	0.36
356.0180054	0.16
376.0028687	0.14
377.2471313	0.18
445.2086182	0.06
471.2100830	0.09
473.1127930	0.05
483.4855957	0.03
503.3137817	2.03
507.2780762	0.09
539.1809692	100.00
539.8446655	0.08
552.2495117	0.17
568.2146606	0.08
577.1092529	13.17
577.7679443	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0023
Annotation	SC-58125
Peak:m/z	Relative Intensity
128.9069214	0.35
154.8857422	0.02
172.9999084	1.40
184.9768677	0.04
190.9670715	100.00
191.9687500	0.08
193.0782166	0.09
207.1193085	0.16
212.9659882	0.20
236.2200623	0.02
247.0553589	0.05
254.9626770	0.13
272.9530640	0.33
277.9065247	0.04
288.6747437	0.01
291.0938721	0.05
298.8523560	0.31
306.3242188	0.08
317.0014038	1.57
330.3027344	0.06
341.0723877	0.03
346.9060974	0.04
349.8740845	0.02
356.2377625	0.10
357.3331909	0.04
358.8408813	0.11
376.8327637	0.03
384.6048584	0.16
403.0815430	2.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
134.9884644	5.66
159.0235748	14.81
183.1115875	4.84
225.109314	5.88
239.345459	4.07
263.2559509	4.29
268.0887756	2.27
281.4726868	5.10
282.6960754	12.21
321.085083	7.40
339.4788513	9.64
355.2462158	16.36
357.1395264	7.32
360.0441895	16.39
362.5780334	13.41
367.1810913	3.04
370.0305176	7.68
377.1391907	16.66
378.2690735	6.58
380.2919617	5.61
390.339447	3.05
395.4125061	11.33
398.2095642	3.55
408.2705688	100.00
409.1144104	23.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	389.0493
Annotation	Repenol
Peak:m/z	Relative Intensity
122.9760590	0.67
156.6143341	0.26
185.2595825	0.28
187.1314087	0.47
192.9893188	0.23
227.0285645	0.12
241.1445007	0.37
255.2823181	0.22
259.0922852	0.14
289.0475464	0.11
306.7439575	0.16
312.9915771	0.08
315.8617249	0.12
317.1430054	0.24
322.9177246	0.24
325.0278015	1.00
326.2162476	0.12
331.3147278	0.58
335.3058777	0.61
335.9890747	0.11
339.1161194	0.33
342.9800110	0.33
345.2111511	0.22
354.3308411	0.18
357.1783752	100.00
362.1919556	0.16
370.3757324	1.38
371.2770081	2.04
372.6356201	0.11
380.1725159	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1121
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
97.0046692	0.31
99.1175461	0.02
108.9348373	0.13
126.9905090	1.48
131.6622620	0.02
139.0900879	0.05
141.1900940	0.01
143.5135193	0.07
144.8510742	4.63
147.0679321	0.02
150.2292175	0.02
150.8502808	0.02
152.6985626	0.01
157.1340332	0.04
159.1705322	0.02
160.8580933	0.03
162.9261932	8.44
165.1425018	0.11
170.8920898	0.05
176.9336700	0.04
179.0524139	0.10
181.1238098	0.07
185.1053162	0.02
188.9702301	0.12
190.8475952	0.10
192.3833923	0.57
193.0766907	0.69
194.5295715	0.06
195.1978149	0.11
199.0088654	1.09
200.3492889	0.04
202.2501984	0.03
205.0719299	0.12
206.9139099	0.16
208.9139404	0.03
211.0105286	0.67
212.9598694	0.17
216.8931885	2.77
217.5006409	0.01
219.2181702	0.05
222.9299927	1.92
225.0541992	0.54
227.2314148	0.04
229.1251526	0.97
231.0229492	0.04
235.0810852	0.55
240.3164062	0.45
240.9506226	0.84
243.1355896	0.29
247.0886230	2.22
248.6325378	0.01
252.9573975	6.90
253.6846924	0.01
256.0257874	0.09
258.1843872	4.08
258.8829346	11.17
259.5916138	0.02
260.9962158	0.16
268.2626953	0.72
269.2603760	0.52
270.9584351	19.10
271.5915833	0.06
275.0718384	0.08
277.0462952	0.01
277.7739258	0.03
278.8634644	0.41
280.1225281	0.06
280.7623596	0.10
281.3836060	0.02
283.5824585	0.14
284.9451599	0.20
285.9951782	0.14
286.7050171	0.46
288.8083496	100.00
289.6407776	0.23
303.9968262	0.07
305.5352173	0.03
306.4648743	1.00
307.1021118	4.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	600.8182
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9855042	2.62
176.0241699	0.25
176.9279633	0.28
179.0094452	0.14
216.8508301	0.16
244.9340820	0.06
273.1486511	0.65
275.0327454	0.07
288.9135132	0.60
291.0423584	0.16
314.9240723	0.17
388.9353027	0.21
398.8117065	0.18
403.1539917	0.26
419.9671631	0.09
420.9076538	0.14
443.2199097	0.97
444.1615601	1.37
445.1647949	2.01
446.4522705	0.68
447.9455566	0.77
448.8679810	1.06
459.2342529	0.31
461.8786011	0.16
471.1426392	0.29
471.8038940	0.17
473.0429688	0.45
473.8554077	0.12
486.7579956	0.58
488.1153564	0.81
488.9898682	2.55
493.0869141	0.14
500.9956665	0.40
506.2035522	0.06
511.5438843	0.05
512.2091064	0.07
516.8034058	0.14
556.8810425	100.00
558.2653809	0.68
559.0359497	0.61
583.3779907	0.17
584.6620483	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1612
Annotation	6-O-Veratroylcatalpol
Peak:m/z	Relative Intensity
151.8236084	2.38
165.0845032	4.20
167.0473938	35.26
181.0271606	0.70
195.0869446	15.48
203.1022949	1.15
209.0255737	7.07
294.9577637	1.00
297.1443176	1.96
315.0115356	7.54
319.2789307	2.03
327.3756714	0.60
350.6013184	0.46
363.0991211	100.00
363.8427734	0.41
389.2052612	1.00
405.1089478	0.94
429.4851685	1.60
435.0084229	6.16
437.5697021	0.76
461.1971436	0.51
465.1270752	6.45
479.2416992	6.01
480.9229736	3.02
486.0153198	1.87
502.7601318	1.25
507.2808838	5.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
105.0576935	0.26
106.0960999	0.08
116.8957062	0.18
128.9290924	0.28
129.7578583	0.35
133.0947113	0.08
145.0022125	0.52
145.9800568	0.15
148.9520111	0.93
149.7359314	0.25
164.9803467	0.54
169.2359772	0.42
174.206604	0.14
178.1332245	0.19
179.0913544	1.06
180.1170654	0.64
180.9887238	0.66
183.1029816	0.32
193.0770264	0.57
194.1316528	0.26
195.2974701	0.78
195.9691925	0.11
206.170517	1.23
207.1600189	8.34
208.1461029	7.64
209.0239105	2.08
210.1255188	0.69
220.9343567	0.47
222.091156	5.78
223.1605377	13.30
224.2364655	2.55
233.0230713	0.39
235.053894	0.17
248.3145752	0.08
251.0836029	100.00
252.0645905	43.35
253.1025238	3.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
94.92079163	0.06
103.1136017	0.15
115.0001221	0.29
119.0465088	0.13
122.868988	0.03
129.0219879	1.00
130.0355682	0.21
148.9923096	0.04
151.0267487	12.12
152.0258179	2.40
152.9332428	0.05
156.299118	0.07
157.9172058	0.25
164.816452	0.09
167.1295166	0.26
168.1748352	0.12
169.1735077	0.21
170.1447449	0.13
172.1303864	0.05
179.0731964	0.29
180.1979675	0.15
183.4272766	0.25
184.5429077	0.46
185.3231049	0.28
186.1806641	0.17
197.1391449	0.42
211.036972	0.05
224.9999847	0.55
226.0795746	0.60
235.3798828	0.13
238.1638184	2.28
239.0462036	0.62
251.1425934	0.18
253.0805054	100.00
254.2160797	2.28
255.2480621	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
92.99038696	0.26
109.0660019	1.54
118.8831024	0.16
122.9381638	0.87
125.0314102	0.66
133.0505676	0.26
135.0358582	0.56
137.0523834	0.60
138.9694519	2.49
143.2593689	0.33
144.052002	0.38
145.1698151	0.48
147.0607605	0.66
151.1505127	0.61
152.8031006	2.88
155.0652161	0.96
159.2622681	0.93
164.1625366	0.55
167.0628357	1.21
168.8725586	2.46
171.1283569	0.72
175.0885162	1.24
181.1218262	0.76
183.1186371	1.25
185.3222504	0.76
187.1315765	0.61
189.3642273	0.21
195.1208038	1.11
196.6141968	0.85
197.2208557	2.00
199.3859253	1.60
200.8241272	1.48
205.0354004	0.88
207.1798096	0.18
209.2795715	0.96
211.0211792	0.74
213.3959961	1.32
215.1781311	0.25
219.1810913	1.65
221.0745544	2.64
223.0215759	0.50
224.9992676	2.14
227.1554871	1.20
229.1166992	0.53
233.0462646	0.71
233.7804871	0.48
235.1209412	0.41
237.1038513	0.65
239.1633606	7.91
240.2564087	0.15
243.2772827	2.41
247.1064148	0.21
250.111145	0.31
251.2290955	3.02
253.0294189	1.29
255.2848206	3.18
257.0718994	0.62
261.2114258	4.39
269.1743774	0.40
279.2345886	100.00
281.4501953	0.80
299.3575134	0.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.7
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0598755	0.22
198.8240051	0.35
274.6437683	0.35
290.8798828	0.53
324.6420898	0.14
364.9129639	0.53
380.8758545	0.52
399.0671997	0.08
425.4125977	0.41
426.9274292	0.22
432.7519531	5.23
448.7620239	12.29
463.4401245	0.13
464.8538208	2.14
480.9694214	0.43
516.6184692	100.00
517.2685547	0.55
532.4424438	9.79
533.4668579	0.38
535.5176392	0.12
541.2454224	0.32
553.8388672	1.75
555.0531616	0.49
556.7229004	0.31
558.0383911	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.18
Annotation	2'-Hydroxyzearalanol
Peak:m/z	Relative Intensity
105.0739365	1.24
122.1812057	1.77
123.2452698	1.65
125.0342178	4.12
127.2028351	1.79
135.1112671	2.89
137.0757446	3.44
155.0155945	2.45
157.3725739	1.52
158.9055634	0.97
163.1064453	3.42
166.8143921	4.36
168.9661865	1.24
171.1478729	2.48
175.2325897	1.80
176.8343811	4.63
180.574585	1.25
181.1963501	4.24
185.1308746	2.20
187.0630188	4.60
197.1276245	7.46
201.1773224	6.14
206.7707214	2.86
221.7070618	2.48
223.1204834	5.04
227.2038574	1.52
228.9932251	1.65
234.0492249	8.56
241.1297302	7.28
251.1590271	8.87
252.8606262	5.47
265.3182373	1.68
277.1508179	2.07
280.2716064	5.33
281.0670166	8.77
283.4076843	1.81
287.119812	1.54
293.1373291	11.56
295.1255798	12.91
297.6152344	7.24
300.9293213	4.36
303.4611816	12.73
306.7670898	3.26
311.3919678	5.21
319.1025696	3.40
320.2668457	4.77
321.1609497	100.00
321.8469238	3.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2876
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
132.8706207	3.90
135.0569153	2.09
141.0613403	1.33
156.1512299	6.18
157.0064697	3.09
160.1479492	2.65
174.8114624	4.59
181.1133118	2.67
184.0412598	3.89
201.149765	1.40
230.9844055	1.86
243.9578247	4.45
247.2810364	3.63
253.2932739	2.37
271.0734863	3.95
280.9976196	3.15
284.4934082	2.65
291.3648376	5.28
293.2021179	6.96
295.7205811	11.25
313.3465576	1.95
317.5207825	9.46
323.4457397	2.24
336.1757202	3.83
339.5320435	13.27
342.0167236	9.93
353.9606018	3.39
357.1529846	11.71
362.3227844	2.17
363.2280884	2.00
364.3443909	4.45
368.0375671	13.43
369.993866	4.24
372.7087097	2.09
377.0803223	3.69
381.0851135	4.99
382.2816772	4.17
385.2532043	4.50
390.4590149	20.60
396.3787842	3.92
397.7582092	8.61
408.2845459	100.00
409.3994446	16.20
411.0687256	11.30
416.3126831	10.13
427.4851685	3.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1541
Annotation	Vicenin 1
Peak:m/z	Relative Intensity
244.0054321	0.53
271.4290161	0.44
278.9995117	0.14
283.0266724	0.66
313.0285034	1.29
317.2680054	0.57
337.2109985	2.52
349.1560669	0.32
367.1653442	31.81
385.1505127	24.65
395.9950562	0.23
403.1558228	100.00
406.6295776	0.55
407.2921143	0.37
409.4815674	0.44
412.2143555	1.22
427.2185059	0.72
429.2362061	0.30
444.6983032	0.19
445.3945312	0.28
475.2042236	3.39
484.2213135	1.15
492.9931641	0.53
499.1801147	5.04
511.1320801	0.52
519.4306030	0.48
520.7760620	0.58
529.1948242	11.72
547.1099243	25.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1558
Annotation	Benzyl gentiobioside
Peak:m/z	Relative Intensity
125.0315628	1.37
126.0701981	0.09
126.9811096	0.22
128.9791565	0.21
130.9727020	5.05
131.9873199	0.23
137.0953674	0.27
139.0590210	0.52
140.7867889	0.18
142.9991913	0.83
148.9903717	7.20
149.9656677	0.52
151.0273438	0.06
152.8296814	0.07
155.0953369	0.23
155.8482971	0.05
158.2073822	0.09
159.0186462	1.46
161.0110016	15.02
162.0483398	1.70
165.0750732	0.11
167.0295715	0.41
168.0027313	0.30
169.1215820	0.16
169.9375610	0.03
172.2648010	0.04
173.1505432	0.19
177.3167725	0.33
178.2627258	0.05
179.0202942	0.04
181.0961609	0.04
184.9443970	0.13
187.0871887	0.58
189.4927063	0.08
191.0923157	4.42
192.1502075	0.15
193.2778473	0.04
194.9052429	0.10
197.0307465	0.05
197.6925812	0.13
203.1326752	0.37
205.0509949	0.17
207.0936737	0.03
209.2250824	0.04
211.3530579	0.04
213.3248901	0.07
215.1281738	1.14
215.9006348	0.08
223.1506348	0.10
225.0767517	0.03
232.3452148	0.52
233.0198669	3.91
234.0288391	0.37
237.0343323	0.11
251.1956177	0.09
252.1809387	0.06
257.0621643	0.04
258.1098022	0.13
261.2885132	0.05
263.3211060	0.05
269.4010315	0.11
270.2729187	0.03
275.0670166	0.04
281.2169189	2.72
282.1821899	0.56
283.1947021	0.04
291.1295166	0.36
293.1801147	6.08
294.1801453	0.32
295.3768921	0.05
299.1202393	100.00
300.1311035	13.08
309.2108154	0.11
311.1645203	0.08
313.1868286	0.92
314.3078308	0.22
316.5028076	0.06
331.1299438	0.61
339.2908020	0.08
340.9814758	0.18
342.1741943	0.16
343.2853088	0.05
344.2263794	0.08
345.5696106	0.06
352.0246277	0.07
353.5700073	0.09
359.2948303	0.07
368.9432678	0.12
372.4641113	0.05
373.2391052	0.56
374.1905212	0.24
385.3030701	0.24
388.4236145	0.24
394.1383057	0.07
395.5162048	0.28
396.1864929	0.05
403.2999573	0.05
405.3401184	0.11
413.1952820	1.23
414.3099060	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1351
Annotation	Vittariflavone
Peak:m/z	Relative Intensity
145.0632935	0.45
160.8891296	0.12
163.1160736	0.17
179.0032043	6.28
197.0632019	1.12
201.1886749	0.08
223.0272827	1.88
229.3933868	0.06
248.848938	0.05
251.3943787	0.07
254.3625793	0.17
255.0391235	0.30
261.1493225	0.06
265.2420349	0.28
281.2713623	0.72
282.983429	0.08
287.4842834	0.08
297.3181152	0.11
299.1609192	0.40
306.9546204	0.05
309.1389771	0.94
314.3583984	0.06
324.6599121	0.76
325.3405457	0.20
341.4588928	0.25
343.0858765	100.00
345.1770935	0.04
353.098877	0.32
358.9672241	0.38
363.3681335	0.21
367.1600037	0.13
369.0693054	0.09
371.1792297	0.46
379.0498657	0.10
385.0743103	0.17
401.5071106	0.12
414.8530884	0.05
417.367157	0.11
420.3945312	0.12
421.3955688	0.35
424.2957764	0.09
425.3865662	0.12
429.3848267	1.40
430.960968	0.10
436.5260925	0.13
441.2320557	0.23
443.3004761	1.10
445.370697	0.10
458.59552	0.28
459.3861389	0.24
460.0414734	0.08
461.3065186	0.42
467.4634094	0.05
481.4358215	0.05
486.079895	0.20
487.085022	1.08
496.5995789	0.29
504.9258118	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.1855
Annotation	Gymnastatin R
Peak:m/z	Relative Intensity
133.5463104	0.25
145.1590729	0.26
184.3369751	0.13
186.1020203	0.51
199.1108093	0.36
234.2120056	0.55
256.1837463	4.79
267.2423706	0.19
274.0776367	0.84
301.0563965	1.28
305.5438843	0.14
309.4677429	0.18
313.1854553	2.46
326.1926880	0.08
328.2167969	0.06
330.1532593	100.00
330.8016357	1.08
338.4414673	0.27
361.0218506	1.54
368.0990295	0.21
371.4101868	0.15
420.6277161	0.10
441.1756287	9.27
441.8532715	0.61
442.4682617	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.19
Annotation	Diphthamide
Peak:m/z	Relative Intensity
94.9452896	0.10
134.0956726	0.11
170.3002319	0.08
174.8973999	0.10
176.2252197	0.10
178.1310730	0.18
185.1253662	0.09
191.0517120	0.11
193.3374634	0.16
210.1153564	0.06
211.2226562	0.04
227.1627197	0.29
231.2919617	0.12
236.1085815	0.11
237.2078247	2.30
238.8499451	0.13
239.8612061	0.06
241.6898499	0.14
243.8916931	0.12
245.2238770	0.06
249.1559143	3.97
252.1451111	0.27
256.0315247	0.04
256.9695740	0.18
260.8421021	0.06
262.8701782	1.48
267.1140747	100.00
278.3462830	0.29
279.2520752	0.52
280.1298828	2.67
281.0234680	2.38
281.9534302	0.08
288.8042297	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.1854
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
126.9456177	0.91
128.1621246	0.12
129.1220856	0.12
130.7657013	0.14
132.9570312	2.75
141.0232544	0.06
143.0997009	0.53
144.9255981	4.82
147.3161926	0.05
148.9559631	0.03
149.9817963	0.31
151.5272522	0.17
153.3703613	0.04
154.9358215	0.17
157.0840607	1.72
158.8818359	0.55
160.8241577	1.01
162.8233185	5.98
169.0475006	0.03
171.1290588	0.34
174.3044739	0.21
174.9765930	1.79
177.0700684	0.12
180.7572632	0.84
187.0070038	2.90
188.9068298	0.10
193.1187439	0.35
194.8816681	0.22
199.0397491	2.30
204.9994202	7.16
208.9710541	0.42
211.1142426	0.06
212.3031311	0.28
214.5193481	0.10
216.4425964	1.17
217.0792847	7.93
222.7663269	3.15
223.4410553	0.08
227.0896912	0.18
229.0902405	0.22
232.0089569	0.08
235.0668030	2.66
237.5881042	0.05
238.3895569	0.13
240.3013000	1.68
240.9133606	7.96
241.5166321	0.08
246.8381958	0.20
249.1975708	0.06
250.7778015	0.11
252.3895874	5.00
253.0389404	9.01
257.2685852	0.40
258.9420166	32.12
260.9242249	0.04
270.1179810	2.45
270.9341736	22.71
272.8025513	0.18
274.2704773	0.04
275.1988525	0.11
276.8775635	14.71
277.5133667	0.07
278.1360474	0.06
288.0740356	4.13
293.0369568	0.08
294.8620300	100.00
295.5230103	0.73
312.0915222	0.79
313.0721436	1.10
319.1646729	0.13
331.1693726	0.30
345.9597168	0.04
348.8742676	0.87
351.2844849	0.39
353.6889038	0.16
356.1260681	0.07
357.5893250	0.05
360.2785645	0.19
366.6944275	0.98
367.3451233	0.23
371.2420654	0.12
376.3660889	0.19
379.1730042	0.05
382.7538147	0.07
384.7927856	3.21
391.1370239	0.09
394.2289429	0.05
402.3595886	2.72
402.9620667	6.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.86
Annotation	Unknow
Peak:m/z	Relative Intensity
240.6000061	0.38
254.1989136	0.10
258.1802368	1.12
259.1568909	0.33
273.2360535	0.74
275.9559326	2.76
276.7053833	0.08
277.3421021	0.30
301.1875000	2.29
310.9695129	0.65
318.5382690	0.20
329.2023926	6.36
341.2363892	0.11
347.2538452	0.33
362.2686157	0.16
363.2096558	0.26
365.0618896	0.75
366.0801392	0.22
383.3035278	0.56
389.2894287	0.31
391.4688110	0.48
401.1588745	1.31
401.7769775	0.15
419.2866821	8.89
420.3477783	1.13
421.4937134	0.37
425.4344482	0.28
458.1795654	1.38
469.2703857	0.50
472.4319458	0.22
475.2056274	0.28
477.2205811	0.13
496.1495361	3.24
497.3453979	0.72
502.3664551	0.50
508.4307861	0.67
509.1877441	0.08
514.2926636	1.27
525.9955444	0.57
527.3504028	0.33
532.3508301	2.47
533.5100098	0.54
562.3712158	0.43
568.2246094	0.11
570.3695679	0.80
586.3132935	2.09
587.1817017	0.47
604.3490601	100.00
605.3921509	22.77
643.4105225	0.22
660.9498901	0.10
677.4680786	0.26
706.1044922	1.54
711.1043091	0.20
735.3766479	0.19
761.5486450	0.32
789.4571533	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	532.71
Annotation	Unknow
Peak:m/z	Relative Intensity
214.7694550	0.10
232.0908661	0.06
235.3305664	0.10
237.2521362	0.10
250.8573456	0.20
259.2176514	0.05
281.1067810	0.11
294.6042786	0.07
296.8240967	0.31
337.2757568	0.20
339.0186768	0.67
341.2364502	0.04
354.8931885	1.16
356.8334351	0.51
358.0717163	0.35
358.9523315	1.57
362.7985840	0.05
364.8762817	6.86
370.8273315	0.10
372.9743042	0.34
374.8179321	0.82
377.1392822	4.30
380.8005371	21.16
382.5556641	0.06
391.0421143	0.03
395.7779541	0.11
396.8433838	0.08
401.1715088	0.04
413.0762329	0.21
415.3546753	0.07
418.8181152	0.05
425.8372803	0.08
446.7360840	0.45
448.6279907	100.00
449.2531128	0.39
457.2590332	0.08
464.0578613	2.38
464.7102051	5.00
468.9983521	0.22
486.3295288	0.40
515.1820679	0.09
516.0768433	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.0718
Annotation	Corynether A
Peak:m/z	Relative Intensity
83.00949097	0.20
95.13779449	0.06
97.00640869	0.09
99.23599243	0.16
106.991951	0.20
107.9535828	0.06
108.9358292	1.02
121.0769653	0.18
123.1060562	0.39
125.0543213	3.12
126.8641357	0.23
135.0812683	1.14
137.0415955	1.94
138.989563	0.30
143.1835022	0.07
147.1886902	0.22
150.9415588	1.27
159.0653687	0.81
161.0640869	2.49
161.8024597	0.21
162.9803009	0.20
163.8694763	0.31
164.9993134	3.29
167.0453339	1.68
171.1390381	0.09
175.0530548	0.92
179.0545654	10.43
180.2295532	0.10
183.0067291	0.26
185.3164673	0.11
186.2374573	0.50
187.0298004	1.04
188.0840302	0.80
194.9371033	0.12
199.312439	0.07
201.1320496	0.70
202.9955139	8.44
205.083252	32.23
205.9008484	0.16
209.3310852	0.16
215.0943604	0.10
216.9929504	0.73
226.925354	2.77
229.1731567	0.66
230.0013733	0.30
231.0706177	5.29
235.1372681	0.21
242.155426	0.31
243.057251	0.58
245.0852356	100.00
246.119751	1.07
247.0664062	4.88
251.9360962	0.43
253.1774902	0.21
255.5634155	0.70
259.2052307	0.20
261.1618652	0.22
269.0654602	0.30
271.0792847	8.96
274.1296082	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.16
Annotation	Puerarin xyloside
Peak:m/z	Relative Intensity
325.0299683	0.22
383.1412354	0.32
390.0860596	0.77
397.2108154	0.98
399.4921265	0.86
403.1414185	0.30
418.2332764	1.36
423.1253052	0.61
427.2549438	1.78
429.2985840	0.61
434.2146606	0.81
441.0039062	1.68
445.1828003	10.77
451.2856445	1.23
459.0889893	1.33
469.1862793	4.51
483.2673950	1.76
495.2556763	7.14
506.1575317	0.34
513.2303467	84.83
531.2042847	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
108.845871	1.32
120.9606705	1.14
130.7106018	2.17
165.2503052	1.93
190.8339844	1.15
195.002121	1.14
203.1957245	0.96
217.1853943	1.85
221.158844	1.05
240.2999573	1.48
240.9516907	1.58
244.2732544	4.74
271.0049744	4.05
283.1157227	5.36
289.0551147	1.46
292.151062	1.14
295.1300049	9.21
297.1281433	2.78
305.2240906	1.13
323.243042	100.00
341.3336487	5.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1587
Annotation	Puerarin xyloside
Peak:m/z	Relative Intensity
229.1390076	0.02
257.1445312	0.01
298.3181763	0.02
313.1997070	0.02
337.3198853	0.02
349.2631226	0.05
358.0885010	0.05
367.2792358	0.04
368.1386719	0.01
379.2680664	0.09
380.1540527	0.01
381.5413208	0.08
385.0642700	0.02
386.1092529	0.13
393.3775024	0.04
396.9451294	0.08
397.6727905	0.03
399.2878418	0.07
403.2537231	0.26
404.3047485	0.14
409.2656250	0.62
410.1577759	0.20
411.4093628	0.48
412.3463745	0.41
413.0280151	0.05
415.4031372	0.04
416.2177734	0.04
417.3602905	0.16
423.2287598	0.57
424.4014282	0.20
427.2625732	3.11
428.2380981	1.35
429.2274780	0.34
430.2984009	0.24
433.2293701	0.10
434.4092407	0.07
436.3344116	0.02
441.2047729	2.31
442.2424927	0.47
445.1747437	3.26
446.3188477	1.31
447.2198486	0.08
448.3198853	0.02
451.2850342	1.93
452.2911987	0.38
459.2617188	1.99
460.2776489	0.61
463.1954346	0.04
465.3421021	0.99
466.4172363	0.49
469.1992798	16.94
470.2863159	6.52
474.9926147	0.07
477.3459473	0.20
478.3510132	0.17
483.2238159	9.74
484.2703857	4.47
487.2498779	0.06
488.2656250	0.02
489.2683716	0.06
495.2326050	13.76
496.2308960	5.68
496.9390259	0.02
503.3457642	0.02
513.2285156	83.09
514.1737671	32.13
514.9241943	0.11
519.6832886	0.04
520.4906616	0.03
531.1746826	100.00
532.2317505	31.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
109.020401	0.63
110.9634247	1.34
121.0018616	0.30
122.3764343	1.16
129.15802	0.23
133.0982208	0.28
134.855011	0.98
138.9206696	1.46
148.8842926	0.76
150.9555664	0.46
153.0501709	2.80
155.0929871	0.62
156.6663208	0.34
163.0754852	0.47
168.8183289	1.28
170.9693451	0.77
180.9249878	1.39
183.0896606	2.92
185.023468	0.48
189.3370056	1.10
193.2396698	1.49
195.0223999	0.25
196.9917297	5.38
199.2236633	0.70
203.1107483	3.08
205.3682861	0.23
207.1653748	0.42
210.8443298	0.73
211.4812012	1.28
213.008667	0.51
217.3946533	0.66
219.3534851	0.32
220.4706421	0.79
221.4263	2.38
223.2666931	1.65
225.0553894	1.25
227.2026978	0.92
229.3533325	0.30
233.282196	1.45
237.249115	7.14
239.0256348	10.78
239.8269043	1.84
241.0171814	0.34
243.1017456	1.26
251.3728333	0.59
252.7033997	0.42
253.3955078	2.65
254.928894	3.34
257.1889343	2.58
260.1604004	0.44
261.253479	3.25
263.0942383	0.60
276.8479614	0.65
279.2396545	100.00
280.1967468	0.25
281.1292725	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	975.98
Annotation	Unknow
Peak:m/z	Relative Intensity
616.6925049	0.55
813.4745483	0.76
884.8638916	0.67
893.4255981	1.01
908.2803345	0.29
909.6990356	0.57
910.5177612	0.36
1126.5085450	0.46
1159.5485840	1.28
1160.4080810	0.18
1231.6630860	0.18
1248.7783200	0.26
1388.6099850	0.33
1694.7408450	2.60
1748.3034670	0.19
1763.4014890	1.40
1769.4266360	0.42
1785.4119870	0.62
1791.9844970	0.22
1792.9361570	0.12
1799.0513920	0.14
1807.7912600	0.21
1815.1741940	0.92
1827.4552000	0.50
1832.6424560	1.67
1836.7191160	0.46
1853.6639400	0.30
1858.5675050	1.08
1860.2547610	0.33
1866.5657960	1.37
1867.8829350	3.57
1869.3135990	0.72
1876.2540280	0.08
1880.1091310	5.09
1893.2828370	0.16
1903.6707760	1.74
1909.4133300	0.29
1910.6955570	1.41
1912.8791500	9.80
1913.6647950	2.19
1916.1740720	0.21
1919.1351320	15.40
1923.7697750	3.28
1926.2979740	0.30
1929.0113530	1.60
1931.7482910	0.82
1934.9034420	0.55
1936.5018310	0.62
1939.2359620	2.88
1939.9974370	0.17
1942.0379640	0.66
1950.3269040	17.23
1953.3553470	15.02
1956.6605220	2.30
1960.3645020	3.49
1964.0075680	0.58
1965.4117430	0.62
1971.0191650	1.23
1972.4324950	1.98
1974.6624760	0.81
1975.8884280	0.22
1976.6398930	0.55
1978.1081540	0.30
1978.9244380	2.06
1980.2193600	1.05
1981.1956790	100.00
1981.8825680	0.15
1983.9348140	1.49
1986.4665530	41.39
1989.9705810	2.03
1992.7740480	5.94
1996.0041500	0.27
1996.6695560	0.45
1997.9537350	1.81
1999.4884030	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	241.09
Annotation	L-Arginine
Peak:m/z	Relative Intensity
104.7879028	0.01
109.0230560	0.02
131.1465454	0.62
154.0220490	0.05
156.0151978	0.21
156.8334503	0.01
167.9847412	0.01
173.0253754	100.00
181.1653290	0.11
194.9921875	0.03
196.1294098	0.03
199.0826874	1.03
216.9759369	0.01
223.5691376	0.12
224.1837311	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	347.098
Annotation	Isotachioside
Peak:m/z	Relative Intensity
114.8729248	0.02
129.1012115	0.02
139.0516968	0.11
157.1840210	0.04
161.0660095	0.17
185.2254486	0.07
209.1812592	0.03
211.0016022	0.02
221.3230591	0.02
241.1066589	0.03
253.0979614	0.03
254.9330750	0.01
256.9760132	0.05
259.1530457	0.02
261.0528259	0.02
271.1923828	0.02
279.3041992	0.02
287.0737305	0.03
299.0802002	0.05
301.0745239	100.00
301.6831055	0.31
303.0880127	0.06
316.8736877	0.01
319.0453491	0.02
327.3428955	0.03
328.0032959	0.02
329.2147827	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
94.96113586	0.36
96.94792938	0.10
98.93496704	0.12
109.0701904	1.00
113.1238708	0.37
121.0307693	0.45
123.0723419	0.76
127.0732117	0.66
129.1328125	0.07
133.1104431	0.18
134.9589539	0.53
136.978714	0.80
139.0873413	0.38
141.151123	0.11
142.9301758	0.10
149.1426239	1.00
151.0932312	1.74
153.0567017	1.28
155.0638428	1.30
157.0531616	0.42
159.2697449	0.11
161.1756439	0.09
163.0598145	0.32
165.1105652	2.97
166.5483398	0.09
167.1830139	0.07
169.1614685	0.24
171.0446472	0.05
174.3016052	0.08
178.9518127	0.17
181.0178223	0.08
183.1478577	1.94
185.1235809	0.14
189.1410828	0.29
193.0296021	0.21
195.4847717	0.10
196.9905701	1.19
199.052124	1.04
203.3547974	0.09
204.8799438	0.06
208.0462341	0.04
208.9674377	0.12
211.0914001	1.57
212.9889221	0.56
215.098999	0.11
219.3813782	0.29
221.2105408	1.89
223.0867615	0.58
225.2510986	0.88
227.2948914	0.16
229.0293884	0.09
233.1331787	6.09
235.1268921	0.10
237.1810303	1.64
239.122406	5.32
241.0895691	0.15
243.1933594	3.50
247.2096252	0.24
249.1442261	0.06
250.5582275	0.38
251.1798096	5.25
253.3158569	0.50
255.0377502	0.42
256.8587036	0.68
261.2681885	7.60
263.2436523	0.09
269.3987732	0.14
279.2237549	100.00
280.8606262	0.13
283.0966187	0.10
285.4308472	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9365
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9458771	0.46
130.8763123	2.11
147.0072479	0.41
158.9878235	8.93
163.0477448	0.02
174.9720306	100.00
177.0803375	0.02
215.0446472	0.22
233.1402588	0.12
243.7708130	0.12
244.9014893	26.04
261.0157471	0.41
270.1424866	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
126.6453781	0.20
174.7547607	0.17
225.5566559	0.24
241.3600159	0.18
250.9235840	0.27
267.8955688	0.20
270.1029358	0.26
274.1878357	0.18
279.4795227	0.08
283.1075134	0.86
289.1051025	0.30
293.2817993	0.19
295.2595825	0.17
298.3846741	0.16
299.2514038	0.20
303.1388245	0.14
306.6420288	0.98
308.0676880	0.17
309.6646423	0.17
313.2131653	13.90
325.0726929	0.33
337.1633911	13.69
346.2895508	0.18
351.3344727	0.20
356.0959473	0.10
357.3159790	0.25
358.3866272	0.50
361.3222046	0.49
365.3996887	0.44
367.1828918	41.86
369.4472351	0.50
372.3141785	0.06
373.3849792	0.17
379.1102295	11.35
379.7541199	0.04
382.2779846	0.32
383.4509277	0.29
387.1341858	0.33
389.0865784	0.40
397.1876831	12.21
398.3067322	0.25
401.5848694	0.20
403.4464111	0.25
415.2251282	100.00
416.1075745	0.31
416.8351135	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	199.99
Annotation	Unknow
Peak:m/z	Relative Intensity
68.9487381	0.14
80.0962677	0.10
80.9718170	0.26
93.9355011	0.29
96.1328278	0.07
97.7384338	0.17
99.0645294	0.16
100.2864838	0.15
107.0229034	0.67
108.0326843	0.13
109.1896973	0.28
120.9100647	0.05
121.9497528	0.12
128.1775818	0.08
140.2550354	0.13
141.0780792	0.12
155.8500671	0.17
157.0979156	0.33
158.8391266	100.00
160.6318970	0.07
162.8821564	0.46
164.0454559	0.04
176.2103882	0.25
176.9020081	1.71
179.6617126	0.24
181.8129578	1.35
183.1607819	0.10
199.6621399	0.07
200.4570312	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	851.3467
Annotation	Unknow
Peak:m/z	Relative Intensity
257.2147827	0.09
257.9411621	0.10
273.2528687	0.06
284.3232422	0.02
285.2450562	0.07
292.1967468	0.03
293.3945618	0.05
298.4791260	0.02
300.5846558	0.10
301.2647705	0.41
302.1821899	1.56
302.9966431	0.16
310.7700195	0.07
311.3787537	0.26
320.2415161	8.09
321.2588806	1.44
322.5888672	0.04
329.1820068	1.62
330.2672729	0.14
335.1322937	0.11
340.3812256	0.03
347.0653076	0.38
348.5703735	0.12
364.3868408	0.04
365.2677307	0.04
371.1171875	0.05
373.4564209	0.02
389.3847046	0.07
391.1313477	0.08
400.2277832	0.09
402.2462769	0.03
408.7698364	0.05
410.0314941	0.02
423.3115234	0.03
427.2758789	0.39
428.3583984	0.18
429.9000244	0.03
445.1743164	0.99
446.3692627	0.21
451.5112305	0.09
458.2019043	1.02
459.0629272	0.01
461.0902100	0.08
463.1769409	11.05
464.2691650	2.22
476.1405640	0.06
496.1851196	2.32
497.3155518	0.66
503.9721069	0.03
507.4292603	0.05
514.1372070	0.28
519.5195923	0.09
532.1683960	3.18
533.2505493	0.79
541.3686523	0.39
542.1353760	0.02
552.3043213	0.08
553.3565674	0.04
554.2831421	0.02
568.3580933	0.07
570.3473511	0.32
571.3296509	0.53
572.3649292	0.14
585.1557007	0.23
585.7924194	0.08
594.3250122	0.04
612.1931763	0.22
614.3820190	0.04
630.2573853	2.66
631.2407837	1.03
631.8864746	0.06
648.2985840	100.00
649.3060303	24.94
650.0157471	0.18
660.6200562	0.05
661.2606812	0.26
662.1913452	0.04
722.5668335	0.05
726.4606323	0.04
749.8173218	0.13
750.4714966	0.09
764.1362915	0.06
788.2249146	0.12
792.8378296	0.10
808.9552002	0.09
815.5690308	0.17
833.2951660	0.58
834.2212524	0.60
852.1394653	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	405.1534
Annotation	3,5-Dihydroxy-4'-methoxystilbene 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
125.9962006	1.09
225.9847107	3.87
243.1018066	100.00
255.1754456	1.18
266.8422852	6.70
285.2407227	7.05
297.2752686	2.68
308.4348145	3.73
309.1554871	5.36
314.9470825	5.33
316.0458679	2.95
329.3114624	3.77
338.3838501	2.57
345.3040771	5.28
351.710144	3.82
369.2511597	11.16
373.0381775	7.09
375.0039978	0.98
386.7094116	2.79
387.3379211	11.15
388.2602234	5.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.27
Annotation	1,3-dihydroxypropan-2-yl (9E,12E,15E)-octadeca-9,12,15-trienoate
Peak:m/z	Relative Intensity
109.0762863	0.63
120.9725723	0.85
123.0888824	1.76
131.0458527	1.30
135.200119	0.40
136.9313049	0.98
142.835556	0.46
146.9050751	2.19
149.072525	4.18
151.1540833	0.76
157.1514282	0.72
159.0320129	2.05
161.1170654	2.43
162.9823914	3.92
165.1162567	0.76
165.9780121	1.11
167.0536499	1.04
168.0213623	0.70
168.8453369	0.63
173.1537323	0.28
174.8707123	0.96
177.2985992	1.32
178.848114	0.88
182.4652557	0.63
183.3042603	1.13
185.2317505	0.28
187.0715942	1.72
191.2944336	0.22
193.1818542	1.44
195.290741	0.45
199.4243774	0.49
201.0135345	1.04
202.9831543	0.28
205.1636047	1.06
210.9896851	2.15
215.0461426	1.04
219.3016357	0.96
233.1435242	3.32
237.245697	1.42
243.2523804	39.50
245.158905	2.28
259.2009277	1.13
261.2131653	100.00
263.1883545	4.90
265.0822144	0.46
269.3016663	0.69
271.2433472	0.40
277.2178345	1.47
279.2379761	12.35
281.1712646	1.59
287.480957	0.68
292.3718262	0.87
293.1631775	2.99
295.2200317	0.60
297.0862122	0.92
299.374115	1.49
305.5684814	1.16
308.5004578	0.37
309.5682373	1.17
311.1896973	1.78
312.1324768	1.34
315.8404541	0.43
317.3677979	7.25
329.9647827	0.69
334.0768738	0.58
335.2659302	64.56
336.1095886	0.58
338.7244263	1.20
344.4207153	0.57
359.1144104	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.92
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1044312	0.01
158.9985657	2.81
160.0438690	0.41
173.1660461	0.02
199.0223999	0.55
200.0552063	0.13
217.0719910	0.18
218.0600586	0.04
229.0076904	0.66
230.1162415	0.06
272.9887085	52.86
274.0162048	11.31
274.9049988	0.01
298.0368652	0.08
344.8968811	0.02
371.1949463	0.04
372.3673706	0.02
376.9061279	0.03
385.0822449	0.06
386.9513855	100.00
387.9552307	32.78
388.5943909	0.04
427.0516052	0.12
428.0226135	0.04
455.2099304	0.02
457.0292358	0.11
457.8585815	0.03
483.0537415	0.05
500.8406677	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	438.98
Annotation	Unknow
Peak:m/z	Relative Intensity
119.6886444	0.03
136.9923096	0.03
149.2469635	0.01
159.1791687	0.04
183.0168457	0.02
200.9962463	0.10
202.1461487	0.06
203.0546722	0.05
209.4094696	0.02
213.1794434	0.08
218.2832642	0.12
226.0788422	0.02
227.0643311	0.05
228.7578735	0.04
241.3050537	0.02
243.0014648	0.39
244.8262024	0.02
247.0980530	0.14
248.0898743	0.05
249.1600647	0.02
251.3328857	0.07
253.1871643	0.05
256.1246948	0.01
258.2357788	0.04
259.0551147	0.02
262.9915161	0.02
264.8822937	0.03
271.0264893	0.86
272.8811340	0.06
277.1956787	0.07
278.1717529	0.03
284.2746582	0.01
286.1954346	0.02
287.0874023	0.14
287.9281006	0.01
288.8489990	0.06
290.2553101	0.03
291.0998230	0.10
292.0910339	0.02
296.3346252	0.02
297.2529602	0.06
305.0138855	2.82
306.5705566	0.05
307.1731567	0.41
309.2203979	0.07
312.8973999	0.04
315.0085754	2.12
317.1287537	0.06
319.0343323	0.08
322.7658081	0.02
331.2113647	0.12
333.0484314	6.35
335.0617676	0.84
348.1726074	0.50
349.0412292	0.77
350.0044250	0.13
351.9940796	0.01
353.0390625	0.15
354.1165771	0.02
356.2841797	0.01
357.1465454	0.07
359.0625916	0.54
360.9953308	0.07
363.2843628	0.15
364.2620544	0.03
374.3783875	0.12
376.9773254	5.14
377.7862244	0.12
378.4882812	0.07
379.1636658	0.07
383.6964417	0.04
391.5690613	0.08
392.2320251	0.13
394.0588684	80.57
395.0306396	19.15
403.0227661	10.12
404.1775818	0.12
406.0209961	0.02
407.2201843	0.01
408.2341614	0.05
414.4975281	0.03
420.9333496	100.00
421.5909729	0.23
424.6675110	0.05
429.1853027	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.96
Annotation	Unknow
Peak:m/z	Relative Intensity
129.8910217	2.73
175.7734985	0.73
193.0292664	1.23
231.6165161	0.34
259.9928894	1.32
263.1050415	0.50
276.3577881	0.59
277.9183960	100.00
286.4546814	0.40
304.0747681	1.52
313.0160522	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
108.9659958	1.10
116.9905777	0.17
118.813118	0.53
121.0571747	4.28
122.9863892	1.09
135.236969	3.64
143.106842	0.33
148.6114044	0.35
149.2329559	0.43
150.9820862	2.14
156.9742737	1.58
159.0830383	0.60
163.0007629	2.07
168.7583923	0.49
170.9628906	0.71
173.050766	1.23
174.7831268	0.78
177.2984924	0.35
183.1250916	0.35
187.0862732	2.28
188.9104004	0.24
190.8808289	0.37
193.3807068	0.23
197.0768738	0.21
203.2479858	0.52
205.414978	0.20
216.8983765	3.00
223.2011414	0.58
231.4159851	0.27
235.1145325	0.41
245.12146	1.34
247.2692871	6.82
253.2506714	0.69
259.1099854	2.87
266.33255	0.22
282.9983826	0.65
294.8064575	0.71
295.5755615	1.23
299.2658081	2.40
303.3211365	0.19
305.478302	1.76
309.4263916	1.02
310.350708	0.49
313.2096558	0.29
323.2405396	100.00
323.8443604	0.48
340.8830872	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0026
Annotation	SC-58125
Peak:m/z	Relative Intensity
142.9024658	0.06
147.0052338	0.09
155.0541382	0.11
159.7651672	0.05
173.0087891	1.81
184.9757996	0.03
190.9341736	100.00
212.9905701	0.23
255.1272278	0.16
257.0160217	0.03
272.1117859	0.11
273.0002136	1.05
286.2052307	0.04
291.2303467	0.09
298.9034119	0.51
306.1672668	0.28
315.0154419	0.15
317.0654907	2.89
330.3894653	0.04
342.7322388	0.07
351.6677856	0.08
354.2305298	0.05
359.0892029	0.47
384.8695374	0.44
403.0203552	12.01
403.7016907	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	258.9
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7534637	64.16
123.5674438	0.14
174.1894379	0.26
174.8875580	0.90
190.8386841	100.00
212.1063690	0.25
213.2380219	0.43
215.1333160	0.39
240.2942352	0.18
241.2310181	0.63
242.1423492	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.2531
Annotation	Unknow
Peak:m/z	Relative Intensity
135.9517212	0.21
147.0397644	0.78
148.0925598	0.14
148.9504089	2.95
176.0811462	0.53
178.1958160	0.88
203.2289429	0.53
204.0936584	1.01
205.0181427	1.92
206.0694275	100.00
207.1472168	1.64
218.1141968	13.98
219.1544037	0.55
223.1201324	2.93
235.1096344	4.71
261.3980408	0.20
273.0614014	0.25
274.4013977	0.38
275.4649658	0.81
276.4936218	3.50
277.3337097	18.93
278.3949890	0.20
292.2535400	1.17
294.2702637	35.23
295.4337769	0.83
303.7625427	0.96
320.2416382	4.88
352.0889282	0.15
422.3735657	13.46
423.3544922	25.00
424.4676819	2.45
452.3719177	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0787
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
130.7729492	0.07
139.9489288	1.53
145.0721283	1.79
158.0905914	0.10
167.1025391	0.06
168.8567047	0.06
187.2823944	0.16
188.8371124	0.09
195.9832306	5.44
199.0462799	0.02
211.1156921	0.17
213.0353851	100.00
214.0666962	0.86
215.0195007	0.46
217.0041351	0.03
228.1778870	0.02
231.0843506	20.32
232.9674225	0.11
241.0673676	0.22
257.0948792	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.3081
Annotation	Integerrine
Peak:m/z	Relative Intensity
170.9757385	1.48
185.0000763	0.65
193.2948761	1.89
197.0703735	2.01
201.1003418	1.04
202.8675537	1.63
209.1575623	1.11
211.1811218	3.62
215.2077942	0.91
221.2537842	0.43
223.0890503	8.59
225.3472290	0.80
231.2611084	1.18
235.1921997	1.27
245.2475586	3.73
247.1360779	2.57
251.5619202	0.95
257.1785278	1.49
261.2536011	2.55
263.1760864	6.07
265.1279907	5.23
268.8814087	0.63
270.9407654	0.28
279.2992554	2.07
283.0855713	1.46
291.0953979	3.22
293.4783936	1.74
297.3032227	1.27
301.1379395	2.51
305.6075439	2.63
307.4194946	0.96
313.3790283	1.86
315.1367188	0.40
317.2702026	1.11
319.3511047	0.52
321.2823486	3.30
323.1723022	4.20
333.4049072	0.68
337.2660522	2.28
339.3275146	1.55
341.2423706	6.56
343.1599121	3.91
345.4033203	10.50
347.3568726	0.40
355.3491211	1.55
357.3245239	1.96
359.2498779	0.76
363.3237305	5.33
365.3733521	1.95
373.2924805	31.33
375.3769531	8.71
381.2714844	6.57
383.1847534	11.03
391.4182129	5.80
393.3840942	3.84
399.1770630	6.39
401.2354126	59.63
409.2098389	4.08
411.4141846	10.96
415.1396484	1.20
419.4066772	27.04
433.3842163	2.66
437.2495117	29.45
455.2764282	15.12
461.2149048	0.44
473.1776733	3.18
486.2928467	0.44
487.3169556	3.33
522.3450317	4.36
532.2454224	0.48
545.5829468	1.24
548.2559814	0.36
558.1327515	2.77
558.8100586	0.44
573.8141479	0.48
576.4061279	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1069.5024
Annotation	Mycaloside J
Peak:m/z	Relative Intensity
410.2088623	0.09
625.4885254	0.04
639.5573730	0.05
727.7985840	0.09
736.4471436	0.06
765.6114502	0.08
769.3742065	0.17
797.1544189	0.10
799.2336426	0.16
813.4558105	0.05
823.3062744	0.10
841.6037598	0.35
845.6339111	0.12
855.3608398	0.13
873.3616943	0.41
883.7237549	0.04
887.5762939	0.51
891.8911133	0.06
901.4703369	1.07
907.3044434	0.15
916.4262695	0.07
917.4796143	0.74
935.3574219	0.23
938.4718018	0.18
949.3968506	0.08
964.7830811	0.11
975.6564941	0.10
993.3288574	3.07
993.9432373	0.64
1011.8372800	0.18
1025.4904790	0.06
1028.0765380	0.25
1033.4794920	100.00
1034.2329100	0.63
1051.5959470	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.15
Annotation	Puerarin xyloside
Peak:m/z	Relative Intensity
161.0864868	0.09
196.7062988	0.05
200.2799835	0.04
215.1516876	0.12
223.1058655	0.02
233.0446777	0.28
239.5044403	0.07
255.1900940	0.10
271.0291748	0.04
277.2656860	0.41
281.2973022	0.24
286.4636841	0.04
289.0502930	0.08
293.3001099	0.12
297.1490784	0.09
301.1588135	0.05
306.3140869	0.10
307.4775696	0.11
311.1930542	0.50
313.0111694	0.05
317.3157349	0.09
323.1132812	0.04
324.3048096	0.05
325.1086426	0.38
335.1708984	0.31
341.1726074	0.10
342.8885498	0.10
347.2469482	0.04
351.1496582	0.11
353.1345825	28.74
354.2194824	0.39
360.3187866	0.04
361.2501221	0.11
363.0161133	0.06
365.1784058	1.20
367.2668457	0.29
370.9730835	0.13
375.1450806	0.06
379.1195679	0.37
381.3518677	0.11
383.2025757	24.50
384.0571899	0.84
384.6956787	0.08
385.3269043	0.05
389.2946167	0.19
393.4002075	0.05
395.3195190	2.01
397.1176758	0.31
402.3700562	0.44
407.1471558	0.15
409.2453003	0.24
413.2058716	6.00
414.2340088	0.11
415.2479858	0.45
416.1959839	0.28
419.3737793	0.32
421.0771484	0.46
421.6823120	0.02
425.2798462	2.34
426.3200073	0.15
427.7045898	0.17
430.9616089	0.11
435.5882568	0.04
437.3311768	0.44
439.2855225	5.75
440.5366211	0.07
441.3889160	0.46
443.1549072	100.00
444.1087036	2.63
445.1682129	0.05
447.0683594	0.16
448.9876709	0.03
451.3603516	0.51
452.0557861	0.07
453.4347534	0.03
455.1642456	3.54
457.1906738	21.86
458.2051392	0.45
458.9060669	0.11
461.2498169	0.34
469.2044067	3.17
470.5060425	0.36
471.4858398	0.23
473.1619263	45.50
474.2221680	1.92
474.8408813	0.11
479.2026367	0.18
484.2834473	0.04
485.1881714	3.28
487.2700806	5.55
499.3463745	0.12
501.1607056	0.26
502.1998901	0.24
503.1862183	5.68
503.8025513	0.03
509.4014282	1.72
510.2663574	0.11
511.2956543	2.81
512.0409546	0.53
514.6615601	0.70
515.4746704	0.42
517.1963501	0.12
518.4266968	0.05
524.2000732	0.89
528.1026001	0.93
529.2729492	24.93
530.3300781	0.63
531.5927124	0.18
532.2352905	0.09
537.4605103	0.22
538.9248047	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3387
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
164.9637604	0.08
166.0099182	0.27
184.0366974	88.98
188.1694946	0.07
214.9454651	0.09
222.2374573	0.19
226.9757996	0.21
241.0516205	0.15
252.9953308	0.21
258.1870117	0.34
279.1251221	0.09
282.8980713	0.18
300.3012085	0.20
312.9435425	0.09
319.3361206	0.17
337.3368530	0.27
358.3473511	0.06
363.2018433	0.10
379.3308105	1.01
384.1353149	0.18
412.4528198	0.08
429.7445679	0.39
431.4580078	0.07
440.3015747	0.43
453.0806274	0.20
457.2618408	0.41
460.1762085	0.06
461.5671387	0.33
463.2305908	0.32
465.9572754	0.12
471.2714844	0.33
474.0621948	0.12
475.5328979	0.28
476.4114380	0.08
485.3198853	0.22
502.4208984	100.00
503.4437866	0.33
521.7731323	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.228
Annotation	2-hydroxyhexadecanoic acid
Peak:m/z	Relative Intensity
88.92189026	15.03
99.12588501	1.07
116.7570953	0.99
128.9711151	2.92
134.763382	0.90
137.0881195	1.69
151.1494904	0.90
183.3054352	1.33
187.283844	7.82
191.2519073	1.07
192.765625	2.02
197.1115723	10.86
199.2254028	12.03
205.1013947	1.16
207.1598358	1.07
209.2707367	5.71
211.3269196	8.84
225.2167511	100.00
227.041275	17.06
229.2507629	35.45
235.1360016	11.03
239.0316925	0.99
241.2608795	2.13
242.8527374	1.07
253.2628174	37.71
255.2796631	6.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	588.9
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9463196	0.26
273.0276184	1.02
274.1900635	0.08
275.0125122	0.21
344.0601196	0.30
359.3024292	0.28
387.9809570	0.29
389.0162354	0.17
414.9836426	0.20
427.1310425	0.94
428.1369629	1.21
429.0985107	5.19
430.0464478	0.05
430.9636841	0.22
432.9012451	0.29
435.0552979	0.28
443.1206055	0.52
457.1673584	0.13
458.9116821	0.12
472.9524536	1.62
473.9249878	1.31
475.0232544	3.80
476.7987671	0.11
486.8018799	0.09
491.9869995	0.22
514.0849609	0.20
515.1398315	0.27
520.0485229	0.10
530.2890015	0.09
531.0198975	0.17
541.8602905	63.57
542.8413086	100.00
543.6710205	0.77
545.0822144	0.22
557.3007202	0.16
559.7586670	0.06
560.9637451	1.66
561.9902954	0.11
571.0973511	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8974
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0201569	0.54
160.1802521	0.01
175.0612183	0.35
199.0349426	0.02
216.9485168	0.03
228.9026947	0.08
244.9549561	0.10
270.9071350	0.02
273.0278320	6.46
289.0232544	9.56
363.0298462	0.12
371.2029419	0.03
386.9500732	0.47
399.9044800	0.03
401.0794067	0.14
402.8965454	100.00
403.5118408	0.28
427.0870972	0.06
428.0646973	0.02
429.0618896	0.03
429.8613892	0.02
431.0451660	0.03
432.1207886	0.03
442.7934570	0.21
443.4307251	0.02
445.2514038	0.02
459.5130615	0.04
460.1173706	0.01
461.0626221	0.06
469.1431885	0.07
470.0132446	0.44
470.9838867	4.53
472.8518066	0.11
489.0560913	0.01
498.0148926	0.03
498.7227783	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1299
Annotation	Malvidin 3-(6-acetylglucoside)
Peak:m/z	Relative Intensity
179.2249756	0.06
200.9963074	0.07
221.1671295	0.14
221.9934387	0.06
230.1602936	0.04
233.1508636	0.18
245.1375122	0.06
263.1821899	0.16
265.1159668	0.11
268.0003052	0.03
275.1636353	0.03
281.2008057	0.11
282.1092529	0.05
293.5057983	0.14
301.0846558	0.23
307.2602539	0.15
310.2748413	0.06
311.1850586	0.58
313.2570190	0.02
321.3018188	0.08
324.9075928	0.13
326.1272583	0.05
327.0202026	0.03
333.2186279	0.10
334.9419556	0.19
335.7484131	0.04
341.3236084	0.07
348.0211792	0.05
350.2167969	0.04
351.2028809	0.08
353.1494141	15.33
354.2562866	4.91
355.3632812	0.05
361.4945068	0.06
364.1007080	0.02
365.2738647	1.18
366.1546021	0.31
371.2943115	0.04
372.2213135	0.02
375.3184814	0.02
378.3498535	0.10
379.1547852	0.43
380.2100220	0.26
381.5723877	0.07
383.1706543	16.90
384.1942139	4.82
390.5578613	0.05
395.1605835	1.13
396.3071899	0.34
397.1533813	0.06
398.2366943	0.12
401.2633667	0.10
403.3005981	0.05
404.2665405	0.03
407.3062744	1.03
408.2792358	0.42
409.2654419	0.11
410.3012695	0.21
411.0134888	0.02
413.1788940	5.17
414.3559570	1.12
415.0505981	0.04
416.0264893	0.05
419.1050415	0.07
421.3034668	0.04
425.2138672	7.31
426.2801514	1.64
427.5872803	0.05
428.8453369	0.03
430.5344849	0.03
431.1741333	0.04
431.8909302	0.03
433.3706055	0.03
434.3065186	0.03
437.3469238	0.47
438.2538452	0.25
441.3066406	0.54
443.1907349	100.00
444.1976318	30.09
445.2235107	0.19
451.2078857	0.07
453.5262451	0.06
455.2055054	7.53
456.2551880	1.62
457.3733521	0.05
467.9023438	0.04
469.3921509	0.55
470.2266235	0.21
471.2621460	0.11
473.2280273	65.86
474.1704102	20.33
475.1103516	0.05
478.4211426	0.06
485.2864380	1.73
486.1653442	0.64
487.3170776	0.49
487.9447632	0.03
488.6442871	0.07
490.3609009	0.02
497.2047119	3.93
498.1757202	0.63
499.6388550	0.03
501.4038696	0.03
503.2549438	2.85
504.2342529	0.81
511.3146362	0.02
512.7864990	0.05
515.2149048	21.55
516.2172241	6.49
517.3016357	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1087
Annotation	Maesopsin 6-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
131.1084137	0.10
149.190506	0.08
151.9568634	0.35
163.187973	0.14
167.1837158	0.25
178.9900055	1.56
181.2809143	0.13
198.4324951	0.09
199.317627	0.13
200.8788147	0.16
209.0304718	0.31
215.1398926	0.20
223.0499725	0.12
225.1654663	0.18
236.242157	0.07
239.4344482	0.26
243.1577454	1.44
245.1684875	0.08
251.360199	0.07
253.1673279	0.10
259.151825	35.44
267.2514038	0.09
268.0914612	0.34
269.0753174	35.12
271.2743225	0.05
274.2165833	0.25
281.1048584	0.18
282.1577148	0.12
283.1660767	0.45
285.1646423	0.08
287.0534668	100.00
287.7091064	0.23
291.0702209	0.13
293.1550903	0.57
294.2801819	0.06
301.3518677	0.19
311.0980225	2.60
312.9548645	0.06
317.2187195	0.15
321.2463989	0.22
325.3006287	0.58
327.2123413	0.28
329.0732117	0.50
332.1401062	0.04
333.3933411	0.07
341.1442261	0.09
342.1236877	1.16
343.162262	0.19
344.372406	0.21
345.3430786	0.13
350.9552917	0.27
353.1749268	0.43
360.9698486	0.13
364.5903931	0.11
372.1239014	0.13
373.1816406	0.67
374.2768555	0.04
375.3798218	0.25
377.0786438	0.23
385.3791809	0.11
389.249176	0.14
392.1098328	0.10
396.9688416	0.08
