#DEFINITION	Reference Metabolome for Citrus limon
#IDENTTFIER	RefMeta-Citrus limon.R1
#FORMAT	msr
#VERSION	1.0/R1
#KEYWORDS	RefMeta
#ORGANISM	Citrus limon
#CREATION	31-MAY-2024
#PUBLICATION	CropMetabolome: a comprehensive metabolome database for major crops cross eight categories
#JOURNAL	The Plant Journal
#AUTHORS	Shi H, Wu X, Zhu Y, Chen P, Xu X, and Li X.
#COMMENT	Reference metabolome for Citrus limon was generated from multi-tissue LC-MS/MS data with redundance removed
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	636.19
Annotation	Unknow
Peak:m/z	Relative Intensity
222.2711487	0.15
251.6256409	0.06
259.0507507	0.03
264.0265503	0.09
292.2981262	0.33
293.9208679	0.39
317.1608887	0.08
322.5463867	0.06
324.1674194	0.19
340.8898315	0.92
342.1179199	0.51
346.2138672	0.08
355.0776367	0.03
383.2119141	0.54
383.8413696	0.05
384.4458008	0.15
393.1080322	0.11
414.0015259	0.53
429.1172485	0.14
435.0949097	0.11
442.9050293	0.58
444.1788940	1.04
453.0612183	0.05
482.8908691	0.08
503.4239502	42.44
504.2361450	100.00
590.1282349	0.15
618.1687012	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.14
Annotation	Limocitrin 7-(6''-acetylglucoside)
Peak:m/z	Relative Intensity
153.1557312	0.04
171.0942688	0.12
177.0253601	2.18
179.0123901	3.83
183.1307373	0.05
188.9367981	0.33
195.0225677	2.39
197.2731171	0.02
201.1017151	0.03
203.0568542	0.31
205.0303955	0.07
207.2351074	0.05
219.1918488	0.27
221.0135193	0.03
229.4116669	0.03
231.0994110	0.07
233.5807190	0.07
238.1230469	0.02
242.9116516	0.03
247.0760498	0.05
255.9526672	0.02
257.3086243	0.06
261.0787354	0.36
262.8739014	0.03
265.0003357	0.15
266.9614868	0.07
277.1194458	0.05
279.2786865	0.11
285.1733398	1.29
287.0747681	0.16
295.7607727	0.02
297.0136719	0.02
298.3527222	0.28
301.0934753	0.90
303.0920410	100.00
304.3057861	0.37
309.2807007	0.04
319.3000488	0.03
320.6879883	0.12
327.1543579	6.68
339.1377563	0.01
340.2371216	0.02
343.4066772	0.07
345.1429443	18.12
347.2316284	7.97
351.1392212	0.05
352.3485718	0.06
354.0780029	0.14
357.1679688	0.03
362.0508423	0.04
365.1377563	0.82
369.1692505	6.80
376.2074585	0.09
379.0479736	0.09
379.8766479	0.02
381.1505127	0.45
383.1449585	3.61
388.9572144	0.05
391.2186890	0.21
393.1317749	1.15
399.6982422	0.01
400.9862671	1.29
405.1352539	0.03
409.2111206	0.08
411.1754150	11.68
412.3470459	0.10
425.2177734	0.09
428.9799194	0.44
430.3899536	0.17
439.1618652	0.06
446.3693848	0.22
447.1440430	0.05
452.9983521	0.33
457.1624756	0.13
464.5851440	0.33
465.2843018	0.87
470.3646851	0.03
471.0764771	0.44
473.4216309	0.09
475.9687500	0.03
478.8202515	0.25
489.0848999	0.12
491.1981201	0.25
497.0329590	1.13
504.8483276	0.12
505.4818726	0.04
506.7971802	0.37
507.4977417	0.09
515.1244507	14.19
518.9812012	0.25
530.4076538	0.04
533.1361694	38.82
557.9582520	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	544.1066
Annotation	Coenzyme M 7-mercaptoheptanoylthreonine-phosphate heterodisulfide
Peak:m/z	Relative Intensity
157.8895721	0.17
169.9252319	1.63
171.8622894	0.28
179.5547943	0.06
184.0123444	0.07
185.4344940	0.11
186.1103058	0.10
187.2065277	0.02
187.9984589	0.37
197.8996887	0.20
199.8790588	0.11
201.0440674	0.04
215.9471436	1.31
227.9351807	0.04
234.0154419	0.85
238.1386719	0.05
246.2571564	0.05
248.0400085	0.24
250.0542908	0.61
255.8027191	0.02
258.1611938	0.04
259.9230042	22.96
261.1105652	0.05
263.2384644	0.05
263.8819580	0.10
272.0091553	0.65
273.9721680	2.02
275.1865234	0.09
275.9642944	0.42
277.0912781	0.70
277.7982788	3.69
285.9244995	0.49
288.1601868	0.06
290.0406799	6.15
291.7196960	0.26
297.4914551	0.06
298.5095215	0.23
306.1079102	1.49
307.1735840	0.04
308.0162354	0.06
315.5592651	0.08
318.0369263	0.10
320.1143188	0.44
321.3991089	0.13
324.2082520	0.04
336.1864624	0.22
338.1654053	0.52
350.0224609	0.15
351.9760132	100.00
352.8075562	0.49
353.9009399	0.58
355.0383911	0.03
361.8445435	0.04
363.2449951	0.16
364.2606201	0.21
369.7554321	0.02
381.2934570	0.84
382.1751099	2.76
390.2514648	0.04
408.1461792	0.49
412.1738281	0.16
412.8130493	0.12
424.3709106	0.24
425.1313477	1.11
426.0108643	1.07
428.0110474	0.91
429.1185913	0.13
430.1487427	0.03
431.9203491	0.09
438.1095581	0.64
442.2997437	0.07
446.1530151	0.08
447.4949341	0.52
449.1401978	0.26
453.5919189	0.18
454.3554077	0.02
455.8320923	0.23
462.7249146	0.10
468.7741699	0.16
469.8850708	0.35
477.9440308	0.05
481.8558960	0.18
484.2279663	0.39
490.6162109	0.05
497.8153687	0.08
500.1303101	59.84
508.0108032	0.11
525.8953247	9.69
526.5933838	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	873.3395
Annotation	Unknow
Peak:m/z	Relative Intensity
273.1212769	0.06
287.5447998	0.05
292.7525635	0.14
327.0259399	0.17
336.5517883	0.06
343.1840515	0.18
346.8916321	0.05
349.2126160	0.07
375.2871094	0.39
393.4434814	0.15
395.3216553	0.15
417.2603760	0.12
427.4304810	0.04
430.9130249	0.48
441.4223633	0.19
445.3071899	1.16
465.2011719	0.03
466.9661255	0.02
469.1118164	0.23
479.3823242	0.17
489.2392578	0.15
501.3913574	0.06
513.3998413	0.22
519.4007568	0.07
537.0320435	0.67
579.2089233	0.54
589.4616699	0.43
603.2084961	0.47
607.3882446	10.50
621.1905518	1.01
631.3408813	0.64
633.3118286	10.70
633.9226074	0.03
645.2732544	0.11
649.3353271	0.13
651.3722534	20.92
661.5314331	0.11
663.4684448	0.36
665.5870361	0.14
669.5337524	0.04
674.8699951	0.18
675.4817505	0.38
681.1837769	3.25
685.4483032	0.15
693.3604126	14.53
705.5115356	0.24
711.3049927	20.07
717.6167603	0.06
719.9974976	0.18
723.2109985	4.39
723.8362427	0.02
735.4749146	1.26
753.2874146	65.87
753.9382324	0.61
764.9050903	0.27
767.3047485	0.05
771.0593262	0.20
777.4903564	0.71
782.9586182	1.00
783.6083374	0.06
789.2651978	0.06
792.2058716	0.16
795.4610596	4.05
807.3776855	0.08
813.2731323	100.00
813.9257202	0.33
827.2085571	0.11
829.6343994	0.12
855.3043823	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	365.1452
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9631577	79.37
133.2781982	1.39
141.0366821	1.01
142.9207153	42.16
155.2840271	0.59
161.0495911	1.84
164.8194885	0.34
183.1223145	0.58
202.9935913	0.88
221.1194458	12.86
225.2860718	0.36
263.0552979	100.00
273.4128723	0.34
281.2211304	4.32
303.0656128	47.97
305.1720581	6.87
317.4123230	0.64
319.0877380	1.95
321.0368652	4.97
323.3285217	1.77
329.3048096	1.16
355.6471252	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.2185
Annotation	Cucurbitoside G
Peak:m/z	Relative Intensity
163.0853577	0.47
172.8665161	0.82
178.5334778	0.60
191.1552582	1.50
209.0683594	0.57
216.7180786	0.10
222.9841614	1.17
229.3584595	0.14
231.3316956	0.12
234.8723450	0.28
254.3069458	0.88
260.7771606	0.23
262.9207764	0.23
266.0631409	0.19
281.4187622	0.25
284.7883911	0.23
285.4254761	0.13
287.2086792	0.29
293.0827942	0.72
299.0492554	0.09
310.9817505	0.34
314.2227173	1.84
315.1956787	0.26
325.1776733	0.54
329.1663818	0.15
333.0266724	0.36
337.1534424	7.12
340.4075928	0.26
341.2446289	0.09
345.4028931	0.46
353.7086182	0.30
355.0761108	2.70
356.1693726	0.65
367.0523682	0.49
369.3866577	0.41
371.1575317	0.19
373.2212524	3.13
381.3413696	0.46
385.2282715	0.11
391.3863525	0.25
394.1602173	0.81
397.1384888	12.70
398.3612061	0.40
399.2196045	1.94
406.2603149	0.43
413.2217407	0.66
414.9783936	13.36
417.2836914	5.71
428.2022095	0.45
431.4404297	0.30
441.3032227	0.48
449.4929199	0.49
454.9393311	3.54
458.2773438	1.46
459.3413086	3.78
461.4193726	0.62
467.1598511	0.17
473.2376709	2.67
475.2689209	1.24
477.0479126	0.17
478.4433594	0.27
480.3381348	0.29
482.2957153	0.29
497.0140991	0.21
497.8981934	0.10
499.4212646	0.79
501.2296753	0.38
503.1912231	0.93
515.3938599	1.48
517.1099243	100.00
517.7806396	0.25
519.2028198	0.35
541.2941895	0.19
542.9868774	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	634.2256
Annotation	Dahuribirin C
Peak:m/z	Relative Intensity
189.0985260	0.34
189.7728882	0.27
191.1795654	0.10
199.0403442	0.21
200.1871033	0.20
201.1733093	0.05
203.0922546	8.24
214.9920349	0.13
216.3624725	0.05
218.0964355	13.05
219.0024414	0.10
226.9816589	0.39
229.0754395	0.79
231.0397339	21.70
232.1775513	3.66
233.0919189	65.03
234.0823669	4.79
240.9384766	0.16
243.1013641	0.07
245.0412598	0.10
257.1387939	0.14
269.0682983	3.16
271.0401917	0.80
273.0862732	0.39
274.2252197	0.50
287.0794067	14.67
299.0092468	16.25
300.0697021	1.13
315.2136841	0.21
317.0086975	100.00
318.0922852	2.64
319.9849243	0.14
327.6404419	0.89
331.1368408	1.06
334.9994507	0.09
342.2841797	0.15
348.2869873	0.16
370.9519653	0.06
391.3153076	0.12
396.3786011	0.09
398.5106812	0.16
400.9544678	0.38
402.2423096	0.33
448.2251587	0.05
502.2781372	0.32
516.4944458	0.07
533.0354614	0.15
536.1432495	0.15
550.2005005	0.09
556.2822876	0.15
572.9003296	0.77
573.5017700	0.55
575.1585083	0.13
576.0961914	0.73
584.4755249	0.97
587.2993774	0.42
590.6038818	0.13
598.2725830	0.27
602.2456055	9.77
602.9910278	22.16
603.8452759	0.18
615.9780884	1.02
616.5892944	0.21
635.5996704	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	965.2201
Annotation	Nicergoline
Peak:m/z	Relative Intensity
297.0824585	0.14
313.2926636	0.06
337.3400269	0.07
341.2860107	0.05
355.1372681	0.88
357.1247864	0.02
369.1447754	1.08
371.3695068	0.04
381.3724976	0.12
399.3043518	1.18
413.5090942	0.03
417.2127686	0.04
429.0939331	0.29
453.4005737	0.04
455.3005981	0.09
459.1829834	0.19
470.1426392	0.09
471.3789062	0.73
489.2532349	5.04
501.0380859	0.21
507.3165894	0.11
519.2110596	1.16
527.5084229	0.08
531.2568970	0.13
561.2291870	0.06
573.5398560	0.12
591.0691528	0.28
609.2203979	100.00
609.8455811	0.25
759.2498169	0.04
818.8658447	0.10
886.5509033	0.03
921.3783569	0.10
946.7905273	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3384
Annotation	Phaeofuran B
Peak:m/z	Relative Intensity
279.0184937	0.03
310.9328918	0.01
319.9909058	0.02
399.2779541	0.02
429.4981079	0.04
457.4840698	1.32
458.4393921	2.27
462.3925171	0.07
475.6715088	0.03
476.3715820	0.06
487.5383301	0.21
500.3410645	0.28
517.6007690	0.03
518.2889404	0.20
531.1350708	0.03
541.1386719	0.07
542.3090210	0.21
554.3159790	0.10
576.1802979	0.05
577.3587036	0.14
578.1895142	0.22
580.4973755	0.03
583.6043091	0.04
596.3568115	0.30
601.6262817	0.23
619.3884888	39.10
620.3703613	100.00
621.0102539	0.18
635.2640991	0.10
637.1419067	5.55
638.2905884	12.66
639.1934204	0.11
644.7565918	0.07
661.6129150	0.17
662.5783081	0.04
665.2545776	0.84
666.3362427	1.30
679.2541504	5.52
680.1856689	15.08
680.8405762	0.06
681.8826904	0.11
695.8052368	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2134
Annotation	Gomisin E
Peak:m/z	Relative Intensity
179.0441895	0.07
185.0472717	0.13
187.3169556	0.07
189.2362061	0.07
191.1615601	0.38
196.9959564	0.05
198.1373596	0.18
202.8162994	0.20
212.1562042	0.07
213.2148285	0.14
219.1879578	0.31
220.9510040	0.09
225.4241333	0.16
227.2498016	0.55
231.0118103	0.35
238.0907898	0.10
239.2461700	0.15
243.1806641	0.18
244.9184265	0.51
247.7920685	0.10
249.4891815	0.14
255.1974335	0.14
256.9653625	0.23
259.2072754	0.15
261.2363281	0.19
263.3816528	0.18
265.1351929	0.08
269.2459106	0.14
271.2591553	0.86
275.1051636	0.61
277.2082520	0.07
279.2003174	0.81
280.3051758	0.07
281.0548096	0.14
283.0786133	0.20
285.2764282	0.39
286.4724731	0.15
287.2956238	0.29
289.1643677	0.93
293.1573486	0.08
294.1477051	0.14
297.2678223	0.37
301.1348877	0.43
303.3565063	0.13
309.4245605	0.25
310.9880371	0.36
313.3949585	0.58
315.2091675	0.24
321.2426147	0.64
323.3377075	0.64
325.0856323	0.23
326.3134766	0.11
331.3516846	0.09
333.1940918	2.52
337.3930664	0.74
338.9666138	0.27
341.3057251	0.97
349.4598999	0.65
350.4738770	0.51
351.3602905	0.36
353.1297607	0.66
355.3048096	0.91
365.4016113	0.36
367.2291870	0.31
371.4670410	0.18
373.1620483	0.42
374.9771118	0.31
376.2294922	0.06
379.3704224	0.83
381.2255859	1.38
383.2114868	1.00
389.4171143	1.14
390.3198242	0.19
391.4042969	0.14
393.2864380	0.09
395.2752686	0.30
397.2078247	0.33
398.3494873	0.25
399.1386108	2.43
407.5833130	0.14
409.2517090	0.67
411.3485107	0.12
415.6331177	0.16
417.2601318	0.14
418.1773682	0.07
419.1583252	0.19
421.0833130	0.10
423.2307739	0.55
425.8165894	0.07
427.1124268	0.25
430.3556519	0.07
431.0159302	0.15
433.4455566	0.64
435.5955811	0.31
437.1182251	0.42
441.2254028	1.68
442.4235229	0.08
443.5115967	0.11
449.3640747	0.46
450.1531982	0.11
451.3519897	1.73
453.2800293	5.30
455.3295898	1.80
467.1558228	0.68
469.4360352	0.25
477.2396851	0.97
480.4476929	0.16
485.2798462	100.00
493.1514893	0.09
495.2486572	19.22
496.3527832	0.06
498.5953979	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1685
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
119.1983185	0.66
125.2848129	0.14
148.9010315	0.26
155.9659271	0.14
157.1938782	0.48
165.0984497	0.43
169.0432739	0.18
169.9653168	4.11
171.0651855	1.31
183.0035248	100.00
183.9849091	17.70
184.9121552	0.14
197.3078918	2.31
198.000885	9.93
199.2201385	1.45
201.2093048	0.22
211.2406311	1.70
212.1088562	3.23
217.1596069	0.36
221.1572266	0.13
225.1724854	1.28
234.9390869	0.97
239.1413574	4.94
240.4248657	0.16
243.079834	1.42
247.2496338	4.51
248.2365417	1.14
249.352478	1.01
250.986084	0.47
253.1766052	2.93
255.0640259	0.15
258.0227051	0.27
262.0343933	0.15
263.0426025	0.61
265.3465576	0.64
267.3977661	1.67
270.2870178	0.21
279.2188416	0.19
281.3528137	0.20
283.0755005	3.75
284.3766174	0.20
291.2595215	0.90
293.2276611	5.82
295.3548584	0.72
311.256073	24.52
312.4074097	1.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	479.1194
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
139.0993805	0.05
167.0425415	13.85
178.6523285	0.22
191.1308441	0.05
197.1656189	2.42
269.1336975	1.90
271.2967834	0.30
287.1731567	10.37
289.1596985	0.35
299.3438721	0.58
316.1774292	0.08
317.1839600	0.61
319.4022827	0.19
341.2211609	0.34
356.7746582	0.26
359.1092224	100.00
371.2948608	0.48
389.0773621	15.44
389.6972961	0.28
393.2647400	0.12
401.2051086	0.30
419.2640381	0.69
430.7103271	0.16
431.5303040	0.31
433.3063660	3.68
435.3131714	0.06
443.1027222	0.72
449.3450623	0.09
461.1518555	7.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	203.0333
Annotation	6-Hydroxyangelicin
Peak:m/z	Relative Intensity
90.6739349	0.08
103.0941010	0.13
107.0673676	0.35
109.2028198	0.30
119.0355225	0.84
122.8507080	0.32
130.9615326	16.98
132.0521240	0.19
132.8567963	0.18
146.9267426	32.33
147.9900665	1.08
157.2012177	0.10
159.0396881	28.06
160.0515900	2.11
161.0596161	0.69
175.0355377	100.00
176.1136322	3.96
184.9863892	3.96
185.9813385	0.13
202.4778595	0.15
203.1163940	8.08
204.2025299	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1821
Annotation	Genipin gentiobioside
Peak:m/z	Relative Intensity
160.8716736	0.18
166.9518585	0.11
179.0656433	1.49
191.9068146	0.05
202.5623932	0.04
203.2491760	0.03
221.1517944	2.92
243.0494843	0.02
245.2091522	0.35
263.0756836	1.29
305.3660278	0.05
315.2356567	0.12
323.1011353	100.00
335.3986816	0.03
369.3416138	0.03
381.3013306	0.06
385.7592163	0.19
387.0270996	0.05
427.9050903	0.09
434.4433594	0.06
438.9615479	0.05
463.3021851	0.02
502.0474854	3.17
502.8476562	43.11
503.4740601	0.57
504.0951538	0.03
505.1808472	0.22
511.3453979	0.06
513.3857422	0.03
532.3031616	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1034
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
101.0393143	0.03
109.0248566	0.52
111.1592636	0.07
118.9390564	0.06
120.9195938	0.50
122.0037079	0.05
125.0008698	0.20
128.9762878	0.27
134.9282532	0.14
137.0718994	9.24
139.0245056	0.04
143.0150757	0.29
154.1747589	0.02
154.9620819	0.05
159.1109619	0.08
161.0488892	0.33
163.0579529	4.93
181.0064392	100.00
182.1087341	0.16
187.0087891	0.28
191.1567535	0.13
200.3096008	0.05
203.0020599	0.34
205.0269165	5.34
219.2433167	0.05
223.0130615	2.67
247.1909180	0.11
253.0128174	0.19
264.9707642	0.10
281.0075378	0.04
283.2683411	0.03
285.9224854	0.10
296.8797302	0.10
299.1571350	0.22
299.8985596	0.07
315.3159485	0.11
323.2895203	0.03
325.2250671	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	383.0753
Annotation	Bikaverin
Peak:m/z	Relative Intensity
119.0509644	1.41
122.8412628	3.38
126.9535217	1.67
138.9859314	1.35
150.8140259	1.52
152.8372498	0.61
181.0540314	0.56
183.1368103	0.75
184.9794922	2.69
195.0419312	1.15
201.0997620	2.51
221.1435547	7.01
233.0512085	15.76
234.9691162	0.50
242.4421387	3.94
243.2468872	0.56
260.3756714	2.80
260.9867554	100.00
271.2111511	3.54
296.2081604	3.12
297.2791138	1.70
303.9406128	3.50
305.3446655	1.46
310.5367737	0.79
311.2468262	3.03
319.2070923	1.70
323.1155090	1.12
324.0385132	1.96
325.3738403	0.53
329.4489746	0.53
337.3833313	3.31
339.5437622	2.14
346.9868774	1.39
353.3641663	1.67
355.3109436	7.34
365.1365051	15.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.1534
Annotation	Unknow
Peak:m/z	Relative Intensity
132.8189240	0.40
137.1652527	0.08
142.1603394	0.07
145.0212250	0.22
147.0013428	4.65
149.0054321	0.25
152.7862549	0.04
156.8962555	0.21
159.0239258	0.31
161.0228424	2.16
163.0107422	0.12
165.0451355	1.91
169.0174866	0.47
171.0820160	0.18
173.0475769	0.31
174.9834290	1.09
176.1353607	0.08
176.9700165	0.57
182.9499207	0.22
185.0484924	0.64
187.0491180	1.19
189.1069031	0.17
191.0554962	0.40
193.1940918	0.15
197.1944733	0.28
199.2847900	0.19
201.1840210	0.28
202.2075195	0.04
203.0261078	0.35
205.1228333	0.16
207.1172485	0.30
211.2488861	0.09
213.0168610	0.23
215.2156677	0.28
217.2187195	0.22
219.0777283	0.09
223.1036530	0.17
225.2493896	0.25
229.1253204	0.27
231.0070801	0.96
233.2089386	0.14
234.8959351	0.31
235.7460327	0.06
236.8163147	0.35
239.2543793	1.21
241.1044312	0.18
242.9583588	0.77
245.2387390	0.74
247.0374756	0.20
251.2617188	0.05
253.0665894	0.30
255.2031250	0.33
258.2984314	0.23
259.1507568	0.56
263.1381531	0.28
265.2013550	0.45
267.3829956	0.04
270.0915222	0.02
271.1887817	0.55
272.9859619	0.70
275.1573486	0.15
277.1991272	0.44
281.2376404	0.03
283.4378052	0.08
285.2032166	0.20
286.1083984	0.08
287.0074463	0.45
290.9074402	0.59
293.3277588	0.24
294.0459595	0.41
295.3919067	0.18
297.2639465	0.65
299.1537476	0.24
301.2163086	0.35
303.3519592	0.30
305.0830688	0.49
307.1530762	0.60
309.1939392	0.22
311.0401001	0.63
312.6333313	0.22
313.3745117	0.54
315.2727661	2.72
317.1033936	0.22
319.5933533	0.29
321.2000122	0.45
322.3129578	0.06
323.2884216	0.44
325.1783447	0.55
327.3179932	0.21
328.4375610	0.08
329.1401367	0.13
331.2842712	0.69
332.5098267	0.73
333.1694031	1.44
335.3145447	0.03
337.2948914	0.70
337.9339600	0.18
339.1907959	0.80
341.1660461	1.67
343.4602356	0.18
345.4963379	0.07
347.2945862	0.92
348.0943909	0.18
349.0861206	0.28
351.2380981	0.59
351.9869995	0.23
353.0558777	0.23
355.3130493	0.19
356.0912476	0.30
357.2841492	1.17
358.4432068	0.46
359.1750488	1.71
361.3455811	0.06
363.3663330	0.09
365.3024902	1.66
367.1672363	0.54
369.2949219	0.16
373.2934875	0.47
375.2345886	1.62
376.9927063	2.46
378.0011902	0.18
381.2707214	0.66
383.4539795	0.33
387.3711548	0.55
388.9384155	0.23
391.2848206	3.22
393.2459412	3.65
395.0415344	100.00
395.7559204	0.12
401.1158752	0.64
401.7394104	0.17
406.0090637	0.16
407.0300598	0.05
409.2226257	21.85
411.2857971	8.15
413.1553650	0.11
419.4319763	2.35
427.2781677	1.09
437.1639099	5.96
437.7755432	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	867.262
Annotation	Unknow
Peak:m/z	Relative Intensity
245.0492096	0.16
277.2111206	0.04
286.9655762	0.04
288.9557190	0.33
305.0951843	0.76
312.9370117	0.21
321.1423340	0.31
329.2614136	0.18
337.2677917	0.41
341.2772217	0.12
349.3157959	0.11
359.4499817	0.14
361.2790222	0.13
363.0439453	0.20
370.6563721	0.03
371.4977417	0.17
375.2304077	0.32
377.1906738	0.13
381.0400391	0.15
401.4340210	0.12
402.8710327	0.10
421.1854858	1.00
433.4419556	0.43
443.7915649	0.05
446.7331543	0.07
449.2433472	0.78
453.1618652	0.49
473.1921387	0.17
474.4117432	0.07
475.0501099	0.07
481.5527954	0.30
491.3765869	0.43
493.3060303	0.14
495.1023560	0.05
504.7434692	0.19
507.3771362	0.27
509.2376709	1.42
511.3170776	0.26
525.2968750	1.33
543.3986206	1.76
544.1232300	0.14
551.3518677	0.27
553.1239014	0.34
567.2354736	0.53
569.3727417	0.21
571.4076538	0.77
581.2597656	0.08
585.3731689	1.28
593.4426270	0.05
603.3699341	14.00
605.1798706	1.52
613.2307129	0.03
625.0958862	3.08
627.2111816	0.17
637.0463867	0.15
638.9857788	0.09
641.3355103	0.65
643.3390503	2.13
645.2450562	0.44
657.3160400	16.15
663.4924316	0.06
675.3133545	33.24
683.4162598	0.30
685.4317017	0.21
687.5147705	0.29
699.2752075	0.05
701.4596558	0.08
703.2932739	0.77
717.3458862	0.70
733.3922729	0.04
735.2212524	61.53
735.9388428	0.08
745.6782837	0.03
757.2082520	3.15
775.2997437	1.10
777.3182983	2.00
777.9251099	0.02
789.3351440	45.36
807.2655029	100.00
808.0228882	0.46
817.5042114	0.21
819.5579224	0.09
831.3297729	0.16
835.2156372	2.37
837.4512329	0.18
849.1981812	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	825.3521
Annotation	Unknow
Peak:m/z	Relative Intensity
243.1032257	0.13
257.2087708	0.23
258.0203857	0.06
271.2409973	0.27
273.3645935	0.06
275.1039734	0.40
279.5951843	0.03
281.1965332	0.04
285.2685547	0.15
288.2798462	0.64
289.4207153	0.08
299.2578735	0.14
302.3154602	0.13
306.1193237	0.17
307.4069214	0.10
314.1475830	0.51
319.4055786	0.13
320.1359863	0.35
321.0710144	0.07
324.2642212	0.06
329.2963562	0.08
331.3973694	0.08
332.2404785	0.14
333.8014221	0.68
334.4065552	0.22
342.1413879	0.23
343.3070679	0.04
349.4982910	0.02
352.3283691	0.19
359.0969238	2.60
360.1630859	0.15
361.3010864	0.14
364.1879883	0.07
375.1181946	0.90
375.9035034	0.35
377.1276245	1.12
385.4130859	0.04
390.4038086	0.21
391.3515625	0.02
394.4146118	0.08
398.9967041	0.18
402.1459351	0.03
403.1103516	0.44
404.0172729	0.30
405.1563721	0.28
421.1075439	0.25
422.0836792	0.18
429.0154419	0.10
430.3449097	0.05
433.4628906	0.07
435.1587524	0.27
445.2306519	0.13
449.2576294	1.35
451.3341064	0.11
452.2613525	0.02
453.2078857	0.09
455.6905518	0.32
456.5426025	0.22
460.5501099	0.40
461.3483276	1.59
462.4382935	0.36
466.3212280	0.06
467.3571167	0.10
468.2543945	0.08
474.3208618	1.37
478.2200928	0.89
479.2442627	1.18
480.1290283	0.06
481.7164307	0.05
485.3382568	0.06
486.0156250	0.14
488.1878662	0.17
492.1843872	0.40
495.6705322	0.30
496.2951660	0.67
502.3292847	0.15
504.6856689	0.13
506.2570190	7.65
507.3300171	0.04
513.1643066	0.12
515.1011963	0.14
520.3591309	2.08
523.1648560	0.09
524.2606812	6.10
526.0551147	0.07
529.3088379	0.06
532.3051758	0.08
536.0855103	0.19
539.4217529	0.11
544.3060303	0.09
545.3362427	0.15
546.0681152	0.05
548.8832397	0.09
550.1828003	0.12
552.5358276	0.15
559.2716064	0.87
561.1872559	0.08
562.2949219	0.30
563.5228882	0.21
564.3601685	0.26
574.8777466	0.10
576.0369263	0.24
577.1596069	0.65
581.6465454	0.05
585.1416016	0.13
589.9824219	0.87
593.4097900	0.05
595.5741577	0.10
596.9788818	0.05
602.8610840	0.69
603.5032349	0.27
607.3472900	0.52
608.2615356	0.44
611.3047485	0.16
613.8256226	0.04
615.0937500	1.92
617.0166626	0.25
619.6186523	0.08
621.2063599	7.90
622.1156006	0.17
625.7210083	0.07
633.1735229	1.40
634.9738159	0.20
635.7588501	0.08
639.1678467	2.89
639.8740845	0.07
642.2335815	0.38
643.4531250	0.04
645.2019653	0.02
649.3955688	0.24
650.3822632	0.05
653.3765869	0.89
660.2705078	2.22
661.2531128	0.16
664.4578247	0.03
666.6118774	0.36
671.5758667	0.04
674.2871704	0.24
677.5306396	0.57
678.3825684	2.06
679.2902832	0.33
680.1743164	0.10
682.3501587	0.62
687.3059692	0.15
688.1546021	0.21
690.7255859	0.14
692.3388062	5.46
696.3920898	0.32
704.2310791	0.18
705.2760010	0.44
706.2266235	0.94
707.2192993	0.06
708.0599976	0.29
709.0980835	0.15
710.2707520	10.80
711.0197144	0.12
714.5843506	0.14
718.5554199	0.37
719.4699097	0.07
722.3538818	1.68
723.3020630	0.63
724.2894897	0.71
732.3007812	3.49
734.4418335	0.04
736.2756958	0.52
744.2007446	0.21
745.4373169	0.14
746.7214355	0.02
750.2689819	4.85
751.3752441	0.29
752.2873535	0.86
753.7171631	0.09
754.5582886	0.14
761.2763062	0.41
762.3272095	0.47
763.3526611	2.35
764.2890625	0.11
772.2019653	0.06
779.1481323	3.98
780.2019043	4.74
781.3827515	3.60
783.1492920	0.04
789.3247681	13.68
790.1687622	0.32
793.4617920	0.08
797.3305054	7.91
807.2725830	100.00
808.0634155	1.06
808.6951294	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	613.17
Annotation	Safflomin A
Peak:m/z	Relative Intensity
173.8697968	0.03
177.0112000	0.07
181.9994354	0.03
188.1406555	0.11
194.9005737	0.04
199.2241211	0.08
213.2102051	0.08
216.3172607	0.03
220.2565613	0.05
230.9253845	0.08
232.9736786	0.56
243.2266083	0.20
245.2597351	0.29
256.0859680	0.06
257.1069336	0.08
259.1481018	0.34
260.9742126	0.02
262.8605957	0.07
266.1864929	0.03
272.1420288	0.02
272.9846191	0.02
278.0268555	0.08
283.0098267	0.19
287.1881104	0.05
288.2577209	0.09
291.2637939	0.07
295.2907104	0.04
301.3809814	0.08
303.1270142	0.08
305.1079102	1.80
311.6112061	0.16
313.3320312	0.20
322.2550659	0.18
323.1053467	0.07
326.3400879	0.23
327.6960449	0.05
329.0280151	0.38
331.3377686	0.07
336.2239990	0.31
337.1990967	0.07
339.4199829	0.04
340.3933105	0.03
346.1694946	0.02
347.0646362	0.87
347.8900757	0.05
354.4614868	0.17
355.1021118	0.06
364.1962280	0.12
365.2297974	0.09
369.3197632	0.03
371.1260986	0.13
372.9362793	0.23
378.2011719	0.05
389.4141235	0.10
390.2515869	0.06
396.9774170	0.06
401.5341187	0.12
403.1027222	0.02
406.5936890	0.06
413.1004639	0.20
415.2175903	0.87
421.2337036	0.05
423.3065186	0.02
431.1734619	0.17
433.0897827	2.27
434.2787476	0.12
439.2248535	0.19
441.0667114	0.55
442.2175903	0.08
443.2031250	0.11
445.2642822	0.20
449.0935669	2.49
450.5316772	1.31
451.1459961	4.10
457.2339478	3.86
459.1956177	0.09
461.0801392	0.03
467.0089111	2.82
469.1919556	0.05
475.1701050	9.86
477.3731079	0.18
481.1764526	0.40
485.4611816	0.21
490.9099731	0.46
492.9885254	1.95
495.3229980	0.06
499.1618042	0.56
511.0258179	0.65
512.8924561	0.12
523.1318970	0.38
529.0283813	0.42
541.1423340	2.52
545.9103394	0.37
547.1971436	0.14
555.4680176	0.03
559.1759644	8.95
568.2562866	0.07
569.4696655	0.33
577.1470947	56.87
577.7551880	0.29
592.8589478	0.02
595.1453247	100.00
595.8361206	0.10
597.5355835	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	246.9918
Annotation	Vanillic acid 4-sulfate
Peak:m/z	Relative Intensity
79.8263474	1.87
96.9417267	6.23
107.8851776	0.14
123.0653534	1.34
137.9321747	0.03
142.8807526	0.02
146.0959320	0.03
152.0897980	0.02
157.1761932	0.12
167.0168304	100.00
185.0464935	0.07
187.0465851	0.02
202.9571991	46.03
211.1031494	0.25
219.1411438	0.03
229.0118408	0.38
231.7956696	0.03
246.9691162	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	783.1957
Annotation	Unknow
Peak:m/z	Relative Intensity
219.6725311	0.06
226.8932343	0.08
229.1147919	0.03
234.9124908	0.08
237.8581543	0.03
244.1060181	0.05
245.1123505	0.25
247.0810852	0.25
253.0292206	0.28
254.9994202	0.08
259.2472534	0.10
260.9962158	0.14
262.1030579	0.04
267.0927124	0.04
270.8486023	0.66
271.9652100	0.56
273.2179565	0.40
276.0371704	0.13
282.0327148	0.02
289.0006104	1.45
289.9346313	0.24
300.4166870	0.33
301.0547485	2.40
304.1740112	0.06
307.0645142	0.28
312.9085693	0.21
315.0252380	0.15
317.1183472	0.42
318.0516052	12.66
319.2491760	0.23
320.8721008	0.14
325.1966553	0.05
326.2609253	0.02
331.2799683	0.20
333.0708313	100.00
333.6851807	0.55
341.0655518	0.03
345.6381226	0.04
347.3005981	0.58
348.9234009	0.26
354.8613892	0.02
362.1575012	0.06
375.1721191	3.00
377.1915283	0.11
379.0624390	0.23
387.3853760	0.02
396.9468994	0.48
399.2289429	0.05
405.3308716	0.03
409.6872559	0.07
414.9380493	1.24
423.1901245	0.09
430.2888794	0.09
433.1513062	3.84
441.1694946	1.70
443.2802734	0.09
448.9006348	0.09
450.8475952	0.15
463.0551758	0.08
475.5721436	0.09
476.2576294	0.04
492.5684814	0.04
509.4940186	0.03
518.4583130	0.04
519.1221924	0.03
540.6834717	0.06
543.2020874	0.02
553.6126099	0.11
555.3035278	0.02
556.5281982	0.02
557.9132690	0.16
567.3103638	0.14
573.0357666	0.07
585.1296997	0.20
587.4805908	0.08
602.9449463	0.75
605.9089355	0.03
616.6123657	0.05
620.2141724	0.02
620.9613037	0.44
621.5983276	0.02
629.8007202	0.23
633.5623779	0.14
635.6245728	0.04
636.8529663	0.07
638.9742432	0.25
651.5933228	0.22
657.1174927	0.05
662.3613892	0.07
670.3712158	0.06
676.5534058	0.03
683.0247192	0.12
703.2478638	0.06
709.3087769	0.19
721.3594360	0.12
722.1604004	0.07
731.3543091	0.02
732.1267700	0.06
738.6934204	0.10
747.1897583	1.22
764.5480347	0.64
765.2063599	4.31
766.9717407	0.16
768.1275024	0.14
782.6333008	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	474.1715
Annotation	Folinic acid
Peak:m/z	Relative Intensity
143.9406738	0.01
166.1224060	0.05
187.2507935	0.04
227.8749084	0.01
230.1320496	0.07
257.9451294	0.03
264.4679871	0.03
284.3052063	0.04
293.1250305	0.02
294.2579041	0.01
301.2884216	0.54
312.3743896	0.09
318.4058533	0.02
327.1453857	100.00
328.1212463	0.10
345.1251221	18.65
346.3113403	0.02
347.3911743	0.02
385.1563416	0.03
385.9524841	0.01
393.2984314	0.07
402.1620483	0.02
410.4120483	0.02
411.6090393	0.20
412.2140198	0.19
426.0236206	0.03
428.2008972	1.16
430.2161560	0.91
430.8396606	0.00
438.1876526	0.24
456.2023621	15.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.12
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
145.0575562	0.02
249.2049255	0.01
301.0842590	100.00
301.9282837	0.01
313.2567749	0.06
324.9838867	0.13
343.2301025	0.90
367.1460571	0.45
373.2095032	0.06
381.3315125	0.05
397.1967163	0.92
409.0716553	0.14
415.4128723	0.04
427.1727905	1.28
445.2826843	4.63
448.0024414	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	197.0804
Annotation	4-Hydroxy-6-methyl-3-(1-oxobutyl)-2H-pyran-2-one
Peak:m/z	Relative Intensity
109.0869446	0.05
114.8764038	0.01
120.9866791	0.05
125.0663300	0.03
133.0863495	0.05
136.9722137	17.67
141.6366577	0.01
162.3166046	0.04
173.8315887	0.03
177.0486145	0.05
178.9767303	100.00
179.7899017	0.02
189.0372162	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	662.8318
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9717407	0.06
245.0372620	0.02
260.8556824	0.02
273.2659912	0.12
288.9799805	2.80
305.0325317	4.77
386.9972534	0.02
402.9178467	2.46
418.9024048	14.52
419.5118408	0.08
434.8439331	5.42
516.8255005	0.11
532.8135376	10.34
533.4269409	0.16
547.1111450	0.08
548.7767944	100.00
549.4283447	0.29
560.7907715	0.05
567.3892822	0.02
577.5537720	0.04
588.9174194	0.09
615.4110718	0.03
616.6010742	0.24
620.5402222	0.02
635.8661499	0.13
644.0174561	0.06
645.0206299	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
78.92021179	0.99
90.88711548	0.61
93.00463104	0.39
97.0018158	0.15
103.0492859	1.09
104.9063873	0.25
108.9846344	1.63
112.9560394	0.24
115.0184479	0.24
115.9996338	0.20
118.6678314	0.30
123.0320282	0.61
125.0078278	0.37
126.9999695	2.89
128.9581604	5.93
135.0697479	0.73
141.0978546	0.96
143.2923431	0.41
147.0499573	1.13
149.1789856	0.69
151.0073395	52.89
152.0728607	4.56
154.9960175	0.52
161.091095	0.16
166.0363922	0.93
167.1201019	1.66
169.1220551	0.81
170.1171417	0.14
175.0760803	0.74
177.1468201	0.69
179.1879272	1.45
180.0988007	1.06
183.1181793	0.46
183.9253998	0.56
185.1798553	0.37
186.2631683	0.42
189.6548462	0.58
190.9786835	0.36
193.9773712	0.72
195.1618195	1.21
196.9674377	1.71
205.1841431	0.26
206.9182281	2.17
209.2686005	0.15
211.1571808	1.61
212.033371	0.13
217.1129608	2.62
224.3517914	0.55
225.1766052	4.82
226.1750336	0.84
235.2107391	7.45
236.0795135	0.60
237.9174957	7.38
239.0563507	1.41
251.0024567	1.26
253.0952301	100.00
254.0482178	17.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.73
Annotation	Unknow
Peak:m/z	Relative Intensity
212.7959595	0.96
296.1026001	0.34
296.8222656	10.02
317.2608643	0.11
332.9444580	0.10
334.4594727	0.04
344.9450073	0.07
380.1159058	5.83
380.7393188	37.81
386.6901245	0.22
424.9332886	0.39
428.8366699	0.26
442.7692261	0.04
463.8244019	3.94
464.5717163	69.17
466.7348633	1.71
470.6394043	1.51
496.7629395	1.36
512.6821899	0.63
524.7993774	0.07
526.5783691	2.31
538.7274170	0.07
542.0149536	0.20
545.9784546	0.21
548.4260254	100.00
549.2608032	0.20
550.7677002	0.08
556.3037109	0.62
557.1865845	0.10
567.8686523	0.11
568.5745850	0.80
572.4902344	1.19
585.5173340	0.12
586.6371460	0.78
589.0393677	0.06
614.9472046	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2154
Annotation	Reissantin E
Peak:m/z	Relative Intensity
137.1254883	1.41
140.0083466	0.09
141.5058136	1.21
145.0407715	0.92
146.9276733	0.17
149.0713196	0.17
150.8957977	0.59
151.9651489	0.40
153.1965179	0.21
157.2072601	0.83
159.2265778	0.93
160.9732819	9.86
163.0870972	3.22
165.1568756	0.36
166.9773560	0.33
169.1826019	1.87
170.0137939	0.28
171.0187988	0.83
173.0330963	1.34
173.9678040	0.38
175.0633850	3.08
177.0322571	0.48
179.0703583	1.09
181.3520203	0.33
182.4057617	0.43
183.1199799	0.17
185.4175415	0.65
187.0982971	11.58
189.0868225	2.27
191.1462708	0.55
193.2356720	0.10
195.1369934	0.80
197.0172119	0.33
199.3486328	0.56
201.1973877	0.48
203.0938110	2.07
205.0146484	1.59
206.9778137	1.15
209.1169281	0.49
210.0642700	0.07
211.1450195	1.00
213.1512299	3.31
214.0569458	0.09
215.1310425	2.42
217.0749817	0.89
219.0464172	1.00
220.9905701	1.02
223.0883636	1.30
225.0188141	0.06
227.2592773	3.16
229.2450562	1.96
231.0956726	5.30
233.1009369	0.93
235.1887207	0.84
236.3076019	0.13
237.2468719	1.41
239.0417175	0.86
241.1204071	4.86
243.0240021	2.36
245.0897827	1.37
246.0640869	0.31
247.1184692	0.28
248.3544922	0.31
249.1029968	1.75
251.1128540	1.80
252.2830811	0.22
253.4089050	0.80
255.1352844	2.53
256.1293030	0.16
257.2722168	0.61
259.0441895	1.09
261.2701416	1.21
263.1636047	2.14
264.5544434	0.48
265.2794495	1.12
267.0670776	5.84
267.8011169	0.27
268.5814819	0.66
269.1952209	0.63
270.4682007	0.38
271.2186890	1.54
273.1799011	0.74
275.1502380	1.66
276.3107300	0.37
277.2651978	3.42
279.2995911	0.65
280.0747070	0.12
281.1910400	1.43
283.2053833	3.05
284.9624329	1.53
285.6161804	0.11
287.1902771	1.37
289.2406311	3.58
291.2624512	1.81
292.5065918	1.22
293.2828369	2.43
295.2366943	3.14
297.2246094	1.96
299.2281189	3.84
301.2129211	3.56
302.3127136	0.50
303.2622375	0.71
305.2288818	2.19
307.1660156	4.49
309.0522461	2.14
310.1176147	0.34
311.1683960	4.82
313.2971191	0.87
315.2947998	1.04
317.2472534	0.66
319.4001465	0.41
321.2109375	3.90
323.1629639	5.76
325.1926880	3.66
326.7318115	0.53
327.3838196	1.30
329.1649170	2.64
331.2476196	2.64
333.2898254	4.09
335.2620544	8.39
337.2586060	5.04
339.1095581	4.35
341.3147583	21.24
343.3135681	2.28
344.9248047	0.80
345.5249634	0.41
347.1397095	2.36
349.2976990	14.49
350.7272034	0.46
351.3290405	10.76
352.9371643	1.12
353.5419922	1.51
355.1665039	4.36
357.4481812	1.46
359.3569336	0.26
361.2770691	2.31
363.0964966	0.85
365.2523193	7.02
367.2620544	26.03
369.2697754	97.11
371.1906738	1.02
373.3756714	1.18
375.2937317	5.55
377.1163635	7.48
379.5757141	0.19
380.2540283	0.30
381.1336365	1.12
383.0694885	1.17
383.6875000	0.04
385.1791077	6.86
385.7941589	0.05
387.4023438	0.11
389.4453430	0.46
391.2051697	3.88
391.8572693	0.06
393.3325500	25.56
395.1669006	8.19
397.2922058	1.86
399.2319031	1.51
401.0812988	2.96
403.3628540	0.31
405.2741089	2.39
407.3379517	1.08
409.2460022	17.91
411.1936035	81.53
411.9131165	1.58
413.1368103	55.52
413.8380737	0.04
415.0409241	0.05
419.2027893	9.18
420.0203857	0.04
425.3158875	0.46
427.2632751	100.00
427.9251404	0.23
429.1847839	35.80
429.8391418	0.13
437.1977844	88.94
441.9249878	0.11
443.1344299	0.57
445.2455139	0.54
454.5138550	6.89
455.2774658	76.71
472.2972107	0.13
473.2284241	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.2764
Annotation	Unknow
Peak:m/z	Relative Intensity
237.1431732	0.12
257.8525696	0.18
284.9481812	0.06
314.0549011	0.17
317.2518921	0.08
321.1233215	0.12
329.2205811	0.08
331.0748291	0.20
337.4990845	0.07
357.0280151	0.54
387.4219971	0.07
445.5689697	0.08
447.0601196	0.11
455.4179077	0.28
472.2632446	0.17
473.3670044	2.79
477.2344360	0.37
479.1438599	0.19
485.4159546	0.06
490.8983154	0.09
495.2772827	0.14
506.2092896	0.17
507.2581787	0.09
515.3539429	0.54
527.2525635	0.06
533.2485962	0.09
545.2561646	0.15
555.1213989	0.13
565.2914429	0.09
587.2952271	0.19
589.1068115	0.06
590.2174683	0.04
591.2185669	0.07
599.3682251	0.19
607.2504272	0.03
611.3285522	0.22
617.3071899	0.92
633.2854004	0.16
635.1484985	0.66
655.1557007	1.07
655.8428345	0.02
677.4776001	0.25
689.1707764	0.04
693.3928833	51.84
694.9692993	0.05
699.1661987	0.07
705.3391724	0.08
717.3043823	0.15
731.1973877	0.37
732.9368896	0.10
735.2570190	100.00
735.9324341	0.65
749.2819214	0.54
756.3300171	0.20
761.3718872	0.52
765.0598755	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.177
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
174.0050659	0.07
180.9352264	0.03
182.0856018	0.17
185.2262115	0.15
186.2595673	0.05
187.1497955	0.11
188.3178406	0.29
189.0622101	0.11
190.2184601	0.04
196.1634979	0.07
201.0132141	0.05
202.0956421	0.07
203.0929260	0.04
203.9912720	0.07
204.9038696	0.05
206.4528198	0.05
209.9907684	0.07
213.2020874	0.02
214.1686707	0.18
215.1456757	0.20
215.8038025	0.04
216.9840393	0.51
230.3169250	0.01
231.2740173	0.19
238.0465851	0.09
239.9006500	0.07
241.0235901	0.29
243.1522827	0.04
245.9898987	0.06
254.0655365	0.09
255.1883545	0.15
256.0237427	0.21
257.0537109	0.10
258.1061401	0.66
259.1920471	0.82
267.1206970	0.14
270.8894958	0.02
272.0355225	0.07
273.1436462	0.97
274.0487671	1.14
275.1321106	0.18
282.2369080	0.16
283.3435669	0.07
284.1687012	0.77
285.1562195	0.87
286.9207458	0.02
288.4536743	0.10
289.1328125	4.00
290.1417847	4.13
295.1259766	0.02
297.2762146	0.12
298.2408447	0.36
299.1715698	4.03
300.1661377	3.74
311.2556763	0.06
312.4936523	0.06
313.1087036	2.80
314.0903931	4.86
317.0712891	13.27
318.1248169	17.23
323.0063477	0.12
324.1478882	0.23
325.1442871	0.05
327.1152954	0.06
329.0493774	0.07
329.9641724	0.01
331.5692139	0.13
332.3239136	0.14
341.1495972	1.03
342.1301880	1.76
344.0876465	0.29
353.2957153	0.21
354.2460327	0.03
354.9857178	0.16
356.1619263	0.29
359.3791504	0.06
360.1928711	0.17
366.2357178	0.02
371.2777100	0.03
372.1232910	0.02
377.0576782	0.02
383.2306519	0.55
384.3900146	0.10
385.2043457	0.51
386.1450195	0.19
400.1214600	0.04
413.9471436	0.41
415.3338013	0.14
416.2180786	0.16
433.3407593	0.03
434.1275635	0.17
442.6129761	0.06
446.3886719	0.07
458.4553223	0.01
459.1201172	0.03
460.0964966	0.26
461.3137207	0.20
463.3411865	0.03
464.1942749	0.05
486.1218262	0.03
487.2108765	0.58
488.1921997	1.09
489.0939331	0.17
494.3368530	0.07
503.4001465	0.03
504.3694458	1.00
505.3746948	0.65
506.2677612	1.93
511.4757690	0.05
530.4443970	0.02
533.8156128	0.04
535.1968994	0.16
536.3328247	0.41
547.9359741	0.14
564.9446411	0.07
572.6768188	0.04
574.2558594	0.02
580.2695923	0.17
582.3158569	0.31
590.2439575	0.47
591.3190308	0.15
598.1641235	100.00
598.8419189	0.17
599.4736938	0.03
607.0678101	0.03
608.1949463	5.35
609.0641479	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	696.4618
Annotation	Unknow
Peak:m/z	Relative Intensity
212.9082031	0.09
219.3020477	0.05
254.0786285	0.04
280.8871765	0.09
289.8977661	0.10
310.3948975	0.10
312.0613403	0.20
314.2658081	0.20
326.1137390	0.44
339.2922363	0.10
340.3565674	0.24
353.3747559	0.05
357.3723755	0.13
359.0969238	0.28
371.2297974	0.13
383.2217407	0.34
385.2580566	0.04
387.2304688	0.12
397.4392090	0.23
401.9342651	0.20
409.1379395	0.54
425.2666016	0.76
427.1458740	0.29
436.4315186	0.13
437.4448853	0.09
439.2806396	1.02
451.2185059	0.07
453.5137939	0.09
456.1595459	0.18
465.1719971	0.06
466.2347412	1.04
470.0291748	0.10
480.4545898	0.24
481.3380127	0.09
482.1828003	0.04
484.2366333	1.42
487.5076294	0.13
493.4911499	0.20
495.3398438	0.06
496.3536377	0.03
499.0053101	0.08
508.2207031	0.27
510.1848755	0.11
512.0291748	0.08
520.1240234	0.10
522.3306274	0.03
523.6794434	0.03
525.4430542	0.15
526.1600952	0.12
534.2087402	0.62
537.0704956	0.20
538.4336548	3.54
541.5545654	0.04
545.3850708	0.11
551.9891968	0.21
555.3567505	0.37
561.1588745	0.16
565.3274536	3.64
567.5950317	0.11
569.1093140	0.16
579.4221191	3.14
583.3252563	8.34
592.3729248	0.10
593.4018555	0.04
594.7987671	0.26
595.5010376	0.69
597.3663330	8.03
604.1858521	0.09
606.3586426	0.06
607.6239014	0.09
611.4462280	0.15
621.3220825	0.63
623.1263428	0.14
624.3528442	0.13
633.2710571	0.91
634.3829956	0.34
636.0582275	0.22
637.2905884	0.22
639.3508301	0.13
650.5607300	2.12
651.4185791	4.65
652.4687500	1.41
656.2285767	0.15
660.5541382	2.62
661.2673340	0.23
668.4668579	9.22
678.4340210	100.00
679.3776855	0.16
680.5303955	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2133
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1930542	0.06
191.2054291	0.37
193.1040649	0.30
209.0644836	0.15
215.1921692	0.09
220.7012939	0.09
223.2070465	0.08
240.1824493	0.19
245.1340485	0.06
266.9949951	0.25
269.1535950	8.60
293.0884399	24.87
311.1704712	2.78
312.1449585	0.11
323.0154419	0.45
325.2962036	0.07
328.0283203	0.14
329.0509033	0.17
335.1549072	0.32
337.1303101	1.08
341.1546631	1.20
344.0601196	0.15
353.2996216	0.58
356.1102905	0.15
361.3135376	0.07
367.2335205	0.49
368.3461304	0.13
369.1541748	0.27
371.3410645	0.10
372.4788208	0.04
377.1730347	0.17
380.2561646	0.19
383.3869019	0.12
385.2211304	0.33
389.1110229	1.14
394.8809814	0.13
397.3179321	0.79
398.6358643	0.12
402.1517944	0.09
410.9082642	0.52
413.1464844	100.00
414.0546265	0.67
415.2981567	2.71
423.0208740	0.04
427.1731567	0.18
429.1486816	0.13
431.1891479	1.27
432.2937622	0.19
433.2802124	1.65
444.1468506	0.11
447.1996460	0.07
449.3857422	0.23
451.2755737	0.22
455.3688965	0.06
457.2229004	8.07
458.3217773	0.30
461.0186157	0.43
472.3989868	0.15
473.1453857	0.51
475.0957642	0.76
479.4551392	0.24
487.1838989	1.06
489.1043091	0.72
491.4815063	0.05
493.1822510	0.06
515.3253784	0.20
517.3258057	1.62
529.7817383	0.03
531.0081177	1.12
533.1554565	31.56
533.8399048	0.05
535.2987671	0.68
545.3298950	0.18
549.2716064	0.27
559.2261353	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.0957
Annotation	Isoimperatorin
Peak:m/z	Relative Intensity
92.8309097	0.01
104.6987457	0.01
123.2270355	0.02
131.0392303	0.04
175.0910034	0.02
185.1386719	0.01
193.1664734	0.02
202.9878387	100.00
203.7690582	0.01
204.8664246	0.04
215.2051849	0.04
228.9869843	0.41
235.1234283	0.06
243.0992889	0.04
253.0579987	0.41
271.2694397	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	514.1909
Annotation	Unknow
Peak:m/z	Relative Intensity
230.8911743	5.25
233.0678406	4.72
247.1618347	0.32
289.0994873	1.65
298.9275513	1.91
317.0212402	42.28
319.1904907	0.54
320.1959839	1.19
334.7578125	100.00
335.5552979	1.07
340.3249512	0.45
347.1964722	1.10
352.2277222	0.61
409.3560181	0.35
453.4567261	0.73
454.4587402	2.87
490.9202271	0.48
494.1179199	1.24
495.8477173	0.46
496.5119019	7.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.0757
Annotation	Beta-Citryl-L-glutamic acid
Peak:m/z	Relative Intensity
101.9577103	0.07
112.0260544	0.47
113.0999146	0.10
121.1133652	0.16
121.9847183	0.08
129.9294739	100.00
140.9330597	0.05
144.0062256	0.07
144.9931641	0.07
146.0485687	0.07
147.2268066	0.15
148.2076569	0.06
149.9833984	0.02
153.1600647	0.08
156.1828003	0.08
158.1293640	0.22
158.9908752	0.04
160.0454712	0.49
161.9765015	0.23
175.9661560	39.64
179.0464630	1.27
179.9539185	0.08
183.0776367	0.08
188.8491058	0.07
189.9792023	0.50
191.1919556	0.03
192.9870300	59.13
193.8423462	0.04
194.8833313	0.09
207.2298279	0.08
208.9085388	0.02
209.7675781	0.06
215.1314392	0.05
217.0995483	0.10
226.1043701	0.04
229.1465759	0.16
232.1612549	0.09
233.1194153	0.46
235.1124268	0.04
236.1761780	0.03
237.0526733	0.03
240.1145325	0.15
242.4297180	0.03
247.1010132	4.74
248.9353027	0.02
250.3607178	0.11
257.9444885	0.12
259.0867615	0.55
260.1359863	0.49
262.1979980	0.13
263.4226685	0.12
266.0798340	0.13
268.1268005	0.28
271.9762268	0.03
276.1654053	0.66
278.0436707	0.99
286.0220032	1.40
289.6405029	0.03
294.2073975	0.04
302.3239136	0.12
304.1206360	4.91
305.1134338	0.18
334.1412048	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.95933533	0.30
102.9812317	2.31
104.9560852	1.12
115.2110443	0.41
117.9750824	0.78
128.890213	5.39
130.0893097	0.93
131.078598	0.16
147.0184937	0.09
150.9308777	54.25
152.0538788	1.95
152.7911835	0.14
153.9711609	0.42
166.19133	0.34
167.3553314	1.06
169.082489	0.15
179.0291748	5.36
179.8508301	0.45
182.2294159	0.48
183.0668945	0.28
185.1156311	1.15
185.9611664	0.63
190.2232819	0.85
197.1814728	0.94
207.2006378	0.19
211.2265472	0.28
225.1301727	5.47
226.2099609	0.44
238.1277924	7.19
239.0231171	0.73
251.0237885	0.37
253.0910492	100.00
254.2020264	22.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	632.88
Annotation	Unknow
Peak:m/z	Relative Intensity
207.0702209	0.20
212.7958221	0.12
214.1291809	0.06
235.4203033	0.08
253.0638885	0.13
284.3080444	0.08
292.9891968	0.07
294.5893555	0.08
296.7432251	0.33
334.8889160	0.21
370.5115967	0.22
380.7773438	7.23
404.7652588	0.14
419.1663208	0.09
420.9525757	0.25
439.9993286	0.14
452.4965210	0.16
458.0159302	0.25
458.8413696	0.21
462.9770508	0.27
464.6896973	30.95
470.8842163	0.04
480.9489746	0.57
495.0863037	0.21
521.0853271	0.39
546.4180298	1.62
548.5139771	100.00
549.3551636	0.89
564.4396362	0.47
565.3788452	0.11
572.6324463	0.24
586.4905396	0.88
590.9642944	0.50
616.6246948	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	266.98
Annotation	Unknow
Peak:m/z	Relative Intensity
79.0244293	0.05
86.1377716	0.14
89.0459290	0.13
95.0019379	0.65
96.8963623	4.00
112.9948578	9.63
114.0450592	1.88
119.0314941	0.10
131.0289307	100.00
152.9756317	0.05
168.9902496	0.14
180.1074066	0.10
181.1353149	0.09
205.3136749	0.05
223.5203094	0.19
225.9637756	0.13
248.9934540	1.97
250.0696869	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1771
Annotation	Hymenoside E
Peak:m/z	Relative Intensity
168.9913635	0.09
170.9050140	0.16
175.0678711	0.14
183.0711517	0.26
185.0643311	0.27
186.9476471	0.05
195.2704773	0.09
211.1400452	0.68
213.0287018	1.88
227.2682190	0.37
235.1635284	0.06
250.7595062	0.04
255.0246277	100.00
257.1085815	0.03
260.1467896	0.04
260.9295654	0.08
269.1903992	0.19
277.1893311	0.05
279.0856934	6.37
293.1568604	0.26
297.1843872	1.11
317.2639771	0.03
321.2938843	0.24
339.1137085	0.03
343.0449219	0.04
343.7709351	0.02
353.2265015	0.07
359.0630493	0.04
359.9468994	0.03
389.0202637	0.02
398.1106567	0.05
401.3341675	0.45
413.2034302	0.74
415.5615845	0.07
417.0019531	0.15
423.4445801	0.05
443.3960571	0.17
457.3823242	0.01
459.9432373	0.02
472.9110107	0.02
477.2519531	0.17
483.3119507	0.14
489.3456421	0.07
495.2382202	0.04
516.0707397	0.02
519.2492676	0.91
526.8936157	0.05
544.1790161	0.04
545.1969604	0.08
548.2755127	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.056
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.8175163	0.37
58.9905815	6.51
60.8405609	0.73
68.9334717	0.44
70.9529953	7.70
72.8879852	0.72
81.1064224	1.32
82.9222870	2.61
84.8991318	100.00
86.9936218	22.65
92.9761963	42.40
98.9125214	3.55
100.9916229	0.89
107.8309631	0.23
108.9902649	16.16
110.9835815	30.66
113.0664062	1.07
114.9360809	1.05
126.9435425	91.56
128.9441071	3.08
131.0826874	0.19
136.9865570	2.17
143.0634613	1.29
145.1472168	0.38
147.0097351	5.96
153.0850677	4.79
154.8711853	9.78
171.0437775	26.22
172.9948120	88.47
190.9547424	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
95.34401703	0.14
103.0746765	2.03
104.8860321	0.88
107.1121826	1.30
107.8008423	0.15
109.1066589	0.31
122.7575531	0.48
128.906662	7.02
131.9601593	0.23
140.8463593	0.60
141.6504364	0.49
150.9355774	63.22
152.0118866	5.09
155.1141205	0.66
164.1829224	0.28
165.0818787	0.28
166.9998016	4.44
168.9549103	0.51
171.1359406	0.67
179.1365509	1.82
180.1609955	0.27
182.1132355	0.58
185.0250549	1.03
196.0219116	0.32
197.0788879	3.74
198.1572723	0.23
207.1296387	0.56
210.2002563	0.45
211.0858002	0.23
225.0664978	3.98
226.0301056	0.56
235.0028534	0.75
238.0787506	9.66
239.2908783	1.11
253.0934448	100.00
254.1648712	12.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1506
Annotation	8beta-Propionyloxy-10beta-hydroxyhirsutinolide-13-O-acetate
Peak:m/z	Relative Intensity
114.9997864	0.09
116.9573517	2.02
118.8771133	3.73
140.9242096	0.33
142.9905090	44.03
144.9899445	44.47
145.9542236	0.30
155.0294342	0.50
157.1508179	0.24
159.1096039	0.18
160.9315338	1.40
163.0512390	18.14
171.1446838	0.20
181.1449738	0.19
186.9664612	100.00
188.1880341	0.20
200.8167725	0.14
203.1335144	0.15
204.9580078	0.31
217.1564026	0.12
221.1337891	12.00
231.2431030	0.42
245.2263794	0.14
247.3452454	0.10
262.2330322	0.06
289.0560303	25.95
349.2810974	16.72
367.1174011	15.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	700.275
Annotation	Unknow
Peak:m/z	Relative Intensity
201.9378357	3.11
202.8438873	13.28
204.2450562	13.84
329.0504150	19.29
386.0975952	14.03
396.1221924	9.81
462.8734741	6.22
495.3596802	28.63
530.5125122	10.86
563.5004272	26.79
564.2052612	1.63
583.5887451	5.04
587.5461426	1.82
631.6391602	100.00
632.4276733	10.03
642.7182617	0.99
724.1314087	6.15
787.9752808	13.70
789.9788208	8.05
797.9797974	3.44
923.2156372	21.82
924.0807495	18.94
925.0283813	21.83
926.3878784	3.22
932.9492798	12.79
934.1430054	4.21
935.9091797	7.37
989.1020508	3.90
989.7113647	1.35
990.6589355	2.72
1061.0280760	9.27
1061.8537600	5.43
1062.6069340	5.92
1069.7985840	3.18
1125.1301270	2.89
1125.8320310	1.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0671
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
102.8290100	0.04
110.9949799	0.80
128.9900665	1.58
133.1174316	0.12
134.0903625	0.16
136.1422882	0.06
147.0433960	4.26
162.9312439	0.37
173.0197601	2.52
178.0396271	0.05
190.9643707	100.00
192.9621887	1.23
209.0563354	36.04
216.1945190	0.04
217.1164856	3.36
259.3339844	0.14
265.1308594	0.09
292.7673950	0.30
308.9487915	0.04
311.0017090	0.07
318.8655396	0.23
327.0841370	0.42
337.0524597	9.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	811.3777
Annotation	Unknow
Peak:m/z	Relative Intensity
228.2127228	0.12
238.2815247	0.16
242.2845459	0.71
243.1132507	0.26
244.1319885	0.08
252.5652466	0.10
259.2005005	0.84
260.2709045	0.47
263.3416443	1.10
264.2594910	0.18
265.1310425	0.26
266.3708496	0.11
267.9716797	0.30
269.3087769	0.35
278.2971802	0.28
280.4072266	0.46
281.0702209	0.88
282.1292725	0.11
283.2198486	0.37
284.3632812	0.21
286.1082764	0.13
295.1449585	0.40
296.1230469	0.19
297.2092285	0.15
299.4249268	0.33
302.5491333	0.35
303.2206421	0.48
304.0472412	0.11
311.2478333	0.24
315.1921082	1.21
317.2740479	0.06
318.3158875	0.05
320.1742554	0.60
321.9750671	0.16
322.6342468	0.05
323.3861694	0.11
324.4015503	0.38
326.5063477	0.18
332.3693237	0.12
336.8885803	0.42
338.1187134	0.88
340.1333618	2.17
341.2806396	1.05
342.2858582	0.47
343.2169800	0.12
343.9713745	0.17
346.2077637	0.22
350.2270203	0.05
351.1454468	0.32
352.3317261	0.32
353.2723999	0.10
355.4869080	0.34
356.3372498	0.25
357.1472168	0.40
358.9639587	0.18
360.1159058	0.32
363.2519531	0.48
369.1148071	0.26
370.1918640	0.21
371.6287842	0.14
372.7966309	0.23
374.6481934	0.19
376.0789185	0.13
377.3084717	0.41
378.1872559	0.23
380.3118286	0.12
381.3428345	0.19
382.5345459	0.59
384.3204346	0.60
385.4332275	0.07
386.1582031	0.13
390.3286743	0.25
393.2360229	0.39
394.3387451	1.77
395.2655029	1.12
396.4086304	0.14
398.2128906	2.32
400.1007080	2.85
401.2205200	0.73
402.4329224	0.25
403.5388184	0.27
409.4328613	0.15
410.5800171	0.13
411.3150024	0.19
412.3264160	7.67
413.3612671	9.07
414.2863770	0.57
415.3101807	0.15
417.2552490	0.21
426.3536987	0.07
428.3773804	0.88
429.1417847	0.53
430.3647461	0.27
432.3750610	0.25
433.3123779	0.12
434.0900269	0.07
437.2212524	0.19
438.7317505	0.15
442.8864136	0.10
444.4140625	0.10
445.1898193	0.27
448.3495483	0.29
449.6148682	0.07
450.4133911	0.19
451.1599121	0.28
452.3688965	1.03
453.2829590	1.16
454.3217163	0.59
456.4869385	0.32
465.6951904	0.77
466.5474243	6.02
467.3858032	2.25
469.2925415	11.66
470.4476929	15.07
471.3150024	0.65
481.3742065	0.74
484.4101562	0.18
485.3156128	0.81
486.2507324	1.23
487.3786621	1.50
488.3572998	0.13
489.1811523	0.32
493.1793213	0.08
497.3785400	0.06
500.3175659	0.10
503.3245850	1.01
504.3920288	1.71
505.6710815	0.29
506.4013672	0.49
507.2175293	0.15
509.2329102	0.58
513.3652344	2.74
514.2650757	3.62
520.3181763	0.07
523.3100586	4.66
524.2565308	7.19
525.3806152	0.69
526.1983643	0.17
528.2319946	0.28
529.1487427	0.07
530.1304932	0.48
531.4265137	0.19
532.2910767	0.20
539.1890259	0.33
541.8657227	0.25
542.6643066	0.21
550.5374756	0.13
555.3605957	0.30
556.5155640	1.39
557.5745239	0.48
558.3248901	0.26
560.2723999	0.16
566.5046997	0.99
567.2797241	1.91
568.4861450	0.18
571.4511719	0.21
572.3604736	0.11
573.3644409	0.13
574.4308472	0.12
575.6196899	0.24
579.3568726	0.52
580.4069214	3.31
581.3889160	5.05
582.4354248	0.54
583.4685669	0.57
584.4781494	4.30
585.3894043	5.39
586.1810303	0.49
590.7141724	0.26
594.4166870	0.45
595.2267456	0.76
596.2418823	0.20
597.3262939	0.17
599.2648315	4.64
600.3783569	8.84
601.4682007	0.74
602.5148315	0.25
605.2918701	0.49
609.5045776	1.24
610.4066772	1.32
612.2609253	0.77
614.0419312	0.10
616.6931763	2.87
617.5007935	3.16
618.3994751	0.32
621.2445679	3.85
622.3995361	0.08
624.2545166	0.41
625.3623047	0.45
633.7389526	0.33
635.9601440	0.17
636.5761108	1.34
638.4137573	7.28
639.3286133	10.71
640.2186890	0.82
642.3490601	7.39
643.3706055	17.78
644.1856079	0.28
651.7042847	0.15
653.2426147	3.17
654.2066650	1.87
654.8159180	0.18
655.6716919	0.58
667.3225708	0.12
669.7717896	0.43
671.3392944	2.20
672.3322754	0.66
682.4789429	0.04
683.3891602	0.31
691.1889648	0.09
695.3677979	14.11
696.4369507	37.55
697.6008301	2.22
706.7554932	0.37
711.1986694	0.05
713.3923340	31.50
714.3962402	100.00
715.5537720	4.17
724.1398315	2.94
724.7548218	0.05
725.4450073	1.01
733.3389282	0.12
739.4345703	0.46
749.5084839	3.55
750.4456177	14.11
751.2296753	0.26
761.1809692	0.37
767.4131470	14.80
768.4188232	71.84
769.4880981	1.74
794.2412720	0.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2007
Annotation	Unknow
Peak:m/z	Relative Intensity
147.1647644	0.23
162.9749603	0.79
167.1177826	0.14
169.0599518	0.16
186.8430481	0.24
204.2207642	1.09
209.0302124	0.60
210.2458344	0.49
213.0501404	11.73
227.0275269	0.31
231.1452484	5.61
245.0776367	0.20
249.0415649	2.10
253.0692139	0.36
262.8126831	0.35
268.9575195	0.73
273.0900269	0.88
277.0437012	0.23
287.3190308	0.05
289.0809937	0.38
291.0182495	5.35
295.1931763	0.59
305.0346069	0.51
313.1215210	2.68
330.8902588	5.48
331.5058594	0.03
332.8403320	0.65
339.3428955	0.19
348.5109863	1.54
349.1428223	14.39
350.9749756	0.28
352.1326904	0.09
356.9451904	7.77
364.1963501	0.14
366.9727783	7.98
368.5095215	0.28
374.9967041	73.08
379.3142700	0.18
391.1925659	2.18
393.0459595	100.00
424.6569214	0.17
427.3443604	0.17
430.8785400	1.08
433.1895752	0.39
434.1036987	0.57
447.1628418	0.11
450.9989624	1.22
457.0291748	0.93
460.6646118	0.08
467.3453369	0.74
475.0452271	17.74
475.9069824	0.18
480.8901978	0.34
484.4448242	0.25
490.2319946	0.08
493.0368652	97.98
494.0656738	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.2195
Annotation	Unknow
Peak:m/z	Relative Intensity
268.9440613	0.14
283.3894043	0.10
287.0581665	29.85
310.8987427	0.09
335.2031555	0.05
342.2713623	0.04
352.8784180	0.05
371.0557861	0.03
383.2689209	0.07
385.4442749	0.04
396.2642822	0.02
414.0997925	0.02
431.0459595	0.06
449.1243896	100.00
450.3756714	0.03
456.4595337	0.04
459.0949097	0.11
475.2369995	0.03
491.3735352	0.05
503.2703857	0.16
504.2019653	0.39
509.2070923	0.06
517.1456299	0.11
551.1558228	0.07
568.3764038	0.03
573.2763062	0.08
576.4768677	0.08
593.2173462	1.77
594.4042358	7.92
595.3012085	34.68
606.7382202	0.11
613.2337646	0.13
621.2196655	0.67
631.2734985	0.03
634.9966431	0.02
636.4140015	0.11
637.4723511	0.09
655.3800049	0.07
666.3135376	0.15
667.4473267	0.25
669.4765015	0.05
711.3073120	0.03
712.7305908	0.04
713.5277100	0.07
726.5963135	0.06
738.9796143	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	350.1588
Annotation	5,8-Dihydroxy-7-methoxyflavanone
Peak:m/z	Relative Intensity
106.8491974	0.06
108.9532013	0.02
110.9449921	0.08
115.0472107	0.03
117.0034027	0.10
120.8878479	0.06
123.0324860	0.03
130.8996429	0.03
134.9313354	0.09
143.0384216	0.04
147.0552979	0.07
149.1246643	0.03
150.3424377	0.06
151.0616760	0.02
155.9624939	0.05
156.6492310	0.02
162.6104126	0.06
164.1500854	0.06
169.0653534	0.02
174.0581055	0.12
175.1381378	0.03
177.0626068	0.06
187.1492004	0.10
188.2085876	0.02
188.9970703	0.02
193.2004395	0.02
196.9875031	0.05
198.1266022	0.02
199.0187836	0.02
203.0830994	1.64
209.2584076	0.03
210.2734528	0.02
223.0717163	0.05
233.0071716	0.08
236.5332031	0.07
241.2184143	0.08
245.1768494	0.13
249.1286011	0.05
251.1622009	0.15
262.1054077	0.02
262.9061279	0.04
269.0726318	8.30
270.8490906	0.18
278.1764526	0.04
281.9299622	0.05
283.5838013	0.03
286.9898071	100.00
287.6054688	0.57
291.2383423	0.02
294.4076538	0.06
301.4819946	0.04
304.1856689	0.11
305.2199097	0.03
306.1081848	0.07
307.1715698	0.04
308.2786255	0.04
314.2656555	0.11
315.2655945	0.11
316.4143982	0.06
317.4987183	0.25
318.8297119	27.98
319.5110168	0.13
320.1557922	0.08
320.7629395	0.02
329.6170044	0.12
331.6970825	0.24
332.3559265	0.54
333.0456848	0.18
338.5769653	0.07
350.4562073	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.2049
Annotation	Tomentodiplacone B
Peak:m/z	Relative Intensity
128.0222778	0.07
128.9921875	0.26
132.9514160	1.30
134.8578491	0.13
137.1255188	0.63
138.8131104	0.57
140.0571136	0.07
141.1166382	0.58
143.1465759	0.11
144.4520264	0.76
145.2204132	0.46
147.0640869	0.80
149.1441040	1.49
151.0722351	1.13
153.0766296	0.81
156.9869080	1.30
158.0064545	0.19
159.0287476	0.89
160.9871826	24.03
161.9778137	0.14
162.9775696	1.78
164.8328552	0.34
167.1535492	0.12
168.9288025	0.95
171.2230377	0.24
172.3356934	1.11
173.1128387	2.06
175.0163422	4.43
177.0355682	1.40
179.3644257	0.37
181.2561646	0.16
181.9499512	0.62
183.1427612	0.15
185.1380310	1.71
187.0751038	8.92
189.0580902	1.66
190.9708252	1.24
192.8270569	0.26
194.9843140	0.24
197.1460266	0.14
198.9902649	2.53
201.0191193	2.77
203.1460876	1.68
205.1620178	0.74
207.2534027	0.39
209.1492615	1.23
211.1651306	0.34
213.1757660	2.27
213.9925995	1.66
215.2038116	5.14
217.1585541	2.00
218.9248352	1.85
222.0130615	0.35
223.1708374	1.08
225.1737213	3.42
227.1336365	3.17
228.2026062	0.24
229.0322876	1.54
230.1820984	0.46
231.3008423	2.48
233.1146088	1.00
235.3675079	0.42
237.1099854	2.39
239.0701904	2.03
241.1790314	3.19
243.2204590	4.73
245.1585999	2.40
246.2062683	0.23
247.1987305	0.75
249.2083130	3.29
251.0685425	2.04
252.0473022	1.10
253.2314148	2.12
254.0389404	0.86
255.1097717	1.14
257.3690491	0.74
259.2365417	1.64
261.0782166	2.60
263.1751099	3.33
264.0482788	0.28
265.3921509	2.83
266.2645569	0.22
267.0762024	1.73
269.1610718	5.51
270.9818726	2.26
273.0082703	3.27
276.1513062	0.16
277.2406311	2.13
278.1427002	1.07
279.0933533	2.55
281.1788635	2.51
282.0838013	0.49
283.0703735	0.77
284.1585693	0.14
285.2048340	1.57
286.2640991	0.38
287.2646484	4.49
289.3196411	0.80
291.1627808	1.43
292.4247742	1.20
293.1975708	4.77
294.1124878	1.73
295.2321777	2.54
297.2224731	7.56
298.4041748	0.11
299.3967896	0.14
300.6397095	1.34
301.3478394	1.12
303.1983643	4.27
304.1621094	1.02
305.2164917	4.49
306.9838867	1.48
309.1567383	5.42
311.2496338	3.49
313.3142090	8.54
315.1745300	29.24
315.8463745	0.18
317.2434082	3.02
319.3071899	2.00
321.1807556	4.47
322.6015625	0.22
323.2194824	4.83
324.2644958	0.72
325.1743164	0.92
327.0184326	1.15
328.6751709	0.27
329.2767944	1.25
330.1975708	0.97
331.0837708	10.86
331.8910522	0.92
332.6527710	1.15
333.3105469	5.43
334.6831665	0.64
335.2864380	1.73
336.5263672	0.73
337.1602478	4.66
339.2011108	2.90
340.3662109	1.98
341.2129517	7.06
343.2869873	0.68
345.1105652	1.33
346.3079834	1.08
347.3731689	3.97
349.1264343	8.13
350.1820374	2.64
351.3156433	7.46
353.0434265	0.88
354.3658447	0.23
355.0578308	1.07
357.2698975	12.24
358.5681763	0.81
359.2312317	5.69
361.0917358	1.14
362.1429749	0.12
363.1594238	2.80
365.2892456	9.86
367.1585693	2.24
368.4316101	0.46
369.3877563	0.54
371.2669983	0.66
373.2157898	2.29
375.2713928	12.61
377.2023010	12.75
379.2801819	1.13
381.1425476	7.40
383.2908630	0.94
384.6232300	0.32
387.3183289	2.38
389.1394958	0.25
391.2510681	15.01
393.2903137	36.85
395.1722107	4.47
399.4893188	0.22
401.2695618	7.07
402.3596497	0.17
407.3377380	0.31
409.2145081	100.00
409.8363342	0.32
411.3294983	67.45
412.2350769	0.09
412.9548035	0.17
419.1941833	16.67
427.3130798	4.95
437.3084412	35.86
438.1758423	0.16
455.2101135	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	797.2084
Annotation	Faratroside
Peak:m/z	Relative Intensity
229.0546722	0.03
231.0267029	0.06
232.8868561	0.02
241.7849274	0.01
243.2067413	0.12
244.0396729	0.09
245.0260010	0.07
246.7119141	0.01
253.0284119	0.26
256.8391418	0.08
258.0762939	0.19
259.2461548	0.01
260.2488403	0.05
261.0084839	0.17
261.6146545	0.02
269.0645447	0.04
270.9233093	0.80
272.0628357	0.59
273.0789185	0.33
274.8945923	0.03
276.1876831	0.04
282.8328857	0.01
285.0734253	0.06
286.1350708	0.23
287.1550598	0.18
289.0157471	1.17
289.9262085	0.04
295.1672974	0.02
297.1339722	0.03
300.1533203	0.85
301.0236206	1.80
303.1646118	0.27
304.2389526	0.30
307.0184021	0.44
313.0625610	0.22
314.2176819	0.41
315.1742554	0.78
316.5507812	0.08
317.1511841	0.76
317.8946228	0.03
319.2239990	0.03
329.2180786	0.07
331.1129150	0.22
332.1679077	10.75
340.1231079	0.07
343.2152100	0.03
343.9901733	0.05
345.0942993	0.47
347.0715942	100.00
347.6981812	0.57
348.3082275	0.01
349.1616821	0.16
351.3872375	0.02
361.3243408	0.06
370.9513550	0.11
379.1706543	0.14
387.3101196	0.03
389.2410278	4.85
397.0788574	0.23
397.6895752	0.01
399.2552490	0.01
413.2515869	0.10
414.5667114	0.05
415.1770630	0.41
425.4128418	0.04
433.0524902	3.67
437.1161499	0.51
443.0068970	0.09
449.2791748	0.02
450.9479980	0.20
455.1977539	1.74
557.0390625	0.03
569.3890991	0.03
580.9172974	0.02
599.1978149	0.28
607.4928589	0.05
617.0282593	0.40
624.3381958	0.01
635.0130005	0.34
653.0966797	0.31
667.4017944	0.01
677.2929688	0.03
698.8168335	0.03
701.2653809	0.03
717.6022339	0.05
721.1086426	0.01
724.9008179	0.03
729.1516724	0.01
734.4668579	0.02
743.1799316	0.07
751.5136108	0.08
761.0541992	1.02
779.1740723	6.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1509
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
173.2359161	0.02
174.1249084	0.08
175.0976562	0.52
175.8862305	0.05
185.1428375	0.09
187.0430756	0.03
193.2056427	0.09
195.0326538	0.15
197.0297546	0.12
198.067688	0.09
199.0666656	0.46
200.1635895	0.03
211.062439	0.09
212.9303894	0.20
215.0100861	0.14
217.0808105	0.74
217.9836731	0.08
222.2166748	0.02
229.2138672	0.11
230.1408081	0.06
239.9932098	0.11
241.1255493	0.39
242.330246	0.02
243.0417786	0.20
255.8582153	0.07
257.2227173	0.14
258.3933716	0.06
267.2658691	0.07
281.2665405	0.04
283.4874268	0.18
285.0476685	100.00
286.085022	3.85
298.1013184	0.10
299.152771	0.35
307.2120361	0.05
308.1905518	0.26
309.0655518	0.03
311.2985229	0.13
323.1323853	2.21
323.9746094	0.04
325.1206055	0.02
327.1414795	0.82
339.0234375	0.15
341.2042847	2.69
352.5904541	0.13
353.2518921	0.06
365.2263184	0.04
367.1012573	0.12
369.2988281	0.10
371.1986084	0.49
383.2241211	0.44
385.2142334	0.23
394.9252319	0.03
428.0405884	0.04
429.1392212	0.03
443.2264404	22.73
444.2994385	0.04
447.2785034	0.53
449.2772827	0.04
455.4100952	0.05
461.2618408	0.19
463.1885986	0.65
473.1663208	1.16
503.2404175	0.26
575.3208008	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.1571
Annotation	Planusin A
Peak:m/z	Relative Intensity
127.0519943	0.11
129.8946228	0.24
130.9832764	0.06
141.1365967	0.05
152.3036957	0.04
162.0939331	0.15
167.3377991	0.09
168.0268250	0.04
173.0826111	0.15
178.0536194	0.03
182.0676575	0.13
183.9919128	0.65
192.0465088	0.20
198.1694183	0.09
198.9706421	0.18
202.1613007	0.21
208.1893768	0.06
209.1567688	0.15
209.9041138	0.13
214.9734955	0.05
216.1658020	0.19
219.0005035	0.03
223.0788269	0.16
227.1171570	0.12
229.0543518	0.29
230.1615448	0.10
231.1310425	0.20
232.2952576	0.03
239.1130066	0.06
244.2187500	0.22
245.1712036	0.12
246.1231079	0.07
248.9492798	0.10
254.9637451	0.19
256.0389404	0.16
260.3616333	0.07
261.0991211	0.24
262.1498718	0.31
265.1797180	0.04
266.3840332	0.15
267.1378479	0.13
268.3484497	0.24
268.9646912	0.08
271.2396240	0.64
274.1375732	1.61
276.1869507	0.35
279.1351318	0.10
280.2838440	0.09
283.0399475	1.48
284.1239014	2.27
285.0930176	3.91
286.2353210	0.32
287.1615601	0.08
288.8293762	0.11
290.3129883	0.03
293.0508423	0.19
294.1134033	0.09
295.1750488	0.09
302.2330322	27.03
311.1165161	87.79
312.3295288	0.77
313.2226562	10.10
318.0609436	0.18
320.1317444	3.71
321.1954041	0.12
323.1380920	0.03
324.1699524	0.21
327.1052856	0.13
330.1980591	28.10
332.1541748	0.14
333.2331238	0.09
334.1288757	0.18
337.5752258	0.03
340.8805847	0.38
345.0815735	0.26
346.2247925	0.11
348.2483521	1.22
349.1266479	0.05
350.4179077	0.06
353.2426758	0.22
357.3041382	0.35
359.1474915	3.09
361.1591492	2.97
363.0215454	0.06
366.5111389	0.14
367.4107361	0.38
369.2483215	0.74
372.2810364	0.09
377.1955261	15.23
381.2667542	0.06
387.1839294	5.32
388.2140198	0.19
391.0560303	0.24
397.2583313	0.10
405.1769104	100.00
406.2260132	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	753.1851
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1716766	0.11
214.9540405	0.03
218.8464661	0.04
226.8800812	0.05
227.6093597	0.13
229.0539093	0.74
238.2880859	0.04
239.2474060	0.08
241.2076874	0.10
246.7960510	0.04
252.9468689	0.11
257.0333557	1.76
270.9902954	2.61
273.3067322	0.33
274.3181152	0.09
281.2619324	0.27
285.0447388	1.29
288.9543457	1.49
291.3469238	0.14
292.4295959	0.08
299.1416321	0.29
303.0928955	100.00
303.9289246	0.07
307.0950317	0.88
313.1334534	0.14
315.2222290	0.25
315.9494019	0.25
317.1821594	0.08
322.0271301	0.04
323.9329834	0.27
325.0942993	0.22
327.2803345	0.85
331.2293701	0.14
333.7866211	0.10
335.3418884	0.04
337.1329041	0.09
337.7533264	0.09
342.2645874	1.46
343.2474670	0.35
345.0897827	11.63
347.3246460	0.03
349.0737305	0.23
354.9103394	0.11
360.0911865	0.18
360.9982605	0.22
369.2276611	0.12
370.2512207	0.13
371.0346069	0.05
374.8216553	0.24
379.2703857	0.43
381.9882202	0.07
387.4290771	0.04
391.7743530	0.08
393.1681519	0.92
393.9279785	0.05
395.0808716	0.06
396.5806885	0.31
397.1982422	1.07
399.0813599	0.17
409.1332397	0.04
411.1704712	3.02
415.0471191	0.95
427.3988037	0.10
428.6409912	0.10
430.6642456	0.08
433.1607056	11.03
435.2581177	0.07
443.3801270	0.14
444.1996460	0.14
445.0514526	0.04
446.6760254	0.07
451.2636108	0.77
453.2579956	0.11
457.2741699	0.10
469.4317017	0.07
471.0135498	0.08
475.2515869	0.21
478.0601196	0.17
487.4390869	0.13
489.2947388	0.23
495.8051147	0.05
496.4727173	0.05
497.2251587	0.21
510.2155762	0.08
513.3513184	0.27
514.3902588	0.06
515.3504028	0.23
524.4720459	0.22
527.0954590	0.21
528.9614868	0.12
536.5819702	0.24
537.2664185	0.16
543.4634399	0.06
549.4498291	0.16
554.3427734	0.17
555.2059326	0.29
569.5541382	0.16
571.5234985	0.15
572.9994507	3.35
588.1005249	0.04
589.0823364	0.40
589.7879028	0.12
591.2075806	1.79
598.8074951	0.10
601.1229248	0.21
602.5913696	0.07
608.2794189	0.29
609.3407593	0.11
619.2504272	0.04
626.1545410	0.16
627.6936035	0.13
628.4744263	0.09
633.0671997	0.28
648.4563599	0.08
662.0391846	0.19
662.6602173	0.18
667.2549438	0.12
672.3360596	0.81
673.2003784	0.50
691.2983398	0.29
699.0409546	1.01
706.3709106	0.05
708.3582764	0.44
709.4016724	0.12
715.9636230	0.16
717.0912476	3.58
732.0855103	0.09
734.5442505	3.84
735.2536621	11.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	685.1984
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
191.3386841	0.04
201.0942841	0.02
202.9158783	0.05
217.1178741	0.27
235.1269531	9.40
259.2699585	0.07
277.4901733	0.13
285.4093628	0.07
287.0180054	0.05
288.8099365	0.02
294.9550781	0.03
311.0825806	0.29
317.2395020	0.10
318.3914795	0.06
325.3057861	0.11
327.5824585	0.04
336.0869141	0.10
370.4292603	0.03
373.4633789	0.03
375.1832275	0.06
377.3151855	0.05
379.2265625	0.95
383.2734375	0.04
397.1975708	49.25
399.9184570	0.10
403.4263306	0.08
415.3463745	0.04
417.3364868	0.05
421.3811035	0.25
431.2269287	0.05
439.2058105	12.06
448.2885742	0.05
455.4714966	0.06
461.2470093	0.07
478.0112915	0.04
479.2145386	2.62
481.0793457	0.89
493.3096313	0.04
496.2869873	0.09
505.5724487	0.03
519.2413940	0.21
521.2421265	0.52
523.2653198	0.24
530.0357056	0.04
538.2753296	0.07
539.3936768	0.06
541.2007446	100.00
549.3117065	0.09
558.5879517	0.06
561.4542236	0.04
563.1403198	0.18
566.1487427	0.02
575.2526245	0.04
580.0625610	0.05
583.1394653	8.19
583.7632446	0.07
596.0559692	0.03
623.1930542	0.42
625.4262695	0.07
638.1054077	0.07
639.5778809	0.10
641.3214111	0.47
648.5334473	0.04
649.6730347	0.13
652.3602905	0.22
655.2485962	0.03
657.1195068	0.43
663.2951050	0.10
667.2468262	1.31
692.9811401	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.1544
Annotation	Trilobatin A-1''-methyl ester
Peak:m/z	Relative Intensity
189.1567078	0.10
208.1547852	0.05
250.7244110	0.08
266.5102539	0.04
270.9535217	0.06
311.4035645	0.11
324.8604736	0.10
326.1471558	0.12
337.0999756	0.06
341.2012329	0.03
360.9454346	0.13
376.3845215	0.16
379.2095947	2.94
391.1098633	0.18
395.4053955	0.07
396.7954712	0.15
397.4960938	0.10
400.3759155	0.13
403.2568359	0.15
409.2097168	3.53
415.2838135	2.45
421.1154785	2.30
427.2032471	2.12
433.3425903	0.49
437.0629272	0.06
439.2370605	4.12
445.2201538	0.89
447.0372925	0.63
451.3011475	0.05
457.1862183	100.00
461.3663940	0.10
462.2529907	0.30
463.2796631	0.77
464.5394897	0.09
474.9709473	0.09
478.9041748	0.05
481.2534180	18.69
486.9860229	0.13
493.1925659	1.50
499.1463013	22.46
499.7585449	0.08
502.3467407	0.07
505.1590576	0.56
507.0719604	0.35
511.2255249	29.24
517.0386353	0.03
523.2611694	18.27
529.1036987	36.29
529.7644043	0.40
533.4423218	0.57
541.1433716	25.64
541.7573853	0.11
557.2257690	0.06
559.1428833	81.27
559.7683716	0.40
568.5709839	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Diosmin 
Peak:m/z	Relative Intensity
198.0184326	0.03
237.8790283	0.02
256.1580811	0.37
284.0606079	30.40
284.7015686	0.09
297.2246094	0.03
299.0484009	100.00
299.9033813	0.09
326.0272827	0.05
341.1383057	0.14
463.4130249	0.02
490.4714966	0.02
505.060791	0.13
528.8831177	0.01
589.2181396	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1047.2625
Annotation	Unknow
Peak:m/z	Relative Intensity
301.2665405	0.03
305.1663818	0.67
315.1537476	1.08
326.4427795	0.08
431.1578674	0.27
449.1914978	0.30
477.1848145	1.90
503.0957642	0.06
519.2299194	2.09
549.4342041	0.06
559.2077026	0.87
561.0782471	0.68
571.1621094	0.09
583.2269287	0.57
597.1788330	84.62
601.1540527	0.18
603.3431396	0.06
621.2264404	9.65
623.3090210	0.16
639.0299072	0.14
661.4676514	0.10
663.2471313	3.70
675.2344971	0.06
692.7781982	0.15
693.4196167	0.03
703.1887207	0.67
705.1640625	0.21
740.9855957	0.24
745.2335815	0.09
756.4309692	0.06
758.5256348	1.32
759.1338501	11.90
765.0461426	0.98
783.1563721	0.14
800.9722900	7.92
801.6354980	0.32
805.7545166	0.19
825.4396973	0.08
841.0592041	2.07
841.6944580	0.05
843.0273438	0.96
843.6287842	0.17
855.4492188	0.08
870.9975586	0.09
882.9616699	0.61
885.1190186	0.30
885.7849121	0.04
903.1298828	100.00
903.8809814	0.18
923.2285156	0.12
926.8610840	0.19
945.0670166	12.54
945.6960449	0.08
985.0092773	3.57
986.9133301	0.13
1029.0734860	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0773
Annotation	Acerosin
Peak:m/z	Relative Intensity
120.9038162	0.30
122.9921494	0.96
124.9799500	0.56
129.1775208	0.13
139.0005798	0.85
147.9955139	0.21
149.1487732	0.32
153.1702881	0.20
166.9519653	100.00
167.5852966	0.13
172.9344940	0.09
173.7547607	0.14
182.0482635	0.09
187.2082367	0.28
191.0249176	0.71
193.1042938	0.22
195.0646057	1.06
195.9360657	0.09
197.1231842	1.49
199.1142273	0.47
205.0791168	0.14
206.1159058	0.16
209.4943237	0.16
213.1465759	0.20
216.7576904	0.57
220.9956055	0.44
222.2341614	0.16
223.0320129	0.07
224.2336426	0.19
227.3235779	0.16
239.0115662	0.25
241.2158813	0.23
242.1145020	0.19
257.4388733	0.14
262.9455872	0.09
282.2899780	0.18
285.4042358	1.00
286.8428955	1.06
287.6376953	0.16
289.1788635	0.49
292.7306824	0.13
297.0989990	0.19
298.3516235	0.20
299.0489197	0.09
305.4149475	0.12
311.9978027	0.16
312.7927246	0.25
313.4344482	0.18
315.0134888	0.47
317.1964111	0.18
328.3707275	0.20
331.2266846	1.21
341.2917480	1.60
344.3859863	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	913.2609
Annotation	Unknow
Peak:m/z	Relative Intensity
256.0946350	1.05
284.0418396	20.33
285.1954041	0.18
287.0382996	0.96
299.1573792	60.37
301.0245056	0.49
311.0413818	0.08
341.0917053	0.11
342.2407837	0.31
409.4759827	0.31
411.3077393	0.28
429.1495361	0.40
431.2821655	0.23
440.9667358	0.14
443.1138306	0.65
449.1337891	2.58
454.4476929	0.38
461.1809082	33.48
463.0427246	0.15
503.1038208	7.07
529.6783447	0.05
543.1529541	2.79
544.7712402	0.27
555.1589355	0.19
587.1572266	0.90
592.8595581	0.11
595.3993530	1.66
605.2829590	6.24
607.1545410	100.00
607.8523560	0.10
609.2305298	0.87
625.4196167	0.36
649.1973267	6.14
689.3256226	0.68
707.1704712	0.13
725.3589478	0.16
735.4828491	0.36
751.2128296	1.01
757.0447388	0.34
768.3051758	0.15
769.2523804	1.51
793.3358765	0.34
800.7489624	0.06
809.5440674	0.26
826.8298950	0.06
839.3931274	0.21
848.2508545	0.09
867.3460693	0.16
869.3994751	0.06
876.2931519	0.57
891.4234009	0.79
895.3629761	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	773.2144
Annotation	Butrin
Peak:m/z	Relative Intensity
221.2097626	0.21
236.7804260	0.16
245.0133667	1.21
269.0857544	0.24
286.8434448	0.29
301.2404785	0.37
302.1219177	0.41
303.0000305	0.10
305.1735229	1.44
314.3139038	0.18
314.9603882	0.08
334.2643127	0.06
335.4437866	0.15
338.8709106	0.36
346.9486694	0.83
357.0911255	0.33
383.1166992	0.29
385.2080078	0.25
388.9345703	0.39
402.8766479	0.07
404.6271973	0.75
407.0940552	2.03
415.1046143	0.10
416.1757202	0.14
423.0682373	1.70
430.0839844	0.21
430.8588257	0.59
438.2072754	0.15
445.5559692	0.12
447.3886719	0.10
448.8218384	1.75
460.3040161	0.04
461.3785400	0.05
462.1664429	0.56
463.2769165	0.05
464.9257812	0.64
467.0940552	100.00
479.2307129	0.16
480.8762817	0.14
483.9126587	0.11
485.4414673	0.23
486.9598999	0.25
492.3685913	0.16
497.3600464	0.61
503.2260132	0.60
508.2122803	0.44
508.9238281	13.43
515.2731323	0.06
517.3052368	0.16
526.5158691	0.34
538.8453369	2.63
547.0698853	0.29
549.2253418	1.37
551.2030029	3.70
565.2852173	0.17
567.1652222	0.15
568.8566284	7.95
569.5471802	0.23
572.7384644	0.07
575.4041748	0.37
581.4440308	0.38
591.3292847	0.07
592.7800903	0.11
593.5169067	0.10
595.6998901	0.11
598.9632568	0.40
605.2454224	0.21
607.1729126	0.46
609.2625122	5.14
610.5095215	0.55
611.2235718	12.87
623.2282104	0.39
627.2883911	0.77
628.8986206	4.04
629.6582031	0.18
635.4310913	0.46
652.3057251	0.58
654.9605103	0.25
660.3118286	0.07
682.7783813	0.44
683.3914185	0.76
687.0979614	0.16
711.1123047	0.10
713.1231689	6.32
728.3917236	0.23
729.1098022	1.04
742.2577515	0.21
755.1517944	0.67
763.4154053	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.3651
Annotation	Phaeofuran B
Peak:m/z	Relative Intensity
336.9689331	0.13
348.3406677	0.02
361.2867126	0.01
367.0406494	0.05
405.1699219	0.02
413.2192383	0.02
429.1264038	0.10
429.7723999	0.05
441.1758423	0.02
457.4083862	1.51
458.8588257	0.01
475.5208740	0.08
489.5191650	0.01
491.4244995	0.05
499.3573608	0.25
517.0532227	0.01
529.1163940	0.11
539.2032471	0.02
541.4677734	0.14
549.5449219	0.22
551.1521606	0.02
553.2026367	0.02
559.3256226	0.05
560.9706421	0.15
561.5932007	0.00
563.3064575	0.03
573.6608276	0.16
575.5025024	0.32
577.1618042	0.39
577.7976685	0.03
591.3692627	2.58
592.0053101	0.01
593.4710083	0.04
595.4677124	0.22
598.5490112	0.02
601.2268677	0.18
605.0684204	0.02
607.5811157	0.01
615.1562500	0.04
619.3643188	100.00
620.2676392	0.02
623.4254761	0.02
627.2158813	0.08
635.2841187	0.01
637.4031372	6.31
651.3363037	9.00
651.9509888	0.18
669.2622070	8.42
679.3095093	15.61
680.1699829	0.01
681.2122803	0.02
693.2839966	0.08
697.3922119	8.05
698.0028687	0.01
710.7948608	0.82
711.4131470	9.59
713.3530884	0.19
725.2465210	0.04
735.8341064	0.05
739.5903320	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1982
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
257.2273254	0.07
273.4473267	0.05
339.2783203	0.09
341.1826782	0.03
343.0554810	0.06
367.1933594	0.27
369.1500244	5.51
370.1171265	0.18
379.3333130	0.13
383.3667603	0.10
397.2261353	0.15
399.1939697	4.43
411.2655029	0.63
412.8466187	0.04
413.4719849	0.02
418.2720337	0.08
418.8760986	0.11
423.2909546	0.17
429.2500000	1.74
435.1680298	0.21
441.3417969	0.47
443.2335815	0.07
447.5363159	0.19
453.3426514	0.36
459.2021484	0.69
471.0836182	3.30
483.1789551	0.23
487.3771362	0.21
489.1791382	31.68
494.9163208	0.10
501.2609863	1.16
503.1257324	0.09
513.1947632	0.33
519.2196045	9.64
531.2482910	5.83
533.4629517	0.18
544.1494751	0.09
549.0300293	0.59
555.1487427	1.03
559.1976318	0.14
561.1773071	5.13
562.0593262	0.13
573.1861572	0.50
575.4694214	0.13
579.0574951	0.76
588.9506226	0.06
591.2318726	5.30
594.9765015	0.07
603.4242554	0.07
605.4157715	0.13
609.2135620	100.00
609.8466187	0.34
610.5317993	0.10
621.6762085	0.13
625.3374634	0.18
627.4595947	0.10
633.2014771	1.22
637.1766968	0.52
649.2250366	0.06
651.2595825	89.76
652.2401733	0.41
663.2579346	0.21
669.3728027	0.09
674.1060791	0.06
675.2118530	0.03
677.4652710	0.54
681.2280884	12.23
681.8405151	0.04
687.1749878	0.15
691.2619019	0.14
693.2874146	1.29
717.1226807	0.09
723.2800903	0.70
726.4814453	0.22
727.5073853	0.10
735.2417603	1.19
740.6361084	0.07
752.0889282	0.09
753.2263794	4.39
770.9367065	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.3205
Annotation	4,5-Dihydroxykleinifulgin
Peak:m/z	Relative Intensity
159.1134033	0.22
164.9488678	0.13
168.9973297	0.71
170.8397675	0.21
173.1610413	1.06
179.0634766	0.22
182.9967041	0.40
185.1495514	0.23
187.3036194	0.73
193.3670959	0.09
195.0098724	0.08
197.1441040	0.07
199.0990295	0.96
201.0794983	0.33
203.1714630	0.31
209.3725891	0.20
211.6470184	0.05
213.0977020	0.09
217.1088104	0.18
219.3539124	0.34
221.2001801	0.54
223.1474609	0.76
229.0233154	0.66
231.3545227	0.52
233.1843262	0.48
234.9584656	0.06
237.0854187	0.19
243.1351929	0.09
245.1286926	1.40
247.4061584	0.12
249.2905273	0.07
253.1825256	0.21
255.1927338	0.21
257.2174988	0.31
261.3309021	0.52
262.8800354	0.34
267.2749939	0.06
269.2342529	0.30
273.3572998	0.27
275.1068726	0.12
277.3194580	0.51
279.2395325	0.65
283.3258057	0.37
285.3865662	0.11
287.3462524	2.23
289.1207275	1.20
293.1326294	0.83
299.1068726	0.14
301.1415710	0.35
302.9405823	3.03
304.1165161	5.41
305.1069336	0.83
307.2301025	0.16
309.1972351	0.91
314.0434570	0.06
315.3916626	0.73
317.2338257	0.04
319.3143921	0.42
322.7208252	0.05
324.3057251	0.11
325.2689209	0.83
327.3851318	1.15
329.0000610	0.21
331.3729858	0.11
335.0100098	0.20
337.0288696	0.10
339.4915161	0.08
341.1894531	0.24
343.3207397	0.31
345.4187012	0.51
351.3051147	0.39
353.2148438	0.86
359.4513550	0.17
363.2066040	0.13
367.2377319	1.20
368.8070068	0.25
371.0208130	0.11
375.6291504	0.42
377.2957153	2.90
378.9982300	0.22
381.3509521	0.77
383.2091675	0.60
385.1470337	0.08
387.5745239	1.07
391.4127808	0.57
393.2520142	0.43
395.2531738	5.03
397.2568970	0.47
399.0988770	1.41
401.2258911	0.08
403.8475342	0.32
405.1684570	1.76
407.4961548	0.56
409.2362671	2.47
411.3470459	0.38
412.9623413	4.53
413.5925903	1.46
417.1958618	0.50
419.1921997	1.91
423.2184448	1.93
425.4987183	0.82
427.2202759	1.64
429.5043335	0.54
431.0751953	1.69
435.1997070	0.54
437.3367920	10.15
441.2095947	3.83
443.2352295	7.21
443.8453979	0.06
445.2659302	0.31
449.4487305	0.21
455.3222656	36.59
456.9326782	0.60
459.3127441	2.15
461.0534668	0.11
462.5884399	0.07
463.2278442	0.25
465.9509277	0.24
473.2797852	35.93
473.9367676	0.24
475.2871094	0.32
477.0867310	0.17
483.3567505	0.27
487.5011597	0.07
491.2520142	26.16
493.7886963	0.06
497.5639038	0.16
503.3594360	0.95
505.1847534	0.42
508.2894897	2.49
509.0838013	4.08
514.6260376	1.07
515.2564697	4.67
519.2442017	3.96
521.3773193	0.41
533.2020264	100.00
533.8444214	0.21
534.7330322	0.39
551.1767578	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1423.5796
Annotation	Nomilinic acid 17-glucoside
Peak:m/z	Relative Intensity
405.3155212	0.05
419.4719543	0.12
439.1950378	0.18
471.3906860	0.04
563.1424561	0.21
589.2756348	0.09
593.4968262	0.06
607.4199219	21.09
608.5145264	0.99
609.5339966	0.13
651.3558350	5.05
652.4554443	0.10
669.2597656	0.64
711.2710571	100.00
712.2800293	3.43
964.9940186	0.07
1216.6745610	0.05
1279.4071040	0.06
1363.3942870	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	221.1031
Annotation	Isopropyl beta-D-glucoside
Peak:m/z	Relative Intensity
68.9012146	0.22
70.9618683	8.20
72.9727020	3.71
80.8467407	0.59
82.9500046	1.52
85.0322113	2.91
86.9177093	1.05
88.9151154	2.45
96.9918976	3.09
98.9653931	1.80
100.9574127	32.33
102.3109741	0.22
103.1286621	0.23
113.0383911	15.56
114.3346863	0.08
115.2553558	0.08
119.0855865	0.66
123.9905243	0.11
125.0318756	2.10
129.0395203	3.07
130.8679657	0.14
133.1741943	0.08
143.0227356	6.90
148.9537506	0.25
151.0652313	0.43
158.8835449	12.10
160.9399567	100.00
176.9131317	0.79
177.7966461	0.09
179.0836029	0.70
193.0729218	0.24
202.9854889	0.53
205.8950653	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	631.1508
Annotation	Unknow
Peak:m/z	Relative Intensity
297.3789368	0.23
315.1441040	100.00
316.3249207	0.23
335.2698364	0.07
343.2515259	0.05
439.1769409	0.07
448.9763794	0.12
451.2187500	0.18
457.1355591	0.40
487.2865601	0.12
494.0704346	0.33
511.2941284	0.11
523.5703735	0.07
542.8055420	0.22
545.2319946	0.13
547.0718384	0.07
551.3070679	0.12
571.1882935	0.04
583.7512207	0.26
585.2397461	0.40
587.3044434	0.14
613.2257080	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1559
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
195.1326447	0.04
223.2423248	0.02
266.6820068	0.05
269.0954895	1.16
279.2915649	0.02
281.3706055	0.14
282.3520508	0.06
283.2922363	0.05
293.1188354	42.46
294.2053833	0.50
295.1738281	0.31
297.1840820	0.21
305.2637634	0.04
311.1754761	3.33
312.0267334	0.11
321.2537231	0.17
323.1885986	5.37
324.1702881	0.06
325.1217041	0.36
333.8479614	0.06
335.1569824	1.38
336.2622070	0.04
337.2114868	0.43
340.6250000	0.36
341.2294312	6.06
348.4467773	0.02
349.0621948	0.06
351.1382446	0.07
353.1566162	2.36
355.2058105	1.50
356.2817993	0.17
365.0145874	0.20
367.3081055	0.24
369.0236206	0.04
371.0565186	0.14
377.1444702	0.69
381.3477173	0.06
383.2733154	0.52
389.3675537	0.09
395.2593994	0.91
403.4481201	0.02
413.1333618	100.00
414.0352173	0.68
415.2997437	0.25
426.8683472	0.08
430.1611938	0.17
431.1160889	1.35
432.0243530	0.13
433.2438965	0.97
439.1971436	0.06
445.0537720	0.14
445.7668457	0.03
448.4370117	0.03
455.1040039	0.05
457.1871948	10.31
458.3447876	0.05
467.3278809	0.07
468.9698486	0.10
473.1943359	0.30
475.1469116	0.34
485.4412842	0.03
487.2348633	1.87
488.1796265	0.03
494.1081543	0.02
499.2348633	0.19
501.5448608	0.14
505.4046021	0.05
513.1403198	0.15
515.2617188	0.02
517.1106567	0.03
523.2107544	0.27
529.4171143	0.02
531.0062256	0.07
533.2777100	0.69
541.2276001	0.03
547.2540894	0.11
558.9834595	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1607
Annotation	Kadsuralignan A
Peak:m/z	Relative Intensity
121.1046143	0.08
134.7329102	0.04
135.9846191	0.05
147.1307983	0.06
148.9680939	0.29
153.0804138	0.04
171.9420776	0.03
175.2112427	0.16
186.8874512	0.04
190.1479645	0.60
192.9615173	0.02
201.0560455	0.05
203.0286255	0.05
205.0939178	2.62
218.7933044	0.04
238.9286194	0.05
251.3305664	0.03
255.1883240	0.06
259.1833801	0.04
285.3359985	0.03
290.9828491	0.05
293.2297363	0.04
296.1491699	0.06
297.1185913	0.06
305.5224609	0.06
311.1593018	4.18
317.2094727	0.01
321.1386414	0.02
323.3056030	0.11
326.1622620	0.52
327.2018433	0.22
329.2108154	0.64
339.1049194	0.13
341.2580261	100.00
342.3006592	0.03
354.9223022	0.07
355.5312500	0.03
357.2284851	0.42
358.5791931	0.24
359.3852234	0.21
366.0428162	0.02
369.0648499	0.04
370.5407715	0.23
371.2801819	0.54
383.3450623	0.70
384.2835083	0.05
385.3047791	0.03
386.3230896	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.2733
Annotation	(4E,8E,d18:2) sphingosine
Peak:m/z	Relative Intensity
111.0845947	0.42
121.0448456	1.19
123.0852051	0.52
139.2466431	0.46
151.0999756	1.49
161.0050201	0.80
171.1502380	0.57
245.1538391	2.68
250.2985229	0.89
255.8107910	0.71
261.8695374	0.47
263.1371155	4.89
280.3280640	100.00
281.1750793	0.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.2458
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9676514	3.43
149.1319122	1.83
151.1765747	0.47
153.1747284	0.15
158.2385406	0.19
160.9626923	10.35
163.0658875	1.02
165.0829163	9.25
167.0695496	0.20
169.1345825	0.80
171.1499176	4.65
173.0962219	3.92
175.1078949	1.06
177.0703583	7.00
185.1832886	1.49
186.9341888	3.90
189.1636505	1.16
191.1438751	2.18
193.1242828	1.33
197.1557465	2.22
199.2403259	1.07
200.8862000	0.26
203.1853638	0.43
205.1262207	2.59
207.1518402	0.57
209.1541290	100.00
210.9679260	0.28
213.0680847	2.10
214.9652100	2.95
217.2723236	1.62
219.2207489	0.54
221.1251678	0.98
223.3723450	0.55
224.9655304	1.58
227.0853882	0.15
228.9487305	1.78
231.1426086	7.44
232.8721771	0.61
234.9920197	0.74
237.2458191	0.50
239.1908264	0.59
241.1571045	0.63
243.0199585	0.55
245.3009338	1.35
247.2619781	1.28
249.3489075	0.98
251.2797546	0.98
257.0474548	1.09
259.1694336	1.24
263.1492920	0.26
267.0719604	1.15
268.9574585	1.78
275.0520325	1.10
278.2343140	0.28
279.0773926	0.83
281.2407837	0.26
285.2056885	2.04
287.1188354	3.86
289.0884399	3.54
293.2420044	1.91
294.2323608	0.49
295.1301270	0.90
297.1244507	1.61
299.2200317	0.11
300.9305420	1.36
304.7249756	1.91
305.3826904	0.51
307.1730957	1.35
309.1336670	0.52
311.1260376	0.85
312.6824951	1.20
313.4368896	0.15
314.2232666	0.51
317.3649292	0.83
318.2186279	0.52
319.1409912	1.12
321.1525269	2.60
321.7902222	0.19
323.0682983	2.91
324.3132935	0.42
325.0913086	0.34
329.1567993	1.47
330.2718506	1.29
331.1696167	0.23
333.1472168	2.74
334.4219360	3.10
335.1057129	4.22
335.7659912	0.65
336.9622803	0.56
339.1983643	2.00
341.2317505	1.15
342.3113403	0.27
343.2669067	0.69
345.1508789	2.17
347.1544189	2.17
349.3721924	3.07
351.1489868	6.13
353.0729980	0.72
355.1391602	0.75
357.4462891	0.27
359.4340210	0.49
361.4336548	2.57
363.4315796	2.03
365.5164795	1.11
367.2861328	9.65
369.2664185	6.26
371.2375488	0.69
373.3074951	4.77
375.3247070	3.47
377.1676025	7.45
379.3424072	1.51
381.2766724	0.15
383.3519287	1.18
385.1976929	3.14
387.3222656	0.28
391.2268677	7.91
393.2748413	22.86
394.2676392	0.86
395.3486938	3.12
397.3678589	0.41
401.2899170	0.80
409.1469727	8.56
411.2545776	26.02
413.1744385	3.63
419.1703491	8.84
421.1408081	0.27
427.2714233	5.02
429.2655029	0.79
433.2061157	0.56
434.4119263	1.30
437.2011108	19.40
441.1136475	0.15
442.2940063	0.49
446.9487305	0.33
451.1065063	2.18
453.0587769	1.42
455.1744385	19.07
461.3112183	6.71
463.0651855	0.11
469.1264038	23.50
469.7543335	0.11
471.2141724	3.03
471.8191528	0.37
473.5354614	0.73
479.2689209	9.87
480.2661133	0.23
483.7604370	0.89
487.2595825	1.02
492.1853638	0.26
497.2158813	17.17
498.3684082	0.23
518.7357788	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutin
Peak:m/z	Relative Intensity
245.1559906	0.11
254.9512482	0.14
257.2090454	0.12
263.2369385	0.02
267.8925171	0.06
272.9546509	0.13
274.1082764	0.06
281.0372009	0.02
285.2474976	0.02
287.0353394	0.22
303.0602417	85.56
303.6733398	0.18
305.1358948	0.14
309.2201538	0.02
314.9393311	0.16
324.2817383	0.05
326.9651489	0.22
328.2839355	0.05
329.1357422	0.08
345.1434937	0.94
352.6712036	0.11
356.0750732	0.13
357.1013184	0.12
369.104187	0.62
371.098938	0.06
381.0713501	0.02
383.0789185	0.05
393.5095215	0.09
398.9036255	0.19
407.1374512	0.02
413.1694946	1.36
423.3323975	0.10
428.75354	0.14
429.5394897	0.28
431.1033325	1.53
433.3886719	0.02
435.9597168	0.07
437.6391602	0.08
439.3463135	0.08
441.3556519	0.13
445.3389282	0.04
447.1538696	0.81
449.1516113	8.82
458.7649536	0.08
463.477417	0.05
465.0863647	100.00
465.6895142	0.38
471.3131714	0.53
473.0474854	4.83
473.7603149	0.02
478.9804688	0.22
489.5057983	0.65
490.180603	0.04
491.1008911	0.91
495.2238159	0.04
496.2240601	0.22
497.3113403	0.22
501.0054321	0.07
507.2391357	0.08
513.2664795	0.25
514.4159546	0.09
515.0315552	0.72
521.4567261	0.07
525.0047607	0.08
527.1348267	1.41
531.3262329	0.17
535.4422607	0.08
537.5584717	0.02
539.229187	0.28
545.2212524	1.25
549.2883911	0.06
551.0612183	0.10
556.5992432	0.29
557.3265381	0.58
566.140625	0.06
567.4696655	0.14
573.2598267	0.08
575.0018311	2.94
575.6790161	0.03
581.2296143	0.08
593.1525879	13.10
593.7720947	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1859
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
175.2980957	0.65
184.4076843	0.07
187.9611816	0.13
195.0829773	2.26
212.7934265	0.10
219.0034332	0.43
231.1022339	0.48
237.1219788	0.66
238.8545685	0.25
245.1005859	2.23
263.0999451	4.12
270.9555054	0.11
272.3584595	0.40
273.0877686	0.51
274.1854248	0.11
280.4716187	1.03
281.1900635	3.54
287.3482056	0.30
289.0045166	2.76
290.2915649	0.41
298.4338684	0.07
301.0048218	1.61
312.9455566	3.33
314.7522278	1.20
323.0861816	0.96
325.2768555	1.11
329.1484985	0.31
331.0967407	10.94
332.0442505	0.08
333.0812988	0.48
339.4727173	0.37
340.9487305	0.59
342.0505981	0.54
347.1422729	0.47
353.1068115	1.67
355.0723877	7.46
365.1927490	0.12
373.0105591	0.94
375.4195557	0.49
379.3428955	1.05
381.2635498	2.20
383.0896606	1.41
391.2432251	0.53
397.2073364	0.88
399.2038574	14.87
400.0706787	0.71
401.1636963	0.26
405.3992920	0.17
409.2037354	2.79
410.7543335	0.08
413.4461060	0.16
415.2330933	0.60
417.0554810	35.02
417.7552490	0.12
419.1730347	0.34
422.9976196	2.27
427.0997314	0.56
429.1379395	1.08
431.3189087	2.65
433.1224365	2.84
435.0562134	75.36
435.6717529	0.28
441.1176147	4.28
443.2075806	0.60
445.1977539	0.43
446.8246460	1.18
449.0884399	9.57
453.6887817	0.43
459.1777344	25.41
461.4398193	0.25
465.2388916	2.93
467.0855103	0.29
476.3316650	2.53
477.0557251	16.62
483.1486206	2.68
489.0845947	0.06
491.1740723	1.52
494.2095337	0.14
500.9564209	1.32
509.0999146	2.36
519.2768555	0.40
527.1807251	56.35
533.1646118	0.57
538.6121826	0.15
545.0999756	100.00
562.5546265	6.16
563.1589355	47.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	507.1566
Annotation	Unknow
Peak:m/z	Relative Intensity
146.9106293	0.65
164.9916840	100.00
211.0039368	0.03
293.4420166	0.13
311.1411133	0.23
327.1802979	0.05
335.5666504	0.58
336.3843994	0.03
341.2432861	0.16
342.2360229	0.15
411.1978760	0.09
423.0718384	0.10
453.4317322	0.17
461.1371765	0.11
463.1905212	0.32
486.9722595	0.08
488.9671326	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	668.2886
Annotation	Unknow
Peak:m/z	Relative Intensity
187.1641541	0.07
188.3587494	0.11
189.1569519	0.06
191.0267334	0.14
193.1220398	0.07
194.0769348	0.06
195.2617645	0.05
196.2825775	0.11
197.2100372	0.14
199.0870514	0.11
199.8810883	0.17
201.1314697	0.09
202.1289673	0.08
204.0803223	0.03
204.6998138	0.06
207.1243744	0.03
209.3542786	0.13
211.2763367	0.08
213.1222382	0.13
215.1845398	0.09
217.1793823	0.13
219.2434692	0.03
220.9541473	0.02
222.1896515	0.10
224.9685669	0.07
225.5824432	0.04
227.0441589	0.32
229.0337219	0.03
231.1839294	0.07
233.0031738	0.19
235.0627136	0.25
237.1517334	0.07
243.1125793	0.18
245.1809540	0.27
246.9747314	0.04
251.1796570	0.09
252.9829102	0.17
256.2998352	0.02
258.3668213	0.06
259.3464355	0.04
261.1405029	0.03
263.1022949	0.03
264.2235107	0.04
265.3312988	0.19
266.9125977	0.04
269.1521912	0.17
271.2276611	0.32
272.9689331	0.07
273.7495728	0.08
274.9472656	0.09
277.1890259	0.31
279.0284119	0.44
281.2775879	0.32
283.1800537	0.32
284.9604492	0.10
287.1848145	0.45
288.5644226	0.24
289.2857666	0.22
291.3129578	0.06
293.3211060	0.15
294.9186401	0.13
297.1925049	0.23
299.0430908	0.06
299.9687195	0.05
301.1453247	0.07
302.2171936	0.14
303.3695068	0.14
304.0168457	0.04
305.2656860	0.37
306.7109375	0.04
307.3760071	0.03
309.3388062	0.45
310.5885010	0.10
311.6119385	0.17
313.4062500	0.20
314.6010132	0.23
315.3412476	0.58
317.0457458	0.29
319.3733521	0.45
320.3656616	0.07
321.3037109	0.66
325.0616760	0.03
326.5597534	0.25
327.2683105	0.05
329.1313477	0.61
330.6120911	0.05
331.2424927	0.65
333.1744080	0.09
335.2205200	0.88
337.1487427	0.08
339.2980042	1.36
340.4441833	0.04
341.2579346	0.21
343.6513062	0.07
344.3963013	0.08
345.3286133	0.40
347.0921021	0.86
349.4020386	0.86
351.4003906	0.03
353.3025513	0.24
354.3060913	0.04
355.3436890	0.03
357.1128540	1.55
359.2260742	0.31
360.1150513	0.08
361.1320190	0.65
363.4898071	0.48
364.3638916	0.05
365.1237183	1.14
365.7648926	0.23
366.6221313	0.56
367.3016357	4.12
369.1481323	0.01
371.1302490	0.95
371.7601318	0.19
373.2681274	0.49
375.2545776	11.98
377.0987549	0.67
379.2227173	0.28
381.3161621	0.23
383.2715454	1.88
384.7529907	0.11
389.1107788	0.56
391.1867065	1.06
391.8538818	0.02
393.1165161	1.05
394.1301880	0.02
394.9000854	0.04
397.2083740	0.33
399.3428955	0.18
403.0989380	1.42
405.2913818	0.09
407.2693481	2.76
409.3336792	6.29
411.3316650	0.77
413.3424683	0.04
415.3566895	0.11
417.3673096	0.32
419.1818848	0.11
421.2677612	0.07
425.1865234	26.30
426.0365601	0.13
427.2624512	8.93
429.0260010	0.73
433.0468750	0.08
435.2117920	2.85
443.0895996	1.51
443.7014160	0.03
453.1795654	5.82
458.2832031	0.15
462.4830933	0.04
463.2723999	0.14
471.2081299	100.00
471.8919067	0.21
482.1131592	0.05
484.9708252	0.04
487.9744263	1.33
489.1386108	1.05
504.3164673	0.19
505.9857788	2.20
506.6788330	0.04
510.1726685	0.17
511.3684082	0.34
512.3010864	0.11
515.3263550	0.09
522.2198486	0.52
524.3222656	0.43
537.0925903	0.09
548.1157837	0.15
550.3446045	0.03
560.3312378	0.05
562.4155884	0.22
571.5974731	0.14
572.4921265	0.25
579.2216187	0.07
583.8143921	0.11
584.4330444	0.08
586.9438477	0.04
597.2276611	0.07
602.3193970	0.02
605.2495728	0.15
606.9234619	0.14
607.8082275	0.09
609.1648560	0.03
610.0673828	0.07
612.8237305	0.06
614.2984619	0.09
615.4362183	0.15
621.4335327	0.12
622.1429443	0.10
624.1149292	0.03
629.4343872	0.04
631.8420410	0.82
632.5291138	1.64
633.1912231	0.25
636.4624634	0.12
639.5678101	0.08
650.2125244	1.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	910.4979
Annotation	Unknow
Peak:m/z	Relative Intensity
260.9632874	0.48
269.7174683	0.36
281.9353027	0.63
294.3119507	0.67
295.3125000	0.18
300.2157593	0.07
305.6322021	0.37
309.1284180	0.07
311.1701660	0.18
318.0417480	0.09
321.2631836	1.21
323.2906494	0.05
326.0639954	0.14
331.1591492	0.14
338.4739685	0.45
339.1938171	1.41
341.1933594	0.31
348.4328613	0.07
351.2589722	0.32
353.3680115	0.46
356.0796509	1.05
357.1869507	0.70
358.1315002	0.05
359.9230347	0.18
365.3485718	0.21
373.8726196	0.24
379.0482178	0.10
381.1700439	1.24
392.4196777	1.12
393.2603760	0.22
400.0523071	0.21
408.4096680	0.89
409.7293701	0.44
410.3591003	0.40
415.3554077	0.17
417.9033203	0.16
419.0529785	0.17
420.2259521	6.27
429.3187866	1.27
436.4542847	0.19
438.3422852	6.68
443.4408569	0.37
445.1282959	0.27
454.4784546	0.24
455.2345581	0.48
457.1369629	0.26
460.0601196	0.11
461.1193237	0.28
470.7166748	0.04
473.3885498	0.82
484.2671509	0.69
488.1949463	0.07
490.3997192	0.07
497.3127441	0.12
499.1863403	0.61
501.4598999	0.34
502.3180542	0.06
505.2972412	0.25
507.4387207	0.29
509.0430908	0.26
511.1185303	0.22
512.3283691	7.98
515.0820312	0.39
523.3611450	1.94
525.3760376	0.09
529.1259766	0.71
533.3160400	2.13
535.4500122	1.42
542.4742432	0.06
546.4694214	0.09
551.3198853	9.02
553.2638550	1.59
554.3035278	0.07
555.8148193	0.20
556.5928955	0.35
563.1378784	0.37
568.9641113	0.70
569.6461792	0.71
570.4658203	0.48
571.3220215	0.39
572.5555420	0.15
581.2011719	2.56
583.4370728	0.44
587.4690552	0.04
593.6895142	0.26
596.0851440	0.04
599.3563843	4.07
601.2847290	0.28
604.4761353	1.22
606.4738159	0.19
609.2073975	0.17
611.3150635	0.09
612.7739868	0.19
614.3292236	0.67
615.5471191	0.21
616.2818604	0.28
619.2584839	0.31
620.1315918	0.11
622.4310913	6.58
624.1517944	0.25
625.3374634	0.13
632.4885864	13.70
634.2539673	0.11
640.4154053	0.74
641.1414795	2.15
645.4973145	0.30
650.4589844	51.66
651.5841064	1.34
652.3283691	0.24
659.5214844	0.51
662.3052368	0.23
667.2179565	0.25
668.2660522	0.27
669.5574341	0.54
670.4246826	1.05
680.3599243	12.89
686.4796753	1.35
688.6327515	0.58
696.5322266	0.16
698.3899536	14.70
699.1495972	0.08
714.3063354	1.00
716.2131348	0.34
719.8324585	0.22
724.4595337	1.14
729.1911621	0.87
731.5768433	0.38
738.4232788	0.39
747.3695679	0.58
748.1307983	0.44
750.7216187	0.07
752.3731689	0.33
756.0710449	0.21
765.6158447	0.19
766.9059448	0.38
768.4157104	10.51
769.1874390	0.10
776.6645508	0.26
779.5885010	2.10
783.5064087	1.28
788.3582764	0.60
793.4618530	6.48
795.5918579	2.60
797.4926147	3.60
803.6539307	0.29
811.3989258	23.92
812.1365356	0.74
813.5162964	4.05
823.4194946	0.63
846.2850952	0.38
847.2655640	0.14
848.0697632	0.08
848.7616577	0.18
849.7948608	0.16
853.4133911	0.14
864.5926514	3.00
865.4342041	1.86
866.4192505	0.98
874.4291382	3.98
875.8648071	0.30
877.3173218	0.23
880.7408447	0.51
882.5717773	31.56
892.4437866	100.00
893.3612671	0.23
895.3397827	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.2867
Annotation	Phyllanthostatin 6
Peak:m/z	Relative Intensity
216.0814362	4.52
229.1068115	0.08
231.0662231	0.11
233.2910461	0.04
241.0058899	0.45
250.0781860	0.07
272.9600830	0.06
275.3647461	0.05
284.8687439	1.55
295.6673889	0.05
305.3385315	0.16
307.3064270	0.12
321.4507446	0.10
325.2566223	0.66
329.3600464	0.02
331.2795410	0.01
333.1023560	0.10
365.2088013	0.06
369.0317993	0.11
375.3712158	0.18
409.3215942	0.08
425.3691406	0.05
427.0429688	0.17
433.4295044	0.05
446.5410156	0.07
447.4006958	0.35
449.1636963	0.22
451.3706665	0.47
453.3770142	0.31
467.2584839	0.03
471.2567139	100.00
481.1635742	0.68
485.3620605	9.63
489.5734253	0.51
495.1680908	23.34
495.7799683	0.39
497.3192749	0.40
507.3636475	0.04
513.2449951	37.35
522.4799805	0.14
525.2288208	1.88
527.5371704	0.15
528.7165527	0.05
530.0191040	0.09
537.2244873	1.02
542.6009521	0.56
543.3292236	1.22
546.9724731	0.84
555.2146606	0.13
563.3535156	0.03
573.1176147	0.29
579.1986694	0.33
588.8967896	0.10
591.1171875	15.77
591.8764648	0.07
596.0160522	0.10
597.1541138	0.27
602.3771973	0.10
612.8156738	0.02
615.0820923	3.93
626.2213135	0.02
633.2438354	0.92
647.8947144	0.14
665.8126831	0.10
673.1594849	0.18
674.4653320	2.72
675.0658569	6.85
688.8867798	0.29
689.5749512	0.03
693.4425659	0.08
697.3183594	0.10
717.1943359	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1127.2736
Annotation	Unknow
Peak:m/z	Relative Intensity
355.0942078	6.41
462.2201538	0.07
463.2648926	0.17
609.2047119	10.58
637.2906494	0.31
708.8402710	0.10
771.3016357	100.00
815.1168213	0.14
920.9639893	0.05
963.0805664	0.05
980.7249756	0.10
987.7302246	0.09
1037.0610350	0.05
1063.1811520	0.16
1082.3634030	0.29
1091.1866460	0.13
1108.6545410	1.25
1109.4503170	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	649.2932
Annotation	Unknow
Peak:m/z	Relative Intensity
187.9812775	38.87
193.0007629	0.03
201.1764526	0.01
202.1773682	0.13
203.2350769	0.23
205.0718689	100.00
205.7912598	0.02
211.2278442	0.03
213.0103455	0.03
217.0730133	0.07
234.9996338	0.19
246.9596252	0.64
265.0974426	5.46
296.2022095	0.15
314.3541260	0.02
332.5605164	0.10
349.2901001	0.05
361.2916870	0.05
366.5695190	0.18
367.2432861	0.73
381.2459106	0.02
409.1875610	0.16
426.6677246	0.62
427.4274902	0.02
450.9968262	0.19
486.6450195	0.37
589.1864014	0.07
630.8425903	0.04
631.4931030	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1664
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
145.2379456	0.03
146.0191193	0.02
149.0349274	0.15
161.0007019	0.03
176.9564056	0.49
179.1408386	0.37
188.0671082	0.09
189.2368927	0.03
203.1085510	3.22
221.0736389	2.39
279.0351257	0.32
308.7927246	0.02
323.1035767	100.00
324.4266357	0.05
341.2442627	0.04
356.6027832	0.02
365.1367798	0.26
383.1868286	2.70
399.0643311	0.01
423.3249207	0.04
467.1921692	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.1088
Annotation	Lactulose
Peak:m/z	Relative Intensity
98.0170288	0.04
100.9263458	0.12
103.0147095	0.16
112.6808472	0.30
120.1262207	0.06
120.9138718	0.24
126.2790756	0.03
130.9587250	0.32
142.8646851	0.40
145.0468445	0.12
161.0283356	0.25
162.7238464	0.06
179.0463257	0.99
180.0988770	0.20
180.9839783	0.87
192.8758240	0.03
206.6727905	0.05
226.9985962	0.13
228.1877136	0.12
237.1748657	0.21
239.1171265	0.06
241.2798767	0.13
248.7356567	0.03
255.1649170	0.17
259.0066223	0.11
266.0632324	0.03
269.1037598	0.06
279.1105347	0.12
280.3348389	0.04
282.8849182	0.08
297.2239990	100.00
299.1237793	0.32
301.2236938	0.21
307.2149048	0.17
325.0850830	1.04
328.2846680	0.03
342.9279785	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	781.2563
Annotation	Glomeratose D
Peak:m/z	Relative Intensity
227.0943604	0.06
229.2251587	0.61
233.1393433	0.84
241.2796631	0.37
247.2982788	0.19
251.1510925	0.48
265.3748169	0.19
271.0166016	0.14
275.1373901	0.23
287.1322021	1.32
295.1975708	0.27
307.2132568	0.05
310.6644897	0.15
311.3522339	0.37
325.2043762	0.49
329.0667419	0.71
330.1381836	0.68
330.9492188	0.30
339.1421509	0.13
342.9116821	0.25
349.0170898	0.09
353.0966187	0.22
357.3257446	0.55
367.1663208	0.98
371.3329468	0.04
382.1882935	0.19
385.3422241	1.27
391.0480957	0.05
393.1253052	0.60
394.9230347	0.22
420.4074097	0.15
421.2226562	0.15
427.1481323	0.12
431.7207642	0.14
433.1868286	1.18
435.1986084	0.14
449.1094360	0.11
451.1076050	1.00
469.1248169	0.19
472.7977905	0.25
475.1959839	6.14
477.2584229	0.09
491.0293579	0.53
493.2626343	14.96
499.0006104	0.06
511.2810059	16.89
517.2437744	3.71
528.8389282	0.09
530.0493164	0.66
535.2228394	18.17
546.2582397	0.42
553.2971802	2.07
557.2795410	0.21
559.1621704	0.92
565.2387085	1.18
574.7649536	0.46
575.4868774	0.19
577.1097412	2.64
583.2648926	0.13
589.4213257	0.25
591.3438110	0.11
593.3032837	0.15
600.9880981	2.09
606.8929443	0.20
607.5414429	0.30
609.2562866	0.13
613.1566772	0.22
619.2568970	4.71
623.5406494	0.12
629.3346558	0.09
637.2061157	29.09
651.1398926	0.11
655.2285767	100.00
658.2071533	0.20
661.1291504	0.85
663.3927612	0.32
677.4285889	0.15
679.1421509	0.72
691.7296143	0.82
718.8817749	0.11
720.8894653	0.41
733.8770142	0.08
735.3001709	0.15
737.3510132	1.06
745.2247314	1.12
750.3580933	0.59
761.2308350	0.08
763.0123901	6.46
763.6661377	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	735.187
Annotation	Unknow
Peak:m/z	Relative Intensity
247.6324463	0.19
263.9053955	0.34
314.6012573	0.07
341.1998901	0.05
345.9907837	0.39
395.1798096	0.04
397.2350464	0.62
417.2366943	0.08
419.4440918	0.04
420.8485107	0.09
429.2259521	0.12
439.1574707	0.04
447.1181030	0.20
448.3482056	0.13
449.2911987	1.32
505.4448242	0.06
514.5978394	0.27
519.3812256	0.17
531.3818970	0.11
541.3699341	0.04
572.3773193	0.08
592.0665283	100.00
593.3761597	0.18
611.3394165	0.54
615.2120972	0.15
617.2831421	0.06
638.3315430	0.24
639.0050049	0.16
670.9387817	0.10
690.3753052	0.06
698.1786499	0.26
701.2451172	0.15
705.0018311	0.06
705.9825439	0.16
709.8585205	0.12
711.8955078	0.29
716.3300781	0.27
717.2955933	0.30
718.6914673	0.15
895.9722290	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
172.0871582	0.06
193.0299988	0.14
215.0583649	0.11
266.9002075	0.17
283.9588623	0.08
285.180481	0.06
285.8521118	0.09
297.1677856	0.02
301.0611572	16.11
302.158844	0.40
303.2850342	0.85
305.3563232	0.08
309.2692261	0.05
315.4262085	0.04
343.2315063	0.63
345.0239258	0.15
346.0844727	0.08
347.0323486	0.64
361.1096802	2.06
375.2149658	0.20
377.4611206	0.12
387.3569946	0.05
391.3505249	0.13
393.9853516	0.07
397.0999756	0.14
411.4242554	0.31
429.0929565	0.49
429.6971436	0.07
433.2668457	0.06
441.3953857	0.04
445.0100098	0.03
447.0545044	0.78
463.1314697	100.00
475.0620728	0.06
476.8294678	0.14
523.0587769	0.18
525.4724731	0.25
531.2977905	0.09
547.046936	0.31
555.166748	0.10
561.5623169	0.14
565.5049438	0.15
567.024292	0.03
573.2119751	0.28
577.4623413	0.10
588.8713379	0.03
591.2402954	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	448.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
131.9173126	0.54
149.0025330	0.06
150.0148315	0.25
150.9662323	0.06
175.0867310	0.18
188.0327148	0.15
190.9346466	0.41
196.8793030	0.04
201.8508301	0.72
216.0333862	1.86
217.1431274	0.07
226.1251526	0.12
230.0525513	0.98
231.1192627	0.11
233.2691345	0.25
240.0321045	0.23
242.2431641	0.25
246.3515625	0.07
254.8052979	0.07
256.0761414	0.09
259.0746765	100.00
260.1217346	1.95
263.1758728	0.15
271.5205383	0.34
275.2285461	0.24
277.2324219	8.36
278.2275085	0.99
284.0977173	58.88
285.0647583	1.94
286.3930054	0.59
288.0586243	0.05
301.1231689	60.71
302.1732178	7.55
303.2362671	0.12
305.1152039	0.07
318.5282288	1.34
319.2013550	23.26
320.2647705	0.51
360.1374817	0.51
362.3267822	0.49
363.2176208	1.08
367.1814575	0.03
368.0288391	0.08
385.0135193	1.54
386.1383057	0.71
387.1098938	0.11
388.2312927	6.89
389.1906433	0.69
394.4788513	0.28
395.1329956	0.39
402.1927490	6.71
403.0975342	0.05
404.3888550	0.97
406.1936340	39.18
407.1240540	1.30
413.1306152	6.02
414.1152039	0.59
421.3976135	0.61
430.2159729	46.31
431.1858215	13.21
432.1445923	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	756.3405
Annotation	Unknow
Peak:m/z	Relative Intensity
211.1097107	0.09
213.1477509	0.06
219.1158142	0.06
222.3746948	0.22
223.3167877	0.25
223.9223785	0.07
224.9838867	0.37
226.1442261	0.09
227.3600159	0.20
229.1981812	0.35
231.2081299	0.25
233.0349579	0.16
235.1481628	0.27
236.4111938	0.03
237.2157593	0.45
238.1328430	0.43
239.2616272	0.41
243.3085632	0.17
245.0763245	0.16
246.1400452	0.05
247.1878510	0.51
249.1581573	0.22
251.1416473	0.21
255.2143860	0.09
257.1770325	0.12
259.2264099	0.15
261.0162354	0.31
262.1325073	0.10
263.2425842	1.30
265.1373901	0.12
267.1607666	0.34
269.1936951	0.68
270.0018921	0.13
271.3277893	0.04
273.1069641	0.27
275.2197876	0.39
276.9926147	0.53
279.0797119	0.95
281.2651367	0.30
283.4389038	0.15
287.3064270	0.05
289.2347412	0.28
291.2535095	0.50
293.0478210	0.17
295.1262512	0.43
297.2342529	0.59
299.2489319	0.50
300.0215454	0.16
303.2406311	0.07
305.3011475	1.61
306.6944885	0.38
307.2966309	0.20
309.1711731	0.38
311.3827515	0.06
313.0784607	0.85
315.3491821	3.57
316.9801636	0.15
319.9203796	0.10
321.1873779	0.62
323.2738647	0.86
325.0362549	0.25
327.5295410	0.17
329.2045898	0.82
331.3637695	0.49
332.5019531	0.46
333.2650146	2.11
334.0261841	0.08
335.0324707	0.35
337.0976868	0.16
338.1773071	0.19
338.9815063	0.47
340.5950317	0.64
341.3530273	4.30
342.2679749	0.29
343.3677979	0.33
345.4369812	0.42
347.1293335	1.08
349.2070312	0.88
351.1200867	2.04
351.7379761	0.21
353.2055664	0.07
356.3237915	0.49
357.2981567	0.25
359.1818848	2.40
360.2628784	0.27
363.7598267	0.56
365.3435669	0.54
366.3496704	0.06
367.3084717	0.69
369.2677612	1.29
372.4783325	0.14
373.1677246	0.29
374.8477173	1.81
375.4984131	1.23
376.5234375	0.35
377.3551025	0.47
378.3099365	0.21
379.5621948	0.29
380.2727661	0.12
381.1540527	0.05
382.4931641	0.12
384.1500854	1.64
385.3703003	0.58
390.4581299	0.13
391.5178833	0.56
392.7584229	1.19
393.3669434	1.48
394.3555298	0.55
395.1679688	0.28
396.4080200	0.44
397.2535400	0.65
398.0872192	0.21
400.1748047	0.18
402.2457886	20.41
406.2225342	0.27
408.5582886	0.71
409.2958374	0.55
411.2177124	2.47
412.3016968	0.15
413.5171509	0.06
414.4291992	0.22
415.2783813	0.16
418.4191895	1.68
419.1667480	0.20
420.3228149	0.80
423.2960205	0.14
426.5286865	0.66
427.2595215	0.44
429.2503662	1.10
430.9002075	0.51
433.1198730	0.21
434.2792358	0.50
436.2666626	6.73
437.3523560	0.37
438.3980713	1.21
440.4439697	0.11
444.4880371	0.13
446.5028687	0.23
448.3497925	0.06
450.2889404	0.12
451.0123901	0.08
452.4849243	0.75
454.3605347	16.53
455.4909668	1.21
458.2761841	3.16
462.2323608	4.32
468.4794312	0.16
469.2791138	0.24
470.4583130	0.92
471.6296997	0.87
472.2626343	6.66
473.2056274	0.82
478.5397949	0.48
480.1442261	10.68
480.9435425	0.33
484.5549316	0.06
486.4392090	0.84
487.1613159	5.70
487.7760620	0.13
493.8286133	0.14
494.5265503	0.08
496.2056885	5.90
498.3255005	24.41
499.8564453	0.73
502.4790039	0.22
507.9246216	0.04
512.2244873	0.35
514.3283081	33.05
516.2721558	8.68
518.2644043	0.63
520.3552246	0.08
522.1798096	0.21
528.2200317	0.51
530.0861816	0.66
530.7059937	0.51
532.2219849	30.63
533.1488647	4.50
534.3239136	0.85
539.1770630	0.06
540.5149536	1.65
541.1864014	0.26
544.9292603	0.20
548.3649292	0.32
550.2985229	1.11
551.9260864	0.13
556.4663086	0.18
558.2585449	24.65
559.2988281	1.01
560.1965942	0.26
562.4245605	0.17
564.2504883	1.02
576.2728882	100.00
577.0807495	0.49
578.2407837	0.33
580.2793579	0.04
582.0507812	0.12
588.3131714	0.31
594.3132324	41.89
595.4183960	0.14
598.1995850	0.05
606.6291504	0.16
607.3823853	0.09
610.1926270	0.21
610.8088989	0.16
616.3891602	0.21
618.3157349	0.15
620.1567993	2.32
622.5053101	0.57
623.1168823	0.33
624.3947144	1.68
625.3403931	0.12
639.4815063	0.09
640.3208008	0.08
642.2977295	2.49
642.9691772	0.08
648.3223267	0.15
654.5028076	0.17
660.2528687	5.38
666.1560669	0.06
672.4956665	0.29
674.6336060	0.47
676.4868774	0.78
678.2523804	0.63
684.3215332	0.39
691.1171265	0.21
692.1220093	0.05
694.1460571	0.17
702.4143677	0.47
705.1774292	0.64
710.1942749	0.92
712.3803101	0.37
716.7065430	0.08
720.2199707	1.34
737.5330200	0.86
738.3140259	13.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0715
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
104.8920135	0.09
116.9092102	0.06
148.9733734	0.17
155.0511017	0.39
163.1743317	0.10
166.208313	0.20
169.1608429	0.20
174.1002197	0.08
179.1174622	0.65
180.1862946	0.07
193.2167511	0.09
195.2708282	0.10
204.9249115	0.32
207.0500031	2.78
208.2047729	3.58
209.0385132	1.41
222.0436249	1.37
223.1109161	4.99
224.2058716	0.73
233.1390839	0.14
234.0147552	0.18
251.0723877	100.00
252.125412	17.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3022
Annotation	Nomilinic acid 17-glucoside
Peak:m/z	Relative Intensity
203.1052551	0.49
205.2012329	0.38
209.1825256	0.12
211.2342072	0.06
212.4628448	0.27
213.2962341	0.18
215.2650909	0.15
219.0883331	0.10
221.0928650	2.38
223.1411591	0.43
226.2750244	0.37
227.1328125	1.25
229.0458984	0.34
229.8587646	0.08
231.2951660	1.24
233.2127380	1.07
234.2238770	0.20
235.2233429	0.21
237.2565002	1.70
239.1861725	0.36
241.1862793	0.68
243.2549438	0.20
245.0117188	0.11
247.4078369	0.17
249.1699829	1.12
250.1829071	0.53
251.3834229	0.73
253.2700043	1.45
255.0921783	1.06
257.1364136	0.29
257.9431152	0.33
259.2886353	0.65
260.4418640	0.08
261.3670044	0.86
264.4615479	0.79
267.2659302	0.13
269.2625732	1.71
271.2480469	1.01
271.9705200	0.78
273.1137085	1.23
274.0483093	0.12
275.1263428	0.71
276.0949097	0.34
277.3311462	0.38
279.4320679	0.14
281.2174683	0.49
282.8880920	0.27
284.2239380	0.10
285.3006287	0.60
287.2947083	1.78
288.2285156	0.12
289.1190796	2.04
290.4389648	1.31
291.3013916	1.66
293.3409424	0.46
294.2061768	0.21
295.1930237	1.09
296.1945190	0.43
297.0940857	0.49
299.3853760	0.16
300.0862732	0.26
301.3473511	0.48
305.2542419	1.71
307.1068726	3.55
308.3528137	0.65
309.3220825	0.84
310.6176758	0.89
311.3943176	0.84
313.3857727	0.72
314.3782959	0.40
315.3603210	0.73
317.2166138	0.56
319.3692017	0.14
321.6004639	0.28
322.2604980	0.34
323.1674500	0.12
324.0604858	0.60
325.1408997	0.83
326.1932983	0.52
327.0782166	0.95
329.3354492	0.17
330.7660828	0.42
331.4094238	1.56
332.1753845	0.41
333.1607056	1.43
335.4701843	0.45
336.2069397	0.21
337.1724243	0.39
338.1480103	0.08
339.1539917	0.63
341.2005310	0.19
343.3285522	0.20
344.2315063	0.07
345.2002563	2.07
346.4331665	0.34
347.2410278	1.41
348.3001099	0.81
349.3204956	1.99
350.2616577	0.79
351.2878113	0.86
352.2437439	0.55
355.2446289	1.33
358.2288818	0.12
360.3421631	0.89
361.3902588	0.22
363.1705322	0.71
364.5508423	0.38
365.3078613	4.28
366.5618896	1.00
367.4245605	2.32
368.3077393	1.24
369.3851318	2.04
370.2816772	0.87
373.0652466	0.82
374.2319336	3.16
380.2353516	0.33
381.0161133	0.54
383.4277954	0.42
385.4692993	0.66
386.1920166	0.36
387.4854126	0.24
388.5940552	0.81
389.4012451	0.46
390.3003540	1.16
391.6428223	0.79
392.3323975	0.22
393.3678589	1.18
394.9986572	0.12
396.1414795	0.89
399.3983765	0.21
401.4011230	1.46
402.2359009	0.27
403.1904297	1.44
404.4101562	0.83
405.1853027	0.48
406.1055908	1.21
407.2382202	0.35
409.1998291	1.26
411.3417969	0.39
415.2949829	0.16
420.3607788	0.45
421.2849121	0.73
423.1743774	3.85
424.3552246	1.33
425.9459229	0.71
427.5274048	1.50
428.3751831	0.13
431.3108521	0.21
433.9814453	0.51
435.4028320	0.70
442.5693359	0.10
445.1965332	2.33
446.3347168	1.61
447.3679199	1.73
448.2429199	0.85
450.2803955	0.24
451.4470825	0.64
456.1956787	0.22
457.4181519	0.10
459.3279419	2.41
460.2095947	0.08
463.3043823	0.39
464.4334106	0.52
468.3986816	0.19
471.1542969	1.87
472.2711182	0.53
473.2868042	0.18
474.2332153	0.12
477.1929321	4.00
478.3961792	1.17
479.0618896	0.73
481.9945068	0.12
487.3166504	0.18
488.2463989	0.08
489.2441406	0.31
491.2083740	0.73
492.3242188	0.11
493.3966064	0.38
494.0718384	0.24
495.1296387	2.57
496.2896118	0.67
505.1955566	0.16
507.3753662	1.72
508.3085327	0.28
513.2550659	1.30
514.4445190	0.30
518.9368896	0.34
520.5326538	0.07
521.4636841	0.26
522.4898682	0.53
527.9598389	0.22
529.3189087	0.50
531.1835327	1.53
532.4046021	0.91
535.3120728	0.68
538.0059204	2.32
541.3351440	0.89
545.1573486	0.04
546.9526367	1.74
548.6778564	0.26
549.5757446	0.53
553.2826538	1.11
554.3367310	0.60
561.1994629	1.18
562.0977173	0.84
563.2015991	0.34
565.2669067	4.75
566.2257080	3.31
571.4390259	3.59
572.3339233	0.52
574.4614258	0.13
575.3264771	0.15
577.2938843	1.79
581.4453735	0.26
585.2310181	0.19
589.3796997	9.36
590.3786011	7.18
603.6007690	0.38
605.3626099	0.88
607.5054932	2.04
608.3746338	1.21
611.4467163	0.17
619.5029907	0.76
620.5825195	3.37
621.3527222	9.16
622.3804932	3.75
623.1687622	0.12
625.2090454	0.11
633.1528931	0.43
634.5744019	0.08
637.5324707	0.31
640.1952515	4.23
647.1769409	0.62
648.4315186	0.20
649.2351685	0.11
650.2931519	0.33
655.2929077	3.18
665.3371582	100.00
666.3959351	61.09
667.3419189	2.79
668.4671021	0.08
681.4888916	0.98
682.5963745	0.38
683.2045288	1.61
689.4361572	0.14
693.4724731	0.35
694.4859009	0.51
707.3872681	0.24
708.5020142	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0564
Annotation	Norbergenin
Peak:m/z	Relative Intensity
101.1021500	0.06
110.9775848	1.07
120.9503174	0.79
129.0029297	8.22
147.0206909	12.12
148.9656830	0.27
160.9060516	0.17
163.0770111	0.08
173.0096741	8.68
188.9868317	0.22
191.0431213	100.00
240.7658081	0.05
251.2150269	0.41
259.1282959	0.03
276.9488525	0.65
295.1395569	21.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	807.3418
Annotation	Unknow
Peak:m/z	Relative Intensity
243.3859253	0.02
254.0719604	0.06
255.1478271	0.11
256.2156677	0.11
256.8688965	0.03
261.2738037	0.10
273.1516724	0.12
285.0176086	0.12
296.2048950	0.12
300.2479858	0.09
301.6894836	0.20
302.7443237	0.24
320.3328857	0.09
322.7999268	0.20
334.3586426	0.54
345.2761230	0.06
358.2114258	0.32
358.9817810	0.02
370.1510010	0.12
378.3114929	0.19
402.3963013	0.06
403.2666626	0.16
404.0328369	0.35
405.2627563	0.33
411.4733887	0.06
428.2802124	0.45
442.6889038	0.16
443.3056030	0.40
446.2218018	0.16
449.1818848	0.13
456.1201172	0.44
460.3237915	0.24
461.3043823	0.07
473.9960938	0.82
475.0333862	0.17
481.3621826	0.14
487.5711670	0.37
488.2960205	0.25
488.9671631	0.04
500.5991821	0.14
506.3948364	0.06
512.5535889	0.23
532.2790527	0.25
539.4725952	0.14
543.1768799	0.05
544.3554688	0.13
545.2280273	0.29
553.3074341	0.11
558.7192993	0.11
562.1338501	0.30
571.3236084	1.01
575.3698120	0.23
576.5399780	0.20
577.4229126	0.23
585.2265625	0.28
586.7720337	0.04
589.1160278	0.51
589.9472046	0.31
593.0662231	0.59
597.3095703	0.82
601.7116699	0.05
603.2255249	9.46
603.8466797	0.07
607.4535522	0.12
611.7931519	0.07
615.1441040	1.49
621.1538696	12.91
621.7650146	0.35
633.1710815	0.15
635.2370605	0.21
642.1792603	1.16
652.4138794	0.10
653.5538940	0.13
660.2489624	4.08
661.0656738	0.19
662.3735962	0.07
673.3677368	0.13
678.2741089	0.14
688.5103149	0.13
690.3547974	0.21
691.6098022	0.26
692.3036499	0.11
700.3458252	0.08
706.0410767	0.36
706.6677856	0.11
718.5510864	0.26
732.3102417	0.05
734.3804321	0.34
735.8945923	0.50
743.1738892	0.10
744.3964844	2.71
745.3939819	1.38
749.8798218	0.04
761.1177979	1.03
762.3245239	8.69
763.4199829	2.87
764.4130249	0.05
771.2813721	3.13
771.9276733	0.05
779.3736572	11.13
789.3044434	100.00
790.1848145	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.1559
Annotation	(R)-Pantothenic acid 4'-O-b-D-glucoside
Peak:m/z	Relative Intensity
112.8808975	0.21
113.9832382	0.16
115.9693909	0.36
118.9075165	0.19
125.1196213	0.09
126.2105026	0.24
127.9744720	0.46
128.9149323	0.61
131.2297974	0.21
142.0567932	0.11
143.0388031	0.42
144.0607910	0.05
146.0045471	60.25
147.0634308	0.41
149.0861053	0.10
159.0570831	0.78
160.9807739	2.38
170.1409607	0.17
171.0688934	0.12
173.0121460	0.24
173.9909363	1.17
178.9716187	0.33
182.1308594	0.22
184.1395416	0.07
190.3410950	0.31
200.0804138	2.61
204.9685364	0.03
205.9832764	0.10
218.1846313	4.42
219.0412292	0.13
230.2745056	0.26
239.1048889	0.18
241.1053772	0.24
241.9579163	0.30
244.8404236	0.09
254.2364502	0.27
258.1656189	0.08
260.0869751	0.56
263.1938477	2.50
267.2575684	0.18
272.1880188	0.49
275.9765625	0.11
288.3191223	0.14
290.1170654	15.37
290.8575439	0.30
293.1035767	0.20
302.1280518	0.21
308.1759033	71.49
309.1685181	0.66
318.1133728	0.34
320.2788086	1.11
331.8777771	0.18
333.9521790	0.17
335.8457642	0.23
344.4735107	0.17
352.2019958	0.20
362.2705688	100.00
363.1907654	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	166.0857
Annotation	Gentiatibetine
Peak:m/z	Relative Intensity
119.9784393	100.00
120.7969055	0.04
130.8742981	0.22
147.7923431	0.77
148.9639282	4.63
165.9848022	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.1789
Annotation	Diosmin 
Peak:m/z	Relative Intensity
178.440155	0.02
231.0429688	0.02
257.3028564	0.01
269.060791	0.03
286.2081909	0.19
289.0079956	0.03
301.1552734	15.41
303.0316772	0.41
325.1158447	0.08
343.2855225	0.07
363.081604	0.01
367.1168213	0.13
375.2873535	0.06
384.8391724	0.02
396.9538574	0.06
409.2902222	0.02
411.156189	0.18
423.3238525	0.01
429.3198242	0.20
441.1760864	0.03
442.4896851	0.02
445.2969971	0.03
447.1522217	0.49
463.1350708	100.00
489.0370483	0.03
497.5320435	0.01
526.9951782	0.06
543.3074341	0.05
549.1082153	0.01
563.5559692	0.10
573.1496582	0.14
590.9926147	0.42
591.6079102	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1822
Annotation	Genipin gentiobioside
Peak:m/z	Relative Intensity
179.0352478	2.55
191.2135925	0.47
195.1608887	0.05
214.3551636	0.29
221.1472473	1.38
244.9993896	0.24
251.1376038	0.27
263.0771484	0.90
274.2467346	0.05
307.3117371	0.06
319.1516113	0.12
323.1580811	100.00
340.8155518	0.08
341.5225220	0.12
353.0063477	0.23
357.2965698	0.22
369.2078247	0.19
378.9619141	0.16
385.1855469	0.13
387.1002197	0.17
400.8391113	0.09
403.2816162	0.38
404.9645996	0.25
408.1091309	0.06
437.4798584	0.34
444.5357666	0.05
459.2720337	0.06
463.0815430	0.06
487.0970459	0.28
489.4736938	0.20
502.1489258	3.01
502.8682251	41.06
505.3043213	0.70
512.2684937	0.08
513.3164673	0.06
514.1427612	0.40
530.1034546	0.66
530.7272339	0.19
531.3369751	0.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Diosmin 
Peak:m/z	Relative Intensity
203.2736816	0.73
213.0635223	0.51
274.9880371	2.22
277.4439392	1.66
284.0786743	38.43
284.7716064	1.02
299.0599365	100.00
299.7176514	0.54
311.1306763	0.39
313.9769897	0.45
366.7039185	1.45
399.2029419	0.76
416.0534058	2.39
419.2330933	1.16
443.3412476	0.42
487.3822021	1.09
491.1690063	0.60
504.2284546	2.94
511.0189209	0.86
535.2425537	1.73
542.8765869	0.35
546.5343628	0.41
558.9343872	0.51
564.9695435	0.65
571.4995728	0.59
579.2418823	1.20
580.4949341	0.48
592.3729858	0.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.1271
Annotation	Machaerol C
Peak:m/z	Relative Intensity
112.6058960	0.08
117.0304718	0.07
127.0812378	0.34
132.9664001	0.27
139.1735382	0.16
140.8888245	0.16
144.1896210	0.10
148.8330994	0.11
150.4158630	0.45
151.0419159	0.85
154.8830414	0.98
157.2236938	0.07
158.9264832	0.25
160.9540100	0.12
161.9284363	0.15
163.8694153	0.33
169.1592712	0.70
175.0759583	0.44
178.1606140	0.33
179.3349304	0.34
181.1758423	0.18
183.0639038	0.08
187.1037140	0.30
188.0528564	0.17
195.1301880	0.30
197.3092651	0.11
198.0123901	0.48
199.1965942	0.18
203.0178528	0.08
207.2075958	0.36
209.3479462	0.31
212.1087952	0.18
214.1487732	0.28
215.3225403	0.16
217.0156555	0.29
218.1379395	0.16
221.2080383	0.14
223.2246399	0.57
224.9566956	0.26
229.0321960	0.15
231.6611938	0.28
232.9670105	2.43
239.2298889	0.62
240.0126648	0.12
241.0712891	0.34
243.3251038	0.21
245.0653381	0.30
246.2218628	0.44
247.2289429	0.47
249.2376709	0.14
251.5083313	0.17
253.0948486	0.24
254.3206482	0.05
257.3170776	0.25
259.2468262	0.21
261.0332031	0.78
262.2271423	0.16
263.1958923	0.17
263.8676147	0.17
265.3707886	0.51
272.1926880	0.22
274.3681030	0.18
275.1971130	0.16
276.4286194	0.05
277.3761902	0.19
281.2060242	0.49
285.3523560	0.38
288.8897400	2.04
289.6143799	0.12
291.1057739	0.72
291.7365112	0.10
293.1663818	0.17
294.1151733	0.18
295.9984131	0.12
298.8790283	6.71
301.1288452	0.48
303.0635986	0.21
305.2261353	0.56
306.1673889	0.35
307.1736450	1.48
307.7810669	0.09
310.2838135	0.21
311.8017578	0.11
315.3833008	0.21
317.0241699	100.00
317.8711548	0.08
319.4259949	0.68
320.3954468	0.30
321.3758545	2.41
322.2702026	0.09
330.0951843	0.05
331.1573486	3.62
332.8132629	0.33
334.1293945	1.92
339.9433289	1.03
349.2365417	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	501.2319
Annotation	Unknow
Peak:m/z	Relative Intensity
143.2189484	0.34
144.1063690	0.08
145.0788879	0.25
147.0049591	0.17
148.9807587	0.11
157.0383148	0.17
159.1671143	0.39
161.1480560	0.28
162.8384399	0.06
165.0472260	0.04
169.2229614	0.04
173.2192535	0.46
175.1159058	0.27
177.0315399	21.48
183.0254669	0.08
187.1566467	0.06
189.0993042	0.44
192.9386292	0.18
199.1060791	0.52
201.0492249	0.09
204.9559021	0.17
207.3140106	0.18
213.0640869	0.31
214.9440613	0.02
217.1693268	2.54
218.9225006	0.14
228.3306122	0.03
229.1188660	0.06
230.3466797	0.14
231.0570068	2.43
235.1712799	100.00
236.3521576	0.15
245.1642151	0.09
251.2350464	0.08
253.1593018	9.64
263.1668091	0.17
265.3268127	0.03
266.7907410	0.08
271.1963501	0.09
274.2304077	0.12
275.4625854	0.08
289.1786194	0.10
291.5607300	0.08
294.9172058	0.02
297.1138916	0.38
299.0035400	0.04
300.2779236	0.14
301.6929321	0.05
309.3753052	0.13
313.0545959	0.24
315.2019653	0.14
318.0122681	0.07
321.1894226	0.18
325.2978516	0.32
327.3148193	0.43
328.9923706	0.31
331.4108887	0.11
336.9711914	0.06
338.9956055	0.20
340.2080078	0.02
343.1833496	0.05
349.2818909	0.06
351.4920959	0.06
353.3862000	0.07
354.8643799	0.16
357.0182495	0.06
372.4077759	0.10
377.5400391	0.10
378.9506531	0.04
380.2049561	0.05
380.9553833	0.24
387.1408691	0.22
389.2428284	0.32
395.2548523	0.44
397.3786011	0.29
415.4078674	0.12
417.0741272	0.05
421.2996521	1.11
423.4952698	0.02
424.9474182	0.04
425.8440247	0.10
433.2267151	0.93
436.7974243	0.23
439.1141663	1.45
441.0237122	0.10
441.9802246	0.23
447.2491760	0.42
455.3219299	0.28
457.2356873	6.74
457.8459167	0.10
464.9770203	3.95
466.0047302	0.09
477.5119324	0.22
480.1255798	0.07
483.1716919	21.90
487.2172241	0.11
488.1560669	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.91801453	0.26
78.78736877	0.31
80.88466644	2.36
82.88342285	0.62
85.01760864	0.47
90.891922	0.51
93.09912109	0.46
94.92095947	3.66
97.24693298	0.37
99.11444092	1.27
102.8184662	1.53
104.9217072	1.46
106.9274902	2.09
108.9079132	1.30
111.0629578	0.28
112.917923	0.97
115.0713654	0.44
117.0461121	0.33
118.9993744	0.42
120.070816	0.39
120.9747925	1.50
123.0556183	2.34
124.9844971	0.91
126.8532715	4.62
128.8963165	4.26
130.0223541	1.58
132.0097809	0.68
133.1337433	1.70
135.1829376	1.04
137.1080627	2.37
138.9570312	1.33
140.7828522	0.61
143.1450043	0.27
146.97258	0.62
149.0570068	1.12
150.9421692	59.64
152.0320282	5.14
152.8664398	0.78
153.9538422	0.44
155.0187225	1.23
157.2310181	1.33
159.1758118	0.81
160.2624969	0.29
161.1327972	1.47
163.0937042	0.53
165.1207581	2.42
166.9461365	1.11
168.0263367	1.32
168.8344269	1.54
171.0441132	1.77
171.8500061	0.38
173.0314178	0.18
175.1515808	1.92
176.8443909	0.68
177.7460175	0.55
178.9547272	4.51
180.1431274	0.36
181.0259399	0.55
182.2055511	0.26
183.017746	1.86
184.9982452	0.38
186.2891083	0.15
189.16008	0.14
191.0938721	1.42
192.8730774	2.22
195.151123	1.09
197.171051	5.93
199.1262054	0.30
200.2350006	0.44
207.0497131	5.35
209.1160126	0.32
210.0250397	1.04
211.1104126	3.28
217.0830841	6.06
222.9572601	0.44
225.0639496	11.87
226.0951996	1.01
233.1186371	0.14
235.1418304	27.47
238.1473999	6.29
239.0794067	0.73
251.1819	0.21
253.0908203	100.00
254.1761627	20.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.2189
Annotation	Cucurbitoside G
Peak:m/z	Relative Intensity
172.9937286	0.21
190.9329224	0.27
193.1060486	0.24
196.1712341	0.11
205.2074890	0.31
222.6361084	0.60
224.2357178	0.35
237.3607788	0.06
239.9625549	0.96
241.0708618	0.92
242.0976410	0.17
252.1883850	0.37
252.8576508	0.07
254.9398346	0.55
257.1734619	2.31
265.0702820	0.44
268.1458740	1.30
269.0324097	0.17
283.0894775	17.31
299.9484863	2.44
301.0736084	9.21
301.7360229	0.16
309.1463623	0.78
313.9624023	0.35
314.9224854	0.37
317.1860352	0.20
327.2730103	0.57
331.2569580	0.24
337.2675781	0.28
353.1257324	0.45
355.3054810	0.43
358.1146851	0.18
360.2519531	2.92
367.0372925	3.85
373.1992188	2.47
384.9666748	0.24
397.2639771	0.54
398.4020386	0.37
414.3641968	2.78
415.0908813	5.18
416.2273560	0.48
417.3253784	0.56
431.2568359	10.58
449.3098755	0.06
453.6147461	0.26
454.5407104	0.31
455.3811646	0.34
458.5469360	0.24
459.4262695	0.13
471.2327881	0.16
473.0504761	1.95
475.1180420	1.04
488.4191284	0.22
515.0104370	0.42
517.1690674	100.00
518.3572388	0.11
519.4240112	0.15
543.2208252	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.2245
Annotation	Lactulose
Peak:m/z	Relative Intensity
233.2719116	0.03
237.0044250	0.04
280.9559021	0.08
339.1376343	0.04
341.1060181	100.00
342.0864563	0.02
361.6990967	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	691.2968
Annotation	Ixerisoside H
Peak:m/z	Relative Intensity
225.4174652	0.07
227.1161804	0.12
272.7304077	0.15
301.0135193	0.03
340.3255005	0.06
361.1005859	0.03
380.2462158	0.09
390.2474976	0.09
423.3078613	3.70
424.3287964	7.92
444.5205688	0.05
465.9943848	0.15
484.6426392	0.13
517.4107666	0.03
527.4154053	0.10
540.3408813	0.06
544.2019653	0.29
544.8683472	0.02
545.8884277	0.06
548.3662720	0.03
562.3201294	0.23
568.4696045	0.04
585.3423462	20.30
586.3403931	100.00
587.0198975	0.32
603.0675659	2.34
604.1347046	11.10
604.7636108	0.07
606.0177612	0.03
619.7994385	0.07
624.5307617	0.06
627.9550171	0.04
631.2182007	0.61
632.2070312	4.19
632.8770142	0.04
646.0228882	23.87
646.7611694	0.10
670.2088623	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.2033
Annotation	Unknow
Peak:m/z	Relative Intensity
142.9643402	49.94
240.5586853	0.76
263.3871460	4.69
305.0201416	23.11
344.3928223	7.25
346.6513367	55.01
347.2828979	56.12
386.9081726	100.00
404.6445618	11.49
405.2718201	1.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.214
Annotation	Safghanoside C
Peak:m/z	Relative Intensity
224.0023956	0.03
235.1970062	0.01
245.1811829	0.04
262.9207764	0.07
270.9098511	0.03
284.9312744	0.02
299.7029419	0.08
300.3041382	0.23
303.2681274	0.03
310.1574707	0.03
311.4495239	0.05
312.2518005	0.47
315.1368408	3.25
327.5388184	0.08
339.1138306	0.03
355.3231812	0.12
365.1722412	0.46
367.2620239	0.04
383.2097168	3.51
385.1062012	0.02
389.9891357	0.02
397.2191772	0.04
409.2371216	0.07
413.2401123	0.82
421.2447510	0.05
425.2904053	0.25
427.5382690	0.08
438.3577271	0.03
439.3926392	0.01
441.2626953	0.04
443.1518555	0.16
449.2991943	0.13
455.3311768	0.10
461.4108276	0.07
467.1901855	0.19
473.1501465	0.02
477.2328491	2.49
479.1502686	0.19
485.4768066	0.18
489.1216431	0.06
490.1491699	0.01
501.1933594	0.05
503.1569824	4.15
503.8502197	0.01
513.4224854	0.04
515.1876221	0.06
521.2732544	0.03
533.1047974	0.23
541.1266479	0.04
545.1706543	0.28
550.9970093	0.08
563.4413452	0.06
569.2588501	0.06
571.4473267	0.07
572.9553223	0.04
579.2925415	0.11
587.3268433	0.41
591.3953857	0.06
593.3429565	0.09
605.2351074	0.18
607.2009277	0.02
609.6193848	0.07
610.2782593	0.04
611.2177124	0.21
619.4172363	0.03
623.2105103	100.00
623.8472900	0.35
631.5470581	0.11
639.3825684	0.15
653.3288574	0.04
660.4146118	0.01
663.6661987	0.11
665.1658936	2.69
665.7741089	0.05
677.2221680	0.13
677.8433228	0.04
695.2350464	1.18
696.5518188	0.03
697.9897461	0.05
707.3159790	0.23
711.0162354	0.04
712.9949341	0.04
721.1889038	0.03
722.9055176	0.02
725.0059814	0.15
727.7703857	0.10
730.3859253	0.03
732.1687622	0.07
735.5360107	0.01
737.1751099	0.02
738.9244995	0.02
741.0247192	0.12
742.7540894	0.01
749.2278442	0.05
750.4359741	0.07
762.8001099	0.04
766.9880371	0.69
767.7384644	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	226.18
Annotation	Adalinine
Peak:m/z	Relative Intensity
68.9224777	0.05
72.0419846	0.10
78.4804840	0.01
81.0376053	0.27
81.9449539	0.05
85.0467072	0.17
86.2881775	0.12
87.0391159	0.01
90.8560791	0.03
92.9751892	1.03
94.8770142	0.23
96.0203400	0.02
96.9904633	0.08
97.9919281	0.03
99.9379273	5.44
105.1262207	0.04
107.0046692	1.38
110.8218384	0.06
113.9570618	0.27
118.9291077	0.01
121.2477112	0.08
128.1303711	0.11
130.0331421	0.16
134.9877777	100.00
135.8647919	0.01
136.9609833	0.21
137.9272766	0.04
139.9168091	0.09
142.1145172	0.08
144.0390778	0.17
152.0779266	1.10
152.8217621	0.04
158.7761688	0.02
165.1060181	0.04
166.2510986	0.10
166.9615021	0.06
178.0469513	0.06
180.1640778	0.34
181.9521790	0.01
184.2773438	0.09
184.9301605	0.10
190.2255554	0.32
194.1282043	7.66
198.0697174	0.19
199.0495911	0.04
205.0638580	0.25
208.1712952	0.32
209.8844604	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.1564
Annotation	Tricin 7-rhamnosyl-(1->2)-galacturonide
Peak:m/z	Relative Intensity
224.3419189	0.07
227.2499542	0.05
229.9520111	0.08
239.2102814	0.08
258.3934021	0.03
269.1748047	0.12
271.1624146	0.11
284.9854736	0.21
286.1986389	0.25
287.2050476	0.26
288.1931763	0.34
301.1130981	0.09
305.1428528	0.32
306.3589478	0.09
315.2247620	0.18
316.0283813	0.22
317.0332642	0.50
330.0722351	1.37
331.2053833	3.08
332.2452393	1.44
345.0520630	15.22
346.0709839	19.78
388.0527954	0.15
391.1762695	0.04
447.0905762	0.03
476.3435669	0.12
488.9801636	0.07
490.0791016	0.05
492.1081543	0.10
493.1239014	0.82
494.1773682	3.95
507.1799927	23.72
508.2459106	100.00
535.3950806	1.26
536.3033447	4.72
549.1549072	9.78
550.2241211	50.44
576.3431396	1.55
577.6200562	0.18
578.2413940	1.13
589.5317993	1.90
590.2142334	19.59
592.1149292	0.73
601.4053955	0.38
602.2010498	2.42
608.3095703	0.64
620.1543579	0.14
634.1768188	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1663
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
173.0216217	0.06
176.2214508	0.03
177.0661163	0.32
178.9976654	0.04
191.1993866	0.02
202.9674988	0.21
219.8922119	0.15
221.1036072	0.33
251.4097290	0.02
279.0433044	0.14
323.1538696	100.00
364.9759521	0.06
383.2275085	0.69
385.3213501	0.04
441.1940002	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	629.1586
Annotation	Unknow
Peak:m/z	Relative Intensity
179.3975983	0.15
187.1535645	0.20
205.0830841	0.09
207.0923309	0.78
213.0601959	0.15
215.1251221	0.12
219.1714172	0.12
228.9970856	0.15
230.9302063	0.26
235.0982666	0.38
237.1712341	2.37
242.9992676	0.26
253.1537323	0.23
258.2886658	0.08
260.0665894	0.04
271.1789551	0.51
274.0753784	0.42
285.1054382	0.70
286.1103516	0.42
288.9705811	0.87
291.0623779	0.80
300.3446960	0.31
302.1687622	1.31
303.3991699	0.41
306.9063721	1.42
310.8736267	0.08
313.1397705	0.84
314.0796204	0.16
317.0885925	79.36
319.3655396	0.15
331.8328247	2.73
332.6375732	0.66
333.4342651	0.12
337.2199097	0.06
338.9148560	0.21
341.2615967	0.55
345.2246094	0.14
347.1365967	100.00
347.8165894	0.28
349.0758667	0.20
352.7553101	0.35
357.0192261	0.33
359.3303833	1.53
360.9381104	0.31
365.2946167	0.35
369.4716187	0.15
370.7778320	0.04
372.7760620	0.14
375.1651001	1.02
376.3032837	0.42
377.1201782	0.42
383.3491821	0.06
385.2014771	0.47
387.3010254	0.20
393.3145752	0.15
393.9447021	0.17
395.1504517	1.47
407.3041382	0.30
411.2351685	0.48
414.8849487	0.78
425.4057007	0.17
432.9992676	1.27
449.4542236	0.07
451.0709229	0.28
456.7349243	0.23
462.9802246	0.17
466.6354370	0.94
467.5209961	0.15
475.0536499	0.13
485.2548828	1.04
491.2098389	0.30
513.1651001	0.24
522.9817505	0.15
529.2171631	0.13
531.1861572	0.08
532.7928467	0.34
536.2101440	0.68
540.2910767	0.24
541.1228027	2.11
548.2189331	0.28
559.2664795	0.73
563.1265259	0.59
567.4869995	0.10
569.2395020	0.15
577.1970215	3.07
579.5015869	0.15
580.2583008	0.15
585.4362183	1.18
593.1021118	1.41
595.1146851	0.47
597.4737549	0.36
599.4844360	0.39
611.2553101	7.97
646.0715942	0.18
650.9774780	0.12
653.1354980	0.41
689.4862061	0.15
731.3728638	0.22
796.2999878	0.09
839.1130371	0.20
869.3285522	0.25
875.2368164	4.26
893.1198120	0.54
905.4363403	0.38
911.1425171	8.69
923.0001831	2.20
925.4129028	0.25
941.0155640	7.66
941.7625122	0.11
1029.2583010	0.10
1110.1578370	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1387.5575
Annotation	Unknow
Peak:m/z	Relative Intensity
505.1636353	0.83
507.3383179	0.77
565.2153320	3.47
571.3331909	0.61
589.0565186	0.42
633.5701904	1.31
693.2944336	100.00
693.9494629	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.291
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.1107483	0.03
149.1819763	0.04
165.4901123	0.04
175.1112061	0.02
198.2529907	0.07
216.0044861	0.08
245.3977356	0.07
263.2919006	0.17
299.3036804	0.02
306.4513855	0.35
324.6695557	0.04
327.0200195	0.05
337.2951355	100.00
338.0288086	0.26
397.3125610	0.05
416.9564514	0.04
435.5522156	0.02
460.3373108	3.59
461.7522278	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	634.2258
Annotation	Dahuribirin C
Peak:m/z	Relative Intensity
186.0641327	0.17
188.0362549	0.14
190.1878967	1.02
194.8854523	0.13
199.2335663	0.12
200.7113037	0.22
203.0746613	8.10
214.1542358	0.11
215.7172241	0.50
216.9765015	0.36
218.0357513	9.88
227.3471375	0.23
229.2111816	0.80
231.0908508	16.21
233.0806274	59.64
243.3104553	0.28
245.1863403	0.30
251.0957947	0.40
269.0768433	3.25
273.0681152	0.23
287.1380005	11.52
291.4067383	0.36
296.2376709	0.11
299.0916748	15.51
317.0811768	100.00
327.3184814	0.40
332.0444336	0.32
347.2086792	0.13
370.4368286	0.11
379.0515137	0.04
401.3299561	0.08
417.6420288	0.06
436.7566528	0.18
466.1698608	0.13
478.4298096	0.62
507.3949585	0.24
553.0347290	0.35
560.6135864	0.58
576.2313843	0.18
583.7376099	0.27
584.5156860	0.31
585.1162720	0.55
601.4324951	1.51
602.5733643	25.21
603.2606812	69.34
615.4087524	0.30
616.4573975	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1613
Annotation	Isorhamnetin-3-Glucoside-4'-Glucoside
Peak:m/z	Relative Intensity
182.9740295	0.11
187.1678619	0.04
188.0435028	0.03
198.1325378	0.03
199.1966553	0.08
199.9109497	0.02
207.0015564	0.04
213.9264526	0.23
216.2063599	0.06
225.2406464	0.11
226.1107483	0.03
227.2625427	0.35
228.1749878	0.04
238.9944458	0.20
240.9965057	0.03
243.1633606	0.50
244.024292	0.26
246.1702728	0.08
252.9530792	0.05
254.2529449	0.45
255.1616364	2.86
256.1943665	0.14
259.1933289	0.39
269.1703491	0.06
271.0255737	6.85
272.0519409	1.19
285.1931458	0.07
286.0022888	0.03
287.2082825	1.01
289.4028931	0.12
293.0596313	0.04
296.8013306	0.02
300.0221863	19.91
300.9508057	0.44
311.0666504	0.10
313.2976074	0.45
315.0452271	100.00
316.2246704	0.49
329.2115479	0.12
340.3248291	0.02
341.2434082	0.20
342.2636719	0.04
351.2200317	0.02
355.2944336	0.04
357.1481323	1.05
372.1218872	0.07
383.138916	0.15
387.1244507	0.15
418.7973633	0.11
419.5411987	0.03
441.5012817	0.07
443.3327026	0.07
446.9877319	0.03
461.3320923	0.03
477.2637329	0.06
479.2219238	0.02
503.2173462	0.74
521.2409668	0.06
561.3293457	0.06
563.012207	0.16
577.3641968	0.04
579.1536865	0.14
591.0479126	0.32
592.3812256	0.02
595.1947021	0.33
603.2160034	0.10
604.9735107	0.25
608.0950928	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	771.2304
Annotation	Kaempferol 4'-methyl ether 3-(2Glc-glucosylrutinoside)
Peak:m/z	Relative Intensity
219.2347717	0.05
243.3762970	0.04
252.9028320	0.17
258.1436768	0.28
266.0223389	0.12
269.2189941	0.07
281.1382751	0.04
282.2478027	0.03
286.8889160	0.08
301.2493591	0.53
310.1203308	0.03
313.1111755	2.90
314.3502197	0.05
321.1115112	0.24
324.0981445	0.09
325.0962830	0.87
339.3280640	0.08
341.3155212	0.17
343.2048340	14.96
350.2647705	0.14
351.3143005	0.04
353.3107300	0.09
364.1123047	0.03
367.0893555	3.59
367.9735107	0.12
373.2698975	0.59
377.3945923	0.03
379.4143066	0.20
381.0239258	0.74
385.3433228	0.11
387.2061768	0.05
391.2183228	0.54
397.1367798	4.70
409.1892700	2.49
427.2923584	2.67
428.9439697	0.15
439.2193604	0.16
445.1206055	26.95
447.0921631	0.44
451.2474976	0.06
453.1735229	0.17
459.0583496	0.15
463.1378174	100.00
463.7789307	0.62
466.3953247	0.25
469.2473755	0.12
471.0869751	0.15
477.3673706	0.18
479.2047729	0.06
484.5567017	0.07
487.2319946	3.31
489.1493530	0.61
499.4693604	0.03
505.0631104	10.90
505.7531128	0.13
511.1985474	0.31
513.0588989	0.14
520.4752808	0.07
529.0296631	0.32
538.1368408	0.19
539.1350708	0.02
541.2102051	0.28
543.3939819	0.28
553.2366333	0.49
555.2460327	1.66
557.1011963	0.22
559.1657104	2.29
564.7051392	0.13
565.8455811	0.10
571.1061401	2.60
573.2319946	1.59
575.0844116	0.21
577.9200439	0.43
589.2002563	4.57
589.8375854	0.02
591.1699829	3.04
603.3714600	0.16
607.1663818	19.30
608.5186768	1.47
609.2488403	34.39
614.6668701	0.12
619.9102173	0.03
625.0620117	74.37
625.8325195	0.31
631.3035278	0.11
633.3090820	0.85
637.3042603	0.13
638.5405884	0.30
639.2927246	0.39
645.3236694	0.15
651.1163940	6.47
656.9941406	0.07
667.0200195	0.17
675.0768433	2.16
675.6913452	0.03
684.7853394	0.05
686.9373169	0.30
687.5687866	0.10
699.1309204	0.19
699.7362671	0.17
704.2880249	0.09
704.9968872	3.21
716.9920044	2.29
727.2672729	0.06
734.4720459	0.08
735.1684570	3.56
753.1546021	26.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.2192
Annotation	Butrin
Peak:m/z	Relative Intensity
191.1894836	1.16
194.0984955	6.14
209.0581207	56.85
209.6686249	0.08
245.0864716	0.97
279.0968018	0.24
285.1479492	0.10
287.1676636	0.21
305.1463623	1.02
323.3386841	0.17
347.3631592	0.57
352.5835571	0.13
357.2893066	0.08
369.1426392	0.29
370.5052490	1.43
371.1769409	0.04
377.3963013	0.50
387.4063721	0.22
399.2667236	0.28
402.7233887	0.16
411.4160156	0.09
412.6342773	0.72
449.2059937	5.57
452.7087402	0.17
453.4664307	0.36
455.1064453	0.17
459.3332520	0.23
461.0831299	0.28
470.7983398	0.83
473.3453369	0.69
497.6109009	0.09
512.7275391	0.62
515.1485596	100.00
557.1270142	6.99
578.2994995	0.33
596.4649048	0.58
597.2431030	0.52
615.0745239	0.54
639.3695679	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	369.1686
Annotation	8-Geranyloxy-5-methoxypsoralen
Peak:m/z	Relative Intensity
104.9986725	0.28
111.3591309	0.22
114.2195053	0.10
116.2588120	0.35
119.0468445	0.28
121.0541534	0.34
124.8747711	0.09
126.7785339	0.45
130.9048615	0.22
137.0161743	24.52
138.7376556	0.11
140.8701477	0.19
143.1277161	0.26
145.2445831	0.25
151.1917725	0.17
155.0325317	0.22
156.9856262	1.93
158.8817749	0.13
163.2801514	0.38
165.0694580	0.98
165.8754120	2.22
167.1765442	0.04
169.0454102	0.37
171.0388947	0.25
173.1910706	0.14
174.8995972	0.82
178.0539551	0.30
179.0777893	0.61
180.0236206	0.51
181.2055969	0.51
183.3049927	0.06
186.0768585	0.21
189.0738068	0.54
192.1295471	0.08
193.2040253	0.36
196.9752655	0.09
198.8736725	0.31
201.4013519	0.10
203.2859192	0.37
208.8149414	0.47
211.2209167	0.97
215.2138977	0.12
219.3953247	0.11
222.9961548	0.30
225.1026306	0.41
227.1536560	0.22
228.9827881	0.57
231.1659851	1.63
233.0627136	100.00
233.9271545	0.32
237.0626526	0.22
239.1684875	0.62
243.1278076	4.27
243.9896851	0.48
249.1588745	0.80
253.0521545	0.26
256.2642517	1.26
257.1951294	0.30
259.0657959	9.60
261.0376282	0.94
262.3065796	1.37
267.1740417	0.18
268.9726868	0.37
273.0639954	2.89
275.0393066	0.57
277.0974121	0.24
279.3251343	0.39
281.1384277	0.43
285.8768311	0.29
295.1590576	0.78
298.9710388	0.41
299.8191528	0.35
309.2033691	0.43
311.2193909	0.35
313.9790039	0.18
315.8828430	0.29
320.3051147	0.08
322.6869507	0.20
323.6323242	0.18
325.0001526	0.42
327.0601807	6.56
327.9642944	1.01
333.2734680	1.77
334.0244141	0.55
335.4125366	0.12
337.3201599	0.12
349.1455994	0.16
351.2990112	7.49
355.1936340	0.13
368.9310913	0.20
370.1806946	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.0196
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.0343666	0.05
69.1415710	0.03
84.8945312	0.51
86.9959412	1.06
93.1148376	0.05
110.9101562	100.00
111.7823181	0.03
126.8019714	0.02
129.0098572	2.79
130.9696350	0.81
147.0553284	0.05
155.1413574	0.18
172.8875732	18.25
173.6784821	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	249.06
Annotation	Unknow
Peak:m/z	Relative Intensity
71.7345886	0.22
73.0238495	0.31
80.9598846	0.81
85.0026245	1.13
87.1484528	0.41
94.9105225	0.13
96.9461517	0.52
98.9284668	1.01
100.9750214	0.96
104.8717041	0.34
108.9479218	4.30
112.8866425	0.17
113.5491486	0.13
114.8986359	5.28
116.9037018	1.96
120.1568604	0.11
122.0227356	0.15
122.9451904	0.37
126.8733063	47.41
132.8273926	0.44
135.0324097	0.25
136.0102539	0.09
138.0291748	0.11
145.0187531	2.11
145.8622131	0.16
146.8601074	0.06
151.0408173	0.04
155.0083771	0.06
156.0581360	0.06
157.0484772	0.45
158.9592590	0.29
160.0875092	0.28
161.0518951	0.16
162.1576538	0.20
163.2163086	0.06
167.2323761	0.20
171.0149841	0.42
173.0527191	15.00
175.0561829	1.80
176.0903931	0.16
177.0126495	0.13
179.2277069	0.17
182.9851685	2.15
185.9402618	0.31
186.9597473	0.45
189.0035858	0.46
190.0557098	0.55
191.0069885	0.31
193.0776520	1.41
197.1577148	0.29
198.2078094	0.29
199.1134033	0.16
200.8922272	0.09
201.5389404	0.12
203.1199188	1.17
204.1804657	1.59
205.0275574	0.71
206.2288361	0.16
207.1369171	0.43
208.2170563	0.04
209.1734161	0.20
210.2177582	0.09
211.7235260	0.10
213.0437469	5.10
214.1840668	0.05
214.9074249	0.04
217.1280212	0.07
218.9888611	0.51
219.8278656	0.13
221.1500702	1.03
225.1914520	0.45
225.9629974	0.27
227.3271332	0.19
228.0173798	0.76
229.0856476	1.21
230.9384155	100.00
232.0950317	0.24
234.1423492	0.16
240.1247406	0.11
241.2078400	0.25
249.2472687	0.04
255.1688843	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	563.1409
Annotation	Clinacoside B
Peak:m/z	Relative Intensity
268.9671326	0.09
278.9761963	0.02
281.0438232	0.02
293.0878906	23.88
293.9702759	0.01
294.9577026	0.01
297.2606201	0.07
309.1789551	0.06
310.3927002	0.07
311.1563110	2.56
321.2308960	0.13
323.1705933	1.37
325.0501709	0.04
335.2941895	0.58
337.2630005	0.09
341.1136475	2.27
349.2075195	0.05
351.1924438	0.06
353.1929932	0.60
355.1250610	0.39
358.9453125	0.05
365.3314819	0.06
371.0241089	0.04
377.2761841	0.17
383.3673706	0.09
395.1004639	0.24
401.2783813	0.01
413.1470947	100.00
414.2164307	0.12
419.1226807	0.03
430.4445801	0.04
431.1840210	0.64
433.1590576	0.04
443.2211304	3.36
445.0899658	0.04
449.0630493	0.04
456.3178101	0.03
473.3072510	0.43
497.0311890	0.05
503.4330444	0.10
515.4775391	0.05
519.0053711	0.03
545.4109497	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1765
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
131.0279846	0.03
143.3484497	0.02
149.2864990	0.05
161.0106812	0.25
165.1517334	0.04
171.1752319	0.05
179.0795135	0.65
189.0453033	0.09
201.1325989	0.02
209.1759033	0.03
213.3061523	0.07
228.0786133	0.10
231.1746521	0.03
233.1886597	0.03
243.2379150	0.09
246.9644165	0.14
249.0314941	0.12
267.2066345	0.15
277.1824341	0.03
306.2424622	0.23
329.2383728	0.06
331.0597839	0.05
333.2598267	0.13
337.2427979	0.14
345.1902771	0.12
347.1842041	100.00
347.8428955	0.14
349.2354126	0.32
350.0235596	0.02
351.3871765	0.10
375.1484070	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.2158
Annotation	Unknow
Peak:m/z	Relative Intensity
210.7063293	0.06
224.8995361	0.05
231.8550568	0.19
236.9475708	0.07
239.2276306	0.13
240.8782043	0.09
247.0402985	0.26
252.8536682	0.11
254.9058533	0.05
259.1961975	0.04
263.1296692	0.18
271.2203979	1.05
272.9618530	0.08
277.0718994	0.35
280.9028931	0.18
281.5924377	0.04
282.9980774	0.74
286.2297974	0.09
289.1751709	0.04
291.1041260	0.13
295.2192078	0.05
301.2182617	0.42
305.4493408	0.11
307.0194702	0.20
308.1245422	0.12
313.1465759	0.19
317.3447571	0.03
323.0337524	0.15
328.1301270	0.05
329.4129639	0.14
331.0711060	0.65
337.1649780	0.04
340.9472351	0.11
345.4136963	0.16
347.3735962	0.07
349.0852051	45.01
365.1005859	6.72
366.7708130	0.12
381.2215576	0.25
383.0643921	33.57
383.7211914	0.04
389.4364014	0.09
395.2567139	0.31
397.1403198	0.41
405.7153320	0.06
407.1199951	0.03
411.2179565	0.11
413.0651855	0.38
415.2672729	0.14
416.9980469	2.72
425.0896606	0.42
429.3809204	0.08
433.1934204	10.70
435.4802856	0.13
442.6032715	0.06
454.8944702	0.22
457.3369141	0.21
459.1928711	0.14
467.1342163	0.18
471.0561523	0.04
475.3483887	0.15
513.4077759	0.13
525.1389771	0.06
526.0974731	0.12
527.1289673	0.82
529.1428833	0.16
534.1592407	0.18
537.9161987	0.16
539.4342651	0.08
541.0751343	0.43
541.9899292	0.13
542.9702759	0.61
544.9600220	7.70
559.2999268	0.04
560.8072510	6.88
561.5109253	0.06
562.8477783	0.05
577.1998901	0.32
579.0064697	28.21
591.4117432	0.03
595.0816650	100.00
595.7719727	0.43
602.9530640	0.14
609.2797241	0.37
617.6297607	0.21
619.0138550	0.12
620.9307251	0.25
622.9661255	0.10
626.4092407	0.08
636.9974976	0.06
657.3893433	0.13
664.7888794	0.08
674.5789185	0.07
680.9610596	0.16
686.9879761	0.09
695.0356445	0.11
696.5540161	0.16
704.0137329	0.04
705.1204224	1.26
722.7738647	1.26
723.4182739	0.28
728.7432861	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	472.1584
Annotation	Folinic acid
Peak:m/z	Relative Intensity
147.8174744	0.27
179.0746307	0.07
204.1886902	0.03
205.0717773	0.08
232.9817810	0.04
258.2568665	0.50
275.0094910	0.09
298.1422119	0.19
300.1581421	43.54
301.1784668	0.22
309.5363770	0.07
310.1996155	0.06
323.4257812	0.44
336.9660034	0.05
341.3535767	0.11
343.1705322	22.82
344.1440125	0.09
351.3571777	0.29
356.2394104	0.22
357.2439880	0.17
360.3700867	1.44
365.5408325	0.24
366.3273315	0.36
367.2927856	0.16
385.2736511	7.27
386.2346802	2.99
401.5432434	0.08
404.2456665	100.00
405.3972473	0.17
409.8698120	0.06
411.2489929	10.41
412.3085632	0.05
426.3572693	0.21
428.4316711	2.05
429.2392883	15.44
430.1416931	0.04
442.2713623	0.05
454.1289978	22.13
454.7553406	0.12
455.4239807	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0553
Annotation	Fludiazepam
Peak:m/z	Relative Intensity
94.9576416	1.67
96.7124863	0.06
98.0713577	0.14
112.9613495	14.60
114.0031204	4.52
125.1138458	0.16
130.9273224	100.00
145.5023804	0.08
150.9070129	0.17
163.9834442	0.17
164.9171906	0.04
173.0412445	0.05
173.8007965	0.07
185.3769226	0.25
199.0511169	0.12
202.2723694	0.08
209.4771118	0.08
213.1433105	0.04
216.1804199	0.11
217.0340271	0.18
224.1104126	0.21
225.1472778	0.19
233.0677185	0.18
239.1213684	0.09
242.1405029	0.56
254.6481018	0.06
257.0114136	0.69
258.2368774	0.21
259.1108398	0.04
269.2151489	0.04
283.0499878	3.36
284.9799194	0.06
286.1362305	1.81
287.5848389	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	573.1738
Annotation	Fesumtuorin D
Peak:m/z	Relative Intensity
162.9018707	0.20
165.1795197	0.15
166.9111938	0.02
171.0508575	0.85
172.0989380	0.03
173.0689850	0.91
174.2752533	0.50
175.1000519	0.59
177.2413330	0.07
177.9478455	0.04
178.7630005	0.04
180.1211700	0.06
181.0088348	0.03
182.1694946	0.16
182.9719238	0.06
183.5977020	0.12
184.2068176	0.09
185.1132355	0.11
185.9307251	0.09
187.1073151	0.15
189.2946777	0.07
193.5525055	0.11
195.0191040	0.31
197.0454407	0.15
199.0917969	4.06
201.0584106	2.76
202.1531830	4.22
202.9872742	65.95
205.0620728	0.02
209.1605682	0.09
210.0771637	0.08
211.0888214	0.13
212.0316925	0.08
213.1182098	0.66
215.1414032	0.83
217.0346375	0.08
218.2088470	0.02
219.1792908	0.27
220.1808167	0.14
225.1894531	0.62
226.0630798	0.11
227.1310730	3.89
229.1515350	0.03
231.2742004	0.11
233.1042786	0.20
235.3234253	0.08
237.1265564	0.26
239.0293732	0.40
240.5474548	0.54
241.1520386	2.85
242.0974426	0.05
243.1219635	0.47
244.8976440	0.05
246.7109528	0.10
247.3220825	0.05
249.2498169	0.08
251.1311646	0.28
253.0196075	0.01
255.0556793	0.21
257.3055725	0.18
260.1862183	0.14
262.9226074	0.03
263.8192749	0.09
264.8363953	0.03
267.1395569	0.13
269.0738525	22.59
276.3237305	0.05
278.4627075	0.04
281.2429199	0.04
283.2451477	0.03
285.2246704	0.09
287.0893555	100.00
291.2442627	0.04
293.0834961	0.27
295.4575806	0.03
297.2430115	0.10
299.0645142	0.25
301.2299805	0.15
304.1206665	0.06
306.9959106	0.03
311.2468872	0.24
313.3184204	0.06
315.6848145	0.03
317.1958618	0.03
323.3379517	0.04
325.3006592	0.09
333.4332886	0.16
335.1039429	0.09
339.0843506	0.04
341.1870117	0.03
343.2408447	0.06
345.1976929	0.08
350.5036011	0.02
353.1638794	2.12
361.1326904	0.04
368.2304688	0.02
371.2298584	7.42
382.1912231	0.03
392.4561157	0.02
397.4088745	0.08
429.3378296	0.02
430.7219238	0.07
435.2939453	0.05
443.3704834	0.06
453.3264771	0.14
454.3917847	0.04
460.1787109	0.05
468.1822510	0.13
471.2225952	0.19
473.7074585	0.05
481.2279663	0.03
484.2277222	0.02
487.1896973	0.15
489.1483765	0.90
497.5205688	0.01
500.8646851	0.02
512.2565308	0.11
513.2850952	0.02
523.4777222	0.11
527.5307007	0.01
529.6085205	0.08
537.1875610	0.22
538.9580688	0.03
540.3892212	0.04
544.3649292	0.02
554.2232666	0.30
555.3074341	6.94
557.8598022	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1515
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
173.2957611	0.02
175.0171967	0.68
194.9051666	0.03
197.0942841	0.03
198.0800018	0.37
199.0283051	0.40
201.0831757	0.43
211.0621338	0.06
211.9629059	0.08
213.0422821	0.41
214.2716675	0.05
215.1732483	0.15
216.9344788	0.23
223.2805176	0.05
225.0738525	0.03
241.0479431	0.58
243.1530609	0.28
255.2832489	0.04
257.0687866	0.10
267.1777954	0.16
268.2508545	0.04
269.15271	0.22
285.0456848	100.00
286.1911621	3.55
299.0091553	0.05
309.2172241	0.06
311.1399231	0.29
323.25177	0.26
325.0953369	0.09
327.1150513	0.68
332.7151489	0.06
340.6398315	0.26
341.2445068	1.74
349.418396	0.05
351.4159546	0.01
352.0900879	0.03
353.0998535	0.45
357.269165	0.02
369.184021	0.05
377.4451904	0.07
383.2836914	0.28
385.3924561	0.07
393.5757446	0.08
394.9995728	0.08
407.2825317	0.09
413.237915	0.12
425.093689	0.15
428.9846191	0.03
430.1867065	0.11
443.1558838	5.17
445.9115601	0.03
447.2114868	0.54
448.0778809	0.02
455.4559937	0.05
457.2961426	0.02
461.1984863	0.09
463.2398071	0.39
471.3787842	0.02
473.2270508	1.43
474.4092407	0.07
483.3643799	0.08
485.1300049	0.03
503.2774048	0.39
517.4260254	0.04
534.4092407	0.08
545.1154175	0.04
549.0407715	0.03
557.0872192	0.03
561.3527222	0.11
575.2814331	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1562
Annotation	Isoscoparin 2''-O-ferulate
Peak:m/z	Relative Intensity
177.0632324	0.08
179.0948944	0.23
186.0762329	0.03
193.0929260	0.14
202.1482239	0.15
203.0284271	0.04
212.1915741	0.06
215.2118530	0.10
217.2405243	0.12
220.0242767	0.06
221.0495148	0.91
227.1737976	0.36
233.1381378	0.52
242.6607056	0.23
245.3888397	0.31
251.5354919	0.08
256.1112976	2.21
263.0722656	0.45
267.1581116	0.11
269.0512390	0.35
271.0692139	0.06
280.1226501	0.06
284.0133667	31.98
285.1619263	8.70
285.9804688	0.04
295.2600708	0.36
297.0625000	1.59
298.1810303	3.65
299.1112671	100.00
299.9259338	0.03
300.7078857	0.02
305.1797485	0.03
311.1045532	0.35
313.1220703	6.78
314.1112366	0.13
317.1879272	0.06
321.3859863	0.16
323.2125244	23.24
324.1175537	0.06
325.3843994	0.07
327.1636963	0.32
329.2266846	0.17
331.1503906	2.20
337.2357178	3.60
339.0948486	0.03
341.1840210	7.07
350.5311890	0.11
353.1959839	0.41
361.1526489	0.14
364.9435425	0.05
367.2098999	0.11
371.1386719	0.81
379.0305176	0.22
383.1134644	0.19
389.4965210	0.07
391.3444214	0.07
395.8466797	0.10
397.3764648	0.07
406.9431763	0.06
413.0111084	0.03
421.3656006	0.10
425.5241699	0.04
429.1929932	0.17
431.1899414	0.16
432.4240112	0.09
433.4348145	0.05
443.1289673	2.05
461.2057495	1.68
463.1772461	0.07
474.9896851	0.14
475.6464233	0.03
491.6437988	0.08
493.2265625	10.09
500.0581055	0.04
517.2553711	0.09
531.9717407	0.08
535.3970337	1.13
539.4592896	0.17
541.1156616	0.20
551.2059326	0.36
575.2349243	0.72
590.9935913	0.38
591.7642822	0.11
593.2904663	0.68
595.1967163	0.14
606.3948364	0.04
615.4024048	0.27
617.2669067	0.06
619.4003296	0.31
621.5427856	0.06
622.4246216	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	539.14
Annotation	Limocitrol 3-glucoside
Peak:m/z	Relative Intensity
155.8876648	0.02
164.8348999	0.02
197.3638916	0.03
209.4081726	0.03
212.9417877	0.17
217.0750122	0.02
230.5356445	0.22
231.1992798	0.60
233.2302094	0.02
235.0570526	0.05
237.2099457	0.02
245.8464355	0.07
247.1986542	0.07
249.0390930	0.24
252.7812195	0.03
253.4034271	0.07
259.2908325	0.02
260.1639404	0.06
261.2537842	0.06
265.4684753	0.02
269.1018066	0.04
271.3424072	0.05
289.2431030	0.02
291.0684204	0.55
297.3846130	0.10
299.2531128	0.05
311.3640137	0.03
315.1038818	0.05
322.6026001	0.10
328.9512329	0.07
331.2511597	0.03
333.5446777	0.03
340.6075439	0.17
341.2456055	0.13
343.1636353	0.02
345.2458496	0.09
356.7774658	0.40
357.4065552	0.03
358.9862061	0.89
370.9745483	0.06
374.5249023	0.09
375.1496582	1.91
377.1701660	100.00
377.7795410	0.41
383.2974243	0.10
389.1397705	0.39
392.4139404	0.65
393.1588745	2.42
394.9599609	0.28
397.3840332	0.04
407.4378662	0.13
410.3864136	0.02
415.3850098	0.06
419.4812622	0.02
421.0993652	0.07
423.0678711	0.04
427.1400757	0.07
427.7995605	0.06
433.0838623	0.15
435.1550293	0.10
437.1977539	0.03
438.0976562	0.03
439.4216309	0.06
443.3176270	0.04
456.4481201	0.01
457.1096802	0.12
461.4051514	0.14
465.1432495	0.10
468.7558594	0.04
475.5485229	0.08
477.2374878	0.07
479.0582886	0.07
485.3161621	0.12
491.1658936	0.23
493.1886597	0.26
493.8071899	0.05
495.1480713	0.54
503.1012573	1.21
507.3181152	0.04
520.4551392	1.54
521.1076660	2.35
521.7626343	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1097.3359
Annotation	Unknow
Peak:m/z	Relative Intensity
311.1859741	0.04
339.2615051	0.05
413.0815430	0.20
431.2575684	0.59
443.5481567	0.04
449.2195740	22.49
450.1685181	0.05
459.2230225	0.11
595.2641602	9.43
611.3623047	0.90
627.1981201	2.85
637.0661011	0.06
721.2878418	0.05
757.2645264	9.00
771.3059082	0.35
789.1949463	100.00
789.8502808	0.65
813.2691650	0.44
854.9693604	0.20
934.6966553	0.59
935.3400879	1.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	838.49
Annotation	8-deethyl-Concanamycin A
Peak:m/z	Relative Intensity
243.1223145	0.10
253.1217804	0.34
261.7827148	0.23
270.3949280	0.10
285.3264771	0.35
290.4067078	0.74
292.3174744	0.14
293.3177490	0.10
295.0171509	0.14
306.3905945	0.11
307.4045410	0.27
308.9118958	0.13
313.4672241	0.41
314.3372192	0.11
322.4934692	0.25
327.1088257	0.12
342.3708191	1.36
343.2423706	0.19
349.3829041	0.08
350.0831909	0.09
352.4085999	0.29
354.4519043	0.67
359.4940796	0.13
367.6667786	0.14
369.7530518	0.23
376.0213013	0.11
377.3056641	0.32
384.1917725	1.18
384.9364624	0.27
386.2452698	0.46
394.4124756	0.09
398.3274536	0.55
399.3225098	2.64
416.2257690	0.37
419.4491577	0.13
423.5356445	0.42
427.4739990	0.33
428.2899170	0.39
436.5581055	0.47
440.3199463	0.29
441.2201538	0.35
443.2146606	0.45
444.2356567	1.51
445.5572510	0.08
452.3698730	0.58
455.4639282	0.52
456.3939819	0.82
457.1591187	0.32
464.2730713	0.68
465.2516479	0.09
467.2180176	0.07
469.5947876	0.27
470.4376221	0.15
471.9247437	0.44
473.0479736	1.69
473.9227905	0.31
474.6008301	0.31
476.8854980	0.20
480.7432251	0.82
481.4188843	0.12
484.3530273	1.45
485.4042358	0.62
486.2919312	0.14
489.4087524	1.01
490.1453247	0.35
497.4171753	0.15
498.2997437	0.55
498.9733276	0.08
503.5534668	0.78
512.3787842	1.13
513.4465942	0.15
514.3943481	0.35
519.7633667	0.73
522.3445435	0.28
525.4411621	0.21
529.3011475	0.11
