#DEFINITION	Reference Metabolome for Citrus sudachi
#IDENTTFIER	RefMeta-Citrus sudachi.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Citrus sudachi
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Citrus sudachi was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	327.2179
Annotation	9,12,13,TriHODE
Peak:m/z	Relative Intensity
94.8957138	0.24
97.0752869	0.44
98.9864883	0.15
108.9395599	0.04
111.0883865	0.12
119.0346985	0.07
122.9317856	0.46
123.6674271	0.06
125.0803986	0.86
127.1867065	0.80
128.8685303	0.08
135.0079041	0.09
137.1579285	0.28
138.9361115	0.30
141.2482758	0.06
143.3070068	0.37
149.3562469	0.21
150.8617859	0.33
153.0024567	0.45
155.0693054	3.50
163.0081787	0.61
165.1073303	5.36
167.2208099	1.12
169.0283203	0.14
171.1458282	25.95
173.1011047	0.14
174.9658966	0.05
177.1684418	2.82
178.0115967	0.04
179.1535797	0.22
181.1791382	0.54
182.1302490	0.26
183.1839294	3.45
184.0530243	0.21
185.0567780	4.42
186.6417236	0.05
188.1492157	0.10
189.1118774	0.12
191.2035522	0.07
193.0596771	5.87
195.0569763	0.78
197.1589355	3.53
199.2721252	0.52
200.0805969	0.08
201.2096558	1.84
203.0929260	2.26
205.3272400	0.08
207.3104248	0.26
209.1423645	14.01
211.0666504	48.71
211.6696472	0.13
213.2012329	0.70
219.0249329	0.11
221.1463013	19.31
223.1507874	0.56
225.1853027	0.09
227.1780090	3.60
229.1224670	100.00
235.3193665	0.28
237.0808716	0.23
239.1821289	15.43
241.0587463	0.25
244.3313293	0.14
244.9399719	0.07
247.1970825	11.43
251.3327026	0.22
253.4169922	0.12
255.0262451	0.15
255.6293030	0.09
257.1325989	0.68
258.2037048	2.43
259.0361633	0.03
263.1906128	0.06
264.1241150	0.05
265.2031250	0.37
267.2408142	0.09
271.3302002	0.19
272.2351074	0.13
273.2479248	8.91
275.2913208	0.13
281.3236084	1.16
283.1699219	0.18
285.1860657	0.07
289.1948242	0.75
291.2512817	71.51
291.9610901	0.57
294.9910889	0.16
297.3145752	0.18
299.4071045	1.07
300.4877930	0.10
307.3260498	2.92
309.2785339	18.90
310.1866455	0.07
312.1806641	0.40
327.2200623	0.15
328.4042969	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	883.4578
Annotation	Unknow
Peak:m/z	Relative Intensity
262.4187317	0.09
282.2716980	0.60
289.3137512	0.33
293.4133606	0.06
306.2909546	0.09
320.2742310	0.45
324.2315674	0.54
333.3122864	0.35
335.4781494	0.40
345.3354187	0.17
348.0463867	0.07
353.4595337	0.08
369.2893066	0.48
372.2512817	0.21
378.2178345	0.12
387.3947144	0.07
410.1647339	0.31
425.0811157	0.24
441.3793945	0.07
443.5330200	0.33
454.4494629	0.29
461.2757568	0.44
480.4807129	0.38
488.3828735	0.15
498.5482788	0.19
504.4600830	0.19
512.6533203	0.25
518.7175293	0.14
531.6404419	0.30
538.6765137	0.27
548.7387085	0.17
550.4249878	0.47
557.6645508	0.28
564.2191162	0.29
568.8807373	0.33
574.7716064	0.34
582.7575073	0.24
598.5648193	0.93
600.4047241	2.14
602.8153687	0.34
614.7330933	1.28
624.7869263	0.45
626.6672363	0.28
632.5311890	8.25
634.0379028	0.09
639.3685913	0.27
640.5033569	0.36
642.4833374	0.25
652.5206299	0.10
656.5925903	0.52
658.1449585	0.44
666.4768677	0.15
675.3175049	0.17
685.3395386	0.16
686.5728760	0.74
698.8757935	0.22
703.5269165	5.35
704.5263062	0.30
707.5932007	0.34
712.5177612	0.54
721.5107422	33.91
726.5570679	0.31
727.6322632	0.17
733.6664429	0.25
746.2115479	0.21
757.7160034	0.26
763.5464478	2.47
767.4013062	0.30
776.4685059	0.26
792.6713257	0.42
794.9146118	0.38
799.6775513	0.10
801.3665161	0.17
829.8754272	0.13
838.6820068	0.21
847.0522461	0.20
847.7324219	1.17
864.3278809	0.27
865.3536987	0.30
866.2012329	0.35
883.5176392	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	450.2627
Annotation	PE(16:1(9Z)/0:0)
Peak:m/z	Relative Intensity
140.0816345	0.06
152.9917297	0.21
167.1165466	0.01
193.0141907	0.02
196.0982819	2.97
197.0709229	0.05
209.4299774	0.02
213.9737549	1.43
215.0015259	0.13
223.0123901	0.01
246.0949707	0.05
253.2236938	100.00
254.2403870	16.78
259.4122620	0.02
271.3891907	0.02
283.3367615	2.55
294.4436035	0.03
295.1408081	0.05
303.4119873	0.01
306.8521729	0.06
312.7321777	0.02
314.0222168	0.02
317.2187805	0.03
345.5985718	0.06
351.1473999	0.01
359.4896851	0.03
363.7261963	0.09
365.1240234	0.02
375.1533203	0.03
377.3169861	0.04
379.4264832	0.05
389.2119446	0.16
390.2298889	0.03
391.2516174	0.03
393.4814148	0.10
404.4325867	0.03
405.2229919	0.17
407.5127563	0.13
410.5797424	0.04
412.3670959	0.02
413.4033203	0.14
414.3939819	0.29
415.3618469	0.13
423.2564087	0.06
432.3031006	0.04
433.2985535	0.17
434.2297974	0.06
435.2965393	0.08
436.2116089	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0986
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
110.9385834	0.87
112.0283508	0.06
128.9735107	5.79
130.0730896	0.44
132.0509796	0.05
134.0196838	4.95
135.0536499	0.91
140.9853210	0.60
141.7970581	0.25
149.0206299	2.17
150.1120605	0.25
155.2120056	0.05
158.9573975	4.39
160.0538940	0.38
160.8068085	0.64
163.9363861	0.17
167.3581543	0.27
175.0534363	4.69
176.9435425	63.23
178.0611267	3.88
179.1900024	0.24
186.2755585	0.08
191.0718689	0.82
193.0149841	66.73
194.1372681	9.58
195.0144348	100.00
196.0526276	7.88
202.2385254	0.15
203.2963257	0.27
206.8884735	0.05
209.0065002	0.06
215.2296448	0.22
216.9558105	0.76
218.1261292	0.60
218.8394775	0.52
229.2643433	0.05
230.9194031	0.08
233.0837097	1.26
234.2224426	0.55
235.2360229	0.96
236.0881958	0.21
241.4587402	0.07
245.2395020	0.17
247.2073975	0.39
247.9409485	0.17
251.0862732	0.12
261.0648193	0.86
262.1887817	0.05
263.1083374	0.51
265.0989380	1.39
266.1053162	0.20
274.3483582	0.19
275.0888367	1.70
275.9710693	0.05
277.1655273	0.57
278.1599731	0.21
280.9719849	0.07
285.3524475	0.18
286.3027039	0.12
293.2932739	0.23
295.0752258	5.40
296.1349487	0.84
303.0646362	0.04
307.1206360	0.09
309.1957092	0.10
325.5420532	0.16
328.1450806	0.05
335.1501160	1.78
336.1170044	0.50
339.1754150	7.48
340.1934509	0.48
353.1351624	34.69
354.1648560	5.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	811.2261
Annotation	Isorhamnetin 3-[2''-(4'''-acetylrhamnosyl)-gentiobioside]
Peak:m/z	Relative Intensity
226.0412903	0.05
229.0600128	0.08
235.1979675	0.03
237.4080200	0.02
244.1264954	0.34
252.9933472	0.23
254.0923920	0.13
254.9558411	0.26
269.0673523	0.07
271.0639954	0.64
272.1007385	0.33
274.7354126	0.10
283.1293640	0.04
285.9492798	0.02
296.9439392	0.07
298.2195740	0.05
300.1793518	0.17
301.1203308	0.06
303.0884094	0.55
311.3394775	0.04
313.2359924	0.43
316.1950684	0.24
316.8207397	0.10
318.7855530	0.10
319.4983215	0.03
328.1329956	2.31
329.1104126	0.85
331.0808716	8.80
332.0633545	1.41
346.1723328	3.39
347.1770020	0.51
349.4456177	0.06
350.2838440	0.03
361.1851196	100.00
362.2496338	16.24
363.3406982	0.07
364.2521362	0.06
373.0649414	0.16
376.2689819	0.05
379.1852417	0.19
387.2451172	0.64
388.3125610	0.24
397.2094116	0.31
403.2402954	0.05
404.7734985	0.22
414.3174438	0.09
415.2463989	0.42
419.4282227	0.02
423.6162109	0.13
432.7467651	0.04
433.4371948	0.05
436.3064575	0.08
440.0488892	0.03
445.3735352	0.20
451.2851562	2.94
452.2326660	0.83
464.2756348	0.05
465.3218384	0.12
469.0868530	5.18
470.2625732	0.74
487.0892334	0.19
488.6204834	0.04
493.7992554	0.11
502.4878540	0.08
505.3601074	0.12
507.1159058	0.12
510.1790771	0.02
516.0866089	0.14
516.9495239	0.09
522.8812256	0.65
523.6098022	0.11
528.1550293	0.03
529.2213135	0.02
530.3758545	0.03
541.2766724	0.05
551.4283447	0.23
559.3249512	0.04
560.1102295	0.03
563.3200073	0.18
569.5100708	0.05
570.2837524	0.08
571.2677002	0.02
581.2650757	0.37
582.3726196	0.05
587.5234375	0.13
588.1590576	0.13
589.2316284	0.06
595.3476562	0.19
596.6201172	0.04
603.1090698	0.04
605.1633911	6.91
606.1390381	2.72
606.9521484	0.43
607.7511597	0.35
613.1619263	0.85
614.4168091	0.31
630.1706543	0.07
631.1552124	1.53
632.3364868	0.28
649.1596069	14.37
650.3400269	3.20
659.1621704	0.09
664.8164062	0.09
666.0716553	0.20
666.6973267	0.14
667.2993774	5.58
668.2015381	1.25
686.2559814	0.08
691.6303101	0.05
709.2465820	2.01
710.3360596	0.22
721.2322388	0.18
722.1896973	0.17
739.3019409	1.51
740.4260864	0.51
749.5819092	0.03
757.1815186	3.48
758.0711060	0.95
766.2611694	0.14
775.1904907	51.42
776.3072510	13.06
779.2900391	0.06
781.3516235	0.09
784.1525269	0.08
793.2462158	24.34
794.3322144	5.06
812.2835693	17.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.1438
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
159.1887207	0.02
180.9255066	0.01
225.1323853	0.01
237.1575775	0.05
239.2999268	0.02
256.3607788	0.03
257.3480225	0.03
261.1734314	0.05
269.4453125	0.02
271.2529907	0.01
273.1530762	0.01
274.4215088	0.15
275.4153442	0.01
278.8873901	0.01
281.1544189	0.05
283.1585083	0.02
283.9472046	0.02
295.3879395	0.08
299.1137695	0.09
301.1226807	0.11
311.5769043	0.04
313.3629150	0.02
315.2507324	0.00
316.0853882	0.04
321.2581787	0.02
328.2022095	0.01
332.4138184	0.01
334.0512085	0.01
335.1013794	0.01
338.6215210	0.01
340.3425293	0.01
341.9996948	0.01
343.0401001	0.01
346.0410767	0.15
352.9865723	0.05
357.3945923	0.01
359.0709229	0.01
361.1619263	100.00
361.7634888	0.47
365.1017456	0.02
366.3581543	0.03
371.1018066	0.07
375.2284546	0.08
381.3041382	0.05
385.2551880	0.06
387.1860352	0.06
389.2648315	0.04
390.6825562	0.06
395.2780762	0.01
397.0404663	0.03
399.2177124	0.01
403.4078369	0.01
405.3259277	0.10
406.9417114	0.01
412.9255371	0.07
415.4139404	0.06
417.1097412	0.07
418.5903931	0.01
419.6904297	0.04
424.2565308	0.04
425.5830078	0.02
429.5798340	0.02
432.1426392	0.01
433.1898804	0.09
441.7462158	0.07
442.4850464	0.01
445.0482178	0.04
447.7918701	0.08
450.8255005	0.02
459.3431396	0.21
461.4414673	0.06
462.4741211	0.03
463.2823486	0.07
465.3059692	0.03
466.9888916	0.02
472.0967407	0.02
475.2093506	0.01
477.1216431	0.42
477.9327393	0.02
486.1380005	0.01
487.2703857	0.11
491.2795410	0.04
495.1152954	0.06
504.2844849	0.15
505.2218628	0.54
522.4790649	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.2613
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0545502	2.45
160.0339050	0.11
161.1962585	0.25
179.0709686	0.36
184.9458313	0.13
186.0780182	0.24
193.1717529	0.67
194.9991150	0.66
203.0550385	100.00
204.3638458	0.07
205.1079102	0.37
206.3572083	0.26
222.7060242	0.12
229.0737152	0.12
239.4752502	0.10
267.4360962	0.11
268.1865234	0.14
271.0104370	0.10
286.8886719	0.39
288.3855591	0.10
296.2769775	0.34
296.8883362	0.25
300.0168762	0.25
301.0987549	1.38
303.3251343	0.09
306.2685852	0.09
310.1057129	0.22
339.0550537	0.12
339.9291992	0.06
344.3452148	0.06
345.2273560	0.12
346.2043457	0.36
347.2547607	11.93
353.1663208	0.18
356.3779907	0.78
359.4325562	0.08
367.5640259	0.28
368.1799927	0.07
369.0604248	0.17
370.3722534	0.05
373.2984619	0.12
374.7957764	0.30
379.4171143	0.20
384.7846680	0.04
386.1433716	0.21
388.2208862	0.17
389.1911621	1.11
397.2970581	0.46
400.2409058	0.76
401.4019165	0.15
403.1802368	0.24
407.1000366	0.06
409.5160522	0.20
413.3514404	0.05
415.3349609	0.11
417.2382812	0.18
419.3368530	0.06
429.0719604	0.20
430.5368652	0.33
431.2296143	5.94
434.5160522	0.10
444.7969971	0.06
446.7311401	0.27
448.8674316	0.15
460.9236450	0.73
462.1649170	0.13
463.0223999	1.30
467.4111938	0.19
471.2130737	0.33
485.3398438	0.08
488.1701660	0.09
489.3601685	0.15
491.4454956	0.35
504.6400757	0.47
505.6525879	1.04
507.3217773	0.70
509.0332642	0.11
513.2699585	0.08
515.1752930	0.19
517.6839600	0.09
520.4854736	0.12
521.6409912	0.09
523.1369019	0.24
532.7837524	0.07
535.6004028	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0722
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
92.8589783	0.58
100.9398651	0.59
107.8883743	5.09
108.9799194	10.77
112.8732147	0.14
118.9492035	0.48
120.9682770	3.18
121.8398590	0.12
122.9737701	1.15
125.1504059	0.29
130.5586700	0.29
133.0043945	0.64
133.9889221	0.26
135.0387268	0.54
135.9134827	0.82
137.0687714	0.65
149.0468140	0.08
151.0115967	5.75
151.9079742	40.68
152.9380341	100.00
159.9158783	0.19
161.1981049	0.07
163.0003052	10.22
164.9587555	11.48
175.2964935	0.19
176.9183502	1.02
179.0945282	2.18
180.9731140	2.85
183.1189575	0.34
188.9120789	0.79
193.1595154	0.87
194.9506531	4.67
207.0667419	3.43
217.1005554	0.69
219.0791626	1.78
225.0903015	8.27
237.0263367	1.31
241.1059265	0.11
271.1952515	0.66
279.1508179	1.02
295.2260132	0.15
297.2689514	0.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
103.5106354	0.14
108.0431976	0.04
126.8730164	0.03
138.7953796	0.02
155.1220398	0.01
160.9189148	0.02
175.1141205	0.04
181.3033905	0.01
183.1175079	0.04
185.2066193	0.04
187.3240356	0.02
190.902832	0.08
192.9259338	0.93
193.5302429	0.01
194.9561615	0.08
197.1278687	0.01
198.0333405	0.04
201.1758881	0.05
202.1243286	0.07
204.2124939	0.07
205.1523438	0.02
208.092865	0.03
211.2179871	0.05
213.3862915	0.09
214.3049927	0.02
217.0747986	0.02
219.2286072	0.02
225.1657715	0.04
226.1366882	0.02
226.7945251	0.06
239.2976074	0.10
241.0512695	0.12
242.265625	0.03
243.4344482	0.05
249.5125732	0.05
251.3829956	0.12
253.2998962	0.21
255.2138367	0.02
256.2524109	0.04
256.9719543	0.03
267.1376953	1.17
268.3537292	0.05
269.4598389	0.47
270.1813965	2.18
271.0080566	0.04
277.3026123	0.01
280.1997681	0.02
281.0665283	0.15
282.1081848	0.20
283.1652527	2.54
285.1836548	5.89
293.2351685	0.11
294.4778748	0.22
295.1337585	2.13
298.0520935	100.00
299.2220459	0.18
311.3508301	0.04
313.1459351	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1951
Annotation	Butrin
Peak:m/z	Relative Intensity
179.0126495	0.44
186.1284943	0.09
187.1679688	0.40
195.0125885	8.96
202.9342804	0.23
219.1896057	1.29
245.1379700	3.83
258.1148071	0.52
261.0599670	0.46
263.0017090	1.38
281.1649170	3.23
285.1983643	0.22
286.0833740	1.16
287.1546021	2.21
288.0447388	0.46
297.1245117	0.63
301.1401978	28.82
302.2269592	29.02
303.1416626	78.98
304.1224060	2.47
315.1864319	4.63
316.1517944	0.27
321.2453613	0.48
322.9424438	0.68
327.2549438	6.89
328.1688232	0.12
339.2378540	2.01
345.1438599	27.97
346.2377930	0.87
347.2305908	0.51
353.2700195	0.26
355.2411499	0.26
356.1936646	0.09
356.8775024	0.08
363.3428345	0.57
365.3900757	0.11
369.2411499	18.54
370.4138184	0.76
371.5377197	0.44
375.1550293	0.30
381.2247314	1.70
387.2187500	0.94
389.2061768	0.38
393.0916138	1.64
395.4833984	0.70
399.1235962	3.56
407.3031616	0.77
411.2362061	7.54
413.1657104	18.17
413.9725952	0.61
423.2993774	0.19
425.0405273	4.15
429.1806030	16.61
431.0103149	26.08
431.8143921	0.85
433.4682617	0.39
435.2830200	0.56
436.9081421	1.73
440.9740601	0.49
443.0964355	1.62
447.1693726	100.00
448.4896851	5.27
449.1782837	58.04
450.5225830	0.63
453.1748657	2.52
454.0648804	0.23
455.1939087	2.54
459.1549683	3.33
463.1615601	6.40
464.5111084	24.54
465.1134644	71.12
466.0798950	1.45
466.7811279	0.25
471.1940918	1.19
473.0137329	7.71
473.9817505	0.26
477.2811890	0.39
478.4343262	0.34
479.4422607	1.00
484.6945801	0.39
489.1707153	26.88
491.0516357	9.93
491.9187012	0.16
497.2406616	2.18
503.3994141	0.20
506.6892090	0.57
513.2486572	3.60
521.1261597	0.78
524.3326416	0.83
526.9644165	3.50
527.8558960	0.20
539.1712036	8.36
540.4542236	0.71
557.1259766	27.74
558.5144653	0.46
574.6368408	1.74
575.2595825	33.29
576.4932251	1.42
580.7280884	0.33
585.2760010	0.28
593.0650635	21.86
594.3168335	1.40
598.4577637	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1797
Annotation	Spinosin
Peak:m/z	Relative Intensity
169.1493988	0.01
185.1078186	0.07
186.0850830	0.05
194.8876190	0.04
202.2253418	0.05
209.0281372	0.04
242.9642639	0.04
253.3036346	0.03
270.2233887	0.01
273.3455200	0.08
274.1977539	0.03
286.2625122	0.21
287.2516479	0.02
291.1652832	0.12
297.1373901	0.04
301.2047119	2.38
313.1834106	1.13
314.8472900	0.05
325.2233887	1.08
327.2982178	0.02
328.3878784	0.03
329.2685547	0.03
337.2741699	0.04
339.0599976	0.02
341.1201172	0.07
343.1749268	8.22
363.5310669	0.07
365.2130127	0.13
367.1791992	3.18
369.9313354	0.02
373.3268433	0.06
375.5415039	0.01
385.2156982	0.11
391.1903687	0.16
395.3678589	0.07
397.1485596	4.74
400.3909912	0.01
401.4988403	0.02
409.2656250	2.07
415.2480469	0.11
423.2465820	0.09
425.4018555	0.05
427.1929321	4.82
428.6452026	0.02
429.5336304	0.06
431.2969971	0.06
433.3188477	0.05
435.1320190	0.05
438.9624634	0.02
440.4865112	0.06
445.2538452	24.96
447.3103027	0.18
448.3587036	0.02
451.3655396	0.02
453.2112427	0.38
457.3205566	0.02
458.1430664	0.08
461.2035522	0.22
463.1591797	100.00
463.7831421	0.80
465.1354980	0.08
469.2963867	0.02
471.2039185	0.15
475.7681274	0.23
476.4293823	0.07
477.3143311	0.13
487.0232544	0.18
489.1294556	0.67
491.3163452	0.12
493.2891846	0.20
494.6829834	0.03
502.3533325	0.03
505.5628052	0.03
511.3047485	0.05
519.3546753	0.04
523.2223511	0.01
525.4354858	0.03
529.1943970	0.03
530.2375488	0.05
531.3858032	0.09
532.1865845	0.05
533.3305664	0.04
543.2622681	0.06
545.1852417	0.21
550.4059448	0.05
551.5531006	0.11
555.2437134	0.36
565.5482178	0.06
572.4902954	0.02
573.3068237	0.40
583.4954224	0.03
589.6730347	0.06
590.5618286	0.78
591.3450317	1.45
594.5172729	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	643.311
Annotation	Trichoverritone
Peak:m/z	Relative Intensity
192.9596252	0.02
197.9400177	0.04
201.8337402	0.02
207.0021820	0.03
229.2036438	0.02
236.2461853	0.02
247.1178894	0.04
253.3136902	0.06
264.3316956	0.03
273.3945923	0.05
275.2833862	0.02
276.7528076	0.08
278.2301636	0.09
281.1869507	0.02
287.2888489	0.05
289.4454346	0.03
291.2337036	0.15
295.1684570	0.07
297.6807861	0.01
303.2446289	0.01
305.2255249	0.06
307.3397827	0.04
315.5189209	0.11
319.4185791	0.03
321.1420288	0.03
331.1817932	0.07
334.2113647	0.02
336.4176025	0.05
338.2536621	0.07
344.2521973	0.04
345.3349609	0.06
346.5420532	0.10
347.6498413	0.09
348.7550659	0.02
359.2623291	0.05
360.5114136	0.08
361.3394775	0.01
389.5493164	0.01
390.4749756	0.08
417.3114014	0.01
420.5454712	0.04
427.6444092	0.03
432.5521240	0.08
444.1040649	0.02
452.7584839	0.01
457.5000610	0.04
474.4620972	0.03
475.4410400	0.03
476.2677002	0.09
477.3777466	0.02
478.6210938	0.06
485.3812256	0.03
489.6284790	0.08
490.5507812	0.08
491.3952026	0.07
495.7184448	0.03
501.9656982	0.17
502.6737061	0.06
503.5727539	0.04
508.4384155	0.05
509.6365356	0.05
511.6681519	0.13
512.4130859	0.15
513.4321899	0.02
525.3081055	0.42
526.4774780	0.12
527.7401733	0.03
535.5629272	0.09
537.4724731	0.08
539.2069092	0.09
540.4483643	0.14
541.2611694	0.04
542.4557495	0.08
543.4230347	0.04
544.7501831	0.03
548.6538086	0.03
550.5839844	0.09
552.3413086	0.08
554.6513062	0.04
555.4653931	0.02
557.6975098	0.12
566.1218872	0.04
567.4077759	4.99
568.4564819	2.45
569.3491821	0.46
570.5496216	0.22
571.5432739	0.17
572.9536743	0.08
576.3966675	0.02
579.3906860	0.22
583.3784790	5.95
584.5366211	3.11
585.5614624	0.26
597.1721191	0.05
599.4575806	100.00
600.4312134	41.87
601.0884399	0.10
611.2521973	14.25
612.4246216	3.97
615.5391846	0.10
625.6132202	0.81
626.6327515	0.46
645.6048584	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.2358
Annotation	Unknow
Peak:m/z	Relative Intensity
205.2140503	0.07
215.0132141	0.01
219.0792999	0.09
221.1645660	0.05
245.1226807	0.22
247.0650177	0.15
262.9970703	0.09
265.1409302	0.38
270.9133606	0.03
275.0230713	0.02
277.0839233	0.11
283.2057495	0.18
289.1527100	0.13
301.3623047	0.02
305.1052551	0.65
317.0182800	0.02
321.1997681	0.17
322.0216064	0.01
329.1048279	0.06
337.1383057	0.34
339.0120850	0.08
349.4675598	0.06
359.9216309	0.01
361.5020142	0.02
373.0866089	0.01
375.3869629	0.02
381.3167725	0.14
382.2106934	0.04
383.2130737	0.02
390.0206299	0.03
397.1911621	0.34
408.9578857	0.03
415.3506470	0.10
421.3275757	0.07
437.6196289	0.12
440.1929321	0.03
449.1545410	0.35
451.4098511	0.08
453.3063354	0.12
454.1983643	0.20
455.3358765	0.04
469.4000854	0.02
472.4512329	0.05
473.3406372	0.07
475.1680908	0.02
481.4077759	0.07
482.2886353	0.05
485.4584351	0.01
491.2564697	0.06
495.2901001	0.03
496.2725220	0.02
505.6071777	0.01
508.4650269	0.03
509.1373901	0.11
510.3554688	0.03
511.1820679	0.14
515.5759888	0.05
524.5340576	0.04
525.2921753	0.21
526.3096924	0.50
529.2095337	0.30
543.0291748	0.02
544.3630981	0.70
545.1918335	0.03
554.5422974	0.02
555.4517212	0.01
561.4701538	0.11
571.2913208	0.01
573.5138550	0.01
586.4378052	0.04
587.1996460	0.01
603.2722168	0.35
604.2619629	1.87
605.2435303	0.40
626.1892090	0.17
627.6454468	0.06
644.5354614	0.01
645.2510986	0.04
646.4232788	0.16
647.1976929	0.01
657.1096802	0.14
658.3018188	2.53
659.4313354	0.25
661.4588013	0.68
675.3329468	0.81
676.3049316	4.59
677.4840698	0.73
693.5761108	0.01
705.3236694	1.25
719.4706421	0.15
737.4166260	100.00
738.5249634	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	929.4739
Annotation	Angiotensin III
Peak:m/z	Relative Intensity
593.2787476	4.47
793.0686035	11.07
903.7733154	6.22
928.5224609	28.57
929.5287476	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.0828
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
110.9334030	1.36
112.9598846	0.20
116.9385071	0.22
119.1027145	0.05
124.9729309	4.86
129.0093384	3.88
134.2634583	0.06
134.9921875	0.09
142.9649353	1.61
147.9268188	0.20
150.1520386	0.06
156.1769714	0.11
160.9090118	0.92
161.5142517	0.03
162.9290771	0.28
169.0075989	0.44
173.9071960	0.06
175.1506042	0.06
176.9297333	0.19
179.0072937	0.18
186.9833679	1.00
191.0935669	0.13
192.9591675	2.16
194.0458832	2.63
195.1304016	0.56
205.0348816	100.00
209.1425934	0.04
223.0067749	79.08
245.0286865	0.04
255.2371521	0.13
279.2013550	0.04
308.1268005	0.05
322.3570557	0.05
323.3397522	0.05
324.2473450	0.06
351.0572205	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0566
Annotation	Dantrolene
Peak:m/z	Relative Intensity
100.8983612	0.06
102.9725494	0.18
111.0624161	0.18
112.8964233	0.03
115.0413971	0.06
121.0590668	0.34
128.9556274	8.47
146.9769592	11.59
161.0352936	0.30
163.0188599	0.19
172.9830780	7.70
189.1074829	0.29
191.0382996	100.00
203.3306580	0.17
221.2211304	0.06
233.1644592	0.09
251.1278687	1.03
254.1371460	0.07
258.8726196	0.09
268.6725464	0.35
269.3306580	0.35
277.0742798	0.73
283.1260986	0.10
294.9946289	16.31
298.1514587	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1
Annotation	5,6,4'-Trihydroxy-7,3'-dimethoxyIsoflavone
Peak:m/z	Relative Intensity
120.8178482	0.21
194.9767609	0.19
198.0242004	0.05
213.0422668	0.15
214.0514526	0.06
271.0899658	0.02
274.0922241	0.01
285.2884521	0.27
288.2678223	0.04
290.2360840	0.03
298.0853271	17.30
299.1989441	1.36
301.0595398	21.50
302.0603027	0.89
313.1122742	1.57
314.2577820	0.04
316.1002502	100.00
317.2037354	7.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.2302
Annotation	Unknow
Peak:m/z	Relative Intensity
221.2717896	0.02
227.1262665	0.09
231.0202789	0.01
243.3048096	0.03
245.2306824	0.33
246.8894501	0.04
253.0609741	0.06
263.0398560	0.06
263.8817139	0.07
269.0567627	0.02
271.0533447	0.09
277.1887512	0.12
281.2042847	0.04
287.0191040	0.03
289.1746216	0.27
299.2039185	0.05
300.4173279	0.02
301.2572021	0.02
305.2944336	0.12
306.2343140	0.01
307.1988525	0.12
311.3861084	0.03
317.1532898	0.06
321.1932373	3.13
322.2390442	0.14
330.9653931	0.04
335.2263184	0.02
339.1937256	3.04
340.1500244	0.15
340.9751282	0.04
342.2952881	0.05
347.2088623	0.05
357.2171021	0.01
359.3713989	0.02
363.1064453	0.02
364.2555237	0.01
367.0367432	0.03
371.4619141	0.03
373.1652222	0.03
375.2858887	0.03
381.2287598	2.55
382.3453979	0.11
385.2577515	0.06
387.4819336	0.05
392.3768921	0.03
401.2117310	0.14
405.2768555	0.03
421.3236694	0.04
423.4431763	0.03
425.3140869	0.02
431.1627197	0.17
432.9069214	0.01
435.0782471	0.14
437.4092407	0.01
447.0728149	0.04
449.1610107	0.53
450.4110718	0.02
451.3956909	0.02
453.1813965	3.10
454.3381958	0.12
461.3629150	0.02
462.2946777	0.04
463.0112915	0.10
465.3477783	0.06
469.3645630	0.03
471.1235962	0.31
473.3333130	0.05
481.3614502	0.20
487.1528931	0.07
488.4622803	0.01
491.2672119	0.42
492.0670776	0.06
493.3287354	0.08
495.2597656	0.73
496.5111694	0.07
503.1616211	0.02
505.3738403	0.07
507.2304077	2.03
508.4504395	0.26
509.3153076	0.25
513.2846680	2.18
514.4215088	0.34
523.3138428	0.06
525.2826538	2.15
526.3586426	0.40
533.5534058	0.08
535.3195190	0.36
536.1881104	0.04
538.1791382	0.08
541.5104370	0.07
543.3280029	0.56
544.4304199	0.10
547.4671021	0.12
549.2905884	0.10
550.1729736	0.01
551.2859497	0.35
552.0370483	0.02
555.2705078	2.02
556.2865601	0.18
567.3220215	14.27
568.2261353	2.26
571.3331909	0.05
577.0007324	0.01
583.1852417	0.04
585.2810059	18.46
586.3518677	3.14
591.4580078	0.04
595.3323975	0.40
596.2645264	0.18
597.5718384	0.05
601.4956665	0.07
603.4244995	1.60
604.3979492	0.21
607.0247192	0.03
608.0770874	0.04
609.1716309	0.12
610.3074341	0.04
613.3436890	0.27
614.5038452	0.06
627.2850342	4.82
628.3692017	0.72
639.3499146	3.36
640.4678345	0.58
645.2904663	35.70
646.3847046	5.27
647.0892334	0.02
657.3466187	2.66
658.3585815	0.64
667.3470459	0.87
668.2991333	0.17
669.4227905	0.01
675.3987427	1.22
676.4967041	0.07
681.7431641	0.14
685.0584106	0.21
687.3367310	2.87
688.4452515	0.56
699.3247070	70.62
700.2892456	12.76
700.9215698	0.04
703.3842773	0.03
717.3319092	89.29
718.3792114	17.00
729.3234253	0.18
730.4249268	0.07
735.3732300	1.75
736.5659180	0.34
741.4547119	0.11
742.5195923	0.10
745.5477905	0.16
746.6220703	0.02
748.4194336	0.08
759.3411255	0.05
760.2761230	0.03
778.3594971	100.00
779.3870850	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0673
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
111.1562500	0.03
118.9088898	0.26
128.9942017	2.00
133.9858246	0.29
146.9617157	5.59
159.9278259	0.03
161.2584229	0.09
162.9297180	0.69
172.9656067	1.00
175.0851746	0.35
190.9357300	100.00
193.0862579	1.95
209.0126953	76.66
234.9533081	0.07
308.2070923	0.16
308.9695740	0.21
337.0585327	7.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.0726
Annotation	Decarbamoylgonyautoxin III
Peak:m/z	Relative Intensity
110.9319153	0.32
119.0052414	12.42
136.9186554	0.01
142.9505920	1.31
155.1459351	0.13
163.0577087	100.00
168.9053192	30.23
169.7346497	0.02
173.0013885	0.04
186.9402771	1.71
191.2244415	0.03
204.9956360	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	685.2883
Annotation	Mombasol
Peak:m/z	Relative Intensity
195.9852600	0.08
226.4725037	0.39
227.2303467	0.12
239.1953735	0.14
242.2562561	0.03
248.1074677	0.06
251.2206573	0.13
253.1486969	0.41
254.1984558	0.21
255.2423401	0.11
258.2189941	0.10
266.0274048	0.04
267.3847656	0.05
268.0785828	0.05
269.1989136	0.05
270.2921753	0.05
281.1523743	0.04
284.2285156	0.07
294.1484985	0.07
296.0989380	0.05
297.0578003	1.12
298.9403687	0.06
300.2160034	0.03
309.1687622	0.50
310.1698914	0.03
311.3233643	0.32
313.1756592	0.20
323.5979919	0.12
324.4271240	0.17
325.4131470	0.29
326.7331543	0.12
327.6116943	0.13
328.3369751	0.46
329.0908508	0.42
330.1422119	0.04
339.3652344	0.17
340.2937012	0.36
341.2690430	0.90
342.0882568	0.23
343.0618286	0.45
344.1283264	0.12
355.1534424	0.46
356.2779541	0.09
363.2984009	0.09
364.1024170	0.04
370.4182129	0.08
371.1413574	0.04
372.1931152	0.24
375.1214600	0.06
378.4267578	0.29
379.3944702	0.11
383.2299194	0.09
386.3331299	0.18
387.3496094	0.32
391.5313110	0.04
395.0433960	0.09
396.4301758	0.28
397.4314575	0.09
402.3728638	0.23
404.2373657	0.14
409.6497803	0.17
414.2075806	0.48
416.1298828	0.21
418.4031982	0.05
419.5614624	0.22
422.5911865	0.18
425.4212646	0.18
426.3535156	0.29
429.5305176	0.04
431.2321777	0.23
433.3858032	0.04
435.2803345	0.09
438.4943848	0.07
440.5551758	0.18
442.4193726	0.04
445.7840576	0.41
446.5376587	0.68
452.2893066	0.06
454.3143311	0.13
455.3959351	0.07
456.2777100	0.67
458.3461304	0.33
461.4868774	0.24
462.5245361	0.49
463.7761841	0.28
464.5811157	0.49
470.5831909	0.11
471.2761841	0.11
474.4824219	0.15
475.4014893	0.31
476.4922485	0.08
477.8552246	0.28
478.5592041	0.09
479.3645020	0.32
480.5693970	0.26
481.5216064	0.13
482.6086426	0.06
484.5443115	0.03
485.2423706	0.21
488.1768799	0.49
490.3880005	6.81
491.4277954	1.62
492.2971191	3.52
493.3261719	0.60
494.4145508	0.76
495.4026489	1.10
496.5413208	0.03
497.4208984	0.03
498.7578735	0.27
499.6892090	0.10
500.3701782	0.07
501.3129272	0.08
502.5324097	0.77
503.4647217	0.25
504.3395996	0.22
505.6168213	0.44
506.5581665	0.63
507.4170532	0.40
508.3666992	0.08
511.0884399	0.19
512.4108887	1.43
513.1978760	0.23
514.4903564	0.25
515.8393555	0.20
516.5864868	0.33
517.4146118	1.56
518.2902832	0.63
519.4412231	0.11
520.6290894	1.08
521.5449829	0.81
523.3765259	0.97
524.4688110	1.27
525.4476318	0.22
526.4030762	0.11
527.2161255	0.53
531.3869019	0.26
532.4890747	0.35
533.4212036	0.63
534.3582764	1.86
535.4411621	1.09
537.5239258	0.38
538.3788452	0.72
539.4966431	0.57
540.4597168	0.14
544.4500122	1.07
545.3961182	1.87
546.4559937	0.86
549.3161621	2.60
550.2496948	1.24
551.3940430	0.78
552.7531128	0.10
553.3787231	0.07
554.7113647	0.06
558.3444214	0.10
559.4848022	0.55
561.5197754	2.32
562.4673462	0.89
563.6093140	0.17
565.3743896	1.18
566.2608643	4.92
567.2679443	3.80
568.3292847	0.54
570.3143921	10.64
571.4626465	0.98
574.3080444	0.10
575.3056030	0.18
577.3733521	11.15
578.3878784	8.41
579.4363403	3.03
581.4016724	22.28
582.3854980	6.48
583.4334106	0.68
584.8259888	0.07
589.1897583	1.00
590.4902954	0.88
591.1687622	0.14
592.2244263	0.09
593.4325562	3.96
594.5284424	1.25
595.4548950	0.09
597.4036255	3.09
598.4748535	1.62
599.6049194	1.37
600.4369507	0.27
602.2546997	0.75
603.2331543	0.89
604.6622925	0.09
609.3673706	8.57
610.6174927	3.28
611.4949341	1.00
612.5669556	0.18
613.4310913	0.09
614.6361084	0.03
621.2794189	19.91
622.4027710	4.03
625.3612671	3.36
626.4598999	1.03
627.3582153	0.20
631.4393921	0.08
635.3315430	1.08
636.3679199	0.84
637.5870972	0.10
638.4520874	0.10
639.1683960	0.05
641.5805054	0.18
642.3836060	0.06
643.7448730	0.14
644.8087158	0.17
649.3311157	0.05
653.3765259	100.00
654.4309692	20.35
657.2493896	0.14
658.5230713	0.15
667.5720825	1.07
670.4708862	0.17
686.3759766	73.98
687.3161011	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.7995
Annotation	Unknow
Peak:m/z	Relative Intensity
161.6997070	0.06
162.7563171	0.07
173.0565796	0.21
176.7468262	0.18
180.9187317	0.06
184.2825012	0.41
187.2734070	0.36
205.3370361	0.04
212.2622986	0.07
219.3870087	0.22
231.3246002	0.14
232.9896240	0.35
243.2190094	0.28
243.9989471	0.06
254.1566315	0.16
254.8679810	0.06
256.5291138	0.39
257.1643066	6.13
259.3337402	0.09
261.2661743	0.79
263.4044189	0.03
275.2880249	0.18
284.2816772	0.25
293.0704346	0.30
295.3571167	0.03
303.7131348	0.45
311.3936768	0.21
312.8264771	1.10
316.1303711	0.23
317.4777832	0.14
321.7497559	9.75
323.4122314	2.49
324.5364380	0.23
332.0457153	0.06
335.3786621	0.62
336.5460205	0.25
342.3435669	0.09
343.2960815	0.07
350.7194824	0.32
353.1308594	0.04
356.9930420	0.32
364.2787476	0.18
367.4426880	0.15
375.4189453	1.63
376.4014893	0.86
377.2446289	0.26
378.4619751	0.25
379.3777466	0.05
383.5458984	0.06
385.3627319	0.48
387.6066895	0.13
392.1331787	0.26
394.6879272	0.11
395.3417969	0.10
396.2966309	15.74
404.0322876	0.11
411.7519531	0.21
414.3551636	0.21
417.4771729	0.14
420.0666504	0.10
423.4586182	1.61
424.1761475	0.27
426.8265381	0.23
429.4896851	0.16
432.8085327	0.09
438.9236450	0.15
439.8627930	0.56
441.4152222	0.25
442.2575073	0.65
443.0385132	0.42
443.9075928	0.11
448.3349609	0.12
450.2630005	0.51
451.8311768	3.66
452.9259644	0.10
457.3713989	0.66
460.8589478	100.00
461.6308594	4.94
463.5316772	0.21
464.2554932	0.15
466.8224487	0.08
468.6195068	0.19
470.4611816	0.05
475.6276245	0.09
477.2635498	1.30
490.4596558	0.13
491.4844360	0.63
495.8402710	0.16
497.2145996	0.18
504.4212036	0.17
505.2429199	0.15
506.3480835	0.21
508.2382202	0.08
509.4722290	0.53
510.0742798	0.15
513.3599243	0.32
514.4025269	0.21
515.0242310	0.10
523.3917847	6.96
524.3313599	0.97
526.0928345	0.22
526.9783325	0.08
531.4097290	4.48
534.4253540	0.14
586.3628540	1.19
596.7108765	0.23
612.4669800	0.19
613.6448975	0.04
615.7610474	0.13
622.7941284	0.06
624.6079712	0.43
641.3951416	0.14
642.3040771	0.71
645.5814209	0.07
647.1444092	0.16
655.5332642	0.39
660.3211060	5.53
669.5445557	0.42
683.4982300	0.41
695.7021484	0.21
697.7176514	0.44
708.6392822	0.14
711.9069214	0.19
726.6073608	0.13
731.4280396	0.16
770.7428589	0.13
775.0222168	0.24
778.1248779	0.06
791.5097046	6.96
792.4173584	0.03
798.5756226	0.14
807.6680908	0.18
812.6441040	0.19
826.3666382	0.51
864.4612427	0.10
902.7459106	0.39
903.8027954	0.24
920.5966187	47.08
921.6773071	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.1304
Annotation	Isoscutellarein 8,4'-dimethyl ether 7-glucuronide
Peak:m/z	Relative Intensity
152.0635223	0.04
163.3066711	0.04
166.1493835	0.04
167.0448151	0.04
173.1342010	0.07
188.9295959	0.05
191.0694885	0.05
198.1956024	0.08
205.9406738	0.03
251.0501862	0.03
261.1159058	0.03
269.2219238	0.03
273.0743103	0.03
283.2884216	0.01
295.1845093	0.12
296.2083130	0.02
297.0531616	0.03
300.2218628	0.08
310.4526367	0.02
311.0892334	0.30
312.3096313	0.18
313.3514404	0.03
315.1860352	0.16
315.8537598	0.01
325.1921997	0.17
327.0568237	0.01
328.1237793	0.27
329.1642456	0.44
331.2655640	0.06
336.2003784	0.02
337.4682617	0.01
339.1425781	0.19
340.2539062	0.11
343.1063232	20.66
344.1328125	4.59
345.1938477	0.49
353.2744751	0.05
354.2174072	0.08
357.4085083	2.53
358.1357422	6.99
359.2273560	5.20
369.5150757	0.02
371.4519653	0.28
373.0513306	0.10
375.3099365	0.28
383.0363770	0.07
386.2880249	0.03
397.0870361	0.07
400.1856079	0.03
401.2427979	0.68
401.9252319	0.01
415.1876831	0.07
416.3327026	0.14
417.4702759	0.03
431.2882690	0.04
462.4201660	0.01
463.2119751	0.01
474.3685303	0.02
475.1832886	0.49
477.3412476	0.02
478.5203247	0.02
489.6115112	0.25
490.3471680	0.30
491.1432495	1.89
491.7610474	0.02
506.1431885	100.00
506.7803345	0.52
507.4111938	0.25
522.2970581	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
94.9860916	0.10
96.8812866	0.12
98.9714050	0.22
100.9527283	0.39
110.9481049	0.20
112.9605560	1.44
113.9057465	0.19
114.8146515	1.55
117.0687103	0.09
119.0410614	0.07
125.0114288	0.16
126.9789734	0.60
128.9908905	0.66
134.8810425	0.04
137.0111084	0.03
138.9517517	0.45
140.8265991	0.04
143.1265411	0.06
152.8790894	0.11
156.9485779	1.85
160.7509460	0.03
167.0149078	0.09
168.9472504	1.48
170.1177368	0.04
173.1872101	0.09
173.9934845	0.89
175.0459595	0.92
181.2653809	0.02
186.8395386	0.02
191.1921539	0.08
199.1382904	0.04
207.1937561	0.11
215.1186218	0.04
217.0072327	0.32
219.0907593	0.15
221.3523560	0.04
231.2690125	0.06
233.1223755	0.05
242.9341736	0.02
247.0133057	0.67
254.0453491	0.09
259.0979919	0.02
261.1552734	0.04
275.0402222	0.07
277.0947571	100.00
277.9869385	0.07
291.0547180	0.28
301.2823181	0.07
302.1909180	0.24
303.3186951	0.06
318.3021851	0.08
319.0726318	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.19
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
186.9933319	0.01
199.1260071	0.01
200.7980804	0.01
204.8147430	0.02
212.2180328	0.04
213.2839355	0.03
215.8235016	0.01
226.8951416	0.01
234.8781738	0.01
245.3645630	0.01
271.1961060	0.06
272.2994995	0.04
300.0991211	0.01
315.0369873	0.05
316.0028687	0.04
328.1802368	1.68
331.0491943	4.52
331.6694946	0.01
343.0583496	0.11
346.1047363	4.06
346.7087402	0.01
356.2977295	0.02
361.1711426	100.00
362.0012207	0.07
396.3487549	0.03
403.2109375	0.05
418.3930664	0.03
469.2353516	0.03
492.3760986	0.06
504.8192139	0.10
505.6378784	0.07
523.2123413	0.05
525.4099731	0.01
571.4014893	0.01
585.7114258	0.01
589.2101440	0.04
591.4343872	0.09
605.3068237	0.14
615.8512573	0.02
616.4808960	0.02
623.4461060	0.01
631.1588745	0.18
649.1807251	0.46
649.9325562	0.02
667.4716187	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8151093	100.00
153.1209412	0.23
155.0397949	0.07
212.7689209	39.11
229.0987549	0.11
252.5773315	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	275.0562
Annotation	O-Demethylfonsecin
Peak:m/z	Relative Intensity
85.0417633	0.09
94.8676453	0.04
111.9337387	0.86
114.9168243	0.11
127.9480133	2.20
141.0549927	0.12
145.0972900	17.59
146.0567627	0.36
146.9961243	0.55
155.8926544	20.21
158.9860840	5.96
159.9940643	0.75
160.9449158	6.37
168.2792053	0.12
171.1032562	0.14
173.8498840	10.80
175.2716675	0.42
176.1424561	0.11
182.9819489	5.77
188.1152496	0.10
199.0825195	0.11
200.0001221	0.43
201.0924683	0.92
206.9701538	0.41
209.9385376	1.17
211.4429321	1.68
212.0503235	5.30
212.9595642	0.20
214.1447144	0.10
215.0917358	0.28
216.1433411	0.34
218.1366272	0.37
219.2015991	0.33
220.0696106	0.07
225.0758362	9.11
227.0031738	16.32
229.0112305	100.00
230.0820923	3.11
230.9625549	4.53
232.1643066	0.60
233.2796631	0.13
243.0768433	3.18
244.9757385	0.42
247.0380249	26.58
256.2763672	1.47
256.9801025	1.42
257.8054199	0.06
260.1672974	0.20
275.3259888	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1143.3104
Annotation	YGM 3
Peak:m/z	Relative Intensity
329.1732788	0.00
331.1600952	0.04
332.0626221	0.01
346.3531494	0.01
347.1458130	0.02
359.3540955	0.00
361.2196045	0.20
362.3498535	0.09
388.4256592	0.02
423.5295410	0.00
435.4940491	0.00
441.0344849	0.01
452.5040283	0.01
453.3649292	0.00
467.5799561	0.01
470.3791199	0.01
564.2390137	0.01
596.4935303	0.00
605.4922485	0.01
606.3503418	0.02
608.4262085	0.00
631.1403809	0.01
631.8604736	0.02
649.4346924	0.03
650.3287354	0.01
666.2691040	0.01
667.3214111	0.00
668.4237671	0.01
709.3175049	0.01
728.5461426	0.00
729.7279053	0.00
740.4144287	0.00
746.1829834	0.01
748.4892578	0.00
757.5151367	0.00
758.2957764	0.00
764.9488525	0.00
765.5913696	0.01
766.1971436	0.00
769.4853516	0.00
770.4868164	0.00
775.4682617	0.03
776.4099121	0.07
777.5115356	0.00
778.4832764	0.01
782.8007202	0.00
794.1568604	0.03
811.4054565	0.03
812.3309326	0.08
1090.3051760	0.01
1108.0007320	0.00
1108.6326900	0.00
1125.9243160	0.01
1126.8389890	0.01
1142.0794680	0.00
1144.1635740	100.00
1144.8955080	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	973.3
Annotation	Alpha-cyclodextrin
Peak:m/z	Relative Intensity
562.2263184	1.91
922.9398804	9.83
972.5845337	13.69
973.328125	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1927
Annotation	Creoside IV
Peak:m/z	Relative Intensity
131.0422668	0.06
143.0389862	0.20
161.0221558	0.66
178.9789124	0.86
179.8016052	0.03
181.0495453	0.06
187.0707245	0.14
215.4288330	0.03
221.1277466	0.03
233.1190491	0.01
244.9583740	0.03
249.2442627	0.06
250.9844360	0.07
257.9458313	0.05
278.2079468	0.04
280.3713379	0.04
315.2746887	0.02
318.1813965	0.03
331.3835754	0.09
333.5054016	0.05
334.7557678	0.11
347.1044006	0.15
349.1965332	100.00
350.2286377	0.04
351.4898071	0.06
353.2310486	0.20
380.2699280	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0825
Annotation	(-)-Usnic acid
Peak:m/z	Relative Intensity
111.9619904	0.04
113.150589	0.03
135.1694031	0.08
138.1311646	0.03
149.1721497	0.04
154.9104767	0.03
171.1565094	0.08
179.0959167	0.03
181.0339966	0.03
197.1422272	0.04
200.8826752	0.07
208.2095947	0.04
213.1844788	0.07
214.0565186	0.03
222.0087891	0.08
225.254364	0.03
227.2136536	0.03
249.3381348	0.17
251.5144653	0.08
256.1350403	0.07
269.2414551	0.09
278.0927429	0.03
282.0449829	0.06
283.2722473	0.14
284.2315979	0.06
287.0108643	0.02
297.1725464	0.43
298.208252	0.06
299.3040161	0.21
300.196167	0.15
301.1810303	0.07
304.97052	0.03
306.8504639	0.20
307.4821777	0.03
309.2810059	0.09
310.026001	0.06
311.2649536	0.15
312.3428345	0.52
313.2030945	3.34
315.1442261	0.70
324.3300171	1.43
325.2695312	3.99
326.0610046	0.26
328.0703125	100.00
329.3178101	0.58
343.4318542	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.2763
Annotation	Myricanol 5-beta-sophoroside
Peak:m/z	Relative Intensity
209.1376190	0.07
318.1845703	0.03
321.0891724	0.03
327.3193970	0.01
330.5064697	0.05
349.5516357	0.07
360.1834106	0.05
373.2200317	0.03
375.1639404	0.07
381.7079468	0.11
387.4013672	0.10
395.2637329	0.09
397.2773438	0.07
413.4889526	0.02
423.5354004	0.07
431.6145630	0.02
443.5381470	0.50
455.5006714	0.18
457.6337280	0.04
461.3905029	1.29
462.5049438	0.15
471.7971802	0.09
473.4329834	0.10
477.2301025	0.03
483.9821167	0.07
486.4755249	0.11
501.2399902	0.05
502.2217407	0.08
516.3416748	0.03
519.6115723	0.19
520.5731812	0.27
537.0055542	0.03
556.7308960	0.15
563.4317627	0.02
568.2732544	0.09
573.3362427	0.16
575.3463135	1.45
576.2024536	0.10
579.5509033	0.04
587.7363892	0.09
593.3604126	5.56
594.2589722	0.18
599.5929565	0.09
605.6739502	0.25
606.3046875	0.08
617.4089355	61.78
618.5637817	2.60
619.6560059	0.06
623.5242310	0.88
624.4085083	0.62
635.2200928	100.00
636.1715088	2.81
636.8419800	0.15
637.5401611	0.16
638.7418213	0.05
645.5477905	0.08
663.3973389	0.53
664.4835815	0.16
682.1239624	1.28
682.7524414	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1127.2908
Annotation	Unknow
Peak:m/z	Relative Intensity
353.2880249	0.02
359.4167480	0.03
449.3981323	0.05
463.3765259	0.03
479.1471252	0.03
503.5051880	0.03
507.3313904	0.06
521.3023682	0.10
533.3701172	0.01
561.2749023	0.01
563.0843506	0.04
579.2470703	0.09
585.2126465	0.05
605.2072144	0.02
620.9962158	0.04
623.3880615	0.02
649.4188232	0.09
665.7294922	0.03
683.3615723	0.01
707.0887451	0.03
767.2446289	0.38
797.4653320	0.03
1001.2879640	0.11
1084.2951660	0.08
1086.3149410	0.02
1127.2309570	100.00
1128.2504880	27.94
1129.0026860	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.175
Annotation	N-Benzoyl-D-arginine-4-nitroanilide
Peak:m/z	Relative Intensity
120.9580307	0.04
122.9470444	0.67
126.9992065	0.41
132.9702148	0.22
133.9620972	0.08
134.8822632	0.34
137.9003906	0.16
142.7726135	0.07
144.9094849	0.13
147.0528107	0.24
148.8328400	0.03
150.9667816	0.93
151.9333191	0.94
153.0161438	0.36
158.9398193	0.12
163.1100464	0.27
166.0494385	9.13
169.1280518	0.29
170.5136414	0.02
173.1165161	0.18
174.2027283	0.04
175.0748901	0.24
177.0484467	0.16
180.0427856	0.03
182.0214844	12.66
183.6108551	0.05
185.1415558	0.07
187.0352783	0.12
189.1139221	0.45
194.0004272	10.56
197.0059204	0.09
198.0608368	1.48
199.9211273	2.10
200.7958069	0.15
202.2402954	0.07
203.2218018	0.11
204.9740906	0.04
207.0552063	0.04
212.0143738	47.13
216.9787292	0.01
219.1430664	0.26
220.0257874	0.10
223.3267822	0.13
231.0870667	1.02
233.8454285	0.02
237.1484985	0.28
241.0803833	0.15
245.1195679	0.03
246.9672241	0.06
248.9406433	0.30
251.1152039	0.07
258.8006897	0.46
265.2082214	0.06
267.4409180	0.18
268.7740479	0.02
271.0076294	0.09
277.3103027	0.30
289.2208252	0.05
292.9992371	0.10
295.0091553	0.51
301.3442993	0.29
308.2694092	0.12
309.1325073	0.29
313.1979980	0.55
317.1652832	2.52
319.2064514	0.24
320.2477112	0.09
324.4291687	0.04
327.9598694	0.09
329.4757080	0.10
331.1423645	0.18
333.3175354	0.11
335.1137390	5.92
336.2744141	0.12
337.2166748	0.24
340.7131348	0.08
344.1948853	0.03
345.1708374	0.60
346.2998047	0.08
349.1433105	3.31
351.0974731	0.06
352.0195923	0.18
353.2857666	0.18
355.2325439	0.12
356.7330627	0.21
363.1476746	21.28
363.7620239	0.09
367.0256653	0.08
371.2810974	0.10
373.3140564	0.02
381.1191711	100.00
381.7625427	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1628
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
203.0635376	0.08
213.5343628	0.03
243.2104187	0.10
244.1300659	0.02
271.1005249	0.30
280.0205078	0.02
284.1192627	0.07
296.2108154	0.07
299.1040649	2.21
300.2397461	0.42
305.1764526	1.33
312.0576172	0.24
314.0932007	11.47
315.2109985	0.54
324.1715088	0.10
327.5228882	0.50
329.1243286	52.79
336.4979858	0.07
339.2251587	0.23
341.1541748	0.04
342.1690674	0.14
343.3198242	0.03
351.1281128	0.51
369.0970459	0.11
371.1410522	5.85
381.2546997	0.06
395.0990601	0.23
412.9266968	0.08
423.1977539	0.10
454.9387817	0.19
472.8132324	0.14
473.4180298	0.38
476.2157593	0.02
477.3126831	0.08
491.2930908	100.00
518.9102783	0.23
519.5725098	0.08
533.2200317	51.50
533.8471680	0.13
559.3728638	0.04
561.4991455	0.03
573.2678223	6.17
585.4130859	0.08
617.3186035	0.04
635.1826172	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.2184
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
135.1383362	1.31
137.0333710	14.81
141.0348206	19.01
143.0777588	0.38
144.9635773	0.35
145.8269653	0.58
147.0303345	1.27
149.0612640	6.41
150.7996216	1.58
153.1184387	2.95
157.7876587	6.10
159.1077881	2.64
161.1461182	5.77
162.9027557	3.74
163.8644104	0.95
164.9861450	3.81
166.1368256	1.53
167.1179810	1.34
168.9031525	1.03
171.2464600	0.66
173.0623322	21.54
173.7609863	1.60
175.1767578	3.48
175.9769592	0.32
177.2936859	1.97
179.1360168	10.71
181.1445923	0.97
183.1676025	8.17
187.0552368	4.86
188.0181274	0.47
189.1794281	12.02
191.1902771	29.41
193.1777954	15.70
195.0239258	2.15
201.0654602	8.74
203.1356812	6.26
205.0950317	1.90
207.1316223	35.05
209.0552979	5.21
211.0678558	8.06
212.2247772	0.43
213.1986237	7.39
215.1576843	12.44
216.2529907	0.58
217.1943054	1.05
219.2181549	5.47
221.1015930	5.79
225.2639771	2.98
227.1896667	14.40
228.6176758	1.99
229.2533875	6.96
230.0888367	1.27
231.1213074	17.29
233.1914825	16.14
235.2485199	5.92
237.2187958	1.79
239.1404419	2.77
241.1179504	2.17
242.0563965	0.38
243.1576538	7.14
244.2283936	1.05
245.2185974	91.26
247.1617432	3.43
249.2232361	25.03
251.2957153	0.73
255.2106323	2.49
257.0758362	5.61
259.2864380	4.89
261.2241516	1.04
263.2534790	39.88
265.2942505	1.55
267.1939087	12.25
269.3223572	0.98
270.3754272	0.89
271.4019775	0.71
273.1945496	19.11
275.0998535	84.93
277.3110352	1.80
279.4884644	1.06
281.3080139	1.17
283.3143005	1.70
284.1493835	0.55
285.2483521	13.71
286.0684204	0.57
287.1787109	0.47
288.3781433	1.67
289.4008179	1.04
291.2874146	5.74
293.3656616	5.75
295.3577271	1.31
297.3500977	0.74
299.1351624	5.94
301.0513916	3.62
303.2724609	100.00
306.6000977	1.61
307.3270264	7.84
309.0677795	0.24
313.1790161	3.79
315.0634460	4.28
317.3005676	0.87
319.2798157	4.89
321.2580261	34.02
323.3233032	11.44
326.8598633	0.47
328.2127991	0.49
329.4913330	0.38
336.7203979	2.70
337.3376465	21.14
340.6679688	0.27
341.3232117	13.92
343.0773621	1.13
344.6015320	1.91
345.4600830	8.31
353.3345032	1.06
356.3290710	0.35
359.1000366	5.95
360.4326477	2.64
365.3407593	20.30
370.9935608	0.35
373.1317444	2.40
374.3457642	0.93
375.5616150	0.30
387.4679565	2.55
401.4356384	1.39
414.4064636	1.35
415.2974548	3.52
416.3899536	3.27
417.4405823	4.73
433.6326599	0.35
446.2775574	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.2317
Annotation	3,7,12-Trioxochol-5-en-24-oic Acid
Peak:m/z	Relative Intensity
122.9613495	0.07
125.1043167	0.57
126.0755386	0.12
131.1834106	0.38
133.1521301	0.09
139.0935822	0.32
145.1254272	0.12
146.8210449	0.19
149.0283508	0.36
150.9173584	0.13
152.9489899	0.20
156.8680573	0.27
158.9810028	0.82
160.7774353	0.92
162.9165497	0.15
164.9827881	0.13
167.0413818	0.87
169.0764313	0.25
171.0690918	0.50
173.0041656	1.26
174.9825439	0.93
177.2062073	0.09
182.9956970	0.56
185.1719971	0.07
187.0607910	2.26
189.1976776	1.01
190.6518402	0.27
193.1954346	0.29
195.1467743	0.35
197.0676422	0.66
199.2366638	0.77
201.1389313	1.40
202.9323425	0.13
205.2451935	0.28
207.1696167	0.18
211.2295380	0.29
212.9668884	0.11
214.0178833	0.21
215.1113892	0.54
216.2658997	0.17
217.2855988	0.30
219.1271667	0.30
221.2363586	0.18
227.2803955	0.55
228.2054443	0.09
229.1560974	0.29
232.9031677	0.18
235.1958313	0.27
237.0894775	1.06
239.1800842	0.78
241.1461487	0.58
242.9362183	0.17
244.2873535	0.12
245.1263123	0.63
247.0760193	0.29
249.1984863	0.56
251.0344238	0.72
253.2635498	1.80
255.1966248	0.98
259.1591797	0.87
260.1870422	0.30
261.2330627	2.59
262.5329895	0.62
263.2704163	5.68
264.5573120	0.70
265.3885498	0.71
267.0159912	1.13
268.9605408	0.35
270.1785583	0.15
271.1496277	0.65
272.9287720	1.27
274.2575684	0.22
275.3065186	0.22
277.1505127	0.58
279.2560425	7.38
280.1464844	0.35
281.2654419	0.54
283.1205444	3.79
285.4069519	0.64
287.4271851	0.55
289.3136902	2.07
291.2159119	0.35
293.2729492	0.71
295.1454468	1.07
297.2895508	3.09
298.8394470	0.97
299.4445190	0.18
300.3490906	0.24
301.2037964	0.76
302.2847900	0.15
303.2379456	0.54
304.1475220	0.53
305.2617493	3.02
306.0484314	0.13
307.1312561	3.39
310.0456238	0.16
311.1372681	0.08
313.4311218	0.45
315.1375732	0.38
316.6961975	0.61
317.2977905	0.75
319.6421509	0.16
320.3787842	0.11
321.3247070	0.87
322.7507629	2.86
323.3631592	7.85
325.1321716	2.16
327.5007935	0.14
328.2633362	0.24
329.3112183	0.90
335.2875671	0.44
337.3214722	2.49
339.4439697	1.28
340.3776245	0.77
341.3720703	5.22
342.2466431	0.06
343.4742737	0.24
347.2752075	5.30
354.0427246	0.23
355.1938782	1.65
355.8820496	0.11
357.2975769	0.24
358.9651184	0.45
359.6247253	0.18
365.1714478	28.44
368.3494263	0.09
372.6807861	0.41
373.4382019	0.76
383.2296448	100.00
383.9502563	1.05
386.1780090	0.57
387.1266174	0.12
391.8299255	0.32
398.1715088	0.19
403.7804871	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	7,3'-Dimethylorobol
Peak:m/z	Relative Intensity
106.2812881	0.03
143.2295074	0.02
160.0552368	0.01
177.9455414	0.02
183.3907776	0.01
186.9258270	0.02
190.7968445	0.03
193.2534790	0.03
199.3125305	0.02
201.3687286	0.01
204.0688782	0.02
211.2374573	0.01
223.0472107	0.02
225.1980591	0.01
229.4592896	0.01
241.0833435	0.04
244.9573059	0.01
251.3501282	0.01
255.1505737	0.09
267.2308960	0.13
268.2135925	0.20
269.1153870	0.24
270.2465820	0.03
270.9731445	0.01
276.4789429	0.02
277.2489014	0.01
280.1978149	0.03
281.0979309	0.15
283.0627441	3.80
283.9434814	0.01
285.2658081	0.35
286.2521057	0.04
293.3959351	0.02
294.2586670	0.18
295.3519592	0.23
298.0779419	100.00
298.9414062	0.01
313.1932983	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.1746
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
120.9719696	0.52
123.0292740	5.59
124.9484711	0.84
126.8452454	0.98
129.0712280	0.08
130.9718018	0.08
132.9681702	1.00
134.1540985	0.10
138.1898804	0.04
139.0979767	0.82
145.1014404	0.44
149.0470581	0.17
151.0812988	52.72
160.9183960	0.09
162.1817932	0.21
162.9335632	0.43
165.7985687	0.13
167.1176147	1.17
169.0155029	100.00
170.9923096	0.34
175.1058960	0.07
176.2829590	0.10
176.9803925	1.29
177.9311218	0.37
186.9698029	0.12
191.1184998	0.18
195.0967865	0.12
201.1081848	0.32
211.0724945	0.09
212.7472839	0.99
217.0977936	0.21
219.4124756	0.40
222.9248657	0.19
224.9682007	0.31
227.4513245	0.32
231.0176086	2.81
232.3040771	0.10
232.9909363	0.36
235.1709900	0.97
235.9876404	0.18
239.2008972	0.18
243.2369080	0.14
247.2784119	0.10
248.2033997	0.30
249.0130310	1.32
250.3415222	0.05
251.0268860	0.37
252.0265808	0.33
254.7915649	0.59
255.8486023	0.17
261.3776855	0.32
262.9740295	0.27
267.2141724	0.38
271.2306213	0.09
277.2100830	0.24
279.1583252	0.11
281.1372070	0.09
285.0598145	0.05
289.0851440	0.16
294.8972778	0.34
297.3772583	0.56
307.1389771	0.28
311.3166199	0.26
320.8471680	0.05
326.2239990	0.10
327.1515198	0.16
329.1869202	0.18
331.0552979	0.69
332.2632141	0.62
339.1504822	1.59
345.4916382	0.23
350.5237122	0.17
351.3395081	0.18
352.6848450	0.30
353.5683594	0.27
355.3048706	1.63
357.5033264	1.14
358.3161316	1.70
359.2348938	0.61
360.6747437	0.14
363.1743164	0.71
367.3582153	0.13
369.2122498	0.17
371.3454895	0.81
372.9516296	0.55
375.3835449	0.07
378.9430847	0.15
380.3118591	0.62
381.0724487	5.51
381.7573853	0.06
384.9873962	0.14
385.6368408	0.20
387.4834900	1.08
388.3059387	1.10
389.3020935	0.15
398.1688538	2.70
399.1515503	3.94
400.0714111	0.30
401.2221985	0.36
404.7198181	0.25
407.4038086	0.72
408.5940857	0.33
417.1172180	0.31
418.2690430	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	367.161
Annotation	(2S)-2-Butanol O-[b-D-Apiofuranosyl-(1->6)-b-D-glucopyranoside]
Peak:m/z	Relative Intensity
113.0299683	0.04
114.0772171	0.09
118.8952026	0.15
119.8550034	0.02
120.8948975	0.07
123.9441147	0.03
141.1621094	0.12
143.1011353	0.13
144.2582092	0.05
150.9382935	0.05
158.1273804	0.03
159.0223236	0.05
160.1377258	0.13
161.0293274	0.77
162.9920044	0.16
163.9788513	0.16
171.1832275	0.07
172.9642334	0.13
178.6946411	0.07
180.1014557	0.09
191.0769043	0.02
192.1400909	0.09
193.0849457	0.10
202.9769135	0.15
205.1810608	0.34
207.4576874	0.02
210.1929626	0.02
221.2269897	0.02
225.0924988	0.04
237.2453613	0.08
241.1731567	0.03
246.3652039	0.03
247.2001038	0.02
249.1837158	0.15
250.1474304	0.11
255.5023193	0.02
263.1553040	0.06
265.1213989	0.02
278.2778015	0.03
279.3005981	0.07
282.2600098	0.05
283.3277588	0.19
287.1447144	0.17
299.0644531	0.32
303.2853699	0.22
304.3236084	0.02
305.2346191	0.09
306.3169556	0.02
307.2442017	0.14
319.1334229	0.03
321.1706238	100.00
321.7973022	0.37
323.1052856	0.17
324.4760132	0.04
325.3191223	0.04
333.3886719	0.04
335.0946045	0.04
337.6287842	0.04
339.4886475	0.08
346.1182861	0.09
347.2993164	0.48
348.1954346	0.27
349.0907288	0.27
349.6947021	0.02
351.2985535	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0718
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
117.2074661	0.05
131.87323	0.11
150.9933014	0.03
163.9326172	0.03
167.0823669	0.07
175.0524597	0.02
178.0045624	0.08
185.0523987	0.02
191.2546997	0.03
193.053894	0.91
194.9951019	0.10
197.3373413	0.03
199.1265259	0.03
203.0809937	0.02
203.9708862	0.03
211.2049866	0.04
213.2219543	0.03
214.0489502	0.01
215.2016296	0.02
217.427002	0.04
219.230835	0.04
221.0565491	0.01
222.915741	0.02
224.2666626	0.04
225.0950928	0.06
227.1403809	0.16
238.8195801	0.03
241.0312195	0.23
242.0194092	0.10
251.3783875	0.16
253.1466064	0.18
254.09729	0.02
255.1113892	0.19
257.244812	0.16
267.066925	0.50
269.12677	0.57
270.0640259	2.73
271.2512817	0.04
277.0386963	0.06
281.1507568	0.11
282.3329773	0.54
283.1477051	2.24
285.0569458	5.45
293.0720825	0.04
294.9964294	1.94
296.0116882	0.13
298.0488892	100.00
299.296875	0.18
313.2613831	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2011
Annotation	Unknow
Peak:m/z	Relative Intensity
133.0700226	1.00
134.9997711	0.29
136.9552002	0.77
139.0799713	2.57
140.8509216	0.38
143.1276550	0.21
145.0155029	0.58
147.0370636	1.97
148.6603088	0.54
149.3614960	0.25
150.9885559	0.33
152.8767548	0.12
155.1953430	0.23
156.0768433	1.47
159.0203247	1.45
161.0469971	1.57
163.0850525	1.01
165.0713196	0.28
165.8864441	0.09
167.0190125	0.12
171.0632172	4.87
174.0765076	0.49
177.0507355	0.59
179.0848999	0.44
181.2207336	0.14
183.0355682	0.09
187.1438293	1.54
189.0260620	8.71
189.6448669	0.09
191.0286102	0.14
203.0108032	0.06
205.3092957	0.11
207.0598450	100.00
208.3315887	0.09
209.3924866	0.05
210.0113525	0.04
213.0605469	0.55
218.9600830	0.17
220.9304810	0.03
224.4607391	3.47
225.1235504	39.01
226.1375732	0.05
228.0796509	0.07
229.0548401	0.04
230.8817596	3.18
235.8234711	0.26
240.4139252	0.04
244.5689240	0.15
248.9218750	0.35
255.1358643	0.09
259.9322815	0.15
260.9281006	0.03
264.9850769	0.02
267.0754395	0.47
268.0932922	0.10
269.1019287	0.05
270.1711121	0.09
272.0737000	0.20
273.2694397	0.10
277.2136230	0.07
279.0131836	0.18
280.0629578	0.06
283.2854004	0.04
287.2645874	0.19
289.2895203	0.10
291.1389771	0.10
293.2285156	0.10
294.3148193	0.05
295.2799988	0.07
296.1830750	0.10
297.0595398	0.06
299.1859131	0.03
301.2482910	0.06
302.0664978	0.06
303.2239380	0.14
305.2033691	0.05
306.5161133	0.02
308.2775269	0.20
309.1023865	0.57
310.2756042	0.08
311.1416321	0.76
315.2848511	0.85
317.3464661	0.02
320.5490723	0.64
321.2637939	0.22
323.1994629	0.13
325.5595703	0.11
326.2397156	0.22
329.1942139	0.09
330.2658081	0.06
331.1992188	0.13
333.3345947	0.44
335.0180969	0.08
338.9189148	0.49
340.5443420	0.12
341.3923645	0.10
342.6677246	0.25
343.2766724	0.22
344.3265381	0.11
348.1271973	0.16
350.2808838	0.04
351.1912842	0.21
352.8922119	0.54
357.2702332	0.02
360.4816284	0.04
364.9205322	0.06
369.1494446	1.60
371.1616821	0.03
373.5312500	0.15
374.8989258	0.83
378.4470215	0.10
379.9341125	0.06
382.4956970	0.11
383.2979431	0.03
384.3028564	0.46
385.4017944	0.24
387.1658325	1.97
389.0337830	0.17
393.1071777	6.63
393.8772583	0.15
394.5092468	0.04
397.2456360	0.14
398.1502991	0.24
399.3890686	0.12
401.2326355	0.31
405.2291565	0.02
407.0394592	0.18
409.1306152	0.27
410.4102478	0.24
411.1823120	4.13
413.3065186	0.43
414.3360291	0.11
415.3414917	0.07
415.9589233	0.09
419.0908203	3.83
419.7836609	0.05
420.5000000	0.12
427.1971130	0.18
428.2391663	0.30
429.1726685	1.04
433.2248840	0.05
434.4260559	0.06
436.2316589	0.97
437.0609131	12.72
437.8529053	0.19
438.8632507	0.03
440.5453491	0.14
442.2816162	0.09
443.3883362	0.13
444.2690735	0.12
445.3217163	0.05
454.5552368	10.52
455.2272644	24.26
456.2757874	0.48
464.2115784	0.08
473.0472107	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.2054
Annotation	Tomentodiplacone B
Peak:m/z	Relative Intensity
127.9727020	0.22
129.0122375	0.29
131.0490417	0.66
132.9646454	1.62
133.8672485	0.13
134.9627838	0.76
137.0463104	0.19
141.0002747	0.59
142.0864563	0.34
142.9700317	0.12
145.0704041	1.49
146.0317841	0.03
147.0563049	1.46
148.9727783	0.96
150.9943542	0.18
152.8957520	0.74
155.0316315	0.19
155.9945831	0.17
157.1031494	0.85
159.0132751	1.82
160.9618683	25.35
162.0546112	0.09
163.0755310	2.40
164.9854584	0.30
167.1293793	0.29
169.0384216	1.74
169.9794922	0.14
170.9848328	1.89
171.9568481	0.12
173.0980530	2.74
175.0270386	4.76
176.9800415	1.55
179.0832825	0.76
180.0792389	0.17
181.2456360	0.99
182.0613708	0.09
183.1254272	0.83
185.0896301	2.62
186.0083160	0.04
186.9958649	8.45
188.9672852	2.71
191.0852051	0.86
193.1887207	1.30
195.1387177	0.52
197.1208496	2.55
199.1143188	3.14
201.1763916	3.17
203.1307220	2.02
204.9344788	0.58
206.0562439	0.14
207.1148071	0.93
209.0895996	1.50
211.1246643	2.59
212.9725952	2.25
214.0809937	0.94
215.1410675	2.93
217.1721191	2.23
218.2157288	0.06
219.1384888	2.52
220.1889496	0.04
221.0719910	0.70
223.1479645	2.06
225.0649109	3.56
227.1696472	3.50
228.9390564	1.98
229.7707672	1.14
231.1758270	1.18
233.0062866	0.91
235.2212677	0.90
236.0975189	0.09
237.1055756	3.09
239.0524445	2.96
241.1567993	2.31
241.9750366	0.04
243.1673889	2.86
244.1471863	0.16
245.2295532	2.78
246.5368042	0.24
247.1696167	1.59
249.0982361	1.70
250.1510010	0.45
251.1657715	2.18
252.4943237	1.21
253.2153320	2.63
254.6185608	0.72
255.3096924	1.44
257.1744995	1.23
258.0712280	0.04
259.1880798	2.26
260.1790771	0.16
261.1329346	1.93
262.0444336	0.09
263.1343689	3.27
264.3695068	0.15
265.2494202	1.71
265.9964600	0.19
267.1638184	2.81
268.6083374	0.14
269.2624512	4.26
270.3191528	1.15
271.1159058	2.12
272.4848328	0.80
273.2374573	3.69
275.0676270	2.07
275.9977722	0.10
277.2298584	2.85
278.1530151	0.78
279.0986328	3.10
280.6040955	0.97
281.2126770	5.51
283.1795044	4.35
284.0523071	0.20
285.2849426	3.24
286.2240906	0.44
287.1679688	5.86
288.3991089	0.49
289.1062622	2.01
290.4575195	0.54
291.2169495	2.62
293.2367249	4.27
294.1840820	2.83
295.2278442	3.35
296.0553894	0.98
297.1940308	5.93
298.3275757	0.12
299.2652893	1.44
300.0712891	0.86
301.2730408	2.16
303.1324768	5.29
304.4989624	0.95
305.2001648	4.52
307.2298889	2.20
308.5403442	0.37
309.3075562	3.47
310.2386475	0.04
311.2051697	4.36
312.0934143	0.26
313.1925964	9.18
315.1631165	22.48
316.3126831	0.50
317.2127075	0.84
319.2542725	4.22
320.2739258	0.42
321.1616211	5.33
322.2313232	0.73
323.2444763	5.71
324.0768433	0.76
325.1348572	1.75
326.1029663	0.21
327.2651978	1.15
328.0330200	0.05
329.2824707	1.81
331.1906128	13.43
332.1533813	1.18
333.2698364	9.52
335.0986938	3.73
337.2508545	4.72
339.2666931	4.09
341.2050171	13.14
343.2512817	1.17
345.1397095	2.52
346.3989868	0.40
347.2995605	5.77
349.1417236	9.11
350.2710571	2.52
351.3074646	8.18
351.9482422	0.03
353.1510620	0.69
355.2808838	3.00
357.2271118	11.37
358.1663208	0.47
359.2247925	11.56
360.0689392	0.03
361.2615967	1.08
362.4233398	0.51
363.2591553	5.67
365.3107300	9.39
367.2214355	1.80
368.4741211	0.64
369.2595520	1.00
373.2914429	8.03
375.3339539	11.10
377.2112427	10.10
379.1590271	0.40
381.3413086	4.44
383.1976013	2.53
386.3308105	0.08
387.2772217	1.64
389.2308960	0.90
391.3178101	19.03
393.3126221	28.94
395.1908264	3.05
397.4468689	0.25
399.4239807	0.56
401.2216187	9.20
407.2926941	1.31
409.2908020	100.00
411.3076782	50.70
412.3531799	0.28
413.0611877	0.20
415.0866089	0.10
417.2261963	0.04
419.2817688	22.80
425.4576111	0.25
427.2775269	4.31
437.2836609	40.01
440.3664856	0.03
455.0866394	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.192
Annotation	Myricatomentoside II
Peak:m/z	Relative Intensity
225.0890656	0.02
235.4206848	0.05
252.9640198	0.04
295.4841309	0.03
297.2555542	0.02
313.3585205	0.03
321.3447266	0.02
323.0895996	0.13
339.2692871	0.10
347.3991699	0.07
349.3555298	0.03
351.2864380	0.05
353.2344971	0.04
357.0386353	0.06
365.3397827	0.03
367.2199707	0.03
375.4811401	0.04
381.3732300	0.02
383.3851929	0.04
391.1594849	0.04
393.3578491	0.07
395.3356934	0.12
397.0210571	0.02
411.2517700	1.23
427.3442383	2.35
435.5682373	0.02
439.3811646	0.08
453.2437134	0.06
469.2273560	100.00
469.8662720	0.51
471.2670898	5.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1734
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
214.3415527	0.03
228.9919128	0.05
236.0401154	0.07
241.0611572	0.03
243.1040955	0.06
252.8714600	0.03
257.1079102	0.10
266.9614868	0.02
283.1691895	0.15
284.9522400	0.06
285.8943176	0.02
296.0654297	0.05
297.1520081	0.14
298.8098145	0.03
301.2252502	0.23
305.1527710	1.19
310.9877319	0.10
312.1931152	0.02
313.4406738	0.14
314.3120728	0.41
315.3634338	0.10
326.2102661	0.42
328.2363892	0.24
329.1947937	3.27
330.2543335	0.66
331.2952881	0.07
343.2677612	1.26
344.1130371	11.50
345.1898804	3.02
354.3271484	0.12
357.0426025	0.25
359.1127930	44.49
366.1541138	0.05
369.2598877	0.07
371.0990601	0.09
372.3434448	0.22
373.2282104	0.28
381.2111206	0.46
381.9360962	0.02
386.2420654	0.12
387.2658081	0.20
401.1760254	4.91
410.2465820	0.04
415.1524658	0.05
425.0737305	0.47
429.0599365	0.03
443.3291626	0.06
471.3812256	0.02
489.2199097	0.07
503.2673340	1.79
506.1534424	1.07
507.3820801	0.91
521.2324829	100.00
521.8504639	0.53
534.3229370	0.24
548.3242798	0.24
549.3314209	3.55
563.2504272	70.69
589.3026123	0.57
591.3492432	0.17
603.3977661	3.37
615.2436523	1.31
633.1963501	0.72
647.1630249	0.48
649.9541626	0.05
665.1160278	5.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1829
Annotation	Genipin gentiobioside
Peak:m/z	Relative Intensity
160.8853760	1.21
166.9363708	0.42
167.8511505	0.06
178.9378967	5.70
181.5578308	0.15
193.0412292	0.05
197.4099426	0.12
202.9942017	0.28
221.1040039	8.02
222.9551849	0.21
241.2976990	0.08
245.0944824	1.11
263.0632324	3.62
275.1876831	0.11
281.1184692	0.07
305.0926514	0.20
311.0594482	0.14
323.1184082	100.00
324.2272949	0.06
357.1467896	0.18
381.3740234	0.40
386.3049927	0.32
387.4541626	0.08
402.3598022	0.13
403.0452271	0.41
411.0856934	0.06
412.4908447	0.21
413.1994629	0.10
419.0893555	0.08
428.1752930	0.10
431.1229248	0.35
439.3253784	0.10
453.4698486	0.27
459.1854858	0.56
461.4783325	0.25
463.2215576	0.56
489.3135376	0.05
501.4050293	0.11
502.8338013	21.15
503.6228638	0.28
505.3824463	0.24
511.7580566	0.21
513.1105347	0.24
516.7412720	0.48
517.5137329	0.59
530.2151489	0.17
531.2880859	0.11
550.1801758	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	856.4323
Annotation	Unknow
Peak:m/z	Relative Intensity
238.2461853	0.07
245.0520782	0.20
250.7545471	0.02
256.0639038	0.17
265.8924561	0.11
283.9399109	0.55
285.1867676	0.04
288.3395691	0.04
297.1539001	0.08
300.1698608	0.03
301.1927490	0.12
302.1516113	0.05
310.7617493	0.05
313.2375183	0.05
317.9675293	0.03
322.0503540	0.08
325.3389587	0.06
328.2868652	0.09
329.2103882	0.08
330.1106567	0.04
340.7594604	0.08
342.4350281	0.07
343.4064941	0.02
346.3333740	0.20
356.2972412	0.02
357.2055664	0.12
359.3321533	0.38
362.7768555	0.01
367.2371826	0.85
379.3364258	0.02
380.1595459	0.03
385.2774963	0.38
386.3218994	0.09
396.3170776	0.05
397.4901123	0.07
398.3529663	0.09
403.0777588	0.07
408.4423218	0.06
413.1426392	0.06
415.3181152	0.07
418.4361572	0.07
421.1641235	0.20
424.2015991	0.25
425.4605103	0.02
426.1207886	0.04
431.1578979	0.22
432.1818237	0.05
436.2185669	0.07
437.2810669	0.03
442.2131348	0.66
444.3914795	0.42
452.1803589	0.02
453.3215942	0.15
453.9668579	0.01
455.6906738	0.03
456.4948730	0.12
465.2976074	0.30
470.3306274	0.55
471.3267822	0.08
472.3046875	0.70
472.9143677	0.10
477.4265747	0.23
481.3597412	0.16
487.5028076	0.02
492.3240356	0.02
493.5373535	0.09
496.6597900	0.06
498.3207397	0.07
499.5581055	0.26
500.3722534	0.46
507.4110107	0.03
510.1859741	0.19
511.4524536	0.16
514.3439941	0.02
515.4630127	0.07
516.4260864	0.04
520.3073730	0.01
525.2194214	0.07
528.2822876	1.76
537.3221436	0.04
539.5524292	0.15
545.2577515	0.32
546.2238770	0.04
549.6291504	0.21
550.3230591	0.03
551.4919434	0.15
554.1068726	0.04
555.5043945	1.52
562.3447266	0.04
565.0434570	0.09
566.5523071	0.20
567.4268188	0.25
568.4274292	0.31
571.0540771	0.04
572.1861572	0.04
573.4100952	1.03
576.2927856	0.17
579.5051880	0.03
582.9596558	0.18
584.2636108	0.92
584.9774780	0.10
585.6102905	0.14
589.1878052	0.02
594.4282227	2.87
596.2758179	0.10
597.4866333	0.11
601.5552368	0.25
606.4959717	0.08
607.6362915	0.01
608.2957153	0.13
611.2841187	1.32
612.4710083	4.29
617.4887085	0.12
624.0603027	0.32
624.6853638	0.07
628.2502441	0.05
629.3754883	0.73
634.5829468	0.13
639.9295044	0.05
640.9083862	0.04
646.5474854	0.06
649.9237061	0.16
652.5415039	0.30
655.7161255	0.07
657.7000732	0.07
660.4597778	0.06
663.2972412	0.04
665.3756714	1.26
667.6657715	0.03
668.5993652	0.23
670.4906616	0.26
674.0161743	0.12
676.9251099	0.08
678.6484985	0.08
680.7879028	0.04
681.5304565	0.15
686.4735718	0.82
691.4995117	3.35
696.4282227	0.20
697.6245117	0.29
698.3916626	0.24
699.4911499	0.06
703.5494995	0.07
707.3792725	0.25
709.4966431	2.85
711.7044067	0.02
714.5263062	4.27
715.5556030	0.07
721.4083862	0.59
724.1035767	0.20
725.4732666	1.60
727.4111938	0.69
737.6972046	0.06
739.4603882	0.18
741.4688110	0.87
742.5121460	0.43
743.5480347	2.22
755.2989502	0.20
759.3226318	0.23
765.2393188	0.08
781.5434570	0.12
783.6826782	0.06
784.4834595	0.18
787.2869263	0.10
789.8839722	0.07
790.5083008	0.06
791.5343628	0.06
792.6167603	0.05
793.3003540	0.03
794.5039673	3.79
795.5397949	0.04
799.5338135	0.48
802.5364380	0.03
803.7329102	0.07
810.5055542	1.28
811.4823608	0.54
812.4228516	0.79
813.0234985	0.02
820.4730835	6.39
821.3002319	0.06
828.6279907	17.16
838.5509644	28.93
856.4456177	100.00
857.1915894	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.16
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
191.0376129	0.02
233.0954895	0.03
255.9412842	0.06
271.1247559	0.45
273.9179993	0.28
275.0690613	0.02
289.0626526	0.02
299.1210327	0.17
302.0435181	4.58
303.5440674	0.02
306.1245728	0.04
313.3377075	0.01
315.2893677	0.14
317.1055908	100.00
317.9255371	0.02
326.9798889	0.02
331.0958862	0.08
334.7003174	0.05
342.1751709	0.15
344.7885742	0.05
359.1746826	0.76
360.1847534	0.29
373.3521118	0.02
375.1643066	2.60
383.2245483	0.10
385.4524536	0.06
397.2439575	0.02
400.4163818	0.09
407.0484619	0.04
413.2749634	0.02
414.9520264	0.02
416.6500854	0.02
417.2791138	0.02
425.2327881	0.29
443.2281494	0.01
448.5391235	0.02
459.6748657	0.02
460.6156006	0.07
461.2717896	0.09
463.0691528	0.11
464.0950317	0.01
474.2514648	0.02
477.1423340	0.01
479.1110229	0.07
489.2854614	0.05
492.3314819	0.02
509.1269531	0.03
525.3533936	0.07
537.4454956	0.03
551.1035156	0.01
558.9656982	0.01
561.1353149	0.91
563.1719971	0.05
569.1334839	0.04
574.4898071	0.03
577.1316528	0.03
578.4378052	0.10
579.1572266	0.05
587.2233276	0.31
590.5747681	0.01
591.2355957	0.06
604.3546753	0.26
605.2814331	1.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.1064
Annotation	6-Deoxyclitoriacetal
Peak:m/z	Relative Intensity
115.0179291	0.01
122.9583588	0.01
124.1151962	0.05
130.9290161	0.01
144.9909515	0.07
147.0877380	0.01
149.4052124	0.01
151.1156158	0.03
163.2242126	0.01
164.9625549	0.48
167.2857361	0.01
170.6314392	0.07
173.0684814	0.04
176.8864746	0.05
182.2352600	0.03
183.0151672	0.03
184.0041962	0.03
193.1640778	0.05
195.2604828	0.01
198.1038666	0.06
200.1220856	0.05
201.0301819	0.03
202.8863220	0.01
205.1003113	0.04
209.0106506	0.02
213.0318146	0.39
214.0008545	0.02
218.7364807	0.03
229.1606445	0.03
233.2398376	0.05
234.3063965	0.07
235.0113525	0.03
238.9940796	0.02
244.3957520	0.02
254.1415710	0.02
254.8503723	0.01
259.0108337	0.11
261.2037964	0.12
265.3451538	0.02
268.2751465	0.02
269.2030640	0.02
271.1980591	0.01
272.1106567	0.01
276.1298523	0.03
277.3267822	0.13
279.0733032	0.05
281.5388794	0.07
282.3605957	0.05
283.2049561	0.01
284.3123169	0.01
287.2855835	0.10
293.4041748	0.08
299.4905396	0.04
300.4879456	0.13
301.2371216	0.08
304.3444214	0.01
305.3986816	0.01
311.6145630	0.01
312.2937622	0.02
313.1519775	0.01
314.2680054	0.08
315.2357483	0.35
317.1521912	0.05
319.4166565	0.02
325.9583740	0.10
328.1392822	0.35
329.2388916	0.34
330.3080139	0.07
331.1358948	0.13
332.6784058	0.04
333.2854919	0.04
338.3822021	0.04
339.3346863	0.04
340.2080383	0.05
342.1531982	21.14
343.1425781	1.27
345.1128540	36.15
346.2070007	2.41
356.2364807	0.86
357.1789551	1.32
360.1009216	100.00
361.2177429	4.18
366.3011475	0.03
374.3551331	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2081
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
158.8930969	0.14
202.8741150	0.22
228.5021057	0.08
243.1029510	0.14
257.2731018	0.24
259.1903687	0.24
261.1148376	0.29
263.2857056	0.04
271.2890930	0.91
275.1034546	0.25
281.0859070	0.07
289.3540649	0.46
297.3275146	0.33
298.0986938	0.34
299.1564331	4.43
308.6619873	0.23
309.2968140	2.98
313.4337769	0.17
315.2960205	0.64
327.7395020	0.12
333.2520752	12.07
335.3322754	0.28
341.0879517	0.10
343.1320190	0.22
351.3177490	0.14
353.2659302	0.98
365.0635986	0.32
367.4887085	0.45
371.1408691	0.79
374.7822266	0.15
383.1989136	0.22
391.1889648	0.19
393.4938354	0.72
409.4901123	0.32
411.3085327	12.95
423.3020020	0.20
429.0654907	46.58
429.7852173	0.12
435.4661255	0.67
441.3372803	0.19
443.4922485	0.05
453.2161255	54.04
454.8343506	0.17
455.5145264	0.33
469.0889282	0.14
471.2593994	100.00
472.7391968	0.08
473.6608276	0.65
480.9446411	0.29
499.1264648	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	RHOIFOLIN
Peak:m/z	Relative Intensity
167.7503052	0.01
168.9893951	0.06
183.0715942	0.04
197.1047668	0.06
203.0066223	0.01
214.1732178	0.00
215.0035553	0.02
225.1308289	0.09
229.1205902	0.04
243.2266693	0.10
253.5028381	0.01
255.3224335	0.04
271.0619507	100.00
271.9752197	0.04
281.0027466	0.02
283.1329651	0.01
294.7341919	0.03
298.0948792	0.01
308.0549316	0.02
313.1824951	0.20
329.0757446	0.03
331.15271	0.15
337.1217041	0.10
347.4126587	0.01
351.1732788	0.02
363.3380127	0.03
367.0773315	0.14
372.4329834	0.02
373.2197876	0.01
379.2546387	0.07
381.1750488	0.26
383.4050293	0.01
387.2261963	0.01
390.9569092	0.02
397.2813721	0.09
399.2067871	0.14
415.1646729	0.60
417.1641846	0.32
429.0834961	0.02
433.1634521	11.55
435.0772095	0.03
441.3076782	0.05
456.4463501	0.04
459.157959	0.02
475.104187	0.01
489.0896606	0.02
497.1256714	0.01
504.2403564	0.01
517.0341797	0.02
520.5359497	0.05
521.2927246	0.03
537.3175659	0.01
538.3392334	0.02
542.3060303	0.01
543.2055664	0.01
560.119751	0.10
560.881958	0.16
570.4943237	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	546.1956
Annotation	Doxorubicinol
Peak:m/z	Relative Intensity
147.1214600	0.02
151.8818054	0.01
153.0942383	0.11
160.1781464	0.07
170.1290283	0.10
175.0603333	0.05
178.0691071	0.75
179.1845093	0.06
182.9934387	0.04
185.2571716	0.02
186.1668701	0.02
187.1771545	0.29
188.2397003	0.09
189.0424500	0.07
201.2344360	0.02
202.0475922	0.02
203.3095093	0.16
204.4329224	0.04
207.0904083	0.08
213.0482941	0.33
218.2307434	0.04
227.1760864	0.13
228.1954193	0.08
231.0502014	1.20
232.0908813	0.03
245.2371521	0.07
248.9473114	0.14
255.0875549	0.06
273.0734558	0.45
291.1806641	0.05
294.5631104	0.03
296.5776978	0.10
298.1812744	80.76
299.2691040	18.06
309.2783203	0.01
314.4387207	0.05
315.2294922	0.04
320.3049316	0.01
323.1313477	0.06
338.4078979	0.09
339.3967285	0.04
340.3201294	0.25
341.0431519	0.04
351.1826172	0.02
356.2590942	8.01
357.2381592	2.33
359.0789795	0.04
364.3770142	0.01
366.4238892	0.03
382.4047241	0.22
383.2835083	0.03
395.0579224	0.64
396.2063599	0.02
398.1397705	0.05
400.1914673	100.00
401.2256470	29.61
401.8408813	0.11
405.9215088	0.03
427.4351807	0.04
436.4037476	0.05
443.8169556	0.03
456.8988647	0.05
460.2355347	4.84
461.3348389	1.82
466.4517212	0.03
484.4561157	0.17
485.2080688	0.05
489.8506470	0.02
502.2456055	6.34
503.3723145	2.12
510.4160767	0.03
528.1354370	2.17
529.1632690	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.08
Annotation	Unknow
Peak:m/z	Relative Intensity
111.9589920	0.19
128.8146057	1.13
130.0404205	0.69
145.2259216	0.22
147.0405426	2.34
147.9879913	0.97
172.7658539	0.70
173.8955536	0.18
190.9546204	100.00
192.0665894	57.69
193.0553284	1.06
194.1738281	0.90
209.0474548	15.10
209.9734039	6.36
350.0632935	1.00
366.9534607	2.88
368.1994019	5.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0765
Annotation	Glutathione
Peak:m/z	Relative Intensity
99.0491257	0.47
99.9330444	0.12
102.0413132	0.05
112.9999695	0.15
115.8018036	0.33
119.9718170	0.09
125.1802902	0.09
128.0191650	10.88
129.9893494	0.10
134.9837189	0.11
142.9595337	11.46
145.0768738	0.27
146.0041199	2.15
153.1122742	0.30
155.0102844	0.20
159.9418030	14.25
165.9760437	0.44
167.1108856	2.04
169.1053467	0.15
169.9900665	0.13
171.1271973	1.36
176.9708862	8.47
179.0541992	17.13
185.1131287	2.11
192.2169189	0.12
197.0618286	1.41
201.0078735	0.05
202.8655701	0.22
210.1377563	10.58
211.1521606	0.07
213.0489502	2.32
215.4573364	0.09
224.1808167	0.04
228.2639465	0.47
231.1039734	1.44
233.1604919	0.06
234.1118774	0.07
236.0421753	1.59
237.1646423	0.05
242.1690369	1.95
244.1941528	0.21
248.2428589	0.12
254.1320190	100.00
258.8308716	0.25
263.0884705	0.18
272.1902466	95.97
288.0850220	44.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	673.3207
Annotation	Heterotropatrione
Peak:m/z	Relative Intensity
195.2214661	0.05
211.3765259	0.09
214.2601013	0.04
219.8495483	0.13
220.9257202	0.07
221.9683990	0.36
223.2675171	0.08
225.0838013	0.09
226.2661591	0.15
228.1784668	0.07
233.1997223	0.07
237.2886505	0.06
238.1499176	0.12
239.0964050	0.33
241.2714691	0.17
244.9619751	0.11
249.1892242	0.05
250.0804138	0.18
253.4583282	0.21
254.3542480	0.10
255.0630341	0.04
261.2285461	0.08
264.2661743	0.10
272.2274475	0.03
273.2173462	0.11
276.5487671	0.07
277.3944092	0.15
279.0501709	0.02
288.4884644	0.03
289.3801880	0.10
293.8692932	0.04
294.4924316	0.05
295.4324341	0.20
297.0085449	0.08
299.3751831	0.05
302.2237549	0.10
304.3243408	0.45
305.3945923	0.10
307.4401245	0.14
309.3859558	0.05
311.4816284	0.06
312.2930298	0.18
313.1578979	0.08
314.9849243	0.03
316.4738770	0.21
317.6413574	0.06
321.2785645	0.06
325.1533203	0.09
327.3126221	0.04
329.3401489	0.04
330.1417847	0.06
331.2415161	0.17
332.3925171	0.36
333.3580627	0.03
334.2551270	0.01
339.1239624	0.08
341.1514282	0.02
351.3417969	0.09
357.2811279	0.09
359.1480713	0.09
360.2510376	0.17
361.3121948	0.14
364.3350220	0.05
367.1185303	0.07
368.1514282	0.08
370.4433594	0.06
371.3657227	0.06
376.9872437	0.03
380.1823730	0.05
381.1152344	0.02
385.5919189	0.09
387.0655518	0.11
387.7806396	0.03
390.2837524	0.08
391.2968140	0.24
392.2961426	0.12
400.3320923	0.02
401.0257568	0.05
402.4187012	0.76
403.5531616	0.35
404.3965454	1.02
405.4310913	0.11
406.2097778	0.09
408.4453125	0.01
409.7674561	0.06
411.2766724	0.20
418.1633301	0.26
419.2354126	1.14
420.5050049	0.12
421.3280029	0.15
422.2034302	0.05
423.5260620	0.04
424.3240967	0.09
425.3467407	0.12
430.4215698	0.05
432.3740845	0.03
433.2967529	0.17
435.4784546	0.05
436.3453369	0.09
437.4127808	2.72
440.2463379	0.04
444.4963989	0.24
445.3081665	0.31
446.5497437	0.10
448.3622437	0.06
450.1488647	0.19
454.4809570	0.06
457.1538696	0.17
458.3312988	0.09
460.3983154	0.24
461.4047852	0.10
463.3107300	0.19
464.1993408	0.05
465.2704468	0.07
467.3186035	0.04
470.5941162	0.08
471.4913330	0.03
472.3889160	0.09
477.1635742	0.04
478.4685669	0.82
479.4528809	0.12
481.3696289	0.08
482.5623169	0.15
488.4449463	0.21
489.3910522	1.93
490.3856201	0.19
491.3679810	1.93
492.1771240	0.09
493.4498901	0.04
495.5820923	0.17
496.7228394	0.10
497.4146729	0.09
499.3388062	0.06
502.6567383	0.04
503.9631958	0.13
504.5885010	0.20
506.5598755	0.34
508.5699463	0.09
509.4727783	0.42
510.2647095	0.83
511.5034180	9.11
512.4928589	0.38
513.3353882	0.76
516.4345093	0.05
518.2493286	0.16
520.2888184	0.03
521.0374756	0.10
521.6713867	0.45
523.4478149	2.45
524.4325562	0.19
525.2709351	0.20
526.5032959	0.06
527.5518188	0.64
528.6389771	0.09
533.3352661	0.14
535.3881226	0.06
536.4350586	0.47
537.7282715	0.51
538.4802246	0.27
539.5657349	0.52
540.4338379	0.74
541.3454590	0.56
542.4354858	0.45
543.2938843	0.22
545.4571533	0.19
547.2399292	0.04
548.2801514	0.15
549.3099976	0.22
550.4982910	0.72
552.5613403	0.08
553.5053101	1.51
554.6530151	0.58
555.4492798	0.26
556.5379028	0.21
557.4089355	0.35
560.8760376	0.07
563.3499146	1.27
564.4053955	3.93
565.2852173	0.05
566.3670044	0.34
567.3461304	1.02
568.7072144	0.62
569.8557739	0.27
570.5927124	0.17
571.6364136	0.25
573.2227783	0.05
579.4884033	0.70
580.1798706	0.03
581.4257202	0.81
582.3576050	4.15
583.4110718	0.64
584.4105835	12.03
585.5031128	4.68
586.3524780	0.39
587.5563965	0.06
588.8840942	0.28
591.4912720	2.18
592.4695435	0.33
593.2997437	0.06
594.6680908	2.12
595.3971558	24.41
596.4165649	10.56
597.4205933	0.47
598.4009399	0.20
599.7672729	0.97
600.4725342	5.17
601.4462891	0.47
602.4917603	0.72
603.3851929	0.05
605.5125122	0.84
606.5267334	0.22
608.4092407	0.60
609.4879150	1.41
611.1656494	0.20
612.5548096	0.26
613.4613037	8.03
614.3737183	0.92
615.6822510	0.32
616.5111084	0.32
623.4837036	25.27
624.5948486	0.60
625.7688599	0.16
626.4448853	3.74
627.4572754	1.10
628.5321655	0.12
629.4405518	2.02
630.4395752	1.39
631.3019409	0.24
637.4192505	0.62
638.4574585	0.05
641.4757690	10.55
642.5519409	0.68
644.5018921	2.12
645.6536255	0.38
655.4265747	100.00
656.5123901	3.29
658.4397583	9.36
659.6290894	0.11
674.4436646	14.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.267
Annotation	Orthosiphol U
Peak:m/z	Relative Intensity
237.2677917	0.02
238.9888458	0.10
239.8801422	0.04
250.1895142	0.02
264.2637024	0.05
281.3049316	0.04
284.8973389	0.04
286.3994751	0.03
297.3160400	0.30
311.2819824	0.21
312.4192505	0.05
316.2487183	0.03
327.3120728	0.02
331.2367554	0.02
337.1716309	0.03
371.2561646	0.22
372.3317261	1.72
373.3776855	0.77
384.3046265	0.22
385.2537842	0.11
402.1754761	0.02
404.2796631	0.17
405.3101196	0.06
415.1279297	0.05
415.9139404	0.02
416.7766113	0.25
418.2938232	0.20
428.3748169	0.24
429.2886963	0.04
432.3336182	0.65
433.3305054	0.39
434.3247681	0.02
444.1222534	0.06
446.6058960	1.67
447.3823242	4.04
448.2973633	0.88
449.3795776	0.02
452.6318359	0.06
459.1801147	0.19
460.4530640	0.11
461.2688599	0.09
463.3502197	0.08
469.5524292	0.06
475.3287354	0.45
476.2692261	11.92
477.3991699	3.51
480.5228271	0.07
485.1528320	0.03
490.4381104	12.30
491.3030396	10.53
492.3922729	2.75
493.4170532	0.16
495.4972534	0.03
507.4191284	0.02
509.4211426	0.77
510.5401001	0.24
522.4163208	0.19
525.5189819	0.07
527.3992310	0.07
528.2017822	0.04
529.2090454	0.14
529.8946533	0.09
535.5263062	0.10
537.3277588	21.72
538.3419800	10.04
539.0024414	0.02
541.5294189	0.08
544.3128052	0.06
545.4124146	0.22
551.4740601	0.05
553.3129272	0.40
554.4747925	0.18
563.4292603	0.66
564.4607544	0.13
567.3751831	0.03
569.3087769	7.29
570.2219849	1.98
570.9511108	0.02
578.3847656	0.58
581.3399658	100.00
582.3201904	32.42
583.0238037	0.36
583.6436157	0.11
585.0850220	0.01
598.0518188	0.04
598.7207642	0.07
614.3811646	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2245
Annotation	Unknow
Peak:m/z	Relative Intensity
148.9450073	3.36
156.9529877	0.15
160.8505859	1.77
163.1781769	0.15
165.2476196	0.11
191.0220337	0.92
193.0924377	0.15
207.0611725	0.15
220.8222504	2.34
240.3545227	0.33
246.7404633	0.44
250.9310303	2.67
255.0813599	0.24
273.3988647	0.25
275.0462646	0.33
281.1351318	0.72
286.9541931	0.16
293.1033936	2.58
310.5797119	2.93
311.1901855	6.58
317.0765381	0.17
347.3279419	0.45
349.1915283	0.26
365.3732300	2.83
373.3262939	0.22
379.9895630	0.07
389.2966919	0.72
391.2313843	0.28
392.4298096	0.42
403.5427856	0.62
423.1594238	0.14
430.2817993	0.76
447.1970215	0.17
450.4625854	0.28
463.1834717	100.00
463.8720093	0.93
465.2036133	0.40
473.3301392	0.49
479.3050537	0.32
491.3705444	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2658
Annotation	Ariakemicin A
Peak:m/z	Relative Intensity
199.0271301	0.05
237.3388977	0.08
253.0771484	0.15
283.0411987	0.35
288.3769531	0.04
299.1849976	0.23
301.1991577	0.03
306.4984741	0.18
325.2299805	0.16
329.1758423	0.26
339.2097168	0.08
342.0579224	0.24
343.6121216	0.18
345.8011475	0.05
353.4700928	0.15
359.1506348	0.40
381.1399536	0.09
395.4443970	0.06
397.4934692	0.12
398.0970459	0.13
405.2090454	0.20
407.3959961	0.05
413.6662598	0.15
425.3643799	17.45
427.1821289	0.20
439.3027344	0.13
445.7272949	0.08
447.3452759	0.11
449.3422241	0.20
451.2899780	0.06
466.9566040	0.47
469.3533936	15.29
470.1333008	0.04
473.7608032	0.19
485.3674927	2.39
487.2908325	0.22
499.0054321	0.10
502.5789795	0.17
503.4370117	0.13
505.3897705	0.20
508.8117065	0.19
516.5765381	0.05
517.2947388	0.23
521.2824097	1.50
527.3924561	0.07
529.2817993	100.00
529.9315796	0.31
530.6224365	0.15
539.4448853	0.19
541.3500977	0.27
542.4488525	0.15
543.4678345	0.14
544.8833618	0.38
545.5946655	0.14
547.2399292	0.10
552.1177979	0.21
558.2256470	0.07
559.7041626	0.08
563.3024292	0.19
570.2792969	0.55
571.4421997	0.38
590.3129272	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	755.24
Annotation	Sibiricose A4
Peak:m/z	Relative Intensity
210.9680634	0.18
229.0481873	0.16
239.2844391	0.08
255.3486938	0.11
256.8897095	0.60
258.0820923	3.81
269.2208252	0.08
285.0523071	0.08
286.1432495	8.81
301.0981750	100.00
311.1421814	0.04
313.2012024	0.22
325.3520508	0.36
343.2376099	0.53
367.2197266	0.88
396.9324341	0.10
400.5817871	0.05
409.4067383	0.04
411.1108398	1.48
429.2127075	1.14
445.1381226	0.31
447.0535278	1.68
459.2371216	0.06
463.0961914	8.24
471.5123901	0.06
475.3097534	0.06
489.0441284	0.19
539.0668335	0.11
573.2482910	0.28
591.4071655	0.25
593.1271973	0.36
609.1471558	79.15
609.8663330	0.36
617.4937744	0.21
737.2429199	0.12
755.1773071	3.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	357.0809
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
105.0110321	0.04
109.0537109	0.06
117.0592346	1.11
119.0340347	0.08
131.2440338	0.09
136.0258026	0.10
142.0582581	0.06
145.0052185	7.79
146.9941864	9.47
152.9592285	0.12
157.2622375	0.06
158.1074982	0.08
162.9935913	0.08
164.8665466	0.24
167.1062317	0.19
168.1478271	0.14
172.8238373	0.49
174.2354584	0.24
174.9378204	0.26
177.0227966	100.00
177.8217316	0.09
179.1508026	0.26
183.9988098	0.04
185.9611816	0.20
188.2236938	0.03
193.4488373	0.15
194.0661163	0.33
195.1663513	0.28
199.0527039	0.13
205.1224213	0.29
208.0800171	0.04
213.2806702	0.07
217.1268311	0.13
220.8425598	0.14
231.0983276	0.20
233.2215271	0.09
235.3125916	0.20
236.0697327	0.10
238.2709961	0.18
241.2564087	0.26
243.0897522	0.10
248.1950378	0.20
252.3491821	0.14
255.2024536	0.13
264.1542358	0.09
264.8781738	0.29
266.6832581	0.21
267.8353882	0.11
268.9045105	0.41
270.9497681	0.07
273.0090332	0.16
273.9743042	0.04
275.1133423	0.74
276.6080933	0.04
278.7703247	0.05
280.0749512	0.11
281.1937866	0.13
285.5733337	0.08
291.2295837	0.20
294.6405640	0.20
297.0774231	0.38
298.4149170	0.07
299.0657654	0.18
303.2615356	0.18
309.1310120	0.16
311.1105347	1.17
312.0915833	0.31
313.8393555	0.24
316.5458374	0.25
321.4188232	0.03
325.2550659	0.34
327.1620483	0.56
328.3213501	0.22
329.5261841	0.07
338.1063538	0.78
339.0229492	4.60
340.1877747	0.50
341.0920105	0.03
347.9401245	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1802
Annotation	Spinosin
Peak:m/z	Relative Intensity
205.1913452	0.01
243.0075073	0.06
259.3068542	0.01
282.0620422	0.03
286.0819702	0.05
287.5220337	0.05
301.0810547	2.73
302.1864014	0.46
303.0772705	0.04
304.2338257	0.03
310.2819214	0.01
313.1853638	0.76
314.1656494	0.17
315.1674194	0.01
325.1671143	0.74
326.3118286	0.28
328.2839355	0.09
329.2263794	0.04
331.2908936	0.01
332.2977295	0.02
337.3136597	0.06
338.0314941	0.02
339.2267456	0.03
340.4605103	0.01
341.3689575	0.02
343.1431885	7.30
344.2501221	1.47
345.8323364	0.09
346.4478149	0.01
353.3516846	0.05
354.9856567	0.08
356.2100830	0.03
358.8648071	0.04
361.2655029	1.46
362.2680664	0.29
367.1638184	2.50
368.2538452	0.84
373.4891968	0.01
379.0200195	0.02
381.2675781	0.07
385.3652344	0.15
386.1338501	0.01
391.1931152	0.04
392.1565552	0.05
397.1394653	3.59
398.2113647	0.70
409.2264404	1.50
410.3364868	0.32
416.2375488	0.03
422.2191772	0.01
426.1512451	0.01
427.2540283	3.08
428.2135010	0.96
429.2257690	0.04
430.1956787	0.05
434.3320923	0.07
436.3848877	0.01
445.2116699	20.48
446.2155151	4.97
447.2093506	0.19
447.8328247	0.02
448.5826416	0.01
453.2235718	0.04
454.2888794	0.02
457.1522217	0.01
463.1763916	100.00
464.1485596	22.47
464.8516846	0.03
471.2470703	0.18
481.3607178	0.03
487.2803345	0.26
489.1320801	1.00
490.1384888	0.07
491.3352661	0.08
503.6262817	0.01
505.4509888	0.02
506.4340210	0.02
511.2692261	0.06
512.7592163	0.03
513.3980103	0.05
514.2046509	0.01
517.2764893	0.05
519.1001587	0.01
528.3584595	0.06
529.3198853	0.06
530.3064575	0.08
537.3510742	0.04
543.9987183	0.03
547.2821655	0.13
548.2877808	0.08
551.4909058	0.03
555.3838501	0.25
556.3779907	0.15
560.3362427	0.03
564.2236938	0.07
565.3133545	0.07
566.2169189	0.01
573.3240967	0.31
574.4413452	0.04
591.1769409	1.95
592.2039185	0.51
592.8309937	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.17
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
267.3890991	0.10
313.0057678	0.19
325.2019653	0.02
337.1899414	0.12
339.2083435	0.16
343.1528931	0.17
355.2005615	1.78
367.2144775	1.75
379.3082275	0.33
381.2473755	0.20
385.2537842	5.35
391.2785034	0.35
397.0068359	0.04
405.3743286	0.04
409.2337036	3.07
415.1683350	0.13
421.1876831	1.69
423.1550293	0.18
427.4008179	0.09
433.1466064	0.53
438.5165405	0.35
439.1492310	4.51
445.2704468	0.48
451.2493286	4.13
456.9751587	0.46
463.3294067	0.37
469.1579590	3.50
470.0621948	0.16
471.1159058	0.14
475.1876831	0.39
476.0684814	0.06
481.3150635	0.18
487.2011719	63.32
493.0287476	0.17
499.1190186	0.12
505.1054077	3.31
511.3055420	0.92
517.2381592	0.19
519.0537109	0.10
523.2339478	1.87
525.2352295	0.28
529.3344116	1.11
531.2944946	0.57
535.1873169	0.28
537.3150635	0.12
541.3067627	3.31
543.2577515	1.51
547.2667847	0.28
548.3184204	0.07
549.2432251	0.74
553.2917480	2.20
555.1395874	1.33
559.2872925	1.09
561.1339111	1.56
564.9456787	0.45
565.7149048	0.08
571.2986450	1.15
573.3086548	10.61
576.7232056	0.10
577.4670410	0.31
579.4032593	0.31
583.3151245	1.13
585.1492310	0.07
589.2554321	0.79
591.2941284	22.37
595.1558228	1.04
597.2922974	6.98
597.9263306	0.03
607.0011597	0.27
609.2656250	0.28
613.3013916	1.64
615.2931519	13.37
621.3473511	0.31
625.2496338	0.26
627.1843872	19.93
627.8336792	0.04
631.4293823	2.00
639.3123779	9.63
645.2031250	22.20
645.8634033	0.11
649.2670898	1.44
657.2098999	19.10
657.8422241	0.10
667.3267212	0.13
675.2720337	38.62
693.1973877	100.00
693.9246216	0.10
696.1736450	0.13
711.1640015	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1769
Annotation	Tryptoquivaline I
Peak:m/z	Relative Intensity
142.9367676	0.07
143.8633270	0.14
148.9687042	0.14
150.9799805	0.03
159.0273743	0.14
160.8698730	0.01
161.8571777	0.04
163.1591492	0.19
165.0896912	0.15
171.3713379	0.03
173.2243652	0.12
175.1173248	0.18
177.1470795	0.04
183.0293884	0.20
184.9959717	0.18
187.2199097	0.08
189.1493530	0.04
190.9604797	0.29
192.8914032	0.03
197.6201782	0.01
199.1716919	0.09
201.1940308	0.13
203.1149292	0.36
205.0640564	0.18
207.0371399	0.04
209.0512543	0.22
211.3406372	0.21
213.2706451	0.69
214.1640625	0.05
215.2035980	0.05
219.3393555	0.04
221.9069977	0.05
223.1152954	0.11
225.2505798	0.11
227.0045929	0.28
229.1229248	0.30
231.0578003	0.07
233.2508240	0.42
236.2439880	0.04
237.4021149	0.04
238.3683624	0.07
239.2000427	0.66
240.2171783	0.09
241.3265686	0.47
243.0819092	0.06
247.0700684	0.19
249.3952332	0.22
251.2420197	0.61
254.1928101	0.08
255.1737976	0.95
257.2421570	0.03
263.2586975	0.49
265.3097229	0.50
267.1252136	0.41
267.9936829	0.07
269.1539612	1.17
271.3069153	0.07
273.3384094	0.02
274.4232788	0.03
275.3212891	0.17
278.1221313	0.25
279.0172119	0.02
281.0649719	0.13
283.2373962	0.76
285.0785522	0.20
289.2686157	0.12
291.3678589	0.14
293.2565002	1.05
294.3577576	0.03
295.3846130	0.14
297.2970886	0.01
298.1847534	0.09
299.4709473	0.07
301.1997375	0.22
305.2962646	0.03
307.3050842	0.18
309.3450012	0.51
311.2155457	0.66
311.9625244	0.03
313.4585266	0.11
315.3183594	0.20
317.2670288	0.06
321.3656616	0.05
321.9658813	0.06
323.4394226	0.10
325.3014221	1.04
327.1636658	2.02
330.1611633	0.07
331.1013184	0.02
333.2561951	0.19
334.9343262	0.03
337.1657104	0.03
338.2908936	0.38
339.1722412	0.38
341.2751465	0.63
343.1572876	0.45
345.3385620	0.54
351.2991333	1.59
352.3403931	0.42
353.3591919	1.83
354.5369263	0.52
355.2623901	0.57
357.3795776	0.10
365.2907715	0.17
367.3192749	4.63
369.2760010	2.73
371.2559204	5.34
379.5289612	0.06
383.2841492	0.42
385.2057495	0.59
385.8704529	0.06
387.2468872	0.68
389.3470764	0.48
393.2396240	0.08
395.3600464	7.51
396.4828796	0.02
397.4141541	0.12
398.5057068	0.78
401.6593933	0.06
403.1571350	0.11
407.8186951	0.07
409.2836609	0.02
411.3848572	0.63
413.3415222	11.76
415.2163696	0.20
425.1889343	0.03
429.3483887	2.69
439.2305298	1.32
441.4663696	0.05
454.8739319	0.26
457.2037048	100.00
457.8381348	0.17
459.1284485	0.05
462.2967834	0.04
463.5425110	0.06
465.2810669	0.09
471.3051147	0.04
473.2438049	0.23
482.3179016	0.03
483.2776184	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1157.2987
Annotation	Unknow
Peak:m/z	Relative Intensity
328.2857361	0.07
331.0870667	0.11
345.1081543	0.06
361.1705017	0.19
375.1592102	0.25
375.9299927	0.12
667.1824951	0.08
723.0625000	0.08
724.4762573	0.10
760.9533691	0.08
775.3992310	0.11
790.2202148	0.11
791.0994873	0.05
793.5429688	0.14
807.3599854	0.20
808.1773071	0.11
809.6259766	0.15
825.1968994	0.11
827.3898926	0.26
1157.1843260	100.00
1158.2932130	17.71
1159.0860600	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1824
Annotation	Hesperidin
Peak:m/z	Relative Intensity
175.0805969	0.11
176.9890747	0.43
185.1580658	0.03
193.1560364	0.06
198.0794067	0.02
198.9163971	0.18
200.9168396	0.17
211.1474609	0.11
214.2463074	0.04
215.2153473	0.19
226.9555359	0.03
230.172226	0.10
240.1036682	0.08
241.1949158	0.12
241.9944305	0.28
251.0447083	0.14
258.1528625	0.19
268.9746094	0.04
275.2322693	0.20
286.1558228	0.23
299.1671143	0.09
301.0828857	100.00
302.1045532	0.15
303.1073608	0.16
323.265686	0.03
324.2776489	0.11
325.1779785	1.43
328.1000977	0.02
343.0908203	1.17
357.3579102	0.04
367.2336426	0.32
369.2770996	0.04
384.2541504	0.08
387.3029785	0.03
409.8400269	0.03
417.0988159	0.14
428.2067261	0.10
430.8416748	0.03
443.302002	0.37
444.253418	0.56
459.1010132	0.91
463.130188	0.52
464.2680664	1.04
465.1578979	0.70
474.1169434	0.03
489.222168	0.15
505.8677979	1.08
506.571228	0.08
518.3285522	0.05
523.22052	0.06
528.2232056	0.13
541.6021118	0.16
546.2954102	0.19
547.9789429	0.04
565.2098999	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.234
Annotation	Ajugapantin A
Peak:m/z	Relative Intensity
173.0928497	0.21
185.2087708	0.42
186.5298157	0.17
187.1549988	0.19
191.0492096	0.40
195.0653076	0.12
201.2246399	0.09
203.1335144	1.63
205.9373474	0.29
216.2383118	0.16
217.2165985	0.39
220.6975403	0.18
224.1821289	0.07
225.2676697	0.38
227.1180267	0.19
229.1397247	0.49
231.2020416	1.53
239.0254211	0.22
242.1612549	0.23
243.2225342	0.82
245.2843475	0.97
245.9917145	0.05
246.8514099	0.07
248.8446045	0.50
254.8863220	0.10
257.1691895	1.26
259.1046753	0.96
261.2877502	2.40
269.3965454	0.14
271.2098389	1.48
277.4082642	0.37
279.2230835	0.25
281.4025879	0.11
283.1397705	0.68
284.1635132	0.10
287.6240845	0.13
289.1613464	3.45
295.2333984	0.17
297.3474731	0.18
298.4486084	3.88
299.2840881	6.03
309.2236938	0.80
311.3555908	0.65
313.3070679	1.56
315.1755371	3.65
325.3044434	0.84
329.3171997	0.29
331.3283691	0.17
333.1165771	55.19
335.1616821	0.07
337.1428223	0.11
338.2947388	0.08
339.0487671	0.35
339.7180786	0.13
341.1262817	2.48
349.6190186	0.08
351.4426880	0.08
353.2041626	4.27
355.3970337	0.98
357.3002930	6.10
363.3735352	0.34
365.2259521	1.67
367.3830566	0.81
371.1451416	1.53
373.0716553	1.85
377.2442017	1.64
381.1409912	0.93
381.7457275	0.30
389.1779785	14.44
389.8467407	0.12
391.1882935	1.44
393.4382935	0.71
395.1632080	0.12
401.4364014	0.23
409.2844849	4.26
411.3705444	22.27
413.4785767	0.08
424.8941650	0.20
427.0513306	0.52
428.5093994	4.09
429.1955566	33.86
435.1499634	2.59
435.9563599	0.07
439.3825073	0.15
441.3635864	0.06
446.3529663	0.14
449.0874023	0.10
453.2495728	9.00
455.3461304	0.23
457.2595825	1.43
467.2986450	33.30
467.9238281	0.48
471.3286743	10.66
485.2612305	88.78
491.4603882	0.09
501.7059937	0.41
502.7500000	0.78
503.6072388	0.04
505.5757446	0.12
517.2157593	100.00
517.8374023	0.28
534.0797729	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1722
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
197.0570068	0.03
224.9205780	0.03
245.2345886	0.03
257.0994263	0.23
260.2275391	0.04
270.2971191	0.02
283.0048828	0.06
286.0039673	0.06
298.3391113	0.04
301.1934204	0.08
305.0473938	2.87
308.0288696	0.05
311.2579346	0.17
312.0477295	0.08
314.2373657	0.10
315.1349487	0.28
318.3542480	0.04
323.0938110	0.07
325.9555054	0.16
329.1369324	3.86
330.1613770	0.91
343.0698853	0.55
344.1658936	14.87
345.2437134	2.90
346.0005493	0.03
351.2354126	0.07
351.9958496	0.03
354.1235352	0.08
355.2747192	0.13
357.1590576	0.40
358.6561890	4.09
359.2622070	48.43
367.2342529	0.04
369.2533569	0.27
371.1388550	0.06
373.2984619	0.05
381.1546631	0.36
386.0622559	0.28
387.4429321	0.52
401.0702515	3.52
401.7008057	0.06
410.2710571	0.26
413.3055420	0.05
419.1828613	0.06
425.2191162	0.34
427.3850098	0.06
461.4598389	0.07
465.1133423	0.02
471.4958496	0.08
474.3837280	0.11
475.4133301	0.05
479.4038696	0.18
485.3144531	0.10
489.0438843	0.28
503.3682861	1.69
506.3941650	0.62
507.2594604	1.03
521.1974487	100.00
521.8665161	0.28
532.6395874	0.06
534.1728516	0.36
540.4166260	0.12
543.2048950	0.13
544.9484253	0.06
548.3450317	0.26
549.2402954	6.53
563.2320557	68.90
563.8417358	0.38
589.2260132	0.93
591.1679077	0.35
593.3628540	0.25
603.2382202	3.97
605.2803955	0.27
615.2564697	2.28
619.8632812	0.03
621.6599731	0.03
623.4666138	0.04
633.2120361	0.65
635.4498901	0.10
643.4746704	0.09
646.3799438	0.08
647.3892212	0.66
650.1868286	0.34
665.1669312	4.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1542
Annotation	Vicenin 1
Peak:m/z	Relative Intensity
208.3569794	0.05
218.4217529	0.09
242.9073944	0.09
270.1393433	0.12
271.0643921	0.94
283.1034546	1.20
286.0359497	0.07
295.0171509	0.73
307.1918335	0.07
313.0964355	9.32
317.1343994	0.02
325.1338501	0.02
337.1441040	4.74
343.3355713	0.14
349.2886963	0.03
351.1729126	0.20
361.0794678	0.18
367.0850220	8.03
367.6866455	0.06
379.1588135	1.67
385.0357666	0.06
387.3770752	0.26
397.1913452	5.00
402.4849854	0.06
403.3374023	0.19
409.1713867	0.04
415.1408691	23.79
415.7573242	0.12
417.2158203	0.42
421.0842285	0.04
425.4224243	0.07
427.1390991	0.05
433.1481934	100.00
433.7690430	0.44
445.0781860	1.53
453.2684937	0.05
499.0053711	0.05
505.3527222	0.01
515.3929443	0.04
522.1526489	0.11
529.0763550	0.30
533.1815796	0.05
547.1705933	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.1862
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
200.2838287	0.07
258.1536255	0.14
268.1692200	0.28
284.9249878	0.06
286.1951904	0.17
287.0613708	0.56
288.5115967	0.24
311.1813965	0.09
313.0574951	0.17
314.2907104	0.07
343.3741455	1.84
345.2749023	0.17
346.4661865	0.05
347.2459106	0.05
373.2896729	10.52
385.8842163	0.43
389.2743530	0.11
395.3880005	0.41
397.2377930	7.67
403.3667603	0.30
409.3760376	0.38
413.2607422	0.08
416.4960938	0.07
417.8913574	0.09
421.2783813	0.92
427.2510986	8.44
439.1129761	5.17
444.2923584	0.16
454.1511841	0.77
455.2449951	0.73
457.2280273	8.03
461.7313843	0.18
472.3748779	0.21
475.2517700	23.49
479.2364502	0.09
493.1173706	2.28
505.1956177	1.69
507.6768188	0.23
508.3257446	0.09
509.1211548	0.17
535.1296997	22.69
536.0714722	0.24
538.3222046	0.26
559.1985474	16.69
562.4514771	0.06
564.0986938	0.13
571.2052612	0.13
575.1143188	0.21
579.3302612	0.16
580.2737427	0.16
581.6004028	0.08
583.0235596	0.47
583.6392212	0.04
589.2327271	54.32
600.0567017	0.15
601.1671753	10.05
609.4105835	0.28
610.2815552	0.17
619.2696533	18.67
632.2018433	0.10
637.1354370	100.00
637.8464355	0.48
638.4613647	0.56
644.4312134	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0717
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
130.2707062	0.04
138.7243958	0.05
142.9250488	0.03
144.8902588	0.05
151.077179	0.04
155.1211548	0.03
169.0115051	0.03
173.9632111	0.10
183.1087952	0.11
184.954483	0.14
192.9263916	0.91
195.0864563	0.02
197.2742462	0.33
197.9991608	0.04
198.9517822	0.42
204.1689148	0.06
209.2324829	0.12
211.0415649	0.03
213.2270813	0.11
214.3981323	0.09
215.2056274	0.02
217.0115967	0.05
223.2242737	0.07
224.017395	0.01
224.9152527	0.05
227.0353088	0.04
228.7284241	0.14
235.4730835	0.11
237.2825623	0.03
239.0316772	0.08
241.3111267	0.35
242.2372742	0.02
243.1513367	0.04
249.1689758	0.05
250.6985168	0.10
251.3075562	0.51
253.0828247	0.12
254.0924072	0.14
255.2627869	0.32
256.8395081	0.06
267.0612488	0.97
268.4341125	0.34
269.2683105	0.98
270.0790405	3.03
270.7559204	0.01
277.2276306	0.13
281.2076416	0.14
282.5095825	0.53
283.1559143	2.89
285.1470642	5.29
293.3689575	0.20
294.2124939	0.09
295.186554	3.50
295.8968201	0.10
298.0505981	100.00
299.0064087	0.12
305.8706055	0.08
313.3685608	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.0987
Annotation	Deacetylasperuloside
Peak:m/z	Relative Intensity
110.3726883	0.05
111.1117325	0.14
114.9406281	0.10
117.0957260	0.11
119.1250458	0.11
128.9750061	4.91
130.9796448	0.09
133.9742432	5.19
140.8847961	0.12
148.9869690	4.18
159.0299988	2.06
160.8563538	0.31
174.9858093	0.48
177.0562439	11.20
178.0227356	4.03
191.0030365	0.10
193.0233765	100.00
194.9999390	53.46
203.0897064	0.03
207.1560364	0.12
209.2459717	0.04
221.2669067	0.13
232.9635925	0.03
235.1893921	0.64
251.1961670	0.24
261.2189026	0.05
264.9825439	0.35
275.0432129	0.33
276.9997253	0.18
290.0895996	0.03
324.4748840	0.05
325.0770874	0.62
335.0861816	0.19
339.1334229	0.40
353.2280579	2.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1518
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
178.8395538	0.07
201.1563721	0.08
211.2939148	0.04
221.8729858	0.05
236.9559326	0.04
239.1586304	0.08
268.1837769	0.05
269.4252319	0.03
281.0197144	0.03
283.2125244	0.38
284.4409180	0.39
285.1107788	1.25
287.4019775	0.04
294.2196045	0.02
295.3377991	0.21
297.1666870	1.21
298.0839233	1.99
299.1725464	0.32
301.0933533	0.06
309.1585083	13.83
311.1508179	2.77
312.3319092	0.04
313.1526489	0.07
320.9821777	0.14
322.3798828	0.16
323.0939941	0.05
324.5335083	0.13
325.3063354	0.54
327.0948486	11.57
329.1463623	0.03
335.2008667	0.21
337.2041016	1.14
339.1798706	11.13
341.1464233	1.11
349.1039429	0.31
351.2400513	3.19
353.2132568	6.52
355.2937622	0.43
355.9675903	0.02
357.2266846	21.59
363.2797852	0.02
365.3330078	0.09
367.2694702	0.45
369.1984253	4.82
371.2706909	4.57
375.2191772	0.04
377.1196899	0.08
379.0520630	0.07
381.2379150	1.10
383.2274780	4.90
385.0702515	0.32
386.2523193	0.08
387.2752686	0.68
392.5314331	0.10
393.2254028	1.61
395.2015381	0.27
397.1717529	0.24
399.2388916	1.03
400.3417358	0.05
406.9119873	0.09
411.2277832	4.19
413.2732544	0.59
417.0983887	0.07
419.0924683	0.14
423.4149780	0.03
425.2223511	0.24
427.0399170	0.07
429.2133789	40.75
430.0584106	0.28
431.1942139	2.35
437.2908936	0.14
445.3347168	0.08
447.1813965	2.68
448.2680054	0.09
449.1022339	0.26
455.2611084	0.89
459.1717529	0.04
463.2626343	0.05
471.3644409	0.05
473.2011108	100.00
473.8455811	0.19
475.4825439	0.08
483.4926147	0.02
485.1589355	0.66
497.5298462	0.09
503.2620239	4.55
511.3218384	0.02
515.3143921	0.49
517.5830688	0.03
529.2556152	0.29
530.0779419	0.05
532.3248901	0.02
533.2999878	0.44
539.4130249	0.02
545.3255615	0.21
546.3788452	0.03
548.3214722	0.02
548.9411621	0.03
556.9214478	0.04
575.3121338	4.65
577.2429199	0.11
593.2684937	0.60
594.2757568	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	753.2257
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
282.9647827	0.04
301.1334534	3.40
314.8491211	0.02
325.3769531	0.18
328.0999146	0.06
343.1248779	0.70
343.7846680	0.03
355.3548584	0.05
409.0990601	0.12
423.1519165	0.07
426.9177856	0.07
445.2158203	0.20
447.1654663	0.27
463.1524658	0.02
464.4376221	0.04
489.0836792	0.57
506.6345215	0.02
533.6855469	0.03
543.8336182	0.08
591.2203979	1.25
591.8640137	0.03
609.3358765	100.00
633.3339844	0.07
637.6105347	0.07
641.3418579	0.05
651.3520508	44.31
666.7225342	0.05
669.4295044	0.04
690.6722412	0.30
691.3152466	10.71
691.9349976	0.21
709.6409302	0.06
738.3621826	0.10
753.2310181	87.78
753.9589844	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0855
Annotation	cis-1,2-Dihydroxy-1,2-dihydro-7-hydroxymethylnaphthalene
Peak:m/z	Relative Intensity
58.8050003	0.01
105.0119629	0.11
114.9599915	0.10
120.9518433	0.01
133.0231628	0.90
137.3402557	0.03
142.9718933	0.02
146.6750183	0.01
156.4398041	0.02
160.9420013	100.00
163.1168671	0.01
174.7103424	0.03
175.9600525	0.03
178.0987701	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.1538
Annotation	Meteloidine
Peak:m/z	Relative Intensity
116.0262146	0.05
131.9564209	0.02
136.0664825	0.15
137.0208588	0.06
152.1371613	0.06
155.9622040	0.53
166.0591888	0.04
167.9531097	0.02
180.0597382	0.11
194.2386627	0.01
198.0337067	100.00
200.2552032	0.03
210.2543488	0.07
212.2602234	0.02
219.4028473	0.05
226.0309906	0.08
228.2566071	0.11
234.4921722	0.02
238.1188507	0.54
239.2904053	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0567
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
101.0194550	0.07
110.8751678	21.70
118.9469604	0.05
129.0328979	0.42
154.9135895	9.46
163.1712952	0.91
172.9995575	100.00
176.1866455	0.08
179.2825165	0.02
191.0597229	1.70
241.3360901	0.16
293.2697144	0.10
301.1483765	0.04
309.3596802	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	323.1349
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
94.7566757	0.74
96.8595123	5.56
100.8712311	53.67
106.6904144	4.95
112.9620209	100.00
118.9108124	74.25
124.9104843	8.23
130.9806519	18.25
142.9052734	52.61
148.7722168	8.39
149.3879089	0.38
160.8701630	25.92
178.4285889	6.41
179.0411072	22.20
181.0194855	1.62
185.1897888	1.13
187.0283356	4.04
226.8424377	0.73
243.0839539	0.94
277.3555298	2.13
304.0168457	1.28
305.0039062	0.89
307.9521484	3.10
309.1014099	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1719
Annotation	Unknow
Peak:m/z	Relative Intensity
139.1003571	0.11
143.0314178	0.20
148.9437256	0.05
150.7157288	0.02
159.0940094	0.07
160.8077545	0.18
175.1967468	0.36
178.9764557	0.68
180.1814575	0.06
186.1206360	0.07
190.7831116	0.02
196.7937164	0.02
201.0717621	2.79
201.6940155	0.01
219.1484375	2.52
222.3080444	0.03
235.2779388	0.03
237.1698608	1.36
239.3629456	0.06
243.1823425	0.03
244.8864441	0.03
261.2230835	0.10
269.4147644	0.06
273.3528442	0.06
279.2083740	0.15
290.3187256	0.11
291.1976929	0.06
299.2985229	0.02
300.1569519	0.19
301.2371216	0.03
303.1604004	0.12
305.3738098	0.04
309.2703247	0.23
339.0850830	0.05
355.2862244	0.18
381.4348450	0.16
399.1720276	100.00
400.0480652	0.33
410.4287415	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	775.41
Annotation	Angiotensin IV
Peak:m/z	Relative Intensity
231.1610260	0.04
247.5531464	0.08
248.6885986	0.10
258.2133484	0.03
270.6455078	0.16
280.3565063	0.29
290.6990051	0.22
319.4091492	0.02
320.4735718	0.24
323.8733215	0.04
325.5583801	0.72
327.3065186	0.05
329.2062378	0.04
333.3788452	0.36
334.2261963	0.22
334.9902344	0.07
336.0793457	0.57
337.7765503	0.06
339.7449951	0.07
342.8986206	0.12
351.5529175	0.05
361.2303162	0.42
362.4404297	0.02
363.3629761	0.05
368.7236938	0.02
373.9539795	0.26
375.0106201	0.23
376.0949707	0.39
381.3762207	0.04
382.7781372	0.06
383.4328613	0.19
385.3039551	0.05
388.3327026	0.65
389.2572021	0.36
390.0532227	0.88
395.8305664	0.12
397.1384888	3.05
398.3336792	8.04
399.4627686	0.83
400.3764648	0.03
401.1651001	0.07
409.3985596	0.29
410.3057861	0.06
414.5989380	0.16
415.2303467	0.03
416.4533081	0.02
417.8159790	0.12
418.4239502	0.29
421.2542725	0.02
429.3687744	0.07
437.1400146	0.33
446.2810059	0.13
448.2767944	0.05
450.4487915	0.06
455.2492676	0.04
460.7100220	0.02
462.4780884	0.16
463.4471436	0.06
464.2825317	0.48
465.4339600	0.16
469.3408203	0.05
470.0882568	0.04
471.2576294	0.13
472.4566040	0.03
475.4769287	0.10
484.2744141	0.05
485.3312378	0.26
486.7705688	0.06
490.5505981	0.06
492.3969116	0.51
495.1260376	0.03
499.3157349	0.10
501.5242920	0.50
502.3978271	0.06
503.3991699	0.94
504.4668579	0.04
505.3804932	0.09
506.4313965	0.07
510.4738159	0.27
512.4913330	0.08
514.4877319	0.07
515.3517456	0.06
516.5105591	0.33
517.4577637	0.07
520.3526611	0.12
522.4371948	0.63
529.3831177	0.05
530.3208008	0.07
530.9498901	0.14
531.6168213	0.07
532.6761475	0.16
534.4063110	0.04
537.4107666	0.04
539.3341064	0.02
542.5879517	0.05
544.3412476	0.08
545.7271729	0.09
547.4690552	0.04
549.5449829	0.12
550.5319214	0.14
551.5665283	0.54
552.2547607	0.17
557.4926147	0.08
558.5466919	0.15
559.5702515	0.19
562.5228882	0.43
568.7470093	0.05
570.1212769	0.21
571.4793091	0.04
574.4489136	0.34
577.4539185	2.91
578.5447388	0.07
583.3765259	0.05
584.8977661	0.07
586.2097168	0.09
587.9638062	0.03
589.3543091	0.03
598.5695801	0.29
600.4835815	0.51
602.3699951	0.25
604.5552368	0.24
605.4465332	1.37
607.8316650	0.07
608.6527710	0.17
612.6742554	0.14
614.2965698	0.21
615.6766968	0.13
617.3726196	0.24
618.4939575	0.72
619.3684692	0.05
622.5783081	0.07
623.4404907	0.14
626.2094727	0.45
627.0069580	0.12
627.6125488	0.26
628.8958130	0.11
629.7214966	0.38
631.6632690	0.05
633.6486206	1.21
634.6445312	6.14
639.3257446	0.22
641.5628052	0.17
644.9935303	0.14
645.6720581	0.13
646.6547241	0.66
648.7659912	0.19
649.3807983	0.23
650.4164429	0.62
655.4965820	0.17
656.2868652	0.04
660.5591431	0.48
661.6847534	1.12
662.4486694	7.41
664.4909058	6.34
665.6418457	0.18
669.4977417	0.06
673.6384888	0.16
675.3953247	0.75
678.6613770	0.22
679.5062866	0.17
682.6321411	0.09
684.3109131	0.06
685.4491577	0.05
686.9034424	0.03
689.6388550	0.11
690.5834351	3.14
691.7250977	0.04
696.6192017	0.14
701.7892456	0.15
703.6854248	0.06
704.6381226	0.14
705.8748169	0.03
706.5218506	0.19
712.3570557	0.55
713.4673462	0.60
714.4834595	0.33
716.8507690	0.21
717.9530640	0.31
719.2117920	0.33
720.6750488	0.15
721.8882446	0.24
722.6610718	0.10
723.5101929	0.12
724.5800171	0.63
725.8577271	0.16
726.7389526	0.05
727.9435425	0.03
729.7127686	0.83
730.5770874	3.48
731.6284790	2.48
733.0208130	0.26
733.6324463	0.08
736.3607788	0.13
737.3345337	0.10
738.5986328	0.04
740.1303101	0.08
740.8717651	0.04
741.6234741	0.05
742.3308716	0.11
747.5750122	100.00
748.6426392	5.41
752.1331177	0.07
752.9755249	0.34
753.6997681	0.30
757.8491821	6.54
758.5444946	33.65
759.6330566	3.00
760.5649414	0.20
761.6448364	0.36
762.8148193	0.04
765.9913330	0.09
775.6174927	29.10
776.5757446	45.44
777.4797363	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.2216
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
271.0560303	6.56
271.6794739	0.04
287.0179749	0.07
305.0209351	0.08
313.1454773	0.07
337.1285400	0.04
363.3110962	0.05
373.3405762	0.15
381.0427246	0.06
391.2456665	0.04
396.7780762	0.02
399.3721924	0.07
433.2044067	25.71
457.1464844	0.35
458.9828491	0.09
473.9959106	0.12
475.1482544	0.27
493.2064819	0.10
505.1621704	0.02
510.1241455	0.09
511.2770996	0.22
541.2899780	0.03
543.0945435	0.21
559.1478882	0.45
561.2079468	0.34
567.5332642	0.12
577.2072754	0.85
579.1585693	1.38
583.3915405	0.04
595.1311646	100.00
595.8539429	0.22
603.5328369	0.02
613.6530762	0.05
619.1633911	0.03
621.0178833	0.28
637.3348999	0.13
639.1939087	0.05
657.5161133	0.16
662.9987183	0.05
667.7196045	0.17
669.7357788	0.10
674.8645630	0.05
687.1074219	0.04
705.0361328	0.72
705.6926880	0.08
712.5705566	0.08
713.4736938	0.17
721.9716187	0.05
723.2880249	1.47
726.1661987	0.05
741.1527100	14.74
741.8663940	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3127
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
161.0574341	0.04
179.0087891	0.02
187.1972198	0.02
233.2359924	0.29
235.1403656	1.09
253.1797791	10.20
257.0173340	0.01
259.3424683	0.24
275.1896362	0.35
277.2363586	100.00
278.1030273	0.02
485.4010620	0.03
513.1162720	16.39
513.9763794	0.06
559.2378540	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1516
Annotation	Unknow
Peak:m/z	Relative Intensity
158.1768951	0.04
162.1381531	0.05
164.3255005	0.09
173.8987427	0.05
175.0121765	2.16
176.0645447	3.15
177.1604919	0.48
178.3148041	0.22
179.1944427	0.11
191.0901184	7.80
192.0834351	0.96
193.1402435	0.42
194.1053619	0.10
195.9968567	0.15
203.9853973	0.10
209.0057373	0.03
218.1526031	0.34
219.1247253	0.06
223.1430054	0.03
233.1303253	0.13
235.0518799	100.00
236.1386108	16.64
236.9166412	0.04
244.9733582	0.73
246.9676819	0.49
248.2499695	0.18
249.0944366	0.07
250.2545471	0.08
250.9967957	0.28
252.1539307	0.11
253.0730133	0.80
254.1697388	0.12
260.1683655	0.15
263.1097412	0.31
264.0780945	0.05
277.2672119	1.69
278.1541138	0.31
278.9339600	0.08
281.1287842	1.17
282.0390625	0.12
289.2732544	0.05
291.2666016	0.41
292.1627808	0.18
293.3263550	0.25
300.0263062	0.06
303.1337891	0.03
307.0493164	2.14
307.8515625	0.44
308.4542847	0.15
309.2924194	0.06
310.9858398	0.48
312.1022339	0.16
314.5642090	0.18
319.3930054	0.06
325.0202637	84.13
326.1230469	16.96
327.4277954	0.03
331.2561035	0.04
333.2351685	0.14
334.8819580	0.03
338.9225464	0.06
340.1918945	0.19
347.0314331	0.03
349.1734619	0.11
351.0938110	0.05
352.4853516	0.29
353.2258301	1.87
354.1670532	0.03
367.2794189	0.06
371.2088013	1.78
372.0028076	0.27
373.2930298	0.11
383.5950317	0.14
389.0581055	0.20
397.1071777	13.16
398.2371216	3.60
409.0590820	0.26
413.0220947	0.07
415.1276855	0.37
416.2722778	0.37
425.2516479	0.08
426.2126465	0.03
428.0641479	0.07
431.0481567	0.24
439.0504761	0.28
444.0908203	0.04
447.9364624	0.29
461.2036133	0.03
470.3247070	0.12
471.2416992	0.17
473.0910034	0.99
474.2059326	0.57
487.0316162	11.75
488.1283569	2.92
488.7529907	0.02
490.2127686	0.31
495.4180298	0.08
497.1599731	0.16
497.9916992	0.11
515.0972290	1.72
516.2055664	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.8525
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9840240	2.29
220.9559021	0.09
231.1791840	0.05
245.3446350	0.11
248.9687195	0.30
260.9596252	0.26
288.9378662	14.06
302.9875488	0.04
304.9821167	34.90
389.0551758	0.09
403.0071411	3.74
404.0664062	1.14
418.9766235	41.76
433.1184692	0.09
434.9292603	100.00
448.0391235	0.09
458.9956665	0.08
473.8408203	0.08
475.0789795	0.31
476.0960693	0.14
501.9090576	1.22
503.0076294	0.67
518.9327393	0.09
520.8856812	0.55
529.9848633	0.07
548.0886841	0.24
556.2858276	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.3647
Annotation	Denin
Peak:m/z	Relative Intensity
203.0923920	0.02
219.0270691	0.01
221.2431030	0.04
223.3092651	0.03
227.3154449	0.02
235.2000122	2.43
236.2279358	0.06
245.3297119	0.04
253.2268066	0.75
257.1912231	0.03
259.0355530	0.09
263.2080688	0.20
264.3370667	0.03
277.3843994	2.48
278.4404907	0.02
281.0489502	0.05
285.3398743	0.02
287.2200317	1.80
288.3574829	0.04
292.9901123	0.08
301.3435059	0.01
303.1428528	0.13
305.1752319	2.77
306.2752075	0.18
319.3273926	0.03
323.2474976	0.48
349.3192749	0.01
351.3872070	0.01
361.2274780	0.23
374.2181396	0.06
379.3328247	0.07
380.4283447	0.04
397.2483521	77.19
398.2859497	3.15
415.2879639	24.12
416.3683472	1.21
513.1972046	0.04
531.6181641	0.12
533.1871948	0.05
569.3694458	0.05
580.6162109	0.02
601.1400757	0.01
627.3186035	0.05
649.5244751	0.06
657.3529663	0.08
663.7367554	0.01
675.2892456	100.00
676.2553101	33.56
677.3092651	0.04
689.5819702	0.02
690.2220459	0.01
703.3804321	0.02
707.0127563	0.01
721.5101929	2.15
722.1449585	26.92
722.8471069	0.08
723.4706421	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.1846
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
204.8854828	0.01
212.8902435	0.03
252.9931641	0.03
270.8334351	0.01
272.2691956	0.01
289.0792236	0.01
300.0437012	0.08
308.3117065	0.01
312.3182983	0.02
315.1565552	0.03
315.9746704	0.01
318.2275391	0.01
328.2062378	2.20
331.1945190	3.75
335.1978149	0.02
343.1489258	0.03
346.1325684	3.93
353.0768433	0.02
360.0383301	0.05
361.1887207	100.00
362.1508789	0.03
396.2074585	0.03
403.3145142	0.01
427.1922607	0.04
469.3354492	0.06
523.0255127	0.07
544.3421021	0.04
585.1096802	0.02
587.0372925	0.04
595.2966309	0.03
598.1483765	0.03
605.1929321	0.47
649.2803345	0.56
668.4848022	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	405.175
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
120.9926147	6.53
122.7996063	0.05
126.9234467	1.76
128.7056580	0.33
132.0383759	0.13
133.3171082	0.17
133.9946899	0.16
136.9455261	0.74
138.9318085	16.45
140.9719696	0.59
144.9813995	1.36
146.9904480	0.24
148.9787750	0.11
150.8139648	0.56
157.0162811	100.00
157.7918091	0.09
158.9650574	0.21
161.1294861	0.11
162.9996185	0.43
164.7003174	0.11
173.1045227	0.26
175.0630798	0.40
177.0876465	0.57
178.6699524	0.11
181.1126251	7.35
182.5380554	0.15
187.2664490	0.60
188.9507294	1.01
193.1406097	2.09
196.8314514	0.61
198.9535675	1.76
200.9869385	0.51
201.9064026	0.25
205.0341492	0.32
207.0823975	0.51
208.0705261	0.11
208.8251038	0.33
212.9818420	0.34
215.1914825	0.30
216.9289551	0.46
219.2683563	0.15
221.0629272	0.10
223.1306458	3.93
224.8145294	0.90
225.4278564	0.03
226.1079407	0.26
227.2977295	0.32
229.2271729	0.85
230.8543396	2.98
232.9797058	0.13
234.1009216	0.14
238.9904175	0.25
241.1440430	1.14
242.8365784	0.06
247.0680237	2.29
248.9534607	0.63
255.1907349	0.16
263.9541931	0.09
265.1662598	3.01
268.0443726	0.13
273.0889893	0.16
274.2777405	0.23
280.0654297	0.32
281.1510010	0.07
283.0570679	0.46
287.1314392	0.16
288.8424683	0.23
292.9815369	0.07
297.9844971	0.18
300.2105713	0.24
300.8668518	0.08
305.3327026	0.22
309.4497070	0.14
314.3969421	0.18
315.2015381	0.39
319.1974792	0.29
324.1989441	0.44
325.0682678	0.30
328.2146606	0.31
329.1638184	0.04
333.0107727	1.13
341.2679138	0.18
343.1982727	0.47
345.2733154	0.30
348.3005066	0.42
349.3066711	0.11
350.1821594	0.32
351.2592468	3.51
355.4862366	0.47
358.0192871	0.17
359.1552124	0.53
360.2935181	0.42
362.2265625	0.20
364.0572205	0.12
369.1025391	6.95
372.0097046	0.28
373.1972351	0.05
375.0681763	0.10
376.9609680	0.60
383.3298950	0.04
386.4574280	2.52
387.2148438	20.80
390.0313416	0.75
391.3258362	0.35
393.9976501	0.14
395.8760681	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	314.0435
Annotation	Unknow
Peak:m/z	Relative Intensity
109.9980927	0.03
124.1143112	0.01
138.1230774	0.05
152.2346344	0.04
159.9863281	0.02
165.1432190	0.06
165.9988708	0.25
167.0310364	0.04
175.1829529	0.01
176.0242157	0.01
179.0122375	0.13
180.1382446	0.17
184.2048035	0.03
192.9538727	0.12
194.0665588	0.19
195.0848389	0.30
196.1279755	0.02
199.2220459	0.04
202.2766418	0.03
208.0246887	0.14
211.9231262	0.04
213.3475037	0.03
214.0064087	0.01
216.0726013	0.01
222.9721680	0.03
224.1839294	0.13
224.7954407	0.03
226.9963989	0.06
228.2557373	0.01
230.2123108	0.04
239.1737366	0.20
240.1120911	0.53
241.1293945	0.07
242.5133362	0.01
243.1505737	0.12
244.2189941	0.05
251.1247559	0.02
252.1716919	0.02
255.3450623	0.06
256.1043091	0.10
257.0090332	0.15
258.2041016	0.07
259.2348328	0.03
267.0587158	0.19
268.1667786	0.58
269.0554199	0.06
271.1512451	0.09
281.4744263	0.01
283.2467651	0.35
284.2142029	0.27
285.2110596	2.17
286.0897217	0.53
286.7102356	0.02
296.1314087	26.86
297.2677002	0.08
299.0813293	100.00
300.0802002	0.03
314.0567017	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3382
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
166.0420380	0.42
184.0496521	100.00
184.8368530	0.03
197.2416077	0.02
205.2252960	0.05
258.0084229	0.46
280.9388428	0.10
337.2198486	0.07
348.2512817	0.05
439.3646851	0.06
441.5672607	0.04
445.4634399	0.08
460.6439209	0.03
474.4096680	0.05
502.4453125	50.53
503.0903931	0.10
504.1489868	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1906
Annotation	Codeine-6-glucuronide
Peak:m/z	Relative Intensity
134.9078064	0.05
142.7309570	0.03
143.9038086	0.02
147.3046875	0.08
149.7635498	0.01
161.0200195	0.78
162.0172119	0.28
167.2492371	0.03
167.9037170	0.02
176.9080811	0.05
177.8017883	0.02
178.9056091	0.62
185.7943115	0.05
188.3178101	0.06
193.0619354	2.18
208.2492676	0.06
209.2220764	0.04
214.9585266	0.03
221.1178131	0.14
226.1871796	0.08
228.0161438	0.03
230.8883057	0.02
244.0664978	0.20
254.0711365	0.03
259.3119202	0.07
260.9470825	0.03
266.1870728	0.02
294.1882935	0.03
296.1803894	0.31
306.0870056	0.11
308.2061157	0.27
309.4313354	0.05
311.2962036	0.30
311.9987488	0.03
326.2609253	0.03
329.2790527	5.65
330.2521362	0.04
332.3888855	0.05
344.0532837	0.07
345.1169739	0.03
347.1127319	0.61
354.2016296	0.04
360.4051819	0.04
378.3450623	0.09
380.6503296	0.06
383.2525330	0.34
387.3144836	0.06
390.2041931	0.04
391.2823181	0.01
401.1210022	0.06
414.2836609	0.03
416.9811401	0.25
418.4616699	0.03
421.2143860	0.02
425.3300476	0.04
426.3110962	0.20
432.3402100	0.02
439.3459167	0.13
440.1246033	0.05
440.9782410	0.02
448.3518372	0.06
458.1971741	100.00
458.8708191	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1146
Annotation	6,7,3',4'-Tetrahydroxyaurone 6-(4'',6''-diacetylglucoside)
Peak:m/z	Relative Intensity
161.1399384	0.63
162.9278412	10.26
171.1814270	0.23
172.9347534	8.94
175.0999146	0.46
176.7803040	0.28
178.0606995	1.04
187.1660767	0.34
190.9893036	68.62
193.1318359	16.65
202.2420959	0.23
203.1175842	0.12
209.1257172	5.71
217.1015625	0.41
223.1133118	0.30
231.0441284	0.81
233.0366364	0.77
246.0425262	0.23
247.0464172	0.49
256.9865417	0.71
261.3154297	1.63
274.0698242	0.17
275.0625000	1.12
287.1496582	0.18
293.1573486	34.57
305.2877808	0.21
309.2763062	1.53
316.2365112	0.36
319.0734863	1.33
323.0972290	57.78
325.3583984	0.27
326.2026978	3.97
327.3457642	0.68
330.8254395	0.55
332.1928101	0.30
337.1290283	100.00
340.9124146	0.45
349.3490601	3.00
355.1439209	32.59
357.2362671	0.15
367.0886841	85.73
383.4229126	0.67
385.1915894	89.69
387.3747559	0.24
389.2085571	0.32
391.3219604	0.26
398.3348999	1.39
441.2919922	0.23
471.3806763	0.31
482.2161865	0.45
485.3751831	0.96
486.4758911	1.19
487.3305664	0.65
489.2474365	0.24
491.1196899	0.30
493.8068237	1.58
494.4899292	1.01
495.2328491	0.37
503.3323364	1.04
512.9006958	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1297
Annotation	Arborescoside
Peak:m/z	Relative Intensity
112.9716339	3.78
115.0681610	0.25
118.8666229	4.01
123.9010468	0.12
130.9561768	2.38
135.1203766	0.25
142.9935303	4.60
147.0900574	0.19
147.9368439	0.17
148.9961090	1.11
152.8199768	0.57
161.0204620	4.74
163.0878754	0.52
164.0084839	0.28
165.2594910	0.83
166.9880981	0.15
178.9845428	100.00
191.0973969	3.16
191.9486084	2.21
192.9710999	0.99
207.0677490	0.99
209.0591125	0.16
210.8390045	0.69
221.0099945	0.22
222.1634827	0.47
224.0881042	0.59
224.9747620	1.95
237.0600891	0.32
239.5689697	0.38
240.2020569	0.37
254.8781128	0.43
266.4897766	0.19
268.8713684	0.15
280.9805908	0.30
293.6000671	0.47
295.3306885	0.45
296.2642212	0.19
299.1558228	0.34
308.3822632	0.14
309.2095337	0.16
311.2673340	0.11
324.1523132	0.21
327.1779175	0.17
341.0577698	8.57
342.3967896	0.61
343.3603516	0.53
345.2624512	0.23
352.2528687	2.04
352.9841309	0.59
355.2209778	3.19
359.1327209	0.42
368.2797852	1.28
369.0893555	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.05
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
174.9010315	0.15
193.0637817	0.07
210.9268494	2.91
218.2499695	0.03
229.0845642	0.13
236.1517639	0.09
237.2027588	0.02
241.0632629	2.30
259.1886597	0.08
261.0757446	0.03
273.0520020	0.67
280.1207275	1.11
293.1690674	0.03
296.9745483	0.12
305.1674500	0.38
310.9231262	0.07
311.8463745	0.03
313.0794678	0.17
320.9406128	1.19
321.6809692	0.02
323.1744995	100.00
350.3745728	0.03
380.3851318	0.12
385.1514893	2.93
390.8394775	0.06
392.5840454	0.12
394.8875122	0.10
396.9946899	0.16
403.0751343	2.70
428.9279785	0.26
453.3859863	0.08
467.2479858	0.23
478.6798096	0.85
479.8436890	0.27
480.7537231	3.24
518.6281128	0.12
522.1148071	0.02
547.3030396	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	499.2553
Annotation	Unknow
Peak:m/z	Relative Intensity
146.8773041	0.04
160.7291107	0.16
165.0997620	0.61
176.3904266	0.06
178.9296417	0.15
191.4672241	0.03
193.0263672	0.05
207.0469055	1.04
225.0252991	0.04
245.6664429	0.03
247.2765198	0.71
252.1957703	0.09
259.5592957	0.07
269.2468872	0.09
271.3563843	0.11
273.3050537	1.99
287.1889648	0.19
289.2218018	0.09
291.2261047	100.00
293.2782288	0.03
299.5804443	0.11
305.2246094	1.31
315.2742920	1.05
317.3936462	0.21
319.3776550	0.04
320.4031982	0.03
327.2237549	0.18
333.3347168	7.22
345.2904968	0.88
351.3034668	0.04
353.0079346	0.06
357.2944946	0.17
363.2392578	1.75
375.3699646	0.27
381.4049377	0.07
387.4867859	0.26
393.4077148	0.09
401.3079224	0.07
403.1802673	0.04
434.8504333	0.05
435.5567932	0.06
439.2536011	0.04
445.1135254	0.02
449.1527405	0.03
452.9909973	7.69
453.7568054	0.02
455.2662354	0.09
457.2541809	0.40
461.1380310	0.03
467.1111450	0.19
469.2377319	0.03
470.0298767	0.05
479.3728333	0.06
481.5220337	0.08
500.5455933	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.003
Annotation	Unknow
Peak:m/z	Relative Intensity
124.7669601	0.24
128.8818054	0.17
131.0556488	0.59
132.1198120	0.15
133.0353546	0.06
149.8702240	0.05
156.0049286	0.18
165.0374298	0.96
172.9407959	1.54
185.0525208	0.21
191.0318604	100.00
192.9244080	0.07
195.0885773	0.46
213.1440582	2.05
230.9403076	0.14
237.9065857	0.06
241.1621094	0.55
249.1012268	0.36
255.0618591	1.26
256.2907104	0.46
258.1556702	0.16
265.1035461	0.06
273.0259094	1.49
279.1773987	0.10
288.8540649	0.35
298.2718506	0.30
299.0344543	2.74
305.0216064	0.20
306.2162170	1.34
307.1248474	0.05
308.1730347	0.53
309.2731934	0.05
317.0085144	3.98
323.2186890	0.15
327.3529053	0.20
329.3858643	0.32
330.0462341	0.17
332.2195129	0.06
339.3388672	0.13
341.0084839	0.23
342.5101318	0.13
347.6559448	0.03
356.8612061	0.21
359.0042114	2.21
360.4450684	0.12
374.1431274	0.70
374.9408875	0.94
376.6540833	1.02
377.4300537	0.03
378.7725525	0.24
382.1353455	0.24
384.9345398	0.54
402.9530334	9.97
403.6009216	0.11
406.2821655	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.18
Annotation	Unknow
Peak:m/z	Relative Intensity
186.0641479	0.12
187.1478271	0.10
191.2200623	0.31
193.1171112	2.94
199.2170410	0.06
201.0139771	0.26
201.9929047	0.48
215.1228790	0.19
217.1164093	1.64
228.0306396	0.29
233.0711823	1.50
242.0255737	0.18
242.9465485	0.73
249.1809692	0.17
251.1730347	0.06
257.3809509	0.12
261.0631409	5.92
274.0054626	0.10
276.6690369	0.16
280.3594055	0.06
286.2212524	0.11
287.0602417	0.57
295.0939331	0.56
301.3284302	0.15
305.1473999	3.08
310.8229980	0.30
313.9568787	0.24
315.2410889	0.40
324.0495300	0.29
325.9248657	0.24
329.1102905	6.12
330.1519165	1.55
343.1151123	2.64
344.2172852	14.33
345.1006470	3.52
349.0332031	0.87
357.6103516	0.57
359.1184692	48.30
359.7610474	0.22
365.1030273	0.13
367.0297852	0.09
373.0873413	0.16
378.5644531	0.14
381.3897095	0.09
386.3298340	0.26
387.2029419	0.31
399.3264160	0.20
401.1674194	5.60
410.3784180	0.26
423.4827881	0.08
425.0675049	0.08
426.4552002	0.22
427.2933350	0.18
429.4023438	0.13
430.3018188	0.24
445.3643188	0.52
449.3995972	0.14
457.5567017	0.05
471.0590210	3.08
485.5796509	0.29
489.1991577	0.29
499.1271362	0.20
503.1770630	2.57
506.3999023	1.33
507.3189087	1.87
509.0903931	0.09
509.9873047	0.19
521.2080078	100.00
522.5314331	0.38
529.2941284	0.10
534.5487061	0.15
538.4204102	0.24
542.1796875	0.91
543.0856934	1.19
548.0775146	0.13
549.2789917	7.98
563.2987671	77.81
564.8594971	0.14
573.8865356	0.16
579.1255493	0.23
581.1473389	0.26
583.3289185	0.49
587.9712524	0.28
589.4566040	1.48
592.6231079	0.28
603.3001099	1.84
615.2366333	3.53
619.3377075	0.07
621.1907349	0.12
632.3020020	0.25
633.3414917	2.55
647.4663696	0.69
649.3820801	0.39
665.0770874	7.40
665.6917114	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	873.2263
Annotation	Kaempferol 3-neohesperidoside-7-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
268.3432922	0.11
309.9441223	0.05
326.1083984	0.08
338.2454529	0.08
343.0891724	0.78
352.1441650	0.41
353.0182495	0.07
355.1653137	1.42
367.2763062	1.04
368.5797119	0.09
379.1844482	0.10
385.1904907	2.31
386.3963623	0.16
391.1998291	0.57
397.3326721	0.11
409.2708740	1.93
409.9927368	0.34
421.3129883	0.23
433.3889771	0.52
439.1905518	1.52
451.3563843	1.21
452.2804565	0.20
463.1618042	0.31
465.3337402	0.11
469.3504639	0.63
475.4436646	0.22
487.2733765	11.28
488.1134033	0.19
499.2382812	0.27
501.1983032	0.13
505.1273193	0.43
506.0868530	0.17
507.1578979	0.29
511.0442505	0.99
512.1497803	0.09
517.2190552	1.09
518.4544067	0.04
529.3291626	1.34
531.3421021	0.20
534.5079956	0.06
537.4348145	0.06
543.1906128	0.55
543.9593506	0.28
547.1828613	2.92
548.5036011	0.15
549.2398682	0.25
553.1943970	1.47
555.2155762	0.94
559.2927246	0.15
565.1325684	0.15
571.3197021	0.78
572.1965942	0.29
573.3016968	5.72
574.0807495	0.12
577.1211548	0.07
583.1412964	1.15
584.3944092	0.03
591.3046265	7.03
592.2817993	0.61
595.3643188	0.54
597.2528687	1.69
598.2771606	0.28
601.3082275	3.41
607.2518311	0.55
609.2598267	0.37
613.3120728	2.78
615.2565918	1.23
616.0807495	0.13
622.5967407	0.12
625.1340942	0.12
627.2338867	6.45
628.4166870	0.73
629.4615479	0.08
631.1754761	3.14
632.3128052	0.14
637.1294556	0.37
639.2034912	4.11
639.9029541	0.20
643.4044800	0.12
645.2251587	1.65
649.2264404	53.03
650.2288208	1.43
657.2101440	3.59
658.1265259	0.42
661.3685913	0.36
667.2135010	6.75
668.5444336	0.19
673.2928467	0.21
675.2290649	11.19
676.1109009	0.50
686.9971313	0.05
691.3173218	0.26
693.2446899	20.39
694.2558594	0.92
698.7716675	0.06
703.2261353	0.74
703.9882202	0.05
705.1776733	1.12
705.9347534	0.11
709.3598022	0.11
711.2018433	3.12
715.0824585	1.13
717.0722046	0.28
721.5228271	0.28
723.1072998	0.51
727.2020874	0.10
733.2365723	0.30
735.2644043	8.48
736.2886963	0.42
745.3690796	1.24
751.2804565	0.29
752.6623535	1.02
753.2835693	17.76
754.5051880	0.30
757.1121826	0.63
757.7755737	0.11
759.2606812	4.72
760.1143188	0.71
763.1946411	0.11
769.3771973	0.37
771.2570801	0.40
775.4213867	1.01
777.2418823	4.80
778.2125244	0.17
783.4264526	0.28
784.5802002	0.09
789.2931519	17.82
790.2667236	0.58
793.3357544	2.41
801.4039917	5.72
802.3806763	0.55
807.1843872	7.43
811.1720581	0.33
818.5891724	0.38
819.3115845	10.78
830.0922241	0.09
837.2350464	32.68
838.3039551	2.33
855.2398682	57.51
856.3383179	1.72
857.4555664	0.05
874.1758423	100.00
874.8602905	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	231.1333
Annotation	Pterolactam
Peak:m/z	Relative Intensity
69.9211349	0.88
80.8847198	0.01
115.8475189	100.00
129.9594421	0.02
130.8367157	0.06
168.8857117	0.05
184.8615265	0.03
199.8900299	0.02
200.9678802	0.09
213.1581268	0.05
231.9556732	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	993.5952
Annotation	Unknow
Peak:m/z	Relative Intensity
279.2437134	0.50
396.4676514	0.03
413.5215454	0.06
476.3003540	4.92
581.2037354	0.06
968.7626953	0.07
992.6905518	9.88
993.3210449	100.00