401.348114	0.80
402.1613464	0.68
403.2662659	2.45
405.2054138	0.52
419.35849	0.09
421.1935425	2.38
429.5503845	0.16
431.1541443	6.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.2264
Annotation	(-)-Malyngolide
Peak:m/z	Relative Intensity
122.9836121	0.99
154.9552612	3.31
185.099762	1.69
191.363739	3.92
198.7273712	1.63
213.2191772	0.79
235.3643951	2.06
253.2119293	100.00
271.0805664	7.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
97.20528412	0.26
106.9814529	0.44
109.0625305	1.04
114.8868713	0.29
121.1545258	2.60
123.1816406	0.44
124.8456573	0.18
135.0100555	2.46
137.0372772	0.15
142.9754181	0.15
144.9631958	0.24
147.1294556	0.70
149.0534973	1.40
150.998642	0.71
152.8606262	0.17
155.1792297	0.24
157.2150879	0.21
160.8009491	0.17
163.0569458	0.78
165.2445984	0.36
166.7585602	0.29
169.182251	0.52
170.271698	0.51
171.1946564	0.80
173.0688782	0.87
174.9767303	0.43
178.3067932	0.27
179.0067291	0.86
185.120285	0.24
186.9852295	1.68
197.1929169	0.39
198.8401794	0.15
201.0377197	0.34
203.0919189	0.47
209.3027649	0.68
210.9844971	0.71
217.1295166	0.43
219.1233215	0.44
221.1862183	0.29
223.4017334	0.56
224.8788757	0.36
227.9987183	0.16
229.4216614	0.67
231.1855774	0.77
239.1642151	0.44
240.5754089	0.78
241.2193909	0.29
245.2720642	2.32
247.1325378	2.89
252.9471436	0.99
254.1281738	0.17
255.0925293	0.42
260.2033386	1.03
267.2177429	0.27
273.539093	0.12
277.1313477	0.38
277.934845	0.71
281.3393555	0.85
283.2370911	0.77
284.9085693	0.33
286.3441772	0.39
287.3352661	0.76
293.765564	0.21
295.1944885	1.89
296.3953857	2.99
299.3609009	2.15
299.9714966	0.30
305.1611633	2.83
313.2718201	0.61
321.2317505	0.30
321.9493713	0.25
323.2373657	100.00
323.8450012	0.89
341.2229919	3.53
342.1525879	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.153
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0093384	0.02
155.9292297	0.03
158.7212524	0.04
184.0437622	0.02
199.0331116	0.04
215.1449280	0.05
232.7832489	0.01
256.0751953	0.07
259.0797729	0.02
262.1253662	0.02
277.8813782	0.03
282.1284180	0.02
296.0422363	1.00
297.1613159	0.28
306.0056763	0.01
312.3074951	0.22
313.2167664	0.93
320.0610046	0.03
328.2322388	0.03
330.1533203	100.00
330.7785339	0.29
338.1647949	0.02
351.2537231	0.03
353.1529846	0.03
366.1929321	0.14
372.2690125	0.03
384.3681335	0.18
397.2275085	0.02
413.4012451	0.02
423.0313416	0.01
428.8137817	0.03
429.7513733	0.10
441.2190247	16.31
442.0236511	0.08
444.3455200	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.13
Annotation	Abscisic acid
Peak:m/z	Relative Intensity
80.43669891	1.29
81.07171631	0.77
83.10766602	1.14
97.0340271	0.73
111.003418	4.08
151.2204742	0.37
153.0890961	100.00
162.88591	0.34
169.0283356	1.02
174.6941071	0.46
177.3433075	0.43
181.2393646	1.53
182.8964691	0.33
189.9784088	1.11
201.1732635	3.19
203.3553925	0.93
204.1421051	2.92
217.2039795	0.85
219.1885071	44.76
235.1336823	2.67
243.0978546	0.90
244.0877838	0.62
245.1881866	17.73
247.2213135	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	624.2332
Annotation	Unknow
Peak:m/z	Relative Intensity
163.0550232	0.16
180.7593994	0.07
195.1647949	0.12
199.1529846	0.48
218.9081421	0.27
222.7389526	0.33
241.1814117	0.30
246.5545197	0.08
252.7851105	0.67
258.5039062	1.12
271.0105896	5.00
276.6460266	0.15
280.5086670	0.17
282.1002808	1.86
288.4069824	2.49
289.0217285	9.85
306.5131226	4.25
307.1524353	3.34
314.8961792	0.14
324.3275146	19.40
324.9787598	100.00
339.6221313	0.19
340.4205933	0.35
341.4730225	1.87
342.7622070	73.88
343.4482422	0.72
370.1055908	0.21
401.6445312	0.12
403.1077271	0.22
416.1864014	0.48
420.8560791	0.35
428.1334229	0.53
432.9495850	0.14
438.2094727	0.34
439.4869385	0.34
441.3146362	0.36
444.0127563	2.08
449.3667603	0.19
450.7904053	0.99
451.4328003	0.26
455.4519653	0.14
462.0100708	19.00
468.9126587	0.90
477.0548706	0.72
486.7369995	3.97
490.4097290	0.73
491.2517700	0.62
503.9909058	0.06
504.8351440	1.78
519.1366577	0.12
541.7637939	0.30
606.0623169	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
100.6114807	0.66
117.0280228	2.29
121.0772934	0.66
123.2138367	1.61
123.9070892	2.46
125.0348663	0.60
130.6359863	1.12
135.4110413	0.84
136.9925842	1.13
142.7917175	0.71
146.883606	4.50
149.3218231	1.51
151.1846924	0.72
154.9617004	1.16
158.8471985	2.55
165.2988892	0.76
167.9445953	1.35
168.9808197	2.79
172.901123	3.43
175.147171	1.14
183.060379	4.80
205.2829742	5.62
210.8625488	1.46
213.0993652	4.14
216.9806213	6.50
223.3766174	4.15
225.0149536	1.23
231.2009277	2.66
239.5744019	0.54
244.9452515	0.49
247.1310425	1.91
271.5589294	0.89
281.2812805	2.86
287.4664917	0.99
295.0487671	5.22
299.0077515	1.40
305.1976929	3.74
321.3287354	1.29
323.237915	100.00
324.1472168	7.04
333.1473999	1.60
341.3372192	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.6521721	0.62
58.9056396	6.30
60.9678345	1.11
66.8828430	0.60
68.9141235	0.92
70.9105301	7.58
72.8878174	0.60
81.1378555	2.71
82.8922882	1.92
84.8651733	84.07
85.6362610	0.33
86.9268646	21.49
92.9509430	63.82
96.0046997	0.17
96.8616791	0.49
99.0509796	3.47
100.7938995	0.70
109.0521545	21.17
111.0368195	42.48
115.0098877	2.63
117.7664642	0.26
118.7195892	0.19
126.9844208	100.00
129.1192474	0.85
136.9575348	4.50
143.0072479	2.83
144.8938141	3.73
146.8790741	1.14
153.0214539	10.67
155.0399017	10.80
171.0007782	25.93
173.0448761	77.11
190.9459991	1.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0878
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
98.9349747	0.09
107.9919281	0.05
123.0383377	0.80
125.1474152	0.10
138.8308411	0.22
149.2018433	0.03
161.0947876	0.10
162.6365967	0.07
165.1499634	0.22
167.0655975	45.71
179.1981201	0.51
185.0284271	0.06
188.9411163	0.13
191.0082397	100.00
195.1004028	0.07
200.9009857	0.09
206.0523987	0.22
209.0361633	3.73
213.0356140	0.12
221.0357971	11.31
223.0832825	0.23
227.2982178	0.05
229.0160217	0.08
231.0545654	0.09
233.2448120	0.87
235.1210022	0.06
239.0967407	0.38
244.6583252	0.18
247.2833557	0.05
251.0771484	0.92
253.1928711	0.04
261.5709839	0.26
267.4573975	0.05
269.0322876	7.33
275.2945251	0.18
281.0113220	0.18
282.2447205	0.19
283.1228638	0.66
284.9462280	0.60
286.1788635	0.07
287.0574646	0.07
293.1050415	0.13
299.2742615	0.11
311.1143494	5.03
314.7742920	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
76.86149597	0.41
97.00105286	0.12
100.8101349	0.07
117.0630798	0.44
130.1162872	0.43
142.905777	0.09
145.9529266	0.62
148.9462128	1.25
157.0747223	0.28
166.259491	0.16
167.1274414	0.26
168.4373016	0.29
169.1735535	0.08
173.1167145	0.16
173.9788055	0.47
177.9984589	0.22
179.1422424	1.95
180.1309357	0.60
181.0674896	1.90
184.339859	0.07
185.1164703	0.12
192.0701904	0.37
193.1080017	0.64
193.8920593	0.09
195.0613098	1.38
197.3231964	0.22
205.0078278	0.09
206.0947418	1.88
207.0563812	10.29
208.1543579	10.35
209.1835632	4.95
210.0550232	1.34
221.1495514	0.65
222.1676788	7.43
223.0632935	11.02
224.117157	3.23
225.2860565	0.71
233.3381805	0.42
234.4412384	0.15
235.1672363	0.39
251.0813751	100.00
252.1644287	37.75
253.1250458	2.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2756
Annotation	Eurystatin D
Peak:m/z	Relative Intensity
127.2156525	0.05
130.6610413	0.04
131.3088074	0.09
143.1585693	0.07
148.9649048	0.10
161.0015717	0.15
163.2056885	0.03
179.0965576	0.45
211.4224548	0.17
212.3144684	0.04
222.0237427	0.10
223.3022156	0.10
225.3460236	0.08
233.3360748	0.04
235.8218384	0.09
237.4572296	0.04
239.3141785	0.42
240.0628967	0.11
241.2236023	4.45
242.3093872	0.96
250.3938599	0.08
253.2936096	0.15
255.3732605	1.45
256.3633728	0.19
257.2334290	0.05
262.1994324	0.03
263.5550232	0.07
265.3299561	0.26
269.3412170	1.95
270.6806335	0.23
271.3675842	1.73
272.1052551	0.13
273.0994873	0.03
278.1584473	0.09
283.3195801	8.80
284.2319336	1.01
285.2418213	0.23
287.2680359	100.00
288.2684631	17.09
289.4719543	0.04
297.2380371	0.16
299.5439148	0.04
300.3467407	0.10
305.9741821	0.08
311.2965088	0.15
312.5597839	0.17
323.0058289	0.05
326.6332397	0.06
329.2684021	5.93
330.3395691	1.31
335.1781616	0.12
341.3087769	0.70
342.1301880	0.07
359.2083740	0.41
362.3243408	0.09
363.2222900	0.03
364.1874695	0.17
365.8597412	0.04
366.8249817	0.19
371.3527832	0.02
377.3750916	0.10
382.2087402	0.12
389.6502991	0.12
391.4231262	0.06
399.3034363	0.03
404.9814453	0.23
406.2245178	0.06
408.3921814	0.11
412.3866882	0.08
413.3071594	0.07
414.1067810	1.04
415.2662048	0.12
431.2356262	0.11
432.4266968	0.05
433.4582214	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
78.81131744	0.19
85.04067993	0.23
95.00410461	0.75
96.81725311	0.49
99.18001556	0.28
107.214035	0.27
109.3124695	0.22
110.8123169	0.39
113.0090485	0.42
121.0919495	0.38
122.4558105	0.14
123.2031326	1.28
126.8433838	1.32
132.9730225	0.73
135.1487427	0.28
136.8428345	0.14
139.0528412	2.73
151.0244751	0.33
152.7408447	0.76
154.9934387	0.48
156.8775635	1.16
161.1083984	1.30
162.9351959	0.11
165.2814941	0.65
167.1384583	0.51
171.0954895	0.38
173.0018463	0.54
178.5233459	0.44
179.2108154	0.75
181.250885	0.18
183.1583557	0.81
185.21138	1.43
187.0804291	0.52
189.3843079	0.09
193.0975647	0.11
193.9597778	0.15
195.3774719	0.45
196.9728699	3.78
199.1019592	1.22
203.0679932	0.35
207.2419434	0.33
209.383606	0.76
211.1147461	1.38
212.8771973	0.23
215.1777649	0.21
221.1385498	3.83
223.2433167	0.93
225.1582031	1.15
226.1331482	0.47
227.2621765	0.39
233.4524231	1.28
235.2304993	0.38
237.1717834	6.80
239.0917664	26.22
241.1618652	0.89
243.156311	0.48
251.1976318	3.22
253.3241882	0.64
254.2025146	0.28
255.2730408	3.97
256.3820801	1.28
257.1833191	1.14
261.2067871	5.21
269.2006836	0.77
271.0653076	0.30
277.3940735	0.12
279.2380371	100.00
281.2220154	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Galactinol
Peak:m/z	Relative Intensity
100.9537506	7.89
112.9697876	17.79
116.9650116	1.27
118.9493256	19.23
124.9283981	3.19
130.9449463	4.85
133.1439514	1.92
142.9621277	21.51
149.0917358	3.28
160.9909363	18.98
179.0492401	100.00
187.1103821	0.51
232.9861145	0.49
243.0656738	1.31
245.2789001	0.41
249.3160706	0.38
251.1411133	2.11
257.1697388	5.65
280.9842529	4.83
294.9876404	6.86
296.9730835	0.89
298.9898071	11.76
300.0595093	0.68
311.28479	0.54
313.0366211	0.37
315.1759949	0.51
321.0682983	1.61
323.2406006	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.9742279	0.25
208.9089966	0.54
230.8614655	0.12
290.8123474	5.62
291.8443298	0.52
292.9003296	7.48
294.5885010	0.04
317.9467773	0.06
371.1777954	0.10
374.6618652	2.61
376.5461426	6.88
377.3609009	0.04
382.1102905	0.18
392.9758911	0.63
401.9418335	0.05
437.0318604	0.05
438.9220581	0.39
458.5443726	26.42
460.0719604	58.56
460.6903687	100.00
473.9656372	0.09
475.8347168	0.29
497.9708862	0.22
498.9006958	0.04
526.8459473	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	440.248
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
126.9681091	0.89
132.8210144	0.80
144.9627075	2.24
149.7942047	0.86
150.9203186	0.26
161.5849152	0.36
162.9690857	6.05
165.0599060	0.29
173.2238312	0.44
176.7144623	0.23
179.5568695	0.27
180.3745728	0.91
183.0048523	0.57
186.8936462	0.26
189.0602417	0.53
194.8375854	0.87
197.6914062	0.33
199.1391602	0.59
204.0248260	0.85
205.2887573	0.35
207.1414490	1.13
210.9189911	0.83
216.8527527	5.88
220.0737610	0.74
222.9240265	2.61
225.1836243	3.17
232.9721222	0.40
237.0457458	1.96
239.0256958	0.31
240.9661255	7.74
243.0093079	6.63
255.2872314	1.42
258.4062500	5.06
259.0161438	35.37
261.3150635	0.60
265.2735901	0.25
273.0643005	4.59
276.3899231	2.35
276.9980469	9.16
281.1706543	0.56
290.6970215	2.54
293.1812134	1.17
294.8375549	100.00
295.4490967	1.32
297.2608948	0.49
301.0208435	0.25
302.1066895	0.47
307.6636047	1.72
312.2344666	4.38
312.9454956	4.56
349.5126038	0.71
350.9191589	0.37
351.7648926	0.21
369.3978577	0.76
382.4758911	2.50
387.2720947	0.38
397.2427673	0.52
404.3917236	2.48
405.1723633	1.97
421.7729797	0.51
422.8208008	4.96
430.8482361	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1534
Annotation	Fragransol-B
Peak:m/z	Relative Intensity
108.928833	0.13
118.9655762	0.36
121.9675064	0.14
137.0030823	0.68
138.7552795	0.19
148.9626617	0.55
151.0500488	9.50
156.962738	0.77
161.0814514	0.21
163.1566925	0.16
169.0369263	0.56
175.2005005	0.12
176.5236664	0.28
177.2018127	0.20
183.1156921	0.58
189.1522522	4.10
190.78508	0.25
193.2091675	0.38
197.2074127	0.52
207.0059662	3.93
212.9108276	0.17
215.2860413	0.27
227.0592957	0.43
231.1478271	0.19
239.1130371	0.27
249.1712341	0.44
252.9933777	0.68
253.8087158	0.10
255.0639648	2.14
267.0988159	0.48
269.2180481	0.09
271.2208252	0.33
273.1411743	0.25
275.0827332	0.90
281.1203918	2.78
285.1782837	11.83
287.1279907	40.93
289.3359985	0.37
290.086792	0.33
295.1304016	0.32
301.228241	1.41
307.7831421	0.44
313.1462708	100.00
314.1121216	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.1043
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9467926	0.11
171.1789703	0.26
180.9146271	0.24
184.0978088	0.17
185.2761230	0.03
194.9808044	0.10
199.0773010	1.06
231.1051483	0.52
251.1134033	0.24
265.2650146	0.48
288.6387329	0.03
289.3685303	0.12
301.2120361	0.14
306.3387451	0.19
307.2689209	0.12
316.0406494	0.17
317.2371216	0.22
324.2334595	0.06
334.0963440	1.21
335.0321960	2.23
347.1903687	0.21
352.0758057	100.00
352.6876526	0.48
434.9694519	0.25
463.2826843	9.08
464.2070007	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.0146
Annotation	Myricatin
Peak:m/z	Relative Intensity
170.9598999	0.06
183.0506287	0.01
187.1082153	0.01
187.9274597	0.13
190.1182404	0.01
191.1366577	0.01
205.0433960	0.06
212.8656006	0.03
213.9058228	0.01
214.9513397	0.14
216.8227539	0.02
228.9458160	0.28
230.1199036	0.01
231.0021667	0.29
231.9932556	0.01
237.0329285	0.07
253.1018372	0.03
254.3194122	0.03
257.1665649	0.07
258.1180420	0.10
260.2734375	0.02
269.0558472	0.05
271.0366821	0.41
279.2008667	0.03
281.0999146	0.17
282.9999390	0.12
285.7565918	0.05
287.1374512	0.06
288.3688354	0.02
297.2802734	0.03
298.0988770	0.02
306.3228455	0.08
307.2627563	0.01
310.1763916	0.03
313.8448486	0.03
315.0486450	3.71
316.0170288	0.07
317.2096558	0.05
325.1729126	0.11
327.0924683	2.86
333.2126465	0.33
341.2634888	0.09
342.0727539	0.01
343.2064209	0.03
356.2057495	0.02
357.2817993	0.35
359.0287476	100.00
360.0805664	5.14
361.1206665	1.85
362.1173706	0.08
366.3538818	0.02
370.2588501	0.05
378.1403809	0.02
386.5026855	0.04
401.3063354	0.05
416.7796631	0.07
421.9172974	0.06
428.5491333	0.02
429.1883545	0.03
435.4331055	0.01
444.5841675	0.06
445.9786377	0.02
447.1425781	0.22
460.9138794	0.23
463.0354614	0.21
469.2586670	0.03
486.6343384	0.01
506.9979248	4.82
514.1015015	0.04
515.0060425	0.02
517.4968872	0.01
531.0380249	0.04
533.0006104	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
76.04307556	0.13
82.07550812	0.16
96.9684906	0.09
104.9770203	0.32
109.07164	0.12
116.7721405	0.33
130.0539856	0.88
130.8380432	0.12
137.9680023	0.09
145.498764	0.35
147.0578918	0.14
149.0337982	1.82
150.0470886	0.64
151.0694122	0.06
165.1506653	0.09
167.4671173	0.10
168.9495239	0.37
173.0062103	0.15
174.0795135	0.34
178.0584564	0.07
179.0399323	1.24
180.0432587	1.22
181.1096954	0.86
181.8272858	0.13
183.33638	0.26
184.9332581	0.36
187.0634613	0.16
191.3516541	0.07
193.0260925	0.86
194.2224426	0.29
195.0808258	1.05
196.2891388	0.38
205.0398102	0.22
206.100235	1.99
207.078537	9.25
208.0817108	8.42
209.0615234	3.55
210.0837555	0.44
210.872818	0.09
216.0576935	0.08
216.9324951	0.22
220.1378021	0.10
221.2358551	0.49
222.0785675	8.12
223.0597839	12.75
224.1332855	2.61
231.006485	0.17
233.1613312	1.04
234.4974365	0.50
235.0986328	0.31
236.1152496	0.57
237.1702118	0.09
249.3662109	0.12
251.0736847	100.00
252.1510773	37.33
253.1106567	4.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.96
Annotation	Unknow
Peak:m/z	Relative Intensity
233.3156433	0.10
234.0816650	0.28
241.9744873	0.19
243.6322937	0.39
245.3235779	0.10
246.2640991	0.14
249.1861572	0.13
260.8588867	0.42
261.9702454	0.09
262.9904785	0.83
263.7173462	0.11
264.9345093	0.52
266.7731323	100.00
267.4550476	0.60
278.6600342	0.09
279.8988953	0.12
281.2164307	0.63
283.7578735	0.88
284.6638794	8.27
289.0397644	0.18
302.8944702	0.10
305.4234619	0.06
307.5299072	0.06
316.5928650	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	779.92
Annotation	Unknow
Peak:m/z	Relative Intensity
252.2158966	0.48
497.9620972	1.98
594.3670044	0.42
606.4773560	0.48
619.0127563	0.41
633.0527954	0.29
650.5177612	0.46
667.5737915	0.37
676.2788696	0.80
683.4190063	1.95
684.3317261	1.78
724.4475708	3.91
732.7523193	3.29
733.4427490	0.39
738.9913330	0.86
826.6998291	5.42
827.6071167	0.48
828.7340698	0.17
921.8115845	0.37
927.0701294	0.24
1068.5916750	2.65
1250.7166750	0.37
1273.1153560	0.19
1658.6373290	0.19
1706.6368410	0.33
1754.0709230	0.78
1777.1278080	1.01
1780.8734130	0.87
1784.2526860	0.76
1788.7218020	0.28
1792.2208250	0.89
1798.7701420	0.59
1807.5113530	0.22
1811.9456790	0.35
1824.8499760	0.22
1826.8732910	0.92
1831.7199710	14.35
1839.1765140	8.00
1849.2413330	0.50
1850.1643070	0.22
1863.5617680	0.88
1864.7791750	0.21
1867.2403560	0.34
1868.3111570	1.52
1879.3619380	0.19
1890.7239990	0.34
1893.3748780	0.70
1900.6029050	0.87
1906.8952640	3.70
1907.9494630	0.21
1908.8304440	0.54
1910.0667720	0.34
1911.9910890	0.52
1916.0388180	22.21
1919.2789310	1.53
1922.4989010	6.99
1926.2663570	0.15
1927.2698970	13.14
1927.8814700	0.59
1930.2941890	0.44
1935.2297360	1.18
1937.4001460	0.45
1938.3238530	1.90
1945.1453860	0.20
1946.3431400	0.87
1948.2081300	0.61
1949.0998540	21.46
1950.2447510	1.80
1951.1976320	0.24
1958.1433110	2.34
1959.7487790	1.40
1960.7185060	9.83
1964.0920410	0.50
1965.2020260	15.24
1968.0970460	1.82
1969.1843260	0.41
1970.2318120	3.87
1971.1287840	0.57
1975.0339360	24.73
1976.3575440	0.29
1977.9791260	1.67
1978.9224850	1.30
1980.9708250	0.67
1983.1177980	0.70
1984.6193850	9.86
1986.4991460	0.43
1987.5394290	3.09
1988.3739010	0.50
1989.6444090	0.52
1990.6612550	3.03
1992.3812260	0.61
1995.1356200	6.18
1995.8049320	1.49
1996.5819090	0.32
1998.5653080	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
135.9718170	16.17
141.0157013	0.02
164.9477692	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	456.2483
Annotation	Malyngamide C
Peak:m/z	Relative Intensity
134.0381622	0.10
172.2840424	0.13
204.2598724	0.68
228.2762756	0.38
230.1488953	0.22
235.0758057	0.28
263.2628479	0.23
276.3001099	0.14
291.3085938	0.10
294.0295410	0.29
310.1989136	0.62
317.1647644	0.09
318.2609863	3.61
321.3277588	0.28
323.0919495	0.67
324.2615356	0.25
333.4425049	0.32
334.5390015	1.21
335.2684021	0.16
349.2413940	0.49
358.2670288	0.15
365.5346680	0.89
379.3603821	0.33
385.2875061	0.23
406.7043152	0.73
407.3308105	0.26
425.9024353	1.02
437.1637878	0.85
438.2772217	100.00
439.3235168	4.05
450.1161194	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.182
Annotation	1,2,10-Trihydroxydihydro-trans-linalyl oxide 7-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
162.8868713	0.07
233.1145935	0.09
263.1670532	0.03
265.2385559	0.07
284.2462769	0.06
303.8572693	0.05
329.2701721	0.06
339.2096558	0.13
340.1667480	0.04
345.0370789	0.14
346.2816772	0.08
349.3106689	0.10
351.0875244	0.13
353.3225098	0.04
365.0953674	0.04
369.0587158	0.31
381.2232361	100.00
383.3930359	0.32
385.6035461	0.04
390.1923828	0.03
391.1177368	0.10
404.5441284	0.12
406.2653503	0.05
407.2951050	0.05
409.0636292	0.15
410.1608276	0.05
412.0715027	0.05
418.1177063	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1752
Annotation	Genistein 4',7-di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
177.1221924	0.13
217.0028381	0.42
249.8312531	0.21
255.2947998	0.21
272.0874023	0.16
313.2822266	1.32
325.0494995	0.14
337.1300659	0.58
338.1906738	0.39
347.0963745	0.15
365.1741943	0.13
376.336731	0.13
381.2315674	1.67
382.2008667	1.36
384.4248657	0.20
388.0962524	0.37
399.2424316	1.98
400.2037354	2.26
402.2200317	0.15
411.3504028	0.24
417.1231689	100.00
418.1958008	78.74
463.2651367	0.34
465.4142456	0.15
466.348999	0.10
475.616394	0.24
483.5081787	0.67
488.4927979	0.26
500.0479126	0.11
501.3406372	0.15
509.3008423	0.19
510.232666	0.25
526.2652588	0.21
527.3099365	0.69
528.3254395	0.30
545.7802124	1.28
546.8329468	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	385.09
Annotation	(3E)-4-(3-acetyl-4,5,7-trihydroxy-10-oxo-9,10-dihydroanthracen-2-yl)-3-hydroxybut-3-enoic acid
Peak:m/z	Relative Intensity
209.3326111	1.30
253.0856628	1.49
258.9858093	9.86
264.9894714	11.35
269.1648254	1.77
276.8800354	63.43
288.650116	1.94
294.4179688	33.00
295.0651245	94.92
301.0548401	1.76
306.8530884	6.54
324.9886475	71.81
325.9998169	5.55
330.2746582	1.12
330.8798218	1.83
337.0481873	2.76
339.9974976	3.51
349.0712891	44.98
357.4404297	0.77
364.9833069	2.60
367.0877686	100.00
367.886261	2.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	379.97
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0525818	0.04
156.2556152	0.31
161.0322876	0.17
161.9661255	0.07
178.9622498	0.49
184.1044464	0.23
202.0065765	1.11
212.4633179	0.06
217.1430664	0.26
218.1464844	0.91
219.1417847	0.09
230.1439209	0.06
232.0975952	0.18
234.2473755	0.32
243.0590515	0.18
250.1719971	0.27
251.2488098	0.61
260.3623352	0.09
263.1390991	0.12
263.8753052	0.07
284.2252808	0.46
290.0442505	1.57
291.0458069	0.34
297.6979980	0.15
299.7572632	0.45
304.2883301	0.13
305.1868286	1.23
307.2175293	0.05
317.0990601	0.22
318.0586548	0.48
333.0899658	0.23
334.1608276	0.08
335.9292908	100.00
336.5853271	0.15
347.0151062	0.05
349.0130310	0.05
351.1270752	0.11
352.1437378	0.11
361.1263123	0.67
362.1148376	2.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9199
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1177368	0.01
159.0974731	3.23
160.0590973	0.45
172.1230164	0.01
198.9605713	0.55
200.0185242	0.09
217.1797943	0.14
229.1065674	0.59
230.0402985	0.09
244.9121704	0.01
270.1022644	0.03
271.1418762	0.01
272.9947205	49.49
274.0688477	13.35
384.9751587	0.04
386.9638062	100.00
388.0185242	33.20
412.9931335	0.05
427.0843506	0.05
428.0600281	0.06
429.0911560	0.02
455.1591492	0.06
456.0216064	0.03
457.2335205	0.02
457.8428040	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	306.96
Annotation	Unknow
Peak:m/z	Relative Intensity
73.8132095	0.03
224.7259216	0.05
233.2256470	0.02
237.2090759	0.04
240.0641785	0.03
240.9937744	0.06
261.2849731	0.03
262.7707520	0.09
265.8641968	100.00
266.5122375	0.11
281.2036743	0.07
282.9729614	1.04
283.7273560	3.79
288.8016968	0.03
306.5689697	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1087
Annotation	Galactinol
Peak:m/z	Relative Intensity
96.9806366	0.45
100.9696045	6.87
106.5790634	0.65
112.9477234	19.05
114.9238968	0.73
118.9726486	9.88
121.0415802	0.59
125.0689697	3.47
130.9443054	15.94
142.9942322	28.78
148.9520111	2.84
158.9894409	0.45
160.9878235	23.25
179.0523529	100.00
197.2042694	1.19
256.8471985	0.41
279.3014526	0.70
281.2593994	1.63
295.2316895	2.16
305.0846252	0.98
314.0837402	0.75
322.8247375	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8218384	0.07
179.0151978	0.32
250.3075256	0.06
252.8987122	0.04
274.9485474	0.12
283.1011658	0.07
286.0310364	0.06
291.0177002	0.11
297.2271729	0.23
303.3954163	0.06
341.2318115	100.00
344.9649658	0.11
350.9040222	0.04
355.2036438	0.11
367.2341614	0.04
369.0652466	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
102.2648926	0.20
128.9240417	0.44
129.8968811	1.06
148.7939911	0.25
151.0248871	8.89
152.0385895	3.87
152.8726349	0.16
155.0098419	0.28
167.100174	0.53
170.0843964	0.20
191.2417755	0.14
194.118454	0.37
194.8970795	0.17
196.8838043	0.74
197.9313812	0.58
221.8185272	0.25
225.0822906	1.27
226.3338165	2.90
236.0540924	0.96
238.1489868	0.87
239.1632233	1.95
253.0922241	100.00
254.2114868	6.81
255.2266998	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3309
Annotation	Unknow
Peak:m/z	Relative Intensity
217.9272461	0.08
242.1149750	0.03
245.0544739	0.02
254.8644409	0.06
255.6254120	0.06
279.3345947	2.42
281.5134888	0.02
283.3425598	0.05
320.4979858	0.13
333.1442871	0.29
355.2524414	0.02
358.2709961	0.09
371.5495605	0.03
379.1445923	0.05
381.3651733	0.03
383.1282349	0.03
391.4089966	0.23
406.5870361	0.05
407.6395874	0.06
409.0582275	0.03
412.1998901	0.06
424.9420776	0.06
425.6395874	0.04
426.2780151	0.05
442.5317383	0.06
443.4733276	0.05
445.7839355	0.06
448.3042603	0.17
451.3143311	0.12
463.2588501	0.04
464.4198608	0.08
475.0148926	0.11
476.0747070	0.06
478.1968384	0.04
480.4461060	0.06
487.4124146	0.22
490.2811890	0.04
491.4049683	0.11
492.4030151	0.10
493.3377075	0.09
496.3616333	0.11
502.2226562	0.08
504.3373413	100.00
505.4453125	0.65
509.4740601	0.06
510.1941528	0.04
515.4777222	0.07
517.8328247	0.12
519.4503784	0.04
522.3988647	0.03
526.1383667	0.10
527.2015381	0.04
528.2362061	0.19
534.2058716	0.02
544.3261719	0.03
545.1240234	0.14
545.7821045	0.05
546.3834229	0.07
554.1337280	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.13
Annotation	AN-7
Peak:m/z	Relative Intensity
166.9319763	0.60
188.7480469	0.81
228.077179	1.97
242.0440979	2.18
243.018158	6.05
244.1652222	9.13
244.9684753	0.60
267.2485962	1.15
269.324646	2.60
278.1130981	1.77
283.3494873	0.80
284.7224121	0.78
287.0165405	4.62
305.3388672	1.01
328.6035156	0.81
353.8813477	1.28
359.3633728	1.42
361.316864	1.65
369.1542053	4.68
375.2043762	2.62
378.0068359	1.28
378.9891663	1.32
389.0778809	3.83
403.1463623	100.00
404.4913635	2.37
405.2621155	3.04
407.0570374	1.04
412.3545837	2.18
413.1104736	1.15
415.4385681	0.87
418.199646	4.09
429.43927	0.73
430.170929	0.73
431.3438416	6.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
88.63935852	0.36
92.95701599	0.14
94.96434021	0.46
98.89237976	0.20
100.0343704	0.22
114.7102661	0.26
123.2699814	0.98
124.5274811	0.25
126.9364319	0.23
128.9331665	0.39
132.8678131	1.11
136.8813477	2.60
138.9176331	0.92
150.9778595	1.41
152.9598389	2.06
155.0285339	0.38
160.9950714	0.86
165.2153625	0.51
166.9868011	0.80
169.1790771	0.32
171.2186279	0.44
175.2373199	1.08
181.0710754	0.26
183.0798035	0.91
185.2015839	0.99
187.0392914	0.79
189.3355408	1.39
195.1756897	1.19
197.0674744	10.23
199.0750732	2.84
200.814209	0.15
203.0930786	0.62
207.1707153	0.11
208.9821167	0.24
211.0707703	3.32
214.8224487	1.54
219.1821289	0.82
221.1355286	4.67
223.2669983	0.69
225.0709534	3.55
227.302887	0.48
229.1253052	0.43
233.2463684	1.52
235.0311279	0.31
237.112854	3.91
239.1435547	12.24
241.1885986	0.47
243.0699158	2.61
251.2326355	2.00
252.8009338	0.14
253.4940186	0.21
255.0284729	2.24
255.7237549	0.69
257.3987427	1.44
261.2710571	2.62
262.8415833	0.55
269.326416	0.22
279.2390137	100.00
280.1496277	0.17
296.8272705	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	944.688
Annotation	Unknow
Peak:m/z	Relative Intensity
301.6351929	1.42
334.0518188	1.03
553.5665894	0.32
595.5279541	0.44
664.9657593	1.78
665.6917114	0.31
730.0292969	4.83
795.4888916	0.68
836.8345947	1.32
871.4110718	1.39
872.1276245	0.57
875.4697876	2.58
914.7128296	2.35
918.8713989	0.32
926.2061157	18.46
927.3208618	1.74
996.8896484	3.06
1094.7072750	1.54
1151.5415040	1.83
1201.4084470	2.46
1322.0319820	0.50
1414.4750980	0.64
1521.7633060	0.37
1524.8060300	0.32
1542.0633540	1.27
1543.0200200	0.30
1588.8197020	0.76
1607.3305660	1.84
1642.8055420	0.41
1655.1907960	2.39
1678.6960450	0.19
1704.7053220	3.35
1721.6522220	0.25
1750.4738770	9.80
1755.2093510	0.28
1777.6125490	0.39
1778.3804930	0.26
1781.0003660	0.17
1781.6380620	5.62
1786.1763920	0.17
1793.4085690	0.36
1797.9035640	0.49
1800.0460210	0.63
1804.7141110	1.90
1815.7180180	3.94
1817.5925290	6.68
1827.9729000	5.02
1839.8363040	0.27
1843.3714600	3.48
1845.1066890	0.16
1850.6179200	0.33
1855.6462400	0.72
1880.1929930	0.40
1881.3919680	1.47
1883.4401860	2.64
1885.6437990	4.34
1892.4749760	0.30
1894.9835210	0.66
1899.5467530	0.83
1900.5687260	0.97
1901.4964600	0.23
1903.0773930	0.75
1907.2427980	1.54
1909.6317140	0.28
1910.8216550	0.16
1913.0104980	0.36
1914.1462400	1.46
1917.5599370	1.69
1918.5036620	2.61
1921.4398190	0.60
1924.7720950	27.40
1927.2741700	9.56
1927.8762210	2.73
1929.9066160	2.16
1931.6275630	1.36
1934.6641850	0.12
1935.3615720	9.62
1939.4141850	35.54
1940.3103030	0.15
1941.6856690	0.77
1946.5798340	0.36
1947.3917240	10.82
1948.6931150	1.16
1949.5886230	0.45
1952.2843020	19.58
1955.0863040	0.35
1956.5167240	8.89
1959.9649660	9.02
1962.5295410	15.20
1966.7619630	0.30
1968.2059330	9.65
1969.4647220	14.75
1971.1121830	0.57
1973.0155030	0.16
1974.8337400	5.99
1975.9852290	0.34
1976.8054200	7.28
1978.4215090	13.73
1983.1580810	1.27
1986.3424070	100.00
1988.1774900	0.24
1988.8448490	0.20
1989.6379390	0.37
1990.5938720	0.40
1992.3428960	6.01
1993.9337160	0.44
1996.2546390	0.67
1996.8820800	75.46
1998.0769040	1.01
1999.6751710	34.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.2339
Annotation	Ixerin N
Peak:m/z	Relative Intensity
164.9632568	0.00
189.0468597	0.01
223.0500183	0.03
265.3145142	0.03
305.4295044	0.01
333.4154053	0.02
342.2600708	0.01
373.2810059	0.02
375.2365112	100.00
376.0840454	0.00
393.0793457	0.12
399.2116089	0.04
405.2263184	0.01
417.2058716	0.05
441.0613403	0.03
444.8133545	0.02
448.4096069	0.02
455.0656128	0.02
455.8278809	0.01
473.0311890	0.01
474.0286255	0.02
490.9637451	0.07
492.1210327	0.03
505.5588989	0.03
514.7953491	0.03
518.1213379	0.02
519.3757935	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	452.3209
Annotation	Polysorbate 60
Peak:m/z	Relative Intensity
144.8813171	2.60
162.8806305	8.17
165.8842010	0.09
180.0882874	0.07
201.2303314	0.13
226.4657898	0.18
227.1297913	4.83
244.4195251	0.12
272.3485107	2.99
273.0541077	13.39
281.1660156	0.16
289.5898438	0.08
309.5075073	0.07
310.1298828	0.06
314.3987427	0.05
335.2506104	0.12
345.0819092	0.19
352.6986389	0.09
356.0259399	0.07
371.0466003	0.80
381.2584229	0.14
385.3092346	0.29
392.2994080	0.23
398.8381958	14.94
403.1918030	0.14
405.9028625	0.24
415.4404602	0.12
416.5913391	0.54
417.2157898	0.10
434.8622131	100.00
435.6108704	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	648.2694
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0531769	12.48
193.3722992	0.08
210.9240112	0.07
216.4263916	0.10
219.8610535	0.21
228.0551758	0.11
239.2869568	0.73
257.1863708	1.91
258.0823669	0.24
266.2822266	0.40
273.0579834	0.46
284.1142273	0.93
285.1676941	0.76
291.2168579	0.11
301.0095825	2.56
302.2191162	10.24
302.9964600	0.13
308.3115540	0.11
320.1674194	56.53
329.1596069	9.80
340.2537842	0.18
346.3104248	0.12
351.0977173	0.06
352.0650024	0.11
364.2462158	0.15
373.3509521	0.58
382.0122681	0.08
400.1793213	1.11
409.1147461	0.25
416.9338989	0.06
427.3437500	3.46
430.1323853	0.37
435.7743530	0.13
445.2898560	4.41
455.4258423	0.38
456.0366821	0.25
457.2515869	0.47
457.9829712	2.99
463.2261353	100.00
463.8386230	0.33
468.2774658	0.17
475.3351440	0.26
476.1217041	0.41
482.3728638	0.15
501.0697021	0.42
513.4285278	0.13
514.2304688	0.28
517.7312622	0.38
532.4076538	0.10
541.3173828	0.42
552.6503296	0.10
553.4683838	0.73
555.3919678	0.60
567.5627441	0.11
570.4751587	0.16
571.4066162	0.27
585.1130371	1.39
599.9657593	1.21
602.5436401	0.52
612.0964355	0.53
613.3478394	0.12
628.4334717	0.11
630.2901001	5.58
631.2283325	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1616
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
181.9032898	0.02
189.1152344	0.27
196.9475098	0.49
258.0944519	0.02
265.2247314	0.04
269.2241211	0.44
270.0925293	0.03
273.1454468	0.05
277.1265259	0.02
280.2639160	0.08
282.3026733	0.16
283.5405884	0.03
293.1383667	16.06
294.1361694	3.58
295.1616211	0.12
300.0435486	0.02
300.9270020	0.01
307.3438721	0.18
308.6945801	0.04
309.3826599	0.02
311.1121826	0.79
312.1940308	0.08
320.1959839	0.02
321.0675659	0.07
323.1855469	2.21
324.2609253	0.43
325.0793457	0.09
335.2083740	0.97
336.3666382	0.28
337.2144165	0.26
338.1890259	0.05
339.3894653	0.01
341.1492920	3.25
342.2258911	0.86
344.3458862	0.04
344.9829712	0.06
353.2368164	1.61
354.3331909	0.33
355.1531372	0.20
361.1000366	0.03
362.2852783	0.14
365.0664673	0.01
367.5269775	0.02
369.2279663	0.02
371.1695557	0.24
372.2413940	0.05
379.1877441	0.27
380.2979126	0.06
381.5976562	0.02
383.1472168	0.10
391.3840942	0.01
395.2440796	0.01
397.1843262	100.00
398.1833496	21.19
399.2438965	0.03
401.1145020	0.04
403.9732056	0.01
411.9841309	0.03
413.4333496	0.06
414.3533936	0.18
415.1252441	1.13
416.3317261	0.49
425.2623901	0.02
426.1574707	0.07
429.3135376	0.13
439.1702271	0.04
457.1777344	6.14
458.2974243	1.70
460.4715576	0.03
461.5291748	0.04
463.1416016	0.05
465.4629517	0.03
481.7243042	0.05
482.3814087	0.01
485.4692383	0.04
486.2305298	0.01
487.2943726	0.17
488.2369995	0.07
489.1233521	0.04
499.1416016	0.05
503.3072510	0.04
508.6696777	0.07
515.4766235	0.14
516.3126831	0.10
517.3038330	0.06
526.2498779	0.18
536.5104980	0.01
543.2952881	0.55
544.2942505	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1169.0546
Annotation	Unknow
Peak:m/z	Relative Intensity
363.0404358	0.06
367.2730103	0.06
407.2093506	0.04
425.2900391	0.02
470.5484619	0.06
491.2791443	0.09
494.6469421	0.07
496.4160156	0.07
498.3574829	0.08
531.2270508	0.07
547.2708130	0.06
559.5459595	0.04
568.9320679	0.02
575.3611450	0.04
581.3039551	0.19
591.1402588	0.05
593.5590820	0.03
608.5203857	0.02
626.9260254	0.19
657.2749023	0.07
669.4048462	0.04
695.4194336	0.04
709.2694092	0.12
711.2550659	0.06
724.6665039	0.10
725.5346680	0.04
753.6928711	0.21
754.5462646	0.19
755.5175781	0.12
756.6375122	0.09
793.7333984	0.07
809.3901367	0.05
816.5335083	0.05
830.9821777	0.04
835.4500732	2.82
836.5759277	1.17
839.4733887	0.12
847.2600098	0.23
848.0004883	0.13
853.4315186	0.63
854.5258789	0.34
856.0642090	0.25
861.3521729	0.04
862.1333008	0.06
863.2121582	0.03
864.5305176	0.10
865.3575439	0.20
868.1799316	0.06
871.5688477	0.02
873.0112305	0.04
881.0693359	0.04
882.5992432	0.26
883.5642090	0.07
885.3818359	0.04
887.8812256	0.07
888.5423584	0.20
893.9910889	0.02
895.0579834	0.13
902.9034424	0.87
903.5756836	0.91
904.2645264	0.01
908.2243652	0.04
910.9738770	0.03
923.3585205	0.07
930.6793213	0.05
934.0284424	0.05
939.3294678	0.13
941.7222900	0.04
943.3734131	0.46
943.9776611	0.24
945.9838867	0.14
947.6674805	0.04
951.1516113	0.07
952.2502441	1.48
953.1328125	0.25
957.4035645	0.30
958.0880127	0.16
959.4274902	0.16
961.4473877	0.46
964.3946533	0.55
965.9300537	1.34
967.0004883	0.37
967.7740479	0.19
968.6365967	0.06
974.8470459	1.34
975.6943359	0.28
977.3498535	0.05
981.0147705	0.10
983.3674316	0.05
995.5451660	0.63
996.7056885	0.14
997.9726562	0.03
999.5888672	0.41
1000.9670410	0.10
1001.5844730	0.02
1002.4051510	0.09
1008.3369140	0.50
1009.3940430	0.37
1012.0102540	0.05
1013.8127440	0.09
1015.2098390	0.47
1016.3249510	0.38
1017.2996830	0.50
1018.2377930	0.05
1021.3961180	2.49
1022.1826170	0.32
1024.3366700	4.12
1025.1896970	1.82
1025.8872070	0.25
1030.0555420	13.37
1030.7999270	13.93
1033.3134770	13.08
1034.1851810	1.50
1037.1118160	0.06
1039.0017090	2.83
1039.6214600	2.09
1040.2486570	0.41
1041.4368900	0.03
1048.2788090	0.18
1049.9797360	0.13
1051.4353030	0.07
1055.9765620	0.03
1060.4721680	0.46
1064.1635740	0.48
1065.0609130	0.51
1068.0797120	0.10
1073.2780760	7.96
1074.1312260	1.22
1075.3906250	0.05
1077.6793210	0.08
1081.9533690	20.60
1082.7618410	24.83
1086.0290530	0.31
1086.7495120	0.48
1087.5767820	0.18
1088.9780270	0.03
1091.1174320	0.48
1094.8046880	3.60
1095.6618650	0.68
1096.5195310	0.04
1097.9587400	0.02
1099.4760740	0.16
1103.9610600	0.55
1104.6369630	0.09
1107.3619380	0.03
1108.0012210	0.03
1108.7398680	0.08
1111.3872070	0.53
1112.3585210	0.05
1121.4753420	0.43
1124.4854740	0.61
1125.6550290	0.26
1126.8621830	0.05
1129.4542240	1.49
1130.2243650	0.90
1130.9353030	1.31
1133.2998050	0.54
1134.0093990	0.11
1137.8822020	1.01
1138.6567380	6.85
1139.6174320	5.52
1140.7788090	0.04
1142.3565670	7.64
1143.1611330	2.07
1144.3884280	0.04
1148.3673100	0.20
1151.3311770	100.00
1152.2531740	17.09
1154.1020510	0.03
1160.3220210	2.00
1177.6677250	0.06
1188.5905760	0.06
1195.5384520	0.85
1196.4709470	0.44
1197.3408200	0.19
1206.4757080	0.14
1208.4886470	0.08
1238.4775390	0.03
1239.4704590	0.09
1256.6446530	0.05
1295.1333010	0.05
1306.6676030	0.34
1307.8277590	0.13
1319.4562990	0.13
1320.3747560	0.05
1321.7812500	0.09
1325.6444090	0.11
1337.5859380	0.87
1338.7426760	0.18
1356.6842040	0.02
1423.9464110	0.07
1434.7319340	0.08
1437.2434080	0.17
1438.0010990	0.12
1438.7485350	0.18
1448.7686770	0.67
1449.8809810	0.04
1466.6107180	3.10
1467.7883300	1.84
1468.8443600	0.27
1491.9409180	0.14
1509.6932370	0.10
1548.8187260	0.20
1549.9614260	0.09
1551.4874270	0.03
1565.7225340	0.28
1566.8681640	0.03
1567.8787840	0.09
1577.9088130	0.07
1595.3970950	0.21
1596.0621340	0.03
1596.7313230	0.05
1599.0296630	0.02
1636.7602540	0.06
1677.0191650	0.03
1678.7452390	0.12
1694.7930910	0.10
1695.3983150	0.08
1697.1602780	0.03
1787.1253660	0.10
1794.5909420	0.07
1804.7652590	0.27
1805.8665770	0.05
1808.1140140	0.05
1820.7678220	0.03
1821.8063960	0.37
1822.8028560	0.46
1823.6783450	0.18
1824.8435060	0.04
1876.7342530	0.06
1888.9036870	0.03
1904.1817630	0.02
1914.9816890	0.09
1916.0441890	0.04
1921.8145750	0.06
1922.4700930	0.06
1924.6599120	0.05
1931.6314700	0.08
1932.7437740	0.30
1934.0496830	0.29
1936.6890870	0.04
1938.0277100	0.18
1950.2189940	0.31
1951.3153080	0.06
1956.2662350	0.05
1960.4530030	0.06
1967.9229740	0.11
1970.0328370	0.23
1971.6158450	0.04
1987.2097170	0.24
1993.7401120	0.04
1995.5531010	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	301.2735
Annotation	Octadecene-1,9,18-triol
Peak:m/z	Relative Intensity
143.8751526	8.29
171.0929871	5.99
221.033905	7.40
229.950592	11.79
238.8998718	13.30
257.8574219	6.39
259.1497803	22.01
259.9898682	3.69
265.1923218	20.83
270.2571106	10.35
274.3123779	8.49
283.2557983	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1257
Annotation	Unknow
Peak:m/z	Relative Intensity
153.8879242	0.24
181.0613098	0.88
186.9546967	0.09
223.0025940	0.63
231.1295471	1.60
253.1805725	0.34
262.8724976	0.15
264.9746704	0.40
276.7164917	0.49
288.0054932	0.30
289.2598877	0.13
290.2569580	0.05
294.8508911	0.14
306.1104126	13.58
315.9151001	0.31
317.1088867	2.10
334.0028687	100.00
335.3010864	0.05
345.0258179	0.14
345.9353638	0.39
351.1769409	0.29
360.0870361	0.32
371.0475464	0.10
372.0894775	0.92
379.9852905	0.15
385.8034668	0.09
389.3568726	0.26
391.0269165	0.83
392.2747192	0.50
402.3363647	0.32
405.5120850	0.26
407.1624756	0.19
409.0760498	71.55
437.6411133	0.09
445.1813965	0.38
463.1705322	0.88
467.0187378	0.11
474.1891479	0.31
475.1513672	0.90
494.2168579	0.42
496.1577759	0.28
500.5064697	0.73
501.2084351	0.38
502.8952026	0.28
515.5195923	0.18
520.2583618	13.95
521.6419067	0.20
528.9096069	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	189.1229
Annotation	Leucyl-Glycine
Peak:m/z	Relative Intensity
83.9406738	0.69
111.7319031	0.05
125.8990631	93.53
128.9971924	0.27
130.0639954	0.48
142.9780579	100.00
146.9733429	0.06
170.9904938	0.33
171.8052979	0.03
174.1321411	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1016
Annotation	32142-31-7
Peak:m/z	Relative Intensity
120.8145752	0.38
150.8867493	1.31
169.0503693	100.00
186.6366882	1.25
193.0617981	0.87
194.9205017	0.64
201.208374	1.59
216.2576904	0.31
217.132019	0.64
243.1574402	1.24
245.3720398	0.32
253.028717	5.55
254.9651794	5.33
256.0561218	0.45
264.68573	2.03
271.0066833	1.70
272.6798096	3.98
278.8815613	1.10
283.0302429	0.31
284.5852661	0.48
285.4559631	0.38
287.0018616	2.70
290.6121216	0.34
295.2893066	4.56
298.9423828	0.31
313.0150146	9.42
313.9633484	1.44
324.2292786	1.16
329.872467	3.80
330.7546692	0.70
343.4003601	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1401
Annotation	Vicenin 1
Peak:m/z	Relative Intensity
167.2694550	0.02
185.3893433	0.06
191.0480042	0.09
208.1875000	0.04
221.3377838	0.11
222.0925293	0.05
231.1928253	0.05
233.0276947	0.03
246.0645447	0.02
251.1548920	0.10
263.2755127	0.09
264.1594543	0.02
275.2733154	0.03
281.1754150	0.04
289.0151978	0.10
292.1096802	0.09
294.2874146	0.02
297.5214844	0.03
298.2950439	0.02
301.9738464	0.03
307.0344849	0.23
308.2868652	0.06
311.2592163	0.50
312.2259827	0.10
317.1261597	0.02
323.1818237	0.06
325.1546631	0.34
333.0413208	0.05
335.1609497	0.17
336.4493408	0.07
337.3161621	0.03
338.4059448	0.16
341.1278076	0.04
347.2340088	0.10
349.3661499	0.07
351.0879517	0.11
353.1226807	28.73
354.1598511	6.65
355.1184692	0.07
359.1126709	0.11
360.3583984	0.02
363.2091064	0.06
365.2117920	0.74
366.2593994	0.08
367.4153442	0.05
377.2431641	0.11
377.9535522	0.11
379.2579346	0.33
380.2282715	0.33
381.5435791	0.09
383.1873779	21.02
384.1905518	4.63
384.8040771	0.11
387.4106445	0.04
389.5407715	0.06
391.0919189	0.26
395.1284790	1.46
396.0694580	0.41
397.3419189	0.44
398.1387329	0.11
401.2849731	0.11
402.4518433	0.05
407.0939941	0.57
408.2991943	0.18
409.3219604	0.20
411.5777588	0.05
413.1878662	3.21
414.1677856	1.17
416.2877808	0.09
419.2857666	0.34
420.2086182	0.10
423.5296631	0.03
425.2734375	3.43
426.2158203	0.46
427.3798218	0.18
428.2350464	0.09
430.4948120	0.07
431.3796387	0.23
432.4246216	0.05
437.2875977	0.70
438.1666260	0.27
441.2023315	0.67
443.1984253	100.00
444.2363892	23.18
445.3544922	0.23
449.6586304	0.02
451.3783569	0.05
453.3449097	0.17
455.2089844	5.72
456.2659302	1.16
457.1878052	0.12
458.4230957	0.06
460.4457397	0.13
467.2313232	0.24
468.4448853	0.06
469.3615723	0.03
470.3637085	0.11
471.2933960	0.21
473.2264404	66.92
474.2383423	14.05
475.4270020	0.16
479.3673706	0.10
485.1591187	4.97
486.2291260	0.87
487.3012085	1.95
488.2975464	0.32
492.2127075	0.04
497.1935425	0.19
499.3246460	0.45
500.2489624	0.09
502.1038818	0.04
503.1843872	14.02
504.2288208	4.42
507.2518921	0.06
509.3277588	0.35
515.1843262	1.77
516.1723633	0.58
517.1392212	0.11
518.4267578	0.06
519.1824341	0.09
521.2759399	0.10
527.2213745	2.44
528.2774658	0.59
533.2606201	0.68
534.2306519	0.24
545.1840820	16.38
546.3309937	4.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	838.4239
Annotation	Unknow
Peak:m/z	Relative Intensity
542.4449463	0.08
581.5855103	0.10
669.3731079	0.10
726.3755493	0.11
779.2232666	0.84
780.6715698	0.26
894.8565063	0.27
923.2583618	2.10
979.6943970	0.53
1044.1706540	1.11
1093.7297360	1.67
1116.9604490	1.04
1118.5908200	0.44
1143.3198240	0.77
1521.8106690	0.15
1560.0441890	0.26
1587.3546140	0.10
1641.0684810	0.17
1652.5272220	0.37
1683.6915280	3.77
1716.2242430	0.45
1719.0557860	0.13
1727.7100830	0.07
1756.4265140	0.19
1759.4998780	0.37
1762.7218020	0.64
1767.6579590	0.60
1771.4528810	0.15
1788.0394290	0.21
1809.3894040	0.23
1815.3459470	0.33
1819.7012940	0.07
1829.4051510	0.86
1833.2977290	0.28
1838.2752690	1.95
1850.3771970	0.11
1851.1492920	0.11
1856.1673580	0.12
1858.6511230	0.20
1860.3898930	0.61
1862.8006590	1.86
1867.7545170	12.11
1870.2999270	0.20
1871.4393310	1.84
1872.6954350	0.08
1873.3323970	0.29
1877.5187990	0.67
1879.9313960	0.23
1880.8435060	100.00
1885.0352780	11.53
1886.2308350	1.09
1887.7437740	0.12
1892.4232180	0.21
1897.5628660	0.19
1899.0808110	8.89
1899.7658690	2.15
1900.7486570	0.92
1903.2185060	0.34
1905.0926510	0.62
1907.5925290	0.07
1908.2574460	0.87
1909.8502200	5.23
1910.8659670	13.51
1913.5301510	29.80
1914.9890140	0.45
1916.7867430	0.52
1918.0384520	0.30
1919.6746830	0.11
1920.3480220	0.16
1924.8333740	38.34
1925.6794430	0.42
1927.0202640	0.28
1928.7449950	4.01
1930.9581300	0.20
1932.5665280	2.00
1934.2730710	3.87
1935.8804930	3.76
1937.7419430	2.88
1938.9903560	0.07
1941.2028810	0.15
1943.2629390	1.39
1945.9401860	0.11
1948.0323490	0.47
1948.8767090	5.01
1952.8171390	0.92
1953.8732910	0.17
1954.5041500	0.12
1957.8981930	9.06
1959.0120850	5.91
1960.5465090	10.03
1961.4603270	0.13
1962.2418210	0.08
1962.8809810	0.38
1966.1120610	16.55
1967.8843990	3.02
1969.7520750	8.18
1972.4294430	7.87
1973.3762210	0.70
1975.1444090	1.24
1976.6252440	0.71
1977.8214110	4.84
1978.6497800	0.46
1982.0461430	0.11
1983.8898930	0.39
1984.7962650	0.11
1988.1307370	1.41
1991.1062010	9.21
1992.4422610	2.25
1994.2019040	0.81
1995.3503420	4.51
1996.6594240	0.57
1997.7117920	2.31
1998.7921140	24.60
1999.9964600	39.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.83
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9952240	0.05
191.1121063	0.41
197.1407776	0.16
207.0156708	4.13
222.9945374	8.09
232.0177002	0.39
274.7966919	100.00
290.7235718	17.82
291.3365479	0.08
298.2637329	0.04
312.0949707	0.07
313.0700378	0.19
330.2349854	0.29
339.7309570	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
145.0829468	4.14
151.0670776	13.31
161.0011902	1.84
172.2664795	2.74
174.9161377	5.39
203.9708862	5.03
204.9720154	2.02
207.139389	19.53
207.9394073	1.85
239.9587097	5.82
254.7547607	8.60
257.1694946	4.33
257.8616333	2.03
265.4001465	1.89
267.2156067	2.54
309.142395	4.69
312.281311	1.31
317.1862183	9.19
324.534668	5.65
330.1921997	2.46
332.2940674	6.70
335.2817993	2.46
336.8441162	4.33
339.2324829	3.48
339.9972534	2.97
342.3812866	4.37
346.0325623	2.46
347.188385	2.91
350.2513428	9.38
355.3885803	6.39
357.3254089	9.56
358.742981	3.44
363.4627686	4.41
365.214325	2.37
366.1336975	12.38
367.4129333	1.88
368.036438	2.02
370.1712952	3.21
377.0777283	8.91
380.9081116	2.85
384.7866211	7.44
390.2041931	6.75
391.0431824	5.01
393.5301208	8.11
395.5839539	12.01
398.4042053	5.45
407.3109436	26.66
408.264679	100.00
409.0523071	12.61
425.884613	5.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	538.75
Annotation	Unknow
Peak:m/z	Relative Intensity
241.3675537	0.86
286.9103394	0.96
327.0158691	0.27
370.8347168	11.10
372.1720581	0.32
386.9286499	1.31
401.0427246	0.49
402.8779907	0.29
454.7492676	100.00
470.8129883	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	414.0445
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8172760	0.14
130.8533936	0.14
133.1292114	0.18
137.0873871	0.08
162.7247314	0.20
195.1518860	0.20
226.1421661	0.13
227.0183563	0.17
229.1321716	0.08
231.0752869	0.30
234.1036377	0.15
236.9375916	0.20
238.5702209	0.09
239.2195740	0.38
252.0052795	0.17
253.0808411	0.11
270.8927612	0.26
280.1242065	0.12
288.7629395	0.24
294.1181030	0.91
297.0878296	0.14
300.9454956	0.18
306.0131531	2.08
319.1467285	0.40
323.9967651	100.00
325.0656128	2.55
326.6236572	0.20
329.0789795	0.19
330.1370850	0.14
335.8118286	0.16
343.1481018	0.14
347.6737671	0.06
353.3676147	0.10
360.1169128	0.59
365.9837952	1.61
367.1183472	0.56
369.7869263	0.47
378.0057068	2.53
381.3123474	0.08
395.8723450	14.45
396.5223694	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2876
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
173.0376587	10.85
186.9305878	10.30
188.4119263	8.83
192.957428	6.37
195.3454895	6.80
196.9883575	15.40
197.726532	12.51
219.0343323	24.28
243.2704773	5.98
245.2365112	7.69
339.3180542	7.11
349.0201416	8.01
370.8713989	5.01
385.4187317	8.78
394.1868591	19.20
395.125824	17.60
408.2640076	100.00
409.276062	5.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
99.50222015	0.72
109.0817871	1.01