531.3901367	0.99
537.4096680	0.63
541.4307251	5.58
542.2972412	0.24
552.2488403	0.10
553.2954712	1.43
554.5033569	0.50
560.4259033	0.12
562.4734497	0.08
567.1364746	0.14
568.3217773	2.31
569.3692017	11.77
570.2988281	0.97
576.3606567	0.16
582.0263062	0.41
582.9390259	0.20
583.7022095	0.16
584.4425659	0.83
585.1225586	0.30
586.3787231	5.91
587.5177612	0.34
591.4478149	0.05
593.1495361	0.73
594.4517212	0.64
595.4616089	0.32
599.2788696	0.11
600.3571167	0.55
606.3497925	0.15
611.3099976	1.95
612.6536255	0.07
616.5808716	0.22
621.1665039	0.12
626.8515015	0.60
628.2725220	4.15
629.2292480	1.22
632.1817017	0.08
634.1802979	0.40
637.3508911	0.68
638.3354492	0.66
639.0060425	0.33
645.6147461	0.11
646.6135864	0.07
647.6782837	0.21
648.5117188	0.24
650.2736816	1.21
650.9868774	0.06
654.4459839	2.83
655.3429565	0.32
662.0691528	0.23
664.2271118	1.35
665.2444458	1.15
666.7993774	1.89
667.5661011	1.65
674.5499268	0.21
676.4204102	0.60
680.4766235	2.45
681.8371582	2.03
682.5386963	10.70
683.6203003	14.42
684.5952759	0.19
690.7892456	0.50
691.6729126	0.82
692.5140991	0.65
693.5317993	0.63
694.5588379	0.85
696.7795410	2.02
697.6921997	0.36
698.3067017	0.11
699.4543457	3.72
700.5283813	0.32
701.5212402	0.11
705.1879883	0.34
707.3093872	3.12
708.4043579	22.41
709.4318237	10.09
710.5641479	0.65
711.6296997	0.83
713.5635986	0.23
719.4617310	0.31
723.2899780	0.14
724.8489380	6.57
725.4663696	61.44
726.5525513	7.87
733.5057983	0.22
735.6779785	0.17
737.5271606	0.18
741.9668579	0.29
750.6516724	2.37
751.5354004	0.12
752.6459351	0.62
753.4641724	0.15
755.7593384	0.21
759.5062256	0.50
760.4145508	0.76
761.5152588	0.63
762.9151001	0.09
765.5635376	0.06
768.5734863	0.66
769.7186890	0.21
770.4135132	0.08
775.3251343	0.73
775.9569092	0.45
776.6945190	0.73
777.5051880	1.93
778.5024414	14.95
779.4728394	2.78
780.4905396	0.54
786.9172974	0.20
792.5012207	3.83
793.4966431	53.53
794.5453491	11.70
795.6757202	1.04
796.4084473	5.99
797.6217041	0.87
802.3467407	0.43
803.4277954	5.28
804.4605103	1.22
810.5390015	82.58
811.5503540	15.08
812.1932983	0.25
820.5569458	52.49
821.4871826	100.00
822.6271973	11.56
823.3125610	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	370.2002
Annotation	Falciformin
Peak:m/z	Relative Intensity
109.1589050	0.07
130.9497528	0.03
137.0962219	22.89
145.2237091	0.02
149.5086517	0.02
167.9739532	1.07
174.8204346	0.03
198.3643646	0.08
199.1662750	0.01
203.0112915	100.00
203.8697510	0.01
219.9912415	0.03
229.0165710	1.49
231.1566162	0.10
232.0285034	0.03
233.9875488	3.33
241.2287292	0.04
243.0807800	1.62
243.8759155	0.13
257.0548096	0.31
268.9298706	0.05
282.9997559	0.12
297.0819702	0.01
301.1225281	0.03
314.1316833	0.02
327.1409302	0.08
328.0553589	0.28
329.0158081	0.04
338.9969788	8.68
339.6034546	0.15
352.2649841	0.23
353.1361389	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	598.18
Annotation	Unknow
Peak:m/z	Relative Intensity
179.1542969	0.59
195.0791016	2.77
196.2698975	0.26
219.0470886	3.20
234.8595886	0.96
249.2206268	1.17
262.9906616	1.06
264.1196899	1.47
265.1090088	0.52
281.3746948	3.55
282.2048340	1.39
289.1273499	37.95
290.0958862	59.81
291.0982056	0.29
300.0419006	0.32
302.1901245	1.73
308.7683411	1.28
314.0528564	4.41
331.2656250	10.74
332.0731201	19.25
336.9120483	1.16
339.2291870	2.48
340.2299194	1.15
354.9807739	8.62
356.1840210	14.76
368.1268311	1.35
374.2064209	0.55
377.9639893	1.61
382.1642456	0.29
384.7886963	0.50
389.2642822	1.49
392.2910156	1.18
396.5094604	0.29
397.8743896	5.30
399.4167480	7.40
400.1512451	14.92
408.3883667	0.84
415.1850586	5.03
416.2258301	6.12
417.1453247	11.66
418.0338135	23.88
424.0969849	1.66
433.0741577	31.91
434.0375977	92.65
435.0866089	23.01
436.0585327	100.00
436.6848755	0.94
439.9465942	0.77
442.0706177	0.88
446.2095947	2.04
450.9296265	26.58
451.9848633	88.99
452.6199341	1.08
460.0216064	6.84
465.6008911	2.09
475.2327881	4.88
476.0811157	19.11
477.0928955	3.75
478.1747437	9.24
483.8118286	3.21
494.1303101	0.32
496.0749512	1.86
500.1329346	1.98
513.9100952	1.60
517.9371948	0.69
526.0610352	5.14
544.1803589	30.83
554.8164673	1.32
562.1550903	62.87
579.4531860	10.85
580.0847168	55.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.13
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
113.0729752	0.36
116.8809967	0.12
118.8847656	0.63
142.7857361	0.29
146.0758057	2.48
147.1290283	0.15
161.0912476	2.20
164.1432190	2.21
179.0453644	100.00
180.9907837	0.19
191.2561340	0.12
193.1217041	0.40
207.0623627	7.53
211.0541077	0.30
222.8828583	0.41
225.1484070	0.71
231.0516968	0.17
249.2678528	0.25
285.1508179	0.14
292.1411133	0.22
300.1640015	0.17
327.0994263	0.79
340.8270874	31.48
341.5067749	0.12
367.9347229	0.06
369.1490173	0.10
370.2834167	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	633.19
Annotation	Unknow
Peak:m/z	Relative Intensity
190.0344849	0.80
193.2905731	0.25
200.2327881	0.09
201.1275635	0.21
202.1374512	0.89
203.0057678	2.39
212.3485565	0.35
215.1588440	0.25
216.2317810	0.66
217.4693909	0.95
218.0752411	23.59
224.9048767	0.35
229.0821228	1.91
230.0242767	0.27
231.0967560	50.18
233.0237427	100.00
233.6412811	0.26
240.9677429	0.27
243.3900146	0.09
245.0773621	0.67
246.9373016	0.46
250.0701294	0.09
253.5693665	0.22
257.2214355	1.48
269.2667236	0.25
270.9488525	0.86
273.1473389	0.46
275.2000122	0.14
281.1829529	0.30
292.0623169	0.30
298.5528564	1.21
299.1784058	18.04
309.6494141	0.16
314.9756470	0.98
317.0421143	60.22
317.7356873	0.52
321.7173767	0.21
323.3372803	0.06
325.0620728	0.56
326.0055542	0.30
327.1155396	0.30
330.9317017	0.45
335.1766357	0.62
337.2208252	0.32
341.2504883	0.44
355.0596924	0.73
359.1697388	0.46
383.4869995	0.23
389.1744995	0.13
401.0413818	1.20
405.0620117	0.07
413.2470703	0.12
426.1769409	0.27
463.2935181	0.53
473.0809937	0.44
487.2907104	0.55
491.3058472	0.16
503.2857056	0.46
535.6412354	0.10
548.1336060	0.62
551.3344116	0.05
561.0543823	0.30
569.1835327	0.12
571.6508179	0.07
587.3364868	0.28
591.2536011	0.25
596.9038696	0.27
614.7514038	0.55
615.6989136	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	335.1118
Annotation	Scandenolide
Peak:m/z	Relative Intensity
110.9205475	0.16
119.1065826	0.03
122.9318085	0.10
133.0524902	0.06
134.9218445	0.19
136.8405762	0.05
138.8390350	0.20
145.1386261	0.40
145.8916779	0.24
147.0449219	0.45
149.2619934	0.08
151.1423035	0.07
154.5761719	0.10
159.2645264	0.19
161.1238098	0.40
162.8820496	0.06
167.0164185	0.12
168.9649353	0.04
170.5443115	0.32
173.1116333	0.41
176.9901733	0.71
178.0259552	1.44
179.1816864	0.91
180.9983368	0.05
183.0082397	0.24
183.9748840	0.24
184.9899292	0.97
191.1257935	0.13
192.1711884	0.27
194.9253845	0.51
205.1203613	0.49
207.9962311	0.24
209.1590576	0.24
210.0556335	0.10
211.0559998	0.78
212.4045105	0.09
213.3656921	0.05
215.3277283	0.08
217.8631897	0.07
219.0682068	0.19
222.8824768	0.53
224.9622803	0.24
226.8181458	0.12
230.0046387	0.05
231.2177429	0.20
232.0651245	0.05
233.1427307	0.26
240.8959961	0.20
243.2803040	0.10
248.2535706	0.02
251.1417236	0.05
252.1450500	0.05
254.5460815	0.19
257.1033020	0.33
259.9628906	0.13
261.0835571	0.30
265.2647095	0.34
268.2163086	0.41
272.2944946	0.24
273.0960693	0.03
275.1578979	0.97
277.1783447	0.23
279.4155884	0.15
280.3628540	0.17
281.2626343	0.19
282.3491821	0.35
286.0904541	0.18
287.0064087	0.12
289.3255005	0.23
290.0119934	0.15
291.2504578	0.02
293.1436462	0.22
294.1599121	0.07
299.0346375	3.26
300.1845093	0.12
303.0312805	0.14
304.1607666	0.04
304.8864746	0.13
307.2637329	0.36
308.4310303	0.08
310.7287598	0.15
313.6174927	0.05
315.3233948	1.05
316.9785156	100.00
317.8330688	0.76
320.1184387	0.43
321.3025513	0.11
334.3071289	0.05
335.6110840	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	739.2816
Annotation	Javanicoside D
Peak:m/z	Relative Intensity
224.9821777	1.01
237.1022644	0.04
238.3099365	0.05
238.9816284	0.03
269.0989380	0.06
271.2001038	0.13
287.0446777	0.10
289.2500305	0.12
299.1363525	0.03
307.2135620	0.03
325.3345337	0.05
350.2173157	0.04
369.1328735	0.08
375.4698486	0.16
389.4526978	0.02
399.3569336	0.06
411.2620239	0.04
417.5940552	0.04
425.3073120	0.10
432.5739136	0.04
449.2340088	0.04
451.1348877	0.13
453.5215454	0.13
471.2634888	100.00
472.3175659	0.15
473.6408691	0.15
480.6585693	0.08
481.3079834	0.04
485.1668091	2.13
485.7707520	0.04
487.5501709	0.04
489.5175171	0.10
495.2868652	16.88
497.1860962	0.27
513.1405640	24.94
513.7729492	0.28
517.1806641	0.10
525.2046509	10.71
525.8427734	0.03
531.0894775	2.23
531.7001953	0.14
533.3670044	0.07
535.4681396	0.01
537.4353638	0.77
540.6457520	0.04
542.9562378	16.54
543.6963501	0.15
544.5610962	0.12
555.1459351	0.55
560.7656860	1.84
569.5498657	0.06
572.9403687	15.64
573.6909790	0.25
577.3480835	0.54
584.9358521	0.09
591.2210083	0.06
593.1747437	0.38
594.3531494	0.06
595.1615601	0.39
596.2132568	0.35
602.7597656	0.29
603.5008545	0.11
606.3180542	0.09
615.0247192	1.01
621.6743164	0.06
632.9401855	49.62
633.5724487	0.82
634.4478760	0.15
635.5110474	0.06
637.0277100	0.07
638.2804565	0.08
643.7161255	0.06
653.6545410	0.06
677.4043579	0.29
679.0601807	71.60
679.8436890	0.16
680.5545654	0.18
692.9969482	73.05
693.9299927	0.24
695.0238037	0.21
696.5516968	0.05
704.2139282	0.07
721.1155396	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	163.04
Annotation	cis-p-Coumarate
Peak:m/z	Relative Intensity
118.9585419	100.00
120.9449310	0.05
146.7616425	0.04
163.0063782	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0565
Annotation	Norbergenin
Peak:m/z	Relative Intensity
101.0064468	0.14
103.0328369	0.03
110.9791794	1.18
121.0988464	0.59
128.9465790	6.88
144.6626892	0.06
146.9472656	9.52
149.1555481	0.03
162.9440002	0.02
173.0216827	7.45
189.2419891	0.05
191.0573578	100.00
250.9544983	0.14
251.6060791	0.04
277.0688782	1.28
295.0971069	21.95
298.1646118	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	781.1829
Annotation	Unknow
Peak:m/z	Relative Intensity
265.0028992	0.02
300.2640076	0.05
301.4001465	0.04
305.0617981	0.10
313.0359497	0.08
315.1387939	0.15
316.1837158	0.23
327.2117310	0.03
330.0841370	0.42
331.1506958	4.02
342.3608398	0.05
344.8575439	0.06
346.2373657	0.02
347.3154907	0.04
360.5104370	0.06
367.1416016	0.04
368.9090576	0.07
371.8206787	0.04
387.2753296	0.04
391.1932373	0.12
397.4334106	0.11
413.1730347	0.02
421.2564087	0.05
451.1496582	0.08
457.1535034	0.02
459.8181152	0.06
464.2718506	0.05
469.3648071	0.10
473.5601807	0.06
475.1411743	0.54
477.1886597	0.04
478.3132935	0.11
479.3732910	0.12
489.4180908	0.02
493.1837769	41.09
507.3995361	0.17
517.1453857	0.08
519.2816772	0.15
520.3626099	0.06
521.2849731	0.12
535.2360229	22.77
537.3834839	0.12
539.4174194	0.05
541.5366211	0.04
542.1910400	0.10
543.3662109	0.03
545.2076416	0.12
549.2184448	0.23
550.3396606	0.14
555.3818970	0.26
556.6364746	0.13
561.0602417	0.11
561.6939087	0.02
563.2383423	0.37
575.1967773	8.50
575.8560181	0.11
577.1887207	3.95
582.9626465	0.08
587.3834229	0.07
589.1989136	0.06
591.4679565	0.23
592.2941284	0.04
601.4350586	0.04
603.2887573	0.12
617.2187500	3.15
619.2335815	0.93
621.3153687	0.15
622.2163086	0.10
623.6191406	0.04
626.4843140	0.04
627.5697632	0.31
628.2835693	0.04
635.4798584	0.18
637.1211548	100.00
637.7755127	0.23
641.3902588	0.09
651.1846313	0.08
652.0483398	0.12
657.4206543	0.82
658.1880493	0.03
658.8983154	0.08
661.1668091	0.09
663.3810425	0.06
671.8086548	0.08
677.1712036	0.01
677.8070068	0.57
679.1231079	15.49
679.7509155	0.03
693.1041260	0.09
695.2261963	0.11
704.2149048	0.05
708.6060181	1.98
709.4368896	0.44
719.2318726	7.62
721.1668701	0.64
722.6901245	0.02
729.7782593	0.70
734.5397339	0.14
735.5740967	0.10
737.2476196	0.08
748.1453247	0.03
749.4310913	0.36
750.2698364	0.34
763.1080933	0.38
765.1766968	0.40
766.0554199	0.13
767.1045532	0.09
794.9962158	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	269.14
Annotation	FD 212
Peak:m/z	Relative Intensity
76.9693909	0.04
81.0585556	0.05
83.0615082	0.02
86.0029831	0.03
91.0958710	0.11
92.9990845	0.04
94.9902802	0.22
96.9898529	0.19
98.6488037	0.09
101.0537415	0.16
104.7790222	0.03
106.9604340	0.06
108.9794464	0.37
110.9304352	0.22
113.0668640	0.08
115.1590881	0.02
117.0804901	0.05
118.8915863	0.07
121.1009521	0.29
123.1771698	0.08
128.9534302	0.06
133.2012634	0.11
135.0489655	0.38
137.1663971	0.04
139.0801849	0.18
141.0337982	0.17
143.0564270	0.16
145.1028748	0.10
147.0852966	0.13
150.9617615	0.17
153.0824127	0.08
155.0609589	0.23
157.0699310	0.10
159.1128845	0.04
161.1014099	0.05
163.0883636	0.13
164.9582672	0.04
167.0388184	0.11
167.9985504	0.02
169.1496582	0.27
171.1170197	0.25
173.1206207	0.24
174.1605988	0.02
175.0976257	0.30
177.1113434	1.40
178.0545502	1.55
179.1816254	0.57
181.0410919	7.89
183.1501312	0.08
184.3626251	0.09
185.1414490	0.28
186.1343536	0.09
187.1767426	0.55
189.1031036	0.05
191.0679932	0.56
193.0790253	0.11
194.1280670	0.11
195.0656586	0.26
197.1080322	0.32
199.0733490	6.30
200.0192719	0.05
200.9658966	9.01
202.0157318	0.08
203.0011902	2.78
205.0650482	0.38
207.0542603	0.13
209.0736847	100.00
209.9388885	0.05
211.0115814	0.48
211.9191132	0.23
213.0787201	1.78
215.0575562	0.53
216.0218353	0.08
223.0682831	1.24
224.1610107	0.07
225.2109222	0.53
225.9408264	0.02
227.0504608	15.18
228.2615051	0.02
229.5742340	0.12
233.1876068	1.17
236.0179443	0.03
237.2163696	0.05
239.1218109	0.15
241.0667267	7.63
242.1688385	0.10
247.4883270	0.07
248.6734161	0.21
251.0879669	9.11
252.0750580	0.32
253.1368408	0.20
254.0215454	0.08
255.0116730	0.02
260.0727234	0.28
271.0094604	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	334.1274
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
101.8847961	0.04
146.1094666	0.04
177.0449219	0.09
183.7104797	0.02
203.9924622	0.02
207.4592285	0.02
227.9851990	0.03
231.2026978	0.13
233.0874023	0.44
249.4299011	0.06
250.0495911	0.03
261.3310547	0.09
270.1712036	0.12
274.9008179	0.06
276.1701660	0.05
276.8820801	0.07
283.9838257	0.04
286.8634644	0.02
288.2855225	0.10
292.0738525	0.07
298.9612427	6.04
299.7010498	0.05
303.2109375	0.11
305.2202759	0.03
306.0578308	0.12
309.7376709	0.03
310.5191650	0.08
312.9574890	0.10
313.8638916	0.83
316.8875732	100.00
317.5919800	0.16
318.9252930	0.04
319.6861877	0.03
322.0369873	0.28
322.6387939	0.02
325.1741333	0.05
334.0687866	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0337
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
61.0346298	0.01
82.9019318	0.02
86.8055878	0.01
87.9127350	0.03
88.8626709	0.01
92.9612732	0.01
95.0425415	0.06
96.8890076	0.09
106.8750458	0.05
108.9670410	0.35
110.9834595	0.25
120.9641724	0.01
122.9985046	0.12
124.5002289	0.03
128.9558258	0.12
130.7368011	0.02
135.8277130	0.04
137.0639343	0.25
138.8638153	0.14
143.1475830	0.03
146.8845978	7.54
148.9185791	0.18
151.0114746	2.70
156.8555450	1.70
160.7608795	0.08
162.4978180	0.01
163.2680817	0.05
165.0288086	6.60
173.2383881	0.02
174.8555756	100.00
176.1538239	0.09
178.3778992	0.07
183.2500153	0.01
184.0846405	0.07
187.2746582	0.06
188.8286133	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	277.1062
Annotation	Minumicrolin
Peak:m/z	Relative Intensity
78.7216949	0.02
81.0861664	0.02
84.3953857	0.07
85.0092926	0.33
91.0374908	0.02
115.0764160	0.01
117.1414108	0.02
119.0376282	0.01
121.0675659	0.04
123.8648376	0.07
125.0755463	0.02
127.0619659	0.01
129.1812134	0.02
133.0652466	0.07
135.0582275	0.01
136.9132996	0.01
145.1019897	0.06
146.6543579	0.02
149.0425415	0.25
151.0727081	0.06
153.0998688	0.04
161.1950989	0.04
163.1133423	0.32
164.0351257	0.02
165.0607605	0.20
174.2469635	0.04
174.9689331	0.04
177.0238037	0.08
179.2401733	0.04
180.7045898	0.01
187.1903076	0.04
189.1634979	0.27
191.0592041	0.02
192.1157227	3.25
193.0161133	100.00
194.1528015	0.39
198.2205811	0.03
198.8787231	0.01
203.1143494	0.02
205.0365601	0.93
206.0018311	0.03
207.0786743	0.06
209.0464783	0.50
210.3041077	0.04
217.1348877	0.48
218.2379456	0.01
219.2148743	0.04
221.0424805	0.17
223.1018677	0.16
226.8999329	0.03
231.1113586	0.13
232.3812256	0.01
233.0296326	0.07
235.2306519	0.97
236.1390381	0.08
241.3295593	0.05
245.0049438	0.05
247.4330444	0.12
249.3261108	0.07
252.9904480	0.04
255.0982666	0.03
256.0379028	0.03
259.2328491	0.40
264.6441040	0.10
277.3389893	0.01
287.1121826	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.92169189	0.38
78.93516541	0.31
81.16345978	0.17
85.07928467	0.12
86.49865723	0.16
89.10939026	0.26
93.00767517	0.17
95.25093079	0.62
98.98114014	0.63
103.0397949	1.33
104.2993317	0.18
105.0062714	0.45
106.0420532	0.15
106.7735596	0.86
108.9893951	1.46
110.7479553	1.67
112.9902344	0.57
114.8744965	0.10
119.2287903	0.21
121.1059113	0.18
123.2284851	0.12
124.1204834	0.37
124.9931183	1.41
126.9285278	6.16
128.9533234	5.84
129.9810638	0.10
131.042572	0.28
135.0214386	2.16
136.9931335	1.17
139.1486511	1.68
141.0417023	0.81
145.1043854	0.49
147.0553436	2.31
151.0254974	54.93
152.0366058	3.72
154.0251617	1.22
154.8607941	1.85
165.0546722	0.51
165.9608917	0.38
167.0748291	3.18
168.0738373	0.62
169.133194	2.01
170.0382233	0.27
171.0973969	0.27
175.0535126	1.11
177.0442963	0.17
179.2028046	1.64
181.4204254	0.86
182.0701141	0.54
183.0948029	1.92
185.0737457	2.31
186.0976257	0.71
189.2884064	0.35
191.0633698	0.55
193.0109711	0.67
194.3780975	0.22
195.1040955	0.76
197.0357208	3.77
198.1834259	0.36
204.467804	0.15
207.0263977	1.85
208.2216644	0.23
209.3144379	0.44
210.1729584	1.08
211.1119843	4.24
212.086853	0.50
217.1573334	3.46
225.2214203	9.93
226.1381378	1.43
235.0254059	20.31
236.2771149	0.23
238.039444	7.87
238.9995117	1.02
253.0925446	100.00
254.2162323	16.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.2184
Annotation	Unknow
Peak:m/z	Relative Intensity
142.8572693	3.20
151.0634308	1.11
160.8968201	0.30
181.2079773	0.38
211.0753326	0.21
225.1578064	0.54
271.1148682	49.00
295.2974243	0.29
311.1486206	0.56
313.2324219	87.73
329.2692261	0.68
331.2301025	50.60
341.4057617	0.27
373.0556030	100.00
373.7584229	0.12
376.9705200	0.77
412.9761353	13.27
413.7527771	1.18
415.4682312	1.53
431.2809753	16.35
432.9997559	1.81
457.1544800	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	604.2154
Annotation	Fesumtuorin D
Peak:m/z	Relative Intensity
170.9543152	0.69
173.0915680	0.83
174.3028717	0.04
175.0992584	1.15
177.1909332	0.07
180.8459167	0.23
184.0696411	0.26
185.6117249	0.10
187.0907898	0.15
191.1522522	0.55
195.0768280	0.41
198.0897675	0.10
199.0487518	7.89
200.9873505	3.16
203.0888672	73.32
211.9019470	0.16
213.2257385	0.50
215.0769348	0.30
223.0984344	1.39
227.0699768	7.73
239.1449585	0.05
241.0068970	6.32
242.2153320	0.07
243.1148376	0.48
251.1351013	0.80
252.1975708	0.10
257.0802612	0.17
269.0983887	64.47
270.4676514	0.19
285.5877075	0.09
287.0030823	100.00
288.5451965	0.15
305.0797119	0.24
315.1474609	0.25
317.3787842	0.14
335.1596069	0.18
341.6171265	0.05
352.9655762	0.12
355.5003052	0.17
384.9573364	0.11
401.2199707	0.05
406.0709229	0.07
424.1745605	0.05
434.8072510	0.12
437.9432983	0.40
458.6565552	0.09
459.5997925	0.15
462.1690063	0.54
468.0101929	0.08
470.4600220	0.05
471.4365234	0.17
472.3754883	0.03
483.4292603	0.10
528.7894287	0.13
540.9478149	0.05
554.7074585	1.71
560.9135132	0.07
568.2686157	0.06
572.0066528	0.27
572.7394409	7.89
583.8499146	0.08
584.8248291	0.21
585.7840576	0.30
586.6497192	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.253
Annotation	threo-Carolignan E
Peak:m/z	Relative Intensity
259.3920898	0.38
289.2155762	0.33
293.7052307	0.16
297.1844177	0.19
307.3363953	0.07
312.9326782	0.11
314.1295166	0.06
321.0631104	0.53
325.2454834	0.52
329.1207886	1.13
333.3171387	0.63
337.5342407	0.09
344.0992432	0.35
345.2248535	0.48
346.0233154	0.21
349.3770752	0.05
351.3001099	0.31
357.9219666	0.14
361.6047363	0.19
369.2751465	0.09
371.1853638	0.22
381.5200195	0.27
383.1928711	0.12
387.3274536	0.34
389.2155151	0.29
391.2672729	0.44
399.3073120	0.85
405.4206543	0.04
409.2966309	0.07
419.1729736	0.15
421.0696411	0.22
425.3483276	0.95
427.2745361	1.49
433.4214478	0.20
437.0037231	0.10
451.2061157	1.03
453.4603882	0.69
457.1961670	0.14
467.3970337	0.22
471.2442017	73.49
471.8557129	0.44
481.1495361	1.63
485.3728027	35.98
489.4666138	0.50
495.2053833	70.16
497.2979736	1.21
501.5377197	0.08
507.4417114	0.08
511.4746704	0.11
513.1815796	100.00
515.2758179	0.17
525.2800293	17.53
531.1603394	0.66
533.5473022	0.13
537.1187744	0.63
537.7260132	0.12
542.6101685	1.60
543.2802734	12.33
553.0652466	0.12
555.2863159	0.84
560.8760376	0.50
567.1187134	0.18
572.0304565	0.29
573.0411987	4.12
585.1604614	0.10
597.0707397	0.48
603.2399902	0.82
609.4591675	0.09
633.2671509	1.90
635.4826050	0.15
639.4082031	0.25
643.2352905	0.16
651.6057739	0.66
663.1271362	0.11
669.3597412	7.30
681.1367798	0.60
698.6036377	0.16
699.3577271	0.50
711.3605347	0.42
714.6044312	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	494.1671
Annotation	Aspoxicillin
Peak:m/z	Relative Intensity
148.9364624	1.16
151.1207581	0.65
161.0895233	0.29
167.0379944	10.41
181.0395508	2.85
181.6764374	0.36
193.1805115	0.50
194.8755188	0.17
210.9782562	100.00
247.9934387	0.51
277.0647278	0.60
281.1671143	0.32
284.0986328	2.23
291.3242188	0.49
314.4096069	0.78
331.7947388	22.67
361.8243408	0.34
370.9148254	0.25
373.1084595	0.56
433.3269958	1.22
434.9645691	1.59
435.6210022	0.23
453.1604919	0.45
457.9062195	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.1564
Annotation	Tricin 7-rhamnosyl-(1->2)-galacturonide
Peak:m/z	Relative Intensity
198.2872314	0.04
201.0878296	1.92
211.1365356	0.05
224.8841095	0.03
245.6374664	0.02
258.0769348	0.03
260.2804565	0.12
273.1663818	0.04
285.1590271	0.07
286.9253235	0.02
295.1359253	0.06
300.4365845	0.08
301.1561279	0.35
302.0543213	0.28
305.2394409	1.03
310.2264404	0.03
311.2676392	0.08
313.3778076	0.03
315.2257080	0.57
316.0773926	0.08
317.1116638	0.18
319.4039307	0.03
328.9768677	0.04
330.1327515	3.58
331.2295532	0.50
343.2182007	0.12
345.1900024	36.54
347.2158813	0.02
348.1477661	0.15
349.3518066	0.07
351.0939331	0.02
361.4415283	0.03
362.8424072	0.18
381.2176514	0.04
382.3578491	0.11
385.2716064	0.04
386.3341675	0.03
387.0117188	0.05
405.2847900	0.02
409.0403442	0.03
413.4464111	0.11
444.2501221	0.23
445.3854370	0.02
446.4661255	0.13
449.2661133	0.21
451.2040405	0.05
455.1677246	0.03
456.8735962	0.08
463.2306519	0.03
468.2726440	0.05
471.5895386	0.09
474.4169922	0.07
475.3234863	0.11
488.3311157	0.36
489.1450806	0.46
493.1924438	1.63
502.4343262	0.14
507.1505737	100.00
507.8015747	0.39
535.2589111	1.80
549.1456909	46.07
549.7601318	0.17
551.1824341	0.04
563.5304565	0.06
564.2733154	0.04
565.3472900	0.30
575.4375000	0.14
577.5342407	0.02
589.1741333	26.00
591.2299805	1.09
597.4413452	0.03
601.1604614	0.16
605.3006592	0.12
606.5781250	0.13
607.4869995	0.38
615.2317505	0.04
619.2523804	0.09
621.3826904	0.03
623.1747437	0.04
632.1037598	0.03
632.8025513	0.10
633.4118042	0.45
655.1569824	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.1929
Annotation	Butrin
Peak:m/z	Relative Intensity
178.9452209	0.82
184.8548737	0.10
190.9933624	4.01
194.9305725	2.24
203.1708221	0.26
203.9581604	0.07
215.2026520	0.25
219.0560608	0.80
225.2760162	0.23
226.9691925	0.51
233.3085632	0.12
237.3690643	0.60
251.1426392	0.98
262.8610840	0.09
267.0768433	0.11
268.9448853	0.77
270.0150146	0.50
275.0146790	0.78
276.8560486	0.19
287.0891418	29.89
289.1609497	0.17
291.2289429	0.08
301.0552368	0.74
303.1466064	0.90
313.1498413	0.32
314.5220947	0.69
315.2964478	0.31
317.1553955	0.09
318.0032349	1.07
318.8858032	0.40
319.4912720	0.08
321.5375977	0.22
330.9891968	0.23
337.4526367	0.15
338.5167847	0.33
339.1273804	4.84
345.1101685	0.33
354.8645020	0.45
357.0705566	14.15
357.6721802	0.74
359.3681030	0.77
360.2357178	0.19
361.2195435	0.09
375.2543945	1.05
380.8466187	0.51
390.0569458	0.12
399.0068970	1.43
417.2644043	0.38
421.6339111	0.15
423.2260132	0.13
427.3064575	0.21
429.2836914	2.75
433.3084106	0.72
434.2570190	1.15
434.9819946	0.19
441.1769409	0.15
446.8414917	0.60
447.5895386	0.46
453.2716064	0.38
458.9146729	0.21
463.2517090	0.09
465.0834351	100.00
466.1810913	0.28
471.0532227	0.20
481.6242676	0.71
483.4763184	0.88
494.2094727	0.12
501.0082397	0.46
502.9981689	0.28
504.4948120	1.37
506.2467651	2.13
507.3685913	2.49
508.1424561	0.29
512.6757202	0.28
534.1292725	0.25
536.1096191	0.91
537.3726807	0.32
541.1796265	0.41
543.3811646	0.17
564.2887573	0.44
581.3828735	0.25
582.0633545	0.06
591.3434448	0.08
597.3287964	0.45
598.3805542	0.39
599.5443115	0.90
607.8523560	0.86
609.1119995	6.38
609.7528687	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.185
Annotation	Arginyl-Phenylalanine
Peak:m/z	Relative Intensity
90.9591751	0.14
93.2571106	0.11
102.6311340	0.17
104.9980011	1.86
106.9748840	25.13
108.0587311	0.18
116.0130844	0.20
119.9138031	0.27
122.1505890	0.47
122.8700790	0.19
125.0124817	100.00
125.7210159	0.13
129.1019440	0.08
143.0859985	1.07
147.1319275	0.21
150.9473267	0.26
153.2336121	0.22
160.2190399	0.08
168.0587769	0.09
170.1185608	0.15
177.0639038	0.07
179.8366089	0.08
185.1023865	0.05
186.6904449	0.07
191.0169830	0.98
197.1145020	0.15
199.0987091	0.10
203.0548401	0.16
204.1451721	0.04
204.8945923	0.20
208.0823975	0.32
209.0290222	0.14
217.3418579	0.08
218.0594482	0.06
220.1090393	0.15
223.1568298	0.06
233.1113892	0.09
237.2319336	0.19
240.0954285	0.23
241.1002808	0.25
245.5870667	0.29
247.2121887	0.27
251.1541443	0.08
255.0531006	0.07
262.1611328	0.20
264.2865295	0.29
266.2359924	0.85
276.6996765	0.30
278.0057678	0.61
279.8393555	0.26
281.1220703	0.68
284.2325134	0.20
286.2926636	0.64
287.0771790	4.08
288.2037964	0.09
288.8175964	0.17
290.5223999	0.11
291.3320312	0.44
294.1853027	0.35
294.9619751	0.31
302.6845703	0.22
304.2105103	12.42
304.9423218	27.00
307.0986023	0.93
308.0477295	0.52
313.6799316	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	526.76
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8615570	0.20
206.8136292	0.78
267.1743774	0.23
274.6929932	2.16
290.7183838	11.13
306.8653564	0.22
336.3259888	0.19
353.1694336	1.06
358.7784424	6.46
365.0772095	1.82
371.2250977	2.08
374.6408081	4.98
390.9561157	0.66
406.3008423	0.89
414.7837524	0.15
420.9790649	0.09
441.0393677	0.26
442.5993042	100.00
443.3512573	0.34
457.7676392	0.49
458.9011841	2.09
462.7600098	0.21
467.1918945	1.42
471.0869141	0.30
480.1806030	0.10
484.7652588	0.72
509.1036377	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	559.23
Annotation	punaglandin 2
Peak:m/z	Relative Intensity
159.9967346	14.30
166.3095551	0.06
167.0290985	1.24
172.1832275	0.84
172.9601440	0.84
173.9168091	0.27
174.9977417	13.24
175.9636841	0.17
181.0540771	0.59
182.2515259	0.06
184.0692139	0.17
186.1877441	1.43
189.1249084	1.13
190.0845337	1.72
191.0566101	31.15
196.1094360	0.29
199.2338257	0.17
200.1291199	0.08
201.1323700	0.51
202.0656281	0.31
203.1073303	0.83
204.9810791	0.34
207.0903473	100.00
209.1731415	0.26
210.0078735	0.24
212.2888184	0.88
214.0492554	1.73
215.3827820	0.57
216.2458496	0.14
217.0442047	0.11
220.0889282	0.35
221.0953522	0.44
225.1266632	1.40
226.2341766	1.19
228.5304565	0.60
229.9565735	0.36
230.8605042	0.48
232.2873230	0.14
233.3189240	0.46
235.2514496	0.21
238.0288544	2.75
240.0730591	0.37
243.7848053	0.06
250.0544739	0.13
251.0809021	0.24
251.9686584	0.25
254.2010193	0.25
256.0974731	1.92
257.0136108	0.91
260.2299500	0.48
267.0595398	0.48
270.2498779	0.06
274.2131348	0.79
280.5256348	0.16
281.2971802	2.31
283.1757812	0.09
286.1969604	0.21
288.1003723	0.35
291.2048340	0.15
292.2222290	0.31
293.9953003	0.20
296.3390503	0.14
299.3013916	0.33
304.2207031	0.19
306.2609253	0.11
309.1887207	0.11
310.2313843	1.75
315.0848389	0.18
317.2794800	0.79
319.2174072	0.18
320.3692627	0.18
322.1871338	3.21
324.2020264	10.07
325.1813354	0.40
326.2546997	0.35
333.0952148	0.21
334.1707764	0.08
335.1164551	1.05
335.9260254	0.10
339.2451782	0.13
341.2131348	0.11
344.0520020	0.11
346.2521973	0.06
348.1820679	2.13
349.1660156	0.11
350.1918335	0.23
351.2344971	11.99
353.2329712	26.03
354.0567627	0.06
356.0559082	0.58
359.3355713	0.08
362.0878906	0.99
364.1699829	2.02
366.1692505	57.66
367.1808472	1.04
369.1166992	14.89
373.0485840	0.42
374.1069946	1.88
375.6008911	0.12
377.3186035	0.28
379.3795776	0.25
380.0356445	0.43
381.9140015	0.08
384.0853882	0.42
390.2871704	3.01
392.2593384	0.30
397.2342529	11.40
398.2217407	0.08
400.3776855	0.06
402.1593018	0.26
404.7847290	0.40
405.5547485	0.31
406.3588257	0.27
408.2053223	5.05
409.0858765	0.09
412.2277222	0.50
414.2396851	0.33
416.7844849	0.32
418.3028564	0.09
420.3289185	0.53
421.0275269	0.17
425.1436157	0.10
430.1453247	0.90
432.3827515	1.22
434.2592773	0.10
437.8195190	0.86
444.2312012	0.26
446.4451904	0.14
450.1774902	0.63
456.1343384	1.78
458.1425781	0.36
462.0952759	1.12
463.3041382	0.05
465.7200928	0.24
473.2370605	0.36
474.2254028	2.28
476.2295532	0.16
480.2402954	4.32
481.2127686	0.36
483.8026733	0.28
486.2114868	1.31
487.4937744	0.25
492.2576294	4.70
494.3113403	0.09
498.1304321	5.67
499.0770874	0.20
501.3131714	0.08
505.3072510	0.24
508.5767212	0.36
509.2276001	0.12
510.2081299	10.16
511.3229370	0.21
512.3329468	0.06
515.1946411	0.46
516.1544800	6.41
516.7593384	0.14
523.0687866	2.41
527.6607056	1.37
528.2723999	9.29
530.1709595	1.05
531.4459229	0.59
541.2402954	5.84
542.1725464	0.87
544.5084229	0.38
550.1713257	1.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	647.3034
Annotation	Unknow
Peak:m/z	Relative Intensity
184.9146118	0.03
193.2292328	0.10
197.0905457	0.10
211.3369598	0.08
213.1334229	0.12
215.3690796	0.10
220.9877319	0.05
223.3850098	0.32
227.2862701	0.23
231.1190491	0.16
237.2400970	0.12
245.0380249	0.09
247.4728088	0.14
249.2953796	0.18
253.2497864	0.08
255.1299133	0.26
256.9866943	0.15
259.2872925	0.05
260.3869324	0.06
262.9833374	0.19
267.4313660	0.04
271.1591797	0.16
273.6867676	0.17
277.2062988	0.04
279.1340027	0.20
281.2473755	0.26
286.2882080	0.02
291.7663574	0.10
293.1535034	0.73
299.4111328	0.18
301.0598145	0.19
303.2622070	0.26
305.2220764	0.81
307.2965698	0.38
309.3530273	0.42
311.0972900	1.11
317.0066833	0.15
318.3047791	0.14
319.0705566	0.19
321.1104736	0.89
323.2761841	0.94
325.2651367	0.35
329.2568970	0.26
331.1722107	0.04
335.0534058	0.31
337.4112549	0.59
339.0799561	1.66
343.3021851	0.22
347.3344727	2.09
349.0610352	0.09
351.2895508	0.56
353.6211548	0.25
355.3149414	0.17
357.4661865	0.11
361.1729126	0.75
363.1996460	0.36
365.3366089	0.90
367.2466431	0.08
371.0974121	0.61
379.5378418	0.03
381.2421875	0.20
383.2067261	17.96
385.2022095	0.02
389.1492920	2.87
392.6817627	0.05
395.4578247	0.24
407.2517090	7.12
408.5991211	0.09
409.4605713	0.19
412.9998169	0.14
419.9214478	0.05
424.5056152	2.29
425.1378784	18.37
425.8574219	0.20
427.2835693	1.98
443.2249756	14.38
443.8480835	0.06
447.1310425	0.11
447.7323608	0.06
449.4239502	0.03
466.9428101	0.21
469.2813721	2.70
470.2851562	0.06
474.9462891	0.03
485.3123779	100.00
491.0143433	0.14
513.0112915	0.10
518.2676392	0.09
521.4761353	0.04
527.4071045	0.46
533.3456421	0.34
539.3174438	0.10
545.3157349	1.11
547.5398560	0.19
551.1853638	0.15
557.2645874	0.03
565.2742310	0.03
585.0136719	0.09
586.4373169	0.19
587.1898804	0.19
588.7764893	0.13
601.2877808	0.18
603.3325806	0.73
604.9347534	1.71
611.6445923	0.11
612.3445435	0.09
615.3566284	0.08
628.7654419	0.64
629.3660278	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.3228
Annotation	Convalloside
Peak:m/z	Relative Intensity
231.2148743	0.02
253.0422974	0.11
289.1419373	0.04
303.3009338	0.06
308.0548706	0.18
319.3585815	0.11
322.9328003	0.04
324.9758911	0.02
329.1112976	0.10
333.1715088	0.04
337.0914917	0.30
337.7373657	0.13
342.4262085	0.05
343.0594177	0.34
355.2475891	0.09
359.2528076	0.15
361.3071899	0.05
362.2540894	0.07
363.1284180	0.09
369.1735840	0.08
373.0173950	0.26
383.3421021	0.05
387.5254517	0.16
389.3272095	0.05
399.5365601	0.02
401.1468506	0.08
407.5823364	0.05
415.1343994	0.14
419.4945068	0.09
423.4587402	0.24
425.3552856	11.81
428.3072510	0.06
442.1288452	0.03
443.1067505	0.55
455.4335938	0.03
457.2677612	0.04
461.3901367	0.12
475.2795410	0.04
479.5920410	0.15
483.1958008	0.06
485.1267700	0.21
497.3613892	0.23
502.5357056	0.15
503.3270264	0.11
505.6300049	0.07
506.5506592	0.15
507.6253052	0.08
509.2782593	0.43
515.1755981	0.22
526.3893433	0.13
527.1380005	0.04
534.1728516	0.06
535.4426270	0.03
543.1491089	0.04
545.4137573	6.51
549.1416626	0.16
551.6008301	0.18
553.0720825	0.10
555.3480225	0.05
563.3899536	1.12
565.3074341	0.17
565.9931030	0.10
567.4022827	0.17
569.2043457	0.43
575.5822754	0.08
577.3892822	0.04
581.5017700	0.16
587.3345947	100.00
588.0168457	0.15
588.8149414	0.05
595.0954590	0.18
605.3362427	44.29
606.0291138	0.11
607.3244019	1.63
608.2937012	0.39
609.4199829	0.09
623.2312012	21.86
625.2889404	0.18
626.1583862	0.05
633.3330688	0.06
647.1987915	3.83
649.2725220	0.04
651.2163696	1.84
651.8171387	0.04
665.3051758	20.73
666.2374268	0.32
667.2988892	0.31
669.3981323	0.08
681.2280273	0.11
683.4671021	0.10
688.9780884	0.07
692.6785889	0.28
693.3789673	0.76
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	407.03
Annotation	Unknow
Peak:m/z	Relative Intensity
138.9745941	0.02
144.6581726	0.07
146.8978882	0.06
149.1679993	0.06
169.0231171	0.04
184.8769531	0.11
186.1379852	0.05
195.0942993	0.58
197.1113129	0.08
211.0621948	0.05
213.0915222	0.06
214.9683685	3.85
220.9788208	0.15
231.0578003	0.04
237.1213074	0.02
238.8573608	2.58
241.0552673	0.05
245.3175049	0.02
255.2151794	0.05
260.1225586	0.04
265.0452576	0.29
273.0599365	0.74
275.0909119	0.02
282.8759766	1.14
283.5778809	0.04
289.1930542	0.03
291.4102173	0.04
300.9728088	13.57
301.6109009	0.14
303.1137085	0.44
309.0946350	0.27
310.9188843	0.55
317.0653076	0.09
326.9307556	1.36
341.0925903	0.07
345.0212402	4.34
352.3352661	0.04
361.3891296	0.08
362.5889893	0.06
363.3305969	0.02
365.9493103	0.03
371.0737915	23.09
372.3036194	0.05
374.9413452	0.11
385.9366760	0.12
388.9758606	100.00
389.5912476	0.25
403.2635803	0.05
406.3303528	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.1874
Annotation	Unknow
Peak:m/z	Relative Intensity
243.0915985	0.05
252.8419647	0.04
255.0854340	0.02
265.2666626	0.02
271.2499390	0.10
287.0197144	0.04
300.1303711	0.56
301.2698364	0.02
302.1606445	0.04
307.2966003	0.07
315.1291504	6.64
317.4044495	0.06
332.5435181	0.05
341.2026672	0.04
346.2900696	0.03
359.2319336	0.18
360.0773315	0.06
367.1492920	0.02
373.0399170	0.10
374.1533813	0.15
375.2157593	0.20
385.5128784	0.19
413.0245361	0.02
415.4834595	0.01
426.1119385	0.02
429.6176147	0.15
449.3896484	0.05
455.3497925	0.01
459.3250732	0.23
473.3120728	0.05
477.2008667	36.24
505.0485229	0.35
505.6806030	0.01
509.1712646	0.12
515.0062256	0.03
519.1676636	21.05
519.8590088	0.10
523.2974854	0.14
537.3030396	0.15
545.4766235	0.02
557.2745361	0.05
559.2598267	10.86
561.3132935	3.52
564.1971436	0.05
575.1917725	0.06
578.0447388	0.11
579.2175903	0.17
601.1416626	2.46
603.1401978	0.24
621.1253052	100.00
621.8392334	0.09
622.5961304	0.03
640.9367065	0.12
645.3533325	0.05
663.0903320	12.56
675.3059082	0.03
682.9125977	0.13
684.4677124	0.02
685.4406128	0.03
692.2949829	0.04
693.3587646	0.06
697.3276978	0.02
702.4347534	0.17
703.1674194	1.57
704.5286255	0.15
705.2781372	0.19
711.1235962	0.23
716.4533081	0.04
719.3855591	0.23
720.2687988	0.02
721.6030273	0.06
723.1977539	0.09
733.0523071	0.06
742.7867432	0.05
746.2874146	0.10
747.1979370	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1667
Annotation	Butrin
Peak:m/z	Relative Intensity
168.9242249	0.10
183.0050964	0.06
186.0508118	0.18
187.0152588	0.10
203.2610931	0.03
225.0226288	0.06
241.1196442	0.05
242.1050720	0.10
269.1488342	0.53
272.0756226	0.10
285.1424561	0.69
287.1379395	100.00
311.1546326	0.03
323.0881348	0.07
329.2139282	0.26
337.2205811	0.07
353.0567627	0.10
367.4447632	0.17
388.8189697	0.25
434.4446411	0.03
443.1145630	0.03
444.8348389	0.12
453.7913208	0.18
459.1781616	1.37
465.1119385	0.09
469.5538330	0.05
478.6463013	0.12
481.0686646	0.13
482.1135254	0.07
489.8639526	0.03
494.4276123	0.09
496.9801636	0.04
504.6527710	0.05
507.2730103	0.06
507.9630737	0.06
508.8914185	0.06
514.6787109	0.15
515.3629761	0.44
517.9552612	0.06
519.8317261	0.18
521.0883179	0.27
521.8056641	0.22
523.2905884	0.21
524.0962524	0.18
527.7153320	0.17
531.1718750	0.19
533.0718384	0.07
534.0169067	0.06
549.2937622	0.66
550.8329468	0.65
551.6083984	0.10
554.8507690	0.07
558.5270386	0.11
562.8554688	0.14
563.6830444	0.19
566.1144409	0.08
571.6578369	0.34
572.7114868	0.13
573.6282349	0.26
577.0824585	0.28
578.0281372	0.02
580.5722656	0.15
586.1824341	0.63
604.0895996	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	545.2216
Annotation	Kunzeaphlogin D
Peak:m/z	Relative Intensity
153.1321411	0.06
155.0315399	0.50
156.8982391	0.42
161.0630188	0.28
163.1951904	0.37
165.0562134	0.13
169.0557861	0.46
170.9547729	0.42
172.8876953	0.45
175.0368958	1.54
177.0551605	1.06
179.2327728	0.36
181.3964081	0.26
182.9746399	0.71
185.2370148	0.80
186.0938416	0.06
187.0987091	1.35
191.2964783	0.53
193.2587891	0.56
195.0086060	0.79
197.1671600	1.30
199.2262878	0.14
201.2528992	0.11
202.8455048	0.89
205.1709290	0.42
207.0464172	2.13
208.8386841	0.22
210.1041718	0.22
212.9317017	0.76
215.2421265	0.45
216.1892700	0.33
217.0236664	0.21
219.2218628	2.11
221.0943298	1.30
222.8464813	0.33
225.1428528	4.98
226.8304596	0.17
228.9182281	0.19
231.0883331	1.25
233.1393738	0.17
234.6367035	0.07
235.2945251	0.23
239.0656128	0.14
243.0388489	7.02
245.2050781	0.08
247.0375061	1.10
254.2657013	0.15
255.0797729	0.22
256.2344971	0.30
257.0903320	0.10
261.2239990	4.43
263.1072998	0.56
265.2800903	0.88
266.1594849	0.39
266.8722534	0.06
269.2595215	0.15
270.1812744	0.19
271.1348267	0.60
272.0346069	0.07
273.4100342	0.63
276.4060669	0.10
278.2831421	0.18
282.8290405	0.62
283.6343384	0.20
285.5230103	0.14
287.3953247	0.12
289.0708618	0.58
290.9988098	1.96
293.3117676	0.64
297.1243286	0.71
300.6450195	0.69
301.2476807	0.69
303.2648315	0.16
305.7572937	0.09
307.2922363	0.09
310.3107300	0.57
311.1507568	1.11
313.2121582	0.22
314.7220459	0.14
319.0026855	5.31
320.3449707	0.61
321.3267822	0.72
325.3986206	0.08
327.1058960	0.09
329.1630859	1.22
330.2765503	0.30
332.9857178	2.97
335.3928223	0.57
336.2022705	0.10
338.4536133	0.77
339.3666382	1.32
344.5496216	0.45
345.2705078	0.55
347.1635742	4.18
349.0297852	0.12
351.2022705	0.25
355.2739868	0.23
356.9453735	1.06
359.0944824	0.06
361.1131592	0.73
362.7731323	0.08
363.3978882	0.40
365.1499634	5.10
369.4081421	0.16
371.1243286	0.21
373.0259399	1.79
373.9105225	0.45
375.0980225	7.23
376.1123047	0.57
377.0493774	0.21
379.4160156	0.35
380.8651733	0.58
383.1597290	7.38
384.3864136	0.47
387.0869751	0.05
390.9738770	1.12
392.9655762	3.74
394.1583862	0.74
395.2349854	0.29
399.1212158	0.34
401.2241821	13.67
402.5667114	0.17
403.3091431	0.50
405.3078003	0.31
406.3513794	1.68
409.2199097	0.39
410.4441528	0.41
411.2625122	0.65
414.8027344	0.56
416.1377563	0.24
420.8825684	0.27
423.4321899	0.26
424.9500122	1.71
426.9799194	2.14
432.7559814	1.17
439.2450562	0.31
441.0861206	1.07
443.1246338	16.60
443.8468018	0.10
445.1964111	0.08
449.1246338	0.08
451.0318604	0.58
453.2218018	0.43
456.5163574	0.48
457.2258301	0.52
458.7322388	0.81
459.3734131	0.09
460.9176025	0.45
463.2857666	0.13
467.2094116	0.49
470.4243774	0.29
473.0627441	0.70
481.3200684	0.22
483.1117554	0.74
483.7483521	0.45
485.2205200	0.52
486.2883301	0.23
491.1702271	0.79
498.3793945	0.67
499.0900269	1.88
500.3060913	2.00
501.3747559	1.32
504.2352295	0.08
506.8875122	0.51
509.2418213	6.44
512.7739868	0.09
515.1403198	0.66
524.9708862	2.21
527.1776123	100.00
527.8466187	0.53
528.7120972	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1516
Annotation	Aesculin
Peak:m/z	Relative Intensity
332.6869507	0.02
352.2485352	0.02
353.3182983	0.02
455.2037354	0.01
466.7819214	0.02
473.2666626	1.07
503.1616821	0.16
512.6375732	0.02
514.9741821	0.12
515.6006470	0.02
534.2773438	0.03
535.0468140	0.01
540.1349487	0.01
545.0757446	0.02
557.2835083	0.01
575.2019043	0.03
588.2343140	0.03
593.3324585	3.65
594.6422729	0.01
599.3880615	0.03
617.0020142	0.07
635.1773682	100.00
635.8424072	0.16
660.3362427	0.01
661.1546631	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.2346
Annotation	Cnidioside B
Peak:m/z	Relative Intensity
239.2592468	0.09
244.7119141	0.06
269.1489563	1.77
270.0439453	0.06
272.0827332	0.06
275.3021851	0.05
286.9948730	0.11
297.0797119	0.76
311.0980530	0.94
315.3767090	0.34
329.4081726	0.30
330.0754700	1.57
345.0792847	3.42
357.1151123	100.00
357.9287109	0.63
369.0843506	0.25
371.1163940	0.06
381.2520752	0.22
387.3781128	0.49
391.3416138	0.14
421.3234863	0.08
427.1098633	0.09
437.0989990	35.28
437.7529297	0.03
445.3493042	0.04
447.1795044	0.08
467.0778198	0.06
473.3307495	0.06
479.2324829	0.12
487.1173096	0.08
488.1643066	0.39
489.2036743	0.43
496.9960938	0.47
507.1602173	4.88
513.0960693	0.08
523.2837524	0.20
525.2131348	0.12
529.9249268	0.26
543.1613159	0.18
547.2274780	0.24
549.3295288	4.48
561.1211548	0.47
570.2924194	0.07
571.4711304	0.25
589.2941284	0.03
591.1283569	1.00
599.2651978	0.34
603.3452759	0.25
613.2661133	0.35
619.2360229	0.09
623.4468384	0.06
630.1441650	0.14
631.1487427	0.24
632.0590820	0.69
633.1398926	1.49
649.3824463	0.69
650.3601685	1.27
651.3384399	1.16
661.2543945	0.18
672.1017456	0.05
673.3285522	0.14
674.2514648	0.09
675.7700195	0.28
689.1751099	0.31
692.2102051	0.64
693.1790161	0.35
695.0813599	0.11
704.2671509	0.08
708.0270996	0.20
709.4426270	0.41
711.1694946	3.79
722.9452515	0.27
733.6100464	0.22
735.2976685	0.39
744.3799438	0.07
748.5996704	0.09
751.2014771	0.58
752.8587646	0.38
757.2418213	0.60
776.9864502	0.24
777.6852417	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	578.2428
Annotation	Unknow
Peak:m/z	Relative Intensity
169.0516663	0.37
171.1815033	0.14
177.1792297	0.06
178.1122589	0.11
187.1841278	0.07
188.2482605	0.54
189.2111053	0.10
210.2005920	0.08
211.9617462	0.10
213.0411987	1.68
216.7560883	0.07
225.1519012	0.15
227.1202087	0.19
228.9117279	0.81
230.3570557	0.38
231.0237579	1.01
235.0833130	0.24
248.9366455	0.43
253.0420074	0.22
254.2322083	0.06
272.6839600	0.38
284.1092529	0.28
289.0591431	0.15
289.8664246	0.07
291.0108032	2.56
295.1353149	0.06
297.8919678	0.08
299.2183228	0.13
304.0411377	0.04
312.7285767	0.14
322.9653931	0.24
330.1367188	0.25
331.2225952	0.20
332.9794922	0.09
338.8920288	0.87
348.3922729	0.05
350.2177734	0.13
351.8904419	0.17
356.6453247	1.37
357.2738037	1.63
361.1600342	0.11
362.5225830	0.13
363.2813721	0.17
366.8838501	0.15
368.4141846	0.02
369.1740723	0.10
372.8439941	0.10
375.0866089	51.01
376.0485229	0.02
378.0254517	0.20
378.9743652	0.03
380.6633301	0.28
382.7368164	0.23
385.2958374	0.05
389.4710693	0.07
393.0237427	97.44
395.3309326	0.08
396.9694824	0.06
398.7554321	0.91
401.3002930	0.05
402.7578125	0.10
405.3029175	0.72
405.9196167	0.24
410.8513184	6.44
415.5303345	0.39
416.9654541	5.22
421.1104736	0.05
423.5310669	0.23
424.2839966	0.09
427.9025269	0.05
429.1031494	0.43
431.4835815	0.03
433.7167358	0.18
438.3246460	0.04
446.2583618	0.25
447.2615967	0.03
460.1505127	0.12
465.1561890	0.24
466.4494629	0.11
476.1255493	0.14
484.0521851	0.02
487.0797729	0.07
491.3707275	0.09
492.7074585	0.49
494.2487793	0.07
496.2224731	0.32
497.2593384	0.08
499.3725586	0.06
500.3587036	0.13
501.5225220	0.05
502.8092651	0.24
504.1034546	0.02
506.4026489	0.29
507.8773804	0.13
516.2438354	0.11
517.1739502	0.15
518.2369385	0.08
521.1774902	0.24
524.4603271	0.27
525.1502075	0.22
529.1613159	0.07
531.9780884	0.07
534.3711548	0.07
535.3755493	0.06
539.3526611	0.11
542.2395630	1.76
542.9180298	16.50
545.3960571	0.47
546.8471680	0.24
548.2864380	0.09
555.5878906	0.36
558.2211304	0.06
559.5866089	2.14
560.8893433	100.00
561.5988770	0.34
563.2394409	0.09
568.3938599	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0561
Annotation	2-O-(Z-p-Hydroxycinnamoyl)-(x)-glyceric acid
Peak:m/z	Relative Intensity
70.8910141	0.38
72.9476624	1.31
74.9358978	3.04
76.6353149	0.84
85.0096130	28.96
91.0446167	0.63
98.8869171	0.57
100.5782318	0.26
104.8694763	0.76
120.9815826	29.83
128.9280853	8.35
133.0672302	0.28
135.0430145	100.00
149.0441132	0.68
150.9064178	6.88
159.3505707	0.12
160.9548645	0.73
162.9209442	0.63
175.2020264	0.42
176.8007965	0.48
178.9685364	10.39
181.0832214	0.25
187.1269836	0.40
188.9872437	52.22
205.0883331	8.51
223.0012970	0.25
231.3788452	0.17
232.9459686	4.06
251.0050049	1.47
252.3206024	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	639.1879
Annotation	6-Hydroxyluteolin 6,4'-dimethyl ether 7-rutinoside
Peak:m/z	Relative Intensity
179.0992126	0.06
198.2389832	0.12
207.2004547	0.18
209.0050201	0.18
214.0619202	0.13
222.9516449	0.05
225.0171204	0.35
228.9467621	0.17
263.2874146	0.19
265.0122681	0.20
265.9764099	0.12
270.9138794	0.06
273.2359619	0.09
277.1856689	0.18
289.1094971	0.09
291.3201904	0.06
292.1342468	0.07
297.1253662	0.14
300.2721558	0.15
301.0398560	0.02
303.1213379	0.12
315.1899719	0.13
315.9828491	0.03
318.3370361	0.05
321.3607788	0.07
323.2525024	0.10
325.1137695	0.10
328.2077026	0.03
329.2791138	0.13
330.9720764	1.07
333.1137695	14.27
333.7597961	0.07
341.2598267	0.17
344.0084839	0.07
344.9470825	0.22
347.1715088	0.11
351.1659546	0.13
355.3185425	0.09
357.2353516	0.05
361.1837158	0.27
362.0565796	0.09
368.7053223	0.16
369.4187012	0.03
373.3786011	0.06
375.1757812	1.87
377.1037598	100.00
377.7640381	0.18
383.4819946	0.04
391.2708740	1.17
399.4198608	0.04
401.4123535	0.33
409.9468384	0.09
422.9490967	0.05
441.1475830	0.39
445.0595703	0.24
453.4569092	0.14
458.5341187	0.32
459.3641968	0.11
465.0811157	0.11
469.0255737	0.11
471.7612305	0.07
477.1619263	0.78
483.0952148	0.05
493.0486450	1.17
494.9462891	0.11
498.5311890	0.16
499.4577637	0.18
500.9661865	0.24
507.1007690	0.09
521.2819214	0.06
538.7259521	0.13
541.0623169	0.06
549.0466309	0.14
551.2080688	0.05
558.6858521	0.08
560.7857666	0.08
563.6146851	0.13
567.2074585	0.24
572.6746216	0.16
577.6784668	0.05
578.3525391	0.13
584.5416260	0.02
585.2348022	0.51
593.5739136	0.06
595.0364990	0.38
596.3981934	0.31
597.9207153	0.11
601.9724121	0.24
603.0708618	2.49
603.9971313	0.21
608.7862549	0.28
612.9234009	0.16
621.0677490	11.49
621.7908325	0.15
625.5741577	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	328.1169
Annotation	5,8-Dihydroxy-7-methoxyflavanone
Peak:m/z	Relative Intensity
98.0212479	0.11
98.9094696	0.06
99.8987579	0.06
104.8958435	0.02
106.7524109	0.03
113.0859222	0.05
125.9201584	0.32
137.1261597	0.07
139.1127625	0.06
144.0165863	0.02
145.1839294	0.04
146.9818726	0.09
151.2335815	0.08
158.0629272	0.13
163.1914978	0.09
165.1344910	0.07
181.2027893	0.03
185.9984589	0.02
191.2614746	0.07
193.1861115	0.03
198.9508820	0.58
201.1665039	0.10
203.0119781	100.00
204.0517273	0.21
205.0716400	0.06
213.1701050	0.13
215.0241089	0.10
217.0878906	0.05
226.9502258	0.61
227.9343567	0.08
229.1463623	0.06
241.0728149	4.58
242.3514099	0.04
243.1974182	0.23
245.3439026	0.04
249.2912903	0.02
251.2361450	0.04
254.3630676	0.12
257.1528320	0.18
269.0497131	29.22
270.2283325	0.47
279.4029236	0.06
281.7001038	0.09
286.9964294	41.13
288.0224609	0.18
292.3370361	0.04
293.1865845	0.11
296.9591675	0.04
303.2467651	0.09
309.2271729	0.38
310.2951660	1.04
311.1225586	0.04
318.9903564	0.11
319.8784180	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.1531
Annotation	Kadsurenin B
Peak:m/z	Relative Intensity
102.9818878	0.34
104.9699631	0.24
106.7586975	0.08
116.1283646	0.09
120.1620483	0.04
121.0314331	0.45
124.9581985	0.58
128.9811707	0.11
130.0539246	0.29
130.9988098	1.90
132.0402527	0.86
132.9096222	0.72
135.0632782	0.18
136.9500732	1.92
143.2602844	0.07
145.1409302	0.24
147.1092224	2.53
148.9246826	0.17
151.0471497	1.16
151.9631500	0.13
153.0525360	3.56
156.7791443	0.14
157.9382629	0.04
159.1137390	1.49
160.1673889	0.09
160.9957886	0.13
163.0069580	3.04
165.1135254	0.61
169.1465607	0.05
173.0854340	0.18
174.9740143	21.31
177.0867920	2.96
178.8215485	0.52
179.9574738	0.15
181.0221405	1.74
182.6222534	0.11
185.2279358	0.12
186.9680481	0.23
188.9261780	0.13
191.1497955	9.56
193.0551453	0.19
200.1984558	0.27
201.0950012	2.95
205.2917175	0.33
205.8986664	0.14
211.1577454	0.19
219.1015015	14.08
222.1230164	0.12
226.9879456	0.09
227.8960571	0.24
229.6887207	0.12
241.2944641	0.25
247.9307861	0.04
254.0360413	0.05
257.0917053	0.19
261.5707092	0.29
265.1022949	0.26
265.9579468	0.07
266.8807373	0.20
268.0028076	0.05
271.2350464	0.09
272.2424316	0.22
273.1259155	0.23
275.1334839	0.22
277.4767761	0.24
279.3108215	0.11
283.2187195	1.58
287.3972168	0.12
293.0532227	1.38
295.2686157	0.31
297.1903992	1.35
299.2937622	0.64
300.9421082	0.19
307.0689697	0.76
311.2310181	2.37
311.9855957	0.11
313.1510620	2.26
315.2175293	0.33
322.9042969	0.15
325.2025146	100.00
334.1223145	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	291.0722
Annotation	Unknow
Peak:m/z	Relative Intensity
84.9879532	4.95
98.8464661	0.10
102.9773178	0.07
110.9032059	1.00
114.9142151	0.03
129.0056000	7.56
144.9483643	0.13
147.0352173	6.90
161.0669403	0.05
167.0567627	0.07
172.9966583	7.49
190.9935608	100.00
201.2053833	0.16
204.1646118	0.15
220.9683228	0.03
229.0716248	0.17
229.6933289	0.02
231.1125793	0.13
245.4049072	0.03
247.1893616	0.10
255.2689819	0.16
273.0873413	15.89
292.1184692	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.261
Annotation	Briaranolide B
Peak:m/z	Relative Intensity
214.8145447	0.11
287.4144287	0.04
295.1513062	0.12
307.1871338	0.19
321.4520874	0.30
325.3625488	0.46
330.2240601	0.13
343.3206787	0.21
369.1586304	0.40
373.4762573	0.51
383.1882324	0.32
415.1458130	0.30
427.2704468	0.13
431.2698975	0.07
441.5831909	0.08
451.0916138	0.04
455.4083862	0.25
463.6360474	0.06
465.2203369	0.27
471.2284546	100.00
471.8490601	0.40
474.2233887	0.06
481.4376831	0.07
485.3000488	2.28
487.2320557	0.05
495.2649536	16.69
497.3504028	0.26
499.5991821	0.43
513.1188354	26.96
517.1137085	0.28
521.4616089	0.21
525.1657715	11.24
530.2279053	0.41
535.1752319	1.73
537.1751709	1.85
541.8143921	0.74
543.0304565	12.76
552.2692261	0.14
553.6106567	0.32
555.2128296	2.25
559.1275635	0.14
559.8830566	0.22
560.7634888	0.90
561.4863892	0.34
571.5868530	0.36
572.4392090	2.06
573.0728760	8.43
575.4583740	0.26
577.2797852	0.45
590.0654907	0.12
593.1426392	0.24
603.2678223	0.66
615.0155029	1.23
619.6234741	0.09
621.4779663	1.63
632.4547729	2.78
633.1547241	20.33
635.1430664	0.92
647.6480103	0.11
661.4334106	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	667.1841
Annotation	7-(4-Carboxy-3-hydroxy-3-methylbutanoyl)sudachitin 4'-glucoside
Peak:m/z	Relative Intensity
196.1462402	0.03
198.0430603	0.02
236.8472290	0.03
258.2192383	0.02
269.0450134	0.02
271.1295166	0.02
275.2372131	0.10
281.4606934	0.03
286.0126343	0.03
297.3389587	0.04
299.0904236	0.03
299.9009399	0.04
301.1755371	0.25
302.1762695	0.01
310.0540771	0.02
315.1307373	0.02
316.1149292	0.03
321.0926514	0.02
323.1481323	0.02
328.0496826	1.12
331.1027222	1.80
332.2122803	0.08
334.9776001	0.01
339.1031494	0.03
343.3112793	0.06
346.1247559	2.29
347.1831665	1.93
356.1377563	0.06
359.6765747	0.08
361.1223145	100.00
361.7590942	0.12
365.0634766	0.03
389.2120972	0.16
391.2272339	0.06
393.2203979	0.07
395.2274170	0.02
403.2674561	0.22
424.8546143	0.05
431.3161011	0.07
438.3977661	0.02
443.3179321	0.04
454.3562012	0.04
455.0832520	0.07
457.2340088	0.03
469.1451416	0.04
473.2138062	0.05
479.2041626	0.06
487.0198364	0.08
497.0792236	0.06
502.4609985	0.01
503.2181396	0.02
505.3624878	0.05
507.2539673	0.01
511.6346436	0.02
513.1876831	0.02
521.2055664	0.02
529.2693481	0.01
537.3272705	0.03
538.4697266	0.02
541.0658569	0.07
543.2900391	0.08
545.1643677	0.02
551.4904785	0.02
561.5731812	0.02
565.4019165	0.06
571.3624878	0.01
576.7753296	0.03
581.5504150	0.05
605.1783447	0.17
613.2231445	0.02
617.0989990	0.02
620.8020630	0.02
621.4426880	0.04
622.6328735	0.10
623.3901978	0.18
626.1397095	0.03
629.9152222	0.02
631.1669312	0.07
637.6094360	0.01
648.5137329	0.09
649.3334961	1.02
667.3810425	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	635.2146
Annotation	Unknow
Peak:m/z	Relative Intensity
178.8128204	0.04
214.7536926	0.02
220.8813019	0.12
232.7814636	0.11
233.5167236	0.04
262.8557129	0.02
281.1022034	0.06
323.0552673	0.24
329.1399536	0.03
341.1530151	0.96
363.1130371	0.07
383.2031860	2.18
391.3026123	0.04
399.9528198	0.03
412.6098022	0.35
413.2098999	0.06
424.9683838	0.27
433.9818726	0.32
442.9356079	5.49
443.5861816	0.02
449.9886475	0.07
455.5252686	0.03
472.7442017	0.22
485.0075073	0.06
488.7908325	0.18
493.7043457	0.04
494.3802490	0.06
503.2093506	100.00
530.2395630	0.09
563.2542725	0.03
589.0581665	0.43
617.1323853	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.2412
Annotation	Unknow
Peak:m/z	Relative Intensity
270.8935547	0.23
297.0725098	0.23
300.0894775	0.50
305.2230530	0.76
313.1224670	0.05
314.1969604	0.44
315.1066895	5.67
347.1655884	0.04
357.3070374	0.41
449.0763550	0.82
459.2335205	0.40
467.3203735	0.15
477.2502441	23.28
492.9151611	0.07
495.4884033	0.16
501.2979126	0.08
507.0786743	0.21
518.6451416	1.20
519.2600098	19.43
521.4290161	0.05
547.2850952	0.06
559.2340698	12.80
561.2222290	4.43
573.4010010	0.15
591.0642700	0.19
601.2748413	2.87
603.3250122	0.90
611.2297363	0.17
617.3081055	0.09
619.3585205	0.12
621.1337891	100.00
621.8535156	0.23
627.1132202	0.26
631.1615601	0.05
639.1029053	0.27
641.1027832	0.64
645.1983643	0.40
657.5542603	0.17
663.1245117	27.47
663.7694702	0.18
667.5181274	0.05
673.3333130	0.17
677.4915771	0.06
681.6147461	0.03
685.1212158	0.27
690.2945557	0.15
692.1128540	0.42
693.1153564	1.54
703.2028198	2.66
705.2810669	1.86
717.4723511	0.08
721.2624512	0.07
723.1283569	2.35
729.2756348	0.27
733.0805054	0.11
735.2340698	1.32
737.0248413	0.11
745.3648071	1.21
747.2116699	0.96
753.3439331	0.05
756.8660889	0.04
758.7369385	0.09
765.1718140	59.36
771.1566162	0.11
775.0580444	0.17
783.1390991	9.22
804.9751587	0.58
807.2222900	7.51
819.2946167	1.22
825.2200928	2.64
836.6469116	0.30
837.2750244	2.15
849.5524292	0.17
859.3871460	0.08
861.1728516	0.21
865.3872681	1.03
867.1920776	8.46
878.9083252	0.06
896.8567505	0.77
909.1907349	2.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	299.24
Annotation	Unknow
Peak:m/z	Relative Intensity
90.9682693	0.18
94.9721375	2.94
97.0967102	1.35
100.9520874	0.74
102.8886108	0.06
104.8195801	0.19
108.8856735	1.30
111.0819397	2.56
112.9523239	0.08
113.9477692	0.14
114.9075012	0.27
117.1903992	0.25
118.3580017	0.40
119.0196533	1.14
120.1209946	0.06
123.0788574	1.34
124.0476532	0.12
125.0036926	1.13
127.2690506	0.28
129.0482178	3.00
130.8794250	0.63
132.9263916	0.89
134.8190918	0.34
137.0366516	1.51
139.0140991	0.67
140.9585571	0.72
143.0317993	6.61
143.9199982	0.41
144.9722290	0.88
147.1476440	0.72
149.0212402	0.41
150.2408447	0.26
151.0629578	1.14
153.1056061	0.23
154.8895264	2.12
155.9573059	0.26
157.0186462	4.71
157.9874878	0.11
159.0231628	0.98
161.0037231	0.49
163.1017761	0.12
165.2061920	0.87
167.1404114	0.09
169.0274658	1.77
170.0285339	0.33
171.1019745	2.73
172.9402466	0.23
175.0347595	0.05
177.1848755	0.15
179.0526733	0.37
181.0847931	0.14
183.0511475	1.62
185.0923157	5.51
186.1460266	0.13
187.0210571	0.50
189.0433502	0.34
191.2180176	0.23
193.2416382	0.37
194.9267273	0.22
195.6547089	0.43
197.0553894	0.96
199.0883484	5.97
202.3698425	0.18
203.0895996	0.22
205.2438660	0.11
209.0636597	0.07
211.0345154	0.24
211.9769897	0.30
213.2765198	0.27
215.3221130	0.83
216.1202087	0.48
217.1989136	1.21
221.1102905	5.71
223.3726196	0.34
225.2458191	1.25
227.2359924	0.28
229.2017822	0.59
231.0881653	3.85
233.0698547	0.39
235.0635376	0.18
237.0957947	0.26
238.9846802	2.37
240.3800659	0.13
241.2156982	0.65
243.0375977	0.89
248.8920593	0.10
251.8303223	0.23
253.1723938	4.28
254.9407349	0.46
256.2637329	0.72
257.2667236	0.90
258.2806091	0.29
259.0644226	0.12
261.0475464	0.37
262.2706909	0.46
263.3057861	3.86
270.1463623	0.42
271.1202087	0.80
279.2751465	0.40
281.1758118	100.00
282.3479919	0.31
283.0570679	0.26
290.1517639	0.78
296.9821167	0.21
299.1351318	1.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.1665
Annotation	Haploside D
Peak:m/z	Relative Intensity
193.0597076	0.02
194.8958435	0.06
196.1822357	0.02
202.9941711	0.17
219.1587830	0.08
221.2959595	0.10
236.9194641	0.05
238.4217224	0.02
245.5749359	0.03
247.1562805	0.03
255.1938934	0.10
263.1373901	0.03
283.9737854	0.01
285.4881897	0.04
287.3662109	0.19
291.2440186	0.21
302.1126709	0.07
303.3039551	0.18
305.2090454	1.13
311.0815430	0.04
315.3829346	0.03
317.2406616	0.81
325.3640137	0.05
331.3924561	0.10
332.2395020	0.05
333.3643799	0.13
339.3276978	0.03
341.0784912	0.06
343.1195374	0.22
345.0559082	0.25
355.2752075	0.03
356.9164429	0.11
360.0773315	3.40
361.1134033	0.56
372.1973877	0.07
375.0452271	12.51
383.3641968	0.12
401.2337036	1.58
417.0478516	0.09
419.1912842	0.14
423.1970215	0.07
443.4923706	0.11
444.2184448	0.02
445.3980103	0.10
457.2446899	0.10
463.3184204	0.10
505.0885620	0.39
519.4134521	0.10
523.2095337	1.07
526.0545654	0.05
533.1834106	0.02
537.1696167	100.00
538.2490845	0.05
545.2633667	0.10
559.3491821	0.09
563.1405640	0.15
565.2542114	1.58
579.1119385	22.40
579.7813110	0.23
585.5175171	0.11
591.0302124	0.05
595.2646484	0.15
605.3732300	0.91
606.5596924	0.08
607.4166260	0.28
615.9680786	0.05
619.2553101	6.50
621.1965332	0.06
631.2077026	0.26
632.1609497	0.04
636.2383423	0.13
636.8767700	0.02
648.7874756	0.11
649.4375610	1.16
653.3406372	0.08
663.1260376	0.53
666.3453979	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.3277
Annotation	Boivinide E
Peak:m/z	Relative Intensity
259.0224609	0.02
260.4239502	0.02
285.9707336	0.01
300.4434204	0.01
309.4492188	0.04
313.2945557	0.02
352.9279175	0.01
367.3298950	0.03
374.1427002	0.01
389.1121826	0.13
403.3975830	0.07
422.3546143	0.01
427.3463135	2.36
433.4926147	0.01
445.2412720	0.12
460.2553101	0.07
469.3240356	0.45
472.4160767	0.03
487.0421143	0.02
499.3791504	0.08
507.3689575	0.04
508.2682495	0.02
511.3178101	0.22
525.3220215	0.01
532.3506470	0.13
533.1230469	0.02
536.9691162	0.05
545.0917358	0.10
547.2704468	0.48
548.1107178	0.03
549.2083130	0.01
558.9723511	0.02
565.3641968	0.15
571.2490234	0.36
577.5401001	0.01
579.8710938	0.07
587.7813110	0.01
589.3410645	100.00
605.2835083	0.07
607.2551880	13.05
609.4270630	0.01
631.2015991	0.14
634.2606201	0.09
635.2885742	1.65
649.2051392	15.34
649.9228516	0.04
651.2786255	0.09
677.3948364	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	304.914
Annotation	Unknow
Peak:m/z	Relative Intensity
130.9827423	4.63
146.8959656	0.64
158.8858948	0.09
174.8904419	100.00
230.8710327	0.14
232.9252625	0.07
248.9621582	0.08
260.9369202	5.49
261.6760254	0.01
276.9381104	1.45
286.9999390	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1821
Annotation	Hesperidin
Peak:m/z	Relative Intensity
174.1064758	0.12
175.0907593	0.04
175.8805237	0.07
184.9480743	0.30
186.9522095	0.04
188.1891479	0.11
189.8994598	0.04
191.0140991	0.12
198.1305695	0.31
199.1481018	0.94
200.0007019	0.07
200.9178772	1.63
201.8243408	0.06
205.3465424	0.06
209.3092346	0.08
210.9202576	0.05
214.041275	0.06
215.1932678	0.27
217.053009	0.20
218.0009308	0.05
223.242981	0.03
224.0090027	0.11
225.0969696	0.06
226.0692902	0.03
226.9580536	0.76
228.9354553	0.08
230.2184601	0.10
233.1038208	0.19
238.2905121	0.03
239.3865509	0.25
240.1941986	0.12
241.1202698	0.33
242.0409546	1.75
243.1650696	0.14
255.0774994	0.47
257.1540222	0.69
258.1039734	0.32
259.2230835	0.05
264.9234009	0.03
265.8488159	0.09
267.0390625	0.05
268.1271362	0.32
273.1424255	0.07
281.3878784	0.07
283.2156372	0.76
284.1483154	0.19
285.1231689	0.72
286.1467285	1.52
292.0518494	0.08
299.1430359	1.21
300.0395203	1.42
301.0805664	100.00
302.1161499	0.20
303.0534973	0.37
307.1911621	0.05
310.1237183	0.05
313.0072632	0.05
315.0339966	0.09
319.2139282	0.02
325.2145386	1.21
327.4708252	0.06
330.2677612	0.05
340.2615356	0.02
341.1984253	0.13
343.3164673	0.39
355.0785522	0.02
357.2713623	0.04
367.012146	0.18
369.2539673	0.19
373.1369019	0.16
385.2410278	0.04
399.2647705	0.36
421.1887207	0.06
423.4599609	0.04
428.2901611	0.03
443.1483765	0.10
447.3892822	0.13
453.3592529	0.10
463.1834717	0.12
464.4223022	0.20
465.3563232	0.26
467.2416382	0.07
471.0181885	0.06
483.4630127	0.05
488.6176147	0.17
489.2495117	1.24
492.1335449	0.03
493.4793091	0.08
501.4032593	0.02
505.4849854	0.03
506.2954712	0.14
507.3569336	0.17
519.3461304	0.24
536.2844238	0.11
537.2184448	0.11
541.4285278	0.04
547.2620239	0.03
549.0599976	0.07
561.5012817	0.05
563.236084	21.60
565.203125	0.21
566.7365112	0.02
591.1298218	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	771.1748
Annotation	Unknow
Peak:m/z	Relative Intensity
217.0193481	0.51
234.9833374	0.25
236.2934418	0.02
236.9629211	0.08
247.3064270	0.01
251.0991821	0.71
260.9741516	0.03
263.1098938	0.40
264.9500122	0.04
274.1394043	0.05
275.1389465	0.14
276.1382751	0.06
277.4096680	0.31
279.0566406	0.79
289.1119080	0.50
290.0215759	0.10
291.1593628	0.02
293.0581055	1.37
301.3197937	0.08
302.0190735	0.02
303.7477722	0.01
305.0435486	0.51
307.0384521	0.04
309.9309998	0.01
311.0206299	0.12
313.1943359	0.10
314.2958679	0.04
317.0302734	0.17
319.0384521	1.03
320.1381226	0.08
321.2308960	0.14
323.9620361	0.05
326.0875244	0.01
328.2694702	0.12
334.2243042	0.10
335.1514893	0.41
336.6813965	0.05
341.3211060	0.06
343.1757202	0.77
346.0886230	0.11
346.9716797	0.24
353.0122070	0.70
359.1522827	0.03
360.2354736	0.03
361.4744873	0.02
365.4261780	0.05
367.2186890	0.34
377.1216431	0.81
378.0475464	1.11
379.1648560	1.58
380.2662354	0.06
381.0779419	0.03
383.1449585	0.01
387.3338623	0.11
391.2727051	0.07
392.7786865	0.06
395.1550293	56.94
397.2358398	0.44
406.8993530	0.04
409.2182617	0.35
413.0240479	100.00
413.7567139	0.26
415.2077026	0.10
427.2495728	0.22
428.0524292	0.03
429.0172119	0.04
431.0708618	0.04
434.9544678	0.12
435.7144165	0.03
439.1746216	0.03
445.1207886	1.23
446.2515259	0.25
447.1359863	0.12
451.2302856	0.05
454.5198364	0.09
455.2509766	0.12
463.1865234	3.11
470.3749390	0.13
471.2279053	0.04
473.5101929	0.04
478.8843994	0.07
485.0672607	0.03
486.1492310	0.02
487.0256958	0.23
488.3221436	0.04
489.1910400	0.15
495.2354736	0.12
505.0213013	0.58
505.6920776	0.01
514.1727295	0.05
515.1167603	0.15
528.9026489	0.20
530.2114868	0.06
532.9055176	0.47
543.3121948	0.03
556.8231812	0.12
558.8974609	0.39
564.1075439	0.04
565.3031616	0.03
571.2123413	0.18
572.3385620	0.11
573.1907349	0.05
574.3804932	0.88
575.1958618	1.38
578.7156982	0.05
587.3836670	0.04
589.1120605	0.12
589.8712769	0.07
590.7781372	1.02
591.4749146	0.10
592.8552856	0.12
597.0247192	0.05
607.0912476	2.21
607.7602539	0.86
608.8698120	6.83
609.5322266	0.02
625.1178589	5.19
625.9258423	0.02
633.2199097	0.03
648.4035645	0.10
650.7260132	0.48
666.4912109	0.12
670.5188599	0.05
675.4296265	0.08
698.5498047	0.09
705.1178589	0.45
707.2573242	0.12
716.9520264	0.26
725.8905640	0.04
734.2008667	0.09
735.0817261	0.41
737.7664185	0.14
752.4865112	0.71
753.1301880	4.05
753.9089966	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	564.8294
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8795929	1.77
203.2326355	0.18
231.2346497	0.05
260.9067993	0.23
277.0346069	0.06
288.9760132	0.02
304.9581299	32.08
305.9241333	0.03
418.9118652	1.41
419.7933350	0.02
434.8226318	100.00
435.4281616	0.40
450.1695557	0.11
490.5711060	0.03
493.0762939	0.05
517.8082886	0.59
518.9472046	0.20
522.2212524	0.07
541.3323975	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	415.1609
Annotation	Secologanin dimethyl acetal
Peak:m/z	Relative Intensity
129.0108032	0.26
131.0767975	0.15
132.9593506	1.67
141.0415192	0.22
142.9954529	0.42
145.0774536	2.77
160.9045868	1.77
162.6641235	0.57
163.2905579	1.62
165.2991638	0.30
173.0790405	0.54
177.1522064	0.68
179.0511169	7.05
189.3330231	0.20
191.0798035	0.60
207.0763245	100.00
217.2703552	0.15
224.8748779	0.79
249.1538086	1.02
287.4995117	0.17
301.2286682	0.34
307.2958984	0.32
308.9942932	1.12
319.3084717	0.23
351.1501465	0.42
355.2341919	1.24
368.8575439	64.48
369.6420593	0.28
371.1918640	0.14
397.4158020	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.2338
Annotation	Ajugapantin A
Peak:m/z	Relative Intensity
159.9276123	0.11
167.1694336	0.09
176.1891174	0.16
178.3722229	0.04
181.0466003	0.11
193.5588379	0.18
194.2579346	0.13
196.1283875	0.04
199.2856903	0.07
201.7963257	0.32
204.5186157	0.04
208.0768890	0.10
211.0148468	0.11
213.3934021	0.15
214.0061188	0.05
215.2128906	0.04
218.3153992	0.03
219.1793518	1.03
220.2916565	0.80
221.2822418	0.03
222.0998840	0.18
225.1961823	0.14
227.2968445	0.12
228.6617126	0.37
229.2685852	2.65
230.2509003	4.26
231.1017456	0.26
232.5505066	0.09
233.1815186	0.07
234.2059631	0.15
244.9095154	0.24
247.1563110	2.14
248.2863617	2.15
250.3660126	0.09
256.2060547	0.03
260.3335571	0.08
262.3524780	0.06
263.0960388	0.45
264.2609558	0.33
269.2296143	0.04
270.2204590	0.02
275.0457153	0.38
276.2545166	0.09
277.3203125	0.14
288.5644531	0.04
291.2105103	0.04
299.4193115	0.22
300.6020508	0.13
303.3332520	0.22
304.2299805	0.44
305.3315430	1.22
306.2749939	1.67
310.7984009	0.11
321.3197021	0.22
322.2623901	1.37
323.2588501	0.03
332.3957520	0.06
341.3186646	0.05
342.2692871	0.07
343.1992798	0.05
344.3540649	0.11
345.9454346	0.11
346.5871582	0.08
349.3623657	0.87
350.2404785	3.11
353.4824219	0.06
360.3149414	0.08
365.3333740	0.30
366.2794189	0.33
368.1218872	0.25
370.4675903	0.11
377.1392822	0.08
384.3649292	0.08
388.2811279	0.17
394.1123657	0.57
401.3473511	0.36
402.2684326	0.45
413.1841431	0.33
416.8176880	0.05
418.3588867	0.48
429.2700806	0.06
430.4606323	0.04
431.3588257	0.10
445.4142456	23.41
446.2833862	100.00
446.9346924	0.10
448.3937378	0.17
460.7181396	0.25
462.3094482	1.12
463.8002319	0.07
472.2466431	0.18
485.2131958	0.16
487.0050659	0.38
487.6325073	0.25
489.4401245	11.20
490.3611450	45.15
507.2428589	0.39
508.3948364	5.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	705.1817
Annotation	Unknow
Peak:m/z	Relative Intensity
209.0599060	0.20
211.1093750	0.10
292.8656311	0.11
310.8629150	0.07
311.5382690	0.10
346.8420410	0.07
349.1680298	0.04
354.7864990	0.14
363.1246338	0.26
364.9745483	0.85
378.9342651	0.47
381.0776367	1.34
383.2760010	0.27
397.0823975	0.14
437.0323486	0.03
437.9658813	0.04
438.9047241	0.03
441.3477173	0.05
444.4550781	0.12
471.0423584	0.24
495.2827759	0.17
503.0569458	0.10
507.2454224	0.06
511.3521729	0.04
525.1947632	1.77
531.1685791	0.26
533.1885986	0.58
534.9069824	3.01
537.3118286	0.05
543.1842651	100.00
544.3421631	0.68
546.7606812	0.20
548.6762085	0.13
565.3298950	0.10
568.9845581	0.68
570.4904175	0.06
571.7440796	0.13
572.9836426	2.21
575.1094971	0.08
599.7982788	0.16
606.9049072	0.43
615.1821289	0.05
620.9114990	0.50
638.0766602	0.07
638.8804321	0.47
640.3311157	0.04
641.0321655	0.05
642.4332886	0.06
644.8119507	0.19
646.1287842	0.03
652.3692017	0.08
658.7852783	0.67
669.1192017	0.14
686.8978882	0.93
687.7786865	0.02
689.1865845	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	317.05
Annotation	Unknow
Peak:m/z	Relative Intensity
94.8912659	2.15
96.9902039	0.87
98.9410324	0.72
100.8713684	0.74
106.9722748	0.35
113.0899658	0.47
115.1203613	0.22
118.8934021	0.03
121.2252045	0.02
122.7848129	0.31
125.0073700	7.38
126.0086975	0.52
126.9742355	1.68
128.6607513	0.07
131.0298920	0.03
134.9785614	2.21
137.0202332	0.74
142.9540100	0.39
145.0174103	0.42
146.7679749	0.51
148.9279785	4.31
150.8274078	0.07
152.9617310	4.95
161.0132141	0.21
164.9919739	16.20
166.1874542	0.34
167.0312805	0.42
177.0070801	0.75
179.0296021	0.90
180.8515015	0.10
182.9057312	0.14
189.0282745	1.06
198.8297577	0.35
200.0192871	0.06
203.1020813	0.42
207.0247498	8.76
208.0582581	0.25
219.1842041	0.10
225.0096741	100.00
226.0664368	2.24
232.9128723	0.22
235.0440369	0.10
240.6754456	0.47
258.0226440	6.69
271.1537476	0.10
272.8920593	0.27
281.1335449	0.18
299.1027832	2.95
300.1137085	0.06
301.0015259	0.04
317.2959595	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	782.2485
Annotation	Unknow
Peak:m/z	Relative Intensity
219.1614380	0.10
230.0270081	0.22
232.8727875	0.04
247.8923035	0.20
252.9641724	0.54
254.0996094	0.16
269.0936890	0.05
270.9246826	1.63
272.1970520	0.59
288.9259949	1.44
290.9607544	0.26
301.2692261	0.17
307.0762329	0.26
312.4213562	0.21
318.8415222	0.19
331.3902588	1.70
332.0784912	4.20
342.1441650	0.03
349.0601807	0.42
355.0541992	0.53
355.9696655	0.21
359.9291382	0.21
365.1954346	0.14
367.9973145	0.12
370.1759949	0.13
373.1442871	1.04
374.2522278	2.17
378.9893799	0.27
384.6296387	0.19
386.3029785	0.06
391.1679688	0.38
392.1480713	3.83
397.0549316	2.36
398.3361816	0.31
410.2321167	0.75
415.0480347	1.31
416.2890015	0.49
417.3048706	0.03
419.4712524	0.20
428.0928955	1.62
433.0601807	9.31
434.1539307	1.14
437.1887207	0.15
450.5556030	0.24
451.1822510	0.53
452.1554565	0.82
455.3262329	0.57
456.5952148	0.43
457.3363647	0.12
463.3358154	1.06
479.1807861	0.63
481.2452393	4.28
492.1583862	0.48
496.8385010	0.08
499.3056030	1.24
500.1208496	0.17
505.3551636	0.06
510.2481079	0.19
517.0075684	0.37
517.8756714	1.23
518.5174561	0.17
523.0741577	2.17
536.0540771	5.71
541.3278198	0.80
554.2322388	29.64
558.7288208	0.25
559.3902588	0.70
560.0295410	0.18
572.1468506	100.00
572.8339844	0.07
578.2585449	0.10
580.2929077	0.07
582.4428101	0.23
588.9990845	0.13
590.1332397	0.05
599.2332153	0.15
600.0829468	0.19
601.6658325	0.04
607.0736084	1.25
613.3289185	0.10
618.1605835	0.12
620.4865723	0.11
625.1172485	0.34
632.1790161	0.15
643.1487427	0.49
647.9263306	0.17
667.4293213	0.50
707.1896362	0.11
718.3569946	0.27
722.0748291	0.08
745.2214355	0.05
746.3615112	0.40
764.4161987	0.51
781.7709351	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.1882
Annotation	Unknow
Peak:m/z	Relative Intensity
121.9588623	0.20
128.9831848	0.05
134.8694763	0.03
136.9311981	0.07
147.0451965	0.11
156.0645752	0.04
159.0592651	0.19
165.0950317	0.13
170.9125366	0.06
175.1304626	0.16
177.0787354	0.66
189.0636902	0.02
193.0051117	0.05
194.1792908	0.02
197.2808533	0.01
199.2098694	0.12
199.8705750	0.01
207.1522217	0.07
215.0854492	0.02
217.1334229	4.63
219.0793152	0.07
220.0734558	0.18
235.1241760	3.37
235.7554626	0.01
239.9605713	0.08
248.0724182	0.05
249.1298218	1.01
251.1891479	0.05
267.1563416	2.42
275.1026611	0.09
277.3199768	0.09
282.2075195	0.03
292.0938416	0.16
293.1399536	0.03
303.2845459	0.03
310.1354370	4.16
311.0160522	0.09
313.0286865	0.03
321.1313171	8.67
338.2395020	100.00
339.1264038	38.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	561.2169
Annotation	Nocardicin B
Peak:m/z	Relative Intensity
159.1323090	0.22
162.8687744	0.40
169.0964203	22.10
179.2512054	0.15
186.9808197	1.13
190.9241028	0.47
193.0791626	0.21
206.0131531	0.07
209.3018494	0.07
211.1425781	0.42
212.3437042	0.48
213.0583191	2.66
217.0931702	0.34
219.3042297	0.12
227.1360626	0.17
228.7897491	1.29
231.0592651	7.05
234.9899292	0.31
237.0427094	0.14
238.9061279	0.06
243.5442505	0.04
248.8437653	0.41
252.9430542	1.04
254.6720276	0.46
259.1770630	0.42
269.0071411	0.09
270.1051025	0.23
271.8496094	0.13
272.9379272	2.43
275.1183472	0.25
277.1164551	0.79
280.9870605	0.07
289.3339844	0.09
290.9888916	8.08
292.3745117	0.08
294.8170776	0.11
297.0421753	0.17
313.0562134	0.88
315.0257568	0.08
318.7018433	0.21
320.9580688	0.49
323.2498169	0.11
331.1826782	2.08
333.0155640	0.34
337.0982056	0.32
338.1697388	0.08
339.1166382	2.10
341.3930664	0.04
345.2872314	0.07
351.0321655	0.07
355.1742554	0.42
356.6072388	3.09
357.2197266	4.07
363.3064575	0.24
369.2203979	0.09
370.5250854	0.08
375.0222168	100.00
375.8524170	0.53
377.2679443	0.12
381.2468872	3.43
392.9421387	28.66
394.2311401	0.24
395.3059082	0.29
397.6721802	0.10
399.0497437	0.55
399.6699219	0.07
417.1046143	8.56
437.1405640	0.34
441.1471558	2.31
457.0943604	0.05
459.2100830	0.26
461.4447021	0.13
475.1132202	0.21
483.5764160	0.08
489.3576660	0.03
492.7902222	0.12
499.1035767	1.71
516.4525757	0.09
517.3890991	0.36
525.2017822	1.28
529.3923340	0.12
533.2132568	0.11
543.1232300	14.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1925
Annotation	(+)-Kurramine
Peak:m/z	Relative Intensity
209.2722626	0.29
265.1696777	100.00
267.1169434	0.10
292.0755615	0.10
410.0333862	0.19
412.8402710	0.09
441.2379761	0.03
471.9164429	0.19
495.2421875	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	467.1169
Annotation	2,5,7,3',4'-Pentahydroxyflavanone 5-O-glucoside
Peak:m/z	Relative Intensity
152.8706665	0.65
204.8283386	0.18
223.2860260	0.44
230.2316284	0.82
245.2875977	0.27
253.2265015	0.53
260.9749146	0.51
287.2490845	1.11
288.9602661	0.70
297.1772766	0.65
304.2228699	0.83
305.3583374	0.82
313.1337280	0.83
315.1779785	0.39
318.3335571	0.30
323.1136475	0.52
329.1545715	1.71
334.7741699	1.87
346.8537598	0.41
365.1696167	0.12
371.2467346	0.83
377.3583374	0.44
383.1017456	0.54
392.3594055	0.18
394.8053589	0.15
407.1794128	1.27
413.1198730	3.60
419.1768494	0.32
430.4080811	0.12
431.1708374	14.89
444.3651428	1.56
449.1977844	100.00
450.1396179	1.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	735.2186
Annotation	Unknow
Peak:m/z	Relative Intensity
218.1273041	0.20
219.1285248	0.71
221.2074432	0.27
227.1118622	0.09
232.7425079	0.17
243.0317383	0.71
245.1228943	5.05
247.0503082	0.76
258.9181519	0.34
262.9925842	0.79
265.1563110	8.30
271.1544800	0.54
275.2666626	0.22
277.2237244	0.64
283.1651001	2.00
289.0505981	1.37
294.8960571	0.44
298.4879150	0.15
305.0539246	13.72
306.1341553	0.62
307.0344849	1.18
308.4250793	0.31
309.1290894	0.20
311.1360779	0.06
317.0578003	2.40
319.2048950	0.52
321.0751953	1.54
322.0037842	0.41
323.2321777	0.12
325.2369385	0.16
329.2234497	0.65
337.2230225	6.08
338.7197571	1.98
339.3884277	0.28
341.2904053	0.33
343.5517578	0.19
349.1328125	0.54
353.4260254	0.16
359.0469055	0.58
361.3730469	0.23
371.0731201	0.41
377.0410767	0.93
377.9755859	0.16
381.2554932	2.67
382.2747192	1.26
383.3018799	2.02
391.1179810	0.07
394.1107178	0.35
394.8065186	0.20
397.1609497	6.45
401.2045898	0.16
409.1156006	0.59
411.6273804	0.54
415.2729492	7.70
421.3541260	0.41
422.1948853	1.20
423.0744629	0.36
435.1850586	0.57
437.1216431	0.45
439.0989990	0.12
440.3020630	0.59
449.0866699	7.74
450.3428345	0.80
451.2346802	0.67
453.2055054	4.09
454.2998047	3.51
455.1437378	1.93
460.2780762	0.75
461.1774902	0.17
462.6578369	0.17
467.0324707	0.39
469.2498779	0.17
471.0628052	0.37
472.2642822	0.53
473.2590332	0.94
476.2785034	0.32
481.3439941	3.58
482.2575684	0.92
485.4374390	1.47
491.3355103	0.66
492.7346191	0.43
493.4102783	0.47
494.3783569	1.86
495.1580200	0.33
508.3065796	0.19
509.4441528	1.20
511.2321167	3.45
512.1400757	0.13
513.3996582	0.53
514.3093872	0.15
515.2285156	0.23
523.2090454	0.32
524.5880737	1.18
525.3048096	2.46
526.3479614	6.99
527.3588257	2.07
529.3496094	6.77
537.1501465	0.41
541.1752319	0.24
543.1544189	4.91
544.3017578	13.53
545.2896118	3.51
554.2860718	0.07
555.2555542	0.75
561.3513794	0.70
568.4094238	0.11
571.6309814	0.28
572.3080444	0.58
573.3657227	1.26
582.0908203	0.13
585.4733276	0.69
586.1813354	0.95
587.4038696	0.50
603.2648315	16.49
604.2668457	51.92
605.3637085	19.87
606.2565308	0.25
614.2999878	0.22
625.7567749	1.44
626.3616333	0.84
627.3671265	1.98
644.2984009	1.28
645.1746826	0.86
646.3965454	0.98
647.1430664	0.43
657.2378540	2.59
658.2639771	37.70
659.2603760	17.17
660.0951538	0.10
661.2522583	17.11
661.9351196	0.24
675.5264282	17.76
676.2940063	100.00
677.3039551	54.20
687.1936646	0.40
693.3327637	3.44
700.1924438	0.16
705.2509766	35.51
705.9259644	0.16
707.2907104	0.79
719.4267578	1.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.4615
Annotation	Unknow
Peak:m/z	Relative Intensity
223.0607452	0.13
224.0808258	0.14
225.2230682	0.41
226.1553497	0.30
228.9917450	0.22
235.1083374	0.22
238.0459595	0.10
242.2169952	4.44
243.2609863	2.24
247.4139862	0.50
249.2857361	0.67
251.5353241	0.21
260.0265808	5.43
265.3683777	1.26
268.1943665	0.36
269.3191223	0.16
278.3665466	0.18
282.2702942	1.46
296.2987976	0.24
298.4403381	0.33
299.2467651	0.72
300.2395020	0.26
303.2135925	0.39
303.9189148	0.26
304.6339111	0.35
305.2855835	0.50
306.4152222	0.92
307.0936584	0.19
308.1495361	0.45
310.3270264	0.31
312.2054749	0.13
313.4599304	0.46
316.2714844	2.74
322.3920288	1.06
324.5836792	0.31
325.2291870	0.92
326.5654907	0.95
330.2885132	0.12
331.4558105	0.68
336.1810303	0.55
339.4594116	1.09
340.3007202	4.31
345.2745361	0.56
350.3430786	0.17
353.5826111	0.16
355.1760864	0.42
356.3984985	1.99
357.1915894	3.29
360.1820679	0.35
363.3401489	0.18
364.1747437	0.14
365.5114746	1.57
367.6438293	0.41
370.5925293	0.43
372.2693176	3.88
373.3287354	7.89
374.2668457	25.21
378.3353271	0.85
380.2048340	0.94
381.5667114	0.90
382.4712524	2.15
386.0064697	0.40
390.3786011	12.30
391.3893433	0.16
392.2305908	0.12
396.3233643	1.23
399.4995728	0.22
406.3053589	0.25
413.4255371	0.39
414.3310547	4.91
416.4333496	2.54
418.2734375	0.92
419.4744263	1.98
420.3054810	0.65
421.2461548	0.64
422.2819824	0.11
425.4971924	0.45
430.3579102	3.72
431.2315063	0.36
432.5874023	0.40
434.4708862	0.66
435.9288940	0.37
437.4532471	0.72
438.2943115	0.70
439.4647217	0.79
442.3611450	0.21
443.2060547	0.46
444.7433472	0.51
446.4309082	0.41
448.3897705	0.34
451.3381958	0.40
452.5010376	2.02
453.4676514	1.99
455.5170288	2.15
458.2955933	1.74
460.3749390	0.12
461.0350342	0.11
462.3853149	1.58
464.5900879	0.30
466.8771973	1.43
467.5120850	0.90
470.2390747	2.18
471.4614868	0.52
474.4191895	0.18
475.5969238	1.48
476.4695435	3.72
478.3059082	7.06
479.4190674	1.01
480.3324585	0.17
482.5610352	0.32
486.1375732	2.77
486.8361206	1.57
492.2874756	3.10
493.5281372	0.63
494.6648560	1.14
496.4353638	0.29
501.2448730	0.58
503.4520264	0.82
504.4736938	2.37
506.4724731	4.54
507.5888062	1.87
509.0509033	0.47
510.4057007	4.38
511.9732666	0.09
513.4766846	0.79
514.4544678	0.48
516.4700317	4.25
519.4095459	1.50
521.6879883	0.24
523.3264160	0.90
524.4475708	1.00
526.6376953	0.65
527.4925537	0.94
528.6099243	1.14
529.4102173	0.25
530.2853394	0.48
531.4666748	2.09
532.5122681	10.72
533.3272095	5.51
534.5719604	3.98
535.6230469	2.24
538.4288330	0.72
539.4422607	0.60
541.2984619	0.35
545.5290527	2.81
548.3386841	1.72
549.5188599	8.57
550.4743652	8.65
551.3567505	0.64
553.3494873	2.25
555.6842651	0.57
556.3441772	0.29
557.4182739	1.96
558.6162720	0.35
561.5230713	0.94
563.4779663	2.83
566.4953003	10.34
567.3992920	11.66
568.2794800	0.17
571.4133911	3.74
572.5920410	0.49
573.6594849	0.67
575.4598999	21.66
576.4692383	0.74
577.3973389	1.84
578.4486084	0.69
579.8925781	0.55
580.5935669	1.36
581.2683105	1.14
582.3956909	0.76
583.4763794	5.28
584.4588013	45.67
585.6454468	0.70
588.5634155	5.96
589.4768677	25.24
590.2803345	0.37
591.5004272	27.82
592.4329224	0.25
594.5574341	0.19
597.6221924	0.21
599.5122681	5.69
600.3880005	0.18
605.3250122	8.82
606.4348755	35.93
607.5155029	0.20
609.2943726	4.09
610.3828125	0.58
611.6262817	0.81
613.7704468	0.20
614.4456177	0.51
618.6563110	1.25
619.4737549	2.73
621.4498901	0.19
622.4663086	2.59
623.4027710	47.82
628.3513794	1.77
630.2980347	3.67
632.4652710	5.68
634.4826660	2.11
635.4193115	2.35
636.8533325	0.71
639.8881226	2.41
640.5887451	22.77
641.3602905	0.10
643.4105835	0.38
644.8226929	0.17
645.8665771	1.30
646.5120239	2.26
647.4652710	0.44
650.7764282	1.99
651.5914917	0.40
652.7163696	1.84
653.5797729	3.30
656.2356567	0.69
657.6766357	0.33
659.4513550	2.18
661.5140991	3.94
662.3954468	0.33
663.5481567	3.50
665.5178223	1.00
666.7349243	0.11
674.2288818	0.12
676.5723877	1.03
677.6854858	0.27
678.4537354	3.46
679.5178833	17.99
680.5912476	7.74
684.6360474	1.80
689.5895386	0.81
691.4796753	1.15
692.5088501	0.13
696.4728394	15.94
697.7673340	0.61
701.7006226	1.30
702.5151978	8.80
704.2123413	0.24
709.3360596	3.45
714.5644531	0.91
718.5011597	2.90
719.6129150	1.77
720.3047485	0.29
722.4573364	1.39
724.7233276	0.40
732.4961548	9.17
736.4840698	46.46
737.1683960	1.96
749.4706421	5.81
750.5796509	31.97
751.7241821	0.36
757.4630737	2.01
764.3381958	1.42
766.5580444	3.52
775.4464111	100.00
776.4874268	2.65
777.6552124	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.1666
Annotation	Haploside D
Peak:m/z	Relative Intensity
201.3080444	0.07
224.9986572	0.02
231.3370667	0.06
263.1513062	0.03
271.1332092	0.02
289.0148926	0.05
305.1970825	0.21
315.2064514	0.06
316.1568604	0.06
317.1475525	0.44
318.1062012	0.16
331.1806030	0.03
332.0838318	0.13
333.0109253	0.02
335.4411926	0.07
343.2915649	0.06
345.0834961	0.17
346.1052246	0.20
353.8969727	0.04
356.3343506	0.01
360.1414185	1.89
361.1758423	0.50
361.9093628	0.05
366.1198120	0.10
372.8913574	0.02
375.1744385	14.24
413.3819580	0.07
415.5402222	0.04
433.4761353	0.09
445.2531738	0.05
451.3034668	0.05
465.4091797	0.02
471.5426025	0.24
472.4423218	0.07
473.4417114	0.07
474.9158936	0.08
486.4263306	0.02
489.3189697	0.03
491.2937622	0.07
492.6519165	0.03
493.6370239	0.02
500.4927979	0.05
501.4074097	0.05
518.2744141	0.04
519.2576904	0.52
521.5293579	0.03
522.1611938	0.05
523.3555298	0.55
528.6035156	0.10
531.0225830	0.01
537.1808472	100.00
537.8460693	0.15
549.4223022	0.04
550.3864136	0.02
551.3916016	0.20
557.4684448	0.08
559.3858032	0.33
565.3325806	0.64
574.1948853	0.06
579.2012329	24.25
585.3909302	0.04
593.4791870	0.03
595.3087158	0.31
597.2351685	0.02
602.3244019	0.02
604.2490845	0.05
605.3025513	0.13
607.0183105	0.12
617.4544067	0.02
619.2227173	6.74
621.1660156	0.64
631.1601562	0.47
635.3982544	0.08
637.1098022	0.18
639.2924194	0.04
640.0965576	0.12
642.4488525	0.07
645.3328247	0.04
648.5464478	0.04
658.2831421	0.05
661.4260864	0.14
662.2764282	0.09
663.2522583	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	326.1436
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9947052	0.11
104.9184189	2.98
108.1039047	0.07
108.9479218	0.19
126.9598312	2.20
132.2610626	0.01
144.9720459	0.10
147.0884857	0.19
163.9817352	0.06
164.9356384	0.06
169.0739288	0.72
180.2053375	0.03
183.0580902	0.05
184.2723999	0.02
186.8961182	0.03
201.9379272	0.08
203.1390686	0.04
204.7127686	0.04
212.0518188	0.02
213.0386658	0.41
215.0170288	0.20
216.2639771	0.01
228.0514526	0.02
230.8942261	19.29
231.5046387	0.05
233.1555481	0.12
244.0105896	0.01
248.8686829	13.75
249.5074768	0.11
250.8910828	0.03
255.0441589	0.16
264.1048584	0.01
266.0281067	1.50
268.2304688	0.03
269.1439514	0.35
270.2320557	0.36
273.0570679	15.69
290.3285522	11.78
290.9301147	100.00
291.6101685	0.21
297.0676270	0.03
308.2279053	0.49
308.8871460	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	751.1723
Annotation	Unknow
Peak:m/z	Relative Intensity
301.0607605	1.59
305.2930908	0.03
329.1021423	0.51
431.3746948	0.07
445.2011108	0.32
463.2015381	43.99
486.9143677	0.07
487.5938110	0.06
505.2756958	26.02
527.1369019	0.18
545.2363892	9.06
547.2349243	5.57
549.5310059	0.06
557.1937866	0.07
561.1350708	0.04
587.1502686	2.37
589.0524902	0.57
604.3909912	0.21
607.1249390	100.00
607.7528687	0.25
608.7417603	0.17
609.4852295	0.06
627.4624634	0.35
649.2167969	15.01
661.4708862	0.16
662.6594849	0.04
669.7888794	0.06
671.4644775	0.07
673.0781860	0.07
689.2727051	5.75
690.2290039	0.35
691.2718506	0.32
701.1305542	0.02
703.4910278	0.14
704.9386597	0.33
707.3511353	0.17
732.9509888	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	304.117
Annotation	5,8-Dihydroxy-7-methoxyflavanone
Peak:m/z	Relative Intensity
108.0999069	0.04
108.9070892	0.04
117.0249786	0.01
124.9668045	0.02
126.1309662	0.03
130.0356598	0.03
135.0255432	0.02
145.7270203	0.21
151.0003815	0.03
152.1612854	0.06
152.9220886	0.29
153.8936157	0.15
174.7721558	0.09
177.0253754	1.26
177.9645386	1.91
179.0275574	0.56
180.0562592	0.96
185.1232147	0.02
186.0977173	0.12
192.1643372	0.04
193.2226562	0.04
194.3915863	0.03
197.0591125	0.05
198.9535522	0.06
200.2826538	0.03
202.9335632	1.05
203.5971375	0.02
218.1924133	0.06
219.2057495	0.07
220.1964111	0.02
228.0806580	0.05
229.3453674	0.06
235.2115479	0.03
236.8163452	0.06
241.0984497	0.02
244.3285828	0.06
245.3692017	0.02
251.4550171	0.09
254.8921509	0.08
258.2923584	0.12
262.0340576	0.08
262.9310303	0.03
267.9993286	0.06
269.1078491	7.83
271.2293396	0.03
272.3194275	0.79
276.1290283	0.12
283.7010498	0.18
285.1301270	0.49
286.8860779	100.00
287.6172791	0.29
288.6806030	0.02
289.5134888	0.13
291.7348633	0.06
310.5325928	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	811.2302
Annotation	Unknow
Peak:m/z	Relative Intensity
299.3328857	0.12
305.0162964	0.44
329.4436646	0.05
331.1455994	0.03
345.1409912	0.11
346.1374512	0.74
347.1666870	0.14
353.9683228	0.03
361.1456299	12.10
389.3474121	0.03
403.1719971	0.13
406.7588501	0.03
429.7030640	0.02
437.3571167	0.05
449.2597046	0.05
477.2595215	0.04
478.4925537	0.05
503.4418335	0.03
505.0954590	0.19
509.3538208	0.14
515.0885620	0.05
523.1287842	73.08
523.7537842	0.18
537.1928711	0.07
538.3126221	0.19
547.1596680	0.11
551.3740845	0.03
561.2410889	0.10
562.7937012	0.11
565.2182007	37.02
565.8621216	0.13
584.3917236	0.02
591.0848389	0.12
593.4022217	0.09
596.3301392	0.15
605.2507324	7.59
605.8510132	0.05
607.1510010	1.98
607.7633667	0.02
609.2305298	0.15
620.3726807	0.08
627.2224121	0.50
633.2020874	0.06
635.3669434	0.03
647.2746582	1.14
648.1492920	0.12
649.0339966	0.02
652.8220825	0.20
663.0323486	0.07
667.2089844	100.00
681.1375732	0.25
682.2468262	0.05
687.0398560	0.29
689.2490234	0.21
697.7134399	0.03
699.1576538	0.03
709.1043701	14.09
709.7909546	0.20
721.2569580	0.05
725.7119141	0.04
739.4507446	0.26
749.2125854	1.27
750.9274292	0.08
760.3056030	0.16
762.5357056	0.08
767.6283569	0.08
779.1310425	0.06
780.3246460	0.07
781.6754761	0.05
792.4749146	0.02
793.3769531	0.08
795.3902588	0.09
796.1239624	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	488.1619
Annotation	Unknow
Peak:m/z	Relative Intensity
145.9491119	100.00
146.7701721	0.13
161.0545197	0.75
161.8189545	0.59
164.8242798	0.19
166.1347504	0.24
174.0059967	0.58
175.0886078	0.34
179.0390015	2.56
180.0384827	1.16
199.9623718	0.10
214.2363892	0.24
218.0809479	0.15
221.2417908	0.36
222.2164764	0.22
245.2468567	0.09
250.8883667	0.19
252.0828857	0.38
263.9001465	0.76
269.2418213	0.03
280.8895264	0.83
282.0695190	0.29
317.1347656	1.02
321.9209290	0.20
323.1598816	0.40
330.1452332	0.21
340.8555603	2.67
342.1144409	1.23
349.4296265	0.53
356.3940430	0.23
372.2749023	0.28
389.6083374	0.08
399.1119080	0.13
416.3925171	0.07
458.2013550	0.51
462.8890686	0.06
470.0864563	1.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	393.1765
Annotation	cis-3-Hexenyl b-primeveroside
Peak:m/z	Relative Intensity
112.9993896	0.25
143.0643616	0.12
145.0825500	0.07
160.8991394	0.08
174.9412994	0.08
178.9695129	0.29
190.9587708	0.15
223.1853943	0.05
231.3283386	0.12
247.0492554	0.21
249.1846619	0.96
253.0364990	0.08
267.1565857	0.61
269.3551025	0.03
273.0288696	0.08
279.2376709	0.06
306.0971680	0.09
321.4218445	0.09
329.3893433	0.05
333.2266235	0.12
345.0928345	0.02
347.2320557	100.00
349.3791504	0.11
355.0704956	0.10
357.2334900	0.02
375.2247620	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1583
Annotation	Rutine
Peak:m/z	Relative Intensity
183.1234589	0.04
218.9833069	0.03
229.3148041	0.03
230.9181824	0.04
235.6598206	0.02
243.1962738	0.08
247.2559509	0.03
254.5503998	0.02
257.1677246	0.08
258.1111145	0.04
271.3227539	0.02
273.0906067	0.08
274.0568542	0.06
285.0230103	0.16
289.1088562	0.03
303.0517578	100.00
305.3468018	0.01
309.2465515	0.04
311.1136169	0.04
314.0076294	0.07
315.1148682	0.14
326.2000122	0.07
342.9520874	0.04
344.3791504	0.03
345.149292	0.51
368.5670776	0.10
369.3060913	0.11
376.1728516	0.04
386.1771851	0.03
387.4591064	0.07
398.5220947	0.10
399.2633057	0.02
410.3492432	0.13
411.2021484	0.16
413.0639648	0.38
428.2504272	0.06
431.2774048	0.43
432.892395	0.04
441.163208	0.03
446.048584	0.06
447.2567749	1.03
449.0154419	3.09
455.3037109	0.04
463.3496704	0.45
464.9969482	30.96
465.6715698	0.09
467.2064819	0.04
473.1932983	0.21
480.5638428	0.06
489.1177368	0.27
489.9468384	0.04
491.2387695	0.25
507.1054077	0.06
515.0374146	0.03
524.2850952	0.08
525.2814331	0.73
527.3255615	0.11
539.2799072	0.11
544.8702393	0.07
549.3832397	0.03
557.2601929	0.13
566.0601196	0.20
567.2252808	1.49
567.8543701	0.04
575.0419312	0.36
593.164978	0.98
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1241.3773
Annotation	Unknow
Peak:m/z	Relative Intensity
431.1463623	0.17
449.1289062	13.68
455.2989502	0.06
459.2209167	0.12
473.2644653	0.21
477.0307312	0.15
491.2097168	0.28
501.1554871	0.12
531.1037598	0.13
542.9902344	0.09
595.2247314	10.16
626.2613525	0.10
627.0933838	3.64
637.0219727	0.89
645.2543945	0.25
655.4853516	0.13
667.5078125	0.25
669.2462158	0.30
708.8389282	0.18
739.3539429	0.07
757.2060547	11.91
771.2600708	0.52
789.2662964	83.25
799.2661743	0.60
812.6982422	0.45
813.3348389	0.08
831.2178955	26.06
831.8365479	0.07
861.3315430	0.22
871.2904053	7.86
873.2807617	0.81
894.8542480	0.06
915.5200195	0.05
933.1519775	11.83
933.9272461	0.15
935.0246582	0.98
974.9796143	0.12
977.3077393	0.35
1079.4251710	0.77
1095.2297360	0.08
1097.1904300	100.00
1097.8657230	0.61
1139.1738280	22.81
1160.0466310	0.72
1179.2260740	8.00
1181.3232420	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.1577
Annotation	Kaempferol 3-(6''-malonylglucoside)-7-glucoside
Peak:m/z	Relative Intensity
205.0426025	0.08
216.9956970	0.16
231.3659363	0.03
232.6884155	0.04
239.2600403	0.04
245.1468506	0.09
267.9877319	0.07
272.0850525	0.09
286.2916870	0.21
287.3903809	0.06
297.0335083	0.09
316.3847656	0.03
323.3303833	0.08
329.0346069	0.11
332.4195557	0.12
336.2338867	0.04
337.3286743	0.09
341.1140747	0.66
351.0097046	0.33
352.9951172	0.73
354.1026001	0.18
359.2377930	0.10
367.2967529	0.12
369.0709839	0.15
371.0869141	1.75
371.6942139	0.06
373.2275391	0.12
376.7791138	0.03
377.4729004	0.03
383.3338623	0.07
385.1147461	0.16
386.2143555	0.04
388.1898193	1.24
389.2868652	0.45
395.2503662	0.42
407.3114624	0.11
417.1092529	0.08
419.3308716	0.16
421.0757446	0.08
422.2274780	0.04
425.1557617	2.93
431.2606812	0.40
433.2567139	0.07
437.2264404	2.24
438.1893311	0.07
443.2150879	0.11
447.5930176	0.04
449.3201904	0.04
451.2974243	0.10
455.1892700	2.27
456.1801147	0.06
457.2681274	0.11
461.4813843	0.23
462.3153076	0.04
466.2256470	0.02
469.2802124	0.04
473.1384888	48.28
473.7547607	0.14
474.3839111	0.03
475.3074341	0.05
478.9961548	0.08
485.2075195	0.04
487.3566895	0.25
491.1182251	3.23
492.2902832	0.18
493.2648315	0.06
497.2495728	0.14
503.2233887	0.32
503.8619385	0.10
505.1192017	0.45
509.0744629	0.31
511.0388794	0.35
513.3294067	0.09
515.3311157	0.81
516.7043457	0.13
520.8986816	0.26
523.2535400	0.05
527.4685669	0.09
529.0369873	0.84
531.1020508	0.06
532.2943726	0.29
533.2141113	0.49
534.4091187	2.59
535.3413696	0.92
537.1513062	0.09
539.1676636	1.35
541.1968994	0.39
545.4411011	0.06
546.4685669	0.41
547.2247314	0.65
549.1542969	0.08
550.2863159	0.50
551.0189209	0.10
553.1854858	0.07
557.2385254	0.40
559.2299194	6.13
563.3135986	0.42
565.2107544	0.46
567.3226318	0.03
569.3311768	1.19
574.4436646	0.18
577.1350708	27.77
577.7506714	0.07
581.2514038	0.47
583.1626587	4.01
584.0126953	0.02
593.1204224	0.05
594.8430786	0.04
596.2774658	0.35
599.2119141	0.71
601.1526489	7.53
607.1869507	0.02
611.3198853	0.32
613.1350708	15.04
613.7619019	0.07
615.2185669	0.08
617.1965332	1.93
619.3019409	0.13
622.6007080	0.03
625.1381836	5.95
625.7687378	0.07
631.2014771	12.18
635.2765503	0.68
640.2670288	0.10
643.1481934	12.70
643.8385620	0.03
651.0888062	0.58
652.3410034	0.06
653.4318237	0.06
654.2682495	0.19
661.1604614	33.87
662.5645752	0.13
679.1177979	100.00
679.9460449	0.30
680.7787476	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	532.8744
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0055695	0.15
174.9131470	1.23
214.8616333	0.07
244.4198608	0.16
245.0354004	0.03
272.8953247	1.12
289.0167236	13.64
304.9223633	4.63
387.0340576	0.08
403.0204468	7.83
416.8630981	0.10
418.8923340	100.00
419.5059814	0.19
456.8273926	0.07
458.9770508	0.33
487.0328979	0.19
488.9119263	0.05
514.4246826	0.06
522.8816528	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	346.131
Annotation	Unknow
Peak:m/z	Relative Intensity
105.0062256	0.17
108.8949051	0.15
112.1699982	0.04
122.1773834	0.03
126.0296936	0.02
126.8896713	0.06
132.1429443	0.16
136.0926819	0.13
140.6430054	0.06
141.2690582	0.09
142.9451294	0.07
145.1791382	0.09
146.7153168	0.46
158.9613953	0.03
159.8001709	0.04
161.9229889	0.16
162.9015808	0.22
164.9693604	0.04
166.0392914	0.04
169.1441956	0.22
171.1202240	0.06
172.0151825	0.09
175.3008118	0.06
177.2637177	0.06
180.1177979	0.40
180.8799133	0.07
183.0520325	0.05
184.1722107	0.27
184.9525909	0.37
185.9545898	0.09
186.8954315	0.21
189.3586731	0.35
193.2045288	0.05
195.1323242	0.54
198.0220947	0.05
203.1292725	0.04
203.9004211	0.12
205.1685638	0.32
205.9643707	0.02
207.1085663	0.52
210.9570007	0.06
213.0777283	0.02
215.0343628	1.64
216.0761719	0.45
221.2525635	0.32
225.0541992	100.00
226.2676392	0.05
227.2806396	0.42
228.0796814	0.10
229.3324890	0.24
232.1902771	0.14
233.1748047	0.58
236.1832886	0.08
239.1883850	0.29
240.2142639	0.77
241.2994080	0.06
242.1611023	0.44
243.9638367	0.16
246.2956238	0.34
247.1600647	0.12
249.0259094	0.17
251.2595825	0.20
255.4366150	0.07
256.0709534	0.11
257.2376709	0.57
258.1398010	0.57
259.9793701	0.20
261.0560303	0.04
262.1201782	0.14
263.2694702	0.04
267.1386108	0.32
268.0824585	0.09
268.8090210	0.08
272.0738831	0.13
273.5959473	0.56
275.2328491	0.15
276.9864502	0.10
280.2400208	0.27
283.8824463	0.03
285.7275085	0.07
288.2594299	0.08
289.8348694	0.08
292.1563721	1.23
293.2984924	0.42
296.0336914	0.60
297.0366211	0.13
300.7865295	0.33
302.2137146	0.28
303.4480896	0.06
304.1564331	0.06
304.8842163	0.10
308.1051941	0.04
310.1837158	3.10
311.3244324	0.46
316.3186035	0.05
319.2218018	0.17
323.9556885	0.26
324.8777771	0.15
328.3018799	12.20
328.9479980	0.06
332.1857910	0.94
333.9432373	0.19
337.0789795	0.40
345.6005249	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	525.1204
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
156.0739136	0.29
158.0828552	3.97
159.1762085	0.41
169.8792419	0.07
172.0451660	0.18
174.2646179	0.14
190.1302185	0.03
200.0664673	0.93
200.9157715	0.28
202.0735626	7.54
217.9916534	2.58
219.0886536	0.76
223.0978699	0.23
224.3500977	0.05
226.1291504	0.05
244.2757874	0.07
262.0890503	100.00
299.2567139	0.41
321.2098999	0.16
333.1795654	0.28
341.0927124	0.03
349.0973511	0.70
365.1697998	0.07
365.8605957	0.09
367.4800415	0.13
391.4657593	0.02
392.0975952	0.03
393.0277100	0.18
405.0998535	0.10
421.0463257	0.03
427.3629150	0.10
428.9771729	0.08
444.9142456	0.16
447.1062622	0.88
452.7333984	0.03
463.1559448	0.21
465.0598145	5.64
489.2393188	0.07
495.1669922	0.07
507.0488892	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2132
Annotation	Gomisin E
Peak:m/z	Relative Intensity
146.0322723	0.16
157.1583099	0.08
160.9934387	0.05
169.1914673	0.08
194.8015747	0.22
199.1833191	0.06
201.0762482	0.04
205.1204529	0.10
210.2737427	0.16
213.2601013	0.05
214.1298981	0.26
217.2867737	0.27
221.0522461	0.11
227.5322876	0.18
228.9111328	0.20
231.2493286	0.25
235.2988586	0.39
237.3044434	0.08
239.3113403	0.13
240.3054810	0.03
243.2427368	0.21
245.0617065	0.40
251.2694397	0.14
255.0393219	0.05
259.4319458	0.35
261.3311462	0.06
262.4392700	0.06
264.1185913	0.20
266.1630859	0.07
271.1925659	0.56
273.2889404	0.06
275.3427124	0.30
279.4021606	0.37
281.2254028	0.34
285.2126770	0.14
285.9489136	0.24
287.4348145	0.41
289.2828064	1.05
295.5194092	0.20
297.3782043	0.32
299.3446655	0.21
303.3239136	0.23
304.3298950	0.24
309.2713013	0.27
310.3746338	0.14
313.4852295	0.22
315.1278076	0.51
317.3124390	0.40
319.2838135	0.07
320.6558838	0.13
321.3361206	1.31
323.2308350	0.23
325.2634277	0.27
327.3137207	0.14
331.1572876	0.27
333.1604614	2.31
337.3916016	0.14
339.2042236	0.56
341.3336792	1.51
344.2483521	0.14
349.3032227	0.22
351.4082031	0.57
353.2825317	0.32
355.3536377	0.88
361.0961304	0.22
365.2104492	0.08
367.0314331	0.64
369.4264526	0.06
371.5814209	0.14
373.1651611	0.30
375.2927856	0.47
379.3110352	1.46
381.2630005	2.60
383.1448364	1.09
384.2730713	0.11
389.4218140	0.72
393.5417480	0.31
395.5032959	0.06
397.3319702	1.14
399.2606201	4.66
407.3328247	0.43
409.5366821	0.33
413.3297119	0.12
416.2672729	0.60
419.3779297	1.26
421.4400635	0.11
423.2804565	0.50
424.4275513	0.33
427.2182007	0.07
433.4461060	0.56
436.2796631	0.10
437.3530273	0.64
441.2084961	2.05
449.2403564	0.40
451.3585815	3.09
453.2238770	4.61
453.8505249	0.32
455.3031616	1.85
457.4944458	0.15
458.9927979	0.34
467.1874390	0.39
471.3463745	0.14
476.2377930	0.08
477.4522705	1.03
478.3988647	0.35
485.3474121	100.00
486.2383423	0.06
495.3018188	16.64
496.2041626	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1141
Annotation	Lactulose
Peak:m/z	Relative Intensity
161.0523071	0.08
175.1622620	0.02
190.6899109	0.03
195.1242371	0.03
244.9286804	0.04
283.2583008	0.08
297.2223511	0.13
299.0237732	0.06
307.5114746	0.02
324.8921509	0.04
326.9583130	0.03
341.1462708	100.00
343.1577759	0.13
359.4239807	0.03
368.9877930	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1683
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
271.1519165	16.66
313.1777649	0.10
337.4754028	0.11
381.2398682	0.12
399.3555908	0.19
415.3858643	0.12
417.1152344	1.13
417.7221069	0.07
433.0566406	100.00
433.6716309	0.21
441.0317993	0.13
542.8663330	0.02
561.1248169	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.04
Annotation	Unknow
Peak:m/z	Relative Intensity
108.8832779	0.37
139.0936584	0.05
155.0645447	0.36
157.2039337	0.39
173.2074738	0.12
175.1918640	0.45
176.5119629	0.16
183.2265015	0.20
191.2514343	0.03
201.0779114	0.12
210.9081726	1.08
212.9220581	13.17
217.0133362	0.05
221.2122192	0.09
222.9908447	0.25
228.9520874	0.25
233.2969055	0.16
237.1013489	0.05
237.9500732	0.12
239.3200989	0.08
251.0015259	100.00
253.2016296	0.21
255.0187378	0.85
261.2654724	0.48
269.1763916	0.17
276.8857727	0.06
278.6180420	0.48
279.2451172	2.07
280.0336914	0.09
281.0786743	0.77
282.5754700	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
177.0287781	0.67
208.9295349	0.03
210.9182129	0.07
237.2635345	0.03
257.4222412	0.02
258.0438232	0.10
261.1131592	0.05
264.8226624	0.13
271.1365662	1.93
286.0872803	1.02
291.3657837	0.45
295.375	0.30
297.8081665	0.07
301.0903931	37.12
303.2438965	0.29
304.1849365	0.10
309.1503296	0.32
313.18927	4.67
317.4971313	0.05
325.3343506	0.08
334.887207	0.20
340.1876221	0.05
343.2380371	0.85
355.1867065	0.05
361.2769775	0.37
367.3361206	0.29
377.1501465	0.46
379.232666	0.13
397.1315918	0.27
401.2839355	0.05
409.208252	0.04
411.5411987	0.17
414.3086548	0.07
416.8776245	0.13
419.1603394	0.03
423.5664673	0.05
429.1765747	0.34
432.6503906	0.32
433.3180542	0.64
445.2333374	0.82
447.0076294	0.55
463.132019	100.00
464.8762207	0.12
469.9924316	0.03
479.600708	0.09
483.125061	0.15
485.2763062	0.01
487.3859253	0.06
489.288269	0.30
505.2526855	0.11
506.7709351	0.14
537.2475586	0.05
543.1640625	0.03
547.1762085	0.03
549.1553955	0.25
555.1659546	0.53
565.3377075	0.38
573.0053101	0.50
577.2675171	0.16
591.2155151	2.52
591.8408813	0.02
598.0621948	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
191.096344	0.21
196.2575989	0.16
198.9732666	1.05
200.1943817	0.57
200.9989929	0.30
202.2400055	0.44
215.0675659	0.45
219.2494965	0.23
224.1559143	0.35
227.1015167	1.06
242.260437	0.40
250.9183197	0.79
254.9958191	0.48
258.1857605	0.71
268.2723389	0.27
271.0300293	0.33
283.0753784	0.36
284.3249512	0.78
285.2381897	1.20
286.2146606	1.04
294.9494019	0.46
298.9586182	2.61
301.0805664	100.00
302.0980225	1.78
325.2119751	1.78
337.31427	0.56
343.0792847	1.24
345.1973267	0.65
356.1242065	0.39
369.2412109	1.08
399.0531616	0.63
413.4891968	0.39
476.684021	0.18
487.2304688	0.34
489.2783203	19.14
490.1334229	0.88
491.2684937	0.18
512.7662964	0.71
517.4092407	0.20
519.2955322	0.96
524.984314	0.25
531.7136841	0.70
549.3125	0.45
555.3563843	1.12
565.1829224	3.06
571.1781616	0.37
573.4337769	0.33
577.4387207	0.95
589.5912476	0.47
591.5196533	6.02
592.5354614	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.1273
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
126.0505600	0.34
134.2708130	0.08
177.1138916	0.02
187.2080078	0.01
215.1891479	0.08
218.0410156	0.04
225.1758423	0.11
226.4286804	0.08
228.9555969	0.16
231.0263367	31.09
233.0200806	100.00
234.0959778	0.05
245.2166138	0.11
247.2827454	0.09
249.0519104	0.02
256.9658813	0.33
259.1778564	0.13
260.0892334	0.03
262.1636658	0.01
271.2756042	0.66
273.0394287	0.13
287.1683655	0.22
299.0909424	20.75
317.0184326	43.12
317.6980591	0.20
318.3161621	0.12
330.4772034	0.09
340.2359924	0.44
348.9410400	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1247
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
139.1278839	0.73
147.1669006	0.19
149.0200500	17.23
151.0483246	0.32
159.0255737	0.26
160.8391876	1.31
163.2435303	0.33
167.1272583	2.04
173.1893616	0.46
175.4154358	0.94
177.0843964	0.89
178.9996643	3.50
191.0018921	6.91
193.0179443	4.65
201.0842133	0.18
202.3676605	0.58
217.1104126	1.95
218.9937592	0.41
221.1735077	1.36
231.1762085	0.90
235.0201874	11.61
251.3164978	1.94
261.1590271	1.22
263.2708130	0.96
265.1463318	3.53
277.1675415	2.32
283.2080688	0.55
295.1165771	42.08
299.9949341	0.55
301.2075500	4.86
323.1116943	24.89
323.7948914	0.28
337.2033081	100.00
341.0710754	4.82
343.0618591	19.42
354.1129150	0.22
371.0075684	0.68
373.1430969	1.51
400.7996826	0.74
403.1313782	0.49
414.9944153	0.72
419.1993713	0.41
427.1436157	0.19
444.9443665	0.70
445.5597229	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.0914
Annotation	Paederosidic acid
Peak:m/z	Relative Intensity
133.0010681	0.07
135.0043182	0.27
136.0983582	0.07
137.0896759	0.41
143.1702576	0.17
146.0154572	0.08
146.9912872	0.15
148.8971863	0.69
152.9708862	1.20
158.1347809	0.13
160.1639709	0.15
161.0961609	0.47
163.0215454	1.49
164.9567261	6.14
165.9110107	0.07
166.9643555	0.05
171.4047089	0.07
179.1852417	0.22
182.3804016	0.06
185.1513672	0.09
186.9887085	0.98
188.9132080	3.55
190.0210266	0.92
199.0211792	0.31
205.0369873	0.61
206.5407715	0.33
207.1494751	4.75
207.8658142	0.43
208.9762878	0.25
210.8785095	0.03
212.9937897	0.15
215.2247925	0.45
222.9287109	0.06
223.9579163	2.01
225.0839691	8.33
226.0503082	0.08
227.1299591	0.59
230.8832245	0.09
242.1795044	0.08
243.4305725	0.04
253.2343750	0.04
255.1186829	0.37
263.0040588	0.20
269.2809143	0.08
271.0856628	1.47
281.1262817	1.73
282.1502991	0.07
285.0495911	0.05
287.1928406	0.09
291.3166504	0.03
293.4270630	0.29
299.0801086	100.00
300.1560364	7.19
301.0011902	0.18
309.2783203	0.15
311.2822571	0.10
317.0377502	36.42
318.1622009	1.92
335.0710449	0.18
339.2814026	0.06
353.3266602	0.19
367.1419067	0.14
371.1302795	11.15
372.1953125	1.02
375.1362610	0.10
417.4411926	0.31
419.5070801	0.41
427.3687439	0.46
435.6100769	0.12
445.2335510	1.65
446.2295532	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	597.1459
Annotation	Unknow
Peak:m/z	Relative Intensity
166.8337708	0.06
170.1256561	0.04
177.0406952	0.55
191.1349182	0.33
193.1509094	0.17
197.0357056	0.16
199.1090698	0.07
204.8654480	0.07
206.1352234	0.06
209.0729218	0.07
217.1296997	0.83
219.1291046	0.30
221.1306152	0.04
223.3574982	0.08
227.3851624	0.12
229.1510620	0.04
231.2754974	0.03
233.8828888	0.19
235.1249847	2.18
241.2593689	0.08
245.1157837	0.14
247.0501404	0.13
249.2785339	0.03
265.1778564	1.23
269.1412659	0.45
273.1731567	0.07
275.2207031	0.05
287.0845947	0.10
289.1358643	0.31
291.0096436	0.83
291.6692505	0.16
299.1767578	15.18
300.2651978	0.12
301.1997681	0.27
303.1994934	0.14
309.0802307	0.25
310.3312378	0.08
319.0733643	0.05
321.3895264	0.04
327.1812134	1.11
336.0039062	0.18
337.1831055	3.23
339.2177124	0.06
341.0703735	0.08
345.1406250	49.27
347.1735840	0.39
355.2569580	1.08
357.1967773	0.79
359.1018677	0.20
367.0892944	34.25
367.9444580	0.09
373.1536865	0.08
375.2078247	9.54
379.3128662	0.10
380.9114990	0.12
385.2011108	0.05
387.1730957	1.10
395.4540405	0.11
397.3323364	0.23
401.2073975	1.31
405.2891235	0.49
411.2982788	0.26
416.8884888	0.09
419.1655273	22.81
423.6031494	0.04
429.2667847	0.69
431.0158691	0.09
432.1719360	0.09
433.2663574	0.11
435.3269653	0.14
438.5940552	0.06
443.2556763	0.14
447.2960815	3.21
449.1054688	0.15
451.2379761	0.07
453.1170044	1.33
459.3222656	1.87
461.1531372	2.00
463.4640503	0.04
465.2213135	3.95
466.3546753	0.10
467.3550415	0.27
469.0842896	0.66
472.9088745	0.05
473.6778564	0.09
477.1526489	97.02
477.7581177	0.20
482.4462891	0.09
487.1417236	100.00
487.7623291	0.33
495.1779175	0.08
501.2426758	0.14
502.9839478	0.03
507.3418579	0.29
520.9302979	0.25
523.4152832	0.06
535.1997681	0.35
535.8268433	0.14
537.3391724	0.12
551.5303955	0.17
552.5100708	0.40
553.2868042	0.49
561.6060181	0.06
563.1267090	0.09
567.3268433	0.14
579.2948608	6.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	458.77
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8622437	14.68
212.8014679	0.44
260.3283386	0.16
290.8097229	100.00
296.7228088	0.09
311.0194092	0.07
338.9248657	0.39
348.3125916	0.14
367.9726257	0.03
374.7034302	24.33
398.7893982	2.78
412.8262939	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	795.472
Annotation	Unknow
Peak:m/z	Relative Intensity
232.8839111	0.15
234.7619476	0.18
238.9628754	0.15
245.0708466	0.89
249.2983093	0.17
251.1849976	0.25
262.4000549	0.17
268.2135620	0.38
277.2733154	0.22
278.8075867	0.24
283.7409973	0.20
285.2242737	0.05
289.5567932	0.25
293.4242859	0.18
295.2514648	0.27
296.1560974	1.15
301.3449707	0.23
302.3098450	1.19
303.3418579	0.16
304.9349670	0.31
306.7941284	0.65
307.6650085	0.06
312.0757446	0.29
313.2422485	0.60
314.2286682	0.92
324.1756287	0.12
325.3598938	0.53
330.1094971	1.05
331.4062500	0.28
342.2260132	19.38
346.8744507	0.12
354.2105103	0.15
357.2181396	0.36
359.3778076	1.24
360.2547913	0.23
371.1102295	2.01
378.8760986	0.09
381.5497437	0.40
382.1989136	0.13
383.5883789	0.11
388.4235840	0.04
397.2476807	0.33
399.2695312	8.66
409.4536743	0.25
415.4461060	0.16
416.1275024	0.24
420.6049194	0.38
422.2434082	0.19
426.4481812	1.76
427.3477173	0.18
428.1978760	0.31
436.3142090	0.42
437.1328735	0.12
438.2893066	0.28
439.0942993	0.08
440.3403320	1.50
443.2225342	1.97
444.1864014	0.85
454.3302612	1.30
455.4852295	1.73
456.3088989	6.15
458.0410156	0.10
459.4579468	0.13
460.2063599	0.16
470.5321655	0.25
471.8687134	0.88
472.4813843	2.27
473.4386597	9.46
482.2090454	0.06
489.1738892	0.25
498.4095459	0.26
500.3255615	0.23
506.3313599	0.27
510.5437012	0.15
512.2340088	0.87
523.5870361	0.42
524.3720093	0.14
525.5991821	0.34
528.4605103	0.49
534.2835693	0.32
535.3684692	0.31
541.3908691	9.37
542.0321655	0.22
551.2869873	1.66
552.3629150	0.23
553.4063110	0.96
554.1287842	0.07
556.1015625	2.04
557.3645020	1.81
568.0984497	0.56
569.4158325	35.59
573.6251831	0.38
577.5545044	0.18
579.1771851	0.22
580.4049072	0.42
583.3583374	1.10
585.4389038	3.31
586.5289917	0.48
591.2684326	0.14
595.5480347	0.18
596.3372192	0.08
597.1709595	0.45
601.3853149	1.12
620.4589233	0.04
625.4346313	0.76
636.8615112	0.55
637.6338501	0.31
638.5685425	0.22
646.2306519	0.14
647.2712402	0.51
648.7123413	0.33
649.5004272	0.10
654.5033569	6.44
664.4405518	5.14
665.8286743	0.44
666.5321045	3.16
668.7217407	0.21
670.5565186	2.51
680.5602417	2.91
682.3828735	99.93
683.1190796	0.08
692.2246094	1.07
692.9412842	0.24
693.5900879	0.25
696.5521240	0.46
698.4450684	10.06
703.1069946	0.06
708.2070923	0.11
710.1746826	0.04
720.4548950	0.21
722.6635132	0.47
726.4498291	0.64
733.4257812	0.32
738.3264771	2.82
748.3696289	0.24
749.6459961	1.42
750.3414917	6.47
751.4628296	3.29
759.7788696	0.78
767.5001831	100.00
768.1857910	0.69
777.5824585	47.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	380.1693
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
115.2855530	0.02
121.1825180	0.02
123.1185608	0.03
127.0453873	0.02
142.9906006	0.04
151.1090698	0.01
180.0614624	0.02
202.8949585	0.02
213.0542603	0.01
222.8536072	0.05
231.0455322	0.18
233.0980530	1.75
256.0208130	0.02
276.2634888	0.02
289.0812988	0.03
293.1900635	0.01
295.3424072	0.02
299.1121826	9.27
304.3515625	0.01
306.3455811	0.01
307.2728271	0.01
308.0738220	0.04
313.0583496	0.03
316.9880371	100.00
317.6787720	0.17
319.2912598	0.04
333.9763794	0.01
336.2084351	0.01
344.1381226	0.04
348.3022461	3.80
348.9820251	20.68
352.1852722	0.09
353.2167053	0.10
358.9301147	0.06
362.3036804	0.16
363.2204285	0.06
368.9119873	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.2449
Annotation	Unknow
Peak:m/z	Relative Intensity
202.1265259	0.21
203.2506866	0.04
205.0385132	0.15
211.4452057	0.09
216.9634094	1.04
218.9780273	0.08
233.2136688	0.41
235.0131683	0.44
242.1628113	0.08
245.0850525	0.22
247.1480713	0.22
249.2514954	0.11
250.3633575	0.05
252.3497620	0.03
262.1984253	0.09
264.9205933	0.10
273.5046387	0.05
277.1585083	0.89
282.5035400	0.09
284.4684448	0.06
287.1492920	0.33
297.1744385	0.06
301.3905945	0.08
304.2406616	0.14
305.0316162	0.05
310.7656555	0.17
312.1178284	0.14
313.4057007	0.04
315.2139893	0.08
316.4821777	0.06
322.2263184	0.09
323.1668701	0.36
325.0616455	0.25
327.1025085	0.99
329.0869446	0.04
331.1167908	0.31
333.2310181	0.09
335.3839722	0.06
337.1994934	100.00
338.4576416	0.06
343.0051880	0.04
345.0602417	0.14
356.9624023	0.16
364.4038086	0.04
367.2309570	0.31
370.1979980	0.14
372.2447510	0.03
374.3594971	0.22
376.2243652	0.06
378.7942505	0.21
381.8521118	0.09
383.1286621	0.04
391.5209961	0.06
398.5120850	0.07
400.2625122	0.21
401.2150879	1.41
402.3779907	0.25
409.4820557	0.09
410.3031006	0.07
417.6683350	0.07
418.3593140	0.04
420.2542725	0.25
423.2205811	0.04
425.0554199	0.04
426.3298340	0.04
427.2373657	0.09
428.4044189	0.12
431.1660156	0.12
436.9784546	0.06
443.2672729	0.10
444.2523193	0.62
445.3402710	0.23
446.4005127	0.08
454.1679077	0.54
455.0845947	0.10
456.2274780	0.05
459.4255981	0.08
465.3576050	0.19
473.4105835	0.08
475.4926147	0.14
486.3501587	0.22
486.9817505	0.10
489.2171021	1.64
490.3007812	0.05
503.1750488	0.62
504.5284424	0.02
509.2560425	0.12
515.4318237	0.20
517.0882568	0.04
520.2715454	0.21
524.2922363	0.27
525.3920288	0.17
533.1865845	30.38
533.8425903	0.04
534.5348511	0.06
535.1740112	0.07
537.2839355	0.51
538.3933105	0.06
545.1400146	0.04
547.3029175	0.36
550.0233765	0.14
551.1307983	1.61
559.3518677	0.48
562.2813110	0.32
563.3617554	17.10
564.0671387	0.07
565.4657593	0.15
566.9761963	0.52
568.4649658	0.35
569.8496704	0.11
577.2564697	0.22
578.5970459	0.04
581.2238770	1.96
586.1714478	0.08
589.1196899	0.35
592.4924927	0.33
593.3704224	0.15
606.1554565	0.54
607.4744263	0.88
608.4024048	2.03
609.4274292	0.85
615.2111816	0.11
617.2148438	0.51
621.6228638	0.06
623.2179565	3.35
624.2633667	0.39
625.3197632	0.87
626.3358765	1.01
631.7301636	0.15
640.0992432	0.42
644.0744019	0.11
649.5416870	0.12
652.2937012	1.44
653.4221802	0.36
664.3358765	0.56
665.4552612	0.04
666.4598389	0.39
667.3320312	0.36
668.4031372	0.42
669.3307495	0.64
673.1892700	0.04
683.2925415	3.51
688.6062622	0.30
692.8082275	0.06
695.1630859	5.47
698.4281006	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	592.1464
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1279602	0.04
200.8135681	0.04
201.9355164	0.11
209.4099731	0.02
215.1332397	0.03
227.1015320	0.06
232.9038696	0.07
234.2275085	0.06
244.1412048	0.05
260.1170044	0.04
264.1162109	0.10
269.3872070	0.06
270.2478027	0.07
271.2347107	0.08
274.1112061	0.11
274.9900208	0.05
276.0050049	0.12
284.9545898	0.06
287.2049561	1.27
288.0004272	0.08
289.2474670	0.06
300.0281372	0.05
301.0440369	0.03
306.1302490	2.12
314.4011230	0.22
315.4435120	0.07
319.4643555	0.02
323.2731934	0.03
325.1248169	0.75
326.2078857	0.19
336.0256958	0.05
339.1280518	0.03
342.8583984	0.27
364.7583008	0.46
368.2908936	0.03
381.2089844	0.03
400.1330566	0.03
407.0825806	1.21
407.9173584	0.45
408.8605957	0.02
414.0205078	0.16
414.6460571	0.18
415.5881958	0.26
417.1818848	0.13
418.6624146	0.06
421.7210083	0.05
427.5092773	0.14
440.6353149	0.13
449.3577271	100.00
450.2585449	4.29
452.0798340	0.25
453.1381836	0.05
454.1303711	0.05
456.5042725	0.24
457.9003906	4.94
458.6449585	4.86
459.4757080	2.21
460.3723755	1.54
461.2385254	0.46
461.9696655	0.28
463.0072021	0.24
464.0815430	0.66
464.8995361	0.71
465.6144409	0.34
466.7739868	0.21
469.4883423	2.78
470.2690430	0.06
472.2889404	0.04
476.9554443	0.03
527.0823975	0.13
528.4952393	0.18
529.7247925	0.08
541.2363281	0.19
542.0225220	0.28
545.6705933	0.08
550.2668457	0.43
551.9674072	0.03
556.3492432	0.02
564.1747437	0.03
567.1347046	0.03
574.2739868	0.24
575.0784302	0.03
592.2601929	0.22
593.0429688	0.18
611.1458130	0.83
612.0592651	0.54
613.2462769	0.02
629.0933228	0.06
631.5521851	0.02
735.9115601	0.06
813.2752075	0.07
828.3309937	0.08
905.2194824	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.1557
Annotation	Gonocaryoside B
Peak:m/z	Relative Intensity
163.3364410	0.05
181.0399170	3.24
253.3002930	0.10
301.2177124	0.03
329.2929688	0.09
341.1016846	0.18
343.1681213	100.00
375.1794434	0.07
405.1427002	0.05
416.8776550	0.04
418.8827820	0.04
441.3899231	0.13
460.2444763	0.12
461.0961609	0.20
487.1482544	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	616.38
Annotation	Unknow
Peak:m/z	Relative Intensity
175.0467682	0.21
176.9780273	0.02
203.1208344	0.16
216.0595856	0.05
217.0622406	0.13
218.0241852	0.49
229.0861053	0.05
231.0512695	4.35
233.0122681	2.95
234.0705566	0.04
235.3444519	0.10
238.1304779	0.03
239.3426971	0.02
240.4183044	0.30
244.0326233	0.05
252.2742310	0.32
254.3640747	0.96
256.5382080	0.18
257.2593994	0.10
259.8616943	0.03
260.7603760	0.05
262.4066772	0.06
264.3760986	0.80
265.3667603	0.19
270.2811890	7.03
271.2060547	0.11
282.2720947	3.95
283.0714111	0.16
286.8749084	0.08
299.1516113	2.38
300.2773438	100.00
300.9336548	0.22
309.6282349	0.04
317.0319214	2.99
317.9649353	0.09
318.9165649	0.05
358.3099365	0.10
359.2938232	0.04
383.0910034	0.03
385.3004150	0.10
390.6519165	0.05
393.2056274	0.02
409.7718506	0.02
444.0403442	0.02
448.3800049	0.01
478.4351196	0.09
484.4983521	0.08
498.9631958	0.02
503.2896118	0.10
506.3373413	0.02
512.2539673	0.11
514.2310791	0.11
523.3571167	0.04
528.8581543	0.01
532.2360229	0.04
543.2902222	0.02
555.2423706	0.04
569.9909058	0.03
572.3545532	0.08
580.4838867	0.04
584.2017822	0.01
587.3962402	0.05
598.2191772	0.15
606.5177612	0.02
609.9450073	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	385.17
Annotation	Isomitraphylline N-oxide
Peak:m/z	Relative Intensity
117.0017471	0.19
134.9177399	0.09
136.2003326	0.29
140.9754944	0.07
144.9421844	0.09
148.9254456	0.24
151.0609741	0.14
153.0258789	0.38
161.0571289	0.54
164.9641876	0.08
167.1196594	0.36
175.2137604	0.05
180.9142151	0.09
187.0753784	0.06
199.4801636	0.38
205.0614014	0.08
213.0000610	0.47
215.2408752	0.10
218.8436890	0.13
223.1700745	0.85
225.1299133	0.05
227.1334534	0.13
233.0490417	3.21
234.3685303	0.21
243.0365601	0.06
247.1474915	0.20
253.8831177	0.29
255.2760010	0.50
258.6316528	0.05
261.0887756	0.24
267.2725830	0.09
268.4618530	0.18
271.3068542	0.25
281.1103210	0.13
284.0585327	0.06
290.8562317	0.25
297.3126526	0.09
299.0071411	0.12
301.0838928	100.00
305.1067505	0.12
307.3818359	0.40
310.0044861	0.44
311.1525269	0.44
313.4270935	0.24
316.9526978	1.84
323.5106506	0.35
324.2799072	1.04
325.2531433	0.61
327.1917725	0.53
329.2731323	0.07
333.4165039	0.69
334.7510376	0.14
339.1420898	0.21
340.1980591	0.18
341.1116333	0.34
343.9905090	0.74
348.8243713	0.85
350.7155762	0.48
354.3608093	0.14
357.3859558	0.21
358.2701111	0.09
365.3301392	0.06
367.2468262	4.32
368.1808167	0.43
376.4844055	0.93
386.6008911	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	873.3387
Annotation	Unknow
Peak:m/z	Relative Intensity
301.3859253	0.10
317.1754456	0.13
322.8699951	0.02
324.3055115	0.09
331.0619507	0.08
343.1220093	0.17
351.1408081	0.05
360.3311768	0.03
377.4287109	0.05
395.3917847	0.15
401.3862305	0.10
423.0600586	0.10
427.3310547	0.25
445.4908447	0.31
451.3048706	0.08
473.2191162	0.03
477.2396851	0.04
479.4100342	0.07
507.2356567	0.10
537.2184448	0.28
545.3327637	0.05
575.1937256	0.05
579.3939819	0.08
584.9033203	0.26
589.1986694	0.98
593.6766968	0.16
603.4097290	0.18
607.4122925	14.44
609.7042847	0.12
619.1436768	0.05
621.3546753	0.43
623.3906860	0.19
625.6192017	0.10
631.2705688	0.75
633.2843628	10.52
649.4371948	0.56
651.3622437	21.18
661.4467163	0.06
665.4419556	0.06
669.4209595	0.58
675.1955566	0.44
681.1331787	1.86
681.7620239	0.05
693.4023438	14.82
705.0563354	0.10
707.2517700	0.08
709.1038208	0.08
711.3719482	43.46
717.5055542	0.04
723.3625488	17.10
731.5376587	0.07
735.3790894	0.44
747.4625244	0.05
753.2536621	41.38
759.2926636	0.10
765.3927612	0.11
777.3912964	1.29
783.3393555	13.50
795.3959351	7.61
807.1828613	0.06
813.3590088	100.00
819.2205200	0.11
837.2584229	0.94
843.3667603	0.35
854.6666870	0.18
855.3518677	3.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	641.1716
Annotation	Butrin
Peak:m/z	Relative Intensity
181.1751709	0.12
191.2175446	0.39
209.1175232	4.14
210.0183258	3.85
221.9040375	0.18
223.1512451	0.19
225.1026154	0.14
239.0798187	6.14
240.0963135	2.43
251.0396423	0.17
251.8543396	0.12
260.0436707	0.11
269.0910034	2.58
270.0903320	2.11
281.2743530	0.37
282.1357117	0.23
293.0204163	0.65
294.0741577	0.58
305.6698608	0.32
311.0318604	2.58
312.2550964	2.80
316.1182251	0.09
324.0993042	0.31
329.1081543	6.08
330.2387085	5.99
336.2342529	0.06
341.1415405	1.60
342.1463013	2.18
354.2269897	0.03
359.1198730	1.98
360.1915283	0.45
383.1953735	0.24
384.4131470	0.22
388.4995728	0.16
390.1575317	0.15
399.3421021	0.22
401.1159668	23.36
402.0611572	59.85
403.7422485	0.41
413.3173218	0.64
414.0943604	1.73
426.3800049	0.15
431.2984619	22.27
432.2704468	39.99
434.3621826	0.18
441.6812134	0.06
442.4073486	0.37
443.0534668	0.11
444.1362915	1.81
447.3169556	0.16
449.2257080	5.12
450.3312378	7.70
456.3471680	0.06
460.9298706	3.71
462.1840820	19.50
468.3605957	0.66
474.2872925	0.36
486.2810059	0.46
487.1212158	0.27
491.3651733	0.60
492.2625122	0.66
502.1606445	0.23
503.2741699	4.29
504.2330933	20.77
515.1589355	0.07
516.1402588	1.33
521.1796265	17.82
522.1222534	100.00
522.7813110	0.22
533.0532227	2.41
534.1637573	17.43
534.8361816	0.04
546.4265747	1.25
551.2984619	1.29
552.1657104	11.80
552.7871094	0.16
556.0301514	0.08
563.2687988	0.09
564.2316895	0.34
582.3425293	0.21
588.2918091	0.60
594.8240967	0.12
596.0779419	0.08
606.2398071	4.27
624.2454224	29.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	362.25
Annotation	Broussonetine F
Peak:m/z	Relative Intensity
102.7750549	0.04
104.7342072	0.18
108.0866623	0.07
113.9727631	0.05
115.8356781	0.10
117.0045090	0.04
120.8120575	0.29
127.0840759	0.03
130.1508484	0.19
131.0715485	0.12
135.1737366	0.19
136.2226257	0.14
136.9721069	0.09
137.8738708	0.05
139.0989990	0.22
140.9792175	0.12
145.1438446	0.08
147.0041504	0.63
148.9277496	0.25
152.0538025	0.09
153.9899597	0.90
155.1620483	0.24
157.0246887	0.26
159.2608185	0.16
160.1582794	0.06
161.0903625	0.36
161.9013977	0.05
164.7018433	0.15
167.1897888	0.04
170.0164795	0.17
170.9508972	0.15
172.1073303	0.05
173.1342468	0.24
174.2586670	0.07
183.9630890	0.13
187.9976807	0.22
192.1226959	0.20
196.2232666	0.15
197.1921234	0.26
197.8032837	0.12
199.0999146	0.12
201.1132202	0.30
203.0229492	0.17
209.1931458	0.40
210.1228180	0.32
210.8277893	0.29
213.1151428	0.25
214.9785767	0.12
216.2080383	0.33
217.1939087	0.06
218.0804138	0.04
222.1763916	0.12
224.8175049	0.08
228.0818787	3.13
231.0610352	0.08
232.3956604	0.09
236.0954285	0.07
237.0583801	0.06
242.0525818	0.04
244.9546814	0.10
246.2313232	0.11
249.1435852	0.42
253.0014038	0.09
254.1985168	0.15
255.2256165	0.19
256.3897095	0.04
259.4060669	0.16
260.0310059	0.53
272.2928162	0.17
273.2149658	0.64
275.2412415	0.38
277.1770020	0.18
278.4025879	0.16
279.8688049	0.04
285.2455444	0.11
288.1837463	0.19
290.2769775	0.45
291.2711792	0.72
292.2929688	0.31
295.1763306	0.40
299.1582336	0.24
308.3510132	1.03
309.2994690	1.28
314.0388184	0.04
316.0909424	1.44
319.1613159	0.54
321.1159058	0.30
323.1084595	0.06
324.6192017	0.20
326.2831421	12.18
327.4454956	0.27
330.0321350	0.19
331.7657166	0.31
334.0947571	0.09
335.0083923	0.11
336.2433472	0.03
344.2476501	100.00
345.1929626	0.17
352.8761292	0.39
354.4789124	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.1976
Annotation	Faratroside
Peak:m/z	Relative Intensity
269.0388794	0.02
286.0608826	0.05
287.1464844	0.11
288.2563477	0.05
301.2039795	0.02
302.9939575	0.09
305.0261841	0.10
315.3869019	0.18
316.2995605	0.02
330.1981812	0.60
331.1676025	0.67
340.6654663	0.01
345.1524658	3.63
346.1901855	3.22
347.0047607	0.07
449.2573853	0.04
490.2792358	0.14
502.3254395	0.08
507.1715698	12.65
508.1781006	23.91
508.8687744	0.11
535.4061890	0.11
536.2055054	0.21
549.1776733	6.01
550.2552490	15.09
578.1311646	0.06
589.1871338	1.91
590.1669312	5.42
591.2283936	0.20
592.2346191	0.90
631.2958374	0.10
632.3483887	1.34
633.1826782	0.08
634.2955933	0.20
651.2598877	25.76
652.1757202	100.00
652.8418579	0.19
693.4724731	3.17
694.1521606	9.08
694.7558594	0.04
704.3075562	0.05
710.1738892	0.03
724.2675171	0.02
733.3330688	0.51
734.1774292	2.37
735.7415161	0.07
778.3883667	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	241.1539
Annotation	Pirbuterol
Peak:m/z	Relative Intensity
69.9482117	1.73
81.0551300	0.55
82.0721741	0.17
82.8726273	0.05
83.9040375	24.85
85.0682297	1.56
86.9742126	0.21
90.9335632	0.13
93.0556946	0.04
94.9622192	0.30
96.1146088	0.10
97.0155335	0.30
98.0039368	4.36
99.0363770	0.09
100.0306091	1.37
105.0929413	0.02
107.1210327	0.15
109.1240082	0.17
110.8616333	0.38
112.7831116	0.12
114.0216370	0.48
115.9324341	1.02
116.7097321	0.12
119.0494080	0.14
121.2536011	0.09
123.2083893	0.06
124.0653992	0.40
125.0316467	0.26
126.0090637	3.33
126.9477386	0.51
128.0685883	35.97
129.0140991	0.48
129.9844666	0.09
131.0948029	0.14
132.8386993	0.03
135.1651611	0.06
136.8536072	0.04
139.2590485	0.09
140.7996979	0.19
141.4155121	0.03
144.0758209	17.69
145.0440216	0.05
147.1097565	0.03
148.9962311	0.05
150.1188660	0.73
152.0626373	1.53
152.8814697	0.07
154.9313049	0.08
158.1250153	1.57
158.8703156	0.26
160.9290771	0.06
162.8645325	0.04
164.2186432	0.06
164.9433594	0.19
167.5151978	0.12
168.1289520	3.30
169.0172424	0.04
170.8645935	0.11
171.9790192	0.14
177.2214966	0.13
178.1498260	0.09
179.3035126	0.35
180.9757080	0.58
183.2991333	0.09
185.1581879	0.05
186.8641205	0.14
189.0984192	0.07
193.0215912	0.11
193.8799591	0.04
196.0230408	100.00
197.0896912	0.96
198.1559906	0.98
199.0423279	1.56
199.9956818	1.56
203.0470886	0.11
205.0702515	1.35
206.1112671	0.02
211.0984344	0.17
212.2065277	0.17
213.1543884	6.21
214.2771149	0.19
217.4452972	0.30
218.3128662	0.44
220.4306488	0.35
223.0944672	5.41
224.1479645	0.69
225.2393036	0.23
226.2500153	0.04
232.3484955	0.43
241.1147003	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1559
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
175.0601349	0.03
181.5561523	0.05
183.0599365	0.04
190.2940979	0.04
195.2352905	0.03
196.1947632	0.08
197.2462769	0.01
199.1637878	0.05
201.1669159	0.05
210.1071320	0.01
213.2976227	0.04
224.2556763	0.03
225.1500244	0.24
267.4837646	0.01
269.0570679	100.00
269.8387756	0.03
310.9920044	0.36
352.9551392	0.03
489.2310181	0.03
491.0776978	0.03
499.3158569	0.03
523.1531372	0.02
533.2465210	0.06
558.0812988	0.09
559.2754517	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	383.1193
Annotation	Quinic acid
Peak:m/z	Relative Intensity
107.7250214	0.03
111.3082352	0.07
127.0178452	0.11
144.8323669	0.02
155.2155914	0.02
171.1647644	0.04
173.1742859	0.39
191.0384216	100.00
191.8491058	0.02
235.0802612	0.03
248.9567871	0.05
307.0418091	0.02
309.1342163	0.01
311.8288269	0.03
347.1980896	0.03
368.2393799	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	693.2754
Annotation	Nomilinic acid 17-glucoside
Peak:m/z	Relative Intensity
197.1840057	0.22
206.1919708	0.91
207.3300476	0.71
211.3001099	0.62
213.2106628	4.36
214.2775269	0.66
217.0830231	0.18
220.9498901	1.86
222.2337646	0.57
225.2580261	0.23
226.3450775	0.39
228.3280945	0.97
231.0745850	0.53
232.5153198	2.16
233.2733765	0.13
236.3792419	0.23
239.1758118	0.14
244.1673279	0.76
249.2358398	2.54
250.2492065	0.29
251.2295837	0.56
253.3232727	0.35
258.1689453	0.51
259.0880432	0.98
260.3016663	0.41
261.1371460	0.75
261.8799438	0.22
263.4032593	0.31
269.2264099	0.17
271.1796265	1.52
272.1148682	0.90
272.9556580	1.03
275.1275024	0.91
276.0249939	0.17
277.3421021	0.65
279.3079834	0.39
282.1481323	0.39
283.4319153	1.30
287.2642822	1.97
289.3449097	2.37
291.1675415	5.51
292.2973633	1.50
293.3691406	0.49
295.1400757	0.40
298.1241455	1.15
299.2390137	0.09
299.8754272	0.33
303.9709778	0.13
305.3931274	1.11
306.0123901	0.29
307.1523438	2.65
307.7644043	0.30
309.2053528	11.09
310.2339478	1.96
312.2982178	0.64
313.2412720	0.13
314.2787781	0.74
317.2568359	0.24
319.3621826	0.81
321.6481323	0.09
327.4517822	2.97
328.4223022	0.65
331.2958984	4.01
332.4216309	1.44
333.2174683	0.90
334.1854858	0.12
340.2559814	0.52
341.2419434	0.49
345.3651733	1.09
346.0791931	0.69
347.2787476	0.45
348.5399780	0.84
349.2081299	2.42
350.3458862	2.01
353.0952148	0.25
354.0979614	0.46
355.2937012	0.49
357.1671143	0.57
359.2426147	1.30
360.1616821	1.21
365.0400391	0.60
366.4005737	1.34
367.2158813	7.68
368.3253784	7.62
369.5123901	0.98
375.2880859	0.56
377.3958130	2.47
383.2277222	4.31
384.2171021	1.63
385.3146973	2.32
386.4382935	2.57
387.8160400	1.71
388.5148926	0.11
391.1567383	0.45
393.1422729	0.68
394.2387085	0.89
395.2504883	33.75
396.2592773	12.30
397.3957520	0.62
401.2312012	18.56
402.3348389	9.78
403.3519897	4.53
404.3744507	5.54
406.5432739	0.98
409.0895386	1.45
410.5172119	1.08
417.4464111	0.25
418.3072510	1.53
421.4019775	2.44
422.1507568	0.68
423.1943359	5.39
424.1276855	2.53
425.1917725	0.42
425.9462891	1.70
427.3004150	11.86
428.3745117	9.75
431.2779541	0.26
432.3209229	0.93
433.5698853	1.63
434.3395996	0.18
435.3019409	3.33
436.2368164	1.96
439.2977295	3.69
440.4525757	1.06
442.2525024	0.17
443.5776367	0.54
445.4095459	21.91
446.2425537	8.23
447.5575562	0.19
453.4485474	0.66
454.5847778	0.31
455.3652954	0.64
457.2390747	0.43
458.2487183	0.57
459.1359863	1.44
461.2236938	0.48
463.1392212	4.96
464.0111084	0.10
470.1478882	1.34
471.2491455	20.66
472.1943359	9.90
477.0722046	0.49
479.2402344	0.25
480.0398560	0.39
484.4157715	0.49
487.2507324	3.00
488.1251221	5.06
489.1763306	11.17
490.2721558	4.11
493.4788818	0.18
497.4830322	0.18
498.3775024	0.13
505.1752319	1.80
506.1069336	0.40
507.3631592	17.46
508.4667969	11.17
509.5119629	0.37
511.3541870	2.94
512.2821655	0.30
513.0668945	0.44
514.1571045	0.68
515.2348022	0.80
529.1646118	4.28
530.1871948	2.85
531.2398071	1.95
532.0999146	1.25
536.2550659	0.44
537.3909302	1.46
538.4591675	1.61
545.3432007	1.17
546.8470459	5.39
547.4729004	3.99
548.2091064	6.75
561.1082153	0.53
565.2449341	100.00
566.2821045	74.19
571.5629272	0.13
572.3465576	1.75
576.4789429	0.47
577.5852051	0.59
587.4013062	0.15
589.2631226	29.64
590.4046631	26.60
607.4788208	12.56
608.3885498	6.34
610.4041138	1.11
616.1530151	0.24
633.3191528	45.01
634.2987671	44.46
634.9203491	0.10
649.1403198	2.63
650.2674561	4.03
651.4442139	3.83
652.3594360	2.84
665.2646484	0.62
666.2852173	0.14
675.7332153	0.24
676.3928833	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.0828
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
121.0375214	1.58
128.9846954	8.56
133.0292358	0.10
143.2893982	0.12
145.1704407	0.17
154.9214325	0.08
159.1466370	0.11
161.0857849	0.64
173.0004578	21.02
189.0852509	4.24
219.0533905	0.11
232.8684387	0.80
251.1141052	11.88
259.0075378	0.37
276.4949646	0.28
277.1503601	3.27
295.0999146	100.00
298.3209839	0.28
317.4179382	0.20
331.4848633	0.09
345.1778564	0.12
355.0096436	0.03
373.2623596	0.31
381.0513611	0.06
398.9848938	2.81
402.0667419	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0564
Annotation	Norbergenin
Peak:m/z	Relative Intensity
102.9217911	0.20
111.0689392	0.77
121.0085754	0.50
128.9710999	5.21
144.9088287	0.15
146.9595947	11.12
172.9867401	7.23
189.1601868	0.02
190.9397888	100.00
236.9715576	0.08
250.8917542	0.19
259.2027283	0.05
268.6031494	0.06
276.9385681	0.38
295.1040649	19.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	845.2303
Annotation	Unknow
Peak:m/z	Relative Intensity
245.0568085	0.12
247.0403442	0.01
255.0889587	0.05
259.0340881	0.30
263.3787231	0.06
269.0229797	0.02
270.5439148	0.02
271.1486816	0.18
273.1503296	0.20
275.1710815	0.02
276.2134399	0.08
283.1540527	0.02
284.1829224	0.02
287.0610962	1.16
289.3561401	0.10
291.1429443	0.13
298.4018555	0.08
301.1163940	0.10
304.0240784	0.08
305.9769287	0.01
309.1373291	0.01
312.3091431	0.02
313.0301514	0.16
315.1896362	0.12
315.7984009	0.05
316.4443359	0.14
317.1008301	0.05
319.0542603	5.26
326.1367798	0.02
327.0961609	0.02
329.2697754	0.07
331.5767517	0.06
332.3630371	0.08
333.2328796	0.06
337.4924927	0.10
344.0279541	2.80
345.2852173	0.05
347.1282043	5.58
348.8057861	0.03
361.5500793	0.20
362.1794434	3.98
377.1394653	100.00
378.2367554	0.07
379.1557007	0.12
397.0215454	0.07
415.0239868	0.46
431.1393433	0.02
433.0927734	0.31
451.1929321	0.15
467.1835938	0.02
517.1958618	0.01
539.0109253	0.03
622.8350830	0.30
623.4551392	0.09
665.2225342	0.03
682.6591187	0.06
683.2935181	0.09
718.5595093	0.01
724.9298706	0.02
745.2844849	0.04
790.9832153	1.01
808.4965820	0.22
809.1022949	1.85
826.9425659	31.51
827.6275024	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	502.1696
Annotation	Unknow
Peak:m/z	Relative Intensity
146.8527527	0.12
148.0533752	0.25
201.0781860	1.90
206.7665710	0.20
208.6415100	0.47
213.1845245	0.38
213.8324280	0.16
231.0149689	0.28
248.2389832	0.15
264.1897583	0.07
293.4640808	0.12
296.9877930	0.14
298.3486328	0.18
305.0530396	0.82
307.2532959	0.11
325.1871338	4.21
328.3115540	0.14
337.2191772	31.93
340.0345459	0.14
342.8726196	0.21
347.1803284	0.20
348.2862549	0.10
355.0975952	100.00
373.0066833	0.57
421.0002747	0.43
429.5116882	0.33
439.1611938	0.32
440.2490845	0.19
454.5545654	0.28
457.1298523	2.08
466.0871582	0.59
472.0755005	6.07
474.3475952	0.54
484.4510193	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1561
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
161.1304932	0.18
176.2232819	0.06
176.9036560	0.06
181.0508881	0.14
182.9473724	0.03
189.9936218	0.07
190.9957275	0.04
193.2379303	0.07
195.1396790	0.10
196.2310028	0.09
196.8633728	0.02
199.1902008	0.04
201.3109589	0.14
207.0996094	0.13
208.1680450	0.11
208.9849701	0.05
223.1400909	0.43
224.0351868	0.51
225.1727753	0.24
227.1285095	0.06
229.1329346	0.11
244.8269806	0.02
247.4820862	0.08
255.1523285	0.11
264.9348450	0.04
269.1336975	100.00
271.0949097	10.67
277.0767517	0.11
283.0183105	0.14
289.1792603	0.04
292.9589233	0.28
307.0587158	0.20
309.2493286	0.23
311.0942383	0.18
325.2012329	0.05
332.1909180	0.06
335.1375732	0.12
337.3450928	0.09
352.2178345	0.22
367.0522461	1.81
369.1608887	0.40
371.2678223	0.04
373.5464478	0.04
383.2746582	0.10
389.2100220	0.46
401.1469116	0.08
411.6116943	0.14
413.2183228	0.68
414.1853027	0.06
415.2988281	0.69
423.0590820	0.06
429.5567017	0.04
431.4011841	0.03
433.1734619	64.33
473.3311768	0.11
474.2344971	0.44
475.2917480	26.83
477.2097778	0.15
479.3231201	0.06
485.2814331	0.11
490.9583130	0.22
492.1738892	0.06
494.1382446	0.12
513.9779663	0.04
515.3065796	15.59
516.6473999	0.09
517.3660278	0.16
530.8759155	0.22
533.1950073	0.72
535.2522583	0.15
546.2401733	0.05
554.8895874	0.15
557.4087524	0.12
559.4545288	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	638.2
Annotation	Unknow
Peak:m/z	Relative Intensity
192.9607544	0.28
210.8257446	0.28
228.9214478	0.77
237.1078796	0.38
241.5897827	1.19
246.9177094	0.39
258.6913452	0.30
271.0278625	6.13
271.9998779	1.73
280.1023560	0.21
287.9576721	1.32
289.0164490	11.15
290.0250854	0.59
295.6054077	1.60
296.3496094	0.47
304.1419678	0.25
306.0341797	2.95
307.0039978	3.44
307.9359131	1.02
313.5078125	0.41
314.1137085	0.47
320.6175537	0.24
322.4797363	0.22
324.3268433	19.04
324.9853516	100.00
325.9791260	4.83
335.4973755	0.17
340.8480225	0.75
342.1115112	6.86
342.8175659	76.18
343.8120728	5.64
357.0030518	0.71
415.6827393	0.40
420.9230957	0.39
433.1213379	0.69
450.4940186	0.73
451.2301636	1.21
458.1122437	3.00
468.4300537	0.98
469.1540527	0.48
475.4301758	12.86
476.1536865	31.69
482.4015503	1.14
486.4564819	4.91
487.0680542	3.80
488.1140747	0.31
503.7940674	0.37
504.7561035	2.17
505.9177246	0.64
553.6078491	0.18
565.3981323	0.15
576.3610229	0.48
620.1989746	1.96
621.7150269	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1095
Annotation	Unknow
Peak:m/z	Relative Intensity
95.2318573	1.10
100.9375076	0.20
113.0513763	12.47
113.9497299	3.19
118.7622299	0.18
124.7520905	0.13
131.0283508	100.00
132.0415649	0.38
148.7546082	0.62
154.3783417	0.12
161.1237183	0.19
179.1356201	1.94
183.0523376	2.55
183.9071655	0.67
197.2723694	0.34
200.8574677	0.18
224.2441101	0.28
225.0388794	0.09
239.2091064	0.09
240.1583557	0.19
247.4172668	0.07
250.7920532	0.28
282.7111816	0.27
293.2272339	0.17
311.5089111	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.071
Annotation	Unknow
Peak:m/z	Relative Intensity
136.0872803	0.18
137.1710968	0.06
138.9524536	0.04
149.0565796	0.36
150.1007843	0.07
163.1224518	0.02
167.0964355	1.17
177.9126587	0.02
179.0483398	0.10
191.1716614	0.09
197.9777527	2.43
199.1524963	0.04
204.9440002	0.24
206.3395081	0.03
207.0792389	0.03
216.0607300	2.16
221.1681671	0.02
223.0832367	0.05
226.1582489	0.04
239.8737640	0.03
257.9316406	0.66
260.0531616	0.04
263.3302917	0.05
266.1982117	0.03
267.5323792	0.01
269.1896057	0.25
271.6996765	0.02
284.2761841	0.07
285.1418457	0.02
286.1284485	0.04
288.1329346	0.46
292.5580444	0.03
300.1074829	2.00
318.3047180	0.03
324.1724854	0.04
342.1604919	0.31
349.0477905	0.22
360.0897217	100.00
361.1659546	2.44
366.9257812	0.26
395.2159119	0.03
406.2463684	2.42
407.1106262	0.09
439.2569275	0.06
468.3179626	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	787.2236
Annotation	Isorhamnetin 3-rhamnosyl-(1->2)-galactoside-7-glucoside
Peak:m/z	Relative Intensity
228.9632111	0.40
231.0730438	0.07
238.9271851	0.15
245.0855408	0.12
257.2335205	0.15
260.2131653	0.14
267.3636169	0.14
271.2651978	0.06
272.8747864	0.07
274.1139221	0.40
284.2157593	0.03
285.0001831	0.44
287.1576538	0.11
288.2879333	0.12
300.9295044	0.05
302.0891113	1.53
305.3320923	0.03
313.3059692	0.19
317.1684570	50.87
329.2193909	0.44
331.0671997	0.16
333.1339722	0.06
341.1809692	0.12
348.0494385	0.02
359.1056824	1.78
366.0585938	0.04
367.0692749	0.02
381.3550415	0.19
383.2157593	0.92
385.3601074	0.09
390.1563721	0.02
391.3254395	0.10
397.2288208	0.04
401.3367310	0.09
409.2911377	0.26
413.3192139	0.02
425.2545776	0.23
427.1151123	0.93
439.0225830	0.06
443.3427124	0.10
445.1455078	1.48
449.4259644	0.08
451.3212891	0.07
456.9899292	0.02
461.1640625	0.83
463.1513062	7.14
467.9014893	0.05
469.3127441	0.18
475.2749023	0.05
479.0675049	100.00
479.6853638	0.52
487.1641846	3.17
493.2328491	0.13
503.4006958	0.42
504.7304077	0.18
505.3774414	0.88
511.3524170	0.23
521.0646973	0.49
529.2028809	0.06
540.3348389	0.19
541.3518066	0.39
545.6536865	0.03
547.3292847	0.08
553.1834106	0.35
557.1408081	0.11
559.2642212	0.24
564.1184692	0.03
571.0161743	0.35
575.0808716	0.07
577.9591064	0.06
587.1331177	0.04
589.2003784	0.99
600.3361816	0.09
601.2307129	0.12
605.2538452	0.10
606.6916504	0.72
607.3069458	4.39
608.3593140	0.10
611.0529175	0.03
613.2037354	0.04
615.5174561	0.11
622.9290161	0.47
625.0095215	38.81
625.6670532	0.06
630.6410522	0.03
631.3686523	0.06
636.6981201	0.13
640.9519043	57.74
641.6825562	0.26
649.0215454	1.20
654.0829468	0.18
655.0375366	0.04
663.3206787	0.02
664.9985962	0.04
666.0853271	0.17
667.0827026	0.82
683.1256714	0.03
691.1879883	0.29
703.2714233	0.03
705.4931641	0.19
709.1674194	0.03
716.0385132	0.05
733.0318604	0.14
736.1863403	0.22
739.1953735	0.17
742.4147949	0.05
743.7297974	0.05
751.0419312	1.25
751.6810913	0.06
767.6303711	0.22
769.0323486	3.99
769.7278442	0.03
770.5950317	0.07
774.7139893	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	782.2487
Annotation	Unknow
Peak:m/z	Relative Intensity
229.9624481	0.09
241.1807404	0.06
248.1889954	0.13
252.8439484	0.28
257.1401367	0.07
270.9996338	1.97
272.1930237	0.05
286.4684753	0.06
289.0639648	1.50
290.2449951	0.17
291.4287415	0.13
295.0382690	0.17
301.2242126	0.55
306.8327637	0.59
309.2707520	0.13
312.0901794	0.09
313.1974792	0.18
314.1814575	0.31
315.2820435	0.05
319.4022217	0.16
329.5322571	0.18
331.8124084	5.61
336.1185913	0.07
337.1553345	0.09
348.9638367	0.43
355.1224365	0.55
355.9869385	0.32
363.2772217	0.12
365.3208008	0.09
373.1838074	1.50
374.1870728	2.38
379.0031128	0.20
389.1231079	0.06
392.0922852	7.24
397.1486206	1.58
398.1571655	0.18
410.3329468	0.35
415.0257568	1.56
417.1078491	0.05
419.1742554	0.05
428.3447266	0.05
432.9945068	6.87
434.0881958	1.82
435.0888672	0.03
437.1721802	0.33
439.3021851	0.30
445.2036743	0.06
450.9219971	0.82
452.1875610	0.90
457.2177734	0.08
462.9140625	0.21
463.5374146	0.65
470.2785645	0.33
473.7620850	0.09
481.1985474	4.15
482.2666626	0.21
491.9991455	0.19
499.0580444	2.14
505.2147827	0.14
517.1157227	0.63
518.0862427	0.60
523.0592651	1.83
523.9318237	0.12
534.1043701	0.06
536.2205811	2.82
541.3834229	0.09
547.2374878	0.05
552.5153198	0.04
554.1651611	18.19
554.7651978	0.11
559.2091675	0.83
572.1209717	100.00
572.7652588	0.56
585.3807373	0.11
589.2182617	0.71
590.2980347	0.24
607.1874390	0.58
620.5767822	0.04
625.2090454	0.25
643.0860596	1.68
651.2330933	0.10
661.0279541	0.33
665.9490356	0.15
695.0153198	0.07
715.9618530	0.19
746.0901489	0.31
750.3212891	0.16
752.0468140	0.15
762.5317993	0.07
764.3080444	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
77.01351929	0.76
80.93739319	0.21
103.1161346	0.91
107.1025391	0.46
115.0172272	0.17
123.0527039	1.36
128.8583679	5.73
140.7850494	0.73
147.3934479	0.20
150.9932098	44.53
151.9657593	4.34
154.3352814	0.63
165.2918243	0.17
167.0836334	0.61
168.359726	1.14
169.1157379	0.28
170.6356812	1.49
179.1948395	0.24
179.9904633	0.46
184.167099	0.36
185.0435638	3.13
197.3245392	1.10
207.1432343	1.10
211.2603302	1.49
225.1108856	7.73
226.0094452	0.67
238.1687164	10.15
238.916626	1.75
251.1222687	0.42
253.0835724	100.00
254.2355957	17.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.1
Annotation	Crotonoside
Peak:m/z	Relative Intensity
82.9764862	0.08
85.0014877	0.06
86.9094238	0.02
88.9767380	0.03
91.1680145	0.01
92.9951172	0.07
93.7822266	0.01
95.0483398	0.15
96.0147934	0.01
97.1074753	0.12
105.0171738	0.04
107.0293884	0.10
107.8521423	0.01
108.9612503	0.19
109.7296295	0.06
114.9997406	0.02
116.0197449	0.02
118.0262604	0.01
119.9603424	0.12
120.8492584	0.06
122.0549316	0.05
123.0316849	0.09
125.0783615	0.03
126.8541336	0.01
128.1083069	0.02
128.9551392	0.10
130.8510437	0.01
131.9409790	0.02
132.6472626	0.01
134.0960388	0.03
134.9364014	0.29
136.0471191	0.12
137.0306396	0.03
137.8132324	0.04
139.0916748	0.07
141.1912537	0.03
143.0923004	0.04
144.5485535	0.09
149.0385742	0.17
150.3634644	0.02
151.9323273	100.00
153.0832825	0.03
154.5193481	0.02
156.2074280	0.03
157.9725342	0.01
162.9622040	0.51
164.0652771	0.04
165.1316223	0.09
166.7998505	0.00
169.0834045	0.04
170.2752533	0.04
172.9458313	0.02
177.1813660	0.08
178.1853790	0.11
180.0715332	0.22
181.2819519	0.04
182.1377716	0.05
185.0591125	0.02
186.1928101	0.07
188.1830597	0.01
191.2252502	0.01
192.0213623	0.09
194.4133301	0.10
199.2962341	0.12
202.0476379	0.04
206.5051270	0.02
208.3361511	0.02
212.3768921	0.02
213.3259583	0.04
214.0214844	0.02
216.4461670	0.07
219.0658569	0.01
220.0406799	0.09
222.9470520	0.38
224.1044617	0.03
225.9685974	0.02
228.2420654	0.08
229.3168335	0.02
230.7864075	0.16
238.1594238	0.54
239.2868042	0.04
239.9703369	0.01
240.7832947	0.04
242.1836243	0.10
243.0474854	0.06
247.2675781	0.18
248.2265625	0.17
249.1121826	0.13
252.6365356	0.04
254.8609924	0.01
256.3637695	0.09
265.3392334	0.82
266.3583984	1.79
266.9921265	5.16
268.1848755	0.05
269.9678345	0.29
283.6205750	0.04
285.3657837	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1564
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
180.996994	0.40
199.0960388	0.10
230.9139252	0.50
263.0106201	0.51
269.0462646	100.00
291.3062134	0.66
293.140625	0.12
311.2325745	0.70
339.1599121	1.71
353.2134399	0.14
385.2449951	0.39
385.9315186	0.57
395.170105	0.15
401.2081299	0.18
405.4708862	0.19
413.4728394	0.13
449.0227051	0.98
453.2857056	0.16
461.9042358	0.38
473.1011353	0.88
479.3067017	0.10
481.4137573	0.27
497.3186035	0.10
517.5427856	0.42
530.1765747	0.69
530.8670044	0.44
531.5621948	1.36
533.4822388	0.61
534.5541382	0.31
540.9179688	0.45
549.7510986	0.61
558.6113281	1.44
559.2846069	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1225
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
145.6899719	0.15
153.0226746	0.27
188.1788635	0.30
191.3605042	0.12
196.0520477	0.29
205.0964661	1.13
213.1858521	0.06
219.1884003	0.96
220.1161194	0.05
221.1424103	0.30
222.3703918	0.18
227.0006104	0.06
232.0675964	0.42
235.2168274	0.61
239.2122498	0.16
243.4045410	0.15
246.0016174	0.32
247.2236938	0.95
249.2812195	0.07
253.2784119	1.14
257.2615356	0.25
261.0942993	0.09
262.9685669	0.42
265.0614929	0.62
268.7247009	0.29
271.2790833	7.11
273.1882324	0.20
274.1942444	0.95
276.3295593	0.13
281.3647461	0.16
282.1391602	0.15
283.0259705	0.65
287.2497559	0.43
288.3374023	18.76
289.1810913	100.00
291.2699890	0.17
297.0989075	1.04
300.1668396	0.05
300.9572449	1.89
303.2574463	0.65
304.1796265	0.88
305.2017212	0.71
307.0244141	0.63
308.9823608	0.22
313.1662292	0.49
315.3044434	0.96
317.1107788	0.10
322.2685852	0.16
328.2701721	0.39
329.2788696	0.60
330.5578918	1.37
331.1919861	3.35
333.3063354	0.10
334.4680176	0.06
335.3335876	0.09
345.1215820	0.52
346.1234131	0.11
347.2013855	0.96
349.1842041	0.92
355.1561279	3.13
360.0503235	0.29
361.3213196	0.36
362.4493408	0.12
365.0652466	0.39
366.0061035	0.37
369.1923218	0.79
370.4103088	0.39
371.1087646	1.50
377.0432434	0.52
378.3572388	0.10
379.3208313	0.54
379.9671631	0.12
385.0659485	2.85
389.2735596	0.15
391.1318665	0.30
393.1504822	0.17
397.0489807	5.37
398.3911438	0.32
402.0505066	0.91
404.9391174	0.28
406.3846130	0.27
407.6780701	0.63
413.2339478	1.04
415.1779480	19.07
419.1800232	0.24
420.4105530	0.45
424.3030701	0.13
431.2031555	0.10
433.0717773	44.79
433.8097229	0.24
434.5270996	0.11
436.1296692	0.14
463.9703674	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	778.64
Annotation	gamma-Pentachlorocyclohexene
Peak:m/z	Relative Intensity
252.2491760	0.03
260.1802673	0.09
275.0177002	0.45
290.7885742	4.92
358.6548462	1.04
374.6921997	1.29
375.9603882	0.06
435.2769775	0.04
442.6322021	10.81
458.5534668	11.18
478.3576050	0.10
496.9593506	0.04
510.7971191	0.12
525.0906372	0.04
526.6293945	63.41
542.5930176	44.20
544.6614380	0.05
588.6162720	0.05
604.6363525	0.16
608.0664673	0.34
608.7614746	0.04
610.5311890	57.04
611.3880615	0.03
612.4423218	0.42
613.0462036	0.23
617.2058716	0.05
624.7616577	0.15
626.4385376	15.59
628.9022827	0.09
648.6600952	0.09
658.9094849	0.04
671.9855347	0.61
672.5885620	0.92
692.3930054	0.45
694.3438110	100.00
695.0978394	0.14
698.7833862	0.17
710.2391357	0.97
713.5393677	0.10
732.5376587	0.53
755.7838745	0.04
760.4406738	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	651.2656
Annotation	1beta-Hydroxybaccatin I
Peak:m/z	Relative Intensity
184.8495331	0.33
192.9281616	1.53
195.1549530	1.14
199.3087463	1.10
200.0256805	1.05
201.1821442	3.00
207.0432434	0.69
213.2878723	3.47
217.2234802	1.05
219.2180786	0.71
221.1560822	6.45
224.1787720	0.51
225.2079010	0.36
228.1867371	1.57
229.2716980	1.87
230.1234436	1.45
231.2606506	2.59
233.2285614	0.60
235.2557526	0.60
237.3742676	0.45
241.0984192	2.13
245.3436737	0.85
247.1701965	0.30
249.0216217	1.10
251.0011597	0.30
253.1527405	3.22
257.2454834	0.23
259.1880493	3.05
261.2037354	1.81
269.2921753	1.47
271.2514038	7.10
275.2447510	0.57
275.9819641	1.19
277.4480591	1.32
278.1083374	0.42
279.0449524	1.76
281.3928833	1.19
285.1403503	1.21
287.1322021	1.96
288.4696655	0.83
289.2976990	1.57
291.2110901	0.68
293.0605774	0.38
298.8985901	0.84
301.3708801	1.13
305.3259583	2.65
307.2681885	1.65
309.2514343	12.54
311.2749634	0.29
313.1158447	3.45
315.9760132	0.27
323.1538086	4.88
327.2484131	5.23
331.1287231	3.55
333.2177734	1.80
334.9348755	1.46
335.5723877	0.45
339.3052368	0.60
341.3161011	2.57
344.4635010	0.25
345.2543335	4.23
346.4653320	0.52
349.3828735	8.20
351.2821655	1.05
353.2551880	0.39
357.2149658	0.43
359.2985840	2.74
365.1156006	2.67
366.7818604	0.87
367.3859253	10.41
373.4677124	0.52
375.2205811	1.77
377.3765259	1.00
381.1648560	0.56
383.1171875	0.43
385.2239990	23.69
385.9279785	0.15
389.4584961	0.72
393.3843994	2.31
395.2390137	10.73
397.3609619	1.05
401.2604980	3.90
403.1349487	22.34
403.7399292	0.92
409.5004883	0.28
411.2693481	0.23
421.3629150	4.37
423.2520752	12.25
427.2930908	2.92
429.0868530	1.63
433.4050903	3.44
435.3101196	0.87
441.4613037	0.30
443.4346313	0.34
445.1863403	22.21
447.3334351	0.45
461.2833252	2.77
464.3725586	0.23
470.6265259	0.53
471.2630005	3.82
475.4705811	0.34
477.4075317	1.91
479.1743774	0.78
483.1003418	0.48
485.0355835	0.87
487.3698730	2.84
489.3426514	8.18
497.3311768	0.47
507.3473511	13.68
509.1046753	1.22
511.3196411	1.94
513.3984985	1.71
519.3324585	2.94
521.3022461	0.87
529.3189697	4.40
531.3544312	0.90
533.6376953	1.07
537.4865112	2.16
547.2233276	9.73
549.1464233	0.80
551.2454834	1.16
563.4958496	3.56
565.3638306	67.38
573.4105835	1.44
577.2430420	1.89
591.3295898	100.00
605.5038452	0.38
607.2997437	8.97
609.2519531	12.23
615.3468018	0.60
633.4307251	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.24
Annotation	Unknow
Peak:m/z	Relative Intensity
245.2534485	0.18
247.0946045	0.09
265.2426147	0.43
283.0556641	0.25
290.9266968	0.17
305.1158142	0.29
306.0795288	0.10
307.1402588	0.14
309.0806885	0.11
321.1223145	1.58
322.1271362	1.65
323.1122131	0.26
328.8023376	0.12
338.6834106	0.17
339.2852173	1.86
339.9670410	0.07
341.1769104	0.79
359.3944092	0.08
379.2630005	0.60
381.1691284	0.30
382.1098022	0.99
383.0863647	0.66
397.3098755	0.41
431.4102783	0.11
437.2148438	0.09
450.4093628	0.43
451.5611572	0.16
454.1459961	0.28
455.1928711	1.24
463.2864380	0.12
464.1431885	0.19
465.2227783	0.10
469.2031860	0.07
475.3004150	0.09
477.4973145	0.15
481.4132080	0.15
491.2994385	0.58
492.8474121	0.40
495.6181030	0.14
497.2091064	0.81
507.1201782	0.36
508.5195312	0.84
509.4767456	0.07
511.2782593	0.23
513.3548584	0.36
514.0407104	0.12
515.2662354	0.77
519.3058472	0.12
524.9880981	0.34
526.8126831	0.77
527.6157227	0.05
529.1531372	0.29
533.3867798	0.04
534.3724976	0.05
537.1586304	0.14
543.4034424	0.10
545.2866821	0.07
550.6600952	0.21
553.2219849	0.13
553.9799194	0.12
555.4603271	0.13
557.4195557	0.28
566.5082397	0.22
567.2664185	2.24
568.0110474	0.95
569.2449341	5.31
579.3551025	0.16
585.1786499	3.17
586.2640381	2.10
587.3021851	11.73
595.3489990	0.20
597.2238159	0.71
601.3567505	0.13
605.2466431	0.88
609.3190918	0.57
610.2064819	0.07
611.2520752	1.11
613.3273315	0.18
614.2520142	0.12
615.1958618	0.25
627.3377075	0.20
628.9122314	1.38
629.6192017	0.09
639.1499634	0.29
641.2361450	1.16
643.3774414	2.43
645.2257690	2.61
646.4528809	10.15
647.2501221	29.18
657.2144165	0.23
659.2749634	1.96
661.2073364	0.79
669.2272339	1.01
675.5468750	0.09
677.5103760	0.41
683.3550415	0.31
687.4146729	0.16
688.5042114	0.09
689.2679443	0.71
693.4687500	0.26
699.1894531	3.72
700.5112915	5.89
701.3289185	36.30
705.4091187	1.49
717.2800903	4.14
719.1801758	100.00
719.9464722	0.08
735.9332886	0.10
737.2492065	7.55
737.9413452	0.16
747.2673950	1.51
748.3281250	0.70
749.1390991	0.16
759.1727905	0.12
761.3330688	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	291.0721
Annotation	Unknow
Peak:m/z	Relative Intensity
85.0120773	5.14
99.0944061	0.23
100.9761200	0.07
110.9521179	1.85
113.2191238	0.04
128.9785156	7.69
130.9300537	0.04
145.0336914	0.12
146.9963074	8.98
172.8687897	7.67
190.9827728	100.00
194.9782562	0.08
228.8809814	0.78
247.1748657	0.25
254.4916687	0.27
255.1904907	0.35
273.0945435	17.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.1516
Annotation	Aesculin
Peak:m/z	Relative Intensity
264.1847839	0.01
265.0054321	0.02
301.4709778	0.03
356.9859619	0.03
358.1476440	0.02
360.3243408	0.01
369.1977539	0.01
370.1914062	0.05
371.4784546	0.03
393.0589600	0.04
445.4620972	0.02
471.1858521	0.01
473.2593384	0.32
474.3391113	0.02
487.1857300	0.06
503.4138184	0.08
515.2372437	0.09
516.2657471	0.03
517.3685913	0.17
532.3737183	0.04
533.1929321	0.01
534.3822021	0.05
535.1918335	0.05
545.0479736	0.02
554.4962769	0.01
560.1671753	0.01
575.0728149	0.11
576.6652222	0.03
593.2288818	26.59
593.8496094	0.16
616.1654663	0.03
617.3528442	0.04
632.9957886	0.03
635.2032471	100.00
635.8668823	0.47
641.0570679	0.03
643.0588989	0.03
646.3151245	0.02
659.2085571	0.01
661.3034058	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1976
Annotation	Cymorcin diglucoside
Peak:m/z	Relative Intensity
160.9753723	0.40
170.7151794	0.05
171.5462494	0.15
178.6688232	0.53
181.1455536	0.09
188.9053040	0.16
207.2622528	0.05
219.2963867	0.11
237.1340790	0.93
252.8222046	0.09
263.1617126	0.09
281.1278076	100.00
281.8011475	0.05
295.2337952	1.02
305.2503357	9.04
307.1645508	0.20
323.1471558	4.94
327.1544800	0.35
335.3255920	0.83
345.6817017	0.23
351.0406189	0.32
352.4743652	1.39
353.1865234	4.86
359.1560059	0.07
362.5360107	0.07
370.6449280	1.53
371.2681580	0.04
377.2784119	0.22
381.4256897	0.07
382.8997498	3.18
383.5822144	0.19
387.1241455	0.13
399.0575562	0.19
407.1755371	0.13
413.1915894	0.42
424.2728271	0.14
425.3591614	0.37
442.8973694	79.48
443.6704102	0.12
445.4613953	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.16
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
181.8952789	0.66
194.7103729	0.20
196.131012	0.35
253.0047607	0.76
265.3145142	0.27
269.038269	100.00
310.9854736	0.85
335.3652954	0.11
339.2348633	2.11
353.1883545	0.41
368.7077026	1.29
385.1807861	0.49
391.5618896	0.53
393.1251221	0.31
413.3241577	1.48
433.3303833	0.12
443.3701782	0.72
473.6625977	0.14
479.6013794	0.25
491.4995728	0.28
515.6625366	0.65
530.7600098	0.47
532.0619507	0.99
533.1949463	0.98
553.9484253	0.34
559.1177979	0.72
560.1420898	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.2028
Annotation	Terretonin A
Peak:m/z	Relative Intensity
133.1765900	0.06
135.0013885	0.07
135.9849243	0.07
136.9072113	0.10
140.8879395	0.05
143.1254272	0.02
145.2009277	0.10
147.9335327	0.05
149.1233368	0.26
151.1223145	0.18
157.1796875	0.05
158.0942078	0.02
159.1278381	0.18
160.8851013	0.04
162.9308167	0.22
167.0950317	0.10
168.0367737	0.04
168.8783569	0.08
170.1931915	0.03
170.9653015	0.31
172.2793121	0.06
173.0740662	0.12
174.1572571	0.04
175.1701508	0.23
178.0092468	0.06
179.8256836	0.07
181.1089935	0.08
183.0756683	0.05
184.2880249	0.04
185.2481689	0.13
186.0559082	0.27
187.2437286	0.16
187.9471893	0.08
189.1923523	0.49
191.3309021	0.22
193.1192627	0.08
195.1318970	0.16
197.1081848	0.67
198.0325317	0.26
199.0946350	0.50
200.8827057	0.52
203.0919952	1.14
204.6210785	0.28
207.0282135	0.11
209.2586823	0.21
210.9401245	0.07
212.1967468	0.07
213.2116089	0.78
214.2648468	0.03
215.2188873	0.16
217.2585144	0.33
219.1658936	0.73
221.8305054	0.04
223.0617676	0.36
224.5013123	0.03
225.5745697	0.11
227.3206787	0.42
229.0941620	0.95
231.1589813	0.36
233.2803650	0.15
235.0028992	0.04
236.1546783	0.07
237.1140442	0.25
239.5186005	0.15
240.1886749	0.11
241.2401276	0.40
243.1136780	0.77
245.2462158	3.58
247.8718567	0.12
249.2157288	0.17
251.2650452	0.61
253.2476196	0.62
254.2455139	0.11
255.2533569	0.63
256.2274475	0.02
257.0946045	0.32
258.0980225	0.04
259.1883850	1.44
261.3813782	0.16
263.1259766	1.56
264.3875732	0.32
265.3143921	0.82
267.2282104	0.43
268.2654419	0.04
269.2835999	0.72
270.2793274	0.12
271.2413940	0.37
273.2189941	2.49
274.3341370	0.06
275.1471558	0.33
277.1258545	0.63
278.1308594	0.06
279.2600403	1.61
281.2048950	0.55
282.2409973	0.22
283.1834106	0.11
284.8468323	0.44
287.3013306	1.69
289.2782288	2.62
290.1246643	0.07
291.2314758	7.22
292.2080078	1.03
293.1894226	0.14
295.3013000	0.79
296.2524109	0.18
297.1723633	4.23
299.2193909	0.73
305.4650269	0.72
307.2175598	34.20
308.2125854	0.54
309.2071228	0.62
310.2949829	0.17
312.2000732	0.03
313.2435913	0.56
315.2917175	1.08
318.1429138	0.34
319.2281494	0.10
320.3715820	0.07
321.5626831	0.01
323.2007446	3.68
325.2229309	100.00
325.8435974	0.19
326.4482422	0.12
329.3740234	0.08
330.3571472	0.11
331.2492065	1.22
333.0773926	0.76
335.2036133	1.69
336.2580261	0.98
337.3624878	0.40
338.3665466	0.05
339.2226562	0.09
340.3099060	0.12
341.1980591	0.98
347.3102722	0.48
349.3682556	0.02
351.1453857	14.80
351.7733765	0.20
353.5986023	0.08
354.9577026	0.11
363.2788696	0.87
365.2355347	3.72
369.2296448	10.83
376.0733032	0.04
377.4700623	0.14
381.3511658	1.03
383.2472839	6.30
391.3584290	0.38
395.4485168	0.14
399.2084351	0.36
409.3345642	3.40
413.2951965	0.68
427.2796936	8.75
435.3504944	0.02
449.6550598	0.11
453.4774780	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
75.17960358	0.10
76.8168335	0.32
79.05883789	0.22
79.78796387	0.32
81.10969543	0.20
83.07793427	0.75
92.99016571	0.62
93.94273376	0.16
94.87006378	2.40
96.08703613	0.37
96.9703064	0.44
98.72930908	0.92
101.0863953	0.57
102.7892914	0.59
104.8317413	2.20
106.9502411	1.20
108.9732513	1.11
111.0592194	0.49
113.1201172	0.36
114.9966888	0.22
121.1264801	2.91
121.9279633	0.20
123.0730286	1.65
124.9977875	0.44
126.9861755	6.61
129.0124359	8.17
130.1219788	0.82
131.0220947	0.31
133.1658936	0.37
134.960022	2.21
136.9866638	1.61
138.83638	0.24
141.0341949	3.22
142.8891754	1.25
144.9120026	1.05
147.0448761	3.54
148.6955109	0.91
150.9705353	59.72
151.8740997	4.91
153.2103882	1.40
155.0127106	1.33
156.4434509	1.09
157.1269226	2.05
159.1846466	0.54
160.9874725	1.25
163.119339	0.18
164.0955658	0.27
165.1287384	0.92
167.0066376	1.70
169.047287	2.87
171.2255402	0.35
173.1362305	0.26
174.9515991	0.28
177.1780548	1.28
178.0089264	0.50
179.0717926	1.21
180.0017395	1.18
181.123703	0.55
182.190918	0.75
183.2816925	0.88
185.0539703	0.50
189.1569977	0.67
193.390274	1.44
194.2471771	0.79
195.1358185	2.51
197.010788	3.80
198.1909332	0.45
198.9877777	0.15
204.8734283	0.85
207.0752411	3.85
207.9256287	1.34
209.1210175	0.73
210.138916	0.42
211.1282654	7.51
211.8153229	0.57
217.2026215	7.38
219.2781525	0.25
224.9835968	9.14
225.8623505	0.60
226.4975433	0.62
228.8035889	0.26
232.3964386	0.37
235.1221161	24.05
236.0151825	0.60
238.0853271	9.39
239.1357422	1.55
253.0928192	100.00
254.1292267	22.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.03
Annotation	Demonomethylchlorpromazine
Peak:m/z	Relative Intensity
112.8842163	0.21
128.8526154	10.26
131.0430756	0.66
145.1202698	0.48
160.9847717	0.04
173.1019897	8.00
178.9215088	0.23
223.4143982	0.04
226.8640747	0.10
254.8488770	0.08
257.0779114	100.00
267.3167725	0.25
273.3514709	0.07
297.4630432	0.11
323.8221436	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.1005
Annotation	GDP-4-acetamido-4,6-dideoxy-alpha-D-mannose
Peak:m/z	Relative Intensity
183.2595520	0.01
191.2560883	0.01
227.1877441	0.01
262.8856506	0.25
286.1762085	0.08
287.2456970	0.05
303.2810059	0.14
317.2357483	0.02
330.9074707	0.02
334.3908081	0.01
346.0588989	0.05
347.0187988	0.02
357.1448975	0.04
360.4064941	0.02
365.2884521	0.01
366.1926880	0.02
372.1584473	0.03
375.6894531	0.01
377.1402588	0.09
383.8609009	0.01
403.3244629	0.02
418.4545898	0.02
419.1878052	0.33
425.3211670	0.07
426.1113281	0.01
432.2103271	0.03
435.0746460	0.10
437.1311035	100.00
437.9274292	0.01
446.1684570	0.02
447.8484497	0.01
454.2301636	0.02
467.2758179	0.06
470.1963501	0.02
488.9180298	0.02
492.0700684	0.33
495.2442627	0.02
508.0950317	0.04
531.4962769	0.01
532.5152588	0.03
550.2533569	0.01
565.2872314	0.02
566.1118164	0.02
567.0910034	0.01
568.4379272	0.13
569.1939087	0.18
579.1450195	0.07
593.5661011	0.01
611.1587524	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	778.3727
Annotation	Unknow
Peak:m/z	Relative Intensity
285.2093811	0.16