994.5389404	2.36
995.1701660	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	940.4792
Annotation	Unknow
Peak:m/z	Relative Intensity
259.3312683	0.03
276.2081299	0.05
335.4938660	0.07
351.5645752	0.06
365.2124023	0.14
377.0634155	0.05
378.2532959	0.03
381.3530273	0.05
408.4766235	0.03
518.6469116	0.06
521.3469238	0.07
542.6849365	0.05
543.6589355	0.04
549.6058350	0.03
553.4450073	0.07
581.4290161	0.07
604.0703735	0.03
607.8367310	0.06
626.5898438	0.09
639.3381958	0.09
643.6608276	0.03
657.4973145	0.64
664.5749512	0.09
673.5492554	0.10
689.4506226	0.59
708.4186401	0.03
721.6378784	0.06
732.2120972	0.25
739.6881104	0.06
743.6169434	0.02
760.3198853	0.30
765.7357788	0.07
778.5766602	4.80
784.9533081	0.17
797.4721069	0.09
802.4450684	0.05
857.0134888	0.04
862.5256958	0.04
904.7222900	0.22
907.7806396	0.25
940.5138550	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.1509
Annotation	Unknow
Peak:m/z	Relative Intensity
128.1174316	0.18
128.7638550	0.05
163.0215454	0.05
168.7192993	0.04
173.9120178	0.03
182.0131531	0.02
190.9496765	0.04
200.2607422	0.06
205.0959930	0.14
209.3281555	0.07
216.9244080	0.23
218.0488586	0.05
219.3106537	0.06
221.0798340	0.41
234.9480896	0.07
237.0933533	0.09
238.8763428	0.06
246.2387085	0.05
249.2443848	0.09
250.9213562	0.14
253.1634827	0.03
261.1075134	0.04
266.3290405	0.05
269.3114624	0.02
274.1178589	0.05
275.6355286	0.12
279.1119385	0.08
281.4296570	0.08
293.3500977	0.14
294.1714172	0.05
304.8084106	0.04
307.2313843	0.05
308.8874207	0.12
311.3483582	0.13
311.9574585	0.08
315.4391174	0.37
318.0760498	0.18
337.1024780	0.17
338.1481323	0.10
339.5432434	0.17
340.6038818	0.29
353.1695862	100.00
353.7793274	0.25
355.0466003	0.84
361.3397827	0.04
362.4393616	0.06
363.3836365	0.15
380.4726868	0.07
381.2621765	0.19
399.0042419	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.2339
Annotation	9-Deacetoxy-14,15-deepoxyxeniculin
Peak:m/z	Relative Intensity
135.0899963	0.03
149.9432068	0.05
150.9267120	0.02
153.0091705	0.10
177.1672668	0.07
177.9773102	0.11
180.9749756	0.25
187.0738525	0.11
187.9927063	0.05
195.8404846	0.16
204.1322937	0.02
204.8835144	0.25
205.9232788	0.30
221.1409607	4.02
229.1448364	0.10
232.0531311	0.03
238.4285278	0.02
241.9597473	0.02
246.1030884	0.13
249.1474304	100.00
256.3143921	0.10
257.2325439	0.09
259.2777710	0.07
263.9850464	18.89
264.5925903	0.09
265.3536682	0.12
289.3269958	0.07
291.1682739	0.05
297.2445679	0.03
299.3894043	0.05
300.2685547	0.25
317.2596130	0.21
321.4341125	0.01
325.3323364	0.54
326.1941833	0.15
327.0718994	0.11
329.3512573	0.08
338.3560791	0.02
341.2583313	0.62
342.2728577	0.04
343.0445557	0.23
344.4007568	0.02
345.2609253	0.21
346.6444092	0.06
357.2863159	5.10
358.2704773	0.15
359.4196167	0.12
365.0586243	0.04
367.7037354	0.14
369.3285217	4.57
371.2642517	0.68
374.2280579	0.06
382.2992249	0.02
383.2249451	0.54
385.4030457	0.08
386.4866943	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.1858
Annotation	Ethotoin
Peak:m/z	Relative Intensity
117.2889404	0.16
118.0692749	0.59
120.0505524	0.02
121.8793182	0.02
127.8859558	0.03
128.9922333	0.04
129.9629364	0.06
131.9084778	0.16
143.4533691	0.11
144.0737152	0.70
145.9633789	5.03
157.0894012	0.13
159.0390930	0.21
169.8786316	0.40
181.0304871	0.04
186.0499725	0.03
187.9950562	43.55
189.1120911	0.11
189.8538208	0.07
193.8517761	0.02
201.0779572	0.02
203.0588074	0.19
205.0102844	100.00
206.3365021	0.05
211.1006470	0.07
212.1101227	0.19
212.8338013	0.06
214.6645203	0.03
221.1694641	0.02
224.1941071	0.03
229.9470520	0.09
233.1718750	0.07
239.5375366	0.09
244.0165710	0.08
245.2099915	0.02
246.1794434	0.08
247.7465210	0.11
248.9501343	0.01
275.2346191	0.06
280.8964844	0.04
285.1328735	0.06
286.6999207	0.02
289.2243652	0.04
293.1066284	0.16
296.2992554	0.02
302.1701050	0.07
303.4120178	0.05
304.2795410	0.06
321.0270081	0.05
328.4444885	0.05
329.2616577	0.20
334.1229858	0.07
335.8264160	0.01
345.0704956	0.12
353.1705627	0.08
357.9114685	0.13
362.2150574	0.13
362.9521179	0.02
364.2283325	0.14
372.2363281	0.11
373.1164551	0.15
374.1539001	0.09
375.9391174	0.01
377.6178284	0.16
378.5403137	0.05
384.3733826	0.21
390.7740479	1.87
391.3911438	1.83
392.3594666	0.19
398.3104248	0.04
400.1671448	0.68
406.2353516	0.04
408.5719299	0.07
410.5110779	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Butrin
Peak:m/z	Relative Intensity
168.3736267	0.02
191.0795288	0.01
271.0684814	1.87
271.6777954	0.01
283.1200562	0.93
288.0562744	0.03
289.1565247	0.01
295.1850586	0.52
308.0834961	0.01
309.3660278	0.02
313.1461792	6.92
313.7886353	0.02
328.4058838	0.02
330.2880859	0.04
337.1602783	2.70
337.7991943	0.05
343.4928589	0.08
349.2685547	0.12
351.3662109	0.11
355.2841797	0.06
361.1986694	0.08
364.1440430	0.06
367.2068481	4.19
369.3130493	0.01
375.3786621	0.09
379.1767578	1.87
381.3059082	0.11
397.1932983	3.39
398.9334717	0.08
405.1673584	0.04
415.1508179	20.45
415.7711792	0.09
417.0983887	0.09
423.0592651	0.08
425.4091797	0.03
429.3332520	0.05
431.2313232	0.03
433.1335449	100.00
435.2083130	0.01
439.3426514	0.01
441.3299561	0.22
457.3596191	0.15
458.6687622	0.25
459.3503418	0.40
461.3392944	0.08
463.3155518	0.07
472.9491577	0.04
475.5050049	0.12
481.3829346	0.09
482.3189087	0.02
483.9836426	0.02
486.4541016	0.05
488.5800171	0.01
489.3026123	0.05
495.1985474	0.03
499.4521484	0.03
500.3894043	0.05
501.3353271	0.01
507.1845093	0.05
512.1579590	0.07
513.5363770	0.12
517.0334473	0.03
525.3015137	0.48
530.4068604	0.07
531.2446899	0.04
542.4732056	0.05
543.3176880	0.46
547.3994751	0.04
560.1845093	0.17
561.1522827	1.27
562.3356323	0.06
580.2299194	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.23
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1509552	0.11
287.1147156	0.08
289.1063538	0.01
316.9610596	0.06
321.2332764	0.18
331.1334229	0.04
339.1838989	0.15
349.2211914	0.02
354.7204590	0.06
367.0444946	0.05
371.3505859	0.01
381.3957520	0.02
435.3203125	0.05
453.1351318	0.31
491.2000732	0.07
495.1682739	0.16
507.2338257	0.14
513.3541260	0.05
525.2686157	0.27
535.3438110	0.01
537.0548096	0.03
543.0778809	0.03
551.1004028	0.02
553.4242554	0.01
555.5339355	0.04
567.2503052	1.11
585.4174805	1.65
595.3037109	0.15
603.0783081	0.05
607.3770142	0.05
609.3275146	0.11
627.3173218	0.42
639.3358765	0.37
645.2959595	2.22
646.0261230	0.01
655.3092651	0.08
657.2398071	0.34
667.4088745	0.01
675.3935547	0.21
687.4048462	0.06
699.3064575	5.14
699.9321289	0.03
717.3287964	5.13
735.1697998	0.02
741.0606689	0.04
745.1625977	0.06
777.3214722	100.00
777.9371948	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0568
Annotation	Norbergenin
Peak:m/z	Relative Intensity
103.0148849	0.37
111.0043640	1.30
118.8808594	0.26
120.9855347	1.05
128.9769135	7.37
138.0649261	0.20
145.0879517	0.15
146.9183960	11.56
151.2312622	0.13
163.9976807	0.06
167.1520081	0.08
172.9786682	7.89
190.9504395	100.00
203.3031921	0.06
225.1895142	0.08
227.0551147	0.31
251.0834351	0.68
253.1313782	0.05
258.8381958	0.09
269.0588684	0.14
277.0202332	0.72
294.4672852	2.02
295.1409912	15.97
298.1305542	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1252
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
160.1892700	0.19
172.9759521	6.79
175.0926819	0.39
178.0412598	2.06
188.4886169	0.18
190.9848633	6.58
193.1022491	15.59
201.9346619	0.26
208.9519958	0.07
215.1489563	0.27
233.1421509	0.89
261.1663208	6.19
293.0413818	0.22
304.9239197	0.11
322.5103760	1.31
323.2195435	14.43
331.2904663	0.16
339.1429443	0.15
349.0148315	0.34
353.5301514	0.45
367.1289062	100.00
385.2013550	8.68
387.2251587	0.24
397.4311523	0.48
399.5934448	0.15
415.4746704	0.07
477.1085205	0.34
500.9879761	0.13
514.1994019	0.08
517.2506104	0.22
542.8932495	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.2191
Annotation	Unknow
Peak:m/z	Relative Intensity
152.6934509	0.08
170.1634369	0.06
170.7685242	0.19
175.1086426	0.17
179.0468750	0.10
191.0446167	0.36
203.1197815	0.24
204.0721893	0.17
206.1238251	0.07
211.0402832	6.96
219.0005188	0.07
221.0632019	0.33
229.9401398	0.11
241.3207703	0.05
242.7696381	0.04
245.2688751	0.08
248.2270508	0.05
250.9496460	0.05
255.1241455	0.10
258.2324219	0.14
263.1332397	1.50
264.6417236	0.25
265.2482300	0.19
266.2131958	0.70
272.4100342	0.06
276.5059204	0.20
284.1765747	0.16
289.0611572	0.14
291.0256958	0.05
293.2589111	0.03
295.2539978	0.10
297.1550903	0.16
299.0480957	0.28
301.2400513	0.27
305.2571411	0.08
306.8316650	0.75
308.3196411	0.23
310.8533325	0.21
313.0294189	1.36
320.9683228	0.25
327.4558716	0.15
328.2528076	0.08
329.4750977	0.06
330.6254883	0.08
332.4048462	0.11
333.8187866	0.28
337.2086792	0.06
342.1959229	0.22
345.3178101	0.08
347.1434937	0.16
348.0507202	0.16
349.4601440	0.18
355.3234253	0.10
356.3087158	0.18
359.1840210	0.11
363.1495361	0.31
373.5195312	0.11
374.8962402	0.06
380.2248535	0.05
380.9519653	0.19
401.2306519	0.08
405.3143921	0.13
421.2256470	0.07
423.0625610	0.12
431.1046753	0.22
432.1575317	0.11
433.3142700	0.52
443.3764038	0.12
445.3097534	0.06
446.4017334	0.14
449.3454590	0.05
453.1613770	0.09
461.2043457	0.27
463.3150635	0.18
475.2349854	0.05
477.2755127	0.43
479.3233032	100.00
481.5846558	0.03
487.1744995	0.70
488.6329346	0.64
489.3430176	0.64
492.6008911	0.18
502.2677612	0.22
506.4153442	0.50
507.5229492	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	552.2861
Annotation	Unknow
Peak:m/z	Relative Intensity
166.8446960	0.11
203.9083557	0.13
209.1684418	0.08
221.8359070	0.53
233.4068298	0.20
242.2349854	0.42
277.2747803	8.24
296.6166382	0.26
323.9786987	0.06
339.3872070	0.06
372.4612427	0.13
383.4938965	0.09
384.8659058	0.05
386.9895630	0.11
395.2757568	0.14
404.2312012	0.23
405.5704346	0.08
420.2898560	0.28
421.3356323	0.05
443.3730469	0.15
456.3708496	0.68
460.2468262	0.22
464.4306030	0.20
465.4835205	0.50
476.4375000	0.11
478.9561768	0.22
489.6815796	0.20
498.1390381	0.20
502.3280640	100.00
503.0007935	0.17
506.4216919	0.28
507.6608887	0.04
508.3073120	0.36
513.8526001	0.48
516.2084351	0.60
524.3181763	0.14
533.4212646	0.30
537.0832520	0.09
552.4611816	0.09
553.4061279	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.2
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
238.9251709	0.06
255.1337738	0.14
256.0507812	0.37
269.0485229	0.03
283.5721130	0.24
284.2452393	0.62
285.0990601	0.07
297.4028015	0.11
299.0719299	5.93
305.2243652	0.24
309.2339783	0.26
311.0857239	0.08
321.1411438	0.10
338.3850708	0.04
338.9934692	0.06
341.1580811	0.96
350.3808594	0.07
365.2408447	0.04
371.2043457	0.11
383.3306274	0.19
425.4151001	0.07
429.1765747	0.04
443.0281982	0.06
446.3945923	0.17
447.3833008	0.06
459.2559204	0.11
461.3510132	21.63
475.3415527	0.05
503.3255615	8.45
526.9920654	0.12
543.3270874	6.67
545.0642700	0.25
569.6817017	0.08
587.4887085	0.08
605.1306763	3.04
618.4542847	0.03
623.4774170	0.22
650.8833618	0.04
665.4066772	0.07
677.2510376	0.10
707.4042358	0.05
722.0067749	0.03
749.1386108	0.06
767.2152710	100.00
767.8699341	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.1592
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
211.9055481	0.01
213.2542572	0.03
226.9593658	0.02
230.0288849	0.03
236.1286316	0.01
248.9428711	0.02
271.0944214	0.01
283.2616272	0.09
285.8804321	0.03
289.3452148	0.02
296.1455078	0.09
296.8740234	0.02
299.3444519	0.02
301.1592407	0.10
302.1207581	0.03
310.2114868	0.05
314.1104126	0.93
315.0927124	0.12
317.1127319	1.57
319.2512817	0.03
327.1948853	0.26
328.8042297	0.03
330.1940918	0.05
331.1736450	0.02
338.1663818	0.03
341.5078125	0.08
342.3206787	0.28
343.0949097	0.01
343.8152466	0.02
345.1830444	2.52
351.3668823	0.01
355.2105103	0.02
357.2980957	0.03
360.2075195	2.83
361.3266602	0.06
373.0229492	0.02
375.1842041	100.00
375.8431396	0.14
402.6114502	0.06
424.3570557	0.02
425.1888428	0.02
443.1502075	0.02
446.7994385	0.09
465.2952271	0.01
467.7634277	0.09
469.2968750	0.08
473.4229126	0.02
503.3142700	0.01
537.1054077	0.01
549.4824829	0.03
554.4818726	0.01
556.5772095	0.14
572.7218628	0.05
573.5092773	0.02
578.5687866	0.02
579.2411499	3.01
586.4005737	0.05
590.5132446	0.01
591.5319214	0.02
604.1170044	0.04
605.1738281	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.093
Annotation	Casticin
Peak:m/z	Relative Intensity
146.9852295	0.03
160.8658752	0.01
165.0890503	0.01
167.1158447	0.03
172.1582336	0.02
180.8481293	0.02
192.0524902	0.01
193.219101	0.02
205.1864319	0.01
209.3245697	0.02
213.412384	0.05
219.0337524	0.04
223.1170959	0.03
225.4269409	0.01
229.0804138	0.01
233.6756897	0.04
249.0014038	0.01
255.3486328	0.02
260.2356873	0.01
269.052002	0.05
270.2150574	0.02
271.5066833	0.03
273.23703	0.03
277.4187622	0.01
278.5337524	0.01
279.2612	0.05
284.0188599	0.01
285.098114	0.01
287.18573	0.08
288.0957031	0.05
294.1818848	0.04
295.0671387	0.02
296.7931824	0.02
305.2750244	0.02
311.4413452	0.09
312.2035828	0.11
313.0137634	0.01
315.1703491	0.02
319.4187012	0.02
322.3018799	0.01
327.1893311	0.05
328.4604187	0.04
329.1355896	0.05
330.1929016	0.03
331.2675781	0.07
334.910614	0.01
336.1491699	0.11
337.2832947	0.52
338.012207	0.01
339.3568726	0.06
340.8741455	0.06
343.1479187	3.21
354.2494507	0.59
355.4449768	1.26
358.0734253	100.00
359.1585083	0.04
366.5938416	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	445.1563
Annotation	Unknow
Peak:m/z	Relative Intensity
124.8764801	0.07
146.9739227	0.09
153.1872101	0.07
160.9788513	0.11
165.1031494	0.03
178.9770050	0.06
180.1571655	0.16
191.0190430	0.43
191.8476257	0.21
193.3238525	0.05
238.9641418	0.11
249.5699768	0.13
252.9446716	0.14
265.1858215	100.00
283.1707458	0.21
284.5490723	0.08
290.0346069	0.14
291.3416748	0.33
295.3012085	0.14
303.9178772	0.04
308.1480713	0.08
313.2273560	0.11
315.3370972	0.06
324.1010437	0.05
327.2783813	0.52
328.2172546	0.37
329.1217346	0.38
341.1843872	1.29
345.0765076	0.08
353.3049927	0.08
357.4073181	0.09
373.3005066	0.06
380.2194824	0.04
381.2101440	0.05
383.2596741	0.10
383.9555054	0.07
397.1559143	0.05
398.2736206	0.40
399.2533569	0.89
400.5999451	0.26
401.2763672	0.26
409.5940857	0.07
411.2917175	0.04
414.4976501	0.19
415.4940491	0.03
425.1712341	0.54
426.3209229	0.20
426.9847107	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	598.281
Annotation	Phoslactomycin A
Peak:m/z	Relative Intensity
166.1317444	0.06
167.0025024	0.86
171.0796051	1.13
179.0155945	11.89
181.1427460	0.13
183.0367889	0.23
184.8876343	0.10
191.9724731	2.05
193.0587158	0.17
197.1569519	1.45
210.1008453	15.93
211.1424866	0.23
226.0866699	0.16
228.0398102	0.70
236.0618744	1.57
247.2361145	0.14
254.0329132	80.63
272.1589355	100.00
284.3001099	0.21
286.1588135	0.26
291.2457275	1.98
297.0538940	0.11
304.0280762	0.42
311.2333374	0.48
316.3726501	0.25
325.2100830	9.87
333.4334106	0.55
337.3319702	0.66
338.4105225	0.25
350.4758911	0.28
360.0230713	0.11
363.3068237	0.77
366.0706177	0.56
370.4473877	0.52
372.1387329	0.22
375.2695312	0.41
382.3306274	0.30
386.1787720	0.34
396.3297729	0.10
412.4660645	1.09
415.0982056	0.37
427.3986206	0.66
451.4160156	2.72
452.3849487	0.14
459.1708374	0.27
461.4293213	0.08
464.5155029	0.14
469.3398438	20.63
475.0264282	0.68
478.3128052	0.17
480.2827148	0.14
482.6872559	0.42
487.8873901	0.36
491.3233032	0.25
497.5407104	0.10
501.4566650	0.34
503.1940918	0.17
505.1939087	0.17
510.3187866	0.19
533.1035156	0.42
534.3817139	0.42
535.4548950	0.11
536.4170532	0.32
537.2326050	0.20
541.6652222	0.37
551.3893433	0.34
552.6813965	0.14
553.3831177	0.14
554.4934082	0.29
561.8771362	0.10
565.1521606	0.30
566.5191650	0.31
580.3270264	38.47
598.4999390	6.01
599.3593750	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0881
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
98.9184418	0.09
110.9989548	0.18
113.1329803	0.08
115.0397491	0.13
119.0287781	9.21
123.1972504	0.12
128.9486237	3.82
134.9470673	1.28
137.0025330	0.20
141.1062622	0.18
145.0389709	0.19
158.9805298	2.06
161.2260132	0.11
162.9696960	88.47
164.8792114	0.15
167.0163574	0.78
173.2541504	0.15
177.0800476	8.85
179.0964203	12.72
183.3638306	0.04
191.1631470	0.04
192.9947815	0.52
195.0420074	100.00
201.1539307	0.06
205.0293274	0.08
208.1204529	0.05
221.0893555	0.54
225.1153870	0.07
233.2241211	0.23
234.7914734	0.08
236.8788147	0.19
251.1351624	0.05
253.0388794	0.10
261.2340698	0.11
265.3107910	0.07
267.2470398	0.11
279.3078918	0.10
281.1346436	0.38
282.1593018	0.07
292.0695801	0.05
294.3270569	0.59
295.1321411	0.68
297.2215271	0.18
298.8986816	0.16
305.0630188	0.36
307.1575317	0.20
313.2939453	0.12
323.1695251	2.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0902
Annotation	Glutathione
Peak:m/z	Relative Intensity
87.9184647	0.03
115.8852692	1.45
116.9980774	0.31
122.0316010	0.03
129.9951782	0.33
130.9308624	0.01
133.0351715	0.04
134.1164551	0.03
143.9222717	2.98
145.0158997	0.51
145.9304810	0.04
146.8711853	0.02
150.1391602	0.03
150.9369812	0.02
156.9334412	0.02
161.9527283	25.74
162.9680023	5.26
174.9813385	0.02
177.2192383	0.02
178.9636078	100.00
179.9516602	18.49
187.0129395	0.00
188.7717896	0.02
196.4302673	0.01
202.8316650	0.01
204.7460022	0.15
205.6616821	0.02
212.0993652	0.17
215.0766602	0.44
215.9556885	0.22
219.2810974	0.02
220.8821411	0.02
228.2658081	0.03
232.9948730	13.76
234.0833435	5.01
244.0597839	0.02
245.0081482	0.64
246.0400085	0.47
253.3593750	0.03
261.6274414	0.02
262.9220581	0.13
272.1481018	0.90
273.1263428	0.58
274.0665894	0.03
286.5717773	0.01
290.0843811	4.86
291.1291504	2.93
292.1407471	0.59
299.1280518	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1819
Annotation	Creoside IV
Peak:m/z	Relative Intensity
161.0106201	2.48
185.2050171	0.27
255.3330383	0.20
316.2668762	2.39
317.3119507	0.38
331.2527466	100.00
335.5930481	0.26
341.4689941	0.11
344.5081177	0.16
358.3361511	0.48
359.1968994	0.24
361.1116638	0.40
362.1128845	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.0168
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9424438	1.76
159.9534149	0.02
160.8506927	0.10
174.8821564	11.01
179.9809875	0.07
198.7642822	0.09
214.9272461	1.52
216.9106750	0.09
228.7460785	0.51
230.9331512	0.12
232.9662476	0.05
234.9811859	0.13
244.9258118	2.63
258.9327698	0.07
261.0406799	0.06
271.1198425	0.06
271.8627930	0.06
273.0616760	7.07
273.9093018	1.70
275.0587769	3.67
287.0750122	0.22
289.0223389	100.00
305.1140442	0.13
314.0184326	0.05
328.9833374	0.16
343.3239746	0.04
346.7908325	0.28
373.2432861	0.67
377.4097595	0.05
378.8862000	0.10
379.6091309	0.06
386.9192200	2.73
388.1917114	3.14
389.0514832	20.09
401.0317383	0.04
409.1106567	0.04
411.1295166	0.04
413.2513123	0.05
415.8551941	0.02
418.3210754	0.04
419.1247253	0.04
426.8402100	0.06
428.8371277	0.16
430.0647278	0.07
435.0572815	0.13
439.1166077	0.14
447.1014099	0.03
454.2898254	0.03
456.5033875	0.40
457.1356201	0.48
459.0354919	0.23
460.9894409	0.08
467.0734253	0.03
472.9751587	0.07
475.0159302	0.23
479.2968140	0.06
484.4632874	0.29
485.4585876	0.05
504.6201782	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.2069
Annotation	Menoxymycin B
Peak:m/z	Relative Intensity
145.0437469	0.28
150.0507812	0.02
151.2225342	0.05
151.9837341	0.10
177.0374908	2.40
178.0583954	0.17
182.1548767	0.01
188.9801636	0.01
195.8999634	0.02
207.0968018	0.01
208.1889954	0.05
220.1128387	0.01
223.2957001	0.01
225.1206970	0.01
254.5490417	0.01
264.0950317	0.03
267.1435852	0.05
281.1802979	0.01
284.1707764	0.05
291.3059387	0.03
295.3883362	0.02
299.0489807	0.02
310.1542053	0.02
314.3696899	0.18
318.2219238	0.01
321.4011230	0.04
328.2051697	100.00
330.0581665	0.02
330.8799744	0.01
332.5997009	0.02
335.2976074	0.03
339.3786011	0.02
347.4249268	0.04
348.1756287	0.02
356.0908203	0.02
357.1245422	0.04
364.4823914	0.01
367.3987427	0.04
369.1365051	0.02
370.4250793	0.01
375.1012878	0.01
381.2606812	0.02
384.8328552	0.01
400.2290955	0.02
402.3547363	0.02
403.1344910	0.02
407.1371155	0.02
408.7426453	0.04
411.1802979	0.02
415.7115784	0.01
429.5157776	0.03
444.3432922	0.08
446.3539124	0.01
453.2254333	0.03
454.3077393	0.01
455.0301514	0.01
458.5991516	0.01
459.3545837	0.02
460.3801270	0.03
471.2852173	0.08
472.2951050	0.11
473.2252808	0.08
480.7823181	0.02
491.4701538	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1694
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
173.164566	0.02
239.2947845	0.01
269.2024841	0.03
271.0314026	0.59
283.1864624	0.83
295.1824951	0.22
307.1904602	0.03
313.134613	6.59
323.2495728	0.01
331.2316895	0.03
337.117981	3.35
349.2644653	0.18
355.2752686	0.02
367.1272583	5.98
379.2299805	1.68
396.6494141	0.35
397.2798462	2.46
399.2043457	0.06
415.1662598	23.33
417.3894043	0.08
423.3708496	0.01
428.854187	0.03
433.1159058	100.00
433.7623901	0.20
439.2424927	0.03
441.352417	0.14
457.1261597	0.16
459.2215576	0.37
471.3408203	0.03
475.3720703	0.09
481.2160034	0.02
495.2350464	0.05
507.234436	0.02
510.2799683	0.02
513.1206665	0.22
517.1779175	0.00
525.1627808	0.07
531.1528931	0.01
543.3743896	0.22
561.2398071	1.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1542
Annotation	Vaccinine A
Peak:m/z	Relative Intensity
88.9077454	4.34
97.8579407	2.05
99.1029663	0.09
111.8306732	0.15
113.9814453	11.52
115.0150452	7.06
116.8489227	0.02
120.0070190	0.11
125.0190125	0.33
136.9990387	0.99
140.7205353	0.05
144.7798157	0.15
151.9499359	6.79
162.8686981	0.07
176.9877930	61.52
191.0930023	0.04
194.0945129	0.20
206.0777740	18.20
217.0714874	0.09
219.3287506	0.09
221.3589325	0.04
223.1190491	0.92
229.4395294	0.05
233.1911621	0.09
248.0818329	100.00
250.1548920	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1796
Annotation	Spinosin
Peak:m/z	Relative Intensity
175.0814362	0.06
201.1184692	0.02
217.4081421	0.06
218.1679688	0.01
255.0635986	0.03
258.0430298	0.66
259.0738525	0.07
269.1141052	0.03
286.0783691	5.14
301.0979614	100.00
303.2942505	0.03
313.6863708	0.05
325.2707520	0.06
343.0895996	0.12
344.8682861	0.01
353.3244019	0.06
355.0877686	0.02
361.0849609	0.04
367.2820435	0.16
375.2733765	0.01
393.1497192	0.02
397.0736694	0.12
407.0298462	0.06
411.1940308	0.26
426.5791626	0.02
427.2190552	0.11
429.1662598	0.17
445.2189331	0.31
447.3150024	0.26
449.1989746	0.05
463.0585938	17.09
463.6735840	0.10
487.2743530	0.01
495.5993042	0.03
525.5618896	0.04
528.1647339	0.02
547.3554077	0.01
555.3389893	0.04
563.1317139	0.03
573.2405396	0.08
575.7659302	0.08
581.6836548	0.01
590.0671997	0.02
591.2313232	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1332
Annotation	Oenin
Peak:m/z	Relative Intensity
143.1078186	0.02
161.1855469	0.05
172.8156128	0.02
175.0451965	0.02
193.0536499	0.01
196.0581055	0.01
197.1655273	0.01
205.1415710	0.01
209.3257446	0.01
210.3337708	0.03
229.3417053	0.01
241.2107239	0.04
246.3459778	0.01
254.2604065	0.05
255.4456482	0.01
257.3778687	0.05
264.2045593	0.01
272.0648499	0.02
281.9231262	0.05
283.3634949	0.02
297.4235535	0.01
298.3036499	0.03
300.1784363	0.04
301.3611450	0.03
315.2795715	0.04
316.1280518	0.26
322.3225708	0.02
323.2536926	0.02
327.4223633	0.03
328.3279114	0.08
329.3550415	0.01
331.1244202	100.00
335.5131531	0.03
340.1502380	0.01
341.3226929	0.03
342.0880737	0.06
343.3032227	0.22
344.4090881	0.04
347.2561951	0.01
352.2183228	0.06
353.4099731	0.01
355.0958862	0.23
358.7893372	0.03
359.5581055	0.03
361.1912842	0.02
362.3151245	0.01
367.5446777	0.03
368.1831970	0.03
370.3591309	0.03
373.2638550	1.93
384.9882812	0.02
386.2990112	0.09
392.0795593	0.05
394.2888184	0.09
397.2753601	0.59
403.2077332	0.09
407.2314758	0.01
409.4411316	0.05
410.1816101	0.01
411.1332397	0.11
412.3784180	0.09
414.0098572	0.05
420.1945496	0.01
425.5311890	0.01
427.1705017	0.55
428.0730286	0.01
428.8559570	0.02
430.4884949	0.14
438.0701599	0.12
439.2039185	0.16
440.4606628	0.04
446.0911865	0.13
456.2291870	0.09
457.3107605	1.07
460.1803589	0.01
474.1108704	0.29
475.2046204	4.39
476.2548218	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1171.3077
Annotation	Sudachiin D
Peak:m/z	Relative Intensity
328.3778381	0.00
331.0450134	0.00
332.0487671	0.00
361.3250122	0.04
362.1184082	0.02
451.5945435	0.00
470.6598816	0.00
605.1052246	0.00
606.2205811	0.00
632.4294434	0.00
649.1949463	0.00
758.4085083	0.00
775.5635376	0.02
776.5888062	0.01
794.3732300	0.01
811.2926636	0.00
812.2584839	0.01
1171.6458740	5.05
1172.2790530	100.00
1173.1162110	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.1801
Annotation	Butrin
Peak:m/z	Relative Intensity
177.0345764	0.25
190.9060364	0.24
194.9803314	1.10
219.1010132	0.32
244.6697998	0.28
261.1232910	1.60
263.0551147	0.54
271.0857544	0.82
281.2136841	0.47
287.0679016	21.62
288.1022339	16.95
289.0853882	23.38
297.0933838	0.29
299.0848389	0.07
301.1253662	2.03
302.0310669	0.77
310.6995239	0.19
313.1459351	2.86
314.0811157	0.28
323.2524414	0.55
327.3270264	0.42
331.1968384	6.05
339.2766113	0.26
343.1030273	0.33
344.2604370	0.60
345.2254028	0.16
347.1477661	0.54
348.2788086	0.45
349.4078979	0.41
353.1406860	0.53
355.0790405	9.32
355.9221802	0.62
363.3798828	0.67
367.2200317	0.20
373.3009033	0.69
374.0976562	0.24
379.2519531	0.49
381.1538696	1.38
384.1193237	0.83
385.1209106	1.07
397.0296631	2.33
399.1047363	7.99
407.1796265	0.19
410.2791748	0.22
411.3677979	0.19
415.1834717	5.46
416.4928589	0.81
417.1696777	6.51
421.3071899	1.30
423.2131958	0.53
425.2872314	0.59
428.9215088	1.47
431.2025757	0.31
433.1621094	23.97
434.2145386	2.25
435.1881714	17.43
439.1345215	0.44
441.2275391	0.79
445.7327881	0.95
447.1427612	0.82
448.4231567	0.48
449.0883179	34.44
450.1150513	100.00
451.1640625	62.91
454.3571167	0.13
457.2007446	0.76
458.2465210	1.15
459.2254639	1.32
461.2285767	0.33
462.8898926	3.60
464.1355591	8.83
465.2516479	1.79
475.0656738	5.10
476.2127686	1.02
477.1443481	1.83
481.0807495	0.43
482.3489380	0.09
483.2401123	2.05
493.0833130	0.81
494.8132935	0.28
499.2593384	1.21
501.3789673	0.33
503.3103638	1.27
511.6039429	0.20
512.5487671	0.58
513.2919922	1.99
515.7891235	0.69
522.3673096	1.35
525.2008667	2.55
525.8884888	0.70
530.2493286	0.18
536.2455444	0.54
538.2493286	0.49
543.0949097	8.18
560.4186401	1.40
561.0905762	7.78
565.3247681	0.19
567.2080688	0.21
578.2495728	5.07
579.1640625	4.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1199
Annotation	12-chloroisoplagiochin D
Peak:m/z	Relative Intensity
132.8590851	0.05
142.8913574	0.06
145.7830200	0.14
170.7294312	0.11
173.0502319	0.44
178.8236237	0.13
191.1026611	13.75
219.9946899	0.02
229.1616669	0.04
234.8837891	0.03
245.0717163	0.05
247.9985962	0.05
253.1401672	0.09
254.3421326	0.06
265.0956726	100.00
277.6105347	0.02
313.2316284	0.02
323.0386658	0.05
327.0208740	0.04
341.1842651	0.03
342.1934814	0.03
352.2723999	0.05
352.9962769	0.01
367.1508179	0.15
369.0956421	0.05
378.4615173	0.02
384.0626221	0.03
385.0609131	0.07
394.2958374	0.08
396.0606079	0.08
411.7135315	0.03
413.2427673	0.07
421.3505554	0.07
424.4542542	0.06
425.1688538	0.10
438.9165344	13.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1051.5582
Annotation	Unknow
Peak:m/z	Relative Intensity
834.4626465	0.13
868.2535400	0.51
888.3090820	0.08
1051.4692380	100.00
1052.3146970	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9935455	0.03
160.1400452	0.03
161.1637268	0.10
178.9530334	0.30
204.6843872	0.06
252.8933105	0.06
263.1576233	0.07
281.0432129	0.01
289.3335876	0.01
297.0482178	0.13
323.0577698	0.05
340.0415344	0.11
341.1599731	100.00
369.4339905	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0936
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
113.0309296	0.02
116.9104919	0.27
122.1110001	0.03
124.9284668	6.01
127.9783707	0.04
128.9412079	0.46
133.9983215	0.06
135.0930786	0.03
142.8716125	1.50
146.9699097	0.03
149.0669861	0.04
153.1675415	0.17
155.0340576	0.04
160.9822235	1.35
169.0502930	0.41
173.0339661	0.47
178.9922791	0.05
187.0249634	0.50
191.0961456	0.29
192.0888977	0.08
193.0452271	0.19
204.9580994	100.00
218.1448059	0.05
219.1473694	0.52
223.0856934	37.87
230.9423828	0.14
232.6601562	0.04
238.1069336	0.13
245.3714905	0.03
261.2048340	0.34
284.1699524	0.18
293.3780823	0.03
308.2199707	0.33
323.3348083	0.06
352.3399658	0.11
354.3891602	0.09
355.0324707	0.07
367.2436829	1.06
381.1083984	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1253
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
160.0143585	0.18
160.7328033	0.30
172.9697418	7.35
174.3561707	0.22
175.0680237	1.94
177.1309357	0.31
182.1618958	0.13
184.1540222	0.11
189.4678650	0.43
191.0274200	12.00
193.0823059	14.01
200.1744080	0.15
202.0640564	0.71
203.0347443	0.21
205.1287842	0.08
217.1276855	2.10
218.0046997	0.13
233.1474762	0.90
243.2030029	0.67
261.0613708	6.83
275.0309448	0.19
287.1300049	0.16
305.1212158	0.58
316.2053223	0.25
323.0967407	18.81
336.4061279	0.18
349.1066895	1.11
367.0507812	100.00
367.6753540	0.49
385.0918579	8.54
499.0703125	0.90
519.5840454	0.39
523.4878540	0.27
542.9588013	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	826.4235
Annotation	Meehanine H
Peak:m/z	Relative Intensity
256.3980103	0.26
268.4516907	0.44
283.2004700	0.11
284.0904541	2.62
293.3337402	0.18
297.9159546	0.13
299.2454529	0.14
300.9600830	0.62
314.2065430	0.14
321.9941711	0.23
323.1952209	0.28
337.1855164	0.11
339.2581482	0.23
341.6846313	0.15
344.2425842	0.26
351.1381226	0.20
354.2617188	0.26
379.4127808	0.25
382.2080078	0.18
385.3685913	0.11
387.1457520	0.07
394.5612793	0.17
402.5303345	0.19
412.6498413	0.49
414.2060547	0.32
415.2354126	1.74
422.0264282	0.30
426.4915161	0.39
430.5717773	0.37
432.2877808	0.77
435.0662231	0.17
440.0762939	0.19
444.1534424	0.11
450.1525879	1.56
459.3920288	0.26
466.1876221	0.37
467.2941895	0.38
483.1375122	0.20
486.3333740	0.12
493.4006348	0.25
495.0601807	0.13
498.1619263	0.37
500.3352051	1.37
509.7340698	0.54
512.1204834	0.28
515.2420044	1.33
525.3811646	0.07
528.3288574	5.02
533.4994507	0.08
537.4410400	0.61
539.2463989	0.26
541.1884155	0.07
543.0406494	0.05
543.6961060	0.70
544.3174438	0.18
547.5816650	0.29
551.6079102	0.23
553.3317261	0.47
557.4069824	1.00
563.2586060	0.27
566.5401611	0.06
569.1382446	0.11
571.3692017	1.58
581.3035278	0.72
582.3210449	0.22
583.5151978	0.08
585.2406616	1.04
586.3282471	0.17
588.5155029	0.15
594.6962280	0.36
597.4215698	0.47
599.2420044	2.26
602.6489258	0.07
613.4610596	0.33
614.4266968	0.48
616.1354370	0.15
624.6987305	0.14
627.4155884	0.08
630.3660889	0.17
632.3804932	0.38
636.7142944	0.19
642.2816162	0.60
651.0309448	0.55
653.5737305	0.17
655.4758301	0.47
656.5358276	0.62
657.7008667	0.33
666.3385010	0.36
670.4064331	5.12
671.0526123	0.20
680.4006348	0.12
682.6078491	0.41
684.4205322	2.16
685.5028076	0.51
694.1265259	0.10
695.4378662	1.06
698.6781616	0.40
699.4059448	0.77
709.4517212	2.70
710.4750366	1.20
711.6968994	0.12
712.9455566	1.67
713.5479126	2.18
722.1254272	0.34
723.3765259	0.26
724.5294189	0.13
727.3588257	17.75
728.0103760	0.11
729.5825806	0.34
733.2418823	0.63
745.1334229	0.08
750.4704590	0.91
753.5185547	0.06
755.4193726	3.73
757.8067017	0.80
763.7355347	0.20
765.2802734	0.13
778.8395386	0.32
780.2843628	0.74
781.5129395	3.16
782.5315552	0.49
789.5157471	0.08
790.4420166	0.28
791.6244507	0.34
797.7821045	1.15
798.5299683	14.16
807.9168701	1.40
808.6183472	7.83
826.5145874	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1622
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
199.1307526	0.17
202.7063599	0.05
223.2738037	0.05
224.7612152	0.03
227.1165466	0.21
235.2069702	0.06
241.2307739	0.03
243.0380859	0.09
245.2821960	0.16
254.8907776	0.04
261.3831787	0.06
262.2467651	0.04
267.2946167	0.11
271.1381836	0.44
282.2263794	0.02
284.0485840	0.10
298.5817261	0.16
299.1887817	3.29
300.1547852	0.25
301.3272705	0.09
302.2819519	0.02
303.3372192	0.03
305.1211853	2.59
311.0696411	0.03
314.1176147	16.00
315.2052002	0.45
323.2842407	0.09
324.3082581	0.21
327.2326965	0.06
329.1013184	59.27
329.7542114	0.04
336.1508179	0.05
339.2004395	0.06
341.1135864	0.09
343.4368896	0.07
351.1533203	0.44
355.9047852	0.03
357.4898682	0.13
359.2707520	0.30
367.3205566	0.11
369.1688232	0.12
371.2001953	6.38
380.2300415	0.31
385.3067627	0.04
389.6060791	0.03
395.2247925	0.64
401.2721558	0.04
411.3137817	0.05
413.1495972	0.18
425.7378540	0.07
448.4907227	0.04
459.2448120	0.18
467.6433716	0.03
473.1630249	0.69
476.4253540	0.16
487.6472778	0.11
491.2002563	100.00
500.2913208	0.05
501.0863037	0.06
503.5803833	0.02
519.3450317	0.25
521.4196777	0.06
531.4722900	0.14
533.2400513	59.07
534.1159058	0.06
535.0607300	0.14
539.5643921	0.10
542.9161987	0.03
546.3889160	0.07
559.3256226	0.06
573.3403320	15.79
574.5659180	0.09
575.3311157	0.03
585.0792847	0.31
590.1740112	0.28
591.7312622	0.41
592.4613037	0.04
598.0332031	0.10
602.4381104	0.18
605.2543335	0.09
616.0846558	0.02
617.3361816	0.09
620.3547974	0.09
635.0832520	4.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1053.2897
Annotation	Chrysosplenoside E
Peak:m/z	Relative Intensity
301.1144409	0.16
325.3437195	0.04
365.1232300	0.04
463.2603149	0.49
505.3710938	0.23
530.8552856	0.04
545.3797607	0.05
547.4907227	0.01
569.2355957	0.02
570.7204590	0.01
571.5579224	0.02
613.3395996	0.02
631.3638306	0.02
649.4138794	0.03
733.4852905	0.01
885.3767090	0.02
927.3405762	0.11
1009.4660640	0.02
1035.5214840	0.03
1053.4003910	100.00
1054.3637700	47.08
1055.0273440	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	482.789
Annotation	Unknow
Peak:m/z	Relative Intensity
146.2060089	0.39
146.9008636	1.72
147.6875305	0.14
174.9423828	0.16
188.8864441	0.21
190.2586060	1.50
190.9355621	19.28
204.9244690	0.11
217.8675537	0.12
218.9110260	0.87
262.0154724	0.58
262.8692932	6.97
290.7644958	0.11
291.8500977	0.88
292.8333435	9.00
293.7930908	0.08
294.9829102	0.29
303.8193665	0.05
334.8142395	1.85
336.0716858	23.45
336.9279175	100.00
337.9548950	0.56
338.9482422	0.45
365.1536255	0.11
365.9736938	0.12
366.7764587	0.09
376.9044495	0.08
390.9497986	0.04
392.9404907	0.08
395.1787109	0.08
407.8958130	0.14
408.8996887	2.21
412.6906738	0.04
436.3131714	0.50
437.0280762	1.10
438.0460510	0.52
438.9551697	2.67
445.9050598	0.09
454.7463074	0.23
464.9116821	0.82
482.6608582	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0568
Annotation	Norbergenin
Peak:m/z	Relative Intensity
100.5465088	0.05
102.9599152	0.14
106.8635635	0.07
111.0129700	1.10
121.0047531	0.68
128.9739990	8.62
144.9879150	0.13
147.0033264	13.68
147.6276855	0.13
150.9616394	0.33
160.8510895	0.14
164.6961365	0.06
172.9996033	8.97
189.0106201	0.15
190.9940338	100.00
225.9548950	0.13
251.0409851	0.19
259.0085754	0.04
267.1779785	0.13
269.1666565	0.30
277.2137756	0.17
282.6474915	0.13
295.1083374	16.59
298.1118774	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1824
Annotation	Butrin
Peak:m/z	Relative Intensity
173.0339813	0.12
174.0276489	0.17
175.5252228	0.12
176.1667786	0.04
177.0608826	0.08
179.1788177	0.05
181.8604126	0.15
186.2571106	0.11
187.1257324	0.12
188.0886688	0.10
190.0899963	0.07
196.0164490	0.07
197.9608307	0.06
199.0553589	1.85
199.8729858	0.49
200.9479828	0.58
202.2216187	0.36
209.1874237	0.06
210.0563965	0.08
212.0655060	0.09
212.9827118	0.13
214.0979614	0.27
215.1662750	0.85
216.1810913	0.08
217.0176392	0.29
220.9249878	0.06
222.8072052	0.05
223.9980774	0.27
225.1004791	0.04
226.0963135	0.12
227.1414490	0.88
228.2326965	0.07
230.2423706	0.12
232.9769135	0.21
233.9944611	0.21
235.2232361	0.05
236.2468567	0.08
238.8225098	0.40
240.0215454	0.53
241.2732086	1.28
242.0473175	2.54
243.0326233	0.68
247.1532135	0.03
254.3153839	0.13
257.1281738	1.30
258.0824585	0.64
259.2064819	0.13
260.0759888	0.10
263.6359253	0.04
265.0926208	0.08
266.1072388	0.13
268.1140137	0.79
269.0403442	0.16
271.1112366	0.08
273.1713867	0.07
275.4607544	0.10
279.3150635	0.05
280.2828369	0.13
281.2835083	0.09
282.0750732	0.59
283.1812134	2.52
284.0788879	0.17
286.0765991	2.39
287.2304382	0.41
291.9485474	0.18
293.4513550	0.05
297.2283936	0.87
299.1245117	0.13
301.1120605	100.00
302.1313477	17.84
305.6544800	0.08
307.0127563	1.07
308.1630249	0.11
309.0718384	0.10
310.1111450	0.96
311.1394348	0.10
312.4596558	0.04
313.3479004	0.36
315.1881104	2.62
316.1173096	0.73
321.3494263	0.03
325.1251831	9.95
326.0932617	1.99
327.0230103	0.08
328.0428467	0.22
337.0776367	0.33
338.3613892	0.11
339.4378052	0.39
340.8848267	0.35
341.9141235	0.11
343.1591187	13.20
344.2069092	1.96
349.2963867	0.07
350.4771118	0.06
351.2139893	0.17
352.0428467	0.21
353.1885986	0.21
355.2142944	2.39
356.2934570	0.71
357.2614746	0.31
366.6064453	0.14
367.2087402	2.32
368.1374512	0.63
373.0199585	0.70
374.0268555	0.03
379.3796997	0.18
385.1486206	1.87
386.3098145	0.43
387.4532471	0.13
388.3552856	0.04
394.1127930	0.12
398.3233032	0.05
400.4710693	0.09
403.2510376	2.09
404.2310791	0.51
410.3549194	0.06
411.0439453	0.10
415.4717407	0.09
416.1901245	0.07
427.1622925	0.06
429.2709961	1.21
430.2182617	0.18
431.1586304	0.06
444.0238647	0.03
445.3003540	0.76
446.1535645	0.11
447.2565918	1.39
448.3249512	0.28
459.2914429	0.09
460.4020996	0.15
461.3328247	0.18
463.4617310	0.41
471.4049683	0.04
472.4703369	0.12
473.1005249	0.04
489.1905518	12.28
490.1967163	2.77
505.0745239	0.07
507.5039673	0.13
565.1613159	0.10
576.3920898	0.08
577.4386597	0.18
591.3157349	0.50
592.2521362	0.13
594.2293091	0.45
610.4633179	0.21
611.4255981	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1053.5344
Annotation	Unknow
Peak:m/z	Relative Intensity
867.2258301	0.07
924.4064941	0.16
1036.5971680	0.18
1053.5572510	100.00
1054.6591800	52.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.0965
Annotation	Mikanin
Peak:m/z	Relative Intensity
106.8456879	0.01
155.1015625	0.03
180.9588623	0.04
183.0531311	0.02
194.9009857	0.13
197.2686157	0.01
203.0384674	0.01
209.1360321	0.02
222.2149353	0.01
225.0762634	0.04
227.0150757	0.02
234.2730103	0.01
235.2991028	0.02
241.3857727	0.02
245.1139526	0.03
248.0500793	0.07
249.2462769	0.03
251.0950623	0.02
257.2301025	0.02
263.1474915	0.03
266.0810547	0.05
267.1503906	0.03
271.3083801	0.03
281.1183777	0.03
282.6952820	0.01
284.1065063	0.61
285.1132812	0.06
294.2023315	0.45
297.1206360	2.54
298.2438354	0.07
299.2084656	0.10
300.3908386	0.04
301.0634155	0.05
301.9472351	0.02
303.4801025	0.03
309.1272278	0.06
312.0777283	4.88
313.1402893	1.28
315.0686646	8.49
316.1006775	0.15
317.2518311	0.08
318.0373535	0.02
325.3767395	0.03
326.6000366	0.25
327.2850952	0.87
328.2745972	0.28
330.0925293	100.00
331.1248474	4.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1144.31
Annotation	Unknow
Peak:m/z	Relative Intensity
331.0458679	0.31
332.2207642	0.54
346.0098572	0.06
361.0967102	1.28
362.0556641	0.45
412.4130859	0.05
421.2654114	0.04
438.2195435	0.17
439.2508545	0.10
441.7012329	0.02
471.5011902	0.06
531.3129883	0.05
575.1919556	0.08
606.3275146	0.12
607.4080811	0.29
639.7335205	0.08
649.4453125	0.07
650.4885864	0.24
651.3677979	0.11
667.2862549	0.03
668.9636230	0.05
727.2010498	0.07
728.2576904	0.03
741.4689941	0.05
745.6937256	0.09
747.2518311	0.25
758.4812012	0.11
765.3270874	0.05
775.4181519	0.28
776.3414917	0.26
777.1362305	0.28
782.3728027	0.12
783.1862793	0.06
793.3728027	0.10
794.3713989	0.23
795.2528687	0.12
811.2851562	0.28
813.1973267	0.21
1143.1103520	100.00
1144.2410890	2.82
1144.8684080	0.15
1145.8221440	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	689.2427
Annotation	Unknow
Peak:m/z	Relative Intensity
252.0128632	0.14
272.2976990	0.16
291.3318481	0.09
293.3248901	0.40
309.2004700	0.23
310.2128296	0.20
311.2327271	0.64
316.3700562	0.12
328.1478271	0.63
329.2603149	0.25
330.0486450	0.31
331.1414185	1.79
332.2910767	0.37
342.4345093	0.13
346.2184448	1.62
347.0505981	0.17
347.6968994	0.36
349.0118408	0.19
359.5380859	0.18
361.1717529	57.52
362.1792603	12.65
363.2608643	3.88
363.9706421	0.16
372.3156128	0.06
377.1359253	0.11
395.3490601	1.05
402.7011108	0.45
403.3203735	0.04
410.9233398	0.13
427.3563232	0.73
435.1092529	0.97
435.8843994	0.48
436.5023193	0.33
445.1372681	0.42
466.9361572	0.40
476.0773315	0.10
482.8212891	0.47
506.1509399	0.11
515.3634033	0.10
524.1984863	0.07
525.3821411	0.14
526.4339600	0.19
528.2372437	0.07
529.9762573	0.55
534.4608765	0.05
535.3272705	0.20
538.1013794	0.04
545.5294189	0.25
553.4428101	0.07
559.4273071	0.15
565.0234375	0.21
566.3187256	0.22
567.5044556	0.18
589.2869263	0.09
601.5599976	0.12
603.2437744	0.18
607.8363037	0.47
615.6653442	0.24
625.2471924	0.05
627.2660522	0.74
631.7277222	0.07
652.0675659	0.26
656.4567261	0.11
657.3126831	0.63
659.8911743	0.13
661.4812622	0.10
671.2368164	100.00
689.0715942	0.84
690.2577515	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.1606
Annotation	Ractopamine
Peak:m/z	Relative Intensity
89.1217804	0.12
93.13721466	0.11
106.0129623	0.56
106.9647217	0.40
108.0780487	0.11
115.9711304	0.64
117.9902344	0.40
118.918808	0.21
120.9614639	0.24
122.1492157	0.05
123.0398254	0.03
130.092041	0.16
131.4138794	0.18
132.049942	0.56
134.0094299	10.31
135.9398193	0.41
140.922821	0.04
142.1402588	0.18
142.9708099	0.12
145.1341248	0.04
146.0918274	0.08
147.047699	2.02
150.0487366	0.05
151.0733643	0.05
156.0049286	1.82
158.1555634	0.12
159.1430969	0.84
160.085907	0.58
161.1027985	0.37
161.91922	0.24
163.1191406	0.11
166.01091	0.02
167.15065	0.03
169.0571594	0.59
170.1322021	0.19
170.8590698	0.19
172.2051239	0.14
173.0523224	0.04
174.0426636	0.56
176.2232666	0.21
177.1201477	0.24
179.1183167	0.03
180.9494781	0.03
182.4644012	0.04
184.01474	0.04
185.2598267	0.42
186.1672821	0.37
187.1357574	1.04
188.0785522	2.05
189.3283386	0.17
191.1520996	0.05
195.2185669	0.03
196.3113098	0.14
197.831543	0.84
199.1770325	0.85
200.0357361	0.08
201.0946045	0.08
201.8079529	0.05
203.4169922	0.16
205.4590149	0.11
211.0559387	0.05
212.187561	0.59
213.1285706	1.00
214.4257812	0.36
215.2373657	0.29
216.0447083	0.13
217.4667664	0.03
219.30896	0.05
220.5596008	0.15
225.2294617	0.44
227.1739807	0.99
229.1739502	71.02
231.0960999	4.23
237.530365	0.26
238.3053284	0.75
240.347229	0.09
241.3265381	0.16
242.2095947	0.16
243.2391968	0.29
244.1267395	0.39
245.3113708	0.91
249.178009	0.03
253.3388062	0.33
254.2172852	0.18
255.1616516	3.44
256.2581177	7.04
257.1762695	0.28
262.0639038	0.09
263.1381836	0.23
263.9902954	0.10
270.2155762	0.03
271.1607971	2.01
272.1629944	1.50
273.2580566	1.36
282.1545715	100.00
282.9559326	0.88
284.1209717	8.06
285.1280212	2.45
286.1405945	0.66
301.1759644	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1667
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
169.0656891	0.08
187.0177155	0.04
189.1747742	0.03
191.0982971	0.03
210.3344421	0.03
216.1882477	0.03
270.9763794	0.03
280.2528076	0.22
282.9338379	0.04
298.1401062	0.59
299.1055298	1.28
307.5525513	0.43
308.1871338	4.01
309.3288574	0.02
310.1760559	0.19
311.1726685	0.76
312.0678101	0.22
317.3286133	0.03
323.1135864	53.92
324.0697021	0.14
325.0333557	0.66
326.0845337	0.03
327.3684082	0.37
335.6294556	0.12
337.0853271	0.20
338.1949463	0.89
339.1751709	0.31
339.9707642	0.11
341.2075806	9.73
349.1826172	0.02
350.2440796	0.16
351.1337891	0.33
353.1994019	8.09
355.1506958	0.14
356.3153687	0.02
357.1860962	0.03
358.2221680	0.21
359.1509399	0.03
365.1926270	3.38
367.1451416	0.59
369.1434326	0.20
371.2371826	7.51
379.4548950	0.04
381.1997070	0.26
383.1855469	3.92
385.1973877	2.02
389.4879150	0.13
392.7590942	0.06
395.0594482	0.32
397.1506348	0.13
401.1098022	0.19
406.0561523	0.10
407.2329102	1.39
411.5786743	0.02
413.1578979	0.17
425.4322510	0.19
428.1870728	0.40
443.1835938	100.00
443.7860107	0.74
445.4800415	0.08
455.3363647	0.05
460.0322876	0.05
461.2334595	1.21
463.3245850	0.69
475.4050293	0.12
478.2815552	0.02
479.0312500	0.08
487.2392578	5.21
500.6893921	0.09
503.1585083	0.13
514.5590210	0.07
517.3103638	0.15
523.2356567	0.03
570.2913818	0.02
575.3262329	0.03
576.3108521	0.02
588.3449707	0.30
589.3666382	0.47
607.2391357	0.04
608.4758911	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.7995
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0851288	0.09
161.2151184	0.28
162.9082489	0.08
168.2043915	0.10
173.0369263	0.11
177.1406555	0.18
179.0817566	0.07
187.1960449	0.39
189.0733643	0.09
194.7858734	0.07
203.2131195	0.10
211.0941467	0.06
215.3766479	0.10
217.2871704	0.12
218.9678192	0.12
233.3745422	0.16
238.2876587	0.32
243.2033997	0.62
255.1008911	0.10
257.1236267	2.07
261.2457581	3.21
265.1519165	0.15
281.4302368	0.08
284.1579895	0.09
287.7979126	0.11
289.4630127	0.08
290.3692017	0.33
291.3601685	0.27
298.7369995	0.11
299.4060059	0.09
300.9956055	0.19
302.4293823	0.19
303.1872559	0.13
307.0619507	0.03
308.4118652	0.09
311.3339233	0.16
312.8507080	0.09
314.2929077	0.22
317.2325439	0.25
321.7462769	3.79
323.2760010	1.10
330.7473145	0.46
331.4333496	0.25
332.2264404	0.12
335.3899536	1.39
336.5046997	0.51
337.1837769	0.13
341.0696411	0.26
343.1887817	0.04
345.1450195	0.25
352.1290894	0.22
353.1572876	0.08
355.3571167	0.18
361.0614014	0.22
367.4974365	0.13
369.1764526	0.22
376.2109985	0.41
377.2103271	0.21
379.6467285	0.05
380.2865601	0.03
381.2015991	0.04
385.2349854	0.18
386.4381714	0.16
387.3298340	2.08
390.3063965	0.05
392.0489502	0.09
396.2677002	14.52
396.9801025	0.54
397.7215576	0.39
398.9109497	0.06
400.3939819	0.06
401.6561279	0.07
405.4094238	0.03
408.0726318	0.09
412.9058838	0.04
415.2628174	0.11
420.4140625	0.34
423.3875122	1.20
425.7137451	1.01
427.3094482	0.66
429.8735962	0.38
432.9785156	0.34
433.7415161	0.11
437.3559570	0.15
439.9660645	0.19
441.1741943	0.42
449.9852295	0.24
451.8297729	4.31
452.6787109	0.15
457.3541870	0.72
459.4326782	0.10
460.8608398	100.00
461.8430176	2.28
462.8598022	0.61
463.8361206	0.83
464.7590332	0.22
465.7098389	0.07
466.6895142	0.19
468.2306519	0.68
470.4773560	0.07
471.1519775	0.17
475.3397217	0.03
477.2539673	0.31
479.5662842	0.12
482.0816650	0.21
483.9923706	0.20
485.2128296	0.05
486.3826904	0.18
491.3764648	0.13
495.8818970	0.11
497.5083618	0.09
498.3146973	0.02
499.9601440	0.10
504.2977905	0.24
506.6838989	0.03
507.3261719	0.03
509.8020630	0.50
513.4556274	0.35
514.9982910	0.24
520.1535034	0.11
523.3383179	3.77
524.2041016	0.14
524.8329468	0.04
529.4992065	0.10
531.3474731	6.71
534.2814941	0.28
537.5059204	0.20
551.6947021	0.11
565.9383545	0.10
568.4816895	0.11
573.4641113	0.08
574.2086182	0.03
586.3798218	0.58
597.5973511	0.21
602.5692139	0.04
612.4902954	0.06
613.7290649	0.11
615.4984741	0.20
642.3972778	1.01
645.6882935	0.13
646.8302002	0.05
647.6990967	0.09
655.6171265	0.04
660.3660278	9.83
661.3334351	0.15
669.5061035	0.11
681.4572144	0.05
682.8845825	0.07
683.6964722	0.10
697.3740845	0.04
699.4382324	0.10
711.6023560	0.15
733.0573120	0.04
737.8938599	0.03
764.4414673	0.07
769.4605103	0.08
770.3592529	0.04
774.1604004	0.05
784.4757690	0.12
791.5348511	4.70
794.3853149	0.06
798.4982300	0.60
810.6818848	0.04
812.8529053	0.02
833.8920898	0.09
840.5645142	0.06
845.9268188	0.08
854.9965820	0.18
867.1300659	0.05
902.0504761	0.07
902.6942749	0.12
919.3012695	0.11
920.5447388	33.45
921.6461792	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1096.5212
Annotation	Unknow
Peak:m/z	Relative Intensity
353.0553894	0.05
394.5700989	0.07
395.3559570	0.09
402.5097046	0.03
404.5018311	0.02
408.4163818	0.03
412.1018066	0.09
419.3513794	0.06
436.1875305	0.04
439.9691162	0.10
447.2957764	0.12
464.4640198	0.11
476.1932983	0.03
486.2448120	0.11
492.4030151	0.05
497.6910095	0.02
508.0755615	0.08
513.2495117	0.04
514.4240112	0.29
524.0291748	0.06
526.3931885	0.04
537.5543213	0.09
553.4667969	0.09
558.2734375	0.19
575.1740723	0.14
577.4303589	0.10
581.4748535	0.03
594.3325195	0.05
598.3065796	0.07
603.4500732	0.04
604.6643066	0.08
605.2851562	0.18
613.3828735	0.08
622.4395142	0.05
626.0822754	0.15
633.2878418	0.10
639.4014282	0.03
650.4987793	0.49
657.3905029	0.40
672.3640137	0.49
673.5355835	0.13
678.5011597	0.10
689.4311523	0.05
700.3668213	0.93
701.6459961	0.08
723.5136719	0.21
738.5079956	0.10
752.6149902	0.05
763.5688477	0.16
770.1821289	0.03
782.4015503	0.06
785.3876953	0.12
787.5260010	0.05
789.6458740	0.11
791.4089355	0.11
797.2902222	0.21
799.7227173	0.02
808.2778320	0.02
813.7907715	0.11
815.4481201	0.18
836.4763184	0.48
841.4885254	0.23
842.6303711	0.03
843.5954590	0.29
858.6547852	0.11
866.6063232	0.10
870.4962158	0.05
880.4864502	0.05
886.5323486	0.45
910.3369141	1.00
911.0695801	0.06
926.6575928	0.09
933.3740234	0.03
939.3640137	0.14
949.7156982	0.08
954.4737549	0.33
955.8128662	0.02
967.6728516	0.11
971.5064697	0.02
981.6430664	0.17
991.3007812	0.08
999.7121582	0.13
1023.8935550	0.06
1027.6817630	0.04
1035.0133060	0.05
1051.3908690	0.30
1052.7098390	0.70
1068.5614010	3.97
1069.6345210	0.05
1078.7678220	0.17
1079.6374510	0.07
1096.5107420	61.25
1097.5627440	100.00
1098.3388670	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	755.2372
Annotation	Sibiricose A4
Peak:m/z	Relative Intensity
210.9535828	0.16
213.1796875	0.50
240.7681427	0.88
258.1521606	7.51
259.1455688	0.99
286.0424805	11.57
298.0988159	1.13
301.1867371	96.47
313.2684937	0.31
343.3452148	1.75
367.2240601	0.21
373.1981201	0.38
411.2558594	2.55
445.0501709	1.40
447.1884766	0.85
463.0966187	7.96
513.1735840	0.66
545.3051758	0.18
557.8060913	0.42
600.3567505	0.86
609.1867676	100.00
725.7907715	1.41
755.2744751	5.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1849
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
176.9146271	0.72
178.8531036	0.63
189.1560516	0.17
191.0931396	0.16
194.9604797	7.70
203.3654938	0.25
218.9501343	3.39
231.1387939	0.22
245.1197205	3.45
248.7788849	0.32
253.9722443	0.20
254.7781982	1.22
257.9827881	0.18
261.1635132	0.54
263.0980835	4.82
273.1564941	81.20
278.8213806	1.42
281.0023804	6.69
285.1607666	3.37
297.1146851	4.83
299.1502075	0.74
303.3477173	0.41
305.0251465	0.38
309.0354919	1.04
315.0964966	20.51
321.2503662	1.17
323.2306519	0.32
327.0883789	0.16
329.0374756	0.26
339.1677856	21.56
345.0372925	0.15
351.0456543	1.56
357.3479004	0.08
363.2767944	1.28
365.1478882	4.24
369.1138306	2.66
381.0876465	8.17
383.1217651	42.79
389.2536011	0.54
393.1100464	0.11
399.2747192	7.23
401.1748047	41.00
405.0766602	0.81
407.1708984	1.95
413.0822144	1.26
417.1075439	40.31
419.1364136	100.00
423.0151978	1.16
425.2999268	4.00
429.1220703	3.44
431.2246094	0.21
435.0800781	46.21
437.0667725	0.10
441.0595093	0.74
443.1016235	4.68
447.3176270	0.15
449.1509399	0.53
458.6464233	0.79
459.2501221	7.90
460.9748535	3.29
467.1381226	0.94
477.0932617	0.43
479.4454346	0.36
483.1887207	1.09
491.3253174	0.23
497.0072021	2.67
509.1754761	4.78
527.2234497	19.79
545.0967407	29.50
545.7525024	0.06
562.9931641	22.63
563.9135132	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0774
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
84.8689804	0.14
88.9624405	0.17
93.0068512	2.73
94.7814102	0.25
99.2044525	0.08
100.9430161	0.56
102.8773651	0.06
106.9443817	0.65
108.8039780	0.06
112.9722900	5.48
118.9681396	0.17
120.6859436	0.14
130.9541321	0.36
133.1273346	0.17
134.6607361	0.28
135.2875061	0.51
136.9088745	100.00
143.0045929	0.48
148.9631653	0.22
151.0337677	7.46
160.8523407	0.15
163.0049133	0.07
171.3035278	0.05
172.9985352	0.07
175.9338226	0.18
178.9517670	92.16
180.2191772	0.23
187.2134399	0.11
190.9700775	0.58
202.8901367	0.53
205.1911926	0.17
209.0714111	26.14
211.0734558	1.70
212.1479797	0.10
215.1940918	0.06
216.8606567	0.23
217.6617432	0.07
225.0649414	0.24
227.1895447	0.15
232.9715271	0.12
237.2366943	0.18
239.0092773	95.77
239.6149902	0.51
253.1004028	1.70
254.9658508	0.47
263.0156860	0.13
270.9352417	0.37
280.2493896	0.49
281.0177612	0.99
284.1832275	2.46
299.4941406	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1956
Annotation	Butrin
Peak:m/z	Relative Intensity
176.9729614	3.63
179.0068970	1.21
191.1000214	0.90
195.0410767	9.35
197.1879272	0.75
203.0446625	0.39
217.0460510	0.77
218.9811401	4.48
221.1231995	0.28
227.2067719	0.55
230.8973083	0.36
233.1546326	0.23
242.9278564	1.03
245.1342163	2.82
246.8381653	0.59
261.1025085	3.02
263.1335754	4.44
275.3748779	0.25
278.9607544	0.85
281.1198120	7.36
285.8036194	0.67
287.1362610	0.85
288.1394043	0.17
289.1645813	0.49
296.6750183	0.13
297.3397217	1.49
298.9765015	0.65
301.3018494	19.06
302.1008911	14.28
303.1629944	98.15
304.9837036	0.99
315.2006226	7.82
321.0658264	0.59
322.9952393	0.93
327.2372437	14.92
329.1480713	0.34
339.2009888	0.97
343.2574463	0.91
345.1635132	40.04
346.4242554	0.25
351.2609863	0.32
353.1789551	0.67
357.1364746	0.33
363.0484009	0.35
369.2098389	36.14
371.3317261	0.56
381.2407837	4.03
383.0827637	1.54
387.3221436	0.76
389.2355957	1.01
392.8513794	2.39
393.4659424	1.10
395.2255249	3.41
398.6146851	2.15
399.2196045	5.72
403.1584473	0.46
407.2424316	0.61
411.2242432	16.54
413.1815186	34.54
423.1690674	2.33
425.3060913	1.90
429.1732788	20.10
431.2133179	41.12
435.1658936	0.24
437.0996704	1.95
441.0379028	0.66
443.1035767	1.37
447.1046753	100.00
448.5523071	9.80
449.2206421	95.22
453.2731934	1.51
455.2174072	7.79
458.9934082	6.70
461.7681885	0.23
463.0388794	18.68
464.1148682	64.62
465.1294556	87.42
471.1975098	2.46
472.4251099	0.46
473.2288818	5.09
476.9602661	0.99
479.1909180	0.79
489.1665649	20.80
491.0713501	8.38
494.9794922	0.34
497.2528687	5.37
507.1303101	0.36
509.4552612	0.69
513.3729248	2.27
521.0883789	1.50
526.9107666	3.87
530.4512329	0.18
539.2062378	5.90
540.1926880	0.96
557.2082520	30.02
565.6336060	0.36
567.5186157	0.23
575.1481323	24.66
592.5375366	2.86
593.1919556	21.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.2865
Annotation	Unknow
Peak:m/z	Relative Intensity
213.3125153	0.41
250.1831207	0.08
253.1448059	0.14
267.2922058	0.09
269.1962280	0.31
278.9173279	0.04
299.4269714	0.10
301.0235596	0.08
309.1870728	0.24
335.2139282	0.07
341.1458130	0.09
342.1282349	0.25
344.0615845	0.05
345.4508667	0.19
353.2681885	0.07
359.4498291	0.07
360.4812622	0.08
371.4078369	0.58
382.1812744	0.10
401.1450195	0.20
431.5467529	0.15
451.5058594	0.15
455.3140869	1.61
460.6943970	0.77
464.3455200	0.12
465.2822876	0.08
466.5540161	0.23
469.4251709	0.16
472.3579712	0.13
482.7463379	0.28
485.3405151	0.17
490.9125366	0.09
499.3063354	0.52
505.3700562	0.34
506.4061890	0.08
516.5664062	0.13
529.1366577	1.08
535.5867920	0.05
542.3876343	0.18
547.2308960	2.77
562.4883423	0.32
567.2904663	0.09
569.3191528	0.11
570.1071777	0.88
573.1663208	0.22
575.2158813	0.29
576.9793701	0.55
581.4218140	0.08
591.0970459	0.36
593.4915161	0.42
602.9213257	0.25
617.3750000	100.00
618.1104736	0.22
634.6384277	0.45
635.2564697	5.48
641.3570557	0.35
647.0710449	0.05
659.4095459	0.12
663.2535400	3.01
667.3228149	0.15
671.6749268	0.48
677.3211670	9.15
678.4867554	0.15
679.3407593	0.13
680.7476196	0.12
687.4163208	1.20
690.7306519	0.37
704.5897827	0.09
705.5475464	0.13
707.5018921	0.45
723.2715454	37.26
724.0223999	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2032
Annotation	Stecholide J
Peak:m/z	Relative Intensity
161.1102905	0.08
185.2056274	0.10
193.3166962	0.03
201.2553253	0.09
211.0358124	0.02
215.2782288	0.03
217.2133636	0.10
218.2338257	0.03
231.0382080	0.10
241.0856781	0.14
245.1607056	0.03
247.0877533	0.07
257.0183411	0.03
262.0353699	0.04
263.4326172	0.04
265.3026123	0.06
267.0666199	0.05
271.3717651	0.03
273.1395569	0.04
283.3325500	0.11
285.2203064	0.03
286.1790771	0.10
286.9244995	0.03
287.9827271	0.04
293.3931274	0.11
294.2963867	0.23
297.3474731	0.03
307.2075195	0.14
308.5789795	0.03
309.4322510	0.97
311.3109741	0.94
317.2457886	0.05
325.3725586	0.22
327.1174927	0.11
329.0273438	0.04
331.3351440	0.10
335.3610840	1.30
337.5000610	0.08
345.3464355	0.09
347.2611084	0.08
349.9479370	0.13
351.4486084	0.19
353.3571777	6.84
355.3863525	2.21
358.4758301	0.02
365.6864624	0.06
367.1632080	0.09
368.1582031	0.28
369.3085327	0.09
371.4896240	0.07
372.3723755	0.01
373.3653564	0.65
379.0140991	0.76
382.1397705	0.03
385.1711426	0.04
395.2998047	0.10
397.3851318	16.38
403.3649902	0.02
411.4154053	0.42
413.3698730	0.21
415.3767090	1.38
433.5912476	0.03
439.3270874	0.53
441.4137573	0.02
442.2962036	0.06
457.3194580	20.46
459.1311646	0.39
467.5736694	0.01
470.2089233	0.07
473.2957153	0.13
481.2293091	0.03
483.4309692	0.08
485.1450806	0.09
493.4925537	0.09
499.1173706	0.10
501.3229370	100.00
503.4989014	0.04
511.9829712	0.03
525.4630737	0.01
526.4157104	0.09
527.6273804	0.03
530.5104980	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.278
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9562073	0.05
152.9559021	0.06
195.9553528	1.85
214.1125488	0.77
243.1231689	0.01
261.1495972	0.20
279.2643433	100.00
280.4302368	0.04
415.2668762	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.0341
Annotation	Unknow
Peak:m/z	Relative Intensity
112.6719055	0.03
122.8026733	0.14
125.1091919	0.09
128.1201477	0.19
136.9736633	0.23
138.9221802	1.85
142.8713074	0.38
145.2498169	0.04
151.0794983	0.16
152.8511200	0.10
155.0316620	0.05
156.3519745	0.09
164.8906860	0.35
168.9653015	0.24
173.2021179	0.05
179.0714111	0.39
180.1390686	0.02
181.0269318	0.23
183.0695038	0.10
185.2160034	0.02
189.1099396	0.05
190.9875641	0.11
193.0282440	0.02
198.0040283	0.03
198.8563995	0.12
203.0685730	0.13
204.9860535	0.04
206.1726837	0.15
209.1218567	0.69
211.0949860	0.03
213.1419220	0.05
214.9712067	0.11
216.2669373	0.02
217.1290588	0.39
221.2061768	0.07
223.0065308	2.65
240.9703674	100.00
244.0088196	1.15
244.9302063	0.43
249.2003174	0.05
253.9986877	1.52
255.1790161	0.21
271.9658813	1.92
272.8959961	0.28
274.0362244	0.27
275.0432129	0.60
287.8787842	0.34
289.4434204	0.07
290.3241272	0.02
292.9658813	0.26
295.0778809	0.12
299.1608582	1.78
306.1404419	0.02
307.1452637	0.06
308.2630310	0.16
318.1880188	0.21
319.0755310	0.43
330.9866638	0.04
332.4125366	0.08
333.9757080	1.12
335.3010254	0.18
341.1381226	0.83
342.1836853	0.35
343.2165527	0.16
344.2502441	0.10
360.0789185	0.96
361.0339355	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	799.2269
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
225.1315308	0.04
227.1983185	0.13
245.0005188	1.03
255.1131439	0.05
271.1431885	0.39
273.1661682	0.62
278.6984863	0.07
286.9180603	0.20
288.9307251	0.03
295.1635742	0.05
298.0500488	1.38
299.0905762	0.07
301.0092468	4.50
303.2778931	0.14
316.2036743	13.25
329.0794067	0.07
331.1112671	100.00
337.4466553	0.10
340.2370605	0.08
343.1555786	0.30
353.1236572	0.12
355.2593079	0.03
361.3429871	0.19
362.9970703	0.05
369.4113159	0.03
373.2148743	8.54
382.2329712	0.10
383.2419434	0.15
394.9610596	0.15
397.2965698	0.73
409.5528564	0.04
411.1166992	0.07
427.1991577	0.08
429.6376343	0.08
439.2370605	1.81
457.2625122	0.78
469.0733643	0.06
475.2349854	2.55
490.8857422	0.07
493.1358032	60.70
493.8341675	0.04
515.1895142	0.07
520.2258301	0.12
532.5656128	0.07
535.0156860	0.05
548.2834473	0.08
551.3930054	0.04
574.7603149	0.18
575.5555420	0.09
576.5059204	0.13
593.3867188	0.04
601.2614746	0.42
606.4041748	0.07
607.5388794	0.09
610.4776001	0.11
619.3607788	0.58
622.6018677	0.12
637.2600708	15.02
642.3579712	0.21
655.1941528	0.25
659.7584839	0.12
661.2271729	1.75
666.4740601	0.07
679.1896973	5.94
682.8998413	0.11
685.1381226	0.08
692.2726440	0.04
693.6045532	0.07
703.1329346	1.20
714.8406372	0.15
718.0502930	0.07
727.5056763	0.35
737.3211670	0.85
745.2960815	0.22
755.4645386	0.04
763.1810303	0.04
769.6033325	0.07
772.5278931	0.05
781.2412720	8.25
781.9351196	0.12
799.1608276	44.01
799.8882446	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1386
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
134.6271973	0.04
136.9782867	0.10
145.0246124	0.32
151.1389465	0.38
152.9438782	0.65
156.9361877	0.12
162.0366821	0.06
165.1639099	0.11
175.2830353	0.15
176.9919586	1.47
179.0968628	1.18
184.0548401	0.08
184.8314514	0.04
188.9670410	0.14
191.1039734	0.08
192.9686279	0.10
195.0732117	1.51
201.0432434	0.10
202.9151611	0.05
205.1469116	0.04
216.0201416	0.14
219.0920410	1.00
227.4623108	0.11
230.2487793	0.10
230.9531097	0.64
231.8314819	0.05
232.9007111	0.13
234.9339447	0.04
244.4926758	0.08
249.0164185	1.00
253.4067688	0.13
261.0755005	1.55
267.5242004	0.13
271.1865234	0.09
272.7952271	0.04
279.2671204	0.69
285.1595459	0.25
289.2683716	0.19
297.1223755	4.17
299.3429565	0.05
301.1354370	0.98
303.0778198	100.00
312.2225952	0.11
313.2279663	0.21
314.5089111	0.78
315.1834717	3.07
325.1032104	0.54
326.2698975	0.62
327.1896362	2.09
329.5432739	0.23
333.9233704	0.06
343.2872314	1.00
344.2276001	3.15
345.0889893	14.91
347.9916687	0.08
357.2443848	0.15
363.3278809	0.08
365.0050659	0.19
366.5568237	0.18
368.3876648	1.80
369.1333008	11.47
374.2084961	0.26
375.4192200	0.14
381.2795715	0.78
383.1606140	0.58
383.9429016	0.05
386.2679138	0.16
387.3790283	0.27
390.8092041	0.66
392.1447754	0.28
393.3734131	0.58
397.1644592	0.11
398.3303528	5.44
399.2033386	11.62
401.3649902	0.08
409.2315063	0.13
411.0384521	15.83
411.8101501	0.24
419.2201538	0.16
421.4187317	0.21
422.4987488	0.09
428.3873291	6.20
429.1818542	17.28
436.3181458	0.16
446.3868713	20.81
447.2475586	70.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.2745
Annotation	Coproporphyrin II
Peak:m/z	Relative Intensity
184.3029633	0.03
191.2471924	0.07
193.0859833	0.25
193.9155579	0.06
194.8916779	0.08
196.4211731	0.07
201.4733429	0.10
203.2012024	0.05
205.1411438	0.13
205.9223633	0.07
206.9300842	0.59
208.4362640	0.23
209.2714539	0.50
210.2099915	0.72
211.1729431	0.55
219.0569458	0.22
220.1645203	0.09
221.0882416	0.29
223.2002869	0.43
224.1014099	0.29
225.1646118	2.09
226.0669556	1.09
231.2486267	0.11
234.2350159	0.10
235.2957153	0.25
236.3817139	0.10
237.3584900	0.09
238.1587677	0.09
239.0437317	0.92
240.1497345	1.28
241.2285156	1.31
245.3259735	0.36
248.2954102	0.08
249.2048950	0.04
249.9858704	0.09
251.3106689	0.26
252.2776947	0.73
253.1233521	0.40
255.3304443	0.07
256.1765137	0.33
257.3003845	0.12
259.3380737	0.16
260.0780334	0.19
262.2817383	0.23
263.1046753	0.35
263.8818054	0.12
265.1651611	0.61
267.1268616	11.02
268.0188599	0.32
269.3470764	0.27
271.0861206	0.19
275.1834717	1.51
276.2306824	0.29
277.4306641	0.28
278.3261719	0.19
279.2451782	0.13
281.2213745	0.09
282.9459839	0.24
285.2048950	0.05
288.0832520	0.09
289.2525940	0.12
290.1042480	0.16
291.3183594	0.51
292.3060303	0.20
293.2996826	0.91
294.0001221	0.07
295.3692017	0.46
297.1168823	0.17
299.1236572	0.14
303.4967041	0.48
307.3618774	0.30
309.2293396	1.11
312.2951660	0.05
312.9390259	0.08
318.3008423	0.80
321.2596436	10.10
322.1961060	0.10
323.2326965	0.24
324.4284058	0.06
325.2662354	0.25
329.2809753	0.16
332.1117554	0.25
333.4250488	0.47
334.4815674	0.27
336.2019348	0.86
339.2636108	0.17
341.1960449	0.17
343.3482056	0.28
345.3441772	0.04
347.3830566	0.05
351.2492065	0.13
353.2118530	0.19
355.1248779	0.69
355.8016968	0.06
357.1740723	0.61
358.3151855	0.13
361.3139648	0.37
362.2989502	0.12
366.4447632	0.47
369.1400757	0.45
370.1644287	0.16
371.3464355	0.04
376.2045898	0.14
381.3322144	0.23
382.8804321	0.20
383.5189819	0.20
384.8695679	0.14
386.1679688	0.24
387.3162231	0.12
388.2259521	0.22
389.5249023	0.09
390.3856812	0.37
394.3515015	0.09
395.0194702	0.14
397.1481934	0.42
398.5870972	0.11
399.3322144	0.04
400.4396973	0.50
402.2645264	0.28
404.3400879	0.16
406.7191162	0.14
412.2944336	0.28
413.5652466	0.10
414.3007202	0.26
416.4090576	0.45
418.3693848	0.33
420.2951050	0.43
426.8194580	0.90
430.1221924	0.06
434.1288452	0.04
436.3829956	0.19
439.3992310	0.16
442.2645264	0.16
443.7373657	0.63
444.4568481	0.92
446.4734497	1.13
450.3666992	0.13
452.4548950	0.12
456.2601318	1.48
458.2390747	0.14
460.2879028	0.67
461.3191528	0.08
462.5324097	0.38
463.2367554	0.15
464.4535522	0.11
466.2384644	0.25
468.2672729	0.30
469.3871460	0.13
470.4538574	0.36
474.1041870	0.07
476.4688110	0.04
477.2346802	0.07
485.4929810	0.16
486.4271851	0.17
487.0900269	0.09
488.3557739	5.71
489.5038452	0.05
490.3167114	0.50
492.5409546	0.23
493.4398193	0.11
495.4155273	0.17
497.7143555	0.21
498.5122681	0.04
500.3824463	0.22
502.1093750	0.21
503.0285034	0.14
504.6231689	0.15
506.4929199	0.19
507.3275146	0.14
508.3400879	0.54
509.5946655	0.21
511.1724854	1.23
512.1410522	0.38
514.4924316	0.13
518.6325684	0.58
520.0895386	0.18
521.4802246	0.78
523.2368774	0.23
525.3910522	3.08
526.3864746	0.43
531.3803101	0.06
532.5370483	0.11
534.3771362	0.60
535.6078491	0.84
536.3875732	4.96
537.5054321	0.34
538.1506348	0.22
540.2433472	0.29
544.1912842	0.04
545.8837891	0.06
548.7128296	0.32
549.5014648	0.12
551.4133911	0.99
552.3602905	1.97
553.3750610	2.38
555.2000122	0.14
559.3040161	0.10
561.4225464	0.17
563.4359741	1.90
564.4369507	0.14
565.2374268	0.11
566.7022095	0.15
567.4912720	2.18
568.4221191	3.21
569.5510864	0.82
570.5325928	0.20
573.4133301	0.26
577.4042358	0.80
579.4387817	2.10
580.3163452	7.10
581.4345703	3.17
582.9224854	0.33
584.3115845	8.82
585.3286743	0.67
586.6442871	0.05
587.5686646	0.49
588.4453735	0.22
591.4555054	0.93
595.4104004	13.30
596.7645874	0.37
597.4734497	0.36
598.6948242	0.66
599.5371094	1.61
605.4014282	8.27
606.3880005	0.27
609.4202271	3.05
612.3234863	100.00
613.4484253	40.97
619.1596069	0.15
620.4119873	0.07
622.4564209	4.32
623.3887329	80.58
624.1519165	0.84
626.2922974	0.23
627.4025269	10.76
628.0062866	0.06
637.3954468	80.63
638.1188965	0.64
640.2632446	5.90
640.9985352	0.25
656.4748535	4.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.1748
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
235.2628174	0.07
273.2241516	0.11
283.2377930	0.06
311.1042175	0.10
330.0649414	0.03
337.1809082	0.57
343.3116455	0.06
352.2117004	0.11
355.2529907	0.78
362.2918701	0.03
367.1930542	1.90
368.5164795	0.11
379.1474609	0.31
385.2066040	3.17
391.2929688	0.10
402.2950439	0.19
409.1615601	3.68
409.7628784	0.07
410.4369507	0.04
412.4040527	0.02
415.2365723	0.07
421.2407837	0.75
426.7247314	0.19
427.5530396	0.07
433.2489624	0.53
439.0668945	3.23
444.2580566	0.13
445.2687988	0.44
451.1913452	3.99
457.1508179	0.21
462.9364624	0.09
463.6824341	0.14
465.3406982	0.05
469.2406616	3.48
475.9523926	0.17
480.7135010	0.17
483.2760620	0.06
487.2650757	38.83
489.1824951	0.03
493.2174683	0.40
495.7578735	0.04
499.4301147	0.15
505.2070923	11.47
505.8406372	0.06
511.3317871	5.73
512.9540405	0.03
516.3383789	0.05
517.2245483	0.06
523.5550537	0.05
525.1662598	0.07
529.2071533	4.61
530.9779663	0.55
535.2223511	0.06
537.2732544	0.53
541.3743286	0.22
543.1950684	1.13
547.2406616	0.52
549.2119141	0.58
549.8732300	0.26
553.2962036	8.63
555.2360229	5.30
561.0327148	0.69
565.4446411	0.55
571.2294312	1.52
573.2942505	37.74
575.0907593	0.17
577.3435669	0.30
583.1930542	1.18
589.3021851	1.01
591.1361694	20.31
591.7553101	0.02
595.0789185	0.78
597.2935181	4.26
601.1345825	0.10
607.1951294	1.38
609.1329956	0.79
613.1796875	1.35
615.3147583	8.46
620.6680298	0.15
621.3561401	0.29
625.4365234	0.55
627.2400513	11.88
631.2321777	2.18
639.1742554	4.19
639.8337402	0.42
645.2296143	12.07
649.2233276	1.38
657.2789917	24.81
664.3726807	0.11
675.1823730	50.12
675.8448486	0.19
693.1608276	100.00
693.8756714	0.45
711.2843628	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	254.1746
Annotation	Unknow
Peak:m/z	Relative Intensity
86.7811508	0.08
90.9206619	0.01
106.8774414	0.05
108.1849823	0.01
109.8951874	3.52
112.2222748	0.02
122.9631653	0.02
124.9311066	0.01
133.0306549	0.01
136.0401917	3.56
149.9280396	0.01
151.0051270	0.03
153.9647827	1.41
154.6441193	0.02
168.0936432	3.94
178.0780945	1.35
182.0666809	0.03
190.1425629	0.04
194.0263824	0.01
196.0670471	100.00
196.6886292	0.23
206.0582886	0.20
208.0841675	0.01
209.2082367	0.02
217.9764862	0.11
225.0260010	0.02
236.0069580	0.40
237.0109100	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.162
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
193.2713013	0.05
203.0463409	0.06
208.6679535	0.11
213.4759979	0.03
227.2110443	0.05
228.0259705	0.02
229.3080292	0.05
244.9928284	0.07
258.2760620	0.04
261.1227417	0.03
267.2627869	0.02
271.2008057	0.41
271.9623413	0.04
284.2894592	0.06
285.4227905	0.04
299.0955200	3.13
300.1096497	0.60
305.1428833	2.68
306.2595215	0.12
310.2592773	0.11
312.9556885	0.53
314.0908813	16.47
315.1990967	2.18
316.2989807	0.02
323.2114868	0.08
326.4522095	0.14
327.1730347	0.26
328.1098633	1.11
329.1171570	98.51
330.2086792	8.91
331.0838013	0.02
339.2132568	0.71
341.3418579	0.04
342.3277588	0.20
343.2104492	0.18
344.1595459	0.02
351.1154785	0.58
352.2764282	0.17
355.1255493	0.05
356.0828857	0.16
369.0701294	0.03
371.1189575	9.09
372.1773682	1.10
380.2926025	0.24
380.9934692	0.09
383.4676514	0.04
385.5196533	0.02
395.2112427	0.36
396.0374146	0.05
411.2368164	0.12
413.1062622	0.14
443.2897949	0.03
455.2117310	0.22
460.3721313	0.03
461.1455078	0.04
462.3378906	0.03
473.1911621	1.26
474.3847046	0.04
476.2649536	0.06
477.2748413	0.12
478.3374023	0.02
480.3050537	0.13
491.2112427	100.00
492.1962891	11.39
492.8355713	0.03
515.5371704	0.18
519.3154297	0.15
533.2026978	42.89
534.3381958	7.10
573.3093262	6.28
574.3810425	1.21
576.4139404	0.03
586.5005493	0.03
591.6361694	0.03
617.3428345	0.10
636.0697632	1.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1635
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
311.3532715	0.16
312.8558655	0.12
325.1428223	0.31
329.0886230	0.37
337.1569214	0.13
348.9950562	0.15
352.9303589	0.10
355.2890625	1.51
361.0942383	0.18
379.1261597	1.49
409.2024536	3.61
415.2372437	1.02
421.2365723	2.09
427.2065430	1.17
433.2503052	0.66
437.2237549	0.06
439.2022705	1.10
445.1961670	1.15
457.1395874	55.78
457.8413086	0.11
463.0827637	0.07
475.2527466	12.95
481.2881470	7.27
493.2084351	0.44
499.2219849	9.28
505.2111206	0.25
511.2109375	18.97
523.2597046	10.20
529.2158813	22.15
541.1994019	12.36
559.1970825	37.16
559.9248657	0.04
577.2336426	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1746
Annotation	Epijasminoside A
Peak:m/z	Relative Intensity
104.9995575	0.21
107.0856476	0.36
108.9920197	1.75
110.9056778	0.79
113.0422897	0.41
114.7474213	0.16
118.7654572	0.06
121.0029602	0.30
122.9740906	2.09
124.9876251	0.07
126.8723602	0.39
130.8852692	0.03
132.9034119	0.04
139.0235901	1.64
139.9784851	0.24
141.9835510	0.07
145.9751892	0.07
148.0638733	0.14
149.1770935	0.07
151.0173035	2.81
152.7586670	0.10
160.7182312	0.10
164.0692749	0.24
169.0077667	100.00
171.0164795	0.08
175.0140686	0.07
177.2134399	0.10
179.2052917	0.06
185.1526794	0.16
186.2508545	0.15
189.0795593	0.23
190.1439209	0.10
192.1938934	0.20
195.1015320	0.34
196.9228973	0.05
201.2644653	0.13
207.1601410	0.10
211.2962341	0.06
214.0830994	0.05
225.2378845	0.10
241.7735291	0.06
242.8663940	0.09
247.2091980	0.16
251.1670532	0.86
252.1056824	0.20
253.0074463	0.33
254.7641296	0.21
263.0466309	0.05
264.1286926	0.31
265.2733459	0.07
266.1029053	0.05
267.3082886	0.04
269.1926270	0.24
271.2629089	0.37
272.6303711	0.04
273.3189087	0.07
275.1965942	0.06
281.2658997	0.35
285.1206055	0.40
287.2196655	0.73
289.2209778	0.12
290.6876831	0.16
295.1027222	1.14
298.8768311	0.28
303.1630554	0.09
304.2753906	0.12
312.5539246	0.73
313.1845093	3.34
313.8873901	0.15
316.0688171	1.83
317.2388306	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	469.2795
Annotation	Lenacil
Peak:m/z	Relative Intensity
135.2112122	0.13
146.9430847	4.29
149.0496368	0.18
151.0752716	0.16
156.0239258	0.18
167.2350464	0.14
183.0118103	0.22
184.0879974	0.18
185.1290588	0.09
186.1113586	0.09
190.7356873	0.09
202.3098602	1.07
203.1175232	0.13
207.1629028	0.12
212.0621033	0.52
214.9389954	0.33
218.1124878	11.31
220.0487976	3.99
221.0964966	3.10
230.1761780	0.11
235.1145020	100.00
235.7483673	0.44
250.1095581	0.08
269.3254089	0.11
271.1345520	0.07
288.8128052	0.07
306.1957703	1.30
307.3006592	0.63
309.0070190	0.11
325.2190857	0.35
329.3999939	0.38
348.4359436	0.14
351.2098389	0.19
354.3379822	0.58
355.2269287	0.53
357.0274353	0.12
379.2178650	0.40
380.2416687	0.88
381.3552551	0.46
384.4274902	0.28
404.3404541	0.06
407.0243835	0.16
415.2206116	0.06
418.2195435	0.34
423.2683411	0.08
425.1305847	0.08
431.1706543	0.07
432.4072571	0.96
438.9524231	0.15
449.2670898	0.22
450.4273071	2.04
451.2313538	3.74
452.0237732	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1819
Annotation	Creoside IV
Peak:m/z	Relative Intensity
112.9976501	0.09
125.1168213	0.03
158.6845703	0.07
161.0041351	3.90
178.8784332	0.14
179.8871918	0.05
197.3025360	0.04
210.7903748	0.08
215.3750000	0.04
229.1353455	0.05
241.4569702	0.03
247.1686096	0.04
260.9212952	0.09
289.1757507	0.03
297.4414673	0.16
302.3121338	0.07
305.4587097	0.03
313.3413696	0.14
315.3222046	0.12
316.1246033	0.11
317.2807617	0.28
331.1736450	100.00
332.0391235	0.10
333.0740967	0.13
334.1968994	0.17
341.2615662	0.41
342.3276062	0.17
344.2179871	0.07
345.3746338	0.05
359.0830078	0.30
361.2196350	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1462
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
177.1007996	0.03
257.1239624	0.02
297.3583374	0.04
298.2085571	0.07
309.0567017	0.03
315.1458740	0.03
327.1477051	0.14
328.3405762	0.21
337.5375977	0.05
339.1301270	0.13
340.1394653	0.18
341.2981567	0.03
357.1964722	0.29
359.6373291	0.02
360.8339233	0.02
367.0115356	0.11
369.1429443	18.88
370.2051392	3.84
371.4488525	0.24
379.2702026	0.08
380.3524170	0.07
381.1427002	0.61
382.0994873	0.13
383.0310669	0.06
386.0999146	0.08
394.1445923	0.03
395.2683105	0.11
397.2171021	0.18
399.1866455	19.36
400.2824707	6.34
401.0270386	0.07
403.2449951	0.14
409.2930908	0.06
410.1931763	0.03
411.1284180	1.68
412.1833496	0.43
413.2334595	0.70
414.1841431	0.22
423.1760254	0.22
425.2521362	0.32
426.3771973	0.03
427.5150757	0.07
429.2214966	7.57
430.3178101	1.19
435.0300903	0.26
435.6961060	0.04
436.4254761	0.06
441.1895752	0.95
442.2104492	0.64
443.2778931	0.27
447.2980957	0.87
451.5653076	0.02
453.1104126	1.03
454.1649780	0.11
459.2849731	0.65
460.2068481	0.17
465.2155151	0.48
466.1058960	0.11
471.3000488	6.68
472.1710815	1.96
472.7753906	0.06
475.2479858	0.04
476.2044067	0.03
476.8198853	0.05
479.4861450	0.03
483.2675171	0.59
484.2199097	0.06
485.4701538	0.09
487.3463135	0.30
489.1751709	100.00
490.2684937	23.32
491.5595703	0.03
495.3029785	0.06
496.3258057	0.07
499.3049316	0.05
501.3504028	3.82
502.3634644	1.24
513.4605713	0.21
514.1807251	0.05
516.2223511	0.09
519.2442017	25.28
520.2824707	5.55
527.1958618	0.02
529.3429565	0.01
531.2242432	1.91
532.2175293	0.28
533.2023315	0.15
534.2545166	0.07
537.2396851	0.15
538.1439819	0.11
543.3361206	0.06
549.3234253	0.28
550.0741577	0.11
555.4152832	0.61
556.3860474	0.55
561.4152222	0.59
562.3509521	0.32
565.2963257	0.12
573.2364502	1.37
574.3493652	0.45
579.1571045	0.02
580.2836304	0.06
591.2139282	6.78
592.3237305	1.92
610.2356567	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	413.1664
Annotation	Unknow
Peak:m/z	Relative Intensity
122.1008453	0.02
137.1555176	0.02
144.0778809	0.03
147.1860962	0.01
148.9744568	0.01
161.0418701	0.04
174.8787842	0.02
178.8027496	0.03
186.8104858	0.01
188.1035156	0.05
188.9447327	0.02
202.9988708	0.02
215.2005615	0.03
220.2136841	0.04
221.0488739	0.17
241.2534790	0.02
243.2419739	0.05
250.0750122	0.06
251.0127563	0.19
259.2430115	0.01
262.5231018	0.02
273.3998108	0.03
277.1241455	0.02
284.2997131	0.19
294.3125000	0.07
298.0906372	0.12
299.0329285	0.03
308.1574707	0.06
315.1855469	0.15
317.1323547	0.01
318.1452332	0.01
318.8858032	0.03
323.3097229	0.04
325.2172852	0.06
335.5709534	0.03
337.3519287	0.13
338.3282776	0.04
345.2631836	0.09
352.3425903	0.03
353.3789978	0.02
365.3332214	0.07
367.1806335	100.00
368.2006226	0.03
369.1546021	0.13
375.2743835	0.02
376.2005310	0.02
380.2161865	0.04
385.1805115	0.07
387.4732056	0.04
395.1621094	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.1717
Annotation	Aristoquinoline C
Peak:m/z	Relative Intensity
160.9429932	0.03
161.9430542	0.03
195.0624084	0.06
215.0749969	0.03
232.1375122	0.02
238.2145233	0.05
243.1247559	0.03
256.0546570	0.22
257.1312866	0.12
258.8254395	0.02
264.2159424	0.01
270.1648865	0.03
272.3112488	0.02
275.9428406	0.03
282.2168274	0.51
283.4156799	0.03
285.2319641	0.17
295.2116089	0.17
298.2419128	0.39
300.2007141	18.21
301.1439209	0.75
302.1173706	0.04
312.1757812	0.58
313.2388000	0.51
314.2151794	0.13
339.3750000	0.14
340.3550415	0.21
341.1893616	0.01
342.0913086	0.05
343.1228638	0.06
352.3023682	0.07
353.2142639	0.01
356.0366516	0.07
357.2245483	2.07
358.2359314	0.85
375.1363220	0.06
375.8184814	0.01
376.4665833	0.03
387.3801270	0.03
388.3547363	0.02
391.2750549	0.08
400.3797302	0.12
402.3156433	5.27
403.2505798	0.19
408.1697083	0.02
417.2483826	0.05
418.4038391	3.05
420.2822876	100.00
421.3751221	4.02
426.0905457	0.02
427.1845703	0.08
428.2998962	0.11
432.5229187	0.03
433.8147278	0.04
446.2310181	6.16
447.4016724	0.21
448.1411133	0.11
465.3041382	4.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.192
Annotation	Myricatomentoside II
Peak:m/z	Relative Intensity
181.2309723	0.01
196.9866943	0.01
201.4479523	0.03
213.2869568	0.02
227.3753052	0.02
229.1282654	0.02
241.3984680	0.01
255.3824463	0.02
265.3737183	0.02
278.2683716	0.02
283.0365906	0.02
295.1605530	0.02
297.4813843	0.04
305.2037964	0.02
306.0666504	0.02
313.0671387	0.10
320.8845215	0.02
323.4729004	0.02
329.1715088	0.07
339.3092041	0.02
347.3382568	0.11
351.5468750	0.03
353.2005615	0.04
357.3090820	0.06
367.4445190	0.05
369.3104858	0.02
375.2716675	0.02
377.5684814	0.04
383.4560547	0.05
395.3848267	0.02
397.2996216	0.03
405.6034546	0.02
409.3457031	0.01
411.2847900	1.55
427.3384399	2.68
439.3952637	0.01
453.1386108	0.39
469.2177124	100.00
469.8488159	0.31
471.3866577	5.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1126.5586
Annotation	Plusbacin B2
Peak:m/z	Relative Intensity
696.6613159	0.38
726.4987793	0.51
736.3895264	0.05
997.9832764	0.07
1126.1632080	100.00
1127.2669680	30.85
1128.1868900	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.9395
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8307953	0.02
158.9865112	2.11
199.1271667	0.03
217.2745819	0.03
229.0124817	0.53
245.0069275	0.01
256.0872803	0.02
256.8833313	0.02
271.0770264	0.24
272.9334106	100.00
274.1828918	0.03
298.0785217	0.02
333.0160522	0.06
343.1541138	0.08
344.3020020	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1127.29
Annotation	Unknow
Peak:m/z	Relative Intensity
519.2312012	0.02
545.5638428	0.05
561.1534424	0.01
765.5987549	0.02
1061.4836430	0.01
1108.7338870	0.04
1126.4162600	20.16
1127.3035890	100.00
1128.0079350	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.24
Annotation	Unknow
Peak:m/z	Relative Intensity
218.1793671	0.01
229.1542358	0.02
239.3056641	0.03
240.1245422	0.02
241.1020050	0.03
242.1394348	0.10
254.2771912	0.06
257.1838989	0.05
258.0977173	0.03
264.2451172	0.02
267.3551025	0.02
268.1781616	0.08
269.3118286	0.01
282.4593201	0.03
283.1822205	0.17
284.0916138	0.24
285.0097351	0.08
286.1909790	0.25
297.2117004	0.08
299.1571960	0.36
300.1481323	0.43
301.2232361	6.19
301.9599304	0.08
307.2198486	0.03
309.2336121	0.02
315.1490479	0.03
325.0497131	0.49
325.8715515	0.06
327.1652527	0.01
327.7862549	0.01
331.0846558	0.03
341.1554565	0.02
343.1783752	0.20
352.1689453	0.04
367.1075439	0.05
397.5525513	0.04
403.1701660	0.01
409.3287964	0.02
411.1856079	0.08
427.3361816	0.02
428.3876953	0.11
429.3336792	0.13
443.4928589	0.01
447.3117065	0.02
448.1883545	0.05
461.2411499	0.21
462.3729858	0.33
463.4462280	0.04
464.2033691	0.03
473.6425781	0.01
475.0292969	0.09
489.4082031	0.05
493.2250366	0.05
527.6098022	0.04
571.2649536	0.02
573.2906494	0.02
576.3248291	0.04
577.3994141	0.13
590.9191284	0.14
591.5459595	0.07
594.3356934	0.10
595.5269165	0.11
603.5902100	0.01
608.1588745	0.34
609.2946167	1.35
617.4862671	0.03
621.5642700	0.11
635.3475952	0.02
647.5828247	0.22
650.2235718	0.12
651.3057251	0.19
685.4482422	0.02
703.2461548	0.06
726.6268311	0.02
738.3099365	0.02
753.3206177	0.21
756.4924927	0.05
771.3682251	100.00
772.3367310	2.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	591.26
Annotation	Serrulatoside
Peak:m/z	Relative Intensity
177.2239380	0.22
184.9106293	0.08
237.1729736	0.16
246.4256897	0.16
253.2693024	0.19
295.3245544	0.07
327.3241577	0.40
341.3159790	0.23
386.7587280	0.06
393.1956177	0.42
429.9367676	0.23
434.1083984	0.27
446.1548462	0.22
448.3859253	0.53
449.2677612	0.19
458.4849243	0.07
459.3893433	1.93
460.5331421	0.99
462.6157837	0.24
471.5072021	0.18
473.5110474	1.26
474.3475342	1.39
475.3079834	3.30
476.5805664	0.22
485.4624634	1.38
486.8054810	0.48
487.4783325	4.21
488.4331665	1.69
489.5829468	0.93
490.4522705	1.14
491.2705078	0.67
492.3784180	0.83
502.2156372	1.14
503.4552612	5.14
504.4583130	1.10
505.3589478	0.84
506.5917969	0.33
513.4282837	0.10
514.4539185	0.31
515.4515991	6.34
516.2900391	1.36
518.3242798	1.87
519.4696655	2.04
520.6116943	1.86
521.7087402	0.35
531.3919067	100.00
532.3789673	40.30
533.4765015	4.24
538.4174805	0.14
541.3640747	0.33
544.4273071	0.29
545.4948730	0.52
547.2793579	3.07
548.4892578	0.93
549.5980835	0.84
550.5942993	0.45
559.4218750	3.87
560.4362183	1.63
562.2251587	0.38
563.4426880	2.13
564.5276489	0.90
573.5874634	0.25
577.1181030	0.50
592.4974365	26.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0823
Annotation	(-)-Usnic acid
Peak:m/z	Relative Intensity
114.8636169	0.02
141.1174164	0.01
142.0414581	0.03
145.0230408	0.01
160.7610168	0.04
165.1114807	0.02
173.1872864	0.02
175.0363464	0.04
186.7740326	0.03
187.988205	0.04
190.0989075	0.05
193.2062683	0.05
195.16539	0.02
201.2217102	0.06
202.1138	0.02
203.973587	0.01
207.0913086	0.03
213.4260254	0.01
225.2967834	0.03
229.6686096	0.04
233.3671875	0.02
234.2849121	0.06
235.0753784	0.01
237.037384	0.04
243.1361389	0.03
244.5623779	0.01
247.2329712	0.01
249.1329041	0.08
250.2415771	0.01
254.5571289	0.05
256.3836975	0.05
257.1876831	0.10
260.9345703	0.05
267.2329102	0.05
269.3373413	0.12
270.0213318	0.01
273.3079224	0.01
281.2361755	0.11
282.1777954	0.20
283.1287537	0.08
285.1565247	0.10
286.4712219	0.02
296.0144043	0.03
297.293335	0.08
298.2779236	0.03
299.2276917	0.25
300.2964478	0.27
301.1335144	0.13
307.4236145	0.12
309.7947693	0.02
310.9920654	0.15
312.0143433	0.32
313.144165	3.10
314.1213989	1.06
315.1392212	0.22
316.1190796	0.06
323.6865234	0.05
325.3008423	1.04
326.3872375	0.93
328.067749	100.00
329.1486511	40.19
329.9239197	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.19
Annotation	Unknow
Peak:m/z	Relative Intensity
173.9852905	0.14
175.1641083	0.31
176.2210236	0.06
177.1093750	0.16
178.0599823	0.05
186.0874939	0.07
188.1499329	0.13
192.9318695	0.17
194.0759277	0.13
197.8873138	0.24
199.0825500	1.31
200.0534058	1.53
201.0101166	0.73
202.0692139	0.39
204.0325317	0.40
205.0569916	0.18
211.0029602	0.06
212.9493561	0.16
214.1895752	0.48
214.9937592	0.75
215.9954987	0.76
216.9890900	0.68
217.9405823	0.28
219.1125031	0.10
223.1047363	0.03
223.9826965	0.10
225.1588593	0.48
226.5383606	0.27
227.2315063	0.43
228.1106720	1.07
229.8609619	0.06
231.2003174	0.06
233.1665039	0.04
235.0487671	1.90
236.0595856	1.07
236.9641418	0.05
240.1275482	0.52
241.1922760	0.30
242.0403442	1.41
243.0544891	1.38
244.0175781	0.38
251.3467102	0.09
252.0048370	0.12
253.0948486	0.14
255.3036346	0.15
257.2832336	0.59
258.1724854	1.35
259.1072998	0.51
260.0416565	0.03
268.0184937	0.30
268.9423828	0.28
270.2263184	0.16
271.2266846	0.26
276.9190979	0.09
278.1638794	0.37
279.1281738	0.08
280.1853943	0.14
282.9801636	0.26
284.1340942	1.12
285.1530151	0.45
286.1455688	2.49
287.0899353	3.06
288.1526794	0.05
293.2141113	0.16
297.1043701	0.17
298.4125977	0.45
299.3944702	0.10
301.1689148	92.01
302.1388550	100.00
303.0906372	13.17
307.1313477	0.08
311.0792236	0.27
312.2434692	0.16
314.4184570	0.06
315.4158936	0.03
323.1559753	0.17
325.2445679	1.50
326.1706543	1.98
327.1713867	0.41
336.2006226	0.11
337.3849487	0.05
338.0775146	0.20
339.2677002	0.59
340.2042236	0.87
341.2864380	0.04
343.1138916	3.06
344.2578735	7.95
345.2158203	1.29
355.1358032	0.15
357.0408325	1.05
357.9644775	0.79
359.3839111	0.30
364.2438354	0.14
366.9709473	0.09
368.2203979	0.15
373.3374023	0.07
374.2334595	0.62
385.1620483	0.18
386.1154785	0.16
397.2789917	0.13
399.0899048	0.10
403.2334595	0.17
404.1729736	0.99
405.2278442	0.24
410.5499878	0.07
411.2655029	0.27
428.5261230	0.17
430.3394775	0.27
431.3834229	0.04
434.2767944	0.10
441.1539917	0.13
442.2939453	0.61
443.6173096	0.04
445.1444092	0.21
446.6248779	0.16
447.3015137	0.28
448.2900391	0.73
449.0047607	0.07
459.1417236	6.84
460.1912842	13.41
461.2773438	3.59
464.4349976	0.06
473.3469238	0.25
474.3311157	0.70
486.0064697	0.25
489.2977295	0.96
490.2189941	5.77
491.4059448	1.48
560.4224243	0.30
561.4663086	0.12
595.0598755	0.20
611.1165161	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0827
Annotation	Methyl gallate 3-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
131.1407623	0.12
136.9426270	15.18
160.3834229	0.06
163.0523071	0.06
163.8613739	0.14
165.0507507	0.30
167.9674377	0.16
177.3289795	0.10
178.1281433	0.06
179.0346375	0.19
180.1981354	0.12
181.0573425	0.04
183.0176239	0.82
199.2081451	0.03
204.9282227	0.09
206.0667114	0.07
207.2335510	0.14
209.2262268	0.07
211.0400085	0.03
212.0175476	0.03
216.2026978	0.02
220.8796692	0.04
225.2560730	0.22
226.9916687	0.06
228.4708862	0.04
229.3824463	0.22
243.4019775	0.12
253.1813049	0.36
254.1291199	0.44
255.0740662	0.47
258.5874634	0.06
259.3150330	0.07
268.3534546	0.09
270.9022522	0.08
272.1805725	0.05
281.2225952	0.05
283.2882080	0.09
284.2726440	0.02
285.1783447	0.29
299.1087952	100.00
300.2977295	0.15
301.1831970	0.07
314.0374146	0.05
325.9014587	0.08
326.9256592	0.59
329.1473999	0.50
330.1668091	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0718
Annotation	KOPARIN 2'-METHYL ETHER
Peak:m/z	Relative Intensity
127.2957306	0.04
136.6465302	0.16
146.9978485	0.03
155.1839752	0.04
161.0812531	0.02
168.9877625	0.01
171.2008362	0.03
175.0574188	0.05
177.9948883	0.11
183.4848633	0.01
185.1298828	0.02
185.797699	0.03
192.9804993	1.16
195.2419739	0.05
197.0939636	0.05
201.2071228	0.07
204.1829529	0.05
214.1043396	0.04
219.1697083	0.06
223.2278442	0.04
224.850769	0.07
225.929718	0.01
227.2644958	0.02
239.0677795	0.03
241.2241821	0.05
242.1322327	0.07
245.4457092	0.02
251.3671875	0.03
253.4047546	0.16
254.9663086	0.02
257.2177124	0.02
267.1640015	0.83
268.4406738	0.04
269.4421997	0.70
270.0909424	3.08
270.8720703	0.02
281.230011	0.06
282.1630859	0.22
283.1119995	2.64
285.0454407	6.95
293.4225769	0.02
295.1004639	2.91
298.0561829	100.00
298.6861267	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.1643
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
218.9260559	0.08
267.3544922	0.05
297.4641418	0.08
307.0049133	0.35
308.0429077	0.07
310.2321777	0.07
313.3477478	0.30
314.1970825	0.02
319.2079468	0.05
321.3432007	0.03
325.3091125	0.03
326.1330261	0.08
335.2629395	0.11
337.1637573	1.99
338.3247070	0.82
349.1669922	0.14
351.1093140	0.11
355.1589966	3.12
356.2111206	0.63
361.0317993	0.07
367.2807007	0.05
368.0867310	0.03
372.3703613	0.04
373.2396851	0.27
374.6719360	0.02
379.2068481	2.30
380.1983643	0.74
391.3770752	0.42
392.1192017	0.11
393.4675903	0.16
397.3656006	0.08
404.4826660	0.06
409.1211548	0.43
410.3135376	0.22
421.2059326	3.27
422.2943726	0.82
427.2272339	0.13
428.1322632	0.26
428.9336548	0.10
433.1112061	0.66
434.4135132	0.08
439.1921997	1.14
440.2188721	0.45
445.1346436	0.41
446.3278198	0.08
457.2180786	14.51
458.2666626	4.60
463.2036133	0.54
464.0565186	0.09
466.5281982	0.20
475.1848755	18.56
476.2640381	4.91
481.2650757	11.41
482.2453003	3.73
483.1928711	0.34
484.3364258	0.09
488.3827515	0.15
499.2485352	6.23
500.2285767	2.82
501.1542969	0.78
502.2319946	0.52
505.2858887	0.25
506.2163696	0.07
507.2802734	0.05
508.2890015	0.47
511.0419922	0.59
512.2639771	0.16
513.1439819	0.15
514.1047363	0.10
517.4036255	0.05
519.3298340	0.80
520.3355103	0.37
523.2760620	14.05
524.2328491	5.77
525.2069092	6.63
526.2114868	2.76
529.3320312	0.84
531.5609131	0.22
536.0971680	0.03
541.1496582	2.34
543.1563110	69.69
544.1965332	23.58
544.8380127	0.04
548.2084351	0.06
549.2042236	0.13
550.2717896	0.17
553.2277222	0.04
555.5936890	0.06
559.1911621	1.36
561.1178589	10.30
562.1120605	3.53
562.7937012	0.20
565.3076782	0.39
566.2901611	0.30
567.1947632	0.82
568.1481323	0.70
572.1351929	0.14
574.3839722	0.14
576.3029175	0.05
577.2793579	3.23
578.2418213	0.96
579.0579834	0.13
580.1677246	0.05
583.3359985	0.45
584.2659912	0.53
585.1525879	0.51
586.2648315	0.61
591.3864136	0.11
592.0928345	0.15
595.1536865	0.83
595.9786377	0.13
597.1144409	1.07
598.2868652	0.32
601.1951294	1.10
602.3185425	0.36
609.2102051	1.52
610.2739258	0.87
615.1236572	0.77
616.2807617	0.73
618.4328003	0.17
619.3277588	0.25
620.1002808	0.25
627.1775513	24.29
628.2688599	13.12
630.4382935	0.20
631.4858398	0.12
637.5285034	0.04
645.2015991	43.44
646.2080078	20.35
646.8387451	0.04
663.1701050	100.00
664.1674805	39.47
664.8703003	0.15
682.1239624	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	336.8587
Annotation	Unknow
Peak:m/z	Relative Intensity
102.3291473	0.21
102.9352875	1.89
144.8245087	0.08
146.8897705	18.02
188.9233093	0.32
190.9272003	100.00
191.9022522	0.17
192.7932281	0.12
203.0812988	0.03
218.8890991	0.46
234.0119629	0.04
246.8243103	0.54
248.8191223	0.15
251.1750183	0.12
254.9165649	0.10
258.7479248	0.12
260.8429871	0.08
262.8912354	14.51
265.0375366	0.11
269.1773376	0.03
280.3018188	0.19
280.9024963	1.13
282.6519165	0.12
290.0855713	0.07
290.9021301	0.96
292.8295288	59.17
309.0107422	0.07
319.0449524	0.15
322.1987000	0.06
324.9500732	0.16
336.7123718	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.1974
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
145.0531006	0.22
145.7097778	0.06
147.0530243	0.18
149.1997833	0.55
151.0664215	0.07
153.0413666	0.10
155.1089783	0.42
157.1010895	0.28
159.0120544	0.34
161.0459595	1.07
162.9673157	1.01
171.0324707	0.88
173.1148376	0.77
174.9877930	1.22
177.1296539	0.25
179.1266937	0.23
181.1289062	0.33
185.0428162	0.97
186.0730286	0.09
187.1782532	1.13
189.1847076	2.76
190.8251038	0.33
193.3384094	0.18
197.2662659	0.15
199.2397766	1.75
201.2940369	0.44
203.4061737	0.07
204.9555969	0.33
207.3049622	0.07
209.1972351	1.86
211.1908264	0.64
212.0237732	0.16
213.3271790	0.22
214.9418030	0.76
217.1628113	2.46
219.1262207	0.80
224.0448914	0.09
225.3982849	0.15
227.2445221	15.48
229.3504639	0.17
230.1469421	0.07
230.9662476	0.47
233.1861877	2.84
235.2847748	0.26
237.3091431	0.15
239.1831360	0.08
241.2176514	0.44
243.1918335	1.17
245.2420502	20.93
251.2929077	0.37
253.0915222	0.25
254.9849854	0.12
257.2922058	0.31
259.2757568	0.45
261.1297913	0.67
263.1595764	6.19
266.4229126	0.09
267.3143616	2.44
269.2798462	1.18
271.2970276	0.05
273.2606506	0.23
275.2204285	2.68
277.2628479	0.14
279.2625427	0.19
283.2212219	0.19
285.2265625	3.86
287.0614319	0.70
287.6776123	0.02
289.2532043	0.71
295.4140625	0.34
297.3852844	3.26
299.1874084	0.23
301.4045410	0.28
303.2320557	2.92
309.3869934	0.04
313.2919922	0.51
315.5161743	0.04
317.3050537	0.80
319.3446045	2.85
321.2822876	0.28
323.1191711	0.22
323.7540894	0.17
325.1523438	0.10
326.1890259	0.87
327.2979736	0.13
329.1474609	3.02
329.7615051	0.06
333.2131348	0.71
339.1959839	0.52
341.3228760	20.98
345.2301636	0.62
347.2197876	100.00
347.8506470	0.19
355.4045410	0.60
356.3862915	0.05
357.5534058	0.12
363.2258301	3.44
365.3728638	0.15
371.4038086	0.14
375.2697144	0.25
381.3191833	0.03
383.6952209	0.05
385.3486938	0.94
391.1974182	1.35
397.4336243	0.08
399.1303711	1.12
401.1841431	0.71
407.2245178	0.04
425.2509460	0.21
427.1148071	0.26
429.5363159	0.20
441.2668762	0.15
443.3769836	8.84
448.3689270	0.09
459.4449768	0.62
469.4996033	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	799.413
Annotation	Phakellistatin 13
Peak:m/z	Relative Intensity
228.8538666	0.11
232.2616119	0.18
237.2126312	0.34
250.2788391	0.03
251.1572266	0.07
252.2091064	0.28
253.2973328	0.04
256.1261597	0.23
259.1344910	0.10
262.1939697	0.17
267.1336365	0.05
273.1926270	0.28
273.9673767	0.05
276.4228210	0.07
280.1424866	0.46
285.3048401	0.08
287.4241333	0.24
291.3164368	0.17
293.0667114	0.05
297.3182068	0.10
298.1284790	0.23
300.1636353	0.09
303.1903687	0.15
304.4373169	0.04
307.0992432	0.22
308.2225952	3.39
309.2976990	0.15
311.0463867	0.09
313.1858521	0.04
314.3242798	0.21
315.2846069	0.26
319.4054871	0.05
326.1693115	7.39
330.1564941	0.18
331.1677856	0.32
333.0979004	0.38
343.2314453	0.82
344.1776428	0.08
347.1585693	0.10
348.8101807	0.08
352.5358276	0.05
355.2568054	0.32
359.1394348	0.34
360.0812378	0.07
361.2544861	1.30
362.2267456	0.12
363.1448975	0.17
364.3570557	0.64
365.2714844	0.05
368.3850098	0.02
371.4342651	0.08
372.3809814	0.04
373.2301025	0.07
375.1992798	0.15
378.2064209	0.04
382.7132568	0.58
383.3656006	3.02
387.3934326	0.10
391.9366455	0.08
393.1962280	0.13
396.0712280	0.08
397.2437744	0.23
399.1945801	1.17
400.4525146	0.45
401.2475586	0.18
403.4453735	0.12
406.1917114	0.10
410.2437134	0.06
411.5624390	0.13
412.2773438	0.09
414.1525269	0.29
416.3687134	0.02
417.1862793	0.11
419.4623413	0.15
421.0923462	0.27
422.3359985	0.11
424.2817383	0.84
425.3053589	0.11
428.1654053	0.20
429.3199463	0.43
430.3093872	0.25
433.3780518	0.13
439.4303589	0.64
440.3807373	2.89
442.1484375	0.26
446.2407227	0.52
447.0037842	0.31
456.2122803	0.24
457.3590088	2.86
458.3945312	0.46
460.5093384	0.04
461.7025757	0.18
462.4059448	0.89
464.3994751	0.11
466.1634521	0.07
468.2179565	0.10
469.5194702	0.15
473.0547485	0.28
474.3840942	1.79
480.2232666	0.04
482.4722290	0.05
484.3771362	0.32
486.2459717	0.04
490.2618408	1.30
492.2117310	0.27
494.1420898	0.22
496.3485107	0.56
498.3890381	0.04
502.1483154	0.27
506.3000488	0.14
507.2852783	0.08
508.4187622	0.11
509.7747192	0.06
511.2146606	0.63
512.3048706	0.95
514.0523071	0.06
514.7007446	0.21
518.1554565	0.06
520.1016235	0.12
525.3588257	0.20
527.6622925	0.11
530.5161743	0.14
535.4262085	0.20
538.5390625	0.31
539.5291138	0.70
541.3956909	0.08
542.2688599	0.06
550.3592529	0.14
553.3678589	0.45
555.3305664	0.02
559.3645630	6.60
560.1421509	0.44
561.4631348	1.10
563.0009155	0.09
569.2432861	0.33
569.8737183	0.09
571.5602417	1.10
572.3262329	0.36
573.8021851	0.04
577.6011963	0.02
580.2814331	0.10
581.6485596	0.11
583.7479858	0.07
584.4556885	0.15
585.2743530	0.06
586.8572998	2.68
587.4777832	15.95
589.2997437	2.13
589.9346313	0.02
595.4130859	0.15
596.5756226	0.09
599.6875610	0.06
603.5292969	0.27
604.4697266	0.56
605.3931274	0.17
607.3842773	0.59
609.1119995	0.04
610.4271851	0.34
611.4105835	0.06
613.2025757	0.18
615.3449097	0.08
617.4910278	0.29
620.3235474	0.15
622.7400513	0.06
624.4611816	0.33
626.4938965	0.13
629.6392822	0.16
631.4254761	0.05
632.9308472	0.08
638.4091797	0.46
640.5213013	0.18
642.0508423	0.05
645.4880981	0.05
652.3860474	1.41
654.6602173	0.05
655.5856934	0.20
656.8629761	0.33
658.4849243	14.52
662.4650269	0.08
664.3411255	0.23
665.9398193	0.04
666.7091675	0.10
668.4675903	2.69
670.4023438	2.65
671.0971069	0.02
672.4164429	0.68
674.5961914	0.63
679.2439575	0.13
680.7471924	0.15
682.0110474	0.30
682.6162720	0.85
684.4768677	1.22
686.3898315	100.00
687.0878906	0.11
700.4270630	5.56
701.0996094	0.08
702.4097290	4.47
710.5465698	0.46
712.5175781	0.05
723.1669922	0.09
723.7804565	0.06
726.6347656	0.62
733.7521362	0.06
736.6757812	0.14
737.4583130	0.53
742.5151978	0.87
751.6080933	0.33
753.6236572	0.63
754.5291138	1.22
755.5867920	1.32
763.6279907	0.03
764.4268188	0.11
771.5379639	50.39
772.2615356	0.08
773.0060425	0.06
781.5203857	9.04
799.4699707	34.31
800.2224731	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1824
Annotation	Neohesperidin
Peak:m/z	Relative Intensity
173.3816986	0.07
174.2617035	0.09
175.692337	0.10
185.0194397	0.56
186.1294708	0.09
187.9006195	0.11
190.9221191	0.10
196.1199646	0.23
197.354248	0.05
199.0388184	2.29
200.1256409	0.30
201.028656	1.30
202.1219177	0.10
211.2000885	0.09
211.9663544	0.12
213.2333374	0.27
214.0419617	0.42
215.0524597	0.87
216.0846252	0.09
217.0762787	0.16
218.0478516	0.09
220.280777	0.12
222.2401123	0.07
223.3694153	0.30
224.1304321	0.13
225.1387024	0.29
227.0132141	0.98
233.0264587	0.53
235.2396088	0.03
238.1784058	0.39
239.0664673	0.77
240.2543793	0.33
241.1184387	0.78
242.0510712	2.17
244.0820312	0.13
248.3317566	0.07
251.1675415	0.38
257.1192322	1.03
258.0515747	0.71
263.3679199	0.16
264.5027466	0.24
265.3198547	0.05
266.1977844	0.09
268.1827087	0.79
269.1292419	0.29
270.1459351	0.08
271.1873779	0.05
282.2072754	0.28
283.1051636	2.67
284.0991821	0.11
285.1940308	0.40
286.0413208	3.28
291.6200867	0.43
292.3093872	0.05
297.1900024	0.60
299.1627197	0.30
301.079895	100.00
303.1262207	0.06
307.1862793	0.66
309.1151733	0.05
310.1204834	0.75
311.3670349	0.10
312.9664307	0.09
315.2352905	2.21
317.2929688	0.05
319.3493042	0.07
323.3234863	0.08
325.1665955	10.22
327.1722412	0.26
328.4431763	0.05
329.2839355	0.02
337.1364136	0.35
340.1864624	0.23
341.2223511	0.36
343.1157837	11.48
349.215332	0.45
352.0557861	0.40
353.163147	0.25
355.1783447	2.60
357.2243042	0.40
367.1202393	2.79
370.0220947	0.03
373.1376343	0.43
378.8721924	0.09
381.2619019	0.06
385.3117676	2.00
387.4107666	0.05
391.2472534	0.12
393.1137085	0.05
395.2509766	0.12
397.1119385	0.73
403.210144	1.76
409.3562622	0.36
411.2287598	0.07
412.1142578	0.12
427.1478271	0.03
429.2883301	1.30
441.1647949	0.08
443.8395386	0.24
445.1496582	1.33
447.302124	1.32
462.7231445	0.37
463.3959351	0.27
471.3140869	0.37
473.2932739	0.06
481.4708252	0.06
485.4533691	0.44
489.1951904	10.40
489.840271	0.06
501.1775513	0.03
513.0192261	0.10
523.239563	0.06
541.4119873	0.17
564.3358765	0.08
577.5141602	0.08
591.3987427	0.45
594.5251465	0.15
610.1194458	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0566
Annotation	Norbergenin
Peak:m/z	Relative Intensity
102.9029617	0.07
111.1635742	0.06
115.1969376	0.14
120.8806839	0.28
123.0442123	0.06
128.8867340	7.51
144.9423523	0.06
146.8731689	11.53
149.1586609	0.33
163.1876831	0.09
169.0676575	0.04
172.9920654	7.02
175.1457062	0.29
189.0780334	0.35
190.9600067	100.00
197.2943115	0.03
214.8898010	0.15
222.8754272	0.10
251.0991821	1.04
252.2850952	0.07
258.9580383	0.16
267.3026123	0.11
271.2379456	0.22
277.1277161	0.52
282.1830444	0.05
295.0030823	19.11
298.2449341	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1522
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
323.1596680	0.06
341.1643066	0.07
353.1501465	0.08
383.3934937	0.03
391.4669189	0.02
437.2191162	0.09
442.1923828	0.04
455.3472290	0.18
461.2208252	0.03
471.1499634	0.14
473.2297974	1.77
477.4858398	0.04
479.3316650	0.10
497.3963623	0.02
501.4329834	0.12
503.4053955	0.61
515.3169556	0.74
517.1265259	0.18
529.1475220	0.02
545.4157715	0.08
547.6129761	0.02
554.9921875	0.17
575.2593384	0.93
579.6786499	0.18
593.2958374	26.40
593.9287720	0.12
617.4916382	0.16
635.2788086	100.00
635.9204102	0.22
661.2000122	0.33
679.1661377	15.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	889.29
Annotation	Isorhamnetin 3-[2''-(4'''-acetylrhamnosyl)-gentiobioside]
Peak:m/z	Relative Intensity
251.3428650	0.10
254.1069489	0.11
254.7507172	0.06
271.0685120	13.94
272.1762695	8.56
273.2745972	0.31
296.2261353	0.18
313.2621765	0.04
337.0376587	0.05
358.1651001	0.05
381.5672607	0.10
382.2108765	0.11
400.1699829	0.18
417.4516602	0.07
433.1690063	28.87
434.1290894	27.31
435.1561890	0.67
445.3311157	0.08
475.1586914	0.09
476.3110962	0.56
499.1354980	0.06
500.1851196	0.39
526.4797974	0.05
530.0869751	0.10
543.0909424	0.20
543.9841919	0.40
544.5977783	0.05
561.2138672	0.38
562.1509399	0.54
571.9667358	0.06
577.3388062	0.08
578.3598022	0.35
579.2613525	1.14
580.3354492	1.69
595.1675415	3.86
596.1497192	7.45
596.9329834	0.08
604.2191772	0.15
619.5984497	0.09
622.3153076	0.07
638.1737671	0.40
690.5317993	0.09
707.0308838	0.14
716.3001099	0.15
724.0966187	0.75
725.2996826	0.23
726.2910156	0.37
741.1766968	18.14
742.1966553	100.00
743.1043701	2.24
770.6513062	0.17
784.2658081	0.21
831.1157837	0.21
834.5047607	0.09
870.2399292	0.36
888.6439819	1.89
889.2861938	29.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1768
Annotation	Phenethyl rutinoside
Peak:m/z	Relative Intensity
123.4351120	0.37
125.0252838	1.08
130.8743286	0.29
134.9634857	0.46
137.0342712	47.37
138.8798676	0.08
142.9838257	1.07
147.1647644	0.35
149.0456696	0.47
153.0365448	0.31
155.2911530	0.08
160.4313965	0.89
161.1009064	6.76
162.1205292	0.25
163.3163147	0.26
166.7955627	1.13
171.0075989	0.10
173.1918945	0.68
175.0963745	0.34
177.2783813	0.77
178.8787079	1.39
181.1175537	10.46
184.9659729	0.38
191.1456299	0.17
193.3551331	0.28
195.0333557	1.57
202.9806366	1.15
204.4031677	0.09
205.0407715	0.88
206.0699615	0.94
206.9783020	0.13
220.9307556	1.04
223.0901489	10.71
224.0804749	0.12
225.2765503	1.69
229.1242981	0.92
230.2744446	1.03
235.0700684	0.52
239.2277222	0.28
240.5751648	0.70
241.3424683	0.08
243.5162048	0.12
245.0566711	16.70
247.1705627	0.07
249.1345215	0.37
253.0948792	3.04
256.0240173	0.22
261.1202698	0.12
264.9482117	0.57
267.0238037	2.07
267.6942749	0.06
273.2555237	0.06
279.2469482	0.26
283.0673828	2.63
297.1854858	0.35
299.2205200	11.83
303.0935669	0.31
307.1195068	0.72
309.2641907	1.60
311.2988281	0.24
312.6900635	0.20
314.4086914	0.46
321.1683350	0.14
325.1934814	0.93
341.3049622	0.21
347.0662842	0.10
349.3769836	0.12
350.2656860	0.17
351.2937622	0.24
359.3482056	0.12
363.0977173	0.05
365.5107422	0.28
367.7621765	0.15
369.2369080	52.78
369.8389893	0.24
371.2898865	0.27
383.1391907	100.00
385.0852356	3.41
387.2668762	31.44
393.2618408	0.80
397.0781555	0.15
400.2673035	0.13
410.4228210	0.17
411.3423157	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
96.88697815	0.42
98.91419983	0.65
100.9119263	0.20
104.896759	0.35
111.9875336	1.93
113.0756683	0.76
137.0817413	0.77
149.0252228	0.57
153.2035675	0.17
161.275528	1.24
165.059845	0.47
176.9893341	0.79
179.0711517	1.59
181.2073669	0.66
183.0261383	0.46
189.1325531	2.04
191.18927	1.23
193.0120392	1.90
194.1268005	0.52
195.099411	0.72
195.968811	0.24
207.1701813	10.58
208.1051178	5.07
209.1104126	2.29
209.932724	0.22
214.9980621	0.90
221.0740509	1.18
222.1008453	7.05
223.1290588	7.45
224.206955	0.72
231.1605377	0.59
232.502243	1.23
233.2799225	6.23
234.1094971	0.34
234.7378693	0.27
235.90065	0.98
251.0841675	100.00
252.1635132	17.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
92.8863678	0.01
112.9457703	0.01
127.2822495	0.01
136.9743347	0.05
146.0626831	0.01
152.0308228	0.02
157.0212402	0.02
167.2219391	0.03
169.2338104	0.01
178.1557312	0.01
183.0968018	0.04
185.5879211	0.01
191.0178528	0.03
192.9994354	0.07
199.2749176	0.01
201.0586548	0.02
204.0645142	0.11
204.9772644	0.02
207.5599976	0.02
211.3152161	0.05
213.1322937	0.07
217.1116028	0.03
225.0862427	0.04
227.1503601	0.03
235.3200378	0.05
239.2312622	0.05
245.3034668	0.02
251.5762634	0.05
253.1177979	0.14
254.2119141	0.02
255.1811523	0.06
256.8692627	0.04
266.9940186	0.22
269.1316528	0.36
270.2906189	0.03
277.3425293	0.06
280.0131836	0.03
281.0932922	0.23
281.9631958	0.01
283.0752563	3.37
285.1564941	0.57
286.2655945	0.01
293.7639771	0.05
294.9868774	0.61
298.0473328	100.00
299.0471802	0.13
313.1639404	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.2941
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
139.9263153	0.10
153.0664978	0.01
158.9286194	0.05
195.9664612	0.09
214.1222839	1.06
227.1047821	0.03
253.1865234	0.06
281.2820129	100.00
281.9242554	0.14
295.5433960	0.03
315.3387146	0.02
410.0757141	0.07
414.4527893	0.08
415.5162048	0.02
417.5057983	0.01
431.4543152	0.08
460.6825867	0.02
463.3098450	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1171.316
Annotation	Didmolamide B
Peak:m/z	Relative Intensity
344.3422546	0.05
361.4120789	0.01
811.0369873	0.06
1171.2795410	100.00
1172.3079830	9.06
1173.0170900	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1717
Annotation	Colabomycin A
Peak:m/z	Relative Intensity
165.0075226	0.25
165.9511108	0.04
166.8977051	0.14
168.9282227	0.24
172.9208527	0.05
175.0492249	1.60
176.1188660	0.04
177.0382233	0.94
177.7778625	0.14
179.0277557	0.10
184.9823608	0.12
188.8987732	0.55
189.9943695	0.13
190.9555817	0.31
192.9891663	2.32
193.9018860	0.22
201.1361542	0.06
205.0779419	2.42
205.7941589	0.12
207.0742493	0.65
209.8249359	0.29
210.9572754	1.47
212.1665649	0.07
217.1731567	0.37
218.9280853	0.35
222.9945068	0.37
227.1068268	0.14
235.0877991	13.69
236.0854034	1.28
238.0996246	0.47
241.1006927	0.23
242.8985901	0.06
253.1719208	0.45
254.1777344	0.24
254.8793945	0.07
258.9785767	0.06
267.2583313	0.09
271.0823059	45.95
272.1935425	8.27
277.2536621	0.57
278.2233276	0.21
279.1390991	0.17
285.3546753	0.20
295.0458374	3.71
296.2554932	0.89
297.1569824	0.47
313.1644897	15.20
314.1877441	1.68
315.1723938	0.42
316.0821533	0.06
325.1866455	1.12
326.1068115	0.09
337.4738770	0.14
338.1759033	0.16
339.0996704	3.06
340.2620850	0.97
343.0967407	0.92
344.2034912	0.15
347.2635498	0.09
351.3501587	0.24
353.4096680	0.12
354.4697266	0.07
355.1297607	0.61
355.9969482	0.22
357.1873169	5.92
358.2170410	1.24
362.9073486	0.27
363.5581055	0.07
365.9779663	0.19
373.1568604	1.63
374.2200928	0.19
380.3153076	0.07
381.2575684	0.23
382.2172241	0.13
397.6697998	0.57
399.2414551	0.65
415.2041626	0.53
416.5471191	0.23
417.2301025	0.37
418.4337158	0.52
423.2258911	0.41
433.2947998	1.25
434.0241089	0.28
441.2286377	3.76
442.3489380	0.33
459.2015381	100.00
460.1950073	27.48
473.3471069	2.26
474.2557373	0.70
533.0852661	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.1228
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
169.2119751	0.02
219.1997223	0.03
243.0622253	0.02
272.0428467	0.03
284.8124084	0.12
298.1614075	0.03
301.2210693	0.72
308.1249084	0.01
313.0932312	2.45
325.2268677	2.58
329.4104309	0.08
331.2109985	0.11
331.8963013	0.02
337.2326050	0.01
341.2945251	0.18
343.2315674	23.27
353.2722778	0.02
355.4265747	0.11
367.1506348	12.33
367.7561340	0.04
373.1677246	1.48
379.2974548	0.25
381.2381287	0.40
385.2013550	0.28
391.1528015	0.25
394.2764893	0.01
397.1661072	28.95
397.7674866	0.12
403.8084412	0.09
404.4239197	0.07
409.1769409	8.15
409.8253784	0.12
415.4601746	0.05
417.0501404	0.10
427.1794434	32.03
428.1698914	0.11
445.1749573	100.00
446.3145142	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.2001
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1113129	0.01
242.9533539	0.06
245.4089508	0.05
258.2133789	0.04
269.8687744	0.04
271.4356689	0.07
281.4625854	0.07
284.7056274	0.07
285.3649597	0.03
286.1933594	0.09
295.0714111	0.01
295.9372559	0.13
297.3888550	0.04
298.2506714	0.05
299.0510559	0.20
301.2856140	0.02
301.9395142	0.03
312.3251953	0.02
313.3210754	0.61
314.2659302	1.85
315.3303833	0.09
317.1171265	0.29
324.0714111	0.23
326.0326843	0.05
327.1101685	1.09
329.9608459	0.09
330.7657471	0.04
331.3757019	0.13
332.4355469	0.03
341.2189026	0.19
342.1904907	1.64
343.5547180	0.03
345.1361084	9.50
346.0530396	0.15
347.3959351	0.06
360.1285400	5.34
361.1804810	0.57
362.2573242	0.48
363.3720093	0.06
375.1668091	100.00
376.0073242	0.01
388.2299194	0.03
413.1907349	0.03
417.3434448	0.05
457.1074219	0.03
517.5144043	0.06
518.5222778	0.03
519.7362061	0.16
525.4177246	0.02
531.2708740	0.02
537.1902466	0.16
549.2941895	0.08
556.2638550	0.25
556.8764038	0.18
563.3914795	0.04
573.3572998	0.07
579.0967407	0.03
592.3059692	0.03
595.3125610	0.06
605.5380249	0.03
609.2224121	0.02
612.4458008	0.05
613.0733032	0.08
619.2453003	0.17
620.2662964	0.06
621.5377197	0.03
622.7545776	0.05
644.9565430	0.09
645.6784058	0.01
662.4161987	0.11
663.3357544	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2616
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
224.2564392	0.01
239.1994781	0.02
253.1625519	0.02
277.1908264	0.01
339.4091187	0.02
345.3697510	0.06
351.6119385	0.02
419.4978638	0.01
437.4935303	0.05
445.3378906	0.04
471.3267822	0.43
471.9384155	0.01
486.4376831	0.02
491.4066772	0.08
495.5255737	0.02
497.2232666	0.10
500.2800293	0.10
504.5006104	0.02
515.3449707	100.00
516.0310669	0.31
518.5070190	0.03
519.3837891	0.24
532.1779175	0.04
535.6491089	0.03
537.1241455	0.20
537.7767944	0.01
547.4036255	0.65
552.4822388	0.04
554.1242676	0.03
555.2933960	0.04
559.2352295	26.38
559.9198608	0.04
573.2838745	0.04
573.8897095	0.08
576.6596069	0.02
591.2978516	0.43
592.4265747	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.61
Annotation	Unknow
Peak:m/z	Relative Intensity
189.9807739	0.10
193.1423645	0.08
195.8342438	0.27
200.0169983	0.42
202.0775452	0.35
206.4933929	0.03
209.8458862	0.06
211.8426514	0.10
213.0681152	0.10
217.0834351	0.12
217.9334106	0.08
226.0862274	0.29
228.1771545	0.05
236.0274963	0.12
244.0267792	0.08
254.0356903	1.57
260.2077637	0.02
262.0112915	0.03
263.0119629	0.13
263.9529114	0.16
270.3701172	0.04
271.9984131	1.18
273.1007080	0.32
274.8738403	0.08
276.1952820	0.07
278.0902100	0.10
278.8907166	0.06
281.0210571	0.29
282.2168274	0.09
283.9977417	0.06
285.9329529	0.09
287.8853455	0.05
290.0295715	0.05
294.0166016	0.07
296.2662659	0.05
299.1879272	0.22
304.0826416	0.83
306.0055542	0.52
310.2439575	0.03
312.0315247	0.25
314.3055420	0.02
318.3860474	0.33
319.1253052	0.20
320.1881714	0.08
322.0069580	0.53
332.1421509	0.15
340.1566162	0.57
341.4539795	0.10
342.1271362	0.06
346.0366211	0.11
348.0844727	7.33
357.9270630	0.19
364.0270996	2.49
371.1331177	0.03
376.0362549	0.67
384.3742676	0.04
386.8729858	0.11
389.9611206	0.01
392.2219849	0.09
394.0903931	100.00
403.2368164	0.09
407.2277832	0.05
420.0600586	0.42
422.1477661	0.05
435.9050903	0.05
438.0671997	66.03
496.4254150	0.10
497.6420288	0.02
511.1780396	0.07
550.7879639	0.13
569.9438477	0.38
584.5769653	0.26
585.6077271	1.65
586.4506836	0.05
611.4296265	0.26
612.0892944	0.74
681.9598999	0.04
682.8543701	0.42
873.7416382	0.11
874.8584595	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.16
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9185333	1.03
119.0674057	0.11
125.0498123	0.76
129.0645447	0.39
130.5333252	0.06
137.1595001	0.08
143.0387115	0.62
149.0077209	0.15
158.9826508	1.38
161.0254822	42.66
162.1593628	0.07
163.9420776	0.11
165.1814270	0.08
167.1203003	0.35
179.0382080	1.35
180.0069885	0.25
183.1128693	1.82
184.1269836	0.03
185.0182190	0.14
185.7150116	0.08
190.9867554	0.24
197.1096191	0.53
203.2913055	0.16
210.5110779	0.13
225.3665771	0.23
226.0568237	0.05
227.1316528	0.05
230.1296692	0.09
230.9477844	0.09
237.0877075	1.78
240.8121643	0.13
245.2216187	0.19
255.1719360	1.60
263.1702881	0.04
265.3119507	0.11
267.9757385	0.11
271.3235168	0.05
273.2988586	0.05
275.0227661	0.06
277.1505127	0.08
283.2039185	0.04
287.0978394	100.00
289.1005249	0.14
300.1940918	0.05
303.1868286	0.66
309.3248901	0.04
312.5692139	0.21
315.0107727	0.08
319.1803589	0.04
327.1918335	0.72
328.4139404	0.06
329.0880127	0.07
331.3297729	1.44
332.1791382	0.16
333.0651855	0.26
342.8639221	0.05
343.8733521	0.17
345.1646118	27.85
346.3852234	0.29
347.2342834	0.24
355.2874756	1.46
359.0977783	0.81
371.3416748	0.18
372.2811584	0.09
373.0133057	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	466.1851
Annotation	Aristoquinoline C
Peak:m/z	Relative Intensity
135.8908691	2.97
136.4940338	0.03
143.7490082	0.04
157.0287781	0.05
158.0044098	0.02
161.3048248	0.08
161.9833984	0.03
166.9868469	0.06
170.9844055	0.02
179.0863037	0.05
188.8230591	0.01
196.2922668	0.04
197.1833191	0.05
199.0492859	0.08
201.2818604	0.04
203.0442505	0.06
209.2859497	0.02
211.0761719	0.04
227.2391052	0.05
232.1584167	0.03
233.4199829	0.07
235.2464294	0.01
243.0379639	0.03
257.3782959	0.01
260.8039246	0.02
267.1398926	0.55
271.0788879	0.03
273.8862610	0.02
276.2038269	0.01
280.3455811	0.01
285.0974121	100.00
288.9544373	0.03
297.2189941	0.10
301.1810913	0.02
301.8115845	0.04
303.3045044	0.15
304.0241699	0.08
306.8865662	0.11
308.1245117	0.13
308.7960205	0.02
310.2976685	0.04
311.1854248	0.01
319.3015137	0.03
323.2545776	0.04
325.3391418	0.03
327.0424194	0.02
331.4754028	0.02
333.1833191	0.04
335.3566589	0.01
341.1640625	0.04
360.0383301	0.04
362.4127197	0.02
368.1738281	0.05
372.1124878	0.13
375.3796997	0.21
377.1331177	0.04
380.4474792	0.08
393.9829712	0.03
404.6308289	0.01
408.9916687	0.07
411.1355286	0.06
412.3345337	0.04
419.4966736	0.80
420.1222229	6.79
446.0525818	0.04
448.0844421	5.60
449.8937073	0.17
456.3950500	0.03
457.8338013	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0858
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
119.9196930	100.00
131.0038757	0.11
137.2493134	0.06
147.8302612	0.48
149.0051422	4.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	265.0934
Annotation	8-Oxodeoxycoformycin
Peak:m/z	Relative Intensity
80.9433899	0.76
82.9019470	0.91
84.8669281	14.99
86.9774857	2.61
88.8850021	22.18
94.8498764	0.68
96.9943543	0.87
98.8725433	0.61
100.9166565	20.44
102.9711304	100.00
112.8976135	25.53
116.9185944	1.67
118.8439178	22.64
124.9734650	1.26
130.9305420	4.88
142.8933105	12.31
144.9058228	6.66
146.9279938	0.13
148.8839569	1.20
156.7309570	1.08
160.9989319	4.27
174.4254761	0.98
175.1365814	4.46
178.9588623	8.92
199.1931458	0.25
205.0270233	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.034
Annotation	Unknow
Peak:m/z	Relative Intensity
115.0615234	0.02
122.9058609	0.06
125.0628357	0.13
136.9071045	0.18
138.9199524	1.58
139.8415527	0.13
140.8786621	0.04
142.9194031	0.03
144.0874329	0.02
146.0230103	0.15
150.9605560	0.17
152.1497803	0.10
152.9602966	0.08
161.0018005	0.03
165.0141907	0.19
166.9462585	0.18
169.0277405	0.09
172.8301086	0.03
174.0747986	0.02
175.2519836	0.02
179.0876465	0.25
180.0154419	0.08
180.8436432	0.41
191.1588440	0.06
193.0984192	0.05
197.2308044	0.04
199.0064240	0.06
199.8798065	0.04
200.9704590	0.04
204.7783661	0.02
209.0823364	0.56
210.1048889	0.08
214.9288025	0.07
216.9921265	0.20
217.7773895	0.04
219.1116943	0.02
220.0820007	0.05
220.8935242	0.04
222.9976807	2.71
224.1472168	0.30
235.3001099	0.02
241.0017700	100.00
242.0084229	8.62
242.6894836	0.11
245.1029968	0.06
251.2416077	0.03
257.2209778	0.04
272.8376465	0.07
276.0025940	0.02
281.1830750	0.12
283.3721313	0.03
293.1358948	0.20
295.8511353	0.01
299.1961060	1.74
300.1084595	0.25
307.2177124	0.02
308.2830505	0.42
318.9614258	0.04
319.6602783	0.05
320.4615173	0.02
335.3222656	0.04
336.1628418	0.06
341.2470703	0.50
342.2006836	0.02
343.1420898	0.17
361.0627747	1.11
362.3535461	0.45
379.4426270	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8035583	2.81
206.7571716	100.00
207.5235291	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	799.26
Annotation	Jionoside A2
Peak:m/z	Relative Intensity
221.0637817	0.02
228.2346497	0.14
229.1782532	0.08
230.2329712	0.01
230.9509430	0.02
233.4250183	0.03
234.2631989	0.01
239.0344543	0.02
240.3074493	0.06
241.2903137	0.06
242.4493713	0.04
243.1974487	0.04
244.2089233	0.07
245.2586060	0.24
246.2765503	0.04
247.2023621	0.04
249.2296295	0.04
250.1736298	0.02
254.2844238	0.02
255.4495392	0.03
257.0231323	0.02
258.1550293	0.02
259.3651428	0.14
260.1259155	0.18
261.0945740	0.16
262.2896423	0.08
263.1643066	0.04
264.2415466	0.01
267.1514587	0.05
269.2248840	0.05
270.2103271	0.01
277.2435608	0.12
278.2575684	0.21
280.3048096	0.03
281.0339966	0.01
283.2265320	0.04
284.4161377	0.05
285.2746582	0.02
287.2583923	0.12
288.1070862	0.08
289.2586670	0.12
290.3934631	0.02
291.1870728	0.04
292.1829224	0.05
293.2972717	0.06
294.3669739	0.08
297.5222778	0.19
298.3215332	0.03
299.1208191	0.05
300.2741089	0.01
301.2872620	0.05
302.0287476	0.08
304.4662476	0.02
306.4402466	0.01
307.3166504	0.05
308.1633606	0.08
309.2171631	0.05
314.1735229	0.01
315.2578125	0.13
316.5972290	0.13
324.3132019	0.09
325.1982422	0.08
329.2153320	0.03
333.3920898	0.01
334.3089294	0.09
341.0650024	0.58
342.2009888	0.31
343.2158203	0.22
349.1984253	0.05
351.9300537	0.03
355.3757324	0.09
356.1437378	0.01
357.8178101	0.10
358.4679565	0.55
359.3921204	0.25
360.3181763	0.04
361.2595215	0.08
362.3067017	0.06
363.2029419	0.03
364.5576782	0.01
366.3217773	0.03
369.3515625	0.01
374.3430786	0.18
375.2986145	0.05
376.4712830	0.09
377.1681519	0.01
378.5235596	0.01
379.4531250	0.01
380.3424683	0.06
381.3681641	0.01
383.6641846	0.15
386.4527588	0.01
387.6506348	0.07
388.3615723	0.01
389.2897339	0.03
390.2265625	0.14
391.1873779	0.15
392.3162231	0.01
395.4326782	0.01
396.3128052	0.06
398.1597900	0.21
399.3088379	0.36
400.4434204	0.06
402.4084473	0.06
403.2814941	0.01
405.1259766	0.15
405.7973633	0.07
406.7269897	0.07
407.4306641	0.02
408.3567505	0.49
409.2819824	0.50
409.9122314	0.01
410.5158691	0.02
411.4365845	0.04
412.2877197	0.15
413.5899048	0.08
414.3045044	0.06
416.4470825	0.02
417.3196411	0.01
418.3447266	0.01
420.5173950	0.04
422.3717651	0.03
423.3972168	0.03
425.5521851	0.02
428.3818970	0.02
429.3640137	0.06
433.4022217	0.07
434.3217163	0.10
435.3077393	0.17
436.3466797	0.10
437.4406738	0.24
438.5700073	0.17
440.1847534	0.04
442.4727173	0.02
444.2338867	0.02
445.6235352	0.01
446.4241333	0.01
448.4759521	0.05
450.2130127	0.03
451.4909668	0.01
455.4155273	0.55
456.3867798	1.01
457.5041504	0.02
458.4569702	0.04
459.3605347	0.02
460.5494385	0.02
461.4292603	0.03
462.4100952	0.11
463.4383545	0.19
464.6600342	0.07
465.5402832	0.04
466.6192627	0.03
468.3357544	0.06
469.5289307	0.07
470.3774414	0.01
471.2609863	0.01
472.5408936	0.18
473.4451294	0.16
477.4633179	0.02
478.2576294	0.05
482.5512695	0.01
484.4697266	0.02
487.5598755	0.09
488.2534180	0.09
489.5518799	0.14
490.4123535	0.04
491.5675049	0.03
492.9276123	0.05
494.4062500	0.10
495.3822021	0.14
497.2300415	0.01
498.4826050	0.06
499.3922729	0.10
500.1802368	0.02
501.3683472	0.03
505.1332397	0.05
506.3117065	0.08
507.5671997	0.02
508.4370117	0.10
509.5156860	0.46
510.4583130	1.20
511.4252319	0.13
512.8295898	0.13
513.5928345	0.07
514.3776855	0.05
515.4038086	0.01
518.3884277	0.06
519.3861694	0.23
520.5014648	0.17
521.6876221	0.07
522.5407104	0.02
524.5270996	0.04
526.8275146	0.23
527.4954834	0.20
528.7606201	0.06
530.0940552	0.09
532.5430298	0.01
534.3190308	0.16
535.6269531	0.18
536.5631104	0.10
537.4076538	0.19
538.5295410	0.03
539.3627930	0.01
540.0172119	0.02
540.9356689	0.02
541.5573730	0.02
542.6362305	0.05
543.4193115	0.02
544.6364746	0.06
545.6183472	0.08
546.6331177	0.08
550.6166992	0.06
552.3593140	0.56
553.4172974	1.11
554.4142456	0.19
555.4307861	0.19
556.2590942	0.02
559.0700073	0.01
561.5838013	0.01
562.7238159	0.05
564.5658569	0.06
566.1716919	0.14
567.6227417	0.16
568.4436035	0.33
569.4815674	0.70
570.5527344	0.78
571.5666504	0.03
573.6962280	0.03
574.4120483	0.01
575.5857544	0.02
576.6951294	0.01
579.5033569	0.30
580.3804321	0.50
581.5385132	0.10
583.1524048	0.09
584.0180054	0.09
584.6228638	0.06
585.5171509	0.12
586.4651489	1.60
587.4661865	3.20
588.3414917	0.27
590.4855957	0.04
591.6735229	0.12
592.4635010	0.25
593.5293579	0.91
594.4964600	1.44
595.5225220	0.21
596.4758911	0.29
602.4416504	0.80
603.4874268	1.75
604.4389038	0.17
605.6427612	0.03
606.6720581	0.07
607.5833740	0.01
608.5886230	0.34
609.4570312	0.87
610.4741821	2.91
611.5263062	1.12
612.5563965	0.20
617.4987183	0.08
618.4550781	0.04
619.4801636	0.06
622.6401367	0.05
623.5824585	0.03
624.4190674	0.03
626.6709595	1.37
627.6041260	2.72
628.5820923	0.11
629.3983765	0.03
632.6155396	0.02
635.5229492	0.32
636.6509399	0.42
637.5391235	0.14
638.7197876	0.01
640.5999146	0.02
641.6633911	0.10
642.5842285	0.01
643.4286499	0.12
644.4329224	0.19
647.1940918	0.01
648.7861328	0.03
650.4243774	0.19
651.4662476	0.55
653.7344360	0.08
654.6812134	0.02
656.0246582	0.01
656.6351318	0.01
657.5482788	0.16
658.4722290	0.06
659.4212036	0.00
660.3871460	0.02
661.4099121	0.03
663.5230103	0.03
664.4055786	0.05
665.4002075	0.09
666.5411987	0.30
667.5310059	0.18
669.6813965	0.01
672.6051636	0.03
673.8244629	0.02
674.7813721	0.02
676.1992798	0.07
676.9277954	0.02
679.4791870	0.05
680.5971680	0.03
681.6434937	0.03
682.2929077	0.02
683.9360962	1.13
684.5374756	3.08
685.3972168	0.27
688.4594116	0.11
689.5939331	0.22
690.7332153	0.04
691.7232666	0.06
693.0822754	0.05
693.7433472	0.01
696.4119873	0.07
697.3991089	0.01
698.5175781	0.54
699.6585083	0.10
700.6490479	0.30
701.5761108	2.30
702.6550903	0.18
703.8143921	0.02
705.6404419	0.04
706.7803345	0.46
707.7161865	0.22
710.4215698	0.02
712.5250854	0.06
713.4199829	0.04
714.8427124	0.03
715.7578735	0.02
719.8771973	0.06
720.5914917	0.03
722.6879883	0.04
723.9429321	0.05
724.7398071	0.04
725.4915161	0.06
727.5252075	0.06
732.5368652	0.83
733.6828613	0.12
737.5444336	0.21
738.5042114	0.05
741.4514771	3.66
742.4772949	0.40
744.0827637	0.02
749.4451904	0.30
750.5397339	4.25
751.5619507	0.23
753.4694824	0.26
754.5164185	0.59
755.4618530	0.79
756.5927124	0.09
762.8151245	0.01
763.4932861	0.08
780.4957275	1.30
781.5595093	0.15
799.5346680	100.00
800.1879883	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1928
Annotation	(+)-Kurramine
Peak:m/z	Relative Intensity
175.1334839	0.06
177.0497284	0.02
179.1532898	0.05
189.0838318	0.05
265.1005249	100.00
350.6654663	0.03
413.1167603	0.02
427.4830933	0.05
485.4022827	0.02
486.9198608	0.05
512.0363159	0.03
513.2573853	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.1176
Annotation	Unknow
Peak:m/z	Relative Intensity
171.9617462	0.33
172.9920807	0.20
175.0754242	0.44
182.0476685	0.13
186.8250275	0.36
198.7249451	0.36
199.6552887	0.06
201.0287781	0.66
211.0820312	0.13
213.9673157	0.34
216.9479370	0.73
219.0457916	0.26
234.8934631	0.33
236.4892273	0.10
237.2947083	0.16
242.9422302	0.58
247.0246582	0.19
250.1505432	0.12
260.8231506	2.68
261.8322754	0.09
273.2497864	0.21
275.0299683	20.89
276.0939636	0.09
277.0491638	2.44
277.7383423	0.12
278.8469849	0.38
284.9218140	0.31
288.8948364	0.11
291.1355591	0.11
301.1221924	0.62
303.0758362	6.44
315.6388550	0.14
317.3378296	0.18
318.8114929	0.94
320.9996948	100.00
322.3995972	0.34
324.9555664	0.17
329.4163208	0.14
336.9260864	1.96
338.3522339	0.23
349.0448608	0.07
360.9110718	0.54
362.9974365	2.58
374.9625854	0.71
378.1766357	3.03
379.1086426	7.85
379.9789429	0.98
380.9568481	1.03
392.3398438	0.93
393.2852173	0.43
396.9372559	0.07
400.7896729	0.11
406.8388672	0.56
411.2616577	0.19
417.0867310	0.24
419.2711792	0.15
422.8938599	4.51
424.2546387	5.38
424.9792480	40.84
425.5953369	0.47
435.1066284	0.18
438.0416870	0.06
440.8897095	0.22
446.5913696	0.14
452.9872437	0.47
464.2593384	0.23
465.1770630	2.51
465.8974609	0.09
467.0629883	1.76
478.9210205	0.23
482.5015869	13.03
483.1849976	66.78
490.9633789	0.34
500.9873657	0.52
527.2238159	1.13
569.0513306	3.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9563446	1.02
85.0328674	0.02
87.9275665	0.04
101.8787079	20.19
102.9217682	0.03
119.7549896	0.01
129.9201508	100.00
130.9349213	1.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	306.14
Annotation	Unknow
Peak:m/z	Relative Intensity
88.0680084	0.24
90.9114685	0.35
92.8259277	0.42
104.9423370	3.70
106.9882660	14.74
109.0139313	0.75
112.8146362	0.11
119.1940308	0.17
119.9274826	0.15
121.8789825	83.54
123.0195847	4.53
124.1932068	0.09
124.9541931	1.92
126.9662781	13.77
129.0018768	0.07
131.0374451	1.46
133.0429688	0.34
135.8353424	0.12
137.0772247	0.22
138.8977051	0.22
140.9619751	0.49
142.7799072	0.29
146.1245880	0.27
148.9234619	27.72
152.9498138	1.89
153.8944702	0.25
159.2904510	0.14
160.1194305	0.10
161.1224365	0.19
164.0454407	0.05
165.1307220	0.18
167.0089874	38.31
168.8763580	0.05
177.0803986	0.62
178.1179962	0.34
178.8702698	0.38
180.2500916	0.08
183.0366516	0.51
184.8748474	100.00
185.8864136	0.18
188.2657166	0.17
195.0411224	0.08
198.9739990	0.16
201.0765686	1.41
202.4096375	0.29
203.1503296	0.72
204.2893372	0.20
205.3280640	0.06
206.1127319	0.55
208.8751526	0.14
216.9688721	0.49
218.1862488	0.20
219.1682129	0.10
220.1524353	0.12
224.2171936	0.17
228.1316223	0.07
229.1646423	0.44
230.6462402	0.28
232.1730042	0.50
236.0729980	0.07
242.1254578	0.32
243.1576538	0.26
244.3215637	0.06
246.2384033	0.06
247.2540894	0.27
248.2534180	0.13
249.6330566	0.07
251.0654297	0.43
252.2054138	0.05
259.0709839	0.65
260.0873413	1.49
261.0379639	0.44
262.1798401	0.20
263.2921753	0.64
264.3024902	0.28
270.1079407	1.30
271.0039368	1.28
272.0603943	0.49
274.1837769	0.04
278.1824341	0.90
283.1488647	0.27
283.8686829	0.07
286.0206299	0.59
287.1402588	2.71
288.0886841	41.32
288.9596558	6.38
292.2068787	1.46
296.5488892	0.41
310.2867432	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.1817
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9076385	0.34
115.9652557	0.34
120.0432281	0.88
121.0908279	0.14
122.0695724	0.06
128.8178406	0.40
138.1014862	0.09
146.2061768	0.05
147.0920258	0.19
149.0419006	0.04
154.0819702	0.33
156.0857391	0.20
161.9714813	0.15
162.9482727	0.06
166.1654816	0.43
167.1189270	0.14
169.8771362	0.07
171.0929871	0.41
185.1921692	0.13
186.1702118	0.15
188.1016541	0.07
194.9946747	0.52
197.0276489	0.40
197.8593445	0.64
199.0829468	0.99
202.1092529	0.13
203.1695862	0.08
204.2374725	0.05
207.2181702	0.25
212.1260986	0.16
216.1268463	0.68
217.2342834	0.25
222.0713043	0.20
226.2084656	0.55
226.9691772	0.14
232.2653503	0.27
234.1342468	4.65
235.1073608	3.83
235.8302917	0.14
236.9708557	0.17
240.2004089	1.25
241.1806335	0.42
248.8916626	8.41
256.8340149	0.05
258.2713013	0.12
258.8854065	0.09
264.6715393	0.04
266.2746582	0.67
267.3395081	0.21
272.4370117	0.42
274.6338806	0.06
279.1680298	0.12
280.1754150	2.10
281.1156616	0.12
282.1205444	0.12
285.1955261	0.78
288.1446228	0.36
288.8575439	0.65
290.3041077	2.11
291.1184998	0.04
294.2462769	2.11
295.1762085	1.11
296.0054626	1.52
297.6249390	0.11
298.5289917	0.26
300.8981934	0.28
304.3024902	21.82
305.2666626	0.95
308.9297485	0.34
312.7994995	0.68
313.6586304	0.12
314.2944031	0.52
314.9483337	0.42
318.6318970	0.30
322.9009094	11.37
323.8992920	1.11
325.2409058	0.47
326.3471375	0.17
330.2478333	0.05
331.8967590	0.96
332.7801208	0.47
336.6262207	0.16
337.2801514	0.09
338.8239136	3.27
340.8961182	12.59
342.0586548	2.17
343.4428101	0.68
345.2434082	0.04
346.2788086	0.21
347.9632263	2.41
350.2098389	0.13
351.0495605	0.17
352.8737488	5.90
353.7874451	1.04
358.2739868	0.07
359.1395874	0.25
360.3548279	0.21
364.1687317	0.83
365.1412964	4.92
366.1344604	0.59
366.9468994	0.17
367.8070068	1.00
369.6908264	0.08
370.5324707	0.19
371.6059570	0.16
373.5538025	38.87
374.4731750	10.21
375.3768616	0.39
376.1585999	0.22
378.5224304	14.11
379.3447571	2.58
380.1834106	0.07
381.3249207	2.39
382.4191589	24.85
383.4441528	1.33
387.5740662	100.00
388.4098206	24.43
402.2075195	0.25
410.3360901	0.17
412.1415710	0.14
420.0922546	0.10
422.5464783	0.13
426.2387390	0.32
432.4195862	0.16
433.2818298	0.88
434.1994019	0.10
435.8155823	0.09
437.1571655	0.05
439.2838745	0.11
441.4153442	0.23
450.1886292	0.10
451.4467468	0.35
452.2724915	0.41
469.3024597	0.28
470.2732544	2.33
471.5746460	0.32
472.3438110	0.09
479.2671509	2.73
480.2354431	2.05
481.4205933	0.10
489.6839905	0.30
490.3619080	0.07
495.5837708	0.12
503.2567444	0.07
507.3128357	0.69
508.3399353	0.53
511.4428101	0.13
512.5466919	0.07
525.5111694	0.17
530.3670044	0.21
534.2340698	0.23
539.2811279	0.96
542.6934814	0.09
543.4887695	0.16
549.7246704	0.32
557.4024658	1.14
558.2927246	0.68
559.5462036	0.08
560.5685425	0.22
562.3667603	0.06
572.8632812	0.22
576.4310303	1.78
577.6185913	0.12
579.5861816	0.11
580.3226318	0.31
587.4122925	0.21
588.5193481	0.24
589.3790283	0.16
591.3762207	0.08
595.4322510	0.15
597.5319824	0.04
600.7026978	0.08
607.6838989	1.77
608.5167236	0.22
609.4537354	0.12
616.5679932	0.10
617.7924194	0.12
620.7518921	0.05
622.5469360	0.10
628.4965210	0.49
629.6785889	0.34
631.5644531	0.44
632.5377808	0.44
636.4398804	0.43
637.4237061	0.48
638.4087524	0.19
644.4016113	2.07
645.4175415	1.64
646.4534302	1.14
649.5671997	1.28
650.5209351	1.07
654.0399780	0.29
654.6514893	0.99
655.3831177	0.18
658.6276245	0.10
659.6279297	0.13
661.6685181	0.11
662.9754028	0.44
663.6047974	1.79
664.5170288	1.56