120.9905014	2.35
132.7792206	0.57
135.0772095	0.85
136.6956177	0.60
143.1282043	0.82
147.0928345	1.76
148.8909912	1.45
157.0922241	2.25
161.1810303	1.62
165.1235046	0.41
167.1892853	0.99
172.8182678	1.63
177.0585938	0.66
179.2018738	0.76
183.1230469	0.65
185.293808	0.41
187.0424194	1.23
189.113678	1.69
197.0111694	0.24
201.0584717	3.03
202.9762268	0.41
205.0868225	2.13
208.0736847	0.80
213.2047729	0.40
215.3314209	1.39
217.059082	1.98
223.2989807	2.36
225.1731873	0.58
226.0133972	1.05
231.2175293	2.28
241.2412109	0.38
245.2300415	3.50
247.230072	6.30
251.5205078	0.27
256.9756165	0.60
259.3204041	2.12
267.0500183	0.41
269.1060181	2.44
277.5683899	0.63
279.3859863	0.38
280.0869446	0.35
283.477356	0.71
287.5540771	0.46
295.3442383	1.31
297.0609131	1.26
298.4182434	0.63
299.7287292	2.39
300.8259277	0.82
305.3538818	4.14
306.2531128	0.33
310.101532	0.71
311.6471558	2.57
317.8171387	0.66
323.2311401	100.00
332.0008545	0.38
341.4247742	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	784.0429
Annotation	Unknow
Peak:m/z	Relative Intensity
259.2450867	0.22
289.7442322	0.27
383.4244385	0.40
426.4253540	0.54
438.8198853	1.03
447.3934937	0.90
476.5949097	0.49
483.2269287	0.17
517.3565674	1.23
518.6964111	0.31
532.3613281	1.44
559.4865112	0.70
568.7780151	1.48
574.4472046	0.22
585.5659180	0.12
616.1904907	1.96
618.5744019	0.27
645.4367065	0.70
647.3359985	0.56
666.1378784	0.58
667.3353882	0.30
673.4302368	0.44
675.1258545	1.37
675.9742432	1.36
724.1842651	0.21
735.3852539	1.23
739.7044067	2.61
744.4838867	1.96
764.3951416	0.33
796.8632812	0.64
804.2138672	1.11
844.5717773	1.13
850.2636108	0.40
861.0009766	0.45
873.5060425	0.72
874.7219849	0.22
875.5256958	0.17
892.6228027	1.30
893.3828125	0.63
908.8661499	0.37
912.8898926	1.17
927.3958130	0.82
942.7434692	0.45
967.5088501	0.43
968.2729492	0.20
968.8939819	1.06
973.0148315	0.52
973.6545410	0.17
988.7185669	1.05
991.2208862	0.26
1002.3762210	1.33
1004.2798460	0.14
1005.4939580	0.39
1024.5622560	0.67
1030.8886720	0.44
1074.5599370	0.32
1079.9345700	1.15
1088.6008300	1.44
1100.8964840	0.11
1101.6230470	0.14
1119.5502930	0.66
1158.6491700	0.78
1192.9931640	0.39
1215.2968750	0.34
1215.9006350	0.33
1219.8337400	0.26
1238.0294190	0.38
1346.7147220	0.49
1464.0245360	0.15
1475.3586430	0.30
1531.0582280	0.22
1661.6959230	0.18
1713.0281980	0.32
1754.9693600	1.58
1772.5906980	0.23
1797.0260010	1.61
1800.8117680	0.15
1814.9681400	0.45
1817.9754640	0.41
1822.2601320	0.14
1848.2189940	1.88
1860.8781740	0.73
1864.9669190	0.18
1866.4698490	8.78
1867.1868900	1.11
1875.8513180	2.12
1879.8526610	23.91
1884.4904790	0.15
1888.0046390	1.09
1892.1658940	1.27
1903.8270260	0.72
1906.7867430	1.22
1913.5333250	1.06
1917.2044680	0.42
1921.1024170	0.31
1927.7443850	0.14
1929.9088130	0.53
1931.7518310	0.27
1941.0367430	0.32
1945.3214110	0.24
1949.4825440	100.00
1957.1203610	0.97
1959.6960450	8.28
1963.7146000	15.73
1969.4239500	24.72
1970.0552980	3.91
1977.2653810	29.70
1979.2845460	7.18
1981.1462400	0.28
1981.9559330	0.69
1984.1193850	0.34
1984.9323730	0.87
1987.9432370	4.04
1989.9720460	0.56
1995.0059810	2.75
1998.6090090	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3309
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0709229	0.06
219.9597168	0.15
227.0843811	0.06
249.3510590	0.04
251.9489441	0.04
263.1775818	0.05
279.2628174	0.30
292.2144775	0.12
299.9872437	0.03
322.4212646	0.05
324.2034912	0.03
334.3102417	0.05
377.4434204	0.07
379.1976929	0.04
391.3168945	0.08
394.0834961	0.04
409.3170166	0.05
415.6164551	0.04
433.3694458	0.04
435.1522217	0.22
465.2947998	0.04
468.4739380	0.04
470.4538574	0.14
481.3665771	0.03
491.2927856	0.10
495.2100220	0.04
502.0540161	0.04
504.3574219	100.00
505.3464966	0.28
510.3547363	0.06
518.3867188	0.16
519.3665771	0.09
519.9869995	0.03
520.6763306	0.08
525.7693481	0.03
528.1456909	0.10
528.9260864	0.04
543.5562744	0.06
545.2410278	0.49
546.3417358	0.15
564.9968262	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1508
Annotation	Odontoside
Peak:m/z	Relative Intensity
143.0366364	0.15
160.9146271	0.37
165.0630493	0.14
167.2736816	0.11
178.9691010	2.75
191.0644836	0.16
221.0214844	0.08
232.9800262	0.14
235.0065613	0.09
258.8707886	0.08
267.3461304	0.26
268.0640259	0.08
279.0455017	0.05
281.1663513	0.25
283.1405029	0.29
290.1653442	0.18
294.9391479	0.24
296.2418518	0.92
297.3374634	0.33
311.1273804	0.39
312.2361755	2.71
315.2179565	0.06
323.2916260	0.06
327.1939697	100.00
327.9581604	0.07
335.0131836	0.15
343.0781555	0.31
344.3297424	0.79
345.2623901	4.75
347.1876526	0.09
349.2045898	0.17
355.2202148	0.19
356.1975403	0.14
357.9807129	0.31
359.0409546	0.11
363.3723755	0.11
371.4266357	0.10
384.4210510	0.10
387.2957764	0.13
392.8999329	0.05
410.3124084	0.06
426.4573059	0.10
427.2666931	0.05
430.4058533	0.17
431.1572876	1.12
446.5731506	0.21
447.2290039	0.06
457.3304138	0.13
460.3660889	0.57
461.3206787	0.80
463.4240417	0.41
466.2384338	0.07
469.0932007	0.08
470.3639221	0.23
471.4662170	0.25
486.9578552	0.22
488.4792786	0.81
489.1938782	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.1150665	0.18
149.3671570	0.02
152.9160767	0.06
189.9087524	0.03
196.0247803	1.33
214.1093445	1.08
223.1654358	0.03
231.2602692	0.05
235.1694336	0.11
238.1650391	0.02
259.4545288	0.03
261.2755127	0.16
269.5054626	0.05
273.5619812	0.02
279.2754822	100.00
285.4539795	0.07
331.3386230	0.03
342.1714478	0.06
348.9639587	0.02
366.2984619	0.02
380.3617249	0.04
391.1444397	0.04
396.0136108	0.02
397.1462708	0.03
400.2733154	0.04
403.4556885	0.02
415.3689270	0.31
422.6673584	0.02
429.5403748	0.13
430.8127136	0.06
431.8741760	0.36
432.8894958	0.11
435.8463440	0.09
440.2494202	0.23
446.2444153	0.05
448.4507446	0.06
456.1244202	0.16
458.2791748	0.05
459.4968872	0.02
462.5429077	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9395
Annotation	Unknow
Peak:m/z	Relative Intensity
115.1724548	0.01
158.9476624	0.38
219.0116425	0.05
228.3040466	0.03
228.9950256	0.26
247.0456543	0.04
270.9355774	0.07
272.9304199	100.00
274.0802002	0.07
313.1184692	0.02
341.0493469	0.02
343.0159912	0.09
358.8823853	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1453
Annotation	Canthoside B
Peak:m/z	Relative Intensity
130.9395905	0.21
139.1129608	0.13
147.4412842	0.08
149.0202179	3.24
160.9588318	0.04
167.1675262	0.02
173.0198822	0.08
179.1276245	0.03
191.1307068	0.40
233.0439301	0.36
267.4215698	0.16
275.3535156	0.06
286.2629395	0.03
291.4536743	0.02
293.1813660	100.00
298.0625610	0.02
299.0409546	0.03
300.2057190	0.04
317.2319336	0.08
319.2847900	0.07
324.9776917	0.05
327.2820435	0.21
333.4113770	0.18
340.9327393	0.08
367.0402222	0.03
373.3201294	0.11
379.3572083	0.05
384.6116028	0.07
387.2514954	0.10
415.3576355	0.08
416.9625854	70.31
417.7338257	0.18
420.2763367	0.04
444.0202332	0.03
445.3707275	0.23
447.3827209	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.14
Annotation	Unknow
Peak:m/z	Relative Intensity
79.9070129	0.38
96.8195877	100.00
113.1105957	0.06
138.9804688	0.10
165.1847839	0.15
167.0534973	0.08
169.1088562	0.07
187.2520905	0.06
193.3451233	0.07
197.1717224	0.22
199.6159668	0.25
209.3001709	0.15
216.1609497	0.06
223.2939148	0.36
235.1727295	0.29
236.1251526	0.07
236.8976135	1.54
237.5226135	0.08
240.8449707	0.10
244.9616699	0.20
253.1888428	0.31
261.1117859	0.06
262.9436646	3.89
264.6121521	0.44
265.2923584	0.56
281.1685486	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	477.2755
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0775604	0.12
143.9291229	0.36
156.0713959	1.69
170.9053650	0.38
222.0689392	0.57
238.6047058	0.14
251.3226624	1.60
253.8538208	0.33
256.1511230	5.88
257.2348022	0.19
266.4734802	0.55
267.3616638	0.57
270.3776550	0.60
283.9252319	10.08
285.1179504	1.20
315.0372009	0.61
323.6555786	1.58
328.3712769	0.84
331.5014648	0.42
339.6607666	0.36
345.0386353	0.15
363.9702148	0.29
371.2529297	0.81
374.2969055	1.77
375.0569153	0.52
379.8406677	2.40
381.2810059	0.24
383.4375000	5.88
384.8677979	0.97
388.3350525	1.70
388.9442749	0.34
397.1344299	1.96
399.1769409	0.25
419.0390015	0.74
420.6612244	7.30
421.4586487	1.06
422.4352722	0.79
428.1475220	0.49
431.5122986	0.30
433.6642151	2.33
434.2888489	0.23
440.0077209	36.08
441.5109558	0.57
443.8189087	0.20
448.9934082	10.53
449.9229431	1.26
453.2078247	2.10
454.1443787	0.11
459.1970215	2.10
460.4102478	2.90
463.3977966	0.25
464.3988953	0.12
465.6688538	1.87
471.4662476	0.60
476.3807678	0.32
480.5484314	0.48
492.4166870	1.35
496.4255066	0.26
497.4474182	0.75
504.0032043	1.04
505.2349548	2.56
506.0422974	1.38
508.2854614	3.56
508.9573669	2.55
509.7452698	0.47
517.5207520	34.91
518.5492554	2.32
526.4428711	1.95
527.3619995	0.41
534.3844604	0.26
549.3755493	1.49
553.3164673	1.46
562.7766724	0.51
565.1596069	5.83
566.0834961	0.35
574.1127930	100.00
575.0480957	7.25
575.8031006	0.74
577.2627563	0.73
581.6488037	1.81
582.4502563	2.33
584.0745850	0.14
590.7402954	4.21
612.5239868	0.55
621.5081787	1.17
629.1011963	2.18
629.7338257	0.63
630.5441284	1.48
637.9031372	12.97
638.7919312	4.35
639.5350952	0.49
647.1449585	19.18
648.1214600	1.57
650.1338501	2.04
652.2734985	0.83
655.3450317	5.03
656.4155273	2.15
657.8192139	0.12
659.2047729	49.00
660.2092285	4.02
661.0737305	0.45
662.3614502	6.17
663.6421509	0.26
666.6267700	0.26
705.3669434	0.39
714.2750854	0.69
750.5925293	0.57
751.8068237	0.71
757.8712158	0.21
766.3963013	0.12
768.4942017	3.32
769.7429199	0.35
773.7958374	0.18
775.6829224	0.57
779.5898438	0.32
791.7101440	1.47
792.6427612	0.53
834.6062622	0.29
878.6593628	5.48
879.8546753	0.44
886.8667603	0.15
897.0014648	0.75
897.6521606	0.33
904.5646973	1.24
920.6677856	0.49
943.0144043	0.53
991.5480957	0.35
992.4091797	1.35
993.6660156	0.42
1009.6748050	0.35
1048.5349120	0.26
1105.7464600	0.60
1119.8918460	0.38
1161.4754640	0.63
1162.7762450	1.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.0908
Annotation	Unknow
Peak:m/z	Relative Intensity
143.7557831	0.16
145.4105377	0.17
146.1014404	0.75
148.2736206	0.32
152.0093689	0.60
153.0459442	1.43
168.8504639	0.09
171.3544159	0.20
178.0770874	0.09
179.0666046	2.96
181.2838440	0.05
184.9711304	0.06
191.2042236	0.10
194.2570190	0.10
195.1404724	0.18
197.0389252	14.06
198.1615601	0.05
201.2368774	0.26
203.2124939	0.23
213.0803528	0.75
215.2574158	0.85
225.2364197	0.13
228.2043152	0.06
229.1409607	0.20
231.0596771	5.57
239.3411865	0.75
240.2497711	1.90
248.0497437	0.29
253.9244995	0.37
261.2685547	0.11
263.0928040	4.68
263.9887390	0.07
265.5039062	0.07
266.1906738	1.94
272.1591797	1.71
275.0307312	0.08
279.3157959	0.22
281.0488892	0.82
282.3063354	0.99
284.1940918	12.60
286.8428345	0.25
288.2792053	0.04
294.0970459	0.53
300.3394165	0.12
302.5033264	0.08
306.1867981	2.00
307.2301025	0.44
308.2300415	0.57
313.1222534	0.11
314.3688965	0.26
316.1002197	2.28
323.2514343	5.19
325.2510376	5.27
326.1757202	2.85
328.0814819	0.06
330.8804016	0.10
332.0153503	2.07
337.0049438	0.05
339.1488647	0.58
340.1535645	0.09
342.3151245	0.61
344.2769775	3.50
345.4521484	0.15
350.2173462	8.49
351.2182922	5.65
357.2001953	23.13
358.4598694	0.07
360.1585083	1.23
367.2641907	2.84
369.2675781	66.79
373.4005737	0.09
374.9724121	0.04
376.1487122	0.96
377.2707520	0.67
378.3533936	0.12
383.2446289	2.04
388.9299927	0.08
389.9709778	0.20
391.1371155	0.41
395.1662598	9.56
401.1694031	25.28
401.7779846	0.15
411.3241882	0.25
413.2050171	78.00
417.2556152	7.63
426.9253235	1.61
435.1516418	100.00
435.7608643	0.34
443.1306458	0.70
444.0652161	0.06
445.2309265	5.46
461.1972351	18.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	594.2526
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0048828	0.13
194.1280975	0.18
341.1273804	0.12
379.1793213	0.07
384.1082764	0.14
410.0161133	0.22
413.2839966	0.10
414.0190430	0.12
415.2821045	0.31
427.0640259	0.10
432.2119141	0.09
433.3025513	0.09
442.1221924	0.09
443.2107544	0.23
451.2498779	0.11
457.0856934	0.12
459.3203125	0.17
461.4702759	0.12
478.3592529	0.45
478.9990234	0.08
480.4494019	0.30
481.4256592	0.24
496.4014282	0.14
498.5315552	0.17
499.6058350	0.09
501.1385498	0.07
505.3121948	0.06
517.6863403	0.10
531.1216431	0.39
533.2027588	0.16
548.6337280	33.24
549.4694214	1.37
551.0416870	0.41
552.7333374	0.24
553.5319214	0.10
563.0585327	0.07
571.3943481	100.00
572.3451538	2.66
575.4338989	0.08
576.6024170	0.49
577.3440552	0.81
585.6498413	0.07
595.5643921	0.17
785.3814087	0.08
804.7811279	0.20
918.0244141	0.06
935.5181274	0.08
946.1825562	0.06
948.8547363	0.10
1097.5695800	0.09
1098.7541500	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	391.2831
Annotation	Di(ethylhexyl) phthalate
Peak:m/z	Relative Intensity
149.0209045	100.00
149.9858093	12.26
167.0646515	17.34
168.1067505	21.36
260.2403564	13.72
261.5994873	10.33
275.1264648	4.77
279.6876526	25.44
305.7344971	6.00
333.1328735	6.17
344.3914185	3.81
349.6270752	6.66
368.765564	6.69
375.1546326	8.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	377.195
Annotation	Jamesoniellide J
Peak:m/z	Relative Intensity
130.9265442	0.23
136.9426422	1.64
162.9719696	10.58
177.1077118	4.50
181.1193542	0.30
190.6575623	0.87
191.3081970	1.35
202.9895630	1.18
217.1905365	7.75
225.1625366	0.62
228.1549377	0.97
234.9924927	1.69
241.2854309	0.33
262.1142578	0.90
279.6855164	0.70
298.8460999	0.28
305.0837097	0.94
309.1843872	3.62
314.2736816	0.40
330.7741089	1.62
341.2407532	100.00
342.0113525	1.25
358.1475220	1.03
359.1238708	17.66
360.1912537	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	438.2397
Annotation	Unknow
Peak:m/z	Relative Intensity
145.0008698	0.02
165.9502258	0.03
167.2024078	0.05
221.3280640	0.07
274.4282227	0.37
275.3110352	1.20
286.0813293	0.16
306.2783813	0.15
308.0032654	0.07
316.2098389	0.24
318.2390747	100.00
318.8407288	0.20
322.4681091	0.02
345.6105652	0.04
353.2772217	0.03
353.9707336	0.04
376.0934448	0.04
382.3244934	0.06
390.4707642	0.04
391.4817810	0.03
392.5162659	0.12
393.3487244	0.03
394.5012207	0.07
401.9462891	0.12
405.4968567	0.06
407.9925842	0.08
417.5197144	0.04
418.3973083	0.03
420.0623169	0.08
420.9415894	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	566.7868
Annotation	Unknow
Peak:m/z	Relative Intensity
164.0765991	0.10
171.0089111	0.06
173.8581848	0.08
177.0020447	0.09
191.7790070	0.17
213.1976013	0.25
219.1591797	0.97
234.9155426	0.14
236.0066833	0.26
246.9922638	0.13
248.1989899	0.12
259.5863037	0.15
264.0420837	0.22
267.4114380	0.13
273.1678467	0.50
279.0996094	0.17
283.3365479	0.25
295.3344727	0.16
297.4754639	0.14
302.4840393	1.76
303.0914917	5.88
303.9910583	0.75
304.7329712	0.22
312.2386475	0.18
313.2185669	0.46
315.4743042	0.12
319.5908203	0.09
321.9157104	0.11
323.2981567	1.33
324.2199707	0.70
326.9980469	0.11
329.2147217	0.07
329.9918823	0.16
330.6047974	0.44
341.6562500	0.12
351.3435059	0.09
360.4987793	0.10
361.4074097	0.48
363.4336548	0.22
364.2871094	0.49
365.1354370	1.29
366.0039062	0.25
367.1710815	0.23
378.2653198	0.26
378.8716431	0.17
379.8800049	0.29
382.1032104	0.09
382.8609009	0.08
383.9185181	0.48
387.0112915	100.00
387.8408203	24.11
388.8876343	2.03
389.7360229	0.87
390.8633423	0.31
391.8502197	0.15
392.6414795	0.72
394.9546509	0.08
398.7897949	0.33
404.0576172	0.09
406.7922974	3.28
407.7738647	2.62
412.4618530	0.56
413.7598877	0.52
418.6455688	0.26
436.1680908	0.98
437.0936890	6.24
437.9232178	0.73
439.2763672	0.83
462.4113770	0.27
464.0476685	0.24
470.3560181	0.27
472.1266479	0.13
473.7487793	0.17
482.1837769	0.54
482.8887939	0.10
484.9999390	0.19
492.8662720	0.09
493.5288696	0.09
494.6615601	0.14
499.3524780	0.66
503.2423096	0.49
504.1339111	0.17
507.8096924	0.16
509.3349609	0.23
511.6181030	0.11
513.2416992	0.16
517.8203125	1.05
520.4667969	0.27
523.4039917	0.15
525.0316772	0.11
529.9822998	0.07
531.0153198	0.29
533.2936401	0.24
535.2634888	0.06
536.1705933	0.17
546.6276245	0.37
548.6298218	2.65
549.5753174	3.33
550.3082275	0.37
551.1644897	0.43
557.4338989	0.51
567.4910278	0.73
602.6961060	0.29
603.5525513	0.91
604.9959717	38.67
606.1801147	11.25
607.2426147	2.73
772.3360596	0.16
773.5015259	1.06
811.5632935	0.19
866.4093628	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.1453
Annotation	Puerarin xyloside
Peak:m/z	Relative Intensity
160.9803925	0.07
175.0307617	0.08
179.0858917	0.08
190.9814148	0.05
192.2502899	0.03
218.9703827	0.03
221.3121948	0.06
233.1618347	0.12
242.1408844	0.02
263.4454956	0.03
264.2757568	0.03
281.2207031	0.05
285.2145386	0.05
289.3607788	0.04
296.1156006	0.02
297.3164062	0.08
302.1893921	0.03
307.2094727	0.05
311.3280029	0.30
312.2591553	0.04
321.1272583	0.02
321.7984619	0.06
323.0220337	0.14
324.0139160	0.13
325.0328979	0.15
326.2286377	0.04
333.2067261	0.12
335.1790771	0.26
341.3328247	0.17
343.1815796	0.30
344.1425171	0.07
345.1743774	0.06
349.5574951	0.18
350.8588257	0.05
351.4592285	0.09
353.1735229	20.43
354.2376709	3.60
355.4041138	0.03
363.5912476	0.05
365.2036743	1.21
366.1978760	0.33
367.4179077	0.04
373.3132324	0.06
375.0959473	0.02
376.5228882	0.02
377.3040161	0.23
379.2446289	0.35
380.3474121	0.03
381.2479248	0.15
383.2241211	26.78
384.2793579	5.49
385.2385864	0.04
386.3120728	0.04
389.3054810	0.05
391.2069092	0.03
395.2384033	1.48
396.1037598	0.62
397.2366943	0.40
401.2054443	0.16
402.1004028	0.02
407.1828003	0.31
408.1016235	0.09
409.1813354	0.37
411.2761841	0.09
413.2391968	6.94
414.2434082	1.91
415.4738770	0.30
417.4764404	0.06
421.3284912	0.14
423.3100586	0.08
425.2612915	4.69
426.2993164	1.22
427.1840820	0.23
429.1069946	0.09
431.1998901	0.02
433.0414429	0.05
437.3226929	0.52
438.6395874	0.48
439.3519287	2.82
440.3041992	0.68
441.1364746	0.32
443.2189941	41.65
444.2229614	9.57
445.1406250	0.35
451.3178101	0.35
451.9279175	0.05
455.2777100	4.51
457.2155151	100.00
458.2030029	19.71
459.0167236	0.35
460.3658447	0.09
465.3616943	0.03
467.3992310	0.17
469.2035522	7.96
470.2895508	2.98
471.4246216	0.09
473.2261353	28.03
474.2393188	5.86
475.4632568	0.05
476.1397095	0.02
483.2462158	0.64
484.0062256	0.22
485.2898560	1.85
487.2164917	66.85
488.2339478	17.48
489.1226196	0.27
493.3245239	0.05
494.1404419	0.10
499.2138062	1.90
500.3176270	0.35
501.3419800	0.49
502.1634521	0.03
503.3300781	3.11
504.3624878	0.83
505.3930664	0.08
510.7241821	0.68
511.3377686	3.03
512.3080444	1.27
517.1920166	3.26
518.1979370	0.99
524.3303833	0.06
529.2211304	29.77
530.2309570	8.53
531.1856079	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.2
Annotation	Pteroside A
Peak:m/z	Relative Intensity
133.0612335	2.90
224.0932465	2.29
258.9393005	6.38
295.1696167	2.49
301.2258911	4.53
317.0976562	3.31
351.2164307	9.16
374.6015015	1.68
393.1989441	100.00
393.8959656	8.16
424.9599915	4.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2499
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.4161682	0.13
106.9202881	0.34
109.0972748	0.81
121.0410461	1.16
123.1284409	0.90
129.105545	0.09
130.8207092	0.61
132.8654175	0.33
135.0726929	1.40
137.036911	0.26
141.2464294	0.19
143.1604614	0.43
145.1152954	0.08
147.0022278	1.73
149.0562744	0.96
151.2330627	0.04
157.0768433	0.88
159.0838318	0.65
161.0275726	0.98
163.2376404	0.44
165.0967407	0.30
169.0628052	0.63
171.0087891	0.22
173.1454468	0.32
175.1748352	1.53
176.978241	0.07
179.1394043	0.24
183.205719	0.12
185.1300507	0.07
187.0530548	0.96
189.0783691	0.55
191.0646973	0.36
193.0250244	0.07
195.2097015	0.27
197.2132874	0.30
201.146347	0.26
203.152771	1.24
205.1064911	0.51
206.7285614	0.11
207.3434448	0.26
211.1153564	1.36
213.1325378	0.31
215.0021057	0.22
217.1560364	1.58
219.2954407	0.47
223.2006226	0.74
225.3537903	0.10
227.0688782	0.92
229.2662354	0.85
231.214386	0.79
235.1604614	0.45
238.8295288	0.05
239.546936	0.23
241.2949219	0.29
242.0345764	0.11
243.0234985	0.05
245.0807495	0.76
247.1768188	6.28
248.4212952	0.13
255.2427368	0.13
256.3884888	0.10
257.4363708	0.53
259.425293	0.17
263.2593384	0.09
265.2836609	0.25
267.2563782	0.33
269.4533081	0.23
271.1616821	0.25
273.1048584	0.05
277.132843	0.30
278.3247375	0.09
279.459259	0.18
281.237915	0.13
283.5715027	0.15
285.1747742	0.35
288.3294067	0.08
295.2148438	1.02
296.2705078	0.06
297.2805176	0.20
299.2698975	2.20
299.9727173	0.26
303.4432983	0.08
305.2034302	3.06
312.3428955	0.43
313.190918	0.42
323.2426758	100.00
323.9940186	0.65
341.2652893	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.02
Annotation	Unknow
Peak:m/z	Relative Intensity
183.1427155	0.04
219.2626343	0.01
221.0235748	0.14
223.8775177	100.00
237.2030182	0.06
241.7668610	17.18
243.6834869	0.05
247.0191803	0.01
264.8609009	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1091
Annotation	Nifedipine
Peak:m/z	Relative Intensity
104.1549225	0.04
124.1128540	0.14
131.9860535	3.44
133.0825195	0.76
133.8426666	0.07
150.0507507	0.30
155.0919495	0.19
163.2598877	0.10
176.0714722	0.12
177.0526276	1.91
178.0266113	0.19
189.1733093	0.05
199.5441132	0.11
201.1365051	0.06
207.0089417	0.09
211.0814819	0.17
213.2557678	0.04
214.2450867	0.10
215.1341858	1.49
237.2159424	0.04
239.1892700	0.09
240.1674805	0.26
241.1913757	0.44
247.1938477	0.11
253.1624756	0.03
255.3302307	0.24
257.1654663	56.67
259.0485840	0.08
265.2267456	0.19
267.1742249	0.05
271.0501099	0.05
273.0719604	0.37
281.4685059	0.05
283.1541748	22.26
285.1469116	0.36
287.5763550	0.12
290.4284058	0.04
299.1227112	0.25
301.1411438	100.00
302.0628052	0.22
305.2178345	0.06
309.1035461	0.39
310.0847473	0.20
311.2479248	0.11
327.1140747	10.00
328.3066711	0.09
330.2483521	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.925
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9864349	0.36
258.8989258	0.10
272.9149170	0.27
274.1119080	0.14
313.9890747	0.22
359.1188965	0.41
383.0922852	0.03
398.9543152	0.05
426.9933777	100.00
428.8670654	3.62
430.1437683	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1087
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
126.9074097	0.20
140.7140961	0.08
148.9248657	0.15
152.0145264	0.05
153.3662109	0.04
158.8797760	0.04
163.1158142	0.13
165.1870728	0.24
177.0724792	0.09
179.0859985	0.45
190.8507385	0.18
198.9811859	0.22
203.1945801	0.08
207.2914734	0.08
215.2250366	0.13
217.1859741	0.30
225.2771912	0.24
227.2518616	0.06
237.0815582	0.15
239.1823730	0.09
241.4802551	0.05
243.0946655	1.33
251.2163086	0.18
253.1346436	0.85
259.0998535	37.01
261.0454407	0.10
263.1468811	0.56
267.4025879	0.71
269.0927429	100.00
279.1896973	0.15
281.2423706	0.07
283.2089233	0.72
287.1647949	33.16
288.9517212	0.07
290.2008972	0.14
293.2827759	0.11
297.1657715	0.05
311.0962830	3.45
313.1908569	0.63
315.1753540	0.07
323.0692749	0.15
325.1224670	0.40
329.1885376	0.27
341.1465149	0.11
342.1386414	1.41
342.9439697	0.05
344.0848389	0.20
351.3205261	0.30
353.1542358	0.13
355.0615845	0.74
361.5670166	0.12
365.2894287	0.07
367.3831482	0.05
369.1795654	0.08
371.2504883	0.40
373.0714722	1.95
374.2541809	0.12
375.1270752	0.09
377.4717407	0.10
385.1322327	0.10
387.3822327	0.13
389.2992249	0.19
392.0247192	0.34
402.5479126	0.41
403.3498230	10.50
404.2913513	0.05
406.1792297	0.05
411.2615051	0.16
413.0420837	0.05
421.2594299	6.39
429.9567566	0.14
431.2364807	15.96
444.8299255	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2256
Annotation	Lactulose
Peak:m/z	Relative Intensity
323.4381409	0.52
339.4017639	0.13
341.2000732	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.2071
Annotation	2,3-Dihydroxycyclopentaneundecanoic acid
Peak:m/z	Relative Intensity
97.03405762	0.17
110.83992	0.12
112.8065186	0.20
135.1026611	0.28
152.8716278	0.23
168.9568176	1.15
171.2900391	0.85
183.2141418	0.81
191.2228394	0.16
195.3449707	0.17
197.3890381	0.15
200.9336243	0.23
205.2301025	0.17
211.3449402	0.57
213.0184326	0.15
214.3101807	0.13
217.1044006	0.38
221.5215759	0.15
223.2733459	31.57
225.2062378	0.61
227.15448	0.26
239.1066284	2.43
240.6157227	0.81
241.2842407	3.10
243.3351746	0.19
247.89505	0.22
249.1420288	1.10
249.991394	0.81
255.309082	0.34
265.0493774	1.12
267.1871948	100.00
268.0486145	2.14
269.1275024	3.50
270.1095581	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	436.2239
Annotation	Lunarine
Peak:m/z	Relative Intensity
145.0789185	0.17
145.9736938	0.03
153.0571442	0.01
239.1280518	0.01
246.9754944	0.00
257.2460938	0.03
271.1335449	0.01
272.3504639	0.22
273.3684998	0.39
274.2989502	0.05
290.0766602	0.07
301.4732361	0.01
311.9344482	0.00
316.2338867	100.00
317.1968079	27.87
317.8852234	0.05
337.0743103	0.01
346.3496704	0.03
355.3133545	0.01
377.4169922	0.02
394.2124939	0.13
400.3681335	0.01
419.3324280	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.9
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0962982	0.01
159.0487823	0.50
159.7943573	0.01
173.0771484	0.01
175.0314484	0.44
175.8578491	0.05
199.0441895	0.14
200.1858826	0.02
215.0945282	0.04
216.2082214	0.03
217.1843567	0.01
228.9975281	0.05
229.6799316	0.02
233.2295990	0.01
245.1009216	0.09
247.1400452	0.01
273.0034180	6.63
274.0955811	1.70
289.0477295	9.17
290.0633545	1.55
363.2470703	0.02
387.0371704	0.66
388.0775757	0.22
388.7202148	0.01
401.2677002	0.02
402.9426270	100.00
403.9052734	24.62
427.0355225	0.02
433.0603027	0.01
434.0259399	0.02
443.0804443	0.09
444.8191528	0.03
461.2686157	0.03
461.9034424	0.01
470.9859619	0.67
472.0620728	0.02
473.9032593	0.04
477.2074585	0.01
498.9498901	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
107.8238678	0.78
113.030426	0.60
122.9073029	2.13
152.0831604	3.12
165.7526398	1.38
167.0250549	100.00
181.0284576	3.06
183.0922394	0.36
203.0585785	0.34
203.7443848	1.04
209.0552979	8.95
213.3846741	0.44
215.0143127	1.08
231.1156006	0.55
233.115387	0.84
234.9581299	0.44
236.9208679	0.73
238.9458923	0.49
257.9491882	0.53
261.1374207	1.57
267.0272522	0.27
269.1149292	1.72
271.1139526	0.78
281.1972046	0.25
283.050293	1.65
284.8893433	1.12
293.2278442	5.11
308.8624878	1.35
311.1951904	2.61
314.1009521	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
94.9848328	0.05
96.9800873	0.11
99.0044784	0.31
100.9843903	0.31
108.9888458	0.05
110.8513794	0.30
112.8921204	0.94
114.9736328	1.06
118.6775360	0.03
120.7910538	0.02
122.9275513	0.02
125.0193634	0.06
126.9969254	0.65
129.0333405	0.45
130.9633942	0.52
136.7404175	0.02
138.9175720	0.43
141.0737152	0.33
143.0484009	0.10
145.1203918	0.05
146.8395386	0.04
149.0810547	4.70
152.9679565	0.13
155.0753326	0.14
156.9087219	2.16
159.1151276	0.03
160.9894714	0.11
162.8449402	0.10
165.1709595	0.02
167.1411438	0.07
168.0181274	0.02
169.0290222	0.95
174.0162964	1.32
175.0691833	2.41
181.0482483	0.07
185.1600494	0.03
186.9394531	0.18
200.8080750	0.02
202.0684814	0.08
203.2119446	0.03
205.1153259	0.18
207.3251801	0.12
214.8887634	0.07
217.2345276	0.18
219.1127625	0.10
229.0087891	0.18
233.2132874	0.11
236.0174866	0.20
237.4633179	0.03
246.1865540	1.10
247.0627136	3.20
248.2214355	0.02
259.0531921	0.13
260.9684143	0.03
261.7213745	0.06
265.8814087	0.02
277.0877075	100.00
277.9501038	0.04
289.0440369	0.03
291.2486267	0.09
293.1138000	0.18
301.0929871	0.27
306.2586975	0.02
307.2929688	0.30
318.2073669	0.12
319.1976929	0.74
320.5013733	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.1445
Annotation	Dodecanedioic acid
Peak:m/z	Relative Intensity
85.09030151	0.16
129.3064423	0.16
130.1889801	0.10
132.89151	0.13
141.3542023	0.13
156.6632996	0.11
158.9460144	0.19
167.1716309	36.10
169.1450195	0.12
171.1918182	0.15
173.9468994	0.44
180.9958038	0.15
182.6415558	0.12
183.2460785	1.11
185.0673828	2.21
187.0531769	0.28
193.013443	0.09
194.894455	0.14
201.1983185	0.33
209.2593231	0.63
211.1398773	100.00
211.7953644	0.15
213.0405731	2.04
214.3167267	0.30
229.2918243	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.3693
Annotation	Unknow
Peak:m/z	Relative Intensity
311.5531616	0.05
467.3041992	0.03
635.4633179	0.03
653.4423218	17.55
654.5270386	3.17
695.4191895	2.90
696.4746704	0.58
697.0747070	0.02
735.3661499	0.68
736.4486694	0.26
746.7427368	0.07
755.2929077	1.60
756.3471680	0.05
766.7246094	0.12
768.8737183	0.05
786.0874023	0.04
797.3049316	100.00
798.3770142	20.90
803.4315796	0.16
823.2628174	0.26
823.9935913	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	937.87
Annotation	Unknow
Peak:m/z	Relative Intensity
696.6215820	1.94
865.4154053	5.82
886.2022095	1.09
913.9738159	3.85
915.2207642	1.69
1025.5321040	3.57
1114.4448240	18.73
1115.7524410	4.60
1116.9132080	0.88
1153.2160640	0.78
1708.1618650	11.41
1741.3302000	0.46
1806.4146730	11.29
1861.8874510	62.64
1877.6888430	0.61
1879.1765140	1.04
1880.2764890	0.66
1886.2349850	0.89
1896.0709230	0.56
1900.5609130	0.90
1902.0513920	1.50
1906.5075680	0.85
1914.6258540	5.89
1918.7432860	2.17
1934.6387940	2.92
1936.7390140	8.61
1943.4730220	0.61
1945.2541500	100.00
1960.5422360	0.74
1972.7254640	0.46
1978.9973140	11.34
1981.3211670	4.60
1982.5020750	56.65
1986.5933840	0.66
1993.4776610	3.73
1994.5573730	83.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1398
Annotation	5,4'-Dihydroxybibenzyl 2-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
122.9653244	0.64
138.8511963	0.47
141.0778503	0.14
149.1962433	0.20
153.0989227	0.53
168.7866821	0.17
170.8795776	0.44
179.1348572	0.17
204.9715271	0.29
210.2466736	0.52
217.0280762	0.44
219.3116455	0.35
223.0222321	0.18
229.0823975	100.00
243.9295959	0.24
251.898468	0.79
253.3553772	0.91
258.89151	0.32
271.6166992	0.17
275.2981873	0.13
278.9291382	0.28
287.418335	0.35
288.7278442	1.53
293.4328003	1.16
294.2313232	0.23
295.2593384	0.15
299.2245178	0.40
301.4189453	0.26
303.4356079	0.24
307.035675	0.18
308.1708069	0.24
315.1322937	0.67
327.3173218	0.41
328.3952637	0.63
329.2366638	0.79
331.4511719	1.43
333.5415039	0.28
337.1449585	0.27
339.0578613	0.17
343.3685303	0.81
344.9757385	3.24
346.2803345	0.37
347.2975464	1.72
348.2713013	0.30
348.9169617	0.42
353.4663086	0.93
354.5088196	0.92
355.6045227	1.05
356.2506409	0.73
358.3792419	0.21
360.3479919	0.61
363.0415344	1.78
363.7556458	0.20
371.5194397	0.51
373.2434387	15.64
376.0753479	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9715
Annotation	Unknow
Peak:m/z	Relative Intensity
117.3632278	0.02
137.1775818	0.04
142.8968658	0.04
153.7070007	0.04
155.4334106	0.03
161.3412476	0.07
179.1965027	0.04
201.9603882	0.07
206.1978455	0.05
216.9359741	0.04
230.0674286	0.02
232.1396179	0.04
233.1064758	0.03
237.1299286	0.03
240.9888611	0.02
243.8672485	0.02
245.0711975	0.08
245.9961853	0.02
247.9887390	0.02
259.2571106	0.10
271.1171875	0.01
275.3596497	0.04
277.8887024	0.02
283.9655151	0.03
290.9965515	0.07
303.3185730	0.11
304.0225220	0.13
304.8673096	0.08
307.9858704	0.34
309.1565552	0.10
310.1591797	0.02
313.4837036	0.07
316.0364990	0.02
321.9957275	0.05
327.0919189	0.01
329.6384583	0.07
331.0523376	0.12
331.9324951	0.12
332.8673706	0.04
333.9483032	0.10
334.8713379	0.02
342.2017822	0.01
343.9983826	0.03
345.2677612	0.08
347.1475220	0.19
347.9424438	0.91
349.0241699	0.02
351.7195435	0.03
353.3444214	0.74
358.0821228	0.05
361.4245300	0.02
362.6002197	0.02
375.2165222	0.16
376.0486450	0.32
378.4252014	0.06
383.9549866	0.02
388.0422668	0.03
391.1191406	0.02
391.7791138	0.04
393.9827576	100.00
394.6103516	0.24
401.0212402	0.22
402.0221252	0.08
407.8235168	0.04
419.0160217	4.22
420.0634155	1.59
421.0925598	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.2134
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
148.9612122	0.05
153.2912598	0.03
164.8263245	0.06
166.9298401	0.05
241.4057312	0.12
261.0739746	0.04
263.1591187	0.06
285.2801208	0.05
287.1845703	0.10
293.2395630	0.05
295.0610962	0.03
299.4906006	0.03
303.2422791	0.47
304.2586365	0.89
305.3488159	0.29
306.1290588	0.05
309.5797729	0.05
313.2473145	0.10
322.1873779	0.20
323.0234985	0.06
343.3525391	0.03
345.3541565	0.11
346.6955566	0.06
351.1484070	0.03
363.3867798	0.03
364.2792358	0.12
365.2793884	0.15
367.6170349	0.13
371.3265381	0.14
373.1945496	0.03
375.7223511	0.04
379.0100403	0.03
383.4559021	0.11
393.6078186	0.06
397.3313904	0.10
404.7830811	0.08
408.3904114	0.07
409.1036682	0.06
421.2120056	100.00
423.2828064	0.14
429.2921143	0.13
430.3922424	0.06
431.3634949	0.06
432.2062988	0.10
434.2649536	0.08
447.2035828	0.06
448.0757446	0.09
449.1297913	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
117.2106705	0.51
156.6881714	0.36
159.1094971	0.51
167.1187134	1.08
170.7691345	0.59
176.9025726	1.58
184.2780609	0.36
185.1219177	0.59
186.9349365	0.55
193.2316895	0.59
198.956131	3.19
201.1001434	3.05
211.0886536	2.19
213.3765564	0.47
215.1295166	2.29
217.1269531	0.36
218.3583069	1.09
219.0626831	0.97
227.2286682	2.55
229.3021851	5.58
229.9382019	0.54
231.178894	0.82
237.0818787	1.35
239.0595398	0.45
243.2264709	0.44
251.1911316	0.70
255.1261902	4.90
257.5289612	1.01
259.2182922	0.43
267.0650635	1.41
271.4012756	2.94
272.1303101	1.38
272.9433899	0.78
281.0596008	1.42
283.2380676	6.00
285.0906372	4.04
287.3144836	0.59
293.2526245	2.82
294.8576965	2.57
295.5856934	0.55
297.2817383	5.58
299.1994324	3.24
311.2036133	3.29
313.2378235	2.80
314.4558716	1.50
315.2911377	1.87
321.3582458	2.88
322.2297058	0.63
323.170105	14.00
325.4667053	0.96
326.4060974	0.21
327.4906006	1.09
329.245697	2.32
339.2557068	100.00
340.0570068	3.56
341.4837952	9.72
342.1578674	0.74
357.4016113	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.015
Annotation	Myricatin
Peak:m/z	Relative Intensity
188.0302734	0.03
209.1854095	0.04
215.1089630	0.07
227.0857697	0.04
229.0362549	0.22
230.1164246	0.03
231.0508575	0.06
237.1085510	0.41
254.1721039	0.07
257.2555847	0.04
258.0252075	0.09
270.9740906	0.16
275.1434326	0.02
281.0616455	0.35
283.1144409	0.26
297.0542297	0.13
298.6405029	0.03
302.1083984	0.04
310.3040771	0.11
315.0607910	4.43
325.1405029	0.07
327.1182251	3.33
333.0103760	0.45
341.0864258	0.94
342.2263184	0.16
343.0296631	0.04
349.1038208	0.14
351.2123413	0.10
357.2293701	0.98
359.0017090	100.00
360.0458374	2.03
360.7512207	1.02
372.8684692	0.04
401.2091675	0.06
401.8247681	0.10
416.6929321	0.35
435.8690796	0.11
447.0079346	0.18
461.2744141	0.06
462.5596313	0.10
488.5349121	0.02
504.3137817	0.24
506.9655151	6.65
513.2257690	0.10
514.9135132	0.04
533.1149292	2.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1788
Annotation	Unknow
Peak:m/z	Relative Intensity
112.7342377	0.15
139.8687439	0.43
145.0802002	15.51
156.9427185	0.32
158.9786377	0.40
196.0723267	0.53
201.0448456	0.10
210.0486145	0.27
213.0672913	2.85
214.1618958	0.12
223.2192383	1.01
231.2097473	0.20
240.1639404	5.39
258.2610168	0.33
263.2187500	0.88
267.0129395	0.57
275.3016052	0.11
277.2762451	0.09
279.1287537	1.82
280.0700073	0.45
294.3372803	2.13
295.5665283	0.90
296.2748413	7.52
297.2041016	0.91
313.3238525	100.00
314.3648987	4.33
315.1199341	0.45
331.0442200	19.53
331.9042053	1.80
332.5311279	0.13
339.1369324	0.48
341.0351562	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.179
Annotation	W123
Peak:m/z	Relative Intensity
140.9220581	0.05
209.1077576	0.09
225.3343201	0.03
233.1592102	100.00
243.2211304	0.02
260.2619019	0.02
261.1598511	0.06
269.3414307	0.02
275.1321716	0.02
277.2776489	0.03
286.3626099	0.15
287.2044983	0.60
305.9501038	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	385.2016
Annotation	2alpha-Anisoyloxy-9-oxoisoanhydrooplopanone
Peak:m/z	Relative Intensity
144.7527618	0.83
147.2097321	0.67
166.9379272	0.27
239.2531738	0.64
263.1600342	3.99
264.7226562	0.66
267.2348022	0.37
313.1931763	100.00
314.9588928	0.17
322.5963135	0.25
325.2880249	0.27
326.2973022	0.17
329.1228027	0.54
338.3031311	0.33
344.2562866	0.25
367.1208191	0.77
385.0343018	0.74
386.2380676	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	210.0604
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
119.7860718	0.97
120.9562836	0.11
130.1674957	0.03
146.0988007	0.11
147.0650177	0.28
163.7072449	0.07
166.1540680	0.08
172.5427704	0.21
174.8701630	4.97
175.5124817	0.02
177.3086548	0.03
192.7726593	100.00
193.4407806	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
178.9009399	0.06
341.2307739	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	612.6931
Annotation	Unknow
Peak:m/z	Relative Intensity
183.1231689	0.06
232.7361145	0.19
260.7446289	0.13
262.8968506	0.16
277.0789795	0.07
280.8543396	0.12
299.2993164	0.03
340.2222290	0.09
355.1192627	0.15
360.9334106	0.28
381.0169678	0.06
390.9307251	0.55
401.1755371	0.26
418.9277344	1.41
434.9176025	1.07
436.8633423	4.77
438.6848145	3.60
439.9332886	0.06
444.7930298	8.83
450.8666992	0.18
452.9644165	1.29
454.8104248	0.76
455.9895020	0.14
456.7462769	0.23
457.9241943	0.03
460.7011108	0.54
469.0882568	0.06
474.9508057	0.07
476.0223389	0.38
476.8031616	0.09
486.9823608	0.05
492.1569214	0.37
500.9238892	0.20
512.9960327	0.18
525.6770020	0.14
526.5763550	0.98
528.7744751	100.00
544.6405640	1.33
565.7739868	0.14
593.6947632	0.06
613.6868286	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
141.0017548	0.43
152.9817505	0.47
154.8608398	0.39
173.0007935	0.85
181.410614	0.48
189.0419159	0.29
199.0531311	0.31
201.2397614	0.73
203.1294403	1.01
205.4317169	0.36
215.0054321	0.30
216.931488	1.66
222.8533783	0.16
225.1625519	0.21
229.2311249	0.52
233.3273468	0.64
238.1801605	0.45
241.3413849	0.11
243.1364288	100.00
243.9541473	0.69
245.1154327	3.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
139.9549255	0.11
152.9521179	0.11
168.7931519	0.01
196.0853119	2.07
212.3536682	0.02
214.0809021	1.35
221.2068481	0.04
222.1703491	0.03
232.0795898	0.05
238.0595856	0.01
255.2339783	100.00
255.8528442	0.34
256.7889099	0.04
265.2415161	0.03
275.4291687	0.01
283.3938599	0.02
284.827179	0.02
345.2628479	0.02
345.9983521	0.01
362.9088745	0.04
364.6824951	0.01
368.3627014	0.02
372.7063904	0.05
373.3407898	0.02
391.3039551	0.54
402.3580627	0.01
403.4558105	0.01
405.4884949	0.01
406.2165833	0.02
407.4634705	0.06
408.5090637	0.02
409.3177795	0.02
411.5233459	0.02
415.3166809	0.06
416.2197266	0.04
417.198822	0.01
433.8423767	0.15
435.0247498	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	410.2198
Annotation	Unknow
Peak:m/z	Relative Intensity
142.1864166	0.07
150.9252625	0.08
169.0283661	0.13
199.0415955	0.04
211.2207489	0.10
213.8245087	0.14
227.0116730	0.12
242.1900330	0.14
272.3811646	0.07
282.2691956	0.11
297.1259155	0.08
321.9258118	0.05
335.2734375	0.15
337.4249268	0.32
343.2691956	0.07
354.2585449	0.07
361.1354370	0.12
364.4266052	0.04
365.1541443	0.12
373.6932678	0.11
375.0325623	0.56
379.1681824	0.28
381.7663269	0.20
389.2951355	0.40
391.3196106	0.77
393.1252747	100.00
393.7590027	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.18
Annotation	2'-Hydroxyzearalanol
Peak:m/z	Relative Intensity
97.14102173	0.83
108.8739395	0.68
111.029686	14.70
119.0721741	3.48
121.1878815	0.98
123.1384583	1.06
125.0126953	0.75
127.1593323	2.34
132.904007	1.59
142.6887512	1.57
146.95578	1.21
159.3977051	1.00
161.7412415	0.75
166.318634	10.93
166.9460754	19.92
172.9233704	1.89
187.1976929	1.71
198.1925507	1.06
203.2637329	5.52
208.863678	1.41
211.1326294	1.81
213.0141907	2.40
223.163147	2.71
227.1165161	0.75
229.4547424	3.00
233.2085876	2.41
239.3103027	2.69
244.035553	1.18
245.5308533	2.77
249.2363892	1.13
251.2996216	2.18
257.1943054	1.11
267.3024292	3.56
269.2782288	1.71
273.0383606	2.39
275.0059204	1.59
278.979187	10.16
281.2641907	10.03
283.2254639	3.63
285.3323364	0.98
292.3993835	1.57
293.0695496	4.44
295.3730469	2.82
298.115509	0.83
303.239563	3.39
305.0889893	1.36
307.0437622	2.92
315.8840027	4.05
320.5461731	27.27
321.1724243	100.00
322.2385864	4.62
338.341156	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.03
Annotation	Unknow
Peak:m/z	Relative Intensity
88.8055573	0.50
107.1794662	0.18
108.7774353	0.09
134.8144531	0.21
139.0852356	0.20
163.2070312	0.46
219.0891418	0.09
237.0317993	0.31
238.6228638	0.31
242.0125122	100.00
247.1893921	0.39
255.1783752	0.53
259.7704163	22.51
261.4366150	0.26
265.2245178	1.77
282.8249207	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
109.0624313	0.26
110.9595947	0.21
120.9673767	0.82
131.1195221	0.36
132.9115601	0.22
135.052597	4.08
136.8905182	0.35
142.5236206	1.22
143.1587677	0.95
144.9917908	0.42
147.1664886	1.79
149.0025024	1.24
155.255249	0.56
156.9492188	0.36
158.8728027	0.47
161.1167908	1.00
163.1061401	1.22
165.4022522	0.24
167.1378174	0.56
168.9790649	0.24
173.0667267	0.29
175.0558167	0.74
176.815506	0.50
177.4231262	0.26
183.1896057	1.70
185.2037048	0.29
186.9769897	0.85
189.2277222	0.34
191.1835938	0.43
193.2217712	1.25
196.7453766	0.35
198.0479736	0.18
199.0260315	0.23
200.9813232	1.63
203.0064697	0.85
204.8481903	1.50
209.0865173	0.64
210.5768738	0.86
211.2397156	0.37
217.1768188	1.01
223.1864929	1.12
225.512146	0.12
234.9996338	0.68
237.1990662	0.64
241.2279053	1.00
243.0495911	0.32
245.0820923	0.77
247.248291	6.61
252.2704773	0.30
254.3674316	0.27
255.4369812	0.82
259.3182983	0.98
265.3894653	0.29
268.1980591	0.46
269.746521	0.20
271.0059814	1.35
278.9657288	0.19
283.1040649	0.20
295.3461304	0.20
297.2439575	1.36
298.2752075	0.41
299.0748901	3.47
299.7646484	0.22
305.1572876	1.67
311.0806274	0.38
312.5695496	0.95
313.3817139	0.60
323.2405396	100.00
323.9391174	0.98
341.1763	1.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
101.8800049	0.11
107.0690384	0.48
109.1225891	2.07
116.8014221	0.23
121.1013184	3.00
125.2010498	0.09
128.8502808	0.63
132.8369751	0.90
135.0132141	2.04
143.2223816	0.41
144.8302917	0.23
147.3102112	0.20
149.1441345	1.74
150.4363708	0.34
153.1196594	0.18
155.2657471	0.25
156.8992004	2.01
158.6235657	0.24
160.976532	0.87
163.0028687	1.08
165.1025085	0.79
168.9930725	0.35
171.3540497	0.60
173.0364685	0.57
175.0508423	0.13
177.1090088	0.61
179.2451782	0.68
183.0675659	2.40
184.9322815	0.49
187.022644	1.29
196.9219666	0.45
201.1097412	1.04
203.0842896	1.00
204.2462006	0.18
207.3036499	0.44
209.3478088	0.10
210.641571	0.18
211.2579651	0.19
213.2776794	1.01
215.1390686	0.17
216.2401428	0.09
217.1318665	0.41
219.322998	0.14
223.0362244	0.83
225.1165161	0.29
227.0614319	0.15
229.2025146	0.63
231.268219	1.14
234.8237305	0.06
238.3771973	0.12
240.4110107	0.15
241.3911438	0.09
245.1961975	5.46
247.2605286	6.77
249.0399475	0.52
253.1400757	0.21
257.2116089	1.26
259.1204224	1.43
260.3558044	0.21
263.23703	0.15
264.1179199	0.24
271.4254456	1.04
277.1378479	0.14
278.890686	0.16
281.1478577	1.15
283.161438	0.23
284.9160156	0.42
287.0856934	0.20
295.2012329	1.67
296.7950439	0.43
299.1523438	1.95
299.7775574	0.10
305.406189	1.39
309.4034424	0.89
323.243042	100.00
323.9447021	0.14
332.4223022	0.71
341.2445679	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.14
Annotation	Inumakilactone D
Peak:m/z	Relative Intensity
146.9284515	1.61
201.4230042	2.07
223.1015015	0.91
232.9889526	2.04
237.1109314	3.25
292.977417	3.18
297.668457	0.82
312.5084839	1.00
321.3934631	1.76
326.3121338	1.37
331.9320374	3.14
349.1285706	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	614.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0387573	0.15
216.9528046	0.02
229.0201569	0.09
273.0755310	8.34
274.1338501	0.03
274.9416504	0.05
289.1187744	0.04
290.8396606	0.01
383.6006470	0.07
384.8570557	0.02
387.0023804	17.68
429.0243530	0.02
441.0897217	0.03
459.0616455	1.08
459.8952026	0.19
461.0416870	0.55
468.0295410	0.01
469.9497070	0.04
479.1350708	0.02
483.0295410	0.07
484.9495850	0.10
486.8888550	0.07
498.1177368	0.05
499.1436157	0.64
500.8434448	100.00
501.5061035	0.13
540.9616089	0.05
542.3737793	0.04
559.6777954	0.01
567.0198364	0.02
567.8781128	0.19
568.9396362	0.21
570.0017700	0.11
570.9020386	0.32
572.8941040	0.03
577.5015259	0.03
582.2883301	0.05
583.0891113	0.03
586.4751587	0.02
588.7240601	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.3917
Annotation	Unknow
Peak:m/z	Relative Intensity
169.2818604	0.25
181.0697479	0.07
183.2432556	0.24
210.8722382	0.92
227.9758911	0.07
254.5180359	0.40
278.2716064	0.05
288.9736328	0.11
302.2603760	0.16
319.2471313	0.11
320.1157837	0.07
323.5899658	0.32
331.4674683	0.07
342.2258911	0.14
346.8737183	0.46
360.9654541	0.37
362.1444702	0.15
365.1710815	0.44
377.0432129	0.27
378.8986816	3.22
379.5947876	0.03
393.0609131	0.32
397.0191650	0.08
411.3971558	0.24
422.1643677	0.17
425.2698364	0.11
431.9563599	0.08
438.2307739	0.99
453.2896729	0.12
467.5239868	0.11
471.1419678	0.07
472.2166748	0.12
478.2824707	4.13
479.2170410	1.54
484.4111328	0.25
488.6864624	0.05
490.9976807	0.80
495.7630615	0.18
506.7011108	0.21
508.4231567	0.27
509.0698242	0.25
512.2736816	0.21
516.3771362	0.43
518.4414673	0.19
520.4337158	0.12
522.2769165	0.57
523.3343506	0.16
528.3325195	0.25
529.4568481	0.39
532.0466919	0.62
538.2355957	0.73
542.5971069	0.99
543.2085571	1.60
543.8834229	0.25
547.1187134	1.53
548.3063965	0.40
551.6290894	0.21
554.0310669	0.08
561.2427979	100.00
562.0836792	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	616.9
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0028992	0.07
228.6514587	0.33
273.0465698	8.28
273.9736023	3.84
275.0674744	2.23
386.9654541	11.62
387.9813232	11.53
388.9583130	14.19
500.9183960	45.49
501.9271240	93.33
502.8955688	100.00
503.5079956	0.41
509.9131470	0.10
526.2498169	0.15
526.9100952	0.06
530.7678833	0.08
542.9843750	0.05
549.8145142	0.10
570.8543091	0.82
572.4731445	0.25
573.1817017	0.30
588.9348755	0.16
598.8960571	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	230.9897
Annotation	Unknow
Peak:m/z	Relative Intensity
69.9660492	0.37
104.3071899	0.55
113.2173767	0.24
129.9639740	5.06
131.0658264	0.53
132.0283508	0.23
142.1149292	0.67
143.0518951	0.99
144.0970154	0.37
145.0499268	0.35
155.9998627	0.16
169.8060150	0.35
170.8726349	0.26
183.1662292	0.49
184.0668182	0.64
185.1117401	1.84
189.9648438	0.45
192.5373535	0.54
195.0525055	0.45
198.8231964	9.97
199.5517883	3.29
211.1965790	0.66
212.8649139	5.34
213.5652924	1.08
214.3879242	0.66
221.8406372	100.00
222.6390228	25.99
241.0193024	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.2629
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
92.73825836	0.95
94.88323212	0.77
96.84465027	0.89
100.9591675	8.27
106.9041595	1.18
109.0355072	6.51
110.8033295	2.75
115.0612946	0.44
121.1851807	8.12
123.0682373	4.11
128.9877319	0.69
135.2460632	0.49
137.1239777	2.32
143.2601624	1.03
149.0421448	1.47
150.9595642	0.59
154.5495453	0.74
161.1421509	0.69
163.2443237	1.33
165.1879272	0.94
167.2609558	0.92
168.6051636	4.04
170.9740295	3.70
176.2220154	5.81
177.1253967	4.50
181.143692	3.63
182.9833374	0.94
185.2796783	1.79
191.2159576	0.69
193.1278381	1.19
199.139801	5.53
209.2459412	2.60
213.0106201	2.71
223.3404236	1.08
224.1275024	0.82
225.103363	11.42
227.066803	4.13
235.3544006	1.17
241.2582703	3.24
247.3019714	21.72
255.2441101	2.30
265.2516174	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
97.9244080	0.04
114.9997101	0.06
122.9658737	0.21
138.9360199	0.08
148.0194092	0.04
151.0251770	0.09
152.9363556	0.25
154.9674072	0.27
156.9653625	0.06
162.7174072	0.06
168.7750549	0.04
171.0138245	0.41
173.0649872	0.05
174.9598694	0.17
177.0665283	0.03
185.1772003	0.06
188.7911682	0.09
200.0242310	0.07
201.0873718	0.06