301.1990356	0.14
311.2959290	0.11
334.6135254	0.08
339.2339478	0.74
347.0799255	0.12
367.1399841	2.44
377.4561768	0.05
394.3235474	0.21
412.0841675	0.55
426.4718628	0.04
429.3134155	0.23
440.9326782	0.24
441.5603638	0.14
448.1322021	0.94
450.3784180	0.51
451.4379272	0.17
468.2493896	0.65
469.1804199	0.78
485.1298218	0.05
486.4530029	0.99
490.1403198	0.30
502.3467407	0.15
505.3353882	0.07
511.5321655	0.13
512.2061768	0.31
514.2350464	1.02
524.1199341	0.08
528.3753052	0.61
530.2352295	0.58
537.6192627	0.25
552.3881226	0.53
556.4272461	0.15
560.3596802	0.09
569.2916870	0.14
570.2512207	1.01
571.7761841	0.11
574.2556152	0.10
576.6654663	0.63
582.5469360	0.12
584.4387817	0.09
585.4029541	0.18
587.2946777	0.16
592.7310791	0.52
597.3200073	0.51
599.2897339	0.10
600.2411499	0.11
603.2985840	0.25
604.6021118	0.48
613.1693726	1.20
614.1784058	0.09
615.4052124	1.13
616.4794312	0.09
627.4225464	0.37
630.6004028	0.10
631.2857056	1.74
632.4071045	1.11
643.4770508	0.24
649.3097534	0.47
651.0061646	0.36
652.4295044	0.09
658.3737793	0.06
659.2958374	0.11
661.5494995	0.20
675.2424927	0.27
677.4996338	1.01
679.2288208	3.56
687.9778442	0.09
689.4088135	0.67
696.4338989	0.25
703.3707275	0.06
704.0514526	0.18
706.2015991	0.35
715.2297363	2.25
716.6840210	0.31
721.3931274	0.11
725.7900391	0.31
732.3380737	6.24
733.6923218	2.07
734.3861694	1.32
735.2214966	0.29
742.3471069	1.67
743.2112427	0.18
746.8348389	0.57
749.0764771	0.07
750.3599243	6.85
758.4854126	0.30
760.2965698	100.00
761.0203857	0.42
764.6084595	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	653.1722
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
195.1569519	0.06
205.2330627	0.07
206.9678192	0.06
215.2873230	0.16
228.1155548	0.08
231.2135162	0.03
235.0495148	0.02
239.1746826	0.10
241.2042236	0.04
242.0251312	0.03
243.1368713	0.17
245.1194153	0.14
257.0499878	0.32
258.0732117	0.67
259.1104736	0.78
269.1303101	0.16
270.2385864	1.06
271.2323608	0.14
273.1482849	0.79
283.2562866	0.08
285.0571899	6.38
286.1979370	2.08
287.1456909	12.38
296.3142090	0.08
298.2728577	0.07
300.0056458	0.24
301.0696106	7.21
302.1403809	9.09
303.3110352	0.15
313.2052002	0.32
314.2065430	0.33
315.0723877	0.66
316.0601196	0.06
317.0120239	0.22
327.1926270	0.34
328.1745605	0.59
329.2033081	5.99
330.0853882	54.36
331.0898132	0.45
343.1151123	0.60
345.0959473	100.00
346.0418701	0.54
347.3337402	0.09
354.0374756	0.05
355.2048950	0.13
358.1190186	0.14
359.1403198	0.49
372.0338135	0.16
373.9583740	0.09
385.2911377	0.02
387.0579224	0.43
388.1362915	0.03
402.2554321	0.07
411.1857300	0.05
447.4489136	0.11
461.3056030	0.25
463.1272583	0.05
470.1878662	0.04
491.2881470	0.07
491.9452515	0.14
493.2249146	0.32
494.5191040	0.03
503.2879028	0.02
507.4351807	0.03
508.3822632	0.05
509.3059082	0.04
521.2390137	0.02
529.5339966	0.05
550.7396851	0.05
579.2084351	0.10
609.2747803	0.14
610.1445312	0.31
621.3200684	0.35
622.4183960	0.09
625.1688843	0.51
626.1550903	0.09
635.4053345	0.05
638.1997070	6.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	434.8717
Annotation	Unknow
Peak:m/z	Relative Intensity
131.0261383	0.06
175.0124207	1.46
211.1140594	0.05
260.8620911	0.12
289.0615540	1.16
304.9370422	100.00
320.8894653	0.04
360.9605713	0.03
361.9223022	0.07
362.8736267	0.04
365.1177063	0.01
365.8195190	0.02
386.7457581	0.08
388.9100037	0.03
390.1633606	0.02
390.8418274	0.06
391.7979126	0.02
416.9151001	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1609
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
118.9169769	0.04
135.1273499	0.05
137.1551971	0.14
153.2523346	0.08
161.1922760	0.06
179.0483093	0.49
181.0766907	0.40
194.9687805	0.05
197.1214447	18.10
202.8774261	0.02
223.1823120	0.55
236.8469543	0.06
239.3027954	0.04
241.0655518	100.00
241.6873169	0.28
247.1779175	0.16
255.0520935	0.03
257.1461792	0.05
265.1882324	0.39
283.1034851	0.84
295.0993042	0.19
299.4319458	0.02
313.2037964	0.30
338.9816895	0.15
343.1693115	1.52
357.2922058	0.48
385.3349609	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	285.075
Annotation	Alnustinol
Peak:m/z	Relative Intensity
83.0857697	0.08
85.0456848	0.08
95.0799942	0.02
97.1153870	0.10
101.0553589	0.03
108.9849014	0.12
123.2100754	0.01
128.9853516	0.03
137.1115417	0.08
139.1732788	0.02
143.1874695	0.04
146.8232422	0.04
151.0762939	0.02
151.9429474	0.05
159.0068207	0.04
165.0567780	0.05
168.8862915	0.01
171.0499878	0.11
173.3787537	0.14
177.0570374	0.09
178.0245056	0.01
179.1390381	0.23
183.1879120	0.05
185.2408752	0.06
187.0645905	0.05
188.2254944	0.01
190.8449097	0.08
193.1180725	0.04
195.2158508	0.01
197.0987854	0.11
198.1342163	0.05
199.1117554	0.49
199.8537292	0.06
201.0867310	0.80
201.9493713	1.32
203.0094604	3.03
204.9722595	0.29
207.0100098	0.18
207.9859924	0.01
211.1769714	0.62
213.1768799	0.55
215.1144104	5.09
216.9703064	100.00
218.0447083	0.17
219.0354614	1.75
221.1327820	0.08
223.1727600	0.28
224.9940186	0.52
226.0552673	0.08
227.0523987	0.91
229.1105042	3.33
234.2607727	0.05
238.9731750	1.28
240.1121826	0.21
241.1128540	2.81
243.1326904	2.67
248.4287109	0.03
249.1648560	0.32
250.2516479	0.03
255.0119019	0.94
257.0583801	7.92
257.9851685	0.03
265.3616943	0.06
267.0652466	2.92
268.4186707	0.02
270.3340149	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1972
Annotation	Carolenalin 4-O-beta-D-glucoside
Peak:m/z	Relative Intensity
125.0177307	1.87
142.9432068	1.07
161.1643372	0.22
163.1205139	0.06
179.2356873	0.20
197.1647949	0.65
203.1515350	0.21
219.2104187	0.35
221.1915741	0.80
223.2206421	5.87
239.2244873	12.59
241.1906433	0.82
241.7969971	0.14
265.2645264	3.46
279.2196960	2.45
281.2565002	31.78
281.9686890	0.05
283.0453491	23.50
283.6703186	0.06
297.1607971	0.08
303.2570190	0.33
305.1495667	10.32
321.2930908	100.00
323.3368530	3.92
325.0887451	14.71
341.4074097	0.55
349.5485229	0.24
365.0079041	6.74
367.2454224	20.60
383.2514648	29.83
385.1915588	19.68
385.8400269	0.06
409.3100891	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	718.304
Annotation	Unknow
Peak:m/z	Relative Intensity
199.3144684	0.15
201.1615753	0.02
204.1594238	0.32
211.1425171	0.02
213.1013489	0.05
213.9696808	0.06
215.2398682	0.13
219.2512054	0.04
221.1274719	0.04
223.3789978	0.07
225.2566071	0.08
226.8970947	0.05
233.0290680	0.05
234.0708008	0.05
235.0585938	0.19
237.1070251	0.23
239.2026672	0.02
241.1826782	0.05
245.1662903	0.16
247.2901306	0.02
249.0306702	0.01
250.3339081	0.03
251.2234802	0.23
252.2886658	0.02
253.2438660	0.08
255.1781158	0.15
256.2540283	0.04
257.2526550	0.04
258.0101624	0.04
259.2768555	0.08
261.2106934	0.11
263.2963257	0.17
265.1780396	0.16
267.1928101	0.09
268.2461548	0.08
268.9693604	0.07
271.1994934	0.03
273.2246094	0.12
274.0452881	0.30
275.1215515	0.04
276.9730835	0.13
279.2900391	0.08
281.3894043	0.11
283.1629639	0.16
285.1898193	0.02
287.3275146	0.10
289.1945801	0.33
291.1659241	0.15
293.1438599	0.07
295.2767944	0.09
297.1030273	0.22
298.0599365	0.08
299.2127686	0.12
300.1674500	0.05
301.3845215	0.07
303.0014343	0.15
305.2919922	0.35
307.2360229	0.48
309.3654175	0.09
311.3250122	0.09
313.2474365	0.16
315.3398438	0.42
316.1470947	0.02
317.0042419	0.05
319.3036804	0.12
321.1368408	0.08
323.2615356	0.21
324.0439758	0.04
324.9483032	0.02
326.1667480	0.09
327.1906738	0.14
329.2826538	0.37
331.2263794	0.14
333.1747437	0.89
335.3747559	0.06
336.2418213	0.07
337.3860474	0.12
339.3262024	0.03
341.2062988	0.26
344.9195557	0.04
347.0893860	0.32
349.1947632	0.25
351.1421509	0.51
352.5640259	0.02
353.3606567	0.02
355.2076416	0.11
356.3455200	0.02
357.2360229	0.29
359.1794434	0.36
361.1746216	0.07
362.1507568	0.03
363.4720459	0.07
365.2471924	0.16
367.2676392	0.24
368.5976562	0.03
369.3140259	0.97
373.2088013	0.25
375.3565674	0.35
377.2234497	0.33
381.9443970	0.05
383.0546875	0.03
384.1038208	0.01
385.0213013	0.03
386.3518066	0.01
387.1712646	0.04
389.4275513	0.07
390.8587036	0.11
391.4890747	0.39
393.2524414	0.47
395.2453613	0.30
397.1371460	0.01
399.5249634	0.09
401.3557739	0.20
403.4005737	0.03
407.2827759	0.04
409.3550415	0.57
411.0828247	0.28
413.3050537	0.71
414.4020386	0.02
415.1577148	0.08
416.2562256	0.03
416.9157715	0.02
418.5428467	0.12
419.4036865	0.45
420.9906616	0.02
427.2725830	0.16
429.4794922	0.12
432.4230957	0.08
434.4202271	0.10
435.2306519	0.11
437.2005005	0.37
439.3250122	0.03
441.6785889	0.03
442.4382324	0.04
443.4302368	0.12
448.2078857	0.03
450.0101318	0.10
451.2721558	0.14
453.2956543	0.26
454.0562134	0.17
455.1863403	0.16
457.5305176	0.05
458.5025024	0.05
461.4974365	0.02
462.1901855	0.05
463.0956421	0.02
465.3450317	0.03
467.4946899	0.20
468.1719360	0.02
469.3142700	0.32
471.4896240	0.14
472.5057373	0.08
474.5117798	0.08
475.1303711	0.03
477.2259521	0.05
479.2328491	0.23
480.1904297	0.02
482.2244873	0.22
483.4092407	0.03
484.4013672	0.07
487.1967163	0.02
492.3741455	0.03
493.4525757	0.23
494.4426880	0.28
495.3931274	0.65
497.3590088	0.47
498.3395996	0.11
500.6376343	0.04
501.4131470	0.04
502.8195190	0.12
503.4780884	0.02
504.7363281	0.01
511.1486816	0.23
513.2492065	0.72
515.1991577	0.19
516.0572510	0.05
517.4138794	0.23
518.3555298	0.58
519.5714722	0.18
520.3981934	0.07
521.3485718	0.20
522.7373657	0.03
524.3159180	0.06
526.3390503	0.03
527.3222046	0.04
529.3889160	0.53
531.1222534	0.13
534.3222656	0.08
535.2966309	0.04
536.1569214	0.08
537.3992310	0.18
538.5978394	0.19
539.2826538	0.28
542.4232788	0.08
544.0443726	0.28
545.2366943	0.03
547.8951416	0.12
550.3377075	0.07
551.2545776	0.02
552.5778198	0.05
553.3516235	0.39
554.4116211	0.18
555.4013062	0.17
557.3218994	1.53
558.3629761	0.09
560.3629761	0.62
562.2518921	0.36
563.4140015	0.01
567.3859253	0.03
570.6039429	0.05
571.2971802	0.02
572.5357666	0.22
575.3268433	0.38
576.4835815	0.16
578.2235107	0.79
578.9422607	0.04
580.3710938	0.37
581.1495972	0.05
582.3478394	0.04
586.3683472	0.28
589.4644165	0.02
594.3611450	0.42
596.2567749	1.51
597.5208130	0.03
598.3663940	0.13
599.1539307	0.31
600.2864380	0.33
604.3527222	0.38
605.2250366	0.12
610.4559937	0.03
612.2797241	0.78
613.3837891	2.86
614.4731445	4.62
615.6094360	0.03
617.2126465	0.58
618.4098511	0.13
621.0254517	0.02
622.3439941	1.57
623.3775024	0.01
625.9703369	0.03
628.5101929	0.02
629.3881226	0.03
630.5443726	0.02
635.2892456	0.03
636.4234009	0.23
638.1661987	0.45
640.2426147	22.85
641.1339722	0.06
644.3618774	0.04
654.1919556	0.05
656.2708130	2.14
657.5391235	4.45
658.3848877	20.34
659.2241211	0.26
664.4996948	0.25
665.6759644	0.01
666.3232422	0.03
672.2075806	0.07
673.3292847	0.47
674.3923950	0.84
676.2314453	0.04
678.5716553	0.18
682.1954346	1.35
682.8416748	0.01
690.2589722	0.02
700.2796631	100.00
700.9276733	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.1449
Annotation	Unknow
Peak:m/z	Relative Intensity
118.8245163	0.82
119.7137299	0.10
122.8954010	0.13
126.8087616	1.45
135.9277344	100.00
136.5480347	0.18
156.9856262	4.77
163.8443604	0.17
164.8203125	0.07
168.8980560	0.20
175.0569458	72.09
194.8463745	0.13
214.8283691	0.56
220.2288818	0.08
225.0364380	0.05
228.5262756	0.12
229.1525269	0.37
231.0894470	0.15
237.0046692	0.05
241.0927429	0.58
250.2015076	0.15
251.2501221	0.06
259.0720215	8.67
268.1647949	0.41
269.3348389	0.14
277.0678711	42.16
285.6019287	0.15
293.8441467	0.05
320.0800171	0.18
326.1363525	0.17
332.1130676	0.29
352.9071655	0.47
362.6760864	0.21
363.5421143	0.66
365.8078003	0.05
366.4661865	0.08
368.2716980	0.53
369.4602966	0.21
370.2397461	0.21
371.0267029	0.77
375.9780579	0.12
384.0716858	0.20
389.1625671	0.11
394.1354675	1.70
395.0636292	0.11
398.4457703	0.11
403.4541931	0.37
412.8896179	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	729.2252
Annotation	Unknow
Peak:m/z	Relative Intensity
235.1759796	0.95
239.1248169	4.53
251.0376282	0.04
261.0200806	0.09
276.9729919	6.56
281.0559692	3.33
293.1950073	0.04
319.4307251	0.10
320.7362061	2.71
323.2046509	0.07
336.7278442	0.14
344.1185913	0.23
346.0499268	0.11
353.2763672	0.15
394.3337402	0.14
407.1476440	100.00
415.0051880	0.09
419.6578369	0.19
435.2628784	0.30
503.5322266	0.04
522.2258911	0.17
523.4291992	0.12
539.0875854	0.11
540.8858032	0.47
566.2973022	0.04
567.2733154	0.08
574.4783325	0.05
585.2562866	0.10
597.3062744	0.06
598.4588623	0.10
608.3399048	0.20
624.2307739	0.13
625.6528931	0.29
637.1210327	0.36
641.2682495	2.35
642.3107910	0.96
643.2640991	0.19
684.6698608	0.10
685.2835083	0.05
710.3352661	1.18
711.2986450	0.84
712.6472778	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1251
Annotation	b-D-Glucuronopyranosyl-(1->3)-a-D-galacturonopyranosyl-(1->2)-L-rhamnose
Peak:m/z	Relative Intensity
172.8925171	100.00
317.1897583	1.25
335.2011719	5.76
339.4191284	1.74
341.2725830	18.49
353.1308594	5.49
371.3082886	0.35
383.4088135	4.26
453.2869873	3.09
455.4163818	1.10
479.1774902	4.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	589.2288
Annotation	Taxchinin N
Peak:m/z	Relative Intensity
174.9699249	1.49
175.9906616	0.03
178.8051147	0.18
190.0802612	0.71
191.1331482	0.36
193.0751953	2.80
203.0787659	0.49
205.1105194	2.65
207.1940155	0.03
217.1386871	0.09
221.1507568	0.11
223.0328979	2.21
225.2610779	0.05
229.1469879	0.06
232.0662231	0.03
235.0282288	0.55
247.1380920	0.06
257.2350464	0.04
261.2835693	0.06
265.1790161	0.50
277.4084167	0.05
285.1209717	0.15
295.1451416	0.33
296.1374512	0.03
301.1520386	0.02
311.3020630	0.02
322.0819092	0.04
325.4727173	0.07
327.1801758	0.04
330.1798096	0.10
337.1199341	0.24
341.3258057	0.08
345.0967407	0.33
347.0922241	0.11
353.1970825	0.38
365.2630005	0.50
367.1992188	1.52
368.9028931	0.07
377.7100830	0.06
383.3124390	1.56
395.1210327	0.05
405.7932129	0.03
406.6237183	0.02
407.2940674	0.09
409.4486694	0.09
410.3542480	0.02
411.6007080	0.09
413.2648926	0.04
425.2829590	1.48
427.1955566	0.12
443.2492676	0.10
444.4266968	0.03
445.3201904	0.08
448.8959961	0.04
459.5816650	0.07
461.4343872	0.08
466.9761353	0.12
475.1829834	0.03
481.9859619	0.06
487.1334229	0.21
497.0974731	0.06
499.1600952	0.05
501.3200073	0.04
503.2288208	0.05
517.2702026	0.04
525.1301270	0.06
526.7401123	0.04
527.9927368	0.03
529.4101562	0.03
531.2783813	0.12
540.8487549	0.13
541.4628906	0.88
542.8267212	0.02
544.8369751	0.39
545.4421387	0.15
547.3713989	0.09
553.4978027	0.08
556.2360840	0.88
557.4487305	0.03
559.3888550	0.17
571.2481079	100.00
571.8495483	0.80
574.3345947	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	771.1984
Annotation	Unknow
Peak:m/z	Relative Intensity
243.1029663	0.03
255.1587524	0.04
258.2041016	0.02
261.0136719	0.05
271.2450562	0.11
272.0928650	0.13
273.1502686	0.04
281.9569092	0.02
285.2339783	0.17
299.0565186	0.05
300.4458618	0.67
301.1964417	4.96
302.1499329	3.19
331.2618408	0.09
342.3010864	0.03
343.2374268	0.09
344.1768188	0.12
361.3036499	0.02
371.3002930	0.03
403.9934692	0.10
442.3923340	0.03
445.1591187	0.05
459.2664185	0.14
463.1812744	3.00
464.1896362	4.73
477.5172119	0.02
478.2542725	0.03
487.6362305	0.02
505.5105591	0.02
506.2337036	0.05
609.2744141	29.06
610.2385864	100.00
611.0202026	0.65
612.1185303	0.08
651.1410522	0.13
652.3781128	0.46
697.4710693	0.04
743.5718384	0.03
754.4343262	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.0856
Annotation	Alnustinol
Peak:m/z	Relative Intensity
89.0208359	0.08
91.3497238	0.05
102.8300323	0.10
107.0229645	0.08
109.6774826	0.02
111.0014420	0.29
116.9067764	0.44
119.0609741	0.08
120.9577942	0.10
122.9497147	0.15
124.7745209	0.36
127.1823730	0.03
133.0464783	0.08
133.9383850	0.06
135.2016602	0.04
137.0606689	0.87
138.1594238	0.07
144.9221344	2.91
147.1003723	0.09
151.0141296	5.25
152.9194031	24.99
154.1704102	0.15
157.3208313	0.03
163.0718231	0.20
165.0276489	0.03
174.9276733	0.69
176.9383240	100.00
178.9277039	50.48
180.8174438	0.02
182.8917847	0.35
189.1003723	0.05
191.0319824	0.07
193.0486755	0.24
195.0658112	0.02
198.1358948	0.20
201.0020447	1.06
203.2717590	0.04
204.7039185	0.05
208.9872437	0.12
214.5631714	0.05
217.1821899	0.34
219.0835876	2.36
225.0330505	0.08
227.0296021	0.03
229.1179504	0.18
232.5234375	0.04
236.9967651	0.14
241.0864258	0.05
243.2055664	0.75
252.9553833	0.15
254.4383240	0.03
257.0379028	0.10
259.2289124	0.21
261.0750427	2.82
267.0513611	0.31
271.2001648	0.36
273.2802734	0.03
275.0725098	0.17
285.0800476	16.39
286.2637329	0.10
288.0848389	0.42
289.4176636	0.01
302.8833008	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	542.73
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8158569	1.03
290.8257446	12.55
296.7167969	0.04
334.8153687	0.03
338.6351929	0.07
362.0651245	0.05
374.6428833	5.94
376.6742554	0.01
380.7165527	0.28
398.8689575	0.01
406.6159058	0.08
422.7280273	0.14
436.7171021	0.25
452.5358887	0.10
458.5531616	100.00
459.3680420	0.23
478.7744751	0.17
482.6395874	0.74
495.8015747	0.10
496.8187256	0.35
512.7809448	0.04
525.5538940	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.27
Annotation	Confertoside
Peak:m/z	Relative Intensity
177.1675110	0.11
212.8296509	0.40
231.0722656	0.20
247.0823517	0.23
263.1249390	0.07
286.6583862	0.31
293.2537231	0.24
301.0778809	14.63
313.3594055	0.26
321.0211182	0.11
339.1743774	0.12
343.0014648	0.32
344.8540039	0.10
356.3825073	0.07
357.0703125	0.24
359.2607422	0.31
367.2961426	0.17
375.1174316	4.69
379.1728516	0.06
392.8854370	4.79
400.4040527	0.22
411.1318970	0.87
415.1976929	0.12
417.1137085	0.50
425.2096558	0.26
429.1107788	1.01
433.1868896	0.47
446.2277222	0.19
447.1921387	0.78
463.0768433	100.00
463.7850342	0.19
464.9495850	0.26
481.2661743	0.10
495.4006348	0.07
521.2014160	0.03
533.3549194	0.10
534.3342896	0.37
545.4069214	0.13
547.3459473	0.21
549.6094971	0.21
555.0532837	0.20
565.2996826	1.08
570.6730957	0.05
573.2240601	0.56
586.2964478	0.54
590.9396362	2.11
591.7190552	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	811.2299
Annotation	Unknow
Peak:m/z	Relative Intensity
283.9873047	0.15
295.1510010	0.06
299.2597046	0.05
303.3412476	0.16
305.0897217	3.51
308.2517090	0.14
325.6875610	0.08
329.2358704	0.27
331.0597229	2.53
331.6723328	0.02
339.5353394	0.10
345.3031006	0.23
346.2104492	3.37
347.2011719	0.88
361.1526184	45.43
375.2391968	0.10
386.9965820	0.09
388.2135620	0.06
397.2047729	0.04
402.8931274	0.17
405.1302490	0.39
415.0330200	0.18
417.0041504	0.05
443.5251465	0.05
449.2431641	2.53
467.0783691	0.15
487.3197632	0.06
505.2044678	0.59
508.3713379	0.11
523.1567993	29.00
523.7766113	0.35
550.5245361	0.03
565.1206665	12.20
565.8381958	0.03
567.0355225	0.05
585.2155151	0.18
591.4798584	0.06
605.3476562	2.61
607.1314697	0.36
621.4052734	0.25
647.2373657	0.44
649.1000366	0.38
649.7145386	0.07
651.8888550	0.16
658.2123413	0.04
667.1242065	100.00
667.8052368	0.62
691.4238892	0.14
707.9393921	0.10
709.1808472	10.97
730.5463257	0.05
749.0657349	2.32
751.3206177	0.06
763.0561523	0.07
765.1259155	0.05
766.2670898	0.27
767.5913696	0.26
769.4898071	0.08
772.3534546	0.20
775.0086060	0.04
779.4071655	0.07
781.3552246	0.07
789.2145386	0.04
793.4766235	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	333.0825
Annotation	Dianthoside
Peak:m/z	Relative Intensity
124.9741669	19.96
136.9555817	0.04
148.9650269	9.48
153.2080994	0.03
159.1591492	0.07
161.0347290	0.06
178.8426514	0.09
185.8706970	0.05
191.1780090	0.31
197.1270142	0.07
200.7728577	0.40
207.0661316	0.09
209.0139465	0.34
227.0038452	2.30
229.0041199	1.36
241.1312561	0.04
245.1256714	0.18
269.1502991	0.07
272.6869507	0.21
287.0702820	100.00
291.1246338	0.05
315.0108032	0.94
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	635.2678
Annotation	Briaranolide B
Peak:m/z	Relative Intensity
182.1729889	0.51
182.9923401	0.13
186.8498993	1.10
189.0072784	0.24
194.9707947	0.15
197.1066895	0.27
199.0862579	0.27
201.0739899	0.30
210.8395691	0.05
213.1419067	0.87
215.2047729	0.06
217.0785675	0.26
221.1732483	0.42
227.1227112	0.59
229.0084839	0.29
231.0953217	0.28
234.9833221	0.14
237.0812073	0.59
240.8583374	0.06
243.3236694	0.59
245.5903473	0.10
251.0478363	0.14
253.1441956	0.06
255.2249908	0.05
257.1140747	0.23
261.3145752	0.21
266.8920288	0.35
283.2266235	0.42
291.5073853	0.17
293.2045898	0.73
296.9511719	0.22
300.1545410	0.11
304.1019897	0.52
305.1302185	0.82
307.1162109	0.90
309.0270691	0.55
310.3098145	0.11
311.3382568	2.35
313.2023010	0.22
317.1450195	0.30
320.3795166	0.28
321.2735596	1.17
322.1030884	0.16
323.1430054	1.14
327.1771240	0.46
329.2085571	0.20
333.1928101	0.14
335.2109985	1.22
337.4510498	0.08
339.1365356	1.24
340.4576416	0.41
341.2615356	4.06
343.1315308	0.31
347.1896362	1.51
349.2593384	0.47
351.2562866	1.47
353.0186768	0.07
357.1573486	1.45
359.3819580	0.20
361.3614502	0.07
365.1279907	1.15
367.2623291	5.84
369.1761475	27.56
371.4051514	0.08
374.0311279	0.07
375.3228760	1.09
377.2062378	1.17
379.0333862	0.49
380.1902466	0.18
381.1932983	0.17
383.2034912	1.23
385.2545166	2.01
387.5183716	0.27
389.1815796	0.12
391.3730469	0.54
393.1665649	3.22
393.7685547	0.18
395.1821289	4.08
397.0741577	0.28
399.1653442	0.23
401.2090454	0.10
403.2939453	0.20
405.1856079	0.33
407.3269043	0.08
409.2181396	4.27
411.1572876	10.17
413.2434082	16.64
414.7454224	0.12
415.4062500	0.26
417.1090088	0.95
419.2885132	0.73
424.6233521	0.17
425.6185913	0.90
427.1762085	12.65
429.2522583	7.34
431.2377319	1.08
437.2703857	3.93
438.5194702	0.33
439.3068848	0.24
445.2595825	0.28
449.2632446	0.64
450.9710083	0.23
453.1959839	3.97
455.3387451	9.80
459.3253784	0.17
465.4658203	0.43
469.4577026	0.13
471.7112427	0.35
473.1151123	9.45
473.7634888	0.15
475.0792847	0.34
479.3007812	0.95
485.5928345	0.27
487.5357056	0.46
489.0648193	0.22
491.1110229	2.00
495.1767578	1.53
496.3291016	0.11
499.6181641	0.12
501.2585449	0.07
503.1869507	0.44
505.5185547	0.21
507.0958862	0.65
509.2637939	0.12
511.1686401	0.31
513.2219849	0.23
515.2063599	1.02
517.2642212	0.65
519.3616333	1.26
521.2352905	0.54
524.5882568	0.38
533.0161743	0.44
535.3252563	0.79
537.5272827	1.18
539.3034668	0.22
541.3111572	0.55
542.4196167	0.90
543.2648926	0.37
545.3620605	1.22
549.2675171	2.38
551.5505371	0.07
553.2346191	4.92
554.0106201	0.05
555.2631226	3.71
557.1970215	1.06
559.1606445	0.06
560.2896118	1.26
561.5461426	0.06
563.1478882	0.99
568.9797363	0.28
571.3854370	21.57
572.6514282	1.50
573.2617798	7.37
575.7551270	0.22
581.2703857	7.93
589.3746338	100.00
593.5988159	0.57
594.3676147	0.07
598.7669678	2.11
599.3728638	17.08
617.2324219	59.71
617.8618774	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
174.0932465	0.12
198.843811	0.59
199.6640625	0.12
201.2022705	0.21
201.999649	1.05
203.0013733	0.59
215.3841858	0.15
230.3595886	0.09
239.8926392	0.63
241.9583435	1.44
257.5391846	1.49
258.2679443	0.57
268.1517334	1.48
283.091095	0.49
284.2102661	0.74
285.0288086	1.55
286.0859375	3.15
298.960144	1.35
301.0825195	100.00
302.0872192	0.21
307.1989746	0.26
313.4116821	1.32
321.2536011	0.54
340.2341309	0.33
343.3164673	0.61
360.0258179	0.29
365.2862549	0.35
369.0491333	1.45
393.0281982	0.37
399.1644287	0.61
428.8098145	0.24
435.2261963	0.22
447.0160522	0.29
454.1158447	0.25
460.2046509	0.51
471.2589111	0.10
473.2896729	0.50
483.317627	1.25
489.2233887	7.52
490.5033569	0.42
519.0661011	2.43
521.5359497	0.29
531.1149292	0.65
535.4786377	0.58
549.4820557	0.23
555.2335815	0.16
563.2058105	0.95
589.8167725	0.47
591.321228	2.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	833.2723
Annotation	Unknow
Peak:m/z	Relative Intensity
269.2575073	0.02
305.1753540	0.09
329.2273865	0.06
349.3486023	0.19
357.4425049	0.02
373.3787231	0.06
422.8101196	0.04
439.5067749	0.07
441.3543091	0.31
465.2420044	0.02
473.2019653	0.05
475.1844482	0.58
483.2175903	18.19
483.8378906	0.05
507.2374878	0.12
508.2886353	0.06
509.2174683	0.08
511.0152588	0.05
525.1611938	1.66
527.2721558	0.03
554.8997803	0.12
565.1611938	0.46
567.2199097	0.02
585.2273560	0.23
609.4895020	0.03
627.2238770	14.62
629.5816650	0.03
644.5186157	0.39
645.1539307	0.33
651.2874146	0.09
652.5126343	0.06
653.7087402	0.09
669.2271118	0.35
670.8704224	1.24
686.8927002	0.24
689.0793457	0.36
699.1072998	0.11
724.6211548	0.05
730.9529419	0.02
742.3778687	0.14
745.7529907	0.03
747.2478638	1.08
751.1949463	0.25
770.5273438	0.09
771.2263184	0.04
772.5781860	0.29
773.3587036	0.23
789.1518555	100.00
789.8534546	0.32
815.2478638	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.1588
Annotation	Luteolin 3'-methyl ether 7-glucuronide-4'-rhamnoside
Peak:m/z	Relative Intensity
187.1906433	0.01
194.9774475	0.07
201.1637878	0.06
204.8809509	0.03
217.0309143	0.02
229.1791687	0.01
256.1116943	0.01
257.2590637	0.04
261.2432861	0.12
271.2552490	0.04
273.1295166	0.11
274.9888306	0.03
283.2669373	0.02
285.1060791	0.24
287.3435059	0.07
288.7151489	0.01
302.1219482	1.26
313.3315430	0.02
315.0975037	0.03
317.0954590	100.00
320.3819580	0.01
323.0227051	0.04
324.8075562	0.02
326.3647461	0.03
327.3139038	0.04
333.2672729	0.02
338.3214722	0.01
341.2961426	0.24
356.2691650	0.03
359.1524658	7.13
360.7070312	0.03
363.4149170	0.02
371.1562500	0.05
374.2799072	0.13
375.2823486	0.08
377.2506104	0.09
383.2173462	0.45
391.2598877	0.01
395.3789062	0.01
400.9808350	0.01
403.1479492	0.01
407.1541138	0.09
409.0797119	0.02
413.3357544	0.11
417.2595215	0.04
425.2670288	1.04
435.1107178	0.02
437.4426270	0.08
439.3090820	0.01
442.4891357	0.04
443.4578247	0.11
461.1907349	0.78
471.6068115	0.01
476.2534790	0.17
477.0953369	0.04
479.3082275	0.11
485.1843872	0.06
489.2615967	0.02
494.1710815	0.11
499.2205200	0.01
504.4701538	0.01
506.6943359	0.02
525.1759644	0.06
527.1638794	0.09
532.3952026	0.04
538.8046265	0.06
540.6758423	0.02
542.7653809	0.07
543.3850708	0.08
545.5928345	0.05
550.3933716	0.02
551.0314331	0.02
560.4629517	0.02
563.2019653	0.20
566.9339600	0.02
569.0723877	0.38
577.1528320	0.07
578.4766846	0.03
579.4287109	0.02
587.2271729	1.03
605.1571655	7.47
605.7601318	0.04
608.9707642	0.06
613.8763428	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.1619
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
305.2780457	0.07
353.1389160	0.01
367.3106689	0.01
372.8098145	0.03
386.7729492	0.08
390.7833252	0.03
401.8873291	0.02
419.2160645	0.02
429.2422485	0.01
431.1214600	0.04
435.3428955	0.03
445.3870239	0.06
469.4491577	0.02
473.4558105	0.03
485.5841064	0.02
503.1943359	0.76
505.2141113	0.07
511.2733765	0.05
515.4566650	0.06
517.1199341	0.01
531.1762695	0.12
533.0764771	0.28
545.4069214	0.06
547.3084106	0.19
557.2158813	0.04
559.3090210	0.08
563.2003784	0.03
564.3649902	0.02
565.3532715	0.04
568.9260864	0.01
579.1667480	0.05
589.2305908	0.01
593.3398438	0.01
605.1226807	0.14
609.2333374	0.07
611.7933960	0.01
621.4299316	0.05
622.1270752	0.02
623.2955322	2.12
624.4187622	0.07
633.1547241	0.05
637.1591797	0.01
641.1834106	0.10
647.1636963	0.19
648.3091431	0.11
649.5667114	0.01
665.2044067	100.00
665.8522949	0.32
667.1138916	0.03
669.9867554	0.11
672.8904419	0.10
689.4635620	0.06
690.4109497	0.03
691.0354614	0.01
696.2962036	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	873.3401
Annotation	Unknow
Peak:m/z	Relative Intensity
273.0847778	0.02
287.4342651	0.07
303.2445984	0.04
311.2998047	0.04
319.3156738	0.03
331.3576050	0.12
335.5827026	0.12
341.3331909	0.03
360.0677490	0.08
361.4104919	0.03
363.2003174	0.05
365.3776855	0.01
373.3530273	0.01
375.1655273	0.23
376.1838379	0.09
377.0981445	0.03
393.3463135	0.16
399.3272705	0.02
415.2957764	0.07
417.3479614	0.14
427.0954590	0.20
445.3010864	0.93
465.2574463	0.04
471.3068237	1.09
489.2336426	1.59
493.2069702	0.02
500.0890503	0.05
513.0951538	0.11
517.0901489	0.12
520.4337158	0.03
523.2794189	0.09
531.3327637	0.18
537.1955566	0.06
549.3263550	0.08
555.4000854	0.09
561.2023926	0.22
567.5671997	0.02
573.5505981	0.02
589.2412109	0.02
591.3386841	0.43
621.0608521	0.01
633.4340210	1.36
651.3301392	4.42
661.3186646	0.01
668.9953003	0.03
675.2413940	0.02
693.3556519	0.89
706.3147583	0.02
711.3273315	0.44
717.2683105	0.66
717.9325562	0.01
726.9558105	0.07
769.3633423	0.32
813.3606567	100.00
814.5488281	0.04
829.3552856	0.11
851.2373657	0.09
855.2457275	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	223.0459
Annotation	Unknow
Peak:m/z	Relative Intensity
83.1700821	0.12
84.8972931	9.09
85.5675201	0.07
86.8988953	0.11
100.9245758	0.25
103.1647339	0.07
110.9875488	8.72
125.0265656	0.61
127.9005127	0.06
128.9534607	2.04
132.9455109	0.20
135.1754608	0.03
142.9193573	0.17
146.9550018	0.19
158.8404388	0.19
161.0191193	0.90
172.8966675	0.43
177.3860931	0.04
178.9751282	0.04
186.9569397	2.10
194.4939728	0.04
205.0447693	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	914.4741
Annotation	Kahalalide C
Peak:m/z	Relative Intensity
255.2587891	0.04
256.1716919	0.13
267.3066101	0.07
273.1779785	0.12
279.2510986	0.08
282.2680969	0.10
284.1433411	0.50
295.8304443	0.23
300.2550049	0.08
301.1407776	0.24
302.4236755	0.14
313.2990723	0.05
318.2575378	0.38
319.3116760	0.14
321.1112061	0.04
325.1509399	0.04
327.8572083	0.13
336.3897095	0.18
340.2778320	0.10
341.3551636	0.19
342.1578064	0.09
344.2460632	0.08
346.1209717	0.02
350.2365723	0.12
351.5405579	0.04
352.4324951	0.10
353.3447571	0.09
357.3373108	0.04
359.3058167	0.21
364.3765869	0.09
366.2036438	0.04
366.9869995	0.05
368.3100586	0.03
369.3528442	0.11
371.0671997	0.28
381.3597717	0.19
384.0548401	0.08
386.0538330	0.13
387.1101074	0.02
388.2862549	0.04
391.3678894	0.02
396.3369751	0.13
397.3853760	0.05
403.2456360	0.13
405.2093506	0.11
408.2883911	0.02
409.1924438	1.46
411.0564575	0.10
420.4674072	0.28
421.9538574	0.03
424.2761230	0.51
425.1016846	0.10
425.7377930	0.03
429.5158691	0.03
430.1644897	0.17
431.2956543	1.87
432.4323730	0.06
436.9867554	0.03
438.3320312	0.06
442.2910767	0.13
443.3724365	0.20
447.2655029	0.04
449.0839844	0.60
450.2108765	0.06
452.4609985	0.09
455.9849243	0.50
459.1912842	0.16
460.1050415	0.93
461.1115723	0.09
464.3420410	0.06
466.1864624	3.08
467.9909058	0.03
470.5833740	0.11
471.6434937	0.10
473.2321777	0.14
480.4134521	0.26
481.1531372	0.09
482.2902832	0.08
484.2418823	0.53
488.1859741	1.75
488.9721680	0.09
499.2573853	0.27
500.6341553	0.31
501.4918213	0.24
502.4061890	0.03
504.0005493	0.25
504.8784790	0.09
506.1965332	0.28
508.2000732	0.06
511.4159546	0.21
516.5245361	0.06
518.2788086	0.08
521.4075317	0.14
522.0123901	0.12
524.1925659	0.08
526.0612183	0.10
527.1119995	0.11
531.3143311	0.37
532.9918213	0.04
533.8137207	0.02
537.3892212	1.01
544.2600098	0.77
545.3611450	0.07
549.3151855	0.47
549.9602661	0.12
554.2604370	0.05
556.3988037	0.06
557.4713745	0.06
563.4700317	0.08
567.4391479	0.66
568.3537598	0.16
569.4403687	0.44
572.2174683	0.32
573.3209839	0.72
575.3488159	0.41
579.3755493	0.30
585.3571167	0.28
586.5616455	0.09
588.1824341	0.10
590.3275757	0.54
595.6262207	1.46
596.2472534	3.04
597.2674561	1.31
601.1484985	2.14
606.9935303	0.18
609.4980469	0.18
613.3329468	25.56
614.3508911	0.29
618.0964966	0.08
619.3202515	0.03
623.0365601	0.48
624.4132690	0.79
625.3348389	0.59
631.3069458	2.03
635.5156860	0.27
641.4341431	0.04
642.3656616	0.04
645.4120483	0.04
646.4832764	0.40
648.4035034	0.14
650.5249634	0.44
652.5979004	0.68
653.3532104	0.68
654.1826782	0.06
658.1672363	0.10
664.9146729	0.12
668.2742310	0.15
669.6104736	0.59
670.4852905	0.56
674.5598145	0.13
675.7037354	0.10
679.0064697	0.18
680.4838867	0.56
681.2046509	0.14
682.3695068	0.11
683.6847534	0.12
685.5212402	0.23
686.1500244	0.20
688.3324585	1.89
692.7351685	0.40
693.4720459	0.15
694.5036621	0.06
696.5511475	0.38
697.5336914	0.12
699.5886841	0.10
701.8576050	0.15
703.7800293	0.11
704.4611816	0.13
710.4347534	9.18
714.3155518	1.05
716.6204224	0.38
719.4985962	0.31
721.3266602	0.07
723.5490112	0.19
726.2006226	0.10
728.4801636	0.51
729.6390991	0.07
731.7584839	0.04
732.9713745	0.20
734.6444092	0.13
735.4027710	0.06
736.8454590	0.65
737.4642944	4.09
738.4407349	1.05
739.5278931	0.53
744.4070435	0.92
748.4357910	0.23
749.4208984	1.47
750.2748413	0.10
754.1692505	0.42
754.9522705	0.15
755.6286011	0.04
756.3187866	0.77
763.5018311	0.74
765.4005737	0.19
766.8142700	1.21
767.4684448	5.86
769.9506836	0.08
772.3687744	1.23
773.3954468	0.30
774.4453735	0.08
779.3502808	1.36
781.4058228	0.11
783.3055420	4.83
785.3318481	0.72
787.6692505	0.44
789.2888794	0.09
793.5667114	0.18
797.5234985	0.22
799.3262329	0.17
800.7861938	1.81
801.4262695	15.99
804.6068115	0.43
806.4362183	0.23
809.2153931	0.07
811.3451538	0.22
814.2704468	0.32
815.5849609	0.06
817.3973389	0.64
820.8746948	0.10
822.5256958	3.83
827.5396118	0.36
829.6543579	0.28
832.5277710	9.21
833.4708862	0.47
839.8987427	0.17
841.0847778	0.15
845.3882446	0.67
848.6364746	0.07
850.4696655	54.76
851.3574829	3.29
852.4502563	0.30
857.5258179	0.57
860.8741455	0.13
866.4100952	0.13
868.1951294	6.78
869.3672485	5.81
870.5165405	0.41
878.4265747	4.89
879.4266357	1.06
884.4082642	0.29
885.8543701	1.01
886.4821777	8.93
896.3779907	100.00
897.1387939	0.37
897.7775879	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.1953
Annotation	Malvidin 3-(6''-acetylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
207.1202240	0.01
230.8363037	0.02
241.2317657	0.01
254.9983215	0.04
262.0476685	0.01
284.2416382	0.04
287.3255005	0.01
293.2056885	0.01
295.1951294	0.02
301.1154175	0.02
305.1420593	0.08
312.3080444	0.03
318.2136841	0.06
329.5013428	0.05
330.1476440	0.24
331.2655640	0.02
332.2086792	0.02
333.1311035	0.30
334.2564697	0.02
338.7554932	0.03
340.1566772	0.07
343.1387939	0.21
345.3990479	0.03
347.8737793	0.01
358.1792603	0.37
359.3330688	0.12
361.1857300	2.87
363.1492920	0.07
369.3876953	0.02
376.1408081	3.56
376.7586670	0.01
383.2727661	0.01
387.3542480	0.01
391.1543579	100.00
391.7814331	0.41
405.2606812	0.01
413.3764648	0.03
420.9210815	0.06
430.8294067	0.05
431.5035400	0.03
448.9199829	0.02
469.0816650	0.02
501.1272583	0.04
504.8912964	0.01
517.3164673	0.01
530.1831665	0.02
532.8191528	0.07
534.0511475	0.01
535.2313232	0.11
538.6373291	0.03
540.2349243	0.01
543.6862183	0.01
548.1612549	0.01
551.0267944	0.02
551.9199829	0.01
552.9851685	0.13
555.1672974	0.02
556.9499512	0.01
565.1918945	0.04
568.2011108	0.01
574.9848022	0.06
577.4655762	0.05
589.3666382	0.01
595.3018188	0.05
612.8439331	0.06
615.3074341	0.07
623.0122681	0.01
623.7327271	0.02
625.3521729	0.02
631.5916138	0.07
643.4992065	0.01
661.0935669	0.12
679.1994019	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.2126
Annotation	Atalanine
Peak:m/z	Relative Intensity
221.2934265	0.20
233.0883636	0.13
233.7442017	0.03
262.7688599	0.19
268.7248840	0.12
307.9500122	0.06
323.0307922	0.30
324.2647705	0.10
341.1327515	1.17
342.2505493	0.24
383.2271118	1.74
412.7752686	0.95
413.4161377	0.15
425.0199585	0.09
443.0065918	1.68
443.8645630	0.33
449.1243286	0.11
466.8645020	0.14
487.2864380	0.04
503.2263184	100.00
504.2291260	42.91
504.9526978	0.05
552.1351318	0.10
631.5024414	0.67
632.1395874	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	920.4636
Annotation	Unknow
Peak:m/z	Relative Intensity
277.9242554	0.14
398.2814941	0.18
404.3958130	0.24
409.1397095	0.40
421.3255615	0.30
456.2319336	0.19
461.4753418	0.35
469.6318359	0.30
476.3446045	0.14
478.2503052	0.15
479.2223511	0.12
507.6187134	0.06
522.8729858	0.27
523.4787598	0.28
548.4555664	0.11
550.3135376	0.15
557.5525513	0.24
562.6541138	0.05
591.9826660	0.34
610.5244751	0.11
619.3848267	0.25
624.9596558	0.39
636.2590332	0.05
645.6102295	0.08
646.6720581	0.24
664.6162720	0.70
666.5550537	0.16
674.7507324	0.11
675.5787964	0.26
676.7346802	0.16
678.5941772	0.07
694.5233765	0.19
695.6840210	0.80
704.1599731	0.30
704.8425903	0.09
712.7500610	0.05
715.5148926	0.09
716.6291504	0.59
717.2632446	0.31
718.4894409	0.16
719.3042603	0.25
722.4006958	1.04
731.6296387	0.20
732.5734863	0.37
733.6508179	0.70
735.0349121	0.62
735.7086792	0.06
736.6348267	0.47
745.2866821	0.16
748.5609741	1.08
749.6538696	0.50
750.4986572	0.07
759.1650391	0.09
761.6348267	1.82
762.5348511	0.29
763.8234253	0.12
771.6712036	0.26
773.0675049	0.11
774.1182251	0.20
777.5429077	0.17
779.3674927	2.21
780.4653931	0.66
789.4098511	3.11
790.6757812	0.28
791.5924683	0.17
795.0108032	0.10
795.9257812	0.22
802.9686279	0.13
805.7855835	1.20
806.5704346	0.92
807.5393677	1.72
808.6036987	0.54
815.7068481	0.54
817.1119385	0.41
824.5785522	0.06
826.7445679	0.13
828.7863770	0.30
830.7167969	0.12
832.5816650	0.62
835.5336914	2.36
836.5406494	0.46
843.8324585	1.12
844.6177979	2.67
845.5883789	0.86
846.4254150	1.17
848.0808716	0.30
857.8113403	0.12
859.3996582	0.13
861.6757812	0.41
862.4978027	2.54
863.5769043	1.26
864.6011353	0.08
872.5204468	1.78
873.4927979	0.96
874.5730591	5.45
875.5748291	1.23
876.5664673	2.01
877.6856079	1.20
884.8831177	0.06
885.6433716	0.40
886.6214600	0.09
888.6901245	0.33
890.5082397	20.30
891.8433228	10.90
892.6386108	44.04
893.4778442	18.25
902.5139771	100.00
903.6278687	34.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.01835632	0.56
89.02224731	0.17
92.85112	0.12
95.02900696	0.58
102.9124146	0.67
104.9619141	1.17
108.9408112	1.73
111.003891	1.23
114.9538879	0.30
119.2601166	0.30
120.9171906	0.63
122.916748	1.73
124.8552399	0.13
126.102417	0.77
126.8551025	3.70
129.0739746	7.51
129.8915405	0.14
133.0099945	0.39
135.0918274	1.09
137.1482391	0.33
139.3023987	0.32
140.9946899	0.51
147.0476532	0.11
151.0305328	48.61
151.9762726	5.43
152.9875336	0.59
153.897171	0.59
156.9871368	1.06
161.0434265	0.26
162.7855988	0.38
164.9111786	1.13
165.9887543	0.72
166.9940643	2.11
168.8955231	0.86
170.3766327	0.18
171.1287079	0.32
175.1345673	0.60
177.0811615	0.78
178.1268005	0.17
178.9836426	1.91
180.0227509	0.19
181.2071075	0.52
181.9860229	0.10
183.1128693	0.32
185.0072479	0.88
185.9881134	0.21
188.9925842	2.17
190.995285	0.19
193.4514618	0.81
194.9097137	0.60
197.0355377	2.14
198.0437317	0.35
199.2507477	0.79
207.0914764	1.61
209.1860504	0.18
210.0517883	0.92
211.1094208	1.21
212.02742	0.16
217.1090851	1.51
225.1277924	7.06
226.0971832	0.15
235.1389771	24.13
236.1207886	0.93
238.0398407	9.35
239.1251984	0.92
251.1988678	1.16
253.0815582	100.00
254.1414795	11.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	296.97
Annotation	Unknow
Peak:m/z	Relative Intensity
102.9973068	0.05
107.1140213	0.06
109.1721497	0.18
119.1160583	0.03
122.9846115	0.04
135.4650116	0.06
138.8301697	0.04
144.9901733	0.03
158.8939972	0.02
165.0457458	0.07
171.0707855	0.04
177.1558838	0.03
179.1697388	0.17
180.8068695	0.03
182.8616943	2.68
183.9291077	0.19
193.9816284	0.10
195.3435974	0.08
200.9584656	0.04
209.2883301	0.10
211.1216431	0.04
213.9865112	0.12
214.9118652	0.20
219.1703186	0.03
221.3597412	0.03
223.0120850	0.26
224.2853088	0.03
225.0267334	0.19
228.0957642	0.07
233.0089111	0.02
235.3886719	0.12
239.0365601	0.29
241.2329102	0.12
243.3225403	0.09
244.1430054	0.19
249.2824097	0.03
250.1603394	0.21
251.1766052	4.20
252.6324463	0.60
253.5192566	0.28
255.6909790	100.00
256.4544373	0.37
265.0020752	0.10
266.9230347	0.23
268.7929382	0.85
269.5068359	0.11
271.4896851	0.20
272.5030518	0.85
273.6058350	2.14
274.7044373	0.24
276.4056091	0.20
279.1218262	1.89
279.8024597	0.08
281.1560364	0.78
282.3124084	0.47
285.1412964	0.50
286.9134521	0.26
288.3098755	0.17
291.7540894	0.17
295.0805359	0.09
296.7961121	0.26
305.5968628	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
128.801178	0.34
131.1026611	0.40
148.8641052	0.42
151.1065674	1.00
157.0242004	0.43
171.1402283	0.32
173.3103943	0.26
184.8919067	0.41
187.0863647	0.76
195.0726013	1.46
199.0167236	0.41
201.1550446	0.30
209.209137	0.15
211.4824219	0.22
215.2739868	0.91
217.3731689	0.81
221.1398621	0.20
227.1970825	0.45
229.2074585	1.98
231.0963745	0.61
241.1473999	1.65
242.9878235	2.24
252.7569275	0.28
255.2514954	0.14
257.3542786	1.58
259.1699219	0.66
263.3615112	0.26
271.0786438	1.07
273.2028198	0.35
279.3590393	0.42
283.2403564	0.94
285.1051025	4.11
295.0581665	0.80
297.3563843	1.99
299.3702698	1.15
301.2245178	0.58
311.2279663	0.39
313.5471191	0.09
321.239624	0.46
323.3887939	7.53
325.4066162	1.02
335.3728333	0.28
339.2444763	100.00
340.5374146	1.62
341.359436	9.59
342.1020813	0.44
343.2640076	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	549.1232
Annotation	Pratensein 7-O-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
193.1259003	0.04
243.0544739	0.12
255.1026306	0.05
263.2905273	0.11
264.3604431	0.05
273.3096924	0.02
298.5068359	0.03
301.1207275	2.61
301.8027344	0.09
313.2420654	0.28
322.1996460	0.05
325.1851807	0.82
339.2578125	0.08
343.1583862	30.93
344.0286255	0.11
351.5420532	0.15
355.2797852	0.05
357.2902832	0.09
358.2782593	0.02
361.0964355	0.04
367.1014404	17.37
369.2145386	0.09
379.0709839	0.21
380.2220459	0.09
385.2949219	0.07
387.1663818	0.08
389.3218384	0.05
391.2121582	0.37
395.2092285	0.04
397.0094604	0.65
399.4360352	0.03
400.3100586	0.14
409.1950073	7.15
417.3046265	0.06
425.2208862	0.09
427.1696777	1.22
445.2195435	7.95
451.2122803	0.12
453.2824707	0.28
459.2937012	0.03
463.1968994	3.78
469.2960205	1.34
483.4170532	0.06
487.2203979	3.17
489.2730103	0.10
490.0775757	0.03
495.2604980	0.29
502.8615112	0.08
505.1511841	0.89
513.1279907	42.39
513.7348022	0.63
516.3421021	0.04
517.6847534	0.01
520.0297241	0.06
531.1432495	100.00
532.1748047	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.1906
Annotation	WF 14865B
Peak:m/z	Relative Intensity
104.9036179	2.10
108.8775940	0.37
120.8606720	0.05
126.8657074	8.22
144.9036255	0.92
146.9779510	0.14
158.9983826	0.12
165.0838623	0.12
166.9380493	0.05
176.9331055	0.09
178.9573975	0.02
179.8648376	0.12
182.3919525	0.06
189.2239838	0.12
191.1003113	0.09
210.9422607	2.00
212.8607178	0.97
219.0709839	0.14
230.4294434	4.45
231.0443115	45.38
242.2619019	0.04
247.4428101	0.31
248.3737488	5.22
249.0339966	22.11
264.1865234	0.03
266.1082153	2.83
267.1717224	0.15
269.0306396	0.09
271.3562622	0.03
281.9873657	0.28
297.1136475	0.28
304.1937256	0.12
307.0789185	0.11
311.0121155	0.05
313.1419067	0.17
315.0080566	34.78
315.6720886	0.13
318.8078308	0.04
322.2141724	0.02
325.1396484	0.04
326.1289673	0.08
327.8337708	0.11
332.8358154	100.00
333.5960083	0.22
340.2884216	0.31
350.6191406	2.57
351.4352722	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	680.2201
Annotation	Unknow
Peak:m/z	Relative Intensity
204.1270752	0.11
222.0683746	0.39
224.1235046	0.75
228.2845764	0.06
240.1485291	0.32
242.1050720	0.16
252.1735840	0.20
255.1773682	0.14
258.2457581	0.12
270.0964661	3.15
288.2056885	4.06
288.9827576	0.45
306.1487427	7.98
321.0665894	0.50
324.1319580	100.00
324.7748413	0.69
338.2047119	0.35
339.0545044	0.47
356.7004395	0.51
372.3073120	0.20
385.6908569	0.22
480.0372925	0.21
488.4355469	0.30
500.1989136	0.83
505.3928833	0.06
518.1635132	6.33
533.3010254	0.38
534.3110962	0.69
560.4692993	0.14
595.6893921	0.06
607.0362549	0.71
633.8906860	0.22
662.3043823	0.16
679.6128540	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	845.2308
Annotation	Unknow
Peak:m/z	Relative Intensity
243.0507812	0.16
245.0708466	0.28
259.1850586	0.13
260.1733704	0.18
270.0867615	0.04
271.1399536	0.11
272.9895020	0.02
274.2533569	0.08
276.0703735	0.13
287.0993042	0.53
289.1431580	0.16
291.0875854	0.07
297.9609985	0.04
301.1842651	0.03
304.2697144	0.20
306.1810913	0.02
313.0474243	0.07
314.9636841	0.09
316.1890564	0.32
319.1020508	4.02
329.0270996	0.22
332.3627930	0.04
343.0300903	0.04
344.0542603	3.09
345.0466614	0.07
346.0422668	0.05
347.1791382	5.87
349.0770874	0.03
354.3180542	0.13
359.0847168	0.05
361.1115723	0.18
362.2204590	3.36
363.0543213	0.02
366.9133301	0.11
377.1232300	100.00
377.9714050	0.07
379.0027466	0.02
387.0769348	0.07
397.3270264	0.04
415.2595825	0.32
431.0277100	0.03
433.3482666	0.32
450.8877563	0.11
519.2951660	0.11
579.4508667	0.02
623.0083618	0.37
634.9456177	0.03
662.3602905	0.05
664.9920654	0.08
683.0441284	0.19
690.3064575	0.05
692.8979492	0.07
715.2820435	0.19
725.2576294	0.05
728.4771729	0.03
772.1118774	0.09
779.2605591	0.11
782.0661011	0.05
783.3950195	0.17
785.0222778	0.10
785.7228394	0.09
790.6345825	0.27
791.2531738	0.67
792.7620239	0.04
808.7742920	1.20
809.7957764	0.03
826.4916382	5.82
827.1133423	22.65
857.2804565	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1719
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
173.0123291	0.59
177.1282501	0.19
181.3654022	0.23
190.9897614	0.26
207.0352173	0.17
225.1494446	12.17
258.8213806	0.96
279.1903076	0.34
285.3606567	0.69
289.4032593	0.39
323.3474121	0.28
337.2904663	0.45
341.4301758	0.23
357.4142456	0.15
367.1991577	1.25
385.3466797	0.46
387.1140137	100.00
411.2394409	0.21
429.1894531	8.76
430.1274414	0.16
469.0762939	0.25
471.0983276	0.36
485.2324219	0.13
487.5363770	0.40
489.3925171	0.16
499.2957153	0.47
513.6445923	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
204.1592102	0.06
212.8666992	0.57
216.6855469	0.06
233.1362	0.35
269.2426758	0.11
273.0431519	0.31
301.1134644	13.41
302.9178467	0.05
313.0576782	0.21
315.920166	0.10
325.2351074	0.26
331.187439	0.32
339.274353	0.14
343.3936768	0.18
357.3677368	0.56
358.0003052	0.13
361.1380005	1.04
365.1470947	0.08
370.0394897	0.22
375.0772095	1.85
377.1275635	0.17
392.921875	0.66
399.0195312	0.25
403.1656494	0.17
423.2452393	0.27
429.211853	0.25
437.6791382	0.16
445.217041	0.22
447.1000366	2.17
463.1107788	100.00
464.5606689	0.25
468.8770142	0.24
478.901001	0.21
512.4830322	0.05
519.1224365	0.30
540.0838013	0.08
542.550354	0.06
549.258606	0.11
551.3869629	0.18
552.9726562	0.14
561.0333252	0.42
563.1016235	0.19
564.03125	0.33
565.3056641	0.66
574.9933472	0.17
579.052063	0.52
591.1919556	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	815.2198
Annotation	Faratroside
Peak:m/z	Relative Intensity
229.2087402	0.25
232.8900452	0.12
259.4724121	0.09
260.9662170	0.15
271.0477905	0.32
272.0022278	0.41
273.0656433	0.88
274.9728394	0.07
283.1837158	0.06
285.0996704	0.06
287.1777954	0.67
289.0950928	1.43
295.0923462	0.06
299.9107666	0.73
301.1122131	1.90
302.0993042	0.30
304.1114502	0.05
306.7254028	0.16
313.1788635	0.07
314.2655029	0.43
315.1930542	0.73
316.8284607	0.51
331.1073303	0.58
332.2158203	7.68
347.0892944	100.00
347.6893311	0.66
373.2954712	0.07
379.0722961	0.12
389.1369629	3.59
396.9007568	0.12
405.2894287	0.12
413.0461426	0.16
415.2922974	2.68
433.2304688	2.54
451.0651855	1.14
454.9995728	0.45
476.4771729	0.05
490.9433594	0.52
508.2435913	0.14
539.1907349	0.20
563.1810303	0.14
565.1538696	0.20
592.9763794	0.86
599.1422729	0.13
617.0595703	0.18
635.0287476	0.87
649.1127930	0.08
653.1305542	0.06
657.6104126	0.20
665.9569092	0.18
679.3383789	0.19
725.5132446	0.13
760.6561890	0.26
761.2636108	2.47
779.1392212	9.84
783.5234985	0.52
796.9872437	85.35
797.7562256	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	265.09
Annotation	Unknow
Peak:m/z	Relative Intensity
81.0838165	0.58
82.7089539	1.32
84.9707489	12.13
86.9702301	1.65
88.9960480	22.77
94.9044952	1.36
96.9643860	0.61
99.0795593	0.79
100.9589233	22.15
102.9334259	100.00
105.9243164	0.30
112.9024506	23.55
115.1521759	0.54
116.9754486	1.56
118.9210052	16.42
125.0025940	2.40
129.2343750	0.22
131.0065460	2.89
142.9831390	7.13
145.0451050	11.91
146.9755707	0.52
148.9776459	2.41
157.0870972	0.49
158.9519958	0.47
161.0049591	6.50
175.1285095	3.61
178.9162445	8.35
181.2614594	0.18
187.1587982	0.26
199.1709595	0.78
205.2472992	0.49
247.1563873	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1816
Annotation	2',4',4-Trihydroxy-3'-prenylchalcone 4'-O-glucoside
Peak:m/z	Relative Intensity
136.9922485	0.19
144.9674683	0.89
146.0550385	0.28
147.0370483	1.20
150.1629333	0.24
155.1443176	0.17
156.9518127	0.12
160.9737854	1.34
162.1164703	0.06
163.0147705	0.82
165.0865173	4.61
166.9891510	0.08
169.1669159	0.46
171.1412659	2.11
173.2213745	3.12
174.1153870	0.43
175.0993652	2.13
176.0132599	0.32
177.2463379	0.92
179.2062073	0.27
181.1084747	0.22
183.1327667	0.35
185.1235962	1.18
186.0875244	0.12
187.1588440	0.60
189.0882568	0.54
190.1604309	4.03
190.8369751	0.37
193.1526489	0.11
195.1809387	0.11
196.0971069	0.48
196.9865112	1.10
198.2197266	0.54
199.0298157	0.61
201.1551208	0.99
202.0330505	0.19
205.1637573	0.16
207.4709778	0.17
208.9149628	1.70
211.1478577	1.25
213.1588440	4.16
214.1557617	0.14
215.2184448	0.68
217.0308685	3.03
218.0367432	9.12
219.0669250	6.35
221.0661621	0.89
223.2293549	3.19
224.1867371	0.81
225.0970306	2.02
226.1822968	0.72
227.0943298	1.41
229.1127319	1.63
231.0687256	0.64
233.1479034	0.45
235.0019531	0.34
237.1387329	1.58
239.1525269	6.03
241.2184753	2.55
243.1156921	0.65
245.3669434	0.24
249.1016235	3.18
250.2407532	2.10
251.2192383	2.68
252.2582397	2.64
253.1481934	4.17
254.2277527	0.46
255.1829834	3.48
255.8684998	0.21
257.1012878	0.84
258.3750610	0.13
259.1298218	0.43
261.1912231	0.52
262.2098389	0.06
263.2073669	0.50
263.8341064	0.25
265.2285461	6.89
266.4079590	2.11
267.1683044	9.55
269.1854553	0.37
270.5700073	0.92
271.3009644	0.57
272.8744202	0.76
275.3126221	0.83
276.0893250	0.87
277.2254028	4.07
278.4366455	1.16
279.2594604	3.27
280.7195435	0.51
281.4449463	0.59
283.2478638	3.15
285.2196960	1.03
288.1104736	2.36
288.7686462	0.15
289.4587402	0.44
291.2094421	0.85
292.2554321	0.66
293.2712708	7.71
294.3897400	0.49
295.1465454	1.78
297.4069214	0.49
298.2171631	0.16
300.2208862	0.32
301.2839966	1.08
302.2171631	0.21
303.2665710	3.40
305.1838074	1.42
306.2344971	9.74
307.3274536	3.14
308.3576660	2.88
309.1994629	5.25
311.2304688	3.62
313.3211670	1.11
317.1727600	0.43
318.4478760	0.99
319.2156372	1.18
321.2308655	19.17
323.3129578	1.65
325.3343201	2.54
326.1952820	0.24
327.3551636	1.38
329.2314453	6.93
331.1566772	1.17
333.2641296	1.24
333.9414368	0.57
335.3278809	3.59
336.3659058	1.09
337.3912964	1.59
339.2714844	6.05
341.4390564	0.20
345.2096863	2.14
346.3168945	1.73
347.1141052	0.38
349.2797852	1.03
350.1903076	0.18
351.2652893	3.40
352.2678833	0.25
353.2929077	1.55
354.3365173	0.98
355.2826538	0.60
358.1985474	0.26
361.3473511	3.25
363.1616211	1.70
364.3129578	5.36
365.3915100	0.45
367.2153931	3.60
367.8565979	0.28
369.2481689	3.19
371.1566772	0.50
373.3155212	2.00
377.3612976	0.09
379.3433838	23.12
380.3450623	0.45
381.3851624	0.33
382.2539062	1.30
383.1595154	2.46
385.4832458	0.43
390.5274963	0.12
393.1421814	0.18
395.3490906	1.68
397.2352295	4.77
398.2961121	0.16
399.2020569	0.61
409.2637634	0.11
411.3721619	3.09
413.0521545	0.66
413.7109070	0.36
415.3458557	0.20
423.3036194	13.73
425.2195129	0.33
426.3962402	0.34
427.4566956	0.54
429.3763428	1.68
439.1218567	0.92
441.2492065	100.00
441.8529968	0.30
443.4806519	0.15
457.3291626	0.91
467.4001160	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	256.08
Annotation	Nicotinate D-ribonucleoside
Peak:m/z	Relative Intensity
79.9626846	0.01
86.9058533	0.01
87.9715500	0.02
94.8757935	0.01
96.9148102	0.02
99.1391067	0.03
110.9154510	0.06
117.9441071	0.02
123.9455566	100.00
124.8210907	0.02
126.9051819	0.04
129.9499664	0.10
133.0019379	0.38
139.9456329	0.05
141.0109100	0.03
142.0974731	0.01
156.0282135	0.04
156.9610138	0.02
168.1484528	0.15
185.9831085	0.06
186.9289703	0.02
192.0185547	0.01
194.0504913	0.02
196.1867065	0.03
200.0619202	0.02
210.0783844	0.20
211.3547821	0.02
212.0720978	0.06
213.0839996	0.04
215.0118866	0.01
218.0432129	0.11
220.2367096	0.06
220.8935699	0.03
226.1426849	0.02
228.2964020	0.15
238.0566864	0.37
239.1816864	0.02
246.9252319	0.28
247.7731323	0.03
256.2138672	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3068
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
151.1276855	0.09
154.9339142	0.20
165.1241608	0.13
175.1493683	0.34
198.1519928	0.53
209.4493866	0.11
216.0477142	0.22
235.9591675	0.05
239.0805206	0.05
259.3481445	0.33
265.2701416	1.68
279.315918	0.25
285.1225281	0.34
291.2702026	0.21
294.3030396	0.05
305.3296509	0.67
308.4726562	1.61
310.197937	0.08
318.1390991	0.42
326.3018799	0.08
329.7776184	0.07
339.2853088	89.09
339.9241028	0.24
342.5529785	2.95
343.2479248	4.95
344.1910706	7.31
345.0084839	0.10
351.0670166	0.16
377.4900208	0.31
382.044281	0.12
418.9897461	7.44
419.6109314	0.26
436.8465881	0.81
444.5709839	0.12
449.423645	0.27
462.2191772	100.00
463.181427	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	389.1432
Annotation	Arborescoside
Peak:m/z	Relative Intensity
131.6903992	0.27
132.7276764	0.17
167.0142517	9.54
176.0933228	0.22
189.1119080	0.25
191.0180359	1.25
196.7948303	0.15
207.0507507	0.81
209.0021362	12.40
221.0573425	0.62
227.0812378	100.00
231.1783142	0.46
239.1890869	0.13
251.0395813	12.16
251.6828613	0.44
263.1182861	0.19
265.3049927	0.37
268.4109192	0.24
269.1231384	0.56
275.0714722	1.89
285.2003174	0.16
287.7567139	0.32
293.0498047	14.51
305.1759644	1.07
308.1706543	0.48
311.5894165	0.14
313.3280640	0.11
317.2223511	3.61
321.0175171	0.30
323.1911316	0.43
329.3161011	0.36
331.4550781	0.37
335.1244507	11.74
343.2501221	0.58
344.9954834	0.65
346.0621948	0.45
353.0227661	4.45
359.3197937	0.21
371.0928650	6.19
372.0871887	0.42
375.3742676	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.2135
Annotation	Barbatoside A
Peak:m/z	Relative Intensity
189.0897980	0.04
206.0137024	0.02
206.9764099	0.02
212.8511047	0.04
217.9544373	0.12
219.1797638	0.06
235.1179047	0.05
235.9816284	0.23
265.1247559	0.01
267.0484619	0.03
273.3054199	0.01
277.2046814	0.11
279.2705688	0.01
321.1109009	1.84
339.1666870	3.17
351.1771851	0.18
358.9608765	0.08
363.0998535	0.01
398.2019653	3.78
428.3373413	0.04
429.1981812	0.01
439.2557373	0.07
441.3858643	0.08
447.2830200	0.04
483.3181152	0.40
491.4035645	0.03
495.1922607	0.16
501.1781006	100.00
501.8541260	0.19
511.1396484	0.03
516.7628174	0.03
519.1513672	0.22
525.4368286	0.04
537.5748901	0.03
542.1078491	0.11
561.2730103	0.25
567.0317993	0.06
573.2545776	0.02
577.3706665	0.12
585.1506348	0.03
616.8756714	0.01
619.3414917	0.05
627.1514893	0.03
645.2958984	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.157
Annotation	Desethylchloroquine
Peak:m/z	Relative Intensity
84.7372818	0.06
86.9493561	0.13
87.8513184	0.07
91.0817490	0.08
93.0283279	1.03
95.0707550	0.30
96.9739075	1.26
102.8133545	0.05
104.8784561	0.15
107.0062332	0.98
109.0131531	1.91
118.0815964	0.10
121.9521942	4.99
122.8997116	0.05
126.9931564	0.05
129.9204712	0.02
131.9541321	0.12
134.3344421	0.59
135.0297852	2.41
139.9785309	0.05
141.0642090	0.19
143.3636475	0.03
146.9131775	0.04
148.3735352	0.03
153.0978088	33.86
161.3602448	0.09
162.9997559	0.08
166.9878082	0.31
170.9905548	1.02
182.1046143	0.01
185.0351562	0.02
187.0905304	0.87
190.0273285	0.04
191.0940552	0.08
192.3009644	0.08
195.2052612	0.08
196.1890564	0.02
202.1054077	0.03
204.1862793	0.03
205.0697327	0.14
211.3125610	0.03
220.2850037	0.06
220.9012756	0.04
222.1522522	0.09
226.6113892	0.14
227.8796082	0.03
230.1096497	0.03
233.8663330	0.02
237.3147583	0.05
239.0135498	0.14
243.3439941	0.17
244.1067200	0.46
246.2955322	0.19
248.0969543	0.10
249.0961914	0.09
250.9704285	0.02
256.0682983	6.89
257.0413818	0.49
261.2290344	0.10
262.1768188	0.14
263.9697266	0.09
269.0620728	0.11
272.2337341	0.05
274.0667725	100.00
275.1454163	0.24
277.8875427	0.02
283.2734070	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	715.2454
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
328.8012695	0.02
357.1376953	100.00
357.7690430	0.10
358.3701172	0.18
432.2501831	0.04
433.2362671	0.06
444.0446777	0.03
447.0649414	0.03
451.0223999	0.20
506.0619507	0.04
534.9052734	0.05
552.3822632	0.09
553.1072388	0.02
627.6579590	0.04
671.5530396	0.10
697.2262573	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	282.1539
Annotation	Eccremocarpol B
Peak:m/z	Relative Intensity
83.8032303	0.13
84.8906250	5.72
91.9929810	0.03
92.9828644	0.05
94.8587112	0.04
96.7908936	0.34
109.0408096	0.20
111.1732254	0.07
114.9658127	0.99
119.9714355	0.47
121.0021210	0.66
126.7832489	0.65
127.9509888	0.15
129.2292786	0.03
130.7716370	0.08
134.7826233	0.07
136.9937744	0.17
144.9741516	2.16
147.0513306	0.18
149.9910278	1.03
151.1864624	0.51
151.8948669	0.06
152.9594727	0.03
153.9487457	0.07
154.8484192	0.12
162.2508850	0.90
162.9372253	8.34
164.6439209	0.10
166.0187683	0.11
166.8644714	0.15
168.4595947	0.69
169.4061127	0.33
170.0464172	0.12
170.8931732	0.38
172.1683350	0.19
174.8025818	0.08
176.3465881	0.15
178.6935425	0.03
180.0553589	1.85
180.9451599	0.94
182.0498199	0.10
183.1962585	0.16
187.0121155	0.16
188.8985291	0.12
191.0539551	0.39
191.9942322	1.10
193.0472717	0.24
198.1456909	0.26
200.1072083	0.16
200.7247314	0.47
202.1537170	0.13
204.1470337	0.05
205.9070740	0.03
207.6498108	0.51
211.0866394	1.51
212.2370300	0.15
214.9940796	0.35
217.2667236	0.16
218.2230530	0.11
219.4991760	0.08
226.3385010	0.21
228.9641724	100.00
233.0215454	0.09
235.1961365	0.09
236.1033325	0.30
237.0307007	0.16
238.0008545	0.10
239.0689697	0.09
240.2836609	0.24
241.1954956	0.27
244.5801697	0.17
245.4395447	1.28
246.0864868	2.37
246.8629761	21.95
251.4450073	0.18
254.2059326	0.26
255.0358582	0.09
258.1840515	0.20
262.2656555	0.12
264.1754150	5.76
265.0918884	1.20
266.0534058	0.43
267.0346069	0.32
273.0134888	1.22
273.7031250	0.12
283.3702698	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	685.2996
Annotation	Unknow
Peak:m/z	Relative Intensity
192.9028625	25.89
193.9365692	3.60
195.1301270	2.10
196.2852783	0.56
204.9680023	0.07
209.9600677	0.18
220.8334198	0.28
230.7858124	0.35
233.0328064	0.62
243.0091400	0.41
244.4182587	0.82
245.2397308	0.32
246.0715332	0.11
259.0802307	0.16
261.1145325	0.29
270.8798218	0.32
272.7807007	0.07
279.2427979	0.34
287.1288147	1.92
288.3099976	0.25
289.3585205	0.49
290.1171570	0.24
300.9131775	0.22
302.1301575	0.14
305.0333862	0.28
312.8209839	0.25
314.3925171	0.73
315.1166992	3.17
316.3044434	3.98
317.0836182	8.13
318.2002563	2.27
319.0150757	0.07
325.2326660	0.19
329.0733032	45.22
330.1836548	8.53
331.1413879	0.66
343.1044006	0.26
354.4367065	2.66
355.2091675	1.01
357.0474243	0.95
358.1588135	0.43
367.1290894	0.10
369.2695312	0.19
379.1051025	0.58
382.1456909	0.91
383.1704712	1.50
384.1520996	4.06
385.1745605	21.28
386.1578369	66.09
387.1588135	9.43
388.1850586	0.56
395.3064575	0.12
399.1622314	0.09
405.5731812	0.26
422.1470337	1.35
423.0726318	0.62
429.4862671	0.08
438.0541382	0.10
439.0989380	0.16
439.9884033	0.54
441.4226074	1.05
446.4161377	0.07
452.0768433	3.69
452.9480591	7.99
453.6783447	1.63
455.1906738	0.92
456.2144775	0.35
460.3308105	0.11
461.1692505	0.57
480.8843384	16.96
481.7541504	1.18
490.9439697	2.16
495.0601196	0.14
503.5108643	0.53
513.4577026	0.39
515.2175903	0.31
516.3494263	0.23
520.0375366	7.43
520.7838745	20.12
521.4945068	4.77
522.4553833	0.36
523.5394897	0.17
524.9579468	0.40
540.9200439	0.47
541.6210938	0.45
542.3416748	0.09
548.8947144	41.59
549.6469116	9.45
550.3080444	0.06
558.0103760	0.81
558.7435303	0.11
560.1594849	0.13
561.7028198	0.27
575.1890259	2.01
576.9649048	8.21
577.9000854	1.73
578.6670532	0.41
579.3778687	0.20
583.2444458	0.64
589.5421753	0.25
594.2507324	0.44
608.0987549	0.07
609.4084473	0.62
614.3076782	0.12
616.9301147	100.00
617.7001953	14.93
618.3634033	0.68
619.0126343	0.64
621.5127563	0.27
623.0496826	0.35
629.0115967	0.23
629.6823120	0.45
630.3745117	0.29
631.1182861	0.89
632.0779419	1.63
633.9838257	0.65
651.0767212	0.27
654.4648438	0.20
657.0910034	0.41
663.4853516	0.19
666.9568481	0.30
667.9183960	0.78
692.9957275	0.19
695.1725464	0.09
701.4113159	0.43
710.2851562	0.38
711.1502075	3.20
712.2026367	5.48
713.2407227	22.61
714.5309448	22.87
716.3739624	0.17
739.3901367	0.07
753.8585815	0.15
766.3776855	1.32
767.1611938	4.71
768.0902710	4.57
769.0245972	7.61
769.8974609	3.93
770.7612915	0.30
778.5874634	0.10
780.3043213	0.81
780.9169312	0.22
781.5515137	0.16
806.4680786	0.37
836.0994263	0.63
836.7369995	0.17
849.7313843	0.89
850.4402466	0.64
851.3555298	0.89
902.2366333	5.70
903.0750122	24.28
904.0645142	37.18
904.9829712	69.02
905.9863892	29.86
906.7832642	2.05
919.0822144	0.36
921.8826294	0.28
922.7116699	0.16
933.2482300	0.36
939.7645874	0.22
943.0300293	0.97
944.5708008	0.28
959.2711792	0.15
960.1381226	1.26
961.0068970	0.93
962.3505249	0.34
973.2709961	0.56
980.0312500	0.42
1027.9114990	0.15
1028.8822020	0.55
1040.0651860	2.91
1041.2519530	13.36
1042.2536620	3.56
1043.2213130	1.94
1095.9504390	5.74
1097.1097410	4.02
1098.2490230	0.50
1108.4184570	0.22
1232.0106200	3.11
1233.2011720	5.72
1234.2166750	1.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	1096.5208
Annotation	Unknow
Peak:m/z	Relative Intensity
327.3845215	0.07
329.3670959	0.09
336.4974060	0.09
341.8656616	0.51
345.3330078	0.25
351.3541565	0.17
353.1302490	0.08
354.3486328	0.12
356.2685242	0.12
358.3132019	0.14
367.3883362	0.89
369.3952637	0.24
370.2835693	0.09
372.9685669	0.04
381.4744263	0.20
394.5853882	1.59
395.2640381	1.76
396.2356262	0.95
397.3340149	1.59
398.2500000	1.47
401.4908447	0.13
402.3035278	0.39
403.5010681	0.05
407.3595276	0.13
412.2280579	2.22
413.2080994	1.20
419.2003174	0.70
420.2082520	1.03
421.6498413	0.28
422.3854370	0.26
423.2211914	0.25
429.8895874	0.63
435.1947632	0.71
436.2055359	0.67
437.2239380	0.45
440.1228638	2.78
441.2257690	1.41
442.9893494	0.21
447.1630859	5.07
448.2185364	1.74
450.2036743	0.19
458.2548828	0.08
461.5542603	0.05
463.3577271	0.32
464.1564026	3.28
465.2890015	0.95
471.3440552	0.19
473.0560303	0.45
477.2280884	0.16
480.4288330	0.92
481.2799988	1.08
485.3462830	0.50
486.2479858	0.82
487.0744019	0.55
489.5368652	0.30
492.3240356	0.16
494.3406372	0.99
495.4020386	0.22
502.5225220	0.15
508.3227844	1.40
509.3312988	1.30
510.3409424	0.63
512.4846802	0.42
513.3796387	0.69
514.4683838	2.77
515.3486938	2.16
516.3082275	1.85
519.1604614	0.16
530.2097778	1.19
531.3271484	0.83
533.4936523	0.10
537.0650635	0.16
537.6945801	0.23
538.3593750	0.39
539.3049927	0.48
551.3752441	0.19
553.8500977	1.19
555.3022461	0.76
558.3863525	1.23
559.3375244	1.02
564.0733643	0.04
567.5747070	0.14
568.2012939	0.39
571.0546875	0.37
575.5786133	0.29
577.5985107	0.72
578.7650146	0.30
580.7564697	0.15
582.2619629	1.17
584.1766357	0.22
584.9259033	0.16
586.6613770	0.39
588.3688965	0.65
589.4171143	1.13
590.1790771	0.26
598.2343750	0.25
599.1422119	0.24
601.2456055	0.51
603.2403564	0.11
604.2159424	0.16
605.1494141	2.93
606.2064209	2.73
607.5275879	0.07
608.3000488	0.20
610.3835449	0.08
611.6889648	0.14
612.3994141	0.07
613.4318848	0.19
614.3216553	1.32
616.4780884	0.44
618.0532227	0.58
618.6801758	0.31
619.4779053	0.14
621.2757568	0.27
622.3797607	4.45
623.3135986	2.54
626.3835449	1.24
627.3255615	0.76
628.2983398	1.03
630.3051758	2.01
632.5809326	0.51
633.5103760	1.78
634.4274902	1.09
640.4880981	0.49
644.5200195	0.52
646.3172607	0.28
647.2748413	0.06
650.3303223	12.74
651.4371948	16.65
655.3209839	0.40
656.1905518	0.83
657.3518066	5.59
658.3895264	4.81
663.5234375	0.45
666.4465942	0.10
667.4598389	0.32
668.3182983	0.12
671.2626953	0.25
672.4259033	6.11
673.3861694	6.32
674.4312744	0.97
675.3928833	2.51
679.5503540	0.14
682.0874023	0.20
683.3777466	0.11
687.4912109	0.40
689.3980713	0.37
690.9198608	0.21
694.9759521	0.40
697.3640137	0.13
700.4500732	11.91
701.3555298	18.88
702.1972656	0.16
703.3553467	0.48
707.2117310	0.30
708.4043579	0.18
710.1129150	0.70
711.3965454	0.29
712.4855347	0.35
713.9754028	0.31
714.7235718	0.31
717.2852783	0.34
719.6928711	0.32
722.4912109	0.30
724.3131104	1.38
725.3684082	0.61
728.4650269	0.18
738.3262939	0.56
739.2503052	0.29
740.4342041	0.54
742.6331177	0.47
744.2890625	0.44
745.7449951	0.12
746.8363647	0.35
748.6195068	0.41
752.4113770	0.12
758.3789673	0.06
760.3796997	0.22
763.3378906	0.45
764.1516113	1.78
768.3193359	1.23
769.3345337	1.13
770.3794556	0.16
772.5072021	0.27
773.6512451	0.21
774.4781494	0.51
782.3677979	0.36
786.2947998	0.34
787.7504883	0.68
788.3871460	1.01
790.1731567	0.41
791.8089600	3.43
792.5365601	8.24
795.4084473	0.10
796.3839111	0.35
797.5523682	0.42
798.3140869	1.41
799.5240479	1.87
800.6965942	1.19
804.5731201	0.22
808.6970215	2.33
809.4985352	1.51
812.6185303	0.50
813.4033203	0.46
814.4366455	3.61
815.5321045	1.75
816.5772705	2.33
818.4854736	0.89
819.3796387	0.27
820.6584473	0.26
824.2165527	0.20
827.6809082	0.24
836.2767334	5.30
837.4277344	11.40
841.3173828	3.69
842.3974609	11.37
843.4670410	6.73
844.4929199	12.63
845.3604736	0.13
852.3757324	0.49
853.3634033	0.20
855.7091064	0.12
858.7510986	1.93
859.5600586	1.26
865.3035889	0.82
866.3636475	0.34
867.4926758	0.08
868.4691162	0.05
869.2700195	1.00
870.3709717	2.02
880.3958740	0.11
882.3251953	1.64
883.3879395	5.55
884.1341553	0.05
885.7788086	1.12
886.5814209	7.66
887.4896240	14.00
889.7937012	0.21
892.6965332	0.19
897.5305176	0.26
898.7542725	0.33
906.3157959	0.14
907.4409180	0.04
910.3985596	11.29
911.4815674	42.53
916.4732666	0.16
918.8499756	0.28
921.4193115	0.11
922.3769531	0.16
926.3988037	0.16
927.5062256	1.70
934.5926514	2.53
938.4458008	0.16
939.6302490	0.71
940.5820312	0.28
949.9774170	1.05
950.9030762	0.35
954.5357666	4.57
955.4062500	6.39
956.5817871	2.13
963.7639160	0.07
967.0855713	1.23
968.0521240	3.91
968.8885498	1.24
972.3775635	0.50
979.1838379	0.06
980.3302002	0.13
982.4768066	2.47
983.3869629	0.74
984.5532227	2.63
991.4039307	0.49
997.3864746	0.42
998.5538330	1.58
999.5943604	1.96
1000.4804690	4.53
1001.0914310	0.05
1008.5924070	0.11
1010.6130370	1.02
1012.4157710	0.14
1024.4338380	1.26
1028.1263430	0.55
1035.5747070	1.04
1036.4040530	0.32
1050.2326660	0.17
1052.3587650	11.54
1053.5032960	27.43
1054.1132810	0.33
1062.2692870	0.08
1068.6307370	21.90
1069.5451660	100.00
1078.8480220	1.58
1079.5570070	13.46
1080.8266600	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1559
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
168.9300385	0.02
181.0400238	0.09
184.2536316	0.06
185.0721741	0.15
196.0154419	0.14
197.1884155	0.15
197.9615479	0.05
199.1459045	0.08
200.8487549	0.05
201.9961853	0.02
210.0264435	0.03
224.0088501	0.03
225.1002808	0.32
226.1644287	0.07
227.0708008	0.06
269.0489807	100.00
270.0649719	94.75
282.9250488	0.10
291.3168335	0.10
311.1339722	0.14
312.1019897	0.26
353.4376831	0.06
414.2993164	0.03
433.6604004	0.06
515.1218872	0.16
533.8737183	0.03
559.132019	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	682.2347
Annotation	Unknow
Peak:m/z	Relative Intensity
208.5309448	0.08
211.9613342	0.35
219.7918854	0.27
224.8723602	0.11
226.3996887	0.12
230.6463623	0.23
232.1791992	0.12
236.7150574	0.87
237.9210052	0.28
254.1375427	21.74
255.0891418	0.89
263.9831238	0.22
268.0035095	0.10
272.1089478	32.86
273.0980530	0.49
290.1029053	4.32
291.0136108	0.12
300.1110229	0.11
314.0748291	1.34
316.3150635	0.17
318.4951782	0.23
325.4347534	0.12
330.0520630	0.29
331.0622559	0.13
332.3307800	0.20
333.2951660	0.13
334.0133667	0.08
341.2852783	0.10
344.2052002	0.58
345.8069458	0.18
354.1043091	0.05
357.0924072	0.61
358.2626343	0.16
362.3260498	0.75
363.4160156	0.08
365.8701782	0.07
375.0256348	1.15
380.1589966	0.09
381.3887939	0.21
382.3355713	0.09
385.9552612	0.07
388.0488892	0.13
389.1674805	0.43
393.1625366	0.38
400.4682617	0.23
402.0090332	0.12
412.4093018	0.36
413.1047974	0.05
418.2847900	0.09
420.6469116	0.13
424.1805420	0.19
426.0791626	0.13
430.1124878	0.71
434.1400146	0.25
435.8781128	0.32
436.5879517	0.56
441.0206909	0.09
443.4898682	0.58
449.0988770	0.18
453.9498291	0.18
457.9450684	0.46
458.5643311	0.13
462.1248779	0.12
466.1765137	5.03
472.0717773	0.54
479.1778564	0.06
480.9310913	0.19
484.0832520	3.65
486.6654663	0.47
489.9583740	0.10
493.4707031	0.11
494.5181274	1.14
496.1992798	0.38
501.8945923	0.67
503.5952148	0.67
506.9235229	0.13
511.8197632	0.21
514.1708374	1.40
515.0201416	1.10
516.0619507	0.46
518.9687500	0.13
520.3073120	0.37
528.8649292	0.51
532.3120728	2.99
536.0454102	0.18
538.1376343	0.43
539.6579590	0.11
540.8117065	0.12
542.1731567	0.45
544.0552979	1.52
550.2044067	1.03
551.4044800	0.24
560.0504761	0.14
562.2770996	0.70
563.3332520	0.22
567.6826782	0.17
574.5257568	0.06
576.8490601	0.10
578.1483765	2.44
584.3615112	0.17
586.5383301	0.10
591.8547363	0.07
596.2364502	3.51
598.0990601	0.49
602.2438965	0.39
606.0860596	0.13
610.3135376	0.16
619.6746216	1.10
620.3717651	1.61
626.9560547	0.60
628.1751709	1.20
634.0419922	0.54
638.4533691	1.50
646.2328491	7.89
647.2095337	0.17
649.5259399	0.48
652.4297485	0.12
664.1554565	100.00
664.8397827	0.18
669.5870972	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1714
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
165.0687408	0.13
174.7032776	0.13
176.9821167	0.94
185.2051392	0.05
192.9606018	0.11
212.2888031	0.05
253.0146790	0.06
271.0644531	100.00
295.0781555	0.99
313.0856323	0.63
325.2025146	0.09
337.2171631	0.07
356.9908447	0.03
360.2774658	0.05
375.0322876	0.10
435.0517578	0.01
459.2097168	1.22
477.2789307	0.03
551.4466553	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	299.0905
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
92.8992538	0.05
119.2955170	0.02
120.8054123	0.03
133.0340424	0.03
134.9907227	0.02
153.2631378	0.03
155.2242126	0.01
163.9578552	0.01
165.1578369	0.08
172.2258911	0.03
174.8128204	0.02
176.9969635	0.03
185.2876129	0.04
187.1373901	0.06
188.9943542	0.03
190.9955902	0.65
192.0395355	0.04
193.0135803	0.56
201.8834534	0.09
205.0475464	0.04
206.8985291	0.03
207.8356323	0.04
211.1807556	0.02
212.2563171	0.01
215.0074463	3.83
216.0139771	5.86
217.0439453	5.32
219.0460815	0.05
221.0021362	0.07
224.9182434	0.03
227.1158447	0.01
229.0327454	14.84
231.0756836	100.00
231.7791443	0.02
232.9085083	0.03
235.1983032	0.06
238.2400513	0.07
239.1673279	0.22
239.9783936	0.03
241.1007080	0.03
243.0342102	2.70
247.3814697	0.00
250.1754761	0.03
253.0481262	0.18
254.2549133	0.07
257.0336609	3.41
257.8771973	0.04
263.0737305	0.02
266.0973816	0.10
267.0231628	0.14
267.7947998	0.01
268.5829468	0.01
269.2186279	0.08
271.0664673	12.43
274.3146667	0.02
281.1750793	1.44
283.9966431	0.13
289.9355469	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.067
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
111.0066681	0.33
118.9019318	0.04
128.9694672	2.09
134.0342255	0.25
145.1261902	0.04
147.0001984	3.37
149.0175781	0.09
163.1161652	0.29
172.9998779	2.21
175.0672302	0.26
190.9740601	100.00
192.8012695	2.14
201.0840149	0.07
209.0823975	49.64
217.1374207	0.13
293.1997375	0.16
327.3865356	0.07
337.1602173	10.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1509
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
174.1630096	0.09
175.0614624	0.52
185.1272125	0.12
195.088913	0.02
196.8748322	0.05
198.2069397	0.07
199.0008545	0.43
200.9622498	0.14
203.2669983	0.03
211.144165	0.07
213.0327301	0.17
214.2735138	0.02
215.1263428	0.05
217.1082764	0.26
223.213089	0.03
229.270874	0.10
239.2810974	0.05
240.2225342	0.18
241.0206909	0.21
242.9855957	0.33
244.0905609	0.02
252.9562836	0.04
257.1427307	0.08
266.9524231	0.07
271.178833	0.09
285.0361938	100.00
286.171875	3.51
297.1647949	0.02
298.1626892	0.02
299.2584839	0.02
308.0203857	0.24
309.0048828	0.02
311.2254639	0.20
323.1860962	1.00
327.1210938	0.48
328.335144	0.03
339.1887207	0.02
341.1420288	2.59
353.2958374	0.20
365.1743774	0.22
369.2662354	0.07
371.1679077	0.44
383.2012329	0.13
385.2704468	0.15
395.2849731	0.03
397.3328857	0.07
407.069458	0.10
411.3264771	0.03
412.8985596	0.09
428.1716919	0.05
429.1651611	0.06
431.0360107	0.02
443.2230835	16.51
445.1147461	0.02
447.1566772	1.01
448.2671509	0.18
463.0007935	0.40
473.0905151	0.77
474.3676147	0.05
503.4209595	0.07
575.3949585	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	287.0907
Annotation	5,8-Dihydroxy-7-methoxyflavanone
Peak:m/z	Relative Intensity
109.1130981	0.02
117.0329590	0.03
131.1241760	0.02
139.0390320	0.01
148.9697266	0.04
160.9743958	0.02
172.9451904	0.04
174.9638672	2.89
186.8965149	0.63
191.0050049	0.01
197.1661682	0.01
199.0400391	0.01
201.0734863	0.12
202.3499756	0.03
203.0622864	0.58
215.0640564	0.74
217.0399780	0.42
218.9926147	100.00
219.9907227	0.04
223.2664185	0.01
225.1664124	0.08
229.3094177	0.03
231.0557556	0.32
238.9789734	0.02
241.0210266	0.07
243.1124573	0.92
245.0847778	0.15
251.1398010	0.03
257.0565186	0.07
259.2792358	0.09
268.9878540	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	677.277
Annotation	Unknow
Peak:m/z	Relative Intensity
190.8003235	0.36
193.2947540	0.21
195.3580017	1.05
197.0454254	0.54
199.1669159	0.91
201.3646240	0.51
202.9835358	1.62
205.2956696	0.10
207.3075867	0.39
208.1008148	0.25
211.1501160	1.14
213.1295319	2.74
215.1040649	2.87
215.9691925	0.27
217.2155762	1.47
219.0108337	0.79
221.4255066	0.49
223.2573242	0.20
224.0809479	0.39
225.0628357	1.38
227.0750122	1.99
228.3380890	0.63
229.3632202	0.58
231.2171173	0.79
232.3966675	0.30
233.3332672	0.79
235.1411438	0.44
237.3920593	0.50
239.2375946	2.25
241.2598572	2.20
243.2558594	0.58
245.0905914	2.39
247.1679230	0.35
248.3873291	0.41
249.3124542	0.37
251.3056641	2.58
253.1921539	0.67
255.1236420	1.66
257.2303467	1.81
261.3060913	0.96
263.1542969	0.74
265.1936035	1.06
267.2618713	0.90
269.2996216	4.98
271.1680603	1.97
272.1926270	0.57
273.0197754	1.66
277.0663147	0.49
277.8869934	0.71
279.1513672	1.68
280.3110352	0.29
281.1894226	1.01
282.9092407	0.43
285.3111877	1.66
286.7174683	2.53
287.3333740	2.00
289.0122375	1.24
291.1213074	1.48
293.2748413	2.90
295.0516968	1.81
297.0943909	1.93
299.3055420	0.41
301.2113647	1.16
302.3684082	0.69
303.3602905	0.86
305.1308289	2.59
306.3037109	0.43
307.2540283	3.20
309.3409424	2.53
311.1680603	1.95
313.2098999	1.36
315.1082153	0.86
317.2875977	2.53
318.6739197	0.60
319.3561401	1.04
319.9946289	0.09
321.2680664	2.45
323.1401978	3.68
323.9722900	0.49
325.2302856	0.84
327.2965698	1.01
329.3487244	0.74
331.3945312	0.74
333.1576538	4.16
335.3756714	1.10
337.2508240	0.79
339.3215332	3.60
340.3500366	0.41
341.2269287	11.95
343.2254028	4.05
345.2475586	0.39
347.3353882	2.08
349.3361816	4.23
351.2781372	7.05
355.1564941	1.26
357.0980225	0.73
359.0457764	1.39
361.0819092	2.40
363.1626587	1.48
364.9757690	1.24
367.2553711	5.07
369.2142334	36.15
370.8150635	0.48
373.3082275	2.68
375.3262329	10.09
377.1614380	5.20
380.3063354	0.22
381.2098389	1.61
383.5744019	0.19
385.0422363	0.86
386.2007446	0.07
387.2543945	0.50
389.4714355	1.72
391.1537476	3.62
393.4159546	31.81
395.4395142	4.95
397.5736084	0.13
399.2506104	1.70
401.3929443	2.14
405.3248291	0.66
407.2486572	2.35
409.2944946	7.43
411.3115845	35.61
413.2621460	5.85
414.2300415	0.28
415.1248169	0.33
417.3112793	5.81
419.3132935	13.78
420.3391724	0.85
421.7012939	0.72
423.3003540	5.79
425.7683105	0.23
427.3499146	2.32
429.2628784	3.57
431.1268311	3.72
433.1523438	2.30
435.2329712	7.56
437.1799316	14.38
439.4846191	0.32
441.0882568	3.26
443.0799561	0.31
445.1646118	0.20
447.2747192	0.84
448.6044312	0.60
449.6678467	0.89
450.7756348	1.86
451.4592896	0.29
453.3049316	12.69
455.1309204	11.38
455.7866821	0.33
457.1010132	0.45
459.3191528	5.83
461.4229126	2.27
463.1387939	0.13
465.2742920	0.64
467.3916626	1.53
468.7147217	0.83
471.2421265	1.15
473.0463867	3.67
475.3386841	0.53
477.2583618	7.01
479.1707764	2.32
481.7373047	0.37
483.2913818	3.34
485.2486572	1.52
489.3806763	0.12
491.2287598	3.06
495.2103882	9.70
497.3729248	4.66
499.2473145	0.96
501.2907104	8.96
505.3997803	0.89
506.2504883	0.50
507.2515869	1.07
509.4627686	1.17
511.2893677	0.77
513.2005005	6.61
515.1865845	1.83
519.2469482	25.76
520.5354614	0.15
521.3019409	0.16
523.4139404	0.37
524.0794067	1.19
525.3650513	0.27
527.1931152	3.34
531.4016724	0.56
533.2656860	2.27
535.2590332	5.41
537.2564697	30.56
539.4336548	0.28
541.1578979	0.18
543.0730591	0.46
545.3414917	6.44
547.4708862	0.41
551.1416016	0.30
553.2249146	6.67
555.3125000	43.37
557.3244019	0.88
559.4866333	1.25
561.2851562	1.60
563.3539429	11.53
571.2862549	1.09
573.3699341	10.98
576.5275269	0.86
577.1476440	0.29
579.2932739	7.59
581.2584229	29.10
584.1561279	2.23
585.6990356	0.99
587.2149048	0.85
589.2001343	1.26
591.0269165	0.46
595.0984497	3.75
597.1437378	5.41
599.2125854	36.50
599.8411255	0.30
602.2384644	0.88
605.1730347	1.34
609.1065674	0.28
613.2058105	6.43
615.1630249	27.05
616.0752563	0.37
617.2314453	26.65
617.8461304	0.24
619.8129272	0.57
623.1849365	5.77
631.4223022	18.38
633.0967407	0.56
641.2372437	15.32
649.7083130	0.19
657.3922729	0.42
659.1984253	100.00
659.9238892	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
114.1787109	0.90
143.1329041	0.24
159.1228485	0.80
171.0400085	4.54
172.9680786	3.25
175.0613403	0.81
185.2422791	0.74
187.1456146	2.73
188.9715118	0.41
197.1877289	3.03
199.1652222	1.68
201.182373	5.14
203.2842102	0.39
213.1940002	1.52
215.2611389	1.26
219.7597656	0.43
224.7832642	0.24
227.2235107	6.45
229.0602722	1.53
231.0805664	0.40
241.2113953	3.45
243.2073669	7.35
243.8432617	1.16
245.1907654	0.89
251.4725647	0.38
255.2319946	4.84
257.2199707	4.99
259.140625	4.39
261.3309631	0.78
263.3084717	3.23
269.1506958	2.22
271.337616	5.63
273.1767883	0.85
281.2216492	1.33
283.3953247	1.50
285.1350098	9.94
287.3295898	0.80
288.3516235	1.07
291.7237549	0.40
294.9833679	0.90
297.295166	5.30
299.2593384	13.77
300.1063232	0.47
313.4139404	1.73
315.2365723	6.11
321.34552	7.04
323.3394165	8.02
339.2581177	100.00
341.1092224	18.99
341.9302979	2.29
343.242157	1.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
113.0133972	0.19
117.0175629	1.18
171.0736084	2.48
173.3096771	0.22
185.1111755	1.65
187.1767273	1.40
195.3500366	0.47
199.1231232	3.60
201.0708618	3.44
211.4178314	0.54
213.1958008	0.45
215.0706482	3.93
217.1634216	0.84
220.1400757	1.19
225.3335571	0.24
226.9263	0.47
229.1309814	3.02
231.2754822	0.24
241.0941467	1.59
243.1539917	2.89
245.2127991	2.24
255.1852722	2.00
257.2679443	4.62
259.4482727	0.57
261.3684692	1.37
263.4321594	3.63
269.1700134	1.35
271.2337036	2.69
273.2585144	1.25
274.9581909	1.23
283.3307495	0.98
285.269165	6.84
288.8447876	0.30
293.2618103	0.27
295.1972961	0.95
297.2940369	5.19
299.3452148	4.62
301.2888184	1.90
310.3620911	0.22
311.2855225	1.61
313.1158142	3.69
315.0966492	5.18
321.124939	1.36
323.2550659	8.80
323.8738098	0.19
325.2800903	1.14
327.2751465	0.57
339.243103	100.00
339.8739319	1.14
341.3842773	23.91
343.0788879	1.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	630.61
Annotation	Unknow
Peak:m/z	Relative Intensity
192.8576813	0.02
200.1241455	0.15
201.8725433	0.13
212.8499298	0.01
214.6821899	0.00
215.9086151	0.01
217.6863098	0.03
226.1576080	0.05
228.0899963	0.05
229.6819153	0.02
233.9826965	0.01
237.8557739	0.03
241.1312561	0.04
241.9060059	0.01
245.9012451	0.01
253.9758453	0.33
255.9444275	0.01
265.8614502	0.01
272.0023193	0.24
272.9867249	0.24
275.1675110	0.04
276.2187500	0.04
280.9221191	0.13
283.6708069	0.02
293.8199463	0.04
297.8798218	0.03
299.1206055	0.07
301.8975525	0.01
304.0464478	0.23
306.1123047	0.10
317.9778442	0.01
319.0623779	0.71
322.0460205	0.56
332.0510254	1.08
333.2507324	0.01
333.8580933	0.04
340.0576172	0.29
342.0816040	0.14
348.0462036	2.44
352.1502075	0.04
357.8966675	0.11
364.0646362	1.05
364.8238525	0.02
367.0424805	0.06
375.9025879	0.29
376.8975830	0.04
377.9745483	0.07
381.8626099	0.05
389.6196289	0.03
392.1604004	0.16
394.1193237	100.00
401.9835205	0.02
403.9642334	0.01
408.2024536	0.02
420.1210938	0.25
421.6834717	0.14
436.0004883	0.01
437.9761963	66.31
438.7620239	0.19
439.5662842	0.06
440.1785889	0.01
450.0766602	0.03
453.2260132	0.09
458.5538330	0.06
468.1496582	0.03
481.9575195	0.06
510.3004761	0.07
510.9548950	0.08
512.1941528	0.05
514.0539551	0.09
527.2678833	0.02
534.0615845	0.18
551.9248657	0.04
555.2604370	0.03
569.1445923	0.04
570.0565796	0.83
570.9302979	0.00
584.6421509	0.42
585.5617065	1.71
586.3388062	0.05
611.3656006	0.34
611.9755249	1.64
682.7175903	0.10
774.8765259	0.03
874.8593140	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
183.2480621	0.06
190.9036865	0.03
209.2077332	0.18
212.9408569	0.16
221.220932	0.09
226.9217072	0.05
253.4720917	0.12
266.9138184	0.10
271.2278442	0.21
278.8951111	0.12
281.3273926	0.45
286.2418213	0.22
301.2005615	19.23
303.3855591	0.03
313.2504883	0.16
316.9035034	0.06
323.3267822	0.02
343.1754761	0.79
348.1920166	0.11
348.9783325	0.14
361.1621704	0.30
374.9969482	0.20
389.1881714	0.12
393.0237427	0.26
401.2854614	0.17
403.0368652	0.09
407.2677612	0.16
411.1847534	0.05
428.1210327	0.12
429.3810425	0.25
433.1864624	0.05
439.3875732	0.10
444.9360352	0.10
447.2243652	1.31
451.5592041	0.08
463.1170044	100.00
487.3622437	0.08
523.2754517	0.05
525.5633545	0.15
534.8693848	0.29
547.159729	0.11
549.4329834	0.35
555.3021851	0.21
565.2990112	0.22
573.0679932	0.39
574.0861206	0.45
590.078186	0.13
591.2774658	1.09
592.5026245	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.1222
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
109.0939789	0.17
112.9895401	0.01
117.0069427	0.03
123.0657043	0.02
125.0582428	0.16
127.0239182	0.63
133.0418396	0.02
134.9140930	0.02
137.0166168	1.84
144.9163818	0.64
147.0032043	0.38
147.9963684	0.37
148.9791870	0.31
157.1878662	0.04
159.3423462	0.02
161.2992249	0.02
161.9966431	0.03
162.9233398	0.04
167.1902161	0.04
171.1995239	0.01
175.2094116	0.02
177.1705017	0.01
178.9923706	100.00
181.1810150	0.04
187.1097870	0.06
197.0624542	2.47
199.0887146	0.49
205.0543518	0.94
206.9485474	0.04
217.0764160	0.97
218.9364624	0.06
219.6987915	0.07
221.1779785	0.24
227.9786377	0.04
229.0625610	0.07
236.8310242	0.04
239.0450439	0.03
244.9985962	0.56
247.4282532	0.02
257.2799683	0.02
258.9688721	0.01
262.9671936	0.37
264.1640320	0.07
267.8846436	0.06
270.3262329	0.01
271.1590576	0.14
275.1160278	0.08
281.2010803	0.03
287.0153503	0.23
295.1932678	0.21
296.3540344	0.03
297.2120361	0.07
300.2542419	0.05
303.0240479	0.02
303.8381958	0.07
305.0717773	1.01
311.2012939	0.05
312.2355957	0.06
313.0437317	0.38
314.1819763	0.02
318.1656494	0.02
323.0649414	5.65
324.1563110	0.04
324.9962158	0.08
332.2842712	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	261.1114
Annotation	8-Deoxylactucin
Peak:m/z	Relative Intensity
85.1827545	0.01
94.9851227	0.02
106.8096771	0.01
112.9970398	0.01
116.9550323	0.02
120.7015228	0.02
133.0072632	0.02
140.7461548	0.02
149.2111053	0.01
159.0301819	0.02
161.0814972	0.02
167.3268280	0.01
176.8578339	0.02
183.1984863	0.03
187.0229340	0.01
193.0126190	100.00
193.8212128	0.06
199.0338593	0.01
202.2626953	0.01
204.9605560	0.37
206.9933319	0.01
215.2025452	0.01
219.1127167	0.01
242.7459869	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1843
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
178.9468384	0.02
188.8476257	0.04
195.0276794	2.19
203.0469513	0.02
211.0957336	0.02
219.0018616	0.39
221.0579224	0.11
231.2285461	0.11
243.0986328	0.03
245.1662292	0.49
249.1798401	0.12
253.9470215	0.04
255.1021423	0.16
259.3458252	0.11
260.8919678	0.09
263.2009277	1.11
271.1823730	0.01
273.1503906	41.25
278.9918823	0.03
281.1429443	2.44
285.2189331	0.81
287.1049194	0.08
297.2084656	1.40
299.2653198	0.03
305.2626953	0.05
306.2242432	0.12
309.0827637	0.49
315.1631470	10.83
323.0391235	0.33
324.9313354	0.12
327.3619995	0.11
333.3449097	0.26
339.0522461	4.56
339.6688232	0.01
345.2732544	0.05
347.0972900	0.37
351.1053467	0.06
353.2220459	0.03
357.1211548	0.47
359.0209351	0.06
359.7123413	0.10
363.2445679	0.27
365.0847778	0.67
369.2107544	0.34
371.1894531	0.07
375.1367798	0.04
375.9880371	0.09
381.0982666	2.37
383.0982666	16.31
385.1988525	0.05
389.1666870	0.11
393.3498535	0.13
399.1385498	2.90
401.0972290	24.74
405.2713013	0.08
407.1218872	0.82
411.1276855	0.10
412.7962646	0.09
413.4229126	0.10
417.1074219	25.57
419.0809937	100.00
419.7620239	0.17
423.0049438	0.55
425.0734253	0.34
429.1000366	1.75
431.2360229	0.11
433.3769531	0.25
434.9847412	32.40
435.7516479	0.13
437.5034790	0.05
441.3150635	0.67
443.1858521	3.34
447.1984863	0.22
449.0991821	0.45
459.1217041	8.46
461.0939331	3.51
466.8449097	0.76
467.5288086	0.10
473.1770630	0.07
476.6422119	0.39
477.4120483	0.30
478.9763794	0.02
483.1257324	0.63
491.2299194	0.50
497.0399780	0.92
497.7164307	0.12
501.1588745	0.05
502.3221436	0.16
507.3562012	0.02
509.1608276	2.96
519.0586548	0.12
520.5827637	0.02
521.4756470	0.02
527.1360474	8.84
534.4799194	0.05
537.5419922	0.14
545.0346680	15.80
545.6795654	0.06
562.4414062	2.32
563.1076050	10.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2622
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
140.0366058	0.14
172.2652588	0.03
195.9872131	0.21
213.9712219	1.83
222.8850098	0.05
225.2844238	0.06
233.3716125	0.58
275.3148499	0.19
277.2417603	100.00
277.8468628	0.25
298.2150574	0.10
308.2607117	0.08
311.2914429	0.06
316.0482483	0.05
323.2114563	0.09
342.1369019	0.05
352.4830933	0.07
353.5872803	0.12
369.5062866	0.11
374.4168091	0.23
386.2658997	0.02
428.4223938	0.07
430.2741394	0.10
430.9070740	0.19
432.0419617	0.05
445.4272766	0.24
446.6881714	0.06
455.8663330	0.05
456.8604126	0.66
457.4646606	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1515
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
173.1229095	0.10
174.0979309	0.04
175.059021	0.28
186.1331787	0.04
187.2177734	0.04
196.0226288	0.07
197.0527496	0.11
198.8337708	0.73
200.1480103	0.10
201.0853271	0.14
202.2923584	0.02
212.3214417	0.24
212.9913025	0.05
215.1030121	0.18
217.0818634	0.38
222.874054	0.17
224.1444397	0.09
225.635498	0.04
239.1364136	0.04
240.9121857	0.34
242.1286926	0.03
243.2053986	0.33
255.2389221	0.04
257.0187988	0.30
266.9254456	0.28
268.1541748	0.04
269.0484009	0.22
283.4139404	0.08
285.0414429	100.00
286.0744019	3.83
286.6779175	0.01
296.8473511	0.03
299.1792603	0.11
311.1115112	0.13
323.0304565	0.25
325.2890015	0.03
327.1930542	0.41
338.9144287	0.15
341.1594849	1.70
353.0429688	0.22
357.0177002	0.03
365.1300049	0.04
371.4144287	0.03
383.1275024	0.25
384.2747192	0.01
385.2339478	0.12
389.0545044	0.02
407.1082764	0.03
413.1737061	0.04
425.0386353	0.03
428.0957642	0.02
431.3093872	0.08
437.369873	0.15
443.1237793	7.81
445.1502686	0.08
447.2442017	1.01
460.5939331	0.06
461.3486938	0.06
463.3476562	0.05
473.1709595	1.73
490.2772217	0.07
503.0730591	0.43
515.3103027	0.06
535.2330933	0.02
547.579895	0.04
549.4579468	0.03
575.2821045	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	474.2622
Annotation	LysoPE(0:0/18:3(9Z,12Z,15Z))
Peak:m/z	Relative Intensity
134.9225616	0.07
139.6816864	0.08
153.1947174	0.10
174.7014771	0.13
196.0827637	2.29
205.4222412	0.16
210.7647552	0.14
214.0631866	2.14
233.2903442	0.59
257.3089294	0.05
275.3979797	0.23
277.2450562	100.00
305.7954407	0.09
313.1701050	0.27
328.2888184	0.05
350.1600037	0.06
360.1297913	0.11
373.3315430	0.08
384.2258911	0.23
402.2210999	0.07
413.3823853	0.29
420.1410522	0.07
431.0774841	0.22
432.7952271	0.04
455.9460754	0.30
457.0670776	0.06
471.9915161	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
195.15979	0.05
221.1884918	0.02
223.2637329	0.07
250.136322	0.03
286.0336914	0.04
288.0476074	0.02
295.2418823	0.08
297.008728	0.03
301.0982361	1.03
303.0038452	0.11
310.2175903	0.03
313.1156006	0.41
323.1740723	0.09
325.1358032	0.38
339.3015747	0.04
341.1448975	0.04
343.2229004	5.94
367.1831055	1.77
375.4075317	0.07
379.1415405	0.10
383.3393555	0.13
385.0306396	0.04
386.6427612	0.03
397.1888428	3.83
403.1859131	0.01
409.0366211	1.05
411.2081299	0.10
415.1595459	0.06
416.1646729	0.04
417.2022705	0.13
421.3260498	0.06
425.0032959	0.04
427.1811523	2.18
429.2531738	0.26
439.2436523	0.11
440.8624268	0.03
443.1373291	0.03
445.1138916	19.11
447.1077271	0.83
453.3450317	0.11
459.1991577	0.10
460.2182007	0.06
463.1190796	100.00
463.7542725	0.11
465.3642578	0.15
469.1329956	0.08
471.288208	0.63
473.1311035	0.06
477.0009155	0.28
485.4406738	0.04
487.149231	1.98
489.1861572	0.62
495.2000122	0.31
505.7177124	0.13
513.2039185	0.54
525.282959	0.80
531.9465942	0.04
538.3585205	0.05
543.1459961	3.13
547.2426758	0.12
549.1466064	0.02
554.8948364	1.01
555.6017456	0.02
563.2287598	0.28
564.1806641	0.06
565.5011597	0.31
573.1260376	3.74
577.1984253	0.05
591.1912231	15.78
592.4602051	0.66
598.4221191	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
177.0279846	0.07
193.2570496	0.06
207.1035309	0.13
213.2674866	0.29
216.8868866	0.30
227.2306061	0.05
231.0635529	0.15
248.9413452	0.05
255.0836182	0.09
257.1702881	0.30
275.2462463	0.06
276.8047485	0.19
283.118988	0.08
286.3902588	0.10
291.1293945	0.40
295.2471008	0.03
301.1488647	16.69
303.2785645	0.12
305.3161621	0.29
307.223114	0.23
313.1437378	0.88
314.6710815	0.11
321.3543701	0.18
330.2526245	0.15
333.0201416	0.03
335.8460693	0.06
343.2132568	0.22
345.0626831	0.10
347.3916626	0.05
351.2822266	0.02
361.0099487	0.18
367.2178955	0.39
375.0178223	0.48
392.9442749	0.84
394.2866211	0.44
397.3150635	0.17
401.2075195	0.14
409.5001831	0.18
415.0046997	0.05
428.8512573	0.73
429.4616089	0.76
445.0546265	0.41
446.5787964	0.67
447.3910522	0.61
453.3027954	0.09
458.0674438	0.09
463.137146	100.00
486.3045654	0.21
489.1985474	0.02
504.4806519	0.10
507.2133789	0.20
521.1210938	0.07
537.4707642	0.15
542.3633423	0.28
546.8889771	0.18
562.9499512	0.14
565.1922607	0.53
572.4888306	0.08
573.3047485	0.10
579.1758423	0.05
590.8578491	2.13
591.5351562	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	218.1034
Annotation	Pantothenic acid
Peak:m/z	Relative Intensity
71.0150299	0.88
87.9838104	100.00
88.9199982	0.09
115.8329010	0.05
129.0302582	0.13
145.9976044	9.60
157.9160919	0.04
160.0547333	0.10
173.0720062	0.16
174.0775146	0.22
175.2189178	0.11
200.0668488	0.12
202.1620789	0.05
202.9796448	0.29
219.0972443	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1733
Annotation	Unknow
Peak:m/z	Relative Intensity
343.4094238	0.07
366.7246094	0.05
385.2680054	0.31
409.3220825	0.40
421.0517578	0.22
425.2338867	0.06
427.3623047	0.12
438.9541626	0.77
445.0574951	0.48
451.1193237	0.57
457.0025024	0.23
457.6202393	0.37
462.9261475	0.37
463.5947266	0.07
469.2366333	1.83
475.1845093	0.45
487.1446533	38.64
487.8364868	0.10
492.9354248	0.07
505.1795654	12.40
511.1979980	3.70
517.2537842	0.09
522.9384155	0.06
528.6777954	0.25
529.2940063	4.34
535.0427856	0.10
541.2068481	12.19
553.2025757	6.15
559.1340942	12.27
566.3658447	0.10
571.2310791	9.56
587.8574829	0.16
589.2429199	35.08
607.1066284	100.00
607.8554688	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1089
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
263.3507080	0.01
285.2977905	0.02
298.2823792	0.69
299.0108643	0.16
311.2015076	0.18
313.1898193	0.16
324.8564758	0.06
326.1723022	0.13
339.1210938	0.07
341.1301270	100.00
341.9316711	0.35
342.5960083	0.01
351.2956543	0.05
352.2849426	0.09
353.1045532	0.70
355.0389404	0.06
356.1445007	0.02
365.1536255	0.02
367.0458679	0.21
371.1562195	16.89
372.4411316	0.02
381.0713501	0.11
383.1208191	1.54
385.0452271	0.60
385.6532898	0.08
395.1696167	0.07
397.0360413	0.05
401.1822815	0.70
407.1917419	0.29
407.8135681	0.01
413.1168213	0.91
415.3264771	0.14
425.1412659	0.39
431.1833191	0.02
443.1153259	2.17
446.1408386	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	246.0601
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
73.1359329	0.03
84.0081787	0.01
84.9187775	0.04
93.9273300	0.05
96.0233154	0.04
99.9492950	0.01
101.9221954	0.04
110.9352570	0.04
114.6274414	0.03
127.4024658	0.07
128.0368958	0.55
131.1690826	0.02
137.9842834	0.50
139.0927429	0.07
143.9700775	0.43
145.9487915	0.22
156.0409698	0.24
157.8971100	0.04
160.6042328	0.08
164.0634155	0.22
166.2321320	0.09
167.0092163	0.14
168.1386414	0.08
170.1268005	0.17
173.9600372	100.00
174.7512665	0.01
181.9583130	0.31
184.0054626	0.06
188.0183105	0.15
199.9487915	1.06
210.0796661	2.41
218.0804596	0.08
227.9846954	22.71
228.8596649	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	371.1478
Annotation	Renealtin A
Peak:m/z	Relative Intensity
109.1734314	0.18
110.9251480	0.10
119.0077362	0.06
122.9650574	0.07
135.1290894	0.12
140.9712219	0.07
144.9493866	0.15
147.0628052	0.16
152.9487762	0.08
157.0669250	0.04
159.3009338	0.23
160.9849091	0.11
167.0714722	0.06
169.0990448	0.07
174.8970032	0.11
180.1347198	0.08
181.1974487	0.13
193.0437164	0.13
199.1159821	0.08
201.0033417	70.67
203.1299896	0.50
209.0654297	0.28
211.1331482	0.35
213.1147766	0.05
215.1578369	0.05
217.0888062	0.31
219.1126404	1.51
221.2854614	0.22
223.0077515	0.20
228.4544678	0.04
231.1335449	0.75
234.0283508	0.06
235.0064697	0.06
237.4329834	0.06
245.9606628	0.16
247.1523438	0.84
248.3278809	0.04
249.1501770	0.22
251.1687012	0.03
253.3018799	0.05
253.9946899	0.18
254.8843384	0.17
256.2491760	0.04
259.1042175	0.26
260.8770142	0.05
268.2634888	0.11
269.0905457	0.18
273.1055298	0.15
279.4169006	0.32
281.1999207	0.83
282.2442017	0.25
283.1262207	0.55
285.0394897	3.78
287.0483704	1.99
288.0796814	0.15
293.3744507	0.04
296.5605469	0.16
297.2344055	0.07
298.3081055	0.05
302.9252014	100.00
303.5962524	0.78
307.3257446	0.22
309.2831421	0.43
311.2675476	0.23
313.1239014	0.11
314.0961914	0.05
317.5531616	0.04
325.3707275	0.48
327.5694580	0.06
329.0567017	0.05
329.9405823	0.26
335.2971802	0.78
336.8395386	0.66
339.0634766	0.05
342.5101624	0.07
353.1462708	4.02
354.1088867	0.10
354.7818298	0.23
356.3542786	0.46
357.7178345	0.17
362.1149902	0.52
362.8815613	0.07
372.1493835	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	313.0564
Annotation	Norbergenin
Peak:m/z	Relative Intensity
110.9428329	1.18
121.0761032	0.79
126.9920349	0.09
128.9909973	4.52
144.9314423	0.17
147.0433960	11.64
148.6612549	0.03
163.0620880	0.07
169.1674652	0.12
173.0379028	8.86
189.1127319	0.09
190.9679260	100.00
234.9674988	0.06
251.2387695	0.11
259.2804871	0.05
269.2894897	0.11
277.0119019	0.65
285.2041626	0.03
295.0186768	20.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.2709
Annotation	Unknow
Peak:m/z	Relative Intensity
201.0932312	0.17
203.2752991	0.21
204.8793335	0.26
209.0693665	0.36
215.0431519	0.30
233.1995544	1.23
243.3903809	0.17
245.1863098	1.11
253.4204102	0.14
259.1684570	2.77
261.4022217	0.91
271.2474060	0.63
272.0249634	0.57
273.2822266	5.33
274.1628418	1.19
275.4256592	0.51
277.5173035	0.35
285.2904968	5.27
287.4185791	0.40
289.6459656	1.48
291.0208130	2.34
301.3005676	0.80
302.0920410	0.15
303.1725769	7.59
305.2413025	0.65
307.3830872	0.12
308.1890259	0.33
311.2139893	0.11
315.0562744	0.71
316.2164917	0.20
317.3712158	0.82
319.0576172	0.41
327.2766724	0.73
329.2266541	2.98
331.0870972	4.16
337.5219116	0.74
339.4689941	0.39
343.5184326	0.21
345.3558350	0.21
347.3342285	7.27
351.0895081	2.91
355.3110962	2.96
357.2945557	2.22
365.4663696	0.14
371.3748779	0.59
373.2706299	3.35
375.2669067	8.49
377.4382935	0.40
379.3260498	0.52
381.3381958	4.83
383.3000488	1.17
385.4570923	0.27
387.5032349	0.39
391.3442993	3.59
393.1979370	0.57
395.3085938	6.66
397.4277344	0.89
399.3051758	56.28
401.2812500	0.79
403.3669434	0.32
407.2142334	0.67
409.5704956	0.37
413.4552612	0.16
416.2393799	1.35
417.2819214	22.87
423.2691650	0.38
425.2468872	9.09
433.3362427	0.59
435.2789307	0.33
437.4805908	0.80
439.0899658	0.13
441.3658447	1.15
443.3223267	36.87
451.2910767	4.54
452.2554321	3.44
453.4066772	0.23
461.2962036	6.27
467.0910034	0.48
471.4592285	0.09
473.3041992	1.12
483.5701294	0.15
485.6575317	0.30
487.0500488	0.12
489.3504639	0.24
499.3295288	10.03
503.3215332	2.39
505.4325562	0.18
513.0004272	0.17
517.3294678	15.27
521.3154297	0.40
525.2132568	0.29
528.8727417	0.45
531.2127075	2.92
533.7071533	0.54
535.3070679	18.48
535.9204712	0.06
541.5939941	0.36
543.3324585	3.44
545.2095947	1.37
546.4915161	0.07
547.2645264	1.07
559.4546509	0.86
561.4032593	24.94
563.4785767	2.96
564.3452759	0.62
565.2015991	0.80
567.2868042	0.29
569.3893433	1.46
575.3278198	0.23
576.5719604	1.89
577.4470825	0.58
579.4057007	1.08
585.8052368	0.15
587.2584229	27.28
595.4467163	0.33
603.2985229	2.30
604.1857910	4.12
605.3973999	100.00
607.3596191	0.14
612.5872192	0.28
621.1867676	1.47
623.3099976	62.51
627.3577271	0.49
629.4748535	0.10
631.2915649	2.82
631.9049683	0.12
636.3264160	0.68
647.2383423	0.17
648.3872681	3.37
649.3009644	3.68
650.1390991	0.58
663.1646729	1.98
665.2898560	4.05
691.2218628	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1771
Annotation	Butrin
Peak:m/z	Relative Intensity
189.1653137	0.03
202.9107666	0.03
210.1035767	0.09
210.7209015	0.06
213.1326447	0.01
215.0950928	0.05
217.9332275	0.02
223.1195984	0.03
225.2027893	0.04
226.2963867	0.02
228.1151733	0.05
233.4810028	0.05
242.7016754	0.06
243.3109741	0.03
254.0636444	0.04
256.9229736	0.05
259.2551880	0.04
260.8114929	0.06
265.1697693	0.07
268.3397217	0.04
272.1002197	0.01
273.2990112	0.06
277.1761475	0.07
283.2184448	0.02
284.5036621	0.13
287.1138306	0.09
288.0036621	0.02
298.1969604	0.79
299.2914429	0.10
301.1472778	0.43
305.1569214	1.30
311.1029053	0.06
313.2288818	0.02
316.0759888	8.22
317.0534058	0.09
325.4475098	0.09
329.1314087	0.09
331.1323242	100.00
347.9837646	0.02
353.3626099	0.08
355.0788574	0.30
373.0343018	0.21
381.2686768	0.02
402.6193848	0.05
403.3335571	0.04
415.2813110	0.21
422.9332886	0.04
432.3434448	0.22
433.1808472	0.09
442.2064209	0.04
461.2500000	0.06
466.1030884	0.06
466.8844604	0.04
474.1473999	0.03
475.1428833	0.12
493.0747681	13.35
493.7902832	0.13
499.0750732	0.05
500.5052490	0.05
505.3281250	0.03
518.3662720	0.04
521.2763672	0.32
535.1329346	3.87
535.7616577	0.05
549.2980347	0.06
553.3150635	0.04
557.4927368	0.03
559.6636353	0.03
561.1369019	0.03
563.0921021	0.07
565.1123657	0.01
573.7504272	0.04
575.2773438	1.13
576.8289185	0.10
577.4334106	0.01
580.4437866	0.03
590.8722534	0.19
592.4329224	0.08
593.5749512	0.15
601.1942749	0.03
607.3101196	0.05
609.3209839	0.03
617.0750732	0.06
619.1384888	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	856.4566
Annotation	Unknow
Peak:m/z	Relative Intensity
560.5559692	0.05
577.5435181	0.03
793.4896851	100.00
794.1958618	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.12
Annotation	N-Succinyl-L,L-2,6-diaminopimelate
Peak:m/z	Relative Intensity
84.9921188	0.69
86.9483490	0.05
88.0160904	0.17
96.6821137	0.68
101.0090637	1.18
101.8635864	0.06
104.1415100	0.22
106.0288620	0.11
106.9567642	0.10
108.9567261	0.53
114.7790146	0.21
116.0912628	0.79
119.0014343	0.16
121.2123108	0.04
123.1078491	0.06
126.9201050	1.32
128.9995575	100.00
133.2062073	0.15
135.0742798	0.06
138.2409515	0.06
143.2552490	0.13
144.8506165	1.98
145.6640778	0.04
147.9636841	0.59
151.1288452	0.57
156.9957123	0.03
158.0424194	0.22
159.0417786	0.07
161.9349670	0.33
163.0044861	1.32
165.0372620	0.04
169.1045227	0.16
170.9480591	14.44
173.7532654	0.03
175.0702515	1.41
176.9759064	0.20
179.2040100	0.06
181.0661011	0.06
183.1134644	0.14
185.6948395	0.06
187.1301422	0.05
187.8390503	0.36
189.0421295	0.16
190.1617584	0.30
190.9855804	0.75
192.9369812	0.46
195.0523376	11.28
199.2439880	0.83
200.3162231	0.49
202.2906799	0.07
203.1366577	0.31
205.2042542	0.09
205.9004517	0.34
207.1470947	1.61
212.9047546	0.04
214.9103394	0.24
215.9617310	0.45
218.1465454	0.49
221.0570679	0.31
225.1607056	2.48
227.0310669	0.22
228.8200378	0.62
231.3808899	0.04
232.2511292	0.13
233.2192078	0.05
237.0675049	7.38
238.1960754	0.15
245.0407104	1.17
245.8858032	0.08
246.8201599	0.20
248.9111023	0.06
249.8302917	0.18
251.8216248	0.11
255.1049194	6.32
255.8846741	0.33
259.0130005	0.26
262.4109192	0.14
263.1473083	0.89
271.0080872	0.08
273.0217285	17.79
274.1341858	0.17
281.6576843	0.42
282.7703552	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.9579
Annotation	Unknow
Peak:m/z	Relative Intensity
156.9903870	0.28
158.9904785	0.02
191.0912781	0.12
200.0313110	0.76
201.0204773	2.31
209.1662750	0.03
214.0019379	0.45
214.9559937	0.22
218.1940613	0.14
226.8039856	0.10
228.9163818	32.45
243.8964844	0.12
244.8980713	1.82
245.8662415	0.10
247.1052246	0.05
258.0711060	1.30
258.9752808	3.15
263.1147766	0.11
271.0426331	0.22
272.1539307	0.53
272.8161316	3.44
287.1511536	0.14
287.8508911	0.10
288.8831482	1.06
289.8693237	0.22
290.9367676	0.25
297.1022339	0.20
301.7412109	1.11
302.9445190	1.67
305.0999756	0.92
314.9734192	18.73
327.7163696	0.04
329.1427612	0.13
330.4485474	0.45
331.2384644	0.50
332.9074707	100.00
333.5130005	0.33
337.4152222	0.03
338.8235168	0.04
340.6692200	0.05
345.9019165	0.64
346.7658691	1.39
347.5379028	0.02
348.7980957	0.04
351.1818848	0.20
356.7572937	0.02
358.1487732	0.25
358.8169556	0.51
365.1140442	0.26
374.7758789	0.49
375.4297180	0.02
376.5174255	0.46
377.1979675	0.63
382.9753723	0.51
392.0924377	0.35
393.0100403	2.37
400.9640808	4.39
401.5886841	0.01
409.3008728	0.08
418.8896790	26.87
419.5230408	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	368.0963
Annotation	Zeanoside B
Peak:m/z	Relative Intensity
110.1009140	0.02
110.9099579	0.04
116.9730225	0.04
118.9877014	0.04
127.1132202	0.10
144.7175598	0.16
147.1481628	0.09
154.0657806	0.02
158.1286621	0.05
160.0191345	0.37
160.9556885	0.06
162.7068024	0.03
164.2333832	0.03
169.6274414	0.02
170.7899170	0.02
173.0513306	0.05
178.1341095	0.22
180.4160919	0.05
181.2539978	0.03
185.1736145	0.02
186.1554260	0.04
188.0397797	1.65
189.0936432	0.10
205.9960022	100.00
211.0912476	0.10
214.3899841	0.03
217.2781982	0.04
219.0472107	0.02
220.9916382	0.04
224.1407471	0.07
225.2245483	0.01
227.0353699	0.01
230.9339294	0.12
233.7505493	0.04
234.4776611	0.04
235.1015320	0.05
240.0731201	0.02
242.9303589	0.01
248.4391785	0.37
249.0715942	1.97
251.1576843	0.03
251.9240417	0.02
255.9758301	0.02
262.0854492	0.01
263.1597900	0.15
265.2607117	0.04
266.1025085	0.05
267.1917114	0.04
274.1939087	0.02
278.4395752	0.10
280.1049500	0.03
281.1259766	0.04
282.5922852	0.04
291.3915405	0.02
292.8275146	0.03
296.4462280	0.04
305.1451111	0.01
306.0712891	0.03
307.9260559	0.05
310.1524048	0.05
314.9357300	0.84
318.2281799	0.05
320.2854919	0.01
321.3106079	0.04
322.0813599	0.10
323.1740723	0.04
324.3153381	0.09
324.9549866	0.08
327.1847534	0.40
331.7989807	0.06
332.7797241	0.24
333.5688477	0.03
334.3577271	0.01
336.1195679	0.01
337.7245483	0.02
339.1154175	0.04
339.8914185	0.03
350.0642090	1.12
351.1155701	0.34
352.3050537	0.02
358.4538574	0.02
359.2257385	0.17
359.8565063	0.14
368.0598450	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.1088
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
160.9989777	0.13
179.0212708	0.09
215.1999359	0.01
284.1900635	0.02
298.0918579	0.04
299.1120605	0.14
311.1793213	0.07
312.9626465	0.10
323.0595703	0.06
326.1699524	0.13
327.2686157	0.02
339.3647766	0.02
341.0899048	100.00
342.1499634	0.04
353.0229492	0.12
356.9428711	0.09
365.2238464	0.04
367.1115112	0.16
371.1013489	7.85
379.3455811	0.10
381.3985901	0.02
383.1872864	1.51
384.2275696	0.01
385.2212830	0.12
395.3423462	0.05
397.3284607	0.02
407.1292725	0.43
413.0556946	0.08
425.2820435	0.09
443.0717773	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.79
Annotation	Unknow
Peak:m/z	Relative Intensity
261.0687256	0.15
273.0817871	0.06
275.3197632	0.31
277.0946655	0.13
307.4432068	0.04
315.3677673	0.09
324.2817078	0.11
343.2799988	0.21
355.2941284	0.11
367.3290405	0.10
376.0238647	0.09
383.1405640	0.05
395.1515503	0.33
401.3319092	1.21
405.7519531	0.03
419.3474121	0.81
420.5338745	0.17
445.2696533	0.35
482.4793701	0.07
563.1428223	0.42
563.7780762	0.04
564.3816528	0.07
589.6392212	0.08
593.2829590	0.11
607.3057251	100.00
608.2752686	22.82
608.9241943	0.02
610.5097046	0.07
625.0020752	0.23
626.2299194	0.09
633.3760986	0.43
634.2834473	0.24
651.2802124	25.20
652.2891235	6.93
669.2883911	2.48
670.3071899	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.1486
Annotation	N-Ethylcytisine
Peak:m/z	Relative Intensity
89.9558716	0.01
94.9110565	0.06
120.8968048	0.03
125.1313477	0.01
126.6862030	0.01
131.0617676	0.02
134.8830261	0.01
154.9201202	0.02
156.9080658	0.01
159.9564056	100.00
160.9737701	0.03
171.9550934	0.01
173.0102234	0.03
175.8934174	0.06
177.3011932	0.01
183.0171967	0.04
186.9768524	0.07
191.1240540	0.01
198.9218903	0.05
201.1369781	0.25
203.1012421	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.0477
Annotation	UDP-D-galactose(2-)
Peak:m/z	Relative Intensity
159.0032043	0.02
176.8314514	0.01
187.0808563	0.03
193.0216980	0.10
205.0931091	0.01
211.0571594	3.36
212.7872009	0.03
235.7953033	0.01
241.0272217	1.05
258.8694153	0.04
261.3182983	0.06
262.1267700	0.03
272.9599915	0.06
280.0709839	0.94
291.1553650	0.02
305.1243591	0.08
321.1376343	0.51
323.0709229	100.00
385.0945435	2.22
390.9362793	0.65
394.8012695	0.08
396.4282227	0.01
397.0322266	0.05
403.1051636	2.40
409.9327393	0.15
412.7548828	0.04
429.0809326	0.07
459.9750366	0.03
467.2123413	0.52
476.6505127	0.07
478.5748901	0.42
479.2120972	0.13
480.6498413	1.16
518.9760742	0.20
547.1464233	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Safflomin A
Peak:m/z	Relative Intensity
177.0916901	0.07
179.0325317	0.52
181.0343933	0.10
191.1524048	1.04
197.0707092	1.32
209.0918732	0.45
220.9992065	0.23
242.9688110	0.05
254.9344330	0.13
267.4283752	0.08
269.1047668	2.86
284.8414307	0.05
287.3200989	0.36
289.2274170	0.07
293.1112671	0.26
299.1599121	71.81
303.1442261	1.00
307.1763306	0.13
317.1362915	0.21
323.1972046	0.09
328.9963379	0.11
331.3698730	0.38
339.2590942	0.08
341.1959229	3.13
345.2407837	0.10
353.1071777	0.25
359.1635132	22.88
371.2216187	2.76
383.0827637	0.40
387.7500610	0.09
389.2161255	7.94
401.1361694	3.06
419.2478027	100.00
420.1173096	0.07
437.2208862	0.18
443.1591797	0.87
445.3085327	0.04
449.1620483	0.71
461.2011108	4.34
463.3236084	0.08
467.1867065	0.93
473.0625610	0.45
478.1461792	0.06
479.2361450	2.56
481.4323120	0.08
491.2009888	95.62
503.3572388	0.34
509.1007080	0.36
519.1423340	0.30
521.1759033	0.22
562.9586792	0.05
567.3718872	0.56
593.2748413	5.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.0904
Annotation	Glutathione
Peak:m/z	Relative Intensity
87.9893417	0.02
115.9246979	1.02
129.9016113	0.21
134.1038513	0.04
143.9659424	2.82
145.0532532	0.02
150.1722870	0.12
161.9992676	26.00
174.8132935	0.02
178.9331360	100.00
204.8519897	0.05
214.9676819	0.33
216.9819336	0.03
233.0684509	15.59
244.0799561	0.11
245.0697021	1.14
245.6731567	0.01
254.0827026	0.02
272.1554871	1.38
274.0283203	0.04
287.1261292	0.04
290.1106873	6.42
291.2077026	0.84
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.2136
Annotation	Isorhamnetin 3-rhamnosyl-(1->2)-galactoside-7-glucoside
Peak:m/z	Relative Intensity
305.3366089	0.02
312.1764832	0.07
335.2829590	0.03
341.9556885	0.04
347.1398315	0.02
366.1365967	0.10
368.9100952	0.04
372.2934570	0.02
381.0164185	0.01
383.1809082	0.13
384.1979370	0.33
396.0645752	0.06
412.9474487	0.06
413.8100586	0.09
414.5686035	0.08
436.9710083	0.02
437.8870850	0.03
439.3479004	0.03
444.1259155	0.04
455.3867798	0.07
471.8526001	0.03
480.1333618	0.05
485.1912842	0.04
486.0463257	0.06
487.1859741	0.02
489.3190308	0.01
502.1474609	0.01
503.2213135	1.43
504.2573853	3.43
516.2663574	0.06
519.1135864	0.01
520.1509399	0.01
534.1863403	0.34
534.7894287	0.19
545.1766968	1.10
546.2721558	2.93
570.3048706	0.07
575.5080566	0.21
576.3090820	0.65
587.1937256	0.07
596.0521851	0.03
606.1088867	0.40
609.6250610	0.14
610.3081665	0.39
623.2232056	12.48
624.2255859	59.51
624.8513184	0.26
630.0206299	0.01
646.2362061	0.08
648.3351440	0.53
650.2604980	0.01
651.2487183	0.03
665.4105835	20.20
666.2305908	100.00
666.8422241	0.32
695.1388550	0.19
696.2457275	1.12
708.2343140	0.51
710.0322876	0.03
719.3677368	0.05
720.2489014	0.04
726.1430664	0.03
732.5280762	0.05
737.9895630	0.14
742.1835938	0.05
750.2614136	0.15
756.4833374	0.06
768.3289795	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	509.1879
Annotation	7-Methoxydiderroside
Peak:m/z	Relative Intensity
179.0705261	0.12
181.1174011	0.08
190.8341675	0.16
221.2424164	0.68
247.0800781	0.31
262.9103394	2.16
263.5310974	0.19
273.0122070	0.23
274.9735718	0.11
303.1494751	1.86
304.8887329	0.04
314.4698486	0.09
317.3085327	0.13
319.2467041	1.15
320.7097778	0.07
329.1315308	0.62
331.2922974	0.11
333.4304199	0.11
344.9486694	0.32
347.0576782	1.27
357.1495361	0.40
363.3758545	0.10
365.1301880	100.00
369.4443359	0.09
371.8757324	0.45
391.4483643	0.15
405.0540771	0.35
407.2142944	9.76
415.0406494	0.05
423.1992798	0.13
435.2092285	0.08
443.5718994	0.18
447.1706543	2.11
449.7707520	0.16
463.3322754	1.05
465.2476807	0.36
479.0845337	0.19
481.2182007	23.07
482.6822510	0.26
491.1627808	0.50
494.2275391	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	697.1948
Annotation	Malvidin 3-(6''-acetylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
196.8598633	0.04
205.1874695	0.02
229.1660767	0.08
229.9671631	0.03
233.1647644	0.02
247.1753693	0.05
252.2102203	0.07
258.9255981	0.08
263.3781128	0.02
269.0165100	0.02
284.1542358	0.03
294.9334717	0.05
301.2708740	0.05
303.1054993	0.02
304.2123413	0.07
305.0126953	0.04
308.8148804	0.03
319.2271729	0.17
320.9523315	0.05
329.1021118	0.03
334.1536865	0.06
339.0259399	0.06
341.1951904	0.01
342.9438782	0.01
344.1373291	0.46
347.0902710	1.58
351.1731567	0.02
357.3187866	0.04
358.8897095	0.04
360.1936646	0.02
362.1206665	1.89
373.3687134	0.03
377.1190186	100.00
377.7550049	0.13
378.4500732	0.04
383.4011230	0.02
389.9785156	0.01
391.2054443	0.47
395.3768921	0.02
403.2673340	0.04
408.3724976	0.01
409.2656860	0.06
412.9757080	0.05
414.5313721	0.03
418.8597412	0.07
420.5216064	0.04
428.3763428	0.03
431.0211182	0.16
433.2466431	0.05
449.4849854	0.01
464.8644409	0.06
466.4382324	0.19
473.1066895	0.05
474.1470947	0.03
491.3482056	0.08
495.2625732	0.11
498.9262085	0.02
504.9328613	0.01
506.9252319	0.02
517.4564819	0.11
534.3024292	0.04
535.3751831	0.15
540.1397705	0.02
541.1968384	0.02
541.9370728	0.05
550.2409058	0.06
551.0341187	0.20
555.3556519	0.01
559.0042725	0.02
567.3117065	0.07
586.1614380	0.03
593.2106934	0.11
594.5513306	0.13
613.2019043	0.06
622.4076538	0.02
625.2632446	0.03
627.1676636	0.16
629.1469116	0.04
632.4562378	0.06
636.2382812	0.05
638.4354858	0.03
642.8646851	0.07
647.2570801	0.03
649.6079712	0.08
650.2730103	0.01
653.1593628	0.07
660.0114136	0.02
661.2662964	0.14
663.9216919	0.02
667.1309204	0.19
677.1953735	0.04
678.2496948	0.12
679.2075806	0.27
683.5799561	0.01
687.2439575	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	319.1853
Annotation	Valerylglycine
Peak:m/z	Relative Intensity
96.1839905	0.01
98.0634613	0.08
109.1833115	0.03
110.9597015	0.04
126.0567245	0.02
127.0794525	0.02
138.9879761	0.03
142.0708923	3.24
157.1448364	0.11
160.0008850	100.00
161.8818665	0.02
162.8947754	0.04
168.2511292	0.04
174.2794495	0.02
186.1526489	0.06
190.8220825	0.02
193.0104980	0.07
193.9949036	0.03
201.0922699	0.04
203.2817078	0.03
213.0699158	0.04
222.7197571	0.21
229.1137695	0.03
230.2615356	0.01
231.4692688	0.04
234.0762939	0.03
237.6159058	0.12
241.4229431	0.03
244.0743713	0.02
245.0108337	0.03
251.0973206	0.01
253.2743225	0.04
255.0486145	0.01
258.4898376	0.03
259.1959534	0.03
260.0163879	0.03
265.0603027	0.05
273.0639343	0.31
277.9386902	0.13
283.0751343	0.11
291.0533447	0.02
301.1296387	2.74
302.2398682	0.04
309.6565857	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.2993
Annotation	Phytosphingosine
Peak:m/z	Relative Intensity
95.2143860	0.03
97.0638351	0.28
109.1693268	0.54
111.1043930	0.02
121.0978317	0.42
123.2115326	0.11
125.1012573	0.12
134.9583740	0.77
138.9765472	0.04
149.2071533	0.16
151.2110901	0.13
158.7989807	0.05
165.2103729	0.02
171.4561310	0.04
177.0873260	0.02
179.2341003	0.06
182.7875519	0.10
193.2967377	0.04
198.2658997	0.07
211.1495361	0.69
225.0119019	0.12
233.3420410	0.03
234.1054688	0.24
235.2140198	0.08
241.4184875	0.07
247.2126770	0.26
252.4334106	0.73
253.3221741	0.04
254.4969482	0.11
256.4950562	0.52
264.1866760	0.98
265.2692261	3.62
269.1096802	0.05
270.3643188	1.20
282.2988281	45.39
283.2311401	0.06
285.1219177	0.10
300.2865601	100.00
301.1802368	0.09
303.2477722	0.14
304.3108521	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	796.61
Annotation	Unknow
Peak:m/z	Relative Intensity
290.6800537	3.28
292.7507019	2.53
374.6050720	1.06
376.6321411	1.85
418.8232422	0.06
440.2473145	0.14
458.5656128	8.08
460.5249634	15.00
542.4807129	43.40
544.5452271	95.18
545.7853394	0.14
588.5389404	0.13
626.2850952	13.70
627.0170288	0.70
628.3244629	57.42
629.0917358	0.09
630.3101196	0.23
660.5256958	0.66
661.1871338	0.12
665.7802124	0.12
666.5209351	0.07
672.5652466	0.11
674.1417236	0.12
680.4916992	0.06
689.3700562	0.28
690.2660522	1.36
710.2914429	11.79
711.6774292	9.24
712.3225708	100.00
713.0181274	0.24
714.4565430	0.27
720.3113403	0.17
732.0770874	0.26
749.5747681	0.92
750.4033813	1.54
751.6708374	0.23
753.6211548	0.14
778.6097412	0.17
779.4529419	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	212.1639
Annotation	3alpha-Isobutyryloxytropane
Peak:m/z	Relative Intensity
67.1727753	0.02
68.9719162	0.05
71.0198212	0.03
71.9198380	0.03
80.9125595	0.02
85.8302002	0.21
87.0649414	0.10
91.0915832	0.03
92.9986877	1.27
94.8707123	0.53
96.1653595	0.04
96.9983978	0.07
98.0086060	0.05
99.9605866	11.78
103.9190216	0.04
106.9124146	1.63
109.0459290	0.20
114.0112152	0.09
125.0888214	0.03
126.0216522	0.02
127.1273193	0.11
127.9194794	0.05
130.4046021	0.03
135.0090637	100.00
136.0932770	0.04
139.1299591	0.06
140.6643219	0.02
141.9055634	0.05
147.8625031	0.02
152.2415924	1.01
153.0977631	4.14
154.0287476	0.05
162.1390991	0.12
164.2631378	0.02
165.9593353	0.07
169.9673004	0.12
171.1669617	0.13
176.0043793	0.14
180.1252899	0.05
182.0948486	0.06
184.0302429	0.10
189.0355835	0.12
190.0248413	0.03
191.5034790	0.27
194.0423889	3.59
195.1826324	0.06
199.8989410	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	284.1331
Annotation	Unknow
Peak:m/z	Relative Intensity
83.0737305	0.18
84.9560089	0.04
87.1066971	0.16
88.7707520	0.19
92.1029434	0.10
93.9681244	0.14
95.9018402	0.10
99.7873306	0.15
104.8397064	0.62
106.0876541	0.15
107.1923523	0.13
108.9309540	0.32
113.1262436	0.20
116.0745544	0.26
117.0915070	0.26
119.9022903	0.11
121.9178772	1.24
125.0984039	0.12
126.0477295	0.14
127.0324249	0.45
132.9908142	0.16
135.0923462	0.39
135.9981995	0.27
137.1868286	0.07
139.9270630	0.32
144.9791870	0.60
146.1593323	0.13
149.0903473	0.20
150.0738525	0.27
151.9779053	0.67
152.9963226	0.09
156.0359955	0.16
157.5753784	0.10
158.1920776	0.06
160.8155060	0.09
162.8848267	5.76
164.0880432	0.76
165.0399170	0.09
170.8017426	0.19
176.0596619	0.17
177.0407715	0.17
178.2836304	0.09
179.9966583	4.67
182.3433533	0.10
183.0292664	0.24
184.0736389	0.25
185.3473206	0.04
187.2947693	0.27
187.9565735	1.27
192.3763885	0.17
195.0551758	0.07
200.9923401	0.04
205.9142151	0.58
211.1023865	0.08
212.1828918	0.15
214.1340332	0.13
222.7673645	0.68
224.2853394	0.69
230.5684204	1.45
231.1981812	0.09
236.2379150	0.04
238.2133789	1.57
240.2002258	0.40
241.4738159	0.55
242.2061768	0.17
242.9154663	0.08
248.1605225	3.53
248.9883423	1.96
256.1277466	1.07
257.1026917	0.09
266.1789551	11.65
266.9509888	100.00
270.0470276	2.31
284.5732422	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1558
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
166.9876099	0.03
183.2223206	0.03
195.1361389	0.05
197.0185547	0.04
200.9430847	0.05
224.2056427	0.11
225.1764526	0.04
227.0877838	0.04
269.046875	100.00
285.2709961	0.02
311.2449951	0.35
335.1896362	0.05
413.229187	0.04
531.4143677	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	922.75
Annotation	Unknow
Peak:m/z	Relative Intensity
288.8717041	0.20
403.1096191	0.27
418.7783813	0.43
434.8245850	1.36
548.7463989	1.35
564.9629517	3.33
662.8144531	1.20
678.7613525	5.92
694.8601685	5.28
792.7650757	9.28
804.8915405	0.07
807.1522217	0.75
808.6868286	100.00
809.3679810	0.48
818.7432251	0.07
820.3292236	0.28
850.8301392	0.22
866.8532104	0.25
876.7678833	0.11
878.7247925	0.16
892.9298706	0.12
894.7785034	0.06
899.6858521	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Safflomin A
Peak:m/z	Relative Intensity
176.8434448	0.09
183.2970123	0.06
200.8836365	0.17
203.0545197	0.08
207.1727448	0.27
214.2074432	0.02
243.0616302	0.03
243.9962769	0.13
258.3363342	0.13
262.3922119	0.04
271.0885010	0.04
286.2197266	0.03
299.8325806	0.06
301.0880127	5.00
302.1499023	4.00
303.2291260	2.92
305.1911011	1.10
323.0447083	0.35
326.3647461	0.05
327.1372070	0.04
342.8148804	0.13
347.0973511	0.17
359.3275146	0.15
364.7154541	0.04
368.1852417	0.04
405.3211670	0.17
423.1230469	3.54
430.5207520	0.13
449.3551025	0.31
454.8637085	0.25
459.3343506	0.11
460.9298706	0.04
464.9505615	0.12
467.0776367	100.00
475.3850098	0.14
491.3339233	0.15
509.1793823	4.19
524.3912964	0.12
525.2244873	0.46
532.5913086	0.14
549.1737061	1.04
567.2144165	0.08
575.0861206	0.06
592.5349731	0.03
593.3060913	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	683.1827
Annotation	Tricin 7-rhamnosyl-(1->2)-galacturonide
Peak:m/z	Relative Intensity
194.0970306	0.05
196.0534363	0.13
205.0099792	0.05
209.1412048	0.04
223.0771484	0.15
224.1064148	0.05
224.8391571	0.04
229.2149963	0.27
239.4332123	0.04
243.3496094	0.06
245.9924927	0.22
266.9096069	0.05
274.1128540	0.27
285.6258240	0.23
286.9274292	0.24
299.2872925	0.12
300.1016846	0.04
301.3065796	0.53
302.1430664	4.63
304.3515015	0.09
315.0812988	0.48
317.1265869	30.83
318.1510925	0.03
325.8383179	0.16
326.9767456	0.04
328.3791504	0.02
329.2557373	0.15
331.1983032	0.22
332.1994934	0.94
339.0277405	0.11
340.4851990	0.26
342.0235596	0.68
343.2208862	0.46
345.1314697	14.51
346.1632080	0.04
347.0623779	0.06
354.9583130	0.06
357.1682739	0.32
359.0556641	3.87
360.1546021	69.66
361.2583008	0.32
371.2848511	0.10
373.1813965	0.92
375.0500488	100.00
376.2376709	0.58
385.3026123	0.06
386.2627563	0.12
387.3493652	0.04
388.5541382	0.11
390.9830322	0.08
394.4278564	0.20
399.1812134	0.10
402.4849854	0.09
403.4026489	0.06
412.2782593	0.07
417.3256226	0.15
432.8834839	0.16
447.2362061	0.26
469.1100464	0.17
477.1802368	0.06
500.3309937	0.18
503.4030762	0.14
517.1980591	0.14
519.5800171	0.13
520.1967773	0.31
533.1571655	0.03
537.2013550	0.18
545.3842773	0.03
551.3049927	0.02
559.5598755	0.17
579.6565552	0.04
580.9844971	0.07
591.4276123	0.06
597.3236694	0.20
623.4105225	0.66
637.0974731	0.05
639.4738159	0.10
640.1408081	0.22
646.3572388	0.11
651.0034790	0.60
652.2848511	0.44
653.2761841	0.63
655.2033081	0.42
664.4086914	0.35
668.2255859	10.33
669.4119263	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.0828
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
120.8997345	1.50
128.9984589	8.38
131.1574097	0.24
133.1286011	0.12
145.1788635	0.14
147.0006409	0.04
154.7397003	0.04
159.0947113	0.24
161.0494995	0.75
162.9578552	0.03
173.0317383	16.06
189.0630188	5.39
233.0423889	0.59
251.1221008	13.90
259.0791626	0.74
277.0624084	1.59
293.7378235	0.07
295.0315552	100.00
355.1279907	0.15
373.0670776	0.12
398.9862366	2.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	650.168
Annotation	Unknow
Peak:m/z	Relative Intensity
185.8670959	0.11
187.5301056	0.12
188.1464081	0.03
197.9578552	0.40
201.3917999	0.04
203.5828094	0.03
215.9038239	1.67
216.7744446	0.04
218.1548462	0.12
223.8018951	0.15
233.9102325	0.28
239.1153870	0.17
246.0954895	0.12
247.8517609	0.53
249.9372253	1.27
251.0559845	0.10
255.9021759	0.14
260.0161438	10.05
263.1311035	0.17
263.9710388	0.06
272.0399780	1.65
273.9664917	1.21
275.9776611	0.15
277.6484985	1.57
280.0046387	0.19
286.0278015	0.67
287.1233521	0.09
289.9713440	2.09
293.8104858	0.09
296.1657104	0.19
317.9754639	0.05
321.3092041	0.07
326.0319214	0.14
334.0434570	0.18
338.1813354	0.02
350.0801392	0.58
351.9711304	42.69
353.1347046	8.87
354.1564331	2.11
355.3401489	0.17
367.9852905	0.05
369.6867065	0.44
374.9386597	0.25
384.0040894	1.39
396.1528931	0.49
407.7787476	0.19
412.0664062	100.00
413.0283203	0.94
414.0493164	0.58
423.2272339	0.15
424.0996094	0.16
425.5438232	0.38
426.1464844	0.21
428.0595093	0.05
436.0928955	0.08
438.0639038	0.12
439.0655518	0.21
440.3267822	0.20
442.0572510	33.26
442.8226318	0.83
443.4791870	0.04
444.3670654	0.27
445.4042969	0.04
457.0185547	0.04
458.1096191	0.28
459.7853394	0.54
464.6442871	0.07
468.1341553	0.24
470.0920410	0.07
472.9594116	0.95
473.7963867	0.20
478.1925659	0.25
479.0349731	0.04
483.7835083	0.04
486.3091431	0.58
487.3424683	1.55
488.0712891	6.99
492.2060547	0.07
495.1665039	0.06
495.8320312	0.23
501.0394287	0.34
502.1556396	0.06
511.4371338	0.23
514.0379639	2.56
516.1530151	0.19
518.2114868	0.07
523.2658691	0.28
527.7399902	0.08
529.0305786	0.12
530.1814575	0.35
531.8616333	7.47
533.1208496	0.93
534.1555176	0.04
537.9956665	0.17
544.5747070	0.33
552.9511108	0.10
554.1099243	0.28
558.7481079	0.33
559.9042969	0.94
561.0346680	0.08
573.7909546	0.10
575.9601440	0.13
589.3660278	0.54
590.0664673	1.56
590.6727905	0.04
601.7703247	0.05
605.8611450	0.02
614.2404175	0.11
618.2675781	0.12
619.1858521	0.26
625.3861694	0.06
629.4198608	0.25
631.1082764	0.07
632.1550293	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	287.0771
Annotation	Dianthoside
Peak:m/z	Relative Intensity
82.9983215	0.39
96.8847122	0.14
99.0079117	0.07
100.9373932	0.58
107.2412186	0.09
124.9307632	100.00
138.9446564	0.09
143.0086365	0.23
148.9969635	19.45
150.9579926	2.25
157.7967224	0.05
159.0878906	0.08
160.9027252	6.03
166.9169006	0.83
179.1388550	1.24
183.3109131	0.10
190.8786011	0.39
197.1528320	0.20
198.9993591	0.33
199.9147034	0.21
209.0948792	1.03
215.0663452	0.17
227.0280762	1.33
228.0117493	0.07
241.1865845	0.06
242.9718018	0.94
245.6457214	0.16
257.1204834	0.09
259.1677551	0.34
268.9128418	0.52
271.0281067	0.06
272.2975159	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	631.2144
Annotation	Kodaistatin A
Peak:m/z	Relative Intensity
177.0102386	0.12
178.9641876	0.14
183.9168549	0.31
186.1845093	0.26
187.2653961	0.18
189.1568909	0.64
191.9749451	0.15
200.3125305	1.20
201.1604004	0.39
202.4826813	0.74
203.1438293	1.08
204.4774933	0.06
205.1918182	0.16
206.2378540	0.17
208.2177887	0.08
214.0103149	0.46
215.0782166	0.42
216.0617523	0.06
217.0661926	1.23
218.1331482	0.62
220.2020111	0.46
221.0097351	0.10
228.2227936	1.68
229.2475281	0.53
231.8947754	0.15
234.1975861	0.72
236.2216187	0.13
243.2326355	0.30
245.2154694	0.05
247.1358337	0.91
248.2385864	0.51
262.1430359	24.42
266.2256165	0.16
271.1683350	1.97
273.1079102	0.08
281.2473450	0.34
283.1639404	0.71
290.0954285	3.26
295.2139893	3.48
300.9002991	0.33
307.1151733	1.44
311.1194458	0.47
314.1528320	0.06
318.9032898	0.22
320.1320190	0.16
322.0063477	0.10
323.2200317	0.49
325.3239136	0.13
332.3191528	0.93
336.0205688	0.13
343.2478027	0.08
347.1173706	2.95
347.7688599	0.11
351.6353149	0.41
365.1637573	100.00
383.3010254	4.37
411.2765503	0.29
413.3446655	0.07
424.5911865	0.12
425.4171753	0.21
427.2921143	0.43
449.1081543	0.37
455.1004639	0.22
469.4362183	0.07
487.0695801	0.16
498.3912964	0.10
506.9780273	0.12
514.4003906	0.05
520.4725952	0.47
527.4168091	0.14
539.4088135	0.40
545.1174927	2.66
567.4031372	0.14
569.1608276	0.84
570.0725708	0.15
577.2899170	0.05
578.3595581	0.10
587.2328491	4.49
595.0687866	1.05
603.0817261	0.21
613.1804810	4.74
614.4545288	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
109.1633759	0.44
127.1410294	0.72
129.005722	0.62
145.0390625	1.27
155.0247498	2.11
171.0978088	1.47
173.0718994	4.49
185.09198	2.88
187.1343536	2.24
195.1491699	0.22
197.1152039	0.37
199.1691437	6.12
201.2676697	2.71
203.0169067	0.93
213.3186035	0.92
215.1305542	8.31
225.2364197	1.78
229.1908875	3.39
239.1255493	1.40
241.1401367	1.07
243.2453613	2.45
245.2882996	4.51
255.086853	8.30
257.3111572	5.08
259.138916	1.89
261.3293152	0.35
263.3075256	2.86
269.1139221	2.22
271.2865601	10.07
277.0026855	0.74
283.0366821	2.90
285.2142944	4.41
287.255188	1.12
297.2974854	10.36
298.4084473	1.10
299.1901855	1.96
301.6075439	1.41
311.2888184	0.79
312.7189026	1.35
313.4154663	0.61
315.4373779	3.41
321.4307861	0.52
323.2001343	5.54
327.142334	0.67
328.9280396	1.35
331.0582886	0.47
337.5863037	1.33
339.2391357	100.00
339.8443604	0.80
341.3861084	26.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1382
Annotation	Luteolin 7-galacturonide-4'-glucoside
Peak:m/z	Relative Intensity
184.1320953	0.00
189.3349762	0.01
230.9211578	0.01
266.9879761	0.02
283.4164734	0.02
285.1914978	0.01
301.2055054	0.14
302.3377075	0.02
304.1021118	0.01
317.1707153	1.23
318.1390991	0.37
319.1762390	0.46
324.9641113	0.02
341.1689453	0.00
342.3134155	0.01
344.1033325	0.01
347.1955566	0.03
349.3838501	0.05
359.4489746	0.01
361.2345581	0.07
362.1560059	0.28
363.2089844	0.03
377.1266479	100.00
377.9433594	0.01
392.4910278	0.02
401.2866211	0.02
415.5276489	0.01
419.2882080	0.00
424.8674927	0.01
430.9847412	0.02
443.3267212	0.04
445.3523560	0.03
460.2595215	0.02
463.1068115	0.27
467.4418945	0.01
479.0282593	1.33
487.1946411	0.25
503.2327881	0.05
505.1978149	0.06
519.4394531	0.02
521.4353027	0.04
529.3128052	0.05
539.0251465	0.14
541.0568237	0.06
545.3788452	0.02
559.2834473	0.11
571.1995239	0.11
580.5802002	0.01
589.1804810	0.22
605.3870850	0.01
606.5775757	0.08
607.2086182	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	545.1511
Annotation	Unknow
Peak:m/z	Relative Intensity
162.8738098	0.14
176.0560913	23.37
191.0699158	100.00
238.8446655	0.05
307.1566772	0.48
339.3119507	0.09
353.1282959	5.61
354.9211426	0.05
365.4637451	0.02
383.3537598	0.17
390.6598511	0.12
421.0952148	0.14
425.2790527	0.05
439.0700073	0.08
441.3857422	0.04
458.0600586	0.05
481.3331299	0.08
483.6421509	0.08
498.1232300	0.32
498.8538818	6.11
499.6802979	0.18
500.8940430	0.08
501.7411499	0.03
503.2047729	0.05
522.3247070	0.12
526.3226929	0.08
527.0964966	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Diosmin 
Peak:m/z	Relative Intensity
211.0686951	1.24
253.1832581	1.26
284.0799255	36.81
299.0548706	100.00
345.4833374	1.21
359.3762817	0.30
361.4464722	3.57
377.2583618	1.43
383.0652466	0.78
441.4762573	0.46
443.4524536	1.65
459.5594482	0.99
465.4547729	1.04
495.1537476	0.85
497.2914429	3.61
520.6950684	0.67
525.4099731	0.85
527.3163452	2.31
545.0929565	0.92
561.2630615	1.12
562.5029907	1.97
563.465271	2.64
571.06427	0.53
587.3730469	1.71
588.9667358	3.42
589.8425903	1.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.1487
Annotation	Luteolin 7-sambubioside
Peak:m/z	Relative Intensity
197.0186920	0.03
216.8970337	0.03
225.0892944	0.05
244.0554199	0.04
254.1459656	0.03
284.2525024	0.02
287.1406860	2.55
299.1951904	0.65
300.1907349	0.05
311.0379028	1.17
325.2872314	0.07
329.1781616	8.82
333.1881104	0.06
339.2936401	0.03
343.1963501	0.03
353.2216797	1.15
357.1618652	0.11
359.2510986	0.21
365.2246094	0.07
367.3251343	0.17
371.2260742	0.09
374.6523438	0.08
377.2426758	0.02
383.1735229	2.71
384.0016479	0.05
394.0998535	0.02
395.1664429	0.95
397.2967529	0.02
398.7796021	0.02
402.2694092	0.05
403.3739014	0.02
409.2277832	0.07
413.2043457	3.25
414.3494263	0.08
415.7504272	0.01
417.0092163	0.10
418.0121460	0.03
419.0524902	0.23
431.1776733	20.36
432.2850342	0.24
435.2765503	0.04
441.1665039	0.02
442.3215332	0.02
443.2592163	0.08
447.2124023	0.06
449.1541138	100.00
450.2497559	0.67
451.8463135	0.03
461.1830444	3.08
472.9100342	0.04
479.0995483	0.02
491.2968140	0.16
499.6574707	0.13
502.3971558	0.06
510.4022217	0.01
515.1283569	0.06
518.2279663	0.09
521.0200195	0.03
527.3576660	0.09
536.5631714	0.05
545.1938477	0.06
551.3952026	0.07
563.1716309	1.25
571.4155273	0.06
572.1496582	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	409.02
Annotation	Unknow
Peak:m/z	Relative Intensity
154.0281067	0.04
201.0850220	0.20
201.8624878	0.12
203.1224976	0.11
212.9916229	0.18
217.0714417	0.17
223.2673492	0.09
228.9795532	0.06
231.0136414	0.26
234.9385376	0.51
248.0940247	0.05
251.1123352	0.05
256.8590088	0.23
258.4784546	0.12
259.2879944	0.15
262.4356384	0.23
272.9863892	0.16
275.0849609	2.79
276.0006409	0.65
277.0928345	0.06
278.2066040	0.11
285.2002563	0.14
292.5686035	0.05
301.0397339	0.57
303.0521851	0.29
313.1444702	0.14
318.9684143	13.34
328.8740234	0.08
331.0810852	0.11
333.8930054	0.55
342.8661804	0.17
345.1912537	0.68
347.0473328	10.27
349.1779175	0.23
360.8009949	0.14
362.9851990	4.18
364.4387512	0.31
365.1579895	0.20
365.9174805	0.09
368.4084167	0.38
373.0434875	3.87
378.3450317	0.06
389.1270447	0.14
391.0627136	100.00
400.8596802	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1637
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
271.0872192	0.23
285.9951782	0.02
286.9996948	0.01
301.0950317	1.11
302.2155151	0.01
313.0647583	0.18
325.2509155	0.22
327.1436157	0.05
329.3254395	0.03
337.2877197	0.05
343.1145020	7.12
344.2413940	0.04
355.2261353	0.07
363.0893555	0.03
367.1869507	1.52
373.1813965	0.23
385.1563110	0.03
393.3067017	0.05
397.2326050	3.76
401.1956177	0.07
409.2603149	1.15
415.2062988	0.44
421.2461548	0.26
423.3894043	0.02
427.2222900	2.62
428.0555420	0.04
429.5663452	0.03
432.5045776	0.15
433.1324463	1.31
439.2093506	0.18
445.1077881	18.30
457.2084961	5.77
463.1027222	100.00
463.9038086	0.42
464.6956177	0.02
473.2502441	0.02
475.1762085	4.08
481.3709106	0.53
487.1838379	0.18
493.4899292	0.10
499.2394409	0.72
511.2111206	1.09
520.1138306	0.05
523.2581177	0.68
529.0685425	2.90
541.1609497	1.80
559.0943604	4.28
559.7672729	0.03
577.1180420	17.50
577.7736816	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	341.1221
Annotation	Juglanoside B
Peak:m/z	Relative Intensity
102.9076843	0.22
122.9077759	0.14
127.0414810	0.58
137.0222778	1.40
144.9136658	0.85
147.0205078	1.33
148.0037537	0.50
149.0611267	0.48
157.2939453	0.03
159.1458130	0.18
161.1522064	0.37
162.7929688	0.07
164.2782440	0.12
165.1869812	0.17
166.9572144	0.21
168.8811035	0.09
173.0904083	0.11
175.3097839	0.11
177.0057526	0.19
178.9729309	100.00
183.2306213	0.12
187.0478516	0.31
188.9756165	0.50
190.9926758	0.83
194.7548981	0.31
196.9284058	2.40
205.0575562	0.09
208.8832397	0.14
211.2146912	0.06
212.2960815	0.07
214.8694153	0.03
217.0404968	0.57
219.3898315	0.10
220.4629517	0.24
221.1441956	1.94
223.1524353	0.07
224.8449097	0.03
229.0948486	0.06
233.1707764	0.57
238.9904480	3.36
242.2670288	0.19
243.8184204	0.04
245.0916443	0.77
247.0711365	0.19
247.7754822	0.10
253.0518799	0.41
257.1681213	0.41
259.3730774	0.43
261.5902405	0.18
262.9237061	5.08
267.0007019	0.23
274.6888123	0.11
277.3305054	0.08
280.9948425	0.32
283.3277283	0.28
287.0998230	0.38
290.9890747	0.19
293.0667419	0.25
295.0856018	0.57
296.2685547	0.04
297.1527405	0.15
299.2921143	0.04
305.1688843	8.81
306.3430786	0.22
309.1372375	0.43
311.2803040	0.20
312.3216248	0.10
313.1416931	0.47
315.5245361	0.10
321.0427551	0.04
323.0299072	35.94
324.4224854	0.07
326.1861572	0.32
332.6111450	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	297.0597
Annotation	Phaseolic acid
Peak:m/z	Relative Intensity
86.7234573	0.26
97.0738449	0.16
99.1066818	0.11
100.7336197	0.16
104.9350357	100.00
110.7750244	0.32
112.6785355	0.14
118.8332825	0.02
119.8464508	0.26
122.9265137	22.23
127.0132599	0.08
128.9280396	0.97
132.0150909	0.13
137.9937897	0.06
138.7751770	0.09
146.4644470	0.33
147.2986145	0.13
153.1728821	0.25
154.8764648	0.26
156.9414062	0.75
158.9710541	0.24
160.0929565	0.06
163.4097595	0.26
166.9572296	0.12
168.9064636	0.12
171.0506592	0.08
175.0591125	0.13
183.1074829	0.16
184.9664001	0.18
193.0869751	0.13
194.9434662	0.20
197.2091217	0.11
201.0977783	0.10
202.1473999	0.10
203.2302246	0.07
207.4557190	0.38
209.1309204	0.04
211.0466309	0.39
212.9828491	0.31
219.2489014	0.37
223.1421814	0.13
224.3794556	0.09
225.0922852	0.11
226.0133057	0.06
227.2169800	0.03
228.1458740	0.04
229.1730652	0.11
237.0784912	0.89
239.1859436	1.03
241.0721436	0.41
243.2002869	0.32
247.1436768	0.15
249.2295532	0.16
251.0013733	22.90
252.0123291	0.20
254.0701599	0.08
255.1635742	0.09
256.5587769	0.24
261.0083008	0.98
261.9681091	0.34
265.1697388	0.27
267.1907959	0.08
268.8574524	1.88
269.9824219	0.05
273.9080200	0.23
279.0321655	63.89
280.1512451	0.32
281.2385559	0.33
282.2258911	0.03
287.6336975	0.11
288.4764099	0.29
296.8976135	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1561
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
169.062149	0.03
180.0860138	0.10
181.2569885	0.17
182.2605591	0.04
183.1070251	0.13
194.9754791	0.04
197.0717773	0.03
225.105545	0.19
227.0640564	0.16
241.170517	0.01
253.1768188	0.06
269.0450745	100.00
269.8847961	0.03
311.0473633	0.21
335.3060913	0.10
413.2797852	0.09
430.8886719	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1511
Annotation	Kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
168.9138794	0.02
173.1450806	0.04
174.9328308	0.16
182.147049	0.03
183.091217	0.03
185.0503235	0.11
186.8788147	0.01
193.103653	0.02
194.9358215	0.02
196.0947266	0.25
197.3539886	0.15
198.0843048	0.28
199.1117859	0.70
201.1702271	0.13
211.0775299	0.11
213.3406982	0.11
214.2430878	0.11
215.1914673	0.10
217.1017609	0.34
222.9797058	0.03
225.2007751	0.08
226.0647583	0.11
229.1231232	0.03
240.1901093	0.17
241.2269897	0.19
242.0780792	0.04
243.1343994	0.68
256.0355225	0.08
257.0673218	0.19
265.1069336	0.04
267.1672363	0.18
270.2000427	0.08
283.0167236	0.05
285.0506592	100.00
286.1724854	4.18
293.0483398	0.12
297.9734497	0.11
298.9106445	0.29
311.0085449	0.02
315.2275391	0.07
322.8230591	0.18
324.9415283	0.04
327.1586304	0.57
340.0648193	0.08
341.1295166	1.16
348.4440308	0.04
351.4204712	0.01
353.2236938	0.75
357.111084	0.02
371.2759399	0.06
381.192749	0.05
383.1532593	0.27
389.3032227	0.19
393.1152344	0.02
395.2344971	0.16
407.1017456	0.02
413.2460327	0.53
431.4084473	0.10
443.2266235	3.81
447.2127686	1.13
449.406311	0.06
455.2692871	0.05
456.9500122	0.04
473.2415771	1.69
474.2531128	0.14
503.1494141	0.49
516.3786011	0.03
517.4624023	0.07
533.4567261	0.10
545.1617432	0.05
547.3999634	0.07
549.2568359	0.09
558.2195435	0.01
574.697998	0.11
575.3266602	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	461.1068
Annotation	Acacetin 7-glucuronide
Peak:m/z	Relative Intensity
169.2236328	0.06
171.3285828	0.02
193.3620605	0.06
231.3494263	0.07
259.1950073	0.09
266.3323364	0.08
269.1357422	0.02
271.2830811	0.13
287.0063782	0.13
297.3726807	0.03
301.0852051	34.26
301.7080688	0.14
305.0267639	0.07
313.2023315	1.64
315.2275085	0.09
317.2489624	0.05
323.4072571	0.03
325.1708069	1.29
325.9159546	0.05
331.4447937	0.04
333.3439941	0.02
336.9729919	0.25
339.5325317	0.24
343.1105347	16.23
355.4453735	0.08
367.1513672	11.69
368.0087585	0.01
373.1685486	0.90
379.6199646	0.08
381.4176331	0.15
382.2725830	0.18
385.1576233	0.02
391.1739502	0.18
394.2954407	0.16
397.1190491	25.64
401.2738037	0.03
401.9031067	0.04
403.2878113	0.19
405.3070984	0.10
406.9134827	0.05
409.2430115	6.12
413.9495239	0.04
421.2598572	0.02
427.1933594	20.61
428.1137390	0.22
433.5996399	0.10
445.1313782	100.00
446.2989807	0.10
448.5236816	0.11
463.1445923	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.1175
Annotation	Unknow
Peak:m/z	Relative Intensity
100.0411606	0.07
101.8903656	0.02
107.0779877	0.06
111.9050369	0.14
116.0277252	0.13
120.8680649	0.07
122.0438385	0.04
129.9233093	0.37
134.0542297	0.03
136.0988464	0.16
139.0121307	7.92
142.1037903	0.06
144.4411621	0.02
146.0289001	0.08
148.0017700	1.37
151.0174255	0.09
156.0226593	0.48
159.1914062	0.32
162.7654572	0.06
165.9861755	0.03
168.1063690	0.10
179.9792023	1.46
181.9478455	0.25
182.8321228	0.11
186.8991394	0.13
189.0136719	0.21
202.0908356	0.04
207.0784607	0.09
210.0807495	0.12
228.2183228	0.11
228.9465332	0.17
230.1390991	0.06
232.8536682	0.26
234.2065125	0.11
235.0087280	0.13
243.2043152	0.13
246.2021484	0.05
251.3066711	0.35
253.1641846	0.12
254.6842651	0.53
256.1919250	0.05
260.0465088	0.14
262.1151123	0.61
265.0976562	0.22
267.2155151	0.27
272.2091064	0.20
274.0548706	0.47
275.5756836	0.12
277.0310974	0.27
283.0823059	1.00
287.1141968	0.17
290.2494202	0.47
291.0466003	0.16
298.1708984	0.24
300.2573242	11.56
300.9173279	100.00
301.6005554	0.21
307.1898499	0.42
308.7955322	0.05
309.7496033	0.21
311.5534973	0.33
317.9728699	0.15
319.4913635	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1511
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
175.0795441	0.11
185.0634155	0.04
195.6787109	0.05
197.1656647	0.03
198.083374	0.13
199.0459442	0.19
201.008194	0.26
212.2360382	0.06
213.1919861	0.16
214.3348846	0.04
215.2051086	0.12
216.9355164	0.22
218.2344513	0.03
223.908371	0.09
225.9420776	0.12
238.8374329	0.04
241.0894928	0.17
242.1438293	0.03
243.1808472	0.48
256.9339294	0.37
266.8909912	0.29
283.3952332	0.02
285.0368652	100.00
286.0890503	2.80
293.2818604	0.03
298.1539917	0.02
299.0935669	0.03
323.2505493	0.21
325.1358643	0.09
327.116394	0.40
336.2391357	0.05
339.1223755	0.09
341.1592407	0.87
353.1309814	0.80
354.223877	0.16
369.3691406	0.08
371.3530884	0.03
377.4373169	0.02
383.1531372	0.38
389.2518921	0.12
407.1914673	0.03
413.2310181	0.20
431.4331055	0.27
443.2215576	4.72
447.2993774	0.84
449.432373	0.08
453.296936	0.09
455.1107788	0.08
463.2589722	0.28
473.1880493	2.71
474.4611206	0.05
487.5391846	0.03
491.2800293	0.08
503.2272339	0.75
517.2556763	0.05
532.0376587	0.06
533.1791382	0.26
575.135437	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.3069
Annotation	Unknow
Peak:m/z	Relative Intensity
259.2745361	0.05
317.3311157	0.03
330.0619507	0.04
337.1530762	0.31
339.9371338	0.05
341.2874756	0.04
347.1376343	0.04
353.2814331	0.06
361.3500366	0.06
385.4157715	0.22
395.4754028	0.03
403.7443237	0.06
409.3605957	0.07
416.4677734	0.03
421.3815308	0.07
425.5023193	0.04
427.0268555	0.03
441.5278931	0.01
453.3424683	0.04
468.4616089	0.03
469.7886963	0.03
473.4609985	0.07
477.1348877	0.03
489.5839844	0.03
499.2873535	0.03
501.3184204	0.20
502.1999512	0.04
503.2772217	0.03
517.2680054	0.03
519.5626831	0.03
521.2241821	0.01
535.2942505	0.02
543.5872803	0.07
545.2868042	0.10
547.4319458	0.21
551.2573242	0.03
559.2409058	0.02
561.1334839	0.02
563.3511353	0.18
564.4014282	0.04
565.3699341	0.38
583.0838013	0.04
584.8561401	0.03
586.1489868	0.04
603.3856812	2.41
606.5693359	0.01
607.4946899	0.21
619.3560181	0.03
621.2437744	0.43
623.3415527	0.21
625.4197388	0.05
628.1994019	0.01
646.2864380	0.01
647.2434692	0.10
649.4746094	0.14
663.3032837	100.00
664.0314941	0.07
665.2355957	0.60
691.0269165	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.2185
Annotation	Cucurbitoside G
Peak:m/z	Relative Intensity
160.9182892	0.27
173.0193329	0.07
175.1950073	0.16
190.2174988	0.13
191.1170654	0.45
193.0187683	0.57
201.2659302	0.17
211.2131348	0.05
220.1770325	0.23
223.0390472	0.21
235.1754456	0.13
249.3251495	0.11
253.1576080	0.52
255.3863831	0.10
257.1644287	0.09
265.2084656	0.28
271.3168945	0.05
272.3131714	0.16
283.2212524	0.11
293.2577515	0.09
295.3950806	0.06
299.4565430	0.22
313.3234863	0.38
315.0786743	0.24
318.6952515	0.11
337.0834961	1.26
345.3869019	0.29
347.0667114	0.21
355.1002197	0.82
367.1834106	0.77
373.1644287	6.82
386.9785156	0.11
397.2349243	0.20
398.4237061	0.14
399.4508057	0.36
411.2570801	0.06
415.0472412	18.07
416.6326904	0.23
417.3118896	0.92
431.4688721	0.08
433.1395874	0.06
439.2686768	0.14
454.9448242	1.15
455.6044312	0.08
456.8812256	0.27
459.4903564	0.34
470.6291504	0.12
473.1056519	5.38
475.1175537	0.51
501.0347900	0.41
515.3816528	0.12
517.0559692	100.00
517.7565308	0.27
519.2060547	0.24
525.1514893	0.06
542.4776001	0.21
543.2227173	0.87
546.1760864	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	814.4451
Annotation	Unknow
Peak:m/z	Relative Intensity
224.6024780	0.12
227.5109711	0.06
233.0335693	0.23
233.7854004	0.04
234.9951172	0.23
237.0888519	0.03
238.1553345	0.09
241.9823456	0.18
247.4765778	0.19
249.7480316	0.08
250.7128906	0.03
254.5924530	0.14
255.5106506	0.17
256.1545410	0.03
260.3323364	0.03
261.1385498	0.08
261.7398682	0.13
262.8486328	0.12
264.1830444	0.15
266.3542480	0.09
267.1833801	0.07
268.3784180	0.01
269.4242249	0.09
272.6947327	0.15
273.3707275	0.10
275.8880920	0.07
280.8057251	0.44
281.8315430	0.04
283.4288635	0.04
285.1891479	0.12
289.5676880	0.17
290.1845703	0.63
290.8628540	0.19
291.9014893	0.08
292.6529236	0.08
295.4044800	0.24
296.3551941	0.10
298.2998962	0.56
300.3132019	0.03
301.3527222	0.34
302.7315063	0.04
304.0487366	0.69
304.9321289	0.28
306.6625977	0.18
307.3585205	0.09
308.7500000	0.09
310.1947021	0.28
312.6153870	0.17
314.1622620	0.01
315.5938110	0.06
318.5041809	0.49
320.3290405	0.33
321.3381348	0.04
323.4461060	0.17
324.6929321	0.03
326.7089539	0.05
328.0763550	0.01
329.4320374	0.27
331.2247009	0.02
332.2010193	0.58
333.3522949	0.09
338.7258301	0.16
339.3763733	0.12
342.6194763	0.36
343.4512024	0.04
344.3062744	0.09
346.8089600	2.82
347.5923462	0.03
349.1260986	0.13
351.2234497	0.38
352.3568115	0.38
353.3182678	0.04
354.8852539	0.40
356.7067871	0.17
357.3444824	0.13
359.7413635	0.19
360.8822632	1.86
361.8933716	0.25
363.3787231	0.01
365.6958008	0.16
366.4130249	0.05
367.0289917	0.05
369.4273071	0.10
371.2489624	0.07
372.0326233	0.03
375.2737427	1.10
375.9261475	0.03
379.6796265	0.06
380.2879028	0.09
382.3355713	0.17
385.2565308	0.20
386.0795288	0.21
386.9124146	0.08
388.9710083	1.13
389.8576050	0.04
391.3726807	0.08
394.3242188	0.59
395.0088501	0.37
397.9476929	0.01
399.3068237	0.04
400.3465576	0.02
403.4455566	3.39
404.1762085	0.01
406.1644897	0.03
407.2349854	0.01
408.5897827	1.47
411.1177979	0.03
413.1566772	0.03
417.4443359	100.00
418.4109497	4.96
421.0510864	0.02
433.2960815	0.04
440.3294678	0.04
448.3638916	0.06
454.0383911	0.07
455.5283813	0.02
456.4208984	0.10
461.3366089	0.05
465.3602905	0.02
468.5621948	0.02
472.8374023	0.01
476.2382812	0.03
484.2425537	0.04
492.7123413	0.02
493.3323364	0.06
498.6903687	0.05
500.4319458	0.03
502.2362671	0.06
510.1518555	0.06
511.3259277	0.22
527.9887695	0.12
532.3814087	0.02
544.1904297	0.01
551.2663574	0.14
556.2598267	0.06
561.1876831	0.03
563.0656128	0.05
568.3521118	0.02
569.3779907	0.17
570.3689575	0.12
577.6135864	0.18
578.5419312	0.11
579.5413208	0.08
589.4906616	0.01
590.4558716	0.02
593.8298950	0.04
611.6439209	0.07
615.3587646	0.04
616.2470703	0.03
624.4519043	0.13
625.5919189	0.02
629.2760010	0.04
635.1968384	0.02
646.5652466	0.04
654.5466919	0.13
666.9012451	0.05
680.2987671	0.04
682.3942261	0.15
683.3953247	0.14
691.5253906	0.03
692.5430298	0.12
698.6198120	0.04
699.2677002	0.16
702.5889282	0.01
714.4628906	0.06
717.1464233	0.07
748.7302856	0.07
754.4729004	0.04
758.7483521	0.02
763.6642456	0.02
767.6537476	0.60
768.4464722	0.25
770.4446411	0.02
771.2142944	0.03
772.6262817	0.04
777.4097290	2.17
778.4871216	0.45
779.2390747	0.13
790.6183472	0.06
795.4953613	4.38
796.5015259	1.73
797.3716431	0.35
798.3237305	0.04
800.7208252	0.36
801.5578613	0.04
805.6710815	0.85
806.5681763	0.21
833.5021362	7.37
834.5546265	3.83
835.6168823	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.2003
Annotation	Kadsuralignan A
Peak:m/z	Relative Intensity
135.1704559	0.07
136.8611450	0.06
148.9617310	0.07
152.0982971	0.09
153.1623688	0.11
159.3056793	0.10
161.0734253	0.06
165.3941650	0.03
169.1307373	0.04
175.3025818	0.06
187.1354370	0.07
195.1293182	0.19
196.9375000	0.15
201.0204620	0.13
202.4663086	0.13
219.2908020	0.17
225.1981201	0.09
230.2756653	0.08
231.3447876	0.17
235.9633484	0.15
243.0188599	0.08
252.2678223	0.21
257.2730713	0.16
259.3176880	0.18
261.0248108	0.09
269.0840149	0.52
274.2518921	0.09
285.0700684	1.23
296.4973145	0.09
302.8161011	0.68
303.4585876	0.37
304.1723938	0.07
307.3776855	0.13
314.3325806	0.19
316.4630737	0.34
320.9970703	0.30
323.0627136	0.07
324.3366394	0.13
326.9435730	0.18
341.2825317	0.09
342.3381958	0.03
353.0513000	1.10
355.2298889	0.15
359.7622070	0.38
364.1567078	0.12
365.1224365	0.18
366.2630920	0.05
367.3811951	0.22
369.5498047	0.09
370.9373474	22.63
374.2269592	0.06
376.1620789	0.06
377.0304565	0.11
378.3099670	0.06
384.0178833	0.06
385.5252991	0.05
389.0311584	1.50
392.5925598	0.12
402.2463684	15.25
402.9342041	100.00
403.8686829	0.08
420.1821594	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	757.2141
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
227.1012268	0.05
248.9346924	0.05
255.3157959	0.02
287.0903320	1.75
288.0366211	1.11
299.1271973	0.02
300.0324097	0.05
317.2091370	0.07
329.0657959	0.07
338.0883179	0.08
344.1905518	0.13
351.2764893	0.08
353.2842102	0.14
397.2603760	0.03
398.3034668	0.14
404.2705078	0.03
409.1644287	0.02
416.3720093	0.13
421.4246216	0.03
422.1180420	0.06
431.3267822	0.15
432.2746582	0.04
433.2645874	0.03
434.1706543	0.12
439.3008423	0.10
440.1035767	0.02
445.1863403	0.02
446.3007812	0.05
449.0675659	4.92
450.1353149	9.41
457.1634521	0.15
458.3826904	0.01
459.0126343	0.03
463.3239746	0.13
464.3248901	0.15
466.1457520	0.24
469.7792358	0.06
474.3861694	0.05
475.5496826	0.09
476.2525024	0.03
482.5038452	0.05
487.1053467	0.03
488.1047974	0.37
491.2724609	0.02
492.3004761	0.10
505.4371338	0.27
506.2764282	0.09
510.2656250	0.04
512.1535034	0.05
531.7265015	0.02
540.0919800	0.06
542.1198120	0.19
554.2177124	0.09
555.2450562	0.16
559.1424561	0.06
560.3447876	0.43
565.6640015	0.07
571.9873047	0.24
572.5956421	0.01
573.3500366	0.01
576.1293335	0.04
577.4295654	0.18
578.2814331	0.47
583.3420410	0.05
589.2202759	0.03
590.1427612	0.54
592.5895996	0.03
593.8059692	0.09
595.0781860	0.82
596.1648560	2.33
607.1348877	0.48
608.2083130	1.16
611.3156738	37.19
612.1075439	100.00
619.4782104	0.06
620.1951904	0.06
624.0767212	0.05
625.9125977	0.70
626.5991821	0.05
636.2073364	0.08
638.2315674	0.29
650.2153320	0.04
653.3567505	0.10
654.2407837	0.03
662.3284302	0.03
668.3916626	0.05
673.9883423	0.04
685.8660278	0.10
692.0098267	0.22
692.6143188	0.02
697.0686646	0.03
704.3388672	0.17
713.1884155	0.12
714.4243164	0.10
722.2310791	0.64
733.2266235	0.14
740.0642090	2.13
740.8192139	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	635.2678
Annotation	3-Hydroxyethylbacteriochlorophyllide a
Peak:m/z	Relative Intensity
181.1244659	0.06
183.0064697	0.13
187.0519409	0.34
191.2641602	0.07
194.2655029	0.36
198.9058380	0.26
201.2760773	0.20
207.0874939	0.50
210.3713837	0.14
211.1273499	0.13
213.2329407	0.37
214.0479736	0.09
215.0248566	0.74
216.0194855	0.08
217.3436890	0.11
221.1621399	0.24
222.9735107	0.35
225.0312958	0.09
227.0005188	0.23
227.9284210	0.07
233.2130737	0.07
235.1655273	0.38
236.7525330	0.17
239.1806488	0.09
241.1730957	0.63
242.1202545	0.04
243.2153778	1.68
245.2281342	0.16
246.2465668	0.08
247.2137146	0.38
248.1018829	0.12
249.4436646	0.04
251.4081879	0.10
253.3226013	0.07
257.2164917	0.20
261.1547241	0.04
263.2221680	0.27
266.2862549	0.06
267.1713867	0.08
271.9462585	0.27
275.4237671	0.23
277.2027588	0.22
278.9938965	0.47
281.0618896	0.62
283.2471924	0.99
285.1851196	0.06
289.0415039	0.42
290.6148682	0.17
291.2495117	0.30
292.6185608	0.48
293.3566589	0.04
295.3394775	0.30
297.2576904	0.48
301.1380615	0.25
303.0912170	0.40
305.0604248	0.19
307.3828735	1.34
308.8934326	0.29
309.5121460	0.22
311.3129272	0.88
313.3544922	0.20
319.0621948	0.27
321.3284607	1.74
323.0919189	0.98
323.8726807	0.04
325.1960754	0.60
328.8858643	0.32
331.2645264	0.65
333.3595581	0.75
334.5525513	0.17
336.4310913	0.07
337.0800781	0.29
339.0667114	1.08
341.2075195	3.63
343.2063599	0.06
345.4236450	0.09
347.2905273	0.59
349.1118774	1.13
351.2227783	2.30
353.2837524	1.00
355.2498779	0.34
357.1765137	0.83
358.9655762	0.13
363.2620239	0.89
364.1938477	0.05
365.1232300	0.50
367.1892090	9.97
369.1749268	19.21
375.2003784	0.34
378.1877441	0.04
381.1735229	0.91
383.0125122	0.21
385.1859741	1.70
387.3026733	0.22
389.5269165	0.14
391.1735840	0.80
393.2713013	0.92
395.1694946	3.42
396.6716309	0.27
397.3440552	0.06
401.4165649	0.04
409.2084961	3.01
411.1778564	5.70
413.2354126	12.92
414.3245239	0.10
415.0977783	0.34
419.2213135	1.02
421.2932739	0.10
425.2292480	0.16
427.2017822	7.49
429.3704834	4.17
430.1891479	0.06
431.1090698	0.61
432.9471436	0.21
435.7155151	0.27
437.1240845	2.92
437.7962036	0.51
440.1152344	0.09
441.3703613	0.29
447.4696655	0.04
453.3771973	0.16
455.1987915	4.47
461.2207642	0.11
463.3477783	0.08
465.1966553	0.65
471.2025146	0.03
473.1259155	9.61
473.7651367	0.19
475.4582520	0.43
481.3421021	0.08
482.3590698	0.13
483.1700439	0.21
487.2431030	0.13
489.4916992	0.33
491.1646729	1.31
493.3523560	0.45
495.2252808	0.11
497.5189819	0.22
499.3132935	0.08
502.8020020	0.57
503.4598999	0.31
507.4885864	0.07
508.3480835	0.20
509.3306885	0.06
512.9832764	0.33
515.3910522	0.23
520.9779053	0.05
522.9916992	0.04
523.7692871	0.06
524.4833984	1.26
525.3321533	1.86
527.3801880	0.15
533.1272583	0.10
535.2678833	0.41
537.2236328	0.16
541.3754272	0.16
542.4886475	1.51
543.4461060	1.16
545.4821777	0.22
549.1104736	0.23
551.4165649	0.14
553.2827759	3.07
555.2850342	1.38
557.2108154	0.53
559.2257080	0.14
560.3519897	3.05
561.3202515	0.18
571.2402344	25.59
571.9183960	0.05
573.2636719	3.45
581.1747437	3.49
589.3217163	54.70
591.2020874	0.10
599.1836548	16.71
599.8364868	0.05
610.2826538	0.07
613.5430908	0.31
617.3026733	100.00
618.2308960	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.2331
Annotation	Unknow
Peak:m/z	Relative Intensity
160.0213470	11.41
166.9804077	0.49
167.9830780	0.70
170.0270691	3.56
170.9187622	0.24
172.0825195	0.13
172.9061584	0.54
173.8451843	0.52
175.0858917	15.28
177.0271606	36.51
181.6103210	0.36
182.9661865	0.26
184.0469360	2.64
186.0020294	4.69
187.2789917	0.68
190.9679871	0.19
192.8329773	0.70
195.0549927	2.20
196.1796417	1.00
196.9382782	0.65
200.0239105	0.29
202.1576843	1.33
203.1150208	2.49
205.1419373	45.90
210.0011597	0.45
212.0448761	4.18
213.8697357	0.30
215.0941467	0.32
218.0873718	0.34
221.0810394	0.65
223.9625549	1.27
226.0551910	1.49
228.1401825	1.22
230.1820068	2.11
242.0617676	1.66
244.9790344	0.26
247.2040710	2.03
248.3342743	0.13
254.1693878	1.09
255.1841736	0.24
260.1286011	1.01
268.3214111	0.34
271.1549683	0.34
275.1449585	0.18
276.2192993	1.23
278.0302124	0.30
280.0773315	0.53
285.9796143	0.32
287.1903687	0.39
288.2196045	0.34
289.4267578	0.34
294.0673218	11.38
303.3190918	1.22
304.2593994	0.35
306.1711426	0.15
308.2971802	3.92
309.1413574	1.51
312.9790039	0.58
316.0441895	2.59
318.2931519	6.05
319.2179565	0.46
321.0892944	11.51
322.2194214	1.11
324.6699829	0.23
328.3206177	0.32
329.4860229	0.26
330.1815796	0.24
331.1631470	0.22
332.3991089	0.63
334.0154419	3.64
336.1606445	100.00
336.7800903	0.65
338.1373901	0.92
339.0183105	1.86
340.1482544	0.17
342.1322632	0.57
347.2195435	0.97
348.2617188	2.90
350.1795654	1.37
353.1204224	0.54
356.1395874	3.23
359.9049072	2.71
362.6862183	0.96
365.0170288	0.11
365.8684692	2.88
367.1989136	23.03
374.2047119	9.68
376.0859375	1.08
378.1123047	3.73
381.1119995	3.92
384.2106934	3.17
389.0831909	0.75
396.4129639	2.10
397.9577637	0.91
402.1402588	1.66
408.3838501	0.60
411.1755371	0.63
414.4368896	2.04
416.4164429	0.75
421.2689209	0.49
423.1546021	1.64
426.3225708	1.40
432.2012939	0.21
436.1130371	1.50
441.7221680	1.53
444.0586548	1.67
445.1441040	7.01
454.1213379	1.56
456.2943726	1.10
462.1989746	8.84
465.1902466	1.94
473.4191284	0.61
480.3004150	12.76
481.1403198	0.83
495.3822632	0.36
496.2036133	0.30
498.3070679	11.82
500.2619019	0.50
513.1802368	0.10
525.1295166	4.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
200.8435974	0.01
229.0360413	0.36
237.0667267	0.03
246.9685669	0.01
255.0830994	0.01
257.0711060	0.23
273.1160278	0.07
274.3418274	0.05
284.9096680	0.17
289.2558594	0.02
296.9907227	0.03
303.0729370	100.00
303.6926880	0.38
309.0844727	0.10
345.1773071	0.63
367.2168579	0.03
369.1637573	0.05
375.0245972	0.02
380.8923950	0.01
399.3070068	0.16
413.2087402	0.07
429.1258545	0.07
431.2947998	0.12
437.3147583	0.04
445.1005249	0.06
447.1533813	0.99
448.9349365	2.29
456.3161011	0.04
463.1473389	0.13
464.3889160	2.15
465.0396729	24.82
465.7002563	0.17
489.4075928	0.10
491.0137329	0.13
507.3328247	0.07
524.0964355	0.02
525.2171021	0.13
527.2811890	0.15
539.0504150	0.10
557.0308838	0.23
566.2631226	0.07
567.4482422	0.17
574.2846069	0.07
575.1572876	0.24
593.1465454	0.42
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.197
Annotation	Terretonin E
Peak:m/z	Relative Intensity
143.3388519	0.03
148.0430145	0.10
149.1425171	0.10
153.0924377	0.21
157.3669739	0.05
159.3600464	0.07
160.8818359	0.28
163.0622101	0.17
169.0230713	0.03
171.1602173	0.02
173.1651459	0.31
177.3252258	0.08
179.0021820	0.06
182.8411407	0.17
185.2415466	0.07
186.0968018	0.05
187.2366333	0.06
188.9388733	0.11
193.2586975	0.06
195.2477417	0.08
197.0904846	0.18
199.0634155	0.02
201.2250671	0.19
202.1778870	0.08
204.9407349	0.11
211.1159515	0.04
213.1954346	0.19
215.3093109	0.32
219.1672821	0.09
223.7433777	0.03
225.2779236	0.09
227.1309814	0.15
229.2959900	0.21
231.2666931	1.21
235.1965027	0.14
237.1894531	0.11
239.1816406	0.34
240.0740662	0.04
241.0714417	0.12
243.2701721	0.10
247.2001343	0.02
249.0548706	0.53
253.2432556	0.17
255.3168030	0.02
257.3723755	0.04
259.1988831	2.50
262.9618835	0.08
265.1490173	0.96
267.4247742	0.20
271.3628235	0.07
273.1671143	0.21
275.4431152	0.26
276.2421265	0.11
277.2417908	0.32
279.3653870	0.03
281.1895752	1.02
281.8822632	0.11
283.3000183	7.28
285.3001099	0.09
287.2221069	0.11
289.4174805	0.23
291.2236938	0.10
293.2456360	3.72
295.0332031	0.69
297.1118469	0.06
299.2554626	0.74
301.3262939	0.04
307.2805176	0.29
308.6310730	0.22
309.3201599	1.24
311.2401428	2.24
317.2476196	1.67
319.3332520	0.41
321.1273804	1.02
322.1291504	0.03
323.2495117	0.12
325.2069702	0.14
327.1776123	2.50
329.2037659	0.72
333.2384644	0.16
335.2569275	0.24
337.2038574	41.17
339.0217590	0.08
341.2964783	0.26
351.3055420	2.80
353.1678467	0.52
355.0067749	5.76
355.7211304	0.02
357.5271912	0.26
363.7285156	0.03
367.1018677	0.34
369.2914429	6.13
371.2938538	0.06
377.2845154	0.13
379.4998474	0.09
381.4190674	0.08
383.2545471	0.03
385.3138123	0.75
389.2681580	0.09
395.2345276	2.89
397.4175720	0.13
399.2233582	0.68
407.4307861	0.02
409.1555481	0.05
411.2923279	0.20
413.2292175	17.93
415.1720276	0.04
425.2895813	0.12
441.3126221	0.04
443.0732422	0.70
457.2395325	100.00
457.8416138	0.27
469.3323669	3.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
148.8082275	0.12
158.9174194	0.16
166.7632141	0.77
169.1307678	0.49
171.1138763	0.95
172.934906	0.88
185.4379425	0.62
187.1387024	0.68
195.2362061	2.44
197.2974854	0.28
199.0751343	0.69
201.1749878	1.64
205.0594025	0.25
209.24646	0.13
213.1235657	1.48
215.1469727	4.07
220.0289612	1.29
227.1524963	0.78
229.1812439	3.36
236.8404236	0.17
240.1991882	0.62
241.2617188	0.33
243.1488647	1.66
252.3873596	0.18
255.3240356	1.18
257.1213074	2.66
263.4780273	0.38
269.237915	1.56
271.2767639	2.90
273.3240967	0.75
277.3598022	0.22
281.4934082	0.49
283.4098511	0.81
285.1286316	4.21
287.3319092	0.18
288.2197571	0.35
293.3721008	0.70
297.1860962	2.38
299.2327271	4.40
301.3897705	0.38
310.5981445	0.32
311.21521	2.70
312.3477173	0.33
313.3869019	2.74
315.3980713	1.80
323.3252869	9.07
325.3171387	1.61
327.1213379	0.57
329.0557251	0.23
337.7608643	0.78
339.2418823	100.00
340.1988525	0.81
341.2720642	13.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	824.7449
Annotation	Unknow
Peak:m/z	Relative Intensity
260.8936768	0.09
305.0003662	3.79
317.1441040	0.06
434.9375000	7.94
438.7171631	0.07
548.5870361	0.04
563.0764160	0.03
564.8849487	31.34
670.8359985	0.08
678.7589722	0.25
680.0469971	0.05
694.7544556	100.00
695.4174194	0.08
707.0682373	0.19
708.6744995	0.09
710.0122681	0.12
710.9385376	0.11
721.6567993	0.19
734.7371216	0.03
736.9652710	0.05
750.7080078	0.27
778.9252930	0.02
779.7305908	0.03
780.7586060	0.07
782.9077148	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.312
Annotation	FD 895
Peak:m/z	Relative Intensity
185.0204468	0.02
299.3125610	0.01
315.4918823	0.07
319.2544250	0.07
370.5367432	0.09
377.0217896	0.03
437.1876221	0.01
439.0308838	0.04
457.3922119	0.04
499.0806274	0.01
522.0708008	0.02
535.3569946	11.55
547.4407349	0.38
559.7209473	0.04
565.2903442	100.00
566.1685791	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	325.0928
Annotation	6-O-p-Coumaroyl-D-glucose
Peak:m/z	Relative Intensity
98.9625092	0.21
113.0519485	0.21
117.0069504	1.12
119.0517120	9.91
121.0785980	0.12
124.7185822	0.08
143.0021667	0.18
145.0116272	100.00
158.2248077	0.45
159.1204529	0.52
161.1016541	1.15
163.0496216	93.54
173.1955261	0.79
176.9666595	1.21
187.0223694	55.36
190.9259491	0.13
203.1878052	0.33
204.9678040	7.11
207.0921326	0.09
215.2311401	0.17
216.9798279	2.22
229.2046509	1.27
235.0487061	9.64
244.9203186	0.33
265.1542053	25.33
278.9403992	0.53
281.2643433	0.08
289.1775818	0.19
295.1400146	0.16
307.0926208	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.23
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9609375	0.12
221.1635590	0.35
232.8857117	0.28
268.0850220	0.12
269.1293030	0.02
281.0226440	0.07
282.0595093	0.03
306.1309814	0.17
323.1547241	0.14
340.9857788	0.75
383.3108521	0.24
412.8938599	0.09
424.7561035	0.14
442.9344482	0.80
443.5938721	0.01
473.0467529	0.03
485.3735962	0.04
495.0029297	0.04
503.2937012	100.00
510.2723999	0.02
528.2599487	0.06
546.0780029	0.09
567.2499390	0.09
589.4644165	0.06
602.9101562	0.02
615.9028320	0.05