665.4387817	0.08
668.5383301	0.12
676.3796387	0.66
681.5015259	0.07
682.7849731	0.04
686.4561157	0.04
694.4762573	0.25
704.4188843	0.37
705.3757935	0.12
723.3237915	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2086
Annotation	6-O-Oleuropeoylsucrose
Peak:m/z	Relative Intensity
143.0906982	0.58
148.8697510	11.65
160.8646240	9.00
170.0806885	0.69
170.9359741	0.13
191.0401001	6.73
207.1585999	0.19
217.3146362	0.17
220.0859375	1.64
220.8420258	13.91
237.0118103	0.57
246.8634644	0.42
250.9964905	5.52
259.1760254	0.47
262.4270935	0.24
263.0797119	1.36
275.1917114	3.62
281.1861877	1.55
293.1666260	20.75
310.9498291	100.00
327.2313232	0.24
329.2142639	0.35
339.0016785	0.19
345.2928772	0.94
387.5981140	0.18
460.4859314	10.78
461.1150208	37.97
472.2518921	0.17
473.1565552	0.18
475.1118469	0.34
492.3345032	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	753.4262
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1563873	0.66
219.2844849	0.15
226.0865326	10.32
239.2129517	0.11
243.3315735	1.88
244.3250732	0.14
245.2982025	1.67
249.7193604	0.21
252.2568512	0.15
253.1016388	0.10
261.9898376	0.08
262.6887207	0.36
267.9317627	0.12
269.8121948	0.12
273.1012573	0.28
281.3872070	0.19
283.0330505	0.30
285.2341309	0.62
293.0678406	0.15
294.4381714	0.62
295.1795654	0.10
299.1397705	0.17
300.4543457	0.05
302.5419006	0.33
304.2793274	0.18
309.0569153	0.18
311.2422485	2.59
313.2507935	0.15
321.3364868	0.99
322.2144775	2.52
323.5007324	0.19
327.2134399	0.14
328.0948181	0.07
330.8338928	0.15
336.0218201	0.19
339.2659302	11.42
344.4210205	0.17
350.9772949	0.73
355.3534851	1.49
356.2428589	0.21
358.1826172	0.67
359.2014160	0.74
360.2595825	0.12
362.8120728	0.15
365.1403809	0.06
366.0463257	0.14
367.2330322	1.11
368.3286743	1.30
369.8231201	0.12
373.1043701	0.97
379.2606812	0.40
380.9431763	0.13
386.4080811	0.56
387.4350586	1.38
394.4307861	1.00
395.4226074	1.92
396.2759399	5.09
399.3399658	0.32
407.6943359	0.08
412.2731323	0.58
413.4447632	0.08
415.1813354	2.97
415.7941284	0.42
419.6084595	0.46
425.3037720	0.48
426.2011719	0.13
427.2720337	0.03
429.0332031	0.12
435.6470947	0.05
440.5787354	0.66
442.1945801	2.69
452.2535400	0.32
453.2921753	0.64
454.4899902	0.16
455.2686768	0.10
463.1525269	0.10
464.4096069	2.82
469.0166626	2.04
470.2611084	19.25
470.8724976	0.28
472.3747559	0.72
474.3674316	1.29
476.4863892	0.17
481.3613892	10.44
482.0757446	0.07
483.2127075	1.68
486.2998657	0.37
487.3188477	4.63
491.5031128	3.22
492.3756714	20.85
494.9155273	0.36
497.3829346	0.14
498.4592285	1.48
500.3640747	2.96
509.3857422	42.64
510.6937866	0.16
512.3872681	0.09
515.1169434	0.15
520.1500854	0.16
525.8234863	0.77
526.5097656	0.56
527.8775635	3.59
528.5305176	9.09
537.5150757	0.05
538.3400269	3.35
539.5418091	1.31
543.4944458	0.87
555.4754028	7.90
565.3562622	2.43
566.4441528	11.80
578.0861816	0.08
580.2429810	0.37
583.4231567	57.25
593.4754639	0.29
594.6002808	0.14
595.7271729	0.23
597.3054199	0.24
604.0418701	0.28
605.7234497	0.36
606.6114502	0.47
607.2682495	0.49
611.3416138	15.15
612.4682007	3.33
621.7734985	0.76
622.5410156	6.78
623.5289307	9.34
624.6694336	0.86
625.6132202	0.44
628.3073120	0.42
637.5164795	0.53
638.2949219	1.72
640.3579712	59.09
641.0182495	0.78
642.3182983	1.80
651.4548950	2.17
656.3008423	2.91
666.2955933	0.39
668.1347046	0.20
674.9401855	0.23
675.7062378	0.35
678.4086914	0.37
684.2512207	0.50
690.8746948	0.41
696.4597778	0.27
700.2400513	0.09
708.0267334	1.67
708.6390991	6.43
709.6600342	0.43
718.5086060	8.03
725.4877319	100.00
726.0980835	0.71
735.5160522	29.78
736.5507202	42.51
753.4894409	12.98
754.6758423	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	330.07
Annotation	Unknow
Peak:m/z	Relative Intensity
117.0019073	0.02
118.0587692	0.01
152.1476288	0.01
161.7719574	0.00
167.0072327	0.04
191.3087769	0.00
198.3525085	0.01
207.1526642	0.01
209.2299500	0.03
224.9834595	0.00
235.1435242	0.01
235.9720459	0.01
251.4953613	0.00
253.2532959	0.01
270.4310913	0.01
286.9812317	0.00
296.1791382	0.01
297.2220154	0.01
299.3347473	0.08
300.2152710	0.02
301.2369385	0.00
311.1999207	0.08
312.3269043	0.01
314.1113281	100.00
315.1112366	20.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.22
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
145.1298828	0.17
147.0826569	0.46
157.1878204	1.26
158.8939819	0.44
160.8948975	0.09
163.0175934	1.92
165.0563965	2.74
167.2071533	0.08
170.0575104	0.42
171.2171173	0.17
173.0497437	0.25
175.0982056	17.20
176.1300049	0.64
176.9889984	0.08
181.3276825	0.62
183.3498688	0.20
186.9689484	0.81
188.9980774	1.65
191.1323090	1.44
192.9844971	7.00
194.0605469	0.11
195.0867615	0.61
197.1967468	0.11
199.1366882	0.92
200.9537354	0.23
202.0342102	0.58
203.1230469	0.18
205.1421356	0.25
209.0615845	0.46
213.1420288	2.52
214.0657043	0.20
215.1224976	0.39
217.1019440	1.39
219.5364380	0.19
221.1556549	0.50
222.9058838	1.53
227.1429138	0.29
229.1906128	3.75
231.0417328	1.78
233.3386230	0.30
234.9045715	0.37
236.1982422	0.59
239.2640533	0.93
240.1285095	0.63
240.9298553	0.23
242.3084106	0.19
243.0344391	0.86
245.2135315	1.06
246.2113495	0.09
247.1523895	2.35
249.2239380	2.03
251.1247406	8.55
251.7610168	0.11
253.2872009	1.36
253.9868011	0.32
256.0474854	0.06
257.1339417	0.58
259.2926025	1.22
261.1809692	2.21
263.1539917	0.09
264.9602051	0.07
267.0270996	0.47
269.2640381	8.11
271.1715393	3.16
272.0954895	0.39
275.2867432	8.86
277.2597656	4.36
283.0750732	0.19
285.2219238	1.10
287.1842651	18.94
291.2405396	0.90
293.0603638	0.50
294.9670715	0.87
299.2969360	0.70
300.2355957	0.39
301.3645020	0.35
303.2671509	8.13
305.1764526	100.00
305.7786255	0.17
311.2064209	0.29
312.8283691	0.37
315.3379517	0.52
317.3175049	0.51
319.2762451	0.43
325.3709717	0.72
327.3040771	0.15
329.3464966	0.23
330.7641602	0.46
331.3962402	0.51
333.3720703	0.39
334.4261475	0.45
340.4425049	0.16
341.2416382	0.60
342.1882935	0.48
343.3083496	1.87
345.1370239	0.09
349.2748413	1.68
351.4935913	0.19
353.3056641	0.07
354.4226685	0.52
355.2446289	0.21
357.0466309	0.42
357.6890259	0.37
361.2908936	8.82
365.2972412	0.12
369.3085327	0.14
371.9852295	0.81
379.1686401	0.56
381.4396973	0.15
383.3121948	1.97
385.3551636	0.26
391.3073730	1.19
399.3506470	0.25
401.3109741	1.19
405.5242310	0.32
413.4269409	0.76
415.0554199	0.16
417.4792480	0.12
423.3247681	1.37
425.2991333	0.63
427.3255615	1.86
429.4691772	0.35
430.1647339	0.81
431.2743530	0.55
433.2261963	0.37
443.3284302	1.82
445.3562622	1.86
453.2210693	0.10
454.5775757	1.41
455.3994141	0.78
458.3901367	0.14
459.4589233	0.39
471.3157349	0.40
472.2699585	2.38
473.3319702	2.46
475.0736084	2.29
477.4718018	0.57
487.3119507	12.58
501.3279419	5.25
504.0123901	1.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2084
Annotation	6-O-Oleuropeoylsucrose
Peak:m/z	Relative Intensity
148.9915466	1.06
173.0571594	0.41
179.4322968	0.31
193.2300720	0.31
198.0745544	0.31
220.9121399	0.22
233.1824036	0.39
238.9548645	0.44
282.8475647	0.22
283.8138428	0.87
293.1282959	12.90
301.2832642	0.33
327.2614746	3.45
327.8628845	0.24
334.3775024	0.85
343.0061646	2.28
344.2488098	2.73
345.1773682	3.22
353.3826904	0.31
361.0669556	0.26
362.4878540	0.51
363.5672913	1.20
420.3666992	0.71
427.1097412	0.31
447.4016724	1.04
461.3363647	100.00
462.7822571	0.22
465.4418030	0.22
472.3244324	2.48
475.9167175	4.29
477.2831421	2.58
489.5111694	0.69
491.1801453	10.38
492.1448059	15.80
492.7549438	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1613
Annotation	Butrin
Peak:m/z	Relative Intensity
205.2613525	0.04
221.0601196	0.07
269.0729065	0.10
275.3112793	0.01
293.3723755	0.06
297.8960571	0.05
299.1737061	0.13
300.9940796	0.05
312.2551270	1.67
319.0079956	0.14
325.9740601	0.16
327.0487671	0.04
335.2254028	0.05
339.9072266	0.28
341.0300293	0.52
347.3057251	0.05
350.2191772	0.03
355.3346558	0.55
363.3199463	0.03
365.2220459	0.38
368.1195679	0.12
369.1204834	0.04
370.1696167	0.14
370.8654175	0.03
377.3953247	0.06
380.3228760	0.05
381.2323608	0.09
383.1723022	67.61
385.6585083	0.06
393.1723022	0.12
395.2051392	0.89
397.3104248	0.12
398.0752563	0.03
405.2457886	0.16
407.1684570	0.05
409.3723755	0.02
411.3739624	0.30
413.1843262	29.39
413.8410034	0.04
419.3394775	0.04
425.2494507	2.32
425.8900146	0.06
427.2668457	1.20
437.3138428	0.04
439.4710693	0.17
441.2782593	0.09
443.2053833	2.73
449.4423828	0.33
455.1597290	1.89
457.2514648	0.30
459.6862183	0.20
461.1388550	0.07
467.2661743	1.52
472.9713135	0.06
474.3654175	0.05
475.0979004	0.14
479.1876221	0.06
483.0927124	0.04
485.2557983	4.03
497.1532593	0.27
501.3359375	0.13
503.1975708	100.00
504.0115356	0.01
513.3426514	0.23
515.3210449	1.35
517.3686523	0.06
521.5435181	0.02
527.3235474	0.07
529.3504639	0.17
533.2827759	17.01
541.1193237	0.04
545.3077393	1.78
547.3136597	0.42
551.3685913	0.09
557.1859131	0.18
559.6174927	0.03
563.0623169	1.19
575.0916748	1.56
587.2194214	1.56
592.8625488	0.13
593.6985474	0.14
605.2793579	5.17
606.2389526	0.05
608.4975586	0.12
623.3381958	1.62
624.2470093	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.143
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
328.4256592	0.01
330.9570312	0.01
346.1477661	0.12
361.1473999	100.00
362.0189209	0.01
403.4276733	0.01
435.4174194	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	915.2775
Annotation	Unknow
Peak:m/z	Relative Intensity
299.0509644	0.03
301.1716003	1.67
302.1776428	0.85
306.3066406	0.01
325.1151733	0.08
326.0990601	0.06
339.3177185	0.08
343.2094727	0.61
344.3696289	0.42
355.1241150	0.06
356.1900330	0.06
357.4384766	0.02
358.0414429	0.07
373.9747314	0.02
382.4223022	0.03
385.1956482	0.02
403.4656982	0.08
404.3230286	0.25
409.6339417	0.03
415.1910400	0.02
427.3967896	0.02
442.3767700	0.14
445.1636353	0.08
446.3140259	0.10
459.2130737	1.23
460.2371216	0.63
463.2701416	0.20
464.1823120	0.47
473.3822632	0.02
489.1718140	0.18
490.2762451	0.77
502.0366211	0.19
505.2694092	0.06
506.4257812	0.25
515.5737915	0.05
530.4029541	0.02
532.2254028	0.10
545.5627441	0.05
546.5405884	0.34
548.4857788	0.11
563.8629150	0.08
572.3462524	0.05
590.2081909	0.05
591.3635864	0.12
592.2431641	0.26
607.0242920	0.07
608.2131958	0.17
609.3422241	46.03
610.3062134	100.00
610.9260864	0.27
618.2608643	0.02
621.5499878	0.07
638.4912109	0.05
651.2981567	2.96
652.4129028	8.44
660.2386475	0.12
668.1666870	0.04
691.3834229	0.80
692.3753052	1.97
693.2833862	0.04
694.5090942	0.02
753.1965942	0.02
754.3428955	0.65
771.5281372	0.73
772.3463745	2.96
772.9841309	0.07
813.7376099	0.56
814.4048462	2.88
854.3143311	2.46
855.2754517	0.15
888.6115112	0.06
898.6102905	0.06
916.3223267	56.09
917.2914429	70.55
918.1751709	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1619
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
183.2532349	0.07
203.0914307	0.12
211.2238159	0.11
215.4954834	0.22
225.3138428	0.07
227.0814667	0.77
228.2349243	0.08
243.1061707	0.17
255.0247040	0.14
270.1326294	0.02
280.8879395	0.06
287.1677856	0.06
296.2721558	0.16
299.1252441	5.78
300.0383911	1.07
305.1760864	8.76
306.2745972	0.49
314.1345215	24.79
315.1029053	3.72
316.1453857	0.32
327.8735657	0.03
329.1256104	92.36
330.2037354	12.45
343.3408813	0.06
356.2192383	0.10
371.1503296	1.91
372.1152344	0.08
402.3905029	0.14
459.5626831	0.25
461.4386597	0.05
473.3901367	0.13
476.4078979	0.29
477.3282471	0.23
491.2307739	100.00
492.2419434	18.66
492.8471680	0.12
519.2081299	0.52
520.1989136	0.20
533.2543335	71.60
534.3377075	14.58
560.3200073	0.11
573.2974243	35.90
574.3073120	9.33
575.3072510	0.07
585.4365845	0.16
600.4025269	0.04
617.4740601	0.13
620.1600342	0.05
636.2831421	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1142.31
Annotation	Unknow
Peak:m/z	Relative Intensity
329.1282959	0.01
475.1915283	0.02
1141.2672120	100.00
1142.3527830	10.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.208
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
146.7933350	0.13
153.0570374	0.04
157.0658569	0.11
159.1601562	0.06
165.1757202	0.03
167.1256561	0.15
173.2184296	0.02
175.1493225	1.71
176.8380737	0.05
177.9871979	0.05
189.2058716	0.02
193.0989075	0.52
205.4117737	0.03
213.4859619	0.03
215.3569946	0.04
216.7657776	0.06
221.1228333	0.03
223.3794250	0.02
225.3686218	0.19
227.2888031	0.05
229.2350159	0.05
231.3857727	0.02
233.3462982	0.05
236.3308868	0.09
239.0445099	0.08
241.2538452	0.10
245.0153809	0.06
247.1909180	0.48
249.4375610	0.03
251.1330261	0.69
253.1669006	0.04
254.2807312	0.02
257.0872803	0.20
259.0466003	0.02
261.2897339	0.14
263.4217834	0.14
269.2876587	0.18
275.2966919	0.24
277.1778564	0.55
287.1312561	1.17
289.2992554	0.07
291.2120361	0.32
293.0552368	0.02
296.9115295	0.15
300.0458069	0.05
301.1614685	0.36
305.2148438	11.27
311.0901489	0.17
313.1628418	0.16
321.4714050	0.09
329.3231201	0.21
331.4116211	0.10
332.0198669	0.04
341.2930603	0.10
343.1268921	0.56
344.0600281	0.17
345.0636292	0.03
347.3403931	0.12
349.1685181	0.36
350.9903564	0.06
353.3942871	0.20
357.5163574	0.04
358.3749390	0.10
359.2624817	0.15
365.3931580	0.08
369.0634766	0.02
370.4499207	0.06
371.6186523	0.29
372.2597046	0.01
380.3965454	0.05
382.2034912	0.03
391.5824280	0.05
401.2621765	0.32
409.3985291	0.11
415.2731018	0.30
416.2262878	0.09
417.0588989	0.20
427.4411926	0.09
442.4908752	0.13
443.8440552	0.17
445.2618408	100.00
445.8703918	0.58
447.3373718	0.17
459.2725525	0.09
460.2369080	0.15
461.4853821	0.13
463.0716858	0.14
467.2695007	0.02
472.4270630	0.07
475.5254211	0.10
487.3786011	0.46
490.1619263	1.33
490.8565979	0.02
506.4004211	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.2081
Annotation	1-Octen-3-yl primeveroside
Peak:m/z	Relative Intensity
124.9495544	0.03
130.6907349	0.02
142.8294678	0.11
160.9774170	0.46
177.2106018	0.10
178.8334961	0.10
183.1178284	0.28
191.3132935	0.02
195.1596680	1.14
207.0067749	0.47
209.0968475	0.01
213.1011505	100.00
223.2253723	0.40
226.9888916	0.25
237.1325378	0.14
249.0947266	0.14
255.2482300	1.09
259.0264587	0.02
267.0571289	0.88
279.2075806	0.04
284.2954407	0.06
285.1956177	0.37
297.2269897	0.07
309.2807007	0.05
314.9544067	0.25
339.6366882	0.03
345.3640137	0.14
356.8355103	0.04
374.4043884	0.71
375.0834045	5.01
377.6612854	0.03
393.4148254	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	168.1014
Annotation	a-Methyldopamine
Peak:m/z	Relative Intensity
137.0829620	0.20
149.9579163	100.00
150.7627411	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.1276
Annotation	2,3-Butanediol glucoside
Peak:m/z	Relative Intensity
72.8908081	3.13
82.7122803	0.05
84.8932953	10.71
88.9775238	0.08
90.8121033	5.38
96.9276733	4.21
99.1672974	0.22
100.9881744	0.13
108.9534302	1.80
113.8622437	0.10
115.0404816	0.33
117.1098175	0.22
118.9866486	0.15
119.8680878	0.05
121.3908386	0.05
122.9827423	0.21
125.0474243	0.16
126.8306885	14.40
128.0357971	0.06
128.7477875	0.36
130.9765015	0.05
132.1484070	0.48
132.9030304	1.08
136.0607605	0.06
137.0885925	0.03
142.9545441	0.07
144.9205780	41.07
146.9238739	0.12
148.0904083	0.06
148.8289948	0.30
151.0886841	1.66
152.1905975	0.15
152.9081879	0.43
156.9333191	4.62
161.2727509	0.04
162.8997955	100.00
164.1086273	0.05
164.9961090	0.55
166.8832397	0.38
168.9512329	8.33
170.7532959	0.22
177.1015320	0.28
179.1438446	0.07
180.7863464	0.56
182.9553375	0.12
184.3467865	0.15
186.4797211	0.76
187.2303162	0.32
189.0340881	0.55
191.0216827	0.52
192.8191071	0.28
194.9890594	0.15
196.7429657	0.08
198.9341888	17.59
205.2747955	0.15
207.2379608	1.54
208.2783661	0.29
209.2291412	0.11
210.0599823	0.32
211.2341766	0.64
212.0136566	0.77
216.9462280	20.31
217.9386139	0.09
223.1730804	0.17
225.1054535	1.23
225.7892303	0.36
234.9297943	6.95
235.8428345	0.18
238.0797729	0.23
238.9836426	0.26
244.4158936	0.83
252.9949799	0.52
254.2968292	0.50
261.1112671	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.4036
Annotation	Unknow
Peak:m/z	Relative Intensity
227.5162354	0.03
228.1900940	0.14
230.1043091	0.03
231.4086914	0.07
232.2699585	0.01
239.1998901	0.04
240.2585754	0.03
241.2378235	0.04
242.0474396	0.01
243.1557312	0.28
244.3976135	0.10
245.1517334	0.08
246.1393433	0.11
249.1780090	0.02
250.1266632	0.03
253.2436218	0.07
254.1604309	0.10
257.2632141	0.05
258.4123840	0.11
259.3192444	0.10
260.1676331	0.11
261.1573181	0.45
265.0295715	0.04
267.4525757	0.04
270.0113831	0.02
276.5487976	0.12
277.2587585	0.66
278.2826538	0.15
281.1654053	0.03
283.0896912	0.10
284.2110901	0.09
285.0975037	0.03
287.1581726	0.27
288.2538452	0.05
289.2205811	0.03
292.3764648	0.06
293.3090820	0.12
294.3250732	0.02
297.2525330	0.28
298.4182739	0.11
299.0411072	0.07
301.1731567	0.42
302.2716675	0.12
303.3160095	0.09
304.9376221	0.07
306.3746033	0.05
307.1324768	0.05
308.3326721	0.06
309.1621094	0.08
310.1188049	0.23
311.5418701	0.07
313.1133423	0.03
314.3480225	0.02
315.3341370	0.13
317.3240356	0.06
318.5195923	0.02
320.5383911	0.03
324.1241760	0.26
325.3770752	0.12
326.2982788	0.16
329.8589783	0.02
331.2099304	0.13
333.1914062	0.05
334.3341980	0.04
339.2097168	0.03
340.3207397	0.27
341.2219849	1.64
342.1642456	0.17
344.2720032	0.07
350.3419800	0.05
351.3845825	0.09
355.3741455	0.09
356.3285522	0.09
357.7174988	0.44
358.3667603	1.74
359.0693970	0.13
363.1899414	0.01
367.3999634	0.04
369.3394775	0.06
374.4954224	0.54
375.5971680	0.02
376.4749146	0.42
377.3610840	0.15
378.1126709	0.10
379.3405762	0.10
380.2224121	0.14
381.7838745	0.21
382.4511719	0.02
383.4416504	0.03
386.3304443	0.09
387.3748169	0.25
388.3705444	0.04
389.7925415	0.16
390.4342041	0.36
391.4320679	0.15
392.3330078	0.07
393.4606323	0.01
394.5153809	0.01
395.4658813	0.06
396.3515015	0.02
398.3699341	0.85
399.5874634	0.09
400.3319702	0.06
401.4804688	0.06
402.5055542	0.14
403.5073242	0.07
404.4139404	0.02
405.3053589	0.33
406.5532837	0.03
407.4303589	0.17
408.4066162	1.13
409.4858398	0.10
410.6254272	0.10
412.2885132	0.59
413.7435303	0.09
414.4327393	0.12
415.7881470	0.05
416.4140015	0.04
418.3211670	0.02
422.3041992	0.30
423.2318115	0.01
424.2327271	0.03
427.4699707	0.04
428.4296265	0.02
431.1988525	0.09
432.3468018	0.01
434.2305908	0.41
435.2674561	0.07
436.5504761	0.20
437.4978638	0.40
438.4454956	0.09
439.4790649	0.10
446.2128906	0.03
448.3511963	0.22
449.3557739	0.02
450.3900757	0.10
454.3197632	0.12
455.4016113	2.95
456.4736938	0.91
457.4424438	0.04
459.3947144	0.05
461.7284546	0.20
462.3429565	0.41
464.4040527	0.18
467.2894287	0.05
468.5203247	0.03
469.2343140	0.02
471.6367798	0.03
472.4063721	0.66
473.5668945	0.18
474.3422241	0.20
480.7484131	0.11
482.2274170	0.04
483.4835205	0.04
485.5299683	0.14
486.7529907	0.03
487.4080200	0.01
488.5174561	0.33
489.3969116	0.04
490.2315674	0.05
491.5409546	0.20
492.4515381	0.12
493.5521240	0.24
494.4662476	0.33
496.2156372	0.06
498.5032959	0.33
499.3303833	0.02
500.4780273	0.04
502.2573242	0.04
503.6771851	0.05
505.3188477	0.14
506.5101929	0.18
507.4932251	0.09
508.9863281	0.46
509.5938110	1.98
510.5439453	0.40
511.3747559	0.06
512.6636353	0.23
513.7791138	0.14
515.3084106	0.03
517.5012817	0.04
518.3179321	0.05
519.5301514	0.33
520.4662476	0.28
521.6043701	0.06
525.5750122	0.11
526.4448853	0.40
527.4931030	0.17
528.5052490	0.02
529.6296387	0.15
530.7264404	0.09
531.5551758	0.01
532.3572998	0.14
534.5134888	0.40
535.4930420	0.23
536.4475098	0.91
537.4682617	0.23
538.5966187	0.05
539.6371460	0.14
541.5525513	0.10
542.4351807	0.03
543.4493408	0.10
545.4094849	0.29
546.1798096	0.15
548.5811157	0.13
551.4692383	0.23
552.4330444	2.41
553.4523315	0.83
554.4039307	0.65
555.6913452	0.07
557.4151001	0.03
559.5216675	0.17
562.5883789	0.08
563.6198730	0.12
565.4973755	0.11
566.5592651	0.38
568.4396362	1.93
569.4898682	1.69
570.4447021	0.19
571.3858032	0.16
574.3981323	0.15
575.4141235	0.06
577.5407104	0.03
578.3471680	0.03
579.3931274	0.99
580.4239502	0.16
581.5601807	0.07
582.3783569	0.02
583.6180420	0.66
584.5123901	0.22
586.4398804	8.77
587.4813843	1.26
590.4511108	0.22
591.5454712	0.27
592.5552368	0.56
593.5358276	4.74
594.4815063	0.67
595.5233765	0.59
596.6339111	0.40
597.5103149	0.07
599.6416016	0.04
602.3937378	4.75
603.3956909	0.78
605.5010376	0.11
606.5048218	0.01
607.7616577	0.19
608.6340942	1.23
609.4876709	5.30
610.4818115	3.81
611.5150757	0.42
612.7444458	0.11
613.6592407	0.02
617.3364868	0.22
618.4641724	0.22
620.5736694	0.09
621.3380127	0.05
622.7897339	0.07
623.6669312	0.11
624.4607544	0.07
625.4103394	0.05
626.4702148	5.70
627.5812378	0.88
630.4000854	0.02
631.7521362	0.10
632.5663452	0.11
633.6121826	0.04
634.8812866	0.28
635.6021729	0.66
636.4578857	0.45
637.4535522	0.03
638.5249634	0.04
639.7628784	0.12
640.4457397	0.05
641.5652466	0.18
643.4172363	0.21
646.4411621	0.21
648.3971558	0.04
649.5227661	0.35
650.4689331	1.39
651.5462646	0.18
652.5304565	0.05
656.4826050	0.32
657.5880127	0.26
660.4627075	0.14
661.8682251	0.07
662.6271362	0.04
663.4799194	0.06
665.7364502	0.51
666.6634521	0.31
667.4553833	0.05
668.7988892	0.04
675.8086548	0.03
676.6981201	0.03
678.3408813	0.10
679.3480225	0.07
680.5983276	0.04
681.7827759	0.12
683.4727783	7.77
684.4047241	0.79
687.8292847	0.18
688.6861572	0.26
689.6940308	0.10
692.5055542	0.57
694.0090332	0.07
695.5493164	0.05
697.5040894	0.55
698.1427612	0.04
698.8567505	0.04
700.4887085	4.77
701.5194702	0.89
703.5492554	0.09
704.6425171	0.08
705.5904541	0.65
706.5239868	0.85
707.4216919	0.13
711.7517090	0.14
713.0124512	0.06
713.6642456	0.25
714.6295776	0.15
718.5516357	0.05
719.6859741	0.04
720.8738403	0.01
722.4183960	0.02
723.5931396	0.18
724.6918945	0.06
725.5263062	0.04
726.6829834	0.02
727.6965942	0.05
728.6155396	0.06
730.9949341	0.10
731.6363525	0.88
732.4987183	0.21
733.2736206	0.01
736.4939575	0.39
737.4082642	0.17
740.4954224	6.37
741.5991821	2.23
749.5591431	7.87
750.6501465	1.50
752.4758911	0.38
753.4873657	0.69
754.5947266	2.32
755.4449463	0.34
761.5110474	0.01
762.3247681	0.08
765.8260498	0.10
769.6842651	0.03
770.8970947	0.10
779.4814453	2.10
780.4721069	0.62
781.3728027	0.01
781.9760132	0.01
798.5251465	100.00
799.5134888	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.3283
Annotation	27-nor-campestan-3beta,4beta,5alpha,6alpha,7beta,8beta,14alpha,15alpha,24-nonol
Peak:m/z	Relative Intensity
179.1086578	0.26
188.8016968	0.06
193.1317291	0.07
235.1610107	0.69
253.0954285	8.44
254.0189056	0.10
255.2115479	0.10
259.2181702	0.15
261.4238586	0.11
269.2687988	0.11
277.3304443	0.05
279.2537231	100.00
346.3127441	0.07
349.1188354	0.19
355.1318970	0.11
357.3948975	0.03
367.1213989	0.11
399.1090088	0.09
420.3634644	0.04
449.3947144	0.04
465.0418701	0.08
481.2363281	0.07
488.2671509	0.13
502.5496216	0.28
515.1965942	18.90
516.6272583	0.18
523.1760254	0.16
525.5324707	0.18
529.8380737	0.18
530.4822388	0.04
531.4960327	0.04
541.2085571	0.04
542.3067017	0.15
561.4013062	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2038
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
164.3143768	0.73
165.0750275	6.32
177.1794128	0.06
179.0825500	10.69
193.1198120	0.11
195.0054169	45.33
204.7760315	0.14
236.1330109	0.06
239.0267639	0.12
263.2579651	0.08
272.2500000	0.25
273.2243042	0.07
308.9859619	0.07
312.1788330	0.36
327.1459351	26.09
333.2483521	0.04
334.3894653	0.06
343.0885620	0.08
356.8885498	0.18
373.2970581	0.11
375.0338135	100.00
375.6719971	0.23
401.5152588	0.11
416.9138794	0.11
421.4068604	0.09
434.2390137	0.26
445.2177734	0.26
457.7808228	0.07
458.9519043	1.65
461.3342896	0.09
471.4489746	0.03
491.2312622	0.25
493.0405273	0.06
495.6383667	0.22
511.8084106	0.18
534.3377075	0.07
536.3566284	4.47
537.0218506	18.46
537.8766479	0.15
539.3608398	0.84
547.4614258	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	683.18
Annotation	Haploside D
Peak:m/z	Relative Intensity
206.9892426	0.04
215.2444763	0.03
226.9442139	0.05
243.3330536	0.01
268.2194214	0.12
271.1787720	0.04
271.8744507	0.03
273.9969482	0.02
282.2169189	0.10
284.0631409	0.08
287.1700439	0.04
297.2578125	0.03
298.4443970	0.01
299.1773682	0.01
299.9103088	0.01
311.2041931	0.08
312.4349365	0.08
313.3744507	0.17
314.1854248	0.17
315.1034546	0.17
316.0220947	0.03
317.1654968	0.03
318.3110352	0.03
319.2122192	0.04
325.5454712	0.06
327.0930786	2.86
328.1735229	2.57
329.2681274	0.56
330.1698608	0.09
331.0319824	0.03
332.6361084	0.06
342.1231689	0.52
343.0274963	0.36
345.1164246	7.99
346.1667480	9.05
347.1693115	2.38
357.4565430	0.06
358.3594971	0.05
360.1219482	6.89
361.1658325	7.38
362.2379761	1.27
375.1624756	68.41
376.1735229	100.00
377.1342773	23.17
377.7609863	0.06
416.4375000	0.05
418.2176514	0.03
419.2471924	0.04
435.6146240	0.11
437.3881226	0.03
453.3405762	0.02
457.3789062	0.01
461.3510742	0.04
475.0714111	0.01
525.7197876	0.05
533.3417358	0.03
537.4017944	0.02
538.1654663	0.01
542.1986694	0.02
559.0234985	0.01
569.3847046	0.04
584.1984253	0.08
620.2184448	0.22
621.4283447	0.09
622.4920044	0.05
624.5198975	0.38
625.5761108	0.09
633.4147339	0.02
646.3218384	0.17
647.1544189	0.02
650.5095825	0.06
655.4984741	0.05
664.1160278	0.14
665.0632324	0.19
665.7396851	0.03
667.5751343	0.04
683.2056885	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2039
Annotation	Unknow
Peak:m/z	Relative Intensity
184.8482361	0.53
189.1493988	0.29
190.9205627	0.10
193.1520386	0.34
203.0917053	0.30
206.2495422	0.13
207.2184753	0.71
214.9018707	1.10
215.9301758	0.48
217.2788696	0.10
221.1128998	0.95
221.9964905	0.20
229.0778046	0.40
233.0252380	0.14
245.2843781	0.27
247.1319122	1.52
248.2827606	0.58
263.0775757	0.89
265.1622009	19.23
266.1534729	1.46
270.8163757	0.16
283.1130371	15.24
284.2572632	1.06
286.3179321	0.21
295.4234009	0.10
298.8633728	0.13
310.5203857	0.18
317.0692749	0.79
329.2439270	0.40
335.0800781	0.22
336.1626587	0.46
337.0197754	0.10
339.3367310	0.11
341.0679932	1.04
343.4052734	0.17
349.1625366	0.52
359.2855835	0.43
361.3678589	0.18
365.8941040	0.18
370.9544067	0.10
373.1101074	0.45
375.2626343	0.49
377.2025757	2.03
379.2527466	6.99
380.2117310	0.36
385.1207886	0.15
387.1664429	0.45
391.2116699	0.58
394.8994751	0.14
397.2761841	12.45
398.2644043	2.56
415.1833496	26.05
416.1749268	3.16
421.3625488	0.15
434.9647827	0.14
436.1209717	0.08
437.4451294	0.17
439.5770874	0.15
453.4458618	0.96
455.4547119	0.42
457.0981445	0.63
462.1101685	0.16
464.2351074	0.10
467.2655640	0.60
485.2243652	1.78
493.4111938	2.55
494.3225098	0.29
495.2802124	0.71
496.4451904	0.32
511.2064209	2.99
512.3193359	0.43
515.1679077	1.42
516.3607788	1.02
529.2312012	7.59
530.3677368	0.28
537.3154297	0.46
555.3471069	7.40
556.2888184	1.53
559.9729614	0.15
560.7987671	0.10
561.4983521	0.23
569.2428589	1.57
570.1787109	0.59
573.2344971	12.71
574.3412476	3.11
587.3038940	70.44
588.3674927	17.33
596.8579712	1.44
597.4717407	1.76
598.5150146	0.68
605.2874146	100.00
606.3157349	14.74
615.3029175	42.27
616.3282471	6.78
627.4567261	0.25
628.7841187	0.30
629.3976440	2.45
630.3501587	0.72
648.2649536	40.33
648.8812866	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1621
Annotation	Safflomin A
Peak:m/z	Relative Intensity
175.0689240	0.53
176.9341736	0.37
181.3264008	0.27
188.9803314	0.04
191.0037842	0.66
192.9884644	0.37
197.3242493	0.08
198.2675934	0.15
199.0377808	0.50
205.0248260	0.19
206.0982819	0.23
209.1490631	0.96
212.8116150	0.04
217.0747681	2.07
218.8805237	0.09
229.0442810	0.11
233.1455841	0.34
234.0793915	0.74
235.1457367	2.63
239.1571655	0.45
239.9813690	0.07
241.1430054	1.32
243.1286316	0.24
247.0888214	0.19
251.1394958	0.15
257.2923584	0.08
259.1745605	0.89
265.1630554	0.87
269.1576843	0.57
271.1279297	0.04
275.2206116	0.39
277.1574402	0.11
280.3794250	0.05
285.0811768	13.34
287.2630005	0.34
288.8358765	0.19
289.4740906	0.13
293.3020020	0.08
299.2096558	0.23
301.3280029	0.17
303.0654907	14.95
304.9987793	0.21
306.4656982	0.18
307.1484375	0.17
308.0089111	0.08
308.8762207	0.08
313.2345581	25.97
318.2159424	0.07
319.2235107	0.33
324.2521362	0.05
327.2702637	0.39
329.0463257	0.40
330.6713867	0.05
337.1405640	3.45
339.4829102	0.15
343.3839722	0.06
345.1713867	7.28
347.2676392	0.48
352.8289795	0.10
355.1134644	0.94
357.0192871	0.77
359.4200439	0.06
362.4154053	0.07
369.7164917	0.06
371.2201538	3.92
375.1389771	2.51
381.1997070	75.91
381.8461304	0.35
383.2281494	0.51
384.2416382	0.08
387.3731689	0.10
391.1022949	0.08
399.1290894	0.06
400.0031128	0.26
401.2483521	3.17
403.6520386	0.39
410.5953369	0.09
411.2888794	0.10
412.1975708	0.13
413.4343872	0.06
415.2338257	0.54
416.3761597	0.09
419.1793213	0.11
429.3263550	0.20
431.2965698	0.95
433.1768188	31.26
437.2526855	0.09
441.0983276	0.05
447.1502686	0.96
448.4067993	0.06
449.2869873	0.62
458.0250854	0.15
459.2224121	0.49
461.1092529	0.41
467.5342407	0.20
473.2840576	5.43
475.3128662	0.27
477.4070435	0.14
483.2718506	2.40
484.4500732	0.21
485.2999268	0.22
487.1386108	2.21
487.8351440	0.25
489.2484741	0.24
491.1660156	67.98
496.3681030	0.20
501.2439575	100.00
503.0940552	0.49
504.6373291	0.08
506.5693359	0.11
517.2267456	0.13
520.2042847	0.19
521.3311768	0.34
529.2883911	0.07
531.9916382	0.06
533.2354736	0.32
549.4272461	0.07
551.4719849	0.17
564.1015015	0.15
565.5192261	0.49
566.3991699	1.11
567.3740845	0.36
574.3203735	0.25
575.5185547	0.55
583.3516235	2.73
592.3169556	0.50
593.3210449	8.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.1931
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
175.1251068	0.09
178.9750214	0.51
206.9891357	0.94
264.3724060	0.08
267.2334595	0.10
279.0881958	0.23
282.4456177	0.05
283.1400146	0.18
294.2880859	0.75
297.3858643	0.17
307.0441284	0.08
308.3222046	1.09
309.1166992	4.38
312.1335449	1.14
313.2750244	0.83
321.0560913	0.17
324.2121582	6.76
325.0532227	0.48
327.2361450	60.82
339.1738892	100.00
346.3222046	0.18
356.3280029	0.92
356.9576416	6.23
358.0048218	0.12
367.0859985	0.07
371.1619263	0.08
403.3861694	0.12
413.3168335	0.09
414.1658325	0.44
415.1374512	0.20
432.2297363	0.23
443.1682739	0.36
444.3154907	0.12
457.6209717	0.26
460.2658691	0.11
501.5767822	0.06
503.5275879	0.18
504.5383301	0.23
505.1976929	1.30
518.4690552	2.04
519.1975708	0.94
521.3842773	0.93
522.2352905	0.24
535.2211304	0.14
547.3051758	0.36
549.2650757	0.10
549.8693237	0.20
550.4824829	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.215
Annotation	Troxerutin
Peak:m/z	Relative Intensity
217.1952057	0.13
224.2403259	0.17
225.2689056	0.19
239.1795959	0.04
251.1879272	0.04
253.1461182	0.02
269.0931396	38.15
283.1004028	0.10
291.1422729	0.26
293.2424927	0.36
307.2156372	0.06
311.1217346	0.40
313.1231384	0.02
321.2264404	0.08
323.1793823	0.31
335.2091675	0.23
341.3098755	0.11
367.2609863	0.05
371.1508179	0.03
376.9434814	0.08
423.2168579	0.03
457.3027344	1.47
505.0168457	0.06
518.1921387	0.03
524.5573730	0.04
529.0981445	0.03
559.3076782	1.75
560.4745483	0.07
577.2942505	1.97
602.0896606	0.03
605.4785156	0.04
623.5858765	0.09
629.3097534	0.02
679.2763062	0.05
685.0464478	0.05
705.3113403	0.30
723.3414307	100.00
724.2550659	1.66
724.9346924	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.1906
Annotation	Diosmetin 7-Apiosyl-(1->2)-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
185.0670624	0.08
201.2426758	0.05
211.2839966	0.02
212.9851379	0.03
253.2231903	0.04
256.0987549	0.01
258.4608459	0.02
266.9915771	0.02
269.1198120	0.04
273.2244263	0.01
284.1075439	2.93
299.0324707	0.13
301.2099609	0.07
312.0865173	9.15
313.2233887	0.02
314.1385498	0.03
315.1566162	0.06
322.2902832	0.03
330.1473389	6.75
330.8456421	0.06
343.8915405	0.07
345.1632080	100.00
345.7659912	0.36
421.9176636	0.03
461.2119141	0.09
462.7097168	0.06
489.3682861	0.09
503.2664185	0.02
507.3064575	0.15
538.8009033	0.07
569.9093628	0.07
589.2375488	0.39
591.2205200	0.10
592.4949951	0.12
615.3494873	0.21
619.6316528	0.04
632.3232422	0.03
633.1958618	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9366
Annotation	Unknow
Peak:m/z	Relative Intensity
86.8050537	0.03
114.8752289	0.58
129.0697937	0.05
130.8474731	1.93
133.0179138	0.04
146.8522949	0.63
158.9650726	7.69
174.8882751	100.00
214.9414673	0.12
217.1666565	0.21
232.9308777	0.19
244.9506226	23.90
259.1949463	0.04
261.1256104	0.56
273.2084351	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	669.2036
Annotation	Butrin
Peak:m/z	Relative Intensity
301.1801147	0.06
305.2964172	0.07
306.3443909	0.07
307.2999573	0.28
330.2379150	0.06
331.2337036	0.72
332.2470398	0.49
333.1903381	0.29
346.1608276	0.55
346.7736206	0.29
348.2399292	0.31
361.1336060	6.30
362.1654663	7.25
363.1854248	0.62
375.2122192	0.06
402.9296875	0.05
461.7409668	0.14
492.5932617	0.14
498.0056763	0.11
506.1576538	0.12
507.6209106	0.17
510.2424316	0.03
523.2733765	3.87
524.2514038	11.53
525.2852173	2.94
546.4996948	0.15
552.6249390	0.18
565.4730835	0.82
566.3373413	5.76
567.2716064	0.57
605.3659668	0.07
606.2752075	1.46
607.4744263	0.08
623.3013306	100.00
624.0051270	0.82
639.3303223	0.12
651.5191650	0.06
668.9880981	5.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1876
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0548248	0.20
151.0950928	1.35
151.9445496	0.32
152.9667053	0.33
160.9597931	0.24
165.0809021	0.03
176.9553833	0.37
177.9524536	0.27
179.0537415	0.18
185.0242615	0.06
190.9004822	0.09
199.9918823	0.08
210.1264954	0.07
211.3649292	0.05
220.2095032	0.14
221.0645142	0.07
228.1054993	0.12
251.1146240	0.47
252.1554260	0.27
253.1809998	0.12
254.1338196	0.07
255.3679810	0.05
263.0852356	0.07
271.0767822	47.46
272.0775452	100.00
273.0609436	38.93
273.6698914	0.02
282.1190186	0.09
296.2339172	0.43
309.3353882	0.04
314.1583252	0.76
315.3509521	0.51
329.2186584	0.36
347.4739685	0.33
361.2822876	0.08
374.2844238	0.07
375.1438293	0.05
389.1527710	4.36
390.5716858	0.14
399.0035400	0.21
401.6271057	0.04
404.6179504	0.28
405.4742432	0.08
417.2440186	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.2139
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0310364	0.57
194.0640869	1.25
195.0030212	7.31
196.2198029	0.36
203.1474609	0.23
209.0919800	9.45
210.0466003	0.25
225.9424744	0.07
269.3053589	0.38
282.2656860	0.10
288.8517456	0.08
300.8901062	0.28
307.1073608	0.14
310.2243042	0.04
323.1406860	0.04
325.4584351	0.06
327.1106567	0.32
342.2698975	0.05
343.5196533	0.07
355.2619019	0.21
357.1827393	26.99
358.2202759	3.16
367.3044434	0.03
368.1973877	0.23
386.8981323	1.15
391.5343628	0.08
397.9463501	0.04
405.0643921	100.00
406.1036987	5.36
419.1564941	0.19
420.3087769	0.04
425.3845825	0.04
440.2223511	0.03
447.1682739	0.24
450.8016357	0.06
452.3806763	0.14
453.3116455	0.09
463.2708130	0.15
469.2970581	1.11
470.1633911	0.30
489.2326050	0.41
494.4367065	0.17
495.2982788	0.10
500.2943115	0.08
502.0964966	0.07
510.2394409	0.08
511.3506470	0.47
523.6530151	0.04
525.7704468	0.16
528.6546631	0.05
532.1411743	0.05
533.1261597	0.12
536.3536987	0.02
538.3779907	0.06
559.3016968	0.15
566.3114014	2.33
566.9650269	4.49
567.8256226	1.72
570.1957397	0.11
577.4104614	0.07
581.2892456	0.48
583.6356812	0.17
595.1447144	0.11
613.8624268	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1669
Annotation	Butrin
Peak:m/z	Relative Intensity
173.0647125	0.12
175.0303650	0.60
175.8854370	0.22
177.0995026	0.69
188.9347229	0.26
190.9818420	0.27
192.1302338	0.04
193.0930176	0.70
194.2948151	0.03
196.9341431	0.34
204.8698120	1.48
205.9520874	0.20
207.1161957	0.03
208.3792419	0.09
209.1187897	0.05
210.9777679	1.35
217.0079041	1.57
219.0155792	0.08
223.0307617	0.43
225.0995636	0.11
229.2512207	0.04
233.2297668	0.06
235.0928802	11.05
236.1267853	0.90
238.8846588	0.09
241.0786743	0.07
243.0609436	0.08
247.3059998	0.06
251.2380371	0.09
252.9421692	0.49
254.2338257	0.16
271.1432495	0.99
272.1182861	0.27
276.9440308	0.16
278.1804810	0.03
279.2608643	0.22
280.2338257	0.22
287.1652222	8.49
288.1900635	1.21
290.0502319	0.07
293.1891479	0.09
294.6253052	0.10
295.2827148	0.43
296.0598755	0.09
297.1981812	0.53
298.0742188	0.36
311.1588440	0.27
313.1489258	0.25
314.2459106	0.03
321.3624268	0.02
323.3187866	0.03
329.1406250	2.05
330.3489990	0.14
337.2246094	0.03
339.1178589	2.47
340.1335449	0.47
341.1118774	0.26
353.0974121	0.35
354.2753296	0.03
357.1655273	5.78
358.1287231	0.93
359.1760864	1.05
363.2572021	0.19
367.1896973	0.07
371.1516724	0.50
381.0825806	0.23
389.1375732	0.24
396.1577148	0.12
399.1280518	0.17
413.1813354	0.43
415.2377930	0.23
431.3220215	0.28
433.1494751	1.38
441.2483521	5.24
442.3574829	0.13
443.2998657	0.59
444.3837280	0.06
445.0626831	0.04
449.1007690	0.09
457.6261597	0.08
459.2349854	100.00
460.1931763	19.84
469.3426514	0.26
473.3556519	0.07
475.3045654	1.84
476.2243652	0.22
535.4009399	0.06
551.5376587	0.06
559.5586548	0.24
577.3725586	1.60
578.3976440	0.62
596.2206421	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1333
Annotation	Oenin
Peak:m/z	Relative Intensity
173.9473114	0.03
176.7971954	0.03
241.1508179	0.02
262.0249939	0.02
313.8484192	0.02
328.2126160	0.05
331.1043091	3.38
343.3607788	0.02
346.1574097	0.01
347.9880981	0.01
351.3917236	0.01
353.2715454	0.02
355.3277893	0.09
361.1492920	100.00
361.7948608	0.33
367.3785400	0.03
371.1854858	0.01
373.1365967	0.78
383.2751160	0.01
397.2071228	0.15
427.0870056	0.23
429.9136047	0.01
434.2395630	0.03
439.2078552	0.15
450.1118774	0.02
457.1320496	0.48
458.1215210	0.01
460.3491821	0.02
461.4167786	0.02
472.8967896	0.02
475.2055359	1.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1695
Annotation	Butrin
Peak:m/z	Relative Intensity
208.9326477	0.04
254.0061340	0.02
267.8522949	0.05
271.1445923	3.97
272.1829224	0.71
272.8758850	0.01
283.1967163	1.31
284.1740723	0.25
295.0800781	1.62
296.1503601	0.20
299.4950562	0.02
307.1959229	0.02
308.0874634	0.02
309.2573242	0.03
310.1107788	0.06
311.5151367	0.11
313.1004639	6.17
314.2855225	1.43
333.1179810	0.01
337.1971436	1.57
338.1237183	0.50
342.2680664	0.03
343.0914307	0.13
349.0563354	0.06
351.1477051	0.05
352.1724854	0.02
367.1011353	1.71
368.1427002	0.58
369.4099731	0.04
372.9375610	0.03
379.2641602	0.89
380.1475220	0.41
380.9514771	0.03
397.1799927	3.06
398.2515869	0.95
399.0926514	0.03
403.4410400	0.05
405.4225464	0.04
415.1880493	14.97
416.1838379	4.33
417.1818848	0.42
418.3948364	0.04
422.5708618	0.02
423.3895264	0.22
424.3932495	0.13
426.9245605	0.04
427.5675659	0.06
433.2122803	100.00
434.1754761	26.89
435.1865234	0.01
436.0695801	0.04
440.1810913	0.05
441.1992188	0.65
442.3833618	0.05
443.4717407	0.04
447.2775879	0.02
448.4597778	0.02
457.3674927	0.13
458.5883179	0.13
459.2660522	0.66
460.2540894	0.21
461.0012817	0.07
462.1298828	0.04
471.2221069	0.05
472.5051270	0.02
475.3544922	0.16
476.2936401	0.06
481.2025757	0.28
482.3540039	0.05
489.0992432	0.01
499.4296265	0.06
507.2446289	0.03
517.3289795	0.29
518.2653198	0.03
525.2974243	0.74
526.3272705	0.12
543.1840820	0.59
544.2258911	0.06
561.2105103	0.69
562.3863525	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.1747
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
272.1408081	0.03
292.8898315	0.07
301.1301880	0.07
323.9239502	0.02
324.9921875	0.42
337.1837158	0.16
339.0627441	0.05
343.2127075	1.21
349.3770142	0.08
355.1577148	0.20
367.2461548	1.63
379.3856201	0.07
383.1009521	0.07
385.1951294	4.93
391.2831421	0.10
409.2277832	2.53
421.1631470	0.28
427.4074097	0.05
433.3118896	0.26
435.0994873	0.03
437.3102417	0.05
439.1062622	0.74
444.2492676	0.06
445.3786621	0.21
446.6040649	0.09
451.2713623	3.21
457.1091919	0.10
463.0568848	0.28
463.7208252	0.07
469.2042236	2.36
475.3643799	0.48
487.1884155	14.88
487.8474121	0.09
493.3038940	0.28
505.2781982	18.08
511.3167114	11.05
513.2498779	0.60
517.0587769	0.08
523.2584229	0.53
529.3035889	9.88
531.2075195	3.63
535.4089966	0.61
537.1442261	0.79
539.4711304	0.15
541.2772827	1.40
542.6721802	0.06
543.4788208	0.09
547.3117676	0.06
549.2062378	2.89
553.2066040	14.52
553.8403931	0.03
555.2891235	10.63
559.1973267	0.49
561.3558350	0.04
571.1751709	1.89
573.2200928	71.49
573.8436890	0.14
589.2742920	2.16
591.2161255	7.13
595.1948853	0.65
597.3347168	1.29
607.2545776	4.05
613.2127075	0.82
615.3458862	1.30
621.4832764	0.24
625.1101685	0.38
627.2045288	1.31
631.2987671	1.00
639.2421265	1.65
645.2587280	1.21
649.2689819	1.08
657.3194580	28.68
667.2911377	0.12
675.2250366	56.37
675.9224243	0.07
683.6893311	0.03
693.2673950	100.00
711.1050415	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1633
Annotation	Unknow
Peak:m/z	Relative Intensity
133.9361877	0.74
163.0160065	5.89
175.2014160	0.16
180.0094299	100.00
181.1747131	0.07
192.0217285	0.09
227.8027954	0.03
260.1917725	0.07
264.9381409	1.16
266.1282959	0.93
267.2308350	0.58
279.0751343	0.18
282.9695435	0.04
299.2293701	0.14
306.1851807	0.30
309.1296997	0.09
315.4285278	0.45
325.1998901	0.04
331.3153687	0.19
341.1913757	1.05
342.3343506	0.04
344.1170654	0.03
351.2695923	0.04
354.0817871	0.05
358.0080566	0.16
358.7161865	0.24
383.2803345	0.05
390.4078064	0.05
399.3670349	0.60
400.2726746	1.66
401.1491699	0.42
403.1158752	0.03
415.2825012	0.07
428.3719177	0.37
429.4076233	0.06
437.9100647	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.241
Annotation	Aurantoside I
Peak:m/z	Relative Intensity
216.0487976	0.04
237.9347382	0.02
240.0781860	0.03
240.9955750	0.02
250.8522339	0.04
255.1111603	0.08
257.3406372	0.09
258.0576477	0.06
271.0925903	0.03
279.1355591	0.03
285.1746216	0.11
286.1112061	0.14
297.0772400	0.10
301.0562439	7.49
313.1201172	0.11
315.1961060	0.12
325.1289673	0.08
339.2113647	1.48
341.1777649	0.04
343.2514648	0.51
353.3067017	0.02
357.2832031	0.93
365.1990356	0.04
367.0922852	0.11
384.8991089	0.03
399.1217651	0.03
409.2550659	0.09
423.2776489	0.15
440.1418457	0.06
441.1778564	0.06
447.3923340	0.06
448.2260742	0.04
449.2036133	0.05
455.2666626	0.03
459.1616821	0.12
473.4324951	0.03
477.3309326	0.64
479.0458374	0.04
489.2731323	1.32
490.5004883	0.11
491.3677979	0.03
525.9911499	0.01
541.3963623	0.09
545.6187134	0.02
559.5382080	0.12
573.1443481	0.03
575.3734131	0.06
579.3276978	0.60
587.3724365	1.41
591.3114624	0.67
593.3305054	0.07
595.3414917	0.04
605.3167114	36.47
605.9172363	0.06
609.4514160	0.35
611.3226929	0.05
619.2346802	1.21
619.8509521	0.05
628.4553833	0.02
631.3622437	0.08
633.2530518	0.04
635.0987549	0.02
649.6022339	0.02
653.5343628	0.08
685.5764771	0.04
705.2957153	0.38
737.4511108	0.10
740.4157104	0.03
755.3801880	100.00
756.3920288	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	910.4999
Annotation	Unknow
Peak:m/z	Relative Intensity
261.1056824	0.02
269.1809387	0.01
270.1228027	0.01
282.0818787	0.01
311.3387451	0.02
320.2911987	0.01
321.3495789	0.15
331.1358643	0.02
339.3060303	0.08
341.0453796	0.02
351.2060242	0.07
356.3083191	0.02
358.0704956	0.03
368.9884644	0.02
379.2520142	0.03
381.1058044	0.09
392.3195496	0.04
408.0145264	0.02
410.3869629	0.02
420.1765137	0.16
438.2762451	0.24
443.4133301	0.02
445.3103638	0.01
454.4539185	0.02
455.4266968	0.13
457.3240356	0.08
464.5928955	0.01
472.2431641	0.01
473.5067749	0.02
475.4468994	0.01
484.5589600	0.03
486.4067383	0.02
493.7512817	0.01
502.3270874	0.01
509.4854126	0.03
512.2721558	0.14
519.3291016	0.01
523.5139160	0.12
533.5141602	0.12
535.7002563	0.03
537.4023438	0.04
542.7282715	0.02
551.4351807	0.34
552.4827881	0.01
553.5134277	0.05
556.5093994	0.04
560.7022705	0.01
564.3755493	0.03
565.4287720	0.02
568.2145996	0.01
569.4044800	0.01
570.8708496	0.01
571.5016479	0.03
572.4129028	0.01
581.5219727	0.04
583.4405518	0.11
599.4436035	0.06
601.1193848	0.04
605.1181030	0.05
614.3568726	0.01
615.5162964	0.02
616.3165894	0.03
620.7385864	0.02
622.4887695	0.21
631.8816528	0.06
632.5441284	0.34
634.5390015	0.02
635.3837280	0.01
641.5582886	0.03
650.4063110	1.34
651.0848389	0.00
652.9996948	0.03
659.6209106	0.03
662.4505005	0.03
669.5444946	0.08
670.6688843	0.10
680.4349365	0.30
686.8765259	0.01
694.3810425	0.01
696.4592285	0.03
698.5590210	0.37
701.5607910	0.01
714.3724976	0.06
724.3388672	0.04
729.6441650	0.01
731.4801025	0.01
738.3855591	0.01
747.4781494	0.05
749.6328735	0.01
750.6853638	0.01
751.4057007	0.01
756.3001709	0.03
760.1311035	0.10
766.6150513	0.02
768.5202026	0.36
779.4780884	0.09
783.5729370	0.03
785.3148804	0.02
793.5468140	0.37
795.7294922	0.07
796.7233276	0.05
797.5217285	0.22
811.5579224	0.66
813.6981812	0.12
823.2209473	0.02
823.8695679	0.02
841.4692993	0.01
846.7327271	0.01
849.7604370	0.01
852.5156860	0.04
864.3699341	0.12
874.3639526	0.17
880.6956177	0.04
882.6104126	0.78
892.6917114	2.38
910.5488892	100.00
911.2570190	0.12
913.0923462	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1333
Annotation	Oenin
Peak:m/z	Relative Intensity
177.0939484	0.08
181.3461609	0.07
186.2134857	0.02
200.2235413	0.06
200.9670258	0.02
202.9735413	0.03
217.0122833	0.04
227.1683807	0.12
230.9594269	0.03
235.1163940	0.02
249.0588226	0.03
253.1449585	0.06
275.0992737	0.02
306.2127991	0.01
309.2995300	0.02
310.2806396	0.07
327.3133545	0.04
329.3326111	0.08
330.3388977	0.28
331.1763306	1.77
332.2705994	0.02
338.3426819	0.04
343.1309814	4.43
343.7534180	0.01
345.5270386	0.04
355.2598877	2.21
355.9730835	0.07
359.2573547	0.26
361.1947632	0.06
363.1377869	0.01
367.0070190	0.06
368.4960327	0.05
371.2518311	0.13
373.1855469	46.61
374.0076904	0.02
376.2409058	0.03
384.8229065	0.09
387.1097717	0.02
394.0303650	0.06
397.2363281	13.03
400.6356506	0.10
403.2696838	1.27
407.3165588	0.05
409.3857422	0.56
411.2502136	0.31
415.3244934	0.13
418.2161255	0.03
421.1810913	0.07
427.2058105	17.66
427.9987793	0.09
429.2374573	0.07
433.2932434	0.01
434.4407349	0.06
439.2336731	6.88
439.8477173	0.03
446.1442871	0.04
451.9589539	0.06
457.1824341	18.95
457.8507385	0.09
461.1835632	0.12
475.2151794	100.00
476.1200256	0.06
494.3561096	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.1876
Annotation	Terretonin F
Peak:m/z	Relative Intensity
132.6049957	0.25
133.2519073	0.15
135.0476990	0.46
137.1584473	1.24
142.9408569	1.10
147.0199127	0.58
149.1325378	1.62
153.0111694	0.22
156.0970154	0.20
157.0179901	0.30
157.8886719	0.15
158.9483185	1.98
160.7972565	0.40
162.8777771	0.34
166.2627258	0.45
166.9653778	0.48
167.7746429	0.20
169.0885773	0.43
170.0055389	1.06
171.0417328	1.13
173.0987091	2.08
175.1561584	2.84
177.0324249	1.22
179.0676575	0.86
181.1510773	1.18
183.0100098	1.59
186.1048584	0.31
187.2801666	2.43
191.0591736	0.62
193.0120544	0.91
197.1251526	2.08
198.0486450	0.21
199.1746826	25.99
201.0357971	10.22
201.8637390	0.14
203.1657410	1.62
206.9464874	0.64
209.1441345	2.34
209.7848206	0.44
211.0845032	2.20
212.3715210	0.17
213.5631256	0.47
214.2319031	0.39
215.1983337	0.55
217.1233368	2.05
219.1109161	1.24
221.1445618	1.14
224.2220764	1.11
225.2296448	7.14
227.1301575	30.13
229.1938324	100.00
231.2306213	2.38
233.2717285	0.74
235.3987122	0.58
237.2926941	3.02
238.1401520	1.23
239.2591248	0.35
241.1204987	1.08
243.1913757	6.78
245.1954651	0.81
248.9765625	5.26
249.8197632	1.73
251.2352905	2.63
253.1737061	23.10
254.3810120	0.18
255.0431824	4.18
257.2129517	4.53
259.1818848	0.92
261.1414185	2.34
262.3667603	0.27
263.2406006	1.16
264.2622681	0.66
264.9974670	4.51
267.3603210	2.06
268.9184265	1.66
271.2061768	8.59
273.2528687	0.97
275.2449646	2.01
276.9577637	9.73
278.2076721	67.15
279.2934875	1.61
280.1797180	0.58
281.1045837	1.35
283.1119995	31.86
285.2750549	2.36
287.4768372	0.59
289.2498779	7.32
290.0614624	3.28
291.1588135	1.62
293.2861633	13.65
295.2692261	6.87
295.9953003	0.33
297.2158203	3.10
299.2144165	1.08
301.2232056	4.71
302.3276672	0.26
303.2723694	2.04
306.0873718	97.53
307.2681580	3.58
311.2550964	5.63
313.2125854	2.08
314.9719543	1.44
317.2039185	0.26
318.3775024	0.38
319.1799316	0.38
321.1872559	69.90
323.2740479	7.51
327.2667236	0.44
329.4004211	10.30
331.4443970	0.19
333.1143799	1.54
334.2211609	9.16
335.3431396	0.68
337.1136475	6.52
338.2654724	1.56
339.0238037	2.64
339.6448059	0.80
345.3384094	2.68
347.1212769	2.64
348.6013184	1.21
349.3179321	16.39
351.3225098	6.34
353.3468628	7.35
354.7614441	0.37
355.4464722	0.69
359.1641846	0.78
361.2147827	1.51
363.3201294	13.08
364.5686340	1.06
365.3485107	6.09
367.3153687	6.83
373.4600525	1.33
377.3191833	7.60
378.2433472	1.34
379.3069763	3.14
381.2687073	55.89
389.4618530	1.14
392.5580750	1.03
393.4064331	3.92
395.2518616	15.84
397.1828918	14.94
405.1871033	1.51
407.3734131	17.04
408.2472229	2.23
409.1704407	3.34
410.1333313	0.43
411.4963074	0.91
423.2027283	0.25
425.1871643	5.47
433.4131165	1.02
441.5440063	0.62
451.3130493	4.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	571.66
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0418854	0.08
187.1054688	0.05
200.9984131	0.03
212.8173218	0.02
234.9548492	0.10
238.9849091	0.04
241.0468445	0.04
253.1312866	0.04
271.1188965	0.21
271.9556885	0.02
298.1900635	0.87
299.2488708	0.45
301.0624084	0.88
301.9498291	0.16
313.0668945	0.07
315.1660767	0.03
316.1258545	1.56
317.0396118	0.07
323.0980835	0.05
328.1736450	0.07
328.9735107	0.06
331.1271973	100.00
332.1509399	12.44
333.0940552	0.16
334.3328857	0.12
345.9942017	0.35
361.1362915	35.26
362.1628418	4.53
364.4757080	0.04
369.1376343	0.08
371.1124268	0.04
378.9304810	0.09
385.5741577	0.35
387.2859497	0.11
398.1708374	0.06
403.3333740	0.03
404.7874146	0.17
409.1702271	0.07
415.3098755	0.02
428.3644409	0.06
439.2369995	0.15
440.1921387	0.04
445.4694214	0.07
448.6318970	0.01
451.2087402	0.70
452.1596680	0.11
469.1897583	0.48
470.1502686	0.02
471.6428223	0.06
485.9848633	0.05
487.2975464	0.14
493.2156982	0.08
499.4725952	0.04
521.1326294	0.06
523.2966919	0.09
526.4662476	0.09
535.5158081	0.14
545.0638428	0.11
547.1685791	0.05
554.2793579	0.29
575.1369629	0.07
576.3178101	0.07
577.1257935	0.06
578.1350708	0.05
581.1631470	0.02
588.4421387	0.05
589.2710571	0.02
601.1923218	0.10
605.2604980	1.03
606.3645630	0.20
607.3815308	0.16
608.4561157	0.01
613.1864624	0.19
614.4368286	0.12
619.0853271	0.16
631.2149658	0.19
632.5107422	0.08
637.2537231	0.12
638.2923584	0.02
649.1630859	3.84
650.2378540	1.13
651.4566650	0.06
666.2005005	0.09
667.2703247	1.62
668.3298950	0.38
679.4636841	0.02
680.3804321	0.02
709.2434692	0.53
710.3941040	0.06
727.1041870	0.22
739.2964478	0.23
745.1825562	1.43
746.4238892	0.33
757.3078003	0.59
758.4545288	0.34
763.3881226	0.76
764.1798706	0.11
775.2069702	12.82
776.3146973	5.95
777.1749878	0.15
780.5965576	0.05
781.2658081	0.52
792.5875854	0.60
793.2129517	9.78
794.3263550	2.30
795.2033691	0.05
811.1517944	4.32
812.3032837	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2083
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
186.6495056	0.07
191.1231995	0.16
193.0949707	0.08
219.2951660	0.21
243.1573944	0.11
252.8898315	0.07
257.2431946	0.10
271.0976562	0.21
274.8890991	0.38
289.4440308	0.08
296.5416870	0.16
297.2465820	0.42
298.2651367	0.52
299.3102417	3.15
304.2939453	0.48
309.2906494	0.25
315.2960815	0.36
322.1978760	0.13
325.2941284	0.12
327.5422974	0.08
333.2172241	13.15
335.3476562	0.17
343.2966309	0.52
353.2940674	1.26
355.3741455	0.08
360.0043335	0.10
364.8788452	0.44
367.3340454	0.16
371.2963257	0.74
375.0759888	0.61
381.2623291	0.16
390.3247070	0.16
391.5310059	0.38
393.1284790	1.34
409.3040161	0.25
411.2188721	17.77
411.8346558	0.06
420.2876587	0.16
429.0854492	57.33
435.3063354	0.34
443.0219116	0.04
453.2152100	58.26
453.8793945	0.37
455.4193115	0.32
461.4652710	0.28
470.2326050	1.32
471.2300415	100.00
471.8342285	0.22
472.4648438	0.15
473.3835449	0.11
474.5407104	0.05
475.2386475	0.28
498.9764404	0.44
499.9969482	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.3383
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
161.0299377	0.08
166.1485443	0.18
183.9923706	41.82
205.0124664	0.09
236.6770477	0.06
240.1252441	0.28
258.1687622	0.92
265.2304993	0.22
270.2443848	0.11
281.4548950	0.05
291.3217773	0.04
299.1845093	0.12
307.2408447	0.13
313.3214111	0.09
337.3581543	0.16
366.3319092	0.06
443.4518433	0.41
453.3925171	0.03
460.0611572	0.06
489.4633789	0.09
502.5249023	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1667
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
176.7017822	0.11
242.4135437	0.03
299.2447510	0.17
301.1070557	48.12
302.1235352	7.16
305.1115723	0.12
343.3182983	0.18
344.1311035	0.07
443.3471680	0.02
445.2843628	0.22
446.4146118	0.13
463.2160034	100.00
464.2953491	18.24
491.1961060	0.06
492.5397339	0.05
505.2352295	49.63
506.2078247	12.29
506.8438110	0.06
519.2460327	0.04
545.2698975	23.22
546.2803345	7.26
547.3444824	0.24
589.3787231	0.04
608.3090210	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.175
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
286.1809692	3.85
301.1477661	100.00
343.1527100	6.43
396.9852295	1.20
409.2489624	1.78
445.2879028	1.14
453.3727417	2.49
463.1633301	46.30
463.8076782	0.92
469.2427368	1.46
487.2012329	5.64
505.0726929	8.37
511.1112061	4.33
512.9933472	0.93
529.1620483	3.40
530.9874878	7.85
540.9572754	2.26
549.2564697	83.47
553.1524658	0.57
555.2523804	1.63
561.3986816	0.61
564.8223877	7.72
573.1836548	9.23
591.3355713	7.01
595.0941772	1.20
601.4679565	0.77
615.0564575	1.98
625.2173462	7.73
638.9445190	0.45
645.0310669	11.83
657.2942505	9.51
675.2066650	17.63
675.8933105	0.67
693.3048706	58.19
710.5603027	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1248
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
149.0351105	0.04
150.9850006	0.75
165.0257874	0.10
173.0131836	0.07
177.1212006	0.31
179.0005493	0.02
200.9065857	0.01
212.2110901	0.03
232.1256561	0.01
233.1325378	0.06
242.1727448	0.07
251.0217896	0.05
255.2338562	0.02
267.9996338	0.01
271.3305969	0.02
281.2118530	0.02
282.9613342	0.05
284.0075073	0.33
285.1721497	0.15
286.2157593	0.24
295.0808105	0.02
297.3612366	0.02
299.1614990	0.23
301.1138306	100.00
315.3594055	0.02
319.3653564	0.02
325.4321289	0.06
341.2244873	0.07
342.2466125	0.25
343.1356812	0.94
347.3379211	0.01
371.1009827	0.02
373.2119751	0.01
402.2197876	0.02
415.4394836	0.08
416.2379456	0.38
417.3309631	0.15
419.3824158	0.02
420.3152161	0.04
426.3322449	0.03
427.1714783	0.01
447.1480103	0.93
448.1993408	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	453.2322
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9838638	0.52
132.8399963	0.09
134.1658936	0.08
144.9247284	3.61
146.8233643	0.61
151.1298981	0.30
158.6968689	0.07
162.8530884	10.84
163.4546814	0.17
164.1802216	0.04
166.8245239	0.42
167.9166107	0.31
168.9513702	1.12
169.8319397	0.17
171.0259094	0.24
174.2152100	0.10
178.8501892	0.10
187.0524902	2.06
188.8985901	0.20
195.0060730	0.31
195.9372559	0.11
204.4581299	0.45
205.0769806	0.94
208.9291687	0.08
211.2672577	0.04
226.9885559	0.04
228.4210052	0.10
234.6677704	0.09
237.2930450	0.42
239.0038757	0.14
243.1347961	0.31
247.2232361	0.83
248.8113403	0.42
252.0791016	0.14
253.0616150	0.60
255.0690308	0.81
256.1722717	0.08
260.0036621	0.07
264.8732910	0.18
268.0642395	0.10
271.0441284	9.24
272.8475647	0.71
273.4478760	0.13
277.0777893	0.18
282.1403198	0.24
283.2183838	0.10
284.1207581	0.06
286.1912842	0.29
287.2344360	0.14
288.8947144	29.40
290.1353455	2.31
291.1530762	1.38
297.2545776	0.59
302.8663025	0.10
304.3045044	0.25
306.8739624	25.17
307.5849304	0.03
310.0339966	0.12
311.1706543	0.42
313.3151550	0.78
314.6791382	0.25
326.1541138	0.12
331.1788330	0.43
332.9015808	4.26
333.5278931	0.12
339.7747192	0.25
342.2508850	0.26
354.3638306	0.07
355.1813660	0.18
358.0069885	0.11
358.9887695	0.43
363.2329102	0.52
364.2388306	0.22
365.3807983	0.10
367.2894592	0.43
368.0624695	0.65
377.3427734	0.15
380.6387634	0.15
381.2971802	0.31
384.8433533	0.10
388.0742493	0.21
389.4966431	0.05
390.2290955	0.51
391.1450500	0.14
392.2850342	0.06
393.0232544	0.23
394.3269958	0.29
398.2472839	0.73
399.2418213	1.12
403.1320496	0.30
404.9338074	0.22
406.6129456	0.10
407.4038391	0.14
408.1141052	0.30
409.2283020	3.21
409.9956055	0.50
411.9855652	0.61
413.2999878	0.43
417.1259460	54.65
418.0259705	0.35
419.9577942	0.13
421.2993774	0.09
423.2884521	0.11
425.2606812	0.37
431.2214050	0.25
432.8293152	0.25
435.0609741	100.00
435.8755493	0.47
438.7794800	1.04
443.2837219	0.23
452.3305969	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1517
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
173.3208466	0.05
174.8440094	0.54
183.1254120	0.05
184.0023804	0.21
186.1310120	0.25
187.1976013	0.06
189.0170288	0.11
191.1572571	0.13
197.2636719	0.04
198.0022125	0.10
199.0365753	0.49
200.9906311	0.12
212.2276917	0.08
213.0235138	0.45
213.9108734	0.12
217.0584106	0.24
223.0771484	0.11
229.0425110	0.06
240.4972839	0.11
241.1277161	0.37
243.1052094	0.32
256.0477600	0.23
257.0807190	0.43
261.1574097	0.16
265.1547546	0.22
267.1325073	0.06
271.1084595	0.16
281.0317383	0.20
284.0740356	15.80
285.0684204	100.00
285.9577942	0.24
287.1848755	0.05
292.7188416	0.07
296.2322693	0.08
297.1411438	0.67
298.0253906	0.91
299.0927734	0.29
308.0191040	0.08
309.1730347	4.97
311.1784058	0.04
312.3304138	0.05
313.1390381	0.02
323.1947021	1.91
325.2269287	0.37
326.5590820	0.46
327.1934204	6.67
329.0942383	0.10
338.5358276	0.23
339.3841553	0.09
341.2217407	0.14
351.1177979	0.25
352.9672241	0.38
357.2197266	2.66
363.4439697	0.10
369.2702637	0.53
371.2557373	0.13
383.3525391	0.20
387.1051636	0.38
388.0650635	0.05
393.2317505	0.47
397.2973022	0.19
407.2114258	0.19
411.4810791	0.06
413.4339600	0.26
418.9476318	0.28
429.1795654	3.71
431.3600464	0.48
443.1613770	7.13
443.8508911	0.07
447.1929932	42.30
447.7993164	0.63
455.5941162	0.12
473.3348389	2.77
474.5270996	0.03
485.1495361	0.04
503.2707520	0.06
521.0530396	0.03
539.5278320	0.26
545.3115845	0.16
546.2130127	0.23
548.6099243	0.04
549.2319946	0.10
575.2933350	0.16
594.2434692	33.14
594.8651733	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1776
Annotation	Unknow
Peak:m/z	Relative Intensity
174.1346283	0.11
176.9619598	0.07
184.0010986	0.07
185.1060486	0.14
185.9918213	0.12
187.1928558	0.05
187.9245300	0.05
189.0647736	0.08
191.1509094	0.34
193.0906982	0.10
197.0769043	0.15
198.9284973	1.69
200.0130310	0.34
200.8799744	0.73
204.2943115	0.03
212.5392456	0.19
213.2570496	0.06
214.9564362	1.12
215.9485779	0.17
217.4886780	0.24
218.1730347	0.10
223.3430786	0.08
224.1682129	0.48
227.1556244	1.03
229.1247559	0.12
233.0045013	0.42
238.0296478	0.24
238.8412170	0.13
239.9967346	0.42
241.2976227	0.73
242.0376740	1.68
243.1741333	0.52
244.4417725	0.15
249.1389923	0.12
251.0699615	0.15
253.2503815	0.05
254.3285828	0.05
257.1189575	1.81
258.0752563	0.80
259.1988525	0.24
260.3653259	0.07
265.1386719	0.07
266.1444092	0.07
268.0239868	0.55
269.1320190	0.37
275.1471863	0.13
279.1489868	0.26
282.1728516	0.13
283.0797424	1.52
284.0593262	0.61
284.9703674	0.25
286.1818848	3.16
287.1680298	0.43
292.2920532	0.30
297.0831909	0.14
298.2720032	0.06
299.2236328	0.13
301.1173401	100.00
302.1707764	17.19
307.1377258	0.64
308.2612305	0.08
308.8884888	0.07
310.1488953	0.46
311.3535767	0.19
313.4451294	0.10
315.2803345	0.91
316.1311646	0.14
317.0549316	0.16
318.3634644	0.16
319.1763916	0.05
322.1368408	0.03
325.2023315	12.05
326.1757202	2.86
327.2691956	0.05
337.0446167	0.34
339.3213501	0.06
340.2102051	0.09
341.1635742	0.31
342.1875610	0.25
343.1871948	7.24
344.2207642	1.13
354.0795898	0.06
355.2219849	2.45
356.3209229	0.22
367.3095703	1.03
368.1956177	0.52
373.1213989	0.19
383.4359741	0.07
384.8936768	1.08
403.2532959	0.71
404.3958740	0.40
409.1887817	0.12
410.4038696	0.13
413.2645874	0.16
415.3962402	0.17
427.3208008	0.08
428.4449463	0.11
431.0610352	0.05
433.5537109	0.18
445.2437134	0.93
445.8452148	0.02
446.4763794	0.09
457.0382080	0.03
459.0943604	0.05
463.3015747	2.35
464.2426758	0.32
477.2529907	0.10
485.0748291	0.03
501.5405884	0.43
502.4902954	0.29
505.2045288	12.65
506.1664429	3.15
506.7678223	0.17
507.3956909	0.32
521.3944092	0.16
535.1741333	0.05
547.3118286	0.07
557.4758911	0.04
563.4784546	0.05
568.3857422	0.06
579.3488159	6.06
581.6425171	0.16
587.5216675	0.12
591.9457397	0.04
593.6152344	0.03
597.2638550	0.09
607.4098511	0.78
608.2303467	0.27
610.2610474	0.38
611.3710938	0.30
626.1898804	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.2453
Annotation	Unknow
Peak:m/z	Relative Intensity
219.0491943	0.03
227.0936432	0.04
245.0986938	0.35
247.1064148	0.14
262.7550659	0.03
265.2131348	0.64
266.4890747	0.08
283.1361389	0.98
284.2371521	0.05
287.1892090	0.03
289.2200317	0.02
295.3485718	0.01
305.1049194	0.44
306.0217285	0.01
317.1443176	0.08
319.2875366	0.03
321.0540161	0.28
333.3505859	0.03
337.2125244	0.15
339.2155762	0.05
349.4292908	0.02
359.0507812	0.13
360.0997009	0.02
363.1997681	0.07
376.9547119	0.14
379.2118530	1.33
380.2543945	0.10
389.2293091	0.01
395.4990845	0.01
397.1506348	0.36
398.1436157	0.05
401.4025269	0.02
403.6812744	0.03
408.9067383	0.05
415.3250122	0.56
419.1991577	0.01
428.1983032	0.08
431.1854858	0.06
433.2694092	0.07
438.9031372	0.03
443.3187866	0.03
449.2510986	0.10
450.5722046	0.05
467.3466797	0.07
479.4678345	0.03
481.3109741	0.17
482.5669556	0.05
487.3275757	0.03
490.5270386	0.02
491.1446533	0.25
492.4177246	0.01
493.2804565	0.09
507.3236694	0.01
509.4025269	0.01
511.2596436	0.41
512.1282349	0.02
523.1002808	0.02
529.1206055	0.26
530.4645996	0.09
532.6007690	0.05
534.3819580	0.03
543.6192627	0.16
554.3131714	0.04
555.0366821	0.03
559.1145630	0.01
561.1394043	0.04
561.7774048	0.03
567.3290405	0.03
579.1892090	0.03
586.3698120	0.06
587.5175171	0.03
597.3132935	0.03
602.9957886	0.01
625.4595337	0.01
627.3602905	0.07
629.4523926	0.10
641.3893433	0.03
643.3619385	0.80
644.1948853	0.24
645.8101196	0.13
647.2736206	0.24
661.2942505	0.77
662.4368286	0.21
669.1621704	0.02
670.1901855	0.02
675.1556396	0.05
687.5158081	0.78
688.4854126	0.27
693.3590088	0.32
701.3286133	0.16
703.5342407	0.09
705.3956299	0.82
706.6348877	0.07
719.3368530	23.93
720.4308472	3.16
729.8299561	0.03
737.3519287	12.85
738.4664307	1.81
747.3325806	1.19
748.2229004	0.22
761.4633179	0.13
762.5609741	0.08
780.3536377	100.00
781.1168213	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.2
Annotation	Isosyringalide 3'-alpha-L-rhamnopyranoside
Peak:m/z	Relative Intensity
191.2605591	0.27
193.2176971	0.09
215.0075531	0.34
256.0572205	0.18
267.2896118	0.14
268.1231079	0.40
269.3636169	0.19
284.0991821	34.44
285.1618652	4.21
286.4901123	0.13
297.1744690	0.68
298.1664429	1.59
299.1586914	100.00
300.1144409	0.20
301.1989136	1.74
307.1403198	0.10
308.0463867	0.08
309.1403809	0.18
311.0177612	0.07
321.2189941	0.20
323.0883789	1.62
325.1087036	0.08
326.3818970	1.01
327.1284790	0.31
330.0828857	0.10
341.1076050	2.54
345.3695679	0.06
353.0529175	0.46
360.1950684	0.05
365.3023071	0.26
367.0306396	0.28
369.1414185	0.25
383.4811401	0.12
395.2473755	0.13
401.4396362	0.20
407.0704956	0.14
411.1820068	0.21
427.1224976	0.09
428.0925293	0.42
439.9021606	0.05
443.1143799	7.74
445.4831543	0.12
447.0779419	1.45
460.8532715	0.92
461.4614258	0.38
463.1417847	6.19
463.8005371	0.18
475.1754150	0.08
477.5563354	0.11
478.4296265	0.06
480.2394409	0.07
487.2722778	3.25
500.1154175	0.42
502.3284302	0.48
503.2783813	0.53
505.1339111	2.35
516.1043091	0.15
521.3648071	0.11
522.4229126	0.28
523.3314209	0.64
529.1175537	0.06
544.3064575	0.65
545.3873901	0.26
546.3307495	0.11
547.1488037	0.11
563.5136108	0.39
565.5560913	0.15
573.4832764	0.15
575.9284058	0.21
577.0610962	0.18
579.1871948	0.35
589.2258911	0.39
592.3993530	1.78
608.4909668	2.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.194
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9593506	11.08
160.9320679	0.22
162.0941620	0.20
162.9266205	0.04
164.9746704	0.29
167.0812988	0.99
167.9295502	0.08
178.0048523	10.26
183.0853882	0.41
185.1183929	0.06
190.7979431	0.10
198.0296631	0.02
206.1135559	0.03
208.0630798	0.40
209.0668945	0.06
219.1856995	0.08
226.1164093	0.27
236.9151001	0.90
238.1562958	0.03
249.1931763	0.02
254.0625305	18.94
255.0083923	0.21
270.5307617	0.10
272.0543518	100.00
272.6718750	0.16
289.1432800	0.09
290.1002808	0.53
303.1151428	0.04
326.3930664	0.12
331.1142578	0.03
344.2953491	0.08
349.9202271	0.16
358.2808838	0.20
359.0830688	0.04
362.5253296	0.03
370.2424316	0.14
375.2949219	0.03
376.1468506	0.13
390.2598877	0.06
396.8084717	0.04
397.8372192	0.09
398.4715576	0.11
399.4279175	0.04
406.1234131	0.04
408.3399658	0.95
412.8411255	0.05
421.3944702	0.04
422.1791382	0.06
426.2263794	0.12
430.0452881	0.04
434.2883301	0.10
452.0895996	0.23
460.2474365	0.06
478.5501709	0.23
484.0447998	0.21
500.5364990	0.03
502.3287964	1.51
503.0444946	0.06
509.2871704	0.11
520.1266479	6.22
521.2672729	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	4'-METHOXYFLAVONE
Peak:m/z	Relative Intensity
76.65206909	0.47
77.88903809	0.53
83.15374756	0.16
89.02981567	0.14
94.91845703	0.61
102.9463043	2.92
104.06604	0.21
105.0073547	0.50
106.7464752	0.62
109.8434296	0.19
118.9725037	0.76
122.7726593	0.40
128.9347992	11.18
129.9793091	2.26
130.9061737	0.09
131.9440002	0.15
133.1638641	0.13
141.016098	1.38
146.2302704	0.53
148.0340729	0.38
150.948349	100.00
152.028595	21.80
153.0524139	0.56
154.3822479	0.19
155.2746735	0.67
158.9907684	0.11
166.1134796	0.71
167.0291138	3.84
168.0812225	1.95
169.1573181	1.50
170.1719971	1.01
170.833725	0.42
176.9994354	0.24
179.1042938	3.81
180.0421753	0.93
182.2472229	0.83
183.0558624	1.21
184.0110168	0.30
185.0519257	2.49
185.9898834	0.86
187.0304108	0.11
191.1091156	0.25
194.2070465	0.38
195.1143799	0.60
197.1124878	7.03
198.0773773	0.65
206.1873016	0.94
207.1572723	0.48
208.1272736	0.51
210.1367645	0.38
211.3176727	0.40
212.029129	0.18
223.3480225	0.26
225.0902863	4.09
226.0741577	4.35
227.3178253	0.56
235.1424103	0.50
236.1956329	2.21
238.0619507	19.93
239.2339478	5.78
240.1898041	0.91
251.1244049	2.40
253.0899811	70.34
254.1096649	17.87
255.2305908	1.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	724.2569
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2727051	0.02
208.2917175	0.08
214.0798492	0.09
215.1587982	0.05
217.0401917	7.79
218.0737305	0.53
219.1612549	0.30
226.1982422	0.05
230.8693848	0.13
233.1463013	1.01
233.9969025	0.02
235.1196289	0.07
235.9965820	0.06
238.4440002	0.03
254.8816223	0.04
256.2721252	0.08
262.1610107	0.19
265.3903503	0.14
271.1831055	0.26
272.1802673	0.09
274.1739502	2.66
275.1258240	0.21
283.2782593	0.06
285.1206055	0.12
289.2529602	0.74
290.1584167	0.29
291.3073120	0.09
293.9862366	0.60
295.0716248	0.05
308.1487732	3.48
309.1645813	0.35
311.1643982	14.57
312.2567749	1.94
313.0681458	0.04
316.2607422	0.10
320.0824585	0.03
329.1359253	33.99
330.1934204	4.46
334.3039551	0.03
340.1140747	0.06
342.2479248	0.04
346.2348938	0.10
347.3754883	0.15
348.2124023	0.08
349.2700195	0.05
351.2718506	0.03
354.9398193	0.03
360.0840454	0.20
364.1823730	4.78
365.1818237	0.94
366.4234009	0.11
370.8916016	0.04
383.2749634	3.05
384.2260132	0.22
393.2333984	0.05
394.8014526	0.11
395.4485474	0.12
396.0612793	0.03
400.6564331	0.03
422.1125488	0.17
423.2091675	0.10
426.8801880	0.04
430.6276855	0.05
440.1556396	6.84
441.2809448	1.99
442.2283325	0.09
458.1646729	100.00
459.2742310	14.97
468.1628418	0.07
474.2388306	0.16
476.2197876	0.75
477.0687256	0.12
483.4385986	0.07
485.7223511	0.07
487.3526001	0.02
491.8027344	0.15
493.2581787	0.04
522.0671997	0.11
523.7559204	0.05
531.3336792	0.11
533.4287720	0.04
541.3300171	0.03
544.2572632	0.04
559.3652954	0.02
560.2669067	0.05
562.5951538	0.02
563.4860229	0.03
577.1237183	0.39
578.1428833	0.20
595.1633911	1.85
596.0847168	0.19
603.5276489	0.03
606.7310791	0.04
612.2301636	0.08
620.2282104	0.18
621.2676392	0.10
625.7141113	0.10
631.5795288	0.06
632.4681396	0.06
638.2191772	0.93
639.3826294	0.15
643.8337402	0.04
649.1292725	0.56
650.3430786	0.16
652.2836304	0.05
653.0892944	0.09
654.4385376	0.05
670.6658325	0.05
679.4826660	0.02
680.3272095	0.12
688.3320923	0.77
689.1945190	0.28
702.8641968	0.08
706.1990356	4.21
707.2258911	1.71
707.8426514	0.02
725.3024292	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.3989
Annotation	Unknow
Peak:m/z	Relative Intensity
184.1738281	0.10
186.2852478	0.50
193.0368347	0.26
207.1351471	0.09
212.9098816	0.13
223.3065643	0.25
251.0258331	0.05
263.3221436	0.21
266.6588135	0.10
267.4210205	0.09
313.0577393	0.47
313.6734619	0.34
338.3631592	0.29
361.1829224	100.00
362.3035889	0.88
373.1952515	0.17
381.1362915	0.08
399.1933594	0.44
403.0269165	0.11
413.4269409	0.78
421.4429321	0.18
437.2301636	0.30
449.3565674	0.20
465.4072266	0.17
504.2230835	1.69
505.4668579	4.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1669
Annotation	Verbasoside
Peak:m/z	Relative Intensity
133.1356354	0.24
133.8564606	0.11
134.9815979	0.33
143.0794220	0.86
144.8672485	1.09
146.0175781	11.04
146.8798828	0.63
148.9955902	0.12
151.0691833	0.64
158.9668579	0.49
160.9956665	9.20
162.9952545	1.00
164.0868835	12.31
176.9118347	0.25
179.0761871	100.00
199.2089233	0.09
201.1861420	0.25
213.1425629	0.09
217.1854858	0.06
223.2010345	0.14
234.9813232	2.41
253.0230103	0.16
281.2200317	0.07
283.5594482	0.17
287.1317444	0.17
293.2171631	0.10
298.0372925	0.75
321.0334778	0.61
326.3248596	0.12
328.2082520	0.58
329.0543518	0.53
341.0894470	0.17
369.0762329	0.27
369.9779663	0.37
371.2474670	0.49
384.3005676	0.19
389.3749390	0.12
397.3353882	1.72
399.3797302	0.17
401.3433533	0.58
413.5529480	0.21
415.0423889	76.59
415.6796265	0.49
417.2135925	0.63
425.4445496	0.62
433.4135437	0.09
441.6901550	0.19
443.0631104	0.44
462.0040588	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	227.129
Annotation	5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid
Peak:m/z	Relative Intensity
165.1198883	100.00
169.0482635	0.04
180.9672699	0.10
183.0867310	78.84
183.9176483	0.04
191.0841370	0.03
198.9527588	0.03
207.0917664	0.16
209.0420685	6.69
211.0491943	0.02
227.1355591	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.18
Annotation	Butrin
Peak:m/z	Relative Intensity
176.8425140	0.13
179.0869751	0.64
191.0411377	0.48
195.0432129	8.24
202.9504089	0.32
207.2099915	0.54
219.1034393	3.39
221.1096802	0.19
225.2360535	0.21
237.1120911	0.15
243.2582092	0.36
245.1051941	2.40
247.1813660	0.08
261.1892090	1.18
263.0158081	6.72
271.0531616	1.03
272.8197021	0.19
278.9395752	0.13
281.1082764	5.26
287.4205933	0.15
289.0515137	100.00
297.0909424	1.41
299.3546143	0.16
301.0507202	3.97
305.1561890	1.05
307.1882629	0.54
308.9499512	0.40
313.1918945	7.96
320.9685669	0.22
322.9020386	0.17
325.0287476	0.83
329.1713257	0.34
331.1151733	31.07
337.0604858	0.43
339.0237427	0.52
343.2904053	1.11
348.4171143	0.16
355.1425781	28.92
357.2716064	0.29
359.1422119	0.09
363.0961304	0.41
367.3218384	0.53
369.1209717	0.08
373.1200562	0.40
379.0885620	1.90
381.1436157	5.16
385.0569458	3.81
388.9987183	0.52
397.0989990	12.70
397.7548218	0.05
399.1117554	40.68
403.0862427	0.85
405.3572388	0.22
407.2874756	1.61
409.2192383	0.24
415.2001953	11.76
417.0811768	41.02
423.1291504	3.01
425.1656494	1.38
427.1886597	1.42
429.1052246	3.83
433.1118774	78.63
435.1982422	83.03
439.4083862	1.47
441.1273804	2.20
443.3205566	0.44
445.2158203	3.39
447.1416016	0.42
449.0942993	0.62
451.0238037	57.53
451.6779785	0.38
453.4113770	0.42
457.2012939	3.29
458.9929810	10.51
463.0388184	0.20
465.2379761	1.47
471.2548828	0.33
474.5399170	1.36
475.2236938	14.27
476.1641846	0.30
477.0431519	4.87
481.3122559	0.27
483.2482910	2.46
487.2337036	0.17
493.0348511	0.30
494.6693726	0.20
495.3286743	0.53
499.1075439	1.13
501.1823120	0.21
507.2062378	1.40
513.0797119	2.86
525.0923462	4.98
530.8945923	0.47
543.1842651	24.80
559.4725342	0.19
561.1746216	21.34
579.0135498	15.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.09
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
82.8219757	0.03
88.6964951	0.11
95.0146027	0.09
112.2985382	0.05
121.8759918	0.02
133.2326813	0.07
134.1007385	0.03
142.0380096	0.02
147.8909760	0.12
150.9876556	0.06
166.0981598	0.30
172.0881805	0.06
173.0104828	0.11
174.0517120	0.02
174.7340240	0.04
175.7141113	0.02
176.8924408	0.04
193.1628571	0.03
206.0101471	100.00
207.0501556	0.03
210.7886047	0.14
215.7948456	0.05
220.2927399	0.12
222.1167145	0.14
224.2492218	0.12
231.1027374	0.03
233.8960419	96.57
234.5798340	0.32
252.1897125	0.04
252.9188080	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.1857
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
199.3499908	0.04
214.1645050	0.03
226.2902832	0.02
241.0520325	0.03
267.3551636	0.06
271.0983276	0.03
274.0034180	0.03
281.2027588	0.01
288.2586365	0.04
301.0978394	0.06
316.2105103	2.57
318.2603149	0.03
331.1211548	84.96
331.7642822	0.18
335.9524231	0.03
343.2467041	0.03
347.2554321	0.03
348.0528564	0.11
353.1978760	0.07
358.2901611	0.07
365.2474365	0.05
373.2175293	0.10
386.8304443	0.03
397.2996216	0.09
403.4969482	0.04
406.1409912	0.03
407.1118774	0.13
439.2322998	0.07
449.4264526	0.01
456.8826294	0.04
463.4717407	0.03
469.3928223	0.08
475.1262817	0.31
483.4900513	0.03
489.3222656	0.03
493.1246338	100.00
493.9183350	0.14
496.5876465	0.01
500.3490601	0.02
501.3862915	0.13
504.3554688	0.12
508.3691406	0.07
511.2602539	0.07
527.0028687	0.03
541.6459961	0.23
559.0571289	0.03
561.1748657	0.03
565.8281250	0.12
568.6423950	0.05
576.5549927	0.01
580.2360229	0.06
589.1348267	0.03
592.2562866	0.09
593.2792969	0.05
594.8332520	0.13
600.4580688	0.05
601.6042480	0.06
610.4274292	0.18
619.2482300	0.14
636.6169434	0.26
637.5297852	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	168.1015
Annotation	a-Methyldopamine
Peak:m/z	Relative Intensity
137.0137787	0.03
149.9870453	100.00
150.7956085	0.01
158.6622925	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.2274
Annotation	Gomisin E
Peak:m/z	Relative Intensity
145.0263519	0.12
146.9756775	0.53
149.1346283	0.55
150.9711304	0.12
153.7591553	0.06
154.8158569	0.17
155.9204254	0.40
156.9293060	2.24
159.1568756	1.60
160.9176483	14.61
162.9029236	0.91
165.1599274	0.70
167.0825500	0.69
168.0826721	0.26
169.0609741	2.45
170.0723267	0.57
171.0243835	3.29
173.0692749	3.24
174.2101746	0.07
175.0694580	5.08
177.1311188	2.95
178.4286499	0.11
179.1176910	0.93
179.9269409	0.14
181.2581787	0.44
182.0892944	0.39
183.0642548	0.95
185.0641632	5.62
185.9771729	0.24
186.9806213	17.79
188.9970551	3.62
191.0535126	1.25
195.0667725	1.70
197.0930481	1.56
198.0838165	0.18
199.0457458	1.53
200.9335175	1.76
203.1056213	4.67
205.1019135	1.94
207.0784912	0.86
209.2334900	2.07
211.1446228	1.34
213.0896912	6.88
215.0605469	14.13
217.0662842	1.62
219.0705872	1.84
220.0096283	0.28
221.0923920	0.56
223.1606750	1.42
225.0323944	1.08
226.9750824	2.04
229.1170959	1.16
230.9972382	19.48
232.0364532	0.18
233.0416870	0.74
235.1890259	1.64
237.1334991	1.63
239.1018219	2.16
240.1402283	0.19
241.1620178	5.25
243.0819550	5.79
245.0868835	2.78
245.9654846	0.24
247.3341522	0.69
249.1287384	2.53
251.1543274	3.40
253.0450745	3.31
253.6779175	0.05
255.2836304	2.30
257.0135498	2.65
259.1489868	1.69
260.1382446	0.11
261.1946411	2.48
263.2064819	4.78
265.1514282	1.62
267.1914062	2.44
269.1007690	2.91
271.1571045	1.29
273.0951538	0.65
275.1920776	1.69
275.8877869	0.49
277.1369019	2.02
279.1536865	2.89
280.3151245	0.51
281.2714233	2.56
283.1493530	2.69
284.4874268	0.40
285.1781006	2.26
287.2515259	3.94
289.2344360	0.92
291.2252808	2.65
291.9321289	0.26
293.2748718	1.80
294.2524109	0.17
295.2230530	4.02
295.8993530	0.17
297.1921387	3.74
297.8290405	0.17
299.0386963	1.85
300.1882324	0.45
301.1173096	0.50
302.0996704	0.29
303.1804810	1.94
305.1922607	4.19
307.2833862	5.71
309.1759644	4.07
311.2666626	3.78
313.2854614	1.19
315.1575928	4.34
317.2775269	2.46
319.3117065	2.04
321.2283325	5.89
322.2222900	1.29
323.0938721	3.90
324.1479492	0.69
325.2471313	5.17
327.0306396	1.12
329.1758423	2.89
331.2085571	3.29
331.9261475	0.17
333.2311401	6.79
335.2736816	6.41
337.2781372	3.89
339.0650635	3.16
340.5830078	1.11
341.2739868	5.73
343.1746826	1.92
345.1758423	0.87
347.2199707	3.34
349.1212158	9.28
350.7585449	3.04
351.3675537	15.49
353.3328857	2.61
355.2611084	2.63
357.2808228	2.60
359.2301025	6.04
361.0759888	3.08
362.3778687	2.02
363.3338013	2.97
364.3090210	0.42
365.3132324	7.88
366.2796021	0.32
367.2915039	11.72
369.2567139	30.62
373.1871948	4.66
375.2410278	13.15
376.1984253	0.28
377.2939453	12.32
379.1511230	1.57
380.2014771	0.54
381.3837280	2.16
383.2797852	2.36
385.1662598	1.41
387.1403198	1.06
389.1362305	0.31
391.2181396	12.99
393.2498169	48.12
393.8619995	0.47
395.2394409	10.31
397.3014526	1.25
398.5923462	0.14
399.2974243	0.69
401.3669434	9.12
407.2153320	1.03
409.2874756	13.34
411.3058472	100.00
413.2754517	17.73
415.4709473	0.23
419.2982788	25.13
423.3753052	0.50
425.4996338	0.76
427.2717285	6.50
429.2916870	8.45
430.9663086	0.19
433.0706177	0.39
435.4043579	1.46
437.2044678	53.85
437.8419800	0.29
441.1674805	1.33
447.2276611	0.51
451.3145752	1.40
453.3312988	2.13
455.2561035	53.11
455.9326782	0.08
461.1552124	0.09
469.3010254	43.83
471.2619019	9.19
473.1032104	3.87
479.1983643	3.98
484.2288208	0.20
487.3453369	1.82
488.4141235	0.16
497.1586304	7.98
523.2205200	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.2104
Annotation	Unknow
Peak:m/z	Relative Intensity
265.1018677	100.00
266.2406006	0.38
341.1848755	0.22
342.0141602	0.07
413.3530273	0.01
487.3906860	0.02
506.2315063	0.06
509.1256714	0.03
543.4172974	0.08
571.2514038	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2871
Annotation	Atractyloside G 2-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
188.1374512	0.09
200.1769714	0.13
224.1977386	0.06
262.1286011	0.29
269.0344238	15.44
269.9801941	0.43
271.2502441	0.14
291.1141968	0.18
293.2797852	0.85
296.3103638	0.80
307.2703552	0.56
309.1990967	0.18
311.2606812	0.61
323.0871582	0.31
325.1101074	0.38
329.1933594	0.16
339.2042847	0.14
341.0635376	0.15
343.3035278	0.22
351.0809937	0.32
353.0701904	0.12
357.1841431	1.08
365.2631836	0.17
372.9512939	1.28
385.1834106	0.09
397.5944824	0.17
401.3676758	0.25
411.2910156	0.27
412.1176147	0.14
413.1959229	9.20
414.2791138	0.23
429.1144409	0.14
431.4489746	0.83
457.2982178	0.30
461.4935303	0.26
463.4830933	0.11
472.7894287	0.39
475.3005371	0.50
491.0743408	0.30
492.3189087	0.08
493.3604126	0.60
499.3959961	0.40
517.3640747	0.15
531.3656006	100.00
533.3026123	3.73
547.2328491	2.33
549.0505981	0.36
559.1895752	0.31
562.3286743	13.94
563.0892334	0.27
578.3961792	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1827
Annotation	Colabomycin A
Peak:m/z	Relative Intensity
180.8464813	0.07
209.2218323	0.12
210.3789368	0.04
222.3408203	0.05
239.3195038	0.05
250.9865875	0.02
263.2131958	0.17
269.4053955	0.22
271.1843262	0.05
282.4191284	0.04
287.1826782	1.33
288.0946655	0.90
289.1464233	0.95
290.1244507	0.22
311.3222656	0.20
312.2962341	0.09
315.0860596	1.38
316.1672058	0.36
326.9992676	0.05
328.2805786	0.17
329.0248413	0.04
339.0808105	0.05
345.2697754	1.07
346.1469116	0.07
349.3744507	0.03
354.2180786	0.07
355.2029419	0.05
357.1844482	100.00
358.2856445	16.11
367.1364136	0.03
369.2069702	2.33
370.2601929	0.43
372.9715576	0.04
381.3637695	0.08
382.1136475	0.08
383.4071655	0.09
387.1911011	74.86
388.1947021	17.42
388.8415527	0.07
391.4220581	0.07
395.2844238	0.12
399.4247437	1.88
400.2095947	0.44
417.1976929	25.41
418.2346191	6.00
418.8375244	0.02
423.3890991	0.52
429.1782837	1.00
430.3388672	0.42
432.4569702	0.14
435.3500977	0.05
441.2527466	1.56
442.3220215	0.34
443.2208252	0.05
447.2281494	0.73
448.2334595	0.05
454.5483398	0.06
457.1524658	0.08
459.1968384	18.42
460.3355103	5.47
461.4365234	0.24
465.4351807	0.02
471.1867676	1.27
472.3759155	0.47
475.1663208	0.11
477.1683350	51.00
478.2985840	7.35
483.5939941	0.06
484.3333130	0.09
489.2005005	13.48
490.3076782	3.79
501.5062256	0.43
503.5590820	0.11
507.2427368	5.20
508.2969971	0.69
519.2834473	0.45
526.3352661	0.28
531.2082520	0.27
532.2105713	0.24
543.3926392	0.04
550.8504028	0.06
553.0823364	0.13
554.2595825	0.04
561.3217163	1.83
562.4251099	0.32
579.2420654	13.18
580.3839722	2.62
598.2846069	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.3795
Annotation	Unknow
Peak:m/z	Relative Intensity
362.1713257	0.01
448.6546631	0.02
496.4190063	0.03
670.3778076	0.01
779.6498413	0.01
788.5073242	0.01
797.5681763	0.92
800.4531250	0.02
833.3531494	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.2008
Annotation	(6R)-9,10-Dihydroxy-4,7-megastigmadien-3-one-9-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
108.9679871	0.07
114.9938354	0.23
117.0258636	0.13
118.9832153	0.44
121.0068512	0.21
122.9953461	0.49
129.9041748	0.09
131.0635376	0.18
133.0456238	0.58
137.0239258	0.14
143.2393188	0.04
144.9822388	1.27
146.9920807	2.03
149.0874634	0.51
151.0131226	0.52
155.8776398	0.13
159.0872650	0.46
159.8900146	0.04
160.9758911	1.28
165.0438232	0.11
171.1569824	0.34
176.9895325	11.34
178.0127563	0.04
179.0674744	0.52
180.0089417	2.17
180.9986267	0.13
185.0751038	0.06
187.1303101	0.08
189.0656738	2.85
194.0788727	0.07
207.0890961	32.36
208.2227936	0.16
209.2445374	0.06
210.9151001	0.04
212.1271057	0.03
218.4104004	0.19
222.0234070	0.17
222.8007812	0.03
225.1299438	100.00
236.0511475	0.03
239.0996704	0.09
243.0412292	0.11
245.0629883	0.05
247.1015320	0.07
255.0762634	0.09
256.1744690	0.04
268.8837891	0.03
275.2318115	0.03
287.9861755	0.07
290.1610107	0.03
294.3435059	0.14
297.0042725	0.43
298.1089783	0.11
302.0073547	0.09
311.0022583	0.20
314.8635864	0.20
316.6390686	0.14
323.3152771	0.06
327.0712891	0.11
333.0113220	0.23
337.3312988	0.08
338.9750366	0.11
341.7120972	0.90
342.4016724	0.04
344.6711121	0.07
350.8145752	0.31
351.5717468	0.21
355.4063416	0.11
358.2345581	0.54
359.2288513	0.02
367.5366516	0.02
369.2890320	2.76
370.0700684	0.06
372.3241882	0.10
373.3867798	0.08
377.7171631	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1455
Annotation	Mitomycin
Peak:m/z	Relative Intensity
112.9519196	6.38
114.1522675	0.05
117.0804138	0.90
118.9490662	2.84
119.9244232	0.09
124.8700104	1.32
126.7475128	0.13
130.9282684	0.81
135.0294800	0.53
136.9315491	0.28
139.0826721	0.38
143.0334167	2.88
147.1077118	0.32
148.8729248	0.25
152.9207611	0.10
157.0919800	91.25
158.2043152	0.15
161.0139923	9.21
161.9503784	0.72
171.0718079	3.03
176.9461823	0.25
178.9593506	4.89
181.0949707	0.28
184.1265564	0.18
188.7763824	0.23
192.3340454	0.10
199.0577850	5.53
201.9684753	0.30
203.1366730	1.49
207.0681152	43.71
208.0013428	0.07
211.0544434	0.11
218.2065430	0.21
220.9713440	1.42
225.1481934	0.34
229.1404724	5.06
245.5088501	0.34
246.9186401	0.26
249.1535950	0.15
250.0261536	0.10
257.0345764	0.20
258.3001404	0.27
258.9260864	3.42
262.9547729	2.25
269.1495972	0.06
275.1306152	1.08
277.0551453	0.08
289.3535767	0.71
293.4426880	0.23
300.9639282	0.50
302.7447205	0.94
304.0226440	0.45
305.2951660	10.15
307.4204102	0.29
311.4418945	0.09
318.9699707	100.00
319.9980164	1.03
321.1743164	0.64
321.8287964	0.14
323.2397461	0.51
329.3595886	0.08
332.3922729	0.99
333.0635986	0.18
335.6339722	0.40
346.2644653	1.61
347.2304382	3.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2782
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
135.1120300	0.04
140.1014709	0.08
153.0442505	0.24
154.1045837	0.02
166.0631409	0.01
196.0127258	2.26
197.0775909	0.17
214.0418091	1.10
215.1390991	0.08
237.3046265	0.01
248.2021484	0.01
255.2273865	100.00
256.3333130	16.99
283.5731812	0.07
284.3547668	0.02
335.3811951	0.03
391.3777771	0.39
392.3785400	0.08
407.4211731	0.10
409.2738037	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1757
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
177.1661530	0.08
189.1764832	0.15
198.2848053	0.37
214.1209106	0.49
231.2111053	0.08
253.2073669	0.06
288.6199951	0.05
292.3304443	0.12
301.3331909	0.26
307.3288574	0.19
313.1609497	3.69
315.3297729	0.24
317.2105713	0.54
325.3395691	0.92
330.0708618	0.03
339.1541138	0.10
341.2358398	0.09
343.2514648	15.73
347.1792603	0.08
353.3200684	0.09
355.3649902	0.07
358.2980957	0.12
361.0570679	0.07
365.6306763	0.03
367.1583862	14.88
367.7623291	0.16
378.1756592	0.04
379.2369385	0.36
380.3909302	0.06
383.1895752	0.52
385.3885498	0.20
391.2233276	0.80
392.5214844	0.27
397.1163940	15.47
402.2800903	0.13
405.5046387	0.30
409.2316284	9.22
415.3363647	0.14
418.9856567	0.04
427.2355957	11.96
439.2516479	0.56
442.6281128	0.21
445.1530762	56.72
445.8427734	0.13
449.2479248	0.35
451.4154663	0.06
457.0355225	0.49
458.9714966	0.98
461.1859131	0.19
463.2365723	16.32
464.8016357	0.20
475.0578613	0.81
478.4304810	0.50
479.2274780	0.32
480.4213257	0.08
487.2312012	2.43
489.0354004	0.32
492.1459961	0.11
498.5796509	0.27
505.1974487	20.98
511.2432251	0.41
513.1432495	0.11
514.3060913	0.43
515.1148071	0.22
516.1444092	0.28
529.1704712	14.87
531.5094604	0.34
534.8922729	0.31
535.5407715	0.16
536.3740845	0.05
537.7642212	0.04
541.1826172	0.82
542.1980591	0.70
543.4926147	0.27
544.9312134	0.29
553.3831177	0.58
557.6492310	0.17
559.2170410	47.04
560.3077393	0.71
561.4072876	0.71
562.3660889	0.28
567.5463867	0.26
571.2127075	10.25
572.3479614	0.21
578.3881226	0.26
579.2796021	0.06
580.1724243	0.56
586.7594604	0.18
588.5153198	3.16
589.1886597	19.11
592.5189209	0.21
593.5366821	0.12
601.3372192	0.28
607.1578369	100.00
607.8463745	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.177
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
113.0128326	0.47
119.0581512	0.42
126.6531067	0.04
130.9783936	0.09
142.8980103	0.13
147.2088623	0.04
148.8730774	0.39
155.0993347	0.08
159.1000061	0.38
161.0321808	3.64
165.0810547	0.04
166.9596252	0.20
177.0203247	0.09
179.0353088	3.91
185.0355682	1.05
193.1123810	0.63
195.1218567	0.11
209.1675720	0.03
211.1869202	0.07
224.9968567	0.17
226.6837158	0.07
233.0404358	0.25
235.1301270	0.03
245.3942566	0.07
257.3514099	0.18
259.4420471	0.07
261.3892822	0.07
269.0196533	0.53
288.1738586	0.06
295.1177368	0.09
324.8849792	0.03
329.0898438	0.21
331.5518799	0.13
332.2843323	0.20
333.2662964	0.39
335.5211487	0.31
345.3934937	0.04
347.1611328	100.00
347.8660583	0.21
348.9937744	0.21
350.2697754	0.03
357.1976929	0.58
374.4099121	0.07
375.2267151	0.37
378.1623230	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0824
Annotation	Eupatorin
Peak:m/z	Relative Intensity
118.8652039	0.04
125.1100388	0.04
129.0553284	0.06
132.2581329	0.02
139.0227356	0.02
143.3108215	0.03
144.7850494	0.03
151.8347931	0.01
157.2070618	0.02
161.3712921	0.02
162.117569	0.02
165.2770081	0.03
168.8428955	0.03
185.0042114	0.01
188.3094025	0.01
191.2582703	0.05
193.1529541	0.02
197.0669098	0.02
199.010025	0.05
201.193573	0.02
219.0439453	0.05
233.2662659	0.01
233.8927307	0.03
237.1887207	0.02
239.0274353	0.03
248.1484375	0.02
249.3782043	0.04
255.451355	0.05
256.0560303	0.02
257.1593018	0.03
263.2252808	0.07
268.1737976	0.03
269.3010254	0.01
271.3278809	0.05
281.3712769	0.15
282.099762	0.11
283.2182312	0.08
284.2391357	0.06
285.371582	0.02
296.2861938	0.14
297.2865295	0.15
299.1856384	0.05
300.0345459	0.16
307.2722473	0.10
309.2255859	0.03
310.1477661	0.03
311.326416	0.24
313.1365967	3.93
314.3381653	0.15
315.1607361	0.34
324.4805298	0.26
325.3034058	1.78
326.4230347	0.18
328.0629272	100.00
329.0982971	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.2032
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9134521	0.55
131.0380249	0.06
135.4299469	0.06
139.0744019	0.12
142.8615265	0.96
153.1465454	0.04
158.8497467	0.20
161.2125702	0.08
179.2149048	0.08
187.1808167	0.89
195.0648193	0.11
207.3956299	0.08
208.9329987	0.06
211.1377258	0.19
212.1580048	0.15
217.2261963	0.16
220.9824524	0.18
229.1276855	0.03
231.3763428	0.06
235.1254883	0.05
253.1778564	0.27
255.1463928	0.32
257.3326416	0.34
275.1694641	1.15
277.3788452	0.04
282.1617126	0.05
283.2356262	0.34
293.2683716	3.11
294.6886902	0.04
297.5698853	0.12
302.1305542	0.09
305.3319702	0.07
313.3398743	0.07
315.2198486	0.58
316.1513062	0.36
318.3699341	0.09
319.2701416	0.19
329.8828735	0.21
331.2477417	21.10
333.2799377	3.78
335.1432190	3.15
341.2770386	0.06
347.2546082	0.09
349.2344971	8.69
351.4557800	0.16
353.2106323	0.04
357.4218445	0.06
361.3425598	0.83
373.3421631	1.18
374.3102722	0.11
375.0097656	0.71
383.3284912	0.23
391.1742249	100.00
392.1325684	0.49
393.2830200	6.31
401.2778015	0.10
404.2492371	0.07
407.4387512	0.04
418.2697449	0.23
419.4909973	0.47
420.3059387	0.15
421.1377869	0.06
421.8378601	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0156708	0.12
128.9666138	0.23
130.9849396	0.05
140.9411011	0.25
142.9590912	1.71
159.0212860	1.89
160.9799042	13.68
175.1180573	0.09
179.0171814	4.23
187.0798187	2.93
203.1876221	0.21
205.0874939	14.19
207.1653290	0.14
218.9126434	0.12
221.9155884	0.10
229.4074402	0.17
239.1262207	0.15
247.1943665	8.48
259.1943970	6.18
269.0729370	0.20
277.1588745	31.56
308.5224609	0.04
311.1648865	2.57
331.2282104	0.11
341.0147705	0.05
342.3869629	0.08
349.2187500	0.05
351.2741089	0.05
367.0998840	100.00
367.7574463	0.31
371.3746033	0.52
384.7794189	0.78
385.4370728	0.31
386.2683105	0.05
387.2760925	0.12
402.5124512	0.05
411.1351624	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.4016
Annotation	Scopoloside II
Peak:m/z	Relative Intensity
301.4161682	0.03
318.0561523	0.03
368.2988892	0.03
381.4234619	0.03
385.3742065	0.02
386.2960815	0.05
387.3469238	0.04
396.5297852	0.07
397.4230347	0.03
408.9948120	0.04
429.7145386	0.16
443.2243042	0.03
481.5476074	0.07
482.2592773	0.19
499.5203247	0.80
500.4153442	1.11
501.4400635	2.30
562.6803589	0.04
563.6868286	0.06
615.9401245	0.03
618.7681274	0.08
619.4817505	0.03
620.6636353	0.29
621.5964355	0.13
624.0667114	0.04
638.7967529	0.09
639.4601440	0.12
645.6358032	0.03
647.5400391	0.08
653.2778320	0.09
661.9618530	5.99
662.5745239	19.33
663.5285034	34.09
664.1690063	0.04
679.1387329	0.13
680.3461914	1.97
681.2460938	1.82
690.7953491	0.03
709.6495972	0.14
722.2347412	2.19
723.4480591	3.87
725.2052002	0.06
726.2490845	0.04
737.4125366	0.10
769.4288330	100.00
770.5427856	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0824
Annotation	(-)-Usnic acid
Peak:m/z	Relative Intensity
112.9454193	0.03
139.0636902	0.01
141.1947479	0.05
155.0721436	0.03
160.944519	0.05
162.0162659	0.02
164.9501343	0.03
180.0059509	0.01
185.78302	0.02
191.0840759	0.08
192.9878693	0.05
199.3960571	0.02
201.1688232	0.01
205.0133667	0.01
210.7739258	0.02
228.3325806	0.04
229.1132812	0.07
231.1706848	0.05
244.0125427	0.09
249.2619629	0.04
250.2175293	0.01
255.6412354	0.02
257.1221924	0.06
263.087616	0.02
269.3981628	0.05
280.4446716	0.12
281.3538818	0.08
282.0717163	0.08
283.058136	0.06
284.3132324	0.02
285.3684082	0.04
292.9781494	0.03
295.8734741	0.03
297.144043	0.31
297.949707	0.05
299.2258911	0.23
300.1821594	0.04
307.2498779	0.01
310.2839355	0.02
311.381958	0.12
312.5892944	0.37
313.239502	2.94
314.8003235	0.27
315.4118347	0.27
322.9507446	0.02
324.4760132	0.36
325.3893738	1.14
326.2904663	0.02
328.0710754	100.00
329.1895752	0.66
343.0036621	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	885.2685
Annotation	Unknow
Peak:m/z	Relative Intensity
269.0742493	0.31
270.2717896	0.01
271.2757568	0.02
424.9808350	0.05
432.4126587	0.05
459.4317017	0.11
465.6146851	0.01
473.3508301	0.01
474.3507690	0.01
501.2912598	0.02
513.3244629	0.01
561.1914062	0.04
577.0907593	0.09
578.2853394	0.40
579.3452148	2.65
620.3692627	0.02
621.3154297	0.44
660.2220459	0.02
661.4165039	0.11
723.5874023	0.07
741.4487915	0.13
783.5763550	0.12
798.4979248	0.11
823.3429565	0.14
830.4050293	0.02
866.4979858	0.08
867.5828247	0.02
885.3481445	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1244
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9343185	2.44
89.0175705	2.96
94.9282532	0.10
96.8850326	0.24
100.9086304	6.33
102.7464676	0.11
110.9565125	0.10
112.9747009	6.74
114.8965149	0.78
118.9977798	4.42
124.7983627	0.12
127.0718994	1.16
128.0085602	0.17
129.0298462	0.34
131.0422363	100.00
138.7914429	0.22
142.8810120	1.94
145.1943359	0.24
148.9876709	0.28
154.9190369	0.07
156.8505554	0.10
159.1137085	0.08
160.9967194	2.10
164.0801697	0.26
172.9934082	7.35
178.9872742	1.45
185.0811462	0.54
191.1614990	0.30
192.0271606	0.10
202.8401794	0.51
206.3608704	0.15
209.2033691	0.09
227.1907043	0.06
233.0571899	0.25
246.9107361	1.56
249.1031494	0.39
261.3028564	0.22
265.0070190	0.09
275.1197815	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	283.0396
Annotation	Unknow
Peak:m/z	Relative Intensity
79.8270569	0.02
95.8080139	0.03
96.8284378	0.05
127.7788239	0.02
142.0042114	5.40
153.0727081	0.02
157.0505676	0.17
157.9529724	0.12
186.0498657	0.46
196.0348206	0.32
203.1445923	3.97
209.0208435	1.45
210.0261841	2.30
221.9832764	100.00
222.7560730	0.01
223.9800720	0.04
236.9466858	0.13
238.0004883	4.38
239.1279907	1.22
240.1451111	0.02
247.0688782	0.10
254.9255981	0.01
264.0122070	0.02
265.2476501	0.35
266.1160583	2.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	615.2141
Annotation	Unknow
Peak:m/z	Relative Intensity
221.1602478	12.58
253.1273346	0.14
262.9743042	100.00
284.7218018	0.08
295.4192200	0.07
303.8040771	0.09
306.1901245	6.17
306.8854980	27.29
309.3176880	0.27
391.3863525	0.13
397.4444580	0.18
411.3813477	0.15
420.3569336	0.14
421.5122681	0.17
427.5972900	0.12
439.5078735	0.23
451.2554932	0.17
501.4169922	0.34
506.6671753	0.15
527.4561768	0.29
528.6831665	0.29
529.5088501	0.34
548.2989502	0.15
570.0869751	0.15
571.0397339	0.46
581.3854370	0.16
584.7662964	0.09
597.2332153	1.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1111.2921
Annotation	Unknow
Peak:m/z	Relative Intensity
313.2147217	0.02
315.5028992	0.01
316.2115173	0.07
328.1017456	0.05
331.1676331	1.71
337.2618103	0.01
343.2615356	0.06
345.2490540	0.04
346.3792114	0.01
357.3247681	0.02
361.2086182	0.52
362.8981018	0.01
366.9700928	0.06
368.2194519	0.02
373.1614990	0.04
374.3258057	0.01
375.2696228	0.01
377.0213928	0.03
383.1745911	0.01
389.2964478	0.02
397.1976929	0.03
406.0216064	0.01
409.0609131	0.03
411.0726318	0.01
421.1182861	0.20
427.0888367	0.03
433.4215088	0.04
439.1550293	0.25
456.6408691	0.01
465.0545349	0.01
475.3258362	0.04
487.3414917	0.03
493.0236816	0.07
517.3719482	0.02
527.4619141	0.02
539.2730713	0.01
540.9699097	0.02
545.1306152	0.02
547.0825195	0.01
553.0191650	0.03
565.5396729	0.01
575.3940430	0.49
577.3869629	0.02
583.1627197	0.04
597.5178223	0.01
601.0797119	0.17
607.3535156	0.06
618.1933594	0.03
619.3721924	0.67
631.6333008	0.02
637.2902832	0.53
637.9227905	0.00
649.3180542	0.07
661.3660278	0.01
663.1193237	0.01
667.4916992	0.01
679.2799683	0.20
697.5516357	0.03
709.4024048	0.09
715.3564453	0.23
727.2161865	0.21
733.5875854	0.03
745.2284546	2.12
745.8497925	0.01
751.3029175	0.10
757.4707031	0.05
763.3677368	1.06
775.5616455	0.08
781.1988525	0.89
793.2802124	0.06
811.2043457	0.03
820.5002441	0.02
1093.3845210	0.03
1111.1070560	100.00
1112.1461180	0.95
1112.9271240	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	398.2007
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9142227	0.25
132.0041809	100.00
144.9791870	0.07
147.9280396	0.76
160.9191284	0.10
162.7116089	0.17
177.3784485	0.18
199.2825165	0.07
230.0754395	0.08
235.2369995	0.08
236.1596375	0.37
237.9046326	0.13
239.1659851	0.20
249.1466370	0.49
267.0169678	1.46
269.0630798	0.14
304.6669312	0.28
308.0067139	0.09
352.1071472	0.26
380.2300720	1.05
388.9012146	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.2618
Annotation	Xylogranatin A
Peak:m/z	Relative Intensity
197.2397156	0.02
211.2230072	0.01
212.9167786	0.01
215.1188354	0.03
219.0522461	0.02
228.3092651	0.03
237.0331573	0.03
239.4379578	0.03
251.1428223	0.02
255.2783356	0.04
265.1345215	0.03
269.3309021	0.02
270.3237305	0.02
272.1020508	0.05
276.9913940	0.02
279.0349731	0.07
284.0274658	0.01
285.2900085	0.02
286.4352417	0.04
287.1889954	0.04
291.1375122	0.01
297.5585022	0.02
298.4338379	0.03
299.3411255	0.18
300.3704224	0.09
301.3889160	0.02
309.0022583	0.03
310.0938110	0.03
313.3930664	0.04
314.2409973	0.17
315.1927490	0.12
317.1139832	0.04
321.2433472	0.08
323.3439331	0.05
326.1650391	0.04
329.0626831	0.82
330.1960449	1.61
334.2186279	0.02
341.2025146	0.02
343.2250977	0.42
344.1956177	1.49
345.1325684	3.28
355.1508179	0.16
357.2958374	0.02
358.0958862	0.10
359.2360840	1.87
360.4251709	0.03
372.4935303	0.01
374.3821411	0.06
375.4505615	0.03
387.2650757	0.16
398.3389282	0.72
399.6644287	0.12
400.3776855	0.35
401.2349243	0.11
402.3896484	0.09
403.2337036	0.13
411.8043213	0.02
412.4466553	0.44
414.3074951	0.05
417.5910034	0.10
425.3067017	0.01
429.6603394	0.04
430.3740845	0.06
432.2921753	0.13
434.5199585	0.04
442.3314209	1.32
443.3129883	1.74
444.3771973	0.38
445.2780151	0.15
446.4839478	0.05
452.0939941	0.03
459.2962646	0.11
460.3644409	0.03
462.3501587	0.01
463.3624878	0.06
469.8972778	0.07
473.5483398	0.07
474.2084351	1.11
475.3612671	2.63
476.3546143	0.33
486.1416016	0.55
487.3530273	11.99
488.4549561	0.33
489.1008301	0.02
490.9298096	0.05
492.6351318	0.07
493.5343018	0.10
494.3268433	0.02
497.4356689	0.03
503.2384644	0.05
504.4263916	0.10
506.1354980	0.06
509.3483276	0.10
518.3944702	0.52
519.3083496	2.25
520.3982544	0.65
521.3381958	0.21
523.4786987	0.22
524.5088501	0.04
530.1165771	0.05
535.3914185	0.08
536.8352661	0.02
537.4519653	0.29
547.2371216	0.25
553.3795776	0.11
563.3506470	0.01
565.3860474	10.95
566.5473633	0.01
568.6132202	0.11
569.4348755	0.11
579.3634644	0.05
581.4103394	0.78
582.5576172	0.04
591.3050537	0.22
594.3572388	0.12
595.5218506	0.03
596.2402954	0.02
597.3278198	10.78
598.0090332	0.02
599.3359375	0.05
604.5312500	0.12
605.2091064	0.02
607.3002930	0.04
609.3283081	100.00
610.3649902	0.04
611.3468628	0.04
613.3964844	0.01
622.4685059	0.05
623.4603882	0.13
625.2617798	2.57
626.3623047	3.57
641.2770386	20.71
642.2827759	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1746
Annotation	Epijasminoside A
Peak:m/z	Relative Intensity
94.8725891	0.22
97.0258865	0.13
100.9142761	0.07
104.9761429	1.27
106.9923859	3.82
108.9251709	1.00
112.8412781	0.23
117.0236053	0.26
119.1541443	0.07
122.9832001	5.68
124.9044647	0.89
133.0414124	3.13
141.0054474	0.22
148.9953308	3.41
150.0104980	1.05
151.0257874	6.17
154.8250122	0.95
158.8632507	0.05
167.0626678	0.13
169.0659332	100.00
181.1947784	0.04
182.9022217	4.57
183.8719788	0.13
188.8596039	0.10
191.2082825	0.26
194.9467773	0.07
197.1849365	0.09
200.7796478	0.13
210.8215942	0.15
215.3512268	0.34
216.1071167	0.12
219.1418457	0.59
224.0675049	0.15
225.9655762	0.14
229.3621826	0.37
243.0304871	0.25
244.2347717	0.14
252.9609680	0.23
254.9614258	0.65
258.7556152	0.06
267.2258606	0.18
271.1055298	1.08
272.2759399	0.15
275.1495972	0.56
281.2287903	0.59
285.1797485	0.06
286.1380310	0.04
287.2775269	0.04
288.3190918	0.16
289.2052917	0.39
293.7823486	0.21
295.0412292	0.28
298.2115173	1.25
299.1200562	0.69
301.1781006	2.27
303.0738220	30.57
304.1316528	5.99
309.1059570	0.28
310.8013916	0.33
313.0525513	2.75
313.9909058	0.52
316.1130981	29.92
317.1887207	3.65
331.0640869	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	500.9199
Annotation	Unknow
Peak:m/z	Relative Intensity
155.1300507	0.17
158.9163971	3.09
198.9831238	0.95
213.0062866	0.05
217.1124878	0.19
228.9329987	0.93
240.1451416	0.04
271.0943909	0.23
272.9391174	76.83
385.0686340	0.41
386.9042358	100.00
387.5065918	0.30
413.2189941	0.25
415.8596191	0.05
423.0350342	0.09
427.1150208	0.19
428.7402344	0.06
455.0591125	0.10
500.6665649	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2188
Annotation	Glabcensin R
Peak:m/z	Relative Intensity
182.9226074	0.27
190.6852417	0.05
210.0632324	0.08
221.1378021	0.03
222.7460327	0.23
234.0162201	0.04
240.3668823	0.04
253.1406555	1.03
254.2577515	0.08
257.0903320	0.19
265.0831299	0.15
271.9406433	0.06
277.2475586	0.81
286.1207886	0.04
290.1074219	0.04
297.1334839	0.33
299.4302368	0.18
307.2512512	0.04
309.2672729	0.79
313.1289062	0.20
323.2961426	0.11
329.2777710	0.16
339.1884766	0.16
341.3782349	0.10
347.4401855	0.12
351.3915405	0.12
353.4324341	0.21
355.3348389	0.09
363.2615967	0.13
365.3649902	0.39
369.3641968	0.59
371.4497681	0.35
379.4315186	1.36
381.0739746	1.22
383.3186035	2.94
396.7930908	0.23
401.1392822	0.08
403.0364990	0.21
404.2781982	0.05
409.1459351	0.11
412.6614990	0.21
417.4691772	0.23
421.3773193	1.74
425.1190796	0.07
427.1505127	17.84
427.7874756	0.21
433.0126343	0.28
435.3143921	0.63
437.5938110	0.15
439.2133789	4.08
439.8831787	0.06
440.8316650	0.17
449.9864502	0.05
450.9378662	0.07
462.7166138	0.12
463.5821533	0.16
464.8956299	0.61
469.0840454	1.97
471.2124634	2.44
473.2245483	0.07
483.1995239	100.00
483.8444824	0.24
486.7794800	0.20
487.4501953	0.68
499.0034180	0.03
500.3611450	0.65
501.2400513	1.34
503.0883179	0.11
508.2590942	0.09
510.2179565	0.08
515.3247681	0.07
519.2802124	0.06
520.2191772	0.20
528.6065674	0.53
529.4016113	0.28
533.1666260	0.09
547.6467896	0.11
548.4714355	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	568.3619
Annotation	Unknow
Peak:m/z	Relative Intensity
169.1023712	0.08
177.4579010	0.12
183.6815186	0.04
196.1667175	0.09
217.6848755	0.10
221.9652710	0.16
224.2293701	0.45
227.9319763	0.11
231.8542175	0.20
241.9053040	0.08
256.8593750	0.08
279.9231873	0.12
283.3273315	3.05
311.6786499	0.09
314.9762573	0.04
330.1656494	0.22
333.0811768	0.13
349.3270874	0.07
359.6177979	0.07
370.4555664	0.08
374.5206909	0.08
378.5275269	0.12
382.3842773	0.05
401.1906738	0.06
419.1938477	0.09
438.3945312	0.20
452.9841919	0.09
472.4810791	0.21
483.1511841	0.17
485.0527954	0.37
494.5430908	0.12
495.9235840	0.06
506.3372192	0.27
508.4647217	100.00
509.2973633	0.04
518.4415894	0.46
522.5402222	0.74
524.3036499	0.10
530.0285034	0.47
530.7160034	0.12
532.1560059	2.45
549.1570435	0.09
550.3837891	0.05
554.0962524	0.13
576.1342163	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.14
Annotation	Unknow
Peak:m/z	Relative Intensity
157.9881287	0.07
160.0853271	0.29
160.9730682	0.10
161.9646606	0.18
163.1457977	0.08
173.1017456	0.08
174.9918976	0.59
176.0611877	0.60
177.0265808	0.15
178.8683624	2.30
179.4828644	0.10
186.0464935	0.60
188.1065369	1.11
189.2041016	0.09
191.0113525	0.47
193.0249176	0.38
194.2299347	0.21
199.9797821	0.23
201.1950684	0.80
202.0088501	0.19
202.9619293	0.94
204.1320190	1.94
205.1755981	0.15
207.2955170	0.30
215.0745697	0.04
217.0076447	0.67
219.0539398	10.63
219.9653015	0.21
220.5696716	0.32
221.1983948	0.69
226.9442902	0.05
229.3519440	0.07
233.1400299	1.32
234.9743195	1.03
237.0435944	0.05
239.2103882	0.03
243.1416931	0.22
245.1646118	0.11
247.0478058	1.50
249.0331726	0.18
249.9555054	0.19
251.1145782	1.37
253.4564209	0.08
256.2928772	0.05
261.3400269	0.27
263.1756897	0.89
264.4932251	0.12
265.0985718	0.74
271.0609131	0.86
272.7131348	0.07
277.3127441	0.13
279.1890869	0.09
281.1402588	0.21
287.0137329	0.07
289.1188965	3.01
291.1717224	4.97
299.1123047	0.18
303.2250977	0.09
307.0977173	100.00
310.1430664	0.05
316.1104126	0.09
321.0104980	0.11
322.2422485	0.30
324.6680298	0.31
325.2988281	0.53
333.3069458	0.50
339.0464478	0.04
342.1848755	0.05
343.2700806	0.65
348.6952515	0.17
351.0487061	6.26
353.1876221	0.12
363.8093262	0.07
366.4100342	0.03
367.0402832	0.24
376.7528076	0.04
378.0574951	0.06
389.1919556	0.16
389.9518433	0.13
391.1033936	0.17
395.7343750	0.06
397.5031738	0.04
399.0737915	0.07
409.2131958	0.26
411.3359985	0.19
413.4666748	0.07
419.2746582	0.08
423.5202026	0.11
427.0902100	0.45
432.0654297	0.24
435.1110840	0.07
437.1348267	0.07
439.3778687	0.17
441.3462524	0.24
444.0043945	0.12
445.5307617	0.03
451.5878296	0.13
454.4303589	0.06
455.1931152	0.05
456.2701416	0.09
463.0498047	0.04
469.1645508	0.17
471.5488281	0.27
485.0935059	0.93
486.3229980	0.47
487.1797485	1.00
492.2212524	0.46
494.2830200	0.05
495.3137817	0.21
499.5204468	0.07
503.3869019	0.05
511.3859253	0.07
512.6581421	0.61
513.2776489	8.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	626.69
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8411560	2.20
290.8196106	12.84
374.6367798	5.37
375.2700806	0.07
398.5198975	0.16
418.9898682	0.16
458.5395508	63.29
459.2593994	0.21
460.7124634	1.34
482.8953247	0.15
490.7702637	0.66
506.4928589	0.23
520.4246216	1.95
529.3767090	0.20
542.5280151	100.00
543.2666626	0.38
566.6040039	0.04
579.7058716	0.18
580.8103638	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	606.44
Annotation	Unknow
Peak:m/z	Relative Intensity
183.1255798	0.29
193.0794067	0.06
194.8738861	0.10
201.0594635	0.39
205.2002563	0.09
225.1305237	0.14
269.2574463	0.08
283.6112671	0.07
296.5302734	0.08
301.0723267	0.06
304.2559204	0.24
332.2391968	0.04
333.4619141	0.25
378.0285645	0.11
380.4315186	0.16
389.3093872	0.12
395.2421265	0.11
419.2741089	0.12
422.6129150	0.08
431.4274292	0.06
447.4495850	0.07
449.3088989	0.10
454.1099243	0.11
460.3322754	0.09
472.4034424	0.20
473.8141479	0.33
474.9844360	0.58
475.9459839	0.30
487.6187134	0.36
488.2873535	0.08
491.4770508	0.40
501.1597900	0.12
501.8414917	0.10
503.0859375	0.04
504.2538452	0.07
505.5015259	0.13
506.3686523	0.15
513.4302368	0.09
515.4265747	0.59
517.1301270	0.57
519.3015137	2.95
520.0071411	0.05
525.4783936	0.34
529.4207764	0.28
530.3933716	0.23
531.2916870	0.37
533.2056885	0.80
539.7186890	0.35
545.3949585	0.97
547.3778076	100.00
548.0099487	0.17
551.6712036	0.38
557.6313477	0.04
559.7268677	0.32
561.4549561	2.57
575.3286743	1.29
579.4932861	17.72
588.4884644	0.11
589.3495483	2.47
591.5544434	0.28
607.4730225	3.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	815.4101
Annotation	Unknow
Peak:m/z	Relative Intensity
234.2405853	0.07
238.3010559	0.02
245.0728912	0.27
249.7578278	0.13
253.3459473	0.11
258.2673645	0.05
260.3068237	0.04
262.3265381	0.32
268.3067627	0.05
274.8344727	0.17
278.1272583	0.65
281.1285706	0.08
284.2618713	0.12
285.3085022	0.04
290.3949585	0.04
295.1589661	0.10
299.9650269	0.11
301.9862061	0.30
304.3120728	0.14
307.3532104	0.10
310.4893799	0.09
315.0578613	0.17
316.8837585	0.07
323.3633118	0.13
324.2476196	0.26
329.1951904	0.04
329.8664551	0.13
331.0954590	0.07
335.1118164	0.53
340.9907227	0.12
342.2145386	2.10
345.3971558	0.03
349.4908447	0.03
352.4223328	0.24
359.3637085	0.16
361.0654297	0.37
361.9420166	0.22
363.4591675	0.14
371.1992188	0.15
376.2546082	0.17
381.3510742	0.24
391.5559692	0.15
392.4249878	1.00
397.4477539	0.05
399.2039795	2.04
402.9804077	0.23
409.3817749	0.33
412.3059082	0.13
413.1973267	0.03
414.3577881	0.10
416.3244629	0.17
417.6290283	0.02
419.0137939	0.10
420.2843018	0.05
424.3046265	0.08
424.9067383	0.05
427.3305664	0.15
428.3861084	0.22
429.2553711	0.19
438.1145020	0.05
441.6156006	0.14
442.3105469	0.77
444.4556885	0.33
446.1961060	0.07
448.4565430	0.15
449.2691650	0.11
455.2825317	0.31
456.2489014	2.46
458.3281860	0.13
463.1942749	0.04
465.2456665	0.09
466.4834595	0.06
469.4640503	0.15
470.3143921	0.19
472.6707764	0.06
473.2921753	0.62
473.9346924	0.28
474.5778198	0.02
477.4243164	0.32
478.2208862	0.15
480.5299683	0.43
481.8801880	1.49
482.5192261	1.22
484.4426270	0.18
485.3320312	0.07
487.5288086	0.03
488.2666626	0.27
489.8010254	0.34
498.3271484	0.05
502.4498901	0.13
505.3564453	0.58
506.2469482	1.33
508.4084473	0.71
509.2189941	0.09
511.3610840	1.22
512.3610229	0.29
513.5471191	0.32
514.4928589	0.15
518.3012085	0.26
521.5095825	0.43
522.2789917	0.15
523.2376709	0.23
524.5341797	0.10
526.3220215	0.13
529.8663940	0.12
532.2589722	0.03
537.5111084	0.06
539.3947144	4.58
541.4586792	0.38
542.7103882	0.13
546.4880981	0.14
553.6031494	0.06
554.4547729	0.06
555.4105225	0.30
556.8593140	0.10
557.5335083	0.75
564.5670776	0.05
569.4807129	0.14
571.1322632	0.21
575.4222412	2.86
577.4011841	0.41
585.1992798	0.58
586.6659546	0.39
587.4589233	0.41
593.4505615	0.59
596.1950684	0.25
603.3386230	10.63
604.2383423	0.07
604.8496094	0.41
605.4650269	0.46
610.5454712	0.38
612.8129272	0.33
618.4836426	0.08
619.1680908	0.32
620.2398071	0.63
621.2265015	0.25
622.6681519	0.65
623.6240845	0.19
626.5392456	0.22
631.4458008	0.51
632.4083252	0.15
634.4957886	0.28
636.4606323	0.07
637.6502075	1.18
638.5112915	10.93
640.5667114	0.21
650.2989502	0.12
652.4619751	1.11
654.4658813	0.66
656.6897583	0.03
662.4593506	0.03
666.3931274	0.10
668.4644165	0.63
671.3706665	0.04
672.4569702	0.14
673.4593506	0.18
674.5004272	3.51
682.5633545	0.12
684.3717651	0.84
686.4541016	0.73
688.6690674	0.25
690.4309692	0.17
691.0687866	0.11
696.4168701	0.08
698.3918457	0.63
699.1285400	0.04
700.3783569	0.54
702.4393921	40.26
703.8350220	0.10
705.4399414	0.02
706.4001465	0.32
707.5579224	0.39
716.5238647	2.52
717.1306763	0.06
718.4754639	1.60
723.4918213	9.51
724.4143066	0.44
726.0369263	0.19
728.6917725	0.10
733.4750366	3.92
734.4634399	0.04
742.7395630	0.14
751.5236816	57.10
752.8598633	0.14
758.4057617	0.30
769.4519653	0.14
770.5071411	0.55
771.3711548	0.50
774.7982788	0.03
787.4758911	26.77
788.1011963	0.31
797.5706787	4.49
800.5137939	0.13
815.4844360	100.00
816.1963501	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.2344
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
157.1221924	0.03
162.9701385	0.14
165.2314758	0.06
169.0506287	0.13
173.0521545	0.62
174.0769958	0.03
175.2522278	0.03
180.9864349	0.10
187.2625122	0.11
189.0333099	0.10
191.0264893	0.23
193.1310272	0.07
194.2668457	0.25
195.1138306	0.20
197.3534241	0.15
199.2581635	0.13
201.2135620	0.24
202.1703949	0.06
203.3577118	0.08
209.1790466	0.07
211.0581512	0.12
213.1814117	0.19
214.2457886	0.09
217.1010742	0.61
219.2416382	1.38
221.2060394	0.79
223.2428284	0.05
227.3583984	0.08
229.2368774	11.35
231.1897888	0.10
232.9095459	0.48
235.3888245	0.33
242.8108063	0.03
245.1829071	0.16
247.1976166	5.02
253.0711060	0.05
257.5307922	0.04
261.0811768	0.12
263.0626831	0.71
267.0392761	0.02
268.6878662	0.03
269.3115234	0.08
273.0937500	0.21
275.2931824	0.15
277.2847595	0.08
285.3326416	0.04
287.2083740	0.43
288.1983643	0.06
289.3828735	0.12
291.1819153	0.58
293.2886047	0.13
299.0358276	0.15
301.3083496	0.09
303.3127441	1.34
305.1549683	3.15
311.2643433	0.05
314.3098755	0.06
315.4233398	0.05
316.3906250	0.10
317.0622559	0.08
319.3641968	0.07
321.2678223	1.29
325.4118042	0.07
328.1520996	0.18
329.2521973	0.28
330.8479004	0.05
331.4589233	0.06
332.9772949	0.21
335.2189331	0.06
343.4624023	0.50
344.2138672	0.44
345.2330322	0.21
347.3571167	0.10
349.3331909	4.44
354.3625488	0.09
355.1846313	0.07
357.5217285	0.01
359.4161377	0.25
361.3242798	0.08
365.3106689	1.97
367.4973755	0.03
371.1096802	0.70
372.2399292	2.35
373.2009277	1.47
384.4669189	0.06
385.2775879	0.07
393.4304199	0.49
395.3409424	0.11
397.1636353	0.08
401.4530029	0.63
405.5209351	0.05
411.2098999	0.04
415.1913452	0.12
431.4590454	0.06
441.4374390	0.23
445.3377075	100.00
446.6943970	0.04
447.3621216	0.44
449.2154541	0.06
450.2976074	0.05
458.1740112	0.07
459.2527466	0.37
461.1595459	1.17
461.7734375	0.03
463.4749756	0.04
465.2796021	0.04
467.2330322	0.21
471.3858643	0.22
473.8717651	0.10
477.7412109	0.06
479.2595215	0.06
480.4348755	0.09
485.2365112	0.63
486.4010620	0.04
487.3263550	0.12
489.2905273	42.69
489.9189453	0.05
502.6825562	0.37
503.3569946	3.46
505.2886353	0.06
507.3358765	4.65
517.1434937	0.36
522.3759766	0.08
531.0947876	0.41
533.1364136	0.03
534.1785278	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1107.5903
Annotation	Ginsenoside Rb1
Peak:m/z	Relative Intensity
1106.862061	61.69
1107.61084	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.29
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0767059	0.11
169.8812561	1.25
171.1447449	0.10
175.1225433	0.17
178.8876190	54.79
180.0718231	0.14
181.2117615	0.11
182.0741577	0.30
185.0248566	0.20
187.1126709	1.55
191.0816040	0.11
201.1737976	0.94
204.9207001	0.35
207.0369415	0.07
214.9260864	2.85
215.9379578	0.62
226.1480865	0.11
227.0436554	0.44
229.0859680	0.31
233.0317078	6.81
237.1872559	0.14
239.1859283	1.33
245.0200806	2.52
249.2724304	0.28
250.7079773	0.14
254.9354858	0.41
257.1199341	1.66
265.3814697	0.14
272.4385986	0.96
273.1392212	3.19
275.1662598	23.42
281.0646973	0.69
287.1852417	0.32
289.0538330	0.11
290.3504639	5.21
291.2607422	7.92
293.2150879	33.68
298.1694946	0.48
299.0305176	1.01
302.1576538	0.23
308.1448364	100.00
318.5673218	0.20
325.5488892	0.28
331.1443481	1.36
331.9783936	0.27
333.3438110	1.34
345.4055176	0.48
347.2901611	0.39
348.2904053	0.16
350.2092896	0.23
351.1954346	3.78
359.2617798	0.41
361.1833496	6.36
362.1785278	4.64
363.2912598	0.84
363.9609985	0.12
368.2319336	27.41
378.1750488	2.16
385.5921021	0.11
408.3435059	0.13
415.2116699	0.23
426.4777222	0.27
433.1006470	0.39
435.3106079	0.24
448.0515137	0.13
453.3024902	99.32
454.1804810	1.25
460.4697876	0.54
462.3449707	0.19
463.6038818	0.13
469.5939941	0.11
471.2738037	10.54
479.1904297	0.37
487.2186279	1.02
489.2719116	0.65
494.9301147	0.31
499.4651489	0.75
501.5051880	0.19
507.4977417	1.16
510.6373901	0.96
513.2487183	0.09
519.2470703	0.48
525.3378906	4.57
532.1481323	0.41
535.5323486	0.43
536.5083618	0.09
537.1897583	1.30
547.3236694	0.26
550.3827515	0.27
556.1716919	0.26
563.3394165	0.33
564.3897705	0.77
572.9000244	0.12
577.0463257	0.58
578.4569702	0.29
581.5181274	0.81
582.5442505	9.08
583.5430298	0.20
585.7798462	0.79
599.2366943	0.12
607.0742188	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1129.3008
Annotation	Furaneol 4-(6-malonylglucoside)
Peak:m/z	Relative Intensity
328.2794495	0.19
329.0932312	0.26
331.1603699	1.08
343.3539124	0.18
346.1159668	0.44
361.0787354	6.58
369.2658386	0.07
418.1783447	0.07
466.9348145	0.40
469.2642517	0.18
569.0506592	0.37
579.6099854	0.08
582.8902588	0.08
591.1270752	0.06
605.1540527	0.06
607.3055420	0.26
613.0422363	0.17
631.2067871	0.12
649.2119141	0.68
652.0283203	0.20
697.6463623	0.17
703.0103760	0.26
709.2931519	0.08
715.4664307	0.22
731.1555176	0.10
739.0858765	0.06
749.0543823	0.18
757.7386475	0.12
767.4328613	0.10
775.3381348	1.95
779.5212402	0.59
785.4829102	0.27
793.2844238	1.55
797.3780518	0.09
810.7478638	0.20
811.3542480	0.75
1111.1491700	0.39
1129.2249760	100.00
1130.1704100	12.64
1131.0402830	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Spinosin
Peak:m/z	Relative Intensity
195.0293274	0.06
215.2480469	0.02
227.3050079	0.04
255.1324768	0.03
261.1950378	0.04
269.3428345	0.02
275.4886475	0.06
283.2149048	0.06
286.1163330	3.50
301.1065674	66.58
302.1531982	0.09
303.0857544	0.43
311.2116089	0.03
313.1928711	0.12
314.9703064	0.06
325.3107300	0.01
327.3550415	0.01
328.1425781	0.03
331.2247314	0.03
341.4085083	0.03
342.2044678	0.14
343.2623291	0.17
345.0886841	0.13
360.5173950	0.17
361.2893677	0.53
367.1063232	0.21
384.3671265	0.02
387.0746460	0.14
387.7192383	0.03
391.2876587	0.03
392.7487793	0.03
396.9299316	0.10
397.7152100	0.02
411.1957397	0.32
427.2760010	0.14
438.3680420	0.02
445.2527466	0.33
447.1429443	0.39
463.0778809	100.00
463.7666626	0.15
471.2479858	0.02
505.5664673	0.06
528.1866455	0.04
536.4137573	0.09
541.4339600	0.03
543.2563477	0.07
555.1158447	0.22
564.6024170	0.03
565.7445679	0.04
573.3322144	0.27
590.7085571	0.17
591.4506226	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	971.322
Annotation	Alpha-cyclodextrin
Peak:m/z	Relative Intensity
837.0966187	5.78
969.989563	3.09
971.2921753	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.1642
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
205.1601257	0.11
243.3561401	0.03
248.1535034	0.04
267.2721558	0.06
271.3828430	0.03
307.7134399	0.15
308.3291016	0.07
311.9208374	0.01
313.2738037	0.32
314.1588135	0.14
315.3358765	0.02
319.3480225	0.04
325.2646179	1.41
326.2008057	0.13
335.3059692	0.02
337.1669922	1.72
338.2352600	0.47
349.1945190	0.11
351.3013306	0.04
352.9612427	0.02
355.2020264	3.22
356.2725220	0.75
361.2811279	0.11
362.0695190	0.03
366.7008667	0.09
370.5601196	0.08
374.0621948	0.02
374.7944946	0.06
375.4570312	0.15
379.1317139	2.61
380.1904907	1.41
385.1928101	0.04
391.1860962	0.45
391.9666748	0.08
393.4203491	0.02
397.3420410	0.10
403.4771729	0.37
404.1676636	0.22
409.1860352	3.52
410.2196045	1.04
415.2236938	1.20
421.1774292	3.12
422.2095337	0.67
427.1777954	0.24
428.3602295	0.16
433.6647949	0.11
434.3804321	0.09
439.1666260	2.76
440.1843262	1.25
442.4906006	0.10
444.6353760	0.12
445.3583374	0.48
446.2805786	0.13
448.5181885	0.01
451.8936768	0.20
457.1968994	56.22
458.2340088	16.28
463.0480957	0.15
469.2760010	0.31
470.4002075	0.02
475.1348877	2.57
476.2611084	0.71
481.2307129	0.82
482.3952637	0.19
485.4120483	0.08
487.5463867	0.12
488.2050781	0.02
489.4254761	0.06
490.4295044	0.05
492.7503052	0.29
493.3677368	0.69
494.2982178	0.48
496.0720215	0.15
499.3861694	0.52
501.3784790	0.20
502.0723267	0.07
505.1503296	0.45
506.2045898	0.18
507.0839844	0.07
511.1294556	1.64
512.3527832	0.54
513.1893311	1.01
514.1406250	0.46
514.7640991	0.02
517.3371582	0.15
518.7086792	0.45
519.4627686	0.68
520.3594360	0.03
523.2161865	2.06
524.3124390	0.51
525.1642456	0.56
526.2451782	0.26
527.1774292	0.03
529.0346680	0.54
530.2062378	0.15
531.1976318	0.89
532.3375854	0.47
535.1410522	0.02
541.3142090	0.91
543.1981812	9.70
544.2615967	3.03
547.2603760	0.33
549.4028931	0.04
550.6276855	0.02
553.1873169	1.25
554.3644409	0.49
556.4084473	0.05
559.2799683	0.39
561.1732788	27.33
562.2922974	7.70
565.2972412	1.04
566.4643555	1.06
567.2833862	5.17
568.2625732	2.58
571.2810669	0.09
572.4284058	0.05
573.0507202	0.02
574.4432983	0.19
577.2872314	0.20
578.3619995	0.23
579.2487183	0.59
580.3646240	0.12
583.3412476	0.74
585.1754150	11.70
586.3068848	4.30
591.3023071	0.25
592.3875122	0.20
593.0184937	0.08
597.1985474	20.85
598.2833252	7.11
601.1136475	1.15
602.1751099	0.52
609.2771606	9.02
610.2349243	3.74
610.8457031	0.03
615.1618042	15.40
616.2676392	5.73
619.2635498	0.92
620.2280884	0.57
627.1912842	15.42
628.2758179	5.04
629.4065552	0.04
645.2034302	36.72
646.2125244	11.61
646.8794556	0.07
649.2446899	0.01
663.1858521	100.00
664.2460327	35.45
682.1724243	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	815.409
Annotation	Unknow
Peak:m/z	Relative Intensity
228.5391235	0.09
232.1858826	0.19
245.1875305	0.23
260.1768494	0.14
262.3098450	0.29
265.7253418	0.05
269.0940552	0.04
275.2406311	0.03
278.2584229	1.20
278.9836121	0.09
287.4180603	0.11
293.6431885	0.09
295.3563232	0.19
297.1942749	0.08
300.0167236	0.05
302.1796875	0.11
306.9277344	0.09
308.1703491	0.03
309.1648560	0.03
310.2954712	0.02
314.1151733	0.12
315.1704712	0.02
316.2825317	0.08
316.9711914	0.06
317.6445312	0.02
324.1841431	0.46
327.3317261	0.03
330.2445068	0.17
335.1460876	0.49
340.0438843	0.06
342.1735840	2.89
345.3529663	0.04
348.2312622	0.08
354.5958252	0.03
355.3388367	0.08
356.1452026	0.08
358.3757019	0.02
359.2176514	0.28
360.4714966	0.14
361.1445923	0.54
363.0205994	0.03
368.4355469	0.07
371.4125061	0.15
373.6122131	0.03
374.3374329	0.17
376.3213501	0.08
379.5703735	0.17
381.3096924	0.20
385.3965454	0.12
387.3765869	0.03
389.2353516	0.09
392.1422119	0.90
392.7820435	0.08
395.4818115	0.04
399.1886597	1.72
403.4257202	0.15
404.3558960	0.08
409.3856812	0.82
410.1724243	0.04
412.3328247	0.09
414.4694214	0.02
416.4705811	0.10
417.2615356	0.07
419.3117065	0.03
424.0649414	0.05
426.7864990	0.21
427.7444458	0.08
428.5301514	0.15
429.2660522	0.32
430.5427246	0.10
436.9255981	0.07
438.3406372	0.03
440.2326660	0.17
442.3006592	0.61
444.2575073	0.17
446.4744263	0.16
448.4129639	0.08
450.6629028	0.12
455.6739502	0.65
456.3860474	1.82
457.1270752	0.20
458.3814697	0.40
461.6012573	0.04
462.2346802	0.03
463.3631592	0.06
465.5679932	0.03
471.5187988	0.05
472.1362915	0.02
473.3434448	1.24
474.3102417	0.39
477.2738037	0.56
482.6439819	0.13
484.1791992	0.18
488.0347900	0.15
489.5684204	0.16
490.3275146	0.10
492.4967651	0.02
493.5366821	0.02
494.5968628	0.15
495.2644653	0.02
496.3125610	0.08
502.6333008	0.02
506.1541748	0.79
507.4547119	0.15
508.3147583	0.35
509.0813599	0.02
509.6983032	0.10
511.3565674	1.27
512.5421753	0.50
513.4470215	0.16
518.5242920	0.41
521.5703125	0.24
523.5686035	0.33
526.3236084	0.02
532.5650024	0.22
534.5120239	0.03
536.0756836	0.06
538.0077515	0.12
539.4421387	5.86
541.3717041	1.06
543.5685425	0.02
548.4809570	0.03
555.3109131	0.42
556.0509644	0.04
557.4963989	0.92
559.3276367	0.07
567.3316040	0.02
568.4884033	0.04
569.4137573	0.35
571.6636353	0.05
575.4475708	3.65
576.5316772	0.16
577.4307251	0.29
579.3504028	0.03
585.4750366	0.16
586.8270264	0.35
587.7693481	0.39
589.6027222	0.06
593.5369263	0.30
594.3668823	0.04
597.5007935	0.02
601.4550171	0.10
603.3985596	11.99
604.7300415	0.72
605.4125977	0.77
609.9153442	0.28
610.5906982	0.79
611.6622314	0.09
613.1748657	0.04
615.7429199	0.03
618.7387695	0.08
620.4139404	0.52
621.4202881	0.25
622.5067749	1.09
623.5765381	0.07
624.6355591	0.06
626.3629761	0.06
631.4234009	0.11
632.8535767	0.02
634.5441284	0.43
636.4596558	0.28
637.7601929	1.50
638.3867798	14.17
639.6553345	0.06
650.3168335	0.09
652.4409180	1.55
654.4188843	1.33
656.4631348	0.03
658.8427734	0.05
664.4440918	0.02
668.3709717	0.70
671.4242554	0.19
674.4988403	5.42
678.5455933	0.12
682.4249878	0.07
684.5051880	0.68
686.5722046	0.88
688.3509521	0.12
689.4363403	0.08
690.5143433	0.81
694.3104248	0.29
698.5930176	0.84
700.4140015	0.75
702.4088135	49.86
703.1036987	0.22
704.7968750	0.05
705.6607666	0.06
706.7266235	0.05
707.7587280	0.37
709.3109741	0.09
711.5068970	0.10
715.8563843	0.25
716.5958862	2.32
718.4284058	1.55
723.4328003	10.61
724.4812622	0.07
726.2359009	0.10
728.6612549	0.21
733.5906982	3.72
742.4385986	0.19
749.6754150	0.05
751.4922485	74.42
752.2772827	0.28
753.5903931	0.07
758.5916138	0.35
769.5602417	0.90
770.4487915	1.20
771.4677734	0.44
779.5789795	0.03
780.5640259	0.26
787.6042480	30.75
795.2115479	0.02
797.5036621	5.73
800.0878296	0.25
800.7011719	0.04
815.4668579	100.00
816.2590942	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1726
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
190.9762573	0.05
203.1536560	0.15
244.1162720	0.12
257.1099243	0.13
284.2649536	0.28
301.0000000	0.07
305.2046509	1.85
315.0801392	0.28
325.3561401	0.47
326.1694946	0.41
329.2028809	5.48
330.1908569	1.55
337.1828308	0.12
343.1001587	0.59
344.1536255	12.14
345.2753296	5.72
350.9102173	0.52
357.4215698	0.56
359.1834717	44.01
359.9530029	0.05
361.1859741	0.09
366.1068726	0.18
369.1405029	0.10
381.1923218	0.13
385.7013550	0.80
386.7343140	0.50
389.2633667	0.07
399.2763062	0.09
401.2043457	3.39
415.2592163	0.08
443.1670532	0.58
471.4592896	0.14
489.5047607	0.36
491.1035156	0.10
501.1985474	0.10
503.0953979	1.78
506.5260010	0.99
507.2277832	2.61
508.2847290	0.27
521.2882080	100.00
522.2058716	0.31
530.3974609	0.13
534.4412231	0.48
535.4242554	0.21
549.3034058	7.45
563.3320923	62.76
578.9754028	0.24
580.8624878	0.23
589.3511353	0.57
591.2861938	0.95
603.1978149	3.84
604.4324341	0.65
606.7035522	0.12
613.8884277	0.21
615.2829590	4.61
618.7401123	0.43
619.5989990	0.25
620.3759155	0.46
621.5673218	0.28
622.6727905	0.30
623.4710083	0.43
628.1311035	0.36
633.1879272	0.89
647.3438721	1.16
650.2481079	0.67
665.1083374	4.06
665.9812622	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	592.27
Annotation	Unknow
Peak:m/z	Relative Intensity
213.3140259	0.05
269.4020691	0.03
372.5102539	0.04
386.4380493	0.10
388.4039917	0.06
389.1553955	0.06
400.2137451	0.05
433.4183350	0.16
446.4465942	0.25
447.2917480	0.31
459.4288330	0.81
460.7520752	0.76
461.5320435	1.35
462.5343628	0.25
463.1850586	0.15
471.6926880	0.04
473.3600464	2.04
476.4759521	0.32
477.6197510	0.19
487.3717651	1.02
488.5889893	0.07
489.3352661	0.19
491.2786865	0.88
492.4067993	1.27
493.4701538	0.18
500.5417480	0.08
502.3789062	0.04
503.4037476	0.16
504.4304199	0.04
505.6689453	0.24
506.7192993	0.13
515.3190308	1.43
516.3203125	0.18
517.4235229	0.19
518.3943481	0.08
519.2979736	0.88
520.4919434	0.40
531.7654419	0.35
533.3480835	100.00
534.1666870	0.35
543.5657349	0.29
546.6508179	0.14
547.5082397	2.48
548.2487793	0.05
550.4181519	0.11
551.5538940	0.15
557.2813110	0.04
560.7451782	0.51
561.5579224	1.27
564.3812866	2.17
565.4514771	1.99
575.5504150	2.56
578.1499634	0.38
578.7621460	0.01
593.4231567	78.47
594.0844727	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1116.32
Annotation	Unknow
Peak:m/z	Relative Intensity
316.0260925	0.22
317.9781799	0.07
326.8424072	0.08
330.4571228	0.56
331.1718445	1.78
332.2368774	1.54
333.2451172	1.21
346.1499939	0.26
347.0905151	0.42
348.2615356	0.31
361.1275024	9.70
362.2166138	4.93
363.2727966	4.84
373.2442627	0.07
387.2083130	0.24
393.1480713	0.03
400.1270752	0.05
407.1151123	0.06
411.2980347	0.28
412.2706299	0.19
422.3835449	0.17
451.2593994	0.34
452.2778931	0.42
458.2215576	0.26
461.3833618	0.22
469.1391296	0.34
470.1336670	0.54
471.3458557	0.15
477.6522827	0.15
491.2023315	0.03
535.0742798	0.07
565.2219238	0.09
567.3132324	0.05
580.4547119	0.18
605.7786865	0.20
606.4220581	0.09
607.1280518	0.11
609.2565918	0.37
619.1141357	0.20
632.8182983	0.39
649.3243408	0.27
650.5017090	0.97
651.2142334	0.12
668.1353149	0.58
669.1105957	0.18
674.1895142	0.10
681.4086304	0.08
683.4403076	0.09
699.2114258	0.22
700.1242676	0.27
710.3245850	0.15
711.1459961	0.81
717.3703613	0.10
721.1633301	0.15
735.1107178	0.57
737.2536621	0.09
745.7733765	0.08
746.4098511	0.25
747.0542603	0.14
752.9348145	0.43
758.3058472	0.19
759.3734131	0.82
765.3543701	0.21
769.1389771	0.12
770.4909668	0.50
771.4749756	0.39
774.8449707	0.06
775.4910889	0.40
776.3363037	2.12
776.9529419	0.60
777.5740967	1.89
782.8840332	0.49
783.4866943	0.25
793.0994873	0.72
794.1835327	1.02
795.2243652	1.22
795.8460693	0.02
811.3620605	0.70
812.4342041	1.91
813.1647949	2.03
885.5148926	0.13
929.1248779	0.11
935.6368408	0.19
1007.6749270	0.04
1061.4665530	0.15
1078.9050290	0.17
1097.0833740	0.08
1115.1596680	100.00
1116.2708740	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	725.2268
Annotation	Troxerutin
Peak:m/z	Relative Intensity
224.9777527	0.11
228.9816284	0.30
238.9013672	0.05
244.2093201	0.12
268.1666565	0.20
271.0812378	97.75
272.0467529	19.70
273.2211304	0.09
275.1142578	0.05
283.2066956	0.32
295.2915955	0.10
296.2633057	0.11
308.1018677	0.06
313.1936035	0.57
331.2021484	0.06
333.1099243	0.03
337.2382202	0.37
338.1879272	0.36
351.3664551	0.12
361.1890259	0.25
362.3583984	0.05
363.2353516	0.12
364.1630249	0.18
366.9878540	0.10
369.7102661	0.13
375.4788818	0.10
381.2770996	0.87
382.1380005	0.61
397.4515381	0.08
399.2973633	0.79
409.2129517	0.05
415.2542725	0.24
417.2910767	1.65
418.3260498	0.71
429.1828613	0.04
433.1177368	6.83
434.2203369	1.92
459.3447266	0.19
475.5380249	0.31
476.3610840	0.36
489.3850708	0.23
490.4296265	0.20
506.3161011	0.29
515.2850952	0.67
526.1835938	0.05
526.8663330	0.10
529.6235962	0.07
541.3355103	0.07
543.2385254	0.49
544.0791626	0.35
551.4553833	0.28
561.3109131	0.45
561.9902344	0.05
563.0454712	0.53
564.2391968	0.22
567.8441162	0.14
570.2822876	0.21
576.4439087	0.20
579.0958862	100.00
580.1365967	28.93
580.7709351	0.17
603.9175415	0.12
618.4562988	0.08
621.2442627	0.51
635.9266968	0.03
649.5480957	0.45
650.3571167	0.06
665.6991577	0.09
667.8928833	0.20
671.3151855	0.23
688.7257690	0.09
689.5656128	0.05
694.7402344	0.04
707.2918091	0.74
708.4006958	0.35
726.1795044	2.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0985
Annotation	Glochidionolactone A
Peak:m/z	Relative Intensity
107.1077271	0.15
108.8811035	0.14
129.0808258	0.54
132.9918823	0.11
134.9628906	0.09
146.9949646	1.38
148.8945160	0.06
151.0007019	3.60
151.8548584	0.46
161.0209351	0.45
163.9795837	0.10
166.8214111	0.11
167.8636475	0.15
171.2507019	0.23
172.1770325	0.08
172.9895477	1.32
175.0572662	0.24
179.0927582	0.10
181.1534119	0.08
182.7529907	0.12
184.2789612	0.06
185.2304993	0.48
191.0019531	11.60
196.0164795	1.74
197.0859680	0.85
198.2526245	0.07
207.0519714	0.07
208.2152252	0.07
209.0845337	0.80
209.8992310	0.12
211.2258606	0.25
213.1101990	0.36
224.2265930	0.05
226.0150452	0.08
227.1745911	0.09
229.0190735	0.11
232.8559875	0.08
237.8113403	0.20
239.1953430	0.94
241.2395020	0.07
263.0251465	0.23
268.0188904	0.83
269.1156616	0.37
271.1092529	0.32
274.9710083	0.09
277.9118652	0.19
281.1441040	0.52
282.9723816	0.30
297.2778931	0.04
299.1325378	1.12
305.2243652	0.28
311.1683960	0.05