203.0176392	0.05
205.2596436	0.07
213.1016846	2.08
216.5389099	0.44
218.9019165	0.06
222.4844360	0.05
224.8752441	0.20
227.0501404	0.28
228.1003418	0.16
228.9275208	0.03
230.8998718	0.83
232.8036499	0.10
239.1522827	0.09
239.8475037	0.22
243.1013489	1.91
243.8765564	0.12
245.5606079	0.20
246.2761230	0.03
247.1555176	0.12
248.0027161	0.39
252.9627991	0.47
260.2812805	0.17
261.0746460	0.28
265.1006470	0.08
269.5065308	0.14
271.0213318	100.00
271.9792786	0.12
279.3878479	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	285.22
Annotation	Vitexifolin C
Peak:m/z	Relative Intensity
85.06352234	0.23
93.09040833	0.36
95.00249481	1.47
96.95918274	0.94
109.1099243	1.70
111.1089172	0.89
119.1154633	0.36
123.0906677	0.61
125.1454926	0.69
128.9699402	3.66
130.521637	0.63
133.0138245	0.23
143.0237122	4.82
147.072998	0.78
151.1708984	1.07
155.0136719	1.85
157.1208801	2.56
158.7923889	0.62
160.8826904	0.29
168.8127289	1.06
170.4824219	2.12
171.0969391	4.91
173.0850677	0.76
185.0331116	5.21
186.9332275	0.91
189.2099915	1.33
191.4170074	0.58
193.3468628	0.56
195.2111511	0.23
197.2909241	1.10
201.1714172	1.00
203.0486145	0.35
207.1362	5.42
209.1253357	0.42
210.2267151	0.31
213.9656677	0.46
220.9132996	1.22
222.8764954	1.44
225.2331848	2.27
226.0364075	0.49
227.0827942	0.64
229.0390015	7.25
239.2176514	4.08
243.2998962	3.79
244.1122437	2.02
249.0984802	3.31
250.4091797	1.11
257.3952637	0.29
267.2096863	100.00
268.1701355	0.32
276.7843323	1.49
285.0384827	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	277.2174
Annotation	Gorlic acid
Peak:m/z	Relative Intensity
95.2355957	2.37
96.9455719	2.22
109.1576614	1.77
113.081749	2.14
135.0189209	0.96
136.1750641	2.22
145.0975342	1.32
154.5878754	1.77
173.3367462	1.24
175.9257812	3.40
178.1264648	1.14
179.3635712	1.05
191.270462	3.90
205.1868591	16.79
207.4676208	1.94
219.2832947	4.66
231.1825562	1.33
233.2339783	100.00
235.1559448	11.55
238.0323181	1.23
239.3946228	1.41
241.2399902	5.48
244.8870239	1.86
247.3844299	1.50
249.9755554	1.34
257.155426	8.85
259.2093811	43.67
260.1096191	1.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.9098053	0.46
108.9708786	0.41
111.0491333	0.30
119.0101929	0.32
120.9530334	3.17
122.9905624	0.46
130.9954224	0.56
133.2517242	0.19
134.8655853	1.59
137.1774139	0.47
137.8024139	0.28
143.1421509	1.15
145.1315613	0.10
146.9117432	0.13
149.1124573	1.67
151.1737518	0.97
154.812439	0.65
156.7480774	0.65
160.9840698	0.16
165.0671234	1.10
166.9894409	0.29
168.9320831	0.74
170.9162598	0.76
172.0497742	0.20
173.0751038	1.85
174.7977905	0.15
176.5887299	1.17
177.2680664	0.44
178.9547272	0.51
182.994751	2.01
187.0770264	2.04
197.1770477	0.40
199.1555023	0.37
201.0544434	0.44
203.014389	0.24
205.2736511	1.41
209.1361694	0.24
211.0415955	2.31
213.3215027	0.35
216.8814087	0.15
217.4873657	0.34
219.0891418	0.11
223.0752869	0.46
231.091095	0.96
232.9058228	0.32
235.0031128	0.18
237.344696	0.19
239.3555603	0.30
243.2054749	0.29
245.1562195	1.99
247.2501221	7.75
249.0015259	0.11
253.1596069	0.27
259.1317139	3.55
262.9337158	0.75
269.3496704	0.34
271.2634277	0.33
273.2713318	0.52
277.0210571	0.08
283.1918945	0.26
287.50354	0.84
294.2188721	0.12
295.2074585	1.24
297.2731323	0.17
299.3282776	5.19
303.3878784	0.18
305.2949524	2.12
306.0606079	0.28
310.3760376	0.13
313.2897949	3.32
314.7940979	0.22
323.2444458	100.00
324.0351868	1.16
325.2476807	0.16
331.6238098	0.23
340.3200073	0.11
341.1518555	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	602.6756
Annotation	Unknow
Peak:m/z	Relative Intensity
193.3292542	0.04
210.9826965	1.15
215.0849609	0.10
223.1036072	0.09
232.8976135	0.08
241.0446472	1.57
255.0100861	0.09
256.9735413	0.28
259.2983398	0.05
262.0598145	0.44
269.1366272	0.10
280.1232300	0.41
293.0626831	0.14
298.9429626	0.15
306.9703674	0.09
311.1392212	0.32
318.1455688	0.07
323.1845093	27.07
324.2378540	0.03
329.1307373	1.17
341.1817627	0.05
351.0722046	0.22
351.9780273	0.10
359.0801392	1.53
371.0888672	0.20
371.8801270	0.05
377.0068359	1.95
380.0745239	0.49
382.2654419	0.05
385.0258789	0.11
388.2232666	0.32
396.2313843	0.04
401.1951294	0.07
418.3596802	0.06
419.0637207	0.70
422.9423218	0.42
424.2550659	0.27
428.7777710	21.20
430.9846802	0.27
432.8595581	0.34
434.8967896	1.62
436.9232178	0.15
439.9032593	0.67
441.1226807	8.44
443.2395630	0.06
446.4912720	0.33
449.1251221	0.14
450.9318237	0.46
451.9506226	0.04
452.9842529	0.15
462.2601929	0.05
466.8312378	52.49
467.8430176	1.23
469.9865723	3.06
473.2165527	0.17
483.0275879	8.78
485.1781616	0.32
487.9876709	0.44
488.7471313	0.10
491.0365601	0.60
499.9805908	0.17
501.3021851	0.05
504.5910034	0.08
506.1646118	0.05
507.2774048	0.04
514.0757446	0.06
516.6123657	0.73
518.7540894	100.00
519.3604126	0.63
519.9982300	0.37
523.7836304	0.15
524.4291382	0.19
526.6248169	0.05
534.7722168	5.61
541.8734741	0.50
556.2139893	0.06
557.0509644	0.13
560.1100464	15.60
585.0173950	7.13
585.6757202	0.02
768.4978027	0.16
942.3881226	0.15
945.6401978	0.04
1076.3288570	0.50
1106.8870850	0.05
1108.4349370	0.31
1114.3247070	0.10
1160.8901370	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.2021
Annotation	Koninginin G
Peak:m/z	Relative Intensity
87.03112793	0.33
113.0826797	0.42
114.8535004	29.07
117.0608215	0.14
140.9850769	0.13
143.1092224	0.20
154.1516571	0.08
156.9641571	0.07
159.1544495	0.21
172.0738983	0.16
172.9170837	0.07
183.2361603	0.08
197.1617279	1.13
199.3668823	0.66
201.4038391	0.17
211.1989441	0.15
226.0036621	0.12
228.8761292	0.27
232.8659363	0.21
237.2276917	0.13
238.4494934	0.04
239.2801208	0.73
241.2233887	0.21
243.0018311	0.21
245.3359985	0.11
254.4252319	1.14
255.2442627	0.34
256.1306763	0.12
257.245636	0.90
257.9877319	0.08
259.0218506	0.59
263.0566406	0.50
263.7982788	0.06
264.8677368	0.44
272.8825073	0.14
281.2484131	0.08
283.192749	100.00
283.882782	0.17
285.3536987	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9172
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9079895	0.02
146.7124939	0.03
159.0352783	0.07
174.9716187	0.77
245.0835266	0.18
247.2195740	0.10
273.0617676	3.49
275.0248413	0.03
287.0123901	0.03
288.9425659	100.00
329.0842285	0.28
347.2707520	0.03
356.9438171	0.48
358.1342468	0.02
358.8782654	0.03
375.0076599	0.22
384.8143616	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.242
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
96.95579529	0.41
122.9111557	0.97
124.9401093	1.37
126.9931946	0.94
136.9769592	0.63
138.938324	10.75
151.0233154	0.25
169.2315674	2.10
171.1969147	0.82
183.2790375	1.72
193.038559	1.32
197.0990295	11.01
198.9069214	0.83
205.1014709	1.00
211.0221558	1.66
213.1276245	0.35
221.1782227	3.33
227.3191223	1.31
229.2890015	0.73
237.1181335	0.99
239.0557251	10.13
240.3875732	0.52
241.1377869	1.73
243.3654175	2.15
251.2425537	1.33
253.3157349	1.48
254.173584	0.46
255.0505981	0.45
255.8036499	0.68
256.6182861	1.71
261.3818359	3.92
269.0331421	0.66
279.2345886	100.00
281.2108154	1.86
288.1904297	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.3729
Annotation	Trillin
Peak:m/z	Relative Intensity
163.1880798	0.24
181.0787354	0.47
205.2097321	1.19
211.9502258	0.50
252.0388031	0.19
253.1832123	3.84
271.1994324	32.27
283.1802979	0.93
397.5415039	2.17
413.4965820	0.24
415.3343506	100.00
433.0711670	0.49
445.3185425	0.31
451.1644897	0.31
457.4558716	0.63
481.2289429	0.42
499.4133911	0.27
500.9745483	0.16
505.4874878	0.43
510.5645752	0.96
520.0521240	0.30
541.4390869	1.15
559.3559570	2.65
560.2835083	0.34
561.0361328	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9794693	5.13
115.8907928	1.76
131.0046997	0.21
132.0642548	0.08
158.9401550	100.00
159.9100037	30.06
174.0150452	0.03
199.0112305	1.76
200.0158997	1.06
201.8910522	0.03
216.9487000	0.69
218.0517883	0.28
228.9231873	17.91
229.9649963	14.41
244.9661255	0.28
246.0115051	0.23
272.9227295	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	281.1378
Annotation	Penifulvin B
Peak:m/z	Relative Intensity
94.96796417	0.35
106.7828979	1.08
111.0863342	0.97
127.0464401	0.84
149.6897888	2.10
166.7220612	0.44
190.9483795	0.81
200.0889282	2.35
201.2988892	2.26
203.3233337	2.60
205.1276245	1.06
206.8812866	2.74
215.0832825	2.26
218.9568176	1.95
221.2338867	0.69
221.9181519	1.49
225.3980713	0.74
227.1846619	2.99
232.3378906	1.13
233.1297913	2.21
234.9673462	2.64
239.2648621	4.97
240.0667114	0.78
245.1460571	9.00
253.1052246	1.19
260.9866028	2.06
263.130127	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0309525	0.33
108.8267746	1.12
109.4651718	0.24
118.9510956	0.21
121.0368195	0.26
126.9022064	0.16
128.7086639	0.62
130.875351	0.57
134.9992676	0.78
137.0887299	0.37
142.9529114	0.21
147.0601501	0.85
149.0595093	1.06
150.464447	0.20
151.138504	0.43
160.9967194	0.62
162.8917999	0.50
167.178299	0.42
168.9530487	0.50
171.0485992	0.65
173.1777954	0.51
175.1919556	0.30
185.070282	0.14
186.9935303	1.61
197.0313721	0.30
203.2029572	0.28
205.8512115	0.34
208.302063	0.28
210.8040161	0.46
214.7283325	0.53
217.1864319	3.61
219.2174377	0.16
222.9624023	0.24
224.1174011	0.27
225.4312439	0.21
229.226593	0.31
230.8247986	2.01
239.0692749	0.56
240.0301514	0.81
241.0585632	1.41
241.9700012	0.63
245.1642456	2.02
247.2793884	1.99
251.019043	1.02
252.9385071	0.38
255.3218689	0.62
263.089325	0.60
264.206604	1.23
265.0171509	0.37
267.1873779	1.78
270.2989197	0.18
270.9613647	0.93
276.2730103	0.53
277.8893738	0.16
278.5661621	0.38
279.1878967	0.19
281.0556641	0.42
282.9994812	1.92
285.3591003	0.41
287.34375	0.56
294.7742615	0.46
299.2954102	2.93
300.0289001	0.39
305.1887207	3.69
306.3963623	0.46
313.182251	0.21
323.2432861	100.00
323.9450378	0.31
325.2716675	0.57
340.8621216	0.51
341.4787292	1.70
350.4141846	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	697.3278
Annotation	Zygophyloside O
Peak:m/z	Relative Intensity
223.2155762	0.04
256.1051636	0.04
299.1422729	0.01
351.8987427	0.05
404.1718140	0.04
449.7053833	0.03
459.5920410	0.07
469.3084106	0.03
491.3458252	0.02
516.7803345	0.01
535.4105835	0.02
549.0686035	0.02
567.5553589	0.02
580.9874268	0.05
600.2961426	0.05
601.3080444	0.01
606.3533936	0.02
611.4348755	0.33
620.4452515	0.04
635.2053833	0.05
637.5698853	0.02
639.1507568	0.01
650.4223022	0.07
651.1205444	0.01
653.4304199	100.00
654.0903931	0.13
661.3383179	0.06
664.1203003	0.01
670.0838013	0.05
674.1071167	0.02
678.7389526	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.2603
Annotation	PI(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
226.1400757	0.03
227.1081085	0.03
291.1092224	0.04
299.0496216	0.04
307.0750122	0.09
319.3579102	0.04
341.3951416	0.02
407.2362671	0.03
421.3054199	0.02
432.8170166	0.02
441.3595581	0.02
454.2795410	0.05
456.1109619	0.05
473.2280273	0.10
481.1486816	0.04
493.2100830	0.03
502.8676758	0.08
505.0941162	0.06
506.2210693	0.11
527.3494263	0.08
528.6937256	0.06
533.2749634	0.54
538.0751343	0.03
541.4317017	0.07
555.3105469	14.39
555.9364624	0.48
557.1436768	0.20
564.8164673	0.28
571.8086548	0.13
578.1741333	100.00
578.8855591	3.55
580.5183716	0.12
581.1978149	0.06
582.8931885	0.10
584.1371460	0.05
585.0636597	0.09
592.8881226	0.05
595.2239380	0.13
785.1869507	0.10
786.6516724	0.03
803.8235474	0.05
950.0433960	0.06
1111.4158940	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.0809
Annotation	Nicotinate D-ribonucleoside
Peak:m/z	Relative Intensity
88.0225601	0.06
123.9206085	100.00
129.1720581	0.07
130.0964813	0.15
132.5488281	0.09
133.1505127	0.27
135.0916138	0.10
139.1728668	0.10
155.0382690	0.06
156.1925354	0.05
190.7545013	0.11
195.0589142	0.17
209.0467682	0.07
212.8729401	0.17
220.0899506	0.07
227.4251556	0.16
237.2111206	0.09
238.3641205	0.81
239.1020355	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
112.7598724	0.04
115.0309906	0.02
142.7064209	0.02
149.0482635	0.02
161.1070251	0.40
179.0128174	1.23
180.0406494	0.42
196.9883423	0.07
198.0714111	0.19
199.0109253	0.65
215.1085968	1.69
216.0255737	1.68
217.0283508	9.22
221.0700989	0.02
222.9657288	0.04
233.1520996	0.06
251.0391235	0.08
288.9143677	0.03
323.2639771	0.13
341.1865234	100.00
342.1481323	37.26
343.1997681	9.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0982
Annotation	Syringic acid beta-glucopyranosyl ester
Peak:m/z	Relative Intensity
112.9795227	1.05
135.1917419	0.80
138.9108124	0.35
140.0806274	0.39
142.9286194	0.80
152.1124268	1.10
153.1607361	1.80
160.9864349	0.74
162.8841705	0.24
179.3797913	1.47
180.1731567	0.45
181.9699707	5.25
194.9431915	0.88
197.045929	100.00
198.0361938	3.10
198.9679565	0.19
211.1427612	4.55
213.1902771	0.26
224.1752625	0.55
230.8981628	0.20
236.0206909	0.25
239.0939636	37.26
251.0300598	0.43
262.8340454	0.69
268.9959412	3.93
271.1573181	1.01
283.9795837	0.28
285.0443726	0.17
290.8374023	0.74
293.5448914	1.37
299.2431946	2.84
312.997345	1.18
315.2645874	0.70
321.244812	0.93
322.9239502	1.47
331.1366577	0.35
341.0879517	2.36
343.0869446	0.19
343.9472351	1.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
92.95042419	0.61
96.70865631	0.61
99.01130676	0.45
112.9954987	0.69
118.9561005	0.49
120.8513718	0.76
123.1452866	0.68
123.9716492	1.00
137.3392334	0.41
139.0686951	2.43
141.1005859	1.42
149.0222168	1.19
152.8591919	0.49
154.9234314	0.72
160.9971619	1.95
162.95755	1.37
169.0384064	4.62
170.8137817	1.48
180.9263611	0.88
182.9788208	0.72
185.5250549	0.49
197.0105591	3.74
199.2679138	1.44
199.9658813	0.53
201.0534058	0.76
203.1804504	0.37
209.0634155	0.93
211.1293945	2.40
213.4534302	0.33
225.3573608	1.11
226.8258362	0.57
233.3656616	2.47
236.9172668	4.81
239.1218262	11.51
243.2414551	1.60
251.3789062	0.72
255.1528931	0.57
257.0072632	0.61
260.951416	2.84
264.8736267	0.88
269.3087158	0.64
271.7578735	0.77
278.0542297	0.58
279.2316284	100.00
281.3818359	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
153.1489563	0.13
196.2445526	0.05
206.0660706	0.12
212.1989441	0.09
214.1346741	1.94
219.1031494	0.07
224.1089783	0.08
235.3871307	0.09
261.3995972	0.17
269.4658203	0.20
276.1046448	0.07
279.2644653	100.00
281.2019958	0.04
283.4890137	0.20
290.2894287	0.06
291.8526611	0.06
314.8687744	0.06
348.7318420	0.08
351.8301392	0.08
356.3674011	0.07
370.6123047	0.08
388.2231750	0.07
392.9955750	0.07
401.0892029	0.41
405.3320007	0.18
408.4849548	0.21
413.5567932	0.16
430.1611633	0.19
431.1637573	0.25
432.1039124	0.19
440.3276367	0.32
448.4984131	0.21
457.8849182	1.71
458.8549500	0.50
460.3648682	0.13
462.6987915	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	407.17
Annotation	Icariol A1
Peak:m/z	Relative Intensity
147.6897583	2.25
183.2014771	3.46
222.0984802	3.13
256.9851685	3.62
259.6174927	1.95
271.0740967	2.10
279.2366638	3.31
282.8885498	1.49
312.6987305	4.03
319.3757629	9.62
342.9785156	9.32
349.2985535	4.21
363.6263123	4.35
371.1434937	4.53
389.1584473	100.00
398.5170288	5.84
406.8514404	5.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.0935
Annotation	Arcyriacyanin A
Peak:m/z	Relative Intensity
147.0859375	0.09
153.8367920	0.13
164.2537994	0.07
175.0566101	0.40
192.7592621	0.14
194.0214539	0.25
194.9808807	0.20
195.6491394	0.18
212.1007385	0.14
213.9661255	0.28
221.6376343	0.29
222.9260864	0.12
230.0733948	100.00
231.5391541	0.12
232.8478699	0.14
236.3618469	0.07
256.9970703	0.75
262.1853027	0.56
267.1437683	0.17
268.4867554	3.11
269.2611694	6.51
270.2461853	1.85
280.1660767	0.14
289.4825439	0.34
291.3546753	0.26
294.6703796	0.31
309.7771606	0.35
317.9737244	0.42
330.0027771	1.11
422.7933655	0.43
457.1246643	0.09
458.1117859	0.10
459.2668762	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
165.1804504	3.72
224.8951721	6.66
285.3098145	11.88
287.0653076	11.87
299.4299927	21.43
323.2346802	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	149.05
Annotation	D-Apiose
Peak:m/z	Relative Intensity
58.9414520	4.24
69.0321503	0.10
70.9828644	0.15
73.0202026	2.01
74.9037704	6.33
84.9809647	0.33
87.0522690	0.38
88.9014206	32.63
100.9670715	0.35
102.9940948	16.05
130.9115906	100.00
131.9670715	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1052.56
Annotation	Unknow
Peak:m/z	Relative Intensity
580.2517090	0.45
781.8823853	0.51
891.6064453	0.81
974.3433838	0.63
1032.1894530	2.20
1034.6431880	1.05
1061.9926760	0.33
1304.4543460	0.35
1646.2122800	0.18
1697.9066160	0.17
1739.9703370	0.43
1745.1190190	0.51
1791.0806880	3.48
1796.3031010	0.20
1817.4620360	0.17
1822.6387940	0.44
1828.2896730	1.46
1839.8161620	1.84
1842.0460210	0.52
1847.7033690	0.28
1851.0711670	2.35
1852.7518310	8.11
1858.8211670	2.49
1860.2663570	2.37
1862.1160890	0.14
1863.2921140	0.19
1867.2955320	8.08
1868.5072020	0.13
1874.7100830	0.76
1889.9576420	0.59
1898.7214360	2.81
1905.8527830	63.09
1909.5061040	12.80
1910.5378420	0.38
1917.3756100	50.38
1920.8721920	1.79
1922.8566890	25.18
1924.1726070	0.26
1927.2960210	0.73
1929.7121580	1.54
1931.2269290	3.77
1932.8078610	19.36
1934.7038570	0.53
1935.7385250	23.48
1937.6199950	3.55
1939.5124510	0.33
1942.5964360	0.65
1945.4078370	6.10
1946.8802490	18.19
1949.9670410	4.15
1950.8093260	0.27
1952.7303470	0.50
1955.6761470	0.96
1958.9127200	0.96
1959.7502440	0.60
1961.0281980	5.17
1962.2149660	0.25
1967.5692140	1.61
1968.5418700	1.35
1969.5109860	4.39
1971.0203860	2.43
1972.6658940	28.40
1973.4753420	0.31
1975.0969240	8.72
1976.8977050	2.73
1979.2916260	1.22
1981.8475340	2.56
1983.0245360	85.24
1984.8029790	6.50
1988.0552980	0.36
1989.9110110	17.61
1992.7393800	1.00
1993.8425290	100.00
1995.2653810	4.48
1997.5943600	4.04
1999.8560790	17.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	386.2508
Annotation	Unknow
Peak:m/z	Relative Intensity
115.1140137	0.04
133.1879272	0.06
144.1279144	0.04
154.0859070	7.83
170.8764648	0.08
172.2407990	0.24
179.8425598	0.24
189.0832825	16.87
198.1179047	100.00
212.8277893	0.28
214.7398376	0.17
215.9484100	0.07
229.1712952	0.31
231.7067871	0.04
253.1186523	0.17
271.9418945	0.41
301.7885132	0.14
310.0095825	0.06
312.0236511	0.22
326.3476257	0.22
327.3289795	0.17
352.6178284	0.03
367.8729248	1.51
368.8622131	0.55
369.9895325	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1258
Annotation	Unknow
Peak:m/z	Relative Intensity
160.1658783	0.41
181.0156860	0.32
210.8685608	0.32
231.1112671	2.29
256.0990601	0.19
306.0366821	8.67
317.1918335	5.22
334.0062256	100.00
344.2178955	0.14
364.3086548	0.50
391.2786255	1.17
409.0711670	83.74
409.7666626	0.31
432.0590210	0.49
444.7067261	0.19
445.3648071	1.35
463.2223511	0.76
464.6920776	0.32
474.7904053	0.21
504.0776367	0.30
509.0332642	0.56
520.3075562	7.65
521.1382446	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.12
Annotation	Curculigoside B
Peak:m/z	Relative Intensity
171.0339050	0.03
179.0587921	0.15
235.1820068	0.20
238.8289185	0.11
249.5460205	0.04
262.9784546	0.12
272.0504456	0.05
279.2282410	0.05
299.2890625	0.11
302.1798401	0.04
305.1343079	0.07
308.0524292	0.03
314.0978699	0.06
323.3438721	0.03
378.9898987	0.31
415.2184753	100.00
433.1166077	0.10
434.1583862	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0764
Annotation	Glutathione
Peak:m/z	Relative Intensity
96.8533401	0.10
98.8956299	0.28
99.7732086	0.09
111.9844055	0.06
115.9786148	0.08
125.0008774	0.09
126.0792770	0.06
126.7809525	0.13
128.0347595	7.94
142.9242554	9.30
143.5358276	0.08
144.1563110	0.09
145.0956726	0.70
146.0907593	1.12
153.1580353	0.13
155.1250305	0.10
160.0234985	9.73
166.0856323	0.40
167.0660400	0.66
168.9511566	0.18
169.9952393	0.21
171.0169525	0.83
177.0528717	9.22
179.0191803	9.18
185.0268097	1.05
197.1376648	0.73
201.0087585	0.10
210.1299438	6.08
212.8939514	1.14
228.1387024	0.42
231.1062317	0.96
234.3663635	0.13
235.9933777	0.57
242.1806946	1.07
254.0769348	88.54
272.1152039	100.00
288.1689453	59.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	245.2108
Annotation	13-Hydroxymyristic acid
Peak:m/z	Relative Intensity
95.00523376	6.83
112.7266998	4.08
124.8856506	3.68
158.7958527	3.81
169.1169434	2.47
177.9273834	2.20
185.114212	8.41
187.0849915	3.35
197.0287323	6.77
198.7003479	4.89
217.0169983	5.26
217.9718781	3.27
227.1913605	100.00
228.2384644	21.33
236.6196747	13.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	677.2515
Annotation	Unknow
Peak:m/z	Relative Intensity
202.2398529	0.06
275.9931335	0.25
277.3318176	0.19
292.9715881	0.06
303.8356934	0.04
304.4370728	0.13
305.1802979	0.20
306.1530762	0.09
329.1693726	0.03
345.2492676	0.10
346.4107056	0.19
347.5321655	0.02
405.3346558	3.56
406.2529297	2.77
407.3588257	1.06
474.4392700	0.04
475.2979736	0.14
476.4592896	0.04
477.3392334	0.66
478.3779907	1.26
479.3929443	0.66
481.0667725	0.03
500.0228271	0.03
507.3495483	0.06
530.5355835	0.07
548.3081055	26.74
549.3200073	100.00
550.3820801	38.32
589.3508301	0.04
594.2369995	0.04
629.6782837	0.10
634.3032227	0.67
635.3742065	0.32
636.3637695	0.06
640.7732544	0.04
642.1624146	0.02
649.5125122	0.08
659.1636353	0.03
660.3590698	1.55
661.3168335	1.28
663.6756592	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	207.0147
Annotation	Garcinia acid
Peak:m/z	Relative Intensity
72.9035645	0.43
82.9704285	0.14
85.1164551	0.05
87.1578674	0.02
88.8063965	0.02
98.9849548	0.56
101.0144501	0.15
102.9355164	0.15
104.0446625	0.01
112.9590149	0.02
116.9947968	0.73
119.0422974	0.03
125.1366272	0.02
127.0027771	11.55
128.8069916	0.01
130.9742889	0.16
133.0523834	0.28
135.0024567	0.04
142.9878693	2.42
144.9348297	0.28
147.1660156	0.01
150.9519501	0.02
161.0039215	0.95
162.9551849	0.05
170.8891449	0.93
175.0042877	0.08
178.7798004	0.03
188.9205170	100.00
189.7710724	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	364.8697
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9652710	5.26
128.9839325	0.32
168.1484222	0.17
192.2737122	0.16
196.8400269	6.08
213.1569824	0.25
229.0936584	0.32
252.4559326	0.46
280.7766113	100.00
296.9750061	0.59
336.1485291	0.14
346.7187805	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	249.15
Annotation	(1R*,3Z,7E,11R*)-(-)-7,10,10-Trimethyl-12-oxabicyclo[9.1.0]dodeca-3,7-diene-3-carboxylic acid
Peak:m/z	Relative Intensity
79.82776642	100.00
81.05408478	8.88
127.0532684	5.44
162.9114227	4.62
179.2590637	2.78
183.4251862	16.18
200.9879303	3.58
202.9668427	10.14
205.1580658	61.95
221.0963287	7.92
228.9736786	7.13
231.1352997	7.32
249.3806	36.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9579
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0531006	0.07
141.8949127	0.21
156.0162659	0.22
160.0407104	0.15
170.0066681	1.22
171.8877869	0.12
177.0927429	0.22
184.0108337	0.50
191.1852112	0.09
199.8491516	18.87
200.9334106	0.71
213.9847260	5.05
217.9745026	0.08
225.6905518	0.11
227.0851898	0.16
228.0030212	0.79
240.1635132	0.22
241.9976196	0.33
243.8782349	5.30
245.9464417	0.57
255.9386902	0.20
257.9145508	64.91
262.0249939	1.85
267.9675598	0.09
271.8423157	0.58
283.9895020	1.57
285.7916260	5.37
288.0072632	8.63
289.7306824	1.24
290.3618164	0.09
299.0408630	0.16
301.8568726	47.34
302.5105286	0.21
303.5147095	1.36
304.1406250	1.03
313.8833618	1.44
327.9661255	3.66
329.6373901	7.73
331.9671021	100.00
338.2799072	0.16
345.0908203	2.43
345.8755188	19.63
347.4735107	0.46
348.0738525	0.60
349.1268311	0.08
357.5846863	0.18
358.2676392	0.17
365.1671753	0.14
372.4690247	0.10
373.6665344	2.80
374.3433533	0.03
375.6108398	0.76
383.3654480	0.07
389.8716431	0.08
392.0012512	36.32
399.8460388	2.37
401.3663025	0.10
417.9847717	74.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1613
Annotation	7-Methoxydiderroside
Peak:m/z	Relative Intensity
179.3988647	0.13
204.0922241	0.07
207.2825928	0.08
235.0465393	0.04
253.0874634	0.05
267.3436584	0.05
271.3183289	0.03
281.9669189	0.04
287.1687317	0.10
297.1665649	0.17
299.3044434	0.15
300.2249756	0.09
301.0776062	0.02
302.1611633	0.04
307.0603027	0.05
311.2097778	0.04
314.2868042	0.21
314.9481812	0.13
319.4129639	0.05
326.2603149	0.04
329.4463806	0.06
341.4265747	0.04
381.1384583	0.09
385.1427612	0.05
388.2441711	0.04
389.2541809	0.04
397.6228943	0.04
406.9770203	0.05
414.6799927	0.03
417.5901184	0.18
423.9270325	0.13
431.1681824	100.00
433.4396667	0.04
437.2081299	0.26
439.3327026	0.03
441.1367188	0.15
457.3605652	0.06
459.4128418	0.19
460.9753723	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Galactinol
Peak:m/z	Relative Intensity
98.95523834	1.63
100.8924103	17.18
112.582901	4.91
118.9180603	16.00
124.597641	4.14
130.9725189	17.78
142.9746704	25.28
148.502655	3.55
149.1391602	5.28
160.7572021	5.50
179.0638123	100.00
207.0445862	1.77
212.0543518	2.80
215.1550598	2.94
221.085144	7.88
236.1400757	1.48
248.052124	2.46
257.2546387	2.63
280.9282837	2.05
295.0739441	16.13
297.227478	1.34
320.8769531	4.65
323.3060303	2.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	377.195
Annotation	Macrocalyxin B
Peak:m/z	Relative Intensity
177.1058502	3.50
191.255188	4.57
217.147583	5.34
219.1323853	2.96
251.1856995	5.85
264.4657288	7.11
283.0843506	4.81
323.3114014	6.80
341.1846313	100.00
349.1459961	5.60
359.1496887	43.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.11
Annotation	Taxicatin
Peak:m/z	Relative Intensity
109.0450592	4.76
121.8955917	0.27
123.0092163	2.05
135.0923462	0.18
153.0496674	100.00
187.2910461	0.08
198.7983704	0.15
212.9211121	0.10
217.3239746	0.08
229.2964478	0.15
238.9732361	0.15
243.4410706	0.07
253.3572998	0.15
254.8451233	0.12
261.1022034	0.53
268.9295044	0.61
271.2182617	0.47
271.8770752	0.10
278.1669617	0.08
279.0926208	0.12
281.5156555	0.42
287.048584	0.17
288.1984863	0.27
295.1617432	0.18
296.2060547	0.07
297.2047729	0.98
298.0172119	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Galactinol
Peak:m/z	Relative Intensity
96.87219238	0.35
100.9848709	2.56
105.884552	0.76
112.9193726	16.94
114.8500061	0.96
118.8706589	6.63
125.0686035	2.86
130.9062195	3.13
132.9492035	6.16
142.943222	18.20
148.9998474	1.57
160.8493347	14.13
179.0474091	100.00
186.1028595	0.26
186.9910889	1.66
210.9512634	0.95
251.1079407	0.35
255.1051331	1.27
256.9992676	9.96
266.9716187	0.64
267.9248657	0.60
279.3826294	2.01
281.1517639	3.18
294.8059082	1.97
297.326416	0.83
299.1303711	5.68
309.1735535	1.60
323.1407471	3.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	9-Hode
Peak:m/z	Relative Intensity
92.78012085	0.60
95.11559296	0.40
109.0946045	3.99
112.8824081	2.58
118.9436035	2.39
123.1890564	1.00
140.5263367	2.75
151.3379517	0.71
152.9649658	2.52
154.7055206	0.55
157.0912323	0.81
159.8883209	1.86
167.1576233	1.69
168.9515686	0.86
175.2929688	1.61
182.9965668	3.13
184.9994049	2.72
187.1480408	0.96
197.1079712	2.17
200.9983215	0.50
206.9724426	0.60
209.0232544	0.50
211.0877075	4.77
213.0851746	5.95
217.3299561	1.27
219.0526733	1.60
223.118042	2.10
225.1170654	6.32
227.2341614	2.27
229.015686	1.82
233.3162842	2.53
237.3131409	3.18
239.1809692	26.96
241.098877	1.04
242.9821777	1.61
251.2705078	3.35
253.2549744	0.91
255.1016235	4.60
255.7815247	0.70
257.0770264	3.00
261.3441162	5.71
279.2409668	100.00
280.1799316	1.35
296.3718262	3.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0982
Annotation	Vitexin
Peak:m/z	Relative Intensity
130.6985321	0.04
145.050827	0.04
161.127533	0.12
179.2758484	0.11
191.2329712	0.07
207.0639496	0.04
251.3713989	0.07
255.2070312	0.20
258.2171021	0.03
267.1087341	0.10
268.0867004	0.37
269.2491455	0.22
275.1651306	0.17
279.3788452	0.11
283.2348328	0.44
288.2584229	0.12
289.0952759	0.07
293.0594177	0.28
295.218689	0.11
299.2309265	0.04
305.1980896	0.06
307.8581543	0.17
308.9068298	0.04
311.0592957	100.00
311.8980713	0.04
312.5009155	0.16
313.8204346	0.07
323.0930176	0.78
325.1474304	0.06
334.3979187	0.23
335.1430969	0.24
341.2354736	27.81
342.5593262	0.31
343.6092834	0.09
349.2806396	0.04
351.3015442	0.24
353.0567017	1.41
354.0355835	0.11
355.203125	0.74
357.2513428	0.28
365.1678772	0.09
367.4154663	0.14
370.4094238	0.06
371.3104858	0.36
372.1352234	0.17
373.214447	0.11
377.5587463	0.05
381.1547241	0.24
383.2681274	1.40
385.1658325	0.73
386.3204041	0.37
387.2267151	0.40
394.0728455	0.23
395.0570984	1.34
411.003418	0.28
413.2112122	7.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.14
Annotation	Emoroidone
Peak:m/z	Relative Intensity
100.9947815	5.97
132.8310852	7.12
149.1234131	7.71
177.0825806	17.86
217.0064087	5.95
219.2024841	2.81
234.152832	4.00
251.1147156	5.65
253.4023743	6.91
265.1944885	9.81
272.0739136	13.87
279.2605286	16.12
286.1485596	2.81
289.3190918	28.55
290.348999	28.72
307.867981	6.78
309.1798401	16.59
311.8624573	44.18
317.1133423	22.94
319.2121887	23.25
325.5121155	17.53
329.9276428	6.38
335.1187744	100.00
336.4382935	13.65
353.1917725	3.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	602.8828
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9002533	2.38
175.9591064	0.06
273.0966492	0.39
289.0866699	0.05
359.4812012	0.09
386.9340210	0.11
402.9784546	0.16
404.3375244	0.06
427.1523438	0.38
430.0249023	0.09
443.1124268	0.34
444.5228882	1.06
445.2280273	0.92
447.1095581	0.19
468.9986572	0.10
473.0092773	0.04
486.1364136	0.18
487.0477295	0.59
487.9050293	0.48
489.0537109	1.75
492.1532593	0.12
494.0997925	0.05
500.2449341	0.64
517.1343994	0.19
519.2019043	0.17
528.1932983	0.29
528.9100342	0.12
530.3110962	0.07
541.0311890	0.14
544.4057007	0.28
547.9572144	0.10
556.8403931	100.00
557.6878052	0.60
558.9822388	0.46
562.9115601	0.05
573.8916626	0.05
574.8525391	0.05
576.2739868	0.13
583.9945068	0.46
584.8449097	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.1343
Annotation	Pseudoanisatin
Peak:m/z	Relative Intensity
105.1333084	0.15
107.1212463	0.08
111.1043091	0.74
112.8087997	0.37
119.2054443	0.64
124.89608	0.14
129.0361633	3.16
135.0722504	0.44
139.0953369	0.12
145.2474976	0.12
147.0551453	2.52
153.0332642	0.06
157.1967621	0.17
159.3294373	0.18
165.0478363	0.28
165.9790497	0.13
167.1861267	0.95
168.9029541	0.15
175.8919373	0.11
176.9958038	1.55
180.9657745	0.13
182.905304	0.46
185.1822968	1.46
187.2688904	0.54
195.1207275	0.32
198.8688354	0.34
205.0180664	1.13
217.0162354	0.12
223.3534546	0.74
225.2133789	0.27
233.1520691	0.77
235.2516479	1.55
237.0587463	0.48
238.1035461	0.07
249.335083	0.24
251.0039978	2.91
253.1369629	100.00
254.1372681	0.17
256.1624146	0.15
259.0003052	0.08
269.2071533	0.26
277.211731	0.13
279.1581726	3.84
279.852417	0.12
282.3265686	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2917
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
150.8585510	0.05
174.7854004	0.04
180.0483551	0.08
197.0559998	0.15
198.2438354	0.07
211.0585022	0.02
233.0325012	0.12
235.2509460	0.08
244.0166779	0.06
251.4165344	0.09
261.0423279	0.09
263.2564392	0.05
270.0813293	0.05
282.2239990	0.05
297.2164917	0.03
306.4067993	0.13
322.9183960	0.03
329.5157471	0.06
337.3052368	100.00
337.9285889	0.46
344.1802063	0.18
346.2788391	0.15
354.3262329	0.11
368.1844482	0.03
371.2393799	0.07
380.4134521	0.15
381.2913513	0.03
383.2666321	0.08
397.1728210	0.18
415.1038818	0.34
417.1659241	0.38
421.5932312	0.04
424.3714600	0.04
428.3548279	0.22
429.1418152	0.09
432.2765503	0.09
435.3963623	0.06
436.9526062	0.41
442.9697876	0.04
447.1401367	0.43
457.4092102	0.14
460.2342834	8.20
461.2871094	0.60
466.5099487	0.05
468.9081116	0.09
469.6780701	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0458
Annotation	Wharangin
Peak:m/z	Relative Intensity
139.0260620	0.13
151.8545380	0.07
184.1400146	0.15
186.0660553	0.07
189.1935730	0.07
193.2142639	0.19
195.0710602	0.09
195.9222107	0.35
197.1133881	0.11
198.1852875	0.21
201.2298279	0.12
203.0911865	0.06
209.1566772	0.13
211.0434265	0.31
212.0015869	0.80
213.2416382	0.24
217.1020203	0.06
223.0894775	0.11
225.0479126	0.48
228.0373535	0.30
229.0010986	0.14
236.8448181	0.07
237.9362488	0.08
238.8062134	0.38
240.0209045	4.13
241.0878906	0.35
243.8995667	0.22
247.1118469	0.15
252.0581360	2.32
253.0090942	0.51
253.9353638	0.65
255.0814819	13.24
256.1576843	0.62
257.2994995	0.10
263.4310303	0.13
265.9849854	0.19
267.1488953	4.54
269.1165161	1.91
271.0688477	1.13
273.0292969	3.39
275.2807922	0.12
280.7308044	0.70
281.4271851	0.55
284.0924683	14.17
285.1010742	0.42
286.9196167	0.13
293.0076294	0.22
297.0804443	1.67
299.0595703	100.00
300.2053223	2.74
307.1074524	0.62
309.0522461	0.16
310.1218262	0.10
310.9430237	0.14
312.0798950	5.48
313.0693970	19.26
314.0830383	0.51
315.0159302	0.37
324.1265259	1.20
325.3198853	2.05
327.0700378	0.07
328.2133789	7.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	238.0916
Annotation	8-Amino-3,8-dideoxy-D-manno-octulosonate
Peak:m/z	Relative Intensity
70.2418518	0.16
75.0542679	0.08
142.0605011	0.62
144.8810577	0.05
148.8313904	0.49
151.9586792	0.05
172.2400818	0.13
175.0417328	0.09
175.7681427	0.08
181.1949310	0.14
183.8203278	0.56
186.0723572	0.16
192.0147247	2.67
196.1472015	0.06
202.0494080	12.81
203.2080383	0.04
206.5799713	0.15
207.3724365	0.09
208.5574188	0.15
210.0676422	0.42
220.0155182	100.00
220.8853149	20.61
221.5230560	0.09
229.2440033	0.29
237.4792938	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.3727
Annotation	Diosgenin 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
167.3377991	0.18
169.0129242	0.48
197.321991	0.36
199.6896362	0.67
207.1445618	0.62
211.1906891	0.55
219.1442261	0.81
229.1099854	0.87
238.1750336	0.67
253.2694092	4.92
255.3818207	0.60
262.8735352	0.20
269.1428833	0.24
271.2662964	26.48
273.4337158	0.42
283.3233643	0.75
287.1554565	0.33
301.6364136	0.43
327.1914673	0.11
360.8967896	0.11
379.0825806	0.62
380.2124634	0.19
395.4005127	0.23
397.2128906	0.44
399.4093628	0.53
415.3143311	100.00
415.9804077	1.20
421.9099731	0.58
427.5455933	0.15
432.9177856	0.95
433.5530396	0.58
439.4622803	0.33
451.9282227	0.68
469.4907837	1.55
487.1586304	0.47
493.5922241	0.88
504.4658203	0.22
511.5459595	0.41
523.94104	0.38
524.5842285	0.37
531.0345459	0.24
541.4273071	3.35
546.7919922	0.44
549.7711792	0.15
553.7722168	0.19
559.614502	3.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1803
Annotation	Unknow
Peak:m/z	Relative Intensity
231.0018463	0.05
261.1324158	0.09
275.1027832	0.05
284.1647644	0.09
318.0586243	0.12
330.0508423	0.66
340.6358032	0.10
376.3502197	0.07
409.3236694	0.21
421.3007812	0.09
431.0492554	0.04
432.1123047	0.05
444.2570190	0.04
459.4727783	0.46
461.1340942	100.00
462.0825195	1.39
463.0151367	0.82
512.2383423	0.03
537.3488770	0.04
541.3826904	0.10
548.5590210	0.11
555.2926636	0.02
575.4874268	0.07
579.2911987	0.12
582.4302368	0.04
616.5068359	0.49
619.3607788	0.15
621.1858521	0.57
622.3190308	0.24
629.2622070	0.03
647.2119751	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0984
Annotation	Syringic acid beta-glucopyranosyl ester
Peak:m/z	Relative Intensity
122.948494	1.69
138.0947723	2.75
152.8650665	2.49
160.985321	1.02
166.9494934	2.42
178.072937	1.27
179.0785828	0.64
182.0744781	1.83
183.0888214	0.47
189.1515961	0.68
195.1045074	1.11
195.9207764	0.58
197.0418396	100.00
210.9881287	3.23
214.7800903	1.67
220.6901855	1.24
221.9988098	1.10
222.9182434	1.19
224.0595398	2.36
226.9211426	0.34
232.3719177	0.46
236.9908752	0.33
239.0809937	64.18
242.382019	0.68
251.0543823	2.65
262.2284546	0.38
264.0027771	1.09
266.9349365	0.89
269.1807251	2.62
281.2984314	0.75
283.0941772	0.47
299.1973572	10.48
302.7600403	0.75
313.1446838	9.68
315.1734009	1.37
315.906189	1.49
317.0458069	0.59
327.2255554	7.07
339.578064	1.71
341.2388306	1.28
343.144043	0.76
344.1223755	5.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.1459
Annotation	3,7,3',4'-tetramethylquercetin 2'-O-beta-D-glucoside
Peak:m/z	Relative Intensity
160.9381256	0.90
175.0724182	0.80
179.0881805	2.91
192.4720001	0.67
193.0884552	0.14
197.1443634	0.33
206.9877167	0.21
209.1003113	0.15
218.964798	0.09
223.1159363	0.81
267.1270142	0.18
279.3303833	0.26
295.2158203	0.50
311.1303101	1.00
329.2784424	1.09
331.2706299	0.29
341.2374878	0.30
343.2537231	18.01
355.0963745	15.00
355.7381592	0.21
359.1012573	0.22
368.2611084	0.25
373.1008301	100.00
384.1486816	0.56
399.1103516	0.89
415.2391968	0.20
425.8379517	0.25
428.1551514	0.30
436.164917	0.46
437.4078369	0.21
439.2613525	0.27
442.0684204	0.29
443.2021484	0.29
444.2697754	0.13
449.046936	1.50
455.3245239	0.39
459.2319336	1.34
462.9227905	0.14
471.0214844	0.26
473.2931519	0.43
475.3961792	0.10
489.1323853	0.41
490.3426514	0.18
491.3952637	1.56
492.331665	0.23
493.135376	0.36
496.9150391	0.26
497.9277954	0.24
499.1447754	0.58
505.2381592	0.73
507.567688	0.23
512.4605103	0.68
515.4342651	0.59
517.3110962	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.14
Annotation	Oidiolactone E
Peak:m/z	Relative Intensity
96.74081421	0.42
111.0180664	0.86
121.0706024	0.39
130.9749756	0.41
135.0092621	3.42
143.283844	0.19
152.9655609	0.32
163.0731354	0.28
175.3990173	0.22
197.1750793	1.07
219.1724854	0.22
221.0283813	0.93
221.8685608	0.60
223.3155823	0.60
225.253479	0.26
233.1062317	0.28
235.0374756	0.88
237.0213623	0.47
247.2131958	0.63
249.1576538	100.00
250.2149048	0.29
253.2790527	1.52
256.9428711	0.39
257.6868591	0.49
265.0009766	0.20
272.960022	0.35
275.1034546	8.20
276.2192993	0.52
277.2987671	0.22
278.9194641	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1984100	0.32
207.5779419	0.06
210.8236389	0.47
212.7893677	100.00
239.3096313	0.25
251.0454712	2.05
282.2935181	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	410.2199
Annotation	Unknow
Peak:m/z	Relative Intensity
122.7957230	0.08
183.3508911	0.14
202.9449463	0.05
227.0821075	0.07
230.0493774	0.11
237.3137207	0.09
241.1667480	0.16
255.9795227	0.06
262.4151611	0.12
276.8047485	0.05
351.0725098	0.15
364.0337524	0.14
374.5674744	0.53
375.2107239	0.71
379.1095276	0.05
383.3023682	0.17
393.1954651	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	871.1292
Annotation	Unknow
Peak:m/z	Relative Intensity
526.4805908	0.89
672.3872681	1.13
743.5170898	0.71
785.2604370	31.45
786.1643677	4.84
787.2297974	0.62
806.9011841	0.23
844.6372681	1.14
891.3520508	1.13
912.4337769	0.93
950.1671753	0.34
1025.0714110	0.59
1025.7075200	1.34
1027.6019290	1.48
1043.4841310	12.49
1044.7342530	1.83
1045.6052250	1.31
1471.8457030	1.88
1473.6453860	0.68
1575.1114500	0.25
1620.4064940	0.21
1730.5916750	0.23
1782.1966550	1.19
1784.5357670	0.25
1786.2530520	0.38
1788.6553960	0.77
1790.4078370	13.43
1808.9699710	0.30
1813.1890870	0.54
1830.5885010	0.60
1844.6873780	0.96
1861.4586180	0.45
1863.3884280	25.99
1867.1329350	3.13
1869.1379390	0.23
1869.8382570	0.39
1876.9180910	0.97
1878.3059080	0.23
1884.1197510	0.78
1891.1452640	43.32
1892.2640380	0.51
1894.0133060	0.46
1894.6652830	7.04
1895.4759520	0.42
1915.6795650	0.37
1922.2225340	0.17
1923.7629390	1.04
1936.4792480	0.33
1937.8489990	0.25
1950.1398930	0.29
1950.8498540	5.83
1961.1849370	1.17
1963.2702640	2.98
1964.5310060	1.55
1967.6228030	0.41
1969.9498290	8.70
1971.6082760	2.01
1972.8580320	19.16
1974.0469970	0.38
1976.5378420	0.39
1977.9093020	2.05
1980.0377200	28.25
1984.4029540	0.36
1986.9118650	0.57
1987.8153080	57.35
1988.4896240	1.93
1990.8840330	10.94
1991.6086430	5.86
1992.3031010	5.59
1993.2176510	0.91
1994.3853760	1.49
1994.9890140	1.72
1995.7779540	4.69
1997.2935790	100.00
1998.1236570	1.97
1998.8643800	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0477
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
169.1308594	0.06
211.0128479	3.21
216.8547974	0.14
233.0737305	0.03
241.0234375	1.15
273.0552368	0.07
280.0947876	0.80
305.0399780	0.06
310.6034241	0.06
321.0606689	0.32
323.0591431	100.00
327.1092529	0.02
385.0526733	1.91
389.7573242	0.03
390.9118042	7.96
397.1201782	0.06
403.0861206	3.15
412.9565430	0.07
424.9522095	0.03
428.8845215	9.29
429.8648071	0.39
467.1296997	0.49
478.8841553	0.52
480.8643188	2.70
482.2022095	0.02
496.8283081	0.27
518.8591919	0.05
547.0335083	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2919
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
137.2700348	0.08
154.9621277	0.06
156.6939392	0.04
165.4065857	0.05
167.0893250	0.11
173.1820221	0.08
175.5048828	0.07
197.2344055	0.07
203.2998657	0.08
216.1627197	0.26
225.7303009	0.06
228.8678589	0.13
237.2756500	0.06
243.3005981	0.04
245.3581848	0.67
263.3089600	2.78
274.0160828	0.08
292.9766235	0.15
306.4891968	1.32
310.0871582	0.07
313.0048523	0.19
314.0323792	0.17
319.6561279	0.03
321.2253418	0.03
327.4371948	0.10
333.0781860	0.07
335.3605957	0.14
337.3267822	53.04
338.0073242	0.10
340.2589111	0.02
347.3101196	0.23
353.3808594	0.13
361.3153687	0.14
376.3506470	0.08
380.4164124	0.13
387.0931091	0.09
389.3421936	0.04
391.4113464	0.05
397.3543396	0.33
410.3913269	0.05
417.0775452	5.67
418.4125061	0.16
425.8555908	0.03
427.3514099	0.12
428.7788086	0.22
431.1484070	0.05
434.5691833	0.07
435.3797302	0.06
442.2649231	0.51
442.8859558	0.04
446.1754456	0.07
447.3594971	0.14
449.2806091	0.07
460.1917114	100.00
461.1494141	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.1909
Annotation	Unknow
Peak:m/z	Relative Intensity
181.7154541	0.08
194.8636017	0.30
200.9877472	0.26
245.7601318	0.22
249.1763611	3.10
256.1165771	0.10
270.4332581	0.20
281.0169983	0.09
283.0970154	0.11
296.0811157	0.18
297.3689880	0.71
298.4098206	0.12
299.6968384	0.52
302.9735718	0.65
311.4237366	0.36
313.7610779	0.36
314.9039307	1.19
320.4434509	2.56
321.0724182	9.34
324.1965027	0.59
325.7992249	0.29
339.0160522	100.00
339.7418213	0.30
368.5894470	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.3694
Annotation	Unknow
Peak:m/z	Relative Intensity
284.2232666	0.17
323.2246704	0.14
372.6187134	0.11
431.4324951	0.06
449.5903320	0.06
450.4581909	0.20
491.4649048	0.41
492.2182617	0.18
517.9503174	0.07
593.8233032	0.42
594.5907593	0.81
611.4094849	82.93
612.4326172	100.00
613.0961304	0.35
625.0335083	0.12
644.4416504	0.15
653.3888550	23.43
654.3972778	30.54
655.0250244	0.60
660.4159546	0.11
665.9922485	0.07
678.4427490	0.05
683.8461304	0.04
693.4114990	5.73
694.4783936	5.91
696.5115356	0.16
704.8576660	0.16
737.1902466	0.37
738.5812378	0.08
756.8101196	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1827
Annotation	Chrysosplenol C 6,4'-diglucoside
Peak:m/z	Relative Intensity
197.1282654	0.01
222.9562378	0.05
291.8896179	0.01
301.0012817	0.04
307.1122437	0.05
318.2764587	0.04
323.0765991	0.03
341.2496338	0.23
341.8735962	0.02
359.1783447	8.24
361.3782349	0.08
368.9421997	0.03
371.1986084	0.05
383.6255493	0.06
401.0689087	0.03
432.4160767	0.01
482.5735474	0.06
503.197876	0.19
508.4057007	0.01
519.3168945	0.03
521.138855	100.00
521.7599487	0.21
538.1051636	0.02
563.4078369	0.02
592.2022705	0.04
594.0341187	0.03
595.5609741	0.02
597.2893677	0.03
599.1120605	0.04
624.4397583	0.03
634.6038818	0.04
636.0949097	0.01
637.5067749	0.09
638.2644653	0.03
639.1638184	0.02
655.7971802	0.03
659.5196533	0.14
662.5010986	0.02
664.5557251	0.08
665.1987915	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.018
Annotation	Unknow
Peak:m/z	Relative Intensity
153.7655182	0.10
203.1642456	0.64
212.9845581	0.44
232.8965454	0.07
257.0113525	0.99
261.9210815	0.42
274.9291382	2.66
278.8721008	0.31
285.0623779	0.20
290.9417419	0.39
293.4361877	0.27
302.9427795	0.36
309.4570923	0.17
310.2185974	0.19
316.0280151	0.18
319.0103455	9.34
319.6613159	0.23
329.1489563	0.79
336.8999023	0.06
345.2018127	0.74
347.0895691	8.34
349.0105896	0.13
363.0290833	4.83
372.0975647	0.10
373.1959229	1.49
379.0587158	0.28
380.4268494	0.12
390.9978638	100.00
391.5989990	0.45
400.6181946	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	495.2952
Annotation	Herkesterone
Peak:m/z	Relative Intensity
146.9675140	1.82
147.9970551	0.49
155.1617126	0.50
203.3359985	1.99
204.1549530	19.73
205.1123657	2.69
221.1701965	0.09
257.4121094	0.23
264.1845093	0.17
275.1903381	100.00
276.2782288	28.11
278.6526184	0.10
292.2612000	1.31
293.3084106	0.13
300.1899414	0.15
320.2692871	0.07
321.2008057	0.18
330.4013977	0.25
366.2082214	0.21
367.1445312	0.56
367.7673950	0.09
370.9703979	0.09
376.2936707	0.22
385.1468811	0.08
410.8285217	0.09
451.1006165	0.09
455.0975647	0.07
458.3984070	0.21
459.8098450	0.30
460.4847717	0.10
463.6942749	0.55
468.0506287	0.21
477.3832092	34.48
478.4051819	22.80
479.3018494	0.58
484.7394104	0.10
486.5773010	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2502
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.3471527	0.68
108.9617462	0.65
120.8600159	0.32
123.0315323	0.80
129.0679626	0.27
134.8621979	0.60
144.7571716	0.47
146.9958649	0.94
148.8775635	0.29
155.1354675	0.27
156.9722595	0.72
158.9147034	0.27
168.9405823	0.79
173.0783386	1.35
177.4667511	1.39
181.1443329	0.32
182.6734161	0.74
187.2558136	1.80
196.9008179	0.29
199.0368652	0.40
205.1804047	0.97
211.1802979	2.56
223.7254639	1.08
225.1535645	1.12
241.3455505	0.25
245.0831909	0.75
247.2402039	5.07
253.0648804	0.97
257.1597595	1.57
271.1077576	0.18
278.8861694	0.20
281.4856567	0.38
283.0089111	1.04
287.3635864	0.61
295.7475891	1.10
299.1455078	1.78
300.2130127	0.86
305.223877	3.52
313.6203613	0.27
323.2432251	100.00
323.8540039	0.64
341.3096924	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.0877
Annotation	Tuliposide B
Peak:m/z	Relative Intensity
85.02890015	2.18
89.00561523	6.28
100.8724976	6.65
107.0298615	1.06
109.0367584	0.83
113.0144577	9.82
118.8446732	6.74
125.0526505	5.78
128.1292114	0.31
129.2565918	0.54
131.0362244	100.00
142.9830627	1.81
148.9484253	20.18
160.7791443	0.65
163.1351166	0.40
166.9118958	1.95
172.9587402	3.86
175.0231171	0.27
178.8812256	0.92
180.2066956	1.92
185.177124	1.20
191.0201874	9.00
198.9212646	0.25
201.9318848	0.31
203.0440369	7.22
205.3444824	0.45
207.202179	0.41
213.4413757	0.32
214.9548645	0.45
216.1680603	0.94
221.265625	2.35
222.7761536	0.43
228.7920227	0.57
231.4698792	0.56
233.0415039	2.28
234.3074951	0.40
245.0905151	0.69
247.1759033	4.58
248.9561157	1.79
255.3292236	0.91
257.2473145	1.36
257.9066467	0.45
263.3349304	1.37
265.1286621	0.34
274.2028198	0.79
275.1016235	6.78
277.3216858	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
96.99052429	0.25
99.0221405	0.34
109.2708664	0.55
113.0308533	0.19
114.9003754	0.21
119.2563477	0.53
121.1445312	2.00
123.0095825	2.65
134.9514465	0.36
137.3001099	0.67
138.9090424	1.74
141.2136841	1.31
144.9494629	1.40
147.1600647	1.30
148.8233948	0.27
153.1003723	0.84
154.8970032	2.70
156.2443237	0.55
156.9734497	0.29
161.2526093	1.37
163.4954834	0.23
165.3224487	1.21
168.9675598	2.24
171.1062622	1.29
173.1616211	0.32
175.1489563	1.31
177.0865784	0.29
178.8544006	1.44
181.0555573	0.61
182.957489	2.43
185.0461121	0.69
187.1624603	1.15
188.1587372	0.46
189.2112274	0.19
195.1775208	1.31
197.0837097	6.76
199.0697327	0.74
201.1601562	0.93
203.0766602	0.82
206.0184631	0.23
207.1058044	0.90
209.1443787	3.04
211.1610718	1.56
213.3091736	1.20
214.5513	0.48
219.278717	2.61
221.1936035	3.97
222.006073	0.31
223.2104797	0.79
225.116272	0.36
227.2414246	0.93
230.3686218	0.91
233.1608887	0.89
237.253479	8.37
239.1882324	18.10
243.2491455	2.62
251.2833252	5.13
252.9468994	1.14
255.1741943	2.19
256.9446716	0.57
261.2821045	7.72
267.2197876	0.76
269.0717163	1.15
271.026886	1.44
279.2277832	100.00
280.2668457	0.36
291.5286255	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1752