631.1099243	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.11
Annotation	DIMBOA-Glc
Peak:m/z	Relative Intensity
117.8807220	0.08
119.0439072	1.03
122.9886551	0.31
131.9707184	0.26
133.0342102	0.16
135.9838867	4.29
146.9670715	1.72
147.9825439	0.35
155.9410400	0.13
164.9941711	10.94
169.7633972	0.07
170.9257812	0.04
174.8100281	0.08
181.9752197	100.00
183.1659241	0.09
193.4239197	0.03
194.8991852	0.09
209.7182617	0.09
212.0270996	0.21
219.2443848	0.11
227.2127075	0.12
230.2017822	0.34
234.1210938	0.10
241.7940369	0.39
243.0379333	0.38
248.9235229	0.12
272.0180359	0.29
272.9474487	1.52
278.1012573	0.99
284.0103455	0.21
284.7481079	0.32
285.9716797	0.03
287.0586243	0.31
288.1120605	0.17
290.2075806	0.13
292.8411865	0.20
296.3199158	0.09
297.0428162	0.75
299.6778259	0.20
307.9123840	0.17
311.7099915	0.17
314.9933777	0.44
318.0466309	0.05
319.9079590	0.09
324.7974854	0.09
328.1205444	0.23
329.0765991	0.08
329.9485474	0.34
333.0979004	2.96
333.9873047	0.43
342.1495056	0.21
345.4179688	0.36
346.0614319	0.09
350.8032227	0.57
353.3589172	0.06
356.3543396	0.62
358.4423523	0.06
359.2811584	0.20
360.3001404	0.15
365.6086731	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	547.2529
Annotation	[4beta(2Z,4E)]-4-[6-[2-(2,5-Dihydro-5-oxo-3-furanyl)ethoxy]-7-hydroxy-2,4-octadienoate]12,13-epoxytrichothec-9-ene-4,15,16-triol
Peak:m/z	Relative Intensity
155.0741882	0.11
157.3102112	0.13
158.1084595	0.17
159.1309052	0.48
160.9763336	1.86
162.9954376	0.41
164.8793640	0.18
165.7142944	0.20
167.0576019	0.21
169.1010437	0.31
171.1427917	0.46
173.0527496	0.29
174.9422913	1.00
177.0930176	0.37
179.2700195	0.10
183.2506104	0.35
184.8891907	0.37
185.4970703	0.06
187.1977234	0.94
189.1816711	0.30
191.1379089	0.37
192.9916382	0.36
195.0888062	0.16
197.2415161	0.39
198.2085724	0.08
199.2091827	0.38
200.8167725	0.06
203.1217651	0.92
205.1612244	0.18
207.0208893	0.64
208.8641052	0.34
209.4648743	0.11
211.0177612	0.55
213.1362915	1.16
215.0204163	0.45
217.0300598	0.54
219.2412415	0.42
221.2524567	0.29
224.0419006	0.21
224.8838806	0.15
227.0823975	1.04
229.1391449	0.33
231.1704102	0.73
233.1830902	0.32
234.8645782	0.25
236.8033905	0.15
237.4806213	0.05
239.0800476	0.45
241.2928467	1.05
243.1641846	0.82
245.0783234	1.11
247.1275787	0.09
248.8116760	0.19
250.0965271	0.12
251.1360474	0.97
252.9965210	0.50
254.2341309	0.09
254.9872894	0.29
257.1851501	0.29
259.2365112	1.05
261.0191345	0.59
263.2327576	1.59
265.0144348	0.77
267.0395203	0.63
268.7435608	0.47
269.3516846	0.31
271.1727905	0.36
273.1799316	0.55
275.1143188	1.02
277.2141724	0.47
278.5254517	0.40
279.1369019	0.27
281.2953491	0.48
283.2742310	0.21
285.1499023	0.67
287.2009888	0.48
289.0016479	1.44
291.2467651	0.67
293.3988953	0.17
294.8178711	0.52
295.7584229	0.08
297.2812500	0.77
299.3089905	1.39
301.5250854	0.08
303.1808472	1.24
305.2471313	0.66
307.1501465	1.19
309.3085327	0.99
311.1253052	1.93
313.1908569	0.90
315.3017578	0.50
317.1160889	1.12
319.1335449	0.67
320.3566284	0.06
321.3273315	0.53
323.3084106	1.73
325.2783813	0.56
327.0549927	1.16
329.2832642	0.90
331.3054199	1.12
333.1508789	0.75
334.2036743	0.51
335.2904663	1.22
337.2458496	0.71
339.1724854	2.03
341.2285767	8.03
343.2423096	0.13
345.3545532	1.12
346.7816772	0.26
347.4136353	1.17
349.3106079	2.10
351.1578369	2.28
353.2410889	0.77
355.0800781	0.94
357.1726074	0.96
357.8074341	0.26
359.3012085	0.25
361.1428223	0.51
363.0493774	0.76
363.6832275	0.24
365.0340576	0.97
365.6529541	0.20
367.2604370	4.40
369.2044067	34.87
369.9104614	0.11
371.1260986	0.35
371.9968872	0.52
373.2266846	4.94
374.1024170	0.10
375.2587280	2.02
376.4722290	0.65
377.2752686	2.00
379.2683716	1.14
381.2656860	1.68
383.2140503	2.66
383.9266968	0.03
385.1856689	1.04
387.0120239	0.23
389.2194214	0.75
391.3143311	2.90
393.2333984	4.52
394.3008423	2.39
395.2434082	4.10
397.3370361	0.74
399.2963257	0.12
401.1551514	1.56
403.1629028	0.72
403.9359741	0.22
405.2808838	2.57
407.2439575	4.72
409.0862427	5.01
411.2371216	6.27
413.1307983	3.89
414.7705078	0.27
415.3972168	0.12
417.1205444	0.39
418.0733643	0.07
419.3148193	3.15
421.1946411	0.29
423.2476196	8.08
425.2535400	17.60
425.9154053	0.15
427.2026367	2.91
429.2425537	0.61
433.2318726	4.73
435.3133545	0.32
437.1791382	3.87
439.1249390	0.60
440.6905518	1.15
441.2924194	9.07
443.2810059	17.58
444.2032471	0.12
445.0319824	0.38
446.4413452	0.14
448.7283325	0.14
451.1956787	9.20
453.4606934	0.38
455.2642212	1.42
457.2607422	0.09
458.7228394	0.05
459.3239746	0.55
461.2086182	0.38
467.1994629	0.28
469.1572876	55.19
469.9142456	0.29
473.1051636	1.00
477.1683350	0.08
479.3858643	0.30
483.0956421	8.71
484.1405640	0.05
485.1210327	1.63
487.1886597	13.42
489.2481079	0.18
493.6194458	0.32
495.6151123	0.06
496.8505249	0.13
497.5032959	0.18
501.0615845	28.45
502.2528687	1.80
505.1831665	0.86
509.3795776	0.27
511.1185913	1.82
515.1289673	1.15
517.5758057	0.15
529.2256470	100.00
546.9796753	0.15
552.7340698	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0719
Annotation	Alnustinol
Peak:m/z	Relative Intensity
106.9566803	0.05
125.0011673	12.60
134.0170288	0.25
135.0343781	0.13
135.9594727	0.29
149.0958557	0.37
150.8982544	2.60
157.9070129	1.32
159.9309235	0.23
161.1464539	0.26
163.0429840	0.03
164.0277863	2.86
164.9195557	0.18
169.0287170	0.09
173.1119385	1.31
174.0523224	2.45
175.1074066	0.88
176.0015259	0.04
176.8484802	0.10
179.2102509	0.39
183.1765442	0.10
185.0547638	0.91
188.0344543	0.06
191.0211792	0.73
196.1781311	0.04
198.3016052	1.61
199.0749512	9.96
200.0309143	1.90
201.0344849	2.02
202.1105957	1.05
208.9839172	0.38
210.8008728	0.05
212.9620361	1.09
214.0345459	0.74
215.1775208	7.18
216.4014587	0.59
217.1138916	4.28
224.1012878	2.19
225.1675415	0.26
227.0588989	5.38
230.0399170	0.38
231.1796570	0.19
233.1179199	6.13
239.0339355	7.59
240.0559082	2.96
241.4557190	6.17
242.0649719	44.51
243.0172729	0.85
244.0206909	0.27
246.9949036	0.05
255.0032959	0.68
257.0901184	31.89
258.1064758	10.93
259.1558838	1.49
265.1671448	0.06
268.0919189	4.13
283.0637817	34.40
284.0497437	0.50
286.1266479	100.00
287.0950317	1.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	403.1611
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
123.1000671	0.05
135.1047516	0.02
153.1180115	0.02
161.0606232	0.08
164.0899353	0.11
167.0765686	0.04
175.0932617	0.13
179.4048767	0.04
181.0876465	0.91
193.0275726	0.21
197.1452789	14.19
202.9860687	0.09
208.9367371	0.15
210.1742096	0.07
221.0034332	0.12
223.0039368	0.39
236.9424744	0.07
239.1787109	0.15
241.0761108	100.00
247.1742249	0.22
253.0472717	0.06
265.2912903	0.31
283.1139832	1.40
305.2805176	0.12
312.8915405	0.35
313.5370178	0.10
330.2398987	0.08
343.1856384	2.17
357.1884155	0.40
359.1205444	0.54
385.1245728	1.37
402.9859314	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
81.0650177	0.87
84.94335938	0.40
91.04100037	0.89
95.08843994	1.60
97.03672791	2.73
98.82649231	0.18
102.897934	0.55
103.641983	0.22
107.0517273	0.32
108.9412842	1.85
111.0500946	1.61
113.203598	0.48
116.5850677	0.10
118.891861	0.50
121.0206604	1.33
123.0721893	0.98
125.0730896	0.62
126.9075317	4.13
128.9692383	6.09
130.0554657	0.14
133.0035706	1.10
133.8906097	0.34
135.1616821	2.11
137.0943756	1.31
139.0404358	0.94
140.9897766	1.55
146.7067719	0.15
149.0591888	0.60
150.9028778	52.90
152.0540314	2.48
152.9776611	1.19
153.95961	0.50
155.0543671	0.89
157.0232544	0.66
161.2182159	1.09
163.1120453	0.34
164.9192505	2.08
167.1208496	1.97
169.0149078	2.36
171.1690979	1.14
174.9801788	1.33
177.2190399	1.18
179.1106873	2.78
183.0948029	0.46
184.8592072	0.66
185.7615967	0.53
189.6310577	1.00
191.0946503	0.98
193.0139465	0.76
194.1177216	1.00
194.9432983	0.30
197.1580353	2.56
199.0061493	0.32
200.2061768	0.13
207.082077	4.09
208.4909668	0.34
210.8843689	4.44
217.150589	4.46
223.2913666	0.48
225.0920868	9.45
226.0457916	0.27
232.4128876	0.89
235.0780182	26.50
238.0713348	6.94
238.9989166	0.85
243.5772095	0.72
244.4131012	3.74
251.1875763	0.16
253.0877075	100.00
254.1682281	15.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	215.9972
Annotation	Unknow
Peak:m/z	Relative Intensity
92.1243744	0.12
96.8401642	0.02
135.9591522	100.00
172.0260773	8.12
188.9922028	0.05
198.1727295	0.23
215.8852386	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	378.0498
Annotation	Unknow
Peak:m/z	Relative Intensity
115.8682404	0.08
127.8523331	0.03
132.0425415	0.02
133.8503265	0.22
136.0149231	9.72
137.2429810	0.08
138.7411652	0.07
145.9773254	0.07
169.0589600	0.03
171.9262390	0.86
178.0752563	2.00
179.0459442	0.06
198.0061493	12.51
199.0636902	0.16
204.2436218	0.09
207.9951477	0.30
212.1027832	0.06
213.9414368	0.08
216.0313721	100.00
223.0632324	0.08
240.0089111	0.68
241.1021118	0.87
243.7468262	0.03
245.3628845	0.04
249.3336792	0.10
254.1185608	0.35
258.0627441	6.37
259.0096436	0.10
270.2087708	0.06
271.8969116	0.07
274.0111389	0.05
280.0487061	0.04
288.0698853	0.96
298.1633301	0.56
301.2417603	0.04
318.1044922	6.05
319.0147705	0.21
330.2970581	0.05
332.1665344	0.13
334.1865845	1.73
338.1411133	0.05
342.1235352	0.17
344.2701416	0.06
360.2629089	0.57
361.2648315	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.3354
Annotation	FD 895
Peak:m/z	Relative Intensity
169.1222839	0.02
170.0681915	0.03
194.1800079	0.08
198.2349091	0.04
222.0992279	0.05
237.3075562	0.04
239.1644745	0.36
280.3640137	0.03
283.2672729	0.23
307.0527039	0.01
322.3750000	0.05
325.2158203	0.03
340.2614136	1.15
342.4917603	0.01
352.3782349	0.30
353.2669067	0.01
355.1998901	0.04
365.6083984	0.09
368.3942261	0.07
370.2962646	0.52
391.4163208	0.03
394.2698975	0.03
399.3878174	0.86
426.8941040	0.04
434.3053589	0.09
439.3911133	0.04
440.2193604	0.05
450.5447388	0.05
467.6130981	0.02
469.3005981	0.09
470.4086304	0.15
476.8116455	0.04
478.4642944	0.08
490.3744507	0.05
491.3271484	0.02
494.5259399	0.06
495.2849731	0.17
496.3881836	0.31
504.6376343	0.07
517.4295654	0.04
522.4727173	0.28
523.3363647	0.02
524.7643433	0.10
529.2407227	0.03
535.3497925	100.00
536.0214844	0.19
538.5263672	0.01
547.3861694	4.54
548.4094849	1.41
549.4680176	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.1192
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
108.0512619	0.38
109.0698166	0.28
119.1151581	0.08
120.8823395	0.12
122.8775864	0.04
128.9483643	0.05
135.1223450	0.09
136.0094910	0.55
146.0838470	0.03
147.0746765	0.09
151.0479126	4.91
152.0234375	1.34
153.0560913	3.38
154.0603943	0.10
160.8919067	0.10
161.9733582	0.08
163.0648499	0.17
165.0044556	0.38
166.8901978	0.21
168.9695740	0.01
171.0877686	0.07
174.8144226	0.03
177.0947723	1.89
179.2352142	0.05
181.1335297	0.13
190.9710846	0.19
191.9328613	0.10
192.8968353	0.09
195.0093079	100.00
204.9907684	0.01
207.1000519	0.16
219.1167908	0.13
225.1347961	0.30
226.2039185	0.01
234.7933655	0.17
240.8728943	0.03
242.7223816	0.03
246.9363708	0.03
252.9190674	0.10
254.9765625	0.04
269.0997314	0.18
269.8942261	0.14
270.8409119	0.02
285.3001099	0.05
295.5038452	0.15
297.0034180	0.23
303.5641785	0.02
313.3571472	0.04
315.1989746	1.08
316.0206909	0.02
337.3215942	0.08
339.0358582	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.0935
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
148.7934265	0.02
151.0419922	0.08
179.1311340	0.03
202.9268646	0.03
221.1650085	0.06
229.0760651	0.20
241.1434937	0.03
265.3313599	0.03
282.1614075	0.03
285.1917725	0.77
297.0195923	0.29
298.0815125	0.18
299.2645264	0.05
300.4691772	0.03
325.2090149	0.40
327.1015320	100.00
328.2248535	0.13
335.0988770	0.05
339.1591187	2.27
341.1503906	0.02
353.1395264	0.39
357.1266479	74.51
358.1474609	0.18
365.3255005	0.06
367.0615234	0.19
369.0616760	1.56
371.2278137	1.63
372.3118591	0.04
379.1446228	0.03
383.0639343	0.08
387.2026062	3.83
393.2820740	0.92
399.1625061	1.07
401.1750183	0.15
403.0247498	0.07
411.2326660	3.38
417.2632141	0.13
429.1434021	21.12
429.7685242	0.14
430.6256104	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	435.1281
Annotation	Robustaside B
Peak:m/z	Relative Intensity
125.9825745	0.06
126.9528656	0.20
137.2351379	0.07
147.0129089	2.26
150.8417358	0.23
152.9141388	0.28
165.0650024	0.56
167.9069672	0.36
168.7985535	0.18
169.8601685	0.17
175.2648621	0.59
191.1325684	0.34
193.1132202	0.39
194.7937164	0.09
201.8878326	0.05
204.8618469	0.25
207.0137634	0.13
216.9962006	1.04
219.0681458	0.19
222.9748230	0.04
230.8117523	0.06
233.4494019	0.04
235.0843811	1.44
238.8924866	0.16
242.4366760	0.24
249.0533142	1.43
250.9732666	0.10
253.1073914	1.70
255.4582214	0.08
258.2595520	0.08
263.0789795	0.45
265.1391602	0.09
266.9570007	0.40
273.0603027	100.00
280.8340454	0.21
284.0780029	0.21
285.2609863	0.45
289.2758179	0.03
291.4404907	0.13
296.1441650	0.17
297.1289062	1.00
309.0108643	1.24
313.2612915	0.28
314.2206726	0.84
315.0727234	2.50
315.7607117	0.06
321.9852295	0.07
322.8590088	0.25
328.1620483	0.04
334.1798096	0.05
335.1421509	0.07
337.1022644	0.48
338.1544189	0.13
339.0958252	3.45
346.9159851	0.47
348.8031311	0.03
351.1293335	0.07
357.0124512	0.02
367.2632446	0.70
368.0251465	0.79
369.1877136	4.42
373.3139648	0.06
377.0959778	0.10
379.4692078	0.12
381.1337891	3.78
391.3152161	0.74
397.3136902	0.54
399.0934143	5.16
405.1348572	0.19
408.1173401	0.24
415.0951233	0.23
417.1183777	24.93
418.0837708	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.2217
Annotation	3'-Hydroxy-T2 Toxin
Peak:m/z	Relative Intensity
137.1705780	0.04
140.9153748	0.04
142.1040955	0.16
143.2007141	0.44
144.9314880	0.23
147.2065582	0.92
149.0427704	0.07
151.1366272	0.06
155.8937988	0.46
157.0435486	1.35
159.0547028	1.92
161.1555786	0.75
162.0264587	0.08
163.1361694	0.27
165.1488800	0.04
169.1633606	0.13
171.1296234	0.74
173.1127777	0.75
174.1577759	0.24
175.0404510	3.53
176.9910889	2.29
177.5982513	0.09
180.8306274	0.14
187.0145264	1.21
189.0323029	1.00
193.1247864	0.32
199.1775208	3.43
205.0841370	0.65
212.8545837	0.34
217.1501923	6.46
219.4537811	0.25
223.0002441	0.03
230.9653625	1.39
235.1528320	100.00
241.2713928	0.12
243.0370636	0.12
248.9608765	0.15
250.9139404	0.02
252.6666260	0.15
259.2754211	0.23
261.1686401	0.13
263.2197876	0.35
269.4429932	0.28
271.1753540	0.84
275.1239929	0.35
288.1469116	0.19
292.6503906	0.31
293.4172974	0.12
295.2764893	0.10
299.3457336	0.05
301.2113953	0.13
303.0768433	0.07
304.0565186	0.08
311.0973511	0.07
317.2123413	0.05
319.1458435	0.67
320.1688843	0.12
322.1040649	0.06
323.1770020	0.12
325.0690308	1.47
326.1673584	0.05
327.0325317	0.03
333.1721191	0.09
337.1402588	1.70
341.1343994	0.16
343.3238525	0.41
345.1964111	0.20
347.4193420	0.09
349.1207581	0.08
351.3061523	0.04
359.6359863	0.04
361.1903381	0.20
371.4215393	0.02
374.2100830	0.04
377.5119629	0.11
379.2367554	0.45
385.0349121	0.17
389.6427612	0.24
393.2469482	0.40
395.4630432	0.06
397.2875061	0.75
403.3523865	0.28
405.2984009	0.11
407.3238220	0.16
411.3540955	0.06
419.4423828	0.20
421.2019958	1.57
425.3039551	0.18
429.0993652	0.47
437.3107910	0.17
439.4273376	1.52
441.5655518	0.10
447.2675781	10.58
452.3652039	0.09
453.7198792	0.05
455.1358948	0.23
461.8186646	0.22
465.2370911	7.69
466.4969788	0.20
483.2597351	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	290.85
Annotation	gamma-Pentachlorocyclohexene
Peak:m/z	Relative Intensity
122.8876190	2.72
164.8915405	0.05
174.9971008	0.04
206.7940674	100.00
231.0476685	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.3067
Annotation	PC(15:1(9Z)/0:0)
Peak:m/z	Relative Intensity
144.0852203	0.21
180.1082458	0.07
184.9511261	0.10
207.3527527	0.05
216.0920258	0.43
238.6199341	0.08
262.3860779	0.19
265.2329102	0.10
266.3991394	0.14
267.3657227	0.15
285.1064148	0.07
296.9949951	0.35
298.0539551	0.19
303.1785889	0.16
304.1722412	0.27
308.4086304	0.41
319.1571045	0.08
332.1569824	0.71
339.2698975	100.00
339.9280090	0.18
345.0864868	0.13
346.0986023	0.07
348.9872742	0.04
379.3092041	0.04
392.1051331	0.31
399.1517639	0.06
411.2204285	0.12
418.9507446	0.05
425.5136414	0.19
427.3456116	0.15
431.3613586	0.04
434.6248169	0.27
439.4595947	0.08
448.9083252	0.09
451.0556030	0.05
452.5823364	0.42
462.2290955	3.94
466.2245483	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1507
Annotation	Datiscin
Peak:m/z	Relative Intensity
175.0773315	0.46
185.1684723	0.32
187.1595154	0.02
197.1123962	0.08
198.0627441	0.08
198.9830933	0.14
201.0653229	0.29
212.1129456	0.05
213.1270447	0.05
214.1646729	0.03
217.1114197	0.54
222.7993774	0.03
225.5682373	0.05
226.7000427	0.09
239.0303955	0.03
241.1293488	0.68
242.1522064	0.05
243.1579895	0.43
244.1241455	0.03
257.1519165	0.08
266.8825684	0.22
283.0873413	0.02
285.0516052	100.00
286.1694336	3.15
287.05896	0.04
298.1976624	0.03
299.1445312	0.38
306.9505615	0.10
308.095459	0.11
310.9916992	0.16
323.1791992	2.00
327.2467651	0.63
327.9747925	0.19
331.0158691	0.01
337.2496338	0.15
339.0713501	0.10
341.1503906	3.25
353.0368042	0.37
355.2053223	0.10
356.1225586	0.05
357.2875366	0.16
365.1472168	0.20
366.3361206	0.05
371.2134399	0.68
383.1971436	0.24
407.0370483	0.05
413.3687134	0.06
425.2976685	0.08
428.1297607	0.53
429.194519	0.06
431.0169067	0.03
443.1586914	26.24
443.7744751	0.37
444.3984985	0.12
447.2199097	0.87
461.0581055	0.17
463.0756836	0.40
463.706665	0.01
471.3313599	0.03
473.0111084	0.75
503.409729	0.08
504.8042603	0.02
549.6524048	0.02
575.4678345	0.04
578.371521	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	604.215
Annotation	Fesumtuorin D
Peak:m/z	Relative Intensity
170.8424683	0.12
172.8699036	0.06
174.9185944	0.52
175.8204498	0.04
184.0821228	0.02
185.1707153	0.13
189.0444946	0.05
191.1268616	0.03
195.0632477	0.17
197.2074585	0.08
199.0683441	1.46
201.0555267	0.75
203.0063629	55.36
204.0226898	0.28
213.2522125	0.09
215.1967773	0.10
217.9640808	0.72
218.9832764	0.31
222.9448242	0.04
227.0933380	1.37
231.1717529	1.28
232.1087952	0.76
233.1016998	3.74
234.0221100	1.41
241.0777893	1.63
242.8740997	0.13
243.5151062	0.06
248.9729462	0.02
250.9012299	0.16
255.1100616	0.05
257.2096558	0.02
258.3241577	0.03
269.0741577	20.00
270.2708435	0.25
273.2147827	0.04
279.3746338	0.02
287.0249634	100.00
288.0600281	0.24
294.8945312	0.13
299.0843506	0.31
300.1149292	0.19
316.9578552	1.34
318.2088013	0.95
326.1308594	0.05
342.7155762	0.03
352.8957520	0.35
370.6088867	0.38
371.2339478	0.22
383.2421875	0.04
400.4092407	0.12
415.9746704	0.05
441.1403198	0.05
475.4164429	0.03
487.4223633	0.04
496.3379517	0.02
506.7242432	0.03
526.7803955	0.02
532.2301636	0.06
544.6121216	0.11
545.3416138	0.09
554.4237061	0.71
555.2019043	0.15
559.3824463	0.07
570.8789673	0.16
572.0507812	4.02
572.8407593	34.10
573.8426514	0.03
585.0723877	0.11
586.2918701	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	333.19
Annotation	Sachalinoside B
Peak:m/z	Relative Intensity
94.8154755	0.14
96.8903351	0.21
104.9940720	0.84
106.9457779	16.26
109.0614395	0.36
120.8393021	0.12
122.8862610	0.07
124.9589005	0.17
126.9132843	0.11
132.8843384	0.07
133.8653259	0.10
134.9863586	43.78
135.9662781	0.11
137.0781097	0.44
139.0709534	0.23
142.0769806	0.15
144.6599884	0.57
145.2972565	0.22
146.9147034	0.37
148.3923187	0.11
151.1828766	0.26
153.0764008	68.49
161.2220459	0.39
162.4860077	0.19
163.1550903	0.85
165.0764465	1.49
167.1742859	0.59
167.9558716	0.06
169.1799622	0.18
170.9124298	100.00
173.0408173	0.21
177.0510864	5.68
178.9916687	0.18
180.8657684	1.09
183.0035095	4.11
188.1350403	0.22
189.1207275	0.38
191.1142578	0.10
192.8937531	0.31
194.1069183	0.06
195.8831482	0.26
197.2390137	0.24
199.2107544	0.09
201.0993042	0.28
203.1887817	0.31
207.0720520	0.85
209.0167847	0.86
212.0378723	0.14
213.0525513	0.59
216.9278564	0.39
219.1031799	1.33
220.9191284	0.10
225.3347473	0.83
227.1729736	0.04
229.2837524	0.17
231.2511292	1.36
232.8340759	0.24
237.0276794	0.65
239.0099487	0.36
241.2561035	0.13
243.3224182	0.90
247.4267578	0.09
249.1146545	0.67
252.9507446	0.09
255.0749512	0.09
261.0707703	1.89
262.1171570	0.38
263.0968628	0.14
264.5162048	0.35
268.9873047	0.21
270.4238281	0.22
271.4508362	0.39
274.1049194	0.26
275.0593567	0.68
277.2765808	0.27
279.1705322	5.46
285.1463623	0.89
286.3244629	0.48
287.1486511	0.97
288.0891418	0.27
289.1080627	0.49
290.2183533	0.93
291.1367188	0.76
292.0765991	0.27
295.9631042	0.53
297.2124023	19.29
297.9631348	0.16
300.3594360	0.15
300.9678040	3.22
302.0502930	3.11
303.1799927	2.19
304.2195435	1.34
305.2553101	1.32
313.2050781	0.30
315.0844116	26.03
316.2280273	0.71
317.0440063	0.18
318.1176147	3.07
319.1828613	0.43
333.4519043	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	478.291
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.1436462	0.02
147.1565399	0.12
155.0502014	0.49
157.0366821	0.19
164.7286377	0.06
172.8232117	0.12
175.2837219	0.15
177.0990295	0.03
187.0026550	0.06
191.2310028	0.04
197.2495117	0.04
197.9798584	0.35
203.1920166	0.17
207.1660919	0.04
215.9983978	0.47
237.2911682	0.02
245.2575684	1.92
249.3802185	0.09
252.9382935	0.05
259.9123230	0.11
263.1983948	4.65
265.1452332	0.09
277.3450317	0.27
293.2376099	0.18
306.4049377	1.16
307.4140320	0.17
315.2504272	0.14
318.8108521	0.10
319.4407959	0.92
324.4069214	0.09
334.5637207	0.04
335.2867737	0.34
337.3801575	76.71
342.6407166	0.04
347.3954163	0.08
380.2333069	0.05
417.0419617	4.09
417.7560730	0.01
420.3547058	0.10
435.4837341	0.09
442.5500793	0.05
444.3461609	0.16
446.9832764	0.02
460.2224426	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	308.02
Annotation	Unknow
Peak:m/z	Relative Intensity
101.1191101	0.02
107.0621185	0.02
115.9171906	0.44
121.9749146	0.02
129.0010681	1.73
129.8974457	0.16
138.9974670	0.22
143.9930420	0.37
146.9277039	2.03
148.0663300	0.06
150.7679138	0.02
154.0697632	0.04
156.9122620	0.74
158.1770325	0.07
161.9360962	6.02
174.8381653	16.10
175.9534912	0.42
179.0607452	23.13
180.1031952	0.09
182.1458893	0.03
189.0677948	0.33
192.9443970	8.48
193.9144897	0.15
202.9164734	0.29
206.1200256	0.09
207.9984131	0.10
212.0063477	100.00
214.9609985	0.20
216.1228027	0.04
220.6244202	0.31
229.9708862	0.05
233.0609436	4.63
245.1649170	0.06
246.9202881	0.07
252.0212708	0.02
261.9135742	0.03
262.8176880	0.14
266.9533081	0.11
272.2856140	0.30
279.9892883	0.08
285.0415649	0.05
290.1581726	2.37
290.9854736	0.46
299.0665283	0.18
319.1383667	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.192
Annotation	Unknow
Peak:m/z	Relative Intensity
125.0819855	0.22
131.2416382	0.02
138.1291199	0.04
142.9383087	0.17
153.0948486	3.41
158.9320679	0.11
161.0112457	3.78
172.3641815	0.04
178.9768829	1.25
187.3345490	0.02
205.1369629	3.60
209.3497467	0.07
223.0321198	9.21
225.1690216	0.25
232.8645782	0.23
234.9194336	0.04
247.0238953	0.05
265.4132080	0.03
269.3744812	0.24
311.2595215	0.33
316.1416931	0.03
331.3843994	0.06
341.2909546	0.06
374.3177795	0.03
375.5749207	0.02
383.1383362	0.16
385.1972961	100.00
432.0442505	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	634.837
Annotation	Unknow
Peak:m/z	Relative Intensity
214.9796143	0.01
273.0131531	0.04
274.9934082	0.04
277.0894165	0.03
286.3173828	0.02
288.7545776	0.08
291.2319336	0.02
304.9265747	0.20
390.9889526	0.05
403.0322876	0.01
405.1137085	0.06
407.1552734	0.05
434.8254395	0.06
458.8386841	0.31
460.9739380	0.01
474.8868408	0.14
505.0099487	0.50
516.9630737	0.01
518.1174927	0.10
518.8839111	1.48
520.0618896	0.44
520.8629150	2.38
523.0158081	0.04
548.7477417	0.01
560.7598267	0.06
561.6142578	0.01
588.8335571	100.00
589.6934204	0.05
591.0520020	0.52
606.9371948	0.17
608.5200806	0.10
611.6371460	0.05
616.8661499	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	857.2345
Annotation	Genistein 7,4'-bis(O-glucosylapioside)
Peak:m/z	Relative Intensity
302.9340210	0.15
330.2365112	0.13
399.2686768	0.13
465.3239746	0.34
485.2490845	0.34
507.3837280	0.14
518.9774170	0.09
550.0049438	0.17
551.3179321	1.08
575.2857056	0.21
606.4148560	0.09
622.2422485	0.18
627.2772827	0.09
651.4639893	0.16
669.2301636	27.92
687.3743896	0.80
695.4863892	0.14
711.2448730	2.81
713.2273560	0.79
750.8742065	0.30
751.6173096	0.13
771.1244507	0.31
797.2435913	0.75
813.0481567	100.00
813.6876831	0.70
837.4375610	0.51
839.1473389	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.0932
Annotation	Acacetin 7-glucuronide
Peak:m/z	Relative Intensity
128.9516602	0.99
136.9565277	0.35
142.9994507	2.77
145.0343323	0.23
149.1933594	0.30
155.0229797	0.27
159.3271790	0.26
160.9008789	3.88
163.0002136	11.16
172.9970245	26.23
187.1087646	2.14
189.1038513	2.89
190.9724426	5.08
193.0222473	0.19
205.1700745	1.24
213.1719666	0.43
214.9499207	0.16
231.0573120	2.26
251.1498413	10.35
276.9872437	1.66
293.1950378	10.18
295.0922241	70.35
313.0637817	37.29
314.0784302	0.36
319.2709961	0.51
337.1078796	100.00
399.0853577	1.87
413.0837097	0.17
415.5697327	0.33
417.3741150	0.19
440.8768005	2.22
441.5181580	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	843.22
Annotation	Unknow
Peak:m/z	Relative Intensity
243.0655823	0.08
244.9917450	0.14
246.3566132	0.08
261.0279541	0.10
274.1226501	0.09
299.0966492	0.03
302.0800476	1.41
305.0855713	4.14
316.2918701	0.15
317.0307007	2.45
331.1907349	0.03
332.3588257	0.35
342.1648865	0.04
344.9770508	1.42
347.2154541	0.26
357.0754395	0.11
358.9880371	0.20
360.2030640	5.42
371.3636475	0.06
373.1372681	0.08
374.1166382	0.68
375.0975647	23.45
376.5523682	0.10
377.5460815	0.09
383.2661743	0.28
389.1589966	0.05
406.7811279	0.09
467.0903320	0.19
474.1611328	0.02
476.8231812	0.16
491.3608398	0.12
501.2617188	0.09
503.5907593	0.15
507.4672241	0.14
519.3663940	0.28
522.1813354	0.03
537.1651001	100.00
537.8367920	0.19
549.3551636	0.09
564.2695923	0.25
565.2196045	0.25
573.2305298	0.06
579.2615967	24.69
583.4089966	0.05
595.1604004	0.09
619.2020874	7.24
619.8452759	0.06
621.2604980	7.34
636.2701416	0.10
651.1897583	1.33
653.2914429	0.06
663.1747437	2.52
668.4285278	0.05
677.2769165	0.20
681.1725464	94.48
687.7119751	0.09
698.0834351	0.20
699.3019409	0.09
704.7166748	0.04
709.3742676	0.10
717.2515259	0.42
723.2204590	22.41
735.1890869	1.72
741.2748413	0.25
746.5316162	0.07
750.3599854	0.16
753.1712036	23.43
754.5192261	0.04
764.3068237	0.29
765.1567993	0.24
777.0164795	0.17
778.8378296	0.11
783.1753540	70.95
784.3356323	0.05
789.2156372	0.09
792.4201660	0.11
798.2645874	0.06
799.2085571	0.35
810.4677734	0.18
813.2861938	0.82
824.0509644	0.08
824.6539307	0.26
825.3729858	1.81
831.4743042	0.04
850.0297852	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	512.2325
Annotation	Unknow
Peak:m/z	Relative Intensity
249.0642395	0.49
265.1151428	2.53
272.1336060	1.37
272.8360596	0.33
291.1473389	0.74
302.2783203	0.68
315.1005859	0.96
332.7196045	17.15
333.4083862	1.61
375.0256958	8.51
393.1011353	32.56
400.9581909	0.97
410.0529785	0.55
414.3067017	0.73
432.2304688	1.94
434.2294312	1.15
453.0654907	0.41
459.0188599	0.37
465.9256592	0.52
471.0650024	1.04
475.6105957	1.19
476.6359253	10.82
477.3364258	6.48
494.3328247	23.66
494.9460449	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	797.2111
Annotation	Faratroside
Peak:m/z	Relative Intensity
244.1336365	0.42
245.2166138	0.07
253.1489868	0.58
254.8390045	0.17
261.0936279	0.14
270.9928284	1.17
273.0492249	0.41
275.2823181	0.18
288.8046265	0.36
300.1226196	0.15
301.2239685	2.25
302.0853271	0.14
306.7732544	0.40
315.0203247	1.34
317.3027649	0.85
329.9882507	0.23
330.8365479	0.21
332.1325378	15.31
343.4963989	0.72
345.0877075	9.06
347.1683350	100.00
355.0478516	0.47
377.0440674	0.18
379.1998291	0.34
385.3599854	0.52
389.1135864	5.35
397.1954346	0.95
409.1453247	0.18
415.1477051	0.56
423.4963989	0.44
425.9468994	0.23
433.0880127	5.12
451.3314209	0.40
455.3123779	3.39
461.1036377	0.13
464.4260864	0.22
471.4132080	0.06
473.1361084	0.19
516.1579590	0.42
558.1398315	0.31
563.3405151	0.76
617.4444580	0.08
634.9866943	0.29
641.0176392	1.00
665.2229004	0.20
707.1371460	0.79
715.7348022	0.23
743.1946411	0.08
761.4321899	0.49
779.0796509	8.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	615.03
Annotation	Unknow
Peak:m/z	Relative Intensity
186.9573059	0.03
211.1211853	0.08
213.0574951	0.04
230.7831879	0.13
246.3101044	0.06
248.8921051	0.05
255.0975037	0.27
289.0844727	0.03
299.0352173	0.23
307.1528320	0.06
317.0582886	1.42
318.5151978	0.14
333.1607056	0.22
343.1402588	0.34
349.3497314	0.04
361.1239624	0.46
365.0274658	0.10
379.1188354	0.09
387.0422974	0.44
404.9730225	12.40
407.0526733	0.21
422.9882202	100.00
423.6058960	0.39
439.2154541	0.03
463.1381226	0.09
523.1040039	0.16
532.2528687	0.24
545.5382690	0.05
564.7162476	0.07
596.7091675	0.24
597.4028931	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.1612
Annotation	3,4,5-Trimethoxyphenyl acetate
Peak:m/z	Relative Intensity
161.1611938	0.11
174.8122253	0.22
175.9786987	3.25
201.0488129	0.11
202.0155792	0.06
219.9773407	56.21
221.0502930	0.96
227.2137909	0.50
233.8526154	0.07
241.2166443	0.06
245.1935425	0.85
249.0729980	0.07
271.1571960	1.06
289.0513000	100.00
289.7018433	0.43
329.1655884	0.29
353.2488708	0.35
355.3612366	0.12
365.0271606	0.08
367.2032776	0.06
382.1423340	1.09
383.2348022	4.76
407.6271057	0.04
422.3346252	0.14
423.1114807	0.20
432.1002197	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1301
Annotation	Unknow
Peak:m/z	Relative Intensity
163.2798920	0.19
171.9713745	0.55
173.1448212	0.38
185.1564331	0.42
186.0790253	0.26
187.1211548	22.32
189.0191345	27.52
203.1117706	5.79
204.9944763	0.65
211.0969391	0.38
213.1099701	4.49
214.9301758	0.12
223.1293640	0.18
229.3562622	0.68
230.9951782	26.32
233.0230713	10.85
244.9295044	0.13
247.1230621	0.27
251.0655518	0.99
256.9978333	4.21
275.0746460	12.47
276.9526978	8.96
282.0127869	0.27
293.1237793	0.40
295.0757141	7.19
300.9061890	0.42
308.8548584	1.00
319.1538696	17.26
325.0424805	0.51
337.0690308	6.93
396.9736938	11.02
414.9313354	0.35
431.3512573	0.10
439.0593872	6.03
440.3870850	4.97
441.0250244	100.00
459.0537109	32.59
459.7147827	0.38
461.6085205	0.72
482.9024048	40.64
503.2402954	0.61
518.9299316	0.75
526.2318115	1.50
543.2506714	0.93
545.4158325	0.51
558.4046021	0.39
561.2935181	0.94
573.5751953	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.06
Annotation	Quinic acid
Peak:m/z	Relative Intensity
56.9944687	1.41
58.8913116	5.30
60.9570618	1.99
67.0763016	0.55
69.0708160	0.57
70.8724976	9.14
80.8161545	1.24
82.7735825	1.36
84.9898224	92.14
86.9518433	15.52
89.0065308	0.14
92.9954224	54.05
97.0143433	0.32
99.0879669	2.38
101.0265045	0.73
109.0279388	19.67
111.0042725	43.87
113.0624084	2.31
115.0174255	1.18
126.9839020	100.00
128.9719543	9.27
137.0477142	1.87
143.0899658	4.61
144.8175812	4.90
146.9127045	4.62
152.9351044	7.69
155.0678864	7.10
171.0112152	34.63
173.0656891	84.07
191.0131836	2.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
98.8966370	0.04
104.9759827	0.04
106.9978790	0.05
121.1054077	0.12
123.0625687	0.65
124.9945297	100.00
128.9632721	0.41
137.0478058	0.13
146.9736633	0.52
147.7490845	0.18
148.9909363	20.22
152.8192749	0.09
167.0812073	1.82
173.0936127	0.07
177.2272797	0.12
179.1054688	0.89
191.0410614	6.61
199.0956726	0.25
202.8476257	0.25
207.3054199	0.27
209.0499573	2.06
225.3975830	0.12
229.2627258	0.08
251.2483215	0.44
263.1715698	0.15
267.1210938	0.54
269.0448303	0.70
283.0524292	0.11
284.9943848	1.57
302.5524902	0.06
311.2059326	0.72
312.4041748	0.04
314.8900757	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.1867
Annotation	Terretonin F
Peak:m/z	Relative Intensity
132.8228455	0.25
134.8802948	0.67
137.1178131	1.59
143.1579437	0.10
144.8586426	1.69
147.1403656	3.16
148.9779205	0.76
157.0824890	0.40
159.1135712	1.82
159.8913116	0.57
162.2454834	0.34
163.2030029	0.34
164.8604736	0.54
166.8623047	0.14
169.1316681	0.20
171.1417542	1.21
173.1255493	4.21
174.1721039	0.75
175.1904144	2.46
177.0566711	1.12
179.1697540	0.72
181.3665161	0.34
183.7252197	1.27
184.9072266	1.12
186.0021667	0.49
187.1821899	1.14
188.1559143	0.23
189.0764160	0.89
189.8458862	0.11
191.1196747	2.06
192.9492188	0.21
195.1533508	0.64
195.7816162	1.07
197.1182556	1.37
198.1122437	0.70
199.0734558	23.04
201.0700684	9.01
203.1089172	3.59
205.1265564	1.34
209.0668030	0.96
210.1871643	0.53
211.1647186	1.62
212.1893311	0.59
213.1820221	1.09
215.2436523	1.84
217.1494751	1.35
218.1296997	0.53
219.3698425	1.56
221.1046143	1.84
223.0993347	0.67
224.1988373	1.16
225.2559509	5.49
227.1120453	28.85
229.2027130	86.91
230.2719116	0.61
231.1451416	1.15
234.2971802	0.58
235.1729431	1.57
236.1203461	0.24
237.1350861	3.12
238.1517029	0.25
239.4106445	0.18
241.0179596	0.75
243.0877991	6.87
245.1502686	2.36
245.8577576	0.36
247.0697021	0.98
248.1608276	1.03
249.2403564	3.55
250.2102966	0.16
251.1848450	1.89
253.1929321	9.77
255.2981873	2.33
256.1278381	0.99
257.0873108	2.24
258.1411438	0.37
259.1941223	1.21
261.1778870	2.84
263.2408142	2.17
264.4330750	0.47
265.2034607	2.42
267.3484192	0.69
269.1791687	1.62
271.1989441	7.36
273.2414856	1.76
274.1808167	0.56
275.3566284	1.14
277.1494751	6.53
278.1743469	31.07
279.2540283	2.02
281.2939453	2.28
283.1174011	39.69
284.2575684	0.59
285.3284302	0.63
286.0096130	0.41
287.2977295	2.78
289.0852661	4.33
290.0969849	2.79
291.1844482	2.45
293.1911011	12.25
295.1326294	4.83
296.2269897	0.78
297.0751038	3.97
298.2564392	0.36
299.2254639	3.58
301.1380310	6.18
302.5309753	1.40
303.2423096	2.09
305.6610413	41.71
306.2950134	63.61
307.4589233	3.68
309.0330200	2.06
311.3157349	4.20
313.2879333	2.75
315.1047668	0.90
317.2947998	0.94
319.3188782	1.00
320.6606445	6.22
321.2729492	79.05
323.2812500	5.33
324.3718872	0.26
327.2167664	0.89
329.2996521	17.72
331.3688965	4.12
333.1366577	5.94
334.1668701	9.50
335.3268433	5.70
337.0111694	3.23
338.1243896	0.77
339.1407471	2.26
343.2247925	0.21
345.3295898	0.42
347.3708191	1.92
348.1760864	0.17
349.2256470	15.28
351.2685547	9.56
353.3481750	5.93
355.2060852	0.95
357.2287903	0.36
359.2081604	0.65
361.3084717	1.46
362.1481934	0.44
363.2363281	20.88
364.1399231	0.65
365.2616577	11.87
366.1023254	1.17
367.2153015	7.83
368.4347534	0.21
371.2314148	0.52
373.3406677	0.12
374.2480774	0.69
374.9114075	0.38
377.3198547	9.65
378.0834656	0.91
379.2543640	5.55
381.3079224	100.00
382.3543091	3.73
383.5408936	0.33
389.2211609	1.88
392.3149109	1.12
393.3507080	4.69
395.3741455	15.77
397.2195129	16.32
405.4844055	0.71
407.2941895	18.68
408.3517151	0.92
409.3130798	5.32
410.8840942	0.16
421.3488464	1.32
423.5527039	0.41
425.2421570	8.25
427.2167664	0.39
436.2273865	0.15
439.2911377	1.36
441.1702881	0.12
451.2722473	9.43
454.3965759	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	683.8
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0490875	6.49
194.0757294	0.08
204.9496613	0.31
218.8529968	0.15
220.0939331	0.57
233.2782440	0.11
237.1268921	0.19
245.1201630	0.44
261.0695496	0.25
273.4265442	0.31
283.3797607	0.23
291.1437073	0.13
312.2860413	0.23
315.5758057	10.37
316.2506104	0.64
329.1484680	11.84
330.1162109	0.47
335.5909424	0.21
337.0367126	0.33
347.3025513	0.14
355.3996582	0.31
357.2766113	0.32
377.2700806	2.26
381.0723877	0.24
382.2371216	0.37
383.6724243	8.04
384.6173706	0.05
390.0837402	0.19
405.3306885	0.14
417.3427124	0.16
430.1020508	0.48
438.2564087	0.79
451.5237427	8.35
452.2647705	1.20
454.2393188	0.18
456.2077026	0.22
463.0708008	0.11
468.8001709	0.09
471.6408691	0.99
479.6994019	0.89
481.3977051	0.13
489.0489502	0.24
506.9179077	0.23
519.6643066	28.44
520.8543091	0.79
522.1574097	0.22
523.7085571	0.23
530.2611084	0.08
540.0532837	0.27
547.6256714	4.15
548.3713989	0.32
551.4247437	0.28
567.5952759	0.11
571.5692749	0.07
572.8340454	0.46
574.2345581	6.45
575.2192383	0.35
581.6857300	0.23
592.2763672	0.37
593.9316406	0.22
598.5558472	0.21
600.2136841	0.51
611.5382690	0.12
613.9736938	0.18
615.6330566	26.11
616.4640503	1.87
617.9199829	0.56
625.6414185	0.32
626.6399536	0.29
629.0943604	0.80
630.0173950	3.91
631.0396118	1.00
637.4003296	0.14
642.4598999	0.16
647.0311890	0.17
650.9392700	0.35
652.2409668	0.06
660.4478149	0.25
665.3353882	1.72
666.2803955	0.07
667.1372070	0.11
697.9284668	0.24
710.1766968	7.92
711.2363892	2.57
766.0646973	13.51
766.9946899	1.95
777.0033569	0.21
778.0534668	1.69
778.9628906	0.45
783.1246948	0.23
795.9973145	0.23
902.0540161	100.00
903.1806030	22.63
934.3087769	0.30
935.0945435	0.17
940.1144409	0.38
941.2795410	2.26
942.1801147	0.28
943.2489624	0.34
1037.4714360	0.07
1039.1411130	0.21
1092.2431640	0.06
1093.8811040	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.1544
Annotation	Clitoriacetal 11-O-glucoside
Peak:m/z	Relative Intensity
155.0212402	0.07
177.1375732	0.11
179.1579590	0.36
179.9667664	0.26
189.0558014	0.09
195.1967926	0.18
196.1455688	0.20
201.0205688	0.06
202.0412903	0.32
202.9538269	3.26
206.8738708	0.50
208.1776428	0.12
212.1098938	0.08
216.6882935	0.12
230.9823456	1.06
235.2750092	0.19
247.2993469	0.21
248.9172668	0.19
251.1153870	0.08
254.9057465	0.32
261.1941528	0.05
261.8929443	0.04
263.1474609	0.12
264.9807434	0.22
269.4733276	0.04
271.3330078	0.13
272.2200928	0.13
279.1790771	0.13
287.1238098	11.75
291.0664368	0.03
297.3611450	0.19
303.1086426	4.57
304.3222351	7.74
305.1151428	100.00
307.3338318	0.06
313.0824585	0.10
314.0780640	0.04
314.9421387	0.45
319.1897583	0.30
327.2455444	0.81
329.1550293	0.55
332.9855347	0.36
341.2672729	0.05
343.2482910	0.30
345.0253906	0.37
346.1121826	0.86
347.0845337	1.96
347.7647095	0.04
348.9978027	0.83
349.5991821	0.05
353.1333008	0.14
355.2913208	0.07
359.2024536	0.21
361.0130615	0.14
365.1670532	0.47
369.4915771	0.31
371.2429199	0.88
373.3233643	0.04
377.9533081	0.08
379.1329956	0.09
383.1895142	0.16
385.0250854	0.74
389.0844727	0.51
391.1370850	2.36
391.7581787	0.02
394.1978149	0.07
395.3753662	0.34
400.9485474	0.04
405.9959106	0.31
409.3811646	0.11
411.1451416	0.29
413.2259521	1.68
414.5160522	0.08
427.4012451	0.14
431.2180176	0.35
432.4656982	0.07
438.1835327	0.17
446.8245850	0.14
448.7847290	0.32
450.2388306	0.10
451.1715088	0.54
455.0535889	0.16
463.0002441	0.09
464.9298096	0.08
466.7852173	0.71
473.2581177	4.06
481.1536255	0.06
487.6513672	0.09
489.3903198	0.03
491.1596069	2.81
493.1309204	0.04
495.2467651	0.27
499.2264404	1.54
501.9865112	0.82
502.9395142	0.67
504.7416382	0.11
507.9122925	0.06
509.0969849	0.75
509.8300171	0.06
511.1691284	0.04
515.5237427	0.12
517.0076904	29.30
517.6763306	0.05
520.4776001	0.36
523.2648315	0.17
529.1658936	0.25
533.1227417	0.05
534.3744507	3.41
535.0718384	16.54
535.8607788	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	670.83
Annotation	Unknow
Peak:m/z	Relative Intensity
206.8147278	0.01
209.0045776	0.04
214.0909271	0.03
238.7995911	0.02
251.1030121	1.44
290.8334656	0.20
333.4854736	0.16
334.9259033	2.75
375.0689697	0.01
388.2957764	0.02
394.7692261	0.02
418.8665161	15.87
432.8919678	0.03
434.7404785	0.03
458.1010132	0.41
458.8026733	0.05
467.1580811	0.09
491.0031128	0.02
495.2338257	0.08
496.0330811	0.16
500.7114258	0.02
502.6950684	25.32
503.3636475	0.24
509.0879517	0.15
518.7786255	0.03
526.9968872	0.06
528.1402588	0.01
538.8341064	0.05
550.9409790	0.31
556.5542603	0.02
564.9421387	0.03
569.0775146	0.07
580.7773438	0.01
583.9959106	0.04
584.7378540	0.07
586.6287231	100.00
587.3683472	0.56
595.4264526	0.06
602.6528931	0.24
607.0432739	0.06
610.3738403	0.14
610.9860840	0.32
624.8154297	0.04
627.1554565	0.01
640.9003296	0.04
652.0592651	0.07
653.2014771	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	301.0718
Annotation	Alnustinol
Peak:m/z	Relative Intensity
106.9674149	0.23
108.1400146	0.19
124.9364319	13.93
134.1237183	0.08
146.2118378	0.06
148.9190369	0.39
150.9424438	3.76
153.2427979	0.04
158.1522369	0.78
160.0051727	0.18
161.0258179	0.23
164.0153503	3.90
165.1706696	0.21
170.8220367	0.07
173.0673218	2.52
173.9958496	3.69
175.1263580	0.88
179.0657196	0.42
180.1569824	0.05
183.9803467	0.09
184.9930267	1.11
186.0472412	0.03
188.0633087	0.13
189.2373657	0.14
191.0791016	0.73
196.1658020	0.20
198.1818237	0.84
199.0957336	11.78
200.0698547	2.26
201.1145020	2.43
202.1364441	1.15
209.1227112	0.12
211.0408936	0.22
213.1350708	0.97
213.9492493	1.33
215.0312195	6.27
216.0704041	0.59
217.1277161	3.67
224.0474854	2.34
225.0269470	0.29
227.0818176	7.51
228.1151428	0.43
228.9718628	0.11
230.1375732	0.99
231.0402222	0.34
233.1204224	6.87
234.2680054	0.04
239.1333313	5.77
240.1625366	4.57
241.2767029	5.90
242.0558472	50.57
243.1779175	0.33
244.9401245	0.02
255.1467285	0.66
257.0861206	30.42
258.0290527	16.29
259.1509094	1.87
265.0122681	0.08
266.8657532	0.36
268.0144348	5.05
270.2589722	0.36
271.2078552	1.34
273.1049194	0.12
283.0310059	37.31
284.1637878	0.25
286.0524292	100.00
287.0863647	0.73
301.2140808	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	640.2218
Annotation	Unknow
Peak:m/z	Relative Intensity
196.1591187	1.61
197.0914612	0.31
206.1044312	0.09
210.2876892	0.06
222.3031921	0.06
229.0429077	0.13
247.1861725	0.30
249.0532074	0.07
254.9067993	0.30
269.3806458	0.10
272.1588745	0.03
272.9031372	0.37
284.0563965	0.05
289.0183105	0.20
314.0939941	0.09
330.2248230	0.20
332.2179565	100.00
333.8065796	0.20
338.3692627	0.08
344.3621826	0.30
348.4120483	0.17
360.2935791	1.24
372.0219116	0.37
398.6119995	0.56
442.4114990	0.81
449.7591553	0.06
460.1614380	1.57
472.3312378	0.22
476.4949341	0.32
478.0466309	6.48
483.4025269	0.39
491.8402100	0.08
494.1707153	23.00
502.1689453	0.10
506.1414185	0.60
546.1940308	0.09
547.8070679	0.14
578.3881226	0.13
585.1468506	0.03
592.4107056	0.12
595.6012573	0.58
596.3946533	0.54
604.4719849	0.58
618.6276855	0.65
622.1987915	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.1995
Annotation	Faratroside
Peak:m/z	Relative Intensity
230.1980438	0.02
243.3199463	0.05
247.1625977	0.05
255.2419434	0.02
259.3255615	0.05
273.2540283	0.03
285.1860962	0.13
286.9489136	0.29
301.2625732	0.05
305.0588074	0.19
315.0490112	0.62
316.1311646	0.03
330.1881409	2.16
345.0975952	17.35
347.1440430	0.02
444.9846802	0.05
449.2922974	0.05
489.3428955	0.54
507.1500244	36.87
507.7684326	0.43
513.1513672	0.09
530.3914795	0.02
531.5097656	0.03
535.1032715	0.42
549.2711792	22.77
577.2951050	0.03
589.2423706	7.20
591.2608032	2.52
614.3739624	0.04
615.5543213	0.02
619.2333984	0.11
631.2844849	1.92
632.3670044	0.18
633.4375000	0.47
651.1151123	100.00
651.7583008	0.26
671.3076782	0.17
673.4614258	0.06
693.1579590	12.10
695.4008179	0.02
709.3341064	0.12
723.5462036	0.04
726.3750000	0.06
733.2272339	1.65
735.0462036	0.22
748.2883911	0.02
751.0861816	0.63
770.3012085	0.07
772.9840088	0.14
777.1591797	0.09
794.2794800	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	621.2884
Annotation	Decipidone
Peak:m/z	Relative Intensity
174.9748077	3.49
176.9634247	1.21
189.1815948	0.05
192.1166992	0.06
199.0316925	0.09
205.0641785	0.07
206.9913483	100.00
208.9611053	0.14
217.1420746	0.39
221.0938110	0.05
225.0899506	3.94
230.1456909	0.03
235.1476135	8.71
253.1748505	7.43
257.1499023	0.03
268.5664062	0.03
283.2792358	0.04
287.1028748	1.16
291.0319824	0.02
295.2167664	0.05
297.1916504	0.03
300.9479980	0.02
305.4116211	0.02
309.0848999	0.07
315.1921997	0.11
325.1923218	0.08
333.2592773	0.18
335.2105103	0.05
336.5312500	0.12
339.0332642	0.09
347.1576538	0.25
350.0137939	0.97
351.1044312	5.38
352.9064331	0.11
368.3515015	5.59
369.1411743	35.57
371.1696777	0.15
375.3819580	0.15
377.3250122	0.16
379.2008667	0.18
385.3067627	0.19
387.0702515	0.36
390.8875122	0.12
393.3634033	0.06
395.1386108	0.05
396.0400391	0.04
397.1244507	1.95
399.1915894	0.11
409.3507080	0.06
412.1755371	0.09
415.1825562	0.81
416.2958984	0.08
417.5231934	0.06
423.4003906	0.26
427.0339355	0.29
441.1542358	0.13
449.6072388	0.03
452.9956665	0.02
456.5563965	0.16
459.0022583	0.55
460.0741577	0.09
466.1824951	0.17
467.5062256	0.17
471.2206421	0.13
472.0137329	0.08
475.2628174	0.02
477.3743286	0.15
478.1670532	0.10
482.7404785	0.10
483.3701172	0.09
517.7655640	0.12
519.3052368	0.42
531.4520264	0.04
535.1552124	0.17
548.9935913	0.41
561.0410156	0.10
561.7376099	0.11
566.5517578	0.04
567.4396973	0.20
572.4625854	0.07
574.5946045	0.04
577.1047974	0.52
584.2212524	0.05
585.3233643	0.70
597.1057739	0.13
602.9860840	33.97
603.8362427	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	793.2999
Annotation	Fuscinarin
Peak:m/z	Relative Intensity
226.0454102	0.18
226.9885406	0.07
228.2062378	0.13
229.2721863	0.08
235.8880615	0.43
238.0438538	0.28
240.2122650	0.49
241.7235718	0.32
242.9444275	0.03
243.9432373	0.20
245.1797943	0.06
247.1478729	0.14
249.9879150	0.12
252.2508087	0.29
256.2545776	0.04
257.3165283	0.12
258.9676514	0.07
263.6997070	0.20
268.0997925	0.79
269.1581116	0.13
271.1900330	0.23
277.1708374	0.12
286.2365723	0.35
287.1244507	0.27
291.2975464	0.04
292.2432251	0.22
293.3318481	0.13
294.0909424	0.07
296.9416199	0.24
299.1090088	0.10
301.1323242	0.15
305.0826416	0.31
306.4160461	0.14
309.1568298	0.14
310.0524292	0.36
313.0072327	0.02
317.0274963	0.37
318.0928955	0.26
320.2893066	0.28
321.9127197	0.07
322.9254761	0.51
328.2018738	0.33
330.4705200	0.24
331.4752808	0.13
335.1314087	0.12
338.1317749	1.54
341.2457275	0.08
344.2798767	0.18
346.3041992	0.17
347.1968994	0.08
348.3015137	0.22
350.0756836	0.18
352.3296204	0.24
355.2719116	0.16
356.3052673	0.10
362.2243042	2.36
363.9902344	0.40
365.1404419	0.04
365.8460693	0.12
367.2561646	0.68
368.2615967	0.09
370.3208008	0.08
372.2588806	0.58
373.0513306	0.08
373.9875488	0.14
376.3772583	0.16
378.3531494	0.03
380.1726685	1.87
384.3243408	0.08
384.9515991	0.11
386.1694336	0.10
388.1298218	0.28
390.4060059	0.03
392.0324707	0.05
393.3217163	0.18
396.4012451	0.03
398.9365234	0.12
400.2108765	0.03
401.1126709	0.21
401.8983765	0.22
404.2297363	0.89
405.7493286	0.03
407.1456299	0.02
408.1157227	0.16
409.7180176	0.48
412.4772949	0.10
414.1633911	0.12
416.2762451	0.08
418.3346558	0.13
422.0448608	0.58
428.1370850	0.86
430.3720093	0.10
432.1510010	0.42
434.2119141	0.27
438.3584595	0.28
440.4474487	0.07
446.2012939	0.93
449.1359253	0.11
450.4042969	0.12
452.3446045	0.12
453.3477783	0.18
456.1201782	0.20
457.3831177	0.11
458.8706055	0.12
460.2446289	0.07
464.2355347	5.67
466.1823730	0.16
470.2026367	0.14
472.4094849	0.30
474.3348389	0.31
478.1784668	0.18
482.3173218	6.62
488.3677368	0.25
491.3691406	0.05
494.2963257	0.39
500.2847900	2.10
502.5190430	0.04
506.3232422	0.87
512.2189331	0.27
516.4952393	0.14
519.2802734	0.27
524.1744385	0.91
527.3696899	0.48
528.1141968	0.09
529.1941528	0.05
530.3016968	0.34
541.9208984	0.13
542.5522461	0.34
545.2324219	49.25
546.0976562	0.03
548.4245605	0.32
550.3248291	0.25
554.2713623	0.85
566.4601440	0.09
572.3524780	0.53
584.3170166	0.24
587.6052246	0.62
590.3965454	1.00
591.2139893	0.56
598.4124146	0.23
605.3634033	0.21
610.8675537	0.11
614.0673218	0.13
615.3604126	0.23
626.4099731	0.15
631.2719727	0.34
632.0350342	0.31
634.0687866	0.17
638.3159790	0.08
642.3128052	0.16
642.9960327	0.62
644.7655029	0.04
646.0852661	0.08
663.0609741	0.38
663.9292603	0.06
668.2556763	0.19
676.4319458	0.26
686.1428833	1.20
686.7669067	0.03
689.3445435	0.17
690.1219482	0.07
691.8135376	0.33
694.6787720	0.18
700.2518311	0.10
704.2864990	0.39
707.3258667	4.05
711.7826538	0.63
712.5703735	0.19
718.2395630	0.19
720.0622559	0.19
727.3854980	0.25
730.3463135	0.59
731.3815918	0.79
733.4755859	0.13
739.1478882	0.07
747.3602905	0.08
749.3181152	100.00
750.3143311	0.40
757.0513306	0.28
764.7911987	0.16
775.2655029	1.63
784.0525513	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	591.19
Annotation	Unknow
Peak:m/z	Relative Intensity
173.2699585	0.09
175.0871277	0.15
177.1235809	2.86
179.1145630	0.19
184.9407959	0.03
186.2902832	0.04
187.1775208	0.03
187.8256836	0.02
191.0253296	0.29
199.4127197	0.18
201.1052551	0.31
203.0850525	0.94
205.1484222	0.28
207.0076141	0.20
213.1430359	0.09
217.0831604	0.22
219.0722961	0.76
221.1245422	8.82
222.4279480	0.04
223.3229370	0.08
229.3350830	0.06
231.2023163	0.28
235.1170807	0.30
237.2491150	0.12
242.9828033	0.19
245.2407837	0.25
249.2148743	0.57
255.2068481	0.04
257.1724854	0.15
259.3792114	0.34
261.1175537	0.51
263.0752563	4.79
273.2156677	0.09
275.2092590	0.48
279.1081543	0.40
280.8748169	0.15
284.7918701	0.07
285.4989624	0.19
287.2630310	0.17
291.2733154	0.14
293.1788940	2.71
295.2306824	0.02
303.3197632	0.05
304.0972290	0.05
305.2306213	0.30
307.3942871	0.05
311.0602417	0.03
317.2641296	0.09
321.3709717	0.09
323.1971436	5.62
325.1197510	0.87
339.0368652	0.55
345.2579346	0.03
347.0831299	0.22
349.3966064	0.03
355.3750000	0.05
365.0859985	1.81
367.0499268	0.12
379.1470947	0.06
381.5848389	0.52
383.0603027	100.00
383.6752930	0.38
384.9998169	0.07
388.9570312	0.02
393.0860596	0.11
396.8771362	0.17
399.1299438	0.04
401.3827515	0.84
406.9413452	0.41
411.1707153	0.58
423.3016968	0.19
425.0231934	1.84
428.8686523	9.04
429.5462646	0.04
437.0565186	0.12
442.9020996	0.31
447.4023438	0.09
449.1796265	0.12
454.6385498	0.69
455.2730713	0.59
459.1262207	0.11
465.6061401	0.03
467.0599976	0.10
481.3894043	0.06
483.5862427	0.37
484.8338013	2.85
485.6021118	0.06
486.9150391	0.04
497.1846924	0.06
500.3651733	0.04
501.5106201	0.04
503.2591553	0.03
509.1061401	0.04
510.3563843	0.13
519.3790894	0.02
527.0545044	0.15
529.4133301	0.18
530.8438110	0.28
531.4768066	0.06
542.4417114	0.09
544.7632446	38.56
545.4353638	0.44
547.3145142	0.42
549.1808472	0.16
561.1555176	0.04
571.2808838	0.05
573.1215210	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	695.28
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0503082	1.12
193.9642639	0.45
195.0473785	0.80
201.9985352	0.10
203.0090637	15.50
204.1366119	1.93
205.1418762	0.47
214.6943207	0.14
222.1393433	0.21
225.0380554	0.19
228.9807739	0.54
233.1391907	0.39
240.2054443	0.10
243.0930176	0.25
244.1626282	0.14
245.2014618	0.84
249.6868286	0.06
261.1341858	0.51
263.1497192	0.20
265.1884766	0.18
286.8448486	0.09
289.2179565	1.00
292.6058350	0.80
309.2443237	0.21
310.4678650	0.04
315.0023804	0.53
317.2316284	1.87
319.1340332	0.15
320.9910278	3.39
321.7583313	0.86
326.3535156	2.61
327.0178223	0.35
329.0575562	18.44
330.2622070	3.08
331.3432617	1.37
332.4954224	0.08
333.8426514	0.43
334.6166992	0.91
339.0591125	9.15
340.1918945	1.76
341.1320801	0.27
342.5425415	0.71
356.2128296	0.22
363.7076416	0.30
364.4702148	0.28
367.2554932	0.17
376.2634888	0.09
382.1312866	0.53
385.2200317	2.45
386.1021729	28.17
389.0561523	4.66
390.2485352	0.53
392.0208130	0.66
393.9082031	1.83
394.5860596	2.24
395.9805298	0.41
401.5328979	0.48
403.0949097	0.10
410.0779419	1.91
411.0608521	0.29
429.1788940	0.13
432.2160645	1.55
437.9287720	0.11
442.3182983	0.38
448.2802124	0.16
449.4444580	0.28
450.0615845	0.43
450.8930054	0.37
456.6530151	2.99
457.2788086	13.00
458.2442627	2.83
461.9660034	1.66
462.6757812	1.42
465.2001953	0.13
466.9906006	0.36
469.1708374	0.54
477.5516968	0.45
479.3630981	0.09
487.0746460	0.29
489.4907837	0.79
490.6363525	4.72
493.0439453	0.12
502.5282593	0.14
513.0663452	0.19
523.1724243	0.76
525.2763062	10.60
526.0819702	2.46
530.2357788	4.00
531.0155640	0.77
533.3251343	0.36
541.1140747	10.48
542.6349487	0.16
546.6331177	0.39
547.9896240	0.17
556.8937378	0.23
558.2127075	15.13
558.8583374	31.48
559.7787476	1.03
560.4871216	0.76
561.0891724	0.30
563.1375732	0.52
565.1885376	0.21
567.7626953	0.26
575.0734253	0.20
576.4136963	0.69
577.8907471	0.18
583.5056763	0.32
584.5888062	0.59
585.3778687	0.85
586.7308960	0.94
587.8169556	0.16
588.6442261	0.07
589.5496826	0.19
591.1526489	0.10
593.0743408	0.34
594.2507324	0.48
595.2517090	0.35
601.3711548	0.16
604.1497192	0.08
607.0942993	0.30
609.2843018	0.48
621.1249390	0.20
626.3451538	100.00
627.1895142	24.69
628.2783813	1.28
629.2869263	0.16
630.1652222	0.13
631.3486938	0.24
635.7846069	0.05
641.1552734	0.31
642.2570801	0.53
645.4166260	0.60
648.0355225	0.23
648.6867676	0.51
650.0983276	0.21
651.0277100	1.36
652.2854614	0.17
654.2389526	1.01
662.0647583	0.11
663.1691284	0.97
664.6260376	0.34
666.6232300	0.39
676.1573486	0.71
676.8943481	0.71
677.5072632	0.24
689.8937378	0.14
710.2301025	0.43
711.1920776	0.79
712.3966064	0.78
713.3671265	8.75
714.0540771	2.48
719.9875488	2.07
721.2058716	1.79
722.4895630	0.97
723.5201416	7.46
730.2111206	0.90
731.8542480	0.54
733.3082886	0.88
733.9093628	0.20
739.4844360	0.23
765.1573486	0.14
776.0912476	1.74
777.1188354	3.20
778.0700684	1.97
779.1344604	3.20
779.7556152	0.03
786.0001831	3.07
787.0449829	10.54
788.1726074	5.89
788.9076538	2.12
789.8195190	0.24
798.8562012	0.45
800.3222046	0.36
801.2995605	0.18
806.1091309	0.54
817.3759155	0.37
859.5419922	0.19
912.0512695	11.10
913.1331177	28.04
914.1418457	18.44
914.9362183	15.03
916.1003418	2.53
922.1755371	11.90
923.0396118	29.77
924.1532593	16.03
925.2797852	3.63
953.1162720	0.96
956.9819946	0.31
962.1139526	0.64
963.6271362	0.56
978.0029907	0.13
1030.9289550	0.15
1043.9951170	0.26
1049.7094730	1.52
1051.1043700	13.43
1052.3111570	2.20
1058.1684570	0.08
1059.9870610	0.17
1114.4968260	0.15
1115.8725590	2.39
1117.2492680	0.29
1127.1684570	0.21
1249.6968990	0.30
1250.6126710	2.17
1251.2375490	0.45
1251.9348140	2.03
1252.8514400	1.34
1253.4919430	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	484.2012
Annotation	Unknow
Peak:m/z	Relative Intensity
127.0542984	0.02
144.8724976	0.08
177.3262024	0.01
183.0702820	0.18
197.1865234	0.02
199.3432617	0.03
212.9058990	0.50
222.2462921	0.01
228.6835632	0.05
230.0180969	0.02
231.0817871	0.51
236.3265686	0.02
242.5638580	0.03
249.0578003	0.08
267.2057495	0.11
268.9415894	0.11
276.3240967	0.04
287.0109558	0.62
291.1026611	0.21
303.0965576	0.03
304.9364624	9.90
307.2975464	0.13
315.4722900	0.03
322.3885803	0.03
331.3028564	0.05
333.1279297	0.05
338.3315125	0.13
350.7504578	0.41
353.4149780	0.02
356.3286133	0.07
357.0071106	0.18
364.3298950	0.04
375.0349121	8.37
382.8156433	0.07
392.9245300	22.03
393.5969238	0.16
404.7282715	0.04
406.1304016	0.07
419.1528015	0.03
430.8507385	1.60
436.2060242	0.09
439.1419373	0.04
440.4847412	0.02
441.9879761	0.04
446.3062439	0.07
448.7693176	13.53
449.5680847	0.08
455.3947449	0.11
464.7162170	0.22
466.7954712	100.00
467.5917664	0.11
469.1012878	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1063
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
161.0725250	0.14
184.8293152	0.04
191.1203918	0.34
196.8590088	0.13
219.2816315	0.11
231.3349915	0.06
232.9426880	0.03
243.2355957	0.10
247.1385803	0.05
249.0087891	0.08
252.8013000	0.05
255.5149841	0.06
261.0629272	0.17
269.2571106	0.13
273.1102295	0.12
274.2073059	0.05
275.9404907	0.09
279.3266907	0.07
280.9892883	0.10
285.2008667	0.06
286.1731873	0.07
287.1289062	0.73
289.1552734	0.03
294.2546387	0.08
297.1679688	0.13
299.1681213	1.22
311.1618958	3.03
312.0772095	0.03
313.1948853	0.09
319.0693359	0.06
323.1582642	0.10
327.2709961	0.11
329.1678467	21.44
339.4689331	0.06
353.1824341	14.14
359.1662598	0.81
365.1477661	0.23
367.1258850	0.34
369.1801453	0.14
371.1151428	0.34
377.3055725	0.16
383.1466675	30.57
387.7713928	0.05
395.2247009	9.67
401.1956787	0.13
405.2424622	0.08
409.9100037	0.04
413.2186890	22.58
419.0377197	0.06
431.1329346	100.00
431.9762878	0.52
440.0231323	0.04
440.8254395	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1821
Annotation	Hesperidin
Peak:m/z	Relative Intensity
172.2108154	0.02
174.0518494	0.12
176.1272736	0.01
184.9988708	0.12
186.3918457	0.04
187.1062012	0.10
189.1542664	0.03
195.9013214	0.01
198.2936859	0.11
199.072937	1.50
200.0895386	0.11
201.0048828	0.69
202.2365112	0.07
210.9580688	0.11
212.0602264	0.01
213.1336365	0.03
214.2224731	0.29
215.1656189	0.76
217.2458801	0.08
222.9292755	0.03
224.1123962	0.18
227.020874	0.58
230.0265656	0.04
231.131897	0.02
233.2558746	0.17
239.1924286	0.02
240.0422363	0.26
241.0579681	0.61
242.1140442	1.70
244.2345123	0.02
257.1191101	0.70
258.0471802	0.15
258.9985352	0.14
263.9751587	0.02
265.1766663	0.11
266.953125	0.03
268.0681152	0.46
283.1380005	0.58
284.1588135	0.17
285.0601807	0.32
286.0571289	1.81
299.1542358	1.01
301.0808716	100.00
307.2182007	0.07
309.0128784	0.09
310.288269	0.04
315.1222534	0.05
325.1201172	0.69
343.1685791	0.23
355.2506104	0.12
367.1386719	0.02
369.0374146	0.02
385.0490112	0.06
447.6119995	0.03
465.1563721	0.05
479.0888062	0.07
489.1885986	0.10
507.440918	0.08
519.0230103	0.02
563.2687988	0.04
565.1010132	0.03
576.9522705	0.02
591.395813	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.1049
Annotation	Drosophylloside
Peak:m/z	Relative Intensity
108.9347916	0.13
110.9954376	0.62
115.9328461	0.08
125.1072083	0.60
127.0712433	0.28
137.1135406	0.90
141.0377655	1.09
142.9934998	2.06
150.8523712	0.16
153.2719727	0.08
154.9920044	1.30
159.0644073	0.92
160.9999695	1.84
169.3146362	0.15
171.0106812	0.07
173.0933533	2.32
174.1934814	0.13
179.1088715	2.43
181.1874084	0.60
185.8963623	0.48
187.0055542	10.36
188.0653229	0.87
190.9977722	50.28
192.0481720	3.09
194.9384460	0.16
199.1206512	6.60
200.1700592	0.27
204.9870911	36.88
206.0126038	1.25
206.9509430	0.05
217.0006409	100.00
218.0603333	3.40
229.1577454	0.63
231.1355286	0.43
231.9833374	0.12
235.0859985	12.48
236.1927795	0.56
237.1611633	0.43
243.1427002	0.96
243.9959717	0.31
247.0738220	53.26
248.1101685	1.52
257.1616821	0.32
259.1322937	1.20
263.2786560	0.13
273.1058655	8.04
273.9629822	0.50
275.0842896	17.53
276.1166077	0.66
278.3269043	0.10
287.0826111	2.51
288.4014893	0.43
289.2090454	11.40
292.2160645	0.08
293.1524963	0.41
297.1526489	0.06
299.1021729	6.80
300.1862183	0.05
303.1976929	0.23
316.2212830	0.21
317.2356262	2.33
318.4867249	0.28
319.2002869	2.15
320.1809692	0.39
331.2303162	0.75
331.9777222	0.40
333.1942139	1.85
335.1609497	2.04
341.1228027	1.40
343.2012024	6.74
344.2992859	0.14
345.4041748	0.21
349.2861328	0.74
359.0874939	0.13
361.1491699	96.90
362.1703796	6.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	421.135
Annotation	Euphroside
Peak:m/z	Relative Intensity
160.8590393	0.59
165.1039429	0.21
169.1431274	0.61
173.0641632	0.17
188.8434753	0.52
190.9710236	5.12
192.9516296	0.07
195.1361389	9.94
198.0378571	0.05
200.0791931	0.06
202.9103394	0.07
213.2211609	0.34
232.2444611	0.52
233.1027527	3.63
234.2160645	0.07
243.1166382	0.07
247.0396118	1.71
251.0368652	0.52
255.2927246	0.09
259.3508301	0.16
265.0574341	0.05
267.1985779	0.21
271.1118774	0.14
273.1056213	0.66
275.0432434	0.52
285.0198669	0.11
298.6176758	0.29
303.1336975	5.29
317.0462646	6.92
320.0587158	0.21
327.1130676	19.33
329.1695862	1.07
333.0635986	0.30
344.6788330	0.07
348.3668823	0.49
349.0200806	0.29
356.9664612	69.39
357.7571716	0.19
358.9766846	0.12
361.0877380	2.23
374.9549255	100.00
375.6708679	0.06
376.6232605	0.25
385.0225220	0.21
389.1533508	2.61
403.0191040	10.01
404.2242737	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	288.9364
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9451828	0.53
130.9500427	1.70
147.0153198	0.32
159.0158081	8.40
174.8995667	100.00
182.9094849	0.02
214.8902588	0.11
217.0242920	0.06
232.7968445	0.13
244.9922485	28.49
261.1552124	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.0338
Annotation	Unknow
Peak:m/z	Relative Intensity
123.1212311	0.02
125.0641632	0.02
136.1255341	0.09
137.0866394	0.42
138.9582520	1.50
143.0321503	0.06
151.0342560	0.43
153.0248108	0.02
163.1194458	0.09
165.0658264	0.29
168.8165588	0.29
172.9200745	0.07
179.1780090	0.22
181.0102539	0.22
183.0596313	0.08
191.0680847	0.28
198.0902710	0.16
199.0504761	0.59
200.0203400	0.12
204.9893188	0.06
209.0947723	0.59
215.9857788	1.96
217.0410309	2.80
218.3776855	0.02
221.3096313	0.10
223.0346985	2.79
235.1133728	0.04
241.0294800	100.00
242.1658936	0.69
249.1086121	0.04
254.0963440	0.03
255.1100464	0.20
258.9764709	0.30
272.1964722	0.03
272.8701782	0.11
274.9052124	0.17
281.4648438	0.08
283.3265381	0.08
288.0618591	0.04
289.3217468	0.33
290.3853760	0.03
299.2373657	1.58
303.2123413	0.07
306.9592285	0.06
319.0032959	0.64
333.2865601	0.04
335.2350464	0.36
341.4989624	0.03
347.1047363	0.04
349.2790222	0.03
350.8882141	0.12
361.0905151	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	264.2315
Annotation	Victoxinine
Peak:m/z	Relative Intensity
79.1661758	0.05
80.8906021	0.78
93.0393372	0.02
94.9826660	1.55
107.2230530	0.05
109.0234985	1.87
110.9216614	0.04
121.0428009	3.29
123.0365295	0.43
123.7932129	0.07
133.0082855	0.05
135.0099182	0.88
136.0458984	0.05
147.1360626	0.04
149.0977783	2.14
151.9597931	0.01
163.1730499	0.17
167.8903351	0.02
175.0786285	0.03
189.1279297	0.04
205.1706848	100.00
206.0807953	0.07
218.2671661	0.16
221.9438019	0.03
223.2787781	0.02
229.5048065	0.03
236.2712860	0.03
246.9688873	0.08
250.1112518	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.64558411	0.18
79.05622101	0.28
80.936203	0.98
82.95137024	0.41
85.15850067	0.44
94.99127197	1.64
96.80477905	2.20
98.99552917	1.25
102.9982605	2.76
104.7705231	1.47
106.0427246	0.27
106.8739166	0.73
108.2155304	0.21
108.9423065	1.33
110.0756836	0.44
111.1494293	0.34
116.7530518	0.11
119.0363464	0.73
121.0067749	0.96
123.0746002	1.24
124.9798889	0.69
126.0232086	0.32
126.9736176	6.00
128.9757233	8.22
129.9589844	0.63
131.0464478	0.30
133.0675049	0.16
135.0901184	2.27
137.0700531	0.13
140.8721771	2.12
143.1490631	2.03
146.1656189	0.21
147.1469879	0.81
149.0360565	1.33
151.0244904	57.27
151.9911346	6.49
153.0136261	0.42
153.9516449	0.27
155.0782318	3.13
157.2104034	0.51
159.1084442	0.32
160.9818268	1.17
163.2668152	0.16
165.0103302	0.70
165.8803253	0.14
167.0870819	6.80
168.0596161	0.33
169.0652161	0.55
171.0947418	0.50
173.1218262	1.55
175.17659	1.38
177.1287994	0.34
179.1613617	3.20
180.9589691	0.23
183.1531219	0.70
185.214035	3.37
187.4470978	0.85
191.0883942	0.16
191.9993896	0.51
193.1541443	0.94
194.0407562	0.23
195.2245026	0.82
197.0725861	2.18
199.2146149	0.30
207.0503998	4.63
207.8163147	0.38
209.0422058	1.16
210.1458588	1.23
211.0973969	3.74
217.2428284	5.49
223.1972809	0.41
225.173645	7.95
226.3313599	0.63
232.4485474	1.46
235.1364136	22.15
238.0878906	8.95
253.0771942	100.00
254.170578	21.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.1229
Annotation	Luteolin 3'-methyl ether 4'-glucoside
Peak:m/z	Relative Intensity
227.1817780	0.02
260.9792480	0.03
286.2878418	0.06
288.2478027	0.07
301.1430359	0.03
302.3947754	0.08
303.4728699	0.02
313.1863403	0.38
314.2322998	1.18
315.2664185	0.03
325.0646973	0.46
326.2297668	1.46
336.9947510	0.09
338.0315247	0.08
341.3939514	0.06
342.1779175	0.10
343.1078491	3.64
344.2263794	11.95
345.1035156	0.01
352.4276428	0.04
364.4285889	0.03
366.3564758	0.03
367.6535950	1.73
368.2789612	5.61
369.1816406	0.07
372.9455566	0.12
374.2009583	1.15
379.2030334	0.05
380.0321045	0.01
382.2297668	0.47
386.3685303	0.03
392.3625793	0.01
397.0159912	0.77
398.1283569	16.40
399.2831726	0.17
403.2272034	0.02
404.6325989	0.03
410.1666565	3.72
410.7994385	0.04
428.1798401	24.55
429.2705688	0.04
446.1412659	100.00
447.2606506	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	669.1791
Annotation	Okanin 4-methyl ether 4'-O-(2''-O-caffeoyl-6''-O-acetylglucoside)
Peak:m/z	Relative Intensity
192.0337219	0.02
200.3744659	0.11
201.3786774	0.02
202.0770721	0.04
205.1729126	0.05
207.0101929	14.07
207.6483917	0.16
217.9422150	0.04
225.1689301	0.03
231.1961060	0.02
232.9880066	0.13
239.9278412	0.02
251.0735626	0.14
255.2072754	0.25
258.0558167	1.99
269.0287476	0.05
284.9293213	0.06
286.1406250	9.02
288.6790771	0.06
289.4605713	0.02
301.1585693	100.00
308.4035645	0.03
312.8681641	0.06
315.2452393	0.04
315.9894104	0.04
321.2269897	0.02
325.2319946	0.07
328.2062378	0.03
329.2414551	0.08
331.1954346	0.41
332.1645508	0.06
334.0731812	0.02
337.2146606	0.04
339.2584229	0.04
341.0274658	0.08
343.1404419	0.89
347.3057251	0.02
351.1840210	3.57
353.2197876	0.62
354.9235840	0.14
361.1849976	0.69
363.0696411	1.11
367.1149902	0.26
369.1624756	4.33
375.1063843	0.06
377.1602173	0.12
379.2252808	0.07
385.3074951	0.04
391.3312378	0.02
406.5151978	0.03
409.2294312	0.51
418.9454346	0.02
421.0446777	0.12
422.0568237	0.03
426.8358154	0.12
427.4505615	0.24
430.4434814	0.02
432.7320557	0.03
434.1649780	0.09
444.9794312	0.36
450.9951172	0.05
463.0581665	0.66
465.2332764	0.02
489.0765381	0.04
504.2579956	0.10
505.3598022	0.06
507.2377319	1.52
509.2435303	0.03
513.5960083	0.05
515.1899414	0.21
519.0805054	0.04
525.0612183	0.03
531.3280640	0.08
537.4983521	0.05
549.2584839	0.04
556.6436157	0.02
559.1842651	0.03
576.2825317	0.03
593.4010620	0.03
599.1887817	0.11
601.1074829	0.02
610.6793823	0.02
625.4440308	0.69
633.3688965	0.18
636.1721191	0.57
637.3783569	0.09
639.3510132	0.08
651.1411743	1.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.1347
Annotation	Unknow
Peak:m/z	Relative Intensity
175.9981537	0.10
179.2761536	0.07
181.2969818	0.33
189.0994568	0.08
190.0612183	0.13
192.0570374	0.06
192.9224396	0.13
193.8415222	0.78
195.0119171	0.43
197.0997009	0.56
198.3486786	0.41
199.3758850	0.15
200.0671387	0.47
202.2179565	0.35
202.9110565	0.19
204.1471252	0.08
205.1343384	0.23
208.9745941	0.21
213.2084503	0.05
214.0622406	0.09
215.0894928	0.50
216.0065308	1.09
217.2745209	0.62
221.3143158	0.29
222.9753723	0.15
224.2036133	0.10
225.8969727	0.36
227.2019501	0.26
228.1452637	0.09
230.0491638	0.55
231.0445251	0.47
231.8801727	0.29
235.1953430	0.23
237.2314758	0.42
238.8643188	0.52
240.0125885	0.47
241.0934296	0.61
242.1293335	0.78
243.1023102	1.56
244.1335754	0.21
244.8505859	0.05
246.2245789	0.12
247.0983582	0.20
248.2851562	0.17
249.0508118	0.10
254.2958527	0.73
254.9591827	0.18
256.0315552	0.08
257.2478638	0.33
258.1973877	0.44
259.0621338	3.56
260.1315918	0.13
261.0977783	0.13
263.8859253	0.06
264.6878357	0.14
267.2214355	0.11
267.8848267	0.09
269.2254639	0.78
270.0739746	5.18
271.0910034	2.46
272.5270081	0.22
273.1760254	0.59
274.1510010	0.47
275.2960815	0.40
281.1463318	2.01
283.0167847	2.19
284.1051941	0.48
285.1599731	8.56
286.0789185	6.43
287.1315918	20.79
288.1982422	1.72
289.2984009	0.09
296.2216187	0.32
299.1639404	1.24
300.1860962	0.91
301.1278076	17.04
302.0346069	14.90
303.2257385	2.22
308.2240295	0.32
311.0260620	1.26
312.0220337	0.66
313.1655884	0.58
315.0286560	8.42
316.1652832	3.44
317.1336670	1.90
318.1357422	0.14
319.1754150	3.29
323.2030029	0.30
325.1239624	0.64
326.2537231	0.26
327.1195068	0.73
329.0110779	20.92
330.0621948	100.00
331.1033325	28.24
332.0104980	0.50
339.9243164	0.40
340.9462891	0.11
342.3927002	0.41
343.3704224	6.35
344.2083740	15.78
345.1116333	42.43
345.9303589	2.12
353.2095337	0.11
353.9899902	0.22
355.3046875	0.80
356.8871460	0.39
358.0664673	0.25
359.0208130	0.59
360.1467896	0.17
364.0662231	0.16
367.0888672	0.18
371.1312866	0.25
373.2370605	0.91
385.0296021	0.54
386.0716553	0.07
387.2034912	0.70
389.3250122	0.06
395.1218872	0.19
403.2015381	0.59
411.1613159	0.14
417.2734375	0.23
419.2379761	0.05
422.9491577	0.37
438.2727051	0.22
440.7884521	0.18
443.4202271	0.94
445.1147461	0.61
447.2182617	0.21
453.0611572	0.16
457.2329102	0.58
459.2310181	0.18
461.3931274	0.52
462.8629150	0.35
464.4264526	0.31
465.5181885	0.86
471.1006470	0.31
473.4332886	0.20
475.2224731	8.43
476.1464233	0.34
479.2630005	0.13
483.0415649	0.18
486.3314209	0.06
487.3162842	0.07
489.2397461	4.78
490.4454346	0.08
492.0739136	0.40
494.1536865	0.10
507.2123413	6.38
524.3890991	0.50
525.2466431	0.26
531.3054810	0.32
533.3002930	0.09
555.4333496	0.28
563.7098389	0.07
564.9871216	0.23
567.2598877	0.33
569.2372437	0.17
570.9578857	0.34
579.1836548	0.12
581.3922729	0.64
583.2366943	1.54
589.8809814	0.11
590.6880493	0.14
595.2990723	0.47
596.7863159	0.90
599.3450317	1.22
600.4306030	0.13
608.7578125	1.88
609.5182495	0.05
612.1042480	43.31
613.2113037	3.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	475.2185
Annotation	Unknow
Peak:m/z	Relative Intensity
142.3922424	0.83
143.0092468	2.89
161.3189545	0.30
169.0727692	0.26
210.7726440	0.49
225.2361755	1.90
283.3126526	0.74
296.9669800	0.22
298.1071167	0.55
313.1827393	100.00
314.3123779	0.75
331.1758118	29.62
331.7843628	0.74
341.0726013	0.32
346.5973206	0.18
355.0073242	0.54
373.0863342	72.77
413.1025085	6.98
414.0738220	0.84
415.6073914	0.63
429.0415039	1.25
429.8355103	0.90
431.1605530	15.68
433.2676697	0.83
457.3164368	1.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	833.4275
Annotation	27-O-demethylrifabutin
Peak:m/z	Relative Intensity
238.9519348	0.04
464.3276367	0.21
476.4524536	0.70
482.4892578	0.11
492.5394897	0.12
494.5359497	0.69
498.6149292	0.11
499.2988892	0.14
503.9492188	0.08
511.4763794	0.53
512.2476196	0.20
513.3717651	0.67
523.2268677	0.10
546.5748291	0.06
547.6522217	0.15
556.7921753	0.16
558.8760376	0.07
559.5989380	0.03
561.5156860	0.13
567.7226562	0.07
571.5698242	0.28
573.8002319	0.17
575.2771606	0.21
578.5194092	0.75
579.5101929	0.71
580.4022827	0.20
589.4423828	0.38
590.7038574	0.05
591.4827881	0.10
595.4019775	0.47
602.3859863	0.18
607.2496338	1.88
608.4083862	0.18
611.8626099	0.19
616.3444214	0.15
617.6602783	0.39
621.4194946	0.09
622.9797363	0.39
624.1670532	0.50
625.0244751	0.40
630.3226929	0.14
632.6453247	0.06
635.3776245	0.32
637.6277466	0.17
640.4758911	0.12
643.4635620	0.12
646.3878784	0.43
649.4597168	0.20
650.1731567	0.24
654.7135620	0.19
659.3939819	0.03
663.3942871	0.06
665.5346069	0.11
667.7498169	0.17
671.4871216	0.12
672.4942017	0.78
675.0792847	0.24
676.4360962	0.82
677.7194214	0.08
680.5481567	0.55
682.8147583	0.12
686.7118530	0.22
690.2135620	0.04
691.8526001	2.08
692.4791870	7.31
693.3984985	4.33
699.2199097	0.28
700.5322876	0.83
701.3808594	0.12
702.3276978	0.16
706.2598267	0.34
706.9480591	0.04
708.3547363	0.95
709.6306763	0.28
711.4597778	0.04
714.2255859	0.41
714.8536987	0.03
715.6588745	0.24
719.5596924	4.45
720.4736938	8.70
721.4907227	3.71
734.1289062	0.10
735.2304688	0.52
736.4247437	0.76
737.6653442	0.39
742.5732422	0.23
746.3412476	0.23
748.4067993	3.08
749.5438232	0.66
755.4522705	0.19
758.5525513	0.16
759.2723389	0.11
762.6380005	0.87
764.6027222	0.28
771.5214233	0.27
772.5956421	0.21
776.6815796	0.67
778.5227661	0.09
787.5609741	0.95
788.7308350	0.65
789.6113281	3.97
790.5341187	1.35
798.5292969	0.08
805.5048218	100.00
806.4704590	40.52
807.2142944	0.10
815.4525146	11.09
816.5112915	3.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	725.3748
Annotation	Unknow
Peak:m/z	Relative Intensity
223.1891479	0.05
263.3047485	0.02
337.4598389	0.02
345.1045532	0.02
369.2915039	0.03
383.4957275	0.03
387.4000854	0.24
400.2166748	0.06
401.1000977	0.12
411.4874878	0.05
413.4719849	0.03
415.2723389	0.07
423.5372314	0.08
431.0148315	0.02
457.3009033	0.26
459.3068848	0.02
461.5589600	0.09
469.2617798	0.48
473.2982178	0.02
477.3135376	0.02
487.3087158	0.43
495.3795776	0.03
500.1089478	0.02
501.0881348	0.06
503.2365112	0.03
513.4945068	0.02
517.3564453	9.99
518.6607056	0.05
519.4463501	0.04
524.2592773	0.02
533.2188110	0.02
535.0584106	0.08
536.7562866	0.05
537.3859863	0.16
539.2528687	0.05
545.4037476	0.05
547.3197021	0.14
559.3366089	0.13
563.3182983	0.13
575.3105469	0.18
577.4151611	0.06
579.2679443	0.03
580.5574341	0.03
581.3578491	0.20
589.6793213	0.05
595.4593506	0.05
596.4808350	0.04
605.0991821	0.31
607.5136108	0.10
609.2962646	0.03
613.4911499	0.16
619.3483887	7.02
621.4210205	0.03
623.1365356	0.04
628.2384644	0.02
631.2717285	0.17
635.3144531	0.03
637.3391724	1.08
649.7952271	0.05
651.2395020	0.06
661.4798584	0.05
665.4260254	0.66
679.3991699	100.00
680.0210571	0.51
681.1395874	0.46
682.0015259	0.08
689.4212036	0.14
692.8351440	0.12
693.4586792	0.30
697.5096436	0.05
699.3943481	0.01
703.4678345	0.17
705.2193604	0.04
707.2909546	0.13
710.3729248	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.15
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
174.8024902	0.09
178.9708252	1.09
179.9630432	0.11
186.1951447	0.03
186.9865265	0.09
190.8328094	0.04
191.9863892	0.02
193.0955811	0.03
202.1969452	0.15
208.9242859	0.05
210.9552612	0.46
215.0727997	0.03
217.1814270	0.41
221.0268555	0.14
222.9213867	0.05
227.0915222	0.27
229.1014709	0.17
233.1388245	0.51
239.9445801	0.12
243.1504364	0.04
245.1029053	0.04
247.2229309	0.04
253.9479980	0.06
255.2234192	0.76
257.1394653	0.39
265.0742798	0.08
266.3361206	0.06
271.1578674	2.31
272.1687012	0.19
272.9350586	0.45
277.3100586	0.03
280.2494812	0.17
280.9800415	0.08
281.9729919	0.04
283.0748596	0.21
284.0068359	0.12
285.1785889	0.30
287.0445862	0.16
298.9307251	0.55
300.1304016	11.81
301.0606689	100.00
302.1779785	1.87
303.0561523	0.09
306.9387207	0.04
311.1015625	0.04
312.9340820	0.12
314.1291504	0.13
315.0058594	0.17
323.3077393	0.04
324.2836914	0.05
325.1658936	0.33
341.1625977	0.13
343.1215820	3.84
344.1464844	0.47
359.3076782	0.10
361.0725098	0.03
366.9880981	0.26
369.0057983	0.18
373.3147583	0.08
374.3621826	0.13
389.1143799	0.12
399.3455811	0.23
429.3023071	0.08
443.3226929	0.08
444.3542480	0.06
445.1574707	0.54
447.1560669	0.50
453.2615967	0.03
454.7634888	0.12
457.0769043	0.03
458.1693115	0.11
459.1918945	0.53
463.0735474	0.18
464.2322388	0.12
465.1862793	0.63
468.8330688	0.05
471.2238770	0.39
473.5545654	0.09
475.4548340	0.27
483.3100586	0.36
487.1792603	0.49
489.1749878	1.83
500.2822876	0.11
505.0315552	0.05
507.4559937	0.02
509.3024292	0.07
519.4353638	0.13
523.3003540	0.17
547.1885376	0.08
549.1491089	0.05
563.0906372	0.27
565.3041992	0.37
566.0322876	0.14
577.8715820	0.06
591.2712402	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Spinosin
Peak:m/z	Relative Intensity
177.1973267	0.01
178.9684448	0.03
183.1023407	0.07
213.1746674	0.03
217.1326599	0.02
227.0253906	0.06
238.9848938	0.06
241.2479706	0.02
256.3687134	0.03
257.1243286	0.16
273.1031494	0.06
286.3123779	0.07
299.5051270	0.02
301.0640259	1.13
302.9295349	0.79
303.5872192	0.01
307.0808105	0.11
327.1683350	0.06
339.1472168	0.05
343.5045166	0.06
345.2655640	0.11
351.0515137	0.19
355.1531372	0.09
361.0488281	0.30
362.8565063	0.02
365.6540527	0.04
369.2000732	0.23
373.0000000	0.03
375.1854248	0.02
377.0098877	0.01
379.0544434	0.03
381.3109131	0.05
383.1439819	0.03
384.8869019	0.03
393.0383301	0.38
398.9129028	0.04
405.3750000	0.04
411.2715454	0.02
412.2909546	0.03
417.1087036	0.13
423.2210693	0.85
427.2700195	0.07
429.2733765	0.55
435.2635498	0.45
437.2100830	0.05
439.1192017	0.10
441.1433716	0.42
441.7709351	0.04
443.2777710	0.04
445.1710205	0.25
446.2929077	0.18
447.1472778	0.72
447.8164673	0.04
453.1518555	0.23
455.3453979	0.08
459.2149658	0.54
460.8579712	0.02
463.1972656	2.27
471.1589355	26.53
471.8421631	0.04
477.0979614	0.06
487.3269653	0.11
489.2362061	10.84
495.2046509	2.21
498.8828125	0.02
500.1447144	0.02
501.1086426	0.06
503.5610962	0.26
504.4923096	0.04
505.2581177	0.15
507.2723389	0.02
509.1249390	0.06
511.1246948	0.06
513.2955933	5.51
519.2832642	0.04
525.2113037	7.83
534.7670288	0.04
537.1642456	4.15
538.2840576	0.03
539.4315186	0.13
543.1768799	12.72
546.3997192	0.03
547.2135620	0.08
549.2589722	0.13
555.1787720	6.60
555.8471069	0.03
565.5436401	0.01
571.9020386	0.10
573.1581421	24.58
573.7954102	0.28
581.4005737	0.03
591.2229614	100.00
599.7836914	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.39
Annotation	Combreglucoside
Peak:m/z	Relative Intensity
202.1334229	0.11
249.0988617	0.08
251.4200439	0.06
253.2079773	0.14
269.4170532	0.07
285.2944031	0.08
285.9293823	0.04
292.0755310	0.08
293.2280884	0.09
295.2002258	0.04
301.9913940	0.06
305.2565308	0.05
311.1478271	0.22
313.1840210	0.11
315.1186523	0.12
324.0502930	0.10
335.3898315	0.29
337.4332275	0.17
339.2835693	0.70
341.5151978	0.03
343.0554810	0.20
345.0776978	0.32
347.4962158	0.09
351.5357666	0.15
352.8500366	0.35
355.4387207	0.22
357.2583008	0.81
358.4628296	0.12
359.2394409	0.18
360.1242676	0.37
361.3026123	0.06
363.4732056	0.38
365.3416748	0.16
368.1900024	0.12
369.3912354	1.86
370.4759521	0.51
371.1986084	0.30
373.1647949	0.14
375.1980591	5.32
377.3599854	0.21
379.2295532	0.14
381.5120239	1.15
382.6197510	0.35
383.4375610	1.92
385.3412476	0.25
387.3977661	2.06
388.8236694	0.48
393.3479614	0.21
395.2688599	2.36
397.3145752	0.91
399.4260254	1.87
400.3923950	0.14
401.3801880	1.23
402.6828613	0.08
407.3074341	0.80
410.7052612	0.07
413.2593384	2.35
414.4418945	0.22
415.9567871	0.16
417.4207764	3.26
418.4047241	0.05
419.4140015	0.21
421.6206665	0.08
423.5930176	0.59
425.2899780	0.99
426.4923096	0.05
427.4533691	0.17
429.4573364	1.76
430.2927856	0.33
431.4842529	4.94
432.3920288	1.49
433.1967773	0.20
435.5086060	0.16
437.6486816	0.06
439.6540527	0.07
441.4867554	0.25
443.4188843	15.30
444.3814697	3.72
445.5247192	0.24
446.3967896	0.38
447.8220825	0.07
452.3301392	0.23
453.3313599	0.70
454.3660278	0.10
457.1042480	0.20
459.4344482	0.25
461.3654785	66.87
462.4700317	9.37
465.3413696	0.19
467.2790527	0.05
469.6991577	0.10
470.4210205	0.32
471.3420410	3.03
472.4356079	2.32
473.3115845	4.98
474.4277344	1.31
475.3472900	2.18
476.5344238	0.04
479.6002197	0.10
483.3705444	3.20
484.4882812	0.70
485.3891602	1.04
486.3389282	0.16
487.4904175	0.77
488.4899902	0.14
491.3211670	0.43
493.5425415	0.16
495.3304443	1.19
497.3063354	0.64
498.5278320	0.05
501.4421387	10.50
502.5192261	2.95
503.5012207	0.24
504.5660400	0.12
512.5021362	0.15
513.8107300	0.92
514.7399902	0.58
515.3720093	7.02
516.7129517	0.78
517.4163818	0.27
519.3576050	35.33
520.4519653	6.98
523.1663208	0.12
524.2430420	0.16
525.5700073	0.52
527.1904907	0.48
528.3727417	0.22
531.8170776	0.11
532.6130981	0.31
535.3856201	0.14
537.2640991	12.51
539.2479248	0.07
542.9152832	0.42
543.5755005	0.80
544.8162842	0.39
545.4402466	1.52
549.6188965	0.06
555.4765625	1.15
556.5061035	0.28
561.5437012	1.21
562.8046265	0.22
563.4118652	0.28
565.2395020	0.57
568.3638306	0.09
572.4169922	0.10
573.3932495	7.28
574.4657593	0.93
575.3725586	2.84
576.4748535	0.60
577.5737305	0.08
579.2670288	5.91
583.4050903	0.38
585.7277832	0.14
587.3428345	0.57
588.3150024	0.25
589.5795898	0.32
591.4152222	5.71
593.4246826	15.37
594.5291138	1.69
595.2560425	0.15
603.4763794	0.22
604.4328003	0.60
605.3967896	24.65
606.4359131	3.20
615.2666016	0.54
617.4479980	0.08
619.2063599	2.45
620.6599731	0.11
621.4738159	0.25
623.4030762	100.00
624.4541016	17.38
627.5668335	0.36
628.2128296	0.24
629.4157104	0.23
633.5388184	0.05
635.2741699	2.79
637.1393433	1.10
645.4038696	5.78
646.4331055	0.40
653.8405151	0.24
658.4843750	0.22
661.7056274	0.47
663.4102173	60.27
664.4740601	9.47
665.0918579	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1073.2751
Annotation	Unknow
Peak:m/z	Relative Intensity
300.0006409	0.06
305.0775757	0.20
315.1728516	2.39
317.2534790	0.08
357.1574097	0.17
449.1504517	0.17
463.3186035	0.05
464.2466125	0.03
477.2173157	2.07
519.0758057	1.35
519.7849121	0.03
533.0955811	0.18
559.2325439	0.82
561.2474365	0.27
567.3045654	0.07
601.3469238	0.04
603.0939941	0.20
609.1865234	0.06
615.1387939	0.04
621.1573486	8.97
621.7926025	0.02
623.1206055	37.65
623.7612305	0.12
645.2261353	0.05
663.1331177	2.70
665.3063965	0.32
675.1016846	0.09
703.3994141	0.87
765.1879883	0.45
771.0087280	0.10
783.2458496	0.20
784.5954590	1.11
785.1994629	4.51
813.2559814	0.08
825.0803223	0.05
827.1387939	2.84
827.7557373	0.01
850.9169922	0.43
867.1489258	0.61
869.0434570	0.93
895.3033447	0.05
909.2476807	0.11
910.4042969	0.32
911.2044678	0.05
915.0578613	0.04
918.6898193	0.17
927.5133057	0.09
929.1265869	100.00
929.8341064	0.09
971.1008301	10.13
993.6113281	0.05
1011.2391360	2.08
1013.2462160	0.09
1029.4213870	0.18
1055.0837400	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	439.1223
Annotation	Loquatoside
Peak:m/z	Relative Intensity
125.0801926	0.50
127.1711578	0.17
136.7953491	0.15
139.0751495	0.24
147.0330505	0.70
151.0106201	26.17
161.0962830	1.27
163.0280762	2.24
165.0090027	0.40
165.9490204	0.38
166.8717346	0.85
168.9441376	43.59
174.9496460	2.52
189.0433044	0.97
190.9515991	1.15
193.0423889	41.78
202.2219849	1.14
203.1636047	0.34
204.9802094	2.72
207.0263672	0.69
211.0797119	8.58
217.0657654	58.00
235.0981445	33.51
239.1907654	0.16
253.1158752	91.31
253.9187622	0.76
256.0778503	0.22
259.0957336	0.27
270.3446350	4.37
270.9893188	20.55
277.1879578	0.98
288.3369751	1.04
290.1858521	1.18
295.0813599	0.52
297.9458008	0.37
301.2728271	0.45
303.2901917	0.81
306.9321899	3.47
308.0186768	1.02
311.1496887	0.47
312.9031982	9.14
319.0322266	1.26
325.0679321	1.01
327.3356934	0.20
331.6500244	0.54
335.1606750	0.14
339.3146057	0.26
342.5634460	1.11
343.1719360	1.07
346.2191772	0.19
346.9634705	0.42
349.3441467	0.55
351.0539856	0.20
352.7944946	0.41
355.1427612	0.95
367.2416077	0.71
368.1021423	0.53
372.4205322	0.75
373.1404114	1.59
375.2716980	0.83
376.2996521	0.82
377.2178040	0.98
384.9864807	44.07
393.2736206	1.74
394.4244080	0.35
395.2156982	2.28
397.3940125	0.88
400.5599670	0.49
402.9297180	16.83
403.7382507	0.12
409.1007385	0.35
418.6207581	0.69
420.9920654	100.00
422.0840149	8.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2037
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
231.0630798	0.11
233.1500854	0.22
237.2086334	0.15
246.1006165	0.43
254.0449829	0.12
257.0822754	0.53
259.2466125	0.13
269.2391968	0.05
273.2528687	0.08
281.2233276	0.15
282.1971436	0.80
283.2295532	0.38
285.0795288	0.64
287.4658508	0.42
290.2672119	0.33
293.1547546	0.06
294.9938660	0.46
297.1630859	5.91
311.0158386	0.35
323.0980225	0.42
325.2148438	4.83
327.2417603	0.45
331.4261475	0.90
333.1915588	0.18
335.1250305	2.31
338.9951172	0.22
344.4017334	0.08
349.2092590	0.18
351.1052856	0.48
353.1197510	79.86
354.2398682	1.46
355.1516724	0.80
365.2010498	3.18
367.2158813	1.08
371.1684570	0.40
375.2299805	0.32
377.1751709	0.75
379.0818481	0.19
383.1158447	11.76
384.2378540	0.28
391.2218628	0.37
392.3070679	0.38
393.3406982	0.06
395.2169189	24.12
396.1211548	0.76
397.2615356	0.30
405.1066284	0.31
407.3867188	1.13
409.2460327	0.50
411.2800293	0.30
413.0651855	0.60
414.9566650	0.17
417.1238403	0.16
419.1638184	1.61
425.2174072	3.96
426.2658081	0.15
437.1627197	8.04
438.0740967	0.16
441.0455933	0.35
447.1293335	0.75
449.1900024	0.29
452.2620850	0.40
455.2094116	15.72
456.0496826	0.13
461.0957642	0.29
467.0698242	1.29
468.2946167	0.12
471.4503784	0.54
473.1588135	100.00
474.2656250	3.54
485.2096558	4.72
485.9486084	0.62
487.2862549	0.16
489.1146851	0.11
495.3126221	0.21
497.2695312	2.74
498.1233521	0.15
503.2567749	0.75
515.1507568	42.82
516.2238770	1.27
519.2826538	0.24
525.3389282	0.24
527.3439941	0.99
529.2009888	0.36
531.3043823	0.20
533.1535034	0.06
539.1620483	2.98
545.2353516	2.76
546.1953735	0.65
547.2818604	0.15
548.2090454	0.44
557.1845093	22.34
558.5053101	0.78
563.1925049	0.20
568.8862915	0.13
575.2178345	50.19
576.1343994	1.39
577.1373901	0.16
587.1803589	0.09
591.1546631	0.06
593.2047729	6.07
609.0227661	0.64
610.1890259	0.26
617.1066284	2.10
623.0601196	0.26
633.2196655	0.62
635.1853638	63.87
636.1383667	2.04
645.5537109	0.12
647.2088013	1.71
665.1565552	26.06
666.3448486	1.33
669.1064453	0.32
677.2742310	8.17
679.1973267	0.72
680.5291138	0.10
691.3973389	0.52
694.5917358	0.17
695.3296509	1.45
709.2803955	0.29
711.3833618	1.09
712.2742920	0.13
719.0816040	1.87
726.3388062	0.43
737.2716675	23.10
738.1719971	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
121.1142578	0.19
151.3179016	0.13
159.1299133	0.46
170.4402924	0.58
171.1441498	0.74
173.254776	0.80
185.2399902	0.38
187.0680389	0.45
195.2185516	0.54
197.0449371	0.17
199.1392975	0.74
199.9427948	0.48
201.1458435	1.88
203.0431213	0.59
213.1628723	1.81
215.3327026	1.68
217.1076965	0.57
227.2598572	0.15
229.2476196	2.68
231.058075	0.30
234.0514832	0.42
241.2451782	0.91
243.1433716	0.33
245.1279907	1.40
255.303772	1.36
257.322876	1.51
259.3291016	0.73
263.2107849	1.25
267.02948	0.23
269.3353882	1.22
271.4338989	0.90
273.2342834	0.11
283.2350769	0.11
285.2706909	3.06
285.9101868	0.40
295.2102051	0.69
297.3526001	2.39
299.2702332	2.76
301.2251892	0.26
305.2650757	0.28
311.3461304	1.78
313.2962646	2.38
314.3511658	0.42
315.6042175	0.27
321.2658081	0.82
323.3752747	9.25
325.4118652	0.15
328.5579834	0.16
337.1703491	0.47
339.249115	100.00
340.0765991	0.49
341.3531189	9.90
342.2087097	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.1164
Annotation	Unknow
Peak:m/z	Relative Intensity
174.8919220	0.65
200.8658295	0.70
216.8559570	0.59
230.7751465	0.30
234.8331604	0.14
261.0543213	4.09
275.0750732	10.89
277.0496826	2.19
283.9685669	0.15
288.9883423	0.41
301.1614685	0.61
303.0064392	2.27
318.9380493	0.30
320.9606323	89.49
337.0162354	0.82
348.0145264	0.17
363.0140381	2.12
363.8187256	0.21
365.9639282	0.25
372.5654297	0.17
374.7981567	0.10
378.1846924	1.39
379.1959229	10.30
379.8240967	0.34
380.7744141	0.83
389.1388550	0.21
393.1641235	0.76
395.0309448	1.48
397.1674194	0.39
401.4791260	0.14
404.9286499	0.46
407.1497803	1.06
411.2640381	0.20
413.0275269	0.22
415.8114624	0.30
416.8952026	0.12
422.9888306	3.15
424.8997192	67.15
425.6684570	0.07
429.0989990	0.62
440.9537964	1.10
452.9646606	1.05
464.3704834	0.38
465.1358032	1.72
466.9887085	1.71
480.4475098	0.27
483.0000000	100.00
483.6762085	0.40
496.9258423	0.35
499.0516968	0.24
500.9630737	0.25
527.0622559	0.73
569.0386353	4.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.3223
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
149.0911865	0.03
165.8615417	0.38
173.2710571	0.11
178.0749359	0.26
184.0389709	34.77
201.2704163	0.05
203.2454376	0.27
233.3633423	0.24
257.9683838	1.33
260.3472290	0.11
265.3062744	0.03
286.1340332	0.54
287.2790222	0.12
288.5167847	0.05
301.3132324	0.22
308.1278687	0.14
309.0039062	0.05
334.2580566	0.15
335.3736572	0.65
340.0487061	0.07
353.2409058	0.25
358.3718872	0.08
377.5518188	0.04
390.8045654	0.08
414.3325195	0.36
431.4143677	0.26
432.1343384	0.14
441.1322021	0.35
449.4836426	0.21
462.4181519	0.18
469.3115234	0.08
470.2127075	0.06
471.9215698	0.14
475.2269287	0.15
482.8814087	0.10
487.2582397	0.10
490.8903198	0.35
492.1621094	0.19
500.3544312	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.1034
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
108.0856094	0.14
112.8424988	0.25
120.9349670	0.08
123.1668854	0.16
125.0572968	0.18
132.1136780	0.35
133.9440613	5.57
134.5644226	0.11
142.9459839	0.16
147.0502014	0.05
148.9414368	0.56
151.2133179	0.08
160.0482025	4.58
161.3959961	0.07
162.9863281	0.09
174.9901733	42.32
175.6988373	0.47
178.0092468	1.02
188.1002502	0.37
189.2150879	0.03
191.1732178	2.15
192.9866638	100.00
202.1267700	1.00
203.1956177	0.66
207.0653992	1.07
209.1695251	0.75
217.0923157	69.54
218.9627686	0.19
221.2722778	0.10
223.0609741	0.04
232.3240662	0.07
235.0715637	10.95
247.0954895	1.72
257.0968018	0.14
259.0569458	1.71
265.0983276	7.46
277.0850220	0.59
295.1420288	7.26
311.9676208	0.33
319.3402100	0.06
337.0733032	2.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1225
Annotation	Marein
Peak:m/z	Relative Intensity
139.0961914	0.11
157.1009216	0.16
162.998703	0.38
195.2038727	0.15
202.9797668	0.19
207.1796875	0.17
210.9585876	0.17
219.1378632	0.48
245.4386597	0.14
247.0811462	0.11
249.2593994	0.57
250.2479553	0.25
253.4277344	0.77
260.4828491	0.64
261.1032715	0.96
269.8511963	0.26
279.0967712	0.78
287.3580933	0.83
289.0740356	100.00
289.7507935	0.07
295.3036804	0.10
296.9614868	3.72
301.0906677	1.32
304.4224854	0.48
307.0602112	0.46
312.9854736	2.02
315.2811279	0.66
319.8914185	0.17
323.3431396	0.08
325.211792	0.28
331.0782471	5.41
333.1055298	1.54
336.0955811	0.15
337.2923584	0.67
338.1997681	0.43
344.3755493	0.49
351.1155701	0.49
355.1851196	7.04
363.2792664	0.31
367.4745178	0.10
385.1542053	12.15
391.467804	0.36
393.0262146	0.10
393.9451904	0.16
396.5796814	1.63
397.1987	7.94
398.288147	0.48
409.2584534	0.17
415.0889587	6.63
421.3110352	0.76
431.2101135	0.12
433.1838989	40.35
434.5700378	0.48
442.0462341	0.55
453.7984009	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	614.74
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9687195	0.17
231.0711517	0.23
241.2116699	0.05
242.0882874	0.09
255.1613464	0.10
274.5464783	0.21
280.5433350	0.14
288.8473511	0.19
290.1467285	0.05
299.0918579	0.10
307.2629395	0.20
314.4287109	0.10
317.0992432	1.03
326.0206909	0.18
343.0778809	0.38
355.0775757	0.26
360.9769287	1.31
379.1909790	0.10
401.0621948	0.21
404.3926392	1.12
405.0124512	12.23
407.3623047	0.23
410.0440674	0.36
422.9535522	100.00
423.5880127	0.20
432.8798218	0.10
434.0347900	0.13
452.1209717	0.33
453.0211182	0.30
465.3052979	0.24
470.5706787	0.14
481.4206543	0.31
483.2310181	0.18
484.0496216	0.18
485.3976440	0.19
516.2028809	0.23
532.1017456	0.05
532.8482056	0.16
539.4784546	0.22
543.1195679	0.13
553.6555786	0.30
554.9937744	0.38
567.1198120	0.13
582.0004272	0.07
582.7913208	0.07
595.9292603	0.62
596.8560181	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	452.2781
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
153.0103760	0.14
196.1345520	2.16
214.0399170	1.10
255.2339783	100.00
255.8452759	0.41
390.0616760	0.02
391.3130798	0.33
408.9020386	0.02
425.3895569	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	179.056
Annotation	D-Hamamelose
Peak:m/z	Relative Intensity
58.7362022	0.35
68.8483353	0.06
71.0189056	0.85
72.9537811	0.33
74.9716721	21.31
80.9226913	4.31
86.9362793	3.65
89.0707703	0.50
97.0146942	0.72
98.8825531	15.67
102.9408722	0.03
106.5679626	0.09
113.1024017	0.22
115.0367584	0.34
117.2143250	0.12
119.1166229	0.13
125.0072174	9.93
130.9356537	0.86
132.4854431	0.18
135.2955780	0.04
142.9563751	36.55
148.8917389	0.36
159.1773529	0.06
160.9607697	100.00
179.1403656	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	781.2762
Annotation	Unknow
Peak:m/z	Relative Intensity
219.1248627	0.13
226.2231750	0.10
258.3769531	0.44
259.3201294	0.14
261.1044312	0.12
267.0429993	0.40
274.1143799	1.21
276.1204834	0.73
290.7770081	0.22
292.3060303	0.16
297.1714478	0.56
302.1169739	2.76
312.8724060	0.70
315.0907288	0.35
327.2309570	0.14
330.1268311	0.08
332.3080139	0.13
342.3596191	0.43
344.3753662	0.14
345.3513794	0.36
348.0238647	0.26
353.1743164	0.26
354.3543396	0.53
358.1308594	0.16
361.0401611	0.48
362.1113892	0.09
376.8484497	0.30
377.8691406	0.10
390.0816040	0.40
400.3875122	0.24
405.5533447	0.16
413.2885132	0.22
414.2617188	0.11
415.3909912	1.23
422.3236084	0.07
424.0971069	0.15
428.1401978	0.11
429.2805176	0.20
432.3330078	0.11
440.1235352	4.94
442.1513672	2.29
444.2290649	0.50
446.2990112	0.76
452.2633667	5.53
458.3480225	1.42
464.1376953	0.08
466.3179932	0.59
468.2197266	1.22
470.1807861	79.04
471.0634766	1.08
472.1865845	1.10
472.8259277	0.17
475.7163086	0.06
482.1761475	0.30
484.4822388	0.12
486.1165161	1.71
488.2445679	16.27
490.3328247	0.45
494.2741699	5.47
496.1448975	0.26
498.4460449	0.57
500.1781006	0.99
506.2183228	0.29
508.2432861	1.10
510.2292480	0.71
512.1553345	11.96
513.4416504	0.25
518.3357544	1.11
519.0379028	0.57
519.8856201	0.20
520.4942017	0.20
522.4582520	0.61
524.2072754	32.02
525.7742310	0.75
530.2447510	0.49
531.2265015	0.45
536.2677612	20.97
538.2691040	0.38
540.0023193	0.35
542.1732178	9.77
544.1881714	0.38
546.4107056	1.72
548.2091675	5.25
549.1578979	0.46
554.1921997	36.91
556.4071655	0.33
559.3010864	0.26
560.1831055	0.63
562.2775879	0.33
563.3654175	0.35
564.3152466	0.66
566.1908569	22.70
567.3181763	0.50
572.2439575	72.53
573.3151245	0.55
574.1252441	0.21
578.2005615	2.47
579.2651367	0.19
580.2645874	0.78
582.2274780	0.47
584.1513062	32.57
584.8383179	0.08
586.5191040	0.40
588.0640259	1.36
590.1622925	100.00
590.7922974	1.55
591.4103394	0.12
593.4749146	0.18
596.2227783	2.99
600.0874634	0.91
602.2296753	24.40
602.8485718	0.27
604.4246826	0.54
606.1148071	0.22
608.2178345	24.60
609.7013550	0.46
614.1600342	9.68
619.6021118	0.81
620.2411499	10.97
620.8554077	0.37
622.5411377	0.33
626.2128296	9.49
627.1486206	0.81
631.6211548	0.56
632.2448120	10.90
633.3717651	0.15
638.1725464	18.29
638.9262085	0.13
640.5272217	0.24
644.4022827	2.77
649.6342163	3.37
650.2753296	28.35
651.0509033	0.06
656.2266846	14.99
657.4501343	0.24
658.6563721	0.24
661.2150269	0.49
662.3323364	0.43
668.2559204	51.49
669.1745605	0.53
674.3389282	0.29
686.2249756	57.88
687.3350220	0.27
691.6089478	0.82
696.1110840	0.21
704.1247559	48.53
704.7993164	0.42
705.5380249	0.16
708.1610718	1.58
722.2476807	25.57
753.2721558	0.28
761.2280884	0.20
763.1389771	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.09
Annotation	Lactulose
Peak:m/z	Relative Intensity
119.0705414	0.05
143.0153198	0.08
161.0891724	0.02
179.0494537	1.48
197.0708923	0.52
215.1098175	8.08
281.0168457	0.16
341.1265869	100.00
341.7551880	0.08
387.7764587	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.083
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
120.8692474	1.39
128.8826752	9.49
133.1350098	0.15
144.9668579	0.06
146.9427490	0.09
155.2349243	0.03
161.0466156	0.78
163.2604218	0.04
173.0241699	17.38
180.0951385	0.07
185.0042419	0.13
189.0251770	6.12
214.8371887	0.19
232.9644165	1.13
251.1112366	17.15
259.0130920	0.41
261.7395630	0.09
275.3791504	0.03
277.0520630	3.89
286.2496338	0.04
295.0345459	100.00
297.5174561	0.07
329.3109131	0.15
344.9379883	0.24
352.3557739	0.11
355.2506104	0.50
357.1026611	0.03
371.4519043	0.05
372.3497620	0.04
373.1146851	0.43
398.4010620	0.34
399.0571899	1.28
401.0196838	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	709.1617
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
221.0793610	0.01
267.1613770	0.03
311.3851318	0.01
317.2716064	0.01
343.5222168	0.02
369.4688110	0.02
395.0915527	0.04
401.0316162	0.05
402.2686157	0.04
416.3811646	0.03
443.5569458	0.01
461.2155151	0.01
463.5564575	0.04
467.1230469	0.05
487.2695923	0.08
503.2352905	0.39
520.2419434	0.03
529.5439453	0.02
533.2257080	0.01
545.2238159	0.16
547.0922241	0.02
557.1107788	0.01
559.2811890	0.01
560.4251709	0.01
562.3096924	0.03
563.4233398	0.01
565.3071899	0.01
575.2543335	0.14
605.3496704	0.01
617.0618286	0.04
623.2604370	28.83
647.3359375	0.09
649.1574097	0.14
662.0756836	0.02
665.2092285	100.00
665.8524780	0.26
690.9306030	0.51
691.6117554	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	551.0143
Annotation	Myricatin
Peak:m/z	Relative Intensity
170.9271698	0.19
187.9575195	0.55
215.0371704	0.14
226.9530792	0.07
228.8247986	0.34
230.0095215	0.10
231.1164246	0.13
237.1234741	0.18
258.1286621	0.17
271.0703125	0.24
281.0018005	0.58
287.0659790	0.26
298.0812378	0.43
315.0208740	4.41
327.0837402	3.81
332.9064941	0.72
341.0039673	0.58
343.0301514	0.06
356.7810669	0.19
359.0329590	100.00
360.0853882	2.24
360.9201050	1.12
406.6386719	0.09
445.7333984	0.10
447.1943359	0.60
460.9638062	0.09
462.9586182	0.68
506.9605103	4.06
533.0258789	1.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	489.2104
Annotation	Terretonin E
Peak:m/z	Relative Intensity
145.0427246	0.04
159.1229706	0.13
160.9206848	0.09
167.3370056	0.02
171.2099457	0.08
173.1189270	0.08
173.8359375	0.13
174.8839722	0.48
177.0306396	0.04
178.9395447	0.06
182.2690887	0.04
185.1961975	0.04
189.0108337	0.15
190.9578857	0.03
199.0120239	0.14
201.0526123	0.08
205.0025482	0.08
209.2879333	0.05
210.8695374	0.05
213.1512451	0.06
215.2245178	0.25
219.1092987	0.13
220.8981171	0.08
222.8926697	0.08
225.2730560	0.18
227.0168915	0.12
231.1386108	0.13
233.2867432	0.17
234.9856262	0.06
239.0232697	0.09
241.2235718	0.07
245.2456207	0.06
246.0339050	0.03
247.1614227	0.04
249.3251343	0.04
257.3190918	0.15
258.7797546	0.12
259.3867493	0.16
261.0777283	0.67
263.1855774	0.19
265.3699036	0.01
269.3274231	0.10
273.2901917	0.11
274.8590088	0.04
277.3449402	0.24
278.6038208	0.05
279.2192688	0.11
280.0728455	0.05
281.0926208	0.07
283.2946167	0.15
285.0868835	0.11
287.0101624	0.24
289.3766479	0.09
291.2922974	0.27
293.0319824	0.16
295.0849609	0.13
297.4402771	0.04
298.3770752	0.02
299.2436218	0.26
301.2524719	0.08
303.1008911	0.02
305.2172241	0.18
306.2875977	0.11
307.1497803	0.31
309.2335205	0.16
311.1588135	0.08
315.1334839	0.02
316.2116699	0.02
319.1321106	1.07
321.1582642	0.21
323.2818604	0.23
325.5292664	0.21
327.0662231	0.16
328.9575806	0.11
330.9804993	0.22
333.1613464	0.46
335.2560425	3.00
337.2706299	0.51
339.1611328	0.85
341.1805420	0.47
343.0987244	0.06
345.0278625	0.66
347.2457886	0.78
349.2276611	0.67
351.2619019	1.40
353.2387085	0.06
355.1933289	2.81
357.1577759	0.64
359.3186035	0.53
363.2567749	0.16
365.2301025	2.64
366.3580627	0.10
367.3278198	1.57
369.2661743	0.28
373.2877808	0.44
375.0615540	0.87
375.6766968	0.02
377.1781311	0.38
378.6086731	0.07
381.1958923	0.05
383.1574402	13.86
385.4522705	0.04
389.1075134	0.19
391.2760925	2.54
393.2147217	1.66
395.1366577	0.23
397.0748596	0.21
401.1947327	8.51
403.5486145	0.06
407.0857849	0.59
409.2643738	8.57
411.1446838	3.71
413.2658997	0.70
417.1694641	1.39
423.6748962	0.05
425.1330872	0.92
427.2073669	7.76
428.7936401	0.45
429.4180908	0.74
431.1493225	0.02
435.1827087	3.48
443.2270813	1.09
444.2686768	0.09
445.1007996	0.05
446.4969788	0.05
447.2010498	0.07
453.1859436	5.11
453.8365173	0.07
471.2350769	100.00
472.2084656	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.1015
Annotation	Starch acetate
Peak:m/z	Relative Intensity
96.7780914	0.21
99.0094986	1.50
101.0190353	0.18
102.8961563	0.55
108.8197021	5.64
121.9040527	0.05
126.9236679	42.99
140.2418823	0.06
144.9085083	9.75
150.0574036	0.12
153.0854187	0.13
155.0645142	0.12
158.0444946	0.19
161.0245514	0.20
162.9112244	10.24
164.9976044	0.17
166.3009796	0.70
166.9823456	0.16
169.0936584	0.29
172.9497375	0.04
178.7399597	0.19
181.0774231	0.18
182.6942902	0.11
183.7934265	0.17
185.1535034	0.36
187.0325928	28.53
191.1630707	0.27
203.3343201	0.19
204.9629211	100.00
209.0251770	0.51
215.2191162	0.17
217.0788574	0.05
219.0525513	0.14
227.1404419	0.31
229.0011902	0.34
232.0231628	0.08
233.0258484	0.08
234.8550415	1.68
241.0687866	0.08
242.9044800	0.96
244.4911194	0.97
245.2679443	0.45
247.0871277	0.10
249.2955017	0.13
251.0593567	0.19
252.9393311	1.61
256.2194824	0.05
257.3082886	0.25
261.3103943	0.18
263.0397339	0.06
271.0211792	22.98
275.3953857	0.26
279.0314331	0.17
288.9900513	79.91
289.8008423	0.77
290.4288330	0.10
292.1565857	0.47
292.7775574	0.50
298.1396484	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	550.2628
Annotation	Rzedowskin A
Peak:m/z	Relative Intensity
156.9684448	0.20
165.1643677	0.68
167.2643433	0.47
169.1760406	0.39
171.0210724	0.90
172.9929504	0.33
175.1784058	0.15
180.8032837	0.13
183.0713196	0.62
189.0812073	0.10
197.0294189	0.06
199.0454407	0.45
201.1303101	0.20
209.3125000	0.27
213.0777435	0.23
215.3235474	0.30
221.1952515	0.35
227.1651001	0.39
228.9911499	3.09
235.0082703	0.15
241.0109253	0.74
243.2799988	0.50
249.1338806	2.80
251.1954193	0.60
252.3985901	0.17
253.0535889	0.34
254.9114075	0.33
257.2828369	0.56
258.9800415	0.14
261.1419678	1.13
267.0887146	0.07
269.1076050	0.58
269.8942871	0.08
270.8458252	1.00
283.2204590	0.60
284.9505005	0.64
291.1639404	0.30
295.1379089	0.46
297.1673279	1.53
298.1021729	0.10
299.2039795	0.23
300.9813232	0.65
302.2692261	0.34
303.2172546	0.42
305.1879272	1.08
308.9926758	0.38
313.2351074	0.22
315.2474976	0.89
317.0018921	0.20
318.2520752	0.30
321.3055420	0.81
323.1718140	0.18
325.2060547	0.08
326.1923218	0.21
329.3749390	1.17
331.2338867	1.33
335.2039185	0.11
340.9595947	0.12
343.2631226	0.09
344.2878418	0.38
347.2612915	0.13
349.3441162	0.54
351.1156006	0.74
353.2529907	1.28
355.0023804	0.76
357.4966431	0.46
359.0311279	1.35
362.7820435	0.34
365.0759277	0.69
367.2222900	2.27
369.2367554	4.25
370.9183960	0.21
372.8453369	0.39
375.3171997	0.40
377.0712891	1.22
379.0984497	0.44
380.1491089	0.12
381.1753540	0.95
383.0695190	1.06
385.0183105	1.20
385.6287842	0.70
387.4011230	0.48
390.6268311	0.34
391.3197021	0.32
393.2019653	5.41
395.2276611	1.43
401.1743774	0.87
409.3068237	2.03
410.1210327	0.17
411.2846069	14.75
413.0890503	5.54
415.4545288	0.64
419.1690674	2.61
420.5091553	0.25
425.2614136	0.11
427.2935791	3.94
429.3063965	3.58
431.1477051	2.14
435.3607178	0.09
436.6046143	0.15
437.3197021	10.24
445.1867676	3.17
453.1082764	1.47
455.2407837	30.04
469.0902100	0.96
469.6986084	0.13
471.2843018	4.64
473.2112427	11.12
479.1926880	1.17
486.4688110	0.22
487.4071045	1.38
489.0364380	2.41
491.1796875	1.60
497.1783447	5.35
504.6054077	1.04
505.2199707	1.47
506.4760132	0.49
510.6879272	0.29
511.4855957	0.21
515.1152344	29.72
515.7676392	0.49
518.7088013	0.07
533.1804810	100.00
533.8342896	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	778.7313
Annotation	Unknow
Peak:m/z	Relative Intensity
222.2055359	0.29
233.1430969	0.54
242.1559143	0.65
260.6942749	0.20
263.0366821	1.91
271.9267273	0.93
272.6045532	0.15
273.3581848	0.39
275.1958618	0.10
283.5953674	2.03
292.8215942	7.74
301.6366577	0.20
305.3411865	0.20
321.1333618	2.23
323.2172852	1.17
333.0966187	0.21
335.1992188	0.69
339.2030640	0.08
344.1848145	3.40
345.4653931	0.39
346.5481567	0.95
349.2111816	0.32
350.8823242	0.22
353.2131348	3.65
357.2331848	0.29
362.0806885	0.89
362.9948730	1.79
363.7326050	0.35
364.6069031	2.29
373.6363525	14.56
374.3449097	2.99
378.8576660	0.08
381.1266479	0.42
382.8771362	0.52
385.7256470	0.15
393.3875732	0.28
395.0067139	0.63
402.3513184	0.44
404.0907593	1.81
404.8563232	0.82
416.5264893	1.49
418.1345215	0.24
423.0832520	2.18
423.9884644	0.24
425.0833740	2.27
425.8925781	0.74
433.1426392	0.72
434.2183838	8.53
435.3985596	0.47
441.0385132	1.59
445.7283936	8.16
446.5170898	0.07
453.2303467	3.24
454.7735596	45.52
455.8643188	0.16
459.4656372	0.37
464.6912842	0.17
476.6273193	0.16
481.2982178	0.15
482.9949951	1.35
485.2620239	5.62
496.8773804	1.23
504.7988281	0.13
506.2822876	1.47
507.2038574	0.42
508.1160889	0.17
510.9145508	0.96
512.8749390	1.21
514.0563965	0.51
515.3021851	3.25
515.9101562	0.62
523.4180908	0.21
524.8289185	2.06
526.9431152	15.16
528.0472412	0.21
535.8565674	65.13
536.8853149	1.18
538.1278687	0.16
548.8046265	0.35
550.1447144	0.21
551.2542725	0.58
555.9408569	0.44
561.0836792	1.55
562.7376099	0.32
566.8546753	2.56
568.5133667	0.15
569.4436035	0.42
572.7598267	1.66
578.1139526	0.92
583.9911499	0.16
585.1817017	6.75
586.1702271	0.43
587.5065308	7.24
596.3665161	5.98
597.0209351	0.48
600.2142944	2.80
603.0542603	0.27
604.0811768	0.33
607.7606812	3.65
608.3895264	0.76
615.0293579	1.93
617.0202026	34.95
620.3780518	0.85
624.3279419	0.93
626.4698486	0.95
627.5562744	0.85
632.9434204	0.93
637.7216797	0.27
638.9019775	0.09
645.1238403	1.07
647.3804321	6.71
648.3023682	0.13
651.7773438	0.33
657.2316284	0.55
668.2247925	4.06
668.8722534	3.43
671.4771118	0.41
677.4549561	54.28
679.1280518	0.09
680.1921387	1.51
685.3671265	1.01
687.1636963	2.72
688.7496948	14.19
689.3618774	2.20
691.1734009	0.12
693.1708984	0.69
697.9450073	100.00
698.8694458	1.26
699.5654907	0.96
701.9233398	0.38
703.5442505	0.07
705.1898804	2.85
705.9868164	0.94
711.1830444	0.97
713.1387329	0.52
717.0126343	0.36
718.9406738	4.54
720.1287231	0.37
724.9428711	0.81
728.3911743	13.31
729.2050171	0.36
734.4172363	0.32
739.8069458	1.83
740.5718384	0.94
747.2083130	12.74
748.1785278	2.41
749.6162720	1.04
760.9697266	1.14
769.7946167	11.66
770.4660034	1.86
789.3070679	0.60
792.4386597	0.46
806.7122192	0.23
807.3963013	0.26
811.3014526	0.10
821.3997803	0.27
829.1317749	8.28
830.1500244	3.68
831.2215576	1.01
832.1611938	0.08
837.1048584	0.36
849.2713623	0.36
867.2798462	0.09
872.9741211	0.11
878.8869019	0.15
889.9582520	0.26
891.1195679	3.83
892.4677124	0.27
909.1567383	6.97
910.1989136	4.15
911.4448242	1.17
912.2161255	0.14
950.8331909	0.18
973.2069702	0.17
982.1145020	0.17
991.0246582	0.51
992.4880981	0.16
993.6004028	0.35
994.7949219	0.20
998.8256836	0.08
1009.1923830	1.36
1011.2536620	0.31
1024.4145510	0.14
1027.7282710	0.07
1035.9589840	0.18
1041.1258540	0.29
1053.2756350	0.16
1054.3649900	0.30
1066.0731200	0.68
1071.1883540	4.56
1072.0736080	0.80
1073.5325930	0.36
1154.2495120	0.35
1174.3796390	0.72
1184.9599610	0.55
1197.0572510	0.39
1214.9125980	0.54
1233.2630620	1.30
1234.2750240	0.71
1376.3691410	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.0831
Annotation	Unknow
Peak:m/z	Relative Intensity
142.8144836	0.07
144.8101501	0.15
149.1473236	0.13
160.9463654	0.77
173.0961304	0.04
175.1241608	0.11
179.0756226	1.09
191.0078125	0.57
203.0507812	0.06
220.9171143	0.68
223.1562195	0.15
232.8874359	0.08
259.0475159	0.04
264.7443848	4.86
267.3639526	0.10
277.2626343	0.36
281.1509399	0.11
295.1215820	0.25
311.1445618	0.03
323.0785522	0.25
334.6353455	0.13
341.1408691	100.00
342.1089172	0.06
355.1712646	0.08
362.1470947	0.14
369.0950317	0.08
395.2179565	0.11
397.2735291	0.04
428.9216003	0.14
431.4272461	0.15
438.4027405	1.34
439.1059875	5.76
440.5729370	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	195.0664
Annotation	4-Hydroxy-6-methyl-3-(1-oxobutyl)-2H-pyran-2-one
Peak:m/z	Relative Intensity
81.1312866	0.04
85.2070160	0.02
121.0998535	0.07
136.1015778	1.10
149.0611725	0.09
150.9944153	100.00
151.8331299	0.06
159.1235962	0.02
162.1445770	0.24
165.2477417	0.04
166.8892975	0.06
176.9572906	31.30
180.0598450	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	345.0826
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
120.2664795	0.28
137.0088806	4.82
160.8896179	0.04
167.5037689	0.14
207.1007385	0.32
220.6062317	0.05
223.1187744	0.06
230.3602905	0.05
237.1116638	0.08
238.8728943	0.05
241.1214294	0.06
249.1510315	0.07
270.6342773	0.13
277.9810486	0.04
281.1381226	0.23
282.9513550	0.16
299.0952759	100.00
301.1051025	0.30
301.7469177	0.15
303.1841431	0.08
326.8663330	0.19
328.1754761	0.17
330.0911255	3.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.2
Annotation	Clinacoside B
Peak:m/z	Relative Intensity
195.1817169	1.27
201.3812256	1.56
263.1142578	1.51
281.0316772	0.48
287.2462158	3.64
289.0967407	0.99
290.9617310	0.59
297.0172119	1.10
303.1484375	24.35
306.7297668	0.78
308.1619873	1.90
310.9304810	0.24
318.0773926	0.69
327.1764526	0.44
329.2978516	0.36
345.1570435	4.93
369.3002930	1.98
383.3029785	0.19
395.1645508	1.50
399.1719360	1.42
411.2560425	0.24
413.2836914	17.29
425.1836548	0.51
430.9868774	19.50
431.6428223	1.36
437.6135254	0.27
438.7671509	1.36
443.3602295	3.63
447.0645752	14.66
449.1760254	57.29
454.0955811	1.32
455.3827515	1.40
456.0026855	0.44
465.0275879	26.04
466.9810791	1.41
473.1516113	19.29
478.9600220	6.68
485.0521851	0.44
487.4803467	0.35
489.1688843	5.41
491.1638794	11.40
492.1306152	0.82
513.4136353	0.44
515.1980591	9.74
520.4592896	0.66
524.1896973	0.34
527.0839233	8.36
539.0781250	3.19
544.9476929	9.72
545.5562134	1.95
549.2895508	0.53
557.1287231	10.26
575.1066895	27.00
593.1765747	100.00
594.3157349	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.1038
Annotation	Apigenin 7-(2''-acetyl-6''-methylglucuronide)
Peak:m/z	Relative Intensity
144.9368896	0.69
146.9332275	1.60
148.9396667	0.26
158.8857574	0.12
162.0178223	0.10
163.0207520	7.43
172.0132904	0.71
172.9926758	7.10
187.2392273	1.27
190.9754944	11.42
203.0116882	0.26
207.1141052	0.56
209.0538483	0.13
213.0812683	0.30
215.2303009	0.39
231.1336975	4.18
287.1546631	0.07
293.1714783	6.01
296.3019409	0.43
301.2423401	0.23
305.3651733	0.11
310.3492432	0.54
319.0388794	0.15
322.4934692	0.35
323.2512817	0.43
323.9785461	0.44
337.0387878	100.00
337.7691956	0.25
339.2892456	0.20
340.2119141	0.07
341.6013184	2.12
342.3692322	1.98
351.0561523	0.18
353.1957092	3.47
354.2887878	17.97
355.1894226	39.20
364.1029968	1.10
365.1372070	1.09
371.1390991	0.41
372.2032166	3.88
385.0594788	0.22
393.2674255	0.36
395.1635742	1.16
426.6080627	0.31
438.3487549	0.23
439.3555298	1.36
450.7345581	0.79
451.6763306	0.60
453.1620483	0.56
454.9439087	0.22
457.2217102	0.50
465.1982727	7.60
470.6032410	1.01
471.3257751	7.02
483.1512146	25.51
483.8445129	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.2261
Annotation	Rzedowskin A
Peak:m/z	Relative Intensity
144.9829865	0.47
145.9538269	0.17
147.9789886	0.66
148.9176941	0.09
149.8874359	0.62
151.3358765	0.06
152.0806274	0.26
152.8226929	0.10
154.1082001	0.35
155.0413208	0.20
157.0491180	0.55
158.0190887	0.63
159.2136383	0.67
160.1399536	0.61
161.0750427	9.64
162.0537720	3.75
163.0072784	0.67
163.8742371	0.12
165.0849915	0.49
166.2275238	0.74
166.8612518	0.06
168.8789825	0.39
170.2232056	0.09
171.1392517	1.51
172.1259003	0.87
173.0589905	0.21
174.0992126	0.09
175.1432648	2.00
176.1016235	1.19
177.1123657	0.63
178.2254944	0.19
179.0142517	0.32
180.2642059	0.39
181.1181641	0.38
182.1473694	0.07
183.2740936	0.51
184.3690186	0.77
185.1614380	0.83
186.3180847	2.35
187.0875244	3.13
188.0471802	3.78
189.0960999	0.86
189.9962463	1.57
191.0628662	0.24
192.3224487	0.24
192.9907532	0.18
194.8546448	1.05
196.0538330	0.39
197.1279602	1.14
198.0829773	0.65
199.1481323	0.47
200.1447754	1.14
201.2336884	0.16
201.9528503	0.86
203.0166168	1.60
204.1044617	0.50
205.0492249	0.44
206.1357880	0.62
207.1683960	0.25
208.0753479	0.29
209.1664429	0.60
210.0542603	0.47
211.0130005	0.82
211.9935303	1.07
213.1586609	3.34
214.1556702	3.48
215.0509949	8.52
216.2402496	5.01
217.1346741	0.95
218.4495544	0.74
219.1897278	0.84
219.9123993	0.64
221.1387939	0.30
223.1258240	1.21
224.1766510	0.49
225.0854645	1.57
226.3511505	0.76
227.2007446	1.94
228.2370300	1.05
229.0899048	0.84
230.4158020	2.39
231.1644287	3.36
232.2609253	2.72
233.1948395	0.24
235.2823029	0.47
236.2881927	0.23
237.0756073	0.17
238.1892395	0.74
239.1313477	1.17
240.4431000	0.68
241.2439270	0.81
242.2681122	1.73
243.2070312	1.19
244.0364838	2.19
245.1728973	2.81
246.2902832	1.42
247.0135498	0.58
248.1295319	0.95
249.2133179	0.86
250.2505035	1.06
251.2005005	1.02
252.2144775	1.45
253.4216156	0.83
254.2026672	0.72
255.1073914	1.47
256.0492249	1.82
257.4481201	1.12
259.0703430	1.23
260.0614624	1.77
261.2529297	0.74
262.1567993	1.57
263.3753052	1.79
264.2359009	5.08
265.2695312	0.71
266.1605835	0.74
267.1387329	0.98
268.4169922	1.10
269.2366943	0.90
270.1582031	3.28
271.0418091	0.62
272.1778564	0.92
273.1740723	0.22
274.0195923	1.52
275.2734985	0.32
276.1805420	1.31
277.0308533	0.45
278.2255249	0.84
279.3051758	1.18
280.2432556	3.81
281.0778198	0.51
282.0864258	2.78
283.2602539	0.75
284.2012024	1.11
285.2332153	1.04
286.2535400	1.77
287.2521973	1.24
288.0762939	1.43
289.1358643	2.78
290.1939697	2.55
292.0432434	0.60
293.1043701	0.17
294.2714233	2.03
295.1877441	1.39
296.0992432	2.49
297.1516113	1.14
298.2750854	2.83
299.5213013	1.02
300.3419800	0.85
301.5743408	0.33
302.3101807	1.02
303.0794067	2.04
304.0864258	2.29
305.2622070	1.08
306.3018188	1.54
307.2805176	1.01
308.2866821	3.02
309.1503906	0.22
310.1365967	1.72
310.9359131	0.77
312.2116699	0.75
313.3404541	0.69
314.2932129	1.48
315.3070679	1.42
316.2098389	1.33
317.1778564	1.17
318.5300293	1.51
319.4048462	0.14
320.1820679	1.35
321.1654053	2.17
322.2500610	5.81
323.4182739	1.55
324.1610718	3.17
325.1743164	2.44
326.1135254	1.43
327.1808472	0.34
328.4005127	0.74
329.4941406	0.48
330.3739624	2.32
331.2268066	0.71
332.2749634	3.85
333.2606201	1.16
334.2206421	3.27
335.2014160	0.21
336.2434082	3.20
338.1544800	1.48
339.2780762	0.82
340.2993164	2.73
341.3808594	0.81
342.2756958	1.31
343.1183472	1.04
344.1462402	1.78
345.2386475	0.46
346.3487549	0.71
347.1560059	0.28
348.1731567	2.42
349.2042236	1.41
350.2548828	8.04
351.0671387	1.23
352.2459717	4.49
354.4783325	0.55
355.2252197	0.47
356.1467285	1.81
357.1362915	0.20
358.2029419	1.16
359.1499023	0.69
360.3024292	2.70
361.4191895	0.56
362.2664185	0.74
363.2152710	2.12
364.2581787	7.51
365.1216431	0.74
366.1804810	6.16
367.3432007	1.93
368.2067871	13.20
369.5050049	4.29
370.4169922	5.73
372.2744141	0.05
373.2239990	1.08
374.1978149	4.86
375.2586060	2.19
376.2689819	11.09
377.3261719	2.06
378.2600098	6.99
379.2055054	0.29
380.2614746	1.65
381.3427734	1.75
382.3058472	4.62
382.9447021	0.27
384.1804199	2.93
385.1393433	0.40
386.2119751	1.41
390.2381592	0.20
392.0662231	19.12
393.4103394	9.27
394.2402954	46.41
395.0693359	2.11
396.1454468	4.42
397.0614014	0.38
398.4984131	0.49
399.2055054	0.25
401.3581543	0.58
402.3427124	9.42
403.0355835	0.10
404.1565552	0.11
406.2365112	0.18
407.1356201	0.21
408.2590332	1.04
408.9907227	1.67
410.1621704	16.81
411.2021484	13.80
412.2537231	100.00
413.1782227	2.20
414.1714478	4.42
419.1485596	2.66
420.2229614	18.92
420.8674927	0.23
425.2728882	0.38
426.2727661	0.91
428.2860107	2.69
430.2205811	0.26
431.5595703	0.10
434.3986206	0.32
436.1405640	0.26
437.2720337	5.57
438.2481689	33.39
438.9340820	0.12
442.3439331	0.69
444.4750366	0.13
448.5054321	0.20
450.2767334	0.05
452.1602783	2.79
453.2253418	0.06
454.3403931	2.72
455.6956787	7.70
456.3154297	32.08
462.2125854	0.74
466.9310303	0.94
468.2164307	0.38
469.3132324	2.68
470.2608032	29.08
472.2095337	26.71
474.0610962	2.93
474.8812866	0.30
479.1931152	0.14
480.2045288	4.36
481.1334839	0.24
484.7174072	0.50
486.4617920	0.14
488.1415405	3.11
488.7697144	0.14
497.6994019	2.69
498.3251953	14.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	533.2003
Annotation	Hymenoside A
Peak:m/z	Relative Intensity
151.0366669	0.07
152.0222473	0.08
152.9700012	0.19
155.1239929	0.05
155.9408112	0.17
159.1443939	0.09
162.7955170	0.60
166.9992676	21.36
170.3887939	0.09
172.0578918	0.54
173.2373352	0.15
174.9864655	2.50
176.3711700	0.48
177.0340271	1.61
181.1485138	0.23
185.2712860	0.19
187.0126648	3.95
189.1477356	1.10
191.0380249	6.06
199.0825806	4.85
201.1282654	0.06
205.0263367	1.49
207.9858551	0.20
209.1075439	4.11
210.7617493	0.52
215.2715912	0.15
217.0928345	3.21
220.9927826	0.45
223.9492493	0.10
225.1092224	0.24
231.2723083	0.16
237.4891052	0.11
252.9139404	0.09
261.1332397	0.39
263.2870483	0.09
267.2623291	0.35
277.4529724	0.32
279.1227722	0.13
280.8531494	0.14
285.2295837	0.29
287.2084656	0.24
289.0181885	0.90
290.8764648	0.20
292.0429688	0.06
294.3049316	0.07
297.3011475	0.26
302.8602905	0.40
307.0713501	0.25
309.2563477	1.46
311.2133789	0.89
313.2757568	0.31
316.7734985	0.10
319.5296631	0.16
321.2021484	8.64
322.3292236	0.50
325.0960693	0.40
326.1156616	0.46
329.1440430	0.13
331.2449951	0.24
338.1422119	0.08
339.0606079	0.10
341.1820068	35.59
347.5090332	0.18
353.1037598	100.00
355.2331543	0.62
356.4015503	0.10
357.2114258	0.19
365.5385132	0.09
367.3418579	0.24
369.5057983	0.47
370.9499512	37.76
371.6810303	0.14
375.2080078	0.14
379.0371704	0.14
381.4309692	0.25
385.0835571	0.20
393.0188599	0.12
394.2344360	0.17
395.3138428	0.16
397.4466553	0.11
400.9193726	0.98
407.3267822	0.22
409.6435547	0.89
410.8858643	0.07
425.3045654	0.71
434.3851318	0.07
435.4755249	0.19
441.8239746	0.29
443.3195190	0.11
447.2254028	0.67
449.6831665	0.07
454.3222656	0.14
455.4471436	0.15
457.2706299	0.05
458.4210815	0.42
460.3435059	0.12
461.8527832	0.10
466.3704834	0.16
467.2750244	0.49
469.9998779	0.23
471.4542236	0.38
473.2086792	1.30
476.9990845	0.43
479.2581177	0.24
487.3430786	0.53
487.9636841	0.27
489.2440796	1.06
497.4314575	0.72
504.8531494	0.09
514.1730347	0.22
515.2403564	6.09
516.3895874	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.17
Annotation	Piperacillin
Peak:m/z	Relative Intensity
162.0372925	100.00
180.9828186	0.68
243.2954102	0.09
284.0804138	0.07
289.0373535	0.20
296.4214172	0.32
306.2341919	0.29
321.1157837	0.12
321.8307495	0.74
324.2517700	0.30
327.9934692	0.36
337.1847534	0.33
338.0239868	0.35
338.7673950	0.07
342.2655640	0.15
344.2383423	0.25
371.0332642	0.46
372.2411499	1.53
383.0594482	0.23
386.9053955	0.59
389.9124146	0.71
398.2359619	0.16
403.0958862	0.40
408.1675415	0.19
442.7324829	0.13
457.3902588	0.14
473.7412720	0.79
481.9170532	0.18
483.5200195	0.27
487.4761353	0.17
500.7443848	0.53
501.4581909	0.07
518.2412109	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	571.16
Annotation	Tenuiphenone B
Peak:m/z	Relative Intensity
160.3522491	0.03
165.1021576	0.02
168.8769684	0.04
169.9805756	1.15
171.8612976	0.02
181.0453491	0.05
185.7979736	0.07
187.9869080	51.73
188.8185272	0.15
193.1491089	0.14
204.9946899	100.00
205.9002991	0.06
206.9194794	0.06
217.0971832	0.22
223.1461639	0.02
235.1233368	0.05
240.7954102	0.07
243.8586273	0.02
252.9382019	0.07
264.8811035	0.09
271.1336060	0.02
273.4017334	0.03
283.0039062	0.35
295.5407715	0.04
299.1468506	0.01
300.7566528	0.11
304.4513550	0.01
305.0568848	0.03
306.8488159	0.03
308.8749390	0.03
312.9528198	0.03
319.2659302	0.02
322.0451660	0.03
323.4199829	0.06
329.3530884	0.05
343.0775146	0.03
349.3417969	0.05
355.2633057	0.08
367.0109863	0.14
378.9211426	0.02
385.0076904	0.13
390.9958496	0.33
404.4042358	0.03
406.4815063	0.01
408.3109741	0.15
409.2944336	0.13
410.1829224	0.01
414.9947510	0.01
423.1442871	0.03
426.6181641	0.14
433.4140015	0.01
444.6677856	0.11
445.2777100	0.18
456.3379517	0.03
466.2636108	0.02
468.4421997	0.02
481.0225220	0.09
498.7330322	0.08
501.2445679	0.02
505.3890991	0.03
511.1138306	0.20
512.6314697	0.01
516.1196899	0.07
516.9330444	0.10
522.3748169	0.02
525.3893433	0.01
527.2062378	0.04
535.1981812	0.09
537.3883667	0.02
553.1016235	1.42
554.5036011	0.07
561.9617310	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1561
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
169.0807495	0.05
172.9289856	0.01
183.2802734	0.04
197.119873	0.10
199.1243286	0.01
201.1868896	0.02
224.1199951	0.08
225.2139282	0.31
226.1040649	0.03
227.1310272	0.08
240.199707	0.03
241.2286987	0.01
263.9295959	0.02
269.0455627	100.00
271.2379456	0.13
283.1018066	0.03
293.0055542	0.01
307.0863037	0.02
310.9958496	0.20
323.1121216	0.05
325.2677002	0.03
331.1028442	0.05
334.8622437	0.03
337.2922363	0.02
339.1743774	0.01
347.9713135	0.01
353	0.13
372.9901733	0.10
385.2498169	0.03
395.5108032	0.06
413.1790771	0.28
415.0080566	0.23
423.25177	0.02
427.2241211	0.03
431.0206299	0.02
433.1709595	0.67
475.0271606	0.26
487.9514771	0.03
489.7059937	0.04
501.5026245	0.01
515.5459595	0.04
530.3609009	0.03
531.319519	0.17
533.2744141	0.04
541.3005981	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.0933
Annotation	Acacetin 7-glucuronide
Peak:m/z	Relative Intensity
129.0265961	1.80
145.1548004	0.45
146.9878235	0.42
158.7262878	0.55
163.1153259	3.67
172.9259644	20.18
175.3025360	0.52
187.1944580	0.17
189.0281982	4.39
191.0614929	5.08
213.2351685	0.99
219.1829834	0.20
221.2980804	0.39
231.0443420	0.74
233.0316162	0.62
251.0798035	9.07
254.9872742	0.20
259.1783142	0.17
276.8832397	1.72
293.1651001	2.20
295.0562744	100.00
303.2525940	0.91
313.1507874	35.98
319.2968140	0.23
337.0848389	40.58
397.0200500	0.66
399.3111267	0.82
440.8648682	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	225.08
Annotation	5-(3',4',5'-Trihydroxyphenyl)-gamma-valerolactone
Peak:m/z	Relative Intensity
76.9789734	0.01
84.9276733	0.02
94.9993744	0.03
104.8276062	0.02
110.9304352	0.05
120.9644623	0.04
122.9951477	0.02
131.1699066	0.02
137.1797638	0.02
146.9879303	0.03
149.1200562	0.01
150.9331512	0.02
154.9683990	0.02
161.3230133	0.04
163.9369202	0.02
165.2401581	0.05
167.2007599	0.06
176.0020294	0.01
179.2053070	0.08
181.0463409	0.17
181.8767853	0.01
183.0861359	0.17
189.0240173	0.04
192.8539581	0.01
195.0821075	0.07
197.0167389	0.12
198.0332184	0.02
207.0058289	100.00
207.8619537	0.00
210.1877747	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1613
Annotation	Safflomin A
Peak:m/z	Relative Intensity
171.1068878	0.06
175.0628357	1.02
177.0076294	3.45
179.1559448	0.36
180.8980560	0.08
184.8100433	0.08
187.0236511	0.12
188.9724121	0.18
193.0265045	0.10
197.8105164	0.62
198.9907837	1.45
200.9814301	0.38
210.9853363	0.11
213.0077209	0.44
214.9573364	0.17
216.1204376	0.04
216.9753265	2.13
218.0683289	0.15
219.0635071	0.10
222.8316498	0.11
224.2967987	0.05
228.2160339	0.13
231.4116364	0.08
239.0271912	0.17
239.9552612	0.08
241.0268097	4.65
241.9727936	0.27
242.9801025	1.64
257.0562134	0.73
259.0691833	1.34
265.0180054	0.17
266.7531738	0.09
275.1541443	1.22
285.0845947	79.92
298.9600830	0.34
301.1666870	0.24
303.0479736	100.00
313.1427002	0.29
326.8504639	0.30
337.2781372	0.05
341.0674438	0.04
357.2161865	0.11
369.3261108	0.14
371.1685791	0.51
381.3847656	0.31
399.1774902	0.04
401.2026367	0.46
431.1507568	0.34
449.2532959	0.12
459.1376343	1.78
461.1171875	1.15
469.2425537	0.34
473.5078735	0.11
485.3258057	0.11
487.0927124	8.21
489.1721802	1.06
491.1503906	0.76
501.1987915	0.87
503.1469116	0.37
565.2234497	0.07
583.3385620	12.25
593.2003784	13.30
602.1209106	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.2737
Annotation	Broussonetine M
Peak:m/z	Relative Intensity
101.9805145	0.02
103.1657867	0.02
104.8582458	0.21
107.0536575	0.23
108.9666748	0.34
110.0151978	0.06
111.0354614	0.17
115.1314392	0.06
116.9377975	0.26
118.9604416	0.47
120.0727463	0.10
121.0410767	1.79
122.8735657	0.23
125.0065994	0.23
126.1363602	0.14
126.9529572	0.02
127.6580353	0.02
129.0310059	0.05
131.0613251	0.69
133.0139771	0.67
134.1601868	0.05
135.1168671	1.62
136.8448792	0.06
137.9818420	0.03
139.0167999	0.14
140.9656982	0.03
142.9043884	0.10
144.8767548	0.76
147.0912018	0.99
148.1492767	0.04
149.0864258	0.39
149.9485779	0.11
151.0262451	0.31
152.1820374	0.13
153.0665131	0.44
154.8812866	0.05
157.0372925	0.42
158.9030457	0.71
161.0834961	0.61
163.0266418	0.18
165.1268311	0.28
171.1223450	1.12
173.1386261	0.26
175.1489563	0.31
177.0228424	0.21
179.1515961	0.06
180.1759186	0.03
181.2409668	0.09
183.1318970	0.06
184.0783386	0.01
185.1050262	0.82
187.1168365	0.54
189.1886139	0.56
191.2507324	0.13
195.0357361	0.03
199.1645660	0.51
201.2188416	0.68
202.2703552	0.02
203.0457153	0.76
205.1048431	0.12
206.0964203	0.02
207.1835938	0.13
212.3623047	0.06
213.2149353	0.27
214.4098511	0.33
215.1990662	0.21
217.2354736	1.84
219.1861267	0.07
221.0922852	0.19
224.1646118	0.02
227.1075439	0.08
229.3587036	0.70
230.7173157	0.08
231.3607483	0.31
233.3312073	0.10
234.3875732	0.13
235.2754822	0.33
237.3103638	0.03
238.3289490	0.07
239.1838074	0.23
241.2240295	1.37
242.2097778	0.03
247.2338257	0.18
248.3052673	0.07
250.1462097	0.17
252.2473145	0.21
253.2452393	0.49
258.2578735	0.95
259.2439575	0.75
264.3098145	0.73
265.4315186	0.14
266.4059448	0.01
268.1704712	0.26
276.2509766	4.57
277.1593933	0.53
282.3876038	0.74
286.3540955	0.09
289.2083130	0.05
294.2172852	10.78
298.7915955	0.07
304.0346375	0.05
304.9597168	0.02
306.8428955	0.05
312.3145447	24.28
313.3084412	0.03
314.1393433	0.02
326.2648926	0.11
330.2705994	100.00
331.1290894	0.17
348.9922180	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	689.2294
Annotation	Unknow
Peak:m/z	Relative Intensity
194.0852203	0.05
206.4261169	0.06
210.9416504	0.02
221.0243835	0.03
238.1531525	0.03
241.0393982	0.09
261.2445374	0.10
263.2012634	0.05
273.1914062	0.07
275.4038696	0.05
281.2002258	0.03
295.0295715	0.04
313.1719360	0.16
328.2737427	0.02
330.2872314	0.02
331.1785889	0.03
338.1805420	0.02
348.5617065	0.02
351.2753906	0.03
357.3234863	0.03
370.5317993	0.04
372.1861572	0.48
373.0705566	0.08
383.1912842	0.38
385.1297607	0.04
399.1051025	0.04
415.1704102	0.07
422.3856201	0.07
425.0194702	0.08
439.2305298	0.15
441.2851562	0.35
444.8570557	0.05
447.1968384	0.06
460.2692261	0.06
463.3029175	0.04
465.2827148	0.28
469.3616943	0.04
475.2438354	0.01
477.3112793	0.03
478.0802612	0.05
483.2302246	100.00
483.8858032	0.25
489.2249756	0.04
491.1156616	0.06
497.0430298	0.17
503.1387939	0.13
507.3726807	0.68
508.2043457	0.02
509.2932129	0.33
510.0842896	0.04
515.3021240	0.04
518.2114868	0.18
519.0744019	0.02
525.0564575	0.47
526.2626343	0.12
527.3107300	0.73
531.6303101	0.04
536.3677979	0.11
541.5656128	0.05
545.2799072	0.27
550.6878662	0.10
552.3031616	0.06
557.0396118	0.07
559.2982788	0.10
568.2921143	0.08
569.3109131	0.06
570.5263062	0.15
571.6517944	0.07
572.3844604	0.05
576.5398560	0.07
577.3029175	0.23
580.2344360	0.03
581.5137329	0.12
584.9501343	0.68
587.3263550	0.07
589.2505493	0.02
594.3256226	0.04
595.3560791	0.13
597.2260132	0.06
599.1953735	0.13
600.1486206	0.04
602.2289429	0.07
603.3065796	0.02
606.1885376	0.21
607.7144165	0.17
609.4957886	0.15
614.2080078	0.08
614.9779663	0.11
622.9829712	0.05
624.2300415	0.57
625.2636719	0.96
626.5194702	0.23
627.2324829	0.02
640.3807983	0.63
641.3345337	0.47
643.1345825	0.17
644.0680542	0.06
645.0644531	1.23
652.2316284	0.05
653.1506348	0.44
658.3892212	0.07
659.4773560	0.38
670.2554932	1.01
671.2466431	0.74
674.1201782	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	319.0669
Annotation	Unknow
Peak:m/z	Relative Intensity
100.8511429	0.06
113.0650864	0.21
114.9767761	2.30
128.7732239	0.08
138.8000183	0.08
143.0084229	0.08
149.2401581	0.04
155.1303406	0.04
156.8719177	0.77
160.9594574	3.65
175.0351562	100.00
192.9601593	0.03
194.1658936	0.20
203.9409790	0.11
217.0939636	3.99
228.2228088	0.20
231.3442383	0.04
232.6627808	0.10
247.2270508	0.07
253.3582764	0.04
257.0468445	0.33
265.1987000	0.06
273.1498718	0.07
274.9566956	0.24
275.9003296	0.27
283.1346130	0.21
288.1955566	0.13
288.8988953	0.16
301.1501465	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	480.307
Annotation	PE(18:1(9Z)/0:0)
Peak:m/z	Relative Intensity
150.9523468	0.71
172.9307251	1.30
192.179718	1.60
198.0206299	0.56
215.9421234	0.93
227.4290161	0.32
283.4176636	0.22
296.2638855	3.10
308.4935913	0.65
314.4246521	0.64
317.1625366	1.59
318.0510559	2.25
319.3381653	0.53
328.1589355	1.06
330.1980286	0.66
335.1981812	1.40
338.1504517	1.53
339.2819824	100.00
343.1141968	0.51
353.1959839	0.54
356.4787903	0.27
378.4700623	0.78
383.0530396	0.90
391.2479553	1.42
419.0375366	5.29
431.4471436	0.40
437.0690613	0.45
462.2245789	93.76
463.143158	2.74
464.3554077	1.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1694
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
207.0971832	0.01
230.5827789	0.01
259.1606445	0.05
266.1074829	0.17
271.1431274	0.36
273.2634277	0.02
283.071167	0.25
291.2175903	0.03
295.0341187	0.08
313.0806885	4.33
318.2018433	0.16
325.4287109	0.12
331.189209	0.17
337.1190186	1.21
355.1772461	0.05
363.1688232	0.06
367.0683594	2.62
367.6798096	0.01
369.2110596	0.02
375.0275879	0.09
379.2205811	1.09
387.0145874	0.12
393.2379761	0.01
396.1087036	0.01
397.1439209	1.71
399.2960815	0.12
407.1708374	0.06
415.1957397	15.22
417.0401611	0.19
429.1951294	0.01
433.1115112	100.00
439.3091431	0.03
441.3250122	0.03
447.8091431	0.07
457.0142822	0.08
459.2042236	0.12
461.59729	0.05
465.2823486	0.02
474.4926147	0.05
475.3255005	0.07
477.2659912	0.11
483.2619019	0.06
494.9761353	0.06
495.6146851	0.04
498.0568237	0.09
500.828125	0.01
507.3908081	0.05
513.1860962	0.07
516.1369629	0.05
517.0777588	0.06
525.2554932	0.34
543.1744995	0.83
561.1660767	2.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.067
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
110.8471832	0.22
128.9522400	2.55
147.0237427	3.07
163.0497742	0.59
172.9649200	1.99
181.1374512	0.05
187.0607605	0.08
190.9747620	100.00
192.9806213	0.04
209.0901642	36.12
243.3652954	0.07
265.5230103	0.04
311.2119141	0.04
327.4304504	0.10
337.0310974	11.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
171.8346558	0.20
174.2460632	1.42
196.0860901	0.60
198.9155579	0.17
201.0196991	1.35
215.0796204	0.35
227.0227203	0.41
237.4944458	0.34
242.0831604	0.40
255.1276245	0.50
257.0930786	1.05
267.9621277	0.71
273.4022522	0.36
283.2200623	1.73
285.3959351	0.21
286.1930542	1.40
299.0944824	2.52
301.0827026	100.00
302.0899353	0.98
327.0799561	0.26
341.0914917	0.35
343.3764038	0.76
349.2877197	0.46
355.4796143	1.06
369.2033081	1.10
385.0428467	0.54
398.9874878	6.39
429.1308594	0.21
441.2463379	1.49
463.1054688	0.75
465.3513184	0.41
470.987854	1.00
489.1463013	10.04
492.0979614	0.29
501.2474976	1.02
513.1262207	0.86
515.3200684	1.01
519.3060913	2.14
548.1398926	0.46
548.7758179	1.30
549.4474487	0.17
551.7567749	0.37
554.9213257	0.60
556.2445068	0.34
564.0753784	0.53
565.3162842	0.62
591.1212769	4.31
592.1616211	0.52
609.6290283	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	573.1739
Annotation	Fesumtuorin D
Peak:m/z	Relative Intensity
163.3845520	0.18
171.0301971	1.29
172.9510040	1.27
174.0048828	0.14
175.0368958	1.98
176.8680420	0.26
177.8544006	0.06
181.9727173	0.07
183.1485901	0.42
184.0839844	0.40
185.0932465	0.94
186.9884949	0.30
194.9483948	1.61
196.1278381	0.17
197.2910614	0.28
199.0791626	6.85
200.0072632	0.07
201.0289612	3.60
202.9713745	100.00
203.7422791	0.19
205.0853729	0.11
206.9337921	0.07
211.1219025	0.14
213.1529694	0.53
215.1312103	0.49
223.1191254	1.08
225.1177216	0.49
227.0693054	6.59
229.1191711	0.14
231.4427795	0.10
236.1495819	0.07
237.2275848	0.04
239.0085754	0.85
241.1248932	7.74
243.1228638	1.54
246.9563293	0.29
249.2048035	0.26
251.1842651	1.45
253.2185364	0.17
262.0086670	0.25
269.0592041	49.90
270.2470398	0.16
271.2763367	0.33
277.2545776	0.12
279.2305603	0.07
281.1964417	0.07
284.2676392	0.80
287.1160278	95.40
293.0995483	0.51
301.0430908	0.10
302.2845459	0.19
303.3459167	0.24
307.2140503	0.35
309.0155640	0.32
311.2298889	0.25
325.2056885	0.09
327.0804443	0.13
335.2521362	1.07
339.0295410	0.20
342.4122925	0.19
353.2490234	1.21
368.0934448	0.27
371.1828613	6.78
375.2180786	0.04
381.0784302	0.08
383.0610962	0.43
392.5397339	0.10
410.1049805	0.35
455.1734619	0.13
456.4091187	0.14
458.1454468	0.19
471.3605347	0.30
474.6101685	0.27
481.0709229	0.11
483.3111572	0.36
485.0182495	0.30
488.9913330	0.21
490.3021240	0.11
494.1283569	0.22
505.2388306	0.22
514.5940552	0.29
519.4212036	0.10
523.3181152	0.29
529.2727051	0.08
531.7467651	0.31
537.0480347	0.40
541.7378540	0.06
546.0928345	0.11
553.6846313	0.07
554.8670044	2.59
555.7593994	0.35
558.2600708	0.11
564.2433472	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	420.2002
Annotation	Renealtin A
Peak:m/z	Relative Intensity
123.1284637	0.06
135.1621246	0.07
155.0254669	0.02
159.1266937	0.03
160.9900208	0.02
172.9169006	0.10
179.1920929	0.02
197.1294556	0.02
201.1027222	7.14
203.0061035	0.15
213.8641205	0.02
214.8561401	0.07
217.0781708	0.47
219.1190948	0.03
221.0594635	0.06
229.1004486	0.03
231.1202698	0.13
241.1050720	0.08
243.1399841	0.11
255.1375427	0.02
257.3866272	0.09
258.4349365	0.04
267.1420593	0.05
268.1389160	0.03
269.2954712	0.15
270.5622559	0.04
275.0392761	0.04
283.0781860	0.09
285.0594788	8.85
285.6674500	0.02
287.0737305	0.64
292.6553955	0.05
293.8715820	0.06
302.4527283	6.55
303.0775757	16.10
305.1652222	0.05
306.3764343	0.02
311.2149963	0.02
312.3327332	0.01
314.1504822	0.09
317.9232788	0.02
333.2106628	0.08
334.8440552	0.04
342.6772766	0.03
343.6296692	0.12
350.2812805	0.05
351.0777283	0.17
352.9564514	3.10
355.4240723	0.04
357.6232605	0.05
360.2037964	0.11
362.6156311	0.07
368.8433838	0.09
370.9848328	100.00
372.4092712	0.03
374.3299866	0.01
379.1159973	0.03
385.2468262	0.02
386.1585083	0.04
388.2306213	2.65
388.9828186	35.00
398.4905090	0.13
402.2735291	0.33
403.3539429	0.07
405.0555115	0.01
406.2216187	0.14
410.3398132	0.12
411.1712646	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	554.2928
Annotation	Unknow
Peak:m/z	Relative Intensity
156.0495758	18.17
165.9676819	2.45
168.9342194	0.56
170.1214142	0.47
175.8979492	0.22
186.9633942	1.15
187.8951416	2.15
188.9483490	3.68
198.0059509	0.40
201.0476379	0.52
205.0739136	7.06
206.0422211	5.04
207.3039246	0.42
210.1730042	0.79
221.7965698	0.13
223.0626221	1.22
224.1399689	1.34
231.1627960	1.71
234.1530762	2.66
240.1353760	10.40
242.8803864	0.16
251.2294617	23.01
258.0047913	15.97
267.9225159	0.29
269.2167969	75.09
286.0134277	100.00
286.6944580	1.27
287.9955444	0.92
289.0112915	0.22
294.4157715	0.26
325.3576660	0.59
331.2496338	1.40
332.1547241	1.11
333.6519775	0.08
342.4368286	0.24
347.9754639	0.11
349.0474243	0.87
349.9272461	0.27
353.2489014	0.78
356.2975464	0.65
363.1392822	0.24
368.2756348	2.98
370.5258789	2.57
371.2067261	4.70
374.3256836	0.53
379.3161621	0.53
381.0105591	2.35
390.2920532	0.56
392.3588257	0.21
399.1472778	45.16
400.1089478	0.20
407.3559570	0.21
415.4632568	0.28
425.3344116	14.81
430.6610718	0.22
433.1848145	1.41
450.9094849	0.36
459.5794067	1.12
462.3557739	0.14
472.6777344	0.10
482.4793091	0.22
492.4066162	0.28
494.2313232	0.87
500.3401489	0.40
506.3779907	0.93
508.3866577	8.12
509.7422485	1.24
512.5141602	0.09
518.4369507	7.37
526.3732300	0.37
536.2676392	83.05
537.2571411	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	409.1502
Annotation	8beta-Propionyloxy-10beta-hydroxyhirsutinolide-13-O-acetate
Peak:m/z	Relative Intensity
117.0754776	3.53
119.0137939	3.47
143.0992432	1.22
144.9425659	100.00
145.9931641	0.26
157.0814056	0.09
163.0479431	38.76
180.9528503	0.12
187.0396423	4.32
189.2394867	0.26
199.0380859	0.19
203.1492310	0.05
204.9229126	0.05
221.1147308	0.60
229.0279541	0.10
231.1377258	0.24
247.2722168	0.55
289.0213013	1.54
323.0364075	0.06
339.3483276	0.10
349.2673340	5.05
363.2178650	0.39
365.3110962	0.27
366.5987854	0.33
367.2522278	4.84
367.8869019	0.10
377.4095154	0.32
389.3201904	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0775
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
111.0340500	0.60
129.0504761	1.42
146.9790039	4.91
163.0806885	0.14
164.0501099	0.41
173.0619812	1.77
174.8994751	0.06
179.0777588	0.12
191.0312653	100.00
193.0544128	0.91
203.1553345	0.21
207.2287903	0.19
208.9990082	7.00
221.2991638	0.32
223.0993652	2.41
239.2398682	0.09
247.2814636	0.20
249.1489258	0.06
250.3381042	0.06
258.8675842	0.10
265.2081909	0.08
266.8797607	0.22
283.9241333	0.05
298.2677917	0.14
307.0702515	0.04
314.9218140	0.16
323.0378723	0.09
325.1841431	1.69
339.3403320	0.16
341.2097778	0.04
342.5587158	0.34
348.9962769	0.42
357.2559509	0.09
358.7052917	0.39
367.0489807	9.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	687.2137
Annotation	Butrin
Peak:m/z	Relative Intensity
247.2011108	0.13
279.1147461	0.07
290.9628296	0.13
294.9053650	0.02
309.0657959	0.42
313.2727051	0.13
336.9637451	0.10
343.1924438	100.00
344.9844971	0.07
360.1531982	0.18
396.8817749	0.05
403.3182373	0.10
417.2181396	0.31
461.4319458	0.09
475.2095337	0.04
479.4799805	0.15
501.2127686	0.23
511.5805664	0.13
518.9818726	1.58
525.2166138	0.44
525.8323975	0.13
564.3447876	0.13
565.5886841	0.12
567.0294800	0.09
568.9058228	0.11
591.8411255	0.10
601.1113892	0.27
640.2901001	0.06
642.5234985	0.05
643.4003906	0.28
649.0646362	0.08
652.4758911	0.06
656.3506470	0.32
668.7324829	0.45
669.3637695	0.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	582.18
Annotation	Unknow
Peak:m/z	Relative Intensity
271.0859375	6.62
272.1323853	11.30
273.0443115	8.25
274.1391907	5.10
315.1235352	0.13
334.0110474	0.17
363.3208618	0.20
375.1184692	0.28
382.1146851	0.22
383.3023071	0.21
384.4536743	0.27
398.3666992	0.07
401.2100220	0.25
401.9783936	0.38
417.8953247	0.45
419.1848145	0.45
420.2299194	1.09
428.9453735	0.04
433.2474365	14.70
434.1726685	42.80
435.1443481	44.93
436.1168823	100.00
448.3726807	0.09
450.3757935	0.10
528.4623413	0.33
545.9603271	0.36
546.7541504	0.24
550.2214966	0.16
564.3012085	0.50
565.4790039	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	959.4658
Annotation	Unknow
Peak:m/z	Relative Intensity
330.1325073	0.22
470.3650513	0.16
815.1275635	0.13
845.6593628	0.11
866.4266357	23.41
867.0477905	0.43
878.5211182	0.86
891.9362183	0.11
896.3477173	100.00
897.0369263	1.35
922.9549561	0.13
923.7348022	0.15
929.6349487	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	579.1928
Annotation	Excelside A
Peak:m/z	Relative Intensity
165.1222839	0.05
173.1524353	0.19
179.0100861	2.21
181.0281067	0.18
208.9962616	0.31
220.9691925	3.82
237.2076874	0.11
245.1557312	0.49
263.0878601	0.86
267.2220459	0.23
305.3193665	0.10
313.1956177	0.04
323.1507568	100.00
324.2227783	0.14
369.2005005	0.23
373.0393677	0.37
411.0181885	0.49
417.0222778	0.39
419.1040649	0.10
435.2338257	0.12
445.2254639	0.28
457.1784668	0.17
489.3881226	0.07
517.2056274	0.64
517.8508301	0.15
532.1007080	3.48
532.9180908	20.84
535.2224731	3.42
550.1218872	0.17
561.1071777	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.072
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
92.9477921	0.65
98.9592361	0.34
101.1124344	0.31
106.9469376	0.28
108.0222626	7.46
108.9453049	9.09
110.8596115	0.06
112.9459381	0.28
121.0139771	1.45
121.9170303	0.21
123.1018219	1.17
132.9828186	0.36
134.1594543	0.14
135.0257263	1.15
136.0519257	0.07
136.9855347	0.27
143.0407715	0.22
145.0548401	0.29
146.9019775	0.14
151.0468292	6.08
151.9676819	37.25
152.9315796	100.00
154.0989685	0.11
159.0608521	0.04
159.7959290	0.18
161.0608521	0.13
163.0559692	11.32
165.0147705	14.46
173.0706177	0.16
175.0636749	0.82
177.0221100	2.35
179.1296082	3.43
180.9912415	2.93
183.1536560	0.19
189.1657715	0.29
191.1216583	0.17
193.1754150	1.64
195.0561218	3.93
197.0832062	0.08
201.0050049	0.32
203.2103882	0.05
205.0102539	0.20
206.9991455	4.41
208.0755005	0.88
209.1000366	0.12
216.9882202	0.41
218.9370728	1.48
225.0226746	9.12
229.0658569	0.23
236.9595947	1.19
243.1446533	0.24
251.1669617	0.13
254.9781494	0.14
267.1879883	0.23
268.9324951	0.46
271.0701599	0.70
273.2347412	0.24
297.0294189	0.54
298.0539246	0.12
299.7740479	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.1575
Annotation	Planusin A
Peak:m/z	Relative Intensity
129.7461853	0.01
142.1319885	0.01
145.1128998	0.01
152.1010132	0.07
163.9849396	0.02
172.2786560	0.02
178.0420532	0.02
184.0845947	0.15
187.0775909	0.01
189.4042969	0.02
192.2323914	0.05
198.7460480	0.01
200.2584381	0.01
202.1575165	1.63
204.0971680	0.01
207.4208527	0.04
209.0914307	0.03
210.0422668	0.03
215.2467346	0.01
217.1833191	0.02
219.0966797	0.02
226.9750977	0.08
234.3333740	0.05
243.2387390	0.01
244.1044617	0.13
244.7639771	0.03
250.4734802	0.02
255.8781738	0.02
258.1982422	0.02
260.1344604	0.06
261.1330261	0.26
262.1109009	0.85
271.0040588	0.03
274.3912659	0.07
276.0857239	0.05
278.2168579	0.06
283.5114441	0.08
284.1614075	0.14
285.2883606	0.08
288.2158508	0.02
291.8978271	0.05
295.4651489	0.02
297.1768494	0.01
302.1730347	1.57
303.1912231	0.02
304.1080933	0.06
309.2998352	0.04
311.1389160	0.91
312.4591675	0.45
313.2192383	1.21
318.8243713	0.02
320.2177429	0.74
323.1498413	0.07
329.4871216	0.08
330.1271973	1.03
337.6857300	0.05
341.0958252	0.01
342.3204651	0.02
343.2964478	0.01
345.1627808	0.14
348.0617371	0.84
359.1912231	0.47
361.2247620	0.24
362.2189026	0.04
363.2110596	0.12
367.0629578	0.03
369.2298889	0.08
373.1425171	0.02
377.2392883	0.24
379.3595886	0.02
386.1111755	0.03
387.3134155	1.13
388.4223938	0.02
393.2171326	0.04
405.1962585	100.00
406.0924377	0.11
408.1932678	0.03
425.8307800	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	594.5626
Annotation	Unknow
Peak:m/z	Relative Intensity
187.2815399	0.17
209.2625427	0.05
211.2024841	0.11
217.1364746	0.12
229.2965546	0.13
239.2611694	0.10
243.4776764	0.09
247.3737488	0.08
253.2647095	0.08
257.1738281	0.04
259.2322693	0.09
265.3003540	0.09
268.1806335	0.05
282.8238525	0.20
284.1987305	0.10
285.0088501	0.08
287.1663818	0.37
291.5042114	0.09
293.2344055	0.36
295.3638916	1.54
296.0481567	0.19
306.3882141	0.04
309.4186401	0.13
311.6178894	0.42
312.5098267	1.11
313.2931519	1.40
314.1289368	0.06
317.1686096	0.06
322.3784790	0.80
323.4731445	0.08
325.4956055	0.61
329.1939697	0.09
330.3796387	9.99
331.4089355	1.00
336.3190308	0.10
337.0942383	0.06
339.2493896	0.03
340.3359375	2.24
341.4766235	0.26
342.3469238	0.04
343.2044678	0.06
353.0135498	0.29
354.4380493	0.12
355.1636963	0.14
359.1075439	0.23
370.8220215	0.04
380.0189819	0.03
383.2250366	0.08
390.3602295	0.05
413.3630371	0.07
419.4212646	0.07
423.6253052	0.14
435.4713135	0.18
449.1628418	0.55
457.3093262	0.28
462.2778320	0.41
463.2117920	0.22
464.5449219	0.06
467.4510498	0.05
474.2694092	0.09
475.5250244	0.09
477.7185059	0.13
483.2976685	0.13
490.6107178	0.18
493.4982910	0.06
504.2296143	0.17
504.8923950	0.08
506.3432007	0.35
510.9131470	0.59
521.1225586	0.07
523.2555542	0.11
527.4118652	0.52
532.0615234	0.11
533.7367554	2.25
534.4147339	11.57
535.5307007	2.79
545.3506470	0.47
548.1588745	0.62
552.0010376	0.13
559.2407837	0.31
560.7285767	0.57
561.3353882	0.13
562.3503418	0.30
565.4640503	0.22
566.4156494	0.73
576.6217041	100.00
577.6707153	28.82
578.7001343	1.99
580.0123901	0.15
594.4820557	0.25
595.5726929	0.45
597.7219238	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.2004
Annotation	4,2'-Dihydroxy-4',6'-dimethoxychalcone 4-apiosyl-(1->2)-glucoside
Peak:m/z	Relative Intensity
177.1308289	0.03
195.0150452	0.37
207.1198730	0.06
208.1041260	0.05
209.2833710	0.20
211.1380005	0.09
217.0144348	0.06
222.1937561	0.07
229.0671692	0.22
234.1315613	0.06
244.8569946	0.23
254.2270050	0.08
255.9315186	0.02
263.0802002	0.38
270.9648438	0.12
272.8160400	0.04
281.1730957	0.63
285.1748657	1.29
286.2639160	1.05
287.0715942	17.48
287.7574158	0.06
291.3568115	0.05
297.0838623	0.09
301.1374817	0.39
307.4472656	0.02
309.1787720	0.21
310.9815063	0.46
313.2026367	0.50
314.1523438	0.28
317.3528442	0.11
325.4260254	0.04
329.2263184	1.14
338.8776245	0.17
340.3061523	0.13
343.1849365	0.39
347.1398926	2.50
348.1794434	0.10
351.3062134	0.11
353.2559814	1.15
355.2742920	0.22
357.2217407	0.06
359.2145996	0.04
362.1109619	0.09
364.8751221	0.08
367.2150269	0.07
368.8177490	0.08
370.3958130	0.08
371.5480347	0.05
375.2747192	0.11
376.2790527	0.16
377.3248291	0.70
378.4441528	0.07
379.1273193	0.05
382.9754028	0.31
387.3361206	0.05
392.4896240	0.13
394.5444946	0.03
395.2159424	0.32
397.1277466	2.69
400.2049561	0.04
407.1734619	0.06
409.0789795	0.33
413.1268311	0.34
415.1314087	3.88
419.1478882	0.04
421.1560059	0.25
425.2063599	0.05
426.8497314	0.66
427.4883423	0.17
431.1074219	3.93
433.1347656	17.40
437.0192261	0.08
439.1516724	0.16
443.2239380	0.10
445.0789795	2.15
447.1608276	2.69
449.1085205	100.00
451.2563477	0.28
457.0921021	7.73
457.7675171	0.06
461.0648193	0.07
463.1987915	3.34
465.5455933	0.21
470.8365479	0.04
473.1242065	1.20
475.0921021	3.01
481.2079468	0.72
490.0321655	0.12
491.3364258	0.02
493.2077026	0.14
497.1907959	0.21
499.2667847	0.78
506.2283325	0.07
511.0475464	2.83
523.2145386	1.98
529.1281128	2.77
535.1820679	0.12
541.1640015	3.69
546.1096802	0.07
549.0997314	0.09
553.9010620	0.05
558.3738403	0.49
559.0919800	7.14
559.7795410	0.10
565.4047241	0.10
567.2474976	0.04
573.4536743	0.08
574.5527954	0.06
577.2146606	26.87
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	459.2217
Annotation	Marioside
Peak:m/z	Relative Intensity
133.0330353	2.34
135.0943909	12.83
136.9339752	0.51
144.9564819	0.20
147.2520294	0.39
149.1305237	0.31
151.2670135	0.31
160.8823242	0.23
163.2694855	0.16
164.9933167	1.29
169.0307617	0.18
175.1737366	13.28
176.8215027	0.12
178.7619934	0.23
185.2269745	0.10
187.1388855	0.71
191.1804657	0.58
193.0905151	17.86
211.0677032	100.00
211.6704407	0.19
213.1421967	0.08
227.1698608	0.25
231.0041504	0.42
253.1145325	0.12
255.0855713	0.46
266.9581604	0.17
270.9329224	0.32
281.3041077	0.05
287.5391235	0.19
289.3262329	0.17
297.3098755	0.49
307.1115112	0.17
309.2917480	0.10
315.1412964	0.29
319.1343384	0.37
339.1116333	2.06
357.3624573	0.28
361.2783508	0.58
363.2077026	0.39
369.5590515	0.51
371.3258667	0.17
373.2405090	0.56
378.7817993	0.36
379.4523010	0.34
395.1068115	0.14
397.2487488	5.36
398.1722717	0.17
399.2008362	0.68
413.3094788	0.74
415.2438660	2.30
423.1130981	25.79
423.8039856	0.46
431.3962402	0.22
440.5236816	4.98
441.1760864	13.31
442.1920166	0.27
443.9545593	0.15
445.2601929	0.22
450.4186707	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	461.11
Annotation	Padmatin 5-glucoside
Peak:m/z	Relative Intensity
169.3819580	0.02
179.0809784	0.02
215.1421661	0.03
218.2784119	0.01
251.9858093	0.02
253.0549622	0.02
257.0645142	0.08
277.0086670	0.01
284.1748962	0.15
298.6585083	0.90
299.3522644	0.43
311.2420044	0.03
313.3925476	0.18
323.2951660	0.06
324.9312134	0.02
326.3863525	0.02
338.3975830	0.03
339.2464294	0.05
341.0957031	100.00
342.0776978	0.30
342.7757568	0.04
351.0787048	0.08
353.1248169	0.30
355.7428589	0.08
357.1860962	0.06
364.5322266	0.06
367.3382263	0.10
371.1330261	11.79
371.8432922	0.12
375.1398010	0.08
379.2958679	0.01
381.3160706	0.17
383.2555847	1.16
384.9570007	0.25
395.0495300	0.13
401.1239929	0.42
407.2400818	0.81
413.1127930	0.25
418.8376160	0.01
425.1553650	0.55
443.2841492	0.64
446.3934937	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393.04
Annotation	Unknow
Peak:m/z	Relative Intensity
147.0450439	0.05
148.9787140	0.85
150.0370789	0.21
150.9352722	0.32
167.1452942	0.10
168.9425049	0.08
197.1816559	0.06
201.0178833	1.29
202.1705322	0.13
203.9635773	0.05
213.2923279	0.06
215.9589539	0.27
217.2497559	0.13
230.9910278	100.00
242.9647827	0.22
246.1112671	0.06
261.3381653	0.16
278.6692810	0.06
279.2773438	0.19
286.0401917	0.06
293.2797241	0.16
298.0082092	0.16
299.0104370	0.06
302.8840332	0.49
307.2323608	0.07
312.0634155	0.13
316.0246582	0.10
318.0862122	0.24
320.5923157	0.19
337.3061523	0.22
339.2591553	0.07
343.7965393	0.05
347.0316162	0.55
348.0656738	0.10
349.1855164	0.19
357.1775208	0.34
362.3513184	0.05
374.4289856	2.40
375.2351990	3.41
384.8948059	0.29
392.1993713	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
125.1127014	0.49
135.065033	1.04
142.9483185	0.74
153.1466675	0.41
154.999115	0.24
165.9346619	0.29
170.9955444	1.25
172.9624329	1.07
181.4612579	0.41
185.0348511	0.37
187.0088806	0.40
195.0488739	3.29
199.0941772	0.23
200.967041	0.37
203.1539764	0.36
215.2675476	2.75
224.9108582	0.48
227.3262634	1.49
229.1798096	1.63
233.1842957	0.68
240.9440308	0.26
243.3032532	0.87
255.2719421	1.10
257.1983643	0.17
258.2984314	0.44
259.1592407	0.39
262.8010864	0.65
263.5432739	0.27
269.2172852	0.42
271.3233643	3.06
272.9776306	0.21
281.2857056	0.40
283.3982544	1.51
285.1654968	6.07
287.1597595	0.61
289.2146912	0.57
293.3893433	0.42
295.4215393	0.86
297.2633057	1.11
299.2828674	2.09
301.3361206	0.56
311.4156799	0.38
313.2237549	4.77
314.0720215	0.23
315.274353	0.46
321.2771606	1.47
321.9522095	0.29
323.3564453	10.87
327.0871582	0.39
330.8666992	0.28
337.4121399	0.21
339.2550049	100.00
341.3475342	16.99
342.102478	0.24
343.2260742	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.2093
Annotation	Clinacoside B
Peak:m/z	Relative Intensity
190.9549561	0.41
192.9652405	0.08
195.0270996	0.34
196.9620819	0.02
201.2432251	0.12
213.1639099	0.04
262.9756470	0.35
279.1701050	0.06
281.0696106	0.29
289.1041870	0.13
291.8453979	0.14
298.9365234	0.05
301.1160278	0.26
301.8839111	0.04
303.2132568	0.47
304.8575439	0.19
309.2567749	0.18
315.0665894	0.17
316.5005493	2.15
317.1415405	29.25
318.1564941	1.65
319.1685181	4.29
329.1979675	0.05
333.3579102	0.02
341.3894653	0.11
343.0902710	0.08
344.1166992	0.27
345.2897949	0.31
347.2019043	0.47
349.3488159	0.11
351.5822754	0.17
354.1759033	0.06
359.1711426	2.25
360.1723022	0.03
361.0060425	0.22
362.2847900	0.16
363.2072144	0.06
367.3382568	0.36
371.2447510	0.07
375.0814209	0.04
377.1577759	100.00
377.9219360	0.03
382.9996338	1.04
383.6221924	0.18
384.5435791	0.08
393.4071655	0.13
395.0177002	0.10
397.2916870	0.17
407.2509766	0.27
409.3446655	0.17
413.0490723	0.52
414.2947998	0.06
419.3549194	0.07
423.2680054	0.10
425.1821899	0.72
427.1892700	1.59
429.1125488	0.22
437.3861084	0.30
439.2227173	0.24
443.1892700	0.30
445.1698608	4.86
451.1853638	0.70
452.7524414	0.04
455.1958618	0.07
457.1289673	0.21
459.3531494	0.05
461.1315918	5.29
463.1049194	11.86
467.2269897	0.04
469.0590820	0.51
469.8547974	0.29
471.0100098	0.10
473.0831299	0.41
475.4490967	0.32
479.0336304	75.35
479.6851807	0.29
481.0139771	0.03
483.3756714	0.08
487.1777954	10.20
503.1784058	1.24
505.1602173	4.57
511.1752319	1.75
515.3814697	0.34
517.0147095	0.06
518.2036743	0.10
521.2272339	0.13
526.7561035	0.22
527.4864502	0.04
528.5029297	0.32
529.2345581	1.30
538.8545532	0.24
541.2429810	2.40
543.3267822	0.14
545.5571899	0.05
550.0210571	0.10
553.2442627	1.27
554.2697144	0.04
559.1987915	4.59
561.9501953	0.05
565.2298584	0.04
567.5624390	0.06
571.0903931	4.39
577.1908569	0.14
579.3577271	0.07
589.2166138	12.02
593.1473389	0.04
595.1746826	0.08
607.0879517	32.22
607.7669067	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.1984
Annotation	Faratroside
Peak:m/z	Relative Intensity
250.1973419	0.04
259.3805237	0.03
283.3841553	0.01
287.0258179	0.06
294.9422302	0.02
299.1199341	0.03
301.2293091	0.02
302.0054321	0.02
305.0979614	0.30
315.1534119	0.17
330.1453247	0.52
331.3245850	0.02
345.1373901	7.02
347.2719421	0.04
357.1154785	0.02
367.1941528	0.12
375.3491211	0.03
387.0278320	0.08
449.1878052	0.09
451.3737793	0.02
461.2928467	0.06
471.3858032	0.09
489.0721436	0.19
507.1644897	20.64
507.7732544	0.16
525.2107544	0.03
531.3303223	0.05
535.0677490	0.04
544.1239014	0.05
549.2440796	13.06
568.9065552	0.02
577.2177124	0.03
589.3269653	5.48
591.1381836	1.39
591.7587280	0.01
621.4915771	0.03
631.3332520	0.60
633.1433716	0.15
633.7714233	0.04
649.7875977	0.33
651.1306152	100.00
652.0095825	0.01
663.6835327	0.04
671.1512451	0.30
681.0408325	0.04
693.1924438	10.34
707.2620239	0.10
722.9929810	0.09
733.1930542	2.76
735.1242676	0.05
750.8026123	0.08
751.5118408	0.16
753.2400513	0.03
757.3481445	0.04
764.7550049	0.09
777.1400757	0.05
780.3521118	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
198.0045166	0.01
212.2349548	0.04
215.9977112	0.07
223.1319275	0.21
227.2018127	0.01
254.9688721	0.04
256.2071533	0.18
273.2110291	0.09
277.0441284	0.03
284.0758667	28.31
285.0625610	0.14
299.0959473	100.00
299.9083862	0.04
301.1797791	0.38
305.0596313	0.05
313.3808594	0.02
323.0351562	0.01
326.1254272	0.04
327.4478760	0.05
341.1365356	0.59
343.6719971	0.02
367.3065796	0.25
397.4230957	0.04
401.3442383	0.11
419.5458374	0.04
443.2256470	0.35
443.8663330	0.06
445.2892456	0.17
449.3125610	0.05
455.1047974	0.02
462.2441406	0.04
463.2416382	1.42
476.9594116	0.02
487.1488647	0.08
491.2741089	0.07
504.5038452	0.06
505.2485962	0.60
521.3316040	0.06
547.1408081	0.12
560.9697876	0.18
562.3753662	0.11
563.2916870	0.21
575.2440186	0.06
577.1189575	0.05
589.2327271	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	387.19
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8068008	0.09
129.1979370	0.02
175.1071472	0.06
190.9694214	0.03
194.9325562	1.27
195.9812317	9.03
202.9964142	0.12
207.2884674	0.16
213.0958557	100.00
216.0943604	0.09
217.0088348	0.04
219.1379700	0.30
225.1238708	0.24
232.0927429	0.11
233.0396118	0.03
234.0199280	0.02
235.0879822	16.06
251.0738525	10.73
252.0148621	0.05
255.1219788	0.17
267.2348022	0.19
283.1470642	0.03
299.1682129	0.07
301.0148315	0.13
302.8736572	1.63
303.6016846	0.09
318.9913330	2.85
324.2078857	0.16
325.2114868	0.15
327.1704712	1.86
328.0010986	0.05
329.0375366	0.07
340.9652710	0.15
342.3343506	0.12
369.1277161	3.21
369.8403625	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.2859
Annotation	Nomilinic acid 17-glucoside
Peak:m/z	Relative Intensity
233.2673798	0.10
247.1964417	0.05
263.5791016	0.04
271.4423218	0.04
275.4483032	0.13
277.0036926	0.09
287.0189819	0.01
299.4195862	0.04
307.2176819	0.04
309.3203125	0.13
319.1243896	0.02
329.2631836	0.02
343.3124390	0.20
347.2638550	0.14
349.1492920	0.08
366.2521362	0.04
367.0269775	0.15
377.3895874	0.04
383.5407104	0.03
393.2438354	0.01
395.1835327	0.26
397.6488037	0.03
401.3383179	1.42
419.2913208	0.71
423.5726318	0.05
443.2569580	0.04
444.4171753	0.06
445.4329224	0.25
467.0463257	0.02
471.4190063	0.19
475.4157715	0.07
481.4769897	0.07
489.3543701	0.74
503.1586914	0.02
505.3541260	0.16
531.2874756	0.10
538.0653687	0.06
544.6681519	0.02
549.4741821	0.11
555.5693970	0.05
561.3380737	0.03
563.4064941	0.76
567.2636108	0.13
575.6434937	0.06
582.6740112	0.02
583.4426880	0.03
589.2587280	0.17
591.2366333	1.07
607.3171387	100.00
607.9357300	0.45
609.3475342	0.54
623.4192505	0.05
625.4472046	0.05
633.3814087	0.60
635.3507690	0.02
651.2717896	28.24
652.0207520	0.06
665.5341797	0.02
667.2019653	0.09
669.3067017	2.85
693.4513550	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
177.1692352	0.62
193.0556793	0.11
202.9264374	0.33
205.2681122	0.04
257.9562378	0.16
270.9920349	0.84
285.300293	0.04
286.1421509	0.28
295.131958	0.30
301.1796265	27.21
303.0422668	0.38
309.1236877	0.38
313.1879578	5.47
317.4697571	0.06
325.1467285	0.09
337.177063	0.08
339.2160034	0.18
343.2593384	2.04
347.2125244	0.21
351.1836548	0.19
361.1896362	0.65
367.3049316	0.18
377.3881836	0.05
379.3018799	0.03
389.09375	0.04
397.4369507	0.07
409.2843628	0.36
411.1982422	0.34
415.3768311	0.44
427.194397	0.08
429.3240356	0.50
433.3858032	0.34
442.2755127	0.13
445.0641479	0.43
445.812561	0.12
447.0116577	0.81
456.7359619	0.38
458.3373413	0.16
463.1372681	100.00
465.2767944	0.06
466.2506104	0.09
471.2321167	0.12
474.9727783	0.04
503.7166138	0.09
513.1483765	0.11
515.2937622	0.08
554.0974731	0.04
555.1218262	0.13
563.6760864	0.07
565.1246948	0.11
566.244751	0.06
573.0310669	0.62
577.4125366	0.31
578.0689087	0.03
585.3421021	0.16
591.2926025	2.30
592.0736084	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	315.072
Annotation	4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid
Peak:m/z	Relative Intensity
90.9033203	0.05
92.7979507	0.35
94.9001160	0.09
101.1040726	0.96
107.8785706	6.18
108.8737640	7.76
112.9196625	0.25
120.9376984	1.57
121.9158478	0.36
123.0908890	1.05
129.0306396	0.20
132.8804626	0.44
134.9378052	1.09
135.9970093	0.09
145.0654297	0.36
145.9009399	0.11
146.9781952	0.04
148.8970337	0.19
151.0628967	5.78
151.9336243	35.57
152.9537964	100.00
153.8945923	0.09
158.8865356	0.21
161.2228699	0.11
163.0580444	9.21
165.0321655	14.63
167.1660461	0.06
173.2771606	0.13
175.0911560	0.72
177.0021820	1.96
179.0288849	3.28
181.0898743	2.51
188.9274597	0.92
190.9880829	0.08
193.1110687	0.58
195.0329285	3.72
200.8052368	0.12
203.0034027	0.21
205.1517334	0.10
207.0585327	3.59
215.1333618	0.08
217.2129517	0.66
219.0659790	1.47
225.0454712	11.25
231.2141724	0.07
237.0918579	2.00
239.2319641	0.15
248.7947388	0.09
255.0906372	0.10
297.2047729	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
176.7684937	0.20
198.9535675	0.04
225.0388947	0.07
229.289978	0.53
245.2929993	0.07
249.618927	0.24
255.8479309	0.06
261.1027527	0.41
263.2794189	0.58
271.2578735	0.05
281.5720215	0.47
286.151947	0.29
292.6004639	3.26
295.0924377	0.46
301.0857239	19.57
303.244751	0.26
305.5547485	0.84
310.2254639	0.12
313.2015381	0.47
314.5603638	6.09
315.5977173	0.38
324.9333801	0.51
326.5164795	0.10
343.3497314	0.35
350.8500366	0.11
361.4222412	0.36
363.2136841	0.07
366.4570312	0.10
367.6504517	0.05
374.5406494	0.34
378.4035034	0.26
379.1907959	0.09
395.0402222	0.21
396.3162231	0.30
403.2872314	0.28
411.1427612	0.81
415.1292114	0.07
426.3304443	0.18
429.4115601	0.50
445.600647	0.10
447.1539307	0.66
459.1571045	0.30
463.1323853	100.00
469.3621216	0.20
471.3547974	0.04
476.2785645	0.08
480.538147	0.36
516.4789429	0.16
518.3602905	0.26
521.1283569	0.27
522.7873535	0.22
524.9898071	0.22
527.3825073	0.17
528.3450317	0.24
529.5045776	0.12
538.6641846	1.12
543.9415894	0.37
555.2975464	0.25
562.850647	0.27
563.5114136	0.13
565.3057251	0.22
569.4024048	0.26
572.3414917	0.15
573.1072388	1.79
578.0814209	1.17
580.954895	0.12
583.2624512	1.56
584.5097046	1.48
585.7177734	0.10
587.0360718	8.15
587.9417114	0.61
591.1166382	2.02
592.0513916	0.11
594.7608643	0.83
595.6997681	1.29
600.1008301	8.80
601.0057983	0.77
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	195.0647
Annotation	Speciosin D
Peak:m/z	Relative Intensity
89.1571350	0.06
100.9767456	0.03
107.9715271	0.01
113.2150574	0.01
133.0460815	0.03
136.2905884	0.01
138.0547180	0.26
144.8610077	0.01
149.1265869	0.01
150.9464569	0.01
152.9116974	0.11
164.1349945	0.02
174.6226959	0.01
176.9913940	100.00
177.8198242	0.03
180.2523499	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.0909
Annotation	Unknow
Peak:m/z	Relative Intensity
108.8870544	0.53
111.0879974	0.11
122.9458237	9.50
126.9807281	36.84
139.1160278	0.36
139.9921570	0.05
144.0939636	0.09
144.9122620	1.05
146.8755341	0.32
149.0018768	0.22
150.9388733	100.00
163.0095978	0.71
165.0382690	0.49
167.0127563	0.24
168.9543457	60.89
171.0059509	0.43
173.0291595	0.16
175.0196533	3.43
176.8786316	0.32
179.0313416	0.03
189.0332947	8.22
193.0029297	55.11
199.1138000	0.34
211.1294403	0.11
213.0118256	0.12
216.9889069	24.64
219.1322632	0.04
228.1896667	0.25
230.9529114	1.97
235.0756531	72.95
243.0913696	0.06
247.4003601	0.07
248.6979675	0.54
253.1020203	1.35
256.7718201	0.18
270.8810120	0.31
277.1161499	1.00
279.0932007	0.38
285.0245361	0.37
289.8645630	0.06
300.0322266	0.77
303.0284424	11.98
311.0281372	0.07
314.9519348	0.07
321.0161743	37.86
321.7058105	0.21
331.1980896	0.20
338.9935303	78.23
339.6801758	0.13
343.2146912	0.09
345.1404419	0.07
351.8548889	0.06
357.0034180	33.90
357.7953186	0.56
358.4592590	0.05
360.2510071	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.16
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
180.1304321	0.04
183.0012512	0.02
191.2901154	0.04
194.1602325	0.05
205.2215271	0.10
215.2741852	0.04
221.1351929	0.02
232.2037964	0.04
233.6662140	0.01
243.3204193	0.01
245.3467712	0.08
253.0728455	0.03
295.0465698	0.02