313.0605164	100.00
313.6923828	0.25
314.9129944	0.52
323.1681519	0.13
330.2388916	0.06
340.0354614	0.09
341.1088562	3.46
344.1546326	52.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.2122
Annotation	9,10-EpODE
Peak:m/z	Relative Intensity
84.8933487	0.28
94.8856125	0.76
96.9035111	0.79
106.8929901	0.16
109.0132675	1.46
111.0102997	0.88
113.0197983	4.48
121.0644531	0.19
123.0160370	0.71
125.1944885	0.15
127.0127487	0.16
130.9262695	0.22
135.2120972	0.15
137.0433044	0.09
139.0469055	0.68
141.0715485	0.64
146.9594421	0.07
149.0291443	1.03
149.9432068	0.44
151.2871399	0.35
153.2682190	0.43
155.1466370	0.89
159.0535889	0.10
161.2406616	0.14
162.9773254	0.19
165.2188110	0.58
167.0716858	1.25
169.2013092	0.99
171.3995667	0.15
175.1726990	0.18
177.1594543	2.66
179.1194458	24.85
181.1629028	4.93
183.2173615	0.38
191.1464996	0.50
193.2342529	0.16
195.1080933	63.93
196.1139832	21.40
197.2739563	1.30
205.1744690	30.73
207.0803833	1.70
209.1360168	0.13
221.2183838	0.54
223.1662903	17.91
224.1672058	24.92
225.2054443	1.30
229.3688660	0.17
231.2457886	6.71
232.2007751	0.09
233.2650146	4.01
237.3699341	1.13
239.2082520	3.49
247.1008606	1.62
249.3131714	16.89
251.3158569	1.55
257.4068298	2.06
265.2850952	10.37
273.3156738	1.07
275.2991028	100.00
276.4998779	0.20
293.3624268	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3715
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
283.3727417	3.89
599.1137695	3.74
609.383728	8.75
641.4113159	14.23
683.4879761	14.58
803.3545532	100.00
804.0040283	8.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	265.093
Annotation	8-Oxodeoxycoformycin
Peak:m/z	Relative Intensity
83.1632843	0.52
84.9081268	10.40
86.8683624	1.93
88.9076386	17.76
94.7780914	2.57
98.9291382	1.30
100.8517075	25.30
102.9560394	100.00
104.0404968	0.24
106.7978363	1.49
110.9985352	0.21
112.9716949	26.93
114.9532013	0.23
116.9614868	1.71
118.8822784	19.62
122.8556366	0.16
124.8791809	1.06
126.9438171	0.62
128.9088287	0.75
130.8354340	6.04
135.8480988	0.33
142.9950562	6.90
144.9918365	9.98
146.9176178	0.97
148.8834381	2.73
156.9909821	1.84
158.9946136	0.29
160.9824066	2.62
165.0685272	0.61
173.3182526	0.50
174.9909668	4.48
178.9031830	7.82
191.0894012	2.25
205.0578156	0.77
219.0833893	1.37
221.0661926	2.76
236.6498871	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.1562
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
113.0025177	0.45
115.9856491	0.63
118.9421463	0.81
127.9408722	0.49
128.7176514	0.09
130.6089172	0.23
142.1681061	0.12
142.8611298	0.21
145.9825897	67.00
146.9626160	5.80
150.9847717	0.11
159.0055237	0.17
161.0271606	1.46
161.8657837	0.06
168.9253540	1.56
173.1080933	0.75
174.0970154	0.70
175.2125702	0.14
179.0873260	0.21
180.8735352	0.11
182.9850311	0.24
198.2150269	0.11
200.0326385	2.84
201.1326141	0.97
215.2494202	0.10
218.0561676	6.34
219.2530518	0.18
242.0504150	0.52
243.0901184	0.22
245.3467102	0.07
254.4701538	0.16
257.2123413	0.23
260.2273254	1.90
261.0245056	0.85
263.0810547	3.04
264.1986389	0.37
265.1456909	0.79
272.2612915	0.99
274.1311646	0.19
283.3225098	0.35
290.1201477	18.22
291.2526855	2.28
299.1048279	0.11
301.1724854	0.09
308.1458740	60.46
309.2054443	7.19
314.2510986	0.10
315.3002930	0.05
335.1882019	1.59
344.3806152	0.20
345.2868958	0.21
362.2243958	100.00
363.2931519	17.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2141
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
256.1017151	0.03
266.8745422	0.03
271.1537170	0.76
272.0820923	0.02
280.9474792	0.04
284.6261597	0.16
285.2714539	0.29
286.3586731	0.03
287.2722778	0.03
298.0698853	0.18
299.0789185	2.38
300.0688477	0.18
305.1348877	1.26
312.2739258	0.44
313.0501099	1.43
314.1176147	10.27
315.1103821	1.12
322.9533081	0.20
327.1844482	0.51
329.1232605	40.93
330.1788330	2.68
335.3153076	0.15
336.3135376	0.14
337.1104126	0.09
339.2207642	0.39
341.2920227	0.24
342.2608032	0.01
343.3143311	0.10
351.0939331	0.22
355.1042480	0.02
356.2801819	0.08
356.9430542	0.02
367.2346802	0.04
368.2599487	0.09
371.1582031	6.90
372.2592773	0.23
380.2718506	0.08
381.3807373	0.12
395.3051147	0.32
395.9939575	0.11
401.2203369	0.10
407.4288940	0.03
413.1864624	0.71
414.3543701	0.03
417.2218018	0.03
436.9504395	0.08
447.3952637	0.03
450.1234741	0.04
453.5284424	0.06
455.1722412	0.14
459.1360474	0.08
473.2028809	0.57
474.3146973	0.08
476.1560059	0.53
477.4537964	0.28
491.2634888	100.00
492.2611084	10.31
505.1673584	0.61
518.3015137	0.24
519.3744507	0.16
533.2555542	46.59
534.3493042	5.08
555.5347290	0.03
556.6223145	0.09
563.0001831	0.59
573.2076416	17.09
574.2809448	2.46
575.1488647	1.32
576.5044556	0.09
590.7764282	0.04
599.1129761	0.02
605.4397583	0.04
606.1521606	0.04
617.3920898	1.80
618.3414917	0.16
635.1139526	30.99
636.1475220	1.99
639.3791504	0.12
645.5480347	0.06
653.2452393	11.83
654.3914185	1.01
657.5398560	0.07
661.7005615	0.20
675.5901489	0.05
677.2379761	0.40
681.2999268	0.04
689.1928711	0.06
695.1954956	0.08
706.9909668	0.29
707.5915527	0.18
719.7287598	0.06
735.2892456	0.04
736.8695679	0.11
738.4340210	0.06
743.1606445	0.08
752.4808960	0.05
753.3807373	0.05
755.1079712	0.05
756.6403198	0.13
762.5025024	0.04
766.8601685	0.22
779.3507080	0.07
780.5046997	0.04
798.2767944	47.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1752
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
179.0388641	0.05
189.4577179	0.02
202.0210266	0.09
221.2185059	0.07
233.0217438	0.05
254.1574249	0.04
270.0417480	0.10
272.3037720	0.07
276.1618042	0.14
283.3500366	0.08
286.3069458	0.08
301.0549927	3.54
308.2618103	0.06
311.1762695	0.03
313.1374512	0.98
315.1928101	0.02
316.0384827	0.14
317.1788330	0.22
318.1792603	0.05
319.4482422	0.16
322.1493530	0.03
325.1621704	1.00
327.1367188	0.06
338.1655884	0.05
339.2975464	0.16
341.0289307	0.41
343.2153931	9.81
355.5666504	0.02
358.3179321	0.05
359.2998657	0.52
362.4106445	0.03
366.0843506	0.04
367.2155762	5.02
371.2490234	0.08
376.3377075	0.32
377.1885986	0.19
379.3803711	0.10
381.3854370	0.10
383.3172607	0.18
384.9969482	0.19
386.1411133	0.11
390.4484253	0.26
391.5297241	0.03
397.2175903	6.18
399.4783325	0.14
400.2077637	0.04
403.6228027	0.06
409.0930786	3.64
409.7876587	0.19
412.8763428	0.18
421.0145874	0.05
426.6417236	0.11
427.2447510	5.60
439.2642212	1.24
443.2070923	0.39
445.1658936	24.31
445.7910767	0.12
451.2206421	0.14
453.3092651	0.29
456.2940674	0.03
457.1817017	0.73
460.7637329	0.27
461.5013428	0.49
463.1823120	100.00
463.8558350	0.27
466.9364624	0.07
468.6159058	0.08
469.2781372	0.10
473.1383667	0.02
475.1708984	0.32
477.0393677	0.04
479.2678833	2.49
481.4179077	0.05
483.2054443	0.09
485.8919678	0.07
487.1950073	14.86
492.2091064	0.03
494.3828125	0.10
495.2811279	0.06
501.2444458	0.08
504.1519775	0.12
505.1710815	6.53
510.2377930	0.06
511.3096924	1.65
512.4454956	0.05
519.2710571	0.16
523.2957764	0.04
528.6143188	0.13
529.2832642	4.21
534.2958374	0.08
535.3642578	0.12
536.3860474	0.16
539.3872681	0.04
541.2449341	5.20
543.5131836	0.12
544.1698608	0.21
545.4074097	0.12
547.2850952	0.10
553.2582397	2.32
559.2341919	9.62
563.2671509	0.22
565.1660156	0.02
566.0006104	0.20
571.2094727	4.99
578.5529785	0.03
580.4624023	0.38
581.2890625	0.21
583.3429565	0.04
589.1776733	13.06
607.2239990	49.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1981
Annotation	Agnucastoside C
Peak:m/z	Relative Intensity
208.0601501	0.06
231.0330811	0.04
240.1855469	0.04
242.2245178	0.02
243.0270996	0.06
257.0687561	0.05
268.9638977	0.07
271.0485840	0.06
299.2821045	0.04
300.1170044	0.08
301.1863403	0.06
308.0938721	0.01
311.1264954	0.22
312.3196411	0.05
313.1881714	0.12
314.4229126	0.05
315.2762451	0.14
316.2397461	0.05
324.1019897	0.02
325.1524048	0.31
326.0342407	0.05
326.7824707	0.10
328.3291016	0.39
329.1235962	0.32
330.2254639	0.30
332.1811523	0.03
337.2213135	0.18
339.3403320	0.06
339.9577026	0.01
341.0970459	0.03
341.8049927	0.03
343.1816711	4.47
344.1941528	1.62
345.1884766	1.45
351.9496460	0.01
357.2439575	0.12
358.1303101	0.85
359.1562500	1.67
359.8011475	0.07
370.7422485	0.02
372.9551392	0.04
374.2138672	0.01
386.3336182	0.02
387.3791504	0.01
401.2244263	0.11
417.3058472	0.02
431.2600708	0.06
442.0436401	0.06
457.2609253	0.05
463.3052368	0.08
475.2761230	0.09
487.8720093	0.03
490.4691162	0.08
502.8319702	0.04
515.5452271	0.10
521.2496338	0.09
538.3320923	0.02
539.5404663	0.02
558.4719849	0.03
562.2056274	0.03
581.2783813	0.04
596.3478394	0.04
597.4103394	0.04
602.3221436	0.11
606.6959229	0.04
607.3497925	0.03
609.2648926	0.05
610.0214233	0.19
611.2050781	0.12
611.9908447	0.02
622.5648804	0.14
624.3909912	0.02
636.2891846	0.12
637.4194336	0.60
638.2561035	0.47
639.3455200	0.11
646.3252563	0.07
647.4101562	0.06
650.3989868	0.22
651.3709106	0.11
653.3518066	7.02
665.4023438	1.39
668.2780762	100.00
669.1181030	0.57
683.3237915	31.23
684.3937378	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	506.2016
Annotation	Alangiside
Peak:m/z	Relative Intensity
161.8956299	0.05
163.2869568	0.02
167.1264648	0.02
174.8878174	0.03
176.8373413	0.08
177.7203674	0.04
189.2890625	0.01
202.0018463	0.06
213.0547791	0.01
223.2867432	0.03
229.0853577	0.05
233.0888672	0.01
252.9006042	0.03
254.0441284	0.02
259.2775879	0.01
262.9732056	0.03
270.7306824	0.01
284.9010010	0.02
292.3426514	0.01
293.1935730	0.05
295.9885254	0.02
300.4441528	0.02
312.3710327	0.03
313.1487732	0.02
326.1463013	2.42
330.0007629	0.03
338.7170410	0.04
344.3350220	0.03
357.9380188	0.04
359.3564453	0.03
376.0358276	0.07
377.2063904	0.07
384.1106873	0.03
398.0771179	0.07
405.2955933	0.02
417.1304626	0.02
426.1376953	0.03
429.4578552	0.02
431.1881409	0.01
438.3220520	0.02
441.3234863	0.09
442.1543884	0.03
446.4604797	0.04
448.2181091	0.10
452.2810059	0.03
453.3465881	0.05
461.2479553	0.19
471.6741028	0.08
475.3118286	0.02
477.2453308	0.05
478.2171021	0.04
488.2075500	100.00
488.8437805	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2625
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0574493	0.02
152.8664246	0.14
179.9969025	0.06
191.2761383	0.01
196.0311279	2.76
197.0816650	0.14
205.1825104	0.01
207.3050232	0.01
214.0133972	1.73
215.0309753	0.09
233.3441467	0.81
234.2694244	0.07
241.2200317	0.02
246.9840698	0.04
257.3620911	0.08
258.0563660	0.01
259.2194824	0.41
260.1773376	0.20
261.2203064	0.05
275.3341370	0.53
277.2541199	100.00
278.2326050	18.23
278.8627625	0.02
313.2076416	0.02
314.1923218	0.03
329.4476624	0.01
379.2590027	0.06
384.8575439	0.02
413.3289490	0.23
414.3942566	0.05
421.4533386	0.07
429.1836853	0.01
457.1203003	0.01
460.2510071	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.3127
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0581970	0.13
207.1548004	0.12
233.0817871	0.15
235.1317139	0.98
243.0028687	0.21
251.2924042	0.04
253.1347046	9.37
259.3280945	0.18
267.2960815	0.04
275.4320984	0.14
277.2845459	100.00
288.4487305	0.17
305.2764282	0.05
327.4768677	0.05
333.3339844	0.03
341.3580933	0.12
374.2531738	0.05
377.2190552	0.03
385.2322388	0.07
422.8491821	0.14
445.5945435	0.05
467.0401001	0.07
477.2351074	0.03
491.3027954	0.04
499.3921509	0.05
511.0908813	0.04
513.1823120	18.52
517.6726685	0.07
521.2075806	0.54
527.5487671	0.15
541.3248291	0.05
543.7195435	0.03
560.3235474	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	274.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8658218	5.60
115.8502197	2.00
116.9495239	2.78
126.8942108	0.03
131.0222778	0.51
132.8791199	0.15
148.8737946	0.07
158.9061584	100.00
159.9315643	43.89
160.9220581	65.31
198.8974304	0.34
199.9476318	1.71
200.9757385	3.49
216.8932190	0.04
217.9646301	0.37
219.0069275	1.13
228.0369263	0.06
228.9474182	1.05
229.9071960	16.77
230.9034729	34.58
242.0733032	0.05
246.1007996	0.27
246.9445190	0.76
259.3287964	0.09
274.7813721	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.2299
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
217.0222473	0.11
227.0613708	0.08
235.0366058	0.22
243.0565186	0.04
253.0112915	0.02
258.9197083	0.13
271.1315918	6.71
272.0878296	1.18
278.2803345	0.06
279.0704346	0.21
295.1572266	0.30
296.0478821	0.31
297.0795288	0.29
298.2371826	0.09
311.0775146	0.11
312.7495728	0.11
313.3577881	0.95
314.2401733	0.08
315.1571045	0.52
316.3735352	0.02
325.1398315	0.19
326.2199097	0.10
337.1657715	0.07
339.1732788	3.43
340.2764893	0.26
343.3504944	0.04
353.3316040	0.03
355.3944092	0.04
356.1654053	0.06
357.2638550	2.04
358.0725098	0.42
362.9240112	0.06
381.1251831	0.10
382.1018066	0.03
399.3059082	0.11
405.5018311	0.09
415.2534790	0.04
417.2586060	0.17
418.4793701	0.08
423.3342285	0.22
424.2557373	0.11
441.1510620	0.28
441.9636841	0.05
443.3895874	0.04
459.2738037	3.77
460.2605591	0.64
477.2266235	0.40
505.4281616	0.03
518.9633179	0.03
561.2017212	0.13
562.5041504	0.29
569.3043823	0.11
570.1514282	0.11
579.3570557	1.23
580.3516846	0.25
587.2286377	1.46
588.2931519	0.54
605.3048096	100.00
606.2848511	23.59
606.9245605	0.03
619.2800903	2.34
620.4243774	0.30
631.0884399	0.15
632.3309937	0.05
707.4692993	0.16
726.3372192	59.71
727.0169067	0.23
727.6621704	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1328
Annotation	Oenin
Peak:m/z	Relative Intensity
327.0926514	0.01
331.1721191	1.01
332.2139282	0.43
343.1927490	2.86
344.2809753	1.20
355.1704102	2.25
356.2337952	1.00
365.1879883	0.03
367.0257263	0.02
368.0614319	0.05
369.2170105	0.09
370.1049194	0.02
373.1707153	44.72
374.2512207	16.80
384.5314636	0.03
385.5181580	0.06
397.2075195	10.19
398.2340393	4.14
399.3585205	0.01
403.3142395	0.76
404.3656311	0.22
409.1217957	0.39
410.2456360	0.18
411.2796631	0.06
412.2793274	0.08
415.2547607	0.33
416.6282654	0.16
420.8794861	0.02
427.1762390	5.77
428.2431946	2.87
431.1257019	0.01
439.1886902	2.49
440.2891541	1.35
457.1832275	13.67
458.2767944	6.79
475.2338257	100.00
476.2347107	36.59
476.8457642	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.06
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.9672356	0.33
70.9264450	2.95
73.0119782	0.50
74.8903275	16.10
80.8864822	8.66
86.9060974	5.41
88.8670883	3.02
96.9826202	1.37
98.9130859	29.23
100.8922272	0.46
103.0083313	0.05
113.0085449	0.54
114.9636993	0.79
116.8738861	0.54
119.0307617	0.92
125.0115814	8.63
128.9515228	0.15
130.8911285	0.78
132.9463654	1.02
141.0586090	0.18
142.9752045	100.00
144.1105804	0.25
148.7604218	0.04
150.9113007	0.16
158.8297577	0.27
160.9141846	77.47
163.9930267	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.66
Annotation	Unknow
Peak:m/z	Relative Intensity
168.8715210	0.05
204.8998413	0.01
213.2187958	0.07
217.0429230	0.07
217.7841492	0.01
222.7297821	0.03
235.2967834	0.03
243.9725342	0.03
253.9530182	0.10
270.9730225	0.17
272.2018433	0.04
298.2681885	0.03
308.2954712	0.03
313.2092590	0.03
326.4082642	0.01
328.1067505	0.21
331.0971069	0.54
331.9216309	0.10
343.2296143	0.04
345.0311279	0.01
346.1812744	0.52
347.2128296	0.26
361.1601562	100.00
362.1049194	13.83
363.2362671	0.09
380.3670654	0.04
387.2194214	0.02
389.1389771	0.03
397.1666260	0.02
403.2073364	0.03
405.1334229	0.02
405.8424683	0.03
410.2980957	0.05
411.8344116	0.15
415.3287964	0.05
423.3173218	0.01
427.3419189	0.03
451.3658447	0.61
452.2805786	0.07
455.1934814	0.01
457.0700073	0.02
465.3901978	0.10
469.0721436	0.90
470.2636108	0.19
480.2849121	0.02
487.2076416	0.06
505.0202026	0.13
507.4809570	0.04
510.9550171	0.04
514.6235962	0.09
523.2983398	0.21
533.2734985	0.06
543.3858032	0.03
550.6504517	0.07
561.2802734	0.05
563.2726440	0.05
568.3303833	0.07
569.3830566	0.04
570.9367065	0.03
605.2213745	1.41
606.2594604	0.16
606.8807983	0.10
607.4890747	0.09
608.1703491	0.04
613.0330200	0.24
631.1163940	0.37
631.9356079	0.09
649.2304077	3.58
650.1430664	0.68
653.1522827	0.01
667.2672729	1.31
668.3506470	0.18
695.1694336	0.07
703.3900757	0.01
709.3691406	0.23
713.0162964	0.03
739.3677368	0.48
740.3220825	0.06
743.1787109	0.02
757.1940308	0.38
758.2138062	0.07
759.3530884	0.02
775.1862183	9.62
776.3323364	2.48
777.1967163	0.03
793.1199341	5.02
794.2560425	1.76
795.3356323	0.02
811.1936035	3.14
812.3837280	0.89
813.2814331	0.09
863.3029175	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.08
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9391479	0.31
113.0958710	0.04
128.9070435	1.34
132.8408508	0.14
133.8767242	0.12
144.6971436	0.20
147.0209656	4.05
149.1119232	0.35
152.8055725	0.09
162.0635071	0.39
164.0367737	0.50
173.0092163	1.92
176.9729614	1.69
177.9500122	0.12
190.9249268	100.00
193.0694733	1.35
205.0986023	3.43
207.1679535	0.11
209.0698853	13.95
220.9659119	0.10
223.0539246	4.35
232.0771179	0.44
232.9694519	0.05
236.9701233	0.07
246.9672546	2.00
259.1365662	0.13
261.3561401	0.06
263.2396240	0.22
265.1237488	0.44
277.1840820	0.16
295.2861023	0.09
322.7514038	0.07
325.3394775	0.04
340.8701782	0.10
349.1117554	0.33
367.0964355	8.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.1955
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
222.6476746	0.13
245.2008667	0.15
316.0706177	0.33
326.4759216	0.06
328.2429504	0.43
329.3001404	0.37
331.2943726	0.55
332.2189331	0.71
346.2185059	0.80
346.9617310	0.59
361.1873779	55.97
362.2716675	20.21
365.9301758	0.06
374.2770996	0.11
375.8914185	0.27
395.0167236	0.11
401.3435669	0.10
420.3856201	0.07
437.1516724	0.17
438.5319824	0.12
441.3839111	0.53
474.3524780	0.13
475.5593872	0.18
476.3962402	0.05
477.1181030	0.09
498.5577393	0.07
502.0119019	0.12
503.3009033	0.11
505.2518311	0.12
511.4525757	0.07
515.0606689	0.05
521.3975830	0.07
523.1010132	100.00
524.2056274	40.95
529.5180054	0.22
534.1634521	0.13
540.3162842	0.17
553.3551636	0.13
566.3815918	0.12
570.2523804	0.04
572.4141235	0.40
592.6546021	0.04
603.4482422	0.40
608.2584229	0.07
610.8073120	0.19
613.2348633	0.03
617.4542236	0.57
621.6622925	0.08
624.2786255	0.21
629.9263306	0.22
641.2869263	0.06
642.9789429	0.08
653.6777954	0.07
667.6425171	0.49
668.4642944	0.09
686.1962280	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8028412	21.21
212.9362335	0.03
254.8471375	0.11
290.7313843	100.00
291.3365173	0.27
296.7738953	0.07
339.0289917	0.01
368.7923584	0.02
373.2092590	0.03
374.5702209	20.53
375.2969666	0.22
398.8862000	0.10
412.7122498	0.10
429.1225891	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1114.31
Annotation	Unknow
Peak:m/z	Relative Intensity
316.3074036	0.02
331.2848511	0.03
343.2340088	0.01
345.9986572	0.02
355.1417847	0.04
463.2471924	0.06
464.3418579	0.07
487.2277222	0.01
491.2655945	0.04
493.4137573	0.02
505.5351562	0.07
507.4733887	0.02
517.7262573	0.04
523.6693115	0.03
535.2082520	0.00
548.1791992	0.02
571.0683594	0.03
585.3199463	0.01
589.3601685	0.02
601.3645020	0.03
607.5968018	0.01
633.1235962	0.02
646.5718384	0.01
649.3211670	0.03
667.2783813	0.01
680.2647705	0.01
692.0051880	0.02
715.3932495	0.02
734.7670288	0.04
750.8947144	0.01
763.3880615	0.03
781.6115112	0.02
811.5114746	0.10
843.6490479	0.01
1096.5014650	0.04
1113.2882080	100.00
1114.4097900	21.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1771
Annotation	Tryptoquivaline I
Peak:m/z	Relative Intensity
149.0592346	0.06
161.2626801	0.06
162.2509308	0.05
163.1332550	0.12
165.2394104	0.29
169.1533051	0.20
174.9814301	0.09
187.1989441	0.36
191.2330627	0.09
193.2582397	0.07
204.4135437	0.04
207.2643433	0.05
224.9238586	0.22
229.0938416	0.07
231.1544037	0.18
233.2811890	0.24
236.9998016	0.05
239.3952026	0.11
245.3512878	0.12
247.0607300	0.13
249.0993958	0.20
251.2638855	0.26
253.3020325	0.05
255.2509155	0.99
257.0687561	0.27
263.0255432	0.45
265.4786072	0.22
267.3825989	0.17
269.2007751	0.19
271.1604614	0.08
274.1380005	0.03
275.2551880	0.19
279.1931763	0.05
283.3013916	0.23
293.4621277	0.57
295.3987427	0.29
297.2264709	0.16
299.3023071	0.27
305.4021912	0.09
307.1576843	0.19
309.3771362	0.09
311.1872253	0.70
313.2716675	0.08
315.2493591	0.05
321.3628540	0.09
323.1531677	0.27
325.3337402	0.18
327.2545471	0.43
329.2920227	0.25
335.2144165	0.23
336.4151917	0.04
339.1920776	0.38
341.4000244	0.08
343.2677612	0.04
345.0122681	0.16
347.3818970	0.10
351.3559875	0.48
352.3288269	0.58
353.3203125	1.49
354.4353333	0.04
355.3640747	0.29
365.4279175	0.06
367.2967224	3.22
369.2548523	1.47
371.2572632	5.36
380.3062744	0.07
385.2758179	0.33
387.4104004	0.30
389.2870789	0.24
395.2821350	2.98
397.3935242	0.03
399.5179138	0.07
403.4540100	0.03
411.4500427	0.06
413.3269348	10.64
415.2623596	0.33
421.7770691	0.07
427.3785095	0.13
429.2715759	1.22
439.4546509	0.75
443.4636536	0.14
455.2329102	0.26
457.1672668	100.00
457.7764587	0.82
459.5229492	0.31
462.4546814	0.12
463.4971008	0.05
464.3794250	0.14
467.2213440	0.11
502.8981323	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.1747
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
118.8671417	0.07
120.9339142	0.77
122.9605026	1.62
123.6499634	0.03
124.9907990	0.05
127.0228577	0.27
128.7920074	0.08
133.0510559	0.19
135.0839081	0.06
139.0447998	1.89
141.1634827	0.07
144.9441528	0.09
151.0008850	3.50
152.9793091	0.66
162.9621887	0.07
165.0114136	0.03
167.3149261	0.01
168.9871521	100.00
172.7704468	0.08
181.0422211	0.06
182.8957214	0.03
186.9000244	0.55
190.6422119	0.06
193.1647034	0.18
197.1535950	0.08
203.0145264	0.10
205.4171448	0.08
211.3076935	0.03
213.0321045	0.44
216.8798218	0.08
223.2147369	0.18
230.9055176	0.63
235.0434265	0.40
248.9529724	0.70
253.1786499	0.42
259.1489868	0.56
265.1968994	0.04
277.0541382	1.72
295.2749023	0.24
296.3012695	0.02
299.1123352	0.06
300.8300476	0.03
313.2521973	0.08
330.4911804	0.04
331.0979614	0.07
337.0755920	0.02
345.1358032	0.03
355.1958008	0.57
363.2481384	0.43
372.1690369	0.11
373.5384521	0.10
381.1487427	6.63
386.7957458	0.06
398.4156494	0.45
399.2021179	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.159
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
173.0039825	0.03
178.9676514	0.32
192.0561218	0.03
202.9641418	0.12
244.9731598	0.03
267.1532593	0.03
275.0830688	0.20
277.2980042	0.08
287.0949707	0.07
302.9268494	0.05
307.9221802	0.04
324.2147217	0.04
327.9376221	0.06
329.1018066	0.09
339.3192139	0.04
341.2478027	0.38
341.8566284	0.04
346.2847290	0.02
350.1997070	0.03
353.0569458	0.48
354.2010498	0.03
363.2007446	0.80
364.3336182	0.12
371.2761841	1.23
372.2292480	0.40
377.2659302	0.13
379.2620850	0.08
383.3343506	0.18
391.4799194	0.06
395.2377930	1.02
396.1301270	0.33
405.0177002	0.04
406.3713989	0.03
407.0553589	0.05
409.2852783	0.08
410.1635742	0.02
413.4995117	0.02
415.4919434	0.45
419.1171875	0.07
420.0506592	0.20
425.1761475	2.55
426.1986084	0.99
427.2718506	0.22
431.2920532	0.82
432.4134521	0.07
437.2332764	2.15
438.1871338	0.53
443.0919800	1.42
444.1349487	0.29
448.5889893	0.26
449.3515015	0.51
450.2988892	0.27
455.1463013	1.27
456.1418457	0.45
457.2557983	0.11
461.2834473	0.55
462.1989746	0.42
465.1113281	0.10
473.1638184	56.13
474.2201538	13.23
479.3317871	0.24
483.5020752	0.25
487.1433716	0.07
491.1725464	17.03
492.2812500	3.46
497.2587280	5.49
498.2675171	2.36
507.2491455	0.03
510.2380981	0.11
515.3008423	7.97
516.3577881	2.66
521.3815308	0.05
522.0419922	0.11
527.1370239	18.87
528.1891479	5.15
528.8618164	0.07
532.2624512	0.06
539.2643433	8.28
540.2744751	2.67
545.1701660	19.31
546.3095703	5.73
550.9171753	0.04
553.0781860	0.11
557.1830444	12.14
558.2460327	3.81
575.2129517	37.44
576.2893677	9.46
585.4089355	0.17
593.1929321	100.00
594.1746216	28.92
594.8437500	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	478.294
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
140.2078552	0.03
147.1403046	0.02
152.9960022	0.14
166.0722351	0.01
196.0908813	2.44
214.0957336	1.04
273.2064209	0.02
279.3311768	0.01
281.2724304	100.00
287.1823425	0.01
309.8297729	0.02
385.4483948	0.02
417.5333557	0.22
445.2293396	0.03
450.2082825	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.162
Annotation	Butrin
Peak:m/z	Relative Intensity
175.1784363	0.10
185.0494080	0.05
191.1230621	0.14
200.0022888	0.02
221.1255798	0.10
251.2277222	0.07
253.3077393	0.03
257.3125610	0.22
274.3179016	0.07
274.9513855	0.07
287.3041382	0.04
294.2160034	0.38
295.0507812	0.02
297.1416626	0.05
299.1435242	0.04
301.1038818	0.09
312.1434937	1.61
315.1922607	0.12
327.5756836	0.02
329.4940186	0.09
339.1832275	0.21
340.0803833	0.29
341.1293945	1.13
351.3444214	0.08
353.2565918	0.46
355.2103271	0.52
365.3103027	0.39
367.2215576	0.04
368.0304565	0.21
368.7550049	0.18
370.1040039	0.38
371.1257935	0.08
379.1784058	0.17
381.3080444	0.20
383.1749268	58.19
385.0496826	0.15
393.1475220	0.08
394.4980469	0.23
395.3350830	0.57
397.1328735	0.04
398.2023926	0.15
409.1121216	0.20
413.2127075	25.94
413.9800415	0.13
419.4207153	0.02
421.3222656	0.12
423.5491333	0.08
425.2822876	2.72
427.2777100	1.20
430.2680664	0.04
437.6898193	0.12
439.2269287	0.46
443.2512817	1.77
449.1265259	1.03
450.2447510	0.04
455.2294922	0.82
457.1194458	0.09
459.1966553	0.08
461.2462158	2.41
467.3112793	1.09
467.9315796	0.02
473.2969360	0.22
475.2300415	0.13
476.4188232	0.05
478.4661255	0.04
479.1535034	0.12
485.3453369	4.33
486.4832153	0.11
495.3709106	0.03
496.5424805	0.22
497.2893066	0.18
500.0935669	0.11
501.3362427	0.24
503.2437134	100.00
504.1601562	0.03
511.2231445	0.07
513.1902466	0.05
515.3244019	1.70
521.2671509	0.05
527.5521240	0.04
529.2592163	0.15
533.3189087	14.63
543.4002075	0.07
545.3250122	1.59
547.2420654	1.29
561.2388306	0.20
563.3002319	1.32
569.3660889	0.02
575.2324219	0.55
587.2345581	0.82
587.8424683	0.01
593.4813843	0.05
602.2603149	0.08
604.2573242	2.64
605.2813721	4.67
608.3903809	0.15
623.4257202	1.07
624.3714600	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.1064
Annotation	6-Deoxyclitoriacetal
Peak:m/z	Relative Intensity
126.8292465	0.02
128.9487762	0.05
136.7923889	0.09
137.8271942	0.02
141.0424194	0.03
150.9559021	0.17
167.2992554	0.05
169.2674255	0.04
171.2040100	0.02
181.0893555	0.09
192.1411591	0.04
194.0175476	0.05
195.1185303	0.09
204.1690674	0.06
210.8065643	0.01
212.0845642	0.02
212.9656372	0.02
215.1714478	0.02
223.0820618	0.04
227.0170898	0.91
229.1546631	0.07
234.4464417	0.07
258.1938782	0.04
280.4205933	0.03
284.2559814	0.02
286.1737976	0.02
293.2815552	0.03
294.4840088	0.04
297.4190063	0.07
299.0306396	0.23
300.9708252	0.17
313.2598572	2.02
314.1423950	8.51
315.2326050	1.43
317.2810974	0.04
318.4238892	0.04
321.0809937	0.02
324.0278015	0.10
325.1242065	0.08
327.1011353	23.31
328.2348633	1.76
329.2679443	0.45
330.2319641	0.08
331.1824951	0.29
331.8457031	0.03
332.5071716	0.02
334.1315613	0.02
339.2536011	0.08
342.1270752	42.36
343.1495972	3.43
345.1286011	60.74
346.1119995	4.92
347.0467224	0.31
356.2658386	0.25
357.2692261	0.96
360.1189270	100.00
361.2164612	8.00
375.2332764	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.1787
Annotation	Unknow
Peak:m/z	Relative Intensity
128.1404724	0.06
139.8516998	0.26
142.7993774	0.07
145.0839996	15.05
154.0067749	0.02
154.8857727	0.03
158.9501801	1.74
167.0430908	0.62
185.1041870	0.16
196.0580139	0.47
203.0976562	0.07
205.7116394	0.07
208.2146912	0.03
211.2918396	0.14
212.0464325	0.19
213.0224304	2.25
213.9867859	0.19
221.1798401	0.13
222.0054626	0.09
223.1674805	1.76
227.3236389	0.12
228.1089172	0.03
231.0797119	0.51
240.0864563	6.44
241.1566162	0.16
245.1215210	0.78
250.0914307	0.06
253.0524292	0.07
255.2901611	0.03
258.0618591	1.17
261.9436035	0.06
263.3947144	0.02
265.3458252	0.07
267.2293396	0.54
270.2742310	0.03
271.4811401	0.04
274.9936523	0.12
277.3052673	0.16
279.2436829	2.72
280.1997681	1.01
285.0589600	0.34
291.2427063	0.08
294.1893921	2.82
295.5322876	1.19
296.1973267	11.10
297.0979004	0.59
298.0908508	0.35
299.0268860	0.02
300.0231323	0.19
300.8797607	0.05
313.2158813	100.00
314.1602173	3.19
315.2895203	0.29
322.4767456	0.04
324.3720703	0.06
329.1742554	0.02
331.0991821	27.95
332.2813110	0.38
333.1410828	0.04
341.2773743	0.36
344.0885620	18.44
345.1466370	0.89
358.8471069	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0824
Annotation	Eupatorin
Peak:m/z	Relative Intensity
116.8893814	0.09
137.3111877	0.03
141.1367645	0.14
157.1849976	0.02
170.1553345	0.02
180.1447144	0.05
187.0594177	0.01
190.8305511	0.07
193.1159515	0.06
199.099472	0.02
199.7064514	0.05
225.1249695	0.03
234.1055908	0.03
235.0474548	0.03
237.2835388	0.05
239.3236694	0.03
241.1916809	0.02
243.3205261	0.09
250.007782	0.02
253.0809937	0.02
254.3879395	0.03
255.1581116	0.02
256.1434326	0.02
262.0339661	0.04
263.1865234	0.06
265.0836792	0.05
269.2304382	0.03
271.2254639	0.03
281.3169556	0.17
282.0870972	0.11
283.2597046	0.14
285.2301941	0.11
293.1848755	0.03
296.1067505	0.09
297.281311	0.24
298.4966431	0.20
299.1814575	0.03
300.2791748	0.09
306.9515991	0.14
311.2306519	0.15
312.0914001	0.16
313.177124	3.77
315.2368164	0.39
316.299469	0.03
324.579895	0.40
325.3587341	1.02
326.3668518	0.09
328.0616455	100.00
329.1126709	0.74
343.4524231	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1738
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
263.4086914	0.04
317.4026489	0.05
337.2900391	0.34
343.1290894	0.05
355.2278442	0.16
367.0780029	0.31
385.2854614	0.90
409.1766357	0.78
420.8841553	0.11
433.0371704	0.04
439.1018066	3.65
445.1465454	0.84
451.2684326	1.54
457.1969604	1.43
463.0850830	0.13
469.2308960	2.62
475.1585693	0.64
487.2184448	43.86
487.8424683	0.20
495.4049072	0.04
505.1867065	12.89
511.2831421	5.24
523.1790161	0.47
529.3215942	10.54
535.4782104	0.04
541.2827759	17.13
553.2694092	7.89
559.2072754	19.51
571.1622925	11.27
571.7653198	0.11
589.2091675	33.77
589.9244995	0.02
607.1812134	100.00
607.8616943	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	389.04
Annotation	Dysamide B
Peak:m/z	Relative Intensity
114.6857529	0.36
130.9574585	7.05
145.1604462	0.05
146.9651489	2.37
157.2228394	0.28
158.9570770	7.06
161.0177002	0.15
174.8910217	100.00
179.9711609	0.16
189.4117279	0.08
190.1664124	0.09
198.9382935	0.16
213.1144867	0.50
218.9791565	0.05
224.1125793	0.40
230.8903503	0.09
240.0190430	0.25
242.3834534	0.22
243.3126526	0.27
244.2010193	0.05
244.8519592	0.16
247.1216736	0.40
254.9077454	0.22
257.0468750	0.12
259.1097107	9.57
272.9980469	20.96
273.9350586	8.67
275.0557251	98.32
275.6719971	0.23
281.0838013	0.08
287.3062439	0.19
304.1129761	0.18
309.9047852	0.12
311.1633911	0.13
317.1036682	0.21
325.1295776	1.22
326.0765076	0.08
327.1096802	0.34
329.1075134	0.19
334.3707275	0.18
341.4279785	0.07
342.9776001	15.65
344.3804321	0.59
345.1237488	0.47
359.0786743	0.25
361.2298279	2.12
364.1860046	0.07
370.3652344	0.43
371.2887878	0.40
372.3837891	0.09
374.5160828	0.11
388.6474609	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	322.2026
Annotation	Brevisamide
Peak:m/z	Relative Intensity
109.0944672	0.05
109.7995758	0.05
112.9142075	0.05
128.1471100	2.92
130.0371094	100.00
149.0015564	0.37
165.0832214	0.45
172.0411377	5.40
189.9845581	0.24
191.1115417	1.31
212.4340820	0.06
225.3214417	0.04
233.2586365	0.03
234.2781982	0.06
260.3084106	0.14
261.9674072	0.04
275.9821777	0.10
277.1219482	0.32
278.2807007	0.87
279.1015015	0.07
286.0535889	0.37
302.3194275	0.16
303.2689209	0.36
304.2664795	0.75
306.2639465	0.05
307.2167969	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	722.2458
Annotation	Unknow
Peak:m/z	Relative Intensity
209.9175110	0.15
254.1067505	2.68
272.2963257	2.05
465.1889648	0.12
476.4783325	0.14
549.4479370	1.89
553.6326294	0.24
560.6373901	0.18
636.4479370	1.25
660.4015503	4.54
662.7980347	0.43
678.4053955	100.00
703.5018311	0.11
722.1654663	50.25
723.3413696	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1237.6217
Annotation	Jujuboside C
Peak:m/z	Relative Intensity
773.5246582	0.04
784.2625732	0.26
785.0922852	0.04
1075.6171880	0.10
1108.2446290	0.07
1167.0023190	0.08
1237.5864260	100.00
1238.5850830	7.76
1239.3725590	0.20
1242.0142820	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.22
Annotation	Quercetin-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside
Peak:m/z	Relative Intensity
284.1514893	3.59
299.2411499	4.37
300.0285339	2.32
301.2007446	2.73
314.1361084	0.69
315.2047119	0.70
379.4271851	3.91
390.2163086	0.37
443.4440918	0.91
447.4518433	3.71
461.0680542	2.56
462.1856079	1.68
463.2648315	6.96
494.6184692	0.62
504.3360596	2.52
505.6397095	3.24
543.1192017	0.53
544.3110962	3.02
605.3183594	2.29
607.3306274	7.13
618.1033936	0.68
623.4120483	3.05
625.6196899	0.89
627.4962769	0.41
648.484314	1.24
678.2949219	3.22
679.5485229	0.91
687.6520386	1.56
689.3395996	0.95
706.2765503	0.73
715.6074219	0.57
726.5474243	3.81
748.8779907	0.78
749.5080566	1.29
751.7428589	0.82
769.2327271	100.00
770.007019	3.92
770.6577759	1.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	263.1749
Annotation	(+)-5,17-Dehydromatrine N-oxide
Peak:m/z	Relative Intensity
83.9098129	5.54
85.9701996	20.72
90.8329239	0.12
95.9907379	0.15
98.0020294	10.32
99.8722687	58.26
103.8298798	0.07
107.0193634	1.24
111.9535370	0.51
116.9943848	100.00
119.0387878	0.33
120.0236664	0.35
121.4638367	0.34
122.0747833	2.00
125.0391235	0.42
125.9759369	0.52
128.0438080	0.12
135.8793030	0.60
138.9720154	0.09
141.9627686	8.98
143.0906067	18.40
146.8766937	70.93
157.0943756	0.25
161.7769623	0.24
168.8686676	0.07
175.1094818	0.07
178.2336273	0.42
187.3075409	0.25
190.0415497	16.94
192.0145416	0.10
201.1931915	0.08
213.0379181	0.11
217.1374817	0.27
218.8769989	0.09
219.8632355	0.13
221.1388550	4.66
221.9429474	0.05
227.1068268	0.08
230.8811188	0.18
232.1050568	24.92
235.0497589	0.33
239.2303619	0.18
246.1652832	31.49
254.1528778	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3073
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
168.6493378	0.04
189.0706024	0.03
197.9907684	0.10
205.3555603	0.02
216.0027313	0.04
229.3980713	0.02
239.257431	0.02
247.2176208	0.06
253.0866699	0.02
264.3293457	0.06
265.122467	0.07
267.4325562	0.13
269.0846863	0.01
279.4143677	0.03
293.0915833	0.06
308.458374	0.48
337.2821045	0.07
339.2893066	100.00
339.9310608	0.26
386.3621521	0.03
419.1148376	0.27
437.3766174	0.06
450.0531311	0.04
462.2467957	3.40
466.3553772	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.1794
Annotation	O-Methyl-waltherione A
Peak:m/z	Relative Intensity
115.8893433	0.32
121.6860809	0.05
125.0503616	0.05
127.2446823	0.03
128.8698578	0.06
129.9500732	0.16
131.8412628	0.08
140.9270172	0.05
143.9207153	1.41
144.7711945	0.10
158.9806824	0.69
161.9856110	21.25
164.0574646	0.12
165.2258606	0.02
166.0595093	0.16
167.9791565	0.03
176.0198669	0.65
187.2662659	0.04
201.0944977	0.27
203.2203979	0.06
205.9796143	0.05
209.1752014	0.09
212.1216583	1.14
216.3102417	0.04
230.0976868	0.74
233.2178650	0.07
234.1131897	0.06
244.0940552	1.51
245.4058228	0.04
247.8094177	0.29
250.9342651	0.29
255.1345825	0.04
255.9812927	0.04
259.1116943	1.86
260.2161255	1.92
262.0324097	56.75
265.2049866	0.05
267.1115112	0.03
269.0876770	0.15
273.9210510	0.16
275.8985901	0.03
279.1428833	100.00
284.7848816	0.30
289.8322754	0.04
294.1733398	0.61
305.9985657	0.09
308.2389526	0.06
310.0778809	0.02
315.0881958	0.26
325.0199890	0.02
332.2747803	0.10
333.1881714	15.68
336.4064331	0.03
345.2966003	0.03
347.1382141	0.07
354.1826782	0.88
362.6213684	0.09
364.0967407	0.05
372.3166504	1.39
390.1419067	6.18
391.3117981	0.89
399.8964539	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1081.2823
Annotation	Unknow
Peak:m/z	Relative Intensity
301.1084595	0.04
314.0798340	0.01
325.4216003	0.02
329.1733398	0.05
339.3056946	0.03
341.2494507	0.02
343.2324524	0.05
433.6632385	0.01
445.4067383	0.01
449.0803833	0.01
463.3159180	0.34
487.2209473	0.07
491.3347778	0.02
505.3745422	0.26
527.1116943	0.02
529.4127197	0.02
534.9588623	0.01
545.0152588	0.01
547.1627197	0.07
563.3408203	0.01
569.4710693	0.01
571.2757568	0.05
587.6345215	0.01
589.2495117	0.03
607.2884521	0.09
629.1678467	0.01
631.3967896	0.14
649.1729126	0.09
655.0878296	0.03
667.5469971	0.01
679.4267578	0.01
687.3630371	0.01
733.6130371	0.01
751.4379883	0.23
781.6191406	0.03
1081.2508540	100.00
1082.2436520	5.93
1082.9356690	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1089
Annotation	Lactulose
Peak:m/z	Relative Intensity
101.0429153	0.04
102.8764496	0.08
112.9292603	0.51
116.7640991	0.03
119.0000153	0.32
130.9409790	2.08
132.9702759	0.04
140.0074768	0.02
142.8770752	0.51
148.9819031	100.00
151.2229919	0.03
152.9880981	0.11
161.0124512	1.07
170.9773560	0.03
173.1894684	0.04
178.9989319	2.25
190.9770813	21.65
191.5868530	0.03
218.1353760	0.04
221.1755371	0.22
234.9790344	0.07
277.0022278	0.31
278.4583130	0.39
279.1780701	0.14
280.1297302	0.65
281.3894043	0.02
295.0152283	0.47
322.9942322	1.37
325.1409912	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	144.1015
Annotation	L-2-Amino-3-methylenehexanoic acid
Peak:m/z	Relative Intensity
55.0001678	3.22
57.7878265	32.01
71.8603287	1.60
83.9239654	100.00
97.8313446	34.59
100.0695953	3.15
101.0607605	2.13
101.9268341	35.88
127.8410492	2.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1462
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
173.9599609	0.05
174.9378357	0.06
176.9294891	0.03
179.0185394	2.44
182.1433258	0.07
183.1332703	0.04
185.1783447	0.14
186.1457214	0.07
188.0870514	0.09
189.0952454	0.03
189.8942871	0.27
191.0372467	0.34
192.9630127	0.32
197.0914612	0.08
198.0852356	0.15
199.2193756	0.13
202.0648499	0.09
203.1877136	0.15
207.0271606	0.10
209.1004486	0.05
210.0893402	0.07
211.0568542	0.37
213.1142120	0.12
214.0904541	0.07
215.2560425	0.10
216.2967529	0.36
217.0884705	0.41
221.3858948	0.04
225.3273468	0.10
227.0845947	0.42
228.1487885	0.12
229.1395569	1.32
231.0202332	0.28
232.9851227	0.21
239.0762787	0.30
240.0833130	0.15
241.0488586	0.04
242.9334412	0.61
245.1801453	0.54
246.2196808	0.04
247.1353149	0.37
253.2442474	0.20
254.1692047	0.83
255.0196533	5.09
255.9937134	0.10
257.1846924	0.59
259.0078125	0.18
266.1174316	0.10
269.1199646	0.15
271.1375732	7.02
272.0268250	0.15
273.1893616	1.66
283.1131592	0.64
284.0449829	0.04
285.2052002	0.15
295.1299438	0.16
296.0668945	0.11
297.1737061	1.26
299.0379639	1.84
300.0836792	48.97
301.0615234	100.00
303.7281494	0.04
308.1227417	0.21
308.8914795	0.36
309.6085205	0.35
311.1466675	0.07
312.2887573	0.50
313.0646973	0.82
315.1803589	0.48
317.2337036	0.05
323.1608887	2.62
324.2337341	3.00
325.1782837	1.08
327.1616821	0.29
329.2877197	0.15
331.2509766	0.13
337.0935669	0.14
338.3112793	0.10
339.2156982	0.27
341.2244873	1.87
342.1788940	2.73
343.1090698	8.17
344.1861572	0.09
352.7843018	0.51
354.1766357	1.17
355.2098999	1.35
356.2925415	0.05
365.6091309	0.36
366.2629395	0.11
367.1734009	0.64
367.8899536	0.07
369.1445312	0.11
371.2788696	0.69
372.2365723	0.98
373.2766113	0.62
380.8571777	0.04
383.4141846	0.65
384.2368164	0.51
385.3588867	0.20
386.1938477	0.09
387.1858521	0.05
402.3994141	0.06
407.0791016	0.05
409.2336426	0.17
411.4495850	0.04
412.1016846	0.06
413.6353760	0.05
419.3515625	0.07
426.3131714	0.11
429.2862549	0.29
437.2125244	0.21
443.2919922	6.72
444.1868896	14.40
445.2764893	3.83
446.2296143	0.04
447.2471924	0.07
457.2409668	0.16
462.3126221	0.05
463.1864624	0.71
464.2981567	0.80
465.4129028	0.72
481.4371338	0.12
483.1429443	0.30
486.9904785	0.19
488.2529907	0.59
489.1651001	0.60
499.1574097	0.20
500.1085205	0.12
505.3729248	0.09
507.3344727	0.04
513.3296509	0.08
519.0772705	0.04
525.3801880	0.14
532.2385864	0.07
562.1740112	0.04
563.4591064	0.36
565.2597046	0.22
573.4783325	0.10
591.2156372	3.36
592.9647217	0.04
609.3893433	0.21
610.3013916	1.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.2724
Annotation	Ixerin Q
Peak:m/z	Relative Intensity
205.2657776	0.31
254.2072449	0.02
330.3169556	0.23
344.2500000	0.11
348.2836914	0.05
359.2407227	0.06
398.2219238	0.05
410.3430786	0.06
413.4068604	0.24
416.2149048	0.22
428.5353394	0.31
429.3116455	0.26
430.4455566	0.08
441.8181152	0.05
444.2310791	0.08
457.0428467	0.29
458.3309326	1.28
460.4141846	0.21
472.2247314	1.09
473.1207886	0.29
474.2503662	0.11
489.2705688	0.15
490.3749390	2.53
495.3792725	0.21
502.2569580	10.70
504.2847290	2.35
505.2737427	1.44
506.3989868	0.11
509.5882568	0.05
516.6995239	3.69
517.3474121	11.24
518.1372070	0.14
519.4450073	0.78
521.3785400	0.13
534.1594849	5.56
535.3829956	0.36
548.2831421	1.34
549.2344360	5.86
550.2736206	0.18
563.3916626	19.21
564.4710693	0.06
567.7258301	0.07
595.3496704	7.31
606.8405151	0.25
607.4418335	6.68
609.5059204	0.07
611.5379028	0.21
612.2280884	0.12
621.6640015	0.21
627.2571411	2.76
639.3646851	100.00
640.5300903	0.05
653.2328491	0.20
671.2781982	24.31
672.0038452	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
117.14888	0.02
143.1318665	0.01
149.9866028	0.07
151.0673523	0.06
162.9260254	0.01
164.9648438	0.02
171.3233948	0.01
175.1921387	0.04
178.0115051	0.08
179.9904022	0.04
183.3295288	0.04
184.561554	0.02
185.1617432	0.06
187.1291809	0.03
190.1384125	0.02
191.9238129	0.02
193.058075	1.05
194.9342499	0.06
197.2129974	0.11
198.745285	0.04
200.9956665	0.02
203.9584961	0.01
212.2749023	0.01
213.2128601	0.03
213.9562988	0.02
221.2980042	0.01
222.875946	0.02
224.0556335	0.04
225.2575989	0.07
225.9631653	0.04
227.1868591	0.03
229.2273865	0.01
233.2113342	0.03
236.1375122	0.04
238.9405212	0.02
240.3275146	0.08
241.2202759	0.12
242.1134338	0.04
243.3453979	0.04
249.3110352	0.02
251.334198	0.06
253.1945801	0.14
253.952301	0.08
255.2048645	0.09
257.0439453	0.04
259.443512	0.05
265.974762	0.04
267.1494751	0.85
269.0975037	0.35
270.0513306	2.50
281.0999146	0.15
282.1419373	0.20
283.1376648	2.32
284.0794067	0.08
285.1531372	6.24
286.1633911	0.02
293.302002	0.01
294.622467	0.20
295.2316284	2.57
298.0509644	100.00
298.9735718	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.0446
Annotation	Unknow
Peak:m/z	Relative Intensity
123.0735474	0.01
130.7543488	0.01
138.9362793	1.81
139.8972015	0.11
141.0639191	0.05
143.0381317	0.09
148.8628998	0.02
150.3963928	0.05
151.0288086	0.27
152.0231476	0.13
153.0640259	0.02
160.9643097	0.07
163.5195160	0.04
164.9414368	0.25
167.0182190	0.66
168.1053925	0.02
169.0425415	0.21
174.9497986	0.01
177.0910339	0.01
178.9247742	0.07
181.0396423	0.48
183.2155762	0.07
193.0549164	0.02
195.1726379	0.02
199.1246643	0.03
200.6555939	0.01
201.3043213	0.01
203.1618958	0.03
205.0705414	0.08
209.1426239	0.03
210.1976929	0.03
211.1480255	0.04
223.0888062	1.99
224.0812378	0.31
229.3157959	0.02
232.9726562	0.01
233.8872375	0.01
239.1903381	0.39
240.9954834	100.00
242.0419312	8.10
247.0549011	0.09
247.9164429	0.02
250.8783569	0.02
253.3021240	0.01
257.7984314	0.04
259.0886536	0.05
272.9772949	0.01
275.1314392	0.02
279.1639709	0.01
281.1936951	0.07
282.9941406	0.01
285.4666748	0.02
286.1073608	0.03
293.1720581	0.03
294.0136108	0.01
305.1892700	0.03
306.1779175	0.01
311.1782532	0.07
318.0402527	0.01
318.9186707	0.01
329.1640015	0.79
330.2075500	0.10
334.9464722	0.00
338.0859680	0.01
345.1757202	0.02
348.3281250	0.05
349.3096619	0.01
361.0325623	0.02
362.1704407	0.03
363.2495422	0.80
364.0516968	0.08
365.2478333	0.03
366.2607727	0.12
367.3644104	0.04
377.3697205	0.01
389.2948914	0.09
391.2202454	0.13
392.2268372	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.2997
Annotation	Mombasol
Peak:m/z	Relative Intensity
266.3267212	0.02
269.2440796	0.06
277.1716003	0.02
292.9356689	0.03
297.3762207	0.04
327.2942505	0.04
351.4844360	0.03
371.2883911	0.02
383.2192383	0.02
385.1737671	0.01
386.6444092	0.01
404.3508301	0.02
417.4819946	0.06
427.4312744	0.01
446.3685913	0.01
457.4632568	0.07
462.4736938	0.03
470.7221680	0.01
475.3944702	0.02
485.3321533	0.05
490.3560181	0.26
491.2659912	0.08
492.6148682	0.11
496.2551880	0.03
502.2604980	0.01
514.5411987	0.04
517.4786987	0.01
524.1923828	0.02
537.5220947	0.04
538.7184448	0.01
567.3505249	0.01
579.4014282	0.08
585.6298218	0.07
587.1271362	0.05
593.4436646	0.07
595.4586182	0.60
596.6765137	0.03
598.3264771	0.04
599.5374146	0.09
600.3131714	0.01
605.2128296	0.02
609.5739136	0.14
611.3379517	0.30
613.2816772	0.14
613.9453735	0.01
618.2160034	0.03
623.2410278	0.34
624.6933594	0.17
626.6833496	0.06
627.4359741	1.80
628.4320068	0.02
629.5668945	0.01
637.3756714	0.95
638.5178833	0.08
644.2553711	0.02
645.3724976	0.20
655.3519897	100.00
656.0187378	0.48
658.2588501	0.03
669.1647949	0.33
670.3585815	0.02
671.6483765	0.02
673.0264282	0.04
673.6518555	0.03
687.4718628	0.70
688.7467651	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.19
Annotation	8-Oxodeoxycoformycin
Peak:m/z	Relative Intensity
179.0454559	0.03
265.1004639	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	324.13
Annotation	Unknow
Peak:m/z	Relative Intensity
105.9759979	0.22
113.8485565	0.03
118.1213379	0.11
123.9748917	0.08
124.9623260	0.11
131.9898529	7.06
144.9484558	0.14
145.8113403	0.03
148.9597626	0.37
150.0131226	0.19
160.6556091	0.05
165.7809753	0.13
166.9969940	0.08
174.9165344	0.04
184.0031433	0.50
191.9136047	0.15
192.9123993	0.51
194.0657959	0.13
195.0663147	0.35
200.9261017	0.19
207.0848083	0.35
212.0792542	3.23
218.1926575	0.14
226.8773804	0.05
227.9362488	0.57
234.2605591	0.06
235.0829773	0.35
243.2442932	0.19
248.9625244	0.10
250.1901855	0.11
252.3688965	0.75
257.1303406	0.15
261.0685425	0.18
262.0609741	0.31
265.1169739	0.14
268.1286926	100.00
268.7418213	1.02
272.1813354	0.16
278.3373718	0.08
280.0552979	0.04
289.1514893	0.07
305.1063232	0.11
306.0518188	0.99
307.2358398	0.23
308.3417664	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.2082
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
151.2188263	0.24
152.9080048	0.10
163.1687317	0.12
171.2283478	0.10
173.1119385	0.09
175.2450256	0.05
176.9516144	0.16
180.8401184	0.06
182.3170471	0.10
183.0307312	0.11
189.0625305	0.04
199.1811981	0.37
201.3445129	0.07
203.2511444	0.11
213.1356049	0.26
215.1240387	0.04
215.9932251	0.05
217.2117310	0.17
219.1253815	0.18
223.5155182	0.09
225.1381073	0.07
229.2369232	0.10
229.8652039	0.04
231.4049988	0.71
233.2180786	0.30
239.2798157	0.29
241.2165833	0.34
243.2031708	0.28
245.2827148	0.47
247.1817169	0.16
249.3807373	0.04
251.2118225	0.09
251.9986725	0.03
253.3023987	0.24
257.1583557	0.95
259.2948303	0.99
261.2685242	0.49
265.3676453	0.03
266.9220886	0.07
268.3012085	0.04
269.1808777	0.16
271.1831055	0.02
273.1931152	0.11
275.1603394	0.59
277.0979004	0.39
278.0614319	0.22
281.2533264	0.53
283.3640747	2.06
285.3589172	0.19
287.2593689	0.68
289.6583557	0.06
291.4996643	0.24
293.3158569	1.08
295.2595215	0.61
297.1381836	0.26
299.0680847	0.18
300.2807312	0.18
301.1540222	1.39
302.1802368	0.04
307.1940308	0.15
309.2449951	0.59
309.9300232	0.05
311.2162476	2.50
313.2319336	0.49
315.0303955	0.46
317.0974121	0.16
317.7852173	0.11
319.1248169	1.05
319.9175415	0.06
321.1978760	1.97
323.1542969	1.55
324.6590881	0.35
325.3671570	0.96
327.3094177	1.28
329.2830811	0.36
333.1742859	0.43
335.0994873	0.16
337.2061157	10.93
337.8666382	0.11
339.2281494	6.84
341.1671143	0.25
342.2529602	0.15
343.1503906	5.38
344.1998596	0.79
345.4290161	0.20
351.2540283	1.48
353.2646179	0.87
355.1144104	3.41
357.0678711	0.71
358.3333740	1.10
359.3080444	0.80
361.3808594	0.03
365.1977844	0.10
369.2351990	2.13
369.8526001	0.09
371.2980347	1.45
372.6975098	0.31
373.4007263	0.35
379.4119263	0.88
381.3919373	0.16
383.6003723	0.09
385.3136597	0.39
387.2612610	1.69
391.7446289	0.03
395.1848450	0.78
397.2858887	4.49
399.3243713	0.24
407.1283264	0.03
409.5407410	0.13
411.3117676	0.17
413.2608032	5.90
415.2170105	100.00
415.9168396	0.21
417.0840759	0.11
418.3207397	0.09
426.0745544	0.17
427.0716858	0.05
430.2703247	0.04
431.9287415	0.05
439.2651672	0.12
443.1770935	0.59
445.1619568	0.16
445.8192749	0.05
457.3401184	32.17
459.3748779	0.48
460.3072510	0.11
461.4805298	0.22
462.2405090	0.03
463.4424744	0.35
469.3330383	1.05
473.2360535	0.05
475.3091125	0.09
482.8337097	0.29
487.3240662	45.73
490.2238159	5.08
506.2418823	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	633.3068
Annotation	Unknow
Peak:m/z	Relative Intensity
178.1852417	0.07
184.9449615	0.19
186.1118622	0.23
196.9939575	0.45
199.1596680	1.69
199.9992065	0.23
204.0527802	1.53
212.3475952	0.16
215.0716553	0.90
215.9301453	0.33
224.0166321	0.32
226.0071411	0.28
227.2590027	0.05
228.9275055	0.09
230.3571014	0.28
232.0714722	5.73
232.9342499	0.54
234.0703125	0.62
236.1989746	1.05
237.2191620	0.72
252.1839600	0.16
253.2221222	0.24
254.1744080	0.76
255.1587372	0.13
259.1544800	0.11
262.3585815	0.41
263.2511902	0.20
270.3975220	0.15
280.1846313	4.06
281.1433105	0.33
296.0024414	0.28
298.2448730	23.92
299.1804199	3.52
304.2766724	0.24
304.9342041	0.05
311.6074829	0.80
312.2857056	2.04
313.3571167	1.11
314.1763916	0.50
315.3065186	0.42
316.3242188	0.54
317.3707275	0.16
318.0723877	0.67
319.0701294	0.09
323.6167297	0.11
327.4715881	0.10
328.1527100	0.14
329.2247925	2.03
330.1468506	0.53
336.0904541	1.06
337.0122070	0.23
341.1354370	0.14
342.2397461	0.33
344.3586426	0.09
367.2207031	0.11
368.0855713	0.08
369.2826538	0.67
370.4164429	0.13
375.0458374	0.07
376.2879028	0.17
377.2257690	0.08
378.1948853	0.30
381.0349731	0.31
385.4620361	0.38
386.3103638	0.21
387.0308838	0.25
395.3157959	1.47
396.3223877	0.45
399.4808960	0.13
400.3464355	0.14
402.2917480	0.12
405.3114624	0.89
407.0655518	0.27
413.2048950	62.93
414.3333130	10.49
417.3182983	0.46
418.5003662	0.07
421.4003296	0.06
424.0087891	0.04
430.2683716	100.00
431.3179932	16.03
435.2125854	3.98
436.3210449	0.92
447.4208984	0.11
451.4815674	0.17
454.2584229	1.51
455.3727417	0.73
464.2309570	0.06
468.8244629	0.04
471.9504395	0.32
475.2857666	0.05
476.2113037	0.09
477.3995972	0.10
494.2335205	0.14
495.2419434	0.40
496.3496094	0.20
508.1825562	0.82
508.7874756	0.20
509.4542847	0.12
510.4206543	0.10
511.5012207	0.06
513.3803711	5.89
514.3380737	1.49
515.3405151	0.21
517.5479736	0.38
519.9124146	0.32
520.5647583	0.19
532.2391968	2.52
533.2608032	0.37
535.3871460	0.16
537.2128906	1.17
538.5055542	0.32
539.3895264	0.13
551.2754517	0.10
554.4762573	0.12
555.9603882	0.38
556.7391357	0.29
559.4064331	0.20
561.2177124	0.91
561.9475708	0.18
570.5411987	0.21
571.3398438	0.21
574.6348267	0.73
579.6063843	0.65
580.3878784	0.93
589.3952637	0.09
592.7467651	0.05
597.4603882	0.88
598.2479248	0.10
615.3429565	12.41
616.4387817	2.81
634.3892212	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1245
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.8897247	1.96
87.0177765	0.69
88.8772888	3.43
95.0653686	0.54
97.1105041	0.15
99.1095962	0.18
100.9377365	4.83
113.0209961	8.40
114.9466858	0.55
117.0509338	0.08
119.0151291	4.06
125.0951996	0.27
127.0238800	2.35
129.0301971	0.43
130.9476166	100.00
131.9865723	0.07
137.0718689	0.11
142.9657288	2.20
145.1632538	0.17
147.0400848	0.05
148.7680969	0.39
155.0441742	0.11
158.9725952	0.23
161.0492554	0.55
173.0608063	8.05
176.9163971	0.15
178.9791565	1.73
185.1123810	1.68
187.1212158	0.20
190.8182983	0.10
203.1564026	1.19
226.9783936	0.13
233.1070557	0.40
246.9751587	0.93
249.3156433	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.18
Annotation	Unknow
Peak:m/z	Relative Intensity
150.9631348	0.42
164.9580231	0.04
172.9414520	0.01
177.0934753	0.52
179.7963257	0.02
198.9342041	0.05
200.3856354	0.01
239.9895020	0.03
251.3567505	0.03
257.9260864	0.07
259.1926575	0.02
283.1495667	0.10
284.1168823	0.19
284.8934326	0.20
286.0691833	0.36
295.1922607	0.11
298.8033142	0.06
299.5289001	0.34
301.0989990	100.00
302.1453857	0.02
313.3937988	0.06
314.0629578	0.06
325.5052490	0.07
327.1669312	0.02
329.5746155	0.04
330.8044434	0.03
341.1565857	0.22
342.1992798	0.17
343.0586243	0.85
353.9993591	0.08
372.1217041	0.02
388.3955994	0.01
398.6571655	0.02
402.3623352	0.03
415.3457336	0.05
416.6883850	0.33
417.5765686	0.15
419.3791199	0.02
447.1188660	0.46
448.1844177	0.33
464.4281616	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0718
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
94.97093201	0.02
137.2718964	0.03
145.1833496	0.02
157.2969971	0.02
161.1990662	0.03
163.0870056	0.02
164.1337585	0.02
165.1174011	0.02
177.9523926	0.09
183.2992554	0.04
184.9611206	0.04
192.9958649	1.09
195.0028534	0.09
197.0518799	0.02
198.0079956	0.03
199.0942383	0.01
200.8911591	0.03
203.1340332	0.01
203.9198914	0.05
212.1107178	0.03
213.2388916	0.12
213.916687	0.09
219.2590332	0.01
220.208252	0.10
222.8791199	0.03
224.3787537	0.05
225.4460144	0.07
226.3427734	0.02
229.1986389	0.08
233.5717773	0.04
241.1337585	0.36
241.9110718	0.02
243.0021973	0.09
244.937439	0.06
251.2771606	0.05
253.0334778	0.03
254.1124268	0.02
255.3072815	0.03
257.1654358	0.15
267.2203674	1.03
268.3053284	0.07
269.0933228	0.62
270.1157837	3.39
271.0589294	0.06
280.1440125	0.01
281.260437	0.17
282.1338501	0.17
283.1939697	2.40
285.1495972	8.58
293.3095093	0.06
295.1925049	3.08
298.055542	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
98.9659729	0.04
114.9073639	5.90
130.8134766	0.22
150.8702850	0.07
156.9434662	0.03
158.9718018	100.00
178.2194824	0.03
198.9687500	2.20
200.8965759	0.19
217.0108032	1.43
219.0176392	0.12
227.2048340	0.10
228.9677429	26.71
244.9762573	0.28
255.3544922	0.02
258.2663879	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1768
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
112.9838791	0.08
118.7891998	0.37
127.2704773	0.07
128.1538239	0.04
130.9847717	0.07
143.0267029	0.68
149.1906738	0.11
159.0728607	0.09
161.0028229	1.62
173.0184631	0.08
178.9988403	5.04
183.1371765	0.06
184.4512787	0.19
231.5177612	0.02
235.1267395	0.02
243.2125854	0.19
253.9156494	0.03
255.2586670	0.09
270.8411865	4.07
271.5906982	0.01
289.1613770	0.46
302.8670654	0.04
308.0780945	0.15
328.5107727	0.08
329.1524658	0.02
345.5726929	0.06
347.1451111	100.00
349.2044067	1.02
350.2258911	0.10
356.6015930	0.07
359.1054993	0.03
362.4207764	0.04
374.0564880	0.08
375.2529602	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1816
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
189.0337372	0.44
190.0252228	0.11
190.9996490	0.07
192.9721375	2.11
201.1383057	0.03
202.1380157	0.82
202.9361267	0.15
211.0338135	0.05
214.9035950	0.07
217.1429749	1.03
218.1730499	0.24
228.0241394	0.05
233.1418152	1.83
235.4147034	0.14
242.1370697	0.13
243.0762634	0.31
245.3451233	0.03
248.8093567	0.04
261.1154785	3.23
270.3044434	0.07
274.9184875	0.04
277.0683289	0.86
286.9951172	0.29
295.2069702	0.38
305.1345825	1.74
307.2104797	0.13
311.3674927	0.25
312.2304077	0.17
314.0940552	0.33
315.2272339	0.30
316.2282104	0.24
323.2929077	0.19
324.0577393	0.12
325.3009644	0.14
325.9279785	0.02
329.1804810	3.22
330.3040161	1.24
339.4924011	0.08
343.2371216	0.60
344.1638184	11.86
345.2630615	2.07
347.2940063	0.15
349.1884155	0.78
357.1204834	0.85
358.1827393	0.62
359.1687622	48.05
366.1445312	0.37
366.9417725	0.14
369.2056885	0.02
372.3355713	0.31
381.2542114	0.69
382.5245361	0.21
383.3223267	0.12
387.3215332	0.57
395.3507690	0.07
401.2675171	6.23
410.1906128	0.25
413.1621094	0.20
417.1653442	0.13
418.9052124	0.20
423.4244385	0.09
425.3803711	0.05
426.8853760	0.75
427.5764771	0.23
429.3309937	0.30
439.4219971	0.04
454.4020386	0.33
455.2974243	0.17
470.4134521	0.54
471.0668945	1.63
487.0793457	0.30
488.0830078	0.27
489.3993530	0.17
499.2051392	0.10
502.6919556	0.21
503.3721924	2.32
506.2272339	0.99
507.2821655	2.26
519.3704224	0.09
521.2300415	100.00
521.9020386	0.20
540.8766479	0.31
541.6171265	0.10
542.9875488	0.86
548.1749878	0.57
549.3165894	4.25
561.1564941	0.35
563.3250122	66.62
571.6422119	0.06
578.2070923	0.09
579.4335327	0.34
580.0982056	0.11
589.3186035	0.57
591.3359985	0.14
596.4525757	0.06
603.2870483	4.09
605.6781006	0.13
606.4027710	0.08
615.2771606	2.54
618.2131958	0.48
619.0628662	0.05
621.4121704	0.13
622.2791138	0.31
628.3373413	0.38
629.2880249	0.10
632.5350342	0.38
633.3826294	0.66
634.5625610	0.08
635.6396484	0.25
646.5084229	0.29
647.2124634	0.34
649.3676758	0.04
650.2655029	0.34
664.9973755	8.49
665.6342163	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.215
Annotation	Troxerutin
Peak:m/z	Relative Intensity
253.0872803	0.21
257.1357727	0.11
267.9345398	0.06
269.2077026	0.41
271.4265137	0.12
283.1852112	0.09
295.3021545	0.18
305.0482483	0.12
313.2521362	0.10
314.4091797	0.24
328.1089172	0.11
329.1339111	0.50
333.3414307	0.04
344.1249390	0.05
344.7977295	0.32
357.2326050	0.18
359.1325684	1.48
360.2518311	0.64
373.0834961	0.12
375.1168823	0.07
379.2893677	0.17
396.0921631	0.09
411.4425659	0.09
415.4602661	0.24
417.3555298	0.72
433.1798096	0.06
441.2386475	0.14
459.2800903	3.01
475.3956909	0.07
489.6667480	0.10
493.5473633	0.19
501.2672119	1.30
516.2630005	0.21
518.2398071	0.06
521.4442139	0.13
535.2150269	0.13
541.2318726	0.12
554.3398438	0.13
561.2583618	0.27
564.4362793	0.27
569.7003784	3.62
570.4785156	0.16
579.3313599	100.00
603.3203125	0.10
615.6923218	0.25
621.2762451	30.11
621.9359741	0.08
633.2882080	0.10
635.3142700	0.46
636.2078247	0.17
661.4006958	9.87
662.6079712	0.37
665.4871826	0.25
678.3499146	0.11
679.4035034	0.04
705.3382568	0.09
723.2656250	79.03
724.0594482	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	931.2885
Annotation	Orchioside A
Peak:m/z	Relative Intensity
284.1085510	0.01
299.0440063	0.07
300.2931519	0.06
301.2525940	0.05
462.3304443	0.03
463.2448730	0.03
468.2921753	0.02
504.8422241	0.06
505.5841675	0.02
624.4742432	0.01
677.1862793	0.01
886.7324219	0.03
913.5343018	0.02
931.3164062	100.00
931.9516602	0.45
934.9089966	0.01
940.0312500	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.246
Annotation	Swietmanin D
Peak:m/z	Relative Intensity
195.2826080	0.02
268.3870850	0.08
284.0609131	0.20
285.0460815	0.11
285.7375793	0.03
297.1752930	0.31
298.1575623	0.04
299.1989136	1.23
300.1481323	0.14
301.0796509	0.03
341.4833374	0.06
344.0816650	0.02
353.0640259	0.06
359.0609131	0.07
387.3297119	0.11
445.2684326	0.03
449.2765503	0.02
461.3671875	0.01
488.4260864	0.01
490.2952881	0.05
500.3361816	0.08
539.3861694	1.61
540.3988037	0.44
551.2751465	0.43
552.6958008	0.08
553.3780518	0.01
554.3475342	0.13
555.3522339	0.17
565.8514404	0.16
566.6315308	0.04
569.5765991	0.02
577.2133789	0.03
583.3624878	100.00
584.3574829	22.65
589.4181519	0.03
591.3731079	0.17
592.1879272	0.22
595.3874512	0.07
596.4318237	0.04
609.4304810	1.55
610.4776611	0.24
612.2940674	0.02
628.2841187	0.50
629.4066772	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.2032
Annotation	Stecholide J
Peak:m/z	Relative Intensity
159.3020325	0.03
162.7444763	0.04
171.2318878	0.02
190.9830627	0.07
194.9517517	0.02
197.2941895	0.02
201.2428589	0.10
211.0320435	0.02
213.1926270	0.02
223.3723145	0.02
227.2202454	0.11
229.3065491	0.08
231.1162109	0.13
240.1315460	0.02
245.2086792	0.05
246.9901428	0.02
261.1138000	0.02
267.2401733	0.14
283.2542725	0.17
285.3455811	0.09
286.9492188	0.03
291.2085571	0.04
293.2954102	0.11
294.2478027	0.22
295.2861328	0.03
297.3277893	0.11
299.3294373	0.08
303.4193726	0.02
305.3141174	0.04
307.1854248	0.04
309.3777466	1.07
311.4263306	0.56
321.2796021	0.09
323.1749878	0.17
327.3566895	0.32
329.4257812	0.12
331.4011841	0.10
335.3027954	1.79
337.2331543	0.11
339.5465088	0.09
343.3637695	0.08
345.0802002	0.20
351.3342896	0.34
353.3728638	7.48
355.1814575	2.02
363.3894043	0.03
369.3000488	0.66
371.5935669	0.06
373.2833252	0.38
379.4280396	0.61
385.1633911	0.07
387.3513184	0.03
395.2769775	0.03
397.3017578	21.51
397.9168091	0.06
405.3152466	0.03
411.3923950	0.50
413.4887085	0.18
415.2683105	2.18
417.7261963	0.38
429.5269165	0.03
431.5333252	0.07
433.4845581	0.04
439.3919678	0.53
441.2856445	0.52
454.3571777	0.06
455.2160034	0.11
457.3425903	22.44
459.4455566	0.28
461.5223999	0.05
471.1746216	0.04
473.2624512	0.33
485.5070190	0.16
498.9240723	0.09
501.3290405	100.00
503.3058472	0.19
513.0485840	0.04
517.1082153	0.14
527.2239380	0.03
546.2040405	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1195.6118
Annotation	Unknow
Peak:m/z	Relative Intensity
578.5319214	0.05
596.4877930	0.07
742.8986816	0.05
850.6933594	0.03
853.6019287	0.21
871.2164307	0.11
890.8015137	0.05
1033.5020750	0.13
1066.4571530	0.04
1160.7211910	0.08
1195.5388180	100.00
1196.6778560	23.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.2537
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
249.0531464	0.03
265.4313660	0.05
291.1434021	0.03
301.1329041	0.14
313.6361694	0.05
329.4259033	0.09
381.2324829	0.07
384.1425781	0.09
385.3088989	0.09
388.2037964	0.06
395.6635132	0.11
404.1163330	0.15
414.4974976	0.18
415.3967896	0.05
424.2999268	0.08
427.4737549	0.03
433.1162720	0.04
442.2752686	0.28
443.3034058	0.19
445.4248047	0.05
446.3452759	0.04
447.5401611	0.19
448.5031128	0.05
454.4085693	0.08
459.3870850	0.20
460.1254272	0.11
461.3967896	0.05
463.0635986	0.21
473.5927734	0.86
474.4156494	0.38
475.4594116	1.25
476.5534058	0.33
477.3762817	0.06
482.5214844	0.26
483.3416748	0.06
487.3730469	5.61
488.4328613	0.83
489.6326294	0.13
491.4334717	0.26
492.3679199	0.06
501.5069580	1.27
502.2800903	0.15
503.5734863	0.31
504.6934814	0.34
505.5112305	0.07
506.3589478	0.36
507.1434937	0.12
512.1284790	0.09
513.1408081	0.19
515.2965088	0.28
517.2603149	0.32
519.3775024	18.92
520.3724976	2.94
529.3361816	3.46
530.5395508	0.76
531.4653931	0.13
533.3633423	0.64
534.3945312	0.45
545.3585815	0.09
547.3817749	100.00
548.4198608	14.83
550.3197632	0.20
551.4056396	0.80
552.5517578	0.03
557.4609985	0.36
561.3994751	3.82
562.3770142	0.88
564.6017456	0.09
574.2603149	0.11
575.4923096	2.67
576.4797974	0.53
579.3869019	91.06
580.3994751	14.61
581.1564941	0.08
589.3728638	4.59
590.5233765	0.53
608.5046387	8.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.2205
Annotation	Quercetin-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside
Peak:m/z	Relative Intensity
269.2863464	0.02
286.2420044	0.03
299.2745667	0.04
301.1627197	9.11
305.156311	0.03
308.2683411	0.03
325.0101013	0.05
342.9374084	0.02
382.9732666	0.02
401.3544312	0.05
408.303894	0.02
426.1644897	0.10
436.9058228	0.02
445.3233643	0.23
461.2332153	0.10
463.2824707	20.24
487.2298584	0.03
505.2374878	10.67
529.3238525	0.21
534.2259521	0.03
535.2279053	0.03
543.2797241	0.02
545.3272095	5.16
546.2200317	0.13
547.2091675	0.27
563.1873779	0.02
569.4330444	0.12
571.3972778	0.07
576.0440063	0.02
587.4630737	0.01
589.1107788	0.11
590.1334229	0.04
607.3016968	12.26
612.7449341	0.05
616.0791626	0.02
617.7006226	0.06
625.3533325	0.06
649.138855	0.60
663.5255127	0.04
667.4552612	0.27
685.3348389	0.01
691.4721069	0.09
703.6740112	0.08
707.6878052	0.07
709.4483032	0.07
725.7455444	0.03
746.9628296	0.07
750.5071411	0.02
769.2214966	100.00
769.9223022	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1113.3054
Annotation	Unknow
Peak:m/z	Relative Intensity
311.3193970	0.01
314.1894226	0.00
316.0442505	0.07
316.9884338	0.04
328.1899414	0.36
329.2450562	0.11
331.1374207	1.66
332.1261902	0.79
341.4038696	0.02
342.0089111	0.01
343.1036987	0.01
345.1424866	0.05
346.1966553	0.48
347.1773376	0.27
349.2201843	0.01
351.0494080	0.02
361.2421875	7.33
362.1846924	3.89
363.2445068	0.01
365.2527466	0.01
367.1943359	0.01
369.1326294	0.02
370.3222656	0.00
372.2637329	0.00
373.4270630	0.01
374.2876892	0.01
375.4394836	0.03
377.9718018	0.01
385.2192993	0.02
387.2825928	0.05
388.3921814	0.03
389.0518799	0.01
393.1928101	0.03
397.1623535	0.03
400.4141846	0.01
403.6033936	0.02
404.3972168	0.01
405.4525757	0.01
406.3002930	0.01
408.0928040	0.00
409.4760742	0.01
411.2032471	0.02
412.3842468	0.05
413.3924255	0.01
414.8804932	0.05
415.5963440	0.00
417.9337158	0.03
421.2024841	0.02
423.2525024	0.02
424.3650513	0.01
428.5101929	0.00
430.2929688	0.01
433.3809814	0.01
435.2829590	0.01
436.2268677	0.02
437.1832581	0.01
439.2516785	0.03
440.4205933	0.02
444.0885620	0.04
447.2781677	0.02
449.3725586	0.00
451.3063965	0.08
452.2346191	0.14
453.4564514	0.00
457.3953247	0.01
458.3417358	0.01
459.0960693	0.01
460.5707092	0.02
463.1957703	0.01
465.2517395	0.01
466.1742554	0.00
469.1385498	0.16
470.2874146	0.20
471.0542603	0.00
472.2395325	0.01
487.2410278	0.08
488.3755188	0.03
490.2977600	0.01
491.3504639	0.00
499.9113464	0.01
504.4890442	0.01
505.3576965	0.01
506.2419739	0.01
512.7231445	0.01
514.3707275	0.01
520.7749023	0.01
523.0664062	0.04
524.3444824	0.00
528.5390015	0.02
529.4920044	0.03
530.5183105	0.02
531.3759766	0.01
532.2191162	0.01
536.2949219	0.00
538.1168213	0.02
545.4648438	0.01
549.3776855	0.05
550.3679810	0.01
555.7690430	0.01
556.3822021	0.01
558.5334473	0.01
560.6021729	0.00
566.1577148	0.01
568.4893799	0.01
569.6234741	0.03
570.4107056	0.02
572.5470581	0.01
573.1870117	0.01
574.6060791	0.02
575.8013916	0.02
576.4339600	0.00
579.9879761	0.01
581.1882935	0.01
582.3697510	0.01
583.0866699	0.01
583.9737549	0.01
586.1088867	0.01
587.9943848	0.01
590.2320557	0.01
595.1985474	0.00
596.2735596	0.00
598.0682373	0.04
603.5505371	0.03
605.2032471	0.21
606.3124390	0.36
613.4421387	0.01
614.2921753	0.03
619.4299316	0.05
620.3071899	0.06
631.6725464	0.08
632.6110840	0.01
636.3020630	0.00
637.2639771	0.03
638.4475708	0.07
645.0916138	0.02
649.2522583	0.34
650.2969360	0.33
667.2498779	0.23
668.3385010	0.35
674.2872314	0.02
680.2125244	0.00
681.3028564	0.03
682.4371338	0.03
683.4745483	0.01
699.7141724	0.02
700.3463135	0.03
709.3028564	0.10
710.3596191	0.08
716.1385498	0.01
717.5633545	0.01
718.1882324	0.01
722.7116699	0.00
727.5479736	0.01
734.0617676	0.02
739.3654785	0.04
740.2990112	0.04
745.2462158	0.10
746.3996582	0.16
752.6893921	0.02
757.6634521	0.06
758.3806763	0.13
760.3756104	0.00
763.4564819	0.04
764.3565674	0.05
766.3378906	0.01
769.2854614	0.18
770.3901367	0.16
774.6526489	0.02
775.3784180	0.86
776.3905029	1.79
777.8989258	0.01
781.2823486	0.08
782.2707520	0.10
783.6553955	0.01
793.1972656	0.41
794.3112183	0.96
811.1730957	0.81
812.2371826	1.41
884.1900635	0.01
901.2053223	0.01
944.6123047	0.00
946.3215332	0.01
1006.2514650	0.01
1024.3415530	0.02
1042.5974120	0.01
1060.5239260	0.06
1078.2526860	0.14
1096.3321530	0.09
1112.1160890	0.02
1114.1562500	100.00
1114.8614500	0.17
1115.6219480	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1827
Annotation	Unknow
Peak:m/z	Relative Intensity
153.1071472	0.11
171.0567322	0.38
172.9110107	0.24
188.9683075	0.07
190.9864502	100.00
192.0901794	0.99
193.0927734	0.12
297.2649536	1.05
298.1472473	0.74
299.2990723	2.55
322.1046753	0.05
323.1936646	0.10
339.4704895	0.10
341.3395996	0.31
353.3555908	0.19
358.0244751	0.09
363.2655029	0.22
375.2580872	0.09
395.3764343	0.12
396.1903992	0.60
410.3463135	0.09
412.0583191	1.05
413.2439880	0.71
419.2398682	0.05
444.1223145	0.39
446.5437927	0.32
457.3446350	0.77
471.3637390	0.13
472.2676392	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1876
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9666443	0.30
142.9511108	0.36
149.1267242	0.09
152.9684143	0.15
155.0976562	0.10
160.8741455	0.53
166.0423584	0.05
178.8667297	0.36
187.0097351	0.29
190.8706970	0.05
197.0062561	0.09
203.0553589	0.08
211.1677399	0.09
221.0570526	0.53
222.9668274	0.12
224.5129089	0.31
227.1774292	0.22
245.2016907	0.27
251.1748962	0.05
253.1886597	0.08
254.4097290	0.21
255.0382080	0.10
265.2914124	0.05
271.2033997	0.99
272.2258606	1.63
273.3185425	0.45
278.2408752	0.17
281.2763062	0.08
287.8731995	0.09
291.2583008	0.46
300.0829468	0.05
313.1788940	0.09
314.2767944	0.11
314.9318237	0.12
319.3012085	0.17
329.1154175	9.49
331.2226562	7.57
347.3784485	1.02
349.2282104	4.92
349.8477478	0.09
354.5586548	0.29
356.8529053	1.02
370.3399963	0.14
375.0077820	0.18
380.3630066	0.07
386.0025330	0.30
387.5655823	0.29
389.1114197	41.69
391.1405640	100.00
391.8351746	0.07
395.9817200	0.11
397.0415344	0.04
398.2483521	0.07
405.2433472	0.07
416.3832397	0.62
417.2730408	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0673
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
110.8086243	1.15
128.9523926	2.63
134.0350952	0.71
144.0852051	0.05
144.9641113	0.17
146.9924927	4.91
149.0823975	0.34
153.0501404	0.07
154.8407898	0.20
160.0260620	0.09
163.0117950	0.95
172.9940186	3.45
175.1004791	0.79
177.0929260	0.02
177.9241333	0.22
178.8858490	0.10
183.2090454	0.13
187.2134094	0.10
190.9413452	100.00
193.0506897	11.73
207.1064758	0.04
208.9960175	44.92
225.0439148	0.13
226.1599121	0.05
229.0800476	0.03
238.1712952	0.06
251.0677490	0.03
253.0466309	0.21
254.0124207	0.10
254.9813843	0.03
259.2168579	0.03
265.2227783	0.06
269.0918579	0.40
275.1692810	0.13
279.5025024	0.04
282.9247131	0.02
291.2526855	0.07
293.1452637	0.56
294.3114319	0.06
295.1035156	0.02
296.4028931	0.15
297.3583069	0.89
301.1961060	0.10
308.0623779	0.17
309.1315918	0.51
311.0438538	0.09
316.1346130	0.13
319.1697083	0.07
321.4239502	0.19
323.1549377	0.04
336.2362061	0.96
337.1571350	8.07
338.3689270	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1698
Annotation	Benzyl gentiobioside
Peak:m/z	Relative Intensity
122.9270401	0.68
124.7761230	0.09
126.8470764	0.34
131.0471191	0.61
136.9568481	0.65
138.9487000	0.33
142.9506683	0.43
144.8314514	0.37
146.9931946	0.41
149.0266724	19.02
151.0794220	0.11
154.9966888	0.11
159.3086090	0.69
160.7222748	0.40
163.1572723	0.24
166.9468689	16.57
168.1203461	0.15
173.0671692	0.81
174.8257751	0.55
177.0350952	0.31
180.4434357	0.21
182.8155212	0.09
184.9376221	44.99
189.0475616	0.15
191.0140228	0.41
199.0105743	0.14
203.2560730	0.62
207.1152802	0.56
210.1325073	0.51
212.8845215	0.39
215.2147675	1.83
222.9403381	0.26
225.0755768	0.65
229.2162018	0.95
230.9349365	4.87
232.2858124	0.49
232.9224243	0.43
235.0970459	0.41
236.9740601	0.10
239.2248535	0.36
245.0644836	0.27
247.0949402	0.30
247.7005615	0.12
249.0320740	2.31
252.2395935	0.20
253.3078308	0.36
257.0902100	1.16
265.0479736	0.12
267.2662964	0.07
270.9476929	1.31
275.2852783	1.60
276.9279175	0.81
278.8069458	0.25
280.2023315	0.15
282.4670105	0.33
283.1532288	2.09
284.1755981	0.09
285.0422058	0.91
287.1135254	0.11
288.3172302	0.09
291.0906982	0.44
293.2517090	0.40
295.2077942	2.69
297.0854492	0.11
299.0258484	0.40
300.1991882	0.50
301.2666931	0.72
307.2310791	0.43
313.1439209	21.42
313.7512207	0.05
319.0465393	0.15
323.4785767	0.18
325.3019104	0.16
326.0706177	0.50
327.6153259	0.34
333.1542053	0.11
335.2315674	0.38
337.1437073	14.81
341.0411377	0.07
343.1581726	1.09
345.3787231	0.07
347.1113281	8.05
349.1700439	0.37
351.3962402	0.30
352.2554932	0.81
353.2138672	2.91
354.0581970	0.28
355.1747437	1.07
359.8878479	0.10
361.2471313	0.79
362.1491394	0.15
363.2227173	0.18
364.9877014	0.24
367.1999817	27.48
370.2215271	0.55
371.1778259	0.71
372.8641968	0.22
373.5511169	0.07
375.1943665	1.83
375.8481140	0.09
377.3942871	0.17
379.0550232	17.57
379.6937256	0.52
383.9073181	0.42
385.3570862	0.23
387.0429382	0.36
389.0708313	9.85
390.2206726	0.08
392.2262268	0.59
394.7970581	0.17
396.5765686	3.36
397.2304077	31.04
405.0440674	0.83
410.3395691	0.25
415.1126099	100.00
416.0754089	0.69
417.3207092	1.00
418.2409973	0.24
419.2229919	0.31
429.3268433	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.1596
Annotation	Chrysosplenoside E
Peak:m/z	Relative Intensity
219.3281555	0.02
289.2630920	0.02
319.2582397	0.02
327.0803223	0.06
345.1843872	0.05
360.1579590	0.48
375.1525269	100.00
376.0302734	0.00
447.0062866	0.03
494.6808472	0.04
500.3445435	0.01
501.6583862	0.03
505.4501953	0.02
518.7490234	0.07
519.4381714	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.19
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9297104	0.04
132.0708313	0.04
142.2847595	0.04
160.8190918	0.05
178.3177948	0.08
183.2478027	0.04
184.8512878	0.07
208.1690674	0.18
210.2877502	0.06
219.7158508	0.11
269.4523010	0.08
273.0643921	2.21
292.9588318	0.05
297.1388245	2.11
297.7957153	0.09
300.0978394	0.14
313.2518005	3.11
327.0124207	0.16
329.1835022	0.43
330.0373840	0.13
331.3165588	0.69
341.1764526	100.00
343.0283203	0.73
354.9444885	0.14
358.1835327	21.07
359.2404480	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	907.5746
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
313.2329712	0.26
393.2090149	0.04
436.2772827	0.31
440.0422974	0.05
454.1859741	0.88
627.7433472	0.12
845.8488159	0.21
863.7647095	0.05
870.3975220	0.03
874.4967041	0.05
888.9729004	0.15
906.5528564	5.77
907.1957397	100.00
908.0197754	0.03
909.1386719	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.387
Annotation	Phepropeptin D
Peak:m/z	Relative Intensity
299.1770020	0.26
317.0455322	0.22
385.3364868	0.16
401.6169434	0.06
475.3908081	0.06
479.3559570	0.18
481.4486694	0.60
499.4447021	2.38
521.2302856	0.15
527.3710938	0.12
547.4071045	0.25
563.2977295	0.23
571.4246826	0.12
577.3056030	0.08
619.4786987	1.19
637.3948364	0.32
661.5902710	36.20
679.1710205	1.11
679.7839966	0.18
707.1892700	0.26
721.3501587	4.02
729.1083374	0.05
735.7039185	0.08
767.3353882	100.00
768.3163452	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.1907
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
217.1763306	0.03
227.1580658	0.03
274.2878418	0.03
298.0376587	0.09
300.9926758	0.09
307.0429077	0.04
315.2280273	0.05
316.2086182	0.24
317.0023193	0.03
327.1420288	0.03
328.8231812	0.03
331.1321411	11.71
332.1760559	0.24
333.1712646	0.13
343.0669556	0.04
361.1408691	0.24
362.0214844	0.03
362.9230957	0.07
391.4650879	0.01
416.1159668	0.05
441.1072998	0.06
444.5980225	0.03
445.2828369	0.03
448.1900024	0.03
450.0567017	0.02
451.2348022	0.04
454.3726196	0.09
459.3374023	0.06
476.2442017	0.06
477.1801758	0.32
481.2878418	0.04
493.1689453	100.00
500.6754150	0.05
508.9971313	0.01
519.0523071	0.08
549.1600342	0.08
555.5876465	0.06
557.4206543	0.20
559.7442017	0.02
566.3530273	0.02
578.1423950	0.06
582.6346436	0.04
589.6354370	0.01
620.1614990	0.10
621.2089233	0.21
639.1099243	0.06
640.3067017	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1802
Annotation	Spinosin
Peak:m/z	Relative Intensity
187.1477051	0.19
199.3480072	0.21
227.2629089	0.15
256.0189819	0.07
258.1495361	0.43
259.1268921	0.08
270.3660278	0.64
272.1811218	0.10
286.0464478	7.92
287.1920166	5.63
288.3329163	0.12
294.2867432	0.11
301.1404419	84.30
302.0887451	100.00
303.2214966	10.00
323.4147949	0.11
326.3122559	0.36
343.1753540	0.91
344.1610107	0.69
345.2347412	1.32
347.2327881	0.16
361.2213135	4.79
362.0183716	0.06
367.0307007	0.35
368.0827637	0.53
369.4379883	0.50
379.3641968	0.48
392.2763672	0.08
401.4809570	0.27
408.9394531	0.42
410.2631226	1.76
411.2511597	0.91
423.3189087	0.17
427.0629883	0.08
428.2282104	0.14
441.6012573	0.06
445.2546387	0.25
446.4926758	0.13
452.5545654	0.19
456.2626343	0.50
462.2987671	0.28
463.2292480	1.33
464.3623657	0.92
465.2479858	0.16
487.4475708	0.13
505.3628540	0.09
510.9382935	0.11
518.2301636	0.14
520.4358521	0.07
523.3309937	2.67
529.4014893	0.12
536.7582397	0.34
546.1818237	4.96
547.4351196	0.51
554.6204224	0.31
565.3771362	1.00
567.3810425	0.06
572.2272949	3.61
573.1702881	1.44
577.2877197	0.12
590.0234375	6.02
590.9665527	4.24
591.7244263	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	309.12
Annotation	Antibiotic DO 248B
Peak:m/z	Relative Intensity
88.9868546	0.39
100.9563675	1.85
107.0230103	0.20
112.9913788	1.97
115.2102203	0.16
117.2214355	0.10
118.9246979	2.65
124.9014206	0.41
129.0006409	0.05
130.7653198	0.59
143.0466919	1.91
146.8942566	0.05
148.3737183	0.11
148.9927368	0.77
160.9714508	2.23
162.0313416	0.06
178.3985596	0.12
179.0345306	0.30
191.0274963	0.07
192.9846802	0.07
219.1025391	0.07
221.2189331	0.05
237.1049805	0.71
246.0575867	0.04
251.3895264	0.04
256.4022827	0.07
263.1679688	100.00
264.1416321	0.16
265.0182495	0.19
271.8648682	0.12
290.0731201	0.20
291.2684937	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.77
Annotation	Unknow
Peak:m/z	Relative Intensity
506.2733765	0.03
521.2117310	0.05
886.9287109	0.02
1042.0454100	16.60
1042.7086180	100.00
1043.6530760	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1696
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
108.8089294	0.03
116.0374298	0.08
122.0837479	0.08
123.0043259	0.06
123.8253784	0.07
135.8889771	0.09
139.0287323	0.02
142.0623169	0.04
144.5661316	0.12
147.1825867	0.03
154.8435822	0.03
158.1900024	0.02
166.0730896	0.40
172.4328156	0.19
173.1716919	0.05
174.0783691	0.31
184.0358429	1.42
185.0234375	0.09
193.0523071	0.02
202.0838470	4.89
220.0327301	100.00
226.5904236	0.04
230.9930115	0.01
235.1052246	0.05
251.0720520	0.08
251.9400635	0.03
253.2813721	0.13
260.2189941	0.08
261.0541382	0.09
272.2052612	0.05
273.1450806	0.05
276.4559326	0.02
281.2346802	0.05
292.7243347	0.07
297.3402710	0.10
298.4380493	0.06
301.3862610	0.05
301.9984131	0.01
304.5506592	0.10
306.9664612	0.13
310.3283691	0.04
315.9611816	0.08
317.1322327	0.07
318.1692505	0.11
322.5189209	0.05
325.1217346	0.07
328.3167114	0.06
336.0101318	0.06
337.7784119	0.05
338.4660339	0.09
341.2800293	0.05
342.9344482	0.11
345.4848022	0.06
346.7190247	0.28
349.9442749	0.05
359.1295471	0.09
359.9392090	0.19
362.2096863	0.14
363.1554260	0.54
363.8211060	0.24
364.4484863	0.61
372.4143372	0.23
393.0848389	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.1488
Annotation	6''-O-(3-Hydroxy-3-methylglutaroyl)astragalin
Peak:m/z	Relative Intensity
179.8635254	0.02
241.2634888	0.01
254.2561188	0.03
280.3244629	0.01
284.1780396	0.40
287.2426758	0.04
297.1708679	0.01
303.4187012	0.02
312.2058716	2.92
313.1618042	0.02
315.0322876	0.02
327.1491699	0.01
329.1950684	0.08
330.1981201	2.58
332.4054565	0.01
342.2006836	0.03
345.1310425	100.00
346.0140991	0.02
361.1976318	0.03
383.3080444	0.02
409.3773804	0.02
412.0510864	0.03
413.2181396	0.16
423.4258423	0.05
460.0285034	0.02
496.2697144	0.02
505.0473633	0.01
507.1820679	0.10
513.3010864	0.04
529.4706421	0.02
530.7348022	0.03
531.3941040	0.03
534.5664673	0.05
547.6517944	0.05
548.6757202	0.41
549.3125610	4.02
560.4218750	0.03
574.3198853	0.23
575.3781128	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.2303
Annotation	Methanofuran
Peak:m/z	Relative Intensity
258.2321167	0.04
281.9876709	0.02
283.0178223	0.03
285.0009155	0.02
301.1526489	0.60
311.3012085	0.01
315.2028809	0.11
325.3282776	0.01
337.4254761	0.02
341.0101929	0.02
343.1484375	0.07
355.2017822	0.02
357.4160156	0.06
367.3113708	0.04
383.2686157	0.03
385.5692139	0.01
429.7008667	0.01
433.4345093	0.03
441.3445435	0.01
445.3922729	0.01
447.4116821	0.06
469.2268066	0.02
481.2611084	0.05
483.3745117	0.06
489.2628174	0.23
503.5001831	0.04
522.5477905	0.04
576.5559692	0.02
591.2869263	0.31
609.3588257	1.04
617.0495605	0.01
623.2167358	0.13
639.3012085	0.01
649.2938843	0.19
738.2503662	0.07
739.3792725	0.02
753.7422485	0.05
754.3969116	0.02
762.7715454	0.01
767.4096069	0.12
785.3472900	100.00
786.3187866	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2758
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
135.1717224	0.10
138.9646301	0.08
145.0345306	0.21
146.9928894	0.41
149.1048889	0.49
154.8636169	0.39
158.7971497	0.41
161.0683289	0.42
163.0783234	0.51
167.3549957	0.08
169.2283173	0.18
172.9279175	0.60
175.3422852	0.22
177.2600403	0.24
180.0200195	0.11
182.9590302	0.42
187.1459045	0.26
188.9943848	0.22
190.9841614	0.17
195.0410461	0.09
198.0298767	0.31
198.9620972	0.11
212.5469055	0.25
216.1330719	0.16
219.0931854	0.03
221.2658539	0.05
227.1472778	0.30
233.4128723	0.44
243.2639923	2.70
257.2947998	0.11
259.3078613	0.06
261.1615906	7.71
271.3114929	0.13
273.2432556	0.16
275.4605103	0.45
276.4034119	0.19
279.2100220	0.09
292.8892822	0.16
299.0154724	0.34
304.3656921	3.06
307.0903931	0.10
317.3123474	1.80
318.9711609	0.22
335.3160400	83.12
335.9318848	0.40
347.3471069	0.06
369.6555176	0.13
397.3963623	0.09
415.2270203	11.47
420.1040039	0.15
429.4256592	0.66
433.3769836	1.36
440.3461609	0.58
441.5767517	0.08
448.4351196	0.26
458.2638855	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.91
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9608002	0.12
130.8930359	4.36
140.9755249	0.13
146.8350525	1.51
149.9810181	0.16
153.1841736	0.05
158.9428558	4.65
159.9000549	0.06
172.9537048	0.11
174.8852081	100.00
176.1699066	0.09
188.9903259	0.12
190.7908630	0.45
214.5148621	0.05
215.2371216	0.12
220.0976562	0.09
229.8590698	0.22
230.9297180	2.66
243.5282593	0.09
247.2055054	0.07
248.9728088	0.73
251.8047485	0.14
258.2906799	1.12
259.0698853	1.21
259.9275513	2.00
260.8499451	11.80
276.9804382	1.78
282.1651917	0.02
291.6903687	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2121
Annotation	Unknow
Peak:m/z	Relative Intensity
140.8302002	0.02
143.0285950	0.35
145.0188293	0.05
146.7622681	0.24
148.8326569	0.09
150.0921021	0.34
152.0032043	3.07
159.0920105	0.04
160.9613953	0.08
163.1904144	0.10
163.8936768	0.06
164.8116760	0.20
167.9627380	22.51
168.9925232	0.03
170.9806824	0.09
175.1655426	0.05
177.0029602	0.05
179.1123352	0.25
180.9711304	0.04
182.1548462	0.09
184.8952332	0.03
189.1611633	0.22
207.3486023	0.03
210.0604248	0.57
213.1376038	0.10
214.9324341	0.04
216.9156952	0.09
219.2526093	0.09
223.2513428	0.27
224.2646027	0.12
227.1961365	0.50
230.0977631	0.11
231.2285309	0.05
243.1046753	0.13
244.2329407	0.04
245.0222015	0.06
254.3212280	0.39
254.9942322	0.33
257.0144043	0.20
267.1356812	0.21
268.1783752	0.10
271.1663208	0.12
273.0054626	0.21
277.9974365	0.09
278.8900146	0.30
280.2274170	0.45
287.3170166	0.24
289.2231445	0.08
290.2001648	0.10
292.1057129	0.05
296.1397095	0.07
298.2255249	1.08
301.2131348	0.15
308.1075439	1.35
309.1286316	0.48
311.2401428	0.21
312.2485352	0.23
313.0768433	0.47
314.3479309	3.54
326.4168091	0.34
327.3441467	0.38
330.0957642	100.00
334.2712097	0.10
342.1479797	0.20
343.0754395	0.14
347.0259399	0.41
369.4122925	0.08
370.4795532	0.06
373.4164429	0.04
383.2848206	0.08
386.1559448	0.31
387.3218079	0.14
389.4596863	0.19
390.5218201	0.30
394.9924011	0.16
398.1323853	0.18
400.2889709	0.05
401.2340393	0.24
403.3646545	0.08
410.6529846	0.07
414.2112122	0.67
418.3920288	8.83
422.3319702	0.14
422.9364319	0.05
429.7554626	0.20
431.2912292	1.14
432.2826843	0.76
440.0435486	0.05
440.6736755	0.08
443.4190674	0.22
447.1690674	0.19
457.4103088	0.40
458.2101440	4.31
459.1592712	0.19
467.0650330	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	283.1552
Annotation	Minwanensin
Peak:m/z	Relative Intensity
132.0972443	0.01
157.1846008	0.04
167.2549896	0.04
179.2358856	0.16
203.0220947	0.01
211.2059631	0.01
215.2287598	0.04
223.1376343	10.18
227.8989258	0.02
237.1302185	0.02
239.2949524	0.01
241.1402588	100.00
247.2293091	0.02
247.9704590	0.04
252.1557007	0.02
253.2159424	0.01
255.1233521	0.08
256.1809082	0.02
265.1847534	0.04
268.2589417	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0555
Annotation	Fludiazepam
Peak:m/z	Relative Intensity
94.9212875	1.76
96.9116669	0.10
112.9328461	14.61
113.9461365	3.49
118.9978027	0.13
130.9750977	100.00
136.9804382	0.07
145.1565857	0.05
151.2006836	0.05
165.0628510	0.11
199.0886230	0.24
214.9345093	0.06
223.8663330	0.08
224.8832397	0.08
226.2124634	0.27
227.4762268	0.08
233.1801453	0.04
241.8130188	0.15
257.0198669	0.08
273.4855347	0.04
283.0093384	2.52
286.1408081	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	829.2366
Annotation	Isorhamnetin 3-[2''-(4'''-acetylrhamnosyl)-gentiobioside]
Peak:m/z	Relative Intensity
243.1341248	0.15
244.1712646	0.05
265.2684937	0.04
272.2120972	0.04
281.4810791	0.04
284.9313660	0.04
288.0924072	0.05
299.2653198	0.06
300.1741943	0.32
303.1487122	0.40
304.1743774	0.04
313.0237122	0.13
316.1215210	0.38
317.0563965	0.02
328.1507263	3.26
329.2085571	0.03
331.1094971	7.28
332.1860657	0.14
342.9408569	0.07
346.1730042	4.31
347.1521606	0.08
361.1558228	100.00
362.2158813	1.38
403.1306152	0.03
521.4105225	0.04
523.1322021	60.98
524.2006226	0.57
581.7258911	0.04
585.0979614	0.06
591.4448242	0.02
647.4736328	0.03
649.1966553	0.03
667.1022949	7.16
668.0574951	0.24
672.3094482	0.04
684.9506226	0.05
700.3621216	0.05
749.3027344	0.11
756.8682861	0.03
767.1293335	0.02
775.2389526	0.07
793.3283081	0.08
811.2879639	0.66
812.5866089	0.04
829.5664673	0.20
830.1977539	6.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.2241
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
145.0915985	0.05
151.0231934	0.12
155.0292969	0.06
157.1564026	0.05
158.9635010	0.11
161.0494995	0.13
163.1268616	0.03
165.0342712	0.54
169.1376648	0.29
173.1018677	0.23
176.0445862	0.18
177.1680450	0.19
179.2390594	0.20
183.1253967	0.20
187.1629333	0.20
189.1238403	0.05
193.0820007	0.63
194.0180054	0.06
195.0668793	0.26
197.3081665	0.12
199.2179260	0.03
201.2598877	0.06
203.0336151	0.34
205.3280029	0.10
206.9551697	0.13
211.0932159	0.21
213.0662231	0.57
216.2758179	0.11
217.1100464	0.26
218.2285767	0.07
219.2673492	0.23
221.1632538	0.13
223.3633423	0.05
225.2308197	0.34
227.1936951	0.92
229.1496887	0.30
231.2558594	1.46
233.2503357	0.92
235.2890320	0.05
243.3561859	0.14
245.2575836	0.82
247.2762756	0.15
249.1383514	1.04
251.2993774	0.03
253.1293640	0.38
259.1802979	0.37
260.2230225	0.12
261.0812378	0.23
263.2067261	0.61
265.2120972	0.07
266.0223694	0.04
269.4008484	0.07
271.1591797	1.26
275.2346191	0.35
277.2087402	0.63
279.3471680	0.06
287.3561096	0.39
289.1682129	2.44
291.0570984	0.11
293.0205688	0.18
294.1292725	0.13
295.3311462	0.37
301.3416748	0.08
303.2168579	0.07
305.3162537	0.77
306.4346313	0.46
307.2201233	1.35
309.0996094	0.04
311.2901001	0.13
323.1291504	0.42
329.2007446	0.06
330.1021118	0.08
331.4236145	0.27
333.3858032	0.27
334.9416504	0.07
337.1257629	0.08
343.1628723	0.33
345.2113953	1.52
346.2810059	0.06
348.1555176	0.16
349.3461304	0.91
351.2182617	0.64
353.3096619	0.03
359.3101807	0.11
361.5406494	0.14
364.2659302	0.03
365.3606873	0.10
367.2024536	0.06
369.3649292	0.04
375.3904419	0.04
380.1587830	0.13
383.4703979	0.05
386.4218445	0.03
387.3406677	0.08
389.2951965	0.76
392.7655945	0.18
393.3744507	0.62
402.0977478	0.07
403.4036865	0.05
405.6454773	0.10
411.3129883	0.51
419.2490540	0.16
431.2940369	0.55
445.4891052	1.49
447.2052917	100.00
447.8365173	0.29
449.4807739	0.50
459.3114929	0.03
460.3978882	0.06
463.2374878	0.74
479.2290344	0.21
489.3089905	1.24
491.0010071	0.13
493.1352844	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	893.4811
Annotation	Racemoside C
Peak:m/z	Relative Intensity
347.1184387	0.07
363.1018066	0.13
365.2930298	0.51
403.5769653	0.21
405.2731934	0.60
407.5679932	0.14
417.8413696	0.11
453.2874146	1.90
519.3584595	2.65
533.5874634	0.12
615.3500366	9.27
616.0168457	0.09
681.5100098	16.14
731.6033325	2.19
741.6379395	0.20
755.6520386	0.20
795.3577271	0.42
815.6127319	0.09
861.1007690	0.15
893.6054077	100.00
894.7262573	5.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	301.1065
Annotation	Isosativanone
Peak:m/z	Relative Intensity
107.1306610	0.01
118.9473343	0.02
120.6623306	0.04
122.9532852	0.01
141.2218933	0.01
145.2237091	0.01
146.9244995	0.06
149.1170654	0.06
157.2300110	0.01
159.0968628	0.05
171.1068420	0.07
177.1838379	0.04
180.6336212	0.01
182.8595276	0.11
185.1165619	0.02
188.9057007	0.02
189.8795471	0.04
192.1073914	0.01
197.1652222	0.03
201.0657654	0.04
211.0349426	0.02
213.0815430	0.03
215.1718445	0.05
216.3289795	0.01
217.3524475	0.03
220.9542236	0.03
225.4990540	0.02
231.0687561	0.52
232.9661865	100.00
234.0955200	0.02
239.2802734	0.01
241.1862488	0.07
243.2509766	0.04
245.0228882	0.24
255.2735596	0.15
256.8057251	0.01
259.1045837	0.29
269.4810181	0.04
273.1592102	0.25
274.1754761	0.10
282.7084961	0.21
283.8395081	0.03
286.0642395	0.99
286.9828491	0.05
300.0890503	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	547.2186
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
160.1273193	0.03
173.1390381	0.05
174.8312225	0.09
176.8799591	0.03
181.1398315	0.04
193.1648560	0.30
195.1278992	0.14
199.2542267	0.09
202.1367188	0.20
210.9700623	0.04
217.2919617	0.07
237.8458252	0.03
245.3370361	0.05
257.2518921	0.08
260.0928345	0.25
273.0711670	0.12
275.3269043	0.09
277.1874390	0.19
278.3546143	0.11
283.6019287	0.09
289.3750000	0.06
299.5081177	0.03
301.1826782	0.08
307.2543335	1.69
309.3600159	0.09
315.2936401	0.04
325.3390503	2.40
327.3723755	0.23
329.0537109	0.06
333.1013184	0.05
335.1760254	0.16
338.3038940	0.06
339.2306519	0.03
350.9674072	0.43
354.3810425	0.07
359.1613159	0.19
363.2417603	0.02
365.3236694	0.05
367.2860107	0.12
369.1743774	12.40
371.1932373	1.14
379.2934570	0.06
381.2222290	0.18
383.3593750	0.05
397.2278442	0.19
399.2449951	0.05
401.2296143	0.12
409.0767212	0.06
413.3345337	1.56
422.1087646	0.04
425.3439331	1.25
427.2698975	0.22
428.3152466	0.06
439.2490845	0.06
443.1705933	20.19
445.2214966	0.18
451.0633545	0.17
457.2473145	0.35
458.0581665	0.36
459.1221924	0.10
461.3698120	0.22
463.0980225	0.22
463.7061157	0.12
469.2767334	1.60
471.3181152	1.22
475.1885986	0.22
483.2162476	2.29
484.2330933	0.14
485.9578247	0.06
487.2623901	100.00
487.9269409	0.11
489.5919800	0.14
493.4647217	0.09
499.2985229	0.12
500.5227051	0.30
501.3677368	0.22
502.2984009	0.87
503.2669067	2.34
505.3229370	4.59
507.8746338	0.05
508.8878174	0.15
510.9266968	0.20
511.6238403	0.08
515.2666626	0.47
515.8805542	0.06
520.2410278	0.12
528.5578003	0.07
529.2464600	0.40
548.3284302	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	575.2843
Annotation	Unknow
Peak:m/z	Relative Intensity
164.8844757	0.07
179.2235260	0.06
217.7029266	0.26
233.2735138	0.37
243.2204590	0.10
257.4403687	0.51
258.5589905	0.22
261.0804443	0.13
263.1834106	0.09
279.2664185	0.09
285.4160767	0.08
287.0823975	0.12
288.4593811	0.33
290.6531372	2.33
293.0634766	0.11
294.8606873	0.05
297.1472168	0.07
302.2309570	0.12
304.9487915	0.04
312.2835388	0.14
317.7650146	0.73
319.8422241	0.14
323.7254028	0.21
327.3046265	0.09
331.1177368	0.54
334.2974243	0.25
335.2885132	0.43
341.5566406	0.08
346.4675293	0.13
347.0718384	0.11
347.7568970	0.59
353.0589600	0.05
354.3419800	0.05
355.2681885	1.68
356.7081909	0.57
359.2198486	0.28
362.4263306	0.25
371.1750488	0.05
373.2297363	0.07
378.1349487	0.86
378.8803101	0.30
382.5769653	0.23
389.6485596	0.24
390.2511597	0.05
403.3092041	0.31
407.7231445	0.12
411.5046387	0.11
412.3134766	0.16
413.9562988	0.14
415.6613770	0.12
417.2415771	0.04
420.9088135	0.89
427.9102173	0.61
429.8115234	8.37
430.5938110	0.05
433.6125488	0.11
434.5197144	0.30
436.3775024	0.06
437.4401245	0.08
438.0676880	0.12
441.2581787	0.41
446.3183594	0.09
447.6528320	0.30
452.2109375	0.34
454.4818115	0.07
456.9271240	1.29
461.5618896	0.18
462.8713379	0.13
470.2395630	0.18
472.5653076	0.38
474.1621704	0.07
480.4902344	0.11
483.9628906	0.13
485.3743896	4.43
488.9718628	0.08
492.9030762	0.24
494.3612671	100.00
495.5907593	1.38
496.7985840	1.04
499.1406860	0.25
500.2417603	0.29
511.3109131	0.13
515.7625122	0.47
519.3850098	0.29
521.4192505	0.24
524.2307129	0.41
531.4599609	0.35
535.1975098	0.12
538.1557617	0.13
539.6482544	0.42
541.1503296	0.20
547.5111694	0.11
548.5647583	0.13
555.1314087	0.04
556.5447388	0.31
557.3903809	0.91
580.4768677	0.72
588.6068726	0.06
598.3032837	2.25
599.3358154	0.11
615.4501343	0.25
618.2450562	0.08
630.3264771	0.05
635.4663696	0.26
636.6597900	0.05
638.1906128	0.07
644.1810913	0.58
652.4382324	0.20
653.7520142	0.04
680.7277222	0.18
709.4281006	0.49
712.4786987	0.50
714.3569946	0.31
718.2636108	0.13
722.5426636	0.43
727.3861084	0.39
734.4631348	0.06
750.7366333	0.14
804.6693726	0.16
832.6367798	0.14
840.6995239	0.16
857.9080200	0.17
858.5470581	3.53
859.6254272	0.27
879.4617310	0.04
912.6730957	0.14
924.8611450	0.10
969.7368774	0.36
987.5886841	29.14
988.8149414	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	989.2938
Annotation	Maltohexaose
Peak:m/z	Relative Intensity
283.3759155	0.06
285.0165405	0.05
286.095459	0.31
299.0914001	0.11
301.2182922	0.89
311.0856323	0.24
313.2947998	0.06
314.2279358	0.43
325.0812683	0.14
326.4309692	0.22
327.132019	0.05
329.1614685	6.01
343.0153809	0.41
344.0800171	10.27
359.188324	25.54
424.9215393	0.21
506.1591797	0.36
521.2651978	0.87
533.5791016	0.38
548.2731934	0.67
563.2476196	4.63
575.5926514	0.06
605.1164551	0.37
629.2699585	0.10
647.3577271	1.92
794.1091309	0.27
809.3931885	0.30
988.6911621	8.07
989.2929688	100.00
990.2370605	45.60
990.9516602	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.2707
Annotation	Probestin
Peak:m/z	Relative Intensity
160.9948425	0.05
170.8927002	0.23
179.1087646	0.24
183.8702087	0.08
186.8368530	0.15
195.0779724	0.71
196.1045532	0.08
220.0513153	0.11
224.1398163	0.15
247.1712494	0.05
255.2930298	0.09
270.8224487	0.40
275.2056885	0.99
284.2323914	0.15
288.9006042	0.07
293.2256775	100.00
293.8335876	0.15
303.2488403	0.36
307.2955322	0.13
311.4379578	0.18
315.0156860	0.06
316.4258423	0.13
317.4055786	0.82
335.3324890	0.65
337.4488525	0.07
340.7812500	0.25
347.2727356	0.32
353.2825623	0.18
355.3747559	0.13
357.0918274	0.14
365.0551147	0.07
375.1469421	0.08
377.7719421	0.12
383.3828125	0.08
395.0736389	0.35
396.1780396	0.09
407.9931335	0.32
412.2061157	0.17
438.5412903	0.21
442.5637817	0.12
447.1195679	0.24
454.2174988	0.45
454.9903259	6.82
456.2390442	0.12
463.0406189	0.27
465.2455139	1.16
467.1930237	0.06
481.4229126	0.17
483.3223267	0.16
487.4611206	0.03
492.2506714	0.36
502.1785278	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.2007
Annotation	Unknow
Peak:m/z	Relative Intensity
286.9061890	0.13
299.1617737	0.68
313.3038940	0.45
314.1007385	1.20
317.0036011	0.26
324.0994873	0.61
327.2598877	0.15
341.2131958	0.07
342.1253662	0.91
345.0867920	2.93
360.1706543	3.72
375.1663818	100.00
375.8350220	0.10
451.1107178	0.55
514.2938843	0.12
524.5051880	0.20
537.3673706	0.19
538.3472900	0.07
561.5004272	0.12
631.4893188	0.27
645.2767334	0.28
649.4322510	0.15
662.6782837	0.23
682.5222778	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.2741
Annotation	Pheophorbide a
Peak:m/z	Relative Intensity
184.0856323	0.01
237.1510620	0.01
263.2312012	0.09
264.2101440	0.03
278.5267334	0.01
283.2763672	0.09
289.3854980	0.01
301.3079834	0.01
302.0313721	0.04
323.9865723	0.05
344.2225952	0.04
351.2929688	0.01
356.3928223	0.04
360.1761475	0.02
370.1220703	0.02
375.4583740	0.03
388.4626465	0.03
389.3998413	0.13
391.3534546	0.02
399.2391968	0.04
402.3942261	0.02
414.2032471	0.04
417.8161621	0.03
424.2766724	0.04
432.3630371	0.09
433.5167236	0.19
434.2744751	0.03
435.7598267	0.02
440.5122070	0.02
446.5532837	0.03
447.3536987	0.13
448.6430664	0.03
449.4386597	0.03
452.2750854	0.02
459.3634644	0.48
460.3990479	0.50
461.3579712	1.26
462.3683472	0.56
463.0157471	0.01
464.3839722	0.05
473.3137207	2.05
474.4401855	0.71
475.4174805	0.08
476.4224854	0.37
477.3948975	0.32
478.3969116	0.06
479.3577881	0.05
486.1557617	0.01
487.3768311	0.59
488.4769287	0.55
489.4018555	0.23
490.2958984	0.04
491.3745117	0.36
492.3772583	0.93
493.4346924	0.43
494.3286133	0.07
495.1701660	0.01
497.4239502	0.02
499.4100952	0.04
501.3999634	0.03
502.6030884	0.06
503.5691528	0.31
504.5207520	0.35
505.4916382	0.44
506.4811401	0.10
507.4443970	0.02
514.4230347	0.03
515.3720703	0.78
516.3999634	0.36
517.5778198	0.22
518.4714966	0.07
519.4157104	0.32
520.4010620	0.40
521.3870850	0.33
522.5895386	0.03
529.1782837	0.01
531.5536499	0.08
533.4057007	100.00
534.3790894	36.03
535.4036865	1.73
536.2426147	0.09
536.9663086	0.02
538.4358521	0.01
543.4598999	0.20
544.4046021	0.05
547.4418335	1.81
548.5090942	0.31
549.4348755	0.20
550.3566284	0.23
551.4511108	0.42
552.3550415	0.11
561.4133911	2.03
562.5007935	0.99
564.3784180	1.59
565.3904419	3.83
566.3301392	1.59
567.5346069	0.03
575.3591309	2.75
576.4168091	1.35
577.6985474	0.17
578.3775024	0.05
579.5136719	0.02
595.4348755	4.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1257
Annotation	Unknow
Peak:m/z	Relative Intensity
180.8411255	0.65
181.4551697	0.26
185.0844879	0.17
190.0924225	0.05
198.9498291	0.94
210.9712982	0.35
231.0109253	13.49
234.9027557	0.20
261.1299438	0.09
263.0604858	1.40
264.9019165	0.74
270.9282837	0.09
272.0811157	0.05
273.2285767	0.05
280.1365662	0.28
281.0510864	0.04
288.1624756	0.64
289.0910034	1.36
306.0607910	20.43
314.2787476	0.20
317.0457764	7.77
334.1072388	100.00
340.2131348	0.31
373.3742065	0.32
376.2312622	0.06
381.0700073	0.17
390.1576538	0.26
391.1868286	2.07
391.9965210	0.48
393.9614868	0.18
399.9580688	0.29
409.1041870	52.75
410.1029053	0.54
417.3438110	0.70
445.1196289	0.77
463.2365723	1.89
475.0452271	0.55
501.4155884	0.04
505.1637573	0.25
520.2123413	11.85
521.1997681	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.1606
Annotation	Ractopamine
Peak:m/z	Relative Intensity
96.96002197	0.14
105.84758	0.55
107.1836319	0.10
107.9571762	0.67
116.0413666	0.39
118.1512909	0.08
119.4080658	0.13
121.1386566	0.26
129.9754181	0.19
131.1296387	0.10
131.9520569	0.87
132.9768829	0.05
134.0508423	9.94
134.8707886	0.06
135.8905945	0.64
141.1069031	0.05
144.8172913	0.35
146.3677063	0.14
147.0075073	2.12
147.9905701	0.25
150.1268921	0.35
156.0685883	0.86
158.0971222	0.56
159.0730286	0.63
159.9642334	0.53
161.0450134	0.17
162.0314636	0.14
168.9724426	0.50
170.2116241	0.12
172.3054199	0.09
173.3249512	0.20
179.9389038	0.09
182.0054016	0.05
186.0959473	0.78
187.0939026	1.89
188.1638794	2.40
189.1355591	0.11
189.8039551	0.07
197.1352844	0.12
198.0099487	0.84
199.2832031	0.69
200.1549377	0.14
203.9588013	0.18
210.160553	0.14
212.1425476	0.25
213.1645813	1.15
213.820282	0.11
216.974884	0.18
222.1984558	0.07
225.2157593	0.16
226.0137024	0.15
227.2651672	0.08
228.0932617	0.44
229.255188	69.63
230.3730164	0.65
231.0499268	2.14
237.2093506	0.10
238.3495178	0.35
241.2309265	0.19
242.0741577	0.31
244.454895	0.47
245.268158	0.84
253.2156982	0.49
254.2191162	0.20
255.1943359	3.86
256.1350098	10.05
257.0660095	0.25
263.2639465	0.14
271.0831909	1.04
272.1057739	1.39
273.0701904	1.62
282.1475525	100.00
283.13974	0.58
284.1395264	2.10
285.0044861	0.91
286.2596741	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	802.42
Annotation	Unknow
Peak:m/z	Relative Intensity
224.2242279	0.05
225.0472107	0.01
229.1074524	0.03
230.0474548	0.06
230.9273987	0.06
232.1835022	0.09
233.2706146	0.02
238.2878418	0.10
245.0309601	0.14
246.0121155	0.09
248.0986938	0.12
249.5723267	0.03
250.2830200	0.01
251.1999054	0.09
252.0639954	0.08
253.1540833	0.06
254.1405182	0.05
255.4552002	0.12
256.2390747	0.09
257.3415833	0.04
258.9006958	0.24
260.3049927	0.14
261.8298645	0.30
262.8697510	0.08
264.1680298	0.10
264.9840698	0.07
266.1088257	0.01
267.0562134	0.06
268.2888794	0.10
273.3544312	0.05
278.2528687	0.02
280.1148376	0.16
281.1735229	0.21
282.2677002	0.19
283.2338562	0.05
285.2611389	0.02
286.1107178	0.13
287.2186890	0.12
288.5090332	0.06
290.1243286	0.05
292.3341980	0.03
293.4477844	0.20
294.1847534	0.16
298.3368835	0.16
300.0751953	0.12
301.2472534	0.11
302.3801270	0.12
303.5808716	0.14
304.4144897	0.03
305.5096741	0.19
307.0759277	0.08
308.2320862	1.53
309.2488403	1.40
310.2847900	1.45
311.2388611	0.23
313.3755493	0.02
314.0255737	0.09
315.0541382	0.03
316.3347778	0.33
317.2947388	0.19
318.9786377	0.03
326.2151489	2.81
327.1943970	2.79
328.1849976	3.84
329.1534119	0.52
330.3072510	0.25
331.3186646	0.10
332.5649109	0.13
333.1959839	0.28
334.2173462	0.34
335.1000977	0.18
338.1206055	0.03
340.2583923	0.03
342.2956543	0.24
343.2445374	0.23
344.3138733	0.21
345.3795166	0.22
347.2237549	0.26
348.0636597	0.10
349.1793823	0.14
356.2244263	0.03
357.2247925	0.16
359.2504883	0.24
360.2205811	0.17
361.1609497	1.42
362.1498413	0.87
363.1792908	0.31
364.1834106	0.72
365.1722412	0.41
366.2725525	0.13
367.1633911	0.13
370.2096252	0.05
371.1835938	0.53
372.1244507	0.31
373.2681885	0.52
374.2723694	0.04
376.0499268	0.02
377.5901489	0.06
379.0531006	0.04
383.3674316	1.32
384.3425903	1.31
385.2468262	1.60
386.3225098	0.42
389.3118286	0.07
393.3720093	0.04
394.6658325	0.11
395.3168335	0.22
396.7565918	0.05
397.8518066	0.26
399.2731934	0.73
400.2310791	0.65
401.1842651	0.47
402.4412842	0.48
403.2301636	0.19
404.1846313	0.22
405.3205566	0.38
411.5429077	0.12
412.5152588	0.13
413.3590698	0.25
414.1035767	0.11
415.1773071	0.13
416.4902344	0.15
417.2893677	0.11
418.3510742	0.03
420.2984619	0.05
421.2072144	0.09
422.1500854	0.03
423.1778564	0.28
424.4125366	0.31
425.4523926	0.30
426.4559326	0.30
427.1507568	0.26
429.2937012	0.16
429.9466553	0.21
431.1560059	0.30
432.5868530	0.07
434.2207642	0.10
435.5170898	0.03
438.4805298	0.12
439.3181152	0.22
440.3118286	1.05
441.2589111	1.66
442.2700195	2.90
443.4382324	0.41
444.2395020	0.07
446.2883301	0.30
447.3860474	0.46
448.2874146	0.55
449.3581543	0.16
450.5697021	0.08
451.4721680	0.05
455.3234253	0.04
456.2999268	0.17
457.3068237	0.76
458.3303833	1.27
459.3266602	2.18
460.3989868	0.30
461.5193481	0.08
462.3410645	0.15
463.4085083	0.18
464.4436646	0.17
465.2936401	0.30
466.3181152	0.14
467.1998291	0.14
468.2725830	0.03
469.6226196	0.10
470.3873291	0.08
472.1777954	0.10
473.0468750	0.23
474.3057861	0.53
475.3323364	1.10
476.3398438	0.50
477.8082275	0.14
480.4429321	0.03
481.3347168	0.02
484.3569336	0.03
485.3064575	0.05
488.4503174	0.01
490.3363037	0.09
491.3688354	0.56
492.3391724	1.49
493.2935791	0.39
494.3492432	0.30
495.6973267	0.11
496.3724976	0.07
497.3796387	0.25
498.4926147	0.45
499.4646606	0.20
500.2957153	0.02
503.7212524	0.10
504.4814453	0.31
505.3797607	0.10
508.1798096	0.07
509.4581299	0.13
510.3474731	0.05
511.4066162	0.50
512.3912354	0.78
513.2822266	0.72
514.1676025	0.35
515.3258667	0.14
516.3204346	0.02
518.0707397	0.02
519.4711304	0.07
521.0047607	0.04
521.6068115	0.11
522.3763428	0.14
523.8850098	0.04
525.5842896	0.04
526.3575439	0.23
527.1847534	0.04
528.3847656	0.03
532.0233765	0.12
536.4800415	0.02
537.4227905	0.10
538.5965576	0.02
539.6159668	0.95
540.4575806	0.40
541.3302612	0.43
542.8289795	0.15
543.6074829	0.10
544.5433960	0.05
545.5023193	0.17
546.4047852	0.03
547.6993408	0.06
551.5852051	0.14
552.6305542	0.10
553.3065186	0.04
554.3085327	0.33
555.5287476	0.75
556.5096436	0.20
559.3475342	0.81
560.4382935	2.39
561.4382324	3.98
562.4677124	1.81
563.4794922	0.94
564.5419312	0.08
566.6917114	0.02
569.4537354	0.05
570.6580200	0.37
571.4094238	1.02
572.4536743	0.50
573.3347778	0.45
574.4528198	0.45
577.2698364	0.08
579.3673096	0.07
580.4297485	0.20
582.1194458	0.31
583.2146606	0.16
586.7501221	0.24
587.7162476	1.68
588.5253296	6.59
589.3815308	15.44
590.3862915	3.94
591.3963013	1.66
592.4754028	0.70
595.6597290	0.03
596.2895508	0.04
597.4196167	0.19
598.5717163	0.09
601.6384888	0.03
602.4647827	0.06
605.2219849	0.29
606.6687012	0.72
607.4470825	0.39
608.3305054	0.06
609.4406738	0.54
610.5726318	0.04
612.3156738	0.03
615.3184204	0.03
616.4959717	0.09
617.6150513	0.11
618.3720703	0.04
620.4755859	0.02
625.3733521	0.01
627.2742920	0.03
629.5250854	0.04
631.6159058	0.12
632.7485962	0.07
634.8873901	0.15
635.7647095	0.06
636.5496216	0.14
637.5286255	0.19
638.4741821	0.04
641.7431030	0.13
642.5079956	0.09
643.3667603	0.11
644.4857178	0.26
645.6246948	0.03
652.4098511	0.11
653.4614258	0.49
654.4796143	0.90
655.6124878	0.36
656.4660645	0.12
657.9428711	0.57
658.6177979	0.78
659.7081909	3.93
660.4878540	8.56
661.5529175	3.44
664.3432007	0.05
666.2337036	0.06
667.5025635	0.11
668.3213501	0.27
669.3934326	0.83
670.5076904	2.95
671.5311890	1.14
672.4895630	2.87
673.4818726	0.83
674.3970947	0.99
675.7551270	0.64
676.5147095	0.84
677.4492188	0.06
679.0581665	0.14
682.7586060	0.13
683.5363159	0.06
684.5999146	0.96
686.2742310	4.55
687.5084229	27.35
688.4514771	100.00
689.4240112	26.17
690.0938110	0.06
698.6909790	0.09
699.5627441	0.04
701.4712524	1.92
702.4140015	6.76
703.4295044	2.59
704.4808350	4.04
705.6175537	0.86
708.1522827	0.04
709.2559204	0.04
712.3340454	0.16
712.9988403	0.03
714.5453491	0.23
723.7348022	0.03
725.0875244	0.02
727.8832397	0.05
728.5775146	0.14
732.4144897	0.08
733.6148071	0.06
734.3554688	0.05
735.4215698	0.18
736.1121826	0.05
739.4364624	0.18
740.2172241	0.02
742.5454712	0.02
743.5277100	0.01
744.4464722	0.71
745.4943237	0.19
751.3069458	0.16
753.3699341	0.29
754.8560181	0.48
755.5677490	0.37
756.4714966	2.17
757.4783325	2.52
758.6163330	0.15
765.2254028	0.12
766.5692139	0.09
767.5684204	0.10
771.5516357	1.02
773.4812012	58.90
774.5167847	15.93
775.1848755	0.07
783.5105591	13.38
784.5039062	3.16
802.4838257	15.40
803.1882324	0.06
803.8668823	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
105.1610718	0.10
116.9544678	0.31
131.2540588	0.26
145.0982208	0.20
145.9796753	0.54
148.9683075	1.35
152.2318268	0.16
165.1954193	0.58
168.8704376	0.10
173.9511261	0.16
178.2058716	0.33
179.1630096	0.24
180.1877899	0.15
181.0916138	0.18
182.2876129	0.36
191.2059479	0.09
193.2141266	0.90
195.0006409	2.02
195.9687805	0.24
207.0097046	10.16
208.0347443	8.39
209.0888214	3.69
210.3717041	0.28
221.1171722	0.42
222.1930542	10.32
223.1025543	9.73
224.1138916	2.68
233.1605835	0.46
235.1280518	0.68
236.1906586	0.43
248.8181915	0.14
251.0799561	100.00
252.0883789	34.42
253.100235	1.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.18
Annotation	Unknow
Peak:m/z	Relative Intensity
107.0119476	0.02
112.9930573	2.34
114.0023804	0.19
115.9316025	0.40
117.2312775	0.06
118.9558334	1.46
120.0139313	0.09
125.0220413	0.16
130.8696289	0.88
131.8286591	0.11
136.9151001	0.02
137.8973694	0.05
143.0048981	2.39
143.9686279	4.21
145.0538025	1.11
148.8563385	0.59
150.2704163	0.03
159.9828491	0.13
161.0383301	2.71
162.1129150	0.21
163.0570068	0.09
173.0125122	0.02
173.8542175	0.06
179.0164337	5.15
179.8417969	0.36
188.0505371	2.98
188.9960022	0.61
205.8979950	0.06
222.0805969	0.06
225.1143494	0.06
234.4593811	0.05
241.1409607	0.04
248.2173767	0.08
250.2143555	0.11
283.3104553	0.09
291.3017578	0.23
301.0341797	0.04
321.3557129	0.20
323.1554260	100.00
324.0415039	0.63
325.0834351	0.19
327.1959229	0.04
348.2853699	0.02
350.3600769	0.09
351.3850403	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0562
Annotation	Pedicinin
Peak:m/z	Relative Intensity
124.2342300	0.01
136.8023987	0.02
142.9652710	0.03
159.0018158	0.06
161.0039368	0.07
170.0122681	0.03
170.8797913	0.29
179.0630188	0.22
180.9636536	0.02
183.1098175	0.04
183.7228851	0.01
197.3959198	0.03
199.0387878	0.82
211.1588745	0.07
215.1610107	0.02
225.2717896	0.07
226.1201782	0.11
227.0826721	0.34
237.0563965	0.04
240.2279663	0.07
243.1148071	1.17
244.2455750	0.05
253.1579590	0.03
255.0897217	2.21
256.0746155	0.26
271.1439514	10.46
272.1232300	0.53
280.9798279	0.45
284.0115356	100.00
285.1104126	0.51
299.2702026	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	259.0787
Annotation	4'-Hydroxyflurbiprofen
Peak:m/z	Relative Intensity
139.9731140	1.60
145.0780334	1.27
158.0004883	0.05
166.7488556	0.26
169.2151642	0.07
185.1112366	0.04
187.2875519	0.17
194.7971191	0.03
196.0530853	5.10
200.9742432	0.16
213.0611572	100.00
214.1116486	1.75
214.8728333	0.10
225.1358948	0.03
231.0316620	22.64
231.9324493	0.07
241.1908722	0.18
242.0592194	0.04
244.2687836	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.2096
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
211.2299805	0.07
213.0923767	0.03
219.1970215	0.04
241.1611023	0.01
242.9458313	0.03
246.8333435	0.03
255.0295715	0.02
257.0901184	0.02
264.9986572	0.01
266.0710754	0.08
266.7696533	0.02
269.4891357	0.09
271.2568970	0.01
283.2267761	0.13
284.0818787	1.23
285.1890259	7.04
297.3131409	0.02
299.1207275	0.04
305.5690613	0.02
307.2467041	0.02
309.1447754	0.16
313.5839233	0.03
325.4485168	0.06
327.1059570	0.39
337.0386353	0.04
339.0241089	0.11
341.2545166	0.02
357.2365417	0.19
365.1741943	0.02
369.4466553	0.03
373.3598022	0.05
381.0206299	0.02
393.2005615	0.02
447.1793823	0.41
455.0855713	0.03
473.2292480	0.32
546.0010986	0.04
557.4236450	0.09
562.6483765	0.02
575.2550659	0.80
593.3613281	4.96
595.4982910	0.02
602.3771362	0.01
611.2927856	0.06
619.2117920	0.01
635.2615356	0.02
695.5692139	0.01
697.5285034	0.01
721.9157104	0.05
739.3610840	100.00
740.3475342	15.41
741.1959229	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1612
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9441223	4.06
118.9663010	1.60
123.1232910	0.20
124.9566650	0.18
127.0711060	0.15
128.8309021	0.21
130.5280457	0.27
131.3676910	0.42
134.9844666	0.38
137.1345520	0.22
139.0856781	6.52
142.8898621	1.53
146.7371368	0.09
149.1496735	0.18
153.1492157	0.18
155.0071259	0.15
160.9422302	7.91
166.9387817	0.13
174.2234802	0.16
178.9740601	5.06
183.0554962	100.00
185.1867371	0.27
193.1855621	0.22
197.0762329	2.50
198.2669220	0.14
199.3369293	0.29
206.9658203	23.13
207.5836792	0.29
210.0442657	0.11
224.5263672	1.75
225.1647949	8.05
229.0078735	0.44
239.9051819	0.41
247.1946716	0.07
248.9030151	0.58
255.0603333	4.82
259.0534058	0.45
265.0142517	0.66
267.5069580	0.09
272.6493530	0.44
278.9395142	0.75
283.2774658	0.40
284.8794556	3.77
285.5894775	0.04
287.5305176	0.15
301.3233643	0.24
309.0171509	0.35
315.0456543	0.29
317.0795593	0.33
330.2705383	0.45
331.2268677	4.83
340.3691711	0.32
343.4153442	0.36
344.9452515	70.38
345.6748657	0.07
348.4905701	0.48
349.3094482	0.31
359.2270203	0.18
372.4385071	0.25
376.2926331	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1646
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
270.2340088	0.02
273.0707397	0.02
283.1447754	0.06
287.0877686	4.01
289.0993652	0.05
295.0641479	0.01
299.1381226	0.87
300.2294312	0.03
311.0384521	1.55
313.0014038	0.10
315.0326233	0.06
323.1223145	0.03
325.1699219	0.07
327.1194458	0.09
329.1688843	6.88
331.3935547	0.02
337.1683960	0.02
341.1339722	0.08
342.9874878	0.03
349.2455444	0.08
353.1702881	1.83
359.1744385	0.15
364.7880859	0.06
367.2156372	0.05
370.5274048	0.09
371.1387329	0.05
377.3471680	0.16
379.1510010	0.08
383.2382202	2.77
394.2225342	0.01
395.3022461	1.31
397.3008423	0.13
407.3892212	0.02
409.5476074	0.08
413.2248535	3.69
415.3015137	0.14
421.1026611	0.04
427.2878418	0.09
431.1665039	17.28
431.9659424	0.15
433.1644287	0.78
438.2064209	0.01
439.2402344	0.25
443.0684814	0.01
445.2183228	0.04
447.3408203	0.01
449.1673584	100.00
450.1164551	0.02
455.2817993	0.05
457.2675171	1.10
461.3674316	0.03
463.1455688	0.05
473.2715454	0.08
475.1413574	0.97
477.3250732	0.13
480.9240112	0.08
491.2548828	0.21
497.2235718	0.16
499.1561279	0.20
505.3776245	0.03
511.1483765	0.38
515.1093140	0.06
523.2268677	0.23
529.2001343	0.41
533.3013306	0.09
535.2529297	0.01
541.3287964	0.74
547.1065674	0.02
553.1686401	0.01
559.2570801	0.92
577.1951294	2.71
577.8435669	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1346
Annotation	Hymenoside M
Peak:m/z	Relative Intensity
89.0834351	0.07
89.9605255	0.07
100.8934708	0.23
101.8716278	0.42
112.9164276	0.15
115.0594635	0.13
119.0382919	0.21
119.9308014	0.18
124.8666306	0.12
130.9250183	1.02
143.3698120	0.05
143.9761047	0.27
159.1192780	0.08
160.9663391	2.57
162.0599976	0.19
163.0527344	0.05
169.3647308	0.13
171.1138000	0.06
175.0610352	0.15
177.3009949	0.07
179.0481110	0.11
179.9367065	0.22
181.8949127	0.08
213.8602905	0.12
220.8980103	0.04
225.2476196	0.11
253.2853699	0.09
255.2466431	0.18
263.3010254	1.13
265.1468506	100.00
267.1567078	0.46
275.3844604	0.06
292.6026611	0.07
293.3251648	0.30
296.2919922	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1409
Annotation	Unknow
Peak:m/z	Relative Intensity
143.3157654	0.04
145.1917725	0.06
146.9922638	0.02
149.1492310	0.04
159.2507019	0.04
160.9434814	1.42
163.1411133	0.26
163.9648132	0.03
173.0254211	0.04
175.0620575	0.04
177.0758972	0.15
178.9566650	21.23
180.0901794	0.02
188.9662170	0.02
191.0481262	0.02
193.1050720	0.09
197.1634827	0.03
203.0590210	0.98
205.1868134	0.06
206.8701172	0.08
220.4162903	0.06
221.0505066	0.35
223.1671143	0.02
235.0833282	0.03
245.1730957	0.09
249.1544800	0.04
251.2843933	0.07
253.3349915	0.02
259.1011353	0.04
261.0019226	0.14
273.3572083	0.06
275.1389771	0.05
276.2225952	0.04
281.0539246	0.35
289.2676697	0.03
295.4311218	0.02
296.7592163	0.09
305.2019653	0.21
306.3866882	0.03
323.1911011	2.74
329.3020020	0.04
333.1832275	0.05
338.1506958	0.03
341.2420654	100.00
351.3930664	0.03
354.8812866	0.07
365.2227783	1.44
366.9695435	0.07
369.0560608	0.04
383.3183594	0.21
395.2354431	0.29
399.1443787	0.03
401.4845581	0.05
405.4553528	0.06
407.3980713	0.06
413.1995239	0.94
415.1278381	0.02
415.9330750	0.03
417.1769714	0.03
421.9071960	0.08
439.9719543	0.02
443.3345337	0.40
456.1774292	0.06
457.3593445	0.17
458.3558044	0.14
459.1465454	0.09
461.5400696	0.03
464.5334167	0.11
465.2432861	0.11
467.1955261	0.25
468.4136047	0.07
472.2595825	0.02
474.1463013	0.06
485.2000122	0.50
488.3371277	0.03
503.0585327	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1923
Annotation	Creoside IV
Peak:m/z	Relative Intensity
130.6971283	0.12
143.1192322	0.31
144.9475555	0.35
161.0014801	5.55
161.9388885	0.19
173.4239502	0.11
178.9205933	1.30
180.0315399	0.14
180.9503632	0.31
183.0426025	0.31
201.0827484	0.24
215.2082062	1.61
221.1001892	0.53
229.1274414	0.07
233.1035156	0.65
251.1305237	1.40
257.0798035	0.07
277.0926514	0.13
289.2118530	0.74
293.0544739	0.32
299.1129761	0.43
307.2844849	0.16
310.8964539	0.21
319.3558960	0.14
333.2753906	0.06
335.2351990	1.03
336.2250366	0.07
339.1240845	0.16
347.0657043	0.37
349.1792603	100.00
349.8698120	0.23
351.4346008	0.57
353.2842407	0.46
377.3823242	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	507.1493
Annotation	Syringetin 3-galactoside
Peak:m/z	Relative Intensity
164.0730591	0.01
179.7590332	0.01
183.1383362	0.01
191.1445923	0.01
297.1517944	0.01
312.2026367	0.01
326.4187012	0.02
327.6915588	0.01
330.3101196	0.11
345.1562195	100.00
346.4651489	0.01
348.9123230	0.01
359.1846924	0.01
360.3113403	0.01
393.1766663	0.02
445.3857727	0.01
447.5575256	0.01
471.5861206	0.02
489.3901672	0.06
491.1705017	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2273
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0563965	0.07
144.0868988	0.89
145.0520477	0.19
146.0312195	5.52
147.1628723	0.11
153.8912048	0.03
158.8635712	0.40
170.0573730	0.61
172.0640259	0.06
181.0496826	0.16
187.9957123	48.72
192.2090912	0.06
204.9541473	100.00
243.2904968	0.09
244.9762421	0.17
253.1677246	0.11
268.1849976	0.10
276.8356934	0.04
288.7790833	0.16
295.2892456	0.04
300.4353638	0.26
301.2431030	0.10
307.0935059	0.08
313.3575439	0.31
319.1584473	0.54
345.1746216	0.34
347.1287231	0.44
349.2763672	1.14
350.2702637	0.10
353.7801514	0.11
362.9045410	0.14
374.4771118	0.13
377.4335327	0.12
381.6015625	0.05
382.2314453	0.09
388.4617920	0.32
391.1585693	0.18
395.2818604	0.04
413.3601685	0.12
423.5912476	0.08
425.0202026	0.17
444.1680298	0.05
452.6253052	0.09
455.2417603	0.05
463.1715088	0.08
476.1619263	0.35
482.2661743	0.34
484.3910522	0.10
492.3461304	0.48
493.2409058	0.33
494.4058228	0.70
496.3935547	0.28
511.3746948	0.07
512.0670776	0.18
513.5640259	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	814.4113
Annotation	Unknow
Peak:m/z	Relative Intensity
227.8506012	0.03
241.1362000	0.40
242.2573090	0.07
257.3768616	0.05
260.0443726	0.09
270.2194519	0.07
277.4275513	0.14
303.0529785	0.06
308.5342407	0.06
310.3716431	0.05
343.3071899	0.08
350.2324219	0.10
357.3602905	0.16
358.9770813	0.03
360.0724487	0.28
374.3005371	0.03
380.9836426	0.07
382.2573242	0.12
387.6080322	0.05
396.2423706	0.11
402.4954834	0.06
406.3038330	0.03
407.3361206	0.06
414.6091919	0.02
418.3471680	0.05
424.5255127	0.18
437.4528198	0.05
442.6123047	0.18
455.4827271	0.49
456.3263550	0.12
460.3723755	0.15
471.4481201	0.12
472.5941162	0.04
482.3958740	0.03
503.2888184	0.08
508.8180542	0.22
509.5619507	0.07
510.3406372	0.07
511.5076294	0.35
513.7477417	0.32
519.6058960	0.25
520.2705078	0.06
523.3530884	0.08
524.6286011	0.21
527.5305786	0.04
529.4707031	0.34
531.6469116	0.08
534.6206665	0.13
536.2504272	0.36
539.4821167	0.21
543.7509155	0.04
545.6637573	0.03
547.4653320	0.21
552.3115234	0.22
554.4257202	0.97
555.1958618	0.08
564.8035889	0.09
568.4338989	0.21
569.5196533	0.18
575.6528931	0.05
584.0463867	0.10
586.7474365	0.62
588.4579468	0.03
595.6901245	0.13
598.8629150	0.08
602.5225220	0.04
608.3459473	0.27
609.5676270	1.78
610.4037476	0.23
613.5803833	0.10
618.4162598	0.92
626.4144897	1.50
627.7001343	0.12
634.6880493	0.04
635.6682129	0.10
636.6290283	0.11
637.2861328	0.02
649.5201416	0.09
651.4876709	0.26
652.4620972	0.21
659.6448975	0.27
662.3287354	0.08
663.3848877	0.19
664.7282104	0.08
666.3926392	0.40
668.3664551	0.07
676.9238281	0.10
678.7081299	0.05
679.7796631	0.04
686.1072388	0.07
687.6216431	0.03
692.5470581	0.34
699.5704956	0.42
704.5383911	0.37
705.3594360	0.20
706.6040649	0.10
707.5606079	0.03
716.3991089	0.51
720.6122437	0.46
722.3837891	2.52
723.6655884	1.33
731.6237183	2.57
732.3993530	0.19
735.6184692	0.63
739.8432007	0.08
746.5739136	0.09
747.6845093	0.15
749.5276489	16.31
751.0170288	2.20
751.6900024	6.96
753.5765991	0.30
756.4811401	0.39
757.4423218	0.33
767.8632812	0.29
769.5684814	0.23
770.6461792	0.22
775.3163452	0.11
780.5003052	0.43
781.5092773	0.19
795.2207642	0.68
798.4678345	0.64
799.4368286	0.20
814.3348999	100.00
815.2153931	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1822
Annotation	Butrin
Peak:m/z	Relative Intensity
172.1905518	0.04
172.9772339	0.17
174.0758362	0.28
175.1400757	0.11
185.0275116	0.26
186.9650269	0.10
187.9360199	0.04
190.0313110	0.18
191.2338257	0.04
191.9158783	0.01
193.1349030	0.06
193.9304810	0.14
195.0454102	0.05
197.2555389	0.02
198.0591431	0.08
198.9771729	1.42
200.0663147	0.30
201.0863342	0.66
202.0420532	0.05
203.2151184	0.03
204.9392395	0.01
205.9993591	0.05
207.0426025	0.04
208.3161316	0.03
209.0850830	0.03
210.8742981	0.07
211.8275299	0.04
213.1637878	0.22
214.2360229	0.26
215.0692444	0.69
215.9833679	0.12
217.1412048	0.12
217.9971466	0.08
219.2801208	0.01
224.2288055	0.16
224.9519348	0.06
226.0257263	0.04
227.0035706	0.69
228.1377869	0.15
229.1090698	0.05
229.9988556	0.12
233.0097656	0.27
235.0020142	0.47
236.1009827	0.04
239.0390778	0.18
240.1463623	0.36
241.0069885	0.77
242.1103363	1.51
243.1306763	0.49
247.0915527	0.02
254.0655823	0.04
257.1997070	0.72
258.0534363	0.27
259.1407471	0.12
264.0948181	0.03
264.9516907	0.05
268.1140442	0.59
269.1328735	0.07
270.9267578	0.01
275.2828064	0.14
277.0132446	0.12
283.1424561	1.14
283.8026733	0.06
286.0814209	2.20
287.1703491	0.31
292.0082397	0.03
295.2128296	0.08
297.3832397	0.05
301.1084595	100.00
302.1115723	13.86
307.3094482	0.08
308.9545898	0.02
310.0755615	0.25
312.1595459	0.07
313.1380615	0.05
315.0190735	0.17
316.2507935	0.01
325.1672974	2.10
326.1795044	0.28
337.3975830	0.02
339.1550293	0.44
339.8345947	0.05
340.8819580	0.05
343.1498413	2.42
344.3212280	0.62
345.1374512	0.05
353.0610352	0.03
355.2099609	0.19
356.0625000	0.05
357.2734375	0.31
357.9391479	0.04
362.9109497	0.04
367.9673462	0.02
373.2210693	0.07
374.0842285	0.01
380.9734497	0.03
383.1070557	0.11
385.3148193	0.26
392.7144165	0.01
403.2139282	0.23
404.1053467	0.08
409.4240112	0.06
423.2285767	0.08
427.2720337	0.07
429.5476074	0.06
433.3661499	0.04
434.4500732	0.02
439.4431763	0.03
441.4176636	0.05
445.2325439	0.11
446.3411865	0.20
447.3980713	0.09
448.1336670	0.03
459.2214355	4.69
460.3347778	0.61
462.9610596	0.04
473.3835449	0.14
485.3761597	0.08
489.2579346	1.35
490.2488403	0.28
541.3438110	0.05
591.1956177	0.11
592.4008179	0.02
595.3585815	0.03
610.4211426	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	537.1592
Annotation	Chrysosplenoside E
Peak:m/z	Relative Intensity
192.9989624	0.01
208.1966400	0.02
211.3455811	0.01
220.1791382	0.01
235.1446991	0.03
242.9238892	0.01
252.7864075	0.04
277.3140259	0.03
342.0730591	0.04
344.9990845	0.03
360.1677856	0.21
375.1514282	100.00
375.7822266	0.36
379.4985962	0.04
382.9696655	0.02
414.2769775	0.01
421.1795044	0.02
424.9210815	0.01
465.4195557	0.03
483.0390015	0.13
484.2187500	0.06
489.1257324	0.02
489.9439087	0.01
491.3106689	0.03
492.6160278	0.07
500.8382568	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	280.263
Annotation	Linoleamide
Peak:m/z	Relative Intensity
80.9866486	0.47
84.0885010	0.51
84.9258804	0.09
86.8088532	0.06
92.9790192	1.29
94.9711533	2.41
96.9585724	0.48
98.6808395	0.39
99.6917267	0.21
104.9502335	0.23
106.8489532	0.86
109.0018768	2.19
110.3885651	0.62
111.0081711	0.58
111.9936676	0.15
112.8424377	0.47
113.9829559	2.30
116.7911606	0.32
118.9890594	2.62
120.9949341	3.32
123.0804443	3.14
124.8471222	0.91
126.1412201	0.17
126.9567795	0.77
128.0398254	2.73
131.1197205	0.32
133.0739136	1.36
135.1010437	4.23
136.1015625	0.21
137.0670013	1.68
139.0247498	0.83
140.9805603	0.91
142.0347900	2.26
145.2722473	0.13
147.0445862	7.44
149.0844116	5.24
149.8928223	0.05
150.9999084	2.74
153.0450745	0.37
154.0308990	0.40
156.0811462	2.37
159.0727234	0.22
161.0717468	7.01
163.0220337	2.67
165.0128479	3.52
167.0169678	1.30
168.0267334	1.21
170.1580200	3.16
175.1510620	2.66
176.1383972	0.08
177.1131592	2.30
179.1069031	3.44
181.1692505	0.58
182.1446533	1.55
184.2266846	3.25
187.1906586	0.05
189.1606750	1.88
191.1628571	0.64
193.2187805	0.88
196.0635986	0.84
198.1671753	2.52
203.1105652	66.36
205.2521667	0.45
207.1618347	1.18
210.1094055	2.61
212.1415710	0.08
217.1276245	1.09
219.2651672	1.79
221.0954285	17.35
224.1214600	1.45
234.3121643	0.52
236.7403259	0.15
238.0692749	0.30
245.2219238	57.57
249.0699463	3.29
262.2461548	13.89
263.1868896	100.00
263.8429871	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.193
Annotation	Unknow
Peak:m/z	Relative Intensity
170.8717194	0.28
173.1750793	0.97
191.0547180	100.00
327.1875610	0.09
352.8648682	0.12
353.5546265	0.31
459.0161133	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1797
Annotation	Spinosin
Peak:m/z	Relative Intensity
177.0921021	0.01
258.0247192	0.01
268.8067017	0.03
286.1842651	0.18
287.5475769	0.04
301.1252136	1.81
302.1942749	0.19
313.2729187	0.92
314.1517334	0.08
325.1980896	0.63
326.1029663	0.17
328.2332764	0.03
339.0058594	0.06
341.0609131	0.03
343.1458130	6.60
344.1148071	1.23
355.3834839	0.04
361.2164307	0.11
362.3394775	0.02
367.1954346	2.37
368.2568970	0.69
372.7929688	0.03
373.4594727	0.03
374.1696167	0.01
379.3175659	0.01
381.3775024	0.03
384.8582764	0.02
386.2525024	0.01
391.2104492	0.10
393.2124634	0.09
397.1404419	3.69
398.2319946	0.71
398.9258423	0.01
409.1961060	1.31
410.3070679	0.34
411.3721924	0.03
412.5744019	0.14
417.5075684	0.07
421.0386353	0.02
423.3938599	0.04
427.1791382	3.22
428.2731934	0.75
429.0671387	0.01
436.1820068	0.01
445.1618042	21.20
446.2173462	5.66
447.2791138	0.22
448.2655029	0.08
453.2836304	0.10
456.4696045	0.01
458.4750366	0.04
463.1913452	100.00
464.1422729	20.18
465.0692749	0.09
471.3544922	0.03
472.2665405	0.09
482.5993652	0.01
487.3915405	0.15
488.1762695	0.04
489.1441650	0.45
490.2218628	0.09
494.2652588	0.06
501.3067017	0.09
502.5032959	0.01
505.1746826	0.19
506.3999634	0.06
511.1950073	0.18
525.1788330	0.04
529.4196167	0.04
537.2362671	0.15
538.3226929	0.04
543.1264038	0.10
547.2579956	0.02
548.0924683	0.04
552.7072144	0.04
555.2976685	0.18
556.2714233	0.21
573.2581177	0.24
574.1713257	0.06
591.2033081	1.18
592.1925659	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8975
Annotation	Unknow
Peak:m/z	Relative Intensity
154.9134216	0.03
158.9286652	0.87
174.9493561	0.84
199.0794067	0.02
215.0049133	0.09
217.0450134	0.05
228.9319305	0.32
244.9335022	0.50
272.9796753	9.21
289.0388794	23.46
289.9349365	0.03
347.0549927	0.05
387.0270386	0.79
401.0894165	0.10
402.8832397	100.00
403.5112915	0.36
453.1297607	0.05
460.9885864	0.04
468.8202515	0.02
470.6087646	0.14
471.3982544	0.16
472.2068481	0.07
506.7133179	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2551
Annotation	Quercetin 5,3',4'-trimethyl ether 3-galactosyl-(1->2)-rhamnoside-7-rhamnoside
Peak:m/z	Relative Intensity
281.3009033	0.13
301.1338501	0.20
311.5395508	0.07
313.2720337	0.15
314.2135620	0.19
315.1549072	0.58
316.2726135	0.30
328.1843872	0.07
329.1157532	0.59
331.0737305	6.93
371.1483154	0.45
377.3901367	0.29
461.1537476	0.18
475.4932861	0.46
476.5583496	0.18
479.2041016	0.29
491.3233643	1.68
492.5285645	3.23
493.3244019	20.62
521.3134766	0.29
533.1970215	0.25
534.2243042	0.38
535.2174683	0.88
572.8112793	0.13
573.4212036	0.37
574.3222046	0.34
575.3329468	0.24
577.4850464	0.14
595.3578491	0.06
604.3070068	0.31
618.2669067	0.08
635.3250122	0.75
636.0936890	0.47
637.1746216	1.21
640.9938354	0.13
647.0632935	0.20
653.2064819	0.15
655.2394409	2.21
663.3414917	0.29
697.3913574	2.75
716.4078979	0.19
723.8693237	0.16
737.4454956	1.42
739.2309570	0.08
781.1373901	0.13
799.2664795	100.00
799.9295654	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.2166
Annotation	Patrinoside
Peak:m/z	Relative Intensity
139.0439911	0.88
151.1068115	0.17
153.1214447	0.27
155.9277344	0.17
161.0504608	0.36
169.0672913	71.52
169.9164734	0.18
176.8711243	0.24
180.8937683	0.12
182.9485931	0.29
193.0729980	0.25
197.0722961	0.59
213.0126343	0.17
213.9817047	0.07
219.1249542	0.46
240.4128876	0.14
242.0115509	0.53
248.9940491	0.22
253.2519531	0.45
255.3801575	0.11
258.1367493	0.45
259.1837769	0.57
262.1319275	0.28
264.9496765	0.70
272.7183533	0.63
280.1132202	0.10
283.3812256	0.82
287.4422607	0.58
295.1571960	0.52
296.9252014	0.08
299.2379150	0.35
301.1413574	8.67
308.9967651	0.15
313.0557251	0.47
324.9844360	1.12
328.3576660	0.08
331.0599060	100.00
332.1564331	0.09
335.4173889	1.06
336.3619080	0.15
337.2463684	0.12
343.2049255	4.72
344.4754333	0.17
349.3923645	0.05
356.7226257	0.36
358.0645142	0.16
362.4064026	0.38
364.2701721	0.11
367.0846252	1.59
372.5932007	0.09
373.3794556	0.14
375.2001648	0.22
376.4225159	0.54
379.3061218	0.44
380.9132385	0.25
384.5553894	0.27
385.2905579	0.35
397.1484070	3.68
402.4158020	1.21
404.4083557	0.33
406.1335754	0.09
409.2439270	1.58
413.2070312	0.25
416.3263855	0.19
416.9466553	0.12
417.6480713	0.17
418.2552795	0.55
419.1691589	0.38
427.2378235	6.60
429.5820618	0.07
431.9703979	0.08
432.9250793	0.33
442.3386230	0.06
445.2279968	24.16
446.0961609	0.18
448.2366028	0.19
454.0549011	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	727.1735
Annotation	Primflaside
Peak:m/z	Relative Intensity
209.0609283	0.46
223.1835632	0.14
231.0531616	0.12
233.0435791	0.07
239.1112061	2.83
249.2054291	0.03
251.0704041	0.12
263.2066650	0.05
269.1268921	1.77
275.4454651	0.09
277.3530273	0.14
281.3480530	0.17
286.9274597	0.32
293.1488037	0.04
305.1161804	0.36
307.0481567	0.41
310.9570312	0.31
323.2218628	0.28
329.0726318	1.10
340.0517578	0.28
341.2166748	0.29
353.1062622	0.42
358.4176025	0.16
359.3956909	0.61
365.2763062	0.12
366.0364990	0.24
371.2905273	0.53
379.3408203	0.32
383.2734985	0.36
389.0286865	0.17
390.2769165	0.08
394.2542114	0.17
395.1356201	0.13
399.1530762	0.05
401.0679932	9.56
413.1057129	0.41
414.3803101	0.28
425.4237061	0.18
431.1535034	14.09
437.2013550	0.17
443.3389282	1.08
454.9909668	0.09
456.1993408	0.26
461.2074585	4.83
473.4189453	0.13
485.2460938	0.76
487.3946533	0.38
491.2302246	1.42
503.2138062	1.49
515.0902710	1.00
516.2180786	0.27
521.1255493	5.34
526.6115723	0.66
527.2741089	0.24
531.3297729	0.16
532.0476685	0.04
533.2319336	1.95
545.1739502	0.44
551.2203369	2.87
559.2055054	0.41
563.1262817	3.32
565.4472656	0.22
575.2744751	1.31
577.4757690	0.17
580.9901733	0.29
587.5225220	0.26
589.4882202	0.12
593.2155762	0.94
605.2250366	0.98
606.3369141	2.08
607.2482300	0.16
623.4131470	0.48
628.9342651	0.16
636.0351562	0.27
638.5881958	0.28
641.2615356	0.74
647.3419800	0.29
665.3063354	3.09
677.0302124	0.21
682.7273560	0.57
683.3582153	5.50
690.3684692	0.24
708.7042847	0.72
709.4301758	0.73
727.2018433	100.00
727.8428345	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.1555
Annotation	2-Nitroestra-1,3,5(10)-triene-3,17beta-diol
Peak:m/z	Relative Intensity
108.2742538	0.04
122.2370377	0.12
125.8619385	0.09
133.8540497	0.05
140.1020203	0.07
145.1274719	0.06
147.1581879	0.05
149.2707214	0.02
149.8919830	0.07
151.8945312	0.03
159.0594482	0.01
163.8518982	0.05
170.0058594	0.02
174.1962433	0.03
202.9821167	0.37
204.1033020	0.09
211.9887695	0.06
220.0024414	0.06
225.4754333	0.15
227.3189392	0.06
229.1034851	0.05
230.1137085	0.26
237.1980286	0.04
239.1526794	0.10
243.2135925	0.12
244.1376953	0.09
245.2211914	1.99
246.1953735	0.03
254.2617188	0.08