Annotation	Genistein 4',7-di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
255.0504456	0.89
313.2023926	1.58
381.2699585	3.04
382.2281494	3.75
399.2496948	3.74
401.4559326	0.27
417.1228638	100.00
418.2005615	68.20
448.1150513	0.57
469.3549805	0.97
472.6554565	0.98
486.3724365	0.78
501.2421265	4.12
509.5727539	0.43
527.2555542	0.63
529.0409546	1.16
545.2045288	0.97
555.3476562	3.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	338.088
Annotation	6-hydroxyindole-3-carboxylic acd 6-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
96.7655640	0.13
99.0589905	0.06
110.9458160	0.15
116.1280441	0.09
120.1277008	0.08
122.8496246	0.08
129.1170502	0.05
142.1433411	0.06
143.9126434	0.05
146.1296082	0.55
147.9820862	0.55
151.8564148	0.09
160.0432129	0.03
163.2645569	0.04
167.2080994	0.23
174.0348816	0.70
175.9482117	100.00
183.0370331	0.07
184.0353394	0.05
186.0147095	0.83
188.0817871	1.71
188.9650269	0.25
198.0480042	0.14
199.6039429	0.04
202.1272583	0.14
207.1504517	0.95
210.8440857	0.04
218.2518921	0.04
224.3809509	0.05
228.1085205	0.11
230.2583618	0.13
230.9730530	0.08
232.2471619	0.05
239.2353210	0.04
244.9361267	0.10
246.1307983	0.05
247.1064148	0.11
255.5072632	0.08
264.1361694	0.08
267.9584351	0.09
277.2413940	0.06
278.1402283	0.05
279.1026306	0.15
293.0545654	0.54
294.1628113	0.42
295.1792603	0.06
301.2882080	0.04
302.0353394	0.16
310.2651978	0.06
318.1411133	0.11
319.6353455	0.23
320.2923584	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.1724
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
199.9672089	0.11
262.6779175	0.06
291.0965881	0.08
325.1156616	0.25
363.1499634	6.69
412.5106201	0.14
424.8243408	0.11
430.3276978	0.05
434.9761353	0.05
472.4788208	0.06
474.7629395	0.14
488.6181641	0.18
495.1951904	0.07
515.2123413	0.63
516.2631226	0.03
520.4479980	0.06
525.2080078	100.00
526.1633911	0.99
543.3855591	0.17
610.4285278	0.05
625.2317505	0.04
642.3068237	0.04
643.9107056	0.04
668.2051392	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1139.5156
Annotation	Unknow
Peak:m/z	Relative Intensity
501.6239624	0.17
744.0862427	0.19
1583.9045410	0.13
1639.5030520	0.12
1671.6119380	2.81
1691.8004150	1.58
1699.3834230	0.23
1716.9351810	0.14
1723.9715580	0.07
1738.5041500	0.39
1771.9676510	0.12
1776.5134280	0.15
1781.7531740	0.53
1783.4039310	0.49
1788.1209720	4.00
1794.1453860	3.78
1797.8458250	0.36
1812.1978760	0.18
1817.5676270	0.25
1821.3439940	1.44
1827.5535890	0.08
1828.7897950	1.29
1831.9617920	0.09
1833.3448490	1.22
1836.2874760	1.92
1837.7961430	0.10
1841.1937260	21.34
1848.1486820	0.20
1849.6517330	0.13
1854.7810060	0.35
1858.8973390	0.64
1861.9454350	0.11
1863.4508060	0.20
1868.4318850	6.03
1870.8319090	2.12
1876.5035400	0.24
1877.1800540	0.18
1885.4177250	0.37
1890.2296140	0.36
1890.8751220	0.25
1891.5484620	0.50
1893.6667480	0.17
1894.7698970	1.66
1901.8220210	1.20
1903.1859130	9.93
1905.2860110	5.01
1910.2198490	3.28
1912.1853030	0.93
1915.1395260	0.25
1915.9273680	0.80
1918.2113040	2.23
1919.3878170	4.34
1922.6541750	0.83
1924.6292720	1.29
1926.2014160	0.46
1929.1439210	0.52
1930.0295410	38.50
1931.9173580	0.21
1933.9493410	0.16
1934.7840580	0.99
1938.5506590	0.19
1939.4195560	24.61
1940.0789790	0.79
1940.8870850	1.39
1942.1719970	1.62
1947.3532710	0.09
1948.1983640	6.28
1950.7733150	0.13
1951.8834230	2.36
1955.7066650	1.03
1956.5847170	0.12
1958.7933350	0.90
1959.9855960	1.01
1962.9255370	3.88
1964.4152830	2.15
1965.6639400	7.62
1966.6859130	0.45
1969.9914550	0.17
1970.7736820	0.84
1972.2581790	0.46
1975.3634030	2.60
1976.6156010	7.21
1977.2497560	0.15
1979.0540770	0.55
1980.9602050	0.15
1981.8977050	5.32
1983.7702640	16.28
1984.7479250	2.88
1987.8968510	7.94
1988.5855710	2.84
1989.5089110	3.89
1990.7336430	0.32
1992.9138180	1.74
1993.9913330	100.00
1994.8640140	0.17
1996.1878660	27.27
1997.5550540	2.41
1999.7415770	2.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1348
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
162.0677185	0.13
167.0896606	0.11
175.0272522	0.06
176.3196716	0.09
177.2276611	0.30
179.0469208	0.05
186.2513123	0.12
187.2360992	0.04
201.0733337	0.05
201.9813232	0.21
203.1925659	0.12
205.0348511	0.12
221.1169586	0.15
221.9656372	0.06
229.1886139	0.34
231.0803223	0.07
243.2474670	0.04
245.0094910	3.71
245.8277740	0.09
255.2001801	0.32
255.9128723	0.07
257.1618347	0.14
260.2409668	0.08
267.1416016	0.04
268.9873352	0.31
273.0916138	2.40
274.1010132	0.05
275.0814209	0.09
281.5023804	0.09
282.1096802	0.10
287.2095947	8.25
289.0895386	24.76
290.1453247	4.04
291.1025391	0.33
299.0588379	7.45
300.1768494	0.60
305.3842163	0.11
306.2777100	0.05
329.1821899	1.24
331.1241455	1.28
332.3431396	0.24
339.3533325	0.11
341.1512451	0.27
358.1570435	0.05
365.4710083	0.08
381.3614502	1.24
382.2819214	0.40
383.0911255	0.12
389.2429199	0.05
407.1331787	54.30
408.2616577	15.55
409.3523560	0.36
410.0427246	0.28
411.0724487	0.11
413.0609131	0.06
416.2443848	0.26
422.9660645	0.10
425.1384277	100.00
426.1461792	25.28
426.8462524	0.12
431.7554932	0.07
433.0082397	0.20
434.6135254	0.09
437.2506714	0.15
447.2229004	0.07
449.1298828	1.07
451.1727295	36.78
452.2755737	6.91
457.3363647	0.16
459.3891602	0.15
461.6260986	0.12
467.1871948	0.99
468.1471558	0.41
476.5004883	0.26
481.4303589	0.21
484.3015137	0.14
487.4041138	0.10
489.3962402	0.05
490.2976074	0.27
491.2136841	0.09
492.4362793	0.07
493.1456909	0.17
494.4525146	0.34
497.4066162	0.05
498.1784058	0.15
501.1845093	0.31
502.9319458	0.10
509.5488892	0.11
515.4487915	0.34
518.2786255	0.07
532.1416626	0.78
533.3344727	1.22
534.2815552	0.70
535.0015869	0.13
540.0991211	0.19
541.1776733	0.18
542.0671387	0.18
559.1769409	13.37
560.2233276	3.37
568.0332031	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	151.04
Annotation	Unknow
Peak:m/z	Relative Intensity
109.8630219	100.00
110.7058411	0.06
127.8519745	8.23
130.3287506	4.42
132.1698761	0.03
139.2805328	1.15
145.7269440	0.02
147.7421417	0.05
151.0012512	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	535.1432
Annotation	6,8-Di-C-alpha-L-arabinopyranosylapigenin
Peak:m/z	Relative Intensity
171.1422272	0.09
225.2572632	0.09
264.9546509	0.05
275.3082275	0.06
279.2740173	0.03
299.2809448	0.03
301.7649841	0.03
313.1174316	0.10
324.2907715	0.03
349.3331909	0.12
355.1228638	0.25
373.4171143	0.04
379.1069336	0.30
384.9800415	0.34
385.6727295	0.05
388.8662109	0.03
391.1688843	0.04
397.1776123	1.63
403.3416138	0.13
409.1727905	1.72
410.953064	0.05
415.2497559	1.97
427.1325073	5.19
433.1867676	0.38
443.4472046	0.13
445.2731934	6.94
451.2858887	3.10
454.6521606	0.16
455.512146	0.09
456.5352783	0.10
462.901062	0.04
469.1115112	25.38
469.7879639	0.10
471.0351562	0.07
475.3197632	0.03
481.2550659	17.39
499.2589111	81.45
503.3654175	0.06
506.0010376	0.13
511.829895	0.03
517.1362915	100.00
518.1810913	0.18
520.045105	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	477.1609
Annotation	Benzyl gentiobioside
Peak:m/z	Relative Intensity
271.1284485	0.06
281.2886047	0.02
299.1658630	0.05
315.0807495	0.05
335.4769897	0.04
431.1906433	100.00
434.3978577	0.07
441.3145447	0.09
446.0055237	0.04
457.5354919	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
90.7662048	0.06
122.8706665	100.00
209.9772186	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	780.3693
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0395355	0.14
220.2928925	0.16
221.0646515	0.16
221.9591675	0.13
229.2756958	0.34
230.6787415	0.22
233.2115479	0.10
234.1704559	0.15
235.2454224	0.18
237.2364807	0.63
239.3481445	0.12
243.1953125	0.24
245.3680878	0.18
246.0198975	0.08
247.2876740	0.85
248.0687866	0.19
249.2030334	0.13
261.2268066	0.78
263.3217773	0.65
265.1533203	1.55
273.3073730	0.26
275.1650696	0.32
276.3383179	0.09
277.0779419	0.53
288.5311890	0.30
289.3032227	0.54
290.6318970	0.10
291.4147949	0.80
295.3579102	1.57
297.1256409	0.73
299.2658691	0.44
301.1267090	0.52
305.1005249	0.82
307.1088257	0.14
308.2364502	1.33
309.3357849	0.78
311.4348755	0.37
313.3603210	0.44
315.2751465	0.17
316.2693481	0.37
317.5158081	0.30
319.2449341	0.19
323.0739441	1.28
325.3730469	0.37
327.5742798	0.10
331.4109497	0.58
335.5910034	0.23
337.1459961	0.31
339.1658936	1.22
341.0493164	0.89
343.3323364	0.26
345.4831543	1.31
346.2781372	0.15
349.3126831	0.18
351.2703247	0.64
355.2812500	0.15
357.1717834	0.22
359.2637634	0.45
361.5784302	0.38
363.4080200	1.05
365.2783813	0.29
368.2655029	0.08
373.3256836	4.65
375.2406006	2.33
377.0056763	0.45
379.3364868	0.12
381.3829346	1.21
383.4726562	0.28
389.7692261	0.27
391.3754272	1.29
393.4066772	2.71
399.3663330	0.60
401.3685913	5.15
405.2737427	0.53
409.2969971	1.54
411.4472046	3.40
415.1570435	0.62
417.1541138	0.26
419.4012451	9.79
423.2011108	0.33
426.3706055	0.17
427.1489868	0.22
431.4730225	0.18
433.4432983	0.25
434.0581055	0.14
435.4606323	0.43
436.1410522	0.17
437.3269653	5.71
439.4629517	0.17
443.1337891	0.29
451.1701050	0.96
455.2954102	3.98
456.0501099	0.15
457.1866455	0.44
459.0406494	0.38
464.2787476	0.31
466.4760742	0.60
467.4612427	0.16
469.4790649	1.37
471.3837280	0.34
473.1834106	3.03
476.6699219	0.90
477.4645996	0.25
478.3956299	0.98
486.7851562	1.28
487.4857178	0.72
494.5188599	0.27
495.5523682	0.13
500.3344727	0.16
504.5527344	0.28
505.2330322	0.18
507.3140869	0.33
512.4882202	1.30
513.1849365	0.30
519.3658447	0.09
522.0163574	0.47
524.3107910	1.20
530.3539429	4.76
531.2241821	0.34
534.3865356	0.57
535.4210205	1.08
536.3730469	0.54
540.4935303	0.22
541.4102173	0.57
542.2933960	0.23
548.2353516	9.99
553.3579712	0.66
554.1105347	0.16
561.6868286	0.29
562.4225464	0.49
571.1817627	0.35
572.6763916	0.40
576.3186646	0.08
579.2823486	1.16
580.3157349	0.56
588.8726807	0.37
590.1499023	0.51
594.4645996	0.15
596.4331665	1.04
597.4666138	8.65
598.4651489	0.92
613.9155884	0.27
615.4201660	19.16
616.4025269	0.93
624.5453491	0.12
633.3751831	100.00
634.0013428	0.24
651.3857422	46.95
669.5641479	0.61
687.5243530	2.99
699.4780273	0.29
703.4573975	0.32
705.4891357	16.23
716.4735107	0.65
717.5954590	0.47
744.5741577	1.62
760.0514526	0.15
762.4317627	35.29
763.3732300	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.124
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9797287	0.92
86.9020386	0.13
88.9488983	4.45
97.1755981	0.05
98.8560944	0.19
100.9121017	3.70
102.9612350	0.07
112.9564590	6.50
115.0601654	0.84
118.1575546	0.07
118.9409866	4.73
124.8843307	0.08
127.0364075	1.33
128.8909149	0.69
130.9654999	100.00
134.9660339	0.96
136.9331665	0.05
138.2553406	0.13
140.8916321	0.25
142.9139404	2.87
143.5277405	0.09
144.9104309	0.82
149.0122986	0.50
160.9816589	1.09
167.0273438	0.20
173.0006409	7.36
175.3954620	0.22
177.0904694	1.32
179.0076294	2.23
184.9556732	0.94
186.8457489	0.15
197.2608948	0.11
203.1224670	0.62
205.1901245	0.14
215.1704712	0.08
217.1782227	0.36
231.1052856	0.54
233.0541382	0.56
235.0182190	1.63
247.0784607	0.35
249.0111084	0.79
251.2591553	0.06
275.1914062	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.3279
Annotation	Unknow
Peak:m/z	Relative Intensity
211.5921631	0.03
233.1504211	0.04
239.3844299	0.02
241.4168854	0.03
253.1114197	0.03
255.4091797	0.01
267.4520569	0.02
269.3225708	0.46
271.5094910	0.15
283.6458130	0.08
285.3818359	0.10
287.3352661	0.93
294.2356567	0.08
295.5077209	0.03
297.4867554	0.07
301.3486328	0.05
302.2976379	0.01
305.4078064	0.04
309.1691895	0.02
311.5449829	0.10
313.2658691	0.03
326.5933838	0.02
327.5347290	0.01
329.4530029	0.05
339.4547119	0.01
341.3272095	0.05
349.2442627	0.03
365.3878174	0.01
367.1809082	0.02
371.1253052	0.10
375.1828613	0.03
383.5502319	0.01
384.9957886	0.05
385.7089233	0.05
395.6165161	0.02
401.4263916	0.13
403.3792725	0.49
405.5861816	0.09
409.6630859	0.06
413.4182129	0.10
415.2889404	0.16
427.3967896	0.06
431.3828125	25.08
432.4529419	0.63
433.4288330	1.39
434.2056885	0.02
445.3966064	1.98
446.2855835	0.01
447.5509033	0.03
449.3707886	100.00
450.3090820	2.27
455.5863037	0.05
457.3538818	1.41
459.6380005	0.01
471.5061035	0.02
473.3809204	0.30
475.3854370	0.26
481.6406250	0.02
483.5880737	0.03
485.5476074	0.10
491.3777466	2.15
492.1063232	0.07
495.3822632	0.06
499.6458130	0.01
501.6306152	0.04
503.3984985	4.74
504.5537109	0.05
515.3126831	0.02
517.4312134	0.02
521.2217407	0.08
522.4863892	0.03
523.3903198	0.01
527.1633301	0.06
529.1780396	0.02
530.4761353	0.01
531.3079224	0.04
533.3380737	0.04
536.1447754	0.02
551.3595581	0.05
557.5872803	0.03
558.2096558	0.01
565.0824585	0.17
566.0647583	0.02
567.3624878	0.14
571.8397827	0.09
573.3541870	0.01
575.0258179	0.07
593.3847656	11.07
594.3942261	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	948.44
Annotation	Unknow
Peak:m/z	Relative Intensity
450.2828979	0.09
503.5208740	0.10
579.0863647	0.09
584.5999756	0.02
632.4251099	0.03
721.9831543	0.17
730.1515503	0.45
757.7280273	0.17
779.2548218	0.03
801.9432983	0.37
849.2782593	0.05
880.1351318	0.38
894.4052124	0.33
901.1503906	0.33
921.6254272	0.18
926.0157471	4.89
926.8239136	0.06
927.9168091	0.12
932.5903320	0.08
1018.1982420	0.06
1037.4079590	0.18
1063.7143550	0.09
1094.6784670	0.33
1108.9034420	0.07
1122.7272950	0.27
1134.1926270	0.07
1192.1008300	0.11
1201.3343510	0.09
1201.9536130	0.07
1280.5162350	0.04
1303.1801760	0.14
1313.4532470	0.04
1328.3587650	0.05
1330.3474120	0.05
1513.9832760	0.28
1558.1719970	0.03
1603.0075680	0.19
1608.8507080	0.04
1634.4219970	0.02
1663.7434080	0.04
1666.9425050	0.16
1677.6419680	0.06
1693.6927490	0.03
1702.3555910	0.06
1735.7127690	0.11
1746.8635250	0.09
1749.7346190	0.33
1765.2102050	0.05
1775.3861080	0.04
1780.4381100	0.63
1782.1931150	0.06
1784.1324460	0.06
1792.7562260	0.58
1799.9558110	0.05
1811.8361820	0.69
1812.4971920	4.17
1816.7728270	0.02
1820.4041750	0.11
1838.9312740	0.05
1846.5599370	0.02
1849.2106930	0.16
1855.3699950	0.02
1856.4761960	0.13
1858.4591060	0.03
1873.2086180	0.17
1875.6223140	0.11
1877.6075440	0.03
1880.4876710	0.07
1886.9304200	0.08
1887.6046140	0.22
1888.9284670	0.27
1891.0528560	2.35
1893.0471190	0.37
1893.8249510	0.05
1894.9211430	0.07
1898.2331540	1.16
1899.2409670	0.80
1901.2603760	0.38
1903.1265870	0.11
1904.4649660	0.14
1910.1447750	0.10
1911.2296140	0.13
1913.4093020	0.65
1915.7386470	0.16
1918.7591550	0.07
1920.6492920	0.93
1923.7722170	0.14
1924.3758540	0.39
1933.4176030	0.09
1934.6439210	0.22
1935.5640870	0.12
1938.2395020	0.45
1940.1486820	0.02
1941.2862550	2.51
1942.0264890	0.04
1944.8787840	0.96
1948.5777590	0.24
1951.6727290	0.09
1953.2471920	2.46
1954.7271730	0.14
1955.6307370	0.77
1959.5101320	0.89
1960.9813230	0.33
1962.0728760	0.06
1965.7033690	0.22
1967.3103030	3.31
1971.6335450	0.67
1972.3909910	1.18
1973.8934330	3.30
1975.3435060	0.54
1976.4752200	0.02
1978.7852780	100.00
1982.0052490	0.15
1983.2268070	2.03
1984.7966310	4.65
1985.6267090	0.03
1986.8861080	2.08
1988.1356200	0.05
1989.1842040	0.24
1990.1179200	1.97
1991.2741700	0.14
1992.8721920	5.80
1995.1057130	0.03
1996.6477050	0.08
1998.3604740	5.04
1999.1805420	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1087
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
137.1129608	0.01
148.9302063	0.03
151.1190948	0.02
151.9610291	0.04
156.2959900	0.02
162.9644775	0.07
164.1372986	0.04
176.0503235	0.05
176.6990051	0.02
177.3039398	0.01
178.9795837	0.42
179.9840698	0.07
181.2340698	0.02
191.0250854	0.07
192.4842377	0.04
198.0487366	0.02
199.3328705	0.03
201.0851135	0.13
202.0485229	0.04
205.1251068	0.04
207.3368530	0.01
212.9672241	0.02
215.0797119	0.08
220.1119080	0.01
221.0917816	0.02
222.7442322	0.02
224.9021301	0.18
225.7816925	0.05
235.1575623	0.02
241.0333862	0.01
243.2160950	1.15
244.1906738	0.25
251.1772461	0.10
259.1272888	28.15
260.2141724	4.83
265.0471191	0.08
267.3446045	0.07
269.1054077	33.24
270.1295166	4.92
271.1623535	0.02
281.1068115	0.04
283.1001587	0.20
287.1167297	100.00
288.1965332	12.73
293.1111450	0.19
294.2800293	0.03
297.2223511	0.02
311.1697388	1.59
312.2530823	0.36
313.9287720	0.03
315.4774780	0.02
323.4735413	0.02
325.6536865	0.10
329.1035767	0.14
330.3281860	0.03
333.4265137	0.02
335.9179077	0.04
342.0463257	1.03
343.2153320	0.08
345.0880127	0.05
346.6485901	0.01
349.2277527	0.04
353.5087891	0.06
354.2066956	0.04
357.4356689	0.02
370.3897400	0.01
371.0915833	0.04
373.1909180	0.38
373.9831543	0.01
375.1030579	0.24
389.0766907	0.08
395.1240845	0.01
403.3240662	0.32
404.2515869	0.11
405.1900940	0.04
406.2276917	0.08
413.0281677	0.05
414.0343018	0.19
419.4521790	0.05
421.2202759	1.71
422.3950195	0.20
423.3132324	0.05
431.1527405	6.35
432.2678833	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	586.91
Annotation	Unknow
Peak:m/z	Relative Intensity
272.7483521	0.22
387.1918335	1.45
427.0417480	9.43
428.0331421	1.10
429.0741577	0.68
430.8808594	0.28
473.0813599	3.22
485.1315918	0.44
490.9519043	0.48
500.8609009	0.37
513.9428101	0.71
540.9480591	100.00
569.2694702	1.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0223846	0.67
108.9281158	0.51
115.1763916	0.51
121.1015778	1.22
123.0024567	1.08
132.8540344	0.14
135.0030518	2.06
143.1562805	1.49
147.0578766	2.28
148.9886475	1.68
151.2887115	0.23
157.1080017	1.96
159.0187225	1.02
161.1621399	1.44
162.1636047	0.18
163.1566772	0.81
171.0286255	0.54
173.0370178	1.56
174.95578	0.22
177.3480225	2.55
187.2754059	1.97
188.9865265	2.01
196.5594482	0.30
197.2205658	0.90
199.0509033	0.21
201.2816467	0.98
202.0776672	0.19
203.183609	0.74
205.2102661	1.50
209.1288757	0.26
211.0475159	1.60
214.9590149	0.25
216.8431396	0.44
227.1401367	0.52
229.1131897	0.82
231.2047119	0.42
245.0400696	0.86
247.3139648	3.76
253.4479065	0.61
256.9702454	0.85
259.3607483	0.54
266.9227295	0.32
270.861084	1.26
281.5020752	0.63
284.3242493	0.61
285.216095	2.03
287.3065186	1.38
295.4416504	0.96
297.9707642	0.65
299.3592224	1.44
305.404541	2.08
313.1072388	0.63
317.7935791	0.51
323.2460022	100.00
324.1287231	1.23
341.0498962	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.028
Annotation	SC-58125
Peak:m/z	Relative Intensity
128.8158417	0.38
130.8358612	0.12
160.9134064	0.09
169.0047913	0.29
172.9649353	2.45
188.9798889	0.11
190.9823608	100.00
191.9849548	0.30
196.9665833	4.39
212.9474945	1.20
232.8351440	0.06
239.1177063	0.11
240.8750610	0.23
242.0566711	0.05
257.0266724	2.16
258.0958252	0.20
263.3333130	0.07
271.0014343	0.04
273.0675354	0.33
275.0617981	0.05
276.3524780	0.07
283.0731506	3.69
293.1930542	0.04
300.0509033	0.11
301.0694275	13.33
306.0431213	0.52
330.9849854	0.26
332.9524536	0.11
342.9891968	0.97
345.2038879	0.19
351.0530090	0.18
360.8280029	0.43
362.5172119	0.18
367.9689026	0.15
369.1182556	2.02
387.0660706	23.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	136.99
Annotation	Unknow
Peak:m/z	Relative Intensity
64.8843689	0.05
72.8746872	100.00
73.5830994	0.10
74.9731140	0.11
80.8521652	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.1809
Annotation	2-hydroxytridecanoic acid
Peak:m/z	Relative Intensity
98.78752136	0.34
159.0946655	0.17
183.4239044	0.31
185.1961212	100.00
186.4253845	0.22
195.2920685	0.25
202.5551758	1.08
211.1884918	0.95
212.0386047	0.24
213.1747894	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1089
Annotation	10-Dehydrogardenoside
Peak:m/z	Relative Intensity
129.0069580	0.21
131.0961304	0.05
151.0542908	8.57
156.9131165	0.33
160.3785248	0.11
161.2070923	0.06
175.0307922	1.10
177.1791077	0.12
185.3418274	0.08
188.9599609	0.06
193.2449036	0.34
202.6731873	0.10
205.3514557	0.14
217.1605988	0.20
221.3045044	0.22
231.0803833	5.81
233.2081909	0.11
239.2491760	0.16
249.0663147	100.00
252.9851685	0.07
268.8983459	0.07
279.1702271	0.15
294.2482300	0.16
297.2192383	0.13
303.3111572	0.23
309.1528625	0.08
311.2445679	0.11
313.4244995	0.14
325.4082031	0.37
330.9761963	0.26
341.1027222	0.59
355.2663574	0.74
356.3885193	0.30
357.2740784	0.91
365.1919556	0.43
367.3582153	0.26
373.9995422	0.10
383.2698669	8.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	382.1542
Annotation	Unknow
Peak:m/z	Relative Intensity
151.8804779	0.09
167.0287781	0.13
201.1449280	0.04
208.2229004	0.13
213.1088257	0.06
215.9408112	0.08
235.9807434	0.06
243.1859436	0.05
249.1091309	0.38
250.1953735	0.36
253.4702454	0.14
256.3940430	0.07
264.0665283	0.44
265.2139893	0.61
278.1027832	0.11
279.1320801	2.30
292.1730347	0.64
293.1390381	3.24
294.2948914	0.06
297.5529480	0.13
299.5063477	0.54
300.4702148	0.34
302.2048950	0.08
307.1995850	2.06
319.2528076	100.00
320.1856384	0.19
321.0960083	0.25
322.1853027	0.16
331.3542175	0.42
335.2212524	1.47
336.1134033	0.42
337.3482666	0.75
338.3930969	0.34
342.4004517	0.19
362.7837219	0.13
363.4790039	0.35
364.3460083	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1396
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0751953	0.23
135.1055603	0.02
142.9989929	2.39
145.0223694	0.18
145.9501953	0.17
153.3173676	0.07
159.7579346	0.03
166.0881500	0.14
167.1494446	0.35
169.9102936	0.13
179.0471802	3.13
181.0860901	0.02
184.0906677	1.75
185.1434937	0.16
192.2009888	0.03
193.2696533	0.03
197.1437988	0.16
210.0665436	3.77
228.0355835	0.11
234.2164917	0.06
236.0290833	0.11
249.9534607	0.02
254.0867920	14.34
261.8104248	0.07
263.4811401	0.02
272.0926819	100.00
273.3118286	0.12
286.2785034	0.02
306.1567383	0.71
310.1672363	0.04
327.5802917	0.08
328.2213440	0.91
335.3133850	0.10
352.9498291	0.09
382.1207581	0.03
383.4761047	0.03
384.9606628	0.04
395.0950012	0.02
410.3677063	0.09
412.2270813	0.28
413.2801514	0.02
424.3402405	0.03
439.0392151	0.77
439.6906433	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	502.92
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0446167	0.07
158.9645538	4.21
159.9359436	1.28
161.0167847	0.55
199.0871582	0.51
200.0729675	0.46
200.9209747	0.17
216.9506531	0.03
218.1031952	0.07
219.0779572	0.18
229.0600586	0.78
230.1043396	0.54
231.0583191	0.35
244.9158630	0.03
246.0991364	0.08
272.9784241	58.16
273.9971008	30.16
275.0510864	29.01
386.9709778	54.89
387.9570923	93.38
388.9229431	100.00
402.9307556	0.05
427.8705750	0.05
428.9724731	0.30
456.9319763	0.04
471.8822937	0.03
474.9406128	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	365.15
Annotation	Gln Ser Met
Peak:m/z	Relative Intensity
167.8958435	4.79
179.5112152	1.46
184.9568176	12.43
203.08638	11.84
209.1988831	2.45
223.2124329	1.23
235.0909119	0.70
242.2219238	2.27
243.2885132	2.03
257.5067749	0.35
260.0159607	6.14
264.297821	0.45
266.1382446	0.90
275.4486084	1.30
284.7609253	0.80
291.2401428	0.40
304.5898438	1.97
306.9907837	0.60
312.3107605	1.38
320.1168518	0.95
321.1295166	0.60
329.1231079	2.33
330.0687561	3.10
333.0720825	0.90
337.3440857	1.70
347.1305847	100.00
348.2477112	1.40
355.490387	2.11
356.872345	0.60
365.0923157	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2499
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
105.1134415	0.42
107.1083679	0.72
108.9800873	2.16
114.6814041	0.07
120.9810333	0.98
123.0164185	0.57
131.153244	0.06
132.9659729	0.64
134.9882507	1.92
136.6467133	0.35
138.7726746	0.34
140.9957886	0.08
143.0811462	0.89
144.9530487	0.07
147.0214996	1.11
149.100647	1.28
150.9186401	0.40
156.9551086	0.48
159.078186	0.44
161.1233368	2.37
163.0279541	0.89
165.0861816	0.09
169.0567627	0.58
171.1399231	0.58
173.0068054	1.11
175.1697693	1.42
177.1601105	0.45
183.1490021	0.64
187.0500793	1.35
188.8869324	0.79
191.1118774	0.43
195.1411896	0.22
197.2555237	0.32
199.1304169	0.09
199.7951355	0.16
201.0572357	0.59
203.0657196	1.08
205.2360687	0.69
206.0125122	0.08
211.0437927	0.49
213.1227417	0.14
217.1227722	1.33
219.0404358	0.09
221.1518555	0.06
223.2271118	0.17
225.1417236	0.33
227.0859375	0.29
229.1297913	0.14
231.1546021	1.50
235.0653687	0.18
237.303833	0.11
239.3082275	0.20
240.7875366	0.33
245.0728455	1.68
247.2267151	5.14
251.4440918	0.14
253.3358154	0.44
255.3447571	0.09
256.3453979	0.13
257.1891479	0.78
259.0106812	0.79
260.4049683	0.15
261.2234192	0.29
263.1725464	0.22
267.1762085	0.20
269.236084	0.44
271.2325439	0.27
273.0387573	0.17
277.2817993	0.27
279.2851868	0.20
281.3534241	0.38
282.2749023	0.20
283.2282104	0.21
285.2550659	0.82
287.170929	0.30
295.0756226	1.06
297.2938232	0.22
299.3816528	2.00
300.2330017	0.16
303.4542847	0.20
305.3240967	4.77
307.1239014	0.08
309.5234985	0.18
313.4171143	0.24
323.2388306	100.00
323.9092407	0.74
324.9572144	0.09
332.322998	0.50
341.2001648	1.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1476
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
175.1087189	1.84
186.9949341	0.90
243.1870270	1.31
246.9367371	13.58
261.2014771	1.62
271.3135376	1.89
283.1222534	5.35
286.9810791	1.45
289.1116333	21.13
291.0098877	21.81
301.0923157	17.96
302.9043579	3.44
368.0961304	0.83
405.1448975	3.30
409.1427612	21.36
411.0513916	15.87
421.3090210	1.55
427.1524658	100.00
433.0667114	0.88
435.0479126	3.24
452.9816895	2.70
542.4916992	0.61
543.3247070	6.14
561.1163940	5.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.1966
Annotation	2-Hydroxymyristic Acid
Peak:m/z	Relative Intensity
70.71086884	1.56
88.92852783	6.71
92.99886322	1.25
99.3414917	1.36
113.1498108	2.46
124.8363495	2.46
131.0960388	1.35
142.7827148	1.36
157.1538696	1.58
169.2854767	1.58
171.1217346	2.02
181.2667236	6.40
182.7798615	6.01
188.9452057	1.46
197.1937103	100.00
199.1196594	17.03
200.9080505	7.67
202.9487152	2.65
205.5469818	1.47
211.0601349	2.14
215.064682	1.18
223.1939545	2.22
225.1461792	42.54
226.0708771	8.64
227.1706696	8.24
228.1057281	2.55
243.9285889	2.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3073
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
260.9772644	0.29
266.4251099	0.74
268.3647156	0.51
289.8609619	0.94
308.5518799	1.66
312.2044373	1.10
314.4685059	0.72
337.2938538	0.83
339.2972412	100.00
350.3228149	0.36
354.9674683	0.68
358.6845703	0.36
359.6947021	0.60
365.2944336	1.22
413.1856689	0.81
415.2457581	0.23
417.2152405	3.16
420.3656616	0.24
422.5302429	1.08
426.17276	0.39
430.6897888	0.77
431.3335876	0.24
443.8331299	0.29
449.3641052	1.17
461.3313599	1.90
462.1695862	9.66
463.1431274	4.76
470.9434204	1.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Citric acid
Peak:m/z	Relative Intensity
73.22457123	0.13
74.90036011	0.06
81.0643158	0.06
85.01716614	0.46
87.01460266	1.51
93.01167297	0.22
99.07061768	0.05
100.9857788	0.06
102.9735413	0.06
111.0089874	100.00
116.9011536	0.12
118.7631683	0.12
126.8888855	0.06
129.0079803	4.31
130.8130951	1.21
144.7660065	0.08
146.8153381	1.24
155.0131683	0.58
172.9554138	28.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	305.1141
Annotation	N-Carbobenzoxyglycylproline
Peak:m/z	Relative Intensity
95.9862366	0.08
100.8925171	0.12
120.1573334	0.08
121.9904175	0.16
123.0880890	0.06
126.9938507	0.12
135.9533386	1.79
138.0008240	42.89
149.0266876	0.23
160.9858704	0.06
161.8367462	0.28
163.0788116	0.05
166.0642853	0.17
166.9613647	0.12
169.1622620	0.29
171.0096741	0.22
174.9909668	0.26
187.9533844	0.16
188.9266510	0.16
202.1615295	0.12
204.1094971	0.35
207.1342468	0.12
208.8533325	0.41
216.1416016	0.31
218.1543274	0.16
225.1362000	0.39
227.2092896	0.23
229.1222839	0.18
233.0563354	2.77
244.0964966	3.78
245.2306519	0.35
247.2023621	0.13
251.2746277	0.16
253.3223877	0.05
259.1365967	0.92
259.9885864	0.34
261.1207275	100.00
263.2390747	0.14
265.1231689	0.18
268.3073730	0.58
269.1480103	0.62
270.3548279	0.08
271.2102966	0.46
272.8280945	0.09
278.3382263	0.09
285.1413269	0.42
287.1740723	26.94
289.7730713	0.25
305.1331787	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.145
Annotation	Unknow
Peak:m/z	Relative Intensity
211.0359497	1.50
218.1118469	0.05
221.4301147	0.06
235.9726257	0.08
248.9669189	0.07
258.0554504	0.05
279.5574646	0.06
280.1786499	0.31
281.0479736	0.10
305.1397705	0.09
310.2762451	0.07
321.1930542	0.06
323.0383911	100.00
341.1478271	0.16
381.0390015	0.07
383.1719971	1.72
414.9769287	0.07
442.5955200	0.10
455.0733643	0.08
473.5216675	0.08
474.9714966	0.08
483.2399292	0.06
485.4541016	0.07
503.1979370	0.43
541.0714722	0.05
542.0477295	0.49
549.0736694	0.08
559.0117798	0.06
567.0900269	0.08
574.1036377	0.14
606.4825439	0.05
607.4561768	0.05
627.2324829	0.08
628.6221924	0.20
646.8895874	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
104.8225555	0.13
115.0687256	0.14
117.1091919	0.28
132.9974365	0.13
143.1022797	0.10
143.9472046	0.17
145.0309753	0.07
145.9990234	0.48
149.0310516	1.50
150.0383301	0.28
157.1488342	0.37
161.0641479	0.16
164.9903564	0.09
166.1305847	0.47
167.1226654	0.22
167.8293304	0.10
169.1739807	0.11
173.8669281	0.21
175.3984528	0.13
178.1711884	0.10
179.0553436	2.03
180.0242157	0.46
181.2445374	0.14
182.181778	0.18
184.2100372	0.32
190.0865784	0.33
191.8937073	0.18
193.0667877	1.18
194.2051392	0.84
195.1242523	0.31
195.8110199	0.22
205.1540985	0.09
206.11763	1.28
207.0949554	9.00
208.1453247	9.79
209.134552	3.36
210.0344543	0.34
216.8442078	0.25
222.1752319	5.16
223.098587	13.59
224.1341858	2.75
233.2302704	0.50
234.2498016	0.30
235.2887421	0.29
236.121933	0.50
251.0759888	100.00
252.0841217	32.59
253.1592255	3.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2503
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.9405289	0.19
106.8621368	0.53
116.9326706	0.62
121.0392227	3.39
122.8841248	1.63
124.970726	1.49
130.8274536	1.66
133.1622314	1.46
135.1510773	1.99
138.7928467	0.21
140.7872925	1.26
143.0554504	2.56
143.8327332	0.35
145.2299042	1.66
149.1651611	1.72
150.8728638	1.23
155.060318	1.19
157.1673889	1.09
159.0242004	2.72
161.0546265	1.08
163.0559387	0.89
165.0523071	0.42
167.1288147	0.65
168.8808441	6.37
170.9823608	1.14
172.6107178	2.88
173.2361145	8.93
175.164444	0.21
183.1168518	1.66
185.1989136	0.81
187.1365051	3.00
191.1357422	0.22
192.9934692	0.43
194.9740295	0.67
197.004715	1.82
199.1768188	0.47
201.3766937	1.16
203.1147156	0.19
205.3801117	0.72
207.3731537	0.44
211.0466919	6.31
221.2723389	0.35
223.2226868	0.38
225.3226929	1.80
231.1719666	0.51
233.1188965	0.34
235.2778015	0.88
243.184967	1.81
245.2779846	2.49
247.2008667	8.46
251.1680908	1.02
252.4208984	0.27
253.2179871	0.28
262.9475098	2.07
265.458252	1.18
267.0883179	0.57
271.2642212	0.45
279.4709778	1.86
281.22229	1.55
285.2897949	0.89
287.1390686	0.45
292.0106506	0.59
295.2173767	4.21
297.0224915	0.90
298.305603	0.58
299.2649231	0.85
305.1708069	4.65
311.142334	0.50
313.3771362	1.06
323.2290039	100.00
323.9396362	1.10
325.3554382	0.35
341.0863342	1.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	203.08
Annotation	Tryptophan
Peak:m/z	Relative Intensity
71.96376038	0.30
72.83102417	0.02
73.93733215	1.46
101.1368408	0.03
114.9244995	0.03
115.9026031	29.44
125.0761261	0.05
127.986557	0.33
128.9811096	0.22
130.052063	0.90
132.0649261	0.53
134.9481354	0.04
138.9150543	0.06
140.9723663	0.03
142.0143585	13.82
142.9799652	0.04
144.2677917	0.09
145.0440826	0.02
157.0235443	0.24
159.0892944	100.00
160.3005219	0.09
161.0778809	0.04
173.0582581	2.45
174.9799805	0.03
184.9664764	1.76
186.107666	9.09
187.0207672	0.04
203.2366791	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1174
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
69.72013855	0.13
71.81262207	0.74
89.88575745	17.11
98.03929138	0.37
112.9070129	0.29
115.9754944	3.73
131.2043457	0.22
147.8808594	0.45
149.1299896	0.14
155.9956055	0.70
159.8842926	0.45
166.1361084	0.14
173.0175171	0.19
173.9272614	5.06
184.1293182	23.52
191.3923645	0.27
202.1107483	100.00
206.1198578	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	286.86
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9793091	1.01
156.9959412	0.05
182.9455261	0.09
202.8651428	100.00
218.8444824	1.10
228.1983948	0.03
267.2448730	0.02
269.2184143	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1116
Annotation	Isovitexin
Peak:m/z	Relative Intensity
180.0155029	0.10
184.9967346	0.55
205.1937256	0.18
211.0980988	0.13
238.7697754	0.28
243.88974	0.13
245.1439514	0.11
258.7654114	0.37
267.1604004	0.09
271.0397339	0.13
283.0884094	0.69
284.3242798	0.15
295.1135864	0.34
302.2186279	0.14
304.2819214	0.14
307.2473145	0.62
313.1852112	18.76
316.06427	0.11
321.4762878	0.25
327.7503662	0.17
337.1602478	14.25
339.4080811	0.19
351.3514099	0.34
352.9501343	0.25
355.4729614	0.66
357.3191833	0.38
360.1427917	0.19
361.2796936	0.46
367.2107849	39.52
369.1445618	0.16
370.0431824	0.20
371.1998596	0.11
374.3464966	0.09
379.2350159	10.17
383.2070312	0.18
388.4090881	0.30
389.1971741	0.35
395.6539307	0.09
397.1938171	17.41
402.4694824	0.22
415.1090698	100.00
416.1984558	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.0878
Annotation	beta-L-Arabinofuranosyl-(1->2)-beta-L-arabinofuranose
Peak:m/z	Relative Intensity
80.7819672	0.37
82.9850006	1.80
84.1059113	0.07
85.0187683	9.70
86.9340515	5.41
89.0744476	0.07
91.0513916	0.21
94.9536820	10.81
97.0361939	1.74
98.9166794	0.64
99.8088074	0.08
101.0104141	0.88
102.9589615	15.01
106.9807739	1.38
108.9863892	1.50
110.3798218	0.17
111.0972748	1.88
112.8948059	84.22
114.9154205	0.37
119.0315247	0.41
121.1841049	0.23
122.8172989	0.13
125.0183258	0.40
127.0595703	3.01
129.0001984	10.55
130.8386841	7.90
138.9963684	4.59
142.9995117	2.76
144.9642181	0.45
152.8505554	0.07
157.0528870	5.55
158.9100952	0.20
161.0733948	1.30
162.7899323	2.62
168.9215393	1.94
170.9325714	0.25
177.4725189	0.11
179.0184326	0.09
180.8996124	0.06
183.1238403	0.11
187.1157837	4.06
189.0209656	2.95
192.7592316	0.13
201.2319641	0.08
203.1201172	0.14
205.0242615	91.70
209.1577148	0.16
218.0936584	0.30
231.0617371	6.53
234.8323364	0.08
237.1261902	11.47
238.1596680	0.16
245.2846680	0.17
249.1059570	100.00
249.9420166	0.21
263.1478271	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	849.2243
Annotation	Unknow
Peak:m/z	Relative Intensity
313.0997009	0.05
363.1597290	1.72
380.9767456	0.06
499.3022461	0.04
507.1581421	0.08
525.3129883	23.01
543.2944946	0.21
567.2617798	0.10
571.2747192	0.17
591.6661987	0.04
669.5554810	0.18
685.6580200	0.05
687.2709961	100.00
688.4421387	0.57
705.3860474	0.08
715.4361572	0.20
729.1255493	0.06
743.2349243	0.06
758.4282837	0.07
787.5641479	0.03
794.6932983	0.09
803.9151611	0.13
831.6881104	0.15
832.4458618	0.04
848.9188843	0.28
849.9066772	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9579
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0723419	0.07
142.0776672	0.17
143.7640991	0.04
155.9099426	1.02
169.2119446	0.14
170.1222076	0.73
171.5713959	0.07
181.1131592	0.24
183.9647675	0.74
187.8762817	0.09
189.1038818	0.25
191.1200256	0.45
196.9849548	0.28
198.0076904	0.60
199.8872986	20.02
200.9490051	0.94
203.0375366	0.35
204.0767059	0.09
214.0256653	6.31
218.0440674	0.94
219.0911255	0.13
223.0890503	0.09
225.2960968	0.33
227.0062561	0.53
227.9916077	1.09
231.1912231	0.21
236.0859070	0.12
239.1207581	0.41
241.1464233	0.06
241.9568481	0.33
243.9378967	5.03
245.9911804	0.94
252.5683289	0.31
253.3757935	0.14
254.0182495	0.23
255.1571045	0.38
256.0454712	0.09
257.9320374	70.14
259.0480347	0.07
260.0645752	0.06
261.3465881	1.50
262.0721130	2.64
262.9893799	0.65
268.1661987	0.06
272.0948486	0.24
273.7821045	0.14
275.1416626	1.10
277.9565430	0.07
279.2484436	0.28
284.0717163	2.11
285.8802490	2.92
287.9738159	8.71
289.7554321	2.56
300.0440979	0.23
301.8817749	49.64
303.1428528	0.34
304.0256958	0.47
306.0941772	0.93
307.3269958	0.06
308.2164917	0.15
312.6800537	0.73
313.9860840	1.63
323.2639465	1.92
324.2100525	0.27
325.2454834	0.99
326.3557434	0.17
328.0194702	3.06
329.7640076	7.72
331.2713013	21.29
332.0196533	100.00
338.2778931	0.40
339.5026245	0.36
341.5917358	0.21
343.9716187	0.07
345.7419128	23.58
346.4317932	0.16
347.8052368	1.47
351.1619263	0.98
352.5653687	0.51
354.1445007	0.08
355.2314758	0.36
357.2221985	10.98
358.3037720	1.27
367.2613831	0.34
369.2576599	26.29
370.3034058	6.11
371.5965881	0.21
373.7452698	2.97
374.7239685	0.36
375.6489563	0.61
381.1275330	0.21
383.2554626	1.32
383.9761047	0.42
391.9116211	37.26
399.2565002	2.52
400.0370178	4.98
401.1683655	10.88
402.1269531	2.86
416.0683899	0.06
417.2417297	17.05
418.0445251	75.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	229.1809
Annotation	2-hydroxytridecanoic acid
Peak:m/z	Relative Intensity
167.0454254	0.16
169.0022583	0.41
183.2437439	0.26
185.1903839	100.00
192.9703369	0.18
201.1754303	0.12
202.6994171	0.67
206.0398254	0.17
211.0091705	0.83
213.3433075	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2996
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
93.0589600	0.05
95.0591354	0.25
96.8978119	0.13
101.9706192	0.03
109.3666000	0.12
121.0836792	0.04
122.7446899	0.07
124.9175186	0.08
131.0744324	0.09
134.9691467	0.07
151.1716309	0.06
153.1266174	0.13
154.8417664	0.05
155.9757996	0.10
165.1574402	0.07
169.0861206	0.06
171.1158447	0.07
179.6208038	0.06
181.4468231	0.06
185.1919556	0.03
187.0965118	0.08
190.9275665	0.04
196.8698730	0.17
197.4945068	0.03
198.3132324	0.05
202.9212952	0.03
207.2339172	0.08
209.0892639	0.14
211.1354065	0.46
224.8528442	0.08
227.2217102	0.10
235.3025818	0.25
236.5076599	0.06
239.1405334	0.31
240.4246521	0.07
241.4029846	0.09
247.2888794	0.30
251.0810852	0.03
252.3286438	0.92
253.2073059	0.34
254.3615112	0.04
256.6967163	0.06
264.2617188	1.15
265.3680725	3.41
269.1030884	0.08
270.3869324	1.01
272.8735352	0.02
282.3840942	39.66
283.3444214	0.36
287.0339966	0.30
288.0169983	0.05
300.2940674	100.00
301.0079041	0.47
317.9832153	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0807
Annotation	4,6,7-Trihydroxy-1,2,3,4-tetrahydroisoquinoline
Peak:m/z	Relative Intensity
124.2156372	0.03
135.9503174	18.78
154.3719940	0.04
161.5877075	0.07
164.9435883	100.00
170.2698822	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.2627
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
82.95278931	1.11
86.7565918	1.05
88.78492737	0.59
91.00724792	1.81
94.98099518	9.88
97.03807831	0.51
101.031723	7.06
108.9611969	3.93
110.1260071	0.63
110.8852081	0.94
114.820694	1.83
120.9642639	1.78
123.0914001	3.49
124.9608459	2.94
126.959549	0.68
128.9872742	2.44
132.9108276	2.81
135.1360626	12.91
139.143158	2.86
140.8954163	2.17
143.1166382	1.50
149.0430603	7.06
150.9062805	2.87
153.0009003	0.56
154.9006653	1.38
157.0772705	0.65
161.1193848	0.40
162.9226074	4.86
165.0439148	6.42
171.0411377	0.71
175.1615906	0.88
177.2582703	0.60
180.842865	1.25
183.0863342	3.75
186.8861694	0.68
191.3254547	1.08
193.0053406	1.61
199.1802979	6.76
207.1756897	0.36
219.2333069	1.14
220.9049988	2.28
223.1934814	2.95
225.104126	13.48
237.194458	0.60
239.0031128	4.30
239.678772	2.01
241.3036194	0.83
241.9150391	0.65
247.2010803	42.64
252.351593	1.13
255.3187866	1.94
265.2562866	100.00
266.3969116	5.49
268.3502197	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.072
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
92.06872559	0.40
108.8777542	5.02
113.2163467	0.31
119.0174561	0.50
122.913559	3.92
135.1125183	0.24
135.9459839	0.73
151.0586853	0.35
151.9211121	3.83
153.0174561	100.00
163.0128326	0.32
164.9755554	1.72
176.0136871	0.82
177.1576538	1.52
193.1659546	1.51
223.0414429	1.17
225.2056885	0.98
227.0005798	0.32
246.9667358	1.34
253.1278687	1.20
269.1517639	1.45
271.1917725	2.31
280.0200195	1.33
287.4578552	1.47
296.2926025	1.06
297.232605	0.95
300.0419922	0.50
316.9217224	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9400558	5.54
115.9364700	2.25
116.9523621	2.62
130.9774628	0.24
132.0571594	0.23
133.0956116	0.04
158.9724731	100.00
159.9888458	52.69
161.0102539	60.33
199.8980103	1.62
201.0109863	2.87
203.0826416	0.02
216.6007996	0.03
218.0863953	0.84
218.9502563	1.06
220.2611084	0.06
229.1593323	1.80
229.9750366	19.70
230.9408264	32.52
245.8560791	0.32
246.9902649	0.48
257.0860596	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1301
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
160.9258423	3.27
179.0313873	1.91
181.2395935	0.07
196.9825745	1.09
199.7243958	0.07
205.2852783	0.07
222.9280396	0.55
224.9925995	0.10
259.1651001	0.02
269.1473389	0.07
289.2954407	0.04
293.0563049	0.11
305.1796875	0.14
315.0238647	0.09
323.0045166	0.41
329.1298218	0.07
341.1436157	1.37
355.4965820	0.04
359.1828003	100.00
389.1932983	0.38
419.9469604	0.14
420.9880981	0.16
426.8994141	0.06
431.1932983	0.22
437.1163330	0.10
458.0451050	0.10
461.4469604	0.04
474.4186401	0.80
475.3068237	13.88
476.5438843	0.14
477.3010864	0.04
484.2568970	0.04
485.2820435	0.38
486.4034424	0.05
491.1165771	0.06
501.3437500	0.13
502.2549438	0.18
503.3678589	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
94.83551025	1.45
102.9292297	0.67
105.0620422	1.50
107.1006165	1.09
119.0883942	0.84
128.9599762	7.46
140.9268188	3.29
142.5908661	0.95
150.9796143	100.00
151.945816	5.22
165.0615387	3.25
165.8552399	0.73
167.071701	3.77
169.0555878	2.24
178.9470215	1.04
180.1205292	2.30
182.3125305	1.09
183.0649872	1.31
185.0991974	2.43
194.000061	2.06
196.9539795	10.41
207.0686798	1.36
210.0458527	2.74
212.3056488	1.76
225.0171661	6.18
238.1023712	18.95
251.2828522	6.04
253.0853729	72.08
254.1127319	11.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
136.9455109	0.04
139.9317932	0.13
152.9764862	0.08
155.9273071	0.05
170.8900299	0.02
195.9935455	0.15
214.133606	1.62
218.9315948	0.04
222.1682587	0.19
243.6296234	0.05
251.0238647	0.03
261.3466492	0.27
269.2844849	0.04
272.1896362	0.03
279.2411804	100.00
279.930603	0.08
281.3171997	0.05
307.2655029	0.03
309.2119141	0.03
331.1165161	0.06
363.216156	0.03
371.6101685	0.04
373.3523254	0.07
387.3616638	0.02
388.1930237	0.07
392.1769104	0.13
395.5504456	0.04
404.4131165	0.17
412.2502136	0.08
416.2962036	0.15
418.182373	0.03
429.0448303	0.03
429.8663025	0.16
430.4786072	0.05
431.3158875	0.04
432.4996033	0.19
440.0296936	0.24
443.6246643	0.03
457.7395325	0.56
458.9660034	0.16
461.3909302	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.3354
Annotation	Unknow
Peak:m/z	Relative Intensity
238.2888641	0.04
240.1617432	0.01
256.2235718	0.07
262.2632446	0.07
264.1212158	0.04
274.0619812	0.08
275.2599182	0.11
276.1582947	0.54
277.3066711	0.43
278.1345520	0.13
282.1093140	0.16
283.2214050	0.16
284.2540894	0.07
297.2860718	0.12
300.2584839	3.56
301.2057190	1.95
302.2231445	0.37
302.9696350	0.03
304.2176208	1.46
305.1314392	0.91
306.0736694	0.05
318.1432800	0.12
319.1398926	0.18
320.1722412	0.04
344.3239746	0.03
345.3590088	0.02
346.3738403	0.08
363.0470886	0.07
381.3041992	0.04
382.1090698	0.03
387.2689514	0.03
405.1859741	11.13
406.1838989	7.96
407.3532104	1.45
413.2286377	0.03
418.3669434	0.07
426.6646729	0.04
435.4779053	0.07
442.4572754	0.05
477.2543335	3.26
478.3232422	5.14
479.4083862	0.92
499.4902954	0.12
500.4526978	0.15
503.3222046	0.03
506.3563843	0.04
507.3928223	0.11
517.2988892	0.05
531.2902222	0.18
532.4121704	0.01
548.2862549	3.63
549.3280640	6.32
550.3784790	1.87
610.3186646	0.06
629.3872070	0.74
630.4999390	0.20
631.6848145	0.09
634.0974731	0.03
634.9406128	0.08
642.4605103	0.04
646.4448242	0.37
647.3731079	1.81
648.1996460	0.31
650.4186401	0.03
659.3818359	1.60
660.3181763	5.05
661.3508911	1.50
662.6318359	0.06
675.5347900	0.02
677.3073120	0.48
678.3546143	1.79
679.3704224	0.51
702.5678101	1.68
703.4084473	8.75
704.4624023	2.12
705.5572510	0.02
720.8883057	0.13
721.5007324	0.05
722.2799683	0.11
745.5995483	0.09
770.2310181	0.09
771.4381714	0.12
772.9227295	0.06
787.7653198	0.17
788.4980469	1.34
789.4538574	1.26
790.5321655	0.15
791.6593628	0.06
797.5668335	0.02
805.3745117	0.06
806.4785156	1.07
807.3822632	0.08
808.6008911	0.32
809.8170776	0.01
814.4536743	0.39
815.4035034	0.52
816.5793457	0.11
830.7676392	0.29
832.3759766	100.00
833.4481812	29.10
834.5263062	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.2054
Annotation	N-Demethyl-desepoxymaytansinol
Peak:m/z	Relative Intensity
158.7520599	0.14
169.0204773	0.12
172.7697754	0.16
183.7357025	0.12
185.1768036	0.04
191.0304260	0.10
226.8868866	0.09
242.9366608	0.17
243.9245300	0.45
245.0626678	0.13
249.8563385	0.08
258.0664978	0.13
259.2984314	0.26
271.0019226	0.31
271.6159668	0.06
274.0974731	0.03
276.8646851	0.16
284.9616699	0.31
298.8847046	0.16
299.7500610	0.09
303.2302246	0.19
314.2893677	0.08
327.4377441	0.38
328.4647827	0.12
339.0677490	0.09
343.2138062	0.07
355.0972900	0.31
357.1109009	0.09
359.3037720	0.06
369.3557129	0.45
370.2573242	0.08
371.1251221	0.78
383.2766113	0.08
385.2865601	0.30
392.1496582	0.07
397.3308716	0.32
399.2858887	0.15
409.5911865	0.11
411.2814941	0.27
413.4088745	0.10
415.0803833	0.05
426.6257935	0.26
427.3765259	0.21
434.2756348	0.08
435.3933716	0.06
437.6672974	0.10
440.4262085	0.25
448.3079224	0.26
449.0348511	0.50
459.9838867	0.06
472.8966675	0.16
479.4730835	0.22
480.8888550	0.22
482.2727661	0.15
486.3032837	1.01
487.2720337	7.11
489.3568726	100.00
496.2581177	1.39
497.2198486	1.71
498.4773560	0.37
503.0055542	0.08
505.6725464	0.16
514.7416992	1.10
515.9200439	0.73
522.9901123	0.12
523.7050171	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	285.22
Annotation	Vitexifolin C
Peak:m/z	Relative Intensity
90.87501526	0.56
92.79575348	0.43
95.2443161	1.23
96.76934052	0.41
102.0217667	0.30
104.9672623	0.60
107.0639877	0.28
108.9556732	0.89
110.2205963	0.34
110.9033585	1.48
114.9034653	1.40
118.7819366	0.91
123.032608	2.05
124.8021927	0.81
128.7718658	2.11
130.9065399	0.70
135.1944885	0.41
135.9472351	0.71
137.0684509	1.50
141.322998	0.29
143.1004028	3.10
146.8755493	0.98
151.0785217	0.77
152.9572449	0.39
155.161026	0.76
157.0197601	2.73
158.967041	0.84
163.1295013	0.30
166.8672485	0.33
169.11586	1.94
171.1078339	4.82
172.4900818	0.43
177.1483612	0.23
178.2229004	0.17
179.2382507	1.44
181.6075134	0.64
182.9221191	0.61
184.9367371	3.88
189.1200867	0.66
197.0579834	1.33
199.0216675	0.15
201.1385803	0.43
205.3786621	1.19
207.2002258	8.31
208.1094971	0.73
209.355835	0.19
211.0843201	0.47
214.6793213	0.28
221.1990356	0.17
223.0249023	1.44
224.9654846	2.10
226.3892822	0.84
229.0887451	2.15
231.2451782	0.54
239.2633362	3.92
241.2199097	0.67
243.7234497	2.69
248.40979	0.98
249.2110901	7.94
253.0565796	0.36
257.1641235	1.01
262.1357117	0.52
264.784668	0.19
265.3881836	0.91
267.2113647	100.00
269.9801636	0.63
285.1776733	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	665.5185
Annotation	Unknow
Peak:m/z	Relative Intensity
270.5623779	0.52
435.3869629	1.86
589.8480225	1.67
618.9662476	2.53
748.4292603	0.65
749.4070435	0.63
757.7492676	1.83
785.8480835	1.60
803.9840088	2.04
886.3483276	1.81
887.4808960	0.94
895.7163086	1.67
961.2374878	0.58
1243.2639160	0.70
1393.9138180	0.68
1465.9122310	0.63
1646.9200440	1.86
1656.7559810	0.32
1688.4176030	0.41
1727.3568120	1.14
1744.4617920	0.64
1777.2097170	18.54
1811.9793700	0.45
1815.7872310	11.62
1820.9815670	0.30
1825.3333740	3.04
1833.5075680	6.99
1853.2220460	0.35
1868.7204590	10.73
1870.8387450	0.76
1875.8332520	1.76
1878.0158690	8.77
1879.8532710	1.55
1891.8386230	1.41
1894.5617680	3.98
1897.5114750	0.45
1900.3170170	1.00
1901.8480220	1.24
1906.8892820	0.76
1908.5845950	1.13
1915.0247800	1.19
1919.6092530	1.73
1921.0968020	15.71
1923.6090090	100.00
1933.1632080	4.62
1934.6473390	3.79