307.1391907	0.01
311.2398071	0.12
313.2133179	0.07
325.3139038	0.36
329.1547852	0.77
333.1868896	0.03
336.9943848	0.11
339.4281006	0.03
349.0059814	0.05
350.9111938	0.05
355.1739502	1.05
359.1388550	0.16
359.8732300	0.04
367.0482178	0.09
375.2551880	0.09
379.2047729	0.95
384.9885864	0.12
391.2150879	0.10
393.2725220	0.07
397.2322388	0.12
402.2680664	0.04
403.3111572	0.34
409.1896362	1.92
412.3555298	0.08
415.1546631	0.66
417.1861572	0.07
421.3213501	1.46
427.1856079	1.39
430.1788330	0.08
433.3193359	0.61
435.4392700	0.08
439.1735840	1.86
441.2933960	0.02
445.2437744	0.75
448.9306030	0.30
451.0007935	0.03
453.1683960	0.03
457.1242676	40.41
462.2080078	0.05
463.2331543	0.17
469.3350220	0.06
473.0816040	0.02
475.1239624	12.61
475.7612915	0.04
477.0601196	0.01
481.2501831	5.15
486.9589233	0.05
491.1262817	0.05
493.2719116	0.27
499.2953491	6.17
503.4342041	0.04
505.2319946	0.08
509.6659546	0.09
511.2749023	10.72
520.5446167	0.11
521.1991577	0.09
523.2852783	5.16
524.1631470	0.02
526.9130249	0.09
529.1646729	14.64
531.2178345	0.02
541.2224731	9.09
542.2594604	0.14
551.3314209	0.04
553.7705688	0.04
556.4600220	0.04
559.1544800	22.87
559.7992554	0.19
577.1376953	100.00
577.7781372	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	313.0909
Annotation	Unknow
Peak:m/z	Relative Intensity
92.8777466	0.11
94.9196701	0.06
96.9984741	0.43
99.2544403	0.04
109.1049500	0.09
116.9461060	0.06
119.1579437	0.02
120.0321503	0.03
123.1198959	0.29
124.9879227	0.38
127.0413818	0.44
135.0891113	0.04
143.9942169	0.03
144.9202881	0.22
146.8708344	0.23
148.8842773	0.12
150.9479980	100.00
157.1362305	0.02
163.1109619	0.06
164.9347382	0.14
165.7220764	0.04
167.3028259	0.05
168.9663849	11.87
171.0608215	0.06
177.0246582	0.08
189.0380707	0.02
193.2619629	0.11
195.2929993	0.03
201.0665894	0.10
211.0541992	0.10
215.0592957	0.01
217.1430054	0.03
225.2414856	0.04
228.3036499	0.08
231.4040833	0.06
234.6321716	0.02
243.0469360	0.25
246.9851074	0.04
253.2454224	0.18
257.0832520	0.08
257.6921387	0.04
258.9830322	0.06
267.4433899	0.08
269.3597412	0.02
270.0910034	0.10
271.0930786	0.06
272.2164307	0.04
277.0538635	0.59
283.9617615	0.08
285.1679077	0.40
285.9329224	0.01
295.0679626	66.41
295.6776123	0.15
298.0791321	7.07
299.1740723	2.16
313.2725830	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.2466
Annotation	Unknow
Peak:m/z	Relative Intensity
173.1242371	0.89
175.6557159	0.07
187.1374664	0.46
189.1337738	0.40
191.0567017	36.02
193.2692108	0.20
199.1096191	0.23
200.7886047	0.11
203.2577209	0.43
209.1205750	27.24
211.1164398	0.15
212.8806763	5.48
213.5149536	0.03
217.1155701	0.46
220.9347992	0.41
227.1550293	0.27
227.9568176	0.19
229.0160217	0.41
231.0251923	3.60
233.0816650	0.25
234.8306580	0.18
239.1967010	0.20
244.3140564	0.15
245.0817871	0.29
246.6818542	0.14
247.3031311	0.18
248.9579773	2.09
253.0383911	0.96
255.1545410	0.14
257.1495972	0.43
263.1923218	0.13
271.0339966	0.47
272.7876587	1.31
274.5122681	0.43
275.1344910	0.08
281.0774536	1.01
289.0430603	0.50
291.1260376	10.18
292.9884644	0.32
294.9249878	0.14
299.2081909	4.71
315.4197998	0.05
317.1200562	0.22
319.2370605	0.13
321.0610962	0.20
329.1285400	0.09
330.9820557	1.54
332.8911133	0.71
334.8907471	1.11
336.3020020	0.31
337.0598755	0.22
338.8937988	2.38
339.5129395	0.07
343.3951416	0.04
345.1846313	0.04
347.1732178	0.26
349.2629395	0.71
353.0094604	12.26
355.7815552	0.44
356.9639282	6.61
359.2303467	0.46
375.1288452	100.00
377.1104126	1.10
385.3690186	0.70
389.9145508	0.04
391.0464478	0.35
392.9841309	77.92
393.6687622	0.11
395.4234009	0.08
398.9544678	0.20
403.1535645	65.34
407.4343262	0.27
408.8973389	0.62
410.9383545	3.85
413.0966797	0.17
418.7973022	1.11
420.3951416	0.88
421.0160522	7.79
421.7555542	0.04
423.2286987	0.05
437.5255127	0.25
439.0531616	8.61
442.9769897	0.45
444.9532471	0.16
448.4088135	0.30
449.2821045	0.09
454.2202759	0.31
455.2448730	0.14
457.0198975	21.26
462.7707520	0.79
476.9736938	0.18
481.0769043	4.03
494.2898560	0.24
501.1206665	0.11
502.9533691	0.43
515.4981079	0.04
516.1115112	0.22
520.7828979	1.12
521.4003906	2.93
527.4584351	0.35
539.0412598	2.79
541.2095947	0.36
545.1167603	0.15
546.2765503	0.90
547.0808105	13.48
557.4005737	1.09
562.3156128	0.14
565.0320435	83.09
565.7886963	0.18
582.5074463	13.79
583.1315308	98.80
584.1964111	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	174.96
Annotation	Unknow
Peak:m/z	Relative Intensity
87.0426254	0.08
102.9877167	0.18
112.9761505	0.08
130.9159393	100.00
134.0293427	0.03
145.0002899	0.04
146.9616241	18.11
156.7425537	0.06
160.0545197	0.15
174.9955292	2.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	713.1928
Annotation	Haploside D
Peak:m/z	Relative Intensity
269.2292786	0.06
287.2596130	0.14
293.0198364	0.04
314.4081116	0.08
316.2177124	0.04
327.3550415	0.12
329.0776367	0.06
345.2676392	0.07
357.0198975	0.06
365.0578613	0.02
373.2699585	0.39
374.4245605	0.03
388.9238892	0.09
399.1196289	0.42
407.4679565	0.06
441.1277466	0.04
447.1226807	0.04
464.2618408	0.12
465.2046509	1.54
466.5032959	0.10
483.5949097	0.02
487.3690796	0.08
501.0280151	0.19
505.1828613	0.05
507.2897339	0.18
509.3780518	0.10
521.3417969	0.04
533.4031982	0.08
535.1859741	0.04
543.3104248	0.04
551.2036133	0.14
567.3854370	0.02
568.3818359	0.02
592.2518921	0.06
594.7743530	0.06
607.1358032	0.04
609.0410767	0.33
611.4994507	0.02
617.3982544	0.05
619.4078369	0.06
622.2087402	0.02
623.3444824	0.02
626.2623901	0.14
626.9816284	0.02
631.2195435	0.01
637.1110229	0.06
638.8073120	0.02
641.0079956	0.09
650.1869507	0.03
651.2443237	0.33
667.1347656	0.03
669.2262573	100.00
692.9557495	0.01
695.0977173	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	563.1749
Annotation	Formononetin 7-O-beta-D-apiofuranosyl-(1->6)-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
192.3031616	0.02
207.1683502	0.03
207.9974060	0.01
211.1812439	0.02
212.7752380	0.08
215.2572174	0.06
239.2576447	0.12
248.9995270	0.01
251.0128174	0.04
255.1321411	17.20
277.2966919	0.01
278.9918213	0.04
285.1289062	0.05
286.8723755	0.13
289.2423096	0.02
290.4021606	0.01
297.2839355	0.05
301.1043701	0.12
312.3638306	0.06
315.1352539	0.01
317.1383667	0.02
321.1055908	0.05
324.1936035	0.10
326.3553467	0.02
329.1810913	0.06
334.9921875	0.03
340.1494141	0.03
343.3447266	0.18
347.2747192	0.02
352.0093384	0.07
353.3238525	0.01
356.0685425	0.01
357.1132202	0.06
358.0205078	0.02
359.1261597	0.03
360.0505371	0.01
365.1959839	0.20
367.0484009	0.07
369.3671875	0.04
371.2353516	0.03
373.4057007	0.05
375.0787354	0.21
380.7307739	0.05
383.3107910	0.22
383.9175415	0.03
393.0402222	0.13
397.3274536	0.05
400.6334839	0.28
401.2548218	1.01
403.0403442	0.04
405.3845825	0.03
408.9371948	0.06
410.7196045	0.04
413.3931274	0.05
417.0686646	100.00
417.6843872	0.51
418.9084473	0.05
421.0267334	0.02
433.1180420	0.05
438.7276611	0.10
440.2943726	0.03
441.4056396	0.08
448.1704102	0.03
459.0977783	0.26
461.2200928	0.07
465.0196533	0.08
475.1537476	0.12
477.0343018	0.02
487.1159058	0.04
494.1464233	0.08
494.8328247	0.07
495.7410889	0.03
500.9837646	0.02
503.2675171	0.08
507.1041870	0.08
509.4421387	0.02
515.2694702	0.09
516.9801025	0.07
519.4612427	0.07
526.1551514	0.07
527.1027222	0.10
531.4054565	0.04
533.1251831	0.03
535.5924683	0.10
544.2096558	0.10
545.2401733	0.74
546.2844849	0.06
554.2092896	0.02
558.0835571	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.2134
Annotation	Barbatoside A
Peak:m/z	Relative Intensity
195.0267487	0.32
206.9992065	0.34
212.8575745	2.84
237.3891449	0.08
247.1093597	0.15
254.9384460	0.30
257.2452393	0.06
277.0180664	0.11
292.2010498	0.07
294.9571228	0.19
305.1078796	0.12
327.0526123	0.08
355.2144775	0.07
355.9924316	0.11
356.9130859	0.09
374.8385620	0.77
375.4396362	0.45
398.0195923	0.07
416.7143555	0.63
427.1154175	0.54
457.2561035	0.10
459.1650391	0.12
475.1602173	1.29
483.4459229	0.07
501.1531372	0.43
508.8996582	0.10
517.1002197	0.05
519.2372437	100.00
524.1213989	0.17
529.3027954	0.13
534.4482422	0.13
539.9739380	0.05
541.9241943	0.53
557.0667114	0.12
557.9613037	0.84
561.2544556	6.44
588.0281372	0.19
601.2665405	1.25
603.5147095	0.26
619.4812622	0.20
636.1594238	0.36
645.1672974	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1103.2869
Annotation	Clitoriacetal 11-O-glucoside
Peak:m/z	Relative Intensity
314.3189697	0.26
315.1203613	2.08
316.1359253	0.17
337.2722778	0.05
355.0653687	0.12
365.2972107	0.03
399.0314331	0.06
469.5588074	0.06
477.2384644	5.18
478.5296631	0.03
479.3330078	0.13
493.2263184	0.16
519.2755127	5.19
521.4177856	0.05
531.3609009	0.04
549.3690186	0.17
559.3280029	3.57
561.1997070	0.86
601.2602539	0.18
603.3249512	0.66
621.1464844	28.38
621.7611694	0.10
625.1682129	0.08
635.2119141	0.03
639.0407715	0.08
641.3814697	0.18
651.0756226	0.03
653.1442871	22.52
653.7657471	0.04
657.2794800	0.11
663.1362915	6.72
675.4403687	0.14
691.3262939	0.04
693.1321411	0.06
703.2220459	0.55
705.3884277	0.25
729.1507568	0.22
741.0201416	0.12
757.4710083	0.08
765.1264038	2.30
767.3411865	0.16
780.9622192	0.09
783.0289917	1.03
791.3841553	0.06
806.1848145	0.06
813.1121826	0.11
815.1937256	6.65
824.0792236	0.23
825.5773926	0.03
843.3879395	0.07
845.3937988	0.08
857.0389404	3.69
857.7066650	0.07
876.6944580	0.06
884.8854980	0.06
888.9750977	0.09
895.2847900	0.17
897.1834717	1.72
898.6479492	0.38
899.2513428	0.39
911.2329102	0.15
915.4552002	0.04
927.2668457	0.07
939.1444092	1.00
940.9698486	0.14
956.2858887	0.15
959.1041260	100.00
959.7613525	0.54
979.1961670	0.28
982.6878662	0.18
987.2724609	0.26
1001.1164550	8.54
1013.1226810	0.13
1022.1224370	0.22
1031.0460210	0.14
1041.1108400	1.64
1043.0800780	0.17
1059.1860350	0.08
1061.2493900	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	721.3151
Annotation	Ritonavir
Peak:m/z	Relative Intensity
202.0774841	2.63
203.9300079	0.07
204.8983917	1.47
206.1074524	0.16
207.9246216	0.31
209.3278046	0.12
210.1930084	0.68
211.9405670	0.64
214.0022278	0.44
215.9179993	0.05
220.3299866	0.40
221.2149963	1.07
221.8902893	0.40
222.9401703	0.11
224.0532074	0.17
225.4657593	0.08
226.1172943	3.61
230.3648071	0.15
232.9677124	0.08
234.1925507	0.19
236.2367249	0.88
238.0133667	4.50
238.7636566	0.10
240.1262360	0.67
244.1079254	4.46
245.1134949	0.26
246.0191345	0.52
250.0545349	0.19
251.1028442	0.11
252.1246643	0.78
253.7974396	0.57
256.2333984	0.90
260.2379150	0.23
262.2220764	0.26
264.2587280	0.81
265.0327759	0.24
266.1116333	0.13
268.1463318	4.75
269.0065002	0.58
270.1861877	0.29
271.1897278	0.30
273.3601685	0.24
274.0835571	0.90
280.1607666	0.77
284.2523804	0.78
286.1437073	3.75
287.0921631	1.32
288.1375732	0.66
292.2106628	2.78
293.0548096	0.25
295.0125732	0.67
298.2285156	1.47
298.9959717	0.35
300.1873169	0.45
301.1291199	0.38
304.1353760	3.88
305.1376343	1.40
306.2561340	0.45
307.3031006	1.10
310.1702881	2.04
311.2787781	0.04
315.9811401	0.25
317.2667847	0.07
319.2084961	0.16
320.1640015	1.14
322.2625427	6.82
322.9982910	1.96
324.1195068	0.16
325.1139526	0.08
328.0707397	4.93
329.4741516	0.13
332.4208984	0.08
333.1102295	0.09
335.2346802	0.65
336.1815186	0.41
338.1723022	25.92
341.1372681	0.56
343.9953003	0.31
346.2227783	1.11
348.0628967	1.75
350.1484985	3.51
353.0003662	0.24
355.2111816	0.13
356.3972168	1.04
358.3328247	0.37
360.9447021	0.06
362.2542114	16.81
363.7724609	0.65
364.3739014	1.40
365.3129883	0.14
368.0257568	0.91
370.1961060	2.13
372.0735474	0.44
374.2983398	0.68
376.3322754	1.01
377.3410645	0.05
378.4390259	0.30
380.2610474	23.02
381.3223877	0.14
383.1641235	0.28
386.3089600	1.16
388.1096802	2.97
390.2521973	1.00
392.0923462	0.57
394.0004883	0.23
394.7271729	0.48
398.2136230	1.40
400.1989746	1.31
402.2210083	0.93
403.0896606	0.29
404.2503052	9.04
406.2864380	0.33
408.2384033	0.59
410.0410156	0.09
412.1535645	2.21
413.2494507	0.20
416.4285889	0.93
418.2522583	0.91
422.2493286	1.23
428.1503296	7.92
430.2195435	1.09
434.2193604	0.98
436.5288086	0.08
446.2761841	21.78
448.2744751	0.81
452.1885376	0.08
464.2605591	57.46
466.6950684	0.53
469.9708862	0.41
476.4924316	0.10
482.2520142	100.00
483.4812622	0.35
486.1840210	1.28
488.1851196	3.14
495.0674438	0.23
500.2332153	26.51
500.8691406	0.33
506.2654419	3.20
512.4011841	0.34
518.4694214	0.32
524.2556152	1.63
530.2622681	0.54
532.5241089	0.08
536.5076294	0.10
542.2644653	0.50
559.3258667	0.41
565.8837280	0.76
566.5141602	0.83
583.2321777	0.50
584.5368042	0.24
590.3445435	2.20
608.3497925	4.12
626.3315430	7.61
641.2454224	0.11
644.3051758	7.63
655.2904663	0.33
662.5433960	0.96
671.3381958	0.10
672.6052856	0.25
675.1934204	0.18
679.2239380	0.56
692.9002075	0.19
703.3534546	2.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1274
Annotation	Juglanoside A
Peak:m/z	Relative Intensity
104.7031097	0.06
108.8726654	0.11
119.8606796	0.10
120.8919678	0.07
121.6958160	0.10
124.0654449	0.04
127.1810226	0.12
132.9709015	0.08
138.9890289	0.27
142.5919495	0.26
146.9164734	1.05
148.0875854	0.17
149.2118835	0.08
153.0352783	0.06
155.9529419	0.05
161.0156860	0.09
162.9555817	1.53
164.9672852	0.09
167.0233154	0.05
174.8732300	0.03
176.9256592	0.93
178.9645081	0.09
181.1944885	0.20
184.2323151	0.16
185.3114319	0.05
187.1678619	0.06
188.9532013	0.14
195.0057678	0.16
197.0914154	0.04
198.8374634	0.03
200.9793091	0.03
201.9263458	0.03
203.0795288	0.07
204.9693298	68.44
209.4171753	0.11
211.9514771	0.51
213.0987854	0.64
217.0406494	0.93
221.1900024	0.21
223.0342407	100.00
229.1560364	0.11
237.1309814	0.19
241.7197876	0.24
243.3128357	0.10
247.1222839	18.88
252.5065308	0.03
255.2854309	0.21
259.0918884	0.50
260.1669617	0.04
261.1745605	0.23
261.9851074	0.12
265.1441650	0.68
268.1356506	21.83
269.1622925	27.94
269.7720032	0.17
270.6092224	0.10
271.2441406	2.00
274.9812012	0.06
277.1160889	2.03
279.2908325	0.21
279.9605713	0.06
283.0595703	0.06
289.0412598	54.69
289.7228088	0.12
292.2625732	0.16
293.1729126	0.56
295.3275146	0.11
297.1588745	0.39
298.1350098	0.04
306.9809265	47.95
308.1259155	0.33
310.1585693	0.32
316.1677246	0.08
325.0737305	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	233.0438
Annotation	9-Hydroxy-4-methoxypsoralen
Peak:m/z	Relative Intensity
94.6798706	0.03
104.9745636	0.35
106.9834747	0.01
114.9899292	0.03
120.8151093	0.07
122.9403839	0.02
130.9415588	0.05
133.1056366	0.05
143.0810089	0.01
149.1255951	0.14
158.9562836	0.05
160.9337463	0.33
163.0011139	0.65
171.0062866	0.12
176.2317352	0.14
177.0156403	0.54
178.2313538	0.10
187.1569366	0.51
189.0982208	0.55
190.0057220	0.02
190.9755707	0.28
191.9379425	0.02
199.2530212	0.03
200.8406830	0.13
205.1084442	0.79
215.0703583	1.33
215.9658508	0.08
217.9910126	100.00
219.0432892	4.10
233.1185455	0.28
234.3023071	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1735
Annotation	Unknow
Peak:m/z	Relative Intensity
176.7784119	0.03
192.9409790	0.03
195.1313629	0.01
201.1950073	0.06
215.1007538	0.02
217.1345673	0.01
225.1776123	0.04
228.9188080	0.03
243.1123352	0.03
245.1383362	0.02
254.3698883	0.01
255.2469177	0.02
261.1660767	0.02
274.1425171	0.12
285.0391846	0.57
302.0612183	0.79
309.1145630	0.01
317.0809937	100.00
317.9198608	0.01
319.0527954	0.01
329.3797607	0.07
343.1291504	0.08
353.0708008	0.04
359.1585083	0.58
379.1461182	0.04
383.0664673	0.09
413.2090454	0.17
425.3903198	0.05
427.2125244	0.06
428.9978638	0.01
439.0319824	0.01
443.2130737	0.13
445.1854858	0.10
451.3615723	0.13
457.2418823	0.14
461.1861572	1.17
462.8942261	2.32
463.5141602	0.03
469.3159180	0.08
476.6315308	0.02
478.9594727	21.40
479.6953125	0.06
487.2457886	0.48
503.0962524	0.04
505.1894531	0.30
511.2717896	0.09
519.0678101	0.07
529.3871460	0.11
541.2178345	0.44
553.2848511	0.10
559.2312622	0.09
570.0725708	0.01
571.0171509	0.09
589.2225342	0.48
607.1229858	2.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1459
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
179.0076904	2.00
185.0516815	0.20
186.9383545	0.03
188.9212646	0.52
190.0498657	0.16
191.0103912	0.40
193.0684814	0.13
198.2522888	0.05
200.5833435	0.04
203.0605469	0.14
204.3108826	0.10
205.2104492	0.12
206.9861145	0.21
210.9711609	0.26
213.9269104	0.02
214.8230438	0.08
217.0704651	0.08
221.0625458	0.05
225.0803528	0.19
226.9742737	0.54
228.1173096	0.10
229.0125122	1.11
230.1777649	0.11
233.0865479	0.27
239.1320496	0.15
242.9956512	0.10
245.0875549	0.23
246.9009247	0.44
253.2440948	0.15
253.9662628	0.07
255.0789490	4.67
256.1652222	0.11
257.0712891	0.37
261.0019531	0.03
266.4542847	0.14
267.1556396	0.21
269.1216431	0.11
271.0521240	6.50
272.0733643	0.89
273.0990601	1.14
275.1469116	0.09
280.9586487	0.13
282.1648865	0.26
283.0708618	0.56
283.9121399	0.05
285.1156616	0.42
286.1370544	0.04
287.2039795	0.12
293.0164185	0.02
297.0077515	1.14
300.0800781	35.25
301.0736694	100.00
302.1037598	3.65
308.2070312	0.13
313.0531006	0.86
314.2113647	0.24
324.9951782	0.09
334.1788330	0.14
337.1265259	0.30
339.1967773	0.10
341.2028198	0.18
343.0794678	6.68
344.3525391	0.28
349.3352051	0.13
354.8616333	0.36
356.8098755	0.04
367.2599487	0.05
368.1360474	0.03
369.1590576	0.08
373.1717529	0.86
385.0088501	0.20
386.2348633	0.05
403.5321655	0.09
427.1795654	0.16
443.3656616	0.20
447.4819946	0.05
457.1036377	0.11
463.2874146	0.59
463.9902954	0.04
465.0564575	0.03
466.3217773	0.04
473.2713013	0.29
483.5364990	0.09
489.4378052	0.09
519.1275635	0.10
523.1333618	0.22
545.2068481	0.03
547.1461792	0.28
549.3500977	0.04
555.1816406	0.05
565.3222656	0.08
572.9594116	0.22
591.1466064	0.92
592.6061401	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
84.9379425	1.91
86.9344177	0.33
89.0085297	2.44
98.7775421	0.19
100.9512482	4.12
102.9107819	0.07
106.7622528	0.17
112.9848557	3.58
114.9459381	1.06
118.9252777	2.99
124.8851318	0.23
126.9945374	0.62
127.9379044	0.18
128.9876404	0.51
131.0030823	100.00
143.0560913	3.17
144.8307495	0.22
147.0772705	0.23
160.7803650	0.50
167.2782898	0.11
173.0386047	5.71
178.9254608	1.42
185.1327820	0.80
186.9368896	0.24
191.0892639	1.75
192.2566528	0.06
203.1465759	0.35
206.1519775	0.19
217.0056458	0.12
227.1314087	0.34
231.1568604	0.52
233.2429199	0.08
247.3528442	0.08
249.1217041	0.63
257.2511292	0.24
265.0592041	0.11
275.0928955	0.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	274.1432
Annotation	Ornazidine
Peak:m/z	Relative Intensity
91.3074417	0.03
116.8868103	0.06
119.9079742	0.04
122.2238693	0.01
132.1668243	0.14
134.9448853	0.02
145.9439392	0.04
148.1014709	0.05
152.6104736	0.12
154.0915527	0.04
159.9682465	0.15
162.0867004	0.01
171.4427338	0.09
172.1096954	0.28
172.8769073	0.04
174.1343231	0.07
175.9308319	0.20
179.2027283	0.09
184.7720642	0.14
190.1339874	0.57
191.1664734	0.04
196.2447815	0.05
198.8603210	0.06
200.2850952	0.07
202.0449524	64.70
203.1228027	0.36
204.3289490	0.09
211.0759583	0.02
214.2594299	0.11
216.0429993	0.81
218.0184937	0.13
224.1654968	1.17
225.0900574	0.07
226.1192017	0.22
228.2163086	0.02
229.0159912	0.05
230.1372070	0.07
232.1883545	0.11
233.0333557	0.01
238.3502808	0.04
239.1365051	0.01
241.3491211	0.01
242.3423767	0.24
243.9923096	0.06
256.1249390	100.00
257.0740967	0.23
265.2189331	0.03
274.1871033	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	257.07
Annotation	1D-1-Guanidino-3-amino-1,3-dideoxy-scyllo-inositol
Peak:m/z	Relative Intensity
125.0616150	0.05
131.1910706	0.28
154.2077026	0.12
156.0515289	0.06
170.7743988	0.04
173.0488892	100.00
186.0078888	0.06
195.2447052	0.07
200.4332581	0.04
211.2639313	0.23
213.0134125	0.15
215.1612091	0.02
229.1527863	0.02
233.3230591	0.09
238.8847656	0.11
240.0676270	4.26
242.1391144	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	576.0964
Annotation	Unknow
Peak:m/z	Relative Intensity
169.9878998	0.02
178.9741516	0.01
189.0309753	0.08
202.8401947	0.03
224.9845123	0.09
227.1815186	0.02
237.9851990	0.05
245.2099609	0.03
246.0218506	0.26
248.2509613	0.07
248.9434204	0.03
251.1712646	0.03
259.0197144	0.10
260.0208740	0.45
260.9847412	0.20
267.1518250	0.08
274.9561768	0.03
276.0152283	0.14
277.0270386	0.43
287.1555786	0.11
290.0496826	0.06
293.9413452	0.24
295.1080933	0.17
307.0574341	0.34
322.9341431	0.07
323.8428345	0.13
325.4367676	0.02
336.8419800	0.62
337.9317627	0.12
350.3574219	0.03
351.9910889	0.81
353.0608521	15.41
360.3011475	0.03
367.1539307	0.14
377.2987061	0.05
378.1944580	0.47
379.1420898	0.05
385.2170410	0.23
396.9595947	8.41
399.3000488	0.07
405.6329346	0.43
409.1861572	0.02
413.2387695	0.06
414.7905273	0.97
426.3415527	0.05
427.4044189	0.02
428.1966553	0.03
429.2540894	0.23
437.1419067	0.03
438.1899414	0.10
439.0538940	0.11
442.0226440	0.07
443.1816406	0.04
444.0346069	0.12
445.0141602	0.05
445.6729126	0.07
453.3020020	0.04
458.9386597	0.12
460.0032959	0.04
460.9162598	0.04
469.1526489	0.06
470.8607178	0.06
472.1181030	0.23
481.9158325	0.10
482.8895264	0.04
486.3249512	0.06
486.9718018	0.23
495.1980591	0.07
498.7611694	0.10
501.5056152	0.08
502.2159424	0.10
503.4970703	0.07
511.1479492	0.10
512.8970947	0.06
515.0646973	0.27
517.3463745	0.01
533.2454224	0.04
539.7921753	0.02
541.0460815	0.52
541.7712402	0.06
557.2144775	0.18
559.0104370	100.00
559.6621094	0.44
578.9199829	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	539.1379
Annotation	Unknow
Peak:m/z	Relative Intensity
160.8316650	0.39
173.0140076	0.04
179.0588379	1.17
184.9465637	0.03
197.0067902	0.05
215.3693390	0.03
221.1515503	0.30
250.2305298	0.03
251.0111084	0.05
268.8058777	0.07
281.0016479	0.38
282.0385437	0.03
293.1867065	0.02
294.1049194	0.12
305.2944946	0.03
322.9563599	0.05
333.3120728	0.09
341.0390015	1.80
354.2711792	0.06
355.4304199	0.09
359.0972290	0.09
377.2072144	10.51
383.2822266	0.91
392.1232910	0.06
405.2913818	0.11
413.1713867	0.06
441.5173340	0.06
442.9808350	0.39
503.1978149	100.00
503.8572998	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	487.1973
Annotation	Terretonin E
Peak:m/z	Relative Intensity
136.8938904	0.21
144.9768066	0.08
149.1334229	0.34
159.0328674	0.31
161.0904694	0.21
163.0678101	0.96
163.8253632	0.21
165.0899658	0.16
171.1464233	0.58
173.1494293	0.27
175.0832214	1.28
177.3660889	0.17
179.1234436	0.23
180.1683960	0.10
181.0250549	0.12
185.1908264	0.54
187.2006073	0.34
189.1748657	2.86
191.2452698	0.12
192.4316406	0.30
193.1601868	0.11
199.0901794	1.29
201.2212830	0.45
203.3283997	0.32
207.2980957	0.03
208.1218872	0.05
209.1323395	1.59
213.0259399	0.43
215.1538696	0.14
217.1395111	0.69
219.3274231	0.29
222.9867859	0.13
225.0765991	0.16
227.1194153	8.79
229.3423462	0.12
230.1483917	0.32
231.1298218	0.38
233.0167236	2.12
235.3111572	0.80
241.4260406	0.51
243.3930817	0.12
245.1772919	14.18
251.1864624	0.07
253.1896973	0.08
254.3136902	0.15
255.2061157	0.51
257.2291565	0.07
263.1693115	5.71
267.2634583	1.42
267.9320068	0.11
269.2245789	0.24
271.1548157	0.06
273.2192383	0.18
275.1371155	4.03
277.1062622	0.15
279.3522339	0.08
283.1437988	0.10
285.3034058	4.60
287.2351990	0.73
289.3287354	0.74
291.4061279	0.16
295.2162476	0.18
297.1489258	2.49
297.7631226	0.07
298.3923340	0.04
299.5397034	0.18
301.2601013	0.98
303.1956482	2.94
309.1148682	0.17
310.9518433	0.09
313.4326782	0.27
317.2831116	0.27
318.5966797	0.30
319.2772217	1.93
323.3072815	0.17
325.2557068	0.16
326.2584229	0.40
327.3234863	0.14
329.2642822	3.76
333.2410278	0.90
335.2581787	0.15
337.5515137	0.04
339.0041199	0.29
341.2348633	15.15
341.8397217	0.02
345.3426514	1.00
347.2880249	100.00
355.2751465	0.44
357.1998901	0.05
363.2460632	3.68
367.3872070	0.15
381.4532166	0.56
385.3937683	1.23
391.4065857	2.09
395.0303040	0.11
399.3858337	1.57
401.3190613	1.51
407.3380127	0.15
413.3551025	1.01
415.3579712	0.11
419.1020203	0.14
425.4024353	0.32
429.1006775	0.17
443.3398743	6.46
445.6245422	0.09
469.5697937	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	351.0721
Annotation	4-Methylumbelliferone glucuronide
Peak:m/z	Relative Intensity
110.9766617	0.39
118.9868317	9.36
119.8419647	0.02
128.9126892	0.06
137.0386963	0.22
143.0594482	0.79
154.9906311	0.24
162.9422302	100.00
169.0664062	34.80
173.0372467	0.16
176.1607971	0.04
186.8425903	1.38
204.9311218	4.99
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
78.86943054	1.55
80.79748535	0.58
82.84386444	0.24
85.29667664	0.93
89.01844788	0.30
93.04891968	0.60
95.0493927	1.60
96.9960556	1.36
98.99617004	0.54
101.1078339	0.10
102.95047	1.85
104.8838959	2.21
107.0467682	1.50
108.971344	2.18
110.1328583	0.29
110.9367523	1.33
112.84198	0.66
115.0458221	0.54
116.704422	0.20
117.7437439	0.33
118.8670807	0.93
121.1098938	3.81
122.6098328	0.69
123.2217102	2.17
124.7001038	1.09
126.9753723	13.23
128.9586945	8.45
130.016571	0.34
133.1378632	0.74
135.0226746	1.50
137.1242371	2.61
138.793457	1.02
140.9610901	1.82
143.0250092	0.21
147.15242	0.73
147.9870605	0.29
148.8854065	0.40
150.9879608	54.01
152.075058	1.44
154.1888885	1.57
155.0852356	0.94
157.164505	0.38
161.0488434	1.82
162.1862335	0.34
163.2182312	1.20
165.0318756	1.75
166.0951996	0.16
166.9499207	4.19
169.0107422	2.09
171.1571808	0.50
175.1295624	1.43
176.0127258	0.48
177.1301727	1.31
179.08815	4.78
180.8986206	0.52
182.003418	0.14
183.2332916	1.18
185.1772614	1.10
189.1293182	2.13
191.1739044	3.39
192.9856415	3.12
194.2876282	0.43
195.1243744	2.11
197.1122131	7.97
198.1009521	0.60
198.9452057	1.06
200.0352478	2.28
203.1552887	1.09
205.9677124	1.06
207.0572815	6.17
208.2570343	0.27
209.9620514	0.29
210.5815735	0.58
211.1952667	5.37
217.1859283	12.65
218.7835541	0.40
221.2859497	0.27
223.2468109	0.36
225.0455475	15.59
226.2395172	0.26
232.1516876	0.67
235.1442871	41.60
236.1777496	0.26
238.0807953	11.93
239.0271454	2.37
253.0891876	100.00
254.1233673	21.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	464.81
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8332977	3.15
295.0746460	0.06
296.7370605	33.65
297.3458252	0.19
302.8645935	0.06
329.0050049	0.12
344.8806763	0.12
363.0818481	0.23
378.5966187	0.84
380.5884705	100.00
381.4443054	0.57
446.4430237	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1741
Annotation	Epijasminoside A
Peak:m/z	Relative Intensity
94.8570328	0.35
105.0327301	0.46
107.0344696	0.54
109.9193573	39.59
119.1824722	0.49
122.1345901	0.07
123.9510117	0.55
132.9720917	1.39
134.1258240	0.47
135.3734894	0.67
136.0695343	1.30
137.9720154	7.47
144.9058685	7.00
147.0296936	0.11
150.9819641	4.99
152.0156250	4.84
156.0536346	100.00
159.1629639	0.12
163.1082153	0.25
168.5944824	4.79
169.8305969	5.15
170.4896240	0.33
177.0216980	60.22
178.2565308	0.09
179.7857208	0.10
180.7484589	0.09
182.0086060	2.72
183.3341827	0.23
184.8507538	0.39
185.9920044	0.53
186.7957153	0.17
190.5952606	0.11
195.9817505	0.57
197.0414276	0.09
200.9718323	1.00
203.0699463	0.28
203.9194641	0.16
205.1693573	0.14
207.1325989	0.10
208.1363220	0.09
211.3513489	0.52
217.1536255	0.34
219.2075195	0.61
219.8815308	0.10
227.1885681	0.35
228.9628601	0.31
230.3024292	0.13
231.2077942	0.16
232.4234619	0.86
237.8327026	0.16
238.7615051	0.14
240.1038513	0.95
243.1745911	0.59
249.8875732	0.07
254.1122437	1.03
254.9922180	0.06
256.1816406	0.57
257.9834595	0.09
260.2789917	0.15
261.3386230	0.09
268.9649963	0.47
270.4745789	0.21
272.3868103	0.25
275.7154541	0.38
278.2029724	0.64
279.0539551	0.23
283.9271851	0.56
286.0769653	13.03
287.1605225	0.32
287.9762268	1.19
288.9434814	0.25
289.9338989	0.14
290.7086182	0.45
297.0765991	14.31
300.0246582	0.94
301.4379578	0.22
305.1705627	0.12
307.7599487	0.10
310.3461609	0.09
314.2274780	68.26
315.0865173	42.56
316.3837891	0.65
317.1481934	0.99
320.3199768	0.16
322.7400818	0.22
323.3870850	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
172.1084595	0.39
174.3146515	0.29
176.1322021	0.15
179.1609344	0.10
195.976181	0.13
197.9714203	0.13
199.1106567	1.38
200.7598724	0.25
211.1386871	0.10
213.9010468	0.24
215.3014679	0.45
217.1281128	0.22
224.0673218	0.20
227.0841522	0.78
229.9896851	0.07
240.2758789	0.20
240.9653778	0.44
242.1372375	1.25
257.0945435	0.62
257.9503174	0.13
258.9473877	0.30
272.3019409	0.19
283.0960693	0.38
284.1400146	0.63
285.0726013	0.90
286.0921326	1.40
292.3564148	0.31
296.9657593	0.08
299.8657837	2.41
301.0830688	100.00
302.1347656	0.43
307.1152344	0.22
313.2633057	0.11
325.2866821	0.29
327.1221924	0.14
329.0795288	0.12
341.0772095	0.14
343.1851807	0.14
355.3004761	0.05
367.2643433	0.36
368.9672852	0.14
370.1394043	0.33
372.2129517	0.15
398.0687866	0.47
399.151062	0.31
400.2949219	0.09
404.1212769	0.16
411.6290283	0.11
447.1756592	0.16
448.2597656	0.47
464.8872681	0.07
471.0458374	0.50
477.5653687	0.09
489.2619019	4.57
490.3196411	0.09
513.3612061	0.40
519.1594849	1.19
549.392395	0.21
550.8146973	0.23
554.0004272	0.14
555.281189	0.37
565.2694092	0.33
573.6182861	0.13
591.2696533	2.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	203.0333
Annotation	6-Hydroxyangelicin
Peak:m/z	Relative Intensity
94.9256439	0.41
96.9734955	0.27
102.9726105	4.01
104.0840912	0.77
104.8940125	0.89
109.0892181	0.24
118.8907471	3.68
128.9715118	0.37
130.9007263	17.82
131.9312286	0.92
133.1430206	0.76
146.9210052	44.22
148.0347290	2.37
158.9374542	100.00
159.9999847	6.00
161.1508179	1.64
175.0074921	27.73
176.1704407	4.53
185.1059418	0.93
202.9374847	9.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	562.31
Annotation	Unknow
Peak:m/z	Relative Intensity
185.1767120	0.04
216.0565796	0.05
277.2724609	0.65
298.6422119	0.05
313.0653687	0.08
317.2595825	0.04
320.0137329	0.09
341.1082153	0.11
353.0984497	0.12
384.2074585	0.10
413.2327881	0.50
436.1487427	0.03
441.2638550	0.14
442.4692993	0.28
443.8176270	0.72
448.1003418	0.04
457.4713745	0.09
459.0724487	0.05
466.3404541	0.05
481.4199829	0.12
500.2069702	0.04
502.3021851	100.00
502.9885864	0.49
504.4005127	0.06
516.1897583	0.33
518.4896851	0.03
519.1892700	0.07
525.9441528	0.03
547.2396851	0.05
558.3434448	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.1558
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9596481	100.00
142.8183899	35.38
161.0296936	0.24
179.3041077	0.22
191.1727905	0.41
194.9829712	0.53
221.2137756	0.87
255.0147400	0.39
262.9645691	7.33
267.4790955	0.94
269.2387085	1.07
304.2333069	4.20
305.0155945	44.53
321.3657227	0.48
344.9449158	36.38
345.8144226	2.49
347.1983032	1.87
360.6273499	1.49
362.9695740	7.16
363.6042786	0.36
379.0695801	0.57
393.4312134	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.3696
Annotation	Allofusicoccin
Peak:m/z	Relative Intensity
193.1268158	0.14
221.1676178	0.10
225.2929382	0.39
229.8891754	0.30
232.2300415	0.29
232.9537506	0.21
242.9993286	0.07
253.2606506	0.10
287.1350098	0.34
299.6105347	0.12
311.2548828	0.05
327.2450256	0.24
337.2565308	0.18
338.0675049	0.08
339.4862671	0.18
340.1573486	0.07
343.2698975	1.34
349.1721191	0.35
353.3493652	0.10
357.7158813	0.23
365.4044800	0.30
367.5534058	0.75
369.5046387	1.55
373.1621704	1.97
376.2333984	0.15
379.3279419	0.81
381.4456177	2.91
383.2062988	0.75
385.2176514	0.13
387.3441162	3.41
388.6576538	0.08
391.3930054	0.27
393.7847290	0.64
395.5007935	0.47
397.5154419	0.08
399.3859863	5.51
400.2438965	0.67
401.4646606	0.66
402.4653931	0.17
407.3121338	0.72
407.9306030	0.09
409.5977173	0.08
411.3317871	3.08
412.4533691	0.18
413.4323730	1.59
414.3390503	0.07
417.6802368	0.21
418.5820923	0.17
419.4027710	0.06
423.3560181	0.59
425.4219360	2.87
429.3186646	11.84
430.3413696	2.26
431.2122192	0.59
433.4047241	0.31
435.5531616	0.12
437.7145996	0.85
439.6526489	0.11
441.4287720	1.58
443.5277710	2.76
445.6440430	0.25
449.0750732	0.05
449.7109375	0.15
451.3936157	4.19
453.3419800	0.64
455.3182983	0.10
457.3176270	0.86
459.3792725	0.66
461.3913574	0.89
463.3804321	0.40
465.4117432	0.21
469.4276123	6.52
470.4296875	1.51
471.3302612	44.27
472.1834106	0.43
472.8504639	0.14
477.4440918	0.16
479.5915527	0.55
481.2421265	4.39
481.8594360	0.14
482.7528076	0.58
483.4038696	3.07
485.1436157	0.26
487.2697754	2.54
488.5127563	0.31
489.7239380	0.18
491.4199829	0.11
493.3723755	0.87
494.4719849	0.33
495.2367554	1.44
496.4867554	0.12
497.1443481	0.14
499.4835205	16.06
500.3952637	1.75
507.2682495	0.06
511.4209595	0.51
513.2893066	1.42
513.9497070	0.15
514.7949829	0.76
517.4066162	58.31
518.4720459	6.27
522.9695435	0.16
523.5883789	0.36
525.5581665	1.23
529.3446655	0.93
530.6377563	0.13
531.4651489	0.45
533.0645142	0.92
535.2288818	3.63
537.1393433	0.08
541.3632812	0.44
543.3298950	1.41
544.3883667	0.42
545.5969849	0.35
549.4440308	0.90
550.3661499	0.07
553.4202881	0.77
557.2053223	0.20
559.5882568	0.16
561.4395142	34.69
562.4389648	1.19
563.2808838	0.30
565.4088745	0.30
571.4780884	15.78
572.3244629	1.46
573.4394531	5.90
574.4559937	0.91
575.5949097	0.37
577.4365845	0.28
581.0945435	0.30
585.4684448	0.58
587.7332764	0.20
591.4063110	100.00
592.3791504	9.36
593.3751831	0.48
595.2526245	0.28
601.4710083	0.78
603.2270508	0.44
605.4921875	2.10
606.2491455	0.11
613.5702515	1.10
614.4487915	0.15
617.1749268	0.26
619.4480591	1.62
621.4369507	22.85
622.3759155	1.06
625.2040405	0.41
631.5216675	2.45
632.8766479	6.26
633.6934204	0.30
635.2717896	2.62
643.3806152	2.31
646.9481812	0.13
649.4921265	5.66
650.5380859	0.68
651.6907349	0.53
659.5372925	0.39
661.4096069	46.84
662.4861450	7.19
663.5223999	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	433.1118
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
127.0137863	0.03
162.0345764	0.11
179.0597839	0.03
217.0166931	0.04
233.0626831	0.04
246.1010742	0.06
252.9400635	0.06
255.1825562	0.02
270.4894104	0.09
271.1279602	0.51
283.1318054	1.51
289.0361328	0.06
293.4249268	0.02
295.1385498	2.45
307.1289062	0.36
311.3109131	0.08
313.1005859	14.97
316.1220398	0.07
335.3847046	0.06
337.1043091	5.25
338.0582275	0.09
343.1541748	1.92
344.0316772	0.05
349.2845459	0.18
351.1611938	0.49
355.2423096	0.10
361.2432556	0.05
367.1095886	18.54
368.2496643	0.29
371.3114319	0.02
379.1910095	5.52
397.1528320	27.47
397.9551392	0.22
398.6534119	0.06
415.1727905	100.00
416.2829895	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.1788
Annotation	Claussequinone-(4->5')-vestitol
Peak:m/z	Relative Intensity
161.1007385	0.26
168.3145294	0.22
169.1027069	0.41
171.1907654	1.47
172.7710724	0.07
174.9069824	0.52
178.8421631	0.17
181.0586548	0.30
182.6043396	0.29
183.2575684	0.26
185.0593719	0.65
186.9745178	0.68
189.0859985	0.18
191.1372375	0.50
194.1564636	0.13
195.3191528	0.17
197.1597443	1.59
198.9642334	0.05
201.0132751	0.83
202.1112976	1.78
203.0165710	24.39
205.0200348	0.19
209.0604401	0.11
211.1054993	0.09
213.1146851	0.49
215.0667419	13.71
217.0667114	0.05
223.0980530	0.16
225.0467529	2.39
227.0274658	1.35
229.0972443	0.94
231.2894135	0.18
232.9980469	0.93
235.2785645	0.69
237.2388763	0.43
241.1845093	0.43
242.4717102	0.58
243.1936798	2.58
244.3426056	0.25
245.1369781	0.21
253.1374512	1.88
254.2168427	0.09
255.3162537	0.16
256.1719971	0.33
257.0393677	0.25
267.3395996	0.18
268.1454468	0.29
269.0104370	4.58
271.1746216	32.69
271.9844360	0.20
275.5479431	0.15
277.3294678	0.53
281.0574951	0.39
283.1077881	0.34
285.3280029	0.23
287.0729370	70.54
287.6788635	0.56
288.2945862	0.05
289.4243774	0.09
293.0659180	0.23
299.2026672	3.41
300.4368286	0.13
304.0592651	0.17
305.1131592	0.12
307.5341492	0.05
309.2819824	0.59
311.3747559	0.18
312.3893433	0.25
313.0659790	0.43
315.2525024	0.24
319.1743164	0.27
321.1771851	0.33
327.3559570	0.48
328.3790894	0.08
329.1752319	0.09
337.3047485	0.82
341.4146729	0.11
351.5421753	0.68
353.2751465	0.17
355.1992188	14.85
357.0303955	0.73
359.2799683	0.15
365.0808105	0.27
369.1734009	0.65
371.4459229	0.31
381.4904175	0.13
385.2747192	0.08
405.4956665	0.04
406.1837158	0.09
413.6060181	0.21
439.5190430	0.06
441.3395996	0.11
442.1898804	0.06
465.2185669	0.47
467.3973999	0.07
469.1409302	0.06
473.2342529	0.12
477.4873657	0.43
483.2823486	0.76
484.3526611	0.07
487.0060425	0.35
488.2843018	12.64
489.1763306	100.00
497.3373413	0.20
501.0947876	56.81
501.7647095	0.21
503.2203979	0.17
507.1681519	0.37
510.6034546	0.06
513.1149292	0.13
521.4156494	0.12
525.1253052	0.35
538.3214722	0.07
539.4665527	0.17
540.2576294	0.16
556.6723022	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.19
Annotation	BUDDLEOFLAVONOLOSIDE
Peak:m/z	Relative Intensity
189.1286621	0.02
192.1578979	0.02
207.0532837	0.27
215.3787231	0.09
277.3105469	0.02
285.1542969	15.57
287.0065308	0.20
288.2258911	0.16
301.0745239	0.05
317.1977234	0.23
327.1546021	0.05
335.1953735	0.02
344.9801025	0.06
346.8800659	0.09
351.347229	0.02
359.3562012	0.02
364.4067383	0.04
367.2293091	0.10
368.748291	0.05
369.3793945	0.04
371.2185669	0.14
377.3933105	0.03
387.3117676	0.12
395.276123	0.09
413.2253418	0.23
415.2642212	0.06
417.4407349	0.09
420.5148315	0.01
422.8903198	0.14
429.3530273	0.05
430.4949951	0.15
431.1633301	1.14
435.2956543	0.04
439.3657837	0.03
447.1379395	100.00
461.3225098	0.04
463.1385498	0.03
471.5021973	0.02
491.2614136	0.05
497.2562256	0.12
505.7573242	0.03
516.1366577	0.04
525.3930054	0.07
533.239624	0.01
549.3820801	0.14
552.1803589	0.05
557.2789307	0.22
561.4891968	0.01
565.4519653	0.07
575.173645	0.78
584.3568726	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	996.6625
Annotation	Unknow
Peak:m/z	Relative Intensity
493.4216919	0.04
521.3066406	0.10
527.2055054	0.07
649.2755127	0.28
751.7632446	0.12
847.0694580	0.10
943.4948730	0.20
955.6032715	0.14
961.7526855	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.09
Annotation	Phenytoin
Peak:m/z	Relative Intensity
81.11378479	1.36
83.03127289	1.42
83.97324371	0.75
85.05360413	0.39
88.82098389	0.69
90.54455566	0.10
91.2729187	0.32
92.91867065	0.30
94.90567017	2.25
96.98892212	0.22
98.96530151	1.15
103.0515747	1.29
104.9608765	0.65
106.9021912	1.10
108.8905334	1.05
109.8190918	0.64
110.969986	1.49
114.8758545	0.92
121.129364	2.99
122.9615479	1.69
124.0996094	0.19
125.1130829	1.60
126.9072723	12.23
127.9053345	0.24
128.9629059	5.67
130.0544586	0.33
133.0697784	3.13
135.144989	0.68
135.9492493	0.50
136.9319	1.24
139.0096741	1.92
141.0243073	2.67
142.9571991	0.81
145.1226044	0.91
146.9440918	2.14
148.9611511	1.15
150.9928589	58.10
151.9981232	4.20
153.0435028	0.72
155.1168365	1.95
157.0519257	0.54
158.8929291	0.54
161.121933	0.65
163.0430908	0.36
164.8847656	1.10
165.9623566	2.33
167.0157928	3.47
169.0094147	2.20
171.1258392	1.52
175.2159576	0.50
176.1529694	0.18
177.0325623	2.08
179.2402191	0.73
180.635025	0.63
182.0246429	0.13
182.9402313	1.73
185.0208282	1.10
186.0506134	0.67
187.1175385	0.27
188.2394714	0.39
189.1677704	2.20
189.8614349	0.12
191.0999908	0.24
193.1477966	1.33
194.2727814	1.55
195.1194458	2.50
197.0462952	7.47
198.2889099	0.24
199.2093201	0.98
206.4731293	0.63
207.1018372	5.88
208.8997345	1.23
211.1299591	5.08
211.8418427	1.21
217.2094421	14.17
220.8810883	0.65
223.2204742	0.60
224.0856018	0.56
225.1374359	12.52
226.2302246	1.06
231.2067108	0.43
232.905899	0.79
235.0592499	31.66
236.3207855	0.49
238.2683716	6.75
239.0995636	0.98
244.1148224	1.55
253.0990143	100.00
254.1658173	16.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	693.2834
Annotation	Orthosiphol L
Peak:m/z	Relative Intensity
197.2018890	0.39
198.0242310	0.05
200.0542603	0.05
202.0693970	0.23
203.2203674	0.07
205.1163330	0.09
206.2375336	0.07
209.2059784	0.13
210.1047363	0.24
212.0180511	0.14
213.2821655	0.06
214.0894012	0.41
215.1947784	0.15
216.0775299	0.02
217.1175690	0.03
220.9973602	0.56
221.9263611	0.16
224.1666718	0.02
226.0895233	0.25
227.0346527	0.15
227.9450836	0.03
232.2865906	0.19
235.0312805	0.07
238.0896149	0.90
238.9197083	0.08
241.1871948	0.07
242.1583862	0.31
244.1958923	0.33
244.9941406	0.07
250.3083496	0.27
255.9524994	0.93
257.2882385	0.24
258.1129456	0.23
259.9570007	0.09
262.2064514	0.05
263.0457764	0.37
264.1715088	0.07
268.0761719	0.18
274.1630554	1.68
275.3317871	0.09
276.3030090	0.09
278.0695801	0.03
280.0126648	0.04
280.9827271	0.29
283.0493164	0.04
286.1747437	0.09
287.0352173	0.78
292.2226562	1.26
292.9314270	0.09
294.3050842	0.15
297.8345947	0.14
304.1508789	0.41
305.0960693	0.33
306.4244385	0.02
307.0802612	0.13
308.4258423	0.04
310.4381104	0.51
311.0641479	0.04
317.1170654	0.12
317.8973389	0.14
320.3766479	0.10
321.2360229	0.11
322.3252563	0.85
323.1094971	0.21
328.2125244	0.13
329.1062622	0.17
334.1264954	0.23
335.2725830	0.87
336.1865234	0.28
338.2498779	2.31
340.3547974	0.25
341.1290588	0.24
342.3008728	0.12
346.0621338	0.12
347.2212524	0.07
348.1802368	0.03
350.3053589	0.21
352.0946655	0.28
353.1056519	1.18
354.3973999	0.03
358.5044556	0.08
360.3652344	0.20
362.1901245	0.65
364.0819092	0.07
366.0592041	0.03
369.0833740	0.62
372.2540283	0.31
374.0018921	0.06
376.1131592	0.08
377.4785156	0.04
380.2896118	1.28
382.2968750	0.10
384.0882568	0.22
385.1223755	0.02
386.3432617	0.38
388.0977173	0.20
389.2701416	0.39
394.9386597	0.04
398.5011597	0.26
400.4735718	0.07
404.1044922	0.96
404.8505249	0.02
406.1531372	0.11
407.3351440	0.09
411.5773315	0.15
415.4047852	0.12
416.2119751	0.22
422.4264526	0.11
428.2224121	0.16
429.9059448	0.04
431.1897583	0.42
432.3729858	0.05
434.3051147	0.51
435.0528564	0.08
437.5065918	0.12
438.4785767	0.14
440.1049194	0.07
446.2992554	0.89
449.3906860	0.09
452.1437988	0.62
454.0192261	0.02
456.1759644	0.03
458.3071899	0.03
461.9171143	0.17
464.2988892	3.19
465.3280029	0.06
470.2585449	2.37
472.0261841	0.10
476.3023071	0.20
480.2661743	0.29
482.2836914	4.75
483.3042603	0.04
486.4462891	0.16
488.2098999	2.23
489.0404663	0.19
494.4367065	0.39
495.3840332	0.23
498.0885620	0.14
500.3087769	1.21
506.1936035	0.22
513.2391968	1.06
516.1110840	0.04
517.3858643	0.05
521.5328979	0.04
524.2809448	0.16
528.3489380	0.19
531.2506104	100.00
532.4111938	0.32
534.0562134	0.10
536.2037354	0.07
542.2321167	0.13
548.3203735	0.03
549.0328979	0.06
553.9935913	0.02
555.4602661	0.28
560.3136597	0.27
561.1600342	0.22
562.5718384	0.06
566.0151978	0.03
568.6397095	0.03
573.3150635	0.90
578.1388550	0.59
580.7848511	0.04
585.2817993	0.51
588.3037109	0.10
591.5349731	0.02
595.2834473	0.06
596.4195557	0.26
597.3165894	0.03
601.2440796	0.04
603.3187256	0.03
606.6585083	0.03
607.3107300	0.06
608.3541870	0.02
610.2566528	0.08
611.8026733	0.26
614.3381348	1.28
619.7197876	0.12
621.4170532	0.05
626.1829224	0.04
631.6166382	0.23
632.4694214	0.66
635.4761963	0.12
637.3594360	0.03
639.6114502	0.18
644.4195557	0.15
647.2827148	0.23
650.2120361	0.82
657.1867676	0.79
657.8662720	0.06
662.4429321	0.19
663.4618530	0.11
664.2650757	0.04
674.7543335	0.53
675.3981323	2.09
676.4385376	0.27
678.8971558	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	841.3077
Annotation	Unknow
Peak:m/z	Relative Intensity
301.0881348	0.15
331.2636414	0.07
344.0894165	0.05
471.2084961	0.65
494.9509888	0.04
543.4804688	0.05
557.4689941	0.16
563.3179932	0.14
574.2382812	0.05
615.1292114	0.02
621.1521606	0.03
649.4274902	0.13
676.6679688	0.04
679.1204224	0.21
695.2500000	0.02
697.5860596	0.13
702.4755249	0.02
750.8825073	0.25
761.3081055	100.00
762.0224609	0.22
795.3380737	0.12
805.1320190	28.09
805.7529907	0.09
807.7503662	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1142
Annotation	Lactulose
Peak:m/z	Relative Intensity
179.1192322	0.02
225.2598267	0.05
323.1797485	0.02
341.1378479	100.00
355.3491821	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.22
Annotation	Safghanoside C
Peak:m/z	Relative Intensity
205.3599701	0.04
221.3887024	0.02
235.0528870	0.06
259.2935486	0.02
285.0599976	0.05
312.9610596	0.02
329.5720520	0.04
337.2598267	0.17
347.4310303	0.02
357.5361328	0.02
360.2822876	0.04
363.2926025	0.03
369.3715210	0.03
372.2648926	0.08
373.2225952	0.05
375.5352173	0.01
379.4656982	0.02
393.3208618	0.05
414.4793091	0.02
431.2602539	0.08
438.9352417	0.04
439.6317749	0.02
454.4728394	0.02
459.4174194	0.01
463.3048096	0.05
464.3726196	0.04
465.4494629	0.04
473.1351929	0.03
475.3198853	0.26
477.3092041	0.01
483.2202759	29.07
483.8464966	0.07
489.2137451	0.02
508.3033447	0.03
509.3909302	0.05
515.4827271	0.01
519.3364868	0.03
525.2467651	1.84
527.2037354	0.56
533.2481689	0.11
550.6099243	0.02
565.4865723	0.08
567.2453003	0.04
569.3184204	0.03
580.1696777	0.05
582.6398315	0.01
584.0153198	0.03
585.3179321	0.19
589.4592285	0.05
608.1077881	0.16
623.4644165	0.04
624.1183472	0.01
627.1337280	100.00
627.7599487	0.54
635.3279419	0.03
653.1015015	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	396.1274
Annotation	Unknow
Peak:m/z	Relative Intensity
131.0677185	0.04
135.0420837	0.13
135.9725952	0.07
149.8038330	0.06
166.1902161	0.04
181.0892029	0.02
189.1973877	0.04
198.5298309	0.02
199.2153015	0.04
200.8668213	0.03
204.0093994	0.05
231.0375366	0.04
234.0407410	100.00
235.1602173	0.22
241.8652344	0.04
252.3737488	0.01
254.1783752	0.07
259.2167969	0.11
276.0783081	0.13
280.6719666	0.20
284.8296509	0.02
294.0022583	0.02
299.3734741	0.05
305.8348083	0.08
309.3400269	0.02
330.1526794	0.06
335.6871338	0.02
337.3696899	0.14
338.1358032	0.04
340.6870728	0.25
350.4232483	0.06
352.2751465	0.09
352.8796997	0.02
355.1648865	0.18
360.2231445	0.23
361.3480530	0.10
363.0227966	0.05
368.4397278	0.09
378.1790466	1.35
379.2338257	0.22
384.0968018	0.05
387.3375549	0.31
388.4110413	0.12
396.3077698	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.3992
Annotation	Dianthin D
Peak:m/z	Relative Intensity
210.0414124	0.08
210.9559479	0.31
212.1724701	0.87
213.2062683	0.80
213.9521790	0.06
217.0550079	0.03
219.1776886	0.05
223.9158936	0.14
224.5249939	0.03
233.2336884	0.21
237.0633240	0.05
242.1298981	0.25
245.4164734	0.41
247.3434143	0.09
249.0052490	0.04
251.3864441	0.11
252.1540833	0.08
253.1570435	0.12
254.1765900	0.09
257.0759888	0.03
258.6181641	0.16
259.3911743	0.08
261.0219727	0.16
262.0584717	0.03
264.2244873	3.11
269.2817688	0.02
270.1785278	0.06
272.9383850	0.29
273.9902039	0.81
274.5967102	0.01
276.6638184	0.05
279.0285034	0.35
281.0101929	0.22
282.2391968	9.64
283.1730347	0.03
288.9717712	0.03
290.3538818	0.12
292.1600952	0.25
293.2862549	0.16
296.3182068	0.04
299.2342834	0.30
300.1570435	0.10
301.8487549	0.24
307.2044373	0.59
307.8767090	0.09
309.2092590	0.35
311.2640686	0.07
314.3130188	0.04
317.5294495	0.28
318.2617798	0.78
320.4402466	0.22
321.2777710	1.13
323.3649902	0.08
325.2651978	0.06
329.2087708	0.36
333.2833862	0.03
338.0804443	0.29
339.2775879	3.69
341.9068604	0.16
344.1370850	0.13
348.8018188	0.06
351.3035583	0.10
352.0238647	0.04
356.2444458	3.52
357.2698975	0.04
357.9697876	0.07
358.9241943	0.12
359.5748291	0.17
360.3737793	0.11
361.1801147	0.49
366.8589478	0.26
367.5187378	0.03
370.6309814	0.07
371.2653809	0.29
374.3480835	0.11
377.3604736	0.25
378.3878174	0.10
380.3229980	0.05
382.2701416	0.13
385.8980713	0.03
387.0421143	1.10
387.9180908	0.07
389.1671753	1.04
393.5030518	0.12
395.2953491	0.96
395.9435425	0.05
397.2671509	0.03
398.2545776	0.11
399.0775757	0.06
403.3081665	0.86
405.2438354	0.43
406.9801636	0.07
413.4827881	0.03
415.0197144	1.08
415.8414917	0.18
417.2775879	0.18
421.3439331	0.16
424.5098267	0.23
428.5632324	0.08
431.1600342	1.69
436.2370605	0.08
437.2886353	0.12
438.1884155	0.09
440.1499634	0.39
441.2492676	0.13
442.0972290	0.11
443.4828491	0.12
445.3093262	0.18
449.3289795	0.04
452.3586426	0.20
454.6912842	0.11
455.5330200	0.40
456.3045654	0.32
458.2595825	4.13
459.0661011	0.14
460.4424438	0.02
462.2368774	0.07
463.1135864	0.08
465.8742676	0.12
466.9038086	0.06
468.3256836	3.34
469.2296753	0.15
470.4556274	0.26
471.6542969	0.33
472.2560425	0.38
474.4147339	0.63
479.1893311	0.55
483.9169312	1.08
484.7037964	0.91
486.1744995	20.31
490.3114624	0.20
491.4747925	0.11
492.1867065	0.07
497.4772949	0.15
500.2258911	2.65
500.8393555	0.02
501.6630249	0.25
502.3978882	0.46
503.5192871	0.11
508.2640991	0.34
509.9023438	0.29
510.6175537	0.08
512.1432495	0.16
513.3928833	0.14
517.3409424	0.04
518.5079346	0.58
520.3540649	0.40
523.3493042	0.05
524.6549683	0.11
526.0595703	0.04
528.1304932	0.53
528.7648315	0.03
529.8052368	0.09
532.4308472	0.22
536.5397949	0.07
537.5298462	0.10
541.1071777	0.27
542.3491821	0.11
546.1835327	0.10
547.3746948	1.19
549.4758911	0.20
550.4822388	0.14
553.4912109	0.10
554.5335083	0.36
555.4646606	0.03
556.1911011	0.04
563.4326172	0.43
565.4749146	1.98
568.2748413	0.57
569.4442749	0.68
570.2811890	0.03
571.3898315	2.94
572.1931763	0.03
573.9486084	0.11
579.3497925	0.32
580.1930542	0.08
581.3887329	3.34
583.4461060	3.24
585.3092651	0.05
587.4929810	0.94
589.0398560	0.10
592.2745361	0.27
597.2882690	6.75
598.4200439	2.14
599.3500366	30.54
600.1564331	0.05
602.6983032	0.06
605.2072144	0.04
607.4848022	0.20
609.2741089	0.33
609.9050903	0.04
611.3690796	0.05
615.3139038	10.54
615.9304199	0.08
616.5745239	0.10
619.2033081	0.04
625.4142456	0.93
631.2843018	0.15
637.5069580	0.23
638.3947754	0.11
639.3438721	0.11
643.4952393	0.27
648.7499390	0.38
649.5917969	0.07
650.4417114	0.29
655.4482422	0.40
658.4898682	0.17
659.9464722	0.18
664.3645020	0.96
666.3920288	3.16
667.4222412	1.45
668.5886841	3.26
674.2410278	0.07
676.4118042	4.58
677.3959961	0.13
680.7906494	0.08
682.4588013	0.03
684.4075317	100.00
685.1105347	0.36
694.3793945	65.12
695.5422974	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	601.1381
Annotation	Unknow
Peak:m/z	Relative Intensity
178.9284210	2.24
198.9925842	0.87
241.2173157	0.18
259.0729675	26.50
299.2588501	0.18
323.0212402	0.45
341.0983887	3.53
368.8615723	0.40
383.0922852	30.86
399.2880249	1.03
421.2371216	3.79
424.3851318	1.46
425.2570190	0.71
429.2503662	1.20
431.3126831	0.29
439.1555786	23.77
443.2094116	4.08
454.7376099	0.40
462.1676025	0.46
468.1934204	0.90
469.4035034	0.12
485.1203613	0.26
503.2722778	100.00
517.2413940	5.08
523.2160645	0.65
541.5603638	1.19
555.0645142	9.96
555.6829224	0.28
583.2927246	40.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.2341
Annotation	Unknow
Peak:m/z	Relative Intensity
205.1276245	0.34
206.3689270	0.35
207.2324219	0.48
215.1208191	1.12
216.2674255	0.24
219.1983948	2.27
220.1444244	0.82
221.2503052	1.37
229.0880890	0.17
233.1041870	0.49
239.2724609	0.36
241.3940887	0.29
242.9393463	0.26
243.9914703	0.29
245.0726013	8.65
246.0339661	4.11
247.0692749	6.73
248.2079926	1.44
249.2513580	0.61
262.9536743	1.34
265.0203247	18.04
266.3501587	7.46
267.2960205	2.87
271.1261292	0.63
276.4309998	0.85
277.2423096	1.67
278.0974426	3.00
279.1196289	0.82
283.1222534	5.06
284.1506348	2.92
285.3137207	0.82
287.2089844	0.50
288.0227356	0.38
289.0876770	3.72
290.1578369	1.79
291.2147827	1.09
297.2930908	0.17
305.0884399	28.94
306.1553650	19.77
307.0782166	8.46
311.0858765	0.58
312.3236389	1.02
315.0571899	0.16
317.1499329	3.01
318.2362671	0.40
319.0861816	0.68
321.1119995	1.05
322.3068237	0.36
323.2325439	0.63
324.3912964	0.56
329.0598755	2.08
330.2041626	0.58
333.1232300	0.14
337.0437927	5.96
338.2029419	5.87
339.1041870	4.18
342.9482422	0.32
346.7287598	0.33
349.2247314	2.47
350.0908813	1.33
351.2778931	0.69
352.3661804	0.24
353.1395874	0.33
357.3692627	0.57
359.4687500	0.74
360.3134155	0.34
361.1444702	0.48
362.2179565	0.60
366.1950684	0.39
371.2105103	1.39
372.0742188	0.17
377.1491089	3.31
378.0786743	3.27
378.9918823	3.30
379.5975342	0.26
382.5047607	0.37
383.4412231	1.77
385.1436157	0.26
389.1885376	0.30
397.2121582	23.20
398.2469482	19.58
399.2052612	14.72
401.0397949	0.37
402.2702637	1.49
403.1082153	1.94
404.8665771	0.26
406.2157593	0.44
409.0656738	0.73
410.3109741	0.60
411.1087036	4.02
415.2528687	11.67
416.2252808	11.11
417.2017822	7.12
419.0742188	0.26
425.0651855	0.22
434.1465454	0.74
437.3693237	0.63
438.2985229	1.81
439.3778076	0.55
440.2550659	0.60
443.7852783	0.24
445.3143311	0.58
449.1874390	14.44
450.1854858	12.77
451.2340698	11.38
452.1398926	0.54
453.2774658	1.18
454.2474976	0.61
457.0981445	0.61
458.2413330	0.88
469.5863037	0.22
470.3724365	1.27
474.3200684	0.75
480.7684326	0.14
481.3753662	7.84
482.2048950	5.08
483.2213745	3.90
485.2951050	0.47
486.1196289	4.29
487.2866211	1.92
491.3068848	3.87
492.2944946	1.34
493.2905884	2.29
495.9853516	0.92
509.2312012	0.30
510.7602539	0.63
511.6634521	1.74
512.4616089	6.34
513.5123291	3.13
524.2736816	0.66
527.4287720	0.78
529.2529907	7.36
530.2945557	8.29
531.2891235	12.40
537.4096680	0.21
539.3734741	0.59
546.3546143	0.91
547.0276489	0.54
555.0935669	0.89
556.2144165	3.94
557.2800903	0.51
561.2653198	3.33
562.2944946	6.41
563.3150024	0.72
574.3290405	0.15
587.3309937	0.77
588.2572632	0.69
589.4257202	0.91
604.3036499	3.20
605.0809326	0.25
606.6097412	3.85
607.5785522	0.76
620.8229370	1.10
629.2829590	0.15
658.2669067	0.37
659.2479858	0.54
661.3152466	6.17
662.2590942	34.29
663.2437744	33.99
678.2483521	3.85
679.2489624	5.86
688.3390503	0.85
689.2462769	0.23
694.4168091	4.50
695.3061523	5.98
705.1797485	8.98
706.3544312	100.00
707.2653809	99.64
708.3040771	0.21
720.3139648	0.71
721.3839722	4.89
722.1929321	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	932.4458
Annotation	Unknow
Peak:m/z	Relative Intensity
634.5166626	0.13
713.5603638	0.15
723.0044556	0.04
758.2764282	0.10
804.0080566	0.38
812.3978882	0.12
842.0427856	0.05
856.1892700	0.07
866.4708862	18.01
878.3764648	1.09
896.3009033	100.00
897.0112915	0.32
902.4161377	0.07
914.3966064	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1615
Annotation	Butrin
Peak:m/z	Relative Intensity
185.3332367	0.04
198.1302490	0.20
199.2129822	0.03
200.3253021	0.07
201.2276306	0.06
214.8704224	0.06
219.1317749	0.07
227.1780853	0.30
227.9684143	0.21
232.3292542	0.05
242.1508484	0.09
243.0440369	0.33
243.9803162	0.30
247.3899994	0.02
253.1105652	0.11
253.9984131	0.36
255.1221771	3.91
256.1495667	0.20
259.3358459	0.16
265.1246643	0.03
271.0801392	5.90
272.0658264	1.11
273.1625977	0.07
282.9409790	0.06
284.0075684	0.08
285.0834656	0.12
287.0785217	1.03
289.3933105	0.12
297.0428467	0.12
298.1448975	0.11
300.0891113	20.55
300.9777222	0.07
312.6158447	0.16
313.2301636	0.64
314.1853027	1.67
315.1105347	100.00
316.1819458	0.59
317.0405884	0.14
323.2415161	0.04
325.1296387	0.07
328.2035217	0.04
329.2568970	0.10
341.3800049	0.02
342.6015015	0.04
355.2366333	0.05
357.0752563	1.06
369.3137817	0.18
382.9825439	0.70
386.9992676	0.02
389.0628052	0.11
413.2028809	0.15
422.9907837	0.02
461.2751465	0.17
478.9346924	0.09
485.3986816	0.03
503.2648315	1.10
515.4071655	0.10
521.2898560	0.04
533.2250366	0.07
563.5337524	0.18
579.4470825	0.19
591.2632446	0.07
595.2239380	0.48
605.1884155	0.39
608.0518799	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	766.71
Annotation	Unknow
Peak:m/z	Relative Intensity
218.8905029	0.15
229.2651520	0.13
230.9997864	0.65
233.2476807	0.23
240.9761200	0.15
247.0800629	0.23
248.9073334	0.33
255.0007782	2.04
264.9727783	0.49
268.6828308	0.35
269.3538208	0.16
270.8402405	0.10
272.4316711	0.28
275.0462036	0.16
278.9600525	0.30
284.9061890	10.88
286.0262451	0.54
287.0195923	0.06
288.7785034	0.36
304.9031982	0.13
312.1224365	0.62
313.0268250	0.28
315.3479004	0.25
322.1922913	0.08
322.8926392	5.55
325.0796814	2.38
331.2094421	0.30
332.2210693	0.23
339.0616455	0.08
340.8770142	0.13
342.5192261	0.74
343.1694336	0.13
362.9623718	0.32
368.2864380	0.81
369.1212769	0.56
377.2543945	0.20
378.0043335	0.68
379.0756226	0.12
381.1884155	0.24
381.8413696	0.09
387.0379028	0.16
397.0073242	2.00
397.9488525	0.18
399.0214844	0.11
400.8262939	0.74
401.5168457	0.06
403.3488770	0.10
404.6324463	0.11
416.3155518	1.00
416.9486694	6.36
418.8421021	0.62
420.4998779	0.07
427.2133179	0.58
434.4354248	0.59
435.5225220	0.62
437.0196533	0.48
443.1558838	0.39
444.2458496	2.71
445.2266846	0.34
454.6613159	0.81
456.9976807	1.98
462.9777222	6.37
463.6033325	0.13
464.3251343	0.37
471.2048950	0.53
472.7931519	1.52
474.1441040	1.05
474.9797363	3.59
481.2882690	0.22
482.3280640	1.83
491.9392090	1.97
493.2586060	0.13
494.5614014	0.12
495.1959229	0.18
500.1918335	0.32
508.1682739	0.26
510.1585693	4.83
511.1117554	0.18
515.7877808	0.44
517.7965088	0.13
519.2553711	0.39
520.0797729	1.10
522.8211670	0.08
528.9793091	6.88
529.9653320	0.67
539.0185547	12.57
539.8216553	0.85
541.2022705	0.05
543.1740723	0.29
548.2227173	0.98
549.0018921	2.54
550.8075562	0.43
557.9967041	11.17
559.1498413	0.34
576.3394165	0.66
577.1328735	0.31
577.8458862	0.10
585.1701050	0.10
586.7047729	1.45
588.2005005	0.60
589.1748657	0.73
594.1408691	0.45
595.0884399	6.12
596.0210571	1.12
596.8830566	0.19
600.2108154	0.06
601.3473511	0.31
603.2496948	0.10
605.0806885	11.27
606.5929565	12.87
607.3498535	0.90
608.3214722	0.38
614.3173828	0.25
615.0880737	1.79
620.4519653	0.06
624.0338745	18.99
625.3670044	1.35
626.7338257	0.29
633.3480835	1.23
634.0964355	11.39
634.8547974	0.27
635.5806274	0.06
638.2283936	0.21
641.0116577	0.86
641.8599854	0.13
643.0256958	0.38
644.5817261	0.05
647.2855835	0.07
659.1250610	1.42
661.1593628	42.20
661.8908691	2.14
663.0214233	0.54
664.4686890	0.17
666.6952515	0.18
670.9603882	5.53
672.0092773	2.08
672.8545532	0.14
681.1516724	2.09
681.8369141	0.49
682.4911499	0.04
685.3965454	0.14
690.0193481	25.57
691.0429077	6.51
691.8908081	0.73
693.3212280	0.14
699.4287720	2.26
700.0857544	28.74
701.1401978	0.84
702.2271118	0.41
703.3138428	0.17
704.3632202	0.28
706.3701782	0.50
709.2159424	0.07
710.1151123	0.08
718.5609131	0.65
720.2140503	0.48
721.0765991	0.29
722.1520386	0.06
735.1054688	0.12
737.1148071	0.54
738.7740479	6.44
740.0072021	0.74
740.8835449	0.48
742.9055786	0.47
747.9437256	0.78
773.1058960	0.51
775.2217407	0.30
789.4749146	0.06
791.3219604	1.66
793.1093140	100.00
794.3467407	0.96
795.0610352	0.46
812.7482910	0.89
830.9530029	0.72
851.2448730	1.04
870.6304321	1.21
888.9258423	0.36
904.7346191	0.17
906.2625122	0.38
907.1989136	0.68
908.6165161	0.31
923.2111816	1.04
925.0957031	68.84
926.0083618	2.15
927.3439941	0.12
942.6701050	0.05
944.8583984	2.90
962.9498901	1.14
965.1444702	0.45
982.5847168	1.45
983.2600708	5.05
984.1837769	0.16
1000.8303830	0.09
1021.3923950	0.04
1022.7199710	0.20
1055.3426510	0.09
1057.1201170	1.78
1058.1286620	0.26
1059.1159670	0.89
1059.7944340	0.06
1074.9520260	0.07
1075.8149410	0.37
1077.0039060	3.27
1078.0639650	0.38
1095.1777340	1.46
1097.0268550	0.49
1114.0429690	1.00
1115.0585940	13.88
1116.4410400	0.67
1117.0710450	0.77
1132.8261720	0.21
1190.3125000	0.22
1209.0541990	1.00
1210.9128420	0.30
1246.3516850	1.07
1247.0631100	10.12
1247.7896730	0.66
1248.6539310	0.37
1266.8785400	2.84
1267.4891360	0.66
1379.0728760	1.94
1398.7106930	1.51
1399.3725590	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1606
Annotation	Claussequinone-(4->5')-vestitol
Peak:m/z	Relative Intensity
186.1167297	0.20
223.8442535	0.05
225.1987000	0.25
240.2044830	0.28
265.2257996	0.17
271.1717529	4.85
293.1789856	0.23
296.1275635	0.05
303.1006470	0.13
309.1390991	8.04
313.2109070	0.22
321.1651611	0.05
355.1484985	0.15
358.7968140	0.18
363.2318115	0.19
373.0415649	0.10
377.2294922	0.53
381.3139038	0.18
415.3075562	0.12
433.1300049	29.99
443.1958618	4.03
459.5540161	0.18
460.2473145	0.07
460.9539795	0.12
464.3132324	0.28
477.2350464	0.16
478.4912720	0.06
483.5512085	0.14
485.4879761	0.21
491.8031616	0.25
494.6433105	0.12
510.1526489	100.00
511.2243042	72.66
512.4283447	0.23
516.4837646	0.19
520.1702271	0.27
531.6707764	0.10
535.3948364	0.13
543.1737671	0.65
551.5737305	0.22
552.1801758	0.19
561.2288818	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.15
Annotation	Bakankoside
Peak:m/z	Relative Intensity
112.1261444	0.04
115.8521957	0.10
122.9657898	0.62
124.9593506	0.06
126.8228912	0.03
132.6498413	0.11
138.7652130	0.14
148.0510254	0.04
148.8339233	0.20
150.9926453	1.47
152.8427124	0.10
154.1383362	0.09
156.8952026	0.08
160.9038086	1.39
166.8924561	0.08
170.9939270	0.03
175.1598663	0.08
178.0496368	0.60
178.9845276	15.29
185.0071869	0.01
191.0805054	0.17
192.0420532	0.04
193.1395569	0.11
196.0038910	100.00
197.2884521	0.02
201.8510590	0.03
203.1163330	0.42
206.3467255	0.03
207.0763245	0.02
208.0958862	0.94
212.0487061	0.07
214.0062561	0.02
214.8979492	0.05
218.9799500	0.03
219.9214783	0.26
221.0948792	0.18
227.1751404	0.06
229.0732422	0.04
232.2567749	0.06
235.1067505	0.11
238.1899719	1.06
239.1524658	0.04
241.8763428	0.22
243.2365723	0.02
245.0464783	0.75
254.0166626	0.05
256.9754944	0.07
262.1167908	2.56
262.9469604	0.08
267.9076843	0.06
268.9971924	0.17
274.2771912	0.40
275.0677795	0.56
279.0709229	0.23
280.1405640	0.22
282.9723206	0.01
286.1300659	0.53
287.0187988	0.36
288.1644897	0.07
289.0545654	0.05
292.1645508	2.12
296.2684326	0.02
297.2395630	0.07
298.8961182	0.05
301.2000122	0.14
304.2637024	1.34
305.1270752	1.22
312.1458740	0.15
312.9826965	0.05
316.5411377	0.07
322.1206970	4.74
323.0435791	2.08
326.7363892	0.22
327.3820190	0.10
340.2123718	14.73
341.1987610	0.14
344.3420105	0.03
349.0870056	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0851
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.81924438	0.26
78.93883514	0.61
81.00067139	0.37
85.08885956	0.62
90.94008636	0.82
92.8734436	0.75
95.05923462	2.95
96.98048401	1.31
98.70687866	0.20
100.7881317	0.13
102.9303436	2.00
104.6136475	0.21
106.9397888	0.63
107.9839478	0.25
109.1389618	0.85
109.7548218	0.21
110.9212036	1.05
113.0965118	0.39
114.7256775	0.41
115.4191132	0.54
119.2210693	0.28
120.9924316	1.57
122.9607849	3.57
125.050415	1.59
126.9296722	9.62
128.9230804	4.61
130.2089539	1.93
135.119278	1.91
137.1100464	1.25
139.20755	0.74
141.0565186	1.09
142.9618835	0.10
147.155899	0.71
150.9224701	51.35
151.974823	5.51
153.1482697	1.02
153.9341278	0.31
154.8829803	1.64
157.0458221	0.92
159.1704254	0.16
161.0821686	1.85
163.0185852	0.51
165.0500946	0.99
166.0406036	0.35
167.0563202	2.15
168.0553436	0.88
169.0511627	1.14
170.7691498	0.73
172.1021576	0.44
173.1780243	0.25
175.0251617	0.53
175.696579	0.31
177.0861664	2.92
179.0574493	2.89
179.9762726	0.47
181.0536346	1.64
182.2033234	1.52
183.1125641	1.67
185.1418152	3.06
189.0563049	1.67
190.3029022	0.18
191.167984	0.13
193.1056976	1.56
194.1200562	1.52
195.1943512	1.02
196.4590607	0.70
197.108429	4.24
199.2030792	0.93
205.2094269	0.83
206.8952637	4.83
208.247879	0.46
209.1476593	0.79
209.7960815	0.16
211.1191559	5.46
217.2311249	8.04
221.1714478	0.17
223.1554718	0.60
225.160965	10.95
226.1241608	0.83
235.1024323	33.32
238.1741943	10.90
238.9640045	2.01
244.2426147	2.24
251.383728	0.77
253.0876923	100.00
254.0487061	13.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
76.93913269	0.27
95.04278564	0.44
100.9187622	0.48
103.1566162	0.22
104.8654938	0.84
112.7055054	0.14
114.8286896	0.25
122.9575806	2.04
126.9719543	1.61
128.9664307	6.84
130.1677704	0.28
135.1154175	0.10
142.8968964	0.13
147.1278381	1.42
150.926651	56.52
152.0066071	3.16
152.8036652	0.24
154.34935	0.15
157.2402496	0.59
159.1618805	1.35
164.9133301	0.12
166.8585663	2.73
169.0950623	1.80
175.1749115	0.14
178.3053589	0.29
179.0096588	1.29
181.9633942	0.61
184.6180267	0.25
185.2260895	0.96
191.0188904	1.68
193.2888794	0.57
195.046936	0.24
197.1535797	2.57
198.1096649	0.23
207.175766	1.11
210.372757	1.25
211.1488037	1.27
217.2576904	0.22
223.412262	0.26
225.1618042	7.84
226.1651001	0.33
235.1511688	3.44
238.1429596	6.65
239.0601044	0.59
251.1484833	0.15
253.0946655	100.00
254.1501312	13.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1738
Annotation	Unknow
Peak:m/z	Relative Intensity
317.3078613	0.03
343.2133179	0.08
379.0098267	0.03
385.2480469	0.27
409.1769409	0.05
421.2344360	0.05
439.2561035	1.05
445.1771851	0.59
451.1958008	0.42
457.0955200	0.40
457.8220215	0.09
463.0807495	0.65
469.2576294	0.73
474.5147095	0.08
475.2171021	0.25
487.1643677	31.10
487.7946777	0.22
491.0252075	0.04
505.2222900	10.00
511.2804565	3.11
523.3728638	0.14
529.2744141	6.17
535.1641235	0.17
541.1311646	8.84
541.8070679	0.09
553.1945190	4.18
553.8392334	0.01
559.0833130	14.37
559.7732544	0.11
571.2333374	5.67
589.1408081	22.27
607.1195679	100.00
607.8385620	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	970.6616
Annotation	Unknow
Peak:m/z	Relative Intensity
331.5205994	0.24
371.2360840	0.37
391.2147217	0.20
405.3171387	0.22
490.3029785	0.27
504.2722778	0.16
506.3934326	0.21
517.7833252	0.17
535.5015869	0.25
546.5408325	0.51
547.8906250	0.51
560.8021240	0.24
561.6381226	0.16
569.5493164	0.08
572.7766724	0.12
573.8110962	0.54
586.3447266	0.45
591.6677246	0.06
592.5312500	0.17
600.4234009	0.17
603.7434082	1.41
604.6140137	0.54
617.1938477	1.10
618.2033691	0.62
631.7017822	0.97
641.4265137	0.20
648.3236694	0.15
659.5867920	0.75
660.6396484	0.56
662.7664795	0.32
663.7138672	0.15
670.3121338	0.66
673.5861206	0.31
687.5957642	0.28
688.6063232	0.16
696.1091919	0.37
698.6786499	0.17
699.7799072	0.86
702.4132690	0.16
716.6398315	2.90
717.7568970	1.71
725.9242554	0.16
726.6820679	0.11
728.2431030	0.11
729.8696899	0.20
730.5082397	1.30
740.5360107	0.80
743.8405762	0.96
744.6373291	0.43
745.6971436	0.19
753.2863159	0.33
754.6891479	1.03
758.7276001	0.08
761.5384521	1.31
762.6371460	0.92
772.6935425	3.29
773.6792603	1.59
775.0652466	0.11
775.9823608	0.33
783.4467163	0.78
784.4646606	0.23
787.0727539	0.37
788.0780640	0.06
788.7249146	0.85
794.4989624	0.11
795.1015015	0.12
795.7659302	0.28
800.2946777	0.26
801.2278442	0.47
805.6608276	0.27
811.6078491	0.63
812.7224731	0.59
813.5867920	0.18
814.7111206	1.05
817.5951538	0.87
828.5896606	0.14
829.6807251	22.77
830.7817993	8.28
834.0045166	0.23
837.6131592	0.15
839.6049805	3.76
840.5675659	2.27
842.5700684	0.07
843.9146118	4.64
844.7728271	2.25
856.7481079	7.11
857.6303101	9.52
858.6381226	0.82
867.7308960	0.24
870.9799805	0.26
872.0160522	0.73
872.7600098	0.28
880.5078125	0.09
885.6281128	6.99
886.8020630	4.50
896.1514893	0.34
899.7532959	1.39
908.6901855	0.34
912.8078003	0.40
924.7368164	0.78
925.9310913	1.13
926.7476196	2.60
927.8269043	2.18
935.9874268	0.34
942.7410278	100.00
943.8219604	43.66
952.6959839	13.55
953.7842407	6.74
955.0419922	0.23
970.9258423	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	387.1296
Annotation	Veranisatin B
Peak:m/z	Relative Intensity
98.5539856	0.13
112.8503265	3.23
115.2260132	0.14
116.9185410	0.13
119.0357666	2.94
130.9330139	1.49
135.2839050	0.15
143.0236359	5.11
149.0064392	0.65
160.3793945	0.41
160.9956970	4.30
165.1667480	0.76
167.8912354	0.13
176.9831543	0.09
178.9913330	100.00
181.0646667	0.57
190.9508514	0.24
191.8827972	0.23
193.1300354	0.10
207.0787964	0.06
208.0918274	0.14
225.0277405	3.43
243.2401428	0.28
247.3228760	0.38
248.2005615	0.51
249.1449280	0.60
266.1214600	0.25
285.2513733	0.22
294.8924561	0.22
296.8770142	0.18
313.3595886	0.33
319.3457031	0.05
322.8602600	0.12
327.0518188	0.64
329.1148682	0.18
341.0288086	2.71
343.9495239	0.23
344.9948730	0.05
357.1180420	0.16
369.1722107	0.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1608
Annotation	Unknow
Peak:m/z	Relative Intensity
112.9992447	2.99
116.1858368	0.07
117.0902710	0.20
118.9399109	1.55
125.0027618	0.58
129.0413513	0.13
131.1774139	0.22
135.1337280	0.17
138.9602203	0.26
143.0282593	1.77
147.0255432	1.04
148.8873444	0.30
160.3196716	0.85
160.9681091	11.69
164.2306519	0.32
166.9686890	0.31
177.0862122	0.17
179.0027466	4.69
181.2250977	0.25
183.1420898	46.21
184.4784546	0.52
187.2178345	0.16
197.1434631	0.96
203.1155396	0.07
207.0059967	48.43
207.9322815	0.38
210.1391602	0.15
216.1114655	1.14
225.1933289	7.14
229.0845642	1.28
235.1859741	0.22
237.2968445	0.09
239.0097961	0.12
251.3417053	0.31
255.1217651	22.93
272.7181091	1.04
275.0478516	0.19
283.0584412	0.17
284.4166260	1.31
285.0681152	10.42
285.6760864	0.08
295.2974854	0.13
301.1622009	0.41
303.5442505	0.14
313.3706970	0.33
314.8770752	1.27
327.2785645	0.25
329.1635132	0.37
331.2148132	17.25
342.9546509	0.19
345.0377808	100.00
345.6736755	0.64
347.4164734	0.13
349.2293701	3.03
355.3433533	0.20
359.6340027	0.07
373.0993652	0.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	537.1976
Annotation	(+)-Cycloolivil 4'-O-beta-D-glucopyranoside
Peak:m/z	Relative Intensity
191.2584381	0.04
238.8860168	0.12
240.1812439	0.02
245.0758667	0.09
272.3038330	0.10
297.2454834	11.61
315.0151367	0.42
327.1770630	14.82
332.2438354	0.07
341.1336060	0.05
345.0581055	23.20
345.6787720	0.16
357.1958008	5.89
370.7534790	0.08
375.1241455	100.00
387.1125488	0.20
390.1723633	0.07
395.3762207	0.12
400.7743530	0.06
421.1702881	0.07
422.2568359	0.04
431.2760010	0.06
445.0806885	0.23
485.2422485	0.17
489.4199219	0.04
491.1669312	1.02
496.0310669	0.21
497.2107544	0.09
501.0547485	0.07
503.1734009	0.25
507.0205078	0.22
519.4371948	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
254.9249725	0.02
255.9897766	0.03
284.0565796	16.66
299.0856323	100.00
301.1083679	0.02
322.9342041	0.01
326.0276489	0.03
329.3430786	0.02
339.1328125	0.04
341.0732422	0.18
361.1855469	0.07
365.2782593	0.02
445.3135376	0.06
463.2044067	0.60
484.2545166	0.03
487.2695312	0.10
489.2617798	0.06
492.7432251	0.07
505.0432129	0.15
511.4418335	0.01
521.3154297	0.03
527.3823853	0.02
529.3579712	0.02
545.2211304	0.07
549.3062134	0.02
561.6264038	0.01
562.7286987	0.02
570.8985596	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	526.2484
Annotation	Unknow
Peak:m/z	Relative Intensity
157.0912933	0.06
158.9264069	0.05
162.8731079	0.13
167.0555115	0.08
173.1440735	0.08
176.9529114	0.03
184.9837952	0.08
187.0055542	0.84
195.0607910	0.14
201.0082092	0.12
202.3750916	0.04
204.8647308	0.12
207.1747284	0.21
210.8394775	0.95
211.4931641	0.07
212.9132080	2.00
216.9128571	0.05
223.1977234	0.04
227.0578918	0.08
228.7252350	1.15
231.0256042	6.38
232.9217224	0.03
234.8893433	0.15
246.7567139	0.09
248.6802368	0.74
249.3215637	0.45
253.0588989	0.31
255.1080933	0.16
260.2713623	1.15
264.3962402	0.04
267.1728516	0.05
271.1486816	0.17
272.9822388	1.74
277.0999756	0.10
278.2828979	0.17
279.3704224	0.04
287.3970337	0.05
291.0733643	7.97
297.1229858	1.10
299.3115234	0.06
308.2580566	0.15
310.9010010	0.03
315.0656128	2.42
316.0405884	0.78
317.0457153	0.42
319.2850342	0.04
329.5798950	0.26
331.1901855	1.27
332.8851318	9.78
333.5977173	0.04
335.1887817	0.07
338.4718628	0.17
339.1152954	1.36
348.8833008	0.36
349.4844971	0.18
351.1755981	0.07
356.3897705	0.78
357.1227417	5.73
359.1425171	0.07
364.1074829	0.15
372.4906006	0.08
373.3637695	0.05
375.0309448	100.00
375.6941528	0.34
379.3770752	0.09
381.0653687	0.05
385.5858154	0.15
392.9755859	37.18
393.6008301	0.31
394.8909302	0.59
395.5242920	0.07
397.0895996	0.03
402.6925049	0.05
404.3150635	0.04
406.1970825	0.03
407.1829834	0.10
413.1750488	0.04
424.1022949	0.14
429.2238159	0.12
439.4407349	0.06
440.4210815	0.18
441.1559448	0.14
458.7775269	4.52
459.4724121	0.21
465.6535645	0.27
474.8718262	0.38
476.4154663	2.14
477.0897827	3.76
482.4467163	0.14
489.6959839	0.04
490.8583374	0.13
494.8540649	5.31
496.3712769	0.05
508.3509521	0.79
509.4874878	0.22
525.5466919	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.15
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
167.0682526	0.07
174.8952179	0.32
185.2461853	0.04
187.3867035	0.03
191.4099121	0.04
195.1408386	0.13
197.3997803	0.15
198.290802	0.10
199.0225525	0.53
201.3945007	0.06
206.1903839	0.07
208.1677399	0.03
211.1012726	0.04
212.362793	0.08
213.3495483	0.04
214.1572113	0.04
214.9298706	0.32
217.1225891	0.72
223.1991425	0.09
225.9417725	0.10
229.1141052	0.10
240.3570557	0.01
241.0632172	0.14
242.9248657	0.58
252.4498749	0.07
253.8251648	0.04
257.1537476	0.30
267.182251	0.18
285.0482788	100.00
286.1934204	1.24
289.6257324	0.03
293.2177124	0.11
297.1821289	0.12
299.0998535	2.72
307.2356262	0.04
308.3510132	0.03
311.0147705	0.33
314.2242432	0.04
321.9786377	0.08
323.0198364	0.09
327.1908569	1.08
339.0206299	0.04
341.1642456	0.87
343.2381592	0.07
346.1446533	0.02
353.1234741	3.12
353.9475098	0.07
357.010498	0.06
359.2563477	0.60
365.1474609	0.15
371.1219482	0.07
383.0933228	1.32
384.1119995	0.02
387.4870605	0.05
389.1837158	0.67
395.0749512	0.12
397.1123657	0.02
399.4345703	0.05
405.4363403	0.10
407.3850098	0.03
413.223877	0.78
430.4522705	0.04
431.2487183	0.18
437.1209106	0.05
443.1954346	4.88
447.1716919	0.84
449.1640015	0.49
455.1846924	0.18
460.3199463	0.02
463.3876953	0.29
471.2692871	0.13
473.2116089	8.68
474.2480469	0.07
485.3812256	0.20
489.1987305	0.10
499.3616333	0.02
503.1234131	4.21
507.453186	0.02
512.2366333	0.03
517.1713867	0.03
531.2857666	0.02
532.958313	0.31
545.1116943	0.14
547.0909424	0.22
549.1084595	0.22
557.2687988	0.15
563.428894	0.04
575.2024536	1.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1696
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
205.0704346	0.04
271.0832520	16.57
273.2273560	0.05
282.8988037	0.03
284.9444580	0.05
292.9668884	0.02
295.0090332	0.01
313.2395935	0.09
323.2445679	0.03
337.0485229	0.02
351.2807007	0.03
367.0144043	0.09
378.9765015	0.05
381.0646362	0.33
386.9843750	0.09
393.7087402	0.02
394.4370728	0.02
399.0708618	0.08
409.1740112	0.04
413.4523926	0.05
415.5127563	0.11
417.0871582	0.92
420.3063354	0.01
425.7214966	0.07
429.1607056	0.05
433.0789185	100.00
435.3386230	0.07
447.1448364	0.40
459.2277832	0.05
463.0085449	0.02
475.2694092	0.07
493.3549194	0.02
500.3029175	0.01
524.9779053	0.02
533.2384644	0.05
543.0582886	0.20
561.1483765	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	987.2623
Annotation	Unknow
Peak:m/z	Relative Intensity
284.9217529	0.13
285.9993286	0.06
287.1334534	0.17
302.0991211	0.62
305.0545349	0.54
315.2370300	0.17
316.8986816	0.23
330.1173706	1.17
345.2354126	1.92
360.1003418	2.96
375.1197510	11.87
405.4140625	0.22
417.1834717	0.07
449.4591064	0.22
489.1642151	0.26
505.4567871	0.06
507.2234497	7.00
537.2553101	40.13
549.1663818	9.14
550.9736328	0.06
579.2326660	26.87
589.0736694	1.16
591.1842651	0.25
607.4610596	0.11
611.1443481	0.37
617.4589844	0.09
619.2892456	6.68
620.6986694	0.05
621.3061523	3.96
631.3237305	0.32
651.1524658	19.90
651.7550049	0.06
661.1303101	2.97
663.1433105	0.94
681.1928101	100.00
687.5225830	0.13
693.1655273	4.26
699.2943726	0.29
701.1054688	0.97
703.2326660	0.94
723.1582031	24.25
730.1014404	0.26
733.2218018	0.18
735.2532959	0.09
753.0447998	2.89
763.1411133	1.56
765.2472534	1.83
783.0058594	1.85
795.1214600	23.71
805.1512451	0.29
813.0296631	0.11
825.0512695	63.81
837.0598145	1.30
843.1868896	28.01
848.9227295	0.30
864.8293457	0.43
867.1401367	7.16
871.1840820	0.45
879.4892578	0.09
885.1099854	4.14
897.1062012	9.47
908.8892822	0.56
925.1397705	2.74
927.1641846	9.74
951.0743408	0.35
956.7524414	0.30
957.3643799	0.33
969.1584473	3.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	246.15
Annotation	Gln Val
Peak:m/z	Relative Intensity
72.93495941	0.09
76.03492737	0.49
76.79572296	0.05
78.97328186	0.10
80.99169922	1.37
83.04083252	0.34
84.14175415	0.03
85.01269531	0.03
86.88243866	1.18
87.84598541	0.40
92.88305664	0.03
95.09503174	0.08
96.90629578	0.06
100.9460449	0.78
103.1319122	0.01
104.0203247	0.03
109.0206299	0.04
114.0869904	0.05
115.1415405	0.12
116.0656128	0.10
119.8798523	0.03
122.0344086	0.03
122.9763947	0.87
125.0414734	0.13
126.043869	0.05
127.016861	0.16
129.959549	0.03
131.207901	0.11
133.0833893	0.01
136.0436249	0.06
142.0799408	7.43
142.684494	0.07
144.9611969	0.06
145.9131012	0.02
149.1916351	0.07
153.031662	0.08
153.9711151	0.05
157.0168152	2.14
158.1308899	0.04
159.0904694	0.05
162.2178802	0.07
164.1863861	0.03
165.2405853	0.02
176.8517303	0.06
182.5371552	0.13
183.2605438	0.47
183.968338	0.02
186.015686	0.08
187.1922302	0.03
190.34935	0.02
193.1549835	0.06
198.2433472	0.01
200.1164856	10.20
200.8875275	0.22
202.4365082	0.02
204.2523193	0.11
204.9993286	0.19
212.9137421	0.06
214.182251	0.02
218.1798706	0.24
222.8941956	0.02
225.5206604	0.05
229.1157684	100.00
236.8676605	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	386.2505
Annotation	Unknow
Peak:m/z	Relative Intensity
113.9206238	0.03
114.8892288	0.07
116.2421799	0.18
132.5683899	0.02
138.9986572	0.06
144.1547699	0.25
154.0909882	11.99
157.0988922	0.05
158.0412292	0.08
163.0341492	0.04
165.0557556	0.10
170.0219116	0.03
171.1222229	0.13
172.1330872	0.31
175.2518005	0.06
179.6058350	0.02
189.1422577	18.15
198.0464172	100.00
205.9280701	0.04
211.9392395	0.09
212.8582458	0.51
213.6726227	0.02
214.8824615	0.54
216.0792694	0.04
216.8304138	0.12
230.0783997	0.05
235.2546997	0.02
236.0618896	0.02
250.6739197	0.18
252.9617004	0.14
253.8748169	0.03
265.2551270	0.17
271.6156616	0.03
288.1968994	0.01
300.8594666	0.04
301.9550171	0.03
303.0881042	0.04
316.2535400	0.09
320.1839600	0.06
325.0650024	0.10
327.1545410	0.06
330.9935913	0.02
331.8903503	0.06
332.9920349	0.03
339.7042236	0.20
340.9055786	0.05
343.0717773	0.07
345.7554932	0.01
350.4570618	0.04
351.2222595	0.01
368.6644287	1.68
369.4744263	0.16
377.2323303	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	7-Methoxyflavone
Peak:m/z	Relative Intensity
94.92784882	0.55
102.8606567	1.16
104.8028717	1.00
106.6770935	0.50
108.8858795	0.53
109.8981476	0.33
112.8482208	0.54
119.3182831	0.40
122.9401093	0.85
128.9048004	5.13
130.0096436	0.82
132.9924622	0.20
140.6488342	0.15
145.0599365	0.51
150.9829865	54.34
151.967804	4.93
152.8154144	0.57
154.0841522	0.39
155.1037445	0.76
165.0112457	0.69
166.0240936	0.20
167.0021057	2.16
169.1731873	1.01
178.0873871	0.80
179.0681152	0.67
185.0827789	1.49
186.1105499	0.89
191.364212	0.37
194.2291565	0.60
195.2213593	0.18
197.0870514	3.20
210.0480499	0.83
211.0258636	0.31
225.0960236	5.09
226.022995	0.94
235.2672119	0.42
238.0478973	7.40
238.8171387	1.48
251.0379486	0.31
253.0832062	100.00
254.1387482	16.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1819
Annotation	Neohesperidin
Peak:m/z	Relative Intensity
174.2194824	0.06
174.983139	0.50
180.2917938	0.38
183.0728607	0.21
186.8977356	0.22
188.1191559	0.06
197.1192474	0.13
197.7455597	0.15
199.0577393	2.36
200.0542297	2.07
200.993103	1.86
202.0587463	0.90
203.0094604	0.11
205.2522888	0.17
211.130661	0.16
213.2746277	0.19
215.2702332	1.36
216.170166	1.67
217.1236267	0.11
223.3320007	0.26
223.9587097	0.28
225.3658447	0.13
226.1750031	0.23
227.0405731	0.16
228.4838104	0.42
229.2200165	0.33
239.5302124	0.28
240.184845	0.30
241.1118164	1.23
242.0415649	4.21
243.1315613	2.07
244.029007	2.41
245.0876312	0.36
257.0559082	2.53
257.8730469	1.16
258.9611816	1.08
260.3279724	0.11
267.1994629	0.16
268.1433105	1.25
283.0964661	0.24
284.2249756	1.03
285.1898499	0.64
286.2290039	1.97
287.3029175	2.46
288.2232971	0.81
299.1958618	0.51
301.0798035	100.00
302.0786743	81.27
303.1879272	86.49
317.4647827	0.39
325.1699219	0.60
326.1168213	1.43
327.2390747	2.24
329.0657959	0.40
342.7631226	0.11
344.0597534	0.09
345.3010864	1.07
347.5071411	0.08
357.0384521	0.29
368.4334717	0.72
369.0563354	0.15
467.2352905	1.04
489.3287354	0.56
490.1552124	0.11
491.4520874	0.27
519.1519775	0.07
521.2280884	0.39
525.4348755	0.12
564.8812866	0.10
569.302063	0.50
579.4629517	0.35
593.0974731	0.58
596.5407104	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	794.61
Annotation	Unknow
Peak:m/z	Relative Intensity
251.2747498	0.14
290.8673706	3.63
374.7594604	1.08
420.8545532	0.12
458.5040894	20.20
459.2397461	0.47
461.9244995	0.22
502.9132690	0.08
504.8787842	0.05
542.4727173	100.00
543.1844482	0.42
586.5057983	0.51
590.5269165	0.12
604.5455322	0.07
624.2324219	0.10
625.6998291	2.99
626.3762207	58.87
627.0971069	0.18
628.5811768	3.12
642.4570923	0.05
650.7062378	0.11
658.4031372	0.36
664.6129150	0.13
674.5510864	0.14
688.4337158	7.07
700.5216064	0.09
707.9583130	0.13
709.7398071	14.78
710.3510132	79.65
711.1794434	0.07
730.4862061	0.68
734.5005493	0.25
745.5119019	0.29
747.9782104	0.66
748.5907593	1.09
771.1275024	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2778
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
140.1024475	0.02
151.0731049	0.02
153.0472107	0.02
196.1117554	0.20
214.1530151	1.40
225.9345703	0.02
233.1627197	0.02
259.3522034	0.01
261.3132019	0.14
279.2701721	100.00
280.0872803	0.00
357.2251587	0.01
388.9261475	0.02
432.2857361	0.01
458.4897156	0.08
459.4288330	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.2292
Annotation	Unknow
Peak:m/z	Relative Intensity
205.3535461	0.02
217.1863861	0.02
219.5209656	0.03
223.1049500	0.02
260.0417480	0.02
265.3903198	0.02
271.0310059	0.02
286.9876099	0.06
301.0271606	0.04
302.0674438	0.01
303.1122437	0.03
311.2108154	0.04
313.1145325	0.92
316.2260742	0.04
317.1092529	0.03
330.5750732	0.04
331.1793213	0.20
339.3808594	0.03
345.1902466	0.14
355.1264038	0.20
365.2912598	0.02
372.2363892	1.08
373.1337280	0.84
379.2847290	0.16
381.5572510	0.14
397.4084473	0.06
403.5317383	0.03
414.4460449	0.02
415.1472168	0.03
421.2932739	0.01
422.7680664	0.02
423.4646606	0.03
439.2535400	0.27
441.4169312	0.01
443.3197021	0.10
463.2843018	0.06
465.3012695	0.22
477.0971069	0.02
483.2069702	100.00
496.1984253	0.04
506.1550293	0.09
521.4594727	0.04
525.3102417	9.17
541.3839722	0.03
565.2750244	1.35
567.2659302	0.03
581.5605469	0.06
583.4360352	0.06
593.3118896	0.03
598.9188232	0.04
600.2460327	0.02
609.2012329	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	821.2715
Annotation	Unknow
Peak:m/z	Relative Intensity
263.1444397	0.10
298.0897827	0.26
305.3653564	0.34
347.3713684	0.06
368.9022827	0.23
370.5901489	0.11
412.7645264	0.11
449.1069336	0.84
452.7205811	0.56
455.2060547	0.17
463.1239014	0.07
485.2796631	0.58
493.9479370	0.22
496.8579712	1.13
512.8783569	0.90
515.1224976	47.02
557.2066650	6.36
586.4763184	0.14
597.2196655	1.83
599.0839233	0.20
611.0597534	0.51
617.2940674	0.62
629.2050171	0.83
640.9735718	0.60
646.7421265	0.22
659.0689087	100.00
659.7103882	1.27
666.4926147	0.57
676.9769897	0.42
701.1620483	3.97
712.9369507	1.02
731.1238403	2.98
734.2567749	0.19
735.2131348	0.29
757.2710571	0.09
758.6463013	0.17
761.1006470	29.35
761.7649536	0.30
766.9832764	0.15
785.0049438	0.34
791.0105591	0.69
802.3865356	0.57
803.3070068	3.16
803.9303589	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1269.3716
Annotation	Unknow
Peak:m/z	Relative Intensity
357.1551208	0.13
372.2039795	0.08
399.1399536	0.61
429.1207886	0.58
477.1363525	1.33
483.1674805	0.14
495.3256226	0.26
501.1136475	1.09
503.2373352	0.05
519.1860352	0.20
591.5456543	0.81
605.2651367	0.12
617.6092529	0.25
623.2015381	100.00
623.9149170	0.53
626.6994629	0.16
632.4696045	0.27
645.0818481	2.43
665.0643311	0.86
690.4215088	0.35
704.9210815	0.67
705.5679321	0.05
709.3212891	0.15
710.2629395	0.36
767.5625000	0.17
785.1512451	2.71
817.0559692	8.41
818.8502197	0.06
826.9579468	0.19
829.0770874	0.16
858.9774170	2.88
885.5327148	0.21
899.0067139	0.51
911.2689209	0.12
933.2991943	0.88
957.1177979	0.09
961.1593018	5.34
963.3807373	0.77
1002.9541020	0.15
1004.7392580	0.35
1034.9243160	0.13
1045.1202390	0.14
1073.0004880	0.25
1089.4356690	0.19
1106.9299320	1.32
1107.5474850	0.71
1125.0742190	45.45
1125.8422850	0.19
1153.4960940	0.49
1166.8837890	3.62
1167.5598140	0.36
1179.4378660	0.25
1187.8511960	0.09
1207.1239010	2.28
1207.7282710	0.20
1209.6763920	0.23
1238.1966550	0.21
1246.6105960	0.12
1251.1098630	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.2742
Annotation	Unknow
Peak:m/z	Relative Intensity
151.0542450	0.14
159.9937592	0.04
162.8071899	0.07
164.6513062	0.09
167.5257874	0.27
168.9181366	4.84
169.9792633	0.44
181.1439056	0.14
186.7983551	4.47
187.9690094	51.35
205.0650177	100.00
210.9805603	0.13
218.9129486	0.09
223.1327972	0.03
228.1416473	0.04
230.9855194	0.09
234.1076202	0.10
235.3649597	0.17
237.1309509	0.19
239.4401703	0.04
247.1657715	0.08
251.1341248	0.55
269.0138550	0.16
277.2259521	0.22
294.9877625	0.27
299.1057434	0.13
304.2256775	0.03
311.0524902	0.06
313.2629395	0.46
330.2723999	2.96
330.9082031	18.21
331.6484985	0.20
343.3048096	0.36
345.8489990	0.15
347.0406494	0.10
348.4839478	2.32
349.1383057	4.51
361.0108032	0.08
366.2605591	0.06
378.2276611	0.28
390.8486938	0.42
395.3825073	0.20
399.2396851	0.09
409.1978760	2.60
433.2118530	0.26
437.4046021	0.08
450.9183350	0.35
465.1766968	0.06
474.9971924	0.09
479.4457397	0.04
486.2284546	0.06
493.0100708	1.33
496.9887085	0.17
506.3178101	0.15
511.2922363	0.09
517.1528931	0.14
523.2276001	0.12
530.6787720	0.14
534.5278931	1.36
535.2167358	3.45
536.2167358	0.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	268.1032
Annotation	Zidovudine
Peak:m/z	Relative Intensity
109.0226288	0.01
135.9550934	100.00
146.7046661	0.02
150.0342255	0.03
188.9733734	0.01
196.0204773	0.02
208.8509064	0.04
231.9657440	0.08
240.2249298	0.02
250.2159882	0.09
259.1880493	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.2711
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
205.1686859	0.03
207.3161011	0.03
215.0645447	0.04
220.4769745	0.05
237.3434753	0.02
243.2338715	0.03
245.2917175	0.16
261.1627197	0.05
265.2033691	0.02
267.1077576	0.25
269.8089600	0.06
273.2740479	0.01
274.9184875	0.03
289.3043823	0.02
291.1969604	0.04
292.3416138	0.01
295.0140381	0.06
297.1412354	0.08
307.3058472	0.51
315.2532959	0.08
321.1503296	0.14
325.2403870	0.87
333.4124451	0.14
339.4849854	0.06
341.2981262	0.02
343.4403381	0.08
347.1584778	0.04
349.2150269	0.06
351.3269043	0.19
353.4058838	0.04
355.3110962	0.01
357.4508667	0.02
373.1608276	0.06
381.4608765	0.04
383.3333130	0.14
388.9405518	0.04
393.0791016	0.02
399.1552124	0.12
409.1633911	0.09
427.2344971	0.19
433.3595581	0.05
437.1109619	0.19
451.1121216	0.74
451.7612305	0.01
453.3634033	0.27
454.8030396	0.05
467.2432251	0.03
471.2741089	100.00
477.0501709	0.07
481.1210327	0.13
483.4237061	0.04
485.2654419	8.40
493.2407837	0.09
495.2615356	13.91
496.2639160	0.05
497.3289795	0.07
499.2476196	0.01
513.1366577	25.24
513.8715820	0.01
519.9297485	0.05
524.6825562	0.20
525.2899170	2.53
537.2301636	0.38
543.1668091	0.87
546.5441284	0.04
555.2267456	0.20
567.6459351	0.05
572.9082642	0.12
573.6334839	0.02
576.4823608	0.07
577.2194214	0.01
597.1489258	0.07
603.1677246	0.09
615.0336304	2.23
639.0678101	0.15
645.2868652	0.05
656.7586670	0.08
659.8142090	0.04
660.4788818	0.05
663.3706665	0.02
674.2798462	1.46
675.0090942	7.51
676.9110718	0.06
685.5473633	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	825.2089
Annotation	Unknow
Peak:m/z	Relative Intensity
245.3778687	0.01
246.0771179	0.02
258.1987915	0.02
302.5472412	0.04
304.9622803	0.08
317.0573120	0.18
328.9660034	0.02
345.1815796	0.08
347.0809631	0.02
357.2238770	0.02
360.1819458	0.91
375.2001648	5.59
501.9564819	0.03
519.1470337	0.15
537.2423096	33.72
543.0611572	0.02
561.3006592	0.06
564.2087402	0.04
565.0685425	0.03
579.1267700	17.75
579.7627563	0.11
589.5458984	0.05
607.5509644	0.04
619.2583618	5.49
621.2352295	1.14
624.1015015	0.04
648.9253540	0.08
649.5845337	0.03
651.2122192	0.08
661.2543335	0.92
663.0067749	0.12
672.7059937	0.03
674.4105835	0.03
681.1234131	100.00
681.7673950	0.45
682.4756470	0.02
701.1806030	0.06
723.1080322	10.29
723.9298096	0.03
739.6631470	0.01
763.1801758	1.70
780.0905151	0.11
781.0889282	0.27
807.1011353	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
185.2854919	0.58
205.0984192	0.14
214.9984589	1.01
226.8989258	0.58
232.9191895	0.21
242.3918152	1.02
255.3594208	0.70
258.097229	0.32
283.0501099	1.67
285.0144348	0.55
286.0611572	1.76
299.4162598	0.62
301.0799561	100.00
341.2470093	0.16
342.9011841	0.49
346.0412598	0.30
370.114624	0.16
399.1989746	3.14
411.2232666	0.37
413.6010132	0.38
414.9697876	0.29
419.1518555	0.81
421.4761963	0.59
429.3060303	0.46
447.4077148	0.34
450.7985229	0.62
460.9367676	0.41
489.201416	6.00
501.3344116	0.41
509.4862061	0.79
518.8190918	2.01
519.6940308	0.14
539.2631226	0.26
549.6142578	1.65
553.8602905	0.94
563.1533203	0.78
565.1939087	0.29
571.581604	0.35
572.9685059	0.14
575.4942627	0.93
578.9073486	1.02
591.3838501	1.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.2875
Annotation	Unknow
Peak:m/z	Relative Intensity
242.2232513	0.23
285.0910645	0.40
297.2338257	0.13
333.0835571	0.42
340.8740234	0.11
346.0559387	1.23
347.1346741	1.13
355.1464844	0.16
376.9818726	0.87
378.3311157	0.19
383.2556763	0.56
395.2017822	0.14
413.3612061	0.27
418.2097778	0.53
419.0898438	0.92
420.1232910	0.22
437.2178345	1.36
438.3400269	3.05
443.0229492	0.14
464.3758545	0.08
468.0714722	0.21
469.2231445	0.15
477.0863647	0.18
479.4939575	0.17
485.2130737	0.19
489.1633301	1.46
496.4871826	0.08
503.2571411	3.11
505.3430786	0.12
515.2080078	0.66
518.3453979	0.07
519.1256714	0.65
526.2852783	0.19
531.0565796	0.22
531.6745605	0.67
533.1670532	0.64
545.1528931	1.98
547.5015869	0.31
569.1565552	0.35
575.3453979	1.25
591.2008667	0.20
593.4373169	0.35
609.1715698	6.90
609.8536377	0.71
621.0364380	0.32
623.2900391	59.95
635.3146973	0.53
640.1853638	0.27
641.3515015	0.82
647.3329468	0.12
663.3455811	0.15
665.2535400	100.00
665.8953857	1.17
667.1119995	0.32
693.2431641	0.10
695.2933350	0.78
699.7758789	0.15
705.3471069	0.17
707.3135376	0.18
713.1658936	0.08
721.2617188	0.44
738.6593018	0.10
741.2785645	1.64
749.0859985	0.11
767.2641602	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.4009
Annotation	Scopoloside II
Peak:m/z	Relative Intensity
277.0780945	0.10
285.3886108	0.11
300.0575562	0.04
309.6055908	0.03
314.1516418	0.11
314.9487610	0.12
327.2329102	0.11
337.3994751	0.04
357.1676636	0.79
360.2250366	0.14
375.1245117	0.05
381.0742188	0.05
419.3097534	0.04
439.4752808	0.08
441.0889893	0.09
446.9579468	0.13
461.0565186	0.10
501.4700928	4.98
519.1807861	0.16
525.3664551	0.03
529.2398682	0.12
549.2966919	0.05
551.4144897	0.10
561.0993652	0.08
565.4331665	0.77
573.4827271	0.19
577.3402710	0.07
581.3750000	0.07
591.0800781	0.11
593.3215942	0.05
595.1893921	0.54
606.7507324	0.11
607.4682617	0.06
615.4879761	0.10
619.4055176	0.17
621.2561646	0.93
622.7634888	0.07
624.2311401	0.09
625.2618408	0.51
625.9669800	0.06
637.2182007	0.15
638.8980713	0.25
639.6707153	0.08
650.8823853	0.14
663.4275513	100.00
664.0952148	0.40
673.4344482	0.19
679.2963257	0.04
681.3908081	9.70
697.0091553	0.11
701.4927368	0.04
705.7141113	0.06
706.8774414	0.20
709.2466431	0.27
723.3460083	13.86
725.4726562	1.18
737.3157349	0.14
746.3844604	0.36
747.3884277	0.14
750.7659302	0.38
751.4390259	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	509.1287
Annotation	syringetin-3-O-galactoside
Peak:m/z	Relative Intensity
163.0161438	0.01
205.0057831	0.04
206.1659546	0.03
215.1698456	0.03
243.1628418	0.01
245.2535095	0.01
247.2720337	0.04
261.3850098	0.02
271.3533936	0.04
272.0368042	0.02
289.9672241	0.04
295.2591553	0.06
302.2576294	0.03
307.2716064	0.07
308.1797485	0.15
319.4662476	0.01
347.0707397	100.00
347.757019	0.10
359.1535645	0.05
360.0601807	0.03
365.1296997	0.01
367.2337036	0.03
389.1031494	0.30
393.2561646	0.01
404.951416	0.03
406.8879395	0.05
413.0991211	0.22
429.0411377	0.01
442.0501099	0.01
443.2012939	0.30
447.4571533	0.04
452.3141479	0.08
455.31604	0.05
464.9060669	0.04
473.2801514	0.22
477.8860474	0.02
489.508728	0.04
491.1533813	1.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2033
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
164.1370697	0.11
165.0620728	0.08
167.1317139	0.01
179.0606537	0.30
195.0826721	1.38
202.9758911	0.05
206.9813232	0.03
218.1298676	0.07
220.7975922	0.05
222.1246185	0.02
247.9891968	0.09
288.1691284	0.04
299.1543579	0.10
301.2014771	0.05
302.3059082	0.03
312.2349243	0.02
327.1994019	21.06
330.0267334	0.06
331.0057373	0.05
334.1421509	0.10
341.3057861	0.04
356.1112061	0.11
357.0911865	0.13
358.4134521	0.03
371.6796875	0.03
375.0272827	100.00
375.6735840	0.20
377.4957886	0.04
381.3353882	0.04
383.0652466	0.12
383.6691284	0.02
384.3923340	0.02
419.9946289	0.46
421.3334961	0.09
429.1988525	0.02
438.2493286	0.02
439.0851440	0.01
459.0270386	0.84
462.4736328	0.12
488.0250854	0.07
496.2265015	0.01
522.2813721	0.04
523.1834106	0.04
525.2688599	0.11
536.2278442	1.56
536.8356323	15.66
537.6441040	0.26
548.2549438	0.05
551.2994385	0.03
553.5210571	0.10
565.4129028	0.09
566.5138550	0.03
568.5267944	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	737.1928
Annotation	Malvidin 3-glucoside-5-(6''-malonylglucoside)
Peak:m/z	Relative Intensity
247.0835419	0.03
258.7922363	0.03
269.0822144	0.02
270.2074890	0.04
287.1767578	0.67
301.0261230	0.03
303.3574219	0.01
308.2305908	0.02
329.1248169	0.04
330.2651978	0.03
337.3152466	0.08
343.2049561	0.02
344.7227173	0.16
345.6815186	0.05
347.3339844	0.02
366.9596558	0.02
379.0615234	0.03
397.3869019	0.04
405.3523560	0.09
413.3837280	0.03
429.7911377	0.02
431.3363037	0.17
435.3960571	0.01
441.5820312	0.02
445.5161133	0.02
449.1904907	18.01
468.5498047	0.18
469.4705200	0.18
473.2274780	0.02
484.9157104	0.02
487.5139771	0.06
491.2470703	3.53
493.4191284	0.07
501.4956055	0.03
507.0028076	0.03
513.3666992	0.07
529.1268311	0.05
530.2186279	0.12
531.1900024	0.73
533.2959595	0.05
535.5464478	0.01
540.0792847	0.03
549.1889038	0.31
550.3923950	0.05
556.2001343	0.03
561.2820435	0.03
571.4208374	0.02
573.2774048	0.28
574.4031372	0.13
575.2824097	0.39
586.3472900	0.02
588.2572632	0.06
589.0806274	0.10
593.2455444	100.00
596.8802490	0.14
603.0806274	0.01
606.2083740	0.03
612.2694702	0.06
613.7916260	0.13
617.1220703	0.01
621.2608032	0.07
625.3340454	0.07
630.4656982	1.04
631.5427856	0.26
633.1112671	0.12
634.0570679	0.05
635.1228638	5.85
635.8354492	0.01
647.7046509	0.03
648.3276978	0.25
649.6348267	0.10
651.5230713	0.08
665.3173218	0.08
674.0885010	0.11
675.1780396	1.06
685.2456055	0.03
689.6936035	0.07
690.3095093	0.05
691.3781128	0.22
692.4830322	0.33
693.2117920	0.44
700.4019165	0.03
714.4288940	0.08
719.1509399	0.23
721.3992310	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	307.1017
Annotation	Starch acetate
Peak:m/z	Relative Intensity
96.9779663	0.46
98.9031906	0.13
103.0090179	1.24
109.0105743	1.99
115.0050049	0.05
126.9709702	13.16
133.0906982	0.25
139.1679688	0.04
143.0987549	0.06
144.3467407	2.13
144.9563293	11.51
147.0238037	0.13
148.9884796	0.11
163.0055237	21.27
165.0653534	0.16
167.4366150	0.05
168.2826080	0.60
168.9458160	0.98
173.2304535	0.10
178.9218445	0.08
180.3014526	0.07
181.0535889	0.11
183.0195312	0.06
185.7938538	0.13
186.9962006	6.36
189.1963959	0.02
191.1659851	0.14
203.1108398	0.28
205.0482178	51.43
209.2310791	0.04
213.4562378	0.07
216.8094482	0.11
222.8621216	0.07
224.0132446	0.10
225.0985107	0.17
227.0634155	0.06
229.0169678	0.30
233.0327759	0.27
240.4407349	0.24
243.3860779	0.07
245.0292664	1.46
247.1808167	0.18
248.2059326	0.09
252.9858093	0.90
256.9101257	0.03
261.1471863	0.23
263.2986450	0.10
269.0310364	0.05
270.3742981	1.78
271.0759888	8.47
275.2882690	0.12
279.1615601	1.01
288.9986267	100.00
290.0820618	0.09
292.2164612	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	627.2627
Annotation	16-Hydroxymilolide G
Peak:m/z	Relative Intensity
177.0568390	0.22
183.1214905	0.74
184.2050781	0.06
187.0738068	0.98
189.0122528	0.77
191.1403046	0.39
193.0071106	0.82
199.1867676	1.95
201.3023071	0.09
209.1600952	0.47
213.0740814	2.59
217.0826111	5.28
227.2541351	0.49
228.8211060	0.63
230.9840851	8.63
233.2192688	0.04
235.0985260	73.47
237.1361237	0.20
245.2700806	0.23
249.0263519	1.02
253.1029358	1.34
255.1136627	0.13
259.1896362	0.39
261.2186584	0.18
270.9916992	0.98
273.0629883	2.47
276.9299927	0.36
287.1396484	0.44
288.1741333	0.38
289.1669922	0.28
291.0404053	6.78
293.4696045	0.11
294.9764404	0.50
295.6042480	0.05
301.0989990	0.55
303.3665161	0.30
305.3373413	0.10
307.2840881	0.08
311.1612549	0.26
313.0605469	0.97
315.1699829	0.17
317.2447510	0.20
318.3931885	0.26
319.2733765	0.60
321.0952148	1.39
322.2668457	0.33
325.0720215	0.28
329.0650330	0.10
330.5599670	0.90
331.1682129	5.99
332.8583374	0.32
335.1027832	0.13
339.1052246	5.87
343.2495728	0.70
347.2299805	0.17
350.8931885	0.05
355.1470947	0.23
357.0172119	6.99
361.3230591	0.36
367.1542358	0.06
375.0368042	100.00
375.9360352	0.05
379.3937988	0.71
385.3593140	0.25
387.3018188	0.12
393.0476074	26.37
403.2586060	0.30
417.2696533	0.35
421.1062012	1.49
429.1335449	1.06
432.1585693	0.05
433.3597412	0.05
435.3750610	0.06
436.5439453	0.09
437.1914673	0.04
439.0453491	0.13
443.3388672	0.16
446.5103760	0.53
447.1822510	4.10
461.3158569	0.14
463.2545776	0.10
465.1120605	4.31
465.7555542	0.02
477.1520386	0.06
479.2205200	0.21
480.1678467	0.64
481.2101440	0.74
483.1999512	33.18
487.4616699	0.31
489.1135864	0.88
502.9990845	0.71
505.1763306	0.18
507.3901978	0.24
513.1099243	0.12
521.3699341	0.47
523.3380737	0.03
525.3997803	0.13
529.4025269	0.28
531.4458008	0.23
541.3484497	1.51
543.2147827	0.31
547.2224731	0.93
553.4145508	0.49
554.9507446	0.13
558.2640991	0.11
560.9425049	0.10
561.5442505	0.06
564.4613037	1.32
565.1066284	9.35
567.2123413	0.68
573.0654907	1.16
583.2838745	0.58
588.8169556	0.10
591.1499634	20.13
595.0578613	0.06
607.2342529	0.14
609.0737305	81.39
609.7634277	0.47
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0876
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
100.8682709	0.30
107.8750076	0.54
112.9824142	1.27
118.9817505	0.18
122.1870117	0.46
123.0385284	4.34
130.6501770	0.32
137.8830261	0.05
142.9105530	0.15
148.9443054	0.14
149.9793091	0.37
152.0326538	2.45
161.0251617	0.37
163.0754700	0.09
165.2910767	0.58
166.0865021	1.91
166.9602661	97.27
177.1358643	0.22
180.9717407	15.39
189.0355988	0.18
191.0233154	0.03
193.2261200	0.29
193.8640442	0.92
195.1959686	0.08
208.9978638	100.00
218.8139038	0.08
221.2864685	0.49
223.2321472	0.19
233.0317688	0.27
235.1990356	0.14
239.0865479	13.13
251.1346436	0.61
262.9241028	0.48
269.1372681	43.07
283.0043945	0.17
311.1533813	0.23
312.8503418	0.04
314.1115723	1.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	829.4382
Annotation	Unknow
Peak:m/z	Relative Intensity
584.3742065	0.07
623.5411987	0.03
652.6411743	0.05
707.3605347	0.02
793.4542847	100.00
794.3518677	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	167.01
Annotation	Unknow
Peak:m/z	Relative Intensity
125.8553772	100.00
137.5720215	0.03
139.2074432	0.03
143.2746582	0.18
143.8852844	0.98
146.3402863	1.29
148.5352325	0.02
155.0085602	0.35
166.7608795	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	613.21
Annotation	Unknow
Peak:m/z	Relative Intensity
176.0836029	0.07
177.1529999	0.09
179.2022552	0.11
191.0897217	0.15
194.0313568	0.33
195.1016541	3.96
206.8011780	0.05
209.1526642	3.59
211.1685181	0.10
220.2931824	0.06
253.1252747	0.07
260.2584229	0.04
261.0764771	0.03
289.1386108	0.03
304.0913696	0.05
305.1182861	0.09
328.3818970	0.04
357.2733765	8.64
386.8596191	0.64
387.5232544	0.02
391.1190796	0.08
405.0629883	100.00
405.6785278	0.36
407.3416748	0.11
433.1776733	0.02
439.1922607	0.02
444.9125366	0.04
447.1421509	0.14
450.0776978	0.21
450.9651489	0.88
459.7933350	0.23
468.3961182	0.05
469.3637085	0.11
475.2805786	0.07
479.3472900	0.10
486.2095337	0.03
487.0671997	0.05
489.1556396	0.41
503.2556152	0.05
517.4105835	0.03
522.2539673	0.16
540.8593750	0.10
549.2246704	0.07
553.3486938	0.25
565.2628174	0.21
566.7155151	16.11
567.6735229	0.02
568.8661499	0.15
569.6359253	0.03
577.2448120	0.06
585.3773804	0.21
595.3792114	0.31
598.9838867	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	516.8972
Annotation	Unknow
Peak:m/z	Relative Intensity
159.1785583	0.13
174.8500366	1.07
198.8815918	0.30
216.9311218	0.07
245.0056458	0.13
272.9841919	5.45
288.9960022	9.83
291.1224976	0.06
386.8038330	1.72
387.5371094	0.05
400.8990479	0.08
402.9444580	100.00
403.8247681	0.12
427.1917725	0.12
445.0862427	0.14
458.9298096	0.25
470.1585083	0.19
470.9776001	0.15
472.9591064	0.38
488.8334351	0.28
490.6174927	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	625.1775
Annotation	Tricornoside B
Peak:m/z	Relative Intensity
176.8407135	0.04
188.1467590	0.08
192.0012360	0.14
195.0368347	0.03
198.1473389	0.04
205.2925720	0.05
213.2124329	0.15
214.0916748	0.05
215.1898804	0.02
215.8965149	0.12
217.1523895	0.06
227.1383362	0.02
229.8678131	0.37
231.1007080	0.23
233.2943420	0.02
234.2568359	0.03
240.1283722	0.09
242.1843414	0.03
255.2155151	0.03
258.2132568	0.84
265.9903564	0.04
271.1961060	0.06
273.0889282	0.79
274.1132202	0.70
284.1470032	0.56
287.0119629	0.03
289.1625977	5.09
295.2340088	0.05
297.1132202	0.22
298.1240845	0.02
299.1917114	3.28
301.3105469	0.49
302.2143555	0.07
304.2053223	0.03
313.1960449	1.70
317.1052856	100.00
318.1899414	0.05
323.1392517	0.03
328.1945801	0.03
331.1748657	0.24
337.4748535	0.04
341.1552734	1.00
352.9822388	0.02
355.1797485	0.06
359.0727539	0.09
365.2177734	0.03
368.0300293	0.07
370.3619385	0.09
370.9735107	0.03
383.2005005	0.62
384.1343384	1.14
385.1741333	1.56
386.2238770	0.03
389.6578979	0.07
395.3881836	0.23
400.3999634	0.03
413.2910156	0.38
414.3510132	0.37
415.2858887	1.51
417.0070801	0.05
429.3951416	0.03
432.7200317	0.03
433.3686523	0.02
443.0411987	0.14
444.3444824	0.05
445.2602539	0.05
451.6046753	0.10
459.3566895	0.22
460.3214111	0.07
461.1447144	0.03
463.1259155	1.72
465.2561646	0.02
467.4271240	0.02
473.4000854	0.04
479.3696289	0.04
481.1851807	0.36
486.3447266	0.26
487.2064819	0.57
488.1254272	0.08
498.6229858	0.03
503.2585449	2.17
504.3401489	3.33
505.2728271	7.29
506.4515381	0.07
515.3283691	0.12
517.1809692	0.29
528.2755737	0.07
534.2866211	0.50
535.3045044	1.16
537.3676758	0.04
538.0711670	0.07
541.6486206	0.16
546.5880737	0.12
547.2395020	0.20
548.4096680	0.08
549.2369995	0.02
557.1845093	0.04
558.3242798	0.03
564.2827148	0.03
575.5094604	0.03
579.3419800	0.21
581.1768799	0.58
589.1074829	0.17
597.2227173	20.99
597.8768921	0.05
607.2459106	2.95
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	335.1117
Annotation	Scandenolide
Peak:m/z	Relative Intensity
96.0478897	0.06
104.8456345	0.08
109.0590286	0.26
109.8609085	0.16
110.8612518	0.34
119.9287796	0.23
123.2117615	0.09
135.0854797	0.12
145.1809387	0.15
147.0114136	0.04
149.0364990	0.33
160.8152771	0.10
163.1412354	0.08
167.0935974	0.06
170.2819061	0.07
171.0030212	0.10
175.1332245	0.10
177.2477875	0.13
179.0268555	0.25
184.1929016	0.12
185.2779388	0.16
186.9641418	0.22
189.0240784	0.13
191.0587921	0.22
193.1083679	0.06
195.1590576	0.14
196.6856537	0.17
209.0110168	0.62
210.3379822	0.03
213.0279846	0.18
219.3347168	0.18
221.0140076	0.25
223.2238770	0.09
225.1237488	0.31
226.9883728	0.08
229.1589050	0.26
231.9278564	0.36
233.1009216	0.83
234.9913025	0.04
235.9290771	0.05
238.1350403	0.13
239.2049255	0.74
240.1181946	0.39
241.1741943	0.49
242.0678711	0.08
245.3320618	0.15
246.3190918	0.12
248.1003113	0.50
249.0931396	0.20
251.1927490	0.08
258.0072937	0.04
258.8443909	0.10
261.2331543	0.20
262.3200684	0.43
263.2663574	0.53
264.2759399	0.46
265.1785889	0.31
268.3404541	0.06
270.2850342	0.07
273.2090759	0.15
274.4689636	0.74
275.2537537	0.31
276.3417053	0.45
277.3331299	0.38
279.1296997	0.19
280.2268982	0.88
281.2171021	1.23
282.1039734	0.51
287.3119812	0.07
289.1938171	1.48
291.1725464	0.12
291.9268494	0.04
293.1104126	0.97
298.2349854	7.32
299.1801147	7.47
299.9902954	0.12
303.1176147	0.35
307.1094360	0.28
308.3327026	0.19
311.2531128	0.13
313.2806396	0.34
316.3083496	46.23
317.0503845	100.00
317.7518311	0.86
320.0511169	0.09
335.1124878	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	393.1296
Annotation	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
Peak:m/z	Relative Intensity
131.0451202	0.10
147.2778778	0.06
150.9096375	0.12
154.9370728	0.66
171.1330109	0.08
176.2672119	0.07
189.1663818	0.13
208.6697388	0.10
209.2818146	0.11
211.5221405	0.04
215.1838989	0.21
221.5798950	0.16
238.9490662	30.09
239.9874268	1.63
243.0733337	0.25
255.9324951	0.08
256.9743347	0.23
275.4294434	0.18
277.3859863	0.17
279.8544922	0.33
280.7940063	0.02
288.6434021	0.08
296.5033569	0.05
297.2024231	0.12
299.4217834	0.13
305.6695557	0.06
307.1918030	0.39
307.9622192	0.72
308.7073364	10.53
310.0539551	0.10
323.9814758	74.38
325.0797119	100.00
326.0321655	0.08
331.2061768	0.04
333.0926208	0.18
347.1806030	0.07
348.2069092	0.09
349.2987671	0.09
358.8750916	0.97
375.1164246	0.40
377.4042664	0.18
378.4567566	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	587.12
Annotation	Unknow
Peak:m/z	Relative Intensity
171.8191833	0.11
173.1677246	0.38
215.0449677	0.08
216.9423828	0.51
226.7192841	0.20
235.2543793	0.20
237.0677185	0.06
243.0568542	0.34
245.0700836	0.20
260.9054565	1.32
273.8356018	0.20
275.0989685	6.97
278.7884216	0.73
284.9071045	0.14
288.6829834	0.08
291.2043457	0.69
292.9806519	0.21
301.1220093	0.87
303.1207275	1.17
306.8399048	0.42
319.1663818	0.42
321.0479126	72.02
336.8488159	2.71
362.5282593	0.85
363.1697388	1.68
374.8880615	0.32
377.9291382	1.70
379.0949707	10.68
380.8860474	1.86
392.9092407	0.67
395.2202759	0.42
396.7221680	0.55
404.6442261	0.25
407.0720215	1.14
410.7608643	0.20
417.1433716	0.21
420.0705566	0.20
422.2620239	0.62
423.0316162	2.46
424.9489136	52.72
425.5935669	0.25
435.0791626	0.62
441.2171631	0.33
452.7711792	0.56
453.4049072	0.43
465.0856934	3.25
466.8686523	0.99
472.4429932	0.10
481.6141357	0.84
483.0915527	100.00
489.3688354	0.20
496.8397827	0.15
501.1010742	0.80
508.9147949	0.22
514.9641724	0.20
525.4721680	0.43
526.8024292	0.71
551.3345947	0.65
569.0357056	2.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	475.175
Annotation	Neocalyxin A
Peak:m/z	Relative Intensity
133.9788971	47.16
143.0401917	0.69
144.9146423	5.56
147.9795685	4.66
162.9199066	57.97
175.2194824	0.56
181.0329285	1.47
210.9721832	0.58
217.0097198	0.62
252.4719238	0.30
254.1402283	0.89
258.8826904	0.70
270.5244446	0.91
271.1531982	10.11
278.0323486	0.50
288.9151001	14.75
295.3028564	2.45
296.0006714	7.64
306.2991638	2.62
306.9732056	10.79
313.4426270	1.71
314.0474243	3.90
322.4175720	1.34
324.3221436	6.45
324.9642944	100.00
325.9235840	0.38
331.1023865	0.51
341.4674377	0.36
342.2111206	0.81
342.9662476	11.06
361.5442200	0.50
440.1811523	5.35
458.0247803	56.88
458.6807251	0.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1556
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
173.1839905	0.02
180.1387939	0.02
181.0695953	0.07
182.8709869	0.01
187.6341858	0.05
196.9723053	0.07
201.2962036	0.01
222.7026367	0.03
224.2111359	0.27
224.9218445	0.07
249.0998535	0.05
257.3395386	0.02
269.0397339	100.00
271.155426	0.05
291.1936646	0.02
293.1617432	0.21
303.1553955	0.04
307.0211182	0.03
311.1501465	0.29
325.0649414	0.02
330.2732544	0.02
337.2102661	0.04
353.2123413	0.12
354.3723145	0.02
355.2669678	0.03
367.15802	0.03
370.9724731	0.02
373.4534302	0.05
413.2041016	0.03
415.2940674	0.08
427.5668335	0.04
431.4616699	0.07
433.2470093	0.72
445.1415405	0.05
449.1289062	0.03
457.3425903	0.11
475.376709	0.11
487.3899536	0.09
489.1438599	0.07
517.270813	0.07
531.4274902	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	718.3036
Annotation	Unknow
Peak:m/z	Relative Intensity
204.1763611	0.12
205.1893616	0.19
209.1620789	0.03
211.2595673	0.14
214.9840851	0.06
222.2507172	0.02
223.1348572	0.26
224.1351624	0.09
225.0906372	0.14
225.7189331	0.05
230.9194946	0.09
233.1382599	0.09
235.4764404	0.02
238.0496826	0.08
243.2550964	0.37
247.3145752	0.02
249.2102356	0.08
251.0148010	0.04
252.1847382	0.11
252.9830017	0.22
257.1704712	0.02
259.1921997	0.03
260.8653870	0.05
262.2193298	0.16
263.3401489	0.12
274.1776428	0.29
275.2589722	0.20
277.2383728	0.46
279.2629089	0.14
281.4152527	0.03
283.2424316	0.08
285.1937561	0.05
287.1850586	0.19
289.1812134	0.38
291.2902832	0.27
292.3377991	0.12
293.2859192	0.34
297.0547485	0.15
299.4555664	0.24
301.2926636	0.11
303.1778564	0.08
305.0716858	0.35
307.1483765	0.38
309.3052979	0.17
310.9537659	0.17
314.3554688	0.10
315.3220825	0.99
319.1411133	0.09
321.0578918	0.30
323.2807617	0.34
324.9696045	0.12
329.1902771	0.59
333.2076416	0.54
335.3388062	0.24
336.9326172	0.15
339.3462524	0.17
340.9935608	0.29
341.6671753	0.05
345.1598511	0.07
347.5513916	0.03
349.5476990	0.04
351.4022217	0.47
353.4025879	0.18
355.3839111	0.13
357.1132202	0.16
359.0723877	0.11
363.1583862	0.06
367.0913086	0.16
369.0641479	0.41
370.4714966	0.03
373.3045654	0.49
375.1858521	0.43
376.1844482	0.04
377.5503540	0.16
381.3593140	0.03
383.1755371	0.23
385.1777344	0.11
391.2174683	0.31
393.2453613	0.70
395.4420166	0.12
397.3445435	0.06
398.3121948	0.02
399.3227539	0.19
401.3455811	0.24
403.7214966	0.08
405.3352661	0.06
409.1937866	0.27
411.5393677	0.36
413.3243408	0.39
415.0186768	0.14
417.3194580	0.08
419.2822266	0.15
426.1594849	0.06
426.9784546	0.04
429.3976440	0.05
430.3137817	0.17
433.2169189	0.09
434.6973267	0.02
435.4620972	0.06
436.0794678	0.10
437.1715088	0.22
441.4032593	0.13
445.1580811	0.08
451.1345215	0.10
453.4025879	0.30
455.1541138	0.39
458.9776001	0.03
465.3571167	0.05
466.2034302	0.04
469.3483887	0.27
471.0274658	0.14
475.3359375	0.08
477.3068237	0.06
479.3351440	0.33
480.2498169	0.10
483.3083496	0.13
484.3131714	0.07
486.0354004	0.02
487.9863281	0.02
488.9791870	0.02
492.8648682	0.06
495.1864014	0.68
497.1129150	0.45
498.2888794	0.11
500.4117432	0.32
502.3630371	0.16
511.3080444	0.36
513.2933350	0.22
514.3610840	0.19
515.3482666	0.15
516.5188599	0.21
518.3740845	0.04
521.4613647	0.03
529.0654907	0.63
531.3788452	0.11
532.6765747	0.18
533.3848877	0.05
534.3040161	0.03
535.1539917	0.04
536.5481567	0.15
537.2458496	0.02
537.8645630	0.05
538.5383301	0.15
539.4174194	0.72
544.2360229	0.31
545.1889038	0.12
550.4138794	0.06
555.2727051	0.27
556.3841553	0.26
557.3078613	0.91
560.3101196	0.10
561.9943848	0.37
566.4044189	0.15
568.4494019	0.17
570.3914185	0.17
571.3835449	0.24
573.1369629	0.08
575.2045288	0.49
576.3656616	0.26
578.2665405	1.00
580.3488770	0.11
581.0786743	0.17
582.3422241	0.05
584.2133179	0.03
588.2697144	0.07
589.1530151	0.02
594.3649292	0.50
596.2359619	1.37
598.1964722	0.06
599.0258179	0.41
600.1437378	0.06
603.9899902	0.17
605.2167969	0.32
612.3959351	1.17
613.2293701	0.47
614.4088135	3.31
615.4805298	0.02
616.3931274	0.03
617.6281128	0.33
618.4075928	0.03
620.1713257	0.12
622.2886963	1.19
623.2480469	0.27
630.6625366	0.09
635.2636719	0.07
637.1064453	0.08
638.1042480	0.14
640.3137817	22.24
646.3540649	0.07
654.3765259	0.14
656.2825317	2.28
658.2507324	19.28
658.9013062	0.55
664.2766724	0.45
672.2865601	0.27
674.5170898	0.82
676.2667847	0.14
682.2921753	1.29
700.2458496	100.00
700.9213867	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	749.21
Annotation	Unknow
Peak:m/z	Relative Intensity
219.2467346	0.04
220.4961395	0.03
231.2639313	0.02
338.1477661	0.03
339.1940918	0.04
357.1153564	0.28
381.3087769	0.04
399.2016602	19.54
404.8855591	0.02
419.3408813	0.07
422.9053955	0.14
429.0488892	0.05
441.0914917	4.26
442.1380615	0.06
452.9978027	0.04
465.0396118	0.05
470.7409058	1.95
471.6777954	0.09
481.1357422	0.23
482.9433594	0.20
488.2758789	0.04
489.2641602	0.05
499.2647095	0.16
500.8454590	3.78
501.5156860	0.09
530.8797607	0.43
543.0012817	3.09
544.7411499	0.05
560.3684692	1.02
561.0016479	5.51
561.6705933	0.01
568.7025146	0.05
569.4933472	0.06
585.3145142	0.02
586.8276978	0.18
595.5490112	0.07
603.1759644	0.09
605.1369019	1.01
615.2371826	0.12
645.1628418	1.60
647.1423950	0.07
660.7244873	0.05
663.2743530	0.71
668.0443726	0.03
687.1664429	0.05
705.1674194	100.00
705.8359985	0.19
707.3296509	0.03
712.4820557	0.08
731.3330078	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.109
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
125.0101700	0.09
133.1173859	0.04
135.0377502	0.38
148.2686920	0.09
149.1600037	0.06
161.1236572	0.29
164.1280365	0.05
175.3164062	0.04
177.0432434	1.26
179.0028381	2.89
189.1905518	0.13
191.0402527	0.64
197.2974243	0.12
201.1496735	0.06
203.1135254	0.27
214.9706879	0.06
218.9575653	0.13
221.0622253	6.81
221.7156372	0.09
227.4560699	0.16
232.9944458	0.31
242.9881897	0.22
251.0922241	0.48
260.0998230	0.05
263.1209106	0.36
269.3320007	0.06
279.7402344	0.15
281.0872192	7.80
287.0509033	1.35
287.6900635	0.12
304.3338928	0.05
305.2331543	0.14
323.1373901	100.00
325.2816467	0.16
327.2111816	2.13
328.0928955	1.89
329.2275696	5.88
345.1012268	0.14
347.2884521	0.13
357.1704712	0.28
358.1156616	1.05
359.2584839	4.37
361.1930847	0.20
364.0670166	0.05
369.2102661	0.30
371.2543945	0.26
373.2342224	0.07
389.2522888	0.59
403.2257080	0.43
406.1913147	0.17
413.1418152	0.31
421.6413269	0.08
431.1276550	2.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	699.3958
Annotation	Unknow
Peak:m/z	Relative Intensity
205.1583405	0.06
214.9795074	0.06
222.8285065	0.05
241.4183350	0.03
253.2216187	0.03
256.9994507	0.15
259.1860352	0.13
267.2299805	0.07
269.4408569	0.06
275.3208618	0.03
278.9655151	0.13
281.1883850	0.05
288.8490601	0.13
295.4873962	0.06
297.2352905	0.48
299.0681152	0.31
301.2048950	0.23
304.1237793	0.40
310.2437134	0.13
311.5467529	0.17
312.5012207	0.26
313.3934326	0.03
314.2205200	0.28
315.3481140	0.15
317.3042603	0.60
318.1992798	0.08
319.2579346	0.19
323.5273438	0.24
324.3444824	0.05
325.3817749	0.31
327.4238892	0.42
329.4208679	0.62
330.2315369	0.10
331.3703308	0.06
333.3652954	0.13
334.8352661	0.09
337.2001038	1.00
338.5192871	0.03
339.4070435	0.11
341.4108276	0.49
343.3944092	0.32
345.3528442	0.20
347.2963257	1.10
349.2359619	0.04
350.3857727	0.03
351.2670288	0.10
355.3317871	0.65
357.4101562	0.17
359.3527832	0.40
361.3590698	0.44
363.2062378	0.05
366.2456665	0.03
367.2927856	0.21
369.2263794	0.12
370.8678589	0.23
371.4717407	0.17
373.4249268	0.61
375.3928833	0.20
376.4537354	0.18
377.3480225	0.34
379.5106812	0.08
381.4381714	0.19
383.3673706	0.58
385.2230835	1.41
386.1425171	0.19
387.3106079	1.43
388.3507690	0.30
389.0593262	0.03
391.5711060	0.35
392.4096680	0.05
395.2796631	0.07
399.3696289	0.14
400.6309204	0.13
401.2866821	1.57
402.5203857	0.48
403.3403320	3.30
404.5082397	0.83
405.4401245	0.88
407.7458496	0.32
410.3668823	0.07
411.1772461	0.36
413.4171143	1.42
414.2587891	0.21
415.5416870	0.05
417.4191895	1.18
418.2066650	0.08
419.2919312	0.61
421.3953247	6.38
422.5216064	0.64
425.4826050	0.86
426.3549194	0.07
427.5371704	0.15
429.2600708	0.10
431.2673950	1.79
432.2597046	0.20
433.3355103	0.52
434.2342529	0.09
435.4055176	2.76
436.4621582	0.18
441.4224243	0.37
443.3614502	5.44
444.3870239	0.93
445.3934326	0.34
446.2259521	0.28
447.4526367	0.40
449.4301758	2.21
450.9061279	0.27
451.5442505	0.06
453.3197021	0.60
455.0781860	0.03
457.1954346	0.13
458.4774780	0.17
459.1817017	0.08
461.3726807	24.11
462.3475952	3.49
463.1295776	0.07
470.4611816	0.15
471.5181274	0.18
472.2432861	0.05
473.4234619	0.20
475.1649170	0.31
476.6079102	0.10
479.3914795	26.83
480.3969727	4.75
483.3292236	0.14
486.2888794	0.06
487.6296387	0.04
489.4723511	0.28
491.2591553	0.54
492.9951172	0.47
493.6275635	0.03
495.4398193	0.23
497.5414429	0.02
500.4512329	0.03
501.3380127	2.09
502.7040405	0.77
503.4399414	0.22
506.4447632	0.09
509.3857422	0.09
510.3585205	0.04
513.5395508	0.07
515.3561401	0.72
516.4174194	0.05
517.2711792	0.22
519.5098877	5.15
520.5053711	0.73
521.4691162	1.24
523.2859497	0.53
527.4130249	0.06
529.2171021	0.19
531.5922852	0.19
533.3346558	4.16
534.3851929	0.45
535.5721436	0.16
536.3489380	0.18
537.4110718	28.76
538.5045776	4.21
539.5423584	0.07
545.4537964	0.48
549.5230103	0.37
550.5489502	0.17
551.5778198	0.21
553.3407593	0.55
554.1243896	0.13
554.7892456	0.15
555.4044800	0.64
561.2333984	0.50
562.4573975	0.15
563.4091187	0.25
565.3596802	0.28
566.4648438	0.13
567.1619873	0.30
573.4074097	1.15
574.6864624	0.19
575.4888306	0.14
576.7297974	0.17
577.3768921	0.03
579.3869019	0.88
581.1736450	0.42
583.4617310	2.64
584.3298950	0.12
587.6458130	0.07
588.4360352	0.03
591.3920898	9.17
592.3328247	1.98
593.3871460	1.86
594.3547974	1.97
595.4288940	0.78
596.4238892	0.54
597.3682251	0.15
603.4933472	0.08
605.5592651	3.30
606.5010986	0.57
607.5225830	0.45
608.9982300	1.79
609.6139526	0.78
611.3699951	15.44
612.3907471	3.46
613.3476562	0.41
614.0811157	0.11
615.5429077	0.07
617.7396851	0.08
619.0748901	0.20
621.6502075	0.17
623.3922119	26.61
624.5022583	4.92
625.3576660	0.06
627.4694214	0.18
633.5646362	0.30
636.1370239	0.05
637.2518921	0.70
638.3986206	2.65
639.4598999	1.63
641.4253540	100.00
642.5364380	18.64
645.5188599	0.75
651.3871460	0.24
653.1677856	2.65
655.1286011	1.60
656.5053101	1.02
657.3939209	1.00
661.3590698	0.03
663.4951782	5.20
664.5046997	1.53
668.0703735	0.07
671.3385010	0.10
679.6724243	0.31
681.4496460	45.54
682.4608154	13.28
683.4900513	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	306.0763
Annotation	Glutathione
Peak:m/z	Relative Intensity
109.2085724	0.08
116.0373840	0.15
126.1608353	0.04
128.0003967	10.42
135.2238464	0.21
143.0471802	9.75
144.9709473	0.34
146.1273499	0.46
153.2809143	0.05
160.0515442	12.04
161.3770752	0.12
166.0776520	0.04
167.1163788	0.25
169.0307922	0.11
170.0110168	0.11
171.1329651	1.12
176.9418793	8.28
179.0814362	7.30
184.9853210	0.68
187.1964722	0.07
192.1240082	0.05
197.0957947	1.15
201.9165649	0.05
210.0910339	5.66
211.0046692	0.14
212.9933777	2.00
217.0029907	0.19
228.1808777	1.14
230.9943542	0.54
235.3926086	0.16
236.0708008	0.43
242.1388550	1.45
254.0696716	83.73
258.6872253	0.11
259.8756714	0.15
262.2707520	0.16
270.1898499	0.08
272.0961609	100.00
283.2059021	0.08
288.1531677	61.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	694.787
Annotation	Unknow
Peak:m/z	Relative Intensity
260.8970337	0.10
304.9133911	11.17
305.5319214	0.03
434.8691406	33.07
435.5011597	0.04
548.9562378	0.69
549.8357544	0.05
551.1606445	0.08
564.8021851	100.00
565.4213257	0.14
566.0888062	0.06
581.2833862	0.11
591.8400269	0.02
619.1041260	0.07
620.1445923	0.04
623.9857788	0.16
636.0608521	0.08
646.5487671	0.02
647.7024536	0.19
648.8359375	0.60
676.7952881	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	519.1923
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9575806	0.12
170.9162292	0.62
172.9506531	0.85
177.2089539	0.35
191.0903168	100.00
192.0002594	0.07
193.0326385	0.15
236.8043518	0.11
256.1140442	0.96
262.1660156	0.22
298.8778076	0.31
327.1320190	1.46
353.2313232	0.73
360.1206665	0.45
372.3408813	0.05
379.4705200	0.12
382.9738159	0.65
391.4675903	0.27
397.2667236	0.22
398.9646606	0.56
414.7001953	0.07
418.3918457	0.27
429.0619507	0.55
437.3183594	0.42
439.7020874	0.05
441.1147461	0.91
457.0026855	0.18
458.9796753	20.46
459.7165527	0.05
471.4224243	0.21
473.1825562	1.41
475.1527710	0.41
476.1198120	0.35
483.0988159	0.26
488.8805542	0.46
500.9681396	0.69
501.6671753	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.143
Annotation	Plumiepoxide
Peak:m/z	Relative Intensity
146.9389496	0.73
165.1837006	0.09
178.9871521	40.14
216.7805176	0.21
222.8622131	0.17
237.1234436	0.27
245.2216797	0.23
246.1925659	0.07
273.0511780	0.66
287.2079468	0.21
289.0275879	1.27
306.3687439	0.15
307.2524414	0.89
321.2514648	0.35
325.1137695	6.49
341.1133118	100.00
349.0130005	0.99
354.8779602	0.52
356.3322144	0.28
365.7397156	0.90
367.3224487	0.07
371.0978699	0.16
380.3711853	0.21
382.9511719	0.19
385.2565918	0.13
395.1425476	0.31
398.3612366	0.10
400.3794861	0.49
401.3019714	0.20
407.2742615	0.58
409.4869690	0.44
413.3922119	0.64
414.2722473	0.53
427.4633789	0.19
439.0936584	0.28
440.8565369	0.12
442.6917114	1.84
443.3288269	1.42
468.2738647	0.17
469.4656067	1.18
470.9377747	0.34
471.8762817	1.10
473.2947693	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.102
Annotation	Unknow
Peak:m/z	Relative Intensity
135.7697906	0.16
147.0741425	0.25
159.1240540	0.33
162.5872192	0.43
166.9588165	0.07
169.1309814	0.45
171.0825348	0.21
174.9482880	0.07
177.1223602	0.15
183.2589111	0.12
184.8675079	0.13
189.1259460	0.47
190.8811951	0.65
197.0828857	0.05
209.1385651	0.15
211.1361389	0.47
212.9794617	0.93
214.9152832	0.76
217.0705261	0.32
225.2001801	0.11
227.1153870	0.47
228.8125000	0.19
231.1010437	3.65
233.0213013	2.08
246.9622955	0.16
248.9111938	0.18
253.2297668	0.17
254.9587708	0.16
258.8195190	0.20
261.2252502	0.17
265.4766846	0.19
266.8953552	0.09
271.2597961	0.40
272.9645691	2.00
279.1526489	0.35
281.1510925	0.13
282.3108826	0.16
289.0470581	0.64
293.2040100	0.08
295.0672302	0.11
297.2085266	0.14
298.4592896	0.11
299.2702026	0.04
302.8253174	0.07
307.9858398	0.24
309.2167969	0.13
311.1889343	0.09
312.8967285	0.18
314.3712769	0.44
315.0784912	0.82
317.1498718	6.66
321.2691650	0.21
326.1705933	0.31
327.2101440	0.22
328.2630920	0.45
331.1444702	0.77
332.0946350	0.33
332.7489319	0.18
339.0824280	2.27
340.1811523	0.29
341.0539551	0.33
350.1018066	0.29
357.0227356	1.38
358.0762329	1.77
359.1542358	2.57
365.3372803	0.18
375.3325195	0.05
376.1923828	0.24
383.1956482	1.12
386.3972168	0.37
388.1307373	0.08
388.9274292	0.08
390.0354309	0.14
393.2963562	0.39
401.5596008	0.44
403.0113220	0.06
404.2126465	0.30
413.3258362	2.20
415.1215820	0.71
417.1600647	0.33
425.1022034	1.77
433.4007874	0.24
435.1298218	1.19
437.3133850	0.35
440.8494568	0.10
443.1324158	15.93
447.4430847	0.23
448.9678040	2.57
450.2221680	0.40
451.3173523	0.22
458.9590149	0.21
460.6026306	10.36
461.2136230	100.00
478.1078491	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	355.0669
Annotation	Caffeic acid 4-O-glucuronide
Peak:m/z	Relative Intensity
102.8913879	0.05
110.9463806	0.28
129.0287018	1.70
134.0756836	0.02
145.0694580	0.05
147.0341797	3.20
148.8901978	0.08
162.9327545	0.05
173.0009918	1.73
191.0263672	100.00
192.0785828	0.13
193.0897675	1.09
201.2805939	0.04
209.0312958	36.50
210.1172638	0.08
212.9720612	0.14
221.1772156	0.34
224.9445496	0.05
231.2734680	0.06
234.9574890	0.20
264.9313965	0.14
275.0903931	0.15
293.1885376	0.18
295.1399536	0.35
319.3580933	0.35
337.1494751	10.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	687.17
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
200.0749054	0.27
202.1489410	0.19
314.1475830	0.12
326.1773682	0.07
332.1921997	0.53
337.2289124	0.10
344.5976562	0.26
353.1048584	0.15
363.1051025	7.57
364.0808105	0.12
425.8554077	0.35
468.5559082	0.40
489.6029663	0.14
493.7049561	0.14
507.1102295	0.17
516.3197021	0.27
525.1342163	100.00
526.2526245	4.22
532.3522949	0.29
597.3126221	0.27
599.3863525	0.08
605.7067871	0.12
613.1159058	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	287.1958
Annotation	N-Acetyl-leucyl-leucine
Peak:m/z	Relative Intensity
83.9533234	0.01
100.1321716	0.02
112.7918091	0.01
122.9604340	0.01
144.0829773	100.00
144.9099426	0.03
154.9317322	0.04
158.1062622	1.02
182.7337952	0.03
185.4308167	0.07
190.9257812	0.07
193.0603027	0.02
200.0156555	0.09
200.9467468	0.02
218.1901855	0.03
224.9311218	0.01
242.9299316	0.02
246.1147766	0.02
252.0448608	0.01
269.4581299	0.06
270.1040649	0.03
271.1865845	0.01
278.0427246	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	548.92
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1088867	0.10
213.0073547	0.26
214.8022766	0.14
227.1668854	0.13
243.0681152	0.06
251.0899048	0.09
253.0342712	0.18
292.7003784	0.39
294.7413330	0.68
296.4031982	1.09
297.2020874	0.86
298.3756104	0.40
299.6431580	0.27
308.6527100	0.08
314.7813721	0.07
336.9635620	0.05
357.0218506	0.14
358.9848633	0.04
368.7839355	0.04
369.4350586	0.03
371.7629395	0.04
374.0245361	0.69
374.9878540	2.36
376.8804321	0.03
378.7985229	0.29
380.6734009	19.51
393.1691895	0.48
394.3352051	0.07
412.9812622	0.03
419.0494385	0.18
428.8295288	0.13
462.6452026	4.24
464.6317139	100.00
465.7189331	0.10
480.7783203	0.25
489.0977173	0.36
502.8001099	1.95
506.7320557	0.10
531.0958252	0.16
548.8368530	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2158
Annotation	Reissantin E
Peak:m/z	Relative Intensity
138.6933594	0.26
141.0345764	0.37
144.9464264	0.52
157.2496033	0.09
158.0403290	0.25
161.0634766	1.68
161.9201355	0.20
162.9742737	0.38
165.0006866	0.15
166.1488342	0.16
169.0732117	0.44
173.0521851	0.26
177.1341858	0.42
179.1820068	0.14
181.1372528	0.71
183.0162811	0.66
185.1218567	0.75
187.0908203	1.02
187.9905701	0.13
189.1904907	0.48
193.3131104	0.05
194.3255920	0.16
195.0976105	0.32
197.1766052	0.59
199.2147064	1.33
201.1157837	0.16
207.0742798	0.57
209.2168274	0.09
210.9393768	0.67
213.1760101	0.51
214.0677643	0.12
215.2953186	0.93
217.0495758	0.77
225.0836792	0.37
227.2378082	1.05
231.2249298	0.14
232.9224854	0.53
237.0124969	0.59
239.3338623	0.85
240.3046417	0.06
241.2853088	0.51
242.9406433	0.76
245.1395416	1.03
247.0747223	0.44
249.1621399	0.99
251.2268982	0.55
253.2168884	0.05
255.1505432	1.27
257.0608521	0.13
259.1785889	0.18
260.9209290	0.15
267.1122131	0.29
269.1507568	0.89
271.0485535	0.60
273.1700439	0.44
275.1344299	0.94
277.2736511	0.22
279.3197937	0.57
281.2219543	0.55
283.0743408	0.47
285.2409668	0.61
286.9393616	0.49
287.5674133	0.08
289.0570679	0.40
293.1444397	0.48
294.1534729	0.31
295.0931396	0.27
297.1738586	0.63
299.0365295	0.31
301.2198486	1.57
303.2244873	1.40
305.2072449	1.10
307.0502014	0.51
309.3032227	0.84
310.2469177	0.55
311.2649536	1.20
313.2424316	0.70
315.3179626	1.43
317.1583557	0.56
319.2857666	0.51
321.2882385	2.31
323.1655579	1.21
325.1218872	1.17
327.5703735	0.35
329.3620300	0.99
331.2555542	0.36
333.1324463	0.79
335.4514160	0.24
337.1877441	1.28
338.1961670	0.17
339.1787109	2.41
341.0824585	3.52
342.0729370	0.09
343.1023560	0.90
343.7024841	0.23
347.0299683	0.73
349.2557983	2.05
351.1235352	1.53
353.3185425	0.60
355.0195312	0.27
357.1119080	2.26
359.1091309	0.44
360.5673828	0.38
361.4158936	0.40
363.1269531	0.80
364.8555298	0.52
365.5424805	0.07
367.2280273	5.18
369.2609253	34.87
371.1395874	0.12
372.9259338	0.72
375.4802551	0.73
376.3970032	0.30
377.2775574	0.68
379.1546936	0.88
380.3459778	0.43
381.3512268	0.68
383.2400208	1.24
384.6335144	0.59
385.3286743	4.56
387.3956299	0.70
389.1713867	0.09
391.4726562	0.52
393.1781311	3.34
395.2800293	6.94
397.2148438	2.26
399.3343201	1.06
401.1697083	3.96
403.2891235	0.20
405.1103210	0.06
409.2639160	6.26
411.1464539	12.95
413.1306458	33.69
413.7591248	0.28
415.1601562	0.42
419.1529846	4.32
425.0003357	0.29
427.3094177	100.00
429.1383362	8.17
437.2818909	15.38
441.8786926	0.33
445.3365173	1.74
455.1299438	62.50
456.0296631	0.67
472.7394104	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	813.21
Annotation	Faratroside
Peak:m/z	Relative Intensity
273.2643433	0.10
284.8634033	0.05
286.9656372	0.07
300.8395691	0.03
302.0697327	0.04
305.0991211	0.81
315.1802979	0.16
330.2106018	1.12
345.1568604	7.76
347.0489807	0.05
357.2261353	0.02
357.9456787	0.01
399.4411621	0.08
417.2078247	0.04
449.0406494	0.04
465.4544067	0.04
491.9296875	0.05
493.3013916	0.20
500.9926147	0.04
507.1186523	39.97
507.8455200	0.03
535.2985229	0.33
549.2304688	18.76
577.0910034	0.15
589.1670532	6.64
589.7833252	0.11
591.1707764	3.40
608.9626465	0.02
619.5321045	0.07
621.7022095	0.08
633.1583862	1.19
647.2609863	0.31
651.1199951	100.00
651.7548218	0.26
655.3176270	0.02
657.2870483	0.15
665.3020630	0.05
669.1804810	1.97
671.4219360	0.05
674.9145508	0.09
687.3308716	0.07
693.2205811	11.57
705.1875610	0.92
711.0863647	0.53
723.0632935	11.04
723.7577515	0.05
735.2597656	0.07
749.4450073	0.14
751.2151489	0.27
753.1274414	30.78
753.7662964	0.27
767.2247925	0.16
777.1657104	0.03
783.2368774	0.70
795.1138306	1.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	219.1737
Annotation	Alloeremophilone
Peak:m/z	Relative Intensity
66.9002686	0.74
69.0202713	0.85
71.1219482	0.05
76.8798370	0.17
78.9170151	0.81
80.9704971	7.13
82.9132996	1.05
84.9986877	0.21
90.8377533	1.14
92.8798218	3.83
95.0128021	16.27
96.9375915	6.35
99.0123138	0.11
105.0057983	3.81
106.9563904	7.87
109.0230713	16.85
111.0077209	9.76
112.7076721	0.04
116.9620514	0.40
119.0160828	11.27
121.0357666	8.86
123.0480957	17.53
124.9550171	5.20
131.0180969	3.74
133.0997162	3.70
135.0621338	40.34
137.0394897	3.59
139.0502167	0.80
145.0462189	22.14
147.0734100	3.77
149.0727539	26.66
151.0269928	0.68
157.0242157	0.21
159.0225067	24.68
161.0968781	37.23
163.0872955	100.00
173.0514069	10.76
173.7740326	0.05
175.1576538	8.91
176.0727692	1.32
177.0268097	14.10
177.8966980	0.14
185.9371185	0.10
188.9645081	0.12
191.1956940	4.06
193.6962738	0.06
199.1202545	0.19
201.1658936	78.71
203.0821686	0.15
204.3275299	0.20
219.3628082	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	775.1844
Annotation	Unknow
Peak:m/z	Relative Intensity
302.8632202	0.55
321.1392212	0.89
330.0284424	0.97
343.0936890	0.15
361.1152344	1.32
411.3153687	0.24
436.9729614	0.44
453.1439819	5.04
493.1813354	9.97
494.1061401	0.34
504.8078003	1.17
585.2470703	0.99
595.7957764	0.15
601.0702515	0.39
607.4031372	1.09
612.9030151	2.34
625.2244263	20.75
627.2571411	4.95
643.2013550	26.75
644.3104248	2.54
655.1286011	0.53
679.5034790	0.89
683.3800659	0.25
695.1481934	0.65
699.2537231	1.36
713.1163330	0.66
715.1868896	100.00
716.1064453	4.33
731.3286743	2.21
739.2311401	1.59
757.2202148	8.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.1982
Annotation	Faratroside
Peak:m/z	Relative Intensity
286.0711670	0.02
287.2424927	0.05
291.4229736	0.03
302.1437073	0.03
305.3959351	0.18
313.3151855	0.02
315.0910034	0.05
322.9547424	0.10
330.2130127	0.67
343.0064697	0.03
345.1724854	5.72
347.2992554	0.03
367.4359741	0.02
387.1390381	0.05
404.9374390	0.05
449.0213013	0.13
487.4136353	0.04
489.2821655	0.04
507.1879883	30.91
515.5692749	0.02
521.4409180	0.03
535.4466553	0.14
547.5692749	0.02
549.2601318	15.45
563.2755737	0.02
589.2789917	6.10
591.2006226	1.52
615.1779785	0.06
617.2959595	0.02
619.2081909	0.02
631.3361816	0.98
632.1557007	0.19
633.0124512	0.12
651.1438599	100.00
651.7782593	0.69
674.4331665	0.05
693.1675415	9.69
699.2388916	0.02
733.2451172	1.97
734.7802124	0.13
749.7523804	0.03
750.4609985	0.02
751.4942017	0.11
775.7191772	0.05
777.0509644	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
174.9887085	0.07
176.9530182	0.99
185.1904602	0.05
199.2895203	0.08
200.8522949	0.20
221.2185669	0.05
235.4026337	0.03
255.4644623	0.02
271.2405701	0.32
273.425354	0.02
275.0340576	0.07
284.1416016	0.30
286.0895996	0.15
289.3151245	0.11
301.0857544	17.64
303.0610352	0.75
303.8209534	0.10
307.2124634	0.10
313.1253967	4.54
314.2327881	0.15
325.272522	0.11
327.9762573	0.06
332.8512573	0.02
337.0167847	0.04
343.1598511	7.33
347.2718506	0.08
351.1326904	0.03
355.0797119	0.02
361.2944946	0.41
365.9389648	0.06
367.0658569	0.29
377.1912842	0.99
379.3110962	0.03
381.3744507	0.07
385.3643799	0.18
391.2261963	0.19
397.4450073	0.04
399.4700317	0.05
401.40802	0.17
409.0824585	0.29
411.2041626	0.59
415.3341064	0.75
427.2095337	0.17
429.1810913	0.45
433.2595825	0.62
437.1309814	0.31
439.315979	0.14
441.1988525	0.04
445.1318359	1.91
446.4888306	0.07
447.1361084	1.16
450.6598511	0.11
463.1246948	100.00
465.175293	0.30
467.6355591	0.02
482.4659424	0.09
489.24646	0.07
509.7247925	0.11
533.2407837	0.04
540.2008667	0.57
543.1206055	0.05
547.2049561	0.04
551.3162231	0.05
552.4796753	0.02
555.1694946	0.07
563.175354	0.11
565.1463013	0.44
570.0454712	0.11
572.6182251	0.48
573.284729	0.44
591.1699829	4.74
592.2496338	0.10
594.6992798	0.06
602.9121704	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	556.7066
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9437408	0.29
162.6627502	0.13
164.9386444	0.14
180.6797485	0.15
187.0413208	0.43
191.0180054	0.09
193.1407166	0.15
197.2465820	0.32
202.9653625	1.75
203.9694519	0.22
215.0246277	3.93
217.0257263	0.27
221.2462158	0.14
231.1212463	0.17
239.0639191	0.12
253.0874786	0.46
255.2598267	0.18
261.0810242	0.06
267.2378540	0.55
269.1539307	0.57
271.1588135	3.33
274.7413330	0.25
281.2827148	0.17
283.2686157	0.19
284.1585083	0.20
285.0630493	0.06
287.1845093	11.74
299.1680298	0.96
307.0352173	0.63
309.2815552	0.11
315.2749023	0.36
319.3023071	0.24
327.1074219	0.16
332.0874634	1.29
337.0689697	0.06
338.5437012	0.33
339.5664673	0.15
346.0951538	0.38
354.0975952	0.08
355.1421509	2.69
363.3665161	0.18
367.6059570	0.08
371.2245483	0.53
374.5142212	0.27
384.4871216	0.06
387.0779419	0.62
392.2628174	0.47
394.7445068	0.08
396.3453979	0.70
400.0419312	1.29
400.7077637	0.20
407.1470337	0.11
417.7178955	0.15
420.2960815	0.59
429.2544556	0.46
430.3079224	0.14
451.2657471	0.60
453.1815186	0.12
467.9400635	10.87
468.7105713	2.96
486.1655884	0.33
487.1983643	0.21
487.8569946	0.52
489.1965332	10.44
489.8753662	0.14
497.7794800	0.58
498.9148560	0.25
501.0179443	2.41
501.6313477	0.29
507.3364868	0.07
508.2846680	0.61
510.6424561	0.52
515.0544434	0.76
516.3278198	0.20
521.8906860	0.35
525.1969604	0.53
527.0278931	0.14
534.5236206	0.24
536.0709229	100.00
536.9431152	1.52
538.2667847	1.39
538.9550781	1.50
539.5667114	1.99
540.4533081	0.69
542.1795044	0.15
555.0823364	0.46
556.4862671	2.76
574.5817261	0.42
596.9477539	0.19
598.0648804	0.59
662.6707764	0.94
663.6807861	0.25
732.8088989	0.89
733.7083130	4.84
734.5232544	0.19
738.5186157	0.09
739.2183838	0.06
784.5139771	0.70
799.7895508	0.14
934.6310425	0.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	773.2084
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
219.2558136	0.05
245.0986633	0.07
255.3621521	0.11
259.1961365	0.06
273.0884705	0.13
274.1738281	0.02
285.2468872	0.22
290.8622437	0.07
303.0461426	39.26
303.6715698	0.12
313.2494507	0.03
315.2247620	0.17
316.4318848	0.13
326.6920166	0.07
335.4939575	0.04
341.0076904	0.33
344.6070557	0.25
345.2332764	1.08
348.1281738	0.06
348.9682007	0.06
353.2604065	0.03
369.0595093	1.54
371.2105103	0.80
375.2351074	0.29
381.2027588	0.25
387.3032837	0.10
395.0806274	0.24
395.7832031	0.06
404.8594360	0.06
413.2091064	1.54
419.3889771	0.09
422.9695435	0.14
425.1795044	0.60
428.7893066	0.17
431.0853271	1.58
437.1593018	0.36
443.0990601	0.30
447.0057983	0.79
449.0578613	8.97
449.7082520	0.23
455.2386475	0.46
465.0324707	100.00
465.6821289	0.27
467.2136230	0.37
471.2026978	0.15
473.0946655	7.72
481.0297852	0.03
488.1759644	0.12
489.0377808	0.77
491.1126709	2.89
497.1427002	0.20
503.3082886	0.07
507.0515747	0.29
520.9042969	0.10
523.0955200	0.16
524.3482666	0.18
527.2167969	2.21
539.1697998	1.27
545.0354004	2.01
557.0194702	1.77
557.7042236	0.25
564.7089233	0.09
573.0098267	0.16
575.2086182	4.00
577.0269775	0.24
583.2280273	0.07
591.2096558	0.26
593.2563477	5.86
609.2518921	0.30
610.9869995	48.31
611.7346802	0.25
626.9420776	59.92
627.6747437	0.07
635.2031250	3.74
636.1997681	0.03
640.3860474	0.14
641.1970825	0.28
650.6719360	0.11
652.2794800	0.38
653.1704102	1.49
659.3495483	0.05
665.4338379	0.08
667.5766602	0.37
668.9321899	0.06
676.8707886	0.25
677.6138306	0.04
689.2229614	1.14
693.2702026	0.09
700.2346191	0.11
701.1873169	0.73
707.0246582	0.44
711.3332520	0.12
719.0891113	0.15
728.3416138	0.16
736.0621948	0.19
737.1956177	3.28
746.1762085	0.48
754.6516113	3.42
755.2887573	12.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	527.1406
Annotation	Unknow
Peak:m/z	Relative Intensity
158.8947906	0.22
160.9651184	0.06
169.0306549	0.21
173.9863281	0.08
187.1400452	0.14
188.0378876	0.05
189.1423645	0.40
190.8230896	0.06
199.0257568	0.65
216.0254364	5.37
217.1464233	1.61
231.1332397	2.26
257.1380005	0.11
275.1693115	0.31
299.1489868	0.04
311.1591187	0.05
319.1027832	100.00
355.1040039	0.06
359.2158813	0.02
365.3006592	0.25
385.1377563	0.03
395.4645386	0.07
403.0665283	0.24
423.2088623	0.12
436.1524658	0.06
441.2182617	0.03
447.4005127	0.18
480.2691040	0.53
481.1643066	0.16
483.1038818	0.07
508.4440308	0.03
509.4513550	0.10
513.2217407	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	604.1725
Annotation	Unknow
Peak:m/z	Relative Intensity
172.0394897	0.09
174.1421509	0.05
175.0952148	0.07
183.1233368	0.03
188.0330963	0.04
200.0670929	0.85
202.0316010	6.26
215.1799316	0.11
217.3270569	0.25
218.0064697	1.16
219.0434418	0.49
243.1157379	0.06
243.7286377	0.06
244.3329620	0.26
245.0794067	0.10
261.9898071	100.00
262.9235840	0.04
321.9627075	0.31
363.9734497	0.11
377.3186646	0.10
379.0130005	0.12
393.4348755	0.28
423.1486816	0.02
423.9464722	0.15
442.0036011	0.04
471.1914673	0.64
472.3398438	0.66
483.2174683	0.06
493.2395630	0.13
511.2597656	0.13
512.1101074	0.03
523.8609009	0.08
525.2072144	0.23
526.3993530	0.14
543.2490234	0.33
544.2412109	0.22
560.2694702	0.09
571.0292358	0.24
585.0524292	0.19
586.0320435	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	633.2549
Annotation	1beta-Hydroxybaccatin I
Peak:m/z	Relative Intensity
178.9410400	0.09
185.0995178	0.09
189.2124329	0.13
193.1853027	0.48
201.0853577	0.63
202.4727020	0.11
203.1592712	0.40
205.1163483	0.56
211.1719818	0.33
213.2571106	0.42
217.1982574	0.20
219.3666077	0.53
221.1207886	1.22
223.2219391	0.55
231.0180511	0.44
233.2369385	0.28
245.2303925	0.83
247.3019257	0.52
251.1771088	0.41
253.2473450	0.14
255.2117615	0.31
257.2114258	1.43
259.4198608	0.16
261.1788025	0.47
269.3922729	0.22
271.6989746	0.44
272.7732239	0.41
273.4498291	0.35
274.1333008	0.10
275.2460938	2.21
276.6997681	0.30
277.4018860	0.43
279.3807373	0.78
281.1179810	0.85
287.2836914	3.05
290.0054321	0.17
291.3580322	0.24
293.0128174	0.06
293.6685181	0.19
295.2832031	0.64
297.3328247	0.21
299.3281250	0.88
303.3557129	0.11
305.1575928	0.22
312.5345764	0.09
313.3477783	3.07
315.3109131	1.98
317.1396484	1.74
321.3612671	0.19
323.3839722	0.11
325.2427979	1.93
327.4191895	0.11
328.1986084	0.10
329.1134949	0.71
331.3183594	11.41
332.4934692	0.16
333.3538208	0.15
335.1630859	0.99
337.1871338	0.44
341.3339233	0.67
343.3185425	0.56
345.1727905	0.48
347.2359009	0.71
349.2544556	0.17
351.1915283	0.55
355.2575684	2.55
356.2539673	0.27
357.4497681	0.16
359.2249756	15.59
365.1074219	0.63
369.2151489	1.73
371.1866455	0.65
375.1929321	1.56
381.4905396	0.51
383.3271484	1.55
387.2838745	1.48
389.2789917	0.14
391.1708374	0.19
393.5255127	0.07
394.4964600	0.29
395.2906494	3.73
397.4211426	0.11
399.5332642	0.23
401.5443726	1.14
403.2432861	0.41
405.4561768	0.17
409.1715698	2.56
411.1268921	0.25
417.2769775	0.06
425.3728638	0.78
427.2588501	100.00
428.1421509	0.27
431.3579102	0.88
433.4003906	0.17
437.3593140	0.15
439.3557129	1.65
445.2221069	2.82
453.0994873	0.76
455.4440308	0.85
471.3264160	1.46
477.2744141	0.21
479.3889160	0.27
481.3414307	0.14
483.1981201	0.44
489.3989868	0.84
498.3842163	0.06
501.2819214	0.21
503.4462891	0.09
513.1016846	0.62
515.4603882	0.23
517.1846313	0.58
519.5241089	0.12
529.3019409	0.38
531.3849487	0.34
547.1422729	0.08
557.7387695	0.22
571.3074951	1.29
575.5223389	2.07
576.3425293	0.21
587.1532593	0.16
589.3225708	20.58
590.6861572	0.12
597.7075806	0.14
604.9641113	0.35
615.2845459	0.08
616.8128662	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
129.0561676	0.46
137.1049347	0.38
145.1002045	0.86
149.4105835	0.61
157.1476898	1.12
171.1776733	4.24
187.2049408	2.40
189.2320862	0.18
191.124176	0.20
195.1145325	1.68
199.1292267	2.05
201.1426697	3.22
203.0015869	0.60
211.1694794	1.15
213.3276367	1.39
215.1802063	2.72
217.0556946	1.62
225.0709839	0.98
227.1810913	2.91
229.2232971	2.04
231.1104431	2.30
243.2061157	1.79
245.1456299	1.35
255.2999268	4.86
257.0820312	4.42
259.2306519	0.92
261.5158081	0.44
263.2408142	2.04
267.1783142	0.66
269.2063599	1.61
271.3508911	4.09
273.2436523	1.12
277.3225098	3.24
283.3796387	1.94
285.1513367	7.98
285.762207	0.24
287.3070068	0.42
295.2636414	1.74
297.3208618	6.97
298.4559937	0.29
299.2776794	5.52
300.0319214	0.40
301.2896118	2.61
310.958313	0.57
313.5200806	2.94
315.3776245	0.81
321.2602539	2.33
323.2608643	8.35
325.3843079	1.87
327.3005371	0.97
339.2537537	100.00
340.1520996	2.86
341.3662109	21.67
342.9967957	2.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	459.0931
Annotation	Acacetin 7-glucuronide
Peak:m/z	Relative Intensity
129.0433350	0.62
143.0848999	0.14
145.1077576	0.70
147.0491028	0.92
154.8810730	0.49
158.2034912	0.12
159.0903625	0.17
160.8584290	1.00
162.9487000	10.10
172.9555664	19.48
187.0885315	1.98
189.1782532	4.08
190.9109802	6.97
231.0216370	0.98
232.9961853	1.11
249.2947388	0.14
251.0855408	11.93
255.3865356	0.71
275.1190186	0.35
277.0357971	3.38
293.0867615	7.08
295.0986328	100.00
313.1604309	39.98
315.0888672	0.13
319.1631165	2.06
337.1227112	77.88
397.3605347	0.41
399.2098694	1.93
415.0169373	0.09
429.0911255	0.14
440.8117981	4.35
441.4312134	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	341.0878
Annotation	Grevilloside F
Peak:m/z	Relative Intensity
131.7355804	0.03
133.0097961	0.44
134.9875336	7.54
160.9824982	32.70
162.7478027	0.04
175.0600891	0.06
177.1275635	0.05
178.9850769	100.00
189.0451660	0.04
195.2042542	0.08
201.2700958	0.16
203.0380249	8.17
218.9850159	0.06
221.1340637	1.40
231.2498169	0.13
233.1221619	0.89
235.3722534	0.04
245.0077209	0.14
246.9942627	0.05
251.0586548	2.41
263.1558228	0.15
281.0531006	3.53
281.6533203	0.20
296.9183960	0.07
305.4276123	0.04
323.2555237	0.51
326.2048950	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.177
Annotation	Coniferinoside
Peak:m/z	Relative Intensity
149.2713165	0.04
150.9667358	12.61
158.0680542	0.08
159.0247345	0.23
161.1227417	0.84
162.1290894	2.32
163.0250549	0.23
174.9310303	0.11
177.0633545	5.39
178.9278412	0.06
193.0946350	0.20
195.0041199	100.00
196.0668488	0.30
205.1114502	1.52
215.1449890	0.19
219.0813904	0.84
221.3452606	0.11
223.0024719	0.26
231.5320129	0.25
237.1317291	0.42
249.1819458	0.17
277.2243347	0.12
286.9866943	0.06
309.0695190	0.13
337.0186157	0.07
339.1875305	19.85
357.1998596	25.25
358.3370972	0.09
383.0313721	3.61
384.0349426	0.18
395.1645203	0.11
399.3555908	0.05
413.1965637	1.04
417.3033142	0.40
422.8448792	0.05
429.2179871	0.22
443.1015625	0.38
457.4736938	0.13
485.2057190	1.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	685.2
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
190.9707184	0.02
201.1956787	0.05
216.8936157	0.28
235.0398407	4.97
293.2235718	0.05
305.1511841	0.02
325.2308350	0.03
345.4592896	0.02
379.0533447	0.44
379.6898193	0.02
388.1359253	0.04
397.2296143	29.85
410.1547852	0.03
421.3270874	0.02
439.1901855	5.76
476.9548340	0.02
479.0888672	1.11
481.2982788	0.23
517.0465698	0.06
521.3071899	0.08
523.3394165	0.18
541.1333618	100.00
542.0200806	0.01
555.1953735	0.03
583.1652222	7.19
613.0138550	0.02
623.1869507	1.57
625.2919312	0.07
640.5864868	0.01
641.4232178	0.39
666.1713257	0.06
667.2366333	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	799.3299
Annotation	Corchoionoside B
Peak:m/z	Relative Intensity
229.1250305	0.12
284.0372314	0.08
287.3283997	0.42
346.3485107	0.11
347.1619263	0.29
355.1430054	0.04
358.1969604	0.14
387.1306763	0.37
397.3103027	0.07
398.7820435	0.05
423.2465210	0.21
473.4617920	0.17
491.3299561	0.09
493.3833008	0.69
515.2559204	0.28
535.1181030	0.39
561.5852661	0.12
576.7854614	0.17
591.3529663	0.12
593.6484985	0.23
595.3169556	100.00
599.6401978	0.09
603.5199585	0.47
619.3600464	0.32
621.4359741	0.45
637.4765015	0.30
644.6569214	0.22
652.0748291	0.19
653.2717285	0.53
654.1685791	0.37
655.2463989	5.07
655.9813843	0.15
679.3477783	0.03
683.4080811	0.10
693.3090210	0.09
697.4083862	0.97
737.6171265	0.58
739.3803711	1.01
753.4249268	0.34
755.4370117	0.66
757.2921143	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	757.2193
Annotation	Unknow
Peak:m/z	Relative Intensity
269.2397156	0.29
287.1213379	45.43
431.1560669	0.13
449.1441040	100.00
449.8156128	0.73
459.1212769	0.14
462.2935791	0.16
595.2026367	45.80
657.0759277	0.03
712.5110474	0.10
738.8152466	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	815.2193
Annotation	Faratroside
Peak:m/z	Relative Intensity
232.8886871	0.37
245.0276794	0.65
249.2302704	0.57
254.1965637	0.52
260.9085083	0.50
268.0412598	1.28
270.7547302	0.13
273.1324463	0.62
273.9824524	2.23
282.2739258	1.00
287.0303040	0.42
289.1628113	0.66
290.0612793	3.11
300.2071228	0.61
301.0368652	3.26
302.0941467	1.11
306.8627014	0.21
308.3404236	0.23
313.0436096	0.68
314.1736145	0.18
315.0870361	0.41
316.0732422	0.99
317.1626282	0.95
331.1119080	0.14
332.1287842	13.25
333.0728149	5.88
347.1363525	95.97
348.2143555	100.00
368.9706726	0.83
378.7867737	0.35
380.4804077	0.52
389.2944946	3.46
390.2014160	4.05
398.2987671	0.81
405.6523438	0.53
415.0645752	1.44
416.2492065	1.23
432.8181152	1.01
434.0518799	0.47
451.0136719	1.16
451.8886719	0.83
500.2189331	0.15
511.2365723	0.17
516.1551514	0.87
528.0211792	0.70
529.8363647	0.30
576.2334595	0.31
593.1774292	1.08
593.8997192	1.11
635.2131348	0.33
654.2234497	0.13
666.5588989	0.29
701.5490112	0.57
736.4201050	0.20
744.2533569	0.50
754.9522095	0.56
761.6812744	0.64
762.3795776	1.07
780.1669312	11.73
797.9138794	72.56
798.6770020	0.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	361.1504
Annotation	[3R-(3alpha,3aalpha,4beta,5alpha,6aalpha)]-3-[(beta-D-Gulucopyranosyloxy)methyl]hexsahydro-4-(hydroxymethyl)-5-methyl-2H-cyclopenta[b]furan-2-one
Peak:m/z	Relative Intensity
112.8516998	5.21
115.0539398	0.24
119.1150894	0.52
121.0928116	0.09
124.9571609	0.56
129.1152344	1.15
130.9989624	0.56
137.1423340	0.91
143.0258026	1.15
149.1181030	0.98
155.0729065	0.54
158.9334106	2.97
161.0207367	52.14
163.1704407	0.21
178.9453278	2.87
181.0667267	0.76
186.8614502	0.12
197.2996216	0.27
198.0288086	0.35
199.0092468	0.74
213.1476440	0.41
214.8728638	1.39
227.0604248	0.14
235.0314941	0.09
240.7841187	0.20
262.9384766	0.07
271.2369995	0.29
282.1569214	0.49
301.1230164	0.78
313.5643311	0.06
315.0288696	0.36
317.1390991	100.00
317.8677368	0.42
325.5954895	0.36
343.2616272	1.91
344.3345947	0.34
345.7038879	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	501.104
Annotation	Apigenin 7-(2''-acetyl-6''-methylglucuronide)
Peak:m/z	Relative Intensity
158.9872131	0.16
163.0270996	5.68
172.9770660	7.88
187.0398865	1.79
191.0059204	7.33
195.1260986	0.21
203.0118408	0.23
209.0655518	1.06
233.3777618	0.20
275.0832520	0.46
281.0684509	0.14
293.2794495	4.71
306.8983154	0.47
319.2670898	1.30
337.0511169	100.00
337.6697388	0.12
355.1226501	20.31
395.4052124	0.35
421.1707764	0.23
455.1875916	5.48
457.3259583	0.49
463.1257629	0.61
483.4102478	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	551.7155
Annotation	Unknow
Peak:m/z	Relative Intensity
189.0918732	0.09
190.9512024	0.16
193.2131042	0.29
202.0735626	0.30
203.0167694	0.64
207.0539246	0.15
215.2733765	0.07
219.3071136	0.39
265.3125916	0.04
291.2294922	0.08
293.1886597	0.27
295.1436768	0.10
308.6263428	0.18
309.8210449	0.12
315.7869263	0.09
319.1883545	0.08
327.1065063	0.14
328.8156738	0.45
329.4791870	0.40
334.0184937	0.16
339.4666748	0.15
340.3334351	0.10
344.5214233	0.10
354.0610962	0.09
358.9606323	0.09
363.2738037	0.09
365.3029785	0.11
379.4589844	0.10
382.8228149	0.73
383.4301147	0.03
385.9914551	1.62
387.2357178	0.40
395.0956421	1.80
396.1494751	0.10
397.1063232	0.16
407.0019531	0.10
415.2170410	0.18
416.0119629	0.24
421.9918823	0.11
426.3989868	0.34
452.2316895	0.10
456.2165527	0.11
462.9414673	7.97
463.7442017	0.84
465.5324707	0.22
469.1774292	0.21
470.9149170	0.31
483.5808105	1.24
484.3336792	0.62
490.6160278	0.07
495.2399902	0.07
503.2023315	0.47
506.3063354	0.04
515.6616821	0.13
527.9796143	0.33
531.0856934	100.00
532.2521362	0.28
533.7506714	0.36
534.5889282	0.26
537.5739136	0.09
540.1284180	0.26
551.4909058	0.81
552.1004028	0.11
587.4773560	0.31
588.2708740	0.17
653.0022583	0.20
653.7827759	0.16
723.4512329	3.56
724.6832886	1.03
729.5429077	0.17
733.9225464	0.41
747.2766113	0.09
754.6702271	0.13
755.6010132	0.16
765.3325806	1.37
789.0237427	0.90
920.2234497	0.24
924.6793823	1.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	486.071
Annotation	Unknow
Peak:m/z	Relative Intensity
136.0877228	0.05
137.2497864	0.06
140.7882233	0.02
149.0009613	0.54
150.3437958	0.02
151.3121948	0.03
160.1244659	0.03
167.0557098	0.87
177.2709656	0.06
178.1506195	0.18
179.1035461	0.18
197.0862732	0.19
198.0478821	1.99
205.0429688	0.39
206.2162476	0.05
209.0221558	0.13
216.0369263	2.83
217.0025024	0.41
244.1703491	0.05
251.0178223	0.09
258.1345825	0.54
262.3007507	0.03
269.1721497	0.16
288.1765442	0.41
300.0865479	1.35
302.3968811	0.04
318.1800842	0.03
323.0839233	0.03
331.8953552	0.04
342.2312622	0.64
343.1150513	0.14
349.3851318	0.02
360.1200256	100.00
361.1264648	2.90
362.3796997	0.03
367.0092468	0.02
368.3711548	0.05
388.2827454	0.11
406.2527771	2.55
407.4055786	0.04
425.2267456	0.05
440.1378784	0.05
444.2611389	0.05
468.1611023	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	489.12
Annotation	Protocercosporin
Peak:m/z	Relative Intensity
141.2181396	0.17
142.1439819	0.27
142.9216461	0.40
146.9134521	5.08
148.9856110	0.47
152.3254395	0.47
153.1173706	0.14
155.0011902	0.65
156.9544678	0.95
158.9621124	0.31
161.3059540	0.10
164.5509338	0.23
165.1812592	0.06
168.9247131	0.17
170.7258606	0.39
172.8483429	0.57
174.0579376	0.52
175.0057983	4.35
181.6502228	0.13
182.5424805	0.45
184.0490417	0.12
185.0556030	0.93
186.9074097	0.16
189.1535034	0.14
191.2766724	0.31
192.2068176	0.15
193.2424011	0.50
194.3347168	0.21
197.2543640	0.78
198.8656616	0.21
201.0382690	1.05
203.0112915	100.00
204.1169739	0.22
207.1934814	0.48
209.3960114	0.57
213.1866608	0.65
215.0372772	0.69
219.0066071	0.08
219.9015808	0.19
223.1258545	0.15
225.1251373	0.52
227.2320251	0.23
228.0795135	0.09
229.1459656	0.95
231.0625610	0.91
233.1061096	1.01
238.9708710	0.32
241.1023560	1.38
242.8939514	0.46
245.0256958	0.92
247.2676697	0.52
251.1364136	0.13
252.9135437	0.08
254.0585327	0.15
257.9675598	0.63
259.2233887	0.11
263.2062683	0.45
265.1513977	1.88
268.5968628	0.55
269.1973572	12.62
271.1971436	0.09
273.1157532	0.22
285.0598450	0.37
287.0766907	65.39
292.3036194	0.08
293.3587952	2.99
298.7414551	0.30
335.2396851	0.25
341.4265747	0.05
346.8676758	0.17
355.2601318	0.33
359.1638184	0.24
364.8229065	0.25
365.5033569	0.09
368.9391479	2.13
369.6001892	0.15
377.2970886	0.47
383.2074280	2.24
387.4778137	0.39
401.5671692	0.20
413.3714905	0.06
435.3308105	0.17
444.4364929	0.08
453.1539307	0.29
467.7655334	0.26
471.0116272	1.43
471.9227600	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	813.3876
Annotation	Unknow
Peak:m/z	Relative Intensity
227.0693359	0.34
228.2385254	0.25
229.2911987	0.32
237.3871307	0.17
239.2059937	0.41
244.1114502	0.50
245.1859283	0.07
262.3186646	0.48
267.6560364	0.07
273.1261597	0.05
274.1728210	0.10
277.1432495	0.23
283.8936157	0.10
285.5194397	0.08
291.6392517	0.54
292.2950745	0.20
294.3532104	0.09
300.1809082	0.19
302.1009521	0.45
308.4066772	0.15
313.1212463	0.12
317.8701477	0.34
324.0970459	0.44
336.3002930	0.12
340.5756226	0.17
346.1251831	1.27
352.2525940	0.99
353.4187927	0.07
355.2491455	0.07
357.1880188	1.38
358.5164795	0.28
360.2073364	1.63
363.1701660	0.52
364.3024292	0.17
365.1353149	0.06
367.3908997	1.58
369.2676392	0.54
371.2080688	0.33
374.0263672	0.59
377.2169800	0.07
378.2660522	0.12
379.1066284	0.22
380.4130859	0.08
381.4273071	0.04
385.0346680	0.09
386.4950562	0.43
387.2895508	1.37
391.1999512	5.70
395.0526123	0.27
397.2099609	7.42
399.4574585	0.38
402.4253540	0.07
403.5336914	0.07
405.1067505	2.12
405.7073975	0.27
409.2197266	0.97
415.0771484	5.46
417.0698242	0.77
418.9390259	0.22
422.9622803	0.53
423.5791016	0.18
424.1929321	0.11
425.9960327	1.02
426.6013794	0.04
436.4327393	0.19
437.5477295	0.05
438.4906616	0.15
439.2661133	0.07
440.4564209	0.45
442.1102295	0.39
443.5024414	0.29
454.2412720	9.15
456.2374878	0.38
459.2332764	5.52
459.8377075	0.04
460.4399414	0.17
466.4149780	0.09
470.8077393	0.15
472.0174561	0.50
476.6424561	0.24
477.4268799	0.11
483.4719849	0.19
484.3441772	0.48
485.4025879	0.13
488.2682495	0.48
494.3477173	0.07
496.2335205	0.22
498.1170654	0.16
499.3776855	0.50
500.3790894	0.26
504.1860352	0.82
506.2919922	0.36
512.1495361	0.45
514.3035278	0.89
516.1885986	0.47
522.5449829	0.33
524.3020630	0.05
525.4471436	0.81
528.3873901	1.33
531.3923950	0.05
532.4987183	0.14
534.3607178	0.04
535.2446899	0.33
537.4535522	0.23
538.4172363	0.58
540.3552246	0.55
541.3162842	0.04
544.5317993	0.18
549.4052124	0.08
551.5324097	1.27
553.3397217	0.12
556.1611328	7.41
557.6099243	0.94
558.4148560	0.43
559.3432617	0.21
563.5341187	0.26
565.3547363	0.44
566.5608521	0.10
569.3198242	0.64
570.3051147	0.20
573.3729858	28.86
575.1923828	0.36
581.4027710	1.55
583.4403687	4.56
584.5620117	0.44
585.2882080	1.20
586.2571411	1.72
591.3333740	1.38
597.1103516	0.29
599.1556396	0.09
601.3651733	100.00
603.2732544	18.66
604.2079468	0.12
609.2627563	1.74
614.2658081	0.04
619.5524902	0.13
620.5127563	0.17
625.1886597	0.18
627.3871460	1.60
639.8548584	0.11
642.3196411	0.48
648.3585815	2.12
649.3240967	0.24
650.4337158	0.41
651.6693115	0.18
654.4337158	0.89
655.4942017	0.13
659.0476685	0.12
666.3865967	3.05
670.4105225	4.29
671.3175659	1.04
678.2261353	0.75
680.2582397	0.32
681.4164429	0.25
683.0676880	0.64
684.5269775	0.27
697.7420044	0.56
698.4667358	4.65
699.2919312	0.76
700.2141724	0.10
703.4873657	0.33
708.7189331	0.17
710.3255005	0.14
711.3561401	1.29
716.3200684	2.69
726.2913208	1.42
728.3934937	0.10
741.5280151	2.20
744.3085938	0.29
749.3626099	0.44
750.5598755	0.41
751.2919312	0.12
752.5942993	0.28
754.4768677	0.24
756.5729980	0.07
767.4024658	5.06
768.4357910	1.34
769.4998169	3.42
777.4322510	0.13
778.6898804	0.22
785.4513550	13.46
795.3823853	16.84
796.3431396	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.1874
Annotation	Cymorcin diglucoside
Peak:m/z	Relative Intensity
153.1006470	0.81
160.9664001	0.11
163.0860291	0.15
165.0137177	0.81
174.9805908	0.26
187.1520996	0.09
191.0594482	0.15
205.1887512	0.72
223.1024475	1.39
247.3079529	0.07
249.0751953	0.06
253.1360779	0.18
255.3406677	0.11
267.0552979	0.87
277.3926086	0.58
291.4277954	0.24
309.1422729	0.54
320.4994202	0.11
323.4273987	0.59
325.0980835	2.32
339.3746338	0.11
351.4368896	0.13
356.2964783	0.36
367.2475586	3.00
383.2384033	0.16
385.1203308	0.24
389.2442322	0.22
409.1532288	0.12
410.7372131	0.62
411.4691467	0.26
425.2975769	0.16
427.1869202	100.00
429.3682556	1.10
453.3217468	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	375.09
Annotation	Unknow
Peak:m/z	Relative Intensity
108.9103394	0.41
114.6790314	0.04
119.9626923	0.03
122.0045242	0.03
123.0390930	0.02
124.9597626	0.05
126.9806290	100.00
136.9830170	0.01
140.8439941	0.08
144.9245911	0.58
145.8123322	0.10
147.0281677	0.27
148.1396484	0.03
149.0203705	0.03
151.0901489	0.18
159.0250549	0.17
160.9892578	0.21
164.8062744	0.05
170.0898132	0.09
173.0836182	0.03
176.7428284	0.05
195.0593262	0.03
203.0958557	0.03
211.1529694	0.07
211.9332886	0.09
213.0927582	0.52
216.1511993	0.18
220.9323120	0.05
226.7634888	0.03
228.1473999	0.27
230.3851929	0.19
231.0431519	1.74
241.0874634	0.04
245.4583130	0.02
246.2059631	0.05
248.9638367	0.29
252.2146301	0.16
252.9957581	0.23
255.0825806	0.04
257.1419373	0.04
263.3176270	0.10
280.2094421	0.05
285.1665344	0.37
286.3768311	0.05
287.2491150	0.16
288.9622803	0.82
291.3789673	0.07
293.1901245	0.04
299.0671387	0.06
301.1778564	0.10
303.0939331	0.06
304.4152832	0.03
311.2365723	0.05
312.0770264	0.09
312.9222412	0.25
314.8900452	0.24
316.5901794	0.02
321.3795776	0.13
326.9413452	0.03
328.8673706	0.10
330.9679565	0.31
339.0538330	0.93
340.1339111	0.13
344.8670654	0.08
347.1124878	0.22
355.0589294	0.01
356.4960632	0.80
357.2298279	3.48
358.4762268	0.17
359.0899048	0.09
360.1430664	0.24
365.8501587	0.48
376.2559509	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	419.1924
Annotation	Unknow
Peak:m/z	Relative Intensity
148.6221466	0.15
150.9455414	0.12
160.8522949	0.10
178.0361328	0.07
212.1712341	0.28
239.5289917	1.14
256.3079224	0.49
257.0973816	0.67
289.3748779	0.47
313.2842712	6.19
331.2257996	1.43
337.4100342	0.22
373.1610107	100.00
375.2069702	0.11
377.5469055	1.08
391.6042175	0.84
398.2315369	0.25
401.2712097	0.45
404.4815979	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	596.17
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0798340	0.12
205.2609558	0.06
206.0524902	0.08
209.1619720	0.05
213.0862427	0.03
254.2720184	0.15
255.4382324	0.06
266.1223755	0.05
269.5563049	0.04
271.0745239	1.06
272.0698547	1.55
280.9071045	0.08
283.1247559	0.77
284.2938538	0.51
287.1167603	0.15
288.0664673	0.16
289.1552734	1.75
290.0909729	2.10
290.8963013	0.06
295.0762939	0.28
296.2655029	0.63
296.8825684	0.03
303.2922668	0.10
310.1634521	0.03
313.1996155	3.33
314.1145630	5.35
318.3564758	0.18
330.1618042	0.38
331.1105957	0.32
332.2606812	0.11
337.0331421	1.28
338.1306152	3.58
343.2263184	0.33
344.1461182	0.08
348.3478394	0.77
350.1837158	0.02
351.0423584	0.09
352.4669800	0.03
355.2968140	0.04
355.9810791	0.18
367.1975098	2.75
368.1402588	6.41
370.4389648	0.15
372.2915039	0.04
376.2467651	0.05
379.1976929	1.51
380.2592773	3.16
384.4378662	0.12
390.9407349	0.14
392.4232788	0.17
393.2223511	0.59
394.4821167	0.10
395.1848755	0.16
397.1065674	0.76
398.2200317	2.29
409.2093506	0.24
410.1676025	0.58
410.8717651	0.17
415.1842651	6.22
416.2231445	18.46
418.1940918	0.02
421.1177368	0.13
421.9687500	0.24
427.5305786	0.21
428.3774414	0.29
430.3038330	0.05
431.2495728	0.11
433.1615601	34.37
434.0900879	100.00
434.6925659	0.69
440.1927490	0.19
441.1514282	0.19
446.1115723	0.47
449.0843506	1.09
450.2220459	0.75
457.4826050	4.02
458.2149658	10.22
463.3427124	0.40
464.1899414	1.20
465.0805664	0.17
470.3048706	0.14
475.1293335	1.47
476.1500244	5.69
476.7745361	0.10
482.2357178	1.24
488.2435913	0.46
499.0333862	0.05
500.2085571	2.95
510.4884033	0.04
511.3970947	0.53
512.2230835	2.44
515.4096680	0.20
518.3440552	0.18