256.2543335	0.05
257.9342957	0.04
271.1443481	100.00
271.8916321	0.36
273.2083130	0.93
280.0910645	0.07
289.1301270	2.00
298.1452026	8.82
299.1492920	0.03
301.2440186	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	829.221
Annotation	Uroporphyrin IV
Peak:m/z	Relative Intensity
305.3520203	0.01
329.1026917	0.05
343.0675049	0.02
344.1492310	0.10
346.2626953	0.01
359.1109619	0.33
360.4467163	0.03
401.0694580	0.01
443.2221069	0.01
445.4785156	0.01
500.4564819	0.02
506.3146362	0.01
522.3364868	0.11
564.4791260	0.05
652.8858032	0.02
667.1109619	0.59
684.2019653	0.03
708.0457153	0.01
782.1592407	0.01
792.4087524	0.01
811.4534302	0.03
829.2857666	100.00
829.9371948	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1977
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9487228	1.30
118.7543335	0.34
123.0924072	0.39
124.8312759	0.38
130.9255676	0.11
136.7064209	0.05
138.9537659	0.35
140.9210052	0.05
142.0139771	0.95
143.1329346	0.45
151.1873627	0.16
152.1394043	0.07
153.0960999	0.74
154.9954834	0.26
159.0667572	0.09
160.9568939	3.03
162.9895325	0.04
165.0788879	0.31
166.9707336	0.23
178.0366364	0.99
179.0295258	0.40
181.0177612	1.07
182.0294189	0.09
182.9888611	0.07
185.1740112	0.32
187.1265564	7.64
191.3017426	0.03
193.1592712	0.62
194.9272461	0.19
203.0337830	0.05
205.3474731	0.25
207.1546326	0.45
208.9640656	0.36
211.0930786	1.46
213.2750244	0.06
217.2030334	0.08
221.0544739	0.24
223.0438843	1.21
227.3216553	0.04
228.9747009	1.78
229.6459961	0.17
235.0851440	0.29
239.1466980	0.40
241.0480652	0.66
243.1207886	0.04
246.8062744	0.07
253.2096863	10.17
255.1772156	0.04
261.1975098	0.06
265.2381897	0.29
283.2067871	1.87
289.1768799	0.07
295.2960205	0.48
303.3323975	0.07
313.1213684	0.84
331.2337036	100.00
342.3472290	0.15
345.1842041	0.83
346.1583862	0.30
349.1996460	38.70
355.0482483	0.21
359.1458435	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.162
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
210.0236511	0.15
225.1236115	0.03
227.0753784	0.25
235.9380493	0.05
243.2193298	0.07
244.0982056	0.09
252.0880737	0.13
257.1716919	0.31
260.8984985	0.05
271.1941528	0.26
285.4749756	0.11
288.5291748	0.05
296.2308350	0.14
299.1446228	1.95
300.2838745	0.43
305.1091309	1.53
312.3389282	0.03
313.5919189	1.01
314.2014771	16.79
315.2735901	0.33
324.3883057	0.06
327.3587036	0.81
329.1381226	70.16
329.7570190	0.17
331.0395508	0.03
335.8720703	0.05
339.0805054	0.16
342.2442017	0.09
343.1611328	0.33
351.2585449	0.46
356.0825195	0.11
371.2139282	5.20
380.5570068	0.13
381.2393188	0.11
395.1693726	0.13
411.3057861	0.20
413.5568237	0.11
441.3695679	0.10
455.2503052	0.08
459.4204102	0.18
461.6187134	0.02
473.3527832	1.43
476.4420166	0.15
487.5207520	0.05
491.2081299	100.00
491.8444824	0.36
519.2009888	0.33
533.2420044	63.78
533.9240723	0.07
545.3496704	0.05
546.5324707	0.11
556.3484497	0.02
559.2107544	0.20
573.2717896	10.48
585.4993896	0.05
589.0641479	0.18
590.7708130	0.12
599.5985718	0.16
616.2828369	0.05
617.3849487	0.11
620.3707886	0.03
634.6522827	0.99
635.2588501	3.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	640.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9111633	0.36
220.9608459	0.31
232.8480225	0.21
241.0064697	0.53
252.9974060	0.16
279.2638245	0.21
295.1558838	0.12
302.9087524	5.75
304.8791504	5.26
354.6786499	0.23
359.0234985	0.13
361.0682373	0.07
366.4084473	0.12
372.2153931	0.17
379.1320190	0.19
386.7142944	18.08
387.8918457	3.00
388.7476196	22.34
414.9690552	0.51
466.0015259	0.10
466.9642944	4.75
469.4163208	0.73
470.6909180	42.06
471.9011841	22.44
472.7072754	100.00
473.3435059	0.24
482.9273682	0.13
484.7510986	1.09
489.5989990	0.12
491.4780884	0.08
499.2963867	0.11
502.9235840	0.11
504.9096069	0.05
507.7807007	0.26
528.7066040	0.10
532.6762085	0.09
554.5516968	13.74
555.7471924	19.47
556.6011353	52.62
557.2938232	0.21
566.6809692	0.03
580.0172729	0.13
594.1406860	0.43
598.1267090	0.97
640.2619629	0.87
641.1196899	0.38
641.9590454	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	888.4925
Annotation	Unknow
Peak:m/z	Relative Intensity
323.2200623	0.11
332.3629761	0.03
361.8132324	0.06
378.2802124	0.05
396.4052734	0.06
418.4400024	0.09
432.7283936	0.09
444.8493652	0.24
451.3687744	0.03
453.1669312	0.31
454.0704956	0.62
455.0735474	0.54
460.2378540	0.05
465.4739990	0.14
470.8009033	0.04
472.4911499	0.25
482.4327393	0.21
488.2682495	0.03
489.6189575	0.02
499.7411499	0.03
503.2613525	0.18
504.5761108	0.02
505.2441406	0.09
511.3968506	0.08
514.5564575	0.04
522.6054688	0.14
531.6785278	0.18
543.5279541	0.03
555.4237061	0.04
564.7271729	0.06
573.2789917	0.07
575.2334595	0.06
579.4721069	0.34
584.6484985	0.03
586.5451660	0.06
588.4944458	0.07
593.5801392	0.53
600.1873169	0.07
600.7954712	0.32
603.4994507	0.10
605.9093018	0.03
611.3649292	0.03
616.4797974	0.08
619.6070557	0.17
625.3481445	0.08
627.2147217	0.14
628.5753784	0.23
629.7116089	0.10
641.4161377	0.03
643.6155396	0.04
644.8486938	0.03
645.6390991	0.05
646.4423218	0.04
647.6610718	0.04
650.5222778	0.19
657.3826904	0.02
658.1600952	0.06
664.5247192	0.28
669.0781250	0.05
670.8264771	0.06
672.2078247	0.08
674.7474365	0.03
676.9507446	0.01
682.3834839	0.05
685.6309204	0.03
687.5682983	0.03
690.5772095	0.27
697.4435425	0.03
702.6306152	0.12
704.3174438	0.14
706.8518677	0.02
707.6038818	0.02
711.6253662	0.16
713.4692993	0.97
719.9323120	0.02
721.6704102	0.12
725.7188110	0.12
726.5363159	0.17
732.9464111	0.05
735.3949585	0.16
736.4498291	0.08
740.5634155	0.25
741.2794800	0.37
742.4650269	0.11
746.7782593	0.12
747.6681519	0.76
748.5878296	0.04
754.4694824	0.71
757.6109009	0.22
761.6902466	0.06
763.6715698	0.63
768.4525757	0.02
769.2844849	0.20
771.7776489	0.23
773.6542358	0.08
774.8064575	0.12
775.6642456	0.56
785.6174927	0.05
786.8765259	0.07
788.6328735	0.17
789.7470093	3.93
799.4890747	0.16
802.6220703	0.02
803.5175171	0.67
816.7723999	1.12
817.5811157	0.72
819.5512085	0.15
831.6937256	0.09
842.5722656	0.72
844.0739746	0.29
844.7882080	1.05
845.8655396	0.09
852.5146484	0.04
856.3990479	0.02
860.6798096	36.13
861.6853638	1.96
870.6658325	1.27
888.6488647	100.00
889.7695923	49.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.1
Annotation	Zeanoside B
Peak:m/z	Relative Intensity
108.8926239	0.14
119.8389816	0.08
123.2163391	0.07
126.8653870	0.16
131.9180756	0.40
139.8393860	0.10
143.2480164	0.21
149.9320679	0.13
151.7729797	0.14
152.8485718	0.12
153.4498901	0.05
159.8203430	0.68
162.7680054	0.12
164.0734253	0.15
167.0770569	0.03
168.0424500	0.05
169.0230255	0.22
169.8750458	0.22
170.7301636	0.03
175.0926514	0.05
178.0742798	0.65
187.8890076	2.46
188.7666016	0.19
200.7264099	0.33
202.9093323	0.13
203.9366455	0.05
206.0697327	100.00
209.2035675	0.13
213.0871887	0.22
216.0281677	0.10
218.5414124	0.13
224.9384155	0.06
231.1935425	0.22
233.3271179	0.34
234.2121277	0.04
237.2202759	0.84
238.0935059	0.10
249.1773071	0.32
250.0586548	0.16
250.9055786	0.06
255.1394653	0.06
262.7387085	0.08
268.6477661	0.14
277.2007141	0.20
278.0465088	0.09
279.8289490	0.23
281.2904663	0.10
290.3842468	0.06
293.5147400	0.05
302.5550537	0.43
304.0623474	0.08
304.9218140	0.23
308.1588135	0.24
309.1821289	0.61
310.1011353	0.05
314.9115906	0.55
318.0167542	0.09
320.3287659	0.09
322.2634888	0.48
322.9740906	0.19
327.3328552	0.31
331.3294678	0.37
332.1430054	0.40
332.8846130	0.17
336.1704102	0.19
337.3750000	0.29
338.0396118	0.27
340.7993164	0.22
345.2871704	0.10
349.2500916	0.43
350.2075195	0.59
351.0331116	0.45
358.8873596	0.04
359.5312195	0.71
367.4383240	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	330.07
Annotation	Unknow
Peak:m/z	Relative Intensity
117.0126953	0.00
123.1375046	0.01
139.1212616	0.00
151.8670959	0.00
167.1869965	0.03
191.0315552	0.01
192.2436676	0.00
201.0210114	0.00
205.0871582	0.00
209.2917786	0.01
226.2815857	0.00
235.1856384	0.01
254.3128357	0.01
267.1326294	0.00
270.2283630	0.03
271.3104858	0.00
296.2686157	0.03
297.7561035	0.02
299.1758728	0.03
300.0897522	0.03
311.2468872	0.07
312.2317200	0.03
314.1662903	100.00
315.1105957	19.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.2
Annotation	Scorzonoside
Peak:m/z	Relative Intensity
168.7185974	0.15
171.8877411	0.58
175.0600891	0.38
176.0903473	0.11
176.8515625	0.14
180.0069427	0.16
184.1537476	1.09
184.8979187	0.13
186.9963989	0.09
188.0862732	0.09
188.9535828	0.09
189.9584961	0.17
193.2102814	1.26
196.0746002	0.08
197.1765442	0.42
198.0308838	0.39
199.2183990	0.57
200.0572357	0.43
201.1781464	0.09
202.3527679	0.08
205.0266876	1.14
206.3014832	0.12
207.3029175	0.75
209.2120972	0.30
211.0138855	0.53
214.1831665	0.05
215.1332703	0.75
215.9248199	0.31
217.0077209	1.52
223.1754913	0.22
224.1285706	0.10
226.0892639	0.19
235.0651550	9.69
237.0403900	0.23
240.2886963	0.61
241.2863159	0.84
242.1965332	0.77
242.9700317	0.15
254.9340210	0.46
256.2380981	0.16
257.2570801	0.54
263.2097168	0.40
265.0966797	0.33
267.0764771	0.29
267.9131470	0.75
269.0325317	0.98
270.2642212	0.67
271.2296753	3.54
276.9999390	0.20
279.1350098	0.10
284.0871582	14.01
285.1015625	97.58
286.0403442	100.00
287.1624756	71.60
288.9576721	0.09
293.2316284	0.35
295.2299805	1.11
296.3558960	0.28
297.0649719	2.18
298.2389526	1.39
299.2014160	0.71
306.9953613	0.11
309.2304688	2.66
310.0623779	4.17
311.1033936	0.89
313.1253662	1.05
323.3234253	0.15
324.2195435	0.41
325.1964722	0.99
327.1549072	6.90
328.2058716	5.24
329.0673218	2.28
336.2757568	0.34
337.1313477	0.09
338.3286743	0.09
339.1060791	2.80
340.1902466	0.25
341.1737061	0.11
342.1000366	1.42
343.3052368	0.95
350.2041626	0.15
351.3445435	0.19
352.0692749	0.52
353.4322510	1.73
354.1005859	2.58
355.3478394	1.00
357.1709595	23.59
358.1743774	2.00
359.2972412	0.27
366.4029541	0.39
369.2764282	34.65
370.0214233	0.16
371.6898193	0.23
372.6880493	0.39
373.3413696	0.31
381.2712402	0.95
382.2691040	0.14
383.3956299	0.95
384.3817749	0.17
386.0957642	0.59
387.1221924	1.49
388.0436401	0.38
389.3693848	0.55
390.3740845	0.18
394.2588501	0.97
396.3874512	0.11
399.1447144	0.25
400.0803223	0.27
403.4710083	0.13
410.5948486	0.22
412.6512451	0.24
415.2713623	0.56
426.5114136	0.10
429.2388916	1.64
430.2113037	3.65
431.2944946	1.53
432.2152100	0.27
433.2142944	0.62
441.2953491	3.00
443.1276245	1.64
444.2802734	4.11
445.3078003	1.21
447.2424316	20.10
448.2342529	51.25
449.1767578	10.88
450.4705200	0.10
456.1572876	0.21
459.2618408	60.96
463.2520752	0.14
473.3378296	1.77
474.2078247	6.53
475.2391357	2.46
485.5012207	0.37
486.3217163	0.13
491.4745483	0.19
499.5036011	0.28
501.4213257	1.02
504.2477417	0.68
505.3589478	1.20
535.4141235	1.73
548.3153687	1.45
549.4611816	0.19
551.1538696	0.48
564.3921509	0.65
576.3871460	0.93
577.3954468	0.47
595.1548462	0.96
596.2681885	9.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.2196
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
225.1348572	0.15
242.9100037	0.02
269.1831360	0.32
287.1023560	58.04
288.1730347	5.64
353.1683960	0.04
431.1073608	0.29
438.3309937	0.04
449.1856079	100.00
450.1777954	9.28
450.7865601	0.03
459.1804199	0.11
460.1492920	0.05
474.3689575	0.10
491.3919678	0.06
520.9218140	0.04
522.2680664	0.07
577.4191895	0.11
590.1192017	0.07
595.2432861	48.20
596.3978271	5.59
621.4641113	0.06
628.2404785	0.05
637.1809692	0.09
758.2697144	38.50
759.0441895	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.227
Annotation	PA(8:0/8:0)
Peak:m/z	Relative Intensity
118.9237823	0.21
125.2327042	0.05
142.0137329	0.21
143.0565796	1.18
145.0623627	0.25
146.9252625	31.20
158.0093842	0.03
158.9940796	0.03
164.9492188	0.25
171.2547455	0.07
175.3916016	0.06
180.9543762	0.02
183.2232056	0.14
184.9934998	0.14
187.0249634	0.14
190.2244263	0.51
194.0767212	0.04
194.9614258	0.08
197.1913605	0.08
206.9022064	0.05
208.3107910	0.16
212.2806091	0.18
213.0722046	0.05
221.2294922	0.40
222.1037750	0.04
225.1210022	0.03
227.0411072	0.19
228.0809479	0.02
230.9634857	0.48
232.2203979	1.80
235.1366577	0.05
236.2556152	0.06
238.7243042	0.02
243.2781067	0.07
244.1088867	0.03
245.0798340	0.06
246.1932373	2.35
254.1936646	0.02
255.0807800	0.04
256.1009521	0.06
261.1354675	0.12
263.1665955	100.00
264.0375061	0.09
270.1239929	0.04
274.1974182	0.15
275.1232300	0.16
277.0784912	0.06
283.5308228	0.09
284.2684937	0.04
291.2124634	1.44
292.3516235	0.07
295.1892395	0.36
296.1913757	0.18
304.2490540	0.07
305.3217163	0.42
309.0975037	1.54
310.7792969	0.60
316.9628906	0.05
321.0729675	0.10
322.3016357	0.09
327.3073425	0.07
332.6467896	0.17
334.6615601	0.32
336.4096069	0.07
341.4190063	0.41
344.2992859	0.30
350.2587585	0.25
353.2592468	0.32
364.2410583	0.79
365.4960022	0.07
366.1005859	0.07
371.2220459	0.34
378.9020081	1.22
381.1431274	0.12
383.3118591	0.21
388.3524475	0.11
389.3334961	0.19
393.9264526	0.49
394.6313782	0.13
400.0487976	0.19
402.2928162	0.06
402.9401855	0.11
406.2941895	0.61
407.2377625	1.37
408.2554626	4.61
409.0544434	0.20
411.4326782	0.05
412.3834534	0.16
414.7153320	0.07
416.9504089	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1035
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
70.9296417	0.42
79.8997192	0.04
87.8706512	100.00
105.5336456	0.10
118.1028748	0.10
129.0467987	0.10
133.7525024	0.10
146.0803375	11.32
172.1640778	0.20
174.0313263	0.47
178.9325256	0.06
190.1216278	0.04
200.0965729	1.20
202.9592590	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	443.16
Annotation	Unknow
Peak:m/z	Relative Intensity
126.0942993	0.18
149.1139221	0.16
151.9203796	0.06
164.9959106	0.75
172.0275726	0.08
176.9632874	0.05
203.9875031	0.36
204.9178772	0.10
221.2988129	0.04
232.5545197	0.54
245.1352844	0.06
246.8469238	0.31
255.1069946	0.06
261.9912109	0.03
263.7301331	0.08
265.1914673	0.26
271.1206970	0.12
281.0977783	100.00
281.9052734	1.42
284.0232849	0.31
298.8928833	0.18
305.3103943	0.15
309.0001831	0.07
311.1973572	0.05
323.0297546	1.22
324.7853088	0.11
327.4548645	0.20
329.3132019	0.05
330.9309082	0.16
337.2424927	0.09
347.1045837	0.31
352.9933472	0.46
357.7931824	0.16
359.0428162	0.87
363.0561829	0.18
368.9968262	0.07
374.9951172	0.04
384.1450195	0.40
387.2672119	0.08
389.0699158	0.15
396.9999084	0.44
406.5275269	0.16
407.2250061	0.08
416.0786438	0.10
424.3096619	0.84
425.2226257	0.67
426.4016418	0.33
428.1274414	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	769.22
Annotation	Unknow
Peak:m/z	Relative Intensity
243.3717346	0.09
256.9841919	0.14
258.0381775	0.17
263.3871460	0.07
271.0310364	0.28
282.3487549	0.10
286.0059204	0.14
299.0901489	0.03
301.2154541	1.31
310.0609741	0.38
311.0389709	0.65
313.1905212	8.11
324.3218079	0.19
325.1829224	1.57
328.3422241	0.07
339.1137085	0.51
341.4474792	0.02
343.1058350	21.48
343.7813721	0.07
348.3264771	0.11
353.2608643	0.20
355.2359009	0.06
363.3943481	0.21
367.1618652	12.90
372.7577515	0.10
373.4989624	0.12
379.1831665	0.39
381.2088623	0.19
391.0875854	0.95
394.3054810	0.04
397.1717529	10.43
409.2272949	12.23
427.2847900	8.23
433.1089478	0.05
445.2299805	38.67
451.2199097	0.14
463.2003784	4.79
469.4186401	0.14
470.4806519	0.31
474.3014526	0.04
487.3530884	0.23
491.3512573	0.04
503.3370361	0.06
505.5231323	0.07
520.4806519	0.08
551.0436401	0.09
553.3280640	0.08
557.2536621	0.08
571.1222534	0.12
587.1500854	0.12
593.6535034	0.06
601.4439697	0.09
604.0465698	0.16
607.1668701	1.16
611.2913208	0.04
619.3524780	3.45
620.0932007	0.08
621.4125977	0.09
622.5028687	0.06
623.3447266	0.05
631.2269287	0.38
646.9954224	0.06
649.2741089	13.15
655.2009888	0.30
667.1724243	0.04
673.2605591	5.99
679.3604736	0.33
685.3842773	0.65
689.4027100	0.48
697.4419556	0.65
703.3594360	29.78
707.2164307	0.05
715.2542725	14.30
715.9209595	0.05
733.3319702	11.81
735.9639282	0.25
751.2503662	100.00
751.9426880	0.38
769.3292236	28.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1139.2897
Annotation	Didmolamide B
Peak:m/z	Relative Intensity
329.2640076	0.06
533.5412598	0.03
1139.1538090	100.00
1140.3128660	4.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1126.545
Annotation	Unknow
Peak:m/z	Relative Intensity
332.3706360	0.02
335.5132141	0.04
363.4394226	0.10
380.5157471	0.14
395.0618286	0.05
397.0608521	0.09
413.4648438	0.14
455.3025818	0.03
464.3568420	0.05
465.2902222	0.13
473.7340088	0.03
481.5000610	0.05
518.4431763	0.06
537.4182739	0.05
539.3161011	0.04
548.5581055	0.05
557.1829834	0.07
562.5454102	0.04
563.5338135	0.10
574.7856445	0.03
579.7521362	0.05
581.5599365	0.01
592.3677979	0.04
600.4693604	0.03
605.1989746	0.01
611.7703857	0.10
612.5463867	0.07
624.5006104	0.04
627.8609009	0.04
631.5379639	0.06
637.6141357	0.12
639.4715576	0.12
640.4986572	0.10
644.3341064	0.03
645.4799805	0.05
655.0753174	0.01
657.3901367	0.32
659.5396118	0.05
671.5244141	0.12
672.7119751	0.04
686.5119629	0.08
689.5583496	1.13
691.3032227	0.06
715.5390015	0.10
732.4205322	0.13
742.3095703	0.06
760.6167603	0.05
780.6306763	0.06
791.5400391	0.03
794.5819092	0.10
798.6373901	0.06
799.4822998	0.05
816.6169434	0.01
817.5122070	0.23
818.4050293	0.27
821.3817139	0.02
835.5439453	7.72
842.5021973	0.09
848.5450439	0.01
859.2329102	0.02
868.9127197	0.03
870.5764160	0.12
871.4020996	0.15
872.5152588	0.06
877.5775146	0.11
889.4805908	0.70
890.1058350	0.11
894.7847900	0.05
903.7612305	0.05
934.1872559	0.09
942.8182373	0.11
943.8814697	0.08
945.2054443	0.03
946.7946777	0.88
947.6394043	0.30
961.7049561	0.08
964.4296875	5.28
965.0964355	0.09
980.5531006	0.03
981.6042480	0.02
996.9987793	0.60
997.6585693	1.29
1051.6033940	0.66
1054.5548100	0.11
1072.5100100	0.12
1109.6311040	0.01
1126.4658200	100.00
1127.5120850	77.94
1128.1885990	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0702
Annotation	Quinic acid
Peak:m/z	Relative Intensity
58.8677826	0.03
83.1132050	0.04
94.8651886	2.13
99.9685669	0.04
105.0194550	0.05
107.0862427	0.11
110.1379242	0.03
110.8021240	0.18
112.8936768	0.03
115.1079254	0.15
116.7948914	0.01
120.9539948	0.36
128.8755798	4.02
138.9674988	4.39
143.8642426	0.02
144.7218018	0.02
146.8899078	100.00
147.9776764	0.02
156.9029388	82.41
161.4867706	0.05
162.8810272	0.16
164.1681671	2.82
164.8180847	7.76
174.8730011	13.16
176.0327911	0.03
197.9867706	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	427.1955
Annotation	Crepidiaside C
Peak:m/z	Relative Intensity
120.9622650	0.26
122.8539734	0.15
127.0744629	0.21
129.1250153	0.13
129.8510742	0.23
131.0331116	0.12
132.7063904	0.68
135.1842651	0.22
136.0014648	0.17
137.0383911	0.45
137.9610138	0.16
141.8432617	0.36
145.1058350	0.33
146.9635315	1.12
148.9913330	0.64
154.0635681	0.12
156.9305267	0.60
159.1396179	0.40
161.1053314	0.70
165.0996704	1.07
166.3181458	0.39
166.9586639	0.19
168.1830139	0.14
169.1933594	0.09
171.0755920	0.36
172.4494019	0.24
173.0702209	0.77
175.0703583	5.70
177.0177917	1.52
178.8997650	0.19
180.1809692	0.21
181.9311523	0.14
183.0451050	0.06
185.0856628	1.06
187.0466919	1.43
188.2000732	0.31
189.1429749	0.38
193.1943054	0.23
196.3580627	0.20
199.0167236	0.38
201.0144501	0.83
203.0893860	2.17
205.3220215	0.37
211.0284271	1.07
215.0963440	0.07
217.1086121	2.58
218.9673462	1.35
220.8998566	0.06
226.9645386	0.18
229.0711365	1.77
232.5252991	0.35
235.1257935	0.36
240.2187500	0.16
245.2440796	0.53
246.9830017	13.84
250.8843689	0.33
252.2148743	0.08
254.6405029	0.33
255.3182068	0.44
257.8589172	0.12
260.2341614	0.13
265.1196289	100.00
269.1101685	0.55
271.2261658	0.42
275.1647949	0.13
278.4049988	0.07
280.7112732	0.17
287.0058289	0.62
288.2438049	0.53
291.1512146	0.19
295.0036926	1.47
297.2244568	0.13
298.1239014	0.13
303.1459045	0.09
305.0541992	3.25
306.0674744	1.53
307.4244385	0.18
309.2755737	0.74
310.1917114	0.22
312.3345947	0.19
312.9472656	0.15
314.1611938	0.36
315.3399963	0.13
318.9905396	0.28
327.1813049	0.15
334.5260620	0.51
336.1897888	0.11
343.1761169	7.03
347.1999512	0.19
349.1564636	2.49
352.7868347	3.57
353.8727112	0.25
361.0338440	0.61
362.7558899	0.38
363.3984070	0.37
368.5751343	0.17
369.5580139	0.10
371.7168884	0.13
373.0998230	1.07
378.6815796	0.52
379.2834778	0.61
381.0138245	7.13
381.6898499	0.25
383.0802307	0.61
384.1210327	0.05
390.4524536	0.68
391.2284241	2.72
392.3656921	0.19
399.3050537	0.63
406.2106628	0.89
406.9197998	0.34
409.1415710	16.72
410.0466614	0.47
416.7261658	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	942.5084
Annotation	Kabiramide C
Peak:m/z	Relative Intensity
333.1020508	0.14
339.2193298	0.17
394.2297668	0.37
423.6894531	0.26
557.4509888	0.33
565.9438477	0.20
594.0874023	0.78
617.7734985	0.51
663.7872314	0.18
667.3753662	0.22
669.6328735	0.43
681.2567139	0.44
693.4790649	0.35
813.5697021	3.31
883.8134155	0.26
923.930481	0.63
924.6050415	1.39
942.5127563	100.00
943.2424927	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.2221
Annotation	Marioside
Peak:m/z	Relative Intensity
131.2671204	0.08
132.9340363	4.60
133.8281250	0.05
135.0152893	12.25
135.7635345	0.04
136.9525604	0.80
147.0451813	0.17
148.8077393	0.31
151.0609741	0.79
153.2091675	0.15
160.1011353	0.07
164.1075134	0.15
165.1025085	0.35
175.0643768	15.36
176.8710022	0.07
182.2293091	0.11
186.0380859	0.03
187.1453552	0.56
190.9497070	0.10
193.0398712	16.87
205.0016479	0.03
208.7168274	0.04
211.0144806	100.00
213.0652313	0.13
227.1258087	0.03
231.1335449	0.02
235.4697113	0.02
243.3257446	0.08
249.0085449	0.05
253.2807617	0.07
274.5784302	0.04
283.6373291	0.03
289.0677795	0.09
301.3695679	0.38
306.3462524	0.16
306.9527893	0.17
309.3520508	0.16
319.1536865	0.16
323.1456909	0.19
326.8019409	0.13
341.2613525	0.03
343.9643555	0.08
345.1555786	0.05
355.0803528	0.18
356.1827393	0.06
369.2149963	0.02
371.1231384	0.05
375.6382751	0.10
378.1678162	0.15
380.8444824	0.17
382.0879211	0.18
395.0691223	0.19
396.6304626	0.45
397.2529297	4.71
399.2398071	0.10
401.0714417	0.43
412.2435608	0.07
413.1235657	0.21
414.1788635	0.08
423.1788025	21.96
424.4388428	0.04
429.0209656	0.25
440.9184265	10.35
441.7581177	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	600.294
Annotation	Phoslactomycin A
Peak:m/z	Relative Intensity
170.0669556	0.02
175.0402527	0.01
182.0757141	0.07
185.1431580	0.02
189.2738037	0.09
191.1215668	0.01
199.2150574	0.05
203.1280975	0.02
209.1345367	0.01
210.2488251	0.01
222.9188232	0.01
225.5093079	0.03
232.8643951	0.02
235.2974091	0.04
238.0872803	0.02
240.6454010	0.04
242.2895508	0.03
244.1688385	0.02
247.3587189	0.03
251.8103638	0.01
255.1708984	0.01
256.2732239	0.10
256.8972168	0.01
263.1799622	0.03
264.3868713	0.02
270.0721436	0.08
271.2677612	0.05
271.9454041	0.02
274.3796997	0.03
275.2680054	0.09
277.1729736	0.04
279.5530701	0.02
281.2716064	0.42
282.0737915	0.09
289.5734253	0.03
290.2441406	0.04
293.1321411	0.03
295.2720947	0.01
306.3225708	0.05
307.3330688	0.05
308.2213135	0.19
308.9063721	0.03
311.2596436	0.03
317.9558105	0.01
321.2965393	0.01
322.6202087	0.01
324.1914368	0.03
325.2346497	0.07
330.1968994	0.02
332.5496826	0.10
333.2334595	0.12
339.2160645	0.04
342.7044678	0.02
350.2544556	3.65
351.4325562	0.20
353.5645142	0.02
358.4679565	0.03
360.3302612	0.12
361.3401489	0.06
368.3513184	4.03
373.2819824	0.03
378.3090210	0.40
384.1508179	1.04
384.7640991	0.01
385.3650513	0.16
389.4157104	0.04
395.5968018	0.04
396.3314819	0.05
407.2907104	0.08
413.3020630	0.01
414.2629395	0.01
416.5937500	0.01
420.2452393	0.03
425.3879395	0.01
434.2982178	0.03
435.1027832	0.13
437.1716309	0.01
453.3124390	100.00
453.9432983	0.46
455.3826904	0.05
457.3574219	0.04
461.3064575	0.02
462.5126343	0.01
471.2506104	0.14
479.4678955	0.09
489.1279907	0.19
493.0310669	0.02
495.4433594	0.01
496.8781128	0.04
507.5361328	0.06
512.5278320	0.03
514.3648071	0.05
519.3899536	0.02
525.3092651	0.44
537.2782593	0.09
554.3631592	0.02
564.4216919	0.08
565.3703003	0.04
567.8028564	0.03
571.4388428	0.03
582.4049683	1.97
583.2665405	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8647919	3.90
295.0545959	0.36
296.7131348	40.29
297.3363647	0.17
302.5529175	0.05
323.2629395	0.42
324.1599121	0.14
345.2236938	0.07
356.6527710	0.04
378.1361084	0.32
380.5991211	100.00
381.2631226	0.83
386.6710815	0.35
440.5194702	0.06
458.3942871	0.21
462.2963867	0.31
464.4619751	46.69
465.5326538	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	488.1752
Annotation	Unknow
Peak:m/z	Relative Intensity
147.0391693	0.09
150.1588898	0.11
151.2156982	0.16
161.1242676	0.17
161.9007874	0.45
163.1475220	0.85
173.1177826	0.18
175.0065918	0.09
177.0192871	0.16
179.0659180	1.49
181.0555420	0.71
182.0986023	0.34
182.7307739	0.27
187.2807312	0.29
190.0614929	0.88
205.1792145	0.26
211.0882416	0.27
212.6173401	0.11
214.6434937	0.07
222.5494995	0.16
228.2850342	0.17
229.1622314	0.37
230.8749390	2.09
233.1911163	0.27
236.0717773	5.56
238.7114563	0.22
240.1674957	1.06
245.2499084	0.05
249.0202026	0.40
255.1064453	0.49
272.1542664	4.25
272.8574829	0.17
290.0588684	21.92
290.9224243	1.03
292.1219482	0.17
301.9871521	0.28
303.0570679	0.25
303.9365845	0.42
305.1771851	0.43
305.8126831	0.24
308.1379395	48.44
309.3741760	0.09
312.2330627	0.30
321.0725098	0.15
322.1215210	0.28
323.1711426	0.78
324.1864624	0.70
325.8993530	6.16
326.6022949	0.10
332.1333313	0.07
341.1053467	0.70
344.3442993	0.11
354.3058777	0.38
355.5566406	0.23
358.2173157	0.83
359.2155151	1.21
369.8621521	0.14
372.5856628	0.09
374.5191956	0.43
383.0578613	0.11
384.0453186	0.13
388.2005615	0.17
389.2980042	0.17
391.1436462	0.17
393.1789246	0.82
394.3246155	0.22
397.6346130	0.28
398.3938599	0.98
402.0766907	0.16
405.3796692	0.22
410.1328430	0.73
410.8814697	0.34
412.2586365	0.12
413.0617981	0.34
415.8660278	0.52
426.1985168	0.51
434.1258850	0.24
440.4716492	0.64
444.2040710	1.45
450.3049622	0.28
452.0593567	26.48
452.7569885	0.14
455.1994324	0.23
470.0241089	100.00
470.8180237	0.42
471.5456848	0.35
473.4131165	0.39
499.2095642	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1571
Annotation	a-L-Fucopyranosyl-(1->2)-b-D-galactopyranosyl-(1->2)-D-xylose
Peak:m/z	Relative Intensity
137.0253754	0.09
144.8095703	0.04
155.0017090	0.12
160.8882751	0.06
172.9975433	0.48
174.9174652	0.09
179.1401520	0.04
191.0332947	57.98
203.0613708	0.05
236.0857697	0.04
253.0945740	0.07
254.0623779	0.03
265.1628113	100.00
266.2142639	0.06
267.1383057	0.36
272.3935547	0.04
309.1794434	0.27
323.0039062	0.05
324.1561279	0.07
326.4396362	0.08
327.1325684	0.05
341.1552734	0.81
366.1588745	0.10
367.0971069	0.03
384.9693298	0.05
397.1937866	0.19
409.1899719	0.05
410.0103760	0.22
411.1327820	0.22
419.4300842	0.07
425.2944031	0.02
428.9800720	0.16
437.2696838	0.19
438.9218445	5.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0718
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
117.0993195	0.09
129.092453	0.05
152.846405	0.01
160.8617706	0.02
162.6749573	0.06
169.3566742	0.06
170.8946991	0.09
175.0108032	0.01
178.1373291	0.05
183.1042786	0.08
185.3951874	0.01
193.083252	1.09
195.1466217	0.10
197.161438	0.02
198.1607971	0.03
199.212326	0.04
204.1347961	0.03
205.1923218	0.01
213.1977539	0.03
213.8217773	0.01
217.1172791	0.01
219.0530701	0.03
223.2055969	0.07
225.1166687	0.10
229.1304016	0.05
239.1676025	0.10
240.0412598	0.01
241.2875061	0.28
242.1300049	0.03
243.2839966	0.04
246.2169189	0.02
251.1917725	0.07
253.0706787	0.07
254.0845642	0.06
254.9730835	0.06
257.2395935	0.29
259.1227112	0.01
267.1593018	0.79
270.0900879	4.33
276.1003723	0.06
277.7106018	0.03
281.1706848	0.13
282.098114	0.38
283.1233521	2.47
285.0740662	8.02
285.8484497	0.05
292.5927124	0.01
293.302887	0.03
294.0141602	0.08
295.2036743	2.64
295.9260254	0.02
298.0488892	100.00
298.9683838	0.13
312.7214355	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1719
Annotation	Unknow
Peak:m/z	Relative Intensity
127.9344177	0.07
142.9009094	0.13
149.9974365	0.19
154.8575745	0.03
157.9501038	0.07
161.1949463	0.14
162.2063599	0.37
165.0953979	1.09
179.0722351	0.19
181.9556580	0.05
187.0373077	0.10
188.3781891	0.07
191.1215973	0.05
195.0318756	0.29
199.1335144	1.84
200.1483917	1.15
201.0826111	4.05
204.2692413	0.08
209.9621124	0.12
212.6622620	0.12
221.0501099	0.14
228.5212402	0.05
241.1468811	0.49
247.0830688	0.16
250.8110657	0.17
253.0058289	0.04
256.2868347	0.10
258.1693420	0.05
259.1053162	0.40
261.0967712	0.07
264.9493713	0.58
268.0393372	0.25
272.3819275	0.07
273.2775879	0.05
275.4231567	0.27
286.8159485	0.19
288.2636108	0.17
289.2046509	0.04
291.0726318	0.17
293.1345825	0.14
294.4750366	0.10
301.1315308	0.10
302.0109863	0.06
303.2955322	0.56
304.4042358	0.44
305.2261353	2.88
307.4841309	0.10
315.1732178	0.07
319.0394592	0.03
321.1697998	0.50
321.9622803	0.05
323.2518311	0.46
329.0916748	0.31
329.7959595	0.07
331.2677307	0.03
333.1334839	0.08
341.0068970	0.06
345.3757019	0.16
347.5135803	0.47
348.2223206	1.51
349.2828369	1.25
355.1232300	0.35
361.4382629	1.27
363.2092896	100.00
365.1045227	7.41
365.7628784	0.04
366.4188843	0.09
371.3315735	0.26
373.2069397	0.96
375.1341248	0.08
377.2561951	0.29
379.4012451	0.18
381.2342224	0.19
388.9574280	0.11
390.1740417	1.13
391.1981201	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.072
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
156.3400726	0.02
165.098114	0.02
177.9902344	0.02
185.25737	0.01
191.1527557	0.04
193.1293335	0.01
197.044342	0.04
199.3770142	0.01
204.066925	0.01
211.2456055	0.06
219.2601318	0.03
223.2122498	0.04
225.2382202	0.02
236.990509	0.01
239.146759	0.01
244.2322083	0.02
250.1868896	0.02
251.3465271	0.06
253.2779236	0.12
254.1035461	0.02
255.1629333	0.07
257.1400452	0.02
267.1915894	0.10
269.0757751	0.58
270.1161499	0.06
277.3554688	0.10
281.1642151	0.17
282.4577026	0.21
283.0927734	2.89
284.2556152	0.02
285.1207581	0.26
293.2079163	0.07
294.2312012	0.08
295.2574463	0.29
296.0283813	0.01
298.0526733	100.00
298.6751404	0.09
313.2073364	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	909.4018
Annotation	Unknow
Peak:m/z	Relative Intensity
350.3351746	0.10
592.7206421	0.17
608.5240479	0.15
612.8083496	0.06
616.2649536	0.21
641.4548340	0.09
660.4601440	1.22
664.7258911	0.22
698.6267090	0.12
724.2413940	0.24
726.8760376	0.21
730.4785767	0.18
731.7073364	0.14
748.4445190	0.08
749.5453491	0.78
768.3643188	0.07
773.5598755	0.11
805.4744263	0.40
822.5169067	0.05
861.2229004	0.08
875.6694946	0.07
893.7695312	0.58
911.5103149	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1273.3456
Annotation	Unknow
Peak:m/z	Relative Intensity
446.4419556	0.01
692.1644897	0.00
733.2631836	0.01
913.0216064	0.02
914.4434814	0.05
1093.8640140	0.02
1112.2386470	0.67
1274.1994630	100.00
1274.8920900	0.27
1275.6318360	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.4174
Annotation	Isorebaudioside A
Peak:m/z	Relative Intensity
328.5779419	0.07
351.2590942	0.05
354.5726318	0.32
360.4312134	0.05
501.2333984	0.30
752.4569092	0.07
821.0507202	0.40
843.8088989	0.31
920.7080688	0.45
936.7849731	0.20
964.7537231	25.85
965.4216919	100.00
966.5194702	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	287.1957
Annotation	N-Acetyl-leucyl-leucine
Peak:m/z	Relative Intensity
83.8218689	0.04
97.8016815	0.02
102.1606674	0.04
115.9672089	0.02
140.9752197	0.04
143.9462280	100.00
147.0451355	0.01
158.0859222	1.24
231.1595154	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.1747
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
121.0209198	0.10
123.0532379	4.11
124.8141861	0.12
126.9583130	1.15
133.0548248	3.29
140.8814545	0.09
145.2304535	0.07
147.1468658	0.03
149.1567993	0.03
151.0618439	5.68
159.2715302	0.08
160.8290863	0.04
166.9607849	0.34
168.9933014	100.00
173.1796570	0.16
183.0466309	0.10
187.0402679	0.20
193.3106537	0.31
194.9878235	0.05
208.8894653	0.05
212.5272217	0.55
213.2865601	0.07
225.0714417	0.08
230.9779663	6.02
233.1042480	0.10
235.0133972	0.12
241.2097473	0.05
248.8865662	0.38
250.9716797	0.06
255.2675781	0.06
259.1697998	0.07
268.2948608	0.04
272.3880005	0.12
277.2369995	0.22
286.9240112	0.13
289.1543884	0.04
306.1540527	0.13
308.7845764	0.05
327.1265259	0.22
330.8501892	0.04
339.0605164	0.29
349.2347107	0.02
353.5563660	0.10
355.2121582	0.12
358.3948975	0.04
363.3444214	0.47
369.1954956	0.11
370.1133728	0.12
371.2824097	0.03
381.0894165	4.91
384.3487549	0.12
385.2786560	0.24
387.5258484	0.59
389.2638855	0.06
397.0042419	0.05
398.5814209	0.33
399.1907043	1.71
417.0361328	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1133.3665
Annotation	Betadex
Peak:m/z	Relative Intensity
1133.390625	100.00
1134.581055	24.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.1901
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
203.2568665	0.03
225.1027527	0.01
231.2497711	0.01
247.0717468	0.03
267.1983643	0.02
283.0735779	0.05
285.3228455	0.07
286.2660828	0.08
288.4409790	0.02
299.9940186	0.05
301.1769409	0.11
302.9862671	0.04
313.5569458	0.03
316.1079102	6.80
317.1452332	1.08
317.7559814	0.01
331.1372986	100.00
332.1399536	17.44
333.2361755	0.14
334.3645020	0.09
342.3911743	0.02
360.1450806	0.01
368.1019897	0.01
373.1191406	0.32
374.3994141	0.05
439.4367065	0.01
448.4628906	0.03
459.5863037	0.03
475.2583008	0.07
477.3114624	0.02
482.4595947	0.02
493.0443115	35.10
494.1002808	7.26
495.0203247	0.03
519.0399170	0.02
529.3726807	0.01
543.3352661	0.01
558.5156860	0.04
559.6080933	0.06
573.5239868	0.01
582.5308228	0.02
603.0885010	0.11
606.9757080	0.02
621.2962646	0.07
641.4891968	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1093
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
138.2079773	0.02
141.1286621	0.02
142.7900696	0.02
153.0762634	0.08
175.1322632	0.02
178.9994812	0.03
193.0233765	0.02
217.3179932	0.02
245.1651001	0.02
253.2206116	0.02
254.3386841	0.03
263.0971375	0.21
283.3872681	0.07
284.0820007	0.02
285.1416626	0.06
297.3787842	0.04
298.0634460	0.36
299.1533813	0.25
304.8735352	0.04
311.1354065	0.02
313.2837219	0.52
323.3096313	0.03
324.9245605	0.03
326.0627441	0.30
329.0190735	0.01
338.2745056	0.03
339.2136841	0.05
341.1541748	100.00
341.8451538	0.17
343.4123535	0.01
353.0581055	0.45
355.2380981	0.06
356.1646118	0.09
362.3862305	0.02
365.4971619	0.03
368.2016907	0.03
371.1697083	6.94
371.8127747	0.08
375.1336060	0.04
381.4365540	0.07
383.2020569	0.61
385.2004700	0.16
395.0716858	0.08
397.3047180	0.13
401.1408691	0.19
407.1542053	0.26
413.2412720	0.37
414.5343323	0.10
415.4138184	0.41
417.1177063	0.38
425.1160889	0.29
442.5938416	0.07
443.2624207	0.75
446.1678162	0.15
462.4152222	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1233
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
187.2279205	0.02
194.6603851	0.13
198.1837158	0.05
214.8801270	0.03
219.0490723	0.06
229.3832245	0.02
233.1543732	0.04
279.1053467	0.03
298.1797485	0.06
299.3212280	0.27
300.3314209	0.34
301.2335510	1.36
310.0533447	0.06
313.1591797	1.22
325.1989746	3.40
335.3034668	0.08
341.1102905	0.10
343.1956787	42.64
344.1027222	0.08
345.3034668	0.05
353.2290649	0.04
355.2922363	0.08
357.2619019	0.13
358.3997192	0.04
359.3644409	0.08
363.2711182	0.03
367.1823120	22.92
368.0075684	0.01
370.9928589	0.01
377.3521729	0.09
379.2207642	1.04
381.1325684	0.14
383.1315308	0.08
385.3027954	0.01
387.2249146	0.02
391.2553711	0.39
394.0756226	0.13
394.8751221	0.09
397.1734619	4.49
400.2536621	0.10
401.3587646	0.38
402.3212280	0.58
403.4215088	0.07
405.0231934	0.08
409.1868286	19.89
427.2254639	4.73
436.3853149	0.12
438.8311157	0.04
445.2119141	10.10
451.2410278	0.44
452.9841919	0.07
455.2715454	0.04
463.2373047	5.25
469.1939087	4.24
470.2787476	0.04
477.4293213	0.05
483.2727661	0.29
487.2631836	4.39
489.3930054	0.02
490.4453735	0.01
495.1718140	0.80
502.2171021	0.11
505.1915283	1.21
513.1379395	61.92
513.7708130	0.23
531.1887207	100.00
532.1046143	0.02
533.4039917	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.1721
Annotation	Unknow
Peak:m/z	Relative Intensity
232.7156677	0.06
243.1508942	0.20
259.1668396	0.17
263.3253479	0.26
266.5158691	0.17
280.9735718	0.10
285.9668579	0.13
293.2990723	0.14
301.1002502	0.49
302.3018799	0.19
306.9354248	0.09
311.9376831	0.13
315.1412964	0.09
319.3030396	0.22
325.2008057	0.12
328.3746338	0.10
329.3030396	0.25
339.1372375	0.37
345.1541748	0.09
346.1895142	0.12
349.1392212	0.14
353.1824341	0.41
354.0412598	0.03
359.3305054	0.12
372.1234741	0.20
376.7864990	0.13
384.2294312	0.10
386.4190063	0.10
390.6144409	0.11
392.2626953	0.22
409.4041138	0.10
411.1383057	0.24
412.5850220	0.06
415.3564453	0.50
417.2849121	0.04
419.6085815	0.16
420.5077515	0.10
451.4325562	0.31
453.5382080	0.30
456.3844604	0.18
459.3886108	0.56
463.2792358	0.13
474.2529907	0.11
475.3931885	0.08
477.2125854	0.14
478.1820068	0.27
479.3592529	0.39
489.4205933	0.35
490.3835449	1.12
491.2424316	0.33
493.4112549	0.35
495.4559937	0.47
496.3081665	0.32
507.3872681	0.12
510.2253418	0.11
517.3949585	0.27
519.3468018	0.71
522.5715942	0.24
527.5697632	1.84
531.1130371	0.51
539.3166504	0.76
547.4306030	0.26
551.0688477	0.06
553.6644287	0.16
555.3519287	4.66
557.7471313	0.16
559.5839233	0.12
569.4459839	0.32
571.4513550	8.17
572.5675049	0.29
573.4612427	0.43
577.6450806	0.26
580.2861938	0.06
581.1370239	0.36
589.0857544	0.06
590.2499390	0.18
597.6237183	0.09
599.4472046	16.98
600.5565796	0.34
611.0690918	0.09
613.5509033	0.33
614.3038330	0.23
615.5237427	2.83
617.3587036	100.00
618.4734497	0.63
622.4090576	0.19
623.2410278	0.65
626.6737061	0.13
629.3716431	0.06
631.4475708	13.71
635.7794800	1.08
636.6629639	0.12
637.9038696	0.24
640.9080200	0.82
659.3816528	2.40
660.4109497	0.68
779.1588745	0.11
779.7993774	0.14
943.2783203	0.06
1125.6225590	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
113.0026398	0.23
118.9945374	0.07
130.6245422	0.09
161.0744019	0.28
161.9216614	0.02
179.0283508	2.42
179.9974365	0.08
197.2661896	0.09
198.0330658	0.19
198.9847107	0.34
215.1095886	1.55
216.2254028	1.97
217.0757904	7.36
333.0112915	0.02
341.1530457	100.00
342.1508179	32.97
343.2544556	8.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	273.0752
Annotation	Alternariol monomethyl ether
Peak:m/z	Relative Intensity
90.8476105	0.39
92.9973907	0.05
106.9999161	0.41
109.0234680	0.05
111.0106049	0.32
118.9439926	2.37
120.8729782	2.40
122.8630066	0.74
124.9713516	0.01
126.8232422	0.03
136.0854187	0.03
144.9691772	0.01
146.9295044	65.11
148.9436798	0.06
150.8727722	0.70
152.8853149	100.00
153.9085236	0.07
161.0411682	0.22
162.9900970	0.54
166.9835815	0.07
168.7664795	0.09
170.9692535	0.36
179.0358124	8.28
183.0127869	0.07
184.9445038	0.03
186.9020081	0.03
188.9736023	4.04
201.0292664	0.02
202.9236755	0.07
207.0776672	0.10
213.0826111	0.30
214.1800232	0.11
227.0646973	0.15
229.0366211	0.08
230.9808960	4.29
237.1658325	0.14
244.9998169	0.16
250.7078857	0.02
255.1171875	1.33
257.0364380	0.06
258.2815552	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	554.3836
Annotation	Unknow
Peak:m/z	Relative Intensity
155.2867279	0.21
157.1631165	0.09
159.2410889	0.17
161.0290680	0.06
167.4016418	0.27
168.9957123	0.10
171.0745392	0.64
174.9306030	0.20
177.1548157	0.40
181.0824738	0.49
183.0699921	0.05
185.0825348	0.48
187.1326904	0.85
189.1849060	0.15
195.2600403	0.19
196.4387207	0.36
199.3532562	0.12
201.2287292	0.51
207.0736389	0.57
207.7464600	0.12
209.0891113	0.22
211.1808472	0.50
213.1257324	1.13
214.8684998	0.28
221.1009521	0.13
223.1662750	0.61
224.9874878	0.52
227.1976318	1.29
228.1078339	0.11
229.2046509	0.56
235.3648834	0.52
237.1526184	0.15
239.1005707	0.94
243.2513123	0.24
245.5231781	0.38
249.4125977	0.20
251.1324158	0.35
253.3271484	0.37
257.3720703	0.08
263.0594482	0.34
264.2003784	0.29
265.3317871	0.19
271.6152039	0.29
274.2036133	0.29
274.9688416	0.12
277.1271362	0.07
279.4165649	0.63
281.2707520	1.74
283.2509766	0.08
291.2267456	0.37
295.1179199	0.42
297.2979126	0.26
301.6331177	0.07
303.2803955	0.19
305.1817627	0.41
307.3209839	0.93
309.4278564	0.65
313.6088867	0.28
319.3029175	6.34
321.3889771	1.53
323.5154419	0.31
324.1992188	0.30
331.0790405	0.41
333.2546997	1.66
335.2659302	3.67
337.2651978	1.36
339.3001709	0.18
343.2125244	0.28
345.5536499	0.22
349.3405762	0.07
353.3234863	0.07
357.2187500	0.07
359.4129028	0.26
361.2258911	0.75
363.2778931	0.56
364.0992432	0.16
374.5515137	0.16
375.3062744	0.06
375.9839478	0.18
377.4946289	1.82
379.4194336	1.63
381.4420776	0.83
383.2667236	0.42
384.4330444	0.10
386.0590210	0.14
393.6077271	0.33
395.2575684	1.77
397.4200439	1.63
399.4158325	1.72
403.4052124	0.14
408.2315063	0.11
411.3480225	0.85
416.8254395	0.23
417.4321289	7.96
419.2683716	0.19
421.7437134	0.44
422.8866577	0.04
423.5578613	0.25
435.3892822	5.57
437.5496826	0.32
440.9180298	0.33
441.5860596	0.84
447.3421631	0.38
449.5772095	0.25
452.7875977	0.23
454.4034424	0.14
455.4396362	1.87
459.3937378	0.12
471.9580688	0.28
476.6138916	1.41
477.4324951	2.26
487.6123047	0.33
493.4248657	0.82
495.3649292	100.00
496.0051880	0.21
508.8629761	0.20
519.4583130	0.66
520.2501221	0.44
523.6339111	0.17
526.0398560	0.12
535.4234619	0.09
536.5505981	0.59
553.1041260	0.07
556.4368896	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1857
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
169.2643127	0.08
177.0727081	0.14
186.1333923	0.03
191.3724060	0.08
193.0462952	0.07
195.0648804	0.23
218.9601288	0.06
222.1711121	0.05
235.1291809	0.04
245.0830536	0.13
254.9744720	0.05
256.0816650	0.07
263.0276794	0.22
271.0955200	13.93
272.0825195	17.24
273.1125793	6.09
274.2470703	0.09
279.5651550	0.01
281.1617432	0.42
283.0460205	0.10
285.0954285	0.12
286.8843994	0.03
296.1238403	0.03
297.2978821	0.59
306.3623352	0.12
307.2021179	0.08
311.1420593	0.03
314.4078979	0.41
315.2367554	1.38
331.4406128	0.04
332.1691895	0.03
333.1605225	0.21
335.9778442	0.12
337.0585327	0.07
339.1494751	0.85
341.1999512	0.04
345.1551514	0.09
346.2567139	0.30
347.2559814	0.07
351.2221069	0.04
363.3304443	0.13
364.3980713	0.13
365.1531372	0.24
367.2212524	0.62
368.2664185	0.04
368.9951782	0.16
374.2346802	0.11
375.7180786	0.24
381.2514648	0.60
382.2504883	0.19
383.2028809	1.71
386.9429321	0.03
395.0769043	0.06
398.1838379	0.03
399.2048340	1.06
400.9895020	2.08
401.7699585	0.04
411.1128540	0.07
413.2905884	0.21
416.1305542	0.42
417.1538086	4.31
418.4887085	2.12
419.2146606	4.00
425.1872559	0.02
427.1646729	0.23
429.4307861	0.13
431.0496826	0.02
433.1391602	30.99
434.1359863	100.00
435.1554565	19.27
442.7495117	0.18
443.4187012	0.25
447.1421509	0.17
449.0803833	0.27
459.1526489	1.25
461.0144653	0.38
462.4966431	0.17
466.9161377	0.32
469.2324219	0.09
473.1909180	0.12
476.0665283	0.44
477.3677368	0.05
493.3601074	0.06
497.1146851	0.28
499.3465576	0.14
500.0686646	0.13
509.0960083	0.46
512.4307251	0.11
513.0479736	0.03
517.0604858	0.15
518.2799683	0.11
521.3340454	0.04
522.5335693	0.63
523.4408569	0.36
527.1002808	1.15
529.8184204	0.10
536.6086426	0.48
545.0852661	2.10
548.2904663	0.20
553.4346313	0.08
557.2567749	0.04
562.3931274	0.57
563.2147217	2.48
580.3167114	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	362.9971
Annotation	Unknow
Peak:m/z	Relative Intensity
110.8935623	6.54
114.9988022	0.40
122.6234589	0.06
124.6653748	0.04
129.1289368	0.20
132.9551697	6.24
137.9367676	0.06
155.0189209	0.15
164.2593994	0.04
166.6755676	0.12
171.1523285	0.04
172.9754944	0.99
181.9662170	0.17
188.0849152	0.04
190.9462433	100.00
198.6375427	0.08
199.9784546	0.05
201.2947235	0.04
205.2178955	0.03
211.1498413	0.13
220.9113770	0.16
223.2966003	0.04
230.9849854	0.14
232.8627625	0.11
241.0982361	0.07
247.0276794	0.12
259.0243835	2.39
265.0222168	0.37
270.9141235	0.07
271.7016296	0.12
272.3357849	0.03
273.1067505	0.04
274.0290527	0.12
289.0888672	0.15
290.9065552	0.22
300.1217651	0.07
301.0611267	0.10
303.0000000	0.46
306.4779663	0.02
311.3675232	0.04
317.0245972	0.05
318.1257935	0.15
327.2290649	0.46
331.1401672	0.04
334.4651794	0.03
345.0067749	1.91
346.0858154	0.12
347.0693970	0.11
348.4919128	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.109
Annotation	Lactulose
Peak:m/z	Relative Intensity
100.9280319	13.09
112.9587708	26.08
116.8257141	0.19
118.2206726	0.98
118.9230347	19.91
124.9742355	2.64
128.7466583	0.22
130.9000092	13.51
133.0421143	0.27
142.9375000	28.35
148.8416138	5.62
158.7138214	0.84
160.9269104	21.33
178.9629974	100.00
182.7070312	0.32
184.0916138	0.26
185.1669464	0.17
198.1832733	0.77
221.3308105	0.20
250.4170532	0.31
281.1473999	1.62
295.2892151	0.25
322.9849243	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1116.32
Annotation	Unknow
Peak:m/z	Relative Intensity
313.1634827	0.11
315.3995667	0.03
316.1280212	0.03
317.0984192	0.08
318.2475281	0.03
328.0700378	0.27
329.2036133	0.20
330.1353455	0.08
331.2108459	0.88
332.1582336	0.42
333.2231445	0.47
339.2413025	0.04
346.1477661	0.43
346.9476318	0.13
348.1585999	0.26
358.1144714	0.05
361.1393738	6.95
362.1829529	4.85
363.2048645	2.33
368.2864380	0.02
387.2965393	0.10
388.6318970	0.01
392.9587708	0.04
394.4899597	0.03
397.2362061	0.09
403.1525879	0.05
405.2142334	0.06
406.1346436	0.08
412.3718567	0.07
413.1843872	0.03
415.3267822	0.04
416.0299683	0.06
423.2201538	0.13
425.0162354	0.06
426.4484253	0.02
430.1091919	0.06
438.9078674	0.04
440.3413086	0.02
446.0405884	0.06
451.1700439	0.61
452.7975159	0.13
453.5043945	0.13
454.4746704	0.06
466.0662231	0.04
468.9563904	0.06
470.2888794	0.17
471.2323303	0.16
488.3670044	0.03
489.3212280	0.16
495.1565552	0.04
499.0766907	0.03
513.8911133	0.03
524.1132202	0.22
525.1884155	0.05
537.1903076	0.06
538.1733398	0.05
548.2395630	0.06
550.3601074	0.11
555.2270508	0.03
568.1876221	0.02
580.2952881	0.16
587.3033447	0.05
601.9976807	0.05
605.0963135	0.20
606.3243408	0.32
607.4362793	0.26
608.9437256	0.14
631.2701416	0.03
632.3366699	0.08
639.3385010	0.16
649.0430298	0.24
650.1458740	0.52
650.9788818	0.15
663.2528076	0.17
666.9728394	0.35
668.3881836	0.25
669.1959229	0.44
674.2319336	0.05
681.1177368	0.04
682.2150269	0.12
693.1823120	0.13
699.1469727	0.02
700.0729980	0.25
700.6993408	0.08
709.3969727	0.35
710.4248047	0.06
711.3064575	0.09
714.3112793	0.02
735.4485474	0.12
736.0986938	0.18
736.8094482	0.02
739.4473877	0.20
740.0628052	0.06
741.5563965	0.04
746.3984375	0.04
758.2125244	0.11
759.4475708	0.12
769.4385376	0.10
770.1968994	0.30
771.4952393	0.13
775.1911621	0.66
776.3445435	1.23
777.3750000	2.13
782.1694336	0.05
783.3676147	0.03
793.3908691	0.44
794.3465576	0.83
795.3391113	1.54
811.1898193	0.49
812.2402344	0.65
813.3234863	0.84
819.0635986	0.03
902.5563965	0.05
935.7186279	0.02
937.4453125	0.03
965.3884277	0.06
1079.3461910	0.33
1115.1989750	100.00
1116.2009280	2.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	900.4763
Annotation	Unknow
Peak:m/z	Relative Intensity
540.6483154	0.07
597.3639526	0.30
621.4308472	0.70
622.0916138	0.01
654.6356201	0.04
668.7742920	0.15
679.3541870	0.04
696.1635132	0.09
697.5305786	2.23
736.5889893	0.06
846.6664429	0.01
864.5659180	100.00
865.5396729	0.43
900.5851440	25.58
901.4854126	61.70
902.1770630	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	316.1556
Annotation	2-Nitroestra-1,3,5(10)-triene-3,17beta-diol
Peak:m/z	Relative Intensity
114.8073196	0.05
121.0192337	0.36
123.8920746	0.10
125.8048096	0.14
128.0274048	0.09
133.7628174	0.06
147.9198914	0.07
148.8683167	0.25
149.9378967	3.39
152.1048126	0.16
159.3672485	0.10
160.9115753	0.08
162.1109619	0.06
163.1497192	0.07
164.1271362	0.40
165.9388733	0.06
171.2150574	0.05
173.2481995	0.05
174.0427551	0.14
175.8420868	0.14
177.0382538	0.29
179.0388794	0.38
184.3711853	0.03
186.0625000	0.16
187.1900177	0.04
188.1853027	0.31
189.2646179	0.11
191.2325745	0.09
193.1831970	0.04
199.2292633	0.05
203.0494690	24.68
204.0917053	0.93
213.2021790	0.06
214.1662598	0.10
215.0621033	0.53
217.1658325	0.43
218.0533142	0.09
219.7994690	0.20
220.5391541	0.04
227.0871277	0.71
229.1115417	1.44
230.1136169	3.02
231.0877686	0.10
233.1351929	0.02
239.7151794	0.14
242.1768494	0.04
243.2557068	0.37
244.2351990	0.24
245.2820129	1.86
247.0597534	0.27
251.5614929	0.07
253.2945251	0.13
254.1546326	0.52
257.1470032	0.35
260.3251953	0.21
261.1639404	0.35
262.1936340	0.09
271.1639404	100.00
272.2042847	5.98
273.3483887	0.31
274.1192627	0.11
279.3466187	0.10
289.1504517	3.26
296.0755005	0.10
298.0397644	12.92
298.8423767	0.03
300.0708618	0.04
301.1081543	1.42
315.9972534	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	520.1864
Annotation	Unknow
Peak:m/z	Relative Intensity
149.1730347	0.20
160.6750946	0.16
175.1243591	0.70
175.9911194	0.09
177.2268677	0.11
178.9751740	1.08
180.2391663	0.31
181.2364197	0.26
185.1823425	0.56
186.1404877	0.21
190.9164276	0.05
201.0546265	7.04
202.6985474	0.08
204.0540924	0.23
206.8493347	0.16
212.8352966	0.09
219.1606750	6.37
235.0925598	0.21
237.1357117	3.18
245.2230072	0.11
251.1874237	0.04
254.1065674	0.08
255.1110840	0.14
257.9956360	0.14
261.0739746	0.24
271.1228943	0.10
273.5371094	0.24
279.4208984	0.21
291.0358276	0.05
300.2243042	0.22
301.4395142	0.12
306.3563843	0.42
307.0844727	0.34
309.2315674	0.10
312.1162109	0.13
314.1401978	0.16
319.0919189	0.07
319.9920654	0.14
325.2708740	0.11
326.3491821	0.07
355.5026855	0.13
357.1618652	0.25
358.4022217	0.10
361.0012207	0.05
376.1170044	0.12
381.2922363	0.42
399.2623291	100.00
414.3194580	0.22
434.1035767	0.27
442.3547974	0.07
447.0120239	0.10
460.1604614	0.08
466.3296509	0.22
474.2582397	2.08
476.6231689	0.14
482.3828125	0.09
484.3232422	0.41
501.0661011	0.05
502.0891113	0.28
502.8045654	0.11
521.6587524	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	522.1828
Annotation	Herbicidin E
Peak:m/z	Relative Intensity
161.1190186	0.04
168.0983887	0.26
178.9862366	2.35
180.0292053	0.37
191.0986176	0.30
206.1813965	0.23
213.2498474	0.10
265.0506592	0.10
269.1688232	0.21
281.1257324	0.25
300.2644043	0.03
303.4030151	0.34
306.4285278	0.16
339.2731934	0.07
341.2141724	100.00
359.1195679	0.06
367.6670532	0.11
405.2688599	0.16
418.4456787	0.10
430.2587280	0.07
431.4993286	0.40
432.1899414	0.07
434.0395508	0.10
458.0101929	0.03
478.5585327	0.10
485.1373901	0.27
503.0884399	0.21
504.4042358	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.1606
Annotation	Dobutamine
Peak:m/z	Relative Intensity
105.9887924	0.36
106.8445358	0.41
107.9715347	0.10
115.9418640	0.38
118.0715942	0.11
118.9478226	0.25
120.9786377	0.02
124.9342651	0.16
132.0388947	0.30
134.0649719	8.78
135.0561523	1.17
136.1469879	0.13
141.0824585	0.05
143.0286865	0.02
146.0453491	0.10
146.8921661	1.67
148.1051331	0.54
149.7007294	0.11
151.0633240	0.35
156.0631714	0.71
157.0606384	0.04
158.1264191	0.10
159.1752319	0.71
160.0308533	0.93
161.1306915	0.23
161.8372650	0.03
163.0855408	0.18
164.0080872	0.06
166.8930359	0.05
168.9559174	0.32
170.0960541	0.11
174.0283813	0.16
176.3149719	0.17
177.1561584	0.18
182.1958771	0.08
183.0077972	0.05
184.2606354	0.05
186.1359253	0.38
187.0629883	1.62
188.0531311	3.13
189.1044312	0.18
198.1997681	0.37
199.1571960	1.09
199.8308105	0.04
201.2487488	0.09
203.1325378	0.05
204.2374878	0.14
209.3482666	0.11
210.9459839	0.14
212.3893738	0.24
213.1689453	1.34
214.1659241	0.26
215.1893616	0.26
217.1807251	0.10
221.0096130	0.06
223.3383789	0.03
225.1487122	0.03
227.2174377	0.59
228.1540833	0.72
229.1551514	36.82
230.2069092	8.09
231.1229858	1.93
232.1961060	0.39
233.0874939	0.15
237.2100525	0.13
238.2744141	0.42
239.2712708	0.33
241.2983704	0.05
242.1215820	0.68
243.4008179	0.17
244.0586548	0.11
245.3412476	0.51
246.1379395	0.29
253.3605957	0.05
255.1838379	3.07
256.0936890	7.68
257.1427002	1.87
257.9447632	0.11
265.1136475	0.13
268.3311768	0.15
271.7175293	0.12
273.0997009	1.58
274.0126343	0.10
282.1763916	100.00
283.1984863	21.20
284.2734680	0.06
285.9577637	1.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.151
Annotation	Unknow
Peak:m/z	Relative Intensity
181.2206268	0.08
188.4146729	0.07
195.2043610	0.06
199.0060425	0.23
201.3247375	0.16
211.0625000	0.08
214.4140625	0.12
215.0817871	0.31
217.2416992	0.28
220.9878387	0.07
222.2002106	0.14
225.3534393	0.33
230.2127686	0.07
232.0534210	0.08
239.0550232	0.71
241.2703094	0.30
242.1684875	0.06
243.0188293	0.32
246.2675629	0.06
251.8872681	0.12
256.1461792	0.45
257.4116821	0.06
267.0825806	0.11
268.2608643	0.10
269.0946045	0.38
270.0912476	0.18
271.0394897	0.46
281.0250854	0.90
283.2696533	0.36
284.0935974	0.17
284.9315186	0.14
285.9649353	0.29
287.2348938	1.48
287.9992065	0.05
293.3242798	0.24
297.2231445	0.19
298.0943298	0.10
299.1319580	0.26
300.0283508	1.63
301.3461304	1.40
302.2957153	0.52
308.2465820	0.60
311.0283813	1.17
312.2525330	0.26
313.1973877	0.37
314.3845825	2.62
315.1076355	8.37
316.2318115	2.02
318.3365173	0.10
325.3916626	0.09
326.1654053	1.05
327.3519287	0.10
328.0173340	0.96
329.1870422	15.02
330.2088013	46.54
331.1333618	7.50
337.0493774	0.05
339.3457642	0.06
340.1636353	0.36
342.2410278	0.50
343.3826294	5.10
344.1227417	26.23
345.1650391	100.00
346.1486206	14.38
350.3866577	0.10
351.3084717	0.27
352.1992798	0.40
355.1393433	0.72
356.4160156	0.15
357.5606079	0.46
359.1291504	46.66
360.2103882	7.87
367.3237305	0.10
369.1522827	0.11
369.8952637	0.15
371.1411133	0.40
372.2971191	1.20
373.4665527	0.15
375.9553223	0.11
377.9629517	0.18
386.1968994	0.39
387.2057495	4.53
388.1270752	0.86
396.2700195	0.17
401.1467285	1.44
402.3041382	0.20
410.9703369	0.43
412.4958496	0.13
415.5272827	0.09
416.2013550	0.26
421.4308472	0.17
429.2709961	0.51
430.2219238	0.30
433.1766968	0.13
443.2687988	0.72
444.0421753	0.09
446.2307129	0.26
447.3167725	0.26
457.4661865	0.16
461.1930542	0.28
462.4191895	0.14
474.4594116	0.26
478.4725952	0.08
489.2357178	0.88
495.0155640	0.17
503.1648560	0.23
518.1339722	0.38
522.4327393	0.05
539.6717529	0.10
553.3997192	0.13
555.3820190	0.15
565.5604858	0.45
566.4296265	1.15
567.2608032	0.27
578.0559692	0.09
581.0498657	0.37
582.3597412	0.71
591.4948730	0.09
593.1538696	0.16
594.0728760	0.53
595.3645020	0.63
597.3932495	0.59
598.5186157	0.09
609.2750854	5.13
610.3176270	2.67
611.2847290	3.24
612.2671509	0.69
613.3920288	0.16
623.4943237	0.16
624.9360962	0.36
626.2346802	78.48
627.2595215	24.18
642.2262573	13.27
643.3758545	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1069.5243
Annotation	Unknow
Peak:m/z	Relative Intensity
440.8391113	0.03
632.3250732	0.03
832.7320557	0.02
1033.0866700	0.06
1069.4772950	100.00
1070.1602780	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1431
Annotation	Hesperetin 7-O-rhamnoside
Peak:m/z	Relative Intensity
150.9859161	0.24
152.7257996	0.15
153.4696503	0.04
168.8404694	0.13
170.0727234	0.18
177.0853882	0.69
179.0797729	0.08
183.3638306	0.04
192.9543762	0.09
195.0104980	5.85
199.9149780	0.12
201.2654724	0.12
203.2018433	0.09
207.0535583	0.05
219.0326538	3.35
221.0532532	0.12
223.3550415	0.07
224.9979248	0.26
232.9324646	0.14
235.3064880	0.09
237.1973724	0.07
239.0810547	0.35
243.0664062	0.14
245.0860291	2.60
249.2191162	0.06
251.4842224	0.06
258.9851685	0.31
260.8524475	0.10
263.0992737	15.64
277.1467896	0.05
278.1361084	0.06
279.4296265	0.21
281.0935364	5.04
285.1263123	0.17
287.0686646	0.45
289.1775818	0.23
297.9393616	0.31
299.0200806	0.78
301.2064209	0.09
303.1567078	7.34
304.0718384	0.22
309.4019165	0.28
315.2151489	2.88
318.2729492	0.12
327.1947937	3.78
328.1483459	0.10
329.2258301	0.39
339.0704346	0.12
343.1910400	0.04
345.1958618	19.22
351.7458191	0.04
353.1926880	0.16
355.4647827	0.13
357.1084290	0.14
363.0377808	0.10
369.1784973	24.08
370.3101501	0.31
371.1216736	0.06
375.4968872	0.16
383.1357117	0.29
384.2382812	0.15
387.2839661	0.36
389.1525269	0.08
390.2392883	0.10
391.2070618	0.18
395.1805725	4.85
399.1191101	0.08
403.2888794	0.03
413.1277771	100.00
413.7795715	0.56
416.0572205	0.22
417.0581360	0.51
418.4597168	0.24
431.1839600	94.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	263.1749
Annotation	(+)-5,17-Dehydromatrine N-oxide
Peak:m/z	Relative Intensity
83.9316101	14.18
85.8804474	21.94
90.9310455	0.05
97.9921112	21.45
99.8964615	59.64
106.9523926	2.80
112.0282593	1.59
116.9797058	100.00
117.8096008	0.10
119.0079651	0.66
121.9471893	4.84
125.0006561	0.31
125.9996948	0.40
127.9572601	1.82
135.9405823	2.48
139.1885071	0.14
141.9999542	20.44
143.0498505	18.20
146.8952484	85.20
157.1733093	0.24
169.0688324	0.13
178.1751862	0.38
190.0958099	48.62
202.8121338	0.22
203.9679871	0.11
221.1566010	12.49
232.1201630	25.00
235.1374359	0.05
246.2167358	62.89
263.0682983	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.088
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
95.0429153	0.09
96.9033203	0.10
101.1927032	0.12
106.8712158	0.09
107.9972000	1.74
109.1114502	0.04
112.8887634	1.56
119.0641937	0.17
121.9822922	0.42
122.9797058	4.23
129.2243958	0.11
135.9675903	0.21
138.0541077	0.05
139.2738953	0.06
149.4501343	0.17
150.0967407	0.69
151.1843719	0.45
151.9993286	2.45
155.0393677	0.12
156.9853058	0.06
161.0390930	0.19
164.2083435	0.22
165.0411072	0.63
166.0412292	2.79
167.0359039	88.58
169.0074158	0.11
177.2647400	0.07
179.0478210	0.25
179.8987885	0.06
181.0363312	14.82
190.9498291	0.16
193.4236908	0.61
194.0988464	0.92
204.8415222	0.09
206.9638367	0.24
209.0194397	100.00
211.0025635	0.28
217.8942871	0.11
219.1027222	0.16
221.1928711	0.57
223.1257324	0.11
227.2171936	0.07
233.0647583	0.58
235.0415344	0.36
237.2612000	0.05
239.1050110	12.85
247.2419739	0.13
250.9771118	0.21
257.2816162	0.11
262.9316711	0.70
265.0695496	0.07
269.0873413	36.34
283.0856323	0.53
285.1590576	0.05
293.0938110	0.22
301.0988159	0.27
309.2148438	0.19
311.1767883	0.04
313.5597534	0.69
314.1810303	8.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	959.2848
Annotation	Unknow
Peak:m/z	Relative Intensity
271.1566772	0.09
285.2643433	0.01
295.9096680	0.07
299.2032166	2.47
311.1613464	0.03
314.0671082	5.42
314.6751709	0.04
329.1589050	13.13
356.2675781	0.02
365.0985413	0.05
370.9523315	0.09
425.0708618	0.16
449.2078247	0.07
461.1917725	0.02
473.3132935	0.05
479.2091064	0.03
491.1755371	0.27
509.4864502	0.05
533.1695557	0.59
533.7722168	0.02
573.3121948	0.15
575.3459473	0.17
589.3136597	0.03
611.0136108	0.03
617.1926880	0.21
628.7442017	0.02
677.0609741	0.17
739.3213501	0.03
764.3330078	0.16
771.4596558	0.02
779.2271729	0.37
915.4232178	0.02
959.2504272	100.00
960.2421265	20.03
960.9221191	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	575.29
Annotation	Herbimycin
Peak:m/z	Relative Intensity
165.9296265	0.28
183.1094360	0.50
183.9626465	0.08
184.9818573	0.04
187.1132812	0.08
190.1373291	0.07
219.2194824	0.05
223.1474915	0.18
227.3453369	0.08
235.0655212	0.21
251.0087891	0.08
265.9799805	0.10
266.8571777	0.17
273.2055054	0.04
277.2819214	0.05
283.3175049	0.23
289.4738770	0.16
291.2503662	0.16
301.2368164	0.26
307.2482300	0.35
308.2552795	0.09
309.1157837	0.11
314.6957397	0.04
323.5975952	0.29
326.0217896	0.43
328.9967651	0.15
333.0636597	0.17
337.2290039	0.25
341.2664185	0.19
343.4616089	0.18
344.2512817	0.20
349.3184814	0.13
351.2354736	0.37
357.1826172	0.32
359.0123291	0.43
361.3964844	0.14
364.3175659	0.04
368.5079346	0.32
370.2650146	0.16
372.5411377	0.07
377.2066650	0.06
379.1307983	0.48
381.3757324	0.08
383.0330200	0.10
384.7780151	0.13
386.2307739	0.05
392.7888184	0.11
397.1745605	0.95
398.3713989	0.10
400.2066040	0.37
401.1855469	0.22
402.0480347	0.07
405.4409790	0.42
409.2851562	0.13
414.2359619	0.11
420.7285767	0.24
424.4368286	0.37
425.5056763	0.11
426.3271484	0.18
436.1157837	0.12
442.2725220	0.35
443.6976929	0.05
452.4696655	0.15
460.7015991	0.08
465.2249146	0.19
466.4160767	0.66
467.5487671	0.04
468.2295532	0.18
477.4645996	0.36
478.3988647	1.72
483.1829224	0.68
485.3955078	0.14
488.3086548	0.54
493.4366455	0.08
495.4147339	3.55
496.3743896	0.44
501.1942139	0.11
504.4511108	0.14
511.3020630	0.46
513.3673706	6.53
514.2808838	0.46
515.3193970	0.15
521.4568481	0.73
522.3080444	0.12
529.5628052	0.16
530.5907593	0.29
531.4160767	0.18
539.3016968	1.36
540.4769897	3.42
556.1053467	0.06
557.3989258	100.00
558.5030518	2.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	205.0967
Annotation	Ethotoin
Peak:m/z	Relative Intensity
118.0693512	0.02
132.0613708	0.03
159.1221313	0.22
177.0657196	0.01
186.5834198	0.05
187.9566498	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	568.9385
Annotation	Unknow
Peak:m/z	Relative Intensity
178.2239685	0.03
224.9851074	0.39
317.0889282	100.00
355.0504150	0.56
400.9749146	37.80
439.1161499	1.24
476.9354248	0.07
484.2130737	1.03
484.8594360	11.61
522.8544312	3.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1907
Annotation	Codeine-6-glucuronide
Peak:m/z	Relative Intensity
143.9465179	0.10
146.9355469	0.09
148.7048035	0.02
150.2421112	0.07
161.8655243	0.06
175.9590149	0.03
179.0203552	0.06
181.0938568	0.03
208.0472717	0.05
223.1418457	0.03
226.1172180	0.08
227.0340576	0.03
229.4099121	0.03
233.0873718	0.11
234.0338440	0.01
252.0150757	0.03
262.2343445	0.03
275.1152039	0.03
294.2242432	0.15
296.1480713	3.12
304.3816833	0.04
306.1280518	0.19
308.1570435	0.13
310.2135620	0.03
311.2375793	0.59
311.9140625	0.12
314.0145264	1.49
326.7199707	0.02
328.4440918	0.08
329.2491455	0.26
346.6099854	0.15
347.3219604	0.25
358.1712036	0.05
363.4479370	0.04
374.4781189	0.01
383.5738831	0.04
387.4580994	0.05
401.1203308	0.06
415.3100281	0.11
418.4159241	0.46
422.5484619	0.14
431.3983459	0.11
438.9030762	0.02
440.2333374	0.42
441.3680725	0.02
458.1956177	100.00
459.2826843	0.83
481.8374634	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1144
Annotation	Lactulose
Peak:m/z	Relative Intensity
113.2787094	0.03
118.9702911	0.04
143.0942383	0.04
161.1652832	0.01
179.0254211	0.27
221.2325287	0.01
235.3894348	0.01
245.2096252	0.02
280.9009094	0.01
341.1701050	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.2083
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
150.3751831	0.04
154.8853455	0.08
159.2738190	0.07
161.0361328	0.04
165.0207672	0.07
179.1978455	0.08
187.2145081	0.21
197.1200714	0.16
201.0680542	0.11
203.1316223	0.18
205.0184326	0.17
213.1294861	0.10
215.3109436	0.13
219.0013733	0.06
221.6396179	0.06
231.1454468	0.81
233.2929993	0.21
237.2050781	0.02
239.3063354	0.11
241.0390320	0.03
243.2679749	0.36
245.2387848	0.02
249.0861816	0.29
251.2027435	0.03
253.2813110	0.31
255.0867004	0.28
257.0706787	1.67
259.2050171	1.61
261.3151855	0.34
263.4486694	0.08
265.3174744	0.15
267.0431213	0.13
269.2335510	0.12
273.0932617	0.21
275.1131287	0.09
277.1013184	0.21
278.2180786	0.08
281.2375793	1.09
283.2001343	2.09
285.2315979	0.06
287.2477112	0.95
291.0542908	0.42
293.1455994	1.72
295.2259827	0.66
297.2660522	0.67
298.1896362	0.07
299.4382935	0.03
301.2198181	0.38
303.1582947	0.19
306.2563477	0.03
307.5743713	0.07
309.2733765	0.28
311.2738342	2.28
313.1874084	0.56
315.3697510	0.09
317.2738647	0.67
319.3246155	1.21
320.3389587	0.11
321.1943054	1.76
323.2747803	1.28
325.3007812	0.94
327.2513733	1.54
329.2649536	0.60
330.3970032	0.07
333.1458740	0.20
335.2561951	0.32
337.1604614	13.62
339.2313843	5.25
341.2120361	0.20
342.5654297	0.34
343.3291321	2.33
344.3392029	0.13
345.1737061	0.11
349.4245911	0.05
351.1719971	0.95
353.2285156	1.71
355.1563721	3.48
357.3363647	0.53
358.2740479	0.44
359.2994995	0.77
361.2812500	0.15
369.3432312	2.08
371.4690552	1.89
372.2279053	0.08
373.2135925	0.29
379.2317505	1.17
381.2081299	0.09
385.0915527	0.33
387.2728577	1.91
389.2820129	0.03
395.2596741	0.83
397.2897034	2.52
399.3675232	0.30
409.2410889	0.21
410.9235840	0.05
413.1776428	5.64
413.7933350	0.09
415.2394714	100.00
417.4361572	0.08
425.3378601	0.06
427.1386108	0.05
439.3460388	0.11
441.3797607	0.13
443.1943970	0.22
444.4327393	0.10
447.3139343	0.16
457.2851257	30.68
458.5433350	0.25
459.3536377	0.22
462.3267212	0.11
469.3435364	0.67
471.4737244	0.08
475.4712219	0.10
487.2849426	51.00
487.9214783	0.08
490.2369995	2.69
491.2145386	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.2991
Annotation	Unknow
Peak:m/z	Relative Intensity
271.2386475	0.35
277.1538086	0.27
296.5090027	0.07
305.3182373	0.24
313.3024292	0.20
324.2902832	0.32
326.2263184	0.29
338.3689270	0.07
339.1817017	0.12
341.2258301	2.63
356.0951538	0.25
356.8840942	0.08
371.2513428	1.57
386.8420410	0.24
392.9835205	0.23
427.4278564	0.11
443.2861938	0.29
447.2248535	0.36
461.2714844	11.92
503.2387085	3.10
533.2598877	0.74
543.5372925	0.31
545.2823486	1.01
571.1785278	0.15
575.2474976	0.93
585.3114014	0.80
587.4086304	0.84
593.2335815	0.06
605.2372437	0.38
615.3841553	0.22
617.4714966	0.19
623.2749634	31.08
623.9288940	0.11
641.2001343	0.12
647.2174683	1.24
665.3609009	21.70
687.2084351	0.06
705.3969116	11.32
707.3671875	1.05
725.2084351	0.36
735.4562378	0.07
767.2033691	100.00
767.9306641	0.31
768.5736084	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0824
Annotation	(-)-Usnic acid
Peak:m/z	Relative Intensity
135.1430664	0.06
172.9846802	0.14
177.2680511	0.09
179.059845	0.05
193.0325928	0.09
203.2856445	0.04
207.3504333	0.07
235.3904114	0.05
237.1821899	0.16
241.0353088	0.15
243.0518494	0.10
249.1999207	0.03
251.2253418	0.06
252.775177	0.06
255.02005	0.16
269.1351929	0.11
271.3501892	0.14
271.9503174	0.08
281.1488953	0.05
282.1117554	0.12
282.7259521	0.06
285.2251892	0.06
287.196167	0.05
291.3793945	0.10
292.9707642	0.15
296.6594238	0.03
297.4155273	0.07
298.2687073	0.60
299.2247314	0.59
300.1717224	0.53
301.1604004	0.09
304.6998291	0.16
307.1447754	0.04
310.1652527	0.06
311.5834656	0.33
313.156189	3.34
315.0150757	0.48
322.6027832	0.22
324.4950256	1.04
325.2681274	6.49
326.2962036	0.34
328.0682983	100.00
329.0933228	2.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1171.31
Annotation	Unknow
Peak:m/z	Relative Intensity
330.1843262	0.10
564.3596191	0.02
809.4790039	0.08
1108.5234380	0.14
1168.0644530	0.12
1170.1314700	100.00
1171.2252200	58.21
1171.9489750	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	355.1533
Annotation	6'-Hydroxygaruganin V
Peak:m/z	Relative Intensity
109.0799789	0.05
118.3886566	0.01
123.0660324	0.02
124.1090851	0.01
128.6523743	0.02
132.9179077	0.11
135.0221252	0.12
135.9781799	0.04
150.1761932	0.01
159.7695923	0.02
164.6660767	0.05
173.1045380	0.08
175.0058746	0.81
177.2511139	0.04
178.2685547	0.02
185.3376465	0.02
187.0506592	0.02
188.1030579	0.15
193.3528900	0.02
197.2348480	0.02
199.2417755	0.05
201.0068817	0.05
202.9075012	0.03
205.4285126	0.06
207.0549011	0.05
215.0805664	0.47
217.0008545	0.05
218.9985352	26.02
225.2277832	0.17
227.1207581	0.05
229.1589355	0.09
230.4915466	0.06
231.2141418	0.04
233.1420288	0.05
234.3724060	0.08
242.0921631	0.05
243.1607361	0.42
244.2421570	0.40
245.2539673	0.13
247.1070862	0.10
251.2111816	0.08
256.9960327	0.20
261.2144165	0.17
262.0793457	0.21
263.1480103	0.17
267.0920410	0.02
269.0898743	0.16
276.2482910	0.07
277.0219421	0.02
279.0807190	0.02
280.5119934	0.14
281.2514343	0.03
287.1611938	100.00
293.3016968	0.02
295.3318787	0.17
296.1015015	0.04
300.2048645	0.01
301.3790894	0.02
309.4702454	0.02
313.3907471	0.68
314.1803894	0.13
318.4173584	0.02
326.0595093	0.11
327.1448975	0.04
331.6964111	0.19
332.4361572	0.01
336.4154968	0.09
337.2905579	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1127.29
Annotation	Unknow
Peak:m/z	Relative Intensity
479.3031311	0.08
521.1639404	0.08
535.3348999	0.04
537.3414917	0.02
591.0902100	0.09
619.1470947	0.03
623.6658936	0.01
647.0291138	0.02
749.3317871	0.04
767.4218140	0.15
1095.3430180	0.02
1110.3117680	0.06
1127.2524410	100.00
1128.2640380	36.39
1129.0045170	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	808.4691
Annotation	Unknow
Peak:m/z	Relative Intensity
225.0918427	0.07
226.1138916	0.72
227.1422424	0.17
230.2397461	0.05
231.0422363	0.02
236.1544952	0.10
237.0927429	0.10
238.1680756	0.10
239.1521912	0.32
240.3464203	0.11
241.1668243	0.15
242.2364960	0.15
243.1083984	0.90
244.1723938	0.14
252.3940125	0.04
254.1377563	0.45
255.4264832	0.07
256.2230225	0.02
258.0069885	0.86
258.9557495	0.20
264.2847595	0.11
265.2064514	0.66
266.1903992	0.09
267.6592712	0.16
268.2773438	0.06
270.2176514	0.13
272.1904297	0.29
275.2123413	0.35
275.9575195	0.02
278.2738647	0.10
279.0087891	0.15
280.4278259	0.03
282.0726929	0.23
283.2534180	0.18
285.1622314	0.12
290.1991577	0.18
293.1857605	0.05
295.1225891	0.07
296.0484009	0.13
297.1940918	3.36
298.2817383	0.62
299.3234863	0.17
300.2063904	1.28
301.1682129	0.04
304.2054443	0.26
306.3482056	0.20
307.2357178	0.11
310.3277588	0.12
311.3562317	0.33
312.1872559	0.14
313.2919006	0.39
314.5106201	0.12
315.2565002	0.25
317.3575745	0.06
319.1669922	0.06
320.3924255	0.31
323.2580566	0.27
325.1697388	10.75
326.2180481	1.63
327.2289734	0.34
335.0888672	0.06
336.2921753	0.22
337.3053284	0.02
338.3220825	0.02
339.3552551	0.37
341.1769409	0.92
342.3646545	1.02
343.2254028	0.36
344.1349487	0.03
346.1475220	0.20
351.2059326	0.21
352.4872437	0.27
353.3967896	0.39
354.1960449	0.69
355.3598022	0.43
356.3834839	0.49
357.1872559	0.04
362.4180908	0.06
364.1191406	0.21
365.4786377	0.24
366.3710938	0.09
367.3298950	0.09
368.2023926	0.62
369.2986450	0.32
371.2067871	7.33
372.2525024	1.45
373.2490234	0.11
378.3348389	0.37
379.3331909	0.29
380.2114868	0.10
381.3921509	0.56
382.4882812	0.23
383.4322510	0.29
384.4957886	0.07
386.0305786	0.14
392.3800659	0.31
393.4544678	0.34
394.2869263	0.31
395.3183594	0.03
396.3900757	1.01
397.4898071	1.14
398.4486694	0.21
399.2711792	0.76
400.1712036	0.07
406.6405029	0.15
407.9488525	0.09
409.0856323	0.19
410.3139038	4.74
411.3486938	0.55
412.5208740	0.40
413.3823853	0.07
414.2877808	0.73
415.2968750	0.12
419.0834351	0.02
420.3461304	0.96
422.1094360	0.51
423.2532349	0.15
425.2655029	2.73
426.3599243	1.20
427.2745361	0.40
428.3320312	0.45
429.2630615	0.04
433.1296997	0.10
434.5556641	0.11
435.7346191	0.22
436.4622192	0.29
438.3165283	19.28
439.3773804	3.89
440.4547729	0.47
442.1268311	0.52
443.2719116	0.07
448.4705200	0.19
449.3203735	0.11
451.5800781	0.08
452.5341797	0.15
453.8088379	0.20
454.7962036	0.94
455.4912109	2.06
456.3469238	5.08
457.4386597	0.86
461.1854858	0.02
464.4630737	0.63
465.1690063	0.16
466.6395264	0.65
467.4925537	0.29
468.4075317	0.37
470.2532959	5.38
471.2730713	0.52
474.5670776	0.07
478.5565796	0.28
479.2416382	0.16
480.3611450	0.28
481.5116577	1.36
482.4077759	2.11
483.3416138	1.48
484.3671875	6.65
485.3929443	1.74
490.4127808	0.16
491.4638062	0.70
492.4010620	0.23
493.4690552	0.27
494.3710327	0.71
495.2954102	0.42
496.4277344	0.03
497.6365967	0.19
499.3677368	1.35
500.8352661	0.08
505.3170166	0.07
506.5561523	0.76
507.2935181	0.36
509.3521729	9.70
510.4158325	2.34
511.3708496	1.35
512.3997192	0.09
513.6398926	0.22
516.3847046	0.13
520.2062988	0.02
521.2869873	0.33
522.3211670	0.35
523.4228516	0.46
524.4251099	0.29
525.4663696	0.30
526.6844482	1.19
527.3578491	7.46
528.3615112	1.65
532.1745605	0.13
533.4933472	0.41
534.4470215	0.06
535.4512329	0.29
536.3962402	0.10
538.2930908	5.59
539.3229980	2.88
540.2567139	0.36
541.3654175	0.74
542.4606323	0.38
543.4530640	0.14
546.8994141	0.10
548.2714233	0.18
549.2885132	0.23
550.3770142	0.32
551.3819580	1.90
552.6331177	1.56
553.4052124	1.77
554.3773193	1.17
555.4901733	1.48
556.4526978	0.22
560.5825195	0.17
561.6541748	0.18
562.5864868	0.15
563.2991333	0.25
564.4079590	0.19
565.3098755	1.04
566.4547729	0.78
567.4953003	0.33
568.2681885	0.21
569.4147339	0.41
570.7500610	0.04
572.1237183	0.06
574.4122925	0.04
577.4050903	2.07
578.4298096	1.75
579.4635620	1.51
580.4553223	4.24
581.4238281	2.46
582.3192139	2.50
583.3901978	8.73
584.4193726	1.42
587.5921021	0.13
588.6343384	0.27
589.7335815	0.11
590.5028687	0.16
592.4410400	0.20
593.5416870	0.02
594.4175415	2.74
595.4003906	2.61
596.3942871	6.70
597.4260864	1.66
598.4597778	0.31
599.7172241	0.36
602.4159546	0.11
604.5885010	1.65
605.7467041	0.69
606.3907471	2.01
607.4880371	0.89
608.4382935	0.55
609.6697998	0.17
610.4981689	0.09
611.1375122	0.10
612.4627075	3.42
613.3721313	1.14
618.4767456	0.05
620.6653442	0.18
622.4176636	23.41
623.5851440	7.07
624.4727173	17.69
625.3905029	4.39
626.2617798	0.11
631.6162720	0.21
632.3746948	0.27
634.1290894	0.22
635.1268921	0.03
636.6252441	0.12
638.4649048	0.22
640.3780518	23.24
641.5028687	4.99
644.1989136	0.11
648.6106567	0.14
649.5752563	2.77
650.3978882	6.13
651.4683838	2.91
652.5352173	2.14
653.5530396	0.29
659.5274048	0.19
661.6299438	0.82
662.2373657	0.07
663.7551880	0.22
664.5058594	0.74
665.7456665	0.78
666.8724976	2.29
667.5447388	5.20
668.5619507	2.77
673.4450073	0.53
674.2641602	0.09
675.6460571	0.07
677.5313110	14.10
678.5040894	3.86
679.5087280	3.35
680.4591675	0.36
681.3862915	0.21
682.4829712	0.14
683.4179077	0.09
684.2757568	0.13
691.4512329	2.21
692.5709839	1.24
693.5665894	2.70
695.4091187	100.00
696.4886475	28.30
706.0575562	0.17
709.4848022	7.50
710.4725342	2.50
711.5199585	1.30
712.6290894	0.40
718.0693359	0.10
719.5980835	0.52
721.3021851	1.59
722.2631226	0.26
723.4655151	0.28
724.3237915	0.04
727.9613647	0.07
729.4822388	0.10
733.8807983	0.09
735.3665161	0.68
736.6051636	0.31
737.4768677	3.26
738.5608521	0.96
739.5543213	0.71
740.5702515	0.35
745.6799927	0.13
746.6699219	0.64
747.7163696	0.30
751.5108643	0.09
752.5451050	0.06
761.8270874	0.13
763.3648071	16.02
764.5790405	27.32
765.6203003	8.32
772.3933716	0.12
773.6117554	0.11
774.3134766	0.24
780.5188599	49.34
781.6091309	16.41
790.5534058	29.15
791.5556641	13.28
792.5972290	0.45
809.5557251	48.74
810.7879028	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.66
Annotation	Unknow
Peak:m/z	Relative Intensity
177.9115753	0.01
187.0011902	0.12
188.1808014	0.03
189.3449402	0.02
198.0716705	0.07
204.9836426	0.01
210.7715607	0.03
212.9123383	0.03
217.0874634	0.07
234.9606476	0.05
252.9385223	0.06
253.9275818	0.02
271.1411438	0.09
272.0955811	0.02
275.2291260	0.01
279.5296021	0.01
289.0415039	0.01
295.1507874	0.03
298.3810120	0.01
313.2967529	0.01
328.2544556	0.65
329.3832397	0.09
331.1112671	1.30
332.1566162	0.18
343.3016357	0.03
345.1942139	0.04
346.1466064	2.37
347.2198486	0.27
354.1531982	0.05
361.1619263	100.00
362.1569824	15.91
363.2589722	0.48
370.9216919	0.04
379.3728027	0.03
387.3281250	0.13
392.3135376	0.01
401.0676270	0.03
415.3025513	0.02
419.1449585	0.03
424.1915283	0.03
433.2947388	0.07
434.4934082	0.02
440.1808472	0.02
441.1303101	0.07
445.5452881	0.02
447.4385376	0.01
451.2807617	0.59
452.4623413	0.07
465.3985596	0.10
469.2072144	1.24
470.2579956	0.21
481.2307129	0.03
487.2372437	0.06
487.9031982	0.04
493.3598022	0.14
511.0545044	0.02
523.2615967	0.42
524.2471313	0.13
549.6728516	0.02
557.5331421	0.05
563.5670166	0.05
565.9854126	0.01
568.6548462	0.12
569.3928833	0.01
570.5584717	0.03
587.4296875	0.06
593.5914917	0.02
595.4052734	0.05
605.1939087	1.37
606.2666626	0.34
607.2301025	0.53
608.2238159	0.13
613.2371826	0.06
631.0899048	0.62
632.2847290	0.24
645.2561035	0.02
649.1378174	2.39
650.2369385	0.85
655.2922363	0.05
665.8651733	0.06
667.2777100	0.56
668.3967896	0.10
691.3814087	0.03
709.2474976	0.39
714.1804810	0.04
715.4234619	0.01
721.3675537	0.01
739.2927856	0.17
740.3392944	0.05
757.2808228	0.28
758.3002930	0.15
775.2282715	3.09
776.1651611	0.75
776.9590454	0.07
793.2041626	1.95
794.4292603	0.22
795.4381104	0.02
811.2509155	1.03
812.2634888	0.40
813.2229614	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1016.5317
Annotation	delta5-Demissine
Peak:m/z	Relative Intensity
356.1073914	0.02
361.4801331	0.04
641.6286011	0.11
705.8695679	0.06
722.2706909	0.07
887.6782227	0.06
941.8182373	0.11
950.1815186	0.09
998.6093750	0.11
1016.4407960	100.00
1017.1142580	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.23
Annotation	Linalool 3,7-oxide beta-primeveroside
Peak:m/z	Relative Intensity
130.0645905	0.02
135.0421906	0.16
137.3248291	0.01
143.1359253	0.03
145.0108795	0.01
151.0208893	0.06
153.1018677	0.04
155.2416382	0.02
157.1132355	0.01
159.1091766	0.01
163.0815735	0.01
165.1117401	0.04
167.0641937	0.01
170.0359192	0.01
171.1324158	0.04
173.3150024	0.03
181.0799103	0.04
183.0926208	0.03
185.1943665	0.01
188.8395996	0.01
195.3229828	0.03
197.1680908	0.05
199.0993042	0.03
204.2035065	0.01
211.0499725	0.01
217.2248535	0.03
219.1547852	0.05
223.1545105	0.01
226.0439453	0.01
228.2255859	0.03
230.9881287	0.02
231.8864746	0.01
237.2534943	0.01
240.2645111	0.02
242.0976410	0.03
243.1779480	0.05
244.1873474	0.06
247.2166138	0.04
249.0269165	0.20
255.1882935	0.01
257.2160034	0.03
261.1844788	0.02
267.1664124	0.10
271.3959656	0.01
280.1705322	0.06
284.0941467	0.05
285.0146179	0.06
288.9022827	0.02
295.5253296	0.01
297.0072937	0.03
298.3571777	0.02
301.3635864	0.20
302.3547058	0.40
303.2709961	0.89
304.2913513	0.01
307.1403809	0.02
310.0354614	0.01
313.2330627	0.68
314.1938477	1.73
315.2031250	0.41
321.1625977	0.03
322.1391602	0.01
325.1752014	0.38
326.2239075	2.06
327.0627747	0.33
328.9490356	0.01
332.4024658	0.03
333.1808167	0.04
337.3600464	0.09
338.1658936	0.11
339.2964478	0.01
341.2313843	0.03
342.1033630	0.10
343.1472778	4.32
344.2134399	15.71
345.1716003	2.69
347.1015015	0.01
350.1468201	0.03
354.0563965	0.01
356.2962036	0.06
360.3853149	0.03
361.1961060	0.02
364.3999634	0.01
365.1582031	0.06
367.3851318	1.96
368.1872253	8.32
369.2064514	1.89
371.2571716	0.01
373.2165527	0.48
374.3224182	1.18
375.2950134	0.41
379.4356384	0.03
380.2542725	0.31
381.2597961	0.17
382.2481995	0.34
383.2196655	0.18
384.3226013	0.04
386.4146118	0.04
387.2450256	0.07
391.2520752	0.03
392.3507080	0.12
393.2383423	0.02
397.1666870	2.25
398.2115479	22.42
399.2103577	4.77
401.1543884	0.02
403.5040588	0.03
404.1791077	0.04
405.5722961	0.01
410.1616821	5.56
411.2679749	1.92
415.2931213	0.04
416.1528320	0.03
419.5588684	0.03
420.7346497	0.04
421.3815002	0.01
423.9751892	0.01
428.1900940	24.51
429.3238831	6.67
432.5657043	0.06
446.2163086	100.00
447.1744690	23.89
448.0635986	0.03
450.2063293	0.01
466.2184753	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1171.308
Annotation	Kistamicin A
Peak:m/z	Relative Intensity
329.1792297	0.01
331.0996399	0.08
331.9866028	0.01
345.3027649	0.00
346.1860352	0.05
346.9991455	0.01
361.1177673	0.73
362.2120972	0.31
388.4132690	0.05
403.2604370	0.01
412.3912964	0.01
422.4926453	0.02
436.0364380	0.03
442.3874512	0.01
451.2065125	0.01
452.3041992	0.04
469.0701904	0.05
470.2139282	0.05
505.3987427	0.01
528.9003906	0.01
572.1507568	0.00
605.2385864	0.04
606.2211304	0.13
606.8724365	0.00
631.0954590	0.00
632.2207031	0.02
649.2829590	0.06
650.3283691	0.05
674.2526855	0.00
709.2245483	0.01
710.4062500	0.01
721.4220581	0.01
740.2363281	0.01
757.8878174	0.01
775.2462769	0.13
776.3566895	0.24
793.0249023	0.01
794.0454712	0.08
811.4122314	0.09
812.3660889	0.04
1154.5948490	0.01
1172.2227780	100.00
1173.1459960	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1724
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
213.3284760	0.03
214.0847015	0.05
242.0624695	0.02
257.2861328	0.14
270.0796814	0.03
272.7735596	0.06
285.2361145	0.07
286.0437317	0.07
299.1895752	0.06
301.0306091	0.02
304.9740601	1.37
308.0422363	0.17
311.1743164	0.24
312.3816833	0.03
314.2292480	0.08
314.9143677	0.08
316.2981567	0.05
326.1532593	0.26
329.1391296	3.83
330.1752014	1.17
344.1100464	9.48
345.1815186	3.37
354.2030640	0.04
355.2785034	0.05
358.1401978	0.66
359.2226562	40.97
366.2160034	0.20
367.1934204	0.06
368.9885864	0.08
379.4052734	0.17
380.6572266	0.15
381.3804932	0.14
385.9552612	0.09
387.0844727	0.07
398.4208984	0.10
401.2131958	3.97
403.4351807	0.05
410.2142944	0.14
415.1463013	0.06
425.2223511	0.19
456.3873901	0.12
467.3446045	0.03
475.2171631	0.21
485.1762695	0.17
489.1088867	0.11
503.3088379	2.88
506.0468750	0.91
507.3620605	1.01
516.8605347	0.03
521.2180786	100.00
521.8414917	0.27
527.3856201	0.07
534.2169800	0.09
545.3645630	0.03
548.6676636	0.43
549.3552246	4.67
563.3074951	58.80
579.3550415	0.04
588.6746216	0.52
589.3686523	1.10
590.5836792	0.07
591.2261353	0.05
593.6924438	0.08
603.3761597	2.55
605.4467773	0.08
614.6835327	0.04
615.3746948	1.50
616.6007690	0.03
620.4005737	0.05
623.7112427	0.04
633.4105835	0.44
647.2741089	0.25
650.4708862	0.15
664.5405273	0.37
665.1629639	4.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.2
Annotation	Unknow
Peak:m/z	Relative Intensity
145.3732300	0.09
162.8639679	0.04
165.7761841	0.10
166.8850861	0.04
186.9925690	0.15
188.3609009	0.21
194.1282349	0.06
198.1935730	0.02
204.9583130	0.19
212.9832764	0.05
214.2341766	0.07
215.4610901	0.04
218.1661682	0.08
230.9649353	0.07
231.8431396	0.03
232.7493134	0.05
237.2485352	0.05
238.1088104	0.05
250.2823181	0.12
251.2117920	0.18
256.0891418	0.05
259.2686768	0.51
263.1763611	0.03
277.1188965	7.55
277.7349854	0.05
278.4330444	0.05
282.2573547	0.11
284.1660767	4.39
300.1840515	0.17
301.1384888	1.81
302.1311951	0.80
303.2896118	0.03
310.3687439	0.09
313.1735840	0.03
317.2189941	0.24
319.1705322	100.00
320.2769775	0.06
333.0421753	0.06
350.9934692	0.10
352.1456909	0.03
357.2649536	0.14
360.1937866	0.04
361.0924683	0.04
363.2444763	0.12
366.2637329	0.09
391.0824585	0.16
394.2511292	0.02
397.3865662	0.05
399.4029236	0.03
401.2162170	0.03
414.3913269	0.05
415.2120361	0.08
416.7225952	0.06
417.5524597	0.05
421.1044617	0.02
427.2060852	0.05
439.3056030	0.10
444.6507874	0.19
446.2278137	0.02
453.2714539	0.02
460.5534973	0.07
462.2262573	0.21
463.3652954	0.63
464.4702454	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	523.1439
Annotation	Sudachiin A
Peak:m/z	Relative Intensity
191.0076904	0.02
211.2968445	0.01
271.8041992	0.01
328.1352539	0.03
346.2348633	0.15
349.2421875	0.01
361.1595459	100.00
362.1723633	0.01
417.6068115	0.04
436.1984253	0.01
477.0226440	0.04
479.2670898	0.05
486.2077637	0.02
495.6438599	0.03
504.4572754	0.05
505.3469238	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0822
Annotation	Mikanin
Peak:m/z	Relative Intensity
117.1434402	0.02
205.1245728	0.04
206.1167908	0.02
225.5276184	0.01
233.9559326	0.04
249.1396179	0.02
250.0805054	0.00
263.1856079	0.01
269.5606079	0.09
271.2375488	0.02
282.2949219	0.11
297.1984863	0.05
298.1474609	0.01
299.0709839	0.07
310.5309448	0.06
311.1598511	0.06
313.1056824	4.10
313.7556763	0.01
315.1866455	0.03
325.1618958	0.03
328.1039734	100.00
329.2181091	0.20
343.1447144	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1352
Annotation	Unknow
Peak:m/z	Relative Intensity
114.8222351	0.05
115.8928757	0.04
116.8609009	0.03
119.0238953	0.28
121.0806656	0.04
124.9157486	5.39
126.0727081	0.06
126.9206238	0.07
129.2427368	0.03
130.8754578	3.02
132.0600891	0.12
135.0668030	0.03
139.0211334	0.10
140.5820007	0.36
141.2584076	0.03
143.0621948	1.03
148.9764099	4.81
149.8831787	0.16
153.2030334	0.07
154.9132996	0.21
157.1556091	0.03
158.8772888	0.50
160.9415894	7.68
161.9108887	0.59
163.3361359	0.03
164.7947693	0.10
167.1531677	0.09
168.1267090	0.03
171.3324890	0.04
173.0822144	0.43
174.5797577	0.12
178.8917542	0.08
180.9360962	0.04
191.0617065	4.46
192.0467682	0.48
194.0499420	0.03
215.1011047	0.72
215.9598541	0.02
220.9716949	0.27
223.0580139	0.30
224.0371704	0.03
231.2297668	0.02
233.0577698	48.56
234.1038513	5.47
239.2484436	0.02
241.0381470	11.18
242.0570374	1.18
246.9190979	0.02
250.8861694	0.20
269.3914185	0.08
271.2917480	0.03
275.2057495	0.32
276.1279297	0.11
277.3214111	0.10
278.1522522	0.10
289.2120361	0.07
291.1449280	0.23
293.1036377	14.82
294.1763306	1.69
305.3841858	0.09
309.2566528	0.35
317.0295410	0.05
317.9293823	0.02
319.1580811	0.10
329.1915894	0.23
330.3046265	0.06
347.1277466	0.23
363.1888733	0.61
365.1727600	100.00
366.1988831	13.24
391.1574402	0.25
392.2058411	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2083
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
162.9221802	0.16
183.2265930	0.09
187.0635986	0.07
190.9102936	0.39
202.8907471	0.10
209.1903381	0.16
219.2907410	0.04
220.9536743	0.08
226.2056580	0.20
231.5240479	0.16
242.8933716	0.06
245.2760162	0.05
257.2578430	0.61
261.1951294	0.06
271.3142090	0.29
280.4113159	0.03
281.1275024	0.21
289.2581787	0.26
296.9843750	0.07
298.2301025	0.94
299.1622925	5.09
309.3134155	0.80
315.3300171	0.81
321.2646484	0.09
327.3712769	0.05
329.0411377	0.08
333.1436768	14.70
333.7578735	0.08
341.2205200	0.43
343.2537842	0.11
343.9491577	0.04
347.0697632	0.32
349.2850952	0.13
353.2640991	0.93
357.5228882	0.13
367.2520142	0.29
370.7945557	0.39
374.8049316	0.66
381.2606812	0.19
383.2034912	0.12
391.2849731	0.66
393.2100830	1.00
401.2117310	0.11
407.3516235	0.45
409.3593140	0.43
411.2139282	16.19
411.8370972	0.05
421.3847046	0.09
428.4753418	3.90
429.1080933	49.48
429.8501587	0.11
430.9981689	0.18
435.1848755	0.91
439.2274170	0.22
443.0042725	0.16
445.7844238	0.15
453.3065796	58.53
455.2897339	0.28
457.5590210	0.16
459.0159302	0.13
471.3416748	100.00
473.4157104	0.26
475.3176880	0.10
478.9490967	0.09
482.4382935	0.13
486.8848267	0.06
499.4010010	0.18
517.1431885	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	284.0987
Annotation	Unknow
Peak:m/z	Relative Intensity
103.8768692	100.00
163.6132812	0.21
164.2261200	0.27
182.0917358	0.74
185.8979492	0.18
193.9306335	0.28
214.0482788	0.51
240.0977783	0.30
246.9494934	0.26
257.0260925	0.15
265.2977905	0.15
266.1033630	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.12
Annotation	Unknow
Peak:m/z	Relative Intensity
107.9482269	0.04
109.0825653	0.01
111.0288620	0.05
127.0439911	0.16
129.0224609	0.02
152.9728088	0.03
171.0578613	0.13
172.9625854	0.67
191.0184326	100.00
191.8848572	0.05
323.3110352	0.06
337.3834229	0.03
341.4135742	0.01
346.9037781	0.33
349.1646729	0.02
364.9940796	5.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.3097
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
141.1317749	0.64
142.9781647	1.81
143.7963257	0.15
145.0051422	3.86
147.1403961	2.65
149.0631714	3.12
151.1218109	0.91
152.0064697	0.15
152.9221039	1.37
154.0070343	0.28
155.0680542	1.87
157.0041199	2.99
158.1455688	0.12
159.0628662	4.56
161.0366974	4.84
163.0014191	1.47
164.9391479	1.27
166.9920654	0.38
169.0694733	4.57
171.1185150	4.04
173.1338348	8.85
175.2058411	1.77
177.0309448	1.11
178.9202271	1.66
180.1185608	0.12
181.0267029	1.74
182.9719849	6.48
185.1473389	2.68
187.1963806	5.16
189.2734833	0.85
191.1366425	0.93
193.1239777	0.26
195.0977173	1.82
197.1506348	3.46
199.0179443	3.92
201.2558594	2.44
203.1047668	2.71
205.1854858	0.33
207.1670837	1.51
208.1676025	0.07
209.0984497	4.61
211.0640259	3.85
213.2187042	1.74
215.1452179	2.03
217.0444641	0.99
219.1576538	2.64
221.1534271	1.08
223.2256927	1.89
225.2070465	2.55
227.0857849	1.71
228.1554413	0.28
229.1597748	1.44
231.2610474	0.89
233.1125488	1.36
235.0172729	1.92
237.2335510	1.06
239.2049866	2.46
241.3007965	3.35
243.1906738	7.10
245.2137451	0.73
247.1191254	1.04
249.0811157	1.81
250.6775818	0.40
251.3348083	0.58
252.1860657	0.14
253.2235718	2.75
255.2120361	2.83
257.3091431	1.26
259.2523499	4.04
261.2786865	15.75
263.3151550	1.36
265.1257629	2.12
265.9783630	0.10
267.3156128	1.54
269.1940308	1.87
271.3941956	1.60
272.2591858	0.30
273.2126160	3.28
275.2218018	1.64
277.2704468	1.14
279.3375244	2.78
281.2801514	0.74
283.2104797	1.36
285.2773743	4.52
287.1365051	2.63
289.0952759	3.07
290.4461060	0.68
291.3280334	2.43
293.1232605	1.82
295.1066589	1.70
296.3997803	0.06
297.2890625	1.45
299.3586426	1.88
301.3286743	3.20
303.3304443	9.72
305.3547363	2.17
307.2217712	3.06
309.3207397	3.40
311.3569946	1.25
312.1415405	0.08
313.2146606	1.75
315.2964478	4.42
317.3395691	6.85
319.3345337	2.45
321.4328003	0.92
323.1425171	1.67
325.3696594	1.29
327.2337036	8.78
329.3150940	0.53
330.1214600	0.15
331.2714844	1.71
333.2741394	3.77
335.2877197	100.00
337.3930664	0.37
339.4116211	1.40
341.4275513	3.37
343.3275757	1.48
345.3993530	3.02
347.2839355	0.63
349.4237061	1.90
351.3565674	11.69
353.1995544	1.69
355.2856445	0.62
357.4396362	2.44
359.4195251	1.07
360.0844727	0.75
361.4814453	1.29
363.3744812	2.65
365.2611694	0.93
367.4138794	0.66
369.3270569	13.83
371.4186401	0.83
373.2658081	1.08
375.4193115	1.46
376.3638611	0.20
377.3965759	3.96
379.4453735	1.28
380.9499512	0.25
383.3467712	0.28
385.2704163	0.15
387.3557129	5.59
389.4037781	2.22
393.2832642	1.74
395.0867920	0.74
397.3549805	0.80
399.1911011	0.11
401.3055115	3.13
403.4616699	0.56
405.3877258	3.88
407.3519897	1.28
409.0115356	0.36
413.3421936	0.88
415.3540649	0.83
417.5113220	0.42
419.3341980	2.24
421.1110535	0.24
423.1447754	0.39
425.3525696	3.22
430.6818542	0.16
431.4230652	0.62
433.0760193	0.48
435.2272034	0.22
443.4570312	22.48
449.1012878	0.39
461.4016418	17.33
465.1063538	0.22
479.3191528	27.12
479.9267883	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0832
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9369812	0.04
130.9129486	0.30
142.9745483	2.19
147.0556183	0.21
148.9776459	1.04
155.0331421	0.09
161.0604858	5.44
173.0749664	2.94
175.0404053	0.58
179.1462402	0.22
187.2415466	0.09
190.9925537	1.24
203.0337219	0.64
204.9805756	0.06
211.0654297	0.11
214.8815308	0.03
220.9379730	11.56
229.1923370	0.36
233.1129761	0.16
247.1479797	0.94
257.3740234	0.05
263.4187012	0.11
264.8538818	26.60
265.5081177	0.10
275.0510559	0.07
334.9413452	0.10
341.2390137	1.02
369.0959167	0.02
377.0490112	0.13
394.7305908	1.00
395.3471069	0.26
420.6858215	0.63
438.3213806	12.20
438.9436951	100.00
439.6853943	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1173.3229
Annotation	Isonigerone
Peak:m/z	Relative Intensity
328.1800842	0.12
328.9794617	0.02
331.1701355	0.13
332.2451172	0.12
346.5054626	0.03
347.8760681	0.05
353.2801514	0.04
361.1619873	2.54
362.1860962	0.94
363.1156311	0.07
364.1443787	0.04
390.2601013	0.05
415.2962646	0.04
451.2329102	0.02
452.5200806	0.02
469.3233337	0.04
547.2695312	0.02
596.3898926	0.02
614.3281250	0.01
632.0941162	0.06
649.2417603	0.13
667.2431641	0.05
668.2385864	0.06
740.1457520	0.02
758.3549805	0.02
776.0541992	0.28
777.0512085	0.06
793.3640137	0.07
794.4963989	0.03
810.9651489	0.03
812.0101318	0.20
814.0414429	0.04
962.5489502	0.01
1156.1641850	0.03
1171.7581790	0.07
1174.1306150	100.00
1175.0883790	0.57
1175.9288330	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	762.36
Annotation	Citrusin III
Peak:m/z	Relative Intensity
329.2272949	0.03
600.5582886	0.07
696.5873413	14.28
708.7418823	0.59
717.7345581	0.04
726.3980103	40.25
727.0537109	0.36
732.3285522	0.06
740.1766357	0.05
743.3380127	0.03
762.3176880	100.00
763.0071411	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0564
Annotation	Diosmetin
Peak:m/z	Relative Intensity
123.139679	0.04
136.8810883	0.01
144.8988647	0.04
149.1114502	0.08
149.8701477	0.06
150.8858948	0.02
161.0510559	0.02
161.8940735	0.03
170.9886169	0.43
172.3707733	0.01
177.0930481	0.02
179.0442505	1.04
183.0871124	0.16
185.0984802	0.04
199.0531311	1.42
200.2038269	0.02
204.0856628	0.07
209.0960083	0.04
210.0854797	0.01
211.1003113	0.28
212.8660583	0.06
214.9399719	0.08
225.1052551	0.13
226.4053345	0.19
227.2069702	0.56
237.3376465	0.15
239.3935242	0.01
241.1519775	0.02
243.055542	1.92
244.1297302	0.24
253.27948	0.03
255.0093994	4.45
256.1262817	0.08
257.0561829	0.02
271.0788269	19.44
272.164093	0.88
281.1073608	0.29
282.3071289	0.08
284.0421143	100.00
285.1323242	0.27
299.1258545	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.274
Annotation	Unknow
Peak:m/z	Relative Intensity
159.3751831	0.88
160.1177979	0.29
165.1967621	0.25
170.0766144	1.23
170.9405518	0.09
188.0227661	59.19
189.0295868	2.47
190.0146179	0.45
205.0179138	100.00
206.0670929	4.00
207.0555420	1.00
244.9788666	0.08
257.0633545	0.11
278.8839111	0.38
285.9098511	0.24
288.4182129	0.28
307.2372437	0.16
332.8694458	0.48
350.9754028	0.74
357.2902832	0.32
371.8264160	0.25
384.4200439	0.18
396.3875122	0.11
398.3409424	0.21
399.2329102	0.36
411.2180786	0.30
414.9659424	0.17
438.4381714	0.37
482.8109741	0.71
527.5598145	0.30
536.0617676	1.77
537.2448120	2.14
538.2092896	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1564
Annotation	Butrin
Peak:m/z	Relative Intensity
176.1664734	0.06
179.9499207	0.05
186.9415283	0.05
223.0271606	0.07
250.2602234	0.07
264.6911011	0.12
266.7319641	0.08
267.5337830	0.09
269.1278992	0.87
270.2795715	0.07
278.9144897	0.10
280.9262085	0.32
282.1546936	0.42
283.3547974	0.17
284.0969849	0.16
293.1319580	62.13
294.0607300	14.67
295.2780151	0.07
296.0964966	0.11
297.1388550	0.16
305.0762939	0.12
306.6806641	0.09
307.9307861	0.21
309.2815552	0.04
310.6111450	0.59
311.2227173	2.98
312.2052612	0.75
313.0104980	0.04
315.2506104	0.13
321.2320557	0.33
323.1173096	7.67
324.2051392	1.08
325.1505737	0.17
335.1521606	3.04
336.3143921	0.81
337.1567383	0.72
338.2660522	0.03
339.2675171	0.06
341.1536865	7.09
342.2634888	2.30
349.2251587	0.04
351.1893921	0.11
353.1962891	3.09
354.2868042	0.77
355.2770996	1.20
356.3137207	0.50
365.1467285	0.16
367.1616821	0.15
369.1229858	0.23
371.1793213	0.32
372.3381958	0.10
377.2727051	1.24
378.1734619	0.31
382.2410889	0.08
383.3280640	0.22
384.2314453	0.14
395.2703247	0.82
396.0750122	0.09
400.6953735	0.04
413.2192993	100.00
414.2714233	21.15
431.1643066	0.93
432.1339111	1.08
445.2083740	0.03
457.2224731	6.73
458.1548462	2.15
473.3291626	0.13
486.9790649	0.19
488.2229614	0.18
545.1124268	0.03
559.4640503	0.03
560.4165039	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1226
Annotation	Unknow
Peak:m/z	Relative Intensity
95.0108185	0.12
104.8206329	0.14
111.9918442	0.11
126.9636383	0.10
133.0143890	0.17
140.1486969	0.23
142.9093933	0.05
145.6266174	0.42
146.8988647	0.52
149.9498901	0.10
193.1524658	0.39
196.8490906	0.18
207.2565918	0.33
208.1417847	0.05
211.2020569	0.36
212.1285095	0.23
213.1690979	0.75
214.0906067	0.17
215.1355286	1.06
218.0187378	0.07
219.9309692	0.69
228.2056580	0.07
229.0144958	0.38
230.7676086	0.25
232.9764404	0.64
239.1802063	0.09
249.0267029	0.28
252.3015137	0.34
253.3850403	0.25
254.0122986	0.22
255.2478027	0.09
262.0796509	0.44
264.5691833	0.17
266.1897278	0.20
267.3419800	0.54
268.3155823	7.54
269.1838989	17.20
270.0744324	3.90
272.6978149	0.16
280.1230469	0.88
280.8610535	0.32
282.3060608	1.83
284.3312988	0.34
285.1343384	0.14
290.0782166	64.06
290.8370361	1.29
291.4497681	0.15
296.9547424	0.23
298.1494751	0.18
299.1918945	0.32
305.5977173	0.09
308.0937195	100.00
309.0690308	0.31
317.0879211	0.74
325.9898682	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	940.4791
Annotation	Hoiamide B
Peak:m/z	Relative Intensity
307.3729248	0.09
323.4771118	0.26
326.8847961	0.05
336.3955688	0.06
363.196106	0.12
375.3637085	0.12
468.2537842	0.17
482.4355469	0.04
489.2270508	0.17
493.5514526	0.07
502.5559082	0.13
531.8227539	0.12
559.5805054	0.12
577.885498	0.09
594.569397	0.05
608.2786865	0.10
618.5907593	0.24
638.8787231	0.17
645.5663452	0.10
653.9088745	0.13
655.0521851	0.04
657.4862671	0.17
671.5861816	0.22
682.4527588	0.06
687.3312988	0.24
689.6311646	2.04
703.5625	0.17
713.5670166	0.11
736.6771851	0.17
740.5292969	0.15
743.6168213	0.40
747.5489502	0.06
760.522644	1.32
777.536438	0.47
778.552063	6.60
787.2620239	0.16
788.390686	0.05
797.9793091	0.16
802.5565186	0.10
820.3257446	0.12
886.1954346	0.16
886.9747925	0.07
893.5584717	0.07
904.4706421	0.63
915.2061157	0.32
940.4473267	100.00
941.1347656	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	704.396
Annotation	Isaridin A
Peak:m/z	Relative Intensity
203.2645874	0.02
205.2227325	0.04
215.1324310	0.02
225.1302795	0.01
226.3341675	0.01
231.0409851	0.05
231.9141541	0.04
233.2073059	0.02
236.0619507	0.03
238.0933075	0.06
243.0539551	0.01
245.2597656	0.03
247.2553101	0.01
248.9666748	0.04
250.0475311	0.04
253.0071716	0.02
256.2329712	0.06
256.9729919	0.06
261.2067566	0.01
266.4782715	0.02
268.3301697	0.07
271.2037048	0.12
272.2566528	0.07
273.1246948	0.03
274.0470581	0.01
284.2817688	0.05
285.4740601	0.03
286.3103027	0.05
287.0317993	0.02
288.2657166	0.15
289.0844116	0.02
297.0902100	0.04
298.1018066	0.03
303.4761353	0.07
306.1924133	0.13
314.1660767	0.07
315.1388550	0.03
316.2496948	0.01
318.2185974	0.09
318.8733521	0.01
326.8042603	0.14
328.2193604	0.08
331.0890503	0.12
332.2150879	0.10
333.3916626	0.02
335.6832886	0.03
342.1370239	0.12
343.2154541	0.02
344.3599243	0.02
345.3500366	0.01
346.1882324	0.10
349.5305786	0.02
351.3156128	0.05
355.2507935	0.07
356.5896606	0.04
357.9940796	0.02
358.6156616	0.01
361.2660522	1.72
362.2354126	0.09
363.3853149	0.03
367.4544067	0.04
368.2251587	0.01
369.2890625	0.03
371.9416504	0.23
373.0030518	0.10
373.7875977	0.03
374.5622559	0.21
375.4701538	0.03
376.2992554	0.01
377.0435181	0.04
379.9707642	0.02
380.7300415	0.02
381.4434204	0.01
383.9124146	0.16
385.0708008	0.05
386.3707275	0.09
387.3156128	0.05
389.1968384	0.18
390.2631226	0.04
391.1904907	0.11
393.1094971	0.00
397.3259277	0.04
399.5531006	0.05
401.0681152	0.88
402.2650146	0.29
403.3264771	0.22
404.5438843	0.03
407.3454590	0.01
409.3030396	0.01
412.7761841	0.06
416.2250366	0.01
419.2200317	0.54
420.3379517	0.01
421.3842163	0.10
422.4325562	0.03
428.3736572	0.06
431.1534424	0.44
432.0518188	0.04
434.1934204	0.01
436.6927490	0.02
438.1231689	0.33
438.8239136	0.09
441.3797607	0.07
442.4313354	0.02
445.4421997	0.06
448.1763306	0.06
449.3572388	0.05
450.2335205	0.03
451.2955933	0.02
453.2413940	0.05
455.4942627	0.03
456.8192139	0.24
457.5280762	0.02
458.4323120	0.04
460.3502197	0.07
461.8494263	0.04
465.2028198	0.03
467.1744995	0.04
468.4978638	0.05
469.2053833	0.09
470.2209473	0.02
471.4181519	0.02
472.5068359	0.03
474.3399048	0.07
475.2335815	0.13
476.5802612	0.06
478.5781250	0.02
479.7041626	0.03
480.4501343	0.04
482.4815674	0.07
484.3472290	0.30
485.3666382	0.12
486.4588013	0.19
487.3067017	0.05
488.6912842	0.07
489.3773804	0.07
490.3608398	0.11
492.4339600	0.03
494.4802856	0.03
497.2408447	0.36
497.9586182	0.05
498.6856689	0.01
499.4645386	0.04
500.5981445	0.06
502.2840576	2.21
503.4360962	0.40
504.3691406	0.14
505.6718750	0.13
514.1967773	2.71
515.2722778	0.71
516.2485962	0.11
518.3132324	0.01
520.4283447	0.24
521.3297119	0.12
521.9912109	0.05
522.7277222	0.01
528.3180542	0.25
529.4193726	0.06
530.3905640	0.04
531.7099609	0.07
532.3521118	1.91
533.4166870	0.40
534.3574219	0.17
538.3990479	0.17
539.3591919	0.18
540.4383545	0.14
541.3196411	0.14
543.5242310	0.06
545.2548218	0.02
546.3979492	0.45
547.4586182	0.07
551.5415649	0.04
552.1956177	0.06
554.1609497	0.03
555.3008423	0.67
556.3711548	0.41
557.4431763	0.54
558.3975830	0.10
559.7636719	0.19
563.0042114	0.02
564.4022827	0.07
566.1271362	0.03
568.1311646	0.23
569.4395142	0.07
570.3167114	0.15
571.3952026	0.06
573.3877563	2.07
574.3537598	0.49
575.3310547	0.11
576.4369507	0.05
580.0761719	0.27
580.8154907	0.12
582.4785156	0.02
584.6502075	0.30
585.4117432	1.30
586.4611816	0.46
588.2860107	0.13
589.4695435	0.10
591.3212280	3.64
592.4458618	0.72
597.2061768	0.72
598.2765503	1.10
599.2178955	0.14
599.9308472	0.01
602.0557251	0.16
603.3816528	0.98
604.4551392	0.19
605.5135498	0.11
612.1915894	0.01
613.1384888	0.02
614.3164673	0.08
615.3100586	1.88
616.4211426	0.56
617.3699341	0.02
619.2230835	0.03
623.3578491	0.12
624.5167847	0.69
625.5290527	0.17
627.7397461	0.01
630.6464844	0.06
631.5352783	0.14
632.9104004	0.25
633.5435791	0.38
634.5670166	0.15
640.2547607	0.09
641.3333130	1.13
642.4144897	3.61
643.5106201	0.77
644.4741211	0.01
647.3203735	0.04
647.9869385	0.01
650.5432739	0.89
651.3710327	1.57
652.3979492	0.53
654.6447754	0.08
655.8582764	0.01
658.5617676	1.78
659.4191284	2.87
660.3095093	1.68
661.3720703	0.21
668.4011841	43.80
669.4069214	13.43
670.3983765	0.69
676.4199829	6.71
677.4172363	1.03
686.3934326	100.00
687.4240723	24.64
688.1101685	0.17
705.5770874	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.175
Annotation	Diosmetin 7-Apiosyl-(1->2)-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
213.1656494	0.04
214.1016846	0.10
242.1550140	0.02
270.0105591	0.11
270.9375305	0.01
285.0486145	0.01
289.1678467	0.02
294.1701355	0.02
298.1141968	1.99
299.1271973	0.02
300.4229126	0.11
301.0987549	3.03
313.3080444	0.05
316.1772461	4.19
331.1205444	100.00
331.7662354	0.13
475.3829346	0.02
479.9572144	0.00
492.9738159	0.05
600.9303589	0.02
619.1927490	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	799.23
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
248.4133911	0.21
285.8842773	0.13
301.3092651	0.28
310.3235779	0.13
314.9136963	0.18
328.1768188	0.80
330.1237488	0.87
331.2030029	1.67
338.9096680	0.12
340.3010559	0.09
343.2779541	1.87
355.2444458	0.90
357.1782837	0.29
369.0003052	0.98
373.2345886	19.90
375.6278381	0.11
383.0222778	0.45
397.2384644	8.64
406.7975464	0.22
409.1149292	0.14
410.7231445	0.73
421.3825073	0.99
427.1157837	4.18
427.7545166	0.03
439.2839355	5.07
457.2785645	4.73
471.1574097	0.20
475.2744141	14.30
482.3828735	0.29
493.2464600	4.59
499.3447876	0.06
505.4439087	0.39
515.7609253	0.27
531.9193115	0.79
547.2323608	0.15
586.3859863	0.39
601.1139526	0.07
606.2829590	0.06
607.5376587	0.18
617.4900513	0.17
621.4218140	0.27
622.2041626	0.20
628.3482056	0.24
635.2754517	0.48
636.3554077	0.19
637.2545776	0.07
649.2593384	3.57
650.4003296	0.29
661.4190063	0.72
669.4640503	0.15
670.1621094	0.32
671.1367798	0.22
679.2741089	27.89
683.6882935	0.12
703.3314819	10.07
709.3470459	0.09
713.5680542	0.11
715.3521118	1.31
719.3370361	0.38
727.1360474	0.23
733.3375244	39.72
745.2673340	20.73
746.0042114	0.03
755.7426147	0.38
762.6604614	1.35
763.3265991	15.13
767.3955688	0.20
781.2082520	100.00
781.9380493	0.40
799.2913208	31.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	381.0829
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
110.7323837	0.67
116.7918015	0.14
134.0032349	5.09
136.9087219	0.10
143.0641022	1.95
145.2495270	0.10
149.0805969	2.49
154.9411163	0.36
168.9172058	32.85
169.5577240	0.04
172.8745728	0.40
178.0193176	3.61
186.9256134	1.54
193.0839233	100.00
205.0769958	2.13
265.3572998	0.04
284.0346375	0.35
297.0195923	0.26
317.2916565	0.03
334.4468689	0.24
337.4067383	0.38
366.2846069	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.23
Annotation	Unknow
Peak:m/z	Relative Intensity
104.8404999	0.01
106.9805756	0.08
109.0478592	0.02
116.9822464	0.02
119.9900360	0.06
125.1491394	0.03
131.9694366	0.09
135.0159149	0.28
141.6123962	0.03
142.9925842	0.02
144.9189148	0.06
152.9848938	0.74
159.9354095	0.93
162.9349213	0.21
164.2277832	0.02
166.1888733	0.04
167.0810547	0.06
169.3933105	0.03
170.7823181	0.33
172.8975525	0.02
178.0633392	0.21
180.1116180	0.06
187.9921417	2.79
188.7957916	0.01
199.8173065	0.01
205.9588470	100.00
207.0449829	0.04
220.7134094	0.02
222.7515259	0.02
224.2098389	0.01
231.0621948	0.01
232.0266113	0.01
235.2524414	0.02
236.8914795	0.02
245.9930725	0.03
248.9914551	0.29
252.0354309	0.08
257.5159912	0.10
263.2837524	0.03
274.1848450	0.06
278.1528625	0.03
279.1126099	0.03
281.1234131	0.24
283.1269531	0.01
286.6462402	0.01
289.2633667	0.05
292.1193237	0.02
297.0722656	0.13
301.9097595	0.01
304.6528931	0.10
305.2638550	0.08
313.8267517	0.05
314.8524780	0.61
315.6198730	0.03
319.0594482	0.07
321.9658203	0.01
323.6920471	0.01
324.5627441	0.01
327.3945312	0.04
330.5391235	0.01
332.4640503	0.50
333.1245422	0.07
338.8161316	0.02
344.3150330	0.01
345.2210083	0.05
347.8336182	0.04
350.1977844	0.52
350.8406677	0.93
352.6160583	0.02
359.3461304	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	436.2473
Annotation	PE(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
128.0872345	0.06
140.0127563	0.28
152.9670410	0.42
165.3285217	0.04
195.4772797	0.02
196.0926514	2.41
201.8518219	0.02
214.0117798	2.37
215.1488037	0.01
221.2729797	0.14
235.1511536	0.12
239.2219543	100.00
240.0072021	0.02
249.0476685	0.08
260.1332397	0.02
265.0562134	0.06
267.0314941	0.08
268.4273987	0.04
325.6407776	0.08
327.1888428	0.08
331.1448975	0.08
332.2703247	0.05
339.5625916	0.15
340.5385132	0.07
348.4491272	0.03
353.4603882	0.16
354.6608887	0.05
375.3146667	0.09
390.1943665	0.09
391.3785095	0.14
393.4889221	0.06
399.7942200	0.10
417.6300964	0.03
437.7969666	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	RHOIFOLIN
Peak:m/z	Relative Intensity
177.2451477	0.02
184.8265991	0.02
189.0072479	0.01
199.0604553	0.01
203.0112152	0.06
216.9866333	0.01
225.1585083	0.20
229.1615295	0.09
232.7924042	0.01
243.2378235	0.02
252.0224304	0.04
261.2888794	0.01
271.0610962	100.00
271.9441528	0.01
277.2849121	0.02
283.1795044	0.03
295.4575195	0.08
297.1536255	0.01
313.177948	0.38
314.3538818	0.02
331.0795288	0.09
337.1463013	0.12
339.3181152	0.01
341.3017578	0.02
355.1639404	0.02
367.1254883	0.22
369.1692505	0.03
377.5540161	0.01
379.3895874	0.04
381.2228394	0.20
385.2822876	0.02
393.3572388	0.01
394.1173096	0.02
397.2231445	0.19
399.1342773	0.14
403.5797119	0.01
415.2661133	0.69
417.1576538	0.13
421.3012695	0.01
433.1730957	11.35
439.2319336	0.03
461.1511841	0.01
463.1035767	0.01
481.3140259	0.01
487.1964722	0.06
492.2935181	0.01
497.5685425	0.01
499.3761597	0.03
517.0963745	0.01
518.7891235	0.01
520.3640747	0.03
521.4594116	0.02
525.0491333	0.04
537.3276367	0.02
542.2526245	0.04
542.9689331	0.01
547.2596436	0.02
551.135376	0.01
552.449646	0.01
559.9440918	0.01
561.3242188	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.2238
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
163.1374969	1.56
166.1043243	0.89
177.2378387	1.06
183.1062012	0.67
189.2656708	1.08
191.0343933	2.20
203.2149811	5.05
211.1782684	1.29
213.1904297	0.99
217.2193909	0.63
219.3687744	3.28
221.0496521	2.78
223.3413544	1.37
226.9736328	0.36
231.2516022	1.27
233.1373901	2.58
237.0530396	0.53
245.2857819	4.94
249.1497498	7.59
253.1543274	1.63
259.2746277	1.79
261.2263489	15.88
263.3968506	0.23
269.1737061	3.23
271.2605286	0.74
273.3827515	0.28
274.1493530	0.46
275.2193604	0.89
277.3004761	1.25
285.3796997	0.36
287.2562866	2.83
289.2875977	23.10
293.4199829	0.54
295.1501160	1.56
299.6160889	0.36
303.4324341	2.27
307.2374878	20.40
313.5679321	1.63
317.3545532	2.07
319.2286377	1.03
320.7698364	1.02
323.3176270	0.88
329.5275269	0.87
331.1687012	12.45
333.3370972	0.58
335.4905396	1.99
337.3130493	0.57
339.2980957	0.36
345.2561035	2.57
347.2739258	25.04
349.3191528	100.00
359.2989502	5.55
365.2471924	28.96
373.3486328	0.38
377.2778320	10.87
383.5396118	0.96
389.2011108	3.57
391.2901611	0.46
401.2118530	1.62
403.2769165	8.76
407.2536621	17.81
419.1892090	0.53
427.3640137	7.77
435.2861328	8.12
445.4858398	6.93
461.3831177	0.88
471.4030762	29.23
485.5100708	2.28
487.8919678	1.35
489.2853394	2.70
532.3479004	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
70.9963226	0.05
84.9604034	0.72
86.9587097	1.38
92.9131165	0.11
100.9862366	0.11
110.8623199	100.00
127.2416382	0.06
128.9288635	2.69
130.8638458	0.98
147.0025940	0.04
152.9017792	0.05
154.8105927	0.25
163.2727966	0.03
171.1316071	0.09
172.8822632	19.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	246.9919
Annotation	Vanillic acid 4-sulfate
Peak:m/z	Relative Intensity
79.8970413	2.83
96.9211578	7.60
107.8861389	0.16
110.9243622	0.05
119.0178223	0.24
123.0093842	0.90
124.9005890	0.02
135.9427948	0.03
138.7874756	0.05
144.9348145	0.02
146.8806763	0.03
151.9046173	0.18
163.0159454	0.03
166.9675140	100.00
173.3038330	0.04
184.8966522	0.08
188.1249542	0.03
198.6950836	0.03
202.9589081	44.30
229.1991730	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	375.2027
Annotation	2,3-di-0-hexanoyl-alpha-glucopyranose
Peak:m/z	Relative Intensity
110.8935165	0.09
113.0295563	1.37
123.0872726	0.08
125.0060425	0.20
134.2090149	0.24
141.0012665	0.09
142.9265747	1.41
148.7962952	0.04
161.1407166	0.54
164.0390320	0.18
171.2540894	0.44
172.9446869	0.08
188.0931854	0.07
191.1347961	0.17
195.1108246	0.30
203.3649292	0.44
208.3653717	0.09
213.1671448	0.60
215.9619904	0.22
227.2194824	0.10
229.1009521	0.23
237.0433350	0.16
244.6848145	0.12
246.2155457	0.08
247.9973755	0.12
252.1091614	0.25
261.3242798	0.05
267.2749634	0.97
268.3365784	0.13
269.3290100	0.33
271.1980591	0.13
274.3349915	0.06
279.2133179	0.09
283.9067383	0.21
287.1686401	0.43
297.3403320	0.09
299.3334961	0.29
313.2975464	0.26
315.2841492	100.00
317.5673828	0.22
327.2373657	0.23
329.2015381	4.60
330.2237549	0.59
331.3020325	1.31
332.1851501	0.14
333.2732544	5.68
339.3117371	0.59
342.1282654	5.03
343.1698303	1.98
344.2153931	3.72
345.2080383	1.88
347.0945129	0.57
356.6060486	0.31
357.2426147	2.17
359.0764465	81.35
360.1311951	22.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	347.11
Annotation	5,6-Dihydroxy-7,8,4'-trimethoxyflavanone
Peak:m/z	Relative Intensity
116.9940796	0.51
124.9368591	0.38
135.9624481	0.51
137.0408020	0.10
140.8900909	0.11
143.1081848	0.16
144.8618622	2.56
149.0761414	0.21
150.9177399	0.48
152.9911804	0.07
154.8630981	0.16
163.8627319	0.85
164.8170776	0.33
167.0365601	0.16
177.0395508	16.49
178.0741577	0.04
179.1387634	0.07
181.8977661	1.61
184.9146423	0.08
190.8157043	0.04
194.8633728	0.12
197.0390167	100.00
197.8088989	0.50
198.8276367	0.04
201.0768433	0.09
211.2725677	0.09
220.0859375	0.14
221.1847839	0.11
223.0025024	1.77
227.0597229	0.34
229.1831970	0.06
231.8534851	0.07
233.1939087	0.10
252.9363403	0.10
255.7666931	0.10
263.3002625	0.07
269.0545654	0.06
271.1291199	0.05
276.1882019	0.29
284.2398376	1.72
285.1892395	1.38
287.1359863	0.51
288.4746704	0.07
289.4118347	0.23
290.0580444	0.04
297.2286072	0.35
298.2395630	1.13
299.0636597	0.59
301.2189941	0.14
303.3617554	0.24
305.0885010	2.61
313.2656250	0.13
315.3426514	1.44
316.0137024	0.06
317.3501892	0.17
319.4097595	0.03
328.6030579	0.72
329.3231201	1.17
330.2188110	0.20
331.1981812	0.16
332.1618042	3.24
332.9824219	0.12
339.1081543	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.75
Annotation	Unknow
Peak:m/z	Relative Intensity
221.0265350	0.09
227.1799316	0.10
245.1239166	0.82
247.1017761	0.08
253.1432343	0.12
263.1544800	0.10
265.1818848	0.91
276.9931641	0.33
283.2715759	3.52
287.0701904	0.30
295.0733337	0.05
305.0713806	1.03
317.2577820	0.04
319.2483215	0.22
321.1810303	0.74
337.2437744	0.05
339.4096069	0.24
361.2886353	0.07
377.0283813	0.12
379.1633911	3.01
379.8431396	0.02
382.0137939	0.06
390.6573486	0.10
397.0167236	0.74
401.3904419	0.18
409.2719116	0.14
415.3833618	0.56
439.6484985	0.07
447.0838623	0.06
449.2556763	0.63
463.3574829	0.26
467.1082764	0.08
473.2277832	0.12
480.9863281	0.11
491.2908325	0.17
493.4545898	0.11
495.3932495	0.06
511.3453979	0.66
523.2233887	0.31
525.3219604	0.16
529.0578613	0.48
537.2380371	0.20
539.3812866	0.10
541.0507812	0.21
543.4169922	0.20
553.4489136	0.21
561.7477417	0.36
569.1130981	0.04
571.0099487	0.05
579.6126099	0.20
587.3511353	0.63
605.5855103	0.05
625.2565308	0.24
627.3059692	0.08
641.1793823	0.06
643.2531128	1.63
647.5175171	0.51
659.3540649	0.16
661.3457642	2.66
669.4296265	0.42
675.5202026	0.09
687.2410278	1.43
693.2857056	1.00
701.2351685	1.17
703.4456787	0.11
705.3550415	0.89
717.2533569	0.08
719.3696289	56.93
720.0280151	0.66
737.3267822	28.74
738.5408325	0.04
747.4035034	3.55
748.5351562	0.06
761.4741821	0.98
779.3927612	43.17
780.3731079	100.00
781.0068970	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	411.1279
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9535522	0.19
116.0684738	0.13
119.0762329	0.14
120.7924042	0.12
126.8368530	0.82
128.2653503	0.30
130.8388672	0.50
136.9096527	0.52
143.0436707	0.10
144.0091248	0.56
145.1154175	0.67
146.9550629	1.69
157.2475586	0.37
159.0846558	0.28
160.1224976	0.09
161.8943787	3.50
163.0050507	2.50
171.1664429	0.08
172.9604950	2.91
173.9155884	0.07
174.9838409	7.80
177.0188599	1.67
177.9755249	0.12
178.9799500	0.13
184.7227173	0.24
187.0335388	5.45
188.2454834	0.08
189.0739288	1.08
191.1633911	0.05
193.1338043	0.13
197.1228333	0.39
198.9981079	1.00
200.2822876	0.07
201.0427094	0.41
203.1086426	1.34
205.0472565	10.08
211.2428894	0.44
212.8283844	0.23
213.9937897	0.21
214.9219666	0.72
217.0125580	7.11
219.1101227	0.18
221.2208252	0.35
222.9199219	0.57
225.0375671	0.14
227.2462311	0.08
229.1301575	5.54
231.0364380	1.14
232.7955322	0.17
235.0902405	0.78
239.0523682	0.05
241.0405273	1.21
243.1354675	2.83
245.0089417	0.27
247.1952515	2.34
248.1734619	0.47
249.0358887	0.35
251.3580322	0.26
253.0485840	5.91
254.2853394	0.45
259.2411804	1.61
261.0963135	1.05
265.9265137	0.07
271.0922241	15.28
272.8622437	0.10
277.2005920	0.55
279.0538025	0.12
283.1817017	0.14
286.0549927	0.12
289.1408386	16.59
297.3535156	0.17
302.0202942	0.29
302.9687500	0.32
305.3452759	0.17
307.0552368	1.46
309.3104248	0.16
313.1586304	0.65
325.5210266	0.15
326.1856689	0.20
327.2431030	0.30
331.0693359	0.53
335.0963135	0.06
336.8729248	0.89
340.4288940	0.07
341.1339722	0.14
345.1235352	2.64
346.5501099	0.31
347.2979736	0.31
348.9596252	0.09
351.3043213	0.09
357.0585327	2.23
358.4985962	0.34
362.8898315	1.05
364.3652344	0.07
365.1770630	0.94
375.1114807	66.20
376.1238403	0.61
378.1569214	0.67
381.1049805	0.08
382.0833740	0.16
393.1594238	100.00
394.1828308	1.44
395.2885742	0.21
401.4104309	0.67
403.2265320	0.13
424.1475830	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1111.2939
Annotation	Unknow
Peak:m/z	Relative Intensity
343.0983582	0.02
463.3674622	0.04
607.4349976	0.01
752.5993652	0.01
1076.5227050	0.02
1111.2119140	100.00
1112.2843020	5.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.2111
Annotation	Methyl hesperidin
Peak:m/z	Relative Intensity
177.0387268	0.09
203.0654907	0.06
220.0634155	0.06
222.0290985	0.18
244.9813538	0.05
271.1615906	0.07
272.1418457	0.88
274.0474854	0.24
274.8878174	0.06
276.0008545	0.09
284.3886108	0.06
288.2537231	0.07
289.1170654	0.06
291.0230713	0.09
299.0475464	0.26
300.3273315	0.12
302.1146851	2.08
303.0847168	3.75
304.3829651	0.67
313.1690063	0.28
317.1229858	75.29
318.1209717	100.00
319.1782227	13.25
331.4395142	0.05
335.2219238	0.11
343.0640869	0.12
357.3877563	0.05
359.1928101	0.48
360.1793823	0.60
361.1286011	0.82
375.1947632	1.19
376.1306763	2.47
377.0093384	0.74
383.3314209	0.19
384.0862427	0.19
385.3609619	0.19
399.5062866	0.19
403.1473999	0.10
404.0782471	0.18
407.1816406	0.15
409.5516968	0.08
414.1025391	0.08
418.5783691	0.08
425.2514038	0.82
426.1202393	0.85
433.9414673	0.05
436.4743652	0.26
438.1948853	0.04
443.0670776	0.18
446.2730103	0.37
451.2532349	0.04
452.6988525	0.07
457.4383545	0.11
461.2518311	0.53
462.9776611	0.49
469.1808472	0.13
470.4855347	0.12
472.8766479	0.29
479.2919922	0.65
479.9343872	0.04
480.7835693	0.21
481.4459229	0.07
487.1423950	0.46
503.5340576	0.12
505.1185303	0.35
510.1126099	0.08
527.0098877	0.09
529.4138794	0.42
538.4067383	0.17
539.3906250	0.07
541.0150146	0.10
543.4235840	0.08
545.4472046	0.25
559.2272949	0.46
562.1554565	2.97
562.9611816	0.47
563.6017456	0.16
566.6287231	0.85
567.7067261	0.19
571.3739624	0.12
580.0569458	0.61
581.4650269	0.06
588.2644653	0.53
589.2324219	0.52
592.0444336	0.08
593.4227905	0.27
596.9386597	0.45
606.0983887	2.91
607.2669067	2.91
608.9968872	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1746
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
233.4250946	0.03
292.1727905	0.02
301.9805908	0.03
309.9695435	0.05
338.2054443	0.03
339.4174194	0.05
343.2835083	0.20
355.0889893	0.40
356.1094971	0.08
367.1596069	0.44
368.4161377	0.11
379.1872559	0.15
380.2094116	0.02
385.2479858	1.24
386.2562256	0.36
391.1080933	0.02
392.2541504	0.07
397.4536133	0.06
398.2547607	0.03
409.2365112	0.85
410.2193604	0.41
415.2213745	0.14
422.0488892	0.23
427.2069702	0.04
433.1130371	0.27
434.1653442	0.21
439.1907959	2.99
440.2070923	0.58
445.3158569	1.14
446.2506104	0.52
451.2397461	1.61
452.1757812	0.48
457.1311646	1.82
458.3008423	0.79
463.1331787	0.33
464.2197266	0.13
465.4474487	0.03
468.6384277	0.31
469.2550049	2.24
470.3909912	0.47
475.2172241	1.25
476.2432251	0.36
479.1420898	0.05
487.2328491	45.29
488.2055664	10.02
493.7623291	0.53
494.4279785	0.02
496.0078125	0.13
500.2504883	0.02
505.2205200	12.85
506.2691040	3.16
511.2365723	5.11
512.2739258	1.62
517.3216553	0.06
518.1937866	0.09
523.1892700	0.36
529.2385254	7.73
530.3364868	2.07
535.2899780	0.37
536.0906372	0.08
541.1912231	14.18
542.2690430	4.37
550.5283203	0.06
553.2133179	5.63
554.2607422	1.96
559.2038574	17.22
560.1600952	6.53
560.7683105	0.01
564.9125366	0.07
567.5344849	0.03
571.2192993	9.29
572.3421021	2.96
589.2048950	28.95
590.3228149	8.54
607.1836548	100.00
608.1928101	26.95
608.8466187	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.2242
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1525269	0.40
180.7430725	0.37
186.2618713	0.19
196.8679047	0.25
199.0286713	0.30
227.0367279	0.15
261.2486877	0.12
310.4908447	0.31
346.2590942	0.21
363.3897095	0.29
371.1871338	0.16
379.2858887	0.31
387.4119873	0.24
389.1451416	0.56
435.4031372	0.20
447.1726685	0.33
449.3684692	0.17
463.3543701	100.00
465.0208740	1.45
466.4508057	0.12
473.3062744	0.40
491.0117798	0.32
492.5064087	0.34
493.2462769	1.02
494.1807861	0.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	667.1672
Annotation	Okanin 4-methyl ether 4'-O-(2''-O-caffeoyl-6''-O-acetylglucoside)
Peak:m/z	Relative Intensity
205.0549316	0.09
208.2161407	0.09
214.1772461	0.08
229.1627502	0.14
238.9897461	0.04
240.0923920	0.04
242.1890106	0.13
242.9751129	0.02
247.1435242	0.19
255.2413635	0.03
256.1615601	0.06
256.9241943	0.05
258.3663940	0.09
264.8424377	0.03
266.0416870	0.02
268.9678650	0.02
270.0706787	0.12
272.1577454	0.04
280.3737488	0.03
282.9787292	0.10
286.1024170	0.06
287.0525513	0.09
296.2173462	0.03
297.1779175	0.08
298.0790405	0.02
299.3612671	0.24
301.1631470	1.07
302.0989380	0.20
307.1582642	1.40
308.1494751	0.32
311.1156006	0.61
312.0370789	0.11
313.0134888	0.03
314.0835571	0.58
315.2249146	0.26
325.1956177	0.02
326.2312927	1.09
327.1712646	0.05
329.1109009	10.96
330.1524658	4.95
331.1931763	0.20
340.2835693	0.04
344.0968018	38.08
345.1430664	9.30
346.1492920	0.81
348.2500610	0.05
359.1870117	100.00
360.1640015	20.31
361.3217773	0.13
365.2871094	0.05
386.2913818	0.08
387.1858521	0.44
396.3709717	0.02
401.2624512	1.26
402.3525391	0.18
410.1935425	0.04
411.1735840	0.02
439.0731201	0.06
443.3397827	0.40
447.2394409	0.11
469.8725586	0.08
473.4147949	0.03
474.3743896	0.03
489.4078369	0.04
521.2796631	0.23
523.0267334	0.59
524.3452759	0.18
536.2379150	0.05
548.1269531	0.07
549.5330811	0.02
563.1998901	0.04
564.3671265	0.07
565.2236938	0.27
566.4855347	0.06
569.8114624	0.02
576.5565796	0.09
587.1216431	0.05
592.7752075	0.07
606.2506714	0.02
623.1785278	0.02
625.5657959	0.02
631.3750000	0.06
635.1580200	0.12
636.4039917	0.03
637.3455811	0.08
649.2628174	0.02
652.2972412	2.99
653.4022217	1.16
668.2726440	4.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.31
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
145.2124481	0.16
174.1313629	0.39
199.1381531	0.30
235.3373413	0.63
270.0854187	0.43
274.0541382	0.55
302.8441772	0.12
308.0308533	1.59
308.7088013	0.36
321.0687866	0.54
331.0903931	0.57
337.1363525	0.34
339.2944946	100.00
346.4886169	0.43
351.4093018	0.61
357.9262695	0.14
363.0020142	0.33
374.5514526	0.69
378.3608704	0.54
390.5528259	0.15
407.4009705	0.43
419.3305359	0.62
423.1910706	1.59
434.7706299	0.23
449.3204346	0.56
453.440094	0.33
462.183197	7.87
463.1842651	1.02
468.8544617	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.2618
Annotation	Xylogranatin A
Peak:m/z	Relative Intensity
209.2143250	0.03
213.3343201	0.03
214.2035217	0.02
240.1164246	0.03
245.2304077	0.07
249.9032440	0.05
251.1464844	0.05
255.4094543	0.03
258.9082336	0.02
265.3062439	0.05
280.6059570	0.02
285.2313843	0.05
293.1834717	0.11
295.5427246	0.03
300.0957031	0.03
311.2118530	0.05
312.1558838	0.03
313.2382202	0.41
314.2475586	0.02
315.0920410	0.01
315.9592896	0.02
323.3474121	0.51
324.3109131	0.07
326.3649292	0.09
329.2197876	0.05
330.0911255	0.14
340.2772217	0.07
343.1777344	0.03
344.5343018	0.15
345.2605591	0.32
346.1985474	0.07
355.2155151	0.35
356.4746094	0.05
358.1347046	0.11
359.3500366	0.26
360.5101318	0.02
368.8734131	0.04
371.3516846	0.07
373.3585815	0.03
385.6139526	0.03
387.4234619	0.07
400.3831177	0.37
401.2013550	0.27
412.4903564	0.16
413.4656982	0.21
430.5768433	0.07
443.4047852	0.05
475.5714111	0.06
476.4765625	0.04
477.5149536	0.02
486.3038940	0.02
497.5228271	0.08
503.5528564	0.08
519.3159790	0.14
521.5820923	0.07
523.3511963	1.79
524.4430542	0.55
525.7279663	0.04
536.5162964	0.30
537.5864868	0.16
538.6250610	0.16
541.2590332	0.04
547.1235962	0.16
547.7311401	0.06
549.4779663	0.03
550.5960083	0.11
551.3894653	0.02
554.5148315	0.05
565.3626709	67.57
566.3593140	29.05
567.3693237	0.28
568.3552856	0.91
569.2987671	0.19
580.0809937	0.06
581.3115234	0.26
582.5625610	0.19
591.3529053	0.31
592.5174561	0.14
594.9307251	0.17
597.3919067	0.53
598.3423462	0.43
599.2866821	0.04
609.3225708	100.00
610.3164673	28.03
611.2612915	0.03
612.3032837	0.08
623.3592529	0.44
624.3385010	0.22
626.3936157	0.04
627.1109009	0.10
642.3288574	5.55
643.5306396	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	327.1433
Annotation	Spicatolide F
Peak:m/z	Relative Intensity
93.1304474	0.04
94.7961731	0.23
96.5887222	0.10
100.6869659	0.03
103.0964127	0.04
105.0220490	0.13
106.9558029	0.33
109.0460358	1.15
110.9239807	0.48
112.9140320	0.13
114.9507599	0.02
116.9210968	0.05
118.9087677	0.31
120.9555588	2.30
122.8904800	0.16
125.0334625	0.47
126.9997864	0.06
128.8212891	0.44
131.0166016	0.09
133.0877686	0.72
133.7922821	0.06
135.0777435	2.57
136.9478760	0.32
138.9038239	2.18
141.0893402	0.36
142.9065399	0.42
145.2595215	0.07
146.8404846	0.06
148.9799500	8.14
150.9965515	0.28
152.9240112	0.44
156.7973938	0.08
159.1421814	1.76
160.8421173	0.03
162.9544220	0.50
165.0389099	0.42
166.9339905	4.32
171.0200653	0.78
175.0157776	0.09
177.0725250	11.36
181.1383972	0.27
183.0103455	0.31
184.9457855	0.44
187.0783386	0.53
188.7176514	0.06
195.0299072	30.59
203.1406097	0.13
205.0746155	6.00
209.2648315	0.11
210.9425964	0.04
213.0938721	0.18
220.9163513	0.03
223.0603333	17.35
224.1606140	0.02
225.2005615	0.14
227.0344849	0.18
228.2410583	0.05
229.3133545	0.09
236.9519043	0.52
239.0119019	0.10
241.1135864	63.91
243.3427734	0.13
244.1375732	0.15
247.1318970	0.14
249.2117615	0.26
250.9940796	0.04
252.9434814	0.95
257.0716553	0.36
263.2660522	0.33
264.4704590	0.34
265.1190796	1.59
267.6386719	0.10
269.3717041	0.09
270.6627197	0.31
272.2289429	0.04
273.1678772	0.07
280.9474487	0.12
283.2369080	0.91
290.9981079	11.31
291.6114502	0.10
299.2653198	0.06
300.2566528	0.38
309.1929321	100.00
313.4290161	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.2
Annotation	Unknow
Peak:m/z	Relative Intensity
204.9653625	0.04
231.9164734	0.01
244.1382599	0.02
247.0543976	0.11
249.3776855	0.03
271.0230408	0.05
279.1549377	0.01
283.6183472	0.02
289.3757935	0.02
297.5453796	0.02
300.0494995	0.14
301.0634155	0.04
307.1232910	0.07
311.3755188	0.35
313.4309998	0.02
315.5624695	0.04
324.2171021	0.02
325.3730164	0.11
328.2025757	2.24
329.0395813	0.07
331.1893921	4.63
332.3171387	0.06
339.2600708	0.01
343.3431396	0.07
346.1395874	3.92
347.2961426	0.09
353.5314331	0.07
361.1592407	100.00
362.1018066	0.18
363.3430786	0.08
364.1930542	0.02
376.8913574	0.01
381.3560791	0.02
396.3033447	0.04
399.7224121	0.07
403.1436768	0.03
422.9211426	0.01
432.4439087	0.03
434.3185425	0.03
452.2489624	0.03
469.1974487	0.02
474.4462891	0.04
479.6208496	0.05
491.5266724	0.04
492.6878052	0.01
504.4895630	0.17
505.8532715	0.03
506.8399048	0.05
507.4432983	0.01
511.4720459	0.02
517.5240479	0.03
519.0856323	0.03
522.4024048	0.02
523.2942505	0.13
524.3564453	0.05
543.3034058	0.01
545.6319580	0.01
554.7994995	0.01
569.1190796	0.04
582.0180664	0.08
586.0209351	0.04
591.2941895	0.05
605.2766724	0.26
607.3736572	0.03
613.2032471	0.03
614.3107300	0.08
620.8652954	0.01
623.4844971	0.04
631.1640625	0.02
634.4547729	0.05
635.5522461	0.06
639.3582764	0.01
649.1204224	0.84
650.8197632	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.083
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
120.9801254	1.21
128.9792480	17.33
131.0658875	0.08
134.7254791	0.06
148.9048004	0.14
161.1298218	1.24
172.9183350	26.95
188.9786072	8.83
190.9696960	0.08
191.8093567	0.09
193.0562439	0.05
209.0503235	0.29
233.0493469	0.91
239.2338867	0.28
242.5044556	0.08
251.1130371	27.46
258.8412170	1.18
275.2856140	0.24
277.0274658	6.32
295.0480347	100.00
295.8449402	0.09
308.7327576	0.06
311.1504517	0.06
319.4711609	0.30
331.0969238	0.94
341.4145508	0.05
353.2775269	0.22
355.0729980	0.13
357.3955383	0.97
371.2084656	0.49
373.3915710	0.26
375.3448792	0.12
398.7717285	1.11
399.4386292	0.35
402.4799805	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.2028
Annotation	Troxerutin
Peak:m/z	Relative Intensity
271.0956421	6.78
433.2907104	25.28
579.2946167	4.97
741.0528564	0.52
777.2322998	100.00
777.9247437	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1667
Annotation	Nocardicin C
Peak:m/z	Relative Intensity
143.0545502	0.57
144.9240265	0.47
145.9401855	10.06
146.9843750	0.39
161.0467529	5.07
162.9820557	2.62
164.0526428	11.03
165.1164856	0.06
167.2398529	0.06
171.0440063	0.06
178.9855194	100.00
203.3511353	0.26
210.1329041	0.22
225.2155151	0.37
242.6660461	0.08
243.3284149	0.20
254.1369019	1.28
269.3116760	0.23
272.2028198	0.43
277.3913269	0.08
280.2496033	0.09
305.2926636	0.78
309.1194458	0.10
312.2906799	0.13
322.3106995	0.09
323.2583008	0.04
335.1624756	0.08
337.0983887	0.58
338.0593872	0.32
338.9363403	0.12
340.8795776	3.00
351.2772827	0.11
353.4718018	0.30
356.4591980	0.31
365.2666931	1.42
365.9405823	0.05
381.3519592	0.20
382.2817688	0.13
383.2541809	0.48
395.2743225	1.09
399.2178040	0.82
407.1959534	0.11
413.2876282	0.17
425.1474609	0.17
437.1144714	0.06
439.1316833	0.85
440.8818970	1.73
442.9779358	0.13
454.5056458	0.24
455.3776550	0.44
467.3013000	1.08
470.2905579	2.11
471.3919373	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1611
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9872131	6.48
117.0874329	0.14
119.0120544	1.04
125.0245667	0.59
129.1390686	0.30
130.6885071	0.70
139.0514374	0.49
140.8843384	0.22
142.9606628	3.97
146.8864899	0.24
148.7571411	0.89
158.9816589	0.54
160.9221802	9.12
165.3306274	0.18
166.9891052	0.41
178.9643555	2.42
180.7435455	0.75
183.1340790	51.30
186.4756927	0.47
187.1926270	6.05
189.2574158	0.18
193.1090698	0.08
195.3382721	0.15
197.1130676	0.46
201.2061157	0.86
207.0698242	18.00
210.1142426	0.16
213.0285950	0.11
216.0297394	0.50
219.1229706	0.85
221.1075134	0.28
225.1910400	5.55
229.1434021	0.76
234.9693298	0.36
237.2643738	0.52
243.0531006	0.12
244.1853943	0.95
247.0451050	0.10
255.1493530	10.44
257.3158264	0.59
261.0331421	0.22
265.2964478	0.33
271.2660217	0.15
273.3586121	0.28
279.3644409	0.15
285.0011597	3.72
327.1451416	0.90
329.1144409	0.18
331.2469482	100.00
345.0278931	47.71
349.2241211	22.26
355.1594849	0.12
373.3430176	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.078
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.8530731	0.36
128.9693604	2.92
132.7399902	0.11
146.9648285	3.10
163.1246033	0.10
172.9402618	2.04
190.9320221	100.00
193.1775208	0.26
209.0491791	12.14
221.3044434	0.16
223.1086426	0.17
239.1174316	0.09
261.3389282	0.13
262.0804749	0.10
323.0580444	0.18
337.3417969	0.19
349.1788025	0.63
367.1670227	7.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.9334030	0.25
127.0899200	0.07
206.7658691	3.87
212.9041443	0.70
254.6994629	0.55
267.0041504	0.10
285.0537720	0.06
286.7621460	0.11
290.8182983	100.00
296.5893250	0.03
308.5724792	0.11
314.8314819	0.59
338.8990173	0.04
357.0561218	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2105
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
97.27176666	0.06
100.8267975	0.06
102.8805389	0.07
105.0534668	0.32
106.8790588	0.32
109.1096649	0.14
110.8183441	0.02
118.9870987	0.03
120.9698486	0.47
122.9418488	0.08
124.8691025	0.20
126.6475525	0.09
127.2708282	0.04
131.0012817	0.47
132.9786072	0.56
134.9607544	0.15
137.0080872	0.30
140.8899536	0.19
143.0728302	0.44
145.0596619	0.56
147.2269897	0.12
149.0578308	0.19
151.0384216	1.64
153.1150208	0.23
155.0023804	0.16
156.8933411	0.60
159.046051	0.37
160.9982758	0.30
162.61763	0.05
163.2619781	0.16
164.7840576	0.22
169.1977997	0.03
171.0523682	0.11
173.0032043	0.60