1936.1491700	0.51
1936.9240720	15.52
1937.5250240	1.96
1940.8079830	0.34
1942.8936770	23.43
1954.9749760	0.46
1960.3166500	6.45
1964.4250490	2.76
1968.7996830	54.48
1973.9744870	4.88
1974.8649900	24.29
1976.2170410	10.39
1977.1663820	4.65
1979.2586670	1.23
1982.9285890	6.21
1984.1497800	0.38
1984.8182370	6.82
1985.9602050	1.93
1986.8970950	1.26
1998.5065920	18.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.263
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
82.99311829	1.24
94.94792175	3.54
96.91548157	1.88
100.8991776	6.70
106.9586792	1.41
108.9234009	5.86
111.2273788	3.09
112.95401	1.66
115.0788727	2.77
120.7828293	5.71
122.9881821	3.72
128.7179871	0.32
133.1508789	1.27
135.0080566	10.06
136.8282776	2.56
138.9751892	1.01
141.0808716	0.92
142.9437256	1.66
149.0418396	4.76
150.9240265	2.40
152.9605408	1.98
154.9666748	0.90
158.8239746	0.68
163.2440491	1.24
165.0795593	6.24
165.6829834	0.67
169.1154785	4.82
171.0498657	0.69
177.0773926	4.43
180.9481506	3.52
182.9562683	2.43
184.1724548	0.82
185.090271	0.55
187.3395844	0.78
191.1921692	0.41
193.2295837	2.96
196.8812256	2.08
198.9594116	1.01
201.1772766	1.88
207.0464783	0.55
209.3807068	1.44
213.116333	7.91
219.2575073	3.25
223.312561	2.29
225.0026855	9.57
226.8024292	1.08
237.1828003	2.69
238.0842285	1.42
239.3061829	5.35
241.2294922	1.25
247.1958313	29.89
265.2532959	100.00
266.3572998	3.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.13
Annotation	CMP-8-amino-3,8-dideoxy-beta-D-manno-octulosonate
Peak:m/z	Relative Intensity
206.9452209	0.34
252.9870300	0.07
261.4575195	0.04
276.8690186	0.07
283.3642578	0.09
290.8014526	7.48
292.7289429	0.04
307.0321655	0.03
320.9000244	0.44
323.2316284	0.18
374.6467285	5.49
376.6793213	0.10
380.5801392	0.34
388.9672241	0.10
390.8276978	1.01
396.3913574	0.07
398.9001465	0.19
406.7362671	0.21
418.0982056	0.07
422.8286133	0.56
429.1580200	0.05
436.7428589	1.35
452.6348267	0.25
456.2360229	0.07
456.8543091	0.04
458.5306396	100.00
459.3369141	0.49
474.5159912	0.06
478.7543335	0.93
482.7298584	4.57
496.7472534	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
89.15607452	0.20
95.07488251	1.07
108.8188934	0.77
121.0850677	0.12
122.4725723	0.88
123.0930023	2.45
124.7864075	0.43
127.0882874	0.74
129.2377319	0.66
131.0340271	0.34
134.1516113	0.15
135.1678772	1.07
136.8063049	0.18
139.0457153	2.65
141.1417236	0.70
142.8337708	0.27
144.8068085	0.18
153.1342621	1.86
161.2970581	0.17
162.9472046	0.69
164.9837646	0.51
166.9610596	0.92
168.9611664	0.24
171.158371	0.70
175.1445923	0.64
178.1196747	1.03
179.279068	0.19
182.8734131	2.39
185.1350403	0.99
189.1087341	0.70
193.3925476	1.08
195.471283	0.39
196.9652252	6.06
198.9573059	0.38
201.1000061	0.63
203.1078491	0.40
209.3078918	0.74
211.1089783	1.37
213.3058472	2.73
215.1165466	0.31
219.3882751	1.83
221.098938	1.52
223.0995178	0.76
225.0621338	1.02
227.0044861	1.07
228.6250305	0.25
233.3163757	1.44
237.2982178	2.13
239.0937805	7.48
241.1754761	1.47
243.3631592	1.62
251.2408447	3.14
253.0434875	0.81
255.1896362	1.41
256.3303223	1.22
257.1273193	2.74
261.3060913	3.92
269.9747925	0.34
279.2236328	100.00
280.2362061	1.05
281.1548462	0.91
288.9795837	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.8581
Annotation	Unknow
Peak:m/z	Relative Intensity
243.1094666	0.04
244.9295349	0.44
272.8797302	0.21
289.1854248	0.11
291.1454468	0.06
314.9297485	0.45
316.9849854	0.05
319.1400452	0.18
343.3055115	0.07
357.9578857	0.21
358.9039307	0.43
360.9523315	0.17
363.1554260	0.03
366.0001831	0.06
384.6880798	0.04
387.9512634	0.05
398.0314026	0.07
401.0315247	0.06
405.1778259	0.30
427.0929260	100.00
428.9065247	8.37
442.1210938	0.09
442.8909607	0.05
445.0429382	0.25
454.6673279	0.29
463.2649536	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	391.2834
Annotation	Di(ethylhexyl) phthalate
Peak:m/z	Relative Intensity
131.0357056	28.01
149.0196533	100.00
150.1403809	8.21
166.9424744	20.45
168.067749	11.99
184.8990173	9.55
187.1339722	11.62
223.262146	10.01
261.2813721	37.24
261.941925	34.52
269.2669067	4.66
275.1469727	5.55
279.0245056	26.87
280.0728455	20.46
346.201416	4.66
351.5671082	11.78
373.9189758	30.33
375.1668396	22.25
383.198761	39.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.2
Annotation	2-Hydroxymyristic Acid
Peak:m/z	Relative Intensity
77.02201843	0.74
83.08591461	0.87
113.2035217	1.02
127.0164795	0.70
138.2617798	1.48
151.0844574	0.66
155.1102448	7.38
164.0446625	1.18
169.1196289	79.59
169.9774475	0.99
171.0454102	0.61
178.9273987	1.03
181.2067413	8.13
182.8727264	0.90
185.1417542	1.88
197.1876984	100.00
199.166153	15.63
200.8903961	1.20
202.806076	2.97
207.0519257	3.99
213.0449982	1.71
213.6472015	0.87
223.0725555	1.88
225.118454	78.15
225.9647217	4.82
227.2222443	9.94
227.847229	0.45
229.0519867	0.45
243.8572998	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.21
Annotation	5(S)-HpEPE
Peak:m/z	Relative Intensity
112.9501648	0.36
120.9070663	0.36
124.9715729	1.29
170.9875793	0.39
215.2045593	0.41
218.9434509	0.59
221.4067078	1.13
235.9888	0.27
236.9224243	0.96
239.2098999	1.28
253.2169189	0.25
255.2599487	8.99
257.1662903	1.11
264.8227844	0.71
269.5238037	0.44
271.2857056	17.22
273.1847534	1.30
287.222168	1.97
289.2242126	5.36
297.2813721	8.29
299.2232056	3.73
304.0652161	0.37
305.9306641	0.40
313.269165	0.90
315.2005615	100.00
315.8474731	0.34
317.3286133	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.9537
Annotation	Unknow
Peak:m/z	Relative Intensity
119.5731659	0.50
184.0085297	0.35
198.7791138	0.16
242.9735413	0.21
256.9253235	0.11
265.4873352	0.28
272.2922363	0.21
299.4377747	0.52
309.3238525	0.42
311.2210388	0.38
312.2655029	1.19
313.0257568	4.71
314.9339294	0.49
328.0279236	0.13
330.6571960	1.98
355.0603638	0.25
367.1078186	0.14
380.1304016	0.72
382.1859436	0.34
383.1172180	0.35
383.9771118	5.04
384.9659729	100.00
397.8681335	0.85
401.8817749	3.43
402.6092529	18.13
407.2651978	0.31
408.1138306	0.20
419.6472473	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
125.3638763	0.06
131.0557861	0.05
135.1266022	0.03
137.2114868	0.03
143.1342163	0.12
146.9161987	0.05
149.0496063	0.05
150.8691254	0.15
153.1313171	1.74
154.1894226	0.24
159.1072998	0.17
161.0203094	2.10
162.1244507	0.34
165.1522217	0.03
168.9979553	0.03
171.2528076	0.04
174.0876465	0.07
177.0670776	0.02
179.0414734	0.59
180.3494263	0.08
182.1177979	0.06
185.3383484	0.06
190.8999023	0.04
193.2504425	0.22
196.0190735	0.05
205.1828918	2.08
206.2024689	0.30
212.9458618	0.02
215.8926392	0.05
223.0639496	5.94
224.1481934	1.36
225.0466919	0.18
230.9319916	0.17
233.0923462	0.17
234.4251709	0.07
249.1827393	0.46
269.3889160	0.08
272.2938232	0.03
277.4197998	0.04
287.2752075	0.05
299.2115479	0.30
303.0380859	0.05
307.2159424	0.05
311.2583618	0.05
313.1725769	0.15
314.1543884	0.03
315.0747070	0.02
317.1268311	0.08
347.1543579	0.05
358.0180359	0.04
359.2294922	0.03
371.2077942	0.16
378.3183594	0.10
385.1724243	100.00
386.2661133	15.81
387.4135437	0.03
388.3483582	0.12
389.1874084	0.07
395.6192932	0.03
399.5706787	0.03
400.1787415	0.02
413.2313538	0.20
414.2655640	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.2648
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9507446	0.10
141.2696991	0.06
142.9765167	0.28
144.9313049	0.05
148.9420319	0.07
160.9810944	0.06
167.0327148	0.04
178.9635620	0.15
182.9856262	0.05
184.9474182	0.06
214.5332794	0.04
215.1954803	0.06
223.2354736	2.99
233.1496582	0.04
235.4663696	0.08
237.2596741	0.07
239.2225342	0.05
245.0964966	0.07
247.3423462	0.15
250.7853088	0.21
251.3872070	2.74
253.0627441	0.31
253.6697388	0.24
265.2949524	2.53
269.2297058	100.00
270.3000793	0.17
281.4622803	0.07
290.8361816	0.05
293.4191895	0.15
295.2349854	0.05
300.2452393	0.04
307.1322021	0.14
311.2570801	4.42
315.1489868	0.08
317.1554260	0.03
321.3949890	0.21
322.3625793	0.09
323.3532715	0.38
329.3888855	0.21
330.9153748	0.06
336.3732910	0.05
341.3590393	0.21
343.2832031	0.06
357.4642334	0.24
359.5470581	0.05
367.2187195	0.05
377.5034485	0.08
385.3195801	0.19
386.6011658	0.04
387.3887024	0.10
395.0714111	0.16
396.0434265	0.05
399.4274597	0.36
411.2068481	0.23
412.7385559	0.14
413.3675842	0.36
414.1417847	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	849.3352
Annotation	Unknow
Peak:m/z	Relative Intensity
238.0481873	0.02
256.2314453	0.20
262.0659790	0.16
276.1505127	1.16
281.0252991	0.02
282.2111511	0.35
283.1301880	0.10
297.3049927	0.04
300.2210083	6.18
301.2531128	0.05
304.2509766	1.87
310.5031738	0.02
314.9395142	0.02
318.2587891	0.28
345.2817383	0.31
353.3743286	0.02
387.3037109	0.07
405.2775879	17.67
410.1874390	0.02
425.3713379	0.03
435.4374390	0.07
437.4779053	0.07
477.3135986	8.31
498.3116455	0.05
499.2904053	0.10
503.3678589	0.02
506.4517822	0.03
529.8498535	0.19
530.5429688	0.10
533.8771362	0.05
540.6521606	0.04
542.1923218	0.03
548.3867188	10.80
597.4168701	0.03
628.2778320	0.46
633.6795044	0.03
641.3673706	0.03
644.4411011	0.03
646.3153687	1.25
646.9784546	0.04
649.6925659	0.09
657.1041870	0.05
658.6795044	0.36
659.3790894	3.96
660.4536743	1.19
677.3767700	1.53
684.0366821	0.03
688.2248535	0.03
702.3650513	11.91
703.4760132	0.04
714.6682129	0.02
720.4647827	0.70
743.7584839	0.04
751.8192139	0.03
769.5598145	0.07
787.4401245	2.91
788.4833984	0.39
789.4634399	0.11
803.3106689	0.02
804.3234253	0.02
805.4754028	1.21
807.5635986	0.16
813.4548950	0.89
814.5029907	0.54
831.3503418	100.00
832.3102417	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.18
Annotation	Tanzawaic acid E
Peak:m/z	Relative Intensity
92.66665649	0.33
127.0268707	0.22
127.8192902	0.10
143.1724854	0.10
145.7337036	0.15
174.5126648	0.22
186.2976379	0.18
191.1791229	0.17
195.4657593	0.28
199.2352905	0.34
201.1723633	0.24
204.098175	0.60
204.8951721	0.06
216.9063721	0.38
227.2134399	0.77
231.1191406	0.15
241.0952148	0.24
242.9367676	0.34
243.9343872	0.10
245.104248	0.97
261.2522888	0.15
266.2961426	0.22
267.7354126	0.14
269.0776672	0.32
271.1784668	100.00
272.1304321	0.22
273.2492065	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.03
Annotation	2-C-Methyl-D-erythritol 4-phosphate
Peak:m/z	Relative Intensity
70.9468842	0.16
87.0158386	0.25
88.9329147	1.65
97.1708984	0.02
101.0284424	0.57
105.6454926	0.01
106.7983704	0.29
112.9436798	0.81
114.9632874	0.02
117.0179901	0.02
118.9647980	1.93
125.0585785	0.38
130.9259949	0.54
133.1693878	0.08
143.0371857	2.59
149.0754852	0.60
161.0023193	5.05
175.3390656	0.02
178.9480286	100.00
184.5853119	0.01
196.8390045	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.2593
Annotation	DL-2-hydroxy stearic acid
Peak:m/z	Relative Intensity
86.94670105	0.05
125.1348801	0.09
126.3232727	0.09
142.9196167	0.08
167.1918793	0.11
173.055542	0.10
183.2266998	0.26
194.8802795	0.09
196.0673828	0.11
201.1670532	0.08
209.15979	0.11
215.2509155	0.06
217.3598022	0.19
225.3198242	0.10
227.2357178	0.31
234.1612549	0.10
235.3218689	0.06
237.2270203	0.17
239.3198547	0.41
247.3761597	0.09
251.4161072	0.45
253.2581177	100.00
254.3755798	2.18
255.2992249	1.47
256.8572998	0.10
262.2915344	0.08
263.1855164	0.39
265.2026367	0.05
269.3828125	0.23
271.1660156	0.25
272.1678467	0.15
279.3513184	0.05
280.3240662	0.28
281.4042358	7.55
283.1757507	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	652.2267
Annotation	Unknow
Peak:m/z	Relative Intensity
198.6582947	0.08
211.2832184	0.15
235.1033936	0.14
252.5673218	0.08
258.9823303	0.33
270.8881836	3.18
288.3129272	1.21
288.9524841	11.71
292.3533936	0.23
303.6159668	0.38
305.7746277	0.34
306.6098022	8.81
309.4811401	0.58
310.1967163	1.41
322.9348755	0.17
324.8706055	100.00
341.3426514	1.71
342.8085938	65.96
343.6000977	0.48
396.8909302	0.34
402.8729248	0.09
414.8261719	0.47
415.5740967	1.01
420.6666260	0.37
437.6617432	0.23
450.8175659	0.48
451.4657593	0.41
455.8797607	0.27
468.3181152	0.81
469.0375366	1.90
471.8444214	1.24
481.4903564	0.21
486.4119263	3.06
487.0259399	1.54
489.9050293	18.23
490.6208496	0.35
504.8666382	1.93
543.8389282	0.25
554.3104858	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
100.481636	0.09
102.5902481	0.10
107.0627823	0.44
108.9111404	1.81
110.930603	0.15
113.177948	0.12
121.0379562	2.04
122.9897003	0.72
129.06073	0.72
132.8818207	0.53
135.0349884	1.74
136.8775635	0.51
138.8379059	0.07
141.1845703	0.18
143.1630249	0.28
147.1078644	0.73
149.1387939	1.25
150.9961548	0.08
156.7976074	0.62
158.8221741	0.25
161.048645	1.39
163.0007019	1.09
165.1621704	0.35
169.1187439	0.81
170.1223907	0.08
171.051712	0.11
173.0511169	0.81
175.0895538	1.20
177.0800018	0.43
183.2345123	0.93
187.1270294	1.13
189.0097351	0.36
190.9854736	0.30
192.8582306	0.30
194.9896698	0.29
197.1061859	0.29
199.0447388	0.45
201.127655	0.31
203.024231	0.67
205.2675629	0.83
210.9117737	0.56
217.1300659	1.30
218.9692688	0.23
223.268158	0.16
225.079071	0.57
229.1309814	0.10
231.1272888	2.28
239.274353	0.17
240.8108215	0.21
243.1273193	0.17
245.2858582	0.71
247.1897278	5.29
249.8594971	0.10
253.0701599	0.90
255.543396	0.16
256.3714905	0.12
257.306488	0.52
259.2010498	0.55
260.3668213	0.54
261.3838501	0.27
262.2259216	0.22
263.0910034	0.19
267.2735901	0.58
271.2619019	0.33
277.0746765	0.29
279.2712402	0.32
281.5281982	0.08
283.0778503	0.31
285.2467041	0.31
287.4830933	0.14
293.8300171	0.20
295.4505615	0.40
297.4402161	0.36
299.2357178	0.89
300.3613892	0.45
305.1734924	2.93
309.0922852	0.12
313.2426147	0.19
317.8945923	0.31
323.2341919	100.00
323.9250488	0.14
324.6334839	0.12
325.3129883	0.22
341.3785095	1.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	570.2602
Annotation	Unknow
Peak:m/z	Relative Intensity
196.2362061	0.03
209.4233704	0.04
260.8522949	0.04
287.7185669	0.04
315.3731079	0.07
318.8128662	0.13
326.1730957	0.05
328.2657471	0.13
330.4859009	0.05
331.4317627	0.06
332.2615356	0.05
337.1301880	0.08
341.2939453	0.07
342.3397827	0.11
345.4562378	0.03
349.2153320	0.03
358.5532227	0.10
360.7224731	0.03
371.2686768	0.12
374.1485596	0.13
380.2723999	0.04
400.1965332	0.09
407.5455933	0.05
415.2338867	0.06
430.2903442	0.05
434.3341064	0.11
447.2890015	0.06
468.0352173	0.03
482.2231445	0.16
484.9973755	0.05
491.1921997	0.07
494.1970825	0.17
499.5620728	0.05
509.3607788	17.40
510.2667236	0.04
512.7917480	0.03
515.3156128	7.68
516.3373413	0.05
517.9370728	0.04
524.0945435	42.58
524.9060669	0.52
526.3314209	0.71
532.1647949	13.91
532.7733765	0.17
534.4169312	0.58
535.4868774	0.19
536.1870728	0.04
538.1875610	3.17
539.3272095	0.23
541.1078491	0.16
544.0170288	0.03
547.0930176	100.00
547.7351685	0.96
548.9994507	1.34
549.7620239	0.38
550.7610474	0.36
551.4271240	0.16
552.1856079	0.40
553.1526489	0.34
554.0443726	0.04
555.3563843	0.22
556.9227905	0.19
558.2073364	0.04
723.6319580	0.09
741.7028198	0.29
753.3582153	0.07
857.3816528	0.04
869.4514160	0.60
873.4541626	0.71
881.5202637	0.06
885.2629395	0.05
887.4755859	1.14
888.5021362	0.08
899.7252808	0.12
903.3113403	0.13
1019.4894410	15.62
1020.5619510	0.59
1031.5429690	4.97
1032.5593260	0.23
1048.9135740	1.07
1049.5234380	13.50
1050.4244380	0.39
1066.3077390	0.20
1094.6370850	0.02
1095.4392090	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2874
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
125.9423828	4.58
140.9375153	5.15
173.1539764	9.91
177.2132874	9.60
189.1426697	3.45
190.9587708	2.88
208.7260132	9.10
213.1122284	6.28
227.4271851	3.45
239.0239868	9.97
273.2568054	9.44
275.7188416	4.79
281.1351013	11.58
294.2479553	4.31
305.5191956	8.86
307.4949646	2.89
319.0583496	7.47
326.3369751	4.04
327.1901855	4.58
335.1515808	4.30
343.2194824	4.78
356.5384827	10.25
359.017334	17.63
367.6920776	6.80
369.0859375	6.59
374.2626038	10.75
380.079895	2.59
382.176178	12.28
383.2634583	3.96
389.524353	3.74
390.7741394	44.28
395.288269	13.46
408.2792358	100.00
409.2935181	41.54
412.2176208	6.49
417.2898865	14.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.287
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
121.0074234	20.23
171.0530396	10.91
172.8890076	2.85
239.284729	6.05
245.1060486	22.81
252.2739868	4.50
256.072937	4.89
260.3792114	2.27
264.8005676	2.55
265.4760132	5.49
267.2381592	7.80
268.1524658	10.00
273.2652893	6.34
281.4873047	19.12
299.2991333	8.94
305.1540527	6.10
313.9893188	18.13
315.5510254	7.90
318.1422119	30.96
321.0336609	3.61
328.2347412	5.96
330.1169434	12.56
333.3525085	11.16
337.0857849	2.86
337.9797363	4.32
339.3249512	6.05
351.1726685	6.05
353.2156067	8.07
366.3865051	10.86
370.5508118	8.94
372.917572	8.70
373.58255	24.24
380.0866394	8.99
381.684906	9.25
384.9819031	22.66
390.2499695	6.04
391.3543091	16.88
392.0457153	5.74
398.4831238	3.74
407.1255798	10.28
408.2806091	100.00
409.3925781	41.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.74
Annotation	Unknow
Peak:m/z	Relative Intensity
206.6354065	0.37
207.2709045	0.03
237.2410583	0.03
258.8556519	0.03
274.8829651	1.33
290.8291016	2.04
306.9937134	0.06
342.7946167	0.11
358.7416992	2.50
374.9204712	1.10
380.8454590	0.05
383.1199951	0.15
397.1420288	0.09
399.1196289	0.06
400.2044067	0.04
414.8867188	0.09
420.3556519	0.12
426.6974487	9.33
439.9258423	0.39
440.5325317	0.06
442.6033325	17.71
443.4196777	0.23
448.4039307	0.12
457.0371094	0.19
458.1075439	1.28
458.8327026	2.09
508.1151733	0.07
508.7943726	0.07
510.5910034	100.00
511.4315186	0.15
526.5863647	6.98
547.8999023	0.88
548.9594727	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1481
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
175.1161194	0.29
201.0075378	0.76
204.7134552	0.14
231.0097809	0.32
233.2514648	0.15
243.2939758	0.35
247.0653381	10.13
249.1442566	0.34
259.2003784	2.59
261.9147034	0.13
271.1947021	2.19
273.0848389	0.24
275.0411987	3.28
283.1833496	0.43
287.0706787	2.73
289.0946960	16.01
291.1394958	32.03
299.3303833	0.40
301.1152954	13.87
303.1610107	4.83
313.1523132	0.84
315.0007019	1.07
333.3680420	0.23
351.2418823	0.26
368.0722656	0.29
381.2910767	0.41
399.0813599	0.36
409.2038574	48.99
411.1946411	12.75
416.1813354	0.21
419.3553467	0.14
420.7778320	0.88
421.5008545	0.91
423.1096191	0.29
427.0556030	100.00
427.6832886	0.60
435.2152100	2.57
439.0996704	5.77
451.2129517	0.54
453.0816650	5.77
469.4282837	0.50
489.7516479	0.35
516.5083618	0.23
534.1002197	0.22
538.1678467	0.12
543.3872681	1.45
550.1547241	0.35
560.9725342	4.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	606.74
Annotation	Unknow
Peak:m/z	Relative Intensity
261.0653381	0.19
267.0325317	0.10
271.1260071	0.12
273.0801392	0.45
282.0490112	1.99
287.1893921	0.06
300.0988159	0.37
301.0144348	0.11
305.1222534	0.25
308.9660339	0.29
311.0014038	0.05
323.1208496	0.98
324.1154785	0.18
350.3778687	0.18
354.8829956	1.89
362.1345215	1.61
363.1878662	0.29
370.8986816	0.61
385.1295776	6.16
386.1459961	0.52
394.8753052	0.12
403.1087036	2.65
404.0958862	0.64
411.0102539	0.08
426.7916870	0.04
430.5982056	0.07
431.9732056	0.51
433.0642090	0.76
434.5932007	0.08
436.4669800	0.04
438.7333984	23.94
442.9931030	0.18
450.8962402	0.68
454.7798462	2.70
470.8338623	0.32
494.1611328	0.19
508.3734131	0.12
509.2087402	0.17
516.4574585	0.13
520.0592041	0.28
520.9231567	0.27
522.6549683	100.00
538.1203613	0.47
538.7241821	2.31
559.9013672	1.12
560.9706421	0.20
588.3064575	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	217.03
Annotation	Unknow
Peak:m/z	Relative Intensity
71.1167068	0.04
86.9665375	0.14
88.9056702	1.78
100.8652954	0.32
106.9942474	0.17
107.8804932	0.07
113.0228424	0.83
118.9819031	2.58
121.1074677	0.05
124.9906006	0.03
126.8769379	0.17
131.0720062	0.87
142.9658661	2.51
144.9557343	0.06
148.9912567	0.48
155.0341797	0.04
160.9663696	7.16
161.8769531	0.23
162.9284210	0.36
173.1832581	0.19
177.2364655	0.06
178.9460297	100.00
179.9965973	1.73
181.0407562	4.46
186.1018829	0.04
199.1360779	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0711
Annotation	2859-88-3
Peak:m/z	Relative Intensity
104.8450775	0.72
148.8861389	2.05
164.9265747	0.48
169.2073212	0.88
178.2229004	0.25
179.421936	1.63
180.1102753	0.55
180.8972626	0.54
182.1375732	0.24
185.2666168	0.48
193.2044525	0.88
195.3111115	0.45
205.1380768	0.30
206.1059418	1.51
207.1156158	10.68
208.1018829	5.79
209.0588837	3.11
222.1879883	5.45
223.107254	14.29
224.2653046	0.95
251.0616608	100.00
252.0872955	14.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.1084
Annotation	Taxicatin
Peak:m/z	Relative Intensity
90.86924744	0.18
107.7327042	1.40
108.9933319	2.02
122.0197906	0.54
123.0282593	4.42
134.9900208	0.64
151.8313599	0.20
153.0613098	100.00
175.1043701	0.18
183.2693024	1.01
184.0377502	0.35
219.1342163	0.32
223.1891174	0.81
224.7730408	0.35
240.7727356	0.20
243.384552	0.15
244.0758057	0.23
269.255188	1.72
273.2142029	0.32
280.2350769	0.33
295.4801331	0.15
297.2849121	1.05
298.1920166	0.26
300.2318726	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0901
Annotation	Glutathione
Peak:m/z	Relative Intensity
116.0285187	0.29
117.9775391	0.50
143.9987488	0.90
144.8609314	0.83
145.9503937	2.16
152.7832642	0.13
160.9838257	0.15
161.9388733	6.70
163.1070557	4.58
163.9931488	21.22
178.9420013	21.21
179.9801941	18.08
181.0439453	100.00
189.2626953	0.11
199.9202271	0.34
204.9807434	0.11
206.4655151	0.06
217.0505981	0.43
232.8798828	1.49
234.0239258	3.18
235.0577087	19.59
244.0826416	0.14
245.0211182	0.13
246.3505859	0.36
247.0111694	0.78
263.9398804	0.39
268.4787903	0.09
272.0367432	0.17
274.0177002	1.96
290.1993713	0.63
291.3268738	1.69
292.1128540	10.13
293.0876160	1.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	271.0822
Annotation	Arbutin
Peak:m/z	Relative Intensity
91.1399612	0.08
96.8452759	0.62
100.9446564	0.08
108.9183197	100.00
118.9351959	0.29
124.1850433	0.11
128.0136719	0.08
137.1632233	0.29
139.0861206	0.26
143.0946350	0.07
151.1210632	0.29
152.9785004	0.09
161.2595367	0.21
165.1879120	0.09
183.2547607	0.17
184.1030884	0.06
189.2353821	0.15
192.8957214	0.12
199.3017731	0.63
200.3107910	0.06
203.1539154	0.22
222.9417725	0.07
225.0801239	0.94
226.9688110	1.01
235.1068115	0.09
253.0823975	1.26
254.7534180	0.10
256.2571106	0.16
271.2397156	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.2678
Annotation	Grandilobatin A
Peak:m/z	Relative Intensity
104.7628326	0.57
106.9169159	0.36
108.8144226	0.23
111.0436859	0.44
113.8223877	1.01
119.2337036	0.80
121.3276138	0.19
122.7859955	0.64
125.0457687	1.13
130.9463806	0.92
133.0406799	0.48
135.1239319	2.06
137.1172638	2.40
138.8500824	0.63
145.2631226	0.27
147.0263672	1.16
149.0585938	1.60
151.0048218	0.49
157.0815735	0.38
159.0715942	2.06
160.9798279	2.42
163.006485	1.82
167.9116821	0.52
168.9163513	1.45
170.9941864	0.19
173.1369629	5.10
175.1721649	1.31
177.141098	2.17
179.2525024	2.01
181.2313232	0.36
184.7102966	0.80
187.2324829	2.50
191.1842651	0.59
198.8906555	0.36
201.2145233	1.21
203.1640015	0.23
208.1188812	0.16
208.8504181	0.60
212.0885162	0.29
213.1202393	0.38
215.2027283	1.29
216.7568359	0.34
219.4502563	1.29
221.1548767	0.19
222.0314331	0.73
226.9860229	0.74
233.1905518	4.57
234.3313904	0.66
235.262146	0.89
239.2957458	0.88
241.1388855	1.41
243.1615295	28.65
243.7626343	0.33
245.0125122	1.78
250.9758301	0.58
257.1036987	0.85
259.071991	0.81
261.2973633	100.00
263.3641968	3.77
265.4200439	0.44
268.9088745	1.34
270.653717	0.53
273.4291992	0.87
277.1767578	0.57
279.2237549	12.06
281.4416504	1.00
285.0516357	0.21
287.3743591	0.58
289.6603088	0.51
290.6165161	1.25
291.4770203	0.27
292.9871826	0.61
294.5640869	0.26
295.3105469	0.29
297.3072205	1.33
299.3823853	1.34
307.2098389	1.63
309.3831787	0.25
311.1378174	1.45
311.98526	0.91
312.9390259	1.69
317.3716736	5.07
321.2284851	0.48
324.6894226	0.72
325.7037048	1.72
335.267334	70.14
336.3500671	0.25
344.3066101	0.54
352.4382019	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
135.0358429	0.02
140.1841125	0.10
152.911438	0.18
166.1428528	0.02
196.070816	1.88
209.9822693	0.02
214.1160278	0.90
222.1898804	0.04
227.0946045	0.07
255.231842	100.00
255.8473206	0.16
263.1027222	0.02
264.293335	0.02
265.1602173	0.04
265.954071	0.02
268.1377563	0.05
272.4613647	0.04
281.5383301	0.03
331.6192017	0.02
333.2790222	0.02
347.1401367	0.11
349.4351501	0.07
364.2930298	0.05
384.3069763	0.07
389.3644104	0.04
391.3126526	0.24
395.2845764	0.02
406.124115	0.06
406.8832703	0.07
408.1242676	0.18
414.0672607	0.02
415.9564819	0.13
429.7216492	0.11
433.8672485	0.17
435.0066833	0.09
437.39328	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
98.87664795	0.24
107.0364761	0.23
113.1094055	0.42
121.0387115	1.46
123.0737305	0.32
135.0181732	2.02
141.208374	0.52
143.0671234	1.28
147.2055054	0.48
149.1515808	0.83
159.3126373	0.21
160.266571	0.93
163.2405396	1.35
165.0410309	0.30
172.8145142	0.59
175.2376404	0.76
176.7402649	1.05
178.9655762	0.75
182.129776	0.32
188.9684448	0.69
191.4673157	0.17
193.0148315	0.34
199.163208	1.99
203.1839752	0.23
206.8490601	0.49
209.177887	0.26
211.0317688	0.25
213.1023254	0.84
217.0993042	1.22
225.2771301	0.19
226.9671021	0.32
229.3170471	1.24
235.0976868	1.88
235.8093872	0.95
238.0993652	0.97
241.2297058	0.74
245.1664734	0.89
247.1696472	1.07
251.1921082	0.51
252.2097168	0.73
253.4196472	0.57
257.271637	0.78
269.2167969	1.13
270.3542175	0.34
270.9603577	0.42
279.3200073	1.21
280.9693604	1.54
283.1700439	0.76
285.7772827	0.91
287.4978943	0.19
294.5732422	1.11
295.2134094	3.26
297.2658081	0.28
298.7971802	0.98
300.8569031	0.34
305.2605591	4.03
313.3189697	1.63
315.0504761	0.40
318.839325	0.63
323.2323914	100.00
323.9598389	0.68
341.2184753	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	Gerfelin
Peak:m/z	Relative Intensity
84.9712067	0.08
96.9900360	0.35
100.7966232	0.09
107.9221191	0.14
109.0349884	1.00
109.9404221	0.16
121.1509552	0.11
123.0832138	0.84
124.9917068	2.77
130.8526001	0.08
135.2211609	0.25
136.9505310	3.09
139.0635223	0.38
145.2309265	0.03
147.0032501	0.16
149.1717529	0.17
151.0642548	1.64
152.1004333	0.15
159.1329651	0.45
161.0259399	2.20
161.9060364	0.25
163.1413879	0.16
163.9712067	0.80
165.0127716	2.58
167.0954895	1.50
169.0363464	0.05
170.1952057	0.03
173.0607300	0.06
173.9565277	0.09
174.9811401	0.80
179.0540466	11.12
180.0757904	0.11
183.0223694	0.15
184.1754456	0.05
184.9856262	0.31
186.0419312	0.57
187.0662537	1.21
188.0867004	0.82
192.9548950	0.06
199.1611938	0.17
201.1280518	0.85
202.0148010	0.47
203.1211243	7.13
205.0931702	35.10
206.2144165	0.06
209.2908325	0.12
212.2263184	0.16
217.1573181	0.88
221.2608337	0.07
227.1525269	1.50
229.1660156	0.15
231.0688171	7.00
240.9266968	0.09
242.0522461	0.18
243.0286865	0.18
245.0616760	100.00
247.0664368	4.57
253.0937805	0.34
259.2957458	0.10
271.1209717	7.94
274.0904541	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
51.6593475	0.08
122.8874359	100.00
123.6098175	0.05
151.2059631	0.03
189.1378479	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2883
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
147.078186	3.36
171.1088257	6.01
172.8755493	6.95
203.2491455	5.17
206.9208069	4.94
209.5128479	3.36
215.086853	3.36
227.1715393	26.00
236.9935608	5.64
239.4189148	18.56
253.311615	7.86
261.420929	3.81
265.2880249	13.32
283.4225464	8.39
311.3102417	5.09
317.0541382	3.62
334.0750732	3.08
337.3571167	5.74
339.196228	8.87
341.1447754	4.41
359.0852051	17.47
368.5084534	3.63
377.0140686	11.90
385.4055786	15.84
387.3486633	3.26
388.1405945	3.76
389.4457703	2.30
390.8473511	15.18
394.243927	21.41
395.3824158	24.26
397.9567566	3.61
406.3401184	3.28
407.1016846	6.50
408.2718811	100.00
409.3991699	24.34
416.7762146	18.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2784
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
139.0629272	0.08
140.2797089	0.07
150.915802	0.04
194.8404846	0.04
195.9606781	1.48
197.0006104	0.04
200.9181824	0.43
210.5362549	0.08
214.1148376	1.30
215.0482941	0.09
219.0443878	0.18
242.8719482	0.04
255.235199	100.00
256.2836609	21.17
257.0310364	0.08
261.4253235	0.08
279.1591187	0.05
283.1729431	0.08
286.9734192	0.03
299.0188293	0.08
304.1621704	0.11
305.3076477	0.05
312.8285828	0.10
324.1625977	0.06
327.0249023	0.23
339.4124756	0.04
349.276123	0.03
365.2752075	0.06
367.1263123	0.14
375.1296692	0.04
389.2294312	0.09
391.0725403	0.26
392.2748718	0.20
393.3855896	0.11
394.1113281	0.04
395.3595276	0.07
397.3076782	0.03
407.3589783	8.06
408.5184326	0.21
409.2458801	0.66
410.3022461	0.12
410.9444275	0.05
416.1860046	0.11
417.2623596	0.49
418.3551331	0.05
429.260498	0.11
433.0275269	0.24
434.497406	0.31
435.4230347	0.59
436.2842712	0.15
438.5104675	0.05
439.4743347	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0928
Annotation	1-beta-D-Glucopyranosyloxy-3-methoxy-5-hydroxybenzene
Peak:m/z	Relative Intensity
94.89984894	0.30
101.1218567	1.58
109.0590668	0.33
112.8428268	0.48
120.9613495	5.72
124.1445465	2.83
139.0393372	100.00
142.9363403	1.34
151.0643311	0.48
160.9519043	5.50
166.9989319	0.87
167.903656	4.84
175.0930786	0.57
180.9781342	0.51
197.0343628	1.06
202.8264465	0.48
215.0368652	0.42
217.0805664	2.22
255.0908813	7.32
259.2922974	0.50
271.3591919	1.16
283.1750793	4.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
100.9154968	0.07
107.8296814	0.80
112.9775162	1.64
114.9921494	0.15
118.9050674	0.09
121.1929626	0.13
122.9504471	4.66
125.0690918	0.15
142.9301910	0.29
149.0052490	1.44
149.9655762	0.24
151.9331055	3.69
160.9307861	0.36
162.0357819	0.16
164.8018494	0.10
166.9705353	95.64
171.3330383	0.10
173.0944519	0.18
178.8665161	0.53
180.9685974	11.91
189.0158539	0.04
190.0363312	0.14
191.1157532	0.31
193.4876251	0.47
194.1019592	0.78
195.1985931	0.06
207.1011658	0.21
209.1290283	100.00
219.1021729	0.15
220.9895630	1.38
233.0763855	0.90
235.1668396	0.26
239.0368652	11.38
242.4338684	0.10
257.2362976	0.28
263.0990601	1.10
267.2641602	0.16
269.1329956	39.28
270.4473877	0.15
283.3740845	0.16
285.2884216	1.22
285.9317017	0.09
292.8507080	0.56
311.2056274	1.87
314.1898804	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0981
Annotation	3-Methoxy-4-hydroxyphenylglycol glucuronide
Peak:m/z	Relative Intensity
106.0340195	0.09
112.9160309	1.21
113.7828217	0.07
119.0577240	0.24
121.0082703	1.65
122.0541763	0.36
123.9900742	0.07
138.0427246	0.84
138.9369965	0.25
143.0038757	0.19
147.0417938	0.11
148.7455139	0.09
151.1408691	0.23
152.9544067	4.99
154.0402527	0.67
156.0412598	0.06
161.0587158	0.04
165.0074463	0.41
166.2438354	0.18
167.2597656	0.04
173.1472931	0.07
174.8286133	0.05
176.2703247	0.08
178.9232788	0.24
180.0938110	0.56
181.0723267	0.49
182.0621490	2.36
183.3119812	0.16
184.1877441	0.18
191.0577087	0.14
193.2862396	0.04
195.0793152	1.13
196.9861298	100.00
198.1139679	15.43
211.0647430	12.97
212.1439667	2.30
219.9213562	0.05
224.0176697	1.04
225.1658020	0.45
236.0031738	0.05
239.0493774	93.13
240.1445312	22.00
249.2357178	0.56
251.1925659	0.47
252.0989685	0.57
252.9167175	0.12
254.2264404	0.10
257.5090942	0.04
263.1756592	0.40
266.2648315	0.06
267.2548523	0.07
269.0671082	12.20
270.1251221	4.03
272.1616821	0.07
273.0181885	0.18
281.0241089	0.54
282.2799072	0.30
284.3165588	0.16
285.1741333	0.07
286.1892090	0.07
293.2126465	0.77
294.2236023	0.05
299.1528320	27.89
300.1690063	10.10
301.9219666	0.07
309.2734070	0.14
313.9313660	0.30
316.0534058	0.41
317.2626648	0.13
323.1904907	0.13
324.3361206	0.04
332.2165527	0.07
341.0892639	0.33
342.0722961	0.28
343.0480652	0.05
344.2113953	2.78
345.2332153	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
67.1139755	0.03
84.8420715	0.26
86.9197998	1.20
100.8284607	0.05
110.8864746	100.00
111.6797028	0.02
127.8256073	0.03
128.9748688	2.25
130.9205170	1.36
147.0188141	0.23
154.8682251	0.36
172.9571991	19.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
81.97349548	4.55
109.9163361	1.71
140.9328613	4.19
149.8391418	1.53
150.9395905	4.57
162.6276093	1.39
170.0363007	1.38
173.8954315	1.39
177.7707367	1.71
178.8957977	1.17
180.0983582	5.76
180.9689789	1.38
183.1145935	3.56
189.8823547	1.60
192.1968079	2.25
193.2568817	1.40
194.0807495	1.28
195.112381	8.54
197.2994232	2.83
205.9942474	4.93
207.184967	24.24
208.0535583	27.67
209.3121643	22.74
215.0027008	3.83
217.2608795	1.62
221.973114	2.91
223.1139679	17.59
224.2064667	10.87
225.2506714	2.25
233.161377	18.15
234.2336426	5.30
251.0704193	100.00
252.1143341	88.23
253.1392975	4.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.9
Annotation	Unknow
Peak:m/z	Relative Intensity
173.1974182	0.03
199.2363892	0.08
217.0352783	0.03
229.0367737	0.18
272.9590454	9.03
274.1196289	2.24
274.8732910	0.07
289.1343079	0.02
290.9139099	0.03
387.0198364	19.78
388.0924072	6.79
459.0877075	0.09
460.1970215	0.01
461.1399536	0.06
461.8714600	0.01
469.8613892	0.02
471.0864258	0.03
499.1113892	0.17
500.9201660	100.00
501.8722534	53.24
502.6138916	0.08
504.9457397	0.03
514.4909668	0.02
515.6463623	0.01
524.6250610	0.06
527.1337891	0.04
529.9346924	0.03
541.3245239	0.05
541.9865112	0.10
559.0335083	0.01
568.8676147	0.38
569.7853394	0.11
571.0176392	0.13
572.0936279	0.18
574.1028442	0.05
583.0251465	0.06
588.6851807	0.03
596.8168335	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.2736
Annotation	Betaenone F
Peak:m/z	Relative Intensity
175.1837158	2.13
192.9944763	1.03
208.982605	0.83
215.5618286	1.63
247.0439758	2.80
261.3843689	1.86
289.0582581	1.33
294.9354858	2.13
318.2520447	3.53
320.690979	2.43
323.8126526	5.88
334.303894	1.60
337.2394104	3.73
341.559082	1.63
345.0864563	1.82
352.4094849	5.73
353.4560547	2.92
375.2627258	1.62
379.3634338	4.43
393.2705078	100.00
394.4907227	1.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.9916
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9097366	7.01
132.8982391	100.00
140.7781982	0.06
155.1348572	0.07
171.0943298	0.05
195.0579376	0.06
200.7208862	0.45
203.8660583	0.05
214.7593994	0.07
218.1537781	0.07
225.1756287	0.03
231.0616455	0.09
232.9541321	1.33
234.8965759	0.05
240.9816589	0.07
242.8992310	0.84
244.9743347	9.95
246.9503174	0.08
250.9031372	0.05
258.1438293	0.07
259.1345215	0.17
260.0135803	0.09
285.0916138	0.19
286.3404541	0.25
287.0385132	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.0601
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9605560	0.78
101.9987640	16.08
130.0266113	100.00
130.9847717	2.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0968
Annotation	(2S)-2-azaniumyl-3-(1H-indol-3-yl)propanoate
Peak:m/z	Relative Intensity
70.82137299	0.02
87.29678345	0.01
95.84257507	0.03
96.91429138	0.01
97.91213989	0.02
100.978653	0.01
108.989624	0.03
110.9969482	0.01
115.0531769	0.06
121.1817322	0.03
126.8938446	0.08
132.0292358	0.09
132.9266815	0.23
134.9078522	0.05
139.0560455	0.07
143.9668121	0.01
145.2719421	0.06
149.1372681	0.14
150.9532318	0.02
158.9810333	0.44
160.9834442	0.08
162.1076355	0.03
162.9769592	0.05
163.8737335	0.03
168.9444427	0.14
175.1425171	0.02
177.0335236	0.09
188.0792389	100.00
189.9513245	0.03
195.8288116	0.03
204.9064331	0.01
207.8547668	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.91
Annotation	Unknow
Peak:m/z	Relative Intensity
201.1088715	0.07
202.9924316	0.03
244.7999878	0.14
273.0569763	1.14
274.1037598	0.41
275.0020752	0.13
275.7484741	0.04
331.0571289	0.08
359.6329956	0.11
386.7915649	0.22
404.2247314	0.06
405.1638184	0.13
427.1292114	3.20
428.1425171	1.62
428.9610596	0.96
430.1885986	0.61
431.0300293	0.30
433.2493286	0.16
433.9570923	0.14
443.2379761	0.09
457.1530151	0.04
470.7017212	0.19
471.9342041	0.73
472.9616089	3.69
474.0628052	1.70
475.7592163	0.04
485.1724243	0.15
486.2126465	0.07
500.0635376	0.35
502.0746460	0.06
504.0645752	0.06
513.8688965	0.16
514.8193970	0.07
525.5899048	0.11
529.1626587	0.11
530.8695679	0.13
531.8578491	0.13
540.8907471	100.00
541.8919067	50.84
542.8835449	0.29
543.8359375	0.33
546.0879517	0.09
546.9100342	0.07
559.4324951	0.09
560.1771851	0.07
568.8738403	0.60
569.7877808	0.09
587.6978149	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	603
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.9118195	0.06
181.9580078	0.09
192.6867981	0.08
194.9810638	0.07
196.9334259	0.05
211.0162964	1.09
215.0618591	0.48
217.1831665	0.05
223.1790161	0.06
233.0418396	0.45
241.0977936	2.39
251.0281830	0.08
256.9763184	0.26
259.1515503	0.39
261.9980469	0.12
264.7631836	0.39
278.8677063	0.04
279.9568481	1.13
287.0567627	0.11
293.1127319	0.13
298.6145630	0.06
310.0278931	0.11
317.0905762	0.25
318.0776367	0.42
323.1616211	47.21
329.0057983	1.21
334.0782471	0.40
346.2041626	0.10
348.8880005	0.54
349.7692261	0.31
350.7326050	0.27
352.2120361	0.18
359.1193237	2.60
360.9912720	0.11
370.4671631	0.07
371.8640747	0.29
377.1977539	3.59
380.0888062	0.45
381.1417236	0.07
388.4150391	0.09
406.2415161	0.17
412.8684082	0.04
419.1283569	0.60
423.0633545	0.85
424.1531372	0.36
428.8233643	22.64
429.4387817	0.10
430.8490601	0.15
432.7083130	1.05
434.7224731	1.09
440.2294922	0.73
441.0895996	16.66
446.1776123	0.22
446.9027100	0.33
448.2448730	0.10
449.1248779	0.50
450.5211182	0.24
452.4142456	0.69
453.3988037	0.23
458.1477051	0.31
462.3389282	0.09
466.7524414	50.51
467.9033813	1.57
470.1214600	3.20
473.1861572	0.05
483.1519165	14.90
484.7868042	0.22
485.9396973	0.11
488.1077881	1.14
491.1386719	1.96
494.9314575	0.08
500.0020752	0.08
504.9570312	0.45
509.0001221	0.17
516.2071533	0.05
516.8682251	0.98
518.7468872	100.00
519.8510742	0.37
523.9142456	0.90
534.7835083	5.60
539.4400635	0.07
542.1838989	0.12
556.8686523	1.20
560.0421143	27.00
560.6909790	0.22
585.0906372	9.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	189.0041
Annotation	Oxalosuccinic acid
Peak:m/z	Relative Intensity
56.9440651	0.11
70.8173828	0.13
72.9740601	5.99
82.9467316	3.27
98.9777985	8.90
100.8214722	0.30
113.0847321	0.07
116.8585205	3.80
126.9235535	100.00
142.9383698	20.34
143.9409332	0.03
144.9951935	1.19
159.1021423	0.07
160.7514648	0.10
165.6608276	0.03
168.8274078	0.02
170.8697052	6.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.97
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0206604	0.09
201.9364624	0.11
237.8220825	0.09
286.1667480	0.05
303.0658569	0.03
304.1152344	0.35
308.0983887	0.03
323.9282837	0.04
330.0455017	0.16
331.8875732	0.49
344.2677612	0.05
347.9380188	0.94
367.0563660	0.12
375.8424072	0.09
393.9814148	100.00
394.5993958	0.18
402.0337830	0.06
419.1820374	0.81
420.0347290	1.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0882
Annotation	6-Hydroxytricetin 5-rhamnoside
Peak:m/z	Relative Intensity
151.0163269	0.79
153.0969849	0.06
161.0273895	0.08
169.3066101	0.02
171.0747375	0.05
179.0391998	1.07
187.1718750	0.06
189.0157318	0.17
190.0032349	0.14
190.7692566	0.05
191.9129639	0.03
192.9747925	0.09
195.1603088	0.02
196.9381409	0.02
201.1362152	0.05
207.0718384	0.14
209.1151123	0.05
213.2359467	0.09
215.1655426	0.05
221.0484009	0.13
228.0215759	0.02
228.9371948	0.32
231.0510559	0.07
232.9761963	0.02
236.7321625	0.03
239.3554688	0.07
242.2647247	0.05
245.2673950	0.02
247.1567688	0.04
254.1280212	0.02
255.1586609	0.32
255.9886169	0.19
257.0924072	0.08
271.0595093	0.42
272.1133118	0.07
273.1616211	0.32
282.3120422	0.11
283.2051392	0.09
284.1432190	0.04
285.2183838	0.05
293.0845642	0.05
294.0220337	0.03
297.3169861	0.10
299.1237183	0.70
300.0946350	22.98
301.0668335	100.00
302.1402893	0.39
309.2319336	0.04
311.0685425	0.05
313.2324829	0.11
319.3799438	0.10
325.0818481	0.29
330.9891357	0.07
337.0505371	0.14
341.2344971	0.09
343.1533203	1.91
344.3391724	0.11
346.4502563	0.03
348.1356201	0.04
354.2959900	0.05
367.2326660	0.44
369.1058350	0.09
373.0886536	0.23
375.3207703	0.07
381.2001038	0.02
389.3354187	0.03
397.0612183	0.05
403.0414429	0.12
403.6480408	0.03
416.7566223	0.11
417.3935547	0.09
418.1059875	0.06
419.3672791	0.05
425.0102234	0.11
426.4293213	0.04
427.4052429	0.06
435.3781433	0.10
445.2407532	0.86
462.7122498	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	968.14
Annotation	Unknow
Peak:m/z	Relative Intensity
321.0997620	0.36
406.0435486	0.20
487.3650513	0.47
504.5214844	0.44
585.0137939	0.15
612.2652588	0.92
626.1848145	1.05
817.8229370	0.17
920.5293579	3.37
938.2053833	0.38
942.9766235	0.37
948.4164429	1.65
951.4784546	0.72
952.2182617	0.28
1057.6918950	1.06
1059.8236080	6.32
1064.1309810	2.64
1066.7900390	3.26
1067.4625240	3.01
1075.5545650	4.91
1080.1784670	4.11
1081.6923830	2.83
1087.1660160	3.46
1088.0933840	1.69
1090.6159670	3.11
1091.6875000	5.17
1093.0546880	3.66
1094.0316160	5.20
1098.8330080	3.04
1101.7332760	2.68
1102.4759520	3.54
1105.3865970	3.66
1107.1845700	5.66
1110.0010990	6.36
1110.8654790	7.43
1112.9481200	0.49
1186.6660160	2.29
1187.9844970	0.78
1195.9436040	1.49
1223.7246090	2.55
1253.9638670	2.35
1256.6208500	1.58
1258.2244870	3.74
1260.7052000	1.63
1263.7390140	1.70
1264.4124760	0.88
1273.9860840	1.68
1276.5607910	1.21
1278.2650150	2.45
1286.7054440	2.42
1295.8482670	2.14
1299.3056640	2.14
1304.6268310	0.30
1315.1441650	1.70
1318.1654050	0.55
1320.0056150	0.72
1346.7539060	3.50
1363.4276120	0.61
1373.1212160	0.83
1376.3582760	0.69
1403.0004880	2.47
1426.2437740	1.52
1428.9324950	2.13
1434.0518800	2.97
1452.1912840	0.82
1457.8878170	1.18
1504.5699460	3.19
1509.1165770	2.49
1531.9533690	2.63
1540.7611080	0.66
1550.9683840	2.70
1559.5197750	2.00
1567.9622800	1.32
1571.2476810	2.48
1574.0250240	0.49
1575.2155760	0.55
1585.9943850	2.60
1603.0622560	2.93
1603.8477780	0.90
1615.9394530	0.32
1666.8674320	1.17
1691.7116700	2.06
1733.4737550	0.29
1743.5479740	2.35
1767.0142820	0.22
1773.3054200	3.37
1790.4005130	1.25
1807.5909420	0.19
1822.2410890	1.88
1826.0183110	0.13
1834.9304200	0.25
1849.3695070	0.21
1854.8321530	0.17
1857.0783690	0.63
1874.7906490	0.24
1893.2620850	1.44
1894.1594240	0.79
1901.7492680	9.71
1908.1871340	0.32
1916.7888180	0.86
1919.1414790	1.08
1923.1219480	56.70
1926.8629150	0.19
1930.9722900	0.73
1932.8167720	4.15
1934.0628660	21.57
1935.5303960	100.00
1936.8460690	0.42
1938.9383540	0.46
1939.8814700	0.22
1941.1602780	2.69
1949.0256350	0.48
1951.4798580	0.70
1957.3260500	0.58
1959.3336180	0.17
1962.2481690	15.77
1965.2916260	0.30
1967.3785400	11.06
1968.2445070	0.90
1970.2615970	2.11
1973.3087160	24.90
1979.5876460	4.82
1980.9776610	4.43
1985.0518800	21.67
1988.1688230	15.59
1989.5831300	3.42
1991.5426030	58.15
1995.6258540	0.96
1996.9300540	22.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.2628
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
81.03829193	1.84
83.10396576	0.65
94.84706116	2.84
97.17736053	1.02
101.0481873	1.71
109.1559448	0.56
110.992569	4.74
112.9478912	3.40
121.0703506	0.80
122.9605865	1.33
126.9734726	0.68
129.0086365	0.89
135.0212402	4.29
136.7381287	0.37
141.2275085	0.52
149.1564941	7.40
152.9235229	1.47
155.0136414	1.87
157.1411438	4.91
160.9878693	2.67
163.3890381	1.51
165.070816	2.34
168.6873474	1.73
171.1360474	2.62
177.1374969	2.95
179.4420166	0.78
183.0556946	1.30
184.9413147	2.81
191.4176788	1.27
198.9945679	7.52
209.296936	2.98
211.0517578	0.51
213.2511902	1.98
225.0725098	1.33
227.0513611	5.83
237.2530518	0.65
239.1705627	0.84
240.274292	1.01
241.1895752	2.03
241.8290405	0.92
244.9713135	1.16
247.2356567	22.37
248.246582	1.76
255.3158264	2.81
265.2609253	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.182
Annotation	Unknow
Peak:m/z	Relative Intensity
145.3081665	0.09
146.0303497	0.07
149.0375671	0.52
155.2517242	0.06
169.0270233	0.06
186.0544128	0.10
221.0265198	0.33
241.0274048	0.07
250.9028320	0.05
254.0359497	0.10
273.2022095	0.03
274.0344849	0.05
276.3747253	0.03
281.2158813	0.04
293.4228821	0.07
299.3271790	0.10
301.9429321	0.04
311.1416016	0.30
317.0210571	0.11
318.3838501	0.16
343.1353149	0.11
344.2180481	0.17
349.1192627	0.07
351.1799622	0.03
359.1728210	0.06
360.4613037	0.11
363.0162659	0.05
365.4440918	0.14
367.2239685	0.12
374.8872375	0.06
377.2556152	0.12
393.2045288	100.00
394.0021667	0.02
395.1754150	0.20
402.2340698	0.05
406.9524231	0.10
420.1794739	0.14
420.9655762	0.16
429.8070984	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1503
Annotation	Benzyl beta-primeveroside
Peak:m/z	Relative Intensity
167.0841064	0.02
240.6352234	0.02
243.3650513	0.01
249.0527954	0.11
269.1887817	0.09
271.0698547	0.03
272.9439392	0.02
276.2570801	0.04
280.1688232	0.02
315.2752075	0.07
343.0683594	0.05
357.2932129	0.03
363.3991699	0.04
367.4999695	0.03
372.3840637	0.02
375.7274475	0.01
387.0901184	0.03
392.4106750	0.03
401.2366028	100.00
402.2337341	23.06
402.8468933	0.09
403.4537354	0.02
404.3427429	0.06
405.2438049	0.10
406.4278870	0.02
409.7885742	0.02
415.3863831	0.04
416.1953125	0.03
419.0221252	0.01
426.9540405	0.04
428.0974731	0.06
429.2130432	0.43
430.2656860	0.07
433.1579590	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	516.74
Annotation	Unknow
Peak:m/z	Relative Intensity
194.1761932	0.03
212.9066772	0.34
235.0878143	0.08
237.2799530	0.06
251.2196045	0.04
280.8684082	0.87
294.6284180	0.04
296.8794556	0.63
323.1580811	0.19
338.8933716	0.81
339.9434204	0.10
340.9215088	0.64
342.1952515	1.01
342.9758301	0.39
348.9295654	2.57
350.9240112	0.03
355.1892700	0.07
356.9166260	0.19
358.7708130	0.28
361.2391968	0.22
362.2226562	0.09
364.8082275	22.14
370.6229248	0.49
378.6594238	0.03
379.2638550	0.03
380.7463989	8.99
396.7578735	0.05
430.8693237	0.14
432.6906738	100.00
434.7015381	0.05
445.6115723	0.03
448.7147827	20.27
454.7252197	0.05
470.3190308	0.05
474.1318970	0.04
493.4761353	0.34
496.1190796	0.08
498.0009155	1.08
506.7067261	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	954.0657
Annotation	Unknow
Peak:m/z	Relative Intensity
360.3557129	0.15
472.9241943	0.45
474.1323853	0.26
559.0232544	0.10
585.9859619	0.59
587.3050537	0.11
601.4514160	0.12
642.1421509	0.10
649.4989014	0.14
657.1405640	0.08
696.3483276	0.30
700.2876587	0.07
713.8927612	0.16
855.4215698	0.35
864.2241821	0.16
880.6520386	0.32
882.0874634	0.80
883.1002197	0.09
908.7122192	0.76
929.2461548	0.07
931.0345459	1.02
936.9044800	1.70
959.2817383	0.07
1014.1613770	12.30
1014.8753050	0.39
1041.7554930	2.69
1045.7191160	1.97
1046.4117430	5.76
1047.4367680	0.53
1050.1575930	0.20
1103.4377440	0.45
1104.6066890	0.32
1106.7576900	0.09
1149.0041500	0.46
1333.8908690	0.09
1348.0777590	0.16
1560.6949460	0.33
1593.4639890	0.13
1635.9022220	0.15
1686.3815920	0.14
1701.0456540	0.26
1710.6361080	0.27
1716.4014890	0.15
1725.1906740	0.16
1768.2458500	0.05
1779.9261470	0.20
1781.9143070	0.07
1787.4708250	4.38
1790.6785890	0.39
1804.8532710	1.60
1809.4156490	0.11
1833.9976810	0.42
1835.6359860	0.44
1850.9249270	0.09
1884.4478760	0.27
1890.1241460	0.19
1907.0550540	0.06
1911.6926270	0.18
1914.2537840	0.16
1915.2203370	0.34
1922.8856200	0.05
1927.1770020	0.15
1929.4324950	0.07
1936.9781490	0.94
1937.6651610	0.07
1943.9796140	0.09
1955.4528810	0.39
1957.5949710	0.35
1961.0316160	1.49
1963.3802490	0.06
1970.2282710	2.90
1971.3353270	1.69
1972.9318850	4.94
1974.9725340	21.69
1976.7736820	0.13
1979.2452390	0.06
1981.1343990	3.89
1981.9039310	0.53
1985.0526120	9.20
1985.6739500	1.09
1988.5808110	0.44
1989.5886230	100.00
1991.9398190	0.07
1993.3663330	0.12
1996.3332520	0.14
1998.7425540	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1956