523.2904663	0.06
524.1871338	1.07
528.8046265	0.17
530.1809692	4.81
534.5643311	0.11
542.2593994	3.21
543.3651123	0.26
550.2915039	0.18
552.5609131	0.26
553.6630859	0.02
558.2496948	0.16
560.1377563	10.46
560.7630005	0.17
565.3823853	0.11
572.6538086	0.22
578.1240845	45.43
579.2283325	0.78
587.0786743	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.2006
Annotation	4,2'-Dihydroxy-4',6'-dimethoxychalcone 4-apiosyl-(1->2)-glucoside
Peak:m/z	Relative Intensity
194.8993225	1.00
217.0634308	0.35
220.9726715	0.22
230.8819733	0.53
245.2105103	0.90
263.0828247	1.40
281.1130981	0.80
283.2031860	0.12
287.1231689	12.57
300.4749756	0.40
301.1428223	0.49
303.2182007	0.97
304.8283081	0.62
310.5070801	0.55
315.1880493	0.76
321.2711182	0.68
323.1402588	1.89
327.1303711	0.41
329.3747559	1.13
339.2132568	1.25
341.0444336	0.80
343.1618042	2.26
345.1787720	9.09
351.2177734	1.07
355.0349121	1.19
356.5498657	0.17
367.2532959	1.59
369.1491089	2.66
373.1559448	0.81
376.2448120	0.32
391.2027588	0.97
394.9315186	3.10
397.1256104	2.45
403.1494141	2.53
409.2985840	0.95
411.1918335	0.38
413.1959229	7.02
423.5889893	0.92
426.1405640	0.82
427.3109131	0.62
431.1333618	20.08
433.0509644	2.56
437.0765991	1.87
445.2678833	6.42
449.0574951	100.00
449.7670288	0.35
455.1614380	4.01
456.9708252	1.43
459.6546631	0.90
463.1246948	25.34
472.9457397	10.68
473.6013184	0.55
475.1124268	0.68
479.1628418	0.21
481.4111938	0.45
491.1253052	7.63
497.1221313	2.43
499.2665405	0.68
504.8834839	0.44
511.3694458	0.17
515.2211304	1.84
523.0840454	0.27
529.1228638	0.77
541.1555786	19.46
558.5489502	4.02
559.1642456	38.23
574.9722290	0.88
576.4755249	4.03
577.1184692	26.94
595.1362915	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	659.2664
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
185.0720520	4.20
187.1363373	5.11
189.1171570	2.13
190.9070435	2.94
191.9253693	0.56
193.2836304	0.80
195.1456909	2.01
197.0978699	0.90
199.2690430	2.07
200.1677399	1.36
201.1380463	2.24
201.9541931	0.26
203.0816040	1.49
205.1412048	0.54
205.8924561	0.25
207.1450043	1.21
209.3032990	1.40
211.1627808	1.79
213.1362762	8.47
214.0962830	0.55
215.2082825	7.00
217.0166016	2.45
219.1386566	2.55
220.0032043	2.03
221.0654297	1.20
222.2093201	0.20
223.1470795	2.87
224.3814240	0.59
225.2621307	2.99
226.4785461	0.17
227.1650848	5.03
228.1895142	0.33
229.2328033	2.27
231.0366211	8.80
233.2664185	0.15
234.9831848	0.95
235.6873779	0.65
237.1623535	5.14
239.0365295	6.36
241.0853577	6.75
243.0095520	4.92
245.2528076	3.76
247.2196503	1.16
249.1119843	3.58
251.0239716	3.80
253.0605164	2.32
255.1961517	2.79
257.2859497	1.60
258.2253418	0.14
259.1422119	1.75
261.2976990	1.35
263.0760803	4.18
265.1980591	3.19
267.0990295	3.91
268.1767578	0.47
269.2084656	5.68
271.1998901	1.27
273.2970581	2.11
276.3092041	0.32
277.2937012	2.48
278.1061401	0.14
279.2030640	5.43
281.2882996	0.83
283.2604370	2.41
285.2398071	2.54
287.1044006	1.61
288.3280640	1.05
289.2167053	3.01
291.2479248	1.20
293.1334839	2.66
295.1136475	3.94
297.1774292	5.34
299.3225708	1.51
301.1479492	0.66
303.3577881	0.69
305.2401733	4.30
307.0737915	4.39
309.3262939	1.68
311.0036621	1.69
313.2646484	3.53
315.2510986	4.25
317.3243408	2.23
318.6964722	0.23
319.3506470	2.81
321.1105347	6.49
323.2573853	3.99
325.1607971	4.97
327.0425415	2.18
329.1429443	5.45
331.1410828	6.09
333.2100830	14.49
335.2487183	5.53
339.3270264	4.87
341.3171997	4.46
343.1531982	0.86
345.2593384	3.04
347.1737671	9.94
347.8422241	0.06
349.2355957	12.98
351.1190796	12.40
351.7709961	0.39
352.8770752	1.11
353.5061035	0.34
355.2090454	3.94
357.2959595	4.46
359.1430054	6.53
360.8383789	2.32
362.0368652	0.94
363.2290649	15.06
365.2753906	5.95
367.1537476	6.81
369.2047729	3.93
371.3481445	0.30
373.2177124	14.79
375.3173218	29.53
377.1555786	11.61
379.0423584	2.59
381.1479492	4.36
383.2976685	3.75
385.1950073	0.47
387.3074951	0.29
389.2026978	1.40
391.2619019	27.86
393.2389526	72.47
393.8419800	0.43
395.1808472	7.61
397.2487183	0.37
399.1387939	0.82
401.2860107	17.41
403.0633545	1.10
405.3013916	2.90
407.2862549	3.42
409.1710815	16.44
411.2172852	100.00
411.8441772	0.60
412.6987915	0.21
413.3267212	4.16
414.6390991	0.49
417.1109619	1.05
419.2504883	48.00
420.2942505	0.30
421.0812378	0.80
423.3648682	1.65
427.4123535	2.81
429.3107300	4.52
435.2363281	4.05
437.2553101	58.87
439.4429932	0.56
440.6085205	1.11
441.3346558	2.17
443.2092896	0.43
445.1223755	1.19
447.4270630	3.09
449.4096069	1.46
451.1076050	3.08
453.0886230	3.51
454.0675049	0.41
455.2620850	22.94
456.8675537	1.74
459.4485474	2.13
461.2575073	2.71
465.2335815	2.55
467.3251953	1.54
469.1526489	3.63
471.2084961	19.28
472.5387573	0.31
473.2277832	2.89
475.3334961	1.24
477.2133179	1.99
478.5097046	0.63
479.1848755	3.63
479.7949219	0.24
481.3472900	1.73
483.2584839	2.25
485.3726807	0.20
487.4407349	1.94
489.3964233	3.17
491.2963867	1.10
493.3134766	1.16
495.1682129	2.57
497.2324219	9.39
499.4155884	1.19
501.4272461	3.88
503.2394409	1.86
505.3825684	1.76
507.4196777	3.52
509.4363403	1.27
511.0086060	0.99
512.4143677	0.89
513.0834351	1.12
515.1850586	64.85
515.8435669	0.06
517.1763306	1.94
519.3503418	12.12
521.0034790	3.14
523.4179077	0.20
525.2187500	4.88
527.1565552	1.27
527.9570312	1.26
531.3979492	0.63
533.1397095	1.48
535.1570435	10.05
535.9284058	0.08
537.3343506	18.90
539.3470459	1.19
541.3874512	0.47
543.3810425	0.34
545.3139038	6.77
549.1522827	1.04
551.2133179	2.08
553.1254272	14.78
555.2551270	90.04
557.5203857	0.52
559.1882324	0.21
561.0625610	0.24
563.2821045	18.26
565.3627930	0.55
567.1006470	1.62
569.4848022	1.00
571.4307251	0.38
579.3276367	2.33
581.2068481	34.46
584.3527832	5.41
585.2919312	2.22
591.1021118	3.19
593.7751465	0.79
595.2257080	4.29
597.1372681	4.19
599.2041626	77.36
599.8410034	0.31
613.1960449	53.88
613.8619995	0.32
615.1221313	13.96
623.3517456	10.61
631.3071899	1.31
641.1820679	35.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	747.27
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
234.8585358	0.01
261.1972656	0.10
263.1341248	0.08
265.2296448	0.07
284.9740295	0.19
303.1257935	0.05
312.0857544	0.05
312.9756165	0.62
330.2915039	2.77
331.2893677	0.99
347.2106323	0.19
355.0428467	0.37
363.4510498	0.03
372.4143066	0.43
373.3362427	0.03
387.1281738	0.06
397.2478027	0.69
405.1168213	0.10
423.2519531	0.62
429.5668335	0.06
439.2475586	0.07
441.2285156	100.00
442.0943604	0.03
447.5177002	0.04
459.3177490	0.08
465.2604980	0.64
474.4199219	0.11
483.1708984	16.43
484.8213501	0.14
488.0105591	0.13
495.2510986	0.08
505.1463623	0.11
507.2954712	0.24
513.3995361	0.04
515.0758057	0.23
522.5283813	0.02
523.1926880	2.30
525.1909790	0.45
541.0308228	0.03
543.3029785	0.35
549.1296387	0.03
555.2434692	0.27
558.7921753	0.09
567.0518188	0.43
585.2525635	54.07
602.3732910	0.13
603.1481934	0.03
609.3471069	0.04
627.2363892	2.85
628.2363892	0.06
632.3687134	0.06
675.5799561	0.11
685.1506958	0.03
687.2374878	1.19
701.0664673	0.16
702.9707642	1.10
729.0779419	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	426.0078
Annotation	Unknow
Peak:m/z	Relative Intensity
138.0671539	0.68
148.8760986	0.22
174.6985016	0.17
182.2789917	0.20
200.0966797	0.23
217.9396057	0.50
230.0076294	1.40
234.1074219	0.11
235.9995728	0.22
240.1138611	0.12
247.1513367	0.16
257.8646545	1.04
262.1940613	0.27
271.4761353	0.12
275.9118042	0.07
283.9538879	0.23
297.3620605	0.19
302.1801758	0.34
304.1096191	0.13
305.9971924	4.04
313.0852051	0.14
313.7122803	0.30
317.7402344	0.67
320.2077942	0.10
321.8384094	0.11
335.9980774	12.58
360.9013062	0.08
365.8920288	1.78
377.7630615	0.23
379.9660339	0.20
381.9811707	100.00
382.6086731	0.72
384.3250732	0.27
390.0342102	0.66
395.8027039	1.13
403.6094971	0.12
405.9252625	1.31
408.0239563	2.22
425.8999329	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1454
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
200.4059143	0.02
280.9040527	0.03
311.2809448	0.06
327.0313110	0.23
329.3605347	0.11
339.2321167	0.32
351.1328125	0.06
354.4394531	0.01
357.1416626	0.17
367.3052979	0.05
369.2139893	12.51
381.1243896	0.52
383.3908081	0.05
392.4418945	0.03
395.0208740	0.15
399.1699829	15.56
400.1053467	0.14
409.1935425	0.06
411.1843262	0.58
413.2962646	0.39
422.8736572	0.03
425.2032471	0.01
429.2377319	5.31
430.0198364	0.07
435.1517334	0.71
437.3969727	0.02
439.2867432	0.05
441.2161865	0.83
443.4099121	0.12
447.2652588	0.23
453.3181763	0.43
459.1620483	1.22
461.1403809	0.03
465.1361084	0.20
469.0574341	0.02
471.2571411	5.65
472.3223267	0.06
475.1691284	0.02
476.2413940	0.02
483.2115479	0.26
487.3243408	0.09
489.1624756	100.00
490.2216187	0.85
495.2994385	0.16
501.2769165	2.29
505.3494873	0.09
507.5332642	0.06
513.3905029	0.16
514.0508423	0.04
515.2368774	0.12
519.1691284	24.35
519.7994995	0.26
525.3031616	0.02
531.2130737	2.32
533.1549683	0.16
534.2211304	0.11
537.0643921	0.11
537.6796265	0.03
538.3876953	0.03
543.3239136	0.17
547.2139282	0.14
549.2984619	0.68
555.2061157	1.24
561.2711182	1.38
564.3738403	0.15
573.2161255	1.10
579.0493774	0.05
591.2678223	7.40
592.2257690	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	374.81
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8365860	0.01
151.0955200	0.01
153.9675598	0.03
155.0356293	0.03
198.1428223	0.30
199.1813812	0.56
200.0897522	0.34
206.9069977	0.84
212.8804932	0.31
214.9234924	0.02
228.2025452	0.01
232.1289673	0.01
246.3062439	0.04
254.8972778	0.26
266.9124146	0.13
284.9836121	0.30
288.8752441	0.04
290.7503052	100.00
298.0541077	0.01
311.1846619	0.02
312.5624390	0.05
314.9583130	0.44
340.3015747	0.05
357.3542175	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	543.2935
Annotation	13beta-Hydroxymilbemycin A3
Peak:m/z	Relative Intensity
155.1226959	0.07
165.1578064	0.52
166.1918030	0.11
167.2426300	0.20
168.1507568	0.52
169.1012573	0.91
169.9851074	0.10
182.1927185	0.18
183.0791321	0.17
185.0030823	0.17
186.1554108	7.36
189.1562195	0.31
191.1293030	0.09
197.0776520	0.06
197.9636536	0.13
198.9851837	0.67
200.3838501	0.19
201.0815735	0.19
203.0745850	3.73
207.4510498	0.63
208.2206879	3.13
209.0288849	0.12
210.9022675	0.07
212.1472015	1.15
213.2214355	0.20
217.1105042	0.78
220.1372681	2.97
221.7292480	0.39
223.2217102	0.11
225.2111206	2.66
226.2088928	1.48
233.2888794	0.25
234.2666931	0.15
237.9292297	0.08
239.1107635	0.33
241.2424927	2.24
242.2681885	4.00
243.2028351	4.15
244.2804565	0.06
246.3131104	0.10
247.3675232	0.26
253.2376709	0.44
255.1852417	0.64
256.1919556	0.21
257.2807617	0.24
259.1717224	2.15
260.1727905	1.91
262.9251099	0.17
264.3141785	0.14
265.2311096	0.22
266.3950195	0.13
267.7744751	0.06
268.5092468	0.34
269.2138672	1.38
271.3169556	0.27
273.1105652	2.10
274.4753418	0.41
276.3171387	2.98
277.1468506	0.43
278.3929443	0.08
279.2263489	0.24
281.3834229	0.92
282.2451782	4.33
283.2427979	4.77
292.9999084	0.04
294.1627808	0.05
295.3900757	0.43
296.2402344	0.61
298.2016296	2.37
299.3024902	2.44
300.2874756	35.70
301.3435364	0.31
302.4639893	0.11
303.1979980	0.56
311.1205444	0.37
312.3048096	0.73
313.5590210	0.48
316.1563721	5.56
317.1926270	4.05
318.4595337	0.17
321.1404419	0.67
322.1508789	0.11
324.5251465	0.28
325.3739014	1.03
327.4096069	0.14
328.2903442	0.08
329.6173706	0.84
330.5057983	0.81
332.6076050	0.48
333.2636719	1.93
334.2841187	6.43
335.5166016	0.08
336.4913330	0.20
337.2117310	0.19
338.2830811	8.33
339.2376099	2.15
340.2373047	0.05
342.9202271	0.09
345.1693115	0.32
347.4025879	0.36
351.5950928	0.22
352.2879639	0.04
355.3867188	4.74
356.3609009	27.23
358.6287842	0.19
359.6076660	0.82
360.3624268	0.67
361.1453247	0.11
367.1673584	0.04
368.3027954	0.66
369.3431396	0.58
372.2420654	15.61
373.2574463	51.29
374.4263916	0.41
378.3863525	4.96
380.3498535	0.25
381.1349487	0.23
382.3635864	1.15
384.0957031	0.16
385.3916016	0.46
386.3280640	0.31
387.2945557	4.71
388.5570679	0.22
390.2656250	100.00
391.2687378	1.43
395.4201050	0.40
396.4079590	5.50
398.4420166	0.09
399.5739136	0.20
400.3210449	0.14
402.2925415	0.73
406.7507935	0.06
407.4960327	0.04
409.3528442	0.10
411.3014526	0.23
412.1997681	0.29
413.3950806	0.98
414.4422607	0.07
416.3668823	0.27
423.2166748	0.07
425.3456421	0.24
426.4251709	0.33
428.3608398	4.14
429.3281250	4.92
430.3366699	9.52
431.4024048	0.60
433.3870850	0.07
438.4311523	0.23
440.6459351	0.23
441.4704590	0.29
444.6385498	0.25
446.3877563	27.25
447.1325684	0.19
448.3273926	0.17
449.4688721	0.11
452.3068848	0.47
453.3176880	0.24
457.7769775	0.17
458.4110107	2.64
464.3563232	0.28
468.4591675	0.12
469.3569946	0.47
470.3731689	2.91
472.0289307	0.10
481.4308472	0.19
482.2885132	2.45
483.1438599	0.05
486.4323120	18.77
487.2330933	0.13
495.2070312	0.20
496.8499756	0.10
498.4369507	3.03
499.3604736	5.17
500.2933960	2.62
501.4015503	0.30
502.6985474	0.10
503.9908447	0.16
505.9907227	0.11
507.4418945	0.08
515.3056030	0.13
516.3323364	0.34
525.2434082	7.49
526.4960327	1.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1691
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
162.0861511	0.04
204.4864655	0.01
208.0456543	0.02
254.1813354	0.05
263.3772583	0.07
267.1471558	0.02
271.1557007	0.36
273.0710449	0.05
282.9741821	0.08
289.0979614	0.05
293.6915894	0.02
295.0596619	0.15
305.1549683	0.03
313.1094666	4.64
331.2787476	0.40
333.4242554	0.05
337.2080078	1.46
343.4650269	0.02
349.2225952	0.04
351.1435547	0.03
353.4475708	0.01
355.1391602	0.14
361.3322754	0.06
367.1377563	2.87
375.1109619	0.14
376.1066895	0.05
377.2380371	0.03
379.1315308	0.72
380.7651367	0.05
393.2445679	0.05
397.1369019	1.47
399.22052	0.14
407.5830688	0.01
415.2120361	18.06
417.1427612	0.33
423.5048218	0.03
426.8116455	0.02
431.1843262	0.11
433.1013184	100.00
433.9227295	0.02
435.414856	0.09
438.9820557	0.16
440.8966675	0.07
447.4249878	0.03
456.9122314	0.18
459.1046143	0.34
461.2062988	0.02
463.3319702	0.07
475.2393188	0.32
479.137207	0.04
482.6173706	0.01
483.2554932	0.08
494.7030029	0.02
497.8112183	0.07
499.4799194	0.02
505.2399292	0.03
509.0384521	0.01
512.6216431	0.04
513.2699585	0.10
517.1899414	0.05
518.1190186	0.05
525.1013184	0.08
535.296814	0.02
543.112915	0.90
561.0179443	2.03
561.710022	0.04
564.4263306	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	501.1586
Annotation	Nocardicin B
Peak:m/z	Relative Intensity
148.8883362	0.32
159.0485535	0.15
162.0451660	0.22
165.0540161	0.41
177.0928955	0.09
177.9575500	0.59
187.1250000	0.25
188.8886108	0.09
192.9951477	100.00
221.0757294	0.40
236.8632507	0.43
238.8099976	0.14
253.8684692	0.42
254.9768982	0.33
261.0807800	1.28
269.2360840	0.11
272.2378235	0.07
273.0562439	0.80
275.2696228	0.47
285.1493835	1.61
293.3822937	0.09
303.0313721	7.88
309.3114014	0.30
313.2937317	0.20
338.9956360	0.47
344.5063477	0.24
347.3876953	0.19
353.1357727	0.08
354.9734497	85.89
369.0360107	0.21
372.2867737	0.33
379.3859558	0.14
382.4053040	0.10
404.5971069	0.42
415.0008850	0.18
421.5184326	0.65
426.1802979	0.16
435.7394104	0.17
439.1810303	0.22
457.3162842	0.93
460.4455261	0.43
464.9315796	30.61
465.5911560	0.15
466.2590637	0.38
471.3681335	0.13
483.3051147	0.57
484.2768250	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.19
Annotation	Unknow
Peak:m/z	Relative Intensity
118.9815063	0.20
124.9361954	0.90
131.1106567	0.10
135.0679321	0.29
136.7554779	0.11
138.9573517	0.30
142.9572144	0.76
147.0937653	0.37
148.7674408	0.11
155.1124573	0.70
158.8713684	0.31
161.0288849	5.30
167.1358032	0.27
179.0326538	2.41
191.1252441	0.19
193.2451019	0.18
197.3123779	0.12
199.0771027	100.00
203.3227692	0.10
207.0639038	14.16
213.1951904	0.97
217.3311615	0.08
220.8598480	0.33
224.9690399	0.28
240.9833679	10.86
241.5946960	0.15
242.8795166	0.08
244.0276184	0.05
244.9463196	0.68
252.9744568	0.44
263.1374207	0.10
269.2489624	0.10
271.1356812	11.95
286.5367432	0.18
288.0625305	0.18
288.9424438	0.90
292.3015137	0.26
299.7337646	0.08
301.0319824	15.14
302.9761963	0.06
304.3423157	0.09
305.0787354	0.24
306.3642578	0.18
313.0321045	0.21
315.1123657	0.14
317.3457031	0.51
321.2911377	0.27
325.1971436	0.33
327.3250427	0.35
329.5507812	0.07
330.6384277	0.14
331.2741699	0.07
335.2284241	0.21
341.1597900	0.09
342.9754639	1.56
344.9572754	0.39
347.2654724	88.69
361.0071106	89.61
361.6828003	0.31
363.1503906	0.42
365.2247925	5.07
374.0950623	0.16
377.2010193	0.16
387.0762329	0.08
389.1553040	1.04
391.9555664	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
134.719696	0.38
153.1030426	0.44
157.0829468	1.51
158.8818817	1.30
168.9697266	0.25
170.5567627	0.26
171.182663	0.56
173.1656494	0.65
184.9810181	2.95
187.1693878	4.39
188.6385498	0.85
197.1232758	0.72
199.08284	2.67
201.2137451	4.24
203.1793518	1.56
215.209259	3.64
217.0727844	2.02
220.1022339	1.33
229.3518066	7.37
231.1517029	1.34
239.522583	0.32
241.370697	1.66
243.0565796	4.11
245.06604	0.58
255.1195374	2.37
257.2445068	3.00
259.0986328	1.08
263.2308044	2.13
267.3875732	1.44
269.239624	2.13
271.2732849	2.97
273.0844727	4.54
285.2355957	10.38
287.0622253	1.28
287.7590637	1.37
295.4695435	0.72
297.3512268	6.28
299.1804504	7.64
300.3029785	1.20
310.8095093	3.46
311.5698853	0.32
313.2276917	2.30
315.5205688	2.61
321.5541992	0.57
323.229248	3.83
325.2986755	3.59
326.3557434	0.38
327.0772095	0.53
329.3280029	2.65
337.1202393	0.81
339.2487793	100.00
340.1865234	1.11
341.2503052	22.55
342.3211365	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	395.0962
Annotation	9-Hydroxy-4-methoxypsoralen 9-glucoside
Peak:m/z	Relative Intensity
118.9262238	4.50
126.9283829	2.97
128.9576721	0.13
133.2022247	0.07
145.0019379	0.10
146.9298859	100.00
148.9937439	0.05
151.0972748	0.11
165.0366211	6.03
169.1695862	0.05
177.1272583	0.26
178.0934601	0.02
179.1382141	0.06
183.0579224	0.03
187.1131134	0.11
189.1176147	0.09
191.1863403	0.06
199.0069580	0.09
212.8977661	1.81
227.3117371	0.04
229.0581360	0.50
231.0354004	1.47
233.2710876	0.07
238.9638367	0.15
245.1763000	0.03
249.1109314	0.15
251.1451111	0.12
253.0872803	0.03
255.1019287	0.28
267.3827515	0.03
269.3604431	0.02
272.9944458	0.18
275.2202454	0.05
276.1172485	0.13
291.1298218	9.56
293.1426697	0.11
309.2926636	0.25
311.4553223	0.02
315.1276245	0.09
332.9163208	0.12
335.0930176	0.46
337.0434570	0.07
351.2605896	0.21
353.5081482	0.15
359.1875916	0.12
367.2860413	0.05
375.0918274	0.15
377.1960754	11.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1635
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
240.9040680	0.01
287.0603027	16.99
287.6774292	0.04
301.0169678	0.06
313.2069702	0.08
329.4783936	0.01
352.9672852	0.05
367.2457886	0.02
381.2525024	0.04
383.2026978	0.01
397.1583252	0.24
415.0656128	0.29
427.3815918	0.02
431.2875977	0.12
433.1447754	0.77
445.1445923	0.21
449.0280762	100.00
449.6383057	0.48
457.4922485	0.05
463.0322266	1.56
463.6827393	0.03
475.2240601	0.05
529.1297607	0.06
541.2559814	0.04
559.0759888	0.20
577.0575562	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1514
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
175.0102997	0.02
193.2635193	0.04
220.9976807	0.02
233.1591034	0.10
239.1484680	0.05
257.2908936	0.04
268.2789917	0.15
269.2037659	0.21
280.3462524	0.03
282.1877441	0.53
283.0933838	1.10
284.0417480	0.05
284.9059753	0.06
293.5007935	0.04
295.1452026	0.12
297.1174927	1.10
298.3002930	0.06
304.5160522	0.02
305.8274536	0.09
309.0242310	1.26
311.0567017	14.81
312.1310425	0.71
319.0100098	0.04
323.0842896	0.60
323.9520264	0.07
325.2826538	0.15
327.1289673	0.62
329.2039795	0.02
335.2097778	0.17
337.1613770	0.17
338.0513916	0.06
339.0380859	1.15
341.2105713	3.72
342.0714722	0.15
351.1367798	0.08
353.1874390	20.19
354.2263184	0.75
355.2283936	0.04
357.2075806	2.16
364.2670288	0.02
365.2235107	0.41
366.1457520	0.04
367.0718994	0.07
369.1738281	0.18
371.1923218	0.21
374.3021851	0.03
377.2062988	0.05
379.3538208	0.15
383.1923828	11.38
384.2864990	0.13
385.4114380	0.03
387.3916016	0.20
393.2333984	0.04
395.1303711	0.95
397.0178833	1.00
405.2700195	0.09
406.9131470	0.11
409.1975708	0.18
411.1121826	0.47
413.1984863	1.88
414.3145142	0.13
415.2518311	0.04
416.3789062	0.03
419.1220093	0.18
425.1283569	0.51
426.0943604	0.10
427.1358032	0.16
428.0088501	0.06
429.1348877	2.68
431.1329956	13.63
432.2186890	0.53
437.1165161	0.41
438.1315918	0.19
439.3656616	0.03
443.2731934	0.74
445.2548218	0.03
447.1223755	0.18
447.7460938	0.05
449.3215332	0.40
455.1710205	4.96
455.9096069	0.09
459.0244751	0.11
461.3706055	0.04
467.1566772	0.50
471.2348022	0.44
473.1174316	100.00
474.2841187	2.25
485.2020264	1.56
487.0902100	0.09
491.2427368	0.09
497.1978760	0.02
499.3079224	0.32
503.2531738	20.87
504.3212280	0.25
514.6760864	0.22
515.2932739	0.94
517.1129761	0.41
520.4580078	0.11
523.1890259	0.04
527.1251831	0.05
531.1258545	0.03
533.1252441	1.16
534.0684204	0.03
545.3290405	0.40
546.8109131	0.20
548.8547974	0.62
549.5407104	0.07
557.2171021	1.11
575.1525269	6.62
576.2301636	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	540.1407
Annotation	Unknow
Peak:m/z	Relative Intensity
155.0872498	0.06
161.9279327	0.64
175.0167542	0.07
179.0528107	2.01
187.0096588	0.20
205.1933289	0.11
206.9144592	0.16
214.9837036	0.49
215.9960938	0.30
232.9639893	4.86
245.1598206	0.21
249.0771332	0.04
250.0375214	0.08
251.0671539	0.19
255.3106079	0.16
274.2249756	0.11
284.1888428	0.32
285.3381958	0.10
290.0786133	0.33
299.9613037	0.06
300.9415283	0.30
302.3781128	0.29
308.1583862	8.41
318.0826416	2.53
319.0927124	0.96
334.1101074	0.07
336.0849609	35.27
341.0130615	0.09
344.1069336	0.78
347.0274048	0.21
349.3029785	0.08
358.1055298	0.09
360.3876343	0.04
361.3598022	0.18
362.3914795	0.60
375.3488770	1.04
376.2392578	0.36
377.9202881	0.29
383.1125488	0.23
384.2538452	0.17
385.1694946	0.06
393.2268677	3.34
394.0643311	0.07
402.0428467	0.75
405.9355469	0.04
411.2003174	100.00
412.0940552	0.06
413.1524048	1.43
420.3742676	0.11
429.1149902	0.38
431.1163330	0.24
447.0458374	2.57
458.8671875	0.12
465.1895752	11.93
477.2394409	0.09
486.2271729	0.12
494.1574097	0.08
496.0614014	0.05
504.2802124	0.53
522.2294312	10.51
523.1629028	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	581.1512
Annotation	Polygalaxanthone V
Peak:m/z	Relative Intensity
167.0193787	2.97
179.0462341	0.08
190.7909393	1.06
192.8911438	0.23
197.1872711	2.21
204.9281921	0.09
205.7269592	0.12
206.3529358	0.10
209.1203613	0.36
217.0654907	1.31
223.1926575	0.05
233.1434326	0.08
235.0171509	1.49
247.2196808	0.23
251.2209167	0.18
259.3346863	0.13
265.0868225	0.38
267.2222595	0.20
269.0796204	1.70
271.3634949	0.31
276.9420471	0.06
281.3949585	0.25
287.1264648	0.55
288.2124634	0.18
289.1566772	0.60
295.2111816	0.07
299.1221313	45.75
309.1131287	0.05
311.0809326	3.73
319.3815002	0.04
323.2705078	0.46
325.2901611	0.15
329.0883789	45.46
331.0200195	0.04
337.2609253	3.19
341.0807495	2.35
345.1135864	0.11
353.2456055	0.22
354.0380859	0.15
354.9926758	0.51
355.6203613	0.15
359.1918945	10.35
367.0779419	11.45
386.3198853	0.13
389.1235352	0.58
401.2014771	1.20
413.2192993	1.46
419.1682739	100.00
419.7750854	0.30
431.1193237	5.08
437.1223755	0.07
443.2779541	0.36
445.3289795	0.54
449.1459351	4.91
451.1679688	0.10
459.3670044	0.10
461.1435547	68.71
461.7653198	0.17
469.1636353	0.50
487.2325439	33.04
491.2937012	0.43
493.7193604	0.30
503.2526855	0.12
521.3549194	0.09
536.5529175	0.23
537.3261719	0.23
545.1546631	0.08
563.2276001	8.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	586.3218
Annotation	Unknow
Peak:m/z	Relative Intensity
168.1564026	0.04
178.8058167	0.02
181.1872711	0.12
183.1338348	0.02
184.2628326	0.04
193.5262451	0.08
195.1974335	0.03
200.8259430	0.05
203.8835754	0.01
204.7505951	0.06
206.9354858	0.02
208.3304749	0.02
209.9162445	0.26
213.0483398	0.01
214.2166138	0.07
215.1813965	0.05
216.9681091	0.02
218.5078583	0.05
224.1483002	0.17
224.7606506	0.10
226.1877899	0.06
229.7140656	0.05
230.6148987	0.07
237.6458130	0.11
238.2669220	0.03
240.2746735	0.08
241.7555695	0.04
242.8065796	0.02
244.6081238	0.16
245.8069153	0.24
249.3044434	0.02
250.4580078	0.17
251.1404572	0.09
252.1808472	0.13
253.9573212	0.04
256.3158569	0.07
257.0979004	0.09
259.0340576	0.04
264.1047974	0.01
265.1996765	0.07
265.9776917	0.10
270.2481689	0.10
272.0827026	0.10
274.1825256	0.05
279.3242798	0.19
288.4084778	0.74
289.3694153	0.08
290.0446167	0.14
294.1459045	4.90
294.7499390	0.81
295.3657837	0.14
298.2850037	0.02
299.2249146	0.07
303.1624756	18.35
303.8953857	6.68
305.9692383	0.02
307.2376709	0.01
311.1678467	0.10
311.9539185	0.07
318.2650146	0.05
319.9004517	0.03
320.7955933	0.08
324.0125732	0.03
326.9884033	0.02
336.4202271	0.05
337.6488647	0.04
339.0604248	0.03
340.8706055	0.01
349.2651367	0.14
349.9799805	0.03
355.1609497	0.22
358.2273560	0.02
364.3078003	0.02
365.3690796	0.02
376.2426147	0.07
382.7131348	0.18
388.2343140	0.04
388.8860474	0.02
390.2113037	0.05
391.2146606	0.09
393.1229248	0.11
400.0461426	0.03
401.2974243	0.07
407.3285522	0.13
409.2171631	0.14
413.1699829	0.07
418.2980347	0.08
422.3801270	0.03
424.5099487	0.03
426.2434692	0.10
431.8316040	0.08
433.1853638	0.18
436.3018188	0.03
440.3292847	0.15
446.4666748	0.02
452.4659424	0.03
453.1596069	0.05
454.3347778	0.55
455.4628296	0.15
460.4661865	0.04
462.3463135	0.04
467.7163696	0.06
468.4090576	0.04
470.2828979	0.14
477.3388062	0.02
479.5327759	0.01
480.1560669	0.07
481.4526367	0.16
482.9103394	0.10
487.0667114	0.04
488.4579468	0.08
492.4534912	0.04
493.2890625	0.04
494.4218750	0.22
498.5498047	0.08
500.3984375	0.08
503.2999878	0.02
504.6423950	0.09
505.4260254	0.02
506.9690552	0.15
514.9710693	0.43
515.8590698	0.38
516.9555664	0.30
518.2504272	0.36
519.7105103	0.16
520.3712769	0.37
521.1005249	0.39
522.8580933	0.27
523.8674927	0.03
529.2119751	0.58
530.0266724	0.80
531.5958252	0.07
532.5858765	0.01
533.6289673	0.18
537.2844849	0.45
538.2015381	0.30
539.1911011	0.25
540.4230347	0.04
542.2384033	0.19
543.0475464	0.16
544.1196289	0.24
544.8852539	0.03
548.8366089	0.27
549.6101685	0.11
551.5040283	0.02
554.1466064	0.16
555.3934937	0.18
555.9983521	0.10
557.3231812	0.46
558.0292358	0.59
562.6196289	1.93
563.7099609	2.22
564.7102661	0.30
567.4218140	0.32
568.5703125	7.65
569.4455566	1.49
571.5422974	3.48
572.5837402	6.24
573.7510376	0.71
575.3386841	5.44
577.5715942	100.00
578.4762573	10.26
580.1059570	0.05
581.9170532	0.05
587.3500366	0.10
589.4774780	0.03
605.4528198	0.68
606.3839722	0.08
607.3015747	0.03
667.1109619	0.06
691.5599976	0.01
1085.4119870	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	823.3413
Annotation	Unknow
Peak:m/z	Relative Intensity
239.9227600	0.01
241.2427368	0.02
268.3320007	0.04
296.1487122	0.27
297.3862305	0.11
302.9923706	0.18
311.0769653	0.02
314.1691895	1.44
315.2337646	0.42
316.9678955	0.04
318.3661499	0.02
332.2904663	0.27
333.2452087	0.17
339.2186890	0.03
340.3255005	0.10
341.3642578	0.07
342.3372192	0.03
356.3325806	0.20
357.2344666	0.07
358.6653137	0.01
359.3540649	0.05
367.3243408	0.10
369.3078003	0.02
374.5441895	0.09
375.2770386	0.11
376.3514404	0.06
385.2261963	0.98
386.3438110	1.11
387.3912964	0.17
400.4024048	0.03
402.3493042	0.08
411.2741699	0.02
420.5441284	0.10
426.5929565	0.01
428.2482910	0.16
428.9776611	0.07
430.3303833	0.17
431.1810913	0.07
445.2189941	0.03
446.3632202	1.03
447.3069458	0.38
449.0192261	0.02
457.2874146	0.40
458.2597046	0.64
459.4208374	0.35
462.1520996	0.02
469.3220215	0.03
472.7185669	0.01
474.1439209	0.04
475.4843750	0.11
477.1802368	0.17
478.1734009	0.11
479.2116089	0.10
486.3104858	0.07
487.5842285	0.06
500.2036743	0.08
501.1938477	0.02
502.4555664	0.32
503.3912354	0.45
504.4922485	0.26
514.2144775	3.78
515.3450928	3.39
516.3261108	0.04
521.3339844	0.19
522.0749512	0.05
529.8745117	0.13
532.3778076	1.27
533.3054199	0.71
539.5211792	0.06
540.4757690	0.04
543.3867798	0.05
544.4596558	0.13
551.5361328	0.04
552.2580566	0.03
553.4731445	0.02
554.6873779	0.06
556.1984253	0.12
557.2376099	5.29
558.3538818	4.60
559.4895020	0.10
560.4144897	0.18
561.5488892	0.15
572.4336548	0.01
574.3641968	0.16
575.3481445	0.16
577.3167114	0.03
580.3771973	0.07
587.5156250	0.03
588.4572754	0.09
589.4205933	0.64
590.3149414	0.51
593.5905762	0.01
605.1074829	0.05
606.2783813	0.30
607.3816528	0.24
608.3944702	0.35
614.4293823	0.38
615.5205078	0.41
616.6452637	0.01
617.7797241	0.11
619.4341431	0.05
622.4988403	0.47
623.3810425	0.33
624.3601074	0.05
626.2885132	0.07
632.3756714	0.60
633.4432983	0.61
636.3287354	0.12
637.3975830	0.02
640.1527710	0.02
644.4786987	0.34
645.3912964	0.98
647.0900269	0.17
649.6948242	0.20
650.5813599	0.15
651.2688599	0.50
662.4159546	0.06
663.3884277	0.07
664.3994141	0.19
665.3145142	0.34
671.5573120	0.02
676.9801636	0.02
680.1337280	0.04
681.6394043	0.11
682.4508057	0.10
690.5520630	0.06
691.8235474	0.07
695.4662476	0.10
700.6000977	0.13
718.0106812	0.75
719.4634399	0.88
720.3296509	0.04
722.1466064	0.07
736.1697998	0.02
743.4042358	0.43
744.3909912	1.19
745.6620483	0.03
761.3596191	67.16
762.3175049	100.00
763.1515503	0.14
764.4905396	0.03
769.9995728	0.05
779.3455200	13.63
780.3701782	20.55
787.1932373	0.05
788.3677368	0.25
804.7819824	0.32
805.9212036	0.55
806.6567383	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	401.0857
Annotation	Versiconal hemiacetal acetate
Peak:m/z	Relative Intensity
123.1413879	0.32
127.0453186	0.34
143.0651550	0.10
153.0017090	0.19
155.0124512	0.22
161.1176605	0.25
170.0804749	0.09
175.0567169	0.05
183.2002869	0.37
197.0969543	0.26
199.0648804	0.12
201.1994476	0.09
207.1005554	0.37
211.1742554	0.29
212.9820404	0.57
218.9058228	0.77
225.2520599	0.08
231.0026245	1.29
233.0686951	0.33
234.2144775	0.07
237.1109314	0.06
247.1833496	0.39
249.0361938	0.59
251.0592041	23.92
253.0496521	0.07
255.2227173	0.43
261.0934143	1.49
269.0941467	0.07
275.1770020	0.26
279.0149536	100.00
283.2805176	0.09
289.0163269	0.59
290.9724121	0.39
293.1878662	0.25
298.9656067	0.39
313.2698364	0.06
323.1274109	0.40
331.0032043	0.69
337.1360779	0.08
339.0919189	0.33
341.1948242	0.34
344.3234863	0.21
355.1833496	1.24
359.8780823	0.99
365.1028442	1.11
369.1240234	0.08
371.2711487	0.66
373.0290527	0.18
383.0735779	7.82
392.9725647	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	418.1329
Annotation	Unknow
Peak:m/z	Relative Intensity
124.0662460	0.46
125.9720764	0.04
128.9990540	0.28
133.9745483	4.96
135.8743286	2.08
136.4969635	0.08
138.8889923	0.03
140.2212372	0.05
142.9822693	0.06
146.1420135	0.04
150.0965118	0.10
152.0206299	14.45
152.9093933	0.09
153.9560547	0.07
170.0208740	23.53
176.0293427	0.28
186.9804230	0.33
188.1196442	0.20
193.8292847	0.12
200.0676880	0.12
201.1088257	0.03
204.1133118	0.14
206.3076630	0.21
212.1923218	0.08
214.1539917	0.13
218.0450134	0.69
221.2466888	0.03
227.1290588	0.05
230.0440674	0.05
232.5471497	0.04
234.1730347	0.07
236.0102234	0.39
242.2552185	0.13
246.5759888	0.08
247.3623962	0.07
248.1767273	0.16
254.0666504	0.05
256.6079407	0.91
260.1768494	0.36
273.0424805	0.03
278.2159424	0.09
282.5015564	0.13
284.1855164	0.18
285.0639038	0.04
285.8077393	0.12
297.1918945	0.05
298.2522583	0.15
302.0491943	0.04
303.3025513	0.07
308.0594177	0.17
312.2583618	0.25
313.5132446	0.58
314.2538452	1.73
315.0997925	0.20
320.1744385	0.41
326.1386414	0.41
326.8198242	0.08
328.0764160	0.24
328.7934875	0.07
332.1831055	30.62
334.2709656	0.11
337.5237427	0.20
338.2132874	6.15
342.4386597	0.27
352.1022644	0.48
354.1921997	0.13
356.1340637	38.48
357.2801514	0.20
358.0410156	0.16
364.3428040	0.42
374.1922913	100.00
375.2283020	0.13
376.2777405	0.13
377.0145569	0.09
382.1542664	2.12
385.1356506	0.10
387.2637939	0.19
396.8899841	0.06
400.1730347	54.50
401.3157043	0.26
408.8307495	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	463.1247
Annotation	Aromadendrin 7-methyl ether 5-glucoside
Peak:m/z	Relative Intensity
215.2809906	0.07
226.2476196	0.03
227.2291565	0.07
228.9357758	0.05
231.2777252	0.09
241.0955505	0.12
259.1015930	0.67
261.1142273	0.11
270.2778015	0.05
281.2277222	0.03
283.2250977	0.02
284.2379761	0.11
285.1470642	0.04
286.1702576	0.13
297.1785583	0.05
298.3395996	0.03
299.8079224	1.17
301.1079407	100.00
301.7565002	0.08
317.2545471	0.01
323.1400757	0.02
325.2253418	0.88
341.0579224	0.09
342.2162476	0.41
343.2354126	0.57
355.4523010	0.07
373.3624573	0.13
377.4241638	0.01
417.2778625	1.36
421.4604797	0.11
431.0463562	0.08
445.1894226	0.58
448.2588196	1.95
449.4246521	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1389
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
137.0411530	0.02
144.9626617	0.07
146.9146118	0.01
150.9411926	0.02
153.0687256	0.25
163.9732208	0.01
173.0650024	0.04
175.2742920	0.01
177.0342712	0.28
179.0922089	0.35
181.8713684	0.03
186.7713623	0.11
189.6227722	0.05
191.0567627	0.06
192.0467224	0.06
195.0000000	0.28
199.0839539	0.06
201.0346985	0.12
202.8604736	0.06
208.1800537	0.11
217.1956635	0.05
218.1096191	0.03
219.0114441	0.08
226.1353455	0.03
231.2640076	0.02
239.4604645	0.02
245.1463318	0.03
254.9980469	0.09
256.9264832	0.06
268.5120544	0.02
269.2390137	0.03
275.0824585	0.02
279.0596619	0.06
285.0261536	0.26
288.9804688	0.02
295.3804321	0.08
297.0973816	0.38
301.0671997	0.51
303.1082153	100.00
304.5478516	0.03
312.3547363	0.04
313.2697754	0.01
314.2061768	0.07
315.1325378	0.16
316.5525513	0.04
317.2656860	0.05
318.2777710	0.10
318.9792480	0.10
321.4154663	0.05
323.1577759	0.09
325.1103821	0.07
326.9795532	0.55
332.0567932	0.02
333.3211975	0.04
336.0470581	0.01
337.2135925	0.02
341.0697021	0.08
342.6220703	0.08
343.3128052	0.54
344.1379089	0.41
345.1021118	2.68
348.2779846	0.09
350.4374390	0.05
355.4994507	0.01
361.2748718	0.16
363.6065369	0.05
366.4658813	0.01
367.2394409	0.18
368.5300293	0.14
369.2298279	1.88
375.2646179	0.14
379.0971985	0.07
385.4033508	0.10
393.6207581	0.03
397.1716003	0.27
399.0888062	3.54
400.4242859	0.03
401.3050842	0.07
404.1324158	0.01
405.0313110	0.22
407.3281860	0.06
409.2611694	0.12
411.2131348	2.73
414.9424133	0.11
419.1732483	0.03
420.1759033	0.02
421.3213501	0.05
424.2092896	0.04
427.1895142	0.19
429.2479553	3.35
433.0837402	0.03
435.3619690	0.04
437.0842590	0.12
445.2904358	0.57
447.1233826	18.01
447.7958069	0.16
448.9998474	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.077
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
89.0596237	0.08
92.9998474	2.62
95.2544098	0.33
101.0189133	0.18
112.9578171	2.81
114.7132797	0.07
118.8724365	1.00
121.0608444	0.12
131.0391846	0.27
135.1457520	0.46
137.0027313	95.17
143.0320435	0.37
149.0589600	0.10
151.0136719	8.32
160.9323730	0.46
163.0883179	0.17
179.0426025	79.60
180.1561584	0.13
191.2122498	0.28
193.2054291	0.62
209.1143799	22.35
221.1160583	0.59
233.0900879	0.76
239.0255432	100.00
239.6694336	0.13
263.4918518	0.20
281.0229797	0.84
284.2335205	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1147.3156
Annotation	Unknow
Peak:m/z	Relative Intensity
345.2409058	0.26
357.4032288	0.05
441.0086365	0.07
449.2053833	0.21
459.0801086	0.12
477.1525574	13.32
478.1455078	4.10
478.8313904	0.05
489.2391357	0.07
500.2639160	0.25
505.2660828	0.09
507.4969177	0.20
508.1992188	0.09
519.1721802	6.93
520.3114624	5.08
527.5087280	0.07
534.2212524	0.12
537.0131836	0.14
541.5632324	0.08
549.0468750	0.21
550.4252930	0.06
559.2751465	5.51
560.2416992	1.66
561.2641602	0.80
562.3005371	0.61
564.8212891	0.12
585.3347168	0.40
591.1461182	0.20
601.3516846	1.36
602.3377686	1.03
603.3098145	0.50
604.2214355	0.25
621.1802979	28.46
622.1444092	23.36
627.2495117	0.03
628.3759155	0.10
641.6494141	0.13
642.2510986	0.06
644.9798584	0.11
663.1100464	8.36
664.2385864	5.89
668.4132080	0.17
675.2373657	0.18
676.3488770	0.19
680.3137207	0.13
681.0289917	0.06
682.5097656	0.09
684.8724365	0.23
697.2792358	3.96
698.3336182	2.62
703.3101196	0.93
704.3239746	0.52
706.0657349	0.34
729.2445679	0.05
735.3946533	0.04
745.2069092	0.11
746.8557129	0.06
764.9539795	3.40
766.2382202	2.42
766.8623047	0.12
794.9718018	0.21
816.4067993	0.03
826.3386230	0.08
859.2291260	9.49
860.2371826	8.14
868.0322266	0.07
884.1977539	0.34
895.5333252	0.06
901.1715088	10.54
902.2089844	9.69
923.1276855	0.03
941.2535400	6.98
942.2203369	7.26
943.0667725	0.92
944.1313477	0.99
956.1364746	0.17
967.5523682	0.38
970.1026611	0.11
983.0401611	0.48
984.3022461	1.26
985.0739746	0.77
1003.1328120	65.10
1004.1254880	100.00
1004.8920900	0.56
1023.2183840	0.21
1023.8659670	0.08
1032.2745360	0.09
1045.1856690	6.52
1046.1394040	9.72
1046.7650150	0.24
1075.4309080	0.32
1085.1549070	2.29
1086.1701660	2.13
1087.4555660	0.10
1102.7596440	0.08
1116.3051760	0.08
1120.2028810	0.11
1126.0646970	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.77
Annotation	Unknow
Peak:m/z	Relative Intensity
212.8123474	2.38
296.7523804	22.96
341.2980957	0.08
350.8025513	0.06
374.0254517	0.04
378.0741577	0.14
380.5695801	81.54
381.3411865	0.22
382.5796509	0.08
386.9737549	0.25
404.7954102	0.06
428.9620972	0.10
433.8474731	0.16
442.7884521	0.05
458.7786865	0.18
462.7800903	0.08
464.5053711	100.00
465.2011108	0.68
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.2237
Annotation	Rzedowskin A
Peak:m/z	Relative Intensity
151.0748138	0.38
177.3452606	1.52
183.1245117	0.19
186.9981079	0.44
191.1833344	0.57
201.2599640	0.80
203.0427704	3.59
211.3385925	0.29
219.3467407	0.24
221.3489227	3.36
222.3621826	2.07
227.2929077	1.18
231.1994171	1.25
233.0803833	0.44
243.2346497	2.29
249.0026855	3.73
259.1323547	0.95
261.1590576	11.92
269.2685547	0.85
271.3029480	2.11
285.2178955	0.76
287.1963501	3.42
289.3008423	8.79
291.2673950	0.13
293.1567383	1.38
303.4087524	3.17
305.2752380	1.07
307.1898193	15.06
313.1408081	0.52
317.3330078	0.70
319.2650757	0.36
321.5018921	0.28
323.2944336	1.47
325.3696289	0.28
329.0291138	2.29
331.1914062	11.11
335.3313599	0.45
345.2363892	1.65
347.2380981	23.21
349.3151245	100.00
359.2849731	3.65
365.2295532	24.04
366.4425659	0.54
371.2178345	0.36
373.1002197	0.87
375.5062256	1.65
377.1724243	10.21
379.4414062	0.67
383.2365112	1.60
389.2078857	4.95
391.4645386	0.44
401.3953247	0.51
403.2953491	4.17
407.2356567	13.73
419.2522583	3.39
425.4031372	0.90
427.2941284	8.48
435.3037720	12.12
445.1038208	4.23
461.5306396	0.26
471.2690430	46.05
487.6117554	0.32
489.2232666	2.96
503.1968384	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	423.2265
Annotation	Unknow
Peak:m/z	Relative Intensity
128.0524139	0.09
136.9883728	40.30
147.0486450	0.24
175.1623535	0.34
193.2432251	0.10
197.2428131	0.05
199.2925720	0.05
202.9721680	100.00
207.0338287	0.12
209.0874634	0.07
229.1272583	1.63
243.0812988	3.32
266.4231873	0.25
267.0413818	0.04
277.9959412	0.08
282.2376404	0.22
283.0015869	0.31
285.0082397	0.30
286.4663086	0.58
287.1099243	1.09
299.2896729	0.19
307.2144775	0.12
309.1026001	0.11
331.5194702	0.27
337.0220947	0.05
338.4219971	2.84
339.1134949	36.95
343.5111694	0.06
349.2166748	0.06
352.0487671	0.09
361.3306885	0.08
362.1255188	0.67
365.1605225	0.49
377.8970642	0.19
379.5222473	0.32
387.2591553	0.11
391.2586975	0.10
392.4592590	0.32
395.2777100	1.76
396.1404114	0.26
404.5928345	0.06
405.3460693	1.62
423.5472412	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	236.0791
Annotation	Unknow
Peak:m/z	Relative Intensity
72.8867188	0.03
86.9668427	0.04
104.0551147	2.43
105.0534210	0.04
132.9485626	2.30
141.0710602	0.03
148.8507690	100.00
151.8363647	0.10
162.0422974	0.40
172.5848846	0.08
176.7923431	27.97
177.4183960	0.07
178.9371185	0.22
180.2088165	0.04
191.9720612	55.95
200.2535553	0.05
218.1941528	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	681.1667
Annotation	Haploside D
Peak:m/z	Relative Intensity
225.1147156	0.03
235.1008911	0.04
238.1244507	0.06
297.0412903	0.03
303.2934875	0.10
305.2152100	0.45
317.1075745	0.70
345.2928772	0.43
346.1076660	1.14
357.1716919	0.02
360.1580811	3.88
361.1707153	1.88
375.1875000	24.90
445.0450439	0.12
505.2450562	0.09
513.3434448	0.14
519.3265381	0.06
523.1984863	2.41
535.3896484	0.10
537.2040405	100.00
537.8470459	0.23
565.2483521	3.45
579.2380981	49.05
605.2650757	0.67
607.0266724	0.24
619.2568970	15.82
621.3474731	0.38
631.1629639	1.27
649.2901001	0.10
663.2005005	0.91
666.3214111	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	773.2082
Annotation	Kaempferol 3-glucosyl-(1->2)-gentiobioside
Peak:m/z	Relative Intensity
323.8036499	0.09
340.9662476	0.19
353.2807617	0.43
365.4458923	0.06
371.1787109	0.20
377.2343750	0.16
417.3613892	0.04
425.1212769	0.07
437.3999023	0.42
449.1327515	0.19
455.0050049	0.09
472.6094971	0.23
473.2744141	2.30
491.2626953	1.28
497.4090576	0.56
515.1381226	0.12
527.4376831	0.10
533.1072998	1.87
539.2009888	0.45
551.2781372	0.18
557.4525757	1.10
569.2227173	0.46
572.3499146	0.11
575.2191772	0.47
587.1696777	3.33
593.0781860	4.64
598.6259766	0.23
599.2997437	0.57
605.1710815	0.85
611.3090210	1.95
617.2678833	0.97
623.1939087	0.21
635.1402588	45.94
635.8533325	0.11
640.8856812	0.31
653.1961670	13.27
659.0931396	4.08
671.2920532	0.30
677.1744995	5.07
685.6141357	0.07
689.1166992	16.20
689.7714233	0.18
701.1613159	8.19
707.1489868	13.53
713.0474243	0.20
714.2162476	0.11
719.2268066	9.26
737.1504517	47.07
737.8513794	0.12
755.1336060	100.00
755.8348999	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.05
Annotation	Aporpinone B
Peak:m/z	Relative Intensity
58.8304749	1.39
77.0262222	0.64
78.9207153	0.61
103.9561768	0.50
105.1890411	0.52
105.9555817	0.29
108.9826050	2.51
117.1471863	0.82
118.8145905	0.52
120.8905640	5.59
125.0865173	0.65
133.1060028	0.14
133.7140045	0.18
135.0364075	0.54
136.9736786	26.49
138.1964417	0.87
145.3330536	0.81
146.2650299	0.37
146.9417725	1.15
149.0242462	100.00
150.0087891	3.10
152.0933685	0.30
157.0980682	0.28
161.0079346	0.79
164.9628448	17.59
165.7731323	0.20
175.1102905	4.81
178.0813751	1.44
183.8931732	0.83
193.1162262	4.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	843.2189
Annotation	Unknow
Peak:m/z	Relative Intensity
263.2051697	0.07
271.0732117	0.10
272.8323669	0.06
274.2353516	0.13
302.0316467	0.25
305.2078857	0.70
317.0859070	0.61
344.9869080	0.37
351.2811890	0.13
360.0399780	2.07
373.4877014	0.02
375.1281128	10.05
407.1872559	0.02
477.3007812	0.08
507.4549561	0.24
519.5981445	0.13
523.1329956	0.08
537.1563721	53.37
537.8501587	0.14
549.0974121	0.02
579.2224731	23.17
591.2266235	0.09
609.4755859	0.20
619.1574097	6.90
619.7871094	0.09
621.2362671	5.46
631.5848999	0.07
645.3593750	0.24
651.0541382	0.85
663.1757202	0.93
667.3585815	0.01
677.5549927	0.08
681.1149902	100.00
681.9013062	0.09
687.1179199	0.29
693.2854004	0.08
699.1328735	0.26
705.4674683	0.06
717.1213989	0.20
723.1298828	17.76
723.8452759	0.17
729.0422974	0.05
735.1042480	2.10
741.3359985	0.12
749.2125854	0.09
753.1215210	10.68
765.1774292	0.70
768.7892456	0.10
771.4321289	0.07
783.1370239	43.87
783.7591553	0.22
789.3774414	0.04
799.1431274	0.11
806.8145142	0.05
807.5928345	0.16
813.1107788	0.29
825.1250000	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	449.1065
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
127.0613556	0.01
190.2573242	0.04
211.2109680	0.03
231.2789459	0.03
235.0465393	0.02
245.3607483	0.02
262.3702393	0.07
286.1352844	0.02
287.1210022	0.34
299.0557251	1.63
299.6624146	0.06
311.1939087	1.78
315.1338501	0.01
319.3070679	0.01
322.9535217	0.14
324.9599609	0.07
326.9729004	0.03
329.1164551	14.98
329.7585449	0.02
339.2983398	0.09
341.2597046	0.17
353.1896973	8.10
354.1624451	0.02
359.0267639	1.12
364.9911194	0.13
367.1434021	0.60
368.2576904	0.04
377.2821350	0.09
383.1011047	23.36
384.3127441	0.06
389.2931824	0.11
395.1639404	7.10
403.0235901	0.17
413.2134705	23.70
414.0160217	0.06
414.6404114	0.03
417.3844604	0.02
421.1647644	0.03
431.1513367	100.00
432.1033630	0.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.2054
Annotation	Tomentodiplacone B
Peak:m/z	Relative Intensity
132.0529785	0.66
137.1428223	0.28
141.2737427	0.63
144.6761475	1.01
150.8960724	1.73
153.0423279	0.42
156.8988800	3.26
161.0389709	5.95
163.1060486	2.35
166.1322021	0.14
167.1127319	0.18
168.3616791	0.46
168.9816895	0.37
171.0241089	0.38
173.2902832	0.68
175.0768433	3.99
177.1695557	0.78
179.0918274	0.80
181.4437866	0.48
185.1077576	3.18
187.1026611	5.79
189.0596924	1.44
191.0780334	1.75
193.1950073	5.60
195.0161743	1.90
197.1967773	3.13
198.0261688	0.31
199.2449036	1.04
201.0352631	5.00
203.1236267	4.25
205.2334747	0.20
209.3860779	0.97
211.0270233	2.33
213.1439514	12.09
214.0462952	1.50
215.1813049	61.96
217.0996399	7.35
218.9763184	2.30
223.2018585	1.55
225.2134705	1.06
227.1665955	1.11
229.1031189	1.49
231.1107178	1.58
235.0166931	1.38
237.1297760	4.26
239.0980072	2.92
241.0711212	5.41
243.3621826	1.35
245.2005615	2.25
247.2079163	1.35
249.1075745	5.15
251.2420959	0.61
253.1452637	3.65
255.2512817	2.35
256.1764221	1.26
257.1878967	6.73
258.9818420	1.31
261.1994324	1.38
263.2607727	2.08
267.1690369	2.09
269.1501160	10.54
270.1419983	0.22
271.1047058	4.30
275.3944702	1.20
277.1825256	0.33
279.0618896	6.28
281.1681519	2.37
283.3056641	2.04
285.3503723	1.26
287.0659485	3.80
289.3359375	1.36
290.4849854	0.35
291.1460876	2.00
293.2577209	2.43
295.2167053	1.83
296.9750977	5.20
299.1794128	3.71
301.0601807	0.26
302.8364868	1.36
304.8041992	0.81
307.0661316	0.65
309.0345459	0.33
311.1669922	2.71
312.9497375	1.86
315.2919922	8.42
316.6908264	1.36
319.2482300	0.65
323.1560059	6.10
324.5677490	2.79
325.3912354	8.07
327.0798950	4.03
331.1741028	3.07
333.0605469	9.62
335.1793823	1.27
337.2145081	1.83
339.2142029	4.79
341.3666992	3.12
342.6850891	0.72
343.3068848	2.36
345.3481750	5.43
347.2600403	1.66
349.1707153	10.94
350.3233337	1.23
351.3187866	8.32
357.1857300	0.25
359.1005249	1.29
361.2298584	0.73
363.3637695	7.06
365.1126709	11.26
367.2619629	4.70
369.0274048	2.77
373.3947449	4.00
375.3867798	12.68
377.2452698	8.20
379.3793640	0.48
380.2149353	0.78
381.3430481	3.48
385.1065063	0.81
386.8614807	2.29
387.6505127	0.48
391.2781982	7.31
393.2175293	90.55
395.1995544	24.70
401.3627930	0.72
409.2102661	36.28
411.2930298	100.00
413.0433350	5.60
419.1783142	19.78
425.1838379	2.24
427.4067688	6.29
437.1980591	46.86
438.2616272	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0853
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.93447113	0.23
79.0667572	0.29
94.74386597	0.81
102.8202667	2.05
104.8516541	1.59
106.7884521	0.32
108.8379059	1.12
111.0512695	1.34
119.0052795	0.34
121.0183411	0.26
123.0568848	0.43
125.1789093	0.22
126.9299469	2.75
128.9490662	7.43
129.8676758	0.27
130.8458099	0.11
133.0308838	1.49
141.1166382	0.77
143.0056458	0.21
144.9775848	0.89
147.1817169	0.64
148.0553436	0.41
150.9309082	54.70
152.0214081	1.60
153.0753326	0.83
155.0084381	0.34
157.0781403	1.17
165.0205994	0.86
166.1322937	2.10
166.9048157	1.86
168.1269379	0.25
169.0886688	0.99
171.0116119	1.20
172.1235199	0.16
177.0501251	1.36
178.8813629	0.55
182.98909	0.34
183.7103119	0.77
185.1105804	1.63
191.1290131	1.47
193.3059235	0.28
194.0531311	0.74
195.1968231	0.48
197.0593109	3.26
207.1506805	0.16
208.0478363	1.35
209.2115326	0.18
211.0052795	0.68
217.1519775	4.19
225.0599365	3.10
232.656723	0.71
235.0977936	10.80
235.961319	0.41
238.0981445	7.00
239.0112762	2.31
251.1862335	0.73
253.0767212	100.00
254.1013641	16.56
254.7631073	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	723.2858
Annotation	Unknow
Peak:m/z	Relative Intensity
278.9847107	0.24
291.1789551	0.06
323.3480835	0.11
349.1403809	0.30
366.9420166	0.17
455.3317871	0.83
470.9857788	0.42
473.1276855	1.35
486.2940674	0.07
497.3428345	0.15
504.8426514	0.54
511.4219971	0.09
531.2907104	0.09
535.1811523	0.15
553.4266968	0.77
576.5765991	0.22
577.6151123	0.35
581.5157471	0.06
591.1362915	0.19
593.3693237	0.66
599.2334595	0.34
604.6758423	0.19
617.3933716	100.00
635.1856689	8.26
635.8378906	0.05
655.0346069	0.54
663.2404175	6.92
677.1233521	15.98
679.2839355	0.07
680.9076538	0.10
684.8026733	0.23
690.8638306	0.08
695.7765503	0.17
705.1525269	0.57
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	216.9813
Annotation	3-hydroxybenzoic acid-3-O-sulphate
Peak:m/z	Relative Intensity
79.9122772	1.16
87.0235138	0.04
92.9996643	1.89
96.9461670	14.69
102.8117981	0.14
109.0301666	0.46
128.8384399	0.05
131.0827484	0.03
137.0370483	100.00
137.7082062	0.06
155.0971832	0.06
169.2167358	0.03
171.0700836	0.06
172.9266968	62.40
180.9877472	0.11
182.8607330	0.18
186.0759583	0.05
187.2407379	0.16
189.0548553	0.07
191.2527161	0.13
198.9142303	0.05
202.1121368	0.22
216.9941406	0.53
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	454.2914
Annotation	PE(16:0/0:0)
Peak:m/z	Relative Intensity
150.7742920	0.07
198.0890961	0.50
199.1130219	0.13
216.0050659	0.13
239.3173218	0.18
282.3299561	1.51
300.2744751	0.02
304.4855042	0.12
313.3395691	71.46
351.3920288	0.22
370.5155640	0.15
385.9492493	0.13
393.1825867	4.26
393.7963562	0.06
410.9385681	0.23
418.4721985	0.10
436.1571960	100.00
436.8536682	0.33
440.1896057	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2191
Annotation	Unknow
Peak:m/z	Relative Intensity
217.1290894	0.10
227.3102112	0.19
229.1842651	0.36
229.8302765	0.17
242.1036530	0.29
247.2332153	0.25
249.0836792	0.08
257.4643860	0.49
268.0933228	0.10
269.3337097	0.07
271.1241150	2.14
283.1077271	0.20
284.9378052	0.24
286.1495361	0.89
291.2212830	1.33
295.2737427	0.24
299.2129517	0.07
301.1786499	34.87
309.1932068	1.80
324.3330994	0.19
325.2211914	0.70
327.5482178	0.10
349.1394348	0.15
351.1334839	17.56
355.2388306	0.13
357.0466614	0.25
363.2338867	0.08
365.3686523	0.23
366.8308716	0.08
375.1817017	2.13
381.1846924	1.31
393.1987915	4.69
399.4360352	0.05
405.1211548	0.19
435.1488037	0.17
447.0942383	3.67
451.5326538	0.63
453.2717896	100.00
455.2968140	0.62
467.3037720	0.22
481.2990723	0.24
483.2737427	0.88
486.4869385	0.23
493.2797852	0.10
501.3602295	0.06
504.1883545	0.07
508.2775879	0.40
533.1403198	0.13
563.6550293	0.23
575.1293335	0.15
582.2562866	0.13
590.6535645	0.17
591.3587036	0.11
593.1990967	1.08
609.2800903	31.60
611.1477051	0.22
630.3591919	0.13
635.3659058	0.64
653.3483276	0.34
658.3673706	0.11
667.2399292	0.05
669.1057129	0.28
670.3306274	0.77
709.3535156	0.21
711.4066772	0.41
718.5600586	0.51
719.3038330	0.69
737.0701294	0.53
737.7988281	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	479.1175
Annotation	isorhamnetin-3-O-glucoside
Peak:m/z	Relative Intensity
140.9758301	0.04
167.0406036	0.05
195.9519958	0.03
275.2913818	0.01
307.3196411	0.01
317.0646973	100.00
317.6871033	0.31
332.1526794	0.03
347.1199951	0.02
349.3407288	0.06
350.1047363	0.13
359.3161316	0.07
375.9944458	0.04
377.0474243	0.04
389.3855896	0.03
413.421051	0.02
433.1551819	0.02
443.0228882	0.08
461.2252808	0.85
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.3145
Annotation	Unknow
Peak:m/z	Relative Intensity
201.1749573	0.60
202.3411255	0.48
203.2775269	0.79
207.8878021	0.05
211.1963196	0.64
213.0375061	0.19
215.1454315	0.30
221.9105682	0.09
225.0361938	0.13
226.9425507	0.40
229.0780334	0.35
232.1487122	0.14
237.2380219	0.34
239.3638000	0.16
241.3415680	0.59
243.1005859	0.15
244.9998474	0.63
247.3057251	0.13
248.1903076	0.09
249.2735443	0.48
251.0931854	0.59
253.3540649	0.94
255.1631165	0.98
256.3037415	0.10
260.9875183	0.66
263.2977905	0.11
267.1116943	0.82
269.2359619	0.38
271.0303650	0.30
273.0243530	0.90
274.8847046	0.41
277.0092773	0.38
278.8642578	0.17
279.4768066	0.23
281.1313171	0.29
282.9186707	0.73
287.0824585	0.25
289.4175720	1.34
291.1257324	0.57
293.2537231	1.23
295.3270874	0.14
297.2520142	0.61
299.4121399	0.22
301.2166748	0.13
303.2599487	0.35
305.3810425	1.57
306.3109436	0.27
307.3494873	1.44
309.3012085	0.21
311.0528870	0.92
313.0013428	0.19
315.2279053	3.18
317.2803345	0.72
318.2214966	0.20
319.5145874	0.19
321.1857910	0.88
323.1762695	1.37
324.1367798	0.23
324.8756104	0.15
327.2285767	0.99
329.2484131	1.08
331.1328735	0.42
332.2130737	0.35
333.1708374	1.06
337.1890869	1.11
339.3191528	1.34
341.3822937	0.31
343.4353027	0.61
345.2514648	0.24
347.2597046	1.63
349.1573486	1.90
351.2695923	0.92
353.2156982	0.07
355.2804565	0.44
357.0321655	1.52
359.1229248	2.48
361.2236938	1.05
363.1037598	1.07
365.3994751	0.51
366.7351074	0.31
367.3543091	2.71
369.2933960	2.66
370.8308716	0.15
371.5157471	0.19
373.1148682	3.28
375.2676392	2.78
377.3205566	2.02
379.3214722	0.08
381.3108521	1.75
383.2291260	0.16
385.3119507	0.39
387.5088501	0.16
389.2371826	0.54
391.2319946	6.61
393.2141724	4.08
395.3538818	1.41
397.0747070	0.23
399.3023071	0.48
401.1969604	1.74
403.1533813	0.26
405.3522339	0.15
407.4293823	0.37
409.2105103	5.09
411.2445679	5.40
413.2215576	1.99
419.1857300	5.72
423.4466553	0.56
425.4247437	0.56
427.1497803	2.69
427.7943115	0.15
429.2378540	1.10
431.6917114	0.24
433.3336182	0.86
435.3084106	0.49
437.2108765	9.50
439.1359253	0.90
440.5754395	0.34
441.4307251	1.47
443.1903687	0.28
445.1921997	1.98
447.0170288	0.37
449.2984009	0.36
451.1713257	0.70
453.2460327	0.61
455.1124878	23.77
456.9283447	0.20
459.1329346	1.02
461.4892578	0.22
463.2768555	1.12
465.3164062	0.57
467.2517700	0.93
469.1617432	1.00
470.6363525	0.16
471.3350830	0.74
473.1877441	4.08
475.2086182	0.70
477.3059692	1.13
479.1909790	1.35
481.3504639	0.96
483.4864502	1.62
485.1707764	0.72
487.2160034	0.23
489.2076416	0.18
491.2747803	1.94
493.3441162	0.50
495.2657471	0.97
497.1068115	1.46
498.9888306	0.73
499.6818848	0.33
501.2250977	3.68
503.2427979	2.84
505.4132690	0.73
506.1995850	0.15
507.4531860	0.55
509.1343994	1.17
512.7626953	0.35
515.2426147	5.81
517.2169189	1.14
519.3701782	7.45
521.4367676	0.48
522.8880615	0.05
525.2819214	0.36
527.2856445	2.58
529.0808716	0.05
531.1688232	0.14
533.3236084	0.95
535.2058105	9.38
537.2551880	8.71
539.1961060	0.18
541.3461914	0.20
545.1981812	3.99
547.4393921	0.08
549.3186035	0.16
550.3517456	0.10
551.5436401	0.13
553.1830444	8.27
553.7866821	0.18
555.1986694	10.05
557.1283569	3.48
557.7731323	0.10
559.2714233	0.89
561.3233032	0.85
563.2260132	18.24
569.3703003	0.15
571.1967163	11.26
573.3873901	1.03
575.0880737	0.27
577.2169800	1.26
579.2547607	4.70
581.1541748	55.29
581.8417358	0.14
582.8738403	0.19
587.1423340	0.27
589.1934814	1.49
595.0793457	3.98
596.2158813	0.17
597.1982422	7.83
599.1707153	71.45
599.8436890	0.18
605.2050171	1.41
613.2385864	4.01
614.7147827	0.61
615.3218384	5.79
617.2382202	23.55
623.1645508	8.68
623.7766113	0.42
631.1962280	2.84
633.1226196	0.09
634.6484985	0.09
635.3287964	1.75
636.8450317	0.29
638.0409546	0.46
639.4391479	0.75
640.4354248	9.86
641.0885010	49.54
641.7672119	0.29
649.3727417	0.18
656.3032837	0.22
659.2083130	100.00
675.4978638	0.10
677.0527954	17.08
677.8475952	0.12
680.0992432	0.26
683.0421143	0.28
693.7654419	1.00
695.2294922	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.2993
Annotation	Macrolactin C
Peak:m/z	Relative Intensity
170.2254333	0.01
190.9583435	0.06
199.1385956	0.02
201.8147888	0.09
204.9060974	0.02
208.8133240	0.25
232.2609558	0.04
260.1280212	0.02
263.0405579	0.03
265.3937683	0.09
271.1152344	1.66
272.2590027	0.03
281.0574951	0.10
283.1959839	0.16
293.2806091	0.19
295.0173340	0.15
296.7492065	0.05
300.2834473	0.09
301.2936401	0.10
303.1919556	0.10
309.1979980	0.03
310.2371216	0.07
313.1259766	4.87
314.3819580	0.25
317.5457764	0.21
325.0951538	0.04
326.0655518	0.06
331.1891479	0.13
335.0750122	0.05
337.1640625	1.51
339.4683228	0.06
343.2664185	0.03
344.3242188	0.09
355.1210938	0.11
359.1217651	0.04
367.1845093	3.82
368.2269897	0.16
373.3546143	0.14
377.0271606	0.01
379.1755371	0.75
392.9581909	0.02
395.2072144	0.06
397.1852417	2.00
398.0902710	0.08
399.0933838	0.15
402.5783691	0.33
403.2506104	0.12
413.2742310	0.08
415.1844482	15.48
416.2479858	0.42
417.3755493	0.39
423.2506104	0.03
423.9409180	0.02
427.2521973	0.04
433.1110229	100.00
434.1300659	2.00
440.6123657	0.05
445.0580444	1.25
457.1602173	0.18
461.4330444	0.13
469.3156128	0.05
478.7088623	0.04
480.8939209	0.11
487.0479126	0.05
489.5470581	0.02
499.0227661	0.12
500.2798462	0.05
501.3167114	0.42
503.1668091	0.07
504.4965210	0.06
505.2245483	0.01
510.8655396	0.07
519.2678833	0.52
520.4863892	0.03
521.5617065	0.14
529.0134277	0.84
536.1950073	0.07
546.0006714	0.02
547.1779175	2.21
548.3419800	0.03
555.8449097	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	337.0776
Annotation	L-Ascorbic acid-2-glucoside
Peak:m/z	Relative Intensity
94.9656525	0.02
98.7594299	0.29
100.9771957	0.30
109.3443832	0.02
111.0493469	0.37
112.9482727	0.76
114.9659653	0.83
123.1487045	0.03
124.8978729	0.12
126.0618134	0.03
127.0210876	0.95
128.1970062	0.11
128.9170990	0.81
131.0061035	0.13
133.3302917	0.02
137.0606232	0.04
138.9936829	0.12
140.9500427	0.07
143.1341248	0.03
146.8547974	0.03
151.3312836	0.02
157.0271301	1.58
161.2373199	0.05
162.0120392	0.03
165.2485809	0.06
169.0787354	1.49
173.0604553	0.11
174.0766907	1.07
175.0010986	1.02
176.9949799	0.04
184.8933716	0.02
189.1206512	0.05
205.2490845	0.03
219.1628418	0.17
233.1602783	0.09
237.1811523	0.15
246.0259399	0.03
247.0381165	0.19
253.3011169	0.02
263.1033325	0.04
264.0875854	0.07
277.0653687	100.00
278.2503357	0.34
289.2937012	0.02
305.0830078	0.09
319.0770264	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	745.2662
Annotation	Unknow
Peak:m/z	Relative Intensity
213.1710815	0.11
216.9728241	0.04
221.3034058	0.17
223.1198578	0.27
231.0093994	0.45
239.1912842	0.19
243.1382141	0.20
245.0621338	0.12
251.3360138	0.13
252.7905273	0.42
259.3566284	0.09
260.3997192	0.15
261.2816772	0.05
263.2410889	0.21
269.4907837	0.27
271.0671387	0.22
281.1264648	0.10
283.0816650	0.18
287.2583923	0.21
288.1918640	0.07
289.2942505	0.91
293.5281372	0.02
295.3089600	0.08
299.1624756	0.17
305.2711792	0.09
307.4246826	0.22
313.5184326	0.07
315.3811646	0.07
316.9831848	0.17
318.8580933	0.06
321.2096558	0.34
325.2683716	0.04
327.0718994	0.25
331.0182495	0.09
333.1824341	0.68
337.2823486	0.15
341.2252197	0.11
345.2445374	0.46
347.1362915	0.22
349.3927917	0.49
351.2966919	0.31
353.4579468	0.14
354.2080688	0.27
355.2943115	0.41
357.1785278	0.35
359.2049255	0.37
361.1093750	0.40
363.3298950	0.76
365.1940918	0.10
367.1737671	0.22
371.4985352	0.03
373.2755127	0.91
375.2883911	1.08
377.2418823	0.56
382.5492554	0.38
383.3084106	0.25
385.4113770	0.18
387.1536865	0.47
391.3045654	1.85
393.1813965	1.91
395.4724121	0.25
399.1810913	0.21
401.2250366	0.51
409.0819092	0.41
411.3701782	0.86
413.5190430	0.05
415.9128418	0.24
417.4755249	0.11
419.2370605	2.12
423.4273071	0.23
427.6738281	0.05
429.2610474	0.15
435.2598267	0.90
437.0619507	2.78
439.3281250	0.05
443.3733521	0.32
451.3652344	0.08
455.2105713	3.11
457.3496704	0.24
459.2093506	0.46
461.3980103	0.23
466.3803711	0.08
468.8646240	0.13
471.4233398	0.11
473.3475952	0.33
475.2838135	0.05
477.3161621	0.04
479.2775879	0.10
480.9016724	0.09
483.3328247	0.14
491.4810181	0.07
493.0358887	0.83
496.2014771	0.61
496.9920044	0.22
499.4367065	0.08
501.2301025	0.62
503.0653076	0.23
509.1296997	0.40
513.5302124	0.16
515.3679810	0.03
517.3390503	0.35
519.3590088	0.92
520.1138916	0.05
521.0915527	0.19
527.4250488	0.16
529.2022095	0.05
533.5676270	0.25
537.2288208	0.44
540.2005615	0.06
545.3768921	0.39
553.2056885	0.05
561.4083862	0.23
563.3382568	0.63
566.4631958	0.06
567.2545776	0.34
571.3301392	0.10
576.7758179	0.09
579.0018311	0.39
581.1430054	0.62
587.3156128	0.39
589.4483032	0.06
595.2714233	0.15
599.0061646	0.34
603.3090210	0.60
605.2758179	0.85
610.3804321	0.08
611.6380615	0.29
619.7416382	0.17
621.4168091	1.00
623.2164307	0.87
626.6187134	0.23
631.1278687	0.23
638.8027954	0.17
639.4334106	1.41
641.2659302	2.15
649.1804810	2.36
651.2130127	0.10
657.1978149	1.78
659.1801147	0.46
663.3159790	0.03
667.2891846	3.63
670.5763550	0.32
680.8536987	0.38
681.6466675	0.46
685.1520996	100.00
685.8348999	0.13
691.0979614	0.12
697.3862915	0.41
698.4193726	0.38
699.1986694	1.58
701.0057983	1.23
708.8099976	0.66
709.4307251	0.81
713.1162720	0.05
717.3656616	0.51
726.5740356	0.84
727.2922363	1.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	477.1383
Annotation	6-Hydroxyluteolin 6,3'-dimethyl eter 5-rhamnoside
Peak:m/z	Relative Intensity
259.0862122	0.04
265.7724915	0.04
286.1722412	0.05
287.0249329	0.08
301.2207947	0.02
309.0033264	0.04
310.8536682	0.01
315.1271057	100.00
316.3188477	0.06
347.4745483	0.02
356.0006104	0.04
357.2344971	0.02
373.3219604	0.04
385.5544434	0.12
387.3475952	0.07
399.3524475	0.02
403.4848938	0.02
417.3538513	0.37
423.1004639	0.01
423.7166748	0.04
433.5070496	0.04
441.1952209	0.04
446.2687073	0.02
459.1736450	0.21
466.2473755	0.01
477.5108337	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	727.2449
Annotation	Periclymenoside
Peak:m/z	Relative Intensity
339.0130615	1.66
340.7921753	5.20
341.5107727	0.06
357.1252441	0.24
373.3722534	0.12
377.2272949	0.06
383.3548584	0.29
403.1722412	0.45
421.0921631	0.06
425.4779053	0.37
430.6943359	0.08
439.0399780	0.14
442.8757935	0.19
461.2922974	0.73
463.3528442	0.09
481.0982056	0.08
487.3757935	0.19
491.3661499	0.07
500.9541626	8.47
501.9690552	0.16
507.2496338	0.10
518.7830811	15.72
522.3768921	0.18
537.3501587	0.11
539.5089722	0.10
543.4160156	0.19
547.5014038	0.27
562.1458740	0.13
563.3760986	0.11
565.3424683	3.75
572.9144287	0.39
573.9121094	0.56
582.2155151	0.13
583.1555176	0.63
591.2055054	0.12
603.3085938	0.31
605.6412964	0.39
607.3418579	0.15
621.5908813	0.20
624.7948608	0.04
631.3795776	0.16
633.9836426	0.81
639.3483276	0.20
641.2163086	0.07
649.2507935	0.16
655.2739868	0.37
666.3328857	0.63
673.5925903	0.29
681.0315552	100.00
682.3523560	0.35
683.2028198	1.14
709.3368530	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.2189
Annotation	Cucurbitoside J
Peak:m/z	Relative Intensity
169.0343475	0.02
177.1337891	0.18
185.0128021	0.05
185.9688110	0.04
200.8577576	0.09
209.2246094	0.02
214.2694702	0.06
219.4113312	0.02
227.0877686	0.05
241.0191956	0.02
242.2886200	0.17
244.9977875	1.12
252.9144897	0.02
260.4207153	0.03
269.2213440	0.06
271.1890869	0.20
285.1693115	0.08
287.0976562	0.73
289.0801697	0.04
302.4691467	0.04
304.2587891	0.06
305.5247803	0.18
309.2969360	0.37
311.1438599	0.06
316.2152100	0.06
327.1499023	4.58
328.3539429	0.04
329.2688599	2.56
340.2240601	0.03
345.5133057	0.03
347.1712036	0.41
353.4837646	0.03
355.2475586	0.06
356.2999268	0.30
357.0939331	0.07
358.2393188	0.12
363.2533569	0.26
365.0850220	0.17
371.2156372	3.36
373.0492554	1.05
381.2807007	0.46
382.9317017	0.34
384.0948486	0.39
385.2360840	0.12
389.1749268	31.69
390.0687866	0.02
396.1754150	0.36
407.3137207	0.14
415.1807861	2.67
417.1325684	0.24
425.2684937	0.36
426.7573853	0.04
431.5728760	0.03
433.1730957	100.00
434.0667725	0.11
435.9699097	0.06
437.1587524	0.30
446.9949951	0.09
449.3912354	0.03
453.0343018	0.07
454.3952026	0.15
455.2912598	0.70
456.2647095	0.02
459.1622925	0.17
463.2797241	1.19
465.3936768	0.03
467.2738037	0.05
468.0104370	0.09
471.4106445	0.07
477.1489868	0.09
483.2786255	0.87
499.1554565	0.05
507.2764893	0.92
509.3186646	0.83
511.5487061	0.08
514.1870728	0.03
522.3141479	0.17
523.4579468	0.15
525.2666626	40.34
526.2983398	0.28
533.1349487	0.11
534.2569580	0.14
540.3915405	1.32
541.4385986	0.11
550.4005737	1.37
551.5121460	1.04
561.5425415	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1822
Annotation	Hesperidin
Peak:m/z	Relative Intensity
172.9782562	0.14
174.1404877	0.21
174.9449921	0.14
179.1186218	0.18
180.2221375	0.27
186.0913086	0.12
188.0216675	0.16
189.0800629	0.47
193.0397034	0.07
198.0262451	0.04
199.0414276	1.04
200.2093811	0.63
200.9715118	2.60
201.9685059	1.21
202.7901917	0.20
207.0420074	0.14
215.1311951	1.10
216.1238403	0.75
217.1461182	0.24
224.981842	0.09
226.0593872	0.18
227.0606079	0.75
228.0574646	0.35
229.7229309	0.09
236.1051941	0.25
239.1825104	0.16
240.3248901	0.37
241.26828	0.29
242.1401825	3.11
242.9906311	0.54
245.9936523	0.16
255.013382	0.22
256.1553955	0.05
258.0880127	0.81
259.1833191	0.32
265.2496338	0.12
267.0326538	0.18
268.3208008	0.20
269.1537476	0.12
273.3447876	0.15
283.1882935	0.15
284.1801147	0.96
285.0374451	0.98
286.0316162	2.44
287.038269	2.56
287.6898193	0.14
300.0204468	2.17
301.0828857	69.97
302.1612854	100.00
303.2523193	0.05
304.3690796	0.27
310.2503052	0.19
311.0699768	0.43
323.47229	0.20
325.0670776	0.67
326.3131714	1.19
343.117981	0.38
344.1290894	0.18
345.0327759	0.09
355.1907349	0.17
355.987793	0.18
366.8537598	0.06
368.3684692	0.24
373.0908203	0.06
399.2156982	0.08
400.1487427	0.51
413.3884888	0.13
430.119751	0.38
448.5982056	0.33
464.0957031	0.14
465.4523315	0.62
466.3709106	1.42
484.2949219	0.05
487.6213379	0.27
489.0847778	0.71
490.3258667	2.69
491.2086792	0.23
494.3671875	0.31
508.9174194	0.26
509.6349487	0.11
524.1522827	0.85
544.9856567	0.08
548.5044556	0.38
550.375	0.37
564.1401978	4.39
564.7665405	0.09
566.0316772	0.49
568.000061	0.14
580.8200684	0.07
582.9646606	0.23
592.4839478	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	203.0333
Annotation	6-Hydroxyangelicin
Peak:m/z	Relative Intensity
103.0306702	0.47
118.9380035	0.66
130.9858551	15.05
132.1660004	0.45
132.9120483	0.32
146.9345703	35.24
148.0640106	0.26
157.1587982	0.05
158.9559174	24.23
160.1000671	0.89
160.9878693	0.36
174.9629974	100.00
175.8770752	5.89
184.9869537	5.86
186.0609131	0.05
203.0544739	6.26
204.0688934	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	682.2345
Annotation	Unknow
Peak:m/z	Relative Intensity
205.0756531	0.04
206.1641846	0.04
208.2385712	0.10
216.0650787	0.43
219.0606537	0.51
223.3012695	0.07
226.0603638	0.65
228.1162567	0.17
234.1567841	0.10
236.8386993	1.36
254.0766449	12.25
254.9088135	0.39
265.0026245	0.49
269.2536621	0.11
272.1234741	100.00
273.1741943	0.07
277.0559692	0.10
278.0996704	0.07
289.2308960	0.35
290.1103821	1.19
291.0222473	0.08
297.0777283	0.18
320.6935425	0.04
322.0014038	0.21
323.0269775	0.43
332.2869873	0.29
334.3443604	0.22
335.9893494	0.18
337.1962891	0.29
339.0981445	0.50
340.0433960	0.38
353.8544922	0.05
356.1506348	0.58
356.9816284	0.25
358.5588989	0.24
372.2934570	1.26
373.2055664	1.28
374.1482544	0.85
374.9653931	0.47
376.1484985	0.13
376.8496094	0.08
378.3677368	0.20
379.0595703	0.17
382.0985107	0.06
383.3517456	0.09
384.3631592	0.09
390.0208130	0.05
393.2929077	0.09
395.2040405	0.04
395.9493408	0.09
414.1459351	0.05
418.2200317	0.11
420.1474609	0.21
421.3864136	0.09
422.5532837	0.80
431.0313721	0.54
432.8836670	0.09
434.0523682	0.51
438.1301270	0.09
449.2445068	0.55
450.9640503	0.40
457.4107056	1.15
458.2672119	1.23
462.3312378	0.18
466.2910767	0.34
467.1956177	0.17
472.3750000	0.18
474.1710815	0.09
476.1436157	1.23
478.7639771	0.10
482.3093872	0.23
483.2476807	0.16
483.9935303	0.33
485.9886475	0.24
489.4487305	0.26
490.1969604	0.21
494.5857544	0.11
497.0281982	0.29
499.1530762	0.21
500.1569214	0.46
501.3158569	0.04
502.2272339	0.50
503.1506958	0.30
514.2577515	0.28
518.3356323	0.58
519.1259766	0.08
520.3289795	4.86
524.0125122	0.51
525.2723999	0.20
526.2044067	0.48
532.8966675	0.32
536.3611450	0.06
543.5546265	0.55
544.2587280	1.71
548.4952393	0.04
557.1428833	0.06
559.5654297	0.13
560.1830444	0.64
562.1094971	2.09
567.9782104	0.24
570.4105835	0.14
578.7317505	0.04
583.9973145	0.15
585.2943726	0.11
586.1257324	0.12
592.0899048	0.32
593.4663086	0.30
596.3801880	0.28
598.2434082	1.04
601.4340210	0.54
602.0839233	0.10
610.1605225	0.17
616.1361084	0.46
622.0812988	0.14
628.1903687	1.91
632.3742676	0.36
638.0761108	0.54
646.0798950	5.74
647.1628418	0.55
652.2479248	0.20
664.0178223	16.35
664.9649048	0.25
672.7304077	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	741.2184
Annotation	Rubrofusarin 6-[glucosyl-(1->3)-glucosyl-(1->6)-glucoside]
Peak:m/z	Relative Intensity
271.1246948	2.27
399.5889893	0.09
417.4968262	0.03
433.1194458	9.89
475.3007202	0.09
523.1880493	0.01
543.1812134	0.15
559.2357788	0.01
561.2183838	0.22
577.2976685	0.03
579.1875610	1.26
595.0713501	100.00
595.7839966	0.29
603.3107910	0.04
705.3423462	0.13
723.0734253	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	549.1668
Annotation	Unknow
Peak:m/z	Relative Intensity
176.1546173	0.02
179.2555237	0.04
202.2619476	0.05
207.0063477	0.26
221.1528625	0.02
237.1129150	0.04
238.8061523	0.05
259.3208618	0.05
271.2907715	0.05
297.2111816	0.12
298.9562988	0.03
312.4204102	0.08
317.0321045	0.14
323.0974121	0.96
326.4195557	0.02
338.9282227	0.07
341.3138428	0.08
353.1722412	0.02
355.4796753	0.13
364.2967529	0.04
365.2957153	0.04
368.8325195	0.29
370.3134766	0.03
373.1416626	0.06
379.1036377	0.21
380.7628174	0.05
383.3616333	0.03
385.3076782	0.04
403.1871338	0.11
415.1857300	0.13
416.2313232	0.30
417.1405640	0.17
418.4276733	0.14
429.1194458	0.02
442.4740601	0.19
443.1700439	0.17
451.3723755	0.03
477.2504883	0.08
487.6376343	0.05
503.2699585	100.00
510.2974854	0.10
512.9129028	0.10
519.2598267	0.04
530.8803101	0.15
532.3039551	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	618.2555
Annotation	Unknow
Peak:m/z	Relative Intensity
189.8828278	0.07
211.2384949	0.05
272.9818115	0.07
287.1534729	0.03
290.2429810	0.09
299.4599609	0.03
307.0433350	0.05
309.9717407	0.06
328.1791992	0.02
333.3713379	0.06
353.3798218	0.09
379.1304321	0.03
385.9267578	0.09
395.5150757	0.09
444.1973267	0.17
465.9887085	0.08
471.2280273	0.63
474.2476807	0.04
516.2519531	0.23
522.1210327	0.21
523.3837280	0.07
528.5112915	0.05
537.4772339	0.04
555.6161499	0.16
556.4739990	0.05
558.2880249	100.00
558.9377441	0.48
572.1904907	0.04
574.4035645	0.53
581.9975586	0.12
583.2511597	0.10
589.8245239	0.04
600.7179565	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1817
Annotation	Unknow
Peak:m/z	Relative Intensity
160.9485168	1.06
249.2362366	0.06
272.0978088	0.04
297.0473938	0.02
331.1997681	100.00
331.8467102	0.03
333.1755676	0.10
359.3232727	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	982.6472
Annotation	Unknow
Peak:m/z	Relative Intensity
403.9741516	0.07
677.9591064	0.10
751.6429443	0.30
843.9345703	0.12
899.4315186	0.08
946.6268311	100.00
947.3560791	0.41
964.2232666	0.17
984.2006836	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1609
Annotation	Unknow
Peak:m/z	Relative Intensity
124.9164734	100.00
139.0113678	0.53
142.8230896	23.81
160.9145966	1.19
181.0955963	3.08
229.2492065	1.62
242.0247803	2.38
247.1494141	34.62
269.0879211	0.53
284.5019531	1.40
285.2878113	1.65
289.0023193	77.05
303.2815552	2.33
305.1446533	1.78
321.1163940	1.60
328.4151001	3.06
329.0384521	40.45
331.2070618	11.35
347.0168762	11.37
373.2305603	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	995.3401
Annotation	Cypellocarpin A
Peak:m/z	Relative Intensity
291.2530212	0.29
313.1956177	0.27
338.4625854	0.07
350.8526917	0.14
372.9343262	2.73
374.0039062	2.43
416.8244019	0.20
417.7387390	0.10
577.2008057	62.64
578.2606812	100.00
579.7257080	0.09
620.4829712	1.00
651.1915283	0.30
724.2018433	0.16
762.4059448	0.08
833.4289551	0.31
834.1630859	0.16
851.5354004	0.17
852.4946289	0.32
858.6282959	0.14
936.4019775	0.37
978.1440430	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	265.1134
Annotation	Asparagine
Peak:m/z	Relative Intensity
85.1963806	0.01
86.9538574	0.88
87.8303909	0.01
94.8630829	0.03
97.0964203	0.04
114.8839569	0.07
115.9589386	0.10
121.9643097	0.80
132.9186707	100.00
136.0447235	0.02
138.0092163	0.03
142.0868988	0.02
143.9615784	0.33
147.1815948	0.01
156.2009735	0.01
208.2229156	0.13
209.1807709	0.02
219.0472260	0.63
235.0570679	0.06
236.1976929	0.02
236.9722137	0.05
247.1020966	0.27
256.5742188	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	628.3306
Annotation	Unknow
Peak:m/z	Relative Intensity
195.0940552	0.05
252.3114014	0.03
285.2350464	0.03
315.1200256	0.20
326.2743835	0.07
341.1149292	0.07
345.2385254	0.15
351.1543579	0.03
355.4454346	0.05
483.2951660	0.02
508.5079956	0.09
519.3497925	0.04
535.3493042	6.68
541.1157837	0.04
542.0520630	0.02
543.0762939	0.05
547.2346802	0.19
555.7141724	0.37
562.9930420	0.06
565.4035645	100.00
569.3181152	0.34
576.3230591	0.12
577.8806763	0.09
584.0057983	0.27
585.5072021	0.03
591.0059204	0.15
592.3328857	0.03
596.6984253	0.39
597.6876831	0.08
599.1790161	0.03
603.1821899	0.03
603.7838745	0.02
610.2180786	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.1609
Annotation	Safflomin A
Peak:m/z	Relative Intensity
175.1269836	0.30
176.9277649	0.79
178.9285736	0.18
179.9100952	0.13
181.2774811	0.28
182.4262390	0.07
185.5344086	0.06
191.0474854	0.07
196.8359070	0.05
198.1331482	0.28
199.0350037	1.08
208.9934998	7.38
210.9361725	0.15
213.2159119	0.46
215.1990662	0.28
217.1100922	0.45
218.2932739	0.14
221.1153870	0.42
234.7187653	0.08
239.0323944	5.12
241.1200104	1.75
242.1919250	0.12
243.1024323	0.08
247.3026581	0.13
249.0302734	0.50
251.2112122	0.85
257.0216064	0.05
259.3200378	0.72
263.1670837	0.12
265.1741028	0.05
267.0988464	0.05
269.1708374	3.45
275.1489868	1.19
277.0546265	0.35
281.2449646	0.34
285.1466675	31.43
289.0415649	0.15
293.2683716	0.61
303.0980835	35.21
303.7074585	0.26
306.9688721	0.31
309.1284180	0.07
311.2699585	2.35
322.9365845	0.06
325.2653198	0.24
329.0546875	7.29
337.2272339	0.13
341.1891479	1.72
353.4041138	0.11
359.1875610	2.32
368.9346924	0.44
371.1599731	67.21
379.1644897	0.58
383.1591187	2.04
395.2261963	0.41
397.1845093	0.48
401.1823120	52.65
405.5120850	0.07
413.1455078	1.71
427.2229614	0.09
431.1657715	24.02
443.0834961	1.13
449.2274170	7.75
455.1677856	2.09
459.1627197	0.05
461.1870117	1.16
467.2272949	0.24
469.4190674	0.09
473.1375122	20.10
473.7555542	0.06
485.2440796	1.19
487.1233521	2.72
489.3820190	0.30
491.1663208	100.00
497.1205444	0.12
499.0985718	0.49
503.2378540	12.18
508.1967163	0.05
515.2848511	0.33
517.2086792	0.24
521.2504272	9.46
533.3164062	0.86
551.1820679	0.58
557.2108765	0.46
562.8187256	0.19
567.4128418	1.09
569.0387573	0.08
575.1065063	2.99
583.2392578	3.91
593.1723022	21.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	352.1593
Annotation	(+)-Validoxylamine G
Peak:m/z	Relative Intensity
104.9406509	5.58
108.0580063	0.16
108.8983078	0.03
110.8686981	0.06
123.1234131	0.05
126.8779449	0.87
138.9071655	0.02
140.1299438	0.01
144.9419250	0.56
147.0780640	0.10
153.5019836	0.03
156.3218231	0.04
158.8299866	0.10
169.2574768	0.03
172.2388916	0.02
174.6086731	0.06
176.7542419	0.02
178.1802368	0.08
183.9494324	0.09
184.9539795	0.06
188.8679047	0.05
190.0888062	0.04
194.9351044	0.10
197.1418610	0.04
207.3354187	0.06
210.0988464	0.03
212.9378967	0.24
219.3706970	0.10
226.0042114	0.02
229.1575012	0.04
230.8682556	5.83
231.5035706	0.01
240.0345154	0.08
243.4824219	0.01
245.6847839	0.14
246.7846985	0.24
248.8949890	100.00
249.5050049	0.27
252.3609619	0.02
257.1327515	0.09
260.4539795	0.10
261.4120483	0.03
263.5668335	0.02
264.4549561	0.17
266.1140747	2.48
266.9044800	2.19
271.2596436	0.02
281.6722107	0.10
284.0434570	19.46
287.8809509	0.05
292.7108459	0.03
296.8833008	0.03
298.5878296	0.27
299.1995850	2.05
302.1035156	0.11
306.4583740	0.03
310.9463806	0.41
316.9417114	1.78
324.1971130	0.05
325.2459106	1.11
328.8968201	0.01
334.0722046	0.64
335.0878601	0.13
337.2852783	0.18
338.2578735	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1117
Annotation	D-Fructofuranose 1,2':2,3'-dianhydride
Peak:m/z	Relative Intensity
84.9728470	0.04
95.1206207	0.02
96.9500503	1.59
98.8799744	0.05
108.8469315	0.75
111.0399017	0.10
114.9517670	0.16
126.9879990	7.70
129.2608948	0.03
134.9791260	0.11
138.9699249	0.07
143.6499176	0.13
144.9391327	10.78
147.0643158	0.19
149.1616974	0.02
158.8256989	0.02
160.8116913	0.10
162.9235382	14.16
165.0078430	0.44
173.2221680	0.07
181.1012726	0.49
187.1549072	0.09
189.0602875	0.10
190.8759155	0.13
192.2864990	0.45
193.0043335	1.32
194.8724976	0.03
199.0412598	1.57
201.3870697	0.05
203.9948120	0.02
204.9049377	0.51
207.0265808	0.39
210.9310913	0.91
212.2771606	0.19
216.9119568	2.34
218.9658508	0.30
220.6971436	0.05
222.1824341	0.21
222.9397278	2.71
225.0270996	0.42
229.1550598	1.50
230.8784180	0.09
233.4784546	0.02
234.4188538	0.11
235.1118774	0.30
239.4181213	0.02
240.9826965	1.26
242.5770569	0.18
243.2568665	0.07
247.0192261	3.30
253.0486145	9.72
257.0667725	0.52
258.1950073	2.90
258.9708862	12.41
261.1515503	0.17
261.8646545	0.04
268.1541138	3.51
269.2601013	1.06
271.0563965	25.76
272.0424194	0.06
273.5508423	0.10
275.2262878	0.05
276.7637329	0.03
278.4379883	0.06
279.0852051	0.28
280.1783142	0.04
281.4553528	0.07
283.7338867	0.35
284.7991028	0.14
286.2023926	0.34
288.7936707	100.00
289.5303955	0.35
306.4386597	0.51
307.1251831	6.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.1974
Annotation	Picroroside B
Peak:m/z	Relative Intensity
191.0989990	8.51
192.9682007	0.49
194.0790405	0.53
194.8493042	0.55
206.2446899	0.27
209.0603638	2.96
210.9944763	0.32
214.2525635	0.21
217.1689911	0.31
218.0791168	0.50
234.9987030	8.56
247.2219543	0.46
251.1964569	0.69
277.2850037	0.12
287.5210266	0.19
295.1863098	8.41
299.0490112	0.31
300.9773560	0.37
305.1280518	0.14
323.0159302	0.25
324.7658081	0.22
337.1971436	11.36
340.1325684	0.36
341.3009033	5.42
346.1984863	0.15
346.9082031	0.42
377.1687012	0.54
381.3815308	0.15
383.1332397	5.78
386.7160034	0.13
389.0936890	10.40
412.9019165	0.67
425.4901733	0.17
427.3603516	0.12
429.1831665	0.11
431.0892334	11.81
431.6907959	0.19
440.9468384	0.20
445.0407104	0.34
449.1267700	0.17
451.5562134	0.59
453.3225098	0.39
455.1400146	1.60
457.5472412	0.25
461.2969360	2.89
463.2041016	100.00
473.0265503	0.20
477.1563110	5.94
481.3734741	0.12
483.3947754	0.10
485.1069336	3.57
491.1676025	2.83
497.2523804	1.91
499.2392578	0.12
505.2454224	1.55
515.2418823	9.53
517.1489258	6.87
519.2424316	0.29
533.2233887	25.76
538.3532104	0.61
540.2635498	0.11
557.2965698	0.31
570.7467651	0.17
571.5227051	0.15
573.2035522	0.16
575.4149170	0.56
596.0990601	0.59
597.2721558	0.26
611.0795288	34.87
614.4040527	0.18
615.5640259	0.91
622.7557373	0.57
623.5254517	2.04
625.0967407	0.13
628.3412476	0.35
641.2491455	4.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	639.1561
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
180.7973633	0.68
183.2315063	0.10
184.1266479	0.20
187.2717133	0.08
190.9528809	0.22
193.1300049	0.11
194.9024658	0.11
199.1853027	0.04
201.2857513	0.13
207.9071350	0.07
208.9613342	2.60
212.1014709	0.24
215.2090759	0.29
216.1965790	0.24
217.0572968	0.30
219.2653503	0.17
220.2062988	0.07
221.7384644	0.29
223.2218018	0.08
225.2098389	0.11
226.1909790	0.10
229.1782990	0.13
237.1338196	0.11
239.0805817	0.18
239.9089813	0.11
241.0787659	0.09
241.8828125	0.60
243.1105347	1.16
244.5626831	1.03
251.1981964	0.23
253.1248322	0.05
255.0605469	0.29
259.0737305	0.17
260.0466309	0.07
268.3396912	0.43
269.1845093	1.11
270.1793823	2.50
271.1189270	5.24
271.9248047	0.24
272.8112183	0.15
276.1192322	0.05
282.1589355	0.07
283.1194458	0.42
284.2406921	0.19
285.1937256	0.19
286.0869751	0.31
287.2340698	6.42
288.0649414	0.79
297.2067261	0.37
298.0986328	0.26
299.2017212	0.24
300.0787354	0.03
303.3131104	0.47
310.0492554	0.06
312.3547363	0.51
313.2268677	0.45
315.0405884	26.21
316.0900574	36.21
317.1213379	1.50
322.2467957	0.05
327.1468506	0.18
327.9815674	0.27
329.2330322	2.71
330.0808716	30.72
331.0908813	100.00
332.1296387	4.15
340.3272705	0.15
341.0806274	0.18
342.9074097	0.18
345.2229004	0.36
355.1466064	0.62
358.1354980	0.83
359.1421509	0.31
361.2611694	0.31
367.0971069	0.10
370.1447754	0.21
373.1282959	6.60
374.3478394	0.59
388.0439453	0.11
397.2374878	0.29
403.2499390	1.45
410.9360962	0.06
415.1138306	0.26
427.2388306	0.73
429.5386353	0.25
439.2563477	0.97
457.0731201	0.32
459.2668457	0.12
465.2028198	0.19
466.2620850	0.22
479.0234985	0.31
483.3421631	0.47
491.6035767	0.11
493.3725586	0.32
494.2856445	0.12
495.1959839	0.28
501.3217163	0.04
507.1556396	0.35
533.5786743	0.10
536.4336548	0.17
537.2557983	0.08
563.2600708	0.13
577.4343872	0.19
579.2504272	0.07
580.4783936	0.17
595.2260132	0.61
603.1004028	0.06
608.4684448	0.18
611.3601685	0.56
612.2128906	0.34
619.2376099	1.78
621.1351929	1.12
622.2113647	0.47
624.2230225	18.05
625.2796631	1.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	781.2197
Annotation	Germanaism F
Peak:m/z	Relative Intensity
251.0087585	0.06
263.2438965	0.08
303.4301758	0.17
304.9135742	0.60
305.6021729	0.03
315.2632141	0.10
316.1858521	0.83
317.1560059	0.04
331.1390381	26.81
337.2918701	0.02
339.1224976	0.22
347.2679443	0.02
354.9329834	0.13
373.1223755	0.32
386.3919067	0.03
387.2176514	0.06
402.9443970	0.12
406.5550537	0.03
449.2512207	0.39
473.3922729	0.05
474.3686523	0.12
475.4284668	0.54
477.2316284	0.20
478.3036499	0.17
479.3399658	0.19
493.1958008	16.07
507.1201782	0.07
508.6132202	0.05
509.6600952	0.09
513.1049194	0.17
517.2924194	0.34
519.6741943	0.02
521.3930054	0.16
533.2520752	0.19
535.2448730	5.75
537.2503662	0.12
540.4515991	0.05
550.4465942	0.05
552.9588623	0.06
555.3467407	0.07
557.0880127	0.04
563.3969727	0.04
566.2998047	0.05
567.0910645	0.12
575.1806030	2.03
577.2137451	0.39
582.5767212	0.03
583.3325806	0.15
585.1539917	0.13
587.2135010	0.04
589.4492798	0.04
591.3120117	0.02
599.4517822	0.06
605.1206665	0.02
607.0336304	0.04
615.3627319	0.02
617.1791992	0.76
618.3975830	0.30
619.2199097	0.11
621.1968384	0.32
622.4353638	0.22
623.3179932	0.65
634.4209595	0.01
637.1222534	100.00
637.7844238	0.41
639.3421021	0.07
648.3725586	0.07
651.2174072	0.22
652.3165894	0.09
653.4240112	0.04
658.3713989	0.14
659.4811401	0.08
677.1128540	0.16
679.1112671	10.25
679.8438721	0.04
689.2249146	0.06
693.3438110	0.06
694.2802124	0.03
694.9345093	0.11
697.0181274	0.02
701.2116089	0.04
708.3576050	0.04
715.3138428	0.19
719.0198364	1.17
719.7006226	0.09
721.1526489	0.02
729.5368042	0.06
730.3029175	0.19
732.9459839	0.22
735.0383911	0.15
735.9066772	0.07
737.3162842	0.38
745.2963257	0.28
749.1239014	0.20
750.4011841	0.02
751.3186646	0.22
758.6937256	0.13
761.5947876	0.09
763.3092651	1.02
765.1858521	0.42
781.0491333	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.1881
Annotation	Unknow
Peak:m/z	Relative Intensity
271.1419983	0.08
272.2264404	0.03
287.1838989	0.08
300.1664124	0.41
305.1005859	0.28
315.1768799	7.25
325.1508789	0.02
347.0941162	0.03
367.3135376	0.06
380.2738647	0.02
443.1575928	0.02
449.4916382	0.16
451.4231567	0.01
459.4463501	0.10
477.2117920	23.74
487.3804321	0.02
505.2402954	0.11
514.3363037	0.03
519.2105713	12.58
559.2910767	7.30
561.0845947	1.66
561.7752686	0.05
600.2090454	0.02
601.3082886	1.30
603.0234985	0.25
619.5518188	0.04
621.1176758	100.00
621.7610474	0.30
641.0546265	0.06
649.4970093	0.05
663.1881714	9.40
685.2551270	0.03
703.1364136	1.83
717.3848267	0.03
720.4677124	0.09
721.3141479	0.02
734.4114990	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	599.2476
Annotation	Briaranolide B
Peak:m/z	Relative Intensity
167.8266144	0.07
169.0353546	0.64
171.1108093	0.42
172.9379120	0.28
174.8755493	2.28
177.0648651	1.85
178.1674500	0.12
179.0567017	0.89
181.1229095	0.51
182.9885864	0.55
185.1892853	2.08
187.1697693	1.67
189.2414703	3.67
191.3071289	0.38
193.1636658	0.58
195.1967010	1.08
195.9910431	0.45
197.0158539	1.25
198.0419617	0.22
199.0498810	1.93
200.5159607	0.61
201.1549072	1.88
202.0670929	0.17
203.1705170	1.26
204.9097137	1.56
206.9916992	2.19
208.3837585	0.15
209.1692505	1.39
209.9938507	0.23
211.2947845	1.43
212.0930786	0.62
213.0541382	2.41
214.0723267	0.36
215.1446991	6.92
216.2207031	0.35
217.1946106	2.16
219.1486969	0.66
221.1697083	1.38
223.2041168	0.93
224.5539551	0.87
225.2158508	2.21
225.9914551	0.11
227.1961060	2.47
229.1237946	8.35
231.2787476	0.51
233.1577606	0.66
235.2919769	2.00
237.3128052	1.17
239.1995239	2.19
240.3445129	1.06
241.1835022	4.49
243.2156982	1.10
245.1446075	1.42
247.0683289	1.69
249.1679840	2.68
251.1851654	3.72
253.2891541	5.25
255.2881470	6.67
257.0663452	4.21
259.2991333	0.63
260.8560791	1.49
261.4651794	0.73
262.7319946	0.95
264.1814575	0.45
265.1495667	0.64
267.0629272	3.16
269.1717834	4.19
271.2511597	3.28
273.1885376	2.00
275.0627747	12.37
275.9228516	0.33
277.1890259	3.23
279.2327881	4.44
280.7261047	0.70
281.3676147	0.31
283.2628174	3.00
284.6491699	0.96
285.3424377	0.58
287.1703491	3.43
289.2124939	0.93
290.2161865	0.07
291.2308960	3.02
293.2539368	2.87
294.1547241	0.40
295.1847534	3.41
297.2159424	3.48
298.9929504	1.58
301.2171631	1.80
302.1591187	0.42
303.2940063	3.91
305.0563354	5.77
307.2218018	2.56
309.1818848	1.95
311.2977295	0.81
312.9141235	3.41
313.5340576	0.19
315.2321777	11.57
316.2540283	0.08
317.1086426	3.20
317.7199707	0.34
319.1838379	1.98
321.1859131	2.90
323.2066650	4.14
324.4079590	0.51
325.1844482	2.38
327.3176270	2.50
329.1353149	4.84
330.6012573	0.67
331.3539429	3.81
333.2404785	12.05
334.2700195	1.16
335.2462158	6.21
335.8566284	0.10
337.2701416	2.37
339.1796265	4.67
341.1458740	2.55
343.1266479	2.45
345.2409058	5.95
347.2989502	7.11
349.1455078	6.02
349.9097290	0.24
351.2801514	6.51
353.2014160	2.65
355.3606567	3.06
356.2558594	0.24
357.2497559	3.08
359.2437744	4.10
361.0275879	2.96
361.9113770	1.07
363.1675415	7.46
365.3606567	6.98
367.2368164	8.51
368.4765015	0.68
369.2161255	1.61
371.3273926	0.97
373.2294922	11.64
375.2961426	14.71
376.1333008	0.22
377.3191528	7.61
379.2857666	3.09
381.3325195	2.85
383.2467041	2.33
384.5993042	0.43
385.3045654	0.38
387.2015381	2.46
389.2808838	2.17
391.2627563	20.77
393.3699951	40.29
395.2065430	17.81
397.2870483	0.47
399.1154785	0.37
401.2719116	9.94
403.2351074	1.53
405.2380371	2.66
407.5780029	1.41
409.2345581	64.05
410.0096436	0.08
411.1791992	8.31
413.1705322	5.41
415.3221436	2.11
417.3054199	1.03
419.2648315	25.84
421.2080688	0.30
423.2342529	1.03
425.2710571	0.50
427.4216919	1.18
429.4850464	1.68
431.3711548	3.04
433.3029175	0.71
435.1932983	1.43
437.2436523	35.95
439.2639160	3.59
441.3602295	3.97
442.3888550	0.27
443.3887939	1.06
447.0986328	0.56
447.7960205	0.23
449.1904907	1.46
451.1560059	0.86
453.2789307	2.09
455.2582397	21.96
457.4138794	2.00
459.0007324	0.61
461.1577759	2.55
463.1802368	0.60
465.1686401	1.84
467.3717041	2.82
468.2624512	0.67
469.3494263	1.35
471.2257080	0.92
473.2847900	0.97
474.0682373	0.33
475.2231445	2.23
476.5310669	0.64
477.2733154	2.17
479.2102661	3.72
481.3248291	1.85
482.6314087	0.28
483.3378906	3.32
485.2296753	1.51
486.4655762	0.24
487.3457031	0.84
490.3074951	0.17
491.5292358	0.42
493.3220825	1.64
495.3362427	4.38
497.2954102	7.37
498.2671509	0.24
499.2451782	1.22
500.3789673	0.07
501.2433472	3.98
503.2540894	1.68
505.2514038	0.64
506.5265503	1.17
507.3890991	3.07
508.3521118	0.93
509.3458862	3.72
511.0881348	1.58
511.7182007	0.25
513.3082886	1.05
515.4716187	1.74
517.3839722	1.83
519.3755493	4.79
520.0720825	0.07
521.4019165	2.19
523.3230591	1.23
524.4182129	0.55
525.3390503	2.20
527.2228394	7.83
530.3063354	0.09
531.2023315	0.74
533.5819702	0.14
534.8255615	0.83
535.4278564	12.04
537.3611450	36.10
539.2246094	4.69
541.1354370	0.65
543.3899536	0.37
545.3297729	8.55
549.4366455	0.33
551.0739136	0.12
553.3063965	44.97
554.1101685	0.16
555.3419800	59.23
557.1985474	3.23
563.3118286	31.10
566.5148315	0.27
569.1101685	0.34
571.3558350	10.59
581.1908569	100.00
581.8632202	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	518.322
Annotation	PC(18:3(6Z,9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
166.1439819	0.18
176.1377258	0.05
183.9720917	100.00
184.7613678	0.02
205.1308594	0.16
218.9574585	0.03
255.2870483	0.10
258.2518311	0.25
271.0023193	0.26
280.2874756	0.17
281.9855957	0.13
285.8795166	0.09
286.9431152	0.14
290.2320557	0.07
299.3844604	0.02
319.2954102	0.06
324.3292847	0.10
325.1586914	0.06
367.0745850	0.03
395.9331665	0.09
398.1358032	0.03
402.4797363	0.09
406.8870239	0.04
409.1971436	0.07
431.1990967	0.30
444.4052734	0.07
446.2743530	0.09
451.3305054	0.06
455.2290649	0.07
459.4418335	0.19
464.4646606	0.05
468.7967529	0.02
472.2847900	0.30
475.5269165	0.05
483.2967529	0.06
491.3449097	0.07
500.3198853	53.48
500.9309692	0.41
501.6823120	0.08
508.7415161	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Taxifolin 3-galactosyl-(1->6)-glucoside
Peak:m/z	Relative Intensity
226.9031372	0.09
271.5808105	0.05
287.9489136	0.06
302.8074341	0.20
307.3364868	0.04
321.3345337	0.05
329.2637939	0.13
353.2633667	0.36
355.1244507	0.03
365.2195435	0.08
369.5524902	0.25
371.1817627	1.31
383.0683594	0.05
394.0149536	0.07
394.9685669	1.08
406.9221191	0.05
413.1594238	0.09
419.1310425	0.18
425.1793213	1.85
431.3768921	0.83
436.9676514	0.60
442.5814209	0.10
443.1951294	0.69
444.1207886	0.06
448.9891357	0.68
455.0903931	1.39
457.3303833	0.09
461.1452026	0.22
471.5310669	0.12
473.0635376	38.82
473.6916504	0.29
475.4172974	0.11
479.0729980	0.05
491.1614380	13.70
491.9283447	0.07
497.2196655	3.68
508.0280151	0.04
509.2549438	0.72
515.2589111	6.19
518.7792358	0.13
521.3999634	0.32
527.2204590	12.84
535.2217407	0.06
539.2711792	7.75
545.0780640	15.81
549.4963989	0.07
550.6394653	0.07
557.2109375	9.30
564.6757202	0.05
575.1984253	25.53
578.2102661	0.12
585.0560913	0.55
593.1053467	100.00
593.7825928	0.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	321.08
Annotation	Unknow
Peak:m/z	Relative Intensity
95.0441284	0.29
104.8279495	0.14
115.0910721	1.05
116.0309143	0.28
117.0250244	0.20
130.9283447	0.21
137.3544464	0.09
149.0127563	1.68
152.9300232	0.37
154.1096802	0.07
154.9098511	0.29
159.2828979	0.29
160.1033020	0.10
176.9267273	3.97
178.1263275	0.99
189.3589478	0.12
190.7981110	0.10
195.1910706	0.28
195.9107971	0.14
197.2420044	0.14
198.9873810	0.11
200.4714508	0.36
201.1101074	2.19
203.6694031	0.24
204.8002014	0.09
205.9797058	0.05
208.7874146	0.05
211.1448669	0.11
215.2560730	0.13
216.2467957	0.23
217.0153198	0.68
219.0932617	0.12
222.1875610	0.12
230.9385681	0.36
233.0406494	0.05
234.2574463	0.07
235.1474304	0.22
250.1962891	0.73
251.2364807	0.34
257.0911560	0.27
258.1377563	0.09
259.1503296	1.25
260.9556885	0.47
262.2319336	0.10
263.0188293	0.41
264.4903564	1.25
268.1083374	0.18
271.6023865	0.46
275.1147461	1.89
276.3965454	0.26
277.2268066	0.10
278.3752747	0.42
279.9401855	1.28
283.2658691	0.05
285.0835876	8.36
285.7680054	0.10
289.1029663	0.40
291.5476074	0.54
292.5478516	0.77
293.2435303	0.42
294.7182617	0.05
296.8870850	0.17
302.9156189	100.00
303.5173340	0.47
308.1020203	0.06
311.6719971	0.16
334.9483337	0.28
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1149.3301
Annotation	Watterose F
Peak:m/z	Relative Intensity
328.9522705	1.13
330.1600037	5.33
331.1811218	0.57
339.8640747	0.42
341.3280640	0.32
343.0209961	0.95
345.0495605	26.90
345.6716919	0.05
357.2679138	0.58
360.1783447	0.24
365.4987793	0.07
367.0755310	0.08
375.2356567	1.54
383.2598877	0.11
413.2325134	0.09
454.9762573	0.13
471.2951355	0.06
474.2948303	0.10
485.3280640	0.20
489.2501831	3.56
492.0377197	0.43
493.1086121	0.17
500.8709717	0.04
507.1485596	14.23
515.2095947	0.84
516.2589111	0.08
517.1329346	0.85
519.0640869	0.28
531.1998291	1.19
535.1362305	3.12
537.0637207	0.11
541.0649414	0.10
549.2557373	40.35
550.1031494	0.05
556.0160522	0.16
562.8790283	0.19
563.5301514	0.15
567.3236084	0.12
571.3250732	1.59
575.2813721	0.20
577.3806152	0.91
579.1755371	3.59
589.2534180	5.12
591.2227783	31.63
599.2949829	0.57
603.4325562	0.07
614.8830566	0.06
616.2829590	0.08
617.2794189	0.58
619.2649536	0.98
621.1627197	1.85
631.2185669	10.65
632.7291260	0.60
633.3376465	3.80
637.1219482	0.24
643.1984863	0.25
649.2290039	0.10
651.1779785	7.20
657.4074707	0.08
659.4819336	0.32
661.2569580	0.53
662.8867798	0.47
671.3067627	1.03
672.9316406	1.83
675.2680054	0.40
679.3591309	0.21
680.2752686	0.13
681.1371460	0.15
693.2069702	15.31
697.4604492	0.27
698.4470215	0.07
699.4360352	0.41
705.3648682	0.35
707.1988525	0.38
723.0178833	1.11
729.4907227	0.10
733.3645630	0.37
735.0369873	1.66
740.1630859	0.35
745.2462158	0.14
753.4274292	0.55
758.8731689	0.70
765.1945190	0.07
775.1123047	0.15
777.1378174	0.30
780.4410400	0.28
781.3721313	0.23
795.1610718	12.17
795.8591309	0.11
803.3558350	2.91
805.7015991	0.19
811.3112793	0.21
819.3227539	0.21
823.1519775	0.25
837.2001953	7.67
848.8006592	0.06
855.1071777	0.11
860.3479004	0.07
867.3762207	0.15
877.0992432	3.09
879.1215820	0.99
885.4444580	0.23
902.5104980	0.10
921.3070068	0.24
922.1866455	0.25
939.2382812	6.02
942.2094727	0.11
943.4943848	0.31
945.0791016	0.16
969.4919434	0.28
987.2761230	1.94
990.7200928	0.86
991.3969727	0.32
1005.1508790	100.00
1005.9248050	0.09
1029.1431880	1.19
1033.2055660	1.22
1047.2600100	41.88
1069.1461180	0.17
1071.1256100	0.31
1075.0290530	0.41
1077.3039550	0.08
1081.1528320	0.09
1087.1824950	26.82
1089.1180420	1.52
1099.1652830	0.06
1102.6247560	0.20
1105.3229980	0.71
1113.4958500	0.49
1131.0964360	2.38
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	317.1009
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
184.8961487	0.02
203.0484467	0.01
229.0256348	0.04
231.0110168	8.64
231.7405701	0.04
233.0077209	100.00
233.8606262	0.01
242.0945740	0.02
244.8311768	0.11
247.0895691	0.09
248.9651794	0.15
257.0638428	0.07
259.2166138	0.04
267.9776306	0.02
271.3116760	0.05
273.1320801	0.90
274.4582214	0.01
284.8539124	0.02
287.1956787	0.09
299.0903931	5.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.1664
Annotation	Butrin
Peak:m/z	Relative Intensity
174.0774536	0.18
176.9743958	0.05
195.9421997	0.06
199.1542358	0.08
199.9694214	0.49
201.0659485	0.15
212.1767120	0.11
215.1984863	0.06
216.2605896	0.08
217.0908356	0.07
225.0931396	0.25
227.2538300	0.74
240.0257111	0.10
241.0479889	0.35
242.2060852	0.63
243.2474365	0.06
258.1707153	0.09
267.1716614	0.10
267.9439697	0.33
269.0108032	1.29
283.1124268	0.35
285.0786438	1.83
287.0317383	100.00
287.9260864	0.05
298.9741211	0.11
301.1651611	50.62
302.3293457	0.13
306.8674316	0.17
311.1196289	0.07
329.3240967	0.12
343.0442505	0.34
352.9783936	0.17
367.2522583	0.44
385.4638062	0.26
389.3825684	0.04
409.0680542	0.40
415.0599365	0.10
433.1934814	0.07
443.1475830	1.89
445.1210938	0.12
449.2201538	0.30
451.2515869	0.27
459.2705078	0.31
463.1889648	0.32
469.2772217	1.86
474.2142944	0.15
475.5724487	0.24
493.2491455	0.21
505.3264160	0.06
546.2926636	0.22
547.3871460	0.19
551.2173462	0.60
558.9345093	0.08
563.2830200	0.06
565.1472778	0.08
572.2033691	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	795.308
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
229.4453583	0.03
237.2069397	0.06
239.2143250	0.03
245.2932587	0.20
247.0689697	0.01
249.0453186	0.06
251.2250366	0.05
253.3407898	0.01
255.2157898	0.08
258.9705811	0.05
261.1697388	0.05
263.2753906	0.08
266.6442871	0.05
267.3816528	0.05
269.2084961	0.09
271.1450500	0.05
273.1951294	0.13
275.3326111	0.06
277.2160645	0.10
279.1902466	0.11
281.2104492	0.04
283.1635132	0.11
287.2763672	0.08
289.2307739	0.11
291.1898804	0.28
292.4778137	0.15
295.3049316	0.03
297.0314026	0.05
299.3832703	0.01
305.1571350	0.11
307.2172852	1.42
309.1398010	0.01
313.2387695	0.03
321.3243408	0.03
323.0970459	0.06
325.2452393	4.78
325.9304199	0.01
330.0833435	0.03
331.7593079	0.04
341.1395874	9.18
345.0211182	0.04
349.2875977	0.04
351.1219482	0.51
365.2627563	0.18
369.1691284	0.27
383.3830566	0.36
409.2454224	0.04
425.2347412	0.02
427.2758179	0.33
453.1901855	0.05
467.4854126	0.03
471.2380981	100.00
471.8410645	0.22
480.4545898	0.08
485.2844849	0.08
495.3033447	0.03
507.6091919	0.02
513.2848511	0.16
525.2398682	0.23
530.9837646	0.04
536.9197998	0.05
548.8693237	0.01
549.5328369	0.02
562.8905029	0.07
573.2853394	0.10
585.2301025	0.07
589.1976318	0.11
590.8257446	0.02
615.4310303	0.07
619.4072266	0.04
632.5223389	0.12
651.1447754	0.87
673.3020630	0.07
733.2621460	0.02
751.1255493	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.3044
Annotation	Sphinganine
Peak:m/z	Relative Intensity
94.97008514	0.49
97.06609344	0.51
109.1418915	0.38
110.9750519	0.31
116.7276306	0.08
123.0130997	0.50
124.9939728	0.14
137.1408386	0.34
139.0429077	0.03
144.9921265	0.56
151.0603638	0.43
153.0494232	1.99
154.2564087	0.02
163.1422119	0.05
165.150528	0.04
167.0671692	0.08
175.1061096	0.13
177.0742188	8.76
179.0540924	2.99
187.161026	0.04
193.0376587	0.06
196.2432709	0.06
203.0420837	0.02
217.0860901	0.03
218.8883362	0.10
225.0567322	0.06
235.0269775	0.08
239.1043091	0.08
240.3023376	0.53
245.2817383	0.06
247.3073425	0.03
249.2428589	0.24
252.7160034	0.03
254.4836426	0.51
255.8171082	0.21
257.2085571	0.18
258.1698608	0.05
259.8925781	0.03
261.265564	0.05
266.2874146	3.86
267.3041687	0.56
270.9604187	0.10
273.4279175	0.11
275.1689453	0.24
284.2880249	100.00
285.1356506	1.82
287.1577148	0.67
288.1987305	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.2007
Annotation	Unknow
Peak:m/z	Relative Intensity
126.9818573	2.49
141.2034760	0.39
144.9040680	1.80
159.0551300	2.12
162.8969116	9.48
177.1433563	3.97
187.1304626	0.45
209.2477417	0.58
252.9587402	1.22
263.2243652	0.51
269.0005188	1.12
270.9658508	4.03
287.5501709	1.05
288.9046631	18.39
299.2921448	0.58
304.9506836	2.40
307.0278015	38.59
318.8160400	1.66
333.0905151	1.87
344.5534973	1.15
349.0034790	0.52
381.1220093	2.76
389.2178040	18.83
401.6258240	1.64
407.1189270	100.00
417.1242065	1.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	644.1637
Annotation	Delphinidin 3-(6-malonylglucoside)-7,3'-di-(6-sinapoylglucoside)
Peak:m/z	Relative Intensity
184.7777557	0.03
193.2010651	0.11
205.0351868	0.03
212.2497864	0.03
216.9707947	0.04
217.8385162	0.04
223.1958008	0.04
226.8955536	0.03
230.0433655	0.02
234.9712830	0.02
246.0445557	0.01
252.7857056	0.01
257.2487488	0.01
269.1287842	0.04
271.1273193	0.09
275.1497192	0.06
276.2537537	0.03
283.3627930	0.03
288.9942627	0.28
290.4105835	0.04
300.0023804	0.08
302.3469849	0.07
304.1982117	0.05
307.1197510	0.17
308.9300537	0.04
313.3822632	0.10
315.2557373	0.01
317.0828247	0.20
323.4621582	0.01
331.1088257	0.01
332.1805420	2.65
333.1234741	0.18
336.0074463	0.06
344.9900513	0.05
347.1245117	100.00
348.1297607	5.48
349.1005249	0.21
350.2001953	0.07
361.1711426	0.04
363.3319092	0.02
367.2249146	0.02
371.2534790	0.09
372.4870605	0.01
375.1766357	0.04
377.3098755	0.16
383.4126587	0.01
389.0523071	1.17
390.0635376	0.06
392.4608154	0.09
393.8536377	0.02
396.0088501	0.05
396.9278564	0.14
402.0935669	0.05
410.9376831	0.08
413.4018555	0.03
414.1109009	0.03
415.2837524	0.24
417.4771118	0.07
418.4114990	0.01
422.2374878	0.05
432.7657471	0.16
433.3792725	0.23
437.0585327	0.06
442.1119385	0.04
455.2636108	0.28
456.3858643	0.08
461.2414551	0.03
464.3165894	0.02
472.3450317	0.09
473.2349243	0.06
475.2346802	0.06
480.3453369	0.03
481.3231201	0.11
482.3468628	0.60
483.1701050	0.12
489.4110718	0.02
490.1412964	0.06
491.2427368	0.12
492.9875488	0.11
498.0393677	0.25
502.2750854	0.01
504.1979980	0.09
509.5192261	0.07
511.2537231	0.05
517.1349487	0.09
523.3482056	0.02
540.4108276	0.23
541.2973022	0.01
542.5541382	0.06
559.1842651	0.55
560.0837402	0.04
566.4691162	0.02
573.7457275	0.04
577.1004028	0.58
578.1101074	0.10
580.3096924	0.04
592.8140259	0.05
594.9521484	0.52
595.9860229	0.10
598.3362427	0.05
599.5521240	0.06
600.3633423	0.23
601.2793579	0.13
608.6893311	0.19
612.4229126	0.02
617.2866821	0.09
625.9017944	0.16
626.5299072	0.43
627.1614380	0.12
630.5460205	0.15
653.2354736	0.09
654.1773682	0.03
736.6312256	0.02
738.4589233	0.09
740.9343872	0.03
761.2276001	0.15
796.6931763	0.06
797.8048706	0.09
803.2570190	0.01
851.1607056	0.09
880.8484497	0.05
904.9896851	0.30
923.1338501	0.85
924.1177368	0.23
940.2963867	0.28
940.9622192	5.82
941.9645996	1.61
953.1109009	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	457.1193
Annotation	Raltitrexed
Peak:m/z	Relative Intensity
130.9928131	0.04
133.2328491	0.06
143.1025238	0.06
156.7770996	0.02
161.0152435	0.09
179.0709229	1.58
200.0694580	0.03
209.0802460	0.37
221.0313721	0.02
223.1522369	0.04
233.3277893	0.05
263.9115601	0.09
265.9519958	0.02
277.1065063	1.34
293.9743042	0.03
295.2272949	0.43
296.1960754	0.03
304.0993042	0.03
318.2703857	0.02
319.0125122	0.19
341.1565552	100.00
351.1141357	0.46
369.5258484	0.04
383.3392639	0.03
395.1178894	0.05
397.1813660	0.06
410.9693604	0.09
412.8092957	0.05
414.2398987	0.02
421.2088318	0.34
422.5291443	0.06
439.1415710	12.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	471.2027
Annotation	Terretonin A
Peak:m/z	Relative Intensity
132.8685303	0.24
145.0800934	0.25
145.8903503	0.06
147.0448608	0.07
151.1466827	0.23
151.8736572	0.08
159.2085571	0.21
163.1702576	0.09
171.0733643	0.33
173.0379944	0.65
175.0409241	0.91
177.2394104	0.05
180.9395599	0.27
185.1860046	0.57
187.1901703	0.30
189.2072906	0.16
191.0113525	0.69
195.0773926	0.13
197.1998901	0.82
198.1433868	0.34
199.0738525	0.40
200.2753906	0.24
201.2320251	0.27
203.1851196	1.45
207.2134552	0.13
210.1489258	0.07
211.2425537	0.43
212.1087952	0.28
213.1110229	0.25
215.3083801	0.05
217.3030548	0.25
219.2460632	1.16
221.0234375	0.09
223.1443481	0.16
226.1081696	0.30
227.2316284	0.22
227.9843903	0.10
229.3522034	0.94
231.2017212	0.75
234.9973297	0.14
237.3022614	0.91
239.1318054	0.13
241.0769043	0.09
243.0986938	0.27
245.1987305	3.88
247.2391052	0.16
248.0520630	0.04
249.1604919	0.15
251.2579346	0.61
252.1313477	0.07
253.2245178	0.64
255.1631165	0.77
257.0615234	0.15
259.1633606	1.52
261.4004211	0.59
263.2605896	1.66
264.3388062	0.04
265.1969604	0.98
267.3007202	0.29
269.3865662	0.44
270.4254150	0.25
271.1942139	0.40
273.1741028	1.15
274.2221680	0.09
275.1569824	0.14
277.1943359	0.24
278.1475220	0.13
279.2199402	1.57
281.2901001	0.08
281.9552917	0.18
283.3511353	0.05
285.3684692	0.08
287.2681274	2.40
289.1701050	1.96
290.1661682	0.14
291.2937927	5.05
292.2169800	1.84
293.4172668	0.36
295.1726990	0.31
296.0810547	0.12
297.2588501	3.08
299.3061523	0.41
303.4671631	0.04
305.3218994	0.28
307.2070312	31.04
308.2307739	0.40
309.3128052	0.62
313.2724609	1.03
315.2931824	1.02
317.4343872	0.20
321.2222900	0.21
323.2393799	1.98
325.2106934	100.00
326.3832092	0.06
329.1555481	0.09
330.0317993	0.11
331.2632141	6.91
333.0936890	0.14
335.2381592	0.38
336.3167419	0.88
339.4746704	0.12
341.2649536	0.45
343.2298889	0.04
347.3186951	0.37
351.2145386	15.22
355.1260986	0.29
359.4453125	0.04
363.4257812	0.08
365.3266602	3.12
366.4326172	0.16
369.1507874	9.07
375.2300110	0.09
381.1833801	0.28
383.3215027	5.76
385.5318298	0.29
391.5701599	0.51
394.2413025	0.22
396.4396057	0.09
399.1803284	0.24
409.2044373	1.81
425.4066467	0.04
427.1954651	7.74
427.9253235	0.02
435.2321777	0.04
453.4956970	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	303.09
Annotation	Alnustinol
Peak:m/z	Relative Intensity
89.0301361	0.12
90.8911743	0.06
95.0448151	0.02
110.9787598	0.15
116.9260864	0.44
119.1421967	0.06
121.1680298	0.09
122.0541458	0.05
122.9192886	0.23
124.8306656	0.28
126.9589539	0.03
135.1606140	0.04
137.1076355	1.31
144.8969421	2.07
146.9414062	0.03
149.0424805	0.44
151.0026703	4.98
152.9195557	24.54
161.8123779	0.02
171.1471100	0.01
175.0530396	0.97
177.0338135	100.00
179.0301819	51.58
179.8263855	0.15
186.1428833	0.05
187.1927948	0.06
193.1093292	0.03
201.0633240	0.64
202.9424438	0.02
215.2907104	0.06
217.1054993	0.11
219.0773315	2.30
220.0775757	0.05
222.9464722	0.02
225.1007385	0.02
234.7009583	0.02
243.0502930	0.63
245.0026245	0.11
253.0946655	0.03
255.3098755	0.11
256.9912415	0.08
259.1982422	0.11
261.0979614	1.81
267.1332092	0.84
271.1125183	0.14
275.0033875	0.21
285.0966187	12.25
288.1196289	0.32
289.1857910	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	569.2188
Annotation	Cucurbitoside J
Peak:m/z	Relative Intensity
167.2402191	0.03
171.0564117	0.03
176.9604950	0.02
185.0692139	0.07
192.0086212	0.03
214.2510986	0.05
220.9742432	0.08
223.9993134	0.03
229.3698730	0.13
247.1892242	0.07
251.1220551	0.06
253.2615051	0.07
256.2164001	0.18
259.1862183	0.03
260.9337158	0.06
263.0550537	0.02
266.9692078	0.14
285.3484497	0.03
287.1365967	0.50
299.5508423	0.06
303.2468262	0.02
314.1632080	0.04
317.0390625	0.08
319.3895874	0.09
321.1034546	0.02
327.1173096	0.17
329.1481934	0.42
339.2789307	0.13
342.3810425	0.03
349.4176025	0.07
350.9351196	0.02
353.0684204	0.10
355.2858887	0.07
356.1602173	0.23
357.2777710	0.07
363.2777710	0.98
371.2493286	0.58
373.1108398	0.13
379.2922363	0.03
381.2712402	3.09
382.5053101	0.04
389.2515259	0.38
401.4877930	0.15
403.3637085	0.15
405.1432495	0.09
407.2890015	0.76
411.0018311	0.04
412.3568726	0.03
415.0057983	0.11
421.3053589	0.03
425.2010498	0.64
428.7536621	0.11
431.1542969	0.12
432.9114380	0.45
433.5706787	0.10
436.7352905	0.55
437.5399170	0.12
441.0279541	0.03
442.9473877	0.04
447.2650146	0.12
451.7313843	0.02
452.8946533	0.03
454.1835938	0.14
455.4513550	0.26
456.0539551	0.04
461.5172119	0.02
463.3580322	8.44
465.2516479	1.93
466.3119507	0.03
467.3073730	0.18
469.5142822	0.03
470.2730103	0.14
483.2963257	4.04
484.0860596	0.22
491.0471802	0.12
491.8220825	0.15
492.8500366	0.04
507.3559570	3.33
508.3721313	0.33
509.3408813	0.57
515.3538208	0.21
516.1687622	0.07
521.3361206	0.06
522.4607544	0.07
523.5174561	0.03
525.2877808	100.00
526.3539429	1.75
532.2116089	0.15
540.4912720	0.80
541.5529175	0.24
550.4777222	1.35
551.3425293	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1089
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
134.9792175	0.07
146.2129974	0.03
150.9439850	4.75
160.9902954	0.04
227.1717224	0.02
269.0669861	0.16
287.0444946	100.00
287.6934814	0.27
305.0348816	0.07
311.2460327	0.20
326.7866516	0.12
329.3203125	0.17
333.1999817	0.02
405.4226074	0.04
431.1853333	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	435.1662
Annotation	Melcanthin E
Peak:m/z	Relative Intensity
128.9799042	0.37
140.7998657	0.07
142.9870453	37.51
145.0273438	29.59
157.0735168	0.16
159.2019653	0.13
161.0602722	1.95
163.0480804	18.98
177.0560608	0.16
181.2358398	0.46
184.9510803	0.09
186.9780273	100.00
199.2730560	0.36
201.0660095	0.36
203.0365448	1.54
205.0694885	0.60
215.4700012	0.44
216.9324646	0.64
219.0184631	0.47
229.1603088	0.15
231.1516724	0.11
235.2561646	0.15
243.1572571	0.12
247.1425171	12.84
261.0020142	0.27
268.9640198	0.97
270.1060181	0.23
290.5652771	0.15
305.1747742	1.26
315.0820923	29.35
315.7027893	0.55
323.0634766	1.08
331.4304810	0.31
365.1381531	8.62
375.2712708	15.77
393.2994385	14.34
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.21
Annotation	Barbatoside A
Peak:m/z	Relative Intensity
195.0485077	11.40
201.1152954	0.16
216.0468292	0.12
219.1397400	1.24
221.3559875	0.06
230.8736877	0.09
237.2021484	0.38
243.3357544	0.10
261.1746826	0.12
316.9827271	0.48
319.1295471	0.14
337.1016541	0.30
339.2438354	3.42
341.4008179	0.17
355.2116699	0.12
357.1320801	100.00
357.7607422	0.07
369.9482422	0.37
380.9135742	0.53
398.0219116	0.39
399.1215210	25.23
399.7574463	0.14
410.9089966	0.25
415.0924683	0.19
421.0545654	0.14
423.1947632	1.43
428.1000977	0.39
429.0573120	1.04
439.1145630	2.30
441.2030640	0.31
455.2205200	0.38
458.9488525	9.28
459.5847778	0.03
464.9481201	0.14
471.2134399	0.30
483.1601562	0.32
489.0362549	0.13
499.3984375	0.24
501.2293091	27.95
517.3501587	0.93
518.8067017	4.37
519.4652710	0.14
543.0753784	2.07
557.4600220	0.26
559.2121582	0.43
561.0187988	0.46
561.6228638	0.38
573.3198853	0.42
579.0094604	0.19
601.3892212	0.09
603.2208252	4.59
617.3058472	0.41
619.3264160	0.06
625.2193604	0.28
627.2429810	1.03
645.1887207	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
255.2115784	0.01
257.9664612	0.02
286.2411804	0.11
301.1773682	14.47
313.1262207	0.02
343.2575073	0.08
345.3066406	0.02
367.1757202	0.02
411.1591187	0.22
429.3823242	0.20
445.1564331	0.06
447.1022339	0.87
463.0657959	100.00
463.6837158	0.53
573.4792480	0.02
591.0681763	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	439.0858
Annotation	9,10-dibromo-stearic acid
Peak:m/z	Relative Intensity
142.9905701	1.42
160.9907532	0.99
178.9081116	4.64
221.0685425	1.82
259.1034546	56.62
277.1034241	44.79
292.2782288	1.19
310.9908447	3.00
341.1927490	100.00
379.3747864	0.46
403.1439514	1.27
421.0706482	41.91
421.7250977	0.55
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	401.1816
Annotation	Spionoside B
Peak:m/z	Relative Intensity
133.9873047	0.18
135.1322632	0.11
149.0455017	0.22
159.2404785	0.07
160.1806946	0.09
171.9870605	0.08
175.1078644	0.08
186.1695099	0.25
187.1476135	0.03
187.8569031	0.02
190.0838928	0.53
191.0692139	0.02
197.1059265	0.06
205.0712891	2.77
217.0955505	0.06
250.9163513	0.02
268.8789673	0.04
271.3353882	0.05
279.1394348	0.06
283.2328491	0.03
295.2880249	0.14
297.3850098	0.03
306.1417542	0.02
307.2977295	0.07
308.1000061	0.04
311.1015015	5.26
313.0465393	0.19
321.3358154	0.05
323.1393433	0.06
325.0826111	0.10
326.0427246	0.55
327.1958313	0.18
329.2589417	0.63
339.3757019	0.06
341.1705322	100.00
342.2376404	0.45
355.8648987	0.05
357.2278748	0.70
359.2623596	0.18
364.0593872	0.05
365.3476257	0.20
369.3522644	0.09
371.2066650	0.97
380.9783630	0.02
383.1661682	0.61
386.3175354	0.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
186.9446716	0.20
188.1804962	0.53
199.3358307	0.32
215.0552063	0.95
224.9729309	0.60
232.9502411	0.69
239.8060608	0.86
242.1956024	0.57
255.2267761	0.46
256.2921143	0.44
257.1235962	1.24
258.0635986	1.75
270.092804	0.16
270.9481812	0.51
283.3524475	1.42
284.4564819	0.21
299.0687561	0.62
301.0812378	100.00
302.2214355	1.43
315.0263977	1.01
323.3126221	0.17
325.2394714	1.50
342.9291992	0.17
369.3391724	1.26
381.3075562	0.88
398.9899292	3.90
413.227478	1.27
429.272522	2.52
449.1680298	1.89
471.357666	1.01
483.0899658	0.21
489.2213745	12.24
490.3157959	0.52
493.552063	0.28
501.3964844	0.68
508.2976685	0.13
513.5709839	0.63
519.2211304	3.99
520.8921509	0.43
529.2929077	0.50
549.8823242	0.91
550.7877197	0.35
561.4273071	0.48
563.2515869	0.74
565.0327148	0.44
587.3779297	0.47
591.3773193	2.11
592.3986206	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	343.1222
Annotation	Lactulose
Peak:m/z	Relative Intensity
109.0375214	0.41
109.9895172	0.20
126.3274231	0.11
127.0376740	0.63
131.2180481	0.08
132.8910370	0.07
134.2157898	0.09
134.9205627	0.07
144.9592590	2.50
147.9421692	0.04
162.8175354	5.09
167.9935913	0.17
175.1369476	0.08
180.9768066	6.23
193.2488861	0.09
197.0563965	0.56
200.1211548	0.41
203.1971283	0.26
223.1077271	0.30
224.1783447	0.21
228.9044800	0.17
229.9752502	0.12
235.2705994	0.25
244.8346863	0.13
246.9638367	0.07
247.7937927	0.09
254.2554321	0.96
257.9810181	0.09
259.0170898	0.14
259.8073425	0.14
269.2913208	0.19
271.0243530	1.13
271.9995117	0.40
283.3073425	0.32
288.9049683	6.25
289.8823853	1.72
301.1017761	0.07
305.7554321	0.48
306.9804688	2.36
308.3125000	0.04
314.2553711	0.15
324.9913940	100.00
326.0137634	6.57
342.8693542	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	515.2256
Annotation	Pterosin U
Peak:m/z	Relative Intensity
146.9978638	0.33
151.1016235	0.26
152.0234985	0.44
153.1325073	0.28
156.9564514	1.17
158.9248657	0.08
160.9956512	12.87
163.0939331	0.25
169.1617889	2.04
171.1252441	3.09
173.1123962	1.87
175.1295471	3.63
178.9918518	2.00
181.1706848	2.14
181.9108276	0.08
183.1241760	0.55
184.0327148	0.29
185.0361328	2.76
187.0003204	13.37
187.6772766	0.10
189.3320007	0.45
190.9107666	0.41
193.2208862	0.62
195.0447998	0.70
197.1630707	0.13
199.1231995	1.40
200.9041138	1.56
203.1507874	1.84
205.0674744	2.34
207.1744080	1.00
208.3123169	0.48
209.1181793	1.20
211.1362915	0.30
213.1934204	4.02
214.9822693	6.92
215.5923157	0.05
216.2279358	0.23
217.2200928	0.71
219.0701447	2.71
221.3395538	0.48
222.5348358	0.57
225.1625671	1.20
227.1833801	2.24
229.2279968	1.47
230.9754333	23.18
233.2210388	0.49
234.8571320	0.27
236.3311462	0.16
237.0720062	2.31
239.2686005	0.86
241.1726074	4.45
242.9727173	2.67
245.1186523	1.49
247.1958313	0.90
249.2204895	0.34
251.3452301	1.47
252.5916290	0.59
253.3737183	0.33
254.8923950	0.88
255.5652008	0.66
257.0516663	2.72
259.1772156	3.40
259.9989624	1.06
261.2136536	2.16
263.2351685	2.60
265.0128784	0.68
267.2088013	1.62
269.2230835	5.17
271.1231689	0.80
272.9417114	0.84
275.2478027	0.36
277.3176575	1.75
278.0804749	0.38
279.2842407	1.26
281.2124023	1.77
283.2327881	4.12
285.0759888	1.77
287.1849060	4.91
289.1240540	2.05
290.1250000	0.55
291.2677002	3.05
293.1102905	3.99
293.7265930	0.81
295.1405029	2.68
297.2802429	4.43
299.2962036	0.94
301.1779175	1.59
302.7694092	0.54
303.4032593	1.57
305.1870728	3.53
307.1865234	2.59
309.1824341	2.01
311.1145630	2.50
313.2084351	2.77
314.2775269	0.49
315.2233887	3.38
317.0800781	1.40
319.1870117	2.43
321.1553345	5.71
322.2430420	0.28
323.1988525	4.67
325.2573853	3.58
327.2850952	1.72
329.2973633	2.10
331.1992188	3.99
333.1911011	4.56
335.1923828	5.51
337.4089966	1.27
339.2828369	5.28
341.3218384	3.55
343.3848877	0.98
345.2067871	2.48
347.2739868	1.14
349.2549438	6.38
351.2706909	7.93
353.3326416	1.72
355.2732544	1.62
357.1342163	1.77
357.9234009	0.34
359.2211304	3.07
361.1821899	1.89
362.2389526	2.06
363.2814331	5.34
365.2152100	7.36
367.2175293	9.08
368.1799316	0.60
369.3167725	18.64
371.1660156	0.38
373.3904419	2.22
375.2452393	8.73
377.2606812	9.41
379.1374512	2.30
380.4914551	0.68
381.2396851	3.08
383.1754150	2.90
385.1284790	2.80
387.2655029	0.65
391.2664795	18.62
393.3273315	43.21
395.1339722	9.44
395.7586060	0.07
397.5408936	0.41
399.3158569	0.41
401.1807251	6.70
405.3465576	0.42
407.0970459	0.13
408.6773682	0.81
409.3229370	19.46
411.2663574	100.00
413.2238770	20.38
415.4697876	0.36
419.2386475	22.50
421.0504150	0.93
425.5485840	0.79
427.1627197	5.51
429.3924561	3.08
433.6473389	0.10
435.1824951	1.28
437.1771851	42.26
437.8353882	0.06
441.1513672	0.74
447.0989380	2.93
451.4196777	4.43
452.7952881	0.56
453.4845581	0.57
455.1435547	39.82
455.8076172	0.50
467.2368774	0.92
469.1263428	57.67
469.8637085	0.30
471.1414795	14.81
473.1254272	4.18
479.1914062	2.42
485.4205933	0.35
487.2819214	3.36
496.6647949	2.09
497.2926636	16.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.088
Annotation	Unknow
Peak:m/z	Relative Intensity
254.7045593	0.14
288.8472900	0.06
298.9626160	0.31
317.1287842	0.36
318.9074707	0.06
326.9836426	0.20
343.0435791	0.04
344.4977417	0.03
360.8577881	0.11
379.0051270	0.03
387.2683105	0.09
405.0620117	5.13
406.2482910	0.07
413.0429688	1.30
418.1008301	0.06
423.0978394	18.31
428.8644409	0.12
439.0605469	0.16
457.1309814	0.11
482.9555054	0.50
501.1149292	6.47
519.0807495	100.00
519.7689209	0.05
579.6779175	0.17
585.1312866	0.23
692.4564819	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	776.8124
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9205627	0.14
273.1455383	0.26
288.9581909	1.16
305.0778809	1.10
306.0175781	0.11
313.1506958	0.09
363.0023804	0.10
387.2341919	0.03
389.0559692	0.11
403.0017090	1.91
418.9580078	5.90
434.8800049	1.78
516.9479370	0.80
532.8325195	16.17
548.8538818	13.62
630.9717407	0.09
646.8777466	4.93
647.5129395	0.05
660.0082397	0.14
660.9259033	0.16
662.7444458	100.00
663.4290161	0.26
664.9431763	0.03
674.8750610	0.20
686.8829956	0.04
701.8308716	0.14
718.1499634	0.10
729.7214355	0.15
730.7467651	0.27
732.8460693	0.13
745.0585938	0.09
748.5470581	0.07
753.7589722	0.11
758.7858887	0.14
759.5983276	0.05
766.5159912	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	437.1089
Annotation	Loquatoside
Peak:m/z	Relative Intensity
124.9484863	31.52
138.9775085	0.94
147.1418762	0.23
148.9463043	16.07
152.0596619	0.19
152.9592438	7.01
166.9762878	3.26
174.9135132	0.32
176.9245605	0.73
178.9932861	2.93
191.0975647	1.48
194.8848724	0.97
207.0597076	1.06
209.0713806	2.99
218.8242340	0.83
224.8792114	0.96
236.9934845	1.21
239.1055298	1.88
250.9158325	1.11
254.2012634	0.83
255.1624146	0.46
269.1337280	85.28
275.1799316	0.34
279.0769348	0.34
293.0101624	0.76
297.0846558	100.00
298.2643433	1.39
298.9114380	0.29
311.1605225	39.42
350.4542236	0.59
377.2051392	0.72
391.2468872	0.34
419.3274841	0.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	896.4714
Annotation	Unknow
Peak:m/z	Relative Intensity
255.2993469	0.01
341.7615967	0.03
356.1933594	0.01
376.5609741	0.02
398.7714844	0.01
438.7669678	0.02
439.4003296	0.01
443.5128784	0.01
447.6231689	0.03
452.3364258	0.03
469.5010376	0.02
470.5174561	0.03
486.4661255	0.02
499.1511230	0.02
508.4033203	0.00
520.3615112	0.02
527.2703857	0.01
528.6385498	0.03
544.3972168	0.01
549.0210571	0.04
566.7888794	0.03
579.3508301	0.01
583.5444946	0.01
601.1635132	0.01
613.5410767	0.01
638.6632690	0.16
640.3890991	0.02
657.6139526	0.11
678.3878784	0.03
687.6199951	0.00
695.6467896	0.13
696.9445190	0.01
714.4784546	0.02
719.6266479	0.02
731.4163208	0.11
733.5390015	0.01
737.5815430	0.57
749.5167847	0.05
767.2653198	0.03
768.2803955	0.00
781.1841431	0.01
800.6188965	0.01
818.5336304	0.10
834.5114136	0.01
848.3761597	0.27
853.8467407	0.05
860.4304199	0.15
866.4767456	100.00
867.1068726	0.62
874.4649048	0.04
877.9034424	0.09
878.5626831	3.97
880.0830688	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	869.2767
Annotation	Unknow
Peak:m/z	Relative Intensity
245.1384430	2.97
263.1595459	0.89
265.1641235	4.79
277.1729736	0.77
283.1812134	4.45
286.7914124	0.34
289.1882019	1.34
295.3308716	0.77
305.0485840	6.84
305.6870117	0.21
317.0238647	1.53
319.0529480	0.16
321.3949585	0.35
329.2203674	0.41
335.4010010	1.12
337.0653076	1.11
339.1252747	0.16
340.9597778	0.87
346.3567505	0.15
350.1605835	0.11
353.1677856	0.24
359.0477905	0.51
377.2763672	0.33
378.0256958	0.15
379.4593506	0.61
383.1531372	0.21
395.4213257	1.29
397.1467896	13.89
401.3062134	0.54
403.1929932	0.98
407.0081177	0.73
409.3668213	1.19
415.2429199	4.77
419.1316528	0.31
433.0503540	0.14
437.0243530	0.83
442.9050293	0.23
449.2177124	1.66
450.3444824	0.32
453.1895752	0.21
454.3807983	0.32
473.2006226	1.60
475.2008667	0.65
479.1968994	0.17
481.3427734	2.06
490.9721069	0.71
505.2431641	0.43
509.2511597	6.88
511.1114502	0.13
524.4909058	0.25
529.3532715	5.18
540.7344971	0.18
541.3502197	2.86
545.1801147	0.20
547.2977905	8.01
548.2108154	0.17
554.1856079	0.53
586.3674927	0.22
589.3418579	0.90
593.1994019	1.76
594.7136841	0.75
600.7640991	0.90
603.3876953	0.32
604.1593018	2.08
605.2025757	0.53
606.0430298	0.24
617.4141846	0.31
623.4470215	1.57
625.3483276	0.71
626.8124390	0.52
637.2965698	0.27
641.2865601	0.84
643.2400513	6.94
644.2050171	0.52
649.7258911	0.49
655.0698242	0.08
657.1140747	0.22
658.3676147	0.11
659.0679932	0.70
661.3322754	12.76
669.2143555	1.61
675.3005981	0.70
676.3300171	1.52
677.6080933	0.83
687.3170776	2.73
688.3234863	0.16
693.4476929	3.80
705.3094482	0.39
707.8120117	0.40
717.2104492	1.05
719.5154419	0.16
735.4050293	0.58
736.4386597	4.12
737.3087158	5.40
779.0641479	1.72
789.8874512	1.35
790.7777710	2.87
791.3922729	1.31
793.2625732	23.95
794.4262085	0.74
807.4959106	1.09
808.2897339	2.42
809.1316528	4.41
809.7849731	0.23
825.4689331	2.78
837.2745972	100.00
838.1851196	5.57
851.2922974	2.90
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	348.1431
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
135.8572388	0.06
146.9416504	0.03
153.1994324	0.02
186.7395935	0.03
229.0589294	0.04
231.0932617	3.70
233.0446167	17.01
263.9771118	0.05
268.3731079	0.02
271.0995483	0.34
290.2540283	0.04
292.0559998	0.02
299.0451660	62.54
299.6893311	0.28
311.5903320	0.22
317.0017700	100.00
317.6748047	0.20
321.0152283	0.06
325.3311157	0.04
329.3330688	0.40
330.2596436	0.12
333.0462646	0.07
340.1183472	0.12
349.8386536	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	427.1974
Annotation	Carolenalin 4-O-beta-D-glucoside
Peak:m/z	Relative Intensity
131.1072388	0.20
135.0352936	0.03
136.0176544	0.28
137.1184082	0.43
138.0293884	0.80
138.9626923	0.05
142.9809875	0.29
147.2192383	0.04
148.9242859	0.13
151.0296631	0.32
151.9562378	0.09
153.0158386	24.23
161.0637512	0.77
163.2971649	0.03
165.0823059	0.28
167.0349121	0.09
169.2296600	0.07
172.0853424	0.26
174.8653259	0.07
179.0115662	0.09
183.1726685	0.30
186.0078735	0.29
187.1634216	0.99
190.2868652	0.12
203.1043701	0.44
205.1874695	26.93
218.8746033	0.05
221.1426239	0.04
223.0575256	10.16
224.9429321	0.04
229.1823578	0.24
245.3891602	0.11
247.1539612	0.74
259.2869568	0.04
261.0014038	0.12
265.0814514	1.82
281.1079102	0.09
282.8937378	0.03
289.0440674	0.20
295.2854309	0.07
297.3470459	0.17
307.2962952	0.06
308.1130676	0.22
319.1540833	0.13
325.1538086	0.20
337.3137207	0.15
341.1187439	0.44
341.7496338	0.03
367.2182007	100.00
382.8899841	0.05
385.2208252	4.67
409.2976379	2.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
174.0912933	0.67
182.958786	0.08
187.9516754	0.30
199.0438385	0.88
200.1640472	0.06
208.8229218	0.90
211.0569611	0.54
213.1705627	0.12
214.306366	0.32
216.3009644	0.14
223.238739	0.22
223.9915924	0.31
226.9489136	0.69
230.7344513	0.16
238.9078827	0.44
240.096817	0.77
242.1044617	1.29
255.0661163	0.11
257.074585	0.38
258.2118225	0.17
267.8700256	0.27
283.1426392	0.60
284.0545044	0.29
285.1151733	0.78
286.0427856	1.83
296.1449585	0.09
299.0705566	1.01
301.081604	100.00
301.6885681	1.03
302.4242859	0.20
325.1604614	1.22
341.2715454	0.24
343.3009644	0.32
358.3641968	0.08
368.9459839	0.13
381.6010132	0.17
399.2199097	1.12
408.5917358	0.11
430.1345215	0.30
443.3413696	0.14
447.3765259	0.08
455.8848877	0.12
459.1018066	0.52
471.0053101	0.31
487.1730347	0.45
489.2114868	5.43
490.2877808	0.36
501.1502686	0.38
519.1366577	1.03
520.2686157	0.14
531.3527832	0.14
537.2712402	0.05
543.1835327	0.36
563.3223267	0.11
565.4279175	0.30
584.9006348	0.07
591.3162842	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.25
Annotation	13,14-dihydro-15-keto Prostaglandin E1-d4
Peak:m/z	Relative Intensity
114.9227982	1.21
129.1102295	0.24
130.0616608	0.43
147.0088806	0.83
157.1282043	0.36
171.3023071	0.67
173.1249084	0.54
185.0679016	3.33
187.1649933	4.40
193.8849335	0.32
195.2063904	1.02
199.1821594	3.01
201.2328186	0.83
213.2954712	2.44
215.1920776	3.09
217.1477966	0.59
227.3904114	1.76
229.1645508	4.22
231.0125732	1.02
241.3826599	1.94
243.2122498	4.33
244.627594	0.54
245.5021362	0.73
255.2269287	3.26
257.0936584	4.56
259.0573425	0.66
263.255127	0.86
269.2077637	2.61
271.1980896	5.42
273.1732788	0.80
278.0664673	0.50
282.9869385	0.96
285.328064	8.36
287.3068848	1.60
297.3539429	1.63
299.1875	11.61
301.21521	2.20
301.8419495	0.19
307.6838379	0.69
311.128479	1.33
313.1816406	2.20
315.3191833	4.53
321.1220093	3.60
323.3460388	16.02
325.3401794	0.25
330.4790344	0.73
339.2475891	100.00
340.1029968	0.81
341.3543396	11.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	207.0646
Annotation	Anhydrosepedonin
Peak:m/z	Relative Intensity
66.9359360	0.08
76.9977341	0.38
78.9843903	0.78
82.8908234	0.12
89.0665588	0.09
90.9926300	0.58
100.8165131	0.06
102.9602966	2.75
103.9475708	0.26
105.0705109	1.05
117.9920044	1.03
118.9545288	1.85
119.8640747	0.55
120.9727173	2.36
122.9736633	0.23
131.8470612	0.06
132.9769135	3.79
134.0926971	0.14
135.0045166	0.86
136.0876923	0.70
136.8346558	1.00
138.9743958	0.91
145.0233765	0.40
147.0602722	0.77
147.9990845	3.83
148.8796844	0.43
151.0485229	24.81
152.0131226	0.27
152.9772644	0.60
161.0748749	0.06
163.0605164	100.00
164.0309601	5.52
165.1481934	0.11
166.0045471	0.37
174.8035736	0.88
176.0875397	0.50
179.1044312	13.62
180.0839081	0.40
191.9727631	56.29
193.0876160	3.07
194.8666687	0.14
207.1324310	22.23
207.8794250	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	481.2022
Annotation	Unknow
Peak:m/z	Relative Intensity
156.8614807	0.03
159.2758179	0.03
161.3729858	0.03
165.9539795	0.03
167.2553101	0.07
186.9768372	0.04
204.9873962	0.08
207.3078156	0.03
213.4641266	0.03
233.1620636	0.18
234.2791748	0.08
251.0727844	0.07
253.1318665	0.05
259.1776428	0.69
262.2214966	0.07
269.1484985	0.03
275.1966248	0.07
277.1002808	5.09
284.1113281	2.95
291.1546326	0.04
301.1165161	1.52
302.0231018	0.35
303.1923523	0.02
305.9360352	0.03
319.1666870	100.00
320.2324219	0.23
321.2217407	0.01
329.1131287	0.03
335.4095154	0.08
337.1010742	0.02
341.3474731	0.15
347.1163330	0.02
348.3214722	0.04
349.1948242	0.02
356.9118347	0.02
360.4186707	0.05
361.3124390	0.02
366.2074585	0.08
369.2880859	0.05
379.3417664	0.13
390.1724854	0.01
401.3588562	0.04
406.2033386	0.08
419.0599060	0.08
421.1852417	0.12
428.0868835	0.06
434.9941406	0.06
437.3564148	0.06
439.5780334	0.04
445.0685730	0.03
446.1751404	0.13
452.7634583	0.16
462.7815857	0.44
463.3856506	0.60
464.3536987	0.15
468.9933472	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	343.1033
Annotation	Teuhircoside
Peak:m/z	Relative Intensity
107.9747925	0.04
108.9209137	0.27
110.8730927	0.02
113.0149612	0.03
118.9796524	0.04
120.8956757	0.37
123.0089874	0.05
134.9686279	0.10
136.9916687	3.57
139.0245819	0.10
143.2373505	0.05
161.2390747	0.03
162.9971008	1.86
165.9775085	0.02
180.9759369	100.00
204.9317017	0.02
211.9909668	0.02
223.0751038	0.03
247.0920715	0.01
262.9464111	0.03
299.0540161	0.03
301.2575378	0.04
325.3800659	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1927
Annotation	8-Acetoxypinoresinol 4-glucoside
Peak:m/z	Relative Intensity
169.3272858	0.10
173.0780792	0.25
174.9828033	0.02
178.9149323	0.22
181.0921173	0.04
188.1454468	0.10
190.3823242	0.05
193.1525879	0.21
194.1337585	0.04
199.0257874	0.04
203.2085571	0.15
206.0233154	0.20
207.1198730	0.13
207.9049530	0.23
217.0781860	0.14
220.1112518	0.04
221.0956116	1.09
223.0688171	2.15
224.8906555	0.24
230.2143860	0.04
232.2234039	0.15
235.1476746	0.48
237.2424011	0.59
239.3426514	0.08
241.2845306	0.05
246.9512634	0.36
249.9828339	0.02
251.0986938	0.08
258.7800903	0.05
265.1839905	9.33
267.0528870	0.11
269.1242065	100.00
277.2033081	0.40
291.0880737	0.14
293.1401367	0.23
295.1268616	5.67
307.2501831	0.07
311.1324463	0.24
314.5678101	0.13
316.9286499	0.10
325.1301880	7.89
330.1417847	0.79
331.2048950	1.47
337.2145386	0.56
339.1707764	0.18
342.2402954	0.03
353.4411621	0.06
355.2357788	0.27
367.2084961	0.96
369.3038940	0.04
379.1461792	0.09
383.1365356	0.18
385.1184692	23.79
387.3887939	0.20
389.3950806	0.12
396.9991455	0.10
407.3806152	0.03
413.0401001	0.61
413.7855835	0.03
415.3181763	0.06
423.3362427	0.23
425.2227783	0.04
427.3276367	0.09
429.5207520	0.10
433.2364502	0.44
435.2124634	0.05
439.1422729	0.37
454.7849121	0.03
457.2775269	0.37
459.3496704	0.35
475.3014526	0.93
485.5709839	0.25
487.4440918	0.17
491.4550781	0.03
505.4797974	0.08
517.2555542	1.28
519.1544800	0.08
521.0270386	0.11
531.4406738	0.50
533.3367310	1.52
535.2438354	0.64
541.4679565	0.17
545.1634521	0.03
547.6028442	0.05
549.2625122	0.09
558.6768799	0.11
559.3828735	2.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	765.2246
Annotation	Unknow
Peak:m/z	Relative Intensity
217.9437866	0.04
239.0464783	3.47
251.0500946	0.41
279.0433655	0.55
280.2570190	0.08
281.1311646	3.47
287.2181396	0.08
304.9713745	0.29
322.2357483	0.21
357.1826477	87.43
383.3766479	0.05
407.2142944	100.00
440.3491211	0.10
441.5283813	0.12
456.9094849	0.45
524.3098145	0.05
568.0490112	0.21
589.3396606	0.19
602.1919556	0.17
620.9653320	0.55
642.9096680	0.07
645.2025146	0.20
720.2791138	0.05
721.4100952	0.08
746.0802002	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1565
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
169.2371216	0.21
172.9801178	0.30
181.2320251	0.19
224.785965	0.13
225.4384613	0.13
226.8799744	0.09
252.0692749	0.36
269.0470886	100.00
269.697998	0.68
275.3934326	0.13
283.2427063	0.47
311.0393677	0.93
359.3022461	0.45
413.0875854	0.50
419.3989258	0.21
423.3866577	0.10
456.78125	0.26
461.3910522	1.06
473.5878906	0.16
476.8045044	0.08
517.4616089	0.30
529.3792114	0.17
530.9951782	1.15
531.8987427	1.24
533.2025146	0.24
534.2247925	0.26
535.5176392	0.60
558.286438	0.79
559.1505127	1.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.0957
Annotation	Isoimperatorin
Peak:m/z	Relative Intensity
93.0776291	0.01
97.1030731	0.03
98.9756470	0.02
106.9036102	0.01
116.1622314	0.03
120.9938660	0.02
146.9537811	0.03
155.2244873	0.06
162.9710541	0.02
177.3176880	0.03
191.0444183	0.02
195.2910767	0.02
202.9824829	100.00
203.7707214	0.01
214.9824677	0.03
225.3110962	0.03
229.0083008	0.05
243.3913422	0.05
250.5602417	0.12
253.2273712	0.15
259.0254211	0.04
262.1693420	0.01
271.1692810	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2292
Annotation	Cinnamoside
Peak:m/z	Relative Intensity
193.2700806	0.24
265.3251953	1.60
297.3222656	0.67
313.2801514	2.90
323.3587036	0.64
331.3259277	1.09
337.1450195	1.48
354.1177979	0.57
354.7461548	1.99
371.2551880	1.76
373.0693359	68.52
373.6926270	0.46
414.3886719	12.28
415.1319580	100.00
433.1416626	1.27
455.0956421	23.05
456.6429443	0.52
457.4936523	0.53
473.0868530	32.27
473.7633667	0.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	302.1743
Annotation	Dobutamine
Peak:m/z	Relative Intensity
90.7550125	0.21
95.0411987	0.08
95.8405075	0.15
99.8453445	0.09
104.0414429	0.05
106.0353622	0.48
106.8920593	0.86
108.9422302	0.19
111.9562149	0.27
113.1390381	0.05
116.3450699	0.20
119.0897522	0.46
121.0440063	2.09
121.9424515	0.05
123.0706940	5.52
125.0684052	0.14
126.9433289	0.06
128.0142365	0.07
131.0122070	0.35
132.2615662	0.37
133.0268250	2.57
133.9067841	1.07
134.9634399	3.26
135.9338531	0.06
137.0475922	1.44
144.8312988	0.53
146.1205444	0.06
147.0137024	0.24
149.1159821	0.84
149.9830627	1.55
150.9698639	0.92
152.9289093	2.35
154.9687195	0.19
157.3457947	0.07
159.0787048	1.31
159.9091034	0.42
161.0583801	1.58
162.0784302	1.82
163.1258850	0.14
164.0785522	0.58
165.1212311	0.28
166.7282867	0.23
171.0885315	0.27
173.3003998	0.87
174.1004333	1.46
175.1088562	1.15
176.9811859	15.78
177.9788971	100.00
179.0421143	4.47
180.1064911	3.16
181.0778961	0.21
182.1333923	0.05
182.9601135	0.25
184.4020081	0.41
185.6203003	0.54
187.1199036	0.55
188.1535950	0.65
189.9653015	0.18
192.0994568	43.47
195.1473694	0.23
195.9757538	0.15
197.2254639	0.54
198.0689392	0.15
200.0513916	0.95
200.8438110	0.55
202.0715027	1.68
203.0361328	7.17
204.1146545	1.00
204.8379517	0.24
206.0131836	30.20
207.0909119	0.27
209.0688477	0.32
210.1052856	0.09
211.2376709	0.51
214.0795898	2.29
215.1819153	0.34
216.0033569	0.12
217.0854797	0.13
218.1567993	1.17
220.0662231	57.02
221.1109009	0.32
225.2649841	0.12
226.9643555	0.29
228.1411133	1.91
229.2262573	5.53
229.9230042	0.13
231.1112366	2.16
232.0115662	2.57
234.0531921	1.22
234.9757690	0.05
238.0841064	0.16
239.2136230	4.45
240.1204224	0.26
241.0653687	0.52
242.1431885	0.15
243.9976196	0.47
246.1336365	14.75
249.0123901	0.04
249.9418945	0.17
251.1470947	1.51
253.2379761	0.12
256.4115601	3.35
257.2052612	17.46
258.0625305	1.71
260.5842896	0.89
261.2488403	0.30
262.3292847	0.13
266.3194275	0.96
267.0225220	1.05
269.2256775	2.78
270.9638977	27.72
272.0805054	0.35
274.1882324	2.59
275.2833862	0.13
284.1986389	15.98
285.2200317	4.93
287.1375732	8.49
288.2213745	1.44
293.1961365	0.18
302.5750732	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	436.0306
Annotation	Unknow
Peak:m/z	Relative Intensity
159.0272064	0.02
169.0542603	0.04
182.2886047	0.05
183.9775085	0.10
200.0453644	0.25
218.1676636	0.08
225.9781189	0.11
243.9742432	0.19
246.0802917	1.47
258.1284180	0.08
260.1822205	0.19
261.0790100	0.08
262.0927124	0.52
263.1475830	0.94
263.9051819	0.11
272.0697021	0.16
280.1937866	0.40
286.1782227	0.10
290.0174255	0.25
302.3645935	0.05
304.0593567	28.77
305.0482788	0.12
312.3327026	0.06
316.1550903	0.13
317.1353760	4.69
318.0705566	0.15
328.1904297	0.04
331.2203369	0.06
332.2570190	0.13
333.5765381	0.23
334.2033081	0.41
344.3467407	0.13
346.1560974	3.09
348.0543823	0.07
349.2286377	0.03
354.6778259	0.03
356.1900635	0.53
359.2759705	0.06
361.9863586	0.17
370.9953918	0.05
372.0859680	1.01
374.0578918	0.39
375.0161438	0.07
376.3475342	0.02
387.6082458	0.07
390.1302490	100.00
392.0909729	56.90
393.2397461	0.18
418.0973816	2.71
419.2493591	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	561.2191
Annotation	Cucurbitoside G
Peak:m/z	Relative Intensity
157.2809296	0.07
160.8268585	0.19
162.9897614	1.33
163.9582214	0.13
172.9834442	4.29
174.9951477	0.09
187.1539917	0.79
191.0993805	7.24
193.0270081	0.99
195.1668091	0.22
204.9742279	0.12
207.7835541	0.09
208.9426880	0.88
213.0690002	0.57
217.2167358	0.11
221.0060883	0.27
223.0014191	1.42
231.0223236	1.02
247.2838593	0.08
255.1264343	0.35
263.2116089	0.11
273.1697388	0.21
284.7967529	0.17
286.3976135	0.15
289.2128906	0.29
291.0327148	2.33
293.1397705	1.86
301.0155640	0.39
314.4656372	0.79
319.1084595	0.07
323.0888062	0.75
326.9965210	0.13
335.1431885	0.15
337.1652832	37.10
353.0122681	2.24
355.0905151	5.27
357.2638550	1.29
367.1182251	11.01
369.1280518	0.31
371.0949097	0.29
372.9755859	0.80
383.2715454	0.23
385.1570435	2.99
397.0725098	33.28
398.7332153	0.79
399.4404297	0.10
413.4061890	0.15
415.0993042	13.36
417.1601562	2.64
435.2577515	0.13
444.4190674	0.50
454.8080444	0.69
458.2620850	0.11
463.2211304	0.68
472.9786987	0.83
474.9848022	0.08
475.6267090	0.10
477.3187256	0.18
486.2213745	0.21
499.1925659	0.82
500.1312256	0.81
500.9952393	0.21
501.6149902	0.09
515.2343750	0.37
517.2135620	100.00
518.1309204	0.07
525.0772095	0.07
531.0124512	0.27
541.1528320	0.34
542.9295044	1.97
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	380.84
Annotation	Unknow
Peak:m/z	Relative Intensity
126.8952942	0.04
128.8744965	9.57
197.2488251	0.06
212.7526093	6.39
219.0349121	0.21
261.1079102	0.05
268.4786377	0.27
269.9718628	0.38
282.2500000	0.05
296.7276917	100.00
297.3602600	0.85
335.1193542	0.18
350.2847595	0.03
352.0612793	0.14
353.2169800	0.06
363.0419006	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	595.17
Annotation	Butrin
Peak:m/z	Relative Intensity
176.7450714	0.19
225.1093597	0.56
241.4720154	0.07
269.0695496	1.45
287.1333618	100.00
310.8956299	0.06
442.9935303	0.07
459.0797729	1.78
469.0684204	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	927.2404
Annotation	Unknow
Peak:m/z	Relative Intensity
271.0769653	0.07
300.0673828	0.25
305.2501221	0.05
315.0117188	2.42
357.2457275	0.05
405.2487793	0.08
449.3517456	0.13
475.3094482	0.03
477.1871338	18.18
489.3104248	0.03
501.4081421	0.03
519.2542725	9.31
531.2908325	0.03
549.3314209	0.69
559.2391968	7.36
561.2444458	2.55
585.3873901	0.04
601.1262207	1.43
601.8530273	0.01
603.2653809	0.57
615.4096069	0.06
621.2449341	100.00
625.3670044	0.04
627.4773560	0.09
635.1213379	0.03
639.1532593	6.36
641.6182251	0.02
643.4562988	0.05
645.0870972	0.04
650.8984985	0.04
652.2294922	0.11
663.1871948	16.27
667.4080200	0.02
674.8305664	0.16
681.3027954	8.29
693.1776123	0.66
703.1838379	3.09
705.2405396	1.32
721.3040161	5.28
723.1684570	1.85
728.9676514	0.05
735.4791260	0.17
745.2670288	0.10
747.3786011	0.13
763.1385498	0.45
765.1156006	23.50
765.7913208	0.18
777.9525757	0.04
781.7918091	0.71
783.1505737	66.44
783.8372803	0.12
807.3047485	0.05
825.2168579	5.18
827.1918335	0.12
836.7651367	0.06
841.4109497	0.20
865.0642090	2.94
866.8154907	0.12
873.1660767	0.04
905.3428955	0.15
909.2796021	0.26
910.5111694	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	153.1269
Annotation	Isocitral
Peak:m/z	Relative Intensity
56.8761482	2.11
58.9139023	5.10
67.0963287	0.42
68.9287949	3.17
70.8720703	100.00
72.8486481	0.44
78.9010544	0.48
80.9662018	34.43
82.9606628	7.55
84.9820099	0.22
91.0065308	0.49
92.9669342	16.59
94.9546356	53.64
97.0026398	15.36
107.0156555	23.06
108.9824219	24.98
109.5947113	0.20
111.0237427	4.66
111.8001404	0.06
116.9039917	0.20
123.0163116	0.94
125.1231537	2.97
135.0431671	83.13
153.1971588	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	627.12
Annotation	Norbergenin
Peak:m/z	Relative Intensity
188.9568939	0.07
190.2843323	0.10
191.0035400	0.06
205.0542908	0.08
213.1779327	0.22
215.9516144	0.13
217.0303040	0.05
229.1295471	0.06
230.8094635	0.44
232.2050934	0.37
241.2745361	0.04
242.1319885	0.06
245.9760895	0.05
254.0797424	0.05
255.9302673	0.05
258.0985718	0.65
259.1588440	0.10
260.1921387	0.23
267.5464172	0.04
268.3708496	0.04
273.2169800	0.81
274.1468506	1.21
275.1097412	1.52
276.2176819	0.08
281.2562866	0.17
282.0650635	0.05
284.0690308	1.05
285.1390381	0.87
286.1567688	0.30
289.1289978	2.62
290.1607971	3.43
291.1800537	2.45
296.9716797	0.27
298.0500488	0.05
299.1733398	2.12
300.2735596	2.19
301.2572021	1.81
303.1321411	0.16
304.2083130	0.03
313.0925903	3.35
314.1790771	1.72
315.0987549	2.88
317.0946045	8.73
318.1004028	6.95
319.1595459	8.16
321.3239746	0.02
323.3182983	0.18
324.5076294	0.20
331.3695068	0.04
340.5017700	0.08
341.1868286	0.94
342.1866455	1.64
343.1201782	0.87
343.9304199	0.19
345.2241821	0.28
354.9404907	0.56
356.0504761	0.38
357.1455688	0.24
359.2019653	0.19
360.0382690	0.12
373.1420288	0.17
377.9921265	0.18
379.2437134	0.15
383.0638428	0.11
384.3035889	0.05
385.1401978	0.10
386.1322632	0.15
386.9944458	0.05
414.3512573	0.16
432.9721680	0.09
434.2121582	0.18
435.2391357	0.17
441.2708130	0.08
445.1867065	0.11
447.4220581	0.04
460.2393188	0.33
461.2129517	0.52
462.0314331	0.22
464.8872681	0.18
473.2752686	0.04
483.0728760	0.06
488.4995117	1.13
489.3059692	0.46
490.0506592	0.36
491.6556396	0.09
504.9102783	0.10
506.2236328	0.27
507.2270508	0.99
521.3184204	0.13
534.0603638	0.05
540.1975708	0.32
547.6298828	0.03
564.1367798	0.05
573.2708740	0.04
579.3975830	0.09
581.1826782	0.16
583.3839111	0.87
591.6409302	0.28
597.2600098	2.16
599.2202148	100.00
599.8516235	0.86
609.2881470	4.98
617.2781982	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	340.1594
Annotation	Unknow
Peak:m/z	Relative Intensity
96.9757538	0.10
104.9371109	4.31
108.9195557	0.36
114.6207886	0.06
122.0436707	0.02
126.9477386	4.15
128.0264587	0.07
134.9741516	0.07
144.9432373	0.23
147.1025085	0.04
164.8979340	0.12
167.0458679	0.04
171.1732025	0.08
177.0316620	0.20
177.9051971	0.36
182.0168304	0.07
182.9470367	0.85
201.1845093	0.05
211.6811218	0.02
212.9503174	0.68
221.0798340	0.07
230.8989563	33.13
231.5039978	0.07
235.9757385	0.07
244.9499207	0.09
246.2356567	0.35
248.3425598	2.22
249.0896301	10.97
251.8732910	0.05
262.7907104	0.04
266.0713806	1.35
269.2997437	0.11
271.2608032	0.02
279.9950562	0.03
286.9921570	20.36
287.5966492	0.07
298.2605591	0.11
304.9192505	100.00
322.0739746	3.68
322.7866821	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	373.1869
Annotation	Rosiridoside C
Peak:m/z	Relative Intensity
129.0066986	0.46
161.0239868	0.36
203.1248169	0.11
211.1589050	0.27
243.1817017	0.12
257.4444885	0.23
265.1264038	0.09
272.9976196	0.19
281.3976135	0.71
283.1279907	0.19
285.3628845	0.34
293.2477112	0.33
295.2667847	0.25
311.3150330	0.31
313.2595825	100.00
329.4586792	0.07
331.2922363	9.83
344.2505493	0.09
355.4214783	0.51
357.9437561	0.16
359.2373657	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	299.0771
Annotation	Pseudolaroside A
Peak:m/z	Relative Intensity
92.9617538	4.22
112.7711945	0.13
131.0159912	0.07
136.9200287	100.00
137.8229980	0.07
151.3543091	0.11
167.1185608	0.04
177.1754456	0.03
179.0429535	1.83
181.1939697	0.03
184.1577759	0.05
197.3424835	0.03
203.1286926	0.14
207.0635376	0.04
209.0670776	0.18
213.1237183	0.08
225.3829041	0.12
238.4672241	0.09
239.1166687	0.23
243.8679810	0.05
253.3021851	0.05
254.9425049	0.11
259.1951904	0.05
271.0365601	0.04
272.1734009	0.04
281.0476990	0.26
284.0477295	1.47
285.2274780	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	632.2709
Annotation	Beiwutine
Peak:m/z	Relative Intensity
308.5237427	0.14
389.5023804	0.20
424.4547729	0.37
426.9515381	0.10
450.9962158	0.22
482.0164185	0.23
484.2023315	0.81
498.2941284	0.20
510.1915283	0.39
519.5086060	0.07
528.2568970	2.45
536.6975098	0.34
537.3411255	0.15
546.2152710	0.20
547.1077271	0.29
572.2680664	100.00
573.3514404	0.48
584.8392944	0.08
586.3133545	0.23
587.0563354	0.27
588.3423462	0.07
594.0437622	0.07
595.8561401	0.21
604.0366211	0.12
612.3575439	0.04
614.1656494	0.64
617.1359253	0.25
618.2700806	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Spinosin
Peak:m/z	Relative Intensity
173.9887390	0.03
182.1920319	0.09
190.9309845	0.07
195.2885437	0.04
200.9931793	0.05
206.9830170	0.04
219.9761047	0.03
226.1981049	0.02
229.8550262	0.01
235.1350708	0.03
237.3138428	0.05
249.0170288	0.02
251.2572327	0.02
259.3895264	0.04
260.9731445	0.07
268.2243652	0.10
268.9256897	0.11
284.8026123	0.10
286.1167297	0.80
301.0744019	24.30
301.6755981	0.06
313.1467285	0.83
323.4284973	0.03
325.0985413	0.95
325.7598267	0.01
328.2617188	0.04
343.2284546	10.37
344.3282471	0.21
345.3276367	0.21
349.4008789	0.02
350.4400635	0.07
354.8276367	0.07
361.1604004	0.07
365.1295776	0.12
367.1976318	1.94
373.0915527	0.15
375.1470947	0.02
379.0319214	0.14
381.2620850	0.11
392.0477295	0.06
397.2700806	2.80
398.2504272	0.09
399.4598389	0.04
409.0654297	1.10
409.6966553	0.09
411.2319336	0.06
419.2017822	0.04
427.1676636	4.58
428.2994995	0.02
429.2326660	0.05
435.3423462	0.06
442.1771240	0.22
445.2300415	23.23
446.2169189	0.34
447.1832886	0.48
453.1249390	0.08
457.3138428	0.03
463.1387939	100.00
464.2330322	0.24
465.1063843	0.09
471.2132568	0.25
473.2210693	0.03
475.6598511	0.01
478.4456787	0.05
479.3150024	0.02
484.8546753	0.05
487.1296997	0.16
489.1055908	4.18
489.7674561	0.04
491.0946045	0.10
500.7031860	0.03
511.2872925	0.08
529.5900879	0.09
532.3887939	0.02
543.2348022	0.04
550.1096191	0.02
555.3350220	0.08
565.5149536	0.07
567.4907227	0.04
573.2236938	0.69
577.5126953	0.05
591.2349243	2.80
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.1137
Annotation	3'-O-Methylguanosine
Peak:m/z	Relative Intensity
86.9312744	0.03
100.8996124	0.02
104.8109360	0.42
108.9035416	0.03
115.9277649	0.01
118.9646454	0.23
124.9446259	0.01
130.2789612	0.02
134.9963074	0.03
135.9683838	0.05
137.2456970	0.01
142.9457092	0.01
146.0310669	0.01
149.0152893	0.03
152.0804443	0.17
154.9595337	0.01
158.0319977	0.01
160.0706482	0.05
162.9198303	0.01
164.5279541	0.02
165.9657288	100.00
167.0667725	0.08
180.0087433	0.04
182.1650085	0.04
183.2449646	0.02
188.2420502	0.01
197.1558075	0.03
199.8313293	0.02
207.0566101	0.04
207.9176636	0.01
209.1076965	0.06
212.1298828	0.01
217.7655029	0.02
218.8797607	0.14
229.0909729	0.02
232.1756287	0.02
234.7516174	0.04
237.0969849	0.02
238.0017395	0.07
239.1442871	0.24
252.0644531	0.25
253.0302734	0.11
254.1277466	0.18
255.1169434	0.03
256.5435791	0.05
257.1656799	0.15
260.0715027	0.07
262.0618896	0.05
262.9832153	0.30
266.5211487	0.25
267.1807861	0.13
270.1519165	0.04
276.3276978	0.03
279.5213928	0.09
280.1418457	0.68
281.0914612	0.14
282.1940308	0.21
289.0600586	0.04
292.2532043	0.17
297.3964539	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	700.2926
Annotation	Unknow
Peak:m/z	Relative Intensity
195.1372070	0.19
197.0283203	0.28
199.1567993	0.52
200.8142242	0.42
202.9107361	0.22
204.0078735	1.18
205.1036224	0.58
209.1188202	0.67
211.0844421	0.89
212.1804810	0.06
213.1933136	0.58
214.2540131	0.10
215.1654663	0.56
216.0627594	0.10
216.8840027	0.09
217.6052246	0.37
218.3598328	0.03
219.0462952	1.19
220.2203979	0.14
221.1743622	0.83
222.1146851	0.35
223.0496674	0.52
225.0554352	0.57
227.2159271	1.01
228.8833466	0.21
231.0624390	0.88
232.0218353	0.70
233.1467896	0.75
235.2222900	0.58
237.1285706	1.28
239.2152710	1.25
239.9150391	0.37
241.1119080	0.72
243.1143341	0.36
244.3857880	0.12
245.2479401	0.77
247.2614288	0.76
247.8968201	0.42
249.2509766	0.55
250.0258026	0.56
251.1203156	0.64
251.9295654	0.12
253.1760101	1.01
254.0859985	0.07
255.2148285	0.39
256.2660522	0.20
257.2412720	0.32
258.5249329	0.42
259.3652039	0.52
260.3873901	0.15
261.2272644	0.95
263.2070923	2.08
264.1929932	0.62
265.2225037	0.85
267.1719971	0.58
268.9749756	1.00
270.1246948	0.28
271.2963867	1.10
271.9857178	0.11
273.3297119	0.13
274.1750793	0.25
275.1724548	1.29
276.3740234	0.32
277.3049316	0.81
279.2747192	1.15
280.3118591	0.21
281.3118286	1.53
282.2307129	0.13
283.2818604	0.56
284.1245117	0.06
285.1716614	0.25
286.3827209	0.39
287.3238525	1.96
289.2477417	1.50
290.3032837	0.19
291.2017517	0.79
292.9933167	0.65
295.3148499	0.91
297.2715759	0.51
298.3769531	0.10
299.1151733	0.39
300.3815918	0.28
301.1560059	0.40
303.0172729	0.48
304.6427612	0.18
305.2524109	1.91
306.1309509	0.34
307.1350403	0.70
309.2403564	0.55
310.2087097	0.70
311.9644775	0.08
313.1326904	0.66
315.1625977	2.58
316.3690186	0.06
317.1029053	0.69
319.2584839	0.68
321.3510132	1.08
322.8304443	1.29
323.5919495	0.29
324.2329712	0.41
325.1896362	0.38
326.9858398	0.30
329.2374878	2.27
330.1047363	0.11
331.3213806	1.30
333.2163086	4.24
334.3774414	0.04
335.3075256	1.17
336.8396301	0.54
337.5197754	0.49
339.3773193	1.10
341.2812500	1.21
343.2034302	0.40
344.7958984	0.76
345.4112549	1.41
347.2741699	2.73
349.2755127	1.09
351.3111572	2.06
355.2717896	0.80
357.2327271	2.43
359.3215332	0.86
360.0504150	0.46
361.4221802	0.40
362.3183594	0.13
363.2981567	1.18
364.0140991	0.11
365.3054810	1.27
367.0853882	0.79
369.3310547	0.70
370.2873535	0.04
371.3348999	0.25
373.2302246	3.00
375.1964111	2.96
376.0137939	0.23
377.0216064	1.60
377.6289062	0.08
378.2974854	0.08
379.4962158	0.32
381.2954102	0.50
383.1570435	1.31
385.1890259	0.32
386.5282593	0.15
387.3264160	0.78
389.1509399	0.28
391.2559204	2.72
393.2039795	4.04
395.3051147	0.92
397.2136841	0.27
399.2329712	0.81
401.0645142	1.01
405.4895630	0.74
407.3416138	1.22
409.3506470	2.74
411.1039429	0.87
414.7183838	0.14
415.6026001	0.63
416.2758789	0.09
417.0995483	1.03
419.2899170	3.56
420.1825562	0.05
421.0690918	0.12
422.3493652	0.07
423.4155273	0.48
425.3612061	0.13
426.1729126	0.47
427.3097534	0.39
428.2966919	0.10
431.2174683	0.58
433.3451538	0.36
435.1023560	1.12
437.0639038	1.61
439.2191162	0.03
440.1749878	0.16
441.1952515	0.36
443.4666138	0.25
444.4515381	0.27
445.5581055	0.05
446.3364868	0.52
448.6354370	0.22
450.5123901	0.39
451.3637695	1.02
453.3273926	2.56
455.2446899	0.78
457.4187622	0.17
458.5416870	0.23
459.5896606	0.28
460.4027100	0.13
461.2873535	0.97
462.4541626	0.26
464.5625000	0.08
465.3514404	0.34
466.5711670	0.11
471.2326660	0.10
472.3437500	0.16
473.5263062	0.11
474.3701782	0.75
475.3695068	0.65
477.2420654	2.30
478.3955688	0.12
479.3153076	0.84
480.4006348	0.28
483.2966309	0.86
485.0778809	0.39
485.9680786	0.08
488.3955688	0.06
490.6723633	0.66
491.3661499	0.14
492.6915894	0.56
493.5472412	0.15
495.1429443	3.97
495.8600464	0.03
497.3757324	2.29
498.4576416	0.18
500.4138794	0.83
501.4301147	0.60
503.2846680	1.12
504.6062622	0.08
508.2306519	0.09
509.0672607	0.04
511.2538452	1.96
512.2235107	0.15
513.2504272	1.26
514.0833740	0.16
515.0562744	0.10
516.5573120	0.19
518.3666992	2.19
519.3785400	1.06
521.3352051	1.02
524.7940063	0.26
526.3097534	0.84
527.0497437	0.06
530.4085693	0.09
532.4817505	0.04
534.1239014	0.14
536.3357544	0.13
537.1565552	0.39
539.1845093	1.34
542.3521118	0.96
543.5401611	0.33
544.2677612	1.25
545.3128052	0.42
546.3402100	0.08
548.6006470	0.14
549.4668579	0.07
550.4546509	0.84
551.3325806	0.15
552.1853638	0.07
553.2378540	0.49
554.2368774	0.06
555.1742554	0.60
557.2974243	10.33
558.5657349	0.19
560.3483887	3.16
561.1719360	0.11
562.2199097	1.61
563.0164795	0.04
564.7124023	0.08
568.4152222	0.34
571.2303467	1.38
573.0556641	0.17
575.1798706	0.14
576.4573364	0.94
577.3585815	0.08
578.3849487	5.57
579.4011841	0.92
580.4349976	0.74
581.2725220	0.10
586.4212036	2.03
588.3942261	0.31
594.2638550	1.08
595.7648315	0.90
596.4277344	5.24
599.2564087	1.24
604.3242798	2.78
605.4246216	0.58
612.3400269	1.55
613.4556885	0.27
614.6060791	0.38
617.1647949	1.70
618.4390259	0.16
620.4028320	0.22
622.2903442	10.77
623.4719849	0.40
625.0979614	0.25
626.2328491	0.28
630.9590454	0.12
634.2323608	0.17
634.9241333	0.12
636.3510132	0.72
638.2357788	1.57
640.2501221	100.00
640.9326172	0.34
646.1694946	0.04
649.4806519	0.39
651.4938965	0.18
654.2440796	1.09
655.0407104	0.25
656.3175659	16.77
658.3009644	0.55
659.2133789	0.14
664.2124634	1.64
672.4263306	0.42
682.3888550	9.17
690.4633789	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1979
Annotation	Cymorcin diglucoside
Peak:m/z	Relative Intensity
149.0185394	0.64
157.0245361	0.31
161.1371613	0.61
163.0182343	0.42
177.0037842	0.40
179.1671295	3.34
180.9104919	1.42
183.2176819	0.53
195.3307190	0.60
197.0526733	44.06
197.6717834	0.11
201.3213196	0.77
205.2477417	0.53
219.3039246	0.37
220.9836121	0.83
222.3211365	0.44
223.0912018	5.10
233.5811157	0.56
239.4717102	0.33
241.0824890	84.05
247.1324463	2.71
261.1005554	0.53
263.3205566	0.14
265.1130676	37.95
283.1937256	14.79
285.1092834	7.72
286.0445557	0.53
294.9829407	0.46
296.3011780	0.27
297.3145142	0.17
305.1597900	0.21
307.0206909	0.90
313.0714722	10.46
319.0480042	0.13
325.4571228	0.28
327.2661743	8.77
329.0693359	0.79
343.1959839	63.51
344.2789917	1.08
345.3167725	3.54
347.1712036	5.16
349.2691650	0.32
367.0888367	1.03
369.3144836	0.44
372.9707031	0.74
385.3052368	2.61
387.2216187	0.46
401.3653870	2.00
403.1914978	100.00
404.2930603	0.96
427.2946777	33.17
429.2376404	65.15
445.1833496	0.44
447.4116821	3.01
453.2303467	6.20
459.2458191	0.75
471.2519836	49.15
472.2922058	0.76
474.5558472	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	548.8517
Annotation	Unknow
Peak:m/z	Relative Intensity
174.9563141	1.28
214.8538818	0.10
230.9678650	0.11
244.8928528	0.29
249.0344086	0.03
261.0361328	0.07
289.0544434	9.50
304.9938965	20.84
402.9818115	0.24
404.0786743	0.20
418.9203491	33.00
432.9609375	0.11
434.8119507	100.00
435.4233398	0.30
460.0632324	0.03
475.1468506	0.28
476.9278564	0.06
491.0709839	0.07
501.8425903	0.20
502.9507446	0.13
504.1721191	0.09
531.0274048	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	429.2256
Annotation	Palliferin
Peak:m/z	Relative Intensity
121.0081482	0.27
133.0198517	0.59
134.9981232	0.43
137.1145630	0.18
139.1037292	0.21
140.8043213	0.05
145.1001282	0.55
146.6495056	0.93
147.2678833	0.03
149.1460266	1.50
150.9620667	0.26
152.9894104	0.10
155.1853638	0.78
156.9690857	0.06
158.9267883	0.63
161.0285645	1.08
163.0821381	0.59
164.7780457	0.05
165.7739868	0.08
169.0242462	0.30
170.9918213	1.08
173.0671692	0.78
175.0772400	1.00
177.3193665	0.07
178.8554382	0.12
183.0269775	0.44
185.0490265	3.07
187.1567688	0.99
188.2763977	0.18
191.2387390	0.28
193.1747742	0.78
195.1534729	0.24
197.0801086	0.80
199.0238953	0.75
201.0314941	1.15
203.0495911	1.20
205.1776581	0.13
207.1374512	0.10
209.1852875	1.24
210.8233948	0.41
211.4279633	0.22
213.3510742	1.53
214.0985413	0.10
215.1664124	0.90
216.1195068	0.24
219.2925415	0.65
221.0676727	0.06
223.1284637	0.63
224.9418945	0.28
227.0465393	1.24
229.2123413	1.24
231.2819366	0.13
233.1679077	0.76
235.0559998	0.24
237.0985107	1.14
238.1455383	0.28
239.0511169	1.53
241.1444702	0.11
243.1828003	0.69
245.2442932	1.37
247.2409058	0.14
249.2214661	0.56
251.0946045	1.93
253.2675171	1.78
255.1912231	1.08
257.0932007	1.33
259.2311096	0.82
260.1293030	0.40
260.8673706	0.36
263.2427673	3.94
265.1525574	1.00
267.2609253	1.41
269.2286987	1.16
270.9194031	0.83
275.0643005	0.50
277.3100586	3.83
279.1918335	4.87
280.0540771	0.64
281.1931763	5.56
283.3052368	1.83
284.0570679	0.37
285.1893311	1.08
287.2619019	0.77
289.1345215	0.79
291.1782837	1.33
293.0809631	1.01
295.1891479	3.60
297.2007141	2.82
298.3190918	0.12
299.2775879	1.29
300.1666260	0.24
301.3260498	0.49
303.1701660	0.36
305.3031006	11.58
305.9995728	0.11
307.1563721	1.01
309.4376221	0.59
311.0951233	0.71
312.0904236	0.20
313.3172607	0.53
315.2761230	1.77
317.1644897	0.62
319.3214722	0.07
321.4858093	0.04
323.2759399	15.19
324.8664551	1.61
325.6522827	0.08
327.2381592	0.53
329.2265625	0.76
331.2795105	0.50
333.3429565	3.66
335.2509155	3.48
336.3615417	0.39
337.3184204	1.35
339.1920471	1.50
341.1836548	14.10
343.4353027	0.57
346.2509460	0.51
347.2529297	1.56
349.2305603	1.24
351.2539978	4.56
353.3152771	2.22
355.2812500	0.57
357.2920532	0.45
361.3534241	0.44
365.3204041	2.14
367.2528381	3.20
369.2017822	19.92
369.8406372	0.09
371.2187195	0.42
375.2241821	5.01
378.1547546	0.15
383.0714722	4.31
385.2445679	2.13
387.1540222	0.16
393.2343140	16.93
398.4860229	0.33
399.5616150	0.17
401.1354675	1.03
411.1506348	100.00
411.9090271	1.50
412.5895386	0.37
413.5280457	0.13
414.2596741	0.18
414.9206238	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	533.172
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0201416	0.17
170.9928589	0.21
173.0221100	0.42
189.1098022	0.21
191.0086365	100.00
341.2708130	0.09
353.4710083	0.61
396.9692993	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
176.9211426	0.15
178.9549866	0.09
208.1521912	0.14
209.4131775	0.07
268.0221252	0.25
271.0002747	0.16
273.1480713	0.27
285.2466431	0.13
286.0365295	0.24
291.8909912	0.08
293.322876	0.42
301.1266479	15.37
303.2553711	0.21
309.420166	0.06
313.3183594	0.35
345.5821533	0.17
347.2297974	0.41
367.2677612	0.09
372.2299805	0.16
379.3948364	0.13
386.3747559	0.14
396.1812744	0.13
409.4002686	0.09
422.4380493	0.64
423.2894287	0.13
427.3303223	0.21
429.1109009	0.48
434.9240723	0.06
445.3327637	0.37
447.6221924	0.35
453.9298706	0.32
463.1210938	100.00
465.3745117	0.44
477.4584961	0.19
489.5471191	0.68
493.4677734	0.16
527.0292358	0.08
549.090271	0.25
552.4907837	0.40
553.5465698	0.42
564.1027832	0.20
565.1948242	0.74
566.0071411	0.06
569.7057495	0.39
573.3659058	0.68
587.0720825	0.48
591.2445679	2.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	724.2565
Annotation	Unknow
Peak:m/z	Relative Intensity
213.2422028	0.06
217.0405426	6.15
218.2475281	0.10
219.2617645	0.23
226.2067566	0.04
230.9646912	0.07
233.1010742	0.58
234.7916260	0.26
236.1007080	0.06
244.9195251	0.10
250.3231659	0.02
256.1975708	0.08
257.2963257	0.08
260.2915039	0.08
262.1594543	0.18
265.9014282	0.07
270.9067383	0.05
272.0330505	0.09
274.1303406	2.26
276.3242493	0.04
279.3350220	0.05
285.2707214	0.12
289.4492798	0.43
290.3109741	0.05
293.9746704	0.56
304.1043701	0.08
306.1293335	0.05
308.1289368	3.02
311.2020569	10.27
312.0403442	0.42
314.4672852	0.14
329.1507568	31.70
336.4288330	0.06
337.6316528	0.06
341.2360840	0.10
346.3401489	0.24
347.0261230	0.06
348.4675903	0.08
353.0919189	0.10
360.3963623	0.02
364.1749268	3.12
365.3457642	0.18
377.2342529	0.08
383.1807251	1.29
395.2387085	0.12
397.9564209	0.02
405.2180786	0.15
410.0996094	0.02
415.9851074	0.03
421.0944824	0.07
422.2553101	0.09
423.3242188	0.08
440.1824341	5.28
441.1412964	0.09
446.3720703	0.19
452.0587769	0.07
458.2105713	100.00
464.3315430	0.02
476.1247559	0.80
482.2329712	0.15
492.1179810	0.04
500.4375000	0.14
509.0471191	0.09
523.3515625	0.07
525.9396973	0.09
530.5742188	0.03
538.5084229	0.08
554.3530884	0.08
556.0676880	0.04
559.1530151	0.10
560.1172485	0.10
561.5687866	0.34
562.3182983	0.06
573.9335327	0.03
576.8737793	0.08
577.5154419	0.12
589.3660278	0.11
595.1613159	1.72
598.9813232	0.15
604.1301270	0.02
607.1336060	0.04
612.3240356	0.05
618.1038208	0.09
625.2300415	0.12
634.3522339	0.06
638.1647339	0.57
646.5086060	0.04
649.4465942	0.09
651.5291748	0.08
662.4624634	0.07
670.1505737	0.13
678.0725708	10.22
678.7627563	0.02
688.1223145	0.41
688.9734497	0.04
695.5454712	1.97
696.3458252	0.02
699.9564819	0.12
705.5846558	0.65
706.2647095	4.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.114
Annotation	3'-O-beta-Glucopyranosyl plumbagic acid
Peak:m/z	Relative Intensity
110.9941864	0.14
112.8609161	0.20
121.8877258	0.03
125.0153656	0.04
129.0432434	0.26
135.1858978	0.05
135.9701538	0.08
138.2328491	0.04
143.0595703	0.21
146.9756317	0.88
149.0294952	0.98
151.8656769	0.09
153.0316162	2.60
160.8552551	1.10
162.0477295	0.15
164.0840759	4.00
173.0385742	0.27
173.8268127	0.13
174.8557129	0.07
177.0362549	0.46
178.9576721	1.95
187.1315613	0.25
190.0246277	6.41
191.0520020	28.17
193.1715698	0.18
195.1047058	0.04
203.0805969	0.17
205.1186829	51.73
206.1017761	0.15
207.9998474	0.84
209.0900269	5.21
219.1593628	0.08
221.0529175	1.47
223.0068970	100.00
223.6138000	0.36
232.0581360	0.79
233.1828308	0.43
237.1935120	0.80
247.0082703	51.91
247.6255798	0.46
251.0549927	0.39
260.6080322	0.08
263.3731995	0.14
265.1369019	9.56
275.3858948	0.34
277.1574707	2.23
281.2122192	0.07
289.0960693	1.51
295.0089111	4.36
305.2315063	0.66
319.0957642	0.11
323.2304688	0.20
325.1480103	6.12
337.2123718	0.17
367.1267700	3.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	412.1744
Annotation	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
Peak:m/z	Relative Intensity
122.9704285	0.04
126.9537582	15.18
135.0904846	0.25
144.0076904	0.14
144.9732513	0.45
159.1716309	0.06
162.1867371	0.17
172.7087402	0.28
176.1887817	0.30
184.9977417	0.06
191.0340424	0.13
201.0086975	39.08
202.7606812	0.51
212.8572083	0.09
215.0906982	0.21
217.0480347	3.93
219.0234070	8.07
227.1560669	0.70
229.1492310	0.36
231.0270691	1.27
239.0981445	0.12
241.2398071	1.24
243.2456665	0.42
251.3022766	0.43
253.2783813	0.13
255.0099792	0.41
256.8881531	0.18
258.3247375	0.10
259.1752319	0.07
267.0331421	0.19
269.1596375	8.06
285.1562195	14.45
287.0358276	0.65
303.0860596	21.23
313.0103760	0.38
327.0072632	0.16
343.0831299	100.00
344.1277466	75.10
345.2770386	0.27
352.7821045	0.27
371.0581360	0.50
395.2709656	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Diosmin 
Peak:m/z	Relative Intensity