175.1336823	0.75
179.1547852	0.09
181.129364	0.08
182.9764099	0.06
185.1859436	0.11
186.7983093	0.18
187.5408936	0.12
189.2576904	0.16
190.870636	0.11
192.9343109	0.09
195.2035217	0.14
196.9488525	0.30
199.0266724	0.55
201.1703491	0.35
205.3839111	0.09
206.8457947	0.03
209.1143188	0.17
211.206665	0.11
213.2503967	0.03
215.1870117	0.45
217.2894287	0.37
218.0355835	0.09
219.1582336	1.43
221.2434998	0.12
225.2607117	0.05
229.149292	0.33
231.2330322	0.15
233.086731	0.16
234.0662231	0.03
235.1548157	0.27
237.0443726	0.46
239.2356262	1.32
247.2161255	1.10
249.1625977	0.32
251.321228	0.30
257.2466431	6.67
259.8215332	0.06
262.3067932	0.17
265.3217468	0.51
266.0055542	0.02
272.3187866	0.04
275.2001343	100.00
293.2640686	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.0808
Annotation	Decarbamoylgonyautoxin 1
Peak:m/z	Relative Intensity
116.9205933	1.48
119.0170593	0.03
120.0815430	0.04
120.9525604	0.14
122.2114563	0.03
128.1088715	0.08
133.0036163	0.04
134.4333038	0.10
139.0502014	0.06
144.8713379	14.33
145.7160645	0.03
147.0841370	0.30
149.0278778	0.22
152.7369690	0.06
155.9542847	0.02
161.0208435	0.13
162.7156067	0.14
163.8600464	0.06
173.2092285	0.03
175.1655884	0.10
176.9671631	100.00
190.8931580	0.10
195.0683746	0.27
197.0488586	0.07
206.0687561	0.88
207.1349640	1.03
216.9265747	0.05
218.9496155	0.03
225.1324768	0.20
228.2208862	0.06
231.3278503	0.07
239.2048950	0.03
240.5516052	0.06
241.1858521	0.03
247.7567444	0.04
251.1612549	0.64
253.3832703	0.25
254.4748535	0.04
267.2088623	0.08
275.1152954	0.03
277.2035828	0.06
277.9034424	0.04
283.3568115	0.19
284.1872559	0.06
287.4223633	0.17
289.0441284	0.04
293.2987061	2.16
297.2088623	0.41
302.7783508	0.17
306.2599487	0.08
308.0330811	0.18
309.3363647	0.11
311.2840576	4.15
313.3903503	0.09
314.2884521	0.04
315.2854004	0.04
320.9297485	0.14
323.2301025	0.30
325.2320557	0.05
326.1391602	0.03
327.3218994	0.40
332.0488281	0.10
332.6976013	0.16
336.1008911	0.32
337.0989990	0.48
342.2236328	0.03
345.7765808	0.08
350.3252258	1.16
351.1699219	7.61
351.9446716	0.30
359.4908752	0.09
360.1071167	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	799.2311
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
245.1451569	0.05
286.9654541	0.04
305.1920166	0.06
313.9630127	0.06
316.2166443	0.99
329.4113159	0.03
331.2035828	5.71
371.1452026	0.03
373.1933594	0.03
402.0886230	0.02
439.0582886	0.05
447.2449341	0.05
475.3771973	0.20
493.2633057	11.85
533.2049561	0.14
534.6563110	0.14
535.3273926	5.21
545.4429321	0.05
560.5429077	0.05
565.4381714	0.05
573.2079468	0.05
574.6814575	0.29
575.3925171	1.97
577.0863037	0.33
587.1751099	0.05
591.3624878	0.04
600.5166626	0.03
601.4655151	0.05
617.2811279	0.02
618.1791382	0.09
619.2739868	0.58
635.8131714	0.06
637.2180786	11.40
637.8729858	0.06
647.1992798	0.09
655.3256226	0.04
678.7194824	0.16
679.3430786	1.50
720.3888550	0.04
721.6193237	0.07
739.1910400	0.62
780.2847900	0.09
781.2611694	0.11
799.2465210	100.00
799.9625854	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1825
Annotation	Butrin
Peak:m/z	Relative Intensity
175.2008667	0.09
177.0551300	0.54
187.0094452	0.03
191.0083466	0.03
198.3131714	0.03
201.1280212	0.08
210.0641479	0.08
214.9820251	0.24
219.1313477	0.04
227.0389557	0.01
237.2676697	0.07
240.0556030	0.03
241.1167603	0.10
242.2743530	0.13
249.1434937	0.05
250.9567871	0.05
257.0472107	0.34
258.1583862	0.09
267.8250122	0.10
269.1661377	0.07
275.2239380	0.06
277.9119263	0.03
281.4273376	0.03
282.8864746	0.06
284.9144897	0.03
286.2277222	0.34
297.5133667	0.03
301.0956421	100.00
302.1481934	0.08
303.4068604	0.04
309.3419189	0.03
314.2037964	0.06
325.1492920	1.24
325.7623901	0.01
343.1940308	1.07
355.2679443	0.06
357.1549072	0.02
367.1912231	0.20
428.3810425	0.04
435.3509521	0.10
443.3432617	0.05
444.1456299	0.03
459.3225098	0.78
461.6276855	0.02
463.1376953	0.31
464.1521606	1.43
465.2548828	0.29
489.4766846	0.02
490.4890137	0.04
497.2822876	0.03
505.0464478	0.12
506.2289429	0.43
507.3795776	0.16
546.3049927	0.25
547.4663086	0.06
548.3276978	0.04
549.5464478	0.06
562.3042603	0.06
564.4980469	0.09
591.2883301	0.04
609.2044067	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1777
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
175.0131531	0.25
177.1197205	0.23
180.2020569	0.04
183.1477356	0.08
185.1426697	0.08
187.1788940	0.15
189.0068665	0.16
190.2533875	0.14
190.8817749	0.05
192.9645844	0.90
195.0445251	0.11
199.0521545	0.39
199.8785706	0.12
200.9519958	0.33
201.9566803	0.05
204.9681244	0.44
207.2050171	0.10
209.9900208	0.07
210.8215332	0.17
214.1226196	0.08
215.7886353	0.06
217.0776367	0.08
219.0005646	0.06
223.0576172	0.09
225.1491699	0.04
228.2218628	0.22
229.1640625	0.04
230.3293457	0.06
231.0198669	0.27
232.8654785	0.06
235.0450745	0.76
237.0831299	0.11
239.5406494	0.16
240.2880249	0.03
241.0891724	0.10
242.1885071	0.08
246.8633728	0.05
250.6631775	0.06
253.2291412	0.09
253.8990479	0.04
255.0523987	0.05
256.1028442	0.23
257.1284790	0.12
258.2825012	0.03
260.0314331	0.06
263.1338806	0.04
265.2031860	0.19
266.0215454	0.18
271.2594299	0.22
272.1303711	0.04
273.3854370	0.06
275.0394287	0.14
277.0177917	0.15
281.3019409	0.06
282.3867798	0.09
284.0918579	0.56
285.2824707	0.07
286.0733337	0.47
287.1723938	0.31
289.0870972	0.15
289.9432068	0.21
295.0428467	0.16
296.9746094	0.04
298.5131226	0.51
299.1363525	3.25
301.1110840	100.00
302.4120483	0.09
308.4635620	0.03
310.2000732	0.20
313.1322632	0.64
315.0935059	0.48
316.3340454	0.83
317.2181396	7.61
318.2655334	0.21
318.9329224	0.10
323.5176392	0.05
325.1965942	7.90
327.1458740	0.08
329.2075195	0.10
330.0904541	0.03
330.9748535	0.53
339.2855225	0.20
341.0689087	0.30
342.0587158	0.07
343.1967163	10.62
346.4609375	0.12
353.3081665	0.05
355.1420898	4.06
357.2642822	0.08
358.2913818	0.03
359.1638184	0.08
360.2960815	0.03
361.0510254	0.03
366.8918457	0.27
367.5284424	0.16
369.3002319	0.24
371.5249023	0.12
373.1973877	7.34
375.2977905	0.06
376.1756592	0.10
379.1134033	0.24
381.2770386	0.08
383.1721802	0.88
384.1091309	2.16
385.1811523	1.10
386.2233276	0.04
387.5480957	0.04
388.2188721	0.18
390.4158936	0.10
393.8068237	0.07
395.3048096	0.03
396.1443481	0.14
397.1445312	0.32
399.3130493	0.16
401.2659302	0.06
403.0697632	0.45
409.4744263	0.08
413.6250610	0.43
414.5657349	0.63
415.2213135	1.22
417.2676392	0.06
420.2232056	0.04
421.3690796	0.18
424.3242798	0.03
425.3152466	0.12
427.2600098	0.24
428.9211426	0.06
432.2005005	0.09
433.3482666	0.68
438.5404053	0.11
439.1785278	0.10
441.5995483	0.04
443.1371460	0.34
445.0198975	2.64
448.6262817	0.24
449.2800293	0.59
450.0555420	0.29
456.2816162	0.16
457.1696167	1.09
459.1303711	0.04
460.5395508	0.05
461.3255005	0.85
462.2068481	0.08
463.2310181	0.93
471.0356445	0.06
473.2669678	0.12
475.1920166	16.11
476.1166382	0.22
477.4375000	0.38
478.1842651	0.09
479.2626343	1.01
480.0828247	0.89
481.2274780	0.22
486.4627075	0.13
489.2831421	0.21
493.6487427	0.04
501.2902832	0.44
503.2941895	1.16
504.2978516	5.15
505.2122803	11.26
507.2388306	0.08
515.2299194	0.04
519.6424561	0.04
521.3828125	0.07
522.5565796	0.71
523.4360352	0.08
532.3453979	0.04
533.0509644	0.05
534.4121704	0.40
535.5761108	0.08
537.2531738	0.15
539.2237549	0.08
546.5378418	0.23
547.3275757	0.05
559.9689331	0.07
562.3369141	0.07
564.3825073	0.24
565.7316895	0.73
575.3562622	0.04
577.1306152	0.16
578.3899536	0.17
580.4110107	0.61
581.4609985	0.23
582.3542480	0.10
583.9121704	0.09
593.2203979	0.21
597.2778931	0.15
598.3663940	0.31
602.4382324	0.23
606.1808472	0.51
607.2664185	2.18
609.1858521	0.18
610.4135742	0.04
625.3059692	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1111.2937
Annotation	Didmolamide B
Peak:m/z	Relative Intensity
463.6241150	0.03
505.4644775	0.04
607.4348145	0.01
687.4658203	0.01
751.2467651	0.01
1111.1440430	100.00
1112.2114260	1.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	386.8
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9711304	0.01
202.9433899	0.01
216.0064545	0.04
218.8852234	2.27
270.8989868	0.01
272.9642639	0.09
274.1465149	0.01
301.1428223	0.07
302.8508606	100.00
303.6375732	0.01
310.7153931	0.02
318.8856812	0.01
340.1328430	0.04
341.0280762	0.01
369.2646179	0.02
371.1998291	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2745
Annotation	PI(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
171.0780640	0.92
222.9533997	26.35
224.0088196	0.62
233.2998505	0.15
241.1014099	61.42
242.0544128	1.77
259.0306091	2.78
260.0209351	0.29
274.9418945	0.63
277.2459412	32.70
278.1975098	6.38
284.1181641	0.38
285.0972290	0.92
311.3602905	0.17
315.1030273	100.00
316.1245117	8.71
325.0690918	0.22
333.0959473	8.73
353.2584229	0.79
354.1666260	1.00
383.0471191	1.02
384.1720581	0.38
395.2752075	0.05
402.4329834	0.12
413.3181152	2.45
414.1316528	0.32
426.0871582	0.16
431.4317017	0.80
432.5713501	0.27
446.9683228	0.21
455.4506836	0.17
456.2846069	0.18
457.3104858	0.12
473.2108154	4.37
474.2341309	0.90
489.7661133	0.53
500.3236694	0.25
503.5676880	0.82
562.3749390	0.14
575.3389282	0.38
576.3482056	0.11
594.4769897	3.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.22
Annotation	Patrinoside
Peak:m/z	Relative Intensity
132.3324280	0.07
135.0047607	0.12
147.1420593	0.23
157.0065765	0.26
163.8864594	0.06
164.9024963	0.07
169.1319580	0.30
170.1144562	0.28
182.1708679	0.20
184.0517883	0.12
187.1934509	0.41
191.3522034	0.15
203.3024902	0.14
208.0585022	0.13
210.2052002	0.04
211.0826263	0.06
218.1506958	0.37
219.2966614	0.07
235.1340027	0.09
237.2170105	0.10
239.1365814	0.13
243.4645386	0.06
248.1230164	0.12
261.2939453	0.18
269.1255493	0.26
277.2432251	0.09
285.0488892	0.08
291.7472839	0.36
295.6503296	0.06
298.1273804	0.14
301.1940918	28.15
301.8745117	0.03
303.2119141	0.05
304.9040833	0.37
308.2939758	0.48
309.3016968	0.19
310.6664124	0.12
313.1251831	1.54
314.9077148	1.48
316.3573608	1.48
317.1094666	0.13
325.2041016	0.16
330.5228271	0.15
332.2456360	0.06
337.3620605	0.05
339.0245056	0.42
339.8692627	0.08
341.4927979	0.31
342.6192627	0.59
343.2314758	26.55
346.6463013	0.05
348.3188477	0.08
348.9462891	0.05
355.6960754	0.41
357.2256775	0.13
358.2140808	0.18
358.9921265	0.26
367.2408447	26.69
369.0385742	0.13
371.0146484	0.06
372.1521301	0.17
373.2180786	0.64
374.9339600	0.17
377.2000732	0.27
379.3832092	1.01
380.2544861	0.22
382.2369080	0.25
385.3731079	0.34
387.3009644	0.09
391.2075500	0.39
392.4858398	0.11
393.9989929	0.60
395.1541138	0.14
397.1436462	52.37
399.0707397	0.41
403.1788025	0.38
404.3434143	0.32
409.2672119	13.87
410.9245911	0.23
412.9590759	0.34
417.3157959	0.80
418.2550659	1.32
419.1535339	0.13
421.2803650	0.13
427.2047729	24.79
427.8408813	0.08
432.5061951	0.24
445.1695862	100.00
446.5494080	0.22
448.0529480	0.05
453.3391418	0.26
454.2955017	0.39
464.1990662	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	887.2783
Annotation	Kaempferol 3-isorhamninoside-7-rhamnoside
Peak:m/z	Relative Intensity
271.1339417	4.70
337.0776978	0.22
399.2901001	0.08
431.4599609	0.04
433.2036133	9.75
475.1948853	0.19
499.1848145	0.04
507.3826294	0.04
527.1754761	0.07
529.4396362	0.03
543.3526001	0.11
559.3517456	0.03
561.4929810	0.07
577.2462769	0.01
579.2758789	0.34
595.2070923	2.14
620.4772339	0.06
657.6828613	0.03
706.4428101	0.07
707.5095215	0.03
723.4496460	0.14
724.7166138	0.06
725.4296265	0.05
726.4244995	0.02
731.7407227	0.05
741.2329102	11.15
825.1727905	0.04
868.5136108	0.03
887.2538452	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.209
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1175842	0.28
220.9057617	0.12
223.0811157	0.06
265.0940552	100.00
266.2523804	0.09
282.3046570	0.18
304.1131592	0.15
314.4804077	0.14
323.3871765	0.09
324.2999878	0.25
338.1087646	0.20
341.3660889	0.19
354.8004761	0.05
385.2382812	0.04
416.0339355	0.24
418.2482300	0.16
419.8644409	0.28
420.5277100	0.20
428.4953003	0.11
456.1579590	0.10
475.2337036	0.16
488.2203979	0.80
489.2332764	0.17
508.2196655	0.07
509.3911743	0.10
515.3594360	0.09
517.3666382	0.19
560.2192383	0.17
561.3843994	0.14
564.5289307	0.18
568.2106323	0.20
570.9656372	0.07
574.3566284	0.08
589.1970825	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.1858
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
207.1318665	0.05
217.0803223	0.05
244.0878296	0.03
254.9272461	0.03
270.8082275	0.02
295.1535339	0.06
303.1926880	0.02
315.0911865	0.04
328.1863098	2.17
331.1470337	3.60
333.3702393	0.09
343.1231689	0.14
346.1912231	3.55
361.1972656	100.00
361.8394165	0.07
365.3631592	0.01
373.4906616	0.02
392.3496094	0.04
401.3448486	0.04
418.2619629	0.01
461.1209717	0.01
468.7795410	0.02
478.2728271	0.02
505.4008789	0.07
512.5237427	0.01
521.2529907	0.18
523.1674194	0.11
605.1873169	0.36
613.4698486	0.04
623.4573364	0.03
631.4116821	0.07
635.4412231	0.06
649.1849976	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1157.3014
Annotation	Didmolamide B
Peak:m/z	Relative Intensity
507.1942139	0.06
779.4267578	0.31
839.6618652	0.06
1094.5715330	0.10
1135.6442870	0.18
1155.5490720	2.67
1156.2139890	50.16
1157.2637940	100.00
1158.0535890	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	753.2253
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
234.9766998	0.21
272.0458374	0.05
284.0767517	0.36
299.1581116	0.16
300.0281372	0.20
301.1173706	1.60
325.3466797	0.08
329.3547363	0.16
339.1812134	0.03
343.1784058	1.84
344.4395142	0.12
355.5397339	0.06
357.3850708	0.05
429.2778931	0.08
432.9981079	0.04
445.0563354	0.12
447.4586792	0.22
451.4661865	0.18
455.4800415	0.04
459.2742920	1.88
463.2583008	0.20
463.9904785	0.25
464.7067261	0.06
468.4559326	0.10
475.5488892	0.22
488.6615601	0.15
489.3732300	0.12
491.3183594	0.08
501.2794189	1.48
505.1239014	0.27
506.3660889	0.40
535.5645752	0.06
541.2072754	0.39
547.8893433	0.11
559.3975220	0.32
591.0900269	0.97
609.3849487	90.61
615.3871460	0.10
617.4138794	0.23
622.2953491	0.07
630.2415161	0.08
631.5054321	0.09
637.5411377	0.03
638.9579468	0.03
651.3298950	40.07
673.6642456	0.05
691.4409790	8.21
693.3901978	0.25
704.2621460	0.12
720.2128906	0.08
730.8306885	0.30
753.2727661	100.00
753.9357910	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2781
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9746857	0.05
152.9371643	0.13
196.0859985	0.18
205.4511566	0.03
214.0845337	1.70
261.3253174	0.35
279.2686157	100.00
385.0918884	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.13
Annotation	Juglanoside A
Peak:m/z	Relative Intensity
106.9108276	0.10
110.9714355	0.97
113.0513306	0.46
121.0255585	0.73
133.0210876	2.23
135.0798340	0.34
135.9281006	0.21
136.9409485	1.08
138.2292786	0.15
146.9996643	0.28
150.8728638	0.08
157.0427246	6.55
159.1109009	2.62
160.8797455	1.47
165.0891724	3.24
170.8101044	0.29
172.7869263	0.17
175.0930481	31.43
177.1506348	1.48
179.2149658	1.91
183.8453369	0.27
185.2482452	0.42
188.2949829	0.45
193.0281830	0.96
197.3114319	0.36
202.9838562	34.82
203.6720581	0.06
212.2346191	1.17
213.3985596	0.47
220.9750061	100.00
221.5887146	0.27
229.1478882	0.19
230.7222900	0.20
239.2522888	0.68
240.2232361	0.19
252.2796021	0.63
268.1571045	20.72
269.2471313	11.79
283.3075562	0.16
293.2675781	0.11
306.0697021	0.09
307.1781921	1.56
310.3390503	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.093
Annotation	6-Deoxyclitoriacetal
Peak:m/z	Relative Intensity
127.8972855	0.01
132.2615509	0.00
160.9809570	0.00
165.0524292	0.00
181.0046234	0.01
182.1876526	0.01
185.1042328	0.02
190.3694458	0.01
201.2510529	0.01
205.1636047	0.00
209.9609985	0.01
219.1529541	0.00
223.0449524	0.00
226.9774780	0.01
231.1440430	0.01
234.1511841	0.02
241.2962952	0.01
245.2610474	0.01
249.2192383	0.03
255.1367188	0.01
265.4520874	0.01
267.2802124	0.02
273.4918518	0.01
284.7531738	0.01
291.5560913	0.01
295.2009583	0.00
297.2005615	0.01
301.2968750	0.03
305.2769775	0.02
309.9974670	0.01
311.3648987	0.04
312.2709961	0.05
313.0490417	0.00
315.3331909	0.02
321.5202332	0.01
322.2388611	0.01
323.2195435	0.02
325.1345825	0.01
326.0729065	0.02
327.2120361	0.04
328.1063843	0.01
329.3276367	0.07
330.4490967	0.06
331.2540588	0.02
332.5910950	0.01
337.3670349	0.10
338.1859741	0.01
338.9995728	0.02
340.1269531	0.01
341.1712036	0.04
343.1539001	2.37
344.2330933	0.60
345.3350830	0.02
346.3941345	0.01
347.1495361	0.00
355.4479065	0.73
356.5085449	0.13
358.1660461	100.00
359.1148682	16.10
359.7607117	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	490.1751
Annotation	Unknow
Peak:m/z	Relative Intensity
138.7628479	0.06
147.9252319	100.00
163.0634155	0.80
264.0627747	0.29
288.9113159	0.26
296.6489258	0.15
302.8299866	0.36
309.2452698	0.05
324.9796753	0.39
340.0487976	0.44
357.0781555	0.13
358.2043457	0.17
359.8593140	0.29
472.1381226	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1083.2974
Annotation	3,3'-Bisanigorufone
Peak:m/z	Relative Intensity
301.1782837	0.05
302.3804321	0.01
331.1278381	0.04
332.0678101	0.02
359.2345276	0.02
446.2873230	0.01
463.1840515	0.02
464.1285706	0.06
493.4189758	0.05
494.3322754	0.07
504.3829956	0.02
505.2921753	0.03
506.4648438	0.09
535.1671143	0.04
536.4584961	0.05
571.2838135	0.01
572.1257324	0.02
602.1791382	0.02
631.2909546	0.01
649.1481323	0.01
679.3651123	0.04
751.6376953	0.02
782.3413086	0.01
783.2189941	0.01
927.6370850	0.01
1066.4731450	0.10
1067.2396240	0.04
1069.3989260	0.03
1084.3884280	100.00
1085.3210450	18.49
1086.0078120	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
130.8103333	0.01
136.1463928	0.01
147.1164246	0.01
164.3059082	0.01
168.9530029	0.03
174.967926	0.01
178.6383972	0.04
181.8793182	0.01
186.5935669	0.02
197.2447052	0.03
199.0908356	0.03
204.125	0.01
204.9041443	0.04
209.4830933	0.04
213.3510742	0.02
219.2000122	0.01
223.0800781	0.02
227.1062927	0.01
237.2322083	0.02
241.268219	0.02
251.3502808	0.08
253.0784607	0.05
255.2354736	0.01
267.1256104	0.03
268.288147	0.27
269.1356812	0.44
270.097229	0.05
272.3110962	0.02
275.008667	0.02
277.1312866	0.01
281.1205139	0.11
283.1586304	3.39
285.1098328	0.17
294.3745117	0.46
295.4198914	0.35
298.0480347	100.00
298.790741	0.20
299.5153809	0.01
313.1175842	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.1974
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
144.9543304	0.15
149.1350098	0.16
152.7873840	0.20
172.9183655	0.07
175.9529114	0.72
181.2805481	0.10
182.9726257	3.75
188.9892273	0.10
194.0976257	0.12
195.2621002	0.22
197.1043701	0.91
198.1038818	0.74
200.8663330	0.07
206.9449158	0.98
209.2300720	0.41
211.0615234	1.22
219.0252228	0.48
223.7132874	0.45
225.2549438	0.85
227.0090790	0.49
228.0126953	0.17
228.8919067	0.24
231.2134094	0.25
235.2694397	0.95
236.2412720	0.15
236.9994202	0.28
238.2356720	1.30
244.0518799	0.11
249.5145264	0.13
251.2485657	1.29
253.1748962	16.70
254.1822510	0.13
255.0414734	0.08
259.2204895	0.44
260.9600220	0.15
263.1443176	0.69
265.1191711	0.31
267.1245422	0.42
269.2983093	1.92
271.4898376	0.07
279.1248474	0.35
281.0983276	0.56
285.1465759	0.79
287.2356567	0.20
289.0837708	0.18
291.9163208	0.16
295.1765137	0.25
297.1325378	10.31
298.1525269	0.61
301.2482910	0.10
303.5274658	0.35
304.3672180	0.13
307.1744385	2.10
308.1032715	0.14
309.1431580	0.47
311.1397095	0.06
314.2731628	0.18
315.0779419	0.10
319.3261108	0.42
321.3080444	0.11
323.1032715	4.16
323.7630615	0.59
325.2504883	3.79
327.2041016	0.18
331.2378235	0.75
333.1105347	0.14
335.3258057	0.30
337.2357483	5.29
343.5611572	0.12
347.3049316	0.64
353.6002197	0.30
354.2764282	0.20
363.3145752	1.91
364.1931152	0.32
365.1929321	16.95
366.2455750	0.66
367.2026367	0.39
369.4357300	0.45
374.0311890	0.13
379.2666321	11.17
380.3415833	0.09
381.2951355	5.88
383.2566223	100.00
384.2997131	0.25
388.6459656	0.19
394.2490540	0.79
395.2804871	0.06
397.3027649	0.49
399.3604431	0.41
405.4001770	0.12
407.2379150	0.60
409.3266602	6.08
411.1254272	3.49
413.3054810	1.13
415.0613708	0.08
423.3766785	0.12
425.3669434	1.46
427.1952820	69.04
429.0473633	0.10
438.9836426	0.12
440.2725220	0.08
441.2300720	0.53
442.4014282	0.98
443.3597107	0.37
449.2778320	0.54
450.5008240	0.23
451.3865662	0.22
456.3647156	0.38
457.2463074	3.55
469.2726135	92.71
488.4606323	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1155.3163
Annotation	Unknow
Peak:m/z	Relative Intensity
327.2561646	0.00
330.0121155	0.01
345.2243652	0.36
360.1995850	0.08
375.2926941	0.76
397.4837952	0.02
547.2185059	0.01
619.3790283	0.07
645.2066650	0.03
663.0184326	0.05
681.5450439	0.08
693.2301025	0.01
723.4871826	0.02
753.3663940	0.01
757.1270142	0.02
759.0614014	0.01
771.4512329	0.05
777.4238281	0.05
789.3029785	0.32
795.1692505	0.08
807.2659302	0.67
807.9572754	0.02
825.1301270	0.72
825.8964844	0.01
1123.4816890	0.03
1138.8372800	0.02
1155.3029790	100.00
1156.2746580	10.94
1157.0446780	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	212.164
Annotation	3alpha-Isobutyryloxytropane
Peak:m/z	Relative Intensity
93.9454956	0.13
94.6814423	0.02
106.8726044	0.03
111.9840393	2.21
122.8911438	0.01
135.8515472	0.15
140.0830078	0.03
152.0879517	0.04
153.9662781	100.00
155.0876923	0.02
156.2510834	0.01
167.2802582	0.01
167.9246368	0.01
170.2258759	0.07
174.9796295	0.03
182.8021088	0.02
194.0428009	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1727
Annotation	Unknow
Peak:m/z	Relative Intensity
171.7972870	0.14
173.0489502	0.27
174.1079559	0.07
182.0391998	0.10
200.0614624	1.09
202.0549622	9.91
214.0776672	0.14
218.1083069	1.83
219.0538025	0.81
249.2445221	0.10
260.8593750	0.54
262.0164795	100.00
265.2944031	0.41
288.8211365	0.16
321.0673523	0.24
338.9591064	0.32
359.3142090	0.09
361.1524048	0.67
380.9601440	0.03
404.2473755	0.19
409.3989258	0.14
411.2059326	0.54
412.3432617	0.07
439.1278076	0.27
442.3589478	0.18
449.1131592	0.14
471.3855591	1.65
472.4812622	0.39
484.1174927	0.05
493.3318481	0.31
511.2974243	0.41
525.2112427	1.41
526.3602905	0.05
543.2764282	4.71
544.1759033	0.62
544.7861938	0.46
586.1027222	1.04
605.0458374	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	992.481
Annotation	Unknow
Peak:m/z	Relative Intensity
992.6372070	100.00
993.7553711	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1235.6129
Annotation	Unknow
Peak:m/z	Relative Intensity
962.7050781	0.17
963.5688477	0.48
1106.6868900	0.20
1107.6719970	0.04
1200.6086430	0.01
1217.7104490	0.04
1218.7535400	0.38
1235.6887210	100.00
1236.6713870	32.55
1237.4250490	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.2192
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1763153	0.17
160.9797821	0.14
177.1477661	0.11
178.0242462	0.13
190.9279785	0.05
193.2665253	0.23
211.0921478	1.45
214.1703796	0.07
218.3043823	0.14
235.1643066	0.04
237.0957184	0.07
237.9798126	0.05
238.9872894	0.15
252.1643677	0.07
257.3985901	0.15
262.9442749	0.04
265.4351196	0.08
275.3784485	0.17
283.3768311	0.07
293.0806274	0.11
307.5593262	0.04
311.2266235	0.34
313.1525879	0.29
315.9401245	0.18
327.0934448	0.07
341.4122314	0.06
342.3160400	0.14
345.4693604	0.17
347.2969360	0.04
351.1924438	0.08
359.1276245	0.10
362.1614990	0.08
363.2243652	0.73
371.5109863	0.27
373.2645264	0.11
375.2396240	0.10
381.2947998	0.39
391.4624023	0.12
397.5679932	0.14
404.9984131	0.17
407.2695312	0.50
418.4485474	0.08
419.3378296	0.17
421.2615967	0.18
439.3922729	0.36
446.2624512	0.06
462.7350464	0.28
463.4387207	0.39
473.4044800	0.11
479.2711792	100.00
479.8850708	0.17
481.2885132	0.10
487.1928711	0.56
489.1316528	1.17
505.3778076	0.30
507.2016602	0.59
526.2865601	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
152.7380981	0.04
170.9113770	0.22
173.0149994	0.19
190.9809418	100.00
249.0533142	0.06
305.2187500	0.03
341.0176392	0.16
353.3058472	0.14
496.8130493	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	638.68
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9340515	0.64
295.3479004	0.04
298.4948730	0.03
300.6886597	0.07
302.8355103	8.27
308.9473877	0.05
373.1377563	0.04
382.8020020	0.04
384.6234131	0.10
386.7438354	36.50
400.0913696	0.05
417.4635620	0.03
454.7161255	0.05
463.8781128	0.20
464.7937012	0.39
468.6822510	0.33
470.6452637	100.00
471.3410645	0.14
482.8950806	0.64
483.7875366	0.07
540.1219482	0.05
552.0465698	0.28
553.0925903	0.14
554.5515747	50.67
590.5401611	0.09
591.3816528	0.08
638.4031372	1.05
639.2655640	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2086
Annotation	Provincialin
Peak:m/z	Relative Intensity
149.1239624	0.10
191.2276306	0.17
201.1249390	0.08
231.1767883	0.07
256.9956665	0.06
258.9841919	0.20
260.8215942	0.17
271.2678833	0.78
275.2144775	0.18
281.4725952	0.15
284.1570435	0.21
289.3154297	0.10
296.9623413	0.74
298.6697388	0.49
299.2703552	4.55
309.0270996	0.09
315.1331787	0.23
327.3421021	0.31
333.2195435	13.69
335.3202515	0.13
343.2564697	0.07
353.1701050	1.85
365.3752441	0.20
367.5935059	0.66
371.2991943	0.39
375.2473755	0.71
391.2506714	0.75
393.3930664	1.73
401.2086182	1.48
407.6374512	0.08
408.9436035	0.47
411.2291870	14.65
428.5742188	3.86
429.1846924	44.02
430.0239258	0.16
435.3946533	0.69
453.2358398	68.90
453.8447266	0.47
455.3712769	0.13
471.2850342	100.00
471.9263916	0.19
499.2151489	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8752
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8819885	0.29
160.1016083	0.06
174.9373474	2.13
176.0957947	0.11
186.9179535	0.02
201.0498962	0.02
214.9723206	0.05
216.0537109	0.02
218.0335083	0.02
233.1691284	0.03
233.9163818	0.04
245.0500183	0.62
246.0571899	0.38
260.9631958	0.11
273.0571289	1.08
274.0421753	0.39
275.0859985	0.11
288.9523315	16.05
290.0470886	3.71
303.0214844	0.01
303.8299561	0.02
304.9086609	11.58
306.0148926	1.13
344.6069946	0.06
387.2149048	0.16
388.5761108	0.60
389.2011108	0.01
401.1966553	0.07
402.9086304	6.62
404.0166016	3.73
417.0477905	0.03
418.8858032	100.00
419.8748779	25.43
420.5371094	0.11
445.2705688	0.14
458.9147339	0.04
459.9102783	0.05
461.1943970	0.07
471.9650879	0.03
486.7785034	0.14
487.7931519	0.31
494.8027954	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.1594
Annotation	(+)-Validoxylamine G
Peak:m/z	Relative Intensity
104.8726654	8.64
108.0930099	0.07
108.8746796	0.08
111.0848389	0.05
113.0353012	0.04
122.7452850	0.06
126.8656616	1.85
128.1253662	0.08
137.0603333	0.02
142.8558960	0.03
143.8098602	0.06
145.0595093	0.72
146.8601837	0.11
148.9451752	0.08
152.8921814	0.06
156.0956116	0.06
158.8944397	0.21
164.6378021	0.03
172.9828033	0.02
177.0095825	0.17
179.8790283	0.03
180.9488068	0.04
184.0178833	0.02
188.9423523	0.06
195.1531677	0.24
200.4011688	0.03
205.2547150	0.02
213.0319519	0.35
215.2254333	0.02
219.0359192	0.03
220.5476074	0.02
224.8482056	0.04
230.9250183	11.80
233.5032959	0.02
240.3301697	0.09
245.5350952	0.12
246.5697937	0.04
248.8818665	100.00
249.5890808	0.09
250.1931152	0.04
256.2825317	0.02
258.5298767	0.04
261.9923096	0.03
262.8125000	0.02
264.8380737	0.03
266.1045532	2.03
266.8726807	0.92
281.1201172	0.42
284.0083618	22.68
288.0127563	0.07
292.1832886	0.04
294.9519958	0.07
299.1256714	3.50
300.9285278	0.03
311.0341187	0.04
315.0477905	0.04
316.2228394	0.28
317.0936279	1.39
325.1056519	0.34
333.0715942	0.32
334.2478638	0.69
335.3078003	0.10
337.5249634	0.02
338.2488403	0.04
343.1908264	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
120.9904175	0.55
125.0740814	1.36
128.9217834	0.15
130.9158936	3.50
136.9513092	0.78
142.3872986	0.79
143.0613251	9.72
149.0822144	1.88
153.1139679	0.10
159.1788635	0.25
160.9579468	22.84
163.0484009	0.29
175.0668182	0.24
177.2062378	1.52
179.0036621	77.62
181.0874481	0.71
187.2784271	1.11
189.0934906	0.42
203.1187592	0.45
205.1454468	71.65
206.6584015	0.10
207.8991089	0.08
211.9131470	0.18
222.8870087	6.91
225.0798645	5.06
227.2183838	1.39
233.3830261	0.34
235.0596008	0.12
251.0621338	1.75
258.8916626	0.36
267.2132568	0.29
268.3100281	1.01
269.3308105	0.57
271.3251343	0.54
272.3492126	0.14
275.9696045	0.69
277.2764893	1.71
281.2771301	0.18
283.2960815	0.36
284.2088013	0.32
286.1229553	0.23
304.9282227	0.21
311.1343384	0.35
322.1326294	0.44
329.0602417	0.17
337.3257141	0.10
341.4256287	0.53
352.9992676	0.28
359.2324219	0.17
367.1429138	11.23
368.3472900	0.47
369.3806458	0.22
371.2265625	0.71
382.9448853	0.25
385.2035522	100.00
387.2106628	1.58
388.2311096	0.11
389.2919006	1.25
391.3671570	0.12
396.5872498	0.07
403.3577881	0.35
411.3069153	0.27
412.4705200	0.95
413.2689819	1.04
416.4373474	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.2089
Annotation	Unknow
Peak:m/z	Relative Intensity
183.0114899	0.07
265.0839844	100.00
273.1169739	0.21
280.2686157	0.05
282.1572876	0.10
304.8760986	0.18
322.9231873	0.11
341.3018799	0.21
343.3735962	0.09
362.0352783	0.41
366.1313477	0.04
379.3455200	0.08
385.0973511	0.29
391.3165894	0.09
403.3158569	0.25
459.9049683	0.07
503.4214478	0.04
509.0974121	0.22
533.3116455	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1646
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
172.7157135	0.05
175.1748657	0.08
182.0932007	0.12
195.0357513	0.03
255.0424042	0.05
268.1835632	0.09
286.4514160	0.11
288.0528564	0.06
308.2218628	0.13
312.9435425	0.07
325.2234497	0.53
329.2282715	0.64
337.1718140	0.42
349.3106689	0.22
352.9866943	0.10
355.2100220	2.09
359.2055664	0.20
361.2540894	0.14
367.0405884	0.12
372.8734741	0.37
379.1735229	1.26
381.6206055	0.03
391.3179932	0.20
398.3539429	0.04
401.1279297	0.29
403.1394653	0.32
409.0054932	3.16
409.6920166	0.09
411.1792603	0.07
412.3282471	0.06
414.6706543	0.28
415.2898560	0.79
416.4295654	0.24
421.2031250	1.32
426.7393188	0.29
427.3876953	1.99
429.0900879	0.06
430.3225708	0.03
433.0087280	0.81
433.6766968	0.02
439.1340942	2.72
440.9657593	0.14
445.0731201	0.46
447.2286377	0.21
449.4235229	0.04
457.2431641	55.67
463.2732544	0.09
466.9149170	0.23
469.4020996	0.17
473.3823853	0.03
475.1627197	14.92
475.8441162	0.05
481.2866821	5.07
493.1646729	0.32
499.2720337	7.58
505.0914917	0.41
511.1527100	17.57
511.7681274	0.26
519.5244751	0.15
523.2608032	8.14
529.2271118	19.38
537.5485229	0.39
541.2998657	10.33
550.1666260	0.07
551.2723389	0.08
559.2326050	33.72
577.2420044	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1926
Annotation	Creoside IV
Peak:m/z	Relative Intensity
113.0832367	0.12
119.0475159	0.05
125.1796417	0.02
130.6969604	0.01
137.2090149	0.02
143.1040955	0.09
159.1382751	0.22
161.0097351	1.76
177.3554230	0.02
179.1545410	0.16
187.1350708	0.90
199.2374878	0.02
221.1818695	0.18
227.2795715	0.02
229.3840027	0.02
233.1955566	0.02
243.1214294	0.02
253.2620544	0.01
259.1917114	0.01
263.2559204	0.02
270.6852722	0.15
271.4113770	0.07
291.2798462	0.04
305.3702698	0.02
333.0402222	0.03
335.4487305	0.04
347.3287659	0.10
349.2128601	100.00
349.8620911	0.18
353.1713562	0.99
358.9935608	0.06
377.0470886	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2083
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
152.9089661	0.08
169.0276031	0.29
173.2084961	0.07
189.4091797	0.04
203.2544861	0.31
205.1769714	0.06
213.0905609	0.13
217.4179688	0.13
219.0181580	0.06
229.3399658	0.06
231.1356354	0.04
257.1981506	0.26
261.1021729	0.28
271.1479492	1.13
275.1854858	0.04
289.2729187	0.36
292.2355957	0.31
297.4887695	0.38
299.1613770	6.57
307.1584473	0.07
315.3312988	0.67
320.8663330	0.08
327.0182495	0.30
333.1884766	14.91
338.8266602	0.05
343.0798340	0.09
345.1340942	0.10
346.8383789	0.12
347.8308716	0.28
353.2660522	1.29
365.5875854	0.18
367.3237305	0.38
371.1829834	0.04
375.2117920	0.41
383.8356323	0.15
385.3889160	0.06
387.4030762	0.09
391.3237915	0.65
393.1286621	1.27
397.4833984	0.06
401.2269287	0.61
407.2891846	0.11
409.1138916	0.69
411.2420044	14.82
412.1737061	0.21
429.1051636	52.25
429.7744751	0.45
431.1014404	0.15
435.1385498	1.14
439.4519653	0.14
446.3215942	0.09
453.2164917	63.96
453.8412476	0.13
455.4847412	0.86
457.7054443	0.16
460.9064331	0.15
469.4442139	0.12
471.2664795	100.00
472.1105347	0.16
472.9750366	0.24
499.2697144	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.0824
Annotation	Eupatorin
Peak:m/z	Relative Intensity
127.8941269	0.02
161.1584778	0.02
180.0543976	0.01
184.1439819	0.01
193.0200806	0.10
195.3591309	0.02
205.1396637	0.02
208.2615356	0.01
218.9190674	0.02
222.9617004	0.05
229.1666565	0.05
233.9893799	0.02
241.2284851	0.04
244.225708	0.03
249.0355225	0.05
254.4179077	0.03
255.2131958	0.05
256.0160217	0.01
263.2405396	0.03
269.3965454	0.05
271.1893005	0.01
280.1002197	0.03
281.8121338	0.01
282.9012146	0.08
283.5485229	0.04
284.2560425	0.09
285.3944092	0.02
289.0336304	0.03
292.3746948	0.01
293.1781311	0.01
296.118866	0.01
297.2952881	0.02
298.096344	0.04
299.1228638	0.05
300.1360779	0.20
306.4560242	0.02
310.0220642	0.05
311.2164917	0.05
313.1621399	4.34
315.1473083	0.60
316.1359558	0.01
323.2358704	0.02
324.2792358	0.05
325.2540588	0.42
328.0596008	100.00
329.1653442	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.2213
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
219.1122742	0.07
225.0660095	0.04
230.5123291	0.04
238.9644470	0.18
240.3352356	0.08
241.1214752	0.33
242.0655212	0.06
244.9319916	0.09
254.7140503	0.22
258.2706299	0.09
259.2267456	0.04
269.3082581	0.15
271.2297668	0.72
272.1629944	0.19
275.2781372	0.24
285.4302673	0.11
287.0679321	100.00
288.1782227	17.68
290.0531616	0.13
299.0869141	0.17
300.0457153	0.11
301.2619019	0.17
306.9381714	0.04
308.1121826	0.12
312.0368042	0.14
312.9333801	0.05
320.9360962	0.16
323.1304321	0.30
325.1890259	0.13
329.1754761	0.95
330.0246582	0.57
332.3325195	0.05
337.0828857	0.20
340.3307495	0.07
343.1987915	0.16
353.1611328	0.94
361.3900146	0.07
364.4023438	0.15
365.2891235	0.09
373.2362671	0.93
374.1946411	0.36
379.3488159	0.03
383.0228271	0.21
395.2294312	0.03
396.3198853	0.05
397.2321777	0.63
398.1609497	0.31
398.8147583	0.18
401.2783813	0.10
413.2960205	0.05
415.3887329	0.50
416.4719849	0.15
417.4501953	0.06
422.4505005	0.03
427.2993774	0.11
431.1456909	0.38
431.9072266	0.50
433.2305298	2.25
434.1740723	1.11
440.3657227	0.05
449.1015625	8.16
450.2373047	3.22
457.2838135	0.04
463.2524414	0.07
473.2738037	0.03
475.3438110	0.25
476.3634644	0.18
491.2911987	0.26
492.3568726	0.06
493.3884888	0.22
494.3909302	0.15
517.3239136	0.19
518.4415894	0.17
525.3641357	0.14
528.5191650	0.03
535.3483276	0.33
540.8713989	0.13
544.4118042	0.19
558.4725952	0.19
559.2136841	0.16
561.2767944	0.36
562.3192749	0.27
574.5162964	0.07
577.2206421	0.28
578.0884399	0.23
579.0852661	1.01
580.3474731	1.77
595.1495972	88.18
596.2294312	34.10
606.9714966	0.10
619.0099487	0.07
622.3712158	0.03
637.1165161	0.10
656.3452148	0.21
683.2984009	0.04
688.5625000	0.23
692.7673950	0.17
697.9832764	0.33
705.2844849	0.20
706.5475464	0.28
709.3436890	0.03
723.0928345	0.51
724.4750366	0.12
742.1120605	15.30
742.8442383	0.11
743.8475952	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1749
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
190.7795715	0.03
209.3264618	0.05
224.8078003	0.05
287.1815491	0.05
313.2692261	0.22
315.3811646	0.12
325.2456665	0.05
332.2832031	0.07
336.9246216	0.03
361.3428345	0.04
367.1499634	0.57
368.3491821	0.02
385.1371460	0.73
386.0220337	0.12
396.9847412	0.42
398.1893921	0.03
409.2817993	0.56
410.4707031	0.21
422.1718140	0.03
427.2017212	0.28
428.0925293	0.10
439.1582031	2.65
440.1352539	0.52
441.3598633	0.06
445.1040039	1.18
446.2879028	0.63
450.3637695	0.09
451.2791138	1.00
452.1406250	0.21
457.0811157	0.89
458.2208252	0.49
459.4996338	0.11
463.2603760	3.22
464.2886963	0.83
469.2504272	0.79
470.2401123	0.70
475.2069092	0.47
476.0225220	0.02
479.5886230	0.04
487.1880493	43.25
488.3179321	11.91
492.9481201	0.31
493.7020264	0.07
505.2125854	15.06
506.2278442	3.23
511.2310181	4.62
512.3201294	1.50
517.3189697	0.17
523.2273560	0.07
524.5704956	0.03
529.2332153	8.79
530.3252563	2.73
534.9354248	0.09
535.7197876	0.13
541.1956177	15.73
542.2924805	5.41
553.2007446	6.61
554.3230591	2.41
556.7640991	0.03
559.1936646	17.54
560.2426147	5.20
565.1405640	0.08
571.2083130	10.87
572.2205200	4.04
582.0574341	0.03
583.8309937	0.22
589.2161255	33.51
590.2685547	9.79
607.1950684	100.00
608.2858887	21.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	RHOIFOLIN
Peak:m/z	Relative Intensity
165.1280823	0.04
187.3059845	0.03
203.2990417	0.18
228.9806366	0.01
243.2571716	0.04
254.7528992	0.02
271.0527954	100.00
272.1228638	0.03
277.0946045	0.04
283.1022339	0.21
295.0645752	0.02
307.9810791	0.05
312.9762268	0.29
330.8233643	0.04
337.06427	0.15
341.4154663	0.02
345.0942993	0.05
360.392395	0.05
361.1582642	0.05
367.0844116	0.25
379.147583	0.13
381.0905762	0.05
385.5057983	0.02
396.9660645	0.09
399.0610962	0.06
415.2127075	0.70
417.1741943	0.53
422.9381714	0.03
426.2757568	0.06
433.1766357	10.39
441.2242432	0.02
457.2250977	0.01
459.4937134	0.03
475.2249146	0.11
483.3641968	0.02
491.7513428	0.06
497.9345093	0.02
524.203186	0.03
543.3831177	0.02
560.8386841	0.15
571.3986816	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.05
Annotation	UDP-glucose
Peak:m/z	Relative Intensity
158.9515839	0.05
193.0433655	0.11
197.1132507	0.26
200.8792114	0.04
211.0759888	3.99
213.232254	0.07
229.0673218	0.57
241.0578003	1.27
273.0513	0.33
280.0863037	1.12
296.8415527	0.21
305.1782532	0.15
313.1273193	0.33
321.0776978	0.45
323.0343018	100.00
334.3777466	0.05
353.0026855	0.14
358.2299194	0.06
380.8092041	0.10
385.1626587	2.57
396.1932373	0.16
396.9255371	1.35
403.0727539	3.03
444.237793	0.09
453.3845215	0.11
467.1530151	0.64
472.8590698	0.08
480.6759644	1.69
481.3859253	0.15
522.0844727	0.10
547.1819458	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	523.1744
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
163.1361847	0.02
163.7953796	0.02
205.2423096	0.01
213.0003967	0.01
216.9015350	0.05
219.1453247	0.03
257.2371216	0.02
267.4664917	0.03
269.2172241	0.02
277.1329346	0.02
281.2102661	0.01
287.0302124	0.03
290.3560791	0.03
293.5473633	0.08
295.5020142	0.07
305.2662354	0.07
311.3615723	0.08
314.0349121	0.04
321.3947144	0.04
323.2504272	0.29
329.2586670	0.02
341.1126709	0.06
344.1354980	0.08
349.0272217	0.03
349.6911621	0.03
357.1786499	0.03
358.3206787	0.07
359.0604248	0.05
360.2198486	0.04
363.6325073	0.03
365.4865112	0.13
367.2620239	0.18
371.3107300	0.01
381.5783691	0.01
383.3544922	0.19
393.1038208	0.04
404.4761353	0.04
405.2202759	0.02
411.1757202	3.80
415.3292847	0.78
419.2899780	0.02
425.1119995	0.01
436.2805176	0.03
438.9312744	0.05
439.5475464	0.16
444.7528076	0.02
446.6163330	0.02
451.6324463	0.05
452.3292847	0.01
461.7819824	0.01
469.2593994	100.00
479.2125854	0.04
484.7936401	0.02
487.0750122	1.74
505.1737061	0.03
506.2932739	0.11
507.1666870	0.57
508.2968140	0.24
509.3842163	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1525
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
239.0297241	0.08
264.9313965	0.06
277.2108154	0.07
353.2734985	0.30
368.0803223	0.06
382.9168091	0.53
395.3814697	0.15
434.6507568	0.06
455.2852173	0.42
471.3112793	0.05
472.6950073	0.12
473.3442993	4.67
485.2694092	0.18
497.2324219	0.05
503.2529907	0.51
515.2269897	0.75
545.5777588	0.14
562.2561646	0.27
575.3843994	0.54
580.5060425	0.48
589.5061646	0.33
593.3122559	5.22
617.4092407	1.09
635.2626343	100.00
635.9451904	0.61
660.2344971	0.09
679.0393677	13.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9171
Annotation	Unknow
Peak:m/z	Relative Intensity
116.7892532	0.00
130.9265594	0.13
132.0899658	0.00
146.7712250	0.03
159.0551453	0.20
159.9278564	0.02
174.9837341	1.40
175.9755554	0.07
198.9742126	0.01
215.2601776	0.01
229.0674744	0.04
242.3774414	0.01
245.1043701	0.32
245.9706726	0.08
261.0910339	0.03
273.0778809	3.07
274.1403809	1.20
287.2984924	0.01
288.9693298	100.00
289.9302673	14.09
313.2987061	0.00
314.0075989	0.01
329.0067749	0.08
329.9813232	0.05
346.7785645	0.02
348.0286255	0.02
357.1112976	0.05
358.0158386	0.01
359.3815918	0.03
360.1641846	0.02
365.1898499	0.01
374.6989136	0.00
377.7241211	0.00
385.2112122	0.01
386.2943726	0.02
391.0421448	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.22
Annotation	Quercetin-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside
Peak:m/z	Relative Intensity
215.0994263	0.01
286.1029663	0.06
301.1435242	6.05
325.427002	0.04
343.1990967	0.14
353.0914307	0.02
384.3248291	0.02
445.3863525	0.01
463.2374268	14.67
463.8630371	0.03
487.2982788	0.06
505.1984863	6.85
521.2338867	0.03
534.0639648	0.03
543.9180298	0.03
545.2595215	2.90
546.9387207	0.09
569.989563	0.04
571.4157715	0.06
576.2179565	0.05
577.7490845	0.06
587.6181641	0.02
589.2473755	0.18
607.3612671	8.17
613.486145	0.19
624.7283325	0.02
625.4562378	0.09
648.1525269	0.04
649.3488159	0.18
667.0142822	0.02
714.3496704	0.09
724.2642212	0.01
736.371521	0.07
751.5272827	0.09
769.2199097	100.00
769.9370728	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	787.3918
Annotation	Phepropeptin D
Peak:m/z	Relative Intensity
541.5649414	0.03
598.3380737	0.02
751.6071167	8.00
754.2205200	0.08
772.1047974	0.01
787.3208008	100.00
788.0902710	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1885
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
244.8689423	0.68
271.4598694	0.31
299.1991272	0.15
301.1067505	52.45
305.2402954	0.53
315.1934509	0.33
325.2367554	1.90
341.2554932	0.89
343.0606689	6.79
360.2153320	0.65
367.2214355	0.28
402.8059692	0.25
409.4237671	0.30
445.2783813	1.22
448.9868164	0.52
463.2730713	100.00
466.2141113	0.19
468.9721069	0.21
487.3296509	3.85
503.4556885	1.28
505.2846069	71.51
506.4437256	0.17
517.2992554	0.55
526.3637085	25.81
527.0469971	0.07
529.2250366	1.26
545.3364868	20.31
547.2519531	15.96
553.2500000	0.11
555.3852539	0.57
557.2388306	0.64
567.4343872	0.76
569.3001099	1.28
571.2816772	1.98
575.2758789	0.63
577.3528442	0.29
587.0446777	0.37
589.3180542	6.55
598.4565430	0.69
604.9553223	0.39
607.2985840	90.73
613.2818604	1.92
617.3590698	0.72
627.2446899	0.12
628.3591919	5.21
629.4548950	0.68
631.2454834	5.12
632.2457275	0.24
635.2813721	0.19
645.4335938	0.63
649.1406860	37.91
649.7745972	0.24
655.3812866	0.49
679.0775757	0.16
679.9016724	3.43
691.3244019	2.55
697.4545288	0.12
709.0984497	0.38
715.3179321	2.67
731.5885010	0.14
733.4505005	4.82
749.2689819	0.64
751.3753052	56.94
752.2156372	0.30
769.1344604	1.06
769.8560791	0.10
770.6681519	0.16
791.2887573	1.00
793.4684448	1.17
811.2949219	3.92
833.3738403	0.07
853.2908325	2.38
913.4025269	0.95
955.3893433	0.15
1052.9731450	0.97
1053.7661130	0.37
1057.0510250	0.39
1215.3129880	5.97
1257.3447270	8.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	622.2479
Annotation	Unknow
Peak:m/z	Relative Intensity
176.3105621	0.05
179.8621521	0.04
186.0006409	0.02
197.2187958	0.04
199.2873077	0.03
201.9158783	0.02
207.3668213	0.05
211.2572021	0.03
218.1632080	0.40
237.2301025	0.03
238.8950806	0.03
258.0703125	0.03
263.2179260	0.07
270.0227661	0.05
283.3457031	0.05
284.0451660	0.09
293.1860352	0.02
295.1191406	0.08
296.2545776	1.21
303.1177979	0.03
309.1337891	0.03
313.8784180	0.04
316.1764526	0.48
347.5705566	0.03
350.4106445	0.03
352.4473877	0.06
356.4656982	0.04
357.4721680	0.03
359.0706177	0.02
362.2582397	0.03
362.9724731	0.03
373.2730103	8.44
374.4106445	1.70
381.0053101	0.06
397.2121582	0.02
398.9836426	0.03
411.5435181	0.05
417.8034058	0.04
420.5020142	0.01
424.2008057	0.05
441.3115845	0.02
455.3265381	0.04
458.2183838	0.11
459.1865845	0.12
460.2098999	0.24
462.4791870	0.15
465.3672485	0.04
475.7384033	0.14
476.4195557	0.07
484.3126831	0.03
492.1709595	0.01
512.2371216	0.08
514.2061157	0.03
524.4737549	0.03
531.1218872	0.03
540.5625000	0.04
547.0685425	0.04
555.2910156	0.13
556.8251343	0.05
559.6380005	0.07
562.1175537	0.01
563.5344238	0.01
577.3247681	1.03
578.4874268	0.59
586.0279541	0.09
589.6740112	0.13
604.2461548	100.00
604.9276733	0.26
631.6380005	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.1565
Annotation	Butrin
Peak:m/z	Relative Intensity
189.9719238	0.05
191.0833130	0.11
195.1868286	0.04
227.3005676	0.07
255.2453003	0.08
258.3035889	0.07
259.2184448	0.05
266.2979126	0.06
270.1784668	0.09
270.9833069	0.33
271.8865967	0.15
272.8693848	0.09
274.0405884	0.09
275.2282715	0.12
277.1993713	0.05
283.4075012	0.22
285.0928345	0.30
287.0759277	0.89
289.2339478	0.06
295.1000977	0.05
299.3559570	0.49
301.0815430	0.51
302.2688599	0.47
304.9846802	0.24
313.9674683	0.07
315.1459961	0.23
316.1743774	0.55
323.2597656	0.05
328.1965332	0.06
329.1451416	0.40
330.2130737	7.04
331.2091980	2.81
342.7341309	0.04
345.0551758	36.72
345.8410645	0.07
349.1271362	0.11
357.4178467	0.09
358.3059082	0.07
360.1631470	0.11
367.2067871	0.03
373.3422241	0.03
382.5328979	0.05
394.8904419	0.12
403.2368774	0.06
455.3988037	0.07
456.1325684	0.10
459.6565552	0.04
463.2824097	0.04
465.2708740	0.05
470.4212036	0.04
475.1893311	0.23
489.5136719	0.05
491.2563477	0.10
491.9494019	0.06
493.2073975	6.86
493.8423462	0.01
501.3045044	0.04
507.2631836	100.00
509.4132080	0.11
513.3076172	0.17
519.1823730	0.07
523.2156372	0.05
525.1763306	0.09
525.8663330	0.41
529.9221802	0.12
534.6829224	0.45
535.3145142	5.84
547.5412598	0.03
549.2232056	58.74
549.8359375	0.09
554.8453369	0.03
557.3925171	0.11
563.3406372	0.04
575.3317261	2.04
577.2167358	0.99
581.0136108	0.06
584.3089600	0.03
589.2138062	19.10
589.8404541	0.10
591.3276978	0.45
600.6579590	0.23
601.2927246	3.04
606.3789062	0.12
609.3826904	0.27
612.3502808	0.07
614.1656494	0.23
618.1870117	0.07
623.2868042	0.08
626.0117798	0.11
628.4005127	0.09
629.1081543	0.10
632.4429321	0.38
633.3358154	1.17
651.3485718	1.13
652.4893188	0.59
656.2009888	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.21
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2951660	0.05
251.2680969	0.10
317.2186890	0.12
323.1940613	0.71
340.6041260	0.30
383.1674194	3.80
383.8521118	0.04
384.8945312	0.17
412.6329346	0.47
443.0145874	2.14
452.0318604	0.06
471.1755981	0.15
473.2533569	0.29
494.9019165	0.08
503.2138062	100.00
503.8421631	0.51
550.8461304	0.08
616.8118286	0.57
635.4087524	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.2029
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
217.0518799	0.04
243.4272614	0.05
298.3045349	0.02
311.1862793	0.02
312.9810181	0.15
314.4018555	0.13
329.0321045	0.05
339.3641968	0.04
340.8600464	0.02
349.5744019	0.05
364.9477539	0.07
371.2537842	0.01
381.0919800	0.08
395.5171509	0.05
407.4438477	0.03
411.2897339	1.86
415.2568359	0.11
421.4253540	0.07
428.6516113	0.09
429.3624268	0.01
439.4154053	0.08
443.2704468	0.11
444.8159790	0.03
457.4855347	0.03
461.5717163	0.02
469.2568970	100.00
473.4112549	0.07
487.1342773	32.15
491.3892212	0.07
514.6215820	0.04
516.2145996	0.03
518.0692749	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	575.2135
Annotation	Saframycin Ad 1
Peak:m/z	Relative Intensity
164.9521637	0.02
193.1398163	0.06
198.8348083	0.03
233.2980957	0.05
243.0887299	0.03
245.4781036	0.11
257.2512817	0.03
267.5257568	0.05
284.0473938	0.03
285.4284668	0.02
301.2338257	0.15
302.3707581	0.02
306.1826172	0.03
315.9710083	0.03
329.1447754	0.15
334.3074951	0.04
337.2124634	0.03
339.3848877	0.02
341.5048828	0.12
343.1989746	0.05
344.0687866	0.03
359.0274658	0.42
367.2321777	0.10
369.0840454	0.03
380.9831543	0.04
384.9884644	0.02
393.1501465	0.02
395.3255615	2.47
399.4300537	0.05
401.4477539	0.08
408.4580688	0.08
411.9953613	0.04
425.2277832	0.06
427.1092529	0.20
428.0858765	0.12
431.2703247	0.07
441.2553101	0.11
450.3203735	0.12
451.2810669	0.05
452.2734375	0.10
453.2772827	0.29
455.3399658	0.49
459.1939087	1.04
465.5875854	0.04
469.3159790	1.92
470.4062500	0.38
471.4346924	1.70
473.5867920	0.15
483.2787476	6.73
483.9223022	0.03
485.3599854	0.04
486.4835815	0.02
487.2598267	0.37
487.9699097	0.03
489.3865356	0.14
490.3200073	0.04
491.7536011	0.08
495.4456787	0.21
496.2642822	0.07
499.3262939	0.07
503.5723267	0.05
513.2766724	100.00
515.2843628	0.18
528.3441162	0.08
529.1932983	0.07
531.0299683	2.78
531.6722412	0.02
538.0549927	0.02
539.2573853	0.03
542.4628906	0.09
543.3666382	0.04
546.3987427	0.03
547.2218628	0.04
555.4411621	0.05
557.0358887	0.10
557.7294922	0.02
560.1972046	0.04
576.1394043	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.1229
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
258.9607544	0.02
301.1347046	0.53
302.1541138	0.16
307.4129028	0.03
313.2117310	1.04
314.2236328	0.52
325.2841797	0.47
326.1477051	0.10
337.2993774	0.01
338.2628784	0.02
339.2279968	0.03
341.4459839	0.03
343.1621094	22.93
344.1639099	5.64
367.2034302	18.21
368.2883301	6.60
373.1961670	0.10
374.1469421	0.11
379.2790222	0.16
380.2622070	0.05
381.0713806	0.07
385.3322144	0.09
391.2078552	0.07
392.4529114	0.07
397.1546326	38.25
398.1946716	14.24
400.2388611	0.06
409.2178040	10.29
410.2622375	4.21
427.1684265	18.64
428.2467346	6.42
445.1584778	100.00
446.2371521	26.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0854
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.92640686	1.02
78.98181152	0.32
82.88497925	0.29
95.0635376	0.72
102.9825745	2.69
104.0202942	0.33
104.9551086	1.15
106.9107819	1.24
107.8713379	0.64
109.0553436	0.19
115.1268768	0.07
119.0615997	0.78
120.939209	0.56
123.0071564	0.64
124.893158	0.39
128.3791046	0.11
128.9861145	10.11
130.04776	1.14
130.9647064	0.65
141.0220795	0.48
142.1490326	0.46
142.9640045	0.11
145.1415558	0.19
147.0265656	0.66
148.2117004	0.26
150.9347839	100.00
151.9450226	14.04
153.0229034	0.36
154.8817291	1.27
156.916748	0.62
158.0466156	0.41
164.8967438	0.91
165.9866943	1.09
167.0952911	3.70
169.1035156	0.80
170.0213165	0.43
171.0329437	0.16
178.5486298	0.56
179.2007294	1.08
179.9011383	0.18
182.0637207	0.39
182.8742065	0.61
184.1096191	0.12
185.1586456	3.59
185.9824829	0.21
189.2544098	0.11
192.1385956	0.30
194.1198425	0.42
195.92099	0.13
197.1860962	4.27
198.1338959	0.72
206.160202	0.34
207.1752167	0.51
207.9113922	0.47
210.1849976	1.11
211.5036469	1.14
212.3817596	0.10
218.202713	1.08
225.0752106	8.90
226.0808563	4.01
234.9418335	0.49
236.2617188	0.22
237.3501434	1.34
238.0438995	18.07
239.0877228	1.51
240.045639	0.70
251.0883179	3.45
253.0908051	74.11
254.15625	13.06
255.2052765	1.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1130.5742
Annotation	Unknow
Peak:m/z	Relative Intensity
820.2867432	0.11
820.9954834	0.11
874.4796143	0.11
1130.4521480	100.00
1131.1887210	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	803.3708
Annotation	REBAUDIOSIDE B
Peak:m/z	Relative Intensity
329.0753479	12.26
497.4353638	2.70
701.5574951	2.03
728.0612183	5.13
771.4938354	3.66
803.3621216	100.00
804.2678223	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	597.18
Annotation	Butrin
Peak:m/z	Relative Intensity
179.0161743	0.09
196.1956482	0.05
211.0440674	0.04
219.1987000	0.02
220.1460571	0.13
231.0801086	0.14
237.1249084	0.04
241.1408234	0.09
242.1112671	0.14
243.0975342	0.14
245.0911713	0.17
245.9399414	0.05
250.3164520	0.20
253.2458649	0.19
253.8489838	0.13
261.1931763	0.17
262.1988525	0.05
267.1712036	0.05
267.8435059	0.07
271.5734863	0.10
274.1521912	0.12
274.9495544	0.05
280.2041626	0.03
287.1184692	87.19
288.1209717	100.00
289.1589966	13.80
297.1130981	0.08
298.3500366	0.08
299.3209229	0.05
301.1608276	0.66
302.2084961	0.69
303.0032959	0.30
313.2977905	0.07
314.1845093	0.13
315.2740479	0.09
322.4331665	0.04
325.2362671	0.26
326.1415405	0.47
329.3936157	0.08
330.3025513	0.13
331.6370850	0.03
336.1072998	0.07
339.0334473	0.13
341.2863770	0.09
343.3112793	3.15
344.1646729	3.89
345.2058716	0.81
348.1860352	0.52
354.2720947	0.02
355.2453613	0.24
357.1797485	0.05
359.3424683	0.03
360.2977295	0.14
367.1749878	0.39
368.1477051	0.88
369.1552734	0.36
374.2421875	0.02
379.0866089	0.42
380.4099731	0.06
381.3106689	0.04
382.0670166	0.08
383.5258789	0.30
385.6472168	0.07
389.4127808	0.06
390.0210571	0.07
391.9130249	0.10
397.1499023	0.72
398.2660522	1.42
399.2624512	0.35
401.1961060	0.08
407.0846558	0.07
410.3212280	0.51
411.3385620	0.26
414.2169800	0.32
416.2984009	0.12
417.3543701	0.26
421.2723999	0.13
422.1594849	0.07
427.1535034	0.42
428.1422729	3.12
429.5290527	0.37
430.1328125	0.06
431.1555176	0.20
432.2263184	0.76
433.2873535	0.19
434.1975098	0.80
435.3026733	0.17
440.1344604	0.05
441.8323364	0.13
443.1310425	0.07
445.2519531	3.09
446.2545776	9.21
447.2044678	2.04
449.1275635	6.95
450.1390381	23.07
451.2370605	5.15
453.2018433	0.03
456.2682495	0.07
457.1054077	0.17
458.3084717	0.82
459.1426392	0.19
463.2702026	10.79
464.2052612	29.30
465.2977905	6.89
467.2472534	0.26
475.3307495	0.45
476.1555786	1.42
477.0938110	0.21
481.6425171	0.10
492.0915527	0.33
499.2570190	0.26
500.0963135	0.05
501.2185669	0.08
506.6900635	0.23
512.3950806	0.21
521.5657959	0.07
525.2786865	0.03
530.1282349	0.19
534.4489746	0.04
535.2722778	0.10
536.3848877	0.05
538.9938354	0.31
542.6046753	0.17
543.2626953	0.05
544.2896118	0.08
547.2901001	0.09
551.3498535	0.12
552.5647583	0.24
558.7118530	0.15
560.4158325	0.58
561.3222046	0.44
578.2487793	3.24
579.2354736	0.88
608.4594116	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1431
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
76.9706802	0.08
78.8457413	0.04
80.9293213	0.17
83.0103760	0.06
85.1004028	0.01
91.1571960	0.05
93.0269623	0.21
94.9327927	0.66
97.0076370	0.58
98.9390717	0.27
103.0795746	0.02
104.9981995	0.07
107.0314941	0.34
109.0271606	1.74
110.9546356	1.17
112.9676514	0.48
114.1244812	0.03
115.0945740	0.04
119.0062408	0.98
121.0016785	1.28
123.0149231	0.41
125.0331116	0.29
126.7164459	0.20
128.9068451	0.06
131.1129913	0.02
132.9803467	0.38
134.9787292	5.76
137.0601501	3.21
138.8983154	1.30
140.7991333	0.04
142.9759674	0.17
145.1105042	1.11
145.9633636	0.04
146.9652405	1.13
149.0034485	0.81
151.0724640	0.39
152.1278839	0.02
153.0847321	0.04
155.0614929	1.17
157.0188446	4.50
159.1238251	2.66
161.0358276	3.30
162.4751740	0.14
163.0881195	0.45
165.0629730	2.61
167.3186340	0.05
169.2879791	0.11
171.0667877	0.57
173.0990906	2.33
175.0032043	11.65
177.1311493	0.31
179.0531464	0.05
183.0919037	0.59
185.1670990	1.47
187.1342316	5.96
187.9985352	0.05
189.0877533	2.56
190.7554169	0.32
191.4300537	0.01
193.0742798	6.07
194.9430084	0.04
196.1283417	0.05
199.1965637	0.77
201.1055450	5.55
203.0607452	13.08
205.1145782	2.02
205.8952484	0.09
207.1370850	0.78
211.0360413	3.72
214.1572113	0.11
217.0814667	10.09
219.1138306	4.67
221.1751709	0.77
223.6790924	0.02
229.0628662	11.40
229.6900177	0.13
235.0219727	6.60
235.6666718	0.07
236.3166351	0.03
243.2616730	0.07
246.9807281	100.00
247.7546844	0.23
248.3632355	0.09
253.0548706	0.14
265.2901001	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	767.2424
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
255.2292023	0.15
256.0744324	0.39
282.9413452	0.14
284.0800171	1.23
299.1611328	8.02
304.9270935	0.12
309.3009644	0.08
313.0389404	0.05
321.3734436	0.13
341.0842896	2.27
344.2710266	0.14
371.3521729	0.07
381.0253296	0.07
383.0435181	0.21
407.2895508	0.23
415.2656860	0.08
443.5267334	0.06
446.2720337	0.55
461.2762451	32.53
503.2380371	11.66
503.8502808	0.09
519.0516357	0.07
520.8176270	0.03
527.4107666	0.17
533.5857544	0.36
543.3097534	9.02
545.2390137	1.03
563.3948364	0.05
587.3728638	0.08
604.4511108	0.07
605.1972046	3.93
611.2254639	0.17
613.2769165	0.22
615.7195435	0.04
623.0291138	0.14
623.7128296	0.03
635.3778687	0.10
647.2323608	0.28
677.2199707	0.20
681.0082397	0.09
689.1603394	0.04
707.3506470	0.36
723.3715210	0.05
733.2590332	0.14
749.1163940	0.26
767.2639771	100.00
768.5944214	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	429.1613
Annotation	Unknow
Peak:m/z	Relative Intensity
152.0357971	1.33
168.1033630	0.07
178.0573425	0.06
190.9499054	0.16
196.2976532	0.04
220.9834290	0.12
222.2156067	0.04
223.2211914	0.25
232.0131989	0.05
237.0589905	0.06
248.3682251	0.17
249.0603638	1.02
260.0346069	0.14
267.1723633	1.50
272.9248657	0.11
279.0549927	0.07
280.9503479	0.13
311.2227173	0.08
312.1955261	0.06
338.9990845	0.18
341.2004395	0.68
342.0704346	0.16
343.0178223	0.51
345.2975464	0.04
365.2889099	0.07
366.3995056	0.21
369.2165527	0.36
383.2119446	100.00
384.0582581	0.14
385.6999207	0.04
399.3110657	0.07
408.2208252	0.32
410.0976257	0.02
411.2474060	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.17
Annotation	Ethotoin
Peak:m/z	Relative Intensity
115.9246674	0.61
125.0828552	0.31
128.9255066	0.06
130.0487976	0.09
131.9498291	0.11
133.0164185	0.07
134.5283966	0.03
135.9258575	0.06
142.1086731	0.91
143.0778961	0.03
145.2104797	0.04
151.0226135	0.15
157.0414276	0.04
159.1057281	2.51
161.0399475	0.72
163.1611938	0.02
164.0673676	0.04
167.0085754	0.07
172.4434509	0.18
173.1632080	0.05
178.9347382	0.76
181.0169678	0.13
183.2079163	0.05
185.0348969	0.16
186.1260223	0.05
187.1359406	0.11
191.1049805	0.10
197.0162659	0.13
198.1753845	0.04
199.0559387	7.14
203.0481415	100.00
207.1571808	0.15
209.1994171	0.28
213.4169769	0.04
217.0453033	0.03
223.1795044	0.23
227.0185547	0.87
234.6749573	0.31
235.3476868	0.03
239.0603943	0.14
241.1433105	0.62
245.3293762	0.48
257.2244263	0.22
259.2479553	0.12
260.0686951	0.03
261.0440369	0.25
263.3682251	0.02
264.1220398	0.04
265.1868591	0.02
269.3026123	0.13
270.8890381	0.04
275.2739868	0.14
283.3488464	0.04
284.0492859	0.03
288.3848877	0.02
290.1853027	0.14
299.1162720	0.20
301.0904846	0.36
303.1211548	0.04
305.2161865	0.12
316.3961792	0.14
317.2954407	0.10
319.2346191	0.64
320.2597656	0.36
321.2168884	0.18
325.3837280	0.03
330.9501953	0.10
342.9942627	0.13
344.2777405	0.14
345.6537170	0.10
347.1759644	9.43
358.2674255	0.03
361.0455322	10.10
361.6863708	0.10
362.5036011	0.18
363.2251892	0.46
364.4680481	0.03
365.2978516	1.59
371.1430969	0.06
372.5850220	0.03
375.1846313	0.04
376.2952881	0.09
377.4335022	0.06
379.5594482	0.05
386.4937439	0.06
388.3628235	0.24
389.1947327	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1069.5222
Annotation	Unknow
Peak:m/z	Relative Intensity
305.1614990	0.09
335.4733276	0.10
351.2836609	0.06
390.4859619	0.03
407.2179260	0.05
444.4202881	0.04
452.5143433	0.06
492.0817871	0.07
506.5260010	0.08
532.4884644	0.13
535.3970947	0.05
553.0889893	0.04
554.9249268	0.19
599.2284546	0.09
600.3748779	0.18
604.4031982	0.14
614.5146484	0.23
632.5399170	1.71
647.2409668	0.13
658.0612793	0.08
674.4286499	0.11
675.2858887	0.17
683.8709717	0.22
685.4111938	0.40
703.5319824	0.20
711.4545898	0.16
712.7112427	0.13
723.4055176	0.29
734.7974854	0.11
743.8740234	0.07
760.0304565	0.05
761.7202148	0.02
767.5530396	0.30
769.6532593	0.06
778.4916992	9.98
779.3458252	0.02
795.1503906	0.05
802.7836914	0.24
813.8836670	0.07
820.5152588	0.23
832.2763672	0.83
832.9500732	0.20
842.5234375	0.03
868.5200195	0.31
886.7380371	0.03
889.5952148	0.87
904.7377930	0.13
907.4704590	8.54
908.4738770	0.17
911.0119629	0.20
940.4176025	4.00
949.9555664	0.03
967.9006348	0.06
985.7153320	0.04
994.6237793	0.52
1069.6702880	23.88
1070.5268550	100.00
1071.2825930	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	885.2268
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1116638	0.18
246.4604034	0.02
255.3111115	0.05
259.1883240	0.06
268.7943420	0.02
269.9612427	0.04
271.2262268	0.12
271.9890747	0.02
273.0407715	1.31
274.1155396	0.10
283.5660400	0.04
284.9367676	0.06
287.1819458	0.07
288.1093140	0.05
289.0976562	0.08
299.1968384	0.01
300.4270020	0.22
301.1351624	1.89
302.1968994	0.02
313.2175598	0.10
316.0847778	20.12
317.2467041	0.98
325.9380493	0.02
328.1358337	0.01
331.1056519	100.00
332.1125793	5.08
332.7606812	0.02
354.1333008	0.01
355.2868652	0.08
371.2527466	0.07
373.1281128	1.18
374.0149841	0.10
397.3529663	0.03
398.3906860	0.01
403.1833496	0.03
411.4744873	0.06
416.7930298	0.02
418.1838379	0.07
421.0977173	0.03
439.5747070	0.06
451.3447876	0.02
475.7166138	0.02
493.1187134	0.86
494.3078003	0.05
495.8176270	0.02
499.2166748	0.02
517.3171997	0.24
518.1305542	0.04
535.1029663	0.18
535.9635620	0.02
557.2716064	0.02
561.1647949	0.48
562.0469971	0.05
575.1610718	0.24
579.0928345	12.89
580.0739746	0.69
580.7578735	0.01
583.1707153	0.03
601.7496338	0.07
602.5551147	0.04
610.2702026	0.09
619.2302246	0.65
637.1687622	29.34
638.3002930	1.22
643.4642334	0.07
661.5905151	0.04
706.3287354	0.02
733.6140747	0.02
741.0775146	0.13
745.5112915	0.03
781.1054688	0.05
799.2295532	0.46
805.5481567	0.06
823.2941284	0.38
840.3309937	0.01
841.3191528	0.33
842.4697876	0.03
867.2366333	1.48
868.2221069	0.20
886.2476807	19.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1329
Annotation	Oenin
Peak:m/z	Relative Intensity
266.8386230	0.01
301.4073792	0.02
316.2978821	0.07
331.1373901	100.00
331.9232788	0.02
355.2566528	0.02
373.2110596	0.39
373.8451538	0.01
397.1813965	0.10
400.4479065	0.01
409.3067627	0.02
427.1235046	0.11
439.1683655	0.03
448.1602478	0.03
457.1864319	0.19
474.6486511	0.09
475.3473816	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	293.2104
Annotation	13-epi-12-oxo Phytodienoic Acid
Peak:m/z	Relative Intensity
90.98124695	0.03
93.0354538	0.07
95.14254761	0.05
98.9912262	0.03
100.8704147	0.03
104.9496384	0.10
107.0197525	0.15
108.9816971	0.07
119.1056519	0.10
121.1619873	0.04
123.1205978	0.04
125.0944672	0.09
127.1250153	0.03
130.950592	0.62
133.0812073	0.48
135.0820007	0.04
137.0310059	0.09
141.130249	0.02
143.0700073	0.14
145.0388794	0.73
146.9699707	0.97
148.8733215	0.07
151.0368347	1.46
153.0210571	0.06
154.9884949	0.20
157.1845245	0.40
159.1177826	0.34
161.081604	0.42
163.0844727	0.40
165.0832062	0.06
166.9618835	0.08
168.9098816	0.12
171.0635986	0.40
173.04422	0.28
175.0500946	0.49
177.0193329	0.21
179.0985107	0.17
182.9407043	0.05
186.9521637	0.28
190.8625183	0.07
193.1900024	0.09
197.1951599	0.12
198.9785461	0.15
201.217926	0.32
203.0326233	0.02
205.0073853	0.41
207.1478577	0.14
208.1529846	0.07
209.0868835	0.04
213.1101074	0.15
215.1462402	0.72
217.1552429	0.12
219.1400146	0.77
222.0079041	0.04
223.1292419	0.01
229.2257996	0.31
231.3577881	0.33
233.2886658	0.16
235.2431641	0.13
237.0393677	0.53
239.2502441	1.23
243.2879639	0.08
245.3370361	0.03
247.2205811	0.46
248.999939	0.35
251.3807373	0.15
257.2001648	7.47
258.133667	0.04
262.4973755	0.06
265.0960083	0.19
275.2030334	100.00
278.1676331	0.15
279.4442749	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Zinc protoporphyrin-9
Peak:m/z	Relative Intensity
204.8284302	0.06
217.1180115	0.02
225.9843750	0.04
237.1243896	0.07
245.3085938	0.02
252.9976349	0.13
258.0147705	0.27
259.1886597	0.02
270.8078613	0.12
272.0926819	0.07
286.1475830	5.85
289.2322388	0.06
298.0351868	0.08
299.1371460	0.20
299.8143921	0.11
301.1165161	100.00
324.9069824	0.12
328.2219238	0.04
330.9396973	0.01
343.3151855	1.00
354.2279053	0.03
359.1714478	0.09
362.4179688	0.20
363.3069458	0.03
367.2046509	0.10
376.2169189	0.14
396.8875122	0.05
409.1939087	0.40
427.3798218	0.05
430.0855103	0.02
445.1778564	0.14
454.1180420	0.02
456.7391357	0.07
462.9803467	0.05
472.5119629	0.08
503.3931885	0.06
509.2539062	0.02
520.4544067	0.07
523.9554443	0.04
535.1379395	0.02
545.2202148	0.88
546.0239868	0.04
552.9337769	0.10
571.1712036	0.42
589.2764893	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	443.1771
Annotation	Unknow
Peak:m/z	Relative Intensity
143.2298279	0.04
164.1631470	0.03
164.8701172	0.06
169.7893829	0.03
187.1707458	0.04
191.2392883	0.06
209.0368347	0.08
215.5453491	0.05
217.7400208	0.02
227.1038208	0.02
234.0959167	0.04
239.0284424	0.07
255.1405029	0.06
257.2841797	0.06
262.4638062	0.04
263.0943909	0.07
265.0361328	0.14
268.1316833	0.03
272.2186890	0.06
278.0260010	4.75
279.0767212	0.12
279.8587646	0.09
287.2723389	0.11
289.1183472	0.16
304.0029297	0.06
306.1642151	0.66
307.1137390	0.16
307.7765808	0.02
321.2678833	0.06
322.3610229	0.02
339.0712891	0.07
342.1858826	0.04
343.0675964	0.05
344.2118835	0.02
347.2438354	0.06
351.1481934	0.06
355.4031677	0.07
368.9625854	0.07
380.3656006	0.57
381.2672729	0.10
383.5390930	0.05
385.1716614	0.04
389.1210632	0.11
392.1435242	0.02
397.1980896	100.00
397.9311218	0.30
398.8783264	0.25
407.4920349	0.08
424.0875244	0.05
425.1797791	0.35
425.9858704	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2251
Annotation	Lactulose
Peak:m/z	Relative Intensity
281.0490112	0.05
341.1080322	100.00
683.0040894	17.39
683.7119141	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1297
Annotation	Arborescoside
Peak:m/z	Relative Intensity
112.9713287	0.12
118.9011536	0.16
131.0291901	0.09
134.9721375	0.15
143.0717926	0.18
146.0211945	3.94
148.7285461	0.41
160.9767914	2.50
163.9443970	5.18
179.0505676	100.00
191.0368195	0.26
193.0229950	0.17
207.0289917	2.56
211.0014954	0.18
340.8053589	10.57
341.4936523	0.17
369.2176514	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1111.2903
Annotation	YGM 3
Peak:m/z	Relative Intensity
315.1788025	0.05
316.1355286	0.09
328.0224609	0.05
331.1870422	1.06
337.3684082	0.03
343.1718445	0.09
345.9488220	0.02
352.1900024	0.02
357.4392090	0.01
361.2442932	0.87
362.6696777	0.01
366.4042664	0.02
373.1758118	0.02
379.0969238	0.02
380.8456421	0.02
385.2157898	0.02
391.1088257	0.02
393.0983887	0.01
396.4743958	0.03
397.2114868	0.01
407.3932495	0.03
409.3081665	0.19
415.4746704	0.03
421.1550293	0.06
433.2390137	0.02
435.2998657	0.02
439.1580200	0.15
451.4998169	0.01
457.2420044	0.01
469.3858032	0.06
511.3005981	0.01
515.4923706	0.02
517.5028076	0.04
535.3897705	0.04
547.1340942	0.08
553.1633301	0.02
559.3304443	0.04
565.2802734	0.01
571.4119873	0.03
575.1882935	0.09
583.3779907	0.02
589.2342529	0.06
601.3562012	0.01
605.3228760	0.06
607.4562988	0.04
619.3704834	0.06
631.2879028	0.03
633.3648682	0.05
637.1146240	0.04
642.9025879	0.01
649.2232666	0.03
665.5251465	0.01
667.4932861	0.07
678.9935913	0.02
683.5033569	0.02
691.3796387	0.02
697.2790527	0.06
698.9978027	0.01
709.5659180	0.05
715.3245850	0.31
717.4518433	0.01
727.4036865	0.28
732.4439087	0.06
733.3189697	0.09
739.2951660	0.04
745.3187866	0.61
751.3040771	0.13
757.3115845	0.03
763.2196655	0.19
763.9128418	0.04
775.2673340	0.24
781.2407227	0.19
793.2187500	0.04
811.0634766	0.13
1093.2270510	0.03
1111.1390380	100.00
1112.3413090	5.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	940.48
Annotation	Hoiamide B
Peak:m/z	Relative Intensity
319.2754517	0.14
323.0906067	0.42
457.5592651	1.60
550.9176025	0.89
596.5595093	0.15
621.5717773	0.21
673.3766479	0.27
689.421936	0.68
731.4899292	0.12
743.6578979	0.42
765.7219849	0.40
778.5709229	4.20
904.5200806	0.42
923.7333374	0.48
940.4311523	100.00
941.1381226	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	235.1434
Annotation	Lenacil
Peak:m/z	Relative Intensity
69.9646530	0.16
71.8748322	2.84
88.9698181	2.95
95.0408020	0.04
97.9838562	0.99
106.9511108	0.05
113.9151306	5.92
114.9791870	2.80
120.9577942	0.02
121.9134216	1.55
122.5428009	0.02
140.8897858	0.05
146.9747772	11.01
163.8695831	0.05
176.0496368	6.38
179.1558838	0.03
193.1226196	0.27
218.0778046	100.00
218.6931305	0.35
226.0242310	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	938.4691
Annotation	Unknow
Peak:m/z	Relative Intensity
274.2459717	0.01
304.8543701	0.03
495.3066406	0.02
505.0627441	0.06
563.6069946	0.03
591.5557861	0.04
890.4869995	0.07
905.3092651	0.03
919.6635132	0.06
938.5126953	100.00
939.1897583	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.22
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
223.0035248	0.01
227.1202087	0.06
228.0592041	0.01
233.0556793	0.01
234.3124695	0.01
235.1305389	0.04
236.3973541	0.05
241.0656128	0.01
243.1016388	0.01
245.4279633	0.01
250.8549500	0.02
251.9937134	0.02
253.4242859	0.01
254.3243256	0.03
259.1363831	0.05
260.1411743	0.01
267.0575256	0.03
269.2005005	0.13
270.0219727	0.02
271.1286621	0.11
272.3995361	0.01
277.0276489	0.04
287.1850891	1.44
288.1216125	0.17
295.1898193	0.14
296.2787170	0.03
297.2752686	0.06
307.3927002	0.02
311.1186218	0.07
313.1525269	0.04
323.1970825	0.04
325.4133301	0.03
327.1240540	0.01
329.2996826	0.21
331.2094727	0.43
332.2289429	0.06
339.2601318	0.05
341.0179443	0.02
345.2826538	0.04
347.5534058	0.02
351.3083496	0.01
353.2162476	0.03
357.3578796	0.10
358.6917114	0.02
359.3045654	0.11
360.3050537	0.01
367.4195557	0.02
371.0067139	0.01
373.1598511	0.01
383.1477661	0.03
389.4088135	0.01
397.0613403	0.01
402.4100342	0.02
405.2822876	0.03
413.3641357	0.05
415.4091797	0.04
431.1492310	0.16
433.3101807	0.19
434.3276367	0.02
441.3640747	0.38
442.1520386	0.06
443.4365234	0.06
447.1165771	0.04
449.3305664	0.09
450.1915283	0.01
451.4636230	0.01
457.2867432	0.13
459.2602539	1.45
460.2864990	0.38
465.7521973	0.01
469.6279297	0.01
470.4387207	0.01
475.3876953	0.07
477.3091431	3.69
478.2694702	0.58
478.9024658	0.01
483.4332886	0.05
484.3038330	0.02
485.6489868	0.02
487.4678345	0.09
493.5268555	0.07
499.2212524	0.06
501.3558960	0.22
502.5056763	0.12
505.2410889	0.03
506.2785645	0.01
514.4064331	0.01
517.3400879	0.08
518.6748657	0.13
519.3468018	0.01
529.1525269	0.02
531.3715820	0.90
532.3976440	0.06
534.3065796	0.01
543.5574341	0.10
549.3859253	0.05
557.3848267	0.08
559.1751099	0.25
560.7523804	0.27
561.3765259	2.03
562.3810425	0.58
568.3242798	0.03
573.5528564	0.04
577.3322754	1.45
578.4505615	0.16
582.4998169	0.03
585.2955933	0.21
586.2610474	0.06
587.4358521	0.07
591.2592163	0.04
593.2288818	0.02
595.3298340	6.87
596.4506226	1.69
600.9159546	0.02
603.3111572	1.61
604.2856445	0.43
605.4176636	0.27
606.4788208	0.12
611.7402954	0.03
613.1580200	0.01
619.4786377	0.03
621.3215942	100.00
622.3513794	21.57
631.3689575	0.13
632.5321045	0.01
635.4055176	1.36
636.4161987	0.11
637.3160400	0.51
638.2366943	0.09
647.2265015	0.39
648.4603882	0.10
665.4033203	0.01
668.3640747	0.02
671.3702393	0.02
696.7514038	0.03
711.4980469	0.01
713.5197144	0.03
721.3481445	0.41
722.4634399	0.07
737.3793945	0.12
739.3762817	2.48
740.3941650	0.71
758.3349609	26.81
759.0382690	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.24
Annotation	O-Apiosylverbascoside
Peak:m/z	Relative Intensity
214.1146240	0.03
215.0829773	0.02
223.9914703	0.06
225.0281372	0.05
226.3157654	0.16
227.1810913	0.50
230.0839996	0.10
233.0515289	0.12
239.0226440	0.12
240.0818481	0.12
241.0667419	0.34
242.0411835	0.40
253.1084290	0.10
255.1243439	0.07
256.6470337	0.10
257.2489929	0.65
258.1038208	0.32
264.0117798	0.03
265.1122437	0.06
267.3214722	0.05
268.1565552	0.15
268.9860229	0.06
271.2316284	0.03
275.1386719	0.03
280.1421204	0.11
281.1287842	0.04
283.1311035	0.73
284.3340759	0.62
285.2576904	0.31
286.1482544	0.97
287.0599976	0.12
292.0687256	0.04
293.0557251	0.06
297.1326294	0.05
299.1653137	0.85
301.0864868	28.07
303.0310059	0.03
307.2409058	0.33
309.2151794	0.05
310.1296997	0.26
313.3481140	0.04
314.4181519	0.02
315.3975830	0.09
321.5965576	0.05
325.0312195	1.08
325.6446533	0.06
328.1829224	0.03
337.1828003	0.18
341.1598511	0.24
343.1963501	0.70
347.2340698	0.04
349.1196899	0.04
350.2629700	0.03
351.3400879	0.03
353.3538818	0.03
355.3288879	0.35
357.1624146	0.05
367.2521973	0.39
373.5364380	0.09
383.3557739	0.03
385.3370361	0.08
391.0739136	0.03
409.1760864	0.48
411.6888428	0.04
429.2045898	0.27
442.9306030	0.04
447.2689819	0.23
471.2321167	0.50
485.4800415	0.02
487.1595459	0.11
489.2444458	4.09
548.4660034	0.02
555.2743530	0.03
575.3460083	0.07
577.3357544	0.28
579.4525757	0.03
591.3695679	0.93
593.3745117	0.08
595.2809448	0.17
600.9896851	0.08
605.4588013	0.50
608.3630371	0.34
609.4094238	1.09
618.2813110	0.07
619.6452026	0.08
631.3956909	0.62
666.3974609	0.22
669.3380127	0.04
693.2886353	0.02
694.2633667	0.04
710.4258423	0.03
711.3574829	0.05
722.2787476	0.15
723.6607666	0.07
725.0555420	0.02
737.3058472	0.90
739.6802979	0.53
740.4100952	0.74
755.3683472	100.00
756.3853760	4.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.2029
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
133.0463104	0.05
137.0280304	0.06
139.0299988	0.32
147.0185089	0.16
148.9959869	0.50
150.8845978	0.08
153.1565247	0.06
158.1142273	0.04
159.1214752	0.11
161.1161346	0.05
163.0208893	0.52
165.1911926	0.02
172.9665527	0.19
175.1291504	0.11
177.0895538	0.24
179.2447205	0.20
185.0992432	0.12
187.0734558	0.03
189.0890198	0.27
191.0659943	0.21
192.2356262	0.04
193.2453613	0.22
197.1422729	0.10
201.0359497	0.40
203.0031128	0.06
205.1387787	0.34
213.3010559	0.06
214.0975494	0.06
215.2941437	0.07
217.3853455	0.23
219.1225281	0.14
222.9982910	0.19
225.2677612	0.34
227.2266235	0.20
229.3618622	0.02
231.0907288	0.18
238.3280945	0.07
241.1803284	0.43
242.9728241	0.35
243.5950317	0.01
245.1525574	0.20
247.1341858	0.26
248.9692078	0.24
251.3488770	0.13
253.0840454	0.26
255.2916260	0.14
257.3143616	0.33
259.1590576	4.02
261.2947083	5.29
265.3056030	0.22
267.3062744	0.10
269.2153931	5.27
271.2841492	0.31
271.9773560	0.21
273.1299744	0.30
275.3677368	0.29
277.2636719	0.19
283.4411621	0.15
284.2690735	0.04
285.2510986	0.69
287.3007507	8.27
289.2421875	0.30
291.2489319	0.24
295.2173157	0.25
297.1058044	0.07
298.2446594	0.03
299.2719116	0.44
301.0972900	0.12
302.7656250	0.11
303.3743591	1.85
307.3287354	0.24
311.4525452	0.25
313.3244629	10.06
315.2168579	0.17
317.2479248	3.41
319.3645630	0.67
321.4234619	0.11
325.3459473	0.91
327.4429932	0.15
329.3022156	0.96
331.2462769	100.00
333.3133545	0.05
336.2578125	0.05
339.3805847	0.14
341.2648926	0.44
347.3155518	6.09
351.2108765	0.51
352.9024658	0.04
355.3778076	0.51
357.3211670	0.12
359.3076782	1.72
362.2796021	0.10
365.4953003	0.31
366.3319092	0.04
367.3232117	0.07
369.2027893	0.38
375.2398987	1.13
379.6625061	0.02
381.6012878	0.14
383.5725403	0.26
386.2464905	0.04
391.4417725	0.16
393.4012146	0.04
397.2944336	0.07
409.2966003	0.07
415.0905762	0.02
425.1261292	0.12
426.3311462	0.03
427.3322449	1.79
435.4928894	0.10
443.3639221	0.15
453.3315735	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	797.2145
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
267.3880005	0.05
284.8923340	0.03
296.1378174	0.14
299.1997070	0.56
305.0600586	0.34
313.3084717	0.28
314.2001953	0.79
315.0602417	0.08
327.0190125	0.04
329.2179871	2.95
347.2055359	0.03
356.1427612	0.04
369.1251221	0.06
371.2193298	0.49
383.2249146	0.03
393.4868164	0.03
401.1382446	0.56
413.1768799	0.06
437.1820068	0.08
445.2435303	0.06
455.3270874	0.11
476.1882324	0.20
491.3294678	5.07
517.7413940	0.07
518.4553223	0.18
533.2577515	5.72
539.5375366	0.06
558.3168335	0.03
563.3873901	1.76
573.2890015	4.99
575.2932739	0.92
586.5003052	0.03
587.1432495	0.07
599.2767944	0.23
605.3550415	0.59
615.2097778	0.02
617.2139282	0.44
617.8436890	0.01
635.2468262	2.20
638.2390747	0.07
645.0973511	0.09
653.2476196	1.39
657.2502441	0.32
659.4239502	0.09
677.3134155	0.77
681.5164185	0.04
689.2251587	0.11
690.4465332	0.02
695.3152466	0.32
707.2819214	1.10
719.1403198	0.08
734.2295532	0.11
735.1791992	0.12
736.9933472	0.33
743.2976685	0.31
766.7232056	0.03
781.4456177	0.10
797.1707153	100.00
797.8021851	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	781.2165
Annotation	Unknow
Peak:m/z	Relative Intensity
270.0523376	0.11
271.1600342	0.39
271.8034973	0.44
274.0495605	0.23
297.9601135	1.31
299.5845032	0.35
301.0949097	4.43
302.4827881	0.92
316.2548828	3.53
317.2971802	0.50
331.1158142	43.68
332.1629639	17.99
364.2884521	0.27
373.1773987	0.36
384.0269165	0.28
416.4840698	0.25
421.1995850	0.45
421.9727783	0.23
436.9843750	0.15
439.2227173	1.71
440.2406616	2.87
452.4459229	0.44
458.3019409	1.28
474.3355713	0.34
480.0292969	0.15
493.2291260	1.14
494.1400757	0.73
518.6794434	0.46
540.1243286	0.65
548.5663452	0.15
552.2734375	0.55
575.1314697	9.48
576.2268066	14.13
577.0963135	1.28
578.1497192	0.96
600.6629639	0.10
602.0500488	5.12
619.1622925	16.06
620.2400513	31.97
627.3571167	0.40
629.4756470	0.51
637.2137451	11.12
638.2293091	14.47
638.9276733	0.20
641.4886475	0.25
661.5621948	0.17
679.4801025	4.33
680.3671265	6.68
684.5334473	0.59
710.1724243	0.80
714.3474731	0.48
727.5968628	2.51
728.3686523	2.73
745.2929688	26.81
746.2830811	100.00
746.9318237	0.46
763.1834717	22.23
764.2736206	90.66
782.2715454	59.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	905.5635
Annotation	Unknow
Peak:m/z	Relative Intensity
255.2546387	5.72
391.4286499	0.07
452.3488159	54.45
452.9541626	0.38
641.4750366	0.04
785.5390625	0.09
847.7025757	0.25
904.9982300	100.00
906.3319092	1.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1797
Annotation	Spinosin
Peak:m/z	Relative Intensity
181.1388855	0.02
191.3286133	0.02
197.8217621	0.05
203.2661743	0.02
207.0414734	0.01
217.2869873	0.02
239.0202637	0.02
250.8867340	0.03
259.0261230	0.03
261.2982483	0.08
275.4083862	0.07
277.2197266	0.07
278.1348877	0.02
285.1452026	0.05
286.1102295	0.16
289.2392578	0.01
301.1043701	2.04
303.0897827	0.04
307.1174316	0.04
310.3658752	0.06
311.4139404	0.05
313.2212524	1.06
314.1198120	0.03
315.4994507	0.04
319.9655762	0.04
322.2595520	0.01
323.2126465	0.01
325.1712036	0.70
328.0543823	0.09
329.0881348	0.02
334.9786987	0.02
339.2180176	0.07
340.5364380	0.07
341.1411743	0.08
343.1937866	8.20
347.2763062	0.02
350.4055176	0.02
353.1825562	0.04
354.3051758	0.04
354.9148560	0.04
360.3449707	0.03
361.3532715	0.04
365.3751831	0.15
367.2504272	3.29
370.1141968	0.04
371.4013062	0.08
372.2522583	0.01
373.2445679	0.04
378.0592651	0.04
379.1387329	0.08
381.2351685	0.03
383.2491455	0.04
385.4374390	0.01
391.2620239	0.28
392.2943115	0.01
393.4371338	0.02
394.3933105	0.02
397.1410522	5.62
405.0885620	0.04
406.4122925	0.01
407.2534790	0.03
409.1992798	1.68
410.0947876	0.05
411.1734619	0.07
416.9133301	0.03
421.1119385	0.02
423.4563599	0.03
424.1919556	0.03
425.0905762	0.25
427.1655884	4.29
427.7853394	0.03
429.3702393	0.05
430.6195679	0.09
435.5877686	0.01
438.4660645	0.05
439.2056885	0.03
440.3126221	0.12
441.2290039	0.19
445.1787720	24.06
446.1874390	0.11
447.3936157	0.21
451.2699585	0.15
453.2325439	0.28
456.3502808	0.05
457.1315918	0.10
458.2329102	0.07
459.1696167	0.03
461.3034668	0.03
463.1855469	100.00
463.8208618	0.17
465.6157227	0.02
469.2812500	0.16
470.4406128	0.01
471.2081299	0.28
473.5173340	0.06
474.8483887	0.18
476.2616577	0.07
477.2234497	0.02
478.0245972	0.07
479.3424072	0.03
480.3637085	0.06
482.2654419	0.18
483.6179199	0.03
487.1878662	0.57
488.2339478	3.05
489.1604004	1.47
489.8558350	0.03
491.1181641	0.06
493.1657104	0.51
494.2324219	0.12
495.0437622	0.06
498.3421021	0.05
500.2386475	0.46
501.3985596	0.17
502.2742310	0.17
503.3998413	0.03
505.1525269	0.19
509.3341675	0.01
511.3303833	0.24
512.1920776	0.76
513.0503540	0.08
517.7269897	0.02
524.4849243	0.07
525.1821289	0.18
528.3718872	0.23
529.6591797	0.49
530.2855835	0.49
531.3067017	0.07
532.5340576	0.18
534.9404907	0.02
537.4113770	0.13
541.3737183	0.10
542.2298584	0.85
543.2443848	0.39
544.4739990	0.08
545.6598511	0.11
546.3359985	0.93
547.0770874	0.31
554.2376099	0.54
555.3998413	0.55
560.0992432	0.74
561.1787109	0.15
562.3229370	0.06
563.1812134	0.06
564.4525146	0.10
565.4269409	0.06
572.1624756	1.00
573.3531494	0.53
576.2120361	0.02
580.6347046	0.03
582.0801392	0.02
583.2912598	0.03
590.1864014	2.66
591.2270508	2.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	425.1668
Annotation	Unknow
Peak:m/z	Relative Intensity
124.8656311	0.01
129.0841064	0.03
139.0996552	0.03
144.0810089	0.24
148.9103088	0.20
158.8741608	0.01
160.9429321	0.01
176.7841187	0.02
179.0836639	0.07
187.2475281	0.01
191.1989136	0.03
194.0898438	0.04
198.9950409	0.07
217.0074005	0.07
220.9057922	0.05
226.9045258	0.01
231.2301788	0.05
233.1720886	0.03
235.0568237	0.01
244.2404175	0.04
245.1692810	0.07
247.0732422	0.09
250.9913025	0.10
259.1917114	0.02
260.9639282	0.09
262.5049133	0.10
263.1855469	0.49
269.2406006	0.01
275.2436829	0.05
276.1390991	0.02
282.2311707	0.03
282.9619446	0.02
285.2679443	0.04
287.4205627	0.02
289.2612305	0.02
292.5712891	0.02
293.4328003	0.02
303.3218689	0.07
308.2997131	0.03
311.0907898	0.12
318.2716675	0.01
320.0783081	0.01
322.3793945	0.01
335.1597290	0.06
338.3453064	0.09
341.3318481	0.02
351.1804810	0.01
352.8042603	0.01
362.5167542	0.01
363.5173035	0.14
365.2838745	0.05
379.1711121	100.00
379.7917175	0.64
381.4121094	0.12
384.3207703	0.03
389.3863220	0.06
395.3978577	0.26
406.6007690	0.19
407.2172852	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.1768
Annotation	Unknow
Peak:m/z	Relative Intensity
112.8692780	0.03
115.7982635	0.03
125.0623245	0.02
131.0246124	0.03
142.9524689	0.09
145.1331177	0.07
161.0673523	0.62
162.3142090	0.01
167.0609741	0.05
167.9574280	0.05
175.0963135	0.15
176.9398499	0.03
178.9467316	0.06
180.0407410	0.03
209.0167542	0.10
218.9562683	0.02
221.2092896	0.08
223.0543823	0.04
230.9913940	0.05
236.3941345	0.02
237.1517639	0.13
249.4102478	0.49
250.2062073	0.37
251.1245117	0.52
252.3445740	0.16
265.3505859	0.03
267.1891479	0.03
268.3354492	0.02
279.3691101	0.04
280.1232910	0.15
281.5370789	0.02
292.2875366	0.10
296.5655823	0.02
298.3519897	0.04
300.3543701	0.02
302.7816772	0.06
304.1313477	0.19
305.3318176	0.06
306.9771729	0.04
309.1050415	0.06
321.0832520	0.10
323.2130432	100.00
325.0234070	0.22
327.4351196	0.03
330.9818726	0.03
332.9026184	0.09
338.2178955	0.16
339.3500977	0.02
341.1333923	0.07
351.2064819	0.11
354.9574280	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1185.3253
Annotation	Unknow
Peak:m/z	Relative Intensity
328.2507324	0.02
345.3129578	0.24
360.1506653	0.07
375.0315857	0.36
376.1013489	0.14
465.4607544	0.02
620.2377930	0.04
664.4351807	0.03
724.0104370	0.06
758.6038818	0.07
775.6144409	0.06
789.5014648	0.04
790.3933716	0.15
807.6173096	0.10
808.4909668	0.67
825.3547974	0.12
826.4359741	0.23
1186.2592770	100.00
1187.2797850	11.04
1187.9533690	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.19
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
182.0358276	0.01
182.8265228	0.11
192.1630859	0.04
213.2047424	0.02
214.1670380	0.02
225.9026489	0.03
242.3053436	0.07
243.1262207	0.02
271.1589966	0.03
272.2031555	0.01
290.1371460	0.02
298.0999146	1.20
299.1733398	1.46
300.3513184	0.63
301.0981445	2.21
302.0572510	2.77
303.1563721	0.27
312.9527283	0.04
314.3756714	0.02
316.1005249	3.02
317.2265015	3.56
318.2327271	0.79
331.1497192	85.21
332.1325684	100.00
333.0961304	15.43
361.6030273	0.05
373.1004639	0.01
375.4974976	0.02
441.2795410	0.05
458.8977051	0.03
492.2592163	0.03
493.1327515	0.04
494.1362915	0.08
495.1214600	0.12
575.3765259	0.05
576.5005493	0.03
602.4458618	0.07
607.2388306	0.12
620.1304321	0.37
621.1278687	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	345.096
Annotation	Mikanin
Peak:m/z	Relative Intensity
120.7974930	0.15
124.9584808	0.02
134.8611145	0.09
170.0798035	0.02
173.0169525	0.02
180.8586731	0.05
183.0225830	0.02
194.8327026	0.03
209.0100555	0.01
227.0602417	0.87
228.1577759	0.11
243.3219299	0.03
255.1811829	0.06
256.4680176	0.01
269.1663818	0.03
270.2118225	0.06
283.0647278	1.86
284.1505127	7.84
285.0998535	0.99
286.2415161	0.01
294.0961609	0.08
294.9895935	0.14
297.1086121	18.74
298.1967468	1.52
299.0899048	0.36
301.0197754	0.18
303.3953247	0.03
310.0420837	0.02
312.0739746	44.38
313.1011047	3.85
315.0732422	50.80
316.1782837	4.05
317.1258240	0.05
322.7352295	0.06
326.5535278	0.45
327.2200928	1.41
328.2427063	0.17
330.0927124	100.00
331.1182861	8.08
345.2406921	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1733
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
194.7536316	0.07
208.9939728	0.03
257.2428589	0.12
266.9322815	0.06
270.4047241	0.08
282.7993164	0.03
296.1179199	0.05
298.3005371	0.03
301.1015625	0.15
305.1332397	1.62
311.0717773	0.04
314.0233765	0.08
315.2038574	0.33
325.4931030	0.03
326.2194824	0.03
328.0610352	0.12
329.0954590	3.77
330.1486206	0.69
339.0696411	0.05
343.1066895	1.00
344.1049805	11.05
345.2117310	1.72
353.8193970	0.07
354.4783936	0.07
357.5687866	0.43
359.1307373	43.90
359.7614746	0.10
369.1345825	0.10
372.2709961	0.27
381.3413086	0.50
386.1986694	0.28
387.2944946	0.17
396.5278320	0.06
401.1546021	4.46
410.3151855	0.22
425.1730347	0.22
443.1566772	0.16
488.0203857	0.16
503.1056519	1.95
503.7357788	0.07
506.2186890	0.82
507.2241211	1.08
521.1953125	100.00
521.8690796	0.23
525.1567993	0.05
534.0927734	0.22
549.1334229	3.90
549.7749634	0.03
563.2361450	65.18
563.8414307	0.26
571.5775146	0.09
589.3549805	0.55
591.2387085	0.20
603.2747803	2.77
615.1762085	1.80
633.1448364	0.63
647.0565796	0.19
650.2964478	0.15
665.0911255	4.45
665.7196655	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1592
Annotation	Unknow
Peak:m/z	Relative Intensity
104.9601746	0.32
107.2790070	0.03
108.7297745	0.17
112.9930496	0.13
113.9846802	0.08
116.5923996	0.11
118.9416428	1.19
121.0451660	0.13
126.9136505	0.43
129.1697845	0.05
130.0108032	0.44
131.0257874	0.04
132.9464722	0.18
135.3236694	0.32
136.1126556	0.06
137.8064575	0.09
139.1222076	0.07
145.2665100	0.08
147.0858459	0.21
147.9585571	0.06
149.1155853	0.31
150.9924011	0.11
153.0431824	0.10
155.3431091	0.07
156.1409302	0.13
156.8451233	0.07
158.8388977	0.35
161.1442413	0.10
163.1044922	0.11
165.1407166	0.10
167.0945740	0.07
168.1651001	0.03
169.1287842	0.07
171.1104126	0.66
172.0178070	0.13
172.9498596	0.08
175.3396912	0.18
176.9794769	0.14
178.1711426	0.08
179.1175537	0.05
181.0049438	0.18
181.9494629	0.06
183.1341553	0.11
185.1499634	0.12
186.9426270	0.71
188.9675903	0.38
191.1209259	0.07
195.0646515	0.03
197.9706421	0.06
199.3685608	0.03
200.4684143	0.06
201.2600403	0.10
202.1056213	0.25
203.0180054	0.45
204.2927094	0.03
205.2405701	0.26
207.9284515	0.10
208.8701630	0.20
211.1040497	0.02
212.9262085	0.12
215.2368469	0.30
216.1678772	0.04
217.1455383	1.21
218.2096252	0.41
219.0546875	0.05
227.9800110	0.13
229.2101440	0.03
230.9418640	3.22
231.5797119	0.10
233.0902100	0.11
235.1873169	0.16
236.4071045	0.07
239.2732544	0.13
240.4860229	0.09
241.2669373	0.52
242.0734863	0.03
246.1235962	0.12
247.0839844	0.03
248.3680725	0.73
249.0403748	3.95
250.1355896	0.05
253.1540527	2.00
254.1906433	0.22
256.1908264	0.07
259.0762939	0.71
260.2477417	0.16
261.1944580	0.17
262.1781311	0.12
263.1639709	0.59
264.1294556	0.05
265.3327637	0.32
269.1381226	0.06
270.0977783	0.06
272.6649170	0.16
274.3723145	0.07
276.2329712	0.52
277.2628784	0.36
278.8028259	0.05
279.9020081	0.28
282.2595520	0.36
286.1699829	0.18
287.0390015	0.07
290.2554932	0.06
294.2494812	2.37
295.1790161	1.49
300.2414246	0.06
302.3037720	0.11
303.2633362	0.10
305.2464600	0.53
307.2003174	0.16
309.4142456	0.12
311.2324829	0.16
312.2831421	9.81
313.2944336	2.58
313.9432068	0.04
317.1075134	0.02
318.1984253	0.04
320.2379150	0.10
321.3990784	0.32
322.3626404	0.03
323.2056580	0.07
325.0678711	0.17
328.1408081	0.32
330.3030396	29.64
331.2642822	10.63
332.0307007	0.06
335.0757446	9.20
335.6770325	0.05
339.1928101	0.45
340.1358948	0.15
348.3605347	100.00
349.3972168	18.59
350.5938110	0.06
352.1334534	0.09
355.6350708	0.21
358.2321472	0.58
359.2469177	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.205
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
262.9389038	0.02
272.2261353	0.07
274.9500122	0.03
281.9718933	0.02
289.0968628	0.07
290.5310059	0.02
294.9664001	0.03
297.2984009	0.02
305.1949463	0.02
306.2358093	0.06
311.2329102	0.04
322.9529419	0.02
325.2143555	0.22
337.2062378	0.04
341.4013672	0.03
348.9353333	0.10
350.9595337	0.07
352.0417786	0.09
353.1995850	2.24
365.3345947	0.11
372.0485840	0.02
377.4078979	0.07
379.0777588	0.02
381.4170532	0.03
383.2184448	1.85
393.2562866	0.06
395.1433716	0.12
396.8612061	0.09
407.1971436	0.04
413.2741699	0.58
419.1759033	0.04
425.2590332	0.20
426.4739380	0.06
431.3078003	0.02
433.3286133	0.04
437.2913818	0.15
443.1594238	0.14
446.2745361	0.04
455.2565918	0.58
461.2527466	0.06
466.6917725	0.04
467.3601074	0.01
471.4252319	0.19
473.2702026	6.56
483.2481079	0.03
485.1407471	0.32
487.1136475	0.04
488.5214233	0.02
489.3428955	0.02
499.2113037	0.09
503.3206177	2.90
513.4837646	0.06
515.2330933	9.80
515.8464966	0.03
517.3704834	0.22
518.4569092	0.07
527.4022217	0.03
529.4016113	0.07
533.2929077	0.22
539.2609253	0.21
541.5186157	0.08
543.4298706	0.02
545.4096680	3.37
548.5559082	0.06
557.2999268	0.51
559.2329712	0.15
562.1624146	0.05
571.4785156	0.03
575.2631836	1.45
581.7806396	0.11
583.5974731	0.01
587.4992065	0.14
591.1220703	0.01
593.3059692	8.11
593.9191284	0.02
599.3901978	0.18
605.4745483	0.03
614.7064819	0.04
617.2329712	0.76
635.3096313	14.13
636.0424805	0.10
644.9942017	0.02
649.2361450	0.03
665.3568726	2.90
668.5433350	0.03
669.4704590	0.04
675.3025513	0.02
677.2689819	0.57
679.4281616	0.13
691.5250854	0.10
692.8699341	0.10
695.3887329	0.29
701.2493896	0.03
707.1577759	0.22
710.5910034	0.40
711.3543091	0.03
719.4671631	0.11
725.2871094	0.01
735.0350952	0.03
737.4228516	1.63
755.3383789	100.00
756.1495361	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	761.206
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
286.9511108	0.15
419.3983154	0.55
523.1123047	0.21
581.0270386	0.21
599.5551147	0.56
605.5750732	0.17
623.2182007	0.44
641.3628540	0.82
671.2970581	0.67
714.7091064	1.71
725.4687500	100.00
742.1026611	0.31
743.3866577	0.78
761.1721802	81.39
761.9316406	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1855
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
165.1288757	0.05
189.4539795	0.09
190.9931793	0.08
195.0121765	0.41
218.9622650	0.11
234.9398346	0.03
244.9971008	0.09
251.1745453	0.05
259.1458130	0.06
260.9659729	0.07
263.1674194	0.34
271.0527954	1.75
272.2097778	1.78
273.1536255	4.99
275.0578003	0.04
281.1955872	0.33
283.1520691	0.26
284.1528320	0.60
285.0895386	0.73
295.0191650	0.22
296.1800842	0.36
297.1116333	0.57
298.2056885	0.07
308.2725220	0.14
310.4059448	0.24
313.1033630	4.56
314.1857910	5.39
315.0937500	2.99
330.3095093	0.05
337.1947021	1.25
338.1112061	1.77
339.1538086	2.12
344.2938843	0.03
350.2481689	0.07
352.2584229	0.08
362.2680664	0.02
363.0542603	0.06
365.2112427	0.52
367.1771851	1.68
368.1132812	2.57
369.1388550	0.25
374.1387939	0.06
379.2692261	0.70
380.0643311	1.42
381.2166748	0.61
382.5615234	0.26
383.2703857	1.72
388.4264526	0.07
389.1138306	0.09
396.0518188	0.05
397.1550903	0.73
398.2639771	2.11
399.2251587	1.44
401.1229858	1.73
402.4841919	0.11
413.1672363	0.04
415.1228638	6.57
416.1611328	15.92
417.2260742	5.49
418.4628296	0.69
419.1437988	4.60
422.6472168	0.03
424.3403320	0.16
425.0468140	0.13
429.2961426	0.18
430.9446411	0.03
433.1686401	33.16
434.1888428	100.00
435.2647705	18.82
437.3189697	0.02
441.2168579	0.34
442.0429077	0.29
443.0994263	0.12
447.4411621	0.05
449.2238159	0.13
458.9010010	1.41
460.1514282	0.67
461.1582642	0.37
463.5510864	0.05
465.2023315	0.04
467.0730591	0.28
470.0769653	0.03
474.0704346	0.07
475.3238525	0.05
476.4610596	0.09
482.5015259	0.08
483.3143311	0.09
484.2393188	0.12
490.3997803	0.18
491.3099365	0.05
496.7603149	0.07
497.3835449	0.07
499.4029541	0.07
501.3704224	0.05
502.6809692	0.06
507.1610718	0.05
508.4484253	0.22
509.1590576	0.13
514.0197754	0.12
519.3670654	0.03
521.4660034	0.08
525.3706665	0.08
526.2791138	0.87
527.1839600	0.86
532.3594971	0.08
534.8690796	0.03
536.4649048	0.04
544.3572998	0.85
545.1204834	2.23
561.0130005	0.04
562.3628540	2.11
563.2074585	2.53
584.4129639	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	491.2264
Annotation	Reissantin E
Peak:m/z	Relative Intensity
136.8755035	0.08
143.2189178	0.26
145.0459747	1.08
147.0697479	0.57
149.0532532	1.08
151.0772095	0.33
152.8641357	0.31
156.9692688	0.99
159.0579224	0.66
161.0278320	4.80
162.9891663	1.63
164.9971313	0.87
166.9671326	0.50
168.9599152	1.25
171.2721863	0.38
171.9027100	0.35
172.9574738	2.55
174.9851990	3.29
177.1726379	0.98
179.0490723	0.40
182.8966980	0.10
184.1194611	0.36
185.0768280	2.48
187.0226288	2.82
189.1740112	0.54
190.9982452	0.33
193.0879517	0.63
195.2392578	0.49
197.1503906	2.37
199.1978455	0.70
201.0860291	3.50
202.1463928	0.14
203.1296692	3.62
205.0823975	1.68
207.4298401	0.12
209.1818542	2.91
210.9900665	0.62
213.1868744	1.41
215.1221161	1.86
217.2907867	1.13
219.1164703	0.56
221.1020355	0.49
223.0292969	0.84
225.0088806	2.08
227.1143799	3.51
229.1345215	2.31
231.2050018	2.10
232.3286743	0.46
233.1253357	0.43
235.1960907	2.51
237.1393433	1.64
239.0347900	2.21
241.1705933	0.45
243.1868134	3.11
245.1427002	6.50
247.1735535	5.73
247.8756256	0.14
249.2904053	0.98
250.1221771	0.21
251.1707001	1.12
253.1460571	4.24
255.1209717	6.66
257.1805115	3.23
259.1892700	1.77
260.0529480	0.43
261.2022095	1.78
263.0595703	3.13
263.8771973	0.26
265.0461121	2.15
267.3303223	1.06
269.2448730	1.49
271.3229065	2.64
273.2197876	1.98
275.0888977	0.95
277.2702637	1.54
278.1832275	0.37
279.1980896	1.78
280.2880554	1.18
281.1893616	8.43
282.9204712	3.69
283.7871094	0.23
285.2561035	2.56
287.2066650	1.05
289.1824341	1.13
290.9996033	3.07
292.2618103	0.48
293.1707458	2.56
293.9487915	0.47
295.1946411	2.67
297.1310425	1.69
299.2344666	3.82
300.1786499	0.16
301.1492615	0.10
302.4431763	0.69
303.3590088	1.14
305.3143005	2.91
306.3430176	0.17
307.2593384	1.38
309.1589661	6.89
310.3229370	1.58
311.2110901	5.03
312.9569092	1.28
314.3145142	0.10
315.2012634	1.32
317.3526611	4.13
319.3683472	1.24
320.1940002	0.49
321.3222351	5.18
323.2182007	15.38
324.3385315	0.53
325.1706848	1.67
327.1466064	7.68
329.3634338	0.86
331.1162109	1.98
333.1884460	2.44
335.2424927	4.68
336.3188477	0.23
337.1754150	0.22
338.2682495	0.89
339.3547974	8.00
341.2905273	71.62
343.2260437	0.50
345.2305298	3.49
346.3513184	0.29
347.1448975	0.76
349.2242126	8.22
350.2604980	0.64
351.2399597	5.96
352.0180664	0.11
353.2362976	0.84
355.2155151	1.56
356.1486206	0.11
357.2940063	2.75
359.1033325	1.12
361.0802307	0.41
363.2720947	1.01
365.4133301	2.03
367.2539062	18.93
368.6614380	5.10
369.3046875	49.12
370.5777283	0.48
371.3279724	0.15
373.2713013	1.45
375.3163452	3.97
377.2760620	2.73
379.3942566	1.80
380.2752686	0.26
381.5120544	0.50
383.3299255	1.98
384.6718140	6.51
385.2914734	59.98
386.0429382	0.33
387.2564697	0.24
389.3174438	0.29
390.3374939	1.10
391.1184692	1.21
393.2694397	27.17
394.1451111	0.08
395.2452393	11.54
395.9617004	0.09
397.1507568	2.27
398.2359924	0.58
399.1396790	0.36
401.1466980	2.09
403.1905518	1.62
404.6275940	0.77
408.2445984	0.68
409.2961731	11.22
411.2966003	91.24
412.5704041	2.56
413.2567749	16.33
414.2530823	0.42
415.3442383	1.29
416.0252686	0.08
417.5943909	0.09
419.3488464	4.44
421.4634094	0.17
425.2992249	1.24
426.4530029	2.61
427.2582703	9.91
429.2062988	86.83
430.2004700	2.03
431.1752625	6.14
433.3431702	0.38
436.6681213	5.31
437.2996216	56.56
438.3070374	0.22
439.3340149	0.25
444.1444092	2.96
445.2041931	3.43
446.2901001	0.96
447.1153870	0.57
455.1122131	57.91
455.8370667	0.67
459.1050720	0.52
460.0235291	0.68
462.2590027	0.51
467.8107605	1.12
469.2326965	0.54
473.1214905	100.00
474.4358521	0.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	889.2271
Annotation	Kaempferol 3-glucosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-galactoside
Peak:m/z	Relative Intensity
281.3272705	0.04
286.1140137	0.03
335.2494812	0.03
342.2145386	0.04
353.3287354	0.02
365.0690918	0.07
408.0816650	0.03
416.0684204	0.08
417.4842529	0.03
421.2584229	0.03
451.2028809	0.02
456.2903442	0.03
475.4199219	0.01
476.4635620	0.03
527.9329834	0.06
536.2109985	0.07
558.2241211	0.03
562.7566528	0.03
563.4803467	0.23
575.2846069	0.11
580.5307007	0.05
593.2002563	0.21
606.3337402	0.09
614.5194702	0.06
623.6024780	0.14
641.0648804	0.04
645.2529907	0.03
647.2769775	0.09
659.3280640	0.02
683.3918457	0.31
695.6798706	0.06
707.4057617	0.14
710.2478027	0.04
725.1743774	0.15
737.3250732	0.07
749.4787598	0.09
755.3350830	0.25
759.8012085	0.10
769.3833008	0.26
773.3279419	0.06
783.1833496	0.11
798.7383423	0.02
801.2703247	0.06
803.2799683	0.13
809.3372192	0.07
827.4201050	0.99
844.2610474	0.06
845.2833252	10.13
845.9273682	0.03
853.1887817	0.14
868.7132568	0.04
870.3270874	0.02
889.2628784	100.00
889.9395142	0.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	780.3879
Annotation	Unknow
Peak:m/z	Relative Intensity
222.9512634	0.21
226.2141876	0.65
270.7685852	0.17
314.0890503	0.05
322.8145142	0.16
339.3042297	0.88
340.2156982	0.23
350.1302490	0.24
357.3162231	0.14
360.2842407	0.11
369.2389832	0.13
371.4806519	0.19
375.5199585	0.09
390.2773438	0.17
394.0816650	0.05
394.8460083	0.12
396.0906982	0.58
396.8717041	0.58
404.1416016	0.40
404.9489136	0.36
408.0291138	0.09
422.2509155	0.04
423.2782593	0.27
441.5027466	0.05
443.3895874	0.08
451.1229858	0.06
454.4164429	0.09
456.2730713	0.12
470.3635254	0.92
471.6377563	0.18
481.5499878	0.38
487.4370728	0.24
491.5988770	0.22
492.5744629	0.55
493.5464478	0.19
501.5764160	0.18
509.3792725	2.94
510.3879395	1.16
511.2767944	0.14
524.1884155	0.11
528.3478394	0.74
529.5550537	0.24
541.3998413	0.31
543.3985596	0.17
550.2597046	0.14
555.5200195	0.18
565.5675659	0.10
566.7337036	0.05
567.4988403	0.57
575.3147583	0.28
583.3871460	1.53
584.3207397	2.44
585.4634399	0.61
591.3796997	0.19
609.4814453	0.09
611.2385864	0.09
612.3832397	0.33
622.2117920	0.18
623.5424805	0.31
624.4061279	0.26
625.7418823	0.14
638.8973389	0.31
640.3126831	1.36
641.4755249	1.97
642.2540894	0.31
643.5899048	0.27
651.7058105	0.17
665.5352783	0.08
666.3928223	0.10
667.4051514	0.41
673.6261597	0.17
677.4351807	0.40
679.6947632	0.16
682.8673706	0.60
690.3292847	0.08
691.4255371	0.27
694.4293213	0.34
698.3444214	0.12
706.2496948	0.11
707.7949219	0.17
708.7317505	0.19
719.2821045	0.16
725.4761353	3.36
726.3718872	3.50
727.7667236	0.23
735.6958618	5.10
736.5013428	5.86
737.5429077	3.57
738.6740723	0.24
746.5059204	0.10
748.1572266	0.27
749.5759888	0.18
751.1055298	0.18
753.4662476	69.78
754.4703369	51.57
755.5908203	8.05
756.5340576	0.19
763.5947876	0.42
764.3661499	0.10
779.0994263	0.07
779.9201050	0.24
780.9900513	0.36
781.9532471	1.18
789.6929321	3.05
790.5578613	3.80
791.5048218	3.93
792.5225220	0.91
805.5429077	0.37
807.4826660	100.00
808.4929810	81.96
809.4866943	23.77
825.5752563	0.05
911.3264160	0.16
1510.5728760	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.2665
Annotation	Lenacil
Peak:m/z	Relative Intensity
152.9599304	0.53
167.1175079	0.27
168.8127441	0.91
178.9621429	0.43
181.0621643	0.31
183.1475525	0.15
191.2460327	0.11
199.2326355	0.14
201.1665344	0.88
203.3331299	0.07
207.2745667	0.19
215.0561523	0.15
221.2395020	0.18
225.1163788	0.08
232.1826782	0.05
233.2488708	5.56
243.2043152	0.42
246.9426575	0.20
259.2308044	0.04
264.6007996	0.14
269.1343079	0.33
275.0673218	0.34
283.0867920	0.10
285.0691528	0.63
286.2000732	0.44
287.4411926	0.31
288.0535889	0.06
293.1322632	0.16
299.2372131	0.47
301.0640869	0.07
302.3919678	0.05
304.2463379	0.50
305.2260742	2.03
307.1414795	0.11
313.2454224	0.17
315.3489380	0.31
316.0972900	0.08
316.9828491	0.09
318.1600037	0.11
319.9286194	0.19
321.1732788	0.21
322.2835693	0.33
323.3783264	0.79
330.0882874	0.33
331.1096191	0.21
334.5081787	0.08
335.4078979	0.05
346.1988525	0.33
349.3995056	0.37
350.3762207	0.27
351.5295715	0.05
359.1706848	0.16
361.2299500	0.16
363.1022339	0.09
364.2441406	0.53
365.2363892	0.43
371.2811584	0.40
375.1920471	0.12
377.1579285	0.27
378.0014648	0.10
379.3211365	0.63
380.5855408	0.53
383.3794861	0.30
384.9709167	0.06
388.2750244	0.06
389.2423401	0.43
391.3293762	0.15
405.1753235	0.32
407.2853088	0.22
421.3286438	7.58
422.2770081	7.13
423.3597717	7.28
424.2605286	0.11
425.6426086	0.14
431.2352600	100.00
432.4465637	0.18
437.3589783	0.72
438.5554504	0.21
439.2135315	0.39
444.1590881	0.17
448.5248413	0.86
449.3194275	0.57
452.2984314	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1388
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8804932	0.47
178.9581909	2.00
181.0614929	0.03
196.9996185	0.13
221.1166687	0.96
232.9339905	0.03
243.1074524	0.07
250.9117126	0.11
257.0731812	0.06
268.7072144	0.04
280.6734314	0.35
282.2608032	0.05
303.1419067	0.10
305.0946350	0.13
311.4093018	0.04
323.1011963	0.68
341.0092163	2.19
341.6994019	0.04
355.2496948	0.03
359.1896973	0.16
377.2454834	6.78
383.2489014	1.74
385.9935913	0.12
387.1894531	0.02
401.0347900	0.11
406.0093384	0.03
423.5006714	0.04
425.2671509	0.09
443.1425171	0.40
485.3038330	0.06
501.0974731	0.05
503.2374268	100.00
503.8476562	0.26
504.4747925	0.08
521.2611694	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.3082
Annotation	Daechuine S7
Peak:m/z	Relative Intensity
160.9396667	0.21
179.1745605	0.20
191.0557251	0.05
233.2811279	1.57
235.1212311	1.00
239.1913605	0.22
253.0550995	8.32
258.9638672	0.17
261.3703613	0.05
275.2322388	0.19
277.2620850	100.00
351.0889893	0.09
439.2911377	0.05
449.4976807	0.17
467.4092407	0.13
469.8107300	0.26
473.0126343	0.05
477.4956055	0.15
494.4972534	0.03
495.9658203	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	592.2375
Annotation	Maytine
Peak:m/z	Relative Intensity
199.2760315	0.02
199.9455566	0.02
205.4547119	0.04
212.9867401	0.02
225.9750366	0.01
229.4256134	0.01
243.1616516	0.06
247.1566467	0.02
258.2177124	0.12
263.3842468	0.01
264.2047119	0.02
267.1840820	0.02
272.5906372	0.01
274.2074280	0.04
286.2772217	0.50
298.1755981	48.21
298.7855530	0.29
308.2046204	0.04
309.4631348	0.02
311.0283813	0.02
312.0252686	0.02
313.9882202	0.05
315.3586426	0.01
322.0117798	0.01
326.3641968	0.07
343.4649048	0.03
344.7026978	0.03
382.2216187	0.04
385.0915527	0.04
389.1236572	0.01
390.5870972	0.04
395.0841675	0.02
398.0070190	0.01
408.3526611	0.03
411.4575195	0.02
413.3845215	0.04
416.5283813	0.02
419.6058960	0.01
423.3074951	0.02
425.3208008	0.02
428.2902222	0.04
429.7232666	0.07
430.4475708	0.07
434.3753662	0.19
435.3801880	0.07
436.4428101	0.08
445.5681152	0.05
452.5201416	0.07
453.1781616	0.01
453.8770752	0.02
456.2181396	0.02
460.1987915	100.00
462.2763062	0.02
463.4063721	0.03
477.5183716	0.01
494.4695435	0.03
514.2879639	0.05
525.3677368	0.01
529.4809570	0.04
530.8781128	0.12
531.4932251	0.10
532.3501587	0.01
533.4464722	0.09
534.4413452	0.03
539.2038574	0.02
547.6224976	0.06
555.4768677	0.01
556.3656006	0.04
560.8969727	0.09
573.3603516	0.27
574.3336792	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.19
Annotation	Deoxynortryptoquivaline
Peak:m/z	Relative Intensity
154.0001221	0.06
163.3553467	0.13
165.3668213	0.05
175.2485352	0.07
181.0591125	0.07
185.1795349	0.07
185.9454803	0.17
189.1565857	0.06
203.1298370	0.06
224.9835815	0.17
227.1967468	0.21
231.0778046	0.07
233.5568085	0.09
234.3634338	0.05
252.3402863	0.17
258.1279907	0.19
265.2069702	0.09
267.1575012	0.08
278.2245483	0.11
285.1405029	0.31
291.2465210	0.11
293.2354126	0.88
295.1842651	0.07
297.2839355	0.15
301.0245972	0.04
303.2512817	0.05
304.1943970	0.12
307.1832275	0.06
309.4903564	0.08
314.3826294	0.10
323.1735229	0.20
328.2662354	0.04
333.3793945	0.48
337.1739502	0.25
339.1157227	0.16
341.4074707	0.08
343.4341431	0.32
344.1907959	0.27
345.2673950	0.28
349.3312378	0.23
351.3086548	0.39
353.6074219	0.07
368.3959351	0.11
369.2938843	0.30
381.0442505	0.13
382.2075195	0.11
385.6707764	0.10
393.3627319	0.21
395.1525269	0.75
397.3323975	0.11
398.4187012	0.31
399.3075562	0.05
411.2136230	1.57
413.0633545	0.18
423.3087158	0.13
424.1982422	0.06
425.5585938	0.04
427.3200684	2.23
429.4022217	0.29
437.7185059	0.09
439.1503906	0.72
441.3200073	0.43
443.5920410	0.57
447.6199951	0.18
453.0340576	0.07
456.3625488	0.36
457.3601685	0.11
469.2459106	100.00
470.0844727	0.33
471.2333984	7.47
472.6257324	0.17
478.3952026	0.07
479.1904297	0.87
483.2340698	0.85
485.2496338	0.25
487.4467773	0.40
495.3323364	0.06
496.8118286	0.10
497.6254272	0.09
500.4389038	0.10
516.1355591	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.1669
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
191.1400299	0.03
230.6226196	0.04
247.2015228	0.03
254.7138062	0.10
255.4336243	0.04
261.2876587	0.01
268.2570190	0.09
271.1305542	0.05
275.0512390	0.03
279.9814758	0.02
282.2850342	0.03
283.8908691	0.06
285.0814819	0.02
294.3393555	0.08
296.2682495	0.01
297.0864868	0.03
298.1780090	0.48
299.1813354	0.29
299.9735107	0.01
307.1307983	0.13
308.1638184	3.06
309.1452026	0.11
310.2633057	0.04
311.1326294	0.32
312.2930603	0.28
313.2124634	0.07
316.0841064	0.05
319.3356934	0.08
323.1165466	23.91
325.2593994	0.17
326.7440186	0.03
327.4147949	0.10
335.1300659	0.02
337.1441040	0.22
338.0940552	0.81
339.0978394	0.21
340.2627563	0.13
341.2277222	4.14
342.9246826	0.03
348.4880371	0.07
350.1585693	0.24
351.4782104	0.17
353.1965332	3.57
355.2073364	0.27
357.0089722	0.09
358.0969238	0.12
361.1323853	0.05
365.2805176	1.55
367.2567749	0.27
368.0941162	0.03
369.1735840	0.09
371.1362915	5.40
371.8544312	0.11
375.5178833	0.03
379.0536499	0.06
381.2520142	0.07
383.2260132	3.02
385.2896118	1.56
393.3074951	0.02
395.1267700	0.35
397.0963745	0.24
399.2465820	0.03
400.3226929	0.06
401.1251221	0.15
407.1399536	0.73
411.1910400	0.09
413.1118164	0.34
419.3834839	0.05
425.3198242	0.71
426.8026733	0.03
428.2440186	7.86
443.1452637	100.00
443.7573242	0.31
444.9090576	0.04
459.2219849	0.09
461.1411133	0.56
463.2116699	0.20
475.3552246	0.16
487.2569580	3.96
503.2732544	0.07
516.0206909	0.01
517.2423706	0.06
529.1873169	0.04
560.8676758	0.14
562.7964478	0.19
588.3692017	0.27
589.4467773	0.06
592.4475098	0.13
607.2816162	0.14
608.3543701	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.11
Annotation	Oganomycin A
Peak:m/z	Relative Intensity
182.8947754	0.03
189.0701599	0.05
196.0226135	0.37
200.0312347	0.88
201.9162598	0.38
207.9387512	0.30
212.3038025	0.06
212.9882202	0.16
217.9394684	0.03
221.7823181	0.01
224.1323395	0.06
225.9040375	0.36
228.0107574	0.02
236.0979004	0.03
237.1588287	0.03
245.9865417	0.07
248.1141663	0.26
253.0327454	0.15
253.9020691	2.29
255.0169830	0.30
260.0270386	0.05
264.0510864	0.22
265.1121826	0.05
271.0170288	0.02
271.9522095	1.09
273.0000610	0.52
276.1911011	0.05
278.3148193	0.05
281.0163269	1.06
283.9161072	0.50
286.0697632	0.47
294.1691284	0.35
298.9361572	0.16
299.6335754	0.04
301.9729614	0.02
304.1079712	0.70
306.0997925	0.62
312.1884766	0.20
313.5155640	0.06
316.1029663	0.16
318.0082397	0.70
319.1602478	0.30
321.9808655	0.29
327.2722778	0.23
329.6489868	0.07
331.1528931	0.09
332.1096802	0.46
339.9274902	0.74
345.4121094	0.05
346.0845947	0.33
348.1499023	8.33
357.9790039	0.48
364.0437012	3.76
365.7439575	0.24
366.4329834	0.03
374.0761108	0.03
376.0903320	1.05
377.0067139	0.15
378.1722412	0.07
391.9976196	0.55
394.0827637	100.00
401.0130005	0.07
402.1950684	0.05
404.1846924	0.05
418.9168091	0.32
420.0205688	1.34
434.9854736	0.04
436.2569580	0.41
438.0420532	70.28
438.6680298	0.11
439.4880981	0.03
455.2866821	0.06
467.3425903	0.10
468.1160278	0.05
497.1246338	0.29
498.3872681	0.15
509.9566040	0.15
511.1476440	0.49
512.2882080	0.07
513.8607178	0.16
532.5438843	0.10
552.0559692	0.02
554.4745483	0.05
569.0760498	0.65
570.0476074	0.57
577.5297241	0.14
584.6041870	0.11
585.7133789	3.07
593.1337280	0.21
611.4061890	0.64
612.0248413	1.76
682.8541870	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3073
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
141.9662781	0.03
150.9381866	0.04
153.0923157	0.06
154.7450409	0.53
163.0548859	0.12
166.8962402	0.07
168.6674957	0.06
177.2937012	0.11
180.1324463	0.05
183.0674133	0.03
187.025116	0.16
191.1732941	0.15
194.2077637	0.09
198.057251	0.09
201.2861328	0.21
210.8869324	0.08
216.1002808	0.42
219.2631226	0.07
237.2928772	0.03
247.2922821	0.30
265.2015991	2.81
279.3296204	0.14
292.994751	0.13
299.4109497	0.09
306.8546448	0.08
308.4502563	3.07
321.2818298	0.51
326.4017029	0.11
339.2942505	92.40
339.9278259	0.36
344.2064209	0.13
358.4280701	0.03
382.2873535	0.13
400.2112122	0.15
411.9986267	0.08
419.1714783	9.72
423.7087708	0.11
424.6867065	0.11
434.700531	0.14
437.1123657	0.27
448.2233582	0.08
462.2018738	100.00
463.0892029	0.03
466.0022888	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.1068
Annotation	6-Deoxyclitoriacetal
Peak:m/z	Relative Intensity
113.0984726	0.04
122.8959656	0.01
145.0648956	0.03
147.8410339	0.03
150.9852142	0.05
153.1484070	0.03
154.0369415	0.02
168.7399750	0.02
177.0518951	0.02
180.8540649	0.03
182.7420197	0.01
187.2961731	0.05
188.2658997	0.01
194.8223724	0.04
227.1611023	0.01
245.1522827	0.01
257.2493591	0.02
279.3724365	0.02
283.2394409	0.03
285.4313354	0.02
292.9145203	0.04
296.2977295	0.05
297.0372314	0.03
299.1165771	0.06
314.2457581	0.63
315.0405273	0.07
324.0827637	0.44
327.0938416	4.57
327.9461060	0.15
329.0225220	0.02
331.3232727	0.06
333.8621826	0.07
339.0491638	0.06
342.0759888	6.49
343.2290649	0.44
345.1179199	15.03
346.2159424	0.69
347.2539673	0.03
356.2056580	0.03
357.2142639	0.85
357.9869080	0.07
360.1139832	100.00
361.1332703	4.02
365.4042053	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2914
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
142.0303650	0.12
146.8934937	0.15
149.2302246	0.19
150.7752533	0.25
153.2548523	0.25
154.9237976	1.92
157.1134338	0.17
163.3115234	0.09
164.9007874	0.16
172.9129486	0.40
175.0772858	0.29
179.2443237	0.29
180.1125183	0.26
193.3081360	0.11
197.9192505	0.43
199.3300171	0.09
201.3323975	0.22
203.3484192	0.14
213.1497803	0.11
216.0491791	0.11
217.1990356	0.24
235.1196289	0.16
243.4261017	0.09
245.2433167	2.23
249.6344910	0.09
253.0695190	0.14
259.2545471	0.16
263.2386475	8.40
265.3249817	0.35
278.9853821	0.06
289.2608337	0.16
293.1586914	0.16
304.9979248	0.09
306.3686523	2.41
307.0499878	0.04
318.9659119	0.11
321.1070251	0.27
331.5328369	0.21
333.2181396	0.13
334.6819458	0.06
337.3088379	95.04
337.9314880	0.32
380.1399841	0.32
417.1778259	5.38
431.4749146	0.18
435.0751038	0.09
442.3132019	0.15
460.2247009	100.00
460.9187317	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0773
Annotation	Acerosin
Peak:m/z	Relative Intensity
147.0688171	0.11
152.1354675	0.03
167.0773621	0.12
190.9675751	0.03
193.9382324	0.05
203.8638611	0.01
209.0195618	0.03
235.3095398	0.01
256.2538452	0.02
268.2123718	0.02
271.2200317	0.01
297.3269958	0.02
298.9961548	0.00
300.1270752	0.04
315.2786255	0.05
326.7327271	0.05
329.2302551	0.38
331.5881958	0.02
339.1726685	0.03
341.3125610	0.04
344.1227722	100.00
345.2156677	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0937
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
112.7795563	0.10
116.9496155	0.05
124.9754791	7.57
127.9011383	0.15
128.9387817	0.19
130.8453369	0.11
143.0027618	2.34
145.0120392	0.02
148.9480896	0.08
161.0140533	0.53
168.9191284	0.24
174.8907471	0.07
178.1864319	0.03
186.8665161	0.34
191.0123596	0.36
193.3063965	0.04
198.9992065	0.03
201.2740936	0.04
204.9946594	100.00
206.0741730	0.05
207.1987152	0.17
217.2207489	0.07
219.2441406	0.25
223.1134338	11.42
225.1799927	0.15
236.4126282	0.04
237.2274170	0.02
249.0191956	0.07
252.2264099	0.05
255.1808777	0.06
265.0151672	0.06
267.1862793	0.05
269.2413330	0.03
286.8994751	0.09
293.1072998	0.05
294.1472778	0.12
297.0463562	0.03
299.1450195	0.04
311.0673828	0.07
312.0395203	0.05
325.1159668	0.08
327.0607605	0.03
337.2470398	0.09
339.0676270	0.26
351.3584290	0.34
352.2765198	0.57
353.1989746	0.23
354.2970886	0.16
355.3909912	0.05
357.3219299	0.05
363.1739197	0.36
367.0370789	0.08
370.9351196	0.09
381.0952148	0.64
384.4867859	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.2759
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
146.9920502	0.03
149.0339508	0.02
161.1708374	0.04
163.3594666	0.09
169.1182709	0.09
171.4120941	0.02
173.3396301	0.03
175.0119781	0.01
175.6379547	0.02
185.2663879	0.03
189.1891785	0.06
191.0370178	0.02
195.1268768	0.01
197.9811707	0.04
199.0634155	0.05
201.1928101	0.03
205.3790283	0.04
215.2541504	0.02
216.2369080	0.06
219.4448853	0.03
243.2535095	0.11
261.2404785	0.37
279.2371521	0.02
293.2113953	0.01
299.1918335	0.06
304.4137268	0.57
317.5233154	0.04
335.2797241	100.00
336.0892334	0.03
378.4482117	0.13
402.2630310	0.03
415.2724915	0.17
415.8973083	0.02
426.9070435	0.20
433.0710449	0.19
458.2586365	3.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.25
Annotation	Echinacoside
Peak:m/z	Relative Intensity
315.3856812	0.27
350.3095703	0.38
383.2650757	2.00
384.6859741	1.41
385.3947144	0.61
398.9284058	1.03
467.4703369	0.59
479.2489624	3.26
503.3463135	0.21
521.1896973	2.46
533.5521851	0.54
556.447998	0.35
561.6642456	1.56
567.4154053	0.25
605.2050781	0.90
622.5678101	2.57
623.3361816	9.26
633.1581421	1.84
650.2807007	0.70
665.2277222	1.27
707.2313843	0.29
723.5219727	0.38
740.1610718	1.02
766.4370117	1.38
784.4313965	13.09
785.2504272	100.00
786.1829224	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.072
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
95.03359222	0.02
97.14675903	0.04
103.0933914	0.01
145.0612183	0.05
149.1929932	0.02
149.9199524	0.01
151.2373657	0.02
153.0227051	0.06
157.3458405	0.03
165.1459656	0.03
169.2098541	0.03
178.1458588	0.02
183.4303589	0.05
184.5394897	0.03
185.1553955	0.04
191.1121521	0.01
193.0846863	0.79
194.8788147	0.07
197.0786743	0.19
199.1519775	0.04
204.2184143	0.01
209.2136536	0.02
211.511322	0.15
212.3036194	0.03
213.2578735	0.05
216.943634	0.03
223.3503723	0.03
225.0524597	0.07
226.0202332	0.11
227.1255798	0.06
229.1001587	0.18
233.0889893	0.21
237.8779297	0.03
239.0961914	0.17
240.1524353	0.04
241.2095032	0.11
242.2834473	0.02
250.3104248	0.04
251.2814636	0.30
253.0463867	0.17
254.2854614	0.17
255.1121216	0.07
257.0038452	0.35
267.1849976	0.68
269.0978394	1.16
270.0742798	2.46
271.4816895	0.08
277.3685608	0.05
281.1824951	0.32
281.896759	0.15
283.1752014	2.81
285.0238953	6.14
286.0002747	0.03
292.4012756	0.04
293.25354	0.14
294.4537048	0.32
295.264679	2.84
298.0560608	100.00
299.0728149	0.02
313.5583801	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.1229
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
151.4014282	0.04
161.9754333	0.03
178.1637421	0.07
179.0140381	0.10
193.2108002	0.05
197.2789917	0.07
206.1446991	0.01
211.2899170	0.05
215.2237244	0.09
230.8549805	0.03
234.9758148	0.06
248.7820129	0.11
253.3728943	0.03
254.2975769	0.07
259.1763000	0.21
267.1644897	0.17
287.3756104	0.06
293.2453918	0.06
301.0945129	0.97
302.9739380	0.07
308.1840210	0.05
309.8827515	0.02
311.3663330	0.04
313.1177063	2.19
325.1796570	2.31
329.0656128	0.26
330.6274109	0.02
332.9709473	0.07
334.3274231	0.02
337.1816406	0.15
339.3848572	0.03
341.2820435	0.29
343.1380005	30.04
351.4260864	0.08
355.2344971	0.09
357.3972473	0.07
359.1070557	0.03
367.1558838	15.88
367.7643433	0.06
373.2290344	1.15
379.1065063	0.26
381.2980957	0.48
383.3063354	0.06
385.3145752	0.09
390.0143127	0.08
391.2871399	0.29
397.1275024	33.26
397.7321472	0.61
398.7512207	0.04
399.4621887	0.04
401.2743225	0.01
403.2866516	0.09
404.2213745	0.03
409.2640686	8.91
410.0625305	0.05
418.0706177	0.08
419.1585388	0.13
427.2570190	23.72
428.1708069	0.02
430.4221497	0.02
431.0294495	0.13
445.1687622	100.00
446.0456848	0.50
448.2091980	0.19
453.0061951	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.1848
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
213.0535736	0.11
235.1989746	0.02
244.0174103	0.02
258.1542664	0.09
271.3016357	0.04
300.0884399	0.13
315.2125244	0.02
316.4053345	0.02
318.0947266	0.05
328.2175903	2.22
331.1543579	4.18
333.1731567	0.06
342.7630005	0.06
343.3774414	0.11
346.1343994	3.85
361.1473999	100.00
361.7790527	0.35
427.1411743	0.08
522.8489380	0.13
605.1843262	0.71
631.2015991	0.15
649.2744751	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.0723
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
92.8905182	0.32
98.9856415	0.03
100.8990555	0.38
106.9983444	0.87
107.9592743	6.02
108.9954987	7.95
112.8308640	0.62
118.9163284	0.28
120.9679108	1.23
122.0454865	0.62
122.9311752	1.80
124.9703445	0.12
128.9679871	0.04
130.9983826	0.04
133.2456665	0.26
134.9768066	1.36
136.0488281	0.28
136.8703156	0.29
146.0934448	0.11
147.1459961	0.15
149.0135498	0.10
150.9237976	3.93
151.8537598	35.70
152.9184875	100.00
158.9690552	0.35
161.1408386	0.28
162.9600220	8.79
164.9915619	13.05
167.0698090	0.37
173.0824280	0.06
174.9419556	0.23
176.9466095	0.80
179.0583038	1.92
181.0880280	3.32
184.0845947	0.12
188.9530334	0.05
190.9345398	0.28
192.9804382	1.42
195.0123596	3.84
199.2134094	0.14
203.1611023	0.26
205.1132812	0.29
207.0839844	2.79
212.1155090	0.18
217.1266785	0.24
219.1919250	0.88
222.8884277	0.13
225.0712585	7.23
227.0969238	0.08
230.9619751	0.09
233.1618042	0.11
237.0110168	0.81
249.2246094	0.19
251.0353699	0.30
260.9741821	0.10
269.2145386	0.46
271.0463257	0.33
279.1451416	1.13
284.1921692	0.09
296.1204834	0.06
297.1025696	0.28
300.0838928	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	728.3948
Annotation	Citrusin III
Peak:m/z	Relative Intensity
210.8645325	0.03
212.2230530	0.06
213.1091156	0.86
217.1157990	0.06
221.2165680	0.24
224.2563477	0.08
227.2480164	0.21
234.2058716	0.03
235.2916412	0.03
236.2311401	0.05
239.5551758	0.08
242.1684113	0.21
248.1383057	0.12
251.1185913	0.10
252.1916504	0.27
259.1738281	0.45
261.2171936	0.48
263.4710388	0.41
264.0946655	2.04
266.2475891	0.03
270.1295776	0.05
273.2128601	0.16
277.3345032	0.16
278.8532104	0.07
280.8616943	0.26
282.2586060	6.10
286.1310425	0.18
289.3098755	0.34
290.1196289	0.23
294.2011719	0.04
295.4643555	0.10
299.4908142	0.17
304.2968750	0.04
306.7790833	0.10
307.5473633	0.80
308.3897705	0.14
309.3056641	0.15
310.3091736	0.10
312.7824707	0.07
318.0897827	0.24
320.4943848	0.12
321.3537292	0.44
323.1624451	0.09
325.1883240	0.13
325.9989624	0.03
331.4870605	0.14
334.0974731	0.94
338.3378906	0.04
339.2489014	4.02
341.3073730	0.17
342.0789185	0.11
345.1977539	0.36
348.3819275	0.09
350.4275513	0.03
351.9334412	0.12
354.8497009	0.26
356.2268066	5.02
357.3876648	0.14
359.0783386	0.05
365.2954712	0.10
370.1314087	0.19
371.5985107	0.11
374.3831787	0.10
375.0361938	0.03
376.2055664	0.20
377.3376465	0.92
378.4393311	0.07
384.6381836	0.07
385.3552856	0.13
386.8119507	0.35
387.4719238	0.28
389.1806641	0.13
390.0222168	0.09
393.2555542	0.25
395.2517700	0.30
400.5015869	0.24
403.0263672	1.24
405.2013550	2.01
406.3199463	0.12
412.1892090	0.04
412.9172974	0.22
414.3155518	0.17
415.1657715	0.22
419.3428345	0.54
421.2197266	0.26
422.2741699	0.14
423.8785400	0.12
431.2236938	0.68
432.6479492	0.06
434.3051758	0.63
436.1237793	0.12
447.0144043	0.47
450.4337158	0.15
452.4837646	0.91
456.3009644	0.34
456.9043579	0.03
462.4982910	0.17
463.3426514	0.48
466.3217163	0.14
472.3311157	0.73
474.2264404	7.11
474.8593750	0.14
479.4827271	0.02
481.2117920	0.16
483.3059082	0.04
484.3352051	1.65
486.3295288	0.71
487.4368896	0.19
488.5183716	0.04
489.6376953	0.41
490.4084473	0.76
498.3409424	0.15
500.1945801	1.72
502.2509155	17.76
506.2143555	0.56
508.5330200	0.26
511.0721436	0.17
516.3530884	2.24
518.5087891	2.15
519.4675903	0.10
520.4143677	0.13
526.1485596	0.15
528.5543823	0.13
529.3970337	0.11
534.4811401	0.42
537.2947998	0.07
539.1365356	0.03
542.1582031	0.24
544.3163452	0.52
546.4026489	0.08
547.4735718	0.60
551.7513428	0.13
552.3660278	0.05
553.4826050	0.14
557.4652100	0.04
565.4518433	2.41
568.0335083	0.04
568.9839478	0.51
569.8305664	0.28
570.5404663	0.21
571.4785156	0.09
575.6655884	0.13
577.4761963	0.05
579.3176880	1.36
581.3450317	0.04
583.0541992	0.05
585.3049927	0.47
587.4524536	6.80
595.3903198	0.40
596.3702393	0.20
597.5068970	5.00
599.4696045	3.91
603.4443970	2.18
613.3818970	6.60
614.7655640	2.64
615.4110718	39.71
616.0335083	0.21
622.5170288	0.06
623.6605225	0.15
625.0771484	0.03
625.7599487	0.21
626.4320679	0.04
629.0814819	0.17
631.3771362	7.14
632.0170288	0.04
641.5319214	0.51
648.4139404	0.06
653.7317505	0.05
655.5904541	0.25
662.3081055	0.05
664.7815552	0.08
665.4799194	0.17
666.6039429	0.40
670.6882324	0.20
671.4801636	0.24
674.3079834	0.12
674.9467773	0.03
680.7482910	0.17
682.5230103	3.89
683.4519653	2.76
684.5662842	2.05
692.5420532	3.58
693.2594604	0.14
698.3883057	0.10
700.5070190	100.00
701.1797485	0.40
710.4513550	36.99
711.0945435	0.22
711.8654175	0.03
728.5536499	13.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	876.3881
Annotation	Unknow
Peak:m/z	Relative Intensity
249.1794128	0.02
256.2004089	0.02
257.5550232	0.02
260.7814331	0.19
270.9772949	0.03
274.2777710	0.06
278.3056335	0.10
284.3334961	0.02
285.1304932	0.02
291.1953430	0.03
295.9933777	0.13
297.8978577	0.01
299.3379822	0.03
300.3271790	0.02
313.2069092	0.02
316.1088257	0.08
318.3041077	0.01
321.3507080	0.04
323.9765015	0.03
329.2627258	0.04
332.1895142	0.03
334.0682068	0.02
338.0413513	0.09
341.1837158	0.04
341.9111633	0.02
347.2414551	0.03
348.2029114	0.15
349.1203003	0.04
353.2804565	0.10
358.1112061	0.04
359.1282959	0.09
371.2905884	0.01
374.1906128	0.25
376.2325439	0.03
377.4692078	0.02
378.9488831	0.01
382.3892822	0.09
383.3352356	0.03
391.4148865	0.06
392.6886597	0.03
400.4648438	0.01
402.4446411	0.01
403.2764282	0.22
404.8060303	0.06
410.1469727	0.03
411.1978760	0.15
412.2033691	0.05
413.1970825	0.01
416.4033813	0.02
421.4153442	0.04
423.3328247	0.03
425.6086426	0.08
428.0477905	0.09
428.7092285	0.04
430.2856445	0.02
431.0934448	0.26
438.5101318	0.08
446.3354492	0.06
448.3925171	0.06
449.2990112	0.02
450.2616577	0.03
451.4537964	0.02
456.0656738	0.01
457.2360840	0.14
460.6230469	0.02
464.4147949	0.04
467.3224487	0.25
468.2467651	0.06
472.4214478	0.05
473.5326538	0.06
475.3255615	0.19
483.2232666	0.09
485.2902222	0.11
487.9555054	0.01
490.2882690	0.08
494.6549683	0.05
499.3704224	0.06
500.4105835	0.25
503.2384644	0.18
507.9836426	0.03
512.0847778	0.08
514.2484741	0.01
515.0483398	0.03
516.1826782	0.22
517.2622070	0.04
518.3558960	0.30
524.1924438	0.05
525.2618408	0.04
528.1945801	0.10
544.6381836	0.18
545.2464600	0.07
546.4435425	0.07
552.5184326	0.03
553.4003906	0.04
555.9568481	0.06
560.4710083	0.06
569.4883423	0.02
570.5662842	0.14
571.4736938	0.11
574.4526367	0.05
580.1113281	0.04
581.3709717	0.05
582.2836304	0.04
585.3623047	0.07
588.2929688	0.18
589.0504761	0.06
591.0778198	0.05
591.9050903	0.02
593.3038940	0.07
598.2905273	0.60
601.2382812	0.02
603.5409546	0.01
607.3446655	0.06
613.5991821	0.03
615.3837280	0.12
616.4310913	0.60
624.3804321	0.04
629.4556274	0.10
630.3670044	0.05
639.2633667	0.03
640.4373169	0.04
641.1448975	0.04
642.6604004	0.05
643.2898560	0.03
648.4110718	0.04
653.0387573	0.04
655.2451782	0.06
658.4961548	0.06
659.5801392	0.05
660.2286987	0.03
666.9304810	0.06
668.4685669	0.16
669.2976685	0.11
670.7788696	0.25
671.5276489	0.16
674.3813477	0.07
676.3953247	0.16
686.3244629	0.98
687.0143433	0.01
688.3623047	0.13
690.4521484	0.32
695.4431152	0.06
698.5872192	0.02
700.3636475	0.05
704.3546753	0.49
706.6199951	0.04
711.2017822	0.02
713.0934448	0.23
713.9702759	0.16
715.5621948	0.12
716.4125977	0.10
717.7802734	0.05
723.4429321	0.05
725.5758057	0.06
729.5651855	0.04
730.5605469	0.02
732.5942383	0.34
733.4286499	0.10
734.1578979	0.13
736.6721191	0.04
743.5130615	0.29
744.5569458	0.09
745.4380493	0.03
754.5650635	0.03
756.3701782	0.06
761.4736328	0.08
763.2338257	0.14
768.6882935	0.04
779.3437500	0.11
783.3087769	0.08
784.1487427	0.29
784.7707520	0.06
786.6838379	0.01
789.2407837	0.05
801.6278687	0.01
803.3473511	0.02
804.7316284	0.16
811.2370605	0.04
812.5704346	0.01
813.6581421	0.14
814.6583862	0.09
823.4713745	0.01
828.7952881	0.06
830.4434814	0.16
831.3997192	0.13
840.3281250	0.77
841.1472778	0.05
841.7602539	0.05
846.5607300	0.05
848.5626221	0.21
857.3068848	0.12
858.5232544	6.09
876.4232788	100.00
877.0313110	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.2195
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1805725	0.02
244.9089203	0.11
277.0228271	0.03
286.7491455	0.02
289.2052612	0.32
300.1309204	0.03
305.1040649	0.30
319.1564941	0.05
321.2380371	0.15
331.1946106	0.04
334.9765015	0.02
337.2520752	0.42
339.3142700	0.15
363.1687012	0.07
371.1884155	0.13
375.0482178	0.04
377.2322998	0.06
381.1828003	0.99
401.2315063	0.02
403.3183594	0.02
419.1112061	0.03
421.1290283	0.30
435.0743408	0.03
437.3425293	0.06
449.2169189	0.21
453.3025513	0.81
459.3480835	0.04
461.1555176	0.02
471.1898804	0.20
481.2617798	0.09
491.0875854	0.09
493.3127441	0.41
505.0967407	0.13
507.0149536	0.02
508.9984741	0.13
513.3585205	0.12
523.4054565	0.06
525.2844849	3.36
541.3211060	0.07
543.3490601	3.35
553.0761108	0.05
553.6974487	0.06
571.2409058	0.29
573.5419312	0.02
585.4047241	0.48
603.3593140	6.23
613.5674438	0.05
625.2452393	0.67
645.3807983	0.61
657.3494263	11.50
675.3057861	18.77
675.9452515	0.11
703.5619507	0.03
705.3212891	0.01
735.2937622	100.00
736.0357666	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1095.5448
Annotation	Unknow
Peak:m/z	Relative Intensity
804.3378906	0.01
822.5858154	0.07
823.7877197	0.21
949.8500977	0.02
966.5776367	0.22
967.6163330	0.49
1003.5889890	0.01
1009.5261230	0.03
1060.7852780	0.06
1077.5009770	0.06
1078.5805660	0.81
1079.2701420	0.01
1095.6271970	100.00
1096.5684810	30.87
1097.2713620	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	727.194
Annotation	Unknow
Peak:m/z	Relative Intensity
210.1502686	0.14
217.0669250	0.07
222.9765625	0.17
254.2578888	0.03
293.0414429	0.07
303.0433350	1.46
306.0780640	0.17
315.2557983	0.05
321.0482788	1.28
327.0281067	0.07
342.1217041	0.03
345.0990601	0.18
362.9291992	0.04
376.8406982	0.23
387.1063843	1.30
390.9783325	0.08
391.6514893	0.22
405.0593262	0.37
412.5192261	0.04
423.2274170	0.06
443.0797729	0.04
447.2334595	0.05
460.5959473	0.11
465.0452881	0.03
488.1971436	0.02
493.5979004	0.04
521.3327637	0.27
563.2485962	0.15
568.8457642	0.03
580.9819336	0.87
581.6905518	0.26
623.3496704	3.01
640.4335327	0.10
667.3090210	0.65
682.4023438	0.39
685.1977539	0.55
696.4989624	0.09
709.3249512	19.14
727.2290649	100.00
727.8678589	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.8
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7369843	8.12
213.3480225	0.09
251.9798584	0.09
294.6437683	0.13
296.7799377	67.70
302.9277954	0.13
345.1435547	0.30
378.2243042	0.41
380.5553284	100.00
381.2816467	0.53
392.9550171	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	657.29
Annotation	Trichilin A
Peak:m/z	Relative Intensity
183.1626129	0.18
185.2137299	0.37
186.9262543	0.06
188.9433289	0.43
193.0891724	0.10
195.1120300	0.19
197.0791321	0.61
199.1072083	0.23
201.1984863	0.07
209.1786804	0.11
211.1764069	0.07
213.0802307	0.26
215.0402222	0.65
218.1496582	0.05
221.2366333	0.24
222.1857300	0.18
223.3463135	0.19
225.2664490	0.19
227.2095032	0.22
229.2024384	0.93
231.1818085	0.51
233.2560883	0.19
237.0540009	0.57
239.4576263	0.09
241.2265472	0.18
243.1299438	0.20
251.3063049	0.31
257.1489258	0.58
259.1408081	0.23
261.1604919	0.31
262.3056335	0.05
267.2529297	0.63
277.2843018	0.19
279.2439575	0.08
281.2522583	0.40
284.5555420	0.08
289.0594482	0.60
295.3084717	0.61
297.1040649	0.26
298.2409668	0.23
301.3098145	0.21
302.1363525	0.35
303.1365967	0.09
305.1822205	0.29
307.0863037	0.15
309.2280884	0.45
315.3939819	0.05
317.3773193	0.15
319.2908325	0.13
321.5932007	0.19
323.1867065	0.91
324.2786865	0.04
327.1998901	0.14
329.3520813	0.19
330.9464722	0.66
345.4473877	0.11
347.5800781	0.23
348.9035034	1.17
349.6738892	0.25
355.3287964	0.08
357.3684082	0.17
360.3383789	0.10
361.5930786	0.06
365.2706299	0.12
367.1662598	0.20
371.4395142	0.08
373.2951660	0.83
375.4552612	0.09
377.0437012	0.20
391.2697144	6.12
393.3164673	7.29
405.2946777	0.26
409.3436279	100.00
415.1857910	0.08
421.0130615	0.52
423.2371216	0.11
427.0610962	0.06
430.4661255	0.48
431.4823608	0.21
433.4897461	0.29
451.3524780	7.51
459.1686401	0.18
467.3350220	0.34
475.1868896	0.38
489.5394287	0.20
495.1036987	0.09
499.5104370	0.49
506.0837402	0.08
517.3572998	0.70
521.4113770	0.14
527.4673462	0.14
535.2743530	0.13
538.7608032	0.28
540.4536743	0.21
556.2673340	0.15
559.0088501	0.33
567.3239136	0.66
569.5437622	0.14
571.2164917	0.05
575.2516479	0.26
577.8848877	0.09
583.7261963	0.11
585.0667114	0.05
594.7626343	0.13
597.3427124	0.12
603.4318848	0.14
607.4663696	0.10
612.2921753	0.09
613.2373047	0.31
620.2567749	0.16
621.2770996	0.65
624.1528931	0.11
625.3469849	0.59
627.1051025	0.17
629.5512085	0.08
638.6336060	0.47
639.4216309	0.85
640.4797974	0.17
642.5883179	0.13
656.8846436	0.08