Annotation	Unknow
Peak:m/z	Relative Intensity
118.8051758	0.13
134.9213104	0.11
137.0332947	0.25
143.2207642	0.12
152.9598083	100.00
163.0960999	0.11
197.0353394	0.11
207.0215149	1.30
240.2761536	0.15
242.9860229	0.28
249.5066223	0.07
261.1241760	0.27
267.2660522	0.83
290.9923706	0.10
311.3098755	0.95
313.5665894	0.71
319.3397217	0.24
320.5561523	0.18
325.4664307	0.09
332.9740906	0.09
347.2589417	0.21
349.2391357	1.15
351.5589294	0.16
353.5917969	0.09
357.5920410	0.09
363.2529907	0.22
365.4864807	0.16
373.2943726	0.07
374.2345276	0.23
375.1681519	2.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.9851
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8421631	0.74
210.1489563	0.06
298.9985352	0.04
306.3206177	0.52
309.3044739	0.07
343.8715210	0.18
355.0833130	0.06
361.3850098	0.07
370.1746216	0.04
397.1514282	0.14
414.0253906	0.11
415.1959229	0.13
421.2042847	0.13
440.9980469	0.76
457.1546631	1.33
458.0474243	4.92
459.0704346	100.00
460.0686035	0.49
475.2573853	0.08
481.3909302	0.12
505.2683716	0.05
515.8588867	0.40
516.6610718	0.10
528.8889771	0.05
551.9684448	0.58
552.7910156	0.19
561.3252563	0.23
605.9981689	0.16
631.9746704	0.52
633.1232910	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
140.0529938	0.07
152.8509064	0.12
178.0659790	0.01
196.0040741	2.11
197.2882233	0.06
199.0652771	0.06
214.0789337	1.47
215.0402679	0.01
221.2007904	0.01
255.2732849	100.00
256.2830200	16.43
259.3467407	0.02
297.5010071	0.02
313.4201050	0.01
316.5541992	0.04
347.4958496	0.01
350.6733704	0.04
357.1836548	0.04
359.3191528	0.02
365.1966248	0.02
372.8038635	0.02
374.3847961	0.02
387.5457764	0.04
391.3041992	0.48
392.1441650	0.08
393.5279236	0.01
396.4973145	0.02
397.5693665	0.02
407.4143066	1.00
409.2953186	0.15
412.4273376	0.01
414.4510498	0.03
416.3384705	0.09
417.3174133	0.05
425.8916931	0.01
433.3851318	0.06
434.8387756	0.06
436.1515198	0.07
453.4182739	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1838
Annotation	Lychnose
Peak:m/z	Relative Intensity
352.2391968	0.14
378.6599731	0.03
393.0256958	0.10
395.0114746	0.03
419.8577881	0.27
479.0972290	0.13
481.0855713	0.08
483.3296509	0.05
486.7653198	0.04
505.7780762	0.08
510.8369141	0.05
525.3535767	1.10
526.3992310	0.17
536.2142944	0.16
537.8300781	0.23
543.1875000	100.00
544.2498779	23.14
559.1406250	0.08
559.9497681	0.10
560.8771362	0.11
562.8225708	0.71
579.3111572	0.03
592.7079468	0.09
601.1220093	0.08
619.9342041	0.26
621.9542847	0.98
659.9265137	0.53
661.2265625	0.09
668.8247681	0.04
675.9583740	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	364.87
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8739014	3.48
128.9544373	1.40
192.0942383	0.08
196.9032898	6.97
212.2738037	0.06
212.8992615	0.24
229.0515442	0.31
280.7839661	100.00
281.4493103	0.39
292.9441833	0.06
296.7667236	0.30
320.8413696	0.05
337.2633057	0.06
347.1117249	0.08
348.4612122	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.2186
Annotation	Excavatolide D
Peak:m/z	Relative Intensity
161.2833862	0.05
163.0918121	0.02
187.1080933	0.02
297.9275513	0.03
299.3565674	0.04
301.5057983	0.04
312.9985352	0.04
317.0762939	0.09
317.9756470	0.04
319.2892456	0.02
327.5527344	0.04
330.0084839	0.04
358.4318237	0.03
359.3447876	0.08
361.2337036	100.00
361.9414062	0.22
364.3975830	0.03
377.2963867	0.10
379.1939087	0.04
385.2427979	0.02
392.2718506	0.06
393.3662109	0.05
403.2719727	0.22
405.4545898	0.02
409.3944702	0.04
415.4372559	0.04
419.3893433	0.03
427.2536621	0.17
439.1079102	0.05
452.1820068	0.06
460.4077148	0.03
463.5036011	0.09
473.3734741	0.04
474.7400513	0.06
477.2028198	0.19
479.2628784	0.14
480.1023560	0.16
487.4260864	0.04
505.3149414	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	364.79
Annotation	Unknow
Peak:m/z	Relative Intensity
196.9371338	0.29
212.7480927	17.30
267.1329346	0.08
280.8516846	100.00
296.7992554	45.32
318.7279053	0.13
346.1979675	4.07
347.1923828	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.2446
Annotation	Hydrangenoside E
Peak:m/z	Relative Intensity
190.9379120	0.07
213.1860809	0.03
224.0138855	0.09
238.1393890	0.07
303.4309692	0.05
307.8065796	0.03
357.3765259	0.31
375.3078613	0.57
376.4457397	0.28
417.3820190	0.10
418.4015503	0.08
420.7567749	0.08
441.1635132	0.03
461.8331299	0.09
471.4597778	0.09
483.5376587	0.14
494.3217773	0.19
502.1522827	0.03
506.2483521	0.08
508.2220459	0.03
508.8504028	0.07
517.2383423	0.03
519.3330688	100.00
520.2991943	33.90
520.9298706	0.13
533.4328613	0.04
537.3084717	22.92
538.3978882	8.10
541.9295654	0.04
544.1346436	0.17
559.3762817	0.03
563.2953491	0.07
570.9606323	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	701.1905
Annotation	Lactulose
Peak:m/z	Relative Intensity
221.0533447	0.07
222.1402588	0.01
250.9071045	0.03
281.2666321	0.05
305.1912231	0.01
323.1677551	0.09
334.2359619	0.04
341.0336914	1.79
342.0130005	0.25
378.9554443	0.02
383.3026123	1.56
384.2211914	0.12
385.7453003	0.01
411.2875977	0.02
412.2431641	0.04
412.9260864	0.46
413.8559570	0.16
414.5133057	0.01
431.7623901	0.01
442.9876099	2.37
443.9776611	0.32
455.0345459	0.02
466.9750366	0.07
473.0841675	0.10
473.9439087	0.01
485.1832886	1.21
486.2951660	0.37
503.0482178	2.43
504.1469116	0.28
521.4102173	0.02
522.1326904	0.02
527.0426025	0.01
538.0922241	0.02
539.2040405	3.39
540.1965332	0.63
545.3482666	0.06
555.2852173	0.01
562.5532837	0.04
569.2479248	0.01
604.3131714	0.02
605.1317749	0.01
617.2796021	0.06
628.2314453	0.01
629.0025635	0.04
647.2918091	0.01
648.2644043	0.03
650.2871704	0.05
655.8096924	0.03
663.9462280	0.07
665.2932739	100.00
666.2597046	21.88
667.3221436	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.2804
Annotation	Polysorbate 60
Peak:m/z	Relative Intensity
129.0626221	0.04
130.9883423	0.09
143.0090027	0.39
148.8394928	0.06
161.1258087	0.34
178.1190186	0.02
179.0870972	0.14
223.2697449	0.14
225.3223267	5.47
235.3876953	0.08
239.2706909	0.10
241.1663513	0.02
253.1848755	3.88
253.8357849	0.06
255.3150330	1.49
267.3647766	3.66
269.3088989	0.39
271.2719727	100.00
272.4055176	0.06
279.2548523	0.05
281.6453857	0.05
283.3198853	0.16
285.1547241	0.07
295.2064819	0.19
297.4428711	0.02
313.2592773	3.61
313.9233704	0.01
323.4658813	0.02
325.4212646	0.74
339.4163513	0.15
343.5907593	0.02
367.3737488	0.03
373.2484131	0.04
397.2208557	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.2577
Annotation	Vibsanin G
Peak:m/z	Relative Intensity
323.4324646	0.31
331.1951904	1.55
345.1038818	0.63
370.3753052	1.32
371.1698914	0.54
382.7013855	0.89
390.1611633	0.85
401.1675720	10.02
415.2820129	100.00
439.9714966	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.1295
Annotation	Unknow
Peak:m/z	Relative Intensity
101.0211334	3.14
102.8221664	0.33
111.0312042	0.07
112.9965668	8.37
116.9262543	0.10
122.9289703	0.08
128.9270630	0.18
131.1589050	0.08
136.7244568	0.09
141.0095062	0.05
145.0087128	0.07
151.9938049	0.12
156.9691620	0.35
163.2365723	0.08
164.9190369	0.07
174.9361115	2.77
180.1180267	0.12
189.0500183	0.29
201.1449585	0.09
205.1652374	1.93
213.0941162	0.11
215.2193298	0.08
223.0743408	0.88
223.8377991	0.12
231.1034546	8.61
233.0605164	0.15
239.0749817	0.18
247.0483093	0.04
249.0534668	100.00
267.1598206	22.03
271.1984253	0.05
273.7664185	0.07
275.0446777	0.27
276.9866943	0.08
279.1302490	0.44
288.3920288	0.05
289.2022095	0.18
291.1127014	1.82
291.9210815	0.03
293.0194702	0.03
301.3989563	0.04
305.2058716	0.18
307.1424255	0.11
314.1000061	0.15
315.1374512	1.10
316.0280457	0.22
317.0138550	0.14
322.6424561	0.05
331.1832581	0.21
333.1931152	15.73
348.8128357	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	486.1224
Annotation	Unknow
Peak:m/z	Relative Intensity
164.9127502	0.07
243.5919495	0.20
249.0286255	2.95
297.9257202	0.09
314.6496887	0.65
317.0627441	0.09
327.9881287	41.53
328.6921997	0.11
334.4745789	0.03
339.0568542	0.21
370.0931396	0.35
396.0884705	0.04
406.9866638	100.00
423.9426575	0.08
441.2595520	0.08
442.2249146	0.08
450.3505554	0.10
456.5142517	0.14
466.2450562	0.15
467.4355164	0.47
468.2491150	0.12
469.4776001	0.20
496.8131409	0.35
497.4304810	0.03
615.8941040	0.16
655.1001587	0.49
800.9385376	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1534
Annotation	Gibberellin A11
Peak:m/z	Relative Intensity
107.1218185	0.12
113.0727997	0.22
118.9403	0.50
136.9506989	0.15
148.7202148	0.49
151.0363464	8.21
151.9614563	0.22
157.0678101	0.41
161.1716309	0.24
163.0144348	0.52
167.032074	0.19
168.8870544	0.48
174.9688568	0.56
177.1291199	0.24
182.9017639	0.16
189.0602112	7.99
193.2926941	0.27
203.1752167	0.48
207.0157318	2.61
211.9864807	0.29
215.9815369	0.17
237.2623291	0.39
244.4133911	0.07
247.3617859	0.17
249.1613464	0.55
251.4103088	0.29
253.056427	0.82
255.1057129	2.05
259.3342896	0.12
263.3068848	1.45
269.352478	0.11
271.30896	0.14
272.3806152	0.19
274.2685852	0.10
275.3507996	0.53
281.3112183	2.69
285.1865845	9.00
287.1719055	38.29
295.0238342	1.13
301.1169434	1.26
313.1396484	100.00
313.8987427	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.88
Annotation	Unknow
Peak:m/z	Relative Intensity
198.8342590	0.12
205.3717651	0.05
216.9360199	0.02
244.8641968	0.17
246.0973206	0.06
247.1019745	0.11
248.1298676	0.03
270.9818726	0.02
273.0131531	1.50
274.8421936	0.04
289.0759888	3.53
315.3913879	0.04
343.1907959	0.07
387.0390015	1.65
402.9219360	17.51
403.5949097	0.05
406.1878662	0.04
413.0006714	0.07
427.2301636	0.04
457.4571533	0.05
461.1376953	0.02
470.9006958	0.13
472.9044189	0.06
474.9114380	0.08
475.7088013	0.11
477.0270386	0.13
485.4365845	0.05
500.8419800	0.71
503.0490723	0.07
514.4860229	0.07
516.8387451	100.00
517.5031738	0.21
540.8908691	0.10
556.9080200	0.18
583.8628540	0.85
584.8352661	2.45
585.8508301	0.02
586.8491211	0.24
601.1566162	0.04
602.0628052	0.08
603.1105957	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	514.8674
Annotation	Unknow
Peak:m/z	Relative Intensity
154.8182373	0.03
158.9785309	0.46
174.9497681	0.53
199.0449219	0.09
215.3440857	0.04
218.6148071	0.02
229.0170898	0.11
232.7195129	0.02
244.8606873	0.12
273.0104980	5.86
275.0723877	0.02
289.0167847	10.85
361.1306152	0.07
363.1117554	0.04
386.9478149	0.90
388.9609985	0.03
401.3122559	0.01
402.8876953	100.00
403.5093384	0.21
404.5265503	0.07
428.1885986	0.02
432.1605835	0.01
442.1746216	0.03
443.0824585	0.12
469.8204346	0.64
470.9544067	3.75
471.8959351	0.04
472.8792114	0.13
497.9010010	0.02
498.9705811	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
90.9455719	0.35
94.86956024	0.26
107.163826	0.35
109.0942154	1.08
114.9601212	0.73
121.0725784	0.42
123.2454071	0.56
125.0894928	0.90
127.1215897	0.30
128.9881592	0.63
134.824585	0.55
137.0956421	0.54
138.8317871	0.26
140.8666992	0.28
147.2308655	0.53
149.2810974	1.09
152.957489	2.46
155.1427612	0.26
159.0347443	0.28
160.9105682	0.19
166.7780762	1.38
168.6219635	0.23
169.3096924	0.68
170.9813995	0.23
178.96875	0.68
181.114212	1.05
183.0982056	1.60
191.046814	0.44
197.0201111	4.39
201.2948608	0.82
204.9313354	0.92
207.1248474	0.79
209.2634583	0.87
211.0623779	1.23
213.3317871	1.77
219.0770264	3.19
221.2075806	3.14
225.1510925	1.94
233.3034363	1.01
234.974884	0.70
237.1369934	1.70
239.2661743	12.98
243.2167358	2.25
251.1313782	4.88
252.8927612	0.57
255.991272	0.26
260.2693787	0.28
261.1384277	5.89
263.1218262	0.66
269.1477966	0.23
279.2309875	100.00
281.149231	3.63
288.1585083	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	255.195
Annotation	4,7,7,11-Tetramethyl-12-oxabicyclo[9.1.0]dodec-4-ene-3,6-diol
Peak:m/z	Relative Intensity
78.87263489	0.18
91.89729309	0.27
92.88089752	0.16
95.09431458	0.62
106.9536896	0.08
109.0427246	1.18
111.0317841	0.12
112.9889832	3.17
115.0199432	0.36
123.0976562	0.38
127.0418549	0.34
129.8881378	1.43
130.8756409	1.83
133.2126465	0.25
135.056488	0.72
151.2308655	0.28
152.9579926	0.38
155.0722656	1.16
155.7687225	0.15
161.1373444	0.41
163.0508118	2.42
165.1251068	0.16
167.1592255	0.35
169.0764923	0.76
177.0922089	1.12
181.1775818	0.88
183.2100372	1.79
185.2125549	0.11
191.0574799	4.14
195.049057	1.19
197.1808777	0.32
198.9405975	0.41
207.8350677	0.34
209.045639	2.92
211.127182	0.24
213.1938324	0.45
214.0264282	0.23
219.0154572	11.02
219.9316101	0.19
227.275238	0.73
228.3160858	0.52
232.104538	0.37
237.1936798	100.00
238.4469757	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.2
Annotation	Pteroside A
Peak:m/z	Relative Intensity
147.1351013	1.19
165.9741058	1.12
174.9978943	2.61
200.9159851	1.36
211.1496277	1.04
222.951416	1.12
257.8996887	4.42
268.7521057	1.36
277.0126953	2.30
309.3151245	1.12
311.265625	2.05
315.1988525	0.96
317.2300415	1.07
323.3434448	2.13
349.1856384	1.81
351.4703369	3.95
362.4289856	3.63
364.9945374	0.96
367.2676697	1.04
369.2209167	0.90
370.6573181	1.36
375.5587769	1.91
393.1949463	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.2205
Annotation	Toddacoumalone
Peak:m/z	Relative Intensity
176.7255096	0.44
188.8813477	0.17
199.0752563	0.18
226.9858551	0.14
239.1180573	0.51
241.1322937	0.27
245.1930695	0.14
259.0063477	0.08
263.8428345	0.40
273.9711304	0.36
281.1087036	0.46
282.2924194	1.06
288.1201172	0.07
310.2276611	0.62
320.7720947	0.25
327.2050781	0.32
329.1281128	0.19
335.3910522	0.36
336.9081421	0.13
341.9898682	0.09
349.2051392	3.38
351.1815186	0.11
367.2946777	100.00
376.4043579	0.13
385.1868896	3.07
407.2861938	0.36
414.1541748	0.09
415.3803101	0.21
421.2777100	0.39
439.2258301	6.97
439.8346558	0.20
451.3504028	0.78
454.8696899	0.28
472.4690552	0.32
475.8619995	0.18
477.2650757	0.54
478.2844849	0.40
495.7559204	0.09
496.3894653	4.37
497.3007812	1.83
505.1585083	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.1531
Annotation	Unknow
Peak:m/z	Relative Intensity
133.2001648	0.07
144.9906158	0.61
150.6730957	0.33
176.9853363	0.08
181.0645294	0.13
185.9731140	0.38
197.1203613	0.05
199.0710754	0.25
234.3218842	0.19
256.0628052	3.17
274.1040039	0.82
288.9595032	0.06
295.1994019	0.19
301.0843506	1.06
309.0383301	0.15
310.1765442	0.07
312.4948425	0.98
313.1148987	2.01
321.1256409	0.24
330.1308289	100.00
330.7601318	0.28
340.5913086	0.12
342.9870605	0.10
351.2049561	0.17
360.6455078	0.45
361.2485046	0.68
368.9123840	0.25
371.1320496	0.23
381.2634277	0.06
395.7281799	0.16
415.7254944	0.08
424.0408630	0.14
441.0626831	8.40
441.8805847	0.77
443.0324402	0.16
445.4099731	0.21
459.7818909	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0292969	0.90
108.843132	0.50
110.8610992	0.24
117.032486	0.26
121.0573044	1.34
123.0377808	0.89
125.1053391	0.21
135.0035095	3.31
137.1741791	0.99
142.9907684	0.74
146.9703369	1.22
148.97052	1.00
150.9832001	1.06
153.1122131	0.13
157.1746826	0.58
159.0414429	0.35
161.0107727	0.88
163.0994873	0.30
164.9964142	0.94
167.1537628	0.39
168.9484711	0.49
173.1760406	0.64
175.0445099	0.50
177.0815735	0.49
179.2121277	0.25
183.1649628	0.75
184.8662109	0.18
187.279541	0.52
189.1121521	0.40
191.245575	0.15
195.2132416	0.27
197.2272949	0.55
203.181076	0.37
205.1619873	0.97
209.1490173	0.19
210.8503113	0.95
213.0536499	0.13
214.0726013	0.11
215.1127014	0.74
217.1123657	0.74
220.9843445	0.15
227.0507507	0.14
231.2365417	0.27
237.3756409	0.12
241.135437	0.81
245.2364197	1.47
247.2049255	3.99
250.9288635	0.58
251.6090393	0.14
253.0152588	0.28
254.1876221	0.74
255.3271484	0.31
259.0448303	0.62
270.4001465	0.82
271.2323608	0.32
273.2716064	0.48
281.2766113	0.30
283.1505127	0.56
284.8643799	0.30
287.2636414	0.15
292.5048218	0.22
295.2359314	0.64
299.3305664	0.85
300.2149353	1.19
305.2875977	2.54
309.9796753	0.25
313.3756409	1.49
323.2408447	100.00
323.8589478	0.68
324.5263062	1.21
325.4462891	0.20
341.289032	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.2624
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
89.14581299	1.73
92.96873474	5.37
94.92315674	4.39
97.19632721	4.93
106.9414825	2.62
109.0474396	8.20
111.2975998	1.62
115.0025024	1.52
120.9789734	5.31
127.2390976	1.87
132.9635925	9.19
134.8607178	2.20
136.9294434	9.51
149.1070251	3.88
151.0611267	1.19
153.178299	2.37
156.8823395	2.78
163.3383484	1.12
165.0424194	4.05
167.0966034	1.53
169.1650848	1.54
177.048645	17.83
183.3316956	3.13
185.0578308	1.98
194.6079102	2.70
199.2070618	3.24
213.0219116	5.90
225.0513306	1.69
227.0596313	3.33
236.8865967	3.53
238.2774658	1.44
239.2840576	1.54
240.9458618	4.33
241.8418579	13.05
247.2879028	32.12
259.8215027	1.15
265.2506409	100.00
266.8588257	3.68
283.1412048	2.46
293.6115723	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	482.2777
Annotation	Unknow
Peak:m/z	Relative Intensity
166.8775635	0.95
175.8340302	0.53
193.1092987	0.38
227.3360748	0.31
247.9032288	1.00
282.4641724	0.65
288.9217834	8.75
316.1977539	0.39
344.8550110	0.49
360.2947998	12.55
360.9446106	100.00
371.3451843	0.33
379.0982666	15.69
415.2385559	0.66
426.7152405	1.35
433.1679382	1.04
435.8073120	0.78
441.2207642	1.62
446.9424438	0.42
450.9467163	0.22
464.3676147	11.16
464.9860229	85.09
465.6696472	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.2264
Annotation	(-)-Malyngolide
Peak:m/z	Relative Intensity
76.56546021	0.71
97.08000183	0.39
117.1290894	0.28
141.0018616	0.56
146.9911957	0.51
156.9536591	0.37
183.0190887	1.13
186.8856964	0.39
189.0860748	0.58
193.0869446	0.39
194.9234161	0.33
197.1598969	1.01
211.1439056	0.49
213.197403	0.63
215.311264	0.54
227.1450348	1.68
229.2255707	0.28
235.3045654	0.71
243.2141876	0.51
253.2166748	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	578.77
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8622437	0.05
207.0683899	0.24
250.9189453	0.03
258.6542053	0.11
274.9041138	2.10
276.3741455	0.04
290.8811035	2.65
301.8813171	0.04
326.8812866	0.04
342.8127441	0.92
358.8300171	2.26
363.0069580	0.04
375.1582642	0.18
382.4679565	0.08
399.4540405	0.22
400.3157959	0.14
404.1332397	0.62
408.9897461	0.30
410.7730103	6.67
415.2382812	0.12
415.9710693	0.20
418.6320801	0.04
423.7022095	0.12
424.3077393	0.23
426.6618042	32.10
427.3474121	0.19
432.3119507	0.05
441.9907837	1.17
442.7913208	6.90
492.2177124	0.25
493.3211670	0.91
494.6741943	100.00
495.2911377	1.21
510.7044067	15.66
513.4811401	0.04
531.8893433	0.89
532.5601196	0.48
533.2420654	0.12
537.1095581	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	1-O-Vanilloyl-beta-D-glucose
Peak:m/z	Relative Intensity
100.9224167	0.26
107.7901764	0.36
110.6269302	0.59
123.01828	5.70
151.9418945	6.77
153.0770264	0.47
167.0411377	100.00
177.0389709	0.49
178.9838867	0.36
196.200592	0.24
208.9670105	15.68
219.0178223	0.34
221.0500183	0.48
234.9561462	0.85
236.8777771	0.36
239.0906372	1.79
242.9125366	0.41
246.0637207	0.47
253.1429443	1.60
257.2284546	0.42
267.1032104	1.46
269.0152588	2.17
282.9275818	6.04
285.1173096	1.40
285.8444519	0.62
293.23172	0.75
298.5344849	0.26
299.3612671	0.36
308.948822	0.29
311.0145264	3.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1885
Annotation	Atalanine
Peak:m/z	Relative Intensity
187.0760803	0.18
207.1205292	0.19
249.0507507	1.08
267.1085205	100.00
327.1960449	0.12
503.2777710	0.62
504.3652954	0.30
562.9552612	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1822
Annotation	5,2',4'-Trihydroxy-3,7,5'-trimethoxyflavone 2'-galactosyl-(1->4)-glucoside
Peak:m/z	Relative Intensity
222.9182587	0.03
323.1411133	0.10
341.2772217	0.86
342.2306519	0.13
343.1131592	0.03
359.1300049	8.93
360.1719360	0.68
401.4609985	0.22
479.4317017	0.03
503.3097534	0.78
504.6580811	0.03
519.2928467	0.04
521.1657715	100.00
522.2577515	5.27
563.3150024	0.12
564.1295776	0.03
587.4217529	0.02
589.7361450	0.07
622.9791870	0.06
637.2243652	0.03
640.2570190	0.02
647.5234985	0.06
664.2853394	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1428
Annotation	Unknow
Peak:m/z	Relative Intensity
93.0613861	0.06
96.8531494	100.00
113.0056152	0.08
152.8522339	0.23
154.6942902	0.04
161.2511139	0.32
180.1194763	0.06
183.0673523	0.11
191.0140686	0.30
193.3121948	0.22
197.3211365	0.26
201.0642090	0.24
207.1232910	0.28
209.0310059	0.13
219.1434021	0.62
222.2143250	0.06
232.3001404	0.07
232.9579468	0.08
235.1363831	0.18
237.2458496	1.72
239.2492981	0.33
242.7897644	0.06
245.8848267	0.26
261.3184814	0.30
263.0752563	1.27
264.2731323	0.48
265.2809753	2.40
266.1681519	4.00
267.2673645	0.22
279.1397095	0.11
281.3421021	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.2875
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
170.8913879	2.99
186.8845825	2.00
195.0935516	3.39
211.2684937	7.08
217.0029907	2.02
225.0250854	15.48
231.0499573	2.40
240.1936646	10.39
245.039032	4.23
257.4781189	8.01
264.0544128	6.45
281.3308105	18.33
288.0892639	1.20
293.1717529	5.19
300.3928223	2.02
311.0508728	2.80
324.3432007	7.42
326.9748535	2.83
332.0975647	2.41
338.0899658	5.60
343.4025879	6.05
350.2690125	2.41
356.927124	2.20
362.3927307	2.96
365.4636536	33.13
366.4367981	9.47
380.3924255	2.53
381.1584778	22.50
384.1350403	5.37
390.6388855	20.93
391.4892273	33.82
392.3036499	10.47
395.3176575	29.97
407.3855896	15.65
408.2825928	100.00
409.2796021	8.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2418
Annotation	Moniliforminol B
Peak:m/z	Relative Intensity
90.99421692	0.28
97.04946136	1.16
99.13800049	0.18
109.3156281	0.36
110.8001022	0.74
112.8266144	1.19
118.9093933	0.75
121.2405396	0.63
124.9783936	1.24
129.1104584	0.29
135.2790222	0.32
137.0248718	1.23
138.9593201	1.21
141.0370483	0.46
148.9167175	1.24
151.1674652	1.00
152.9766846	0.37
155.1417542	1.52
157.0979462	0.55
159.1336517	0.29
161.2049713	0.38
163.1992493	0.32
165.090744	1.04
167.0517883	0.84
169.0097046	1.63
170.8742371	1.05
173.2321472	0.16
177.0423279	0.14
179.0346069	0.16
181.2214813	0.75
182.8413849	2.45
185.2443848	0.16
187.0557556	0.20
189.4504395	0.32
191.2367706	0.28
192.8651428	0.83
195.1300659	0.72
196.5753174	1.13
197.27948	2.80
199.1490479	0.58
200.9276428	0.14
203.2279053	0.72
206.4379883	0.22
209.1374207	0.24
209.9576416	0.35
211.1827393	2.30
213.2049255	2.45
219.453186	0.15
221.1799316	4.48
223.1473694	1.41
225.0240479	1.63
227.2270508	1.69
233.1824646	1.01
235.2929688	0.16
237.252533	3.43
239.2037964	12.87
243.231842	1.77
247.2915955	0.18
251.067688	1.24
253.2848206	1.73
255.2946167	1.64
256.0678101	0.61
256.9867554	1.57
261.2733459	6.01
265.3917847	0.50
269.3320618	0.63
276.9160156	0.18
279.2299194	100.00
281.1435242	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
96.7406769	0.28
100.9121857	5.06
106.4743195	0.22
112.8918457	18.56
115.0228882	0.18
118.9506989	21.21
124.9938431	1.05
130.9159851	9.24
143.0031586	21.47
149.0488892	4.58
155.0264893	0.22
160.9528351	22.79
178.9990692	100.00
185.0396423	0.28
186.2263794	0.13
190.2371826	0.18
190.9871368	0.28
220.5201111	0.55
221.1313477	0.31
262.2626343	0.15
267.3854065	0.59
280.8471069	4.35
281.6048279	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	465.1974
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9267273	0.05
144.9702148	0.03
148.9427185	2.07
153.0705719	0.18
157.0932159	0.03
158.9981079	0.03
161.0249786	0.35
162.9673767	0.06
190.9786224	0.42
220.7520905	0.70
239.0048676	0.11
249.6867371	0.03
250.4767456	0.02
251.0915833	0.07
254.1276550	0.04
255.3000488	0.02
262.9629517	0.08
267.2295227	0.06
281.1269836	0.14
281.8601990	0.02
285.5845947	0.11
289.2474365	0.04
293.2948303	0.26
297.7137451	0.05
300.8619385	0.11
302.0635376	0.13
303.3073120	0.37
310.9186401	0.77
328.9326477	0.08
335.7525940	0.09
336.3712158	0.02
343.3789673	0.21
345.2149048	0.10
361.4423218	0.03
362.0443115	0.04
362.8775024	0.05
369.0104370	0.01
381.2253113	0.13
383.6688843	0.09
389.6047668	0.02
391.2053223	0.11
391.8122864	0.06
393.4061890	0.04
403.3028259	0.03
405.1221008	0.05
407.2282715	0.08
419.1975708	100.00
420.8612366	0.05
421.5077209	0.02
429.1924744	0.03
433.2177429	0.42
445.4410706	0.07
446.4851074	0.07
447.5205383	0.41
450.5982361	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	alpha-Sorinin
Peak:m/z	Relative Intensity
160.9993896	0.08
179.0063477	0.93
221.0948181	0.38
233.0909119	0.03
250.9599762	0.16
263.2949829	0.07
280.9203186	0.21
311.1113281	0.14
321.4388428	0.04
323.1331787	0.47
329.2744751	0.03
341.0302124	2.05
359.2467651	0.09
377.1887817	12.25
383.2319336	0.08
397.6984253	0.05
399.8110962	0.04
425.2888184	0.02
501.1428833	0.11
503.2477417	100.00
503.8493042	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
85.07523346	0.26
86.3996582	0.77
97.07307434	0.75
109.0315628	1.39
119.0102921	0.23
121.0568085	0.38
123.0593414	1.75
125.0764313	0.51
127.0333252	1.02
129.127121	0.40
133.1488037	0.24
135.1730957	0.67
137.0976868	0.41
138.8619537	1.16
141.2441864	0.12
143.0863342	0.10
149.0317841	1.13
151.0201111	0.85
152.8699036	0.71
155.0552826	1.06
157.0507812	0.42
161.2684326	0.11
162.763092	0.43
165.1648254	1.88
168.9823608	0.61
171.0813904	0.08
173.063385	0.23
175.0991821	0.34
177.3962555	0.35
179.0657959	0.68
181.1276093	0.19
183.1864319	1.65
185.0097961	0.95
189.0388489	0.36
191.1216278	0.12
193.4221344	0.17
195.1294861	0.48
197.095993	4.45
199.1613159	1.19
203.2466736	2.01
204.7506409	0.10
207.291687	0.17
209.1973877	0.33
211.0967102	3.81
213.1321411	1.29
215.2462463	0.25
216.9898071	0.08
219.302063	0.52
221.1508789	3.08
222.9443665	0.15
224.0184326	0.22
225.0820923	2.85
227.4110413	1.53
228.9996338	0.94
233.1998901	5.26
237.2738342	1.83
239.1897888	7.77
241.1120605	0.44
243.1069336	2.40
244.4905396	0.26
251.1295166	5.03
253.1306152	1.38
253.8219604	0.54
254.9019775	0.84
255.6065979	0.83
257.1376648	1.91
261.1922607	5.29
261.9985962	0.23
269.401123	0.72
276.0542297	0.49
279.2415161	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1694
Annotation	Isofurcatain 7-O-glucoside
Peak:m/z	Relative Intensity
203.0763397	0.30
241.0877991	0.23
309.1165161	0.28
313.3257446	1.05
314.0230103	1.06
333.2611694	0.30
336.5159302	0.23
337.1981201	6.04
338.2460327	2.49
381.2125244	14.57
382.2817993	6.80
399.2250977	15.64
400.1986694	8.45
409.2210693	0.48
410.1661987	0.25
417.125	100.00
418.1490479	36.14
425.3780518	0.23
433.1005859	0.21
435.4856567	0.95
453.145752	0.46
455.5131836	0.11
457.3068848	0.15
475.2069702	1.19
476.2542114	0.31
482.0951538	0.18
499.114624	6.34
500.1637573	1.41
507.9406128	0.40
522.3205566	0.54
524.7859497	0.51
526.8108521	0.15
533.8341675	0.33
538.7819214	0.60
539.7616577	0.95
543.123291	8.78
544.1717529	8.66
548.4017334	0.52
551.421814	0.19
561.1692505	21.46
562.1470337	10.02
563.173645	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2501
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.9987106	0.73
109.0383911	0.54
116.8367004	0.29
118.9965668	0.27
121.0969543	0.88
123.1347275	0.85
129.0886536	0.18
130.8029785	0.80
133.0115509	0.84
135.1018982	3.75
137.1445007	0.17
142.9294128	1.40
145.0184326	0.49
145.9221497	0.67
147.0521851	0.81
149.0053711	1.47
151.0971832	1.07
157.0194397	1.83
158.9877014	1.29
161.1656342	0.08
163.0016937	0.37
165.1129761	0.26
166.625946	0.13
169.0379181	0.66
171.0459442	0.42
172.9968262	1.74
175.1484222	0.37
177.2172394	0.38
179.133606	0.09
181.1996765	0.11
183.1984863	0.51
185.0375061	0.61
187.1043396	0.95
191.3737488	0.11
197.0144958	0.99
201.1083679	0.40
202.053894	0.08
205.3514099	0.16
210.9769592	1.23
213.2609253	0.18
217.2594299	1.55
221.8651428	0.08
223.2694092	1.21
225.036438	0.17
226.9424438	0.18
229.2163086	1.03
231.2971802	0.74
241.3080444	0.12
243.3930664	0.12
245.3269653	0.75
247.2764893	8.65
253.0586548	0.20
259.3650513	1.26
267.0036926	0.22
268.3634033	0.11
269.9078674	0.39
271.1309814	0.51
277.1186218	0.49
278.9230347	0.35
281.1842041	0.73
283.4694824	0.26
285.3325195	1.26
294.651886	0.31
295.3112793	1.05
297.3302612	0.34
299.2331238	4.02
299.8373108	0.76
303.0069885	0.37
303.895813	0.10
305.1685486	3.21
313.2685547	2.45
323.2478943	100.00
324.0065308	0.32
325.0032043	0.13
327.04245	0.32
341.0527039	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1055.33
Annotation	Unknow
Peak:m/z	Relative Intensity
379.3526306	0.43
422.3462830	0.24
467.4020996	0.23
474.2175293	0.65
597.4152832	0.32
627.0825806	0.45
632.4433594	0.45
656.1397095	0.37
688.3394775	0.44
694.0750732	0.34
697.1654663	0.45
701.1258545	0.59
708.1361084	2.03
720.9433594	0.65
722.5923462	0.40
727.4921875	0.42
731.2818604	0.89
765.9118042	0.41
769.9048462	0.45
778.3970947	0.19
793.8820801	0.92
829.5664062	1.20
831.9833984	0.42
841.9552002	1.28
850.1606445	0.37
852.8979492	1.04
857.2944336	0.70
871.9555664	0.17
876.1716309	0.64
887.3487549	3.12
901.5388184	0.82
903.4738770	0.55
911.0695801	1.02
917.4426270	0.27
920.3613281	0.78
921.4119873	0.91
922.4891357	0.42
931.1202393	1.73
935.3039551	0.95
942.0998535	0.23
960.9959717	0.67
962.1842041	0.75
978.8427734	1.04
983.2609863	0.53
989.6889648	1.29
991.6828613	0.61
994.3181152	2.15
996.4426270	4.87
997.2703857	3.22
1017.2246090	0.84
1022.5323490	1.10
1026.5635990	1.57
1031.8305660	1.06
1032.5187990	0.88
1062.4636230	1.08
1075.6396480	0.62
1086.8286130	0.20
1089.1765140	2.44
1091.9493410	0.46
1093.8052980	0.68
1094.4324950	2.35
1100.1778560	0.43
1111.2779540	0.95
1112.7780760	2.97
1125.4017330	0.25
1128.0222170	0.57
1134.0627440	0.78
1137.8122560	0.22
1138.9099120	0.71
1143.7222900	1.38
1170.5153810	0.23
1171.7180180	2.15
1173.5582280	0.72
1175.5448000	0.51
1176.8446040	0.51
1177.8928220	0.97
1182.6174320	3.79
1190.2293700	0.75
1194.3789060	0.49
1199.4863280	10.44
1201.2066650	3.77
1220.5073240	0.23
1228.9748540	1.50
1234.5629880	3.00
1253.6574710	1.75
1254.3833010	0.73
1265.6109620	0.21
1268.8811040	0.83
1274.9667970	0.42
1281.7825930	0.75
1285.1931150	0.36
1286.6999510	0.16
1294.4680180	0.93
1303.8488770	0.58
1305.3880620	0.70
1306.0721440	0.68
1313.4991460	0.49
1314.3448490	0.42
1330.1534420	0.39
1345.9735110	0.23
1346.8778080	0.47
1355.8233640	0.45
1357.5588380	0.33
1365.0321040	0.58
1373.7829590	0.46
1377.6951900	0.21
1380.9766850	0.74
1383.1325680	0.35
1384.4324950	0.86
1486.8068850	0.15
1491.2966310	0.43
1515.6666260	0.64
1532.3803710	0.65
1579.1290280	0.39
1612.7574460	0.41
1645.7017820	1.30
1699.7159420	0.27
1717.6120610	0.17
1725.1492920	0.58
1727.3464360	0.62
1775.1472170	0.28
1780.3435060	0.19
1782.0408940	1.56
1784.5843510	0.12
1792.4888920	0.13
1797.5635990	0.25
1799.7601320	0.17
1803.4769290	0.13
1809.3527830	4.77
1812.0775150	2.67
1815.0013430	0.21
1834.6427000	1.40
1842.2437740	2.09
1853.5930180	0.23
1854.4251710	0.68
1858.8653560	0.13
1860.0347900	0.19
1866.7271730	0.20
1867.6955570	0.51
1879.5755620	0.23
1881.3822020	0.21
1884.5736080	8.88
1901.0144040	0.53
1906.2185060	0.70
1912.8098140	13.42
1914.0260010	0.29
1923.1451420	3.66
1925.3160400	0.56
1926.7614750	7.02
1931.2102050	0.84
1936.4185790	2.13
1940.1707760	0.43
1942.6046140	6.75
1946.7816160	0.27
1950.0159910	5.21
1950.7637940	0.19
1952.2170410	1.80
1957.2528080	1.68
1959.3820800	8.43
1962.5609130	9.55
1963.2510990	4.07
1964.7468260	18.62
1965.6610110	5.42
1966.8957520	82.61
1968.5037840	22.24
1971.1156010	100.00
1975.3319090	0.47
1975.9527590	0.94
1979.8343510	13.33
1981.5040280	1.74
1983.0432130	13.26
1986.2604980	1.14
1987.1120610	5.88
1989.7736820	0.74
1996.6590580	30.68
1997.3306880	6.03
1999.8548580	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0983
Annotation	Syringic acid beta-glucopyranosyl ester
Peak:m/z	Relative Intensity
112.7966537	0.08
123.2104797	0.29
131.0750275	0.32
138.0943604	1.55
139.0095978	0.14
139.8743896	0.09
153.0997925	0.27
161.2830353	0.21
165.7961426	0.08
167.1218719	0.18
179.0157471	0.49
179.9265594	0.10
180.6879272	0.21
182.0579987	4.60
183.0909119	0.20
185.3500519	0.24
188.8975983	0.08
195.3908997	0.43
197.0365906	100.00
211.1555939	1.43
223.0478516	0.13
224.0475159	0.13
226.9434814	0.12
231.260437	0.06
236.9231567	0.21
239.1321716	10.10
243.2558899	0.22
269.1583862	0.69
277.1366577	0.23
279.1816406	0.11
283.2240601	0.13
299.1951904	0.69
311.7037659	0.10
313.0179138	1.61
315.2724304	0.47
316.4917908	0.21
327.0538025	0.62
328.1117554	0.14
330.4748535	0.15
339.2436523	0.08
341.031311	1.22
342.1715698	0.08
344.1896667	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2782
Annotation	LysoPE(18:2w6/0:0)
Peak:m/z	Relative Intensity
140.0900116	0.20
152.3513184	0.05
153.1645813	0.04
168.2302551	0.05
196.034668	1.86
198.2050781	0.02
210.0303345	0.02
211.1072693	0.06
214.1285553	1.32
226.8704987	0.04
242.0102386	0.03
243.5441132	0.03
250.9280701	0.04
261.2862854	0.18
271.0615845	0.06
279.2420654	100.00
297.7086792	0.03
298.5552368	0.05
306.2578735	0.04
318.298645	0.04
327.2188721	0.09
340.3834839	0.02
349.8070679	0.02
355.4627686	0.04
359.3081665	0.02
363.9202881	0.03
386.3027649	0.03
392.0952148	0.07
395.7333069	0.04
403.1942444	0.23
404.2158508	0.14
415.0917358	0.32
421.2878723	0.05
429.8030701	0.04
431.1407471	0.02
432.4415588	0.03
433.5845032	0.03
440.0406799	0.02
457.2759705	0.13
458.2773438	0.20
459.4188538	0.18
460.7427673	0.02
472.6455688	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1351
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
161.0580597	0.10
163.1857910	0.06
173.0295715	0.05
175.0867462	0.06
177.1026001	0.05
179.0101929	0.19
180.1965637	0.02
183.0616150	0.05
185.0488129	0.05
187.1640320	0.06
189.0766296	0.06
189.9989624	0.02
196.2356720	0.04
199.0188904	0.02
201.0850067	0.14
203.1715088	0.30
204.1550598	0.09
205.0936737	0.12
206.0008698	0.04
211.1297607	0.02
212.1670227	0.11
215.2472687	0.03
217.1983643	0.10
225.0613708	0.06
227.2884216	0.11
231.2233887	0.12
243.1696472	0.41
245.1182861	2.78
246.2118225	0.38
247.2120209	0.07
248.1859894	0.02
248.8430176	0.02
251.4003906	0.02
254.1603546	0.02
255.2225647	0.18
257.1843567	0.13
258.0436707	0.04
265.1521606	0.02
269.2029114	0.49
270.2969971	0.03
273.1972656	2.21
274.1231689	0.17
279.2120361	0.02
281.0115967	0.15
282.6840210	0.02
285.1264343	0.05
287.1525879	6.02
288.0779724	0.85
289.1910706	16.62
290.1200867	2.12
297.2650452	0.04
299.1058044	4.91
300.1849670	0.83
301.1864014	0.27
305.0613403	0.07
309.3588257	0.02
310.3386230	0.03
313.2713623	0.07
314.1193237	0.03
315.2420654	0.05
327.2981567	0.22
329.2358398	0.46
330.4708252	0.09
331.1304321	0.57
333.3006592	0.02
339.0817871	0.11
340.1951294	0.06
341.1068115	0.20
342.1939087	0.03
357.2550049	0.65
357.9741211	0.14
365.2503052	0.03
366.9078979	0.02
371.1002197	0.04
372.0798340	0.04
381.2332764	0.59
382.3439941	0.13
383.4234619	0.05
384.5779419	0.02
389.1165161	0.08
390.3082275	0.10
393.2265015	0.04
405.3276978	0.02
407.1743164	42.38
408.2932129	9.09
409.2999268	0.75
410.7015991	0.25
411.6055298	0.10
415.3223877	0.13
416.2927246	0.03
421.2679443	0.03
423.1242065	0.22
425.1680908	100.00
426.1740112	14.30
433.2442017	0.16
434.1578369	0.08
437.4848022	0.06
441.4144287	0.04
447.5507202	0.02
449.2481689	0.56
451.2005005	25.55
452.2453003	4.89
453.1947021	0.13
455.2433472	0.05
459.2890625	0.02
467.1292114	1.03
468.4420776	0.27
471.4172974	0.02
474.2038574	0.06
475.3800049	0.17
479.3010864	0.05
481.0452881	0.02
489.3520508	0.03
491.4432983	0.07
492.4766846	0.20
493.3046265	0.13
501.4845581	0.16
504.2774048	0.04
505.2965698	0.03
515.3335571	0.27
516.4044189	0.06
531.1770020	0.36
533.0769653	1.20
534.0928345	0.41
534.7619019	0.01
541.2088013	0.07
542.0482788	0.04
559.1744995	8.70
560.2703247	2.50
568.2075195	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	405.2681
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9981308	0.16
134.7104950	0.42
136.9263916	0.17
150.8862305	5.70
153.0215607	0.11
258.3179016	0.04
263.3301086	0.03
267.5680237	0.04
293.1386108	0.05
302.2806091	0.12
303.2308350	0.04
305.5314636	0.09
313.0309448	0.05
319.1603699	0.03
321.2521973	0.36
323.3593750	0.18
324.3348389	0.06
329.4995728	0.04
333.3924255	100.00
337.4702148	0.09
359.5777893	0.03
361.2310486	1.08
369.2432861	0.05
370.3136292	0.11
377.3642883	0.04
387.3279419	7.72
388.4400330	0.21
389.5404358	0.30
405.2494202	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	257.21
Annotation	Homalomenol E
Peak:m/z	Relative Intensity
93.9990387	1.21
116.3925629	1.89
119.2397766	1.29
121.0639648	3.51
124.2116852	1.34
126.8248596	2.97
136.9845734	0.69
145.0846252	1.42
169.0342102	1.42
170.188797	9.48
187.2636566	3.63
189.2218475	1.55
197.024704	9.64
199.2256012	9.98
200.8298187	0.43
203.2534943	5.17
211.16362	2.96
213.1846161	3.87
215.145462	1.42
215.9409485	3.90
221.0146332	7.19
229.2459106	7.34
230.2103424	0.69
238.5564117	16.72
239.197403	100.00
239.975235	3.48
247.641983	4.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0043106	0.20
112.8867493	0.12
116.8172302	0.49
121.1205139	1.19
122.9512024	0.50
125.0088348	0.97
126.8932343	0.61
134.9820404	2.13
141.0428467	0.69
143.0247498	0.80
147.0234528	0.90
149.0016174	0.36
151.1738739	0.60
155.1564789	0.49
157.0671082	1.12
158.9640503	1.55
160.4594727	0.73
161.1014404	0.46
162.96521	0.13
165.0054932	1.30
169.3084717	0.47
170.9569702	0.29
175.0950317	1.04
179.0904541	0.26
180.8553467	0.43
183.0122223	0.67
187.1129761	0.96
188.2579651	0.17
188.9692383	1.48
190.9716187	1.21
194.3421631	0.31
197.0802155	0.66
203.0527649	1.05
209.0812073	1.18
211.2490234	0.68
212.8284912	0.68
214.9299011	0.98
217.1802368	0.46
223.1714783	0.56
227.910675	0.25
229.0106506	0.19
231.1749573	0.28
237.0918274	0.36
238.9901123	0.18
240.6519165	0.49
242.7426147	0.23
245.2695923	2.33
247.2156067	3.27
251.3688049	0.96
255.3831177	0.20
259.2424927	0.95
269.2440186	0.30
277.2396851	0.70
279.258606	0.57
281.4933777	0.44
282.2392883	0.45
283.2108765	0.81
287.446228	0.57
294.9282837	0.49
295.5306396	0.73
297.2895508	0.45
299.2000122	2.00
300.2671509	1.07
303.4351196	0.86
304.7330933	0.34
305.3862	3.00
306.5111694	0.36
312.4465942	0.65
313.217926	0.32
323.2363892	100.00
341.1825562	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1349
Annotation	Vittariflavone
Peak:m/z	Relative Intensity
145.0924225	0.79
160.8963318	0.07
162.8504181	0.19
179.024826	5.37
189.1469269	0.08
197.0856628	1.33
205.0137939	0.04
211.255188	0.10
223.0611115	1.63
255.0664062	0.10
265.2190857	0.08
268.9743958	0.06
271.2331543	0.05
273.0714111	0.11
281.252594	0.98
287.538269	0.04
293.0931091	0.10
299.1636353	0.25
309.1702881	0.47
325.0987244	1.73
327.0549927	0.85
329.0519104	0.07
340.3198547	0.10
343.078064	100.00
343.6834717	0.34
353.1834412	0.05
359.1978149	0.58
371.2950745	0.06
385.1991882	0.18
401.0583801	0.06
409.3265076	0.03
416.0782166	0.24
417.1369629	0.04
423.1448059	0.11
427.243866	0.08
429.1419373	1.30
431.3547668	0.09
443.2327576	0.41
445.317749	0.09
447.2546082	0.15
457.1562805	0.16
458.4889832	2.28
459.3569641	0.67
460.3201599	0.98
461.3482361	0.14
468.361145	0.07
469.0324097	0.08
477.523468	0.16
487.2643433	1.53
489.164978	0.12
496.4874573	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2783
Annotation	16:0 LYSO-PE
Peak:m/z	Relative Intensity
153.1478577	0.25
178.9830017	0.40
214.029068	1.41
225.841156	0.10
255.2371521	100.00
255.8456421	0.61
264.8461914	0.16
265.9478149	0.38
282.3533936	0.18
297.6480713	0.15
301.3244629	0.32
332.2295532	0.28
335.2022095	0.24
351.3386841	0.15
353.388855	0.20
362.3053589	0.12
364.3424683	0.24
371.3838806	0.24
374.1386719	0.38
377.9308777	0.94
380.2462158	0.24
389.0315857	0.37
390.3696289	0.12
391.1429749	0.37
406.3484192	1.52
408.4324036	0.30
415.4104919	0.31
417.4342346	0.16
433.2287292	0.10
434.0637207	1.69
435.0688782	0.63
436.6105652	0.31
452.9173889	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.1018
Annotation	6-hydroxyindole-3-carboxylic acd 6-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
112.1300812	1.21
143.1108856	1.07
178.0533447	100.00
186.0154724	2.39
196.756134	1.86
269.1885376	2.26
304.668396	2.01
321.6230469	2.96
323.058075	1.33
337.2438049	1.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	370.83
Annotation	Unknow
Peak:m/z	Relative Intensity
131.0440369	0.04
172.9984131	0.29
174.2787628	0.04
194.9669647	0.19
196.8436127	0.26
202.9817047	0.21
233.0217896	0.68
234.9759827	1.54
285.1905212	0.13
286.8674011	100.00
302.9385071	0.59
326.9490356	0.04
354.2181702	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2199
Annotation	(-)-SNF 4435C
Peak:m/z	Relative Intensity
179.1286011	0.84
204.9613647	0.24
227.9676208	0.18
255.1774292	0.09
278.8718262	0.18
307.9922791	0.73
313.5184937	0.19
314.1979370	0.27
324.2364502	0.15
331.2130127	16.79
332.4433594	0.46
349.0186768	4.87
349.6765137	0.07
358.9805908	0.35
367.1613159	0.11
391.2450562	0.12
403.1606750	0.94
403.7871399	0.18
406.1244202	0.17
432.4016418	0.24
434.2441101	0.15
437.1271362	0.29
442.0153503	2.49
442.6413879	0.08
460.1846924	100.00
460.9538269	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.2
Annotation	Pteroside A
Peak:m/z	Relative Intensity
123.0014725	0.75
129.1984558	1.25
133.7622986	1.09
147.1998901	0.55
158.9557648	1.41
164.8920288	0.22
175.9368591	1.01
179.15979	1.26
190.1115112	2.04
192.9974976	0.56
195.7820435	0.38
201.1578979	0.76
207.0155334	1.06
212.9161987	0.43
215.1647644	2.17
239.1915894	0.31
255.0047913	0.47
277.3675232	0.51
281.3852234	0.38
283.0909424	1.00
293.210022	2.07
311.4395142	1.21
317.3641968	1.00
321.3929138	0.75
325.4594727	3.81
333.235321	2.72
334.9949951	1.43
337.0462341	0.92
339.2836914	0.30
347.3005066	1.20
351.1147766	0.92
352.7478027	2.60
355.2792358	0.76
357.055542	0.39
364.9533386	0.76
369.4467468	2.38
370.1425476	2.61
374.6776428	4.84
375.3457031	0.88
379.2266846	4.05
382.9287415	0.80
393.1949768	100.00
394.4468079	4.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1827
Annotation	5,2',4'-Trihydroxy-3,7,5'-trimethoxyflavone 2'-galactosyl-(1->4)-glucoside
Peak:m/z	Relative Intensity
272.3940735	0.05
323.2566528	0.10
329.0507812	0.05
341.2373047	0.62
342.2525635	0.03
359.1358032	8.59
360.1077881	1.35
383.3060303	0.03
448.2947998	0.03
494.4312134	0.06
503.4165649	0.60
521.1679077	100.00
522.1625366	16.10
522.7715454	0.10
526.2309570	0.05
562.9611816	0.22
588.3521118	0.03
591.2973633	0.08
598.3572388	0.08
602.1005249	0.02
607.1736450	0.10
608.2130127	0.06
621.1393433	0.06
638.0401001	0.04
663.1524048	0.02
665.9126587	0.02
666.7150269	0.02
674.8711548	0.05
683.6414185	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0982
Annotation	Syringic acid beta-glucopyranosyl ester
Peak:m/z	Relative Intensity
105.9536362	0.42
113.1313782	0.68
121.0462265	0.41
122.8807755	0.98
130.8448181	0.46
137.9472198	1.15
139.908493	4.13
143.0570679	0.77
153.1123657	13.05
154.9985962	29.57
160.0508728	1.30
179.9925079	2.58
180.9882202	3.83
182.0757446	4.07
188.163208	0.60
195.2128754	2.46
197.0395508	87.05
206.8642731	0.33
210.9831848	13.49
215.9640198	0.58
223.4727783	1.76
224.1245117	2.57
229.2492676	1.08
237.2154846	1.32
239.0602722	100.00
239.6698608	0.25
249.106781	3.72
251.1822205	0.42
253.1238403	0.90
259.3988647	0.82
263.1547852	1.22
269.2049866	7.63
272.2838745	0.50
281.0980835	0.59
294.0391235	0.77
296.9681702	0.77
299.152832	16.51
313.2296143	3.60
315.1216431	3.81
316.8496094	0.97
321.8396301	0.55
327.3586426	3.99
339.2211914	1.21
341.5162659	1.22
342.4220276	0.68
343.5584106	1.48
344.1881409	11.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	285.2071
Annotation	2,3-Dihydroxycyclopentaneundecanoic acid
Peak:m/z	Relative Intensity
85.14532471	0.12
131.0284119	0.19
152.9645996	0.09
169.0970154	0.56
171.1365967	0.32
173.0945892	0.11
181.2154388	0.16
183.2533569	0.39
184.5626984	0.27
189.090332	0.15
191.2045593	0.26
195.1123047	0.35
197.0708313	0.24
201.2605896	0.27
212.9389954	0.22
215.085022	0.47
221.1354675	0.08
223.2678223	34.16
225.3109436	0.52
237.3538208	0.16
239.2218018	2.27
241.273407	4.51
249.2684326	1.19
255.3039856	0.12
257.1896362	0.41
265.1142883	0.36
267.1915588	100.00
268.0467529	5.24
269.1914673	1.74
269.972168	0.38
285.1608276	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	584.81
Annotation	Unknow
Peak:m/z	Relative Intensity
181.0639343	0.43
213.1750183	0.06
248.8793945	3.11
264.9087524	4.66
280.9480591	0.94
332.7272949	16.17
348.8230591	10.24
359.0783081	0.30
362.9721680	0.11
364.7077026	0.42
365.4204102	0.11
414.8005981	0.14
416.6540527	34.08
417.2697754	0.49
432.5953979	19.67
433.2537231	0.07
447.6712646	0.17
448.6085205	0.72
492.0661621	0.17
497.3338013	0.04
500.5625610	100.00
501.2588501	0.47
516.3493042	3.15
517.1762085	0.28
538.0707397	1.93
546.5455933	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	302.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9249878	1.18
200.0378113	0.06
212.1886597	0.02
213.4749146	0.03
216.7703552	0.03
218.9129944	100.00
235.0034180	0.03
240.9778748	0.02
257.0241699	1.00
260.7796021	0.03
284.2132568	0.55
285.2230835	0.04
286.0912170	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	886.7687
Annotation	Unknow
Peak:m/z	Relative Intensity
279.1309814	0.34
542.4364624	0.32
642.5809937	0.89
724.1980591	0.39
775.1714478	0.90
784.6640015	0.46
793.9608765	4.20
796.5477905	0.51
798.6996460	0.71
831.7529907	10.65
832.5553589	2.03
843.5543823	1.07
849.0664673	1.54
855.3784790	0.28
886.8466797	0.66
1013.8176270	0.42
1041.6561280	2.39
1061.5736080	2.71
1170.7102050	1.21
1181.7099610	0.36
1190.6254880	5.70
1191.2553710	0.70
1195.0186770	0.24
1337.1402590	1.06
1522.7562260	0.24
1696.4339600	0.44
1713.3265380	0.29
1715.0589600	0.32
1763.2458500	0.74
1770.7604980	0.34
1798.3404540	4.96
1813.3577880	1.71
1820.4719240	0.22
1841.2371830	0.34
1846.3961180	5.16
1852.2061770	0.80
1864.3265380	1.51
1872.3918460	2.32
1893.5848390	0.80
1894.5554200	0.36
1897.4401860	60.33
1898.1419680	0.31
1901.4089360	6.54
1908.0931400	85.49
1913.7907710	0.43
1926.4548340	3.07
1928.5739750	2.41
1933.5982670	0.22
1937.3103030	2.33
1947.1571040	0.29
1950.1051030	6.95
1951.1564940	0.62
1953.9166260	1.21
1955.6507570	0.29
1957.2528080	5.32
1960.2476810	17.77
1960.8586430	4.27
1967.3177490	0.36
1968.3192140	100.00
1969.4561770	28.20
1974.8333740	15.28
1976.4538570	2.04
1980.1506350	28.14
1983.0295410	0.44
1984.3104250	2.96
1985.1359860	2.64
1988.0535890	6.80
1989.6013180	41.21
1996.9495850	0.29
1997.7541500	1.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.162
Annotation	Unknow
Peak:m/z	Relative Intensity
145.0040131	14.06
145.9487305	100.00
161.1472168	0.68
178.9768066	0.44
221.1307068	0.97
222.0515289	0.38
233.2459717	0.42
250.9968262	0.14
297.2652588	0.53
341.0961609	2.19
342.0308838	0.28
367.9311523	0.21
469.4142761	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	438.2375
Annotation	Lunarine
Peak:m/z	Relative Intensity
146.9383392	11.38
148.1298218	0.25
154.0956726	0.11
155.1762695	0.73
172.1367798	1.61
198.0544434	1.14
204.0460663	100.00
205.1513062	1.53
216.0678558	0.51
218.0976562	11.74
221.1353760	3.16
235.1849823	0.47
252.3889465	0.15
266.2574768	0.34
274.4420471	9.69
275.2834778	13.15
276.2556763	0.09
292.2499390	82.01
293.2961121	2.54
301.1376038	0.66
317.5122070	1.77
318.2659912	3.63
339.0119324	0.28
350.1060181	0.29
375.0626831	0.07
391.9567261	0.34
393.2876892	0.53
396.3255615	0.17
401.7993469	0.10
419.2063599	0.19
420.3686218	16.49
421.2865601	35.84
422.4163513	1.90
432.4424133	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.2133
Annotation	7,7-O-Dihydroebuloside