256.0018005	0.28
284.0328979	30.92
284.6764526	0.06
299.0617065	100.00
299.6824951	0.22
339.1607666	0.05
340.1156616	0.05
340.968811	0.22
383.3764038	0.03
401.2659912	0.14
445.6025391	0.05
563.0841064	0.40
592.2952271	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	651.4407
Annotation	Unknow
Peak:m/z	Relative Intensity
215.2281342	0.03
219.0656281	0.06
237.1010590	0.10
262.9940186	0.04
278.2536011	0.02
299.1884155	0.02
302.3201904	0.07
305.0747681	0.10
321.2725830	0.04
326.8686218	0.04
329.2855835	0.18
335.2189636	0.05
345.3618774	0.08
346.9273682	0.02
357.2961426	0.15
360.8346558	0.12
389.3544312	0.06
391.5168457	0.05
425.4026489	0.11
451.2351074	0.04
493.1235352	0.11
494.1389160	0.12
495.0878296	0.03
497.4954224	6.85
511.6916504	0.30
513.3119507	0.14
515.4286499	100.00
517.2617798	0.04
523.2005615	0.11
531.0110474	0.19
573.1668091	0.07
595.2713013	0.06
606.2415771	0.09
633.5183716	0.31
634.3395996	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	541.7301
Annotation	Unknow
Peak:m/z	Relative Intensity
153.0145569	0.05
162.9920807	0.07
177.0773163	0.05
191.3899231	0.03
192.9663391	0.20
201.7636566	0.04
217.1953583	0.03
219.1043701	0.09
220.9258728	0.02
243.2886047	0.02
261.4006653	0.10
269.3542480	0.02
276.4659424	0.04
277.1386719	0.03
281.5218506	0.02
299.1195068	0.04
304.3718262	0.14
316.2506714	0.04
318.1217041	0.29
327.2989502	0.06
328.1461182	0.03
329.0269165	0.30
338.6404419	0.06
363.2909546	0.03
385.9274292	0.34
387.1421509	0.05
388.6603394	0.03
390.2145386	0.23
398.4714355	0.04
403.7363281	0.02
405.7442017	0.25
412.6752930	0.08
426.4698486	0.17
441.0769043	0.13
449.8424683	0.12
453.1085205	1.96
453.8031006	0.36
454.6058960	0.17
457.7469482	0.10
458.7387085	0.02
467.3610229	0.08
467.9905396	0.14
472.7686768	0.13
484.1497192	0.06
489.1329956	0.06
493.5471802	0.05
496.0429077	0.15
497.7223511	0.05
498.3415527	0.21
501.1072998	0.32
505.6873169	0.08
510.3536987	0.26
511.2128906	0.07
512.3308105	0.16
514.0860596	0.03
521.1599731	100.00
522.2340698	0.65
523.2216187	1.27
524.7791748	0.32
526.0830078	0.19
526.8574829	0.26
527.5219727	0.15
541.4584351	1.72
542.1517944	0.38
560.1728516	0.18
562.1953735	0.04
576.7368774	0.20
713.2114868	0.53
714.0413818	0.78
754.9660034	0.42
768.9041138	0.68
806.7584229	0.07
878.6762085	0.05
904.9140015	3.34
906.0733032	0.83
941.0004272	0.05
941.8916016	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	647.2817
Annotation	Unknow
Peak:m/z	Relative Intensity
188.9179840	0.36
191.3909302	0.02
201.1620331	0.28
203.1702423	4.03
204.0332489	0.06
207.1804504	0.39
214.2989197	0.03
219.1445312	0.73
220.1867218	0.03
231.4373474	0.05
237.1443176	5.96
244.9693298	0.62
247.0830383	0.11
251.1934662	0.10
261.2710266	0.09
275.1702271	0.34
277.4506836	0.07
279.1109619	0.04
281.1224976	100.00
291.0263062	0.05
292.7683105	0.04
295.1293945	1.05
305.2026367	10.50
311.2554932	0.10
317.4827881	0.03
323.1885986	4.01
325.2165527	0.02
335.2651672	1.03
337.1191406	0.04
341.2406616	0.27
347.0716553	0.12
353.1498413	3.42
355.2863770	0.04
365.0291748	0.56
369.0171509	0.08
370.7881470	0.23
376.6487427	0.04
377.2708130	0.24
382.9844360	1.50
413.0785522	0.56
425.0025635	0.46
441.0256348	0.19
443.0183105	18.85
467.3052368	0.63
483.6132812	0.10
484.7490845	0.26
502.8186646	0.07
510.5363770	0.02
545.1448975	0.06
557.4555054	0.08
561.2956543	0.03
567.1215210	0.03
569.0487671	0.08
585.3436890	0.08
586.9459229	0.07
587.7427368	0.06
592.4255371	0.08
601.4032593	0.32
614.0545654	0.09
629.1068726	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.2471
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1334991	0.08
177.1105652	0.39
177.9920044	0.22
181.0836639	0.21
183.0999146	0.82
185.1946411	0.35
187.0525208	0.46
189.2879639	0.86
195.3814240	0.16
197.0499420	0.32
198.0075684	0.23
199.0679321	0.74
201.1861267	0.51
203.0497284	0.32
209.2385712	0.47
211.0653992	0.08
213.3269653	0.73
214.2844238	0.14
214.9158936	0.17
215.9503937	0.08
216.8807678	0.36
218.0191345	0.21
219.1763306	0.28
221.1244965	0.09
223.0597687	0.71
225.0576324	0.57
227.0254974	0.22
231.2817078	0.22
233.2580872	0.68
234.1542969	0.15
235.0283813	0.60
237.1998444	0.31
239.1877747	0.87
241.0918732	0.50
243.0207520	1.07
245.1724701	0.54
245.8777008	0.84
247.1855164	0.81
248.2454529	0.45
249.3020325	0.41
250.6535492	0.96
251.2950134	0.47
253.1611481	0.75
254.2120056	0.08
255.0262756	0.75
257.2601929	0.25
259.1221619	0.51
260.8544922	0.64
261.5191956	0.22
262.7803650	0.45
263.4761963	0.35
265.1650696	0.59
266.2954102	0.24
267.2321777	0.66
267.9764404	0.50
269.1644287	3.41
271.3141785	0.51
273.3045654	0.70
277.2356873	0.79
279.1268921	1.01
281.1557312	0.84
283.1576233	0.85
284.0558472	0.18
285.0331421	0.69
287.0511475	1.15
288.2901306	0.04
289.1611328	2.42
289.9714050	0.07
291.5513916	0.37
293.1897583	1.02
295.1614990	1.07
296.1051636	0.22
297.3079224	0.66
298.7201538	0.09
301.1909180	0.71
302.5087585	0.33
303.2754517	0.48
305.2197876	1.32
306.3717346	0.39
307.0904846	0.52
309.1727905	1.08
311.3476562	0.18
312.4082031	0.11
313.3240967	1.48
314.2286377	0.08
315.3439331	0.66
317.0420532	6.39
318.3463135	0.65
319.4265137	0.44
321.2061768	1.04
323.2766724	4.96
325.2844849	0.69
327.3668213	0.67
328.2995300	0.31
329.2468872	0.23
329.9568787	0.21
331.0791016	2.71
332.3700562	0.22
333.2199707	0.71
335.2255859	1.42
337.1818848	0.40
339.3394775	0.74
340.1448364	0.09
341.2473755	1.29
342.0781860	0.08
342.9995117	0.62
345.1636963	1.32
346.2438354	0.19
347.3944092	1.18
349.2268677	1.29
350.2993164	0.06
351.1968384	1.76
352.2130127	0.19
353.4880371	0.88
357.4878540	1.34
359.2962036	1.16
360.4544678	0.47
361.4046631	0.28
362.3041992	0.26
363.2127075	0.84
365.2095947	0.28
367.1070557	0.47
368.2048340	0.22
369.2662964	0.72
371.1390991	1.61
372.3548584	1.03
373.2147217	2.15
374.2751465	1.12
375.1221313	2.15
377.3212280	2.14
378.2647095	0.23
379.1323242	0.80
380.1242676	0.10
381.4419556	0.99
383.2020874	0.24
385.1282349	1.56
386.3682861	0.61
387.3414307	1.83
389.3616943	1.32
390.7191162	0.50
391.3475342	2.90
392.3254395	0.87
393.2745361	1.47
395.3422852	1.68
397.2016602	0.99
399.0388184	2.00
401.1503906	1.92
403.3205566	0.80
404.2228394	0.04
405.2341309	1.79
407.4845581	0.22
408.1636963	0.51
409.3987427	1.07
410.4437256	0.28
411.2861328	0.54
413.1614990	0.84
415.1283569	1.71
417.1451416	1.57
418.4510498	0.31
419.2185669	1.90
420.0215454	0.03
421.0398560	1.76
421.7039185	0.15
423.3704224	1.85
425.3104858	1.43
427.3588257	0.41
429.2817993	2.01
430.7029419	1.63
431.4469604	0.76
432.0664062	0.15
433.1119995	1.57
435.2662354	2.62
436.2618408	0.21
437.3808594	2.47
439.3452148	2.86
441.1552124	2.74
443.2961426	0.77
443.9413452	0.71
445.2227783	0.46
447.2407227	2.92
449.1755981	0.82
451.0679932	1.97
453.1946411	3.33
454.8301392	1.51
455.4792480	1.16
457.1669312	2.82
459.2507324	3.19
460.9818726	1.00
463.3688965	1.06
465.2781982	1.52
467.3275757	1.34
469.2687378	0.54
471.3816528	1.79
472.2036743	0.37
473.3038330	2.12
475.2492676	2.13
477.2143555	0.69
479.2078247	0.38
481.2087402	3.85
483.2703857	11.76
485.3329468	1.47
489.2150269	1.72
490.2305298	0.36
491.2076416	0.32
493.1688232	0.50
495.0661011	0.73
497.3707886	0.90
499.3322754	10.86
501.3289185	28.95
503.2973022	1.08
505.4608765	0.28
507.4171143	0.64
509.2567139	5.25
511.1656494	0.25
513.2691040	0.49
514.1577759	0.36
515.3212280	0.41
517.1815796	20.50
519.2651978	17.08
520.2359009	0.05
521.0654907	0.53
525.4456787	0.23
527.2142944	13.05
535.1799927	3.04
535.8413696	0.04
537.1000977	0.15
543.5010986	0.71
545.1996460	22.11
548.1826782	1.95
549.0682983	0.34
549.8091431	0.12
555.4146729	0.14
559.1959229	4.55
559.8779907	0.46
561.1126099	5.18
563.2666016	100.00
564.2628784	0.44
565.2238159	0.34
577.2199097	44.58
579.2487183	5.87
581.1493530	3.75
587.3475952	3.84
595.2362061	2.16
601.0698853	0.24
605.1121216	16.50
605.8411255	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.3149
Annotation	14(15)-EET-d11
Peak:m/z	Relative Intensity
95.13493347	0.22
100.9526215	0.06
104.920578	0.14
107.3896103	0.24
108.9800415	0.14
110.9372864	0.49
117.0739975	0.05
119.0789948	0.14
120.8545837	0.15
121.9504318	0.12
122.9863892	0.27
124.9320755	0.16
126.8515472	0.15
132.8421326	0.04
135.0815887	0.53
136.9672089	0.67
139.1188812	0.08
143.1143799	0.06
149.0195312	0.16
150.9519806	0.31
153.949707	0.06
155.1040039	0.34
163.3154602	0.07
165.287262	0.06
167.094986	0.06
169.1145782	0.17
170.3083038	0.09
172.1828613	0.23
176.993103	0.06
179.0255432	0.11
183.0543213	0.64
185.2174683	0.15
187.0784149	0.22
191.3816833	0.29
192.6912842	0.16
193.2985229	0.08
197.3995056	0.02
198.9470978	0.13
205.1539764	0.13
206.1385651	0.04
207.3165741	0.25
211.2191162	0.10
213.2895203	0.04
217.1469421	0.09
218.8823853	0.04
220.3467407	0.12
223.3085938	0.42
225.2521667	0.33
227.2037048	0.20
229.2964478	0.16
231.0949707	0.04
234.2352295	0.05
235.2988281	0.07
237.3457336	0.09
239.23172	0.13
240.2590637	0.14
243.3727722	0.03
246.0946655	0.27
247.3236084	0.06
248.1885071	0.07
249.2852783	0.05
252.3996887	0.13
253.3079834	0.03
254.7203674	0.12
255.5067139	0.14
261.1930237	0.15
263.894043	0.09
265.045105	0.23
266.1904297	0.87
267.367981	0.17
268.2658081	0.15
269.0266418	0.36
270.393158	0.21
272.2217102	0.25
273.1591797	0.20
278.3355713	1.50
279.3956299	3.95
282.9763794	0.94
284.4501953	1.45
285.123291	0.15
286.3450928	0.40
287.1960754	0.09
289.5316162	0.04
290.1882935	0.08
291.2600403	0.22
296.28125	40.32
297.1584473	0.36
300.1628113	0.06
300.9404907	0.40
302.5844116	0.07
303.2348022	0.17
304.2581177	0.15
311.9382935	0.06
314.2976379	100.00
315.1394348	1.79
317.1793213	0.26
318.2045898	0.56
322.8407593	0.20
332.242981	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	531.1143
Annotation	6,7,3',4'-Tetrahydroxyaurone 6-(4'',6''-diacetylglucoside)
Peak:m/z	Relative Intensity
149.0549927	0.10
159.1234741	0.46
160.9984436	0.54
163.0248871	3.10
172.9092712	12.74
175.1020050	0.33
178.1879883	0.20
187.1277161	0.87
191.1021271	9.72
193.0145874	5.92
203.1136322	0.31
207.3603516	0.16
216.9930420	0.22
224.0250397	0.11
225.1866150	1.03
226.3916931	0.16
230.8233490	0.10
256.9391174	0.44
261.1925659	0.96
274.6242676	0.09
279.2238159	0.09
293.1914062	3.56
305.3043518	0.19
318.8037109	0.13
323.1669922	6.20
337.0603638	78.37
349.1276245	1.12
355.0402222	5.10
367.1337280	100.00
368.2424316	0.30
369.1760254	1.00
385.1193237	17.39
387.2680664	0.52
417.2448730	0.11
429.1925659	1.55
431.3290405	0.21
451.3076782	0.26
468.8374023	0.40
485.1455688	3.41
486.9688721	0.86
489.2847290	0.31
512.9910278	1.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	655.1851
Annotation	Malvin
Peak:m/z	Relative Intensity
182.9639893	0.05
247.9301605	0.10
282.0164795	0.16
312.9709473	0.38
314.0532837	0.18
317.1525879	0.21
332.2062378	0.21
347.1029053	100.00
347.8098755	0.34
349.1727905	0.49
363.2112427	0.07
380.1184692	0.07
412.9122314	0.10
425.3527222	0.04
427.0999146	0.59
445.4485474	0.14
489.4320068	0.06
492.7829590	2.24
508.8684082	15.91
509.5338135	0.13
525.4721069	0.09
532.7059937	0.04
576.8126831	0.08
593.4125366	0.06
595.5647583	0.09
597.0218506	0.20
601.3383179	0.04
622.0582886	0.35
637.0681152	0.23
638.4857788	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	553.1541
Annotation	Clitoriacetal 11-O-glucoside
Peak:m/z	Relative Intensity
163.2818756	0.01
287.0050049	0.03
303.2157593	0.01
304.2291260	0.01
305.2127991	0.01
309.5832520	0.06
346.5206299	0.01
361.2027588	0.03
363.1038818	0.02
376.4513550	0.07
385.2883911	0.04
391.1409912	100.00
391.7576904	0.21
463.7432861	0.05
464.3567505	0.03
473.4684448	0.10
476.7027588	0.05
499.6497192	0.02
516.9962158	0.03
517.9966431	0.06
534.0050049	0.09
535.0217896	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	182.0806
Annotation	Unknow
Peak:m/z	Relative Intensity
118.9580383	0.02
135.9705963	26.48
139.7203217	0.11
140.4626312	0.03
146.8027039	0.07
165.0400543	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.1223
Annotation	8-C-Glucopyranosyleriodictylol
Peak:m/z	Relative Intensity
129.0887909	0.09
149.2135620	0.07
153.0038300	0.06
157.2230835	0.06
158.1208344	0.12
163.1012268	0.23
167.0953979	0.15
185.2136383	0.04
187.0706177	0.17
202.9320068	0.13
205.1473541	0.16
210.3270874	0.03
225.2344513	0.04
227.2986145	0.13
228.5314636	0.04
230.8837891	0.03
233.1959381	0.19
235.1394958	0.03
240.2028198	0.02
245.0597229	0.12
249.0503540	0.04
250.2106323	0.14
252.0176697	0.13
254.0713806	0.04
265.5586548	0.06
270.8413696	0.11
273.0860291	0.09
275.1307678	0.03
287.2041626	0.33
289.1309814	100.00
290.1402893	0.11
292.4260864	0.04
296.9841919	0.03
302.1779175	0.06
307.0628357	0.22
309.2124634	0.13
310.8359985	0.20
313.1426392	0.27
314.2523193	0.08
315.2493286	0.08
325.2666931	0.07
329.5080261	0.02
331.0483398	2.36
336.2070923	0.03
337.5510254	0.04
343.1099243	0.39
348.3378296	0.10
349.1578064	0.18
355.1602173	0.95
360.5889587	0.10
362.4840393	0.05
363.8397217	0.02
364.9559937	0.18
370.6349487	0.02
375.1839294	0.09
377.1431885	0.25
378.1352234	0.04
379.4516296	0.08
383.1402588	0.09
384.0277100	0.03
385.1961365	1.00
387.0226746	0.10
391.0575867	0.02
397.1040344	2.24
397.8498840	0.04
402.4036865	0.13
404.9881592	0.02
410.0620422	0.56
411.1218567	0.02
415.0158691	2.36
415.8844910	0.07
427.6477966	0.09
433.0473328	13.03
434.1036682	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	671.1791
Annotation	Limocitrin 3,7-diglucoside
Peak:m/z	Relative Intensity
203.1353455	0.18
243.5805969	0.11
249.0894928	0.13
250.9147034	0.10
271.8843689	0.05
302.4088745	0.29
312.6492920	0.08
314.1693420	0.07
316.5438232	0.04
318.1680298	0.04
318.9035034	0.23
323.1841125	0.16
327.4368896	0.15
332.2455444	1.08
338.3360596	0.12
347.0916138	81.33
347.6983032	0.64
357.3945923	0.17
359.0092773	0.13
364.9586792	0.14
382.8360596	0.23
389.2233276	0.69
405.2472534	0.24
443.3330688	0.22
457.1225586	0.15
460.5203857	0.18
463.2655640	0.13
465.2382202	0.15
468.5650635	0.12
470.7171631	0.25
473.0997314	0.27
491.0864258	0.37
495.1671753	0.18
498.1181641	0.53
500.3090210	0.14
501.4308472	0.07
509.0375366	100.00
509.6760864	0.28
519.4324341	0.25
522.9350586	0.07
529.4557495	0.46
533.0462036	0.04
537.4190063	0.05
540.2699585	0.13
556.0462036	0.22
561.3486938	0.16
562.9895020	0.09
563.5912476	0.54
576.4603882	0.17
581.0973511	0.11
584.8449097	0.42
592.7420654	0.14
594.0512085	0.44
604.4863892	0.80
607.1160278	0.41
610.1367798	0.12
611.0699463	0.16
612.3174438	0.07
628.4021606	0.21
630.8748779	0.07
632.0684204	0.10
635.2755127	0.16
652.3257446	0.31
653.0669556	0.31
659.1183472	0.51
661.8631592	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	679.2609
Annotation	Briaranolide B
Peak:m/z	Relative Intensity
224.8359833	0.04
229.1613464	0.90
271.1633911	0.04
273.3990784	0.05
289.3568726	0.12
311.2067261	0.01
318.8375244	0.05
325.3169861	0.48
335.9196777	0.06
339.4803772	0.02
341.2485352	0.08
341.8802490	0.04
351.2241211	0.04
370.9512329	0.08
372.4258423	0.05
373.1522827	0.01
382.9656372	0.01
423.4309082	0.09
425.4151001	0.10
427.2313843	0.06
435.3348999	0.04
450.5996704	0.17
451.4545898	0.03
471.2937012	100.00
475.5650024	0.02
481.2617798	0.03
485.2702026	1.90
491.0980835	0.13
493.5522461	0.10
495.1528320	11.24
495.7531738	0.03
497.4241333	0.10
499.4231567	0.12
513.1826782	17.41
516.6570435	0.13
517.4104004	0.40
521.1643066	0.08
522.0741577	0.06
524.1133423	0.05
525.2059326	5.52
533.1428833	0.06
534.6389160	0.48
535.3207397	1.08
537.2220459	0.26
543.0990601	5.51
555.2205200	0.26
561.0745239	0.35
567.3738403	0.04
570.0046997	0.02
570.6989136	0.09
572.8968506	4.50
575.7501831	0.07
579.2250977	0.08
585.2693481	0.16
593.6721191	0.02
603.3353271	0.17
614.8406982	0.46
615.5395508	0.01
621.3991699	0.21
628.9287109	0.03
632.3373413	1.42
632.9620972	17.17
633.6703491	0.01
635.1035767	0.22
647.1134033	0.12
649.2659302	0.04
661.5171509	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	845.2311
Annotation	Unknow
Peak:m/z	Relative Intensity
244.9516144	0.35
260.1391907	0.23
271.1895142	0.23
276.1877441	0.16
286.2674561	0.29
287.0429688	0.53
287.8404846	0.32
291.0714722	0.30
309.3358459	0.08
313.2791748	0.41
315.3858643	0.28
316.2553711	0.36
317.0955200	0.63
319.1266785	6.62
322.3109741	0.27
343.4116821	0.29
344.2214050	3.48
347.0824890	5.08
353.4575195	0.08
355.2593994	0.26
362.1712036	7.64
374.1846313	0.12
377.1770630	100.00
378.0251770	0.23
395.1196289	0.07
397.6222534	0.46
423.5377808	0.48
425.1646729	0.14
426.2976685	0.08
433.0040283	0.39
435.0823975	0.12
449.2712402	0.43
450.5266113	0.54
451.2152100	0.32
456.2403564	0.21
468.2083740	0.09
474.8957520	0.47
489.4082031	0.41
491.2725830	0.16
493.2021484	0.35
496.9810181	0.11
513.3635864	0.12
522.1812134	0.26
550.3603516	0.06
553.4833374	0.52
556.4841919	0.10
563.3945923	0.06
577.4791870	0.06
607.5721436	0.23
609.5758057	0.22
611.4060059	0.16
615.4115601	0.10
622.8601074	0.18
627.1325073	0.35
634.0225220	0.07
647.3497314	0.11
648.1234131	0.15
650.3184204	0.40
654.2159424	0.31
655.5109863	0.29
663.2474976	0.36
680.3446045	0.70
681.4546509	0.43
682.2665405	0.32
683.3290405	0.45
687.3977661	0.22
691.5762329	0.31
705.3546753	0.07
723.1750488	0.32
742.1763916	0.21
754.8622437	0.26
761.2612305	0.13
764.6764526	0.11
774.4855347	0.33
783.4033813	0.17
791.1480103	1.27
797.2472534	0.11
800.2356567	0.20
801.5831299	0.13
808.8005981	1.42
812.2886353	2.11
813.5247192	0.16
815.1702881	0.22
826.9297485	32.11
827.6043091	0.41
828.7571411	0.32
829.8527222	0.39
831.3817749	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	527.2108
Annotation	Abelioside A
Peak:m/z	Relative Intensity
149.0187225	0.34
151.2430573	0.42
151.9391022	0.16
155.1499329	0.07
157.0035858	0.26
159.1733704	0.37
161.0787964	0.97
163.0131531	3.01
164.7243652	0.33
167.1260376	0.72
168.4077454	0.47
169.2186584	0.18
171.1196442	0.47
172.6278534	0.06
175.1520996	0.43
179.0399170	0.36
180.6513367	0.31
181.2589874	0.33
182.4180908	0.07
183.1555481	0.20
185.0673218	1.91
187.1331482	0.38
188.8968506	0.57
191.0277100	0.59
193.2057800	0.29
194.9035492	0.21
197.1278534	1.34
200.9766235	2.44
203.1482544	0.28
205.0985107	0.90
207.1204529	1.69
213.0117645	0.36
215.2148743	3.83
217.1753540	0.06
219.1798401	2.54
221.2462463	0.14
223.0777588	0.11
225.2065277	3.88
230.9714050	0.85
233.2443390	0.15
239.1221924	0.09
241.1378479	0.06
243.0873413	33.51
248.8234558	0.08
251.0756073	0.07
253.0717773	0.22
261.1098938	39.49
267.2975159	0.07
269.0078125	0.05
270.7640381	0.07
273.2135620	0.62
279.0526733	3.08
283.0644226	0.07
285.1912842	0.88
286.9502563	0.34
295.3251953	0.60
297.0238037	0.09
301.2440186	0.07
303.0733643	1.06
306.8767700	0.34
311.4029541	0.13
317.2813110	0.06
321.2991943	2.45
329.1777954	3.59
333.1593018	1.12
335.2116089	0.36
339.1061401	0.43
347.1295776	18.73
348.3718262	0.14
358.8785400	0.14
361.0426636	0.19
363.0220947	0.50
365.1934204	39.61
375.0802002	0.67
381.5389404	0.11
383.2246094	27.25
387.1826172	0.55
389.1289062	1.69
393.1164551	0.10
395.5905762	0.11
401.2383423	0.09
405.4642334	0.86
406.9972534	6.03
407.6568604	0.05
423.0311279	0.77
425.2069092	100.00
427.2328491	0.08
441.2202148	0.21
447.3457031	1.10
465.2106934	1.39
467.3558350	0.12
473.0062256	1.47
473.6401978	0.40
482.2640991	0.25
483.3392944	0.47
491.1838989	20.81
509.1630249	33.74
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	827.2198
Annotation	Unknow
Peak:m/z	Relative Intensity
245.2311554	0.07
271.1385193	0.06
273.1979675	0.06
284.9468384	0.06
287.0207214	0.10
288.6314087	1.28
290.2207031	0.06
291.0645447	0.21
299.1275635	0.08
301.0523682	0.06
305.8460999	0.24
307.1717529	0.46
316.1468811	0.33
319.1570435	6.74
329.9039307	0.15
331.1934814	0.15
333.2953491	0.08
344.1995850	3.73
345.1179199	0.24
347.1707764	6.34
362.0603027	3.88
377.0825195	100.00
415.0296631	0.23
431.3056030	0.26
435.1489258	0.12
464.9072266	0.20
467.2127075	0.32
511.4821167	0.04
557.3325195	0.05
611.3872681	0.13
623.0398560	0.22
629.0741577	0.23
631.0507812	0.31
639.3645630	0.12
646.3305054	0.27
661.2773438	0.21
664.3707886	0.09
665.5137329	0.26
681.3494263	0.09
682.9219360	0.11
693.3477173	0.12
701.6079102	0.06
725.9594727	0.75
747.2199097	0.27
749.4121704	0.17
773.2061768	0.08
791.1372681	0.43
799.1954956	0.12
809.2321777	0.72
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2184
Annotation	Unknow
Peak:m/z	Relative Intensity
211.2538605	0.54
215.3863525	0.26
216.2296448	0.13
217.1879883	0.38
219.0440216	0.87
223.0826416	0.10
224.0461731	0.52
227.0756531	0.25
229.1313782	0.24
230.9686890	0.21
232.1088562	0.09
232.9010773	0.11
240.9157257	0.17
242.1979523	0.69
243.2623596	0.18
247.0775757	3.09
249.1707611	1.22
256.9995728	0.31
258.1308899	0.07
259.3486328	0.08
261.1170044	0.36
265.0938416	0.14
268.1335754	0.41
272.7508850	0.05
277.1068115	0.43
283.2866821	0.14
285.0230713	0.32
286.0318604	1.10
289.0668335	0.42
291.1262207	7.23
301.0755920	49.08
303.1391602	0.07
307.1557617	0.40
309.1654053	7.42
325.1822510	1.56
343.1057129	0.07
347.1647034	0.08
351.1477051	100.00
351.7524109	0.15
355.4679565	0.17
357.4094849	0.05
364.8007812	0.12
367.2301636	3.77
373.1430664	1.08
375.1506348	4.62
380.9317627	0.36
381.5762939	0.15
393.2367554	10.04
411.3190308	0.17
417.1514893	2.13
434.7101440	0.99
435.3211060	0.29
445.0667114	0.74
446.8809204	0.86
453.2375488	89.97
465.1361084	0.28
489.1877441	0.06
503.3590698	0.09
579.4172363	0.09
588.9813843	0.20
591.1970215	0.44
593.3301392	0.07
609.3167114	46.73
629.3469238	0.24
674.7416992	0.13
711.7750244	0.10
737.3276978	0.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.2054
Annotation	Terretonin A
Peak:m/z	Relative Intensity
129.1033173	0.67
131.0107422	0.37
133.1177826	2.33
137.0491943	2.07
141.1642761	0.17
145.0792389	0.53
146.9253998	3.12
149.0770111	1.99
151.2496490	1.01
154.0182190	0.61
155.1121826	0.50
158.2058105	0.24
159.2423706	3.64
160.9989624	9.22
163.0478210	3.26
169.0582123	0.26
171.0229492	0.30
173.0722656	0.73
175.0907898	9.93
176.9662781	0.88
179.1896362	0.64
181.1965332	0.38
183.2576294	1.94
185.0353699	3.70
187.0351868	4.28
189.0500488	3.96
191.1088867	1.82
192.9192810	0.99
195.2050781	0.38
197.1785126	1.86
199.2181549	0.47
200.8953247	1.87
203.1595612	2.95
205.3503418	0.52
206.8783112	1.25
208.9585724	1.92
211.2316437	1.10
213.1103821	16.97
215.1712036	50.21
216.6497803	2.92
217.2735901	2.19
219.1513824	0.71
222.6276398	1.34
223.2982941	0.70
224.8826599	0.66
227.2017670	3.63
228.2423706	0.61
229.0745544	1.10
231.0806580	2.09
233.2533264	0.48
235.3492279	0.63
237.1914520	3.05
239.2841339	1.68
241.1307678	5.85
243.1547546	3.07
245.2612000	0.88
247.1676331	0.40
249.1698914	1.15
251.0179443	1.98
251.8840942	0.22
253.3876343	2.65
255.1564636	2.08
257.1309204	1.50
258.1362000	0.46
259.1991882	0.53
261.0083008	0.65
263.1083374	0.60
267.3572083	2.12
269.1178284	8.83
271.0562439	5.44
273.2830505	1.58
277.0200195	0.17
278.8580627	1.31
279.8661499	0.31
281.0971985	3.26
283.2030945	5.30
285.2607422	1.33
286.0196533	0.27
287.1145020	1.25
289.2578430	3.84
291.4155884	1.65
293.2428284	0.47
295.2531433	2.94
297.1472473	3.45
299.3012390	2.15
303.4017944	2.10
305.2380371	1.05
307.2963257	2.76
309.4138184	1.72
311.1473389	1.10
315.3014832	5.92
319.2678223	0.29
321.3863525	4.03
323.1783752	6.12
324.5331116	1.86
325.1643066	3.94
327.1345215	2.56
329.2900391	2.13
331.1215820	2.98
333.2505798	7.29
335.2033691	2.45
337.1592407	3.30
339.0447083	3.19
341.3190918	3.53
342.0239258	0.29
343.3484802	1.61
345.1365662	2.17
347.2172546	4.89
349.3991394	4.38
351.2556763	5.41
353.5102539	2.06
355.0737305	1.22
357.1777344	1.08
359.3802795	0.67
361.2106934	0.92
362.3799438	0.16
363.2181702	1.26
365.2601013	5.86
367.2411804	3.98
369.3031006	0.71
373.2751160	5.46
375.2118225	12.83
376.2406616	1.46
377.1540222	9.23
379.2857361	0.90
381.2536621	6.99
382.9346008	0.58
383.5805359	0.96
388.0562439	0.39
391.2268372	8.48
393.3455505	85.80
395.3461914	4.66
397.3194275	1.38
401.2938232	4.57
409.3047180	25.76
411.2447205	100.00
413.3302002	1.38
418.7168579	0.98
419.3267517	13.41
425.6172180	0.29
427.1573486	1.79
437.3285828	41.52
438.3555908	0.59
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.0855
Annotation	BL V
Peak:m/z	Relative Intensity
119.1915054	0.39
132.8310699	0.03
144.8901215	0.26
147.0328674	100.00
148.0587311	0.48
149.3977051	0.11
165.2741394	0.25
177.0468750	0.94
193.4592896	0.23
202.0846710	0.32
203.2799530	0.08
207.6194611	0.50
208.8319397	0.17
219.2708435	0.23
220.0784912	0.21
225.3234711	0.08
227.2373352	0.07
231.2181549	0.28
233.0696564	2.86
243.4127197	0.06
258.3308105	0.12
261.0477600	4.30
262.3450928	0.19
263.4128113	0.43
267.1809082	0.19
269.2378235	0.10
271.1586304	0.08
275.0125427	1.09
279.1661072	0.16
283.1817017	0.07
285.4107666	0.11
288.7116699	0.07
296.5023804	0.22
297.5352783	0.10
299.3613892	0.49
303.1862793	1.21
310.8853760	0.04
313.0352478	0.17
317.5866699	0.03
318.4244385	0.17
322.1404419	0.21
325.2187805	0.08
330.4382935	0.34
335.0140686	0.45
339.3036194	0.05
348.3744812	0.27
350.1880798	0.23
357.0608521	0.05
364.9936523	0.13
377.0094910	0.06
379.2345276	0.87
381.2451172	0.39
383.2495422	1.73
393.1235046	0.49
397.0639648	0.14
406.4582825	0.28
407.3165588	1.96
408.3952332	0.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.182
Annotation	Hesperidin
Peak:m/z	Relative Intensity
172.9365845	0.03
174.1176605	0.16
176.0624695	0.01
183.0297241	0.01
184.0798492	0.01
184.9259033	0.15
186.5961456	0.07
188.0679932	0.12
189.2375488	0.04
195.217804	0.02
197.9906921	0.01
199.0645752	1.14
200.2531586	0.15
201.134552	0.41
202.1510315	0.12
210.8948364	0.03
212.0525665	0.07
213.1894379	0.08
213.9829407	0.12
215.0668182	0.58
216.9253387	0.12
224.0597839	0.28
225.2475433	0.05
226.9382324	0.64
229.0116882	0.02
230.0631714	0.07
233.0953369	0.07
239.0624237	0.11
240.1639252	0.41
241.0753021	0.51
242.1316071	1.68
243.0078125	0.05
255.0370178	0.06
257.2160034	0.88
258.1603394	0.52
259.2269897	0.03
265.5681152	0.04
268.0134583	0.45
270.9782104	0.02
272.2766724	0.02
283.1291504	0.86
284.2156982	0.52
285.1008606	0.37
286.1618652	2.45
297.1946106	0.03
299.1803589	1.70
301.0810547	100.00
302.0704956	0.03
307.6463318	0.03
310.1739807	0.05
325.1435547	1.18
327.2306519	0.05
331.4295044	0.02
339.7182007	0.05
343.2556763	0.27
355.2215576	0.01
366.8227539	0.03
367.4359741	0.09
373.0554199	0.01
385.1873169	0.01
409.4237061	0.02
433.1536865	0.28
444.2672119	0.04
453.7674561	0.01
464.6768799	0.06
477.4475098	0.02
487.2315063	0.03
489.1575928	0.12
507.5899048	0.07
519.562561	0.07
542.1387329	0.08
565.2863159	0.02
573.2597046	0.02
576.9555054	0.01
591.2084351	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	577.1031
Annotation	Unknow
Peak:m/z	Relative Intensity
185.0260315	0.03
187.3370667	0.10
197.8848572	0.03
216.1593475	0.05
216.8726959	0.03
244.9959259	0.04
246.0653381	0.05
248.1480408	0.05
251.1334229	0.06
259.9210815	0.06
260.8649292	0.05
269.2702026	0.06
272.0105286	0.07
276.1023560	0.08
277.2991333	0.77
278.0261230	0.02
278.6882935	0.04
287.0692139	0.29
288.1401367	0.02
288.9920654	0.07
291.1605835	0.10
292.8884888	0.02
294.1099548	0.15
295.0919800	0.13
299.9761353	0.03
306.8578491	0.61
310.6166992	0.03
315.1614990	0.03
316.2329102	0.07
328.6887207	0.02
336.8944092	0.26
338.1041870	0.13
339.0833130	0.17
342.9280396	0.03
351.1176758	0.04
351.9990845	0.85
353.1505737	16.46
355.1741943	0.18
360.0383911	0.11
366.9147949	0.14
368.8536987	0.06
377.8553467	0.27
378.5762329	0.34
379.3466797	0.02
382.4201660	0.02
384.9761963	0.02
396.9738770	7.73
406.8222656	0.14
412.2037354	0.08
413.0591431	0.05
413.9558105	0.13
415.0073853	1.13
416.3301392	0.01
421.0786133	0.10
422.0102539	0.16
425.1650391	0.05
426.3626099	0.18
427.1510010	0.16
428.0560913	0.28
429.2119751	0.22
430.8009033	0.04
436.4899902	0.06
438.1273193	0.24
439.1397095	0.85
441.2497559	0.17
443.3485718	0.06
444.2734985	0.24
445.2668457	0.16
456.8877563	0.04
458.8251953	0.11
469.5382690	0.04
470.9138184	0.08
472.3166504	0.08
483.1018066	0.02
486.8270264	0.20
491.1712036	0.02
497.1483765	0.08
499.2342529	0.14
501.8635864	0.09
503.8952637	0.01
504.7492065	0.06
512.8360596	0.06
514.9355469	0.71
517.0427246	0.13
519.1309814	0.03
522.8451538	0.03
531.0203247	0.09
533.0908203	0.11
541.0546265	0.27
547.0648193	0.05
559.0131226	100.00
559.7031860	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.2085
Annotation	Unknow
Peak:m/z	Relative Intensity
220.7693176	0.12
237.1591492	0.06
265.1126099	100.00
341.1363525	0.66
385.1820679	0.12
417.1718140	0.06
424.8698730	0.08
463.2172852	0.20
481.4284668	0.25
501.0209351	0.11
509.3493042	0.04
515.5711670	0.12
543.0464478	0.03
563.2537231	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	424.1225
Annotation	Unknow
Peak:m/z	Relative Intensity
133.1470947	0.17
136.0358582	5.14
144.9134369	0.10
154.0090485	11.45
186.3630066	0.10
189.0899658	0.38
196.0804443	0.71
198.2430573	0.15
217.0906525	0.18
225.9774780	0.22
235.1370544	0.57
238.1995850	0.16
240.0166626	0.14
245.9715271	0.07
256.1302490	8.68
262.0415344	0.48
277.0581970	0.53
280.0842896	100.00
280.9548950	0.05
282.9406128	0.14
292.1560059	0.03
295.2586365	0.05
296.6158142	0.09
298.1093750	57.89
301.3273926	0.09
303.1557312	0.06
303.8440552	0.04
321.9669495	0.06
342.1965637	0.02
348.7515869	0.06
352.0401917	0.12
359.1940918	0.41
360.8042297	0.04
364.3212280	0.06
370.2194214	0.95
370.8424988	0.05
377.6946106	0.09
379.9045105	0.08
382.3967285	0.07
388.1929626	1.54
389.2832336	0.43
391.4280701	0.37
396.1745605	0.25
406.1319275	4.43
406.9075012	0.20
407.6295471	0.04
415.4285889	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	601.2467
Annotation	Unknow
Peak:m/z	Relative Intensity
173.0786896	0.47
175.0836487	0.24
179.0770111	0.07
181.0643311	0.06
182.9600525	0.12
185.1442108	0.03
187.1279449	0.67
189.1215210	0.20
191.1180725	2.66
193.1409454	5.45
195.1731720	0.08
199.5585480	0.23
203.1004791	0.77
209.1275177	100.00
211.0086670	0.26
213.0049133	1.94
215.1664734	0.32
217.1600037	0.37
227.1044159	0.53
228.6424866	0.48
229.3740845	0.13
231.0760803	8.36
232.9648285	0.27
235.0422668	0.43
237.4618988	0.25
241.3040771	0.22
243.3211060	0.25
247.2186737	0.62
249.0250549	0.96
250.6610260	0.06
253.1957245	1.18
254.6434326	0.17
259.2301025	0.07
261.0960999	0.08
264.2654419	0.23
265.0601196	1.13
266.9892578	0.12
269.1706543	0.39
271.0798950	0.44
272.4255676	0.37
273.1391296	1.48
275.3583679	0.12
281.2515869	0.11
284.9454346	0.24
287.1751709	0.34
289.0782471	0.41
291.0196228	4.22
295.1100464	0.27
299.2014771	0.17
305.1434326	0.14
307.0534058	1.88
312.9061890	0.77
317.1223755	0.42
318.0051270	0.37
321.0445557	0.59
329.1022339	0.07
331.0220947	7.32
335.5665894	1.00
336.1802368	0.05
339.1615601	3.00
345.3054810	0.35
347.3887329	0.15
352.8786011	0.44
355.1054077	0.04
356.5304565	0.76
357.2163086	3.56
358.4623413	0.25
359.5109863	0.05
373.0319214	2.17
375.0925903	93.53
377.3259888	0.76
378.4913330	0.13
379.1434937	0.16
385.3535156	0.26
391.0150757	5.38
393.0356445	33.10
395.0913086	1.56
403.1564941	2.61
408.9910889	7.30
412.6279297	0.30
421.1323853	4.52
421.7827148	0.11
429.2698975	0.07
431.4989624	0.11
433.4082642	0.06
437.3212280	0.43
438.8237915	0.74
439.5325928	0.10
457.1213379	37.98
457.7590332	0.14
463.2228394	0.27
464.5877075	0.18
477.0028076	0.47
481.2274780	7.26
497.3444824	0.48
499.4205933	0.31
502.9688110	0.20
515.1963501	1.33
516.0733032	0.12
521.4227905	2.02
535.4210815	0.38
539.0728149	11.10
541.1787109	0.95
542.1965942	0.09
546.4303589	0.70
547.1530762	1.00
548.1310425	0.41
555.1613159	0.22
556.5891724	0.19
557.4676514	0.41
558.9697266	0.06
565.1156616	26.00
566.1602173	1.52
583.1165161	68.54
583.9693604	0.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1851
Annotation	Bufotenine O-glucoside
Peak:m/z	Relative Intensity
105.7088852	0.05
114.7371445	0.15
133.8460388	0.60
145.1188812	0.13
160.0361633	3.89
162.0025024	0.18
176.1378784	0.21
202.1579285	0.31
205.1032410	14.26
208.0965576	0.35
213.2003479	0.22
242.0796814	0.08
252.2612000	0.28
259.1406860	0.11
260.1359558	0.16
271.4315186	0.38
278.0114441	0.39
286.2190247	0.06
288.4645996	0.16
296.1571655	1.06
306.7717896	0.06
319.2415771	0.34
320.9618835	0.17
322.1419067	100.00
322.7993164	0.45
331.2749939	0.11
347.2682800	0.15
349.2359924	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	741.2239
Annotation	Troxerutin
Peak:m/z	Relative Intensity
271.1578979	29.03
296.6930542	0.10
307.1240540	0.06
313.0663757	0.18
335.3631592	0.08
353.2499390	0.55
355.0955811	0.47
356.7686768	0.07
366.1931763	0.06
367.3078003	0.18
379.1341553	0.17
383.3759766	0.18
384.2669067	0.34
385.2119751	1.37
387.4138794	0.04
390.3574219	0.09
416.2611694	0.06
433.1617432	100.00
438.2062988	0.03
440.4152222	0.05
442.2691650	0.21
443.2816162	0.05
456.1301880	0.05
457.2854614	0.45
458.5767212	0.25
459.4956665	0.14
465.1881714	0.09
473.1090698	0.22
474.1633301	0.33
475.1927490	0.13
485.3598022	0.03
492.8910522	0.04
503.1257324	0.08
504.2338867	0.09
531.2695923	0.18
531.9837036	0.09
532.9984131	0.38
535.2570190	0.54
537.2288208	0.04
549.1334229	0.38
560.3003540	0.27
561.4507446	0.04
574.7770386	0.06
577.1239014	0.19
579.2321777	10.95
609.4462891	0.03
619.1475220	0.08
620.1771851	0.88
621.2686157	0.79
623.5028687	0.08
626.8804321	0.28
628.5833740	0.16
633.1333618	0.12
639.4666138	0.04
649.3073730	0.51
650.2743530	0.25
651.3283691	0.47
655.2579346	0.25
656.5627441	0.06
665.3208618	0.08
681.0733643	0.13
692.2897339	0.03
694.7582397	0.19
696.3682861	0.13
697.1254883	2.34
704.1820679	0.11
718.7412109	0.39
719.9741821	0.07
722.1264648	0.21
723.0938721	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1853
Annotation	Bufotenine O-glucoside
Peak:m/z	Relative Intensity
114.9653549	0.09
127.0157471	0.25
131.9266815	0.04
133.9315491	0.98
135.2173767	0.26
138.7908783	0.14
146.1839600	0.14
146.9622955	0.05
156.6957550	0.40
160.1093445	4.00
171.0491638	0.26
174.9404907	0.55
175.9033203	0.26
184.2342224	0.19
186.3670502	0.14
187.1004333	0.41
191.7450867	0.16
192.5648651	0.43
193.2109985	0.23
200.2645264	0.07
203.1571350	0.39
205.1499786	17.32
207.8834839	0.19
212.8773804	0.14
215.1875916	0.27
218.2453613	0.07
218.9153748	0.06
223.0813904	0.05
225.1928101	0.26
228.1973877	0.29
230.0606689	0.16
231.1364136	0.73
234.9461365	0.12
237.2881470	0.05
238.1697083	0.21
241.6621399	0.12
247.2468262	0.55
249.8355713	0.13
251.1587830	0.11
252.0130005	0.42
256.1541748	0.10
259.0585938	0.05
265.2473755	0.09
271.0714417	0.44
277.4249573	0.18
278.2127075	0.11
286.1182251	0.21
288.9765320	0.11
289.9361877	0.18
292.2588501	0.05
295.1284180	0.39
296.1872559	1.23
301.3098755	0.09
305.1512146	0.28
308.1649170	1.86
313.3583679	0.05
318.7257080	0.10
320.3710632	0.23
322.1103516	100.00
323.3560791	0.46
331.2085266	2.06
337.3028564	0.19
347.0188293	0.16
349.2136536	3.45
350.1561584	0.57
358.1902771	0.44
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	263.1289
Annotation	Psilostachyin C
Peak:m/z	Relative Intensity
81.0987854	0.19
92.8676758	0.85
104.9775696	0.22
110.9969177	3.64
112.1270447	0.25
124.7570496	0.25
136.9750824	0.04
139.1635895	0.21
151.1638794	0.14
152.9882050	100.00
161.0164490	0.89
162.8920593	0.28
171.0570068	0.34
175.1021576	0.26
177.0083466	0.25
179.1972046	0.31
189.0630951	0.21
190.9777527	0.17
201.0189972	5.37
203.0492706	1.19
204.2016754	3.97
216.9967041	0.60
219.0959625	38.56
219.9379730	0.11
221.3571625	0.13
231.7236938	0.07
234.8932037	0.20
245.1936188	2.97
247.1937256	0.35
247.8687744	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	520.338
Annotation	PC(18:2(2E,4E)/0:0)
Peak:m/z	Relative Intensity
184.0117493	31.36
184.9585571	0.03
195.1165924	0.08
196.9821472	0.14
205.2783051	0.18
236.9334412	0.08
245.1608734	0.17
258.1599121	0.44
262.1401367	0.07
271.2359619	0.16
272.1118164	0.24
314.4332275	0.16
321.2445679	0.05
337.4543457	0.19
381.2301636	0.25
382.2021484	0.04
421.1603394	0.07
437.1335449	0.13
439.4503174	0.10
443.4801636	0.29
452.3555908	0.12
464.0695801	0.03
493.4515991	0.08
502.4279175	100.00
503.0894165	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.1066
Annotation	7,2'-Dihydroxy-4'-methoxy-isoflavanol
Peak:m/z	Relative Intensity
84.8984070	0.74
107.0343704	0.12
126.9488983	0.24
131.2062073	0.14
133.3206787	0.14
135.2505188	0.17
144.8825073	0.67
153.0244141	0.61
159.0444794	0.06
160.9861450	0.13
162.9532166	1.59
164.3413239	0.08
171.2264099	0.13
176.9960938	0.03
178.9891357	0.72
181.1023712	0.07
187.1245270	38.23
188.2074585	0.19
189.0489197	0.20
193.1104431	0.10
199.0649719	0.14
201.1354065	4.07
203.0085144	1.00
204.9657593	45.20
205.5686035	0.28
207.1228333	0.38
209.1038818	0.09
211.0971375	1.52
213.0419617	0.32
215.0679626	0.08
216.1325684	0.06
217.1425476	0.23
218.2775269	0.08
219.0061035	0.28
221.0198364	2.31
222.0862732	0.06
227.1680603	0.08
229.0498047	100.00
229.9003906	0.49
233.1070557	2.19
240.9965820	0.04
243.0544434	3.85
245.2184753	0.65
247.0136108	4.47
253.1900635	4.32
256.2490845	0.03
258.3007202	0.06
259.0921631	0.30
261.1661987	0.49
271.0914917	64.42
272.2927246	0.06
274.3419189	0.10
280.3094788	0.04
289.0313110	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	957.2516
Annotation	Unknow
Peak:m/z	Relative Intensity
285.1692505	0.25
287.0776062	0.57
300.9458008	0.33
302.0348511	0.04
305.1250916	0.03
315.1407471	0.93
329.0794373	0.29
330.0714722	1.89
339.0364380	0.27
345.1112366	14.67
375.5295410	0.08
431.0422974	0.08
449.3145142	0.84
451.3770752	0.20
455.5690308	0.09
477.1268311	0.06
488.9394531	0.50
493.1861572	0.11
501.4672852	0.03
505.3599854	0.12
507.1464844	36.75
507.7897339	0.28
509.2267456	0.06
521.3157959	0.29
531.0389404	0.22
535.2839355	0.12
543.4294434	0.24
549.2687378	30.67
581.4973145	0.10
589.1716309	8.74
591.1668091	10.22
608.7553711	0.08
611.2281494	0.26
620.6202393	0.08
621.2868042	0.30
623.4511719	0.09
631.3269653	3.35
632.9710083	0.88
645.3389282	0.49
647.1641846	0.24
651.1708374	100.00
657.2910767	0.11
669.2622681	1.02
671.3506470	0.14
673.2053833	0.36
675.1375122	0.07
693.1776733	22.43
695.4031372	0.04
697.3710938	0.18
711.1196899	0.50
715.3379517	0.23
719.1041260	0.05
723.1312866	2.09
733.0632935	2.94
735.1609497	1.75
740.2282715	0.11
747.2001953	0.17
751.3857422	0.20
753.0863037	1.35
753.7005005	0.13
764.1157227	0.15
765.2368774	1.31
768.8939819	0.13
773.8200684	0.11
775.1207886	0.23
777.1553345	0.45
795.1961060	61.58
805.3983765	0.14
813.0903931	16.43
837.0861206	6.74
848.9461060	0.41
855.1311035	1.98
855.7593384	0.04
867.1836548	5.36
878.6988525	0.09
890.9684448	0.04
893.1058350	0.27
895.2859497	0.29
897.0584717	15.65
897.7664185	0.11
927.3108521	0.97
939.1760254	3.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1512
Annotation	kaempferol-7-O-neohesperidoside
Peak:m/z	Relative Intensity
168.9851532	0.01
171.0419312	0.12
173.9941711	0.01
175.0348969	0.35
177.2042694	0.03
181.9181519	0.08
184.1541595	0.04
184.9665527	0.28
186.6949768	0.15
195.105957	0.04
197.2145081	0.17
198.0402832	0.15
199.1470947	0.51
201.04216	0.50
213.1614075	0.10
215.3566895	0.02
217.0974731	0.53
218.2624817	0.03
223.0307617	0.11
228.987854	0.05
230.4165955	0.03
239.2474976	0.04
240.9294891	0.32
241.8092041	0.15
243.0885468	0.54
257.2421265	0.22
267.1645508	0.06
269.1867371	0.06
282.9279785	0.04
285.0489502	100.00
286.138916	3.54
297.1773071	0.10
298.2550049	0.03
299.3460083	0.08
308.0386963	0.04
323.2223511	0.95
327.1477051	0.60
328.1513062	0.15
341.2420044	0.09
353.1975098	0.41
354.37677	0.03
357.1537476	0.04
368.918335	0.05
371.359314	0.14
385.3279419	0.08
393.2633057	0.07
395.3098145	0.02
412.8774414	0.01
431.3210449	0.03
443.2191772	2.96
447.2349243	0.46
448.3092041	0.21
449.4208374	0.09
455.1156616	0.05
461.3024292	0.08
473.1968994	0.63
474.0674438	0.02
503.0812988	0.11
506.8844604	0.03
514.9209595	0.04
533.2077026	0.11
539.2301636	0.04
545.2093506	0.05
548.9432983	0.05
556.9371338	0.02
575.4928589	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	175.12
Annotation	L-Arginine
Peak:m/z	Relative Intensity
59.8423653	51.18
69.9705811	6.91
72.0113220	1.82
84.0438995	0.19
87.0512695	0.09
96.9916840	0.31
97.9541321	0.23
111.9239044	6.11
113.0325623	0.48
114.1303101	4.73
115.0255432	2.08
115.9972076	50.99
130.0108337	37.64
130.9397278	0.37
133.0933075	1.09
139.9658203	2.80
141.1159973	0.47
157.0122375	74.80
158.0744171	100.00
166.2117004	0.53
174.9484406	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.2961
Annotation	Synechoxanthin
Peak:m/z	Relative Intensity
181.0148621	0.02
270.9732666	0.01
277.1267700	0.05
284.1669617	0.06
285.2100830	0.07
299.0500488	0.03
300.0053101	0.34
312.2304688	0.03
315.1150513	2.29
317.1352844	0.05
323.2649841	0.13
325.2105103	0.01
327.4694214	0.02
341.4364624	0.05
342.3731079	0.02
352.1775513	0.04
353.2779541	0.02
355.3471069	0.01
357.2902222	0.03
383.2401733	1.71
384.2672119	0.13
393.1655884	0.02
395.4899292	0.03
397.2839966	0.03
413.2434082	0.52
414.1580200	0.07
421.4721680	0.05
422.1404419	0.02
425.2034302	0.02
427.1855469	0.07
435.4581909	0.05
442.9436035	0.08
455.4765625	0.02
460.4630127	0.08
461.4467773	0.03
463.3203735	0.02
473.2924194	0.03
479.3417358	0.08
485.2305908	0.09
486.5739746	0.02
501.3162842	0.03
503.3092041	4.71
504.3854980	0.37
506.2511597	0.04
509.5200806	0.03
515.4236450	0.14
521.3086548	0.04
529.1738892	0.01
533.1359863	0.47
534.3621826	0.12
535.1103516	0.02
538.7479858	0.06
541.7247314	0.04
543.3597412	100.00
544.0222778	0.25
545.1633911	0.07
547.3933716	0.07
551.1716919	0.08
561.3534546	0.03
563.0316772	0.10
565.9461670	0.03
569.4101562	0.08
574.8590698	0.02
577.1788940	0.15
579.2363281	0.13
585.0591431	0.02
587.1740112	13.46
587.8571167	0.06
595.5871582	0.03
605.2460938	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	588.0959
Annotation	DC 89B1
Peak:m/z	Relative Intensity
173.9664917	0.26
185.1591492	0.09
197.9582214	0.38
202.0146790	0.19
202.8040009	0.11
215.9050903	0.59
228.3257446	0.06
232.2229309	0.19
233.9606018	2.96
239.5713348	0.26
245.1716003	0.46
246.1748047	0.30
258.1255493	0.11
260.1216431	0.35
261.8815918	0.10
270.1923218	0.10
274.8485413	0.85
276.0304565	12.66
290.0903931	0.10
302.0657959	0.20
304.0151367	0.10
305.9663086	37.92
315.7935181	0.04
319.2063293	0.45
321.6944580	0.31
323.7401733	0.19
327.9110718	0.09
329.8731079	0.05
331.5856934	0.20
334.3757324	0.29
336.0693359	7.07
343.5758057	0.09
345.2127686	0.08
346.2432861	0.06
348.4449463	0.10
351.1376343	0.15
359.9106445	0.39
363.9008789	0.49
364.8793335	0.06
366.1147461	0.69
371.9197998	0.14
377.1704712	1.97
377.9709473	3.44
379.6994629	0.41
382.0452271	0.96
383.1680298	0.20
385.1942139	0.43
387.4851074	0.26
395.8929443	26.99
396.5206909	0.49
397.7255249	0.17
408.0579224	1.95
411.0120850	0.29
417.4240723	0.08
424.3430786	0.55
425.9503174	100.00
438.0126953	0.32
440.4303589	0.10
446.3824463	0.48
452.0285034	0.17
454.9859619	0.20
456.2932739	0.14
468.1801758	1.76
469.1187744	0.19
477.7340698	0.14
485.2941895	0.70
490.0319824	0.26
491.4454956	0.05
492.1008911	0.71
497.9201050	3.05
513.9620972	0.03
525.8796387	0.25
527.9100952	0.15
528.9758911	0.13
539.9484253	0.13
544.1879272	1.25
566.0926514	0.26
569.3150635	0.29
569.9644165	1.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.2502
Annotation	Glucosyl-limonin
Peak:m/z	Relative Intensity
183.1741333	0.29
187.2093048	0.09
198.3053131	0.11
202.2926636	0.12
205.2610168	0.41
209.0855560	7.29
213.2590332	0.20
215.2501068	0.11
217.0068512	0.05
219.2319031	0.68
225.1184998	0.23
227.2012024	1.28
229.2238464	0.32
233.2657776	0.85
237.0530701	0.33
243.2502899	0.33
245.1697693	0.92
251.0512848	0.06
257.0982056	0.18
257.7096252	0.08
258.9644775	0.27
260.9918823	0.24
263.1693726	0.33
267.3351135	0.31
268.8649597	0.24
273.2948914	0.52
275.1420288	0.40
277.2134094	0.30
281.0142212	0.09
285.3211975	0.31
287.2015381	0.80
289.2124939	0.55
291.2357788	0.07
295.1680908	0.41
297.3125000	1.10
299.4481812	0.16
301.1493530	0.17
303.2677307	0.44
305.3831177	0.58
309.5051880	0.43
311.2873535	0.35
313.2512817	0.89
315.3673096	0.16
317.2383423	0.34
319.3672180	0.56
323.2468262	1.54
325.3859863	0.09
327.5220947	0.23
329.2033081	0.21
333.2682495	0.29
334.2097778	0.14
337.4174805	0.14
339.2749023	0.39
340.6372681	0.26
341.2709351	4.44
347.2719727	4.22
349.1275635	0.11
351.1039429	0.28
355.3721924	0.44
359.3689575	0.53
361.1599731	0.37
363.1849365	0.58
365.2707520	0.21
367.3251343	0.29
371.4744873	0.45
373.5104980	0.55
381.4194946	0.24
383.2211304	0.75
384.7150879	0.65
385.3171387	8.69
389.2860107	0.11
391.0573120	0.46
395.1805420	0.29
399.3521118	1.15
403.4300537	0.63
407.3678589	0.74
413.2755127	0.38
417.3690796	1.61
423.4682007	0.06
425.3441162	0.72
427.3059082	0.59
435.2745972	0.20
441.3329468	0.08
443.2189941	42.55
443.9428711	0.27
445.0763550	0.46
447.1189575	0.09
455.1931152	0.26
457.6283569	0.49
461.3731079	18.13
463.3590698	2.63
466.9237061	0.52
469.4402466	0.07
473.2104492	0.12
474.0053711	0.20
475.1274414	0.49
475.8208618	0.30
483.4158325	0.22
485.3765259	0.26
487.0621338	0.14
491.0534668	0.05
493.3422241	5.53
497.1867676	0.36
503.2416382	1.11
505.5796509	0.38
507.3864136	0.15
509.4972534	0.92
511.3909912	0.21
515.1490479	0.19
525.0454102	0.07
529.1981812	0.31
531.2633667	0.09
537.5093384	0.14
543.0339966	0.28
545.3757935	0.83
547.3609009	5.26
558.9864502	0.44
561.4434814	2.54
568.9763794	0.34
573.2471924	0.43
575.2846069	1.06
587.3524780	5.16
591.3549805	0.83
593.3614502	0.27
603.2546997	0.30
605.3415527	100.00
606.2502441	0.55
631.2427368	6.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	672.1782
Annotation	Norbergenin
Peak:m/z	Relative Intensity
199.1040955	0.20
268.0869141	0.05
286.0189209	0.17
301.0687256	8.80
497.2693481	0.12
509.6897583	0.08
527.2595825	0.13
569.1585083	0.08
607.3408813	0.07
609.1774902	100.00
609.8751831	0.28
629.8217773	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	746.36
Annotation	Dianthin D
Peak:m/z	Relative Intensity
434.1888428	0.11
444.3333130	0.12
477.2140503	0.05
598.2271118	0.08
602.4325562	0.20
634.1860352	0.03
640.0115356	0.10
660.2750854	0.07
680.5319214	4.51
681.9284668	0.20
686.2623901	0.16
692.0408325	0.06
702.4317017	0.19
710.4408569	100.00
711.6536865	0.02
716.6619263	0.12
723.6924438	0.12
728.3710938	0.61
729.2702026	0.10
730.9420166	0.07
747.9492188	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	611.14
Annotation	Oxidized glutathione
Peak:m/z	Relative Intensity
174.2774048	0.09
177.1573944	0.48
179.0243073	1.07
180.8826294	0.17
185.0714874	0.37
192.2535400	0.29
193.1723328	0.47
197.2043915	0.22
210.1548767	1.51
213.2424927	0.14
214.0383606	0.18
226.0401611	0.12
227.9219360	0.10
236.1003265	0.16
242.3865356	0.11
252.1270142	0.27
254.0692444	13.15
268.9369507	0.09
272.0989990	29.93
286.1176758	0.34
288.1132202	5.90
304.1254883	16.55
306.1535339	100.00
315.6920776	0.31
320.0594482	0.56
329.1560059	0.13
338.0915527	35.94
340.3073730	0.14
353.0450439	0.18
381.2540894	0.12
391.3230591	0.17
407.0886230	0.36
464.1059570	1.20
482.1951294	28.49
527.1889038	0.08
536.4013062	0.14
549.3482666	0.05
575.2175293	0.47
593.2520142	14.25
594.3685913	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	434.2162
Annotation	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
Peak:m/z	Relative Intensity
124.0093384	0.04
143.0809479	0.09
150.9914551	0.08
153.1828156	0.06
165.2763367	0.05
190.0533600	0.09
197.3449707	0.03
201.0551453	7.87
203.0927734	0.28
208.8730621	0.10
213.1473694	0.09
215.3056488	0.04
216.6640930	0.15
218.3700409	0.08
219.0308075	0.02
221.1809387	0.03
226.5757751	0.03
228.9791870	0.05
231.0432587	0.08
241.0365601	0.09
243.1357422	0.23
248.7455444	0.01
250.2244568	0.02
255.2092896	0.03
257.2513123	0.12
264.1849060	0.11
267.2199402	0.01
269.0553589	0.19
285.0270996	15.43
287.0153809	0.66
298.0590820	0.04
300.1401978	0.03
301.9918823	1.88
302.9282227	20.61
303.6676025	0.04
313.7630920	0.02
333.9252930	0.03
347.4683228	0.02
349.4738159	0.04
351.9387512	0.31
352.9380798	3.22
354.1923828	0.02
360.6095581	0.01
365.1936035	0.14
367.2672424	0.20
368.3271179	0.17
370.9053650	100.00
371.6728210	0.06
376.4483948	0.05
379.2746277	0.03
380.1913757	0.03
384.8680115	0.18
388.4607239	0.08
391.0803833	0.03
397.5271301	0.08
398.2754211	0.14
402.7969666	23.74
403.5257874	0.12
416.2384644	1.08
417.1006165	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	304.2836
Annotation	Unknow
Peak:m/z	Relative Intensity
89.9718018	0.16
92.8986511	0.06
94.9743729	0.61
97.1154251	0.23
98.0691834	0.08
100.9156952	0.07
103.1547318	0.03
107.2443390	0.16
109.1530151	0.08
110.9877625	0.28
111.8222275	0.12
113.0780182	0.32
121.0686417	0.57
123.0911255	0.44
124.8516541	0.04
127.2632294	0.11
132.9203033	0.05
135.1676941	0.57
137.2614746	0.16
138.2137604	0.33
139.1635132	0.03
141.2372437	0.04
145.0769348	0.16
146.0591125	0.08
149.0544891	0.03
150.7736206	0.60
151.8771057	0.17
152.9820557	1.10
154.0159302	1.65
154.9444580	0.07
157.1548920	0.10
159.9776306	0.09
161.1772614	0.03
163.0460815	0.04
163.8986511	0.12
165.1956177	0.44
167.0563354	0.03
168.2971649	0.15
169.1105499	0.50
172.5872192	0.15
176.0775757	0.23
177.0241699	6.65
178.0753937	11.62
179.0334473	4.11
180.0436096	3.62
181.4579773	0.03
182.1246948	0.03
183.2265625	0.07
185.3408813	0.06
190.1507111	0.09
191.1165619	0.39
192.1120758	0.04
193.1090240	0.10
197.1018066	0.79
198.9860229	0.24
201.0535889	0.58
203.0635376	24.46
206.9179993	0.05
209.2288208	0.27
210.2334900	0.14
211.2448730	0.21
212.0570984	0.05
213.3288574	0.07
214.1283875	0.40
219.1574402	0.61
220.2962341	0.44
221.1165466	0.31
225.3878174	0.19
227.1110229	0.14
229.9994812	0.31
233.1484070	0.78
234.2291870	0.27
238.4732361	0.79
239.3628540	0.67
240.3017883	0.09
241.3163147	0.47
242.1824036	0.13
242.9149780	0.08
244.6993408	0.14
246.0241699	0.31
246.7447815	0.07
248.1854858	0.06
249.2676697	0.12
250.2130432	0.94
251.2903442	3.97
254.2473145	0.09
255.1636963	0.41
256.2735596	1.14
257.9878540	0.84
259.2622375	0.20
261.0940857	0.19
262.1946411	0.37
263.0729980	0.56
268.2627563	38.27
269.1244812	0.52
272.0905151	0.15
273.1996765	0.35
275.0953674	0.04
276.0910034	0.65
277.1484680	0.22
277.8443298	0.30
281.8828125	0.18
283.0624695	0.13
284.1429443	0.43
286.2525940	100.00
287.2282104	1.95
289.2734985	0.50
295.1551819	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	787.2249
Annotation	Isorhamnetin 3-rhamnosyl-(1->2)-galactoside-7-glucoside
Peak:m/z	Relative Intensity
258.9633484	0.10
301.1146240	0.03
337.3350830	0.18
343.1840210	0.17
348.2429810	0.06
355.1560974	0.28
367.1279297	0.59
373.1724854	0.04
379.2031250	0.28
385.1195679	0.37
391.4099731	0.07
397.0645752	0.04
409.2550659	0.63
418.1332397	0.11
421.0755005	1.17
421.9659424	0.23
433.2707520	0.19
439.1089478	1.30
441.5623169	0.07
445.1843872	0.63
451.2442017	1.02
457.1818848	1.19
463.1505127	0.25
469.0827637	0.58
475.1812744	0.49
487.2426758	18.75
499.4104004	0.10
505.2399902	3.66
511.1997681	3.02
511.8052368	0.03
517.0783081	0.07
523.1314087	0.35
527.2169189	0.06
529.2216797	1.26
535.3094482	0.27
541.2126465	10.90
543.4190063	0.13
547.1724854	1.91
553.2480469	5.95
559.2461548	2.92
571.2796631	6.83
573.3905029	0.10
576.6305542	0.16
577.5911255	0.04
583.0563354	0.77
583.9896851	0.04
589.1317749	18.36
589.7647095	0.17
595.4591675	0.24
601.2780151	3.46
607.1339111	43.31
607.7818604	0.47
608.7619019	0.04
613.2730713	1.05
619.2184448	1.05
624.6719360	0.93
625.2969971	3.68
631.1670532	2.29
642.0006104	0.03
643.1654053	1.51
649.1917114	100.00
649.8450928	0.42
660.7318726	0.03
664.9318848	0.16
667.1524048	29.50
667.7738037	0.24
673.2527466	7.58
679.1623535	0.12
683.9570923	0.18
685.1438599	1.36
691.2775269	5.00
697.2962036	0.38
703.1985474	14.99
703.9240112	0.03
715.2745361	7.35
721.0972290	5.48
727.0368042	0.74
727.8867798	0.32
733.1785278	13.11
733.8562012	0.05
751.2196045	54.56
769.1514282	86.44
769.8418579	0.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
198.914978	1.43
201.0914612	1.37
214.1733551	0.15
215.1390839	0.48
217.1786194	0.13
224.2685852	0.39
226.9660339	0.80
233.0508575	0.14
240.1439514	0.85
241.150528	0.37
242.2121582	0.62
248.3248444	0.17
250.1107178	0.09
257.0756531	0.94
257.835083	0.07
267.1668701	0.14
268.1920776	0.34
272.0234375	0.17
282.9955444	1.78
284.1641846	0.58
285.2836914	0.40
286.1680908	1.91
299.2780762	1.82
301.0799561	100.00
302.0064392	0.20
306.8679199	0.13
325.0093384	1.98
327.2959595	0.51
338.5218506	0.14
343.227417	0.48
355.2737427	0.33
369.184082	0.12
399.2723389	0.60
410.9752197	0.32
436.975647	0.12
438.1616211	0.31
446.194458	0.27
447.43927	0.67
453.4386597	0.10
471.2128296	0.22
479.9321289	0.72
489.222168	4.90
501.0921631	0.59
504.9872437	0.18
519.2043457	3.71
523.3748169	0.21
545.1013184	0.08
546.2860718	0.66
551.0782471	0.12
561.3427734	0.43
586.9837646	0.11
589.241394	0.12
591.1202393	2.29
591.8294067	0.21
592.7160645	0.36
593.5892944	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	160.0963
Annotation	Unknow
Peak:m/z	Relative Intensity
57.9052963	1.27
69.7746735	0.75
70.9018250	0.56
87.9563141	100.00
96.1881867	2.86
99.9851685	3.19
101.9366455	6.73
114.0156403	2.85
127.0774078	1.01
142.0797577	4.54
160.2080383	2.45
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	391.1048
Annotation	Garcimangosone D
Peak:m/z	Relative Intensity
111.0558167	1.44
113.0297852	1.51
137.0430298	2.91
143.0190125	5.54
143.9582214	0.14
153.0185852	1.57
154.9762268	6.57
156.0536194	1.52
172.9742737	10.27
174.1106567	1.13
181.0483093	0.48
189.0025635	0.57
191.0897522	4.28
198.9615173	36.73
199.9756317	0.93
217.0357666	100.00
218.0717773	7.09
230.8430786	0.15
241.1119080	0.38
259.0724487	39.18
259.6931763	0.17
273.1129761	0.18
285.0034180	0.48
287.1528931	1.52
304.2330627	1.55
305.1920776	2.13
311.2673340	4.52
315.1144714	0.40
326.6514282	0.34
327.3649902	0.47
329.1398621	1.79
330.4747925	0.20
331.1439514	0.84
345.5764465	1.32
346.6322327	0.59
347.3003540	8.52
355.1755981	3.14
373.1427612	98.51
374.2386780	2.55
391.2769470	9.24
392.1427307	2.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1147.3146
Annotation	Unknow
Peak:m/z	Relative Intensity
328.9769287	0.07
332.8183594	0.23
342.0643616	0.31
359.0839233	0.20
399.0018921	0.31
448.3646851	0.11
449.1473999	0.24
459.2617798	0.51
477.1712341	10.30
505.1519165	0.23
519.2384644	11.63
531.3301392	0.10
535.2467041	0.07
543.3201294	0.26
549.0467529	1.00
550.1995239	0.08
559.2058105	5.14
561.2915039	4.41
563.0214844	0.21
565.2711182	0.15
585.1917725	0.07
590.9562988	0.27
593.2919922	0.18
594.8928223	0.06
601.1770020	2.89
603.2629395	0.57
605.6398926	0.12
621.1527100	36.54
621.7656250	0.18
627.0190430	0.12
630.7260132	0.62
641.4454346	0.31
645.1124268	0.28
651.1704712	0.19
655.2535400	0.08
656.1800537	0.27
663.1068115	9.08
665.4521484	0.51
677.2040405	0.07
684.0373535	0.11
686.1656494	0.16
697.2685547	9.40
702.7017212	0.83
703.3261108	0.36
705.2023926	0.90
711.3559570	0.26
738.8991089	0.15
747.1883545	0.13
765.1669312	4.98
770.2875977	0.11
779.5015259	0.14
789.5562744	0.18
800.1535645	0.34
803.4049072	0.06
806.7657471	0.36
845.3941650	0.17
858.6267090	1.11
859.2614746	18.76
883.5316162	0.24
901.1794434	20.24
921.0716553	0.14
925.1448975	0.09
940.5842285	0.26
941.2893066	11.06
943.1960449	3.10
954.8808594	0.09
971.0281982	0.15
983.1292725	2.99
985.0823975	0.37
989.1711426	0.11
992.4726562	0.25
1003.2384030	100.00
1045.1198730	12.72
1051.7583010	0.47
1062.5799560	0.08
1084.9349370	2.38
1086.2714840	0.18
1087.2100830	0.33
1100.5036620	0.11
1102.4111330	0.48
1114.5272220	0.09
1116.2053220	0.16
1129.1899410	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	206.89
Annotation	Unknow
Peak:m/z	Relative Intensity
122.8161926	100.00
160.9105072	0.02
164.8238983	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	534.1617
Annotation	Unknow
Peak:m/z	Relative Intensity
161.0438385	0.31
162.9797974	0.25
170.0662537	0.04
196.9907990	0.02
203.9675598	0.35
209.9548340	0.03
225.2193604	0.05
228.2122498	0.13
233.0836487	0.07
250.0965881	21.02
263.0169067	0.07
266.3877563	0.03
268.1188660	5.98
284.1116943	0.16
285.5013428	0.12
286.1856689	0.61
286.9909058	0.12
295.0095825	0.03
310.2460327	0.04
314.0535278	0.03
330.2078857	0.16
331.2855225	0.25
336.0166016	0.03
343.3363647	0.03
344.1926270	0.05
354.1729736	0.21
368.0636597	0.31
371.1987305	0.16
372.2223511	0.71
373.4602051	0.14
374.1297607	0.03
387.3554688	0.10
391.4833374	0.14
399.2203369	0.05
413.3932495	0.15
417.1033936	0.07
430.3256226	0.33
435.9054565	0.08
447.9682617	0.11
450.2152100	0.02
451.9528809	0.03
454.2267456	0.04
462.1354980	0.14
463.3807983	0.14
466.5085449	0.16
472.1381226	0.06
473.4899902	0.11
480.0546265	0.11
481.1960449	0.04
491.2307129	0.13
498.1380005	2.05
499.3483887	0.07
501.3616333	0.05
502.3059082	0.06
506.6630249	0.25
516.1406250	100.00
516.7650146	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	593.1849
Annotation	BUDDLEOFLAVONOLOSIDE
Peak:m/z	Relative Intensity
177.1164551	0.02
194.1086121	0.01
210.2574463	0.03
223.3232422	0.02
231.2160339	0.04
244.7394714	0.01
257.3736572	0.02
285.2127075	17.22
287.0967712	0.16
305.3742981	0.01
309.4747314	0.01
327.1383667	0.10
330.8619385	0.03
343.3814697	0.04
345.3977661	0.03
357.1732788	0.02
380.9649658	0.02
383.2595215	0.03
389.1379395	0.01
393.5464478	0.05
395.2561035	0.45
403.411377	0.05
413.2424316	0.33
423.1615601	0.13
431.2432251	0.89
439.4129028	0.09
447.1389771	100.00
451.1585693	0.03
455.3743896	0.02
467.2063599	0.10
493.2429199	0.08
497.7213135	0.02
507.3488159	0.08
513.3400879	0.04
527.2866821	0.03
532.3693848	0.05
532.9699097	0.03
539.1580811	0.07
557.5803833	0.03
569.5317993	0.01
575.3510132	0.36
577.2459106	0.05
583.9347534	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Diosmin 
Peak:m/z	Relative Intensity
271.2485046	0.81
284.0930481	23.97
299.0553894	100.00
300.147522	0.47
301.1653442	0.30
308.1621094	0.24
310.9975586	0.97
329.2462769	0.77
335.5943604	1.63
445.4310303	0.74
446.041626	0.75
449.3059692	1.29
497.2616577	1.02
543.2555542	0.98
546.0457764	1.58
560.7698975	0.34
563.0856934	1.46
588.7269897	0.50
589.5297241	3.27
590.2180176	0.83
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	407.0985
Annotation	Annulatophenonoside
Peak:m/z	Relative Intensity
124.9251556	81.32
136.0691833	0.10
136.9841614	2.41
138.9493713	0.09
149.0432281	17.21
166.9194641	1.72
178.9976196	13.83
188.9916229	0.33
191.0578308	2.55
208.9930725	0.47
217.0990143	0.27
221.3062897	0.14
232.9611206	0.34
239.0011902	100.00
243.0850830	0.11
251.1993713	1.75
256.0559082	0.15
269.0791931	0.96
281.0870972	31.80
316.9183350	0.17
347.0890198	0.58
371.1697083	1.92
377.2829590	0.06
379.4420776	0.18
389.0213318	0.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	643.1714
Annotation	Unknow
Peak:m/z	Relative Intensity
191.2836761	0.14
214.7520294	0.03
217.0704498	0.80
258.9155273	0.15
261.8295288	0.06
289.0812378	0.06
303.0925903	11.41
321.1612549	9.34
346.1857300	0.11
347.1669312	0.09
375.3253784	0.11
381.3760986	0.90
391.3471069	0.06
397.1481934	0.05
402.2256470	0.09
405.1835327	0.04
409.1464233	0.11
419.0935669	0.22
423.0025635	0.15
425.0531006	0.12
433.3596191	0.08
437.1493530	2.28
450.1104736	0.17
451.1885986	2.59
463.1279297	1.07
467.1990356	0.13
479.1682129	27.09
481.2153320	0.22
484.8820801	0.62
485.5821533	0.31
495.5119629	0.22
497.2137451	11.28
506.4804077	0.04
507.2089233	0.44
509.4712524	0.04
521.3907471	0.17
539.2344360	40.75
539.9233398	0.05
581.0935059	1.24
581.7525024	0.23
596.9400024	0.05
607.3189087	0.05
625.1251831	100.00
625.8648071	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	402.19
Annotation	3S-5,7,3'-Trihydroxy-4'-methoxy-5'-prenylisoflavanone
Peak:m/z	Relative Intensity
123.1802826	0.07
132.9475708	0.02
169.4012146	0.03
201.0084534	44.27
203.0729370	1.14
209.0721436	0.03
215.0274353	0.41
217.0532684	3.07
219.0389709	2.21
229.0561218	0.75
230.9983521	1.01
241.0960083	0.87
243.2083435	1.18
245.2545166	0.02
251.1263123	0.10
253.0068359	0.03
255.1611633	0.43
257.0776062	0.60
267.2680969	0.26
269.1751709	0.42
283.1982117	0.37
285.0493774	100.00
287.0792236	3.85
296.6080322	0.50
297.3566284	0.03
300.8218384	0.18
301.7379456	1.68
302.4418945	11.86
303.0588989	41.28
303.6901245	0.30
312.2841797	0.03
320.3729858	0.03
323.2440796	0.28
324.3944702	0.20
325.0248108	0.06
333.1358032	0.12
334.1995850	0.12
335.3836060	0.05
349.3697815	0.12
350.0384521	0.12
352.8606262	14.14
353.6256714	0.21
361.2321472	0.06
368.4274597	0.15
369.2799072	0.29
370.8881531	67.40
371.6795044	0.11
384.6046753	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1137
Annotation	Spicatolide C
Peak:m/z	Relative Intensity
117.0709152	0.88
123.0914536	0.05
134.8712311	0.05
147.0767212	0.17
147.9593048	0.16
149.0767975	0.15
158.8674622	0.15
167.0524597	0.61
173.3089752	0.11
175.0372314	0.21
181.0364990	0.05
190.9793701	1.97
193.0649567	0.36
197.2570496	0.17
201.2596436	0.08
203.0348053	0.61
216.5969543	0.55
217.2133484	0.34
218.2152100	0.11
220.9332886	0.18
225.3190308	0.07
226.2260742	0.09
236.9822083	0.03
239.1908875	0.62
243.0288086	0.67
249.0405579	0.20
251.0802612	1.46
253.1311035	0.05
263.8812866	0.06
266.9714355	0.20
268.0564575	2.65
281.1461182	0.49
283.0794678	100.00
284.1370239	8.18
293.2295532	0.80
296.2471924	0.06
311.1535034	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1743
Annotation	Unknow
Peak:m/z	Relative Intensity
300.9857788	0.16
313.1864929	0.40
317.0601807	0.16
319.2343750	0.10
324.9173889	0.24
337.1750488	0.03
340.3496704	0.03
341.1402588	0.02
343.1868286	3.39
351.8676758	0.03
354.9508667	0.06
365.3900146	0.10
367.1604614	1.90
374.8905029	0.10
377.3235474	0.08
379.0929565	0.01
385.1398926	0.71
390.8858032	0.15
393.6024780	0.07
397.1278076	3.98
409.1395264	1.09
421.0111084	0.10
427.1323853	1.84
439.0925293	0.93
445.0889282	12.61
445.6964111	0.16
446.7737427	0.03
451.1082764	0.63
454.4064331	0.09
457.2044067	0.33
461.2430420	0.02
463.2113037	16.89
469.0577393	0.73
474.9375000	0.36
475.6348267	0.02
479.1779785	0.77
487.1093750	30.72
487.7138672	0.43
492.9481201	0.06
499.2726440	0.01
505.1828613	12.18
511.2959595	3.62
517.2273560	0.08
529.1210938	5.56
535.3886108	0.15
541.0808105	10.15
541.8246460	0.10
542.6445923	0.06
545.3292847	0.08
553.2637329	6.02
559.0830078	13.62
559.7606812	0.05
563.3267822	0.05
569.4815063	0.05
571.1694946	7.56
571.7883301	0.08
581.0858765	0.02
589.1453857	28.67
590.1346436	0.05
607.1583862	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	766.2051
Annotation	Unknow
Peak:m/z	Relative Intensity
211.3249359	0.30
228.6987762	0.24
229.3341675	0.23
231.2202759	0.27
236.1125183	0.14
246.9810486	1.09
248.8720856	0.28
255.0381775	1.48
256.2741089	0.07
264.7445679	1.16
269.1470642	0.37
271.0272827	0.12
272.7911072	0.58
279.1581421	0.83
283.4225464	0.37
284.8901367	10.74
285.6958008	0.18
286.3323364	0.36
287.1181641	0.54
302.0888062	0.10
304.5119629	0.04
319.0948181	0.28
322.7513428	3.66
325.0812073	2.77
331.1108398	0.60
338.1632690	0.10
339.2909546	0.18
342.7563782	0.53
349.6315918	0.42
359.4646606	0.20
360.8893433	0.09
362.8706055	0.92
368.1246338	0.28
369.1182861	0.06
370.1576538	0.04
378.1362915	1.33
378.8795776	0.22
381.0493774	0.12
397.0392456	2.63
400.7424927	0.28
404.5952148	0.35
406.2365723	0.35
406.8582153	0.09
416.3593140	1.02
417.0187378	7.53
418.2377930	0.29
418.8798828	1.18
425.2609863	0.25
426.1539307	0.31
426.9469604	0.29
433.0725708	0.05
434.0463867	1.78
435.0795898	0.43
436.9353027	0.72
444.2249756	3.90
445.1312256	1.28
454.7073364	3.53
455.9932251	0.27
457.0954590	2.98
463.0946655	5.72
463.9346924	0.41
466.6593018	0.16
468.9855957	0.52
469.7894897	0.04
471.0949097	0.58
473.1380005	3.22
474.7073975	7.60
476.2175293	0.25
478.4094849	0.14
484.2874756	0.32
491.9899902	0.47
493.5076904	0.20
495.3063965	0.18
500.1895752	0.49
501.0377808	0.41
509.4979858	0.57
510.2368774	2.46
511.1437988	0.56
512.6387939	0.09
519.3258667	0.09
520.1720581	0.54
528.9816895	10.14
529.9604492	2.11
532.9464111	0.57
539.1145630	11.80
540.0578003	0.85
541.2876587	0.42
542.0062866	0.57
544.5104370	0.19
548.8416748	2.84
550.9533081	0.66
553.0564575	0.13
557.9904785	13.00
558.8906860	0.32
561.7822266	0.08
568.3711548	0.13
569.0178223	0.13
570.7857666	0.14
573.1716919	0.44
576.1643677	0.56
577.5397339	0.28
578.7511597	0.05
581.0944824	0.08
583.3400269	0.21
584.7661743	0.11
586.4497070	0.45
587.3068237	0.41
588.7338257	1.62
594.4705200	0.27
595.1560669	4.31
595.9174805	0.53
597.0323486	0.79
603.2142944	0.42
605.0967407	13.23
606.0960693	2.57
606.8748169	9.61
607.8054810	0.16
611.0778198	0.23
612.2141113	0.33
613.9669800	1.43
615.1685181	1.12
617.2710571	0.06
623.9867554	20.76
624.6365356	2.78
625.2684937	0.64
626.5147095	0.13
632.3384399	0.04
634.0231323	10.85
634.7816772	0.59
635.4495239	0.33
641.1107788	0.50
642.9457397	0.72
653.2586670	0.05
659.1727905	0.53
660.0801392	0.23
661.1712646	45.33
661.9936523	0.43
663.0095825	0.41
670.3995361	0.61
671.1815796	2.81
671.9735718	1.12
672.9041748	0.46
674.3822632	0.14
681.0857544	1.35
682.0699463	1.51
689.9993286	23.33
691.0849609	6.23
692.0328369	0.62
700.0476685	36.55
701.0991211	1.07
708.0242920	0.07
708.6273804	0.16
718.7703247	0.61
720.8397827	0.18
725.8323975	0.51
735.4002686	0.07
737.1321411	0.34
738.1884155	0.81
738.8410645	5.87
739.5139771	0.04
743.2600708	0.17
748.0170288	1.50
748.8153076	0.13
750.4304199	0.19
754.8942871	0.38
757.1223145	0.16
773.3402100	0.53
774.9960938	0.12
791.0540161	1.23
793.0972290	100.00
794.0087891	1.58
795.0823364	1.05
810.9866943	0.10
812.9473877	0.88
831.2196655	0.27
849.1621704	0.06
851.1708374	1.66
869.2585449	0.25
870.8778076	1.09
889.4855957	0.53
905.2373657	0.39
906.1642456	0.07
907.1015015	0.20
923.4290161	0.89
925.1005859	72.44
926.0617676	1.17
942.3771973	0.18
945.0125122	3.81
963.4297485	0.63
981.3579712	0.17
982.8166504	5.10
983.4292603	0.24
1000.8427730	0.11
1007.3522950	0.16
1057.0817870	0.52
1076.8801270	5.53
1077.5965580	0.10
1095.0271000	0.68
1095.7751460	0.14
1096.7728270	1.42
1114.5950930	6.83
1115.2077640	9.83
1115.9235840	0.43
1116.9526370	0.15
1133.3477780	0.13
1134.7846680	0.11
1208.7707520	0.46
1210.3758540	0.22
1211.3374020	0.18
1226.4598390	0.09
1227.1553960	0.20
1228.0865480	0.82
1229.1807860	0.94
1245.0701900	0.12
1246.9588620	14.40
1247.6959230	0.22
1248.4637450	0.42
1264.3201900	0.49
1265.2204590	0.09
1266.0848390	0.35
1266.9555660	4.01
1267.5588380	0.65
1378.9688720	1.66
1399.1962890	1.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2033
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
263.1284485	0.07
292.1805420	0.07
297.1713257	0.12
300.9970703	0.18
307.3391418	0.03
319.9172363	0.04
321.1774292	0.05
323.9231567	0.05
325.1555176	0.21
329.1234131	0.15
334.9499512	0.06
337.0061646	0.07
345.1845703	0.15
351.3414917	0.06
353.2155762	5.71
353.8799438	0.09
354.5751953	0.06
355.2164307	0.03
361.0638428	0.02
365.0842896	0.56
367.3240356	0.10
377.0765991	0.03
379.3208618	0.09
383.1405029	6.04
389.3366089	0.08
391.2854614	0.12
393.0538330	0.35
395.2300415	0.19
396.1901245	0.03
397.1925049	0.33
407.0751953	0.14
409.1961670	0.14
411.1483765	0.11
413.2344971	0.99
414.2761230	0.06
416.9666748	0.14
419.0123291	0.18
425.3614502	0.12
427.2479858	0.22
431.3258667	0.07
432.1984863	0.19
433.6417236	0.03
437.3574829	0.39
439.1400757	0.08
443.1718140	0.40
447.5128784	0.04
455.2770386	2.35
467.1541748	0.21
471.2838745	0.08
473.1584473	35.23
474.1101074	1.37
483.4585571	0.10
485.3699341	3.38
486.4425659	0.07
499.4247437	0.15
501.1826782	0.13
503.2832642	15.16
504.4276123	0.20
510.2152710	0.18
512.9493408	0.07
515.1908569	29.82
516.2955933	0.26
517.2855835	0.28
527.3500977	0.57
529.4519653	0.22
533.3416138	1.77
539.3521118	0.13
541.4467773	0.32
545.1989136	12.87
546.3502808	0.28
551.0923462	0.28
554.7481079	0.21
557.1881714	2.38
559.3336792	0.40
560.6848755	0.07
563.1847534	0.03
565.2410889	0.05
573.1121216	1.16
575.2544556	7.38
576.5617065	0.03
581.1702271	0.38
587.3749390	0.97
591.1841431	0.39
593.2875977	64.25
594.4276733	0.83
599.3973389	1.32
609.3862915	0.04
611.2235718	0.04
617.2329102	3.08
633.1835938	0.16
635.2044067	100.00
636.3276978	1.89
647.2601929	0.22
653.4535522	0.56
665.2557373	18.66
666.5158081	0.47
677.2191772	2.03
679.2053223	0.64
691.6531372	0.03
693.1836548	0.08
695.2911377	1.20
705.2086182	0.06
707.2274780	0.75
708.2407837	0.14
708.9539185	0.30
710.8053589	0.57
711.5226440	0.06
718.9002075	0.39
719.5211182	0.68
720.9678345	0.17
725.2907715	0.23
737.1921997	10.36
738.1516724	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	671.4
Annotation	Guineamide D
Peak:m/z	Relative Intensity
195.0775452	0.03
204.8456573	0.06
223.0703735	0.07
263.2363281	0.06
302.2032471	0.04
329.3706055	1.13
331.0613403	0.05
339.2020874	0.05
341.0606689	0.10
353.2678223	0.27
355.2989502	0.02
357.3829956	0.14
366.2882080	0.04
375.1406250	0.03
433.4444580	0.08
445.4255371	0.23
446.3698730	0.18
447.5505981	0.12
448.5928955	0.18
453.5123291	0.08
463.4107666	15.09
464.4625854	0.94
465.4641724	0.59
471.2042236	0.10
473.3576050	0.06
477.5464478	0.62
483.4068604	0.12
489.3810425	0.96
491.3118896	3.28
493.4234009	1.60
497.2681274	0.47
499.2400513	0.10
500.2983398	0.09
505.4311523	2.54
506.1861572	0.23
507.4102173	3.68
508.5433960	9.43
509.4663696	100.00
510.5332642	4.39
515.4490967	0.05
517.3242188	0.25
519.1283569	0.10
525.4895630	0.31
527.2298584	0.25
533.4766846	1.12
534.1933594	0.03
543.3157349	0.10
549.2401733	0.04
551.4535522	1.22
555.3992920	0.05
556.4689331	0.04
565.6109009	0.26
597.4273071	0.08
608.1223145	0.10
611.2738647	0.18
623.6466675	0.05
625.2261963	0.09
627.0845947	0.62
629.4570312	0.25
632.9978638	0.22
633.6338501	0.08
635.0361938	0.31
651.4620972	0.02
653.3589478	1.52
654.3070068	0.19
656.3639526	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	587.3197
Annotation	Avermectin B2b aglycone
Peak:m/z	Relative Intensity
219.1277161	0.05
232.7644043	0.03
285.1957397	0.03
341.3090210	0.01
365.3873901	0.04
377.3231812	0.11
395.1643066	0.03
400.5287476	0.04
443.4569702	0.03
488.2975464	0.02
489.1744995	0.04
503.4169312	0.02
514.4194946	0.06
527.1473999	0.03
540.9635010	0.11
543.4010620	100.00
544.1015015	0.04
549.4409790	0.03
553.5344849	0.09
569.3170776	0.74
571.6492310	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	757.2134
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
271.1917419	0.19
274.1497498	0.23
292.3407593	0.37
356.2002563	0.10
368.8427124	0.30
390.5828247	0.15
391.9590454	0.06
400.8931274	0.11
417.5357056	0.45
421.2935181	0.22
422.2810059	0.19
458.3597412	0.49
476.7023315	0.14
489.0331421	0.19
500.3331299	0.22
510.4871826	0.21
512.2334595	0.15
517.9608765	0.29
524.1467285	0.44
530.1720581	0.19
542.1364136	0.72
551.6241455	0.13
553.3565674	0.14
554.2232666	0.29
560.4332275	0.14
566.3918457	0.21
572.1012573	1.24
578.1691284	1.97
583.0902100	0.65
584.1156616	0.48
589.1523438	0.08
590.0570679	0.61
593.8103638	0.22
596.0415649	1.29
601.3453979	0.30
602.1266479	2.25
604.0888672	0.22
610.8324585	0.12
612.2141113	1.31
620.1621704	46.57
626.0565796	0.51
637.2421265	2.70
638.2177124	11.49
640.4271851	0.33
643.1904297	0.58
644.1760864	3.91
656.1941528	0.43
661.4960938	1.55
662.3145142	3.86
674.2267456	18.52
686.1439819	4.21
691.6854858	2.97
692.3214111	10.44
697.8984375	0.06
703.2156372	0.22
704.2390747	7.69
722.2118530	44.17
740.1958618	100.00
748.8878174	0.30
750.0076294	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	898.4798
Annotation	Unknow
Peak:m/z	Relative Intensity
254.2330627	0.09
255.4697571	0.07
256.1967773	0.10
257.0566711	0.05
267.6506958	0.08
269.1851807	0.06
278.2616577	0.14
279.2740479	0.33
280.3162231	0.07
284.2636108	1.56
285.1714478	0.82
293.3274536	0.04
296.2659302	0.13
297.0671082	0.13
299.8817749	0.23
301.1008911	0.69
302.2778931	0.12
303.3358459	0.04
307.9550781	0.17
312.5189819	0.04
314.2124939	0.16
315.0192871	0.18
322.2347717	0.07
323.2781982	0.11
325.9574890	0.05
330.1600952	0.17
331.1475830	0.22
340.2398682	0.12
341.2208252	0.09
342.1363525	0.12
346.2843323	0.14
353.2478333	1.17
354.3970337	0.35
356.0502930	0.07
359.6942139	0.06
365.3804321	0.03
368.4271240	0.27
371.2279663	0.92
372.3930664	0.96
373.0657349	0.09
375.9729919	0.06
382.0193481	0.05
385.1449585	0.05
386.0488892	0.16
387.3901978	0.33
388.4946289	0.23
389.4518433	0.24
393.1399536	0.09
396.3569946	0.10
397.3202515	0.11
407.3438110	0.09
409.0150757	1.38
410.0651245	0.45
411.3507080	0.17
415.1948853	1.44
416.3886719	0.11
422.3150024	0.06
425.2457886	0.14
426.4995728	0.27
427.3707886	0.76
428.1794434	0.04
438.0715942	0.13
439.2611084	0.32
440.2045288	0.17
444.2924805	0.57
449.1826172	0.95
450.1550293	0.52
455.2515869	0.22
456.4431152	0.31
457.3287354	0.15
466.0961914	8.43
467.1387329	10.29
468.2431641	0.09
472.3363647	0.80
473.0929565	0.39
474.0997925	0.13
482.6010132	0.06
483.4310303	0.14
484.3469849	0.32
485.2402344	0.49
494.4783325	0.07
495.0956421	0.20
500.7084961	0.38
502.1571045	0.38
503.1038208	0.07
504.1932373	0.05
505.2841797	0.13
511.5147705	0.39
513.4866943	0.05
521.2055664	1.21
522.1397095	0.68
525.1291504	0.14
526.4058838	0.07
528.4547729	0.95
529.2926636	0.52
532.5033569	0.02
534.2153931	0.17
537.4367065	0.04
539.6817017	0.13
540.2945557	0.05
540.9066162	0.06
542.4873047	0.11
544.1569824	0.11
550.4506836	0.07
551.1528320	0.07
552.8621216	0.46
553.6130371	0.03
556.2609253	0.19
557.3611450	0.93
558.2655029	0.28
559.4658813	0.51
560.1867065	0.15
562.6147461	0.21
563.4043579	0.03
564.5900269	0.08
568.7935791	0.96
569.7702637	1.79
570.3760376	1.14
579.9918823	0.94
580.6911011	0.12
581.4113159	0.62
582.2782593	0.15
585.5706177	0.79
586.2824097	0.80
587.2742310	0.04
588.2145996	0.57
590.2518311	0.34
591.3529053	1.33
595.3173828	0.11
597.1640015	11.10
598.2664185	20.90
600.3294067	0.19
603.4313965	0.06
604.2666626	0.17
607.9243774	0.34
608.6205444	0.10
609.9318848	0.41
614.1392822	0.60
615.2779541	2.43
616.3871460	3.22
619.8828735	0.13
621.5154419	0.20
623.5773315	0.06
624.6520386	0.06
625.3717041	0.11
626.4567871	0.63
634.3456421	0.16
636.3848267	0.03
637.9837036	0.82
638.6791992	0.03
642.2178345	0.41
643.2676392	0.12
644.4031372	0.10
645.4678345	0.18
646.3396606	0.28
650.3793335	0.12
654.0229492	1.52
655.2192993	2.14
655.8480225	0.06
663.8670654	1.00
668.1823120	0.22
671.5580444	0.70
672.2905273	1.05
673.2875366	1.16
676.5587769	0.19
677.4030762	0.07
678.4084473	0.11
681.5701904	0.31
682.4594116	0.33
683.2947388	0.12
684.2142334	0.21
685.6394653	0.03
692.6281128	0.73
693.5017700	1.17
694.4372559	1.56
695.4060059	2.65
698.4165649	0.10
699.4112549	1.11
701.4739990	0.47
705.0325928	0.23
705.7506104	0.17
710.4832153	3.72
711.4303589	8.46
713.3543091	0.38
720.9409180	0.07
721.5626221	0.15
722.2338867	1.71
723.3612061	1.45
724.6000977	0.15
728.2737427	0.09
729.4547119	1.24
733.0795898	0.19
734.4454956	0.93
738.5147095	0.76
739.3037109	1.48
740.3340454	1.68
741.3427124	1.28
745.4607544	0.05
749.3742065	1.42
750.3554688	3.99
751.4479370	0.11
752.3826294	1.12
756.3348389	0.26
757.3402710	3.01
758.4137573	1.36
763.2988892	0.05
764.3809814	0.96
766.8757935	0.72
767.6842651	3.47
768.3687134	22.01
769.5021362	0.18
770.5338745	0.14
777.8373413	0.11
783.3870239	0.18
784.4840698	0.67
785.4581909	6.55
786.3345947	29.71
786.9513550	0.77
793.4480591	0.06
796.1943359	0.37
797.5053101	0.12
800.9078979	0.18
802.1714478	0.10
805.4960327	0.56
806.6153564	0.05
807.4154663	0.09
811.2254028	0.28
812.1166382	0.11
812.7472534	1.36
814.6536255	0.22
820.6240845	0.07
823.4667969	32.38
824.5006104	0.22
825.8404541	0.17
826.5518188	0.03
829.3423462	0.07
830.5521851	0.18
835.2751465	0.17
836.3883667	4.23
837.7581787	0.33
841.7877808	0.30
842.3944702	0.15
845.6587524	0.16
851.3946533	1.68
853.1695557	7.69
854.3073120	9.00
855.6932373	0.63
862.7856445	0.97
863.4299927	3.38
864.4616089	0.87
869.3541260	0.61
870.3373413	1.09
871.3280640	23.59
872.0911255	0.07
880.9049683	8.26
881.5053711	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	463.4043
Annotation	Halicyclamine A
Peak:m/z	Relative Intensity
144.8907013	0.16
174.6682739	0.08
183.0523682	0.08
198.9878540	0.19
207.1199188	0.06
214.3937073	0.31
215.0468445	2.20
215.9430084	0.10
218.8836670	1.65
220.2174072	0.11
227.2675781	0.06
232.5121460	0.06
234.5451202	0.08
239.8158264	0.15
241.0859528	0.07
241.8107605	0.05
244.2708740	0.07
255.3041077	0.08
296.0573120	0.09
310.3006897	0.07
313.3543396	0.14
317.0889893	0.11
321.3880005	0.48
328.8624268	1.97
329.9291382	0.36
331.0631714	0.23
332.8002625	4.80
333.8658142	1.34
344.9418945	2.19
345.8227539	0.70
346.9083252	7.86
348.8811951	100.00
349.8798218	7.42
351.4608459	0.29
352.9501343	0.33
353.7929077	0.04
361.9125061	0.25
362.9679565	0.11
363.9921875	0.32
365.2560425	1.54
366.3292847	4.83
369.7288208	0.08
371.8164978	0.12
372.7370911	0.48
383.7797852	0.21
388.3629150	0.27
390.3694153	0.09
390.9779968	0.56
398.9281006	0.04
404.0999146	0.20
408.0873718	0.18
410.2343445	0.11
416.6182861	0.51
417.3068542	1.39
418.2203979	0.59
419.2548828	0.26
419.9608459	0.14
422.4475098	0.11
427.0230408	2.86
434.3997192	0.43
436.1676025	0.35
441.5655518	0.61
442.9237976	8.67
443.9438782	0.78
445.9714661	0.49
449.6913147	1.30
450.8012390	0.43
451.6171265	3.22
452.9459534	0.04
455.0099182	0.13
455.6779785	0.55
458.8584595	1.02
460.5692444	0.16
462.9235535	0.27
474.8234558	0.39
483.2842102	0.05
523.6733398	0.13
525.6029663	0.24
546.6697998	0.14
552.3757935	0.56
556.8502808	0.64
567.0584717	0.59
572.6748657	0.40
581.9868774	0.04
588.6797485	0.05
670.7714233	0.15
686.9026489	1.26
710.9695435	0.04
712.8151245	0.19
729.9719849	0.05
730.7487183	0.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1874
Annotation	4,2'-Dihydroxy-4',6'-dimethoxychalcone 4-apiosyl-(1->2)-glucoside
Peak:m/z	Relative Intensity
170.9660034	0.04
175.0048981	0.27
176.8383331	0.02
179.8677063	0.09
183.1821289	0.09
184.9996796	0.03
187.0109100	0.10
188.1260681	0.04
189.2393951	0.04
195.0236511	0.02
196.8938141	0.08
198.0074005	0.03
199.0052948	0.14
199.9566650	0.08
201.1134644	0.06
204.9896240	0.21
206.1299744	0.06
208.1462708	0.04
209.1283417	0.02
211.0012817	0.03
215.1636963	0.16
216.8497009	0.03
223.1177368	0.33
225.1336365	0.13
226.1908722	0.21
226.9319000	0.11
228.1010284	0.21
241.1690369	0.12
243.0739899	1.80
247.2611084	0.02
250.2006836	0.01
255.0114441	0.03
257.0458984	0.14
265.2926331	0.16
267.0510254	0.07
270.1604614	1.09
283.1126099	0.09
285.0804443	100.00
286.1594849	0.34
287.0371094	0.25
293.9807739	0.07
299.1547241	0.16
309.2130127	3.55
309.8829956	0.05
310.9117737	0.14
325.3063965	0.03
327.1218262	0.50
330.4791260	0.02
339.0641479	0.41
341.2044678	0.20
351.1140137	0.40
352.6572876	0.07
353.3028564	0.37
356.6258545	0.02
369.3009644	0.02
373.3494263	0.08
375.1632080	0.06
383.3191528	0.14
384.2667847	0.06
387.8440552	0.15
388.9462891	0.14
397.0803223	0.04
425.1158447	0.05
431.2293091	0.16
443.2171631	0.20
446.0888672	0.02
447.3101196	0.24
449.2499390	0.49
455.3691406	0.03
473.2297363	1.34
485.4263306	0.04
491.1497192	0.12
503.2453003	0.87
504.2396851	0.02
517.1964722	0.03
531.2197876	0.05
547.4427490	0.04
575.3756714	0.37
578.0901489	0.64
579.3614502	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1298
Annotation	Galactotriose
Peak:m/z	Relative Intensity
200.9374695	0.64
247.1820984	0.15
321.2099609	0.13
336.7948608	0.07
363.0863037	6.01
364.1286011	0.82
368.9906006	0.15
375.1281738	0.33
381.0751953	100.00
382.0787964	0.32
393.2548218	0.18
397.1201782	0.12
410.1685791	0.25
411.1052856	0.47
423.3416748	0.21
445.0653076	0.27
471.2191772	0.16
483.0623779	0.73
499.3805542	0.20
506.6119995	0.04
525.0070190	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	629.2084
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
179.0916290	0.18
195.0735779	0.02
199.1872864	0.02
221.2790680	0.08
225.0404663	0.07
299.1855469	0.02
305.1105347	0.05
316.2943115	0.06
320.3157349	0.04
323.1384888	3.73
345.1832275	0.03
383.1151733	0.20
420.5209351	0.05
422.8815918	0.03
424.1467285	0.06
425.1274414	0.04
463.5148926	0.09
467.2040405	0.26
485.2120972	100.00
485.8424683	0.22
527.2571411	11.19
528.2764893	0.03
566.6739502	0.09
567.3070679	0.72
583.2068481	0.02
585.3411255	0.08
593.2116089	0.02
598.3954468	0.04
607.3539429	0.13
611.2367554	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	293.1242
Annotation	Ethyl (S)-3-hydroxybutyrate glucoside
Peak:m/z	Relative Intensity
85.0641022	1.66
87.3157120	0.20
88.9006348	3.72
94.9950714	0.51
97.0496216	0.24
98.8981857	0.07
100.9948730	4.76
111.0411682	0.09
112.9411545	6.87
114.9346390	0.99
118.3645172	0.41
119.0060577	6.05
125.0700531	0.68
126.9756012	1.94
129.0598450	0.79
131.0258484	100.00
131.7695923	0.04
137.1217041	0.09
142.9899292	3.14
144.9909668	0.16
148.8175812	0.37
155.1590271	0.32
158.9406738	0.16
160.9755402	0.91
169.0018463	0.17
173.0663452	9.38
178.9252777	1.45
185.1268921	1.20
191.0948944	0.18
199.1271667	0.31
203.1464844	0.92
205.1101990	0.15
221.0289612	0.15
231.2248230	0.09
233.1192627	0.27
247.0967102	0.63
249.0244141	0.30
274.8931274	0.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	985.1896
Annotation	Unknow
Peak:m/z	Relative Intensity
317.1414795	0.15
347.1347046	0.13
358.8217163	0.24
377.2727661	0.70
407.1787720	0.09
439.0297241	0.03
457.2180786	0.06
490.8760071	0.24
508.0270386	0.48
509.0607910	0.53
541.1005859	0.32
569.0150146	0.15
570.0216675	0.12
571.0469360	0.45
581.0910645	0.13
603.1713867	0.16
611.0960693	0.19
612.6955566	0.09
629.2298584	0.15
639.7678833	0.11
641.0627441	2.67
643.2037964	1.18
645.2588501	0.16
659.1815186	0.16
661.1385498	3.00
700.5275269	0.37
702.1521606	0.66
703.1436768	0.53
733.2069702	0.39
760.8963623	0.21
774.5140381	0.23
775.2070312	0.20
791.2374268	0.26
793.0905762	100.00
793.7645264	0.36
805.2076416	0.05
833.0347900	0.16
853.3973389	0.24
967.5734863	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	690.29
Annotation	Unknow
Peak:m/z	Relative Intensity
193.0694733	6.92
193.8860168	1.09
195.1435394	0.83
203.0349121	5.35
204.1208801	0.16
204.9363251	0.23
216.6920471	0.06
219.8120728	0.13
222.7762451	0.05
231.0544434	0.16
233.0994568	0.37
235.2438812	0.18
243.1407013	0.08
245.1213379	0.79
255.3720551	0.08
256.2713623	0.35
260.9259644	0.13
269.0966187	0.05
271.1673889	0.24
273.0957642	0.09
281.1130371	0.08
282.8235474	0.08
285.1905518	0.20
286.1304321	0.26
287.2109985	0.16
298.1640015	0.06
301.9188232	0.08
303.7275696	0.17
315.9434814	1.27
317.0237122	3.91
318.0408936	0.05
320.9830933	1.81
321.7008667	0.71
324.1680298	0.23
324.7785645	0.04
329.0784302	19.83
330.0933228	3.97
331.0545654	0.39
334.0958252	0.04
339.0944519	1.47
340.2097168	0.44
341.4854126	0.69
349.9501648	0.14
353.5397339	0.27
356.8974609	0.13
358.1309814	0.03
359.0135498	0.09
362.1560059	0.10
371.2088013	0.43
372.3181152	0.57
373.1439819	0.19
379.1476440	0.08
383.1767578	0.48
384.3973999	1.50
385.2890015	2.71
386.1653442	21.09
388.8126221	2.82
389.6807251	1.14
391.6652222	0.30
393.2329712	0.17
394.0744629	0.06
395.2042236	0.76
395.9655151	0.34
397.0004272	0.32
418.1044922	0.50
429.4908447	0.05
436.8981934	0.12
448.0936279	0.08
449.0270386	0.05
452.1064453	6.03
453.0587769	1.06
455.2880249	0.10
457.1290283	7.53
458.0830078	0.72
466.3872070	0.36
477.7447510	0.33
484.5029297	0.03
485.8602295	2.93
488.8854980	0.10
492.0169678	0.03
495.2111816	0.52
519.9799805	9.59
520.7463379	7.80
521.6531372	0.13
523.1305542	0.18
524.9505005	4.77
525.7042236	2.29
526.3369141	0.33
530.5344238	0.06
535.4561157	0.06
540.4929199	1.23
541.6652222	0.19
544.9711304	0.18
545.6920776	0.40
549.2427368	0.05
552.3828125	0.97
553.8063354	17.23
554.7547607	0.23
555.8295898	0.42
562.9356079	0.15
574.1892700	0.25
575.1347046	0.70
576.2736206	0.90
577.2632446	0.46
578.3685303	0.08
584.0238647	0.11
585.0211792	0.38
586.2023926	0.44
587.1377563	0.50
587.9236450	0.33
590.0990601	0.13
619.7954102	0.05
621.0263062	20.30
621.8399048	100.00
622.8348999	1.32
624.1503296	0.60
625.5540771	0.24
627.3026733	0.13
630.9384155	0.49
631.5889282	0.04
632.4011841	0.25
633.0066528	0.16
640.4028931	1.20
641.0722046	0.81
642.1498413	0.15
643.0386353	0.04
643.7692871	0.15
645.2861328	0.07
646.0669556	0.10
652.7771606	0.10
655.2215576	0.18
657.4250488	0.18
658.3662720	0.44
659.1445923	0.29
671.6541748	0.17
673.1006470	0.12
675.0048218	0.06
676.0700684	0.22
690.3613892	0.44
709.1521606	0.28
710.6348267	1.74
711.3886719	1.18
712.1831665	0.69
713.3356323	7.65
714.1465454	1.77
720.6813965	0.15
721.5147705	0.36
722.4360962	0.58
723.1272583	0.60
723.9088135	0.54
753.8516235	0.13
766.0414429	0.46
767.0197754	2.35
767.9133911	0.83
776.0549927	3.24
777.0571899	5.74
778.1310425	3.17
778.8672485	0.98
785.1211548	0.05
788.0982666	0.75
789.0726929	1.03
790.2668457	0.36
795.7990112	0.07
805.8059082	0.05
818.4298706	0.03
829.9186401	0.46
835.3945923	0.34
848.9356079	0.15
902.0725708	2.49
903.2085571	12.79
904.2622681	5.80
905.0441284	5.30
905.9370728	0.30
910.7424316	0.07
912.0734253	12.53
913.0656738	34.83
914.0781250	23.92
914.9744263	8.75
915.7871704	0.33
943.8146362	0.11
952.4626465	0.22
953.1926880	0.15
955.2859497	0.12
968.1184082	0.14
970.0431519	0.08
980.8718872	0.09
1037.5634770	0.08
1039.1931150	0.03
1040.9929200	10.73
1042.0737300	2.32
1042.6800540	0.12
1048.8554690	0.06
1049.8492430	0.51
1051.2585450	0.47
1051.9565430	0.13
1105.4019780	0.43
1106.5162350	0.55
1107.1994630	0.07
1240.9011230	0.36
1241.5858150	1.29
1242.4190670	0.85
1243.1776120	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	408.1277
Annotation	Unknow
Peak:m/z	Relative Intensity
119.9282913	16.32
122.2294922	0.09
126.7452011	0.40
137.9979706	21.03
139.0367126	0.14
144.0933685	0.23
150.8707275	0.40
153.0699158	0.28
161.7895203	0.18
162.7798767	0.05
168.8054504	1.47
173.7317810	0.14
174.9611511	0.58
177.5455627	0.15
180.0648499	10.73
183.1053772	0.46
185.9172974	0.25
187.1870270	0.11
187.8482361	0.15
191.0049744	0.64
192.9579163	1.36
196.9597473	0.09
199.0909576	0.77
201.1004639	0.10
204.0740662	0.94
206.0968475	0.25
210.9986572	0.08
215.8941345	0.20
217.0436096	11.05
222.0849457	8.99
233.2112732	0.31
235.0521545	22.05
240.1003723	36.16
246.0840759	2.06
251.9194031	0.13
253.0414429	5.83
261.2578125	0.22
261.8914795	0.18
264.0351562	5.49
266.2985840	0.23
269.9054565	0.13
273.9321594	0.07
276.2116699	0.18
278.2221985	0.20
279.2602539	0.43
279.9959106	0.40
282.1024780	100.00
285.9676819	0.14
288.0626831	0.34
294.2312622	0.22
297.7544556	0.87
299.2828064	0.19
300.1444702	0.14
310.2123413	0.58
311.2748718	0.28
312.0565796	0.25
318.4258423	0.55
325.2949524	0.20
327.2926331	0.10
333.6333008	0.06
336.1396790	2.92
337.2349548	1.55
338.0725098	0.25
341.8878174	0.77
344.0616455	0.07
346.3958740	0.22
349.0565491	0.09
350.6755676	0.49
351.5842896	0.16
352.3655701	0.41
354.1655273	7.32
362.3417053	0.35
363.5913391	0.50
364.2688293	7.40
365.0386658	0.27
366.6289673	0.97
367.2832336	0.17
372.1116028	60.61
372.7214050	0.34
373.3918152	0.17
376.4319763	0.19
378.0850220	0.15
380.1797791	0.07
390.0778503	40.82
391.0791626	0.52
392.7439270	0.83
396.6148376	0.20
398.9821167	1.18
407.7976379	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.1
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
191.0584412	0.01
251.2070618	0.04
269.1218262	0.27
281.3756714	0.03
283.2138062	0.33
284.2203369	0.05
295.0936890	0.03
297.1155701	0.10
309.1438599	0.07
311.0915527	100.00
312.1793213	0.41
321.2179565	0.12
323.1456299	0.77
324.9390869	0.06
333.1492310	0.05
335.2198792	0.04
337.2112732	0.16
341.0880127	26.54
342.1820068	0.18
349.1862183	0.01
351.3366089	0.02
353.2030334	1.32
355.2326965	0.68
365.1312256	0.18
366.2174377	0.02
366.9712219	0.36
370.4001770	0.13
371.1206665	0.55
377.2011719	0.35
383.1527710	0.99
389.3776550	0.02
395.1534119	0.65
413.2166443	4.95
414.4958496	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	377.1818
Annotation	Unknow
Peak:m/z	Relative Intensity
129.1833191	0.06
158.9634705	0.06
161.1055298	0.51
235.0879517	0.04
267.2392578	0.03
315.5710144	0.26
317.4310303	0.05
329.3572388	0.04
331.1728516	100.00
333.1449890	0.30
359.2968445	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1505
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
221.2305450	0.15
233.1565247	0.02
251.3418274	0.07
256.9231262	0.03
263.1871033	0.03
282.2775574	0.10
283.2511292	0.14
297.0173340	0.18
305.0157776	0.04
306.8271179	0.03
308.0547485	0.06
311.0650024	0.32
323.2903442	0.23
325.2556152	0.28
333.3104858	0.11
335.2350464	0.54
341.1392212	0.09
347.3037109	0.11
351.5687866	0.15
353.1657715	35.65
354.2393188	1.22
363.1932373	0.20
365.1232300	0.87
366.3013916	0.05
367.3690186	0.26
377.2169189	0.06
378.7795410	0.06
379.4140625	0.11
383.1287842	18.68
384.3308105	1.06
389.0054321	0.03
391.4201660	0.13
392.2330322	0.06
392.8962402	0.18
395.2162476	1.72
397.0704346	0.72
398.2814941	0.10
406.9556885	0.05
408.3613281	0.04
409.1780396	0.33
411.3324585	0.09
413.1047974	2.73
414.1456299	0.02
416.2313232	0.03
419.1138306	0.15
421.6681519	0.13
423.2827148	0.14
425.2262573	0.80
426.2495117	0.10
437.1067505	0.64
437.9009399	0.10
438.8803711	0.02
443.1851196	0.42
448.9106445	0.12
455.2274170	4.65
456.2562256	0.09
457.4229736	0.04
467.2917480	0.27
468.1380615	0.06
471.3748169	0.55
473.1588135	100.00
474.1881104	4.19
479.1520996	0.04
483.3978271	0.26
485.2199097	3.73
486.3411865	0.22
487.1898193	0.21
499.1730957	0.22
501.0121460	0.03
503.2130127	32.32
504.2271729	2.18
509.1951294	0.15
515.2304077	2.19
516.1885376	0.23
517.2612915	0.66
527.2569580	0.04
529.4641113	0.16
531.0682373	0.10
533.1851196	2.50
533.8405762	0.04
534.5956421	0.03
539.2509155	0.37
545.2215576	2.09
557.0736084	0.98
558.3152466	0.19
563.3223267	0.11
564.3407593	0.06
575.2238159	10.83
576.2947998	1.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	446.1501
Annotation	Unknow
Peak:m/z	Relative Intensity
133.9909821	0.09
134.9058380	8.23
135.8764496	0.21
152.0046997	100.00
153.0573730	0.23
157.8782959	0.05
167.1519470	0.39
186.2343140	0.09
240.2142029	0.06
244.2993164	0.13
260.9841614	0.57
266.0547485	0.26
266.7972717	0.07
284.1669617	1.31
296.3506775	0.27
314.1113586	0.27
330.2786865	0.15
331.0545044	0.18
337.4106445	0.11
350.4147339	0.16
358.3538818	0.17
402.0220642	0.41
411.3764038	0.05
428.0780945	0.62
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	675.21
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0257416	0.13
206.9537048	0.03
225.1099243	7.36
267.3123779	0.10
369.1570435	0.33
387.2207642	31.22
411.4194946	0.13
425.3124390	0.06
429.2070312	7.68
467.0244751	0.03
469.1411133	0.92
471.1370850	0.50
486.9647217	0.34
495.2058105	0.06
531.2058716	100.00
573.2229614	9.95
591.4585571	0.14
607.4251099	0.06
613.2355957	1.69
631.0336304	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	529.2427
Annotation	Satratoxin H
Peak:m/z	Relative Intensity
152.0729218	0.16
153.2061920	0.32
155.0810852	0.29
157.2979126	0.74
159.3335266	0.66
161.0455017	8.60
163.1954803	0.36
165.3307343	1.03
167.9700623	0.68
169.0492401	1.64
170.9675293	2.69
172.9189453	1.81
175.1723938	3.73
176.8685760	2.49
179.0292053	0.87
181.2607727	2.80
182.9926758	0.42
185.0614624	3.62
187.0721741	5.72
189.0614624	2.05
191.2490234	1.25
192.9621429	1.86
195.0937347	0.83
197.2156219	1.04
199.0121460	1.33
201.0755005	0.88
203.0683289	5.55
209.0792542	0.49
211.1369171	4.96
213.0080719	6.45
214.1688232	0.42
215.0826569	11.43
217.1219635	4.44
219.2015991	1.77
221.3238068	1.09
225.0466003	1.23
227.0560303	1.22
229.1016541	1.03
231.0651245	2.83
233.1374054	1.23
235.2772217	0.97
237.1392212	1.63
238.9671936	2.38
241.0556335	2.57
243.2167969	0.61
245.1760559	9.53
247.1875916	0.79
249.1604004	1.36
251.2330475	1.23
252.1239624	0.15
253.2839355	1.02
255.1563568	0.69
257.4563599	1.12
259.0792542	5.15
261.1213379	2.89
263.2542114	3.83
265.0953369	1.43
267.1816711	0.29
269.2326050	2.22
271.2785034	1.29
273.2977600	2.59
275.2508850	1.13
277.1697998	3.24
279.2601929	4.19
280.9741516	1.96
283.1848755	2.07
285.0713501	1.51
286.9286194	1.45
287.5494995	0.42
289.1546326	1.36
291.3172607	1.36
293.1678467	2.52
295.3677979	2.62
297.2926636	0.94
299.2912292	3.09
300.8966064	3.81
303.1196899	2.01
305.4488525	2.37
307.1833496	5.35
309.0695801	1.55
311.2111206	5.48
313.2376709	2.61
314.1517334	0.88
315.4067993	2.33
317.1845703	3.85
319.2291260	1.28
321.1744995	5.27
323.1876831	3.99
325.1282349	2.26
327.4589233	1.82
329.1643677	4.39
331.1403809	2.17
332.8419189	7.56
333.4491577	0.90
334.7960815	2.64
335.3990479	2.44
336.1018066	0.52
337.5233765	2.66
338.7767944	0.84
339.4011230	3.83
341.2472534	2.06
342.1054688	0.24
343.1761475	0.72
345.2810669	6.88
347.2230225	5.41
349.3655396	12.07
351.3132935	9.84
353.1750488	0.64
355.3310547	2.35
357.0680542	3.75
357.6738892	1.05
358.5892944	1.38
359.2373657	1.47
363.2101440	5.84
363.8216553	0.89
365.3179932	7.11
367.2633057	13.14
369.5005493	0.70
372.1455688	0.57
373.2908936	13.41
375.2825928	6.20
377.2554321	8.87
378.3099976	0.66
379.2257080	0.52
381.2550659	3.74
382.1171265	1.55
383.2796631	6.00
384.9171143	3.25
387.4133301	0.50
389.2659302	6.54
391.2453003	13.21
393.2650757	28.20
394.6160889	1.92
395.3331299	12.01
397.2901611	1.57
401.1016846	4.02
405.3593750	12.30
407.3480225	16.47
409.2146606	9.78
411.2671509	1.78
412.1095581	0.87
413.3512573	0.76
415.1292725	5.82
419.2730103	12.60
421.4596558	0.33
423.2395630	21.24
425.3156738	100.00
427.1942749	7.50
433.2510376	13.22
437.2928467	8.48
440.0252686	0.78
441.2597656	3.38
443.4773560	1.43
447.5800171	0.54
451.2137451	34.40
453.2993164	1.93
455.1130981	1.98
461.1224976	0.75
465.3630981	4.79
467.0106201	1.73
469.3227539	49.37
472.8557129	0.64
479.0103760	0.35
481.3588867	2.11
483.1669312	32.72
485.1112061	7.28
487.3195801	5.38
493.3024902	2.34
497.4489136	1.20
501.3823853	1.47
511.1677246	12.84
511.8429565	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.05
Annotation	Unknow
Peak:m/z	Relative Intensity
202.9827118	0.62
220.9538574	0.09
223.0567932	0.09
227.3798523	0.04
229.1189880	0.19
230.9418030	0.25
238.9091492	0.32
243.0320435	0.26
245.1217346	0.16
248.9289856	1.80
257.1299744	6.93
262.8415833	0.69
266.9666748	0.07
270.9272156	1.26
275.1717224	0.06
278.3869934	0.11
281.2764282	0.11
285.1537781	0.63
287.0172729	0.16
289.0237732	1.53
315.0438843	0.65
317.0734253	0.57
321.2463379	0.16
328.9768066	1.74
332.9025574	5.92
333.5626831	0.15
341.1712952	1.10
342.4338989	0.34
343.0685120	1.20
344.6766968	0.11
347.0010376	14.34
349.2945557	0.18
351.4272766	0.37
356.7664185	0.91
357.8076172	0.15
358.9519348	2.51
361.0524597	31.46
362.9768372	0.29
364.6414795	0.16
370.9179688	0.17
372.9767761	0.85
375.1295776	6.79
377.0633850	3.29
378.6450500	0.04
386.5692444	0.81
387.2289124	0.27
390.9795532	9.06
391.9647217	0.71
393.1033936	0.94
395.0465393	0.25
397.2742920	0.05
400.9262085	1.70
405.0622253	55.39
408.0646057	0.24
408.6670837	0.27
414.3974915	0.13
418.9553833	100.00
419.6389771	0.74
422.7460938	0.86
436.4647827	0.39
437.1242065	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	311.1687
Annotation	5S-HETE-d8
Peak:m/z	Relative Intensity
113.104187	0.43
118.7827225	0.19
120.1415787	0.29
129.219574	0.57
129.9216309	0.58
167.1952515	0.28
170.0797424	4.38
181.0360413	0.66
183.0138245	100.00
183.9622498	17.11
184.8471985	0.28
197.0875549	13.37
198.167099	9.03
198.994751	1.50
211.2136841	1.00
212.1329651	0.43
217.0092163	0.55
225.1958923	1.77
226.1273499	2.13
235.2158203	0.43
238.9629211	2.52
239.9736023	2.97
241.1761169	0.92
243.0764771	0.21
247.3283691	6.56
248.3382568	1.16
249.3023682	1.39
253.3042908	1.72
254.036499	0.10
255.267334	0.74
267.260437	5.99
269.196167	0.41
270.4905396	0.32
271.3124084	0.19
279.0908508	0.11
283.0479126	7.90
290.9881592	0.66
293.3181763	15.18
311.2549438	19.60
312.3780518	2.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	489.1824
Annotation	Unknow
Peak:m/z	Relative Intensity
152.9039001	0.11
155.0487518	0.08
160.0655823	0.20
170.9547424	0.26
173.2310944	0.11
175.5874023	0.04
191.0216064	100.00
207.1235046	0.05
258.8883667	0.06
278.3232117	0.03
297.1999207	0.35
298.2905273	0.05
299.0828857	0.17
311.2943726	0.03
341.2293091	0.09
355.4063721	0.07
356.5878296	0.40
357.2041016	0.22
357.9421997	0.74
360.0322876	0.05
367.8011169	0.05
370.9924316	0.21
373.3135376	0.08
375.7409973	0.09
383.2137146	0.04
384.9053040	0.06
394.6951599	0.40
401.1996765	0.16
410.2043152	0.09
413.3981628	0.10
415.0722351	0.07
425.8659058	0.28
428.1164246	0.24
429.1406555	0.26
442.0773621	0.10
444.1584778	3.73
446.0388794	3.35
455.2356567	0.06
458.9969788	0.04
467.1978149	0.12
471.3224487	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	193.0491
Annotation	Aporpinone B
Peak:m/z	Relative Intensity
76.9170380	0.24
78.9932175	0.10
81.2195587	0.39
89.0291596	0.34
90.9151306	0.88
92.9028473	0.77
95.0385437	0.16
104.9219513	0.16
105.9347992	0.49
108.9855957	1.28
116.9499664	0.38
117.9964905	0.06
120.9099426	6.05
121.9341125	0.42
125.0056915	1.19
133.8822479	0.52
136.9783020	15.27
138.0819855	0.90
148.9720001	100.00
150.0485992	3.42
161.1069794	0.18
164.9687653	9.86
166.0398407	0.35
174.9644012	0.40
192.9469757	3.45
194.2790070	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	418.8942
Annotation	Unknow
Peak:m/z	Relative Intensity
158.7630615	0.06
174.9775238	1.47
215.1396790	0.08
245.0555725	0.23
272.9463196	0.07
273.9931946	0.06
276.8855591	0.06
288.9525452	26.16
303.2188721	0.02
304.9391479	100.00
345.0192566	0.37
363.3035278	0.22
373.2179565	0.13
374.0836487	0.05
375.0480957	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0877
Annotation	Phaseoloidin
Peak:m/z	Relative Intensity
107.9812393	1.14
111.0330200	0.04
112.9765472	0.04
121.0978165	0.04
122.9300766	1.44
129.0389404	0.21
146.9732056	0.20
149.9076538	0.11
152.0430908	4.09
166.9850159	100.00
172.7296295	0.14
180.8164062	0.02
190.9676208	4.42
209.0857544	3.15
210.7727051	0.05
229.0704346	0.09
239.1944885	0.02
243.1398315	0.03
257.0733948	0.06
267.0167542	0.08
269.1303711	0.45
282.8472290	0.04
284.2979126	0.02
285.1697998	0.38
287.1757812	0.09
310.9462891	1.24
314.1408386	0.12
314.8472290	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1612
Annotation	Butrin
Peak:m/z	Relative Intensity
179.2434692	0.04
191.2597351	0.02
198.8307343	0.06
213.0226135	0.03
221.0178375	0.07
271.1409302	0.02
287.3638916	0.02
293.4257507	0.06
298.1299744	0.02
312.2421875	0.20
315.0424805	0.47
326.1415405	0.10
327.2543945	0.09
336.0330811	0.03
341.1915283	1.23
342.3214111	0.03
351.3148804	0.07
353.0335693	0.03
355.4196167	0.22
357.3918457	0.03
364.9581909	0.03
366.1320801	0.01
367.2192993	0.11
368.0950928	0.02
370.1842041	0.04
371.3137207	0.43
380.9329834	0.22
383.1398926	34.17
384.2998047	1.18
385.1187134	0.07
387.0678711	0.06
389.4049683	0.02
393.1509399	0.02
395.0620117	0.44
397.3522949	0.10
398.1304321	0.15
399.0477905	0.03
409.3290405	0.09
410.4074097	0.03
413.2185059	14.83
414.2322998	0.32
422.3900757	0.05
425.0632935	0.87
426.1326294	0.06
427.1559448	0.85
428.2863159	0.02
437.1787720	0.05
439.1951904	0.20
443.2338257	1.40
443.8760986	0.03
447.2485352	0.06
449.4893188	0.05
450.9881592	0.09
455.1213989	0.71
457.6337891	0.06
460.2001953	0.03
461.2086792	2.28
467.0637817	1.28
471.5803223	0.06
473.2144165	0.19
479.3808594	0.06
485.2446289	2.76
486.2105713	0.04
487.9921875	0.02
488.9762573	0.03
489.6281128	0.14
490.8630371	0.06
496.7982788	0.02
501.2640991	0.11
503.1761475	100.00
504.2223511	2.74
513.3214722	0.51
515.2402344	1.57
516.2012329	0.06
517.2583618	0.06
528.9801636	0.12
533.1902466	14.65
533.9618530	0.41
545.2161255	1.31
546.5464478	0.06
547.3188477	0.43
551.4452515	0.07
556.9888916	0.12
559.2734375	0.05
560.3721924	0.03
561.6947632	0.03
563.2507935	1.05
564.1670532	0.06
569.1469116	0.15
575.2654419	0.71
578.9584351	0.30
587.2653198	0.67
605.2709961	5.13
606.3388672	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	815.45
Annotation	Unknow
Peak:m/z	Relative Intensity
231.0323486	0.21
234.2953491	0.04
240.1268158	0.09
241.2700195	0.07
250.1272430	0.15
259.0362854	0.11
269.9768372	0.14
294.5682373	0.25
299.3742065	0.15
301.0537720	0.50
316.3057861	18.57
318.1492310	1.12
326.4408569	0.25
335.2425537	0.11
347.4006348	0.40
350.4852600	0.06
357.2621460	0.37
363.7912598	0.16
370.3546143	0.05
375.9725952	0.17
379.1102905	0.04
387.6125488	2.17
388.3944702	14.69
390.4697876	0.34
391.4613647	0.21
405.3898315	100.00
406.5703735	0.23
407.4403076	0.42
409.1997681	0.03
423.4747314	7.10
429.6994019	0.05
433.5252686	0.15
445.4174805	0.06
448.3605957	0.48
457.0912476	0.48
477.7639160	0.11
486.5858154	0.09
504.1112061	0.21
506.3994141	0.28
507.2865601	0.54
508.9428101	0.25
535.3952026	0.17
540.9218140	0.09
555.6978149	0.08
560.5927734	0.12
585.5582886	0.17
591.5968628	0.40
593.3862915	0.10
599.2826538	0.33
617.6102905	0.62
627.5666504	0.30
635.2206421	0.07
653.3016968	0.55
669.4356079	0.35
671.5145264	0.10
682.4257812	0.70
691.1997681	0.15
699.8472900	0.54
709.6170044	0.43
711.5977783	0.41
712.7352905	0.29
717.3497925	0.10
723.1972046	0.32
724.9014282	0.11
726.6093140	1.55
729.4791260	7.97
733.3214722	0.25
734.1200562	0.29
753.5212402	2.25
754.6449585	2.22
755.5033569	0.30
771.4418335	49.60
772.1352539	0.40
772.8306885	0.17
779.2758179	1.03
783.1957397	0.48
797.2234497	5.96
798.5344849	11.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	438.9785
Annotation	Unknow
Peak:m/z	Relative Intensity
132.9297791	0.01
148.2095032	0.03
150.1098633	0.04
151.1304932	0.02
157.1416016	0.05
158.9648590	0.06
183.0449829	0.02
186.4267883	0.02
190.7975769	0.01
198.9482422	0.15
201.0379486	0.04
202.9100647	0.04
214.1741333	0.02
214.8017578	0.08
217.0349426	0.05
218.2738037	0.01
219.3050079	0.06
224.0255432	0.03
227.0205383	0.33
228.9888306	0.13
241.2380066	0.02
242.9381409	0.44
244.9227295	0.22
246.0760193	0.04
246.9026794	0.03
253.3529663	0.05
257.2973633	0.02
261.3791199	0.04
262.8825378	0.01
264.3659668	0.02
265.0499878	0.01
271.0018616	0.78
272.8660278	0.17
275.1943359	0.01
286.3146362	0.11
287.0713501	0.29
289.1739197	0.01
292.1572266	0.05
297.0236511	0.07
304.9822083	3.50
307.0249634	0.65
312.3526001	0.05
313.1182251	0.03
314.9970398	1.77
316.8505554	0.16
324.3756409	0.01
329.9363403	0.01
331.3555298	0.05
333.0181885	7.43
335.0323486	1.24
342.8045349	0.01
348.8455200	0.83
349.4499512	0.02
353.2484131	0.34
354.2973633	0.17
357.8330078	0.06
359.0064697	0.96
361.3709717	0.15
363.2684937	0.04
377.0113220	6.25
377.8631287	0.06
379.0461121	0.10
379.7234192	0.02
384.7910156	0.07
393.8743896	0.15
395.0211792	1.98
402.9734802	8.55
403.5897217	0.01
407.1779480	0.02
420.9855042	100.00
421.5895996	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	605.1722
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2309723	0.06
178.7697754	2.03
195.0724640	1.91
209.1161346	0.09
216.1719055	0.12
218.8967133	0.17
220.7762909	0.46
231.3134460	0.24
260.3839111	0.15
264.8995056	0.61
321.0806274	0.09
339.2198486	0.77
357.1817627	1.44
358.1542969	0.18
380.9506226	0.34
393.1843872	0.33
399.1364136	100.00
399.7671509	0.31
407.4939575	0.13
411.1208496	0.12
415.0814209	0.23
422.5331421	0.60
423.1444092	0.22
425.2670898	0.14
428.8776855	0.26
440.8316040	5.19
441.5107422	0.03
442.3914185	0.16
443.2272339	1.45
452.1471558	0.19
452.9761963	0.12
460.4376831	0.75
461.2154541	0.98
467.2371216	0.96
469.6707764	0.20
470.8294067	6.50
472.1781616	0.22
473.0144043	0.74
476.5969849	0.33
477.2321167	0.30
483.1563721	0.37
484.0637817	0.06
485.3226318	0.20
486.9835205	0.54
492.2925415	0.07
493.4359131	0.25
494.3826904	0.36
500.2077026	1.13
500.9687500	28.45
515.1583252	0.89
519.0675049	1.63
523.0956421	0.43
525.1525269	0.12
527.3932495	0.06
529.3030396	0.71
530.9973145	1.69
537.3379517	0.67
542.9092407	2.00
545.1395264	0.22
556.8977051	0.13
557.9658813	0.17
559.1583862	2.50
560.8488770	20.91
561.9751587	0.64
563.6174316	0.12
565.1231689	0.15
569.0776978	0.46
570.3631592	0.24
575.0452881	0.45
587.3856201	0.70
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.19
Annotation	Isocytisoside 6''-O-beta-D-apiofuranoside
Peak:m/z	Relative Intensity
175.2348633	0.08
177.0028992	0.68
179.0579071	0.45
195.0539093	3.85
217.0507965	0.02
218.9657440	0.36
229.1849670	0.07
244.9591522	0.68
254.6417847	0.08
255.3631592	0.13
260.9806519	0.12
263.1036987	1.48
273.2721558	0.21
281.1016235	2.73
284.9481201	0.09
297.1022949	0.44
299.0692749	0.30
301.0494385	2.53
302.4989624	4.75
303.1183472	55.31
305.2769165	0.07
307.2541809	0.11
309.1424866	0.21
315.1994019	0.67
323.1412354	0.39
327.2316895	2.83
329.1794434	0.26
331.0946655	0.30
339.2526245	0.42
345.1087646	16.69
347.0673828	0.10
353.1862793	0.05
357.1044922	0.03
363.1419067	0.10
365.3103638	0.17
369.1829834	5.71
387.1611328	0.20
389.3225708	0.22
393.1557617	0.22
395.1042480	1.10
399.0735474	0.94
407.2591553	0.65
411.2032471	3.22
413.1140747	17.84
418.2137451	0.20
425.1783447	0.76
429.0502319	2.77
431.0603027	27.12
431.8459473	0.02
437.2570801	0.26
440.8209229	0.31
443.1947632	0.56
447.1774292	45.17
449.0484619	100.00
449.6810303	0.58
453.2561646	0.68
455.0969849	0.57
459.1766357	1.14
461.0326538	0.12
463.0516357	6.03
464.3509521	24.68
465.0928345	51.71
471.2046509	1.72
473.0811768	5.35
477.3730469	0.08
479.0091553	0.61
487.2811279	0.03
489.0523071	15.13
490.4723511	0.87
491.1030884	4.77
497.1228027	1.04
507.0084839	0.66
509.1036987	0.14
513.1445312	0.62
521.1490479	0.50
526.9495239	2.13
531.2188721	0.09
539.0227051	5.07
539.7706299	0.18
557.1291504	14.26
575.1268921	19.27
582.3867188	0.08
593.0289917	17.89
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	359.0619
Annotation	Norbergenin
Peak:m/z	Relative Intensity
110.9202805	1.34
114.7520142	0.16
128.8970947	4.74
147.0357513	9.11
167.0837402	1.34
172.9917450	7.54
178.9787140	0.43
190.9826660	100.00
192.9537048	0.04
194.9690857	0.09
197.1184998	1.07
209.0621796	4.30
232.9941406	0.24
235.1423035	0.57
239.2767334	0.20
243.2070312	0.05
247.0308838	0.09
261.0367737	0.08
268.9323425	0.21
280.9910889	0.08
287.1906738	0.67
289.0140991	0.03
297.0567017	0.57
300.2965698	0.09
313.0598145	0.12
315.3085022	0.88
316.2929077	0.17
323.2936707	0.53
325.2789001	0.10
327.4476929	0.05
329.0533447	0.12
331.4042053	0.33
341.1163635	29.91
344.2852783	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	594.22
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2590942	0.20
179.0621796	0.85
193.1271210	1.53
202.1524811	0.13
210.7945251	0.43
285.0648804	8.02
286.0720825	6.19
299.2286987	0.15
318.5588989	0.13
326.3450928	0.10
327.3009644	0.09
342.0133667	0.45
352.9594727	0.37
354.1929932	2.19
357.0769043	0.06
371.2577515	0.21
372.0913696	0.88
383.2241821	0.15
384.1572266	0.97
385.3750000	0.13
386.2772827	0.25
387.4686279	0.11
390.3925781	0.09
399.7228394	0.14
401.2725830	0.47
403.1536865	0.18
414.2071533	0.16
417.3143311	0.19
418.3923340	0.05
427.1845703	4.57
444.1915283	0.66
445.3056030	0.21
455.1184692	0.27
456.5349731	0.25
471.3364868	2.92
473.2799683	0.95
474.3193970	5.45
475.2343140	0.24
480.1779785	0.18
486.1581421	0.81
487.0754395	1.54
489.2643433	1.65
503.9017944	1.63
521.3986206	0.10
523.2766724	0.05
525.8912354	0.14
531.2189331	100.00
533.2775269	0.05
534.5046997	0.35
535.6317749	0.11
540.2531738	0.31
549.9951782	0.07
556.0628052	0.08
565.1302490	0.08
576.3419800	0.61
580.2633667	2.81
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	767.1989
Annotation	Unknow
Peak:m/z	Relative Intensity
216.9140930	0.02
225.4358368	0.10
227.1241455	0.02
228.2364197	0.17
229.0815582	1.10
229.8988800	0.02
231.1387939	0.03
245.1414337	0.32
246.1417389	0.14
247.1054230	0.07
249.2456207	0.02
251.6130676	0.01
252.8892822	0.49
256.4020996	0.21
257.0868225	0.64
258.7055664	0.02
260.1753235	0.16
261.1403503	0.25
270.4966736	0.41
271.2373047	1.17
273.0090027	0.22
274.1243896	0.93
284.1954346	0.12
285.1415405	1.89
286.1446533	0.09
287.0238342	0.05
288.8500977	1.08
295.2687988	0.10
297.9541016	0.05
300.1460266	0.04
302.1383057	3.92
307.1319275	0.85
313.0791016	0.24
315.1496887	0.47
317.0720215	100.00
317.6937256	0.42
318.6471558	0.05
326.0659180	0.06
329.2845459	0.09
330.0777588	0.04
330.8096313	0.05
331.4632568	0.10
341.1450806	0.47
346.8905029	0.02
349.1972656	0.16
353.1818848	0.02
357.3743286	0.02
359.1202393	11.77
361.2145386	0.06
375.3093872	0.02
376.9673462	0.05
379.0561523	0.32
380.2746582	0.06
383.1743164	0.29
385.4581909	0.06
394.9589844	0.02
396.8830566	0.55
397.4921875	0.16
401.8290405	0.01
407.1412354	0.93
413.4300537	0.17
415.0761108	1.10
425.2057495	4.29
425.8590088	0.01
433.1220703	6.22
443.2438965	0.06
450.8739014	0.62
467.2739868	0.18
473.9706421	0.07
485.0957642	0.11
507.5992432	0.03
519.2338867	0.06
521.3349609	0.08
527.0975342	0.94
528.0891724	0.01
543.3380737	0.01
551.0963135	0.16
557.3203125	0.02
562.1163940	0.07
569.0714722	1.35
581.3281860	0.06
585.3209839	0.01
586.2499390	0.03
587.1163940	0.81
591.2716064	0.08
602.4738159	0.02
605.3053589	2.01
623.1137085	0.34
629.0276489	0.09
631.4920654	0.09
646.1173096	0.04
647.4141235	0.08
655.9812012	0.03
669.3369751	0.07
687.2206421	0.18
713.1153564	0.42
716.0099487	0.09
731.0066528	2.23
731.7017212	0.04
747.9138794	0.05
749.1360474	10.26
749.8506470	0.03
751.4724731	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1299.5049
Annotation	15-Hydroxyansamitocin P-3
Peak:m/z	Relative Intensity
380.3631592	0.15
381.5460205	0.48
382.9662170	0.11
384.5184326	0.20
387.4014282	0.11
399.3380127	0.60
404.2873840	0.43
443.3919067	2.57
444.1884766	0.81
461.2904053	0.75
462.1301270	0.35
475.4889221	0.19
493.4969482	0.10
494.3276367	0.36
503.4604797	0.32
547.4837646	0.20
548.1769409	0.22
561.5435791	0.06
569.4927979	0.07
575.2078857	0.22
587.1321411	1.12
590.4500122	0.06
605.3553467	4.31
606.4077148	2.54
621.2369385	0.17
631.1304932	0.09
632.4117432	0.40
649.3035889	100.00
650.2760010	57.75
650.8842773	0.62
746.1644287	0.05
826.2974243	0.16
1053.0800780	0.10
1108.2738040	0.16
1137.5871580	0.10
1156.3918460	0.11
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	712.65
Annotation	Unknow
Peak:m/z	Relative Intensity
206.6439819	0.24
208.6519470	0.38
212.9286499	0.18
290.8239746	3.35
292.8144531	2.81
374.5629272	1.65
376.2861938	0.58
376.8966675	1.04
382.4597168	0.07
424.8786621	0.20
458.5817871	8.54
459.9582520	2.35
460.6204834	19.09
462.5969238	0.07
476.4528809	0.02
492.2926025	0.03
492.9929199	0.19
504.6499023	0.46
508.4890747	0.09
522.4622192	0.23
537.7185059	0.05
542.5586548	30.43
544.5669556	100.00
546.5490112	1.23
550.5038452	0.26
558.6829834	0.12
567.4727173	0.05
568.8009033	0.02
574.8685303	0.09
576.0773315	0.38
576.7326050	0.48
580.5402222	0.03
582.4400635	0.08
590.5401001	0.08
591.8839111	0.11
592.6111450	0.04
603.9636841	0.12
605.5975342	0.58
606.4614868	3.03
607.1779785	0.03
618.4055176	0.23
622.3041382	0.09
623.1467285	0.27
625.8603516	1.63
626.5122681	3.52
627.8042603	6.50
628.5657959	23.13
636.3355103	0.02
645.0212402	0.08
646.7512817	0.15
648.5625000	1.27
651.7732544	0.28
652.5544434	0.73
654.8112183	0.04
658.4570923	0.25
666.1130981	0.60
666.8544312	0.25
681.4081421	0.13
682.4041138	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	314.11
Annotation	Amoxapine
Peak:m/z	Relative Intensity
98.1326447	0.01
125.2060623	0.01
133.0187073	0.19
136.8264618	0.09
150.2491760	0.09
151.9294434	0.02
161.0158691	5.31
162.9703217	0.03
167.0710297	0.03
169.1251831	0.02
170.1684570	0.01
178.0259705	0.08
188.2164612	0.04
192.9780579	100.00
208.8038330	0.05
214.2234497	0.01
215.2962952	0.03
222.3688660	0.02
225.0900879	0.07
225.8964233	0.03
227.1212158	1.92
234.1402893	0.02
236.0175476	0.01
242.2167969	0.02
245.0496521	0.07
246.0662537	0.02
251.0927734	0.01
259.3039551	0.06
263.8842468	0.02
265.2720337	0.07
267.9580078	0.01
269.3133545	0.03
272.2745972	0.06
273.0130005	0.10
282.0103760	0.14
285.8025208	0.06
296.0113525	0.38
297.4266968	0.03
299.1380615	0.29
300.2608032	0.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	629.2786
Annotation	Unknow
Peak:m/z	Relative Intensity
176.7416229	0.15
186.1354980	0.09
187.0940857	0.20
189.1338806	0.71
191.2344818	0.21
193.2237701	0.13
201.1184845	1.46
207.0782471	0.95
211.0698242	0.24
212.8198853	2.59
216.9193268	0.77
219.1880493	2.68
225.1657257	0.18
227.2381592	0.66
228.8122864	0.71
230.4374542	0.66
231.0628357	6.43
235.0056915	0.50
237.1390381	78.40
249.2408905	0.68
252.8288269	0.45
265.3806152	0.41
271.1388550	0.80
273.0888672	1.48
279.2259521	0.54
283.1834106	0.26
291.1269531	4.84
295.3849182	0.18
302.1480103	0.23
303.3795166	1.28
307.0465088	0.26
312.6618042	0.90
313.2965393	0.39
315.5023193	0.36
317.1900635	12.73
321.1260376	1.82
325.2484741	0.18
327.4768677	0.17
330.0367432	0.19
331.0696411	7.24
331.7655640	0.09
332.5292358	0.15
337.3131104	0.13
338.9519043	3.94
340.2752686	0.15
343.4216309	0.56
345.3571777	0.62
347.1140137	11.70
347.7668457	0.12
356.9346924	4.39
359.1366577	0.06
375.1243896	56.76
376.0764771	0.14
379.2440796	0.13
391.6389160	0.27
392.9956055	12.17
397.0071411	0.09
401.2269287	0.13
402.0067139	0.37
404.7841187	0.06
405.6087646	0.18
407.2583008	0.09
413.0806274	0.19
423.2824097	1.29
431.5626831	0.13
432.8621216	0.41
441.0122070	0.24
449.2515869	5.52
465.0651855	0.18
467.2252197	2.31
473.4562378	0.12
479.0574341	0.05
481.2844849	0.20
482.3342896	0.18
483.4796753	0.20
485.2305908	45.57
505.2841187	0.74
507.0213013	0.13
509.5846558	0.27
511.5986938	0.21
525.5538330	0.33
531.0607910	0.19
543.1912231	0.68
544.8610840	0.05
549.4123535	1.12
567.1065063	15.37
567.7918091	0.32
569.1021118	1.05
575.2691040	1.14
577.0155029	0.23
581.3301392	0.14
585.3597412	0.53
586.3739014	0.16
593.1257935	25.91
593.7610474	0.10
598.7926025	0.42
599.4951172	0.70
601.2029419	0.12
611.2039795	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	220.1173
Annotation	Trans-Zeatin
Peak:m/z	Relative Intensity
69.28271484	0.22
71.96266937	3.26
83.93534851	0.22
84.96958923	0.01
86.93725586	0.05
89.9692688	41.97
95.06109619	0.17
97.78326416	0.28
99.94668579	0.25
102.9789276	0.05
112.8809814	0.01
115.8893433	5.36
118.1373749	0.06
124.0811615	0.22
130.0542755	0.04
130.976181	0.45
133.1165771	0.05
142.0360107	0.20
145.870575	0.07
147.1112366	0.03
156.0751038	0.50
158.3325348	0.03
159.9287872	1.19
161.0675049	3.05
166.0683594	1.37
170.9243011	0.02
172.1479645	0.27
174.0760956	4.29
176.6687775	0.12
178.086731	0.02
183.998291	27.39
189.4439697	0.19
192.048645	2.37
199.7101593	0.07
202.1058044	100.00
203.1902618	0.09
204.1546478	0.04
210.7556305	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	785.3954
Annotation	Diospolysaponin A
Peak:m/z	Relative Intensity
222.9627991	0.13
225.1310730	0.15
227.0372009	0.21
231.2772827	0.11
235.1074829	0.56
240.7390747	0.03
242.2481384	0.03
246.9017944	0.12
265.1212158	0.17
270.0513306	0.03
277.2797546	0.14
286.8564453	0.10
299.0590820	0.11
301.1875000	3.20
307.1970215	0.09
309.6424866	0.07
318.1881714	0.08
321.0719604	0.14
324.2964172	0.03
339.3288574	0.08
352.1436768	0.10
353.4144287	0.15
367.2304688	5.05
368.3517456	0.05
373.2042847	0.54
381.2836914	0.35
387.1156616	0.30
395.4811401	0.03
399.2797241	0.09
403.1665039	1.69
411.3092041	0.04
417.2654419	0.48
423.1622314	0.10
425.2263794	0.11
441.5307617	0.08
449.3942261	0.04
452.9937744	0.07
459.3683472	5.53
473.3814087	0.19
476.7780151	0.12
477.4362183	0.11
479.3925171	0.11
483.2525024	6.95
493.0946655	0.11
497.3048096	0.34
503.3740845	0.07
504.5046997	0.28
515.0603638	0.16
517.2758789	0.48
519.4202881	0.32
531.4688721	0.10
533.3562622	0.37
535.2947388	0.43
537.4391479	0.04
547.0916138	0.56
552.8597412	0.08
559.6150513	0.24
577.3603516	0.83
578.5797119	0.51
579.5204468	0.33
581.2886353	0.08
589.3995972	0.15
591.4371338	0.82
595.4041138	0.03
597.2798462	0.38
603.3773804	0.07
605.2373657	0.09
609.3529663	2.02
617.3562012	0.06
621.3921509	100.00
622.0854492	0.75
623.3261108	0.18
631.4924316	0.04
637.3615112	0.08
639.2273560	15.38
640.8746948	0.05
641.4956665	0.04
651.0358276	0.41
657.3551636	0.05
661.3356323	1.14
663.4044800	0.38
665.6380005	0.23
666.8605957	0.04
669.4925537	0.06
677.4578247	0.23
678.7716064	0.14
679.4232178	0.43
681.2677612	48.23
683.5328979	0.02
693.1491089	0.05
697.1730957	0.62
699.7916260	0.16
705.3334961	0.88
713.5512085	0.08
721.3997192	0.37
723.3256226	2.18
725.4402466	0.55
738.7438354	0.59
739.3488159	4.23
740.6022949	0.45
741.2795410	3.70
743.5236816	0.11
752.3950806	0.06
754.7905273	0.27
765.4872437	0.12
767.7249146	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	230.0128
Annotation	Benzeneacetamide-4-O-sulphate
Peak:m/z	Relative Intensity
71.8153076	0.03
81.9557800	0.66
96.0359650	1.80
99.0972900	0.12
107.9729309	1.17
113.9870453	4.21
141.9877472	75.90
175.3036041	0.03
185.9757690	100.00
207.8545380	0.07
212.2088165	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.1505
Annotation	6-Deoxylamioside
Peak:m/z	Relative Intensity
112.7643356	0.49
123.1814499	0.09
133.8657990	0.28
135.0880127	3.86
143.0281525	0.27
147.1899109	0.43
159.0978394	0.19
160.9224854	1.15
163.2433472	0.19
173.1226196	0.18
179.0193787	52.05
181.1786804	1.89
191.0650024	2.40
193.1316986	0.55
203.1843567	1.72
205.1624756	1.43
208.1280518	0.10
209.0575256	0.32
221.1548004	1.09
223.0093842	100.00
227.3633423	0.17
233.0950317	0.16
237.0851135	0.12
241.1047974	0.24
245.1079102	0.11
247.0759277	2.93
265.1324463	10.15
276.9916077	1.06
277.6419067	0.08
288.8516846	0.35
295.0858154	5.91
301.0260315	0.09
323.1695557	0.17
325.1538391	9.14
328.0282288	0.17
339.3475952	0.48
340.2330933	0.07
341.2070007	0.27
342.1906128	0.17
349.3199158	0.52
352.0696106	0.18
353.3704529	0.15
355.2994690	0.46
367.0365601	1.13
370.2247925	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	567.3475
Annotation	Unknow
Peak:m/z	Relative Intensity
166.9429016	0.51
171.3290710	0.37
185.0251923	0.66
195.9544983	0.50
206.9611816	0.09
213.0300293	0.70
223.1120605	0.10
224.0539551	1.93
225.1553345	1.42
225.8554535	0.05
227.9797363	0.38
229.2341919	0.23
231.1577759	0.47
239.9400330	1.56
242.1100922	5.22
258.0476990	0.42
259.1121826	6.39
265.3927002	0.18
266.1674805	0.08
268.0874634	0.60
270.1712036	4.92
279.0529785	0.07
280.3905334	0.88
281.1597900	1.57
281.7772217	0.15
286.2677612	0.41
293.3893127	0.08
294.2338867	0.16
296.0656128	0.16
298.3482666	0.39
309.2433472	0.74
310.1652832	0.11
311.9641113	1.24
321.2465210	0.40
325.2429199	0.32
327.1699829	4.67
328.1390381	0.49
328.8016357	0.11
337.2385254	3.97
339.0038452	4.94
348.9038696	0.44
349.6948853	0.30
355.1749268	20.68
356.9076538	0.25
367.0085449	1.35
369.0681763	0.20
376.2413940	0.23
381.0138550	0.05
382.6395874	2.08
383.2608643	9.98
393.5820923	0.13
395.3070679	0.21
396.9143066	0.23
405.1245728	0.27
407.2242432	0.08
408.3702393	1.03
409.5634155	0.15
418.7476807	1.16
419.3877563	1.17
422.3621216	0.25
423.5120239	0.45
425.0737915	1.00
426.3408813	2.84
434.0953369	0.64
436.1655884	25.89
438.4920044	0.10
440.3240356	0.53
442.2285156	0.15
450.2418213	2.18
452.2132568	12.87
454.2386475	50.19
454.8628540	0.68
462.4916382	0.20
464.2288818	0.59
465.4488525	1.44
468.3234253	7.31
470.3186646	6.26
478.1766357	0.48
480.2946167	1.52
481.6392822	0.23
486.4870605	0.62
492.2525635	0.25
494.4763794	0.44
498.5598755	0.70
504.2489624	0.73
508.3093872	0.63
510.4202271	0.21
519.5667114	1.65
521.4035034	6.25
522.4429932	7.12
523.3563843	0.62
531.3074341	9.68
532.2877808	0.56
537.3501587	0.32
539.4625854	94.64
549.3268433	100.00
550.0064087	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	437.9712
Annotation	Unknow
Peak:m/z	Relative Intensity
161.8396301	0.02
169.9474792	0.07
174.0160980	0.03
202.0614777	0.10
213.1142426	0.01
214.2294769	0.02
219.9174652	0.03
235.0056152	0.02
242.5538635	0.01
246.3520508	0.02
247.1911011	0.03
258.0501099	0.02
259.8070068	0.03
270.1039124	0.14
272.1859131	0.01
273.1405640	0.02
276.1006165	0.15
286.0218506	0.01
290.9863281	0.02
303.9639893	0.39
304.8388367	0.03
308.2722778	0.03
314.1709595	0.05
321.2797546	0.02
324.0102844	0.03
325.0988159	0.02
327.1329346	0.10
330.0849915	0.14
331.9171448	0.80
333.8371887	0.03
337.6734009	0.02
341.6565552	0.02
345.2647705	0.03
347.9761963	0.95
353.1411438	0.07
358.1125488	0.20
362.1842651	0.03
363.3769531	0.07
368.4260864	0.04
370.7456360	0.05
375.4256897	0.01
376.0849609	0.32
380.2261047	0.03
393.9604492	100.00
401.9963074	0.11
403.0634460	0.01
407.9762878	0.01
419.9624939	2.60
421.4433899	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	386.1951
Annotation	6'-Hydroxygaruganin V
Peak:m/z	Relative Intensity
135.3027649	0.10
153.2861023	0.03
162.0663757	0.05
175.1444550	0.01
193.0677643	0.05
219.0471802	0.42
247.9627075	0.11
260.9939880	0.13
278.5611572	0.03
286.9691772	4.19
287.5964050	0.04
296.9792480	0.03
316.6644897	0.08
318.0697632	0.62
330.8910522	0.07
337.4492798	0.03
345.3291016	0.02
355.0128784	100.00
355.6771240	0.24
368.5229187	0.38
369.1510925	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1555
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
269.0470581	100.00
311.2976685	1.10
325.2539673	0.14
339.2813721	0.95
355.3880005	0.18
373.2789307	0.12
406.9966431	0.32
409.2062378	0.30
413.1830444	0.96
433.4504395	0.43
457.262085	0.43
473.9550781	0.61
477.3898315	0.37
489.6865845	0.43
502.6651001	0.19
509.243103	0.98
515.0704346	0.66
519.3716431	0.42
531.2487183	1.19
532.0916138	0.55
541.0732422	0.92
552.0493774	0.89
553.8842163	1.10
559.274353	0.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	332.3149
Annotation	14(15)-EET-d11
Peak:m/z	Relative Intensity
95.02424622	0.12
98.9342804	0.04
104.0718384	0.05
107.05439	0.12
108.9297104	0.18
111.0303345	0.34
117.1484146	0.21
121.0713806	0.35
122.077713	0.07
123.0677032	0.02
127.2710266	0.11
133.0308685	0.04
135.2650757	0.27
136.9083099	0.62
145.0065613	0.07
147.947113	0.11
149.1146545	0.18
150.2149353	0.18
151.0862427	0.40
152.0498962	0.06
153.0522614	0.28
155.0782166	0.21
159.0905151	0.02
162.9620667	0.22
165.0830688	0.07
166.2191162	0.20
170.0547791	0.09
175.1724243	0.09
177.0568237	0.08
179.0982056	0.44
183.2107849	0.28
190.1835632	0.12
192.7807922	0.05
194.25354	0.07
194.996521	0.05
203.1639862	0.22
205.1020813	0.04
210.7758179	0.04
212.8872986	0.07
216.0595703	0.12
219.0683899	0.12
225.2374268	0.12
227.2156677	0.21
228.8024902	0.09
239.4061279	0.20
240.1947937	0.16
243.8848572	0.04
247.1547546	0.18
249.3936768	0.25
250.1869812	0.10
252.335022	0.18
253.4024658	0.07
261.2270203	0.43
262.1269226	0.04
264.3874512	0.06
266.3888855	0.92
269.3356323	0.03
270.2713318	0.27
272.131897	0.03
273.4836426	0.08
275.1477051	0.08
276.2689209	0.06
278.3410034	1.35
279.2225952	3.07
283.7043457	0.33
284.3597107	1.02
285.985321	0.18
289.3338318	0.23
290.163269	0.07
296.2858887	49.39
297.07901	0.29
299.0542297	0.02
301.9962158	0.03
304.1025391	0.35
314.2898254	100.00
315.3841553	0.26
317.024292	0.31
318.1903076	0.15
323.8124084	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0985
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
161.1533051	0.09
190.6777802	0.04
212.2236786	0.01
219.4400635	0.01
247.0937500	0.03
251.3699036	0.02
257.3641968	0.03
258.8045349	0.03
269.1901550	0.45
281.1531982	0.04
283.1416931	0.58
293.1597290	0.09
297.1732178	0.02
301.1783447	0.02
311.1149597	100.00
312.2011108	0.27
323.1118774	0.12
325.4128418	0.02
337.2840271	0.05
341.1908875	7.95
342.3413086	0.04
349.2097778	0.05
351.1855164	0.02
353.1113281	0.40
355.2695923	0.05
365.3380432	0.11
367.0719910	0.07
369.1951904	0.03
370.7098694	0.11
371.4810486	0.02
377.1783752	0.17
383.1517029	0.18
385.5335999	0.02
389.1589966	0.02
395.2272949	0.02
401.2730103	0.01
413.1309204	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1693
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
168.0705566	0.06
178.0690765	0.19
213.1347046	0.10
221.2543182	0.10
236.2235107	0.18
271.054657	15.27
271.6939697	0.49
300.1033936	0.19
312.8582153	0.34
318.9179688	0.08
323.2740479	0.45
324.8152466	0.14
326.3456421	0.19
327.3198242	0.58
331.5214844	0.31
335.1928101	0.04
341.4897461	0.19
352.336853	0.12
358.5761108	0.09
375.34729	0.12
382.5859985	0.06
389.3275146	0.13
390.4196777	0.26
395.4993286	0.26
397.3797607	0.16
406.2357178	0.38
407.8534546	0.35
413.2108765	0.16
415.2528076	0.18
417.2053223	1.25
433.1040649	100.00
433.7648926	0.61
450.5605469	0.14
455.2255249	0.27
459.2360229	0.20
469.5151978	0.37
473.6702881	0.19
484.8581543	0.19
491.0561523	0.07
495.729187	0.21
497.1941528	0.13
507.4459229	0.12
509.4048462	0.44
510.0702515	0.19
515.3652344	0.18
516.161377	0.09
519.1512451	0.22
523.4848022	0.06
529.3487549	0.13
530.3921509	0.09
532.2528687	0.30
537.4667358	0.17
542.243042	0.37
543.2731323	0.68
544.0356445	0.33
547.8189087	0.06
552.5153198	0.19
557.2686768	0.13
558.1541138	0.44
560.8148193	1.89
561.4450073	0.91
562.0880127	0.14
581.0771484	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1765
Annotation	8beta-Propionyloxy-10beta-hydroxyhirsutinolide-13-O-acetate
Peak:m/z	Relative Intensity
124.9419098	0.28
129.1360931	0.09
131.0540161	1.19
133.1131134	0.21
137.0703125	0.16
139.0000000	8.18
143.0020447	1.83
148.6784210	0.10
150.1832886	0.33
151.0743713	0.18
153.1565399	0.10
158.9297943	0.21
160.9924164	8.52
163.0979004	0.11
168.8637085	1.17
176.9988403	0.42
178.9719086	2.97
187.0723572	1.18
205.0836792	7.26
211.1919250	0.29
214.9015045	0.10
217.1679382	4.40
235.1529083	5.66
243.2240295	0.46
253.0967102	0.07
261.0085754	1.22
277.2883911	0.33
279.0018616	0.57
288.9517517	0.10
303.3078613	0.41
330.1752930	100.00
331.1758423	45.91
379.1882324	2.86
381.3050537	1.85
382.2128906	0.55
395.3411255	0.17
397.2841187	38.72
399.3912964	1.47
423.2247925	3.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	451.161
Annotation	3,4,5-Trimethoxyphenyl acetate
Peak:m/z	Relative Intensity
147.9750061	0.16
148.8492737	0.27
161.1967621	0.17
176.0927734	0.37
176.8446655	0.14
184.4337921	0.05
191.0181580	0.05
203.1577759	0.22
217.0625916	0.87
220.1006317	16.02
221.1025543	2.68
221.9598846	0.04
229.3486633	0.04
245.1128845	1.24
246.9749146	0.38
269.1218872	0.35
271.2167053	1.30
283.4356384	0.19
289.1583862	100.00
302.1761780	0.09
303.2849731	0.17
321.3360901	0.11
329.2584229	0.04
331.3026123	0.20
349.3117981	0.20
362.1250000	0.09
365.0685425	0.11
370.9842834	0.08
375.4288635	0.07
383.1817932	15.76
391.2940674	0.05
407.6265564	0.36
408.3923035	0.07
433.0048828	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	581.206
Annotation	Excelside A
Peak:m/z	Relative Intensity
187.0739899	0.26
189.2554626	0.03
213.2100983	0.05
225.0914154	0.03
231.3963318	0.08
235.2378387	0.06
237.2518921	0.01
249.4035797	0.04
255.2117310	0.01
257.1041870	0.03
263.4085693	0.05
271.2029419	1.08
272.0799255	0.46
272.9449158	0.53
273.5633850	0.04
287.3995361	0.08
288.9750977	0.03
315.0737915	0.12
317.1038208	0.10
321.3273926	0.06
327.1077271	0.04
331.2604980	0.14
332.6513672	0.10
333.2516479	0.69
334.0908203	0.04
334.9494629	0.05
339.0523682	0.50
343.1525269	0.03
347.0188599	0.02
348.2578735	0.03
357.1141968	0.02
359.2559204	0.04
363.0419312	0.03
364.8931885	0.02
367.3319702	0.04
370.9016724	0.04
375.2723389	0.12
377.1178589	100.00
377.9251709	0.02
383.2971802	0.18
386.3977051	0.04
392.9796143	0.02
394.1856689	0.15
400.6062012	0.15
401.4441528	0.12
411.3533325	0.13
413.3596802	0.08
416.8755493	0.10
419.1420898	0.74
420.1906128	0.02
420.9973145	0.07
424.5797119	0.03
428.1130981	0.02
431.2409668	0.05
433.1561279	1.29
434.1127319	2.12
435.1170654	6.12
443.1051636	0.11
447.0194092	0.04
449.3005371	0.63
451.1494751	0.03
455.1526489	0.07
461.0196533	0.26
467.1950684	0.05
471.2612305	0.07
477.5616455	0.08
479.1721802	0.43
490.7141724	0.05
491.4598389	0.13
499.0455322	0.04
503.5647583	0.01
506.9039307	0.02
509.3917847	0.01
521.2947388	0.14
526.8936157	0.09
535.3169556	0.03
537.2172241	0.20
545.1128540	0.46
551.2429810	0.03
560.5972290	0.03
562.9448242	1.57
563.7764282	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	610.72
Annotation	Unknow
Peak:m/z	Relative Intensity
190.7900391	0.19
206.8285217	0.67
218.1589050	0.03
267.1284180	0.03
274.8889771	0.28
290.8391113	2.69
355.0456543	0.05
358.6789551	1.10
374.6389160	0.45
380.6676636	0.14
414.9792480	0.03
442.6266479	15.56
444.7707520	1.38
456.2606201	0.28
458.6692505	6.20
466.4616699	0.25
474.8029785	0.51
490.8135986	0.21
504.1262817	0.78
504.7980347	2.48
508.9132080	0.17
526.5223999	100.00
527.2725220	0.25
534.3203125	0.14
542.4699707	3.23
543.0914917	0.02
550.6744995	0.43
564.5877686	1.48
593.4696045	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
177.1164703	0.14
177.9748077	0.07
199.1636658	0.17
216.6819	0.15
230.5764923	0.12
252.7727966	0.18
274.8008118	0.18
277.1156006	0.07
283.192688	0.13
301.0922241	18.36
303.0680542	0.63
313.2113647	0.15
317.3314514	0.11
339.5419922	0.12
343.4838257	0.24
348.9749146	0.13
357.2044678	0.40
361.0866699	0.32
367.4207764	0.09
375.1349487	2.49
388.2869873	0.53
393.0026855	1.90
401.2814331	0.18
409.2876587	0.36
410.9299316	0.27
413.1762085	0.22
416.7848511	0.12
421.1334839	0.25
428.2893677	0.53
429.4381104	0.10
430.9365845	0.12
433.2479248	0.23
435.5421753	0.05
447.2466431	1.31
453.3265381	0.04
463.1184082	100.00
487.3416138	0.23
497.3535767	0.13
507.0264282	0.10
519.2747192	0.07
521.381897	0.04
531.2323608	0.14
555.2251587	0.33
563.4800415	0.32
565.2459106	0.15
565.953064	0.25
591.3795776	1.90
596.7525024	0.82
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	467.1558
Annotation	Seguinoside G
Peak:m/z	Relative Intensity
144.9543915	0.08
159.1359100	0.24
172.8516083	0.01
174.1077271	0.03
176.2287598	0.05
176.8960876	0.12
201.0184021	0.04
203.0903625	0.69
216.0973816	0.02
219.5150452	0.11
220.2097473	0.25
221.2825928	0.02
229.0077972	0.24
233.2669067	0.13
237.2081757	0.04
247.1203003	1.56
261.0654297	0.45
263.2651978	0.06
273.0126953	0.05
287.0795288	0.22
290.6403198	0.05
305.1096191	100.00
323.0266113	0.01
339.1950684	0.03
365.2759094	0.04
366.8889771	0.13
367.5226135	0.02
377.2939148	0.07
407.2765503	0.03
422.6035156	0.06
449.4766541	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	148.06
Annotation	3-Aminopentanedioate
Peak:m/z	Relative Intensity
83.9390411	1.57
84.9100723	0.02
87.8974304	0.09
101.9350433	22.39
103.1049347	0.03
129.8943329	100.00
130.8697510	1.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.1713
Annotation	Lupiwighteone hydrate 7-glucoside
Peak:m/z	Relative Intensity
148.8784943	0.25
160.0952148	1.09
161.0350647	0.15
163.1441345	0.02
171.9032745	0.11
173.2497253	0.01
175.0763855	4.96
176.0577545	0.14
178.1276550	0.07
179.1052246	1.61
183.1518555	0.06
187.0687256	0.02
188.2224426	0.09
189.1304321	0.09
190.1763153	0.11
191.0950165	0.74
193.0254517	4.32
197.1422119	0.05
199.9291687	0.22
200.9821167	0.07
202.9503632	0.14
205.0740051	0.10
206.0467224	0.05
207.1754456	0.03
209.2588806	0.05
213.8773499	0.01
215.1100922	0.18
216.1734161	0.06
217.1587524	1.99
218.0721741	0.01
219.0792389	0.17
221.3538513	0.04
230.9838562	0.03
233.1198120	0.25
235.1632690	0.35
244.2557068	0.04
245.0360260	0.23
247.1174316	0.19
249.2067413	0.19
250.2288818	0.03
259.1837158	0.06
261.3743896	0.01
262.1804810	0.02
265.0278320	0.13
267.3612671	0.03
271.2844849	0.03
272.9965210	0.02
275.1499023	0.09
277.0920715	1.29
289.2101440	0.07
291.4172363	0.09
293.3969727	0.02
307.4049072	0.11
309.3523560	0.01
313.1143188	0.14
319.1423340	0.08
322.0797729	0.10
323.2042847	0.29
330.1759033	0.01
337.1488037	100.00
367.1025391	0.04
373.2662964	0.07
385.3892822	0.07
386.9294434	0.02
413.2706299	0.03
415.2718506	0.02
429.2202148	0.02
431.1842041	0.08
433.2215576	0.07
443.1191406	0.02
445.4190063	0.24
455.6248779	0.10
457.3649292	0.20
466.0352173	0.11
471.3068848	0.02
473.1384888	0.17
474.9182739	0.10
485.5368042	0.04
499.3166504	0.11
500.7575684	0.10
502.0664673	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	557.1788
Annotation	Claussequinone-(4->5')-vestitol
Peak:m/z	Relative Intensity
159.2403412	0.38
171.0970001	0.07
173.1111755	0.33
175.1084900	1.18
177.8394470	0.12
182.0433655	0.07
183.8670197	0.73
185.0104675	0.20
186.8481750	0.10
191.2248230	0.32
195.0542908	0.12
198.9989166	2.51
200.9775391	0.31
202.9735565	100.00
204.8575897	0.10
211.0352478	0.45
213.1383362	0.75
215.1583252	1.52
221.1042786	0.07
223.0830994	0.35
225.1530609	0.07
227.1668854	4.37
229.3336182	0.11
241.0249481	5.76
243.0486603	0.96
245.1567383	0.37
251.1625824	0.18
253.1638641	0.74
256.2702942	0.10
261.4506836	0.14
269.1610718	46.70
271.1470947	19.77
272.0613403	0.22
274.2578735	0.38
287.0896606	83.17
294.9520569	0.12
311.2599487	0.07
315.2019653	0.10
329.0173340	0.17
337.3493652	0.54
339.2664795	0.23
355.1990356	0.79
363.5512695	0.17
367.4196167	0.39
385.2614746	0.45
399.4765625	0.17
409.3278809	0.20
473.1296387	0.21
483.7577515	0.22
488.1934204	0.65
489.0427856	1.64
495.4254761	0.35
511.0022583	0.30
512.7899780	0.36
521.1731567	0.68
526.3511353	0.31
538.7929077	1.34
539.5201416	0.83
540.5568237	0.51
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	177.04
Annotation	2-Dehydro-D-glucono-1,5-lactone
Peak:m/z	Relative Intensity
69.1272049	0.02
70.8923035	0.02
84.8398590	0.15
94.9317627	4.94
97.0350037	0.67
103.0798187	0.01
110.8778839	0.08
111.8922119	0.02
112.9654846	0.64
115.0105286	0.13
117.1297302	0.03
128.9701691	5.99
130.1150513	0.04
130.9764404	0.07
133.9609375	0.04
140.8677216	100.00
146.9378052	0.03
149.0767822	0.07
158.8253174	4.40
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	711.1735
Annotation	8-Hydroxyluteolin 7-[6'''-acetylallosyl-(1->2)-6''-acetylglucoside]
Peak:m/z	Relative Intensity
301.1188354	0.03
319.0609131	0.09
337.1887817	0.21
343.2819214	0.27
355.0390930	0.31
367.1902466	0.78
385.1730957	2.15
391.3665161	0.05
397.3337402	0.09
403.5254517	0.02
409.2775269	1.54
421.1968384	0.40
427.3932495	0.06
433.4914551	0.05
439.1136475	2.05
445.1494141	0.41
451.2700195	1.46
458.1280518	0.05
463.2396240	0.18
469.2371216	1.93
470.9401855	0.02
475.3350220	0.10
487.1378784	50.09
487.7613525	0.25
493.3408203	0.07
495.3158569	0.03
498.7558594	0.10
499.3848267	0.25
503.1726685	0.21
505.2114258	2.68
511.3469849	0.69
513.3882446	0.11
516.9838867	0.12
519.3150024	0.12
523.2666016	0.12
529.0963745	0.44
531.1058350	0.16
535.2040405	0.05
537.1127319	0.10
541.3462524	0.48
543.2500610	0.59
546.8706665	0.07
549.1378784	0.81
553.1333008	1.79
555.2640381	0.44
559.2059326	0.17
561.1299438	0.56
565.1937256	0.12
570.5893555	0.06
571.2630005	0.34
573.2097778	7.08
575.2896118	0.02
576.7061157	0.10
577.3876343	0.05
583.1731567	1.23
584.9902954	0.11
589.1890259	0.24
591.1435547	25.13
592.0114746	0.01
595.2754517	0.82
597.2064819	4.34
601.0563354	0.22
607.0773315	0.37
609.3159180	0.27
613.1488037	0.48
615.1697388	6.94
619.0970459	0.06
620.6933594	0.02
621.3754272	0.32
625.3044434	0.30
627.1802368	15.49
631.1101685	1.58
639.1719360	5.83
639.8964844	0.09
645.1348267	12.12
649.0735474	1.04
649.6780396	0.03
657.1478882	11.06
666.5014648	0.08
667.2827759	0.10
675.2048340	40.88
683.6204224	0.06
693.1152954	100.00
693.7691650	0.67
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	905.2364
Annotation	Unknow
Peak:m/z	Relative Intensity
271.4032288	0.11
281.1911621	0.04
283.0788879	0.07
284.8541565	0.17
295.0664368	0.17
299.0465698	0.04
299.9327393	1.56
301.0435791	1.90
313.2890625	0.12
315.1331787	4.66
343.0972595	0.07
357.1731567	0.20
459.4004517	0.18
521.3155518	0.05
593.5085449	0.03
597.1690063	100.00
597.7783203	0.51
599.3197632	0.84
609.3056030	0.39
623.1937256	5.94
624.2454834	0.08
638.9589233	0.12
665.3059692	0.10
743.2545776	0.30
807.9135132	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	291.129
Annotation	N2-(3-Carboxy-2-hydroxy-1-oxopropyl)arginine
Peak:m/z	Relative Intensity
97.8449707	0.02
112.0227356	0.35
112.9944382	0.14
114.0255356	0.18
115.0580597	0.18
115.9564972	1.80
121.9135284	0.02
123.9638748	0.02
129.3173523	0.08
130.1199188	0.87
132.0143433	1.38
133.0774384	0.08
134.1141357	0.04
137.0596161	0.06
139.8563232	0.21
140.9840393	0.16
141.9078674	0.01
145.0221252	0.03
145.9243469	0.03
147.0805664	0.03
151.0077209	0.01
157.0069275	2.62
158.0322876	2.47
158.9591217	0.07
160.0491028	0.04
175.0454407	100.00
176.1114807	0.39
182.8204651	0.07
184.9643555	0.13
191.0707550	0.07
192.9841766	0.22
195.0287170	0.21
199.2087402	0.03
200.0080566	0.11
200.6164551	0.04
202.9636841	0.09
205.2454529	0.01
209.9712219	0.12
213.0213928	0.76
214.0231018	0.33
214.9769592	0.02
216.9629211	0.01
219.1002502	0.07
220.0933533	0.09
227.9253235	0.04
231.0809326	2.50
232.1257324	0.90
232.8887634	0.03
238.1042480	1.71
244.5748901	0.12
245.2239990	0.41
249.2434082	0.17
255.9932251	2.41
257.1925659	0.24
258.9757690	0.02
264.5521240	0.01
273.1010437	2.23
274.1622620	2.04
282.0167236	0.23
282.8276672	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	466.0023
Annotation	Unknow
Peak:m/z	Relative Intensity
167.0589294	0.09
201.6609650	0.05
207.3616943	0.20
215.8293610	1.08
216.5149078	0.14
227.1802216	0.18
230.1004181	0.87
231.7131653	0.15
241.8112640	0.47
245.8530884	1.14
249.0883179	0.39
255.9407654	0.09
257.7157288	0.51
259.8083191	0.25
269.7684326	0.47
271.9640198	0.13
276.0061035	0.72
277.9375305	4.71
286.1257935	0.56
291.9367065	0.81
301.8121338	0.52
302.5466614	0.07
304.2555237	0.12
314.0486450	0.12
316.1384888	0.59
317.8323364	7.50
318.4460449	0.13
319.9570618	5.36
320.5989380	0.14
327.9050903	0.84
330.0431519	0.24
330.9151611	0.10
335.7034912	1.55
343.7088013	1.40
346.0249023	9.07
347.4414368	0.24
348.0701294	2.79
348.8529358	1.01
357.9588928	0.78
361.8814087	17.36
362.9994202	8.83
371.9394836	1.00
373.8526917	0.15
376.0148315	0.28
379.7047424	0.67
385.8343506	0.22
387.9353333	2.49
389.9688416	26.92
401.9435120	0.71
404.0271301	1.11
405.8235168	8.12
406.9236145	12.19
408.7285461	0.08
416.2033997	0.27
422.0267029	26.14
423.2389832	0.20
425.9942322	0.06
427.9039001	0.35
430.1422424	1.31
433.9475098	100.00
434.6022034	0.70
447.9457703	15.02
448.6477661	0.57
465.7474976	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	629.1479
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0532227	0.06
189.0571289	0.02
195.2105713	0.05
210.8218689	0.07
215.1372681	0.02
217.4348145	0.15
218.1181335	0.02
219.0600586	0.07
230.4875183	0.32
231.2696838	0.33
232.0848083	0.13
233.1147003	0.53
234.0716858	0.42
237.5202332	0.04
245.7110138	0.09
246.6899109	0.08
257.0801392	0.05
261.0528564	0.07
265.1383057	1.34
273.3762207	0.17
279.2586670	0.13
281.3547363	0.02
283.0416565	15.75
287.2316284	0.12
291.1450195	0.09
295.3907471	0.04
299.0070190	0.47
300.2078247	0.13
300.9688110	0.15
305.2071533	0.16
309.1595764	0.11
311.4363403	0.07
313.4551086	0.12
317.0944824	0.89
318.0814209	1.47
319.2573242	0.08
322.0909424	0.22
323.1732788	0.09
332.0857544	0.52
333.1815186	0.04
334.4068604	0.25
335.1939697	0.15
339.1730957	0.02
343.3145142	0.06
345.2374878	0.12
347.1034546	100.00
348.2174683	0.19
350.9835815	0.02
371.1169434	0.03
377.2250977	0.14
379.1945190	0.05
380.2351685	0.09
389.1758423	4.66
390.2190552	0.07
393.1284790	0.28
407.0526123	0.01
413.1302490	0.81
417.2379761	0.08
425.0623779	0.12
426.4821777	0.03
429.2592163	0.07
431.9241943	0.04
435.0166016	0.09
441.0289917	0.11
455.1451416	2.48
462.6052246	0.08
466.3277588	0.09
467.2722168	0.49
470.1141357	0.05
472.8220215	0.08
481.9054565	0.03
487.9705811	0.06
491.1270752	0.15
492.5213013	0.02
494.1763916	0.14
495.1686401	0.07
497.9843750	0.09
503.0694580	0.35
503.9318237	0.44
509.1361694	0.18
526.7393799	0.04
529.8538818	0.13
533.2428589	0.15
539.1669922	0.02
543.2683716	0.02
546.9985352	0.06
548.0805054	0.25
553.3042603	0.05
563.0689087	0.13
565.0767822	0.06
565.9751587	0.41
567.4352417	0.09
574.9836426	1.24
584.4724731	0.06
585.4043579	0.02
586.7576294	0.21
592.8469238	0.37
597.4521484	0.04
598.5108032	0.06
609.0393677	0.06
610.5854492	0.83
611.2368164	4.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	515.1918
Annotation	Myricatomentoside II
Peak:m/z	Relative Intensity
331.4179077	0.06
357.2380981	0.12
369.1590576	0.02
375.1476440	0.12
397.2527466	0.04
401.1259155	0.03
411.2172852	1.03
417.5858765	0.03
427.2839355	2.72
435.0101318	0.02
453.3588257	0.04
469.2114868	100.00
469.8355103	0.15
471.2852173	7.48
497.0162964	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	550.1925
Annotation	Ipecosidic acid
Peak:m/z	Relative Intensity
161.0918121	0.11
191.2410278	0.26
243.0841827	0.12
301.5602417	0.10
322.0917969	0.05
336.0496826	0.08
350.0293579	0.11
359.2296143	0.67
364.4888916	0.31
384.1856689	0.43
388.1603394	0.06
408.3812256	0.19
446.1181030	0.08
464.3753662	0.09
477.9340820	0.34
482.1206055	0.21
487.3074341	100.00
488.4756470	0.35
490.1514893	0.10
491.2215576	0.26
497.1542358	0.11
504.3098145	0.51
506.3256836	0.39
508.5845337	0.07
514.1801147	0.41
532.1481323	0.30
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	425.16
Annotation	Kadsuralignan A
Peak:m/z	Relative Intensity
110.0020065	0.43
140.2817383	0.07
159.0850525	0.12
163.4043579	0.30
165.2561340	0.09
197.1622925	0.12
211.4111938	0.11
214.2308350	0.05
215.2746582	0.08
232.9092255	0.16
238.9416199	9.35
239.9610596	2.39
240.9526672	0.08
251.0874329	0.21
252.1494141	0.09
254.9847717	0.05
255.9675598	0.14
261.2339783	0.05
267.2080078	0.47
273.1007080	0.47
283.2316895	0.40
287.2605591	0.15
290.1087952	0.08
293.1977234	0.17
294.2229614	0.05
297.0611572	0.04
300.7211914	0.17
305.1836548	0.09
307.4356079	0.58
313.1195984	0.29
315.4976196	0.08
321.2968750	0.40
323.3865356	0.53
325.9934692	8.91
327.2792969	0.15
329.5283508	0.18
331.4328003	0.06
335.3333130	0.23
339.2969971	0.14
345.4439087	0.09
349.4628601	0.18
356.0654907	100.00
357.2268677	77.95
363.1844177	0.08
367.3841858	0.06
371.1519165	0.60
371.8984680	0.16
378.0675354	0.05
379.2804260	0.33
381.2532349	0.17
383.1827087	0.20
383.9639282	0.11
389.2937622	0.62
390.6488953	0.07
393.2986145	0.07
394.9008179	0.35
397.4043274	0.56
406.4653931	0.15
407.2414246	3.44
424.2926941	0.15
426.2179260	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	317.1009
Annotation	Byakangelicol
Peak:m/z	Relative Intensity
90.8581238	0.04
99.0791016	0.02
125.1275482	0.01
131.1378174	0.02
135.0096741	0.01
137.1912537	0.01
145.1356506	0.05
149.1549988	0.01
153.0146790	0.04
157.1043701	0.02
158.9583130	0.09
169.1154022	0.01
174.9973450	0.02
177.1560974	0.07
179.0808868	0.01
187.0164337	0.01
193.2568512	0.07
194.8753662	0.01
197.2009277	0.03
201.1972351	0.02
202.9786682	100.00
203.9057312	0.08
211.0945435	0.02
215.0223694	0.04
217.0419006	0.05
219.0168457	0.04
221.2962341	0.03
229.1672974	0.01
232.8914185	0.53
234.0838013	0.53
235.0790710	1.33
239.3338318	0.04
243.3426208	0.03
245.0019226	0.07
246.9996643	0.27
250.1287231	0.01
257.2015381	0.03
260.0378418	0.02
260.9769592	0.01
262.1672058	0.02
265.4511108	0.05
266.3789673	0.04
271.0796509	0.01
273.2246094	0.02
275.3082886	0.09
282.4288330	0.34
283.3879089	0.16
286.1284180	0.05
287.2653198	0.24
288.3622742	0.02
291.1937256	0.03
292.2301331	0.05
300.2901306	1.16
301.3793335	0.45
302.0382385	0.02
304.1600952	0.02
305.3952026	0.01
307.1791992	0.01
317.0759277	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	317.1012
Annotation	Scandenolide
Peak:m/z	Relative Intensity
124.0644455	0.02
139.0051270	0.02
153.0381012	0.01
157.0413208	0.01
159.2475891	0.06
161.9041901	0.01
177.2442627	0.02
181.2530212	0.02
188.0828857	0.03
198.6204834	0.02
202.2554321	0.01
205.0082397	0.12
226.6865540	0.03
229.2236328	0.04
231.0303040	11.45
232.9858093	100.00
235.4538269	0.03
241.3070679	0.02
245.1258545	0.48
247.0439453	0.04
249.1812134	0.03
257.3136597	0.07
258.4434509	0.03
268.7030334	0.01
271.1951904	0.21
273.0786743	1.24
275.1011353	0.06
275.8943787	0.09
285.5599976	0.03
289.1404114	0.02
296.0086670	0.12
299.1054993	3.94
300.5052795	0.02
301.4141235	0.04
302.0909424	0.10
303.1515503	0.04
308.0185547	0.04
316.2868652	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	623.25
Annotation	Unknow
Peak:m/z	Relative Intensity
175.2092743	0.45
185.0417480	0.95
188.1734314	0.25
195.2471313	0.50
198.0802460	0.44
199.0452423	0.38
201.1855316	0.56
203.0501099	1.25
207.1305542	0.92
209.1676331	1.07
211.0775757	1.16
212.1290283	0.20
213.2945862	0.56
217.0392456	0.58
218.9640198	0.45
221.7485046	0.22
222.9800110	0.62
225.2090149	1.63
229.0380859	0.89
231.1457214	3.50
233.0765076	0.24
235.0924683	0.42
237.1314545	1.07
239.3736115	0.99
240.9231873	0.92
243.3039551	1.19
246.2406464	1.23
247.1536713	0.94
251.3242188	0.65
253.2792053	0.91
255.2798157	0.54
259.0680847	1.03
261.2597351	0.54
263.4352417	1.53
267.3932495	0.34
269.1459961	3.14
271.1182861	1.42
273.3078003	1.41
274.2701416	0.35
275.3007202	1.06
279.2069092	0.57
281.1981812	2.73
283.0317993	1.75
285.2050781	0.76
287.3454590	0.95
289.2136841	2.42
291.0556946	0.36
293.2797852	1.13
295.2089233	1.06
297.3836060	0.79
299.2094116	0.77
301.3770142	0.65
302.2092285	1.12
303.6856689	0.12
304.9136963	0.57
306.3651428	0.09
307.3019409	0.88
309.2081909	1.75
311.4328613	1.76
313.1530762	2.70
314.3824463	0.26
317.2350464	5.61
319.0945435	1.22
321.0416870	2.52
323.3592529	2.01
325.2272339	1.54
327.2094116	0.09
329.1606140	0.18
330.0719604	0.47
330.9954224	1.30
333.3233032	0.48
335.3801270	1.31
337.3264771	0.25
339.1610107	1.31
341.0540771	2.37
342.4956055	0.32
343.3118896	1.14
345.1945190	1.53
347.5321655	0.13
349.2608643	2.12
350.9982910	1.70
353.3764038	1.76
355.2720337	0.69
356.0993042	0.85
357.0110474	1.00
359.1975708	2.26
360.9583740	1.94
361.6420898	0.24
362.4381714	0.34
363.2385864	1.52
366.1583252	0.15
367.3544312	0.76
368.5601807	0.53
371.3878174	1.96
373.3285522	3.61
374.0880127	0.97
375.3295898	3.45
376.3242188	0.34
377.2186890	0.76
379.1810303	1.86
381.2868042	1.71
383.3950195	1.94
384.2943726	0.20
385.1915283	1.39
387.2879639	2.44
389.1897583	3.95
390.2968140	0.38
391.2482910	3.14
392.2291870	1.71
393.2407837	1.76
394.2052002	0.83
395.1966553	1.75
397.2262573	0.88
399.2383423	1.58
401.3536987	0.42
403.1672974	1.31
405.3331909	4.04
407.2436523	1.50
409.2204590	3.43
410.0197754	0.50
411.3617554	0.35
412.7749634	0.14
415.3492432	1.14
417.3953857	1.13
419.2767334	3.69
421.2355347	1.47
423.2420654	1.09
425.4767456	0.77
428.9783325	0.93
430.2885132	0.91
431.2130737	2.29
433.2147217	1.35
435.1918945	2.95
436.4349365	1.27
437.3067017	2.70
438.4069824	0.33
439.0323486	2.96
441.3013306	3.03
443.0034180	1.02
443.7299805	0.54
445.3859863	0.87
447.2287598	4.95
449.2772827	1.01
451.2831421	1.10
453.3282471	3.97
454.3062744	0.21
455.3200684	2.38
457.3053589	2.88
459.2307739	2.54
461.3775024	1.43
463.6444092	0.65
465.1849365	2.81
467.2943726	4.10
468.7396240	1.21
469.4510498	0.54
470.9162598	1.95
471.5167236	1.16
473.2813721	4.49
475.5109253	1.56
476.9024048	1.68
477.8703003	0.24
479.1899414	0.87
481.2687378	6.16
483.4063110	9.99
485.2492065	1.96
487.2647095	0.30
489.3649902	2.14
491.1349487	1.45
493.0569458	0.13
497.2559814	0.68
499.2661743	18.29
501.2901001	33.08
503.2180176	1.26
507.3654175	0.41
509.3240967	3.75
513.1148071	1.21
517.1858521	24.70
519.2544556	15.67
520.6441040	0.78
527.2902222	15.19
535.2350464	3.29
536.9866943	0.72
543.1870728	0.40
544.7488403	5.19
545.3673096	21.10
548.3193970	1.55
550.6939087	0.34
555.0859985	0.32
558.5405273	0.98
559.1782227	6.28
559.8429565	0.13
561.1123047	9.77
563.2024536	100.00
564.1154175	2.97
565.5249634	0.34
569.2714844	0.54
571.0457764	0.82
577.2182007	61.41
579.2570190	2.01
581.2816772	1.09
587.1397095	4.02
589.5797729	0.11
593.1683960	1.37
595.1986084	2.77
605.1455688	17.61
605.7525635	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	402.9167
Annotation	Unknow
Peak:m/z	Relative Intensity
158.9566040	0.26
174.9896545	1.07
215.2864380	0.01
229.1667175	0.06
243.1565247	0.02
244.9674683	0.32
273.0632935	3.98
288.9532776	100.00
289.7817993	0.01
328.9725342	0.11
330.2389526	0.01
330.9469604	0.03
349.1344604	0.01
357.0342712	0.08
358.8585510	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	568.1667
Annotation	Unknow
Peak:m/z	Relative Intensity
162.1146698	0.40
163.0645294	0.12
164.0864563	0.08
175.2136230	0.10
177.0267944	1.24
177.9716034	0.26
180.1416321	0.12
183.0955505	0.21
185.2006073	0.35
192.2664490	0.38
192.9697571	0.23
195.0067139	3.57
197.0920258	0.30
210.2121582	0.65
211.9391479	0.09
213.1248932	11.08
214.1896362	0.13
214.9888611	0.16
220.2367859	0.42
231.1293030	0.07
233.1752625	0.07
238.1444092	1.27
239.5379944	0.11
240.2270813	0.12
252.0722046	0.11
256.0338135	2.94
257.0737610	0.14
262.2560425	0.06
266.1008911	2.97
267.0525513	1.78
271.1414185	0.07
274.0075073	0.15
284.0791626	18.65
285.2018738	0.34
292.0444336	0.10
300.1033325	0.15
300.8866577	0.32
302.1331177	10.70
303.1849060	1.17
305.2085571	0.17
314.2747192	0.20
317.8435669	0.03
320.0634155	100.00
320.9384766	0.05
326.3261719	0.40
329.8995361	0.14
339.1486206	0.12
344.2446899	0.43
345.9325562	0.18
349.6351929	0.04
362.0853882	1.41
368.2263184	0.14
371.2503662	0.05
373.9567871	0.30
380.0593872	0.14
382.2152710	0.34
386.1692505	0.37
390.1499634	0.09
392.0967407	0.92
397.7117310	0.04
406.2456665	0.03
410.1767578	0.84
411.0895996	0.05
415.9969482	0.25
423.1030273	0.11
425.9758301	0.06
427.0412598	0.08
429.2579956	0.12
436.3930054	0.06
438.2545776	0.07
445.2758789	0.10
446.1416016	0.06
448.0863647	0.09
449.9891357	0.35
452.0894165	0.29
463.3936768	0.21
470.6707153	0.17
478.3108521	0.60
480.3413696	0.25
482.2209473	0.03
496.1659546	4.25
504.1891479	0.38
506.2262573	0.60
507.0324707	0.11
508.2339478	0.13
509.1018066	0.25
514.1799316	7.05
519.6530762	0.10
520.4082642	0.09
524.6421509	0.53
529.4354858	0.61
532.1369629	7.49
550.1312866	10.61
551.4943237	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.15
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
197.0142517	0.08
229.2696838	0.06
231.1090393	0.06
247.1668854	0.01
251.2839355	0.08
257.0653687	0.03
273.4940796	0.09
283.2825928	0.04
285.0271606	0.18
297.2229004	0.09
298.2369385	0.07
299.2169800	0.38
300.1780396	0.14
301.1301270	0.82
311.1857910	0.10
312.8782959	0.02
323.2777710	0.10
325.4557190	0.21
327.1276855	15.74
328.2346191	0.25
337.5718994	0.01
339.1503906	0.33
341.2939453	0.15
342.8928223	0.09
353.1775513	0.04
354.4351807	0.02
357.2011719	7.67
358.3374634	0.07
360.1990967	0.06
363.9544678	0.04
367.1296387	0.07
369.2249756	6.09
371.2902832	0.15
375.3682861	0.12
377.0521240	0.02
379.0065918	0.10
381.3122559	0.15
383.1030884	0.21
387.2891846	0.61
391.2890015	0.08
393.3393555	0.07
395.4940186	0.11
399.1691284	10.19
400.0408325	0.03
401.1864624	0.03
402.1417847	0.08
403.2575684	0.07
411.1397095	0.77
413.1193237	0.29
414.3247681	0.02
417.1323853	0.07
423.0368652	0.10
425.1011963	0.05
429.2940063	4.60
431.3701172	0.04
432.1223145	0.02
433.0609131	0.07
435.2431030	0.45
441.3886719	0.20
447.1525879	51.87
448.2596436	0.52
453.2050781	0.32
459.3177490	0.25
463.3140259	0.05
464.7355347	0.09
465.3389282	0.13
471.2438965	2.13
476.4471436	0.02
478.0390015	0.03
483.1663208	0.34
487.3952026	0.07
489.1557007	100.00
490.2301025	0.52
491.0389404	0.04
493.3907471	0.08
495.1115112	0.12
499.1934204	0.21
501.2429810	1.77
505.3369751	0.14
513.0455933	0.09
515.1869507	0.09
517.2784424	0.02
519.1572266	29.16
519.8953247	0.24
521.8121948	0.36
523.6106567	0.11
529.2750854	0.05
531.2571411	2.63
532.0422363	0.07
533.1659546	0.46
537.1735229	0.19
543.2521362	0.20
545.3236694	0.04
547.2988892	1.53
549.3073120	0.68
551.1723022	0.02
555.1625366	1.47
561.1607056	1.01
563.2901001	0.20
565.2099609	0.78
573.1752319	1.21
577.4799194	0.02
581.2640991	0.04
583.0686646	0.03
589.1587524	0.03
591.2633057	7.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	755.2032
Annotation	Orientin 4'-O-glucoside-2''-O-rhamnoside
Peak:m/z	Relative Intensity
266.0992432	0.01
285.0456848	0.49
286.1743469	0.37
300.1881104	0.03
312.9669800	0.01
324.1096191	0.04
327.1560059	0.01
336.3825684	0.01
337.0178528	0.01
340.1810303	0.03
353.1660156	0.01
354.2099609	0.02
357.3306885	0.01
365.3506470	0.12
366.2459106	0.14
369.0895996	0.02
372.2879639	0.01
378.1390991	0.02
383.6657104	0.18
384.4920654	0.04
396.1639404	0.01
399.5701294	0.05
413.2212524	0.02
414.2864990	0.04
425.1502075	0.01
444.1392212	0.01
447.5406494	0.11
448.3497925	0.16
449.0681152	0.04
450.3926392	0.01
454.6308594	0.01
455.4619751	0.01
467.1989746	0.02
468.3247681	0.09
473.3856812	0.04
474.3725586	0.08
478.1091309	0.01
485.3744507	0.33
486.1823730	0.41
499.2730103	0.02
499.9312744	0.01
503.2446899	0.06
504.3523560	0.24
513.0268555	0.02
516.3869019	0.09
530.1238403	0.01
533.0745239	0.01
534.3358154	0.04
546.1990356	0.06
575.0584106	0.01
576.2896118	0.01
578.4938354	0.01
582.4685059	0.01
588.4586792	0.06
593.4307251	33.45
594.2554321	100.00
595.0993652	0.01
595.9426880	0.01
606.2594604	0.03
610.5648804	0.01
612.2416382	0.02
624.3859863	0.05
635.1516724	0.09
636.2436523	0.39
636.9284668	0.00
648.1672363	0.01
666.2340698	0.13
681.0215454	0.01
690.3641968	0.01
694.1475220	0.05
695.8811646	0.06
696.5352173	0.02
707.4151611	0.04
712.2277222	0.09
737.9899292	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1562
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
188.9756165	0.25
201.2563782	0.09
213.2158203	0.10
235.1152039	0.32
255.2969818	0.28
261.972168	0.15
269.0422363	100.00
279.272644	0.17
282.9164429	0.38
293.1673584	0.44
307.368103	0.17
311.1594238	0.45
373.305542	0.30
385.4929199	0.55
397.2080078	0.22
413.1618652	0.65
415.1096191	1.11
459.8341064	0.52
473.2963257	0.67
475.1022949	0.11
477.579895	0.32
488.2160645	0.85
508.6941528	0.14
513.6652222	0.46
517.7033081	0.90
531.2058716	0.76
533.1304321	1.24
541.3049316	0.24
549.5791626	0.54
559.0449829	0.14
559.960144	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	476.2779
Annotation	PE(18:2(9Z,12Z)/0:0)
Peak:m/z	Relative Intensity
139.9709167	0.08
152.8925171	0.04
196.0698242	1.44
214.0895691	1.18
259.1502075	0.02
261.3847656	0.25
277.4152527	0.02
279.2083740	100.00
279.8464661	0.36
415.0466919	0.19
433.3979797	0.23
459.2473450	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	296.88
Annotation	Unknow
Peak:m/z	Relative Intensity
128.8472443	100.00
152.9985504	0.50
170.8679504	0.19
179.1788330	0.22
197.8815613	0.07
202.0109863	0.34
206.8579712	0.08
208.5354309	0.18
209.2081604	0.15
210.0865784	0.04
212.7419739	41.87
213.3496399	0.48
221.8588867	0.29
225.1586914	0.26
253.4314575	0.04
278.3905029	0.27
279.4579468	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	360.1489
Annotation	Lactulose
Peak:m/z	Relative Intensity
105.8800583	0.55
121.9382477	0.13
126.9617767	4.58
144.9748993	3.48
147.2156372	0.11
158.0561218	0.20
162.9117126	5.12
180.0353699	10.68
198.1148071	3.85
229.1766663	0.14
241.2036743	0.37
256.9776001	0.30
258.9595947	4.38
263.3929138	0.25
270.9881897	0.35
276.5834045	5.05
277.1841125	0.37
288.9616394	13.52
305.7784424	0.47
306.7623291	6.78
307.9502563	0.38
317.3437500	0.58
321.3352661	1.13
322.6423340	0.41
324.1737671	6.67
324.8883667	100.00
325.6798706	0.10
341.0287476	0.70
342.8499756	38.93
346.3396301	0.27
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	505.2292
Annotation	Unknow
Peak:m/z	Relative Intensity
160.6220703	0.06
163.0489349	0.10
180.4416809	0.04
181.0666809	0.07
233.3802032	0.05
260.8457947	0.10
265.3925171	0.13
283.0449829	0.04
287.2743225	0.21
294.2276917	0.09
297.2882080	0.05
299.1586914	0.11
301.2188721	0.72
302.0924683	1.03
304.8656006	0.03
313.0395508	0.35
323.1691589	0.06
330.3143921	0.14
334.2934265	0.12
337.5092773	0.27
342.3955078	0.04
343.1188354	0.32
353.2521057	0.15
359.2681885	0.10
361.2999268	0.16
367.2868042	0.28
370.2119446	0.02
382.3262329	0.12
385.3157959	0.70
399.2691650	0.14
400.4024658	0.19
401.2519226	0.24
403.5129700	0.03
409.4452209	0.17
415.4093628	0.11
429.2989807	0.12
445.2211914	0.35
445.9815369	0.05
459.1881714	100.00
459.8702087	0.25
461.2087708	0.19
463.2697144	0.91
467.1930847	0.04
469.3632507	0.08
471.8154907	0.03
477.0626526	0.21
487.3351440	0.48
489.9934998	0.17
491.1477661	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	447.09
Annotation	Luteolin 5-glucoside
Peak:m/z	Relative Intensity
161.0864563	0.03
174.9440765	0.03
178.9299316	0.04
195.3828125	0.03
199.0597229	0.02
215.8378906	0.07
220.9601593	0.14
223.2089539	0.02
261.0020752	0.05
267.3885193	0.03
285.2054443	0.46
297.1784058	0.06
299.2737732	0.06
325.1925659	0.24
327.0955505	100.00
329.0215454	0.02
331.3279419	0.04
335.2269287	0.02
337.2100830	0.02
339.2189331	0.84
343.4254456	0.02
349.4394531	0.02
351.1156921	0.13
353.2705688	0.05
357.1333008	49.91
365.1994324	0.04
367.2063599	0.10
369.1604309	5.01
371.2886963	0.81
378.7311096	0.04
381.1726074	0.18
382.9844971	0.11
387.2535706	1.06
393.1626892	2.65
399.2875061	0.93
401.1803284	0.21
403.4574890	0.15
405.1866760	0.09
411.2244568	1.52
415.3871765	0.13
417.3918762	0.07