658.3920288	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0672
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
102.9203415	0.09
119.0171661	0.07
129.0431213	2.45
134.0984650	0.86
146.9890442	5.47
148.8728943	0.24
160.0622864	0.23
163.0338440	1.45
172.8214569	1.82
173.8533020	0.09
175.0451355	0.74
190.9345093	100.00
193.0774231	9.37
205.1362762	0.07
209.0002136	85.83
224.9459229	0.31
229.9530640	0.23
231.2096558	0.21
235.1010437	0.14
249.1697083	0.10
282.9121094	0.10
283.5217285	0.14
291.7829590	0.09
297.1231079	0.16
307.4457397	0.06
309.1571655	0.30
309.9989929	0.19
310.9499207	0.07
319.2016907	0.08
327.0306396	0.07
337.0376587	9.65
337.6698914	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.1904
Annotation	Tryptoquivaline I
Peak:m/z	Relative Intensity
142.9173889	0.30
145.8565063	0.18
147.0033264	0.50
148.9130859	0.18
161.0179138	11.05
175.0132446	8.29
179.0029907	3.15
182.8929138	0.27
185.0756226	1.47
187.0637970	7.26
199.0576477	1.83
217.1649475	4.51
219.1375732	0.37
231.1975098	0.52
235.3269348	0.47
247.0794373	2.17
251.0453186	0.86
262.9719543	0.15
279.1306152	4.45
291.1802063	16.51
295.3326416	2.50
297.4505615	0.33
308.1003723	0.39
311.2186584	39.10
323.1415100	100.00
325.5686035	0.23
333.3084412	0.33
341.0994263	13.80
346.2672119	0.11
347.3700867	0.23
352.2460022	0.73
434.6721191	0.64
437.2210388	0.72
439.0182190	0.57
444.4868774	1.65
449.1578064	0.80
453.3593750	0.45
467.3876038	0.31
472.7808228	0.15
484.1550598	0.68
485.2486877	3.10
485.8541870	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.1393
Annotation	Limocitrin 7-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
177.0815430	1.38
179.1655426	0.12
189.2630005	0.17
194.9754028	9.84
201.0387421	0.10
202.6827393	0.20
218.7652588	0.21
231.2567902	0.36
253.9930878	0.48
260.9458313	1.04
282.5265808	0.79
285.3610229	0.35
286.0343628	0.51
287.1495056	2.47
288.1045532	0.32
291.1523438	0.34
301.1018066	68.57
302.0898132	100.00
303.1190186	44.59
327.2031250	10.47
329.1550293	0.23
345.1228027	25.40
347.0144653	0.12
358.1403809	0.21
365.1651001	3.40
369.1671143	15.40
381.3729248	2.10
383.1314697	10.12
385.1749878	0.48
388.7236328	1.44
389.3412476	11.02
391.3246460	0.43
392.2564697	0.12
393.1616821	2.20
395.0916748	0.22
397.3085938	0.37
400.3663940	0.41
401.2484741	0.38
403.0782471	0.47
411.1506958	14.02
419.0512695	0.57
426.3423462	0.54
428.4163818	0.62
429.0981445	0.96
430.2541504	0.20
446.8887329	0.11
453.1070557	0.89
462.8260498	1.50
464.1662598	4.84
465.0502930	3.36
470.8887939	2.14
471.6955566	0.39
478.2287598	0.54
479.0178833	0.50
485.2045288	0.48
486.2858276	1.05
489.3079224	0.47
492.4501343	0.21
497.2796631	2.45
502.2485962	0.14
505.1469727	0.28
507.3312988	0.55
515.0223389	40.32
515.6594849	1.59
519.4923706	0.17
533.0932007	88.17
533.8005981	0.73
536.4270630	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.23
Annotation	Troxerutin
Peak:m/z	Relative Intensity
226.8770142	0.12
255.2377014	0.06
269.9024048	0.08
271.1766968	0.05
295.0704956	0.09
343.2934265	0.10
397.2670898	0.04
441.3511353	0.24
459.2393188	1.48
486.3222656	0.53
563.4989014	0.06
576.4961548	0.11
579.2590942	49.10
604.9320679	0.05
632.4740601	0.07
650.0767822	0.26
650.8680420	0.30
665.3318481	0.11
722.3686523	0.07
741.2545776	100.00
741.9230957	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0937
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
113.0398560	0.09
114.9812698	0.09
117.0595856	0.14
125.0390320	6.84
128.9978943	0.89
142.9896088	2.04
161.0786133	0.82
168.8651123	0.43
172.9420776	0.13
177.9059143	0.08
186.9319458	0.39
191.1694946	0.03
193.0201874	0.61
195.2159729	0.09
204.9873047	100.00
219.2892151	0.06
223.1026306	19.02
260.9587708	0.04
265.2156067	0.06
309.1424561	0.03
323.2470703	0.04
352.0928955	0.07
353.2544861	0.09
355.2800598	0.07
363.2328796	0.04
368.2734070	0.11
381.0770569	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0673
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
111.0254898	0.22
119.0464172	0.18
128.9543152	2.53
134.0080872	0.12
146.9659119	4.66
149.1391602	0.06
159.8286133	0.12
163.0617371	2.43
173.0686188	1.69
175.0914612	0.49
190.9947205	100.00
192.9909363	3.23
209.0840149	71.62
231.3219910	0.05
277.3250732	0.06
293.3478394	0.60
310.1998291	0.33
337.1565552	9.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1255
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
157.7917328	0.10
159.1824036	0.11
160.3091278	0.08
173.0029297	6.43
173.7407837	0.11
175.0901337	1.86
179.0745850	0.09
191.0440674	10.41
193.0202637	12.76
199.0943756	0.28
202.0576172	1.29
209.3363800	0.25
217.1504974	0.46
218.1644440	0.39
222.9708405	0.24
232.8964233	1.23
242.0243225	0.19
243.1667328	0.09
249.4279480	0.08
259.1948242	0.37
261.1257629	5.43
301.0375977	0.11
305.1734314	1.07
306.2380371	0.29
308.4105835	0.14
323.1763306	12.65
337.1610107	0.22
348.9893799	2.91
354.4913330	0.59
367.0884399	100.00
385.1382446	7.57
399.3563843	0.34
415.3003540	0.11
417.3376465	0.74
433.1742554	0.44
441.0484009	0.26
443.4539795	0.59
445.2182617	0.19
457.1778564	0.11
461.1611328	0.58
466.3442993	0.20
472.2049561	0.54
473.4550171	0.30
477.4274292	0.83
479.4159546	0.43
499.4524536	0.34
516.6624756	0.30
533.6576538	0.64
543.0316772	2.96
562.5046997	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3149
Annotation	Unknow
Peak:m/z	Relative Intensity
167.9908600	0.11
224.1330872	0.07
233.4872284	0.05
242.1542053	0.52
253.1604309	0.17
254.1154938	0.03
255.2336273	0.11
275.3265686	0.05
277.2797852	17.89
278.2999878	0.37
279.2344360	0.50
280.4712524	0.04
324.4234009	0.02
343.2523804	0.02
344.1816406	0.03
365.2003784	0.04
386.3922119	0.06
457.4559326	0.02
459.5185547	0.01
502.3147583	100.00
503.2734985	0.29
513.2002563	0.06
515.3767700	0.22
548.1544800	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0725
Annotation	Unknow
Peak:m/z	Relative Intensity
101.0670624	0.14
102.7219391	0.24
112.9639816	0.17
119.0929108	0.22
124.7693787	0.02
130.8742981	2.09
143.1256256	0.14
148.9422455	100.00
161.0638123	0.20
178.9719238	0.80
191.0795288	4.53
193.1800690	0.06
278.2363281	0.19
279.2341309	0.11
280.0914307	0.45
281.0420227	0.02
295.1605835	0.18
310.2111816	0.06
322.3994751	0.12
323.0314941	1.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.17
Annotation	Raloxifene
Peak:m/z	Relative Intensity
146.5728912	0.06
147.9671478	0.05
151.9185638	0.06
162.0823975	0.02
165.9859009	0.35
166.6645813	0.15
170.8409882	0.05
175.2418671	0.03
176.8406067	0.02
179.1467285	0.15
182.8346558	0.03
195.3187256	0.05
197.1027679	0.03
207.0430603	0.18
208.2173462	0.11
211.1334839	0.02
212.8718872	0.23
227.9704132	0.10
230.8899231	0.07
255.0570679	0.05
257.1379700	0.04
259.9270630	0.11
261.1357422	0.11
262.1287231	0.07
272.4105530	0.03
275.1011658	0.04
280.3054199	0.10
287.9472351	0.01
293.0686035	0.13
294.2861938	0.07
301.2309875	0.34
304.8761902	0.08
308.1174011	0.03
309.0522156	0.23
310.1096497	0.21
311.1098633	0.12
312.1835938	0.11
319.3930054	0.17
320.2272949	0.16
327.1283569	100.00
327.7598267	0.24
333.2882080	0.09
334.7492676	0.07
341.3832397	0.14
343.5525818	0.24
345.0606384	17.03
345.6919861	0.16
359.1113892	0.04
369.1305542	0.05
378.2442932	0.07
384.4700928	0.09
386.9006348	0.07
389.4298401	0.07
397.3147278	0.03
402.1857910	0.04
410.4137573	0.02
412.3209534	0.25
417.0935974	0.06
428.1907043	0.58
429.3034058	0.25
430.2652283	0.78
435.3083191	0.06
438.1318665	0.23
442.1996765	0.02
456.2358093	11.86
457.1415710	0.02
464.1003723	0.10
474.1584167	0.04
480.6907654	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1512
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
190.9507904	0.08
220.9544983	0.05
233.0224304	0.02
252.2540894	0.06
274.9927368	0.04
293.1188049	0.06
294.9633789	0.02
297.3550415	0.22
298.1513062	0.09
307.1079102	0.07
310.7400818	0.09
311.3541870	0.18
311.9960938	0.03
323.1306763	0.29
325.1894531	0.71
326.2632446	0.28
331.3335571	0.06
335.2535400	0.54
336.0521851	0.13
337.1488037	0.18
341.2997437	0.09
342.0993042	0.05
345.2918701	0.11
347.2763062	0.11
349.3053589	0.12
351.1814575	0.22
353.1555786	44.22
354.2142334	10.83
365.1443481	0.88
366.2553101	0.18
367.2163696	0.06
368.2904053	0.04
375.3772583	0.02
377.3034058	0.15
379.4949951	0.05
383.1732178	25.38
384.2720947	7.06
392.2075195	0.06
393.2086182	0.06
395.2312622	1.78
396.3999023	0.87
397.2232666	0.59
398.3789062	0.54
407.3554688	0.12
408.3490601	0.09
409.2799072	0.60
410.6129150	0.04
412.2030640	0.02
413.2586060	3.95
414.1873779	1.32
419.2547607	0.87
420.0964355	0.05
421.3051147	0.04
423.2979736	0.03
425.2852173	1.38
426.2231445	0.65
427.1421509	0.44
431.0967407	0.03
437.2202148	1.44
438.2235107	0.40
443.4743652	0.04
444.3229370	0.18
450.1503906	0.13
453.3018188	0.15
455.2590942	5.50
456.3015747	1.18
458.3988037	0.03
465.2507935	0.10
467.2075195	0.69
468.1152954	0.16
471.2698364	0.40
473.2164917	100.00
474.2070923	23.09
474.8567505	0.04
483.3367310	0.11
485.1596680	2.43
486.2788696	0.67
487.4209595	0.04
489.4548340	0.08
497.3920288	0.07
499.4393921	0.17
501.1574707	0.04
503.2088013	32.56
504.2852173	7.11
509.2411499	0.05
511.3225708	0.11
515.2482300	3.08
516.3762817	0.61
517.2135620	1.14
518.4425659	0.27
520.4454956	0.04
521.6771240	0.04
527.2971191	0.09
529.2596436	0.03
533.3367920	2.61
534.2509155	0.76
539.2687378	0.28
545.2360229	1.88
546.1707153	0.39
547.2701416	0.04
557.2825317	1.79
558.1688843	0.34
563.2175293	0.19
564.2866821	0.06
575.2444458	9.21
576.2750244	2.48
594.3129883	0.48
595.3466187	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1113.3063
Annotation	Unknow
Peak:m/z	Relative Intensity
327.8641052	0.44
329.1739807	0.47
331.0713196	1.60
332.1082458	1.01
346.9962769	0.29
359.9506531	0.40
361.1321411	10.16
362.1170654	6.75
371.8578186	0.44
382.8260498	0.06
386.9983826	0.25
397.6664429	0.21
399.3201294	0.28
422.0046387	0.08
423.3133545	0.21
451.3815308	0.28
452.4112854	0.49
469.3739624	0.34
470.1575928	0.57
563.0587158	0.18
596.0609131	0.07
599.1691895	0.50
604.2569580	0.55
605.4703979	0.12
606.2019043	0.54
608.1831055	0.32
616.0574951	0.21
631.1289062	0.84
632.3043213	0.06
649.4932861	0.95
650.2808228	0.56
667.2540283	0.51
667.8780518	0.07
668.6240234	0.37
681.3305054	0.16
682.7231445	0.57
699.9802246	0.12
710.3270264	0.53
740.3181763	0.48
753.0307617	0.45
757.4453125	0.50
758.3751831	0.83
764.1629639	0.72
769.5274658	0.61
770.2221680	0.55
775.2501831	3.81
776.2654419	4.29
788.6270142	0.31
793.0684814	2.20
794.1856689	1.25
796.1655884	0.13
811.1654053	0.33
812.3392334	1.33
1060.2194820	0.12
1114.1528320	100.00
1114.8923340	1.44
1115.5590820	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.1508
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1607971	0.15
149.8058777	0.12
173.1108398	0.41
175.8368835	0.04
191.2240448	0.23
201.1166077	0.06
208.1461334	0.10
223.3421936	0.09
235.2375488	0.06
236.9146423	0.17
260.8456421	0.61
275.2775879	0.05
292.6738281	0.19
295.0413818	0.07
309.1853638	0.36
310.8908081	0.18
313.2302856	0.73
321.4160767	0.21
339.6982117	0.14
353.2450256	100.00
354.8413391	0.57
355.4552917	0.04
357.3047180	0.20
363.1505432	0.48
379.0420837	0.40
381.2167969	0.59
384.0928345	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1695
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
177.1301575	0.03
196.2407227	0.08
203.1867676	0.04
267.2570496	0.03
271.1034546	1.06
272.0644531	0.32
283.2029114	0.32
284.0397339	0.22
295.0753174	0.51
296.0543213	0.13
313.1130981	6.96
314.2162476	1.47
324.489624	0.11
335.0757446	0.01
337.1107178	2.78
338.0695801	1.09
341.4118042	0.03
349.3704224	0.02
350.3972778	0.02
352.1223755	0.02
355.0636597	0.04
361.3062134	0.09
362.0780029	0.04
367.1279297	4.15
368.1116333	1.26
379.2055664	1.85
380.3120117	0.39
381.1436157	0.06
397.151062	2.45
398.1861572	1.17
403.3723755	0.02
405.3057861	0.01
411.4940796	0.02
415.1612549	20.56
416.15448	6.68
417.0303955	0.21
418.3065796	0.09
419.541748	0.01
422.2922974	0.01
423.3047485	0.13
426.0529175	0.03
427.4063721	0.07
433.121582	100.00
434.171875	28.87
441.3037109	0.24
457.3022461	0.19
459.064209	0.60
460.0615845	0.13
461.4348145	0.02
464.951355	0.01
470.4100342	0.01
476.5549316	0.05
477.2687378	0.03
481.3826904	0.04
483.6063843	0.05
484.2648315	0.07
489.5023193	0.03
495.5127563	0.04
496.359436	0.01
507.2719727	0.20
517.5209351	0.02
525.3726196	0.14
526.1882324	0.07
530.3314819	0.06
535.8528442	0.07
543.1965332	0.67
544.6061401	0.05
561.2213745	1.20
562.2043457	0.71
565.5597534	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	618.86
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9739532	0.42
228.8657074	0.31
229.8401794	0.13
230.8398743	0.22
232.0419922	0.06
244.7729034	0.03
272.9749451	2.07
274.0931702	0.99
274.9856567	1.67
275.8462524	0.40
277.1077271	0.12
289.0548096	0.09
375.1860962	0.06
386.9743652	0.56
388.0113525	2.35
389.1384277	5.68
390.1199341	0.71
391.0548096	1.07
415.1741333	0.24
418.7717285	0.35
443.1411743	3.28
458.9351196	10.03
460.2882690	0.06
489.2005005	0.25
500.9477539	0.04
501.9784546	4.86
502.9042969	8.00
503.9705200	13.87
505.0190430	9.23
514.9652710	0.08
543.9782104	0.21
561.5275269	0.05
571.6010132	0.22
572.9017334	100.00
573.9776001	0.48
574.8677368	0.80
577.9983521	0.39
586.9182129	0.24
600.1005859	0.04
601.3202515	0.04
617.8032837	0.17
618.7477417	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8945
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9802094	0.25
147.0586700	0.05
158.9608765	0.13
174.9959412	3.68
199.1260223	0.03
215.1243896	0.01
216.8555145	0.03
231.0415649	0.01
243.1823730	0.02
245.0369568	0.23
260.8960571	0.19
273.0301208	1.68
273.9013062	0.23
275.1554565	0.03
277.0600586	0.09
286.2993164	0.01
286.9254761	0.01
287.9188538	0.12
289.0033875	29.19
291.0897827	0.01
303.2043762	0.02
304.8912354	100.00
307.1122437	0.03
328.2469482	0.01
328.9381714	0.12
330.0718994	0.21
333.0709839	0.02
345.0152588	0.21
345.8138123	0.02
346.6665039	0.05
347.4548340	0.03
351.3351746	0.01
354.8858032	0.01
362.0530090	0.03
362.8765564	0.05
372.6037903	0.13
373.9814148	0.20
374.9234314	0.28
378.9775085	0.01
390.4825745	0.02
391.1177979	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1192
Annotation	Quinic acid
Peak:m/z	Relative Intensity
108.9509506	0.05
115.0210419	0.01
126.8541718	0.15
128.9986267	0.03
155.0581207	0.04
170.9976044	0.10
173.0481262	0.21
189.0399475	0.03
191.0013428	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1926
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9447479	0.17
134.7635803	0.05
136.9437408	0.12
138.1817474	0.09
142.9758911	1.10
148.9331665	0.20
151.3226776	0.04
152.0700684	0.14
153.0875854	8.96
158.9111633	0.85
160.9937744	10.21
165.1007385	0.15
167.0387573	0.09
177.2124939	0.07
178.9858093	11.39
187.2022095	0.06
190.5250092	0.33
205.1372070	9.03
219.1496887	0.23
222.9701538	14.36
223.7018585	0.32
224.9452209	3.28
228.9821472	0.13
233.1223145	0.09
260.4408875	0.19
265.3172607	0.13
285.1123962	0.10
306.9065857	0.11
315.1363525	0.06
329.5014648	0.05
341.1325684	0.60
351.2777710	0.18
367.3285828	0.67
383.5090637	0.26
385.2479553	100.00
387.1123352	0.16
399.2137451	0.05
410.9963074	0.13
412.3721008	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.2204
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
216.1235046	0.05
219.2026062	0.08
230.7751617	0.03
233.3209076	0.05
243.0920410	0.03
247.0047455	0.07
256.0513916	0.16
257.0895996	0.22
267.4713745	0.09
273.0885620	0.16
274.0422974	0.40
275.3229370	0.12
276.1525269	0.03
284.2694092	0.13
285.3987427	0.05
295.3646545	0.23
313.2868042	1.59
314.3187866	0.13
316.9628296	0.05
322.1443787	0.23
323.0034790	0.02
324.3834229	0.04
327.9748535	0.09
329.1522827	0.10
337.2233887	0.26
338.2612915	0.13
345.2363892	0.47
346.1769409	0.56
347.3148804	0.28
364.7968140	0.03
367.3442993	0.28
368.2864990	0.24
379.7406616	0.19
380.4288330	0.15
397.1730957	0.13
398.9147339	0.03
409.2935791	0.03
411.3050537	0.08
415.0483398	0.56
416.1486206	0.39
417.1576538	0.05
421.2766113	0.31
421.9747314	0.04
433.1531372	0.28
434.0634155	0.34
445.2800293	0.28
446.3028564	0.27
457.1854248	0.09
468.0782471	0.08
474.2799683	1.22
475.2922363	5.66
476.2844849	3.22
483.1243286	0.07
494.3800049	0.26
497.2295532	0.04
499.2844238	2.03
500.2581177	1.00
501.5420532	0.08
510.3143311	0.03
512.2175903	0.10
518.3562622	0.04
523.1786499	0.08
524.1114502	0.10
529.1701660	5.12
530.2825317	4.20
541.2859497	1.91
542.3034058	0.68
559.2261963	2.39
560.2135010	1.43
561.2981567	0.18
577.2416382	25.32
578.2382202	13.66
579.2401733	0.42
580.2639771	0.31
580.9472046	0.16
584.0896606	0.12
586.1720581	0.02
595.2061157	100.00
596.2138672	34.46
596.8671875	0.36
601.5797729	0.04
604.2841797	0.03
612.3678589	0.25
613.3063354	0.03
619.3469849	0.41
620.2496948	0.13
621.3609619	0.66
622.5953369	0.03
633.4990845	0.05
639.4149780	0.06
645.3353882	0.18
655.3902588	0.17
656.4768066	0.05
657.1777954	0.06
669.4755859	0.30
675.4920044	0.46
676.1077271	0.06
677.2048950	0.06
687.2208862	0.67
688.4931030	0.34
705.5525513	0.47
706.3049316	0.18
723.2904663	3.27
724.2510986	0.78
742.0853882	10.78
742.6871948	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	168.1015
Annotation	a-Methyldopamine
Peak:m/z	Relative Intensity
121.9470215	0.01
149.9666595	100.00
150.7925415	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.0547
Annotation	Unknow
Peak:m/z	Relative Intensity
94.9480209	2.17
96.9647217	1.46
99.0333633	0.11
101.0370255	1.10
106.9001770	0.12
108.8326874	0.10
113.1814270	0.25
114.9795227	0.05
120.9458466	0.08
122.9904709	0.45
125.0153046	6.24
127.0278015	1.48
131.9505310	1.19
134.9626770	1.34
136.9665222	0.65
143.0373840	0.26
146.1582794	0.96
147.0671387	0.18
148.9850464	4.36
150.9575500	0.06
152.9338379	5.21
159.2178345	0.05
160.9877014	0.13
165.0075989	16.72
167.1421204	0.67
170.8671570	0.08
176.9624023	0.31
179.0193634	0.46
183.0802460	0.08
189.0079193	1.58
196.9952240	0.18
207.0824280	10.57
225.0020142	100.00
242.9650879	0.07
257.4548950	0.12
288.8863220	0.18
299.0889893	0.80
317.1811523	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1069.2853
Annotation	Actinoplanone D
Peak:m/z	Relative Intensity
750.4223633	0.04
767.6260376	0.01
922.5278320	0.08
1024.7299800	0.09
1051.1402590	0.04
1069.2629390	100.00
1069.9444580	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.11
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0070801	0.06
199.8816223	0.05
202.9057922	0.15
211.0731049	0.08
214.7110138	0.04
227.1018524	0.06
237.1721191	0.05
240.1134338	0.19
248.1149902	0.09
254.0168304	0.67
254.7501373	0.41
256.1499023	0.05
267.8749390	0.11
271.9131165	0.40
273.0955200	0.53
273.8430481	0.20
282.1226196	0.17
285.0294800	0.04
286.9780579	0.05
290.1440430	0.27
290.8340454	0.08
299.0430908	0.12
304.1060486	0.25
304.7689819	0.30
306.0586548	0.37
307.0585938	0.43
315.0196533	0.05
319.0406494	0.37
320.0780334	0.89
323.0078735	0.13
329.3082275	0.11
332.1984253	0.71
333.0108643	0.91
335.0993652	0.45
340.0059204	0.11
340.9489136	0.79
343.4694824	0.40
348.0463257	2.03
349.0346069	2.10
350.2856445	0.09
358.8698730	0.10
361.0352783	0.45
364.2357178	1.15
365.2543335	0.20
366.7639771	0.11
375.8558960	0.30
378.8352051	0.46
385.1563110	0.07
393.0178223	0.68
394.0975952	27.85
395.0513306	51.27
396.1020508	2.73
408.8741455	0.21
420.2534180	0.61
421.1000366	8.48
422.0435791	1.66
438.0559082	17.61
439.0686035	100.00
440.1084595	7.74
448.2451782	0.13
454.7584229	0.11
469.1934814	0.12
479.7258301	0.14
500.4296265	0.38
510.9205933	0.11
512.7314453	0.07
515.4573975	0.09
535.5921631	0.76
541.9547729	0.17
571.0743408	0.33
572.4672241	0.26
586.7354126	1.28
613.1026611	0.47
614.0386963	0.06
640.2348022	0.28
683.8736572	0.08
685.2515869	0.34
686.0203857	0.86
876.9155273	0.13
1253.9495850	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.2217
Annotation	Unknow
Peak:m/z	Relative Intensity
201.2040405	0.11
204.1140900	1.80
206.0511322	0.31
210.9965363	0.13
222.1968384	0.16
227.9987946	0.85
240.1357422	0.39
252.1571960	0.74
270.0668030	2.67
288.1319580	7.04
306.2229919	8.49
320.0293579	0.34
321.3198242	0.16
324.1380615	100.00
324.7514038	0.16
338.1402588	0.35
356.7866821	0.11
362.9038086	0.29
429.2265015	0.11
482.1787720	0.35
486.2312622	0.13
496.7991943	0.10
500.2675781	1.28
514.2247314	0.14
518.1483765	5.03
518.7634888	0.13
524.4545288	0.26
525.4767456	0.37
529.7020874	0.32
534.3988647	0.07
589.9350586	0.18
596.2791748	0.14
601.2466431	0.18
606.4863892	1.46
607.4895630	1.13
614.4603882	0.83
634.3412476	0.19
644.4470825	0.08
660.2825317	0.46
662.1098022	0.07
664.3099976	0.24
680.1207886	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
175.7551727	0.05
200.1752014	0.12
214.9812317	0.31
217.1578674	0.16
233.1182556	0.06
245.0675049	0.07
246.9561615	0.06
270.2418518	0.03
271.9360962	0.07
272.9736938	3.45
273.9723206	1.04
275.0407715	2.21
276.1352844	0.05
288.9960022	12.24
289.9175415	3.79
291.0722961	3.98
387.1514282	0.81
388.0333862	2.08
389.0550537	2.23
401.2811890	0.04
402.9761963	29.62
403.9769897	21.16
404.9279785	14.37
458.8533936	0.08
470.7196655	0.09
500.9431152	0.07
501.9662476	0.55
503.0615845	0.80
514.8689575	0.12
516.8944092	44.95
517.9014282	100.00
518.8637695	68.41
519.5338135	0.14
529.9382324	0.05
542.9707642	0.13
547.0991211	0.11
559.0523071	0.12
561.1278687	0.04
562.8779907	0.05
564.7063599	0.03
566.1109619	0.04
576.7338257	0.39
586.0654907	1.13
587.0798950	0.71
589.0482788	0.31
600.0106201	0.13
604.7782593	0.35
608.9003296	0.03
613.8015137	0.30
615.1234131	0.08
632.9150391	2.25
746.0101929	0.08
746.6934204	0.17
761.9924927	0.22
858.9121704	0.21
874.8244629	0.03
988.5081177	0.33
989.3505859	0.29
990.9655762	0.33
1104.7983400	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	457.2062
Annotation	Glochidacuminoside C
Peak:m/z	Relative Intensity
132.9943237	0.14
134.8824768	0.25
136.9704437	0.41
143.1057129	0.05
145.1054993	0.20
145.7790985	0.02
147.0334778	0.37
149.0632019	3.46
151.0648193	11.74
153.0708923	0.04
158.2457123	0.10
159.0446777	0.07
161.0572968	0.18
163.0816193	0.18
165.1064453	11.06
168.9388428	0.06
173.1394196	0.51
175.2394714	0.16
181.1807709	0.10
183.9526062	0.07
189.3443298	0.08
191.0413513	2.14
193.0502014	3.53
193.7631989	0.02
195.0659790	0.03
201.1171875	0.23
203.0281982	0.02
207.1626129	0.23
209.0782776	100.00
213.0980835	0.10
214.9147186	0.09
215.7979126	0.04
219.0236816	0.07
229.0708923	0.03
230.8652039	0.09
232.6385651	0.22
233.3609467	0.04
234.9946442	0.07
237.1921692	0.02
241.1123962	0.08
245.1063843	0.05
247.0449524	0.73
247.9361877	0.02
249.1672363	0.15
257.1327209	0.03
260.9028625	0.02
265.0593262	0.29
267.1102905	0.09
269.1188354	0.04
271.3624878	0.02
273.3111267	0.09
276.5262451	0.05
283.0808411	0.10
286.9969482	0.05
293.2530518	0.07
294.8735046	0.08
297.1533813	0.04
299.4058228	0.09
305.1410217	0.51
307.5040283	0.02
312.2049561	0.03
313.2798462	0.06
314.9702759	0.19
315.8352661	0.04
317.1455688	0.24
320.4235840	0.04
323.1752014	0.22
325.1371460	0.16
327.2548218	0.07
331.3820496	0.04
333.0115967	0.04
335.0608521	0.08
342.0283508	0.02
343.1186523	0.10
344.0869446	0.04
353.1967773	0.08
358.9614258	0.03
366.1436462	0.04
367.2670288	0.23
368.1857910	0.12
369.3240967	0.02
370.3933105	0.05
371.1217957	0.02
373.4613342	0.05
377.3274841	0.35
380.9746399	0.22
383.5070801	0.12
385.3648376	0.07
391.6974182	0.02
393.0157776	0.18
395.1213074	0.59
397.1771240	0.07
398.1775513	0.02
399.2623596	0.10
400.8500671	0.10
403.3690491	0.36
410.8610535	0.05
413.1315308	1.81
414.3760986	0.06
421.1877747	5.82
424.1084290	0.09
428.3800964	0.17
438.8965149	4.83
440.0786438	0.29
441.0050964	0.10
455.4084473	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1339
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
211.2884674	0.01
221.8845520	0.02
223.0230103	0.02
231.1130524	0.01
271.0000000	0.02
274.1658936	0.01
285.1976318	0.02
288.2106934	0.01
299.2067871	0.03
301.0264893	0.12
313.4106445	0.02
316.1045532	4.84
331.1147461	100.00
333.3408203	0.03
347.2093506	0.04
361.2975464	0.11
373.1922607	0.08
375.0380859	0.02
415.1317749	0.02
427.0963745	0.01
433.3542480	0.04
439.2772217	0.01
450.3110962	0.01
474.7503052	0.01
480.9236450	0.04
492.9345703	0.39
493.5882568	0.10
517.1220093	0.02
535.0301514	0.38
542.4570923	0.01
543.4031372	0.02
547.2605591	0.07
560.2138062	0.07
561.2265015	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.1434
Annotation	Unknow
Peak:m/z	Relative Intensity
189.1565704	0.97
192.2960052	0.12
193.0132751	3.36
199.9892578	0.27
201.1860199	0.63
202.0014343	0.84
203.0018311	0.22
217.0282135	1.74
218.1306610	0.11
223.2278137	0.09
227.0990448	0.08
228.2208099	1.13
229.0389099	0.07
233.1662598	2.89
242.2700043	0.27
243.0530090	0.19
245.9687195	0.18
248.9102325	0.10
258.7691040	0.20
261.1508179	3.59
277.1109924	0.48
282.9934387	0.08
286.1663818	0.41
287.1426392	0.40
294.8806458	0.27
301.1277466	0.06
305.0772095	3.18
308.1771240	0.10
310.9058838	0.32
314.3026733	0.04
314.9777527	0.06
323.1511841	0.15
325.1730347	0.08
326.1156006	0.37
327.2412109	0.06
329.0968018	4.78
330.1459961	0.50
331.2892761	0.07
333.2059326	0.07
341.1394653	0.10
342.1046753	0.21
343.1697998	1.41
344.1130371	10.05
345.2175903	4.66
349.1834106	1.49
350.2535400	0.09
351.4691772	0.18
354.0935059	0.10
359.1608887	46.93
366.0352173	0.18
367.0720825	0.73
372.0359497	0.13
373.4244995	0.36
381.1068115	0.32
381.7101440	0.11
385.9458618	0.22
387.2373047	0.05
401.1755981	5.04
406.0029297	0.09
410.2561646	0.08
423.7634277	0.06
427.1306763	1.25
435.2316895	0.11
443.2476196	0.06
445.4806519	0.05
446.3969727	0.12
455.2380371	0.12
464.3590698	0.11
470.9684448	2.26
471.5964966	0.07
485.3411255	0.12
488.1744995	0.09
488.9462280	1.40
490.3654175	0.09
500.9506836	0.15
503.3816528	2.29
506.3319092	1.04
507.2276611	1.49
517.5126343	0.09
518.3193970	0.10
521.1582642	100.00
521.7777100	0.97
532.0968628	0.22
534.5001221	0.30
542.9805298	1.62
549.3039551	5.15
563.1989136	66.99
563.8675537	0.67
565.2090454	0.20
575.1802368	0.10
579.1044922	0.09
584.2214966	0.38
586.5578003	0.23
589.3270874	0.93
591.3952026	0.21
599.1191406	0.16
603.1862183	3.70
605.5979614	0.18
615.2672119	2.54
618.3833008	0.13
623.6104126	0.18
626.4085693	0.11
628.6774292	0.40
633.4030762	0.45
637.9514771	0.09
647.3536377	0.47
649.3786621	0.65
650.5250244	0.14
665.0697632	15.17
665.9286499	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0771
Annotation	Acerosin
Peak:m/z	Relative Intensity
131.8502197	0.15
136.1982422	0.09
144.5612488	0.06
147.0178833	0.26
150.8922424	0.80
167.0103760	0.05
190.9367371	0.08
197.0089264	0.12
207.0438995	0.06
213.0300293	0.05
218.1739502	0.09
221.1187744	0.04
233.6023560	0.07
242.0305176	0.16
270.8497620	0.73
274.1898193	0.13
287.2272339	0.18
295.8577881	0.12
296.8712769	0.06
300.1770020	0.22
312.4603882	0.17
313.1538086	0.29
314.9670410	0.13
315.7465820	0.10
316.8252258	0.06
329.1451416	0.29
335.3184814	0.11
340.9978027	0.36
341.6108704	0.04
344.1093445	100.00
345.0110779	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	385.185
Annotation	Jatamanvaltrate M
Peak:m/z	Relative Intensity
116.0300598	0.14
117.0848541	0.14
118.9683914	0.04
120.9880371	0.56
123.1112976	0.17
132.8506470	0.11
135.1322632	0.31
137.0079498	6.87
139.0911102	0.77
143.2659607	0.07
147.0588837	0.65
149.0364380	0.83
149.7761536	0.23
156.8616333	0.43
159.1356964	0.40
160.9305115	0.18
162.9723511	2.86
166.9832458	0.35
174.9532776	1.27
177.1658325	2.12
177.9067383	0.08
187.1247559	0.92
191.0511932	0.17
205.0224304	0.80
207.1259918	0.31
217.1559143	0.22
219.1059570	0.05
223.0579987	100.00
224.0267029	0.21
231.1516724	0.48
244.2758179	0.20
246.2772522	0.15
249.0241089	0.22
251.3088684	0.29
252.1186523	0.40
270.2159424	0.43
272.1318054	0.33
287.8349609	0.79
296.2525635	0.09
300.5661011	0.12
301.2254639	0.90
304.2774658	0.21
308.0501709	0.25
308.8905334	0.33
312.6111145	0.35
318.8833618	0.50
320.9945679	0.08
322.1683350	0.16
325.0717773	0.07
327.4739990	0.30
329.3529968	0.09
330.5152893	0.24
331.3689270	0.30
335.1596985	0.11
338.3667297	3.86
339.3190308	2.43
341.3294678	0.11
343.0675049	0.29
344.1965637	0.10
345.3011475	0.21
348.9390259	0.73
351.8738708	0.24
353.0679932	0.54
355.7917786	0.30
357.0778198	0.53
366.1448669	1.93
367.2546692	3.67
368.3865662	0.22
370.2470398	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.2914
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
135.0601959	0.02
139.2051392	0.04
141.9724731	0.04
143.2528534	0.01
145.2488556	0.03
151.0313416	0.02
157.1001282	0.02
161.0074158	0.03
163.1762085	0.06
165.1183167	0.02
172.8350525	0.01
179.1787415	0.04
180.1310272	0.05
181.0492554	0.01
186.8231354	0.05
195.3597107	0.01
198.1175842	0.05
199.3045349	0.01
201.1607361	0.03
203.0915222	0.01
215.9895020	0.10
217.1826172	0.04
245.3513794	0.08
247.1807556	0.06
263.2230835	0.18
283.3943176	0.01
306.2699890	0.30
310.3155518	0.02
319.3560791	0.12
333.0255737	0.01
337.2572327	100.00
380.5605164	0.05
417.2704163	0.11
435.3905945	0.06
449.1036377	0.13
460.2868958	3.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.186
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
185.2105408	0.05
227.0337219	0.01
231.9829102	0.06
234.9329834	0.04
244.1259308	0.04
271.0757446	0.17
275.1584473	0.01
299.9813843	0.11
303.3929443	0.03
313.0560913	0.06
314.2721558	0.03
316.1950684	0.08
318.9566345	0.02
328.1589966	2.26
331.0395508	5.14
331.6771851	0.01
335.3043213	0.06
337.0968628	0.11
343.2410889	0.12
346.2262573	4.41
348.0486450	0.08
359.2221680	0.02
361.1655273	100.00
361.7655640	0.39
364.0509644	0.05
365.2616577	0.10
417.3541870	0.09
418.4131470	0.12
427.3142090	0.09
460.2929688	0.03
466.1399536	0.01
475.4767456	0.02
482.9152222	0.08
485.8435059	0.02
487.2813110	0.04
502.0549316	0.06
503.0195923	0.02
505.5526733	0.07
509.1666260	0.05
519.2296753	0.07
520.3368530	0.40
521.4945679	0.04
523.2316284	0.30
561.0277710	0.02
581.3580933	0.03
600.0167847	0.11
605.2021484	0.54
606.3853760	0.08
612.9389038	0.11
631.2942505	0.17
634.1780396	0.03
640.2252808	0.06
647.8874512	0.02
649.1149292	0.50
649.8731079	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.1624
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
195.2104645	0.13
199.3005066	0.07
207.5048218	0.14
208.1169434	0.10
227.2508240	0.17
265.4051514	0.24
271.2003784	0.28
275.3024902	0.26
283.8397522	0.14
293.2123108	0.87
295.2402344	0.28
296.2692261	0.65
297.2433472	0.57
299.0984497	2.52
301.0575867	0.14
303.3475342	0.26
305.1928101	1.56
314.0861816	15.14
315.1257324	1.67
323.2338867	0.41
323.8581543	0.79
327.0882568	0.43
329.1780396	61.78
330.3020020	0.44
331.1905518	0.53
337.3435059	0.29
339.0809937	0.15
341.2503662	0.08
342.9440918	0.15
344.0557251	0.19
351.2955322	0.34
353.1742554	0.13
356.5571289	0.08
359.3112183	0.85
360.2316895	0.34
363.2585449	0.09
367.0517578	0.12
371.2057495	9.41
388.0468140	0.32
389.4233398	0.48
395.0509033	0.68
401.0103149	0.18
405.2210693	0.18
407.5872803	0.16
410.3831177	0.17
428.2344360	0.65
439.2357788	0.10
441.1585083	0.46
444.1033325	0.18
451.2298584	0.37
453.1665649	0.20
454.2848511	0.37
458.4663086	0.58
459.2837524	0.50
460.3117676	0.16
471.1484985	0.39
473.3225708	0.81
476.4331665	0.12
482.4885254	0.20
488.2636108	0.11
489.2549438	0.28
491.2088013	100.00
491.8348999	0.14
501.4279175	0.08
504.1234131	0.28
515.3631592	0.39
516.4550171	0.31
519.1867676	0.79
521.3937378	1.01
528.2891235	0.26
531.5034790	0.22
533.2167969	67.85
533.8442993	0.22
539.4798584	0.45
544.3613892	0.08
546.4824829	0.32
549.2114258	0.31
561.4063721	0.35
562.4373169	0.09
564.6331787	0.17
570.2058105	0.12
571.5304565	0.10
572.7842407	1.30
573.3862915	10.25
574.6282349	1.09
576.7214355	0.28
584.4850464	0.30
585.3785400	0.31
588.3928833	1.62
589.4165649	0.88
590.6655273	1.46
591.5314941	0.29
593.5126343	0.11
596.5253296	0.22
598.5048828	0.39
599.2531738	0.29
602.4280396	0.14
603.4816284	0.16
616.1446533	0.30
617.4571533	1.35
620.4976807	0.43
635.1491089	4.71
636.2752686	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.1306
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
147.0418701	0.21
153.0573578	0.19
153.9784546	1.12
154.9664612	0.13
164.9502411	0.35
172.8668365	0.07
182.0227661	4.63
191.0244751	2.40
194.0641632	0.16
197.0572815	17.24
198.1160583	0.15
206.9333801	0.06
209.1802368	0.15
211.9676208	1.67
223.1373596	0.05
224.0794373	0.12
227.1312103	5.51
237.1316528	0.22
239.1355286	2.20
239.9630585	0.11
248.1950684	0.16
250.1060333	0.71
251.1946411	0.14
253.1314087	0.07
257.0308838	0.03
265.1227417	3.58
265.9552002	0.15
269.1029663	0.95
280.0088196	0.26
281.0803223	0.79
293.0690918	0.16
295.1265259	1.24
299.1501465	1.66
303.7035522	0.21
310.3878784	0.17
311.4396362	0.06
317.0730591	3.29
325.0523682	0.18
339.0785522	0.11
341.1508789	0.06
342.1564941	0.04
343.4411011	0.10
347.1463013	0.75
361.2763062	0.16
365.2019043	0.09
367.0495605	0.10
371.2891235	0.23
374.1040039	0.51
385.2127075	0.22
387.3447876	0.10
389.1262207	100.00
401.1439819	2.48
404.3517456	0.05
411.3322144	0.10
413.0904541	0.39
419.1105957	24.37
419.7509155	0.04
427.4944458	0.11
429.3850098	0.03
431.1326904	0.95
447.3734131	0.10
449.1698608	1.15
455.3942261	0.52
461.0599365	0.32
463.3040161	10.82
464.0093384	0.06
465.3405151	0.19
473.2457886	0.86
479.1655273	0.15
491.1677856	7.60
491.9202881	0.04
494.3314209	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.08
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.8668213	0.22
128.9431763	1.82
144.6211548	0.23
147.0171509	2.85
172.9138794	2.30
190.9330139	100.00
192.9857635	0.38
193.5859680	0.06
204.2354736	0.05
209.0651093	16.40
243.0557861	0.07
305.2031860	0.05
323.2487793	0.03
349.1589355	0.29
367.0636902	7.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
229.9929047	0.03
244.1612244	0.02
245.2146606	0.07
254.7391968	0.02
258.1552124	0.23
258.9343872	0.07
273.3363342	0.09
286.1209717	5.33
287.2086792	0.24
288.260498	0.06
301.0786743	100.00
302.0785522	5.26
303.1338501	0.83
313.1571655	0.12
315.2811279	0.06
329.9102783	0.06
343.2668457	0.26
344.2782593	0.06
345.1807251	0.09
346.2371826	0.86
347.145874	0.15
355.3147583	0.09
361.1905518	1.08
367.263916	0.27
375.1135254	0.15
391.0383301	0.03
397.6330566	0.01
409.2911377	0.51
410.1446533	0.02
411.2221069	0.45
419.4302368	0.02
429.3175049	0.05
430.2192383	0.10
433.2765503	0.07
439.2188721	0.11
440.2098999	0.05
444.3023682	0.03
445.203125	0.76
446.8635254	0.27
454.5852051	0.08
463.0924072	22.10
471.5299072	0.02
530.0177002	0.07
539.7055054	0.10
542.8841553	0.08
550.4946899	0.08
563.9938354	0.06
565.4468994	0.06
571.069519	0.08
572.1126709	0.14
573.2481079	0.01
575.5779419	0.04
581.3762207	0.06
590.0744629	0.18
591.0961304	0.54
591.696228	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	312.0949
Annotation	Unknow
Peak:m/z	Relative Intensity
95.7965012	0.16
98.7128525	0.14
100.6965790	0.11
117.0816498	0.07
132.0382690	0.09
133.9360809	87.13
135.9598541	0.14
161.9666443	0.07
244.0833130	0.08
252.2252197	0.18
263.9983521	0.12
265.9929199	100.00
266.5959473	0.28
268.0799866	0.28
269.0135803	0.12
269.9136353	0.12
311.3682251	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	755.43
Annotation	Voamatin C
Peak:m/z	Relative Intensity
211.2821808	0.05
212.0965271	0.01
217.1638184	0.54
218.0935822	0.27
222.0920258	0.08
223.2532043	0.03
224.2183228	0.05
226.1135864	8.28
227.1296844	2.80
228.2162476	0.24
230.2982788	0.04
233.1251221	0.03
238.3237000	0.07
239.2233276	0.29
240.1987000	0.13
241.4324646	0.02
242.1538544	0.17
243.1392517	2.02
244.2973633	1.45
245.1024170	1.71
246.1558533	1.17
247.1735687	0.02
256.9499512	0.05
258.2509460	0.03
261.1337280	0.03
262.2202148	0.36
263.2080688	0.16
264.2359924	0.11
267.3911133	0.08
268.2828064	0.39
269.2041016	0.11
270.3682251	0.20
273.1591187	0.22
275.1618042	0.01
276.5049438	0.08
277.5312195	0.04
278.2530823	0.02
281.3148193	0.28
282.2334290	0.20
283.1659546	0.18
284.2548523	0.22
285.2977295	0.38
286.6107788	0.07
287.3284912	0.03
290.0609741	0.12
294.3047485	1.09
295.2018433	0.53
296.2188110	0.11
297.3030701	0.06
298.1389465	0.06
299.1995239	0.19
300.1678772	0.13
301.2590637	0.13
302.1333008	0.23
303.0860901	0.06
304.3030396	0.02
305.3401184	0.02
306.3993530	0.03
307.3181152	0.06
309.2939148	0.07
310.6263428	0.30
311.3215942	0.92
312.2989197	0.72
313.2301025	0.26
313.9642944	0.42
315.4691772	0.03
321.3052368	0.78
322.2541199	2.64
323.2153931	1.43
324.0706787	0.32
325.5113220	0.10
327.0856934	0.49
328.2034302	0.44
329.2865295	0.28
330.3576050	0.29
332.4822388	0.06
336.4200439	0.24
337.2943115	0.07
338.2310791	0.22
339.2435913	8.53
340.2304688	6.95
341.3475342	0.59
342.3081055	0.15
343.4291382	0.28
349.4850464	0.08
350.2558594	0.04
351.4274902	0.33
352.3271484	0.24
354.4226990	0.12
355.4638062	0.18
356.2379150	0.26
357.4224854	0.12
358.4154663	0.33
359.3272705	1.16
360.2414551	0.63
361.2194824	0.46
362.8397217	0.05
363.5193481	0.07
366.2264404	0.47
367.2501221	0.91
368.2854004	0.85
369.4299316	0.49
370.1688843	0.09
372.4401855	0.05
373.3099365	0.08
374.3667603	0.16
377.0715942	0.02
378.5067749	0.29
379.3300171	0.58
380.2720337	0.74
381.3458252	0.27
382.3593140	0.12
383.5579224	0.10
384.3500977	0.02
385.2398682	0.18
386.4061279	0.34
387.1615601	0.61
388.2234497	0.87
389.2068481	0.15
394.2955322	1.40
395.2539062	1.74
396.1614990	3.16
397.3161621	2.87
398.3776245	0.60
399.5441895	0.20
402.1216431	0.07
403.4688110	0.09
407.3512573	0.24
408.4940796	0.21
409.2138672	0.07
411.8983154	0.38
412.8154297	0.19
413.4707031	0.70
414.3669434	0.65
415.2177124	2.30
416.2366943	3.35
417.2805786	0.59
418.4483643	0.08
422.7094116	0.11
423.3853760	0.13
424.3211060	0.17
425.4255371	0.50
426.4532471	0.41
427.3168945	0.21
428.5031738	0.10
430.4550781	0.01
431.2186890	0.04
431.9862061	0.09
434.1083984	0.05
436.3568115	0.02
437.3804321	0.06
440.3134155	0.29
441.3382568	0.72
442.2548828	1.21
443.3164062	1.27
444.3754272	0.07
446.4846191	0.18
447.2319946	0.20
449.4095459	0.06
450.2504272	0.02
452.3705444	0.42
453.3935547	0.77
454.4348145	0.87
455.2025757	0.15
456.1262817	0.34
456.7459717	0.23
457.6007080	0.03
458.4288330	0.07
459.5106201	0.18
460.5502319	0.08
463.4625854	0.09
464.4194946	1.29
465.4567261	1.91
466.5054321	0.48
467.4835205	0.09
468.6945190	0.15
469.5243530	1.27
470.3314209	8.93
471.3217773	11.80
472.2918701	2.00
473.5650635	0.26
474.3284912	0.28
475.4312744	0.40
476.4106445	0.26
478.6911621	0.04
479.5858154	0.02
481.3804321	4.04
482.4287720	7.05
483.4031372	2.39
484.3392334	1.17
485.3523560	0.24
486.3106689	0.14
487.4059448	3.14
488.3791504	3.56
489.4226685	0.47
492.3505859	10.12
493.3716431	14.34
494.4457397	1.84
495.3450928	0.10
496.3365479	0.19
497.3750000	0.18
498.4115601	0.41
499.4027710	1.25
500.3851929	1.37
501.3873901	2.73
502.5336914	0.19
507.4267578	0.07
509.3695679	17.71
510.3698120	34.17
511.4653320	5.04
512.5769043	0.32
513.4111328	0.17
514.9063721	0.03
516.5437012	0.32
517.3967896	0.07
521.1847534	0.01
522.5733032	0.08
523.6251221	0.06
525.3483887	0.05
526.2985840	0.59
527.2824707	1.58
528.3908081	4.64
529.3758545	9.17
530.4453735	0.89
537.5613403	0.18
538.5608521	0.39
539.4042969	1.07
540.5190430	1.04
541.5042725	0.11
543.3202515	0.23
544.4057007	0.17
545.4262695	0.10
549.1339722	0.28
549.8333740	0.05
555.3856812	1.88
556.3937378	5.27
557.4976807	0.72
561.3553467	0.03
563.5243530	0.02
565.4154663	0.85
566.4173584	6.63
567.4028931	11.06
568.3195801	2.34
568.9267578	0.02
574.4712524	0.09
578.4447632	0.14
579.7747803	0.04
580.9584351	0.17
581.7107544	0.05
583.6033325	19.29
584.4432983	43.73
585.5302124	6.40
588.2133179	0.07
589.3883667	0.05
590.6606445	0.19
591.5816650	0.25
592.5847168	0.09
593.6171875	0.18
594.9615479	0.14
595.7317505	0.22
596.4240112	0.51
597.6668091	0.14
598.6203613	0.02
601.5916748	0.05
605.4378052	0.20
606.4660645	1.13
607.3990479	1.67
608.3893433	0.55
609.2664185	0.03
611.4284058	3.49
612.3990479	13.58
613.4898071	3.41
614.5415039	0.29
621.4171753	0.19
622.5098267	0.99
623.4901733	7.55
624.4402466	10.77
625.4061890	5.08
626.5377808	1.70
627.4566040	0.17
629.2134399	0.44
629.9393311	0.01
630.7966309	0.06
638.9269409	0.57
639.7448120	4.59
640.5924072	15.26
641.4796753	46.43
642.3964233	9.41
643.4085693	2.85
644.4483032	0.51
649.7169189	0.02
650.6076050	0.07
651.6140747	0.59
652.6091919	0.97
653.4656982	0.68
656.4913330	0.52
657.5452881	3.49
658.3796387	0.45
665.3936768	0.06
666.6493530	0.22
667.4735718	0.37
668.8179932	0.06
669.5012817	0.29
676.5824585	0.02
678.4960327	0.09
679.6159668	0.30
680.7817993	0.11
681.4169922	0.12
682.8456421	0.12
684.6204224	0.04
685.7646484	0.39
691.6762085	0.23
692.7991333	0.44
693.9141846	0.40
694.7536621	0.16
696.4953613	0.05
697.3911743	0.26
698.5662231	0.01
703.8239136	0.04
707.6378784	0.09
708.4723511	1.24
709.4741821	5.33
710.6106567	2.07
711.8203125	0.13
719.4629517	8.56
720.6168823	2.56
726.4716187	100.00
727.5332642	19.90
728.2185669	0.14
736.5260620	39.19
737.4889526	62.78
738.4089966	12.61
739.0216675	0.13
755.4785767	2.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3308
Annotation	Unknow
Peak:m/z	Relative Intensity
242.1902466	0.49
249.8193359	0.02
270.4502563	0.02
279.3427429	17.13
329.1065674	0.03
370.6563110	0.02
443.3137207	0.02
468.4466553	0.03
504.3341675	100.00
505.4126587	0.30
528.2623901	0.04
546.5082397	0.02
548.7102051	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.22
Annotation	Unknow
Peak:m/z	Relative Intensity
245.2540894	0.03
247.3324127	0.15
265.2687988	0.13
275.0753784	0.03
289.2225037	0.08
305.0697937	0.41
307.0850525	0.05
317.2346802	0.07
319.3307495	0.06
321.0955200	0.63
337.3049622	0.05
339.1026001	0.22
340.9293823	0.06
349.1804199	0.02
353.0499268	0.03
361.2470703	0.04
363.0736694	0.11
377.1332397	0.13
381.2754517	1.13
395.3949585	0.05
401.6231689	0.08
403.3068848	0.04
421.1177979	0.16
437.4739380	0.13
449.2987061	0.48
453.2727661	1.22
463.2672119	0.04
471.2290649	0.27
481.4323730	0.04
490.5975342	0.04
491.2265015	0.12
493.2192993	0.58
495.4396973	0.18
507.4091797	0.22
508.7220459	0.04
509.4871216	0.19
511.0872192	0.24
513.2223511	0.35
525.3885498	3.00
543.1981201	2.68
543.8386841	0.01
553.2901611	0.60
567.2316284	0.23
571.4443970	0.15
585.2861328	0.38
603.2921143	7.39
613.3419189	0.23
625.2136230	0.69
643.3591919	0.23
645.3316040	0.32
657.2843628	17.68
657.9454956	0.25
675.3930054	18.86
703.3810425	0.12
735.3750610	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	436.0312
Annotation	Unknow
Peak:m/z	Relative Intensity
183.8998108	0.05
199.9564819	0.17
216.1204224	0.01
217.7391663	0.12
227.9126587	0.26
246.0312195	2.13
253.8715820	0.03
258.0994263	0.28
260.0220337	0.31
261.8359680	0.40
263.0494690	0.42
270.0923157	0.07
271.9716492	0.35
273.9763489	0.05
280.1168518	0.60
284.0230713	0.07
289.0578003	0.04
289.9630127	0.26
299.8574219	0.07
302.1765137	0.06
304.0905151	36.03
315.1403809	0.05
315.9843140	0.17
317.0548096	5.01
318.1610107	0.15
326.0936584	0.03
328.1469727	0.12
330.0956726	0.06
331.2010498	0.25
332.1811523	0.49
333.5182495	0.11
334.1879883	0.27
343.9888916	0.10
346.1385193	4.26
347.9670715	0.06
353.2605286	0.13
356.1465454	0.91
358.1959839	0.05
359.3955383	0.03
372.0776367	0.90
374.1853027	0.61
375.0854187	0.10
388.2546692	0.13
390.0838013	100.00
392.0975647	43.66
418.0690002	0.99
419.2128601	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3073
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
143.3085785	0.01
149.3669586	0.02
152.9098206	0.03
162.8600311	0.01
176.8334045	0.06
179.3471832	0.01
180.091217	0.05
184.0561523	0.01
191.3687134	0.06
198.1517944	0.14
203.2888947	0.03
204.786499	0.05
209.2029266	0.01
215.885437	0.17
218.059021	0.01
247.3726349	0.01
251.97229	0.01
265.3016968	0.15
308.4657898	0.31
312.1434326	0.01
321.491333	0.02
331.4421997	0.05
337.8787537	0.09
339.291687	100.00
339.9241943	0.18
343.3474121	0.10
358.225708	0.02
363.1607971	0.11
382.2586975	0.02
407.1457214	0.03
415.9021912	0.02
419.3946533	0.11
446.8097229	0.09
449.3367615	0.01
452.5524597	0.08
462.2446899	3.78
463.5135193	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.18
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
112.9931335	0.59
118.9072113	1.29
124.9060211	0.11
130.8527222	0.51
133.0309143	0.08
142.9701691	1.48
148.6171875	0.62
159.0277710	0.25
160.9375000	3.61
162.3561554	0.20
163.0056610	0.18
167.1563263	0.02
173.1126251	0.03
178.9769287	4.98
180.0478516	0.05
185.1151428	1.30
191.1092834	0.21
198.1863251	0.06
200.3413391	0.05
206.2166443	0.08
224.9689636	0.02
228.8750610	0.05
247.0883484	0.59
257.0074768	0.26
268.7938538	0.07
269.4028320	0.07
272.1643982	0.11
273.3123169	0.05
287.1842041	0.54
288.0898438	2.58
289.1668701	1.09
305.3461304	0.07
327.9631653	0.14
329.1250916	0.74
332.4481201	0.22
333.1922302	0.08
345.2439575	0.07
347.1665039	100.00
351.3863525	0.10
355.1572876	0.22
360.3830872	0.06
375.3989868	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1141.3
Annotation	Unknow
Peak:m/z	Relative Intensity
521.3139648	0.03
606.1912231	0.03
1139.5437010	6.52
1140.1722410	100.00
1141.2448730	80.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	273.96
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9290237	4.67
115.9100647	1.65
130.9794922	0.49
131.8837128	0.13
136.9290771	0.03
158.8987732	100.00
159.9282837	31.58
173.2395020	0.01
186.9410095	0.02
188.8146667	0.02
198.9937439	1.34
200.0194397	1.14
201.8097534	0.02
216.9882812	0.56
217.9754944	0.71
228.8917847	19.41
229.9874573	13.74
245.0130310	0.31
246.1051025	0.26
255.1383667	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	366.0832
Annotation	Zeanoside B
Peak:m/z	Relative Intensity
109.1423035	0.03
113.0280914	0.21
116.0697174	0.53
116.8712616	0.05
124.9022980	0.05
132.0188141	0.02
140.1341858	0.17
141.9846191	0.03
142.9027710	0.09
144.0267029	0.17
149.1846924	0.02
151.1382599	0.05
159.9601135	100.00
161.0117798	0.32
172.8990479	0.14
178.1472626	0.25
179.0825348	0.53
191.1234741	0.62
192.0207825	0.25
202.1611786	0.06
203.9726257	40.53
206.0671997	0.06
207.2107391	0.09
213.9104614	0.02
216.1461334	0.05
231.8925476	0.06
237.0539551	0.08
245.9029846	0.05
259.1300354	0.02
260.9582520	0.04
268.1540222	0.02
276.1264343	0.04
276.9622192	0.21
277.9037476	0.09
285.3876953	0.06
287.1498108	0.03
293.9616699	0.04
304.2035217	0.07
320.1003418	1.18
321.3368225	0.22
322.0855103	0.07
323.3071594	0.02
329.2829895	0.72
330.1427307	0.07
332.1354980	0.12
348.1222839	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.15
Annotation	Bocconoline
Peak:m/z	Relative Intensity
115.8143005	1.21
128.9242859	0.18
129.9307251	1.97
131.0911865	0.53
140.2368469	0.05
143.6857910	0.17
145.0435791	0.25
145.7514648	0.09
147.9918213	0.59
150.0417786	0.12
152.9537964	0.04
156.2602539	0.19
161.9982605	6.02
165.4337463	0.07
168.0025787	0.08
173.0706482	0.08
173.9659424	0.35
175.7537384	0.08
181.1888580	0.08
200.3266296	0.04
216.0338287	11.03
218.0270996	0.23
231.0036621	0.97
232.0507202	1.72
234.0515137	50.37
241.0160522	0.04
249.2176208	0.60
251.0836487	100.00
257.5546875	0.08
258.2594299	0.07
268.0668335	0.26
274.1885376	0.26
280.4613953	0.06
284.4639893	0.14
287.4693604	0.03
301.1323547	0.04
305.1099243	11.68
317.1828613	0.07
318.6124268	0.16
321.2163696	0.06
326.4383545	0.30
335.1532593	0.33
336.1219788	0.28
343.2835083	0.06
344.3530273	1.22
361.2660522	0.71
362.1931458	4.87
363.2768250	0.88
365.0541077	0.04
370.7783813	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.0028
Annotation	SC-58125
Peak:m/z	Relative Intensity
128.9482117	0.28
130.9936676	0.06
133.1280212	0.08
141.0593872	0.04
146.9178467	0.01
155.1750793	0.02
164.9439087	0.13
172.9603577	1.42
185.0702209	0.05
187.0690613	0.04
190.9531860	100.00
192.1154785	0.03
205.0508728	0.05
210.8231964	0.02
212.2534485	0.13
212.8833313	0.25
229.1813507	0.07
230.0537415	0.02
241.3057556	0.13
243.6506348	0.03
253.2580261	0.04
255.0919189	0.16
256.1634216	0.06
269.2232361	0.03
272.1562195	0.03
273.0444641	0.51
287.2229004	0.16
288.1421204	0.05
289.1441345	0.08
298.7277222	0.39
304.3464966	0.02
306.2500610	0.10
313.0936279	0.01
315.2337646	0.02
316.1636963	0.07
317.1146545	0.73
322.1403809	0.01
330.3494263	0.13
337.2316284	0.05
340.2375488	0.03
341.3190918	0.03
342.6236877	0.03
347.3700562	0.03
352.3680115	0.03
356.8804626	0.05
357.4989319	0.03
359.1282959	0.04
373.1573181	0.02
374.0357971	0.07
375.1212463	0.56
376.1205750	0.14
377.1029968	0.20
384.9347534	0.19
388.1571960	0.13
389.0448914	0.07
389.7932434	0.09
400.7468567	0.03
402.0250854	0.31
403.0812073	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	418.133
Annotation	Unknow
Peak:m/z	Relative Intensity
123.8959427	0.40
134.0101471	4.01
135.9083710	4.84
147.8721161	0.47
149.1436310	0.07
149.9105377	0.39
151.9947815	17.31
161.9754791	0.07
162.9683228	0.17
163.8698120	0.26
166.5641479	0.20
168.1065369	0.10
168.9063110	0.17
170.0449066	29.47
172.7059021	0.45
174.9663239	0.23
175.9020386	0.66
186.0960083	0.06
186.7333984	0.16
190.1033325	0.29
192.2567444	0.15
194.0493011	0.53
203.9108887	0.08
205.8780670	0.31
210.1883240	0.10
217.9642029	0.16
225.4105377	0.12
228.3613281	0.14
230.1713867	0.33
232.0937805	0.70
236.2940979	0.09
246.7259521	0.14
250.0309448	0.18
256.2652893	0.52
257.0475769	0.94
260.2333984	0.53
265.9158630	0.09
267.0941162	0.18
271.1506042	5.41
276.0843506	0.42
277.1423950	0.08
278.3178406	0.53
284.2565918	0.10
285.1453552	0.27
291.8393555	0.21
295.3974609	0.18
308.2075195	0.10
310.1814270	0.04
311.7494202	0.17
312.5416565	1.14
313.2810669	0.07
314.1892700	1.69
316.3058472	0.33
320.3090820	0.58
321.2423096	0.21
326.2265320	0.12
332.2230530	33.46
335.9781494	0.12
337.0964661	0.26
338.2215271	7.93
339.0968018	0.30
342.6998901	3.44
344.1717529	0.14
351.4471436	0.23
352.1640625	0.46
353.5739136	0.14
356.1681824	48.13
364.1061096	0.71
371.1321411	0.15
374.2648621	100.00
382.0816650	1.02
387.4849243	0.20
389.0711365	0.99
400.1601257	65.45
400.7608032	0.28
408.7049866	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1035.6365
Annotation	Unknow
Peak:m/z	Relative Intensity
725.6395874	0.10
727.0232544	0.09
812.8950195	0.23
854.2866211	0.11
872.7723389	0.07
887.5528564	0.26
905.8245850	0.06
973.4854736	0.04
1035.4901120	100.00
1036.1312260	1.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1133.3661
Annotation	Betadex
Peak:m/z	Relative Intensity
563.3271484	4.99
1040.726929	9.03
1133.360718	100.00
1134.459229	80.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	417.175
Annotation	Phenylethyl O-alpha-L-arabinopyranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
119.2576447	0.11
121.1618271	0.31
122.9979782	1.65
126.9330292	3.22
132.8504639	0.24
144.9320068	0.68
151.0187988	14.54
164.9327087	0.06
166.9903870	0.44
168.9765778	100.00
174.8112183	0.28
177.0809631	0.87
177.9686584	0.46
178.9700012	0.17
182.8726654	0.21
186.8777161	0.07
188.9840088	0.50
199.0526886	0.18
201.0970154	0.18
205.0153046	0.05
208.2228851	0.16
213.0081024	2.25
216.7290497	0.19
217.3514709	0.16
222.5280914	0.06
225.2041016	0.12
229.1763916	0.34
230.9915771	7.78
232.1563721	0.09
235.2034302	0.30
241.1098633	0.37
247.6309814	0.09
248.9180603	4.49
254.0972290	0.18
259.1665344	0.88
267.0666809	0.11
277.3602905	0.47
300.0073242	0.28
303.1141663	0.28
317.2261963	0.10
339.3140259	0.08
345.3281555	0.35
354.9722290	0.12
357.2866516	1.75
358.1256409	1.86
359.2489319	1.22
361.3922729	0.26
363.0244751	1.21
371.6292725	0.17
375.4980774	0.14
379.0739441	0.35
380.9399109	8.18
381.6178589	0.20
388.5590515	0.15
398.9131470	4.65
399.7445374	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.175
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
183.9265442	0.05
189.2155609	0.15
235.2512360	0.11
286.1065063	0.96
287.0170288	0.15
289.2577820	0.19
295.8331299	0.14
301.1307983	75.54
302.1831055	11.76
316.8186035	0.12
344.4840088	0.13
356.2517700	0.12
367.4655151	0.48
381.0967407	0.05
385.2290039	1.77
386.2257080	0.04
388.0289307	0.07
391.0656128	0.09
397.5971680	0.16
409.1943359	0.83
410.3852539	0.34
421.1813965	0.46
427.1898193	0.28
428.3752441	0.05
439.1008301	1.15
440.3041382	0.97
445.2367554	1.40
446.3867798	0.63
451.2415771	1.51
457.1694946	0.64
458.2537231	0.41
458.9421387	0.04
461.6642456	0.19
463.1298828	69.00
464.0743408	17.01
464.7508545	0.02
469.0551758	1.47
470.1352539	0.27
475.1422119	0.63
476.3059692	0.08
478.2127686	0.21
479.1561890	0.08
480.2435913	0.11
485.0974731	0.22
487.2089844	45.53
488.3114014	11.21
505.1947632	14.84
506.1504517	3.18
511.2295532	4.79
512.4293823	2.13
518.4229736	0.14
523.1405640	0.11
529.2175293	6.89
530.2163696	3.01
530.8773804	0.12
535.5363770	0.41
536.4074097	0.25
537.1666260	0.08
538.5378418	0.10
541.1767578	14.67
542.3151245	3.47
544.6270142	0.15
546.3968506	0.46
553.2402954	7.20
554.3020020	1.97
559.1563110	16.08
560.3052979	4.79
564.4252319	0.10
571.2562866	9.70
572.2306519	4.05
589.2396851	32.58
590.1915894	9.90
590.8414307	0.05
595.3706055	0.09
605.2296753	0.04
607.2202759	100.00
608.2102661	24.70
608.8688354	0.16
627.5949097	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.13
Annotation	Isoscutellarein 8,4'-dimethyl ether 7-glucuronide
Peak:m/z	Relative Intensity
152.0128174	0.03
166.9610291	0.02
172.7756348	0.04
183.2235413	0.04
191.2085114	0.07
205.2671051	0.03
208.0105591	0.02
294.9747314	0.03
297.3862915	0.08
299.3329468	0.06
300.1348877	0.02
311.2493896	0.21
312.1802368	0.09
313.1183472	0.06
315.2955322	0.01
328.0045776	0.11
329.2009277	0.50
331.2130737	0.01
337.1602783	0.06
338.2601929	0.02
339.1419067	0.21
340.3411865	0.20
340.9502563	0.05
343.1549683	7.54
344.2280273	1.49
354.0742188	0.04
357.1213379	0.69
358.1177368	3.53
359.1626587	3.83
360.2326050	0.03
366.2293701	0.04
369.0966797	0.01
370.1500244	0.03
372.0187378	0.13
375.0681763	0.01
381.0473633	0.04
395.0693359	0.01
401.2640381	0.24
417.3564453	0.04
431.2288208	0.02
435.3333130	0.02
460.5465698	0.02
462.3035889	0.09
475.3222656	0.41
488.1041870	0.04
488.9819336	0.01
491.2628784	1.71
506.1908569	100.00
507.3574829	0.28
522.2808838	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	562.191
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0253448	0.03
190.0673828	0.08
195.1708221	0.05
195.7908020	0.02
196.8513031	0.07
200.4973450	0.06
202.1695557	0.11
210.0570984	0.01
228.2998047	0.05
236.2978210	0.04
249.0133362	0.05
268.2849121	0.04
278.0776978	0.02
279.2027588	0.05
283.2438660	0.07
288.2915649	0.04
290.2294312	0.03
291.4692383	0.01
296.2481689	1.08
317.0146484	0.13
322.1226196	0.04
332.5139771	0.04
334.1828003	0.04
337.2366943	0.03
341.3324585	0.11
351.6285400	0.04
365.1213989	0.02
369.2998047	0.05
380.2423706	0.06
394.9416504	0.04
398.6577148	0.06
399.5812378	0.02
400.2252197	0.28
406.8822632	0.14
414.4241943	0.03
415.5510864	0.02
416.9055786	0.05
425.1337891	0.01
427.6506958	0.04
433.2686157	0.10
446.9619141	0.01
476.2068481	0.12
481.0086670	0.15
487.1907349	0.02
488.6199341	0.14
492.5939331	0.06
500.2144165	0.67
503.5443115	0.02
508.1393433	0.02
509.6938477	0.02
525.2870483	0.03
530.4064331	0.02
535.4868774	0.04
542.8413696	0.13
544.2409058	100.00
544.9384155	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	476.1905
Annotation	Codeine-6-glucuronide
Peak:m/z	Relative Intensity
135.0151215	0.07
136.7946320	0.06
144.9543457	0.32
146.9290466	2.84
148.9667969	0.04
150.0521240	1.64
151.0300598	0.11
154.8767395	0.03
157.0978394	0.11
160.9261475	0.16
162.0278320	0.06
162.9773865	0.03
169.2156372	0.04
173.8124390	0.08
176.0876923	0.68
176.9895325	0.12
179.0419464	0.09
184.7602997	0.06
188.8912964	0.14
190.1231689	0.85
192.0526428	0.03
193.1027222	0.45
194.7687378	0.06
200.0097198	0.04
201.2691650	0.02
201.9911804	0.80
204.2966309	0.10
206.8450470	0.03
207.9727478	0.08
209.2350769	0.18
209.9402161	0.12
217.9719849	0.03
226.0323029	0.37
226.9867859	0.30
228.0694885	0.38
231.2063446	0.13
241.9905243	0.11
243.0670776	0.03
244.1278381	0.94
249.2119751	0.08
250.9587708	0.23
252.5921631	0.02
254.3970032	0.05
256.0768433	0.11
260.0636292	0.04
265.1817932	0.12
272.1785278	0.02
273.2498169	0.02
275.2299194	0.07
278.0668030	0.07
282.9004517	0.12
287.3344421	0.09
292.3051453	0.06
296.1322021	100.00
296.7512817	0.15
307.2996521	0.17
308.0875244	0.04
311.1420593	7.54
311.8513794	0.03
314.0267944	7.95
315.1864014	0.11
323.4329834	0.03
326.1272278	0.03
327.1672363	0.03
328.1035767	0.36
329.1669312	19.54
330.3054504	0.12
338.9110718	0.15
339.8202515	0.09
342.9900208	0.04
345.2160645	0.02
346.9979858	0.37
355.2665100	0.18
355.9303589	0.11
360.3247681	0.11
362.3707886	0.03
371.8016357	0.05
377.7612610	0.06
383.3385315	0.06
389.3404236	0.25
390.2312622	0.05
397.2162476	0.05
398.0536194	0.02
401.3183289	0.08
410.3922424	0.02
411.9724731	0.09
413.2713318	0.21
415.2895508	0.20
419.5010681	0.11
421.7443848	0.02
422.9646912	0.07
430.0938416	0.11
431.0485229	0.07
432.3324890	0.41
434.1623535	0.06
437.9066162	0.02
440.1877136	0.11
442.6803589	0.05
449.4697571	0.11
457.0508728	0.38
458.2625427	2.24
459.3980408	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	462.2625
Annotation	PE(17:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9137726	0.05
153.0014038	0.44
181.2146606	0.08
182.9630127	0.20
184.8646851	0.07
195.1611633	0.31
196.0722351	2.07
198.8438568	0.08
207.0964050	0.20
214.1323547	1.13
224.2057037	0.07
225.2428436	0.14
232.1396484	0.11
237.9059143	0.11
247.2231445	0.46
265.2377319	100.00
266.0104675	0.09
275.0965881	0.34
284.1022034	0.11
285.2994385	0.18
291.1334229	0.15
293.3019104	6.84
294.3642273	0.96
299.3106384	0.65
313.2132874	0.23
314.4377441	0.22
340.9638977	1.48
342.1813049	1.13
343.3430786	0.33
355.6541138	0.19
356.3724060	0.38
369.4063110	0.08
370.4335938	0.28
372.2099915	0.17
382.3591919	0.16
384.1525879	0.08
390.5048828	0.06
392.4102173	0.10
399.1464539	0.09
401.3450623	0.20
415.4361267	0.42
416.3307495	0.31
418.3668823	0.25
419.0546875	0.07
424.1894531	0.05
425.9828186	2.07
427.2253723	0.34
429.1467590	0.19
434.2632141	0.10
443.4105225	0.11
444.3630676	0.73
445.5327148	0.13
447.3638611	1.00
448.0968933	0.04
453.4808655	0.31
463.5213928	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.3309
Annotation	Unknow
Peak:m/z	Relative Intensity
169.9627075	0.05
177.8730469	0.04
224.1602631	0.09
232.7249908	0.06
235.2914886	0.02
242.1431427	0.23
253.3588562	0.02
254.1271515	0.02
279.3020325	5.24
281.3094482	1.65
282.4568481	0.97
311.2968750	0.23
339.3630371	0.03
344.3969727	0.04
403.5757446	0.05
413.3064575	0.06
422.6511230	0.03
430.6332397	0.02
439.5312500	0.06
459.4733887	0.07
468.2687988	0.02
474.3498535	0.02
478.3975220	0.06
502.5154419	0.02
504.3603516	100.00
505.3590088	0.20
517.1387939	1.12
518.2725220	0.43
519.4995728	0.08
528.0870972	0.04
532.6640625	0.05
535.3856201	0.08
546.4243774	0.05
548.0964355	0.03
548.9955444	0.19
549.6190796	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	799.2286
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
272.0945740	0.10
281.4956665	0.07
305.2283936	0.05
306.3306274	0.13
311.2661743	0.04
314.2312622	0.13
315.0089111	0.12
316.2228394	0.36
317.3900146	0.12
327.2125549	0.04
329.1744995	0.92
330.3468018	1.08
331.1174316	6.81
331.7569580	0.05
367.2595825	0.03
371.5057068	0.26
377.5737305	0.07
401.5748291	0.14
442.6116333	0.08
475.3754272	0.36
491.1300659	1.21
492.2164917	2.43
493.3169556	17.96
505.3308105	0.03
519.1557007	0.19
520.2594604	0.07
521.2981567	0.06
533.3122559	0.72
534.3838501	2.20
535.3436890	0.94
555.9898682	0.16
559.3645630	0.12
563.3837891	0.13
564.2520752	0.21
573.4262085	0.06
574.1235352	1.09
575.2836304	0.33
576.0673218	0.24
586.5952759	0.05
587.2356567	0.06
588.4312744	0.17
603.0684204	0.08
603.9548340	0.03
605.3331909	0.05
606.2941284	0.18
619.4570923	0.13
621.2219849	0.10
622.4063110	0.17
635.2062378	0.51
636.0990601	0.88
637.2864380	1.01
641.5128784	0.05
654.3462524	0.61
655.3060303	3.44
655.9230347	0.52
658.3302612	0.04
666.3482666	0.32
679.3740845	0.10
683.0963745	0.09
697.2761841	2.12
708.4154663	0.34
712.2898560	0.11
720.4673462	0.05
737.3758545	0.85
738.2025146	0.07
742.5360718	0.23
755.0260010	0.07
781.0183716	0.16
799.2660522	100.00
799.8763428	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1043.2671
Annotation	Anhydrosafflor yellow B
Peak:m/z	Relative Intensity
299.0517883	0.29
343.2083435	0.24
344.3292542	0.13
345.0227966	0.07
506.4111328	0.49
507.3146973	1.24
521.2114868	5.81
522.2191162	3.10
1042.9941410	12.80
1043.7017820	100.00
1044.8172610	4.23
1045.5362550	2.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.2255
Annotation	Troxerutin
Peak:m/z	Relative Intensity
214.8908997	0.13
216.6722412	0.02
227.1907654	0.08
229.9256592	0.02
232.8257141	0.04
242.1557007	0.02
256.9630127	0.04
264.9909973	0.01
267.2277222	0.01
271.1220093	1.44
282.0161743	0.02
283.0217896	0.06
284.1362305	0.03
286.2770386	0.03
295.1693115	0.01
299.0758667	0.05
301.1804810	1.74
313.0498962	0.12
315.2570801	0.02
325.3669434	0.03
327.1222534	0.01
331.3086548	0.02
342.8173828	0.02
343.5025024	0.01
355.3450928	0.04
357.2388916	0.07
359.3356934	0.02
367.1281738	0.05
397.4008179	0.02
413.2620239	0.01
414.3228149	0.02
429.5230103	0.03
432.3980713	0.04
433.2424316	0.03
439.2236938	0.03
443.4378052	0.01
447.3446045	0.03
457.3928833	0.07
459.2788696	0.32
473.3023071	0.09
475.2973022	0.33
477.3223267	0.66
491.3175659	0.02
501.3041992	0.04
517.2106934	0.07
519.2065430	0.04
531.3070679	0.06
559.3660278	0.13
560.0363159	0.01
561.4032593	0.25
567.1854248	0.10
577.4755249	0.20
578.7058716	0.11
579.4482422	0.80
585.4588013	0.04
591.2420044	0.09
595.3992920	2.01
603.3385010	0.24
605.2698975	0.21
609.3113403	0.01
617.3535156	0.05
621.3894653	10.49
623.1513062	0.02
635.3289185	0.42
647.4622192	0.10
694.8964233	0.08
697.3111572	0.06
723.0756226	0.07
741.3206177	100.00
742.2860107	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1767
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
113.0281677	0.21
118.9790344	0.43
124.9505157	0.03
130.8747101	0.05
143.0181732	0.46
148.7206268	0.04
160.9977417	1.09
178.9528198	3.60
185.1518097	0.34
224.8977966	0.12
247.0475464	0.04
269.1492920	0.21
296.9123535	0.11
303.0914612	0.02
329.4296265	0.03
331.1919556	0.06
333.4810791	0.04
345.2257385	0.07
347.1370239	100.00
347.7590637	0.27
349.1781921	0.21
375.2471924	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	399.0938
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone-4'-O-glucuronide
Peak:m/z	Relative Intensity
112.9944839	0.06
115.0418243	0.05
119.0445404	0.05
124.9875412	6.36
129.0256500	0.13
130.8858337	0.08
132.8445435	0.03
141.0244446	0.08
142.9586945	1.44
148.9232788	0.04
158.0443420	0.04
161.1066589	0.68
165.0517883	0.03
169.1117249	0.27
175.1656494	0.15
176.1846313	0.06
178.9781799	0.13
181.1626740	0.10
187.0647888	0.44
191.1361694	0.43
193.3742371	0.09
201.1721497	0.78
203.7704620	0.04
204.9672852	100.00
210.7120056	0.05
219.1038971	0.44
223.0462799	11.60
225.1410217	0.02
237.1063538	0.12
261.2757874	0.03
300.7867737	0.23
319.3656921	0.03
340.2152100	0.05
349.9479065	0.13
351.3381042	0.48
352.3097839	2.78
353.1745911	0.76
355.0651855	0.09
357.3021240	0.12
363.1144104	0.02
365.9770203	0.03
367.1659546	0.17
381.1759949	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1484
Annotation	Methyl di-alpha-L-rhamnoside
Peak:m/z	Relative Intensity
109.0494614	0.32
116.9758301	2.09
118.9856949	0.44
121.0401611	0.21
121.9920731	0.18
127.0583038	0.69
133.0160675	0.24
145.0320282	0.70
147.0319214	3.01
148.9776917	0.54
157.2637787	0.42
160.7402191	0.29
162.9412842	3.87
175.1499786	0.16
178.0783081	0.20
180.1125488	0.29
180.9672852	0.22
184.0774841	0.81
185.1350098	0.31
192.1508789	0.20
192.9750214	0.42
212.0852051	4.07
213.2740479	1.16
215.2673645	0.05
218.1786804	0.52
222.0707703	0.09
225.0002441	0.61
236.1431274	0.20
238.0877991	0.38
246.8325195	0.12
249.1127625	0.15
250.0255127	0.54
251.1273193	0.53
252.1749268	0.30
253.0313110	0.09
258.0104370	0.09
265.1994629	0.11
268.1611023	100.00
269.1573181	36.54
271.0771484	0.78
275.5911865	0.41
277.1745911	0.48
278.9294128	0.66
284.6153870	0.42
289.2145081	1.66
293.3737793	0.61
296.8004761	0.43
306.0639648	0.24
307.1387329	2.13
308.2220459	0.54
309.3204651	0.62
315.7484741	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	331.07
Annotation	Unknow
Peak:m/z	Relative Intensity
116.9667358	0.01
118.0989914	0.01
152.1581268	0.00
161.0993652	0.01
162.1087799	0.01
167.1430664	0.02
168.0880280	0.02
194.0982513	0.00
208.0612335	0.00
209.2527466	0.00
210.2416687	0.02
211.1161499	0.00
214.1557312	0.00
229.3588867	0.01
236.3801270	0.00
243.4204407	0.01
244.2166748	0.01
254.1980591	0.01
261.4122620	0.00
270.3348999	0.00
271.4801025	0.00
287.2209778	0.00
295.4083557	0.01
297.0784912	0.02
298.1756287	0.01
299.2984619	0.02
300.1877136	0.11
301.2868347	0.02
303.4977417	0.00
312.2078247	0.03
314.5173035	10.20
315.2212524	100.00
316.1141968	15.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	903.2787
Annotation	Unknow
Peak:m/z	Relative Intensity
271.3649292	0.02
287.1402588	0.08
329.5700378	0.01
339.2218018	0.05
357.3964233	0.06
359.2738953	0.04
449.2290039	0.03
475.2822876	0.03
503.4661865	0.01
559.7101440	0.01
579.3762207	0.03
595.3522339	0.21
605.4104004	7.84
623.2227173	0.02
723.4165649	0.03
741.3657837	100.00
742.8704834	0.01
757.4102173	0.01
767.3304443	0.03
783.3233643	0.01
903.3844604	9.78
904.3471069	34.73
905.0149536	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1055.5428
Annotation	Unknow
Peak:m/z	Relative Intensity
335.4967346	0.08
338.3986511	0.09
342.3911438	0.05
360.4435730	0.08
393.1156921	0.03
400.1987305	0.04
420.4876099	0.02
421.3736267	0.07
429.1836853	0.03
434.1659546	0.02
450.5442810	0.02
466.4031067	0.04
476.6343079	0.02
478.4672241	0.05
490.3437500	0.02
496.3193665	0.12
508.4213867	0.02
510.3269043	0.08
520.3967285	0.03
521.4735107	0.04
522.4787598	0.04
524.5577393	0.09
528.6275024	0.05
536.5123291	0.04
537.6511230	0.03
538.3206787	0.05
540.3142090	0.02
541.5551758	0.06
544.7791748	0.06
554.9428711	0.02
556.5824585	0.02
564.3927002	0.02
579.7094727	0.01
584.5553589	0.31
586.5777588	0.51
588.5958252	0.03
597.7612305	0.04
600.6256104	0.30
602.3079834	0.05
610.3164062	0.02
615.2309570	0.06
617.9960938	0.16
618.6097412	3.64
620.5651855	0.17
626.3488770	0.04
628.7471924	0.10
634.6479492	0.10
642.5183105	0.03
644.4461060	0.34
671.5000000	0.14
672.6828613	0.02
684.6138306	0.02
689.4675293	0.58
690.0942383	0.01
698.7024536	0.02
703.5020752	0.06
707.1905518	0.06
708.5097656	0.07
709.5814819	0.17
712.8226318	0.07
714.5726929	0.01
725.8233643	0.05
726.6925049	0.02
729.0775757	0.10
729.7253418	0.14
730.5781250	0.07
731.8453369	0.05
744.7593384	0.08
746.5157471	0.27
747.5152588	0.06
749.1121216	0.01
752.8273926	0.02
753.7520752	0.05
755.6457520	0.24
764.5002441	12.05
765.1740723	0.04
769.8786011	0.03
771.1156616	0.01
777.5733032	0.07
780.5514526	0.22
782.4949951	0.01
788.5252686	0.46
795.4050293	0.05
799.8901367	0.06
800.7344971	0.40
806.6828613	0.51
812.4034424	0.14
818.6715088	0.69
823.1512451	0.12
823.7852783	0.05
839.4456787	0.11
842.8829346	0.07
854.9963379	0.11
856.3845215	0.10
872.5660400	0.39
875.4935303	1.07
876.2758789	0.07
890.4993896	0.42
891.5461426	0.05
893.5240479	9.67
908.5229492	0.13
926.6079102	4.71
933.8725586	0.02
935.1754150	0.09
935.7825928	0.16
944.3948975	0.14
962.4816895	0.04
963.6688232	0.09
971.6962891	0.04
980.6413574	0.33
983.5418701	0.18
1001.6378170	0.15
1011.9428710	0.03
1019.4567870	0.10
1037.4919430	0.04
1038.5009770	0.17
1055.5449220	100.00
1056.5219730	60.96
1057.2648930	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1799
Annotation	Diosmin 
Peak:m/z	Relative Intensity
174.9080811	0.02
184.9717102	0.01
196.8931274	0.01
201.0963745	0.02
201.8887634	0.01
203.3128662	0.04
211.2401123	0.01
223.4289551	0.03
245.2008362	0.04
255.0501556	0.06
258.1104431	0.41
259.1093445	0.08
269.09375	0.02
283.2473755	0.03
286.1309204	4.77
301.0748291	100.00
301.6925659	0.44
313.1298828	0.09
325.2631836	0.04
343.0076294	0.08
345.1489258	0.02
367.0699463	0.10
379.2453003	0.02
405.2589111	0.01
411.2288818	0.25
427.0855713	0.14
445.1256714	0.47
447.2773438	0.15
463.0958862	17.52
463.7526245	0.02
505.4230347	0.03
511.0820312	0.03
518.2020874	0.01
529.3815308	0.04
555.081665	0.05
564.2316895	0.01
566.6117554	0.07
573.4525757	0.04
580.2223511	0.02
590.7211304	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	526.15
Annotation	Unknow
Peak:m/z	Relative Intensity
259.3035278	0.23
260.3408203	0.10
273.2100220	0.06
278.3484497	0.29
289.0689087	0.43
332.1804810	0.11
347.2316284	0.34
349.0526733	0.05
355.4683838	0.13
361.1630249	31.17
362.1497803	73.98
363.1453247	100.00
364.1318359	93.65
364.8084717	0.72
397.8049316	0.16
401.0023804	0.15
435.9506226	0.48
444.4616089	1.18
445.0622559	0.23
466.5315552	0.18
467.4177246	0.08
481.5747681	0.09
494.1260376	0.86
507.3350220	0.47
508.3003540	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1234
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
200.9913177	0.02
224.2348938	0.02
232.2472839	0.03
254.9485931	0.01
269.1831665	0.04
283.0596924	0.08
286.1102905	3.65
287.0396118	0.03
301.0721436	100.00
301.6788330	0.21
302.3025513	0.02
305.1360779	0.01
325.0993042	0.05
331.1214600	0.04
333.0673828	0.01
334.2738037	0.03
335.1813965	0.02
339.3149414	0.01
343.0692139	0.02
347.0285034	0.04
352.6499634	0.03
365.0780640	0.04
367.1939697	0.04
372.1611328	0.01
396.4194336	0.02
399.0120850	0.07
409.2878418	0.08
427.4232788	0.02
444.9796753	0.03
463.1693115	2.96
477.1785278	0.07
483.3283081	0.04
495.5253296	0.03
505.1496582	0.32
513.1387939	0.08
531.1178589	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	221.1894
Annotation	1,10-Epoxy-aristolane
Peak:m/z	Relative Intensity
68.9497070	0.29
70.8829346	0.20
78.8312836	0.19
80.7752228	0.47
82.9978180	0.46
84.9248047	1.65
92.7994995	0.04
94.9509735	1.08
96.8345947	0.26
98.9725342	0.22
104.8010406	1.05
107.0197144	0.79
108.8673248	1.91
110.9251862	0.32
113.0545197	0.15
119.0290527	4.40
121.0941772	0.77
123.0316315	1.22
124.9980469	0.56
126.9627533	1.72
127.8717499	0.06
133.0169830	4.56
135.0159607	1.71
136.1440887	0.12
137.1678619	0.56
138.9968567	0.09
141.0080414	0.10
145.1380463	0.15
147.0526733	9.30
149.0422058	1.72
151.0402069	4.20
152.8721466	0.11
159.1348114	0.36
161.0200043	13.83
163.0881653	4.60
164.9887848	1.95
173.0976105	0.22
174.3308258	0.16
175.1359863	1.14
176.1193542	0.20
177.1379700	1.80
179.2408905	0.09
185.0214844	0.20
188.7536163	0.21
192.7809448	0.28
193.4018860	0.19
203.0813751	100.00
203.9600067	0.69
211.5372162	0.11
221.6066132	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.1696
Annotation	Trans-Zeatin-9-glucoside
Peak:m/z	Relative Intensity
115.876152	0.36
118.856369	0.03
123.9702072	0.11
126.7773438	0.08
135.9492035	0.29
136.9968109	0.05
141.9993896	0.13
145.9221954	0.03
156.1101379	0.06
157.9762573	0.09
166.0403442	0.22
172.8897095	0.03
182.0369873	0.13
184.0689392	1.23
185.022644	0.17
201.9830933	7.11
202.9810638	0.11
218.1777039	0.13
220.1193542	100.00
225.8361206	0.06
230.8345032	0.22
235.1959534	0.02
240.1750488	0.17
245.2484131	0.16
246.1348267	0.09
250.0333252	0.06
250.9855347	0.09
259.5130615	0.23
267.0114441	0.03
273.8251038	0.02
274.7845459	0.07
279.0318909	0.05
292.6448975	0.11
298.8327026	0.17
301.2605286	0.24
306.6188965	0.15
308.6138916	0.06
309.5919189	0.10
322.1155396	0.07
334.4749146	0.08
335.822937	0.24
345.3093872	0.06
346.1950684	0.44
363.2115479	0.85
364.3699036	1.84
370.5532532	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1097.5543
Annotation	Unknow
Peak:m/z	Relative Intensity
336.0634155	0.04
350.3224792	0.04
351.1135254	0.04
366.4409790	0.06
380.3849487	0.02
417.4672241	0.02
433.5316772	0.03
435.6440430	0.07
462.2568970	0.08
472.4172668	0.04
491.3063354	0.03
497.1740112	0.03
501.2690430	0.04
520.9243774	0.06
538.7935181	0.05
552.4324951	0.09
568.4685669	0.02
578.6291504	0.03
592.6683350	0.02
626.5186768	0.06
628.6922607	0.07
639.2797852	0.02
660.4918213	3.37
670.7399902	0.05
672.7706299	0.11
684.3733521	0.12
686.6720581	0.30
703.4432373	0.50
708.3010254	0.03
713.5459595	0.12
731.6005249	0.11
740.4573975	0.09
750.5028076	0.09
751.5036621	0.19
752.4784546	0.05
768.5150146	0.01
769.5911865	0.07
770.7247314	0.03
771.5332031	0.30
772.3930664	0.10
780.5068359	0.06
786.7210693	0.02
788.1597900	0.04
790.5676880	0.02
795.6420288	0.04
797.4982910	0.04
806.5224609	8.94
807.5163574	0.05
812.5650635	0.06
822.2449951	0.01
828.9350586	0.02
830.5113525	0.11
842.1472168	0.03
847.3872070	0.02
848.5709229	0.19
854.8067627	0.10
860.3438721	0.20
860.9581299	0.03
896.3861084	0.12
904.4180908	0.14
914.6651611	0.13
917.5891113	0.59
932.5023193	0.30
935.4941406	6.19
936.1101074	0.12
938.6069336	0.06
950.5556641	0.16
968.5604248	3.52
977.9084473	0.06
999.7292480	0.04
1007.6274410	0.09
1013.6977540	0.03
1022.3625490	0.16
1025.8070070	0.12
1061.2890620	0.20
1062.8261720	0.02
1097.5025630	100.00
1098.5281980	72.92
1099.2572020	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	726.384
Annotation	Citrusin III
Peak:m/z	Relative Intensity
231.1514587	0.02
239.1278992	0.02
258.2189941	0.03
275.2675171	0.08
287.0550842	0.05
293.5159607	0.03
305.3576660	0.04
353.3936768	0.05
357.3164673	0.08
372.0190430	0.02
420.5142212	0.04
476.6430664	0.08
486.5371094	0.09
487.4509277	0.14
493.4044189	0.06
499.3900146	0.13
517.3937988	0.02
529.2631226	0.03
545.5005493	0.07
559.3538208	0.02
576.4980469	0.12
590.7260132	0.38
599.2741699	0.01
600.4166870	0.11
602.5969849	0.15
639.2952271	0.07
678.5718384	0.17
690.4617310	0.23
696.5010986	73.60
697.1738892	0.17
708.5432129	4.13
709.2170410	0.01
726.3869019	100.00
727.1286621	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0562
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.9210968	1.07
58.6731262	4.42
61.0689583	0.72
67.0302124	3.18
70.7685089	1.81
80.9038696	1.94
82.7651901	0.49
84.9396362	100.00
86.9040146	12.83
92.9426117	46.60
99.0106049	4.35
101.1335449	0.71
108.9538269	17.73
111.0007782	28.39
112.7510986	1.73
114.8166962	0.38
126.9110718	76.25
128.9593506	0.78
137.0540924	2.06
142.9112701	1.53
144.8523407	3.89
152.8808441	2.08
154.9789886	10.05
170.9155121	31.61
173.0632782	55.81
191.1268768	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.2213
Annotation	Unknow
Peak:m/z	Relative Intensity
220.9743652	0.05
227.1373291	0.10
239.2287598	0.13
265.2565002	0.05
279.0302124	0.10
288.1026611	0.06
306.1630859	0.28
314.6240234	0.17
315.2254028	0.32
316.1486206	0.07
317.1376343	0.10
319.3572998	0.09
325.0773926	0.06
351.4129639	0.03
352.2758789	0.15
369.0534058	0.12
383.9642944	0.13
395.1844482	0.09
396.6770020	0.09
401.2034912	0.08
412.3338623	3.92
413.3444214	0.67
425.4222412	0.13
429.2732544	0.61
430.3615112	0.42
437.6861572	0.14
443.2966919	100.00
457.1301270	0.25
467.2803955	0.31
476.5178223	0.14
481.1442261	0.06
483.5473633	0.06
485.4091187	0.11
486.7404175	0.06
493.3913574	0.23
495.5859375	0.11
503.4003296	0.39
519.3074951	0.17
524.5568237	0.16
526.6931152	0.10
540.5890503	0.10
545.1054077	0.64
552.0706177	0.04
553.3023071	0.34
555.3439941	0.12
558.7469482	0.42
578.5465698	1.24
579.5880127	0.93
583.5944214	0.06
594.4236450	0.20
596.4731445	1.39
597.3891602	0.51
604.8828735	0.40
605.6270142	0.43
622.3849487	15.91
623.4438477	5.44
641.4110718	3.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1715
Annotation	Colabomycin A
Peak:m/z	Relative Intensity
164.9547882	0.17
174.8773804	0.02
177.0845795	1.45
178.0541687	0.15
204.1424713	0.05
227.1294861	0.18
253.0115814	0.04
271.0459290	100.00
272.1860962	16.97
295.1116028	0.99
313.1755981	0.65
314.2418213	0.09
459.2542114	1.25
460.3524170	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	371.1195
Annotation	Unknow
Peak:m/z	Relative Intensity
110.8945465	0.11
113.2975159	0.05
126.9619217	0.20
172.9995422	0.12
179.0196838	0.63
191.0017853	100.00
250.8835754	0.04
253.0270081	0.05
311.0376587	0.03
321.2169495	0.04
324.2288208	0.03
325.0643921	0.11
327.0962830	0.03
351.1242065	0.08
354.3107605	0.02
356.1257629	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	270.1695
Annotation	Heliohoustine
Peak:m/z	Relative Intensity
108.8370514	0.01
149.1514587	0.00
164.0131836	0.04
164.6945343	0.00
168.1228943	0.09
169.1060791	0.02
170.0637970	0.08
194.1394043	0.07
209.9445801	0.00
212.0696259	100.00
212.9245300	0.00
224.2687531	0.05
226.1855011	1.13
252.1735077	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.0701
Annotation	2-O-Acetyl-trans-coutaric acid
Peak:m/z	Relative Intensity
105.9274368	0.05
110.8924026	0.06
112.9236755	0.55
118.9385147	4.46
119.7317734	0.07
122.9155350	0.19
127.0506516	0.04
128.9086914	0.02
132.0761871	0.11
139.0175629	0.27
140.6315918	0.34
144.7251587	0.07
146.9038391	100.00
147.8805542	0.08
152.8937378	0.05
156.9339752	0.42
158.9497375	0.47
159.9706726	0.03
164.9603729	1.39
166.0492859	0.24
171.9831238	0.06
172.9532776	0.09
174.1859589	0.04
174.8275452	0.04
176.9450073	2.84
179.0149536	0.03
181.4149628	0.04
182.3515015	0.09
193.0714417	0.06
196.8768921	0.10
198.1127319	0.06
200.6051941	0.07
206.8817749	0.06
207.9433136	0.10
215.1459961	0.02
217.9223328	0.26
221.0947266	0.04
224.8955383	0.08
228.1282349	0.17
232.1507263	0.08
235.3188782	0.04
235.9456787	0.06
238.0791016	0.07
240.1497803	0.08
254.0285645	0.06
256.9371643	0.09
261.1429443	0.09
273.1510315	0.09
275.2309875	0.14
279.1513672	0.11
282.2664185	0.05
283.0560913	0.05
292.0743713	0.08
293.1279297	1.19
293.8999939	0.11
295.2332764	0.11
302.8574829	0.06
304.4264832	0.03
307.2218018	0.15
311.1792603	0.16
319.2811279	0.21
320.9733887	2.33
321.5967102	0.02
322.2395020	0.27
329.8636169	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	926.429
Annotation	Hoiamide A
Peak:m/z	Relative Intensity
361.380249	2.28
367.4028931	13.74
441.223938	1.81
485.5792236	2.61
519.59729	9.48
583.005188	4.50
648.4078979	2.44
681.8599854	4.90
763.5231934	10.36
907.5563354	6.03
925.2130737	6.61
926.4208984	100.00
928.46698	1.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	994.4902
Annotation	Unknow
Peak:m/z	Relative Intensity
498.4057617	0.09
544.7703857	0.04
548.3784180	0.16
710.6860962	0.06
814.7252197	0.49
815.4278564	0.10
832.3895264	0.99
976.3974609	0.61
994.5483398	100.00
996.8852539	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.296
Annotation	Taxezopidine J
Peak:m/z	Relative Intensity
198.0785522	0.12
211.0958557	0.29
240.1708527	0.08
241.2861481	0.28
247.0488892	0.07
253.3783875	0.15
256.0372620	0.19
257.9353333	0.50
266.3489380	0.14
267.2937927	0.35
273.0947876	0.07
293.4124451	0.12
297.6872559	0.13
304.2143555	0.13
322.6007385	0.05
337.5526733	0.21
342.1760254	0.09
361.1536255	0.54
370.9778442	0.04
372.0043945	0.26
378.2876587	0.13
382.1884766	0.43
384.5521240	0.21
387.2589722	0.47
388.0218506	0.07
399.5236816	0.31
401.2709961	0.07
402.2114258	0.74
407.2904663	0.44
409.3361206	0.33
415.2144165	0.35
417.3261108	0.23
418.3354492	0.43
429.1192017	0.12
430.1168823	0.20
431.0821533	0.17
435.4600220	0.15
439.6134644	0.07
441.5225220	0.20
459.3815308	0.11
469.1281128	0.11
470.5019531	0.18
475.1298218	0.12
479.5695190	0.15
489.4008179	0.24
493.0098877	0.44
494.2078857	0.14
497.2507324	0.60
503.1740112	0.39
507.3466187	0.63
508.3778687	0.25
509.4479370	0.56
513.7535400	0.23
518.5020142	0.05
519.3978882	0.08
521.4346924	12.03
522.6351929	0.93
525.3636475	0.73
533.3178101	0.10
535.5883179	0.81
536.5051270	0.27
537.4484253	0.07
540.2948608	0.48
547.4134521	0.14
549.3734131	1.74
551.2246094	0.19
552.9663696	0.30
553.5990601	0.30
559.0359497	0.20
560.5608521	0.28
561.4085693	0.23
563.4866333	7.53
564.3185425	1.83
565.4681396	0.92
566.2418823	0.38
567.5137939	0.75
568.2717896	0.08
573.3614502	0.40
574.1046753	0.09
575.5430298	0.15
579.2361450	0.59
580.6107788	1.22
581.4464111	14.06
582.4080200	1.03
583.5280151	0.28
585.3422852	59.29
591.5523071	0.45
592.5405884	0.29
593.5765991	0.34
595.3900757	100.00
596.4626465	5.98
599.2568359	0.41
600.8264771	0.11
604.4166870	0.45
605.4523315	0.30
606.7139282	0.14
607.3190308	0.37
609.4408569	9.00
610.4281616	1.89
611.2807617	0.49
611.9404297	0.73
613.3276978	6.54
619.2537231	0.28
622.3784180	5.95
623.3925171	34.04
624.3942871	4.32
625.4860840	1.01
626.6857300	5.87
627.4349976	27.64
628.9089966	0.51
630.2458496	0.09
637.3580933	4.19
638.4872437	0.70
640.6072388	0.21
656.5543213	26.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.2131
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
140.9895782	0.15
143.0727234	0.23
144.1304321	0.06
145.2086945	0.03
147.1661682	0.43
148.0752258	0.06
149.1381531	0.53
150.0030060	0.10
151.0803070	0.30
157.1419830	0.05
158.0329285	0.03
159.1462250	1.03
160.0408630	0.51
160.8641205	2.29
162.0325317	0.17
163.0890198	0.33
165.2370911	0.03
168.9128418	0.14
171.0649414	0.11
172.1172485	0.16
172.8493805	0.28
173.8540649	0.25
175.0989380	1.21
177.0371704	0.25
178.2334595	0.09
179.0499268	0.19
179.9639282	0.12
181.2303162	0.07
182.9477539	0.03
185.1612091	0.67
187.1611633	0.76
188.0541077	0.21
189.1932373	0.16
191.1313934	1.52
192.0597687	0.74
193.0848083	0.08
199.1960144	0.12
200.0403748	0.04
201.2655640	0.75
203.0587616	6.69
204.2047882	0.71
207.2681427	0.02
208.6757507	0.11
209.3268738	0.23
211.3096771	0.26
212.5286865	0.23
213.1577454	0.77
214.7761230	0.03
216.1042023	0.17
217.0354614	0.49
218.2122498	0.15
219.2018890	0.66
220.0423889	0.04
221.1911774	2.88
225.0936737	0.14
227.2531586	0.30
228.0851746	0.10
229.2031250	1.28
230.1497498	0.27
231.2110443	3.84
232.1844482	0.41
233.3233185	0.07
234.2010498	0.06
235.2756042	0.25
237.2425232	0.24
238.0951538	0.14
239.2163086	0.51
240.1089172	0.10
241.3343964	0.20
242.3287964	0.02
243.2472076	2.86
244.2842407	0.67
245.1684265	1.52
246.2541504	0.27
247.2911835	0.62
251.2960510	0.39
252.3730774	0.11
253.1835022	0.45
254.1232910	0.11
255.3002625	0.30
257.0588074	5.54
258.0397339	0.96
259.2006531	1.63
261.1644897	8.85
262.2929077	1.83
263.0776062	0.07
265.3164062	0.11
266.4025879	0.06
267.3892212	0.60
268.2911682	0.13
269.1865234	0.46
271.2341614	6.23
272.3263245	1.95
273.3084717	0.18
274.3187256	0.29
275.2656555	1.09
276.1679382	0.11
277.4376831	0.06
279.1394043	0.25
281.2091064	1.45
282.3274231	0.24
283.2212219	0.49
284.1947327	0.22
285.0161743	0.28
287.2665405	0.67
289.1404114	7.67
290.2738953	1.10
291.3420105	0.12
292.5398560	0.11
293.4054260	0.12
295.2455444	0.35
297.2930908	1.72
298.1972351	1.34
299.3073730	3.19
300.1441956	0.69
301.1547241	0.24
303.0783997	0.22
305.1239319	0.48
306.2893982	0.12
307.3038025	1.36
308.2398682	0.28
309.3120117	1.00
310.3239136	0.22
311.2929688	0.85
312.5906372	0.21
313.4144897	0.23
315.1528320	9.16
316.1969604	2.69
317.2282715	0.37
318.5161438	0.13
320.2073364	0.04
321.4232788	0.10
322.2683105	0.07
323.5209961	0.35
325.2229004	9.62
326.2934570	3.44
327.2896118	0.34
328.2647095	0.05
329.4307251	0.24
331.2999573	0.84
333.1984558	58.70
334.1793823	10.94
335.2534790	0.46
336.6681213	0.56
337.4642944	0.19
339.2719116	1.08
340.5627136	0.28
341.2446899	0.45
343.2906189	0.67
345.5563965	0.06
347.4773254	0.15
349.1508484	0.18
351.0488281	0.64
352.0736084	0.37
353.1962585	9.13
354.2548828	1.84
355.2449951	0.10
357.3525085	1.79
358.2172852	0.24
363.3851318	0.91
364.4309082	0.03
365.4790039	0.66
366.3615723	0.16
367.3343201	0.28
368.2460938	0.12
369.1225586	0.56
371.1085205	1.27
374.4570312	0.03
376.4542542	0.04
377.1737976	0.12
381.2240906	0.51
383.3230591	2.29
384.2667542	0.05
385.2540588	0.17
391.3596802	0.49
392.4722595	0.24
393.0744934	0.16
394.3484192	0.11
395.3547363	0.19
399.2472534	0.89
401.3139038	2.88
402.3003540	0.44
409.3524475	2.59
411.2765808	27.55
412.2865906	6.73
413.2018738	0.49
414.9067993	0.68
416.0444641	0.20
420.2030640	0.16
427.3476257	2.84
428.4659729	1.21
429.2741089	5.55
430.2267151	0.71
431.1668396	0.24
452.2618103	0.06
454.2893982	2.64
457.4268494	0.18
458.1454773	0.04
459.2693481	1.48
460.1863708	0.20
471.2894592	100.00
472.3007202	26.51
476.3442688	0.27
491.1742554	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	751.4153
Annotation	Phepropeptin D
Peak:m/z	Relative Intensity
209.2405090	0.05
219.2190399	0.06
222.1501465	1.09
224.1611023	0.04
225.1037750	0.17
228.1556549	0.02
229.1294708	0.06
238.1769714	0.09
239.4747009	0.26
240.3074341	0.11
241.2119293	0.13
242.4445038	0.13
243.2148438	0.26
248.0701294	0.05
249.0994720	0.03
249.8701172	0.01
254.0708618	0.14
257.1374817	0.18
265.2501831	0.21
268.0418701	0.21
270.0371704	0.06
274.3576660	0.22
275.2529297	0.04
277.1651001	0.07
279.0218506	0.04
282.0970459	0.02
283.1254883	0.15
285.3939209	0.03
286.3438721	0.03
292.1034851	0.03
293.4333496	0.02
295.3948975	0.02
297.3634644	0.20
297.9957275	0.02
299.2985840	0.17
305.2964172	0.02
308.1224670	0.03
310.4282837	0.02
314.4084473	0.11
317.4510803	0.07
318.2748413	0.06
319.2483521	0.10
321.4584351	0.11
323.3698120	0.03
324.2113342	0.10
325.2711182	0.08
328.3254395	0.07
331.3878174	0.01
333.3548584	0.03
334.4572754	0.02
336.2821045	1.43
337.2295532	0.02
340.3621216	0.37
341.5233154	0.04
352.3749390	0.06
354.3276978	5.37
355.5916748	0.14
356.3852539	0.18
357.1853027	0.08
357.7869263	0.07
359.7624512	0.02
360.3911133	0.02
362.5202026	0.05
365.2405396	0.02
367.3468018	0.08
369.3456421	0.08
370.5100708	0.03
371.3187256	0.10
378.3287964	0.23
379.3200684	0.04
379.9445190	0.01
381.3914185	0.22
382.3673096	0.04
388.4108276	0.27
390.3010254	0.04
391.4051514	0.07
392.2239990	0.02
394.6370239	0.20
395.3789062	0.23
396.4459839	0.39
398.2598877	0.04
399.3850708	0.06
404.3096924	0.20
406.3925171	0.53
408.5759277	0.06
410.2601318	0.66
412.3552856	0.14
413.3983154	1.42
420.0896606	0.03
422.2313843	0.56
423.3689575	0.13
424.2879639	0.01
425.4336548	0.07
428.6132812	0.07
430.5573730	0.09
433.4264526	0.04
435.3039551	0.02
438.1719360	0.04
440.0958862	0.19
443.4531860	0.34
446.3866577	0.06
448.0059204	0.30
449.3012695	0.18
450.5299683	0.03
451.4965210	0.02
453.5799561	0.02
456.5164795	0.02
461.5089111	0.01
463.4883423	0.18
464.5788574	0.03
466.4407959	0.98
468.1370850	0.12
470.5236816	0.03
471.4870605	0.15
477.5404663	0.06
481.4891968	0.23
482.3599243	0.20
483.7320557	0.22
484.4182129	1.69
488.7932129	0.06
489.6417847	0.16
491.4217529	0.14
492.5178833	0.23
493.5137329	0.10
495.2327271	0.10
497.3106079	0.03
498.5906982	0.02
499.4058838	0.06
500.4553223	0.03
505.4108887	0.05
506.8810425	0.14
507.5604858	0.54
508.3818359	0.29
509.4866333	3.33
510.4542236	0.16
512.3713989	0.05
513.4104614	0.05
522.7002563	0.10
523.4035645	1.38
524.4276733	0.40
525.4756470	0.53
526.4384155	0.72
527.3532104	0.37
528.5880127	0.03
534.4440918	0.02
536.3638916	0.06
541.4260254	0.93
543.6231079	0.02
544.6459961	0.02
550.4428101	0.02
552.5093384	0.02
553.4121704	0.13
554.6211548	0.02
557.9444580	0.04
562.6688232	0.05
571.3873291	0.08
577.5004272	0.25
578.5266724	0.03
580.4546509	1.69
581.9902344	0.03
584.4071045	0.06
588.5769653	0.04
590.4387817	0.05
593.6539917	0.06
598.4509277	9.04
599.0847778	0.03
603.4233398	0.04
605.5029907	0.50
607.1730957	0.08
608.5767822	0.03
610.1603394	0.02
611.4190674	0.02
615.6304321	0.04
619.6356812	0.04
623.5341187	1.19
632.7297974	0.04
636.5225220	0.37
637.3480835	0.07
637.9544678	0.01
638.5786743	0.05
650.5099487	0.34
652.5471191	0.04
654.5214844	0.12
655.3652954	0.07
659.3108521	0.04
662.6596069	0.07
672.4872437	0.04
680.5814819	0.18
684.4804077	0.06
689.5462036	0.09
690.6279907	0.58
692.4138794	0.12
706.4534302	0.07
707.7017212	0.51
708.6177368	0.20
715.3727417	0.11
716.4525146	0.02
723.4754028	0.03
724.7677612	0.05
733.6099243	3.91
734.7696533	0.37
751.5016479	100.00
752.2448730	0.58
752.8585815	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.19
Annotation	Baenzigeroside A
Peak:m/z	Relative Intensity
147.2890625	0.33
149.0425720	0.31
151.0499420	0.49
153.1833496	0.45
157.1448669	0.27
158.1822662	0.44
159.2533569	0.26
161.0558167	1.29
161.9049835	0.09
163.1186066	0.66
165.1323090	0.44
171.2009888	0.29
172.1220398	0.11
173.2646179	0.08
175.1463318	1.76
177.2761536	0.22
178.0266724	0.31
178.9133453	1.20
181.0138245	0.68
182.0625153	0.39
183.0520782	0.68
185.1462250	0.67
187.2355804	1.22
188.0469666	0.17
189.1060638	0.54
191.1020813	0.11
193.4825897	0.52
195.0164185	0.05
195.9845886	0.32
197.0980072	0.58
199.1184845	0.79
201.1544189	0.53
203.3847809	0.56
205.1206360	0.40
206.2058105	0.12
207.3402405	0.38
209.1289978	0.79
211.0598145	2.19
212.1563568	1.63
213.1759949	1.64
215.1877594	1.79
217.2506714	1.40
219.2644348	1.23
221.2021942	0.46
222.0693512	0.24
223.2217712	0.37
225.1734161	0.52
227.1954803	2.33
229.2625427	1.30
231.3275452	0.76
233.1548615	1.65
237.2908325	0.42
239.1571350	0.75
241.0842285	0.62
243.0081024	1.45
244.1010437	0.26
245.2135620	3.34
247.3231964	0.20
249.0046997	0.41
250.2765350	0.19
251.0622559	0.12
252.5038757	0.42
253.3010864	1.15
255.1780701	1.48
257.1969604	1.33
259.3854370	0.26
260.0969238	0.12
261.2812500	0.76
263.1623840	1.72
263.9533691	0.15
265.1542969	2.83
265.7662964	0.17
267.2929077	1.93
268.0725098	0.75
269.1823730	1.40
270.1999512	0.76
271.3419189	0.76
273.4285278	0.61
275.1678162	4.64
277.1589355	0.82
278.9486084	0.07
281.3733521	0.97
283.3175659	8.32
285.2240601	0.94
285.8688354	0.19
287.2357788	0.58
288.7930298	0.12
289.4004517	0.42
291.3618774	0.30
293.1331177	3.82
295.0979614	0.42
296.3368530	0.33
297.3570862	0.90
299.3024292	1.04
301.2503052	2.02
303.2866211	0.20
305.1392822	0.12
306.2441406	0.16
307.3029785	0.43
309.2749634	1.07
311.3330078	4.85
312.4742432	0.30
313.4132690	2.12
314.2174072	0.19
315.0635376	2.63
317.1943970	2.37
319.1979370	0.26
322.0829468	0.23
323.1644287	3.42
324.3636475	0.66
325.2455444	1.99
327.3065186	2.90
329.2236938	4.03
331.2642822	0.65
333.3370972	2.94
335.1635132	0.29
337.3630371	0.96
338.2812500	1.00
339.3610840	1.01
341.3213501	3.38
342.3394775	0.23
343.3736572	2.72
345.3121338	12.45
347.3294678	16.44
349.3179932	0.96
351.4192505	0.46
353.3348999	1.11
355.1533203	0.67
356.2104492	0.10
357.1505127	1.82
357.9254150	0.49
359.3356323	1.33
361.2767944	0.73
363.3676147	3.87
367.2192993	4.70
369.3392944	5.86
371.1951904	2.24
373.2430420	5.69
375.2252197	6.06
376.9044189	1.00
380.3332520	0.36
383.2416382	0.64
385.3508911	11.59
387.3237915	7.88
389.2514038	10.68
391.2903442	8.89
393.1464844	0.15
395.3334351	2.83
396.5802002	0.55
397.3980713	0.80
398.3524170	1.63
399.5181274	0.39
401.3860474	2.57
402.0880737	0.24
403.4638062	4.11
405.4035645	0.28
407.3533325	0.12
411.4323730	4.63
413.3286133	30.24
415.4447021	0.98
416.7320557	1.45
417.5851440	3.03
419.3029175	3.79
421.3294678	0.18
423.1752319	0.38
429.3850708	27.77
431.3262939	25.02
433.4678345	0.56
435.0770874	0.26
439.3437500	0.86
442.3824463	0.22
443.3817139	0.60
445.3137207	7.03
447.3164062	47.61
455.4008179	0.39
457.2370605	31.06
458.0332642	0.82
463.3851318	0.56
465.3978882	0.11
471.8439331	0.14
473.2197266	100.00
474.1056519	0.47
475.2258911	40.91
482.2745361	0.13
483.0082397	1.10
486.2960815	1.37
487.4192505	0.92
491.3081055	11.64
501.1829224	26.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	771.2308
Annotation	Kaempferol 4'-methyl ether 3-(2Glc-glucosylrutinoside)
Peak:m/z	Relative Intensity
229.3061523	0.26
258.1532898	0.13
286.3279114	0.95
287.2804565	0.30
295.3968506	0.28
298.1551514	0.15
299.1304321	0.04
301.0866089	25.20
313.2268066	0.38
323.9525757	0.11
343.0932617	0.62
343.9577026	0.15
367.0837402	0.23
385.2832642	0.33
409.3228149	0.13
410.7219238	0.16
427.1267700	0.25
428.9808350	0.25
445.3618774	0.17
450.4526978	0.21
453.3148193	0.12
460.1128540	0.42
461.6618652	0.82
463.1289673	72.83
463.7609863	0.18
465.3721313	0.13
486.7794189	0.16
487.4193726	1.24
501.3029175	0.05
505.2961426	0.34
511.3800659	0.22
521.1470337	0.14
541.2637939	0.90
552.1181030	0.04
552.9376831	0.12
558.2549438	0.06
561.0028687	0.10
571.2470093	0.13
573.6790771	0.30
589.0745239	0.78
590.2953491	0.07
597.4151001	0.11
607.4449463	0.79
608.6248779	0.44
609.2943726	0.91
621.3810425	0.26
623.2540283	0.09
625.1904297	100.00
633.4602661	0.32
669.1323853	0.17
675.9204712	0.20
681.2642212	0.07
687.2001953	0.62
704.3251953	0.20
716.8562012	0.11
717.6143188	0.99
726.5499878	0.06
735.1119385	0.76
738.7340088	0.46
752.6553955	1.01
753.3259277	4.69
759.5942993	0.36
771.1510620	20.60
771.7605591	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0673
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
103.0873642	0.21
110.9099884	0.36
118.8315430	0.07
127.1225739	0.08
129.0021057	2.86
134.1031494	0.09
146.9974823	4.13
149.1907959	0.14
163.1009521	0.63
173.0462646	2.41
174.9631042	0.29
177.9787292	0.12
180.9642792	0.07
189.0753479	0.16
190.9744873	100.00
193.0954895	1.43
205.0931854	0.06
209.0544739	49.44
213.2777405	0.10
230.9530945	0.13
240.9686584	0.10
261.1118469	0.09
293.3607178	0.04
311.1775208	0.16
317.0369873	0.08
319.4500427	0.18
337.0161743	8.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.1798
Annotation	Unknow
Peak:m/z	Relative Intensity
114.7638397	0.05
117.1171875	0.26
118.9223633	0.75
121.0566177	0.13
126.8810349	0.25
128.9267883	0.65
130.9866486	0.20
132.9668274	0.22
134.4049072	0.19
137.0646057	2.73
137.7439880	0.12
138.8426971	0.06
141.8465729	0.20
145.0481873	1.53
145.7918701	0.22
147.0254211	3.44
149.3039246	0.27
151.0455933	0.38
157.0231018	0.68
158.8886108	1.03
160.8863525	1.03
163.0325012	0.59
164.8873291	0.58
165.8896790	0.06
166.9961090	0.22
171.2271729	0.36
172.9807434	3.74
175.0914917	3.88
175.9411316	0.04
177.0528412	6.33
178.2170410	0.20
179.1580811	0.77
181.0718994	0.12
183.0118561	0.20
184.9570007	0.45
188.2642975	0.31
189.0235291	0.10
191.0534058	2.54
193.0230103	6.17
195.1426392	0.06
203.0630798	5.33
206.9771118	0.43
209.3503113	0.04
212.0610352	0.28
213.0724182	0.13
214.5376587	0.27
219.1168060	0.07
221.0393677	15.96
236.1578369	0.23
239.0681458	100.00
249.0308228	0.25
250.2064514	0.05
253.2287292	0.13
254.9407043	0.23
260.0783691	0.14
262.9028625	0.04
264.0638123	0.05
271.0470886	0.12
285.4890747	0.06
287.3084717	0.10
289.0240784	0.11
299.9162292	0.21
302.0670166	0.05
304.5178833	0.31
307.3565063	0.06
323.0480042	0.49
325.9184570	0.11
331.3964844	0.39
335.6492615	0.28
337.0939941	0.16
341.2454834	0.19
346.9205933	0.10
351.4188843	0.08
355.1365967	0.30
356.4435730	0.06
357.1898193	0.19
365.3471680	0.34
371.3297424	0.05
380.2948608	0.12
382.8830872	8.42
384.0633240	0.23
385.1282654	0.20
391.9577637	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.2573
Annotation	Kupitengester 1
Peak:m/z	Relative Intensity
178.9885712	0.59
190.9115753	0.26
193.0777283	0.22
199.0047302	0.59
201.8779449	0.24
208.0861359	0.09
210.8539429	0.07
216.9681702	12.15
219.2222137	0.86
226.0656433	0.09
230.4295044	0.06
232.9207153	0.27
234.9415894	0.14
238.9637299	0.13
241.2228241	0.12
244.5218658	0.33
269.1508484	0.33
271.3945007	0.17
272.2223206	0.23
274.2034912	4.16
288.0674438	0.23
289.2092896	1.17
293.8999634	0.55
295.7604370	0.07
308.2009888	5.87
311.1170044	13.09
311.9897766	0.39
313.1183472	0.18
319.3491211	0.10
323.0487366	0.30
329.2084351	37.64
331.1024475	0.44
335.3563232	0.09
339.4975586	0.08
341.3012085	0.19
345.2421875	0.15
349.3137817	0.13
353.7531738	0.39
356.3659058	0.18
357.0253906	0.09
364.1068726	6.28
365.2823486	0.72
383.3490601	3.25
403.2833252	0.18
404.1362915	0.20
415.2048340	0.12
416.3767700	0.38
422.6885986	0.13
437.5457764	0.06
439.6111450	0.72
440.2463379	7.69
444.8337402	0.18
451.8629761	0.12
458.2363281	100.00
463.1248169	0.18
473.6517944	0.05
476.1403198	3.99
483.2262573	0.13
491.3228760	0.20
492.2395020	0.42
499.1726685	0.51
500.3800659	0.59
506.0651855	0.54
509.1137085	0.44
539.4158325	0.22
540.2433472	0.08
545.5178833	0.27
563.4208374	0.14
566.3170776	0.10
575.8300781	0.27
583.3390503	0.12
584.3146362	0.72
600.2324829	0.17
601.8364258	2.51
602.5952148	0.06
607.2211914	0.09
614.1950684	0.59
619.3432007	1.49
620.2619019	5.46
621.7819214	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.0547
Annotation	Unknow
Peak:m/z	Relative Intensity
94.8653183	1.44
96.2044907	0.04
96.8880539	1.36
98.7415314	0.11
100.9848785	0.25
106.8349304	0.98
113.0264740	0.21
120.9942245	0.07
122.9351501	0.70
125.0008316	7.81
126.9086685	0.75
129.1587067	0.06
134.9118347	1.90
136.9345856	1.48
142.9332275	0.47
144.8703003	0.09
147.0070801	0.36
148.9904480	4.64
151.0765991	0.09
152.9638977	5.28
158.9751740	0.07
161.0044250	0.23
164.9545593	19.01
167.1087036	0.80
177.0260162	0.60
178.9810791	0.69
183.0842133	0.08
189.0065460	2.06
195.1033936	0.05
205.3182373	0.11
206.9867859	12.94
225.0397644	100.00
227.0530396	0.07
281.2450256	0.05
299.1377258	0.31
317.1926270	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1171.31
Annotation	Unknow
Peak:m/z	Relative Intensity
329.0944519	0.04
345.3058167	0.05
359.3984375	0.10
522.3458862	0.17
562.9038696	0.03
898.8166504	0.13
1170.1845700	100.00
1171.3098140	68.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	249.16
Annotation	NP 25302
Peak:m/z	Relative Intensity
71.8303299	0.10
83.9500122	7.16
84.8264008	0.12
85.9616089	34.03
92.9990463	0.08
94.9171295	0.59
97.0291290	0.05
100.7610931	0.05
103.0102386	27.39
104.8429718	0.10
106.9824982	0.95
111.9763489	3.31
113.8297119	0.76
114.8055878	1.05
116.8020325	0.74
119.0285339	0.06
120.9022369	0.54
121.9929352	5.22
126.6545258	3.00
127.9424896	11.26
128.9490662	16.32
130.6486969	0.36
144.9403076	0.53
146.8892975	100.00
147.8745270	0.05
151.0519562	0.14
155.2272797	0.25
156.0732574	0.06
163.9263916	0.08
166.1207581	0.04
172.3522797	0.42
173.0672760	2.39
174.7655792	0.41
182.8827667	0.35
187.0095978	0.16
188.2807770	0.22
190.0287018	76.99
191.2814026	1.06
203.0691223	0.69
205.2070923	0.33
207.2202911	6.14
207.9205475	0.04
213.2046356	0.28
224.8413391	0.60
230.3895721	0.54
231.0258942	4.33
232.1011200	83.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1336
Annotation	Oenin
Peak:m/z	Relative Intensity
150.0981750	0.02
184.0025024	0.01
203.1676636	0.03
269.2514343	0.03
299.4287720	0.02
306.8531494	0.01
308.4331665	0.02
311.7588501	0.01
312.9635315	0.01
316.1523743	0.01
319.6247864	0.01
331.2090454	4.82
336.2789917	0.01
339.2059937	0.08
341.0798950	0.03
343.0776367	0.14
344.2691040	0.02
355.1787109	0.06
361.1477051	100.00
361.7615051	0.21
371.2702332	0.02
373.2109680	0.91
385.0936584	0.01
385.9304504	0.00
392.3760681	0.01
397.2965698	0.28
401.4347534	0.02
411.6549988	0.03
414.0828552	0.01
416.4045715	0.01
417.1601257	0.01
425.1936951	0.02
427.0982361	0.21
430.0759277	0.01
438.5354614	0.08
439.2403564	0.02
447.4598694	0.01
456.2673035	0.03
457.2412109	0.50
459.4742126	0.02
461.2932434	0.01
464.3392029	0.01
465.3582153	0.03
475.1728821	2.33
475.7754517	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1169.2975
Annotation	Unknow
Peak:m/z	Relative Intensity
344.1269531	0.03
359.1672363	0.05
360.3643188	0.09
563.0529785	0.02
809.3853760	0.06
1125.9877930	0.01
1153.5352780	0.02
1167.0847170	0.05
1168.0919190	0.06
1170.1427000	100.00
1171.3099370	13.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1339
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
230.4766235	0.01
245.0795288	0.02
271.2805786	0.06
273.1865234	0.13
274.2553711	0.01
285.1173706	0.01
291.0900269	0.02
299.2570801	0.08
301.1215820	0.05
302.1340942	0.05
313.2608643	0.02
316.1190796	2.61
317.2276001	0.70
331.1410522	100.00
332.1347656	21.09
332.9328613	0.05
347.2062988	0.44
348.1681519	0.06
350.2379761	0.02
351.1171875	0.01
361.1138916	0.12
363.4245605	0.01
370.5286255	0.02
373.2680664	0.05
375.2372437	0.03
381.2642212	0.07
397.2446899	0.03
399.5386963	0.01
413.1882324	0.02
417.2530518	0.01
419.6822510	0.01
433.2906494	0.10
446.4414062	0.08
455.1482544	0.01
457.1553345	0.01
469.9312134	0.01
474.2180786	0.04
493.0916138	3.37
494.1079712	0.81
499.2259521	0.01
522.2025757	0.03
525.2091675	0.04
535.0393066	0.20
536.0712280	0.16
543.2406006	0.06
561.0655518	0.98
562.1600952	0.60
563.5889282	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.1635
Annotation	6-Acetonyldihydronitidine
Peak:m/z	Relative Intensity
129.9124603	0.05
139.0781097	0.04
142.9290161	0.04
144.8792419	0.02
156.0129547	1.98
157.0639954	0.01
161.2523193	0.01
161.9186707	0.25
165.7958221	0.01
167.1246338	0.03
174.0123291	0.19
176.8911438	0.25
178.9006195	0.61
184.0487366	0.02
187.2365112	0.02
188.0833130	0.02
189.1416931	0.06
190.8232117	0.01
195.9852600	0.01
199.1310272	0.05
206.9451904	0.04
209.0714417	0.04
210.0631409	0.86
212.9739685	0.05
216.0566406	0.28
222.9770508	0.04
224.2608795	0.03
225.1306763	0.02
229.6403809	0.08
233.2868958	0.09
234.0195007	0.04
235.1095276	0.02
241.9683838	0.27
243.0632629	0.05
243.9665527	0.01
245.4513550	0.03
251.1665955	0.01
259.0640869	100.00
259.7704773	0.27
265.0563660	0.01
267.2138367	0.05
270.1199341	0.01
272.0979309	0.23
273.1294861	0.05
277.0808105	0.22
282.0189209	0.03
285.0380554	2.08
289.5227051	0.03
290.7363892	0.03
298.9454346	0.03
308.1490479	1.28
313.0692139	1.33
322.1246948	0.02
326.1327209	0.01
329.7369995	0.04
331.0737000	0.98
331.6976929	0.02
336.8699951	0.01
340.1028442	0.01
342.8473816	0.16
343.4992065	0.02
344.1848145	0.02
352.2611084	0.01
362.3446045	0.01
364.8932800	0.02
370.2713928	0.08
371.0247498	0.01
378.3317566	0.02
388.2153320	3.57
389.0928650	0.09
389.8769226	0.06
395.9919739	0.02
416.5528259	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.2347
Annotation	Unknow
Peak:m/z	Relative Intensity
205.3185272	0.03
215.0824890	0.02
219.0595551	0.20
220.2033844	0.03
223.2848206	0.09
227.1943970	0.03
233.0139160	0.06
233.8210297	0.06
241.1920929	0.05
243.2091370	0.04
245.0561218	3.02
245.8831787	0.09
247.0530853	0.33
248.1515350	0.02
262.9102478	0.30
263.7603149	0.05
265.1892090	3.31
266.1412354	0.26
277.0480347	0.23
283.2553101	1.27
284.1695557	0.19
289.0741577	0.55
301.3532104	0.07
305.1421509	5.13
306.2053833	0.71
309.0773010	0.03
312.0770569	0.03
313.2523499	0.07
316.6169128	0.06
317.2350769	0.73
319.4677124	0.03
321.2318726	0.30
322.1101074	0.04
329.3057251	0.33
330.2338257	0.13
330.9728394	0.03
337.2457886	3.27
338.3543701	0.29
349.2540894	0.53
353.4233704	0.04
358.3676758	0.06
359.1398315	0.08
361.0241699	0.21
371.1369019	0.10
375.0531006	0.04
377.0699463	0.83
377.6876221	0.03
379.1490479	0.08
389.2285767	0.27
391.3179321	0.10
397.2311401	4.26
398.3429565	0.29
401.1438599	0.25
402.2777710	0.18
403.3690796	0.09
405.2264404	0.04
409.2172852	0.08
410.2982788	0.09
415.2767944	1.95
416.1752930	0.41
421.0957031	0.03
433.0803833	0.07
437.2893677	0.33
438.0026855	0.06
439.3505859	0.05
449.0801392	2.71
450.2485962	0.58
458.3033447	0.10
461.3479004	0.16
469.3106079	0.12
473.2144775	0.27
481.2402954	1.34
482.3780518	0.51
485.3856812	0.29
486.1985474	0.09
491.2325439	0.23
492.3231812	0.04
494.6065063	0.03
507.4583130	0.16
508.2429199	0.07
509.3767090	0.26
511.3878174	1.57
512.2406006	0.23
524.3469849	0.04
526.2672119	0.10
529.3851929	2.77
530.4669189	0.19
537.4367065	0.07
543.6947021	0.05
545.3613892	0.02
553.4890747	0.08
554.7067261	0.02
555.3690186	0.19
556.5067139	0.16
561.3433228	0.65
562.2692871	0.12
571.4094849	0.06
573.3400269	0.11
585.1927490	0.31
587.4851685	0.08
603.2803345	0.13
604.8818359	0.36
605.5100708	0.61
606.4822388	0.08
659.5190430	0.18
661.3215332	6.00
662.4307251	0.71
677.2547607	0.28
678.3774414	0.10
687.3035889	0.07
693.3713989	0.76
694.3547974	0.27
705.2892456	11.12
706.4360962	3.23
719.3208008	0.64
720.3927612	0.10
738.3667603	100.00
739.1869507	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	300.1606
Annotation	Ractopamine
Peak:m/z	Relative Intensity
92.02776337	0.06
92.88319397	0.08
104.9295807	0.13
106.0972824	0.18
106.9213104	0.18
108.0331421	0.20
115.7037125	0.12
117.1561584	0.07
118.0001221	0.11
119.043457	0.07
121.0416718	0.08
123.1771088	0.02
124.9741364	0.10
130.1160431	0.06
131.9986877	0.48
133.9559479	9.40
135.0461426	0.84
135.90065	0.23
137.0664673	0.06
141.0718689	0.02
142.2349854	0.03
145.075943	0.04
145.8869019	0.23
147.0284424	1.93
148.0392151	0.22
149.2446136	0.02
150.7652283	0.42
156.0752411	0.86
157.03125	0.11
158.0146332	0.09
159.0136719	0.66
160.0379944	0.83
161.142334	0.40
162.9313049	0.53
163.9537659	0.06
165.0661926	0.17
169.0444031	0.29
172.143692	0.20
174.3007355	0.18
175.0065613	0.02
176.0436401	0.14
177.0802612	0.25
178.0658875	0.03
185.202179	0.04
186.091568	0.47
186.9954529	1.24
188.0397797	3.26
188.6585693	0.07
189.2614441	0.43
192.5128784	0.07
196.8608398	0.04
198.0976257	0.27
199.0848389	1.28
200.1302185	0.22
201.2737427	0.10
202.1126404	0.16
203.2188416	0.07
204.1595764	0.18
207.5507812	0.15
212.1282349	0.14
213.1489868	1.68
214.1785889	0.35
215.1092834	0.12
217.0786743	0.16
224.2921753	0.04
225.2127075	0.31
227.1557007	0.34
229.161499	30.15
230.1953735	6.64
231.1144104	0.89
232.0823059	0.38
232.9256592	0.09
236.2739868	0.05
238.2731934	0.19
239.819397	0.12
240.4659119	0.12
241.9118652	0.83
243.3062134	0.13
244.1743164	0.34
245.1939697	0.76
246.1967773	0.20
253.1981201	0.29
254.5526428	0.26
255.3295898	4.04
256.1735229	7.10
257.1764526	1.47
257.8969116	0.07
264.4454346	0.04
266.0449829	0.05
268.2599487	0.04
272.1266479	0.11
273.2175903	1.00
274.3909302	0.31
282.1517639	100.00
283.1575317	26.51
284.9550781	0.59
286.1124878	1.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1253
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
159.8226624	0.05
160.9676514	0.10
172.9620972	7.43
175.1369934	0.47
178.0118866	0.22
191.0649414	3.58
191.9347382	0.48
192.9963989	9.75
193.9190369	0.29
201.9840393	0.21
203.0647583	0.09
204.8298950	0.15
217.1234436	1.46
218.0565491	0.07
233.1175842	0.40
243.1326904	0.07
249.2093506	0.07
259.0144043	0.15
260.5626221	0.07
261.1693115	2.43
262.2135315	0.03
264.3675537	0.05
287.1976318	0.23
302.1932068	0.18
305.1666260	0.16
305.9720764	0.10
323.2316284	8.71
324.1534424	0.91
341.4804688	0.10
349.1445923	1.67
367.0809326	100.00
368.0891113	7.48
385.1135864	5.76
386.1823730	0.73
387.4483032	0.69
399.3287964	0.09
499.0879517	0.10
517.3215942	0.07
543.1398926	1.95
544.2328491	0.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	240.159
Annotation	9-Angelylplatynecine
Peak:m/z	Relative Intensity
94.1232376	0.01
112.0157013	0.05
123.0271149	0.02
136.0342407	0.25
139.9572601	1.07
147.0790558	0.05
152.0657959	0.08
168.1800385	0.02
180.0645905	0.94
182.0297546	100.00
183.0055695	0.03
184.3888550	0.01
191.8248444	0.02
194.0950470	0.38
194.9173431	0.06
198.0882263	0.45
198.8569641	0.03
204.9669800	0.19
212.1633301	0.12
222.0323944	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	284.0236
Annotation	Unknow
Peak:m/z	Relative Intensity
96.8859177	4.41
142.0460510	8.56
158.0791016	0.83
186.0444489	1.49
195.9891663	0.65
202.1762390	0.07
204.0274353	57.68
209.9846802	41.62
222.0212097	100.00
238.0642090	5.77
240.0184937	0.07
241.0907288	0.10
266.1230469	4.56
284.4257812	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.1783
Annotation	8-Hydroxyluteolin 4'-methyl ether 7-(6'''-acetylallosyl)(1->2)(6''-acetylglucoside)
Peak:m/z	Relative Intensity
213.2459412	0.24
225.1361847	0.06
227.2436218	0.35
258.1199036	0.40
261.1501465	0.16
269.0702820	32.16
272.1816406	0.19
283.3096924	0.22
293.0999756	0.22
310.0548096	0.21
311.2314758	0.63
335.1494141	0.22
349.3459473	0.34
355.2052612	0.12
367.0734253	0.83
377.3845825	0.24
379.3391113	0.32
423.5612793	0.10
455.5166626	0.20
457.1333008	0.70
457.9158325	0.09
485.3425293	0.63
529.3649292	0.86
549.4151611	0.08
559.2727051	3.22
561.3723145	0.29
576.7290649	0.26
577.3817749	0.61
678.3280640	5.06
704.8239136	0.15
723.2953491	100.00
724.2485962	1.42
724.9092407	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1199
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
138.9120636	0.07
147.0860291	0.04
151.0865936	0.08
153.9795380	0.31
160.8542023	0.14
163.1521912	0.12
164.7806549	0.22
167.0685272	16.35
169.0869751	0.23
179.0390472	0.08
181.9937134	0.12
187.2233582	0.05
191.0128479	0.23
196.0172424	0.03
197.0634460	5.85
205.0187988	0.08
209.2105408	0.12
212.1325073	0.14
224.0630035	0.07
227.0908813	1.21
230.9335938	0.06
235.0561829	1.43
240.0333099	0.04
247.9171295	0.09
250.1170349	0.10
251.0531006	0.11
265.0753479	1.46
269.0845947	0.73
269.9510498	0.05
270.9690247	0.05
274.0886230	0.22
280.3528137	0.04
281.3689575	0.23
286.1036072	0.07
287.2144165	3.42
289.2728882	0.18
294.2964478	0.05
295.0828857	0.07
299.2496948	1.16
317.1755981	1.98
318.9927368	0.11
336.9431763	0.11
347.2699890	0.50
355.1347961	0.15
357.3721313	0.22
359.0524597	100.00
359.6709900	0.21
363.5203552	0.19
371.2318420	1.02
375.2582703	0.10
383.3291931	0.06
389.2299500	24.25
393.5774536	0.08
401.2997131	0.37
403.1495056	0.04
406.2905273	0.06
414.4737549	0.16
419.1880493	0.79
431.4214172	0.17
432.2166443	0.47
433.3723145	1.82
435.3619080	0.25
437.3038635	0.08
443.4338989	0.56
449.2965393	0.86
461.1470642	7.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	559.2557
Annotation	Penisimplicin A
Peak:m/z	Relative Intensity
235.1767120	0.04
351.6666870	0.23
361.2717896	0.04
379.2442627	0.02
395.2940674	17.54
397.0937500	0.12
397.7342529	0.24
413.5164185	0.31
419.3299561	0.14
439.3656616	15.09
455.3533325	3.51
463.4334106	0.06
499.2662964	100.00
500.0917358	0.04
519.3133545	0.26
521.3560791	0.11
527.5260620	0.03
540.6281128	0.07
541.4321289	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.154
Annotation	Vaccinine A
Peak:m/z	Relative Intensity
79.9226456	0.12
85.9778137	0.09
88.9212036	6.02
97.9270020	2.60
101.1163177	0.04
103.0147400	0.23
109.9304199	0.15
111.8829346	0.25
113.9477997	13.71
114.9488525	11.11
124.9511261	0.06
128.9159088	0.08
133.1623077	0.06
136.9511566	0.57
138.7736511	0.03
141.0726318	0.15
144.9858551	0.30
151.9503021	8.57
155.1812592	0.03
160.9259491	0.05
163.2258911	0.12
164.9245911	0.02
169.3768463	0.04
173.1185913	0.03
175.1501617	0.57
176.9952545	82.66
181.0705261	0.06
183.0301666	0.32
190.9225159	0.05
192.0962830	0.02
194.1268463	0.34
195.1911774	0.05
199.1871490	0.55
203.2047272	0.04
206.0488434	23.44
209.2325592	0.13
211.2359772	0.11
217.0027466	0.06
219.1926117	0.22
221.0985870	0.02
223.2646332	0.94
224.1529999	0.12
229.0374298	0.35
233.4530640	0.04
234.7412109	0.12
237.2064209	0.18
241.6541290	0.03
247.1673126	1.50
248.1080170	100.00
249.1408844	0.05
255.4174805	0.09
256.4237061	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	493.1331
Annotation	Oenin
Peak:m/z	Relative Intensity
174.2253876	0.02
328.3890991	0.03
331.2330322	1.21
343.1593018	1.83
346.3599243	0.03
355.3201904	0.07
357.9583740	0.06
371.0321350	0.10
373.2573547	29.77
393.2870178	0.04
397.1808167	23.16
397.8636169	0.09
409.2856140	0.13
415.4316406	0.02
421.2306824	0.33
427.1405334	49.54
427.8499756	0.08
433.2451172	0.07
439.1680298	15.80
439.7942200	0.11
449.5884094	0.03
457.1809082	23.29
475.1455994	100.00
475.7628479	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	522.2476
Annotation	Sapintoxin A
Peak:m/z	Relative Intensity
152.0291138	0.06
153.1597595	0.03
162.9645844	0.03
163.9621887	0.08
167.1446686	0.13
170.9213562	0.09
177.6911926	0.08
179.2365723	0.20
193.2066193	0.13
194.3668060	0.01
195.9558258	0.14
205.2699127	0.13
207.1152954	0.41
214.0175018	1.09
217.0149841	0.02
219.3616180	0.07
220.8891296	0.05
226.1337128	0.02
231.2200623	0.43
232.9913635	0.21
247.1596222	0.01
249.2848816	6.60
261.1260681	0.01
263.2945557	0.11
265.4428711	0.11
267.2580566	0.02
275.2418823	4.40
275.9298096	0.02
281.3106384	2.20
285.2491455	0.02
289.5186157	0.02
293.2619629	54.68
295.9689331	0.02
297.0627441	0.05
298.0426636	0.01
299.1024780	0.03
300.0574341	0.02
302.2546387	0.09
307.2765503	2.77
308.2644653	0.33
312.2247925	0.15
313.2760620	0.10
314.2797852	0.03
316.4575806	0.03
317.3134155	0.09
322.1604614	0.04
323.1906738	0.12
325.2636108	100.00
327.3913574	0.10
329.3297729	0.16
330.2941895	0.03
339.1271362	0.03
342.0470581	1.40
343.1119995	4.38
344.2393188	2.66
345.0615234	0.24
349.4014893	0.04
351.3801880	0.01
353.2262573	0.03
357.3117676	0.81
358.1085205	2.27
359.1240845	3.62
360.2391357	1.38
361.4263306	0.03
367.1527710	0.91
368.3766479	0.10
370.4733276	0.07
373.2495728	0.05
374.0496826	0.19
375.1422729	0.02
381.1536255	0.02
385.2056274	0.03
386.3225098	0.14
387.3457031	0.05
398.1750488	0.03
399.2598267	0.57
400.1274414	0.03
400.9367676	0.09
402.2593384	0.11
414.2618408	0.16
417.3563843	0.07
423.5368042	0.03
430.2812500	0.15
431.2033691	0.02
432.2186890	0.01
433.1707764	0.04
441.4105225	0.07
446.3720093	0.40
448.0728149	0.04
452.0950928	0.07
457.3096924	0.09
458.2429199	2.80
463.4926758	0.07
473.4489136	0.10
475.3614502	0.44
478.3420410	0.22
480.3098755	0.03
484.4086914	0.04
485.6382446	0.13
486.4011841	0.11
490.2445679	12.58
491.2883301	0.57
492.3596802	0.19
496.1680908	0.01
503.7715454	0.07
506.1884155	47.80
507.1868286	22.13
508.4570312	0.02
523.2752686	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.24
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
149.1314392	0.43
150.9601746	0.04
153.2950134	0.06
155.1868439	0.17
158.1719971	0.10
161.1639862	0.12
165.0051880	1.05
166.7969055	0.09
169.0429993	0.04
173.0946960	0.85
174.1088104	0.07
175.1222534	0.64
177.1415405	0.55
179.1248779	0.31
185.1310577	0.42
187.1558533	0.70
188.1612549	0.09
189.0228882	0.58
191.1500549	0.45
193.0831299	0.72
195.3040619	0.25
198.1331329	0.06
199.2198486	0.30
201.1240845	0.39
203.2310791	0.44
205.1065369	0.26
207.0521240	0.20
209.1438904	0.33
211.1626892	0.40
213.1713562	0.38
215.2958679	0.23
216.2843323	0.08
217.2632599	0.60
219.1666565	1.08
221.2608948	0.35
224.9665680	0.08
225.6626892	0.06
227.1427155	1.45
229.0744019	0.64
229.9300690	0.08
231.1860046	1.77
233.1257324	0.53
235.1298065	0.43
237.2724915	0.12
238.1944275	0.07
240.3512268	0.31
242.9511414	0.41
245.2209473	0.96
247.2235565	0.10
249.1932068	1.52
251.3691406	0.16
253.2656860	1.04
255.1588745	1.10
257.3127441	0.08
259.1740723	0.12
261.1787109	0.78
263.2228088	1.36
265.3967285	0.06
269.2549744	0.26
271.3019104	1.58
273.2567749	1.02
275.2574463	0.43
277.2894897	1.55
277.9740601	0.07
279.3238525	0.20
280.0756226	0.20
283.3380127	0.04
285.2150269	0.24
287.2483521	0.40
289.2666626	3.17
293.3163452	0.47
295.2443848	0.95
295.8685303	0.05
301.1336670	0.32
303.2260742	0.31
305.2750854	0.16
307.2497559	2.48
309.2398071	0.55
311.2630615	0.15
312.7737427	0.42
313.4038086	1.62
315.5064087	0.10
317.1365967	0.25
319.3872070	0.17
323.4223633	0.31
327.3822632	0.33
328.4678345	0.05
329.4208374	0.06
331.2144165	1.53
332.9649048	0.22
341.9673462	0.08
343.1088867	10.15
344.2209473	4.26
345.3099976	1.26
347.0560913	0.04
349.4387207	0.24
351.2521973	0.21
357.6209717	1.95
358.2639160	4.19
359.2383423	5.81
360.2039795	0.05
363.3051147	2.13
367.2986450	0.08
369.0386963	0.40
370.1839600	0.08
372.2244263	0.23
373.1580200	0.15
381.3082275	0.26
385.5760498	0.19
386.4629517	0.06
393.4828491	0.13
401.1489258	0.22
407.0959473	0.13
411.1960449	0.08
413.3653564	0.10
416.2059326	0.41
417.4631348	0.48
425.4400024	0.09
437.4068604	0.04
441.4627686	0.15
445.3847656	0.22
447.1690674	1.76
453.5458984	0.05
459.3914795	0.19
462.3908081	0.19
463.6502686	0.14
471.4536743	0.13
472.3336182	0.13
475.1901245	0.31
476.0756226	0.13
477.4600220	0.83
485.1621704	0.69
489.2056885	0.70
490.0514526	0.08
491.1953735	1.55
492.1627808	0.06
503.4069214	1.41
506.1567383	100.00
507.3267212	2.73
522.2338867	2.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	392.15
Annotation	2-(Glutathion-S-yl)-2-methylbut-3-en-1-ol
Peak:m/z	Relative Intensity
115.7810287	0.24
121.1440659	0.09
124.5840454	0.06
130.0467529	0.13
135.9484406	0.23
143.0653381	0.25
148.9481506	4.61
149.9644165	0.30
160.0254211	0.36
162.0403137	1.62
162.7961426	0.08
167.0574036	0.76
175.0946960	0.16
179.0341644	1.01
184.7486877	0.07
187.7874146	0.04
194.9416962	0.34
196.0376434	0.58
202.4708252	0.23
204.9817047	0.22
226.1362305	0.09
227.9254761	0.24
228.9561157	0.28
245.0764160	100.00
245.7727356	0.53
251.7807312	0.30
253.2697449	0.22
260.5484314	0.23
261.2941589	0.06
263.0764160	10.46
270.9629211	1.82
272.2864990	0.19
274.1265259	0.26
276.1695557	0.24
278.9158325	0.37
279.9035950	0.22
286.0370178	0.14
293.0500793	0.03
299.0178833	1.34
301.8099976	0.17
308.3267822	0.16
317.1259766	5.10
317.7684021	0.11
329.2846680	0.27
330.5531006	0.10
331.2974548	0.28
332.2672119	0.03
333.3059692	0.17
334.2988281	0.28
336.7756958	0.29
338.6503906	0.11
342.6519165	0.21
344.3119507	0.10
346.3040771	0.35
348.0895081	0.24
349.2183838	0.17
351.4335022	0.07
355.1455383	0.43
356.2304382	0.77
359.2046204	0.22
361.0942383	0.55
370.8266907	0.28
373.4554749	0.89
374.3110962	6.90
375.3067627	0.79
382.8681946	0.11
395.3550720	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	398.201
Annotation	Unknow
Peak:m/z	Relative Intensity
130.0190735	0.04
132.0136719	100.00
146.9428711	0.27
148.0646973	0.10
152.8625488	0.20
170.3016052	0.04
180.1382751	0.12
182.2538300	0.07
189.9692230	0.03
190.9934540	0.08
211.1826782	0.05
217.2175293	0.08
218.0216980	0.18
222.9644165	0.02
227.1839600	0.07
231.7688904	0.09
235.4873352	0.55
236.1887817	0.05
238.9939270	0.07
250.9318237	0.07
265.1912537	0.26
266.8103638	0.24
277.2043457	0.12
294.1719360	0.11
307.7543640	0.03
323.2431641	0.13
337.9320679	0.53
344.4008179	0.05
354.3624573	0.02
362.5747375	0.23
379.1525269	0.10
380.2593079	0.85
384.2060547	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	361.0906
Annotation	Acerosin
Peak:m/z	Relative Intensity
122.9969177	0.07
150.9590607	0.31
151.8060608	0.05
194.8150635	0.01
197.9753876	0.08
212.9963226	0.71
259.0079956	0.07
273.2563782	0.03
297.0609436	0.02
299.0918579	0.11
300.1027527	0.02
301.1251221	0.13
313.0923157	0.04
315.2109375	0.29
316.1336975	0.07
317.9822998	0.03
319.1263123	0.03
328.1007690	21.73
329.2503662	2.69
330.0771484	0.19
331.0706787	30.14
332.1844177	3.03
343.1560364	0.82
344.1191101	0.31
346.1493225	100.00
347.0773621	13.43
347.6859741	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.19
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
193.1691589	0.30
204.1633911	0.04
222.9275208	0.06
269.3566284	0.10
274.3213501	0.10
301.7145996	0.05
303.0762634	0.04
306.7655945	0.05
312.2943420	0.05
317.1907349	0.10
330.1802979	0.21
331.2265320	0.88
335.1875000	0.09
340.2974243	0.09
342.2967529	0.05
345.4238892	0.15
346.1327515	0.04
347.2503052	0.35
348.0537720	0.20
352.5321655	0.11
357.0011597	0.04
358.2501831	0.14
361.2192993	36.62
364.0729370	0.15
373.4895630	0.33
382.1131592	0.07
388.3452759	0.26
397.4248657	0.13
407.1934814	0.21
439.3526611	0.15
445.8327637	0.31
457.3554688	0.11
470.6563721	0.11
473.9530029	0.18
475.5125122	0.29
479.3847046	0.11
486.4238281	0.24
492.7608032	0.68
493.4090576	1.55
501.6502075	0.06
505.2169800	0.17
508.2628174	0.31
509.0961304	0.28
511.4333496	0.13
516.4772339	0.06
523.0896606	100.00
523.8031006	0.54
535.0534058	0.16
564.9063721	0.42
569.3634033	0.28
572.8779907	0.19
573.6843872	0.52
576.9652710	0.21
593.8827515	0.10
596.5244751	0.44
597.7067261	0.29
600.4608154	0.14
601.4541626	0.12
611.6314697	0.32
619.0918579	0.05
621.6767578	0.42
622.4033813	0.46
623.2172241	0.09
636.3032837	0.90
637.2564087	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0714
Annotation	Deoxyinosine
Peak:m/z	Relative Intensity
143.0940704	0.34
145.8536224	0.56
148.8874054	0.38
165.1613159	1.49
166.8778534	0.40
169.1898651	0.47
179.1066437	2.19
180.8477631	1.39
182.1888275	0.41
193.1967316	1.73
206.9967804	5.82
208.0009918	8.38
209.2229767	0.57
222.0697479	6.01
223.1275024	9.46
224.1593781	0.87
251.0814056	100.00
252.1406403	18.08
252.7744598	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1563
Annotation	a-L-Fucopyranosyl-(1->2)-b-D-galactopyranosyl-(1->2)-D-xylose
Peak:m/z	Relative Intensity
132.9606171	0.09
136.9616241	0.07
152.8841248	0.05
162.9669952	0.06
171.1434021	0.05
172.9675751	0.42
179.0380554	0.34
191.0032959	63.56
205.0250854	0.08
208.2645874	0.09
250.9203491	0.19
253.2050171	0.11
265.1894836	100.00
282.1348267	0.06
290.9573364	0.07
295.1308289	0.13
307.1434937	0.05
309.1881104	0.08
311.3695374	0.08
317.9501343	0.04
321.0130310	0.13
325.0584106	0.16
325.9134521	0.08
327.1477661	0.23
341.1803589	9.37
361.3867493	0.14
367.4865112	0.22
371.2768860	0.13
376.9374084	0.08
378.8864136	0.15
410.1879883	0.42
411.1582947	0.64
413.2250061	0.07
419.2638550	0.04
421.4066772	0.11
424.9745789	0.16
437.1918640	0.49
438.3659668	0.92
439.0053101	3.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.2526
Annotation	Echinacoside
Peak:m/z	Relative Intensity
240.1199036	0.54
311.9278564	0.84
323.300293	0.54
340.0726318	0.48
383.2416382	2.77
405.2661743	0.39
413.0161133	1.68
413.6760254	0.39
437.3929443	0.66
467.288269	0.55
478.291626	0.50
503.0687256	3.01
513.3897705	0.49
522.1738281	1.36
533.2653198	2.18
563.4365845	0.35
587.3362427	1.40
623.3629761	1.00
653.3744507	0.29
665.2670288	4.00
677.7929077	0.73
704.6626587	0.37
749.1394653	0.40
754.4841309	0.96
785.2575073	100.00
785.9729614	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0461
Annotation	Unknow
Peak:m/z	Relative Intensity
80.9919891	0.04
82.9560242	0.05
84.9381485	10.49
86.7420044	0.06
100.9568481	0.48
110.9312286	8.71
125.0643005	0.24
128.9603882	1.92
130.9285889	0.06
132.8516235	0.12
143.0183563	0.25
147.0391998	0.30
159.0323334	0.17
161.0405273	0.72
163.2605743	0.02
172.9002533	0.47
177.0314484	0.21
186.9527283	2.34
202.9212189	0.02
205.0187073	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1979
Annotation	Methyl hesperidin
Peak:m/z	Relative Intensity
175.1455688	0.06
179.1581421	0.05
197.1235962	0.02
198.8778076	0.08
201.9294891	0.02
206.1076355	0.03
211.0983429	0.13
212.1921844	0.03
213.2396545	0.04
215.0063782	0.11
216.0911560	0.03
217.2704926	0.05
221.9473419	0.05
227.0692902	0.23
228.8623657	0.21
229.9942169	0.04
233.1965637	0.07
241.1801300	0.49
243.2329407	0.03
244.2857971	0.02
245.0868683	0.05
247.1306610	0.11
249.7728271	0.01
252.1151428	0.04
256.0124207	0.15
257.1274414	0.02
258.2536926	0.26
265.2764893	0.02
267.4060059	0.05
271.1326294	0.95
271.9782715	0.08
273.1089478	0.61
276.2331848	0.05
279.2633667	0.06
281.2094116	0.04
282.2322388	0.15
285.0051880	0.54
287.3238525	0.08
291.2626648	0.03
295.9951782	0.04
297.1768799	0.16
298.1906738	0.05
299.1798706	1.69
300.2379761	1.99
310.4050293	0.05
311.2854614	0.11
313.3417358	0.37
315.1215820	100.00
317.3038330	0.06
319.0659180	0.05
320.2286987	0.03
322.5283203	0.05
324.1280518	0.16
326.0856018	0.04
327.3132935	0.24
329.1557617	1.48
337.2778320	0.20
339.1506958	5.52
341.5484619	0.18
342.2623291	0.11
343.0367432	0.07
351.2395630	0.06
353.2938843	0.10
354.2807007	0.13
355.3228149	0.02
355.9989014	0.20
357.1915894	15.42
365.3114014	0.05
368.0285645	0.09
369.2315063	2.01
371.1651611	0.24
381.2446899	1.57
383.1353760	0.14
387.2595215	0.50
399.2487183	3.17
401.2055054	0.39
411.0013428	0.15
417.2470093	2.20
423.3740234	0.14
425.0386963	0.03
431.1097412	0.05
435.3889771	0.03
441.2024536	0.44
443.3414307	0.52
458.0693970	0.04
459.2038574	1.28
461.2426758	2.54
475.5850830	0.08
477.3596191	0.40
478.0872803	0.08
479.3920288	0.04
485.3327637	0.13
487.3491211	0.08
488.3248291	0.02
489.4899902	0.02
503.2829590	12.46
533.2410889	0.06
545.3714600	0.03
560.5388184	0.01
577.1499023	0.02
579.3895874	0.03
587.0739136	0.02
608.2470703	0.19
623.3978882	0.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	643.1642
Annotation	Unknow
Peak:m/z	Relative Intensity
183.8307190	0.05
213.1303101	0.02
244.2822876	0.10
264.0124512	0.07
265.0527344	0.41
266.1445312	0.11
282.0366821	0.06
283.0207520	0.26
284.2350159	0.03
285.2843018	0.01
295.5419006	0.02
299.9965210	0.09
300.8649597	0.03
312.9880981	0.05
314.4484558	0.02
315.2284546	0.01
316.1697388	0.13
324.9625244	0.02
328.1831055	1.54
329.1951904	0.20
331.1266479	3.95
332.1150513	0.69
332.7684937	0.02
339.0301514	0.02
341.0615845	0.02
344.2567749	0.05
345.5709229	0.12
346.1820679	2.25
347.1816406	0.81
356.9118652	0.02
358.3911133	0.01
361.1592407	100.00
362.1353760	18.70
363.0515137	0.18
403.2152710	0.03
427.3189087	0.05
428.1735229	0.06
435.7126465	0.05
477.2746582	0.03
480.2580566	0.05
481.3002319	0.06
482.6018066	0.03
490.0195923	0.02
497.3474731	0.01
522.3826294	0.20
523.0654907	0.62
524.1666870	0.05
558.6500244	0.03
579.3373413	0.02
580.9169312	0.01
584.3934326	0.02
586.5170288	0.01
599.3676758	0.02
611.3516846	0.25
612.3056030	0.15
645.5702515	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.1973
Annotation	2-Epihelmanticine
Peak:m/z	Relative Intensity
137.2156677	0.06
146.9974365	0.08
149.3304596	0.03
150.8051147	0.04
153.0630798	0.30
155.0183258	0.09
159.0066528	0.06
159.9040680	0.03
161.1504211	0.20
162.4552460	0.11
163.1020050	0.20
165.1566010	0.02
170.8829041	0.04
175.1084442	0.14
179.1219330	0.05
182.4163818	0.03
183.0622406	0.31
185.1847839	0.28
186.1585846	0.16
187.0938568	0.22
188.2959442	0.04
193.3802338	0.04
195.1557617	0.08
197.1661987	0.35
198.2004852	0.23
199.0762024	0.27
201.1093445	0.23
203.1715088	0.19
205.1236877	0.04
211.0490112	0.19
211.9415283	0.04
213.2250366	0.37
215.2063599	0.59
217.2880859	0.05
219.2569427	0.24
221.1318054	0.05
222.5050201	0.03
223.3309174	0.12
225.0651398	0.19
226.3968964	0.03
227.1020050	0.08
228.0785065	0.05
229.1717224	0.25
231.0558319	1.74
232.3643494	0.05
233.2959900	0.14
235.3215637	0.12
236.1619873	0.07
237.2607422	0.23
238.3550110	0.06
239.0164795	0.24
241.1979065	0.32
243.2042542	0.03
244.9877014	0.15
247.3099823	0.03
248.0206299	0.12
249.2886658	0.17
251.3683167	0.21
253.2175598	1.13
254.7017212	0.12
255.5002136	0.04
257.0888977	0.10
259.2451477	2.51
263.2903442	0.15
265.1766357	1.19
267.1796265	0.29
269.3352356	0.26
271.2633362	0.15
273.3536377	0.23
275.3702698	0.25
276.1240845	0.04
277.2052307	0.36
278.1830444	0.03
279.1042480	0.15
281.1749268	1.15
283.2255859	7.83
285.4639893	0.11
289.3251648	0.15
291.2810364	0.24
293.2533569	4.77
294.2284241	0.05
295.2087402	0.58
296.6920471	0.11
297.3322144	0.21
299.1345215	0.54
299.8524780	0.06
301.2786865	0.12
307.1229858	0.50
308.6003723	0.05
309.2606506	1.24
310.3917847	0.08
311.2625122	2.22
313.3607788	0.05
315.3049011	0.05
317.2081909	2.11
319.3450928	0.34
320.3334656	0.10
321.2636719	1.86
322.3889465	0.22
323.2282715	0.29
325.2435913	1.11
327.3145752	2.71
329.2373047	0.09
333.4468079	0.34
335.0143738	0.12
337.1827393	45.92
337.8462524	0.10
339.2431641	0.05
340.4137573	0.10
341.3515320	0.15
343.4057922	0.08
349.2430725	0.08
351.3323975	3.27
352.4529419	0.06
353.3026733	0.48
354.5773010	0.61
355.2159424	4.18
357.3038635	0.23
363.2728271	0.19
365.3640137	1.10
367.4721375	0.05
369.3199463	9.48
371.5545654	0.05
379.2545776	0.93
380.4126282	0.12
381.5945129	0.21
383.3013916	4.65
385.2399597	0.85
390.4233398	0.08
392.4655762	0.08
395.2958984	2.66
397.2548828	0.05
398.1678162	0.22
399.3333740	0.98
407.2040710	0.08
409.2096252	0.30
411.1952209	0.43
413.1904602	12.59
415.2587585	0.06
421.2630310	0.03
425.3462524	0.43
427.1199036	3.25
427.7521667	0.02
429.3214722	0.04
439.3222961	0.03
442.0086365	1.57
443.2844543	0.61
444.4390564	0.05
454.4000549	0.03
457.2399292	100.00
457.8502502	0.31
469.3751831	3.52
470.2045593	0.01
472.0388489	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	413.14
Annotation	N6-Carbamoyl-L-threonyladenosine
Peak:m/z	Relative Intensity
118.9029388	0.06
120.0240021	0.46
126.9570084	0.37
128.1081543	0.43
128.8721771	0.02
136.0232391	0.88
145.0691223	0.75
146.0974121	0.43
146.9126282	0.14
160.8520050	0.06
161.9688110	2.87
162.9683685	0.61
164.0031128	0.31
172.2523804	0.07
177.0562744	0.02
180.0647888	0.04
181.0704651	0.04
186.0945587	0.02
200.7445831	0.04
202.3243561	0.03
213.1811829	0.10
221.0480652	0.10
225.2367554	0.18
233.2174377	0.06
244.2338257	0.06
248.8623352	0.09
249.9974365	0.20
251.3262024	0.09