Peak:m/z	Relative Intensity
149.1942139	0.12
167.0160675	0.12
267.2803955	0.14
297.3714294	0.18
311.9873352	0.06
312.6987915	0.14
315.0288696	0.07
325.0857544	0.15
330.2574768	0.06
346.9390869	0.06
357.1040039	0.16
370.2683716	0.16
372.1575928	0.22
376.3405762	0.06
381.4990845	0.06
387.4748535	0.18
394.5057678	0.25
400.0286255	0.04
402.1402893	0.12
405.3114624	0.20
408.8196106	0.22
412.0756531	0.09
419.2979431	0.11
420.0854187	0.22
424.2290039	0.10
430.7018433	0.24
445.2621765	48.83
446.3428650	100.00
448.0394897	0.19
456.3176575	0.96
456.9723206	0.07
473.0924377	0.41
474.1793518	0.30
482.8043823	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
104.9517441	0.18
107.1736908	0.36
108.9603271	0.91
110.9639282	0.28
117.0139465	0.85
121.0993652	1.02
122.9784088	0.47
128.7720032	0.43
131.0784607	0.90
132.8134003	0.31
135.1408386	1.87
141.0362854	0.30
143.0402374	1.02
144.9579163	0.42
146.0290222	0.28
147.0512085	1.04
149.1746216	2.35
153.0562134	0.23
157.1227875	0.26
159.1660156	0.17
161.0248108	1.60
163.1496735	0.71
164.865036	0.21
169.0211487	1.14
172.9381714	0.61
175.018631	0.11
177.0397034	0.12
179.0486145	0.25
183.0092468	0.31
187.0527344	1.21
188.9813843	0.53
190.9620361	0.13
198.950531	0.44
200.7509613	0.43
203.2735596	0.79
209.0364685	0.46
209.9566956	0.29
211.0145569	1.05
213.2820435	0.19
215.1132812	0.31
217.1336365	0.73
221.2612915	0.44
223.1730957	0.93
227.093689	0.55
228.9359131	0.37
231.264801	1.18
232.7314758	0.14
237.2235107	0.38
239.2145386	0.14
241.0418396	0.86
245.2058105	2.24
246.0063782	0.18
247.2264709	2.67
249.0450134	0.19
255.3629456	0.50
256.2066956	0.36
257.1334839	0.43
258.0517883	0.24
259.2729187	0.25
267.0145264	1.15
269.1938477	0.37
270.9267883	0.21
276.9796448	0.78
279.2621765	0.24
280.7834167	0.30
283.2347107	0.63
285.2266541	0.27
287.4606018	0.27
295.1283569	2.01
296.3721008	1.05
297.0928955	0.37
299.1037292	2.39
300.0683594	0.74
305.1941528	2.33
313.3411865	0.73
321.4768066	0.21
323.2339478	100.00
323.8499756	0.73
324.992981	0.37
327.2708435	0.64
332.9367371	0.39
340.3087769	1.22
341.2967224	1.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.83
Annotation	Unknow
Peak:m/z	Relative Intensity
190.7812347	0.18
196.9771118	0.08
206.8931885	1.74
212.7676086	0.08
223.2317505	0.15
228.1793823	0.16
229.3581238	0.07
238.9540405	0.03
250.9562073	0.05
269.0422363	0.34
271.3746338	0.45
274.7409668	100.00
275.3519592	0.70
280.9895325	0.06
290.7530823	17.52
298.8894653	0.30
328.0904846	0.08
344.1830750	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1346
Annotation	2''-O-p-Coumaroylvitexin
Peak:m/z	Relative Intensity
167.2170258	0.05
174.2353058	0.14
175.1616669	0.19
177.0141602	0.03
179.2560730	0.09
185.1430359	0.03
186.1182709	0.04
187.0657501	0.20
187.7753906	0.03
199.2689819	0.16
203.0819855	0.41
205.1053619	0.44
206.2007141	0.08
213.3621979	0.07
214.8801880	0.03
227.0831146	0.32
229.1762085	0.05
231.1085815	0.15
243.2572632	0.11
245.1909790	2.68
246.4281006	0.47
247.2186584	0.10
255.1511993	0.09
256.9639282	0.05
261.2411804	0.07
263.2279053	0.25
269.0690613	0.23
271.1174316	0.19
273.0489807	1.26
274.1748657	0.06
281.3048096	0.03
283.9656372	0.03
285.2977295	0.09
287.1004028	6.50
288.2414551	1.59
289.1112976	17.35
290.2271118	2.39
293.0529785	0.03
299.0748291	6.28
300.1344604	0.80
301.0703735	0.13
313.2799072	0.04
315.1024170	0.12
318.1345825	0.04
327.1513062	0.14
329.0733032	0.42
331.3068848	0.63
332.2438354	0.06
339.1859741	0.19
341.2449951	0.27
342.0696411	0.09
344.7337036	0.10
357.1445312	0.42
358.1044922	0.14
361.2307129	0.05
362.9536133	0.04
376.3074951	0.03
379.0412598	0.07
381.2117310	1.21
382.3512573	0.14
393.1495361	0.03
397.6271362	0.07
404.9372559	0.03
407.1697998	42.49
408.2739258	8.87
409.3131714	0.62
410.2395020	0.53
411.1699829	0.16
412.3165283	0.12
413.4364624	0.06
415.2030640	0.02
416.2910156	0.08
423.0631104	0.05
425.1155396	100.00
426.2276611	17.94
433.2494507	0.35
434.2546997	0.23
436.4936523	0.09
440.1753540	0.05
449.1805420	1.63
451.1687012	25.97
452.1971436	4.63
453.0358276	0.02
457.0167236	0.09
467.1693726	0.72
468.2019043	0.16
469.1332397	0.03
471.5306396	0.03
487.2915039	0.09
489.6558228	0.13
491.3770142	0.17
493.1133423	0.22
497.4197998	0.07
498.2886353	0.11
500.6517944	0.04
501.5628662	0.24
509.4490356	0.03
515.1398315	0.31
516.1181030	0.15
522.2611694	0.19
531.8757324	0.20
533.2872925	1.00
534.3161011	0.39
541.0957642	0.10
542.0254517	0.09
547.4519653	0.08
555.1579590	0.03
559.2111206	7.69
560.1807251	2.83
568.0670776	0.07
568.9378662	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2756
Annotation	Eurystatin D
Peak:m/z	Relative Intensity
140.8839722	0.08
146.9203949	0.05
155.1340485	0.10
160.8721924	0.30
162.1275330	0.20
179.1904602	0.55
194.9413910	0.05
211.8830872	0.31
221.0627289	0.16
224.3786011	0.09
233.6410522	0.04
241.2392273	2.71
242.3237915	0.85
253.0359497	0.27
255.3187866	1.47
256.3742676	0.34
258.2450867	0.21
262.9547729	0.05
265.1926575	0.18
267.6315308	0.04
269.3322144	0.95
271.2406921	2.91
272.3134766	0.41
281.1255493	0.18
283.2731323	7.64
284.1665344	1.30
285.3677368	0.36
287.2749023	100.00
288.2965088	20.42
289.2244263	0.16
311.3131714	0.27
315.2936096	0.08
322.7109375	0.12
324.5606689	0.08
325.5213013	0.05
329.2361450	4.90
330.3246155	0.65
341.2908325	0.60
342.2755432	0.21
349.2204895	0.05
355.1896973	0.05
359.4654541	0.06
360.4224854	0.05
361.0681458	0.03
363.2803955	0.25
366.0779724	0.04
368.7945862	0.25
378.4292603	0.39
382.2543945	0.08
383.2068481	0.05
387.4433594	0.07
403.9883423	0.34
412.2303772	0.32
414.2672424	0.55
420.1502380	0.07
431.4488831	0.41
432.1225891	0.61
434.0574951	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.07
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
79.80014038	4.20
81.94688416	0.89
95.32060242	2.24
96.92317963	100.00
98.96734619	1.28
117.2481384	2.45
125.1146088	2.24
136.8258667	1.99
156.9677277	0.80
164.9983063	3.63
169.1997528	2.59
179.1703339	1.08
181.1352081	2.49
194.239975	3.76
195.2132263	6.85
197.4186554	1.08
207.1800995	24.28
207.9131012	4.50
209.0592194	15.37
211.2590637	1.08
214.9825592	2.77
220.1833954	1.18
221.1976776	4.20
223.1654205	11.94
228.2167206	4.30
233.1154938	7.25
235.5159302	3.53
251.076004	72.97
252.1734772	5.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3388
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
181.0809326	0.05
184.0662079	12.57
191.2804565	0.49
233.1956787	0.15
258.2438354	0.07
260.6914062	0.11
296.5486450	0.35
298.6572266	0.14
307.3876953	0.14
315.4629517	0.08
337.6129150	0.18
345.9352417	0.09
371.3296509	0.48
391.1806030	0.09
418.4703369	0.38
436.2910767	0.14
443.1785889	0.61
445.4171143	0.15
453.5127563	0.23
457.7919922	0.24
466.1857910	0.09
471.2008057	0.10
474.4403687	0.25
484.4636841	0.33
485.0835571	0.10
502.4822998	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	518.9
Annotation	Unknow
Peak:m/z	Relative Intensity
156.0898743	0.03
158.9251404	0.41
160.2861328	0.44
161.1589355	0.20
174.8724365	1.04
176.0048828	0.06
177.0854645	0.05
199.1437073	0.01
200.9836121	0.26
214.9971619	0.12
217.9213867	0.06
228.9815979	0.05
230.0440063	0.08
231.1301117	0.09
245.1190796	0.15
246.0884705	0.06
246.9134827	0.02
273.0101318	6.46
273.9801636	4.85
275.1127319	5.70
288.9795532	15.77
290.0112305	5.57
291.0101929	5.13
387.0724487	0.11
387.9618530	0.71
388.9558105	1.25
402.9974365	77.52
403.9907227	86.07
404.9124146	100.00
444.0415039	0.08
445.1081543	0.16
445.8808594	0.07
471.9151001	0.65
473.0158691	1.30
474.0579224	0.09
509.3204956	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.0961
Annotation	Unknow
Peak:m/z	Relative Intensity
123.1299667	0.78
123.9500122	0.07
135.0896912	0.07
137.0508118	0.03
139.1085052	0.05
144.8524475	0.11
150.9614868	0.07
152.9854584	0.52
161.1301880	0.06
162.8256531	0.07
169.1472473	0.10
171.0879669	2.71
174.1302948	0.05
175.2051697	0.15
177.1564026	0.05
183.3184052	0.06
186.9590454	0.05
189.1342773	1.05
195.0017242	0.07
197.2044983	0.05
201.2305908	0.50
203.3867035	0.08
207.2033844	1.41
211.1951904	0.08
213.1651917	0.08
217.1660767	0.04
218.9677429	2.20
219.5948486	0.04
221.2620239	0.05
225.4852295	0.06
231.2535095	0.04
237.2116394	29.37
261.8893433	0.06
263.3371277	0.63
264.8495789	0.08
271.0954590	0.05
275.1701050	0.08
279.2119141	0.06
281.2397766	100.00
282.2301025	0.14
285.1362000	0.07
290.0743103	0.09
299.4320679	0.06
300.7316895	0.08
305.3044128	0.07
314.1914673	0.07
315.2294312	0.60
317.2169495	12.90
319.4197083	0.04
323.8755188	0.21
325.2929993	0.23
331.0089111	0.13
341.3316956	0.05
342.2232971	0.46
343.2245789	3.23
346.3051453	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.135
Annotation	Vittariflavone
Peak:m/z	Relative Intensity
145.0812988	0.46
161.0555267	0.07
179.0025787	5.73
189.2095947	0.18
197.1554871	0.92
223.0118561	2.27
243.2175598	0.04
255.2713013	0.30
281.2758179	0.90
291.0348816	0.04
296.9734497	0.10
299.1844788	0.84
307.3809814	0.05
309.2139893	0.48
323.3684082	0.13
325.152832	1.39
341.5021973	0.12
343.0882568	100.00
353.2076416	0.40
359.2084045	0.29
371.0235596	0.45
375.4152527	0.05
385.1840515	0.19
386.483429	0.04
401.3009949	0.06
409.5840149	0.07
412.9685364	0.05
417.1524658	0.08
421.0090027	0.23
424.3070374	0.05
429.1138611	0.84
429.7730713	0.11
433.6109009	0.09
437.8026123	0.09
443.2302246	0.72
445.3282776	0.04
447.2930603	0.39
458.202179	0.49
459.0619507	0.36
460.3459167	0.29
461.3102112	0.29
462.3988342	0.08
469.9784851	0.18
471.1449585	0.05
482.1045227	0.31
483.9081421	0.23
486.1339417	0.09
487.387146	0.82
490.0259399	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
56.8238831	0.03
72.8500748	0.01
75.0001221	0.04
84.9167938	0.44
86.9933777	1.25
101.1132202	0.01
110.8884583	100.00
111.7496338	0.10
116.8172607	0.03
126.9435272	0.19
128.9549713	2.38
130.9271698	1.01
144.9403839	0.09
146.8358307	0.03
154.9964294	0.38
172.8918304	23.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.2342
Annotation	Ixerin N
Peak:m/z	Relative Intensity
160.9739990	0.10
161.9651794	0.04
163.0814514	0.10
164.7345428	0.17
165.9898376	0.03
167.8513184	0.03
179.0716553	0.17
188.3526306	0.01
190.2156677	0.01
193.1234283	0.06
195.0281982	0.05
205.4211426	0.07
206.1693420	0.09
207.2208405	0.10
208.3099976	0.01
209.1240540	0.09
210.1784363	0.04
221.0534668	0.06
222.1517487	0.03
223.2449951	0.04
232.1870422	0.01
293.5444946	0.01
299.4769592	0.01
301.4066162	0.04
315.3264771	0.05
325.4115601	0.05
327.9009399	0.06
329.3149414	0.14
330.3456421	0.07
331.1050415	0.06
337.2479858	0.02
339.2976074	0.23
340.3868408	0.07
341.2858887	0.04
342.2819824	0.24
343.2340088	3.42
344.3690186	0.87
346.0645142	0.07
347.2771606	0.23
348.2946777	0.02
355.4664917	0.01
357.2857056	12.26
358.3118896	2.38
359.2006836	0.01
360.2536621	0.28
361.2770386	5.75
362.3334961	1.29
373.3126221	0.01
375.2943726	100.00
376.2819214	19.58
377.0971069	0.01
386.2931519	0.04
389.3622437	0.03
390.3662109	0.01
397.4161377	0.04
399.2032471	0.03
401.4277344	0.01
402.1817627	0.01
404.1744995	0.01
415.4246826	0.16
416.2189941	0.01
417.2298584	0.19
418.4650879	0.04
422.3220825	0.02
425.4878540	0.01
428.4192505	0.03
431.2697144	0.02
432.3214722	0.03
434.3024292	0.01
435.0168457	0.03
436.2537231	0.04
442.2040405	0.02
445.1992188	0.14
446.1865845	0.05
451.2457886	0.02
464.5230103	0.02
466.4545288	0.01
467.3241577	0.01
471.4453125	0.02
473.4089355	0.04
477.5315552	0.04
483.4746704	0.09
491.4346924	0.19
492.2877197	0.08
493.0239868	0.06
494.1369019	0.03
495.3724365	0.01
496.4041748	0.01
500.0545044	0.03
505.3173218	0.05
506.3163452	0.03
519.2973022	1.05
520.3943481	0.23
522.3638916	0.50
523.4093628	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1447
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
170.6705933	0.09
171.2997894	0.05
175.1142273	0.35
177.0103760	0.06
178.9641571	2.32
180.1060028	0.16
182.0865021	0.03
185.0919037	0.35
192.1400909	0.41
197.2005310	0.55
207.9417267	0.06
209.1089172	0.05
210.1028137	1.94
211.0414124	0.21
226.1910248	0.11
228.1231689	0.33
231.0403290	0.03
243.1198730	0.07
252.2514038	0.14
254.0571289	13.41
255.1055298	1.70
262.9301758	0.08
269.0309448	0.16
269.9205322	0.06
272.1161804	34.06
273.1932678	3.07
286.1905823	1.16
288.0735474	4.19
289.1021729	0.58
297.8487854	0.08
304.1557617	14.68
306.0798340	100.00
307.2142944	10.08
311.4185791	0.06
319.6653442	0.17
320.7238770	0.35
328.8997803	0.06
338.0869141	39.56
339.1934814	3.60
353.1940918	0.35
362.3159790	0.11
384.4965210	0.04
395.1287231	0.06
453.8834229	0.04
464.1589966	1.42
465.2348022	0.24
467.3553467	0.08
477.2603760	0.11
482.1249390	37.58
483.1394043	7.21
483.7648315	0.05
489.9353638	0.07
499.2240601	0.06
504.6564331	0.04
509.0663452	0.07
511.0335083	0.17
513.8867188	0.06
521.3803711	0.25
524.0644531	0.05
530.0321045	0.06
549.2173462	0.42
567.3162231	0.04
575.3131714	0.23
576.1798096	0.30
593.2431641	15.47
594.2716064	3.42
595.5353394	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.9771
Annotation	Unknow
Peak:m/z	Relative Intensity
148.1481018	0.24
155.1093140	0.18
177.1208191	0.16
201.8097076	0.05
215.1899719	0.12
260.0684814	0.16
289.1661682	0.08
290.0167542	0.11
303.8508301	0.43
308.0164185	0.21
309.1333923	0.03
318.8936462	0.14
321.9275818	0.08
330.0725708	0.10
348.0172729	1.25
353.1010132	0.33
363.1313171	0.04
372.8294067	0.15
375.7167664	0.15
391.2433472	0.06
391.9725037	0.13
394.0425110	100.00
419.2275696	0.57
420.0420227	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	540.86
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9529724	2.64
198.9707489	0.19
228.9473877	0.28
268.4063721	0.09
272.9884949	26.25
274.0984497	0.07
289.8661499	0.09
296.8956299	0.05
310.0089722	0.16
312.0963745	0.04
312.9849243	0.16
315.0828857	0.10
330.7901001	0.09
379.7690430	0.07
383.0140991	0.11
385.2943115	0.41
387.0332031	100.00
388.1599731	0.07
389.0322266	0.14
390.1447754	0.30
390.8211670	0.10
392.1141968	0.05
395.2073364	0.04
403.0723267	0.09
403.9481201	0.08
409.0884399	0.04
423.8137817	0.28
424.9356079	1.00
426.2377930	1.11
427.0578003	4.50
428.1204834	0.41
429.2559204	0.18
447.1561890	0.06
450.2180786	0.19
451.8653564	0.05
453.0983276	0.08
466.7459717	0.52
469.1783447	0.14
473.0304565	0.09
483.6319580	0.42
485.1920776	0.07
493.8327026	0.92
494.9442749	1.54
496.3312378	0.65
496.9515991	0.86
511.8238525	0.10
513.0697632	0.15
521.8031006	0.14
522.8801270	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	525.1204
Annotation	Galactotriose
Peak:m/z	Relative Intensity
197.9203491	0.28
264.0610352	0.24
273.1137390	4.83
288.9728394	0.36
304.8038940	0.21
326.9796753	0.45
344.9136963	0.27
354.1663208	9.50
363.0896606	100.00
363.7009888	0.47
410.2558594	0.31
455.0653687	0.77
484.9144897	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.16
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
172.9178467	0.09
227.2825470	0.06
233.1090393	0.09
247.0130463	0.10
253.2807770	0.08
254.5581360	0.07
263.2120056	0.08
267.1688843	0.22
268.1267700	0.24
269.0893555	0.52
281.2316895	0.64
282.1100464	3.57
283.1729736	5.24
284.0576782	0.50
287.1918945	0.35
288.1192627	0.12
289.1641846	0.65
293.1098022	0.56
295.0747681	0.30
297.2233887	6.10
298.0139160	0.44
310.0211182	0.79
311.0712280	68.09
312.1705322	3.83
321.3853149	0.07
323.0861206	3.06
324.0899048	0.31
325.0599976	0.19
333.1011963	0.20
335.3006592	0.65
337.3435669	0.13
339.2042847	0.69
341.1600342	25.27
342.3536987	0.51
351.2165527	0.22
353.1375732	5.05
354.1845093	0.49
355.0296631	0.20
359.3646240	0.07
361.2801514	0.49
366.1221924	0.19
367.3762207	0.10
368.0129395	0.07
369.3027344	0.33
370.2055664	0.19
371.0983887	0.16
375.1998291	0.27
379.3448486	0.77
383.1398315	1.96
395.0533447	0.31
397.1658936	3.78
398.3900757	0.18
407.1800537	0.64
411.0103149	0.08
413.5016479	0.77
415.1790771	100.00
416.2850342	7.01
418.2958984	0.05
419.2698364	0.10
425.3616333	1.15
429.3731079	0.81
430.5225830	0.12
431.2700806	0.17
433.1894531	0.10
439.1973267	0.49
440.6806641	0.29
453.3121948	0.06
455.2667236	0.08
456.1309204	0.06
457.3064575	1.70
458.2845459	0.35
469.5256348	0.22
473.2304077	20.69
474.3035278	1.24
476.0558472	0.11
485.2778931	0.09
487.3957520	0.46
489.2048950	0.09
491.0785522	0.25
500.4441528	0.55
501.3157349	0.45
502.6520996	0.55
503.2849731	5.13
504.3983765	0.92
515.3717651	0.38
516.3895264	0.79
522.4741821	0.73
531.1824341	1.31
532.1238403	0.11
533.2509766	2.30
539.2980957	5.19
542.3264771	0.19
545.2001953	0.95
554.0991821	5.31
556.3510132	0.12
557.0787354	0.13
557.8287964	0.22
558.4511108	0.22
559.3364868	1.20
560.3188477	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.0150452	0.31
108.8255844	0.39
121.036026	1.12
123.164238	0.18
135.1601715	0.93
136.652298	0.31
146.9950562	0.35
149.1030884	2.20
154.9765015	0.38
157.052063	0.52
161.017746	1.55
168.9388428	0.29
175.1261292	0.49
183.1087341	1.01
187.0599976	0.55
189.2030334	1.17
191.1315155	0.27
197.0744019	0.75
198.9744415	0.24
203.2766876	0.24
205.4866486	0.69
211.111145	3.33
217.1054688	1.12
218.7522583	0.29
222.927002	0.82
225.3005371	0.23
227.0337219	1.12
229.1049194	0.29
231.270813	1.13
235.0571289	0.23
239.0792236	2.45
240.9094849	0.69
244.9780884	1.33
247.2887268	3.08
253.139801	0.26
265.4264832	0.27
267.5036316	0.46
269.2738647	0.27
271.193634	0.85
281.3338013	0.53
285.2783203	0.59
287.0913696	0.60
295.2417603	1.19
296.773407	1.65
299.3168335	1.43
305.1732788	2.90
312.345459	0.35
313.2630615	0.45
323.2335205	100.00
324.0527649	0.64
331.7954102	2.86
340.1662903	0.46
340.9102478	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0338
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
107.8413391	0.04
118.9019928	0.05
119.9803009	0.06
121.0636597	0.04
123.0137024	0.03
131.0729980	0.04
146.8359680	4.41
156.9460297	0.02
160.9810181	0.10
162.4552155	0.08
164.2851868	0.35
170.1454010	0.34
173.4368744	0.04
174.8536987	100.00
175.9399872	0.03
176.6867981	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2422
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
97.05236816	1.87
98.93503571	2.07
109.1581116	2.09
119.1347961	0.48
122.9210739	2.86
130.8752747	3.28
138.9996033	3.49
141.0794067	0.58
143.0466461	0.53
150.9084167	0.82
165.224411	0.82
172.9833679	1.73
177.1111298	1.20
179.1159515	1.91
183.3418274	4.93
186.9822693	1.11
197.0344238	16.28
203.2554321	1.15
207.6204834	0.77
211.197998	0.43
217.1127625	0.87
221.3110352	2.23
225.3347168	1.30
237.1123657	0.82
239.2727356	22.67
247.6322327	1.19
253.2862549	4.00
255.1623535	4.96
255.9585266	1.43
261.3651123	2.49
263.4300232	1.50
265.2077637	1.14
269.548645	2.06
279.2261353	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	190.98
Annotation	Unknow
Peak:m/z	Relative Intensity
149.9322662	100.00
150.6335602	0.07
167.1023254	0.12
167.7408295	2.67
170.2873077	0.19
178.9268341	0.20
190.8203583	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.8666229	0.35
108.8344574	0.28
110.9774933	0.22
120.9699097	3.08
123.2258072	0.23
124.5890579	0.17
128.7710571	0.37
133.0003662	1.12
135.0944977	3.42
137.0641785	0.73
143.0003967	1.09
147.2095642	0.12
149.1272583	1.38
151.0672302	0.26
157.0115967	2.98
159.0578461	2.73
163.3887329	1.65
164.9591675	1.43
166.9933777	0.42
169.0841827	0.32
171.109375	0.21
173.0817413	2.18
175.2861328	0.25
176.9878845	0.11
179.207489	0.57
181.1788025	0.86
183.0766296	2.61
186.972168	1.35
189.1566925	0.20
190.9904327	0.24
193.0242615	0.81
197.107666	0.21
198.2803192	0.46
199.1833954	0.27
201.2229614	0.31
203.0705872	0.65
205.1599426	0.47
207.0965881	0.78
210.9230347	0.84
213.0065002	0.26
215.3004761	0.20
216.9141541	1.01
217.515564	0.17
219.4938354	0.12
223.3078003	1.13
225.242157	0.08
227.2606506	0.10
229.1833191	0.41
230.7086792	0.19
231.3336487	0.12
235.0494995	0.14
239.2919617	0.27
242.2570801	0.13
243.2145996	0.64
245.0625916	1.02
247.2670288	8.32
253.4290771	0.49
257.4792175	0.20
259.1481628	0.91
260.9093018	0.48
263.0455933	0.35
264.3009338	0.18
267.2145996	0.65
273.0479126	0.41
279.2694702	0.17
281.2497559	0.18
282.0786438	0.21
283.1696472	0.65
285.9321594	0.25
287.2362976	0.49
295.37323	2.90
297.0009155	0.77
297.6152344	0.34
299.3070068	6.24
300.25354	0.37
305.3590698	2.96
306.3894653	0.11
309.3314209	0.18
310.3243408	0.68
312.1662292	0.19
313.2781067	0.92
314.2763367	0.26
323.2470398	100.00
323.8984985	1.89
324.6564941	0.39
325.5515442	0.55
327.3800659	0.36
332.3312988	0.26
340.3678894	0.41
341.3710022	1.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1662
Annotation	Verbasoside
Peak:m/z	Relative Intensity
130.7829437	0.14
149.0527649	0.89
161.1510925	0.22
167.0584106	0.06
191.0641937	0.20
205.3237610	0.03
220.7205353	0.55
230.2330322	0.04
239.1210938	0.14
245.1214905	0.03
251.1490784	0.07
263.3917236	0.07
269.8341675	0.06
271.3063965	0.16
278.9967041	0.02
280.2401428	0.04
281.3089600	0.17
290.0962524	0.03
293.0339050	0.27
299.1912842	0.18
311.0735168	1.29
314.1854858	0.03
325.1511230	0.03
327.0131836	0.10
329.4122009	0.04
331.1915283	0.04
333.3537598	0.06
337.2585754	0.07
340.9478455	0.17
341.7038574	0.09
364.9968567	0.15
367.1149292	0.03
375.3266296	0.10
385.0360413	0.07
389.1292114	0.11
397.1005859	0.04
402.2474060	0.03
409.2862244	0.03
412.1974182	0.14
415.1516418	100.00
415.7667542	0.46
421.5758362	0.08
423.3727112	0.02
425.1863098	0.20
441.3389587	0.03
443.1681213	0.22
452.3580322	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1827
Annotation	Chrysosplenol C 6,4'-diglucoside
Peak:m/z	Relative Intensity
197.0093231	0.06
223.064743	0.03
231.391449	0.03
315.5078125	0.02
323.3829346	0.07
341.2216797	0.38
343.3904419	0.02
357.132019	0.01
359.2017212	8.87
362.1102905	0.01
375.3536987	0.01
444.9801636	0.02
473.4802246	0.02
503.2602539	0.19
521.1364746	100.00
521.7619019	0.23
544.7910767	0.01
548.357605	0.08
551.2989502	0.01
563.2782593	0.02
587.2212524	0.03
598.9494019	0.04
621.2573242	0.05
630.0706177	0.02
636.1967773	0.15
636.9196777	0.01
637.854187	0.02
665.3297729	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.214
Annotation	Atalanine
Peak:m/z	Relative Intensity
205.1525879	0.09
262.4268494	0.11
289.2364197	0.12
305.8130493	0.29
307.1267395	0.21
308.1271057	0.10
323.0516357	0.28
340.9525757	0.53
342.1750488	0.09
383.5324707	0.05
390.2406616	0.22
392.2749023	0.10
470.1968384	0.13
475.1858521	0.07
503.2225952	100.00
504.3121338	15.94
510.0328979	0.21
606.2273560	0.17
632.2322388	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.19
Annotation	Celorbicol
Peak:m/z	Relative Intensity
83.09802246	0.68
85.10720825	0.20
96.85328674	0.57
101.0816956	0.34
109.1989441	0.29
118.7817688	0.22
128.8956451	0.49
143.0110474	1.06
143.857666	0.60
155.0267181	0.51
156.8394623	0.49
159.1318512	0.72
161.1947632	0.28
165.1655426	0.90
169.0653839	0.96
169.9365387	0.14
170.9445953	0.48
173.1196136	0.26
182.9414978	2.09
189.1042786	1.46
192.9761353	1.76
196.9265747	1.09
201.1891022	0.54
211.2361298	0.83
215.0800934	0.38
216.8081207	0.32
217.4770508	0.34
224.9417267	5.46
225.5997467	0.27
227.0398407	0.66
228.8360596	0.81
230.2086639	0.14
235.1046753	11.30
238.1067352	0.29
240.3757935	0.95
243.1029053	1.45
253.1857147	100.00
271.0731201	4.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
227.1941376	11.64
229.2845764	19.15
245.9755859	48.72
264.1732178	25.08
269.8834229	12.24
327.2685547	15.45
339.5342102	11.00
363.155365	20.52
369.1513367	9.11
373.6668701	12.25
380.046051	21.43
385.1983337	17.33
390.0213318	11.00
391.3170776	30.60
398.1801453	12.93
408.2774353	100.00
411.3363037	23.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.05
Annotation	TOPOPYRONE C
Peak:m/z	Relative Intensity
148.8290405	4.53
198.0620422	11.76
248.9538574	6.58
279.0288391	20.81
282.5161438	8.68
321.0426636	100.00
349.4820862	5.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	303.1448
Annotation	Urechitol B
Peak:m/z	Relative Intensity
93.0748978	0.11
95.1078110	0.12
97.1043091	0.06
101.1105652	0.10
107.1500702	0.15
109.1061859	0.13
110.8723297	0.62
112.9566650	0.08
115.0742035	0.24
119.0345917	0.03
120.9791336	0.11
123.0180435	0.39
124.9532471	0.10
126.8424988	0.58
127.4902191	0.14
129.0334167	0.74
133.1980896	0.06
139.1922302	0.16
141.1496277	0.27
143.2927399	0.04
145.0416565	0.45
146.6448669	0.19
151.1468201	0.08
152.9591675	0.20
155.0014038	0.39
157.0888367	0.16
158.8592224	0.08
161.1956177	0.79
163.0494232	0.07
169.2745361	0.33
173.0904846	0.02
177.1547394	0.17
179.1608887	0.83
183.2381592	0.03
185.1165161	0.90
187.0464020	1.41
191.0838165	0.05
195.0882416	0.07
201.0318909	0.28
202.1721802	0.05
205.1993103	2.24
206.9801941	0.04
213.3204346	0.08
215.1603088	0.06
216.9934998	0.18
218.4849243	0.03
219.1600342	0.04
221.1664429	0.24
223.2373657	6.54
225.3323059	0.12
227.0557251	0.21
228.0963135	0.05
231.0388794	0.40
235.0501709	0.05
239.2389526	0.12
241.1899414	12.51
243.0840759	0.04
244.1362610	0.09
246.7623901	0.04
249.1589050	1.74
256.9142456	0.33
258.4650269	0.07
259.0900879	0.61
260.1241150	0.12
264.9148560	0.04
266.1328125	0.04
267.2775269	4.68
275.0400391	0.03
285.1408691	100.00
288.1468506	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.2419
Annotation	18-Hydroxyoctadeca-9Z,12Z-dienoic acid
Peak:m/z	Relative Intensity
94.92819977	0.75
96.94471741	0.67
99.10372162	0.69
106.9990234	0.73
108.9886475	0.56
111.0842133	0.83
118.9539413	0.12
121.008667	0.65
122.9742508	2.43
124.0073242	0.13
125.037796	0.65
127.0752411	0.46
133.0708618	0.19
135.099823	0.98
136.4706421	0.15
139.050293	3.79
141.1506042	0.56
146.9908447	0.80
151.0690918	0.12
152.1139526	0.28
152.9828186	1.62
155.0845032	1.46
156.8826294	0.16
161.2763062	0.14
165.1446228	0.44
166.9771118	0.50
169.0356445	0.32
171.2509918	0.11
173.2801819	0.36
174.9916992	0.88
179.1587524	0.38
180.8132782	0.17
183.114151	1.35
184.9335632	0.42
189.0246277	0.56
191.0955811	0.38
193.2837219	0.59
195.2068939	0.67
197.0464172	4.61
198.9457703	0.61
200.9249268	0.25
202.0249329	0.21
203.303833	1.81
205.1407776	0.44
209.047821	0.25
211.2000427	1.39
213.0879822	0.52
215.0958557	0.58
219.2935181	0.16
221.2222595	5.70
223.3500671	0.55
225.222229	1.52
227.3232117	1.95
235.0676575	0.12
236.0477905	0.46
237.327179	5.38
237.9787903	0.49
239.072052	17.16
239.6889038	0.14
241.0028076	0.72
243.1419067	0.57
250.9962158	2.09
253.2688599	0.74
255.2033081	2.94
255.8870239	0.46
256.9987793	1.50
260.2738953	0.20
261.125824	2.39
265.2846985	0.26
268.198761	0.27
269.4381104	0.22
276.9385376	0.64
279.2258911	100.00
280.5046387	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	188.0702
Annotation	Deethylatrazine
Peak:m/z	Relative Intensity
117.9551392	0.20
142.0349121	0.80
144.0821075	10.05
146.0290375	100.00
159.9698029	0.71
170.0707245	4.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	167.09
Annotation	3-(4-Methyl-3-pentenyl)thiophene
Peak:m/z	Relative Intensity
120.0317535	13.53
120.9764099	100.00
125.8755951	0.04
131.9686584	0.13
139.0814667	0.12
148.8398895	2.38
149.9407501	10.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.92
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9901886	2.37
159.8872681	0.52
161.0522766	0.86
199.0350342	0.53
200.0141907	0.40
200.9812927	0.27
201.9663696	0.10
216.9508514	0.05
218.1089172	0.06
219.1979218	0.02
220.2613831	0.04
228.9487762	0.22
230.1834564	0.12
230.9881744	0.67
232.0045166	0.04
272.9804688	27.63
274.0037537	14.87
275.0369873	31.11
276.0739441	5.19
329.0575562	0.04
346.0852051	0.07
373.0323486	0.02
386.9920959	24.21
387.9723816	25.16
388.9599304	100.00
390.0165405	25.57
413.3067322	0.04
447.0174866	0.10
447.7488403	0.04
455.5108948	0.02
457.1573792	0.18
458.5945129	0.20
459.2138672	0.10
459.9483948	0.04
461.8608704	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.2629
Annotation	omega-Cycloheptylundecanoic acid
Peak:m/z	Relative Intensity
80.83570099	0.99
83.05808258	0.73
84.75763702	0.56
89.0996933	0.91
91.11712646	1.66
93.03827667	0.65
95.05514526	2.83
97.08460999	4.31
98.18054962	0.70
99.19965363	0.73
100.8082275	6.02
107.1511536	1.67
109.0244827	6.81
111.1319427	1.45
113.0387268	0.52
114.9710846	2.73
121.0565109	5.75
123.05439	1.09
124.9535828	1.80
129.1089325	0.46
133.1117249	1.42
135.1162262	7.25
137.1083374	3.75
141.3343506	0.35
142.8450317	3.77
149.1535797	6.25
150.9530029	3.39
155.1351929	0.73
157.0055695	3.27
163.1498718	5.35
165.1822815	7.20
169.0028839	3.19
170.9441833	5.55
173.074234	0.90
177.2371521	3.45
178.986557	0.87
181.0993042	0.32
185.0447693	2.77
189.2629395	0.80
191.2800293	12.53
194.7442017	0.25
195.3638306	0.96
196.9716187	0.77
199.1205444	3.85
205.1914978	2.16
207.214447	3.25
210.6712341	0.66
212.5809326	2.42
213.2567749	2.36
219.3351135	0.57
223.0787354	1.26
225.0580444	8.79
226.1317749	0.81
227.2910767	1.76
228.9585571	1.73
237.2049561	1.04
239.0779724	6.28
241.1444702	1.82
247.2539673	35.16
251.0520935	0.28
253.5801697	1.42
255.4312134	1.16
265.2459412	100.00
267.0726624	1.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
290.5920410	0.68
362.3333740	0.17
374.6020508	0.36
404.8511963	0.26
414.7544556	0.70
430.7873535	1.29
452.8394775	0.97
458.5276489	14.72
459.1799927	0.16
497.7914429	0.20
510.2244263	0.44
520.7858276	0.89
539.4970093	0.29
540.8425903	1.42
542.5202026	100.00
543.1924438	0.79
544.7086182	0.55
566.8314209	0.13
568.8773193	0.53
580.3201294	1.70
581.0532837	0.41
582.8902588	0.19
592.4105835	0.17
608.7014771	0.17
609.9406738	0.34
626.6208496	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.29
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
147.0488586	0.28
195.9745331	3.36
208.8306427	0.24
213.9832153	1.24
222.9831238	0.57
225.8463745	0.45
237.3214264	0.73
243.0940552	0.17
248.0910034	0.17
252.1308594	0.43
267.2467346	0.44
272.2782288	0.11
281.2504883	100.00
281.8604431	0.55
288.7579956	0.21
293.3500671	0.78
323.3318481	0.26
329.2097168	0.18
347.9358215	0.24
350.3887939	0.43
365.9385986	0.27
373.0601501	0.31
376.4683228	0.17
381.4703064	0.17
391.0517883	1.92
392.1354675	0.11
393.0514832	0.70
394.0895996	0.35
399.4336243	0.17
406.1841125	0.71
421.5496826	0.34
432.0140991	0.14
433.4339294	0.65
434.3878174	0.57
435.4651794	0.48
440.2529297	1.21
441.9302063	0.39
447.5419006	0.23
450.339386	0.17
459.13974	0.20
460.1351013	2.54
461.0613708	1.26
462.4306946	0.65
479.1342468	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.77
Annotation	Unknow
Peak:m/z	Relative Intensity
181.8593903	0.22
206.9344482	0.06
265.9801636	0.49
290.7626038	0.93
294.6884460	0.03
296.4652100	0.06
347.3869019	0.08
349.3109741	1.25
349.9180298	6.71
374.1314087	0.04
374.8482666	0.33
387.8908081	0.02
433.7442627	18.71
435.1448364	0.03
439.3337402	0.06
441.1619263	0.02
442.7508545	0.08
448.2345581	0.05
448.9523315	0.12
449.9885864	0.05
452.0117798	0.05
457.2103271	0.03
458.1923218	0.10
458.8154297	1.27
460.0634155	0.03
470.8110352	0.05
472.1490479	0.02
475.4794312	0.02
477.9260254	0.02
481.8336182	0.08
487.4204102	0.06
488.0783081	0.06
495.7532959	0.04
509.3790894	0.05
514.7353516	0.06
515.7824097	0.13
517.5993042	100.00
518.3415527	0.14
532.7628784	0.10
541.6347046	0.05
542.8173218	0.02
543.7625732	0.02
554.6549683	1.53
555.7503662	0.99
557.3168335	0.04
558.5332031	0.02
577.8087769	0.05
589.5510864	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	331.1032
Annotation	Koaburaside
Peak:m/z	Relative Intensity
97.06785583	1.43
100.8887863	9.33
113.0287933	6.89
119.0869751	1.41
137.06604	4.01
138.9506378	3.09
142.8661346	3.72
146.2061462	0.83
150.8510284	3.72
151.9969482	1.05
153.9296875	26.74
155.0695801	7.28
161.111084	22.47
167.034256	24.43
167.7758026	2.02
169.0597687	100.00
179.0916901	14.52
181.2447815	2.37
191.1448059	1.27
193.0479736	1.34
195.9726562	1.56
197.0555115	0.54
202.923111	1.07
205.9757385	1.70
209.2877197	1.66
211.2252808	3.42
216.780304	2.46
221.3118286	1.49
224.9966736	14.55
235.0758972	8.64
239.1063232	2.65
244.331543	0.70
246.8843994	2.02
252.9453735	2.84
269.1156311	1.97
270.9705811	0.90
284.8486938	10.85
287.2087097	5.74
293.4906006	0.69
295.0033569	1.20
299.1361084	8.33
301.3008118	3.86
310.6732178	2.02
313.0831299	11.75
313.9692688	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	541.14
Annotation	Resveratrol 4'-(6-galloylglucoside)
Peak:m/z	Relative Intensity
160.9675293	0.26
179.0429535	1.72
179.9282227	0.22
181.0308838	0.10
198.8002625	0.04
208.3527222	0.04
218.2835541	0.03
221.1710052	0.49
222.2308960	0.07
226.9081726	0.09
245.8488007	0.04
250.5917969	0.38
251.8126068	0.13
252.8713989	0.06
259.0704041	0.10
268.7362671	0.03
280.9309082	0.27
282.3098755	0.09
293.4743652	0.03
310.5623169	0.03
311.2250977	0.12
313.0902100	0.14
319.7608032	0.05
323.2095947	0.66
324.1785278	0.40
325.1670532	0.13
340.9605103	2.67
341.9492188	0.79
342.9396362	0.41
359.3034668	0.15
360.4520874	0.26
361.3673706	0.12
377.1702271	1.87
378.1599121	5.83
379.1484375	13.56
380.2344971	0.10
383.4259644	0.08
407.0781860	0.03
424.7270508	0.09
426.3598022	0.04
443.4429932	0.05
444.2319946	0.05
484.8597412	0.08
485.9067993	0.02
503.2412720	100.00
504.2213745	56.47
505.2887573	16.62
549.1831665	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.99
Annotation	Unknow
Peak:m/z	Relative Intensity
82.7073517	0.25
123.8041916	0.53
173.1965485	0.46
205.2442322	0.41
210.8275452	0.87
217.0250244	0.38
235.3348083	0.30
236.9341431	1.51
239.8680420	100.00
248.9728088	0.67
256.3630676	0.41
257.5424194	4.93
263.2277527	0.68
265.2886353	0.58
278.4023132	0.80
280.5183411	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8752
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9637146	0.11
170.9446564	0.05
174.9717102	1.11
198.9684448	0.09
214.4884033	0.14
229.0950623	0.02
244.9028473	0.41
273.0389099	1.36
273.9736328	0.12
288.9620972	15.14
304.9659424	4.86
378.9998169	0.19
386.9443970	2.34
387.9993286	0.30
389.0775146	0.48
402.9464111	10.21
403.9179077	0.09
416.8715820	0.19
418.9650269	100.00
442.8129272	0.05
445.1198730	0.07
447.9727173	0.04
457.9517212	0.03
458.9493408	0.28
460.9554443	0.03
475.1464844	0.09
484.7141724	0.02
485.8179321	4.35
486.8368530	11.05
487.8128662	0.33
488.8225708	0.81
505.2122192	0.12
506.1300049	0.11
507.2633667	0.05
515.1597900	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1537
Annotation	Vicenin 1
Peak:m/z	Relative Intensity
364.6421509	0.33
367.2354126	0.10
379.4472656	0.44
385.2880859	0.42
403.5728149	0.38
409.1689453	0.94
415.2155151	0.19
427.1724854	6.34
439.2479858	0.24
445.1070557	6.82
445.7113647	0.47
451.7056274	0.56
457.1513062	4.01
469.2127686	4.73
481.1339111	6.63
493.3622437	1.57
499.2406616	17.90
510.7025146	0.65
511.3413696	8.75
529.2583618	21.11
547.2260132	100.00
552.9641724	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	346.1122
Annotation	Unknow
Peak:m/z	Relative Intensity
104.7018204	0.21
109.0523529	0.06
116.2542191	0.26
119.0442505	0.15
137.0103302	25.31
151.0297852	0.34
153.9614258	100.00
166.0002441	0.24
168.0185547	0.20
173.8836365	0.12
175.2165070	0.11
184.1695557	0.51
190.1090088	0.21
196.9455109	0.57
198.1412659	0.07
214.1020813	9.62
217.2620239	0.30
233.2198486	0.20
270.1226196	0.13
271.2269287	0.26
282.2782898	0.27
286.1147461	0.68
288.6063232	0.24
301.0335083	0.16
302.4376221	0.07
303.1893921	0.12
304.1729126	0.21
309.1740417	0.23
310.2315063	0.12
326.2142334	0.07
327.1522522	0.65
328.1109314	3.96
337.0444641	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	415.27
Annotation	Feigrisolide D
Peak:m/z	Relative Intensity
140.8425903	1.53
142.952179	0.24
147.1041565	0.16
152.8850861	0.68
160.7455292	0.68
163.1426392	0.16
171.2648315	0.32
180.9711304	0.43
185.2510681	0.47
189.0157318	0.82
192.9387054	0.23
201.0215759	1.08
205.1625671	0.85
209.1326904	0.47
217.2432556	0.52
229.1181641	0.42
231.0350647	0.50
235.2843933	0.63
236.3223877	0.41
243.0927429	0.56
244.1185303	0.66
247.2377014	0.39
256.8654175	0.21
265.2055359	0.63
271.7878418	0.33
275.4261475	0.18
286.5126953	0.34
287.4578552	0.70
295.3691711	0.47
301.2990723	0.56
302.22052	1.08
309.1123962	0.28
310.0731812	0.31
313.1539917	0.39
321.2519531	0.19
323.6185913	0.47
325.3940735	1.55
327.0162964	0.97
341.2453918	0.42
343.3475342	0.60
352.4076843	0.17
353.5117798	0.54
357.0237427	0.24
365.3733826	0.60
366.7081604	0.19
367.3680725	0.30
369.3268738	4.02
377.122406	0.45
379.4616699	0.45
380.1542053	0.18
387.4593506	0.23
397.2613525	100.00
398.2975159	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	Swertinin
Peak:m/z	Relative Intensity
120.0727463	0.15
122.8816757	0.43
124.9532623	0.24
134.9769592	0.19
152.8746796	1.15
155.002533	0.67
166.8940887	0.23
171.1500244	0.80
172.950531	0.14
185.0747681	0.43
186.9721985	0.12
189.04776	0.38
195.0656738	0.43
201.4529419	0.49
205.161499	0.38
213.1970215	2.27
223.1402893	0.19
226.9718323	0.32
230.995575	2.38
243.0453796	3.49
244.3252563	0.41
247.9724731	0.11
253.0218506	0.66
260.9534607	0.50
261.5975342	0.13
271.0656433	100.00
276.1577148	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.29
Annotation	Prostaglandin E2 serinol amide
Peak:m/z	Relative Intensity
131.1195374	2.15
155.0161133	7.17
173.0484314	1.76
193.8605347	3.50
212.0220642	3.89
215.3027649	3.29
229.2278442	4.08
233.4303894	1.96
237.1647644	7.96
248.6679077	2.37
249.298584	4.22
263.2132568	5.76
281.3018188	9.41
282.9594727	1.76
284.1124268	15.76
285.1893921	4.47
286.1950684	5.79
295.9559021	2.73
296.7769165	4.25
304.3385315	3.86
323.3443909	2.36
332.2404785	5.90
333.093811	4.06
334.9060059	2.73
339.2794189	19.44
343.2991028	3.69
351.9350586	2.17
356.8863525	13.25
371.2869568	11.35
372.9143677	14.71
377.3672485	9.66
381.0588074	2.17
382.0845642	8.66
385.1948547	3.09
391.0020142	21.47
395.1621399	26.17
398.4243469	9.06
403.7224121	5.06
407.5957947	10.16
408.2744446	100.00
409.2414246	16.57
411.139679	3.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	243.1967
Annotation	2-Hydroxymyristic Acid
Peak:m/z	Relative Intensity
86.9457016	3.76
97.08883667	3.81
141.0375214	2.77
157.1330109	3.15
162.953476	1.51
164.2171631	1.71
165.1999664	2.55
168.8450165	4.65
171.2594757	2.21
175.1669159	2.35
182.9738617	10.72
184.9737396	2.97
185.6961823	4.23
189.2614288	2.97
197.190979	100.00
198.7807617	6.64
199.4007416	4.73
201.0138397	2.97
202.9131775	15.79
206.8860321	20.44
210.9576874	27.09
215.2817841	4.23
225.0517426	81.04
225.9037476	20.76
226.9608612	3.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	227.9822
Annotation	Unknow
Peak:m/z	Relative Intensity
80.9471893	0.85
97.0376129	0.65
111.1927490	1.59
186.9564667	100.00
187.8076935	2.88
204.9484558	0.95
210.1808014	1.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.25
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
107.027153	0.39
109.0990143	0.80
120.908432	0.17
122.9065094	1.09
132.9057312	1.18
134.9818726	0.80
137.1939545	0.55
143.146347	1.01
146.8961792	1.22
149.072464	0.39
150.9345703	0.90
155.1312561	0.24
157.0054016	1.25
160.9866333	1.38
163.2885437	0.62
165.0580444	0.86
168.8719177	0.30
172.0746307	0.41
173.1085815	0.69
175.1842346	0.28
179.4441071	0.65
183.0243835	0.91
185.3852539	0.30
187.0858765	1.79
189.0826111	0.73
195.3088531	0.78
199.1391144	0.58
200.9355927	0.57
202.9931488	2.36
205.2953644	1.17
209.2802734	0.37
211.2180481	1.95
212.2384644	0.24
213.3162842	0.70
214.2720337	0.88
215.9775696	0.23
217.2395325	1.06
219.2433472	0.79
221.1703796	0.32
223.2557983	0.34
227.1929626	1.31
229.1502991	0.25
231.002594	1.82
240.4013977	0.18
241.4181213	0.48
245.229187	1.21
247.2435303	5.15
248.9938354	0.38
251.0150452	1.07
253.2228394	1.08
257.2536316	0.24
261.0716553	0.45
269.1547241	0.67
271.2460938	0.23
273.2167358	0.36
277.2877197	0.29
279.1171265	0.89
281.3283691	1.32
282.0574341	0.27
283.1872864	1.32
284.5427856	0.24
285.4846802	0.21
287.4639282	0.72
291.0714722	0.13
295.0916748	0.57
297.2643127	0.59
298.9923706	1.69
299.932373	0.59
304.9825745	1.68
309.0939026	0.26
310.2470703	0.32
313.3043823	0.67
323.2438965	100.00
324.1871948	1.38
325.2824707	0.29
327.4055176	0.71
331.5684814	0.51
341.3993835	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	261.15
Annotation	Cordiaquinol J
Peak:m/z	Relative Intensity
83.68951416	0.08
93.13555908	0.16
120.793335	0.12
167.1960297	0.23
171.1572418	0.50
175.2438812	0.77
181.013031	0.23
183.1374969	0.25
193.1191406	0.38
199.010025	0.41
200.795105	0.12
205.3420563	0.34
214.9778748	0.21
217.0990601	1.59
218.3345795	0.18
220.1719971	0.14
224.3930969	0.31
225.076355	0.62
231.2696381	0.38
232.2329865	0.08
233.1443481	0.73
240.2653198	0.25
243.1467743	100.00
244.3638458	0.16
245.1465302	1.39
246.260376	0.60
261.841095	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1192
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
137.0718079	0.11
149.0268402	0.30
150.0794067	0.08
151.0990753	0.36
152.9425812	0.06
162.8921509	0.26
164.2752533	0.11
165.1523132	0.19
174.9391327	0.08
176.9851837	0.09
178.8980408	0.36
180.0631714	0.14
191.1848450	0.20
193.2430420	0.04
209.1779022	0.95
210.1287842	0.40
214.3274841	0.17
216.0435181	0.08
229.3418884	0.27
230.9141998	0.07
233.2823181	0.26
255.3333435	0.19
268.2648926	0.19
269.1646423	0.07
270.2315063	0.10
272.9900208	1.53
275.6352844	0.06
284.1299133	0.51
285.0769348	0.25
289.1007080	46.87
290.1034241	15.40
297.1011963	0.07
297.9171753	0.16
299.1217041	100.00
300.1325684	31.50
303.6345520	0.06
312.1267700	0.17
313.2935791	0.77
314.0896301	0.33
315.2217712	0.07
317.0929565	23.04
318.0897827	8.87
323.1771545	0.98
326.3471069	0.05
327.0701294	0.19
328.5005493	0.10
331.2302246	0.28
334.8801270	0.07
337.2301025	0.08
339.1284180	0.04
341.1880493	3.15
342.2068176	2.15
343.2721252	0.74
344.0559692	0.04
352.8976135	0.03
359.3177795	0.51
365.3155518	0.07
371.2775269	0.38
372.2630615	0.04
376.0742798	0.06
386.2372742	0.04
391.2709656	0.10
392.2464294	0.29
393.2124634	1.01
395.9518127	0.14
396.8059998	0.06
403.4183044	0.13
405.0644226	0.21
406.6200867	0.06
408.4346008	0.07
417.3424683	0.34
419.4891052	0.10
425.9546509	0.11
433.4297180	0.14
434.3933411	0.13
435.3166809	0.13
436.1925964	0.24
441.5757751	0.04
443.8088684	0.06
444.5131226	0.08
451.1585999	5.81
452.2293701	3.01
459.2134399	0.04
461.1646423	10.67
462.1629028	2.59
463.4482117	0.08
464.9105530	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2499
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
106.7865906	0.49
109.0928574	0.47
114.8570099	0.08
116.7824554	0.04
121.0027924	1.16
123.0262146	0.61
125.0051498	0.09
127.0684662	0.08
128.9355621	0.05
130.8711548	0.20
132.9324188	0.65
135.046814	1.57
137.0995789	0.09
138.6417694	0.04
141.1726532	0.05
142.87117	0.33
145.0287476	0.09
147.039856	2.12
148.9668579	1.02
151.1403503	0.52
153.0458984	0.05
156.9890747	0.64
158.976532	0.18
161.080719	2.22
163.0284424	0.64
165.1688538	0.38
168.9041595	0.19
171.0292664	0.16
172.4590302	0.25
173.1205292	0.19
174.9846497	1.13
177.1095734	0.05
179.2147827	0.30
180.9980621	0.14
182.9818115	0.33
185.1006775	0.22
186.9965515	0.46
189.0294189	1.04
191.1852417	0.19
193.0591125	0.13
197.1294556	0.18
199.0708618	0.23
201.1026611	0.05
203.2124786	0.90
205.0865173	0.86
209.3935852	0.06
210.9284668	0.27
211.9432068	0.09
213.0259399	0.31
215.2742004	0.19
217.0614624	1.38
219.2009277	0.04
223.1238403	0.43
224.8416748	0.17
227.2151184	0.09
229.2479553	0.22
231.2686768	0.81
239.8052673	0.07
240.5127258	0.10
241.255249	0.11
242.9491272	0.05
245.2155762	1.67
247.3009338	4.71
253.1043701	0.10
255.458252	0.11
257.1465759	0.18
265.2626953	0.17
267.1143494	0.08
271.2059937	0.70
281.5337524	0.24
282.9690247	0.24
285.3837585	0.40
287.2061768	0.23
294.9389648	0.41
297.1453247	0.23
299.338623	1.45
303.4326172	0.11
305.1430359	1.87
305.7805481	0.14
313.105072	0.31
323.2447205	100.00
324.0173645	0.39
325.289032	0.05
326.1907959	0.05
340.8086243	0.63
341.4509277	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.124
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
85.0758209	1.60
85.9867554	0.44
87.0674744	0.19
88.9702606	2.98
89.9629517	0.39
94.8751602	0.24
96.9803238	0.15
99.2480316	0.08
100.0450974	0.07
100.8960876	4.78
101.8322525	0.28
106.3885422	0.04
109.1513519	0.07
112.9323730	6.97
114.0407715	0.84
115.0822601	0.52
116.0817413	0.24
116.9551544	0.06
119.0034637	3.89
120.0263214	0.39
125.1089401	0.56
126.9578857	0.53
128.2042542	0.40
129.1062927	0.06
130.9762421	100.00
131.9911804	11.73
133.6176910	0.07
141.9217529	0.04
143.0570526	2.69
143.8667908	0.23
144.9614105	0.08
145.9231567	0.04
148.8905029	0.24
155.1095581	0.03
156.8053436	0.10
160.9255981	0.91
162.0060425	0.31
165.8877106	0.04
167.0199127	0.05
169.2357025	0.12
170.3480225	0.10
172.9414062	5.60
174.0268250	0.82
178.9798431	2.19
179.9996948	0.50
183.1881714	0.05
185.1149445	0.95
186.2000122	0.08
193.0550995	0.18
198.3059387	0.04
203.2444763	0.50
204.1811523	0.30
206.0462952	0.15
215.1412354	0.14
222.2818909	0.11
227.2077332	0.12
232.1989441	0.13
233.1855774	0.28
235.1278381	0.10
246.8161316	0.09
247.9772949	0.04
249.2072754	0.41
250.2935181	0.05
257.8331909	0.05
260.0909424	0.10
275.2338257	0.37
276.1713257	0.29
276.8579407	0.03
279.6890564	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	362.9968
Annotation	Unknow
Peak:m/z	Relative Intensity
110.9803162	3.88
114.8316193	0.26
128.8471375	0.05
130.9831238	0.18
133.0013580	1.72
138.5844269	0.03
141.9806366	0.09
153.1141052	0.04
155.0698853	0.12
160.0710144	0.57
172.9914856	1.51
189.0344543	0.67
189.8102112	0.09
191.0485535	100.00
192.0043488	0.11
207.2850647	0.11
211.0953979	0.22
212.0462036	0.02
218.0907898	0.04
219.2081299	0.19
226.8517761	0.04
229.0296326	0.06
231.0797729	0.14
232.2112427	0.11
232.8265076	0.04
233.6732788	0.12
242.5128479	0.03
244.9605408	0.04
245.7757568	0.08
257.2976379	0.03
258.8768311	3.03
261.8876953	0.08
263.0593872	0.07
270.9317017	0.11
274.9453430	0.16
300.7328491	0.11
302.8556519	0.03
316.8973083	0.07
318.1501465	0.08
319.0304871	0.20
320.8876648	0.05
327.1511841	0.12
344.9995422	2.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.2499
Annotation	(3beta,5alpha,11beta,17beta)-9-Fluoro-17-methylandrostane-3,11,17-triol
Peak:m/z	Relative Intensity
105.0136414	0.34
107.1753845	0.95
117.0077515	0.47
121.0430832	1.84
129.0582886	0.37
131.0823975	0.53
134.9946594	1.19
137.1448975	0.34
143.1307068	0.57
144.8102417	0.41
149.1149139	1.04
157.1241455	1.69
158.8127441	2.60
169.3211365	0.48
173.000061	1.07
175.0209961	0.49
182.9980774	0.80
187.0873718	2.02
192.7946167	0.56
201.1742401	0.82
205.0144348	3.67
211.079834	0.83
215.2284546	0.67
219.2654724	0.76
222.9488831	0.32
225.2922974	0.49
229.2731934	0.73
245.0562744	2.76
247.2677917	1.88
267.3251038	0.29
269.2951965	0.64
271.2628174	0.85
277.1124878	0.38
285.6116028	0.65
287.3452454	1.70
295.1789551	2.18
297.1763	0.37
299.2478333	2.45
303.5187378	0.71
305.0572205	9.08
310.2959595	0.95
313.2072144	1.10
314.4061584	0.50
323.2433472	100.00
323.8769836	0.77
340.7275391	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	495.1025
Annotation	(3-Hydroxy-4-methylanthranilyl)adenylate
Peak:m/z	Relative Intensity
152.8901367	100.00
314.6807861	0.51
459.4115295	0.96
477.2522583	0.51
END