429.1968079	7.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	792.7892
Annotation	Unknow
Peak:m/z	Relative Intensity
273.1806030	0.17
288.9158020	0.89
305.0075073	1.77
389.8307495	0.03
402.8906860	0.53
418.9365234	2.83
434.8666382	3.96
438.7244263	0.07
451.2232056	0.04
453.4988403	0.01
517.0701904	0.03
532.8272095	2.64
533.4481201	0.03
548.8691406	15.44
564.7591553	7.09
646.7009888	0.16
662.7487183	9.68
676.7519531	0.18
678.7756348	100.00
689.6256714	0.06
702.0778198	0.07
702.8490601	0.03
717.8803711	0.05
718.8224487	0.09
719.4755859	0.11
731.8839722	0.03
744.8943481	0.02
745.6420288	0.04
746.7409668	0.22
747.3523560	0.03
748.6693726	0.10
764.2052002	0.06
774.9035034	0.11
776.4929199	0.14
777.1194458	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	431.0984
Annotation	Vitexin
Peak:m/z	Relative Intensity
147.2444458	0.06
150.7986755	0.04
161.1228333	0.02
168.7220764	0.03
191.0026245	0.03
203.0603333	0.01
265.2563171	0.02
267.0201721	0.01
269.0188904	0.07
281.4507446	0.01
283.1207581	0.76
293.0853271	0.06
311.0614014	100.00
312.0991516	0.29
312.9927673	0.04
319.1790771	0.07
321.2914734	0.02
323.3021851	0.20
324.8781738	0.02
335.2311096	0.03
337.3038025	0.03
341.1951904	7.10
342.977417	0.01
353.2814941	0.52
355.452179	0.10
365.2669373	0.02
367.213623	0.06
371.1670227	0.29
377.2155151	0.32
383.1160583	0.08
385.0238342	0.05
389.5895081	0.06
395.0361633	0.06
413.2015686	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	623.1609
Annotation	Butrin
Peak:m/z	Relative Intensity
221.4373016	0.02
298.1063232	0.06
312.1739502	0.65
323.0702820	0.02
337.4392090	0.08
340.1922607	0.07
341.2249146	0.29
350.9692993	0.02
353.0488281	0.17
355.2492065	0.20
364.9769287	0.15
366.1895142	0.05
367.1948242	0.14
368.1767578	0.15
369.9274902	0.13
381.3833008	0.01
383.1674805	29.45
384.2178955	0.46
395.1712036	0.40
397.5008545	0.05
403.2648315	0.02
407.4105225	0.04
409.2422485	0.06
410.0530396	0.02
413.2022705	12.50
414.2154541	0.16
419.2559204	0.07
423.2969971	0.03
425.1605835	1.11
427.2435303	0.85
428.4312134	0.07
433.4142456	0.14
437.6093140	0.05
441.3849487	0.05
443.2932129	1.64
444.2631836	0.03
449.2312012	0.08
455.1310425	0.67
456.2922363	0.10
457.2052002	0.01
459.9694824	0.04
461.2219849	0.08
463.2819824	0.08
467.2935181	1.00
474.9296265	0.04
479.1422729	0.19
485.1806030	2.03
486.2564697	0.14
488.3536377	0.19
497.0410767	0.01
501.1547241	0.24
503.1571655	100.00
504.2092896	2.32
513.2615356	0.07
515.2886353	0.75
527.1868896	0.08
529.0213013	0.03
531.3668213	0.04
533.1823120	13.72
534.2077637	0.38
545.2232666	1.18
546.5961304	0.19
547.2894287	0.75
557.4470215	0.04
559.4454346	0.13
563.3548584	0.63
564.6234741	0.03
569.4003906	0.18
575.1149902	0.51
575.7857666	0.05
576.5490723	0.03
587.1630859	0.66
588.2066040	0.07
593.3433228	0.22
605.2842407	3.77
606.2554932	0.01
608.3312378	0.32
609.1700439	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Diosmin 
Peak:m/z	Relative Intensity
196.0821381	0.09
202.1662292	0.21
203.5086365	0.09
205.1395874	0.31
215.1012268	0.22
223.1870117	0.07
255.1455536	0.18
269.5510864	0.13
271.1641235	0.10
273.2759399	0.57
285.1462402	0.14
285.7548218	0.44
293.1838379	0.07
295.3781128	0.09
301.0631104	12.14
303.1690369	0.20
310.8670044	0.19
312.6633301	0.11
313.2677917	0.78
314.1769104	0.09
327.3164062	2.13
328.4516602	0.27
341.1213989	0.12
343.1347656	0.50
345.3686523	0.21
359.3735352	0.17
374.9107666	0.13
396.3773193	0.08
397.3377686	0.39
407.6969604	0.29
409.4506226	0.41
419.4491577	0.36
420.8317261	0.12
421.6530151	0.52
429.2640381	0.10
433.2122192	0.59
439.7706299	0.22
441.4487915	0.09
447.1340332	1.65
451.3546753	0.08
453.5059204	0.18
458.3550415	0.27
459.4104004	0.08
463.1078491	100.00
463.7561646	0.17
465.2183228	0.10
465.8554077	0.34
471.1176758	0.39
473.0547485	0.66
475.2143555	0.10
477.359375	0.29
479.4960327	0.11
488.2106934	0.31
489.171814	0.06
491.6685181	0.16
495.7509155	0.23
497.2723389	0.15
505.2110596	0.21
520.5883179	0.57
524.9542236	0.28
533.3817749	0.14
537.6295776	0.12
541.3112793	0.73
543.0828857	0.19
547.5420532	0.06
548.9697266	0.10
551.6176147	0.55
553.7896118	0.14
558.9005737	0.17
560.3789062	0.32
562.6450195	0.31
563.510498	0.39
565.6516724	0.29
567.234314	0.05
573.1698608	0.18
575.1378784	0.10
578.2074585	0.49
590.4575195	0.84
591.4609985	3.20
592.206543	0.90
609.7473755	0.09
612.3400269	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
217.3224487	0.03
219.0606689	0.11
220.8823547	0.05
239.9658203	0.03
271.3917236	0.02
286.4965210	0.07
301.2101440	0.64
302.2794800	0.02
303.2558899	0.11
313.0769043	0.15
325.1857300	0.23
336.1039429	0.03
337.2043457	0.04
343.1858521	4.47
344.0061035	0.01
349.3092041	0.08
353.0756836	0.02
359.9594727	0.02
367.2089844	1.67
373.1828003	0.02
376.0592041	0.06
381.2765503	0.09
385.1900635	0.03
391.0234985	0.06
397.1782837	2.76
403.2603760	0.04
409.0430908	0.77
409.6476440	0.17
411.3586426	0.08
423.3271484	0.03
427.1591187	1.56
427.8603516	0.02
428.9478760	0.08
431.6798096	0.03
435.1072998	0.06
439.3061523	0.06
441.1088257	0.08
442.5356445	0.09
445.1494751	17.41
447.1731567	0.30
451.2873535	0.03
453.2611084	0.09
457.3063965	0.08
459.4100342	0.05
463.0776978	100.00
463.7504883	0.12
465.5459595	0.06
468.8944092	0.08
469.5100708	0.09
471.3600464	0.21
476.8775024	0.07
478.4739380	0.09
487.2217407	1.30
489.1535645	0.76
495.3458862	0.19
507.3892212	0.02
513.2201538	0.43
519.1210327	0.07
524.9098511	0.32
525.5124512	0.10
527.3740845	0.01
529.2619019	0.01
537.1537476	0.30
543.1599731	1.20
547.1748657	0.03
555.1403198	1.29
560.0819702	0.02
565.3912964	0.22
566.3413696	0.02
573.1937256	2.99
591.0995483	9.82
592.2527466	0.26
610.1200562	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	213.1479
Annotation	12-hydroxy-3Z,6Z-dodecadienoic acid
Peak:m/z	Relative Intensity
64.9717560	0.17
66.9350891	2.80
69.0703125	0.42
70.9285736	6.69
76.9276657	0.09
78.6973343	0.26
80.9903870	5.14
83.0007019	0.96
85.1120758	0.17
88.0389710	0.23
90.8696747	0.52
92.9198608	29.64
94.9198608	100.00
97.0256348	2.78
99.0004730	0.53
101.1400604	0.04
107.0314178	29.92
109.0306091	17.33
110.8768158	0.84
113.0876007	0.93
115.0913849	0.18
117.3009644	0.08
118.7008972	0.08
121.0397034	0.46
123.0932770	0.58
125.0252991	3.61
127.0029755	0.19
127.9758301	0.14
129.1035767	0.07
130.7774811	0.06
134.9995575	98.57
135.9373016	0.07
136.9687500	0.20
139.0270538	0.11
140.9973297	0.14
143.0782318	0.48
150.7889557	0.23
153.0000458	95.69
154.9391327	0.52
157.1803741	0.18
158.8598328	0.08
165.1995392	0.05
167.1631470	0.46
169.0201874	0.74
171.0596161	1.41
171.9330902	0.05
177.1295319	2.40
183.5580292	0.10
185.0942993	0.50
186.0888672	0.19
192.1575470	0.13
195.0077057	7.30
195.6124725	0.16
200.8182068	0.12
213.1824646	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	258.11
Annotation	Glycerophosphocholine
Peak:m/z	Relative Intensity
83.9454803	0.03
85.9414749	0.06
95.8963623	0.08
103.9840546	100.00
123.9675293	0.02
124.8545685	0.03
154.9921112	0.03
184.0714417	0.20
199.1153107	0.03
212.1830902	0.05
240.2190399	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.18
Annotation	Hesperidin
Peak:m/z	Relative Intensity
174.0913086	0.42
185.1727905	0.50
188.3727264	0.31
197.918335	0.37
199.5226898	1.23
200.9529572	0.30
213.0638885	0.31
215.1140442	0.41
217.4041748	0.21
227.1267395	0.37
239.3610992	0.61
241.0355835	0.46
242.0824585	1.03
251.0438385	0.13
255.0680847	0.27
257.259552	0.79
283.112915	1.82
285.3463745	0.22
286.280365	2.27
299.2445068	1.76
300.117981	3.71
301.0822144	100.00
301.9493408	0.26
312.2765503	0.16
325.1199341	1.26
368.6776123	0.82
370.2980347	0.52
399.3236694	0.33
400.0232544	0.30
407.3704224	0.32
429.2706299	0.73
437.4772949	0.29
451.2290039	0.34
463.149292	0.26
465.2783203	0.59
471.1479492	0.83
477.3988647	0.34
489.1791382	11.47
501.1769409	1.21
505.2258911	0.44
513.6980591	0.31
519.302124	1.98
528.2905884	0.69
543.2875366	0.65
547.9255371	0.26
554.9533081	0.99
562.7932739	0.31
573.1843262	1.35
588.4763184	1.60
591.3294067	1.81
593.6424561	0.78
600.1316528	0.70
610.6652222	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	546.7223
Annotation	Unknow
Peak:m/z	Relative Intensity
175.1918793	0.05
188.1287842	0.14
188.9339447	0.13
193.1993256	0.97
196.1646118	0.10
202.5150757	0.25
203.2714081	0.14
217.2784882	0.05
221.2396851	0.04
231.0854492	0.12
245.8803253	0.16
261.1878357	0.62
269.2487793	0.05
287.3526611	0.62
295.1430969	0.09
296.5169067	0.14
306.6785278	0.09
311.1339111	0.12
322.1840210	0.19
325.2266235	0.11
329.2117920	0.84
330.0856934	0.13
339.3232422	0.32
340.7438354	0.25
342.9561157	0.11
352.3047485	0.05
356.1201172	0.14
357.0266724	0.12
359.3003540	0.14
386.0011597	0.96
388.9490967	0.19
390.0581055	0.63
390.8359375	0.11
394.6254272	0.06
404.2454224	0.16
408.4902344	0.10
409.4501343	0.05
410.7664185	0.09
411.4812622	0.04
414.0373535	0.13
415.1221313	0.20
416.2424927	0.10
445.3508301	0.12
451.1950684	0.20
456.0474854	0.11
457.9677124	3.82
458.6235352	1.83
462.7691650	0.32
467.0995483	0.19
470.5350342	0.08
477.2900391	0.38
478.6984253	0.18
479.4808960	0.04
487.5310059	0.04
489.3126221	0.21
496.3256226	0.24
497.1378784	0.09
498.3555298	0.12
501.0248413	0.18
502.3889160	0.06
506.2127075	0.19
519.4865723	0.18
523.3134155	0.03
526.1304932	100.00
527.5297241	0.71
528.5473633	1.09
529.5194092	0.87
530.5903931	0.15
531.2896729	0.11
537.5325317	0.33
541.1792603	0.43
545.9927979	0.28
546.7136841	1.90
548.0922241	0.17
576.9812622	0.10
578.2061157	0.26
579.6970825	0.16
586.7693481	0.19
587.4154663	0.12
713.4860229	1.79
714.2720947	0.32
723.0902710	0.07
754.9119263	0.28
763.3652344	0.28
765.3234863	0.41
778.5922241	1.34
779.4448242	0.28
914.0719604	0.45
914.9555054	1.91
915.8798828	0.65
955.9982300	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	385.0777
Annotation	O-Feruloylgalactarate
Peak:m/z	Relative Intensity
110.9351654	0.21
128.9510956	2.54
137.0076294	0.04
144.9339294	0.18
147.0137329	3.22
153.2312317	0.04
173.0641479	2.25
177.2222595	0.02
181.1112976	0.42
191.0434265	100.00
193.0839233	0.32
209.0576324	19.27
220.3358307	0.04
222.9175720	1.13
231.3085632	0.05
241.0600586	0.05
247.1334534	1.57
249.0412903	0.10
263.0270691	0.03
265.3171082	0.04
277.3401794	0.11
281.9528809	0.04
295.1464233	0.04
325.0482788	0.16
341.0291443	0.15
349.1441040	0.15
357.3003845	0.06
367.0897522	8.92
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	650.315
Annotation	Unknow
Peak:m/z	Relative Intensity
262.9125366	0.05
311.2783203	0.03
321.3009033	0.04
361.3439941	0.02
386.0015259	0.05
398.0639648	0.04
405.2975464	0.03
446.0040283	0.06
472.3547974	0.13
478.1574097	0.02
506.4979858	0.07
515.1779175	0.04
517.2649536	0.04
528.1443481	0.15
529.3087158	0.08
535.2877197	0.03
540.0783081	0.08
543.3654785	100.00
544.0083618	0.24
564.4193115	0.51
578.9090576	0.14
587.2572632	23.85
590.2807007	0.27
604.2774048	0.04
606.2386475	0.12
612.1248169	0.15
618.3109131	0.09
632.3100586	0.24
641.3547363	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1394
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
83.0378189	0.11
111.2792892	0.10
117.2229309	0.09
119.0978699	0.30
121.0952759	0.43
123.0908127	5.95
132.9276123	0.07
137.0342865	0.11
139.0168762	0.30
142.9793396	0.16
144.9943848	0.44
152.9680634	0.95
155.1330109	0.04
159.2339935	0.25
165.3395844	0.16
167.2435760	0.04
168.9463196	0.65
171.0657654	10.23
176.3224335	0.10
177.2203979	0.20
179.0431366	0.79
181.1086884	0.03
189.1319275	3.28
193.0580750	0.12
201.0333557	3.92
202.9357300	0.09
207.1196289	6.29
211.2659302	0.05
219.0299683	11.61
221.1806335	0.24
237.1002808	100.00
252.9633789	0.09
261.3413086	0.02
263.2564697	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	455.22
Annotation	(-)-10-Methoxyvincamedine N-oxide
Peak:m/z	Relative Intensity
128.3376465	0.16
131.9866028	0.10
135.1882782	0.07
148.1246796	0.19
161.0691681	0.33
163.1208191	0.08
172.9101105	0.11
174.8722534	0.05
177.0559692	0.08
179.0624084	0.14
180.1242371	0.03
187.2592316	0.04
193.0617065	0.20
199.0650024	0.16
201.0122070	0.25
203.0319519	0.15
204.8303986	0.06
207.0504761	0.04
209.1064453	0.06
211.0765076	0.27
212.4851379	0.15
215.2353973	0.30
215.9288635	0.49
224.8242188	0.33
226.9902954	0.04
232.3122253	0.07
239.4304657	0.14
240.9815674	0.10
246.6223450	0.21
257.1612854	0.35
261.2901611	0.08
263.4841614	0.10
269.0484619	0.08
277.2066956	0.07
281.1748962	0.14
283.2302246	0.98
285.1086731	0.24
287.4262085	0.16
288.1939087	0.20
293.1701660	0.12
295.1869507	0.33
297.0368652	0.18
298.2617188	0.10
299.3994751	0.21
301.3719177	0.26
302.5301514	0.59
303.4434814	0.45
305.1750793	0.29
307.3312988	0.24
313.3113098	13.93
314.3870239	58.79
315.1927490	0.26
317.4524536	0.11
321.0310059	0.51
326.2735291	0.08
328.2671509	0.51
337.4244080	0.06
341.3721924	0.22
351.2377014	0.79
353.2373047	0.25
355.0847168	0.19
357.2012939	0.26
359.1885681	0.38
363.2367554	0.67
365.3010559	0.13
370.9739685	1.29
373.6215515	0.07
377.1950073	0.26
385.8329773	0.53
387.1444092	2.33
391.1664734	0.33
393.5121460	2.33
394.2335205	4.15
407.2866516	0.15
409.2867126	2.42
411.3283386	2.33
413.4347534	0.16
419.2107239	1.07
423.0240173	0.07
427.8619690	0.07
437.1361389	100.00
437.8677063	0.61
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	649.2862
Annotation	Excavatolide U
Peak:m/z	Relative Intensity
187.7313538	0.03
191.0133820	0.03
203.1314392	0.12
216.0567169	0.08
227.4743042	0.06
247.1425171	0.08
284.1546631	0.03
299.1313171	0.03
300.9972534	0.02
305.1471558	0.14
311.3527527	0.11
321.2090454	0.27
323.1807251	0.75
325.4202576	0.09
329.4496460	0.05
337.0786133	0.07
339.2362671	0.04
341.1782837	0.05
342.8900757	0.06
381.4734497	0.10
385.1026001	0.04
417.1414185	0.05
423.3771973	0.66
437.3701172	0.08
441.2741699	0.30
443.3002319	0.36
452.9651489	0.13
456.0830078	0.03
481.3710938	0.16
483.0944824	0.14
485.2775269	0.12
487.0983276	0.16
493.5349121	0.05
505.1750488	2.37
515.2707520	0.08
527.3700562	0.07
543.2339478	1.06
547.2453003	0.42
557.1851196	0.11
561.2562256	0.58
563.2727661	0.24
569.2434692	1.07
572.3257446	0.17
585.3936157	31.12
586.3037720	0.07
587.3784790	0.44
589.3023071	0.04
593.1702881	0.14
603.1469116	100.00
603.7748413	1.23
605.1229858	0.86
605.7411499	0.29
615.1811523	0.17
617.3168335	0.13
619.4139404	0.41
631.3031616	0.29
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	579.1687
Annotation	Vitexin-2''-O-rhamnoside
Peak:m/z	Relative Intensity
221.0918274	0.16
230.2758331	0.06
231.3607178	0.18
233.1249847	0.36
271.0639648	12.86
271.6690063	0.03
273.7822876	0.76
289.2555542	0.12
313.1529541	0.14
331.1230469	0.63
335.0476685	0.12
342.1975708	0.27
347.3068848	0.13
358.5764771	0.11
372.4179688	0.47
383.739563	0.21
395.4185791	0.19
397.1535645	0.10
402.281311	0.53
403.5759277	0.44
407.065979	0.15
415.0291748	0.13
417.0787354	0.65
433.119873	100.00
433.8660278	0.03
443.751709	0.06
449.3601074	0.05
455.1415405	0.22
483.1787109	0.06
509.1444092	0.15
515.5643921	0.16
535.6065063	0.28
536.4800415	0.19
538.092041	0.47
543.3855591	0.63
547.3158569	0.13
549.1297607	0.75
552.1691284	0.25
561.3228149	0.95
562.7654419	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	513.2133
Annotation	Gomisin E
Peak:m/z	Relative Intensity
149.1249542	0.16
150.2550964	0.13
169.1697388	0.07
173.0979462	0.21
177.2822418	0.25
185.1255951	0.06
187.0890045	0.14
191.1346283	0.07
205.2286530	0.27
208.2156677	0.05
210.9692688	0.12
213.1722260	0.12
221.0247803	0.64
227.1568909	0.17
228.2796021	0.09
231.1471252	0.51
235.9857178	0.10
236.9727478	0.03
243.0911255	0.23
247.1281128	0.12
249.3121185	0.12
257.1461182	0.47
259.0399170	0.08
261.0947876	0.06
262.5057678	0.17
263.2078857	0.20
267.4628296	0.05
269.2602539	0.15
271.2347107	0.57
275.2254028	0.60
279.3444214	0.20
281.2994385	0.05
283.2374268	0.31
288.9689331	0.58
293.4667053	0.03
296.0824585	0.33
297.2673645	0.17
298.9902954	0.17
300.8942871	0.03
301.5325317	0.16
306.1015625	0.16
307.1526489	0.06
308.0725708	0.03
311.2109985	0.22
313.3383179	0.06
315.1861572	0.05
321.2496948	1.83
322.1266479	0.06
323.2176514	0.24
325.4170532	0.31
327.2813110	0.22
331.1255493	0.10
333.1681519	2.29
335.2208862	0.13
337.3417969	0.58
339.2593994	0.47
341.2184448	1.00
347.0797729	0.17
349.0831909	0.05
351.1882324	0.20
353.4043579	0.03
355.3256836	2.43
357.2559814	0.54
363.4578247	0.16
365.2647705	0.48
367.1452026	0.93
367.8209839	0.06
371.7244263	0.20
373.3101807	0.21
374.6168213	0.32
375.3710938	0.17
379.2666016	0.70
381.3531494	2.15
383.2750244	1.49
389.2419434	0.08
393.1345825	0.85
395.0825195	0.30
397.3737183	0.38
399.2336426	2.48
403.2842407	0.35
405.4681396	0.08
407.2637329	0.13
409.1644897	0.67
411.1380615	0.04
413.2000732	0.06
415.3195190	0.26
419.1501465	0.06
421.1115112	0.17
423.3259277	0.69
427.1759033	0.37
433.3259277	0.78
437.1276245	0.69
441.3931885	0.62
449.4801025	0.13
451.2400513	3.55
453.2126465	5.31
455.2859497	1.88
457.0978394	0.15
459.2141113	0.43
466.9685669	0.06
471.5471802	0.06
477.3388062	1.64
480.1106567	0.09
482.2283936	0.08
485.2647095	100.00
495.2347412	18.58
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	569.1508
Annotation	Tenuiphenone B
Peak:m/z	Relative Intensity
160.1037750	0.04
179.1499634	0.15
191.1415710	0.04
203.1757812	0.05
209.0214844	0.09
227.2850647	0.02
239.1766663	1.86
251.1744843	0.16
273.2644958	0.12
281.1504211	1.16
323.1937866	0.09
340.3300171	0.03
343.3913574	0.04
359.5161743	0.03
371.3289185	0.20
374.0576782	0.07
387.2545776	0.02
388.1907959	0.03
389.2402344	0.16
407.1104126	100.00
412.2884521	0.08
421.3412476	0.12
425.3558350	0.23
432.1837158	0.02
438.1434326	0.18
447.1408691	0.04
453.7021484	0.07
460.4187012	0.06
467.0072021	0.02
479.2287598	0.02
491.2908325	0.02
501.3909302	0.02
505.1609497	0.05
507.4129028	0.07
509.2675171	0.03
523.0663452	0.07
524.2849731	0.02
525.2114868	0.14
533.0731812	0.05
535.2401733	0.09
549.8889160	0.05
551.2761230	0.14
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	358.1482
Annotation	Bakankoside
Peak:m/z	Relative Intensity
108.9371948	0.06
122.9708862	0.23
127.0769043	0.14
130.0793762	0.02
133.1411896	0.20
138.6760101	0.15
147.1588745	0.06
149.1806030	0.06
150.9992981	1.88
152.9487305	0.10
155.2300568	0.02
161.0199280	0.89
178.1354370	1.90
179.0627594	20.51
179.7097778	0.03
191.3365479	0.08
196.1159363	100.00
197.1290588	0.11
199.2734375	0.06
201.9333191	0.03
203.1395874	0.35
208.1312561	0.63
214.0783997	0.06
217.1759644	0.04
220.4071655	0.24
221.2460632	0.40
223.7206726	0.01
226.0651550	0.02
228.9556885	0.18
231.0265503	0.03
232.0089417	0.16
233.8461304	0.02
235.1372681	0.24
238.1202393	1.69
245.0154114	0.83
252.7794800	0.08
254.1994324	0.18
255.0601196	0.21
258.8094788	0.02
262.1834717	3.05
268.1177063	0.19
271.1050720	0.10
274.1563721	0.31
275.1358337	0.20
286.1075439	0.30
287.1465759	0.45
288.2896423	0.08
292.1306763	1.51
298.8159790	0.03
300.4436646	0.06
304.2066040	1.48
305.1340332	0.27
309.0633850	0.04
312.2217407	0.02
313.9992371	0.09
315.1293640	0.02
316.1264648	0.02
322.1070557	3.11
323.1100464	1.26
327.0889893	0.29
335.0286255	0.02
340.2165222	15.86
341.2303162	0.05
344.1694641	0.16
352.6353455	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.16
Annotation	Rutin
Peak:m/z	Relative Intensity
195.0787354	0.01
201.0509796	0.05
210.0611267	0.03
218.2115479	0.07
219.0079651	0.10
225.0339661	0.04
229.1367798	0.06
237.197464	0.05
242.9674835	0.02
254.3519745	0.02
255.0752869	0.10
257.1065063	0.29
268.40979	0.02
285.3588867	0.04
287.1464844	0.01
299.038147	0.04
303.0590515	100.00
319.3376465	0.03
326.9161987	0.02
343.5889893	0.05
345.1464233	0.94
368.1757812	0.04
369.3366699	0.08
393.3922729	0.01
399.0976562	0.05
410.928894	0.09
413.2496948	0.06
415.3290405	0.04
430.9244385	0.10
433.3983765	0.04
437.1357422	0.01
441.171814	0.01
445.2879639	0.15
446.4799194	0.20
447.2560425	0.90
448.5452881	0.87
449.151062	2.33
453.0472412	0.02
463.3444214	0.26
464.9640503	24.25
465.6762085	0.08
471.3280029	0.04
472.3922729	0.01
473.315979	0.03
486.5292358	0.04
491.1738892	0.22
496.8748169	0.07
514.9101562	0.03
522.2333374	0.04
524.3895874	0.14
525.3485718	0.59
527.4434204	0.07
530.3093872	0.06
539.1984863	0.03
544.8912354	0.01
549.3651733	0.05
557.2958374	0.31
566.6103516	0.31
567.435791	0.45
575.1866455	0.15
593.0430298	0.86
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	262.0568
Annotation	Ascorbalamic acid
Peak:m/z	Relative Intensity
82.1550293	0.11
86.1911926	0.15
95.9945679	22.79
97.9163437	0.71
101.1210632	0.08
110.1469727	0.05
112.9831085	0.15
113.9537201	0.49
115.9315186	0.50
116.9984589	0.06
118.9138947	0.58
126.0120544	0.38
128.0373535	9.97
128.8539886	0.48
131.1490021	0.27
138.0342865	4.45
138.7699280	0.28
139.9711609	1.82
142.0267639	40.58
143.8208618	0.18
147.1193237	0.26
156.1396637	2.93
157.9779510	94.56
158.7835236	0.21
160.1846161	0.24
170.1583557	0.98
172.0228119	6.56
174.1199646	0.39
174.8476562	0.37
182.0040436	1.27
184.0282440	0.12
188.0151215	2.51
199.9753265	13.23
201.9822693	100.00
213.9648895	0.33
218.0109100	22.67
219.0472260	6.89
232.0139160	0.32
244.0484467	3.08
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	381.08
Annotation	Unknow
Peak:m/z	Relative Intensity
186.3771515	0.15
191.9578247	0.24
192.9457855	1.43
194.1959381	0.70
208.9793396	55.76
210.9000702	100.00
211.9166412	0.19
212.7380219	0.77
219.0523987	0.38
235.2604065	0.17
236.0635071	0.25
247.8141785	0.51
249.0194092	1.84
250.0818481	0.28
260.9668274	0.20
266.1640015	0.33
283.2342224	0.15
291.2047424	0.78
294.8739624	0.99
296.7348633	12.52
334.8828735	3.81
363.0458984	5.62
363.9942932	1.73
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	658.1635
Annotation	Norbergenin
Peak:m/z	Relative Intensity
287.0876160	0.90
288.0451355	0.04
349.9296875	0.03
357.2731323	0.01
501.9732666	0.01
513.1512451	0.02
514.4598999	0.04
595.1873169	100.00
595.8494873	0.15
639.8710938	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	625.1737
Annotation	isorhamnetin-3-O-rutinoside
Peak:m/z	Relative Intensity
202.8938599	0.01
224.8150177	0.05
228.1440887	0.03
229.3153534	0.02
243.1031189	0.07
255.086731	0.09
257.0619507	0.04
273.9695435	0.06
284.305542	0.07
285.0227661	0.24
286.1366272	0.06
302.0435181	0.85
317.068512	100.00
317.6691284	0.15
341.1604614	0.04
343.0028687	0.03
359.0701904	0.81
359.7908325	0.06
369.2173462	0.03
377.0648804	0.08
385.0758667	0.06
409.3731079	0.07
413.0500488	0.11
425.3289185	0.05
427.3267212	0.09
443.0001831	0.26
445.1329346	0.15
449.3865356	0.05
450.6224365	0.02
454.322937	0.03
461.1418457	1.50
462.28479	0.41
462.9487305	1.84
463.635437	0.01
477.3642578	0.05
478.9541016	20.09
479.6989136	0.15
487.2208252	1.21
489.3704834	0.02
503.118042	0.05
505.0412598	0.48
511.1697388	0.19
521.2445679	0.23
529.1335449	0.10
541.2173462	0.33
553.3163452	0.15
559.144165	0.31
565.3463745	0.01
571.2415161	0.21
578.5901489	0.05
581.27948	0.08
589.1854248	1.01
597.3754272	0.05
607.1496582	3.33
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	535.325
Annotation	Fungicide K 99-5278A
Peak:m/z	Relative Intensity
151.0316467	1.60
153.1214600	0.30
158.8752747	0.06
165.9817963	0.03
167.9904480	0.25
169.0706940	0.72
170.0976562	2.02
172.3155060	0.17
184.3134155	0.08
186.0754395	0.75
191.0914001	0.10
192.0012665	0.07
193.1753235	1.12
194.1894531	0.27
195.1165161	0.10
206.9402161	0.25
208.1911621	0.12
209.2085419	0.32
210.1771393	1.67
211.2135162	0.79
212.2825775	0.82
213.1300659	0.04
221.9788208	0.64
223.1089478	0.10
224.1658478	0.22
225.3593750	0.26
226.2048035	1.58
227.6123962	0.24
228.2890930	2.03
236.0721588	0.21
238.4207611	0.25
240.2401123	0.11
241.2876892	0.06
242.4453125	0.06
243.5396729	0.07
248.1542816	0.14
250.1371155	0.35
254.1081543	0.21
263.3707275	0.32
264.2734375	0.19
265.2352295	0.33
266.2329102	1.49
267.5574951	0.54
268.3124390	0.37
269.1969604	0.21
279.0995483	0.09
280.1614075	0.06
282.0764771	0.19
282.9705811	0.37
285.4205017	0.31
286.1907959	0.26
293.4294128	0.19
295.4976807	0.08
296.9317322	0.45
298.3466187	0.42
299.0534668	0.07
305.2019653	0.09
307.6362915	0.19
308.5087280	0.08
309.5421753	0.71
310.5883179	0.07
311.2454834	0.21
322.2863159	23.02
323.2535400	2.87
324.2778320	0.39
325.2929077	2.22
326.2319946	1.32
327.9284058	0.12
330.2831421	0.08
331.0561523	0.33
337.2531128	0.25
338.2600098	0.05
340.2006836	100.00
341.2859497	0.68
342.3074951	0.57
343.3134766	0.07
348.2423096	0.19
351.3609009	0.46
355.4830322	0.11
356.4333496	0.30
364.3366699	7.47
365.3597412	2.65
366.3598633	0.14
367.1649170	1.36
368.3621826	0.83
373.6476440	0.04
377.6953125	0.05
378.7655640	0.32
379.4366455	0.24
380.6824951	0.31
381.5555420	5.37
382.2963257	42.48
383.3650513	0.46
385.0093994	0.20
388.1333618	0.33
391.5017700	0.07
394.2578125	3.31
395.5283813	0.04
396.3552246	1.24
397.2849121	0.12
398.3071899	1.32
401.4711914	0.09
402.2764282	0.17
406.3487549	0.91
408.5177612	0.23
410.2858887	0.09
417.2450562	0.14
420.3776245	0.76
421.2738037	2.11
422.2711182	0.49
424.3848267	1.45
436.3664551	0.54
438.4522095	26.65
439.6224976	0.47
448.3123169	0.08
450.4315796	0.43
456.4641724	0.16
462.3063965	0.60
463.7872314	0.16
465.4548950	0.23
466.2844238	0.49
474.3902588	0.66
477.2135010	0.52
478.4103394	1.31
491.3828125	5.08
492.4249878	0.49
493.1785278	0.07
499.5050049	0.07
508.4133911	1.12
517.3667603	3.09
518.5703125	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1902
Annotation	Hymenoside E
Peak:m/z	Relative Intensity
172.1483307	0.17
175.1736450	0.06
176.9779663	0.02
179.1795654	0.16
194.9874573	1.81
205.2616425	0.06
207.0871582	0.25
212.9989624	0.76
215.2200928	0.47
227.3128357	0.10
230.8947296	0.20
233.0324860	0.55
237.0031281	0.16
239.1766052	0.09
240.9584045	0.04
248.7539825	0.37
251.0016937	0.25
253.3112488	0.09
254.9124756	0.43
255.8270569	0.78
257.1368408	38.48
263.1691284	0.46
267.2609863	0.07
269.0217896	1.31
270.2218018	0.11
271.0158386	0.55
273.1101074	0.29
277.3416138	0.27
278.0242920	0.17
281.1529541	2.06
282.9902344	0.08
285.2012329	0.15
287.1888428	0.03
293.2130737	0.03
296.9275513	0.16
299.1865845	13.34
301.1149292	0.07
309.0628052	0.37
313.2329712	0.73
317.1330566	8.20
323.2368774	5.55
325.0397949	0.17
330.7854614	0.14
331.5135498	0.05
333.1276245	0.17
334.9802856	0.12
337.4585571	0.07
339.0027466	0.10
341.1701050	0.65
345.0681763	1.20
347.3981934	0.20
349.1101685	0.90
351.3497314	0.11
353.2293701	0.80
357.0125122	0.09
359.1524048	0.19
359.9923096	0.04
365.0751953	1.88
367.0807495	17.19
369.1604004	0.22
375.1618652	0.32
377.2344360	0.33
379.2437744	0.35
383.0480957	2.10
385.0453491	21.11
385.6766357	0.09
388.8325806	0.13
390.3019409	0.08
391.1763916	0.60
393.3414917	0.21
395.3137817	0.12
397.1748047	0.37
401.1354370	25.20
403.0540161	100.00
403.9334106	0.67
407.4038696	0.39
409.1703491	1.86
411.3041992	0.11
413.2242432	0.68
415.1395264	1.53
417.4344482	0.20
418.9133911	33.49
419.5938721	0.24
420.6260376	0.16
421.4506226	0.11
422.3197632	0.13
425.1077881	0.97
427.1377563	3.71
433.1862793	9.95
435.3562622	0.04
441.4824219	0.27
443.0845947	7.18
445.0107422	4.67
445.6797485	0.09
450.8649292	0.41
451.4734497	0.12
457.3111572	0.10
460.1809692	0.08
462.8674316	0.18
467.1556396	0.80
468.6654053	0.19
469.3255615	0.20
475.0201416	0.59
479.1896362	0.80
481.0349731	1.57
485.4045410	0.11
486.1510620	0.16
487.2633057	1.03
493.1539307	1.41
496.9949341	0.05
501.2470703	0.25
503.0761108	1.01
504.1782837	0.12
511.2322998	8.47
516.8196411	0.18
519.0720825	0.81
519.6967163	0.08
521.2343140	0.50
529.0311890	15.63
529.6846313	0.34
532.8145142	0.19
535.1795654	0.46
546.9373169	16.31
547.6527100	0.35
548.2683716	0.07
549.8062744	0.03
551.1232910	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	252.0862
Annotation	N-Carboxyacetyl-D-phenylalanine
Peak:m/z	Relative Intensity
100.2970734	0.02
122.9557648	0.10
130.0955963	0.12
147.8732605	0.12
150.9446564	0.05
165.8184967	0.42
166.9623566	0.02
172.3178406	0.08
190.6970673	0.04
192.1140900	0.03
198.5141296	0.02
206.0079651	94.99
206.9811859	0.02
215.9795685	0.03
220.3079987	0.03
224.3859711	0.05
233.9358673	100.00
235.0925293	0.04
243.6464233	0.09
252.0239105	0.08
253.3666229	0.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	843.2188
Annotation	Unknow
Peak:m/z	Relative Intensity
261.3381348	0.02
302.1166687	0.24
305.1708984	1.11
317.1288757	0.69
330.9158325	0.27
345.1859131	0.59
347.0254517	0.06
358.2166443	0.04
359.0398560	0.07
360.1442871	1.84
361.1611328	0.07
375.1614380	8.23
377.2664185	0.03
406.9118042	0.09
417.1138306	0.05
431.2986450	0.05
507.0207520	0.27
537.1295776	44.18
537.7578735	0.07
565.2023315	0.10
579.1757202	21.27
579.8374634	0.05
619.2701416	8.13
621.2424927	4.41
645.2792358	0.26
651.4286499	0.10
663.2667236	1.45
677.2662964	0.65
681.1763306	100.00
687.3605957	0.09
699.4046021	0.12
707.1444702	0.07
717.3075562	0.06
723.2404175	16.07
735.1973267	0.69
740.7467041	0.20
741.8135376	0.08
753.1444092	8.83
753.8361206	0.02
765.2217407	0.41
780.7446289	0.07
783.1734009	45.08
806.5659790	0.26
813.3811646	0.03
825.0947266	1.79
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.1
Annotation	Mollugoside
Peak:m/z	Relative Intensity
123.0808258	0.37
130.6184082	0.15
152.1130066	0.31
152.9178619	1.53
156.7810669	1.03
167.0280762	14.33
168.0688782	0.16
169.1681061	0.12
171.2828064	0.08
175.3018799	0.06
185.0593262	0.11
188.8200378	0.11
191.2420349	0.57
192.7419128	0.24
207.1104279	0.58
209.0432434	2.80
223.1284637	0.48
225.9601898	0.64
227.1011047	48.36
231.0484924	5.18
241.1236877	9.32
249.0576477	65.35
255.0390015	6.72
267.1337585	43.98
269.1300659	0.98
295.0614014	0.07
299.2515259	0.09
309.1514893	2.31
321.2515259	0.31
325.0578003	0.14
339.2841492	0.37
341.1136169	1.28
349.2564392	0.12
355.2225342	5.03
357.1704102	9.58
367.1477966	0.08
373.2005310	1.81
381.2112427	0.36
382.1502991	0.10
385.2008972	47.56
399.1925964	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	390.1
Annotation	Unknow
Peak:m/z	Relative Intensity
114.9145355	0.24
116.0025635	0.58
117.0565796	0.11
118.0181274	0.34
119.6103897	0.97
128.0191650	0.06
132.0374451	1.32
133.1331024	2.06
134.0516357	2.82
134.8782043	0.21
136.0142822	0.34
137.1344452	0.15
137.9857330	0.56
142.8878174	0.34
147.9062958	0.32
149.0193939	11.70
150.1728363	0.42
150.9599915	0.26
152.9882660	0.42
156.0865936	0.08
157.0395203	0.31
161.9686584	11.05
162.9982605	11.01
164.0709229	24.79
165.0877991	1.04
166.0167847	0.71
167.0741425	0.42
168.9274902	0.24
170.8900909	0.17
173.0084839	0.54
177.1911621	0.48
178.8762207	0.09
181.0309753	0.19
182.0986938	0.30
187.2422791	0.38
188.0637054	0.30
189.2552185	0.20
190.0546722	0.41
191.0836792	0.37
192.2126160	0.09
193.9976044	100.00
195.0251160	4.11
196.1015930	4.94
197.2984619	0.09
198.9636536	0.09
202.0505371	1.00
207.0292664	0.06
208.8604126	0.20
209.8575897	0.25
211.0734863	1.25
216.0252991	1.62
218.0324097	0.35
220.0975800	0.10
221.0034790	0.35
223.2170105	0.18
235.3350220	0.18
237.0688477	0.56
242.0116882	0.21
245.2752991	0.11
247.0223083	0.18
253.0636292	1.23
255.0828857	0.38
257.2001038	0.25
266.9020386	0.07
268.2035522	0.78
269.2369690	0.37
270.1878662	0.07
273.2423706	0.82
274.0995483	0.15
276.3312378	0.14
278.2999573	0.26
279.0612488	0.40
282.3143311	0.10
283.1910400	1.10
285.2525635	0.19
285.9738464	0.35
288.5437622	1.23
289.1797485	0.33
294.4458313	0.07
296.2468872	1.60
297.0527344	1.22
298.0822449	66.28
299.2111511	1.66
300.0123291	1.53
300.8574829	0.87
302.1781921	0.36
303.1756592	0.64
313.2380676	0.84
314.3273926	0.46
322.1523743	0.25
323.3171387	0.40
324.2873840	0.41
325.9495239	19.86
326.9209900	0.74
330.0724182	2.92
332.1668091	0.57
339.1488953	0.36
341.2086182	37.82
341.8561401	0.10
345.2349243	0.25
346.3159180	0.47
348.4077148	0.17
355.1183777	1.57
356.2843628	0.22
358.0617981	70.18
359.0460205	7.21
360.2630615	0.75
361.2523193	0.41
362.2650452	0.07
372.3119507	2.42
373.0262146	0.46
374.3901062	0.30
376.0546570	0.77
380.7661438	0.57
399.3090210	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	678.8096
Annotation	Unknow
Peak:m/z	Relative Intensity
203.2780304	0.04
244.9804077	0.03
261.0214539	0.09
273.0473022	0.16
289.0315857	1.40
305.0553589	8.65
345.1614075	0.02
360.9373779	0.06
403.0753174	0.27
418.9532471	12.08
434.8383789	18.91
533.0520020	0.07
545.0766602	0.06
547.1313477	0.02
548.8582764	34.93
561.8233032	0.02
564.7872925	100.00
565.4329224	0.35
587.9164429	0.03
604.9757690	0.15
608.0861206	0.02
632.4413452	0.12
633.2696533	0.01
636.6816406	0.11
660.8558960	0.16
678.4833984	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	329.1737
Annotation	Gelomulide D
Peak:m/z	Relative Intensity
94.9789581	0.66
106.9650421	0.01
109.0574188	0.06
110.9241943	0.01
137.0332947	6.19
137.6782990	0.01
149.1541748	0.01
160.0058899	0.01
161.0357666	0.01
175.4344635	0.02
191.3890228	0.01
193.0022583	100.00
193.9551697	0.02
205.0857849	0.65
209.1320190	0.01
212.9562378	0.04
217.1826172	0.04
219.1048889	0.43
231.2010803	0.47
233.0704651	0.82
245.0734558	1.29
246.9586487	0.02
249.3314819	0.02
259.0027161	0.07
261.2143860	0.10
273.1621094	0.07
275.3862305	0.01
287.1057739	0.03
297.2014160	0.01
301.2986755	0.01
311.3425598	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	511.2007
Annotation	PHYSALIN B
Peak:m/z	Relative Intensity
200.7837219	0.94
213.1543579	0.47
230.7588196	2.22
253.4243774	0.13
286.8405151	0.47
289.0179443	0.39
305.1122437	1.81
330.8041992	0.65
337.2196045	1.39
347.3061523	1.37
348.5546265	3.54
349.3681641	2.75
356.8036499	0.86
367.4362793	0.19
375.0023804	4.83
377.2064819	0.11
380.1210327	0.27
384.1263428	0.19
391.1445923	9.33
392.9715576	16.94
396.1237793	1.26
402.0864258	0.78
405.3162231	0.34
409.0269775	1.02
419.1761475	1.79
433.244751	13.93
437.9154053	0.49
445.5313721	1.19
449.142395	0.74
452.3275757	0.56
463.1806641	4.28
465.3892212	1.27
467.2369995	0.54
473.9053345	0.32
475.2407837	7.94
481.0691528	0.20
483.4390259	1.03
492.5482788	7.28
493.197876	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	691.1962
Annotation	Scandenolide
Peak:m/z	Relative Intensity
223.1853638	0.32
239.0099792	0.77
247.2034607	0.07
254.0693359	0.97
265.1246338	0.51
278.0323792	0.11
299.2456360	0.23
312.2092896	0.18
326.0802612	0.10
334.7878418	0.39
339.0733643	0.23
357.1916504	100.00
373.3007812	0.24
375.5562744	0.36
377.4901733	0.06
386.4994507	0.57
418.4136963	0.60
425.6358032	0.22
438.4868774	0.19
441.3549194	0.10
457.6942139	0.16
464.8865356	0.47
466.1683350	0.06
468.3319092	0.28
479.3717041	0.37
494.5297241	0.69
508.1477661	0.17
523.1589355	0.37
528.7913818	0.45
534.0361938	0.67
552.4860840	0.29
557.1751709	0.13
569.2069092	0.93
585.5112915	0.06
588.0582886	0.77
589.3701782	0.15
595.4554443	0.26
602.0741577	0.36
612.1179810	0.68
624.0155029	0.40
631.7865601	0.21
644.2932739	0.18
654.3494263	0.14
655.2371826	0.08
672.5250244	0.54
673.4658813	3.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	565.1926
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
173.0088348	0.06
207.0478058	1.13
283.3302002	0.07
293.3223877	0.15
294.0363159	0.04
297.4345093	0.24
309.2063599	0.68
310.3457642	0.06
312.1915894	0.24
324.1381226	2.02
325.1851196	0.04
327.2227783	59.06
339.1275024	100.00
339.8016357	0.31
352.5416260	0.24
356.0642700	3.46
356.8455811	14.18
357.6585693	0.45
385.3093262	0.22
397.2044067	0.18
398.9283447	0.06
413.2949829	0.28
414.2620850	0.47
415.1786499	0.17
419.3048706	0.05
421.2166748	0.35
422.9724121	0.06
431.4387207	0.21
461.3391113	0.29
503.3950195	0.07
505.3120117	1.08
517.2575073	0.10
518.6478882	3.66
523.4136963	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	543.1301
Annotation	Galactotriose
Peak:m/z	Relative Intensity
200.2874756	0.66
201.1931152	0.07
218.1002960	0.06
218.8796692	0.69
281.6661987	0.04
288.8981934	0.04
290.4194946	0.96
291.0380859	0.06
363.1134033	18.72
364.2166748	0.18
370.2645874	0.48
371.5993042	0.68
372.2340698	0.24
381.1072998	100.00
382.2988892	0.95
453.0134888	0.19
525.1889038	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	659.2192
Annotation	Butrin
Peak:m/z	Relative Intensity
192.0081635	0.13
194.0943756	2.04
195.0443115	2.51
209.1585083	27.47
210.1419983	21.24
305.2125854	1.22
306.2274780	0.49
371.7944336	1.98
399.3427124	0.18
400.2677002	0.09
413.9600220	0.20
436.2636108	0.08
442.3605347	0.16
449.4013672	0.46
452.4753418	0.41
453.6414185	0.38
498.5826416	0.23
515.3284302	32.67
516.2035522	100.00
516.8397827	0.29
535.7555542	0.07
557.4945679	3.79
558.2476196	10.32
596.7495728	0.10
598.1401367	2.13
600.3166504	0.12
614.3171387	0.19
641.7839966	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	595.1371
Annotation	Claussequinone-(4->5')-vestitol
Peak:m/z	Relative Intensity
171.2543335	0.07
173.2022095	0.22
175.0197296	0.19
177.1447144	0.20
189.2604675	0.09
203.0368652	0.34
221.1538849	0.05
233.2876129	0.07
236.9491577	0.05
243.2248230	0.20
247.4598083	0.33
251.9035950	0.18
259.0025024	0.10
261.4642944	0.04
263.3730164	0.04
272.8892212	0.14
287.2293701	2.08
301.2209473	0.11
303.3534546	0.06
309.0568542	0.24
312.7830811	0.21
317.6085815	0.14
323.6820068	0.08
325.0916138	1.13
335.3568115	0.16
337.2842407	0.46
338.4799805	0.13
343.3068848	0.53
345.1593018	0.35
347.1005859	0.56
353.0233765	0.16
355.0819092	0.48
371.3646851	0.22
380.0026855	0.14
381.3341064	0.69
387.4154663	0.09
393.1538086	0.21
397.2056885	0.52
409.0820923	0.26
415.1160889	0.44
433.0034180	1.22
438.9085693	0.60
445.1937866	0.70
449.1373291	28.49
457.3082886	12.05
459.0471802	1.50
463.1771240	2.42
475.1904907	4.21
476.4378662	0.20
477.5929565	0.08
481.3627930	1.63
482.2484131	0.16
499.3057861	2.68
510.4297485	1.61
511.2199097	3.61
517.5816040	0.59
520.9108276	0.10
523.2389526	1.34
526.1410522	100.00
527.2152100	53.99
529.0926514	4.36
536.6085815	0.12
541.1740723	3.12
549.0686646	0.09
551.6036987	0.12
558.0612183	0.07
559.3035278	5.77
564.8084717	0.04
577.1565552	36.15
577.9439087	0.28
594.9005127	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	677.2769
Annotation	11-epi-Azadirachtin D
Peak:m/z	Relative Intensity
191.3109894	0.09
193.2418365	0.16
195.1127472	0.25
197.1343536	1.38
197.9921570	0.13
199.0815887	0.46
201.0440369	0.47
202.8944244	0.25
203.6285095	0.39
207.3291168	0.60
209.2231750	0.47
211.3383789	0.13
213.0901489	1.08
215.1959534	3.94
217.0467224	0.78
219.1657410	0.50
220.4998474	0.21
221.2128906	0.65
222.0494537	0.18
223.0047302	0.19
225.2406921	2.78
226.9846802	0.85
229.1563110	0.64
231.1478271	7.80
233.1330261	0.54
234.2970886	0.16
235.1512451	0.41
237.1985779	1.03
239.1409912	0.87
241.2413330	4.63
243.0706635	0.88
244.0323334	0.41
244.9102936	0.57
245.5150757	0.29
246.6587830	0.90
247.4167175	0.21
249.1630859	1.29
250.9739380	1.63
253.1843414	1.78
255.1994629	0.93
257.1070862	0.25
259.3361206	0.33
261.1340332	2.26
263.2723389	0.50
265.1875610	1.16
267.0476074	0.49
269.1612854	3.94
271.1177673	0.72
273.3676147	0.70
275.1348877	0.42
277.2508240	0.88
279.1593018	1.94
281.2650146	1.32
283.2352295	1.86
284.8713379	0.61
285.6364746	0.14
287.3375854	1.82
289.2249756	3.97
290.1578979	0.42
291.0912781	1.23
293.1655273	2.20
294.0856323	0.17
295.1516113	2.61
297.1843262	1.92
299.0996094	1.45
301.2686157	1.51
303.1234131	0.92
303.8275757	0.10
305.2207642	3.16
307.1664124	2.37
309.1274109	3.02
310.4426270	0.51
311.1416626	0.89
313.2564087	2.03
315.3092651	1.71
317.1613464	2.35
319.2178345	1.30
321.1512451	2.51
323.1367798	2.03
324.0850220	0.97
325.1974487	1.43
327.1994629	1.49
329.3305054	2.57
330.3262939	0.17
331.2160339	3.80
333.2578125	5.53
335.1829834	1.76
337.2750549	1.09
339.1988831	2.32
341.3040161	27.05
345.2207642	0.57
346.1317139	0.53
347.2189331	1.87
349.2141113	4.97
351.2412720	12.00
353.1441040	2.08
355.2434082	2.23
357.2261353	0.49
359.2404785	4.39
360.3078003	0.15
361.2973022	2.00
363.1616211	3.40
365.2324829	2.57
367.2473755	9.41
369.3032837	74.57
371.2321777	0.97
372.1644287	0.19
373.3552246	4.06
375.3373413	11.91
377.2196045	6.13
379.2261963	1.14
380.4027710	0.42
381.2689819	0.83
383.2777100	1.07
385.0972900	2.71
387.2421875	0.58
388.6618652	0.32
389.3669434	0.86
391.2822876	8.18
393.3108521	33.13
395.2181396	10.96
396.7559814	1.19
397.4450684	0.36
399.4277954	1.17
401.2741699	5.07
403.2083130	0.64
405.2575073	2.13
407.2075806	0.93
409.2514648	8.59
411.2695312	68.00
413.2033081	8.34
415.3634033	0.10
417.3513794	0.43
419.2559814	22.44
421.1953125	0.16
425.0644531	0.08
427.3372803	3.03
429.2359619	23.76
431.2373047	1.73
433.2039795	1.57
435.1763306	0.69
437.2627563	21.55
439.1569214	1.26
441.1978149	0.81
445.4190063	0.69
447.3534546	1.22
449.2891846	0.46
451.1550903	1.09
453.3029785	1.60
454.5457153	1.47
455.2359619	17.01
457.4028931	0.32
459.2366943	2.74
460.4780884	0.16
461.3839722	0.23
463.3034668	0.10
464.5250244	0.69
465.2952881	1.79
468.2602539	0.49
469.3339233	0.97
471.2713623	10.74
473.2262573	8.80
475.2079468	0.95
477.2738647	8.49
478.0881958	0.07
479.3059082	0.47
481.4699707	1.32
483.3936157	0.80
485.4470215	0.80
486.3306274	0.76
487.2011719	1.06
489.3197632	1.25
491.3786011	1.02
493.3258057	1.53
495.0516968	2.88
496.5454712	1.28
497.4605713	1.94
499.2061157	0.90
501.2537231	5.63
503.2235718	0.73
505.4468994	0.16
506.5865479	0.13
507.2674561	1.28
509.2780762	0.76
511.3675537	1.01
513.2689819	1.11
515.0280762	4.63
515.8298950	0.36
517.3977051	0.25
519.2357788	7.44
520.6967163	0.18
521.3851318	1.70
523.1228638	0.56
524.1361084	0.70
525.2625732	0.67
526.9924927	1.99
527.6143188	0.15
531.4655151	1.60
533.3423462	4.49
535.1779175	3.08
537.3264771	13.60
539.2664185	0.82
541.1455078	0.48
542.2216187	0.44
543.2625122	0.79
545.3143921	2.42
548.0631104	0.18
549.5204468	0.09
553.2835083	3.75
555.2810669	37.78
557.2780762	1.38
559.2174683	0.82
561.0409546	0.19
563.3632202	9.29
569.2347412	0.49
571.2667236	9.63
573.2658081	19.78
577.9437866	0.77
579.4541626	0.84
581.2905884	15.79
583.5607300	0.07
584.6661987	0.61
585.4414062	0.20
587.6518555	0.30
589.0134888	0.44
597.3539429	2.91
599.3140869	35.69
600.0766602	0.10
602.3858643	3.24
603.5471802	0.61
605.3577271	0.46
609.2879639	0.20
610.2535400	0.51
613.1671753	8.64
615.1192627	4.45
616.6478271	1.43
617.3366089	35.99
623.2340088	1.82
631.2889404	15.30
633.2160034	1.16
634.9484863	0.21
640.5545654	0.51
641.2539673	5.46
645.2588501	0.87
649.3119507	0.42
659.2122192	100.00
659.8477173	1.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	153.1269
Annotation	Isocitral
Peak:m/z	Relative Intensity
56.9337578	3.46
58.9742432	5.50
66.9643402	0.22
68.9254456	2.39
70.8543549	100.00
72.9465256	0.20
78.7892456	0.10
80.9892807	31.09
82.8894501	7.45
84.8838654	0.06
92.8983765	24.18
94.9381104	51.20
96.9664612	18.56
97.7435608	0.06
107.0186768	20.94
109.0424652	23.92
110.9296112	5.94
123.1198425	0.80
125.0601044	2.76
132.3183899	0.11
134.9786377	83.90
137.4487457	0.50
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	779.2448
Annotation	Unknow
Peak:m/z	Relative Intensity
234.9762268	0.06
245.0752563	0.35
247.1732025	0.17
250.9237061	0.36
258.9679260	0.05
264.1179810	0.24
265.0988770	1.36
283.1412048	3.60
289.1263428	0.39
305.0455322	1.16
310.7551270	0.16
317.2753296	0.12
321.1344604	1.89
322.4162598	0.09
329.3521118	0.12
337.1166382	0.40
339.0059814	0.04
343.0613403	0.12
349.6145935	0.21
359.4332275	0.27
361.3118286	0.22
371.5159912	0.07
377.1397705	0.24
379.2310791	6.27
381.2296143	0.50
382.2014771	0.14
383.3523560	0.24
395.0565186	0.11
397.2742310	1.03
401.2035522	0.16
409.2963867	0.17
415.3086548	1.23
431.2253418	0.06
435.4107056	0.24
439.3322754	0.08
442.6898193	0.16
449.2679443	0.55
453.4194946	0.56
455.2334595	0.20
457.1580811	0.09
463.0498047	0.28
467.0449219	0.06
473.2973633	0.26
481.2886963	0.45
485.3303833	0.12
491.2887573	0.06
492.1281128	0.09
493.4450684	0.54
496.0758057	0.13
507.1015015	0.21
509.0823975	0.08
511.1945190	1.72
523.3804321	0.12
525.2150879	0.20
529.3953247	0.55
535.5902710	0.04
543.4024658	0.22
561.4906616	0.78
567.1300659	0.83
568.1543579	0.30
569.3667603	0.59
579.4357910	0.22
585.4785767	0.56
586.2374268	0.13
587.2265625	1.18
597.4685669	0.09
603.1852417	0.11
605.1911011	0.04
629.0018311	0.02
629.7845459	0.10
643.2993774	3.62
645.4916382	1.35
646.4544067	1.96
647.4017334	3.45
661.2892456	6.41
669.3613892	0.38
675.4817505	0.63
687.4110718	2.96
688.2789917	0.20
689.2035522	0.08
693.3771362	1.10
699.3533936	0.35
700.6449585	2.10
701.3902588	3.29
703.2587891	0.16
705.3290405	1.75
717.2822876	2.06
718.6425781	9.07
719.2825928	100.00
720.4132080	1.11
729.2750244	0.09
731.3012085	0.07
735.5191040	0.06
737.3270264	49.08
738.2907104	0.11
747.2958984	8.64
748.3540649	0.45
761.1766357	1.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1822
Annotation	Butrin
Peak:m/z	Relative Intensity
172.9256439	0.04
174.0979462	0.02
177.0451813	0.58
181.7651215	0.02
185.0962677	0.06
187.3863831	0.02
193.2639465	0.08
199.0684204	0.16
199.9652863	0.10
200.8804932	0.05
215.1017609	0.13
239.3096619	0.17
241.0724640	0.03
242.1251678	0.10
242.9078064	0.01
250.9953003	0.16
255.1226959	0.05
257.0458679	0.08
258.2055054	0.11
259.1115723	0.02
267.9832153	0.03
275.1763916	0.05
286.1004639	0.69
287.0766296	0.03
299.3336487	0.05
301.0943604	100.00
301.9434814	0.04
315.4694214	0.03
325.1517029	0.81
343.1132812	0.76
354.7817993	0.02
367.1509399	0.03
398.9349976	0.04
441.1101074	0.03
459.2950439	0.56
463.0794678	0.02
463.7905884	0.09
465.3952026	0.34
489.2519531	0.06
507.2182617	0.06
519.3888550	0.08
565.3865356	0.05
591.4024658	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	331.1744
Annotation	Epijasminoside A
Peak:m/z	Relative Intensity
98.9436798	0.27
102.1840363	0.13
107.0773468	0.29
109.0713196	1.07
111.0922165	0.03
113.1003723	0.11
121.0722046	0.51
123.0630646	1.19
125.1005859	0.16
126.8929367	0.28
131.0585632	0.07
132.9473572	0.15
137.1204224	0.16
138.2011108	0.46
139.1179352	0.99
140.8866577	0.03
144.3581848	0.12
151.0293579	0.90
153.0885620	0.04
154.5857391	0.07
159.1524963	0.11
163.0453186	0.24
169.0502167	100.00
172.2593384	0.44
173.2376556	0.09
175.0741272	0.11
176.7769165	0.07
179.2972717	0.38
180.9111633	0.19
182.8841858	0.22
185.3101196	0.05
186.9498138	0.10
189.1034698	0.12
191.1407471	0.15
191.8685608	0.15
195.2039795	0.11
196.4527893	0.31
198.7897034	0.11
201.1355133	0.20
202.2088013	0.08
204.8244934	0.07
207.2636871	0.14
215.1996155	0.05
217.2666931	0.05
224.0442505	0.06
226.9831543	0.06
228.9666443	0.86
233.1026306	0.19
235.0613098	0.04
236.9658508	0.15
239.2767029	0.26
241.9397888	0.05
243.0347900	0.29
246.1699219	0.14
247.0278015	0.13
248.1535034	0.20
252.9189148	0.97
255.0376587	1.08
257.1943054	0.29
259.9680786	0.29
261.0451965	0.52
262.3885803	0.04
266.9981079	0.17
269.8342285	0.06
271.1404419	0.53
273.1385498	0.75
275.0374756	0.37
277.0575562	0.14
283.2560120	0.10
284.1662903	0.02
285.2235718	0.17
287.0752563	0.40
289.1560364	0.08
290.0211792	0.26
295.2803955	0.93
298.9449463	0.24
301.0651245	0.48
303.1693420	10.09
304.1252136	3.22
307.9526978	0.28
312.4877319	0.57
313.1884766	5.78
313.7890625	0.19
315.2057190	0.08
316.3551941	1.22
317.1714172	0.45
319.3200378	0.21
322.2379761	0.28
324.9013062	0.04
330.8876343	0.08
331.4963074	0.09
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1556
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
182.9930878	0.32
197.0843811	0.15
200.959259	0.98
227.1823425	0.33
251.0522156	0.31
269.0429077	100.00
285.166687	0.51
293.3405151	0.31
311.0709839	0.15
312.3106689	0.60
327.0378418	0.40
341.2998047	0.52
377.2919312	0.91
385.5311279	0.09
389.2492676	0.77
405.446167	0.13
413.2925415	0.74
439.3268433	0.15
447.0734253	1.04
457.0806885	0.09
473.3348999	1.67
475.2186279	0.15
481.390564	0.18
503.2342529	0.88
517.4192505	4.86
527.0436401	0.46
531.1707764	0.61
533.0274048	1.21
534.4113159	0.27
535.335144	0.27
559.3900146	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	497.2112
Annotation	Unknow
Peak:m/z	Relative Intensity
141.9730225	0.60
143.8439026	2.53
145.0726471	2.21
146.0024414	1.57
148.0585327	9.83
149.9782257	0.05
152.0201263	0.18
154.1845245	0.88
154.9927216	0.49
155.9897156	2.56
156.9387817	0.57
157.9151459	0.77
160.0086975	74.33
161.0444946	0.44
162.2436981	0.82
163.1237488	0.58
166.9941711	1.25
168.0544128	0.93
169.1138000	0.87
170.0138245	0.99
171.2174835	1.16
171.9491730	10.37
173.2631836	0.08
174.0014954	0.67
175.3790283	0.51
178.0229187	0.96
180.3033142	0.17
182.0928040	1.15
182.9830322	0.10
184.0693054	10.39
186.1010132	4.05
187.1437531	0.70
188.0709839	1.11
190.0703735	21.73
191.0331421	46.01
191.8122559	0.38
196.0639343	0.27
197.2730103	0.07
198.1759186	1.21
198.9593811	0.33
200.0166321	4.84
200.9786377	0.97
202.1342773	11.44
203.0215454	0.56
204.0228271	0.20
204.9922485	0.45
206.0644836	0.16
207.2933655	0.30
208.9249268	0.25
210.2655029	1.85
211.1701660	0.17
212.1040039	0.64
214.0426178	17.85
215.0966492	1.11
216.1086731	0.44
220.1078186	0.34
222.1601868	0.30
223.8842163	0.20
224.6197968	0.08
226.1256409	8.43
227.1192169	0.19
228.1591492	1.00
229.2875366	0.24
230.3727570	0.25
232.0833282	0.20
232.8213806	1.13
235.1002502	0.10
238.0728607	9.35
238.9518738	0.37
240.0499268	2.47
242.1471863	4.00
244.0832672	1.20
246.9205017	2.12
250.1399078	5.57
252.0543671	0.36
253.2213440	0.57
256.0636597	18.04
257.4193420	0.35
258.4831543	0.25
261.2436523	0.16
263.0932007	0.58
265.2621460	0.33
266.0391235	0.39
268.1569214	7.58
269.1310425	0.77
270.1683350	1.33
270.9317017	0.23
272.0582275	0.75
274.1996460	6.48
275.2308350	0.16
277.2802734	0.24
278.2220154	0.28
281.1464233	1.24
284.2385559	2.84
286.1778259	5.52
288.2571411	0.13
288.9396667	0.81
292.1811218	1.59
293.1193542	0.18
297.8035583	0.46
299.3606262	0.45
300.4590149	0.46
302.3755493	0.76
304.2666626	1.70
307.0282288	0.35
310.2850342	2.06
316.0029907	0.50
317.0202637	0.78
318.1481323	0.09
319.3131714	0.23
320.2608337	0.68
321.0739441	0.19
322.1013184	5.96
326.2399902	0.26
328.2534180	0.24
329.1258240	0.12
332.1642151	0.95
334.0860596	0.92
335.0753784	1.69
336.5639038	0.17
338.1661377	0.52
341.2280273	0.87
345.2530823	0.17
348.4947205	0.23
350.1926270	2.14
353.3045044	15.64
356.1218262	1.02
358.2127075	0.30
359.2922363	0.13
360.1603088	0.17
362.2891235	1.91
363.3624268	0.20
364.1666260	0.49
365.3460693	0.18
366.9127197	0.16
368.1159058	0.64
371.1611328	0.31
374.1833496	0.76
377.1331787	0.99
379.0599365	0.12
382.3461609	0.49
384.8493347	0.08
386.2914124	2.18
388.1387024	0.45
392.1302185	1.49
394.1436462	0.94
395.7024841	1.36
399.1525574	0.20
400.2649231	1.86
401.3470154	0.26
404.2127380	3.23
405.3574219	0.28
406.0748291	0.11
407.3057556	0.39
412.2386475	4.38
414.7235718	0.07
417.4568176	2.71
418.2705994	14.74
420.4226074	0.05
422.4829712	0.31
430.1311646	4.56
431.2729187	0.30
435.2441406	100.00
436.1639404	23.54
437.1669617	6.09
443.0420532	0.89
448.2961121	10.77
451.0984802	0.15
454.2370300	13.89
461.2935791	3.83
466.2524719	6.75
467.2189331	0.37
468.3529968	1.01
479.1993103	14.87
480.1494751	1.36
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	570.1802
Annotation	Unknow
Peak:m/z	Relative Intensity
170.8649750	0.32
191.0606232	0.07
195.0525665	0.10
200.9090118	0.14
203.0597992	4.69
206.9437103	0.18
213.1761475	0.14
227.2569580	0.09
238.1293030	0.38
241.1169739	0.65
243.1413422	0.17
246.9408417	0.11
250.0855865	0.42
269.1225586	3.51
283.1362305	0.19
286.4122925	1.36
287.1382446	11.91
292.1618652	0.21
297.0552368	0.04
302.5657349	0.13
304.7962646	22.24
305.4229736	0.11
315.1021729	0.31
335.4608154	0.20
351.2988281	0.12
355.0722046	0.08
362.1199341	0.09
364.3065186	0.09
372.9958496	0.44
377.2812500	0.28
390.1171265	0.44
394.1989136	0.05
395.3044434	0.14
404.4760742	0.33
405.9511719	0.08
407.1086426	0.88
408.2763062	0.77
411.4547729	0.07
415.1770020	0.44
417.1918945	0.08
432.5234985	0.24
436.3277588	0.61
437.1398926	0.19
466.3450317	0.86
472.9881592	4.72
480.5725098	0.12
491.2212524	0.23
492.1744995	0.10
493.2604370	0.17
499.2048950	5.08
508.2672729	0.22
509.3637695	0.17
510.5330200	0.25
516.8784790	71.08
517.6726685	0.07
524.0317383	0.24
525.9855347	0.64
532.8775024	0.51
534.2907104	9.96
534.9534302	100.00
535.5968628	0.63
536.3325195	0.65
539.2871704	0.10
551.3472290	3.08
552.1754761	7.12
552.8798218	56.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	808.7674
Annotation	Unknow
Peak:m/z	Relative Intensity
260.9674377	0.01
272.9203491	0.03
289.0273743	0.38
305.0139771	2.47
336.9146423	0.04
403.1261597	0.17
419.0023804	1.14
434.9231567	5.77
474.8289795	0.01
548.8277588	8.69
550.1061401	0.03
564.8187256	17.36
565.4699097	0.05
662.6544189	0.40
663.7525024	0.20
676.0523682	0.03
678.8276367	27.70
693.1240234	0.27
694.7661743	100.00
706.8705444	0.07
720.7330933	0.03
724.9305420	0.02
734.7468872	0.13
761.7758179	0.04
762.6489868	0.08
777.5411377	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	356.1844
Annotation	Falciformin
Peak:m/z	Relative Intensity
137.0313263	31.36
144.9964600	0.91
203.0952148	64.26
219.8888855	2.14
229.0975647	1.51
243.3229370	0.80
258.1423950	0.60
287.1133118	2.72
288.2569580	0.27
296.8424683	0.78
307.1445007	0.54
314.8189392	1.31
328.2209473	0.41
338.9907227	100.00
339.6889343	1.66
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	538.1936
Annotation	Unknow
Peak:m/z	Relative Intensity
159.9555817	10.70
161.7036591	0.15
163.0488281	0.05
165.0929871	0.57
166.8789520	0.56
169.8934021	0.18
173.9889832	0.08
178.0159912	6.98
178.8189545	0.30
182.9042358	0.46
184.6165314	0.11
187.0093994	0.10
190.9979248	0.20
197.0624390	0.20
203.2356567	0.10
204.0452728	0.05
204.7039337	0.80
206.0811615	0.14
209.2118988	0.18
210.8970337	0.32
216.2402649	0.13
221.2595215	0.29
225.6828613	0.07
233.7872620	0.07
236.9956360	1.38
239.2428589	0.05
254.1617126	13.70
254.9058380	0.17
264.7882690	0.04
272.1223755	100.00
289.1623535	0.09
290.0235596	0.66
291.2927856	0.16
292.1304932	0.17
305.0290527	0.14
307.0640869	0.17
309.2939453	0.13
311.4013062	0.14
317.4159546	0.09
320.1851807	0.06
329.2655640	0.40
332.4519043	0.04
334.5356445	0.11
340.2318726	0.12
341.1921997	0.41
346.3641968	1.64
357.1622925	0.24
357.9563599	0.22
363.2106323	0.20
371.7789307	0.10
376.3869629	0.44
377.1013794	0.06
394.0616455	0.06
394.9418945	0.06
409.7712402	0.22
416.2099609	0.19
419.0996704	0.16
423.2278442	0.48
426.2378540	0.07
431.2491455	0.24
436.2511597	0.11
438.6770630	0.11
449.2335815	0.12
452.1793823	0.30
457.1425171	0.13
461.0000610	0.38
466.1327515	0.11
475.1776733	0.07
479.1893921	0.03
484.1851807	0.15
486.4310303	0.13
489.7733154	0.04
491.4276733	0.24
493.2543335	0.10
494.1841431	0.68
494.9988403	0.22
502.2285767	1.57
503.0836792	0.96
506.9517212	0.10
508.4666138	0.47
509.2468872	0.10
520.2583008	11.71
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	607.17
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
254.8808899	0.03
256.2480164	0.02
284.0781860	29.86
284.7521362	0.11
299.0938721	100.00
313.1703796	0.02
326.2329102	0.02
329.3086548	0.02
341.0031128	0.23
367.2094727	0.02
383.2339478	0.04
445.4950562	0.03
463.1542969	0.02
505.2052612	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	471.2367
Annotation	Subtrifloralactone L
Peak:m/z	Relative Intensity
157.1624451	0.09
161.0973511	2.59
162.1637115	0.47
163.0063782	1.14
166.8021851	0.15
175.0239105	0.87
177.1409607	0.36
185.0935669	0.42
187.2236328	0.33
197.2280426	0.29
199.1212921	1.79
201.1472778	0.92
203.2182922	0.33
205.3210297	0.35
213.0913086	0.18
214.9175873	0.35
216.1026459	0.32
217.0175171	0.93
219.1252289	0.37
225.1383667	0.17
227.0691528	0.21
229.1210632	0.57
233.3464966	0.24
235.1021118	0.84
237.1387634	0.21
241.2743225	0.90
244.6120300	0.12
253.1363831	0.09
256.9352417	0.26
263.1424561	0.76
267.0349426	0.94
269.4899597	0.45
273.2239075	0.47
277.3336487	0.46
279.2221069	0.77
283.2196655	1.26
284.9287720	3.81
289.2588501	0.57
290.0134583	0.14
291.6618652	1.04
293.3292236	1.74
295.2209473	0.84
297.2992249	0.61
299.0324707	0.40
301.1229248	0.21
307.1015015	0.78
311.0942383	1.22
317.1248474	0.34
319.2255554	0.92
321.1068115	0.44
323.2946167	2.65
325.2426758	0.34
327.3018799	0.60
331.0833740	0.61
332.9221191	1.27
335.3210449	0.21
339.2852173	1.04
341.2708740	1.17
343.3247986	0.62
345.1781311	0.57
349.0765076	0.42
351.2232971	1.98
353.1319885	1.87
355.1785278	0.54
357.2312927	1.90
359.1634216	0.93
365.3317261	0.38
367.4204102	1.28
369.2958069	31.70
371.0982666	2.46
372.9085693	0.08
375.5177917	0.59
377.2521057	1.55
381.2807312	0.45
383.2909851	2.37
385.4584656	0.70
387.1157227	0.19
391.3070984	0.91
393.0708923	2.92
395.2841797	0.84
399.3457336	0.35
400.9435730	4.08
404.5723572	0.78
409.2369690	6.64
411.2112122	23.49
412.4953613	1.32
413.1320496	12.45
413.7632446	0.32
425.1288147	0.87
427.3169556	100.00
429.1664734	20.84
431.1627502	0.49
437.3221741	8.42
445.2362366	0.44
452.9806824	0.69
453.8363342	0.69
455.1731262	31.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1562
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
166.9914093	0.08
169.0793152	0.03
173.2979126	0.05
181.2051392	0.01
182.5037231	0.07
183.1164093	0.05
196.0813293	0.11
197.2136688	0.09
201.1026306	0.06
210.0112305	0.03
222.9337311	0.06
223.9061584	0.02
225.0406799	0.19
227.0355225	0.03
269.0485535	100.00
271.0723877	0.14
293.1091309	0.11
294.9588013	0.04
310.9512634	0.26
316.1185913	0.07
340.0689697	0.05
343.0844727	0.05
373.142334	0.16
377.128418	0.04
391.3051758	0.04
413.0560303	0.09
414.2372437	0.10
415.2979736	0.08
427.1541138	0.10
432.6480103	0.17
433.2648315	0.52
451.2018433	0.02
457.1825562	0.08
474.0977783	0.11
475.3247681	0.16
515.1842651	0.02
531.3422241	0.07
533.2619629	0.11
559.0812378	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	318.1326
Annotation	Isosativanone
Peak:m/z	Relative Intensity
150.8814545	7.98
179.2457428	6.84
232.9165039	6.93
233.7821960	3.18
277.3267212	2.17
300.9575500	100.00
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	325.1275
Annotation	Juglanoside A
Peak:m/z	Relative Intensity
92.9815674	0.31
107.0976486	0.13
120.9244919	0.17
132.9933472	0.38
137.0426331	0.19
144.6223755	0.28
146.9421692	0.06
151.2204132	0.12
157.1060791	0.15
161.1109467	0.16
162.8191833	0.55
173.1484070	0.07
175.2529907	0.32
179.0314178	0.40
183.9705048	0.46
184.9433746	0.42
187.3259583	0.06
189.2163239	0.16
201.3106842	0.19
203.0230103	1.18
204.9983215	1.17
212.1104431	2.59
213.1612244	0.53
218.2813110	0.35
221.0194397	0.46
223.0366211	1.64
227.1575317	0.22
232.9848938	0.81
239.5494080	0.41
247.1049194	2.38
250.9326172	0.13
268.1264343	31.02
269.1734619	23.30
271.3849182	0.14
276.3842773	0.12
278.8707275	0.60
280.1876831	0.08
283.0134888	0.09
288.9836731	100.00
293.2124634	1.03
298.1584473	0.10
299.3108521	0.18
301.4966125	0.54
304.3607788	0.33
305.8092957	2.87
306.9020081	94.14
310.2915344	0.18
315.9844971	0.93
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1562
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
183.1379242	0.25
195.8924103	0.24
201.2249451	0.30
225.0544281	0.28
248.4815216	0.06
262.1637878	0.21
269.0386963	100.00
269.69104	0.40
283.2752991	0.08
293.0323486	0.17
295.2035522	0.30
311.1291809	0.60
361.2325439	0.30
373.1779785	0.13
376.0192261	0.14
383.0581665	0.74
394.8406372	0.15
413.2119751	0.98
445.2848511	0.06
459.2704468	0.09
471.5636597	0.30
473.460022	0.46
481.0113525	0.50
487.447876	0.13
492.369812	0.12
493.5328369	0.65
497.5776978	0.17
508.0739136	0.18
514.3632202	0.08
517.3510132	1.27
530.3863525	0.12
533.171875	1.41
540.8720093	0.20
544.5233765	0.26
545.4608765	0.20
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	451.9869
Annotation	Unknow
Peak:m/z	Relative Intensity
127.7704163	0.15
146.1481934	0.08
148.1745453	0.25
148.9281616	0.17
168.1656494	0.12
175.2169800	0.09
259.1449585	0.21
269.0714111	0.19
270.2333374	0.19
272.1740112	0.16
277.8012085	0.53
278.9556274	0.07
279.9866333	0.10
288.3126221	0.32
288.9299927	0.31
290.2854309	1.27
304.9996948	0.30
306.0352173	0.72
313.0601501	0.16
317.8492737	0.06
319.9088135	0.27
323.0568237	0.11
330.8989258	0.37
332.0095520	0.12
336.1410217	0.14
343.9457092	0.25
346.2163086	0.50
348.0386353	0.37
361.9474487	1.51
377.7312317	0.51
389.9601746	1.94
405.9667053	0.16
407.9820862	100.00
416.1590576	0.57
420.1296082	0.15
421.1402893	0.22
431.9966736	0.07
433.9257202	4.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	556.2038
Annotation	Tiapamil
Peak:m/z	Relative Intensity
157.7937317	0.16
161.0730438	0.16
165.1898346	0.33
165.8534088	0.92
168.9703369	0.52
171.8421478	0.57
174.1509247	0.39
175.0735016	0.11
181.9468079	0.65
184.9699097	0.29
186.0394897	9.98
190.3117218	0.36
198.0022430	2.86
201.1319733	5.87
206.1573944	0.15
208.0527039	1.57
217.0720520	0.53
219.1416626	0.12
226.1029968	2.38
226.9135437	1.03
230.0392151	0.22
235.7433167	0.15
242.2592926	0.28
244.2777100	1.14
249.0094604	0.46
254.1327820	13.99
255.0631256	0.37
270.2007446	0.75
272.0912476	64.01
273.0746460	3.18
280.1245117	0.18
288.1753540	0.39
290.0853577	100.00
308.2116699	11.87
325.9903564	0.47
328.3131714	0.92
332.0381470	0.39
333.7608643	0.36
353.1445923	0.56
363.3355103	1.37
364.1369629	0.64
368.3179321	0.54
370.1972046	1.37
370.9696045	0.17
392.1178589	0.40
393.9791870	0.66
398.2699585	1.25
417.6423340	0.68
419.3871460	0.40
428.4864502	0.31
429.8037720	0.34
434.8569336	0.51
452.1795654	0.90
454.4088135	0.29
457.2269287	0.91
458.1679077	1.20
463.0778198	0.40
470.2583618	3.76
476.3347778	0.17
484.1854858	2.20
485.1475830	0.26
494.1388550	0.83
502.2666016	4.33
510.2799683	0.25
520.2818604	8.31
538.1726074	19.47
540.9679565	2.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.2142
Annotation	Unknow
Peak:m/z	Relative Intensity
163.1327209	0.05
191.0467224	1.04
192.8103638	0.12
200.9681396	0.10
209.1086121	0.08
217.3125000	0.16
219.0192261	0.08
223.2098389	0.26
232.8479767	0.22
246.9185791	0.11
255.1421661	0.18
260.7086182	0.11
269.0651855	11.22
281.1705322	0.54
291.1599121	0.39
295.2578735	0.06
298.9371338	0.58
306.9616699	0.79
308.9889221	0.64
310.2015991	0.11
311.3504028	0.31
319.0648804	0.23
323.1457520	0.23
329.2001953	0.38
335.0770264	0.12
337.1661377	24.99
338.1699829	2.62
347.0830688	0.78
349.1983643	2.65
351.2981567	0.12
353.2247314	3.91
354.2248535	0.16
357.3398438	0.28
362.9285889	0.06
365.1817627	0.06
367.1650391	10.61
368.2460327	2.06
371.2614136	0.54
377.0602417	0.22
379.0993042	2.52
379.9613647	0.23
381.4862061	0.59
383.0657349	2.03
384.1878662	0.05
389.2434082	1.30
390.0586548	0.12
390.9166260	0.50
392.9714355	0.14
397.2089844	1.43
403.3178711	0.82
409.4537964	0.35
413.2355347	0.39
414.8038330	0.91
415.5218506	1.53
421.1744385	0.79
422.3316040	0.08
424.8098145	0.18
431.0896606	0.19
433.1829834	1.81
439.0527344	2.17
442.9434814	0.22
447.1067505	0.29
449.3626099	0.22
455.3583984	0.21
457.1734619	100.00
458.2689819	8.56
464.1862183	0.06
467.0711060	0.11
469.4083252	1.24
471.2247925	0.53
472.6900024	0.48
473.2922974	6.21
474.5750732	0.99
475.2995605	0.29
479.1808472	0.16
485.2592163	0.31
487.1721191	34.43
488.1151733	1.86
489.1702271	0.91
490.3359375	0.28
493.3078003	0.19
499.2606201	1.64
500.4278564	0.43
501.1585693	0.67
503.2949829	3.00
504.3804321	0.69
511.3248901	0.17
512.1426392	0.24
514.6422729	0.13
517.2957153	5.34
518.3345337	0.76
522.9993896	0.29
529.2173462	0.24
530.2701416	0.10
533.1981812	10.80
535.5911255	0.19
541.2275391	2.29
542.4049683	0.27
547.5979614	0.26
549.7230835	0.11
559.2813110	10.10
560.0682373	1.60
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	654.2362
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
194.1105347	0.01
196.0724640	0.83
203.2165527	0.14
204.1750031	0.07
211.0559235	0.02
214.2453918	0.05
220.1283112	0.41
230.5632324	0.02
234.2132111	0.08
245.3543091	0.04
255.7327576	0.02
256.3362427	0.03
258.2474976	0.03
259.3108826	0.05
261.4464111	0.11
262.2656860	0.15
269.0523071	0.05
279.4030151	0.02
285.1152954	0.23
287.0701294	0.64
287.7231445	0.04
291.9708557	0.04
296.2611084	0.02
300.2777100	0.03
303.1587219	0.57
306.2781372	0.03
308.5723877	0.06
328.1511230	0.03
330.4463501	0.01
331.3332520	0.08
346.1639404	100.00
347.0787964	0.03
388.2155762	0.12
406.2016602	0.04
412.3001709	0.16
423.8508911	0.06
430.3818359	0.11
436.9579468	0.02
442.1587524	0.07
449.2874146	0.07
454.4784546	0.02
456.1750488	0.92
472.2623901	0.11
474.2039795	0.86
487.1721802	0.03
490.2337036	0.77
492.2153320	4.88
497.0482788	0.05
508.1382446	22.57
508.7568970	0.08
532.5822144	0.01
534.2109985	0.06
537.7900391	0.11
550.3806763	0.08
564.5320435	0.04
568.1841431	0.01
570.1238403	0.06
573.7212524	0.02
583.1251831	0.02
588.4125366	0.04
600.3389282	0.03
608.1705933	0.02
609.8792114	0.06
618.4451294	0.13
636.3705444	0.38
638.0012207	0.05
644.3983154	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.1511
Annotation	Scutellarein 7-neohesperidoside
Peak:m/z	Relative Intensity
190.9933167	0.02
199.1931152	0.06
203.0203400	0.12
221.4909058	0.02
241.2537231	0.02
243.0786133	0.04
264.0829468	0.05
267.2861023	0.04
268.1861572	0.12
269.0743103	0.12
279.2568359	0.04
282.1708984	0.07
282.9697876	0.04
285.1386719	2.58
285.7408447	0.04
293.1010742	29.05
294.2091064	0.08
294.9962158	0.10
297.3659058	0.15
298.1430664	0.15
308.4819031	0.01
309.1466064	0.17
311.1627808	1.57
312.3436279	0.18
313.3023071	0.09
321.2594604	0.10
323.1746216	1.08
326.2099609	0.03
327.2075806	0.33
329.3215332	0.03
332.2887573	0.10
333.4570312	0.07
335.2259521	1.17
337.3465576	0.03
339.3967896	0.07
341.2306519	2.65
347.1405029	0.01
353.2060547	8.84
354.1884155	0.38
355.2897339	0.63
357.1135864	0.19
361.1442871	0.25
365.3725586	0.69
367.1920776	0.10
369.0773926	0.14
371.1615601	0.13
377.2919922	0.20
381.7120361	0.07
383.2479858	7.02
384.9636841	0.18
387.3503418	0.04
388.5678101	0.06
395.1334839	0.95
397.3549805	0.10
405.0545654	0.09
407.4034424	0.02
413.2166748	100.00
414.1591797	0.25
418.8324585	0.08
425.1345825	0.58
427.4479370	0.08
429.1877441	0.16
430.0250854	0.04
431.1523438	0.75
437.2225952	0.30
440.2794189	0.09
443.2557983	0.21
447.4703979	0.11
449.3016968	0.24
455.2120361	1.24
465.6060791	0.02
466.3811035	0.09
467.0933838	0.12
469.2915039	0.09
471.3827515	0.12
473.2172241	35.39
474.1829224	0.98
485.2948608	0.95
487.3098145	0.07
488.9351196	0.03
491.0901489	0.12
501.3278198	0.18
503.2192383	10.75
504.3220825	0.58
515.3281250	0.62
517.2858887	0.19
529.3209839	0.05
533.2509155	0.96
534.3258667	0.09
539.2178345	0.12
545.2274170	0.19
546.9843750	0.25
547.5912476	0.18
549.1639404	0.38
551.2044678	0.10
557.1386719	0.37
563.1806030	0.06
575.2340088	3.80
576.1221313	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	487.2306
Annotation	Terretonin A
Peak:m/z	Relative Intensity
143.1363983	0.32
145.0560303	0.40
146.9885101	0.33
148.8858795	0.14
151.0655212	0.47
153.0811157	0.27
155.0962524	0.93
157.2692413	0.55
159.0736847	1.69
160.9713135	1.47
165.0848083	0.82
166.9844818	0.20
168.9310760	1.20
169.7331848	0.21
170.9242249	0.69
173.0017395	0.66
175.1833496	2.56
176.9703522	1.67
179.1458130	0.85
182.1249695	0.37
182.9582672	1.10
185.1353149	1.89
186.9829407	0.91
189.1009216	1.46
191.4193420	0.19
193.0690918	1.07
195.1018982	1.90
197.2060394	4.02
199.0940399	0.90
200.0320740	0.06
201.1164398	1.96
202.9109802	1.42
205.0663910	0.12
207.1864929	0.36
209.0257111	0.46
211.0633545	1.68
212.9271851	2.27
213.6026917	0.08
214.9765167	2.69
217.0242004	0.81
219.0835114	0.80
221.2545319	0.51
222.9173889	0.58
225.1620178	1.23
227.1795654	1.39
229.0079041	3.31
231.1340027	1.33
233.2331238	1.14
235.1979065	1.79
237.2870178	1.81
239.0717773	1.23
241.2349701	0.95
243.1550598	1.49
245.3064117	3.75
246.0951691	0.17
247.2117615	1.32
249.2227478	1.52
251.1578674	4.84
253.3067017	0.82
255.1397705	1.00
257.3109131	1.09
259.1383972	0.85
261.0473328	3.45
262.9821777	0.44
264.2843018	0.46
265.2342834	0.68
267.2145386	2.55
269.1792603	5.69
271.2987976	1.77
273.1678467	1.70
274.2154846	0.19
275.2428589	1.37
277.1656799	2.00
277.9426270	0.44
279.2395935	2.51
281.1541748	4.79
283.2123718	1.74
285.0450134	3.86
287.1473694	2.41
289.1691284	5.13
291.1054993	1.67
293.3938599	1.76
294.2725220	0.16
295.2254028	3.42
297.1583862	3.41
299.0520935	1.26
300.3227844	0.64
301.1682739	1.61
303.2838135	4.69
305.1647644	3.44
307.2703857	7.23
308.3536377	0.20
309.2169800	2.38
311.2203979	1.53
311.9948730	0.08
313.1974182	4.72
315.1970520	1.41
317.1959229	1.81
318.9464722	0.90
321.2194214	12.54
323.1748962	4.53
325.0223389	0.58
327.2658691	0.66
331.1716309	9.94
333.3300476	2.22
335.2948608	2.29
337.2690125	1.17
339.2035522	6.55
341.1767273	6.95
345.2675476	4.61
346.4845581	0.25
347.2592773	0.51
349.2115479	26.17
350.1416626	0.29
351.3053589	2.39
353.0180664	0.86
353.6591492	0.33
355.3637390	0.39
356.4949036	0.46
357.2079773	0.72
359.1792603	0.45
363.2320557	12.99
365.2040710	10.89
366.5146790	5.67
367.2744141	13.00
368.5476074	0.05
369.2738647	2.20
371.4478455	0.39
373.1762085	4.71
376.4762878	0.48
377.6158142	0.29
381.3013916	10.24
385.1521912	11.51
391.2950134	38.76
393.1827698	0.14
399.3894958	1.70
409.2280579	100.00
409.9630432	0.26
423.4565125	0.41
425.3227844	0.09
427.2103577	91.49
427.8536987	0.47
428.9262390	0.18
433.4062500	0.05
441.2236633	11.91
445.2154541	6.52
451.0722961	0.51
469.2931824	14.63
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	637.1769
Annotation	Butrin
Peak:m/z	Relative Intensity
180.1662598	0.02
182.1370392	0.02
213.2316437	0.08
240.1460876	0.01
265.2626343	0.02
270.0646057	0.10
271.2452393	0.04
281.1541748	0.13
286.1464844	0.04
289.1640320	0.03
297.9583435	0.11
299.0705566	0.06
301.1994629	0.12
313.1713257	0.79
316.1831055	0.93
317.1257324	0.39
328.2734375	0.04
329.1629028	0.44
331.1210327	91.73
331.7546387	0.12
334.5492554	0.07
341.2192993	0.14
347.3742676	0.03
366.6500244	0.16
375.0962524	0.04
387.1154175	0.08
389.0356445	0.03
401.4669800	0.20
409.6512451	0.04
430.1081543	0.26
431.3245239	0.01
432.5705566	0.11
442.0356445	0.04
445.4363403	0.07
448.6697998	0.09
450.1828003	0.02
457.3827515	0.07
461.2183228	0.07
473.2059326	0.06
475.4244385	0.73
479.1699219	0.43
493.1687622	100.00
493.8401489	0.11
518.8672485	0.03
521.2185669	0.30
535.1535645	23.66
535.8617554	0.10
537.5265503	0.01
549.0704956	0.02
553.1736450	0.09
556.6245728	0.04
575.2743530	3.85
578.2920532	0.05
590.3607178	0.04
593.4108276	0.21
594.4462280	0.07
598.9716797	0.03
604.8916016	0.09
609.3019409	0.08
617.1591187	0.08
619.1964111	0.24
622.1555176	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2157
Annotation	Terretonin A
Peak:m/z	Relative Intensity
139.1041718	0.13
140.8661499	0.07
145.0751801	0.71
146.8250580	0.10
148.5462341	0.03
152.9975891	0.15
155.1984253	0.05
156.8840942	0.29
158.9420624	0.04
160.9748535	0.46
163.0810547	1.20
165.2038269	0.03
167.0427704	0.12
168.9200745	0.05
170.9884949	0.09
173.0251617	0.16
175.0314331	0.36
177.0940857	1.86
179.0455170	0.17
181.7064209	0.11
183.1406403	0.41
185.2435608	0.20
186.0469360	0.04
186.9892578	0.49
189.0393677	0.12
193.1571960	0.24
197.1618347	0.44
199.1454163	0.30
199.8553314	0.11
201.1552277	0.65
202.8122253	0.24
205.0391846	0.07
209.2303162	0.26
211.0043640	0.29
212.1632538	0.09
214.9919586	0.09
215.8521423	0.13
217.1531677	0.15
219.1049194	0.27
223.1834564	0.09
225.3573303	0.04
226.8538055	0.29
229.0003204	0.38
231.0642700	0.21
233.4898987	0.19
235.2617798	0.65
237.0787354	0.45
238.0940552	0.09
241.2649536	0.10
245.2361298	0.21
249.9188843	0.07
251.1526794	0.22
253.2456970	0.38
255.3185730	0.23
257.2576599	0.29
259.0713806	0.09
262.7001343	0.06
264.9926453	0.21
266.0803223	0.06
267.1341248	0.39
269.0951843	0.18
273.2248230	0.10
275.1887512	0.52
277.2251892	0.15
279.3335876	0.47
283.2692871	0.38
285.1994019	0.99
287.3320312	0.16
289.1454773	0.40
290.9824524	0.52
293.3242188	0.27
295.0953369	0.49
297.1706543	0.21
298.3446045	0.05
301.2136536	0.30
303.4143066	0.09
305.3169556	0.59
307.3307800	0.15
309.2001343	0.24
311.2298889	1.03
312.0937805	0.08
313.1799316	0.13
315.1322021	0.66
315.9419861	0.06
317.3540039	0.56
319.2975464	0.40
321.3900757	0.35
322.9731445	0.23
323.5989685	0.09
324.7111206	0.07
325.3328247	0.19
327.1990662	0.61
329.3002319	0.40
331.1924438	0.55
333.1855774	0.39
334.7225952	0.32
335.3920288	0.39
337.4488831	0.54
339.2048035	1.42
341.4420776	0.81
342.8222351	0.25
345.5641785	0.17
347.2250366	0.50
349.3257141	1.16
350.1178589	0.09
351.2151489	2.89
352.1716309	0.11
353.1947937	0.63
355.2332764	0.31
357.0546265	1.09
359.1473083	0.38
361.2774353	0.83
365.1067505	0.30
367.0944214	1.26
369.1788940	34.89
369.8523254	0.12
371.0879822	0.47
373.0780334	0.05
374.9605103	0.12
377.1828308	1.50
379.0280457	0.20
380.3546143	0.05
381.1716309	0.41
383.1811218	1.38
385.2597656	1.14
386.9038086	0.07
389.4583435	0.28
391.1455078	0.16
393.2941284	2.82
395.3137512	1.90
396.7390747	0.12
398.3907471	0.17
399.3013611	0.69
401.5586548	0.35
404.6007080	0.20
405.4599915	0.08
406.1993103	0.07
409.2543640	6.12
411.2452698	20.03
413.2490845	7.50
419.2281189	1.26
427.2322083	100.00
427.9305115	0.10
429.2798462	13.62
431.0924683	0.16
437.3310242	4.38
445.2304077	0.53
455.2384033	22.16
456.1966553	0.24
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	975.4003
Annotation	RA XIII
Peak:m/z	Relative Intensity
283.3488464	0.47
284.0465393	0.07
291.2402954	0.05
293.2348938	0.73
307.1717529	0.22
308.1964722	0.08
309.3684692	0.14
311.1885071	0.60
319.1568604	0.17
321.3916626	0.09
325.2941284	0.08
327.3488464	0.21
337.2525940	2.41
339.1062622	0.23
351.2603149	0.13
355.2429810	0.60
369.1719360	1.66
395.2600098	0.25
399.3814392	0.13
413.3185425	1.08
442.8602295	0.11
457.1441650	8.09
469.5217896	0.07
487.2778931	100.00
653.5069580	0.06
669.3356323	0.15
831.5753784	0.17
848.4620361	0.23
877.6141968	0.12
882.5017700	7.10
885.3569336	0.12
894.3806763	0.28
912.4214478	19.85
939.3230591	0.46
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	813.2086
Annotation	Faratroside
Peak:m/z	Relative Intensity
285.1375732	0.06
285.9963074	0.04
286.9382324	0.18
301.2114258	0.11
302.1634216	0.07
305.0230103	0.72
315.1829834	0.21
329.3766785	0.16
330.2192993	0.78
345.0751343	6.34
349.5068665	0.04
377.2299194	0.10
387.2912598	0.03
388.9981079	0.06
407.2425537	0.05
467.1427612	0.11
492.1064453	0.05
507.2503662	37.25
533.8989258	0.10
535.3334961	0.06
549.1786499	20.51
549.8432617	0.05
589.2914429	7.39
591.1370239	4.58
609.5902710	0.03
633.0647583	0.72
633.6796265	0.02
647.1683960	0.27
651.1358032	100.00
651.8554077	0.03
657.0422974	0.18
665.1690063	0.10
668.4790039	0.03
669.4296875	0.07
675.0936890	0.37
683.1719971	0.13
684.2235718	0.05
687.1968384	0.07
693.2477417	11.60
705.0156250	0.97
705.7450562	0.31
723.1605225	7.49
735.2527466	0.52
749.1737671	0.20
753.1853027	31.49
765.1687622	0.06
767.3398438	0.04
768.5841675	0.03
777.1112061	0.10
779.9016113	0.08
782.9699097	0.52
795.1929932	2.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	357.12
Annotation	Junipediol B 8-glucoside
Peak:m/z	Relative Intensity
134.0676270	0.06
135.9621582	0.38
149.0404663	0.10
151.1034546	4.40
177.0704041	1.59
192.9255676	0.01
195.0053558	100.00
285.2132568	0.40
297.2293701	0.13
298.0663452	0.12
300.2220154	0.02
327.4465942	0.04
339.1243286	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	295.0459
Annotation	Norbergenin
Peak:m/z	Relative Intensity
84.9431152	13.72
110.8565826	6.88
115.0451660	0.33
120.9192886	34.68
129.0102234	70.28
131.2719574	0.13
133.0852661	0.95
135.0272522	0.52
145.0785522	0.69
147.0319214	0.31
149.1482849	0.34
153.0346069	0.16
154.8056641	0.09
158.9515381	0.21
161.0462036	2.75
163.1069489	0.11
172.9416504	100.00
175.1160889	0.20
177.2843781	0.28
179.0241699	0.54
189.0911255	59.24
193.0464172	1.83
207.4748535	0.10
217.0989990	0.18
221.2221680	0.46
225.1291809	0.14
232.7827148	0.19
235.1973877	2.35
247.2388306	0.09
251.0436401	99.57
258.8919983	3.02
261.0598145	0.24
267.3335571	0.46
277.0909424	30.46
278.1845398	0.21
280.1202698	0.26
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	517.2079
Annotation	Provincialin
Peak:m/z	Relative Intensity
191.2986298	0.13
213.3144531	0.10
218.9326477	0.70
257.2174072	0.25
271.0993652	0.39
289.4692383	0.10
297.2255859	0.14
298.6345215	0.62
299.2430420	3.24
315.1396484	0.19
317.0429688	0.15
333.1234741	8.50
353.2553101	0.50
356.9906006	0.08
365.1505127	0.23
367.2318115	0.33
371.3156128	0.25
375.3275757	0.58
383.3601074	0.25
391.1860352	0.55
393.2672119	3.06
401.2710571	0.42
409.3082886	0.15
411.2555542	13.78
429.0808716	71.38
429.7915039	0.44
435.4264526	0.29
443.3659058	0.27
446.3154297	0.05
453.3050537	55.46
469.4315186	0.31
471.2448120	100.00
473.1305542	0.24
479.2035522	0.03
480.2240601	0.16
498.5386353	0.19
499.1995239	0.65
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	453.1402
Annotation	Unknow
Peak:m/z	Relative Intensity
131.1225433	0.01
139.0522156	0.02
143.1089478	0.01
147.1751404	0.02
161.2855682	0.02
163.0651245	2.03
174.5854797	0.03
187.4035034	0.02
189.0131836	0.38
223.0373230	0.03
234.8769226	0.02
249.1345825	0.02
259.2256165	0.02
279.3699951	0.01
291.1163330	0.02
331.2544861	0.05
349.3121033	0.14
352.9914551	0.01
365.6619263	0.03
367.2388000	0.07
373.3059998	0.03
376.6296082	0.01
381.3392029	0.02
391.0752563	0.01
393.5330505	0.08
409.2060852	100.00
411.1455383	0.10
417.5989685	0.03
421.6352234	0.02
435.1551208	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	552.1735
Annotation	Unknow
Peak:m/z	Relative Intensity
159.8895111	0.51
162.7219238	0.04
165.0210114	1.03
166.9398193	0.14
168.2206421	0.18
171.9287415	0.02
173.9921112	0.42
176.9953766	0.03
179.1333618	1.11
187.2544250	0.10
191.3637085	0.12
193.1461182	0.09
194.0289459	0.23
194.9081726	0.16
197.0919037	2.14
199.2007904	0.06
204.1370239	0.17
205.1607208	0.02
212.0043335	0.18
222.0737457	1.15
223.1003265	0.86
227.1860657	0.05
228.1567993	0.08
231.8063965	0.04
240.1257324	7.79
241.0175171	0.03
244.1312256	0.07
245.0243683	0.09
246.3242493	0.07
248.1754150	0.02
250.2189484	0.46
251.1716003	0.04
255.0992737	0.16
264.1401367	0.03
266.2913208	0.05
268.0240479	23.45
269.0491943	4.64
269.9201050	0.09
284.6643677	0.11
286.0568237	44.85
287.0508423	0.45
290.1515503	0.13
300.0270386	0.06
304.0450439	100.00
309.2358398	0.07
310.3062134	0.43
311.4262695	0.01
314.2443848	0.32
316.1133423	0.18
317.8004761	0.11
321.9340210	0.07
326.0369263	0.04
328.0690308	1.09
329.2763672	0.04
330.1781616	1.14
334.1616211	0.49
342.2348633	0.63
346.1199951	2.43
346.9672852	0.04
348.1352539	0.06
349.8584595	0.14
352.2064209	0.53
353.9661255	0.20
358.0065308	0.34
359.0335693	0.02
360.5127563	0.13
362.2235718	0.03
367.0303955	0.10
368.2052002	1.17
370.2064209	0.20
371.2338257	0.06
372.2199707	0.11
375.8836670	0.63
376.5023804	0.24
378.2587280	0.22
383.3348389	0.03
390.0979614	0.02
394.1762695	0.08
395.3322754	0.05
396.8713989	0.04
405.1596069	0.07
406.0640259	0.14
412.1313477	0.26
413.1646118	0.03
418.2753296	0.14
424.4133911	0.04
427.1542358	0.08
430.5720215	0.04
431.2141724	0.11
433.8733521	0.08
436.2104492	0.13
448.5399780	0.14
454.2375488	0.34
456.0411987	0.02
462.3776245	0.32
463.1845703	0.38
466.2769775	0.76
472.2515869	0.28
480.1397095	4.99
481.3351440	0.06
489.2121582	0.05
490.2047729	0.17
491.1488647	0.16
492.4895630	0.10
493.1813354	0.12
498.1748657	7.02
499.3167114	0.17
506.1674194	0.18
516.2030640	8.77
517.1212769	0.21
523.2578125	0.06
532.2254028	0.03
534.1727905	17.91
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.1821
Annotation	Butrin
Peak:m/z	Relative Intensity
174.0616302	0.25
175.1351471	0.04
185.1470032	0.27
187.0175629	0.20
195.0058289	0.17
198.1540833	0.22
199.0409241	1.50
200.1921234	0.17
201.2140961	0.42
214.1877441	0.23
215.1881409	0.25
216.6366577	0.28
217.2618256	0.02
223.0069275	0.04
224.1163330	0.09
225.0470886	0.11
226.1307831	0.14
227.0335999	0.63
233.0728149	0.15
239.1510010	0.29
240.0489044	0.75
241.1221619	0.91
242.1467590	1.43
244.2958527	0.02
255.3563538	0.21
257.1659546	0.46
258.0946960	0.52
259.1064148	0.14
267.1964722	0.09
268.0837402	0.62
283.0913696	1.03
285.1394653	0.11
286.0212402	1.51
292.2335510	0.07
301.0585022	100.00
301.8637085	0.07
307.0964050	0.05
310.1624756	0.03
325.1055908	1.74
343.1447754	0.11
355.1730347	0.12
367.0699463	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	932.4802
Annotation	Unknow
Peak:m/z	Relative Intensity
302.9205933	0.23
333.2490234	0.06
353.3854370	0.34
411.1161499	0.16
419.3211670	0.09
432.4656372	0.25
435.2741089	0.17
460.1448364	0.51
473.7074585	0.34
476.4237671	0.12
481.9702148	0.11
489.3482666	0.24
495.4621582	0.17
506.2563477	0.08
515.4508667	0.17
522.9647827	0.08
524.5539551	0.20
530.5291748	0.54
532.6426392	0.27
540.2551880	0.20
545.3457031	0.11
546.5076294	0.74
558.2589722	0.14
566.3435669	0.70
573.3505859	0.41
576.2667847	0.26
578.1201782	0.16
590.3399048	0.18
593.3870239	0.72
603.3803711	0.15
614.4996948	0.61
615.4402466	0.40
629.6926880	0.16
643.3765869	0.06
644.3701782	0.66
645.5651245	0.14
652.9494019	0.74
653.7287598	0.29
654.7165527	0.14
657.6027222	0.28
661.3056641	0.27
664.8951416	0.07
666.0407715	0.17
672.4863892	0.48
682.5242310	0.24
691.6270142	0.15
692.6749268	1.37
693.4138184	0.26
697.0133667	0.36
700.1566162	0.16
705.3997192	0.36
706.3957520	0.24
707.5386353	0.18
709.4420166	0.29
714.4938354	0.17
717.4676514	0.33
719.1989136	0.33
720.5455322	1.56
721.3896484	0.39
725.2489624	0.15
729.6341553	0.43
737.5366821	0.13
738.2816772	0.67
746.3922729	0.40
747.6724243	0.12
755.5273438	0.15
761.6132202	0.10
766.4657593	0.74
768.4526978	0.52
773.3615112	0.10
774.5974121	0.56
775.4643555	0.09
776.6771851	0.12
778.6722412	0.14
779.3878174	0.36
780.3256226	0.76
783.4812622	0.18
787.4426270	0.42
789.7302856	0.73
790.5352173	0.14
791.5108643	4.03
792.5706177	0.47
800.6793823	0.16
803.3660278	0.47
805.4854126	4.24
806.5964966	2.17
807.5827026	1.29
808.5722046	1.01
810.7996216	1.00
815.5011597	0.69
816.4046631	0.25
817.5917358	0.51
818.6032104	0.51
819.5593262	1.07
820.3319702	0.50
820.9568481	0.06
825.3218384	0.04
827.4651489	0.44
831.6284180	0.52
832.7149658	1.29
833.4732666	3.64
834.4005737	0.67
835.8375854	0.36
836.6743774	0.09
843.1461792	0.49
845.3999634	0.47
846.7778320	0.28
847.5170288	0.17
855.9500122	0.53
857.3587036	0.64
859.7373047	0.23
861.4026489	0.24
863.4900513	0.83
864.4002075	0.29
869.3933716	0.14
870.5598755	0.70
873.9483032	2.52
874.5649414	5.30
875.4604492	1.69
876.1053467	0.37
884.5925903	4.65
885.4357300	1.63
886.5464478	6.16
887.5722656	3.24
888.5722656	3.49
889.4963379	0.99
902.5136719	29.39
903.7239380	17.73
904.6176147	100.00
905.7142944	33.19
914.5387573	65.17
915.6632080	29.78
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	292.1017
Annotation	Sarmentosin epoxide
Peak:m/z	Relative Intensity
83.9155960	0.18
84.7915802	0.17
108.9164734	0.30
112.9739990	0.11
127.0252533	0.30
128.6728363	0.21
130.0635529	0.70
130.8817749	0.28
146.1555176	0.26
147.1052246	0.20
149.1670532	0.09
149.9750977	0.11
159.9815674	0.22
170.1839752	0.15
171.1061707	0.50
175.9755554	0.27
176.9779358	0.26
177.9891052	0.27
181.7859802	0.23
187.9938507	6.44
188.9932098	0.54
199.9670715	0.10
201.9342346	1.52
205.0193176	0.43
206.2065125	0.11
207.0920105	1.24
216.9640808	0.12
217.8742065	0.08
220.1216431	0.35
220.7413940	0.12
222.0935669	0.07
223.0088196	0.69
228.2103271	0.32
231.1006165	0.55
232.1039734	0.49
234.2050781	0.32
238.0332642	0.22
242.9458008	0.61
246.0055542	1.57
247.0351257	1.22
248.1829529	0.69
249.1664124	0.23
250.0978394	0.46
251.0454712	0.61
256.2957153	0.34
260.2136230	0.09
261.1957092	0.11
263.1538086	0.05
270.1256104	0.34
272.0829163	0.19
274.1157227	100.00
276.4647217	0.68
282.8627930	0.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	367.1587
Annotation	Unknow
Peak:m/z	Relative Intensity
104.8970490	0.60
107.0901718	0.09
108.8238220	0.16
112.1411133	0.03
113.1103210	0.07
118.8865280	1.66
121.1213760	0.06
122.2348328	0.10
123.2651901	0.10
124.8176804	0.10
126.8721008	1.36
129.8748779	0.04
131.0224609	0.07
132.8146057	0.04
135.0698242	0.24
136.1390381	0.12
137.1004639	0.02
144.9949341	0.15
146.8534088	0.18
148.0993652	0.05
149.0915222	0.17
150.6395874	0.05
156.8434143	0.09
159.1096497	0.30
161.1995544	0.05
164.2793274	0.03
171.0268860	0.12
179.3220520	0.10
181.1244354	0.23
185.2501831	0.25
186.1324463	0.17
187.0934601	1.20
189.8868713	0.05
191.0228271	0.13
202.6097870	0.02
203.5983582	0.47
204.2860260	3.76
205.1764069	3.90
207.0666962	0.06
209.1315918	1.13
213.0030518	1.21
216.0781555	0.09
217.2290649	0.81
218.2538147	0.08
221.2687683	0.14
229.2344971	0.45
230.9797363	15.26
233.1045227	0.08
235.0868225	0.14
236.2002563	0.05
239.2667847	0.10
241.2549133	0.08
242.4448242	0.10
247.7387695	0.35
248.8630981	10.63
249.6032715	0.05
250.7316895	0.06
253.1455688	0.25
254.1234741	0.12
259.4089661	0.20
260.4465637	0.03
264.1084595	0.04
265.2188110	0.12
269.0520020	0.79
276.3138733	0.19
277.2320557	0.24
278.3706055	0.04
286.2168579	0.32
287.2199707	0.70
288.0562744	0.11
288.9935303	0.09
291.4737854	0.05
294.3223267	1.41
295.1746216	1.50
305.1007385	3.09
307.1781311	0.05
312.3009644	4.66
313.1420288	6.43
320.9780273	0.05
323.1665344	0.03
325.3032837	0.09
330.2539368	13.51
331.0634766	14.97
332.0950623	0.06
335.3327332	0.08
337.1231079	0.13
339.4594727	0.06
341.3549194	0.14
346.4095764	0.15
348.3880005	51.51
349.0836487	100.00
349.7913513	0.40
361.4182434	0.04
367.4064636	0.10
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	272.96
Annotation	Ribose-1-arsenate
Peak:m/z	Relative Intensity
114.9546280	5.30
130.9361572	0.56
142.8374634	0.08
158.8938141	100.00
160.0611420	0.02
199.0028381	2.18
201.1063232	0.02
217.0742188	0.91
225.6135254	0.04
228.9043274	24.42
229.5184021	0.14
245.0935059	0.21
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1119.3052
Annotation	Unknow
Peak:m/z	Relative Intensity
315.2382202	0.09
327.3757935	0.03
330.0840759	1.09
331.4378052	0.08
345.0624084	4.77
345.6879578	0.09
449.0924988	0.39
488.6752930	0.09
489.3515015	0.04
491.1383667	0.03
493.5379944	0.06
501.3840332	0.07
507.2510376	11.74
519.3038330	0.02
531.3051758	0.05
535.1864014	0.30
549.2446289	9.01
551.1289062	0.07
565.4241943	0.04
589.2418213	3.81
591.1127930	3.07
603.5024414	0.08
609.3466797	0.42
611.0035400	0.11
631.2523193	1.00
633.2016602	0.62
651.0995483	16.80
651.7282104	0.08
669.1449585	15.80
669.7618408	0.12
671.3792114	0.12
672.5971680	0.05
673.2679443	0.05
675.0719604	0.20
679.3773193	0.08
693.0568237	5.82
693.6776123	0.08
711.2171631	15.68
713.4772949	0.07
733.2879639	0.62
734.9685059	0.40
735.6810913	0.01
750.6037598	0.27
751.2670898	5.48
753.2744141	5.85
764.4821777	0.08
765.2679443	0.22
775.0908203	0.17
776.8367920	0.12
783.4448242	0.36
785.4769287	0.08
793.1978149	2.16
795.1926880	12.86
813.1464844	98.88
813.7607422	0.58
818.9665527	0.30
827.2028809	0.14
833.1933594	0.35
835.0588379	0.34
837.1451416	2.75
841.5994873	0.09
849.2199707	0.05
852.9652100	0.02
855.0887451	18.83
855.7816162	0.11
864.9865723	0.03
867.2861328	0.33
877.2478027	0.68
881.2280273	0.10
883.2670898	0.20
885.3237305	0.10
895.0661621	5.87
895.7677002	0.19
897.1376953	1.75
900.7152100	0.09
914.3393555	0.02
927.2625732	0.24
937.0236816	0.14
939.1748047	0.84
948.5848389	0.03
957.1253662	100.00
957.7696533	0.43
963.0594482	0.14
969.5511475	0.08
975.1918945	3.48
999.1086426	4.58
999.8486328	0.06
1011.0957030	0.31
1017.2631840	0.22
1028.9458010	1.17
1029.5783690	0.27
1054.9138180	0.10
1057.2404790	0.23
1059.1562500	9.82
1083.4244380	0.08
1089.3664550	0.55
1101.1564940	3.54
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	503.1404
Annotation	6-Caffeoylsucrose
Peak:m/z	Relative Intensity
161.0082245	0.86
175.2510071	0.15
179.0266724	12.10
189.1495056	0.09
191.7604218	0.08
193.3353882	0.08
203.0986938	0.69
221.1359100	0.23
233.0277100	0.06
251.0607452	0.25
281.1080017	0.23
295.2378235	0.03
311.3212891	0.08
323.2084351	2.54
329.1741333	0.03
341.1295776	100.00
365.2366333	1.73
370.8202515	0.07
383.1755066	0.34
385.3852844	0.04
386.0390625	0.02
395.2571106	0.26
407.2681580	0.06
411.4394836	0.11
412.9930115	0.12
425.2874451	0.04
443.3094788	0.45
445.0197449	0.17
457.1779480	0.13
459.8581543	0.05
467.4017944	0.02
472.5972290	0.08
473.2622986	0.05
484.4606323	0.07
485.3131714	0.04
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	710.3875
Annotation	Dianthin D
Peak:m/z	Relative Intensity
329.5080566	0.03
343.2312622	0.10
419.3361206	0.04
420.5349121	0.22
430.2236938	0.06
472.3839111	0.22
476.8903809	0.25
477.6271362	0.01
489.7740479	0.04
492.0399170	0.04
503.4266968	0.56
521.3674927	0.08
523.7525635	0.17
528.5977173	0.04
539.2854614	0.40
543.3255005	0.05
547.4182739	0.20
549.2950439	0.26
550.5567627	0.02
567.1017456	0.55
578.2429810	0.07
589.3174438	0.16
593.2229614	0.04
605.4776611	1.35
607.2424316	0.84
618.9959106	0.05
621.3474731	0.05
622.9875488	0.05
623.7454834	0.05
624.4638062	0.25
625.4041138	0.02
627.5919800	0.07
643.1376343	0.09
647.3288574	0.06
651.4461670	0.13
652.5806274	0.08
663.6337891	0.09
665.2324829	0.50
665.8489990	0.04
667.2314453	0.33
681.3944702	100.00
682.0203857	1.10
692.6152954	0.76
693.5115356	2.49
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	769.4009
Annotation	Scopoloside II
Peak:m/z	Relative Intensity
237.2122955	0.03
245.2466736	0.08
266.2489014	0.01
284.1561890	0.10
298.3655701	0.06
299.0615540	0.06
311.1034546	0.11
334.4214783	0.07
354.2682495	0.03
429.1785278	0.18
442.6522217	0.02
454.5319214	0.10
462.1666870	0.07
486.5953369	0.02
501.4097900	1.83
502.4212036	4.43
533.8218384	0.05
537.2137451	0.04
564.9591064	0.55
565.6812134	0.37
566.4087524	0.98
572.8303223	0.04
593.4082031	0.03
595.2256470	0.02
604.4147339	0.06
610.0632324	0.03
616.0650024	0.09
620.5806274	0.20
621.4820557	0.03
622.4755249	0.63
626.2538452	0.03
640.5709229	0.12
645.4494019	0.03
646.4805908	0.41
650.7736206	0.01
663.6904297	17.99
664.4589844	100.00
665.0880127	0.24
678.3181152	0.12
681.3804321	0.98
682.3173218	8.23
682.9236450	0.05
706.5173950	0.20
710.3847046	0.25
723.7108765	2.68
724.3810425	12.15
725.3049927	0.08
726.3884888	0.13
735.3775635	0.06
752.1119995	0.14
752.7417603	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	433.17
Annotation	Secologanin dimethyl acetal
Peak:m/z	Relative Intensity
124.9920197	16.61
143.0187225	5.49
150.7284241	0.34
165.0782776	0.23
267.2519531	0.44
271.0787659	20.04
282.1179504	0.31
283.2182007	0.35
288.3751831	0.49
289.1364136	2.24
311.0552979	38.22
312.1574097	47.70
313.2167358	100.00
327.0520020	0.19
330.2206726	2.11
330.9087219	13.51
341.2074890	5.98
342.2461243	11.04
343.1923523	29.15
345.2414856	0.21
354.1450806	0.59
355.2860107	3.13
357.0733643	0.19
369.0243835	0.37
370.5569763	1.08
371.1964722	13.46
373.2002258	2.41
378.9181519	0.87
383.1323242	1.03
385.2399597	0.83
387.2648926	5.58
389.0489807	2.03
390.4349060	0.86
391.3011475	0.18
397.1727295	1.12
413.1036072	0.68
415.1833801	6.48
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	329.0514
Annotation	5-Hydroxydantrolene
Peak:m/z	Relative Intensity
108.0603256	1.51
110.9614258	1.26
112.9826584	0.33
121.0629883	0.44
122.9358215	2.38
125.0476990	0.97
128.9794769	8.14
130.1093292	0.10
137.0167847	0.80
144.9839020	0.45
147.0383301	11.85
149.7723083	0.13
152.0482025	5.24
153.1577759	0.08
164.9451294	0.37
167.0163879	94.00
172.9914856	6.70
179.0570984	0.23
181.0593109	0.54
183.1097870	0.10
190.9516144	100.00
207.1261292	0.40
209.0798035	41.05
221.3428345	0.16
222.9416809	0.19
232.1420288	0.15
238.9729309	0.49
251.3666382	0.34
267.2067261	0.33
269.2049561	1.22
281.3009949	0.33
283.1499634	0.51
284.9823914	2.35
293.2047119	1.29
297.3463135	0.09
301.0355225	0.21
311.0901489	29.20
314.2861328	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	503.1902
Annotation	Limonexic acid
Peak:m/z	Relative Intensity
143.7325439	0.06
146.1085205	0.06
148.1148376	0.18
148.9736176	1.36
150.9609985	0.41
159.0780487	0.07
161.0947266	0.84
163.0270996	7.89
165.0227966	0.13
173.0213928	0.26
175.0406494	2.23
177.1322937	0.92
179.1240845	1.84
183.1237946	0.03
185.1913300	0.03
186.0652924	0.04
187.1411285	0.87
189.1371460	0.29
191.0917053	14.32
193.0310669	1.71
197.0568695	0.19
198.9962158	0.30
201.1540527	0.57
203.1309509	0.28
205.0371704	0.94
206.9188843	0.05
209.0275269	4.98
211.0507965	0.26
211.8076477	0.10
213.2214661	0.34
213.9647064	0.04
215.0743103	0.64
217.1319275	7.90
219.1873779	0.25
221.1734314	0.68
225.1896362	0.20
226.0814056	0.11
227.2325134	0.13
229.1621399	1.20
231.0545654	0.15
233.2825012	0.67
235.0173340	5.20
237.2429657	0.10
238.9686279	0.21
241.1688385	2.99
243.3034363	1.07
244.8825378	0.30
247.1498718	1.57
249.0935669	0.11
250.9994659	1.96
253.0396271	1.33
254.1307678	0.16
255.2354431	0.13
257.1191711	1.35
259.1091614	0.94
263.1241150	0.40
265.1924744	0.31
267.3417053	0.06
268.3291321	0.04
269.0393677	0.13
271.0869141	2.46
275.0301208	1.55
277.4138794	0.34
279.1612549	0.29
281.1085205	0.35
282.8481140	0.35
284.8235474	0.02
287.1355896	0.63
289.1210022	3.50
291.0706177	0.21
293.0812073	3.51
295.2744141	0.12
297.2077637	6.93
299.2008057	1.06
301.0059204	0.67
305.1810303	0.30
307.1627197	1.62
311.0714722	6.00
313.2711182	0.22
315.3044434	0.04
317.0835876	1.34
319.1888733	0.31
320.8964233	0.16
323.1264343	4.05
325.1665649	8.08
327.2987671	0.21
328.3852844	0.05
331.1489868	0.15
333.0234070	0.14
335.1077271	4.29
337.2062378	1.22
339.1815796	12.01
341.1469116	100.00
341.8768005	0.41
343.2462769	2.38
347.1777039	0.19
351.2431946	0.35
353.0993652	37.14
355.2233887	0.36
355.9391479	0.05
357.1746216	1.35
358.9188232	1.05
361.1926270	2.61
365.1676941	3.28
369.3418884	0.23
370.9096069	0.07
372.9924622	0.50
375.0675659	0.02
377.0549011	0.60
379.1102295	9.37
381.0696411	0.24
383.0985718	4.06
389.1441650	0.82
390.3421326	0.03
393.4480896	0.23
394.5689087	0.10
395.2646179	0.73
397.9875793	0.10
399.2277527	0.20
401.1177063	0.15
403.1617432	0.16
405.2783813	0.18
407.2357483	2.71
411.3533630	0.08
413.2032776	0.24
417.2452698	0.48
419.2061157	1.52
421.2081604	0.26
424.3744507	0.11
425.1943054	0.48
429.4801331	0.02
431.2905579	3.81
433.1186829	0.03
434.7604065	0.19
435.4376526	0.08
437.3065491	0.60
439.1333618	0.28
441.0032349	0.33
443.3731384	0.05
449.2455139	10.56
455.5280762	0.12
458.1834106	0.16
460.5565491	0.25
461.3998413	0.05
467.1196594	28.67
467.7576294	0.09
468.4292297	0.16
485.1847534	37.87
486.3709106	0.05
487.6134644	0.23
488.3585815	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	301.1061
Annotation	Isosativanone
Peak:m/z	Relative Intensity
153.1805115	0.05
201.2022705	0.01
206.8125305	0.03
215.3121338	0.02
216.8981628	0.02
231.0914917	0.57
232.9911194	100.00
233.6104431	0.32
234.2676392	0.00
235.1743164	0.02
245.0420837	0.33
247.7419128	0.01
257.8101196	0.02
259.2807007	0.12
260.1612549	0.01
273.6007690	0.01
283.1608276	0.13
285.9349976	0.04
287.1494141	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	322.1276
Annotation	Niazirinin
Peak:m/z	Relative Intensity
127.0970001	0.02
151.0186768	0.06
157.9342957	0.05
160.0689087	0.12
167.0150604	0.02
169.0061646	0.03
177.1464996	0.13
187.1914673	0.06
201.2131805	0.08
209.4714050	0.03
210.1710205	0.03
212.0509949	0.03
221.1577148	0.05
222.1431580	0.01
223.4110413	0.05
233.0518799	0.01
239.0589905	0.01
248.1423340	0.06
252.0350952	0.01
259.1933594	0.02
260.9823608	0.04
263.1079102	0.01
266.2288513	0.08
276.1198730	0.06
281.0042419	0.14
287.0450439	10.93
289.3328552	0.04
290.9135132	0.12
294.3444824	0.09
295.2433777	0.09
299.5735779	0.05
304.8476257	100.00
305.5154724	0.28
306.2573547	0.13
307.1215210	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	637.2261
Annotation	Unknow
Peak:m/z	Relative Intensity
182.9538269	0.21
210.7704163	0.30
212.0316315	0.33
241.1055908	0.99
246.1336060	0.54
246.8605347	0.27
253.0157471	0.13
257.8796082	0.42
259.0968628	1.68
259.8587646	0.41
270.9929504	7.04
272.1239014	0.94
288.6473389	8.60
289.9132996	0.92
296.0728149	7.35
306.3479309	5.56
307.0382690	2.15
308.0012817	0.25
320.0210571	0.17
324.8356323	100.00
325.8908691	6.23
339.1371460	0.42
340.2223511	0.20
342.7554321	58.49
343.8192749	4.14
359.8148804	0.43
381.1473999	0.34
412.0690918	0.16
435.0595703	0.41
449.7919922	0.10
451.2576294	1.85
458.0198364	4.01
467.8576660	0.80
468.8767090	1.71
475.2651978	4.61
476.0895386	30.43
486.8341675	4.42
487.9815063	1.02
490.3034058	0.28
491.0237427	0.61
504.7924805	1.26
505.9685059	1.34
529.9494019	0.09
579.1643677	0.34
620.0473022	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	777.2296
Annotation	Unknow
Peak:m/z	Relative Intensity
245.4842987	0.11
289.1931763	0.08
305.2306519	0.10
317.2685547	0.09
321.2191162	2.83
335.0009155	0.04
339.1274109	1.94
343.2008057	0.07
349.0712891	0.12
361.0050659	0.06
381.2075806	2.02
401.0747681	0.07
421.3765259	0.05
423.0681763	0.07
423.8112183	0.02
426.5212402	0.08
433.2932129	0.02
435.2128906	0.11
437.4177246	0.09
449.1757202	0.34
453.1056519	1.42
491.2780151	0.44
493.3966064	0.03
495.2991333	1.00
507.2674561	1.26
509.3289795	0.03
513.2329102	3.17
515.1888428	0.12
517.0085449	0.11
523.0290527	0.30
525.2056274	2.02
533.1436768	0.10
535.3109131	0.59
541.3244019	0.12
543.3109741	0.18
549.1793213	0.23
551.2667236	0.21
553.4460449	0.04
555.2848511	0.65
567.2087402	7.92
571.2945557	0.07
579.2160034	0.09
585.2893066	18.73
603.3450317	1.08
608.6806641	0.03
611.2744751	0.09
613.2626343	0.32
623.0606079	0.06
627.2901001	1.89
639.3630981	0.80
645.3211060	37.74
657.2170410	2.29
657.8466187	0.05
667.3933716	1.07
669.2960205	0.02
675.3193970	0.73
681.1367798	0.17
685.1569214	0.08
687.3767090	2.50
699.2709351	52.60
717.2226562	100.00
717.9326172	0.83
729.1126099	0.14
732.6299438	0.12
735.3270874	1.76
745.2433472	0.36
759.3972168	0.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	483.1487
Annotation	Nocardicin B
Peak:m/z	Relative Intensity
149.1185455	0.54
161.0539856	0.09
162.1206512	0.16
166.9687195	0.27
177.0258942	0.45
191.2766418	0.15
192.8746033	0.31
196.0791931	0.21
200.8695526	0.32
202.9875183	0.21
213.0002136	0.23
215.1743317	0.20
219.0921326	0.10
227.9757843	0.08
229.2560272	0.12
230.9361877	0.11
235.2621460	0.19
239.7263794	0.78
241.0115051	0.35
247.0135193	0.13
257.0876160	0.13
264.2265930	0.23
271.0671387	0.15
279.1258850	0.31
285.0395813	6.37
288.9649353	0.11
295.4242249	0.05
303.0783691	8.11
313.1902161	0.24
321.2830811	1.04
330.1362305	0.34
334.1727600	0.66
342.0892334	0.30
345.2315369	0.05
346.2640381	0.65
349.2539978	0.62
353.7681580	0.28
356.5935669	0.20
359.2583008	0.83
362.9775391	0.61
365.3744202	0.20
379.2328491	0.60
399.3997803	0.66
408.3016357	0.22
409.1907043	0.53
411.6450500	0.13
428.3943481	0.11
429.2548523	0.61
431.2546692	0.07
437.3370361	0.16
439.3015137	0.95
441.5759583	0.76
442.1834412	0.10
445.7301941	0.06
447.1718140	1.19
455.4205627	0.24
464.9838257	100.00
465.6831360	0.57
466.4214478	0.37
468.5132446	0.44
473.5728149	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	609.182
Annotation	Butrin
Peak:m/z	Relative Intensity
172.9887085	0.06
174.1496582	0.17
174.8127594	0.03
178.9655762	0.01
184.8650055	0.09
187.1894836	0.17
188.3123169	0.03
197.0575256	0.02
198.0221558	0.02
199.0242004	1.23
200.0702667	0.16
201.0350800	0.89
202.0285339	0.02
203.2028046	0.02
211.1215210	0.04
213.0822144	0.20
214.3566589	0.17
214.9748840	0.41
216.1477356	0.05
217.0422516	0.22
222.9896240	0.08
224.0146179	0.09
225.2265015	0.07
225.9694977	0.04
227.0922546	0.78
229.1242676	0.08
230.0445557	0.06
233.0097656	0.10
239.1600342	0.25
240.2694397	0.50
241.1507263	0.42
242.1623840	1.54
255.4277191	0.08
257.0680542	0.56
258.1259460	0.55
259.1459961	0.12
268.1432495	0.20
274.0534058	0.02
283.1909790	0.75
284.1216431	0.20
285.2835693	0.41
286.1621399	1.85
292.2501831	0.02
299.0230713	0.85
301.0919800	100.00
302.0865479	0.03
307.2221680	0.14
310.1604614	0.03
314.9674377	0.09
325.1889038	1.29
341.3654175	0.01
343.1511230	0.50
355.1693115	0.03
367.1743164	0.13
369.3287354	0.04
395.4890747	0.02
415.1631470	0.05
419.7793579	0.01
429.1387939	0.13
443.2233276	0.05
444.2045898	0.05
447.4031982	0.13
465.2277222	0.06
469.1774292	0.04
479.5481567	0.05
489.1517334	0.37
519.1452026	0.03
551.5283813	0.03
562.9818726	0.16
564.1539917	0.01
565.4581909	0.06
573.3556519	0.04
581.8021851	0.07
591.3206177	0.17
594.4240723	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	298.15
Annotation	Unknow
Peak:m/z	Relative Intensity
95.9906769	0.10
98.8061447	0.09
100.7379761	0.18
115.9917221	0.09
118.8530807	3.50
120.0936203	0.15
123.8381805	0.04
126.8095016	0.08
128.0839386	0.08
129.3644409	0.11
134.8898621	0.31
135.9647522	0.18
138.9967651	0.49
141.0519562	0.07
144.8069611	0.62
147.0084839	0.05
148.5233612	0.11
151.9112854	0.06
157.9980469	0.08
162.3277130	0.79
162.9724426	2.60
166.2589111	0.17
168.1499023	0.11
170.9752808	0.16
176.3393097	0.21
180.1429749	0.24
184.0435638	0.04
185.1051636	0.27
185.9588013	0.18
189.9743958	0.10
194.6377869	0.14
195.3321533	0.10
196.1258698	0.07
197.1233215	0.15
203.0794067	0.34
207.9581909	0.06
209.1258850	0.29
215.2062073	0.06
225.9711304	0.05
227.8955078	0.16
228.8017883	0.35
230.3480835	0.16
231.2454834	0.22
232.1709595	0.24
234.1913757	0.32
234.8468933	0.04
236.7560425	0.04
238.1956177	0.42
239.1469116	1.00
243.0055542	0.17
243.6295776	0.14
244.8982544	0.93
245.5633545	0.27
251.0172424	0.21
252.1009216	0.64
254.1213074	28.44
254.7557983	0.06
256.6300659	1.67
257.2474670	0.68
259.8847961	0.57
262.0700684	0.27
263.1221924	0.34
266.6217957	0.38
267.9725952	0.06
270.3205566	0.35
273.9452515	0.62
275.3718262	0.38
278.2480469	0.47
280.7766113	100.00
281.9297485	0.98
282.6731567	0.24
288.6414795	0.89
292.3913574	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	565.1549
Annotation	Unknow
Peak:m/z	Relative Intensity
266.9404297	0.04
271.0808716	0.47
283.2133789	0.13
295.0831909	0.15
309.2047729	0.11
313.1616211	5.59
314.2517700	0.03
324.9779663	0.02
337.1346436	1.46
349.2529297	0.03
351.1724854	0.08
356.2974854	0.02
361.3887939	0.04
367.1432495	3.80
379.1858521	1.21
397.1108398	1.96
402.7655640	0.06
403.4568481	0.01
415.1224976	14.20
415.9877319	0.07
417.1791992	0.11
426.9608154	0.04
433.0892944	100.00
434.1500244	0.25
445.0853271	1.27
445.6907959	0.02
483.3162231	0.02
487.1943970	0.03
493.2972412	0.02
499.2977295	0.02
511.5821533	0.02
529.1266479	0.05
547.1921387	1.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	441.1765
Annotation	8beta-Propionyloxy-10beta-hydroxyhirsutinolide-13-O-acetate
Peak:m/z	Relative Intensity
124.5331726	0.21
130.5014954	0.18
131.1198120	0.69
133.0094299	0.17
137.1123657	0.74
138.9890594	10.09
143.0125580	2.49
147.0126343	0.25
148.9724121	0.17
151.0181885	0.73
156.8209686	0.08
158.8897705	0.99
160.9456329	11.21
162.0575256	0.19
163.1387329	0.21
168.8892975	1.56
173.1295166	0.25
177.1014709	0.24
179.0371552	5.23
182.9233093	0.57
187.0217285	1.15
189.1186981	0.21
190.1279907	0.09
195.9375458	0.25
197.1045685	0.21
199.0116882	0.44
201.0404663	1.02
202.2426147	0.29
204.4333344	0.31
205.1287537	5.66
216.0836182	0.11
217.1431732	3.80
235.1002502	9.21
238.5848999	0.17
241.3364258	0.11
249.2312927	0.07
260.3589783	0.30
261.1023254	1.02
277.1640320	0.11
279.0808105	1.73
294.1425781	0.09
298.3506470	0.19
303.3046875	0.17
327.4046936	0.27
330.1906128	100.00
331.2466431	39.12
339.4666138	0.26
355.2592468	0.10
367.4381409	0.07
379.2625427	2.78
381.0108948	0.09
382.3038025	0.08
395.3144226	0.36
397.2609558	40.11
423.2829895	5.16
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	805.3305
Annotation	Unknow
Peak:m/z	Relative Intensity
447.3561401	0.12
501.6671753	0.14
514.4078979	0.05
515.2695923	0.03
557.4473267	0.35
558.5808716	0.29
560.5448608	0.04
630.4771118	0.04
674.3609009	0.13
681.1716919	0.14
744.5473022	0.19
745.8568726	0.24
759.5292358	0.51
762.2789917	100.00
762.9264526	0.34
763.9849243	0.23
788.1789551	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	382.206
Annotation	Unknow
Peak:m/z	Relative Intensity
110.0314102	0.05
115.9827728	0.56
126.9696655	0.20
131.9863892	100.00
139.0184021	0.11
142.6914062	0.23
144.7166748	0.08
147.1296997	0.11
163.0607605	0.17
171.9842834	0.27
174.9147339	0.08
180.9118500	0.16
185.9698029	0.17
189.8361969	0.05
200.0079041	0.07
201.9440002	1.02
210.0588531	0.54
214.9167328	0.30
216.0864868	0.40
217.9189758	0.18
220.1534119	1.77
221.1223145	0.11
226.1173706	0.15
229.4407349	0.16
230.0864868	0.86
232.8677063	0.13
234.1969910	0.24
235.0640869	0.20
241.8307190	0.70
242.4668884	0.05
245.0977478	0.08
248.8753357	0.16
250.7337646	1.02
251.3686218	0.54
252.6291809	0.22
254.0635681	0.93
257.9277649	0.06
259.9208679	0.30
261.9020691	3.73
263.9192505	0.20
265.8400574	0.80
282.7250671	0.33
286.0618286	0.59
288.8111572	0.23
289.6806335	0.05
292.0189514	2.93
293.8359375	0.17
300.6440125	0.35
307.0371704	0.07
308.1181030	0.16
310.0219116	0.15
318.0289307	0.29
320.1963501	0.27
322.0959473	0.16
328.2472229	0.19
332.1876221	0.18
334.0241089	0.25
336.0504456	0.38
338.1399841	0.46
346.2160339	0.98
346.8305054	0.27
349.9941711	0.52
354.2840881	0.09
364.1938171	3.68
365.2111511	0.39
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	711.2868
Annotation	Nomilinic acid 17-glucoside
Peak:m/z	Relative Intensity
199.1634674	0.03
219.3921356	0.03
229.2796173	0.06
243.3515930	0.11
247.3246613	0.22
259.2285156	0.30
263.1730347	0.13
271.1752625	0.03
275.3254395	0.03
295.1532593	0.12
297.1966553	0.03
303.4604492	0.03
305.1908569	0.18
307.2398682	0.04
311.0986328	0.03
315.2006836	0.13
319.3938599	0.07
321.3414917	0.15
329.3583984	0.04
331.4183960	0.14
345.3184814	0.39
348.6018066	0.05
349.4553223	0.22
351.1716919	0.05
355.0323792	0.10
363.2161865	0.12
365.3101196	0.23
367.3348389	0.05
373.3786621	0.12
379.1287231	0.07
381.5927124	0.15
387.3629150	0.37
389.3023682	0.37
391.1666870	0.54
393.1038818	0.47
401.3059692	0.25
413.5173340	0.07
417.2770996	0.04
419.3764648	0.11
421.1874390	0.02
427.3386230	0.06
429.4239502	0.03
431.3429565	0.13
434.1846313	0.07
435.2471313	0.05
445.1647339	3.57
447.3314819	0.16
455.4633179	0.05
459.3355713	0.47
461.2786865	0.07
465.1792603	0.23
469.3151245	0.80
471.2287598	3.57
475.3750610	0.05
487.2904663	0.52
489.2722168	12.83
497.4508057	0.12
499.3832397	0.06
504.2320557	0.14
507.1827393	0.18
511.4313354	0.08
513.2052612	0.17
523.0675659	0.04
531.2378540	10.74
531.8640137	0.07
537.4896851	0.08
543.3729858	0.16
549.2895508	12.32
561.3547974	11.21
563.1751099	0.09
574.5990601	0.10
585.1170044	0.03
586.5342407	0.06
589.4187622	0.02
591.3278809	57.54
603.4962158	0.07
607.3411255	5.98
609.4290161	0.04
615.1332397	0.20
621.3663330	3.97
633.2742310	1.32
646.3054810	0.03
651.2175903	100.00
651.9542847	0.31
665.2918091	0.05
666.3482056	0.36
667.2500610	0.68
669.4199829	0.54
674.7684937	0.09
681.2872925	0.17
693.4097290	0.75
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	417.0826
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
120.9264755	1.17
128.9027710	10.93
143.1348572	0.06
155.1629791	0.27
159.1036987	0.13
161.1096802	0.82
172.9478302	19.83
189.0160980	5.31
233.2395325	0.84
251.1046143	14.62
259.0678101	0.48
277.0016479	4.63
295.0207214	100.00
355.4330750	0.17
374.5208435	0.04
398.9648132	1.52
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	271.0957
Annotation	Isoimperatorin
Peak:m/z	Relative Intensity
78.05947113	0.01
80.96492004	0.07
97.10050201	0.03
109.8605652	0.06
112.9339294	0.01
124.1867676	0.04
126.1518402	0.08
128.0471497	0.04
143.0786133	0.04
144.2804108	0.08
146.0350037	0.03
147.0175629	0.04
152.9395294	0.08
158.0645294	0.10
182.9219818	0.02
190.0092621	0.04
192.3992157	0.05
194.265625	0.10
203.0307465	50.85
203.9942017	100.00
206.0584564	0.04
210.975647	0.06
212.0071564	0.08
215.9616547	0.05
223.0892639	0.07
224.1778717	0.07
226.1174164	0.24
227.1354218	0.04
229.3755035	0.05
230.0292358	0.26
230.9586945	0.04
236.5155029	0.03
241.1349335	0.03
244.0993652	0.19
249.1010895	0.03
254.2055054	1.18
255.0204926	0.11
256.5375977	0.02
257.2256775	0.12
270.3044434	0.08
272.0949097	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	556.2042
Annotation	Tiapamil
Peak:m/z	Relative Intensity
161.1518555	0.07
162.1421814	0.12
163.1741180	0.12
164.0842590	0.06
165.0410156	0.16
166.6456146	0.14
167.3778687	0.02
169.0408325	0.87
171.1866150	0.16
172.1061707	0.72
173.9790039	2.39
175.1312866	0.03
181.7947540	0.03
183.0488281	1.06
184.5237427	0.16
186.0202637	6.81
187.1606598	0.13
190.0386047	0.10
190.9273987	0.16
198.0457916	0.95
199.1146240	0.13
200.9837189	6.31
208.1231079	2.21
209.4036407	0.20
211.2413788	0.04
212.0156555	0.33
212.8167114	0.16
214.2598267	0.07
216.0169220	0.59
226.1337433	2.43
227.3005219	0.06
231.2686462	0.02
236.0758667	0.05
236.8397980	0.06
242.2102661	0.43
244.4723816	0.15
248.3242188	0.07
254.1597443	13.30
255.1496887	0.59
257.3103333	0.08
258.9485474	0.15
260.8638916	0.09
268.0674438	0.22
272.1229858	55.31
273.1500854	4.80
274.3627930	0.03
276.3041687	0.10
290.1818848	100.00
291.3015747	0.14
300.0050659	0.04
301.0166931	0.12
304.1102905	0.12
306.7208862	0.20
308.1488037	11.45
309.4105835	0.13
313.3016357	0.13
315.4415283	0.08
316.1852417	0.19
327.2401123	0.15
328.0104980	0.10
330.9402466	0.05
332.2176514	0.46
333.8272095	0.16
336.0912476	0.05
339.1296387	0.10
342.2519531	0.29
345.1060181	0.17
350.2484131	0.40
352.2386475	0.16
361.7706909	0.15
363.2443848	0.03
365.1380615	0.04
370.1116333	0.71
373.2738647	0.13
374.1058960	0.05
375.3837891	0.03
376.3341675	0.23
380.2154541	0.04
381.1160889	0.09
393.3226929	0.07
394.3287964	0.19
395.3813477	0.19
398.0428467	0.22
399.1165771	0.07
410.1958618	0.04
412.0187988	0.41
424.0853882	0.25
430.1001587	0.51
431.2062988	0.18
432.8225098	0.20
434.9597778	0.42
436.2664795	0.13
440.6213989	0.09
444.9739380	0.03
452.4969482	0.15
454.0454712	0.26
458.3638306	0.23
459.2708740	0.17
466.7707520	0.05
467.4901123	0.17
468.2755127	0.10
470.0609741	3.52
473.0540771	0.15
475.1806030	0.40
476.1310425	0.45
484.2597046	2.46
494.0759277	0.15
502.0761108	2.16
503.0479736	0.23
510.1425171	0.04
511.5020142	0.32
512.2847900	0.17
520.1370850	6.95
520.7770386	0.09
538.2421265	14.22
539.2122803	0.04
545.1270752	0.53
546.6922607	0.37
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	353.1694
Annotation	Unknow
Peak:m/z	Relative Intensity
105.0841827	0.04
114.7264175	0.15
115.9194336	0.03
117.0875092	0.13
119.8961639	0.18
122.9363708	0.05
129.8728333	0.04
131.0364685	0.05
131.9260559	0.47
132.9985657	0.11
134.0174561	0.92
142.9667969	0.02
144.1375580	0.13
144.9317017	0.17
146.0098267	0.31
148.0411682	10.76
158.1487274	0.04
159.9442749	47.57
172.0611572	0.53
172.9618988	0.07
174.2708740	0.05
176.0750732	0.53
184.0213623	0.20
185.9260559	0.05
188.0075836	0.17
188.9709473	0.10
191.0324707	60.26
194.0827637	0.25
196.3716125	0.09
198.1757507	0.10
200.0401764	0.21
201.1796265	0.14
202.0440674	0.44
203.1434174	0.70
204.9658051	0.09
206.0688019	0.34
212.0817871	0.18
214.1622009	0.36
215.1253662	0.21
224.2252808	0.17
225.9373474	0.07
228.0280457	0.06
229.0765686	0.06
232.8786316	1.10
233.4905701	0.21
234.9753418	0.24
237.6779785	0.07
240.0264587	0.04
244.0766296	0.17
245.0438232	0.10
248.0664673	0.12
250.3753052	0.05
256.0163574	1.21
257.0656128	0.05
260.0933228	0.27
260.9431152	0.12
262.8630676	1.53
268.0198059	0.42
270.2777100	0.11
272.2109985	0.27
274.2103271	0.78
276.9852905	0.19
278.1597900	0.16
281.1676331	0.43
286.1416931	0.35
287.1560059	0.25
288.2636108	0.20
292.1484375	1.70
292.9462585	1.37
296.1220398	0.72
299.0585327	0.09
299.8713989	0.14
304.4423218	0.31
305.1062927	0.08
307.2713623	0.03
310.2438660	48.30
312.2023621	0.14
317.0978394	0.58
320.8874512	0.13
322.0953674	100.00
323.3717957	0.19
324.2903442	0.11
333.1349182	0.10
335.0370178	3.00
336.2221069	0.06
353.1561279	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	793.2001
Annotation	Unknow
Peak:m/z	Relative Intensity
230.8437958	0.07
233.2135162	0.03
240.4493561	0.04
251.2552490	0.07
279.7755127	0.12
291.0620728	0.09
291.7986145	0.05
293.1830444	0.06
307.2154236	0.03
309.1105652	0.09
315.5242920	0.19
316.6419983	0.16
320.7749023	0.06
335.1198730	0.03
343.0516968	0.06
350.9785156	0.07
357.3192749	0.21
359.4651794	0.07
373.9916992	0.09
381.2732544	0.15
385.0299683	0.04
390.3729248	0.15
405.2157593	0.07
409.1535034	0.31
421.5880737	0.04
425.1424561	0.04
428.4479370	0.22
431.2066040	0.08
440.0412598	0.10
443.6795044	0.05
447.4396362	0.07
450.8911133	0.02
453.1881104	0.46
459.1247559	0.08
462.4862671	0.06
467.1294556	0.12
475.4736328	0.03
481.2166748	0.10
484.1041870	0.13
489.0140991	0.22
491.0244751	0.05
493.2024536	0.11
494.9981689	0.16
497.0413818	0.17
497.8884888	0.03
499.1331787	0.31
515.0897217	0.14
516.2369385	0.07
519.5974731	0.08
521.5890503	0.11
522.3043213	0.18
525.4436035	0.08
531.1770020	0.03
532.7181396	0.15
535.2786865	0.61
536.8507690	0.05
538.5849609	0.09
545.8850708	0.26
548.4408569	0.12
549.3544312	0.15
552.6549683	0.06
555.0632935	0.05
557.1292725	0.07
562.6498413	0.04
569.1643677	0.19
571.1967773	0.40
574.9265747	0.05
583.4996338	0.58
585.1524048	1.23
587.5413818	0.05
589.4938354	0.03
591.5526733	0.19
593.7868042	0.07
599.4933472	0.14
600.9924316	0.19
602.3972778	0.28
603.2777710	0.08
606.6242676	0.09
608.2519531	0.15
609.3117065	0.13
610.6357422	0.19
611.3965454	0.21
615.2913818	0.63
619.3972778	0.20
621.9227905	0.25
627.1151733	0.44
628.9326782	1.26
630.8849487	0.79
632.3417969	0.04
637.3994141	0.16
639.3021240	0.22
640.8890991	0.10
642.5374756	0.08
643.2055664	0.91
644.1918945	0.21
645.3237915	0.40
646.9110718	0.05
647.8159180	0.09
650.5404663	0.11
651.2656250	0.33
653.5437622	0.19
654.9963989	0.37
657.0607300	0.09
658.0264282	0.07
659.3978882	0.11
661.3282471	0.44
661.9291992	0.03
663.1086426	0.27
665.1195679	0.19
666.8195190	0.11
668.3632202	0.25
670.8375854	0.14
671.9847412	0.11
673.0907593	0.49
674.1502075	0.03
675.1333618	0.16
675.8426514	0.12
678.9469604	0.24
681.5620728	0.11
682.2283936	0.26
683.1384888	0.34
685.1476440	0.06
686.4888306	0.08
687.2288208	0.12
688.2681274	1.29
689.3630981	0.63
690.7098999	0.15
691.7303467	0.05
693.9537354	0.30
694.5635376	0.04
695.2927856	0.04
697.1622925	0.34
699.0419312	0.35
701.0147705	3.75
703.3238525	100.00
705.2119751	6.99
705.9042358	0.50
706.7963257	0.54
707.7747803	0.22
708.9065552	0.25
710.5870972	0.22
712.8360596	0.18
713.7062378	0.04
715.1700439	0.03
717.3359375	0.24
717.9491577	0.14
718.7646484	0.66
719.8623047	1.16
721.3959351	0.14
722.5029907	0.25
724.8967896	0.20
727.1052856	0.16
728.2583618	0.30
729.1340942	0.53
731.5177612	0.17
732.4121094	0.52
733.1647949	0.21
734.2075195	4.49
736.2263794	0.27
738.5769653	0.18
740.0523071	0.18
741.4566650	0.04
742.9701538	0.07
745.0465698	0.17
745.9819946	0.99
747.0861816	27.39
749.1616211	67.73
750.0280151	0.49
750.8080444	0.21
752.3426514	0.04
753.7705688	0.06
760.8165894	2.14
761.9966431	0.25
762.7720947	0.13
764.1067505	0.38
765.2164917	0.42
766.1696777	0.23
766.9388428	0.10
769.6753540	1.22
770.3538818	1.34
771.1080933	0.64
773.5041504	0.21
774.8920288	2.41
775.8041382	0.60
776.5410767	0.37
777.8247070	0.07
779.2855835	0.25
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	583.2031
Annotation	Sylvestroside IV
Peak:m/z	Relative Intensity
165.0548096	1.56
179.1548920	3.59
195.0644989	12.80
207.0418701	0.02
280.2296753	0.02
299.3683167	0.10
303.0462646	0.03
316.6120605	0.04
327.2025146	9.25
333.1042480	0.17
343.3546753	0.07
369.1056519	0.06
375.0400391	100.00
375.6783447	0.38
377.2985840	0.04
391.2472534	0.11
416.9165039	0.25
420.2225342	0.69
421.2800293	0.76
427.4844971	0.05
436.0299072	0.16
439.1869507	0.25
458.9035034	0.99
459.5075684	0.20
460.9414673	0.03
467.4887695	0.08
485.3625488	0.11
493.1166992	0.14
495.1544800	0.05
495.7996826	0.04
497.1785889	0.13
507.2771606	0.07
520.1081543	0.09
521.4227905	0.09
522.9782715	0.07
536.3986206	11.36
537.0214844	43.46
539.5861206	0.05
547.0413208	0.08
565.4694214	0.22
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	469.2079
Annotation	Unknow
Peak:m/z	Relative Intensity
143.0213776	0.15
144.7141266	0.07
168.9955444	0.17
175.2446899	0.09
176.6973114	0.20
180.8977356	0.15
199.7079468	0.43
201.2181396	3.36
203.1575623	1.26
219.4257965	0.03
220.8038330	0.76
221.9297485	0.09
222.9714050	0.16
226.9661407	0.10
228.9353485	0.51
243.2781677	0.31
245.1611328	1.53
247.1546021	1.62
263.1926880	40.20
265.1695557	0.11
271.1103210	0.13
275.0854797	0.50
287.3931885	0.21
289.1445312	1.69
295.2279053	0.14
303.2868652	0.27
305.1301880	0.75
307.1109619	100.00
311.0899048	0.08
313.1943359	0.27
327.2973022	0.15
337.3299561	0.03
340.9767151	0.17
343.2269287	0.12
349.1710205	1.27
351.2362671	0.25
355.4049988	0.11
361.4840393	0.10
365.1954346	0.09
371.3028259	0.10
378.6175537	0.98
379.2836304	0.25
383.1475525	1.13
386.5095520	0.22
406.8443909	0.25
409.1395264	2.18
409.7641907	0.18
423.1420593	0.10
425.1229553	0.62
433.2455750	0.14
437.1634827	0.18
451.5007629	0.17
454.1434021	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.138
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
145.0431061	0.19
146.8984375	0.27
149.0563202	0.03
152.9689636	0.04
168.1305695	0.10
172.2200928	0.08
178.6843414	0.16
180.2384644	0.04
187.3784180	0.08
195.1228943	0.20
204.2256470	0.02
216.4370117	0.04
220.8745422	0.48
270.3606262	0.06
271.8724670	0.05
278.9251404	0.06
285.9578247	0.04
287.3117676	0.08
289.0828857	0.28
293.3598633	0.19
297.1749573	0.61
298.0963135	0.66
301.1612244	1.23
302.0690613	2.86
303.0782776	22.20
304.0889282	100.00
305.3792725	0.07
314.1983032	0.04
315.2471313	0.09
316.0980225	0.20
320.4516296	0.03
325.2409363	0.11
326.0362549	0.02
327.2062073	0.11
328.2236938	0.47
345.0191040	1.01
346.1180420	4.69
352.3726501	0.04
361.7379761	0.02
365.8754272	0.03
366.8486633	0.06
368.3961182	0.10
369.1705933	0.39
370.2370300	1.96
376.3334656	0.07
377.1273804	0.06
380.0890808	0.19
382.1002197	0.21
385.3840942	0.08
394.0743713	0.03
399.5205688	1.13
400.1892395	3.21
402.2940063	0.24
408.1286316	0.06
412.0735779	4.74
413.3019714	0.02
423.6291199	0.04
425.0865173	0.03
428.1119385	0.15
430.0101318	4.29
431.1531677	0.06
434.0779419	0.07
436.3161316	0.04
446.2183228	0.08
448.0391235	25.52
448.7575989	0.04
450.4894104	0.07
451.5346069	0.31
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.1558
Annotation	Rhoifolin
Peak:m/z	Relative Intensity
168.7844391	0.02
180.0263367	0.03
181.1684265	0.04
182.1564484	0.02
183.0486145	0.02
194.9792328	0.07
196.0608521	0.06
197.3060455	0.13
201.0391235	0.05
210.0769043	0.05
224.168808	0.05
225.4044952	0.12
227.0895386	0.15
239.9099121	0.04
269.0509033	100.00
311.1455688	0.39
335.2919312	0.07
353.2716675	0.02
413.0862427	0.05
430.921936	0.04
432.1963501	0.02
433.4421997	0.01
451.244873	0.02
531.1724243	0.03
532.9780884	0.02
559.2373047	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	319.1853
Annotation	Valerylglycine
Peak:m/z	Relative Intensity
101.9556046	0.01
109.0321426	0.01
127.2572784	0.01
139.0188599	0.02
142.0423279	0.07
146.9230957	0.01
157.0151062	0.01
160.0424805	100.00
174.1701050	0.21
213.1393738	0.02
275.5306091	0.01
283.0893555	0.00
291.0219727	0.01
300.5894470	0.01
301.2124023	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	473.2159
Annotation	Terretonin A
Peak:m/z	Relative Intensity
135.0980835	0.25
137.0081635	0.06
140.8954315	0.09
144.9015198	0.29
147.0997467	1.54
149.1667175	0.44
150.9973907	0.09
152.8794556	0.05
157.1441193	0.81
160.9060974	5.89
163.0442505	2.97
167.0293579	0.62
168.8810577	1.12
170.0975189	0.29
170.9990692	0.69
172.0111694	0.35
173.0723572	0.56
174.9716339	1.74
177.0467529	1.17
179.0492706	1.08
180.9891968	0.17
183.0936432	0.12
184.9426422	0.99
186.0122681	0.22
187.1481323	6.12
189.1581726	1.31
191.1042938	0.41
193.3263702	0.70
195.0114746	0.45
197.1321411	0.55
199.1233215	0.47
201.0814514	1.59
203.0656738	1.45
205.0685425	0.23
207.0517578	3.01
209.1723938	0.29
211.1107483	0.98
212.1745605	0.06
213.1537018	1.96
215.0999298	1.51
219.2048035	0.39
220.9316406	0.16
223.3548279	0.11
225.1713562	1.25
227.1481171	0.82
229.2110291	0.28
231.0424957	3.71
233.1394043	0.40
235.0976562	0.80
237.0236206	0.62
239.0673828	0.81
241.0458984	1.82
242.7058105	0.29
243.3756104	0.80
244.9273987	1.20
245.5764160	0.06
247.0277710	0.82
247.8891144	0.24
249.3968201	0.07
251.0870972	1.49
253.1604614	0.86
255.2754822	0.79
257.0471497	0.69
259.0755310	0.66
261.2365417	0.76
263.1052856	1.14
265.1732178	2.04
267.1133423	4.01
267.7594910	0.03
269.0448914	0.47
271.1058655	1.53
275.1026917	0.78
277.0627441	1.14
279.2239075	1.51
281.2122192	1.39
283.2467346	2.28
285.1474915	1.90
289.2320251	1.22
291.3554688	0.61
292.0991211	0.35
293.0752258	1.42
295.1864014	1.84
297.0694580	0.49
298.9299927	0.58
301.1676636	0.39
303.0620728	0.88
305.0633545	0.30
307.1321106	1.28
309.1240234	1.97
311.0659180	2.61
313.0360718	0.75
315.2599487	0.79
317.1834717	1.26
318.3543091	0.10
319.2207947	0.78
320.6794739	0.17
321.2973938	1.39
323.2456665	2.90
325.1730957	1.43
326.9092407	0.38
327.5112915	0.30
329.1544189	0.95
331.2330322	1.37
333.1047363	1.37
334.4019165	0.79
335.2367249	3.99
337.2306519	2.24
338.5428467	0.20
339.1931763	3.56
341.3397217	8.76
342.0935059	0.24
343.1723633	0.76
345.4674988	0.28
347.2293091	1.85
349.2277222	3.92
350.0367432	0.27
351.2024536	5.55
353.3545227	0.83
355.2224121	1.63
357.1925964	1.44
358.4240112	0.14
359.2346191	0.89
361.3804626	1.11
363.2521362	0.24
365.2174072	1.12
366.6531982	0.18
367.2892151	11.95
369.2403564	45.11
371.0123291	0.38
371.7639465	0.29
373.2524719	0.92
375.2464600	1.67
377.3344421	3.75
379.1534119	0.41
381.2356873	2.53
383.2436523	1.08
383.8793030	0.06
385.2000427	5.93
387.2130737	2.90
389.3395081	0.57
391.1524048	3.90
393.2622681	7.18
395.1097107	4.51
397.1576233	0.62
399.0818176	1.26
399.6947327	0.43
401.1997986	0.21
403.3681030	0.08
405.2258606	3.93
407.3047791	0.24
409.2646790	9.39
411.1630859	23.97
413.1213379	27.96
415.3500061	0.53
419.1852417	3.68
425.0744629	0.05
427.1543884	100.00
427.7789001	1.05
429.3042908	19.28
437.2833862	27.28
441.0470581	0.11
442.8910828	0.25
445.0207520	4.41
454.5315857	1.96
455.2625732	41.53
473.2659607	0.15
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	191.02
Annotation	Diketogulonic acid
Peak:m/z	Relative Intensity
57.0680733	0.05
60.9033356	0.05
84.9663696	0.61
86.9915085	0.89
92.9508514	0.20
110.8876495	100.00
127.2145081	0.10
129.0058289	2.07
131.0093689	0.71
146.9553375	0.18
153.0239716	0.11
155.0399475	0.47
170.2509766	0.01
172.9991302	20.56
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	1303.5398
Annotation	1beta-Hydroxybaccatin I
Peak:m/z	Relative Intensity
385.1423950	0.07
395.3062439	0.05
403.1412354	0.05
425.1621094	0.05
426.9108276	0.06
441.3953247	0.11
487.2954102	0.11
489.1334229	0.19
507.0881348	0.10
521.0709229	0.07
535.4349365	0.09
547.4470215	0.33
565.2828369	0.33
573.0842285	0.11
591.3801270	0.52
607.2033691	0.15
609.4576416	0.04
651.2735596	100.00
652.0880127	0.04
653.2509766	0.10
794.5199585	0.06
845.1723633	0.07
977.1552734	0.06
1141.3489990	0.38
1159.4050290	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	577.16
Annotation	RHOIFOLIN
Peak:m/z	Relative Intensity
199.0737915	0.52
225.0851746	1.92
255.5001068	0.24
268.0521851	0.30
269.0537109	100.00
270.1092224	0.31
330.180603	0.59
339.4501953	3.77
356.4812012	0.46
361.2544556	0.52
373.2333374	0.66
392.6542969	0.40
399.3985596	0.19
413.2979126	0.72
427.0391846	0.42
433.0541382	0.82
493.1104736	0.16
497.2940674	0.36
501.2147827	0.72
504.9611206	0.18
509.1425781	0.24
510.0852661	0.74
531.3469238	1.21
533.1939087	0.35
533.7980347	0.48
539.4569702	0.24
541.427063	0.21
548.4295654	1.64
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	251.0712
Annotation	7-Hydroxy-3-Methylflavone
Peak:m/z	Relative Intensity
104.8335266	0.15
106.8713379	0.11
146.0508881	0.30
154.9738007	0.34
174.2662354	0.14
179.2215729	0.11
180.9394836	0.24
193.2277679	0.50
206.0618896	1.66
207.1611786	2.93
208.067276	2.27
209.0902557	0.73
222.1698151	2.96
223.0915375	5.60
224.1524658	1.56
236.3099213	0.18
251.0770111	100.00
252.0998993	17.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	349.23
Annotation	L-Arginine
Peak:m/z	Relative Intensity
109.2531967	0.02
111.8354492	0.03
116.0214539	0.43
130.0200348	0.24
133.2322845	0.02
157.0920715	0.75
157.9611816	0.32
175.0814972	100.00
175.8542480	0.01
187.1505127	0.04
193.9467163	0.07
195.2002411	0.06
195.9931183	0.02
203.0666199	0.03
213.1315613	0.26
217.0169983	0.08
228.1459045	0.03
228.9843140	0.08
232.0470581	0.03
234.9013977	0.43
244.0794983	0.01
249.1072998	0.02
253.0102844	0.03
261.3300171	0.01
262.0981140	0.02
264.7228088	0.27
266.9644165	0.02
273.0819702	0.09
281.0445557	1.44
281.8759766	0.04
289.1149902	0.10
296.8374023	0.09
303.0195618	0.28
304.1165466	0.16
305.1496887	0.08
308.0108032	0.05
312.8878174	0.03
331.2611694	0.13
332.0352173	0.18
332.8873901	0.02
334.2673340	0.01
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	593.2086
Annotation	Zizybeoside II
Peak:m/z	Relative Intensity
174.9689941	0.22
179.0756378	0.06
184.9754333	0.25
193.0855713	0.08
205.1886444	0.15
211.2068024	0.14
220.7907715	0.04
222.2267151	0.34
227.2167664	0.38
241.0822449	0.90
242.3621063	0.11
251.0219421	0.08
269.2161255	0.05
281.1920166	0.11
283.1911926	0.35
285.0858765	22.45
286.0745239	0.45
286.7456665	0.14
287.3494263	0.34
293.1825256	18.65
295.2231750	0.35
297.0084839	0.77
299.1836548	0.11
305.0236511	0.23
309.1724854	0.21
311.0632935	3.25
311.9841919	0.10
323.1869507	1.19
326.2722778	0.06
327.3399048	0.73
335.3795166	0.78
339.2142944	0.19
341.1855469	1.27
351.1958008	0.22
353.1736450	30.09
354.2297974	1.76
354.9971924	0.11
357.3449097	0.39
363.4083252	0.16
365.1264648	0.47
367.3671875	0.17
368.3858643	0.18
369.4017334	0.09
370.9619141	0.23
383.1355591	20.23
384.1344604	1.71
385.0477295	2.70
385.6805420	0.03
387.2768555	0.29
389.0139771	0.32
392.1209106	0.08
392.9586182	0.23
395.4147949	0.93
396.5924683	0.35
397.2354126	0.86
403.1500854	0.22
405.4301758	0.21
409.0986938	0.44
413.1837769	81.51
414.2333374	1.24
419.0518188	0.41
425.2842407	1.21
426.0940552	0.33
427.4111938	0.34
428.5507812	0.55
429.3515625	0.38
431.1439819	0.76
433.3302612	0.24
437.0053711	0.10
441.3617554	0.23
443.1967773	2.80
448.5412598	0.23
449.3991089	0.32
455.1119385	2.83
467.2399902	0.24
471.2426147	0.55
473.1234741	100.00
474.2263184	6.94
482.8784180	0.11
485.3242798	2.47
491.5781860	0.09
497.1934204	0.17
499.3361206	0.15
503.2114258	35.33
504.1944580	3.35
511.5486450	0.29
515.2378540	3.06
516.2565308	0.51
517.3256226	2.68
521.4971313	0.22
529.3716431	0.49
530.9431763	0.17
533.2261353	4.93
534.3237915	0.78
545.2019653	2.01
546.4387817	1.58
547.0631104	1.06
548.1498413	0.11
549.3453979	1.93
551.4097900	0.72
557.1768188	2.41
575.1873169	11.39
576.3310547	1.69
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	603.18
Annotation	Dahuribirin C
Peak:m/z	Relative Intensity
172.0243378	0.34
173.2581329	0.30
175.0425415	1.91
176.0233765	0.26
177.3380585	0.06
178.1719360	0.14
182.2814178	0.05
183.9608765	0.12
184.9853058	0.38
188.0535889	0.20
189.8558960	1.47
191.1865997	0.13
192.9570618	0.15
199.1575775	1.91
201.0043030	0.75
202.0363159	0.08
203.0895538	20.55
204.7779388	0.38
213.0776520	0.15
214.8773193	0.66
216.0054932	0.76
218.0365906	16.12
219.0779877	0.05
227.0583344	0.84
228.9716034	1.49
230.3650208	2.44
231.0960693	46.74
233.0791473	100.00
239.3971558	0.13
241.0991516	0.97
242.1825867	0.08
243.0707397	0.53
244.8837585	0.56
247.3679810	0.25
251.3232727	0.31
253.2300568	0.08
257.0280151	1.26
263.8294067	0.04
267.5026245	0.10
269.0758362	10.63
271.0546265	0.98
273.0238647	0.26
275.2789307	0.20
278.0487671	0.31
281.0616150	0.44
285.3773804	0.75
287.1247559	11.38
297.1250610	0.40
299.1091309	19.87
301.0488281	0.25
311.1070557	0.10
315.1484375	0.03
317.0990295	56.64
323.0440063	0.34
325.4073486	0.17
326.2428589	0.21
335.0148315	0.04
347.4962769	0.23
352.9685059	0.11
363.4342041	0.05
371.2838745	0.41
383.2337646	0.53
401.0388794	1.17
406.2175903	0.10
417.0166626	0.11
431.4684448	0.33
447.0460815	0.11
456.8914795	0.19
459.4207764	0.14
476.6296387	0.11
497.3419800	0.12
499.3213501	0.05
507.3877563	0.08
509.2760620	0.19
517.9352417	0.13
518.6848145	0.20
519.4825439	0.53
531.2315063	0.36
538.8151245	0.04
541.4944458	0.48
545.2534790	0.05
557.2822876	0.61
567.4492188	0.11
576.7401123	0.09
585.0476074	0.78
585.8335571	0.21
588.3369751	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	339.07
Annotation	2-O-Acetyl-trans-coutaric acid
Peak:m/z	Relative Intensity
103.1533661	0.03
109.0129929	0.09
109.9119415	0.02
113.0463562	0.04
116.9027786	0.10
119.0109100	3.22
123.0493317	0.03
127.0312958	0.08
131.0577698	0.05
134.9505615	0.07
137.2829590	0.07
141.0283508	0.05
145.1354370	0.07
146.9176941	100.00
149.0217896	0.05
156.8976440	0.06
159.2002869	0.24
164.9933472	0.06
174.1045380	0.03
176.0536194	0.04
177.0677490	1.29
178.9794922	0.04
181.0536194	0.02
182.9263153	0.04
193.1237335	0.03
199.1413727	0.04
200.9221191	0.03
203.9002228	0.16
205.2496033	0.08
207.1290283	0.15
217.0684509	0.10
225.1592407	0.04
235.0559082	0.02
240.1086731	0.04
243.0855103	0.03
246.0254517	0.12
246.8471985	0.04
248.2798462	0.25
252.1866760	0.03
257.0054626	0.03
261.1472168	0.17
264.3872681	0.02
270.2127686	0.07
277.0010986	0.03
279.8471680	0.04
282.9287415	0.02
285.0093994	0.05
290.5303650	0.17
291.2214355	0.04
293.1583252	0.52
294.1220703	0.16
295.5243835	0.03
296.4885559	0.05
297.2619019	0.08
298.0858459	0.08
300.0832520	0.13
302.9478149	0.49
303.8446350	0.06
306.9547729	0.15
308.9884338	0.14
311.0816040	2.19
319.1871643	0.29
321.1095886	6.25
322.0968628	0.05
323.1272583	0.04
338.2776184	0.02
339.2346802	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	399.1639
Annotation	Methyl (3x,10R)-dihydroxy-11-dodecene-6,8-diynoate 10-glucoside
Peak:m/z	Relative Intensity
117.8950882	0.37
121.0335541	0.83
123.0525894	0.10
126.9507141	33.45
129.0540009	0.65
130.9885864	1.29
133.0592651	22.09
134.9584351	4.63
136.7325134	0.36
144.9839478	24.75
147.0040741	3.44
148.9596558	0.31
150.9853210	50.79
151.5997620	0.34
157.0564270	1.26
158.9650879	5.53
161.0712433	1.61
163.2037048	2.27
167.2052460	1.00
170.9177246	0.57
173.0506897	1.04
175.0310974	1.98
176.9821014	2.22
178.9791260	0.88
182.8274078	2.74
185.1047058	0.18
187.0534973	1.13
190.2315216	0.35
191.1847229	0.62
192.4815979	1.02
193.1682587	0.96
197.0938873	0.48
198.1207581	0.35
201.1158295	1.35
205.0446777	0.90
207.0423889	2.62
209.3192596	1.58
212.1909943	1.17
212.8232880	8.22
213.5686646	2.31
217.0150757	3.64
219.1249390	0.66
221.0748749	1.14
222.8942261	0.24
230.9115295	100.00
233.3260803	1.08
235.2208557	0.44
237.2106628	0.76
239.3759766	0.53
240.9771118	2.57
248.9426575	43.11
254.7308960	0.61
257.1215820	0.61
259.0326843	2.15
267.3021240	0.51
273.3577881	0.20
277.1264648	1.33
282.0680237	1.34
287.4049683	0.25
289.2826538	0.48
292.2276611	0.60
293.1009216	0.19
295.2269897	32.95
301.2729797	0.63
302.2471619	0.54
307.1056519	0.27
308.9899902	0.42
313.2308655	35.73
324.9501648	0.86
327.2892456	0.68
328.9956665	0.48
337.1027832	20.03
339.3473511	0.41
341.3609924	0.83
343.1470337	2.81
345.0990601	2.17
352.5139160	0.20
353.2058411	0.14
355.1250305	4.48
363.2001648	25.84
371.0246277	1.12
381.1265869	39.39
382.4496765	0.19
390.2036438	1.23
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	449.1088
Annotation	Salvianolic acid D
Peak:m/z	Relative Intensity
134.8926392	0.09
149.0388641	0.22
150.9404755	1.66
166.9230957	0.24
221.2447052	0.18
223.2230682	0.09
269.0594482	0.33
287.0858154	100.00
287.7500000	0.26
288.3843384	0.16
297.1701965	0.45
305.1216736	0.04
311.2902527	0.31
323.0087891	0.14
327.0639954	0.25
328.9855652	0.48
349.2832642	0.11
359.2942505	0.33
371.0634766	0.43
389.4588318	0.12
395.3459778	0.06
403.1526489	0.07
407.3432922	0.06
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	721.2713
Annotation	Juncin I
Peak:m/z	Relative Intensity
249.3151398	0.06
252.8148041	0.11
260.9216614	0.11
267.0918579	0.29
277.4091492	0.12
279.3022766	0.06
283.3228149	0.07
297.1257324	0.20
299.4216919	0.18
305.3221436	0.09
306.8322144	0.04
307.5271606	0.11
325.1692505	0.25
343.1485596	0.05
369.4378052	0.47
409.2889404	0.20
425.0552979	0.13
427.5955811	0.23
441.4147339	0.08
451.1189575	0.16
469.2246094	0.35
471.2626343	100.00
485.4129028	2.31
488.4719238	0.20
489.2608643	0.04
495.2727051	10.21
496.9302368	0.40
497.7370605	0.12
507.2440796	0.13
509.3639526	0.15
513.1674805	15.66
514.1209106	0.31
523.5062866	0.07
525.3338013	2.93
527.5154419	0.08
537.1015015	0.05
539.6188354	0.12
542.7294312	1.79
543.3766479	0.93
555.1245728	0.28
556.7147827	0.15
559.3400879	0.10
560.8936157	0.45
567.0068359	0.46
572.8266602	2.36
575.2201538	0.09
577.2981567	0.30
579.3958130	0.12
583.2977295	0.36
585.3264771	0.27
596.7205200	0.34
602.9974365	0.49
604.7141113	0.10
613.1706543	0.04
614.6544189	0.90
615.2825317	3.39
618.8527222	0.13
635.1535034	0.09
657.2989502	0.06
660.8688354	0.06
674.8895874	5.49
675.5158691	0.05
677.1481934	0.10
682.4749146	0.12
689.2658691	0.13
693.0383301	0.17
698.1705933	0.10
702.2456665	0.17
703.3860474	0.38
707.0237427	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	562.2478
Annotation	Dracunculifoside Q
Peak:m/z	Relative Intensity
160.0221863	0.09
207.3723145	0.16
212.3417053	0.09
213.0367432	0.69
215.1063538	0.11
229.0912170	0.18
230.3463440	0.17
231.0252686	0.47
235.1290741	0.24
236.2200623	0.06
245.0541077	0.11
249.0546265	0.20
250.9072876	0.04
253.2206573	0.15
268.9476929	0.03
271.1397705	0.37
291.1064453	3.67
296.0972290	0.44
301.2112427	0.08
303.1905518	0.03
309.0501099	0.11
313.4216919	0.03
314.3084106	0.14
315.3249512	0.21
319.3115234	0.06
331.1641235	0.05
332.1651001	0.10
339.4462891	0.04
343.2438965	0.25
348.4131470	0.03
352.2062378	0.05
356.9481201	0.30
358.2522583	0.27
359.1412964	0.05
360.4433594	0.12
362.9390869	0.04
364.3619385	0.03
365.1602783	0.14
372.8786011	0.09
375.0764771	23.95
377.1588135	0.06
382.9920044	0.13
390.7040405	0.33
392.9881592	100.00
393.6771851	0.13
398.2344971	0.14
408.2882080	0.14
409.0281982	0.02
410.1737061	5.32
410.8404541	36.82
411.5076294	0.11
416.1078491	0.13
419.2213135	0.03
424.3217773	0.32
425.1865234	0.24
427.3024292	0.13
428.1302490	0.06
440.3478394	0.32
442.1941528	0.47
456.3245850	0.12
460.3025513	2.93
467.0360718	0.24
469.3012085	0.09
472.2585449	0.18
484.5018311	0.18
499.3892212	0.21
502.2683716	0.13
509.0046997	0.15
510.2100220	0.07
515.4932861	0.04
525.7656860	0.15
527.0952759	1.79
527.7608643	0.05
535.4348755	0.06
542.1441040	0.12
544.0917358	0.84
544.6930542	0.21
548.7156982	0.10
552.9934082	0.13
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.18
Annotation	Malvidin 3-(6''-acetylglucoside)-5-glucoside
Peak:m/z	Relative Intensity
196.9225311	0.04
202.8527527	0.39
212.3073120	0.27
213.3016663	0.68
221.3478088	0.05
222.4477234	0.16
223.0853271	0.12
230.1307526	0.03
234.2246704	0.14
235.2104492	0.12
236.1320953	0.06
243.2648315	0.10
250.9786682	0.04
269.3346863	0.05
271.4116821	0.06
274.1466370	0.26
278.3905945	0.09
279.3338928	0.05
281.2115479	0.07
289.3022766	0.50
291.8808594	0.28
301.1222534	0.05
307.9262085	0.15
309.2486572	0.38
310.5541382	0.08
313.2299805	0.32
314.4013977	0.04
316.2465515	0.31
317.2591248	0.36
324.3523560	0.08
327.0982056	0.08
328.1520386	0.24
328.9802246	0.14
331.2409973	1.92
332.1674805	0.05
333.0686035	0.11
336.2041931	0.09
337.6076660	0.16
338.4212646	0.18
342.2574463	0.16
343.3794861	0.14
344.3122559	0.08
345.1873169	0.04
347.1429443	0.19
350.3730469	0.05
351.4563599	0.06
354.3755493	0.40
359.0062256	1.47
360.1569214	1.19
367.1119385	0.21
368.1275024	0.34
369.4374390	0.09
372.1257324	0.04
374.1035156	13.65
375.1642456	2.82
376.8873901	0.14
379.0819092	0.14
382.0659790	0.10
383.3783569	0.35
384.2370605	0.10
385.0995483	0.03
386.8928223	0.26
387.5399780	0.06
389.0852051	100.00
390.3345947	0.09
395.2268677	0.78
396.3638306	0.56
397.2894897	0.60
401.3587646	1.86
402.3464355	1.20
403.1641235	0.57
404.1550293	0.14
408.2006226	0.43
419.9973145	0.06
423.1968384	0.15
424.6364136	0.36
426.2510986	0.26
427.5531006	0.67
428.2388306	0.61
429.4364624	0.07
432.4372559	0.15
436.3843384	0.56
437.4526978	0.09
441.1317139	0.31
445.0737915	0.39
446.0706787	0.49
447.4450073	0.73
456.4157104	0.04
465.5172729	0.16
472.0662842	0.34
472.9655151	0.36
480.3771973	0.20
488.3847046	0.83
489.3757324	0.58
490.1580811	1.03
491.2274170	0.12
506.2626953	0.29
507.6795654	0.71
508.3491821	0.06
512.3716431	0.20
513.0302734	0.10
515.2611694	0.15
519.3134766	0.04
530.3477173	0.25
531.1685791	0.13
532.1942749	0.04
533.2219849	0.27
537.2524414	4.34
538.5205688	0.04
540.8764648	0.37
545.2103882	0.08
546.2341919	0.19
547.3859253	0.12
548.2382202	0.33
549.6954956	0.69
551.1792603	69.71
554.2650146	0.05
562.4869995	0.09
565.1314697	0.74
566.2420044	3.03
567.3374023	1.57
572.6085815	0.12
575.3669434	0.26
577.2817993	0.15
577.9163208	0.07
579.3032227	4.06
588.6023560	0.28
589.3826904	1.16
590.3158569	1.85
591.4976196	1.22
593.2313232	80.08
593.8372803	0.22
603.0460815	0.10
605.0092773	0.21
606.4358521	0.08
607.2498779	0.48
608.3265381	0.85
609.4219360	0.43
610.4078979	0.32
617.1309204	0.20
619.2088013	2.23
621.3125610	0.19
624.1801147	0.04
633.2332153	20.94
634.3695679	6.54
635.4046631	2.94
636.6539917	0.06
643.9054565	0.22
645.1245728	2.11
645.7947388	0.08
648.4124146	0.07
649.6012573	0.12
650.5110474	1.06
651.3024292	1.88
652.3169556	0.13
656.1898193	0.08
658.6655273	0.08
659.3652344	0.17
663.2916870	0.97
674.9620972	0.03
676.3637695	0.27
677.4049072	0.61
680.0076294	0.35
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	289.07
Annotation	1,6-Dihydroxy-3,7-dimethoxyxanthone
Peak:m/z	Relative Intensity
88.9684143	0.13
90.8673553	0.09
92.8197327	0.02
95.0764923	0.15
106.9751816	0.11
110.9232712	0.80
114.9489899	0.06
116.9399338	1.03
122.9667740	0.66
126.9445801	0.46
134.8881836	0.65
136.9487152	2.89
138.9234619	0.08
143.0212402	0.03
144.9659729	5.22
151.0235291	1.10
152.9242554	45.64
154.1316833	0.06
156.7849731	0.02
159.1429443	0.02
160.9595795	1.51
162.9316406	100.00
164.0570831	0.81
167.0706177	0.34
171.0231323	0.41
176.9104004	0.06
178.9533844	35.14
179.9898376	0.37
183.0668640	0.05
185.0665741	0.38
186.9824371	4.16
200.9777527	0.14
203.0700073	0.04
204.9724731	3.41
206.1053162	0.07
207.2092590	0.06
215.1304626	0.05
220.7934875	0.17
223.1003723	0.10
225.0700684	0.14
229.0481262	1.35
230.1032715	0.10
241.1767273	0.08
242.8754883	0.26
243.4757996	0.04
247.0483093	4.25
247.9859619	0.12
253.0937500	4.21
254.2149658	0.03
261.2474365	0.03
271.0206299	20.06
272.0140686	0.53
272.6269226	0.02
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	379.08
Annotation	Didymocalyxin C
Peak:m/z	Relative Intensity
113.0725555	0.06
119.1193085	0.01
143.1146698	0.03
161.1097412	0.02
178.9153137	0.83
198.9779358	1.05
215.1181793	0.12
216.0125580	0.04
217.0202026	8.67
341.1573181	100.00
342.0388184	0.06
343.2465210	7.88
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	253.0852
Annotation	6-Methylflavonol
Peak:m/z	Relative Intensity
76.90570068	1.09
79.30781555	0.47
80.89390564	1.34
84.98153687	1.19
90.87002563	0.22
94.95547485	1.85
103.0948792	0.95
104.6197205	1.86
106.9477844	0.45
109.0185089	0.90
111.108139	0.37
112.9584351	0.30
115.1347351	0.79
119.021698	1.16
123.0008698	2.01
123.6942749	0.52
124.8776398	1.04
126.9073181	8.40
128.9234009	4.29
129.5658569	1.14
132.7681427	0.42
135.1015167	0.80
137.0604095	1.44
138.988739	1.02
147.1440582	3.31
149.2163849	1.59
150.874527	77.19
151.9742889	6.49
153.0819855	1.32
154.0108795	1.00
154.8952637	1.40
156.9706116	1.68
167.0505524	1.07
169.1765594	1.46
174.8652496	1.53
179.1296844	2.91
181.8502808	1.39
182.8764496	0.79
185.0763702	3.91
186.0813293	1.93
189.2511902	1.07
193.1444092	1.66
194.1963959	0.27
194.8730927	0.20
197.0662842	4.41
198.9903107	0.86
207.2407379	1.42
209.7796783	0.92
211.057785	2.59
217.1578827	5.36
221.0109863	1.70
225.1628418	11.90
226.3469238	0.55
235.1701813	23.67
236.2978668	0.88
238.1706085	13.61
239.2238312	0.96
251.1519318	0.32
253.0792236	100.00
254.22052	14.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	471.2361
Annotation	Subtrifloralactone L
Peak:m/z	Relative Intensity
147.0159302	0.29
149.0861511	0.07
155.1359406	0.14
157.0398560	0.22
158.9405212	0.15
161.0296631	1.22
162.9459076	0.78
165.2909546	0.09
169.0561829	0.12
171.1751709	0.22
173.0377045	0.20
175.1126404	0.33
177.0327148	0.58
181.1814270	0.44
184.9192200	0.27
187.0260925	0.67
188.2966919	0.21
189.1854858	0.08
190.8363647	0.06
192.9142761	0.07
199.1972656	0.89
201.1616516	1.07
202.1182098	0.11
206.9078369	0.24
209.1688385	0.11
211.3073120	0.17
213.1026306	0.31
214.4080048	0.27
219.1754761	0.23
221.1609192	0.39
223.3158417	0.07
225.1075745	0.21
227.0224609	0.09
228.2912445	0.07
228.9391327	0.07
230.9697571	0.22
232.3238373	0.24
233.1217804	0.29
235.1815796	0.42
237.3869629	0.59
239.3510590	0.52
240.9964447	0.22
243.3253479	0.30
244.9481354	0.76
246.4143982	0.26
247.4826660	0.08
249.1987305	0.18
250.8677673	0.27
253.2203369	0.47
255.3046875	0.48
259.2341309	0.32
260.9260864	0.22
263.4708557	0.31
267.1309204	0.48
268.4253235	0.13
269.4001770	0.09
271.2912903	0.37
272.4982910	0.15
274.6203613	0.35
277.2204590	0.12
279.2498169	0.36
282.9853210	0.29
284.9692078	0.37
287.1535950	0.81
289.1232910	0.62
290.3742981	0.29
291.0855408	0.28
293.5567017	0.26
294.2825623	0.10
295.0236511	0.80
297.4515991	0.30
298.7732544	0.08
300.2275696	0.05
301.0905457	0.31
303.1925659	0.12
305.2020264	0.87
307.1834106	0.61
309.0841064	0.80
309.7153015	0.15
311.0979004	1.17
312.9890442	0.94
315.3255615	0.36
317.3179626	0.55
321.3572388	0.49
323.1849976	0.69
324.3173523	0.04
325.3955078	1.63
327.0985107	0.08
331.2861938	0.45
333.3535156	0.97
334.5942688	0.28
335.2514648	0.78
337.3183899	0.12
339.1140442	1.13
341.3650513	1.69
343.3403625	0.87
349.2325439	0.72
351.0924683	1.62
352.1454468	0.23
353.3130188	0.53
355.0816956	0.80
357.2286682	0.63
358.9812927	0.16
361.6015625	0.61
363.1438293	0.59
365.3638916	0.68
366.6337585	0.30
367.2397461	1.05
369.2445679	34.44
370.2231445	0.74
371.4663696	1.49
372.9442444	0.21
377.2090759	0.72
379.3819275	0.23
381.1736755	0.64
383.3141785	2.14
384.2590027	0.16
385.1618652	2.82
387.3808899	0.84
391.2794495	0.49
393.4851685	2.14
395.1882324	1.99
397.1372070	0.29
399.2708435	0.70
401.2356567	2.85
409.2797546	5.73
411.1098022	20.38
411.7514343	0.05
413.1546936	12.79
413.8099365	0.11
414.5401917	0.08
417.2743835	0.10
419.0828857	1.73
424.7795715	0.14
427.2478333	100.00
429.2165527	16.62
430.4609985	0.20
431.5306702	0.25
436.3327332	0.22
437.2859802	7.76
439.8127441	0.13
445.1941833	0.54
455.1037903	24.72
455.9436340	0.18
473.4160767	0.18
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	485.1505
Annotation	Unknow
Peak:m/z	Relative Intensity
179.0828857	0.56
202.9717102	0.16
277.1233521	0.42
311.2439880	0.04
323.1831665	5.20
339.1580811	0.09
341.1515808	100.00
342.0534668	0.61
367.2217407	0.68
371.1805420	0.04
383.1452332	15.14
397.1569519	0.21
421.0572205	0.04
423.2646484	0.64
425.1802368	0.14
438.9572754	0.98
441.1587219	1.12
451.0346069	0.15
457.3833313	0.17
467.2119446	0.22
468.3078308	0.17
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	465.1379
Annotation	Petunidin 3-arabinoside
Peak:m/z	Relative Intensity
148.9580841	0.51
152.7383118	1.02
165.0217896	0.67
172.9205170	0.30
176.8683777	0.60
179.1376648	0.10
188.9937439	0.12
191.0730133	0.24
193.2075195	0.48
195.0445099	21.39
197.1991272	0.74
203.1122131	0.46
204.8867035	0.21
207.1456146	0.16
209.2809906	0.10
212.2341919	0.53
216.9796753	0.37
219.0627136	16.73
225.0592957	0.08
234.7261200	0.38
237.1008453	1.25
245.0829773	7.59
247.1528015	0.23
259.2238770	0.11
260.9848938	1.02
263.1035461	56.67
263.9713745	0.31
265.2463989	0.31
271.1047668	0.10
273.0911865	1.35
277.2708435	0.21
278.1394043	0.05
280.5246277	4.65
281.1375732	55.23
285.1173401	1.82
288.5216675	0.72
296.9331665	3.96
299.1388550	48.36
301.0366821	2.39
303.1589966	2.14
305.2466125	0.58
309.2677612	0.25
313.1746216	3.68
315.1061707	12.37
318.0434570	0.46
319.1674194	9.52
320.8309021	0.10
323.2179565	0.55
325.0535889	7.46
329.3938293	0.57
331.1313477	0.89
335.1929321	0.22
337.4714355	0.34
339.2015991	5.06
341.0341797	2.04
343.0264282	21.22
344.4041443	0.24
345.0983887	0.48
351.2886047	0.51
355.2388611	0.39
361.1015320	44.34
365.2957153	2.13
367.1251526	6.93
368.3526611	0.44
368.9855347	0.16
376.2993164	0.08
377.0341492	0.13
379.3399353	1.57
383.1499939	6.44
385.1683655	15.63
387.0354004	0.28
392.3190613	0.52
393.1098022	1.51
399.2214050	0.34
401.1277771	12.65
403.3147583	0.07
411.1649780	14.91
419.1614075	6.21
421.3002319	0.33
429.0199280	56.48
429.6261597	1.90
447.1461792	100.00
448.2028503	0.07
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	281.1396
Annotation	(+)-Cheimonophyllal
Peak:m/z	Relative Intensity
83.0243073	0.09
84.7628326	0.03
95.1250000	0.12
98.9598923	0.05
101.2789612	0.10
105.1621552	0.11
110.8458862	0.52
119.0125732	0.24
119.8096008	0.04
121.0839233	0.20
123.0755310	5.70
125.0697098	0.23
133.2153015	0.16
137.1351624	0.35
139.2020569	0.09
143.2293549	0.04
144.4976654	0.04
145.1441803	0.98
146.9109497	0.07
149.0070190	0.09
149.9215088	0.09
151.1228943	0.42
153.0956726	1.41
155.2135010	0.03
159.2695770	0.39
161.2507629	0.06
166.9637451	0.08
169.0151978	0.30
171.1964417	9.50
172.9305267	0.10
175.3002167	0.18
176.1483154	0.04
177.2514038	0.13
189.1508789	3.67
191.3540344	0.22
198.9214478	0.10
201.2160950	3.59
203.2247925	0.05
205.1380615	0.13
207.2197266	6.23
218.9940796	9.07
219.5959473	0.06
237.1557007	100.00
237.7583923	0.11
253.4521484	0.11
262.9999084	0.12
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	679.2947
Annotation	Hv-NCC-1
Peak:m/z	Relative Intensity
204.0541077	0.22
209.2718506	0.03
218.1175385	0.06
220.9231110	0.03
227.0769958	0.24
229.2265625	0.16
236.2543640	0.16
242.4057007	0.03
243.4694214	0.03
244.1131439	0.04
246.1203613	0.28
248.2039185	0.06
258.9472961	0.02
260.2532043	0.06
262.0420532	0.26
269.3503723	0.12
273.0759888	0.40
273.7974854	0.03
274.8450928	0.08
287.1353149	0.17
293.9127808	0.02
297.3281555	0.19
299.1210327	1.03
301.1810913	0.12
303.3001404	0.03
304.9790039	0.29
311.1412964	0.10
312.8436279	0.08
315.2741089	1.71
317.0872192	0.05
321.3261719	0.08
323.2252808	0.33
325.2349243	0.28
327.3779907	0.13
337.2279053	1.09
338.4974976	0.18
339.3331299	0.15
341.0866699	0.42
343.0130615	0.06
347.3859863	0.14
349.3709717	0.04
353.1071777	0.06
357.0335693	0.30
359.0973511	0.17
365.4484863	0.07
369.1868286	0.26
370.0667725	0.05
371.2570801	0.35
373.3371582	0.67
374.9642334	0.08
377.4547119	0.03
381.1008301	0.05
383.0899658	0.96
389.4376831	0.16
393.4998169	0.13
395.2810669	0.09
401.1460571	3.82
401.7595215	0.02
411.4498291	0.06
415.2097778	0.84
418.2487793	0.08
421.6738281	0.06
428.1674194	0.04
432.4880981	0.10
433.2116089	1.44
436.6133423	0.08
437.5227051	0.07
438.3248901	0.07
446.3777466	0.42
450.3665161	0.37
455.4397583	0.08
458.0186768	0.11
462.1215820	0.18
464.3162231	14.70
466.3816528	0.17
472.3643799	0.33
475.9810791	0.52
478.3642578	0.02
482.2006226	1.07
484.4164429	0.11
490.2062378	10.67
490.8684082	0.10
494.2951050	0.81
496.4699707	0.07
499.2238770	0.27
508.1002808	8.41
508.7613525	0.05
510.1937256	0.32
514.2315063	1.29
517.3431396	1.27
519.5245972	0.03
522.2023926	29.34
523.1887207	0.08
524.3490601	0.22
526.2933960	0.93
533.1771851	0.38
535.2949829	0.18
540.5601196	0.03
554.5152588	0.06
555.1976929	0.12
567.5137329	0.05
583.3931885	0.45
585.4492798	0.34
586.7903442	0.26
587.4096069	1.90
588.3185425	0.19
591.0664673	0.02
592.8856812	0.02
593.4999390	0.16
601.2982788	0.32
603.2252808	4.93
604.1548462	0.06
611.1862793	5.89
619.2109985	2.33
619.8427124	0.04
621.1625366	0.14
625.2584839	0.06
629.2549438	13.07
630.4786377	0.17
633.2210083	0.03
635.6436157	0.12
642.6570435	0.29
643.2968140	6.26
647.2429810	100.00
647.8663330	0.22
661.1329956	4.42
661.9696655	0.19
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	611.1572
Annotation	Isoorientin 6''-O-glucoside
Peak:m/z	Relative Intensity
260.2552185	0.08
328.9927368	0.07
341.2706909	0.02
371.1304932	0.39
395.1835327	0.44
407.1974487	0.18
419.1708984	0.08
425.0697021	0.82
425.6777954	0.03
431.2954102	0.84
437.2655640	0.50
443.2194824	0.27
449.3596802	0.16
455.2501221	0.63
461.1621704	0.52
473.1076660	39.12
473.7662964	0.22
479.2274170	0.04
486.9495239	0.01
491.0973511	11.94
491.7524414	0.02
497.2745361	3.54
509.1798706	0.19
515.2338257	4.88
521.1185913	0.11
521.7240601	0.02
527.2024536	14.39
539.2298584	6.85
543.1157837	0.03
545.1959839	15.23
557.1193848	8.82
557.9089966	0.04
575.2185669	31.98
591.0565186	0.04
593.1340942	100.00
594.1172485	0.03
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	695.2339
Annotation	Unknow
Peak:m/z	Relative Intensity
193.1108551	0.16
200.9813538	0.18
202.2448120	0.18
203.7944183	0.18
205.1296539	0.11
206.9691925	0.07
216.0365906	0.16
217.1953430	2.28
218.4991608	0.10
221.2292175	0.15
231.2911682	0.28
233.2536011	0.28
235.2264557	0.91
241.1877441	0.25
245.2091370	0.60
247.1013794	0.52
249.2037659	0.20
257.0451660	0.14
258.7611694	0.41
261.3415833	0.13
263.2545166	0.25
264.1760864	0.09
264.7769165	0.22
267.2117004	0.07
268.1914062	0.22
275.1362915	0.06
276.1007690	0.05
277.1915894	0.93
278.1472778	0.33
278.7803650	0.26
280.4364319	0.20
281.1950684	0.20
287.2927246	0.29
291.0211182	0.31
291.8905640	0.09
292.9675293	0.09
294.3769226	0.14
295.0863647	0.20
296.2889709	0.28
297.1391296	1.18
305.3411255	0.15
307.0042725	0.42
308.4536133	0.60
309.2750244	2.65
310.0416870	0.41
311.7459106	0.40
312.3877563	0.23
313.0830688	0.29
317.0283203	0.21
322.1691895	0.04
324.2448120	2.42
325.2729492	1.60
327.2829285	7.84
337.1444092	100.00
339.2200928	8.20
343.2867432	0.15
354.2610474	0.42
360.1923218	0.09
361.1429443	0.20
367.2071533	0.10
373.8981934	0.20
375.1494751	0.12
386.4913940	0.22
388.9025269	1.80
394.2141724	0.15
396.4470825	0.15
402.4329224	0.74
403.2244873	0.14
404.5174561	0.47
422.2836914	0.07
428.0129395	0.05
428.9181519	0.29
436.1331787	0.49
445.3959961	0.19
446.3414917	0.19
447.4970093	0.28
457.3518677	0.09
463.3536377	0.20
472.0932007	0.05
472.9898071	0.11
485.4020996	0.17
487.2689819	0.16
489.2421265	0.14
493.0081787	0.09
498.7301636	0.07
505.3529663	0.09
507.2073975	0.37
508.2932739	0.81
514.3718262	0.19
515.2346802	0.41
519.1012573	0.18
529.7913208	0.12
530.5066528	0.08
531.2893677	0.20
533.3434448	0.33
536.6241455	0.13
537.5741577	0.05
539.9454346	0.06
545.1592407	0.07
546.3425293	0.38
547.0700684	0.13
551.2188110	2.06
565.4387207	0.22
566.3499146	2.79
567.3391724	0.73
572.2832642	0.38
573.3378906	0.26
590.4487305	1.40
591.4588013	0.57
593.2118530	0.68
607.4236450	0.10
608.3853149	0.24
609.2876587	0.68
631.2553711	0.38
632.8203125	0.47
634.3084106	1.37
635.2266235	1.12
647.2928467	1.63
648.7155151	0.24
649.3483276	0.43
650.4183350	0.90
651.1765747	1.95
653.3414917	0.22
658.6871948	0.22
659.4778442	0.21
663.1491699	0.63
665.2282104	0.79
676.0932007	0.09
677.2635498	1.73
680.1737061	0.80
681.2222290	0.41
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	527.2113
Annotation	Abelioside A
Peak:m/z	Relative Intensity
148.7217102	0.23
155.0168610	0.89
156.7086945	0.96
159.0448151	0.66
161.0476379	1.89
162.9862213	3.36
165.0989685	0.92
167.0661774	0.84
167.7961121	0.40
169.0722961	1.14
171.1230927	1.01
173.2459412	1.46
175.1136169	0.65
177.2210999	0.86
179.1205139	0.13
180.9275818	0.40
183.0412750	2.31
184.0744781	0.21
185.0426025	3.08
186.9673615	1.01
189.0071411	0.90
191.0551605	0.63
195.1596985	0.45
197.1317139	3.16
199.1902618	1.15
201.0421906	3.57
203.1798248	0.87
205.1607971	0.64
207.1304626	2.24
209.3612976	0.15
210.0354919	0.36
212.9810333	1.11
215.0699005	3.83
217.1777039	0.34
219.1316376	4.80
222.9425049	0.07
225.1719055	6.47
231.1444550	2.37
233.1657104	1.59
235.0158234	0.37
237.2379150	0.24
241.0833435	0.30
241.9368439	0.07
243.1757202	37.28
249.2236938	0.09
251.0267639	0.10
254.8319244	0.34
257.3278809	0.13
260.5452271	2.17
261.1660461	37.17
271.1635742	0.71
273.0513306	0.44
275.1613770	0.13
277.0572510	0.28
278.5806885	0.09
279.1893005	1.66
281.4303589	0.76
285.2255859	0.22
289.1277771	0.77
291.6137085	0.45
295.4400024	0.09
300.9558716	0.16
303.2762146	0.98
317.2736816	0.71
319.2224121	0.42
321.1905518	3.56
322.7093506	0.62
325.2095947	0.48
327.1594238	0.11
329.0824585	3.86
332.7805786	0.55
335.0170898	0.79
339.1506348	0.28
341.3953857	0.13
343.0030518	0.38
345.0235596	1.44
347.1149292	28.11
348.3135376	0.08
349.8980103	0.44
350.9209595	0.11
355.1264038	0.11
357.1162109	0.30
358.7703857	0.46
363.0148926	0.70
365.1583252	35.41
369.2069092	0.48
375.1693726	1.43
376.1627808	1.65
378.3170776	0.20
383.1328735	21.05
387.1812134	2.14
388.7533569	0.49
393.5840454	0.97
405.2096558	1.06
406.5172729	0.59
407.1544800	7.81
417.0402832	0.07
423.3853149	0.57
425.1502075	100.00
441.4983521	0.42
447.2459717	0.58
449.5352173	0.50
452.2774048	0.38
453.4399414	0.23
463.3244629	0.52
464.8228149	1.13
465.5237427	0.66
467.2608643	0.38
470.7231445	0.21
473.2089844	3.61
479.0199585	0.90
481.3468018	0.28
482.9353027	0.89
483.6311646	0.52
491.1481323	17.61
495.3716431	0.39
499.3659058	0.21
509.0978394	37.20
509.7649536	0.32
510.6876831	0.32
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	negtive
CollisionEnergy	NA
PrecursorMz	663.2139
Annotation	Barbatoside A
Peak:m/z	Relative Intensity
195.1005249	11.82
203.0099030	0.07
209.1766052	0.20
219.2376251	0.52
229.3073730	0.03
237.0075073	0.60
245.2084351	0.07
248.8780365	0.11
279.3288574	0.09
283.2484436	0.07
307.2160034	0.10
323.1694336	0.04
335.2788086	0.06
337.0814209	0.07
339.1345520	4.24
357.1337280	100.00
363.1904907	0.41
371.0928955	0.34
380.8894043	0.83
399.0906372	24.27
410.8656006	0.20
415.1748047	0.16
422.7614746	0.15
423.4036865	0.41
427.8428955	0.07
428.9448853	2.35
429.6152954	0.13
437.3425903	0.20
439.2279663	2.07
441.0418091	0.99
453.2952271	0.16
454.9990234	0.15
457.4435425	0.08
458.8385010	8.64
459.5202637	0.12
465.0338745	0.60
467.1325684	0.16
469.2020874	0.19
470.8905029	0.12
473.9918823	0.27
481.0270386	0.12
483.2628784	0.35
489.1027222	0.31
499.4734497	0.47
501.1359253	25.23
501.7622681	0.13
505.3243408	0.12
511.2622681	0.25
517.1265259	0.45
519.0079956	4.14
543.0207520	0.84
555.1000366	0.11
558.6171265	0.12
561.2808228	0.25
573.1785889	3.60
575.0319214	0.05
579.0269165	0.04
599.2390747	0.05
601.2872925	0.05
603.1032104	14.97
617.2383423	0.11
618.4432983	0.10
619.4259033	0.72
627.1804199	10.40
633.0927734	0.29
643.1448364	0.26
645.1539307	0.43
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	604.2153
Annotation	Fesumtuorin D
Peak:m/z	Relative Intensity
174.5723419	0.03
175.2022552	0.03
178.0655823	0.02
185.1397552	0.11
199.1109619	0.86
200.9172058	0.37
202.9830627	8.78
204.3915405	0.11
209.3340759	0.08
215.0476837	0.27
218.0383911	0.44
219.3128204	0.07
223.3022003	0.11
227.1228027	0.35
229.2956390	0.06
230.4772949	0.12
231.3215790	0.38
232.1283264	0.22
233.1804810	1.56
234.2149048	0.72
238.0792542	0.15
241.2959137	0.35
243.1098938	0.13
256.1010437	0.06
257.4101257	0.44
262.1015015	0.06
265.3166504	0.01
269.0961304	5.17
270.0884705	0.38
271.2445068	0.13
287.0790405	59.73
288.2298584	0.14
298.7430420	0.39
300.0503540	0.07
313.1728516	0.16
317.0268555	1.14
318.1619873	1.82
324.1973267	0.04
353.3464355	0.13
385.2290649	0.06
392.3882446	0.07
400.9965210	0.14
433.5002441	0.07
473.2619019	0.07
474.3144531	0.11
502.1439209	0.06
503.7702637	0.02
513.3671265	0.05
518.1231079	0.08
519.0184937	0.06
532.1619263	0.04
533.2265015	0.04
550.3423462	0.09
555.0690308	0.34
568.3546143	0.03
569.8170776	0.07
573.0434570	100.00
573.8367310	0.14
577.0177612	0.08
583.4883423	0.05
586.5563354	0.37
587.1838989	0.04
590.1237183	0.05
END
BEGIN
MsLevel	MS2
Instrument	LTQ-FT (Thermo Fisher Scientific)
InstrumentType	LC-FTICR-MS
IonMode	positive
CollisionEnergy	NA
PrecursorMz	484.1803
Annotation	Unknow
Peak:m/z	Relative Intensity
191.0232544	0.60
199.0537720	0.37
201.4089661	0.26
202.9918823	3.53
226.4602966	0.73
241.2237091	0.13
269.0993042	3.92
283.2630005	0.45
287.0077209	32.36
291.1001587	0.18
291.9975891	0.27
304.8455200	100.00
305.5062256	0.27
306.9523926	0.13
311.9252625	0.11
320.3386230	0.17
321.9421692	0.16
330.0983276	0.20
332.4178467	0.10
338.3553162	0.44
344.9659424	0.26
358.3101196	0.21
363.2961426	0.55
369.3183899	0.47
371.3812866	0.66
378.4276428	0.09
381.3214417	0.87
382.0764465	0.31
384.9782410	0.16
390.0180664	0.25
394.3241882	0.27
395.4628601	0.44
424.6105957	0.40
428.1416016	0.62
437.0308228	0.20
438.3290710	0.53
439.2278748	0.45
440.3601379	0.09
442.4353333	1.20
448.1993103	0.25
453.0155945	0.29
454.1993103	0.13
466.2372131	4.40
466.9322815	0.32
END