262.0516968	0.10
268.1438599	4.02
269.3964233	0.03
272.2562866	0.06
273.0327148	0.02
275.1991882	0.03
277.1790161	0.03
281.0984497	100.00
286.0401611	0.05
293.0958557	0.07
294.0072632	0.85
298.0505371	0.06
301.1771851	0.03
311.0509949	0.02
313.3457031	0.08
314.4195251	0.05
322.8862305	0.12
324.2622375	0.03
326.2361450	0.03
327.4877319	0.05
329.5338135	0.03
332.0856018	0.06
337.3040161	0.23
340.1917725	0.02
345.5002747	0.02
349.1777344	0.07
350.2352600	0.03
351.1873779	0.06
352.0925598	0.04
353.2295227	0.13
355.3445129	2.50
356.8292847	0.05
359.1892090	0.06
361.2618103	0.04
368.1531372	0.38
369.3164673	0.05
371.1064758	0.07
376.1066895	0.21
377.1264343	0.84
379.2737732	0.02
382.1706848	0.06
385.9828796	0.04
388.1658020	0.03
393.9469910	0.40
395.2508850	1.53
396.1269531	0.03
404.5060730	0.21
420.2768860	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.196
Annotation	Geniposide pentaacetate
Peak:m/z	Relative Intensity
177.0436249	0.23
214.0361328	0.10
225.3890381	0.11
230.3887329	0.11
245.2602844	0.14
249.3552856	0.12
261.2702637	0.18
265.1296997	0.08
266.5250854	0.14
277.0282288	0.09
280.1511230	0.08
286.1199341	0.12
287.3405151	0.07
292.2321777	0.14
293.3931274	0.53
296.3286133	0.07
299.0674438	0.09
308.4620972	0.09
312.3464355	0.11
315.2917480	0.11
317.1596680	0.04
324.4859009	0.05
333.5091553	0.09
334.4355469	0.11
340.9904175	0.13
342.1779785	0.08
355.3052368	0.16
359.2891846	0.60
368.2344360	0.15
371.0406494	0.32
377.2293091	0.11
379.1943970	0.19
383.2084961	1.15
384.2672119	0.09
389.4768066	0.14
395.2577515	0.50
400.3240356	0.08
407.1649780	0.54
408.2330322	0.08
413.0856323	0.45
417.1770630	0.07
418.9935913	1.50
419.6041870	0.07
420.2145996	0.07
425.1367798	0.96
425.9930420	0.43
429.3195801	0.11
431.1759644	2.56
432.2397461	0.43
434.0961914	0.03
434.9713745	0.19
437.1522217	1.93
438.2391357	0.59
443.1744385	1.72
444.0679932	0.11
445.9260254	0.12
449.2029419	1.41
451.6340942	0.08
453.2249756	0.58
456.2199707	0.06
461.1784058	23.40
462.2145996	1.19
465.2875366	0.19
467.3656006	0.12
468.3159790	0.15
470.4267578	0.20
477.2891846	0.17
479.1278687	9.10
480.1098633	0.22
485.2134399	7.66
486.2863770	0.45
491.3913574	0.90
492.2077026	0.05
497.1118774	1.26
497.8058472	0.16
498.6304932	0.14
501.3942261	0.07
503.5204468	0.11
509.3402710	1.14
510.2471313	0.35
515.0975342	6.58
516.1583862	1.03
525.4794922	0.10
527.1621704	12.60
528.2772827	1.28
533.3309937	0.11
537.4860229	0.28
538.4066772	0.05
542.6266479	0.15
544.6358032	1.26
545.2382202	11.60
546.1315308	1.21
555.5972900	0.56
556.2675781	0.19
563.2062988	100.00
564.2619019	7.17
579.2778931	0.11
581.1014404	78.18
582.1560669	5.69
582.8911133	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1029.4435
Annotation	Gomisin E
Peak:m/z	Relative Intensity
407.3955688	0.05
544.6885986	0.04
576.4764404	0.04
721.5615234	0.04
739.2983398	0.01
847.5828857	0.06
868.4488525	0.20
1030.3977050	100.00
1031.1799320	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.1747
Annotation	Diosmetin 7-Apiosyl-(1->2)-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
190.5683136	0.01
198.9526062	0.01
213.0042267	0.03
216.8886108	0.04
245.0518646	0.02
270.2248230	0.04
271.0955200	0.07
285.0273438	0.03
287.2227783	0.02
288.3856506	0.02
289.0872498	0.03
298.1297607	0.44
300.1411743	0.03
301.1708374	0.95
313.2147827	0.07
316.0926819	7.40
316.7592773	0.01
322.2909546	0.06
329.3068237	0.01
331.1420898	100.00
361.0761108	0.04
373.1099243	0.19
375.3934326	0.01
397.0557251	0.03
408.9993286	0.01
431.3947144	0.01
439.0819702	0.01
457.1237183	0.03
469.2724609	0.05
475.3869629	0.06
493.1591797	0.03
575.1929321	0.49
590.2377319	0.01
601.2941284	0.17
619.2539673	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1364
Annotation	Bisindigotin
Peak:m/z	Relative Intensity
140.0702515	0.17
145.0803833	0.79
155.9756165	0.59
158.8050842	0.46
161.2344360	0.10
169.9672394	0.24
173.0516510	0.05
174.3143005	0.43
174.9714661	6.62
182.9996796	0.35
196.0278931	0.11
200.9978485	0.07
205.9958496	0.13
207.0445862	0.18
211.7882690	0.41
213.1001434	1.84
217.1922150	0.14
221.8558350	0.12
224.9305573	1.41
226.9960022	0.90
229.1554871	2.51
229.9305725	0.20
230.9008484	0.13
244.7034149	0.49
246.7688904	0.64
259.0862427	10.45
261.2628479	0.26
273.0348511	3.66
274.1346130	2.16
275.0740356	100.00
288.9433289	3.36
311.2760010	0.11
324.1148682	0.09
325.2642822	0.31
329.3948669	0.24
330.1354675	0.09
335.0017395	0.04
341.1947632	0.20
342.2067871	0.62
343.2617188	1.69
351.1832275	0.22
352.2399292	0.06
353.3108826	0.68
356.0638428	0.12
359.3088379	2.40
373.2186584	0.12
374.2438965	0.26
375.3188171	15.09
383.1610413	0.30
383.8672180	0.35
384.8630066	0.24
386.2767639	0.09
388.4490051	0.20
393.9968872	0.06
397.4412537	0.13
399.3012695	0.15
401.5071106	0.31
403.2049866	0.15
405.2706604	0.12
425.2503967	0.81
427.0471497	0.08
442.6694641	1.96
443.2834473	2.71
444.5171509	0.24
445.2482605	0.21
446.5505066	0.15
453.6917725	0.07
461.3601379	1.07
470.3694763	0.11
471.3491821	0.71
472.1262512	0.10
490.4835815	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	560.32
Annotation	Unknow
Peak:m/z	Relative Intensity
215.1122131	0.25
310.6282349	0.10
314.9460449	0.53
328.8908081	0.48
329.9928589	1.02
330.9251099	1.33
333.0313721	0.17
348.8674316	0.13
400.6768799	0.37
415.8459473	0.19
426.7102661	0.53
429.8385620	3.92
430.9801025	2.27
443.8738403	64.58
444.9497070	100.00
445.9918823	87.17
446.9182129	52.39
447.5223389	0.27
448.7100830	0.32
457.5747681	0.09
459.0010986	1.21
460.1761475	3.43
461.1533813	2.71
462.0068359	1.36
462.7305298	1.27
463.4904175	0.18
464.3231201	0.28
475.9648438	0.16
478.8045654	0.22
485.0396118	0.34
489.3162231	0.08
491.3657837	0.26
513.9375610	0.20
514.9452515	1.89
531.8961792	0.78
532.9149170	0.55
536.6652222	0.20
543.0459595	0.39
544.0576172	0.76
550.2002563	0.33
560.6807251	0.43
572.7584839	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	915.4397
Annotation	Unknow
Peak:m/z	Relative Intensity
398.0025024	0.01
516.5214233	0.01
569.4957275	0.02
618.4407959	0.02
692.4756470	0.04
752.6310425	0.01
770.7920532	0.01
776.7313232	0.01
855.5972290	0.09
870.3131714	0.04
882.3853149	0.04
915.5178833	100.00
916.1928101	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1776
Annotation	Cyclocalopin D
Peak:m/z	Relative Intensity
150.9508667	1.68
160.8926849	5.41
176.0733795	3.04
178.9440460	9.95
179.8618164	0.09
190.5046692	0.28
191.1115723	2.22
194.0591736	16.08
203.0742340	0.06
209.0450745	100.00
225.1650848	0.17
304.9700317	1.85
334.0183716	0.07
370.7329102	0.58
371.4195557	0.43
452.1791382	0.21
469.2913208	0.12
471.0851440	0.27
499.5410767	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.28
Annotation	Taxiflorine
Peak:m/z	Relative Intensity
187.2998199	0.12
208.2480774	0.07
217.0142975	0.12
219.9876404	0.10
237.3229370	0.04
242.1232605	0.04
246.9428253	0.02
270.2731323	0.05
275.2453003	0.06
283.2509155	0.11
294.1301270	0.08
299.2441406	0.08
305.0598755	0.11
311.3070679	0.22
321.2424316	0.09
324.0542603	0.03
331.2542114	0.54
332.4636841	0.15
333.4293213	0.19
334.3375244	0.22
341.3848267	0.03
346.3372803	0.10
350.3703003	0.06
365.5233765	0.08
367.3260498	0.17
369.0240479	0.22
371.4077148	0.23
372.9624023	0.21
377.5234985	0.08
381.3174438	0.12
387.0206299	0.07
389.3185425	0.39
390.1490479	0.15
397.5366211	0.33
399.2677002	0.08
406.9043579	0.20
409.5486450	0.05
410.4613037	0.04
435.3059082	0.24
440.3295898	0.03
445.6159668	0.08
453.5072021	0.07
455.4735718	0.07
458.5759277	0.03
463.0845337	0.05
468.2376099	0.07
472.6204834	0.44
473.6101685	0.17
477.5681763	0.07
483.4015503	0.09
488.2167358	0.07
493.2873535	0.09
498.3042603	0.06
499.5751343	0.14
501.6282959	0.14
504.5408325	0.07
506.4088135	0.10
512.2985229	0.09
516.3713989	0.11
521.4326782	0.14
523.4013062	0.13
524.0016479	0.13
525.5780640	0.28
529.0588989	0.06
532.2821045	0.23
534.8822632	0.03
535.4956055	0.30
536.3190918	0.76
537.0703735	0.34
538.1085815	0.10
538.9799805	0.26
539.5811157	0.12
543.4881592	0.13
548.5910034	0.07
549.5758667	0.26
552.2211304	0.57
553.4379272	0.80
554.3126831	0.05
561.4071655	0.13
562.3897095	0.25
563.4170532	2.44
564.4495239	1.35
565.4622192	3.23
566.4318848	1.09
567.3572388	4.48
568.4158325	2.26
569.3065796	0.99
570.3046265	0.65
573.4307251	0.08
575.3178101	0.67
576.1764526	0.36
577.3970337	0.07
579.3197021	3.93
580.4446411	1.70
581.3981934	0.10
582.2759399	0.11
583.4293823	0.26
584.0523071	0.11
589.3493042	0.71
590.2625122	0.94
593.3862305	0.45
595.7441406	3.86
596.4804688	26.43
597.3978882	100.00
598.4785767	32.36
604.5007935	0.28
607.3288574	60.16
608.3590088	23.94
609.4865723	0.34
611.3894653	15.33
612.4196777	5.27
621.3604736	8.45
622.4043579	3.84
623.2915649	0.34
624.4229126	1.07
625.3955078	0.37
639.9562378	0.04
640.8626099	0.63
641.5627441	1.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1771
Annotation	Butrin
Peak:m/z	Relative Intensity
179.9556885	0.06
180.9305573	0.27
192.0262909	0.07
193.1350555	0.06
207.2870483	0.09
242.6917725	0.04
245.0308228	0.05
288.0535583	0.05
299.1137695	0.55
300.0140991	0.91
300.8588867	0.22
302.0288696	0.03
305.2219849	1.52
306.1450195	0.76
307.1265869	0.03
312.2671204	0.11
314.1191406	2.23
315.3652954	3.71
316.1100464	8.11
317.4575195	0.27
329.1382141	9.53
330.1731873	11.81
331.1677856	100.00
343.1156006	0.07
344.2141724	0.14
352.2715454	0.02
355.1668091	0.65
359.2293091	0.62
371.3410645	0.06
372.6244507	0.60
373.2506714	0.99
374.2306519	0.06
401.0908203	0.05
415.0946655	0.03
425.2257080	0.04
461.1220093	0.19
471.1386719	0.02
474.3468628	0.08
475.2849731	0.70
477.2897949	0.10
478.3031616	0.15
491.2634888	6.61
492.2422485	20.70
493.3079834	45.19
501.5100708	0.07
503.2058716	0.07
517.4321899	0.03
520.0873413	0.17
521.4119873	0.27
533.2864380	2.82
534.2319336	12.20
535.2586060	27.61
553.2146606	0.12
563.5289307	0.04
574.1982422	7.19
575.2615967	9.87
577.1567383	0.44
586.9497681	0.25
592.5729980	0.04
593.4114380	0.10
600.7262573	0.09
619.4336548	0.13
621.0161743	0.07
637.1962891	4.57
637.8407593	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.8336
Annotation	Unknow
Peak:m/z	Relative Intensity
186.3977661	0.31
190.8936462	0.09
198.9746704	0.11
238.7580872	0.27
255.9361725	0.23
257.1988831	5.84
258.8151550	0.30
261.1146851	0.28
279.5140991	0.42
284.4420471	0.64
301.1071167	0.10
303.2678833	0.83
312.8993225	1.51
313.6210632	0.25
320.8198853	0.57
321.7260132	5.88
324.9422607	0.10
344.9460449	0.84
348.1666870	0.80
360.0332642	0.39
361.2191772	1.21
362.2209473	1.10
363.2176514	1.98
364.2888794	0.68
367.4869385	0.24
369.3685913	0.32
375.4704590	0.30
376.3690796	1.00
385.4174194	1.13
397.3071899	0.95
412.1895752	0.85
413.1575928	0.25
414.9128418	0.57
421.3378296	0.27
431.1664429	0.37
431.9789429	0.27
439.3922119	0.19
440.0534058	0.26
440.8929443	0.99
447.4927979	0.63
449.7875366	100.00
450.8503418	2.79
452.0220337	0.82
452.8027344	0.27
455.1717529	0.32
456.0205688	0.67
457.4500122	0.92
458.0891113	0.68
459.4606934	0.20
460.2171021	0.17
465.1362305	0.56
489.4143677	0.27
514.0949707	0.19
515.2355347	0.19
530.7883911	32.63
531.5670166	3.67
532.5131226	0.70
533.9924927	0.19
536.6024780	0.40
579.2170410	0.22
586.4309082	1.98
593.2516479	1.29
594.3687134	0.75
623.8890991	0.19
642.4318237	0.29
660.4415894	1.33
769.5059204	7.95
770.9255981	0.10
879.6039429	0.31
896.6315918	0.12
898.5463257	46.63
899.7947388	0.32
931.5622559	0.64
997.5676880	0.36
1060.0667720	0.90
1060.9798580	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1141.3004
Annotation	Isonigerone
Peak:m/z	Relative Intensity
316.2123108	0.03
328.0497437	0.01
331.1714783	0.31
332.2446289	0.07
343.2677307	0.01
344.1837769	0.02
346.2567749	0.03
347.3933411	0.02
353.2525330	0.00
357.4185791	0.00
361.2412415	0.42
362.2201233	0.25
373.3502808	0.00
374.0983276	0.02
393.2928467	0.00
400.8478394	0.01
409.0510254	0.01
416.1499023	0.00
421.4030457	0.01
422.0639038	0.01
439.2461548	0.06
440.5075073	0.03
449.5357666	0.01
451.1515503	0.02
452.2401428	0.02
458.5112305	0.01
469.1547852	0.04
470.2867432	0.01
475.0979004	0.01
492.0931396	0.01
524.2991333	0.00
530.3063965	0.02
542.3624268	0.01
547.5151367	0.01
558.1737061	0.01
560.4343262	0.00
565.2369385	0.02
575.2252808	0.01
575.8822021	0.02
577.2304077	0.01
587.2633667	0.01
595.2185059	0.01
602.1268311	0.01
605.6992188	0.04
606.4959717	0.02
613.6909180	0.02
614.4570312	0.01
619.1282349	0.03
620.4147949	0.02
631.9729004	0.01
649.0231323	0.01
650.4630127	0.05
663.2053223	0.01
665.5584106	0.01
668.5648193	0.01
679.2535400	0.02
692.4589233	0.01
709.5626221	0.03
710.2526855	0.03
727.3571777	0.02
728.3749390	0.03
745.3689575	0.07
746.2689209	0.10
757.2044678	0.01
758.1710205	0.01
763.2908325	0.03
764.4331055	0.05
775.2443237	0.03
776.3511353	0.10
781.2956543	0.05
782.1845703	0.04
793.3372803	0.01
794.4284668	0.10
811.3356323	0.04
812.1964111	0.04
812.8297119	0.00
961.3968506	0.01
1142.2376710	100.00
1142.9785160	0.66
1143.9149170	0.01
1144.6956790	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.156
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0617676	0.04
129.2534637	0.07
135.1663971	0.11
137.0733948	0.11
138.1091156	0.03
143.0049896	1.02
155.1415405	1.64
159.3309326	0.09
161.0798492	2.22
163.9073944	1.00
167.0183716	1.34
169.2213745	0.05
170.9981384	0.06
178.0084076	0.11
179.0671387	1.88
181.2434998	0.59
187.0151672	0.26
187.9863892	0.13
190.9779663	0.12
197.0422363	0.27
199.0641785	100.00
203.1293945	0.07
207.0879211	8.03
215.0455475	0.05
217.3304596	0.37
223.0195312	0.18
225.0566101	0.80
226.0036316	0.04
226.9296570	0.06
230.1865540	0.12
231.2334290	0.05
232.2025146	0.61
233.0176086	0.35
234.2433777	0.34
235.3449097	0.05
241.1610107	10.85
244.8289490	0.13
249.1212158	0.07
253.2426453	0.39
256.2457886	0.07
260.0927124	0.56
265.3395691	0.06
271.1071777	8.05
275.3480225	0.07
276.2556763	0.04
288.5103760	0.56
295.1424255	0.43
299.2402954	0.04
301.0931396	10.68
304.0889893	0.08
305.3806763	0.20
310.8769531	0.05
313.4030151	0.14
317.2809448	0.94
319.2372437	0.72
321.0660095	1.89
331.2622986	0.59
333.4177856	0.27
335.1865234	0.03
343.0111389	0.57
344.5343018	0.53
347.3067017	3.06
357.3457947	0.24
358.0631714	0.25
359.3411865	0.17
360.6138306	8.84
361.2139587	51.21
362.8946533	0.07
364.2291565	0.08
365.3372803	0.51
370.0909729	0.06
371.5033264	0.12
375.2091980	1.34
377.0985718	0.04
389.3920593	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0197
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
59.0999413	0.05
66.9412613	0.05
71.0637054	0.02
84.9812698	1.37
86.9105072	1.08
92.9293518	0.81
98.7816467	0.12
108.9401093	0.33
110.8457794	100.00
114.9112396	0.03
126.9022369	1.19
127.5229340	0.02
128.8905029	2.49
130.7894897	1.45
137.0777130	0.05
146.8729706	0.04
154.9409637	0.13
170.6422272	0.04
171.6122284	0.16
172.9039154	19.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	454.1204
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0210114	0.21
129.0995789	0.09
135.1429749	0.07
137.9126282	0.04
139.7642822	0.15
140.9523926	0.38
141.9607544	2.30
147.0516663	0.06
156.0643921	0.24
157.9375610	6.31
158.9625092	0.30
170.1143188	0.03
171.9709320	0.81
175.1796875	0.02
181.9358826	0.05
183.0013885	0.03
184.1644897	0.05
188.1801453	0.27
191.0763855	0.84
200.1132660	0.85
201.9989929	9.55
207.1307983	0.07
218.0480499	2.17
219.0820618	0.71
230.2438354	0.05
242.8037872	0.02
243.9851074	0.31
262.0903931	100.00
274.2532654	0.06
280.0712280	0.07
292.0453491	0.02
304.0349731	0.05
304.9214172	0.06
305.8281250	0.03
325.3182373	0.06
330.2170105	0.03
335.1354370	0.36
336.0133057	0.10
341.1376343	0.15
350.3245239	0.03
360.1820984	0.05
381.2129517	0.27
391.9274902	0.26
393.2091675	0.07
395.2467346	0.03
409.0704651	0.03
410.2945251	0.01
410.9060059	0.08
418.1515503	0.10
436.2851562	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1876
Annotation	Scorzonoside
Peak:m/z	Relative Intensity
166.8372345	0.08
174.8932953	0.03
176.2159271	0.02
187.8748169	0.04
193.1260376	0.01
200.0074463	0.04
241.2992554	0.04
243.3579865	0.08
253.1702271	0.01
259.2756348	0.01
269.4241943	0.04
271.1249390	0.02
279.1685181	0.04
281.4047241	0.03
284.0695801	0.11
287.3796997	0.02
289.3542786	0.02
293.2762451	0.05
298.9192505	0.03
301.1054077	0.03
305.0912170	0.06
306.3484497	0.04
309.3077393	0.03
311.2949829	0.09
313.3536987	0.07
315.3483887	0.08
321.2409058	0.07
323.6801758	0.01
325.3739624	0.22
327.4429932	0.02
331.3633423	0.03
337.0565796	0.12
339.3120117	0.27
344.9251709	0.04
346.0648804	0.05
347.0595093	0.04
349.2672119	0.07
351.3138428	0.11
352.1782227	0.04
355.1610107	0.12
357.1191406	1.17
359.5858154	0.03
363.4443359	0.16
365.3865967	0.07
366.2742920	0.02
367.3244019	0.25
368.5080566	0.04
369.1679688	0.38
371.2327881	0.08
375.4616699	0.14
377.3247070	0.14
379.5120239	0.05
381.2717896	0.13
383.2128296	0.19
385.5321045	0.05
392.1406250	0.02
393.3076782	1.48
394.6399536	0.02
395.2989502	2.26
397.2667236	0.08
407.3082886	0.07
409.1450806	0.06
410.6510010	0.28
411.2791748	2.71
413.3019409	0.32
421.3334351	0.04
423.2095947	0.06
424.7562866	0.07
427.1996460	1.58
428.4765625	0.01
429.3919067	0.04
437.1960449	0.13
439.1212769	0.03
441.3005981	0.24
443.4055786	0.32
445.2472534	0.06
449.3430176	0.51
455.1925049	7.21
456.5025635	0.10
463.2833862	0.05
467.3494873	1.66
471.2946167	1.32
483.6511841	0.02
485.2837524	100.00
487.3589478	1.10
489.2169800	0.62
491.9950562	0.04
493.3154907	0.08
494.1580811	0.12
495.1654663	0.04
496.2780151	0.05
499.1254883	0.02
503.5007935	0.02
511.3150024	0.02
513.5444946	0.03
516.6068726	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1649
Annotation	PA(6:0/6:0)
Peak:m/z	Relative Intensity
106.8578110	0.09
108.9190979	0.11
113.2590103	0.06
116.9045410	0.23
118.9413910	0.20
124.9259338	0.24
126.7909393	0.07
135.9504395	0.73
138.9773712	0.06
144.9577332	2.43
147.0285645	0.41
149.3479462	0.10
156.9279785	0.30
158.2417908	0.09
158.8626556	0.11
161.1824646	0.13
164.0225830	12.57
164.9737854	0.26
170.1573792	0.18
175.1845398	0.04
176.9735260	15.96
177.9832611	0.04
180.5492249	0.04
181.9549561	100.00
183.9446564	0.08
187.1451721	0.34
187.9837189	0.11
188.7234497	0.03
191.2691956	0.08
192.0216370	0.05
192.9541626	0.04
194.1539764	0.05
195.1742096	0.35
196.3312073	0.06
197.9644012	0.14
199.9532623	0.04
204.0084839	0.17
206.3243103	0.60
207.1563263	1.40
212.0482330	0.08
213.3304138	0.21
225.2405396	0.40
226.1350708	0.07
227.0733643	0.15
231.0887451	0.04
249.1789246	0.04
252.6904907	0.04
255.0747375	0.14
266.3755798	0.03
267.1823120	0.10
270.9618530	0.27
277.0768433	0.39
279.8240662	0.11
283.2945557	0.22
285.5231323	0.07
287.1376343	0.10
291.3340454	0.05
294.0816650	0.02
297.2588501	0.10
305.3074341	0.18
311.3227539	6.75
313.2086182	0.12
314.9660339	0.30
317.9357910	0.05
319.1147461	6.02
320.5310059	0.21
322.9752808	0.17
324.5314941	0.53
325.2825928	0.36
327.2633972	0.52
328.2667847	0.09
332.3671265	0.62
333.3237000	0.39
336.1748047	3.78
336.9530029	39.05
341.1537781	0.26
345.9811096	0.06
350.4876404	2.81
351.1249084	8.24
352.4354553	0.04
354.3481140	0.17
357.6858521	0.16
360.8920593	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.22
Annotation	Luteolin 7-(6''-malonylneohesperidoside)
Peak:m/z	Relative Intensity
225.1343079	0.37
228.9109192	0.22
243.0513611	0.23
253.1452332	0.05
271.1115417	95.93
282.9598389	0.05
313.1849365	0.34
314.9118652	0.06
324.7178345	0.05
329.3287354	0.04
337.2974243	0.38
363.2508545	0.15
397.1055298	0.13
399.2937012	0.11
415.4605713	0.19
416.4782715	0.05
417.3375854	0.05
426.7745972	0.05
427.3914185	0.04
433.1340332	100.00
433.7675171	0.15
439.1831665	0.10
457.2501221	0.23
474.0906372	0.04
475.0991211	0.20
475.7366333	0.09
481.1769409	0.09
487.3895264	0.08
529.2091064	0.36
541.5784912	0.03
543.1928101	0.37
549.4921265	0.28
559.3172607	0.28
561.1166382	0.26
571.3425293	0.12
576.5319214	0.13
577.1860352	0.87
579.1537476	1.76
589.3058472	0.05
595.1365356	28.66
595.7695923	0.24
611.1539307	0.19
617.9923706	0.03
619.3156738	0.08
620.5682983	0.27
621.3598022	0.04
637.4896851	0.11
649.1716919	0.05
657.1130981	0.04
678.3872681	0.09
679.6652222	0.09
687.4703979	0.06
704.4923706	0.18
705.3207397	0.10
717.1018066	0.35
722.4628296	0.21
723.3994751	0.59
741.1210327	33.53
741.7596436	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.3105
Annotation	Unknow
Peak:m/z	Relative Intensity
164.9451447	0.07
167.2993164	0.07
175.1080933	0.11
176.7727509	0.08
179.0142517	0.27
187.3653870	0.04
197.0034180	0.24
201.3538208	0.20
208.1258392	0.15
216.2247620	0.07
221.1943665	0.22
225.1121521	0.26
227.0915527	0.06
239.2424164	0.10
244.0111084	0.13
245.4153595	0.05
250.3110199	0.16
252.9652100	0.18
254.1252289	0.20
255.2634125	0.04
257.1699219	0.07
265.4380188	0.09
275.1084595	0.21
277.6308289	0.06
281.2497253	0.24
284.1372070	0.11
285.2661133	0.15
290.2960205	0.12
306.1994019	0.07
310.3784790	0.06
312.2667847	0.09
313.3016968	0.07
316.9125977	0.24
321.2425537	0.05
322.6282959	0.07
329.2398682	0.49
331.7246094	0.34
333.1759644	0.06
336.3709106	0.13
338.1619263	0.20
340.0200195	0.15
341.2871094	0.16
342.3487549	0.09
350.1837158	0.16
356.4492798	0.07
359.2869873	0.06
361.2687988	0.28
363.2642212	0.07
364.3889160	0.05
366.0800781	0.05
381.3883057	0.07
384.3723145	0.16
387.4473267	0.11
391.2901001	0.26
392.2600098	0.19
393.2595825	0.07
394.9385986	0.38
398.0762329	0.11
398.7153320	0.65
399.3153687	2.15
400.4995728	0.33
401.4462280	0.34
402.4938354	0.12
403.2970581	0.05
405.1255493	0.16
406.2402954	0.17
407.1957397	0.09
408.3099365	0.11
409.4743652	0.60
411.4572754	0.51
415.4257202	0.16
417.5191650	0.12
419.4297485	0.11
420.3628540	0.06
425.1881104	0.17
426.3234863	0.31
427.3882446	0.56
428.2656860	0.17
429.7631226	0.17
431.3253174	0.22
435.3719482	0.07
439.5606689	0.13
441.2924194	0.13
444.4837646	0.15
446.4470215	0.04
453.1066284	0.07
455.3884888	0.10
457.2406616	0.94
461.3521729	0.26
464.1368408	0.31
467.7340698	0.36
470.2315063	0.34
471.2910767	0.07
472.1253662	0.34
475.7437744	0.12
479.4388428	0.39
480.3812256	0.72
485.3526001	1.36
487.2135620	0.55
488.3742065	0.05
489.1978149	0.05
490.2965698	0.18
495.0214233	0.10
496.1996460	1.19
497.4174805	12.54
498.4250488	1.46
499.0787354	0.22
503.3474121	0.48
504.1026611	0.43
508.2779541	0.04
511.1416016	0.10
513.4343872	0.58
514.3609009	0.17
515.4379272	6.77
516.4079590	0.14
517.3312378	0.07
522.4335327	0.22
523.3395386	0.22
524.4238892	0.08
527.5466919	0.23
530.0783081	0.03
531.2875366	0.17
532.3342896	0.04
533.4420776	1.59
541.4680176	3.07
542.3665161	1.61
547.1444092	0.50
559.3827515	100.00
560.4711914	0.64
562.7802124	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	283.1648
Annotation	Unknow
Peak:m/z	Relative Intensity
80.8257828	0.08
86.7008362	0.06
88.7698669	0.03
92.9180908	0.09
94.7581024	0.09
96.8691330	0.02
107.0418549	0.03
109.0373993	0.05
111.0747223	0.11
120.9763718	0.07
122.0846329	0.10
122.9354401	0.09
125.0545502	0.02
133.0173950	0.14
135.0910339	0.14
135.9987488	0.08
136.8855896	0.03
139.0695801	0.12
142.8391876	0.08
149.0486755	0.10
150.6843567	0.03
154.9528046	0.01
157.0409546	0.02
163.0368958	0.08
163.7045288	0.07
164.5966492	0.05
165.9705200	0.23
168.1969757	0.34
171.0192108	0.02
177.3041687	0.05
179.1557312	0.35
180.9782715	2.06
181.8506927	0.08
182.9902649	0.32
183.9897766	0.05
185.0707397	0.02
191.0105591	0.04
195.1049805	0.02
197.0604248	0.03
197.9702454	0.01
198.7881470	0.03
203.3809814	0.03
205.0682678	0.01
207.0986633	0.24
208.0996704	1.01
212.1315002	0.03
213.1967773	0.07
214.9205017	0.03
219.1968079	0.03
221.1479187	2.00
222.2279663	0.13
223.0996704	0.14
225.0493164	100.00
225.6924744	0.23
227.2287903	0.02
234.9597778	0.01
237.0531616	0.40
237.9820251	0.02
239.1734619	1.24
240.4131775	0.06
241.1066284	0.08
246.2907104	0.01
247.2416077	0.40
252.1959534	0.06
253.0572510	0.03
255.1500854	0.26
255.8984070	0.03
262.7619934	0.06
265.1366272	4.10
266.2196655	1.26
267.2106628	0.03
273.2957458	0.02
274.1448975	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	456.1699
Annotation	Gymnastatin A
Peak:m/z	Relative Intensity
128.8668213	2.00
140.8695831	19.92
158.8584900	0.68
176.9526978	100.00
261.9784851	0.09
307.9140625	0.51
310.3589783	0.20
319.1129150	0.20
322.1440125	0.07
322.9078674	0.37
336.8138428	0.05
337.7879333	0.87
338.7355957	9.25
339.4933472	0.05
340.9793091	0.09
350.7868042	0.09
360.2537842	0.54
369.1045837	0.05
381.0212708	0.04
384.0390930	0.12
419.7981873	0.05
424.9489441	0.24
438.1834412	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.367
Annotation	Unknow
Peak:m/z	Relative Intensity
101.8779755	1.35
102.9465408	0.29
105.8693848	4.02
106.5426407	0.02
150.9931183	0.08
194.3897400	0.03
200.1547852	0.04
219.2495728	0.05
230.8679504	0.03
233.0644226	0.04
247.2063293	0.12
279.8152466	0.08
296.4526672	0.91
297.3124695	0.12
312.6676636	0.04
314.4909363	5.47
315.5185547	0.22
322.5518188	0.29
326.9665222	0.07
340.4152222	100.00
341.4604187	11.17
343.1584167	0.05
344.2574768	0.18
358.4061584	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
187.0016174	0.04
196.8811035	0.06
198.1509705	0.12
217.2686005	0.08
223.1482849	0.05
232.9868622	0.04
238.2794189	0.03
241.2967377	0.05
243.4487457	0.04
256.0888062	0.38
267.8348694	0.06
271.1246643	0.15
281.1676636	0.06
284.0382080	34.39
285.1369934	3.10
294.6381836	0.02
296.0383911	0.03
297.8974609	1.28
299.1178589	100.00
300.2205200	0.08
301.0333252	0.16
306.8356934	0.18
309.2528076	0.17
310.0929565	0.11
311.1370239	0.10
312.0631409	0.03
313.1411133	0.28
320.8026733	0.08
323.1213989	1.07
324.1676025	0.05
324.9715576	0.02
326.2131348	0.05
327.3104858	0.10
339.2960205	0.35
340.2628784	0.34
341.2832031	1.24
342.1196289	0.14
353.3361816	0.02
365.3463745	0.39
369.1657104	0.17
371.3258057	0.06
383.3305054	0.08
398.0380249	0.10
401.3314209	0.45
425.2771606	0.04
427.3078613	0.04
429.4687500	0.21
443.2182007	3.40
446.1327515	0.13
447.3551025	0.70
461.2114868	1.25
463.2267456	0.45
465.4827881	0.03
475.4646606	0.06
485.5403442	0.04
487.2325439	1.38
491.2844849	0.04
501.8422241	0.09
503.2545776	0.06
517.3756104	0.03
521.4688110	0.08
522.3829956	0.05
545.4968872	0.07
548.3906860	0.03
559.2662964	0.04
561.7695923	0.09
562.3803101	0.09
563.2053833	0.08
574.9965210	0.05
585.8204956	0.09
592.3096313	0.68
608.4481812	1.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	866.5101
Annotation	Unknow
Peak:m/z	Relative Intensity
241.8011475	0.08
244.9972992	0.07
250.2257690	0.03
254.1669312	0.02
259.0515442	0.08
262.1616821	0.07
264.2882080	0.06
265.2785645	0.11
268.1111450	0.59
269.2127075	0.04
271.4398804	0.04
273.3766479	0.03
282.2735901	0.77
285.2806396	0.32
287.2926636	0.22
292.3258972	0.06
296.1410217	0.74
297.1534729	0.11
299.2233887	0.12
300.2377930	0.10
303.5310364	0.01
307.2785034	0.07
308.1139832	0.08
310.1620789	0.36
311.2112122	0.16
312.0209351	0.03
313.2252197	0.42
314.0923462	0.16
318.3473206	0.07
319.0493469	0.04
320.2970581	0.03
322.6369324	0.08
325.1090088	0.26
326.3445129	0.21
328.3052979	0.03
330.0318604	0.07
333.5590515	0.01
336.3607483	0.34
337.2816772	0.07
339.1409912	0.38
340.4398193	0.16
341.2391357	0.15
342.3524475	0.36
344.3224487	0.21
345.5242004	0.03
346.6684875	0.01
347.4295044	0.11
352.3162842	0.03
353.2224121	0.24
356.1020508	0.02
358.2794800	0.25
359.4727478	0.02
361.2738342	0.73
362.2126465	0.01
365.1608887	0.03
367.2388000	0.32
368.3677979	0.11
369.5107117	0.03
370.3046265	0.14
371.1591187	0.05
372.3312988	0.05
373.3631897	0.07
379.4665527	0.07
380.3018799	0.04
381.2346497	0.15
382.3279419	0.18
384.8226929	0.04
386.1733398	0.28
387.4029236	0.21
388.6774902	0.49
389.3482971	1.00
390.3454590	0.16
392.3037109	0.03
395.7841797	0.22
396.4420166	0.35
398.2933960	0.02
400.8664551	0.13
401.4854736	0.05
407.3042603	0.48
408.3242188	0.03
409.1477051	0.13
410.3912964	1.71
411.3989868	0.08
412.2717896	0.11
413.2475586	0.31
415.1931763	1.70
416.2635498	0.20
417.4998169	0.04
420.1199341	0.05
422.2425537	0.08
424.4160767	0.21
426.0639648	0.11
427.2912598	0.18
429.3760376	1.10
430.5291138	0.11
432.3203125	0.75
433.3632812	0.32
434.3269043	0.02
436.9682617	0.05
438.3385010	2.55
439.3648071	0.40
440.4422607	0.07
441.2964478	0.19
443.1877441	1.71
444.3093872	0.48
447.4478760	0.03
450.3870239	0.62
451.6082764	0.07
452.4607544	0.67
453.3881226	0.15
454.0402832	0.03
455.4260864	0.47
457.2732544	0.52
458.3306885	0.65
460.2431641	2.66
461.3982544	0.19
462.6502075	0.10
464.3046875	1.31
465.5224609	0.22
468.1915894	0.05
469.4358521	0.09
470.1975708	0.35
471.4446411	0.23
472.4721680	0.19
473.1875610	0.18
474.7272339	0.02
478.3820190	1.97
479.4330444	0.29
481.3110962	0.77
482.5242310	0.14
483.4946899	0.19
484.1968994	0.01
486.3087158	0.73
488.0468750	0.21
491.3588867	0.34
492.6642456	0.14
493.2958984	0.11
495.4508667	0.18
496.4209595	0.06
497.3897705	0.98
498.4179077	0.52
500.1370239	0.56
501.2218628	0.01
502.4501343	0.06
503.6414795	0.14
504.6260376	0.04
505.5933838	0.07
507.5584717	0.06
509.3258667	3.52
510.3915405	0.34
511.5023193	0.01
512.4683838	0.33
514.3026733	1.50
515.2261963	0.16
516.1730957	0.02
519.2175903	0.06
520.3214722	0.05
521.4484253	0.30
522.6646118	0.20
523.4692993	0.71
524.5397339	0.22
526.1853638	0.39
528.2549438	1.14
529.3550415	0.23
533.3493652	0.04
535.4662476	0.12
537.2927856	0.04
538.2969360	0.09
539.3439941	0.04
540.4311523	0.80
541.5418091	0.20
542.3482056	0.59
543.3287964	0.50
545.5136719	0.13
549.4347534	1.56
550.4588623	0.28
551.9240112	0.24
554.3209229	1.49
555.2493896	0.34
557.3295898	3.87
558.3466797	0.48
559.3904419	0.12
560.6188965	0.02
567.4938354	1.72
568.5956421	0.62
569.7887573	0.04
571.3941650	1.94
572.7476807	0.19
573.4475098	0.05
575.7925415	0.06
577.3558960	2.62
578.1533813	0.25
580.7885132	0.44
581.5660400	0.74
582.3685303	0.13
583.3411865	0.53
585.3333740	15.35
586.3822632	1.77
587.3694458	0.17
588.4746704	0.21
589.4953003	0.07
590.5658569	0.05
591.4884644	0.05
593.5960693	0.02
594.8726196	0.06
595.6575928	0.04
597.3576050	0.33
598.1289673	0.04
599.3981934	7.32
600.3129272	0.58
604.7068481	0.28
605.4041138	0.03
606.4511108	0.62
607.4542847	0.32
609.2717896	0.03
611.3659058	1.80
612.4985352	0.19
613.4758911	0.08
617.4650269	0.04
618.3995972	0.03
620.8823242	0.16
625.3319092	1.70
626.5203247	0.06
627.8247070	0.29
628.4542847	1.87
629.4088745	0.57
635.3175659	0.05
638.4094238	2.54
639.4808960	0.19
642.4185181	2.36
643.4240723	0.34
648.5425415	0.26
651.4531250	0.43
652.5409546	2.47
653.3856201	0.85
654.5350342	0.10
656.4053345	14.54
657.5491333	2.06
663.2504272	0.03
664.8268433	0.02
666.6467896	0.10
668.6383057	0.09
670.3939819	9.02
671.5439453	1.03
678.5888062	0.11
680.7753296	0.24
682.5135498	0.43
683.6772461	0.04
691.5824585	0.98
692.5848999	0.15
693.7448120	0.23
694.4253540	0.03
696.5620728	1.06
697.5840454	0.28
701.4373169	0.36
702.2089233	0.19
703.5025024	0.20
706.4683838	0.05
708.4473267	0.37
709.6546631	0.09
710.5587769	0.04
719.5054321	7.77
720.6217651	1.18
724.3912964	5.44
725.5093384	2.01
726.7451782	0.13
734.5507202	0.10
735.5078125	0.15
737.5089722	0.18
738.4329834	0.24
739.4429321	0.09
741.3534546	0.30
749.3623657	0.04
750.4136353	0.19
751.4785767	0.54
753.4007568	4.38
754.5140991	0.78
764.4757690	1.01
765.5462036	0.15
767.5098267	1.52
768.7156372	0.33
769.6272583	0.93
770.2453003	0.05
777.3742065	0.26
778.6178589	0.10
779.4928589	0.31
780.4932251	0.14
793.6948242	0.46
794.8283691	0.28
795.4840088	6.29
796.6168823	1.12
797.5534058	0.18
804.5347290	0.05
809.6564331	0.16
820.4210205	0.13
821.5089722	2.13
822.5292969	0.78
830.5311890	0.09
838.5438232	18.79
839.6442261	3.26
848.5541382	11.39
849.5390625	2.35
867.5316162	100.00
868.2628784	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	622.25
Annotation	Unknow
Peak:m/z	Relative Intensity
177.7228394	0.03
201.1552734	0.02
240.2852325	0.08
250.1446533	0.01
255.0964050	0.02
275.1497498	0.01
288.3329468	0.01
296.1564941	0.06
298.1740112	10.81
298.7789917	0.13
300.1604614	0.02
309.3574829	0.03
316.2410583	0.66
327.1305847	0.03
337.1829224	0.02
338.2706299	0.03
355.0871582	0.04
358.3191528	0.05
373.4821167	0.07
380.1581421	0.01
382.1979980	0.04
384.1458740	0.01
389.2720337	0.01
405.1566162	0.02
406.1276245	0.03
409.5642700	0.07
415.7418823	0.04
416.4025879	0.03
421.8839722	0.01
424.3967285	0.01
427.3120117	0.03
428.6131592	0.01
441.8531494	0.02
453.2286377	0.03
454.6965942	0.02
460.2469482	100.00
460.8529053	0.57
480.1970825	0.03
490.4028931	0.02
502.3632202	0.05
505.1826782	0.02
518.3361206	0.03
523.7236328	0.01
524.6923828	0.02
562.4367065	0.05
564.6024780	0.02
568.4796753	0.13
571.4140015	0.20
572.3710938	0.02
603.9885254	0.37
604.7003174	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1141.3052
Annotation	Unknow
Peak:m/z	Relative Intensity
359.1966248	0.09
533.5507202	0.06
1078.9086910	0.09
1140.1335450	100.00
1141.2622070	54.46
1142.0100100	0.07
1142.7047120	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.3978
Annotation	Diospolysaponin A
Peak:m/z	Relative Intensity
459.4237061	0.31
506.4993286	0.05
517.7241821	0.17
561.3147583	0.01
578.8930054	0.14
591.5595093	0.02
597.3723145	0.02
603.7516479	0.01
619.4195557	0.03
621.4675293	1.35
637.7533569	0.08
639.4364624	0.02
661.5529785	0.09
679.5166626	4.28
697.2731323	0.47
697.8911743	0.07
739.4008179	3.57
785.3112183	100.00
786.0567017	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	246.9919
Annotation	Vanillic acid 4-sulfate
Peak:m/z	Relative Intensity
79.8550873	2.27
86.7185898	0.04
96.8486557	7.50
107.9655914	0.05
113.0131989	0.05
120.9995575	0.02
122.9884796	1.74
124.0538635	0.05
138.9625244	0.08
145.1082611	0.04
151.9516602	0.15
159.9994202	0.03
166.9722137	100.00
188.0132141	0.05
189.0722351	0.04
201.1060028	0.01
202.9567719	41.72
211.1893768	0.10
213.4792328	0.05
218.1902008	0.14
218.9730530	0.04
228.2604828	0.02
229.1526642	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.1722
Annotation	Butrin
Peak:m/z	Relative Intensity
191.1823578	0.07
197.1212158	1.38
203.1265869	0.09
207.0072327	0.08
209.1304779	17.33
212.9847412	0.42
221.1638336	0.95
222.9353027	0.13
237.3517761	0.48
239.0096741	22.22
247.1225586	0.18
251.0518188	1.78
263.3103943	0.70
269.0810242	14.27
274.9510498	0.20
277.4631958	0.16
279.0617065	0.19
281.1654663	3.98
293.2032471	2.22
299.4838562	0.28
307.2473755	0.24
311.1645508	6.30
323.2772217	0.36
329.1868286	5.47
341.1621094	4.92
359.2367554	4.50
365.3567505	0.14
371.4956665	0.28
373.3742065	0.39
379.3235474	0.57
383.1980591	0.47
387.1679077	0.37
389.0499878	0.72
395.4218140	0.45
399.3537598	0.24
401.1041870	100.00
413.2901001	8.82
424.4445801	0.17
425.1961670	0.66
428.5211792	0.09
431.1414795	82.31
431.7807617	0.35
443.1705933	3.15
449.2367554	6.41
453.4951172	0.15
457.0859375	0.20
461.2218018	29.23
466.7523193	0.11
467.4042969	1.20
473.0089722	0.24
479.4296875	0.32
485.1442261	2.38
491.2750854	1.11
497.0944214	0.33
503.2550659	26.71
515.1500244	3.66
517.3885498	1.08
521.2322388	77.52
533.2551880	17.35
545.0742798	0.37
551.3426514	11.11
563.0286865	0.55
581.2548218	0.16
587.1488037	0.18
605.1492310	5.58
623.2552490	15.61
641.2416382	26.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1128.5742
Annotation	Unknow
Peak:m/z	Relative Intensity
340.8210144	0.11
360.1289978	0.13
451.0923462	0.06
480.5713196	0.11
521.1207275	0.05
522.1393433	0.06
535.2333984	0.04
548.1781006	0.16
549.5370483	0.05
605.2946777	0.03
619.4495850	0.15
666.4194336	0.07
696.6625977	0.06
726.6955566	0.06
758.3210449	0.04
767.4545898	0.19
768.3582153	0.09
1128.1230470	100.00
1129.3156740	18.45
1130.0931400	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1129.2997
Annotation	Furaneol 4-(6-malonylglucoside)
Peak:m/z	Relative Intensity
315.9913635	0.03
319.4494934	0.05
328.2031250	0.38
331.1506653	1.41
331.9766541	0.05
332.9302979	0.09
346.1340332	0.36
355.3037720	0.04
361.1336060	10.71
362.0845642	0.15
385.5744019	0.08
387.2765198	0.18
408.9673462	0.05
415.1994629	0.06
423.4000854	0.03
426.9978638	0.02
427.7176208	0.16
439.5078735	0.08
444.4855652	0.02
451.0388489	0.38
457.4490662	0.04
469.1672058	0.22
480.1663208	0.14
487.4238892	0.10
511.1616211	0.07
563.0510254	0.07
589.3378296	0.05
605.1868896	0.14
631.5311279	0.16
635.4982910	0.06
649.2021484	0.29
667.1428833	0.34
695.2597656	0.12
697.3016357	0.06
715.3540649	0.07
757.1538086	0.22
768.8674927	0.12
775.2563477	2.80
793.2272949	0.27
809.4187012	0.09
811.2281494	1.79
1129.1257320	100.00
1130.3566890	4.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.1589
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
267.9655457	0.00
287.3830872	0.01
296.1291504	0.01
299.3214417	0.03
301.2677307	0.02
312.4780579	0.01
313.3547363	0.06
314.2702026	0.19
317.1139526	0.11
323.9071045	0.01
327.0710449	0.85
327.7658691	0.01
331.0822144	0.04
341.3808594	0.02
342.0234985	0.17
343.8371582	0.03
345.2141724	2.91
357.3009033	0.04
360.1523438	4.96
375.1588135	100.00
376.0335693	0.01
384.1294556	0.01
393.0904541	0.01
439.6100464	0.02
468.2869873	0.01
537.4266968	0.05
556.1441040	0.06
562.2180176	0.03
568.3280640	0.01
577.4303589	0.03
579.2075806	3.93
590.3099365	0.01
604.0245972	0.01
605.5646973	0.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	807.2446
Annotation	Unknow
Peak:m/z	Relative Intensity
247.0951080	0.05
250.2171783	0.04
259.2621765	0.04
261.1433716	0.03
278.2364197	0.02
290.0898132	0.01
293.3126221	0.20
297.2111206	0.01
302.4174194	0.04
313.3034058	0.02
324.2808838	0.06
325.3025818	0.09
356.1203613	0.02
373.3533020	0.07
382.1768188	0.04
389.4396973	0.02
394.3356934	0.07
397.1647949	0.18
399.2809448	0.98
406.4276123	0.02
416.3088379	0.09
428.2037964	0.07
442.7172241	0.04
468.4416504	0.01
474.2824707	0.02
475.6524048	0.07
486.1555176	0.02
488.5642090	0.02
494.1536865	0.02
511.4674683	0.12
512.3688354	0.03
513.3892822	0.67
525.0374146	0.02
528.6550293	0.01
539.2673340	0.07
540.4572144	0.02
541.4744263	0.04
545.2899780	0.21
547.3661499	0.01
548.3576050	0.01
557.3862305	1.65
563.3081055	0.03
567.4710083	0.05
578.3455811	0.03
580.2869263	0.02
589.2239380	0.07
590.7882690	0.07
591.3936768	2.76
599.4180298	0.04
600.4304810	0.06
602.9389038	0.04
611.5009766	0.12
621.3186646	0.02
623.3226929	0.41
628.3073730	0.73
634.0200806	0.18
637.3101196	0.03
643.7147217	0.05
651.4729004	0.13
653.5100098	0.02
655.4721069	0.05
660.5654907	0.01
663.3360596	0.02
682.4614868	0.02
685.5404663	0.33
686.1909790	0.01
689.5764771	0.06
694.0830078	0.04
697.4590454	4.71
706.2982788	0.05
709.6068115	0.08
720.2818604	0.04
721.3056641	0.04
722.1559448	0.10
722.7861328	0.09
724.6284180	0.04
725.3493652	0.06
729.5260010	0.81
741.3601685	0.18
745.4743652	0.05
746.3457031	0.06
763.3977051	2.75
773.4537354	0.05
788.5547485	0.04
789.3568115	0.02
790.4572144	0.10
807.3493042	100.00
808.1804810	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	470.76
Annotation	Unknow
Peak:m/z	Relative Intensity
218.9243927	1.17
262.3776550	0.01
284.9165039	0.04
286.9884033	0.06
298.8763428	0.03
299.9549561	0.01
300.9698792	0.07
302.8794250	34.25
309.0197754	0.02
311.1751404	0.02
315.0023499	0.02
344.1969604	0.09
380.2630310	0.03
380.8771362	0.13
383.7313232	0.10
384.7160645	0.16
386.7002869	100.00
387.3525085	0.31
423.8637695	0.08
427.1350098	0.04
433.8996887	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.2
Annotation	Unknow
Peak:m/z	Relative Intensity
194.0355835	0.01
195.3801117	0.02
203.1078644	0.02
210.8650665	0.02
214.1363220	0.02
225.0004272	0.02
230.2421265	0.04
240.2228394	0.03
245.7127991	0.02
255.6715851	0.01
268.0524902	0.05
279.2899780	0.04
281.1222229	0.01
284.9459229	0.04
285.8301086	0.01
296.1927185	0.06
298.9874573	0.03
299.9602661	0.01
302.1934814	0.02
307.1735535	0.06
313.2521362	0.11
314.2764587	0.19
317.2844238	0.06
318.4014893	0.03
324.3126831	0.16
327.0722961	3.59
329.3001099	0.04
330.0875549	0.13
331.2686768	0.31
332.3159180	0.02
341.9591064	0.51
342.9411621	0.01
343.5441895	0.01
345.0924683	11.75
346.0452271	0.02
357.3673096	0.02
360.1195068	8.04
362.1649780	0.05
375.1755371	100.00
376.0160522	0.01
408.8985596	0.02
417.3160400	0.05
441.2531128	0.01
487.8782959	0.01
503.3911743	0.03
508.3804932	0.02
522.3569946	0.02
524.5540771	0.01
531.3326416	0.02
537.5646362	0.04
543.2962036	0.01
549.3937378	0.02
550.3072510	0.01
556.5601196	0.13
564.5408325	0.04
569.2687378	0.04
575.2141724	0.01
614.8936157	0.01
619.3584595	0.23
627.3584595	0.03
637.5503540	0.01
643.5045776	0.01
645.4278564	0.17
648.5009766	0.03
663.3666382	0.07
665.3425903	0.01
666.6143799	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.1876
Annotation	Unknow
Peak:m/z	Relative Intensity
130.8003540	0.11
138.1250153	0.37
143.0016479	0.62
146.9127045	0.07
150.0084076	0.38
150.9846497	5.35
153.0426941	11.06
156.9690552	0.31
157.8027954	0.15
159.0733032	0.25
160.9945679	4.16
165.0582275	7.49
172.9245148	0.30
175.1709290	0.06
178.1586304	0.11
179.0180664	0.60
181.2805176	0.09
188.1782227	0.53
190.4175720	0.18
191.0926208	0.62
193.2204285	0.31
201.1326599	0.27
203.1853638	3.87
204.0732269	0.49
205.0864258	0.46
206.0112000	0.83
207.0780487	0.07
211.0253296	0.31
218.2257843	0.05
221.1642456	100.00
222.0963593	0.18
239.0375977	98.93
239.7068176	0.28
248.5405273	0.48
249.2245178	1.25
259.3187866	0.13
283.1029053	0.20
284.0671692	0.66
284.9850464	0.06
288.3759766	0.10
299.4435425	0.44
300.2874756	0.12
301.3618774	0.09
304.8778381	0.16
306.2167664	0.47
326.1318970	0.72
326.8728027	0.34
328.3014526	0.06
346.1067505	0.10
356.2086792	0.64
359.2758484	0.08
367.2185059	0.18
383.1772156	1.70
386.0430603	4.58
387.1427307	1.43
401.1310730	57.18
402.3726501	0.05
404.4747009	0.09
415.1440430	0.19
428.4431458	0.06
429.1531067	0.26
448.2784119	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0719
Annotation	3,7-Dihydroxy-3',4'-dimethoxyflavone
Peak:m/z	Relative Intensity
117.0461273	0.02
138.8803558	0.01
152.0096436	0.01
161.0480347	0.02
168.7497864	0.07
175.1038208	0.06
177.7290802	0.01
184.2989655	0.02
185.1405945	0.03
191.1846313	0.01
193.0426483	0.01
197.3015137	0.02
199.1328125	0.03
211.2012329	0.06
220.0429382	0.01
223.1116943	0.02
226.8175964	0.04
229.0397034	0.02
235.4669189	0.02
239.2618408	0.02
243.2137146	0.02
246.9864502	0.01
250.2808838	0.02
251.2872925	0.05
253.2751465	0.05
255.0792847	0.02
267.2124634	0.04
269.0813293	0.65
270.2058411	0.04
271.3452148	0.01
277.3646851	0.03
281.1188965	0.45
282.0428467	0.02
283.090332	3.17
285.0797729	0.22
292.9055176	0.01
294.1538391	0.04
295.2498169	0.30
298.0477295	100.00
298.883606	0.00
313.3232727	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Butrin
Peak:m/z	Relative Intensity
166.0267944	0.05
215.2592773	0.03
269.2597046	0.02
271.0917053	28.69
271.7541504	0.04
273.0655823	0.02
301.2284851	0.05
312.2925415	0.04
313.2368469	0.44
314.1651611	0.10
316.1606445	0.02
325.2739258	0.03
331.2023926	0.54
333.3435669	0.03
337.1412964	0.06
345.2178345	0.13
367.0646362	0.07
379.2695923	0.22
381.1764526	0.24
388.8767090	0.04
397.1271362	0.05
399.0977783	0.25
412.5147705	0.04
415.3806763	0.76
417.1306763	0.72
423.3545532	0.03
433.0657349	100.00
433.6876221	0.70
434.8193970	0.02
449.6201782	0.03
457.4769287	0.09
471.2273560	0.03
475.1272583	0.06
488.8504639	0.05
509.3468628	0.03
521.2625732	0.09
525.1503296	0.04
535.4627686	0.05
543.3135376	0.07
561.1746216	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	477.247
Annotation	Trillenogenin
Peak:m/z	Relative Intensity
144.8278351	0.08
160.9404907	0.15
167.0962524	0.34
175.0704346	0.42
177.0118866	0.23
185.1085815	0.18
189.2587585	0.33
193.1259766	0.83
196.8453064	0.39
198.5174866	0.10
207.0009003	0.26
209.3403015	0.14
212.4331055	0.05
215.2388763	0.07
216.9279175	0.17
219.1992188	0.07
223.1283875	0.20
228.9572449	0.22
231.1839600	0.06
234.3445435	0.29
243.2445526	0.31
247.0858917	0.05
251.0296021	0.11
252.2174683	0.37
253.5588989	0.06
257.1754761	0.35
258.8852844	0.13
261.3594360	0.06
265.3054504	0.21
269.2010803	0.54
271.1301575	0.14
275.0596619	0.08
278.3771362	0.08
283.2339172	0.04
285.3226318	0.17
289.1196594	0.54
293.2249756	0.17
295.3435669	0.10
297.3023682	0.27
303.1224976	0.17
305.1188965	0.08
307.5359497	0.06
311.1202698	1.45
312.3017883	0.06
313.2189636	0.66
315.2180786	0.49
316.7275391	0.26
321.5119629	0.25
323.2132874	0.17
327.2878418	0.05
329.2371521	0.51
331.2276001	0.31
335.2333374	0.36
338.0005798	0.15
339.2988281	5.08
341.1318970	0.19
343.3008423	0.04
344.0116577	0.13
345.4619141	0.08
349.2511597	0.30
350.1715393	0.03
351.2716980	0.37
354.2564087	0.14
355.2506104	0.30
357.1640625	31.71
357.7739563	0.22
363.3787231	1.43
365.0253601	1.33
367.2026367	1.84
369.2840576	0.21
373.0542603	0.38
381.0625610	1.41
383.2008362	1.08
385.1884155	1.29
388.8742676	0.13
391.2708740	1.05
395.2967834	0.43
399.0057678	0.07
401.2261047	0.06
403.2347717	0.39
405.2916565	0.84
406.3275452	0.16
407.1220093	0.07
409.1423340	1.74
411.2930298	0.08
413.1926270	0.28
423.1989136	6.97
427.4403992	0.27
441.3654785	11.66
446.3911743	0.45
449.4132385	0.32
452.3356323	0.42
459.2716675	100.00
462.4862671	0.28
467.3818054	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.2086
Annotation	8-Acetoxy-4'-methoxypinoresinol 4-glucoside
Peak:m/z	Relative Intensity
166.8617401	0.16
209.1759491	0.13
259.9953308	0.09
273.2652588	0.05
279.8075562	0.06
282.2595825	0.25
285.0916138	0.34
293.2717896	0.19
297.2623291	0.44
313.3663330	0.23
322.0673828	0.22
326.2185669	0.22
327.1759644	0.05
327.9375610	0.85
329.4235840	0.21
341.3861084	0.20
343.0698242	9.94
343.9921875	0.57
344.9066162	0.76
347.3115234	0.10
357.3352051	0.67
358.1920776	1.73
359.2550659	0.71
360.3645020	0.50
361.3580322	0.16
366.6584473	0.11
367.3424683	0.10
381.3046265	0.06
386.4082642	0.17
387.1801758	0.12
403.4569092	0.04
411.5709229	0.26
423.4795532	0.09
426.0772095	0.31
429.2648315	0.43
438.7198486	0.12
443.5195923	0.05
445.3308105	0.14
446.0954590	0.14
447.2419434	0.31
448.4202881	0.48
449.1589966	0.27
454.2981567	0.10
467.2392578	0.37
471.2128296	0.25
484.9248657	0.18
487.5541382	0.30
495.3886108	0.35
497.2312622	0.11
499.0803223	0.09
501.3677368	0.33
502.2213745	0.19
505.4436035	0.38
511.3760986	0.17
513.2824707	0.04
515.6386719	0.18
522.3748779	0.22
523.4414062	0.08
528.4689331	0.11
529.0978394	0.20
530.5214233	0.53
531.4988403	0.32
533.9394531	0.20
545.2555542	1.98
545.9497681	0.07
546.6157227	0.64
547.4754028	0.57
548.4658813	0.23
553.2018433	0.35
555.4978638	0.34
556.7864380	0.17
559.3750000	0.17
561.3516235	1.84
563.2879639	0.17
573.4092407	0.58
576.2510376	100.00
576.9816284	1.72
592.3836060	7.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	738.3609
Annotation	Cyclomontanin A
Peak:m/z	Relative Intensity
302.8993530	0.01
398.6809692	0.04
434.6453247	0.02
473.3558350	0.03
487.2341919	0.02
493.1844482	0.02
515.8991699	0.02
522.4138184	0.05
525.6135254	0.02
576.4431763	0.01
596.4796753	0.01
605.4340820	0.01
614.5409546	31.86
640.2861938	0.08
658.2897949	6.57
659.1244507	0.02
683.2969971	0.02
691.6626587	0.02
694.5558472	0.03
702.3327637	3.88
707.2886353	0.01
719.5555420	0.05
738.3051147	100.00
739.1897583	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	877.4817
Annotation	Unknow
Peak:m/z	Relative Intensity
441.3476562	0.03
492.3077393	0.06
550.6417236	0.07
568.3359985	0.07
580.5415039	0.06
590.6408081	0.33
628.6033325	0.12
799.6111450	0.08
818.7085571	0.03
832.7693481	0.14
838.6245728	0.04
858.5429077	0.22
877.5537720	100.00
878.3964844	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	879.5272
Annotation	Dolastatin 16
Peak:m/z	Relative Intensity
520.4468994	9.78
535.6517944	4.60
604.1155396	10.54
693.6032104	4.21
817.9776001	12.84
861.296814	20.96
879.5405884	100.00
880.3117065	8.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.2
Annotation	Unknow
Peak:m/z	Relative Intensity
83.9077148	0.18
89.0686188	0.03
94.8373108	0.10
100.1163864	0.03
111.9975891	2.98
113.0358658	0.15
113.8854294	0.08
114.8695068	0.12
119.1011505	0.07
126.7007294	0.05
129.0856476	2.59
130.0757599	0.08
132.8931580	0.07
142.8988190	0.26
145.0274353	0.02
146.1350098	4.69
147.0412292	5.61
155.0800781	6.06
156.1871338	0.28
157.1317139	1.06
160.9686432	0.05
161.9548340	0.03
168.9239502	0.07
172.1447754	0.68
173.1975250	0.08
176.0304108	0.26
181.1683350	0.09
202.0040588	0.05
203.0194092	0.63
204.0795898	21.67
206.2803040	0.05
207.3654785	0.04
216.5823669	0.03
218.1645813	42.53
219.2421875	0.07
221.1112671	2.09
228.2424927	0.12
229.5043030	0.05
234.0679321	0.19
235.1025696	9.09
235.7926331	0.21
240.8220825	0.10
242.2407532	0.05
247.0147705	0.24
249.1787720	0.05
250.2593994	0.09
257.2755737	0.06
260.1726685	0.08
261.1016235	0.04
261.9900513	0.04
263.1132812	0.09
264.0923767	0.05
274.1810913	11.41
275.1892700	100.00
276.1362915	0.31
276.8636169	0.13
282.7221680	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0859
Annotation	Alnustinol
Peak:m/z	Relative Intensity
88.8810577	0.25
90.8792877	0.07
92.9983368	0.02
94.9337082	0.05
106.9609528	0.05
108.7461548	0.02
110.0548477	0.05
110.9870682	0.44
114.7858124	0.03
116.9201813	0.31
118.8415833	0.13
121.0325470	0.06
123.0463638	0.19
125.0629578	0.33
133.8578796	0.04
136.4020996	0.11
137.0511780	0.59
140.0493774	0.02
140.8669281	0.06
142.2264862	0.04
144.9738464	3.02
147.2050781	0.04
148.9882507	0.32
151.0198059	4.10
152.9720917	23.35
158.9551849	0.10
161.9855042	0.08
162.9352722	0.10
170.8197021	0.05
173.1203613	0.01
175.0031433	0.73
176.9952087	100.00
178.9292297	43.15
186.9009552	0.02
190.2021027	0.03
193.0646057	0.25
194.8990936	0.04
201.0465393	1.26
207.1836853	0.03
215.0063782	0.14
217.1469421	0.10
219.0103760	2.61
229.4390259	0.09
236.9269714	0.25
243.0800781	0.40
245.9872742	0.03
246.9713135	0.03
253.1038818	0.02
257.1224976	0.07
259.2402344	0.05
261.1556396	2.09
265.9462891	0.15
267.0642700	0.53
273.6876221	0.03
274.4109497	0.03
275.2117615	0.04
285.0502319	11.39
286.1857910	0.81
288.1669312	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	777.2021
Annotation	Unknow
Peak:m/z	Relative Intensity
323.0031128	1.05
361.0217896	1.83
455.2071533	3.83
465.1154785	0.18
493.2711182	2.72
493.9956055	0.60
587.2204590	0.58
607.3621216	0.87
625.3353882	17.39
627.4224854	0.89
629.3737183	5.73
645.2434082	8.79
685.3703003	2.65
701.4235840	1.45
715.2541504	0.56
716.4052124	0.28
717.5112915	0.39
733.4591064	1.55
759.0034180	0.55
777.2869263	100.00
778.4174194	6.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0713
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
104.9949493	0.30
112.0470886	0.37
120.6504669	0.10
140.0785217	0.09
142.9225311	0.09
146.1077423	0.10
149.1116333	1.04
150.1390228	0.58
154.9581146	0.26
162.1212921	0.10
163.1458282	0.16
165.0934296	0.58
167.2193146	0.26
168.9255829	0.46
169.7937317	0.21
173.884964	0.09
179.0335236	0.94
180.2310028	0.41
181.0816345	0.87
182.1605072	0.13
185.1845856	0.10
192.8652802	0.76
194.0870209	0.70
195.0446625	0.42
206.216629	1.63
207.1301727	11.11
208.1243286	10.44
209.1071472	3.30
210.0079193	0.21
222.1042023	4.73
223.0257874	11.71
224.1030731	2.89
225.2232971	0.37
233.219101	0.14
234.1313934	0.20
236.2080078	0.34
249.3709564	0.27
251.0684204	100.00
252.075119	32.13
252.9946442	2.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.201
Annotation	Unknow
Peak:m/z	Relative Intensity
134.2220306	0.56
135.0946503	0.89
137.0966797	0.22
140.9204254	0.16
144.9010773	0.26
147.1316833	2.18
149.0602570	11.14
151.0306244	1.81
152.9100647	0.08
156.1119232	0.80
159.1446075	1.72
159.8069153	0.06
161.0185852	3.14
163.0250549	2.67
164.9863586	2.65
167.5850067	0.19
171.0456543	2.52
174.2007141	1.56
176.9365387	0.06
178.1745758	0.13
179.0544739	1.33
180.9256897	0.11
183.1766968	0.40
186.8576355	0.13
189.1118164	11.65
191.2447662	0.55
196.1514893	0.14
196.9776154	0.31
198.8339844	0.11
207.0345154	100.00
207.6920776	0.46
212.7839966	0.50
214.1889801	0.13
216.8986206	0.18
221.2195740	0.41
222.4313049	0.05
223.3686676	0.21
224.5267639	2.44
225.1354675	3.41
227.1590881	0.28
229.4800873	0.79
231.0446320	7.24
240.1833496	0.36
243.2166901	0.17
244.9106140	0.08
248.9950256	13.43
250.2369690	0.35
255.1729431	0.05
261.4234619	0.09
265.4282532	0.21
267.2664795	0.31
269.1175537	0.16
272.7950134	0.15
281.1677246	0.07
285.1986084	0.25
289.2023010	0.28
290.4282837	0.22
291.2019043	0.32
293.2179260	0.37
297.3763428	0.20
299.9357910	0.16
303.1381226	0.12
307.0164490	1.06
309.1605835	0.54
310.6176758	0.91
313.8029175	0.45
315.0086365	0.79
317.1321106	0.25
320.4062500	0.48
321.2180176	0.95
323.2693787	0.10
325.3619690	1.31
326.7927551	0.07
333.2124634	0.37
335.3621826	0.22
337.2151184	0.09
339.1084595	0.27
343.3158569	1.22
344.2849731	0.32
349.3033752	0.08
350.1473083	0.07
351.2238159	0.46
352.6757812	0.10
353.3151855	2.36
358.6050415	0.12
365.5485229	0.05
367.3510132	0.10
369.0384521	0.97
371.3118896	0.23
373.2386475	0.28
375.1504517	0.28
377.2059631	0.37
381.2536316	0.18
382.9809265	0.13
384.2304993	0.62
387.3730774	0.38
389.2297668	0.12
393.2777405	0.58
394.8768921	0.23
397.3070374	0.22
399.1134644	0.17
400.0311584	0.23
400.9049072	0.68
402.3705444	0.19
407.0869446	0.15
409.0268860	0.20
411.1462708	2.12
414.3925171	0.17
419.0735779	4.65
424.9822083	0.47
427.4131165	0.10
428.2538147	0.79
429.3103943	4.16
430.5042419	0.19
431.4276123	1.03
435.4667969	0.37
436.3845520	2.83
437.1113281	14.13
437.7587280	0.09
444.4482727	0.05
445.3203125	0.09
452.9891663	1.51
454.1400146	13.71
455.0309143	58.95
456.1769409	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1926
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
180.0384521	0.01
199.7870178	0.01
257.3124695	0.01
285.2125244	0.03
294.3046875	0.03
301.1823120	0.04
302.0628662	0.02
305.3467407	0.01
312.2135010	0.19
316.2241211	0.01
317.4723206	0.01
318.4688721	0.02
331.0742188	0.43
332.2879028	0.09
333.1877441	0.09
334.3842773	0.03
366.2843628	0.03
396.3081055	0.03
404.5069580	0.01
453.4517212	0.01
461.8751221	0.01
473.2947388	0.06
495.0725098	0.08
496.4819336	0.06
523.4542847	0.02
537.0975342	0.09
553.4077148	0.06
575.3765259	0.02
580.5319214	0.01
593.3003540	100.00
594.4357300	1.15
595.4852905	0.14
596.1799927	0.01
621.5321045	0.13
640.0554199	0.30
641.2929077	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	406.1635
Annotation	6-Acetonyldihydronitidine
Peak:m/z	Relative Intensity
115.7324371	0.02
116.8354263	0.01
122.0575867	0.01
129.9892273	0.28
137.0641479	0.01
139.0409546	0.04
142.0034485	0.03
143.8405762	0.10
145.0621948	0.10
156.0655365	1.90
161.9123230	0.47
162.9916077	0.03
169.9780579	0.03
174.0994873	0.23
177.0299683	0.35
178.9649048	1.39
183.0223846	0.08
184.0580750	0.05
188.9755554	0.12
195.5902405	0.03
206.9236298	0.01
207.9778900	0.02
209.0862885	0.01
210.1425629	0.78
212.9970093	0.02
215.4069824	0.03
216.0649719	0.27
217.2423248	0.01
225.1518250	0.07
227.0152283	0.10
228.3627625	0.01
229.1646118	0.01
232.3119507	0.03
233.0751038	0.02
242.0012817	0.18
244.8949280	0.12
249.1284180	0.01
256.4376221	0.04
259.0973206	100.00
260.1175232	0.12
272.0730286	0.30
276.9710999	5.74
277.6726074	0.01
285.0699463	2.40
289.5451965	0.10
290.1915283	0.00
305.0919495	0.04
308.1667786	1.12
311.4535522	0.03
312.6033936	0.20
313.2082520	2.05
322.3135376	0.06
325.0500793	0.06
331.1041870	1.54
343.2092590	0.14
347.7176208	0.01
362.1415710	0.08
370.1174622	0.04
370.9416199	0.02
374.2465820	0.04
377.8760986	0.02
388.2088623	11.04
389.2815857	0.13
396.7012939	0.04
397.7454224	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.2133
Annotation	Hydrocortisone succinate
Peak:m/z	Relative Intensity
137.1113892	0.14
138.9567261	0.40
141.0740051	0.39
147.0740967	0.30
148.9853668	0.77
152.9350586	0.50
156.9511871	0.57
161.1438293	0.56
162.9149780	1.87
165.0305481	2.06
170.2840271	0.28
172.1629639	0.15
172.9707642	0.73
173.8639832	0.19
175.1889343	1.26
177.0175781	0.55
178.1040649	1.04
181.0439453	3.22
183.0950470	0.22
185.1729736	0.65
186.3997040	0.77
187.0196381	0.38
188.8396149	0.25
191.0921173	2.37
192.9710999	3.16
197.1095276	0.74
198.3135223	0.17
201.0186462	2.32
203.2539368	1.42
205.0493622	0.38
206.6835327	0.74
211.0785980	3.51
213.0876617	2.65
215.3537292	0.75
216.8283539	0.90
219.0767822	1.09
221.0286560	0.20
222.1830444	0.30
225.1842651	1.79
227.1891785	7.93
228.1729736	0.59
229.2275391	1.97
231.1995239	20.05
233.2355804	4.79
234.9721832	0.24
238.1234894	0.16
239.1940308	0.21
241.0914764	2.92
243.2561798	11.87
245.1867828	11.35
246.4291077	0.52
247.1117401	0.88
249.2113342	5.63
251.1111450	2.55
253.1840515	7.43
255.2421570	0.76
257.1779175	1.01
259.2471008	77.14
261.1841736	12.75
263.1972046	5.18
269.2028809	1.41
271.2158203	14.08
274.4055786	1.65
275.0125427	0.16
277.2014465	8.59
280.7493591	1.29
285.0135498	0.25
287.2695618	2.80
289.2403564	47.04
291.4473877	0.29
293.2092285	2.08
295.1078186	3.25
303.5308228	0.64
305.1539612	0.79
307.2142334	24.38
307.8398438	0.24
311.2494202	0.80
313.2519836	1.11
315.0485229	0.67
316.0760193	0.16
317.1511536	0.66
319.3716431	0.53
321.2034912	1.52
323.2739258	10.33
327.2060547	0.58
328.7983398	0.24
331.2929077	1.91
333.2414856	5.45
335.1891785	1.42
337.4017334	0.25
339.3110962	0.40
341.3480530	0.51
345.4245911	2.50
347.3000793	3.28
349.3296509	100.00
351.2619629	2.97
357.1302490	0.63
359.2628784	0.24
365.1721191	9.89
367.1641235	1.68
375.2894897	0.94
377.4904480	0.13
381.2183838	0.94
383.6369019	0.11
385.2296448	1.95
387.2767029	0.20
389.1202393	0.23
393.2995300	8.39
401.2431030	4.27
419.1499939	0.28
427.4056091	0.44
429.3193054	7.38
441.4393311	0.43
443.1200867	0.31
444.9339905	0.71
445.5394287	4.91
447.2157898	1.33
461.3459473	1.04
471.3105774	3.39
490.0862122	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2626
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
139.9272919	0.03
147.0323944	0.01
153.1647491	0.02
196.0776672	0.07
203.1978149	0.03
214.1395111	1.88
233.3203735	0.55
240.9036560	0.03
259.3537292	0.35
275.3422241	0.53
277.2141418	100.00
278.0054321	0.01
328.4103394	0.01
367.4960327	0.04
429.4251099	0.04
431.1222839	0.02
442.0745544	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1669
Annotation	Butrin
Peak:m/z	Relative Intensity
176.9903564	0.27
224.0026093	0.04
235.1484070	0.09
251.3391266	0.15
269.0464172	0.50
270.0178833	0.04
287.0507812	100.00
288.0872192	13.42
311.0879517	0.06
359.0831909	0.14
434.2833862	0.06
459.2861938	3.08
460.1591187	0.27
469.2318726	0.12
487.2658691	0.20
577.3411255	0.32
578.1887817	0.16
595.8322144	0.19
596.5858154	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.17
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
214.2078247	0.03
221.1848602	0.03
225.292572	0.01
250.4679565	0.03
254.9065857	0.02
271.0735474	28.26
271.7381592	0.22
273.1475525	0.21
283.2589111	0.08
287.4917603	0.05
294.458313	0.10
307.3117676	0.02
313.2625122	0.55
315.2720337	0.02
316.7823486	0.03
325.4368896	0.02
329.1416016	0.06
330.2766113	0.31
331.1184082	1.12
337.28479	0.19
343.1086426	0.03
345.1975708	0.10
363.2839355	0.02
367.3481445	0.02
373.2901001	0.05
375.0109253	0.06
379.5600586	0.03
380.3366699	0.04
381.1925049	0.71
397.2757568	0.23
399.2490845	0.01
415.328064	0.84
416.0101318	0.04
417.1496582	0.60
424.3509521	0.01
426.5470581	0.02
431.2907104	0.08
433.112915	100.00
433.8467407	0.34
447.3083496	0.04
450.1138916	0.12
457.2133789	0.02
459.2366333	0.11
462.2775879	0.03
464.6134644	0.05
475.2015991	0.03
485.3042603	0.03
488.3256226	0.02
489.2880859	0.02
493.1384277	0.07
501.1672974	0.02
506.15802	0.02
516.6362915	0.03
517.2521362	0.02
518.8069458	0.04
520.4415894	0.05
521.4291382	0.15
542.5265503	0.07
543.2126465	0.11
560.5233154	0.09
561.3999634	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1724
Annotation	Asystasioside C
Peak:m/z	Relative Intensity
149.0699310	1.00
164.8971863	0.31
172.9944000	0.26
176.1149292	0.31
187.1016083	0.78
191.1744995	1.31
193.1632080	0.42
199.1665955	0.21
205.1317444	0.14
221.3114929	0.15
232.9944611	2.99
239.0364990	0.43
249.1805725	0.17
252.1372833	0.12
280.2697754	0.57
286.9663696	0.19
293.1376343	100.00
337.2952271	0.18
338.3583984	0.50
357.3143311	0.38
368.3998413	0.33
375.2082520	0.19
407.3320312	0.19
420.9620361	0.27
429.3132935	0.12
432.1220093	0.22
433.2989502	0.23
446.4355469	0.17
447.2280273	0.47
472.9411621	46.88
474.0946045	0.54
475.2499390	0.16
481.4893188	0.64
501.0786133	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	761.1753
Annotation	Ptd(S)Ins-(3,4)-P2 (1,2-dioctanoyl)
Peak:m/z	Relative Intensity
302.8910522	11.96
391.2418823	10.83
418.696106	4.51
459.2305908	12.59
495.2313232	100.00
550.9273071	4.83
563.104187	3.55
569.4050903	15.02
570.992981	11.27
731.3120728	7.39
761.1856079	94.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	571.66
Annotation	Unknow
Peak:m/z	Relative Intensity
177.0537872	0.03
179.1823273	0.01
187.0979614	0.03
196.1989441	0.05
212.9330444	0.10
214.2658081	0.06
253.1008606	0.05
271.1851807	0.04
272.0778198	0.01
286.0513306	0.02
287.3021240	0.02
289.3844604	0.02
298.1541138	0.33
299.2652588	0.01
300.1806641	0.11
300.9933472	1.03
302.0032349	0.11
316.1641846	1.39
317.1734619	0.29
328.2025757	0.14
331.1476440	100.00
332.1235352	11.12
333.1884766	0.08
346.1991577	0.42
347.1905518	0.03
361.1452026	29.80
362.1505127	4.14
362.7512207	0.01
369.0672607	0.02
387.3159790	0.10
388.3260498	0.07
389.2872925	0.05
390.7655640	0.03
397.1561890	0.10
402.6863403	0.10
407.2535400	0.06
436.3988647	0.06
439.1188965	0.06
451.1859741	0.50
452.0152588	0.29
469.0629883	0.75
470.2114258	0.25
485.0392456	0.03
487.2896729	0.12
488.8633423	0.03
489.6171265	0.02
503.3641357	0.01
508.5812988	0.05
509.4805908	0.02
513.6448364	0.06
519.3200684	0.05
523.4035645	0.05
524.9294434	0.06
546.4601440	0.05
547.1990356	0.02
554.7248535	0.04
575.3357544	0.06
594.9579468	0.06
601.3573608	0.05
605.1806030	0.58
606.0147095	0.28
607.2677612	0.07
608.2519531	0.06
613.2478638	0.23
619.0154419	0.06
619.9248047	0.09
620.5686646	0.09
630.5181274	0.09
631.2657471	0.32
631.9541626	0.03
637.2704468	0.05
638.4520874	0.05
649.1698608	3.85
650.0457153	1.06
650.8388062	0.08
667.3024902	1.65
668.3134155	0.11
686.3313599	0.07
688.3142700	0.02
708.9843140	0.62
709.6159058	0.17
710.2940063	0.23
721.6848145	0.06
732.2727661	0.05
738.8850708	0.26
739.4917603	0.35
745.3328247	0.71
746.4318237	0.03
756.8118286	0.46
757.5109863	0.41
758.1476440	0.20
763.1948853	0.34
764.4208984	0.06
775.2003784	15.18
776.3236694	6.03
781.2676392	0.10
782.5634155	0.07
793.1619263	9.49
794.2852173	2.51
811.1917114	5.90
812.3341675	1.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	395.1924
Annotation	Creoside IV
Peak:m/z	Relative Intensity
114.9802094	0.10
128.1718597	0.04
142.9340973	0.11
158.7910461	0.06
160.4627991	0.28
161.0770416	1.35
162.2115784	0.06
171.0930481	0.13
173.2258606	0.14
187.1779327	0.05
187.9637146	0.07
191.0709686	0.11
197.0600891	0.16
215.0921173	0.34
221.1885986	0.07
224.9598083	0.04
229.1018677	0.08
233.2606506	0.69
245.2733765	0.28
247.1268311	0.22
249.1749878	0.12
253.3337402	0.05
259.0732727	0.09
261.2358398	0.10
263.1948853	0.11
279.3934937	0.07
282.9343872	0.14
289.1889648	0.06
293.2606812	0.08
295.0902100	0.25
297.2819214	0.07
305.0249023	0.06
307.1593018	0.13
309.1736450	0.28
311.0534058	0.28
323.2731323	0.11
330.9144897	0.05
333.3836670	0.11
335.2587280	0.47
347.1949158	0.36
349.1567993	100.00
349.8633728	0.51
351.0990295	0.17
353.2481689	0.27
358.9981995	0.29
364.2914124	0.04
365.3647766	0.23
376.9194641	0.41
380.2298279	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.1254
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
160.0187073	0.78
172.8666687	6.02
175.0669556	0.98
176.9771423	0.32
177.9217377	0.63
183.2312927	0.13
190.9640503	8.34
192.9884338	12.96
201.3872528	0.13
202.4523468	0.13
208.9712524	0.36
217.0857544	1.35
221.2261505	0.15
223.0105743	0.18
233.0958557	1.13
243.1285553	0.62
261.0716553	6.70
287.0260620	0.51
305.1349792	0.26
317.0721436	0.63
323.2080688	14.10
327.3894043	0.26
330.4953613	0.16
337.1043091	0.15
348.7714844	0.20
353.2164307	0.45
355.2091064	0.34
361.2966309	0.08
367.1483154	100.00
373.3638306	0.13
385.1000366	10.86
395.5373535	0.12
441.3228760	0.23
479.4237061	0.14
498.9441528	1.17
517.1596069	0.21
517.8683472	0.15
521.9070435	0.17
523.3475952	0.13
542.7097778	2.32
543.3262329	0.89
547.2893066	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	743.2025
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
215.0292664	0.03
216.9185486	0.05
218.1053162	0.02
219.2012634	0.06
220.0072784	0.03
224.0129089	0.01
224.9632263	0.01
233.0111084	0.05
234.8402710	0.03
236.2285004	0.01
242.9026031	0.11
244.2666626	0.02
249.3166351	0.01
253.2501526	0.05
254.4579620	0.01
259.1813354	0.02
259.8471375	0.01
269.3216553	0.08
270.3216553	0.12
271.1893921	0.06
272.2697754	0.03
277.3448486	0.04
279.3720398	0.05
280.2021179	0.01
287.1665039	0.48
288.1968384	0.35
289.2572327	0.04
294.9649353	0.01
297.0498352	0.09
298.2113953	0.02
310.1180420	0.02
311.0715637	0.01
312.3194580	0.01
313.3841553	0.05
314.0535278	0.01
315.2245789	0.16
316.1076965	0.10
329.4024353	0.07
330.0478516	0.08
339.1578369	1.70
340.2919922	1.20
341.2406006	0.14
343.3416138	0.02
353.7920837	0.03
355.2038574	0.02
356.0415039	0.06
357.1422119	1.14
358.1978760	0.79
359.4081421	0.16
360.2127686	0.05
364.2297974	0.06
365.3776245	0.06
368.8789673	0.01
371.1361084	0.02
382.1822510	0.01
384.1011963	0.03
393.5930786	0.03
400.1975098	0.02
401.6787109	0.02
405.3188477	0.01
406.3159790	0.08
415.3850098	0.02
418.5081177	0.01
423.3405151	0.16
424.3934937	0.05
425.4127197	0.10
433.4520264	0.16
434.3345337	0.10
441.3036499	0.27
442.1768188	0.12
444.3204346	0.11
457.5690918	0.04
459.1916504	0.15
460.2753906	0.10
461.5739746	0.09
475.3069458	0.17
476.2827759	0.19
477.2503662	0.32
478.2856445	0.20
479.3232422	0.10
490.6405029	0.03
493.4403076	0.04
498.7495117	0.03
503.1718750	0.02
504.5059814	0.02
505.1770020	0.02
506.3424072	0.01
520.3050537	0.03
535.3366089	0.03
536.4377441	0.06
537.4497681	0.03
547.4318237	0.04
559.6251831	0.03
560.4490356	0.02
561.4496460	0.01
562.5751953	0.04
563.2315063	0.02
570.2916870	0.02
577.4634399	0.06
578.8096313	0.15
579.5988770	0.28
580.4073486	0.37
581.4628296	0.22
583.3133545	0.07
587.1986084	0.34
588.3325806	1.34
589.4226685	0.28
590.2880859	0.03
591.1286011	0.02
595.4470825	0.16
596.3246460	0.29
597.6098022	0.02
605.4866333	45.81
606.3330078	100.00
607.2927246	21.39
607.9306030	0.07
614.4879150	0.01
616.4782104	0.12
617.4831543	0.04
618.5412598	0.03
619.4622803	0.17
620.3414917	0.34
621.3384399	0.24
622.3303833	1.14
623.5145874	0.19
631.8674316	0.12
632.5443115	0.04
633.1788330	0.03
636.4641113	0.01
638.4533691	0.01
640.3370361	0.06
653.3008423	0.02
654.4348145	0.01
659.2272949	0.01
663.3339844	0.02
669.3833618	0.02
683.3728027	0.06
684.9525757	0.07
696.0816040	0.04
698.4055176	0.02
700.4061279	0.01
701.4826660	0.04
706.2142944	0.17
724.3283081	1.78
725.3607788	0.26
726.6835938	0.01
743.3721924	5.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	491.1199
Annotation	Oenin
Peak:m/z	Relative Intensity
178.9964752	0.06
185.9553680	0.04
207.0214844	0.12
213.0957642	0.07
218.8820953	0.09
227.0596008	0.09
227.9917908	0.20
242.0657654	0.09
245.1617126	0.05
249.1802216	0.03
253.1910095	0.05
253.9579773	0.06
256.1815186	0.39
257.1367798	0.41
258.2148438	0.04
259.8702087	0.07
267.1224976	0.02
268.0200806	0.10
269.3019714	0.10
270.5737915	0.03
272.3893127	0.03
281.4364319	0.34
282.3410950	0.26
283.1424255	0.31
284.1601868	0.10
285.2236938	0.33
286.3988037	0.09
287.2427979	0.04
296.4106750	0.15
297.0631104	0.13
298.2990417	0.31
299.1141968	1.03
302.3343506	0.05
309.1342773	0.32
309.9522705	0.11
310.9811401	0.14
313.0733032	34.17
314.1215210	10.82
315.1841736	1.32
327.2218933	2.84
328.1372070	10.90
329.2407227	21.35
330.3285828	0.10
336.6033020	0.04
339.6438599	0.16
340.2631531	0.02
341.2521667	0.24
342.1575928	0.22
343.1601562	0.23
351.0477295	0.04
356.2186890	0.59
357.4411316	0.15
358.2753906	0.02
359.2874756	0.03
369.9148865	0.05
371.2364807	6.03
372.0499268	0.04
380.2005615	0.07
383.1763916	0.03
384.3193970	0.08
391.2753296	0.04
397.3808594	0.11
401.1785583	0.31
404.2864380	0.02
407.1242371	0.03
415.2210693	0.05
419.2339783	0.51
427.5863342	0.02
431.2318726	0.18
445.1732483	1.56
447.2151184	0.02
454.4050598	0.05
455.2357178	0.07
459.1910706	0.41
460.1260071	0.09
461.2354431	2.22
463.5634460	0.02
476.1902771	100.00
477.0918884	1.97
477.7552185	0.01
492.3487244	3.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	526.1406
Annotation	Unknow
Peak:m/z	Relative Intensity
150.9996490	0.21
165.0818787	0.13
176.4382629	0.15
177.0929565	0.18
193.1222229	0.11
198.8798065	0.09
212.1665649	0.20
216.4548950	0.06
242.1542816	0.34
286.2941895	0.05
299.1933594	1.17
301.0840454	59.19
302.2572021	5.05
315.1417847	0.25
325.0162354	1.01
327.2260132	0.12
339.2359619	0.07
340.3568726	0.22
343.2037354	1.03
344.2383423	0.11
368.0053101	0.15
418.3748779	0.21
439.3520508	0.11
444.2778320	0.11
445.2588501	2.34
446.3073730	0.23
463.2161255	100.00
464.3173218	12.88
466.4263306	0.05
487.2354736	0.43
488.2448730	0.16
489.2116699	0.26
491.4304199	0.08
495.3565674	0.30
503.2059326	1.10
505.2271118	84.05
506.2719727	13.89
517.2490234	0.20
517.8751221	0.10
527.0215454	0.45
545.2365723	1.10
547.2929077	8.96
548.3029175	2.25
569.3172607	0.09
570.3566284	0.34
571.3184814	3.36
572.2810669	0.05
577.5165405	0.19
587.2223511	0.18
589.2729492	3.18
590.3234253	0.66
607.3036499	0.14
608.6719971	0.26
617.6309204	0.22
631.1690674	1.16
649.2647095	1.35
650.2332153	0.92
653.0466309	0.41
666.8288574	0.10
673.1321411	0.27
689.1563110	0.23
691.2639771	0.31
703.9661255	0.10
709.3003540	0.13
715.1912231	0.22
733.3340454	1.30
751.1696167	3.08
752.4103394	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1821
Annotation	Hesperidin
Peak:m/z	Relative Intensity
171.3074188	0.09
173.0240173	0.09
174.2073669	0.29
175.0985413	0.07
177.0853119	0.11
185.1124573	0.17
186.7520294	0.09
188.0954132	0.18
188.9629669	0.09
190.1676636	0.06
195.039093	0.03
197.1339111	0.04
199.0487976	1.91
200.0233002	0.02
201.0412292	0.56
202.1677399	0.49
207.1414795	0.08
209.2476501	0.02
211.1105499	0.12
211.9614563	0.09
213.1498718	0.49
214.1176758	0.23
214.9906921	0.97
215.9988403	0.29
217.1039581	0.50
217.8050842	0.04
219.2389832	0.04
222.0930023	0.06
224.0313263	0.44
224.9524078	0.22
227.1030731	1.06
229.042923	0.12
230.0425415	0.18
233.1441193	0.37
235.2761536	0.07
237.9159546	0.04
239.1675568	0.32
239.8650513	0.25
241.0690765	0.94
242.0581207	2.42
244.3437347	0.14
249.1160431	0.08
250.2537537	0.13
254.0661316	0.06
257.1558228	0.98
258.06427	0.31
259.0355225	0.17
264.7111816	0.48
265.9562378	0.24
268.1351929	0.92
269.1838989	0.12
271.3248596	0.04
279.2736206	0.25
280.1269226	0.08
281.4491272	0.22
282.4314575	0.73
283.2074585	1.92
284.1510315	0.09
285.4522095	0.51
286.1785889	2.46
292.2265015	0.18
293.0425415	0.10
296.0747681	0.12
297.2008057	0.88
299.2000122	1.33
301.0803833	100.00
301.6945801	0.29
307.2380981	0.57
308.2064209	0.06
310.135437	0.74
313.0643921	0.08
313.9658203	0.13
315.1563721	2.05
319.4714355	0.06
322.2080688	0.19
323.7024841	0.16
325.1914062	10.72
326.5714111	0.02
327.2977905	0.12
328.262146	0.20
337.263916	0.34
339.1950684	0.12
340.43927	0.07
341.1069336	0.43
343.1722412	12.71
343.7885742	0.20
349.0768433	0.22
352.0917969	0.06
354.4874878	0.54
355.2614746	2.19
357.1453247	0.08
361.1790161	0.17
367.303833	2.31
369.1315308	0.11
371.3366699	0.03
373.1965332	0.41
380.8873901	0.10
383.2045898	0.03
385.1331177	1.61
387.1845093	0.03
391.2780151	0.17
393.0587769	0.23
395.1288452	0.03
397.3019409	0.28
402.7718506	0.30
403.3737183	1.32
409.3847046	0.14
411.3231201	0.05
421.296875	0.05
427.3798218	0.16
429.2042236	1.16
443.3126831	0.03
444.4397583	0.21
445.2337036	0.77
447.2556763	1.87
455.2734375	0.09
459.2320557	0.36
463.2382812	0.90
464.5213013	0.04
471.0946045	0.57
473.3382568	0.10
485.0776367	0.19
485.7177124	0.13
489.3179932	11.25
495.0888672	0.05
509.2260132	0.13
541.2371826	0.11
565.1156006	0.11
567.3428345	0.06
576.4033813	0.07
591.3920898	0.90
594.465332	0.19
609.5771484	0.03
610.2979126	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.0827
Annotation	Dianthoside
Peak:m/z	Relative Intensity
113.0055542	0.05
125.0002441	38.49
141.0940399	0.04
149.0223389	19.01
160.9983215	0.05
167.1403351	0.06
171.1393738	0.08
179.2000122	0.17
191.1961975	0.65
205.0440979	0.07
209.0197754	0.31
217.2286377	0.15
227.0762939	2.83
241.1459656	0.03
242.4137268	0.08
261.2136230	0.07
265.2962952	0.11
269.0159912	0.55
287.0167847	100.00
293.5049438	0.15
298.2379761	0.09
315.0440063	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.2145
Annotation	ATRACTYLOSIDE
Peak:m/z	Relative Intensity
230.2740173	0.34
235.1793823	0.13
262.925293	0.14
265.0647583	0.20
315.0587769	0.14
322.9868774	0.25
337.177002	2.33
339.0974731	0.33
341.15448	0.86
345.2345581	0.11
375.1665649	0.33
383.347229	0.15
517.1966553	93.13
550.3339233	0.14
579.9526978	0.13
593.5819092	0.08
629.3902588	0.96
634.1038818	0.27
641.335022	0.73
665.2748413	0.18
678.4868774	4.15
679.0873413	16.60
691.7473755	0.06
706.1826782	0.06
707.3823242	0.40
708.5533447	0.12
725.1951294	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	521.2037
Annotation	Acetylchapliatrin
Peak:m/z	Relative Intensity
151.1295776	1.94
152.9015961	2.38
154.2060242	0.35
159.1143188	0.81
161.2075958	0.50
162.9372559	0.90
169.0115356	3.10
172.9461212	0.37
175.3839417	0.37
177.0756989	0.85
186.3208313	0.17
187.0446472	1.31
189.1569214	3.12
191.2240448	3.21
192.9490662	0.97
201.1139832	0.45
203.2245178	0.76
205.0101624	0.57
207.1020203	1.56
210.0911407	0.48
211.2463684	0.57
212.9484100	0.75
215.2480164	1.00
217.1432343	1.58
219.1311340	3.65
224.0194397	0.76
225.1295624	0.16
227.1973267	1.08
228.9967346	0.86
231.3235321	0.48
233.2194214	1.60
234.2978210	0.47
237.1445007	0.55
239.4629974	0.73
241.0689850	0.63
243.2642059	2.50
245.4557495	1.15
246.5999451	0.77
247.2406006	4.82
249.2236481	3.89
251.2195587	1.32
253.3568726	0.55
255.3002930	4.01
257.3200684	0.72
259.2475586	3.37
261.3110352	0.60
262.9430542	1.23
265.0827942	0.67
267.1105957	0.47
268.2125244	0.47
269.2749939	0.95
270.2731323	0.58
271.3535461	1.25
273.2123413	8.49
275.4608765	1.01
277.1028442	9.65
279.2068481	1.07
281.5040283	0.38
282.7288513	1.17
283.6026611	0.15
285.5727539	0.78
287.2095947	4.14
289.1547241	6.88
291.3807983	0.82
293.2644958	3.78
294.3421631	0.27
295.4592896	1.67
297.3289795	4.93
299.4829102	0.62
301.3191528	0.99
303.1348877	1.05
304.6458130	0.59
305.2667847	2.39
307.1105957	9.01
309.3491211	6.82
311.5230103	1.59
315.3408813	8.83
317.2208862	0.36
318.3397827	0.55
319.4794312	1.45
322.4162598	0.19
323.2470093	1.96
325.2131958	3.90
326.1614380	0.29
327.2021484	2.76
329.2747192	1.63
330.3421021	0.17
331.2248535	1.75
333.1933594	22.17
335.2825317	0.46
336.5661011	0.43
337.2901001	6.83
339.1254272	0.15
340.3713379	0.98
341.2200928	2.92
343.1425171	1.74
344.1241455	0.54
345.3234253	4.50
346.6918335	0.78
347.4176025	4.99
349.3557739	7.53
351.3701172	2.47
353.3836670	1.98
355.2730713	14.08
356.4552002	0.37
358.1734619	2.28
359.1914673	1.55
361.3181763	2.85
363.3662720	0.17
365.1726685	1.72
369.2918701	0.81
371.2788696	4.10
373.2372437	43.74
375.4038086	0.34
377.3654785	2.69
379.4002686	2.28
380.9006348	0.58
382.2088013	2.27
383.2790527	0.28
389.3726807	5.62
391.2836914	34.74
393.2777100	20.78
397.2902832	4.04
399.3403320	3.03
400.3803101	0.57
401.3176270	0.43
403.3168945	3.33
405.2534790	0.69
407.2974243	0.24
409.0000000	0.14
413.3898926	0.20
415.3808594	31.30
417.1871338	4.86
419.1410522	0.62
421.2915649	0.15
425.3828125	0.27
429.5547485	0.56
431.1510620	4.38
431.7756958	0.58
433.3511963	43.01
435.3442383	5.27
441.2297974	0.59
443.4088745	0.70
447.4438477	0.49
449.2218628	1.90
459.2733765	31.83
460.0565186	0.35
461.2196655	4.11
475.3904419	3.60
477.2885742	100.00
478.1372681	1.63
479.2854614	1.18
490.3621826	0.83
491.1221313	5.55
493.4782104	0.59
503.2821655	2.01
506.2475586	16.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.2377
Annotation	Rzedowskin A
Peak:m/z	Relative Intensity
161.0113678	15.72
203.0534058	5.78
217.2842255	2.23
233.2104492	4.96
241.1360474	4.83
257.0744629	3.57
270.8458252	2.11
312.3311157	2.41
315.4619141	3.19
319.0843506	9.65
325.2212524	2.40
327.0112915	4.55
333.1618652	8.97
341.2136841	6.94
357.4538574	2.27
363.2928467	4.94
365.2100830	2.75
367.1879272	4.04
369.2625732	100.00
375.3555908	7.56
376.9392700	6.28
380.6138916	1.95
381.6557007	3.72
391.2946167	14.47
393.3616333	23.00
409.2242432	20.78
411.4024048	7.89
413.3413086	3.71
419.3763428	6.42
429.2546387	17.29
437.2741699	18.61
455.1812134	22.21
456.9758301	1.84
469.1873779	4.67
471.3758545	11.13
473.3161011	9.14
487.0186157	16.16
497.4738770	2.72
515.1696167	93.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1141.3047
Annotation	Unknow
Peak:m/z	Relative Intensity
330.0787964	0.13
507.6445007	0.04
548.3586426	0.15
763.4084473	0.03
773.3074951	0.04
1140.1990970	64.83
1141.2192380	100.00
1142.0112300	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.2625
Annotation	Cryptophycin A
Peak:m/z	Relative Intensity
190.1814423	0.19
202.0767670	0.28
213.0321960	0.65
215.1489563	0.26
224.1410217	0.55
225.5292511	0.17
226.9675293	0.27
230.2586975	0.10
230.9474792	0.22
236.8427429	0.13
238.0725861	0.19
241.1888580	0.81
242.2695618	0.13
247.2727661	0.07
248.7136230	0.50
249.9904327	0.13
253.3515015	0.70
254.2882080	0.25
255.0658569	0.19
256.1876221	0.06
257.1250610	0.18
258.8577271	0.38
264.2733765	0.28
265.2243652	0.23
266.1385498	0.43
267.2480774	0.50
268.1141357	0.16
269.0524902	0.30
271.2467041	0.42
273.8284912	0.43
276.0398560	0.37
277.1809082	0.21
279.2463379	0.25
280.1004028	0.27
281.3846130	0.11
283.1143188	0.23
284.2224731	0.19
285.0652771	0.26
286.5931702	0.11
287.3046265	0.08
291.3999634	0.06
293.0378418	0.34
294.0769958	0.44
295.0550842	0.06
297.2440491	0.06
298.0033264	0.32
298.6052246	0.08
299.2908936	1.03
300.2110596	0.57
301.2810669	6.43
302.2580566	2.11
303.3142395	0.23
307.2031860	0.68
308.3790283	0.18
309.1346436	0.82
311.3287659	0.62
313.2761841	0.69
314.5561523	0.25
315.4298096	0.34
319.3799438	0.43
321.1993408	2.06
322.3503723	0.54
323.2517395	0.90
325.1795044	2.16
327.1542358	1.06
328.2149048	0.53
328.9345703	0.07
332.3318481	0.54
334.2074585	0.18
337.3173523	0.40
338.2441101	0.52
339.2954712	0.24
341.0621948	0.44
342.3079834	0.51
343.4376221	0.22
344.4827881	0.07
345.4080811	0.25
347.2202148	0.09
351.2393799	0.08
351.9913940	0.27
353.3504639	3.80
355.2272339	6.44
356.2938843	1.68
358.1492310	0.38
359.3174438	0.19
360.5501709	0.12
366.3243408	0.16
367.2158813	0.51
368.2216187	0.64
369.0754395	0.33
371.3005371	0.42
372.5562744	0.41
373.5273438	0.33
374.4182739	0.10
376.3684692	0.19
377.3396606	0.13
378.5993652	0.11
381.2172852	0.42
385.0214233	2.42
386.2423706	0.20
387.3077393	2.56
388.3106689	0.33
389.3186646	1.11
390.0399780	0.20
391.3726807	0.17
394.3422241	0.08
398.3343506	0.10
399.1554565	0.18
400.2395020	1.17
401.3145142	0.34
402.0969238	0.10
409.3911743	0.18
410.4372559	2.16
411.3704834	0.71
413.4152222	0.29
414.3001709	0.43
415.5154419	0.49
416.2064819	0.63
417.1617432	0.42
418.3604126	1.00
421.1314697	0.27
423.2158813	0.36
426.3663330	1.35
427.5220337	0.78
428.2763062	3.38
429.3793335	0.68
430.5255737	0.31
431.6203613	0.24
432.3802490	0.69
433.4176636	0.72
436.1193848	0.28
438.4049683	0.07
439.3664551	0.22
441.4365234	0.05
442.2653198	1.19
443.6240234	0.16
444.2631226	0.34
445.4973755	0.34
446.3983765	0.12
447.2570801	0.57
448.3165283	0.82
449.2184448	1.13
450.5245972	0.10
452.3123169	0.12
453.5610352	0.50
454.3525391	0.89
456.1434326	0.49
457.1773071	0.17
458.1820068	0.16
460.3153076	1.18
461.2008667	0.35
463.3731689	1.01
464.3219604	1.61
465.2672729	0.59
466.2630005	0.15
468.4809570	0.10
470.5398560	0.17
472.5645142	0.69
473.4877319	0.29
475.1929932	0.44
476.8039551	0.38
477.5679321	0.47
478.6179199	0.11
480.4090576	0.36
481.6005859	0.94
486.2801514	1.79
488.4605103	0.07
489.5099487	0.16
490.3071289	3.84
491.3745117	12.75
492.4384766	5.15
493.3024292	2.38
494.2186890	0.37
495.3087158	0.33
497.1065063	1.06
498.1403198	1.51
499.2537842	0.54
500.2048340	0.54
501.3498535	0.94
502.3301392	1.71
503.3523560	0.85
504.5214233	0.71
505.3921509	0.46
506.3917236	1.41
507.4026489	4.14
508.3331909	1.34
509.2277222	0.21
510.3023071	0.45
511.5817871	0.11
512.2971191	0.17
516.6552124	2.95
517.5715942	2.33
518.5956421	0.78
519.3147583	1.71
520.4431152	1.04
521.5975952	1.04
522.4534912	2.63
523.4132690	8.30
524.4285278	5.33
525.2808228	0.96
526.4045410	0.14
527.5497437	0.81
528.5028076	0.38
529.6220093	0.25
531.4464722	0.91
532.5079956	0.45
533.7330933	4.31
534.3690796	9.00
535.3339844	18.66
536.5122681	4.49
537.2330933	0.42
539.3298950	1.16
540.2551880	0.13
544.3734741	0.51
545.5027466	3.27
546.4264526	1.52
547.3662720	1.15
548.3472290	3.11
549.3453369	8.27
550.3926392	6.45
551.4237061	18.62
552.4176636	6.68
553.4512329	2.04
554.3899536	0.84
556.5447388	0.46
557.2746582	0.37
559.5357666	1.45
560.4036865	1.79
561.4219971	2.36
562.5109863	0.56
563.5455322	0.94
564.5399780	0.10
565.7245483	3.52
566.4979858	4.24
567.4768066	3.42
568.3694458	1.07
570.3977661	0.45
571.4302368	1.39
572.4194946	0.34
573.3183594	0.16
574.7998657	0.32
575.5770874	2.11
577.4238892	41.98
578.3975220	22.37
579.3534546	8.27
580.4265747	6.40
581.4672241	3.55
582.5690918	1.98
583.4058838	4.83
584.3194580	4.83
588.2567749	0.10
589.3644409	5.06
590.4852905	2.02
591.4612427	0.11
593.3777466	23.96
594.4188843	8.32
595.4343872	0.91
596.3843384	0.80
597.3328857	1.20
598.4678345	1.07
599.3375244	1.98
603.3837280	13.46
604.3949585	5.49
606.3123169	0.84
607.3635864	2.80
609.3480835	11.02
610.3537598	84.42
611.3637085	34.91
612.4335938	0.21
617.3749390	0.20
621.3123169	100.00
622.3148193	34.85
623.0885010	0.05
625.3285522	21.82
626.4741821	5.68
635.3799438	40.51
636.3955688	14.27
638.3237305	83.21
639.3929443	34.73
654.3692017	9.42
655.3281250	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1095.5433
Annotation	Unknow
Peak:m/z	Relative Intensity
822.5854492	0.27
823.4569092	0.06
966.5117188	0.83
967.6263428	0.66
1034.7559810	0.05
1078.6496580	0.65
1095.5861820	100.00
1096.5695800	48.73
1097.2150880	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8460541	0.20
210.8609772	0.07
212.7613220	1.83
290.8075562	0.27
292.9317017	0.56
294.9307861	0.08
295.8594360	0.07
296.8409424	3.03
359.0466309	0.07
380.7498779	26.64
386.6184082	0.23
393.1058960	0.04
397.0310669	0.11
453.1900024	0.06
458.1781006	0.06
460.8760986	0.24
461.7136841	0.39
462.9415283	0.16
464.6127319	61.64
465.2609253	0.44
485.2191772	0.49
521.0871582	0.03
542.7064209	0.46
545.5831909	0.34
546.6813965	0.12
548.5486450	100.00
549.2603149	0.27
569.1614380	0.04
589.8532715	0.14
636.4589844	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	630.88
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0889282	0.33
244.8525085	0.41
272.9783020	4.00
273.8904724	0.07
288.9996948	12.35
304.9425049	0.20
329.2454224	0.07
385.2191772	0.05
386.8936157	2.05
398.9284668	0.05
400.2555542	0.07
401.2329102	0.26
402.9158325	43.27
403.5941162	0.04
424.1088867	0.04
441.7279663	0.11
466.8610229	0.06
467.8105469	0.04
470.3789673	0.05
471.3463135	0.02
484.8958740	0.17
496.6439819	0.04
499.6872559	0.37
500.9696655	0.75
514.8746948	1.67
516.9080200	100.00
518.7754517	0.04
538.1046753	0.15
539.1685181	0.07
539.8866577	0.05
544.8784180	0.28
556.8316040	0.25
562.8583984	0.12
567.9843750	0.03
584.0071411	0.78
585.0274658	0.35
585.9962769	0.15
595.2745361	0.06
600.7300415	0.21
602.7188721	0.05
608.9921875	0.04
612.0843506	0.52
620.7146606	0.11
630.9448853	0.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	646.86
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9649506	0.20
232.9458313	0.06
244.9773712	0.22
260.8614502	0.14
273.1210632	0.38
288.9967957	9.18
304.9277954	3.58
386.9592285	0.31
402.9848022	11.75
417.3375244	0.07
418.8750000	26.19
419.5004272	0.05
458.8376465	0.08
500.9588623	0.51
502.1271973	0.23
516.2461548	0.38
516.8883667	2.84
517.5137329	0.05
530.9122925	1.28
532.8145142	100.00
533.5034790	0.18
535.0756836	0.05
571.8256836	0.18
572.7045898	0.10
599.9884644	0.29
601.1702271	0.43
601.9092407	0.17
602.8261719	0.05
614.0256958	0.04
628.8964233	0.11
635.9970093	0.10
646.8607788	5.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.2409
Annotation	Phaeophorbide b
Peak:m/z	Relative Intensity
281.2460022	0.01
283.9047241	0.02
299.1680603	0.01
365.0834351	0.01
461.4461060	0.08
462.2596436	0.03
463.4890747	0.03
485.1760254	0.18
486.3651733	0.05
487.1369019	0.08
488.2656250	0.06
502.5492554	0.03
503.2037964	0.01
505.4971924	0.01
511.5748901	0.01
512.3333130	0.04
513.0386353	0.02
513.8057251	0.01
514.4086304	0.05
515.2512817	0.06
529.3417358	100.00
530.3468018	33.27
532.3746948	0.09
533.4705811	0.56
534.5265503	0.19
538.4993286	0.02
543.3476562	0.01
544.9845581	0.05
546.0866089	0.01
547.6139526	0.02
551.7231445	0.02
561.3451538	1.72
562.4193726	0.49
573.1842651	14.22
574.2777710	2.55
606.2635498	0.09
607.7514038	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	312.18
Annotation	Racemonine
Peak:m/z	Relative Intensity
90.8551712	0.48
93.0874634	0.37
93.9110794	0.23
94.9629440	10.42
95.8220215	0.40
100.8097916	0.27
101.9080811	0.31
108.9840775	1.32
109.9676743	2.16
111.7922668	0.46
113.9441681	0.36
121.7940979	3.86
127.9035263	6.35
130.3776245	0.08
136.9754028	100.00
137.8636475	0.26
139.9566956	22.87
141.8497314	0.07
147.0460815	0.22
150.2134705	0.22
151.9798889	0.11
154.2500153	0.13
157.9571228	17.50
166.2353363	0.21
174.0136261	1.30
175.9793091	34.51
178.0797729	0.82
187.9277039	1.36
192.0552673	0.35
193.9817505	0.20
196.1798096	0.07
202.0186615	0.10
203.0590057	0.20
206.1915283	0.07
207.0299377	0.72
220.1415100	5.92
222.0360718	0.68
224.1692200	3.36
230.3123474	0.29
232.1517944	0.34
236.2828674	0.17
238.1833191	8.11
242.1295471	0.09
246.1008301	0.22
247.9439697	0.10
250.1969604	3.14
252.1820068	46.83
253.2070618	0.07
256.1704712	4.55
258.1730042	0.13
258.9294434	0.10
264.4027710	0.15
266.2534485	8.52
267.2477417	0.18
268.2925720	0.61
269.8638916	0.22
276.3776855	0.48
284.2227783	68.50
294.1765137	5.08
298.1089783	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1123
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
127.0873718	0.14
142.6758118	0.09
145.8504333	0.19
148.0007477	0.25
149.1844482	0.17
149.8471527	0.07
166.9253387	0.10
180.0380707	0.03
184.9738312	0.34
193.2345886	0.04
209.7941284	0.04
212.7817078	0.03
249.1564026	0.05
268.1419067	0.12
271.1290588	0.47
275.0632935	0.08
276.0488586	0.02
283.1538086	1.53
294.9918518	1.13
297.6221313	0.04
299.2304993	0.06
300.2791443	0.10
301.2632446	0.03
307.2238770	0.06
311.0975342	0.12
313.1361084	25.63
313.8027344	0.14
316.7015076	0.03
319.3224487	0.04
326.9479370	0.08
337.1134644	28.98
342.9757385	0.38
343.5877686	0.10
349.2307739	0.40
351.0760193	0.32
352.2250366	0.03
355.2467041	0.29
359.7380676	0.06
361.2486877	0.51
367.1297607	50.54
367.7560730	0.10
369.0674744	0.52
371.3016968	0.03
372.5263977	0.04
374.3080139	0.02
376.8037415	0.06
379.1095886	15.67
379.7567444	0.04
383.5317383	0.10
386.8548279	0.07
389.1839294	0.08
391.3545532	0.04
397.1455994	28.34
398.7054138	0.11
401.1468506	0.03
403.3273010	0.02
405.6993103	0.05
415.1393738	100.00
416.3506775	0.11
419.2030945	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.26
Annotation	Unknow
Peak:m/z	Relative Intensity
184.9838867	0.29
206.9799500	0.52
231.1016235	0.44
232.5963745	0.62
233.2227020	1.03
262.1674194	0.16
263.2435303	0.13
281.3679199	0.37
321.2683411	0.68
326.1753540	0.52
344.0672607	0.15
349.3117676	0.84
350.2795715	0.18
351.0721436	0.11
356.6738281	1.43
357.3572388	2.57
358.4985962	0.30
365.2615356	0.31
368.2173767	0.22
381.1770325	3.23
381.8942261	1.36
382.5002136	0.84
392.1206360	0.79
392.8140869	1.27
395.3582153	1.31
397.1490784	3.95
397.9478455	3.64
399.3086243	0.12
406.3448181	15.15
413.3139648	42.27
414.2833862	3.06
415.2341309	0.36
415.9765930	0.68
416.8276672	0.68
417.9277649	0.50
431.3578491	0.62
439.7884521	1.86
440.3929749	0.18
441.3636475	1.52
444.2582397	0.27
445.2846985	3.75
446.0444641	1.06
448.7392883	4.16
449.4044800	1.29
451.4708557	0.52
452.4204712	0.38
512.2865601	0.79
549.2089844	0.78
553.1152344	0.86
565.8081665	0.63
567.7527466	0.34
586.6499023	0.26
599.6210327	0.50
600.3442993	0.59
664.3978882	5.14
665.3782959	3.52
680.3842773	1.84
681.6964111	0.94
694.2002563	1.94
694.9951782	2.39
695.6441650	1.77
698.2954712	2.46
699.5207520	2.26
712.4238892	13.68
713.5247192	2.88
761.5280762	0.69
793.3843994	2.73
794.4364624	0.54
807.3852539	0.91
808.7858887	0.73
811.4479370	100.00
812.6501465	45.56
813.6854858	0.39
825.5765991	12.18
826.6454468	6.17
827.5496216	3.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Malvidin 3-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
205.3295746	0.05
213.2506561	0.07
229.9978333	0.15
242.0058594	0.03
247.3759613	0.10
256.7276001	0.03
261.2658691	0.20
268.8954773	0.04
273.0531616	0.05
285.1693726	0.07
286.2568359	0.15
287.2637939	0.39
289.0511475	0.04
298.2630005	0.20
301.2085266	1.76
302.4143372	4.67
303.1029663	70.18
304.0142212	0.20
313.2853394	1.04
314.3464661	0.87
316.1655884	0.07
325.0074463	1.36
326.1671143	1.25
327.1101685	0.20
328.1786499	0.11
337.9801025	0.11
343.1048584	4.04
344.1400146	5.96
345.1000366	2.05
360.1937256	0.05
361.5970459	0.76
362.5155029	0.48
363.2268677	0.16
367.1986084	0.98
368.2326660	2.48
369.2349854	0.58
370.0563965	0.04
373.2028809	0.10
386.0750122	0.22
387.0039673	0.29
391.4774170	0.11
397.1662598	0.96
398.1064453	2.02
399.1765137	1.27
403.0886841	0.03
405.1804199	0.05
406.2073364	0.18
409.1689453	0.48
410.1784058	2.37
411.2127075	0.66
412.1920166	0.09
413.1596069	0.10
427.1132202	1.01
428.2109985	3.93
429.2269287	0.96
431.0014038	0.31
434.2824097	0.04
436.2261963	0.10
440.1276855	0.06
441.0297852	0.19
445.2950439	8.61
446.2097778	17.94
447.3192139	4.95
448.1990356	0.24
449.0562134	1.10
454.1968994	0.31
455.5336914	0.14
458.3687134	0.06
461.4860229	0.04
463.1917114	29.06
464.2126465	100.00
465.2457886	30.94
470.8345337	0.22
472.2738647	0.45
473.4346924	0.16
474.0717773	0.09
478.3837280	0.44
483.1500854	0.04
488.1889648	0.44
489.1298218	0.16
490.2435913	0.80
491.3075562	0.29
492.3901367	0.11
495.8558960	0.07
503.7192993	0.16
506.5153809	0.05
512.2437134	0.18
520.4259644	0.30
526.0490112	0.03
527.1641846	0.04
530.1380005	0.13
538.4002075	0.16
545.1974487	0.05
546.5179443	0.08
548.1817017	0.08
551.4622803	0.07
553.4335327	0.07
556.2773438	1.02
557.3486328	0.72
561.4420776	0.20
564.4262085	0.12
567.2929077	0.03
569.2678223	0.04
574.2431030	0.65
575.2831421	0.22
592.2666626	2.02
593.2892456	0.95
593.9533691	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1111.2965
Annotation	Didmolamide B
Peak:m/z	Relative Intensity
358.9728088	0.03
527.4349365	0.05
631.2124023	0.04
648.8786621	0.10
649.6198730	0.03
751.3649902	0.03
1023.4799800	0.02
1097.6343990	0.03
1111.2084960	100.00
1112.3190920	13.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.2145
Annotation	Unknow
Peak:m/z	Relative Intensity
217.0481567	0.09
223.2073975	0.08
236.7913208	0.10
240.8010712	0.12
245.1228027	0.07
285.1708679	0.22
303.1411438	0.82
306.3266602	0.12
321.1767273	1.26
337.0362549	0.17
338.3595581	0.35
341.4318848	0.10
352.9813843	0.20
363.2488403	0.05
381.3547974	0.23
387.0677490	1.87
405.1933594	0.85
433.4031982	0.19
443.0271606	0.15
446.1259766	0.15
447.0946655	0.05
465.3082886	0.15
517.2464600	9.65
518.2542114	36.80
519.3744507	2.75
521.1607666	0.63
527.3409424	0.08
528.4570923	0.14
535.3865356	0.19
539.2477417	0.05
550.2768555	0.05
563.1658325	1.17
580.2842407	0.07
581.1172485	1.64
623.1843872	2.85
631.4929199	0.05
641.4548950	0.20
654.8323364	0.09
666.1991577	0.21
667.1475220	1.21
679.1193237	0.15
680.0519409	2.20
681.0258179	0.83
685.3638306	0.47
690.1546021	0.48
696.6755981	0.23
709.3399658	22.81
727.1948242	100.00
727.8430786	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.2254
Annotation	Troxerutin
Peak:m/z	Relative Intensity
215.1968231	0.00
217.0307312	0.05
218.0577698	0.01
227.1360779	0.01
235.1044312	0.02
245.4653778	0.01
253.2989502	0.00
259.1541443	0.04
267.0822449	0.00
269.2662964	0.04
270.8889160	0.04
271.5099182	0.00
279.1022949	0.04
280.4592896	0.02
285.3851013	0.01
287.1782227	0.64
288.2922363	0.06
294.2206116	0.01
297.1670532	0.09
298.1467285	0.01
311.2148743	0.07
313.2234497	0.09
313.9401245	0.01
315.1107483	0.24
316.0895691	0.03
318.1499023	0.01
328.9985962	0.05
329.6165161	0.02
330.5532227	0.02
332.3676147	0.03
335.3551331	0.01
337.1665039	0.01
339.1831360	1.69
340.3314819	0.23
341.1838989	0.04
343.2077637	0.02
350.5857239	0.01
353.4338379	0.01
357.1871338	1.40
358.2905273	0.33
359.1773071	0.14
360.2749023	0.01
363.1792603	0.06
364.2641602	0.01
371.3003540	0.06
380.6984253	0.03
395.3000488	0.03
397.9149170	0.09
399.3521729	0.05
400.3125000	0.02
405.1306152	0.02
407.4461060	0.01
415.3862305	0.05
416.2520752	0.01
417.3101196	0.07
423.3081055	0.20
424.3948975	0.01
425.2808838	0.00
429.6781006	0.02
433.2589111	0.01
434.5744019	0.01
440.1547241	0.00
441.2368774	0.23
442.1431885	0.03
443.3764038	0.08
444.0155640	0.01
453.1851196	0.01
457.2137451	0.05
459.3065796	0.08
460.2650757	0.04
461.3523560	0.03
463.4362793	0.01
467.3477173	0.00
475.2327881	0.16
476.3528442	0.06
477.2459106	0.31
478.4501343	0.01
483.4439697	0.00
501.0432739	0.01
505.4205322	0.01
517.6856689	0.02
519.1920166	0.04
524.9285278	0.01
535.1382446	0.00
547.3455200	0.01
559.9268188	0.03
562.3118286	0.01
570.7415771	0.01
577.3839722	0.07
579.4235229	0.34
580.4421997	0.09
586.2200317	0.01
587.3695679	0.77
588.3817139	0.24
589.4707642	0.04
590.3822632	0.01
595.4489136	0.44
596.3463745	0.07
597.1024780	0.01
603.5661011	0.02
605.3106079	100.00
606.2770996	21.05
606.9279785	0.04
615.3594360	0.14
619.3378906	0.29
620.6395874	0.06
621.3474731	0.08
631.3566284	0.07
638.4599609	0.01
647.2749634	0.03
663.3292847	0.01
697.4011841	0.03
705.3309937	0.11
706.3197632	0.01
723.3764648	1.33
724.4121704	0.35
742.3666992	17.41
743.0923462	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1749
Annotation	Rhamnocitrin 3-glucosyl-(1->2)-galactoside
Peak:m/z	Relative Intensity
188.8650818	0.16
210.8906708	0.06
239.9426575	0.15
257.9968262	0.12
271.1419067	0.39
273.0222168	0.09
275.2848511	0.21
286.4544067	0.45
290.3848267	0.07
299.3454590	0.41
300.1029053	0.10
301.1231079	3.30
302.0742188	1.12
303.2379761	0.38
313.1881104	0.33
315.1025085	0.06
317.0924072	100.00
318.0250854	0.24
325.0558777	0.23
327.8698120	0.18
331.2794189	0.11
343.1687012	0.06
354.9017334	0.49
358.9622192	1.11
373.4387817	0.61
375.4421387	0.22
376.2140503	0.09
380.6111450	0.09
383.2852783	0.13
397.1863403	0.81
401.7252808	0.35
402.4008179	0.22
409.3023682	0.52
439.1137695	0.28
449.4509277	0.25
456.0793457	0.33
459.3818359	0.38
461.1467285	1.49
462.3362427	0.39
463.2189331	2.58
466.3889771	0.15
467.5617676	0.26
475.2595215	1.97
479.1234131	64.15
487.3235474	2.82
493.2025757	1.43
505.1087036	0.30
507.3621826	0.10
511.1770630	0.31
528.4356079	0.08
529.3248901	0.69
539.8568726	0.35
541.1296997	2.44
542.9083252	0.16
553.2203979	0.43
559.3298340	0.99
560.9570923	0.23
570.9407349	1.10
571.5571289	0.60
580.3406372	0.10
589.1445923	2.28
605.2152100	0.72
606.5145874	1.52
607.3307495	5.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	369.1767
Annotation	Unknow
Peak:m/z	Relative Intensity
113.1109924	0.03
125.1126709	0.02
161.0651245	0.23
163.2060547	0.01
178.8637390	0.06
180.1847382	0.01
189.0998077	0.07
190.2487793	0.03
195.1439972	0.10
202.9907074	0.02
207.4461670	0.04
225.1646118	0.02
249.1870117	0.03
251.3200989	0.03
263.2163391	0.04
264.3050537	0.06
265.3188782	0.08
268.9329529	0.02
279.0998840	0.07
280.1400757	0.06
287.8009644	0.02
290.7985535	0.05
291.4704895	0.03
293.1621704	0.01
294.1067505	0.02
304.1006165	0.03
305.1513062	0.06
309.0278931	0.04
321.2137756	0.01
323.1707153	100.00
324.8178406	0.03
328.1554565	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1030.5189
Annotation	Dehydrotomatine
Peak:m/z	Relative Intensity
306.4985352	0.03
657.5643311	0.06
781.1568604	0.04
968.7882080	0.12
1012.5891110	0.03
1030.4576420	100.00
1031.1878660	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	681.2012
Annotation	Unknow
Peak:m/z	Relative Intensity
199.0720520	0.02
202.3494873	0.01
216.1669312	0.02
226.9478149	0.06
230.2274475	0.02
240.3940582	0.02
241.0937500	0.04
252.2846527	0.01
255.9433136	0.02
258.3738403	0.02
270.9352417	0.04
285.1732178	0.01
289.1428528	0.01
298.7208557	0.09
301.2343750	0.04
302.3953247	0.01
313.2568359	0.25
314.1937866	0.35
317.3006592	0.05
327.1458740	2.13
331.2659912	0.03
342.0963745	1.21
343.2548828	0.03
345.1163940	4.77
351.2597046	0.01
357.2281494	0.04
359.1225586	0.19
360.2413940	2.41
361.2463989	0.06
369.6119385	0.04
375.1510010	100.00
375.8524780	0.11
393.0626831	0.04
395.3447266	0.11
396.1738281	0.02
409.0576172	0.10
412.0553589	0.05
416.9678955	0.04
421.3294067	0.05
426.5430908	0.02
428.0577393	0.17
457.2922974	0.01
481.3095093	0.01
494.5254517	0.01
519.4939575	0.03
525.4537964	0.09
537.1512451	0.13
543.2158203	0.03
576.4426880	0.02
613.6075439	0.06
619.2567139	0.41
630.4188232	0.02
637.5474243	0.03
645.2393188	0.26
648.6423950	0.04
652.5053101	0.02
663.2029419	0.34
681.2438354	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	297.1191
Annotation	8-Oxodeoxycoformycin
Peak:m/z	Relative Intensity
86.7561340	0.11
101.0434799	0.40
113.1241455	0.27
113.8504486	0.15
116.8989716	1.52
131.0657654	0.12
160.9204865	1.52
174.8045349	0.24
179.0460510	0.09
187.0589905	0.15
196.7998505	0.38
203.1147156	0.08
222.7691040	0.17
235.3719177	0.17
251.1848755	100.00
251.9785156	0.05
253.1680908	0.75
265.3417358	0.16
270.5054626	0.09
279.3433228	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	967.41
Annotation	Cys-Asp-Pro-Gly-Tyr-Ile-Gly-Ser-Arg 
Peak:m/z	Relative Intensity
931.0610352	7.61
967.4454956	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.2482
Annotation	4-[N-(p-Coumaroyl)serotonin-4''-yl]-N-feruloylserotonin
Peak:m/z	Relative Intensity
231.3067322	0.47
246.1471100	0.24
259.1524048	0.53
283.1860352	0.27
287.1940918	0.24
288.8649597	0.37
294.5726318	1.07
311.3026733	0.18
312.1891479	0.56
313.7683716	0.66
315.2770996	0.93
316.2225952	0.17
325.9902344	0.64
326.6938477	0.44
329.4880371	6.42
330.2674561	2.24
330.9684448	0.23
344.1284790	7.94
345.2073975	12.04
346.2526245	0.74
353.3245239	0.47
359.1372681	14.80
360.9351196	0.62
372.8699341	0.58
401.4009399	0.85
409.6738281	0.76
446.7647705	0.46
459.2990723	0.15
460.0853271	1.12
471.3424072	0.10
487.6229858	0.36
488.2348022	0.34
489.5244141	0.28
491.3869629	0.12
502.2225342	0.74
505.1915894	0.67
506.6074219	0.48
508.1437378	5.44
508.8876343	0.97
509.7392578	2.26
572.4467163	0.37
575.4155884	4.02
579.6766968	0.20
593.3156738	12.12
595.2084351	0.76
598.5922241	0.15
605.4044800	0.20
609.0405884	0.25
611.4407349	0.63
617.4038086	100.00
618.0042114	0.24
625.6389771	0.52
627.2947998	1.19
629.6458130	0.54
635.3009644	11.98
638.5751953	0.29
639.4536133	1.12
643.2993164	0.38
651.2094116	0.55
653.2996826	1.55
656.2407837	4.99
671.4241943	11.96
672.6027832	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1169.2979
Annotation	Unknow
Peak:m/z	Relative Intensity
345.3403931	0.05
360.1036072	0.08
563.3209839	0.10
1170.1901860	100.00
1171.2324220	30.80
1172.0141600	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
128.9228210	24.02
212.7992554	12.42
260.7858276	0.17
269.3372803	0.21
296.7412109	100.00
363.1536560	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	787.2244
Annotation	Isorhamnetin 3-rhamnosyl-(1->2)-galactoside-7-glucoside
Peak:m/z	Relative Intensity
336.9562378	0.12
348.1337280	0.05
355.1279297	0.08
367.2075195	0.59
379.5863037	0.12
385.3355713	0.59
395.3233032	0.07
409.2947388	0.80
421.2536011	0.21
433.2882080	0.18
439.3105469	1.24
440.1444702	0.11
445.2565308	0.05
451.2551270	0.60
457.3358765	0.51
469.2205811	0.83
487.2454224	6.01
499.2247925	0.10
504.3417969	0.18
505.4046021	0.80
511.2485962	1.73
511.8740234	0.02
515.2830200	0.04
517.2108154	0.35
523.2387085	0.26
525.4404297	0.05
529.1548462	0.42
541.3527832	1.91
547.0934448	0.54
553.2916870	1.87
559.3158569	0.90
571.1660156	3.07
571.8594360	0.08
583.3642578	0.15
589.2348022	3.59
601.1766357	1.93
601.9741821	0.14
607.2721558	4.67
613.1874390	1.06
619.2561035	2.09
625.2015991	0.27
631.2722168	2.52
637.3869019	1.15
639.2666626	0.10
649.2184448	37.30
649.8712158	0.20
655.4846802	0.05
667.2529907	10.59
673.2576904	6.08
685.3609009	0.16
691.3357544	5.88
697.3208618	0.20
702.7334595	0.24
703.3527222	12.46
709.1980591	0.05
711.0851440	0.14
715.2834473	6.05
721.2958984	6.80
733.2481689	7.93
751.2041626	22.58
751.8106689	0.97
769.2786255	36.28
787.1982422	100.00
787.8468018	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	801.2429
Annotation	Malvidin 3-rutinoside-5-glucoside
Peak:m/z	Relative Intensity
245.0096741	1.49
257.3552246	0.23
273.0076294	1.03
285.4246216	0.34
288.0974731	0.51
292.3369751	0.18
301.1078491	1.18
316.1138000	20.30
316.7667847	0.50
331.2056580	100.00
332.0279541	1.53
333.0770264	0.14
343.4249878	0.92
344.3027954	0.31
373.0530396	2.43
374.1874390	3.54
375.2222290	0.69
394.2088623	0.28
397.2150269	1.19
398.4604492	0.60
426.9938354	0.65
428.1131592	2.35
429.3750000	0.49
439.1143188	0.61
440.0731812	1.62
441.2050781	0.74
457.2020264	1.01
458.2063599	0.64
459.1710205	0.10
475.2423706	5.29
476.2257690	3.00
477.3242188	1.22
491.7449341	0.90
493.1749878	69.60
494.1935425	0.78
518.6300049	0.17
535.3234253	0.70
553.4033203	0.49
602.5982056	0.20
635.0374146	0.18
639.2195435	3.71
645.2018433	0.61
650.0496826	0.63
651.0541382	0.57
655.1532593	51.75
680.1533203	10.60
681.3036499	5.03
698.3085327	0.29
703.1954346	0.34
704.1997070	2.98
705.1264038	2.27
717.5316162	0.24
728.2830200	0.32
729.3593140	0.83
733.3473511	1.99
734.2401123	16.90
735.3447876	5.72
746.2340698	5.90
747.2380981	2.38
764.3240967	5.85
765.3289185	1.01
782.2828979	35.97
783.4069214	19.57
784.7389526	0.18
801.1760864	33.26
802.0326538	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	753.2252
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
211.1947327	0.02
213.0672760	0.01
215.0848694	0.10
218.1577759	0.02
224.2298279	0.17
225.1920776	0.01
227.1538544	0.24
229.8029633	0.03
232.3319092	0.01
232.9568176	0.03
235.8877106	0.01
238.2974243	0.02
240.0590057	0.09
241.0509644	0.12
242.0716858	0.47
243.0982971	0.01
249.1527405	0.04
255.2387848	0.07
257.1184082	0.23
257.9939575	0.06
259.5682983	0.03
263.1094971	0.01
265.0870972	0.01
265.8800964	0.02
267.3316956	0.03
268.0485535	0.20
269.1603699	0.07
271.9378357	0.04
278.8825684	0.02
282.1401978	0.09
283.2208862	0.57
284.1813965	0.17
285.2486267	0.37
286.1791687	0.53
293.2074585	0.01
299.0827637	0.77
300.0702820	0.48
301.1608887	18.34
301.9278564	0.01
307.0594788	0.07
307.8859253	0.03
310.2452087	0.06
313.2320557	0.05
315.0505066	0.03
321.2333069	0.02
322.3845215	0.01
323.1957703	0.02
325.2496948	0.85
327.2550659	0.08
328.2921753	0.01
331.4335938	0.05
336.6406860	0.01
339.2866211	0.02
340.0617676	0.07
341.2229919	0.17
342.2126465	0.02
343.2739258	0.79
345.1929321	0.03
349.1926270	0.04
353.2200928	0.01
355.1882324	0.24
357.1437988	0.08
365.3890991	0.04
367.1441040	0.20
369.5702515	0.03
373.3107910	0.03
380.9720459	0.03
385.4204712	0.03
393.2563477	0.01
409.2284546	0.06
427.0695190	0.02
429.1851196	0.12
447.2770386	0.26
447.9308472	0.01
449.4888916	0.05
455.0936890	0.01
459.1531982	0.08
463.1025391	0.03
471.1625977	0.13
474.5625610	0.05
489.1976929	3.21
489.8476562	0.03
513.7263184	0.01
523.4461670	0.02
531.6855469	0.02
541.6059570	0.01
561.1412964	0.01
573.0162964	0.03
576.1155396	0.03
577.2933350	0.32
587.4735107	0.03
590.4987183	0.23
591.2954712	0.58
592.3804321	0.02
593.6008301	0.12
595.4321899	0.04
605.2999268	0.67
607.3887329	0.02
608.7839355	0.16
609.5095825	0.83
611.4197388	0.03
619.4095459	0.07
629.0092163	0.04
631.4943237	0.50
633.3352661	0.03
637.5504150	0.01
667.4951782	0.01
687.4696655	0.02
695.4215698	0.06
696.5957642	0.03
705.8498535	0.02
722.1327515	0.06
724.2689819	0.02
737.4169312	0.92
738.4105225	0.03
739.2153931	0.02
740.4937134	0.59
742.1931152	0.02
755.3661499	100.00
756.3082886	1.96
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	667.19
Annotation	Mingjinianuronide B
Peak:m/z	Relative Intensity
215.1021576	0.12
221.8260651	0.07
247.0658417	0.08
274.9981689	0.04
305.1790771	0.16
317.1418457	0.07
331.0648193	1.40
332.1475220	0.20
346.1926880	5.51
347.0946655	1.11
361.2449951	44.75
403.2453003	0.14
413.4771118	0.18
471.3360596	0.11
485.2089844	0.06
491.0790405	0.24
505.3267822	0.56
506.2973633	0.23
507.8093262	0.06
509.2483521	1.53
523.2392578	100.00
523.8960571	0.76
549.9690552	0.17
551.1325684	2.18
551.8464966	0.15
561.3062134	0.14
565.2478638	48.50
565.8917236	0.19
590.3344116	0.36
591.5922241	0.36
593.2362671	0.07
603.4390259	0.21
605.3569946	13.23
617.3887329	0.60
621.4403076	0.26
622.1817017	0.05
624.2189331	0.11
633.5452271	0.12
634.4742432	0.06
649.1663208	0.32
652.4381714	0.16
667.2731934	3.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.1192
Annotation	3,4,5-Trimethoxyphenyl glucoside
Peak:m/z	Relative Intensity
99.0027771	0.07
100.8454590	0.12
112.8584595	0.28
116.7031250	0.05
118.6987839	0.19
130.8643799	0.07
137.3688202	0.04
143.0181274	0.50
149.1187439	0.03
161.1385193	0.05
165.2025146	0.05
178.8759155	0.67
181.0923309	0.38
182.0709229	0.25
183.0398407	0.34
191.0482178	0.12
192.1278687	0.15
193.9455719	0.08
205.0601349	0.06
206.7859192	0.06
209.3506775	0.05
215.0972595	0.03
222.6011047	0.15
225.3044739	0.10
241.9948425	0.18
257.2431335	0.05
260.4465942	0.03
280.9349365	0.07
283.0168762	0.36
285.2436218	0.04
288.9269409	0.07
299.1962280	100.00
300.3567200	0.03
301.1767578	0.08
302.4634094	0.14
317.2433167	0.10
327.1000977	0.29
329.0866089	1.09
329.9753418	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	466.2942
Annotation	PC(14:0/0:0)
Peak:m/z	Relative Intensity
135.0832825	0.08
139.9849854	0.14
150.9226227	0.04
152.9537048	0.02
184.1155548	0.09
196.0676575	1.31
213.9643860	0.73
229.1611633	0.03
241.1576996	0.08
269.2795715	100.00
271.2479858	0.07
285.4112549	0.02
302.0400696	0.03
347.3575439	0.07
401.5406799	0.02
403.5715942	0.09
405.3671875	0.10
419.1492004	0.16
421.8379517	0.12
423.8015747	0.02
431.2348328	0.10
433.4549255	0.04
439.1859741	0.04
447.4645691	0.48
448.2001953	0.36
449.3076782	2.56
450.6612549	0.13
451.7516174	0.06
467.2247009	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1622
Annotation	Safflomin A
Peak:m/z	Relative Intensity
171.0704803	0.07
181.1204071	0.15
190.8179626	0.05
192.8757629	0.12
197.2972870	0.42
207.0580444	0.14
209.0950623	15.12
221.1028748	1.19
223.1941223	0.24
233.1672363	0.23
237.1293030	0.10
239.1564331	14.63
247.1698914	0.05
251.0630188	0.85
265.1771240	0.18
269.1254883	9.64
275.1706543	0.25
277.1652222	2.42
281.1808472	0.58
285.1642456	0.59
287.3726501	0.06
289.0809937	0.21
293.1754761	1.13
299.1961060	0.24
303.1929932	0.42
307.1200562	1.60
309.2659302	0.11
311.1667480	6.38
313.2202148	0.09
319.3477783	0.05
323.2686768	0.42
329.1885986	7.17
336.9324951	0.94
341.2090454	6.96
349.3253174	0.14
353.0971680	0.62
359.2109375	3.22
371.1336670	100.00
371.7528687	0.12
379.2123413	0.36
383.1346436	3.35
383.7542725	0.73
391.0480347	0.10
395.1632080	0.12
397.2617188	1.01
401.1307983	69.05
401.7708740	0.31
402.4407349	0.14
409.4700317	0.14
413.2509155	4.84
415.0877075	0.10
427.2061768	0.64
431.2217407	20.89
437.2440186	0.10
443.1848145	0.99
449.3298950	5.45
455.2952881	1.46
457.0213013	0.11
459.4080811	0.09
461.3216553	0.55
466.9911499	0.06
467.6088257	0.35
473.2449951	25.05
485.2947388	3.03
487.2311401	0.22
491.2316895	70.87
503.2266846	15.69
515.2214966	0.24
521.2328491	7.99
545.2807007	0.08
547.1619263	0.25
556.6567993	0.29
557.4448853	0.08
566.3633423	1.75
575.2698364	3.46
593.2390137	14.68
593.8486938	0.24
611.0542603	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	665.19
Annotation	Unknow
Peak:m/z	Relative Intensity
186.9777679	0.07
189.0537567	3.43
189.8365631	0.05
190.6438751	0.04
193.0733032	5.01
199.7207031	0.18
202.0231323	1.78
210.8942566	0.10
216.9822845	1.62
218.0464935	0.32
232.9249725	3.70
234.2336121	0.07
243.0724487	0.74
247.0689087	0.10
251.0790710	0.40
255.1738434	0.16
257.2178955	0.14
259.0473022	0.15
261.0034180	4.39
276.8964844	0.94
287.0403137	1.13
295.0954285	0.67
296.0812378	0.18
298.3051758	0.09
300.1071777	0.17
301.1298828	0.78
305.1661987	3.93
308.1584473	0.12
311.4507446	0.60
313.3073730	0.07
313.9950562	0.10
315.3398438	0.07
319.2229004	0.07
323.0185547	0.49
329.1500244	2.64
330.2441406	1.33
341.1907959	0.03
342.0463867	0.06
343.0621948	1.12
344.1708374	14.62
345.3006592	2.64
349.0479736	1.87
354.4345703	0.07
357.3889771	0.45
358.1581421	1.07
359.2023926	45.63
360.1264648	0.04
365.1475220	0.07
367.1071167	0.40
368.1038208	0.05
369.0083008	0.04
371.1857300	0.48
372.0942993	0.08
373.1083374	0.32
381.1655273	0.13
386.1292725	0.17
386.9982910	0.12
401.1285400	5.49
402.8829346	0.08
410.4274292	0.30
419.2969971	0.36
425.4838867	0.08
427.0380859	1.56
429.1409302	0.12
433.2545776	0.07
450.3128052	0.06
463.4182129	0.12
465.4618530	0.05
467.3836670	0.10
470.8831787	4.64
471.5220947	0.18
484.9893799	0.32
488.1970825	0.15
489.0372925	0.99
490.3464966	0.04
491.5505981	0.07
498.7314453	0.33
499.4716797	0.12
502.5578003	0.19
503.2206421	1.74
506.2127075	1.34
507.2779541	2.65
511.3068237	0.60
521.2146606	100.00
521.8406982	0.20
526.6222534	0.08
534.3013916	0.54
543.0477905	2.31
548.6235962	0.79
549.2880859	4.91
558.8847046	0.04
561.1031494	0.10
563.2080688	60.71
577.2064819	0.17
578.3588257	0.38
589.2200317	1.01
589.8530884	0.16
591.3322144	0.15
591.9921265	0.05
600.5872192	0.04
603.3106689	2.72
605.3872681	0.19
615.3060913	2.71
617.3275757	0.09
620.5692749	0.21
621.2453003	0.21
623.4895020	0.09
632.3049316	0.08
633.3092041	0.88
642.5836792	0.16
646.2893677	0.45
647.5235596	0.47
648.9728394	0.11
650.6248779	0.13
665.1105347	7.98
666.2615967	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1439
Annotation	6-Hydroxyluteolin 7-[6''-(3-hydroxy-3-methylglutaryl)glucoside]
Peak:m/z	Relative Intensity
179.9333496	0.01
194.9783478	0.02
213.0966187	0.01
243.0970764	0.02
253.7959290	0.03
257.9252319	0.01
272.1643677	0.01
286.1520996	0.04
287.0816040	0.05
290.0626831	0.02
301.1394653	0.98
302.1904297	1.30
303.0601807	0.15
317.4306030	0.01
328.1719360	0.97
331.1829834	1.79
333.2664795	0.04
343.2990112	0.05
346.1741943	2.80
359.4747314	0.02
361.1709595	100.00
403.1938477	0.05
427.0795898	0.02
463.1378784	0.06
523.0494995	0.12
547.5865479	0.02
565.1461792	1.22
565.7525024	0.01
590.4895630	0.05
591.0901489	0.11
591.7254028	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.3151
Annotation	Unknow
Peak:m/z	Relative Intensity
168.0968933	0.01
224.0820160	0.08
235.9470520	0.02
242.1407013	0.08
255.1553650	0.01
259.5305481	0.03
277.2923889	6.06
278.2922363	0.14
279.3670654	0.20
298.9458313	0.04
329.4677734	0.02
347.1857910	0.06
368.2929077	0.07
382.4387207	0.01
400.3891602	0.03
411.5223999	0.09
413.0186768	0.11
431.3678589	0.03
502.3528442	100.00
503.3159790	0.20
513.9905396	0.07
515.3129883	0.22
534.7889404	0.03
544.3739624	0.03
549.7507935	0.01
563.2510376	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1623
Annotation	Butrin
Peak:m/z	Relative Intensity
199.1631317	0.04
209.2224121	0.04
216.8806152	0.07
219.3952942	0.05
221.1911621	0.09
228.9047852	0.04
232.9408264	0.04
244.9623718	0.07
251.1468506	0.10
256.1343079	0.05
257.1028442	0.02
261.1948547	0.03
268.0705261	0.03
271.2507324	0.02
272.3716125	0.06
277.0911560	0.03
293.3101807	0.03
297.9369507	0.05
299.0804443	0.23
303.2151184	0.06
305.2086182	0.02
306.2433472	0.09
307.8623352	0.03
312.1649170	0.92
314.4710693	0.15
315.3682251	0.62
316.3788452	0.07
317.4201660	0.12
327.2720337	0.12
338.0912476	0.08
339.3558960	0.06
341.2248535	1.04
351.0117188	0.18
352.2462769	0.07
354.5285034	0.26
355.2873535	0.42
357.2462769	0.18
361.3361206	0.03
363.4765015	0.12
365.0880737	0.25
367.9436035	0.10
369.3942871	0.06
370.2027588	0.09
371.1506348	0.14
375.3020020	0.08
379.3090210	0.05
381.0786743	0.18
383.1870117	50.80
385.1544189	0.05
387.1494141	0.05
393.4498291	0.03
395.1970825	1.37
397.3056030	0.13
398.0958862	0.06
401.1995239	0.06
407.2643433	0.18
409.3268433	0.23
410.1798706	0.06
413.2252197	22.33
421.3345337	0.06
423.2381592	0.04
425.2121582	1.82
427.3263550	0.86
431.4321899	0.10
436.9716187	0.10
439.1629028	0.28
441.1480103	0.16
443.2575684	2.56
444.4406128	0.07
449.3773804	0.43
455.3338013	2.02
457.0273438	0.15
459.3717041	0.06
460.2236328	0.04
461.2188721	0.59
467.2363892	1.85
469.0153198	0.05
472.9889526	0.13
475.4431763	0.16
477.4359131	0.36
478.1937866	0.23
479.4006958	0.53
482.9559326	0.05
485.2167358	3.87
487.3353271	0.15
489.2302856	0.09
491.2355347	0.08
492.2801514	0.06
493.4814453	0.04
497.3968506	0.05
501.2305908	0.23
503.2229614	100.00
503.8414307	0.29
511.1734009	0.02
513.0903320	0.09
515.1808472	1.34
516.1782227	0.13
518.5375366	0.07
520.1694946	0.42
521.1736450	0.07
527.1337891	0.11
529.3389282	0.03
531.4815063	0.05
533.2039185	9.07
534.1782837	0.19
545.3226929	0.82
547.2124634	0.21
549.1323853	0.05
557.4308472	0.04
559.1955566	0.03
560.4529419	0.32
561.2556152	0.24
563.2551880	1.05
569.6810913	0.10
575.1754761	1.00
576.5873413	0.03
577.5780640	0.04
578.5661621	0.39
587.1674194	0.40
593.0902100	0.04
594.0208130	0.15
595.3499146	0.16
603.6545410	0.12
605.3720703	3.90
608.0126343	0.13
623.2639771	1.48
624.2694702	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	831.232
Annotation	Uroporphyrin IV
Peak:m/z	Relative Intensity
255.0140991	0.06
272.0850220	0.06
291.1824646	1.01
292.2864990	0.22
301.0674438	0.21
303.2284241	0.08
309.0971375	0.65
313.3408203	0.11
316.2822266	0.16
328.1740723	1.52
329.1451721	0.10
331.0820618	4.08
332.0633850	0.72
342.7208252	0.10
344.3603821	0.03
346.0729370	1.97
347.0549316	0.32
361.1639709	72.08
362.1154785	6.17
362.9970093	0.11
387.1389160	0.32
488.4050293	0.05
490.1093750	0.14
523.0523071	0.82
524.3629150	0.23
525.3661499	0.05
553.2214966	0.08
553.8281250	0.13
597.1967163	0.03
625.8298950	0.06
657.4497681	0.03
669.1547241	100.00
670.2622681	6.93
684.3805542	0.16
711.2100220	0.08
725.9030762	0.04
748.5023804	0.16
759.3661499	0.22
787.4317627	0.11
812.5380859	0.06
813.8048706	0.06
832.1293945	50.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9051819	2.73
218.9162140	0.28
242.1951294	1.07
296.1317749	2.37
296.7920227	26.35
302.7747192	0.17
316.2025757	0.24
334.3206177	0.45
357.0683594	0.23
359.0360107	0.30
378.2402344	0.14
380.5761108	100.00
381.2384033	2.87
382.9054565	0.74
386.4058228	1.37
387.0372925	3.90
404.5934448	1.10
412.6397705	0.13
424.8160400	3.99
428.7302246	1.69
463.9448242	19.26
464.5543823	94.62
465.1928711	0.53
466.8578491	6.61
470.0161133	1.84
470.6718140	2.14
484.6221313	0.64
496.8101807	5.95
507.8702393	0.34
512.4661255	2.73
526.5247192	2.96
538.7688599	0.34
541.9448853	0.72
546.1619873	0.40
548.4096680	58.04
549.3518677	0.20
556.3882446	0.63
567.8521729	0.33
569.0584106	0.86
572.6273193	1.00
585.8567505	0.16
586.6353760	0.69
632.4978638	2.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1642
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
197.1794586	0.02
198.0986938	0.02
235.9827881	0.09
237.2002563	0.01
248.0263367	0.01
283.1232910	0.10
287.3086548	0.14
295.1201172	0.02
299.0697021	0.94
311.2420044	0.32
313.1721191	0.46
325.1732788	0.06
327.2566528	0.17
329.0930176	6.53
337.1367798	0.17
346.1167603	0.02
353.2438965	2.88
355.1862793	0.21
365.5983276	0.01
367.2094727	0.38
377.0622559	0.13
379.1500244	0.55
383.1648560	6.37
395.1671143	2.29
397.1997681	0.10
409.2534790	0.40
413.2125854	2.57
415.2137451	1.48
421.0567627	0.04
427.2911987	0.17
429.5320435	0.05
431.1342773	21.25
431.9256592	0.02
433.2603760	2.27
439.0073242	0.23
441.3451538	0.01
445.2496948	0.10
449.1508179	100.00
449.7704468	0.39
455.2360840	0.03
457.1533203	4.76
457.7590332	0.03
463.1641235	0.04
473.2993164	0.03
475.2343140	1.80
481.1953125	0.87
487.3344116	0.01
499.0521851	0.75
499.6830444	0.02
505.2731934	0.15
507.6536865	0.10
511.2198486	1.80
523.3506470	0.89
529.2248535	2.41
541.2324219	1.62
542.0130005	0.01
554.0759277	0.09
559.1655273	4.43
559.7983398	0.04
577.1648560	13.01
577.8531494	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.2473
Annotation	Unknow
Peak:m/z	Relative Intensity
245.2031097	0.01
247.2036743	0.09
261.3997192	0.03
265.1932678	0.06
283.1795044	0.10
287.2599792	0.01
290.1291504	0.03
304.8116150	0.02
306.2254333	0.04
317.9276123	0.01
321.2128906	0.09
322.2114868	0.04
331.0410156	0.04
337.1995239	0.01
339.5336914	0.05
340.2869873	0.01
341.0338745	0.03
359.1032104	0.06
377.3430176	0.02
379.2379150	0.20
381.0079956	0.04
382.4100342	0.02
391.4043579	0.03
397.2159424	0.06
401.4288330	0.01
415.2042847	0.07
431.0639648	0.02
449.4279785	0.08
451.4124146	0.02
454.3137817	0.06
476.5485840	0.04
481.2261963	0.08
493.4122925	0.02
505.0783081	0.02
507.2698364	0.05
508.1357422	0.01
511.6893921	0.01
513.2009277	0.04
514.3911743	0.02
515.2199707	0.02
522.7485962	0.02
526.4203491	0.04
528.8328247	0.02
533.2049561	0.01
536.3773804	0.04
552.3169556	0.01
556.1962280	0.01
567.2471924	0.12
568.2908936	0.28
569.3973999	0.01
585.3372192	0.10
586.3732300	0.19
587.2960205	0.05
596.2875366	0.01
597.1885376	0.01
603.9041138	0.06
614.5285034	0.04
615.4265747	0.03
628.1925049	0.20
631.3609009	0.02
640.3139648	0.06
643.4890747	0.24
645.7144165	0.35
646.3717041	0.36
657.3604126	0.05
658.1075439	0.21
661.4386597	0.26
668.4445801	0.08
675.6339722	0.06
687.3367310	0.13
688.4878540	0.02
698.2949829	0.01
699.5190430	0.29
700.2571411	1.94
701.4043579	0.24
705.4666138	0.09
717.1953125	0.16
718.3533325	2.40
719.4415894	2.01
737.3514404	1.14
738.0292969	0.04
747.3234863	0.22
748.2814331	0.04
779.3555298	100.00
780.4102173	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.87879181	0.48
80.44389343	0.21
90.95761108	0.67
95.01629639	0.92
102.9717102	1.78
103.8406982	0.40
104.9901276	0.44
105.6477814	0.15
106.9054718	1.02
114.9320984	0.95
119.0211182	0.86
120.0139923	0.17
122.984848	0.82
128.9498291	9.24
129.9060669	1.74
130.9080353	1.08
133.005249	0.54
140.9701843	1.56
142.1308136	0.15
142.7728119	0.19
144.8766327	0.36
147.0479736	0.26
150.9307709	100.00
151.9252472	15.42
153.8147125	0.27
154.8897247	0.70
155.9360809	0.21
156.9447937	1.28
158.2701416	0.13
165.0046997	1.87
166.0899506	0.19
166.9037018	2.69
168.0939331	0.54
168.9785614	1.26
169.9703674	0.26
171.0400085	0.30
174.9767303	0.74
178.337738	1.08
179.0788422	3.30
181.214859	0.15
182.0546417	1.92
182.9825287	0.23
185.0840149	3.81
186.3122101	0.24
193.9567719	0.48
194.66539	0.42
197.0971832	5.86
198.2172394	0.40
205.9369812	0.20
207.1116486	0.46
209.6692657	0.80
211.0700226	0.69
223.0679932	0.36
224.1358795	0.84
225.0363007	11.69
226.1191406	2.33
235.9337158	0.40
238.0261841	19.51
239.0422363	4.94
240.2411346	0.45
251.2559967	3.83
253.0861816	71.11
254.0326691	14.60
255.1824188	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1825
Annotation	Hesperidin
Peak:m/z	Relative Intensity
173.9395752	0.21
174.8761902	0.04
176.1365204	0.08
177.1203766	0.08
179.0415649	0.12
184.2331238	0.03
187.1335449	0.23
188.2299194	0.10
188.9884949	0.14
191.0473633	0.04
193.0757751	0.30
195.422699	0.05
198.3918304	0.32
199.089859	1.30
200.5536957	0.15
201.1699524	0.63
206.1426544	0.14
208.1923676	0.07
209.1817017	0.12
211.276474	0.12
213.1204071	0.32
214.1377716	0.17
215.1076965	0.91
215.9531097	0.33
217.0513916	0.15
218.2885895	0.18
221.1609802	0.12
223.2582703	0.18
224.0540161	0.20
225.196106	0.02
227.0431824	0.97
230.0667725	0.04
233.3040619	0.43
235.1351471	0.35
239.164917	0.16
240.0766602	0.53
241.1311188	0.80
242.0938416	2.56
243.1735687	0.03
249.1256409	0.10
251.1881714	0.06
254.0870514	0.11
255.3048248	0.16
257.0112305	1.34
258.0265198	0.45
259.0810852	0.07
260.1046143	0.14
264.2756653	0.16
265.2960815	0.08
267.0952148	0.10
268.1380005	0.99
269.2304993	0.13
271.5541077	0.05
279.1208191	0.05
281.119812	0.02
282.1165771	0.44
283.1438599	1.81
284.1937256	0.55
285.1577759	1.74
286.0896606	2.50
292.057312	0.06
292.9181519	0.10
295.0424194	0.02
296.0916748	0.04
297.1871643	0.14
299.1077271	2.40
301.0819702	100.00
301.9584351	0.61
307.1008301	0.87
309.1313477	0.27
310.1645508	0.42
311.3831787	0.06
313.3866272	0.04
315.3032227	2.15
319.1231079	0.13
321.2778625	0.07
322.3028564	0.05
323.8601685	0.15
325.2046509	8.84
325.9362793	0.05
327.2109985	0.09
328.3411255	0.27
331.1229248	0.02
334.1358643	0.03
337.2567139	0.23
339.1834717	0.47
340.4047241	0.37
341.2463989	0.38
342.5231323	0.63
343.2090454	10.84
344.2006226	0.12
349.3287354	0.17
352.5081177	0.13
353.3468018	0.05
355.0741577	1.60
355.6846924	0.02
357.24646	0.21
358.9293213	0.27
361.2992554	0.03
367.180481	2.28
370.1849365	0.03
371.4058838	0.07
373.2897949	0.20
381.3994751	0.14
385.1634521	1.67
393.3256226	0.02
397.5467529	0.12
403.1532593	1.57
409.1635742	0.25
415.2047119	0.26
427.0700684	0.35
429.2771606	1.13
433.2547607	0.54
441.1766968	0.15
443.3656006	0.54
444.3168945	0.56
445.2987671	0.40
447.2277222	1.76
459.2125854	2.30
461.2113647	0.08
463.3325806	1.07
464.1906128	0.10
465.3796997	0.24
469.2910156	0.05
471.1810913	0.10
473.1332397	0.17
477.3884277	0.03
485.5162354	0.03
489.269043	11.04
491.2926636	0.18
493.4108887	0.26
503.6461792	0.04
506.7837524	0.14
516.4732056	0.03
518.1557007	0.12
519.4050903	0.08
527.0421753	0.10
541.3175049	0.03
547.5462036	0.06
550.5075684	0.12
562.1856079	0.59
563.0144043	0.03
565.0114746	0.08
572.0773315	0.08
576.284668	0.26
591.2896118	1.05
594.2841187	1.56
608.9873657	0.07
610.5062866	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1023.5251
Annotation	Unknow
Peak:m/z	Relative Intensity
372.1910400	0.21
699.5111084	0.78
701.2015381	0.30
861.5078125	0.40
885.6109619	0.33
902.6458740	0.09
1023.4954830	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0827
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
119.9458923	0.04
136.9495850	20.51
148.9516296	0.03
167.8354797	0.18
183.0851440	0.95
190.9732666	0.01
192.8564453	0.08
198.9029846	0.03
206.0349884	0.03
209.2317505	0.02
215.0066223	0.03
228.2723083	0.03
253.4021301	0.08
270.8865967	0.04
283.1836548	0.02
283.9699097	0.02
287.2734375	0.07
299.0782471	100.00
301.2285156	0.19
302.0601196	0.04
309.1063232	0.02
315.3944092	0.01
329.2023621	0.18
330.2793579	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	911.4907
Annotation	Ardisiamamilloside H
Peak:m/z	Relative Intensity
260.5772095	0.03
292.3564758	0.18
310.5338440	0.05
334.4939270	0.18
335.2557068	0.04
352.1912231	0.06
414.2025146	0.25
459.2741699	0.03
474.1705933	0.04
478.3801270	0.11
489.2337036	0.09
511.3168945	0.05
532.4652100	0.09
538.4424438	0.19
548.6147461	0.12
552.5114746	0.08
578.5946655	0.09
586.7740479	0.04
600.2352905	0.07
602.7379150	0.05
615.7140503	0.10
625.5634155	0.07
626.6741333	0.25
628.4622192	0.47
630.6745605	0.06
638.6058960	0.15
642.7952271	0.12
648.9782104	0.18
659.3234863	0.05
660.5725098	4.17
663.6923828	0.15
670.8126221	0.10
672.6080933	0.21
680.9339600	0.18
714.4973755	0.25
727.0097046	0.21
731.5438843	0.47
740.7460327	0.28
748.6638794	1.07
749.5297241	4.12
750.3914185	0.14
752.5903931	0.09
773.6565552	0.05
783.2548218	0.14
786.6123657	0.21
803.7509155	0.12
820.8228149	0.04
822.4531860	0.22
830.2244263	0.13
839.9088745	0.07
857.9415894	0.45
875.5545654	0.47
878.7843018	0.08
911.5642700	100.00
920.7538452	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	554.72
Annotation	Unknow
Peak:m/z	Relative Intensity
202.8492126	0.02
216.0899048	0.02
218.7817078	0.66
247.9107056	0.11
287.0037231	0.03
302.8834839	14.13
309.0286865	0.02
331.7852173	0.08
371.9686890	0.28
375.4050293	0.02
376.3374634	0.17
377.7656250	0.05
381.5865479	0.04
383.4358521	0.19
384.7636108	0.10
386.7944946	54.61
392.9192505	0.06
431.0792236	0.08
440.8938599	0.05
441.7203979	0.08
443.1357422	0.07
444.0242920	0.02
468.7464600	0.37
470.6157837	100.00
471.2728882	0.40
486.9453735	0.06
494.9799194	0.14
536.3895874	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	757.2151
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
228.1044006	0.17
242.0795288	0.06
252.4084320	0.14
256.0922546	0.14
271.0232544	5.78
287.1360474	0.87
310.9706726	0.27
325.3405762	0.49
329.1473694	1.86
334.8889771	0.06
337.2620239	0.65
348.7722778	0.20
353.0995789	0.33
355.1749878	0.22
367.3726807	0.47
379.3200073	0.24
383.0392456	0.25
385.4648438	0.23
391.3507080	0.44
395.0864868	0.43
407.2727051	0.09
409.2349854	2.19
413.4046021	0.11
422.3462524	0.31
427.0272217	1.09
431.2775879	2.14
433.1842651	3.26
438.9913940	0.17
445.4517822	0.06
449.1986694	5.34
457.2800293	7.14
460.6711426	0.06
461.2751465	0.43
472.8386230	0.74
475.2900391	3.38
477.2203369	0.21
481.2304688	0.63
491.2131348	8.09
493.2205811	0.42
496.8938599	0.17
497.5043945	0.08
498.9166870	0.54
511.2255859	3.67
515.3037720	4.13
523.1026001	1.38
523.7388306	0.17
527.2971802	0.30
529.2841797	1.94
541.3317261	1.76
545.2106323	15.11
546.2039185	0.23
557.1509399	3.10
559.2973633	4.01
575.2302856	3.79
577.3335571	6.49
586.8223267	0.25
589.0447388	0.09
591.5192261	0.32
593.2340088	48.65
593.8510132	0.33
595.1999512	9.93
600.8989868	0.91
607.0383911	0.25
609.0904541	0.35
611.2984009	100.00
619.2303467	3.88
620.1365356	0.49
625.1844482	0.28
635.3221436	0.52
637.2681274	4.98
643.6671143	0.47
661.3201294	0.70
672.6809082	0.21
673.4137573	0.22
685.3660278	0.38
691.1234741	2.42
703.2259521	1.73
703.8470459	0.20
712.5158691	0.09
721.2801514	3.95
737.3031006	0.24
739.1600952	14.73
740.0347290	0.14
756.7999268	1.23
757.4045410	5.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.2773
Annotation	Granaxylocarpin A
Peak:m/z	Relative Intensity
245.0926361	0.14
246.2718048	0.03
253.3635712	0.03
269.2471313	0.05
271.4700317	0.04
272.3723450	0.06
277.3594360	0.06
279.5562439	0.03
280.2981567	0.05
284.0697632	0.03
285.1801758	0.13
287.0160522	0.05
295.2899170	0.09
299.2678833	0.06
301.5806885	0.02
309.1233521	0.07
311.3328857	0.07
313.1954346	0.19
314.2679443	0.06
323.2050171	0.19
325.1674194	0.09
345.1734009	0.03
347.1356812	0.06
355.3247070	0.06
356.3730469	0.04
360.3940430	0.06
389.2670288	0.09
390.1142578	0.03
402.3863525	0.81
403.3309937	0.34
414.4180298	0.05
415.5228271	0.07
416.3742676	0.02
417.4291382	0.03
431.3152466	0.04
432.0372314	0.04
444.1452637	1.78
445.2388306	0.55
446.4880371	0.08
448.3339233	0.63
459.2738647	0.02
460.9453735	0.16
461.6781006	0.03
463.2792969	0.06
471.1884766	0.05
475.3224487	0.10
476.2921143	0.50
477.5950317	0.05
481.6423950	0.06
488.3023682	4.50
489.3810425	2.02
490.4324951	0.48
492.6406860	0.05
493.4270630	0.07
494.6228027	0.03
503.6348267	0.03
507.3500366	0.06
508.1638794	0.16
509.0017700	0.06
520.3031616	24.99
521.2437134	6.53
522.3144531	0.27
523.1102295	0.09
524.3934937	0.19
525.3193970	1.21
526.3877563	0.52
539.5890503	0.04
544.9764404	0.12
546.3016357	0.07
551.2660522	0.09
564.9200439	0.03
567.3878174	25.60
568.4047241	8.64
569.4960938	0.06
570.2654419	0.35
571.4280396	0.17
572.1963501	0.06
583.3130493	0.79
584.3786011	0.22
593.4162598	0.41
594.4807739	0.23
595.3223267	0.04
597.5913086	0.13
598.6077271	0.06
599.3466187	0.30
601.5668335	0.03
607.3430176	0.04
608.3608398	0.16
611.2907104	100.00
612.4112549	27.99
615.2612305	0.12
625.3984375	0.06
626.4732056	0.03
628.4588013	0.21
644.3219604	7.40
END